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1

MODELING AND CONTROL OF A O2/CO2 GAS TURBINE CYCLE FOR CO2 CAPTURE  

E-Print Network [OSTI]

MODELING AND CONTROL OF A O2/CO2 GAS TURBINE CYCLE FOR CO2 CAPTURE Lars Imsland Dagfinn Snarheim and control of a semi-closed O2/CO2 gas turbine cycle for CO2 capture. In the first part the process predictive control, Gas turbines, CO2 capture 1. INTRODUCTION Gas turbines are widely used for power

Foss, Bjarne A.

2

MAC-Kaust Project P1 CO2 Sequestration Modeling of CO2 sequestration including parameter  

E-Print Network [OSTI]

MAC-Kaust Project P1 ­ CO2 Sequestration Modeling of CO2 sequestration including parameter identification and numerical simulation M. Brokate, O. A. PykhteevHysteresis aspects of CO2 sequestration modeling K-H. Hoffmann, N. D. Botkin Objectives and methods of CO2 sequestration There is a popular belief

Turova, Varvara

3

System-level modeling for geological storage of CO2  

E-Print Network [OSTI]

of Geologic Storage of CO2, in Carbon Dioxide Capture forFormations - Results from the CO2 Capture Project: GeologicBenson, Process Modeling of CO2 Injection into Natural Gas

Zhang, Yingqi; Oldenburg, Curtis M.; Finsterle, Stefan; Bodvarsson, Gudmundur S.

2006-01-01T23:59:59.000Z

4

CO2 Sequestration Modeling Using Pattern Recognition and Data Mining;  

E-Print Network [OSTI]

carbon dioxide (CO2) sequestration process is to ensure a sustained confinement of the injected CO2CO2 Sequestration Modeling Using Pattern Recognition and Data Mining; Case Study of SACROC field, USA Abstract Capturing carbon dioxide (CO2) from industrial and energy-related sources and depositing

Mohaghegh, Shahab

5

Gravity monitoring of CO2 movement during sequestration: Model studies  

E-Print Network [OSTI]

combined CO 2 enhanced oil recovery (EOR) and sequestrationMODEL The enhanced oil recovery (EOR)/sequestration

Gasperikova, E.

2008-01-01T23:59:59.000Z

6

Modeling of CO2 storage in aquifers  

E-Print Network [OSTI]

Feb 6, 2011 ... atmosphere, increasing its temperature (greenhouse effect). To minimize climate change impacts, geological sequestration of CO2 is an ...

santos,,,

7

Selection of coals of different maturities for CO2 Storage by modelling of CH4 and CO2 adsorption isotherms  

E-Print Network [OSTI]

of this study is to compare and model pure gas sorption isotherms (CO2 and CH4) for well-characterised coals of different maturities to determine the most suitable coal for CO2 storage. Carbon dioxide and methane; Coals; Methane and carbon dioxide adsorption; Modelling isotherms 1. Introduction CO2 is a greenhouse

Paris-Sud XI, Université de

8

Modeling long-term CO2 storage, sequestration and cycling  

SciTech Connect (OSTI)

The application of numerical and analytical models to the problem of storage, sequestration and migration of carbon dioxide in geologic formations is discussed. A review of numerical and analytical models that have been applied to CO2 sequestration are presented, as well as a description of frameworks for risk analysis. Application of models to various issues related to carbon sequestration are discussed, including trapping mechanisms, density convection mixing, impurities in the CO2 stream, changes in formation porosity and permeability, the risk of vertical leakage, and the impacts on groundwater resources if leakage does occur. A discussion of the development and application of site-specific models first addresses the estimation of model parameters and the use of natural analogues to inform the development of CO2 sequestration models, and then surveys modeling that has been done at two commercial-scale CO2 sequestration sites, Sleipner and In Salah, along with a pilot-scale injection sites used to study CO2 sequestration in saline aquifers (Frio) and an experimental site designed to test monitoring of CO2 leakage in the vadose zone (ZERT Release Facility).

Bacon, Diana H.

2013-11-11T23:59:59.000Z

9

Inverse modeling of CO2 sources and sinks using satellite observations of CO2 from TES and surface flask measurements  

SciTech Connect (OSTI)

We infer CO2 surface fluxes using satellite observations of mid-tropospheric CO2 from the Tropospheric Emission Spectrometer (TES) and measurements of CO2 from surface flasks in a time-independent inversion analysis based on the GEOS-Chem model. Using TES CO2 observations over oceans, spanning 40 S 40 N, we find that the horizontal and vertical coverage of the TES and flask data are complementary. This complementarity is demonstrated by combining the datasets in a joint inversion, which provides better constraints than from either dataset alone, when a posteriori CO2 distributions are evaluated against independent ship and aircraft CO2 data. In particular, the joint inversion offers improved constraints in the tropics where surface measurements are sparse, such as the tropical forests of South America. Aggregating the annual surface-to-atmosphere fluxes from the joint inversion for the year 2006 yields 1.13 0.21 PgC for the global ocean, 2.77 0.20 PgC for the global land biosphere and 3.90 0.29 PgC for the total global natural flux (defined as the sum of all biospheric, oceanic, and biomass burning contributions but excluding CO2 emissions from fossil fuel combustion). These global ocean and global land fluxes are shown to be near the median of the broad range of values from other inversion results for 2006. To achieve these results, a bias in TES CO2 in the Southern Hemisphere was assessed and corrected using aircraft flask data, and we demonstrate that our results have low sensitivity to variations in the bias correction approach. Overall, this analysis suggests that future carbon data assimilation systems can benefit by integrating in situ and satellite observations of CO2 and that the vertical information provided by satellite observations of mid-tropospheric CO2 combined with measurements of surface CO2, provides an important additional constraint for flux inversions.

Nassar, Ray [University of Toronto; Jones, DBA [University of Toronto; Kulawik, SS [Jet Propulsion Laboratory, Pasadena, CA; Worden, JR [Jet Propulsion Laboratory, Pasadena, CA; Bowman, K [Jet Propulsion Laboratory, Pasadena, CA; Andres, Robert Joseph [ORNL; Suntharalingam, P [University of East Anglia, Norwich, United Kingdom; Chen, j. [University of Toronto; Brenninkmeijer, CAM [Max Planck Institut fur Chemie, Mainz; Schuck, TJ [Max Planck Institut fur Chemie, Mainz; Conway, T.J. [NOAA, Boulder, CO; Worthy, DE [Environment Canada

2011-01-01T23:59:59.000Z

10

numerical methodology to model and monitor co2 sequestration  

E-Print Network [OSTI]

CO2 sequestration is a means of mitigating the greenhouse effect [1]. Geologic sequestration involves injecting CO2 into a target geologic formation at depths ...

santos,,,

11

Methanol Synthesis from CO2 Hydrogenation over a Pd4/In2O3 Model...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Methanol Synthesis from CO2 Hydrogenation over a Pd4In2O3 Model Catalyst: A Combined DFT and Kinetic Study. Methanol Synthesis from CO2 Hydrogenation over a Pd4In2O3 Model...

12

Gravity monitoring of CO2 movement during sequestration: Model studies  

E-Print Network [OSTI]

CO 2 enhanced oil recovery (EOR) and sequestration in afor a coalbed methane formation. EOR/sequestration petroleumbut shallow compared to either EOR or brine formations. The

Gasperikova, E.

2008-01-01T23:59:59.000Z

13

Modelling CO2 diffusion and assimilation in a leaf with axisymmetric finite volumes  

E-Print Network [OSTI]

Modelling CO2 diffusion and assimilation in a leaf with axisymmetric finite volumes Emily Gallouët. This paper deals with the numerical simulation of the diffusion and assimilation by photosynthesis of CO2 medium, from experimental measurements of the pointwise value of internal CO2 concentration, giving some

Herbin, Raphaèle

14

USING TIME-LAPSE SEISMIC MEASUREMENTS TO IMPROVE FLOW MODELING OF CO2 INJECTION  

E-Print Network [OSTI]

Marly. The EOR process in the RCP section of the Weyburn Field uses CO2 and water injection to displaceUSING TIME-LAPSE SEISMIC MEASUREMENTS TO IMPROVE FLOW MODELING OF CO2 INJECTION IN THE WEYBURN, particularly CO2. Time lapse seismic monitoring has motivated changes to the reservoir description in a flow

15

System-level modeling for geological storage of CO2  

E-Print Network [OSTI]

CO 2 escapes the reservoir through the abandoned well. Theof the abandoned well and the gas reservoir is calculated by4 reservoir 1.e-12 1.e-14 8.4e-4 Fracture or abandoned well

Zhang, Yingqi; Oldenburg, Curtis M.; Finsterle, Stefan; Bodvarsson, Gudmundur S.

2006-01-01T23:59:59.000Z

16

Semi-analytical model of brine and CO2 leakage through an abandoned plugged well. Applications for determining an Area of Review and CO2 leakage rate  

E-Print Network [OSTI]

Semi-analytical model of brine and CO2 leakage through an abandoned plugged well. Applications for determining an Area of Review and CO2 leakage rate Arnaud Réveillère, Jérémy Rohmer, Frédéric Wertz / contact the leak, and of CO2,g as a first approach. Compared to the state of the art, it adds the possibility

Paris-Sud XI, Université de

17

Long-term effects of anthropogenic CO2 emissions simulated with a complex earth system model  

E-Print Network [OSTI]

Long-term effects of anthropogenic CO2 emissions simulated with a complex earth system model Uwe earth system model con- sisting of an atmospheric general circulation model, an ocean general

Winguth, Arne

18

Particle-scale CO2 adsorption kinetics modeling considering three reaction mechanisms  

SciTech Connect (OSTI)

In the presence of water (H2O), dry and wet adsorptions of carbon dioxide (CO2) and physical adsorption of H2O happen concurrently in a sorbent particle. The three reactions depend on each other and have a complicated, but important, effect on CO2 capturing via a solid sorbent. In this study, transport phenomena in the sorbent were modeled, including the tree reactions, and a numerical solving procedure for the model also was explained. The reaction variable distribution in the sorbent and their average values were calculated, and simulation results were compared with experimental data to validate the proposed model. Some differences, caused by thermodynamic parameters, were observed between them. However, the developed model reasonably simulated the adsorption behaviors of a sorbent. The weight gained by each adsorbed species, CO2 and H2O, is difficult to determine experimentally. It is known that more CO2 can be captured in the presence of water. Still, it is not yet known quantitatively how much more CO2 the sorbent can capture, nor is it known how much dry and wet adsorptions separately account for CO2 capture. This study addresses those questions by modeling CO2 adsorption in a particle and simulating the adsorption process using the model. As adsorption temperature changed into several values, the adsorbed amount of each species was calculated. The captured CO2 in the sorbent particle was compared quantitatively between dry and wet conditions. As the adsorption temperature decreased, wet adsorption increased. However, dry adsorption was reduced.

Suh, Dong-Myung; Sun, Xin

2013-09-01T23:59:59.000Z

19

Modeling of Near-Surface Leakage and Seepage of CO2 for Risk Characterization  

SciTech Connect (OSTI)

The injection of carbon dioxide (CO2) into deep geologic carbon sequestration sites entails risk that CO2 will leak away from the primary storage formation and migrate upwards to the unsaturated zone from which it can seep out of the ground. We have developed a coupled modeling framework called T2CA for simulating CO2 leakage and seepage in the subsurface and in the atmospheric surface layer. The results of model simulations can be used to calculate the two key health, safety, and environmental (HSE) risk drivers, namely CO2 seepage flux and nearsurface CO2 concentrations. Sensitivity studies for a subsurface system with a thick unsaturated zone show limited leakage attenuation resulting in correspondingly large CO2 concentrations in the shallow subsurface. Large CO2 concentrations in the shallow subsurface present a risk to plant and tree roots, and to humans and other animals in subsurface structures such as basements or utility vaults. Whereas CO2 concentrations in the subsurface can be high, surfacelayer winds reduce CO2 concentrations to low levels for the fluxes investigated. We recommend more verification and case studies be carried out with T2CA, along with the development of extensions to handle additional scenarios such as calm conditions, topographic effects, and catastrophic surface-layer discharge events.

Oldenburg, Curtis M.; Unger, Andre A.J.

2004-02-18T23:59:59.000Z

20

Physics and Seismic Modeling for Monitoring CO2 Storage JOSE M. CARCIONE,1  

E-Print Network [OSTI]

, methane-bearing coal beds and saline aquifers. An example of the latter is the Sleipner field in the North-elastical equations model the seismic properties of reservoir rocks saturated with CO2, methane, oil and brine-simulation methodology to compute synthetic seismograms for reservoirs subject to CO2 sequestration. The petro

Santos, Juan

Note: This page contains sample records for the topic "ks modeling co2" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Modeling Studies on the Transport of Benzene and H2S in CO2-Water Systems  

E-Print Network [OSTI]

interest in subcritical (hot/liquid) water from 298 K to 473subcritical region. Modeling Studies on the Transport of Benzene and H 2 S in CO 2 -Water

Zheng, L.

2011-01-01T23:59:59.000Z

22

Thermodynamic Data for Geochemical Modeling of Carbonate Reactions Associated with CO2 Sequestration – Literature Review  

SciTech Connect (OSTI)

Permanent storage of anthropogenic CO2 in deep geologic formations is being considered as a means to reduce the concentration of atmospheric CO2 and thus its contribution to global climate change. To ensure safe and effective geologic sequestration, numerous studies have been completed of the extent to which the CO2 migrates within geologic formations and what physical and geochemical changes occur in these formations when CO2 is injected. Sophisticated, computerized reservoir simulations are used as part of field site and laboratory CO2 sequestration studies. These simulations use coupled multiphase flow-reactive chemical transport models and/or standalone (i.e., no coupled fluid transport) geochemical models to calculate gas solubility, aqueous complexation, reduction/oxidation (redox), and/or mineral solubility reactions related to CO2 injection and sequestration. Thermodynamic data are critical inputs to modeling geochemical processes. The adequacy of thermodynamic data for carbonate compounds has been identified as an important data requirement for the successful application of these geochemical reaction models to CO2 sequestration. A review of thermodynamic data for CO2 gas and carbonate aqueous species and minerals present in published data compilations and databases used in geochemical reaction models was therefore completed. Published studies that describe mineralogical analyses from CO2 sequestration field and natural analogue sites and laboratory studies were also reviewed to identify specific carbonate minerals that are important to CO2 sequestration reactions and therefore require thermodynamic data. The results of the literature review indicated that an extensive thermodynamic database exists for CO2 and CH4 gases, carbonate aqueous species, and carbonate minerals. Values of ?fG298° and/or log Kr,298° are available for essentially all of these compounds. However, log Kr,T° or heat capacity values at temperatures above 298 K exist for less than approximately one-third of these compounds. Because the temperatures of host formations that will be used for CO2 injection and sequestration will be at tempera¬tures in the range of 50ºC to 100ºC or greater, the lack of high temperature thermodynamic values for key carbonate compounds especially minerals, will impact the accuracy of some modeling calculations.

Krupka, Kenneth M.; Cantrell, Kirk J.; McGrail, B. Peter

2010-09-28T23:59:59.000Z

23

Hydro-mechanical modelling of geological CO2 storage and the study of possible caprock fracture mechanisms  

E-Print Network [OSTI]

Hydro-mechanical modelling of geological CO2 storage and the study of possible caprock fracture element modelling of a hypothetical underground carbon dioxide (CO2) storage operation. The hydro

24

NUMERICAL MODELING OF CO2 SEQUESTRATION WITH ANOZIE EBIGBO, ANDREAS BIELINSKI, ANDREAS KOPP, HOLGER CLASS, RAINER HELMIG  

E-Print Network [OSTI]

KOPP, HOLGER CLASS, RAINER HELMIG Universit¨at Stuttgart Institute of Hydraulic Engineering Chair. It takes into account the two phases CO2 and brine and the components CO2 and water which can dissolve the conceptual model for a non-isothermal composi- tional CO2-water (brine) model based on the simulator MUFTE

Cirpka, Olaf Arie

25

Gravity monitoring of CO2 movement during sequestration: Model studies  

SciTech Connect (OSTI)

We examine the relative merits of gravity measurements as a monitoring tool for geological CO{sub 2} sequestration in three different modeling scenarios. The first is a combined CO{sub 2} enhanced oil recovery (EOR) and sequestration in a producing oil field, the second is sequestration in a brine formation, and the third is for a coalbed methane formation. EOR/sequestration petroleum reservoirs have relatively thin injection intervals with multiple fluid components (oil, hydrocarbon gas, brine, and CO{sub 2}), whereas brine formations usually have much thicker injection intervals and only two components (brine and CO{sub 2}). Coal formations undergoing methane extraction tend to be thin (3-10 m), but shallow compared to either EOR or brine formations. The injection of CO{sub 2} into the oil reservoir produced a bulk density decrease in the reservoir. The spatial pattern of the change in the vertical component of gravity (G{sub z}) is directly correlated with the net change in reservoir density. Furthermore, time-lapse changes in the borehole G{sub z} clearly identified the vertical section of the reservoir where fluid saturations are changing. The CO{sub 2}-brine front, on the order of 1 km within a 20 m thick brine formation at 1900 m depth, with 30% CO{sub 2} and 70% brine saturations, respectively, produced a -10 Gal surface gravity anomaly. Such anomaly would be detectable in the field. The amount of CO{sub 2} in a coalbed methane test scenario did not produce a large enough surface gravity response; however, we would expect that for an industrial size injection, the surface gravity response would be measurable. Gravity inversions in all three scenarios illustrated that the general position of density changes caused by CO{sub 2} can be recovered, but not the absolute value of the change. Analysis of the spatial resolution and detectability limits shows that gravity measurements could, under certain circumstances, be used as a lower-cost alternative to seismic measurements.

Gasperikova, E.; Hoversten, G.M.

2008-07-15T23:59:59.000Z

26

MODELING OF CO2 LEAKAGE UP THROUGH AN ABANDONED WELL FROM DEEP SALINE AQUIFER TO SHALLOW FRESH  

E-Print Network [OSTI]

1 MODELING OF CO2 LEAKAGE UP THROUGH AN ABANDONED WELL FROM DEEP SALINE AQUIFER TO SHALLOW FRESH restricted to: (i) supercritical CO2 injection and storage within the Dogger reservoir aquifer, (ii) CO2 the cement-rock formation interface in the abandoned well (iii) impacts on the Albian aquifer water quality

Paris-Sud XI, Université de

27

Modeling of CO2 Reduction Impacts on Energy Prices with Modelica Philip Machanick1  

E-Print Network [OSTI]

Modeling of CO2 Reduction Impacts on Energy Prices with Modelica Philip Machanick1 , Ariel Liebman1 and benefits, which may be better addressed by earlier interven- tion. In this paper we present a Modelica at the ap- propriate rate. In this paper we present a Modelica model which explores the trade

Machanick, Philip

28

The martian mesosphere as revealed by CO2 cloud observations and General Circulation Modeling  

E-Print Network [OSTI]

a rare dataset of mesospheric winds. We compare the mesospheric zonal winds pre- dicted by the model by the model. Ã? 2011 Elsevier Inc. All rights reserved. 1. Introduction While the formation of CO2 clouds observations on board Mars Global Surveyor (Clancy et al., 2004, 2007), and later confirmed by THEMIS-VIS (Mc

Spiga, Aymeric

29

Intercomparison of simulation models for CO2 disposal in underground storage reservoirs  

E-Print Network [OSTI]

oil recovery (EOR) using CO2 requires an understanding ofexperience with using CO2 for EOR projects (SPE, 1999), and

Pruess, Karsten; Tsang, Chin-Fu; Law, David; Oldenburg, Curt

2001-01-01T23:59:59.000Z

30

Toward Verifying Fossil Fuel CO2 Emissions with the CMAQ Model: Motivation, Model Description and Initial Simulation  

SciTech Connect (OSTI)

Motivated by the urgent need for emission verification of CO2 and other greenhouse gases, we have developed regional CO2 simulation with CMAQ over the contiguous U.S. Model sensitivity experiments have been performed using three different sets of inputs for net ecosystem exchange (NEE) and two fossil fuel emission inventories, to understand the roles of fossil fuel emissions, atmosphere-biosphere exchange and transport in regulating the spatial and diurnal variability of CO2 near the surface, and to characterize the well-known ‘signal-to-noise’ problem, i.e. the interference from the biosphere on the interpretation of atmospheric CO2 observations. It is found that differences in the meteorological conditions for different urban areas strongly contribute to the contrast in concentrations. The uncertainty of NEE, as measured by the difference among the three different NEE inputs, has notable impact on regional distribution of CO2 simulated by CMAQ. Larger NEE uncertainty and impact are found over eastern U.S. urban areas than along the western coast. A comparison with tower CO2 measurements at Boulder Atmospheric Observatory (BAO) shows that the CMAQ model using hourly varied and high-resolution CO2 emission from the Vulcan inventory and CarbonTracker optimized NEE reasonably reproduce the observed diurnal profile, whereas switching to different NEE inputs significantly degrades the model performance. Spatial distribution of CO2 is found to correlate with NOx, SO2 and CO, due to their similarity in emission sources and transport processes. These initial results from CMAQ demonstrate the power of a state-of-the art CTM in helping interpret CO2 observations and verify fossil fuel emissions. The ability to simulate CO2 in CMAQ will also facilitate investigations of the utility of traditionally regulated pollutants and other species as tracers to CO2 source attribution.

Liu, Zhen; Bambha, Ray P.; Pinto, Joseph P.; Zeng, Tao; Boylan, Jim; Huang, Maoyi; Lei, Huimin; Zhao, Chun; Liu, Shishi; Mao, Jiafu; Schwalm, Christopher R.; Shi, Xiaoying; Wei, Yaxing; Michelsen, Hope A.

2014-03-14T23:59:59.000Z

31

The H-Cube Project: Hydrodynamics, Heterogeneity and Homogenization in CO2 storage modeling  

E-Print Network [OSTI]

. Audigane, BRGM, E. Mouche, CEA, S. Viseur, CEREGE, D. Guérillot, TERRA 3E And the H-CUBE team Key words-scaling processes We propose to assess the buoyant forces on the CO2 and brine vertical migration of heterogeneity field distribution on the same 3D static earth model appropriate ranking measures of the static

Paris-Sud XI, Université de

32

3D CFD Model of High Temperature H2O/CO2 Co-electrolysis  

SciTech Connect (OSTI)

3D CFD Model of High Temperature H2O/CO2 Co-Electrolysis Grant Hawkes1, James O’Brien1, Carl Stoots1, Stephen Herring1 Joe Hartvigsen2 1 Idaho National Laboratory, Idaho Falls, Idaho, grant.hawkes@inl.gov 2 Ceramatec Inc, Salt Lake City, Utah INTRODUCTION A three-dimensional computational fluid dynamics (CFD) model has been created to model high temperature co-electrolysis of steam and carbon dioxide in a planar solid oxide electrolyzer (SOE) using solid oxide fuel cell technology. A research program is under way at the Idaho National Laboratory (INL) to simultaneously address the research and scale-up issues associated with the implementation of planar solid-oxide electrolysis cell technology for syn-gas production from CO2 and steam. Various runs have been performed under different run conditions to help assess the performance of the SOE. This paper presents CFD results of this model compared with experimental results. The Idaho National Laboratory (INL), in conjunction with Ceramatec Inc. (Salt Lake City, USA) has been researching for several years the use of solid-oxide fuel cell technology to electrolyze steam for large-scale nuclear-powered hydrogen production. Now, an experimental research project is underway at the INL to produce syngas by simultaneously electrolyzing at high-temperature steam and carbon dioxide (CO2) using solid oxide fuel cell technology. A strong interest exists in the large-scale production of syn-gas from CO2 and steam to be reformed into a usable transportation fuel. If biomass is used as the carbon source, the overall process is climate neutral. Consequently, there is a high level of interest in production of syn-gas from CO2 and steam electrolysis. With the price of oil currently around $60 / barrel, synthetically-derived hydrocarbon fuels (synfuels) have become economical. Synfuels are typically produced from syngas – hydrogen (H2) and carbon monoxide (CO) -- using the Fischer-Tropsch process, discovered by Germany before World War II. High-temperature nuclear reactors have the potential for substantially increasing the efficiency of syn-gas production from CO2 and water, with no consumption of fossil fuels, and no production of greenhouse gases. Thermal CO2-splitting and water splitting for syn-gas production can be accomplished via high-temperature electrolysis, using high-temperature nuclear process heat and electricity. A high-temperature advanced nuclear reactor coupled with a high-efficiency high-temperature electrolyzer could achieve a competitive thermal-to-syn-gas conversion efficiency of 45 to 55%.

Grant Hawkes; James O'Brien; Carl Stoots; Stephen Herring; Joe Hartvigsen

2007-06-01T23:59:59.000Z

33

ENHANCING THE ATOMIC-LEVEL UNDERSTANDING OF CO2 MINERAL SEQUESTRATION MECHANISMS VIA ADVANCED COMPUTATIONAL MODELING  

SciTech Connect (OSTI)

Fossil fuels currently provide 85% of the world's energy needs, with the majority coming from coal, due to its low cost, wide availability, and high energy content. The extensive use of coal-fired power assumes that the resulting CO2 emissions can be vented to the atmosphere. However, exponentially increasing atmospheric CO2 levels have brought this assumption under critical review. Over the last decade, this discussion has evolved from whether exponentially increasing anthropogenic CO2 emissions will adversely affect the global environment, to the timing and magnitude of their impact. A variety of sequestration technologies are being explored to mitigate CO2 emissions. These technologies must be both environmentally benign and economically viable. Mineral carbonation is an attractive candidate technology as it disposes of CO2 as geologically stable, environmentally benign mineral carbonates, clearly satisfying the first criteria. The primary challenge for mineral carbonation is cost-competitive process development. CO2 mineral sequestration--the conversion of stationary-source CO2 emissions into mineral carbonates (e.g., magnesium and calcium carbonate, MgCO3 and CaCO3)--has recently emerged as one of the most promising sequestration options, providing permanent CO2 disposal, rather than storage. In this approach a magnesium-bearing feedstock mineral (typically serpentine or olivine; available in vast quantities globally) is specially processed and allowed to react with CO2 under controlled conditions. This produces a mineral carbonate which (1) is environmentally benign, (2) already exists in nature in quantities far exceeding those that could result from carbonating the world's known fossil fuel reserves, and (3) is stable on a geological time scale. Minimizing the process cost via optimization of the reaction rate and degree of completion is the remaining challenge. As members of the DOE/NETL managed National Mineral Sequestration Working Group we have already significantly improved our understanding of mineral carbonation. Group members at the Albany Research Center have recently shown that carbonation of olivine and serpentine, which naturally occurs over geological time (i.e., 100,000s of years), can be accelerated to near completion in hours. Further process refinement will require a synergetic science/engineering approach that emphasizes simultaneous investigation of both thermodynamic processes and the detailed microscopic, atomic-level mechanisms that govern carbonation kinetics. Our previously funded Phase I Innovative Concepts project demonstrated the value of advanced quantum-mechanical modeling as a complementary tool in bridging important gaps in our understanding of the atomic/molecular structure and reaction mechanisms that govern CO2 mineral sequestration reaction processes for the model Mg-rich lamellar hydroxide feedstock material Mg(OH)2. In the present simulation project, improved techniques and more efficient computational schemes have allowed us to expand and augment these capabilities and explore more complex Mg-rich, lamellar hydroxide-based feedstock materials, including the serpentine-based minerals. These feedstock materials are being actively investigated due to their wide availability, and low-cost CO2 mineral sequestration potential. Cutting-edge first principles quantum chemical, computational solid-state and materials simulation methodology studies proposed herein, have been strategically integrated with our new DOE supported (ASU-Argonne National Laboratory) project to investigate the mechanisms that govern mineral feedstock heat-treatment and aqueous/fluid-phase serpentine mineral carbonation in situ. This unified, synergetic theoretical and experimental approach has provided a deeper understanding of the key reaction mechanisms than either individual approach can alone. We used ab initio techniques to significantly advance our understanding of atomic-level processes at the solid/solution interface by elucidating the origin of vibrational, electronic, x-ray and electron energy loss sp

A.V.G. Chizmeshya; M.J. McKelvy; G.H. Wolf; R.W. Carpenter; D.A. Gormley; J.R. Diefenbacher; R. Marzke

2006-03-01T23:59:59.000Z

34

A Mechanistic Model for CO2 Sequestration in Tiffany Coal Bed Methane Field  

SciTech Connect (OSTI)

The objective of this project is to develop mechanistic models specific to CO2 sequestration in BP’s Tiffany coal bed methane (CBM) field. In this study, the original field model was modified to match the field performance of a 5-spot pattern in the northern part of the Tiffany Field where BP plans to perform a micro-pilot test. The modified model consists of one high-permeability fast layer sandwiched between two low-permeability slow layers. In this mechanistic model, the fast layer represents well-cleated and fractured coal from all geological layers while the slow layers represent coal with little or no fracture development from the same geological layers. The model successfully matched the performance of the 5-spot pattern during the enhanced recovery period (N2 injection). However, in order to match nitrogen breakthrough times and nitrogen cut the vertical transmissibility between layers had to be set to zero. During gas injection, nitrogen was allowed to enter all three layers, not just the high-permeability fast layer. However, because the permeabilities of the slow layers were low and there is no communication between the fast and the slow layers, most of the injected nitrogen entered the high-permeability fast layer. This suggests that the future gas injection and CO2 sequestration may be restricted to only one third of the total available pay. For future gas injections, the modified model predicted early CO2 breakthrough with high CO2 cut. This suggests that the actual CO2 sequestration capability of the Tiffany Field might not be as high as originally expected. This is a direct consequence of the reduced available pay in the modified model. The modified model also predicted early inert gas (N2 plus CO2) breakthrough and high inert gas cut during future gas injections. If this is confirmed in the pilot test, the high volume of inert gas produced could overwhelm the reprocessing capability resulting in early termination of the project.

Jenn-Tai Liang; Kevin T. Raterman; Eric P. Robertson

2003-05-01T23:59:59.000Z

35

Project Profile: Physics-Based Reliability Models for Supercritical-CO2 Turbomachinery Components  

Broader source: Energy.gov [DOE]

GE, under the Physics of Reliability: Evaluating Design Insights for Component Technologies in Solar (PREDICTS) Program will be leveraging internally developed models to predict the reliability of hybrid gas bearing (HGB) and dry gas seal (DGS) components in the turboexpander of a supercritical CO2 turbine. The Bayesian model is to include phase changes, low cycle fatigue/high cycle fatigue, dynamic instabilities, and corrosion processes.

36

Mathematical models as tools for probing long-term safety of CO2 storage  

E-Print Network [OSTI]

reservoirs, with large capacity for CO 2 storage (Bradshaw and Dance, 2004; Bachu, 2008). Improperly abandoned

Pruess, Karsten

2010-01-01T23:59:59.000Z

37

A Mechanistic Model for CO2 Sequestration in Tiffany Coal Bed Methane Field  

SciTech Connect (OSTI)

The objective of this project is to develop mechanistic models specific to CO2 sequestration in BP's Tiffany coal bed methane (CBM) field. In this study, the original field model was modified to match the field performance of a 5-spot pattern in the northern part of the Tiffany Field where BP plans to perform a micro-pilot test. The modified model consists of one high-permeability fast layer sandwiched between two low-permeability slow layers. In this mechanistic model, the fast layer represents well-cleated and fractured coal from all geological layers while the slow layers represent coal with little or no fracture development from the same geological layers. The model successfully matched the performance of the 5-spot pattern during the enhanced recovery period. However, in order to match nitrogen breakthrough times and nitrogen cut the vertical transmissibility between layers had to be set to zero. During gas injection, nitrogen was allowed to enter all three layers, not just the high-permeability fast layer. However, because the permeabilities of the slow layers were low and there is no communication between the fast and the slow layers, most of the injected nitrogen entered the high-permeability fast layer. This suggests that the future gas injection and CO2 sequestration may be restricted to only one third of the total available pay.

Liang, J.; Raterman, K.T.; Robertson, E.P.

2003-05-01T23:59:59.000Z

38

Modeling and Evaluation of Geophysical Methods for Monitoring and Tracking CO2 Migration  

SciTech Connect (OSTI)

Geological sequestration has been proposed as a viable option for mitigating the vast amount of CO{sub 2} being released into the atmosphere daily. Test sites for CO{sub 2} injection have been appearing across the world to ascertain the feasibility of capturing and sequestering carbon dioxide. A major concern with full scale implementation is monitoring and verifying the permanence of injected CO{sub 2}. Geophysical methods, an exploration industry standard, are non-invasive imaging techniques that can be implemented to address that concern. Geophysical methods, seismic and electromagnetic, play a crucial role in monitoring the subsurface pre- and post-injection. Seismic techniques have been the most popular but electromagnetic methods are gaining interest. The primary goal of this project was to develop a new geophysical tool, a software program called GphyzCO2, to investigate the implementation of geophysical monitoring for detecting injected CO{sub 2} at test sites. The GphyzCO2 software consists of interconnected programs that encompass well logging, seismic, and electromagnetic methods. The software enables users to design and execute 3D surface-to-surface (conventional surface seismic) and borehole-to-borehole (cross-hole seismic and electromagnetic methods) numerical modeling surveys. The generalized flow of the program begins with building a complex 3D subsurface geological model, assigning properties to the models that mimic a potential CO{sub 2} injection site, numerically forward model a geophysical survey, and analyze the results. A test site located in Warren County, Ohio was selected as the test site for the full implementation of GphyzCO2. Specific interest was placed on a potential reservoir target, the Mount Simon Sandstone, and cap rock, the Eau Claire Formation. Analysis of the test site included well log data, physical property measurements (porosity), core sample resistivity measurements, calculating electrical permittivity values, seismic data collection, and seismic interpretation. The data was input into GphyzCO2 to demonstrate a full implementation of the software capabilities. Part of the implementation investigated the limits of using geophysical methods to monitor CO{sub 2} injection sites. The results show that cross-hole EM numerical surveys are limited to under 100 meter borehole separation. Those results were utilized in executing numerical EM surveys that contain hypothetical CO{sub 2} injections. The outcome of the forward modeling shows that EM methods can detect the presence of CO{sub 2}.

Daniels, Jeff

2012-11-30T23:59:59.000Z

39

Mathematical models as tools for probing long-term safety of CO2 storage  

E-Print Network [OSTI]

where CO 2 used for enhanced oil recovery has broken throughformations for enhanced oil recovery (EOR) has been

Pruess, Karsten

2010-01-01T23:59:59.000Z

40

Large releases from CO2 storage reservoirs: Analogs, scenarios, and modeling needs  

E-Print Network [OSTI]

abandoned wells is a major concern for storage of CO 2 in depleted or near-depleted oil and gas reservoirs [

Birkholzer, Jens; Pruess, Karsten; Lewicki, Jennifer; Rutqvist, Jonny; Tsang, Chin-Fu; Karimjee, Anhar

2006-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "ks modeling co2" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Large releases from CO2 storage reservoirs: analogs, scenarios, and modeling needs  

E-Print Network [OSTI]

abandoned wells is a major concern for storage of CO 2 in depleted or near-depleted oil and gas reservoirs [

Birkholzer, Jens; Pruess, Karsten; Lewicki, Jennifer; Rutqvist, Jonny; Tsang, Chin-Fu; Karimjee, Anhar

2005-01-01T23:59:59.000Z

42

Large Releases from CO2 Storage Reservoirs: A Discussion of Natural Analogs, FEPS, and Modeling Needs  

E-Print Network [OSTI]

abandoned wells is a major concern for geological storage of CO 2 in depleted or near-depleted oil and gas reservoirs [

Birkholzer, J.; Pruess, K.; Lewicki, J.L.; Rutqvist, J.; Tsang, C-F.; Karimjee, A.

2008-01-01T23:59:59.000Z

43

Techno-economic modelling of CO2 capture systems for Australian industrial sources.  

E-Print Network [OSTI]

??Australia is recognising that carbon capture and storage (CCS) may be a feasible pathway for addressing increasing levels of CO2 emissions. This thesis presents a… (more)

Ho, Minh Trang Thi

2007-01-01T23:59:59.000Z

44

A Plant-Level Simulation Model for Evaluating CO2 Capture Options  

E-Print Network [OSTI]

- Resource use Environmental Emissions - Air, water, land Plant & Process Costs - Capital - O&M - COE #12;E · Subcritical · Supercritical · Ultra-supercritical Furnace Firing Types · Tangential · Wall · Cyclone Furnace: - Water gas shift + CO2 capture (pre-combustion) · CO2 Transport Options Pipelines (six U.S. regions

45

Modeling Density Effects in CO2 Injection in Oil Reservoirs and A Case Study of CO2 Sequestration in a Qatari Saline Aquifer  

E-Print Network [OSTI]

(and density) of a reference component (usually methane) and other factors that are independent of mixture density. Therefore, modifying the shift parameter of CO2 does not affect the viscosity of the mixture. Table 2.1 – Fluid composition...

Ahmed, Tausif

2012-10-19T23:59:59.000Z

46

Development of Chemical Model to Predict the Interactions between Supercritical CO2and Fluid, and Rocks in EGS Reservoirs  

Broader source: Energy.gov [DOE]

This project will develop a chemical model, based on existing models and databases, that is capable of simulating chemical reactions between supercritical (SC) CO2 and Enhanced Geothermal System (EGS) reservoir rocks of various compositions in aqueous, non-aqueous and 2-phase environments.

47

Large releases from CO2 storage reservoirs: analogs, scenarios,and modeling needs  

SciTech Connect (OSTI)

While the purpose of geologic storage in deep salineformations is to trap greenhouse gases underground, the potential existsfor CO2 to escape from the target reservoir, migrate upward alongpermeable pathways, and discharge at the land surface. In this paper, weevaluate the potential for such CO2 discharges based on the analysis ofnatural analogs, where large releases of gas have been observed. We areparticularly interested in circumstances that could generate sudden,possibly self-enhancing release events. The probability for such eventsmay be low, but the circumstances under which they occur and thepotential consequences need to be evaluated in order to designappropriate site-selection and risk-management strategies. Numericalmodeling of hypothetical test cases is suggested to determine criticalconditions for large CO2 releases, to evaluate whether such conditionsmaybe possible at designated storage sites, and, if applicable, toevaluate the potential impacts of such events as well as designappropriate mitigation strategies.

Birkholzer, Jens; Pruess, Karsten; Lewicki, Jennifer; Rutqvist,Jonny; Tsang, Chin-Fu; Karimjee, Anhar

2005-09-01T23:59:59.000Z

48

Developing Model Constraints on Northern Extra-Tropical Carbon Cycling Based on measurements of the Abundance and Isotopic Composition of Atmospheric CO2  

SciTech Connect (OSTI)

The objective of this project was to perform CO2 data syntheses and modeling activities to address two central questions: 1) how much has the seasonal cycle in atmospheric CO2 at northern high latitudes changed since the 1960s, and 2) how well do prognostic biospheric models represent these changes. This project also supported the continuation of the Scripps time series of CO2 isotopes and concentration at ten baseline stations distributed globally.

Keeling, Ralph [UCSD-SIO

2014-12-12T23:59:59.000Z

49

Mulitdimensional reactive transport modeling of CO2 minreal sequestration in basalts at the Helllisheidi geothermal field, Iceland  

E-Print Network [OSTI]

geothermal power plant. In simulations of the pilot CO 2simulation of a 10 year full-scale CO 2 injection from Hellisheidi power plant. (

Aradottir, E.S.P.

2013-01-01T23:59:59.000Z

50

Data Assimilation Tools for CO2 Reservoir Model Development – A Review of Key Data Types, Analyses, and Selected Software  

SciTech Connect (OSTI)

Pacific Northwest National Laboratory (PNNL) has embarked on an initiative to develop world-class capabilities for performing experimental and computational analyses associated with geologic sequestration of carbon dioxide. The ultimate goal of this initiative is to provide science-based solutions for helping to mitigate the adverse effects of greenhouse gas emissions. This Laboratory-Directed Research and Development (LDRD) initiative currently has two primary focus areas—advanced experimental methods and computational analysis. The experimental methods focus area involves the development of new experimental capabilities, supported in part by the U.S. Department of Energy’s (DOE) Environmental Molecular Science Laboratory (EMSL) housed at PNNL, for quantifying mineral reaction kinetics with CO2 under high temperature and pressure (supercritical) conditions. The computational analysis focus area involves numerical simulation of coupled, multi-scale processes associated with CO2 sequestration in geologic media, and the development of software to facilitate building and parameterizing conceptual and numerical models of subsurface reservoirs that represent geologic repositories for injected CO2. This report describes work in support of the computational analysis focus area. The computational analysis focus area currently consists of several collaborative research projects. These are all geared towards the development and application of conceptual and numerical models for geologic sequestration of CO2. The software being developed for this focus area is referred to as the Geologic Sequestration Software Suite or GS3. A wiki-based software framework is being developed to support GS3. This report summarizes work performed in FY09 on one of the LDRD projects in the computational analysis focus area. The title of this project is Data Assimilation Tools for CO2 Reservoir Model Development. Some key objectives of this project in FY09 were to assess the current state-of-the-art in reservoir model development, the data types and analyses that need to be performed in order to develop and parameterize credible and robust reservoir simulation models, and to review existing software that is applicable to these analyses. This report describes this effort and highlights areas in which additional software development, wiki application extensions, or related GS3 infrastructure development may be warranted.

Rockhold, Mark L.; Sullivan, E. C.; Murray, Christopher J.; Last, George V.; Black, Gary D.

2009-09-30T23:59:59.000Z

51

CO2 sequestration | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

CO2 sequestration CO2 sequestration Leads No leads are available at this time. Low-Temperature Carbon Monoxide Oxidation Catalysed by Regenerable Atomically Dispersed Palladium on...

52

CO2 exposure at pressure impacts metabolism and stress responses in the model sulfate-reducing bacterium Desulfovibrio vulgaris strain Hildenborough  

SciTech Connect (OSTI)

Geologic carbon dioxide (CO2) sequestration drives physical and geochemical changes in deep subsurface environments that impact indigenous microbial activities. The combined effects of pressurized CO2 on a model sulfate-reducing microorganism, Desulfovibrio vulgaris, have been assessed using a suite of genomic and kinetic measurements. Novel high-pressure NMR time-series measurements using 13C-lactate were used to track D. vulgaris metabolism. We identified cessation of respiration at CO2 pressures of 10 bar, 25 bar, 50 bar, and 80 bar. Concurrent experiments using N2 as the pressurizing phase had no negative effect on microbial respiration, as inferred from reduction of sulfate to sulfide. Complementary pressurized batch incubations and fluorescence microscopy measurements supported NMR observations, and indicated that non-respiring cells were mostly viable at 50 bar CO2 for at least four hours, and at 80 bar CO2 for two hours. The fraction of dead cells increased rapidly after four hours at 80 bar CO2. Transcriptomic (RNA-Seq) measurements on mRNA transcripts from CO2-incubated biomass indicated that cells up-regulated the production of certain amino acids (leucine, isoleucine) following CO2 exposure at elevated pressures, likely as part of a general stress response. Evidence for other poorly understood stress responses were also identified within RNA-Seq data, suggesting that while pressurized CO2 severely limits the growth and respiration of D. vulgaris cells, biomass retains intact cell membranes at pressures up to 80 bar CO2. Together, these data show that geologic sequestration of CO2 may have significant impacts on rates of sulfate reduction in many deep subsurface environments where this metabolism is a key respiratory process.

Wilkins, Michael J.; Hoyt, David W.; Marshall, Matthew J.; Alderson, Paul A.; Plymale, Andrew E.; Markillie, Lye Meng; Tucker, Abigail E.; Walter, Eric D.; Linggi, Bryan E.; Dohnalkova, Alice; Taylor, Ronald C.

2014-09-01T23:59:59.000Z

53

A model comparison initiative for a CO2 injection field test: An introduction to Sim-SEQ  

E-Print Network [OSTI]

in the water leg of a CO 2 -EOR field with a strong waterwater leg of an active CO 2 -EOR field with a strong waterthe presence of an active EOR operation nearby may also

Mukhopadhyay, S.

2013-01-01T23:59:59.000Z

54

Modeling the resolution of inexpensive, novel non-seismic geophysical monitoring tools to monitor CO2 injection into coal beds  

E-Print Network [OSTI]

of enhanced oil recovery (EOR) projects showed them to bestudy of proposed CO 2 EOR/sequestration of the SchraderAbbreviations CBM CO 2 Ex Ey EM EOR Im ?Gal NIST Re Rx S Tx

Gasperikova, E.

2010-01-01T23:59:59.000Z

55

Modeling the resolution of inexpensive, novel non-seismic geophysical monitoring tools to monitor CO2 injection into coal beds  

E-Print Network [OSTI]

Plasynski, S. , 2008, Advancing Coal-Based Power Generationto monitor CO 2 injection into Coal Beds as a part of theanalysis for CO 2 movement in coal beds was based on the

Gasperikova, E.

2010-01-01T23:59:59.000Z

56

Monitoring CO 2 sequestration into deep saline aquifer and associated salt intrusion using coupled multiphase flow modeling and time lapse electrical resistivity tomography  

SciTech Connect (OSTI)

Successful geological storage and sequestration of carbon dioxide (CO2) require efficient monitoring of the migration of CO2 plume during and after large-scale injection in order to verify the containment of the injected CO2 within the target formation and to evaluate potential leakage risk. Field studies have shown that surface and cross-borehole electrical resistivity tomography (ERT) can be a useful tool in imaging and characterizing solute transport in heterogeneous subsurface. In this synthetic study, we have coupled a 3-D multiphase flow model with a parallel 3-D time-lapse ERT inversion code to explore the feasibility of using time-lapse ERT for simultaneously monitoring the migration of CO2 plume in deep saline formation and potential brine intrusion into shallow fresh water aquifer. Direct comparisons of the inverted CO2 plumes resulting from ERT with multiphase flow simulation results indicate the ERT could be used to delineate the migration of CO2 plume. Detailed comparisons on the locations, sizes and shapes of CO2 plume and intruded brine plumes suggest that ERT inversion tends to underestimate the area review of the CO2 plume, but overestimate the thickness and total volume of the CO2 plume. The total volume of intruded brine plumes is overestimated as well. However, all discrepancies remain within reasonable ranges. Our study suggests that time-lapse ERT is a useful monitoring tool in characterizing the movement of injected CO2 into deep saline aquifer and detecting potential brine intrusion under large-scale field injection conditions.

Chuan Lu; CHI Zhang; Hai Hanag; Timothy C. Johnson

2014-04-01T23:59:59.000Z

57

Assessment of Energy Efficiency Improvement and CO2 Emission Reduction Potentials in India's Cement Industry  

E-Print Network [OSTI]

Model Inputs Emissions Factors CO2 Emission factor for grid tonne CO2/MWh)  CO2 Emission factor for fuel  (tonne CO2/TJ)Improvements and CO2 Emission Reduction Potentials in the

Morrow III, William R.

2014-01-01T23:59:59.000Z

58

ECONOMIC MODELING OF CO2 CAPTURE AND SEQUESTRATION Sean Biggs, Howard Herzog, John Reilly, Henry Jacoby  

E-Print Network [OSTI]

of carbon capture and sequestration technologies using the MIT Emissions Prediction and Policy Analysis (EPPA) model. We model two of the most promising carbon capture and sequestration technologies, one, technological, and social issues of carbon capture and sequestration technologies. In 1997, the President

59

Modeling the effects of topography and wind on atmospheric dispersion of CO2 surface leakage at geologic carbon sequestration sites  

E-Print Network [OSTI]

CO 2 from geologic carbon sequestration sites, Vadose Zoneleakage at geologic carbon sequestration sites Fotini K.assessment for geologic carbon sequestration sites. We have

Chow, Fotini K.

2009-01-01T23:59:59.000Z

60

Numerical Modeling Studies of The Dissolution-Diffusion-Convection ProcessDuring CO2 Storage in Saline Aquifers  

SciTech Connect (OSTI)

For purposes of geologic storage, CO2 would be injected into saline formations at supercritical temperature and pressure conditions, and would form a separate phase that is immiscible with the aqueous phase (brine). At typical subsurface temperature and pressure conditions, supercritical CO2 (scCO2) has lower density than the aqueous phase and would experience an upward buoyancy force. Accordingly, the CO2 is expected to accumulate beneath the caprock at the top of the permeable interval, and could escape from the storage formation wherever (sub-)vertical pathways are available, such as fractures or faults through the caprock, or improperly abandoned wells. Over time, an increasing fraction of CO2 may dissolve in the aqueous phase, and eventually some of the aqueous CO2 may react with rock minerals to form poorly soluble carbonates. Dissolution into the aqueous phase and eventual sequestration as carbonates are highly desirable processes as they would increase permanence and security of storage. Dissolution of CO2 will establish phase equilibrium locally between the overlying CO2 plume and the aqueous phase beneath. If the aqueous phase were immobile, CO2 dissolution would be limited by the rate at which molecular diffusion can remove dissolved CO2 from the interface between CO2-rich and aqueous phases. This is a slow process. However, dissolution of CO2 is accompanied by a small increase in the density of the aqueous phase, creating a negative buoyancy force that can give rise to downward convection of CO2-rich brine, which in turn can greatly accelerate CO2 dissolution. This study explores the process of dissolution-diffusion-convection (DDC), using high-resolution numerical simulation. We find that geometric features of convection patterns are very sensitive to small changes in problem specifications, reflecting self-enhancing feedbacks and the chaotic nature of the process. Total CO2 dissolution rates on the other hand are found to be quite robust against modest changes in problem parameters, and are essentially constant as long as no dissolved CO2 reaches the lower boundary of the system.

Pruess, Karsten; Zhang, Keni

2008-11-17T23:59:59.000Z

Note: This page contains sample records for the topic "ks modeling co2" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Integrated modeling of CO2 storage and leakage scenarios including transitions between super- and sub-critical conditions, and phase change between liquid and gaseous CO2  

SciTech Connect (OSTI)

Storage of CO{sub 2} in saline aquifers is intended to be at supercritical pressure and temperature conditions, but CO{sub 2} leaking from a geologic storage reservoir and migrating toward the land surface (through faults, fractures, or improperly abandoned wells) would reach subcritical conditions at depths shallower than 500-750 m. At these and shallower depths, subcritical CO{sub 2} can form two-phase mixtures of liquid and gaseous CO{sub 2}, with significant latent heat effects during boiling and condensation. Additional strongly non-isothermal effects can arise from decompression of gas-like subcritical CO{sub 2}, the so-called Joule-Thomson effect. Integrated modeling of CO{sub 2} storage and leakage requires the ability to model non-isothermal flows of brine and CO{sub 2} at conditions that range from supercritical to subcritical, including three-phase flow of aqueous phase, and both liquid and gaseous CO{sub 2}. In this paper, we describe and demonstrate comprehensive simulation capabilities that can cope with all possible phase conditions in brine-CO{sub 2} systems. Our model formulation includes: (1) an accurate description of thermophysical properties of aqueous and CO{sub 2}-rich phases as functions of temperature, pressure, salinity and CO{sub 2} content, including the mutual dissolution of CO{sub 2} and H{sub 2}O; (2) transitions between super- and subcritical conditions, including phase change between liquid and gaseous CO{sub 2}; (3) one-, two-, and three-phase flow of brine-CO{sub 2} mixtures, including heat flow; (4) non-isothermal effects associated with phase change, mutual dissolution of CO{sub 2} and water, and (de-) compression effects; and (5) the effects of dissolved NaCl, and the possibility of precipitating solid halite, with associated porosity and permeability change. Applications to specific leakage scenarios demonstrate that the peculiar thermophysical properties of CO{sub 2} provide a potential for positive as well as negative feedbacks on leakage rates, with a combination of self-enhancing and self-limiting effects. Lower viscosity and density of CO{sub 2} as compared to aqueous fluids provides a potential for self-enhancing effects during leakage, while strong cooling effects from liquid CO{sub 2} boiling into gas, and from expansion of gas rising towards the land surface, act to self-limit discharges. Strong interference between fluid phases under three-phase conditions (aqueous - liquid CO{sub 2} - gaseous CO{sub 2}) also tends to reduce CO{sub 2} fluxes. Feedback on different space and time scales can induce non-monotonic behavior of CO{sub 2} flow rates.

Pruess, K.

2011-05-15T23:59:59.000Z

62

A Statistical Model to Assess Indirect CO2 Emissions of the UAE Residential Sector  

E-Print Network [OSTI]

. Determination of household energy using ?fingerprints? from energy billing data. Energy Research 10(4), pp: 393?405. [5] Snakin JPA, 2000. An engineering model for heating energy and emission assessment The case of North Karelia, Finland. Applied Energy...

Radhi, H.; Fikry, F.

2010-01-01T23:59:59.000Z

63

Integrated Reflection Seismic Monitoring and Reservoir Modeling for Geologic CO2 Sequestration  

SciTech Connect (OSTI)

The US DOE/NETL CCS MVA program funded a project with Fusion Petroleum Technologies Inc. (now SIGMA) to model the proof of concept of using sparse seismic data in the monitoring of CO{sub 2} injected into saline aquifers. The goal of the project was to develop and demonstrate an active source reflection seismic imaging strategy based on deployment of spatially sparse surface seismic arrays. The primary objective was to test the feasibility of sparse seismic array systems to monitor the CO{sub 2} plume migration injected into deep saline aquifers. The USDOE/RMOTC Teapot Dome (Wyoming) 3D seismic and reservoir data targeting the Crow Mountain formation was used as a realistic proxy to evaluate the feasibility of the proposed methodology. Though the RMOTC field has been well studied, the Crow Mountain as a saline aquifer has not been studied previously as a CO{sub 2} sequestration (storage) candidate reservoir. A full reprocessing of the seismic data from field tapes that included prestack time migration (PSTM) followed by prestack depth migration (PSDM) was performed. A baseline reservoir model was generated from the new imaging results that characterized the faults and horizon surfaces of the Crow Mountain reservoir. The 3D interpretation was integrated with the petrophysical data from available wells and incorporated into a geocellular model. The reservoir structure used in the geocellular model was developed using advanced inversion technologies including Fusion's ThinMAN{trademark} broadband spectral inversion. Seal failure risk was assessed using Fusion's proprietary GEOPRESS{trademark} pore pressure and fracture pressure prediction technology. CO{sub 2} injection was simulated into the Crow Mountain with a commercial reservoir simulator. Approximately 1.2MM tons of CO{sub 2} was simulated to be injected into the Crow Mountain reservoir over 30 years and subsequently let 'soak' in the reservoir for 970 years. The relatively small plume developed from this injection was observed migrating due to gravity to the apexes of the double anticline in the Crow Mountain reservoir of the Teapot dome. Four models were generated from the reservoir simulation task of the project which included three saturation models representing snapshots at different times during and after simulated CO{sub 2} injection and a fully saturated CO{sub 2} fluid substitution model. The saturation models were used along with a Gassmann fluid substitution model for CO{sub 2} to perform fluid volumetric substitution in the Crow Mountain formation. The fluid substitution resulted in a velocity and density model for the 3D volume at each saturation condition that was used to generate a synthetic seismic survey. FPTI's (Fusion Petroleum Technologies Inc.) proprietary SeisModelPRO{trademark} full acoustic wave equation software was used to simulate acquisition of a 3D seismic survey on the four models over a subset of the field area. The simulated acquisition area included the injection wells and the majority of the simulated plume area.

John Rogers

2011-12-31T23:59:59.000Z

64

A Simplified 1-D Model for Calculating CO2 Leakage through Conduits  

SciTech Connect (OSTI)

In geological CO{sub 2} storage projects, a cap rock is generally needed to prevent CO{sub 2} from leaking out of the storage formation. However, the injected CO{sub 2} may still encounter some discrete flow paths such as a conductive well or fault (here referred to as conduits) through the cap rock allowing escape of CO{sub 2} from the storage formation. As CO{sub 2} migrates upward, it may migrate into the surrounding formations. The amount of mass that is lost to the formation is called attenuation. This report describes a simplified model to calculate the CO{sub 2} mass flux at different locations of the conduit and the amount of attenuation to the surrounding formations. From the comparison among the three model results, we can conclude that the steady-state conduit model (SSCM) provides a more accurate solution than the PMC at a given discretization. When there is not a large difference between the permeability of the surrounding formation and the permeability of the conduits, and there is leak-off at the bottom formation (the formation immediately above the CO{sub 2} plume), a fine discretization is needed for an accurate solution. Based on this comparison, we propose to use the SSCM in the rapid prototype for now given it does not produce spurious oscillations, and is already in FORTRAN and therefore can be easily made into a dll for use in GoldSim.

Zhang, Y.; Oldenburg, C.M.

2011-02-15T23:59:59.000Z

65

TWO-DIMENSIONAL REACTIVE TRANSPORT MODELING OF CO2 INJECTION IN A SALINE AQUIFER AT THE SLEIPNER SITE  

E-Print Network [OSTI]

systems are under consideration for CO2 storage in the subsurface (Holloway, 1997), (i) depleted oil or gas reservoirs, (ii) unmineable coal beds and (iii) saline aquifers. Deep saline aquifers offer) dissolution trapping, which represents CO2 dissolved in the liquid phase (oil or brine), and (iii) mineral

Boyer, Edmond

66

Three-phase compositional modeling of CO2 injection by higher-order finite element methods with CPA equation  

E-Print Network [OSTI]

and gravitational fingering that can negatively affect hydrocarbon (HC) recovery, or aid carbon sequestration and other simulators. The examples consider gravitational fingering during CO2 sequestration in aquifers could have a significant impact on CO2 sequestration and IOR. Accurate simulation of compositional

Firoozabadi, Abbas

67

Final report on "Modeling Diurnal Variations of California Land Biosphere CO2 Fluxes"  

SciTech Connect (OSTI)

In Mediterranean climates, the season of water availability (winter) is out of phase with the season of light availability and atmospheric demand for moisture (summer). Multi-year half-hourly observations of sap flow velocities in 26 evergreen trees in a small watershed in Northern California show that different species of evergreen trees have different seasonalities of transpiration: Douglas-firs respond immediately to the first winter rain, while Pacific madrones have peak transpiration in the dry summer. Using these observations, we have derived species-specific parameterization of normalized sap flow velocities in terms of insolation, vapor pressure deficit and near-surface soil moisture. A simple 1-D boundary layer model showed that afternoon temperatures may be higher by 1 degree Celsius in an area with Douglas-firs than with Pacific madrones. The results point to the need to develop a new representation of subsurface moisture, in particular pools beneath the organic soil mantle and the vadose zone. Our ongoing and future work includes coupling our new parameterization of transpiration with new representation of sub-surface moisture in saprolite and weathered bedrock. The results will be implemented in a regional climate model to explore vegetation-climate feedbacks, especially in the dry season.

Fung, Inez

2014-07-28T23:59:59.000Z

68

Modeling Studies on the Transport of Benzene and H2S in CO2-Water Systems  

SciTech Connect (OSTI)

In this study, reactive transport simulations were used to assess the mobilization and transport of organics with supercritical CO{sub 2} (SCC), and the co-injection and transport of H{sub 2}S with SCC. These processes were evaluated at conditions of typical storage reservoirs, and for cases of hypothetical leakage from a reservoir to an overlying shallower fresh water aquifer. Modeling capabilities were developed to allow the simulation of multiphase flow and transport of H{sub 2}O, CO{sub 2}, H{sub 2}S, as well as specific organic compounds (benzene), coupled with multicomponent geochemical reaction and transport. This included the development of a new simulator, TMVOC-REACT, starting from existing modules of the TOUGH2 family of codes. This work also included an extensive literature review, calculation, and testing of phase-partitioning properties for mixtures of the phases considered. The reactive transport simulations presented in this report are primarily intended to illustrate the capabilities of the new simulator. They are also intended to help evaluate and understand various processes at play, in a more qualitative than quantitative manner, and only for hypothetical scenarios. Therefore, model results are not intended as realistic assessments of groundwater quality changes for specific locations, and they certainly do not provide an exhaustive evaluation of all possible site conditions, especially given the large variability and uncertainty in hydrogeologic and geochemical parameter input into simulations. The first step in evaluating the potential mobilization and transport of organics was the identification of compounds likely to be present in deep storage formations, and likely to negatively impact freshwater aquifers if mobilized by SCC. On the basis of a literature review related to the occurrence of these organic compounds, their solubility in water and SCC, and their toxicity (as reflected by their maximum contaminant levels MCL), benzene was selected as a key compound for inclusion into numerical simulations. Note that considering additional organic compounds and/or mixtures of such compounds in the simulations was beyond the scope of this study, because of the effort required to research, calculate, and validate the phase-partitioning data necessary for simulations. The injection of CO{sub 2} into a deep saline aquifer was simulated, followed by modeling the leaching of benzene by SCC and transport of benzene to an overlying aquifer along a hypothetical leakage pathway. One- and two-dimensional models were set up for this purpose. The target storage formation was assumed to initially contain about 10{sup -4} ppm benzene. Model results indicate that: (1) SCC efficiently extracts benzene from the storage formation. (2) Assuming equilibrium, the content of benzene in SCC is roportional to the concentration of benzene in the aqueous and solid phases. (3) Benzene may co-migrate with CO{sub 2} into overlying aquifers if a leakage pathway is present. Because the aqueous solubility of benzene in contact with CO{sub 2} is lower than the aqueous solubility of CO{sub 2}, benzene is actually enriched in the CO{sub 2} phase as the plume advances. (4) For the case studied here, the resulting aqueous benzene concentration in the overlying aquifer is on the same order of magnitude as the initial concentration in the storage formation. This generic modeling study illustrates, in a semi-quantitative manner, the possible mobilization of benzene by SCC. The extent to which the mobilization of this organic compound evolves temporally and spatially depends on a large number of controlling parameters and is largely site specific. Therefore, for more 'truly' predictive work, further sensitivity studies should be conducted, and further modeling should be integrated with site-specific laboratory and/or field experimental data. The co-injection of H{sub 2}S with CO{sub 2} into a deep saline aquifer was also simulated. In addition, the model considered leakage of the supercritical CO{sub 2}+H{sub 2}S mixture along a preferential p

Zheng, L.; Spycher, N.; Xu, T.; Apps, J.; Kharaka, Y.; Birkholzer, J.T.

2010-11-05T23:59:59.000Z

69

Modeling Gas Transport in the Shallow Subsurface During the ZERT CO2 Release Test  

SciTech Connect (OSTI)

We used the multiphase and multicomponent TOUGH2/EOS7CA model to carry out predictive simulations of CO{sub 2} injection into the shallow subsurface of an agricultural field in Bozeman, Montana. The purpose of the simulations was to inform the choice of CO{sub 2} injection rate and design of monitoring and detection activities for a CO{sub 2} release experiment. The release experiment configuration consists of a long horizontal well (70 m) installed at a depth of approximately 2.5 m into which CO{sub 2} is injected to mimic leakage from a geologic carbon sequestration site through a linear feature such as a fault. We estimated the permeability of the soil and cobble layers present at the site by manual inversion of measurements of soil CO{sub 2} flux from a vertical-well CO{sub 2} release. Based on these estimated permeability values, predictive simulations for the horizontal well showed that CO{sub 2} injection just below the water table creates an effective gas-flow pathway through the saturated zone up to the unsaturated zone. Once in the unsaturated zone, CO{sub 2} spreads out laterally within the cobble layer, where liquid saturation is relatively low. CO{sub 2} also migrates upward into the soil layer through the capillary barrier and seeps out at the ground surface. The simulations predicted a breakthrough time of approximately two days for the 100kg d{sup -1} injection rate, which also produced a flux within the range desired for testing detection and monitoring approaches. The seepage area produced by the model was approximately five meters wide above the horizontal well, compatible with the detection and monitoring methods tested. For a given flow rate, gas-phase diffusion of CO{sub 2} tends to dominate over advection near the ground surface, where the CO{sub 2} concentration gradient is large, while advection dominates deeper in the system.

Oldenburg, Curtis M.; Lewicki, Jennifer L.; Dobeck, Laura; Spangler, Lee

2009-01-15T23:59:59.000Z

70

West Pearl Queen CO2 sequestration pilot test and modeling project 2006-2008.  

SciTech Connect (OSTI)

The West Pearl Queen is a depleted oil reservoir that has produced approximately 250,000 bbl of oil since 1984. Production had slowed prior to CO{sub 2} injection, but no previous secondary or tertiary recovery methods had been applied. The initial project involved reservoir characterization and field response to injection of CO{sub 2}; the field experiment consisted of injection, soak, and venting. For fifty days (December 20, 2002, to February 11, 2003) 2090 tons of CO{sub 2} were injected into the Shattuck Sandstone Member of the Queen Formation at the West Pearl Queen site. This technical report highlights the test results of the numerous research participants and technical areas from 2006-2008. This work included determination of lateral extents of the permeability units using outcrop observations, core results, and well logs. Pre- and post-injection 3D seismic data were acquired. To aid in interpreting seismic data, we performed numerical simulations of the effects of CO{sub 2} replacement of brine where the reservoir model was based upon correlation lengths established by the permeability studies. These numerical simulations are not intended to replicate field data, but to provide insight of the effects of CO{sub 2}.

Engler, Bruce Phillip; Cooper, Scott Patrick; Symons, Neill Phillip; Bartel, Lewis Clark; Byrer, Charles (National Energy Laboratory, Morgantown, WV); Elbring, Gregory Jay; McNemar, Andrea (National Energy Laboratory, Morgantown, WV); Aldridge, David Franklin; Lorenz, John Clay

2008-08-01T23:59:59.000Z

71

Evaluating Potential for Large Releases from CO2 StorageReservoirs: Analogs, Scenarios, and Modeling Needs  

SciTech Connect (OSTI)

While the purpose of geologic storage of CO{sub 2} in deep saline formations is to trap greenhouse gases underground, the potential exists for CO{sub 2} to escape from the target reservoir, migrate upward along permeable pathways, and discharge at the land surface. Such discharge is not necessarily a serious concern, as CO{sub 2} is a naturally abundant and relatively benign gas in low concentrations. However, there is a potential risk to health, safety and environment (HSE) in the event that large localized fluxes of CO{sub 2} were to occur at the land surface, especially where CO{sub 2} could accumulate. In this paper, we develop possible scenarios for large CO{sub 2} fluxes based on the analysis of natural analogues, where large releases of gas have been observed. We are particularly interested in scenarios which could generate sudden, possibly self-enhancing, or even eruptive release events. The probability for such events may be low, but the circumstances under which they might occur and potential consequences need to be evaluated in order to design appropriate site selection and risk management strategies. Numerical modeling of hypothetical test cases is needed to determine critical conditions for such events, to evaluate whether such conditions may be possible at designated storage sites, and, if applicable, to evaluate the potential HSE impacts of such events and design appropriate mitigation strategies.

Birkholzer, Jens; Pruess, Karsten; Lewicki, Jennifer; Tsang,Chin-Fu; Karimjee, Anhar

2005-09-19T23:59:59.000Z

72

International Symposium on Site Characterization for CO2 Geological Storage  

E-Print Network [OSTI]

CONSTRAIN CO2 INJECTION FEASIBILITY: TEAPOT DOME EOR PILOTEOR, and coupled process modeling will investigate the total system including preliminary estimates of CO2

Tsang, Chin-Fu

2006-01-01T23:59:59.000Z

73

Synthesis and Evaluation of CO2 Thickeners Designed with Molecular Modeling  

SciTech Connect (OSTI)

The objective of this research was to use molecular modeling techniques, coupled with our prior experimental results, to design, synthesize and evaluate inexpensive, non-fluorous carbon dioxide thickening agents. The first type of thickener that was considered was associating polymers. Typically, these thickeners are copolymers that contain a highly CO{sub 2}-philic monomer, and a small concentration of a CO{sub 2}-phobic associating monomer. Yale University was solely responsible for the synthesis of a second type of thickener; small, hydrogen bonding compounds. These molecules have a core that contains one or more hydrogen-bonding groups, such as urea or amide groups. Non-fluorous, CO{sub 2}-philic functional groups were attached to the hydrogen bonding core of the compound to impart CO{sub 2} stability and macromolecular stability to the linear 'stack' of these compounds. The third type of compound initially considered for this investigation was CO{sub 2}-soluble surfactants. These surfactants contain conventional ionic head groups and composed of CO{sub 2}-philic oligomers (short polymers) or small compounds (sugar acetates) previously identified by our research team. Mobility reduction could occur as these surfactant solutions contacted reservoir brine and formed mobility control foams in-situ. The vast majority of the work conducted in this study was devoted to the copolymeric thickeners and the small hydrogen-bonding thickeners; these thickeners were intended to dissolve completely in CO{sub 2} and increase the fluid viscosity. A small but important amount of work was done establishing the groundwork for CO{sub 2}-soluble surfactants that reduced mobility by generating foams in-situ as the CO{sub 2}+surfactant solution mixed with in-situ brine.

Robert Enick; Erick Beckman; J. Karl Johnson

2009-08-31T23:59:59.000Z

74

Modeling basin- and plume-scale processes of CO2 storage for full-scale deployment  

SciTech Connect (OSTI)

Integrated modeling of basin- and plume-scale processes induced by full-scale deployment of CO{sub 2} storage was applied to the Mt. Simon Aquifer in the Illinois Basin. A three-dimensional mesh was generated with local refinement around 20 injection sites, with approximately 30 km spacing. A total annual injection rate of 100 Mt CO{sub 2} over 50 years was used. The CO{sub 2}-brine flow at the plume scale and the single-phase flow at the basin scale were simulated. Simulation results show the overall shape of a CO{sub 2} plume consisting of a typical gravity-override subplume in the bottom injection zone of high injectivity and a pyramid-shaped subplume in the overlying multilayered Mt. Simon, indicating the important role of a secondary seal with relatively low-permeability and high-entry capillary pressure. The secondary-seal effect is manifested by retarded upward CO{sub 2} migration as a result of multiple secondary seals, coupled with lateral preferential CO{sub 2} viscous fingering through high-permeability layers. The plume width varies from 9.0 to 13.5 km at 200 years, indicating the slow CO{sub 2} migration and no plume interference between storage sites. On the basin scale, pressure perturbations propagate quickly away from injection centers, interfere after less than 1 year, and eventually reach basin margins. The simulated pressure buildup of 35 bar in the injection area is not expected to affect caprock geomechanical integrity. Moderate pressure buildup is observed in Mt. Simon in northern Illinois. However, its impact on groundwater resources is less than the hydraulic drawdown induced by long-term extensive pumping from overlying freshwater aquifers.

Zhou, Q.; Birkholzer, J.T.; Mehnert, E.; Lin, Y.-F.; Zhang, K.

2009-08-15T23:59:59.000Z

75

Pore-scale simulation of liquid CO2 displacement of water using a two-phase lattice Boltzmann model  

SciTech Connect (OSTI)

A lattice Boltzmann color-fluid model, which was recently proposed by Liu et al. [H. Liu, A.J. Valocchi, and Q. Kang. Three-dimensional lattice Boltzmann model for immiscible two-phase flow simulations. Phys. Rev. E, 85:046309, 2012.] based on a concept of continuum surface force, is improved to simulate immiscible two-phase flows in porous media. The new improvements allow the model to account for different kinematic viscosities of both fluids and to model fluid-solid interactions. The capability and accuracy of this model is first validated by two benchmark tests: a layered two-phase flow with a viscosity ratio, and a dynamic capillary intrusion. This model is then used to simulate liquid CO2 (LCO2) displacing water in a dual-permeability pore network. The extent and behavior of LCO2 preferential flow (i.e., fingering) is found to depend on the capillary number (Ca), and three different displacement patterns observed in previous micromodel experiments are reproduced. The predicted variation of LCO2 saturation with Ca, as well as variation of specific interfacial length with LCO2 saturation, are both in good agreement with the experimental observations. To understand the effect of heterogeneity on pore-scale displacement, we also simulate LCO2 displacing water in a randomly heterogeneous pore network, which has the same size and porosity as the dual-permeability pore network. In comparison to the dual-permeability case, the transition from capillary fingering to viscous fingering occurs at a higher Ca, and LCO2 saturation is higher at low Ca but lower at high Ca. In either pore network, the LCO2-water specific interfacial length is found to obey a power-law dependence on LCO2 saturation.

Liu, Haihu; Valocchi, Albert J.; Werth, Charles J.; Kang, Oinjun; Oostrom, Martinus

2014-11-01T23:59:59.000Z

76

A Model of Transient Thermal Transport Phenomena Applied to the Carbonation and Calcination of a Sorbent Particle for Calcium Oxide Looping CO2 Capture  

E-Print Network [OSTI]

looping is selected as the model cycle because of its suitability for solar-driven carbon dioxide captureA Model of Transient Thermal Transport Phenomena Applied to the Carbonation and Calcination of a Sorbent Particle for Calcium Oxide Looping CO2 Capture Lindsey Yue and Wojciech Lipi´nski, The Australian

77

EMSL - CO2 sequestration  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

co2-sequestration en Low-Temperature Carbon Monoxide Oxidation Catalysed by Regenerable Atomically Dispersed Palladium on Alumina. http:www.emsl.pnl.govemslwebpublications...

78

Modeled Interactive Effects of Precipitation, temperature, and [CO2] on Ecosystem Carbon and Water Dynamics in Different Climatic Zones  

SciTech Connect (OSTI)

Interactive effects of multiple global change factors on ecosystem processes are complex. It is relatively expensive to explore those interactions in manipulative experiments. We conducted a modeling analysis to identify potentially important interactions and to stimulate hypothesis formulation for experimental research. Four models were used to quantify interactive effects of climate warming (T), altered precipitation amounts [doubled (DP) and halved (HP)] and seasonality (SP, moving precipitation in July and August to January and February to create summer drought), and elevated [CO2] (C) on net primary production (NPP), heterotrophic respiration (Rh), net ecosystem production (NEP), transpiration, and runoff.We examined those responses in seven ecosystems, including forests, grasslands, and heathlands in different climate zones. The modeling analysis showed that none of the threeway interactions among T, C, and altered precipitation was substantial for either carbon or water processes, nor consistent among the seven ecosystems. However, two-way interactive effects on NPP, Rh, and NEP were generally positive (i.e. amplification of one factor s effect by the other factor) between T and C or between T and DP. A negative interaction (i.e. depression of one factor s effect by the other factor) occurred for simulated NPP between T and HP. The interactive effects on runoff were positive between T and HP. Four pairs of two-way interactive effects on plant transpiration were positive and two pairs negative. In addition, wet sites generally had smaller relative changes in NPP, Rh, runoff, and transpiration but larger absolute changes in NEP than dry sites in response to the treatments. The modeling results suggest new hypotheses to be tested in multifactor global change experiments. Likewise, more experimental evidence is needed for the further improvement of ecosystem models in order to adequately simulate complex interactive processes.

Luo, Yiqi [University of Oklahoma; Gerten, Dieter [Potsdam Institute for Climate Impact Research, Potsdam, Germany; Le Maire, Guerric [Laboratoire des Sciences du Climat et de l'Environement, France; Parton, William [University of Colorado, Fort Collins; Weng, Ensheng [University of Oklahoma, Norman; Zhou, Xuhuui [University of Oklahoma; Keough, Cindy [University of Colorado, Fort Collins; Beier, Claus [Riso National Laboratory, Roskilde, Denmark; Ciais, Philippe [Laboratoire des Sciences du Climat et de l'Environement, France; Cramer, Wolfgang [Potsdam Institute for Climate Impact Research, Potsdam, Germany; Dukes, Jeff [University of Massachusetts, Boston; Emmett, Bridget [Centre for Ecology and Hydrology, Bangor, Gwynedd, United Kingdom; Hanson, Paul J [ORNL; Knapp, Alan [Colorado State University, Fort Collins; Linder, Sune [Swedish University of Agricultural Sciences, Upsalla, Sweden; Nepstad, Daniel [Woods Hole Oceanographic Institution (WHOI), Woods Hole, MA; Rustad, Lindsey [USDA Forest Service

2008-01-01T23:59:59.000Z

79

A Conceptual Model of H2O/CO2 Frost Sublimation and Condensation Caused Albedo Change in Crater Interiors, Martian Seasonal Polar Cap Regions H. Xie1  

E-Print Network [OSTI]

A Conceptual Model of H2O/CO2 Frost Sublimation and Condensation Caused Albedo Change in Crater.Xie@utsa.edu; 2 School of Chemistry, Physics and Earth Sciences, Flinders University, Australia; 3 Research Center are a major element of the current Mars' climate and circulation. Understanding the sublimation

Texas at San Antonio, University of

80

MODELING, IDENTIFICATION AND CONTROL, 2006, VOL. 00, NO. 0, 000000 Control Design for a Gas Turbine Cycle with CO2 Capture  

E-Print Network [OSTI]

MODELING, IDENTIFICATION AND CONTROL, 2006, VOL. 00, NO. 0, 000­000 Control Design for a Gas capture The semi-closed oxy-fuel gas turbine cycle has been suggested in (Ulizar and Pilidis, 1997 in Section 2), is based on concept (c) above. The exhaust gas from a gas turbine with CO2 as working fluid

Foss, Bjarne A.

Note: This page contains sample records for the topic "ks modeling co2" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

meters in CO2 euthanasia chambers. All CO2 euthanasia chambers in both  

E-Print Network [OSTI]

meters in CO2 euthanasia chambers. All CO2 euthanasia chambers in both the facilities and laboratories will need flow meters. ULAR is currently in the process of identifying a cost-effective, accurate, and durable flow meter to install in all of the CO2 chambers in all of the vivaria. When a specific model

Bushman, Frederic

82

Comprehensive ecosystem model-experiment synthesis using multiple datasets at two temperate forest free-air CO2 enrichment experiments: model performance and compensating biases  

SciTech Connect (OSTI)

Free Air CO2 Enrichment (FACE) experiments provide a remarkable wealth of data to test the sensitivities of terrestrial ecosystem models (TEMs). In this study, a broad set of 11 TEMs were compared to 22 years of data from two contrasting FACE experiments in temperate forests of the south eastern US the evergreen Duke Forest and the deciduous Oak Ridge forest. We evaluated the models' ability to reproduce observed net primary productivity (NPP), transpiration and Leaf Area index (LAI) in ambient CO2 treatments. Encouragingly, many models simulated annual NPP and transpiration within observed uncertainty. Daily transpiration model errors were often related to errors in leaf area phenology and peak LAI. Our analysis demonstrates that the simulation of LAI often drives the simulation of transpiration and hence there is a need to adopt the most appropriate of hypothesis driven methods to simulate and predict LAI. Of the three competing hypotheses determining peak LAI (1) optimisation to maximise carbon export, (2) increasing SLA with canopy depth and (3) the pipe model the pipe model produced LAI closest to the observations. Modelled phenology was either prescribed or based on broader empirical calibrations to climate. In some cases, simulation accuracy was achieved through compensating biases in component variables. For example, NPP accuracy was sometimes achieved with counter-balancing biases in nitrogen use efficiency and nitrogen uptake. Combined analysis of parallel measurements aides the identification of offsetting biases; without which over-confidence in model abilities to predict ecosystem function may emerge, potentially leading to erroneous predictions of change under future climates.

Walker, Anthony P [ORNL] [ORNL; Hanson, Paul J [ORNL] [ORNL; DeKauwe, Martin G [Macquarie University] [Macquarie University; Medlyn, Belinda [Macquarie University] [Macquarie University; Zaehle, S [Max Planck Institute for Biogeochemistry] [Max Planck Institute for Biogeochemistry; Asao, Shinichi [Colorado State University, Fort Collins] [Colorado State University, Fort Collins; Dietze, Michael [University of Illinois, Urbana-Champaign] [University of Illinois, Urbana-Champaign; Hickler, Thomas [Goethe University, Frankfurt, Germany] [Goethe University, Frankfurt, Germany; Huntinford, Chris [Centre for Ecology and Hydrology, Wallingford, United Kingdom] [Centre for Ecology and Hydrology, Wallingford, United Kingdom; Iversen, Colleen M [ORNL] [ORNL; Jain, Atul [University of Illinois, Urbana-Champaign] [University of Illinois, Urbana-Champaign; Lomas, Mark [University of Sheffield] [University of Sheffield; Luo, Yiqi [University of Oklahoma] [University of Oklahoma; McCarthy, Heather R [Duke University] [Duke University; Parton, William [Colorado State University, Fort Collins] [Colorado State University, Fort Collins; Prentice, I. Collin [Macquarie University] [Macquarie University; Thornton, Peter E [ORNL] [ORNL; Wang, Shusen [Canada Centre for Remote Sensing (CCRS)] [Canada Centre for Remote Sensing (CCRS); Wang, Yingping [CSIRO Marine and Atmospheric Research] [CSIRO Marine and Atmospheric Research; Warlind, David [Lund University, Sweden] [Lund University, Sweden; Weng, Ensheng [University of Oklahoma, Norman] [University of Oklahoma, Norman; Warren, Jeffrey [ORNL] [ORNL; Woodward, F. Ian [University of Sheffield] [University of Sheffield; Oren, Ram [Duke University] [Duke University; Norby, Richard J [ORNL] [ORNL

2014-01-01T23:59:59.000Z

83

Research project on CO2 geological storage and groundwaterresources: Large-scale hydrological evaluation and modeling of impact ongroundwater systems  

SciTech Connect (OSTI)

If carbon dioxide capture and storage (CCS) technologies areimplemented on a large scale, the amounts of CO2 injected and sequesteredunderground could be extremely large. The stored CO2 then replaces largevolumes of native brine, which can cause considerable pressureperturbation and brine migration in the deep saline formations. Ifhydraulically communicating, either directly via updipping formations orthrough interlayer pathways such as faults or imperfect seals, theseperturbations may impact shallow groundwater or even surface waterresources used for domestic or commercial water supply. Possibleenvironmental concerns include changes in pressure and water table,changes in discharge and recharge zones, as well as changes in waterquality. In compartmentalized formations, issues related to large-scalepressure buildup and brine displacement may also cause storage capacityproblems, because significant pressure buildup can be produced. Toaddress these issues, a three-year research project was initiated inOctober 2006, the first part of which is summarized in this annualreport.

Birkholzer, Jens; Zhou, Quanlin; Rutqvist, Jonny; Jordan,Preston; Zhang,K.; Tsang, Chin-Fu

2007-10-24T23:59:59.000Z

84

Incompatible Statistics and Bell-KS Theorem  

E-Print Network [OSTI]

We analyze a possible loophole to the conclusion of the Bell-KS theorem that quantum mechanics is not compatible with any realistic and noncontextual or local theory. We emphasize that the models discarded by Bell-KS-like arguments possess a property not shared by quantum mechanics, i.e. the capability to make non-trivial statements about the joint statistics of quantum incompatible observables. By ruling out this possibility, apparently nothing seems to prevent from a realistic, noncontextual or local view of quantum mechanics.

Ángel Rivas

2015-01-20T23:59:59.000Z

85

Methanol Synthesis from CO2 Hydrogenation over a Pd4/In2O3 Model Catalyst: A Combined DFT and Kinetic Study  

SciTech Connect (OSTI)

Methanol synthesis from CO2 hydrogenation on Pd4/In2O3 has been investigated using density functional theory (DFT) and microkinetic modeling. In this study, three possible routes in the reaction network of CO2 + H2 ? CH3OH + H2O have been examined. Our DFT results show that the HCOO route competes with the RWGS route whereas a high activation barrier kinetically blocks the HCOOH route. DFT results also suggest that H2COO* + H* ? H2CO* +OH* and cis-COOH* + H* ?CO* + H2O* are the rate limiting steps in the HCOO route and the RWGS route, respectively. Microkinetic modeling results demonstrate that the HCOO route is the dominant reaction route for methanol synthesis from CO2 hydrogenation. We found that the activation of H adatom on the small Pd cluster and the presence of H2O on the In2O3 substrate play important roles in promoting the methanol synthesis. The hydroxyl adsorbed at the interface of Pd4/In2O3 induces the transformation of the supported Pd4 cluster from a butterfly structure into a tetrahedron structure. This important structure change not only indicates the dynamical nature of the supported nanoparticle catalyst structure during the reaction but also shifts the final hydrogenation step from H2COH to CH3O.

Ye, Jingyun; Liu, Changjun; Mei, Donghai; Ge, Qingfeng

2014-08-01T23:59:59.000Z

86

Laboratory H2O:CO2 ice desorption data: entrapment dependencies and its parameterization with an extended three-phase model  

E-Print Network [OSTI]

Ice desorption affects the evolution of the gas-phase chemistry during the protostellar stage, and also determines the chemical composition of comets forming in circumstellar disks. From observations, most volatile species are found in H2O-dominated ices. The aim of this study is first to experimentally determine how entrapment of volatiles in H2O ice depends on ice thickness, mixture ratio and heating rate, and second, to introduce an extended three-phase model (gas, ice surface and ice mantle) to describe ice mixture desorption with a minimum number of free parameters. Thermal H2O:CO2 ice desorption is investigated in temperature programmed desorption experiments of thin (10 - 40 ML) ice mixtures under ultra-high vacuum conditions. Desorption is simultaneously monitored by mass spectrometry and reflection-absorption infrared spectroscopy. The H2O:CO2 experiments are complemented with selected H2O:CO, and H2O:CO2:CO experiments. The results are modeled with rate equations that connect the gas, ice surface an...

Fayolle, Edith C; Cuppen, Herma M; Visser, Ruud; Linnartz, Harold; 10.1051/0004-6361/201016121

2011-01-01T23:59:59.000Z

87

CHARACTERIZATION OF MIXED CO2-TBPB HYDRATE FOR REFRIGERATION APPLICATIONS  

E-Print Network [OSTI]

in a dynamic loop and an Ostwald-de Waele model was obtained. Keywords: CO2, TBPB, mixed hydrates, solubility

Paris-Sud XI, Université de

88

electroseismic monitoring of co2 sequestration: a finite element ...  

E-Print Network [OSTI]

Keywords: Electroseismic Modeling, Poroelasticity, CO2 sequestration, Finite element methods. 2000 AMS ... carbon dioxide emissisons into the atmosphere.

Fabio Zyserman

89

amine methanol, ether . Amine amine CO2  

E-Print Network [OSTI]

, . promoter . 1.2 CO2 HBGS process CO2 , CO2 . CO2 , IGCC (Integrated Gasification Combined Cycle) (fuel gas) CO2 . IGCC CO2 H2 . (gasification) CO H2 (water gas shift reaction) H2 CO CO2 . CO2 H2 turbine H2 . H2 , CO2 #12;. fuel gas CO2 40%, 60% H2 . fuel gas (gasification) HBGS process . CO2 CO2 . venture

Hong, Deog Ki

90

Capturing CO2 via reactions in nanopores.  

SciTech Connect (OSTI)

This one-year exploratory LDRD aims to provide fundamental understanding of the mechanism of CO2 scrubbing platforms that will reduce green house gas emission and mitigate the effect of climate change. The project builds on the team member's expertise developed in previous LDRD projects to study the capture or preferential retention of CO2 in nanoporous membranes and on metal oxide surfaces. We apply Density Functional Theory and ab initio molecular dynamics techniques to model the binding of CO2 on MgO and CaO (100) surfaces and inside water-filled, amine group functionalized silica nanopores. The results elucidate the mechanisms of CO2 trapping and clarify some confusion in the literature. Our work identifies key future calculations that will have the greatest impact on CO2 capture technologies, and provides guidance to science-based design of platforms that can separate the green house gas CO2 from power plant exhaust or even from the atmosphere. Experimentally, we modify commercial MFI zeolite membranes and find that they preferentially transmit H2 over CO2 by a factor of 34. Since zeolite has potential catalytic capability to crack hydrocarbons into CO2 and H2, this finding paves the way for zeolite membranes that can convert biofuel into H2 and separate the products all in one step.

Leung, Kevin; Nenoff, Tina Maria; Criscenti, Louise Jacqueline; Tang, Z [University of Cincinnati; Dong, J. H. [University of Cincinnati

2008-10-01T23:59:59.000Z

91

A workflow for handling heterogeneous 3D models with the TOUGH2 family of codes: Applications to numerical modeling of CO2 geological storage  

E-Print Network [OSTI]

) is straightforward. Three examples are shown for validation: i) leakage of CO2 up through an abandoned well, ii) 3D of pilot sites for CCS. Extrapolation of laboratory results from core to reservoir scale can be done

Paris-Sud XI, Université de

92

Assessment of Energy Efficiency Improvement and CO2 Emission Reduction Potentials in India's Iron and Steel Industry  

E-Print Network [OSTI]

Efficiency Improvement and CO2 Emission Reduction PotentialsModel Inputs Emissions Factors CO2 Emission factor for grid electricity (tonne CO2/MWh)  CO2 Emission factor for fuel (

Morrow III, William R.

2014-01-01T23:59:59.000Z

93

A Numerical Investigation of Wettability Alteration during Immiscible CO2  

E-Print Network [OSTI]

A Numerical Investigation of Wettability Alteration during Immiscible CO2 Flooding Process, April 2012 #12;2 Table of Contest Abstract 3 Introduction 3 Literature Review 5 CO2 Flooding 7 New alteration during CO2 flooding. However, limited research on numerical and/or analytical modeling

Hossain, M. Enamul

94

CO2 Capture by Absorption with Potassium Carbonate  

E-Print Network [OSTI]

CO2 Capture by Absorption with Potassium Carbonate First Quarterly Report 2006 Quarterly Progress the process for CO2 capture by alkanolamine absorption/stripping by developing an alternative solvent, aqueous.................................................................................................................................... 8 Task 1 ­ Modeling Performance of Absorption/Stripping of CO2 with Aqueous K2CO3 Promoted

Rochelle, Gary T.

95

CO2 Capture by Absorption with Potassium Carbonate  

E-Print Network [OSTI]

CO2 Capture by Absorption with Potassium Carbonate Third Quarterly Report 2006 Quarterly Progress of this work is to improve the process for CO2 capture by alkanolamine absorption/stripping by developing...................................................................................................................................11 Task 1 ­ Modeling Performance of Absorption/Stripping of CO2 with Aqueous K2CO3 Promoted

Rochelle, Gary T.

96

CO2 Capture by Absorption with Potassium Carbonate  

E-Print Network [OSTI]

CO2 Capture by Absorption with Potassium Carbonate Second Quarterly Report 2006 Quarterly Progress of this work is to improve the process for CO2 capture by alkanolamine absorption/stripping by developing.................................................................................................................................. 10 Task 1 ­ Modeling Performance of Absorption/Stripping of CO2 with Aqueous K2CO3 Promoted

Rochelle, Gary T.

97

Time-lapse seismic modeling and production data assimilation for enhanced oil recovery and CO2 sequestration  

E-Print Network [OSTI]

gases into the earth’s atmosphere. Numerical simulators are used for designing and predicting the complex behavior of systems under such scenarios. Two key steps in such studies are forward modeling for performance prediction based on simulation studies...

Kumar, Ajitabh

2009-05-15T23:59:59.000Z

98

Modeling Coal Matrix Shrinkage and Differential Swelling with CO2 Injection for Enhanced Coalbed Methane Recovery and Carbon Sequestration Applications  

SciTech Connect (OSTI)

Matrix shrinkage and swelling can cause profound changes in porosity and permeability of coalbed methane reservoirs during depletion or when under CO{sub 2} injection processes, with significant implication for primary or enhanced methane recovery. Two models that are used to describe these effects are discussed. The first was developed by Advanced Resources International (ARI) and published in 1990 by Sawyer, et al. The second model was published by Palmer and Mansoori in 1996. This paper shows that the two provide equivalent results for most applications. However, their differences in formulation cause each to have relative advantages and disadvantages under certain circumstances. Specifically, the former appears superior for undersaturated coalbed methane reservoirs while the latter would be better if a case is found where matrix swelling is strongly disproportional to gas concentration. Since its presentation in 1996, the Palmer and Mansoori model has justifiably received much critical praise. However, the model developed by ARI for the COMET reservoir simulation program has been in use since 1990, and has significant advantages in certain settings. A review of data published by Levine in 1996 reveals that carbon dioxide causes a greater degree of coal matrix swelling compared to methane, even when measured on a unit of concentration basis. This effect is described in this report as differential swelling. Differential swelling may have important consequences for enhanced coalbed methane and carbon sequestration projects. To handle the effects of differential swelling, an extension to the matrix shrinkage and swelling model used by the COMET simulator is presented and shown to replicate the data of Levine. Preliminary field results from a carbon dioxide injection project are also presented in support of the extended model. The field evidence supports that considerable changes to coal permeability occur with CO{sub 2} injection, with significant implication for the design, implementation and performance of enhanced coalbed methane recovery and CO{sub 2} sequestration projects.

L. J. Pekot; S. R. Reeves

2002-03-31T23:59:59.000Z

99

Actualistic and Geochemical Modeling of Reservoir Rock, CO2 and Formation Fluid Interaction, Citronelle Oil Field, Alabama  

SciTech Connect (OSTI)

This report includes description of the Citronelle field study area and the work carried out in the project to characterize the geology and composition of reservoir rock material and to collect an analyze the geochemical composition of produced fluid waters from the Citronelle field. Reservoir rock samples collected from well bore core were made into thin-sections and assessed for textural properties, including pore types and porosity distribution. Compositional framework grain modal data were collected via point-counting, and grain and cement mineralogy was assessed using SEM-EDS. Geochemistry of fluid samples is described and modeled using PHREEQC. Composition of rock and produced fluids were used as inputs for TOUGHREACT reactive transport modeling, which determined the rock-fluid system was in disequilibrium.

Weislogel, Amy

2014-01-31T23:59:59.000Z

100

Analysis of Field Development Strategies of CO2 EOR/Capture Projects Using a Reservoir Simulation Economic Model  

E-Print Network [OSTI]

($) Drilling cost for one well ($) Facilities cost for one pattern ($) Tubing cost for one well ($) Drilling depth (feet) EIA US Energy Information Administration EOR Enhanced Oil Recovery EOS Equation of State IEA International... in the reservoir ................................................................ 20 Figure 13: Scope of this chapter: definition of the economic model ............................... 21 Figure 14: Spot price of the oil on the WTI market from 1986 to 2013 (EIA...

Saint-Felix, Martin

2013-05-03T23:59:59.000Z

Note: This page contains sample records for the topic "ks modeling co2" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Regional CO2 and latent heat surface fluxes in the Southern Great Plains: Measurements, modeling, and scaling  

SciTech Connect (OSTI)

Characterizing net ecosystem exchanges (NEE) of CO{sub 2} and sensible and latent heat fluxes in heterogeneous landscapes is difficult, yet critical given expected changes in climate and land use. We report here a measurement and modeling study designed to improve our understanding of surface to atmosphere gas exchanges under very heterogeneous land cover in the mostly agricultural U.S. Southern Great Plains (SGP). We combined three years of site-level, eddy covariance measurements in several of the dominant land cover types with regional-scale climate data from the distributed Mesonet stations and Next Generation Weather Radar precipitation measurements to calibrate a land surface model of trace gas and energy exchanges (isotope-enabled land surface model (ISOLSM)). Yearly variations in vegetation cover distributions were estimated from Moderate Resolution Imaging Spectroradiometer normalized difference vegetation index and compared to regional and subregional vegetation cover type estimates from the U.S. Department of Agriculture census. We first applied ISOLSM at a 250 m spatial scale to account for vegetation cover type and leaf area variations that occur on hundred meter scales. Because of computational constraints, we developed a subsampling scheme within 10 km 'macrocells' to perform these high-resolution simulations. We estimate that the Atmospheric Radiation Measurement Climate Research Facility SGP region net CO{sub 2} exchange with the local atmosphere was -240, -340, and -270 gC m{sup -2} yr{sup -1} (positive toward the atmosphere) in 2003, 2004, and 2005, respectively, with large seasonal variations. We also performed simulations using two scaling approaches at resolutions of 10, 30, 60, and 90 km. The scaling approach applied in current land surface models led to regional NEE biases of up to 50 and 20% in weekly and annual estimates, respectively. An important factor in causing these biases was the complex leaf area index (LAI) distribution within cover types. Biases in predicted weekly average regional latent heat fluxes were smaller than for NEE, but larger than for either ecosystem respiration or assimilation alone. However, spatial and diurnal variations of hundreds of W m{sup -2} in latent heat fluxes were common. We conclude that, in this heterogeneous system, characterizing vegetation cover type and LAI at the scale of spatial variation are necessary for accurate estimates of bottom-up, regional NEE and surface energy fluxes.

Riley, W. J.; Biraud, S.C.; Torn, M.S.; Fischer, M.L.; Billesbach, D.P.; Berry, J.A.

2009-08-15T23:59:59.000Z

102

The effects of gas-fluid-rock interactions on CO2 injection and storage: Insights from reactive transport modeling  

SciTech Connect (OSTI)

Possible means of reducing atmospheric CO{sub 2} emissions include injecting CO{sub 2} in petroleum reservoirs for Enhanced Oil Recovery or storing CO{sub 2} in deep saline aquifers. Large-scale injection of CO{sub 2} into subsurface reservoirs would induce a complex interplay of multiphase flow, capillary trapping, dissolution, diffusion, convection, and chemical reactions that may have significant impacts on both short-term injection performance and long-term fate of CO{sub 2} storage. Reactive Transport Modeling is a promising approach that can be used to predict the spatial and temporal evolution of injected CO{sub 2} and associated gas-fluid-rock interactions. This presentation will summarize recent advances in reactive transport modeling of CO{sub 2} storage and review key technical issues on (1) the short- and long-term behavior of injected CO{sub 2} in geological formations; (2) the role of reservoir mineral heterogeneity on injection performance and storage security; (3) the effect of gas mixtures (e.g., H{sub 2}S and SO{sub 2}) on CO{sub 2} storage; and (4) the physical and chemical processes during potential leakage of CO{sub 2} from the primary storage reservoir. Simulation results suggest that CO{sub 2} trapping capacity, rate, and impact on reservoir rocks depend on primary mineral composition and injecting gas mixtures. For example, models predict that the injection of CO{sub 2} alone or co-injection with H{sub 2}S in both sandstone and carbonate reservoirs lead to acidified zones and mineral dissolution adjacent to the injection well, and carbonate precipitation and mineral trapping away from the well. Co-injection of CO{sub 2} with H{sub 2}S and in particular with SO{sub 2} causes greater formation alteration and complex sulfur mineral (alunite, anhydrite, and pyrite) trapping, sometimes at a much faster rate than previously thought. The results from Reactive Transport Modeling provide valuable insights for analyzing and assessing the dynamic behaviors of injected CO{sub 2}, identifying and characterizing potential storage sites, and managing injection performance and reducing costs.

Xiao, Y.; Xu, T.; Pruess, K.

2008-10-15T23:59:59.000Z

103

Co2 geological sequestration  

SciTech Connect (OSTI)

Human activities are increasingly altering the Earth's climate. A particular concern is that atmospheric concentrations of carbon dioxide (CO{sub 2}) may be rising fast because of increased industrialization. CO{sub 2} is a so-called ''greenhouse gas'' that traps infrared radiation and may contribute to global warming. Scientists project that greenhouse gases such as CO{sub 2} will make the arctic warmer, which would melt glaciers and raise sea levels. Evidence suggests that climate change may already have begun to affect ecosystems and wildlife around the world. Some animal species are moving from one habitat to another to adapt to warmer temperatures. Future warming is likely to exceed the ability of many species to migrate or adjust. Human production of CO{sub 2} from fossil fuels (such as at coal-fired power plants) is not likely to slow down soon. It is urgent to find somewhere besides the atmosphere to put these increased levels of CO{sub 2}. Sequestration in the ocean and in soils and forests are possibilities, but another option, sequestration in geological formations, may also be an important solution. Such formations could include depleted oil and gas reservoirs, unmineable coal seams, and deep saline aquifers. In many cases, injection of CO2 into a geological formation can enhance the recovery of hydrocarbons, providing value-added byproducts that can offset the cost of CO{sub 2} capture and sequestration. Before CO{sub 2} gas can be sequestered from power plants and other point sources, it must be captured. CO{sub 2} is also routinely separated and captured as a by-product from industrial processes such as synthetic ammonia production, H{sub 2} production, and limestone calcination. Then CO{sub 2} must be compressed into liquid form and transported to the geological sequestration site. Many power plants and other large emitters of CO{sub 2} are located near geological formations that are amenable to CO{sub 2} sequestration.

Xu, Tianfu

2004-11-18T23:59:59.000Z

104

Modeling the resolution of inexpensive, novel non-seismic geophysical monitoring tools to monitor CO2 injection into coal beds  

SciTech Connect (OSTI)

A sensitivity study of gravity and electromagnetic (EM) techniques, and amplitude vs. angle (AVA) analysis for CO{sub 2} movement in coal beds was based on the SECARB pilot test planned in the Black Warrior basin in Alabama. In the area of interest, coalbed methane is produced mainly from the Black Creek, Mary Lee, and Pratt coal zones at depths between 400 and 700 m and approximately 3 m thick on average. The permeability of coal in the Black Warrior basin decreases exponentially with depth as overburden stress increases. The permeability of the top layer is 100 mD, while the permeability of the deepest layer is around 1 mD. The pilot field test will include injecting a total of 1000 tons of CO{sub 2} into these three coal zones ({approx}300 tons to each zone). The density, sonic and resistivity well-logs from a deep disposal well a couple of miles from the pilot test site were used to create background (pre-injection) models. Our laboratory measurements of seismic velocity and electrical resistivity as a function of CO{sub 2} saturation on coal core samples were used to provide a link between the coalbed CO{sub 2} flow simulation models and the geophysical models. The sensitivity studies showed that while the response to the 300 tons of CO{sub 2} injected into a single layer wouldn't produce measurable surface response for either gravity or EM, the response due to an industrial-size injection would produce measurable surface signal for both techniques. Gravity inversion results illustrated that, provided we can collect high-quality gravity data in the field and we have some a priori information about the depth of the reservoir, we can recover the spatial location of CO{sub 2} plume correctly, although with the smoothing constraint of the inversion, the area was slightly overestimated, resulting in an underestimated value of density change. AVA analysis showed that by inverting seismic and EM data jointly, much better estimates of CO{sub 2} saturation can be obtained, especially in the third injection zone, where seismic AVA data fail to detect the high CO{sub 2} saturation. Analysis of spatial resolution and detectability limits show that gravity and EM measurements could, under certain circumstances, be used as a lower-cost alternative to seismic measurements.

Gasperikova, E.; Hoversten, G.M.

2008-09-01T23:59:59.000Z

105

R & D Supercritiacl CO2/ Rock Chemicals Interactions  

Broader source: Energy.gov (indexed) [DOE]

model that couples chemical reactions of mineral dissolution precipitation with spatial and temporal flow variations in CO 2 brinerock systems Principal Investigator:...

106

Enhanced Geothermal Systems (EGS) with CO2as Heat Transmission...  

Broader source: Energy.gov (indexed) [DOE]

Program eere.energy.gov * The project started in FY10 * Collaboration between LBNL (Pruess) and INL (Redden) - Berkeley leads modeling, CO 2 -brine flow and heat...

107

Enhanced Geothermal Systems (EGS) with CO2 as Heat Transmission...  

Open Energy Info (EERE)

Targets Milestones - Test crucial predictions from theoretical models about the heat transfer and fluid flow properties of CO2; - Obtain essential data to be incorporated...

108

CO2 exposure at pressure impacts metabolism and stress responses...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

in the model sulfate-reducing bacterium Desulfovibrio vulgaris Abstract: Geologic carbon dioxide (CO2) sequestration drives physical and geochemical changes in deep...

109

ATOMIC-LEVEL MODELING OF CO2 DISPOSAL AS A CARBONATE MINERAL: A SYNERGETIC APPROACH TO OPTIMIZING REACTION PROCESS DESIGN  

SciTech Connect (OSTI)

Fossil fuels, especially coal, can support the energy demands of the world for centuries to come, if the environmental problems associated with CO{sub 2} emissions can be overcome. Permanent and safe methods for CO{sub 2} capture and disposal/storage need to be developed. Mineralization of stationary-source CO{sub 2} emissions as carbonates can provide such safe capture and long-term sequestration. Mg-rich lamellar hydroxide mineral carbonation is a leading process candidate, which generates the stable naturally occurring mineral magnesite (MgCO{sub 3}) and water. Key to process cost and viability are the carbonation reaction rate and its degree of completion. This process, which involves simultaneous dehydroxylation and carbonation is very promising, but far from optimized. In order to optimize the dehydroxylation/carbonation process, an atomic-level understanding of the mechanisms involved is needed. In this investigation Mg(OH){sub 2} was selected as a model Mg-rich lamellar hydrocide carbonation feedstock material due to its chemical and structural simplicity. Since Mg(OH){sub 2} dehydroxylation is intimately associated with the carbonation process, its mechanisms are also of direct interest in understanding and optimizing the process. The aim of the current innovative concepts project is to develop a specialized advanced computational methodology to complement the ongoing experimental inquiry of the atomic level processes involved in CO{sub 2} mineral sequestration. The ultimate goal is to integrate the insights provided by detailed predictive simulations with the data obtained from optical microscopy, FESEM, ion beam analysis, SIMS, TGA, Raman, XRD, and C and H elemental analysis. The modeling studies are specifically designed to enhance the synergism with, and complement the analysis of, existing mineral-CO{sub 2} reaction process studies being carried out under DOE UCR Grant DE-FG2698-FT40112. Direct contact between the simulations and the experimental measurements is provided by computing, from first principles, the equilibrium structures, elastic, optical, and vibrational properties of Mg(OH){sub 2} (brucite), MgO (periclase), MgCO{sub 3} (magnesite), as well as the energetics of the dehydroxylation reaction (Mg(OH){sub 2} {yields} MgO + H{sub 2}O), and the reactivity of CO{sub 2} with MgO and Mg(OH){sub 2}. From these calculations, thermodynamic characteristics of the reaction conditions can be inferred. This kind of information, when integrated with the atomic level data obtained from experimental gas-solid dehydroxylation/carbonation studies, will be used to design optimized reaction processes leading to the practical and cost-effective sequestration of CO{sub 2} in mineral form.

A.V.G. Chizmeshya; M.J. McKelvy; J.B. Adams

2001-11-01T23:59:59.000Z

110

Large Releases from CO2 Storage Reservoirs: A Discussion ofNatural Analogs, FEPS, and Modeling Needs  

SciTech Connect (OSTI)

While the purpose of geologic storage in deep saline formations is to trap greenhouse gases underground, the potential exists for CO{sub 2} to escape from the target reservoir, migrate upward along permeable pathways, and discharge at the land surface. In this paper, we evaluate the potential for such CO{sub 2} discharges based on the analysis of natural analogs, where large releases of gas have been observed. We are particularly interested in circumstances that could generate sudden, possibly self-enhancing release events. The probability for such events may be low, but the circumstances under which they occur and the potential consequences need to be evaluated in order to design appropriate site-selection and risk-management strategies. Numerical modeling of hypothetical test cases is suggested to determine critical conditions for large CO{sub 2} releases, to evaluate whether such conditions may be possible at designated storage sites, and, if applicable, to evaluate the potential impacts of such events as well as design appropriate mitigation strategies.

Birkholzer, J.; Pruess, K.; Lewicki, J.L.; Rutqvist, J.; Tsang,C-F.; Karimjee, A.

2005-11-01T23:59:59.000Z

111

CO2 Sequestration short course  

SciTech Connect (OSTI)

Given the public’s interest and concern over the impact of atmospheric greenhouse gases (GHGs) on global warming and related climate change patterns, the course is a timely discussion of the underlying geochemical and mineralogical processes associated with gas-water-mineral-interactions encountered during geological sequestration of CO2. The geochemical and mineralogical processes encountered in the subsurface during storage of CO2 will play an important role in facilitating the isolation of anthropogenic CO2 in the subsurface for thousands of years, thus moderating rapid increases in concentrations of atmospheric CO2 and mitigating global warming. Successful implementation of a variety of geological sequestration scenarios will be dependent on our ability to accurately predict, monitor and verify the behavior of CO2 in the subsurface. The course was proposed to and accepted by the Mineralogical Society of America (MSA) and The Geochemical Society (GS).

DePaolo, Donald J. [Lawrence Berkeley National Laboratory; Cole, David R [The Ohio State University; Navrotsky, Alexandra [University of California-Davis; Bourg, Ian C [Lawrence Berkeley National Laboratory

2014-12-08T23:59:59.000Z

112

Root-derived CO2 efflux via xylem stream rivals soil CO2 efflux.  

SciTech Connect (OSTI)

• Respiration consumes a large portion of annual gross primary productivity in forest ecosystems and is dominated by belowground metabolism. Here, we present evidence of a previously unaccounted for internal CO2 flux of large magnitude from tree roots through stems. If this pattern is shown to persist over time and in other forests, it suggests that belowground respiration has been grossly underestimated. • Using an experimental Populus deltoides plantation as a model system, we tested the hypothesis that a substantial portion of the CO2 released from belowground autotrophic respiration remains within tree root systems and is transported aboveground through the xylem stream rather than diffusing into the soil atmosphere. • On a daily basis, the amount of CO2 that moved upward from the root system into the stem via the xylem stream (0.26 mol CO2 m?2 d?1) rivalled that which diffused from the soil surface to the atmosphere (0.27 mol CO2 m?2 d?1). We estimated that twice the amount of CO2 derived from belowground autotrophic respiration entered the xylem stream as diffused into the soil environment. • Our observations indicate that belowground autotrophic respiration consumes substantially more carbohydrates than previously recognized and challenge the paradigm that all root-respired CO2 diffuses into the soil atmosphere.

Aubrey, Doug, P.; Teskey, Robert, O.

2009-07-01T23:59:59.000Z

113

Evaluation of the Nordland Group overburden as an effective seal for the Sleipner CO2 storage site (offshore Norway) using analytical and stochastic modelling techniques   

E-Print Network [OSTI]

Saline aquifers and depleted hydrocarbon fields situated beneath the North Sea are currently being proposed as storage repositories for anthropogenic CO2 captured from point source emitters in the UK and mainland Europe. ...

Nicoll, Grant Douglas

2012-11-29T23:59:59.000Z

114

Uncertainty analyses of CO2 plume expansion subsequent to wellbore CO2 leakage into aquifers  

SciTech Connect (OSTI)

In this study, we apply an uncertainty quantification (UQ) framework to CO2 sequestration problems. In one scenario, we look at the risk of wellbore leakage of CO2 into a shallow unconfined aquifer in an urban area; in another scenario, we study the effects of reservoir heterogeneity on CO2 migration. We combine various sampling approaches (quasi-Monte Carlo, probabilistic collocation, and adaptive sampling) in order to reduce the number of forward calculations while trying to fully explore the input parameter space and quantify the input uncertainty. The CO2 migration is simulated using the PNNL-developed simulator STOMP-CO2e (the water-salt-CO2 module). For computationally demanding simulations with 3D heterogeneity fields, we combined the framework with a scalable version module, eSTOMP, as the forward modeling simulator. We built response curves and response surfaces of model outputs with respect to input parameters, to look at the individual and combined effects, and identify and rank the significance of the input parameters.

Hou, Zhangshuan; Bacon, Diana H.; Engel, David W.; Lin, Guang; Fang, Yilin; Ren, Huiying; Fang, Zhufeng

2014-08-01T23:59:59.000Z

115

CO2 Capture by Absorption with Potassium Carbonate  

E-Print Network [OSTI]

CO2 Capture by Absorption with Potassium Carbonate Third Quarterly Report 2005 Quarterly Progress absorption/stripping by developing an alternative solvent, aqueous K2CO3 promoted by piperazine. Modeling.................................................................................................................................. 11 Task 1 ­ Modeling Performance of Absorption/Stripping of CO2 with Aqueous K2CO3 Promoted

Rochelle, Gary T.

116

10 MW Supercritical CO2 Turbine Test  

SciTech Connect (OSTI)

The Supercritical CO2 Turbine Test project was to demonstrate the inherent efficiencies of a supercritical carbon dioxide (s-CO2) power turbine and associated turbomachinery under conditions and at a scale relevant to commercial concentrating solar power (CSP) projects, thereby accelerating the commercial deployment of this new power generation technology. The project involved eight partnering organizations: NREL, Sandia National Laboratories, Echogen Power Systems, Abengoa Solar, University of Wisconsin at Madison, Electric Power Research Institute, Barber-Nichols, and the CSP Program of the U.S. Department of Energy. The multi-year project planned to design, fabricate, and validate an s-CO2 power turbine of nominally 10 MWe that is capable of operation at up to 700°C and operates in a dry-cooled test loop. The project plan consisted of three phases: (1) system design and modeling, (2) fabrication, and (3) testing. The major accomplishments of Phase 1 included: Design of a multistage, axial-flow, s-CO2 power turbine; Design modifications to an existing turbocompressor to provide s-CO2 flow for the test system; Updated equipment and installation costs for the turbomachinery and associated support infrastructure; Development of simulation tools for the test loop itself and for more efficient cycle designs that are of greater commercial interest; Simulation of s-CO2 power cycle integration into molten-nitrate-salt CSP systems indicating a cost benefit of up to 8% in levelized cost of energy; Identification of recuperator cost as a key economic parameter; Corrosion data for multiple alloys at temperatures up to 650ºC in high-pressure CO2 and recommendations for materials-of-construction; and Revised test plan and preliminary operating conditions based on the ongoing tests of related equipment. Phase 1 established that the cost of the facility needed to test the power turbine at its full power and temperature would exceed the planned funding for Phases 2 and 3. Late in Phase 1 an opportunity arose to collaborate with another turbine-development team to construct a shared s-CO2 test facility. The synergy of the combined effort would result in greater facility capabilities than either separate project could produce and would allow for testing of both turbine designs within the combined budgets of the two projects. The project team requested a no-cost extension to Phase 1 to modify the subsequent work based on this collaborative approach. DOE authorized a brief extension, but ultimately opted not to pursue the collaborative facility and terminated the project.

Turchi, Craig

2014-01-29T23:59:59.000Z

117

Capturing CO2 from Air Anca Timofte  

E-Print Network [OSTI]

Capturing CO2 from Air Anca Timofte Climeworks AG Birchstrasse 155, 8050 Zürich www.climeworks.com, contact@climeworks.com Carbon Mitigation Lecture, 27 October 2014 #12;Air Climeworks CO2 capture plant CO2-free air Pure CO2 #12;3 Climeworks Products Demonstrator · 1 ton CO2 per year · Online since 12

Fischlin, Andreas

118

Modeling CO2 Sequestration in a Saline Reservoir and Depleted Oil Reservoir to Evaluate The Regional CO2 Sequestration Potential of The Ozark Plateau Aquifer System, South-Central Kansas  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: VegetationEquipment SurfacesResource Program PreliminaryA3,0StatementsMixing UpModeling &

119

Surface CO2 leakage during the first shallow subsurface CO2 release experiment  

E-Print Network [OSTI]

numbered 0-6. Plots of F CO2 measured along the surface wellin Figure 2. Figure 2. Log F CO2 maps for measurements madeof soil CO 2 flux (F CO2 ). The surface leakage onset,

Lewicki, J.L.; Oldenburg, C.; Dobeck, L.; Spangler, L.

2008-01-01T23:59:59.000Z

120

CO2 Capture by Absorption with Potassium Carbonate  

E-Print Network [OSTI]

CO2 Capture by Absorption with Potassium Carbonate Fourth Quarterly Report 2005 Quarterly Progress absorption/stripping by developing an alternative solvent, aqueous K2CO3 promoted by piperazine. In Campaign.................................................................................................................................... 9 Task 1 ­ Modeling Performance of Absorption/Stripping of CO2 with Aqueous K2CO3 Promoted

Rochelle, Gary T.

Note: This page contains sample records for the topic "ks modeling co2" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Northern California CO2 Reduction Project  

SciTech Connect (OSTI)

C6 Resources LLC, a wholly owned subsidiary of Shell Oil Company, worked with the US Department of Energy (DOE) under a Cooperative Agreement to develop the Northern California CO2 Reduction Project. The objective of the Project is to demonstrate the viability of using Carbon Capture and Sequestration (CCS) to reduce existing greenhouse gas emissions from industrial sources on a large-scale. The Project will capture more than 700,000 metric tonnes of CO2 per year, which is currently being vented to the atmosphere from the Shell Martinez Refinery in Contra Costa County. The CO2 will be compressed and dehydrated at the refinery and then transported via pipeline to a sequestration site in a rural area in neighboring Solano County. The CO2 will be sequestered into a deep saline formation (more than two miles underground) and will be monitored to assure secure, long-term containment. The pipeline will be designed to carry as much as 1,400,000 metric tonnes of CO2 per year, so additional capacity will be available to accommodate CO2 captured from other industrial sources. The Project is expected to begin operation in 2015. The Project has two distinct phases. The overall objective of Phase 1 was to develop a fully definitive design basis for the Project. The Cooperative Agreement with the DOE provided cost sharing for Phase 1 and the opportunity to apply for additional DOE cost sharing for Phase 2, comprising the design, construction and operation of the Project. Phase 1 has been completed. DOE co-funding is provided by the American Recovery and Reinvestment Act (ARRA) of 2009. As prescribed by ARRA, the Project will stimulate the local economy by creating manufacturing, transportation, construction, operations, and management jobs while addressing the need to reduce greenhouse gas emissions at an accelerated pace. The Project, which will also assist in meeting the CO2 reduction requirements set forth in California?s Climate Change law, presents a major opportunity for both the environment as well as the region. C6 Resources is conducting the Project in collaboration with federally-funded research centers, such as Lawrence Berkeley National Lab and Lawrence Livermore National Lab. C6 Resources and Shell have identified CCS as one of the critical pathways toward a worldwide goal of providing cleaner energy. C6 Resources, in conjunction with the West Coast Regional Carbon Sequestration Partnership (WESTCARB), has conducted an extensive and ongoing public outreach and CCS education program for local, regional and state-wide stakeholders. As part of a long term relationship, C6 Resources will continue to engage directly with community leaders and residents to ensure public input and transparency. This topical report summarizes the technical work from Phase 1 of the Project in the following areas: ? Surface Facility Preliminary Engineering: summarizes the preliminary engineering work performed for CO2 capture, CO2 compression and dehydration at the refinery, and surface facilities at the sequestration site ? Pipeline Preliminary Engineering: summarizes the pipeline routing study and preliminary engineering design ? Geologic Sequestration: summarizes the work to characterize, model and evaluate the sequestration site ? Monitoring, Verification and Accounting (MVA): summarizes the MVA plan to assure long-term containment of the sequestered CO2

Hymes, Edward

2010-06-16T23:59:59.000Z

122

Predicting CO2-water interfacial tension under pressure and temperature conditions of geologic CO2 storage  

E-Print Network [OSTI]

E EPM2- TIP4P2005 PPL- TIP4P2005 Predicted (f) a P ? CO2 2SE? CO2 2SE? CO2 2SE ? CO2 2SE ? CO2 2SE ? CO2 2SE a Surface excess CO

Nielsen, L.C.

2013-01-01T23:59:59.000Z

123

6.11 Atmospheric CO2 and O2 During the Phanerozoic: Tools, Patterns, and Impacts  

E-Print Network [OSTI]

6.11 Atmospheric CO2 and O2 During the Phanerozoic: Tools, Patterns, and Impacts DL Royer, Wesleyan.11.2 Models for Atmospheric CO2 and O2 Estimation 251 6.11.2.1 Key Principles 251 6.11.2.2 GEOCARB Models 252.11.2.2.5 Estimates of CO2 and O2 from the GEOCARB model 254 6.11.2.3 Other Models for CO2 and O2 Reconstruction 254 6

Royer, Dana

124

Predicting CO2-water interfacial tension under pressure and temperature conditions of geologic CO2 storage  

E-Print Network [OSTI]

within ± 15% of nominal P. EPM2-SPC/E DZ- SPC/E PPL-SPC/EEPM2- TIP4P2005 PPL- TIP4P2005 Predicted (f) a P ? CO2 2SE ?to C and O atoms (Table 1). The PPL model (In Het Panhuis et

Nielsen, L.C.

2013-01-01T23:59:59.000Z

125

8, 73737389, 2008 Scientists' CO2  

E-Print Network [OSTI]

ACPD 8, 7373­7389, 2008 Scientists' CO2 emissions A. Stohl Title Page Abstract Introduction substantial emissions of carbon dioxide (CO2). In this pa- per, the CO2 emissions of the employees working, the total annual per capita CO2 emissions are 4.5 t worldwide, 1.2 t for India, 3.8 t for China, 5

Paris-Sud XI, Université de

126

6, 1092910958, 2006 Regional scale CO2  

E-Print Network [OSTI]

ACPD 6, 10929­10958, 2006 Regional scale CO2 flux estimation using radon A. I. Hirsch Title Page Chemistry and Physics Discussions On using radon-222 and CO2 to calculate regional-scale CO2 fluxes A. I (Adam.Hirsch@noaa.gov) 10929 #12;ACPD 6, 10929­10958, 2006 Regional scale CO2 flux estimation using

Paris-Sud XI, Université de

127

Short communication Satellite-derived surface water pCO2 and airsea CO2 fluxes  

E-Print Network [OSTI]

Short communication Satellite-derived surface water pCO2 and air­sea CO2 fluxes in the northern for the estimation of the partial pressure of carbon dioxide (pCO2) and air­sea CO2 fluxes in the northern South), respectively, the monthly pCO2 fields were computed. The derived pCO2 was compared with the shipboard pCO2

128

Pore-scale simulation of liquid CO2 displacement of water using...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Pore-scale simulation of liquid CO2 displacement of water using a two-phase lattice Boltzmann model. Pore-scale simulation of liquid CO2 displacement of water using a two-phase...

129

Properties of CO2-Rich Pore Fluids and Their Effect on Porosity Evolution in EGS Rocks  

Broader source: Energy.gov [DOE]

Project objective: Quantify key parameters critically needed for developing and validating numerical modeling of chemical interactions between EGS reservoir rocks and supercritical CO2and CO2-rich aqueous fluids.

130

CO2 http://andrew.ucsd.edu/co2qc/ University of California, San Diego  

E-Print Network [OSTI]

cooled by liquid nitrogen. The water and CO2 are separated from one another by sublimation and the CO2 for oceanic CO2 analysis: A method for the certification of total alkalinity. Marine Chemistry 80, 185

131

CO2-Based Glue - Energy Innovation Portal  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation Proposed New Substation Sites Proposed Route BTRIC CNMSMethanol Steam Reforming.modelCO2

132

QGESS: CO2 Impurity Design Parameters  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

10. Shah, Minish. Capturing CO2 from Oxy-Fuel Combustion Flue Gas. Cottbus, Germany : Praxair Inc., 2005. 11. Spitznogle, Gary O. CO2 Impurity Specification at AEP Mountaineer....

133

ATMOSPHERIC CO2 A GLOBAL LIMITING RESOURCE  

E-Print Network [OSTI]

Carbondioxideatmosphericburden,PgC Land use Fossil CO2 from land use emissions ­ not fossil fuel combustion ­ was the dominant CO2 Comparison of CO2 mixing ratio from fossil fuel combustion and land use changes 400 380 360 340 cores 0 0.2 0.4 0.6 0.8 1.0 1.2 1.4 1.6 Forcing,Wm -2 #12;ATMOSPHERIC CO2 EMISSIONS Time series 1700

Schwartz, Stephen E.

134

5, 33133340, 2005 SCIAMACHY CO2 and  

E-Print Network [OSTI]

ACPD 5, 3313­3340, 2005 SCIAMACHY CO2 and aerosols S. Houweling et al. Title Page Abstract Evidence of systematic errors in SCIAMACHY-observed CO2 due to aerosols S. Houweling 1,2 , W. Hartmann 1 Commons License. 3313 #12;ACPD 5, 3313­3340, 2005 SCIAMACHY CO2 and aerosols S. Houweling et al. Title

Paris-Sud XI, Université de

135

2, 711743, 2006 Glacial CO2  

E-Print Network [OSTI]

CPD 2, 711­743, 2006 Glacial CO2 sequestration L. C. Skinner Title Page Abstract Introduction CO2 change: a simple "hypsometric effect" on deep-ocean carbon sequestration? L. C. Skinner Godwin Scientist Award win- ners 2006 711 #12;CPD 2, 711­743, 2006 Glacial CO2 sequestration L. C. Skinner Title

Paris-Sud XI, Université de

136

CO2 & global temperature: Analysis of ice core and marine sediment data in  

E-Print Network [OSTI]

CO2 & global temperature: Analysis of ice core and marine sediment data in combination with modeling of marine reservoir ages Gerrit Lohmann & Martin Butzin #12;Deglaciation CO2 vs. global temperature Ice cores: Temperature leads CO2 People (mainly outside the scientific comunity) use

Sengun, Mehmet Haluk

137

Author's personal copy Antioxidant capacity reduced in scallions grown under elevated CO2  

E-Print Network [OSTI]

Author's personal copy Antioxidant capacity reduced in scallions grown under elevated CO2 was used as a model plant to study the impact of a range of CO2 concentrations and light intensities in controlled environmental chambers under a combination of 3 CO2 concentrations of 400, 1200 and 4000 lmol mol

Paré, Paul W.

138

Wavelet-based reconstruction of fossil-fuel CO2 emissions from sparse measurements  

E-Print Network [OSTI]

Wavelet-based reconstruction of fossil-fuel CO2 emissions from sparse measurements J. Ray1, V: Develop a technique to estimate anthropogenic (fossil- fuel) CO2 emissions from sparse observations · Motivations: ­ An alternative to estimating ffCO2 emission using bottom-up (economic model) techniques

Ray, Jaideep

139

Allocation of Transportation Cost & CO2 Emission in Pooled Supply Chains Using  

E-Print Network [OSTI]

Allocation of Transportation Cost & CO2 Emission in Pooled Supply Chains Using Cooperative Game and the transport CO2 emissions. In this regard, this paper introduces a scheme to share in a fairly manner the savings. After a summary of the concept of pooled-supply-networks optimization and CO2 emission model, we

Boyer, Edmond

140

Geologic controls influencing CO2 loss from a leaking well.  

SciTech Connect (OSTI)

Injection of CO2 into formations containing brine is proposed as a long-term sequestration solution. A significant obstacle to sequestration performance is the presence of existing wells providing a transport pathway out of the sequestration formation. To understand how heterogeneity impacts the leakage rate, we employ two dimensional models of the CO2 injection process into a sandstone aquifer with shale inclusions to examine the parameters controlling release through an existing well. This scenario is modeled as a constant-rate injection of super-critical CO2 into the existing formation where buoyancy effects, relative permeabilities, and capillary pressures are employed. Three geologic controls are considered: stratigraphic dip angle, shale inclusion size and shale fraction. In this study, we examine the impact of heterogeneity on the amount and timing of CO2 released through a leaky well. Sensitivity analysis is performed to classify how various geologic controls influence CO2 loss. A 'Design of Experiments' approach is used to identify the most important parameters and combinations of parameters to control CO2 migration while making efficient use of a limited number of computations. Results are used to construct a low-dimensional description of the transport scenario. The goal of this exploration is to develop a small set of parametric descriptors that can be generalized to similar scenarios. Results of this work will allow for estimation of the amount of CO2 that will be lost for a given scenario prior to commencing injection. Additionally, two-dimensional and three-dimensional simulations are compared to quantify the influence that surrounding geologic media has on the CO2 leakage rate.

Hopkins, Polly L.; Martinez, Mario J.; McKenna, Sean Andrew; Klise, Katherine A.

2010-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "ks modeling co2" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Samenvatting CO2 is het meest belangrijke broeikasgas. The concentratie van CO2 in de atmosfeer  

E-Print Network [OSTI]

Samenvatting CO2 is het meest belangrijke broeikasgas. The concentratie van CO2 in de atmosfeer brandstoffen en veranderingen in landgebruik. Toenemende concentraties van CO2 in de atmosfeer zullen naar toename van CO2 in de atmosfeer op de dynamiek van de microbiële gemeenschap in de directe omgeving van de

van den Brink, Jeroen

142

Stragegies to Detect Hidden Geothermal Systems Based on Monitoringand Analysis of CO2 in the Near-Surface Environment  

SciTech Connect (OSTI)

We investigate the potential for CO2 monitoring in thenear-surface environment as an approach to exploration for hiddengeothermal systems. Numerical simulations of CO2 migration from a modelhidden geothermal system show that CO2 concentrations can reach highlevels in the shallow subsurface even for relatively low CO2 fluxes.Therefore, subsurface measurements offer an advantage over above-groundmeasurements which are affected by winds that rapidly disperse CO2. Tomeet the challenge of detecting geothermal CO2 emissions within thenatural background variability of CO2, we propose an approach thatintegrates available detection and monitoring techniques with statisticalanalysis and modeling.

Lewicki, Jennifer L.; Oldenburg, Curtis M.

2005-03-29T23:59:59.000Z

143

K/S Relay Issue 4  

E-Print Network [OSTI]

?' lEEL^U A CONTENTS This Deadly Innocence or "The End of the Hurt/Comfort Syndrome" by Leslie Fish 5 Axtivonk by Roo. Re.pA*.\\ite.d &Aom Nake.d Th)\\eA 3. **************** Lester's Complaint by Leslie Fish 68 Aitwoxk by Ann Hamplviey Rep...Alal. K/S RELAY 4 1982 (c) Janet Hunt. Once again Relay is reprinting some of Leslie Fish's marvellous K/S stories, THIS DEADLY INNOCENCE or The End of the Hurt/Comfort Syndrome is, in my opinion, just about the most exciting and well written story...

Fish, L.; Rathbone, W.

1982-01-01T23:59:59.000Z

144

The supply chain of CO2 emissions  

E-Print Network [OSTI]

emissions from traded fossil fuels; Top), production (F Pr )Regional, and National Fossil-Fuel CO 2 Emissions (Carbonfrom the burning of fossil fuels are conventionally

Davis, S. J; Peters, G. P; Caldeira, K.

2011-01-01T23:59:59.000Z

145

Representing Vapor-Liquid Equilibrium for an Aqueous MEA-CO2 System Using the Electrolyte Nonrandom-Two-Liquid Model  

E-Print Network [OSTI]

, Massachusetts 02141 Following the work of Austgen et al., the electrolyte nonrandom-two-liquid (NRTL) model reaction as well as important interaction parameters of the electrolyte NRTL model were carefully fitted

Zhang, Luzheng

146

A model-data intercomparison of CO2 exchange across North America: Results from the North American Carbon Program Site Synthesis  

SciTech Connect (OSTI)

Our current understanding of terrestrial carbon processes is represented in various models used to integrate and scale measurements of CO{sub 2} exchange from remote sensing and other spatiotemporal data. Yet assessments are rarely conducted to determine how well models simulate carbon processes across vegetation types and environmental conditions. Using standardized data from the North American Carbon Program we compare observed and simulated monthly CO{sub 2} exchange from 44 eddy covariance flux towers in North America and 22 terrestrial biosphere models. The analysis period spans {approx}220 site-years, 10 biomes, and includes two large-scale drought events, providing a natural experiment to evaluate model skill as a function of drought and seasonality. We evaluate models' ability to simulate the seasonal cycle of CO{sub 2} exchange using multiple model skill metrics and analyze links between model characteristics, site history, and model skill. Overall model performance was poor; the difference between observations and simulations was {approx}10 times observational uncertainty, with forested ecosystems better predicted than nonforested. Model-data agreement was highest in summer and in temperate evergreen forests. In contrast, model performance declined in spring and fall, especially in ecosystems with large deciduous components, and in dry periods during the growing season. Models used across multiple biomes and sites, the mean model ensemble, and a model using assimilated parameter values showed high consistency with observations. Models with the highest skill across all biomes all used prescribed canopy phenology, calculated NEE as the difference between GPP and ecosystem respiration, and did not use a daily time step.

Schwalm, C.R.; Williams, C.A.; Schaefer, K.; Anderson, R.; Arain, M.A.; Baker, I.; Black, T.A.; Chen, G.; Ciais, P.; Davis, K. J.; Desai, A. R.; Dietze, M.; Dragoni, D.; Fischer, M.L.; Flanagan, L.B.; Grant, R.F.; Gu, L.; Hollinger, D.; Izaurralde, R.C.; Kucharik, C.; Lafleur, P.M.; Law, B.E.; Li, L.; Li, Z.; Liu, S.; Lokupitiya, E.; Luo, Y.; Ma, S.; Margolis, H.; Matamala, R.; McCaughey, H.; Monson, R. K.; Oechel, W. C.; Peng, C.; Poulter, B.; Price, D.T.; Riciutto, D.M.; Riley, W.J.; Sahoo, A.K.; Sprintsin, M.; Sun, J.; Tian, H.; Tonitto, C.; Verbeeck, H.; Verma, S.B.

2011-06-01T23:59:59.000Z

147

Laboratory and Field Experimental Studies of CO2 as Heat Transmission...  

Broader source: Energy.gov (indexed) [DOE]

Systems (EGS) with CO2as Heat Transmission Fluid Tracer Methods for Characterizing Fracture Stimulation in Engineered Geothermal Systems (EGS) Development of Chemical Model to...

148

4, 23852405, 2007 CO2 and climate  

E-Print Network [OSTI]

BGD 4, 2385­2405, 2007 CO2 and climate affect European carbon ballance R. Harrison and C. Jones Competing roles of rising CO2 and climate change in the contemporary European carbon balance R. Harrison and C. Jones Met Office, Hadley Centre for Climate Change, Exeter, EX1 3PB, UK Received: 13 April 2007

Paris-Sud XI, Université de

149

CO2 Capture with Enzyme Synthetic Analogue  

SciTech Connect (OSTI)

Project overview provides background on carbonic anhydrase transport mechanism for CO2 in the human body and proposed approach for ARPA-E project to create a synthetic enzyme analogue and utilize it in a membrane for CO2 capture from flue gas.

Harry Cordatos

2010-03-01T23:59:59.000Z

150

Study of CO2 Mobility Control in Heterogeneous Media Using CO2 Thickening Agents  

E-Print Network [OSTI]

CO2 injection is an effective method for performing enhanced oil recovery (EOR). There are several factors that make CO2 useful for EOR, including promoting swelling, reducing oil viscosity, decreasing oil density, and vaporizing and extracting...

Al Yousef, Zuhair

2012-10-19T23:59:59.000Z

151

Cross sections for the reactions $e^+ e^-\\to K_S^0 K_L^0$, $K_S^0 K_L^0 ?^+?^-$, $K_S^0 K_S^0 ?^+?^-$, and $K_S^0 K_S^0 K^+K^-$ from events with initial-state radiation  

E-Print Network [OSTI]

We study the processes $e^+ e^-\\to K_S^0 K_L^0 \\gamma$, $K_S^0 K_L^0 \\pi^+\\pi^-\\gamma$, $K_S^0 K_S^0 \\pi^+\\pi^-\\gamma$, and $K_S^0 K_S^0 K^+K^-\\gamma$, where the photon is radiated from the initial state, providing cross section measurements for the hadronic states over a continuum of center-of-mass energies. The results are based on 469 fb$^{-1}$ of data collected with the BaBar detector at SLAC. We observe the $\\phi(1020)$ resonance in the $K_S^0 K_L^0$ final state and measure the product of its electronic width and branching fraction with about 3% uncertainty. We present a measurement of the $e^+ e^-\\to K_S^0 K_L^0 $ cross section in the energy range from 1.06 to 2.2 GeV and observe the production of a resonance at 1.67 GeV. We present the first measurements of the $e^+ e^-\\to K_S^0 K_L^0 \\pi^+\\pi^-$, $K_S^0 K_S^0 \\pi^+\\pi^-$, and $K_S^0 K_S^0 K^+K^-$ cross sections, and study the intermediate resonance structures. We obtain the first observations of \\jpsi decay to the $K_S^0 K_L^0 \\pi^+\\pi^-$, $K_S^0 K_S^0 \\pi^+\\pi^-$, and $K_S^0 K_S^0 K^+K^-$ final states.

The BABAR Collaboration; J. P. Lees

2014-03-29T23:59:59.000Z

152

Sustainable Carbon Sequestration: Increasing CO2-Storage Efficiency through a CO2-Brine Displacement Approach  

E-Print Network [OSTI]

CO2 sequestration is one of the proposed methods for reducing anthropogenic CO2 emissions to the atmosphere and therefore mitigating global climate change. Few studies on storing CO2 in an aquifer have been conducted on a regional scale. This study...

Akinnikawe, Oyewande

2012-10-19T23:59:59.000Z

153

A Multi-Model Analysis of the Regional and Sectoral Roles of Bioenergy in Near- and Long-Term CO2 Emissions  

SciTech Connect (OSTI)

We study the near term and the longer term the contribution of bioenergy in different LIMITS scenarios as modeled by the participating models in the LIMITS project. With These scenarios have proven useful for exploring a range of outcomes for bioenergy use in response to both regionally diverse near term policies and the transition to a longer-term global mitigation policy and target. The use of several models has provided a source of heterogeneity in terms of incorporating uncertain assumptions about future socioeconomics and technology, as well as different paradigms for how the world may respond to policies. The results have also highlighted the heterogeneity and versatility of bioenergy itself, with different types of resources and applications in several energy sectors. In large part due to this versatility, the contribution of bioenergy to climate mitigation is a robust response across all models, despite their differences.

Calvin, Katherine V.; Wise, Marshall A.; Klein, David; McCollum, David; Tavoni, Massimo; van der Zwaan, Bob; Van Vuuren, Detlef

2013-11-01T23:59:59.000Z

154

Molecular Dynamics Simulations of CO2 Formation in Interstellar Ices  

E-Print Network [OSTI]

CO2 ice is one of the most abundant components in ice-coated interstellar ices besides H2O and CO, but the most favorable path to CO2 ice is still unclear. Molecular dynamics calculations on the ultraviolet photodissociation of different kinds of CO-H2O ice systems have been performed at 10 K in order to demonstrate that the reaction between CO and an OH molecule resulting from H2O photodissociation through the first excited state is a possible route to form CO2 ice. However, our calculations, which take into account different ice surface models, suggest that there is another product with a higher formation probability ((3.00+-0.07)x10-2), which is the HOCO complex, whereas the formation of CO2 has a probability of only (3.6+-0.7)x10-4. The initial location of the CO is key to obtain reaction and form CO2: the CO needs to be located deep into the ice. The HOCO complex becomes trapped in the cold ice surface in the trans-HOCO minimum because it quickly loses its internal energy to the surrounding ice, preventi...

Arasa, Carina; van Dishoeck, Ewine F; Kroes, Geert-Jan

2013-01-01T23:59:59.000Z

155

Reference Inside KS1992 Tray Inside Air  

E-Print Network [OSTI]

Reference Inside KS1992 0.2 Tray Inside Air 0.5 Tray Inside Air 0.8 Tray Inside Air 0.2 Tray Side Wall Inner 0.2 Tray Side Wall Inner Under TAMP near sensor pos4 Under TAMP near sensor pos4 Air Gap Below TDIG pos1 Air Gap Below TDIG pos4 Air Gap Below TDIG pos6 HPTDC1 Chip pos6 HPTDC4 Chip pos6 HPTDC2

Llope, William J.

156

The contribution of CO2 capture and storage  

E-Print Network [OSTI]

The contribution of CO2 capture and storage to a sustainable energy system Policy brief of Energy Models for INtegrated Technology Systems' is partially funded by the EU under the Scientific.html. The following partners are involved in Part 2 of the CASCADE MINTS project: · Energy research Centre

157

Reactive transport modeling to study changes in water chemistry induced by CO2 injection at the Frio-I brine pilot  

SciTech Connect (OSTI)

To demonstrate the potential for geologic storage of CO{sub 2} in saline aquifers, the Frio-I Brine Pilot was conducted, during which 1600 tons of CO{sub 2} were injected into a high-permeability sandstone and the resulting subsurface plume of CO{sub 2} was monitored using a variety of hydrogeological, geophysical, and geochemical techniques. Fluid samples were obtained before CO{sub 2} injection for baseline geochemical characterization, during the CO{sub 2} injection to track its breakthrough at a nearby observation well, and after injection to investigate changes in fluid composition and potential leakage into an overlying zone. Following CO{sub 2} breakthrough at the observation well, brine samples showed sharp drops in pH, pronounced increases in HCO{sub 3}{sup -} and aqueous Fe, and significant shifts in the isotopic compositions of H{sub 2}O and dissolved inorganic carbon. Based on a calibrated 1-D radial flow model, reactive transport modeling was performed for the Frio-I Brine Pilot. A simple kinetic model of Fe release from the solid to aqueous phase was developed, which can reproduce the observed increases in aqueous Fe concentration. Brine samples collected after half a year had lower Fe concentrations due to carbonate precipitation, and this trend can be also captured by our modeling. The paper provides a method for estimating potential mobile Fe inventory, and its bounding concentration in the storage formation from limited observation data. Long-term simulations show that the CO{sub 2} plume gradually spreads outward due to capillary forces, and the gas saturation gradually decreases due to its dissolution and precipitation of carbonates. The gas phase is predicted to disappear after 500 years. Elevated aqueous CO{sub 2} concentrations remain for a longer time, but eventually decrease due to carbonate precipitation. For the Frio-I Brine Pilot, all injected CO{sub 2} could ultimately be sequestered as carbonate minerals.

Kharaka, Y.K; Doughty, C.; Freifeld, B.M.; Daley, T.M.; Xu, T.

2009-11-01T23:59:59.000Z

158

An integrated experimental and numerical study: Developing a reaction transport model that couples chemical reactions of mineral dissolution/precipitation with spatial and temporal flow variations in CO2/brine/rock systems  

Broader source: Energy.gov [DOE]

Project objectives: Generate and characterize mineral dissolution/precipitation reactions in supercritical CO2/brine/rock systems under pressure-temperature-chemistry conditions resembling CO2injection into EGS. Characterize three-dimensional spatial and temporal distributions of rock structures subject to mineral dissolution/precipitation processes by X-ray tomography, SEM imaging, and Microprobe analysis.

159

Development and validation of a radial inflow turbine model for simulation of the SNL S-CO2 split-flow loop.  

SciTech Connect (OSTI)

A one-dimensional model for a radial inflow turbine has been developed for super-critical carbon dioxide (S-CO{sub 2}) Brayton cycle applications. The model accounts for the main phenomena present in the volute, nozzle, and impeller of a single-stage turbine. These phenomena include internal losses due to friction, blade loading, and angle of incidence and parasitic losses due to windage and blade-housing leakage. The model has been added as a component to the G-PASS plant systems code. The model was developed to support the analysis of S-CO{sub 2} cycles in conjunction with small-scale loop experiments. Such loops operate at less than a MWt thermal input. Their size permits components to be reconfigured in new arrangements relatively easily and economically. However, the small thermal input combined with the properties of carbon dioxide lead to turbomachines with impeller diameters of only one to two inches. At these sizes the dominant phenomena differ from those in larger more typical machines. There is almost no treatment in the literature of turbomachines at these sizes. The present work therefore is aimed at developing turbomachine models that support the task of S-CO{sub 2} cycle analysis using small-scale tests. Model predictions were compared against data from an experiment performed for Sandia National Laboratories in the split-flow Brayton cycle loop currently located at Barber-Nichols Inc. The split-flow loop incorporates two turbo-alternator-compressor (TAC) units each incorporating a radial inflow turbine and a radial flow compressor on a common shaft. The predicted thermodynamic conditions at the outlet of the turbine on the main compressor shaft were compared with measured values at different shaft speeds. Two modifications to the original model were needed to better match the experiment data. First, a representation of the heat loss from the volute downstream of the sensed inlet temperature was added. Second, an empirical multiplicative factor was applied to the Euler head and another to the head loss to bring the predicted outlet pressure into better agreement with the experiment. These changes also brought the overall efficiency of the turbine into agreement with values cited by Barber Nichols for small turbines. More generally, the quality of measurement set data can in the future be improved by additional steps taken in the design and operation of the experimental apparatus. First, a thermocouple mounted at the nozzle inlet would provide a better indication of temperature at this key point. Second, heat losses from the turbine should be measured directly. Allowing the impeller to free wheel at inlet conditions and measuring the temperature drop between inlet and outlet would provide a more accurate measure of heat loss. Finally, the enthalpy change during operation is more accurately obtained by measuring the torque on the stator using strain gauges rather than by measuring pressure and temperature at inlet and outlet to infer thermodynamic states.

Vilim, R. B. (Nuclear Engineering Division)

2012-07-31T23:59:59.000Z

160

Prospects for Subsurface CO2 Sequestration  

E-Print Network [OSTI]

to be around 28 Gigatons. For the last few centuries prior to the industrial revolution, the average atmospheric CO2 concentra- tion was about 280 ppm.2 Since the onset of the industrial rev- olution, there has

Firoozabadi, Abbas

Note: This page contains sample records for the topic "ks modeling co2" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Numerical simulation of leakage from a geologic disposal reservoirfor CO2, with transitions between super- and sub-criticalconditions  

SciTech Connect (OSTI)

The critical point of CO2 is at temperature and pressureconditions of Tcrit = 31.04oC, Pcrit = 73.82 bar. At lower (subcritical)temperatures and/or pressures, CO2 can exist in two different phases, aliquid and a gaseous state, as well as in two-phase mixtures of thesestates. Disposal of CO2 into brine formations would be made atsupercritical pressures. However, CO2 escaping from the storage reservoirmay migrate upwards towards regions with lower temperatures andpressures, where CO2 would be in subcritical conditions. An assessment ofthe fate of leaking CO2 requires a capability to model not onlysupercritical but also subcritical CO2, as well as phase changes betweenliquid and gaseous CO2 in sub-critical conditions. We have developed amethodology for numerically simulating the behavior of water-CO2 mixturesin permeable media under conditions that may include liquid, gaseous, andsupercritical CO2. This has been applied to simulations of leakage from adeep storage reservoir in which a rising CO2 plume undergoes transitionsfrom supercritical to subcritical conditions. We find strong coolingeffects when liquid CO2 rises to elevations where it begins to boil andevolve a gaseous CO2 phase. A three-phase zone forms (aqueous - liquid -gas), which over time becomes several hundred meters thick as decreasingtemperatures permit liquid CO2 to advance to shallower elevations. Fluidmobilities are reduced in the three-phase region from phase interferenceeffects. This impedes CO2 upflow, causes the plume to spread outlaterally, and gives rise to dispersed CO2 discharge at the land surface.Our simulations suggest that temperatures along a CO2 leakage path maydecline to levels low enough so that solid water ice and CO2 hydratephases may be formed.

Pruess, Karsten

2003-04-13T23:59:59.000Z

162

PLAINS CO2 REDUCTION PARTNERSHIP  

SciTech Connect (OSTI)

The PCOR Partnership continues to make great progress. Task 2 (Deployment Issues) activities have focused on utilizing Dakota Gasification Company (DGC) experience and data with respect to DGC participation in the enhanced oil recovery project at Weyburn, Saskatchewan. A solid line of communication has been developed with the Interstate Oil & Gas Compact Commission (IOGCC) for the mutual benefit of the PCOR Partnership and IOGCC's complementary efforts. Task 3 (Public Education and Outreach) activities have focused on developing a foundation of background materials in order to avoid a duplication of efforts and provide the best outreach and educational materials possible. Progress in Task 4 (Characterization and Evaluation) has included the development of a database format, the preliminary collection of data regarding CO{sub 2} sources and sinks, and data on the performance and costs for CO{sub 2} separation, capture, treatment, and compression for pipeline transportation. Task 5 (Modeling and Phase II Action Plans) activities have resulted in a conceptual model for screening and qualitatively assessing sequestration options. Task 5 activities have also been useful in structuring data collection and other activities in Tasks 2, 3, and 5.

Thomas A. Erickson

2004-04-01T23:59:59.000Z

163

Version 3.0 SOP 4 --p(CO2) October 12, 2007 (p(CO2))  

E-Print Network [OSTI]

Version 3.0 SOP 4 -- p(CO2) October 12, 2007 91 SOP 4 (p(CO2)) - 1. . microatmospheres . (20°C 250-2000 µatm) (mole fraction) . 2. CO2 (mole fraction) . 2 2(CO ) (CO( ) . . Frit . #12;October 12, 2007 SOP 4 -- p(CO2) Version 3.0 92 CO2 CO2 2 . p(CO2) (1) . 4. 3

164

Numerical modeling of injection and mineral trapping of CO2 withH2S and SO2 in a Sandstone Formation  

SciTech Connect (OSTI)

Carbon dioxide (CO{sub 2}) injection into deep geologic formations could decrease the atmospheric accumulation of this gas from anthropogenic sources. Furthermore, by co-injecting H{sub 2}S or SO{sub 2}, the products respectively of coal gasification or combustion, with captured CO{sub 2}, problems associated with surface disposal would be mitigated. We developed models that simulate the co-injection of H{sub 2}S or SO{sub 2} with CO{sub 2} into an arkose formation at a depth of about 2 km and 75 C. The hydrogeology and mineralogy of the injected formation are typical of those encountered in Gulf Coast aquifers of the United States. Six numerical simulations of a simplified 1-D radial region surrounding the injection well were performed. The injection of CO{sub 2} alone or co-injection with SO{sub 2} or H{sub 2}S results in a concentrically zoned distribution of secondary minerals surrounding a leached and acidified region adjacent to the injection well. Co-injection of SO{sub 2} with CO{sub 2} results in a larger and more strongly acidified zone, and alteration differs substantially from that caused by the co-injection of H{sub 2}S or injection of CO{sub 2} alone. Precipitation of carbonates occurs within a higher pH (pH > 5) peripheral zone. Significant quantities of CO{sub 2} are sequestered by ankerite, dawsonite, and lesser siderite. The CO{sub 2} mineral-trapping capacity of the formation can attain 40-50 kg/m{sup 3} medium for the selected arkose. In contrast, secondary sulfates precipitate at lower pH (pH < 5) within the acidified zone. Most of the injected SO{sub 2} is transformed and immobilized through alunite precipitation with lesser amounts of anhydrite and minor quantities of pyrite. The dissolved CO{sub 2} increases with time (enhanced solubility trapping). The mineral alteration induced by injection of CO{sub 2} with either SO{sub 2} or H{sub 2}S leads to corresponding changes in porosity. Significant increases in porosity occur in the acidified zones where mineral dissolution dominates. With co-injection of SO{sub 2}, the porosity increases from an initial 0.3 to 0.43 after 100 years. However, within the CO{sub 2} mineral-trapping zone, the porosity decreases to about 0.28 for both cases, because of the addition of CO{sub 2} mass as secondary carbonates to the rock matrix. Precipitation of sulfates at the acidification front causes porosity to decrease to 0.23. The limited information currently available on the mineralogy of naturally occurring high-pressure CO{sub 2} reservoirs is generally consistent with our simulations.

Xu, Tianfu; Apps, John A.; Pruess, Karsten; Yamamoto, Hajime

2004-09-07T23:59:59.000Z

165

PLAINS CO2 REDUCTION PARTNERSHIP  

SciTech Connect (OSTI)

The Plains Co{sub 2} Reduction (PCOR) Partnership continues to make great progress. Task 2 (Technology Deployment) activities have focused on developing information on deployment issues to support Task 5 activities by providing information to be used to assess CO{sub 2} sequestration opportunities in the PCOR Partnership region. Task 3 (Public Outreach) activities have focused on developing an informational video about CO{sub 2} sequestration. Progress in Task 4 (Sources, Sinks, and Infrastructure) has included the continued collection of data regarding CO{sub 2} sources and sinks and data on the performance and costs for CO{sub 2} separation, capture, treatment, and compression for pipeline transportation. Task 5 (Modeling and Phase II Action Plans) activities have focused on screening and qualitatively assessing sequestration options. Task 5 activities also continue to be useful in structuring data collection and other activities in Tasks 2, 3, and 5.

Edward N. Steadman

2004-07-01T23:59:59.000Z

166

PLAINS CO2 REDUCTION PARTNERSHIP  

SciTech Connect (OSTI)

The Plains CO{sub 2} Reduction (PCOR) Partnership continues to make great progress. Task 2 (Technology Deployment) focused on developing information regarding deployment issues to support Task 5 (Modeling and Phase II Action Plans) by providing information to be used to assess CO{sub 2} sequestration opportunities in the PCOR Partnership region. Task 3 (Public Outreach) focused on developing an informational video about CO{sub 2} sequestration. Progress in Task 4 (Sources, Sinks, and Infrastructure) included the continued collection of data regarding CO{sub 2} sources and sinks and data on the performance and costs for CO{sub 2} separation, capture, treatment, and compression for pipeline transportation. Task 5 focused on screening and qualitatively assessing sequestration options. Task 5 activities also continue to be useful in structuring data collection and other activities in Tasks 2, 3, and 5.

Edward N. Steadman; John A. Harju; Erin M. O'Leary; James A. Sorensen; Daniel J. Daly; Melanie D. Jensen; Thea E. Reikoff

2005-01-01T23:59:59.000Z

167

Atmospheric CO2 concentrations during ancient greenhouse climates were similar  

E-Print Network [OSTI]

Atmospheric CO2 concentrations during ancient greenhouse climates were similar to those predicted atmospheric CO2 concentrations (½CO2atm) during Earth's ancient greenhouse episodes is essential for accurately predicting the response of future climate to elevated CO2 levels. Empirical estimates of ½CO2atm

Ahmad, Sajjad

168

Category:Wichita, KS | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of InspectorConcentrating SolarElectricEnergyCTBarreis aCallahanWindSyracuse, NY JumpKS" The following 16

169

Assessment of Basin-Scale Hydrologic Impacts of CO2 Sequestration, Illinois Basin1 Mark Person*1  

E-Print Network [OSTI]

: Mount Simon, Illinois Basin, CO2, earthquakes, pressure, brine transport69 #12;Page | 3 1. IntroductionPage | 1 Assessment of Basin-Scale Hydrologic Impacts of CO2 Sequestration, Illinois Basin1 2 3 4 sharp-interface models of CO2 injection were constructed for the Illinois49 Basin in which porosity

Gable, Carl W.

170

PLAINS CO2 REDUCTION PARTNERSHIP  

SciTech Connect (OSTI)

The Plains CO{sub 2} Reduction (PCOR) Partnership characterization work is nearing completion, and most remaining efforts are related to finalizing work products. Task 2 (Technology Deployment) has developed a Topical Report entitled ''Deployment Issues Related to Geologic CO{sub 2} Sequestration in the PCOR Partnership Region''. Task 3 (Public Outreach) has developed an informational Public Television program entitled ''Nature in the Balance'', about CO{sub 2} sequestration. The program was completed and aired on Prairie Public Television in this quarter. Task 4 (Sources, Sinks, and Infrastructure) efforts are nearing completion, and data regarding CO{sub 2} sources and sinks and data on the performance and costs for CO{sub 2} separation, capture, treatment, and compression for pipeline transportation are being incorporated into a series of topical reports. The expansion of the Decision Support System Geographic Information System database has continued with the development of a ''save bookmark'' feature that allows users to save a map from the system easily. A feature that allows users to develop a report that summarizes CO{sub 2} sequestration parameters was also developed. Task 5 (Modeling and Phase II Action Plans) focused on screening and qualitatively assessing sequestration options and developing economic estimates for important regional CO{sub 2} sequestration strategies.

Edward N. Steadman; John A. Harju; Erin M. O'Leary; James A. Sorensen; Daniel J. Daly; Melanie D. Jensen; Lisa S. Botnen

2005-07-01T23:59:59.000Z

171

PLAINS CO2 REDUCTION PARTNERSHIP  

SciTech Connect (OSTI)

The PCOR Partnership is off to a very exciting and ambitious start. Task 1 activities have included the planning and execution of an internal kickoff meeting, participation in the DOE's national kickoff meeting, and the planning and execution of the first meeting of the PCOR Partnership at the Energy & Environmental Research Center (EERC). Task 2 activities have focused on developing effective and critical partnerships. A plan has been developed to utilize Dakota Gasification Company's (DGC) experience and data with respect to their participation in the enhanced oil recovery project at Weyburn, Saskatchewan. A solid line of communication has been developed with the Interstate Oil & Gas Compact Commission (IOGCC) for the mutual benefit of the PCOR Partnership and IOGCC's compensatory efforts. Task 3 activities have been focused on developing a foundation of background materials in order to avoid a duplication of efforts and provide the best outreach and educational materials possible. Progress in Task 4, Characterization and Evaluation, has included the development of a database format, the preliminary collection of data regarding CO{sub 2} sources and sinks, and data on the performance and costs for CO{sub 2} separation, capture, and treatment to prepare the fluid for pipeline transportation. Task 5 activities have resulted in a conceptual model for screening and qualitatively assessing sequestration options. Task 5 activities have also been useful in structuring data collection and other activities in Tasks 2, 3, and 5.

Thomas A. Erickson

2004-01-01T23:59:59.000Z

172

Growth, CO2 Consumption, and H2 Production of Anabaena variabilis ATCC 29413-U under Different Irradiances and CO2 Concentrations  

E-Print Network [OSTI]

Phase Medium Irradiance ? H2 ? CO2 Maximum Reported Ratesa) Specific CO 2 uptake rate, ? CO2 (kg CO 2 /kg dry cell/h)

Berberoglu, Halil; Barra, Natasha; Pilon, Laurent; Jay, Jenny

2008-01-01T23:59:59.000Z

173

The Effects of CO2 Abatement Policies on Power System Expansion  

E-Print Network [OSTI]

The Effects of CO2 Abatement Policies on Power System Expansion by Conrad Fox B.Sc.E., Queens means, without the permission of the author. #12;ii The Effects of CO2 Abatement Policies on Power abatement policies. The model proposes a novel approach for incorporating investment in non- #12;iv

Victoria, University of

174

Heterogeneous capital stocks and the optimal timing for CO2 abatement  

E-Print Network [OSTI]

Heterogeneous capital stocks and the optimal timing for CO2 abatement Mark Jaccard *, Nic Rivers a model and empirically estimated abatement costs. The results suggest that under many different assumptions, an early start at CO2 abatement for long-lived capital stocks would be economically optimal

175

Remediation of CO2 Leakage from Deep Saline Aquifer Storage Based on Reservoir and Pollution  

E-Print Network [OSTI]

and of the Council of 23 April 2009 on the geological storage of carbon dioxide IEA-GHG, 2007. Remediation of Leakage from CO2 Storage Reservoirs. IEA Greenhouse Gas R&D Programme, 2007/11, September 2007. Le Guenan T : review and modelling., in CO2NET 2009 Annual Seminar Agenda - Trondheim - Norway - 18-19 June 2009. Xu T

Paris-Sud XI, Université de

176

Micromodel Investigations of CO2 Exsolution from Carbonated Water...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Micromodel Investigations of CO2 Exsolution from Carbonated Water in Sedimentary Rocks. Micromodel Investigations of CO2 Exsolution from Carbonated Water in Sedimentary Rocks....

177

Cryogenic CO2 Formation on Oxidized Gold Clusters Synthesized...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Cryogenic CO2 Formation on Oxidized Gold Clusters Synthesized via Reactive Layer Assisted Deposition. Cryogenic CO2 Formation on Oxidized Gold Clusters Synthesized via Reactive...

178

Exsolution Enhanced Oil Recovery with Concurrent CO2 Sequestration...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Exsolution Enhanced Oil Recovery with Concurrent CO2 Sequestration. Exsolution Enhanced Oil Recovery with Concurrent CO2 Sequestration. Abstract: A novel EOR method using...

179

Reaction of Water-Saturated Supercritical CO2 with Forsterite...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Water-Saturated Supercritical CO2 with Forsterite: Evidence for Magnesite Formation at Low Temperatures. Reaction of Water-Saturated Supercritical CO2 with Forsterite: Evidence for...

180

Summary Report on CO2 Geologic Sequestration & Water Resources Workshop  

E-Print Network [OSTI]

F Monitoring studies above EOR-CO2 fields Weyburn-MidaleTexas •? Over 30 years of CO2-EOR •? Sampled outside of

Varadharajan, C.

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "ks modeling co2" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Potential method for measurement of CO2 leakage from underground sequestration fields using radioactive tracers  

SciTech Connect (OSTI)

Reduction of anthropogenic carbon dioxide (CO2) release to the environment is a pressing challenge that should be addressed to avert the potential devastating effects of global warming. Within the United States, the most abundant sources of CO2 emissions are those generate from coal- or gas-fired power plants; one method to control CO2 emissions is to sequester it in deep underground geological formations. From integrated assessment models the overall leakage rates from these storage locations must be less than 0.1% of stored volume per year for long-term control. The ability to detect and characterize nascent leaks, in conjunction with subsequent remediation efforts, will significantly decrease the amount of CO2 released back into the environment. Because potential leakage pathways are not necessarily known a priori, onsite monitoring must be performed; the monitoring region in the vicinity of a CO2 injection well may be as large as 100 km2, which represents the estimated size of a supercritical CO2 bubble that would form under typical injection scenarios. By spiking the injected CO2 with a radiological or stable isotope tracer, it will be possible to detect ground leaks from the sequestered CO2 using fewer sampling stations, with greater accuracy than would be possible using simple CO2 sensors. The relative merits of various sorbent materials, radiological and stable isotope tracers, detection methods and potential interferences will be discussed.

Bachelor, Paula P.; McIntyre, Justin I.; Amonette, James E.; Hayes, James C.; Milbrath, Brian D.; Saripalli, Prasad

2008-07-01T23:59:59.000Z

182

Assessing the health risks of natural CO2 seeps in Italy  

SciTech Connect (OSTI)

Industrialized societies which continue to use fossil fuel energy sources are considering adoption of Carbon Capture and Storage (CCS) technology to meet carbon emission reduction targets. Deep geological storage of CO2 onshore faces opposition regarding potential health effects of CO2 leakage from storage sites. There is no experience of commercial scale CCS with which to verify predicted risks of engineered storage failure. Studying risk from natural CO2 seeps can guide assessment of potential health risks from leaking onshore CO2 stores. Italy and Sicily are regions of intense natural CO2 degassing from surface seeps. These seeps exhibit a variety of expressions, characteristics (e.g., temperature/ flux), and location environments. Here we quantify historical fatalities from CO2 poisoning using a database of 286 natural CO2 seeps in Italy and Sicily. We find that risk of human death is strongly influenced by seep surface expression, local conditions (e.g., topography and wind speed), CO2 flux, and human behavior. Risk of accidental human death from these CO2 seeps is calculated to be 10-8 year-1 to the exposed population. This value is significantly lower than that of many socially accepted risks. Seepage from future storage sites is modeled to be less than Italian natural flux rates. With appropriate hazard management, health risks from unplanned seepage at onshore storage sites can be adequately minimized.

Roberts, J.J.; Wood, R.A.; Haszeldine, R.S. [Scottish Carbon Capture and Storage, School of GeoSciences, Grant Institute, University of Edinburgh, West Mains Road, Edinburgh EH9 3JW, Scotland (United Kingdom)

2011-10-04T23:59:59.000Z

183

Near-Surface CO2 Monitoring And Analysis To Detect Hidden Geothermal Systems  

SciTech Connect (OSTI)

''Hidden'' geothermal systems are systems devoid of obvious surface hydrothermal manifestations. Emissions of moderate-to-low solubility gases may be one of the primary near-surface signals from these systems. We investigate the potential for CO2 detection and monitoring below and above ground in the near-surface environment as an approach to exploration targeting hidden geothermal systems. We focus on CO2 because it is the dominant noncondensible gas species in most geothermal systems and has moderate solubility in water. We carried out numerical simulations of a CO2 migration scenario to calculate the magnitude of expected fluxes and concentrations. Our results show that CO2 concentrations can reach high levels in the shallow subsurface even for relatively low geothermal source CO2 fluxes. However, once CO2 seeps out of the ground into the atmospheric surface layer, winds are effective at dispersing CO2 seepage. In natural ecological systems in the absence of geothermal gas emissions, near-surface CO2 fluxes and concentrations are predominantly controlled by CO2 uptake by photosynthesis, production by root respiration, microbial decomposition of soil/subsoil organic matter, groundwater degassing, and exchange with the atmosphere. Available technologies for monitoring CO2 in the near-surface environment include the infrared gas analyzer, the accumulation chamber method, the eddy covariance method, hyperspectral imaging, and light detection and ranging. To meet the challenge of detecting potentially small-magnitude geothermal CO2 emissions within the natural background variability of CO2, we propose an approach that integrates available detection and monitoring techniques with statistical analysis and modeling strategies. The proposed monitoring plan initially focuses on rapid, economical, reliable measurements of CO2 subsurface concentrations and surface fluxes and statistical analysis of the collected data. Based on this analysis, are as with a high probability of containing geothermal CO2 anomalies can be further sampled and analyzed using more expensive chemical and isotopic methods. Integrated analysis of all measurements will determine definitively if CO2 derived from a deep geothermal source is present, and if so, the spatial extent of the anomaly. The suitability of further geophysical measurements, installation of deep wells, and geochemical analyses of deep fluids can then be determined based on the results of the near surface CO2 monitoring program.

Lewicki, Jennifer L.; Oldenburg, Curtis M.

2005-01-19T23:59:59.000Z

184

Aquifer Management for CO2 Sequestration  

E-Print Network [OSTI]

Storage of carbon dioxide is being actively considered for the reduction of green house gases. To make an impact on the environment CO2 should be put away on the scale of gigatonnes per annum. The storage capacity of deep saline aquifers...

Anchliya, Abhishek

2010-07-14T23:59:59.000Z

185

Porous Hexacyanometalates for CO2 capture applications  

SciTech Connect (OSTI)

Prussian blue analogues of M3[Fe(CN)6]2 x H2O (where M=Fe, Mn and Ni) were synthesized, characterized and tested for their gas sorption capabilities. The sorption studies reveal that, these Prussian blue materials preferentially sorb CO2 over N2 and CH4 at low pressure (1bar).

Motkuri, Radha K.; Thallapally, Praveen K.; McGrail, B. Peter

2013-07-30T23:59:59.000Z

186

Projecting human development and CO2 emissions  

E-Print Network [OSTI]

We estimate cumulative CO2 emissions during the period 2000 to 2050 from developed and developing countries based on the empirical relationship between CO2 per capita emissions (due to fossil fuel combustion and cement production) and corresponding HDI. In order to project per capita emissions of individual countries we make three assumptions which are detailed below. First, we use logistic regressions to fit and extrapolate the HDI on a country level as a function of time. This is mainly motivated by the fact that the HDI is bounded between 0 and 1 and that it decelerates as it approaches 1. Second, we employ for individual countries the correlations between CO2 per capita emissions and HDI in order to extrapolate their emissions. This is an ergodic assumption. Third, we let countries with incomplete data records evolve similarly as their close neighbors (in the emissions-HDI plane, see Fig. 1 in the main text) with complete time series of CO2 per capita emissions and HDI. Country-based emissions estimates a...

Costa, Luís; Kropp, Jürgen P

2012-01-01T23:59:59.000Z

187

Well Technologies for CO2 Geological Storage: CO2-Resistant Cement  

E-Print Network [OSTI]

Résumé — Technologies de puits pour le stockage géologique du CO2: ciment résistant au CO2 — Le stockage souterrain du CO2 est actuellement considéré comme la voie la plus efficace pour une séquestration sure et à faible coût. Cette nouvelle application exige une étanchéité du puits à très long terme. La rupture de la gaine de ciment dans l’intervalle entre le cuvelage et la formation géologique peut créer des chemins préférentiels favorisant la fuite du CO2 vers la surface avec des vitesses probablement supérieures à celles pouvant être provoquées par les fuites au travers des formations géologiques. Il en résultera une perte économique, une réduction de l’efficacité du stockage de CO2 et la remise en cause du champ pour le stockage de CO2. Ce risque potentiel de fuites soulève des questions quant à la bonne iso-lation du puits à long terme et à la durabilité du ciment hydraté utilisé pour isoler l’annulaire entre les intervalles de production et d’injection dans les puits de CO2. Nous proposons une nouvelle procédure expérimentale et une méthodologie pour étudier la réactivité des systèmes CO2-Eau-Ciment en simulant les interactions du ciment pris avec le CO2 injecté à l’état supercritique dans des conditions de fond de puits. Les conditions utilisées pour ces expériences sont de 90ºC et 280 bars. L’évolution des propriétés mécaniques et physico-chimiques du ciment Portland est mesurée dans le temps sur une période maxi-male de six mois. Les résultats sont comparés à ceux obtenus par une étude similaire sur un nouveau

V. Barlet-gouédard; G. Rimmelé; B. Goffé; O. Porcherie

188

Synthesis, characterization and performance of single-component CO2-binding organic liquids (CO2BOL) for post combustion CO2 capture  

SciTech Connect (OSTI)

Carbon dioxide (CO2) emission to the atmosphere will increase significantly with the shift to coal powered plants for energy generation. This increase in CO2 emission will contribute to climate change. There is need to capture and sequester large amounts of CO2 emitted from these coal power plants in order to mitigate the environmental effects. Here we report the synthesis, characterization and system performance of multiple third generation CO2 binding organic liquids (CO2BOLs) as a solvent system for post combustion gas capture. Alkanolguanidines and alkanolamidines are single component CO2BOLs that reversibly bind CO2 chemically as liquid zwitterionic amidinium / guanidinium alkylcarbonates. Three different alkanolguanidines and alkanolamidines were synthesized and studied for CO2 capacity and binding energetics. Solvent performance of these three CO2BOLs was evaluated by batch-wise CO2 uptake and release over multiple cycles. Synthesis of CO2BOLs, characterization, CO2 uptake, selectivity towards CO2 as well as solvent tolerance to water will be discussed.

Koech, Phillip K.; Heldebrant, David J.; Rainbolt, James E.; Zheng, Feng; Smurthwaite, Tricia D.

2010-03-31T23:59:59.000Z

189

Simulation of Coupled Processes of Flow, Transport, and Storage of CO2 in Saline Aquifers  

SciTech Connect (OSTI)

This report is the final scientific one for the award DE- FE0000988 entitled “Simulation of Coupled Processes of Flow, Transport, and Storage of CO2 in Saline Aquifers.” The work has been divided into six tasks. In task, “Development of a Three-Phase Non-Isothermal CO2 Flow Module,” we developed a fluid property module for brine-CO2 mixtures designed to handle all possible phase combinations of aqueous phase, sub-critical liquid and gaseous CO2, supercritical CO2, and solid salt. The thermodynamic and thermophysical properties of brine-CO2 mixtures (density, viscosity, and specific enthalpy of fluid phases; partitioning of mass components among the different phases) use the same correlations as an earlier fluid property module that does not distinguish between gaseous and liquid CO2-rich phases. We verified the fluid property module using two leakage scenarios, one that involves CO2 migration up a blind fault and subsequent accumulation in a secondary “parasitic” reservoir at shallower depth, and another investigating leakage of CO2 from a deep storage reservoir along a vertical fault zone. In task, “Development of a Rock Mechanical Module,” we developed a massively parallel reservoir simulator for modeling THM processes in porous media brine aquifers. We derived, from the fundamental equations describing deformation of porous elastic media, a momentum conservation equation relating mean stress, pressure, and temperature, and incorporated it alongside the mass and energy conservation equations from the TOUGH2 formulation, the starting point for the simulator. In addition, rock properties, namely permeability and porosity, are functions of effective stress and other variables that are obtained from the literature. We verified the simulator formulation and numerical implementation using analytical solutions and example problems from the literature. For the former, we matched a one-dimensional consolidation problem and a two-dimensional simulation of the Mandel-Cryer effect. For the latter, we obtained a good match of temperature and gas saturation profiles, and surface uplift, after injection of hot fluid into a model of a caldera structure. In task, “Incorporation of Geochemical Reactions of Selected Important Species,” we developed a novel mathematical model of THMC processes in porous and fractured saline aquifers, simulating geo-chemical reactions associated with CO2 sequestration in saline aquifers. Two computational frameworks, sequentially coupled and fully coupled, were used to simulate the reactions and transport. We verified capabilities of the THMC model to treat complex THMC processes during CO2 sequestration by analytical solutions and we constructed reactive transport models to analyze the THMC process quantitatively. Three of these are 1D reactive transport under chemical equilibrium, a batch reaction model with equilibrium chemical reactions, and a THMC model with CO2 dissolution. In task “Study of Instability in CO2 Dissolution-Diffusion-Convection Processes,” We reviewed literature related to the study of density driven convective flows and on the instability of CO2 dissolution-diffusion-convection processes. We ran simulations that model the density-driven flow instability that would occur during CO2 sequestration. CO2 diffused through the top of the system and dissolved in the aqueous phase there, increasing its density. Density fingers formed along the top boundary, and coalesced into a few prominent ones, causing convective flow that forced the fluid to the system bottom. These simulations were in two and three dimensions. We ran additional simulations of convective mixing with density contrast caused by variable dissolved CO2 concentration in saline water, modeled after laboratory experiments in which supercritical CO2 was circulated in the headspace above a brine saturated packed sand in a pressure vessel. As CO2 dissolved into the upper part of the saturated sand, liquid phase density increases causing instability and setting off convective mixing. We obtained good agreement

Wu, Yu-Shu; Chen, Zizhong; Kazemi, Hossein; Yin, Xiaolong; Pruess, Karsten; Oldenburg, Curt; Winterfeld, Philip; Zhang, Ronglei

2014-09-30T23:59:59.000Z

190

CO2 as a raw material for chemistry : an  

E-Print Network [OSTI]

intermediates from biomass · CO2 accelerates production of biomass · Ex microalgae biofuel, chemicals, .. · Ex

Canet, Léonie

191

CO2 enrichment increases carbon and nitrogen input from  

E-Print Network [OSTI]

CO2 enrichment increases carbon and nitrogen input from fine roots in a deciduous forest Colleen2 Ecological Society of America, 2008 #12;#12;#12;#12;#12;+ [CO2] #12;+ Net primary production + [CO2] #12;+ Net primary production + [CO2] + C and N storage in biomass #12;+ Net primary production

192

Original article Limitation of photosynthetic activity by CO2  

E-Print Network [OSTI]

Original article Limitation of photosynthetic activity by CO2 availability in the chloroplasts to resistances opposing the CO2 fluxes in the mesophyll of tree leaves. To validate this assertion, values of CO2 CO2 assimilation and respiration rate measurement, and using the known electron requirements (four

Paris-Sud XI, Université de

193

Cost Assessment of CO2 Sequestration by Mineral Carbonation  

E-Print Network [OSTI]

Cost Assessment of CO2 Sequestration by Mineral Carbonation Frank E. Yeboah Tuncel M. Yegulalp Harmohindar Singh Research Associate Professor Professor Center for Energy Research... them carbon dioxide (CO 2 ). This paper assesses the cost of sequestering CO 2 produced by a ZEC power plant using solid sequestration process. INTRODUCTION CO 2 is produced when electrical energy is generated using conventional fossil...

Yeboah, F. E.; Yegulalp, T. M.; Singh, H.

2006-01-01T23:59:59.000Z

194

Laboratory and Field Experimental Studies of CO2 as Heat Transmission Fluid in Enhanced Geothermal Systems (EGS)  

Broader source: Energy.gov [DOE]

Project objectives: obtain basic information on the performance of CO2-based EGS; and enhance and calibrate modeling capabilities for such systems.

195

CO2 http://andrew.ucsd.edu/co2qc/ University of California, San Diego  

E-Print Network [OSTI]

by sublimation and the CO2 is transferred into an electronic constant-volume manometer [ECM]. There its pressure of total alkalinity. Marine Chemistry 80, 185­197). Nutrients Nutrient levels were determined using

196

The response of soil CO2 ux to changes in atmospheric CO2, nitrogen supply and plant diversity  

E-Print Network [OSTI]

three major anthropogenic global changes: atmos- pheric carbon dioxide (CO2) concentration, nitrogen (N atmospheric carbon dioxide (CO2) concentra- tions, increasing rates of nitrogen (N) deposition, and decliningThe response of soil CO2 ¯ux to changes in atmospheric CO2, nitrogen supply and plant diversity J O

Minnesota, University of

197

Study of CO2 Mobility Control Using Cross-linked Gel Conformance Control and CO2 Viscosifiers in Heterogeneous Media  

E-Print Network [OSTI]

result, early gas breakthrough has been a very common problem in CO2-related projects, reducing the overall sweep efficiency of CO2 flooding. This research aims at improving the CO2 flood efficiency using cross-linked gel conformance control and CO2...

Cai, Shuzong

2011-10-21T23:59:59.000Z

198

An estimate of monthly global emissions of anthropogenic CO2: Impact on the seasonal cycle of atmospheric CO2  

E-Print Network [OSTI]

An estimate of monthly global emissions of anthropogenic CO2: Impact on the seasonal cycle of anthropogenic CO2 are presented. Approximating the seasonal CO2 emission cycle using a 2-harmonic Fourier series with regions of strong anthropogenic CO2 emissions. Citation: Erickson, D. J., III, R. T. Mills, J. Gregg, T. J

Hoffman, Forrest M.

199

Rigorous Screening Technology for Identifying Suitable CO2 Storage Sites II  

SciTech Connect (OSTI)

This report serves as the final technical report and users manual for the 'Rigorous Screening Technology for Identifying Suitable CO2 Storage Sites II SBIR project. Advanced Resources International has developed a screening tool by which users can technically screen, assess the storage capacity and quantify the costs of CO2 storage in four types of CO2 storage reservoirs. These include CO2-enhanced oil recovery reservoirs, depleted oil and gas fields (non-enhanced oil recovery candidates), deep coal seems that are amenable to CO2-enhanced methane recovery, and saline reservoirs. The screening function assessed whether the reservoir could likely serve as a safe, long-term CO2 storage reservoir. The storage capacity assessment uses rigorous reservoir simulation models to determine the timing, ultimate storage capacity, and potential for enhanced hydrocarbon recovery. Finally, the economic assessment function determines both the field-level and pipeline (transportation) costs for CO2 sequestration in a given reservoir. The screening tool has been peer reviewed at an Electrical Power Research Institute (EPRI) technical meeting in March 2009. A number of useful observations and recommendations emerged from the Workshop on the costs of CO2 transport and storage that could be readily incorporated into a commercial version of the Screening Tool in a Phase III SBIR.

George J. Koperna Jr.; Vello A. Kuuskraa; David E. Riestenberg; Aiysha Sultana; Tyler Van Leeuwen

2009-06-01T23:59:59.000Z

200

Continuous CO2 extractor and methods  

SciTech Connect (OSTI)

The purpose of this CRADA was to assist in technology transfer from Russia to the US and assist in development of the technology improvements and applications for use in the U.S. and worldwide. Over the period of this work, ORNL has facilitated design, development and demonstration of a low-pressure liquid extractor and development of initial design for high-pressure supercritical CO2 fluid extractor.

None listed

2010-06-15T23:59:59.000Z

Note: This page contains sample records for the topic "ks modeling co2" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

10-MW Supercritical-CO2 Turbine  

Broader source: Energy.gov [DOE]

This fact sheet describes a 10-megawatt supercritical carbon dioxide turbine project, awarded under the DOE's 2012 SunShot Concentrating Solar Power R&D award program. The research team, led by NREL, intends to showcase the turbomachinery for a new cycle—the supercritical carbon dioxide (s-CO2) Brayton cycle. The cycle is being optimized and tested at conditions representing dry cooling in desert environments, thereby accurately simulating real-world concentrating solar power system operating conditions.

202

A Review of Hazardous Chemical Species Associated with CO2 Capturefrom Coal-Fired Power Plants and Their Potential Fate in CO2 GeologicStorage  

SciTech Connect (OSTI)

Conventional coal-burning power plants are major contributors of excess CO2 to the atmospheric inventory. Because such plants are stationary, they are particularly amenable to CO2 capture and disposal by deep injection into confined geologic formations. However, the energy penalty for CO2 separation and compression is steep, and could lead to a 30-40 percent reduction in useable power output. Integrated gas combined cycle (IGCC) plants are thermodynamically more efficient, i.e.,produce less CO2 for a given power output, and are more suitable for CO2 capture. Therefore, if CO2 capture and deep subsurface disposal were to be considered seriously, the preferred approach would be to build replacement IGCC plants with integrated CO2 capture, rather than retrofit existing conventional plants. Coal contains minor quantities of sulfur and nitrogen compounds, which are of concern, as their release into the atmosphere leads to the formation of urban ozone and acid rain, the destruction of stratospheric ozone, and global warming. Coal also contains many trace elements that are potentially hazardous to human health and the environment. During CO2 separation and capture, these constituents could inadvertently contaminate the separated CO2 and be co-injected. The concentrations and speciation of the co-injected contaminants would differ markedly, depending on whether CO2 is captured during the operation of a conventional or an IGCC plant, and the specific nature of the plant design and CO2 separation technology. However, regardless of plant design or separation procedures, most of the hazardous constituents effectively partition into the solid waste residue. This would lead to an approximately two order of magnitude reduction in contaminant concentration compared with that present in the coal. Potential exceptions are Hg in conventional plants, and Hg and possibly Cd, Mo and Pb in IGCC plants. CO2 capture and injection disposal could afford an opportunity to deliberately capture environmental pollutants in the gaseous state and co-inject them with the CO2, in order to mitigate problems associated with solid waste disposal in surface impoundments. Under such conditions, the injected pollutant concentrations could be roughly equivalent to their concentrations in the coal feed. The fate of the injected contaminants can only be determined through further testing and geochemical modeling. However, the concentrations of inadvertent contaminants in the injected CO2 would probably be comparable to their ambient concentrations in confining shales of the injection zone. In general, the aqueous concentrations of hazardous constituents in distal parts of the injection zone, regardless of source, are likely to be limited by equilibrium with respect to coexisting solid phases under the acid conditions induced by the dissolved high pressure CO2, rather than by the initial concentrations of injected contaminants. Therefore, even if a deliberate policy of contaminant recovery and injection were to be pursued, water quality in USDWs would more likely depend on thermodynamic controls governing aqueous contaminant concentrations in the presence of high pressure CO2 rather than in the injected CO2. The conclusions reached in this report are preliminary, and should be confirmed through more comprehensive data evaluation and supporting geochemical modeling.

Apps, J.A.

2006-02-23T23:59:59.000Z

203

Penguin pollution in the B^0 -> J/psi K_S decay  

E-Print Network [OSTI]

We present the most complete analysis of the penguin correction to the extraction of the standard-model parameter sin(2\\phi_1) from the B^0 -> J/psi K_S decay up to leading power in 1/m_b and to next-to-leading order in \\alpha_s, \\phi_1 being the weak phase, m_b the b quark mass, and \\alpha_s the strong coupling constant. The deviation \\Delta S_{J/psi K_S} of the mixing-induced CP asymmetry from sin(2\\phi_1) and the direct CP asymmetry A_{J/psi K_S} are both found to be of O(10^{-3}) in a formalism that combines the QCD-improved factorization and perturbative QCD approaches. The above results, different from those of O(10^{-4}) and of O(10^{-2}) obtained in the previous calculations, provide an important standard-model reference for verifying new physics from the B^0 -> J/psi K_S data.

Hsiang-nan Li; Satoshi Mishima

2007-03-02T23:59:59.000Z

204

Measurement of the KS->gg branching ratio using a pure KS beam with the KLOE detector  

E-Print Network [OSTI]

We have searched for the decay KS->gg in a sample of 2x10^9 phi->KS KL decays collected at DAPHNE with an integrated luminosity of 1.9 fb^{-1}. KS are tagged by the KL interaction in the calorimeter. Two prompt photons must also be detected. Kinematic constraints reduce the initial 6x10^5 events to 2740 candidates, from which a signal of 711\\pm 35 events is extracted. By normalizing to the KS->2pi^0 decays counted in the same sample, we measure BR(KS->gg)= (2.26\\pm0.12_{stat}\\pm0.06_{syst})x10^{-6}, in agreement with O(p^4) Chiral Perturbation Theory predictions.

The KLOE collaboration

2008-05-08T23:59:59.000Z

205

Effects of the Uncertainty about Global Economic Recovery on Energy Transition and CO2 Price  

E-Print Network [OSTI]

This paper examines the impact that uncertainty over economic growth may have on global energy transition and CO2 prices. We use a general-equilibrium model derived from MERGE, and define several stochastic scenarios for ...

Durand-Lasserve, Olivier

206

CO2 Reduction through Optimization of Steam Network in Petroleum Refineries: Evaluation of New Scenario  

E-Print Network [OSTI]

Steam network of petroleum refinery is energy intensive, and consequently contribute significantly to the greenhouse gases emissions. A simple model for the estimation of CO2 emissions associated with operation of steam network as encountered...

Manesh, M. H. K; Khodaie, H.; Amidpour, M.

2008-01-01T23:59:59.000Z

207

CO2 Abatement in the UK Power Sector: Evidence from the EU ETS Trial Period  

E-Print Network [OSTI]

This paper provides an empirical assessment of CO2 emissions abatement in the UK power sector during the trial period of the EU ETS. Using an econometrically estimated model of fuel switching, it separates the impacts of ...

Ellerman, A. Denny

2008-01-01T23:59:59.000Z

208

Metal Carbonation of Forsterite in Supercritical CO2 and H2O...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

and reaction extent relevant to geologic carbon sequestration (GCS) using a model silicate mineral forsterite (Mg2SiO4)+supercriticalCO2 with and without H2O. Run conditions...

209

Optimal synthesis of a pressure swing adsorption process for CO2 capture  

SciTech Connect (OSTI)

The emission of carbon dioxide from cement industry and power plants that burn fossil fuels is the major cause for the accumulation of CO2 in the atmosphere, which causes long-range environmental problems. One option to mitigate the emission of CO2 is to capture it from the emission sources and store it to the ocean or depleted oil field or use it for enhanced oil recovery. CO2 recovery has been achieved by gas absorption employing solutions of carbonates and alkanolamines. However, this process is energy-intensive for the regeneration of solvent and also faces problems due to corrosion. Recently, the pressure swing adsorption (PSA) process has been considered as an alternative to the absorption process. PSA processes have been widely applied for the removal of CO2 from various feed mixtures, such as CO2 in the steam reformer off gas, landfill gas and natural gas. In all these commercial PSA cycles, the weakly adsorbed component in the mixture is the desired product and enriching the strongly adsorbed CO2 is not a concern. On the other hand, for the capture of CO2 for sequestration, it is necessary to concentrate the CO2 to a high purity to reduce the compression and transportation cost. Thus, it is necessary to develop a PSA cycle by which a high-purity product for the strongly adsorbed component with a high recovery is obtained. A multitude of PSA cycles and adsorbents have been developed for producing highly pure heavy component (CO2) from feedstock with low CO2 concentration. Kikkinides et al. suggested a 4-bed 4-step process with activated carbon as the sorbent and could recover 68% of CO2 at 99.997% purity. Chue et al. compared activated carbon and zeolite 13X on a 3-bed 7-step process and concluded that the latter is better than the former for CO2 recovery. However, the CO2 recovery was low in their process due to the lack of a countercurrent step in the chosen cycle. Choi et al. reported more than 70% CO2 recovery at more than 90% purity for a modified 3-bed 7-step cycle. However, they solved a very small two variable optimization problem, thus being a specialized case. Zhang et al. have given justifications for using a specific cyclic component step in the adsorption cycle in the context of CO2 capture by using a simplistic mathematical model for the PSA process. Reynolds et al. have suggested a variety of stripping PSA cycles for CO2 recovery at high temperature using a hydrotalcite-like adsorbent. In this study, a two-bed superstructure of the PSA process has been developed to optimally synthesize an appropriate cycle for CO2 capture. The superstructure considers all the possible operating steps in a PSA cycle with two beds. An optimal control problem with a PDE-based model for PSA system has been formulated in which different steps within a cycle are realized with the help of control variables changing with time. The optimization problem has been solved for three different cases of maximizing CO2 recovery (for a given purity), maximizing feed throughput and minimizing specific power (for a given level of CO2 purity and recovery). Current results indicate the superstructure-based approach as a promising technique for deriving optimal PSA cycles. Different cases with different number of control variables indicate convergence to a particular kind of PSA cycle with over 99% purity and recovery of CO2. The results obtained from optimization problem will also be compared with the optimal PSA cycle simulated more accurately in a dynamic simulation environment.

Agarwal, A.; Biegler, L.; Zitney, S.

2008-01-01T23:59:59.000Z

210

PLAINS CO2 REDUCTION (PCOR) PARTNERSHIP  

SciTech Connect (OSTI)

During the period of October 1, 2003, through September 30, 2005, the Plains CO2 Reduction (PCOR) Partnership, identified geologic and terrestrial candidates for near-term practical and environmentally sound carbon dioxide (CO2) sequestration demonstrations in the heartland of North America. The PCOR Partnership region covered nine states and three Canadian provinces. The validation test candidates were further vetted to ensure that they represented projects with (1) commercial potential and (2) a mix that would support future projects both dependent and independent of CO2 monetization. This report uses the findings contained in the PCOR Partnership's two dozen topical reports and half-dozen fact sheets as well as the capabilities of its geographic information system-based Decision Support System to provide a concise picture of the sequestration potential for both terrestrial and geologic sequestration in the PCOR Partnership region based on assessments of sources, sinks, regulations, deployment issues, transportation, and capture and separation. The report also includes concise action plans for deployment and public education and outreach as well as a brief overview of the structure, development, and capabilities of the PCOR Partnership. The PCOR Partnership is one of seven regional partnerships under Phase I of the U.S. Department of Energy National Energy Technology Laboratory's Regional Carbon Sequestration Partnership program. The PCOR Partnership, comprising 49 public and private sector members, is led by the Energy & Environmental Research Center at the University of North Dakota. The international PCOR Partnership region includes the Canadian provinces of Alberta, Saskatchewan, and Manitoba and the states of Montana (part), Wyoming (part), North Dakota, South Dakota, Nebraska, Missouri, Iowa, Minnesota, and Wisconsin.

Edward N. Steadman; Daniel J. Daly; Lynette L. de Silva; John A. Harju; Melanie D. Jensen; Erin M. O'Leary; Wesley D. Peck; Steven A. Smith; James A. Sorensen

2006-01-01T23:59:59.000Z

211

co2 capture | netl.doe.gov  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLasDelivered energy consumption byAbout SRNL HomeYoungClean Energy Projects SolicitationscivilCO2

212

Sandia National Laboratories: lower CO2 emission  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the1developmentturbine blade manufacturinglife-cycleionlow-temperature dieselCO2

213

CO2 Conference Presentation | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-Up fromDepartmentTie Ltd:June 2015 <Ones |Laboratory, June 2011TO0CNG and3, 2015CO2

214

CO2 Heat Pump Water Heater  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-Up fromDepartmentTie Ltd:June 2015 <Ones |Laboratory, June 2011TO0CNG and3, 2015CO2CO

215

CO2 Compression | netl.doe.gov  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-Series to someone6Energy, science, andAnalysis15 CNMS Userpulse injectionCO2

216

Sandia National Laboratories: S-CO2  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the1 -theErik SpoerkeSolarCybernetics: DynamicCybernetics: WeighBlade SensorsRozaS-CO2

217

CircleKs DEFINITIVE vim Reference Version: 1.0  

E-Print Network [OSTI]

CircleKs DEFINITIVE vim Reference Version: 1.0 Major rules: 1. Vim has 2 modes: insert and command inserting text s! Cut character under cursor and start inserting text After youre in insert mode, vim

218

CO2 capture processes in power plants - Le captage du CO2 dans les centrales thermiques  

E-Print Network [OSTI]

This review is devoted to assess and compare various processes aiming at recover CO2 from power plants fed with natural gas (NGCC) and pulverized coal (PC). These processes are post combustion CO2 capture using chemical solvents, natural gas reforming for pre-combustion capture and oxy-fuel combustion with cryogenic recovery of CO2. These processes were evaluated to give some clues for choosing the best option for each type of power plant. The comparison of these various concepts suggests that, in the short and medium term, chemical absorption is the most interesting process for NGCC power plants. For CP power plants, oxy-combustion can be a very interesting option, as well as post-combustion capture by chemical solvents.

Chakib Bouallou

2010-08-12T23:59:59.000Z

219

International Symposium on Site Characterization for CO2 Geological Storage  

E-Print Network [OSTI]

157 WELL INTEGRITY IN CO 2 ENVIRONMENTS: PERFORMANCE, RISK,of CO 2 injection, wells integrity and long term behavior ofcan compromise the well integrity and thus its functional

Tsang, Chin-Fu

2006-01-01T23:59:59.000Z

220

Summary Report on CO2 Geologic Sequestration & Water Resources Workshop  

E-Print Network [OSTI]

2 exposure in both CO 2 -EOR and natural CO 2 reservoirs (as enhanced oil recovery (EOR) and enhanced gas recovery (2 field injections for CCS-EOR, where the water quality of

Varadharajan, C.

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "ks modeling co2" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Summary Report on CO2 Geologic Sequestration & Water Resources Workshop  

E-Print Network [OSTI]

projects based CO 2 enhanced oil recovery in the US. Energydeveloped for CO 2 -enhanced oil recovery. In: 16th SPE/DOEpurposes such as enhanced oil recovery (EOR) and enhanced

Varadharajan, C.

2013-01-01T23:59:59.000Z

222

Chemical Impact of Elevated CO2on Geothermal Energy Production...  

Broader source: Energy.gov (indexed) [DOE]

Chemical Impact of Elevated CO2on Geothermal Energy Production Chemical Impact of Elevated CO2on Geothermal Energy Production This is a two phase project to assess the geochemical...

223

Formation Damage due to CO2 Sequestration in Saline Aquifers  

E-Print Network [OSTI]

Carbon dioxide (CO2) sequestration is defined as the removal of gas that would be emitted into the atmosphere and its subsequent storage in a safe, sound place. CO2 sequestration in underground formations is currently being considered to reduce...

Mohamed, Ibrahim Mohamed 1984-

2012-10-25T23:59:59.000Z

224

Near Miscible CO2 Application to Improve Oil Recovery  

E-Print Network [OSTI]

Carbon dioxide (CO2) injection for enhanced oil recovery is a proven technology. CO2 injection is normally operated at a pressure above the minimum miscibility pressure (MMP), which is determined by crude oil composition and reservoir conditions...

Bui, Ly H.

2010-07-26T23:59:59.000Z

225

CO2 Capture by Absorption with Potassium Carbonate  

E-Print Network [OSTI]

CO2 Capture by Absorption with Potassium Carbonate First Quarterly Report 2007 Quarterly Progress of this work is to improve the process for CO2 capture by alkanolamine absorption/stripping by developing

Rochelle, Gary T.

226

CO2 Capture by Absorption with Potassium Carbonate  

E-Print Network [OSTI]

CO2 Capture by Absorption with Potassium Carbonate Fourth Quarterly Report 2006 Quarterly Progress of this work is to improve the process for CO2 capture by alkanolamine absorption/stripping by developing

Rochelle, Gary T.

227

Electrolysis byproduct D2O provides a third way to mitigate CO2  

SciTech Connect (OSTI)

Rapid atomic power deployment may be possible without using fast breeder reactors or making undue demands on uranium resource. Using by-product D2O and thorium-U233 in CANDU and RBMK piles may circumvent need for either fast breeder reactors or seawater uranium. Atmospheric CO2 is presently increasing 2.25%/year in proportion to 2.25%/year exponential fossil fuel consumption increase. Roughly 1/3 anthropologic CO2 is removed by various CO2 sinks. CO2 removal is modelled as being proportional to 45-year-earlier CO2 amount above 280 ppm-C Water electrolysis produces roughly 0.1 kg-D20/kWe-y. Material balance assumes each electrolysis stage increases D2O bottoms concentration times 3. Except for first two electrolysis stages, all water from hydrogen consumption is returned to electrolysis. The unique characteristic of this process is the ability to economically burn all deuterium-enriched H2 in vehicles. Condensate from vehicles returns to appropriate electrolysis stage. Fuel cell condensate originally from reformed natural gas may augment second-sage feed. Atomic power expansion is 5%/year, giving 55000 GWe by 2100. World primary energy increases 2.25%/y, exceeding 4000 EJ/y by 2100. CO2 maximum is roughly 600 ppm-C around year 2085. CO2 declines back below 300 ppm-C by 2145 if the 45-year-delay seawater sink remains effective.

Schenewerk, William Ernest [self, Los Angeles, CA (United States)

2009-09-01T23:59:59.000Z

228

International Symposium on Site Characterization for CO2 Geological Storage  

E-Print Network [OSTI]

Marchetti, C. , On geoengineering and the CO2 prob- lem.to the location of geoengineering activities seems to be

Tsang, Chin-Fu

2006-01-01T23:59:59.000Z

229

CO2 stabilization, climate change and the terrestrial carbon sink  

E-Print Network [OSTI]

CO2 stabilization, climate change and the terrestrial carbon sink A N D R E W W H I T E , * M E L V, Hybrid v4.1, with a subdaily timestep, was driven by increasing CO2 and transient climate output from scenarios were used: (i) IS92a, giving 790 ppm CO2 by 2100, (ii) CO2 stabilization at 750 ppm by 2225

White, Andrew

230

CO2 levels during the greenhouse of the Paleocene  

E-Print Network [OSTI]

to reconstruct CO2 concentrations during this period of global warming 56 million years ago. 56 million year oldCO2 levels during the greenhouse of the Paleocene Eocene Thermal Maximum (PETM) Francesca A. Mc, Boulder #12;Estimating paleopCO2 0 5 10 15 20 25 30 0 500 1000 1500 2000 2500 3000 Meter Level, start

Shull, Kenneth R.

231

results and benefits... Birmingham Cutting your CO2  

E-Print Network [OSTI]

results and benefits... Birmingham Cutting your CO2 Birmingham City Council July 2007 c a s e s t u of the BirminghamCutting CO2 campaign, news items, display materials etc. · Advising on pledge gathering materials system was launched in July 2007 as part of the `Birmingham Cutting Your CO2' campaign. By the end

Everest, Graham R

232

Central serotonin neurons are required for arousal to CO2  

E-Print Network [OSTI]

Central serotonin neurons are required for arousal to CO2 Gordon F. Buchanana,b,1 and George B neurons are stimulated by CO2, and sero- tonin activates thalamocortical networks, we hypothesized any arousal response to inhalation of 10% CO2 (with 21% O2 in balance N2) but had normal arousal

233

Original article Interactive effects of elevated CO2, O3,  

E-Print Network [OSTI]

Original article Interactive effects of elevated CO2, O3, and soil water deficit on spring wheat of elevated carbon dioxide (CO2), ozone (O3), and soil water deficit on spring wheat (Triticum aestivum L. cv consisting of two O3levels (ambient and 1.5-times ambient) in combination with two CO2levels (ambient

Paris-Sud XI, Université de

234

CO2 Emissions Mitigation and Technological Advance: An  

E-Print Network [OSTI]

PNNL-18075 CO2 Emissions Mitigation and Technological Advance: An Updated Analysis of Advanced/2003) #12;PNNL-18075 CO2 Emissions Mitigation and Technological Advance: An Analysis of Advanced Technology of atmospheric CO2 concentrations at 450 parts per million by volume (ppmv) and 550 ppmv in MiniCAM. Each

235

Reduction of CO2 emissions and utilization of slag  

E-Print Network [OSTI]

Reduction of CO2 emissions and utilization of slag products by producing calcium-based products-free calcium-based ma- terial, such as steelmaking slags, significant re- ductions in CO2 emissions may of the CO2 emissions reduction achieved. However, the pu- rity and crystal structure of the PCC produced

Zevenhoven, Ron

236

Advanced Amine Solvent Formulations and Process Integration for Near-Term CO2 Capture Success  

SciTech Connect (OSTI)

This Phase I SBIR project investigated the economic and technical feasibility of advanced amine scrubbing systems for post-combustion CO2 capture at coal-fired power plants. Numerous combinations of advanced solvent formulations and process configurations were screened for energy requirements, and three cases were selected for detailed analysis: a monoethanolamine (MEA) base case and two “advanced” cases: an MEA/Piperazine (PZ) case, and a methyldiethanolamine (MDEA) / PZ case. The MEA/PZ and MDEA/PZ cases employed an advanced “double matrix” stripper configuration. The basis for calculations was a model plant with a gross capacity of 500 MWe. Results indicated that CO2 capture increased the base cost of electricity from 5 cents/kWh to 10.7 c/kWh for the MEA base case, 10.1 c/kWh for the MEA / PZ double matrix, and 9.7 c/kWh for the MDEA / PZ double matrix. The corresponding cost per metric tonne CO2 avoided was 67.20 $/tonne CO2, 60.19 $/tonne CO2, and 55.05 $/tonne CO2, respectively. Derated capacities, including base plant auxiliary load of 29 MWe, were 339 MWe for the base case, 356 MWe for the MEA/PZ double matrix, and 378 MWe for the MDEA / PZ double matrix. When compared to the base case, systems employing advanced solvent formulations and process configurations were estimated to reduce reboiler steam requirements by 20 to 44%, to reduce derating due to CO2 capture by 13 to 30%, and to reduce the cost of CO2 avoided by 10 to 18%. These results demonstrate the potential for significant improvements in the overall economics of CO2 capture via advanced solvent formulations and process configurations.

Fisher, Kevin S.; Searcy, Katherine; Rochelle, Gary T.; Ziaii, Sepideh; Schubert, Craig

2007-06-28T23:59:59.000Z

237

Directed Technical Change and the Adoption of CO2 Abatement Technology: The Case of CO2 Capture and Storage  

E-Print Network [OSTI]

This paper studies the cost effectiveness of combining traditional environmental policy, such as CO2 trading schemes, and technology policy that has aims of reducing the cost and speeding the adoption of CO2 abatement ...

Otto, Vincent M.

238

Rate Determination of the CO2* Chemiluminescence Reaction CO + O + M = CO2* + M  

E-Print Network [OSTI]

flame characteristics, such as fuel consumption rate, heat release rate, and H-atom concentration. In 2002, Kim et al. [2] made detailed spectral measurements in SI, HCCI, and SCCI engines from various excited state species and determined that CO2...

Kopp, Madeleine Marissa, 1987-

2012-10-15T23:59:59.000Z

239

How secure is CO2 storage? Leakage mechanisms of natural CO2 reservoirs  

E-Print Network [OSTI]

technology available to reduce greenhouse gas emissions from large point sources such as power plants and the burial of organic rich rocks such as coal seams.2 We have compiled the first global dataset on natural CO ­ but not necessarily leaking. Figure 4: Diagram showing the state of CO2 in the studied reservoirs. Supercritical

240

Published in: Journal of Geophysical ResearchVOL.100E10 21,119--21,234, October 25, 1995. Low brightness temperatures of Martian Polar caps : CO 2  

E-Print Network [OSTI]

to the condensation of CO 2 in the atmosphere. We have used a combination of data analysis and modeling to compare to the frost point of CO 2 gas, CO 2 condenses, and polar ice caps are formed. The surface temperature which have directly condensed on the ground could have an emissivity close to unity and in any case much

Forget, François

Note: This page contains sample records for the topic "ks modeling co2" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Gulf of Mexico Miocene CO2 Site Characterization Mega Transect  

SciTech Connect (OSTI)

This project characterized the Miocene-age sub-seafloor stratigraphy in the near-offshore portion of the Gulf of Mexico adjacent to the Texas coast. The large number of industrial sources of carbon dioxide (CO2) in coastal counties and the high density of onshore urbanization and environmentally sensitive areas make this offshore region extremely attractive for long-term storage of carbon dioxide emissions from industrial sources (CCS). The study leverages dense existing geologic data from decades of hydrocarbon exploration in and around the study area to characterize the regional geology for suitability and storage capacity. Primary products of the study include: regional static storage capacity estimates, sequestration “leads” and prospects with associated dynamic capacity estimates, experimental studies of CO2-brine-rock interaction, best practices for site characterization, a large-format ‘Atlas’ of sequestration for the study area, and characterization of potential fluid migration pathways for reducing storage risks utilizing novel high-resolution 3D (HR3D) seismic surveys. In addition, three subcontracted studies address source-to-sink matching optimization, offshore well bore management and environmental aspects. The various geologic data and interpretations are integrated and summarized in a series of cross-sections and maps, which represent a primary resource for any near-term commercial deployment of CCS in the area. The regional study characterized and mapped important geologic features (e.g., Clemente-Tomas fault zone, the regionally extensive Marginulina A and Amphistegina B confining systems, etc.) that provided an important context for regional static capacity estimates and specific sequestration prospects of the study. A static capacity estimate of the majority of the Study area (14,467 mi2) was estimated at 86 metric Gigatonnes. While local capacity estimates are likely to be lower due to reservoir-scale characteristics, the offshore Miocene interval is a storage resource of National interest for providing CO2 storage as an atmospheric emissions abatement strategy. The natural petroleum system was used as an analog to infer seal quality and predict possible migration pathways of fluids in an engineered system of anthropogenic CO2 injection and storage. The regional structural features (e.g., Clemente-Tomas fault zone) that exert primary control on the trapping and distribution of Miocene hydrocarbons are expected to perform similarly for CCS. Industrial?scale CCS will require storage capacity utilizing well?documented Miocene hydrocarbon (dominantly depleted gas) fields and their larger structural closures, as well as barren (unproductive, brine?filled) closures. No assessment was made of potential for CO2 utilization for enhanced oil and gas recovery. The use of 3D numerical fluid flow simulations have been used in the study to greatly assist in characterizing the potential storage capacity of a specific reservoir. Due to the complexity of geologic systems (stratigraphic heterogeneity) and inherent limitations on producing a 3D geologic model, these simulations are typically simplified scenarios that explore the influence of model property variability (sensitivity study). A specific site offshore San Luis Pass (southern Galveston Island) was undertaken successfully, indicating stacked storage potential. Downscaling regional capacity estimates to the local scale (and the inverse) has proven challenging, and remains an outstanding gap in capacity assessments. In order to characterize regional seal performance and identify potential brine and CO2 leakage pathways, results from three high-resolution 3D (HR3D) seismic datasets acquired by the study using novel HR3D (P-Cable) acquisition system showed steady and significant improvements in data quality because of improved acquisition and processing technique. Finely detailed faults and stratigraphy in the shallowest 1000 milliseconds (~800 m) of data allowed for the identification and mapping of unconformable surfaces including what is probably

Meckel, Timothy; Trevino, Ramon

2014-09-30T23:59:59.000Z

242

Research Project on CO2 Geological Storage and Groundwater Resources: Water Quality Effects Caused by CO2 Intrusion into Shallow Groundwater  

E-Print Network [OSTI]

Changes in Response to CO2 Leakage from Deep Geologicalstudy mineral trapping for CO2 disposal in deep arenaceousconstituents as function of P(CO2)? function of P(CO2)? – –

Birkholzer, Jens

2008-01-01T23:59:59.000Z

243

A Feasibility Study of Non-Seismic Geophysical Methods forMonitoring Geologic CO2 Sequestration  

SciTech Connect (OSTI)

Because of their wide application within the petroleumindustry it is natural to consider geophysical techniques for monitoringof CO2 movement within hydrocarbon reservoirs, whether the CO2 isintroduced for enhanced oil/gas recovery or for geologic sequestration.Among the available approaches to monitoring, seismic methods are by farthe most highly developed and applied. Due to cost considerations, lessexpensive techniques have recently been considered. In this article, therelative merits of gravity and electromagnetic (EM) methods as monitoringtools for geological CO2 sequestration are examined for two syntheticmodeling scenarios. The first scenario represents combined CO2 enhancedoil recovery (EOR) and sequestration in a producing oil field, theSchrader Bluff field on the north slope of Alaska, USA. The secondscenario is a simplified model of a brine formation at a depth of 1,900m.

Gasperikova, Erika; Hoversten, G. Michael

2006-07-01T23:59:59.000Z

244

MIXTURES OF CO2-SF6 AS WORKING FLUIDS FOR GEOTHERMAL PLANTS  

SciTech Connect (OSTI)

In this paper, mixtures of CO2 and SF6 were evaluated as working fluids for geothermal plants based on property measurements, molecular dynamics modeling, thermodynamic cycle analysis, and materials compatibility assessment. The CO2 - SF6 was evaluated for a reservoir temperature of 160 oC. Increasing the efficiency for these low reservoir sources will increase the options available for geothermal energy utilization in more sites across the country. The properties for the mixtures were obtained either from thermodynamic property measurements and molecular dynamics simulations. Optimum compositions of the CO2 - SF6 were identified for a well reservoir temperature and a given water-cooling condition. Concerning the global warming potential, it was estimated that the equivalent CO2 emissions per 1kWh for a Rankine cycle operating with 100% SF6 would be approximately of 7.6% than those for a coal-fired power plant.

Sabau, Adrian S [ORNL; Yin, Hebi [ORNL; Gruszkiewicz, Miroslaw {Mirek} S [ORNL; McFarlane, Joanna [ORNL; Qualls, A L [ORNL; Conklin, Jim [ORNL; Pawel, Steven J [ORNL

2011-01-01T23:59:59.000Z

245

In Situ Spectrophotometric Determination of pH under Geologic CO2 Sequestration Conditions: Method Development and Application  

SciTech Connect (OSTI)

Injecting massive amounts of CO2 into deep geologic formations will cause a range of coupled thermal, hydrodynamic, mechanical, and chemical changes. A significant perturbation in water-saturated formations is the pH drop in the reservoir fluids due to CO2 dissolution. Knowing the pH under geological CO2 sequestration conditions is important for a better understanding of the short- and long-term risks associated with geological CO2 sequestration and will help in the design of sustainable sequestration projects. Most previous studies on CO2-rock-brine interactions have utilized thermodynamic modeling to estimate the pH. In this work, a spectrophotometric method was developed to determine the in-situ pH in CO2-H2O-NaCl systems in the presence and absence of reservoir rock by observing the spectra of a pH indicator, bromophenol blue, with a UV-visible spectrophotometer. Effects of temperature, pressure, and ionic strength on the pH measurement were evaluated. Measured pH values in CO2-H2O-NaCl systems were compared with several thermodynamic models. Results indicate that bromophenol blue can be used to accurately determine the pH of brine in contact with supercritical CO2 under geologic CO2 sequestration conditions.

Shao, Hongbo; Thompson, Christopher J.; Qafoku, Odeta; Cantrell, Kirk J.

2013-02-25T23:59:59.000Z

246

Geochemical Implications of CO2 Leakage Associated with Geologic Storage: A Review  

SciTech Connect (OSTI)

Leakage from deep storage reservoirs is a major risk factor associated with geologic sequestration of carbon dioxide (CO2). Different scientific theories exist concerning the potential implications of such leakage for near-surface environments. The authors of this report reviewed the current literature on how CO2 leakage (from storage reservoirs) would likely impact the geochemistry of near surface environments such as potable water aquifers and the vadose zone. Experimental and modeling studies highlighted the potential for both beneficial (e.g., CO2 re sequestration or contaminant immobilization) and deleterious (e.g., contaminant mobilization) consequences of CO2 intrusion in these systems. Current knowledge gaps, including the role of CO2-induced changes in redox conditions, the influence of CO2 influx rate, gas composition, organic matter content and microorganisms are discussed in terms of their potential influence on pertinent geochemical processes and the potential for beneficial or deleterious outcomes. Geochemical modeling was used to systematically highlight why closing these knowledge gaps are pivotal. A framework for studying and assessing consequences associated with each factor is also presented in Section 5.6.

Harvey, Omar R.; Qafoku, Nikolla; Cantrell, Kirk J.; Brown, Christopher F.

2012-07-09T23:59:59.000Z

247

Theoretic Insight into CO2 Reduction at Active Sites of Molybdenum and Tungsten Enzymes: a {\\pi} Interaction between CO2 and Tungsten Bis-Dithiolene Complexes  

E-Print Network [OSTI]

Active sites of molybdenum and tungsten enzymes, particularly mononuclear tungsten formate dehydrogenase (FDH) have been theoretically investigated towards their interaction with CO2. Obvious {\\pi} interaction has been found between the 2e reduced metallodithiole moiety and the molecular CO2. This weak {\\pi} bonding is predicated both at gas phase, noted as -6.0 kcal/mol and aqueous solvation level, -3.6 kcal/mol. Such interaction is not only limited to CO2, but also to the CO2 reduced product, i.e. formate, in the form of anion- {\\pi} interaction, noted as -6.8 kcal/mol and -4.1 kcal/mol respectively in gas and aqueous solvation model. The Bailar twisted angles from 60o to 0o, governing structure preference of tungsten dithiolene from octahedron to triangle prism in their restricted structures, has been explored to evaluate such {\\pi} in-terrelations with CO2 and formate. An octahedral structure with 3 kcal/mol energy lower is preferred over the triangle prismatic when such interactions are concerned.

Yan, Yong

2014-01-01T23:59:59.000Z

248

14 Diffusive CO2 Flux at the Air-Water Interface of the Robert-Bourassa Hydroelectric Reservoir in  

E-Print Network [OSTI]

14 Diffusive CO2 Flux at the Air-Water Interface of the Robert-Bourassa Hydroelectric Reservoir Hydroelectric reservoirs and lakes in boreal Québec produce greenhouse gases (GHG) mainly in the form of CO2 of the interface. When applied to the Robert- Bourassa hydroelectric reservoir in boreal Québec, this model

Long, Bernard

249

Influence of reduced carbon emissions and oxidation on the distribution of atmospheric CO2: Implications for inversion analyses  

E-Print Network [OSTI]

Influence of reduced carbon emissions and oxidation on the distribution of atmospheric CO2 carbon emissions. We used TransCom3 annual mean simulations from three transport models to evaluate carbon emission and oxidation processes in deriving inversion estimates of CO2 surface fluxes. Citation

Krakauer, Nir Y.

250

Mechanisms of air-sea CO2 flux variability in the equatorial Pacific and the North Atlantic  

E-Print Network [OSTI]

Mechanisms of air-sea CO2 flux variability in the equatorial Pacific and the North Atlantic Galen A circulation model is used to estimate the magnitude of interannual variability in air-sea fluxes of CO2 and O2 from 1980­1998 and to examine the controlling mechanisms. The global variability in the air-sea flux

Follows, Mick

251

The c2d Spitzer spectroscopic survey of ices around low-mass young stellar objects II: CO2  

E-Print Network [OSTI]

This paper presents Spitzer-IRS spectroscopy of the CO2 15.2 micron bending mode toward a sample of 50 embedded low-mass stars in nearby star-forming clouds, taken mostly from the ``Cores to Disks (c2d)'' Legacy program. The average abundance of solid CO2 relative to water in low-mass protostellar envelopes is 0.32 +/- 0.02, significantly higher than that found in quiescent molecular clouds and in massive star forming regions. It is found that a decomposition of all the observed CO2 bending mode profiles requires a minimum of five unique components. Roughly 2/3 of the CO2 ice is found in a water-rich environment, while most of the remaining 1/3 is found in a CO environment. Ground-based observations of solid CO toward a large subset of the c2d sample are used to further constrain the CO2:CO component and suggest a model in which low-density clouds form the CO2:H2O component and higher density clouds form the CO2:CO ice during and after the freeze-out of gas-phase CO. It is suggested that the subsequent evolution of the CO2 and CO profiles toward low-mass protostars, in particular the appearance of the splitting of the CO2 bending mode due to pure, crystalline CO2, is first caused by distillation of the CO2:CO component through evaporation of CO due to thermal processing to ~20-30 K in the inner regions of infalling envelopes. The formation of pure CO2 via segregation from the H2O rich mantle may contribute to the band splitting at higher levels of thermal processing (>50 K), but is harder to reconcile with the physical structure of protostellar envelopes around low-luminosity objects.

Klaus M. Pontoppidan; A. C. A. Boogert; Helen J. Fraser; Ewine F. van Dishoeck; Geoffrey A. Blake; Fred Lahuis; Karin I. Oberg; Neal J. Evans II; Colette Salyk

2007-11-28T23:59:59.000Z

252

Supersonic Technology for CO2 Capture: A High Efficiency Inertial CO2 Extraction System  

SciTech Connect (OSTI)

IMPACCT Project: Researchers at ATK and ACENT Laboratories are developing a device that relies on aerospace wind-tunnel technologies to turn CO2 into a condensed solid for collection and capture. ATK’s design incorporates a special nozzle that converges and diverges to expand flue gas, thereby cooling it off and turning the CO2 into solid particles which are removed from the system by a cyclonic separator. This technology is mechanically simple, contains no moving parts and generates no chemical waste, making it inexpensive to construct and operate, readily scalable, and easily integrated into existing facilities. The increase in the cost to coal-fired power plants associated with introduction of this system would be 50% less than current technologies.

None

2010-07-01T23:59:59.000Z

253

Improved Efficiency of Miscible CO2 Floods and Enhanced Prospects for CO2 Flooding Heterogeneous Reservoirs  

SciTech Connect (OSTI)

The goal of this project is to improve the efficiency of miscible CO2 floods and enhance the prospects for flooding heterogeneous reservoirs. This report provides results of the second year of the three-year project that will be exploring three principles: (1) Fluid and matrix interactions (understanding the problems). (2) Conformance control/sweep efficiency (solving the problems. 3) Reservoir simulation for improved oil recovery (predicting results).

Grigg, Reid B.; Schechter, David S.

1999-10-15T23:59:59.000Z

254

CO2 flood tests on whole core samples of the Mt. Simon sandstone, Illinois Basin  

SciTech Connect (OSTI)

Geological sequestration of CO2, whether by enhanced oil recovery (EOR), coal-bed methane (CBM) recovery, or saline aquifer injection is a promising near-term sequestration methodology. While tremendous experience exists for EOR, and CBM recovery has been demonstrated in existing fields, saline aquifer injection studies have only recently been initiated. Studies evaluating the availability of saline aquifers suitable for CO2 injection show great potential, however, the long-term fate of the CO2 injected into these ancient aqueous systems is still uncertain. For the subject study, a series of laboratory-scale CO2 flood tests were conducted on whole core samples of the Mt. Simon sandstone from the Illinois Basin. By conducting these tests on whole core samples rather than crushed core, an evaluation of the impact of the CO2 flood on the rock mechanics properties as well as the geochemistry of the core and brine solution has been possible. This empirical data could provide a valuable resource for the validation of reservoir models under development for these engineered CO2 systems.

O'Connor, William K.; Rush, Gilbert E.

2005-09-01T23:59:59.000Z

255

Agricultural green revolution as a driver of increasing atmospheric CO2 seasonal amplitude  

SciTech Connect (OSTI)

The atmospheric carbon dioxide (CO2) record displays a prominent seasonal cycle that arises mainly from changes in vegetation growth and the corresponding CO2 uptake during the boreal spring and summer growing seasons and CO2 release during the autumn and winter seasons. The CO2 seasonal amplitude has increased over the past five decades, suggesting an increase in Northern Hemisphere biospheric activity. It has been proposed that vegetation growth may have been stimulated by higher concentrations of CO2 as well as by warming in recent decades, but such mechanisms have been unable to explain the full range and magnitude of the observed increase in CO2 seasonal amplitude. Here we suggest that the intensification of agriculture (the Green Revolution, in which much greater crop yield per unit area was achieved by hybridization, irrigation and fertilization) during the past five decades is a driver of changes in the seasonal characteristics of the global carbon cycle. Our analysis of CO2 data and atmospheric inversions shows a robust 15 per cent long-term increase in CO2 seasonal amplitude from 1961 to 2010, punctuated by large decadal and interannual variations. Using a terrestrial carbon cycle model that takes into account high-yield cultivars, fertilizer use and irrigation, we find that the long-term increase in CO2 seasonal amplitude arises from two major regions: the mid-latitude cropland between 256N and 606N and the high-latitude natural vegetation between 506N and 706 N. The long-term trend of seasonal amplitude increase is 0.311 ± 0.027 percent per year, of which sensitivity experiments attribute 45, 29 and 26 per cent to land-use change, climate variability and change, and increased productivity due to CO2 fertilization, respectively. Vegetation growth was earlier by one to two weeks, as measured by the mid-point of vegetation carbon uptake, and took up 0.5 petagrams more carbon in July, the height of the growing season, during 2001–2010 than in 1961–1970, suggesting that human land use and management contribute to seasonal changes in the CO2 exchange between the biosphere and the atmosphere.

Zeng, Ning; Zhao, Fang; Collatz, George; Kalnay, Eugenia; Salawitch, Ross J.; West, Tristram O.; Guanter, Luis

2014-11-20T23:59:59.000Z

256

Developing a Comprehensive Risk Assessment Framework for Geological Storage CO2  

SciTech Connect (OSTI)

The operational risks for CCS projects include: risks of capturing, compressing, transporting and injecting CO?; risks of well blowouts; risk that CO? will leak into shallow aquifers and contaminate potable water; and risk that sequestered CO? will leak into the atmosphere. This report examines these risks by using information on the risks associated with analogue activities such as CO2 based enhanced oil recovery (CO2-EOR), natural gas storage and acid gas disposal. We have developed a new analysis of pipeline risk based on Bayesian statistical analysis. Bayesian theory probabilities may describe states of partial knowledge, even perhaps those related to non-repeatable events. The Bayesian approach enables both utilizing existing data and at the same time having the capability to adsorb new information thus to lower uncertainty in our understanding of complex systems. Incident rates for both natural gas and CO2 pipelines have been widely used in papers and reports on risk of CO2 pipelines as proxies for the individual risk created by such pipelines. Published risk studies of CO2 pipelines suggest that the individual risk associated with CO2 pipelines is between 10-3 and 10-4, which reflects risk levels approaching those of mountain climbing, which many would find unacceptably high. This report concludes, based on a careful analysis of natural gas pipeline failures, suggests that the individual risk of CO2 pipelines is likely in the range of 10-6 to 10-7, a risk range considered in the acceptable to negligible range in most countries. If, as is commonly thought, pipelines represent the highest risk component of CCS outside of the capture plant, then this conclusion suggests that most (if not all) previous quantitative- risk assessments of components of CCS may be orders of magnitude to high. The potential lethality of unexpected CO2 releases from pipelines or wells are arguably the highest risk aspects of CO2 enhanced oil recovery (CO2-EOR), carbon capture, and storage (CCS). Assertions in the CCS literature, that CO2 levels of 10% for ten minutes, or 20 to 30% for a few minutes are lethal to humans, are not supported by the available evidence. The results of published experiments with animals exposed to CO2, from mice to monkeys, at both normal and depleted oxygen levels, suggest that lethal levels of CO2 toxicity are in the range 50 to 60%. These experiments demonstrate that CO2 does not kill by asphyxia, but rather is toxic at high concentrations. It is concluded that quantitative risk assessments of CCS have overestimated the risk of fatalities by using values of lethality a factor two to six lower than the values estimated in this paper. In many dispersion models of CO2 releases from pipelines, no fatalities would be predicted if appropriate levels of lethality for CO2 had been used in the analysis.

Duncan, Ian

2014-08-31T23:59:59.000Z

257

Uncertainty quantification for CO2 sequestration and enhanced oil recovery  

E-Print Network [OSTI]

This study develops a statistical method to perform uncertainty quantification for understanding CO2 storage potential within an enhanced oil recovery (EOR) environment at the Farnsworth Unit of the Anadarko Basin in northern Texas. A set of geostatistical-based Monte Carlo simulations of CO2-oil-water flow and reactive transport in the Morrow formation are conducted for global sensitivity and statistical analysis of the major uncertainty metrics: net CO2 injection, cumulative oil production, cumulative gas (CH4) production, and net water injection. A global sensitivity and response surface analysis indicates that reservoir permeability, porosity, and thickness are the major intrinsic reservoir parameters that control net CO2 injection/storage and oil/gas recovery rates. The well spacing and the initial water saturation also have large impact on the oil/gas recovery rates. Further, this study has revealed key insights into the potential behavior and the operational parameters of CO2 sequestration at CO2-EOR s...

Dai, Zhenxue; Fessenden-Rahn, Julianna; Middleton, Richard; Pan, Feng; Jia, Wei; Lee, Si-Yong; McPherson, Brian; Ampomah, William; Grigg, Reid

2014-01-01T23:59:59.000Z

258

Estimation of CO2 Emissions from China's Cement Production: Methodologies and Uncertainties  

E-Print Network [OSTI]

L. , 2006. Discussion of CO2 emission reduction in ChineseFurther discussion of CO2 emission reduction in Chinesecalculation method of CO2 emissions of cement production.

Ke, Jing

2014-01-01T23:59:59.000Z

259

Cimpor inventa nova frmula para reduzir pegada de CO2  

E-Print Network [OSTI]

Cimpor inventa nova fórmula para reduzir pegada de CO2 CIMENTO. A Cimpor descobriu uma nova fórmula para produzir ci- mento que lhe permitirá reduzir a pegada de CO 2 em 25%. Segundo as contas da as fábricas do grupo, seriam emitidos menos quatro milhões de toneladas de CO 2 por ano, o que permitiria uma

Instituto de Sistemas e Robotica

260

Aquatic primary production in a high-CO2 world  

E-Print Network [OSTI]

Aquatic primary production in a high-CO2 world Etienne Low-De´carie, Gregor F. Fussmann, and Graham-Penfield, Montreal, QC, H3A 1B1, Canada Here, we provide a review of the direct effect of increas- ing CO2 on aquatic: the assessment of theories about limitation of productivity and the integration of CO2 into the co

Fussman, Gregor

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261

IMPLEMENTING A NOVEL CYCLIC CO2 FLOOD IN PALEOZOIC REEFS  

SciTech Connect (OSTI)

Recycled CO2 is being used in this demonstration project to produce bypassed oil from the Silurian Dover 35 Niagaran pinnacle reef located in Otsego County, Michigan. CO2 injection in the Dover 35 field into the Salling-Hansen 4-35A well began on May 6, 2004. A second injection well, the Salling-Hansen 1-35, commenced injection in August 2004. Oil production in the Pomerzynski 5-35 producing well increased from 9 BOPD prior to operations to an average of 165 BOPD in December, 2004 and has produced at an average rate of 61 BOPD (Jan-Dec, 2005). The Salling-Hansen 4-35A also produced during this reporting period an average of 29 BOPD. These increases have occurred as a result of CO2 injection and the production rate appears to be stabilizing. CO2 injection volume has reached approximately 2.18 BCF. The CO2 injection phase of this project has been fully operational since December 2004 and most downhole mechanical issues have been solved and surface facility modifications have been completed. It is anticipated that filling operations will run for another 6-12 months from July 1, 2005. In most other aspects, the demonstration is going well and hydrocarbon production has been stabilized at an average rate of 57 BOPD (July-Dec, 2005). Our industry partners continue to experiment with injection rates and pressures, various downhole and surface facility mechanical configurations, and the huff-n-puff technique to develop best practices for these types of enhanced recovery projects. Subsurface characterization was completed using well log tomography and 3D visualizations to map facies distributions and reservoir properties in the Belle River Mills, Chester 18, Dover 35, and Dover 36 Fields. The Belle River Mills and Chester 18 fields are being used as type-fields because they have excellent log and/or core data coverage. Amplitude slicing of the log porosity, normalized gamma ray, core permeability, and core porosity curves are showing trends that indicate significant heterogeneity and compartmentalization in these reservoirs associated with the original depositional fabric and pore types of the carbonate reservoir rocks. Accumulated pressure data supports the hypothesis of extreme heterogeneity in the Dover 35. Some intervals now have pressure readings over 2345 psig (April 29, 2005) in the A-1 Carbonate while nearby Niagaran Brown intervals only show 1030 psig (March 7, 2005). This is a pressure differential over 1300 psig and suggests significant vertical barriers in the reef, consistent with the GR tomography modeling. Digital and hard copy data have been compiled for the Niagaran reefs in the Michigan Basin, including a detailed summary of 20 fields in the vicinity of the demonstration well. Technology transfer took place through technical presentations regarding visualization of the reservoir heterogeneity in these Niagaran reefs. Oral presentations were given at two Petroleum Technology Transfer Council workshops, a Michigan Oil and Gas Association Conference, a Michigan Basin Geological Society meeting, and the Eastern American Association of Petroleum Geologist's Annual meeting. In addition, we met with our industry partners several times during the first half of 2005 to communicate and discuss the reservoir characterization and field site aspects of the demonstration project. A technical paper was published in the April 2005 issue of the AAPG Bulletin on the characterization of the Belle River Mills Field.

James R. Wood; W. quinlan; A. Wylie

2006-06-01T23:59:59.000Z

262

The Power to Reduce CO2 Emissions: the Full Portfolio  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

energy- efficient CO 2 capture for pulverized coal and integrated gasification combined cycle plants. Both nuclear and advanced coal with CCS technologies are...

263

co2-use-reuse | netl.doe.gov  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

in addition to their conventional energy balances and life cycles. Read more about Carbon Use and Reuse research. Recent studies of current and potential CO2 use...

264

Consumption-based accounting of CO2 emissions  

E-Print Network [OSTI]

Soviet Union (Ukraine, Kazakhstan, Belarus, and Russia),kg CO 2 /$GDP FSS Ukraine Kazakhstan Iran East Asia BelarusAsia China South Africa Kazakhstan Malaysia Russia Thailand

Davis, S. J; Caldeira, K.

2010-01-01T23:59:59.000Z

265

Novel Processes for Power Plant with CO2 Capture.  

E-Print Network [OSTI]

?? The purpose of this thesis was to examine different technologies, which enhances the CO2 partial pressure in the flue gas from the natural gas… (more)

Ekre, Kjetil Vinjerui

2012-01-01T23:59:59.000Z

266

The geomechanics of CO2 storage in deep sedimentary formations  

E-Print Network [OSTI]

strain and microseismicity, well integrity, caprock sealingstrain and microseismicity, well integrity, caprock sealingactions. 7 WELLBORE INTEGRITY The well design of a deep CO 2

Rutqvist, J.

2013-01-01T23:59:59.000Z

267

Enhanced Geothermal Systems (EGS) with CO2as Heat Transmission...  

Broader source: Energy.gov (indexed) [DOE]

precipitation with spatial and temporal flow variations in CO2brinerock systems Tracer Methods for Characterizing Fracture Stimulation in Engineered Geothermal Systems (EGS)...

268

International Symposium on Site Characterization for CO2 Geological Storage  

E-Print Network [OSTI]

EOR) and enhanced coalbed methane recovery (ECBMR) becauseand potential for coalbed methane. The Mannville coals areCO 2 injectivity and coalbed methane producibility. Thus,

Tsang, Chin-Fu

2006-01-01T23:59:59.000Z

269

Summary Report on CO2 Geologic Sequestration & Water Resources Workshop  

E-Print Network [OSTI]

CO 2 Geological Storage and Ground Water Resources U.S.and Ground Water Protection Council (GWPC) State and Federal Statutes Storage,

Varadharajan, C.

2013-01-01T23:59:59.000Z

270

Chemical Impact of Elevated CO2on Geothermal Energy Production  

Broader source: Energy.gov (indexed) [DOE]

Chemical Impact of Elevated CO 2 on Geothermal Energy Production Principal Investigator Susan Carroll Lawrence Livermore National Lab Track Name May 18-20, 2010 This presentation...

271

Quantum Alloys Offer Prospects for CO2 Management Technologies...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

radical new catalysts capable of converting CO2 emissions into fuels, chemicals, and plastics. Their unique discovery involves shrinking gold into a system consisting of just 25...

272

Influence of capillary pressure on CO2 storage and monitoring  

E-Print Network [OSTI]

solutions to mitigate the greenhouse effect. We are interested in analyzing the influence of capillary pressure on CO2 in- jection, storage and monitoring in saline ...

gabriela

273

Advanced Post-Combustion CO2 Capture Prepared for the  

E-Print Network [OSTI]

Advanced Post-Combustion CO2 Capture Prepared for the Clean Air Task Force under a grant from...................................................................................... 3 2. Current Status of Post-Combustion Capture

274

accelerating co2 emissions: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

based on the empirical relationship between CO2 per capita emissions (due to fossil fuel combustion and cement production) and corresponding HDI. In order to project per capita...

275

atmospheric co2 content: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Of Physics Version 4 Gerlich and Ralf D. Tscheuschner Abstract The atmospheric greenhouse effect, an idea that many authors Of The Atmospheric CO2 Greenhouse Effects . . . 3...

276

atmospheric co2 concentrations: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Of Physics Version 4 Gerlich and Ralf D. Tscheuschner Abstract The atmospheric greenhouse effect, an idea that many authors Of The Atmospheric CO2 Greenhouse Effects . . . 3...

277

atmospheric co2 concentration: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Of Physics Version 4 Gerlich and Ralf D. Tscheuschner Abstract The atmospheric greenhouse effect, an idea that many authors Of The Atmospheric CO2 Greenhouse Effects . . . 3...

278

atmospheric co2 measurements: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Of Physics Version 4 Gerlich and Ralf D. Tscheuschner Abstract The atmospheric greenhouse effect, an idea that many authors Of The Atmospheric CO2 Greenhouse Effects . . . 3...

279

atmospheric co2 variations: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Of Physics Version 4 Gerlich and Ralf D. Tscheuschner Abstract The atmospheric greenhouse effect, an idea that many authors Of The Atmospheric CO2 Greenhouse Effects . . . 3...

280

atmospheric co2 mixing: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Of Physics Version 4 Gerlich and Ralf D. Tscheuschner Abstract The atmospheric greenhouse effect, an idea that many authors Of The Atmospheric CO2 Greenhouse Effects . . . 3...

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281

Physical Constraints on Geologic CO2 Sequestration in Low-Volume Basalt Formations  

SciTech Connect (OSTI)

Deep basalt formations within large igneous provinces have been proposed as target reservoirs for carbon capture and sequestration on the basis of favorable CO2-water-rock reaction kinetics that suggest carbonate mineralization rates on the order of 102–103 d. Although these results are encouraging, there exists much uncertainty surrounding the influence of fracture-controlled reservoir heterogeneity on commercial-scale CO2 injections in basalt formations. This work investigates the physical response of a low-volume basalt reservoir to commercial-scale CO2 injections using a Monte Carlo numerical modeling experiment such that model variability is solely a function of spatially distributed reservoir heterogeneity. Fifty equally probable reservoirs are simulated using properties inferred from the deep eastern Snake River Plain aquifer in southeast Idaho, and CO2 injections are modeled within each reservoir for 20 yr at a constant mass rate of 21.6 kg s–1. Results from this work suggest that (1) formation injectivity is generally favorable, although injection pressures in excess of the fracture gradient were observed in 4% of the simulations; (2) for an extensional stress regime (as exists within the eastern Snake River Plain), shear failure is theoretically possible for optimally oriented fractures if Sh is less than or equal to 0.70SV; and (3) low-volume basalt reservoirs exhibit sufficient CO2 confinement potential over a 20 yr injection program to accommodate mineral trapping rates suggested in the literature.

Ryan M. Pollyea; Jerry P. Fairley; Robert K. Podgorney; Travis L. McLing

2014-03-01T23:59:59.000Z

282

Inducinga CO2 leak into ashallow aquifer (CO2FieldLab EUROGIA+ project): Monitoring the CO2 plume in groundwaters.  

E-Print Network [OSTI]

(saline aquifer, depleted oil/gas reservoir), aquifers are ubiquitousin the overlying sedimentary pile in case of unwanted CO2leakages from a storage site. Independently from the nature of the reservoir

Paris-Sud XI, Université de

283

Impact of CO2 quota allocation to new entrants in the electricity market  

E-Print Network [OSTI]

Impact of CO2 quota allocation to new entrants in the electricity market Hans Henrik Lindboe 3.3.3 Germany 27 3.3.4 Sweden 27 4 THE ELECTRICITY MARKET ­ IMPACTS OF ALLOCATION TO NEW ENTRANTS 29 4.1 ELECTRICITY SPOT-MARKET 29 4.2 INVESTMENTS IN POWER PLANTS 33 5 MODEL ANALYSES 40 5.1 MODELLING

284

Synchronous records of pCO2 and D14 C suggest rapid, ocean-derived  

E-Print Network [OSTI]

with the GENIE Earth System Model. We suggest that sharp transitions of pCO2 may have remained undetected so far System Model a b s t r a c t Just before the onset of the Younger Dryas (YD) cold event, several stomatal climate change Stomatal proxy Radiocarbon Younger Dryas Lateglacial Ocean flushing event GENIE Earth

De Boer, Agatha M.

285

EGS rock reactions with Supercritical CO2 saturated with water and water saturated with Supercritical CO2  

SciTech Connect (OSTI)

EGS using CO2 as a working fluid will likely involve hydro-shearing low-permeability hot rock reservoirs with a water solution. After that process, the fractures will be flushed with CO2 that is maintained under supercritical conditions (> 70 bars). Much of the injected water in the main fracture will be flushed out with the initial CO2 injection; however side fractures, micro fractures, and the lower portion of the fracture will contain connate water that will interact with the rock and the injected CO2. Dissolution/precipitation reactions in the resulting scCO2/brine/rock systems have the potential to significantly alter reservoir permeability, so it is important to understand where these precipitates form and how are they related to the evolving ‘free’ connate water in the system. To examine dissolution / precipitation behavior in such systems over time, we have conducted non-stirred batch experiments in the laboratory with pure minerals, sandstone, and basalt coupons with brine solution spiked with MnCl2 and scCO2. The coupons are exposed to liquid water saturated with scCO2 and extend above the water surface allowing the upper portion of the coupons to be exposed to scCO2 saturated with water. The coupons were subsequently analyzed using SEM to determine the location of reactions in both in and out of the liquid water. Results of these will be summarized with regard to significance for EGS with CO2 as a working fluid.

Earl D. Mattson; Travis L. McLing; William Smith; Carl Palmer

2013-02-01T23:59:59.000Z

286

Leakage and Sepage of CO2 from Geologic Carbon Sequestration Sites: CO2 Migration into Surface Water  

E-Print Network [OSTI]

from geologic carbon sequestration sites: unsaturated zoneCO 2 from Geologic Carbon Sequestration Sites, Vadose Zoneseepage from geologic carbon sequestration sites may occur.

Oldenburg, Curt M.; Lewicki, Jennifer L.

2005-01-01T23:59:59.000Z

287

Spatial Disaggregation of CO2 Emissions for the State of California  

SciTech Connect (OSTI)

This report allocates California's 2004 statewide carbon dioxide (CO2) emissions from fuel combustion to the 58 counties in the state. The total emissions are allocated to counties using several different methods, based on the availability of data for each sector. Data on natural gas use in all sectors are available by county. Fuel consumption by power and combined heat and power generation plants is available for individual plants. Bottom-up models were used to distribute statewide fuel sales-based CO2 emissions by county for on-road vehicles, aircraft, and watercraft. All other sources of CO2 emissions were allocated to counties based on surrogates for activity. CO2 emissions by sector were estimated for each county, as well as for the South Coast Air Basin. It is important to note that emissions from some sources, notably electricity generation, were allocated to counties based on where the emissions were generated, rather than where the electricity was actually consumed. In addition, several sources of CO2 emissions, such as electricity generated in and imported from other states and international marine bunker fuels, were not included in the analysis. California Air Resource Board (CARB) does not include CO2 emissions from interstate and international air travel, in the official California greenhouse gas (GHG) inventory, so those emissions were allocated to counties for informational purposes only. Los Angeles County is responsible for by far the largest CO2 emissions from combustion in the state: 83 Million metric tonnes (Mt), or 24percent of total CO2 emissions in California, more than twice that of the next county (Kern, with 38 Mt, or 11percent of statewide emissions). The South Coast Air Basin accounts for 122 MtCO2, or 35percent of all emissions from fuel combustion in the state. The distribution of emissions by sector varies considerably by county, with on-road motor vehicles dominating most counties, but large stationary sources and rail travel dominating in other counties.The CO2 emissions data by county and source are available upon request.

de la Rue du Can, Stephane; de la Rue du Can, Stephane; Wenzel, Tom; Fischer, Marc

2008-06-11T23:59:59.000Z

288

Insights into Silicate Carbonation Processes in Water-Bearing Supercritical CO2 Fluids  

SciTech Connect (OSTI)

Long-term geologic storage of carbon dioxide (CO2) is considered an integral part to moderating CO2 concentrations in the atmosphere and subsequently minimizing effects of global climate change. Although subsurface injection of CO2 is common place in certain industries, deployment at the scale required for emission reduction is unprecedented and therefore requires a high degree of predictability. Accurately modeling geochemical processes in the subsurface requires experimental derived data for mineral reactions occurring between the CO2, water, and rocks. Most work in this area has focused on aqueous-dominated systems in which dissolved CO2 reacts to form crystalline carbonate minerals. Comparatively little laboratory research has been conducted on reactions occurring between minerals in the host rock and the wet supercritical fluid phase. In this work, we studied the carbonation of wollastonite [CaSiO3] exposed to variably hydrated supercritical CO2 (scCO2) at a range of temperatures (50, 55 and 70 °C) and pressures (90,120 and 160 bar) that simulate conditions in geologic repositories. Mineral transformation reactions were followed by three novel in situ high pressure techniques, including x-ray diffraction that tracked the rate and extents of wollastonite conversion to calcite. Increased dissolved water concentrations in the supercritical CO2 resulted in increased silicate carbonation approaching ~50 wt. %. Development of thin water films on the mineral surface were directly observed with infrared spectroscopy and determined to be critical for facilitating carbonation processes. Even in extreme low water conditions, magic angle spinning nuclear magnetic resonance detected formation of Q3 [Si(OSi)3OH] and Q4 [Si(OSi)4] amorphous silica species. Unlike the thick (<10 ?m) passivating silica layers observed in the fully water saturated scCO2 experiments, images obtained from a focused ion beam sectioned sample indicted these coatings were chemically wollastonite but structurally amorphous. In addition, evidence of an intermediate hydrated amorphous calcium carbonate forming under these conditions further emphasize the importance of understanding geochemical processes occurring in water bearing scCO2 fluids.

Miller, Quin RS; Thompson, Christopher J.; Loring, John S.; Windisch, Charles F.; Bowden, Mark E.; Hoyt, David W.; Hu, Jian Z.; Arey, Bruce W.; Rosso, Kevin M.; Schaef, Herbert T.

2013-07-01T23:59:59.000Z

289

Highlights of the 2009 SEG summer research workshop on "CO2 Sequestration Geophysics"  

E-Print Network [OSTI]

CO 2 saturation at the Weyburn CO 2 EOR injection project inMonitoring CO 2 storage during EOR at the Weyburn-Midalean excellent example of a CO 2 EOR (enhanced oil recovery)

Lumley, D.

2010-01-01T23:59:59.000Z

290

Single photon ionization of van der Waals clusters with a soft x-ray laser: ,,CO2...n and ,,CO2...n,,H2O...m  

E-Print Network [OSTI]

Single photon ionization of van der Waals clusters with a soft x-ray laser: ,,CO2...n and ,,CO2...n 2006; published online 20 October 2006 Pure neutral CO2 n clusters and mixed CO2 n H2O m clustersV. The distribution of pure CO2 n clusters decreases roughly exponentially with increasing cluster size. During

Rocca, Jorge J.

291

Screening and ranking framework (SRF) for geologic CO2 storagesite selection on the basis of HSE risk  

SciTech Connect (OSTI)

A screening and ranking framework (SRF) has been developedto evaluate potential geologic carbon dioxide (CO2) storage sites on thebasis of health, safety, and environmental (HSE) risk arising from CO2leakage. The approach is based on the assumption that CO2 leakage risk isdependent on three basic characteristics of a geologic CO2 storage site:(1) the potential for primary containment by the target formation; (2)the potential for secondary containment if the primary formation leaks;and (3) the potential for attenuation and dispersion of leaking CO2 ifthe primary formation leaks and secondary containment fails. Theframework is implemented in a spreadsheet in which users enter numericalscores representing expert opinions or published information along withestimates of uncertainty. Applications to three sites in Californiademonstrate the approach. Refinements and extensions are possible throughthe use of more detailed data or model results in place of propertyproxies.

Oldenburg, Curtis M.

2006-11-27T23:59:59.000Z

292

Amplitude Analysis and Measurement of the Time-dependent CP Asymmetry of B0 to KsKsKs Decays  

SciTech Connect (OSTI)

We present the first results on the Dalitz-plot structure and improved measurements of the time-dependent CP-violation parameters of the process B{sup 0} {yields} K{sub S}{sup 0}K{sub S}{sup 0}K{sub S}{sup 0} obtained using 468 x 10{sup 6} B{bar B} decays collected with the BABAR detector at the PEP-II asymmetric-energy B factory at SLAC. The Dalitz-plot structure is probed by a time-integrated amplitude analysis that does not distinguish between B{sup 0} and {bar B}{sup 0} decays. We measure the total inclusive branching fraction {Beta}(B{sup 0} {yields} K{sub S}{sup 0}K{sub S}{sup 0}K{sub S}{sup 0}) = (6.19 {+-} 0.48 {+-} 0.15 {+-} 0.12) x 10{sup -6}, where the first uncertainty is statistical, the second is systematic, and the third represents the Dalitz-plot signal model dependence. We also observe evidence for the intermediate resonant states f{sub 0}(980), f{sub 0}(1710), and f{sub 2}(2010). Their respective product branching fractions are measured to be (2.70{sub -1.19}{sup +1.25} {+-} 0.36 {+-} 1.17) x 10{sup -6}, (0.50{sub -0.24}{sup +0.46} {+-} 0.04 {+-} 0.10) x 10{sup -6}, and (0.54{sub -0.20}{sup +0.21} {+-} 0.03 {+-} 0.52) x 10{sup -6}. Additionally, we determine the mixing-induced CP-violation parameters to be S = -0.94{sub -0.21}{sup +0.24} {+-} 0.06 and C = -0.17 {+-} 0.18 {+-} 0.04, where the first uncertainty is statistical and the second is systematic. These values are in agreement with the standard model expectation.

Lees, J.P.

2012-04-11T23:59:59.000Z

293

Chemical Impact of Elevated CO2on Geothermal Energy Production  

Broader source: Energy.gov [DOE]

This is a two phase project to assess the geochemical impact of CO2on geothermal energy production by: analyzing the geochemistry of existing geothermal fields with elevated natural CO2; measuring realistic rock-water rates for geothermal systems using laboratory and field-based experiments to simulate production scale impacts.

294

Implementation of the El Mar (Delaware) Unit CO2 flood  

SciTech Connect (OSTI)

Union Royalty, Inc., Amoco Production Company, and Enron Liquids Pipeline Company recently announced that they have commenced operations of an innovative enhanced oil recovery project at the El Mar (Delaware) Unit in Loving County, Texas, about 100 miles west of Midland, Texas. The project will convert the unit`s existing oil recovery system from a secondary (waterflood) system to a tertiary (CO2 flood) system designed to use carbon dioxide and water to increase crude oil production from the unit. What makes this EOR project unique is the creative deal structured by the partners involved. Amoco, Union Royalty, and Enron have worked out an unprecedented arrangement whereby Amoco essentially trades CO2 for an interest in Union Royalty`s future oil production from the unit. By pioneering this innovative deal new production life has been restored to a field that otherwise might dry up. Enron is participating in the project by transporting CO2 to the unit via a 40-mile expansion of its Central Basin Pipeline system from the Dollarhide oil field in Andrews county, Texas. The project will be implemented in four phases. The first phase in operation today comprises seven CO2 injection wells which have begun to process the reservoir with CO2. Plans now call for more CO2 injectors to be installed during the next three to five years until a total of 65 CO2 injectors and an on-site CO2 compression facility serve the unit`s 70 production wells.

McKnight, T.N. Jr. [Union Royalty, Inc., Midland, TX (United States); Merchant, D.L.

1995-12-31T23:59:59.000Z

295

THERMOCATALYTIC CO2-FREE PRODUCTION OF HYDROGEN FROM HYDROCARBON FUELS  

E-Print Network [OSTI]

THERMOCATALYTIC CO2- FREE PRODUCTION OF HYDROGEN FROM HYDROCARBON FUELS N. Muradov Florida Solar Energy Center 1679 Clearlake Road, Cocoa, Florida 32922 tel. 321-638-1448, fax. 321-638-1010, muradov (except for the start-up operation). This results in the following advantages: (1) no CO/CO2 byproducts

296

Distribution of anthropogenic CO2 in the Pacific Ocean  

E-Print Network [OSTI]

Distribution of anthropogenic CO2 in the Pacific Ocean C. L. Sabine,1 R. A. Feely,2 R. M. Key,3 J] This work presents an estimate of anthropogenic CO2 in the Pacific Ocean based on measurements from the WOCE tracers; 9355 Information Related to Geographic Region: Pacific Ocean; KEYWORDS: Pacific Ocean

297

Comprehensive Monitoring of CO2 Sequestration in Subalpine Forest Ecosystems  

E-Print Network [OSTI]

, carbon sequestration, ecosystem, multi-tier, multi-modal, multi-scale, self organized, sensor array to comprehensively monitor ecosystem carbon sequestration. The network consists of CO2, Weather (pressureComprehensive Monitoring of CO2 Sequestration in Subalpine Forest Ecosystems and Its Relation

Han, Richard Y.

298

Oxidation in Environments with Elevated CO2 Levels  

SciTech Connect (OSTI)

Efforts to reduce greenhouse gas emissions from fossil energy power productions focus primarily on either pre- or post-combustion removal of CO2. The research presented here examines corrosion and oxidation issues associated with two types of post-combustion CO2 removal processes—oxyfuel combustion in refit boilers and oxyfuel turbines.

Gordon H. Holcomb

2009-05-01T23:59:59.000Z

299

Energy solutions for CO2 emission peak and subsequent decline  

E-Print Network [OSTI]

Energy solutions for CO2 emission peak and subsequent decline Edited by Leif Sønderberg Petersen and Hans Larsen Risø-R-1712(EN) September 2009 Proceedings Risø International Energy Conference 2009 #12;Editors: Leif Sønderberg Petersen and Hans Larsen Title: Energy solutions for CO2 emission peak

300

Using CO2 & Algae to Treat Wastewater and  

E-Print Network [OSTI]

Using CO2 & Algae to Treat Wastewater and Produce Biofuel Feedstock Tryg Lundquist Cal Poly State School, UCSB March 23, 2007 #12;CO2 and Wastewater Treatment · WW Treatment Technologies · Scale Actinastrum sp. #12;Major Wastewater Treatment Technologies in U.S. Activated Sludge 6,800 Facilities 25

Keller, Arturo A.

Note: This page contains sample records for the topic "ks modeling co2" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Original article Responses to elevated atmospheric CO2 concentration  

E-Print Network [OSTI]

Original article Responses to elevated atmospheric CO2 concentration and nitrogen supply of Quercus* School of Forest Resources and Conservation, University of Florida, 326 Newins-Ziegler Hall, Gainesville. Elevated [CO2] increased biomass production only in the high-N treatment. Fine root/foliage mass ratio

Paris-Sud XI, Université de

302

HYDROMECHANICAL CHARACTERIZATION FOR SITE SELECTION IN CO2 PERMANENT  

E-Print Network [OSTI]

-BarcelonaTech), Barcelona, Spain 3 Energy City Foundation (CIUDEN), Spanish Government CO2 Geological Storage Programme (Vilarrasa et al., 2011, Energy Procedia) Trees killed by CO2 leakage in Mammoth Mountains (Farrar et al EQUATIONS Mass conservation equation Darcy's law Momentum balance Effective stress Hooke's law (linear

Politècnica de Catalunya, Universitat

303

Falsification Of The Atmospheric CO2 Greenhouse Effects  

E-Print Network [OSTI]

Falsification Of The Atmospheric CO2 Greenhouse Effects Within The Frame Of Physics Version 4 Gerlich and Ralf D. Tscheuschner Abstract The atmospheric greenhouse effect, an idea that many authors Of The Atmospheric CO2 Greenhouse Effects . . . 3 Contents Abstract 2 1 Introduction 6 1.1 Problem background

Learned, John

304

Ex post evaluations of CO2 based taxes: a survey  

E-Print Network [OSTI]

of fossil fuels, and which are introduced with the explicit intention of abating CO2 emissions. This paper and, especially, subsidies, has been called into question. Secondly, the CO2-based taxes themselves and subsidies), it is unlikely that they have been cost-effective (in the sense of attaining their environmental

Watson, Andrew

305

European and Global Perspectives for CO2 Capture and Storage  

E-Print Network [OSTI]

plants. Therefore, it is recommended to employ mixes of the different CO2 emission reduction options are compared in order to address the question how to achieve significant CO2 emission reductions through2 emission reductions through the application of CCS technologies. The analysis shows that CCS can

306

Quantifying Regional Economic Impacts of CO2 Intensity Targets in China  

E-Print Network [OSTI]

To address rising energy use and CO2 emissions, China’s leadership has enacted energy and CO2 intensity

Zhang, Da

2012-09-01T23:59:59.000Z

307

Analysis of Potential Energy Saving and CO2 Emission Reduction of Home Appliances and Commercial Equipments in China  

E-Print Network [OSTI]

Others* Air Conditioner Frozen Scenario Total CO2 EmissionsCO2 Emissions (million tonnes CO2)Improvement Scenario Total CO2 Emissions *Others include:

Zhou, Nan

2011-01-01T23:59:59.000Z

308

Exsolution Enhanced Oil Recovery with Concurrent CO2 Sequestration  

SciTech Connect (OSTI)

A novel EOR method using carbonated water injection followed by depressurization is introduced. Results from micromodel experiments are presented to demonstrate the fundamental principles of this oil recovery method. A depressurization process (1 MPa/hr) was applied to a micromodel following carbonated water injection (Ca ? 10-5). The exsolved CO2 in water-filled pores blocked water flow in swiped portions and displaced water into oil-filled pores. Trapped oil after the carbonated water injection was mobilized by sequentially invading water. This method's self-distributed mobility control and local clogging was tested in a sandstone sample under reservoir conditions. A 10% incremental oil recovery was achieved by lowering the pressure 2 MPa below the CO2 liberation pressure. Additionally, exsolved CO2 resides in the pores of a reservoir as an immobile phase with a high residual saturation after oil production, exhibiting a potential synergy opportunity between CO2 EOR and CO2 sequestration

Zuo, Lin; Benson, Sally M.

2013-01-01T23:59:59.000Z

309

3, 17631780, 2006 CO2-calcification  

E-Print Network [OSTI]

an ensemble of realizations of an Earth system model that encapsulates a comparable range of un- certainty

Boyer, Edmond

310

SUBTASK 2.19 – OPERATIONAL FLEXIBILITY OF CO2 TRANSPORT AND STORAGE  

SciTech Connect (OSTI)

Carbon dioxide (CO2) is produced in large quantities during electricity generation and by industrial processes. These CO2 streams vary in terms of both composition and mass flow rate, sometimes substantially. The impact of a varying CO2 stream on pipeline and storage operation is not fully understood in terms of either operability or infrastructure robustness. This study was performed to summarize basic background from the literature on the topic of operational flexibility of CO2 transport and storage, but the primary focus was on compiling real-world lessons learned about flexible operation of CO2 pipelines and storage from both large-scale field demonstrations and commercial operating experience. Modeling and pilot-scale results of research in this area were included to illustrate some of the questions that exist relative to operation of carbon capture and storage (CCS) projects with variable CO2 streams. It is hoped that this report’s real-world findings provide readers with useful information on the topic of transport and storage of variable CO2 streams. The real-world results were obtained from two sources. The first source consisted of five full-scale, commercial transport–storage projects: Sleipner, Snøhvit, In Salah, Weyburn, and Illinois Basin–Decatur. These scenarios were reviewed to determine the information that is available about CO2 stream variability/intermittency on these demonstration-scale projects. The five projects all experienced mass flow variability or an interruption in flow. In each case, pipeline and/or injection engineers were able to accommodate any issues that arose. Significant variability in composition has not been an issue at these five sites. The second source of real- world results was telephone interviews conducted with experts in CO2 pipeline transport, injection, and storage during which commercial anecdotal information was acquired to augment that found during the literature search of the five full-scale projects. The experts represented a range of disciplines and hailed from North America and Europe. Major findings of the study are that compression and transport of CO2 for enhanced oil recovery (EOR) purposes in the United States has shown that impurities are not likely to cause transport problems if CO2 stream composition standards are maintained and pressures are kept at 10.3 MPa or higher. Cyclic, or otherwise intermittent, CO2 supplies historically have not impacted in-field distribution pipeline networks, wellbore integrity, or reservoir conditions. The U.S. EOR industry has demonstrated that it is possible to adapt to variability and intermittency in CO2 supply through flexible operation of the pipeline and geologic storage facility. This CO2 transport and injection experience represents knowledge that can be applied in future CCS projects. A number of gaps in knowledge were identified that may benefit from future research and development, further enhancing the possibility for widespread application of CCS. This project was funded through the Energy & Environmental Research Center–U.S. Department of Energy Joint Program on Research and Development for Fossil Energy-Related Resources Cooperative Agreement No. DE-FC26-08NT43291. Nonfederal funding was provided by the IEA Greenhouse Gas R&D Programme.

Jensen, Melanie; Schlasner, Steven; Sorensen, James; Hamling, John

2014-12-31T23:59:59.000Z

311

Carbon storage: the economic efficiency of storing CO2 in leaky reservoirs  

E-Print Network [OSTI]

industry routinely injects CO2 underground to enhance oil recovery (CO2-EOR). A bit more than two thousand kilometers of CO2 pipelines have been laid in Texas to provide for CO2- EOR. In these operations the goal must pay for the CO2. Yet at the end of an EOR operation a major fraction of CO2 purchased remains

Paris-Sud XI, Université de

312

Predicting PVT data for CO2brine mixtures for black-oil simulation of CO2 geological storage  

E-Print Network [OSTI]

Predicting PVT data for CO2­brine mixtures for black-oil simulation of CO2 geological storage efficiency of the black-oil approach promote application of black-oil simulation for large-scale geological into geological formations has been considered as a potential method to mitigate climate change. Accurate

Santos, Juan

313

Performance Analysis of a Transcritical CO2 Heat Pump Water Heater Incorporating a Brazed-Plate Gas-cooler.  

E-Print Network [OSTI]

??This study focuses on the experimental testing and numerical modeling of a 4.5 kW transcritical CO2 heat pump water heater at Queen’s University in the… (more)

Murray, PORTIA

2015-01-01T23:59:59.000Z

314

Semi-analytical Solution for Multiphase Fluid Flow Applied to CO2 Sequestration in Geologic Porous Media  

E-Print Network [OSTI]

atmospheric emissions of CO_(2). Feasibility assessments of proposed sequestration sites require realistic and computationally efficient models to simulate the subsurface pressure response and monitor the injection process, and quantify the risks of leakage...

Mohamed, Ahmed Mohamed Anwar Sayed

2013-08-01T23:59:59.000Z

315

Odors that Modify CO2 Receptor Activity in Insects and Their Effect on Innate CO2-Mediated Behavior and Neuronal Plasticity  

E-Print Network [OSTI]

Intermediates in Insect CO2 Sensory Systems. Science Certel,2007). The molecular basis of CO2 reception in Drosophila.J. (2004). Floral CO2 Reveals Flower Profitability to Moths.

Turner, Stephanie

2010-01-01T23:59:59.000Z

316

Enhanced geothermal systems (EGS) with CO2 as heat transmission fluid--A scheme for combining recovery of renewable energy with geologic storage of CO2  

E-Print Network [OSTI]

Could Sequestration of CO2 be Combined with the DevelopmentTOUGH2 Code for Studies of CO2 Storage in Saline Aquifers,and J. Ennis- King. CO2-H2O Mixtures in the Geological

Pruess, K.

2010-01-01T23:59:59.000Z

317

Health, Safety, and Environmental Screening and Ranking Frameworkfor Geologic CO2 Storage Site Selection  

SciTech Connect (OSTI)

This report describes a screening and ranking framework(SRF) developed to evaluate potential geologic carbon dioxide (CO2) storage sites on the basis of health, safety, and environmental (HSE) risk arising from possible CO2 leakage. The approach is based on the assumption that HSE risk due to CO2 leakage is dependent on three basic characteristics of a geologic CO2 storage site: (1) the potential for primary containment by the target formation; (2) the potential for secondary containment if the primary formation leaks; and (3) the potential for attenuation and dispersion of leaking CO2 if the primary formation leaks and secondary containment fails. The framework is implemented in a spreadsheet in which users enter numerical scores representing expert opinions or general information available from published materials along with estimates of uncertainty to evaluate the three basic characteristics in order to screen and rank candidate sites. Application of the framework to the Rio Visa Gas Field, Ventura Oil Field, and Mammoth Mountain demonstrates the approach. Refinements and extensions are possible through the use of more detailed data or model results in place of property proxies. Revisions and extensions to improve the approach are anticipated in the near future as it is used and tested by colleagues and collaborators.

Oldenburg, Curtis M.

2005-09-19T23:59:59.000Z

318

CO2 Capture with Liquid-to-Solid Absorbents: CO2 Capture Process Using Phase-Changing Absorbents  

SciTech Connect (OSTI)

IMPACCT Project: GE and the University of Pittsburgh are developing a unique CO2 capture process in which a liquid absorbent, upon contact with CO2, changes into a solid phase. Once in solid form, the material can be separated and the CO2 can be released for storage by heating. Upon heating, the absorbent returns to its liquid form, where it can be reused to capture more CO2. The approach is more efficient than other solventbased processes because it avoids the heating of extraneous solvents such as water. This ultimately leads to a lower cost of CO2 capture and will lower the additional cost to produce electricity for coal-fired power plants that retrofit their facilities to include this technology.

None

2010-10-01T23:59:59.000Z

319

Hybrid heat exchange for the compression capture of CO2 from recirculated flue gas  

SciTech Connect (OSTI)

An approach proposed for removal of CO2 from flue gas cools and compresses a portion of a recirculated flue-gas stream, condensing its volatile materials for capture. Recirculating the flue gas concentrates SOx, H2O and CO2 while dramatically reducing N2 and NOx, enabling this approach, which uses readily available industrial components. A hybrid system of indirect and direct-contact heat exchange performs heat and mass transfer for pollutant removal and energy recovery. Computer modeling and experimentation combine to investigate the thermodynamics, heat and mass transfer, chemistry and engineering design of this integrated pollutant removal (IPR) system.

Oryshchyn, Danylo B.; Ochs, Thomas L.; Summers, Cathy A.

2004-01-01T23:59:59.000Z

320

Combustion-Assisted CO2 Capture Using MECC Membranes  

SciTech Connect (OSTI)

Mixed Electron and Carbonate ion Conductor (MECC) membranes have been proposed as a means to separate CO2 from power plant flue gas. Here a modified MECC CO2 capture process is analyzed that supplements retentate pressurization and permeate evacuation as a means to create a CO2 driving force with a process assisted by the catalytic combustion of syngas on the permeate side of the membrane. The combustion reactions consume transported oxygen, making it unavailable for the backwards transport reaction. With this change, the MECC capture system becomes exothermic, and steam for electricity production may be generated from the waste heat. Greater than 90% of the CO2 in the flue gas may be captured, and a compressed CO2 product stream is produced. A fossil-fueled power plant using this process would consume 14% more fuel per unit electricity produced than a power plant with no CO2 capture system, and has the potential to meet U.S. DOE s goal that deployment of a CO2 capture system at a fossil-fueled power plant should not increase the cost of electricity from the combined facility by more than 30%.

Sherman, Steven R [ORNL; Gray, Dr. Joshua R. [Savannah River National Laboratory (SRNL), Aiken, S.C.; Brinkman, Dr. Kyle S. [Savannah River National Laboratory (SRNL), Aiken, S.C.; Huang, Dr. Kevin [University of South Carolina, Columbia

2012-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "ks modeling co2" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Evaluating impacts of CO2 gas intrusion into a confined sandstone aquifer: Experimental results  

SciTech Connect (OSTI)

Deep subsurface storage and sequestration of CO2 has been identified as a potential mitigation technique for rising atmospheric CO2 concentrations. Sequestered CO2 represents a potential risk to overlying aquifers if the CO2 leaks from the deep storage reservoir. Experimental and modeling work is required to evaluate potential risks to groundwater quality and develop a systematic understanding of how CO2 leakage may cause important changes in aquifer chemistry and mineralogy by promoting dissolution/precipitation, adsorption/desorption, and redox reactions. Sediments from the High Plains aquifer in Kansas, United States, were used in this investigation, which is part of the National Risk Assessment Partnership Program sponsored by the US Department of Energy. This aquifer was selected to be representative of consolidated sand and gravel/sandstone aquifers overlying potential CO2 sequestration repositories within the continental US. In this paper, we present results from batch experiments conducted at room temperature and atmospheric pressure with four High Plains aquifer sediments. Batch experiments simulate sudden, fast, and short-lived releases of the CO2 gas as would occur in the case of well failure during injection. Time-dependent release of major, minor, and trace elements were determined by analyzing the contacting solutions. Characterization studies demonstrated that the High Plains aquifer sediments were abundant in quartz and feldspars, and contained about 15 to 20 wt% montmorillonite and up to 5 wt% micas. Some of the High Plains aquifer sediments contained no calcite, while others had up to about 7 wt% calcite. The strong acid extraction tests confirmed that in addition to the usual elements present in most soils, rocks, and sediments, the High Plains aquifer sediments had appreciable amounts of As, Cd, Pb, Cu, and occasionally Zn, which potentially may be mobilized from the solid to the aqueous phase during or after exposure to CO2. However, the results from the batch experiments showed that the High Plains sediments mobilized only low concentrations of trace elements (potential contaminants), which were detected occasionally in the aqueous phase during these experiments. Importantly, these occurrences were more frequent in the calcite-free sediment. Results from these investigations provide useful information to support site selection, risk assessment, and public education efforts associated with geological CO2 storage and sequestration.

Qafoku, Nikolla; Lawter, Amanda R.; Shao, Hongbo; Wang, Guohui; Brown, Christopher F.

2014-12-31T23:59:59.000Z

322

State Regulatory Framework Will Most Likely Result in Robust CO2 Pipeline System, New Study Says  

Broader source: Energy.gov [DOE]

A private sector model with a state rather than Federal-based regulatory framework is the approach that will "most likely result in a robust CO2 pipeline system" in the United States, according to a new report developed with funding from the U.S. Department of Energy’s National Energy Technology Laboratory.

323

Fuel Chemistry Division Preprints 2001, 46(1), 217 CO2 ADSORPTION ON CARBONACEOUS SURFACES  

E-Print Network [OSTI]

on cellulose char. In order to compare the theoretical data of CO2 adsorption energy on carbon models, we have for Theoretical Chemistry, Dept. of Chemistry University of Utah, 315 South 1400 East, Room 2020 Salt Lake City the volumetric technique and it is compared to the theoretical prediction. Such comparison allows us to elucidate

Truong, Thanh N.

324

2. INVESTIGATION OF CO2 GRAVITY DRAINAGE AFTER WATER INJECTION IN FRACTURED SYSTEMS  

E-Print Network [OSTI]

on whole diameter Berea cores and Spraberry cores under the conditions of reservoir temperature fractured cores, five experiments had been performed on Berea and Spraberry reservoir cores. The properties investigations was designed to model the actual field experience of waterflooding followed by CO2 injection

Schechter, David S.

325

Methanogenic Conversion of CO2 Into CH4  

SciTech Connect (OSTI)

This SBIR project evaluated the potential to remediate geologic CO2 sequestration sites into useful methane gas fields by application of methanogenic bacteria. Such methanogens are present in a wide variety of natural environments, converting CO2 into CH4 under natural conditions. We conclude that the process is generally feasible to apply within many of the proposed CO2 storage reservoir settings. However, extensive further basic R&D still is needed to define the precise species, environments, nutrient growth accelerants, and economics of the methanogenic process. Consequently, the study team does not recommend Phase III commercial application of the technology at this early phase.

Stevens, S.H., Ferry, J.G., Schoell, M.

2012-05-06T23:59:59.000Z

326

Et notat til "det elektriske CO2 projekt". Med udgangspunkt i de studerendes CO2 tips analyseres CO2 emissionen i de forskellige belysningssituationer. De forskellige tips ses p projektets hjemmeside  

E-Print Network [OSTI]

1 Et notat til "det elektriske CO2 projekt". Med udgangspunkt i de studerendes CO2 tips analyseres CO2 emissionen i de forskellige belysningssituationer. De forskellige tips ses på projektets hjemmeside www.co2tips.dk Indholdsfortegnelse EL-FORBRUG TIL BELYSNING I HUSHOLDNINGER

327

International Symposium on Site Characterization for CO2 Geological Storage  

E-Print Network [OSTI]

in depleted or abandoned oil and gas reservoirs; how- ever,abandoned wells represent a potentially direct route from reservoirabandoned in the 1930s with no barrier installed after it encountered a natural CO 2 reservoir

Tsang, Chin-Fu

2006-01-01T23:59:59.000Z

328

International Symposium on Site Characterization for CO2 Geological Storage  

E-Print Network [OSTI]

in depleted or abandoned oil and gas reservoirs; how- ever,oil well abandoned in the 1930s with no barrier installed after it encountered a natural CO 2 reservoir

Tsang, Chin-Fu

2006-01-01T23:59:59.000Z

329

The geomechanics of CO2 storage in deep sedimentary formations  

E-Print Network [OSTI]

such as depleted oil and gas reservoirs, unminable coaltakes place in depleted oil or gas reservoirs (IAE, 2003).of CO 2 in depleted oil and gas reservoirs. J Can Pet

Rutqvist, J.

2013-01-01T23:59:59.000Z

330

International Symposium on Site Characterization for CO2 Geological Storage  

E-Print Network [OSTI]

IN DEPLETED AND NEAR- DEPLETED OIL RESERVOIRS V. A. KuuskraaDEPLETED AND NEAR-DEPLETED OIL RESERVOIRS Vello A. Kuuskraaof CO 2 in a depleted oil reservoir: an overview,

Tsang, Chin-Fu

2006-01-01T23:59:59.000Z

331

Novel CO2-Thickeners for Improved Mobility Control  

SciTech Connect (OSTI)

The objective of this contract was to design, synthesize, and characterize thickening agents for dense carbon dioxide and to evaluate their solubility and viscosity-enhancing potential in CO2.

Enick, Dr. Robert M.; Beckman, Dr. Eric J.; Hamilton, Dr. Andrew

2002-01-15T23:59:59.000Z

332

CO2 MONITORING FOR DEMAND CONTROLLED VENTILATION IN COMMERCIAL BUILDINGS  

E-Print Network [OSTI]

Transactions 105(2). Emmerich, S. J. and A. K. Persily (Fisk and de Almeida 1998; Emmerich and Persily 2001), CO 2Fisk and de Almeida 1998; Emmerich and Persily 2001; Apte

Fisk, William J.

2010-01-01T23:59:59.000Z

333

Bees, Balloons, Pollen Used as Novel CO2 Monitoring Approach  

Broader source: Energy.gov [DOE]

Researchers at the Office of Fossil Energy's National Energy Technology Laboratory have discovered an innovative way to use bees, pollen, and helium-filled balloons to verify that no carbon dioxide (CO2) leaks from carbon sequestration sites.

334

Canada’s Bitumen Industry Under CO2 Constraints  

E-Print Network [OSTI]

We investigate the effects of implementing CO2 emissions reduction policies on Canada’s oil sands industry, the largest of its kind in the world. The production of petroleum products from oils sands involves extraction of ...

Chen, Y.-H. Henry

335

International Symposium on Site Characterization for CO2 Geological Storage  

E-Print Network [OSTI]

FEASIBILITY: TEAPOT DOME EOR PILOT L. Chiaramonte, M.TO IDENTIFY OPTIMAL CO 2 EOR STORAGE SITES V. Núñez Lopez,from a carbon dioxide EOR/sequestration project. Energy

Tsang, Chin-Fu

2006-01-01T23:59:59.000Z

336

From CO2 to Methanol via Novel Nanocatalysts  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Here, Graciani et al. report on a new nanocatalyst that can do just that for CO2- in producing methanol, a key industrial chemical commonly used to make other chemicals and...

337

International Symposium on Site Characterization for CO2 Geological Storage  

E-Print Network [OSTI]

carbon dioxide-enhanced oil recovery project as a prototypeCO 2 injection for enhanced oil recovery. Indeed, most near-as well as Enhanced Oil Recovery projects. REFERENCES

Tsang, Chin-Fu

2006-01-01T23:59:59.000Z

338

Improving CO2 Efficiency for Recovering Oil in Heterogeneous Reservoirs  

SciTech Connect (OSTI)

The work strived to improve industry understanding of CO2 flooding mechanisms with the ultimate goal of economically recovering more of the U.S. oil reserves. The principle interests are in the related fields of mobility control and injectivity.

Grigg, Reid B.; Svec, Robert K.

2003-03-10T23:59:59.000Z

339

Quantum Chemistry of CO2 Interaction with Swelling Clays | netl...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Quantum Chemistry of CO2 Interaction with Swelling Clays Sep 2014 Aug 2014 Jul 2014 June 2014 May 2014 Apr 2014 Mar 2014 Feb 2014 Jan 2014 Dec 2013 Nov 2013 Oct 2013 Sep 2013 Aug...

340

Implications of "peak oil" for atmospheric CO2 and climate  

E-Print Network [OSTI]

Peaking of global oil production may have a large effect on future atmospheric CO2 amount and climate change, depending upon choices made for subsequent energy sources. We suggest that, if estimates of oil and gas reserves by the Energy Information Administration are realistic, it is feasible to keep atmospheric CO2 from exceeding approximately 450 ppm, provided that future exploitation of the huge reservoirs of coal and unconventional fossil fuels incorporates carbon capture and sequestration. Existing coal-fired power plants, without sequestration, must be phased out before mid-century to achieve this limit on atmospheric CO2. We also suggest that it is important to "stretch" oil reserves via energy efficiency, thus avoiding the need to extract liquid fuels from coal or unconventional fossil fuels. We argue that a rising price on carbon emissions is probably needed to keep CO2 beneath the 450 ppm ceiling.

Kharecha, P A

2007-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "ks modeling co2" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Electron Transfer Dynamics in Photocatalytic CO2 Conversion ...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Electron Transfer Dynamics in Photocatalytic CO2 Conversion Sep 2014 Aug 2014 Jul 2014 June 2014 May 2014 Apr 2014 Mar 2014 Feb 2014 Jan 2014 Dec 2013 Nov 2013 Oct 2013 Sep 2013...

342

DOE Manual Studies 11 Major CO2 Geologic Storage Formations  

Broader source: Energy.gov [DOE]

A comprehensive study of 11 geologic formations suitable for permanent underground carbon dioxide (CO2) storage is contained in a new manual issued by the U.S. Department of Energy.

343

CO2 gas/oil ratio prediction in a multi-component reservoir bycombined seismic and electromagnetic imaging  

SciTech Connect (OSTI)

Crosswell seismic and electromagnetic data sets taken before and during CO2 flooding of an oil reservoir are inverted to produce crosswell images of the change in compressional velocity, shear velocity and electrical conductivity during a CO2 injection pilot study. A rock properties model is developed using measured log porosity, fluid saturations, pressure, temperature, bulk density, sonic velocity and electrical conductivity. The parameters of the rock properties model are found by an L1-norm simplex minimization of predicted and observed compressional velocity and density. A separate minimization using Archie's law provides parameters for modeling the relations between water saturation, porosity and the electrical conductivity. The rock properties model is used to generate relationships between changes in geophysical parameters and changes in reservoir parameters. The electrical conductivity changes are directly mapped to changes in water saturation. The estimated changes in water saturation are used with the observed changes in shear wave velocity to predict changes in reservoir pressure. The estimation of the spatial extent and amount of CO2 relies on first removing the effects of the water saturation and pressure changes from the observed compressional velocity changes, producing a residual compressional velocity change. The residual compressional velocity change is then interpreted in terms of increases in the CO2 /oil ratio. Resulting images of CO2/oil ratio show CO2 rich zones that are well correlated with the location of injection perforations with the size of these zones also correlating to the amount of injected CO2. The images produced by this process are better correlated to the location and amount of injected CO2 than are any of the individual images of change in geophysical parameters.

Hoversten, G.M.; Gritto, Roland; Washbourne, John; Daley, Tom

2002-08-28T23:59:59.000Z

344

Assessment of Energy Efficiency Improvement and CO2 Emission Reduction Potentials in India's Iron and Steel Industry  

E-Print Network [OSTI]

Improvement and CO2 Emission Reduction Potentials in theUS $/GJ- saved) CO2 Emissions Reduction (Mt CO 2 ) CCF RankUS$/GJ- saved) CO2 Emissions Reduction (Mt CO 2 ) * The

Morrow III, William R.

2014-01-01T23:59:59.000Z

345

Experimental assessment of CO2-mineral-toxic ion interactions in a1 simplified freshwater aquifer: Implications for CO2 leakage from deep2  

E-Print Network [OSTI]

ton CO2/year),2 caused mainly by fossil fuel combustion, have led to concerns about global warming. To,version1-21Jun2013 #12;5 Introduction1 Unregulated CO2 emissions into the Earth's atmosphere (about 22x1093 maintain the atmospheric CO2 level below 500 ppm, CO2 emissions will have to be stabilized4

Paris-Sud XI, Université de

346

Experimental Assessment of CO2Mineral-Toxic Ion Interactions in a Simplified Freshwater Aquifer: Implications for CO2 Leakage from  

E-Print Network [OSTI]

by fossil fuel combustion, have led to concerns about global warming. To maintain the atmospheric CO2 level. INTRODUCTION Unregulated CO2 emissions into the Earth's atmosphere (about 22 Ã? 109 ton CO2/year), caused mainly below 500 ppm, CO2 emissions will have to be stabilized at current levels, although they are forecast

347

CO2 leakage up from a geological storage site to shallow fresh groundwater: CO2-water-rock interaction assessment and  

E-Print Network [OSTI]

CO2 leakage up from a geological storage site to shallow fresh groundwater: CO2-water repository requires the investigation of the potential CO2 leakage back into fresh groundwater, particularly sensitive monitoring techniques in order to detect potential CO2 leaks and their magnitude as well

Paris-Sud XI, Université de

348

Free Air CO2 Enrichment (FACE) Data Management System  

DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

The DOE Biological and Environmental Research Program (BER) is responsible for four "core" FACE sites and projects. These are known as Aspen FACE, Duke FACE, ORNL FACE, and Nevada Deseret FACE. Brookhaven provides operational support to some of these sites, while The FACE Data Management System at ORNL and CDIAC serves as a data repository. In addition, DOE supports OTC experiments in conjunction with the Smithsonian Environmental Research Center (SERC) in Maryland and Florida. There are also FACE experiments ongoing in other countries. [Quoted from the home page of the FACE Data Management System and other pages within the web site.] The FACE Data Management System at ORNL provides links to all the FACE and SERC sites and to the data (both the data archived at CDIAC and data still residing on site-specific pages). Users are also given in-depth information on the concept, provided with a full, linked list of international projects, and guided to related research. The FACE projects were part of the CO2 research network fostered by the Global Change and Terrestrial Ecosystems core project of the International Geosphere-Biosphere Programme. Results from the experiment contribute to the Terrestrial Ecosystem Response to Atmospheric and Climatic Change (TERACC) project, a 5-year initiative integrating experimental data and global change modeling.

349

Generation of a Doubly Bridging CO2 Ligand and Deoxygenation of CO2 by an (NHC)Ni(0) Complex  

E-Print Network [OSTI]

for CO2, µ-2,2-CO2, at a dinickel core. The reaction of [(IPr)Ni(µ-Cl)]2 18 (IPr ) 1,3-bis(2,6-diisopro, (IPr)- Ni(6-C6D6). We note that this symmetric pattern for the backbone protons is observed in reacted isolation of the product as a solid. Reaction of [(IPr)Ni(µ-Cl)]2 with Li(HBEt3) or with NaOt-Bu followed

Müller, Peter

350

Intracranial Pressure Variation Associated with Changes in End-Tidal CO2  

E-Print Network [OSTI]

Intracranial Pressure Variation Associated with Changes in End-Tidal CO2 Sunghan Kim, James Mc that the partial pressure of arterial CO2 (PaCO2) can affect cerebral blood flow, cerebral blood volume, and therefore ICP. The end-tidal CO2 (ETCO2) is usually monitored by clinicians as a proxy for PaCO2. We show

351

Geochemical Impacts of Leaking CO2 from Subsurface Storage Reservoirs to Unconfined and Confined Aquifers  

SciTech Connect (OSTI)

Experimental research work has been conducted and is undergoing at Pacific Northwest National Laboratory (PNNL) to address a variety of scientific issues related with the potential leaks of the carbon dioxide (CO2) gas from deep storage reservoirs. The main objectives of this work are as follows: • Develop a systematic understanding of how CO2 leakage is likely to influence pertinent geochemical processes (e.g., dissolution/precipitation, sorption/desorption and redox reactions) in the aquifer sediments. • Identify prevailing environmental conditions that would dictate one geochemical outcome over another. • Gather useful information to support site selection, risk assessment, policy-making, and public education efforts associated with geological carbon sequestration. In this report, we present results from experiments conducted at PNNL to address research issues related to the main objectives of this effort. A series of batch and column experiments and solid phase characterization studies (quantitative x-ray diffraction and wet chemical extractions with a concentrated acid) were conducted with representative rocks and sediments from an unconfined, oxidizing carbonate aquifer, i.e., Edwards aquifer in Texas, and a confined aquifer, i.e., the High Plains aquifer in Kansas. These materials were exposed to a CO2 gas stream simulating CO2 gas leaking scenarios, and changes in aqueous phase pH and chemical composition were measured in liquid and effluent samples collected at pre-determined experimental times. Additional research to be conducted during the current fiscal year will further validate these results and will address other important remaining issues. Results from these experimental efforts will provide valuable insights for the development of site-specific, generation III reduced order models. In addition, results will initially serve as input parameters during model calibration runs and, ultimately, will be used to test model predictive capability and competency. The results from these investigations will provide useful information to support site selection, risk assessment, and public education efforts associated with geological, deep subsurface CO2 storage and sequestration.

Qafoku, Nikolla; Brown, Christopher F.; Wang, Guohui; Sullivan, E. C.; Lawter, Amanda R.; Harvey, Omar R.; Bowden, Mark

2013-04-15T23:59:59.000Z

352

Integrated Geothermal-CO2 Storage Reservoirs: FY1 Final Report  

SciTech Connect (OSTI)

The purpose of phase 1 is to determine the feasibility of integrating geologic CO2 storage (GCS) with geothermal energy production. Phase 1 includes reservoir analyses to determine injector/producer well schemes that balance the generation of economically useful flow rates at the producers with the need to manage reservoir overpressure to reduce the risks associated with overpressure, such as induced seismicity and CO2 leakage to overlying aquifers. This submittal contains input and output files of the reservoir model analyses. A reservoir-model "index-html" file was sent in a previous submittal to organize the reservoir-model input and output files according to sections of the FY1 Final Report to which they pertain. The recipient should save the file: Reservoir-models-inputs-outputs-index.html in the same directory that the files: Section2.1.*.tar.gz files are saved in.

Buscheck, Thomas A.

2012-01-01T23:59:59.000Z

353

Active Management of Integrated Geothermal-CO2 Storage Reservoirs in Sedimentary Formations  

DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

The purpose of phase 1 is to determine the feasibility of integrating geologic CO2 storage (GCS) with geothermal energy production. Phase 1 includes reservoir analyses to determine injector/producer well schemes that balance the generation of economically useful flow rates at the producers with the need to manage reservoir overpressure to reduce the risks associated with overpressure, such as induced seismicity and CO2 leakage to overlying aquifers. This submittal contains input and output files of the reservoir model analyses. A reservoir-model "index-html" file was sent in a previous submittal to organize the reservoir-model input and output files according to sections of the FY1 Final Report to which they pertain. The recipient should save the file: Reservoir-models-inputs-outputs-index.html in the same directory that the files: Section2.1.*.tar.gz files are saved in.

Buscheck, Thomas A.

354

Integrated Geothermal-CO2 Storage Reservoirs: FY1 Final Report  

DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

The purpose of phase 1 is to determine the feasibility of integrating geologic CO2 storage (GCS) with geothermal energy production. Phase 1 includes reservoir analyses to determine injector/producer well schemes that balance the generation of economically useful flow rates at the producers with the need to manage reservoir overpressure to reduce the risks associated with overpressure, such as induced seismicity and CO2 leakage to overlying aquifers. This submittal contains input and output files of the reservoir model analyses. A reservoir-model "index-html" file was sent in a previous submittal to organize the reservoir-model input and output files according to sections of the FY1 Final Report to which they pertain. The recipient should save the file: Reservoir-models-inputs-outputs-index.html in the same directory that the files: Section2.1.*.tar.gz files are saved in.

Buscheck, Thomas A.

355

Abstract Atmospheric CO2 partial pressure (pCO2) was as low as 18 Pa during the Pleistocene and is projected to  

E-Print Network [OSTI]

Abstract Atmospheric CO2 partial pressure (pCO2) was as low as 18 Pa during the Pleistocene and is projected to increase from 36 to 70 Pa CO2 before the end of the 21st century. High pCO2 often increases the growth and repro- duction of C3 annuals, whereas low pCO2 decreases growth and may reduce or prevent

Antonovics, Janis

356

International Collaboration on CO2 Sequestration  

SciTech Connect (OSTI)

On December 4, 1997, the US Department of Energy (USDOE), the New Energy and Industrial Technology Development Organization of Japan (NEDO), and the Norwegian Research Council (NRC) entered into a Project Agreement for International Collaboration on CO{sub 2} Ocean Sequestration. Government organizations from Japan, Canada, and Australia, and a Swiss/Swedish engineering firm later joined the agreement, which outlined a research strategy for ocean carbon sequestration via direct injection. The members agreed to an initial field experiment, with the hope that if the initial experiment was successful, there would be subsequent field evaluations of increasingly larger scale to evaluate environmental impacts of sequestration and the potential for commercialization. The evolution of the collaborative effort, the supporting research, and results for the International Collaboration on CO{sub 2} Ocean Sequestration were documented in almost 100 papers and reports, including 18 peer-reviewed journal articles, 46 papers, 28 reports, and 4 graduate theses. These efforts were summarized in our project report issued January 2005 and covering the period August 23, 1998-October 23, 2004. An accompanying CD contained electronic copies of all the papers and reports. This report focuses on results of a two-year sub-task to update an environmental assessment of acute marine impacts resulting from direct ocean sequestration. The approach is based on the work of Auerbach et al. [6] and Caulfield et al. [20] to assess mortality to zooplankton, but uses updated information concerning bioassays, an updated modeling approach and three modified injection scenarios: a point release of negatively buoyant solid CO{sub 2} hydrate particles from a moving ship; a long, bottom-mounted diffuser discharging buoyant liquid CO{sub 2} droplets; and a stationary point release of hydrate particles forming a sinking plume. Results suggest that in particular the first two discharge modes could be successfully designed to largely avoid zooplankton mortality. Sub-lethal and ecosystem effects are discussed qualitatively, but not analyzed quantitatively.

Peter H. Israelsson; E. Eric Adams

2007-06-30T23:59:59.000Z

357

Recovery Act: Innovative CO2 Sequestration from Flue Gas Using Industrial Sources and Innovative Concept for Beneficial CO2 Use  

SciTech Connect (OSTI)

field testing of a biomimetic in-duct scrubbing system for the capture of gaseous CO2 coupled with sequestration of captured carbon by carbonation of alkaline industrial wastes. The Phase 2 project, reported on here, combined efforts in enzyme development, scrubber optimization, and sequestrant evaluations to perform an economic feasibility study of technology deployment. The optimization of carbonic anhydrase (CA) enzyme reactivity and stability are critical steps in deployment of this technology. A variety of CA enzyme variants were evaluated for reactivity and stability in both bench scale and in laboratory pilot scale testing to determine current limits in enzyme performance. Optimization of scrubber design allowed for improved process economics while maintaining desired capture efficiencies. A range of configurations, materials, and operating conditions were examined at the Alcoa Technical Center on a pilot scale scrubber. This work indicated that a cross current flow utilizing a specialized gas-liquid contactor offered the lowest system operating energy. Various industrial waste materials were evaluated as sources of alkalinity for the scrubber feed solution and as sources of calcium for precipitation of carbonate. Solids were mixed with a simulated sodium bicarbonate scrubber blowdown to comparatively examine reactivity. Supernatant solutions and post-test solids were analyzed to quantify and model the sequestration reactions. The best performing solids were found to sequester between 2.3 and 2.9 moles of CO2 per kg of dry solid in 1-4 hours of reaction time. These best performing solids were cement kiln dust, circulating dry scrubber ash, and spray dryer absorber ash. A techno-economic analysis was performed to evaluate the commercial viability of the proposed carbon capture and sequestration process in full-scale at an aluminum smelter and a refinery location. For both cases the in-duct scrubber technology was compared to traditional amine- based capture. Incorporation of the laboratory results showed that for the application at the aluminum smelter, the in-duct scrubber system is more economical than traditional methods. However, the reverse is true for the refinery case, where the bauxite residue is not effective enough as a sequestrant, combined with challenges related to contaminants in the bauxite residue accumulating in and fouling the scrubber absorbent. Sensitivity analyses showed that the critical variables by which process economics could be improved are enzyme concentration, efficiency, and half-life. At the end of the first part of the Phase 2 project, a gate review (DOE Decision Zero Gate Point) was conducted to decide on the next stages of the project. The original plan was to follow the pre-testing phase with a detailed design for the field testing. Unfavorable process economics, however, resulted in a decision to conclude the project before moving to field testing. It is noted that CO2 Solutions proposed an initial solution to reduce process costs through more advanced enzyme management, however, DOE program requirements restricting any technology development extending beyond 2014 as commercial deployment timeline did not allow this solution to be undertaken.

Dando, Neal; Gershenzon, Mike; Ghosh, Rajat

2012-07-31T23:59:59.000Z

358

Figure 9. Conceptual model for regionally divergent responses of the air-land fluxes to CO2 fertilization, which increases the water-use efficiency of photosynthesis. In dry regions where  

E-Print Network [OSTI]

parameterizations of these processes in models of Mediterranean- climate lands and obtaining a baseline for assessing changes. Acknowledgments NYK is supported by a NOAA Climate and Global Change postdoctoral.1 (2006). I. Y. Fung, S. C. Doney, K. Lindsay, J. John, Evolution of carbon sinks in a changing climate

Krakauer, Nir Y.

359

Enhanced Practical Photosynthetic CO2 Mitigation  

SciTech Connect (OSTI)

This quarterly report documents significant achievements in the Enhanced Practical Photosynthetic CO{sub 2} Mitigation project during the period from 4/2/2003 through 7/01/2003. As indicated in the list of accomplishments below we have completed some long-term model scale bioreactor tests and are prepared to begin pilot scale bioreactor testing. Specific results and accomplishments for the second quarter of 2003 include: (1) Bioreactor support systems and test facilities: (a) Qualitative long-term survivability tests for S.C.1.2(2) on Omnisil have been successfully completed and results demonstrate a growth rate that appears to be acceptable. (b) Quantitative tests of long-term growth productivity for S.C.1.2(2) on Omnisil have been completed and initial results are promising. Initial results show that the mass of organisms doubled (from 54.9 grams to 109.8 grams) in about 5 weeks. Full results will be available as soon as all membranes and filters are completely dried. The growth rate should increase significantly with the initiation of weekly harvesting during the long term tests. (c) The phase 1 construction of the pilot scale bioreactor has been completed, including the solar collector and light distribution system. We are now in the phase of system improvement as we wait for CRF-2 results in order to be able to finalize the design and construction of the pilot scale system. (d) A mass transfer experimental setup was constructed in order to measure the mass transfer rate from the gas to the liquid film flowing over a membrane and to study the hydrodynamics of the liquid film flowing over a membrane in the bioreactor. Results were reported for mass transfer coefficient, film thickness, and fluid velocity over an Omnisil membrane with a ''drilled hole'' header pipe design. (2) Organisms and Growth Surfaces: (a) A selectivity approach was used to obtain a cyanobacterial culture with elevated resistance to acid pH. Microlonies of ''3.2.2 S.C.1 Positive'' migrated towards light along a light gradient, and against acid gradient, in whole. Nonetheless, some microcolonies were able to generate ''secondary'' microcolonies with increased ability to move towards acid area. These microcolonies with elevated resistance to acidity have been isolated and inoculated in BG-11 with pH 6. They are still under incubation. (b) We have continued our work on the genotyping of unialgal cyanobacterial cultures isolated in YNP. Because partial sequence of 16S rRNA gene of the isolate 5.2 S.C.1 did not appear to be more than 93% identical to published cyanobacterial sequences, we carried out entire sequence of this gene using the combination of different primers. It appears that we have found a representative of putative new genus. We expect to publish all sequences. (c) The new species (even probably new genus) of cyanobacteria, 5.2 s. c. 1 that was isolated from La Duke Spring in Great Yellowstone Basin demonstrate an elevated resistance to some compounds of iron. This might be very important for our project, because plant gases may have elevated amount of iron. Our study of the effect of different concentration of FeCl3 6H2O on the growth of 5.2 S.C.1 isolate showed that iron additions stimulated rather then inhibited the growth of 5.2. S.C.1 isolate. Because of this we would recommend this isolate for further experiments.

Gregory Kremer; David J. Bayless; Morgan Vis; Michael Prudich; Keith Cooksey; Jeff Muhs

2003-07-22T23:59:59.000Z

360

CO2-selective, Hybrid Membranes by Silation of Alumina  

SciTech Connect (OSTI)

Hybrid membranes are feasible candidates for the separation of CO2 from gas produced in coal-based power generation since they have the potential to combine the high selectivity of polymer membranes and the high permeability of inorganic membranes. An interesting method for producing hybrid membranes is the silation of an inorganic membrane. In this method, trichloro- or alkoxy-silanes interact with hydroxyl groups on the surface of ?-AlO3 or TiO2, binding organic groups to that surface. By varying the length of these organic groups on the organosilane, it should be possible to tailor the effective pore size of the membrane. Similarly, the addition of “CO2-phillic” groups to the silating agent allows for the careful control of surface affinity and the enhancement of surface diffusion mechanisms. This method of producing hybrid membranes selective to CO2 was first attempted by Hyun [1] who silated TiO2 with phenyltriethoxysilane. Later, Way [2] silated ?-AlO3 with octadecyltrichlorosilane. Both researchers were successful in producing membranes with improved selectivity toward CO2, but permeability was not maintained at a commercially applicable level. XPS data indicated that the silating agent did not penetrate into the membrane pores and separation actually occurred in a thin “polymer-like” surface layer. The present study attempts to overcome the mass transfer problems associated with this technique by producing the desired monolayer coverage of silane, and thus develop a highly-permeable CO2-selective hybrid membrane.

Luebke, D.R.; Pennline, H.W.

2007-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "ks modeling co2" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

CO2 Sequestration in Unmineable Coal Seams: Potential Environmental Impacts  

SciTech Connect (OSTI)

An initial investigation into the potential environmental impacts of CO2 sequestration in unmineable coal seams has been conducted, focusing on changes in the produced water during enhanced coalbed methane (ECBM) production using a CO2 injection process (CO2-ECBM). Two coals have been used in this study, the medium volatile bituminous Upper Freeport coal (APCS 1) of the Argonne Premium Coal Samples series, and an as-mined Pittsburgh #8 coal, which is a high volatile bituminous coal. Coal samples were reacted with either synthetic produced water or field collected produced water and gaseous carbon dioxide at 40 ?C and 50 bar to evaluate the potential for mobilizing toxic metals during CO2-ECBM/sequestration. Microscopic and x-ray diffraction analysis of the post-reaction coal samples clearly show evidence of chemical reaction, and chemical analysis of the produced water shows substantial changes in composition. These results suggest that changes to the produced water chemistry and the potential for mobilizing toxic trace elements from coalbeds are important factors to be considered when evaluating deep, unmineable coal seams for CO2 sequestration.

Hedges, S.W.; Soong, Yee; McCarthy Jones, J.R.; Harrison, D.K.; Irdi, G.A.; Frommell, E.A.; Dilmore, R.M.; Pique, P.J.; Brown, T.D

2005-09-01T23:59:59.000Z

362

Surface Ocean CO2 Atlas (SOCAT) gridded data products  

SciTech Connect (OSTI)

A well documented, publicly available, global data set for surface ocean carbon dioxide (CO2) parameters has been called for by international groups for nearly two decades. The Surface Ocean CO2 Atlas (SOCAT) project was initiated by the international marine carbon science community in 2007 with the aim of providing a comprehensive, publicly available, regularly updated, global data set of marine surface CO2, which had been subject to quality control (QC). SOCAT version 1.5 was made public in September 2011 and holds 6.3 million quality controlled surface CO2 data from the global oceans and coastal seas, spanning four decades (1968 2007). The SOCAT gridded data is the second data product to come from the SOCAT project. Recognizing that some groups may have trouble working with millions of measurements, the SOCAT gridded product was generated to provide a robust regularly spaced fCO2 product with minimal spatial and temporal interpolation which should be easier to work with for many applications. Gridded SOCAT is rich with information that has not been fully explored yet, but also contains biases and limitations that the user needs to recognize and address.

Sabine, Christopher [NOAA Pacific Marine Environmental Laboratory; Hankin, S. [Pacific Northwest National Laboratory (PNNL); Koyuk, H [Joint Institute for the Study of the Atmosphere and Ocean, University of Washington; Bakker, D C E [School of Environmental Sciences, University of East Anglia, Norwich, UK; Pfeil, B [Geophysical Institute, University of Bergen; Uni Research AS, Bergen, Norway; Olsen, A [Bjerknes Centre for Climate Research, UNIFOB AS, Bergen, Norway; Metzl, N [Universite Pierre et Marie Curie, LOCEAN/IPSL, Paris, France; Kozyr, Alexander [ORNL; Fassbender, A [School of Oceanography, University of Washington, Seattle, WA; Manke, A [Pacific Marine Environmental Laboratory, National Oceanic and Atmospheric Administration; Malczyk, J [Jetz Laboratory, Department of Ecology and Evolutionary Biology, Yale University; Akl, J [CSIRO Wealth from Oceans Flagship, Hobart, Tasmania, Australia; Alin, S R [Pacific Marine Environmental Laboratory, National Oceanic and Atmospheric Administration; Bellerby, R G J [Geophysical Institute, University of Bergen, Bergen, Norway; Borges, A [University of Liege, Chemical Oceanography Unit, Institut de Physique, Liege, Belgium; Boutin, J [Universite Pierre et Marie Curie, LOCEAN/IPSL, Paris, France; Brown, P J [School of Environmental Sciences, University of East Anglia, Norwich, UK; Cai, W-J [Department of Marine Sciences, University of Georgia; Chavez, F P [Monterey Bay Aquarium Research Institute, Moss Landing, CA; Chen, A [Institute of Marine Geology and Chemistry, National Sun Yat-sen University, Kaohsiung, Taiwan; Cosa, C [Pacific Marine Environmental Laboratory, National Oceanic and Atmospheric Administration; Feely, R A [Pacific Marine Environmental Laboratory, National Oceanic and Atmospheric Administration; Gonzalez-Davila, M [Universidad de Las Palmas de Gran Canaria, Facultad de Ciencias del Mar, Las Palmas de Gran Canaria,; Goyet, C [Institut de Modélisation et d'Analyse en Géo-Environnement et Santé, Université de Perpignan; Hardman-Mountford, N [CSIRO, Marine and Atmospheric Research, Wembley, Western Australia, Australia; Heinze, C [Geophysical Institute, University of Bergen, Bergen, Norway; Hoppema, M [Alfred Wegener Institute for Polar and Marine Research, Bremerhaven, Germany; Hunt, C W [Ocean Process Analysis Lab, University of New Hampshire, Durham, New Hampshire; Hydes, D [National Oceanography Centre, Southampton, UK; Ishii, M [Japan Meteorological Agency, Meteorological Research Institute, Tsukuba, Japan; Johannessen, T [Geophysical Institute, University of Bergen, Bergen, Norway; Key, R M [Atmospheric and Oceanic Sciences, Princeton University, Princeton, New Jersey; Kortzinger, A [GEOMAR, Helmholtz Centre for Ocean Research, Kiel, Germany; Landschutzer, P [School of Environmental Sciences, University of East Anglia, Norwich, UK; Lauvset, S K [Geophysical Institute, University of Bergen, Bergen, Norway; Lefevre, N [Université Pierre et Marie Curie, LOCEAN/IPSL, Paris, France; Lenton, A [Centre for Australian Weather and Climate Research, Hobart, Tasmania, Australia; Lourantou, A [Université Pierre et Marie Curie, LOCEAN/IPSL, Paris, France; Merlivat, L [Université Pierre et Marie Curie, LOCEAN/IPSL, Paris, France; Midorikawa, T [Nagasaki Marine Observatory, Nagasaki, Japan; Mintrop, L [MARIANDA, Kiel, Germany; Miyazaki, C [Faculty of Environmental Earth Science, Hokkaido University, Hokkaido, Japan; Murata, A [Japan Agency for Marine-Earth Science and Technology, Yokosuka, Japan; Nakadate, A [Marine Division, Global Environment and Marine Department, Japan Meteorological Agency, Tokyo, Japan; Nakano, Y [Japan Agency for Marine-Earth Science and Technology, Yokosuka, Japan; Nakaoka, S [National Institute for Environmental Studies (NIES), Tsukuba, Japan; Nojiri, Y [National Institute for Environmental Studies, Tsukuba, Japan; et al.

2013-01-01T23:59:59.000Z

363

Weeks Island gravity stable CO2 pilot: Final report  

SciTech Connect (OSTI)

The Weeks Island ''S'' sand Reservoir B (''S'' RB) gravity-stable CO2 field test was completed during February 1988. Injection started in October 1978 and production began in January 1981 in this high-permeability, steeply-dipping sandstone reservoir. About 264,000 barrels of oil or 65 percent of the starting volume has been recovered. A 24-percent pore-volume slug of CO2 mixed with about six mole percent of natural gas (mostly methane) was injected at the start of the pilot. Since 1983, produced CO2 plus hydrocarbon gases have been recycled. CO2 usage statistics are 9.34 MCF/BO with recycle and 3.24 MCF/BO based on purchased CO2. Previous annual reports document the pilot design, implementation, and early results for the 1977 to June 1981 time period. This report is a review of early pilot history and a more detailed account of the post June 1981 results and overall interpretation. A reservoir-simulation history match of pilot performance plus core and log data from a 1983 swept-zone evaluation well are described in this report. A brief description of the production facility and an account of the corrosion control program are also included. 11 refs., 34 figs.

Johnston, J.R.; Perry, G.E.

1989-01-01T23:59:59.000Z

364

Stabilization of CO2 Atmospheres on Exoplanets around M Dwarf Stars  

E-Print Network [OSTI]

We investigate the chemical stability of CO2-dominated atmospheres of M dwarf terrestrial exoplanets using a 1-dimensional photochemical model. On planets orbiting Sun-like stars, the photolysis of CO2 by Far-UV (FUV) radiation is balanced by the reaction between CO and OH, the rate of which depends on H2O abundance. By comparison, planets orbiting M dwarf stars experience higher FUV radiation compared to planets orbiting Sun-like stars, and they are also likely to have low H2O abundance due to M dwarfs having a prolonged, high-luminosity pre-main sequence (Luger & Barnes 2015). We show that, for H2O-depleted planets around M dwarfs, a CO2-dominated atmosphere is stable to conversion to CO and O2 by relying on a catalytic cycle involving H2O2 photolysis. However, this cycle breaks down for planets with atmospheric hydrogen mixing ratios below ~1 ppm, resulting in ~40% of the atmospheric CO2 being converted to CO and O2 on a time scale of 1 Myr. The increased abundance of O2 also results in high O3 concent...

Gao, Peter; Robinson, Tyler D; Li, Cheng; Yung, Yuk L

2015-01-01T23:59:59.000Z

365

Is the northern high latitude land-based CO2 sink weakening?  

SciTech Connect (OSTI)

Studies indicate that, historically, terrestrial ecosystems of the northern high latitude region may have been responsible for up to 60% of the global net land-based sink for atmospheric CO2. However, these regions have recently experienced remarkable modification of the major driving forces of the carbon cycle, including surface air temperature warming that is significantly greater than the global average and associated increases in the frequency and severity of disturbances. Whether arctic tundra and boreal forest ecosystems will continue to sequester atmospheric CO2 in the face of these dramatic changes is unknown. Here we show the results of model simulations that estimate a 41 Tg C yr-1 sink in the boreal land regions from 1997 to 2006, which represents a 73% reduction in the strength of the sink estimated for previous decades in the late 20th Century. Our results suggest that CO2 uptake by the region in previous decades may not be as strong as previously estimated. The recent decline in sink strength is the combined result of 1) weakening sinks due to warming-induced increases in soil organic matter decomposition and 2) strengthening sources from pyrogenic CO2 emissions as a result of the substantial area of boreal forest burned in wildfires across the region in recent years. Such changes create positive feedbacks to the climate system that accelerate global warming, putting further pressure on emission reductions to achieve atmospheric stabilization targets.

Mcguire, David [University of Alaska; Kicklighter, David W. [Ecosystem Center, The; Gurney, Kevin R [Arizona State University; Burnside, Todd [University of Alaska, Fairbanks; Melillo, Jerry [Marine Biological Laboratory

2011-01-01T23:59:59.000Z

366

E-Print Network 3.0 - af co2 fra Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

co2 fra Search Powered by Explorit Topic List Advanced Search Sample search results for: af co2 fra Page: << < 1 2 3 4 5 > >> 1 En femtedel af verdens CO2-udslip stammer fra...

367

EIS-0429: Proposed IG CO2 Pipeline Route | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Proposed IG CO2 Pipeline Route EIS-0429: Proposed IG CO2 Pipeline Route Map of Proposed CO2 Pipeline Route More Documents & Publications EIS-0429: Amended Notice of Intent To...

368

E-Print Network 3.0 - abiotic co2 flows Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

co2 flows Search Powered by Explorit Topic List Advanced Search Sample search results for: abiotic co2 flows Page: << < 1 2 3 4 5 > >> 1 Preindustrial Air-Sea CO2 Flux: Sensitivity...

369

Enhancement of CO2/N2 selectivity in a metal-organic framework by cavity modification  

E-Print Network [OSTI]

electricity is a major source of CO2 in the atmosphere, but the capture and sequestration of CO2 from flue gas two-thirds), CO2, water vapor, oxygen, and minor components such as carbon monoxide, nitrogen oxides

370

Regulation, Allocation, and Leakage in Cap-and-Trade Markets for CO2  

E-Print Network [OSTI]

and Philippe Quirion. Co2 abatement, competitiveness andDaniel Kahn. Allocation of co2 emissions al- lowances in theA short-run case analysis of co2 leakage and nox and so2

Bushnell, Jim B; Chen, Yihsu

2009-01-01T23:59:59.000Z

371

On CO2 Behavior in the Subsurface, Following Leakage from a Geologic Storage Reservoir  

E-Print Network [OSTI]

1 - 16, 1987. Skinner, L. CO2 Blowouts: An Emerging Problem,Assessment for Underground CO2 Storage, paper 234, presentedReservoir Performance Risk in CO2 Storage Projects, paper

Pruess, Karsten

2006-01-01T23:59:59.000Z

372

Leakage of CO2 from geologic storage: Role of secondary accumulation at shallow depth  

E-Print Network [OSTI]

Large Releases from CO2 Storage Reservoirs: Analogs,S.T. Nelson. Natural Leaking CO2-charged Systems as AnalogsY. Sano, and H.U. Schmincke. CO2-rich Gases from Lakes Nyos

Pruess, K.

2008-01-01T23:59:59.000Z

373

Inventory of China's Energy-Related CO2 Emissions in 2008  

E-Print Network [OSTI]

China’s 2008 Thermal Electricity Sector CO 2 Emissions byheat. Share of thermal electricity sector’s CO 2 emissionsheat. Share of thermal electricity sector’s CO 2 emissions

Fridley, David

2011-01-01T23:59:59.000Z

374

Inventory of China's Energy-Related CO2 Emissions in 2008  

E-Print Network [OSTI]

China's 2008 Total CO 2 Emissions from Energy Consumption:10. China's 2008 Total CO 2 Emissions from Energy: Sectoral16 Table 11. China's 2008 CO 2 Emissions from Energy:

Fridley, David

2011-01-01T23:59:59.000Z

375

DOI: 10.1002/cssc.201000032 The Immobility of CO2 in Marine Sediments Beneath 1500  

E-Print Network [OSTI]

to capture CO2 produced at indus- trial facilities and approaches to inject the CO2 into geologic of buoyant CO2 in terrestrial reservoirs that often contain fractures, faults, and abandoned wells and may

Schrag, Daniel

376

Automobile Fuel; Economy and CO2 Emissions in Industrialized Countries: Troubling Trends through 2005/6  

E-Print Network [OSTI]

Energy Savings and CO2 Emissions Implications. J. ofcommitment to reduce CO2 emissions from new passenger carsACEA’s Commitment on CO2 Emission Reductions from Passenger

Schipper, Lee

2008-01-01T23:59:59.000Z

377

Regulation, Allocation, and Leakage in Cap-and-Trade Markets for CO2  

E-Print Network [OSTI]

Daniel Kahn. Allocation of co2 emissions al- lowances in theRasmussen. Allocation of co2 emissions permits: A generalthe aggregate annual CO2 emissions for each of the key

Bushnell, Jim B; Chen, Yihsu

2009-01-01T23:59:59.000Z

378

Potential Energy Savings and CO2 Emissions Reduction of China's Cement Industry  

E-Print Network [OSTI]

2050 China Energy and CO2 Emissions Report. Science Press,Energy Savings and CO2 Emissions Reduction of China’s CementEnergy Savings and CO2 Emissions Reduction of China’s Cement

Ke, Jing

2013-01-01T23:59:59.000Z

379

Inventory of China's Energy-Related CO2 Emissions in 2008  

E-Print Network [OSTI]

of unadjusted energy-related CO2 emissions is attributed toEMISSIONS- T C EMISSIONS -T CO2 TOTAL Energy EmissionsEMISSIONS- T C EMISSIONS -T CO2 Coal Coke and Other

Fridley, David

2011-01-01T23:59:59.000Z

380

What Can China Do? China's Best Alternative Outcome for Energy Efficiency and CO2 Emissions  

E-Print Network [OSTI]

China Energy and CO2 Emissions Report (CEACER). Beijing:Oil consumption and CO2 emissions in China’s road transport:Growth, Oil Demand and CO2 Emissions through 2050. Report

G. Fridley, David

2010-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "ks modeling co2" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Challenges and opportunities in accounting for non-energy use CO2 emissions: an editorial comment  

E-Print Network [OSTI]

carbon dioxide (NEU-CO2) emissions, represent a signi?cantSimply described, NEU-CO2 emissions are generated via twoData permitting, NEU-CO2 emissions arising from energy

Masanet, Eric; Sathaye, Jayant

2009-01-01T23:59:59.000Z

382

Potential Energy Savings and CO2 Emissions Reduction of China's Cement Industry  

E-Print Network [OSTI]

Energy Savings and CO2 Emissions Reduction of China’s CementEnergy Savings and CO2 Emissions Reduction of China’s Cementenergy savings and CO2 emission reduction potentials are

Ke, Jing

2013-01-01T23:59:59.000Z

383

Regulation for Underground Storage of CO2 Passed by U.S. States  

E-Print Network [OSTI]

generation. Its use, therefore, is necessary in order to achieve the CO2 emission reduction targetRegulation for Underground Storage of CO2 Passed by U.S. States Holly Javedan Massachusetts................................................................................................... 8 2.4 CO2 Ownership

384

Thermal desorption of CH4 retained in CO2 ice  

E-Print Network [OSTI]

CO2 ices are known to exist in different astrophysical environments. In spite of this, its physical properties (structure, density, refractive index) have not been as widely studied as those of water ice. It would be of great value to study the adsorption properties of this ice in conditions related to astrophysical environments. In this paper, we explore the possibility that CO2 traps relevant molecules in astrophysical environments at temperatures higher than expected from their characteristic sublimation point. To fulfil this aim we have carried out desorption experiments under High Vacuum conditions based on a Quartz Crystal Microbalance and additionally monitored with a Quadrupole Mass Spectrometer. From our results, the presence of CH4 in the solid phase above the sublimation temperature in some astrophysical scenarios could be explained by the presence of several retaining mechanisms related to the structure of CO2 ice.

R. Luna; C. Millan; M. Domingo; M. A. Satorre

2008-01-21T23:59:59.000Z

385

The Potential for Increased Atmospheric CO2 Emissions and Accelerated Consumption of Deep Geologic CO2 Storage Resources Resulting from the Large-Scale Deployment of a CCS-Enabled Unconventional Fossil Fuels Industry in the U.S.  

SciTech Connect (OSTI)

Desires to enhance the energy security of the United States have spurred significant interest in the development of abundant domestic heavy hydrocarbon resources including oil shale and coal to produce unconventional liquid fuels to supplement conventional oil supplies. However, the production processes for these unconventional fossil fuels create large quantities of carbon dioxide (CO2) and this remains one of the key arguments against such development. Carbon dioxide capture and storage (CCS) technologies could reduce these emissions and preliminary analysis of regional CO2 storage capacity in locations where such facilities might be sited within the U.S. indicates that there appears to be sufficient storage capacity, primarily in deep saline formations, to accommodate the CO2 from these industries. Nevertheless, even assuming wide-scale availability of cost-effective CO2 capture and geologic storage resources, the emergence of a domestic U.S. oil shale or coal-to-liquids (CTL) industry would be responsible for significant increases in CO2 emissions to the atmosphere. The authors present modeling results of two future hypothetical climate policy scenarios that indicate that the oil shale production facilities required to produce 3MMB/d from the Eocene Green River Formation of the western U.S. using an in situ retorting process would result in net emissions to the atmosphere of between 3000-7000 MtCO2, in addition to storing potentially 900-5000 MtCO2 in regional deep geologic formations via CCS in the period up to 2050. A similarly sized, but geographically more dispersed domestic CTL industry could result in 4000-5000 MtCO2 emitted to the atmosphere in addition to potentially 21,000-22,000 MtCO2 stored in regional deep geologic formations over the same period. While this analysis shows that there is likely adequate CO2 storage capacity in the regions where these technologies are likely to deploy, the reliance by these industries on large-scale CCS could result in an accelerated rate of utilization of the nation’s CO2 storage resource, leaving less high-quality storage capacity for other carbon-producing industries including electric power generation.

Dooley, James J.; Dahowski, Robert T.; Davidson, Casie L.

2009-11-02T23:59:59.000Z

386

CO2 Injection Begins in Illinois | Department of Energy  

Energy Savers [EERE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion |Energyon ArmedWaste andAccessCO2 Injection Begins in Illinois CO2 Injection Begins in

387

E-Print Network 3.0 - availability co2-quadrupling experiment...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

co2-quadrupling experiment Search Powered by Explorit Topic List Advanced Search Sample search results for: availability co2-quadrupling experiment Page: << < 1 2 3 4 5 > >> 1...

388

Diesel Passenger Car Technology for Low Emissions and CO2 Compliance...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Passenger Car Technology for Low Emissions and CO2 Compliance Diesel Passenger Car Technology for Low Emissions and CO2 Compliance Cost effective reduction of legislated emissions...

389

Potential Energy Savings and CO2 Emissions Reduction of China's Cement Industry  

E-Print Network [OSTI]

dioxide (CO2) emissions from fossil fuel combustion, as wellCO2 emissions (including cement process and fossil fuel combustion

Ke, Jing

2013-01-01T23:59:59.000Z

390

A Feasibility Study of Non-Seismic Geophysical Methods for Monitoring Geologic CO2 Sequestration  

E-Print Network [OSTI]

CO 2 enhanced oil recovery (EOR) and sequestration in athe measurement configuration. EOR/sequestration projects inshow that a CO 2 –based EOR could increase oil recovery by

Gasperikova, Erika; Hoversten, G. Michael

2006-01-01T23:59:59.000Z

391

The Rosetta Resources CO2 Storage Project - A WESTCARB Geologic Pilot Test  

E-Print Network [OSTI]

of enhanced oil recovery (EOR) using injected CO 2 to driveof enhanced oil recovery (EOR) using injected CO 2 to swell

2006-01-01T23:59:59.000Z

392

The Influence of a CO2 Pricing Scheme on Distributed Energy Resources in California's Commercial Buildings  

E-Print Network [OSTI]

The Influence of a CO2 Pricing Scheme on Distributed Energy5. Regional Results for the CO2 Pricing Scheme no-invest

Stadler, Michael

2010-01-01T23:59:59.000Z

393

Use of experience curves to estimate the future cost of power plants with CO2 capture  

E-Print Network [OSTI]

2004. Experience curves for power plant emission controlassessments of fossil fuel power plants with CO 2 capturethe future cost of power plants with CO 2 capture Edward S.

Rubin, Edward S.; Yeh, Sonia; Antes, Matt; Berkenpas, Michael; Davison, John

2007-01-01T23:59:59.000Z

394

Leakage of CO2 from geologic storage: Role of secondary accumulation at shallow depth  

E-Print Network [OSTI]

adiabatic (= no external heat supply) expansion of CO 2 toCO 2 without external heat supply will cause temperatures toenables more sustained heat supply from the surroundings,

Pruess, K.

2008-01-01T23:59:59.000Z

395

A parametric study on reservoir cooling for enhanced oil recovery from CO2 injection.  

E-Print Network [OSTI]

??Whorton et al. (1952) received a patent for their development of an oil recovery method by CO2 injection. Since then, CO2 flooding for secondary and… (more)

Wang, Zhenzhen

2013-01-01T23:59:59.000Z

396

Automobile Fuel; Economy and CO2 Emissions in Industrialized Countries: Troubling Trends through 2005/6  

E-Print Network [OSTI]

s Commitment on CO2 Emission Reductions from Passenger Cars.is a small extra reduction in CO2 emissions per km due to a

Schipper, Lee

2008-01-01T23:59:59.000Z

397

Exploring the effects of data quality, data worth, and redundancy of CO2 gas pressure and saturation data on reservoir characterization through PEST Inversion  

SciTech Connect (OSTI)

This study examined the impacts of reservoir properties on CO2 migration after subsurface injection and evaluated the possibility of characterizing reservoir properties using CO2 monitoring data such as saturation distribution. The injection reservoir was assumed to be located 1400-1500 m below the ground surface such that CO2 remained in the supercritical state. The reservoir was assumed to contain layers with alternating conductive and resistive properties, which is analogous to actual geological formations such as the Mount Simon Sandstone unit. The CO2 injection simulation used a cylindrical grid setting in which the injection well was situated at the center of the domain, which extended up to 8000 m from the injection well. The CO2 migration was simulated using the PNNL-developed simulator STOMP-CO2e (the water-salt-CO2 module). We adopted a nonlinear parameter estimation and optimization modeling software package, PEST, for automated reservoir parameter estimation. We explored the effects of data quality, data worth, and data redundancy on the detectability of reservoir parameters using CO2 saturation monitoring data, by comparing PEST inversion results using data with different levels of noises, various numbers of monitoring wells and locations, and different data collection spacing and temporal sampling intervals. This study yielded insight into the use of CO2 saturation monitoring data for reservoir characterization and how to design the monitoring system to optimize data worth and reduce data redundancy.

Fang, Zhufeng; Hou, Zhangshuan; Lin, Guang; Engel, David W.; Fang, Yilin; Eslinger, Paul W.

2014-04-01T23:59:59.000Z

398

International Symposium on Site Characterization for CO2Geological Storage  

SciTech Connect (OSTI)

Several technological options have been proposed to stabilize atmospheric concentrations of CO{sub 2}. One proposed remedy is to separate and capture CO{sub 2} from fossil-fuel power plants and other stationary industrial sources and to inject the CO{sub 2} into deep subsurface formations for long-term storage and sequestration. Characterization of geologic formations for sequestration of large quantities of CO{sub 2} needs to be carefully considered to ensure that sites are suitable for long-term storage and that there will be no adverse impacts to human health or the environment. The Intergovernmental Panel on Climate Change (IPCC) Special Report on Carbon Dioxide Capture and Storage (Final Draft, October 2005) states that ''Site characterization, selection and performance prediction are crucial for successful geological storage. Before selecting a site, the geological setting must be characterized to determine if the overlying cap rock will provide an effective seal, if there is a sufficiently voluminous and permeable storage formation, and whether any abandoned or active wells will compromise the integrity of the seal. Moreover, the availability of good site characterization data is critical for the reliability of models''. This International Symposium on Site Characterization for CO{sub 2} Geological Storage (CO2SC) addresses the particular issue of site characterization and site selection related to the geologic storage of carbon dioxide. Presentations and discussions cover the various aspects associated with characterization and selection of potential CO{sub 2} storage sites, with emphasis on advances in process understanding, development of measurement methods, identification of key site features and parameters, site characterization strategies, and case studies.

Tsang, Chin-Fu

2006-02-23T23:59:59.000Z

399

Active Management of Integrated Geothermal-CO2 Storage Reservoirs in Sedimentary Formations  

SciTech Connect (OSTI)

Active Management of Integrated Geothermal–CO2 Storage Reservoirs in Sedimentary Formations: An Approach to Improve Energy Recovery and Mitigate Risk : FY1 Final Report The purpose of phase 1 is to determine the feasibility of integrating geologic CO2 storage (GCS) with geothermal energy production. Phase 1 includes reservoir analyses to determine injector/producer well schemes that balance the generation of economically useful flow rates at the producers with the need to manage reservoir overpressure to reduce the risks associated with overpressure, such as induced seismicity and CO2 leakage to overlying aquifers. This submittal contains input and output files of the reservoir model analyses. A reservoir-model "index-html" file was sent in a previous submittal to organize the reservoir-model input and output files according to sections of the FY1 Final Report to which they pertain. The recipient should save the file: Reservoir-models-inputs-outputs-index.html in the same directory that the files: Section2.1.*.tar.gz files are saved in.

Buscheck, Thomas A.

2012-01-01T23:59:59.000Z

400

Wirebonding SVX prime silicon ladders using the K&S 1478 wirebonder  

SciTech Connect (OSTI)

This report discusses the follow on the K&S 1478 Wirebonder: Power Up; Tool Calibration; Manual Mode; Teach Mode; and Reference Systems.

Dyer, A.

1993-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "ks modeling co2" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

SecuestrodeCO2enestructurasgeolgicas Modelacin numrica de  

E-Print Network [OSTI]

Kioto Responsables del 55% de las emisiones se comprometen reducir en 5% el total de emisiones respecto forma diferente A España le corresponde no aumentar en mas de 15% sus emisiones respecto a 1990 En 2006enestructurasgeológicas Una forma de disminuir emisiones: Almacenamiento de CO2 en estructuras geológicas Yacimientos de

Politècnica de Catalunya, Universitat

402

Center for By-Products Utilization CO2 SEQUESTRATION  

E-Print Network [OSTI]

Center for By-Products Utilization CO2 SEQUESTRATION IN NON-AIR ENTRAINED CONCRETE By Tarun R. Naik. Maximize environmental benefits: resource conservation, clean water, and clean air. #12;Center for By-Products, Italy, June 30, 2010. #12;Center for By-Products Utilization UWM Center for By-Products Utilization

Saldin, Dilano

403

UPDATE ON THE INTERNATIONAL EXPERIMENT ON CO2 OCEAN SEQUESTRATION  

E-Print Network [OSTI]

in the deep ocean, forming a buoyant plume. Sea water will be entrained into the rising droplet plume Center, Bergen, Norway 4 Norwegian Institute for Water Research (NIVA), Bergen, Norway 5 University objective of our project on CO2 ocean sequestration is to investigate its technical feasibility

404

ORIGINAL ARTICLE Navajo SandstonebrineCO2 interaction: implications  

E-Print Network [OSTI]

in the western US (Loope and Rowe 2003), and is thus potentially sig- nificant with respect to carbonORIGINAL ARTICLE Navajo Sandstone­brine­CO2 interaction: implications for geological carbon a source of carbon for the precipitation of carbonate minerals. Mineral trapping through the precipitation

Zhu, Chen

405

The Energy and CO2 Emissions Impact of  

E-Print Network [OSTI]

centers at MIT: the Center for Global Change Science (CGCS) and the Center for Energy and Environmental reduction target of 40­45% relative to 2005 and a non-fossil primary energy target of 15% by 2020. DuringThe Energy and CO2 Emissions Impact of Renewable Energy Development in China Xiliang Zhang, Tianyu

406

CO2-avskiljning med syrgasfrbrnning -nya tekniska mjligheter  

E-Print Network [OSTI]

with power and industrial sectors #12;Air-Fuel Combustion Air Fuel Flue gas CO2: 10-20 % N2: 60-70% Combustion Process #12;Oxy-Fuel vs. Air-Fuel Combustion - principle changes Principle changes: · Feed gas composition · Concentration of N2 · Recycle of flue gas · Concentration of combustion products · Residence

Lemurell, Stefan

407

Carbonation: An Efficient and Economical Process for CO2 Sequestration  

E-Print Network [OSTI]

Carbonation: An Efficient and Economical Process for CO2 Sequestration Tarun R Naik1 and Rakesh sequestration. Most of the studies related to the carbonation are limited to its effects on corrosion. The possibility of using carbonation process as a direct means for carbon dioxide sequestration is yet

Wisconsin-Milwaukee, University of

408

Chemical Looping Combustion for inherent CO2 capture in a  

E-Print Network [OSTI]

HRSG Stack Steam TurbineFuel Compr. Air Flue gas H2O CO2 to compression Depleted air HP Steam not possible with Ni/NiO 6 CLC in a combined cycle power plant Fuel Reactor Air Reactor Gas Turbine Gas Turbine) ­ adiabatic, 20 bar Stoichiometric MeO Air-fuel ratio Stoichiometric ­ 3*Stoicihometric Gas turbine

409

A Review of Emerging Energy-efficiency and CO2 Emission-reduction Technologies for Cement and Concrete Production  

E-Print Network [OSTI]

efficiency and CO2 Emission-reduction Technologies forefficiency and CO2 Emission- reduction Technologies forefficiency and CO2 Emission-reduction Technologies The

Hasanbeigi, Ali

2014-01-01T23:59:59.000Z

410

ACID GASES IN CO2-RICH SUBSURFACE GEOLOGIC ENVIRONMENTS  

SciTech Connect (OSTI)

The analysis of species behavior involving dilute fluid environments has been crucial for the advance of modern solvation thermodynamics through molecular-based formalisms to guide the development of macroscopic regression tools in the description of fluid behavior and correlation of experimental data (Chialvo 2013). Dilute fluid environments involving geologic formations are of great theoretical and practical relevance regardless of the thermodynamic state conditions. The most challenging systems are those involving highly compressible and reactive confined environments, i.e., where small perturbations of pressure and/or temperature can trigger considerable density changes. This in turn can alter significantly the species solvation, their preferential solvation, and consequently, their reactivity with one another and with the surrounding mineral surfaces whose outcome is the modification of the substrate porosity and permeability, and ultimately, the integrity of the mineral substrates. Considering that changes in porosity and permeability resulting from dissolution and precipitation phenomena in confined environments are at the core of the aqueous CO2-mineral interactions, and that caprock integrity (e.g., sealing capacity) depends on these key parameters, it is imperative to gain fundamental understanding of the mineral-fluid interfacial phenomena and fluid-fluid equilibria under mineral confinement at subsurface conditions. In order to undertand the potential effects of acid gases as contaminants of supercritical CO2 streams, in the next section we will discuss the thermodynamic behavior of CO2 fluid systems by addressing two crucial issues in the context of carbon capture, utilization and sequestration (CCUS) technologies: (i) Why should we consider (acid gas) CO2 impurities? and (ii) Why are CO2 fluid - mineral interactions of paramount relevance?

Chialvo, Ariel A [ORNL] [ORNL; Vlcek, Lukas [ORNL] [ORNL; Cole, David [Ohio State University] [Ohio State University

2013-01-01T23:59:59.000Z

411

Ris Energy Report 6 CO2 capture and storage 2 6.1 What is CO2 capture and storage?  

E-Print Network [OSTI]

be burned in an engine or fuel cell, and a CO2 stream for storage (see chapters 7.3 and 7.6 for further2 Gas, oil Air O2 H2 Raw material Gas, ammonia, steel Air/O2 Steam Figure 15: the three main

412

Gravity monitoring of CO2 movement during sequestration: Model studies  

E-Print Network [OSTI]

an oil reservoir, (2) a brine formation, and (3) a depletedoil-bearing formations or depleted coalbed methane reservoirs.

Gasperikova, E.

2008-01-01T23:59:59.000Z

413

System-level modeling for geological storage of CO2  

E-Print Network [OSTI]

formations or depleted oil or gas reservoirs. Research hasas brine formations or depleted oil or gas reservoirs. The

Zhang, Yingqi; Oldenburg, Curtis M.; Finsterle, Stefan; Bodvarsson, Gudmundur S.

2006-01-01T23:59:59.000Z

414

Gravity monitoring of CO2 movement during sequestration: Model studies  

E-Print Network [OSTI]

2 Sequestration in Coalbed Methane Reservoirs of the Black2006 International Coalbed Methane Symposium Proceedings,and the third is for a coalbed methane formation. EOR/

Gasperikova, E.

2008-01-01T23:59:59.000Z

415

Seismic modeling to monitor CO2 geological storage: The Atzbach ...  

E-Print Network [OSTI]

Jun 8, 2012 ... greenhouse effect. In order to avoid these emissions, one of the options is the geological storage of carbon dioxide in depleted hydrocarbon ...

2012-05-30T23:59:59.000Z

416

A seismic modeling methodology for monitoring CO2 geological ...  

E-Print Network [OSTI]

May 20, 2011 ... possible causes of the greenhouse effect. In order to avoid these emissions, one of the. 30 options is the geological storage of carbon dioxide ...

2011-05-20T23:59:59.000Z

417

System-level modeling for geological storage of CO2  

E-Print Network [OSTI]

Gas Reservoirs for Carbon Sequestration and Enhanced Gasfrom geologic carbon sequestration sites, Vadose Zonethe feasibility of carbon sequestration with enhanced gas

Zhang, Yingqi; Oldenburg, Curtis M.; Finsterle, Stefan; Bodvarsson, Gudmundur S.

2006-01-01T23:59:59.000Z

418

A Review of Hazardous Chemical Species Associated with CO2 Capture from Coal-Fired Power Plants and Their Potential Fate in CO2 Geologic Storage  

E-Print Network [OSTI]

capture of CO 2 from gasifier process producing electricalPlaquemine, Louisiana. The gasifier is a proprietary designGasifier .

Apps, J.A.

2006-01-01T23:59:59.000Z

419

The Anthropogenic Perturbation of Atmospheric CO2 and the Climate System  

E-Print Network [OSTI]

of carbon dioxide (CO2), a powerful greenhouse gas (GHG), are redistributed within the climate system

Fortunat, Joos

420

Constraint of the CO2 rise by new atmospheric carbon isotopic measurements during the last deglaciation  

E-Print Network [OSTI]

Click Here for Full Article Constraint of the CO2 rise by new atmospheric carbon isotopic increase of atmospheric carbon dioxide (CO2) during the last glacialinterglacial climatic transition remain debated. We analyzed the parallel evolution of CO2 and its stable carbon isotopic ratio (d13 CO2

Chappellaz, Jérôme

Note: This page contains sample records for the topic "ks modeling co2" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

CO2 efflux from Amazonian headwater streams represents a significant fate for deep soil respiration  

E-Print Network [OSTI]

CO2 efflux from Amazonian headwater streams represents a significant fate for deep soil respiration amounts of CO2 to the atmosphere, while the magnitude of CO2 degassing from small streams remains a major was as terrestrially-respired CO2 dissolved within soils, over 90% of which evaded to the atmosphere within headwater

Lehmann, Johannes

422

Large CO2 disequilibria in tropical lakes Humberto Marotta,1,2  

E-Print Network [OSTI]

Large CO2 disequilibria in tropical lakes Humberto Marotta,1,2 Carlos M. Duarte,2 Sebastian Sobek,3 November 2009. [1] On the basis of a broad compilation of data on pCO2 in surface waters, we show tropical lakes to be, on average, far more supersaturated and variable in CO2 (geometric mean ± SE pCO2 = 1804

Wehrli, Bernhard

423

Observations and simulations of synoptic, regional, and local variations in atmospheric CO2  

E-Print Network [OSTI]

Observations and simulations of synoptic, regional, and local variations in atmospheric CO2 Jih] Synoptic events may play an important role in determining the CO2 spatial distribution and temporal 2001, which had the most significant CO2 concentration variation in our case pool. The CO2

Collett Jr., Jeffrey L.

424

Physical controls on the isotopic composition of soil-respired CO2  

E-Print Network [OSTI]

Physical controls on the isotopic composition of soil-respired CO2 Nick Nickerson1 and Dave Risk1] Measurement of the isotopic composition of soil and soil-respired CO2 (d13 CO2) has become an invaluable tool in understanding the effects of diffusive transport on soil CO2 isotopic composition, it is crucial

425

Edinburgh Research Explorer Can seasonal and interannual variation in landscape CO2 fluxes  

E-Print Network [OSTI]

Edinburgh Research Explorer Can seasonal and interannual variation in landscape CO2 fluxes be detected by atmospheric observations of CO2 concentrations made at a tall tower? Citation for published in landscape CO2 fluxes be detected by atmospheric observations of CO2 concentrations made at a tall tower

Millar, Andrew J.

426

Extracting CO2 from seawater: Climate change mitigation and renewable liquid fuel  

E-Print Network [OSTI]

Extracting CO2 from seawater: Climate change mitigation and renewable liquid fuel Matthew Eisaman and their impact · Technology: Extracting CO2 from seawater · Application: Renewable liquid fuel #12;Outline: Renewable liquid fuel #12;The data on atmospheric CO2 2000 years ago http://cdiac.ornl.gov/trends/co2

Homes, Christopher C.

427

Rcupration assiste d'hydrocarbures, conventionnels ou non, par injection de CO2.  

E-Print Network [OSTI]

· Récupération d' hydrocarbures conventionnels - CO2 ­ EOR enhanced oil recovery - CO2 ­ EGR enhanced gas-combustion (gas processing) 7 EOR 1986 Sleipner CO2 Injection Norway Pre-combustion (gas processing) 1 (+ 0 EOR 2000 Enid Fertilizer Plant United States Pre-combustion (fertiliser) 0.7 EOR 1982 In Salah CO2

Canet, Léonie

428

CO2 Capture and Utilization for Enhanced Oil Poul Jacob Vilhelmsen1  

E-Print Network [OSTI]

for Enhanced Oil Recovery (EOR). CO2 capture is to some extent a know technology but has not yet been optimised and commercialised for power plant utilisation. Correspondingly CO2 utilisation for EOR is a known method in other and utilisation of CO2. DONG E&P within DONG Energy has started work on the utilisation of CO2 for EOR

429

Wavelength dependence of prepulse laser beams on EUV emission from CO2 reheated Sn plasma  

E-Print Network [OSTI]

Wavelength dependence of prepulse laser beams on EUV emission from CO2 reheated Sn plasma J. R. The expanding plume was then reheated by a 35 ns CO2 laser operating at 10.6 m. The role of prepulse wavelength, Tanaka et al.11 demonstrated the advantages of using a CO2 laser for generating higher CE. The CO2 LPP

Harilal, S. S.

430

Carbonation of alkaline paper mill waste to reduce CO2 greenhouse gas emissions into the atmosphere  

E-Print Network [OSTI]

Carbonation of alkaline paper mill waste to reduce CO2 greenhouse gas emissions into the atmosphere of anthropogenic emission of greenhouse gases into the atmosphere such as CO2, CH4, N2O and CFCs. The CO2 emissions to reflect, adsorb and emit the solar energy. However, the continuous emissions of CO2 into the atmosphere

Montes-Hernandez, German

431

Efficient CO2 Fixation Pathways: Energy Plant: High Efficiency Photosynthetic Organisms  

SciTech Connect (OSTI)

PETRO Project: UCLA is redesigning the carbon fixation pathways of plants to make them more efficient at capturing the energy in sunlight. Carbon fixation is the key process that plants use to convert carbon dioxide (CO2) from the atmosphere into higher energy molecules (such as sugars) using energy from the sun. UCLA is addressing the inefficiency of the process through an alternative biochemical pathway that uses 50% less energy than the pathway used by all land plants. In addition, instead of producing sugars, UCLA’s designer pathway will produce pyruvate, the precursor of choice for a wide variety of liquid fuels. Theoretically, the new biochemical pathway will allow a plant to capture 200% as much CO2 using the same amount of light. The pathways will first be tested on model photosynthetic organisms and later incorporated into other plants, thus dramatically improving the productivity of both food and fuel crops.

None

2012-01-01T23:59:59.000Z

432

VUV-absorption cross section of CO2 at high temperatures and impact on exoplanet atmospheres  

E-Print Network [OSTI]

Ultraviolet (UV) absorption cross sections are an essential ingredient of photochemical atmosphere models. Exoplanet searches have unveiled a large population of short-period objects with hot atmospheres, very different from what we find in our solar system. Transiting exoplanets whose atmospheres can now be studied by transit spectroscopy receive extremely strong UV fluxes and have typical temperatures ranging from 400 to 2500 K. At these temperatures, UV photolysis cross section data are severely lacking. Our goal is to provide high-temperature absorption cross sections and their temperature dependency for important atmospheric compounds. This study is dedicated to CO2, which is observed and photodissociated in exoplanet atmospheres. We performed these measurements for the 115 - 200 nm range at 300, 410, 480, and 550 K. In the 195 - 230 nm range, we worked at seven temperatures between 465 and 800 K. We found that the absorption cross section of CO2 is very sensitive to temperature, especially above 160 nm....

Venot, Olivia; Bénilan, Yves; Gazeau, Marie-Claire; Hébrard, Eric; Larcher, Gwenaelle; Schwell, Martin; Dobrijevic, Michel; Selsis, Franck

2015-01-01T23:59:59.000Z

433

CO2 Storage and Enhanced Oil Recovery: Bald Unit Test Site, Mumford Hills Oil Field, Posey County, Indiana  

SciTech Connect (OSTI)

The Midwest Geological Sequestration Consortium (MGSC) carried out a small-scale carbon dioxide (CO2) injection test in a sandstone within the Clore Formation (Mississippian System, Chesterian Series) in order to gauge the large-scale CO2 storage that might be realized from enhanced oil recovery (EOR) of mature Illinois Basin oil fields via miscible liquid CO2 flooding. As part of the MGSC�������¢����������������s Validation Phase (Phase II) studies, the small injection pilot test was conducted at the Bald Unit site within the Mumford Hills Field in Posey County, southwestern Indiana, which was chosen for the project on the basis of site infrastructure and reservoir conditions. Geologic data on the target formation were extensive. Core analyses, porosity and permeability data, and geophysical logs from 40 wells were used to construct cross sections and structure contour and isopach maps in order to characterize and define the reservoir architecture of the target formation. A geocellular model of the reservoir was constructed to improve understanding of CO2 behavior in the subsurface. At the time of site selection, the Field was under secondary recovery through edge-water injection, but the wells selected for the pilot in the Bald Unit had been temporarily shut-in for several years. The most recently shut-in production well, which was surrounded by four nearby shut-in production wells in a five-spot pattern, was converted to CO2 injection for this pilot. Two additional wells outside the immediate five-spot pattern, one of which was an active producer, were instrumented to measure surface temperature and pressure. The CO2 injection period lasted from September 3, 2009, through December 14, 2010, with one three-month interruption caused by cessation of CO2 deliveries due to winter weather. Water was injected into the CO2 injection well during this period. A total of 6,300 tonnes (6,950 tons) of CO2 were injected into the reservoir at rates that generally ranged from 18 to 32 tonnes (20 to 35 tons) per day. The CO2 injection bottomhole pressure generally remained at 8.3 to 9.0 MPag (1,200 to 1,300 psig). The CO2 injection was followed by continued monitoring for nine months during post-CO2 water injection. A monitoring, verification, and accounting (MVA) program was designed to determine the fate of injected CO2. Extensive periodic sampling and analysis of brine, groundwater, and produced gases began before CO2 injection and continued through the monitored waterflood periods. Samples were gathered from production wells and three newly installed groundwater monitoring wells. Samples underwent geochemical and isotopic analyses to reveal any CO2-related changes. Groundwater and kinetic modeling and mineralogical analysis were also employed to better understand the long-term dynamics of CO2 in the reservoir. No CO2 leakage into groundwater was detected, and analysis of brine and gas chemistry made it possible to track the path of plume migration and infer geochemical reactions and trapping of CO2. Cased-hole logging did not detect any CO2 in the near-wellbore region. An increase in CO2 concentration was first detected in February 2010 from the gas present in the carboy during brine sampling; however, there was no appreciable gas volume associated with the detection of CO2. The first indication of elevated gas rates from the commingled gas of the pilot�������¢����������������s production wells occurred in July 2010 and reached a maximum of 0.36 tonnes/day (0.41 tons/day) in September 2010. An estimated 27 tonnes (30 tons) of CO2 were produced at the surface from the gas separator at the tank battery from September 3, 2009, through September 11, 2011, representing 0.5% of the injected CO2. Consequently, 99.5%

Frailey, Scott M.; Krapac, Ivan G.; Damico, James R.; Okwen, Roland T.; McKaskle, Ray W.

2012-03-30T23:59:59.000Z

434

Stomatal proxy record of CO2 concentrations from the last termination suggests an important role for CO2 at climate change transitions  

E-Print Network [OSTI]

Stomatal proxy record of CO2 concentrations from the last termination suggests an important role for CO2 at climate change transitions Margret Steinthorsdottir a,*, Barbara Wohlfarth a , Malin E2 reconstruction Betula nana Sweden a b s t r a c t A new stomatal proxy-based record of CO2

Wohlfarth, Barbara

435

1M. Panahi, S. Skogestad ' Optimal Operation of a CO2 Capturing Plant for a Wide Range of Disturbances' Optimal Operation of a CO2 Capturing  

E-Print Network [OSTI]

1M. Panahi, S. Skogestad ' Optimal Operation of a CO2 Capturing Plant for a Wide Range of Disturbances' Optimal Operation of a CO2 Capturing Plant for a Wide Range of Disturbances Mehdi Panahi Sigurd Skogestad 18.10.2011 AIChE Annual Meeting #12;2M. Panahi, S. Skogestad ' Optimal Operation of a CO2

Skogestad, Sigurd

436

ULTimateCO2 : A FP7 European Project dedicated to the understanding of the long term fate of geologically stored CO2  

E-Print Network [OSTI]

ULTimateCO2 : A FP7 European Project dedicated to the understanding of the long term fate of geologically stored CO2 Audigane, P.1 , Brown, S.2 , Dimier A.3 , Frykman P.4 , Gherardi F.5 , Le Gallo Y.6 Recherches Géologiques et minières - France 2 CO2SENSE limited, United Kingdom 3 EIFER, EIFER europaisches

Paris-Sud XI, Université de

437

Incorporating the Effect of Price Changes on CO2-Equivalent Emissions From Alternative-Fuel Lifecycles: Scoping the Issues  

E-Print Network [OSTI]

function of CO2 taxes (or CO2 emission limits) 10 . b) Taxesrefinery process areas CO2 emissions from the control of COfertilizer use. CH4 and CO2 emissions from soil (parameters

Delucchi, Mark

2005-01-01T23:59:59.000Z

438

Predicting CO2-water interfacial tension under pressure and temperature conditions of geologic CO2 storage  

E-Print Network [OSTI]

liquid/vapor interface of SPC/E water. J. Phys. Chem. 100,dioxide mixtures described by the SPC/E and EPM2 models. (and water oxygen is denoted by O SPC/E and O TIP for SPC/E (

Nielsen, L.C.

2013-01-01T23:59:59.000Z

439

Separation of CO2 from flue gas using electrochemical cells  

SciTech Connect (OSTI)

ABSTRACT Past research with high temperature molten carbonate electrochemical cells has shown that carbon dioxide can be separated from flue gas streams produced by pulverized coal combustion for power generation, However, the presence of trace contaminants, i.e" sulfur dioxide and nitric oxides, will impact the electrolyte within the cell. If a lower temperature cell could be devised that would utilize the benefits of commercially-available, upstream desulfurization and denitrification in the power plant, then this CO2 separation technique can approach more viability in the carbon sequestration area, Recent work has led to the assembly and successful operation of a low temperature electrochemical cell. In the proof-of-concept testing with this cell, an anion exchange membrane was sandwiched between gas-diffusion electrodes consisting of nickel-based anode electrocatalysts on carbon paper. When a potential was applied across the cell and a mixture of oxygen and carbon dioxide was flowed over the wetted electrolyte on the cathode side, a stream of CO2 to O2 was produced on the anode side, suggesting that carbonate/ bicarbonate ions are the CO2 carrier in the membrane. Since a mixture of CO 2 and 02 is produced, the possibility exists to use this stream in oxy-firing of additional fuel. From this research, a novel concept for efficiently producing a carbon dioxide rich effiuent from combustion of a fossil fuel was proposed. Carbon dioxide and oxygen are captured from the flue gas of a fossilfuel combustor by one or more electrochemical cells or cell stacks. The separated stream is then transferred to an oxy-fired combustor which uses the gas stream for ancillary combustion, ultimately resulting in an effluent rich in carbon dioxide, A portion of the resulting flow produced by the oxy-fired combustor may be continuously recycled back into the oxy-fired combustor for temperature control and an optimal carbon dioxide rich effluent.

Pennline, H.W; Granite, E.J.; Luebke, D.R; Kitchin, J.R; Landon, J.; Weiland, L.M.

2010-06-01T23:59:59.000Z

440

Photodesorption of ices I: CO, N2 and CO2  

E-Print Network [OSTI]

A longstanding problem in astrochemistry is how molecules can be maintained in the gas phase in dense inter- and circumstellar regions. Photodesorption is a non-thermal desorption mechanism, which may explain the small amounts of observed cold gas in cloud cores and disk mid-planes. This paper aims to determine the UV photodesorption yields and to constrain the photodesorption mechanisms of three astrochemically relevant ices: CO, N2 and CO2. In addition, the possibility of co-desorption in mixed and layered CO:N2 ices is explored. The ice photodesorption is studied experimentally under ultra high vacuum conditions and at 15-60 K using a hydrogen discharge lamp (7-10.5 eV). The ice desorption during irradiation is monitored by reflection absorption infrared spectroscopy of the ice and simultaneous mass spectrometry of the desorbed molecules. Both the UV photodesorption yields per incident photon and the photodesorption mechanisms are molecule specific. CO photodesorbs without dissociation from the surface layer of the ice. N2, which lacks an electronic transition in this wavelength range, has a photodesorption yield that is more than an order of magnitude lower. This yield increases significantly due to co-desorption when N2 is mixed in with or layered on top of CO ice. CO2 photodesorbs through dissociation and subsequent recombination from the top 10 layers of the ice. At low temperatures (15-18 K) the derived photodesorption yields are 2.7x10^-3 and CO2 photodesorption yield is 1.2x10^-3x(1-e^(-X/2.9)) + 1.1x10^-3x(1-e^(-X/4.6)) molecules photon-1, where X is the ice thickness in monolayers and the two parts of the expression represent a CO2 and CO photodesorption pathway.

Karin I. Oberg; Ewine F. van Dishoeck; Harold Linnartz

2009-01-23T23:59:59.000Z

Note: This page contains sample records for the topic "ks modeling co2" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Meeting the CO2 Challenge DEER 2002 | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion | Department of EnergyDevelopmentTechnologies | DepartmentADVISORYFinal Report onthe CO2

442

Grangemouth Advanced CO2 Capture Project GRACE | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to: navigation,Ohio: Energy ResourcesGordon, Alabama:5812144°Grangemouth Advanced CO2

443

Economically Efficient Operation of CO2 Capturing Process Part I: Self-optimizing Procedure for Selecting the Best Controlled Variables  

E-Print Network [OSTI]

the greenhouse gas CO2 that causes global warming. Due to the effect of CO2 emissions on global warming

Skogestad, Sigurd

444

Assessment of Energy Efficiency Improvement and CO2 Emission Reduction Potentials in the Iron and Steel Industry in China  

E-Print Network [OSTI]

Improvement and CO2 Emission Reduction Potentials in theElectricity Saving and CO2 Emission Reduction in the Iron

Hasanbeigi, Ali

2013-01-01T23:59:59.000Z

445

IMPLEMENTING A NOVEL CYCLIC CO2 FLOOD IN PALEOZOIC REEFS  

SciTech Connect (OSTI)

Recycled CO2 will be used in this demonstration project to produce bypassed oil from the Silurian Dover 35 pinnacle reef (Otsego County) in the Michigan Basin. Contract negotiations by our industry partner to gain access to the CO2 supply have been completed and the State of Michigan has issued an order to allow operation of the project. Injection of CO2 is scheduled to begin in February, 2004. Subsurface characterization is being completed using well log tomography animations and 3D visualizations to map facies distributions and reservoir properties in two reefs, the Belle River Mills and Chester 18 Fields. The Belle River Mills and Chester18 fields are being used as type-fields because they have excellent log and/or core data coverage. Amplitude slicing of the normalized gamma ray and core permeability and core porosity curves is showing trends that indicate significant heterogeneity and compartmentalization in these reservoirs associated with the original depositional fabric of the rocks. Digital and hard copy data continues to be compiled for the Niagaran reefs in the Michigan Basin. Technology transfer took place through technical presentations regarding visualization of the heterogeneity of the Niagaran reefs. An oral presentation was given at the AAPG Eastern Section Meeting and a booth at the same meeting was used to meet one-on-one with operators.

James R. Wood; W. Quinlan; A. Wylie

2004-01-01T23:59:59.000Z

446

Search for the CP symmetry violation in the decays of Ks mesons using the KLOE detector  

E-Print Network [OSTI]

The aim of this work was to determine the KS -> 3pi0 decay branching ratio and a modulus of the eta000 parameter, defined as the ratio of amplitudes for KS -> 3 pi0 to KL -> 3pi0 decays, which characterizes the CP symmetry violation in this decay. The measurement has been carried out with the KLOE detector operating at the phi-factory DAFNE in the Italian National Center for Nuclear Physics in Frascati. The KS mesons were identified with high efficiency via registration of these KL mesons which crossed the drift chamber without decaying and then interacted with the KLOE electromagnetic calorimeter. The KS four-momentum vector was then determined using the registered position of the KL meson and the known momentum of the phi meson. Next, the search for the KS -> 3pi0 -> 6gamma decay was carried out by the selection of events with six gamma quanta which momenta were reconstructed using time and energy measured by the electromagnetic calorimeter. To increase the signal over background ratio after identification of the KS meson and requiring six reconstructed photons a discriminant analysis is performed. It is based on kinematical fit, testing of the signal and background hypotheses and exploiting of the differences in kinematics of the KS decays into 2pi0 and 3pi0. Hence, we have obtained the upper limit on the KS -> 3pi0 branching ratio at the 90% confidence level BR(KS -> 3pi0)KS -> 3pi0 decay presented in this work failed to detect a signal of sufficient statistical significance. This upper limit can be translated into a limit on the modulus of the eta000 parameter amounting to: |eta000| < 0.009 at the 90% confidence level.

M. Silarski

2013-02-19T23:59:59.000Z

447

Tropical forest responses to increasing [CO2]: current knowledge and opportunities for future research  

SciTech Connect (OSTI)

Elevated atmospheric [CO2] (ca) will undoubtedly affect the metabolism of tropical forests worldwide; however, critical aspects of how tropical forests will respond remain largely unknown. Here we review the current state of knowledge about physiological and ecological responses, with the aim of providing a framework that can help to guide future experimental research. Modelling studies have indicated that elevated ca can potentially stimulate photosynthesis more in the tropics than at higher latitudes, because suppression of photorespiration by elevated ca increases with temperature. However, canopy leaves in tropical forests could also potentially reach a high temperature threshold under elevated ca that will moderate the rise in photosynthesis. Belowground responses, including fine root production, nutrient foraging, and soil organic matter processing, will be especially important to the integrated ecosystem response to elevated CO2. Water-use efficiency will increase as ca rises, potentially impacting upon soil moisture status and nutrient availability. Recruitment may be differentially altered for some functional groups, potentially decreasing ecosystem carbon storage. Whole-forest CO2 enrichment experiments are urgently needed to test predictions of tropical forest functioning under elevated ca. Smaller scale experiments in the understory and in gaps would also be informative, and could provide stepping stones toward stand-scale manipulations.

Cernusak, Lucas [Australian National University, Canberra, Australia; Winter, Klaus [Smithsonian Tropical Research Institute; Dalling, James [University of Illinois, Urbana-Champaign; Holtum, Joseph [James Cook University; Jaramillo, Carlos [Smithsonian Tropical Research Institute; Korner, Christian [University of Basel; Leakey, Andrew D.B. [University of Illinois; Norby, Richard J [ORNL; Poulter, Benjamin [Laboratoire des Sciences du Climat et de l'Environement, France; Turner, Benjamin [Smithsonian Tropical Research Institute; Wright, S. Joseph [Smithsonian Tropical Research Institute

2013-01-01T23:59:59.000Z

448

Improved Efficiency of Miscible CO(2) Floods and Enhanced Prospects for CO(2) Flooding Heterogeneous Reservoirs.  

SciTech Connect (OSTI)

The overall goal of this project was to improve the efficiency of miscible C0{sub 2} floods and enhance the prospects for flooding heterogeneous reservoirs. This objective was accomplished through experimental and modeling research in three task areas: (1) foams for selective mobility control in heterogeneous reservoirs,( 2) reduction of the amount of C0{sub 2} required in C0{sub 2} floods, and (3) low IFT processe and the possibility of C0{sub 2} flooding in fractured reservoirs. This report provides results from the three-year project for each of the three task areas.

Grigg, R.B.; Schechter, D.S.

1997-08-01T23:59:59.000Z

449

Conversion of CO2 into Commercial Materials Using Carbon Feedstocks  

SciTech Connect (OSTI)

In this project, our research focused on developing reaction chemistry that would support using carbon as a reductant for CO2 utilization that would permit CO2 consumption on a scale that would match or exceed anthropomorphic CO2 generation for energy production from fossil fuels. Armed with the knowledge that reactions attempting to produce compounds with an energy content greater than CO2 would be thermodynamically challenged and/or require significant amounts of energy, we developed a potential process that utilized a solid carbon source and recycled the carbon to effectively provide infinite time for the carbon to react. During testing of different carbon sources, we found a wide range of reaction rates. Biomass-derived samples had the most reactivity and coals and petcoke had the lowest. Because we had anticipated this challenge, we recognized that a catalyst would be necessary to improve reaction rates and conversion. From the data analysis of carbon samples, we recognized that alkali metals improved the reaction rate. Through parametric testing of catalyst formulations we were able to increase the reaction rate with petcoke by a factor of >70. Our efforts to identify the reaction mechanism to assist in improving the catalyst formulation demonstrated that the catalyst was catalyzing the extraction of oxygen from CO2 and using this extracted oxygen to oxidize carbon. This was a significant discovery in that if we could modify the catalyst formulation to permit controlled the oxidation, we would have a very power selective oxidation process. With selective oxidation, CO2 utilization could be effective used as one of the process steps in making many of the large volume commodity chemicals that support our modern lifestyles. The key challenges for incorporating these functionalities into the catalyst formulation were to make the oxidation selective and lower the temperature required for catalytic activity. We identified four catalyst families that had the potential to meet these challenges. Initial screening of the catalyst families did show that the reduction/oxidation activity did occur at lower temperatures and that these catalysts were able to cause carbon chain growth as well as C—C cleavage. A preliminary techno-economic feasibility of using petcoke/catalyst to produce a CO-rich syngas product was completed and showed significant economic promise. Testing of the different catalyst families demonstrated that Catalyst A was able to stably produce 5 sccm of ethylene/gram of catalyst at 900°C for one hour. For dry methane reforming, our Catalyst 4 was able to achieve production rates of > 10 sccm of CO and > 3 sccm of H2 per gram of catalyst at 600°C and 350 psig. Based on these developments, the potential for CO2 utilization in the production of large volume commodity chemicals is very promising.

Shen, Jian-Ping; Peters, Jonathan; Lail, Marty; Mobley, Paul; Turk, Brian

2014-05-31T23:59:59.000Z

450

STOMP Subsurface Transport Over Multiple Phases: STOMP-CO2 and STOMP-CO2e Guide: Version 1.0  

SciTech Connect (OSTI)

This STOMP (Subsurface Transport Over Multiple Phases) guide document describes the theory, use, and application of the STOMP-CO2 and STOMP-CO2e operational modes. These operational modes of the STOMP simulator are configured to solve problems involving the sequestration of CO2 in geologic saline reservoirs. STOMP-CO2 is the isothermal version and STOMP-CO2e is the nonisothermal version. These core operational modes solve the governing conservation equations for component flow and transport through geologic media; where, the STOMP-CO2 components are water, CO2 and salt and the STOMP-CO2e operational mode also includes an energy conservation equation. Geochemistry can be included in the problem solution via the ECKEChem (Equilibrium-Conservation-Kinetic-Equation Chemistry) module, and geomechanics via the EPRMech (Elastic-Plastic-Rock Mechanics) module. This addendum is designed to provide the new user with a full guide for the core capabilities of the STOMP-CO2 and -CO2e simulators, and to provide the experienced user with a quick reference on implementing features. Several benchmark problems are provided in this addendum, which serve as starting points for developing inputs for more complex problems and as demonstrations of the simulator’s capabilities.

White, Mark D.; Bacon, Diana H.; McGrail, B. Peter; Watson, David J.; White, Signe K.; Zhang, Z. F.

2012-04-03T23:59:59.000Z

451

Geological Sequestration Training and Research Program in Capture and Transport: Development of the Most Economical Separation Method for CO2 Capture  

SciTech Connect (OSTI)

The project provided hands-on training and networking opportunities to undergraduate students in the area of carbon dioxide (CO2) capture and transport, through fundamental research study focused on advanced separation methods that can be applied to the capture of CO2 resulting from the combustion of fossil-fuels for power generation . The project team’s approach to achieve its objectives was to leverage existing Carbon Capture and Storage (CCS) course materials and teaching methods to create and implement an annual CCS short course for the Tuskegee University community; conduct a survey of CO2 separation and capture methods; utilize data to verify and develop computer models for CO2 capture and build CCS networks and hands-on training experiences. The objectives accomplished as a result of this project were: (1) A comprehensive survey of CO2 capture methods was conducted and mathematical models were developed to compare the potential economics of the different methods based on the total cost per year per unit of CO2 avoidance; and (2) Training was provided to introduce the latest CO2 capture technologies and deployment issues to the university community.

Vahdat, Nader

2013-09-30T23:59:59.000Z

452

Effects of CO2 on H2O band profiles and band strengths in mixed H2O:CO2 ices  

E-Print Network [OSTI]

H2O is the most abundant component of astrophysical ices. In most lines of sight it is not possible to fit both the H2O 3 um stretching, the 6 um bending and the 13 um libration band intensities with a single pure H2O spectrum. Recent Spitzer observations have revealed CO2 ice in high abundances and it has been suggested that CO2 mixed into H2O ice can affect relative strengths of the 3 um and 6 um bands. We used laboratory infrared transmission spectroscopy of H2O:CO2 ice mixtures to investigate the effects of CO2 on H2O ice spectral features at 15-135 K. We find that the H2O peak profiles and band strengths are significantly different in H2O:CO2 ice mixtures compared to pure H2O ice. In all H2O:CO2 mixtures, a strong free-OH stretching band appears around 2.73 um, which can be used to put an upper limit on the CO2 concentration in the H2O ice. The H2O bending mode profile also changes drastically with CO2 concentration; the broad pure H2O band gives way to two narrow bands as the CO2 concentration is increased. This makes it crucial to constrain the environment of H2O ice to enable correct assignments of other species contributing to the interstellar 6 um absorption band. The amount of CO2 present in the H2O ice of B5:IRS1 is estimated by simultaneously comparing the H2O stretching and bending regions and the CO2 bending mode to laboratory spectra of H2O, CO2, H2O:CO2 and HCOOH.

Karin I. Oberg; Helen J. Fraser; A. C. Adwin Boogert; Suzanne E. Bisschop; Guido W. Fuchs; Ewine F. van Dishoeck; Harold Linnartz

2006-10-25T23:59:59.000Z

453

Impact of porous medium desiccation during anhydrous CO2 injection in deep saline aquifers: up scaling from experimental  

E-Print Network [OSTI]

into the atmosphere. CO2 is captured from exhaust gas in power plants or industrial units and then stored of the saturation profile evolution with two phase flow model integrating thermal effects. An up scaling on recent experiments and numerical simulations, the near-well injection zone is identified

Boyer, Edmond

454

2 Large CO2 reductions via offshore wind power matched to inherent 3 storage in energy end-uses  

E-Print Network [OSTI]

2 Large CO2 reductions via offshore wind power matched to inherent 3 storage in energy end-uses 4 by matching the winds of the 14 Middle-Atlantic Bight (MAB) to energy demand in the 15 adjacent states] We develop methods for assessing offshore wind 9 resources, using a model of the vertical structure

Firestone, Jeremy

455

Inexpensive CO2 Thickening Agents for Improved Mobility Control of CO2 Floods  

SciTech Connect (OSTI)

The objective of this research was the design, synthesis and evaluation of inexpensive, non-fluorous carbon dioxide thickening agents. We followed the same strategy employed in the design of fluorinated CO{sub 2} polymeric thickeners. First, a highly CO{sub 2}-philic, hydrocarbon-based monomer was to be identified. Polymers or oligomers of this monomer were then synthesized. The second step was to design a CO{sub 2}-thickener based on these CO{sub 2}-philic polymers. Two types of thickeners were considered. The first was a copolymer in which the CO{sub 2}-philic monomer was combined with a small proportion of CO{sub 2}-phobic associating groups that could cause viscosity-enhancing intermolecular interactions to occur. The second was a small hydrogen-bonding compound with urea groups in the core to promote intermolecular interactions that would cause the molecules to 'stack' in solution while the arms were composed of the CO{sub 2}-philic oligomers. Although we were not able to develop a viable thickener that exhibited high enough CO{sub 2} solubility at EOR MMP conditions to induce a viscosity increase, we made significant progress in our understanding of CO{sub 2}-soluble compounds that can be used in subsequent studies to design CO{sub 2}-soluble thickeners or CO{sub 2}-soluble surfactant-based foaming agents. These findings are detailed in this final report. In summary, we assessed many polymers and verified that the most CO{sub 2}-soluble oxygenated hydrocarbon polymer is poly(vinyl acetate), PVAc. This is primarily due to the presence of both ether and carbonyl oxygens associated with acetate-rich compounds. In addition to polymers, we also made small acetate-rich molecules that were also capable of associating in solution via the inclusion of hydrogen-bonding groups in hopes of forming viscosity-enhancing macromolecules. Despite the presence of multiple acetate groups in these compounds, which can impart incredible CO{sub 2}-solubility to many compounds, our attempts to make acetate-rich high molecular weight polymers and small hydrogen-bonding compounds did not yield a highly CO{sub 2}-soluble polymer or hydrogen-bonding associative thickener. The conclusions of our molecular modeling calculations confirmed that although acetates are indeed 'CO{sub 2}-philic', nitrogen-containing amines also interact favorably with CO{sub 2} and should also be examined. Therefore we obtained and synthesized many N-rich (e.g. amine-containing) polymers. Unfortunately, we found that the intermolecular polymer-polymer interactions between the amines were so strong that the polymers were essentially insoluble in CO{sub 2}. For the convenience of the reader, a table of all of the polymers evaluated during this research is provided.

Robert Enick; Eric Beckman; Andrew Hamilton

2005-08-31T23:59:59.000Z

456

Study of Penguin Pollution in the B^0 -> J/psi K_S Decay  

E-Print Network [OSTI]

We study the penguin pollution in the B^0 -> J/psi K_S decay up to leading power in 1/m_b and to next-to-leading order in \\alpha_s, m_b being the b quark mass and \\alpha_s the strong coupling constant. The deviation \\Delta S_{J/psi K_S} of the mixing-induced CP asymmetry from sin(2\\phi_1) and the direct CP asymmetry A_{J/psi K_S} are both found to be of O(10^{-3}) in a formalism that combines the QCD-improved factorization and perturbative QCD approaches.

Satoshi Mishima

2007-03-18T23:59:59.000Z

457

Pre-Combustion CO2 Control | netl.doe.gov  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas ConchasPassive Solar Home Design PassivePostdoctoralKanareykin,U DPre-Combustion CO2 Control

458

CO2e Capital Limited | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of InspectorConcentrating SolarElectricEnergyCTBarreis a city in ChittendenPartners LLC JumpCO2e Capital Limited

459

Direct s-CO2 Reciever Development | Department of Energy  

Office of Environmental Management (EM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "of EnergyEnergy CooperationRequirements Matrix U.S. DepartmentBaseload OperationDirect s-CO2 Reciever

460

From CO2 to Methanol via Novel Nanocatalysts  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsing ZirconiaPolicyFeasibilityFieldMinds"OfficeTour theFrom CO2 to Methanol via

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461

From CO2 to Methanol via Novel Nanocatalysts  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsing ZirconiaPolicyFeasibilityFieldMinds"OfficeTour theFrom CO2 to Methanol

462

From CO2 to Methanol via Novel Nanocatalysts  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsing ZirconiaPolicyFeasibilityFieldMinds"OfficeTour theFrom CO2 to MethanolFrom

463

Exsolution Enhanced Oil Recovery with Concurrent CO2 Sequestration. | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsing ZirconiaPolicy andExsolution Enhanced Oil Recovery with Concurrent CO2

464

From CO2 to Methanol via Novel Nanocatalysts  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-SeriesFlickr Flickr Editor's note: SincePlantFreedomofFrom CO2 to Methanol via

465

From CO2 to Methanol via Novel Nanocatalysts  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-SeriesFlickr Flickr Editor's note: SincePlantFreedomofFrom CO2 to Methanol

466

From CO2 to Methanol via Novel Nanocatalysts  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-SeriesFlickr Flickr Editor's note: SincePlantFreedomofFrom CO2 to MethanolFrom

467

Geologic CO2 sequestration inhibits microbial growth | EMSL  

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468

co2 capture meeting | netl.doe.gov  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched5 Industrial Carbon Capture and Storage CleanDiscovery of θ1cmarquardt2013 NETL CO2