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Sample records for ks mo mt

  1. Category:Wichita, KS | Open Energy Information

    Open Energy Info (EERE)

    Wichita KS ... 64 KB SVLargeHotel Wichita KS Westar Energy Inc.png SVLargeHotel Wichita K... 59 KB SVLargeOffice Wichita KS Westar Energy Inc.png SVLargeOffice Wichita ... 64 KB...

  2. Category:Goodland, KS | Open Energy Information

    Open Energy Info (EERE)

    KS Jump to: navigation, search Go Back to PV Economics By Location Media in category "Goodland, KS" The following 16 files are in this category, out of 16 total....

  3. Mo-99

    National Nuclear Security Administration (NNSA)

    its project for domestic production of molybdenum-99 (Mo-99) without highly enriched uranium (HEU).

    Mo-99 is the parent isotope of technetium-99m, which is the most widely...

  4. DOE - Office of Legacy Management -- Spencer Chemical Co - KS 0-01

    Office of Legacy Management (LM)

    KS 0-01 FUSRAP Considered Sites Site: SPENCER CHEMICAL CO. (KS.0-01 ) Eliminated from further consideration under FUSRAP - an AEC licensed operation Designated Name: Not Designated Alternate Name: Jayhawk Works KS.0-01-1 Location: Pittsburg , Kansas KS.0-01-1 Evaluation Year: 1985 KS.0-01-2 Site Operations: Processed enriched uranium (UF-6) and scrap to produce primarily uranium dioxide (UO-2) under AEC licenses. KS.0-01-3 KS.0-01-4 Site Disposition: Eliminated - No Authority - AEC licensed

  5. Climate Action Champions: Mid-America Regional Council, KS and MO

    Broader source: Energy.gov [DOE]

    In 2008, the MARC  Board of Directors adopted a vision of sustainability, helping to guide the agency’s mission of fostering regional cooperation to solve problems that cannot be solved by a single...

  6. Mo-99

    National Nuclear Security Administration (NNSA)

    NorthStar Medical Radioisotopes to further develop its technology to produce Mo-99 via neutron capture, bringing the total NNSA support to this project to the maximum of 25...

  7. Control of Well KS-8 in the Kilauea Lower East Rift Zone | Open...

    Open Energy Info (EERE)

    Control of Well KS-8 in the Kilauea Lower East Rift Zone Jump to: navigation, search OpenEI Reference LibraryAdd to library Conference Paper: Control of Well KS-8 in the Kilauea...

  8. MO: ZL

    Office of Legacy Management (LM)

    II , --fsi2L /~YlO MO: ZL W./O -1 ;3UN 2 2 1984 DeLanr 6/W/f. NE-20 -24 Authorization for Remedial Action at the Seaway Industrial Park and Ashland 0 1 Co. (I) Sites at Tonawanda, 9 NY, and Mallinckrodt Chemical Co., St. Louis, MO Ba 1s J. LaGrone, Eianager Oak Ridge Operations Office 6/20/E We have determined that the subject sites are contaminated with residual NE-20 radioactive material as a result of the Manhattan Engineer District/Atomic ,/"/1. EnergyXommission operations at those

  9. Mt Poso Cogeneration | Open Energy Information

    Open Energy Info (EERE)

    Poso Cogeneration Jump to: navigation, search Name: Mt Poso Cogeneration Place: Bakersfield, California Zip: 93308 Product: California-based project developer for the Mt Poso...

  10. Mt. Baker Geothermal Project | Open Energy Information

    Open Energy Info (EERE)

    Mt. Baker Geothermal Project Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Development Project: Mt. Baker Geothermal Project Project Location Information Coordinates...

  11. Category:Billings, MT | Open Energy Information

    Open Energy Info (EERE)

    Billings, MT Jump to: navigation, search Go Back to PV Economics By Location Media in category "Billings, MT" The following 16 files are in this category, out of 16 total....

  12. File:USDA-CE-Production-GIFmaps-KS.pdf | Open Energy Information

    Open Energy Info (EERE)

    KS.pdf Jump to: navigation, search File File history File usage Kansas Ethanol Plant Locations Size of this preview: 776 600 pixels. Full resolution (1,650 1,275 pixels,...

  13. EV Community Readiness projects: Delaware Valley Regional Planning Commission (PA); Metropolitan Energy Information Center, Inc. (KS, MO)

    Broader source: Energy.gov [DOE]

    2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  14. Basin Play State(s) Production Reserves Williston Bakken ND, MT, SD

    Gasoline and Diesel Fuel Update (EIA)

    tight oil plays: production and proved reserves, 2013-14 million barrels 2013 2013 Basin Play State(s) Production Reserves Williston Bakken ND, MT, SD 270 4,844 387 5,972 1,128 Western Gulf Eagle Ford TX 351 4,177 497 5,172 995 Permian Bone Spring, Wolfcamp NM, TX 21 335 53 722 387 Denver-Julesberg Niobrara CO, KS, NE, WY 2 17 42 512 495 Appalachian Marcellus* PA, WV 7 89 13 232 143 Fort Worth Barnett TX 9 58 9 47 -11 Sub-total 660 9,520 1,001 12,657 3,137 Other tight oil 41 523 56 708 185 U.S.

  15. Geothermal Literature Review At Mt Ranier Area (Frank, 1995)...

    Open Energy Info (EERE)

    navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geothermal Literature Review At Mt Ranier Area (Frank, 1995) Exploration Activity Details Location Mt...

  16. Water Sampling At Mt Ranier Area (Frank, 1995) | Open Energy...

    Open Energy Info (EERE)

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Water Sampling At Mt Ranier Area (Frank, 1995) Exploration Activity Details Location Mt...

  17. Isotopic Analysis At Mt St Helens Area (Shevenell & Goff, 2000...

    Open Energy Info (EERE)

    Home Exploration Activity: Isotopic Analysis At Mt St Helens Area (Shevenell & Goff, 2000) Exploration Activity Details Location Mt St Helens Area Exploration Technique...

  18. Compound and Elemental Analysis At Mt St Helens Area (Shevenell...

    Open Energy Info (EERE)

    Exploration Activity: Compound and Elemental Analysis At Mt St Helens Area (Shevenell & Goff, 2000) Exploration Activity Details Location Mt St Helens Area Exploration Technique...

  19. Isotopic Analysis At Mt St Helens Area (Shevenell & Goff, 1995...

    Open Energy Info (EERE)

    Home Exploration Activity: Isotopic Analysis At Mt St Helens Area (Shevenell & Goff, 1995) Exploration Activity Details Location Mt St Helens Area Exploration Technique...

  20. Compound and Elemental Analysis At Mt St Helens Area (Shevenell...

    Open Energy Info (EERE)

    Exploration Activity: Compound and Elemental Analysis At Mt St Helens Area (Shevenell & Goff, 1995) Exploration Activity Details Location Mt St Helens Area Exploration Technique...

  1. Controlled Source Audio MT At Roosevelt Hot Springs Area (Combs...

    Open Energy Info (EERE)

    Audio MT At Roosevelt Hot Springs Area (Combs 2006) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Controlled Source Audio MT At Roosevelt Hot...

  2. Mt Wheeler Power, Inc | Open Energy Information

    Open Energy Info (EERE)

    Power, Inc Jump to: navigation, search Name: Mt Wheeler Power, Inc Place: Nevada Phone Number: 1-775-289-8981 Website: mwpower.net Facebook: https:www.facebook.com...

  3. NREL Helps Greensburg, KS Launch GreenHome Partnership - News Releases |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NREL Helps Greensburg, KS Launch GreenHome Partnership KBIA's partnership with Greensburg is a model for communities needing to rebuild April 28, 2009 The U.S. Department of Energy's (DOE) National Renewable Energy Laboratory (NREL), in collaboration with the City Council of Greensburg, Kansas, and the Kansas Building Industry Association (KBIA), announce the launch of Greensburg GreenHome Residential Green Building Program. Greensburg GreenHome is a voluntary program with KBIA and supported

  4. Mt Wheeler Power, Inc (Utah) | Open Energy Information

    Open Energy Info (EERE)

    Mt Wheeler Power, Inc (Utah) Jump to: navigation, search Name: Mt Wheeler Power, Inc Place: Utah Phone Number: 1 775-289-8981 Website: mwpower.net Facebook: https:...

  5. RAPID/Roadmap/18-MT-a | Open Energy Information

    Open Energy Info (EERE)

    Bulk Transmission Geothermal Hydropower Solar Tools Contribute Contact Us Underground Storage Tank Permit (18-MT-a) A developer must obtain an Underground Storage Tank...

  6. Mt Princeton Hot Springs Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    in the area. Since 2007 Mt. Princeton Geothermal, LLC has been assessing the area for its geothermal energy production potential. The company has conducted several preliminary...

  7. Targeting Mycobacterium tuberculosis Biotin Protein Ligase (MtBPL...

    Office of Scientific and Technical Information (OSTI)

    Protein Ligase (MtBPL) with Nucleoside-Based Bisubstrate Adenylation Inhibitors Citation Details In-Document Search Title: Targeting Mycobacterium tuberculosis Biotin Protein ...

  8. RAPID/Roadmap/12-MT-a | Open Energy Information

    Open Energy Info (EERE)

    not in range. Flowchart Narrative 12-MT-a.1 - Consult Regarding Potential Impacts on Fish and Wildlife Building with Wildlife, a guide developed by private landowners,...

  9. Refraction Survey At Mt Princeton Hot Springs Geothermal Area...

    Open Energy Info (EERE)

    Location Mt Princeton Hot Springs Geothermal Area Exploration Technique Refraction Survey Activity Date 2012 - 2012 Usefulness useful DOE-funding Unknown Exploration Basis...

  10. Aeromagnetic Survey At Mt Princeton Hot Springs Geothermal Area...

    Open Energy Info (EERE)

    Princeton Hot Springs Geothermal Area (Case, Et Al., 1984) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Aeromagnetic Survey At Mt Princeton...

  11. RAPID/Roadmap/1-MT-a | Open Energy Information

    Open Energy Info (EERE)

    RAPIDRoadmap1-MT-a < RAPID | Roadmap Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About Bulk Transmission Geothermal Hydropower...

  12. RAPID/Roadmap/11-MT-c | Open Energy Information

    Open Energy Info (EERE)

    RAPIDRoadmap11-MT-c < RAPID | Roadmap Jump to: navigation, search RAPID Regulatory and Permitting Information Desktop Toolkit BETA About Bulk Transmission Geothermal...

  13. Vertical Electrical Sounding Configurations At Mt Princeton Hot...

    Open Energy Info (EERE)

    navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Vertical Electrical Sounding Configurations At Mt Princeton Hot Springs Geothermal Area (Zohdy, Et Al.,...

  14. Water Sampling At Mt Princeton Hot Springs Geothermal Area (Olson...

    Open Energy Info (EERE)

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Water Sampling At Mt Princeton Hot Springs Geothermal Area (Olson & Dellechaie, 1976)...

  15. Water Sampling At Mt St Helens Area (Shevenell & Goff, 1995)...

    Open Energy Info (EERE)

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Water Sampling At Mt St Helens Area (Shevenell & Goff, 1995) Exploration Activity Details...

  16. Geothermometry At Mt St Helens Area (Shevenell & Goff, 1995)...

    Open Energy Info (EERE)

    St Helens Area (Shevenell & Goff, 1995) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geothermometry At Mt St Helens Area (Shevenell & Goff,...

  17. 3D Mt Resistivity Imaging For Geothermal Resource Assessment...

    Open Energy Info (EERE)

    Mt Resistivity Imaging For Geothermal Resource Assessment And Environmental Mitigation At The Glass Mountain Kgra, California Jump to: navigation, search OpenEI Reference...

  18. RAPID/Roadmap/20-MT-a | Open Energy Information

    Open Energy Info (EERE)

    Us Well Abandonment Process (20-MT-a) Montana requires the employment of particular engineering standards when abandoning wells. Developers may elect to abandon wells or...

  19. City of Mt Pleasant, Iowa (Utility Company) | Open Energy Information

    Open Energy Info (EERE)

    Number: (319) 385-2121 Website: mountpleasantiowa.orgalliance Twitter: @MtPleasantIOWA Facebook: https:www.facebook.commountpleasantia Outage Hotline: (319) 385-2121...

  20. Magnetotelluric Techniques At Mt Princeton Hot Springs Geothermal...

    Open Energy Info (EERE)

    Techniques At Mt Princeton Hot Springs Geothermal Area (Held & Henderson, 2012) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Magnetotelluric...

  1. RAPID/Roadmap/14-MT-e | Open Energy Information

    Open Energy Info (EERE)

    Geothermal Hydropower Solar Tools Contribute Contact Us Groundwater Pollution Control System (14-MT-e) The Montana Department of Environmental Quality (DEQ) regulates the...

  2. RAPID/Roadmap/14-MT-c | Open Energy Information

    Open Energy Info (EERE)

    Geothermal Hydropower Solar Tools Contribute Contact Us Underground Injection Control Permit (14-MT-c) The United States Environmental Protection Agency (EPA) has not...

  3. RAPID/Roadmap/3-MT-c | Open Energy Information

    Open Energy Info (EERE)

    Permitting Information Desktop Toolkit BETA About Bulk Transmission Geothermal Hydropower Solar Tools Contribute Contact Us State Encroachment Process (3-MT-c) There are several...

  4. RAPID/Roadmap/11-MT-a | Open Energy Information

    Open Energy Info (EERE)

    Permitting Information Desktop Toolkit BETA About Bulk Transmission Geothermal Hydropower Solar Tools Contribute Contact Us State Cultural Considerations Overview (11-MT-a)...

  5. RAPID/Roadmap/6-MT-d | Open Energy Information

    Open Energy Info (EERE)

    Permitting Information Desktop Toolkit BETA About Bulk Transmission Geothermal Hydropower Solar Tools Contribute Contact Us Other State Construction Permits (6-MT-d)...

  6. RAPID/Roadmap/4-MT-a | Open Energy Information

    Open Energy Info (EERE)

    Permitting Information Desktop Toolkit BETA About Bulk Transmission Geothermal Hydropower Solar Tools Contribute Contact Us State Exploration Process (4-MT-a) 04MTAStateExploration...

  7. RAPID/Roadmap/11-MT-b | Open Energy Information

    Open Energy Info (EERE)

    Permitting Information Desktop Toolkit BETA About Bulk Transmission Geothermal Hydropower Solar Tools Contribute Contact Us Human Remains Process (11-MT-b) 11MTBHumanRemainsProcess...

  8. RAPID/Roadmap/14-MT-d | Open Energy Information

    Open Energy Info (EERE)

    Permitting Information Desktop Toolkit BETA About Bulk Transmission Geothermal Hydropower Solar Tools Contribute Contact Us 401 Water Quality Certification (14-MT-d) A person may...

  9. Analysis of borehole temperature data from the Mt. Princeton...

    Open Energy Info (EERE)

    borehole temperature data from the Mt. Princeton Hot Springs area, Chaffee County, Colorado (abstract only) Jump to: navigation, search OpenEI Reference LibraryAdd to library...

  10. RAPID/Roadmap/15-MT-a | Open Energy Information

    Open Energy Info (EERE)

    BETA About Bulk Transmission Geothermal Hydropower Solar Tools Contribute Contact Us Air Quality Permit (15-MT-a) The Montana Department of Environmental Quality (DEQ)...

  11. Thermal Gradient Holes At Mt Princeton Hot Springs Geothermal...

    Open Energy Info (EERE)

    Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Thermal Gradient Holes At Mt Princeton Hot Springs Geothermal Area (Held & Henderson, 2012)...

  12. RAPID/Roadmap/5-MT-a | Open Energy Information

    Open Energy Info (EERE)

    Geothermal Hydropower Solar Tools Contribute Contact Us Drilling and Well Development (5-MT-a) - 05MTADrillingAndWellDevelopment (1).pdf Error creating thumbnail: Page number...

  13. RAPID/Roadmap/18-MT-b | Open Energy Information

    Open Energy Info (EERE)

    Bulk Transmission Geothermal Hydropower Solar Tools Contribute Contact Us Hazardous Waste Facility Permit (18-MT-b) The Montana Department of Environmental Quality (DEQ)...

  14. Controlled Source Audio MT At Cove Fort Area - Liquid (Combs...

    Open Energy Info (EERE)

    search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Controlled Source Audio MT At Cove Fort Area - Liquid (Combs 2006) Exploration Activity Details Location Cove...

  15. Controlled Source Audio MT At Mccoy Geothermal Area (DOE GTP...

    Open Energy Info (EERE)

    search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Controlled Source Audio MT At Mccoy Geothermal Area (DOE GTP) Exploration Activity Details Location Mccoy...

  16. US WNC MO Site Consumption

    U.S. Energy Information Administration (EIA) Indexed Site

    WNC MO Site Consumption million Btu $0 $500 $1,000 $1,500 $2,000 $2,500 US WNC MO Expenditures dollars ALL ENERGY average per household (excl. transportation) 0 3,000 6,000 9,000 12,000 15,000 US WNC MO Site Consumption kilowatthours $0 $300 $600 $900 $1,200 $1,500 US WNC MO Expenditures dollars ELECTRICITY ONLY average per household * Missouri households consume an average of 100 million Btu per year, 12% more than the U.S. average. * Average household energy costs in Missouri are slightly less

  17. WPA Omnibus Award MT Wind Power Outreach

    SciTech Connect (OSTI)

    Brian Spangler, Manager Energy Planning and Renewables

    2012-01-30

    The objective of this grant was to further the development of Montana??s vast wind resources for small, medium, and large scale benefits to Montana and the nation. This was accomplished through collaborative work with wind industry representatives, state and local governments, the agricultural community, and interested citizens. Through these efforts MT Dept Environmental Quality (DEQ) was able to identify development barriers, educate and inform citizens, as well as to participate in regional and national dialogue that will spur the development of wind resources. The scope of DEQ??s wind outreach effort evolved over the course of this agreement from the development of the Montana Wind Working Group and traditional outreach efforts, to the current focus on working with the state??s university system to deliver a workforce trained to enter the wind industry.

  18. Effects of finite volume on the KL – KS mass difference

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Christ, N.  H.; Feng, X.; Martinelli, G.; Sachrajda, C.  T.

    2015-06-24

    Phenomena that involve two or more on-shell particles are particularly sensitive to the effects of finite volume and require special treatment when computed using lattice QCD. In this paper we generalize the results of Lüscher and Lellouch and Lüscher, which determine the leading-order effects of finite volume on the two-particle spectrum and two-particle decay amplitudes to determine the finite-volume effects in the second-order mixing of the K⁰ and K⁰⁻ states. We extend the methods of Kim, Sachrajda, and Sharpe to provide a direct, uniform treatment of these three, related, finite-volume corrections. In particular, the leading, finite-volume corrections to the KLmore » – KS mass difference ΔMK and the CP-violating parameter εK are determined, including the potentially large effects which can arise from the near degeneracy of the kaon mass and the energy of a finite-volume, two-pion state.« less

  19. U.S. Energy Information Administration | Annual Energy Outlook...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    OH 1. NE 3. S1 4. S2 5. GF 6. OH 7. EN AL,MS MN,ND,SD IA,NE,MO,KS TX,LA,OK,AR MT,WY,ID CO,UT,NV AZ,NM 9. AM 11. C2 12. WS 13. MT 14. CU 15. ZN WV,MD,DC,DE 2. YP...

  20. US WNC MO Site Consumption

    Gasoline and Diesel Fuel Update (EIA)

    in the South than those in the Midwest. 0% 20% 40% 60% 80% 100% US WNC MO OtherNone Propane Electricity Natural Gas MAIN HEATING FUEL USED COOLING EQUIPMENT USED DIVISION:...

  1. HERO Ski Trip to Mt. Hood Meadows February

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    If there is enough interest, we may be able to charter a bus to drive us up and back. Stay at the Best Western Plus Hood River Inn which is just 30 miles from Mt. Hood's largest...

  2. RAPID/Roadmap/17-MT-b | Open Energy Information

    Open Energy Info (EERE)

    Stream Protection Act (SPA 124 Permit) (17-MT-b) Montana has a policy to preserve fish and wildlife habitat as well as maintain Montana's streams and rivers in their natural...

  3. RAPID/Roadmap/13-MT-a | Open Energy Information

    Open Energy Info (EERE)

    Contribute Contact Us State Land Use Assessment (13-MT-a) 13MTALandUseAssessment.pdf Error creating thumbnail: Page number not in range. Error creating thumbnail: Page number...

  4. RAPID/Roadmap/3-MT-b | Open Energy Information

    Open Energy Info (EERE)

    Tools Contribute Contact Us State Land Lease (3-MT-b) 03MTBStateLandAccess (1).pdf Error creating thumbnail: Page number not in range. Error creating thumbnail: Page number...

  5. RAPID/Roadmap/6-MT-c | Open Energy Information

    Open Energy Info (EERE)

    Contact Us Drinking Water Permit (6-MT-c) Add Text 06MTCDrinkingWaterPermit.pdf Error creating thumbnail: Page number not in range. Error creating thumbnail: Page number...

  6. Ground Gravity Survey At Mt Princeton Hot Springs Geothermal...

    Open Energy Info (EERE)

    lithologic distrubtions Notes Gravity low associated with Mt. Princeton Batholith; density contrast of -0.5 gcm3 of valley-fill sediments relative to batholith References J.E....

  7. RAPID/Roadmap/3-MT-a | Open Energy Information

    Open Energy Info (EERE)

    Resources & Conservation. The application requires an adequate description of the lands. The application fee is 10. 3-MT-a.2 - Does the Director Decide to Announce the Sale...

  8. MT Energie GmbH Co KG | Open Energy Information

    Open Energy Info (EERE)

    Saxony, Germany Zip: 27404 Sector: Services Product: MT-Energie provides both turn-key biogas plants and related components and services. Coordinates: 53.295765, 9.27964 Show...

  9. Mt. Wachusett Community College Makes Huge Investment in Wind Power |

    Energy Savers [EERE]

    Department of Energy Mt. Wachusett Community College Makes Huge Investment in Wind Power Mt. Wachusett Community College Makes Huge Investment in Wind Power March 14, 2011 - 1:14pm Addthis Mount Wachusett Community College staff Bill Swift, Bob LaBonte, Norm Boudreau, George Couillard and Vestas trainer Bill Fulkerson about to ascend the MWCC north wind turbine | Photo courtesy of GreenOnGreenStreet Mount Wachusett Community College staff Bill Swift, Bob LaBonte, Norm Boudreau, George

  10. Targeting Mycobacterium tuberculosis Biotin Protein Ligase (MtBPL) with

    Office of Scientific and Technical Information (OSTI)

    Nucleoside-Based Bisubstrate Adenylation Inhibitors (Journal Article) | SciTech Connect Targeting Mycobacterium tuberculosis Biotin Protein Ligase (MtBPL) with Nucleoside-Based Bisubstrate Adenylation Inhibitors Citation Details In-Document Search Title: Targeting Mycobacterium tuberculosis Biotin Protein Ligase (MtBPL) with Nucleoside-Based Bisubstrate Adenylation Inhibitors Authors: Bockman, Matthew R. ; Kalinda, Alvin S. ; Petrelli, Riccardo ; De la Mora-Rey, Teresa ; Tiwari, Divya ; Liu,

  11. DOE - Office of Legacy Management -- St Louis Airport - MO 01

    Office of Legacy Management (LM)

    Airport - MO 01 FUSRAP Considered Sites St. Louis Airport, MO Alternate Name(s): Airport Site St. Louis Airport Storage Site (SLAPS) Former Robertson Storage Area Robertson Airport MO.01-1 MO.01-2 Location: Brown Road, Robertson, Missouri MO.01-2 Historical Operations: Stored uranium process residues containing uranium, radium, and thorium for the MED and AEC. MO.01-2 MO.01-3 MO.01-4 Eligibility Determination: Eligible MO.01-1 MO.01-7 Radiological Survey(s): Assessment Surveys MO.01-4 MO.01-5

  12. Observation of a narrow structure in 1H(?,KS0)X via interference with phi-meson production

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Amaryan, M J; Nepali, C; Polyakov, M V; Azimov, Ya; Briscoe, W J; Dodge, G E; Hyde, C E; Klein, F; Kuznetsov, V; Strakovsky, I

    2012-03-21

    We report observation of a narrow peak structure at ?1.54 GeV with a Gaussian width ? = 6 MeV in the missing mass of KS in the reaction ? + p ? pKSKL. The observed structure may be due to the interference between a strange (or antistrange) baryon resonance in the pKL system and the ?(KSKL) photoproduction leading to the same final state. The statistical significance of the observed excess of events estimated as the log-likelihood ratio of the resonant signal + background hypothesis and the ?-production-based background-only hypothesis corresponds to 5.3?.

  13. Observation of a narrow structure in 1 H( γ , KS0 ) X via interference with φ -meson production

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Amaryan, M. J.; Gavalian, G.; Nepali, C.; Polyakov, M. V.; Azimov, Ya.; Briscoe, W. J.; Dodge, G. E.; Hyde, C. E.; Klein, F.; Kuznetsov, V.; et al

    2012-03-01

    We report observation of a narrow peak structure at ≈1.54 GeV with a Gaussian width σ = 6 MeV in the missing mass of KS in the reaction γ + p → pKSKL. The observed structure may be due to the interference between a strange (or antistrange) baryon resonance in the pKL system and the φ(KSKL) photoproduction leading to the same final state. The statistical significance of the observed excess of events estimated as the log-likelihood ratio of the resonant signal + background hypothesis and the φ-production-based background-only hypothesis corresponds to 5.3σ.

  14. SSL Demonstration: Street Lighting, Kansas City, MO

    SciTech Connect (OSTI)

    2013-08-01

    GATEWAY program report brief summarizing an SSL street lighting demonstration at nine separate installations in Kansas City, MO.

  15. 3-D Density Model Of Mt Etna Volcano (Southern Italy) | Open...

    Open Energy Info (EERE)

    Density Model Of Mt Etna Volcano (Southern Italy) Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: 3-D Density Model Of Mt Etna Volcano (Southern...

  16. Www.deq.mt.gov/MFS/LawRules/Circular2 | Open Energy Information

    Open Energy Info (EERE)

    Www.deq.mt.govMFSLawRulesCircular2 Jump to: navigation, search OpenEI Reference LibraryAdd to library Reference: Www.deq.mt.govMFSLawRulesCircular2 Published Publisher Not...

  17. DOE - Office of Legacy Management -- Washington University - MO 07

    Office of Legacy Management (LM)

    Washington University - MO 07 FUSRAP Considered Sites Site: WASHINGTON UNIVERSITY (MO.07 ) Eliminated from consideration under FUSRAP Designated Name: Not Designated Alternate Name: None Location: St. Louis , Missouri MO.07-1 Evaluation Year: 1987 MO.07-1 Site Operations: Activities were limited to programs involving relatively small quantities of radionuclides and chemicals in a controlled environment. MO.07-3 MO.07-1 Site Disposition: Eliminated - Potential for contamination remote MO.07-1

  18. DOE - Office of Legacy Management -- Latty Avenue Site - MO 04

    Office of Legacy Management (LM)

    Latty Avenue Site - MO 04 FUSRAP Considered Sites Latty Avenue Site, MO Alternate Name(s): Futura Coatings Futura Chemical Company Facility Hazelwood Interim Storage Site (HISS) Former Cotter Site, Latty Avenue Properties Contemporary Metals Corp. Continental Mining and Milling MO.04-1 MO.04-2 MO.04-5 MO.04-6 MO.06-8 MO.06-11 Location: 9200 Latty Avenue, Hazelwood, Missouri MO.04-1 Historical Operations: Received, stored, and processed uranium residues for the AEC. Storage and processing were

  19. Mo99 Production Plant Layout

    SciTech Connect (OSTI)

    Woloshun, Keith Albert; Dale, Gregory E.; Naranjo, Angela Carol

    2015-06-25

    The NorthStar Medical Technologies 99Mo production facility configuration is envisioned to be 8 accelerator pairs irradiating 7 100Mo targets (one spare accelerator pair undergoing maintenance while the other 7 pairs are irradiating targets). The required shielding in every direction for the accelerators is initially estimated to be 10 feet of concrete. With the accelerator pairs on one (ground) level and spaced with the required shielding between adjacent pairs, the only practical path for target insertion and removal while minimizing floor space is vertical. The current scheme then requires a target vertical lift of nominally 10 feet through a shield stack. It is envisioned that the lift will be directly into a hot cell where an activated target can be removed from its holder and a new target attached and lowered. The hot cell is on a rail system so that a single hot cell can service all active target locations, as well as deliver the ready targets to the separations lab. On this rail system, coupled to the hot cell, will be a helium recovery and clean-up system. All helium coolant equipment is located on the upper level near to the target removal point.

  20. DOE - Office of Legacy Management -- Petrolite Corp - MO 08

    Office of Legacy Management (LM)

    Petrolite Corp - MO 08 FUSRAP Considered Sites Site: PETROLITE CORP (MO.08) Eliminated from further consideration under FUSRAP Designated Name: Not Designated Alternate Name: None Location: St. Louis , Missouri MO.08-1 Evaluation Year: 1987 MO.08-4 Site Operations: Research involving test quantities of radioactive materials. MO.08-2 Site Disposition: Eliminated - Licensed - Potential for contamination remote MO.08-3 Radioactive Materials Handled: Yes Primary Radioactive Materials Handled:

  1. Missouri Department of National Resources Energy Center Mo DNR...

    Open Energy Info (EERE)

    Department of National Resources Energy Center Mo DNR Jump to: navigation, search Name: Missouri Department of National Resources Energy Center (Mo DNR) Place: Jefferson City,...

  2. Demonstration of LED Street Lighting in Kansas City, MO (Technical...

    Office of Scientific and Technical Information (OSTI)

    Report: Demonstration of LED Street Lighting in Kansas City, MO Citation Details In-Document Search Title: Demonstration of LED Street Lighting in Kansas City, MO Nine different ...

  3. CONTINUED COOLING OF THE CRUST IN THE NEUTRON STAR LOW-MASS X-RAY BINARY KS 1731-260

    SciTech Connect (OSTI)

    Cackett, Edward M.; Miller, Jon M.; Brown, Edward F.; Cumming, Andrew; Degenaar, Nathalie; Wijnands, Rudy

    2010-10-20

    Some neutron star low-mass X-ray binaries have very long outbursts (lasting several years) which can generate a significant amount of heat in the neutron star crust. After the system has returned to quiescence, the crust then thermally relaxes. This provides a rare opportunity to study the thermal properties of neutron star crusts, putting constraints on the thermal conductivity and hence the structure and composition of the crust. KS 1731-260 is one of only four systems where this crustal cooling has been observed. Here, we present a new Chandra observation of this source approximately eight years after the end of the last outburst and four years since the last observation. We find that the source has continued to cool, with the cooling curve displaying a simple power-law decay. This suggests that the crust has not fully thermally relaxed yet and may continue to cool further. A simple power-law decay is in contrast to theoretical cooling models of the crust, which predict that the crust should now have cooled to the same temperature as the neutron star core.

  4. Sweetgrass, MT Liquefied Natural Gas Pipeline Exports to Canada (Million

    U.S. Energy Information Administration (EIA) Indexed Site

    Cubic Feet) Liquefied Natural Gas Pipeline Exports to Canada (Million Cubic Feet) Sweetgrass, MT Liquefied Natural Gas Pipeline Exports to Canada (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2012 2 2013 3 5 4 6 9 8 5 8 7 5 7 5 2014 8 11 10 8 8 5 6 6 6 6 6 7 2015 5 4 5 5 5 4 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 02/29/2016 Next Release Date: 03/31/2016 Referring

  5. F-1 U.S. Energy Information Administration | Annual Energy Outlook...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Central West North Central East North Central Mountain AK WA MT WY ID NV UT CO AZ NM TX OK IA KS MO IL IN KY TN MS AL FL GA SC NC WV PA NJ MD DE NY CT VT ME RI MA NH VA WI MI OH...

  6. F-5 U.S. Energy Information Administration | Annual Energy Outlook...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Figure F4. Oil and Gas Supply Model Regions Atlantic WA MT WY ID NV UT CO AZ NM TX OK IA KS MO IL IN KY TN MS AL FL GA SC NC WV PA NJ MD DE NY CT ME RI MA NH VA WI MI OH NE...

  7. Rock Sampling At Mt Ranier Area (Frank, 1995) | Open Energy Informatio...

    Open Energy Info (EERE)

    Exploration Activity Details Location Mt Ranier Area Exploration Technique Rock Sampling Activity Date Usefulness not indicated DOE-funding Unknown Notes This paper relies...

  8. Controlled Source Audio MT At Pilgrim Hot Springs Area (DOE GTP...

    Open Energy Info (EERE)

    search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Controlled Source Audio MT At Pilgrim Hot Springs Area (DOE GTP) Exploration Activity Details Location Pilgrim...

  9. Release on M&O Selection Final

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Federal Services LLC, of Bethesda, Maryland) has been awarded a 1.3 billion contract for management and operating (M&O) at DOE's Waste Isolation Pilot Plant (WIPP) in Carlsbad,...

  10. BWXT Pantex, LLC Route 726, Mt. Athos Road

    National Nuclear Security Administration (NNSA)

    9B. DATED (SEE E M 11) I 1 DE-ACO4-OOALO6020 10s. DATED (SEE ITEM 13) I . CONTRACT ID CODE PAGE I OF 2 PAGES 2. AMENDMENT/MODlFlCATlON NO. MO99 Offers must acknowledge receipt of this amendment priw to the hour and date specifid in the solicitation a s amended. by one of the fdlovving methods: (a) By completing Items 8 and 15, and returning - copies of the amendmmS (b) By acknwuledglng receipt of this amendment on each oopy of the offer submitted; or (c) By separate letttx or tdegram which

  11. Elevated Temperature Tensile Tests on DU10Mo Rolled Foils

    SciTech Connect (OSTI)

    Schulthess, Jason

    2014-09-01

    Tensile mechanical properties for uranium-10 wt.% molybdenum (U10Mo) foils are required to support modeling and qualification of new monolithic fuel plate designs. It is expected that depleted uranium-10 wt% Mo (DU10Mo) mechanical behavior is representative of the low enriched U10Mo to be used in the actual fuel plates, therefore DU-10Mo was studied to simplify material processing, handling, and testing requirements. In this report, tensile testing of DU-10Mo fuel foils prepared using four different thermomechanical processing treatments were conducted to assess the impact of foil fabrication history on resultant tensile properties.

  12. Oxidation, Reduction, and Condensation of Alcohols over (MO3)3 (M=Mo, W) Nanoclusters

    SciTech Connect (OSTI)

    Fang, Zongtang; Li, Zhenjun; Kelley, Matthew S.; Kay, Bruce D.; Li, Shenggang; Hennigan, Jamie M.; Rousseau, Roger J.; Dohnalek, Zdenek; Dixon, David A.

    2014-10-02

    The reactions of deuterated methanol, ethanol, 1-propanol, 1-butanol, 2-propanol, 2-butanol and t-butanol over cyclic (MO3)3 (M = Mo, W) clusters were studied experimentally with temperature programmed desorption (TPD) and theoretically with coupled cluster CCSD(T) theory and density functional theory. The reactions of two alcohols per M3O9 cluster are required to provide agreement with experiment for D2O release, dehydrogenation and dehydration. The reaction begins with the elimination of water by proton transfers and forms an intermediate dialkoxy species which can undergo further reaction. Dehydration proceeds by a ? hydrogen transfer to a terminal M=O. Dehydrogenation takes place via an ? hydrogen transfer to an adjacent MoVI = O atom or a WVI metal center with redox involved for M = Mo and no redox for M = W. The two channels have comparable activation energies. H/D exchange to produce alcohols can take place after olefin is released or via the dialkoxy species depending on the alcohol and the cluster. The Lewis acidity of the metal center with WVI being larger than MoVI results in the increased reactivity of W3O9 over Mo3O9 for dehydrogenation and dehydration.

  13. Accelerator Production Options for 99MO

    SciTech Connect (OSTI)

    Bertsche, Kirk; /SLAC

    2010-08-25

    Shortages of {sup 99}Mo, the most commonly used diagnostic medical isotope, have caused great concern and have prompted numerous suggestions for alternate production methods. A wide variety of accelerator-based approaches have been suggested. In this paper we survey and compare the various accelerator-based approaches.

  14. MOED_of_the_Italian_Republic.PDF | Department of Energy

    Office of Environmental Management (EM)

    MOED_of_the_Italian_Republic.PDF MOED_of_the_Italian_Republic.PDF PDF icon MOED_of_the_Italian_Republic.PDF More Documents & Publications Scanned_Agreement.pdf International_Agreements_January_2001_December_2004.pdf Implementing Arrangement Between DOE and METI on R&D Cooperation on Clean Energy Technology - April 2015

  15. A Large Self-Potential Anomaly And Its Changes On The Quiet Mt...

    Open Energy Info (EERE)

    Large Self-Potential Anomaly And Its Changes On The Quiet Mt Fuji, Japan Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: A Large Self-Potential...

  16. Role of SrMoO{sub 4} in Sr{sub 2}MgMoO{sub 6} synthesis

    SciTech Connect (OSTI)

    Vasala, S.; Yamauchi, H.; Karppinen, M.

    2011-05-15

    Here we investigate the elemental and phase compositions during the solid-state synthesis of the promising SOFC-anode material, Sr{sub 2}MgMoO{sub 6}, and demonstrate that molybdenum does not notably evaporate under the normal synthesis conditions with temperatures up to 1200 {sup o}C due to the formation of SrMoO{sub 4} as an intermediate product at low temperatures, below 600 {sup o}C. However, partial decomposition of the Sr{sub 2}MgMoO{sub 6} phase becomes evident at the higher temperatures ({approx}1500 {sup o}C). The effect of SrMoO{sub 4} on the electrical conductivity of Sr{sub 2}MgMoO{sub 6} is evaluated by preparing a series of Sr{sub 2}MgMoO{sub 6} samples with different amounts of additional SrMoO{sub 4}. Under the reducing operation conditions of an SOFC anode the insulating SrMoO{sub 4} phase is apparently reduced to the highly conductive SrMoO{sub 3} phase. Percolation takes place with 20-30 wt% of SrMoO{sub 4} in a Sr{sub 2}MgMoO{sub 6} matrix, with a notable increase in electrical conductivity after reduction. Conductivity values of 14, 60 and 160 S/cm are determined at 800 {sup o}C in 5% H{sub 2}/Ar for the Sr{sub 2}MgMoO{sub 6} samples with 30, 40 and 50 wt% of added SrMoO{sub 4}, respectively. -- Graphical abstract: SrMoO{sub 4} is formed at low temperatures during the synthesis of Sr{sub 2}MgMoO{sub 6}, which prevents the volatilization of Mo from typical precursor mixtures of this promising SOFC anode material. SrMoO{sub 4} is insulating and it is often found as an impurity in Sr{sub 2}MgMoO{sub 6} samples. It is however readily reduced to highly conducting SrMoO{sub 3}. Composites of Sr{sub 2}MgMoO{sub 6} and SrMoO{sub 3} show increased electrical conductivities compared to pure Sr{sub 2}MgMoO{sub 6} under the reductive operation conditions of an SOFC anode. Display Omitted Highlights: {yields} Sr{sub 2}MgMoO{sub 6} is a promising SOFC anode material. {yields} During the Sr{sub 2}MgMoO{sub 6} synthesis SrMoO{sub 4} is formed at low temperatures. {yields} Formation of SrMoO{sub 4} effectively prevents volatilization of Mo at high temperatures. {yields} Insulating SrMoO{sub 4} reduces to highly conductive SrMoO{sub 3} under SOFC-anode conditions. {yields} Composites of Sr{sub 2}MgMoO{sub 6} and SrMoO{sub 3} show high electrical conductivities.

  17. DOE - Office of Legacy Management -- St Louis Downtown Site - MO 02

    Office of Legacy Management (LM)

    Downtown Site - MO 02 FUSRAP Considered Sites St. Louis Downtown, MO Alternate Name(s): Destrehan Street Plant Downtown Site Mallinckrodt Chemical Plant Mallinckrodt Chemical Works MO.02-1 MO.02-3 Location: 65 Destrehan Street, St. Louis, Missouri MO.02-5 Historical Operations: Conducted uranium metal and uranium oxides research, development, and production for MED and AEC. MO.02-6 MO.02-7 Eligibility Determination: Eligible MO.02-1 Radiological Survey(s): Assessment Surveys MO.02-2 MO.02-3 Site

  18. Mo-99 | National Nuclear Security Administration

    National Nuclear Security Administration (NNSA)

    Mo-99 | National Nuclear Security Administration Facebook Twitter Youtube Flickr RSS People Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy Emergency Response Recapitalizing Our Infrastructure Countering Nuclear Terrorism About Our Programs Our History Who We Are Our Leadership Our Locations Budget Our Operations Library Bios Congressional Testimony Fact Sheets Newsletters Press Releases Photo Gallery Jobs Apply for Our Jobs Our Jobs Working at NNSA Blog Home /

  19. DOE - Office of Legacy Management -- Rogers Iron Works Co - MO 10

    Office of Legacy Management (LM)

    Rogers Iron Works Co - MO 10 FUSRAP Considered Sites Site: ROGERS IRON WORKS CO. (MO.10 ) Elimination from consideration under FUSRAP Designated Name: Not Designated Alternate Name: Rogers Iron Co. MO.10-1 Location: Joplin , Missouri MO.10-1 Evaluation Year: 1990 MO.10-2 MO.10-3 Site Operations: Tested C-liner crushing methods. MO.10-1 Site Disposition: Eliminated - Potential for contamination considered remote based on limited quantities of material handled MO.10-3 MO.10-4 Radioactive Materials

  20. Demonstration of LED Street Lighting in Kansas City, MO Kinzey...

    Office of Scientific and Technical Information (OSTI)

    Street Lighting in Kansas City, MO Kinzey, Bruce R.; Royer, Michael P.; Hadjian, M.; Kauffman, Rick LED streetlighting; field illuminance measurement LED streetlighting; field...

  1. MoRu/Be multilayers for extreme ultraviolet applications

    DOE Patents [OSTI]

    Bajt, Sasa C. (Livermore, CA); Wall, Mark A. (Stockton, CA)

    2001-01-01

    High reflectance, low intrinsic roughness and low stress multilayer systems for extreme ultraviolet (EUV) lithography comprise amorphous layers MoRu and crystalline Be layers. Reflectance greater than 70% has been demonstrated for MoRu/Be multilayers with 50 bilayer pairs. Optical throughput of MoRu/Be multilayers can be 30-40% higher than that of Mo/Be multilayer coatings. The throughput can be improved using a diffusion barrier to make sharper interfaces. A capping layer on the top surface of the multilayer improves the long-term reflectance and EUV radiation stability of the multilayer by forming a very thin native oxide that is water resistant.

  2. Dynamic Structural Response and Deformations of Monolayer MoS...

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect Search Results Journal Article: Dynamic Structural Response and Deformations of Monolayer MoS 2 Visualized by Femtosecond Electron Diffraction Citation Details ...

  3. Valence and metal/silicate partitioning of Mo: Implications for...

    Office of Scientific and Technical Information (OSTI)

    Valence and metalsilicate partitioning of Mo: Implications for conditions of Earth accretion and core formation Citation Details In-Document Search Title: Valence and metal...

  4. Mo Year Report Period: EIA ID NUMBER:

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mo Year Report Period: EIA ID NUMBER: http://www.eia.gov/survey/form/eia_14/instructions.pdf Mailing Address: Secure File Transfer option available at: (e.g., PO Box, RR) https://signon.eia.doe.gov/upload/noticeoog.jsp Electronic Transmission: The PC Electronic Zip Code - Data Reporting Option (PEDRO) is available. If interested in software, call (202) 586-9659. Email form to: OOG.SURVEYS@eia.doe.gov - - - - Fax form to: (202) 586-9772 Mail form to: Oil & Gas Survey Email address: U.S.

  5. Experiment operations plan for the MT-4 experiment in the NRU reactor. [PWR

    SciTech Connect (OSTI)

    Russcher, G.E.; Wilson, C.L.; Parchen, L.J.; Marshall, R.K.; Hesson, G.M.; Webb, B.J.; Freshley, M.D.

    1983-06-01

    A series of thermal-hydraulic and cladding materials deformation experiments were conducted using light-water reactor fuel bundles as part of the Pacific Northwest Laboratory Loss-of-Coolant Accident (LOCA) Simulation Program. This report is the formal operations plan for MT-4 - the fourth materials deformation experiment conducted in the National Research Universal (NRU) reactor, Chalk River, Ontario, Canada. A major objective of MT-4 was to simulate a pressurized water reactor LOCA that could induce fuel rod cladding deformation and rupture due to a short-term adiabatic transient and a peak fuel cladding temperature of 1200K (1700/sup 0/F).

  6. Structure and electronic properties of Cu nanoclusters supported on Mo2C(001) and MoC(001) surfaces

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Posada-Pérez, Sergio; Viñes, Francesc; Rodríguez, José A.; Illas, Francesc

    2015-09-15

    In this study, the atomic structure and electronic properties of Cun nanoclusters (n = 4, 6, 7, and 10) supported on cubic nonpolar δ-MoC(001) and orthorhombic C- or Mo-terminated polar β-Mo2C(001) surfaces have been investigated by means of periodic density functional theory based calculations. The electronic properties have been analyzed by means of the density of states, Bader charges, and electron localization function plots. The Cu nanoparticles supported on β-Mo2C(001), either Mo- or C-terminated, tend to present a two-dimensional structure whereas a three-dimensional geometry is preferred when supported on δ-MoC(001), indicating that the Mo:C ratio and the surface polarity playmore » a key role determining the structure of supported clusters. Nevertheless, calculations also reveal important differences between the C- and Mo-terminated β-Mo2C(001) supports to the point that supported Cu particles exhibit different charge states, which opens a way to control the reactivity of these potential catalysts.« less

  7. MT71x: Multi-Temperature Library Based on ENDF/B-VII.1

    SciTech Connect (OSTI)

    Conlin, Jeremy Lloyd; Parsons, Donald Kent; Gray, Mark Girard; Lee, Mary Beth; White, Morgan Curtis

    2015-12-16

    The Nuclear Data Team has released a multitemperature transport library, MT71x, based upon ENDF/B-VII.1 with a few modifications as well as additional evaluations for a total of 427 isotope tables. The library was processed using NJOY2012.39 into 23 temperatures. MT71x consists of two sub-libraries; MT71xMG for multigroup energy representation data and MT71xCE for continuous energy representation data. These sub-libraries are suitable for deterministic transport and Monte Carlo transport applications, respectively. The SZAs used are the same for the two sub-libraries; that is, the same SZA can be used for both libraries. This makes comparisons between the two libraries and between deterministic and Monte Carlo codes straightforward. Both the multigroup energy and continuous energy libraries were verified and validated with our checking codes checkmg and checkace (multigroup and continuous energy, respectively) Then an expanded suite of tests was used for additional verification and, finally, verified using an extensive suite of critical benchmark models. We feel that this library is suitable for all calculations and is particularly useful for calculations sensitive to temperature effects.

  8. DOE - Office of Legacy Management -- West Lake Landfill - MO 05

    Office of Legacy Management (LM)

    Lake Landfill - MO 05 FUSRAP Considered Sites Site: West Lake Landfill (MO.05) Designated Name: Alternate Name: Location: Evaluation Year: Site Operations: Site Disposition: Radioactive Materials Handled: Primary Radioactive Materials Handled: Radiological Survey(s): Site Status: Also see http://www.epa.gov/oerrpage/superfund/sites/npl/nar1289.htm Documents Related to West Lake Landfill

  9. Fragile structural transition in Mo3Sb7

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yan, Jiaqiang -Q.; McGuire, Michael A; May, Andrew F; Parker, David S.; Mandrus, D. G.; Sales, Brian C.

    2015-08-10

    Mo3Sb7 single crystals lightly doped with Cr, Ru, or Te are studied in order to explore the interplay between superconductivity, magnetism, and the cubic-tetragonal structural transition. The structural transition at 53 K is extremely sensitive to Ru or Te substitution which introduces additional electrons, but robust against Cr substitution. We observed no sign of a structural transition in superconducting Mo2.91Ru0.09Sb7 and Mo3Sb6.975Te0.025. In contrast, 3 at.% Cr doping only slightly suppresses the structural transition to 48 K while leaving no trace of superconductivity above 1.8 K. Analysis of magnetic properties suggests that the interdimer interaction in Mo3Sb7 is near amorecritical value and essential for the structural transition. Futhermore, all dopants suppress the superconductivity of Mo3Sb7. The tetragonal structure is not necessary for superconductivity.less

  10. Neutrino scattering off the stable even-even Mo isotopes

    SciTech Connect (OSTI)

    Balasi, K. G.; Kosmas, T. S.; Divari, P. C. [Theoretical Physics Section, University of Ioannina, GR 45110 Ioannina (Greece)

    2009-11-09

    Inelastic neutrino-nucleus reaction cross sections are studied focusing on the neutral current processes. Particularly, we investigate the angular and initial neutrino-energy dependence of the differential and integrated cross sections for low and intermediate energies of the incoming neutrino. The nuclear wave functions for the initial and final nuclear states are constructed in the context of the quasi-particle random phase approximation (QRPA) tested on the reproducibility of the low-lying energy spectrum. The results presented here refer to the isotopes Mo{sup 92}, Mo{sup 94}, Mo{sup 96}, Mo{sup 98} and Mo{sup 100}. These isotopes could play a significant role in supernova neutrino detection in addition to their use in double-beta and neutrinoless double-beta decay experiments (e.g. MOON, NEMO III)

  11. DOE - Office of Legacy Management -- United Nuclear Corp - MO 0-03

    Office of Legacy Management (LM)

    Nuclear Corp - MO 0-03 FUSRAP Considered Sites Site: UNITED NUCLEAR CORP. (MO.0-03) Eliminated from further consideration under FUSRAP Designated Name: Not Designated Alternate Name: Mallinckrodt Chemical Works Mallinckrodt Nuclear Corporation MO.0-03-1 MO.0-03-2 Location: Hematite , Missouri MO.0-03-1 Evaluation Year: Circa 1987 MO.0-03-3 Site Operations: Commercial fuel fabrication operation. Licensed to reclaim unirradiated enriched uranium from scrap generated in fuel fabrication and fuel

  12. DOE - Office of Legacy Management -- Spencer Chemical Co - MO 0-01

    Office of Legacy Management (LM)

    MO 0-01 FUSRAP Considered Sites Site: SPENCER CHEMICAL CO. (MO.0-01) Eliminated from further consideration under FUSRAP - an AEC licensed operation Designated Name: Not Designated Alternate Name: Jayhawk Works MO.0-01-1 Location: Joplin , Missouri MO.0-01-1 Evaluation Year: 1985 MO.0-01-2 Site Operations: Processed enriched uranium (UF-6) and scrap to produce primarily uranium dioxide (UO-2) under AEC licenses. MO.0-01-3 MO.0-01-4 Site Disposition: Eliminated - No Authority MO.0-01-2 Radioactive

  13. DOE - Office of Legacy Management -- Tyson Valley Powder Farm - MO 11

    Office of Legacy Management (LM)

    Tyson Valley Powder Farm - MO 11 FUSRAP Considered Sites Site: TYSON VALLEY POWDER FARM (MO.11) Eliminated from further consideration under FUSRAP Designated Name: Not Designated Alternate Name: None Location: St. Louis County , Missouri MO.11-1 Evaluation Year: 1987 MO.11-2 Site Operations: Storage of C-Special material (residue from production of uranium metal). MO.11-1 MO.11-2 MO.11-3 Site Disposition: Eliminated - Referred to Army Corps of Engineers MO.11-2 Radioactive Materials Handled: Yes

  14. SU-E-T-625: Use and Choice of Ionization Chambers for the Commissioning of Flattened and Flattening-Filter-Free Photon Beams: Determination of Recombination Correction Factor (ks)

    SciTech Connect (OSTI)

    Stucchi, C; Mongioj, V; Carrara, M; Pignoli, E; Bonfantini, F; Bresolin, A

    2014-06-15

    Purpose: To evaluate the recombination effect for some ionization chambers to be used for linacs commissioning for Flattened Filter (FF) and Flattening Filter Free (FFF) photon beams. Methods: A Varian TrueBeam linac with five photon beams was used: 6, 10 and 15 MV FF and 6 and 10 MV FFF. Measurements were performed in a water tank and in a plastic water phantom with different chambers: a mini-ion chamber (IC CC01, IBA), a plane-parallel ion chamber (IC PPC05, IBA) and two Farmer chambers (NE2581 and FPC05-IBA). Measurement conditions were Source- Surface Distance of 100 cm, two field sizes (10x10 and 40x40 cm2) and five depths (1cm, maximum buildup, 5cm, 10cm and 20cm). The ion recombination factors (kS), obtained from the Jaffe's plots (voltage interval 50-400 V), were evaluated at the recommended operating voltage of +300V. Results: Dose Per Pulse (DPP) at dmax was 0.4 mGy/pulse for FF beams, 1.0 mGy/pulse and 1.9 mGy/pulse for 6MV and 10 MV FFF beams respectively. For all measurement conditions, kS ranged between 0.996 and 0.999 for IC PPC05, 0.997 and 1.008 for IC CC01. For the FPC05 IBA Farmer IC, kS varied from 1.001 to 1.011 for FF beams, from 1.004 to 1.015 for 6 MV FFF and from 1.009 to 1.025 for 10 MV FFF. Whereas, for NE2581 IC the values ranged from 1.002 to 1.009 for all energy beams and measurement conditions. Conclusion: kS depends on the chamber volume and the DPP, which in turn depends on energy beam but is independent of dose rate. Ion chambers with small active volume can be reliably used for dosimetry of FF and FFF beams even without kS correction. On the contrary, for absolute dosimetry of FFF beams by Farmer ICs it is necessary to evaluate and apply the kS correction. Partially supported by Lega Italiana Lotta contro i Tumori (LILT)

  15. Mo-O bond doping and related-defect assisted enhancement of photoluminescence in monolayer MoS{sub 2}

    SciTech Connect (OSTI)

    Wei, Xiaoxu; Yu, Zhihao; Cheng, Ying; Yu, Linwei; Wang, Junzhuan Wang, Xinran; Shi, Yi; Hu, Fengrui; Wang, Xiaoyong; Xiao, Min

    2014-12-15

    In this work, we report a strong photoluminescence (PL) enhancement of monolayer MoS{sub 2} under different treatments. We find that by simple ambient annealing treatment in the range of 200?C to 400?C, the PL emission can be greatly enhanced by a factor up to two orders of magnitude. This enhancement can be attributed to two factors: first, the formation of Mo-O bonds during ambient exposure introduces an effective p-doping in the MoS{sub 2} layer; second, localized electrons formed around Mo-O bonds related defective sites where the electrons can be effectively localized with higher binding energy resulting in efficient radiative excitons recombination. Time resolved PL decay measurement showed that longer lifetime of the treated sample consistent with the higher quantum efficiency in PL. These results give more insights to understand the luminescence properties of the MoS{sub 2}.

  16. Polystyrene/MoS{sub 2}@oleylamine nanocomposites

    SciTech Connect (OSTI)

    Altavilla, Claudia; Ciambelli, Paolo; Fedi, Filippo; Sorrentino, Andrea; Iannace, Salvatore

    2014-05-15

    The effects of adding different concentrations of MoS{sub 2}@oleylamine nano particles on the thermal and mechanical properties of polystyrene (PS) nanocomposites have been investigated. X-ray diffraction and optical microscopy were used to characterize the morphology of the resulting nanocomposites. The thermal stability of the nanocomposites has been characterized by thermogravimetric analysis. It has been found that the MoS{sub 2}@oleylamine nanoparticles have a good compatibility with the PS matrix forming homogeneous dispersion even at high concentrations. The PS/MoS{sub 2}@oleylamine nanocomposites showed enhanced thermal stability in comparison with neat polystyrene.

  17. Hazard assessment in geothermal exploration: The case of Mt. Parker, Southern Philippines

    SciTech Connect (OSTI)

    Delfin, F.G. Jr.; Salonga, N.D.; Bayon, F.E.B.

    1996-12-31

    Hazard assessment of the Mt. Parker geothermal prospect, conducted in parallel with the surface exploration from 1992 to 1994, was undertaken to determine the long-term suitability of the prospect for development. By comparison with other acidic magmatic-hydrothermal systems in the Philippines, the geochemical data indicated minimal input of acidic magmatic fluids into Mt. Parker`s hydrothermal system. This system was regarded to be a neutral-pH and high-enthalpy chloride reservoir with temperature of at least 200-250{degrees}C. These favorable geochemical indications contrasted sharply with the C-14 and volcanological data indicating a shallow magmatic body with a potential for future eruption. This hazard led PNOC EDC to discontinue the survey and abandon the prospect by late 1994. On September 6, 1995, a flashflood of non-volcanic origin from the caldera lake killed nearly 100 people on the volcano`s northwestern flank.

  18. Babb, MT Liquefied Natural Gas Exports to Canada (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    Liquefied Natural Gas Exports to Canada (Million Cubic Feet) Babb, MT Liquefied Natural Gas Exports to Canada (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2015 5 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 02/29/2016 Next Release Date: 03/31/2016 Referring Pages: U.S. Liquefied Natural Gas

  19. Havre, MT Natural Gas Pipeline Imports From Canada (Million Cubic Feet)

    U.S. Energy Information Administration (EIA) Indexed Site

    Million Cubic Feet) Havre, MT Natural Gas Pipeline Imports From Canada (Million Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1990's NA NA 2000's 1,309 NA NA 0 - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 2/29/2016 Next Release Date: 3/31/2016 Referring Pages: U.S.

  20. 9 Cr-- 1 Mo steel material for high temperature application

    DOE Patents [OSTI]

    Jablonski, Paul D; Alman, David; Dogan, Omer; Holcomb, Gordon; Cowen, Christopher

    2012-11-27

    One or more embodiments relates to a high-temperature, titanium alloyed, 9 Cr-1 Mo steel exhibiting improved creep strength and oxidation resistance at service temperatures up to 650.degree. C. The 9 Cr-1 Mo steel has a tempered martensite microstructure and is comprised of both large (0.5-3 .mu.m) primary titanium carbides and small (5-50 nm) secondary titanium carbides in a ratio of. from about 1:1.5 to about 1.5:1. The 9 Cr-1 Mo steel may be fabricated using exemplary austenizing, rapid cooling, and tempering steps without subsequent hot working requirements. The 9 Cr-1 Mo steel exhibits improvements in total mass gain, yield strength, and time-to-rupture over ASTM P91 and ASTM P92 at the temperature and time conditions examined.

  1. Support effects on hydrotreating activity of NiMo catalysts

    SciTech Connect (OSTI)

    Dominguez-Crespo, M.A. Arce-Estrada, E.M.; Torres-Huerta, A.M.

    2007-10-15

    The effect of the gamma alumina particle size on the catalytic activity of NiMoS{sub x} catalysts prepared by precipitation method of aluminum acetate at pH = 10 was studied. The structural characterization of the supports was measured by using XRD, pyridine FTIR-TPD and nitrogen physisorption. NiMo catalysts were characterized during the preparation steps (annealing and sulfidation) using transmission electron microscopy (TEM). Hydrogen TPR studies of the NiMo catalysts were also carried out in order to correlate their hydrogenating properties and their catalytic functionality. Catalytic tests were carried out in a pilot plant at 613, 633 and 653 K temperatures. The results showed that the rate constants of hydrodesulfurization (HDS), hydrodenitrogenation (HDN) and hydrodearomatizing (HDA) at 613-653 K decreased in the following order: A > B > C corresponding to the increase of NiMoS particle size associated to these catalysts.

  2. CO2ReMoVe | Open Energy Information

    Open Energy Info (EERE)

    of industrial, research and service organizations with experience in CO2 geological storage. References: CO2ReMoVe1 This article is a stub. You can help OpenEI by expanding...

  3. Structural Insights into FeMo Cofactor Biosynthesis

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    a catalytic component and a specific reductase, which, in the standard system, are referred to as the MoFe protein and the Fe protein. At the active site of the...

  4. Co-Mo Electric Cooperative- Energy Efficiency Rebate Program

    Broader source: Energy.gov [DOE]

    Co-Mo Electric Cooperative provides rebates to its residential and commercial members who install air source, dual fuel, and/or geothermal heat pumps, and certain energy efficient appliances. Heat...

  5. M.O. Wascko, LSU NuInt05...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    O. Wascko, LSU NuInt05 26 September, 2005 MiniBooNE CC + CCQE Ratio M.O. Wascko, LSU J.R. Monroe, Columbia CC interactions Quasi-Elastic (CCQE) Inclusive Single +...

  6. Ethanol Conversion on Cyclic (MO3)3 (M = Mo, W) Clusters

    SciTech Connect (OSTI)

    Li, Zhenjun; Fang, Zongtang; Kelley, Matthew S.; Kay, Bruce D.; Rousseau, Roger J.; Dohnalek, Zdenek; Dixon, David A.

    2014-03-06

    Oxides of molybdenum and tungsten are an important class of catalytic materials with applications ranging from isomerization of alkanes and alkenes, partial oxidation of alcohols, selective reduction of nitric oxide and metathesis of alkeness.[1-10] While many studies have focused on the structure - function relationships, the nature of high catalytic activity is still being extensively investigated. There is a general agreement that the activity of supported MOx (M = W, Mo) catalysts is correlated with the presence of acidic sites, where the catalytic activity is strongly affected by the type of oxide support, delocalization of electron density, structures of tungsten oxide domains and presence of protons

  7. Microstructures in rapidly solidified Ni-Mo alloys

    SciTech Connect (OSTI)

    Jayaraman, N.; Tewari, S.N.; Hemker, K.J.; Glasgow, T.K.

    1985-01-01

    Ni-Mo alloys of compositions ranging from pure Ni to Ni-40 at % Mo were rapidly solidified by chill block melt spinning in vacuum and were examined by optical metallography, x-ray diffraction and transmission electron microscopy. Rapid solidification resulted in an extension of molybdenum solubility in nickel from 28 to 37.5 at %. A number of different phases and microstructures were seen at different depths (solidification conditions) from the quenched surface of the melt spun ribbons.

  8. DOE - Office of Legacy Management -- Medart Co - MO 09

    Office of Legacy Management (LM)

    Medart Co - MO 09 FUSRAP Considered Sites Site: MEDART CO. (MO.09 ) Eliminated from consideration under FUSRAP - Facility believed to be torn down and the original site built over Designated Name: Not Designated Alternate Name: None Location: 180 Potomoc Street , St. Louis , Missouri MA.09-4 Evaluation Year: Circa 1990 MA.09-3 Site Operations: Conducted test machining operations on uranium bar stock during the early 1950s. MA.09-2 Site Disposition: Eliminated - Potential for contamination

  9. DOE - Office of Legacy Management -- St Louis University - MO 0-02

    Office of Legacy Management (LM)

    University - MO 0-02 FUSRAP Considered Sites Site: ST. LOUIS UNIVERSITY (MO.0-02) Eliminated from consideration under FUSRAP - As of 1987 the facility operated under an NRC license Designated Name: Not Designated Alternate Name: None Location: St. Louis , Missouri MO.0-02-1 Evaluation Year: 1987 MO.0-02-1 Site Operations: Performed research activities involving small quantities of radioactive materials in a controlled environment. MO.0-02-1 Site Disposition: Eliminated - No Authority - Potential

  10. Coated U(Mo) Fuel: As-Fabricated Microstructures

    SciTech Connect (OSTI)

    Emmanuel Perez; Dennis D. Keiser, Jr.; Ann Leenaers; Sven Van den Berghe; Tom Wiencek

    2014-04-01

    As part of the development of low-enriched uranium fuels, fuel plates have recently been tested in the BR-2 reactor as part of the SELENIUM experiment. These fuel plates contained fuel particles with either Si or ZrN thin film coating (up to 1 m thickness) around the U-7Mo fuel particles. In order to best understand irradiation performance, it is important to determine the starting microstructure that can be observed in as-fabricated fuel plates. To this end, detailed microstructural characterization was performed on ZrN and Si-coated U-7Mo powder in samples taken from AA6061-clad fuel plates fabricated at 500C. Of interest was the condition of the thin film coatings after fabrication at a relatively high temperature. Both scanning electron microscopy and transmission electron microscopy were employed. The ZrN thin film coating was observed to consist of columns comprised of very fine ZrN grains. Relatively large amounts of porosity could be found in some areas of the thin film, along with an enrichment of oxygen around each of the the ZrN columns. In the case of the pure Si thin film coating sample, a (U,Mo,Al,Si) interaction layer was observed around the U-7Mo particles. Apparently, the Si reacted with the U-7Mo and Al matrix during fuel plate fabrication at 500C to form this layer. The microstructure of the formed layer is very similar to those that form in U-7Mo versus Al-Si alloy diffusion couples annealed at higher temperatures and as-fabricated U-7Mo dispersion fuel plates with Al-Si alloy matrix fabricated at 500C.

  11. Havre, MT Natural Gas Pipeline Imports From Canada (Dollars per Thousand

    U.S. Energy Information Administration (EIA) Indexed Site

    Cubic Feet) Dollars per Thousand Cubic Feet) Havre, MT Natural Gas Pipeline Imports From Canada (Dollars per Thousand Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1990's NA NA 2000's 3.66 NA NA -- - = No Data Reported; -- = Not Applicable; NA = Not Available; W = Withheld to avoid disclosure of individual company data. Release Date: 2/29/2016 Next Release Date: 3/31/2016 Referring Pages: U.S. Price of

  12. EM SSAB NATIONAL CHAIRS MEETING Deer Creek State Park, Mt. Sterling, Ohio

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    EM SSAB NATIONAL CHAIRS MEETING Deer Creek State Park, Mt. Sterling, Ohio November 5-7, 2013 DAY 1 - Tuesday, November 5, 2013 8:00 a.m. - 8:20 a.m. Welcome and Opening Remarks Cate Alexander, EM SSAB Designated Federal Officer Will Henderson, Chair, Portsmouth Site Specific Advisory Board William Murphie, Manager, Portsmouth Paducah Project Office, DOE-EM 8:20 a.m. - 8:30 a.m. Overview of Meeting Eric Roberts, Facilitator 8:30 a.m. - 9:30 a.m. EM Program Update Alice Williams, Associate

  13. Ligand Bridging-Angle-Driven Assembly of Molecular Architectures Based on Quadruply Bonded Mo-Mo Dimers

    SciTech Connect (OSTI)

    Li, Jian-Rong; Yakovenko, Andrey A; Lu, Weigang; Timmons, Daren J; Zhuang, Wenjuan; Yuan, Daqiang; Zhou, Hong-Cai

    2010-12-15

    A systematic exploration of the assembly of Mo?(O?C-)?-based metalorganic molecular architectures structurally controlled by the bridging angles of rigid organic linkers has been performed. Twelve bridging dicarboxylate ligands were designed to be of different sizes with bridging angles of 0, 60, 90, and 120 while incorporating a variety of nonbridging functional groups, and these ligands were used as linkers. These dicarboxylate linkers assemble with quadruply bonded MoMo clusters acting as nodes to give 13 molecular architectures, termed metalorganic polygons/polyhedra with metal cluster node arrangements of a linear shape, triangle, octahedron, and cuboctahedron/anti-cuboctahedron. The syntheses of these complexes have been optimized and their structures determined by single-crystal X-ray diffraction. The results have shown that the shape and size of the resulting molecular architecture can be controlled by tuning the bridging angle and size of the linker, respectively. Functionalization of the linker can adjust the solubility of the ensuing molecular assembly but has little or no effect on the geometry of the product. Preliminary gas adsorption, spectroscopic, and electrochemical properties of selected members were also studied. The present work is trying to enrich metal-containing supramolecular chemistry through the inclusion of well-characterized quadruply bonded MoMo units into the structures, which can widen the prospect of additional electronic functionality, thereby leading to novel properties.

  14. LICENSE HISTORY MO.8 Petrolite Corporation, St. Louis

    Office of Legacy Management (LM)

    LICENSE HISTORY MO.8 Petrolite Corporation, St. Louis 07,16/93 l See attached Document and Pile Sumnary for MO.8 l License History: l 24-10452-01, 30-051175, 08/13/79. Loose H-3, I-131, P-32. l 24-10452-1, 10/30/64. K66 R. R. Annand et al Multiple. . 70-621, 12-15-61, SNM license for 0.5 kg. of U-235, 93% enriched as a fuel loading and star-up ~curce for Webster Groves, Missouri reactor. l Discussion: Historical documents for this site are limited. The only information available on work done

  15. Policy Flash 2013-71 AL 2013-11 NON M&O CONTRACTOR BUSINESS SYSTEMS...

    Energy Savers [EERE]

    Policy Flash 2013-71 AL 2013-11 NON M&O CONTRACTOR BUSINESS SYSTEMS CLAUSES FOR SECTION H Policy Flash 2013-71 AL 2013-11 NON M&O CONTRACTOR BUSINESS SYSTEMS CLAUSES FOR SECTION H...

  16. Solution-based thermodynamic modeling of the Ni-Al-Mo system...

    Office of Scientific and Technical Information (OSTI)

    as (Al,Mo,Ni)0.75(Al,Mo,Ni)0.25. Thus, -fcc and -Ni3Al are modeled with a single Gibbs free energy function with appropriate treatment of the chemical ordering contribution. ...

  17. Domestic production of medical isotope Mo-99 moves a step closer

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Domestic production of medical isotope Mo-99 Domestic production of medical isotope Mo-99 moves a step closer Irradiated uranium fuel has been recycled and reused for molybdenum-99 (Mo-99) production, with virtually no losses in Mo-99 yields or uranium recovery. May 13, 2013 From left, Los Alamos scientists Roy Copping, Sean Reilly, and Daniel Rios. Copping examines the Buchi Multivapor P-12 Evaporator, and Reilly and Rios are at the Agilent Technologies Cary 60 UV-Vis Spectrometer. From left,

  18. Corrosion report for the U-Mo fuel concept

    SciTech Connect (OSTI)

    Henager, Jr., Charles H.; Bennett, Wendy D.; Doherty, Ann L.; Fuller, E. S.; Hardy, John S.; Omberg, Ronald P.

    2014-08-28

    The Fuel Cycle Research and Development (FCRD) program of the Office of Nuclear Energy (NE) has implemented a program to develop a Uranium-Molybdenum (U-Mo) metal fuel for Light Water Reactors (LWR)s. Uranium-Molybdenum fuel has the potential to provide superior performance based on its thermo-physical properties, which includes high thermal conductivity for less stored heat energy. With sufficient development, it may be able to provide the Light Water industry with a melt-resistant accident tolerant fuel with improved safety response. However, the corrosion of this fuel in reactor water environments needs to be further explored and optimized by additional alloying. The Pacific Northwest National Laboratory has been tasked with performing ex-reactor corrosion testing to characterize the performance of U-Mo fuel. This report documents the results of the effort to characterize and develop the U-Mo metal fuel concept for LWRs with regard to corrosion testing. The results of a simple screening test in buffered water at 30C using surface alloyed U-10Mo is documented and discussed. The screening test was used to guide the selection of several potential alloy improvements that were found and are recommended for further testing in autoclaves to simulate PWR water conditions more closely.

  19. NNSA Awards Mo-99 Cooperative Agreement to General Atomics | National

    National Nuclear Security Administration (NNSA)

    Nuclear Security Administration Mo-99 Cooperative Agreement to General Atomics | National Nuclear Security Administration Facebook Twitter Youtube Flickr RSS People Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy Emergency Response Recapitalizing Our Infrastructure Countering Nuclear Terrorism About Our Programs Our History Who We Are Our Leadership Our Locations Budget Our Operations Library Bios Congressional Testimony Fact Sheets Newsletters Press

  20. Tuning magnetism of monolayer MoS{sub 2} by doping vacancy and applying strain

    SciTech Connect (OSTI)

    Zheng, Huiling; Yang, Baishun; Han, Ruilin; Du, Xiaobo; Yan, Yu; Wang, Dingdi

    2014-03-31

    In view of important role of inducing and manipulating the magnetism in two-dimensional materials for the development of low-dimensional spintronic devices, the influences of strain on electronic structure and magnetic properties of commonly observed vacancies doped monolayer MoS{sub 2} are investigated using first-principles calculations. It is shown that unstrained V{sub S}, V{sub S2}, and V{sub MoS3} doped monolayer MoS{sub 2} systems are nonmagnetic, while the ground state of unstrained V{sub MoS6} doped system is magnetic and the magnetic moment is contributed mainly by six Mo atoms around V{sub MoS6}. In particular, tensile strain can induce magnetic moments in V{sub S}, V{sub S2}, and V{sub MoS3} doped monolayer MoS{sub 2} due to the breaking of Mo–Mo metallic bonds around the vacancies, while the magnetization induced by V{sub MoS6} can be effectively manipulated by equibiaxial strain due to the change of Mo–Mo metallic bonds around V{sub MoS6} under strains.

  1. Defects Engineered Monolayer MoS2 for Improved Hydrogen Evolution Reaction

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ye, Gonglan; Gong, Yongji; Lin, Junhao; Li, Bo; He, Yongmin; Pantelides, Sokrates T.; Zhou, Wu; Vajtai, Robert; Ajayan, Pulickel M.

    2016-01-13

    MoS2 is a promising, low-cost material for electrochemical hydrogen production due to its high activity and stability during the reaction. Our work represents an easy method to increase the hydrogen production in electrochemical reaction of MoS2 via defect engineering, and helps to understand the catalytic properties of MoS2.

  2. Crustal models of the geothermal areas of Larderello and Mt. Amiata, Italy

    SciTech Connect (OSTI)

    Gianelli, G.; Manzella, A.; Puxeddu, M.

    1996-12-31

    The study of core samples and geophysical data from the Larderello and Mt. Amiata geothermal areas indicate the presence of granite intrusions and granitic dykes as old as 3.8-2.9 Ma and widespread contact aureoles. Reflection seismic surveys reveal the presence of a highly reflective horizon (named K) in a depth range of 3-12 km in the two geothermal areas; seismic tomography and teleseismic studies show at Larderello a low velocity body, 30-40 km wide below the K horizon. Magnetotelluric surveys indicate the presence of a conductive body in good correlation with the anomalous tomographic and teleseismic body. The occurrence of shallow intrusive bodies, still partially molten and associated with saline brines is here considered a reliable model.

  3. Uranium hydrogeochemical and stream sediment reconnaissance of the Mt. Hayes NTMS quadrangle, Alaska

    SciTech Connect (OSTI)

    Not Available

    1981-05-01

    Results of a hydrogeochemical and stream sediment reconnaissance of the Mt. Hayes quadrangle, Alaska, are presented. In addition to this abbreviated data release, more complete data are available to the public in machine-readable form. In this data release are location data, field analyses, and Laboratory analyses of several different sample media. For the sake of brevity, many field site observations have not been included in this volume. These data are, however, available on the magnetic tape. Appendices A to D describe the sample media and summarize the analytical results for each medium. The data were subsetted by one of the Los Alamos National Laboratory (LANL) sorting programs into groups of stream sediment, lake sediment, stream water, lake water, and ground water samples. For each group which contains a sufficient number of observations, statistical tables, tables of raw data, and 1:1000000 scale maps of pertinent elements have been included in this report.

  4. EIS-0092: Conversion to Coal, Holyoke Water Power Company, Mt. Tom Generating Station Unit 1 Holyoke, Hampden County, Massachusetts

    Broader source: Energy.gov [DOE]

    The Economic Regulatory Administration prepared this statement to assess the environmental impacts of prohibiting Unit 1 of the Mt. Tom Generation Station Unit 1 from using either natural gas or petroleum products as a primary energy source, which would result in the utility burning low-sulfur coal.

  5. Thermal transport properties of metal/MoS{sub 2} interfaces from first principles

    SciTech Connect (OSTI)

    Mao, Rui; Kong, Byoung Don; Kim, Ki Wook, E-mail: kwk@ncsu.edu [Department of Electrical and Computer Engineering, North Carolina State University, Raleigh, North Carolina 27695-7911 (United States)

    2014-07-21

    Thermal transport properties at the metal/MoS{sub 2} interfaces are analyzed by using an atomistic phonon transport model based on the Landauer formalism and first-principles calculations. The considered structures include chemisorbed Sc(0001)/MoS{sub 2} and Ru(0001)/MoS{sub 2}, physisorbed Au(111)/MoS{sub 2}, as well as Pd(111)/MoS{sub 2} with intermediate characteristics. Calculated results illustrate a distinctive dependence of thermal transfer on the details of interfacial microstructures. More specifically, the chemisorbed case with a stronger bonding exhibits a generally smaller interfacial thermal resistance than the physisorbed. Comparison between metal/MoS{sub 2} and metal/graphene systems suggests that metal/MoS{sub 2} is significantly more resistive. Further examination of lattice dynamics identifies the presence of multiple distinct atomic planes and bonding patterns at the interface as the key origins of the observed large thermal resistance.

  6. Undercooled and rapidly quenched Ni-Mo alloys

    SciTech Connect (OSTI)

    Tewari, S.N.; Glasgow, T.K.

    1986-01-01

    Hypoeutectic, eutectic, and hypereutectic nickel-molybdenum alloys were rapidly solidified by both bulk undercooling and melt spinning techniques. Alloys were undercooled in both electromagnetic levitation and differential thermal analysis equipment. The rate of recalescence depended upon the degree of initial undercooling and the nature (faceted or nonfaceted) of the primary nucleating phase. Alloy melts were observed to undercool more in the presence of primary Beta (NiMo intermetallic) phase than in gamma (fcc solid solution) phase. Melt spinning resulted in an extension of molybdenum solid solubility in gamma nickel, from 28 to 37.5 at % Mo. Although the microstructures observed by undercooling and melt spinning were similar the microsegregation pattern across the gamma dendries was different. The range of microstructures evolved was analyzed in terms of the nature of the primary phase to nucleate, its subsequent dendritic growth, coarsening and fragmentation, and final solidification of interfenderitic liquid.

  7. IRRADIATION PERFORMANCE OF U-Mo MONOLITHIC FUEL

    SciTech Connect (OSTI)

    M.K. Meyer; J. Gan; J.-F. Jue; D.D. Keiser; E. Perez; A. Robinson; D.M. Wachs; N. Woolstenhulme; G.L. Hofman; Y.-S. Kim

    2014-04-01

    High-performance research reactors require fuel that operates at high specific power to high fission density, but at relatively low temperatures. Research reactor fuels are designed for efficient heat rejection, and are composed of assemblies of thin-plates clad in aluminum alloy. The development of low-enriched fuels to replace high-enriched fuels for these reactors requires a substantially increased uranium density in the fuel to offset the decrease in enrichment. Very few fuel phases have been identified that have the required combination of very-high uranium density and stable fuel behavior at high burnup. UMo alloys represent the best known tradeoff in these properties. Testing of aluminum matrix U-Mo aluminum matrix dispersion fuel revealed a pattern of breakaway swelling behavior at intermediate burnup, related to the formation of a molybdenum stabilized high aluminum intermetallic phase that forms during irradiation. In the case of monolithic fuel, this issue was addressed by eliminating, as much as possible, the interfacial area between U-Mo and aluminum. Based on scoping irradiation test data, a fuel plate system composed of solid U-10Mo fuel meat, a zirconium diffusion barrier, and Al6061 cladding was selected for development. Developmental testing of this fuel system indicates that it meets core criteria for fuel qualification, including stable and predictable swelling behavior, mechanical integrity to high burnup, and geometric stability. In addition, the fuel exhibits robust behavior during power-cooling mismatch events under irradiation at high power.

  8. Single Phase Melt Processed Powellite (Ba,Ca) MoO{sub 4} For The Immobilization Of Mo-Rich Nuclear Waste

    SciTech Connect (OSTI)

    Brinkman, Kyle; Marra, James; Fox, Kevin; Reppert, Jason; Crum, Jarrod; Tang, Ming

    2012-09-17

    Crystalline and glass composite materials are currently being investigated for the immobilization of combined High Level Waste (HLW) streams resulting from potential commercial fuel reprocessing scenarios. Several of these potential waste streams contain elevated levels of transition metal elements such as molybdenum (Mo). Molybdenum has limited solubility in typical silicate glasses used for nuclear waste immobilization. Under certain chemical and controlled cooling conditions, a powellite (Ba,Ca)MoO{sub 4} crystalline structure can be formed by reaction with alkaline earth elements. In this study, single phase BaMoO{sub 4} and CaMoO{sub 4} were formed from carbonate and oxide precursors demonstrating the viability of Mo incorporation into glass, crystalline or glass composite materials by a melt and crystallization process. X-ray diffraction, photoluminescence, and Raman spectroscopy indicated a long range ordered crystalline structure. In-situ electron irradiation studies indicated that both CaMoO{sub 4} and BaMoO{sub 4} powellite phases exhibit radiation stability up to 1000 years at anticipated doses with a crystalline to amorphous transition observed after 1 X 10{sup 13} Gy. Aqueous durability determined from product consistency tests (PCT) showed low normalized release rates for Ba, Ca, and Mo (<0.05 g/m{sup 2}).

  9. Applications of stable isotopes in hydrological studies of Mt. Apo geothermal field, Philippines

    SciTech Connect (OSTI)

    Salonga, N.D.; Aragon, G.M.; Nogara, J.B.; Sambrano, B.G.

    1996-12-31

    The local precipitation in Mt. Apo is depleted of heavy isotopes owing to high elevation and landward location of the field. Rainwaters infiltrate the shallow grounds, circulate in short distances with almost no interaction with the host bed rocks, and effuse in the surface as cold springs. Lakes and rivers are affected by surface evaporation while the acid SO{sub 4} springs are affected by both evaporation and steam-heating. Only the neutral-pH Cl springs have the signature of the deep thermal fluids. The parent fluids of the deep thermal brine contain Cl of 4,800 to 5,000 mg/kg, {delta}{sup 18}O of -4.62 to -4.13 {per_thousand} and {delta}{sup 2}H of -60.0 to -57.8 {per_thousand}. Inside the Sandawa Collapse, boiling of the parent fluids resulted in a two-phase reservoir with lighter isotope contents. The thermal fluids laterally flow towards the west where they are affected by cooling and mixing of cold waters. Deep water recharge has {delta}{sup 18}O of -10.00 {per_thousand} and {delta}{sup 2}H = -61.20 {per_thousand} which come from the upper slopes of Sandawa Collapse (1580-1700 mASL).

  10. Four-year prospective study of the respiratory effects of volcanic ash from Mt. St. Helens

    SciTech Connect (OSTI)

    Buist, A.S.; Vollmer, W.M.; Johnson, L.R.; Bernstein, R.S.; McCamant, L.E.

    1986-04-01

    This report describes the 4-yr follow-up of 712 loggers exposed over an extended period to varying levels of fresh volcanic ash from the 1980 eruptions of Mt. St. Helens. Concerns related to the irritant effect the ash might have on the airways and also to its fibrogenic potential if exposures were intense and continued over many years. Our subjects were divided into 3 groups: high, low, and no exposure. Baseline testing was begun in June 1980, 1 month after the major eruption, and follow-up testing continued on an annual basis through 1984; 88% of the loggers have been tested at least 3 times. Analysis of lung function data showed that a significant, exposure-related decline in FEV1 occurred during the first year after the eruption. The decline was short-lived, however, and by 1984 the differences between exposure groups were no longer significant. Self-reported symptoms of cough, phlegm, and wheeze showed a similar pattern. No ash-related changes were seen in chest roentgenograms taken in 1980 and in 1984. Our findings are consistent with the hypothesis that the inhaled ash caused mucus hypersecretion and/or airway inflammation that reversed when the exposure levels decreased. The ash levels to which the loggers were exposed were low compared with permissible occupational levels for nuisance dusts, but generally higher than the total suspended particulate levels permissible in ambient air.

  11. CO2 flood tests on whole core samples of the Mt. Simon sandstone, Illinois Basin

    SciTech Connect (OSTI)

    O'Connor, William K.; Rush, Gilbert E.

    2005-09-01

    Geological sequestration of CO2, whether by enhanced oil recovery (EOR), coal-bed methane (CBM) recovery, or saline aquifer injection is a promising near-term sequestration methodology. While tremendous experience exists for EOR, and CBM recovery has been demonstrated in existing fields, saline aquifer injection studies have only recently been initiated. Studies evaluating the availability of saline aquifers suitable for CO2 injection show great potential, however, the long-term fate of the CO2 injected into these ancient aqueous systems is still uncertain. For the subject study, a series of laboratory-scale CO2 flood tests were conducted on whole core samples of the Mt. Simon sandstone from the Illinois Basin. By conducting these tests on whole core samples rather than crushed core, an evaluation of the impact of the CO2 flood on the rock mechanics properties as well as the geochemistry of the core and brine solution has been possible. This empirical data could provide a valuable resource for the validation of reservoir models under development for these engineered CO2 systems.

  12. Preliminary study on mercury uptake by Rosmarinus officinalis L. (Rosemary) in a mining area (Mt. Amiata, Italy)

    SciTech Connect (OSTI)

    Barghigiani, C.; Ristori, T.

    1995-04-01

    Among the different plants analyzed to assess environmental mercury contamination of mining areas, lichens are those most studied, followed by brooms together with pine, which was also used in other areas, and spruce. Other species, both naturally occurring and cultivated, have also been studied. This work reports on the results of mercury uptake and accumulation in rosemary in relation to metal concentrations in both air and soil. R. officinalis is a widespread endemic Mediterranean evergreen shrub, which in Italy grows naturally and is also cultivated as a culinary herb. This research was carried out in Tuscany (Italy), in the Mt. Amiata area, which is characterized by the presence of cinnabar (HgS) deposits and has been used for mercury extraction and smelting from Etruscan times until 1980, and in the country near the town of Pisa, 140 km away from Mt. Amiata. 16 refs., 3 figs., 1 tab.

  13. Domestic production of medical isotope Mo-99 moves a step closer

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    partners, including Morgridge Institute for Research-SHINE Medical Technologies (MIR-SHINE), which proposes to use a particle accelerator to produce Mo-99 from a mildly...

  14. Experimental activities supporting commercial U.S. accelerator production of 99-Mo

    SciTech Connect (OSTI)

    Dale, Gregory E [Los Alamos National Laboratory; Chemerisov, Sergey D [ANL; Vandegrift, George F [ANL

    2010-01-01

    {sup 99m}Tc, the daughter product of {sup 99}Mo, is the most commonly used radioisotope for nuclear medicine in the U.S. Experiments are being performed at Los Alamos National Laboratory and Argonne National Laboratory to demonstrate production of {sup 99}Mo using accelerators. The {sup 100}Mo({gamma},n){sup 99}Mo reaction in an enriched {sup 100}Mo target is currently under investigation. Three scaled low-power production experiments using a 20-MeV electron linac at Argonne have been performed to date. Two of these experiments used natural Mo targets and produced a total of 613 {mu}C of {sup 99}Mo. The third experiment used an enriched {sup 100}Mo target and produced 10.5 mCi of {sup 99}Mo. Following irradiation the targets were dissolved and the low specific activity solution was processed through an ARSII generator from NorthStar Medical Radioisotopes. Yields of {sup 99m}Tc >95% have been observed.

  15. Conceptual design of a new homogeneous reactor for medical radioisotope Mo-99/Tc-99m production

    SciTech Connect (OSTI)

    Liem, Peng Hong [Nippon Advanced Information Service (NAIS Co., Inc.) Scientific Computational Division, 416 Muramatsu, Tokaimura, Ibaraki (Japan); Tran, Hoai Nam [Chalmers University of Technology, Dept. of Applied Physics, Div. of Nuclear Engineering, SE-412 96 Gothenburg (Sweden); Sembiring, Tagor Malem [National Nuclear Energy Agency (BATAN), Center for Reactor Technology and Nuclear Safety, Kawasan Puspiptek, Serpong, Tangerang Selatan, Banten (Indonesia); Arbie, Bakri [PT MOTAB Technology, Kedoya Elok Plaza Blok DA 12, Jl. Panjang, Kebun Jeruk, Jakarta Barat (Indonesia)

    2014-09-30

    To partly solve the global and regional shortages of Mo-99 supply, a conceptual design of a nitrate-fuel-solution based homogeneous reactor dedicated for Mo-99/Tc-99m medical radioisotope production is proposed. The modified LEU Cintichem process for Mo-99 extraction which has been licensed and demonstrated commercially for decades by BATAN is taken into account as a key design consideration. The design characteristics and main parameters are identified and the advantageous aspects are shown by comparing with the BATAN's existing Mo-99 supply chain which uses a heterogeneous reactor (RSG GAS multipurpose reactor)

  16. Solution-based thermodynamic modeling of the Ni-Al-Mo system using

    Office of Scientific and Technical Information (OSTI)

    first-principles calculations (Journal Article) | SciTech Connect Solution-based thermodynamic modeling of the Ni-Al-Mo system using first-principles calculations Citation Details In-Document Search Title: Solution-based thermodynamic modeling of the Ni-Al-Mo system using first-principles calculations A solution-based thermodynamic description of the ternary Ni-Al-Mo system is developed here, incorporating first-principles calculations and reported modeling of the binary Ni-Al, Ni-Mo and

  17. Synthesis of molybdenum disulfide (MoS{sub 2}) for lithium ion battery applications

    SciTech Connect (OSTI)

    Feng Chuanqi; Ma Jun; Li Hua; Zeng Rong; Guo Zaiping; Liu Huakun

    2009-09-15

    This paper reports the use of a rheological phase reaction method for preparing MoS{sub 2} nanoflakes. The characterization by powder X-ray diffraction indicated that MoS{sub 2} had been formed. High resolution electron microscopy observation revealed that the as-prepared MoS{sub 2} nanoflakes had started to curve and partly form MoS{sub 2} nanotubes. The lithium intercalation/de-intercalation behavior of as-prepared MoS{sub 2} nanoflake electrode was also investigated. It was found that the MoS{sub 2} nanoflake electrode exhibited higher specific capacity, with very high cycling stability, compared to MoS{sub 2} nanoparticle electrode. The possible reasons for the high electrochemical performance of the nanoflakes electrodes are also discussed. The outstanding electrochemical properties of MoS{sub 2} nanoflakes obtained by this method make it possible for MoS{sub 2} to be used as a promising anode material.

  18. Mechanically Activated Combustion Synthesis of MoSi2-Based Composites

    SciTech Connect (OSTI)

    Shafirovich, Evgeny

    2015-09-30

    The thermal efficiency of gas-turbine power plants could be dramatically increased by the development of new structural materials based on molybdenum silicides and borosilicides, which can operate at temperatures higher than 1300 °C with no need for cooling. A major challenge, however, is to simultaneously achieve high oxidation resistance and acceptable mechanical properties at high temperatures. One approach is based on the fabrication of MoSi2-Mo5Si3 composites that combine high oxidation resistance of MoSi2 and good mechanical properties of Mo5Si3. Another approach involves the addition of boron to Mo-rich silicides for improving their oxidation resistance through the formation of a borosilicate surface layer. In particular, materials based on Mo5SiB2 phase are promising materials that offer favorable combinations of high temperature mechanical properties and oxidation resistance. However, the synthesis of Mo-Si-B multi-phase alloys is difficult because of their extremely high melting temperatures. Mechanical alloying has been considered as a promising method, but it requires long milling times, leading to large energy consumption and contamination of the product by grinding media. In the reported work, MoSi2-Mo5Si3 composites and several materials based on Mo5SiB2 phase have been obtained by mechanically activated self-propagating high-temperature synthesis (MASHS). Short-term milling of Mo/Si mixture in a planetary mill has enabled a self-sustained propagation of the combustion front over the mixture pellet, leading to the formation of MoSi2-T1 composites. Combustion of Mo/Si/B mixtures for the formation of T2 phase becomes possible if the composition is designed for the addition of more exothermic reactions leading to the formation of MoB, TiC, or TiB2. Upon ignition, Mo/Si/B and Mo/Si/B/Ti mixtures exhibited spin combustion, but the products were porous, contained undesired secondary phases, and had low oxidation resistance. It has been shown that use of SHS compaction (quasi-isostatic pressing after combustion) significantly improves oxidation resistance of the obtained MoSi2-Mo5Si3 composites. The “chemical oven” technique has been successfully employed to fabricate low-porous Mo5SiB2–TiC, Mo5SiB2–TiB2, and Mo–Mo5SiB2–Mo3Si materials. Among them, Mo5SiB2–TiB2 material possesses good mechanical properties and simultaneously exhibits excellent oxidation resistance at temperatures up to 1500 °C.

  19. Recovery of Mo/Si multilayer coated optical substrates

    DOE Patents [OSTI]

    Baker, S.L.; Vernon, S.P.; Stearns, D.G.

    1997-12-16

    Mo/Si multilayers are removed from superpolished ZERODUR and fused silica substrates with a dry etching process that, under suitable processing conditions, produces negligible change in either the substrate surface figure or surface roughness. The two step dry etching process removes SiO{sub 2} overlayer with a fluroine-containing gas and then moves molybdenum and silicon multilayers with a chlorine-containing gas. Full recovery of the initial normal incidence extreme ultra-violet (EUV) reflectance response has been demonstrated on reprocessed substrates. 5 figs.

  20. Recovery of Mo/Si multilayer coated optical substrates

    DOE Patents [OSTI]

    Baker, Sherry L.; Vernon, Stephen P.; Stearns, Daniel G.

    1997-12-16

    Mo/Si multilayers are removed from superpolished ZERODUR and fused silica substrates with a dry etching process that, under suitable processing conditions, produces negligible change in either the substrate surface figure or surface roughness. The two step dry etching process removes SiO.sub.2 overlayer with a fluroine-containing gas and then moves molybdenum and silicon multilayers with a chlorine-containing gas. Full recovery of the initial normal incidence extreme ultra-violet (EUV) reflectance response has been demonstrated on reprocessed substrates.

  1. Microsoft Word - chapter FeCrMo_ver2.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Reference on Hydrogen Compatibility of Materials Low-Alloy Ferritic Steels: Tempered Fe-Cr-Mo Alloys (code 1211) Prepared by: B.P. Somerday, Sandia National Laboratories Editors C. San Marchi B.P. Somerday Sandia National Laboratories This report may be updated and revised periodically in response to the needs of the technical community; up-to-date versions can be requested from the editors at the address given below or downloaded at http://www.ca.sandia.gov/matlsTechRef/ . The success of this

  2. Greenfield Alternative Study LEU-Mo Fuel Fabrication Facility

    SciTech Connect (OSTI)

    Washington Division of URS

    2008-07-01

    This report provides the initial “first look” of the design of the Greenfield Alternative of the Fuel Fabrication Capability (FFC); a facility to be built at a Greenfield DOE National Laboratory site. The FFC is designed to fabricate LEU-Mo monolithic fuel for the 5 US High Performance Research Reactors (HPRRs). This report provides a pre-conceptual design of the site, facility, process and equipment systems of the FFC; along with a preliminary hazards evaluation, risk assessment as well as the ROM cost and schedule estimate.

  3. Characterization of modified 9 Cr-1 Mo steel extruded pipe

    SciTech Connect (OSTI)

    Sikka, V.K.; Hart, M.D.

    1985-04-01

    The fabrication of hot-extruded pipe of modified 9 Cr-1 Mo steel at Cameron Iron Works is described. The report also deals with the tempering response; tensile, Charpy impact, and creep properties; and microstructure of the hot-extruded pipe. The tensile properties of the pipe are compared with the average and average -1.65 standard error of estimate curves for various product forms of several commercial heats of this alloy. The creep-rupture properties are compared with the average curve for various product forms of the commercial heats.

  4. d::;":,",:::,, ST. LOUIS.7. MO,

    Office of Legacy Management (LM)

    i ,' ~CKRODT CHEMICAL d::;":,",:::,, ST. LOUIS.7. MO, PiARCH 14, ,jq;ll MR. H. L. PRICE, GIRECTOR ,.' , . . DIVISION OF LICENSING AND F~EG~~LATION ,... L.' S. ATOMIC ' ENERGY COMMISSION :' ;._ hASHINGT0N 25, D. c. T> "-VW-; PEAR P;R. FRICE: PURSUANT To THE PROVISIONS OF 10 CF? FART 20, PARAGRAPH 2O-.lO3, (4 (31, THE NUCLEAR DIVISI:IN, COMMERC I AL ~PERAT I ONS DF MALL- INCKRODT ' CHEMICAL b:ORKS WOULD LIKE TO MAKE.APPLlCATlON FOR A MODIFICATION TO LICENSE NO. SNPI 33 TO INCLUDE

  5. DOE/NNSA - MoD Certification Form

    Office of Environmental Management (EM)

    14 (01/2014) UNITED STATES DEPARTMENT OF ENERGY NATIONAL NUCLEAR SECURITY ADMINISTRATION UNITED KINGDOM MINISTRY OF DEFENCE DOE or MoD CERTIFICATION * Select as applicable SECTION I - DOE/NNSA MARK QUALITY MATERIAL This material has been accepted by the DOE/NNSA or inspected and accepted by DOE/NNSA contractor(s) authorized to acquire such material and is of like quality to that used in DOE/NNSA weapons or in support thereof. (Note: Application of UK Stamp is by DOE/NNSA only) Signature: Date:

  6. Dark Matter Particle Spectroscopy at the LHC: Generalizing M(T2) to Asymmetric Event Topologies

    SciTech Connect (OSTI)

    Konar, Partha; Kong, Kyoungchul; Matchev, Konstantin T.; Park, Myeonghun; /Florida U.

    2012-04-03

    We consider SUSY-like missing energy events at hadron colliders and critically examine the common assumption that the missing energy is the result of two identical missing particles. In order to experimentally test this hypothesis, we generalize the subsystem M{sub T2} variable to the case of asymmetric event topologies, where the two SUSY decay chains terminate in different 'children' particles. In this more general approach, the endpoint M{sub T2(max)} of the M{sub T2} distribution now gives the mass {tilde M}p({tilde M}{sub c}{sup (a)}, {tilde M}{sub c}{sup (b)}) of the parent particles as a function of two input children masses {tilde M}{sub c}{sup (a)} and {tilde M}{sub c}{sup (b)}. We propose two methods for an independent determination of the individual children masses M{sub c}{sup (a)} and M{sub c}{sup (b)}. First, in the presence of upstream transverse momentum PUTM the corresponding function {tilde M}p({tilde M}{sub c}{sup (a)}, {tilde M}{sub c}{sup (b)}, P{sub UTM}) is independent of P{sub UTM} at precisely the right values of the children masses. Second, the previously discussed MT2 'kink' is now generalized to a 'ridge' on the 2-dimensional surface {tilde M}p({tilde M}{sub c}{sup (a)}, {tilde M}{sub c}{sup (b)}). As we show in several examples, quite often there is a special point along that ridge which marks the true values of the children masses. Our results allow collider experiments to probe a multi-component dark matter sector directly and without any theoretical prejudice.

  7. Uranium hydrogeochemical and stream-sediment reconnaissance of the Mt. Michelson NTMS quadrangle, Alaska

    SciTech Connect (OSTI)

    Zinkl, R.J.; Shettel, D.L. Jr.; Langfeldt, S.L.; Hardy, L.C.; D'Andrea, R.F. Jr.

    1982-04-01

    This report presents results of a Hydrogeochemical and Stream Sediment Reconnaissance (HSSR) of the Mt. Michelson NTMS quadrangle, Alaska. In addition to this abbreviated data release, more complete data are available to the public in machine-readable form. These machine-readable data, as well as quarterly or semiannual program progress reports containing further information on the HSSR program in general, or on the Los Alamos National Laboratory (LANL) portion of the program in particular, are available from DOE's Technical Library at its Grand Junction Area Office. Presented in this data release are location data, field analyses, and laboratory analyses of several different sample media. For the sake of brevity, many field site observations have not been included in this volume; these data are, however, available on the magnetic tape. Appendices A and B describe the sample media and summarize the analytical results for each medium. The data have been subdivided by one of the Los Alamos National Laboratory sorting programs of Zinkl and others (1981a) into groups of stream-sediment and lake-sediment samples. For each group which contains a sufficient number of observations, statistical tables, tables of raw data, and 1:1,000,000 scale maps of pertinent elements have been included in this report. Also included are maps showing results of multivariate statistical analyses. Information on the field and analytical procedures used by the Los Alamos National Laboratory during sample collection and analysis may be found in any HSSR data release prepared by the Laboratory and will not be included in this report.

  8. Characterization of U-Mo Foils for AFIP-7

    SciTech Connect (OSTI)

    Edwards, Danny J.; Ermi, Ruby M.; Schemer-Kohrn, Alan L.; Overman, Nicole R.; Henager, Charles H.; Burkes, Douglas; Senor, David J.

    2012-11-07

    Twelve AFIP in-process foil samples, fabricated by either Y-12 or LANL, were shipped from LANL to PNNL for potential characterization using optical and scanning electron microscopy techniques. Of these twelve, nine different conditions were examined to one degree or another using both techniques. For this report a complete description of the results are provided for one archive foil from each source of material, and one unirradiated piece of a foil of each source that was irradiated in the Advanced Test Reactor. Additional data from two other LANL conditions are summarized in very brief form in an appendix. The characterization revealed that all four characterized conditions contained a cold worked microstructure to different degrees. The Y-12 foils exhibited a higher degree of cold working compared to the LANL foils, as evidenced by the highly elongated and obscure U-Mo grain structure present in each foil. The longitudinal orientations for both of the Y-12 foils possesses a highly laminar appearance with such a distorted grain structure that it was very difficult to even offer a range of grain sizes. The U-Mo grain structure of the LANL foils, by comparison, consisted of a more easily discernible grain structure with a mix of equiaxed and elongated grains. Both materials have an inhomogenous grain structure in that all of the characterized foils possess abnormally coarse grains.

  9. Annual Energy Outlook 2015 - Appendix F

    Gasoline and Diesel Fuel Update (EIA)

    8 Regional maps Figure F7. Coal demand regions Figure F7. Coal Demand Regions CT,MA,ME,NH,RI,VT OH 1. NE 3. S1 4. S2 5. GF 6. OH 7. EN AL,MS MN,ND,SD IA,NE,MO,KS TX,LA,OK,AR MT,WY,ID CO,UT,NV AZ,NM 9. AM 11. C2 12. WS 13. MT 14. CU 15. ZN WV,MD,DC,DE 2. YP Region Content Region Code NY,PA,NJ VA,NC,SC GA,FL IN,IL,MI,WI Region Content Region Code 14. CU 13. MT 16. PC 15. ZN 12. WS 11. C2 9. AM 5. GF 8. KT 4. S2 7. EN 6. OH 2. YP 1. NE 3. S1 10. C1 KY,TN 8. KT 16. PC AK,HI,WA,OR,CA 10. C1

  10. New Generation of MoSx Based Solid Lubricant Coatings: Recent Developments and Applications

    SciTech Connect (OSTI)

    Haider, Julfikar; Hashmi, M. S. J.

    2011-01-17

    In recent times, there is a growing interest in applying Molybdenum disulphide (MoS{sub x}) solid lubricant coatings on components to improve the tribological performance (i.e. lower friction coefficient and wear rate). The tribological performance of MoS{sub x} coating is strongly dependent on coating properties and tribological environment. MoS{sub x} coatings are highly successful in certain applications such as in space/vacuum technology, but its effectiveness is questioned in other terrestrial applications such as in cutting tool industry due to its lower hardness and poor oxidation resistance leading to shorter life. In order to circumvent this drawback, the paper identifies that current research is being concentrated on developing MoS{sub x} based coatings using three different approaches: (1) Metal or compound addition in MoS{sub x} coating (2)MoS{sub x} layer on hard coating and (3)MoS{sub x} addition in hard coating matrix. Although the primary objective is same in all three cases, the third approach is considered to be more effective in improving the tribological properties of the coating. Finally, the potential applications of MoS{sub x} based coatings in different industrial sectors have been briefly outlined.

  11. Photo-oxidation method using MoS2 nanocluster materials

    DOE Patents [OSTI]

    Wilcoxon, Jess P. (Albuquerque, NM)

    2001-01-01

    A method of photo-oxidizing a hydrocarbon compound is provided by dispersing MoS.sub.2 nanoclusters in a solvent containing a hydrocarbon compound contaminant to form a stable solution mixture and irradiating the mixture to photo-oxide the hydrocarbon compound. Hydrocarbon compounds of interest include aromatic hydrocarbon and chlorinated hydrocarbons. MoS.sub.2 nanoclusters with an average diameter less than approximately 10 nanometers are shown to be effective in decomposing potentially toxic aromatic and chlorinated hydrocarbons, such as phenol, pentachlorophenol, chlorinated biphenols, and chloroform, into relatively non-toxic compounds. The irradiation can occur by exposing the MoS.sub.2 nanoclusters and hydrocarbon compound mixture with visible light. The MoS.sub.2 nanoclusters can be introduced to the toxic hydrocarbons as either a MoS.sub.2 solution or deposited on a support material.

  12. Synthesis and characterization of model MgO supported catalyst with Pt-Mo interactions.

    SciTech Connect (OSTI)

    Alexeev, O.; Kawi, S.; Gates, B.C. [Univ. of California, Davis, CA (United States)] [Univ. of California, Davis, CA (United States); Shelef, M. [Ford Motor Co., Dearborn, MI (United States)] [Ford Motor Co., Dearborn, MI (United States)

    1996-01-04

    MgO supported platinum and platinum-molybdenum catalysts were prepared from organometallic precursors and charaterized structurally to determine how the nature of the bimetallic precursors and the treatment conditions affected the interaction between the two metals. Samples were prepared from [PtCl{sub 2}(PhCN){sub 2}], [PtCl{sub 2}(PhCN){sub 2}] + [Mo(CO){sub 6}], and [C@Pt[Mo(CO){sub 3}(C{sub 5}H{sub 5})]{sub 2}(PhCN){sub 2}] BC@ characterized by infrared and extended X-ray absorption fine structure (EXAFS) spectroscopies, tranmission electron microscopy, and chemisorption of H{sub 2}, CO, and O{sub 2}. The samples were treated in H{sub 2} at 400{degree}C prior to most of the characterizatons. Incorporation of Mo reduced the chemisorption of CO and of H{sub 2}. EXAFS spectra measured at the Pt L{sub III} edge and at the Mo K edge showed substantial Pt-Mo contributions with a Pt-Mo cordination number of about 2 and an average distance of 2.63 A for the sample prepared from [C@Pt[Mo(CO){sub 3}(C{sub 5}H{sub 5})]{sub 2}(PhCN){sub 2}] BC@. In constract, no significant Pt-Mo contribution was observed for the sample prepared from [PtCl{sub 2}(PhCN){sub 2}]+ [Mo(CO){sub 6}]. Electron micrographs and EXAFS results show that interaction between Pt and Mo ions in the former sample helped to maintain the platinum in a highly dispersed form, with supported platinum clusters being smaller than about 10 A. 53 refs., 9 figs., 9 tabs.

  13. Amplitude Analysis and Measurement of the Time-dependent CP Asymmetry of B0 to KsKsKs Decays

    SciTech Connect (OSTI)

    Lees, J.P.

    2012-04-11

    We present the first results on the Dalitz-plot structure and improved measurements of the time-dependent CP-violation parameters of the process B{sup 0} {yields} K{sub S}{sup 0}K{sub S}{sup 0}K{sub S}{sup 0} obtained using 468 x 10{sup 6} B{bar B} decays collected with the BABAR detector at the PEP-II asymmetric-energy B factory at SLAC. The Dalitz-plot structure is probed by a time-integrated amplitude analysis that does not distinguish between B{sup 0} and {bar B}{sup 0} decays. We measure the total inclusive branching fraction {Beta}(B{sup 0} {yields} K{sub S}{sup 0}K{sub S}{sup 0}K{sub S}{sup 0}) = (6.19 {+-} 0.48 {+-} 0.15 {+-} 0.12) x 10{sup -6}, where the first uncertainty is statistical, the second is systematic, and the third represents the Dalitz-plot signal model dependence. We also observe evidence for the intermediate resonant states f{sub 0}(980), f{sub 0}(1710), and f{sub 2}(2010). Their respective product branching fractions are measured to be (2.70{sub -1.19}{sup +1.25} {+-} 0.36 {+-} 1.17) x 10{sup -6}, (0.50{sub -0.24}{sup +0.46} {+-} 0.04 {+-} 0.10) x 10{sup -6}, and (0.54{sub -0.20}{sup +0.21} {+-} 0.03 {+-} 0.52) x 10{sup -6}. Additionally, we determine the mixing-induced CP-violation parameters to be S = -0.94{sub -0.21}{sup +0.24} {+-} 0.06 and C = -0.17 {+-} 0.18 {+-} 0.04, where the first uncertainty is statistical and the second is systematic. These values are in agreement with the standard model expectation.

  14. XRD micro-XANES EMPA and SIMS investigation on phlogopite single crystals from Mt. Vulture (Italy)

    SciTech Connect (OSTI)

    F Scordari; M Dyar; E Schingaro; M Lacalamita; L Ottolini

    2011-12-31

    Selected phlogopite flakes from Mt. Vulture in southern Italy were studied using a combination of single-crystal techniques: electron microprobe analysis (EMPA), secondary ion mass spectrometry (SIMS), single-crystal X-ray diffraction (SCXRD), and micro-X-ray absorption near-edge spectroscopy (XANES). The latter technique was employed to analyze the structure of the Fe-K absorption edge over the region from 7080-8100 eV and to determine Fe{sup 3+}/{Sigma}Fe at a micrometer scale, albeit with large error bars due to known effects of orientation on pre-edge energy. The annite component, Fe/(Mg+Fe), of the samples studied ranged from 0.16 to 0.31, the Ti content from 0.11 to 0.27 atoms per formula unit (apfu) and the Ba content from 0.03 to 0.09 apfu. SIMS analysis showed H{sub 2}O (wt%) = 1.81-3.30, F (wt%) = 0.44-1.29, and Li{sub 2}O (wt%) = 0.001-0.027. The intra single-crystal chemical variability for major/minor elements (Mg, Fe, Al, Ba, Ti, and K) was found particularly significant for samples VUT191{_}11 and PG5{_}1, less significant for the other samples of the set. SIMS data relative to crystals VUT187{_}24, VUT191{_}10, VUT191{_}11, and VUT187{_}28 showed a noteworthy variation in the concentrations of some light elements (H, Li, and F) with coefficient of variation CV (as 1{sigma}%) up to {approx}18% for H{sub 2}O. The analyzed micas belong to the 1M polytype. Structure refinements using anisotropic displacement parameters were performed in space group C2/m and converged at 3.08 {<=} R {<=} 3.63, 3.32 {<=} R{sub w} {<=} 3.98%. Micro-XANES results yielded Fe{sup 3+}/{Sigma}Fe from 51-93%. Previous Moessbauer data from powdered samples suggested Fe{sup 3+}/{Sigma}Fe values ranging from 49-87%. However, the Fe{sup 3+} content determined by both techniques is sometimes remarkably different, in part because of the large errors ({+-}10-15%) presently associated with the micro-XANES technique and in part because the Fe{sup 3+} content of a single crystal may significantly depart from the average value obtained from routine Moessbauer analysis. The combination of EMPA, SIMS, and micro-XANES resulted in the characterization of the samples at a comparable spatial scale. By means of in-situ data and the results of crystallographic investigations, the occurrence of different relative amounts of M{sup 3+}-oxy [{sup VI}M{sup 2+} + (OH){sup -} {leftrightarrow} {sup VI}M{sup 3+} + O{sup 2-} + {1/2}H{sub 2}{up_arrow}], Ti-oxy substitutions [{sup VI}M{sup 2+} + 2(OH){sup -} {leftrightarrow} {sup VI}Ti{sup 4+} + 2O{sup 2-} + H{sub 2}{up_arrow}], and Ti-vacancy ({open_square}) substitution (2{sup VI}M{sup 2+} {leftrightarrow} {sup VI}Ti{sup 4+} + {sup VI}{open_square}) was ascertained for the studied samples.

  15. Microsoft Word - Gage-KS.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Intercomparisons of Cloud Observations from the AL S-band Profiler and the ETL K-band Millimeter-Wave Cloud Radar on the R/V Ronald H. Brown during Nauru99 K. S. Gage and D. A. Carter National Oceanic and Atmospheric Administration Aeronomy Laboratory Boulder, Colorado P. E. Johnston and C. R. Williams Cooperative Institute for Research in Environmental Sciences University of Colorado Boulder, Colorado M. Ryan Science Technology Corporation Boulder, Colorado D. Hazen and B. W. Orr National

  16. Print

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    < 5k 0 < 50k < 100k < 250k < 500k < 1M > 1M > 5M > 10M DE MD DC MA RI NJ AZ UT WY ID OR WA CA TX OK KS CO NE SD ND MN WI IL IA MO AR LA MS AL FL GA TN KY IN OH MI ME NH CT VT NY PA WV VA NC SC MT AK HI NV NM Princeton Plasma Physics Laboratory Procured Materials and Services 2015 (> $35M) Small business procurements in US: $14.73M

  17. Annual Energy Outlook 2015 - Appendix B

    Gasoline and Diesel Fuel Update (EIA)

    5 U.S. Energy Information Administration | Annual Energy Outlook 2015 Regional maps Figure F4. Oil and gas supply model regions F-5 U.S. Energy Information Administration | Annual Energy Outlook 2014 Regional maps Figure F4. Oil and gas supply model regions Figure F4. Oil and Gas Supply Model Regions Atlantic WA MT WY ID NV UT CO AZ NM OK IA KS MO IL IN KY TN MS AL FL GA SC NC WV PA NJ MD DE NY CT ME RI MA NH VA WI MI OH NE SD MN ND AR OR CA VT East (1) Gulf of Mexico LA Gulf Coast (2)

  18. Annual Energy Outlook 2015 - Appendix F

    Gasoline and Diesel Fuel Update (EIA)

    1 U.S. Energy Information Administration | Annual Energy Outlook 2015 Source: U.S. Energy Information Administration, Office of Energy Analysis. U.S. Energy Information Administration / Annual Energy Outlook 2010 213 Appendix F Regional Maps Figure F1. United States Census Divisions Pacific South Atlantic Middle Atlantic New England West South Central West North Central East North Central Mountain AK WA MT WY ID NV UT CO AZ NM TX OK IA KS MO IL IN KY TN MS AL FL GA SC NC WV PA NJ MD DE NY CT VT

  19. Annual Energy Outlook 2015 - Appendix F

    Gasoline and Diesel Fuel Update (EIA)

    7 U.S. Energy Information Administration | Annual Energy Outlook 2015 Regional maps Figure F6. Coal supply regions WA ID OR CA NV UT TX OK AR MO LA MS AL GA FL TN SC NC KY VA WV WY CO SD ND MI MN WI IL IN OH MD PA NJ DE CT MA NH VT NY ME RI MT NE IA KS MI AZ NM 500 0 SCALE IN MILES APPALACHIA Northern Appalachia Central Appalachia Southern Appalachia INTERIOR NORTHERN GREAT PLAINS Eastern Interior Western Interior Gulf Lignite Dakota Lignite Western Montana Wyoming, Northern Powder River Basin

  20. padd map

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    FL PADD 4: Rocky Mountain PADD 5: West Coast PADD 2: Midwest PADD 1: East Coast PADD 3: Gulf Coast PADD1A: New England PADD1B: Central Atlantic PADD1C: Lower Atlantic Petroleum Administration for Defense Districts AK HI WA OR CA NV AZ MT WY CO UT ID ND SD NE KS OK MO MN WI MI IL IN OH KY TN IA NM TX AR LA AL MS WV VA NC SC GA FL ME NH VT NY PA NJ MD DE MA CT RI

  1. DOE Hydrogen and Fuel Cell Overview

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    DOE Hydrogen & Fuel Cell Overview Dr. Sunita Satyapal Program Manager U.S. Department of Energy Fuel Cell Technologies Program DOE/CESA/TTC Hydrogen and Fuel Cells Webinar December 14, 2010 2 Examples of DOE-funded Partners and Locations - Fuel Cell Technologies Program TX NM AZ NC AR CA CO HI WA IL KY MA MN MO MS AL NV TN UT WV ID FL MI ND OR OH IN MT WY IO NE KS OK AK LA GA WI SC VA PA DE MD DC NJ NY RI CT VT NH ME SD Source: US DOE 12/2010 2 3 Fuel Cells: Addressing Energy Challenges 4

  2. EIA-912.xls

    Gasoline and Diesel Fuel Update (EIA)

    Month 2 0 Address 2: City: State: Zip: - to meet the due date. Report volumes in million cubic feet (MMcf) @14.73 psia-60⁰ F.) No East Region (Million Cubic Feet) South Central Region (Million Cubic Feet) Midwest Region (Million Cubic Feet) Mountain Region (Million Cubic Feet) (AZ, CO, ID, MT, NE, ND, NM, NV, SD, UT, & WY) Midwest Region (Million Cubic Feet) (IL, IN, IA, KY, MI, MN, MO, TN, & WI) South Central Region (Million Cubic Feet) (AL, AR, KS, LA, MS, OK, & TX) Mountain

  3. Buildings Energy Data Book: 3.9 Educational Facilities

    Buildings Energy Data Book [EERE]

    6 2010 Regional New Construction and Renovations Expenditures for Public K-12 Schools ($Million) Region New Schools Additions Renovation Total Region 1 (CT, MA, ME, NH, RI, VT) Region 2 (NJ, NY, PA) Region 3 (DE, MD, VA, WV) Region 4 (KY, NC, SC, TN) Region 5 (AL, FL, GA, MS) Region 6 (IN, MI, OH) Region 7 (IL, MN, WI) Region 8 (IA, KS, MO, NE) Region 9 (AR, LA, OK, TX) Region 10 (CO, MT, ND, NM, SD, UT, WY) Region 11 (AZ, CA, HI, NV) Region 12 (AK, ID, OR, WA) Total Source(s): School Planning

  4. Surface Structures of Cubo-octahedral Pt-Mo Catalyst Nanoparticles from Monte Carlo Simulations

    SciTech Connect (OSTI)

    Wang, Guofeng; Van Hove, M.A.; Ross, P.N.; Baskes, M.I.

    2005-03-31

    The surface structures of cubo-octahedral Pt-Mo nanoparticles have been investigated using the Monte Carlo method and modified embedded atom method potentials that we developed for Pt-Mo alloys. The cubo-octahedral Pt-Mo nanoparticles are constructed with disordered fcc configurations, with sizes from 2.5 to 5.0 nm, and with Pt concentrations from 60 to 90 at. percent. The equilibrium Pt-Mo nanoparticle configurations were generated through Monte Carlo simulations allowing both atomic displacements and element exchanges at 600 K. We predict that the Pt atoms weakly segregate to the surfaces of such nanoparticles. The Pt concentrations in the surface are calculated to be 5 to 14 at. percent higher than the Pt concentrations of the nanoparticles. Moreover, the Pt atoms preferentially segregate to the facet sites of the surface, while the Pt and Mo atoms tend to alternate along the edges and vertices of these nanoparticles. We found that decreasing the size or increasing the Pt concentration leads to higher Pt concentrations but fewer Pt-Mo pairs in the Pt-Mo nanoparticle surfaces.

  5. Searches for supersymmetry using the MT2 variable in hadronic events produced in pp collisions at 8 TeV

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Khachatryan, V.

    2015-05-15

    Searches for supersymmetry (SUSY) are performed using a sample of hadronic events produced in 8 TeV pp collisions at the CERN LHC. The searches are based on the MT2 variable, which is a measure of the transverse momentum imbalance in an event. The data were collected with the CMS detector and correspond to an integrated luminosity of 19.5 fb?. Two related searches are performed. The first is an inclusive search based on signal regions defined by the value of the MT2 variable, the hadronic energy in the event, the jet multiplicity, and the number of jets identified as originating frommorebottom quarks. The second is a search for a mass peak corresponding to a Higgs boson decaying to a bottom quark-antiquark pair, where the Higgs boson is produced as a decay product of a SUSY particle. For both searches, the principal backgrounds are evaluated with data control samples. No significant excess over the expected number of background events is observed, and exclusion limits on various SUSY models are derived.less

  6. LOCA simulation in the national research universal reactor program: postirradiation examination results for the third materials experiment (MT-3)

    SciTech Connect (OSTI)

    Rausch, W.N.

    1984-04-01

    A series of in-reactor experiments were conducted using full-length 32-rod pressurized water reactor (PWR) fuel bundles as part of the Loss-of-Coolant Accident (LOCA) Simulation Program. The third materials experiment (MT-3) was the sixth in the series of thermal-hydraulic and materials deformation/rutpure experiments conducted in the National Research Universal (NRU) reactor, Chalk River, Ontario, Canada. The main objective of the experiment was to evaluate ballooning and rupture during active two-phase cooling in the temperature range from 1400 to 1500/sup 0/F (1030 to 1090 K). The 12 test rods in the center of the 32-rod bundle were initially pressurized to 550 psi (3.8 MPa) to insure rupture in the correct temperature range. All 12 of the rods ruptured, with an average peak bundle strain of approx. 55%. The UKAEA also funded destructive postirradiation examination (PIE) of several of the ruptured rods from the MT-3 experiment. This report describes the work performed and presents the PIE results. Information obtained during the PIE included cladding thickness measurements metallography, and particle size analysis of the cracked and broken fuel pellets.

  7. Distributed Production of Radionuclide Mo-99 Charles A. Gentile, Adam B.

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cohen and George Ascione | Princeton Plasma Physics Lab Distributed Production of Radionuclide Mo-99 Charles A. Gentile, Adam B. Cohen and George Ascione This invention is for the production of Technetium-99m (Tc-99m), a widely used medical isotope in a distributed and in-situ fashion. Tc-99m results when Molybdenum 99 (Mo-99) decays. Mo-99 is typically produced in a nuclear reactor, but it can be produced from naturally occurring Molybdenum 100 or from Molybdenum 98 using either neutrons or

  8. Monolayers of MoS{sub 2} as an oxidation protective nanocoating material

    SciTech Connect (OSTI)

    Sen, H. Sener; Sahin, H.; Peeters, F. M.; Durgun, E.

    2014-08-28

    First-principle calculations are employed to investigate the interaction of oxygen with ideal and defective MoS{sub 2} monolayers. Our calculations show that while oxygen atoms are strongly bound on top of sulfur atoms, the oxygen molecule only weakly interacts with the surface. The penetration of oxygen atoms and molecules through a defect-free MoS{sub 2} monolayer is prevented by a very high diffusion barrier indicating that MoS{sub 2} can serve as a protective layer for oxidation. The analysis is extended to WS{sub 2} and similar coating characteristics are obtained. Our calculations indicate that ideal and continuous MoS{sub 2} and WS{sub 2} monolayers can improve the oxidation and corrosion-resistance of the covered surface and can be considered as an efficient nanocoating material.

  9. Microscopic origin of low frequency noise in MoS{sub 2} field-effect transistors

    SciTech Connect (OSTI)

    Ghatak, Subhamoy; Jain, Manish; Ghosh, Arindam; Mukherjee, Sumanta; Sarma, D. D.

    2014-09-01

    We report measurement of low frequency 1/f noise in molybdenum di-sulphide (MoS{sub 2}) field-effect transistors in multiple device configurations including MoS{sub 2} on silicon dioxide as well as MoS{sub 2}-hexagonal boron nitride (hBN) heterostructures. All as-fabricated devices show similar magnitude of noise with number fluctuation as the dominant mechanism at high temperatures and density, although the calculated density of traps is two orders of magnitude higher than that at the SiO{sub 2} interface. Measurements on the heterostructure devices with vacuum annealing and dual gated configuration reveals that along with the channel, metal-MoS{sub 2} contacts also play a significant role in determining noise magnitude in these devices.

  10. File:USDA-CE-Production-GIFmaps-MO.pdf | Open Energy Information

    Open Energy Info (EERE)

    MO.pdf Jump to: navigation, search File File history File usage Missouri Ethanol Plant Locations Size of this preview: 776 600 pixels. Full resolution (1,650 1,275 pixels,...

  11. Substrate interactions with suspended and supported monolayer MoS2: Angle-resolved photoemission spectroscopy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Jin, Wencan; Yeh, Po -Chun; Zaki, Nader; Zhang, Datong; Liou, Jonathan T.; Dadap, Jerry I.; Barinov, Alexey; Yablonskikh, Mikhail; Sadowski, Jerzy T.; Sutter, Peter; et al

    2015-03-17

    We report the directly measured electronic structure of exfoliated monolayer molybdenum disulfide (MoS₂) using micrometer-scale angle-resolved photoemission spectroscopy. Measurements of both suspended and supported monolayer MoS₂ elucidate the effects of interaction with a substrate. Thus, a suggested relaxation of the in-plane lattice constant is found for both suspended and supported monolayer MoS₂ crystals. For suspended MoS₂, a careful investigation of the measured uppermost valence band gives an effective mass at Γ¯ and Κ¯ of 2.00m₀ and 0.43m₀, respectively. We also measure an increase in the band linewidth from the midpoint of Γ¯Κ¯ to the vicinity of Κ¯ and briefly discussmore » its possible origin.« less

  12. DE-EM-0001971 WIPP M&O J-8 PART III - LIST OF DOCUMENTS, EXHIBITS...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    8 PART III - LIST OF DOCUMENTS, EXHIBITS AND OTHER ATTACHMENTS SECTION J ATTACHMENT C: DRAFT PERFORMANCE EVALUATION AND MEASUREMENT PLAN (PEMP) DE-EM-0001971 WIPP M&O J-9 Draft...

  13. Electrochemical Testing of Ni-Cr-Mo-Gd Alloys

    SciTech Connect (OSTI)

    T. E. Lister; R. E. Mizia; H. Tian

    2005-10-01

    The waste package site recommendation design specified a boron-containing stainless steel, Neutronit 976/978, for fabrication of the internal baskets that will be used as a corrosion-resistant neutron-absorbing material. Recent corrosion test results gave higher-than-expected corrosion rates for this material. The material callout for these components has been changed to a Ni-Cr-Mo-Gd alloy (ASTM-B 932-04, UNS N06464) that is being developed at the Idaho National Laboratory. This report discusses the results of initial corrosion testing of this material in simulated in-package environments that could contact the fuel baskets after breach of the waste package outer barrier. The corrosion test matrix was executed using the potentiodynamic and potentiostatic electrochemical test techniques. The alloy performance shows low rates of general corrosion after initial removal of a gadolinium-rich second phase that intersects the surface. The high halide-containing test solutions exhibited greater tendencies toward initiation of crevice corrosion.

  14. Thermo-physical Properties of DU-10 wt.% Mo Alloys

    SciTech Connect (OSTI)

    Douglas E. Burkes; Cynthia A. Papesch; Andrew P. Maddison; Thomas Hartmann; Francine J. Rice

    2010-08-01

    Low-enriched uranium alloyed with 10 wt% molybdenum is under consideration by the Global Threat Reduction Initiative reactor convert program as a very high density fuel to enable the conversion of high-performance research reactors away from highly-enriched uranium fuels. As with any fuel development program, the thermophysical properties of the fuel as a function of temperature are extremely important and must be well characterized in order to effectively model and predict fuel behavior under normal and off-normal irradiation conditions. For the alloy system under investigation, there is a lack of thermophysical property data, and in most cases, the data is relatively inconsistent and lacks sufficient explanation. Available literature on this alloy system comes mainly from studies done during the 1960s and 1970s, and often does not include sufficient information on fabrication history or conditions to draw conclusions for the current application. The current paper has investigated specific heat capacity, coefficient of linear thermal expansion, density, and thermal diffusivity that were then used to calculate alloy thermal conductivity as a function of temperature. The data obtained from this investigation was compared to available literature on similar U-Mo alloys, and in most cases are in good agreement.

  15. Rotationally Commensurate Growth of MoS[subscript 2] on Epitaxial Graphene

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect SciTech Connect Search Results Journal Article: Rotationally Commensurate Growth of MoS[subscript 2] on Epitaxial Graphene Citation Details In-Document Search Title: Rotationally Commensurate Growth of MoS[subscript 2] on Epitaxial Graphene Authors: Liu, Xiaolong ; Balla, Itamar ; Bergeron, Hadallia ; Campbell, Gavin P. ; Bedzyk, Michael J. ; Hersam, Mark C. [1] + Show Author Affiliations NWU Publication Date: 2016-03-04 OSTI Identifier: 1240188 Resource

  16. Demonstration of LED Street Lighting in Kansas City, MO (Technical Report)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    | SciTech Connect Demonstration of LED Street Lighting in Kansas City, MO Citation Details In-Document Search Title: Demonstration of LED Street Lighting in Kansas City, MO Nine different streetlighting products were installed on various streets in Kansas City, Missouri during February, 2011, to evaluate their performance relative to the incumbent high-pressure sodium (HPS) lighting. The applications investigated included 100 W, 150 W, 250 W, and 400 W HPS installations. Initial measurements

  17. DOE - Office of Legacy Management -- Weldon Spring Chemical Co - MO 03

    Office of Legacy Management (LM)

    Weldon Spring Chemical Co - MO 03 FUSRAP Considered Sites Site: Weldon Spring Chemical Co. (MO.03) Designated Name: Alternate Name: Location: Evaluation Year: Site Operations: Site Disposition: Radioactive Materials Handled: Primary Radioactive Materials Handled: Radiological Survey(s): Site Status: Also see Weldon Spring, Missouri, Site Documents Related to Weldon Spring Chemical Co. Summary of Work Session - Focus Area: Monitoring and Maintenance. Summary of Weldon Spring Long-Term Stewardship

  18. High reflectance and low stress Mo2C/Be multilayers

    DOE Patents [OSTI]

    Bajt, Sasa (Livermore, CA); Barbee, Jr., Troy W. (Palo Alto, CA)

    2001-01-01

    A material for extreme ultraviolet (EUV) multilayers that will reflect at about 11.3 nm, have a high reflectance, low stress, and high thermal and radiation stability. The material consists of alternating layers of Mo.sub.2 C and Be deposited by DC magnetron sputtering on a substrate, such as silicon. In one example a Mo.sub.2 C/Be multilayer gave 65.2% reflectance at 11.25 nm measured at 5 degrees off normal incidence angle, and consisted of 70 bilayers with a deposition period of 5.78 nm, and was deposited at 0.83 mTorr argon (Ar) sputtering pressure, with the first and last layers being Be. The stress of the multilayer is tensile and only +88 MPa, compared to +330 MPa of a Mo/Be multilayers of the same thickness. The Mo.sub.2 C/Be multilayer was capped with carbon which produced an increase in reflectivity of about 7% over a similar multilayer with no carbon capping material, thus raising the reflectivity from 58.3% to over 65%. The multilayers were formed using either Mo.sub.2 C or Be as the first and last layers, and initial testing has shown the formation of beryllium carbide at the interfaces between the layers which both stabilizes and has a smoothing effect, and appear to be smoother than the interfaces in Mo/Be multilayers.

  19. Stability of precipitate phases in Fe-rich Fe-Cr-Ni-Mo alloys

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yang, Ying; Tan, Lizhen; Busby, Jeremy T

    2015-01-01

    Understanding the stability of precipitate phases in the Fe-rich Fe-Cr-Ni-Mo alloys is critical to the alloy design and application of Mo-containing Austenitic steels. Coupled with thermodynamic modeling, stability of the and phases in two Fe-Cr-Ni-Mo alloys were investigated at 1000, 850 and 700 C for different annealing time. The morphologies, compositions and crystal structures of the matrix and precipitate phases were carefully examined by Scanning Electron Microscopy, Electron Probe Microanalysis, X-ray diffraction and Transmission Electron Microscopy. Two key findings resulted from this work. One is that the phase is stable at high temperature and transformed into the phase at lowmoretemperature. The other is that both the and phases have large solubilites of Cr, Mo and Ni, among which the Mo solubility has a major role on the relative stability of the precipitate phases. The developed thermodynamic models were then applied to evaluating the Mo effect on the stability of precipitate phases in AISI 316 and NF709 alloys.less

  20. Thermal stability of intermetallic phases in Fe-rich Fe-Cr-Ni-Mo alloys

    SciTech Connect (OSTI)

    Yang, Ying; Tan, Lizhen; Busby, Jeremy T.

    2015-06-12

    Understanding the stability of precipitate phases in the Fe-rich Fe-Cr-Ni-Mo alloys is critical to the alloy design and application of Mo-containing Austenitic steels. Coupled with thermodynamic modeling, stability of the chi and Laves phases in two Fe-Cr-Ni-Mo alloys were investigated at 1000, 850 and 700 °C for different annealing time. The morphologies, compositions and crystal structures of the matrix and precipitate phases were carefully examined by Scanning Electron Microscopy, Electron Probe Microanalysis, X-ray diffraction and Transmission Electron Microscopy. The two key findings resulted from this work. One is that the chi phase is stable at high temperature and transformed into the Laves phase at low temperature. The other is that both the chi and Laves phases have large solubilites of Cr, Mo and Ni, among which the Mo solubility has a major role on the relative stability of the precipitate phases. The developed thermodynamic models were then applied to evaluating the Mo effect on the stability of precipitate phases in AISI 316 and NF709 alloys.

  1. Thermal stability of intermetallic phases in Fe-rich Fe-Cr-Ni-Mo alloys

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yang, Ying; Tan, Lizhen; Busby, Jeremy T.

    2015-06-12

    Understanding the stability of precipitate phases in the Fe-rich Fe-Cr-Ni-Mo alloys is critical to the alloy design and application of Mo-containing Austenitic steels. Coupled with thermodynamic modeling, stability of the chi and Laves phases in two Fe-Cr-Ni-Mo alloys were investigated at 1000, 850 and 700 °C for different annealing time. The morphologies, compositions and crystal structures of the matrix and precipitate phases were carefully examined by Scanning Electron Microscopy, Electron Probe Microanalysis, X-ray diffraction and Transmission Electron Microscopy. The two key findings resulted from this work. One is that the chi phase is stable at high temperature and transformed intomore » the Laves phase at low temperature. The other is that both the chi and Laves phases have large solubilites of Cr, Mo and Ni, among which the Mo solubility has a major role on the relative stability of the precipitate phases. The developed thermodynamic models were then applied to evaluating the Mo effect on the stability of precipitate phases in AISI 316 and NF709 alloys.« less

  2. Effects of thermal treatment on the co-rolled U-Mo fuel foils

    SciTech Connect (OSTI)

    Dennis D. Keiser, Jr.; Tammy L. Trowbridge; Cynthia R. Breckenridge; Brady L. Mackowiak; Glenn A. Moore; Barry H. Rabin; Mitchell K. Meyer

    2014-11-01

    A monolithic fuel type is being developed to convert US high performance research and test reactors such as Advanced Test Reactor (ATR) at Idaho National Laboratory from highly enriched uranium (HEU) to low-enriched uranium (LEU). The interaction between the cladding and the U-Mo fuel meat during fuel fabrication and irradiation is known to have negative impacts on fuel performance, such as mechanical integrity and dimensional stability. In order to eliminate/minimize the direct interaction between cladding and fuel meat, a thin zirconium diffusion barrier was introduced between the cladding and U-Mo fuel meat through a co-rolling process. A complex interface between the zirconium and U-Mo was developed during the co-rolling process. A predictable interface between zirconium and U-Mo is critical to achieve good fuel performance since the interfaces can be the weakest link in the monolithic fuel system. A post co-rolling annealing treatment is expected to create a well-controlled interface between zirconium and U-Mo. A systematic study utilizing post co-rolling annealing treatment has been carried out. Based on microscopy results, the impacts of the annealing treatment on the interface between zirconium and U-Mo will be presented and an optima annealing treatment schedule will be suggested. The effects of the annealing treatment on the fuel performance will also be discussed.

  3. MoS{sub 2} nanotube exfoliation as new synthesis pathway to molybdenum blue

    SciTech Connect (OSTI)

    Visic, B.; Gunde, M. Klanjsek; Kovac, J.; Iskra, I.; Jelenc, J.; Remskar, M.; Centre of Excellence Namaste, Jamova cesta 39, SI-1000 Ljubljana

    2013-02-15

    Graphical abstract: . Display Omitted Highlights: ? New synthesis approach to obtaining molybdenum blue via exfoliated MoS{sub 2} nanotubes. ? Material is prone to self assembly and is stable in high vacuum. ? Molecules are as small as 2 nm and their clusters are up to tens of nanometers. ? Change in absorption and oxidation states from the precursor MoS{sub 2}. -- Abstract: Molybdenum blue-type materials are usually obtained by partially reducing Mo{sup VI+} in acidic solutions, while in the presented method it is formed in ethanol solution of exfoliated MoS{sub 2} nanotubes, where the MoS{sub 2} flakes are the preferential location for their growth. Material was investigated by means of scanning electron and atomic force microscopy, showing the structure and self assembly, while also confirming that it is stable in high vacuum with molecules as small as 1.6 nm and the agglomerates of few tens of nanometres. The ultravioletvisible and photoelectron spectrometry show the change in absorption properties and oxidation states from MoS{sub 2} structure to molybdenum blue, while the presence of sulphur suggests that this is a new type of molybdenum blue material.

  4. Microstructure evolution of Li uptake/removal in MoO{sub 2}@C nanoparticles with high lithium storage performance

    SciTech Connect (OSTI)

    Liu, Yulong; Zhang, Hong; Ouyang, Pan; Chen, Wenhao [School of Materials Science and Engineering, Central South University, Changsha 410083 (China); Li, Zhicheng, E-mail: zhchli@mail.csu.edu.cn [School of Materials Science and Engineering, Central South University, Changsha 410083 (China); State Key Laboratory of Powder Metallurgy, Central South University, Changsha 410083 (China)

    2014-02-01

    Highlights: The carbon-coated MoO{sub 2} (MoO{sub 2}@C) ultra fine nanoparticles are synthesized by one-pot hydrothermal method. MoO{sub 2}@C nanoparticles have high specific capacity, excellent cycling performance and rate performance. Phase transformations for lithium ion uptake/removal are examined carefully by TEM. Phase transformations are highly reversible during the redox process. - Abstract: A facile one pot strategy of a hydrothermal methodology was applied to synthesize the carbon coated MoO{sub 2} (MoO{sub 2}@C) nanostructured particles, which are composed of ultra fine nanoparticles with homogeneous carbon coating about several nanometers. As an electrode in lithium ion batteries, the MoO{sub 2}@C shows a high specific capacity and reversible capacity (730 mA h g{sup ?1} after 60 cycles). Microstructure investigations, by using a high resolution transmission electron microscopy, of the MoO{sub 2}@C based electrodes employed at various states during the first discharge/charge cycle were conducted to elucidate the lithium ion uptake/removal mechanism and cycling behavior. In the lithium uptake process, the original MoO{sub 2} phase transfers into Li{sub 0.98}MoO{sub 2} through an addition type reaction, and then nanosized metallic Mo emerges as a result of a conversion reaction. In turn, Mo could be oxidized to the intermediate Li{sub 0.98}MoO{sub 2} before converting to hyperfine MoO{sub 2} phase on upcoming lithium removal process.

  5. The mitochondrial fatty acid synthesis (mtFASII) pathway is capable of mediating nuclear-mitochondrial cross talk through the PPAR system of transcriptional activation

    SciTech Connect (OSTI)

    Parl, Angelika; Mitchell, Sabrina L.; Clay, Hayley B.; Reiss, Sara; Li, Zhen; Murdock, Deborah G.

    2013-11-15

    Highlights: The function of the mitochondria fatty acid synthesis pathway is partially unknown. Overexpression of the pathway causes transcriptional activation through PPARs. Knock down of the pathway attenuates that activation. The last enzyme in the pathway regulates its own transcription. Products of the mtFASII pathway are able to drive nuclear transcription. -- Abstract: Mammalian cells contain two fatty acid synthesis pathways, the cytosolic FASI pathway, and the mitochondrial FASII pathway. The selection behind the conservation of the mitochondrial pathway is not completely understood, given the presence of the cytosolic FAS pathway. In this study, we show through heterologous gene reporter systems and PCR-based arrays that overexpression of MECR, the last step in the mtFASII pathway, causes modulation of gene expression through the PPAR pathway. Electromobility shift assays (EMSAs) demonstrate that overexpression of MECR causes increased binding of PPARs to DNA, while cell fractionation and imaging studies show that MECR remains localized to the mitochondria. Interestingly, knock down of the mtFASII pathway lessens the effect of MECR on this transcriptional modulation. Our data are most consistent with MECR-mediated transcriptional activation through products of the mtFASII pathway, although we cannot rule out MECR acting as a coactivator. Further investigation into the physiological relevance of this communication will be necessary to better understand some of the phenotypic consequences of deficits in this pathway observed in animal models and human disease.

  6. Doping against the native propensity of MoS₂: Degenerate hole doping by cation substitution

    SciTech Connect (OSTI)

    Suh, Joonki; Park, Tae-Eon; Lin, Der-Yuh; Fu, Deyi; Park, Joonsuk; Jung, Hee Joon; Chen, Yabin; Ko, Changhyun; Jang, Chaun; Sun, Yinghui; Sinclair, Robert; Chang, Joonyeon; Tongay, Sefaattin; Wu, Junqiao

    2014-12-10

    Layered transition metal dichalcogenides (TMDs) draw much attention as the key semiconducting material for two-dimensional electrical, optoelectronic, and spintronic devices. For most of these applications, both n- and p-type materials are needed to form junctions and support bipolar carrier conduction. However, typically only one type of doping is stable for a particular TMD. For example, molybdenum disulfide (MoS₂) is natively an n-type presumably due to omnipresent electron-donating sulfur vacancies, and stable/controllable p-type doping has not been achieved. The lack of p-type doping hampers the development of charge-splitting p–n junctions of MoS₂, as well as limits carrier conduction to spin-degenerate conduction bands instead of the more interesting, spin-polarized valence bands. Traditionally, extrinsic p-type doping in TMDs has been approached with surface adsorption or intercalation of electron-accepting molecules. However, practically stable doping requires substitution of host atoms with dopants where the doping is secured by covalent bonding. In this work, we demonstrate stable p-type conduction in MoS₂ by substitutional niobium (Nb) doping, leading to a degenerate hole density of ~3 × 10¹⁹ cm⁻³. Structural and X-ray techniques reveal that the Nb atoms are indeed substitutionally incorporated into MoS₂ by replacing the Mo cations in the host lattice. van der Waals p–n homojunctions based on vertically stacked MoS₂ layers are fabricated, which enable gate-tunable current rectification. A wide range of microelectronic, optoelectronic, and spintronic devices can be envisioned from the demonstrated substitutional bipolar doping of MoS₂. From the miscibility of dopants with the host, it is also expected that the synthesis technique demonstrated here can be generally extended to other TMDs for doping against their native unipolar propensity.

  7. MCNPX-CINDER'90 Simulation of Photonuclear Mo-99 Production Experiments

    SciTech Connect (OSTI)

    Kelsey, Charles T. IV [Los Alamos National Laboratory; Chemerizov, Sergey D. [Argonne National Laboratory; Dale, Gregory E. [Los Alamos National Laboratory; Harvey, James T. [NorthStar Medical Radioisotopes; Tkac, Peter [Argonne National Laboratory; Vandegrift, George R III [Argonne National Laboratory

    2011-01-01

    The MCNPX and CINDER'90 codes were used to support design of experiments investigating Mo-99 production with a 20-MeV electron beam. Bremsstrahlung photons produced by the electron beam interacting with the target drive the desired Mo-100({gamma},n)Mo-99 reaction, as well as many undesired reactions important to accurate prediction of radiation hazards. MCNPX is a radiation transport code and CINDER'90 is a transmutation code. They are routinely used together for accelerator activation calculations. Low energy neutron fluxes and production rates for nonneutron and high energy neutron induced reactions computed using MCNPX are inputs to CINDER'90. CINDER'90 presently has only a neutron reaction cross section library up to 25 MeV and normally the other reaction rates come from MCNPX physics models. For this work MCNPX photon flux tallies modified by energy response functions prepared from evaluated photonuclear cross section data were used to tally the reaction rates for CINDER'90 input. The cross section evaluations do not provide isomer to ground state yield ratios so a spin based approximation was used. Post irradiation dose rates were calculated using MCNPX with CINDER'90 produced decay photon spectra. The sensitivity of radionuclide activities and dose rates to beam parameters including energy, position, and profile, as well as underlying isomer assumptions, was investigated. Three experimental production targets were irradiated, two natural Mo and one Mo-100 enriched. Natural Mo foils upstream of the targets were used to analyze beam position and profile by exposing Gafchromic film to the foils after each irradiation. Activation and dose rate calculations were rerun after the experiments using measured beam parameters for comparison with measured Mo-99 activities and dose rates.

  8. In Situ Time-Resolved Characterization of Ni-MoO2 Catalysts for the Water-Gas Shift Reaction

    SciTech Connect (OSTI)

    Wen,W.; Calderon, J.; Brito, J.; Marinkovic, N.; Hanson, J.; Rodriquez, J.

    2008-01-01

    Active catalysts for the water-gas shift (WGS, CO + H2O ? H2 + CO2) reaction were synthesized from nickel molybdates ({beta}-NiMoO4 and nH2O{center_dot}NiMoO4) as precursors, and their structural transformations were monitored using in situ time-resolved X-ray diffraction and X-ray absorption near-edge spectroscopy. In general, the nickel molybdates were not stable and underwent partial reduction in the presence of CO or CO/H2O mixtures at high temperatures. The interaction of {beta}-NiMoO4 with the WGS reactants at 500 C led to the formation of a mixture of Ni (24 nm particle size) and MoO2 (10 nm particle size). These Ni-MoO2 systems displayed good catalytic activity at 350, 400, and 500 C. At 350 and 400 C, catalytic tests revealed that the Ni-MoO2 system was much more active than isolated Ni (some activity) or isolated MoO2 (negligible activity). Thus, cooperative interactions between the admetal and oxide support were probably responsible for the high WGS activity of Ni-MoO2. In a second synthetic approach, the NiMoO4 hydrate was reduced to a mixture of metallic Ni, NiO, and amorphous molybdenum oxide by direct reaction with H2 gas at 350 C. In the first pass of the water-gas shift reaction, MoO2 appeared gradually at 500 C with a concurrent increase of the catalytic activity. For these catalysts, the particle size of Ni (4 nm) was much smaller than that of the MoO2 (13 nm). These systems were found to be much more active WGS catalysts than Cu-MoO2, which in turn is superior to commercial low-temperature Cu-ZnO catalysts.

  9. Method for the production of .sup.99m Tc compositions from .sup.99 Mo-containing materials

    DOE Patents [OSTI]

    Bennett, Ralph G. (Idaho Falls, ID); Christian, Jerry D. (Idaho Falls, ID); Grover, S. Blaine (Idaho Falls, ID); Petti, David A. (Idaho Falls, ID); Terry, William K. (Idaho Falls, ID); Yoon, Woo Y. (Idaho Falls, ID)

    1998-01-01

    An improved method for producing .sup.99m Tc compositions from .sup.99 Mo compounds. .sup.100 Mo metal or .sup.100 MoO.sub.3 is irradiated with photons in a particle (electron) accelerator to ultimately produce .sup.99 MoO.sub.3. This composition is then heated in a reaction chamber to form a pool of molten .sup.99 MoO.sub.3 with an optimum depth of 0.5-5 mm. A gaseous mixture thereafter evolves from the molten .sup.99 MoO.sub.3 which contains vaporized .sup.99 MoO.sub.3, vaporized .sup.99m TcO.sub.3, and vaporized .sup.99m TcO.sub.2. This mixture is then combined with an oxidizing gas (O.sub.2(g)) to generate a gaseous stream containing vaporized .sup.99m Tc.sub.2 O.sub.7 and vaporized .sup.99 MoO.sub.3. Next, the gaseous stream is cooled in a primary condensation stage in the reaction chamber to remove vaporized .sup.99 MoO.sub.3. Cooling is undertaken at a specially-controlled rate to achieve maximum separation efficiency. The gaseous stream is then cooled in a sequential secondary condensation stage to convert vaporized .sup.99m Tc.sub.2 O.sub.7 into a condensed .sup.99m Tc-containing reaction product which is collected.

  10. Method for the production of {sup 99m}Tc compositions from {sup 99}Mo-containing materials

    DOE Patents [OSTI]

    Bennett, R.G.; Christian, J.D.; Grover, S.B.; Petti, D.A.; Terry, W.K.; Yoon, W.Y.

    1998-09-01

    An improved method is described for producing {sup 99m}Tc compositions from {sup 99}Mo compounds. {sup 100}Mo metal or {sup 100}MoO{sub 3} is irradiated with photons in a particle (electron) accelerator to ultimately produce {sup 99}MoO{sub 3}. This composition is then heated in a reaction chamber to form a pool of molten {sup 99}MoO{sub 3} with an optimum depth of 0.5--5 mm. A gaseous mixture thereafter evolves from the molten {sup 99}MoO{sub 3} which contains vaporized {sup 99}MoO{sub 3}, vaporized {sup 99m}TcO{sub 3}, and vaporized {sup 99m}TcO{sub 2}. This mixture is then combined with an oxidizing gas (O{sub 2(g)}) to generate a gaseous stream containing vaporized {sup 99m}Tc{sub 2}O{sub 7} and vaporized {sup 99}MoO{sub 3}. Next, the gaseous stream is cooled in a primary condensation stage in the reaction chamber to remove vaporized {sup 99}MoO{sub 3}. Cooling is undertaken at a specially-controlled rate to achieve maximum separation efficiency. The gaseous stream is then cooled in a sequential secondary condensation stage to convert vaporized {sup 99m}Tc{sub 2}O{sub 7} into a condensed {sup 99m}Tc-containing reaction product which is collected. 1 fig.

  11. Surface oxidation energetics and kinetics on MoS{sub 2} monolayer

    SciTech Connect (OSTI)

    KC, Santosh; Longo, Roberto C.; Wallace, Robert M.; Cho, Kyeongjae

    2015-04-07

    In this work, surface oxidation of monolayer MoS{sub 2} (one of the representative semiconductors in transition-metal dichalcogenides) has been investigated using density functional theory method. Oxygen interaction with MoS{sub 2} shows that, thermodynamically, the surface tends to be oxidized. However, the dissociative absorption of molecular oxygen on the MoS{sub 2} surface is kinetically limited due to the large energy barrier at low temperature. This finding elucidates the air stability of MoS{sub 2} surface in the atmosphere. Furthermore, the presence of defects significantly alters the surface stability and adsorption mechanisms. The electronic properties of the oxidized surface have been examined as a function of oxygen adsorption and coverage as well as substitutional impurities. Our results on energetics and kinetics of oxygen interaction with the MoS{sub 2} monolayer are useful for the understanding of surface oxidation, air stability, and electronic properties of transition-metal dichalcogenides at the atomic scale.

  12. TEM Characterization of High Burn-up Microstructure of U-7Mo Alloy

    SciTech Connect (OSTI)

    Jian Gan; Brandon Miller; Dennis Keiser; Adam Robinson; James Madden; Pavel Medvedev; Daniel Wachs

    2014-04-01

    As an essential part of global nuclear non-proliferation effort, the RERTR program is developing low enriched U-Mo fuels (< 20% U-235) for use in research and test reactors that currently employ highly enriched uranium fuels. One type of fuel being developed is a dispersion fuel plate comprised of U-7Mo particles dispersed in Al alloy matrix. Recent TEM characterizations of the ATR irradiated U-7Mo dispersion fuel plates include the samples with a local fission densities of 4.5, 5.2, 5.6 and 6.3 E+21 fissions/cm3 and irradiation temperatures of 101-136?C. The development of the irradiated microstructure of the U-7Mo fuel particles consists of fission gas bubble superlattice, large gas bubbles, solid fission product precipitates and their association to the large gas bubbles, grain subdivision to tens or hundreds of nanometer size, collapse of bubble superlattice, and amorphisation. This presentation will describe the observed microstructures specifically focusing on the U-7Mo fuel particles. The impact of the observed microstructure on the fuel performance and the comparison of the relevant features with that of the high burn-up UO2 fuels will be discussed.

  13. FeAl and Mo-Si-B Intermetallic Coatings Prepared by Thermal Spraying

    SciTech Connect (OSTI)

    Totemeier, T.C.; Wright, R.N.; Swank, W.D.

    2003-04-22

    FeAl and Mo-Si-B intermetallic coatings for elevated temperature environmental resistance were prepared using high-velocity oxy-fuel (HVOF) and air plasma spray (APS) techniques. For both coating types, the effect of coating parameters (spray particle velocity and temperature) on the microstructure and physical properties of the coatings was assessed. Fe-24Al (wt.%) coatings were prepared using HVOF thermal spraying at spray particle velocities varying from 540 m/s to 700 m/s. Mo-13.4Si-2.6B coatings were prepared using APS at particle velocities of 180 and 350 m/s. Residual stresses in the HVOF FeAl coatings were compressive, while stresses in the APS Mo-Si-B coatings were tensile. In both cases, residual stresses became more compressive with increasing spray particle velocity due to increased peening imparted by the spray particles. The hardness and elastic moduli of FeAl coatings also increased with increasing particle velocity, again due to an increased peening effect. For Mo-Si-B coatings, plasma spraying at 180 m/s resulted in significant oxidation of the spray particles and conversion of the T1 phase into amorphous silica and {alpha}-Mo. The T1 phase was retained after spraying at 350 m/s.

  14. Fragile structural transition in Mo3Sb7

    SciTech Connect (OSTI)

    Yan, Jiaqiang -Q.; McGuire, Michael A; May, Andrew F; Parker, David S.; Mandrus, D. G.; Sales, Brian C.

    2015-08-10

    Mo3Sb7 single crystals lightly doped with Cr, Ru, or Te are studied in order to explore the interplay between superconductivity, magnetism, and the cubic-tetragonal structural transition. The structural transition at 53 K is extremely sensitive to Ru or Te substitution which introduces additional electrons, but robust against Cr substitution. We observed no sign of a structural transition in superconducting Mo2.91Ru0.09Sb7 and Mo3Sb6.975Te0.025. In contrast, 3 at.% Cr doping only slightly suppresses the structural transition to 48 K while leaving no trace of superconductivity above 1.8 K. Analysis of magnetic properties suggests that the interdimer interaction in Mo3Sb7 is near a critical value and essential for the structural transition. Futhermore, all dopants suppress the superconductivity of Mo3Sb7. The tetragonal structure is not necessary for superconductivity.

  15. A polymorphism in metallothionein 1A (MT1A) is associated with cadmium-related excretion of urinary beta 2‐microglobulin

    SciTech Connect (OSTI)

    Lei, Lijian; Department of Epidemiology, School of Public Health, Shanxi Medical University, Shanxi ; Chang, Xiuli; Rentschler, Gerda; Tian, Liting; Zhu, Guoying; Chen, Xiao; Jin, Taiyi; Broberg, Karin

    2012-12-15

    Objectives: Cadmium (Cd) toxicity of the kidney varies between individuals despite similar exposure levels. In humans Cd is mainly bound to metallothioneins (MT), which scavenge its toxic effects. Here we analyzed whether polymorphisms in MT genes MT1A and MT2A influence Cd-related kidney damage. Methods: In a cross-sectional study N = 512 volunteers were selected from three areas in South-Eastern China, which to varying degree were Cd-polluted from a smelter (control area [median Cd in urine U-Cd = 2.67 μg/L], moderately [U-Cd = 4.23 μg/L] and highly [U-Cd = 9.13 μg/L] polluted areas). U-Cd and blood Cd (B-Cd) concentrations were measured by graphite-furnace atomic absorption spectrometry. MT1A rs11076161 (G/A), MT2A rs10636 (G/C) and MT2A rs28366003 (A/G) were determined by Taqman assays; urinary N-Acetyl-beta-(D)-Glucosaminidase (UNAG) by spectrometry, and urinary β2-microglobulin (UB2M) by ELISA. Results: Higher B-Cd (natural log-transformed) with increasing number of MT1A rs11076161 A-alleles was found in the highly polluted group (p-value trend = 0.033; all p-values adjusted for age, sex, and smoking). In a linear model a significant interaction between rs11076161 genotype and B-Cd was found for UNAG (p = 0.001) and UB2M concentrations (p = 0.001). Carriers of the rs11076161 AA genotype showed steeper slopes for the associations between Cd in blood and natural log-transformed UB2M (β = 1.2, 95% CI 0.72–1.6) compared to GG carriers (β = 0.30, 95% CI 0.15–0.45). Also for UNAG (natural log-transformed) carriers of the AA genotype had steeper slopes (β = 0.55, 95% CI 0.27–0.84) compared to GG carriers (β = 0.018, 95% CI − 0.79–0.11). Conclusions: MT1A rs11076161 was associated with B-Cd concentrations and Cd-induced kidney toxicity at high exposure levels. -- Highlights: ► Cadmium is toxic to the kidney but the susceptibility differs between individuals. ► The toxic effect of cadmium is scavenged by metallothioneins. ► A common variant of metallothionein 1A was genotyped in 512 cadmium exposed humans. ► Variant carriers of this polymorphism showed more kidney damage from cadmium. ► The frequency of these variants needs to be taken into account in risk assessment.

  16. Thermal stability of fission gas bubble superlattice in irradiated U10Mo fuel

    SciTech Connect (OSTI)

    Gan, J.; Keiser, D. D.; Miller, B. D.; Robinson, A. B.; Wachs, D. M.; Meyer, M. K.

    2015-09-01

    To investigate the thermal stability of the fission gas bubble superlattice, a key microstructural feature in both irradiated U-7Mo dispersion and U-10Mo monolithic fuel plates, a FIB-TEM sample of the irradiated U-10Mo fuel with a local fission density of 3.51021 fissions/cm3 was used for an in-situ heating TEM experiment. The temperature of the heating holder was raised at a ramp rate of approximately 10 C/min up to ~700 C, kept at that temperature for about 34 min, continued to 850 C with a reduced rate of 5 C/min. The result shows a high thermal stability of the fission gas bubble superlattice. The implication of this observation on the fuel microstructural evolution and performance under irradiation is discussed.

  17. Observation of localized states in atomically thin MoS{sub 2} field effect transistor

    SciTech Connect (OSTI)

    Ghatak, Subhamoy; Pal, Atindra Nath; Ghosh, Arindam

    2013-12-04

    We present electrical transport and low frequency (1/f) noise measurements on mechanically exfoliated single, bi and trilayer MoS{sub 2}-based FET devices on Si/SiO{sub 2} substrate. We find that the electronic states in MoS{sub 2} are localized at low temperatures (T) and conduction happens through variable range hopping (VRH). A steep increase of 1/f noise with decreasing T, typical for localized regime was observed in all of our devices. From gate voltage dependence of noise, we find that the noise power is inversely proportional to square of the number density (? 1/n{sup 2}) for a wide range of T, indicating number density fluctuations to be the dominant source of 1/f noise in these MoS{sub 2} FETs.

  18. Controlling the metal to semiconductor transition of MoS2 and WS2 in solution

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chou, Stanley Shihyao; Yi-Kai Huang; Kim, Jaemyung; Kaehr, Bryan James; Foley, Brian M.; Lu, Ping; Conner Dykstra; Hopkins, Patrick E.; Brinker, C. Jeffrey; Jiaxing Huang; et al

    2015-01-22

    Lithiation-exfoliation produces single to few-layered MoS2 and WS2 sheets dispersible in water. However, the process transforms them from the pristine semiconducting 2H phase to a distorted metallic phase. Recovery of the semiconducting properties typically involves heating of the chemically exfoliated sheets at elevated temperatures. Therefore, it has been largely limited to sheets deposited on solid substrates. We report the dispersion of chemically exfoliated MoS2 sheets in high boiling point organic solvents enabled by surface functionalization and the controllable recovery of their semiconducting properties directly in solution. Ultimately, this process connects the scalability of chemical exfoliation with the simplicity of solutionmore » processing, enabling a facile method for tuning the metal to semiconductor transitions of MoS2 and WS2 within a liquid medium.« less

  19. Electronic and magnetic properties of Mo doped graphene; full potential approach

    SciTech Connect (OSTI)

    Thakur, Jyoti Kashyap, Manish K.; Singh, Mukhtiyar; Saini, Hardev S.

    2015-05-15

    The electronic and magnetic properties of Pristine and Mo doped Graphene have been calculated using WIEN2k implementation of full potential linearized augmented plane wave (FPLAPW) method based on Density Functional Theory (DFT). The exchange and correlation (XC) effects were taken into account by generalized gradient approximation (GGA). The calculated results show that Mo doping creates magnetism in Graphene by shifting the energy levels at E{sub F} and opens up a channel for Graphene to be used in real nanoscale device applications. The unpaired d-electrons of Mo atom are responsible for induced magnetism in Graphene. Magnetic ordering created in Graphene in this way makes it suitable for recording media, magnetic sensors, magnetic inks and spintronic devices.

  20. Highly conducting SrMoO{sub 3} thin films for microwave applications

    SciTech Connect (OSTI)

    Radetinac, Aldin Mani, Arzhang; Ziegler, Jrgen; Alff, Lambert; Komissinskiy, Philipp; Melnyk, Sergiy; Nikfalazar, Mohammad; Zheng, Yuliang; Jakoby, Rolf

    2014-09-15

    We have measured the microwave resistance of highly conducting perovskite oxide SrMoO{sub 3} thin film coplanar waveguides. The epitaxial SrMoO{sub 3} thin films were grown by pulsed laser deposition and showed low mosaicity and smooth surfaces with a root mean square roughness below 0.3?nm. Layer-by-layer growth could be achieved for film thicknesses up to 400?nm as monitored by reflection high-energy electron diffraction and confirmed by X-ray diffraction. We obtained a constant microwave resistivity of 29???cm between 0.1 and 20?GHz by refining the frequency dependence of the transmission coefficients. Our result shows that SrMoO{sub 3} is a viable candidate as a highly conducting electrode material for all-oxide microwave electronic devices.

  1. Exciton-dominant electroluminescence from a diode of monolayer MoS{sub 2}

    SciTech Connect (OSTI)

    Ye, Yu; Ye, Ziliang; Gharghi, Majid; Zhu, Hanyu; Wang, Yuan; Zhao, Mervin; Yin, Xiaobo; Zhang, Xiang

    2014-05-12

    In two-dimensional monolayer MoS{sub 2}, excitons dominate the absorption and emission properties. However, the low electroluminescent efficiency and signal-to-noise ratio limit our understanding of the excitonic behavior of electroluminescence. Here, we study the microscopic origin of the electroluminescence from a diode of monolayer MoS{sub 2} fabricated on a heavily p-type doped silicon substrate. Direct and bound-exciton related recombination processes are identified from the electroluminescence. At a high electron-hole pair injection rate, Auger recombination of the exciton-exciton annihilation of the bound exciton emission is observed at room temperature. Moreover, the efficient electrical injection demonstrated here allows for the observation of a higher energy exciton peak of 2.255?eV in the monolayer MoS{sub 2} diode, attributed to the excited exciton state of a direct-exciton transition.

  2. Monitoring of arsenic, boron and mercury by lichen and soil analysis in the Mt. Amiata geothermal area (central Italy)

    SciTech Connect (OSTI)

    Loppi, S.

    1997-12-31

    Epiphytic lichens and top-soils from the Mt. Amiata geothermal field (central Italy) were analyzed for their As, B and Hg content. Three areas were selected: (1) Abbadia S. Salvatore, where a large Hg mine with smelting and roasting plant was located; (2) Piancastagnaio, where there are geothermal power plants; (3) a remote site far from mines and geothermal power plants. The results showed that the geothermal power plants do not represent a macroscopic source of arsenic and boron contamination in the area. As far as mercury is concerned, at the Hg mining area of Abbadia S. Salvatore concentrations were extremely high both in soil and epiphytic lichens, and the anomalous content in these organisms was due to the uptake of elemental mercury originating from soil degassing. At the geothermal area of Piancastagnaio, soil mercury was not different from that in the control area, but Hg in lichens was almost twice the control levels, suggesting that the gaseous emissions from the geothermal power plants are an important source of air contamination.

  3. Two-step growth of two-dimensional WSe2/MoSe2 heterostructures

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gong, Yongji; Lei, Sidong; Lou, Jun; Liu, Zheng; Vajtai, Robert; Zhou, Wu; Ajayan, Pullikel M.

    2015-08-03

    Two dimensional (2D) materials have attracted great attention due to their unique properties and atomic thickness. Although various 2D materials have been successfully synthesized with different optical and electrical properties, a strategy for fabricating 2D heterostructures must be developed in order to construct more complicated devices for practical applications. Here we demonstrate for the first time a two-step chemical vapor deposition (CVD) method for growing transition-metal dichalcogenide (TMD) heterostructures, where MoSe2 was synthesized first and followed by an epitaxial growth of WSe2 on the edge and on the top surface of MoSe2. Compared to previously reported one-step growth methods, thismore » two-step growth has the capability of spatial and size control of each 2D component, leading to much larger (up to 169 μm) heterostructure size, and cross-contamination can be effectively minimized. Furthermore, this two-step growth produces well-defined 2H and 3R stacking in the WSe2/MoSe2 bilayer regions and much sharper in-plane interfaces than the previously reported MoSe2/WSe2 heterojunctions obtained from one-step growth methods. The resultant heterostructures with WSe2/MoSe2 bilayer and the exposed MoSe2 monolayer display rectification characteristics of a p-n junction, as revealed by optoelectronic tests, and an internal quantum efficiency of 91% when functioning as a photodetector. As a result, a photovoltaic effect without any external gates was observed, showing incident photon to converted electron (IPCE) efficiencies of approximately 0.12%, providing application potential in electronics and energy harvesting.« less

  4. Thermal aging modeling and validation on the Mo containing Fe-Cr-Ni alloys

    SciTech Connect (OSTI)

    Yang, Ying; Tan, Lizhen; Busby, Jeremy T.

    2015-04-01

    Thermodynamics of intermetallic phases in Fe-rich Fe-Cr-Ni-Mo alloys is critical knowledge to understand thermal aging effect on the phase stability of Mo-containing austenitic steels, which subsequently facilitates alloy design/improvement and degradation mitigation of these materials for reactor applications. Among the intermetallic phases, Chi (χ), Laves, and Sigma (σ) are often of concern because of their tendency to cause embrittlement of the materials. The focus of this study is thermal stability of the Chi and Laves phases as they were less studied compared to the Sigma phase. Coupled with thermodynamic modeling, thermal stability of intermetallic phases in Mo containing Fe-Cr-Ni alloys was investigated at 1000, 850 and 700 C for different annealing times. The morphologies, compositions and crystal structures of the precipitates of the intermetallic phases were carefully examined by scanning electron microscopy, electron probe microanalysis, X-ray diffraction, and transmission electron microscopy. Three key findings resulted from this study. First, the Chi phase is stable at high temperature, and with decreasing temperature it transforms into the Laves phase that is stable at low temperature. Secondly, Cr, Mo, Ni are soluble in both the Chi and Laves phases, with the solubility of Mo playing a major role in the relative stability of the intermetallic phases. Thirdly, in situ transformation from Chi phase to Laves phase was directly observed, which increased the local strain field, generated dislocations in the intermetallic phases, and altered the precipitate phase orientation relationship with the austenitic matrix. The thermodynamic models that were developed and validated were then applied to evaluating the effect of Mo on the thermal stability of intermetallic phases in type 316 and NF709 stainless steels.

  5. Electrical and photovoltaic characteristics of MoS{sub 2}/Si p-n junctions

    SciTech Connect (OSTI)

    Hao, Lanzhong Liu, Yunjie Gao, Wei; Han, Zhide; Xue, Qingzhong; Zeng, Huizhong; Wu, Zhipeng; Zhu, Jun; Zhang, Wanli

    2015-03-21

    Bulk-like molybdenum disulfide (MoS{sub 2}) thin films were deposited on the surface of p-type Si substrates using dc magnetron sputtering technique and MoS{sub 2}/Si p-n junctions were formed. The vibrating modes of E{sup 1}{sub 2g} and A{sub 1g} were observed from the Raman spectrum of the MoS{sub 2} films. The current density versus voltage (J-V) characteristics of the junction were investigated. A typical J-V rectifying effect with a turn-on voltage of 0.2?V was shown. In different voltage range, the electrical transporting of the junction was dominated by diffusion current and recombination current, respectively. Under the light illumination of 15?mW?cm{sup ?2}, the p-n junction exhibited obvious photovoltaic characteristics with a short-circuit current density of 3.2?mA?cm{sup ?2} and open-circuit voltage of 0.14?V. The fill factor and energy conversion efficiency were 42.4% and 1.3%, respectively. According to the determination of the Fermi-energy level (?4.65?eV) and energy-band gap (?1.45?eV) of the MoS{sub 2} films by capacitance-voltage curve and ultraviolet-visible transmission spectra, the mechanisms of the electrical and photovoltaic characteristics were discussed in terms of the energy-band structure of the MoS{sub 2}/Si p-n junctions. The results hold the promise for the integration of MoS{sub 2} thin films with commercially available Si-based electronics in high-efficient photovoltaic devices.

  6. Rapid first-cycle lithiation strategy for enhanced performance of Li-MoS2

    Office of Scientific and Technical Information (OSTI)

    batteries as identified by in situ studies. (Journal Article) | SciTech Connect Rapid first-cycle lithiation strategy for enhanced performance of Li-MoS2 batteries as identified by in situ studies. Citation Details In-Document Search Title: Rapid first-cycle lithiation strategy for enhanced performance of Li-MoS2 batteries as identified by in situ studies. Abstract not provided. Authors: Jiayu Wan ; Wenzhong Bao ; Yang Liu ; Jiaqi Dai ; Fei Shen ; Lihui Zhou ; Xinghan Cai ; Dan Urban ;

  7. Neutrino-nucleus scattering of {sup 95,97}Mo and {sup 116}Cd

    SciTech Connect (OSTI)

    Ydrefors, E.; Almosly, W.; Suhonen, J.

    2013-12-30

    Accurate knowledge about the nuclear responses to supernova neutrinos for relevant nuclear targets is important both for neutrino detection and for astrophysical applications. In this paper we discuss the cross sections for the charged-current neutrino-nucleus scatterings off {sup 95,97}Mo and {sup 116}Cd. The microscopic quasiparticle-phonon model is adopted for the odd-even nuclei {sup 95,97}Mo. In the case of {sup 116}Cd we present cross sections both for the Bonn one-boson-exchange potential and self-consistent calculations based on modern Skyrme interactions.

  8. Valence and metal/silicate partitioning of Mo: Implications for conditions

    Office of Scientific and Technical Information (OSTI)

    of Earth accretion and core formation (Journal Article) | SciTech Connect SciTech Connect Search Results Journal Article: Valence and metal/silicate partitioning of Mo: Implications for conditions of Earth accretion and core formation Citation Details In-Document Search Title: Valence and metal/silicate partitioning of Mo: Implications for conditions of Earth accretion and core formation Authors: Righter, K. ; Danielson, L.R. ; Pando, K.M. ; Shofner, G.A. ; Sutton, S.R. ; Newville, M. ; Lee,

  9. Morgan Wascko Imperial College London M.O. Wascko FNAL User's Meeting

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    from the BooNEs Morgan Wascko Imperial College London M.O. Wascko FNAL User's Meeting M. Sorel Goals of the BooNEs * MiniBooNE: Confirm or rule out LSND * SciBooNE: * Near detector measurements for MiniBooNE * Precise cross section measurements * Especially useful for T2K 2 M.O. Wascko FNAL User's Meeting Goals of the BooNEs * MiniBooNE: Confirm or rule out LSND * SciBooNE: * Near detector measurements for MiniBooNE * Precise cross section measurements * Especially useful for T2K 2 W + ν µ n p

  10. Site-dependent free energy barrier for proton reduction on MoS2 edges

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect Site-dependent free energy barrier for proton reduction on MoS2 edges Citation Details In-Document Search Title: Site-dependent free energy barrier for proton reduction on MoS2 edges Authors: Choi, W ; Wood, B C ; Schwegler, E ; Ogitsu, T Publication Date: 2013-05-30 OSTI Identifier: 1113397 Report Number(s): LLNL-JRNL-639087 DOE Contract Number: W-7405-ENG-48 Resource Type: Journal Article Resource Relation: Journal Name: Journal of Physical Chemistry C,

  11. Primary arm spacing in chill block melt spun Ni-Mo alloys

    SciTech Connect (OSTI)

    Tewari, S.N.; Glasgow, T.K.

    1986-01-01

    Chill block melt spun ribbons of Ni-Mo binary alloys containing 8.0 to 41.8 wt % Mo have been prepared under carefully controlled processing conditions. The growth velocity has been determined as a function of distance from the quench surface from the observed ribbon thickness dependence on the melt puddle residence time. Primary arm spacings measured at the midribbon thickness locations show a dependence on growth velocity and alloy composition which is expected from dendritic growth models for binary alloys directionally solidified in a positive temperature gradient.

  12. Probing the Mechanism of the Mycobacterium tuberculosis [beta]-Ketoacyl-Acyl Carrier Protein Synthase III mtFabH: Factors Influencing Catalysis and Substrate Specificity

    SciTech Connect (OSTI)

    Brown, Alistair K.; Sridharan, Sudharsan; Kremer, Laurent; Lindenberg, Sandra; Dover, Lynn G.; Sacchettini, James C.; Besra, Gurdyal S.

    2010-11-30

    Mycolic acids are the dominant feature of the Mycobacterium tuberculosis cell wall. These {alpha}-alkyl, {beta}-hydroxy fatty acids are formed by the condensation of two fatty acids, a long meromycolic acid and a shorter C{sub 24}-C{sub 26} fatty acid. The component fatty acids are produced via a combination of type I and II fatty acid synthases (FAS) with FAS-I products being elongated by FAS-II toward meromycolic acids. The {beta}-ketoacyl-acyl carrier protein (ACP) synthase III encoded by mtfabH (mtFabH) links FAS-I and FAS-II, catalyzing the condensation of FAS-I-derived acyl-CoAs with malonyl-acyl carrier protein (ACP). The acyl-CoA chain length specificity of mtFabH was assessed in vitro; the enzyme extended longer, physiologically relevant acyl-CoA primers when paired with AcpM, its natural partner, than with Escherichia coli ACP. The ability of the enzyme to use E. coli ACP suggests that a similar mode of binding is likely with both ACPs, yet it is clear that unique factors inherent to AcpM modulate the substrate specificity of mtFabH. Mutation of proposed key mtFabH residues was used to define their catalytic roles. Substitution of supposed acyl-CoA binding residues reduced transacylation, with double substitutions totally abrogating activity. Mutation of Arg{sup 46} revealed its more critical role in malonyl-AcpM decarboxylation than in the acyl-CoA binding role. Interestingly, this effect was suppressed intragenically by Arg{sup 161} {yields} Ala substitution. Our structural studies suggested that His{sup 258}, previously implicated in malonyl-ACP decarboxylation, also acts as an anchor point for a network of water molecules that we propose promotes deprotonation and transacylation of Cys{sup 122}.

  13. Single-layer MoS{sub 2} roughness and sliding friction quenching by interaction with atomically flat substrates

    SciTech Connect (OSTI)

    Quereda, J.; Castellanos-Gomez, A.; Agrat, N.; Rubio-Bollinger, G.

    2014-08-04

    We experimentally study the surface roughness and the lateral friction force in single-layer MoS{sub 2} crystals deposited on different substrates: SiO{sub 2}, mica, and hexagonal boron nitride (h-BN). Roughness and sliding friction measurements are performed by atomic force microscopy. We find a strong dependence of the MoS{sub 2} roughness on the underlying substrate material, being h-BN the substrate which better preserves the flatness of the MoS{sub 2} crystal. The lateral friction also lowers as the roughness decreases, and attains its lowest value for MoS{sub 2} flakes on h-BN substrates. However, it is still higher than for the surface of a bulk MoS{sub 2} crystal, which we attribute to the deformation of the flake due to competing tip-to-flake and flake-to-substrate interactions.

  14. High blue-near ultraviolet photodiode response of vertically stacked graphene-MoS{sub 2}-metal heterostructures

    SciTech Connect (OSTI)

    Wi, Sungjin; Chen, Mikai; Nam, Hongsuk; Liu, Amy C.; Meyhofer, Edgar; Liang, Xiaogan

    2014-06-09

    We present a study on the photodiode response of vertically stacked graphene/MoS{sub 2}/metal heterostructures in which MoS{sub 2} layers are doped with various plasma species. In comparison with undoped heterostructures, such doped ones exhibit significantly improved quantum efficiencies in both photovoltaic and photoconductive modes. This indicates that plasma-doping-induced built-in potentials play an important role in photocurrent generation. As compared to indium-tin-oxide/ MoS{sub 2}/metal structures, the presented graphene/MoS{sub 2}/metal heterostructures exhibit greatly enhanced quantum efficiencies in the blue-near ultraviolet region, which is attributed to the low density of recombination centers at graphene/MoS{sub 2} heterojunctions. This work advances the knowledge for making photo-response devices based on layered materials.

  15. Electric contributions to magnetic force microscopy response from graphene and MoS{sub 2} nanosheets

    SciTech Connect (OSTI)

    Li, Lu Hua Chen, Ying

    2014-12-07

    Magnetic force microscopy (MFM) signals have recently been detected from whole pieces of mechanically exfoliated graphene and molybdenum disulfide (MoS{sub 2}) nanosheets, and magnetism of the two nanomaterials was claimed based on these observations. However, non-magnetic interactions or artefacts are commonly associated with MFM signals, which make the interpretation of MFM signals not straightforward. A systematic investigation has been done to examine possible sources of the MFM signals from graphene and MoS{sub 2} nanosheets and whether the MFM signals can be correlated with magnetism. It is found that the MFM signals have significant non-magnetic contributions due to capacitive and electrostatic interactions between the nanosheets and conductive cantilever tip, as demonstrated by electric force microscopy and scanning Kevin probe microscopy analyses. In addition, the MFM signals of graphene and MoS{sub 2} nanosheets are not responsive to reversed magnetic field of the magnetic cantilever tip. Therefore, the observed MFM response is mainly from electric artefacts and not compelling enough to correlate with magnetism of graphene and MoS{sub 2} nanosheets.

  16. Ferromagnetic superexchange in insulating Cr2MoO6 by controlling orbital hybridization

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhu, M.; Do, D.; Dela Cruz, Clarina R.; Dun, Zhiling; Cheng, J. -G.; Goto, H.; Uwatoko, Yoshiya; Zou, T.; Zhou, Haidon D.; Mahanti, Subhendra D.; et al

    2015-09-11

    We report the magnetic and electronic structures of the newly synthesized inverse-trirutile compound Cr2MoO6. Despite the same crystal symmetry and similar bond-lengths and bond-angles to Cr2TeO6, Cr2MoO6 possesses a magnetic structure of the Cr2MoO6 type, different from that seen in Cr2TeO6. Ab-initio electronic structure calculations show that the sign and strength of the Cr-O-Cr exchange coupling is strongly influenced by the hybridization between Mo 4d and O 2p orbitals. This result further substantiates our recently proposed mechanism for tuning the exchange interaction between two magnetic atoms by modifying the electronic states of the non-magnetic atoms in the exchange path throughmore »orbital hybridization. This approach is fundamentally different from the conventional methods of controlling the exchange interaction by either carrier injection or through structural distortions.« less

  17. MoS{sub 2} functionalization for ultra-thin atomic layer deposited dielectrics

    SciTech Connect (OSTI)

    Azcatl, Angelica; McDonnell, Stephen; Santosh, K.C.; Peng, Xin; Dong, Hong; Qin, Xiaoye; Addou, Rafik; Lu, Ning; Kim, Moon J.; Cho, Kyeongjae; Wallace, Robert M.; Mordi, Greg I.; Kim, Jiyoung

    2014-03-17

    The effect of room temperature ultraviolet-ozone (UV-O{sub 3}) exposure of MoS{sub 2} on the uniformity of subsequent atomic layer deposition of Al{sub 2}O{sub 3} is investigated. It is found that a UV-O{sub 3} pre-treatment removes adsorbed carbon contamination from the MoS{sub 2} surface and also functionalizes the MoS{sub 2} surface through the formation of a weak sulfur-oxygen bond without any evidence of molybdenum-sulfur bond disruption. This is supported by first principles density functional theory calculations which show that oxygen bonded to a surface sulfur atom while the sulfur is simultaneously back-bonded to three molybdenum atoms is a thermodynamically favorable configuration. The adsorbed oxygen increases the reactivity of MoS{sub 2} surface and provides nucleation sites for atomic layer deposition of Al{sub 2}O{sub 3}. The enhanced nucleation is found to be dependent on the thin film deposition temperature.

  18. Magnetic Force Microscopy Study of Zr2Co11 -Based Nanocrystalline Materials: Effect of Mo Addition

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yue, Lanping; Jin, Yunlong; Zhang, Wenyong; Sellmyer, David J.

    2015-01-01

    Tmore » he addition of Molybdenum was used to modify the nanostructure and enhance coercivity of rare-earth-free Zr2Co11-based nanocrystalline permanent magnets. he effect of Mo addition on magnetic domain structures of melt spun nanocrystalline Zr16Co84-xMox(x=0, 0.5, 1, 1.5, and 2.0) ribbons has been investigated. It was found that magnetic properties and local domain structures are strongly influenced by Mo doping. he coercivity of the samples increases with the increase in Mo content (x≤1.5). he maximum energy product(BH)maxincreases with increasingxfrom 0.5 MGOe forx=0to a maximum value of 4.2 MGOe forx=1.5. he smallest domain size with a relatively short magnetic correlation length of 128 nm and largest root-mean-square phase shiftΦrmsvalue of 0.66° are observed for thex=1.5. he optimal Mo addition promotes magnetic domain structure refinement and thus leads to a significant increase in coercivity and energy product in this sample.« less

  19. Equation of state of bcc-Mo by static volume compression to 410 GPa

    SciTech Connect (OSTI)

    Akahama, Yuichi; Hirao, Naohisa; Ohishi, Yasuo; Singh, Anil K.

    2014-12-14

    Unit cell volumes of Mo and Pt have been measured simultaneously to ≈400 GPa by x-ray powder diffraction using a diamond anvil cell and synchrotron radiation source. The body-centered cubic (bcc) phase of Mo was found to be stable up to 410 GPa. The equation of state (EOS) of bcc-Mo was determined on the basis of Pt pressure scale. A fit of Vinet EOS to the volume compression data gave K{sub 0} = 262.3(4.6) GPa, K{sub 0}′ = 4.55(16) with one atmosphere atomic volume V{sub 0} = 31.155(24) A{sup 3}. The EOS was in good agreement with the previous ultrasonic data within pressure difference of 2.5%–3.3% in the multimegabar range, though the EOS of Mo proposed from a shock compression experiment gave lower pressure by 7.2%–11.3% than the present EOS. The agreement would suggest that the Pt pressure scale provides an accurate pressure value in an ultra-high pressure range.

  20. Effect of mechanical strain on electronic properties of bulk MoS{sub 2}

    SciTech Connect (OSTI)

    Kumar, Sandeep Kumar, Jagdish Sastri, O. S. K. S.

    2015-05-15

    Ab-initio density functional theory based calculations of electronic properties of bulk and monolayer Molybdenum di-Sulfide (MoS{sub 2}) have been performed using all electron Full Potential Linearised Augmentad Plane Wave (FPLAPW) method using Elk code. We have used Generalised Gradient Approximation (GGA) for exchange and correlation functionals and performed calculaitons of Lattice parameters, Density Of States (DOS) and Band Structure (BS). Band structure calculations revealed that bulk MoS{sub 2} has indirect band gap of 0.97 eV and mono-layer MoS{sub 2} has direct band gap which has increased to 1.71 eV. These are in better agreement with experimental values as compared with the other calculations using pseudo-potential code. The effect of mechanical strain on the electronic properties of bulk MoS{sub 2} has also been studied. For the different values of compressive strain (varying from 2% to 8% in steps of 2%) along the c-axis, the corresponding DOS and BS are obtained. We observed that the band gap decreases by about 15% for every 2% increase in strain along the c-axis.

  1. On the combined gradient-stochastic plasticity model: Application to Mo-micropillar compression

    SciTech Connect (OSTI)

    Konstantinidis, A. A.; Zhang, X.; Aifantis, E. C.

    2015-02-17

    A formulation for addressing heterogeneous material deformation is proposed. It is based on the use of a stochasticity-enhanced gradient plasticity model implemented through a cellular automaton. The specific application is on Mo-micropillar compression, for which the irregularities of the strain bursts observed have been experimentally measured and theoretically interpreted through Tsallis' q-statistics.

  2. EIS-0475: Disposition of the Bannister Federal Complex, Kansas City, MO

    Broader source: Energy.gov [DOE]

    NNSA/DOE announces its intent to prepare an EIS for the disposition of the Bannister Federal Complex, Kansas City, MO. NNSA previously decided in a separate NEPA review (EA-1592) to relocate its operations from the Bannister Federal Complex to a newly constructed industrial campus eight miles from the current location.

  3. The carburization of transition metal molybdates (MxMoO?, M= Cu, Ni or Co) and the generation of highly active metal/carbide catalysts for CO? hydrogenation

    SciTech Connect (OSTI)

    Rodriguez, Jose A.; Xu, Wenqian; Ramirez, Pedro J.; Stachiola, Dario; Brito, Joaquin L.

    2015-05-06

    A new approach has been tested for the preparation of metal/Mo?C catalysts using mixed-metal oxide molybdates as precursors. Synchrotron-based in situ time-resolved X-ray diffraction was used to study the reduction and carburization processes of Cu?(MoO?)?(OH)?, a-NiMoO? and CoMoO?nH?O by thermal treatment under mixtures of hydrogen and methane. In all cases, the final product was ?-Mo?C and a metal phase (Cu, Ni, or Co), but the transition sequence varied with the different metals, and it could be related to the reduction potential of the Cu?, Ni? and Co? cations inside each molybdate. The synthesized Cu/Mo?C, Ni/Mo?C and Co/Mo?C catalysts were highly active for the hydrogenation of CO?. The metal/Mo?C systems exhibited large variations in the selectivity towards methanol, methane and CnH?n?? (n > 2) hydrocarbons depending on the nature of the supported metal and its ability to cleave C-O bonds. Cu/Mo?C displayed a high selectivity for CO and methanol production. Ni/Mo?C and Co/Mo?C were the most active catalysts for the activation and full decomposition of CO?, showing high selectivity for the production of methane (Ni case) and CnH?n?? (n > 2) hydrocarbons (Co case).

  4. Modeling of Interaction Layer Growth Between U-Mo Particles and an Al Matrix

    SciTech Connect (OSTI)

    Yeon Soo Kim; G. L. Hofman; Ho Jin Ryu; Jong Man Park; A. B. Robinson; D. M. Wachs

    2013-12-01

    Interaction layer growth between U-Mo alloy fuel particles and Al in a dispersion fuel is a concern due to the volume expansion and other unfavorable irradiation behavior of the interaction product. To reduce interaction layer (IL) growth, a small amount of Si is added to the Al. As a result, IL growth is affected by the Si content in the Al matrix. In order to predict IL growth during fabrication and irradiation, empirical models were developed. For IL growth prediction during fabrication and any follow-on heating process before irradiation, out-of-pile heating test data were used to develop kinetic correlations. Two out-of-pile correlations, one for the pure Al matrix and the other for the Al matrix with Si addition, respectively, were developed, which are Arrhenius equations that include temperature and time. For IL growth predictions during irradiation, the out-of-pile correlations were modified to include a fission-rate term to consider fission enhanced diffusion, and multiplication factors to incorporate the Si addition effect and the effect of the Mo content. The in-pile correlation is applicable for a pure Al matrix and an Al matrix with the Si content up to 8 wt%, for fuel temperatures up to 200 degrees C, and for Mo content in the range of 6 10wt%. In order to cover these ranges, in-pile data were included in modeling from various tests, such as the US RERTR-4, -5, -6, -7 and -9 tests and Koreas KOMO-4 test, that were designed to systematically examine the effects of the fission rate, temperature, Si content in Al matrix, and Mo content in U-Mo particles. A model converting the IL thickness to the IL volume fraction in the meat was also developed.

  5. Novel Processing of mo-si-b Intermetallics for improved efficiency of power systems

    SciTech Connect (OSTI)

    M.J. Kramer; O. Degirmen; A.J. Thom; M. Akinc

    2004-09-30

    Multiphase composite alloys based on the Mo-Si-B system are candidate materials for ultra-high temperature applications. In non load-bearing applications such as thermal barrier coatings or heat exchangers in fossil fuel burners, these materials may be ideally suited. Alloys based on the Mo{sub 5}Si{sub 3}B{sub x} phase (Tl phase) possess excellent oxidation resistance to at least 1600 C in synthetic air atmospheres. However, the ability of Tl-based alloys to resist aggressive combustion environments has not yet been determined. The present work seeks to investigate the resistance of these Mo-Si-B alloys to simulated combustion atmospheres. Material was pre-alloyed by combustion synthesis, and samples for testing were prepared by classic powder metallurgical processing techniques. Precursor material synthesized by self-heating-synthesis was sintered to densities exceeding 98% in an argon atmosphere at 1800 C. The approximate phase assemblage of the material was 57% Tl, 29% MoB, 14% MoSi{sub 2} (wt%). The alloy was oxidized from 1000-1100 C in flowing air containing water vapor at 18 Torr. At 1000 C the material achieved a steady state mass loss, and at 1100 C the material undergoes a steady state mass gain. The oxidation rate of these alloys in this temperature regime was accelerated by the presence of water vapor compared to oxidation in dry air. The results of microstructural analysis of the tested alloys will be discussed. Techniques and preliminary results for fabricating near-net-shaped parts will also be presented.

  6. MoS{sub 2}@ZnO nano-heterojunctions with enhanced photocatalysis and field emission properties

    SciTech Connect (OSTI)

    Tan, Ying-Hua; Yu, Ke Li, Jin-Zhu; Fu, Hao; Zhu, Zi-Qiang

    2014-08-14

    The molybdenum disulfide (MoS{sub 2})@ZnO nano-heterojunctions were successfully fabricated through a facile three-step synthetic process: prefabrication of the ZnO nanoparticles, the synthesis of MoS{sub 2} nanoflowers, and the fabrication of MoS{sub 2}@ZnO heterojunctions, in which ZnO nanoparticles were uniformly self-assembled on the MoS{sub 2} nanoflowers by utilizing polyethyleneimine as a binding agent. The photocatalytic activities of the composite samples were evaluated by monitoring the photodegradation of methylene blue (MB). Compared with pure MoS{sub 2} nanoflowers, the composites show higher adsorption capability in dark and better photocatalytic efficiency due to the increased specific surface area and improved electron-hole pair separation. After irradiation for 100?min, the remaining MB in solution is about 7.3%. Moreover, the MoS{sub 2}@ZnO heterojunctions possess enhanced field emission properties with lower turn-on field of 3.08?V ?m{sup ?1}and lower threshold field of 6.9?V ?m{sup ?1} relative to pure MoS{sub 2} with turn-on field of 3.65?V ?m{sup ?1} and threshold field of 9.03?V ?m{sup ?1}.

  7. Study of structure of the TiO{sub 2}MoO{sub 3} bilayer films by Raman spectroscopy

    SciTech Connect (OSTI)

    Santos, Elias de Barros; Sigoli, Fernando Aparecido; Mazali, Italo Odone

    2014-12-15

    Highlights: TiO{sub 2}MoO{sub 3} bilayer thin films were easily prepared by dip-coating technique. Ti and Mo metallo-organic compounds were used as source of its respective oxide. TiO{sub 2} in anatase phase and orthorhombic phase of ?-MoO{sub 3} were identified. The bilayer structure was investigated by Raman spectroscopy. - Abstract: In this work, TiO{sub 2}MoO{sub 3} films were easily prepared by dip-coating technique and metallo-organic decomposition process (MOD). Raman analyses indicate the formation of TiO{sub 2} in anatase phase and orthorhombic phase of ?-MoO{sub 3}. It was observed that the Raman bands intensities attributed to TiO{sub 2} and MoO{sub 3} oxides were dependent on the number of decompositiondeposition cycles (DDC). The different number of DDC generates films with different thicknesses and the Raman signal was sensitive to this variation. Raman analyses provided qualitative information about the bilayer structure of the bi-component TiO{sub 2}MoO{sub 3} films, which was confirmed by scanning electron microscopy. In this direction, the dip-coating technique and MOD process can be an efficient strategy to facile preparation of many samples to be used in applications.

  8. Theoretical study on strain induced variations in electronic properties of 2H-MoS{sub 2} bilayer sheets

    SciTech Connect (OSTI)

    Dong, Liang; Dongare, Avinash M.; Namburu, Raju R.; O'Regan, Terrance P.; Dubey, Madan

    2014-02-03

    The strain dependence of the electronic properties of bilayer sheets of 2H-MoS{sub 2} is studied using ab initio simulations based on density functional theory. An indirect band gap for bilayer MoS{sub 2} is observed for all variations of strain along the basal plane. Several transitions for the indirect band gap are observed for various strains for the bilayer structure. The variation of the band gap and the carrier effective masses for the holes and the electrons for the bilayer MoS{sub 2} structure under conditions of uniaxial strain, biaxial strain, as well as uniaxial stress is investigated.

  9. AMoRE: Collaboration for searches for the neutrinoless double-beta decay of the isotope of {sup 100}Mo with the aid of {sup 40}Ca{sup 100}MoO{sub 4} as a cryogenic scintillation detector

    SciTech Connect (OSTI)

    Khanbekov, N. D., E-mail: xanbekov@gmail.com [Institute of Theoretical and Experimental Physics (Russian Federation)

    2013-09-15

    The AMoRE (Advanced Mo based Rare process Experiment) Collaboration is planning to employ {sup 40}Ca{sup 100}MoO{sub 4} single crystals as a cryogenic Scintillation detector for studying the neutrinoless double-beta decay of the isotope {sup 100}Mo. A simultaneous readout of phonon and scintillation signals is performed in order to suppress the intrinsic background. The planned sensitivity of the experiment that would employ 100 kg of {sup 40}Ca{sup 100}MoO{sub 4} over five years of data accumulation would be T{sub 1/2}{sup 0{nu}} = 3 Multiplication-Sign 10{sup 26} yr, which corresponds to values of the effective Majorana neutrino mass in the range of Left-Pointing-Angle-Bracket m{sub {nu}} Right-Pointing-Angle-Bracket {approx} 0.02-0.06 eV.

  10. Microstructure evolution in solution treated Ti15Mo alloy processed by high pressure torsion

    SciTech Connect (OSTI)

    Jane?ek, Milo; ?ek, Jakub; Strsk, Josef; Vclavov, Kristna; Hruka, Petr; Polyakova, Veronika; Gatina, Svetlana; Semenova, Irina

    2014-12-15

    Microstructure evolution and mechanical properties of ultra-fine grained Ti15Mo alloy processed by high pressure torsion were investigated. High pressure torsion straining resulted in strong grain refinement as-observed by transmission electron microscopy. Microhardness and light microscopy showed two distinct regions (i) a central region with radial material flow and low microhardness (340 HV) and (ii) a peripheral region with rotational material flow and high microhardness (430 HV). Positron annihilation spectroscopy showed that the only detectable defects in the material are dislocations, whose density increases with the radial distance and the number of high pressure torsion revolutions. The local chemical environment around defects does not differ significantly from the average composition. - Highlights: Beta-Ti alloy Ti15Mo was processed by high pressure torsion (HPT). Lateral inhomogeneity of the microstructure and microhardness was found. Dislocations are the only lattice defects detectable by positron annihilation. Molybdenum is not preferentially segregated along dislocation cores.

  11. LANL Experience Rolling Zr-Clad LEU-10Mo Foils for AFIP-7

    SciTech Connect (OSTI)

    Hammon, Duncan L.; Clarke, Kester D.; Alexander, David J.; Kennedy, Patrick K.; Edwards, Randall L.; Duffield, Andrew N.; Dombrowski, David E.

    2015-05-29

    The cleaning, canning, rolling and final trimming of Low Enriched Uranium-10 wt. pct. Molybdenum (LEU-10Mo) foils for ATR (Advanced Test Reactor) fuel plates to be used in the AFIP-7 (ATR Full Size Plate In Center Flux Trap Position) experiments are summarized. Six Zr-clad foils were produced from two LEU-10Mo castings supplied to Los Alamos National Laboratory (LANL) by Y-12 National Security Complex. Details of cleaning and canning procedures are provided. Hot- and cold-rolling results are presented, including rolling schedules, images of foils in-process, metallography and local compositions of regions of interest, and details of final foil dimensions and process yield. This report was compiled from the slides for the presentation of the same name given by Duncan Hammon on May 12, 2011 at the AFIP-7 Lessons Learned meeting in Salt Lake City, UT, with Los Alamos National Laboratory document number LA-UR 11-02898.

  12. Determination of the direct double- β -decay Q value of Zr 96 and atomic masses of Zr 90 <mo>-> 92 <mo>,> 94 <mo>,> 96 and Mo 92 <mo>,> 94 <mo>-> 98 <mo>,> 100

    SciTech Connect (OSTI)

    Gulyuz, K.; Ariche, J.; Bollen, G.; Bustabad, S.; Eibach, M.; Izzo, C.; Novario, S. J.; Redshaw, M.; Ringle, R.; Sandler, R.; Schwarz, S.; Valverde, A. A.

    2015-05-06

    Experimental searches for neutrinoless double-β decay offer one of the best opportunities to look for physics beyond the standard model. Detecting this decay would confirm the Majorana nature of the neutrino, and a measurement of its half-life can be used to determine the absolute neutrino mass scale. Important to both tasks is an accurate knowledge of the Q value of the double-β decay. The LEBIT Penning trap mass spectrometer was used for the first direct experimental determination of the ⁹⁶Zr double-β decay Q value: Qββ=3355.85(15) keV. This value is nearly 7 keV larger than the 2012 Atomic Mass Evaluation [M. Wang et al., Chin. Phys. C 36, 1603 (2012)] value and one order of magnitude more precise. The 3-σ shift is primarily due to a more accurate measurement of the ⁹⁶Zr atomic mass: m(⁹⁶Zr)=95.90827735(17) u. Using the new Q value, the 2νββ-decay matrix element, |M|, is calculated. Improved determinations of the atomic masses of all other zirconium (90-92,94,96Zr) and molybdenum (92,94-98,100Mo) isotopes using both ¹²C₈ and ⁸⁷Rb as references are also reported.

  13. Co-Rolled U10Mo/Zirconium-Barrier-Layer Monolithic Fuel Foil Fabrication Process

    SciTech Connect (OSTI)

    G. A. Moore; M. C. Marshall

    2010-01-01

    Integral to the current UMo fuel foil processing scheme being developed at Idaho National Laboratory (INL) is the incorporation of a zirconium barrier layer for the purpose of controlling UMo-Al interdiffusion at the fuel-meat/cladding interface. A hot co-rolling process is employed to establish a ~25-m-thick zirconium barrier layer on each face of the ~0.3-mm-thick U10Mo fuel foil.

  14. NNSA Works to Establish a Reliable Supply of Mo-99 Produced Without Highly

    National Nuclear Security Administration (NNSA)

    Enriched Uranium | National Nuclear Security Administration Works to Establish a Reliable Supply of Mo-99 Produced Without Highly Enriched Uranium | National Nuclear Security Administration Facebook Twitter Youtube Flickr RSS People Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy Emergency Response Recapitalizing Our Infrastructure Countering Nuclear Terrorism About Our Programs Our History Who We Are Our Leadership Our Locations Budget Our Operations

  15. Tribological properties of self-lubricating NiAl/Mo-based composites containing AgVO{sub 3} nanowires

    SciTech Connect (OSTI)

    Liu, Eryong; Gao, Yimin; Bai, Yaping; Yi, Gewen; Wang, Wenzhen; Zeng, Zhixiang; Jia, Junhong

    2014-11-15

    Silver vanadate (AgVO{sub 3}) nanowires were synthesized by hydrothermal method and self-lubricating NiAl/Mo-AgVO{sub 3} composites were fabricated by powder metallurgy technique. The composition and microstructure of NiAl/Mo-based composites were characterized and the tribological properties were investigated from room temperature to 900 C. The results showed that NiAl/Mo-based composites were consisted of nanocrystalline B2 ordered NiAl matrix, Al{sub 2}O{sub 3}, Mo{sub 2}C, metallic Ag and vanadium oxide phase. The appearance of metallic Ag and vanadium oxide phase can be attributed to the decomposition of AgVO{sub 3} during sintering. Wear testing results confirmed that NiAl/Mo-based composites have excellent tribological properties over a wide temperature range. For example, the friction coefficient and wear rate of NiAl/Mo-based composites containing AgVO{sub 3} were significantly lower than the composites containing only metallic Mo or AgVO{sub 3} lubricant when the temperature is above 300 C, which can be attributed to the synergistic lubricating action of metallic Mo and AgVO{sub 3} lubricants. Furthermore, Raman results indicated that the composition on the worn surface of NiAl-based composites was self-adjusted after wear testing at different temperatures. For example, Ag{sub 3}VO{sub 4} and Fe{sub 3}O{sub 4} lubricants were responsible for the improvement of tribological properties at 500 C, AgVO{sub 3}, Ag{sub 3}VO{sub 4} and molybdate for 700 C, and AgVO{sub 3} and molybdate for 900 C of NiAl-based composites with the addition of metallic Mo and AgVO{sub 3}. - Highlights: NiAl/Mo-AgVO{sub 3} nanocomposites were prepared by mechanical alloying and sintering. AgVO{sub 3} decomposed to metallic Ag and vanadium oxide during the sintering process. NiAl/Mo-AgVO{sub 3} exhibited superior tribological properties at a board temperature range. Phase composition on the worn surface was varied with temperatures. Self-adjusted action was responsible for the improvement of tribological properties.

  16. Study on Shielding Requirements for Radioactive Waste Transportation in a Mo-99 Production Plant - 13382

    SciTech Connect (OSTI)

    Melo Rego, Maria Eugenia de; Kazumi Sakata, Solange; Vicente, Roberto; Hiromoto, Goro [Nuclear and Energy Research Institute, IPEN-CNEN/SP (Brazil)] [Nuclear and Energy Research Institute, IPEN-CNEN/SP (Brazil)

    2013-07-01

    Brazil is currently planning to produce {sup 99}Mo from fission of low enriched uranium (LEU) targets. The planned end of irradiation activity of {sup 99}Mo is about 185 TBq (5 kCi) per week to meet the present domestic demand of {sup 99m}Tc generators. The radioactive wastes from the production plant will be transferred to a waste treatment facility at the same site. The total activity of the actinides, fission and activation products present in the wastes can be predicted based on the yields of fission and activation data for the irradiation conditions, such as composition and mass of uranium targets, irradiation time, neutron flux, production schedule, etc., which were in principle already established by the project management. The transportation of the wastes from the production plant to the treatment facility will be done by means of special shielded packages. An assessment of the shielding required for the packages has been done and the results are presented here, aiming at contributing to the design of the waste management facility for the {sup 99}Mo production plant. (authors)

  17. Exciton-dominated dielectric function of atomically thin MoS2 films

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yu, Yiling; Yu, Yifei; Cai, Yongqing; Li, Wei; Gurarslan, Alper; Peelaers, Hartwin; Aspnes, David E.; Van de Walle, Chris G.; Nguyen, Nhan V.; Zhang, Yong -Wei; et al

    2015-11-24

    We systematically measure the dielectric function of atomically thin MoS2 films with different layer numbers and demonstrate that excitonic effects play a dominant role in the dielectric function when the films are less than 5–7 layers thick. The dielectric function shows an anomalous dependence on the layer number. It decreases with the layer number increasing when the films are less than 5–7 layers thick but turns to increase with the layer number for thicker films. We show that this is because the excitonic effect is very strong in the thin MoS2 films and its contribution to the dielectric function maymore » dominate over the contribution of the band structure. We also extract the value of layer-dependent exciton binding energy and Bohr radius in the films by fitting the experimental results with an intuitive model. The dominance of excitonic effects is in stark contrast with what reported at conventional materials whose dielectric functions are usually dictated by band structures. Lastly, the knowledge of the dielectric function may enable capabilities to engineer the light-matter interactions of atomically thin MoS2 films for the development of novel photonic devices, such as metamaterials, waveguides, light absorbers, and light emitters.« less

  18. Electrical properties of a-C:Mo films produced by dual-cathode filtered cathodic arc plasma deposition

    SciTech Connect (OSTI)

    Sansongsiri, Sakon; Anders, Andre; Yodsombat, Banchob

    2008-01-20

    Molybdenum-containing amorphous carbon (a-C:Mo) thin films were prepared using a dual-cathode filtered cathodic arc plasma source with a molybdenum and a carbon (graphite) cathode. The Mo content in the films was controlled by varying the deposition pulse ratio of Mo and C. Film sheet resistance was measured in situ at process temperature, which was close to room temperature, as well as ex situ as a function of temperature (300-515 K) in ambient air. Film resistivity and electrical activation energy were derived for different Mo and C ratios and substrate bias. Film thickness was in the range 8-28 nm. Film resistivity varied from 3.55x10-4 Omega m to 2.27x10-6 Omega m when the Mo/C pulse ratio was increased from 0.05 to 0.4, with no substrate bias applied. With carbon-selective bias, the film resistivity was in the range of 4.59x10-2 and 4.05 Omega m at a Mo/C pulse ratio of 0.05. The electrical activation energy decreased from 3.80x10-2 to 3.36x10-4 eV when the Mo/C pulse ratio was increased in the absence of bias, and from 0.19 to 0.14 eV for carbon-selective bias conditions. The resistivity of the film shifts systematically with the amounts of Mo and upon application of substrate bias voltage. The intensity ratio of the Raman D-peak and G-peak (ID/IG) correlated with the pre-exponential factor (sigma 0) which included charge carrier density and density of states.

  19. Superconducting and structural properties of {delta}-MoC{sub 0.681} cubic molybdenum carbide phase

    SciTech Connect (OSTI)

    Sathish, C.I. [Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo, Hokkaido 060-0810 (Japan) [Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo, Hokkaido 060-0810 (Japan); Superconducting Properties Unit, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Guo, Yanfeng, E-mail: GUO.Yanfeng@nims.go.jp [Superconducting Properties Unit, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan)] [Superconducting Properties Unit, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Wang, Xia [Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo, Hokkaido 060-0810 (Japan) [Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo, Hokkaido 060-0810 (Japan); Superconducting Properties Unit, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Tsujimoto, Yoshihiro [International Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan)] [International Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Li, Jun [Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo, Hokkaido 060-0810 (Japan) [Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo, Hokkaido 060-0810 (Japan); Superconducting Properties Unit, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Zhang, Shoubao [International Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan)] [International Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Matsushita, Yoshitaka [Synchrotron X-ray Station at SPring-8, National Institute for Materials Science, 1-1-1 Kouto, Sayo-cho, Hyogo 679-5148 (Japan)] [Synchrotron X-ray Station at SPring-8, National Institute for Materials Science, 1-1-1 Kouto, Sayo-cho, Hyogo 679-5148 (Japan); Shi, Youguo; Tian, Huanfang; Yang, Huaixin; Li, Jianqi [Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China)] [Beijing National Laboratory for Condensed Matter Physics, Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China); Yamaura, Kazunari, E-mail: YAMAURA.Kazunari@nims.go.jp [Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo, Hokkaido 060-0810 (Japan) [Graduate School of Chemical Sciences and Engineering, Hokkaido University, Sapporo, Hokkaido 060-0810 (Japan); Superconducting Properties Unit, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan)

    2012-12-15

    The superconducting and lattice properties of {delta}-MoC{sub 0.681} were studied by electromagnetic measurements, synchrotron X-ray diffraction, neutron diffraction, and electron diffraction. The superconducting properties (T{sub c}=12 K) of {delta}-MoC{sub 0.681} were well characterized by a weak coupling model. The carbon vacancies present in the host cubic structure were found to be robust, although the material was synthesized from stoichiometric carbon and Mo powder under a high-pressure of 6 GPa. A thermodynamically-stable structure with ordered vacancies did not account for the robust features of {delta}-MoC{sub 0.681} since the vacancies are unlikely to be ordered in long range in the host structure. A model based on inherent phonon instability theoretically predicted for a stoichiometric MoC phase might be responsible for the robust features of {delta}-MoC{sub 0.681}. - Graphical Abstract: The cubic molybdenum carbide shows an excellent superconductivity with robust carbon vacancies. Inherent phonon instability theoretically predicted for a stoichiometric MoC phase might be responsible for the vacancies rather than a thermodynamically-stable structure with vacancies ordering. Highlights: Black-Right-Pointing-Pointer The 12 K superconductivity is well characterized by a weakly coupling model. Black-Right-Pointing-Pointer Carbon vacancies are robust and disordered in the cubic host structure. Black-Right-Pointing-Pointer Inherent phonon instability might be responsible for the robust carbon vacancies in {delta}-MoC{sub 0.681}.

  20. Low-frequency 1/f noise in MoS{sub 2} transistors: Relative contributions of the channel and contacts

    SciTech Connect (OSTI)

    Renteria, J.; Jiang, C.; Samnakay, R.; Rumyantsev, S. L.; Goli, P.; Balandin, A. A.; Shur, M. S.

    2014-04-14

    We report on the results of the low-frequency (1/f, where f is frequency) noise measurements in MoS{sub 2} field-effect transistors revealing the relative contributions of the MoS{sub 2} channel and Ti/Au contacts to the overall noise level. The investigation of the 1/f noise was performed for both as fabricated and aged transistors. It was established that the McWhorter model of the carrier number fluctuations describes well the 1/f noise in MoS{sub 2} transistors, in contrast to what is observed in graphene devices. The trap densities extracted from the 1/f noise data for MoS{sub 2} transistors, are 2??10{sup 19}?eV{sup ?1}cm{sup ?3} and 2.5??10{sup 20}?eV{sup ?1}cm{sup ?3} for the as fabricated and aged devices, respectively. It was found that the increase in the noise level of the aged MoS{sub 2} transistors is due to the channel rather than the contact degradation. The obtained results are important for the proposed electronic applications of MoS{sub 2} and other van der Waals materials.

  1. Preparation of Al{sub 2}O{sub 3}/Mo nanocomposite powder via chemical route and spray drying

    SciTech Connect (OSTI)

    Lo, M.; Cheng, F.; Wei, W.J.

    1996-08-01

    A route to prepare nanometer-sized Mo particulates in Al{sub 2}O{sub 3} was attempted by a combination of solution reactions in molecular scale and forcing precipitation by a spray-drying technique. MoO{sub 3} was first dissolved in ammonia water and then added in the slurry with high purity, submicrometer Al{sub 2}O{sub 3} powder. Mixed suspension was spray-dried, and then the dried granules were reduced by hydrogen gas and further hot-pressing to a bulky composite at various temperatures. Dissolution of Mo oxide, adsorption reactions on alumina surface, and surface potential of alumina particles in homogeneous ammonia suspension were studied. Characterization of the granules, including compactability, flowing properties, surface morphology, grain growth of Mo and Al{sub 2}O{sub 3}, and mixing homogeneity, were examined. Homogeneity of the spray-dried granules was determined by the calculation of mixing index and the observation of the microstructure of sintered body. The existence of intergranular, intragranular, and nanosized Mo particulates within Al{sub 2}O{sub 3} grains was observed by transmission electron microscopy (TEM). All the evidences revealed that homogeneous composites with nanometer-sized Mo had been successfully prepared by this attempt with the proposed chemical route and following spray-drying process. {copyright}{ital 1996 Materials Research Society.}

  2. Kinetic study of hydrogen evolution reaction on Ni{sub 30} Mo{sub 70}, Co{sub 30}Mo{sub 70}, Co{sub 30}Ni{sub 70} and Co{sub 10}Ni{sub 20}Mo{sub 70} alloy electrodes

    SciTech Connect (OSTI)

    Dominguez-Crespo, M.A.; Plata-Torres, M.; Torres-Huerta, A.M.; Arce-Estrada, E.M. . E-mail: earce@ipn.mx; Hallen-Lopez, J.M.

    2005-07-15

    The hydrogen evolution reaction on nanocrystalline Ni{sub 30}Mo{sub 70}, Co{sub 30}Mo{sub 70}, Co{sub 30}Ni{sub 70}, and Co{sub 10}Ni{sub 20}Mo{sub 70}, metallic powders prepared by mechanical alloying was investigated with linear polarization and ac impedance methods, in 30 wt.% KOH aqueous solution at room temperature. The formation process and structural properties of these nanocrystalline materials were characterized by X-ray diffraction and transmission electron microscopy. Alloyed powders showed the presence of two phases: an fcc solid solution and intermetallic compounds of Ni, Co and Mo. Based on polarization and ac impedance measurements, an improved electrocatalytic activity for hydrogen evolution reaction was observed in mechanically alloyed Co{sub 30}Ni{sub 70} powders, which is slightly higher than milled metallic Ni powders.

  3. Characterization of few-layer 1T-MoSe{sub 2} and its superior performance in the visible-light induced hydrogen evolution reaction

    SciTech Connect (OSTI)

    Gupta, Uttam; Naidu, B. S.; Maitra, Urmimala; Rao, C. N. R.; Singh, Anjali; Shirodkar, Sharmila N.; Waghmare, Umesh V.

    2014-09-01

    Based on earlier results on the photocatalytic properties of MoS{sub 2}, the 1T form of MoSe{sub 2}, prepared by lithium intercalation and exfoliation of bulk MoSe{sub 2}, has been employed for the visible-light induced generation of hydrogen. 1T-MoSe{sub 2} is found to be superior to both 2H and 1T MoS{sub 2} as well as 2H-MoSe{sub 2} in producing hydrogen from water, the yield being in the 6075 mmol?h{sup ?1}?g{sup ?1} range with a turn over frequency of 1519 h{sup ?1}. First principles calculations reveal that 1T-MoSe{sub 2} has a lower work function than 2H-MoSe{sub 2} as well as 1T and 2H-MoS{sub 2}, making it easier to transfer an electron from 1T-MoSe{sub 2} for the production of H{sub 2}.

  4. A practical grinding-assisted dry synthesis of nanocrystalline NiMoO{sub 4} polymorphs for oxidative dehydrogenation of propane

    SciTech Connect (OSTI)

    Chen Miao; Wu Jialing; Liu Yongmei; Cao Yong; Guo Li; He Heyong; Fan Kangnian

    2011-12-15

    A practical two-stage reactive grinding-assisted pathway waste-free and cost-effective for the synthesis of NiMoO{sub 4} has been successfully developed. It was demonstrated that proper design in synthetic strategy for grinding plays a crucial role in determining the ultimate polymorph of NiMoO{sub 4}. Specifically, direct grinding (DG) of MoO{sub 3} and NiO rendered {alpha}-NiMoO{sub 4} after annealing, whereas sequential grinding (SG) of the two independently pre-ground oxides followed by annealing generated {beta}-NiMoO{sub 4} solid solution. Characterizations in terms of Raman and X-ray diffraction suggest the creation of {beta}-NiMoO{sub 4} precursor in the latter alternative is the key aspect for the formation of {beta}-NiMoO{sub 4}. The DG-derived {alpha}-NiMoO{sub 4} tested by oxidative dehydrogenation of propane exhibited superior activity in contrast to its analog synthesized via conventional coprecipitation. It is suggested that the favorable chemical composition facilely obtained via grinding in contrast to that by coprecipitation was essential for achieving a more selective production of propylene. - Graphical Abstract: Grinding-assisted synthesis of NiMoO{sub 4} offers higher and more reproducible activities in contrast to coprecipitation for oxidative dehydrogenation of propane, and both {alpha}- and {beta}-NiMoO{sub 4} can be synthesized. Highlights: Black-Right-Pointing-Pointer NiMoO{sub 4} was prepared through grinding-assisted pathway. Black-Right-Pointing-Pointer Direct/sequential grinding rendered {alpha}-, {beta}-NiMoO{sub 4}, respectively. Black-Right-Pointing-Pointer Grinding-derived {alpha}-NiMoO{sub 4} showed high and reproducible activity for oxidative dehydrogenation of propane.

  5. Searches for supersymmetry using the M$_{T2}$ variable in hadronic events produced in pp collisions at 8 TeV

    SciTech Connect (OSTI)

    Khachatryan, V.

    2015-05-15

    Searches for supersymmetry (SUSY) are performed using a sample of hadronic events produced in 8 TeV pp collisions at the CERN LHC. The searches are based on the M$_{T2}$ variable, which is a measure of the transverse momentum imbalance in an event. The data were collected with the CMS detector and correspond to an integrated luminosity of 19.5 fb1. Two related searches are performed. The first is an inclusive search based on signal regions defined by the value of the M$_{T2}$ variable, the hadronic energy in the event, the jet multiplicity, and the number of jets identified as originating from bottom quarks. The second is a search for a mass peak corresponding to a Higgs boson decaying to a bottom quark-antiquark pair, where the Higgs boson is produced as a decay product of a SUSY particle. For both searches, the principal backgrounds are evaluated with data control samples. No significant excess over the expected number of background events is observed, and exclusion limits on various SUSY models are derived.

  6. Martensitic transformation behaviors of rapidly solidified TiNiMo powders

    SciTech Connect (OSTI)

    Kim, Yeon-wook

    2012-10-15

    For the fabrication of bulk near-net-shape shape memory alloys and porous metallic biomaterials, consolidation of TiNiMo alloy powders is more useful than that of elemental powders of Ti, Ni and Mo. Ti{sub 50}Ni{sub 49.9}Mo{sub 0.1} shape memory alloy powders were prepared by gas atomization, and transformation temperatures and microstructures of those powders were investigated as a function of powder size. XRD analysis showed that the B2RB19 martensitic transformation occurred in powders smaller than 150 ?m. According to DSC analysis of the as-atomized powders, the B2R transformation temperature (T{sub R}) of the 2550 ?m powders was 18.4 C. The T{sub R} decreased with increasing powder size, however, the difference in T{sub R} between 2550 ?m powders and 100150 ?m powders is only 1 C. Evaluation of powder microstructures was based on SEM examination of the surface and the polished and etched powder cross sections and the typical images of the rapidly solidified powders showed cellular morphology. Porous cylindrical foams of 10 mm diameter and 1.5 mm length were fabricated by spark plasma sintering (SPS) at 800 C and 5 MPa. Finally these porous TiNi alloy samples are heat-treated for 1 h at 850 C, and then quenched in ice water. The bulk samples have 23% porosity and 4.6 g/cm{sup 3} density and their T{sub R} is 17.8 C.

  7. Extraordinary selectivity of CoMo{sub 3}S{sub 13} chalcogel for C{sub 2}H{sub 6} and CO{sub 2} adsorption.

    SciTech Connect (OSTI)

    Shafaei-Fallah, M.; Rothenberger, Z.; Katsoulidis, A. P.; He, J.; Malliakas, C. D.; Kanatzidis, M. G.

    2011-11-09

    The chalcogel CoMo{sub 3}S{sub 13} is obtained from the reaction of (NH{sub 4}){sub 2}[Mo{sub 3}S{sub 13}] with cobalt acetate in solution. The chalcogel has a BET surface area of 570 m{sup 2} g{sup -1}, and pair distribution function analysis (PDF) and infrared spectroscopy indicate that the [Mo{sub 3}S{sub 13}]{sup 2-} cluster is a building block in the porous network. The CoMo{sub 3}S{sub 13} chalcogel exhibits high selectivity for separating ethane and carbon dioxide from hydrogen and methane.

  8. In Situ Time-Resolved Characterization of Novel Cu-MoO2 Catalysts During the Water-Gas Shift Reaction

    SciTech Connect (OSTI)

    Wen ,W.; Liu, J.; White, M.; Marinkovic, N.; Hanson, J.; Rodriguez, J.

    2007-01-01

    A novel and active Cu-MoO{sub 2} catalyst was synthesized by partial reduction of a precursor CuMoO{sub 4} mixed-metal oxide with CO or H{sub 2} at 200-250 C. The phase transformations of Cu-MoO{sub 2} during H{sub 2} reduction and the water-gas shift reaction could be followed by In situ time resolved XRD techniques. During the reduction process the diffraction pattern of the CuMoO{sub 4} collapsed and the copper metal lines were observed on an amorphous material background that was assigned to molybdenum oxides. During the first pass of water-gas shift (WGS) reaction, diffraction lines for Cu{sub 6}Mo{sub 5}O{sub 18} and MoO{sub 2} appeared around 350 C and Cu{sub 6}Mo{sub 5}O{sub 18} was further transformed to Cu/MoO{sub 2} at higher temperature. During subsequent passes, significant WGS catalytic activity was observed with relatively stable plateaus in product formation around 350, 400 and 500 C. The interfacial interactions between Cu clusters and MoO{sub 2} increased the water-gas shift catalytic activities at 350 and 400 C.

  9. Microsoft Word - chapter FeNiCrMo_ver4.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Low-Alloy Ferritic Steels: Tempered Fe-Ni-Cr-Mo Alloys (code 1212) Prepared by: B.P. Somerday, Sandia National Laboratories Editors C. San Marchi B.P. Somerday Sandia National Laboratories This report may be updated and revised periodically in response to the needs of the technical community; up-to-date versions can be requested from the editors at the address given below or downloaded at http://www.ca.sandia.gov/matlsTechRef/ . The success of this reference depends upon feedback from the

  10. Corrosion and degradation of a polyurethane/Co-Ni-Cr-Mo pacemaker lead

    SciTech Connect (OSTI)

    Sung, P.; Fraker, A.C.

    1987-12-01

    An investigation to study changes in the metal surfaces and the polyurethane insulation of heart pacemaker leads under controlled in vitro conditions was conducted. A polyurethane (Pellethane 2363-80A)/Co-Ni-Cr-Mo (MP35N) wire lead was exposed in Hanks' physiological saline solution for 14 months and then analyzed using scanning electron microscopy, x-ray energy dispersive analysis, and small angle x-ray scattering. Results showed that some leakage of solution into the lead had occurred and changes were present on both the metal and the polyurethane surfaces.

  11. Spin and valley transport in monolayers of MoS{sub 2}

    SciTech Connect (OSTI)

    Sun, J. F.; Cheng, F.

    2014-04-07

    We investigate theoretically quantum transport and Goos-Hnchen (GH) effect of electrons in a p-n-p junction on monolayers of MoS{sub 2}. We find that the transmission properties of spin-up (spin-down) electrons in K valley are the same with spin-down (spin-up) electrons in K? valley due to the time-reversal symmetry. The GH shifts for the transmitted K and K? beams in the n-p interface are in the opposite direction, and GH shifts for the spin-up and spin-down electron beams at the same valley have different values in the same direction due to the different group velocities. Therefore, the spin-up and spin-down electrons can be separated after passing a sufficiently long channel created by a p-n-p junction. These features provide us a new way to generate a fully spin- and valley-polarized current in monolayers of MoS{sub 2}.

  12. On the bonding nature of electron states for the Fe-Mo double perovskite

    SciTech Connect (OSTI)

    Carvajal, E.; Cruz-Irisson, M.; Oviedo-Roa, R.; Navarro, O.

    2014-05-15

    The electronic transport as well as the effect of an external magnetic field has been investigated on manganese-based materials, spinels and perovskites. Potential applications of double perovskites go from magnetic sensors to electrodes in solid-oxide fuel cells; besides the practical interests, it is known that small changes in composition modify radically the physical properties of double perovskites. We have studied the Sr{sub 2}FeMoO{sub 6} double perovskite compound (SFMO) using first-principles density functional theory. The calculations were done within the generalized gradient approximation (GGA) scheme with the Perdew-Burke-Ernzerhof (PBE) functional. We have made a detailed analysis of each electronic state and the charge density maps around the Fermi level. For the electronic properties of SFMO it was used a primitive cell, for which we found the characteristic half-metallic behavior density of states composed by e{sub g} and t{sub 2g} electrons from Fe and Mo atoms. Those peaks were tagged as bonding or antibonding around the Fermi level at both, valence and conduction bands.

  13. Experimental study of the electric dipole strength in the even Mo nuclei and its deformation dependence

    SciTech Connect (OSTI)

    Erhard, M.; Junghans, A. R.; Nair, C.; Schwengner, R.; Beyer, R.; Klug, J.; Kosev, K.; Wagner, A.; Grosse, E.

    2010-03-15

    Two methods based on bremsstrahlung were applied to the stable even Mo isotopes for the experimental determination of the photon strength function covering the high excitation energy range above 4 MeV with its increasing level density. Photon scattering was used up to the neutron separation energies S{sub n} and data up to the maximum of the isovector giant resonance (GDR) were obtained by photoactivation. After a proper correction for multistep processes the observed quasicontinuous spectra of scattered photons show a remarkably good match to the photon strengths derived from nuclear photoeffect data obtained previously by neutron detection and corrected in absolute scale by using the new activation results. The combined data form an excellent basis to derive a shape dependence of the E1 strength in the even Mo isotopes with increasing deviation from the N=50 neutron shell (i.e., with the impact of quadrupole deformation and triaxiality). The wide energy coverage of the data allows for a stringent assessment of the dipole sum rule and a test of a novel parametrization developed previously which is based on it. This parametrization for the electric dipole strength function in nuclei with A>80 deviates significantly from prescriptions generally used previously. In astrophysical network calculations it may help to quantify the role the p-process plays in cosmic nucleosynthesis. It also has impact on the accurate analysis of neutron capture data of importance for future nuclear energy systems and waste transmutation.

  14. Electronic structure and conductivity of nanocomposite metal (Au,Ag,Cu,Mo)-containing amorphous carbon films

    SciTech Connect (OSTI)

    Endrino, Jose L.; Horwat, David; Gago, Raul; Andersson, Joakim; Liu, Y.S.; Guo, Jinghua; Anders, Andre

    2008-05-14

    In this work, we study the influence of the incorporation of different metals (Me = Au, Ag, Cu, Mo) on the electronic structure of amorphous carbon (a-C:Me) films. The films were produced at room temperature using a novel pulsed dual-cathode arc deposition technique. Compositional analysis was performed with secondary neutral mass spectroscopy whereas X-ray diffraction was used to identify the formation of metal nanoclusters in the carbon matrix. The metal content incorporated in the nanocomposite films induces a drastic increase in the conductivity, in parallel with a decrease in the band gap corrected from Urbach energy. The electronic structure as a function of the Me content has been monitored by x-ray absorption near edge structure (XANES) at the C K-edge. XANES showed that the C host matrix has a dominant graphitic character and that it is not affected significantly by the incorporation of metal impurities, except for the case of Mo, where the modifications in the lineshape spectra indicated the formation of a carbide phase. Subtle modifications of the spectral lineshape are discussed in terms of nanocomposite formation.

  15. MoO3 as combined hole injection layer and tapered spacer in combinatorial multicolor microcavity organic light emitting diodes

    SciTech Connect (OSTI)

    Liu, R.; Xu, Chun; Biswas, Rana; Shinar, Joseph; Shinar, Ruth

    2011-09-01

    Multicolor microcavity ({mu}C) organic light-emitting diode (OLED) arrays were fabricated simply by controlling the hole injection and spacer MoO{sub 3} layer thickness. The normal emission was tunable from {approx}490 to 640 nm and can be further expanded. A compact, integrated spectrometer with two-dimensional combinatorial arrays of {mu}C OLEDs was realized. The MoO{sub 3} yields more efficient and stable devices, revealing a new breakdown mechanism. The pixel current density reaches {approx}4 A/cm{sup 2} and a maximal normal brightness {approx}140 000 Cd/m{sup 2}, which improves photoluminescence-based sensing and absorption measurements.

  16. Comparison of Two Preparation Methods on Catalytic Activity and Selectivity of Ru-Mo/HZSM5 for Methane Dehydroaromatization

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Petkovic, Lucia M.; Ginosar, Daniel M.

    2014-01-01

    Catalytic performance of Mo/HZSM5 and Ru-Mo/HZSM5 catalysts prepared by vaporization-deposition of molybdenum trioxide and impregnation with ammonium heptamolybdate was analyzed in terms of catalyst activity and selectivity, nitrogen physisorption analyses, temperature-programmed oxidation of carbonaceous residues, and temperature-programmed reduction. Vaporization-deposition rendered the catalyst more selective to ethylene and coke than the catalyst prepared by impregnation. This result was assigned to lower interaction of molybdenum carbide with the zeolite acidic sites.

  17. Enhancing the photocurrent and photoluminescence of single crystal monolayer MoS{sub 2} with resonant plasmonic nanoshells

    SciTech Connect (OSTI)

    Sobhani, Ali [Department of Electrical and Computer Engineering, Rice University, Houston, Texas 77005 (United States); Lauchner, Adam [Department of Physics and Astronomy, Rice University, Houston, Texas 77005 (United States); Najmaei, Sina; Lou, Jun [Department of Materials Science and NanoEngineering, Rice University, Houston, Texas 77005 (United States); Ayala-Orozco, Ciceron; Wen, Fangfang [Department of Chemistry, Rice University, Houston, Texas 77005 (United States); Halas, Naomi J., E-mail: halas@rice.edu [Department of Electrical and Computer Engineering, Rice University, Houston, Texas 77005 (United States); Department of Physics and Astronomy, Rice University, Houston, Texas 77005 (United States)

    2014-01-20

    Monolayer molybdenum disulfide (MoS{sub 2}) produced by controlled vapor-phase synthesis is a commercially promising new two-dimensional material for optoelectronics because of its direct bandgap and broad absorption in the visible and ultraviolet regimes. By tuning plasmonic core-shell nanoparticles to the direct bandgap of monolayer MoS{sub 2} and depositing them sparsely (<1% coverage) onto the material's surface, we observe a threefold increase in photocurrent and a doubling of photoluminescence signal for both excitonic transitions, amplifying but not altering the intrinsic spectral response.

  18. Visualizing the Surface Infrastructure Used to Move 2 MtCO2/year from the Dakota Gasification Company to the Weyburn CO2 Enhanced Oil Recovery Project: Version of July 1, 2009

    SciTech Connect (OSTI)

    Dooley, James J.

    2009-07-09

    Google Earth Pro has been employed to create an interactive flyover of the worlds largest operational carbon dioxide capture and storage project. The visualization focuses on the transport and storage of 2 MtCO2/year which is captured from the Dakota Gasification Facility (Beula, North Dakota) and transported 205 miles and injected into the Weyburn oil field in Southeastern Saskatchewan.

  19. Preparation and structural study from neutron diffraction data of Pr{sub 5}Mo{sub 3}O{sub 16}

    SciTech Connect (OSTI)

    Martinez-Lope, M.J.; Alonso, J.A.; Sheptyakov, D.; Pomjakushin, V.

    2010-12-15

    The title compound has been prepared as polycrystalline powder by thermal treatments of mixtures of Pr{sub 6}O{sub 11} and MoO{sub 2} in air. In the literature, an oxide with a composition Pr{sub 2}MoO{sub 6} has been formerly described to present interesting catalytic properties, but its true stoichiometry and crystal structure are reported here for the first time. It is cubic, isostructural with CdTm{sub 4}Mo{sub 3}O{sub 16} (space group Pn-3n, Z=8), with a=11.0897(1) A. The structure contains MoO{sub 4} tetrahedral units, with Mo-O distances of 1.788(2) A, fully long-range ordered with PrO{sub 8} polyhedra; in fact it can be considered as a superstructure of fluorite (M{sub 8}O{sub 16}), containing 32 MO{sub 2} fluorite formulae per unit cell, with a lattice parameter related to that of cubic fluorite (a{sub f}=5.5 A) as a{approx}2a{sub f}. A bond valence study indicates that Mo exhibits a mixed oxidation state between 5+ and 6+ (perhaps accounting for the excellent catalytic properties). One kind of Pr atoms is trivalent whereas the second presents a mixed Pr{sup 3+}-Pr{sup 4+} oxidation state. The similarity of the XRD pattern with that published for Ce{sub 2}MoO{sub 6} suggests that this compound also belongs to the same structural type, with an actual stoichiometry Ce{sub 5}Mo{sub 3}O{sub 16}. -- Graphical Abstract: Formerly formulated as Pr{sub 2}MoO{sub 6}, the title compound is a cubic superstructure of fluorite (a=11.0897(1) A, space group Pn-3n) due to the long-range ordering of PrO{sub 8} scalenohedra and MoO{sub 4} tetrahedral units, showing noticeable shifts of the oxygen positions in order to provide a tetrahedral coordination for Mo ions. A mixed valence Mo{sup 5+}-Mo{sup 6+} is identified, which could account for the excellent catalytic properties of this material. Display Omitted

  20. Toward epitaxially grown two-dimensional crystal hetero-structures: Single and double MoS{sub 2}/graphene hetero-structures by chemical vapor depositions

    SciTech Connect (OSTI)

    Lin, Meng-Yu [Graduate Institute of Electronics Engineering, National Taiwan University, Taipei, Taiwan (China); Research Center for Applied Sciences, Academia Sinica, Nankang, Taipei, Taiwan (China); Chang, Chung-En [Department of Photonics, National Chiao-Tung University, Hsinchu, Taiwan (China); Wang, Cheng-Hung [Institute of Display, National Chiao-Tung University, Hsinchu, Taiwan (China); Su, Chen-Fung; Chen, Chi [Research Center for Applied Sciences, Academia Sinica, Nankang, Taipei, Taiwan (China); Lee, Si-Chen [Graduate Institute of Electronics Engineering, National Taiwan University, Taipei, Taiwan (China); Lin, Shih-Yen, E-mail: shihyen@gate.sinica.edu.tw [Graduate Institute of Electronics Engineering, National Taiwan University, Taipei, Taiwan (China); Research Center for Applied Sciences, Academia Sinica, Nankang, Taipei, Taiwan (China); Department of Photonics, National Chiao-Tung University, Hsinchu, Taiwan (China)

    2014-08-18

    Uniform large-size MoS{sub 2}/graphene hetero-structures fabricated directly on sapphire substrates are demonstrated with layer-number controllability by chemical vapor deposition (CVD). The cross-sectional high-resolution transmission electron microscopy (HRTEM) images provide the direct evidences of layer numbers of MoS{sub 2}/graphene hetero-structures. Photo-excited electron induced Fermi level shift of the graphene channel are observed on the single MoS{sub 2}/graphene hetero-structure transistors. Furthermore, double hetero-structures of graphene/MoS{sub 2}/graphene are achieved by CVD fabrication of graphene layers on top of the MoS{sub 2}, as confirmed by the cross-sectional HRTEM. These results have paved the possibility of epitaxially grown multi-hetero-structures for practical applications.

  1. High-temperature behavior of dicesium molybdate Cs{sub 2}MoO{sub 4}: Implications for fast neutron reactors

    SciTech Connect (OSTI)

    Wallez, Gilles; Raison, Philippe E.; Smith, Anna L.; Clavier, Nicolas

    2014-07-01

    Dicesium molybdate (Cs{sub 2}MoO{sub 4})'s thermal expansion and crystal structure have been investigated herein by high temperature X ray diffraction in conjunction with Raman spectroscopy. This first crystal-chemical insight at high temperature is aimed at predicting the thermostructural and thermomechanical behavior of this oxide formed by the accumulation of Cs and Mo fission products at the periphery of nuclear fuel rods in sodium-cooled fast reactors. Within the temperature range of the fuel's rim, Cs{sub 2}MoO{sub 4} becomes hexagonal P6{sub 3}/mmc, with disordered MoO{sub 4} tetrahedra and 2D distribution of CsO bonds that makes thermal axial expansion both large (50??{sub l}?70 10{sup ?6} C{sup ?1}, 500800 C) and highly anisotropic (?{sub c}??{sub a}=6710{sup ?6} C{sup ?1}, hexagonal form). The difference with the fuel's expansion coefficient is of potential concern with respect to the cohesion of the Cs{sub 2}MoO{sub 4} surface film and the possible release of cesium radionuclides in accidental situations. - Graphical abstract: The weakness of the CsO bonds and the disordering of the MoO{sub 4} tetrahedra array in the high-temperature form are responsible for the huge thermal expansion of Cs{sub 2}MoO{sub 4} along the c-axis. - Highlights: Thermomechanical behavior of Cs{sub 2}MoO{sub 4} fission products compound is studied. High-temperature form of Cs{sub 2}MoO{sub 4} is characterized by XRD and Raman. Thermal expansion appears very high and anisotropic. Cohesion between Cs{sub 2}MoO{sub 4} and nuclear fuel seems questionable, and Cs release is expected.

  2. Role of Si on the Diffusional Interactions between U-Mo and Al-Si Alloys at 823 K (550 degrees C)

    SciTech Connect (OSTI)

    E. Perez; Y.H. Sohn; D.D. Keiser, Jr.

    2013-01-01

    U-Mo dispersions in Al-alloy matrix and monolithic fuels encased in Al-alloy are under development to fulfill the requirements for research and test reactors to use low-enriched molybdenum stabilized uranium alloys fuels. Significant interaction takes place between the U-Mo fuel and Al during manufacturing and in-reactor irradiation. The interactions products are Al-rich phases with physical and thermal characteristics that adversely affect fuel performance and lead to premature failure. Detailed analysis of the interdiffusion and microstructural development of this system was carried through diffusion couples consisting of U-7wt.%Mo, U-10wt.%Mo and U-12wt.%Mo in contact with pure Al, Al-2wt.%Si, and Al-5wt.%Si, annealed at 823K for 1, 5 and 20 hours. Scanning electron microscopy (SEM) and transmission electron microscopy (TEM) were employed for the analysis. Diffusion couples consisting of U-Mo vs. pure Al contained UAl3, UAl4, U6Mo4Al43, and UMo2Al20 phases. The addition of Si to the Al significantly reduced the thickness of the interdiffusion zone. The interdiffusion zones developed Al and Si enriched regions, whose locations and size depended on the Si and Mo concentrations in the terminal alloys. In the couples, the (U,Mo)(Al,Si)3 phase was observed throughout interdiffusion zone, and the U6Mo4Al43 and UMo2Al20 phases were observed only where the Si concentrations were low.

  3. Development and validation of capabilities to measure thermal properties of layered monolithic U-Mo alloy plate-type fuel

    SciTech Connect (OSTI)

    Burkes, Douglas; Casella, Andrew M.; Buck, Edgar C.; Casella, Amanda J.; Edwards, Matthew K.; MacFarlan, Paul J.; Pool, Karl N.; Smith, Frances N.; Steen, Franciska H.

    2014-07-19

    The uranium-molybdenum (U-Mo) alloy in a monolithic form has been proposed as one fuel design capable of converting some of the worlds highest power research reactors from the use of high enriched uranium (HEU) to low enriched uranium (LEU). One aspect of the fuel development and qualification process is to demonstrate appropriate understanding of thermal conductivity behavior of the fuel system as a function of temperature and expected irradiation conditions. The purpose of this paper is to verify and validate the functionality of equipment methods installed in hot cells for eventual measurements on irradiated uranium-molybdenum (U-Mo) monolithic fuel specimens, procedures to operate the equipment, and models to extract the desired thermal properties. The results presented here demonstrate the adequacy of the equipment, procedures and models that have been developed for this purpose based on measurements conducted on surrogate depleted uranium-molybdenum (DU-Mo) alloy samples containing a zirconium diffusion barrier and clad in aluminum alloy 6061 (AA6061). The results are in excellent agreement with thermal property data reported in the literature for similar U-Mo alloys as a function of temperature.

  4. Concept Feasibility Report for Using Co-Extrusion to Bond Metals to Complex Shapes of U-10Mo

    SciTech Connect (OSTI)

    Lavender, Curt A.; Paxton, Dean M.; Smith, Mark T.; Soulami, Ayoub; Joshi, Vineet V.; Burkes, Douglas

    2013-12-30

    In support of the Convert Program of the U.S. Department of Energys National Nuclear Security Administration (DOE/NNSA) Global Threat Reduction Initiative (GTRI), Pacific Northwest National Laboratory (PNNL) has been investigating manufacturing processes for the uranium-10% molybdenum (U-10Mo) alloy plate fuel for the U.S. high-performance research reactors (USHPRR). This report documents the results of PNNLs efforts to develop the extrusion process for this concept. The approach to the development of a co-extruded complex-shaped fuel has been described and an extrusion of DU-10Mo was made. The initial findings suggest that given the extrusion forces required for processing U-10Mo, the co-extrusion process can meet the production demands of the USHPRR fuel and may be a viable production method. The development activity is in the early stages and has just begun to identify technical challenges to address details such as dimensional tolerances and shape control. New extrusion dies and roll groove profiles have been developed and will be assessed by extrusion and rolling of U-10Mo during the next fiscal year. Progress on the development and demonstration of the co-extrusion process for flat and shaped fuel is reported in this document

  5. Modification of polymer velvet cathode via metallic Mo coating for enhancement of high-current electron emission performances

    SciTech Connect (OSTI)

    Xiong, Ying; Wang, Bing; Yi, Yong; Xia, Liansheng; Zhang, Huang

    2013-09-15

    The effect of surface Mo coating on the high-current electron emission performances for polymer velvet cathode has been investigated in a diode with A-K gap of 11.5 cm by the combination of time-resolved electrical diagnostic and temporal pressure variation. Compared with uncoated polymer velvet cathode under the single-pulsed emission mode, the Mo-coated one shows lower outgassing levels (?0.40 Pa L), slower cathode plasma expansion velocity (?2.30 cm/?s), and higher emission stability as evidences by the change in cathode current, temporal pressure variation, and diode perveance. Moreover, after Mo coating, the emission consistency of the polymer velvet cathode between two adjacent pulses is significantly improved in double-pulsed emission mode with ?500 ns interval between two pulses, which further confirms the effectiveness of Mo coating for enhancement of electron emission performance of polymer velvet cathodes. These results should be of interest to the high-repetitive high-power microwave systems with cold cathodes.

  6. Thermomechanical process optimization of U-10wt% Mo Part 2: The effect of homogenization on the mechanical properties and microstructure

    SciTech Connect (OSTI)

    Joshi, Vineet V.; Nyberg, Eric A.; Lavender, Curt A.; Paxton, Dean M.; Burkes, Douglas E.

    2015-07-09

    Low-enriched uranium alloyed with 10 wt% molybdenum (U-10Mo) is currently being investigated as an alternative fuel for the highly enriched uranium used in several of the United States high performance research reactors. Development of the methods to fabricate the U-10Mo fuel plates is currently underway and requires fundamental understanding of the mechanical properties at the expected processing temperatures. In the first part of this series, it was determined that the as-cast U-10Mo had a dendritic microstructure with chemical inhomogeneity and underwent eutectoid transformation during hot compression testing. In the present (second) part of the work, the as-cast samples were heat treated at several temperatures and times to homogenize the Mo content. Like the previous as-cast material, the homogenized materials were then tested under compression between 500 and 800C. The as-cast samples and those treated at 800C for 24 hours had grain sizes of 25-30 ?m, whereas those treated at 1000C for 16 hours had grain sizes around 250 ?m before testing. Upon compression testing, it was determined that the heat treatment had effects on the mechanical properties and the precipitation of the lamellar phase at sub-eutectoid temperatures.

  7. Mesoporous carbon-containing MoS{sub 2} materials formed from the in situ decomposition of tetraalkylammonium thiomolybdates

    SciTech Connect (OSTI)

    Alonso, Gabriel; Berhault, Gilles; Paraguay, Francisco; Rivera, Eric; Fuentes, Sergio; Chianelli, Russell R

    2003-05-26

    Molybdenum disulfide with unique mesoporous structure was synthesized from tetraalkylammonium thiometallate precursors in situ decomposed in a batch reactor in the presence of dibenzothiophene (DBT). The precursors used in this study were tetraalkylammonium thiomolybdates with alkyl groups ranging from propyl to octyl. Molybdenum disulfide thus prepared presents high surface area (from 255 up to 329 m{sup 2}/g), high content of carbon (C/Mo=2.7-4.0) and type IV nitrogen adsorption-desorption isotherms when decomposed from tetrahexyl-, tetraheptyl- or tetraoctylammonium thiomolybdates. The as-formed materials are poorly crystallized with a very weak intensity of the (0 0 2) peak of the 2H-MoS{sub 2} structure. Such diffraction patterns are characteristic of exfoliated samples. Characterization by TEM shows a disordered layered structure with no long range order for the MoS{sub 2} catalysts. Therefore, the nature of the alkyl group in the precursor affects both the surface area and the pore size distribution of the final MoS{sub 2} catalysts with a progressive morphological modification up to a mesoporous organization.

  8. The photocatalysis of Bi{sub 2}MoO{sub 6} under the irradiation of blue LED

    SciTech Connect (OSTI)

    Sun, Yuanyuan; Wang, Wenzhong Zhang, Ling; Sun, Songmei

    2013-10-15

    Graphical abstract: - Highlights: • ·OH trap and hole sink were involved to investigate the active radicals. • Holes play a more important role in the degradation of RhB. • The ·OH were related to the decomposition of phenol. • The ·O{sub 2}-played a leading role in the photodegradation of phenol. • Blue LED is competitive and promising alternative for the future application. - Abstract: Bi{sub 2}MoO{sub 6} has been reported as a promising photocatalyst in wastewater treatment. The active radicals generated over the Bi{sub 2}MoO{sub 6} during the photocatalytic process were thought to be hydroxyl radical (·OH) but have not been proved. Herein, Bi{sub 2}MoO{sub 6} with nanoplate like morphology was synthesized and its photocatalytic performances in the degradation of rhodamine B (RhB) and phenol as colored and colorless model pollutants respectively were evaluated under the irradiation of blue light emitting diode (LED). The tert-butyl alcohol (TBA) as a ·OH trap and ethylene diamine tetraacetic acid (EDTA) as a hole sink were involved to investigate the main active groups that are generated on Bi{sub 2}MoO{sub 6} and function during the photodegradation of RhB and phenol. In addition, it is a competitive and promising alternative plan to use blue LED as light source for the future practical application in environmental remediation.

  9. Prediction of U-Mo dispersion nuclear fuels with Al-Si alloy using artificial neural network

    SciTech Connect (OSTI)

    Susmikanti, Mike; Sulistyo, Jos

    2014-09-30

    Dispersion nuclear fuels, consisting of U-Mo particles dispersed in an Al-Si matrix, are being developed as fuel for research reactors. The equilibrium relationship for a mixture component can be expressed in the phase diagram. It is important to analyze whether a mixture component is in equilibrium phase or another phase. The purpose of this research it is needed to built the model of the phase diagram, so the mixture component is in the stable or melting condition. Artificial neural network (ANN) is a modeling tool for processes involving multivariable non-linear relationships. The objective of the present work is to develop code based on artificial neural network models of system equilibrium relationship of U-Mo in Al-Si matrix. This model can be used for prediction of type of resulting mixture, and whether the point is on the equilibrium phase or in another phase region. The equilibrium model data for prediction and modeling generated from experimentally data. The artificial neural network with resilient backpropagation method was chosen to predict the dispersion of nuclear fuels U-Mo in Al-Si matrix. This developed code was built with some function in MATLAB. For simulations using ANN, the Levenberg-Marquardt method was also used for optimization. The artificial neural network is able to predict the equilibrium phase or in the phase region. The develop code based on artificial neural network models was built, for analyze equilibrium relationship of U-Mo in Al-Si matrix.

  10. Heat treated 9 Cr-1 Mo steel material for high temperature application

    DOE Patents [OSTI]

    Jablonski, Paul D.; Alman, David; Dogan, Omer; Holcomb, Gordon; Cowen, Christopher

    2012-08-21

    The invention relates to a composition and heat treatment for a high-temperature, titanium alloyed, 9 Cr-1 Mo steel exhibiting improved creep strength and oxidation resistance at service temperatures up to 650.degree. C. The novel combination of composition and heat treatment produces a heat treated material containing both large primary titanium carbides and small secondary titanium carbides. The primary titanium carbides contribute to creep strength while the secondary titanium carbides act to maintain a higher level of chromium in the finished steel for increased oxidation resistance, and strengthen the steel by impeding the movement of dislocations through the crystal structure. The heat treated material provides improved performance at comparable cost to commonly used high-temperature steels such as ASTM P91 and ASTM P92, and requires heat treatment consisting solely of austenization, rapid cooling, tempering, and final cooling, avoiding the need for any hot-working in the austenite temperature range.

  11. H-point exciton transitions in bulk MoS{sub 2}

    SciTech Connect (OSTI)

    Saigal, Nihit; Ghosh, Sandip

    2015-05-04

    Reflectance and photoreflectance spectrum of bulk MoS{sub 2} around its direct bandgap energy have been measured at 12?K. Apart from spectral features due to the A and B ground state exciton transitions at the K-point of the Brillouin zone, one observes additional features at nearby energies. Through lineshape analysis the character of two prominent additional features are shown to be quite different from that of A and B. By comparing with reported electronic band structure calculations, these two additional features are identified as ground state exciton transitions at the H-point of the Brillouin zone involving two spin-orbit split valance bands. The excitonic energy gap at the H-point is 1.965?eV with a valance bands splitting of 185?meV. While at the K-point, the corresponding values are 1.920?eV and 205?meV, respectively.

  12. Process for fabricating high reflectance-low stress Mo--Si multilayer reflective coatings

    DOE Patents [OSTI]

    Montcalm, Claude; Mirkarimi, Paul B.

    2001-01-01

    A high reflectance-low stress Mo--Si multilayer reflective coating particularly useful for the extreme ultraviolet (EUV) wavelength region. While the multilayer reflective coating has particular application for EUV lithography, it has numerous other applications where high reflectance and low stress multilayer coatings are utilized. Multilayer coatings having high near-normal incidence reflectance (R.gtoreq.65%) and low residual stress (.ltoreq.100 MPa) have been produced using thermal and non-thermal approaches. The thermal approach involves heating the multilayer coating to a given temperature for a given time after deposition in order to induce structural changes in the multilayer coating that will have an overall "relaxation" effect without reducing the reflectance significantly.

  13. High reflectance-low stress Mo-Si multilayer reflective coatings

    DOE Patents [OSTI]

    Montcalm, Claude; Mirkarimi, Paul B.

    2000-01-01

    A high reflectance-low stress Mo-Si multilayer reflective coating particularly useful for the extreme ultraviolet (EUV) wavelength region. While the multilayer reflective coating has particular application for EUV lithography, it has numerous other applications where high reflectance and low stress multilayer coatings are utilized. Multilayer coatings having high near-normal incidence reflectance (R.gtoreq.65%) and low residual stress (.ltoreq.100 MPa) have been produced using thermal and non-thermal approaches. The thermal approach involves heating the multilayer coating to a given temperature for a given time after deposition in order to induce structural changes in the multilayer coating that will have an overall "relaxation" effect without reducing the reflectance significantly.

  14. Microstructural Characterization of Irradiated U-7Mo/Al-5Si Dispersion to High Fission Density

    SciTech Connect (OSTI)

    J. Gan; B. D. Miller; D. D. Keiser, Jr.; A. B. Robinson; J. W. Madden; P. G. Medvedev; D. M. Wachs

    2014-11-01

    The fuel development program for research and test reactors calls for improved knowledge on the effect of microstructure on fuel performance in reactors. This work summarizes the recent TEM microstructural characterization of an irradiated U-7Mo/Al-5Si dispersion fuel plate (R3R050) irradiated in the Advanced Test Reactor (ATR) at Idaho National Laboratory to 5.21021 fissions/cm3. While a large fraction of the fuel grains is decorated with large bubbles, there is no evidence showing interlinking of these large bubbles at the specified fission density. The attachment of solid fission product precipitates to the bubbles is likely the result of fission product diffusion into these bubbles. The process of fission gas bubble superlattice collapse appears through bubble coalescence. The results are compared with the previous TEM work of the dispersion fuels irradiated to lower fission density from the same fuel plate.

  15. Thermodynamic modeling and experimental validation of the Fe-Al-Ni-Cr-Mo alloy system

    SciTech Connect (OSTI)

    Teng, Zhenke; Zhang, F; Miller, Michael K; Liu, Chain T; Huang, Shenyan; Chou, Y.T.; Tien, R; Chang, Y A; Liaw, Peter K

    2012-01-01

    NiAl-type precipitate-strengthened ferritic steels have been known as potential materials for the steam turbine applications. In this study, thermodynamic descriptions of the B2-NiAl type nano-scaled precipitates and body-centered-cubic (BCC) Fe matrix phase for four alloys based on the Fe-Al-Ni-Cr-Mo system were developed as a function of the alloy composition at the aging temperature. The calculated phase structure, composition, and volume fraction were validated by the experimental investigations using synchrotron X-ray diffraction and atom probe tomography. With the ability to accurately predict the key microstructural features related to the mechanical properties in a given alloy system, the established thermodynamic model in the current study may significantly accelerate the alloy design process of the NiAl-strengthened ferritic steels.

  16. Intense femtosecond photoexcitation of bulk and monolayer MoS{sub 2}

    SciTech Connect (OSTI)

    Paradisanos, I.; Fotakis, C.; Kymakis, E.; Kioseoglou, G.; Stratakis, E.

    2014-07-28

    The effect of femtosecond laser irradiation on bulk and single-layer MoS{sub 2} on silicon oxide is studied. Optical, field emission scanning electron microscopy and Raman microscopy were used to quantify the damage. The intensity of A{sub 1g} and E{sub 2g}{sup 1} vibrational modes was recorded as a function of the number of irradiation pulses. The observed behavior was attributed to laser-induced bond breaking and subsequent atoms removal due to electronic excitations. The single-pulse optical damage threshold was determined for the monolayer and bulk under 800?nm and 1030?nm pulsed laser irradiation, and the role of two-photon versus one photon absorption effects is discussed.

  17. Extreme ultraviolet spectra of highly ionized Ge, Kr and Mo emitted by imploding plasmas

    SciTech Connect (OSTI)

    Goldsmith, S.; Feldman, U.; Cohen, L.; Behring, W.E.

    1984-01-01

    Spectra of highly ionized Ge, Kr and Mo in the spectral region of 10 to 80A were excited in laser-produced plasmas. The plasma was obtained by focusing the energy of the 24 laser beams of the University of Rochester Omega system on 0.4 mm diameter microballoon targets. The laser pulse duration was in the range of 0.87 to 1.09 ns, with total energy in the range of 1.8 to 2.2 kJ. The observed spectral lines include n = 2-2 transitions in the oxygen and fluorine isoelectronic sequences and n = 3 to 4 transitions in the sodium, magnesium and aluminum isoelectronic sequences. The present observations are compared with previous experimental and theoretical studies.

  18. Insulator to correlated metal transition in V_1-xMo_xO_2

    SciTech Connect (OSTI)

    Klimczuk, Tomasz; Ronning, Filip; Holman, Katherine; Mcqueen, Tyrel M; Williams, Anthony J; Stephens, P W; Zandbergen, Henny W; Xu, Q; Cava, Robert J

    2009-01-01

    The change from metallic to insulating states is one of the most dramatic transitions that solids undergo on cooling or chemical doping. Many materials display this transition, but only a handful have the right combination of crystal structure and physical properties to serve as model systems. VO{sub 2} is one of those materials. Using Mo as a chemical dopant in VO{sub 2}, we find unanticipated phenomenology for both the electronic and structural characteristics of the resulting insulator to metal transition. The results support a complex, previously proposed scenario involving the coexistence of both electron repulsion and electron pairing for yielding an insulator in VO{sub 2}, but not simply; many issues are raised about local versus itinerant behavior and structure-property correlations in this most iconic ofdoped correlated electron systems.

  19. Microstructural characterization of as-cast biocompatible Co-Cr-Mo alloys

    SciTech Connect (OSTI)

    Giacchi, J.V.; Morando, C.N.; Fornaro, O.; Palacio, H.A.

    2011-01-15

    The microstructure of a cobalt-base alloy (Co-Cr-Mo) obtained by the investment casting process was studied. This alloy complies with the ASTM F75 standard and is widely used in the manufacturing of orthopedic implants because of its high strength, good corrosion resistance and excellent biocompatibility properties. This work focuses on the resulting microstructures arising from samples poured under industrial environment conditions, of three different Co-Cr-Mo alloys. For this purpose, we used: 1) an alloy built up from commercial purity constituents, 2) a remelted alloy and 3) a certified alloy for comparison. The characterization of the samples was achieved by using optical microscopy (OM) with a colorant etchant to identify the present phases and scanning electron microscopy (SE-SEM) and energy dispersion spectrometry (EDS) techniques for a better identification. In general the as-cast microstructure is a Co-fcc dendritic matrix with the presence of a secondary phase, such as the M{sub 23}C{sub 6} carbides precipitated at grain boundaries and interdendritic zones. These precipitates are the main strengthening mechanism in this type of alloys. Other minority phases were also reported and their presence could be linked to the cooling rate and the manufacturing process variables and environment. - Research Highlights: {yields}The solidification microstructure of an ASTM-F75 type alloy were studied. {yields}The alloys were poured under an industrial environment. {yields}Carbides and sigma phase identified by color metallography and scanning microscopy (SEM and EDS). {yields}Two carbide morphologies were detected 'blocky type' and 'pearlite type'. {yields}Minority phases were also detected.

  20. Development of an energy-use estimation methodology for the revised Navy Manual MO-303

    SciTech Connect (OSTI)

    Richman, E.E.; Keller, J.M.; Wood, A.G.; Dittmer, A.L.

    1995-01-01

    The U.S. Navy commissioned Pacific Northwest Laboratory (PNL) to revise and/or update the Navy Utilities Targets Manual, NAVFAC MO-303 (U.S. Navy 1972b). The purpose of the project was to produce a current, applicable, and easy-to-use version of the manual for use by energy and facility engineers and staff at all Navy Public Works Centers (PWCs), Public Works Departments (PWDs), Engineering Field Divisions (EFDs), and other related organizations. The revision of the MO-303 manual involved developing a methodology for estimating energy consumption in buildings and ships. This methodology can account for, and equitably allocate, energy consumption within Navy installations. The analyses used to develop this methodology included developing end-use intensities (EUIs) from a vast collection of Navy base metering and billing data. A statistical analysis of the metering data, weather data, and building energy-use characteristics was used to develop appropriate EUI values for use at all Navy bases. A complete Navy base energy reconciliation process was also created for use in allocating all known energy consumption. Initial attempts to use total Navy base consumption values did not produce usable results. A parallel effort using individual building consumption data provided an estimating method that incorporated weather effects. This method produced a set of building EUI values and weather adjustments for use in estimating building energy use. A method of reconciling total site energy consumption was developed based on a {open_quotes}zero-sum{close_quotes} principle. This method provides a way to account for all energy use and apportion part or all of it to buildings and other energy uses when actual consumption is not known. The entire text of the manual was also revised to present a more easily read understood and usable document.

  1. Word Pro - Untitled1

    Gasoline and Diesel Fuel Update (EIA)

    State-Level Energy Consumption Estimates and Estimated Consumption per Capita, 2010 Consumption Consumption per Capita 14 U.S. Energy Information Administration / Annual Energy Review 2011 TX CA FL LA IL OH PA NY GA IN MI NC VA NJ TN WA KY AL MO MN WI SC OK CO IA MD AZ MA MS KS AR OR NE UT CT WV NM NV AK WY ID ND ME MT SD NH HI DE RI DC VT 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 0 2 4 6 8 10

  2. Partial substitution of Mo{sup 6+} by S{sup 6+} in the fast oxide ion conductor La{sub 2}Mo{sub 2}O{sub 9}: Synthesis, structure and sulfur depletion

    SciTech Connect (OSTI)

    Mhadhbi, Noureddine; Corbel, Gwenaeel; Lacorre, Philippe; Bulou, Alain

    2012-06-15

    Powder-solid state reaction route using La{sub 2}(SO{sub 4}){sub 3} as sulfur source was used to prepare compositions of the solid solution La{sub 2}Mo{sub 2-y}S{sub y}O{sub 9}. Single phases were only obtained in the substitution range extending up to y=0.8 (40 mol% S) at the annealing temperature of 850 Degree-Sign C with regard to the limit of stability of the lanthanum sulphate reactant. Within the synthesis conditions, a stabilization of the high temperature {beta}-form is observed from and above y=0.1 (5 mol% S). Temperature-controlled X-ray diffraction and thermogravimetric analyses have shown that La{sub 2}Mo{sub 2-y}S{sub y}O{sub 9} raw powders undergo thermal decompositions in two steps. Heating above 900 Degree-Sign C, a sulfur depletion to the benefit of molybdenum in La{sub 2}Mo{sub 2-y}S{sub y}O{sub 9} raw powders leads to the formation of La{sub 2}SO{sub 6}. At higher temperature, the exsolved La{sub 2}SO{sub 6} phase then decomposes into La{sub 2}O{sub 3}, which in turn reacts with the sulfur-depleted La{sub 2}Mo{sub 2}O{sub 9} phase to form La{sub 2}MoO{sub 6}. The present study also reveals that depending on the substitution rate y, the sulfur depletion can be induced by ball-milling of raw powders. Along the La{sub 2}Mo{sub 2-y}S{sub y}O{sub 9} series, the isovalent substitution of molybdenum by sulfur tends to restrict in magnitude, or even to suppress above 400 Degree-Sign C, the distortive thermal expansion of the cubic {beta}-type structure, thus strongly decreasing the conductance at high temperature. - Graphical abstract: La{sub 2}O{sub 3}-MoO{sub 3}-'SO{sub 3}' ternary phase diagram showing the exsolution path at low temperature (white arrows) and the total decomposition path at high temperature (black arrows) of {beta}-La{sub 2}Mo{sub 2-y}S{sub y}O{sub 9} raw powders. Highlights: Black-Right-Pointing-Pointer Isovalent substitution of molybdenum by sulfur in La{sub 2}Mo{sub 2}O{sub 9} up to 40 mol%. Black-Right-Pointing-Pointer Stabilization of the {beta}-form for a sulfur content greater than or equal to 5 mol%. Black-Right-Pointing-Pointer Decomposition by sulfur exsolution induced by thermal treatment or ball-milling. Black-Right-Pointing-Pointer Reduction or even cancellation of the distortive thermal expansion above 400 Degree-Sign C. Black-Right-Pointing-Pointer Decrease of conductance at high T involved by the low thermal expansion above 400 Degree-Sign C.

  3. Searches for supersymmetry using the M$$_{T2}$$ variable in hadronic events produced in pp collisions at 8 TeV

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Khachatryan, V.

    2015-05-15

    Searches for supersymmetry (SUSY) are performed using a sample of hadronic events produced in 8 TeV pp collisions at the CERN LHC. The searches are based on the Mmore » $$_{T2}$$ variable, which is a measure of the transverse momentum imbalance in an event. The data were collected with the CMS detector and correspond to an integrated luminosity of 19.5 fb1. Two related searches are performed. The first is an inclusive search based on signal regions defined by the value of the M$$_{T2}$$ variable, the hadronic energy in the event, the jet multiplicity, and the number of jets identified as originating from bottom quarks. The second is a search for a mass peak corresponding to a Higgs boson decaying to a bottom quark-antiquark pair, where the Higgs boson is produced as a decay product of a SUSY particle. For both searches, the principal backgrounds are evaluated with data control samples. No significant excess over the expected number of background events is observed, and exclusion limits on various SUSY models are derived.« less

  4. Synthesis and mechanical properties of CrMoC{sub x}N{sub 1-x} coatings deposited by a hybrid coating system

    SciTech Connect (OSTI)

    Yun, Ji Hwan; Heo, Su Jeong; Kim, Kwang Ryul; Kim, Kwang Ho

    2008-01-15

    Quaternary CrMoC{sub x}N{sub 1-x} coatings were deposited on steel substrates (AISI D2) and Si wafers by a hybrid coating system combining an arc-ion plating technique and a dc reactive magnetron sputtering technique using Cr and Mo targets in an Ar/N{sub 2}/CH{sub 4} gaseous mixture. The carbon content of CrMoC{sub x}N{sub 1-x} coatings was linearly increased with increasing CH{sub 4}/(CH{sub 4}+N{sub 2}) gas flow rate ratio. The maximum hardness of 44 GPa was obtained from the CrMoC{sub x}N{sub 1-x} coatings containing a carbon content of x=0.33 with a residual stress of -4.4 GPa. The average friction coefficient of Cr-Mo-N coatings was 0.42, and it is decreased to 0.31 after applying CrMoC{sub x}N{sub 1-x} coatings. This result was caused by the formation of a carbon-rich transfer layer that acted as a solid lubricant to reduce contact between the coating surface and steel ball. The microstructure of the coatings was investigated by x-ray diffraction, scanning electron microscopy, and x-ray photoelectron spectroscopy. In this work, the microstructure and mechanical properties of the CrMoC{sub x}N{sub 1-x} coatings were systematically investigated with the instrumental analyses.

  5. Method for generating a crystalline {sup 99}MoO{sub 3} product and the isolation {sup 99m}Tc compositions therefrom

    DOE Patents [OSTI]

    Bennett, R.G.; Christian, J.D.; Kirkham, R.J.; Tranter, T.J.

    1998-09-01

    An improved method is described for producing {sup 99m}Tc compositions. {sup 100}Mo metal is irradiated with photons in a particle (electron) accelerator to produce {sup 99}Mo metal which is dissolved in a solvent. A solvated {sup 99}Mo product is then dried to generate a supply of {sup 99}MoO{sub 3} crystals. The crystals are thereafter heated at a temperature which will sublimate the crystals and form a gaseous mixture containing vaporized {sup 99m}TcO{sub 3} and vaporized {sup 99m}TcO{sub 2} but will not cause the production of vaporized {sup 99}MoO{sub 3}. The mixture is then combined with an oxidizing gas to generate a gaseous stream containing vaporized {sup 99m}Tc{sub 2}O{sub 7}. Next, the gaseous stream is cooled to a temperature sufficient to convert the vaporized {sup 99m}Tc{sub 2}O{sub 7} into a condensed {sup 99m}Tc-containing product. The product has high purity levels resulting from the use of reduced temperature conditions and ultrafine crystalline {sup 99}MoO{sub 3} starting materials with segregated {sup 99m}Tc compositions therein which avoid the production of vaporized {sup 99}MoO{sub 3} contaminants. 1 fig.

  6. Method for generating a crystalline .sup.99 MoO.sub.3 product and the isolation .sup.99m Tc compositions therefrom

    DOE Patents [OSTI]

    Bennett, Ralph G. (Idaho Falls, ID); Christian, Jerry D. (Idaho Falls, ID); Kirkham, Robert J. (Blackfoot, ID); Tranter, Troy J. (Idaho Falls, ID)

    1998-01-01

    An improved method for producing .sup.99m Tc compositions. .sup.100 Mo metal is irradiated with photons in a particle (electron) accelerator to produce .sup.99 Mo metal which is dissolved in a solvent. A solvated .sup.99 Mo product is then dried to generate a supply of .sup.99 MoO.sub.3 crystals. The crystals are thereafter heated at a temperature which will sublimate the crystals and form a gaseous mixture containing vaporized .sup.99m TcO.sub.3 and vaporized .sup.99m TcO.sub.2 but will not cause the production of vaporized .sup.99 MoO.sub.3. The mixture is then combined with an oxidizing gas to generate a gaseous stream containing vaporized .sup.99m Tc.sub.2 O.sub.7. Next, the gaseous stream is cooled to a temperature sufficient to convert the vaporized .sup.99m Tc.sub.2 O.sub.7 into a condensed .sup.99m Tc-containing product. The product has high purity levels resulting from the use of reduced temperature conditions and ultrafine crystalline .sup.99 MoO.sub.3 starting materials with segregated .sup.99m Tc compositions therein which avoid the production of vaporized .sup.99 MoO.sub.3 contaminants.

  7. Facile deposition of Ag{sub 3}PO{sub 4} on graphene-like MoS{sub 2} nanosheets for highly efficient photocatalysis

    SciTech Connect (OSTI)

    Wang, Peifu; Shi, Penghui; Hong, Yuanchen; Zhou, Xuejun; Yao, Weifeng

    2015-02-15

    Graphical abstract: The photocatalytic performance of Ag{sub 3}PO{sub 4} was highly improved by the in situ deposition of Ag{sub 3}PO{sub 4} particles on graphene-like MoS{sub 2} nanosheets. - Highlights: A novel composite photocatalyst was synthesized by depositing Ag{sub 3}PO{sub 4} on the graphene-like MoS{sub 2} nanosheets. Ag{sub 3}PO{sub 4}/MoS{sub 2} photocatalyst exhibited a high photocatalytic activity for RhB degradation. Graphene-like MoS{sub 2} nanosheets. MoS{sub 2} nanosheets play an important role in photocatalytic activity by serving as an effective acceptor of the photogenerated carriers. - Abstract: A facile method for the in situ deposition of Ag{sub 3}PO{sub 4} on graphene-like MoS{sub 2} nanosheets was developed to improve the photocatalytic performance of Ag{sub 3}PO{sub 4} catalysts. The heterostructure of Ag{sub 3}PO{sub 4}/MoS{sub 2} composites was characterized by using X-ray diffraction spectra (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and X-ray photoelectron spectroscopy (XPS). The prepared Ag{sub 3}PO{sub 4}/MoS{sub 2} photocatalyst exhibited a much higher photocatalytic activity than that of Ag{sub 3}PO{sub 4} for the degradation of Rhodamine B (RhB) under visible light irradiation (>400 nm). The improved photocatalytic activity of Ag{sub 3}PO{sub 4}/MoS{sub 2} is attributed to the efficient separation of photogenerated electronhole pairs in the composite. This result provides a new perspective on the design of high-performance photocatalysts which is promising for energy applications.

  8. Results of U-xMo (x=7, 10, 12 wt.%) Alloy versus Al-6061 Cladding Diffusion Couple Experiments Performed at 500, 550 and 600 Degrees C

    SciTech Connect (OSTI)

    Emmanuel Perez; Dennis D. Keiser, Jr.; Yongho Sohn

    2013-04-01

    The Reduced Enrichment for Research and Test Reactors (RERTR) program has been developing low enrichment fuel systems encased in Al 6061 for use in research and test reactors. UMo alloys in contact with Al and Al alloys can undergo diffusional interactions that can result in the development of interdiffusion zones with complex fine-grained microstructures composed of multiple phases. A monolithic fuel currently being developed by the RERTR program has local regions where the UMo fuel plate is in contact with the Al 6061 cladding and, as a result, the program finds information about interdiffusion zone development at high temperatures of interest. In this study, the microstructural development of diffusion couples consisting of U-7wt.%Mo, U-10wt.%Mo, and U-12wt.%Mo vs. Al 6061 (or 6061 aluminum) cladding, annealed at 500, 550, 600 degrees C for 1, 5, 20, 24, or 132 hours, was analyzed by backscatter electron microscopy and x-ray energy dispersive spectroscopy on a scanning electron microscope. Concentration profiles were determined by standardized wavelength dispersive spectroscopy and standardless x-ray energy dispersive spectroscopy. The results of this work shows that the presence of surface layers at the UMo/Al 6061 interface can dramatically impact the overall interdiffusion behavior in terms of rate of interaction and uniformity of the developed interdiffusion zones. It further reveals that relatively uniform interaction layers with higher Si concentrations can develop in UMo/Al 6061 couples annealed at shorter times and that longer times at temperature result in the development of more non-uniform interaction layers with more areas that are enriched in Al. At longer annealing times and relatively high temperatures, UMo/Al 6061 couples can exhibit more interaction compared to UMo/pure Al couples. The minor alloying constituents in Al 6061 cladding can result in the development of many complex phases in the interaction layer of UMo/Al6061 cladding couples, and some phases in the interdiffusion zones of UMo/Al6061 cladding couples are likely similar to those observed for UMo/pure Al couples.

  9. Cobalt-doped Bi{sub 26}Mo{sub 10}O{sub 69}: Crystal structure and conductivity

    SciTech Connect (OSTI)

    Mikhailovskaya, Z.A.; Buyanova, E.S.; Petrova, S.A.; Morozova, M.V.; Zhukovskiy, V.M.; Zakharov, R.G.; Tarakina, N.V.; Berger, I.F.

    2013-08-15

    A series of cobalt-doped bismuth molybdates were synthesized and investigated using X-ray powder diffraction, transmission electron microscopy and impedance spectroscopy. The ranges of solid solution were determined. Two new compounds, Bi{sub 1?x}Co{sub x}[Bi{sub 12}O{sub 14}]Mo{sub 5}O{sub 34.5?} (x=0.2) and Bi[Bi{sub 12}O{sub 14}]Mo{sub 5?y}Co{sub y}O{sub 34.5?} (y=0.2), which crystallise in monoclinic unit cells have been examined in detail by diffraction methods. Impedance spectroscopy measurements show that the studied materials are good ionic conductors with conductivity values about 510{sup ?3} Scm{sup ?1} at 973 K and 1.710{sup ?4} Scm{sup ?1} at 623 K, which are similar to conductivity values of yttrium substituted zirconia and (YSZ) gadolinium doped ceria (CGO). - Graphical abstract: Measured and calculated diffraction spectra for Bi{sub 12.8}Co{sub 0.2}Mo{sub 5}O{sub 34?} and projection of the Bi{sub 12.8}Co{sub 0.2}Mo{sub 5}O{sub 34?} crystal structure onto the ac plane. Highlights: The limit of the Bi{sub 1?x}Co{sub x}[Bi{sub 12}O{sub 14}]Mo{sub 5}O{sub 34.5?} homogeneity range is equal to x=0.2. The limit of the Bi[Bi{sub 12}O{sub 14}]Mo{sub 5?y}Co{sub y}O{sub 34.5?} homogeneity range is equal to y=0.2. Solid solutions have monoclinic symmetry. No phase transition is observed. The conductivity at 700 for y=0.2 solid solutions is equal to ?lg ?, Scm{sup ?1}=2.23. The conductivity at 350 for y=0.2 solid solutions is equal to ?lg ?, Scm{sup ?1}=3.74.

  10. Microstructural evolution during solution treatment of Co-Cr-Mo-C biocompatible alloys

    SciTech Connect (OSTI)

    Giacchi, J.V.; Fornaro, O.; Palacio, H.

    2012-06-15

    Three different Co-Cr-Mo-C alloys conforming to ASTM F75 standard were poured in an industrial environment and subjected to a conventional solution treatment at 1225 Degree-Sign C for several time intervals. The microstructural changes and transformations were studied in each case in order to evaluate the way in which treatment time influences the secondary phase fraction and clarify the microstructural changes that could occur. To assess how treatment time affects microstructure, optical microscopy and image analyzer software, scanning electron microscopy and energy dispersion spectrometry analysis were employed. The main phases detected in the as-cast state were: {sigma}-phase, M{sub 6}C, and M{sub 23}C{sub 6} carbides. The latter presented two different morphologies, blocky type and lamellar type. Despite being considered the most detrimental feature to mechanical properties, {sigma}-phase and lamellar carbides dissolution took place in the early stages of solution treatment. M{sub 23}C{sub 6} carbides featured two different behaviors. In the alloy obtained by melting an appropriate quantity of alloyed commercial materials, a decrease in size, spheroidization and transformation into M{sub 6}C carbides were simultaneously observed. In the commercial ASTM F75 alloy, in turn, despite being the same phase, only a marked decrease in precipitates size was noticed. These different behaviors could be ascribed to the initial presence of other phases in the alloy obtained from alloyed materials, such as {sigma}-phase and 'pearlitic' carbides, or to the initial precipitate size which was much larger in the first than in the commercial ASTM F75 alloy studied. M{sub 6}C carbides dissolved directly in the matrix as they could not be detected in samples solution-treated for 15 min. - Highlights: Black-Right-Pointing-Pointer Three different Co-Cr-Mo alloys were poured under an industrial environment. Black-Right-Pointing-Pointer Transformation of existing phases followed during conventional solution treatment. Black-Right-Pointing-Pointer In as-cast/treated samples, phases were identified by color metallography, SEM and EDS. Black-Right-Pointing-Pointer M{sub 23}C{sub 6} {yields} M{sub 6}C transformation was corroborated by SEM and EDS analysis. Black-Right-Pointing-Pointer Carbide spheroidization was also detected prior a noticeably carbide size decreasing.

  11. Development of an Immobilisation Technology for Radioactive Waste Solution from Mo-99 Production

    SciTech Connect (OSTI)

    Sizgek, G.D.; Sizgek, E.

    2006-07-01

    Australian Nuclear Science and Technology Organisation (ANSTO) developed a method to immobilize the Intermediate Level Liquid Waste (ILLW) arising from its Mo-99 production process. The immobilisation process involves impregnation of waste solution into ceramic precursor powders, drying, calcining and consolidation (Hot Isostatic Pressing, HIP) to produce final ceramic waste form. Ceramic precursor powder is produced by spray drying of a sol-gel based colloidal dispersion. These free-flowing, microspherical, 20-80 microns, precursors have porosity of 40-50%. An in-house custom designed and manufactured microwave-heated and mechanically fluidized mixer-drier was used for impregnation of the precursor powder with the simulated waste (Depleted Uranyl Nitrate Hexahydrate, DUNH, and inactive Cs, Sr nitrates as fission products) and drying. During impregnation an evaporation rate of 1 l/h water per kW microwave energy in steady state was achieved by matching the feed rate of DUNH to produce equivalent of 35% UO{sub 2} loading. It was demonstrated that the tuned microwave energy can be delivered to the mixer-drier during the entire impregnation process within very low reflection values. The samples of the waste loaded free-flowing powder were subsequently calcined at 750 deg. C under reducing atmosphere for thermal denitration and mineral phase nucleation. Calcined powders were filled into cans. After evacuation and sealing, the cans were isostatically pressed at 1260 deg. C. The consolidated ceramic waste form produced from the DUNH run has been assessed by durability and material characterization tests. Successful confirmation of each processing step at pilot and/or plant scale, has led to the design and construction of the overall process at full scale (equivalent of processing 8 kg U per batch) in a simulated hot-cell mock-up plant. The constructed plant mainly consists of a Microwave-heated Mechanical Fluidized Bed (MWMFB) mixer-drier a fluidized bed calciner, an off gas unit, material transfer/holding and can filling units. Performance of the overall process by integrating each of the processing steps and material transfer operations are currently being tested with inactive simulants from the point of remote operated plant design perspective. Definitive design of a hot-cell production system has been initiated in parallel to the mock-up plant tests. This paper describes the results of both full-scale DUNH impregnation run and inactive mock-up plant tests in developing unique Mo-99 waste immobilisation technology. (authors)

  12. SEM in situ MiniCantilever Beam Bending of U-10Mo/Zr/Al Fuel Elements

    SciTech Connect (OSTI)

    Mook, William; Baldwin, Jon K.; Martinez, Ricardo M.; Mara, Nathan A.

    2014-06-16

    In this work, the fracture behavior of Al/Zr and Zr/dU-10Mo interfaces was measured via the minicantilever bend technique. The energy dissipation rates were found to be approximately 3.7-5 mj/mm2 and 5.9 mj/mm2 for each interface, respectively. It was found that in order to test the Zr/U-10Mo interface, location of the hinge of the cantilever was a key parameter. While this test could be adapted to hot cell use through careful alignment fixturing and measurement of crack lengths with an optical microscope (as opposed to SEM, which was used here out of convenience), machining of the cantilevers via MiniMill in such a way as to locate the interfaces at the cantilever hinge, as well as proper placement of a femtosecond laser notch will continue to be key challenges in a hot cell environment.

  13. Mass Measurements of Very Neutron-Deficient Mo and Tc Isotopes and Their Impact on rp Process Nucleosynthesis

    SciTech Connect (OSTI)

    Haettner, E.; Plass, W. R.; Scheidenberger, C.; Ackermann, D.; Block, M.; Eliseev, S.; Herfurth, F.; Hessberger, F. P.; Hofmann, S.; Kluge, H.-J.; Audi, G.; Blaum, K.; Ketter, J.; Fleckenstein, T.; Ketelaer, J.; Marx, G.; Schweikhard, L.; Mazzocco, M.; Novikov, Yu. N.; Vorobjev, G.

    2011-03-25

    The masses of ten proton-rich nuclides, including the N=Z+1 nuclides {sup 85}Mo and {sup 87}Tc, were measured with the Penning trap mass spectrometer SHIPTRAP. Compared to the Atomic Mass Evaluation 2003 a systematic shift of the mass surface by up to 1.6 MeV is observed causing significant abundance changes of the ashes of astrophysical x-ray bursts. Surprisingly low {alpha} separation energies for neutron-deficient Mo and Tc are found, making the formation of a ZrNb cycle in the rp process possible. Such a cycle would impose an upper temperature limit for the synthesis of elements beyond Nb in the rp process.

  14. Calculation of Design Parameters for an Equilibrium LEU Core in the NBSR using a U7Mo Dispersion Fuel

    SciTech Connect (OSTI)

    Hanson A. L.; Diamond D.

    2014-06-30

    A plan is being developed for the conversion of the NIST research reactor (NBSR) from high-enriched uranium (HEU) fuel to low-enriched uranium (LEU) fuel. The LEU fuel may be a monolithic foil (LEUm) of U10Mo (10% molybdenum by weight in an alloy with uranium) or a dispersion of U7Mo in aluminum (LEUd). A previous report provided neutronic calculations for the LEUm fuel and this report presents the neutronics parameters for the LEUd fuel. The neutronics parameters for the LEUd fuel are compared to those previously obtained for the present HEU fuel and the proposed LEUm fuel. The results show no significant differences between the LEUm and the LEUd other than the LEUd fuel requires slightly less uranium than the LEUm fuel due to less molybdenum being present. The calculations include kinetics parameters, reactivity coefficients, reactivity worths of control elements and abnormal configurations, and power distributions under normal operation and with misloaded fuel elements.

  15. The Influence of Casting Conditions on the Microstructure of As-Cast U-10Mo Alloys: Characterization of the Casting Process Baseline

    SciTech Connect (OSTI)

    Nyberg, Eric A.; Joshi, Vineet V.; Lavender, Curt A.; Paxton, Dean M.; Burkes, Douglas

    2013-12-13

    Sections of eight plate castings of uranium alloyed with 10 wt% molybdenum (U-10Mo) were sent from Y-12 to the Pacific Northwest National Laboratory (PNNL) for microstructural characterization. This report summarizes the results from this study.

  16. Origin State>> CA CA ID ID ID IL KY MD MO NM NM NY NY OH SC

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    MO NM NM NY NY OH SC TN TN TN, WA, CA TN TN TN TN Total Shipments by Route Lawrence Livermore National Laboratory General Atomics Batelle Energy Alliance Idaho National Laboratory Advanced Mixed Waste Treatment Project Argonne National Laboratory Paducah Gaseous Diffusion Plant Aberdeen Proving Grounds National Security Technologies Sandia National Laboratory Los Alamos National Laboratory Brookhaven National Laboratory CH2M Hill B&W West Valley, LLC Portsmouth Gaseous Diffusion Plant

  17. Measurement of fission gas release from irradiated UMo monolithic fuel samples

    SciTech Connect (OSTI)

    Burkes, Douglas E.; Casella, Amanda J.; Casella, Andrew M.; Luscher, Walter G.; Rice, Francine J.; Pool, Karl N.

    2015-06-01

    The uraniummolybdenum (U-Mo) alloy in a monolithic form has been proposed as one fuel design capable of converting some of the worlds highest power research reactors from the use of high enriched uranium (HEU) to low enriched uranium (LEU). One aspect of the fuel development and qualification process is to demonstrate appropriate understanding of the extent of fission product release from the fuel under anticipated service environments. An apparatus capable of heating post-irradiated small-scale samples cut from larger fuel segments according to specified thermal profiles under a controlled atmosphere has been installed into a hot cell. Results show that optimized experimental parameters to investigate fission product release from small samples have been established. Initial measurements conducted on aluminum alloy clad uraniummolybdenum monolithic fuel samples reveal three clear fission gas release events over the temperature range of 30-1000 C. The mechanisms responsible for these events are discussed, and the results have been compared with available information in the literature.

  18. Modeling the Influence of Interaction Layer Formation on Thermal Conductivity of UMo Dispersion Fuel

    SciTech Connect (OSTI)

    Burkes, Douglas; Casella, Andrew M.; Huber, Tanja K.

    2015-01-01

    The Global Threat Reduction Initiative Program continues to develop existing and new plate- and rod-type research and test reactor fuels with maximum attainable uranium loadings capable of potentially converting a number of the worlds remaining high-enriched uranium fueled reactors to low-enriched uranium fuel. Currently, the program is focused on assisting with the development and qualification of an even higher density fuel type consisting of a uranium-molybdenum (U-Mo) alloy dispersed in an aluminum matrix. Thermal conductivity is an important consideration in determining the operational temperature of the fuel plate and can be influenced by interaction layer formation between the fuel and matrix, porosity that forms during fabrication of the fuel plates, and upon the concentration of the dispersed phase within the matrix. This paper develops and validates a simple model to study the influence of interaction layer formation and conductivity, fuel particle size, and volume fraction of fuel dispersed in the matrix on the effective conductivity of the composite. The model shows excellent agreement with results previously presented in the literature. In particular, the thermal conductivity of the interaction layer does not appear to be important in determining the overall conductivity of the composite, while formation of the interaction layer and subsequent consumption of the matrix reveals a rather significant effect. The effective thermal conductivity of the composite can be influenced by the fuel particle distribution by minimizing interaction layer formation and preserving the higher thermal conductivity matrix.

  19. Measurement of Fission Gas Release from Irradiated U-Mo Monolithic Fuel Samples

    SciTech Connect (OSTI)

    Burkes, Douglas; Casella, Amanda J.; Casella, Andrew M.; Luscher, Walter G.; Rice, Francine; Pool, Karl N.

    2015-06-01

    The uranium-molybdenum (U-Mo) alloy in a monolithic form has been proposed as one fuel design capable of converting some of the worlds highest power research reactors from the use of high enriched uranium (HEU) to low enriched uranium (LEU). One aspect of the fuel development and qualification process is to demonstrate appropriate understanding of the extent of fission product release from the fuel under anticipated service environments. An apparatus capable of annealing post-irradiated small-scale samples cut from larger fuel segments according to specified thermal profiles under a controlled atmosphere has been installed into a hot cell. Results show that optimized experimental parameters to investigate fission product release from small samples have been established. Initial measurements conducted on aluminum alloy clad uranium-molybdenum monolithic fuel samples reveal three clear fission gas release events over the temperature range of 30-1050 C. The mechanisms responsible for these events are discussed, and the results have been compared with available information in literature.

  20. Wettability of brazing alloys on molybdenum and TZM (Mo-Ti-Zr alloy)

    SciTech Connect (OSTI)

    McDonald, M.M.; Keller, D.L.; Heiple, C.R.; Hofmann, W.E.

    1988-01-01

    Vacuum brazing studies have been performed on molybdenum and TZM (0.5Ti-0.08Zr-Mo). Wettability tests have been conducted for nineteen braze metal filler alloys on molybdenum and thirty-two braze metal filler alloys on TZM over a wide range of temperatures. A wetting index, which is a function of contact angle and braze alloy contact area, was determined for each filler alloy at each brazing temperature. The nature and extent of interaction between the brazing alloys and the base metals was analyzed by conventional metallography, scanning-electron microscopy, and electron microprobe analysis. A comparison is made between the behavior of filler alloys on molybdenum and TZM -- filler alloys consistently exhibited less wettability on TZM than on molybdenum. The lower wettability of TZM is believed to be due to a small amount of titanium in the surface oxide on TZM. Cracking was observed in the base metal under some of the high temperature braze deposits. The cracking is shown to arise from liquid metal embrittlement from nickel in the high temperature braze alloys. 7 refs., 11 figs., 2 tabs.

  1. Search for neutrinoless double-beta decay of Mo 100 with the NEMO-3 detector

    SciTech Connect (OSTI)

    John D. Baker; A. J. Caffrey

    2014-06-01

    We report the results of a search for the neutrinoless double- decay (0? ) of Mo 100 , using the NEMO-3 detector to reconstruct the full topology of the final state events. With an exposure of 34.7??kgy , no evidence for the 0? signal has been found, yielding a limit for the light Majorana neutrino mass mechanism of T 1/2 (0?)>1.110 24 years (90% C.L.) once both statistical and systematic uncertainties are taken into account. Depending on the nuclear matrix elements this corresponds to an upper limit on the Majorana effective neutrino mass of ?m ? ?<0.30.9??eV (90% C.L.). Constraints on other lepton number violating mechanisms of 0? decays are also given. Searching for high-energy double electron events in all suitable sources of the detector, no event in the energy region [3.210] MeV is observed for an exposure of 47??kgy .

  2. Coupled spin and valley physics in monolayer MoS2 and group-VI dichalcogenides

    SciTech Connect (OSTI)

    Xiao, Di; Liu, G. B.; Feng, wanxiang; Xu, Xiaodong; Yao, Wang

    2012-01-01

    We show that inversion symmetry breaking together with spin-orbit coupling leads to coupled spin and valley physics in monolayer MoS2 and group-VI dichalcogenides, making possible controls of spin and valley in these 2D materials. The spin-valley coupling at the valence band edges suppresses spin and valley relaxation, as flip of each index alone is forbidden by the 0.1 eV valley contrasting spin splitting. Valley Hall and spin Hall effects coexist in both electron-doped and hole-doped systems. Optical interband transitions have frequency-dependent polarization selection rules which allow selective photoexcitation of carriers with various combination of valley and spin indices. Photo-induced spin Hall and valley Hall effects can generate long lived spin and valley accumulations on sample boundaries. The physics discussed here provides a route towards the integration of valleytronics and spintronics in multi-valley materials with strong spin-orbit coupling and inversion symmetry breaking.

  3. Optimal electron irradiation as a tool for functionalization of MoS{sub 2}: Theoretical and experimental investigation

    SciTech Connect (OSTI)

    Karmakar, Debjani Padma, N.; Ghosh, M.; Kaur, M.; Chandrasekhar Rao, T. V.; Halder, Rumu; Abraham, Geogy; Vaibhav, K.; Bhattacharya, D.

    2015-04-07

    We demonstrate the utility of electron irradiation as a tool to enhance device functionality of graphene-analogous MoS{sub 2}. With the help of first-principles based calculations, vacancy-induced changes of various electronic properties are shown to be a combined result of crystal-field modification and spin-orbital coupling. A comparative theoretical study of various possible vacancy configurations both in bulk and monolayer MoS{sub 2} and related changes in their respective band-structures help us to explain plausible irradiation induced effects. Experimentally, various structural forms of MoS{sub 2} in bulk, few layered flakes, and nanocrystals are observed to exhibit important modification of their magnetic, transport, and vibrational properties, following low doses of electron irradiation. While irradiated single crystals and nanocrystals show an enhanced magnetization, transport properties of few-layered devices show a significant increase in their conductivity, which can be very useful for fabrication of electronic devices. Our theoretical calculations reveal that this increase in n-type conductivity and magnetization can be correlated with the presence of sulfur and molybdenum vacancies.

  4. Reconfigurable p-n junction diodes and the photovoltaic effect in exfoliated MoS{sub 2} films

    SciTech Connect (OSTI)

    Sutar, Surajit; Agnihotri, Pratik; Comfort, Everett; Ung Lee, Ji; Taniguchi, T.; Watanabe, K.

    2014-03-24

    Realizing basic semiconductor devices such as p-n junctions are necessary for developing thin-film and optoelectronic technologies in emerging planar materials such as MoS{sub 2}. In this work, electrostatic doping by buried gates is used to study the electronic and optoelectronic properties of p-n junctions in exfoliated MoS{sub 2} flakes. Creating a controllable doping gradient across the device leads to the observation of the photovoltaic effect in monolayer and bilayer MoS{sub 2} flakes. For thicker flakes, strong ambipolar conduction enables realization of fully reconfigurable p-n junction diodes with rectifying current-voltage characteristics, and diode ideality factors as low as 1.6. The spectral response of the photovoltaic effect shows signatures of the predicted band gap transitions. For the first excitonic transition, a shift of >4{sub kB}T is observed between monolayer and bulk devices, indicating a thickness-dependence of the excitonic coulomb interaction.

  5. A low-temperature extraction-solvothermal route to the fabrication of micro-sized MoS{sub 2} spheres modified by Cyanex 301

    SciTech Connect (OSTI)

    Shi Huaqiang; Fu Xun . E-mail: fuxun4483@163.com; Zhou Xiaodong; Wang Debao; Hu Zhengshui

    2006-06-15

    Mono-dispersed molybdenum disulfide micro-spheres with the diameter of 1-3 {mu}m have been successfully synthesized via extraction-solvothermal method at 150 deg. C. The extractant Cyanex 301 (di-(2,4,4-trimethylpentyl) dithiophosphinic acid) acted as phase transferring agent, reductant, sulfur source and morphology-controlling agent in the whole procedure. The obtained MoS{sub 2} micro-spheres were characterized by XRD, EDS, SEM, TEM, HRTEM, IR, UV-Vis and TG, respectively. The influences of reaction conditions were discussed while a mechanism was proposed to explain the formation of the micro-spheres. Moreover, the tribological properties of liquid paraffin (LP) containing Cyanex 301-modified MoS{sub 2} micro-spheres were also evaluated on a four-ball machine, showing that the obtained MoS{sub 2} product was an excellent oil additive in LP and such lubricant had good anti-wear and friction-reducing properties. - Graphical abstract: Mono-dispersed MoS{sub 2} micro-spheres with the diameter of 1-3 {mu}m were synthesized in gasoline via extraction-solvothermal method at 150 deg. C. The MoS{sub 2} product could be well dispersed into organic solvents again and the tribological properties of liquid paraffin (LP) containing MoS{sub 2} micro-spheres were improved.

  6. Synthesis, characterization and evaluation of the photocatalytic performance of Ag-CdMoO{sub 4} solar light driven plasmonic photocatalyst

    SciTech Connect (OSTI)

    Adhikari, Rajesh; Malla, Shova; Gyawali, Gobinda; Sekino, Tohru; Lee, Soo Wohn

    2013-09-01

    Graphical abstract: - Highlights: Ag-CdMoO{sub 4} solar light driven photocatalyst was successfully synthesized. Photocatalyst exhibited strong absorption in the visible region. Photocatalytic activity was significantly enhanced. Enhanced activity was caused by the SPR effect induced by Ag nanoparticles. - Abstract: Ag-CdMoO{sub 4} plasmonic photocatalyst was synthesized in ethanol/water mixture by photo assisted co-precipitation method at room temperature. As synthesized powders were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), UVVis diffuse reflectance spectroscopy (DRS), X-ray photoelectron spectroscopy (XPS) and BrunauerEmmettTeller (BET) surface area analyzer. Photocatalytic activity was evaluated by performing the degradation experiment over methylene blue (MB) and indigo carmine (IC) as model dyes under simulated solar light irradiation. The results revealed that the Ag-CdMoO{sub 4} showed the higher photocatalytic performance as compared to CdMoO{sub 4} nanoparticles. Dispersion of Ag nanoparticles over the surface of CdMoO{sub 4} nanoparticles causes the surface plasmon resonance (SPR) and enhances the broad absorption in the entire visible region of the solar spectrum. Hence, dispersion of Ag nanoparticles over CdMoO{sub 4} nanoparticles could be the better alternative to enhance the absorption of visible light by scheelite crystal family for effective photocatalysis.

  7. Mo{sub 6}Se{sub 8}-cluster-based superconducting compounds Cs{sub 2}Mo{sub 12}Se{sub 14} and Rb{sub 4}Mo{sub 18}Se{sub 20}: Evidence for a strongly correlated and anisotropic electron system

    SciTech Connect (OSTI)

    Brusetti, R.; Laborde, O.; Sulpice, A.; Calemczuk, R.; Potel, M.; Gougeon, P.

    1995-08-01

    We studied the normal and superconducting states of the title compounds by measuring the conductivity and magnetization of single crystals and powder samples. From the upper and lower critical fields we deduced the characteristic lengths and thermodynamical fields. These results are borne out by our specific-heat measurements. We recognize in these compounds many features of the Chevrel-phase superconductors, including very small coherence lengths and strong-coupling-like effects. However, we show that the electron system is much more anisotropic and still less delocalized in these materials where the Mo{sub 6}Se{sub 8} clusters have condensed in Mo{sub 6{ital n}}Se{sub 6{ital n}+2} finite chains. This condensation is accompanied by an enhancement of the magnetic response whereas the lengthening of the chains leads to a counteracting reduction of the density of carriers. This indicates that superconductivity is built upon highly correlated molecular states. Reviewing the available data on the other Chevrel-cluster-based superconductors confirms this picture and suggests that the small coherence lengths reflect the local character of the electron pairing. This comparison also shows that forming finite chains of Mo{sub 6}Se{sub 8} clusters makes the electron correlations more repulsive and pushes the electron system near the borderline between superconductivity and magnetism. In this respect these compounds could provide valuable complementary information on issues which are at the center of the research upon high-{ital Y}{sub {ital c}} superconductivity.

  8. Laser welding and post weld treatment of modified 9Cr-1MoVNb steel.

    SciTech Connect (OSTI)

    Xu, Z.

    2012-04-03

    Laser welding and post weld laser treatment of modified 9Cr-1MoVNb steels (Grade P91) were performed in this preliminary study to investigate the feasibility of using laser welding process as a potential alternative to arc welding methods for solving the Type IV cracking problem in P91 steel welds. The mechanical and metallurgical testing of the pulsed Nd:YAG laser-welded samples shows the following conclusions: (1) both bead-on-plate and circumferential butt welds made by a pulsed Nd:YAG laser show good welds that are free of microcracks and porosity. The narrow heat affected zone has a homogeneous grain structure without conventional soft hardness zone where the Type IV cracking occurs in conventional arc welds. (2) The laser weld tests also show that the same laser welder has the potential to be used as a multi-function tool for weld surface remelting, glazing or post weld tempering to reduce the weld surface defects and to increase the cracking resistance and toughness of the welds. (3) The Vicker hardness of laser welds in the weld and heat affected zone was 420-500 HV with peak hardness in the HAZ compared to 240 HV of base metal. Post weld laser treatment was able to slightly reduce the peak hardness and smooth the hardness profile, but failed to bring the hardness down to below 300 HV due to insufficient time at temperature and too fast cooling rate after the time. Though optimal hardness of weld made by laser is to be determined for best weld strength, methods to achieve the post weld laser treatment temperature, time at the temperature and slow cooling rate need to be developed. (4) Mechanical testing of the laser weld and post weld laser treated samples need to be performed to evaluate the effects of laser post treatments such as surface remelting, glazing, re-hardening, or tempering on the strength of the welds.

  9. Nano-Scale Fission Product Phases in an Irradiated U-7Mo Alloy Nuclear Fuel

    SciTech Connect (OSTI)

    Dennis Keiser, Jr.; Brandon Miller; James Madden; Jan-Fong Jue; Jian Gan

    2014-09-01

    Irradiated nuclear fuel is a very difficult material to characterize. Due to the large radiation fields associated with these materials, they are hard to handle and typically have to be contained in large hot cells. Even the equipment used for performing characterization is housed in hot cells or shielded glove boxes. The result is not only a limitation in the techniques that can be employed for characterization, but also a limitation in the size of features that can be resolved The most standard characterization techniques include light optical metallography (WM), scanning electron microscopy (SEM), and electron probe microanalysis (EPMA). These techniques are applied to samples that are typically prepared using grinding and polishing approaches that will always generate some mechanical damage on the sample surface. As a result, when performing SEM analysis, for example, the analysis is limited by the quality of the sample surface that can be prepared. However, a new approach for characterizing irradiated nuclear fuel has recently been developed at the Idaho National Laboratory (INL) in Idaho Falls, Idaho. It allows for a dramatic improvement in the quality of characterization that can be performed when using an instrument like an SEM. This new approach uses a dual-beam scanning microscope, where one of the beams isa focused ion beam (FIB), which can be used to generate specimens of irradiated fuel (-10m x 10m) for microstructural characterization, and the other beam is the electron beam of an SEM. One significant benefit of this approach is that the specimen surface being characterized has received much less damage (and smearing) than is caused by the more traditional approaches, which enables the imaging of nanometer sized microstructural features in the SEM. The process details are for an irradiated low-enriched uranium (LEU) U-Mo alloy fuel Another type of irradiated fuel that has been characterized using this technique is a mixed oxide fuel.

  10. Application of U10Mo Fuel for Space Fission Power Applications - White Paper

    SciTech Connect (OSTI)

    James Werner

    2014-07-01

    A novel reactor design has been proposed for space applications to provide hundreds of watts to one or two kilowatts of electrical power. The reactor concept proposed uses the alloy U10Mo (uranium with 10 weight percent molybdenum) as the fuel. This fuel was selected for its high uranium density, high thermal conductivity, and excellent neutronic characteristics for this application. The core is surrounded by a BeO reflector. Heat is carried from the reactor by liquid metal heat pipes. A shadow shield of LiH tungsten is also utilized to reduce the neutron and gamma radiation dose to the rest of the spacecraft. This design represents a best effort at minimizing the complexity of the fission system and reducing the mass of the system. The compact nature of the block UMo core and BeO radial reflector allows the reactor diameter to be as small as practical while still meeting the neutronic and thermal power demands. This directly results in a reduced shield mass since the reactor diameter dictates the footprint of the radiation shield. The use of heat pipes offers a straightforward primary heat transport approach using proven liquid-metal heat pipe technology. Further, the elimination of a liquid core coolant system heat transport components, both at the reactor side and radiator side, contributes to reducing the total part-count and lowering system mass. The proposed reactor is using a fuel that is being developed by DOE, but there are significant differences in the fuels enrichment, operating conditions and the physical shape of the fuel itself. This paper attempts to highlight some of the basic consideration and needs that would be expected to be met in developing this fuel and qualifying it for use.

  11. Technical assumption for Mo-99 production in the MARIA reactor. Feasibility study

    SciTech Connect (OSTI)

    Jaroszewicz, J.; Pytel, K.; Dabkowski, L.; Krzysztoszek, G. [Institute of Atomic Energy, 05-400 Otwock-Swierk (Poland)

    2008-07-15

    The main objective of U-235 irradiation is to obtain the Tc-99m isotope which is widely used in the domain of medical diagnostics. The decisive factor determining its availability, despite its short life time, is a reaction of radioactive decay of Mo-99 into Tc- 99m. One of the possible sources of molybdenum can be achieved in course of the U-235 fission reaction. The paper presents activities and the calculations results obtained upon the feasibility study on irradiation of U-235 targets for production of molybdenum in the MARIA reactor. The activities including technical assumption were focused on performing calculation for modelling of the target and irradiation device as well as adequate equipment and tools for processing in reactor. It has been assumed that the basic component of fuel charge is an aluminium cladded plate with dimensions of 40x230x1.45 containing 4.7 g U-235. The presumed mode of the heat removal generated in the fuel charge of the reactor primary cooling circuit influences the construction of installation to be used for irradiation and the technological instrumentation. The outer channel construction for irradiation has to be identical as the standard fuel channel construction of the MARIA reactor. It enables to use the existing slab and reactor mounting sockets for the fastening of the molybdenum channel as well as the cooling water delivery system. The measurement of water temperature cooling a fuel charge and control of water flow rate in the channel can also be carried out be means of the standard instrumentation of the reactor. (author)

  12. Removal of Radioactive Nuclides from Mo-99 Acidic Liquid Waste - 13027

    SciTech Connect (OSTI)

    Hsiao, Hsien-Ming; Pen, Ben-Li

    2013-07-01

    About 200 liters highly radioactive acidic liquid waste originating from Mo-99 production was stored at INER (Institute of Nuclear Energy Research). A study regarding the treatment of the radioactive acidic liquid waste was conducted to solve storage-related issues and allow discharge of the waste while avoiding environmental pollution. Before discharging the liquid waste, the acidity, NO{sub 3}{sup -} and Hg ions in high concentrations, and radionuclides must comply with environmental regulations. Therefore, the treatment plan was to neutralize the acidic liquid waste, remove key radionuclides to reduce the dose rate, and then remove the nitrate and mercury ions. Bench tests revealed that NaOH is the preferred solution to neutralize the high acidic waste solution and the pH of solution must be adjusted to 9?11 prior to the removal of nuclides. Significant precipitation was produced when the pH of solution reached 9. NaNO{sub 3} was the major content in the precipitate and part of NaNO{sub 3} was too fine to be completely collected by filter paper with a pore size of approximately 3 ?m. The residual fine particles remaining in solution therefore blocked the adsorption column during operation. Two kinds of adsorbents were employed for Cs-137 and a third for Sr-90 removal to minimize cost. For personnel radiation protection, significant lead shielding was required at a number of points in the process. The final process design and treatment facilities successfully treated the waste solutions and allowed for environmentally compliant discharge. (authors)

  13. Study on the reduction of atmospheric mercury emissions from mine waste enriched soils through native grass cover in the Mt. Amiata region of Italy

    SciTech Connect (OSTI)

    Fantozzi, L.; Dini, F.; Tamburello, L.; Pirrone, N.; Sprovieri, F.

    2013-08-15

    Atmospheric mercury emissions from mine-waste enriched soils were measured in order to compare the mercury fluxes of bare soils with those from other soils covered by native grasses. Our research was conducted near Mt. Amiata in central Italy, an area that was one of the largest and most productive mining centers in Europe up into the 1980s. To determine in situ mercury emissions, we used a Plexiglas flux chamber connected to a portable mercury analyzer (Lumex RA-915+). This allowed us to detect, in real time, the mercury vapor in the air, and to correlate this with the meteorological parameters that we examined (solar radiation, soil temperature, and humidity). The highest mercury flux values (8000 ng m{sup −2} h{sup −1}) were observed on bare soils during the hours of maximum insulation, while lower values (250 ng m{sup −2} h{sup −1}) were observed on soils covered by native grasses. Our results indicate that two main environmental variables affect mercury emission: solar radiation intensity and soil temperature. The presence of native vegetation, which can shield soil surfaces from incident light, reduced mercury emissions, a result that we attribute to a drop in the efficiency of mercury photoreduction processes rather than to decreases in soil temperature. This finding is consistent with decreases in mercury flux values down to 3500 ng m{sup −2} h{sup −1}, which occurred under cloudy conditions despite high soil temperatures. Moreover, when the soil temperature was 28 °C and the vegetation was removed from the experimental site, mercury emissions increased almost four-fold. This increase occurred almost immediately after the grasses were cut, and was approximately eight-fold after 20 h. Thus, this study demonstrates that enhancing wild vegetation cover could be an inexpensive and effective approach in fostering a natural, self-renewing reduction of mercury emissions from mercury-contaminated soils. -- Highlights: ► Mercury air/surface exchange from grass covered soil is different from bare soil. ► Light enhances mercury emissions and is the main parameter driving the process. ► The presence of wild vegetation covering the soil reduces mercury emission. ► Vegetative covers could be a solution to reduce atmospheric mercury pollution.

  14. A novel Bi-based phosphomolybdate photocatalyst K{sub 2}Bi(PO{sub 4})(MoO{sub 4}): Crystal structure, electronic structure and photocatalytic activity

    SciTech Connect (OSTI)

    Huang, Hongwei; Chen, Gong; Wang, Shuobo; Kang, Lei; Lin, Zheshuai; Zhang, Yihe

    2014-03-01

    Graphical abstract: - Highlights: A new type of phosphomolybdate K{sub 2}Bi(PO{sub 4})(MoO{sub 4}) photocatalyst was successfully synthesized. The products synthesized at 600 C were mainly composed of nano-cubes. The indirect band gap of K{sub 2}Bi(PO{sub 4})(MoO{sub 4}) has been determined to be 2.93 eV. K{sub 2}Bi(PO{sub 4})(MoO{sub 4}) synthesized at 600 C exhibits the highest photocatalytic activity. The electronic structure was calculated by density functional calculations. - Abstract: A novel phosphomolybdate photocatalyst K{sub 2}Bi(PO{sub 4})(MoO{sub 4}) has been successfully developed via a solid-state reaction. The products were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HRTEM), diffuse reflectance spectrum (DRS) and photoluminescence (PL) spectra. The photocatalytic activities of the samples prepared at different temperature were determined by the photooxidative decomposition of methylene blue (MB) in aqueous solution. The results revealed that K{sub 2}Bi(PO{sub 4})(MoO{sub 4}) can be used as an effective photocatalyst under UVvis irradiation and the nanocubes obtained at 600 C exhibits the highest photocatalytic activity. The photodegradation of MB by K{sub 2}Bi(PO{sub 4})(MoO{sub 4}) nanocrystals followed the first-order kinetics. Theoretical calculations on electronic structure confirmed the indirect optical transitions property in the absorption edge region of K{sub 2}Bi(PO{sub 4})(MoO{sub 4}), and the orbital constitutions of CB and VB were also analyzed.

  15. Prediction and Monitoring Systems of Creep-Fracture Behavior of 9Cr-1Mo Steels for Teactor Pressure Vessels

    SciTech Connect (OSTI)

    Potirniche, Gabriel; Barlow, Fred D.; Charit, Indrajit; Rink, Karl

    2013-11-26

    A recent workshop on next-generation nuclear plant (NGNP) topics underscored the need for research studies on the creep fracture behavior of two materials under consideration for reactor pressure vessel (RPV) applications: 9Cr-1Mo and SA-5XX steels. This research project will provide a fundamental understanding of creep fracture behavior of modified 9Cr-1Mo steel welds for through modeling and experimentation and will recommend a design for an RPV structural health monitoring system. Following are the specific objectives of this research project: • Characterize metallurgical degradation in welded modified 9Cr-1Mo steel resulting from aging processes and creep service conditions. • Perform creep tests and characterize the mechanisms of creep fracture process. • Quantify how the microstructure degradation controls the creep strength of welded steel specimens. • Perform finite element (FE) simulations using polycrystal plasticity to understand how grain texture affects the creep fracture properties of welds. • Develop a microstructure-based creep fracture model to estimate RPVs service life . • Manufacture small, prototypic, cylindrical pressure vessels, subject them to degradation by aging, and measure their leak rates. • Simulate damage evolution in creep specimens by FE analyses. • Develop a model that correlates gas leak rates from welded pressure vessels with the amount of microstructural damage. • Perform large-scale FE simulations with a realistic microstructure to evaluate RPV performance at elevated temperatures and creep strength. • Develop a fracture model for the structural integrity of RPVs subjected to creep loads. • Develop a plan for a non-destructive structural health monitoring technique and damage detection device for RPVs.

  16. Progress and status of the IAEA coordinated research project: production of Mo-99 using LEU fission or neutron activation

    SciTech Connect (OSTI)

    Goldman, Ira N.; Adelfang, Pablo E-mail: P.Adelfang@iaea.org; Ramamoorthy, Natesan

    2008-07-15

    Since late 2004, the IAEA has developed and implemented a Coordinated Research Project (CRP) to assist countries interested in initiating indigenous, small-scale production of Mo-99 to meet local nuclear medicine requirements. The objective of the CRP is to provide interested countries with access to non-proprietary technologies and methods to produce Mo-99 using LEU foil or LEU mini-plate targets, or for the utilization of n,gamma neutron activation, e.g. through the use of gel generators. The project has made further progress since the RERTR 2006 meeting, with a Technical Workshop on Operational Aspects of Mo99 Production held 28-30 November 2006 in Vienna and the Second Research Coordination Meeting held in Bucharest, Romania 16-20 April 2007. The paper describes activities carried out as noted above, and as well as the provision of LEU foils to a number of participants, and the progress by a number of groups in preparing for LEU target assembly and disassembly, irradiation, chemical processing, and waste management. The participants' progress in particular on thermal hydraulics computations required for using LEU targets is notable, as also the progress in gel generator plant operations in India and Kazakhstan. Poland has joined as a new research agreement holder and an application by Egypt to be a contract holder is undergoing internal review in the IAEA and is expected to be approved. The IAEA has also participated in several open meetings of the U.S. National Academy of Sciences Study on Producing Medical Radioisotopes without HEU, which will also be discussed in the paper. (author)

  17. Effects of Irradiation on the Microstructure of U-7Mo Dispersion Fuel with Al-2Si Matrix

    SciTech Connect (OSTI)

    Dennis D. Keiser, Jr.; Jan-Fong Jue; Adam B. Robinson; Pavel Medvedev; Jian Gan; Brandon D. Miller; Daniel M. Wachs; Glenn A. Moore; Curtis R. Clark; Mitchell K. Meyer; M. Ross Finlay

    2012-06-01

    The Reduced Enrichment for Research and Test Reactor program is developing low-enriched uranium U-Mo dispersion fuels for application in research and test reactors around the world. As part of this development, fuel plates have been irradiated in the Advanced Test Reactor and then characterized using optical metallography (OM) and scanning electron microscopy (SEM) to determine the as-irradiated microstructure. To demonstrate the irradiation performance of U-7Mo dispersion fuel plates with 2 wt% Si added to the matrix, fuel plates were tested to medium burnups at intermediate fission rates as part of the RERTR-6 experiment. Further testing was performed to higher fission rates as part of the RERTR-7A experiment, and very aggressive testing (high temperature, high fission density, high fission rate) was performed in the RERTR-9A, RERTR-9B and AFIP-1 experiments. As-irradiated microstructures were compared to those observed after fabrication to determine the effects of irradiation on the microstructure. Based on comparison of the microstructural characterization results for each irradiated sample, some general conclusions can be drawn about how the microstructure evolves during irradiation: there is growth of the fuel/matrix interaction layer (FMI), which was present in the samples to some degree after fabrication, during irradiation; Si diffuses from the FMI layer to deeper depths in the U-7Mo particles as the irradiation conditions are made more aggressive; lowering of the Si content in the FMI layer results in an increase in the size of the fission gas bubbles; as the FMI layer grows during irradiation more Si diffuses from the matrix to the FMI layer/matrix interface, and interlinking of fission gas bubbles in the fuel plate microstructure that may indicate breakaway swelling is not observed.

  18. Strain, interdiffusion, and microstructural evolution under ion irradiation in Ni(111)/Mo(110) multilayers: Interdependence with elastic properties

    SciTech Connect (OSTI)

    Martin, F.; Jaouen, C.; Pacaud, J.; Abadias, G.; Djemia, Ph.; Ganot, F.

    2005-01-15

    The interdependence between the microstructure of sputter-deposited Ni(111)/Mo(110) superlattices and their elastic behavior is investigated as a function of the bilayer period ({lambda}). Brillouin light scattering measurements show that a drastic softening of the effective shear modulus occurs with decreasing {lambda}, until {lambda}=2 nm where it reaches -62%. Ion irradiation is here used to trigger stress relaxation and to induce, in a controlled way, interdiffusion and structural changes allowing us thus to investigate their influence on the elastic anomaly. At a very low irradiation dose (0.1 displacements per atom), the relief of the lattice expansion and associated compressive stresses does not induce any change of the elastic response, which indicates that the elastic behavior of the as-grown multilayers is not correlated with the presence of elastic strains. Furthermore, a detailed x-ray diffraction analysis shows that the unstrained lattice parameter of Mo layers exhibit a linear dependence with the interface density, while the Ni unstrained lattice parameter remains nearly unchanged in the same {lambda} range. This effect can be attributed to an interfacial mixing of a constant Ni amount ({approx}1.5 monolayers) into the Mo layers, as a consequence of a dynamic segregation of Ni atoms during growth. Thus, the formation of interfacial metastable and supersaturated solid solutions, structurally and mechanically unstable, appears as the origin of the huge elastic softening observed in this system. At high ion fluences, when the mixing process becomes dominant, the present study also provides experimental data on phase transformation in 'driven' alloys, by addressing the issue of the stability of out-of-equilibrium structures under irradiation.

  19. Crystal structural study of ternary molybdate LiRbBi{sub 2}(MoO{sub 4}){sub 4}

    SciTech Connect (OSTI)

    Klevtsova, R.F.; Glinskaya, L.A.; Alekseev, V.I.

    1994-03-01

    Single crystals of the title compound have been synthesized and its crystal structure has been determined. The compound crystallizes in the monoclinic system, space group C2/c, Z = 2 (a = 5.3056, b = 12.976, c = 19.578 {angstrom}, {beta} = 92.583{degrees}, R = 0.029). A distinctive feature of the structure is lacy layers of eight-vertex Bi polyhedra and Mo tetrahedra connected to them via common vertices. The adjacent layers are linked together by ten-vertex Rb polyhedra and Li octahedra.

  20. Deformation and fracture behavior of Ni-Mo-Al (. gamma. /. gamma. -. cap alpha. ) in-situ composite

    SciTech Connect (OSTI)

    Siramamurthy, A.M.; Tewari, S.N.

    1984-10-01

    Tensile properties for directionally solidified (DS) eutectic alloy of a nominal composition Ni-33 Mo-5.7 Al (weight percent) have been investigated at room and elevated temperatures. The microstructure-mechanical property relationship has been studied for the as-DS and heat-treated conditions. Changes in yield strength, work hardening behavior, and fracture morphology are explained in terms of microstructural changes due to heat treatment. The yield drops are attributed to microdebonding due to segregation of impurities at the fiber-matrix interface and partly to strain aging.

  1. Discrete Li-occupation versus pseudo-continuous Na-occupation and their relationship with structural change behaviors in Fe?(MoO?)?

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yue, Ji-Li; Zhou, Yong-Ning; Shi, Si-Qi; Shadike, Zulipiya; Huang, Xuan-Qi; Luo, Jun; Yang, Zhen-Zhong; Li, Hong; Gu, Lin; Yang, Xiao-Qing; et al

    2015-03-06

    The key factors governing the single-phase or multi-phase structural change behaviors during the intercalation/deintercalation of guest ions have not been well studied and understood yet. Through systematic studies of orthorhombic Fe?(MoO?)? electrode, two distinct guest ion occupation paths, namely discrete one for Li and pseudo-continuous one for Na, as well as their relationship with single-phase and two-phase modes for Na? and Li?, respectively during the intercalation/deintercalation process have been demonstrated. For the first time, the direct atomic-scale observation of biphasic domains (discrete occupation) in partially lithiated Fe?(MoO?)? and the one by one Na occupation (pseudo-continuous occupation) at 8d sites inmorepartially sodiated Fe?(MoO?)? are obtained during the discharge processes of Li/Fe?(MoO?)? and Na/Fe?(MoO?)? cells respectively. Our combined experimental and theoretical studies bring the new insights for the research and development of intercalation compounds as electrode materials for secondary batteries.less

  2. Synthesis of novel MoS{sub 2}/g-C{sub 3}N{sub 4} heterojunction photocatalysts with enhanced hydrogen evolution activity

    SciTech Connect (OSTI)

    Tian, Yuming; Ge, Lei; Wang, Kaiyue; Chai, Yuesheng

    2014-01-15

    Novel MoS{sub 2}/g-C{sub 3}N{sub 4} heterojunction photocatalysts were synthesized via a simple impregnation and heating methods. The products were characterized by X-ray diffraction, transmission electron microscopy and UVvis diffuse reflectance spectra. The photocatalytic activities of MoS{sub 2}/g-C{sub 3}N{sub 4} samples were evaluated based on the hydrogen evolution experiments under visible light irradiation (? > 400 nm). The UVvis diffuse reflectance spectra revealed that the MoS{sub 2}/g-C{sub 3}N{sub 4} photocatalysts had strong absorption in the visible light region. The photocatalytic results indicated that the highest H{sub 2} evolution rate of 23.10 ?molh{sup ?1} was achieved on the 0.5 wt.% MoS{sub 2}g-C{sub 3}N{sub 4} sample, which was enhanced by 11.3 times compared to pure g-C{sub 3}N{sub 4}. This study may provide an approach to the development of novel heterojunction photocatalysts for hydrogen production under visible light irradiation. - Highlights: MoS{sub 2}/g-C{sub 3}N{sub 4} photocatalyst is obtained by simple impregnation and heating methods. and determined by XRD, TEM, UV-vis diffuse reflectance spectra. the photocatalysts had strong absorption in the visible light region. the highest H2 evolution rate was achieved on the 0.5wt% samples.

  3. Thermal expansion of Cr{sub 2x}Fe{sub 2-2x}Mo{sub 3}O{sub 12}, Al{sub 2x}Fe{sub 2-2x}Mo{sub 3}O{sub 12} and Al{sub 2x}Cr{sub 2-2x}Mo{sub 3}O{sub 12} solid solutions

    SciTech Connect (OSTI)

    Ari, M.; Jardim, P.M.; Marinkovic, B.A. Rizzo, F.; Ferreira, F.F.

    2008-06-15

    The transition temperature from monoclinic to orthorhombic and the thermal expansion of the orthorhombic phase were investigated for three systems of the family A{sub 2}M{sub 3}O{sub 12}: Cr{sub 2x}Fe{sub 2-2x}Mo{sub 3}O{sub 12}, Al{sub 2x}Fe{sub 2-2x}Mo{sub 3}O{sub 12} and Al{sub 2x}Cr{sub 2-2x}Mo{sub 3}O{sub 12}. It was possible to obtain a single-phase solid solution in all studied samples (x=0, 0.1, 0.3, 0.5, 0.7, 0.9 and 1). A linear relationship between the transition temperature and the fraction of A{sup 3+} cations (x) was observed for each system. In all orthorhombic solid solutions studied here the observed thermal expansion was anisotropic. These anisotropic thermal expansion properties of crystallographic axes a, b and c result in a low positive or near-zero overall linear coefficient of thermal expansion ({alpha}{sub l}={alpha}{sub V}/3). The relationship between the size of A{sup 3+} cations in A{sub 2}M{sub 3}O{sub 12} and the coefficient of thermal expansion is discussed. Near-zero thermal expansion of Cr{sub 2}Mo{sub 3}O{sub 12} is explained by the behavior of Cr-O and Mo-O bond distances, Cr-Mo non-bond distances and Cr-O-Mo bond angles with increasing temperature, estimated by Rietveld analysis of synchrotron X-ray powder diffraction data. - Graphical abstract: In this figure, all published overall linear coefficients of thermal expansion for orthorhombic A{sub 2}M{sub 3}O{sub 12} family obtained through diffraction methods as a function of A{sup 3+} cation radii size, together with dilatometric results, are plotted. Our results indicate that Cr{sub 2}Mo{sub 3}O{sub 12} does not exactly follow the established relationship.

  4. Demonstration of femtosecond laser ablation inductively coupled plasma mass spectrometry for uranium isotopic measurements in U-10Mo nuclear fuel foils

    SciTech Connect (OSTI)

    Havrilla, George Joseph; Gonzalez, Jhanis

    2015-06-10

    The use of femtosecond laser ablation inductively coupled plasma mass spectrometry was used to demonstrate the feasibility of measuring the isotopic ratio of uranium directly in U-10Mo fuel foils. The measurements were done on both the flat surface and cross sections of bare and Zr clad U-10Mo fuel foil samples. The results for the depleted uranium content measurements were less than 10% of the accepted U235/238 ratio of 0.0020. Sampling was demonstrated for line scans and elemental mapping over large areas. In addition to the U isotopic ratio measurement, the Zr thickness could be measured as well as trace elemental composition if required. A number of interesting features were observed during the feasibility measurements which could provide the basis for further investigation using this methodology. The results demonstrate the feasibility of using fs-LA-ICP-MS for measuring the U isotopic ratio in U-10Mo fuel foils.

  5. Efficient Interlayer Relaxation and Transition of Excitons in Epitaxial and Non-epitaxial MoS2/WS2 Heterostructures

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yu, Yifei; Hu, Shi; Su, Liqin; Huang, Lujun; Liu, Yi; Jin, Zhenghe; Puretzky, Alexander A; Geohegan, David B; Kim, Ki Wook; Zhang, Yong; et al

    2014-01-01

    Semiconductor heterostructurs provide a powerful platform for the engineering of excitons. Here we report on the excitonic properties of two-dimensional (2D) heterostructures that consist of monolayer MoS2 and WS2 stacked epitaxially or non-epitaxially in the vertical direction. We find similarly efficient interlayer relaxation and transition of excitons in both the epitaxial and non-epitaxial heterostructures. This is manifested by a two orders of magnitude decrease in the photoluminescence and an extra absorption peak at low energy region of both heterostructures. The MoS2/WS2 heterostructures show weak interlayer coupling and essentially act as an atomic-scale heterojunction with the intrinsic band structures of themore » two monolayers largely preserved. They are particularly promising for the applications that request efficient dissociation of excitons and strong light absorption, including photovoltaics, solar fuels, photodetectors, and optical modulators. Our results also indicate that 2D heterostructures promise to provide capabilities to engineer excitons from the atomic level without concerns of interfacial imperfection.« less

  6. Electrolysis of uranium nitride containing fission product elements (Mo, Pd, Nd) in a molten LiCl-KCl eutectic

    SciTech Connect (OSTI)

    Satoh, Takumi; Iwai, Takashi; Arai, Yasuo

    2007-07-01

    The electrolysis of burnup-simulated uranium nitride, UN, containing representative solid fission product elements (Mo, Pd, Nd) was investigated in the molten LiCl-KCl eutectic salt with 0.54 wt% UCl{sub 3} from the view point of application of pyrochemical reprocessing to nitride fuel cycle. It was found from cyclic voltammetry and anodic polarization curve measurement that anodic dissolution of UN began at about -0.75 V vs. Ag/AgCl reference electrode in all samples. After the electrolysis at the constant anodic potential of -0.65 {approx} -0.60 V vs. Ag/AgCl, most of UN was dissolved into LiCl- KCl as UCl{sub 3} at the anode, and U was recovered in the liquid Cd cathode in all samples. Further, Nd was dissolved into LiCl-KCl as NdCl{sub 3}, while Mo and Pd were not dissolved but remained at the anode. (authors)

  7. Density functional theory study of chemical sensing on surfaces of single-layer MoS{sub 2} and graphene

    SciTech Connect (OSTI)

    Mehmood, F.; Pachter, R.

    2014-04-28

    In this work, density functional theory (DFT) calculations have been used to investigate chemical sensing on surfaces of single-layer MoS{sub 2} and graphene, considering the adsorption of the chemical compounds triethylamine, acetone, tetrahydrofuran, methanol, 2,4,6-trinitrotoluene, o-nitrotoluene, o-dichlorobenzene, and 1,5-dicholoropentane. Physisorption of the adsorbates on free-standing surfaces was analyzed in detail for optimized material structures, considering various possible adsorption sites. Similar adsorption characteristics for the two surface types were demonstrated, where inclusion of a correction to the DFT functional for London dispersion was shown to be important to capture interactions at the interface of molecular adsorbate and surface. Charge transfer analyses for adsorbed free-standing surfaces generally demonstrated very small effects. However, charge transfer upon inclusion of the underlying SiO{sub 2} substrate rationalized experimental observations for some of the adsorbates considered. A larger intrinsic response for the electron-donor triethylamine adsorbed on MoS{sub 2} as compared to graphene was demonstrated, which may assist in devising chemical sensors for improved sensitivity.

  8. Comparison of Crevice Corrosion of Fe-Based Amorphous Metal and Crystalline Ni-Cr-Mo Alloy

    SciTech Connect (OSTI)

    Shan, X; Ha, H; Payer, J H

    2008-07-24

    The crevice corrosion behaviors of an Fe-based bulk metallic glass alloy (SAM1651) and a Ni-Cr-Mo crystalline alloy (C-22) were studied in 4M NaCl at 100 C with cyclic potentiodynamic polarization and constant potential tests. The corrosion damage morphologies, corrosion products and the compositions of corroded surfaces of these two alloys were studied with optical 3D reconstruction, Scanning Electron Microscopy (SEM), Energy Dispersive Spectroscopy (EDS) and Auger Electron Spectroscopy (AES). It was found that the Fe-based bulk metallic glass (amorphous alloy) SAM1651 had a more positive breakdown potential and repassivation potential than crystalline alloy C-22 in cyclic potentiodynamic polarization tests and required a more positive oxidizing potential to initiate crevice corrosion in constant potential test. Once crevice corrosion initiated, the corrosion propagation of C-22 was more localized near the crevice border compared to SAM1651, and SAM1651 repassivated more readily than C-22. The EDS results indicated that the corrosion products of both alloys contained high amount of O and were enriched in Mo and Cr. The AES results indicated that a Cr-rich oxide passive film was formed on the surfaces of both alloys, and both alloys were corroded congruently.

  9. Electrical characteristics of multilayer MoS{sub 2} transistors at real operating temperatures with different ambient conditions

    SciTech Connect (OSTI)

    Kwon, Hyuk-Jun; Grigoropoulos, Costas P.; Jang, Jaewon Subramanian, Vivek; Kim, Sunkook

    2014-10-13

    Atomically thin, two-dimensional (2D) materials with bandgaps have attracted increasing research interest due to their promising electronic properties. Here, we investigate carrier transport and the impact of the operating ambient conditions on back-gated multilayer MoS{sub 2} field-effect transistors with a thickness of ?50?nm at their realistic working temperatures and under different ambient conditions (in air and in a vacuum of ?10{sup ?5}?Torr). Increases in temperature cause increases in I{sub min} (likely due to thermionic emission at defects), and result in decreased I{sub on} at high V{sub G} (likely due to increased phonon scattering). Thus, the I{sub on}/I{sub min} ratio decreases as the temperature increases. Moreover, the ambient effects with working temperatures on field effect mobilities were investigated. The adsorbed oxygen and water created more defect sites or impurities in the MoS{sub 2} channel, which can lead another scattering of the carriers. In air, the adsorbed molecules and phonon scattering caused a reduction of the field effect mobility, significantly. These channel mobility drop-off rates in air and in a vacuum reached 0.12?cm{sup 2}/V s K and 0.07?cm{sup 2}/V s K, respectively; the rate of degradation is steeper in air than in a vacuum due to enhanced phonon mode by the adsorbed oxygen and water molecules.

  10. untitled

    Gasoline and Diesel Fuel Update (EIA)

    2005 (Thousand Barrels) East Coast Appalachian No. 1 Total IN, IL, KY MN, WI, ND, SD OK, KS, MO Total Liquefied Refinery Gases 382 8 390 2,072 157 116 2,345 EthaneEthylene 10...

  11. untitled

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    2005 (Thousand Barrels) East Coast Appalachian No. 1 Total IN, IL, KY MN, WI, ND, SD OK, KS, MO Total Liquefied Refinery Gases 331 -18 313 2,398 -147 -220 2,031 EthaneEthylene...

  12. Category:Utility Rate Impacts on PV Economics By Location | Open...

    Open Energy Info (EERE)

    MI Traverse City, MI International Falls, MN Minneapolis, MN Kansas City, MO Jackson, MS Billings, MT Greensboro, NC Wilmington, NC Bismarck, ND Minot, ND Omaha, NE...

  13. Scanning Electron Microscopy Analysis of Fuel/Matrix Interaction Layers in Highly-Irradiated UMo Dispersion Fuel Plates with Al and AlSi Alloy Matrices

    SciTech Connect (OSTI)

    Dennis D. Keiser, Jr.; Jan-Fong Jue; Brandon D. Miller; Jian Gan; Adam B. Robinson; Pavel Medvedev; James Madden; Dan Wachs; Mitch Meyer

    2014-04-01

    In order to investigate how the microstructure of fuel/matrix-interaction (FMI) layers change during irradiation, different U7Mo dispersion fuel plates have been irradiated to high fission density and then characterized using scanning electron microscopy (SEM). Specifially, samples from irradiated U7Mo dispersion fuel elements with pure Al, Al2Si and AA4043 (~4.5 wt.%Si) matrices were SEM characterized using polished samples and samples that were prepared with a focused ion beam (FIB). Features not observable for the polished samples could be captured in SEM images taken of the FIB samples. For the Al matrix sample, a relatively large FMI layer develops, with enrichment of Xe at the FMI layer/Al matrix interface and evidence of debonding. Overall, a significant penetration of Si from the FMI layer into the U7Mo fuel was observed for samples with Si in the Al matrix, which resulted in a change of the size (larger) and shape (round) of the fission-gas bubbles. Additionally, solid-fission-product phases were observed to nucleate and grow within these bubbles. These changes in the localized regions of the microstructure of the U7Mo may contribute to changes observed in the macroscopic swelling of fuel plates with AlSi matrices.

  14. Population Pulsation Resonances of Excitons in Monolayer MoSe 2 with Sub- 1 μ eV Linewidths

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Schaibley, John R.; Karin, Todd; Yu, Hongyi; Ross, Jason S.; Rivera, Pasqual; Jones, Aaron M.; Scott, Marie E.; Yan, Jiaqiang; Mandrus, D. G.; Yao, Wang; et al

    2015-04-01

    Monolayer transition metal dichalcogenides, a new class of atomically thin semiconductors, possess optically coupled 2D valley excitons. The nature of exciton relaxation in these systems is currently poorly understood. Here, we investigate exciton relaxation in monolayer MoSe₂ using polarization-resolved coherent nonlinear optical spectroscopy with high spectral resolution. We report strikingly narrow population pulsation resonances with two different characteristic linewidths of 1 and <0.2 μeV at low temperature. These linewidths are more than 3 orders of magnitude narrower than the photoluminescence and absorption linewidth, and indicate that a component of the exciton relaxation dynamics occurs on time scales longer than 1more » ns. The ultranarrow resonance (<0.2 μeV) emerges with increasing excitation intensity, and implies the existence of a long-lived state whose lifetime exceeds 6 ns.« less

  15. Irradiation behavior of the interaction product of U-Mo fuel particle dispersion in an Al matrix.

    SciTech Connect (OSTI)

    Kim, Y.S.; Hofman, G. (Nuclear Engineering Division)

    2012-06-01

    Irradiation performance of U-Mo fuel particles dispersed in Al matrix is stable in terms of fuel swelling and is suitable for the conversion of research and test reactors from highly enriched uranium (HEU) to low enriched uranium (LEU). However, tests of the fuel at high temperatures and high burnups revealed obstacles caused by the interaction layers forming between the fuel particle and matrix. In some cases, fission gas filled pores grow and interconnect in the interdiffusion layer resulting in fuel plate failure. Postirradiation observations are made to examine the behavior of the interdiffusion layers. The interdiffusion layers show a fluid-like behavior characteristic of amorphous materials. In the amorphous interdiffusion layers, fission gas diffusivity is high and the material viscosity is low so that the fission gas pores readily form and grow. Based on the observations, a pore formation mechanism is proposed and potential remedies to suppress the pore growth are also introduced.

  16. Formation of BaSi{sub 2} heterojunction solar cells using transparent MoO{sub x} hole transport layers

    SciTech Connect (OSTI)

    Du, W.; Takabe, R.; Baba, M.; Takeuchi, H.; Toko, K.; Hara, K. O.; Usami, N.; Suemasu, T.

    2015-03-23

    Heterojunction solar cells that consist of 15?nm thick molybdenum trioxide (MoO{sub x}, x?

  17. Effects of the solvent on the structure, morphology and photocatalytic properties of Bi{sub 2}MoO{sub 6} in the solvothermal process

    SciTech Connect (OSTI)

    Bi, Jinhong; Che, Jiangang; Wu, Ling; Liu, Minghua

    2013-06-01

    Graphical abstract: Various nanostructure Bi{sub 2}MoO{sub 6} photocatalysts have been prepared by a solvothermal process via simply altering the used solvent. It is revealed that the type of solvents has a strong influence on the morphology of Bi{sub 2}MoO{sub 6}. This could be understood in terms of the reaction media effect on the crystal growth. The photocatalytic experiments for the decomposition of RhB demonstrate that the samples prepared by different solvents show different photocatalytic activity. The highest photocatalytic activity is obtained by the sample with glycol as solvent. Highlights: ? The used solvent in the synthesis can affect the morphology and size of Bi{sub 2}MoO{sub 6}. ? Different solvent in the reaction leads to different surface area and pore size. ? The highest photocatalytic activity is obtained by the sample prepared in glycol. ? The high activity is mainly due to the large surface area and small particle size. - Abstract: Visible-light-driven photocatalyst Bi{sub 2}MoO{sub 6} was prepared by a solvothermal process with different kinds of solvent including water, isopropanol and ethylene glycol. The obtained samples were characterized by X-ray diffraction technique, N{sub 2}-sorption, UVvis diffuse reflectance spectra, transmission electron microscopy and Fourier transform infrared spectroscopy. The results revealed that the type of solvent has a strong influence on the morphologies and physico-chemical properties of Bi{sub 2}MoO{sub 6}. Meanwhile, the formation mechanism of Bi{sub 2}MoO{sub 6} with various morphologies was discussed. The photocatalytic activities of Bi{sub 2}MoO{sub 6} photocatalysts were evaluated by the decomposition of rhodamine B (RhB) under visible light irradiation (? > 420 nm). It was found that the sample prepared with glycol as solvent showed the best performance in the photodegradation of RhB under visible light irradiation. This could be ascribed to the large surface area, unique morphology and small particle size.

  18. Comparative study of water reactivity with Mo{sub 2}O{sub y}{sup ?} and W{sub 2}O{sub y}{sup ?} clusters: A combined experimental and theoretical investigation

    SciTech Connect (OSTI)

    Ray, Manisha; Waller, Sarah E.; Saha, Arjun; Raghavachari, Krishnan; Jarrold, Caroline Chick

    2014-09-14

    A computational investigation of the Mo{sub 2}O{sub y}{sup ?} + H{sub 2}O (y = 4, 5) reactions as well as a photoelectron spectroscopic probe of the deuterated Mo{sub 2}O{sub 6}D{sub 2}{sup ?} product have been carried out to understand a puzzling question from a previous study: Why is the rate constant determined for the Mo{sub 2}O{sub 5}{sup ?} + H{sub 2}O/D{sub 2}O reaction, the terminal reaction in the sequential oxidation of Mo{sub 2}O{sub y}{sup ?} by water, higher than the W{sub 2}O{sub 5}{sup ?} + H{sub 2}O/D{sub 2}O reaction? This disparity was intriguing because W{sub 3}O{sub y}{sup ?} clusters were found to be more reactive toward water than their Mo{sub 3}O{sub y}{sup ?} analogs. A comparison of molecular structures reveals that the lowest energy structure of Mo{sub 2}O{sub 5}{sup ?} provides a less hindered water addition site than the W{sub 2}O{sub 5}{sup ?} ground state structure. Several modes of water addition to the most stable molecular and electronic structures of Mo{sub 2}O{sub 4}{sup ?} and Mo{sub 2}O{sub 5}{sup ?} were explored computationally. The various modes are discussed and compared with previous computational studies on W{sub 2}O{sub y}{sup ?} + H{sub 2}O reactions. Calculated free energy reaction profiles show lower barriers for the initial Mo{sub 2}O{sub y}{sup ?} + H{sub 2}O addition, consistent with the higher observed rate constant. The terminal Mo{sub 2}O{sub y}{sup ?} sequential oxidation product predicted computationally was verified by the anion photoelectron spectrum of Mo{sub 2}O{sub 6}D{sub 2}{sup ?}. Based on the computational results, this anion is a trapped dihydroxide intermediate in the Mo{sub 2}O{sub 5}{sup ?} + H{sub 2}O/D{sub 2}O ? Mo{sub 2}O{sub 6}{sup ?} + H{sub 2}/D{sub 2} reaction.

  19. Electronic and magnetic properties of armchair MoS{sub 2} nanoribbons under both external strain and electric field, studied by first principles calculations

    SciTech Connect (OSTI)

    Hu, Ting; Dong, Jinming; Zhou, Jian; Kawazoe, Yoshiyuki

    2014-08-14

    The electronic and magnetic properties of armchair edge MoS{sub 2} nanoribbons (MoS{sub 2}-ANRs) underboth the external strain and transverse electric field (E{sub t}) have been systematically investigated by using the first-principles calculations. It is found that: (1) If no electric field is applied, an interesting structural phase transition would appear under a large tensile strain, leading to a new phase MoS{sub 2}-A'NR, and inducing a big jump peak of the band gap in the transition region. But, the band gap response to compressive strains is much different from that to tensile strain, showing no the structural phase transition. (2) Under the small tensile strains (<10%), the combined E{sub t} and tensile strain give rise to a positive superposition (resonant) effect on the band gap reduction at low E{sub t} (<3 V/nm), and oppositely a negative superposition (antiresonant) one at high E{sub t} (>4 V/nm). On the other hand, the external compressive strains have always presented the resonant effect on the band gap reduction, induced by the electric field. (3) After the structural phase transition, an external large tensile strain could greatly reduce the critical field E{sub tc} causing the band gap closure, and make the system become a ferromagnetic (FM) metal at a relative low E{sub t} (e.g., <4 V/nm), which is very helpful for its promising applications in nano-mechanical spintronics devices. (4) At high E{sub t} (>10 V/nm), the magnetic moments of both the MoS{sub 2}-ANR and MoS{sub 2}-A'NR in their FM states could be enhanced greatly by a tensile strain. Our numerical results of effectively tuning physical properties of MoS{sub 2}-ANRs by combined external strain and electric field may open their new potential applications in nanoelectronics and spintronics.

  20. Microstructural characterization of a thin film ZrN diffusion barrier in an As-fabricated U7Mo/Al matrix dispersion fuel plate

    SciTech Connect (OSTI)

    Keiser, Dennis D.; Perez, Emmanuel; Wiencek, Tom; Leenaers, Ann; Van den Berghe, Sven

    2015-03-01

    The United States High Performance Research Reactor Fuel Development program is developing low enriched uranium fuels for application in research and test reactors. One concept utilizes U7 wt.% Mo (U7Mo) fuel particles dispersed in Al matrix, where the fuel particles are coated with a 1 ?m-thick ZrN coating. The ZrN serves as a diffusion barrier to eliminate a deleterious reaction that can occur between U7Mo and Al when a dispersion fuel is irradiated under aggressive reactor conditions. To investigate the final microstructure of a physically-vapor-deposited ZrN coating in a dispersion fuel plate after it was fabricated using a rolling process, characterization samples were taken from a fuel plate that was fabricated at 500 C using ZrN-coated U7Mo particles, Al matrix and AA6061 cladding. Scanning electron and transmission electron microscopy analysis were performed. Data from these analyses will be used to support future microstructural examinations of irradiated fuel plates, in terms of understanding the effects of irradiation on the ZrN microstructure, and to determine the role of diffusion barrier microstructure in eliminating fuel/matrix interactions during irradiation. The as-fabricated coating was determined to be cubic-ZrN (cF8) phase. It exhibited a columnar microstructure comprised of nanometer-sized grains and a region of relatively high porosity, mainly near the Al matrix. Small impurity-containing phases were observed at the U7Mo/ZrN interface, and no interaction zone was observed at the ZrN/Al interface. The bonding between the U7Mo and ZrN appeared to be mechanical in nature. A relatively high level of oxygen was observed in the ZrN coating, extending from the Al matrix in the ZrN coating in decreasing concentration. The above microstructural characteristics are discussed in terms of what may be most optimal for a diffusion barrier in a dispersion fuel plate application.

  1. STEM HAADF Image Simulation of the Orthorhombic M1 Phase in the Mo-V-Nb-Te-O Propane Oxidation Catalyst

    SciTech Connect (OSTI)

    D Blom; X Li; S Mitra; T Vogt; D Buttrey

    2011-12-31

    A full frozen phonon multislice simulation of high angle annular dark field scanning transmission electron microscopy (HAADF STEM) images from the M1 phase of the Mo-V-Nb-Te-O propane oxidation catalyst has been performed by using the latest structural model obtained using the Rietveld method. Simulated contrast results are compared with experimental HAADF images. Good agreement is observed at ring sites, however significant thickness dependence is noticed at the linking sites. The remaining discrepancies between the model based on Rietveld refinement and image simulations indicate that the sampling of a small volume element in HAADF STEM and averaging elemental contributions of a disordered site in a crystal slab by using the virtual crystal approximation might be problematic, especially if there is preferential Mo/V ordering near the (001) surface.

  2. Policy Flash 2013-40 Acquisition Guide Chapter 43.3 Maintaining Alignment of Project Management with Contract Management of Non-Management and Operating (M&O) Cost Reimburstment Contracts

    Broader source: Energy.gov [DOE]

    Attached is Policy Flash 2013-40 Acquisition Guide Chapter 43.3 Maintaining Alignment of Project Management with Contract Management of Non-Management and Operating (M&O) Cost Reimbursement...

  3. Self-powdering and nonlinear optical domain structures in ferroelastic beta'-Gd{sub 2}(MoO{sub 4}){sub 3} crystals formed in glass

    SciTech Connect (OSTI)

    Tsukada, Y.; Honma, T.; Komatsu, T.

    2009-08-15

    Ferroelastic beta'-Gd{sub 2}(MoO{sub 4}){sub 3}, (GMO), crystals are formed through the crystallization of 21.25Gd{sub 2}O{sub 3}-63.75MoO{sub 3}-15B{sub 2}O{sub 3} glass (mol%), and two scientific curious phenomena are observed. (1) GMO crystals formed in the crystallization break into small pieces with a triangular prism or pyramid shape having a length of 50-500 {mu}m spontaneously during the crystallizations in the inside of an electric furnace, not during the cooling in air after the crystallization. This phenomenon is called 'self-powdering phenomenon during crystallization' in this paper. (2) Each self-powdered GMO crystal grain shows a periodic domain structure with different refractive indices, and a spatially periodic second harmonic generation (SHG) depending on the domain structure is observed. It is proposed from polarized micro-Raman scattering spectra and the azimuthal dependence of second harmonic intensities that GMO crystals are oriented in each crystal grain and the orientation of (MoO{sub 4}){sup 2-} tetrahedra in GMO crystals changes periodically due to spontaneous strains in ferroelastic GMO crystals. - Graphical abstract: This figure shows the polarized optical photograph at room temperature for a particle (piece) obtained by a heat treatment of the glass at 590 deg. C for 2 h in an electric furnace in air. This particle was obtained through the self-powdering behavior in the crystallization of glass. The periodic domain structure is observed. Ferroelastic beta'-Gd{sub 2}(MoO{sub 4}){sub 3} crystals are formed in the particle, and second harmonic generations are detected, depending on the domain structure.

  4. Exciton diamagnetic shifts and valley Zeeman effects in monolayer WS2 and MoS2 to 65 Tesla

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Stier, Andreas V.; McCreary, Kathleen M.; Jonker, Berend T.; Kono, Junichiro; Crooker, Scott A.

    2016-02-09

    In bulk and quantum-confined semiconductors, magneto-optical studies have historically played an essential role in determining the fundamental parameters of excitons (size, binding energy, spin, dimensionality and so on). Here we report low-temperature polarized reflection spectroscopy of atomically thin WS2 and MoS2 in high magnetic fields to 65 T. Both the A and B excitons exhibit similar Zeeman splittings of approximately –230 μeV T–1 (g-factor ≃–4), thereby quantifying the valley Zeeman effect in monolayer transition-metal disulphides. Crucially, these large fields also allow observation of the small quadratic diamagnetic shifts of both A and B excitons in monolayer WS2, from which radiimore » of ~1.53 and ~1.16 nm are calculated. Further, when analysed within a model of non-local dielectric screening, these diamagnetic shifts also constrain estimates of the A and B exciton binding energies (410 and 470 meV, respectively, using a reduced A exciton mass of 0.16 times the free electron mass). Lastly, these results highlight the utility of high magnetic fields for understanding new two-dimensional materials.« less

  5. Electron-phonon coupling and thermal transport in the thermoelectric compound Mo3Sb7–xTex

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bansal, Dipanshu; Li, Chen W.; Said, Ayman H.; Abernathy, Douglas L.; Yan, Jiaqiang; Delaire, Olivier A.

    2015-12-07

    Phonon properties of Mo3Sb7–xTex (x = 0, 1.5, 1.7), a potential high-temperature thermoelectric material, have been studied with inelastic neutron and x-ray scattering, and with first-principles simulations. The substitution of Te for Sb leads to pronounced changes in the electronic struc- ture, local bonding, phonon density of states (DOS), dispersions, and phonon lifetimes. Alloying with tellurium shifts the Fermi level upward, near the top of the valence band, resulting in a strong suppression of electron-phonon screening, and a large overall stiffening of interatomic force- constants. The suppression in electron-phonon coupling concomitantly increases group velocities and suppresses phonon scattering rates, surpassingmore » the effects of alloy-disorder scattering, and re- sulting in a surprising increased lattice thermal conductivity in the alloy. We also identify that the local bonding environment changes non-uniformly around different atoms, leading to variable perturbation strengths for different optical phonon branches. The respective roles of changes in phonon group velocities and phonon lifetimes on the lattice thermal conductivity are quantified. Lastly, our results highlight the importance of the electron-phonon coupling on phonon mean-free-paths in this compound, and also estimates the contributions from boundary scattering, umklapp scattering, and point-defect scattering.« less

  6. Temperature-dependent phase-specific deformation mechanisms in a directionally solidified NiAl-Cr(Mo) lamellar composite

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yu, Dunji; An, Ke; Chen, Xu; Bei, Hongbin

    2015-10-09

    Phase-specific thermal expansion and mechanical deformation behaviors of a directionally solidified NiAl–Cr(Mo) lamellar in situ composite were investigated by using real-time in situ neutron diffraction during compression at elevated temperatures up to 800 °C. Tensile and compressive thermal residual stresses were found to exist in the NiAl phase and Crss (solid solution) phase, respectively. Then, based on the evolution of lattice spacings and phase stresses, the phase-specific deformation behavior was analyzed qualitatively and quantitatively. Moreover, estimates of phase stresses were derived by Hooke's law on the basis of a simple method for the determination of stress-free lattice spacing in inmore » situ composites. During compressive loading, the NiAl phase yields earlier than the Crss phase. The Crss phase carries much higher stress than the NiAl phase, and displays consistent strain hardening at all temperatures. The NiAl phase exhibits strain hardening at relatively low temperatures and softening at high temperatures. During unloading, the NiAl phase yields in tension whereas the Crss phase unloads elastically. Additionally, post-test microstructural observations show phase-through cracks at room temperature, micro cracks along phase interfaces at 600 °C and intact lamellae kinks at 800 °C, which is due to the increasing deformability of both phases as temperature rises.« less

  7. Better Catalysts through Microscopy: Nanometer Scale M1/M2 Intergrown Heterostructure in Mo-V-M Complex Oxides

    SciTech Connect (OSTI)

    He, Qian [ORNL; Woo, Jungwon [University of Cincinnati; Belianinov, Alex [ORNL; Guliants, Vadim V. [University of Cincinnati; Borisevich, Albina Y [ORNL

    2015-01-01

    In recent decades, catalysis research has transformed from the predominantly empirical field to one where it is possible to control the catalytic properties via characterization and modification of the atomic-scale active centers. Many phenomena in catalysis, such as synergistic effect, however, transcend the atomic scale and also require the knowledge and control of the mesoscale structure of the specimen to harness. In this paper, we use our discovery of atomic-scale epitaxial interfaces in molybdenum vanadium based complex oxide catalysts systems (i.e., MoVMO, M = Ta, Te, Sb, Nb, etc.) to achieve control of the mesoscale structure of this complex mixture of very different active phases. We can now achieve true epitaxial intergrowth between the catalytically critical M1 and M2 phases in the system that are hypothesized to have synergistic interactions, and demonstrate that the resulting catalyst has improved selectivity in the initial studies. Finally, we highlight the crucial role atomic scale characterization and mesoscale structure control play in uncovering the complex underpinnings of the synergistic effect in catalysis.

  8. Evaluation of ferritic alloy Fe-2-1/4Cr-1Mo after neutron irradiation - microstructure development

    SciTech Connect (OSTI)

    Gelles, D.S.

    1984-05-01

    Microstructural examinations are reported for nine specimen conditions of 2-1/4Cr-1Mo steel which had been irradiated by fast neutrons over the temperature range 390 to 510/sup 0/C. Two heats of material were involved, each with a different preirradiation heat treatment, one irradiated to a peak fluence of 5.1 x 10/sup 22/ n/cm/sup 2/ (E > 0.1 MeV) or 24 dpa and the other to 2.4 x 10/sup 23/ n/cm/sup 2/ (E > 0.1 MeV) or 116 dpa. Void swelling is found following irradiation at 400/sup 0/C in both conditions and to 480/sup 0/C in the higher fluence conditions. Concurrently dislocation structure and precipitation formed. Peak void swelling, void density, dislocation density and precipitate number density developed at the lowest temperature, approx. 400/sup 0/C, whereas mean void size, and mean precipitate size increased with increasing irradiation temperature. The examination results are used to provide interpretation of in-reactor creep, density change and post irradiation tensile behavior.

  9. Twisted MoSe2 bilayers with variable local stacking and interlayer coupling revealed by low-frequency Raman spectroscopy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Puretzky, Alexander A.; Liang, Liangbo; Li, Xufan; Xiao, Kai; Sumpter, Bobby G.; Meunier, Vincent; Geohegan, David B.

    2016-01-14

    Unique twisted bilayers of MoSe2 with multiple stacking orientations and interlayer couplings in the narrow range of twist angles, 60 ± 3°, are revealed by low-frequency Raman spectroscopy and theoretical analysis. The slight deviation from 60 allows the concomitant presence of patches featuring all three high-symmetry stacking configurations (2H or AA', AB', A'B) in one unique bilayer system. In this case, the periodic arrangement of the patches and their size strongly depend on the twist angle. Ab initio modeling predicts significant changes in frequencies and intensities of low-frequency modes versus stacking and twist angle. Experimentally, the variable stacking and couplingmore » across the interface is revealed by the appearance of two breathing modes corresponding to the mixture of the high-symmetry stacking configurations and unaligned regions of monolayers. Only one breathing mode is observed outside the narrow range of twist angles. This indicates a stacking transition to unaligned monolayers with mismatched atom registry without the in-plane restoring force required to generate a shear mode. As a result, the variable interlayer coupling and spacing in transition metal dichalcogenide bilayers revealed in this study may provide a new platform for optoelectronic applications of these materials.« less

  10. Microstructure investigation of 13Cr-2Mo ODS steel components obtained by high voltage electric discharge compaction technique

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bogachev, Igor; Yudin, Artem; Grigoryev, Evgeniy; Chernov, Ivan; Staltsov, Maxim; Khasanov, Oleg; Olevsky, Eugene

    2015-11-02

    Refractory oxide dispersion strengthened 13Cr-2Mo steel powder was successfully consolidated to near theoretical density using high voltage electric discharge compaction. Cylindrical samples with relative density from 90% to 97% and dimensions of 10 mm in diameter and 10–15 mm in height were obtained. Consolidation conditions such as pressure and voltage were varied in some ranges to determine the optimal compaction regime. Three different concentrations of yttria were used to identify its effect on the properties of the samples. It is shown that the utilized ultra-rapid consolidation process in combination with high transmitted energy allows obtaining high density compacts, retaining themore » initial structure with minimal grain growth. The experimental results indicate some heterogeneity of the structure which may occur in the external layers of the tested samples due to various thermal and electromagnetic in-processing effects. As a result, the choice of the optimal parameters of the consolidation enables obtaining samples of acceptable quality.« less

  11. Adsorption of propane, isopropyl, and hydrogen on cluster models of the M1 phase of Mo-V-Te-Nb-O mixed metal oxide catalyst

    SciTech Connect (OSTI)

    Govindasamy, Agalya; Muthukumar, Kaliappan; Yu, Junjun; Xu, Ye; Guliants, Vadim V.

    2010-01-01

    The Mo-V-Te-Nb-O mixed metal oxide catalyst possessing the M1 phase structure is uniquely capable of directly converting propane into acrylonitrile. However, the mechanism of this complex eight-electron transformation, which includes a series of oxidative H-abstraction and N-insertion steps, remains poorly understood. We have conducted a density functional theory study of cluster models of the proposed active and selective site for propane ammoxidation, including the adsorption of propane, isopropyl (CH{sub 3}CHCH{sub 3}), and H which are involved in the first step of this transformation, that is, the methylene C-H bond scission in propane, on these active site models. Among the surface oxygen species, the telluryl oxo (Te=O) is found to be the most nucleophilic. Whereas the adsorption of propane is weak regardless of the MO{sub x} species involved, isopropyl and H adsorption exhibits strong preference in the order of Te=O > V=O > bridging oxygens > empty Mo apical site, suggesting the importance of TeO{sub x} species for H abstraction. The adsorption energies of isopropyl and H and consequently the reaction energy of the initial dehydrogenation of propane are strongly dependent on the number of ab planes included in the cluster, which points to the need to employ multilayer cluster models to correctly capture the energetics of surface chemistry on this mixed metal oxide catalyst.

  12. Low-field magnetoresistance up to 400 K in double perovskite Sr{sub 2}FeMoO{sub 6} synthesized by a citrate route

    SciTech Connect (OSTI)

    Harnagea, L.; Jurca, B.; Berthet, P.

    2014-03-15

    A wet-chemistry technique, namely the citrate route, has been used to prepare high-quality polycrystalline samples of double perovskite Sr{sub 2}FeMoO{sub 6}. We report on the evolution of magnetic and magnetoresistive properties of the synthesized samples as a function of three parameters (i) the pH of the starting solution, (ii) the decomposition temperature of the citrate precursors and (iii) the sintering conditions. The low-field magnetoresistance (LFMR) value of our best samples is as high as 5% at room temperature for an applied magnetic field of 1 kOe. Additionally, the distinguishing feature of these samples is the persistence of LFMR, with a reasonably large value, up to 400 K which is a crucial parameter for any practical application. Our study indicates that the enhancement of LFMR observed is due to a good compromise between the grain size distribution and their magnetic polarization. -- Graphical abstract: The microstructure (left panel) and corresponding low-field magnetoresistance of one of the Sr{sub 2}FeMoO{sub 6} samples synthesized in the course of this work. Highlights: Samples of Sr{sub 2}FeMoO{sub 6} are prepared using a citrate route under varying conditions. Magnetoresistive properties are improved and optimized. Low-field magnetoresitence values as large as 5% at 300 K/1 kOe are reported. Persistence of low-field magnetoresistance up to 400 K.

  13. A study of nitrogenation of a NdFe{sub 12-x}Mo{sub x} compound by in situ neutron powder diffraction.

    SciTech Connect (OSTI)

    Ding, Y.; Lin, J.; Loong, C.-K.; Short, S. M.

    1997-11-18

    The effects on the crystal lattice of a NdFe{sub 12{minus}x}Mo{sub x}(x {approx_equal} 1.7) compound which contained {approximately}12 vol% of bcc-Fe were studied by neutron powder diffraction during controlled nitrogenation over the 25-600 C temperature range. The sample inside the furnace was connected to a closed volume of ultra-pure nitrogen gas while neutron data were collected over regular time intervals during sequential heating. Substantial nitrogen absorption occurred between 500 to 600 C. During the nitrogenation process the NdFe{sub 12{minus}x}Mo{sub x}N{sub y} lattice expanded while the bcc-Fe lattice contracted. An increasing decomposition of the compound into bcc-Fe at 600 C was observed. The average size of the NdFe{sub 12{minus}x}Mo{sub x}N{sub y} crystalline grains decreased starting at {approximately}300 C, reaching a minimum at {approximately}500 C and then increased markedly at higher temperatures. The development of lattice strains, on the other hand, showed an opposite trend, i.e., a maximum at 500 C. A correlation of structural modification of the crystalline phases and the nitrogenation process is discussed.

  14. Nanoscale Phase Separation In Epitaxial Cr-Mo and Cr-V Alloy Thin Films Studied Using Atom Probe Tomography: Comparison Of Experiments And Simulation

    SciTech Connect (OSTI)

    Devaraj, Arun; Kaspar, Tiffany C.; Ramanan, Sathvik; Walvekar, Sarita K.; Bowden, Mark E.; Shutthanandan, V.; Kurtz, Richard J.

    2014-11-21

    Tailored metal alloy thin film-oxide interfaces generated using molecular beam epitaxial (MBE) deposition of alloy thin films on a single crystalline oxide substrate can be used for detailed studies of irradiation damage response on the interface structure. However presence of nanoscale phase separation in the MBE grown alloy thin films can impact the metal-oxide interface structure. Due to nanoscale domain size of such phase separation it is very challenging to characterize by conventional techniques. Therefor laser assisted atom probe tomography (APT) was utilized to study the phase separation in epitaxial Cr0.61Mo0.39, Cr0.77Mo0.23, and Cr0.32V0.68 alloy thin films grown by MBE on MgO(001) single crystal substrates. Statistical analysis, namely frequency distribution analysis and Pearson coefficient analysis of experimental data was compared with similar analyses conducted on simulated APT datasets with known extent of phase separation. Thus the presence of phase separation in Cr-Mo films, even when phase separation was not clearly observed by x-ray diffraction, and the absence of phase separation in the Cr-V film were thus confirmed.

  15. Nanoscale phase separation in epitaxial Cr-Mo and Cr-V alloy thin films studied using atom probe tomography: Comparison of experiments and simulation

    SciTech Connect (OSTI)

    Devaraj, A.; Ramanan, S.; Walvekar, S.; Bowden, M. E.; Shutthanandan, V.; Kaspar, T. C.; Kurtz, R. J.

    2014-11-21

    Tailored metal alloy thin film-oxide interfaces generated using molecular beam epitaxy (MBE) deposition of alloy thin films on a single crystalline oxide substrate can be used for detailed studies of irradiation damage response on the interface structure. However, the presence of nanoscale phase separation in the MBE grown alloy thin films can impact the metal-oxide interface structure. Due to nanoscale domain size of such phase separation, it is very challenging to characterize by conventional techniques. Therefore, laser assisted atom probe tomography (APT) was utilized to study the phase separation in epitaxial Cr{sub 0.61}Mo{sub 0.39}, Cr{sub 0.77}Mo{sub 0.23}, and Cr{sub 0.32}V{sub 0.68} alloy thin films grown by MBE on MgO(001) single crystal substrates. Statistical analysis, namely frequency distribution analysis and Pearson coefficient analysis of experimental data was compared with similar analyses conducted on simulated APT datasets with known extent of phase separation. Thus, the presence of phase separation in Cr-Mo films, even when phase separation was not clearly observed by x-ray diffraction, and the absence of phase separation in the Cr-V film were confirmed.

  16. Propane ammoxidation over the Mo-V-Te-Nb-O M1 phase: Reactivity of surface cations in hydrogen abstraction steps

    SciTech Connect (OSTI)

    Muthukumar, Kaliappan; Yu, Junjun; Xu, Ye; Guliants, Vadim V.

    2011-01-01

    Density functional theory calculations (GGA-PBE) have been performed to investigate the adsorption of C3 (propane, isopropyl, propene, and allyl) and H species on the proposed active center present in the surface ab planes of the bulk Mo-V-Te-Nb-O M1 phase in order to better understand the roles of the different surface cations in propane ammoxidation. Modified cluster models were employed to isolate the closely spaced V=O and Te=O from each other and to vary the oxidation state of the V cation. While propane and propene adsorb with nearly zero adsorption energy, the isopropyl and allyl radicals bind strongly to V=O and Te=O with adsorption energies, {Delta}E, being {le} -1.75 eV, but appreciably more weakly on other sites, such as Mo=O, bridging oxygen (Mo-O-V and Mo-O-Mo), and empty metal apical sites ({Delta}E > -1 eV). Atomic H binds more strongly to Te = O ({Delta}E {le} -3 eV) than to all the other sites, including V = O ({Delta}E = -2.59 eV). The reduction of surface oxo groups by dissociated H and their removal as water are thermodynamically favorable except when both H atoms are bonded to the same Te=O. Consistent with the strong binding of H, Te=O is markedly more active at abstracting the methylene H from propane (E{sub a} {le} 1.01 eV) than V = O (E{sub a} = 1.70 eV on V{sup 5+} = O and 2.13 eV on V{sup 4+} = O). The higher-than-observed activity and the loose binding of Te = O moieties to the mixed metal oxide lattice of M1 raise the question of whether active Te = O groups are in fact present in the surface ab planes of the M1 phase under propane ammoxidation conditions.

  17. Chemical relationship between discharging fluids in the Siena-Radicofani Graben and the deep fluids produced by the geothermal fields of Mt Amiata, torre Afina and Latera (Central Italy)

    SciTech Connect (OSTI)

    Duchi, V.; Paolieri, M.; Prati, F ); Minissale, A. Centro di Studio per Mineralogia e la Geochimica dei Sedimenti, Via La Pira 4, 50121 Firenze ); Valori, A )

    1992-06-01

    This paper reports that the thermal springs discharging in the Siena-Radicofani basin and the deep fluids within the geothermal systems of Piancastagnaio (Mt Amiata), Torre Alfina and Latera (Vulsini Mts) have a common origin. The chemical composition and evolution towards the low enthalpy of the springs as compared to the high enthalpy of the geothermal fluids are affected by both the structural setting of the region and the deep hydraulic conditions. Recharge of both the shallow thermal aquifer and the deep geothermal systems takes place in the outcrop areas of Mesozoic carbonate rocks, which constitute the main potential geothermal reservoir in central Italy. The waters of meteoric origin are heated at depth, as a consequence of anomalous heat flow in the region; these waters acquire a CO[sub 2]-rich rising gas phase, equilibrate with the reservoir rocks and, finally, assume their Ca--HCO[sub 3]--SO[sub 4] composition. If these waters discharge rapidly from the border fault systems of the Siena-Radicofani basin they maintain their original composition. If, instead, they emerge from the inner faults of the graben, their temperature and dissolved solids increase so that they become Na--Cl with a high content of NH[sub 4], and H[sub 3]BO[sub 3].

  18. NaYF{sub 4}:Er,Yb/Bi{sub 2}MoO{sub 6} core/shell nanocomposite: A highly efficient visible-light-driven photocatalyst utilizing upconversion

    SciTech Connect (OSTI)

    Sun, Yuanyuan; Wang, Wenzhong Sun, Songmei; Zhang, Ling

    2014-04-01

    Highlights: Design and synthesis of NaYF{sub 4}:Er,Yb/Bi{sub 2}MoO{sub 6} based on upconversion. NaYF{sub 4}:Er,Yb/Bi{sub 2}MoO{sub 6} nanocomposite was prepared for the first time. Coreshell structure benefits the properties. Upconversion contributed to the enhanced photocatalytic activity. Helps to understand the functionality of new type photocatalysts. - Abstract: NaYF{sub 4}:Er,Yb/Bi{sub 2}MoO{sub 6} core/shell nanocomposite was designed and prepared for the first time based on upconversion. The products were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), high resolution TEM (HRTEM), energy dispersive X-ray spectroscopy (EDS) and diffuse reflectance spectra (DRS). The results revealed that the as-synthesized NaYF{sub 4}:Er,Yb/Bi{sub 2}MoO{sub 6} consisted of spheres with a core diameter of about 26 nm and a shell diameter of around 6 nm. The core was upconversion illuminant NaYF{sub 4}:Er,Yb and the shell was Bi{sub 2}MoO{sub 6} around the core, which was confirmed by EDS. The NaYF{sub 4}:Er,Yb/Bi{sub 2}MoO{sub 6} exhibited higher photocatalytic activity for the photodecomposition of Rhodamine B (RhB) under the irradiation of Xe lamp and green light emitting diode (g-LED). The mechanism of the high photocatalytic activity was discussed by photoluminescence spectra (PL), which is mainly attributed to upconversion of NaYF{sub 4}:Er,Yb in the NaYF{sub 4}:Er,Yb/Bi{sub 2}MoO{sub 6} nanocomposite and the coreshell structure.

  19. The carburization of transition metal molybdates (MxMoO₄, M= Cu, Ni or Co) and the generation of highly active metal/carbide catalysts for CO₂ hydrogenation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Rodriguez, Jose A.; Xu, Wenqian; Ramirez, Pedro J.; Stachiola, Dario; Brito, Joaquin L.

    2015-05-06

    A new approach has been tested for the preparation of metal/Mo₂C catalysts using mixed-metal oxide molybdates as precursors. Synchrotron-based in situ time-resolved X-ray diffraction was used to study the reduction and carburization processes of Cu₃(MoO₄)₂(OH)₂, a-NiMoO₄ and CoMoO₄•nH₂O by thermal treatment under mixtures of hydrogen and methane. In all cases, the final product was β-Mo₂C and a metal phase (Cu, Ni, or Co), but the transition sequence varied with the different metals, and it could be related to the reduction potential of the Cu²⁺, Ni²⁺ and Co²⁺ cations inside each molybdate. The synthesized Cu/Mo₂C, Ni/Mo₂C and Co/Mo₂C catalysts were highlymore » active for the hydrogenation of CO₂. The metal/Mo₂C systems exhibited large variations in the selectivity towards methanol, methane and CnH₂n₊₂ (n > 2) hydrocarbons depending on the nature of the supported metal and its ability to cleave C-O bonds. Cu/Mo₂C displayed a high selectivity for CO and methanol production. Ni/Mo₂C and Co/Mo₂C were the most active catalysts for the activation and full decomposition of CO₂, showing high selectivity for the production of methane (Ni case) and CnH₂n₊₂ (n > 2) hydrocarbons (Co case).« less

  20. Using Qualified Energy Conservation Bonds (QECBs) to Fund a Residential Energy Efficiency Loan Program: Case Study on Saint Louis County, MO

    SciTech Connect (OSTI)

    Zimring, Mark

    2011-06-23

    Qualified Energy Conservation Bonds (QECBs) are federally-subsidized debt instruments that enable state, tribal, and local government issuers to borrow money to fund a range of qualified energy conservation projects. QECBs offer issuers very attractive borrowing rates and long terms, and can fund low-interest energy efficiency loans for home and commercial property owners. Saint Louis County, MO recently issued over $10 million of QECBs to finance the Saint Louis County SAVES residential energy efficiency loan program. The county's experience negotiating QECB regulations and restrictions can inform future issuers.

  1. Characterization of fundamental catalytic properties of MoS2/WS2 nanotubes and nanoclusters for desulfurization catalysis - a surface temperature study

    SciTech Connect (OSTI)

    U. Burghaus

    2012-07-05

    The prior project consisted of two main project lines. First, characterization of novel nanomaterials for hydrodesulfurization (HDS) applications. Second, studying more traditional model systems for HDS such as vapor-deposited silica-supported Mo and MoSx clusters. In the first subproject, we studied WS2 and MoS2 fullerene-like nanoparticles as well as WS2 nanotubes. Thiophene (C4H4S) was used as the probe molecule. Interestingly, metallic and sulfur-like adsorption sites could be identified on the silica-supported fullerene-particles system. Similar structures are seen for the traditional system (vapor-deposited clusters). Thus, this may be a kinetics fingerprint feature of modern HDS model systems. In addition, kinetics data allowed characterization of the different adsorption sites for thiophene on and inside WS2 nanotube bundles. The latter is a unique feature of nanotubes that has not been reported before for any inorganic nanotube system; however, examples are known for carbon nanotubes, including prior work of the PI. Although HDS has been studied for decades, utilizing nanotubes as nanosized HDS reactors has never been tried before, as far as we know. This is of interest from a fundamental perspective. Unfortunately, the HDS activity of the nanocatalysts at ultra-high vacuum (UHV) conditions was close to the detection limit of our techniques. Therefore, we propose to run experiments at ambient pressure on related nanopowder samples as part of the renewal application utilizing a now-available GC (gas chromatograph) setup. In addition, Ni and Co doped nanocatalyts are proposed for study. These dopants will boost the catalytic activity. In the second subproject of the prior grant, we studied HDS-related chemistry on more traditional supported cluster catalysts. Mo clusters supported by physical vapor deposition (PVD) on silica have been characterized. Two reaction pathways are evident when adsorbing thiophene on Mo and MoSx clusters: molecular adsorption and dissociation. PVD Mo clusters turned out to be very reactive toward thiophene bond activation. Sulfur and carbon residuals form, which poison the catalyst and sulfide the Mo clusters. Sulfided silica-supported MoSx samples are not reactive toward thiophene bond activation. In addition to S and C deposits, H2, H2S, and small organic molecules were detected in the gas phase. Catalyst reactivation procedures, including O2 and atomic hydrogen treatments, have been tested. Cluster size effects have been seen: thiophene adsorbs molecularly with larger binding energies on smaller clusters. However, larger clusters have smaller activation energy for C4H4S bond activation than smaller clusters. The latter is consistent with early catalysis studies. Kinetics and dynamics parameters have been determined quantitatively. We spent a significant amount of time on upgrades of our equipment. A 2nd-hand refurbished X-ray photoelectron spectrometer (XPS) has been integrated into the existing molecular beam scattering system and is already operational (supported by the DoE supplemental grant available in October 2009). We also added a time of flight (TOF) system to the beam scattering apparatus and improved on the accessible impact energy range (new nozzle heater and gas mixing manifold) for the beam scattering experiments. In addition, a GC-based powder atmospheric flow reactor for studies on powder samples is now operational. Furthermore, a 2nd UHV kinetics system has been upgraded as well. In summary, mostly single crystal systems have so far been considered in basic science studies about HDS. Industrial catalysts, however, can be better approximated with the supported cluster systems that we studied in this project. Furthermore, an entirely new class of HDS systems, namely fullerene-like particles and inorganic nanotubes, has been included. Studying new materials and systems has the potential to impact science and technology. The systems investigated are closely related to energy and environmental-related surface science/catalysis. This prior project, conducted at NDSU by a sma

  2. Superconducting nanowire single photon detectors fabricated from an amorphous Mo{sub 0.75}Ge{sub 0.25} thin film

    SciTech Connect (OSTI)

    Verma, V. B.; Lita, A. E.; Vissers, M. R.; Marsili, F.; Pappas, D. P.; Mirin, R. P.; Nam, S. W.

    2014-07-14

    We present the characteristics of superconducting nanowire single photon detectors (SNSPDs) fabricated from amorphous Mo{sub 0.75}Ge{sub 0.25} thin-films. Fabricated devices show a saturation of the internal detection efficiency at temperatures below 1?K, with system dark count rates below 500 cps. Operation in a closed-cycle cryocooler at 2.5?K is possible with system detection efficiencies exceeding 20% for SNSPDs which have not been optimized for high detection efficiency. Jitter is observed to vary between 69 ps at 250 mK and 187 ps at 2.5?K using room temperature amplifiers.

  3. Overview of 2007 ANL progress for conversion of HEU- based Mo-99 production as part of the U.S. global threat reduction--conversion program

    SciTech Connect (OSTI)

    Vandegrift, George F.; Bakel, Allen J.; Thomas, Justin W.

    2008-07-15

    ANL effort is divided into five areas: (1) cooperation with Argentina to demonstrate the use of LEU-foil targets in alkaline-based processes, (2) cooperation with Indonesia in converting their HEU-based Cintichem process to LEU-foil targets, (3) technical assistance to two potential U.S. domestic suppliers (MURR and BWTX), (4) responding to the National Academies Study, and (5) participation in the IAEA CRP for Indigenous Mo-99 production. This paper presents highlights of these activities. A short description of how the dose emitted by spent HEU target material compared to spent fuel is also included. (author)

  4. Overview of 2007 ANL progress for conversion of HEU-based Mo-99 production as part of the U.S. Global Threat Reduction--Conversion program.

    SciTech Connect (OSTI)

    Vandegrift, G. F.; Bakel, A. J.; Thomas, J. W.

    2007-01-01

    ANL effort is divided into five areas: (1) cooperation with Argentina to demonstrate the use of LEU-foil targets in alkaline-based processes, (2) cooperation with Indonesia in converting their HEU-based Cintichem process to LEU-foil targets, (3) technical assistance to two potential U.S. domestic suppliers (MURR and BWTX), (4) responding to the National Academies Study, and (5) participation in the IAEA CRP for Indigenous Mo-99 production. This paper presents highlights of these activities. A short description of how the dose emitted by spent HEU target material compared to spent fuel is also included.

  5. M&O

    National Nuclear Security Administration (NNSA)

    Security Administration (NNSA) today announced the award to Honeywell Federal Manufacturing and Technologies, LLC, to be the management and operating contractor for the...

  6. Mo#va#on

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    = a n i nherent l imita#ons of both: h ot & c old f usion r eac#ons: Hot (well--- d eformed r adioac1ve ac1nides ( Act.) t argets a re u sed a nd compound n ucleus i s q uite e xcited ) * a8empts o f g oing b eyond the r eac#ons A ct. + 48 Ca b y using h eavier p rojec#les l ike 50 Ti, 54 Cr, 58 Fe, a nd 64 Ni gave n o r esults s o f ar. * all h eavier a c#nides w ith Z>98 l ive t o s hort t hat o ne could p erform t arget w ith them. Cold ( magic n uclei a s t argets a re u sed w ith

  7. MoS2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    a decline in air quality worldwide. A recent New York Times article described the major impact a growing Chinese economy will have on sulfur pollution causing an increase in acid...

  8. Effective hole extraction using MoO{sub x}-Al contact in perovskite CH{sub 3}NH{sub 3}PbI{sub 3} solar cells

    SciTech Connect (OSTI)

    Zhao, Yixin; Nardes, Alexandre M.; Zhu, Kai

    2014-05-26

    We report an 11.4%-efficient perovskite CH{sub 3}NH{sub 3}PbI{sub 3} solar cell using low-cost molybdenum oxide/aluminum (i.e., MoO{sub x}/Al) as an alternative top contact to replace noble/precious metals (e.g., Au or Ag) for extracting photogenerated holes. The device performance of perovskite solar cells using a MoO{sub x}/Al top contact is comparable to that of cells using the standard Ag top contact. Analysis of impedance spectroscopy measurements suggests that using 10-nm-thick MoO{sub x} and Al does not affect charge-recombination properties of perovskite solar cells. Using a thicker (20-nm) MoO{sub x} layer leads to a lower cell performance caused mainly by a reduced fill factor. Our results suggest that MoO{sub x}/Al is promising as a low-cost and effective hole-extraction contact for perovskite solar cells.

  9. Mt Signal Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    135C408.15 K 275 F 734.67 R 1 USGS Estimated Reservoir Volume: 3 km 1 USGS Mean Capacity: 15 MW 1 Click "Edit With Form" above to add content History and...

  10. Marysville Mt Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    Volume: Mean Capacity: USGS Mean Reservoir Temp: USGS Estimated Reservoir Volume: USGS Mean Capacity: Click "Edit With Form" above to add content History and Infrastructure...

  11. Mt Rainier Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    -121.75128794312 Resource Estimate Mean Reservoir Temp: Estimated Reservoir Volume: Mean Capacity: USGS Mean Reservoir Temp: USGS Estimated Reservoir Volume: USGS Mean...

  12. Marysville Mt Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    GEA Development Phase: Resource Estimate Mean Reservoir Temp: Estimated Reservoir Volume: Mean Capacity: USGS Mean Reservoir Temp: USGS Estimated Reservoir Volume: USGS Mean...

  13. Controlled Source Audio MT | Open Energy Information

    Open Energy Info (EERE)

    Telluric Survey Time-Domain Electromagnetics Self Potential Field Procedures The signal for a CSAMT survey is artificially generated through the installation of a long...

  14. Havre, MT Natural Gas Exports to Canada

    Gasoline and Diesel Fuel Update (EIA)

    1998 1999 2000 2001 2002 2003 View History Pipeline Volumes NA NA 1,309 NA NA 0 1998-2003 Pipeline Prices NA NA 3.66 NA NA -- 1998-2003

  15. Havre, MT Natural Gas Exports to Canada

    Gasoline and Diesel Fuel Update (EIA)

    9,437 6,806 4,331 2,160 680 3 1998-2015 Pipeline Prices 4.05 3.82 2.40 3.09 4.22 2.30 1998

  16. Babb, MT Natural Gas Export to Canada

    Gasoline and Diesel Fuel Update (EIA)

    6,671 12,807 15,525 17,235 17,421 20,708 1996-2015 Pipeline Prices 3.86 3.98 2.47 3.13 4.05 2.34 1996

  17. Babb, MT Natural Gas Export to Canada

    Gasoline and Diesel Fuel Update (EIA)

    0 20 0 0 122 1996-2014 Pipeline Prices -- 3.39 -- -- 4.90 1996-2014 Liquefied Natural Gas Volumes 5 2015-2015 Liquefied Natural Gas Prices 12.95 2015

  18. Mt Rainier Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    and Environmental Issues Click "Edit With Form" above to add content Exploration History First Discovery Well Completion Date: Well Name: Location: Depth: Initial Flow...

  19. Structures, Mechanisms, and Kinetics of Ammoxidation and Selective Oxidation of Propane Over the M2 Phase of MoVNbTeO Catalysts

    SciTech Connect (OSTI)

    Goddard, William A.; Liu, Lianchi; Mueller, Jonathan E.; Pudar, Sanja; Nielsen, Robert J.

    2011-05-04

    We report here first-principles-based predictions of the structures, mechanisms, and activation barriers for propane activation by the M2 phase of the MoVNbTeO multi-metal oxide catalysts capable of the direct conversion of propane to acrylonitrile. Our approach is to combine extensive quantum mechanical (QM) calculations to establish the mechanisms for idealized representations of the surfaces for these catalytic systems and then to modify the parameters in the ReaxFF reactive force field for molecular dynamics (MD) calculations to describe accurately the activation barriers and reaction mechanisms of the chemical reactions over complex mixed metal oxides. The parameters for ReaxFF are derived entirely from QM without the use of empirical data so that it can be applied to novel systems on which there is little or no data. To understand the catalysis in these systems it is essential to determine the surface structures that control the surface chemistry. High quality three-dimensional (3D) Rietveld structures are now available for the M1 and M2 phases of the MoVNbTeO catalysts.

  20. Neutron Diffraction Measurement of Residual Stresses, Dislocation Density and Texture in Zr-bonded U-10Mo ''Mini'' Fuel Foils and Plates

    SciTech Connect (OSTI)

    Brown, Donald W.; Okuniewski, M. A.; Sisneros, Thomas A.; Clausen, Bjorn; Moore, G. A.; Balogh, L

    2014-08-07

    Aluminum clad monolithic uranium 10 weight percent molybdenum (U-10Mo) fuel plates are being considered for conversion of several research and test nuclear reactors from high-enriched to low-enriched uranium fuel due to the inherently high density of fissile material. Comprehensive neutron diffraction measurements of the evolution of the textures, residual phase stresses, and dislocation densities in the individual phases of the mini-foils throughout several processing steps and following hot-isostatic pressing to the Al cladding, have been completed. Recovery and recrystallization of the bare U-10Mo fuel foil, as indicated by the dislocation density and texture, are observed depending on the state of the material prior to annealing and the duration and temperature of the annealing process. In general, the HIP procedure significantly reduces the dislocation density, but the final state of the clad plate, both texture and dislocation density, depends strongly on the final processing step of the fuel foil. In contrast, the residual stresses in the clad fuel plate do not depend strongly on the final processing step of the bare foil prior to HIP bonding. Rather, the residual stresses are dominated by the thermal expansion mismatch of the constituent materials of the fuel plate.

  1. Evaluation of 2.25Cr-1Mo Alloy for Containment of LiCl/KCl Eutectic during the Pyrometallurgical Processing of Used Nuclear Fuel

    SciTech Connect (OSTI)

    B.R. Westphal; S.X. Li; G.L. Fredrickson; D. Vaden; T.A. Johnson; J.C. Wass

    2011-03-01

    Recovery of uranium from the Mk-IV and Mk-V electrorefiner vessels containing a LiCl/KCl eutectic salt has been on-going for 14 and 12 years, respectively, during the pyrometallurgical processing of used nuclear fuel. Although austenitic stainless steels are typically utilized for LiCl/KCl salt systems, the presence of cadmium in the Mk-IV electrorefiner dictates an alternate material. A 2.25Cr-1Mo alloy (ASME SA-387) was chosen due to the absence of nickel in the alloy which has a considerable solubility in cadmium. Using the transition metal impurities (iron, chromium, nickel, molybdenum, and manganese) in the electrorefined uranium products, an algorithm was developed to derive values for the contribution of the transition metals from the various input sources. Weight loss and corrosion rate data for the Mk-V electrorefiner vessel were then generated based on the transition metal impurities in the uranium products. To date, the corrosion rate of the 2.25Cr-1Mo alloy in LiCl/KCl eutectic is outstanding assuming uniform (i.e. non-localized) conditions.

  2. Microstructural evolution of U(Mo)Al(Si) dispersion fuel under irradiation Destructive analyses of the LEONIDAS E-FUTURE plates

    SciTech Connect (OSTI)

    A. Leenaers; S. Van den Berghe; J. Van Eyken; E. Koonen; F. Charollais; P. Lemoine; Y. Calzavara; H. Guyon; C. Jarousse; D. Geslin; D. Wachs; D. Keiser; A. Robinson; G. Hofman; Y. S. Kim

    2013-10-01

    Several irradiation experiments have confirmed the positive effect of adding Si to the matrix of an U(Mo) dispersion fuel plate on its in-pile irradiation behavior. E-FUTURE, the first experiment of the LEONIDAS program, was performed to select an optimum Si concentration and fuel plate heat treatment parameters for further qualification. It consisted of the irradiation of 4 distinct (regarding Si content and heat treatments), full size flat fuel plates in the BR2 reactor under bounding conditions (470 W/cm2 peak BOL power, approximately 70% peak burn-up). After the irradiation, the E-FUTURE plates were examined non-destructively and found to have pillowed in the highest burn-up positions. The destructive post-irradiation examination confirmed that the fuel evolves in a stable way up to a burn-up of 60%235U. Even in the deformed area (pillow) the U(Mo) fuel itself shows stable behavior and remaining matrix material was present. From the calculation of the volume fractions, the positive effect of a higher Si amount added to the matrix and the higher annealing temperature can be derived.

  3. Demonstration Assessment of Light-Emitting Diode (LED) Parking Lot Lighting in Leavenworth, KS

    SciTech Connect (OSTI)

    Myer, Michael; Kinzey, Bruce R.; Curry, Ku'uipo

    2011-05-06

    This report describes the process and results of a demonstration of solid-state lighting (SSL) technology in a commercial parking lot lighting application, under the U.S. Department of Energy (DOE) Solid-State Lighting Technology GATEWAY Demonstration Program. The parking lot is for customers and employees of a Walmart Supercenter in Leavenworth, Kansas and this installation represents the first use of the LED Parking Lot Performance Specification developed by the DOE’s Commercial Building Energy Alliance. The application is a parking lot covering more than a half million square feet, lighted primarily by light-emitting diodes (LEDs). Metal halide wall packs were installed along the building facade. This site is new construction, so the installed baseline(s) were hypothetical designs. It was acknowledged early on that deviating from Walmart’s typical design would reduce the illuminance on the site. Walmart primarily uses 1000W pulse-start metal halide (PMH) lamps. In order to provide a comparison between both typical design and a design using conventional luminaires providing a lower illuminance, a 400W PMH design was also considered. As mentioned already, the illuminance would be reduced by shifting from the PMH system to the LED system. The Illuminating Engineering Society of North America (IES) provides recommended minimum illuminance values for parking lots. All designs exceeded the recommended illuminance values in IES RP-20, some by a wider margin than others. Energy savings from installing the LED system compared to the different PMH systems varied. Compared to the 1000W PMH system, the LED system would save 63 percent of the energy. However, this corresponds to a 68 percent reduction in illuminance as well. In comparison to the 400W PMH system, the LED system would save 44 percent of the energy and provide similar minimum illuminance values at the time of relamping. The LED system cost more than either of the PMH systems when comparing initial costs. However, when the life-cycle costs from energy and maintenance were factored into the scenario, the LED system had lower costs at the end of a 10-year analysis period. The LED system had a 6.1 year payback compared to the 1000W PMH system and a 7.5 year payback versus the 400W PMH system. The costs reflect high initial cost for the LED luminaire, plus more luminaires and (subsequently) more poles for the LED system. The other major issue affecting cost effectiveness was that Leavenworth, Kansas has very low electricity costs. The melded rate for this site was $0.056 per kWh for electricity. However, if the national electricity rate of $0.1022/kWh was used the payback would change to between four and five years for the LED system. This demonstration met the GATEWAY requirements of saving energy, matching or improving illumination, and being cost effective. The project also demonstrated that the Commercial Building Energy Alliance (CBEA) specification works in practice. Walmart appreciated having an entire site lighted by LEDs to gain more experience with the technology. Walmart is reviewing the results of the demonstration as they consider their entire real estate portfolio.

  4. Cancer Facts & Figures - 2010

    National Nuclear Security Administration (NNSA)

    AL 23,640 AZ 29,780 AR 15,320 CA 157,320 CO 21,340 CT 20,750 DE 4,890 FL 107,000 GA 40,480 ID 7,220 IL 63,890 IN 33,020 IA 17,260 KS 13,550 KY 24,240 LA 20,950 ME 8,650 MD 27,700 MA 36,040 MN 25,080 MS 14,330 MO 31,160 MT 5,570 NE 9,230 NV 12,230 NH 7,810 NJ 48,100 NM 9,210 NY 103,340 NC 45,120 ND 3,300 OH 64,450 OK 18,670 OR 20,750 PA 75,260 RI 5,970 SC 23,240 SD 4,220 TN 33,070 TX 101,120 UT 9,970 VT 3,720 VA 36,410 WA 34,500 WV 10,610 WI 29,610 WY 2,540 DC 2,760 HI 6,670 AK 2,860 MI 55,660 PR

  5. Room-temperature thermally induced relaxation effect in a two-dimensional cyano-bridged Cu-Mo bimetal assembly and thermodynamic analysis of the relaxation process

    SciTech Connect (OSTI)

    Umeta, Yoshikazu; Ozaki, Noriaki; Tokoro, Hiroko; Ohkoshi, Shin-ichi

    2013-04-15

    We observed a photo-switching effect in [Cu{sup II}(1,4,8,11-tetraazacyclodecane)]{sub 2}[Mo{sup IV}(CN){sub 8}]{center_dot}10H{sub 2}O by irradiation with 410-nm light around room temperature using infrared spectroscopy. This photo-switching is caused by the photo-induced charge transfer from Mo{sup IV} to Cu{sup II}. The photo-induced phase thermally relaxed to the initial phase with a half-life time of 2.7 Multiplication-Sign 10{sup 1}, 6.9 Multiplication-Sign 10{sup 1}, and 1.7 Multiplication-Sign 10{sup 2} s at 293, 283, and 273 K, respectively. The relaxation process was analyzed using Hauser's equation, k=k{sub 0}exp[-(E{sub a}+E{sub a}{sup *}{gamma}) /k{sub B}T], where k is the rate constant of relaxation, k{sub 0} is the frequency factor, E{sub a} is the activation energy, E{sub a}{sup *} is the additional activation energy due to the cooperativity, and {gamma} is the fraction of the photo-induced phase. k{sub 0}, E{sub a}, and E{sub a}{sup *} were evaluated as 1.28 Multiplication-Sign 10{sup 7}{+-} 2.6 s{sup -1}, 4002 {+-} 188 cm{sup -1}, and 546 {+-} 318 cm{sup -1}, respectively. The value of E{sub a} is much larger than that of the relaxation process for the typical light-induced spin crossover effect (E{sub a} Almost-Equal-To 1000 cm{sup -1}). Room-temperature photo-switching is an important issue in the field of optical functional materials. The present system is useful for the demonstration of high-temperature photo-switching material.

  6. Two-dimensional [sup 1]H-NMR EXSY study of the fluxional behavior of the novel carbenium ion complex [FvMo[sub 2](CO)[sub 4]([mu],[eta][sup 2],[eta][sup 3]-MeC[equivalent to]CCH[sub 2])][BF[sub 4

    SciTech Connect (OSTI)

    Amouri, H.E.; Besace, Y.; Vollhardt, K.P.C.; Ball, G.E. Lawrence Berkeley Lab., CA ); Vaissermann, J. )

    1993-03-01

    The title compound [FuMo[sub 2](CO)[sub 4]([mu],[eta][sup 2],[eta][sup 3]-MeC[equivalent to]CCH[sub 2])][BF[sub 4

  7. Long-lived nanosecond spin relaxation and spin coherence of electrons in monolayer MoS2 and WS2

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yang, Luyi; Sinitsyn, Nikolai A.; Chen, Weibing; Yuan, Jiangtan; Zhang, Jing; Lou, Jun; Crooker, Scott  A.

    2015-08-03

    The recently discovered monolayer transition metal dichalcogenides (TMDCs) provide a fertile playground to explore new coupled spin–valley physics. Although robust spin and valley degrees of freedom are inferred from polarized photoluminescence (PL) experiments PL timescales are necessarily constrained by short-lived (3–100 ps) electron–hole recombination9, 10. Direct probes of spin/valley polarization dynamics of resident carriers in electron (or hole)-doped TMDCs, which may persist long after recombination ceases, are at an early stage. Here we directly measure the coupled spin–valley dynamics in electron-doped MoS2 and WS2 monolayers using optical Kerr spectroscopy, and reveal very long electron spin lifetimes, exceeding 3 ns atmore » 5 K (2-3 orders of magnitude longer than typical exciton recombination times). In contrast with conventional III–V or II–VI semiconductors, spin relaxation accelerates rapidly in small transverse magnetic fields. Supported by a model of coupled spin–valley dynamics, these results indicate a novel mechanism of itinerant electron spin dephasing in the rapidly fluctuating internal spin–orbit field in TMDCs, driven by fast inter-valley scattering. Additionally, a long-lived spin coherence is observed at lower energies, commensurate with localized states. These studies provide insight into the physics underpinning spin and valley dynamics of resident electrons in atomically thin TMDCs.« less

  8. Determination of the direct double- β -decay Q value of Zr 96 and atomic masses of Zr 90 - 92 , 94 , 96 and Mo 92 , 94 - 98 , 100

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gulyuz, K.; Ariche, J.; Bollen, G.; Bustabad, S.; Eibach, M.; Izzo, C.; Novario, S. J.; Redshaw, M.; Ringle, R.; Sandler, R.; et al

    2015-05-06

    Experimental searches for neutrinoless double-β decay offer one of the best opportunities to look for physics beyond the standard model. Detecting this decay would confirm the Majorana nature of the neutrino, and a measurement of its half-life can be used to determine the absolute neutrino mass scale. Important to both tasks is an accurate knowledge of the Q value of the double-β decay. The LEBIT Penning trap mass spectrometer was used for the first direct experimental determination of the ⁹⁶Zr double-β decay Q value: Qββ=3355.85(15) keV. This value is nearly 7 keV larger than the 2012 Atomic Mass Evaluation [M.more » Wang et al., Chin. Phys. C 36, 1603 (2012)] value and one order of magnitude more precise. The 3-σ shift is primarily due to a more accurate measurement of the ⁹⁶Zr atomic mass: m(⁹⁶Zr)=95.90827735(17) u. Using the new Q value, the 2νββ-decay matrix element, |M2ν|, is calculated. Improved determinations of the atomic masses of all other zirconium (90-92,94,96Zr) and molybdenum (92,94-98,100Mo) isotopes using both ¹²C₈ and ⁸⁷Rb as references are also reported.« less

  9. Probing the Role of Interlayer Coupling and Coulomb Interactions on Electronic Structure in Few-Layer MoSe 2 Nanostructures

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bradley, Aaron J.; M. Ugeda, Miguel; da Jornada, Felipe H.; Qiu, Diana Y.; Ruan, Wei; Zhang, Yi; Wickenburg, Sebastian; Riss, Alexander; Lu, Jiong; Mo, Sung-Kwan; et al

    2015-03-16

    Despite the weak nature of interlayer forces in transition metal dichalcogenide (TMD) materials, their properties are highly dependent on the number of layers in the few-layer two-dimensional (2D) limit. Here, we present a combined scanning tunneling microscopy/spectroscopy and GW theoretical study of the electronic structure of high quality single- and few-layer MoSe2 grown on bilayer graphene. We find that the electronic (quasiparticle) bandgap, a fundamental parameter for transport and optical phenomena, decreases by nearly one electronvolt when going from one layer to three due to interlayer coupling and screening effects. Our results paint a clear picture of the evolution ofmore » the electronic wave function hybridization in the valleys of both the valence and conduction bands as the number of layers is changed. This demonstrates the importance of layer number and electron-electron interactions on van der Waals heterostructures and helps to clarify how their electronic properties might be tuned in future 2D nanodevices.« less

  10. Long-lived nanosecond spin relaxation and spin coherence of electrons in monolayer MoS2 and WS2

    SciTech Connect (OSTI)

    Yang, Luyi; Sinitsyn, Nikolai A.; Chen, Weibing; Yuan, Jiangtan; Zhang, Jing; Lou, Jun; Crooker, Scott  A.

    2015-08-03

    The recently discovered monolayer transition metal dichalcogenides (TMDCs) provide a fertile playground to explore new coupled spin–valley physics. Although robust spin and valley degrees of freedom are inferred from polarized photoluminescence (PL) experiments PL timescales are necessarily constrained by short-lived (3–100 ps) electron–hole recombination9, 10. Direct probes of spin/valley polarization dynamics of resident carriers in electron (or hole)-doped TMDCs, which may persist long after recombination ceases, are at an early stage. Here we directly measure the coupled spin–valley dynamics in electron-doped MoS2 and WS2 monolayers using optical Kerr spectroscopy, and reveal very long electron spin lifetimes, exceeding 3 ns at 5 K (2-3 orders of magnitude longer than typical exciton recombination times). In contrast with conventional III–V or II–VI semiconductors, spin relaxation accelerates rapidly in small transverse magnetic fields. Supported by a model of coupled spin–valley dynamics, these results indicate a novel mechanism of itinerant electron spin dephasing in the rapidly fluctuating internal spin–orbit field in TMDCs, driven by fast inter-valley scattering. Additionally, a long-lived spin coherence is observed at lower energies, commensurate with localized states. These studies provide insight into the physics underpinning spin and valley dynamics of resident electrons in atomically thin TMDCs.

  11. Theoretical Investigation of H? Oxidation on the Sr2Fe1.5Mo0.5O6 (001) Perovskite Surface Under Anodic Solid Oxide Fuel Cell Conditions

    SciTech Connect (OSTI)

    Suthirakun, Suwit; Ammal, Salai Cheettu; Munoz-Garcia, Ana B.; Xiao, Guoliang; Chen, Fanglin; zur Loye, Hans-Conrad; Carter, Emily A.; Heyden, Andreas

    2014-06-11

    Periodic density functional theory (DFT) calculations and microkinetic modeling are used to investigate the electrochemical oxidation of H? fuel on the (001) surface of Sr2Fe1.5Mo0.5O6 (SFMO) perovskite under anodic solid oxide fuel cell conditions. Three surface models with different Fe/Mo ratios in the topmost layer-identified by ab initio thermodynamic analysis-are used to investigate the H? oxidation mechanism. A microkinetic analysis that considers the effects of anode bias potential suggests that a higher Mo concentration in the surface increases the activity of the surface toward H? oxidation. At operating voltage and anodic SOFC conditions, the model predicts that water desorption is rate-controlling and that stabilizing the oxygen vacancy structure increases the overall rate for H? oxidation. Although we find that Mo plays a crucial role in improving catalytic activity of SFMO, under fuel cell operating conditions, the Mo content in the surface layer tends to be very low. On the basis of these results and in agreement with previous experimental observations, a strategy for improving the overall electrochemical performance of SFMO is increasing the Mo content or adding small amounts of an active transition metal, such as Ni, to the surface to lower the oxygen vacancy formation energy of the SFMO surface.

  12. Effects of the foil flatness on the stress-strain characteristics of U10Mo alloy based monolithic mini-plates

    SciTech Connect (OSTI)

    Hakan Ozaltun; Pavel Medvedev

    2014-11-01

    The effects of the foil flatness on stress-strain behavior of monolithic fuel mini-plates during fabrication and irradiation were studied. Monolithic plate-type fuels are a new fuel form being developed for research and test reactors to achieve higher uranium densities. This concept facilitates the use of low-enriched uranium fuel in the reactor. These fuel elements are comprised of a high density, low enrichment, UMo alloy based fuel foil encapsulated in a cladding material made of Aluminum. To evaluate the effects of the foil flatness on the stress-strain behavior of the plates during fabrication, irradiation and shutdown stages, a representative plate from RERTR-12 experiments (Plate L1P756) was considered. Both fabrication and irradiation processes of the plate were simulated by using actual irradiation parameters. The simulations were repeated for various foil curvatures to observe the effects of the foil flatness on the peak stress and strain magnitudes of the fuel elements. Results of fabrication simulations revealed that the flatness of the foil does not have a considerable impact on the post fabrication stress-strain fields. Furthermore, the irradiation simulations indicated that any post-fabrication stresses in the foil would be relieved relatively fast in the reactor. While, the perfectly flat foil provided the slightly better mechanical performance, overall difference between the flat-foil case and curved-foil case was not significant. Even though the peak stresses are less affected, the foil curvature has several implications on the strain magnitudes in the cladding. It was observed that with an increasing foil curvature, there is a slight increase in the cladding strains.

  13. Syntheses, structure and rare earth metal photoluminescence of new and known isostructural A{sub 2}Mo{sub 4}Sb{sub 2}O{sub 18} (A=Ce, Pr, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu) compounds

    SciTech Connect (OSTI)

    Mohitkar, Shrikant A.; Kalpana, G.; Vidyasagar, K.

    2011-04-15

    Nine new A{sub 2}Mo{sub 4}Sb{sub 2}O{sub 18} (A=Ce, Pr, Eu, Tb, Ho, Er, Tm, Yb, Lu) compounds have been synthesized by solid-state reactions. They are isostructural with six reported analogues of yttrium and other lanthanides and the monoclinic unit cell parameters of all fifteen of them vary linearly with the size of A{sup 3+} ion. Single crystal X-ray structures of eight A{sub 2}Mo{sub 4}Sb{sub 2}O{sub 18} (A=Ce, Pr, Eu, Gd, Tb, Ho, Er, Tm) compounds have been determined. Neat A{sub 2}Mo{sub 4}Sb{sub 2}O{sub 18} (A=Pr, Sm, Eu, Tb, Dy, Ho, Er, Tm) compounds exhibit characteristic rare earth metal photoluminescence. -- Graphical abstract: Among the fifteen isostructural A{sub 2}Mo{sub 4}Sb{sub 2}O{sub 18} (A=rare earth metal) molybdoantimonites, eight (A=Pr, Sm, Eu, Tb, Dy, Ho, Er, Tm) compounds exhibit neat characteristic lanthanide photoluminescence in the 200-800 nm range at room temperature. Display Omitted Research highlights: {yields} Syntheses of nine new A{sub 2}Mo{sub 4}Sb{sub 2}O{sub 18} (A=Ce, Pr, Eu, Tb, Ho, Er, Tm, Yb, Lu) compounds. {yields} X-ray structures of eight A{sub 2}Mo{sub 4}Sb{sub 2}O{sub 18} (A=Ce, Pr, Eu, Gd, Tb, Ho, Er, Tm) compounds. {yields} Photoluminescence of neat A{sub 2}Mo{sub 4}Sb{sub 2}O{sub 18} (A=Pr, Sm, Eu, Tb, Dy, Ho, Er, Tm) compounds.

  14. PSA Vol 1 Tables Revised Ver 2 Print.xls

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    2005 (Thousand Barrels) East Coast Appalachian No. 1 Total IN, IL, KY MN, WI, ND, SD OK, KS, MO Total Liquefied Refinery Gases 14,825 298 15,123 33,928 1,840 2,446 38,214...

  15. untitled

    Gasoline and Diesel Fuel Update (EIA)

    2005 (Thousand Barrels) East Coast Appalachian No. 1 Total IN, IL, KY MN, WI, ND, SD OK, KS, MO Total Total Net Input 16,465 108 16,573 10,405 2,208 1,923 14,536 Pentanes Plus...

  16. PSA Vol 1 Tables Revised Ver 2 Print.xls

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    2005 (Thousand Barrels) East Coast Appalachian No. 1 Total IN, IL, KY MN, WI, ND, SD OK, KS, MO Total Natural Gas Liquids 359 5,914 6,273 26,874 4,786 77,174 108,834 Pentanes...

  17. PSA Vol 1 Tables Revised Ver 2 Print.xls

    Gasoline and Diesel Fuel Update (EIA)

    Refining Districts, 2005 East Coast Appalachian No. 1 Total IN, IL, KY MN, WI, ND, SD OK, KS, MO Total Liquefied Refinery Gases 2.5 0.9 2.4 4.2 1.2 0.9 3.1 Finished Motor...

  18. untitled

    Gasoline and Diesel Fuel Update (EIA)

    2005 (Thousand Barrels) East Coast Appalachian No. 1 Total IN, IL, KY MN, WI, ND, SD OK, KS, MO Total Total Net Input 17,809 97 17,906 9,452 1,740 1,790 12,982 Pentanes Plus 0...

  19. untitled

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    2005 (Thousand Barrels) East Coast Appalachian No. 1 Total IN, IL, KY MN, WI, ND, SD OK, KS, MO Total Natural Gas Liquids 44 526 570 1,615 417 5,414 7,446 Pentanes Plus 5 89 94...

  20. PSA Vol 1 Tables Revised Ver 2 Print.xls

    Gasoline and Diesel Fuel Update (EIA)

    2005 (Thousand Barrels) East Coast Appalachian No. 1 Total IN, IL, KY MN, WI, ND, SD OK, KS, MO Total Total Net Input 199,173 1,285 200,458 117,409 24,041 20,032 161,482...

  1. untitled

    Gasoline and Diesel Fuel Update (EIA)

    December 2005 East Coast Appalachian No. 1 Total IN, IL, KY MN, WI, ND, SD OK, KS, MO Total Liquefied Refinery Gases 0.7 -0.6 0.6 3.5 -1.1 -1.0 1.9 Finished Motor Gasoline a 50.3...

  2. untitled

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    2005 (Thousand Barrels) East Coast Appalachian No. 1 Total IN, IL, KY MN, WI, ND, SD OK, KS, MO Total Natural Gas Liquids 0 508 508 2,142 393 6,367 8,902 Pentanes Plus 0 90 90...

  3. untitled

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    September 2005 East Coast Appalachian No. 1 Total IN, IL, KY MN, WI, ND, SD OK, KS, MO Total Liquefied Refinery Gases 0.7 0.3 0.7 2.9 1.3 0.5 2.2 Finished Motor Gasoline a 47.9...

  4. Project Specific Waiver for Heartland Community College | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Project Specific Waiver for Heartland Community College Project Specific Waiver for Heartland Community College PDF icon il_signed More Documents & Publications EA-1807: Finding of No Significant Impact Project Specific Waiver for the Texas State Energy Office EV Community Readiness projects: Delaware Valley Regional Planning Commission (PA); Metropolitan Energy Information Center, Inc. (KS, MO

  5. untitled

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    MN, WI, ND, SD OK, KS, MO Total Liquefied Refinery Gases 382 8 390 2,072 157 116 2,345 EthaneEthylene 10 0 10 0 0 0 0 Ethane 0 0 0 0 0 0 0 Ethylene 10 0 10 0 0 0 0 Propane...

  6. Influence of microstructural changes due to tempering at 923 K and 1,023 K on magnetic Barkhausen noise behavior in normalized 2.25Cr-1Mo ferritic steel

    SciTech Connect (OSTI)

    Raj, B.; Moorthy, V.; Vaidyanathan, S.

    1997-01-01

    Magnetic Barkhausen noise analysis has been used to characterize the microstructural changes in normalized and tempered 2.25 Cr-1Mo steel. It is observed that tempering at 923 K shows a single peak behavior up to 20 h and tempering at 1,023 K shows a two peak behavior. This has been explained on the basis of the two stage process of irreversible domain wall movement during magnetization, associated with two major obstacles to domain wall movement: namely lath/grain boundaries and secondary phase precipitates. At lower fields, existing reverse domain walls at lath/grain boundaries overcome the resistance offered by the grain boundaries and move to a distance before they are pined by the precipitates. Then, at higher field, they overcome these precipitates. These two processes occur over a range of critical field strengths with some mean values. If these two mean values are close to each other, then a single peak in the rms voltage of the magnetic Barkhausen noise, with the associated changes in its shape, is observed. On the other hand, if the mean values of the critical fields for these two barriers are widely separated, then a two peak behavior is the clear possibility. The effect of the microstructural changes due to tempering for different durations at 923 K and 1,023 K in 2.25 Cr-1Mo ferritic steel on magnetic Barkhausen noise is explained based on these two stage processes. The influence of high dislocation density in bainitic structure, dissociation of bainite, and precipitation of different carbides such as Fe{sub 3}C, Mo{sub 2}C, Cr{sub 7}Ce{sub 3}, M{sub 23}C{sub 6}, etc., on magnetic Barkhausen noise behavior has been analyzed in this study.

  7. Synthesis of Compositionally Defined Single-Crystalline Eu 3+ -Activated MolybdateTungstate Solid-Solution Composite Nanowires and Observation of Charge Transfer in a Novel Class of 1D CaMoO 4 CaWO 4 :Eu 3+ 0D CdS/CdSe QD Nanoscale Heterostructures

    SciTech Connect (OSTI)

    Han, Jinkyu; McBean, Coray; Wang, Lei; Jaye, Cherno; Liu, Haiqing; Fischer, Daniel A.; Wong, Stanislaus S.

    2015-02-10

    As a first step, we have synthesized and optically characterized a systematic series of one-dimensional (1D) single-crystalline Eu?-activated alkaline-earth metal tungstate/molybdate solid solution composite CaW??xMoxO? (0 ? x ? 1) nanowires of controllable chemical composition using a modified template-directed methodology under ambient room-temperature conditions. Extensive characterization of the resulting nanowires has been performed using X-ray diffraction, electron microscopy, and optical spectroscopy. The crystallite size and single crystallinity of as-prepared 1D CaW??xMoxO?: Eu? (0 ? x ? 1) solid solution composite nanowires increase with increasing Mo component (x). We note a clear dependence of luminescence output upon nanowire chemical composition with our 1D CaW??xMoxO?: Eu? (0 ? x ? 1) evincing the highest photoluminescence (PL) output at x = 0.8, amongst samples tested. Subsequently, coupled with either zero-dimensional (0D) CdS or CdSe quantum dots (QDs), we successfully synthesized and observed charge transfer processes in 1D CaW1-xMoxO4: Eu3+ (x = 0.8) 0D QD composite nanoscale heterostructures. Our results show that CaW??xMoxO?: Eu? (x = 0.8) nanowires give rise to PL quenching when CdSe QDs and CdS QDs are anchored onto the surfaces of 1D CaW??xMoxO?: Eu? nanowires. The observed PL quenching is especially pronounced in CaW??xMoxO?: Eu? (x = 0.8) 0D CdSe QD heterostructures. Conversely, the PL output and lifetimes of CdSe and CdS QDs within these heterostructures are not noticeably altered as compared with unbound CdSe and CdS QDs. The difference in optical behavior between 1D Eu? activated tungstate and molybdate solid solution nanowires and the semiconducting 0D QDs within our heterostructures can be correlated with the relative positions of their conduction and valence energy band levels. We propose that the PL quenching can be attributed to a photo-induced electron transfer process from CaW??xMoxO?: Eu? (x = 0.8) to both CdSe and CdS QDs, an assertion supported by complementary NEXAFS measurements.

  8. Formation of voids and secondary-phase precipitates in the Fe-16Cr-15Ni-2Mo-1Mn-Ti-Si steel under high-doze neutron irradiation and during post-irradiation annealing

    SciTech Connect (OSTI)

    Portnykh, I. A. Kozlov, A. V.; Shcherbakov, E. N.; Asiptsov, O. I.

    2009-12-15

    The effect of high-dose neutron irradiation on the structural changes in Fe-16Cr-15Ni-2Mo-1Mn-Ti-Si austenitic steel have been investigated. Samples irradiated at temperatures of 390, 500, and 600{sup o} to damage doses of 46, 86, and 46 dpa, respectively, were analyzed by electron microscopy and dilatometry. The quantitative characteristics of radiation voids and secondary-phase precipitates formed under neutron irradiation are obtained. Their behavior upon heating to 700{sup o}C and annealing at this temperature for 2 h is studied. It is shown that annealing leads to the dissociation of small voids, which is accompanied by the growth of large ones. The secondary-phase precipitates are partially dissolved upon annealing, and their volume fraction decreases.

  9. STEAB Meeting Minutes April 2007

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    State Energy Advisory Board Meeting April 8-10, 2007 Albuquerque, NM A Visit to the Sandia National Laboratory BOARD MEMBERS PRESENT Chris Benson (Chairman) (AR), Patricia Sobrero (Vice-Chair) (VA), Elliot Jacobson (Secretary) (MA), JamesEtta Reed (PA), Janet Streff (MN), Duane Hauck (ND), Peter Johnston (AZ), John Davies (KY), Jim Ploger (KS), Jim Nolan (MT), Susan Brown (WI), Steven Vincent (OR), Paul Gutierrez (NM), Daniel Zaweski (NY), and Robert Hoppie (ID). Others present were: Gary Burch,

  10. Whitlash, MT Natural Gas Pipeline Imports From Canada (Million...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2011 586 518 591 564 622 539 612 629 604 606 591 599 2012 598 571 600 542 575 525 550 549 530 526 493 512 2013 511 452 475 485...

  11. Sweetgrass, MT Natural Gas Pipeline Imports From Canada (Million...

    Gasoline and Diesel Fuel Update (EIA)

    Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2011 71 62 68 68 70 68 68 67 64 57 53 64 2012 57 60 63 62 65 61 68 60 55 57 52 55 2013 52 46 46 25 991...

  12. Direct-Current Resistivity Survey At Mt Princeton Hot Springs...

    Open Energy Info (EERE)

    Activity Date 2010 Usefulness useful DOE-funding Unknown Notes Used to map fracture and fluid flow patterns. References K. Richards, A. Revil, A. Jardani, F. Henderson, M....

  13. RAPID/Roadmap/17-MT-d | Open Energy Information

    Open Energy Info (EERE)

    to cross a stream or wetland; handling, storing, applying or disposing of hazardous or toxic material in a manner that pollutes streams, lakes or wetlands or that may cause damage...

  14. Geothermometry At Mt Princeton Hot Springs Geothermal Area (Pearl...

    Open Energy Info (EERE)

    Celcius References R.H. Pearl, J.K. Barrett (1976) Geothermal resources of the Upper San Luis and Arkansas valleys, Colorado Additional References Retrieved from "http:...

  15. Integrated Dense Array and Transect MT Surveying at Dixie Valley...

    Open Energy Info (EERE)

    Geothermal Area, Nevada- Structural Controls, Hydrothermal Alteration and Deep Fluid Sources Jump to: navigation, search OpenEI Reference LibraryAdd to library Conference Paper:...

  16. RAPID/Roadmap/19-MT-a | Open Energy Information

    Open Energy Info (EERE)

    in Kalispell, Missoula, Helena, Bozeman, Havre, Glasgow, Lewistown and Billings. Once an application is filed, its status may be tracked using the Montana Pending Water...

  17. Port of Morgan, MT Natural Gas Exports to Canada

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    2 2013 2014 View History Pipeline Volumes 0 123 0 1998-2014 Pipeline Prices -- 3.14 -- 1998-2014

  18. Sweetgrass, MT Liquefied Natural Gas Exports to Canada

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    09 2010 2011 2012 2013 2014 View History Pipeline Volumes 1,109 932 781 716 1,160 0 1998-2014 Pipeline Prices 3.52 3.98 3.77 2.41 3.67 -- 1998-2014

  19. Whitlash, MT Natural Gas Imports by Pipeline from Canada

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    7,707 7,062 6,571 5,387 5,128 4,651 1996-2015 Pipeline Prices 3.88 3.65 2.35 3.07 4.04 2.13

  20. RAPID/Roadmap/17-MT-a | Open Energy Information

    Open Energy Info (EERE)

    Along with protecting the aesthetic value, the policies protect water quality and fish habitat. An additional benefit of the policy is minimization of sedimentation....

  1. RAPID/Roadmap/6-MT-f | Open Energy Information

    Open Energy Info (EERE)

    be obtained from the Department of Environmental Quality, or may be waived by Montana Fish, Wildlife & Parks during its review process under the Natural Streambed and Land...

  2. Field Mapping At Marysville Mt Area (Blackwell) | Open Energy...

    Open Energy Info (EERE)

    intrusive (outlined by the magnetic data) and the heat flow anomaly occupy a broad dome in the Precambrian rocks, the stock outcropping in the northwest portion of the dome,...

  3. 2007-mt-elbert | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The Alaska North Slope Stratigraphic Test Well image showing Donyon Rig Photo courtesy Doyon Drilling Inc Project Background Maps of Research Area Photo Gallery Well log Data From BP-DOE-US "Mount Elbert" Test Is Now Available. Digital well log data acquired at the February 2007 gas hydrates test well at Milne Point, Alaska are now available. Data include Gamma ray, neutron porosity, density porosity, three-dimensional high resolution resistivity, acoustics including compressional- and

  4. RAPID/Roadmap/3-MT-e | Open Energy Information

    Open Energy Info (EERE)

    on Montana Department of Transportation lands. 03MTEEncroachmentPermit.pdf Error creating thumbnail: Page number not in range. Error creating thumbnail: Page number...

  5. RAPID/Roadmap/3-MT-f | Open Energy Information

    Open Energy Info (EERE)

    easements established before 1997. 03MTFRightOfWayEasementForUtilitiesProcess.pdf Error creating thumbnail: Page number not in range. Error creating thumbnail: Page number...

  6. Port of Morgan, MT Natural Gas Exports to Canada

    Gasoline and Diesel Fuel Update (EIA)

    485,026 690,466 658,934 730,988 695,152 518,386 1996-2014 Pipeline Prices 3.90 4.14 3.75 2.45 3.23 4.41...

  7. Aeromagnetic Survey At Mt St Helens Area (Towle, 1983) | Open...

    Open Energy Info (EERE)

    structure of Mount St. Helens in more detail. Electrical and electromagnetic methods would be especially useful in determining the actual electrical conductivity of...

  8. Self Potential At Mt Princeton Hot Springs Geothermal Area (Richards...

    Open Energy Info (EERE)

    groundwater flux patterns Notes Researchers collected 2700 SP measurements. Equilibrium temperature data from wells and shallow (305 cm) holes was correlated to geoelectrical...

  9. DC Resistivity Survey (Wenner Array) At Mt Princeton Hot Springs...

    Open Energy Info (EERE)

    and produced 12 resistivity profiles, each approximately 1.3 km in length. Equilibrium temperature data from wells and shallow (305 cm) holes was correlated to geoelectrical...

  10. Ground Magnetics At Marysville Mt Area (Blackwell) | Open Energy...

    Open Energy Info (EERE)

    field of the effect of the stock. References D. D. Blackwell (Unknown) Exploration In A Blind Geothermal Area Near Marysville, Montana, Usa Additional References Retrieved from...

  11. Ground Gravity Survey At Marysville Mt Area (Blackwell) | Open...

    Open Energy Info (EERE)

    and with the heat flow anomaly. References D. D. Blackwell (Unknown) Exploration In A Blind Geothermal Area Near Marysville, Montana, Usa Additional References Retrieved from...

  12. Direct-Current Resistivity Survey At Marysville Mt Area (Blackwell...

    Open Energy Info (EERE)

    with the thermal anomaly. References D. D. Blackwell (Unknown) Exploration In A Blind Geothermal Area Near Marysville, Montana, Usa Additional References Retrieved from...

  13. Mt. Edgecumbe High School Wind Project | Open Energy Information

    Open Energy Info (EERE)

    - Yankton School District Wind Project

  14. RAPID/Roadmap/7-MT-a | Open Energy Information

    Open Energy Info (EERE)

    convenience, and necessity; Water and air quality decisions have already been issued; and Public lands and federal corridors were considered. The DEQ must approve a facility as...

  15. RAPID/Roadmap/14-MT-b | Open Energy Information

    Open Energy Info (EERE)

    waters of the United States. Point sources are discrete conveyances such as pipes or man-made ditches. Individual homes that are connected to a municipal system, use a septic...

  16. Micro-Earthquake At Marysville Mt Area (Blackwell) | Open Energy...

    Open Energy Info (EERE)

    observed in the geothermal areas in the Salton Sea between 1-10 Hz (in units of power density). Because of this very low background noise the micro-earthquake survey was possible...

  17. RAPID/Roadmap/3-MT-d | Open Energy Information

    Open Energy Info (EERE)

    lease, exchange and sell school lands" and other lands granted for the support of education. It has the authority to issue leases for agriculture, grazing, mineral production,...

  18. Mt St Helens Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    -122.04050509296 Resource Estimate Mean Reservoir Temp: Estimated Reservoir Volume: Mean Capacity: USGS Mean Reservoir Temp: USGS Estimated Reservoir Volume: USGS Mean...

  19. Mt St Helens Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    Resource Estimate Mean Reservoir Temp: Estimated Reservoir Volume: Mean Capacity: USGS Mean Reservoir Temp: USGS Estimated Reservoir Volume: USGS Mean Capacity: Click "Edit With...

  20. RAPID/Roadmap/9-MT-a | Open Energy Information

    Open Energy Info (EERE)

    (MEPA) is intended to protect the state from the cumulative affect of development on nature and human health, much in the same way the National Environmental Policy Act regulates...

  1. RAPID/Roadmap/6-MT-b | Open Energy Information

    Open Energy Info (EERE)

    surface waters. The NOI must include a narrative description of: The location and nature of the activity; The total area of the site and the area within the site that is...

  2. RAPID/Roadmap/6-MT-e | Open Energy Information

    Open Energy Info (EERE)

    creating thumbnail: Page number not in range. Flowchart Narrative Anyone planning new development within a designated Special Flood Hazard Areas (SFHA). Check with local...

  3. RAPID/Roadmap/14-MT-a | Open Energy Information

    Open Energy Info (EERE)

    through the voluntary implementation of best management practices identified in science-based, community-supported watershed plans. 14MTANonpointSourcePollution (1).pdf...

  4. Mt Carmel Public Utility Co | Open Energy Information

    Open Energy Info (EERE)

    2008-04 388 3,487 4,603 146 1,267 856 104 2,826 104 638 7,580 5,563 2008-03 486 4,284 4,607 147 1,239 856 275 2,792 105 908 8,315 5,568 2008-02 418 4,603 4,612 127 1,318 855 226...

  5. RAPID/Roadmap/17-MT-c | Open Energy Information

    Open Energy Info (EERE)

    Permitting Information Desktop Toolkit BETA About Bulk Transmission Geothermal Hydropower Solar Tools Contribute Contact Us Natural Streambed and Land Preservation Act (310 Permit)...

  6. Sweetgrass, MT Liquefied Natural Gas Exports Price (Dollars per Thousand

    U.S. Energy Information Administration (EIA) Indexed Site

    Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 2010's -- 13.29 14.38 14.95 13.48

  7. Sweetgrass, MT Natural Gas Pipeline Imports From Canada (Dollars per

    U.S. Energy Information Administration (EIA) Indexed Site

    Thousand Cubic Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1990's NA NA 2000's NA 1.94 NA 5.09 5.12 7.37 5.81 6.12 8.02 3.52 2010's 3.98 3.77 2.41 3.67 --

  8. Sweetgrass, MT Natural Gas Pipeline Imports From Canada (Dollars per

    U.S. Energy Information Administration (EIA) Indexed Site

    Thousand Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2011 4.08 3.79 3.87 3.96 4.08 4.18 3.94 3.78 3.71 3.37 3.24 2.96 2012 2.51 2.19 1.86 1.71 2.08 1.95 2.37 2.27 2.42 3.20 3.44 3.26 2013 3.14 3.12 3.42 3.69 3.73

  9. Sweetgrass, MT Natural Gas Pipeline Imports From Canada (Million Cubic

    U.S. Energy Information Administration (EIA) Indexed Site

    Feet) Decade Year-0 Year-1 Year-2 Year-3 Year-4 Year-5 Year-6 Year-7 Year-8 Year-9 1990's NA NA 2000's NA 121 NA 347 2,728 2,043 2,012 1,539 1,373 1,109 2010's 932 781 716 1,160 0

  10. Sweetgrass, MT Natural Gas Pipeline Imports From Canada (Million Cubic

    U.S. Energy Information Administration (EIA) Indexed Site

    Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2011 71 62 68 68 70 68 68 67 64 57 53 64 2012 57 60 63 62 65 61 68 60 55 57 52 55 2013 52 46 46 25 991

  11. RAPID/Roadmap/8-MT-a | Open Energy Information

    Open Energy Info (EERE)

    That the facility will serve the public interest, convenience, and necessity; Water and air quality decisions have already been issued; and Public lands and federal corridors were...

  12. BWXT Pantex, LLC Route 726, Mt. Athos Road

    National Nuclear Security Administration (NNSA)

    I I . CONTRACT ID CODE I I 9B. DATED (SEE ITEM 1 1 ) PAGE I OF 4 PAGES 10A. MODIFICATION OF CONTRACTIORDER NO. I 1 DEJCOCOOAL66620 106. DATED (SEE ITEM 13) 2. AMENDMENTIMODIFICATION NO. MI00 extended. 3. EFFECTIVE DATE See Block 16C CODE I FACILITY CODE Offers must acknowledge receipt of this amendment prior to the hour and date specifled in the solicitation as amended, by one of the following methods: (a) By completing Items 8 and 15, and returning - copies of the amendment; (b) By

  13. BWXT Pantex, LLC Route 726, Mt. Athos Road

    National Nuclear Security Administration (NNSA)

    Sol-lClTATlONlMODlFlCATlON OF CONTRACT I I . CONTRACT ID CODE PAGE I OF P PAGES 9B. DATED (SEE E M 11) 2. AMENDMENTIMODIFICATION NO. MI01 Offers must acknowledge receipt of this amendment prior to the hour and date specifmd in the solicitation as mended, by one of the following methods: (a) By completing Items 8 and 15, and returning - coples of the amendment; @) By acknowledging r d p t of this amendment on each copy of the offer submitted; or (c) By seperate letter or telegram whlch includes a

  14. BWXT Pantex, LLC Route 726, Mt. Athos Road

    National Nuclear Security Administration (NNSA)

    9B. DATED (SEE ITEM 11) I I DE-AC04-00AL66620 10B. DATED (SEE ITEM 13) CONTRACT ID CODE PAGE I OF 2 PAGES 2. AMENDMENTIMODIFICATION NO. MI18 extended. CODE I FACILITY CODE Offers must acknowledge receipt of this amendment prior to the hour and date specified in the solicitation as amended, by one of the following methods: (a) By completing Items 8 and 15, and returning - copies of the amendment; (b) By acknowledging receipt of this amendment on each copy of the offer submitted; or (c) By

  15. BWXT Pantex, LLC Route 726, Mt. Athos Road

    National Nuclear Security Administration (NNSA)

    I 1 CONTRACT ID CODE I I 9B. DATED (SEE ITEM 11) PAGE I OF 2 PAGES 10A. MODIFICATION OF CONTRACTIORDER NO. DE-AC04-00AL66620 1 1 1 0 B DATED (SEE ITEM 13) 2. AMENDMENTIMODIFICATION NO. M I 22 - . - extended. Offers must acknowledge receipt of this amendment prior to the hour and date specified in the solicitation as amended, by one of the following methods: (a) By completing Items 8 and 15, and returning - copies of the amendment; (b) By acknowledging receipt of this amendment on each copy of

  16. BWXT Pantex, LLC Route 726, Mt. Athos Road Lynchburg, V

    National Nuclear Security Administration (NNSA)

    V A 24506 AMENDMENT OF SOLlClTATlONlMODlFlCATlON OF CONTRACT ( A . CONTRACT ID CODE PAGE I OF 2 PAGES I 1 9B. DATED (SEE ITEM I ) I I I 2. AMENDMENTIMODIFICATION NO. M120 I 10A. MODIFICATION OF CONTRACTIORDER NO. DE-AC04-00AL66620 I 1 10B. DATED (SEE ITEM 13) 3. EFFECTIVE DATE See Block 16C 6. ISSUED BY CODE U.S. Department of Energy National Nuclear Security Administration Service Center Property and M&O Contract Support Department P.O. Box 5400 Albuquerque, NM 871 85-5400 7. ADMINISTERED

  17. RAPID/Roadmap/6-MT-a | Open Energy Information

    Open Energy Info (EERE)

    well as ARM 18.8.5 govern the maximum dimensions, weights, and other characteristics of motor vehicles operating on highways in the state. Vehicles exceeding the maximum width,...

  18. Data Acquisition-Manipulation At Marysville Mt Area (Blackwell...

    Open Energy Info (EERE)

    D. Blackwell (Unknown) Exploration In A Blind Geothermal Area Near Marysville, Montana, Usa Additional References Retrieved from "http:en.openei.orgwindex.php?titleDataAcqui...

  19. Northwest Distributed/Community Wind Workgroup Meeting- MT

    Broader source: Energy.gov [DOE]

    The Northwest Wind Resource and Action Center, which is partially funded by the U.S. Department of Energy, will facilitate a workgroup meeting for stakeholders involved in the distributed and...

  20. File:INL-geothermal-mt.pdf | Open Energy Information

    Open Energy Info (EERE)

    current 12:41, 16 December 2010 Thumbnail for version as of 12:41, 16 December 2010 5,100 4,200 (1.99 MB) MapBot (Talk | contribs) Automated upload from NREL's "mapsearch"...

  1. Sweetgrass, MT Liquefied Natural Gas Exports (Million Cubic Feet...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Natural Gas Exports (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2014 8 11 10 8 8 5 6 6 6 6 6 7 2015 5 4 5 5 5 4 - No Data Reported; -- Not...

  2. Sweetgrass, MT Liquefied Natural Gas Exports Price (Dollars per...

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2014 15.01 15.61 15.61 14.97 15.10 14.88 14.94 14.34 14.48 14.42 14.07 14.93 2015 13.77 13.30 13.27 12.89 13.25 14.56...

  3. Babb, MT Liquefied Natural Gas Exports (Million Cubic Feet)

    Annual Energy Outlook [U.S. Energy Information Administration (EIA)]

    Natural Gas Exports (Million Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2015 5 - No Data Reported; -- Not Applicable; NA Not Available; W Withheld...

  4. Babb, MT Liquefied Natural Gas Exports Price (Dollars per Thousand...

    Gasoline and Diesel Fuel Update (EIA)

    Price (Dollars per Thousand Cubic Feet) Year Jan Feb Mar Apr May Jun Jul Aug Sep Oct Nov Dec 2015 12.95 - No Data Reported; -- Not Applicable; NA Not Available; W ...

  5. Measurement of the Effective Weak Mixing Angle inpp<mo stretchy='false'>mo> stretchy='false'>?mo>Z<mo>/?* stretchy='false'>?mo>e<mo>+mo>e<mo>->Events

    SciTech Connect (OSTI)

    Abazov, V.? M.; Abbott, B.; Acharya, B.? S.; Adams, M.; Adams, T.; Agnew, J.? P.; Alexeev, G.? D.; Alkhazov, G.; Alton, A.; Askew, A.; Atkins, S.; Augsten, K.; Avila, C.; Badaud, F.; Bagby, L.; Baldin, B.; Bandurin, D. ?V.; Banerjee, S.; Barberis, E.; Baringer, P.; Bartlett, J. ?F.; Bassler, U.; Bazterra, V.; Bean, A.; Begalli, M.; Bellantoni, L.; Beri, S.? B.; Bernardi, G.; Bernhard, R.; Bertram, I.; Besanon, M.; Beuselinck, R.; Bhat, P.? C.; Bhatia, S.; Bhatnagar, V.; Blazey, G.; Blessing, S.; Bloom, K.; Boehnlein, A.; Boline, D.; Boos, E.? E.; Borissov, G.; Borysova, M.; Brandt, A.; Brandt, O.; Brock, R.; Bross, A.; Brown, D.; Bu, X. ?B.; Buehler, M.; Buescher, V.; Bunichev, V.; Burdin, S.; Buszello, C.? P.; Camacho-Prez, E.; Casey, B.? C.?K.; Castilla-Valdez, H.; Caughron, S.; Chakrabarti, S.; Chan, K.? M.; Chandra, A.; Chapon, E.; Chen, G.; Cho, S.? W.; Choi, S.; Choudhary, B.; Cihangir, S.; Claes, D.; Clutter, J.; Cooke, M.; Cooper, W. ?E.; Corcoran, M.; Couderc, F.; Cousinou, M. -C.; Cutts, D.; Das, A.; Davies, G.; de Jong, S. ?J.; De La Cruz-Burelo, E.; Dliot, F.; Demina, R.; Denisov, D.; Denisov, S.? P.; Desai, S.; Deterre, C.; DeVaughan, K.; Diehl, H.? T.; Diesburg, M.; Ding, P. ?F.; Dominguez, A.; Dubey, A.; Dudko, L.? V.; Duperrin, A.; Dutt, S.; Eads, M.; Edmunds, D.; Ellison, J.; Elvira, V. ?D.; Enari, Y.; Evans, H.; Evdokimov, V.? N.; Faur, A.; Feng, L.; Ferbel, T.; Fiedler, F.; Filthaut, F.; Fisher, W.; Fisk, H.? E.; Fortner, M.; Fox, H.; Fuess, S.; Garbincius, P. ?H.; Garcia-Bellido, A.; Garca-Gonzlez, J. ?A.; Gavrilov, V.; Geng, W.; Gerber, C.? E.; Gershtein, Y.; Ginther, G.; Gogota, O.; Golovanov, G.; Grannis, P. ?D.; Greder, S.; Greenlee, H.; Grenier, G.; Gris, Ph.; Grivaz, J. -F.; Grohsjean, A.; Grnendahl, S.; Grnewald, M.? W.; Guillemin, T.; Gutierrez, G.; Gutierrez, P.; Haley, J.; Han, L.; Harder, K.; Harel, A.; Hauptman, J.? M.; Hays, J.; Head, T.; Hebbeker, T.; Hedin, D.; Hegab, H.; Heinson, A. ?P.; Heintz, U.; Hensel, C.; Heredia-De La Cruz, I.; Herner, K.; Hesketh, G.; Hildreth, M.? D.; Hirosky, R.; Hoang, T.; Hobbs, J. ?D.; Hoeneisen, B.; Hogan, J.; Hohlfeld, M.; Holzbauer, J.? L.; Howley, I.; Hubacek, Z.; Hynek, V.; Iashvili, I.; Ilchenko, Y.; Illingworth, R.; Ito, A.? S.; Jabeen, S.; Jaffr, M.; Jayasinghe, A.; Jeong, M.? S.; Jesik, R.; Jiang, P.; Johns, K.; Johnson, E.; Johnson, M.; Jonckheere, A.; Jonsson, P.; Joshi, J.; Jung, A.? W.; Juste, A.; Kajfasz, E.; Karmanov, D.; Katsanos, I.; Kaur, M.; Kehoe, R.; Kermiche, S.; Khalatyan, N.; Khanov, A.; Kharchilava, A.; Kharzheev, Y. ?N.; Kiselevich, I.; Kohli, J.? M.; Kozelov, A.? V.; Kraus, J.; Kumar, A.; Kupco, A.; Kur?a, T.; Kuzmin, V. ?A.; Lammers, S.; Lebrun, P.; Lee, H.? S.; Lee, S.? W.; Lee, W. ?M.; Lei, X.; Lellouch, J.; Li, D.; Li, H.; Li, L.; Li, Q.? Z.; Lim, J.? K.; Lincoln, D.; Linnemann, J.; Lipaev, V.? V.; Lipton, R.; Liu, H.; Liu, Y.; Lobodenko, A.; Lokajicek, M.; Lopes de Sa, R.; Luna-Garcia, R.; Lyon, A.? L.; Maciel, A. ?K.?A.; Madar, R.; Magaa-Villalba, R.; Malik, S.; Malyshev, V.? L.; Mansour, J.; Martnez-Ortega, J.; McCarthy, R.; McGivern, C. ?L.; Meijer, M.? M.; Melnitchouk, A.; Menezes, D.; Mercadante, P. ?G.; Merkin, M.; Meyer, A.; Meyer, J.; Miconi, F.; Mondal, N.? K.; Mulhearn, M.; Nagy, E.; Narain, M.; Nayyar, R.; Neal, H.? A.; Negret, J.? P.; Neustroev, P.; Nguyen, H.? T.; Nunnemann, T.; Orduna, J.; Osman, N.; Osta, J.; Pal, A.; Parashar, N.; Parihar, V.; Park, S. ?K.; Partridge, R.; Parua, N.; Patwa, A.; Penning, B.; Perfilov, M.; Peters, Y.; Petridis, K.; Petrillo, G.; Ptroff, P.; Pleier, M. -A.; Podstavkov, V. ?M.; Popov, A.? V.; Prewitt, M.; Price, D.; Prokopenko, N.; Qian, J.; Quadt, A.; Quinn, B.; Ratoff, P.? N.; Razumov, I.; Ripp-Baudot, I.; Rizatdinova, F.; Rominsky, M.; Ross, A.; Royon, C.; Rubinov, P.; Ruchti, R.; Sajot, G.; Snchez-Hernndez, A.; Sanders, M.? P.; Santos, A. ?S.; Savage, G.; Savitskyi, M.; Sawyer, L.; Scanlon, T.; Schamberger, R. ?D.; Scheglov, Y.; Schellman, H.; Schwanenberger, C.; Schwienhorst, R.; Sekaric, J.; Severini, H.; Shabalina, E.; Shary, V.; Shaw, S.; Shchukin, A. ?A.; Simak, V.; Skubic, P.; Slattery, P.; Smirnov, D.; Snow, G.? R.; Snow, J.; Snyder, S.; Sldner-Rembold, S.; Sonnenschein, L.; Soustruznik, K.; Stark, J.; Stoyanova, D.? A.; Strauss, M.; Suter, L.; Svoisky, P.; Titov, M.; Tokmenin, V.? V.; Tsai, Y. -T.; Tsybychev, D.; Tuchming, B.; Tully, C.; Uvarov, L.; Uvarov, S.; Uzunyan, S.; Van Kooten, R.; van Leeuwen, W.? M.; Varelas, N.; Varnes, E.? W.; Vasilyev, I.? A.; Verkheev, A. ?Y.; Vertogradov, L. ?S.; Verzocchi, M.; Vesterinen, M.; Vilanova, D.

    2015-07-22

    We present a measurement of the fundamental parameter of the standard model, the weak mixing angle sin2??eff which determines the relative strength of weak and electromagnetic interactions, in pp?Z/?*?e+e- events at a center of mass energy of 1.96 TeV, using data corresponding to 9.7 fb-1 of integrated luminosity collected by the D0 detector at the Fermilab Tevatron. The effective weak mixing angle is extracted from the forward-backward charge asymmetry as a function of the invariant mass around the Z boson pole. The measured value of sin2??eff=0.231470.00047 is the most precise measurement from light quark interactions to date, with a precision close to the best LEP and SLD results.

  6. Influence of the support of CoMo sulfide catalysts and of the addition of potassium and platinum on the catalytic performances for the hydrodeoxygenation of carbonyl, carboxyl, and guaiacol-type molecules

    SciTech Connect (OSTI)

    Centeno, A.; Laurent, E.; Delmon, B. [Universite Catholique de Louvain, Louvain-la-Neuve (Belgium)] [Universite Catholique de Louvain, Louvain-la-Neuve (Belgium)

    1995-07-01

    The present work corresponds to part of a program aimed at upgrading oil obtained by pyrolysis of biomass by hydrotreatment (hydrodeoxygenation HDO). CoMo sulfide catalysts, nonsupported, supported on different supports (alumina, carbon, silica), or modified by K or Pt, were used. The authors used a model reacting mixture containing compounds representative of the molecules that must react to permit a primary stabilisation of the pyrolytic oil: 4-methy lacetophenone (4-MA), diethylsebacate (DES), and guaiacol (GUA). In the reaction of the carbonyl group of the 4-MA it is shown that no important role is played by any acid-base mechanism; dispersion determines the activity. Acidity of the support influences the formation of active sites for decarboxylation and hydrogenation of the carboxyl group of DES. It was confirmed that guaiacol-type molecules lead to coking reactions. The role of acidity in the mechanism of these reactions is confirmed, but the modifications made in the catalysts in this work are still not sufficient to control coke deposition. The catalysts supported on carbon lead to the direct elimination of the methoxyl group of the guaiacol. Carbon, on the whole, seems to be a promising support. This work suggests that appropriate modifications of the hydrotreating catalysts can lead to a more effective process for stabilisation of the bio-oils by reaction with hydrogen. 55 refs., 3 figs., 5 tabs.

  7. Precision Measurement of the<mo stretchy='false'>(mo>e<mo>+mo><mo>+e- stretchy='false'>)mo>Flux in Primary Cosmic Rays from 0.5GeV to 1TeV with the Alpha Magnetic Spectrometer on the International Space Station

    SciTech Connect (OSTI)

    Aguilar, M.; Aisa, D.; Alpat, B.; Alvino, A.; Ambrosi, G.; Andeen, K.; Arruda, L.; Attig, N.; Azzarello, P.; Bachlechner, A.; Barao, F.; Barrau, A.; Barrin, L.; Bartoloni, A.; Basara, L.; Battarbee, M.; Battiston, R.; Bazo, J.; Becker, U.; Behlmann, M.; Beischer, B.; Berdugo, J.; Bertucci, B.; Bigongiari, G.; Bindi, V.; Bizzaglia, S.; Bizzarri, M.; Boella, G.; de Boer, W.; Bollweg, K.; Bonnivard, V.; Borgia, B.; Borsini, S.; Boschini, M.?J.; Bourquin, M.; Burger, J.; Cadoux, F.; Cai, X.?D.; Capell, M.; Caroff, S.; Casaus, J.; Cascioli, V.; Castellini, G.; Cernuda, I.; Cervelli, F.; Chae, M.?J.; Chang, Y.?H.; Chen, A.?I.; Chen, H.; Cheng, G.?M.; Chen, H.?S.; Cheng, L.; Chikanian, A.; Chou, H.?Y.; Choumilov, E.; Choutko, V.; Chung, C.?H.; Clark, C.; Clavero, R.; Coignet, G.; Consolandi, C.; Contin, A.; Corti, C.; Coste, B.; Crispoltoni, M.; Cui, Z.; Dai, M.; Delgado, C.; Della Torre, S.; Demirkz, M.?B.; Derome, L.; Di Falco, S.; Di Masso, L.; Dimiccoli, F.; Daz, C.; von Doetinchem, P.; Donnini, F.; Du, W.?J.; Duranti, M.; DUrso, D.; Eline, A.; Eppling, F.?J.; Eronen, T.; Fan, Y.?Y.; Farnesini, L.; Feng, J.; Fiandrini, E.; Fiasson, A.; Finch, E.; Fisher, P.; Galaktionov, Y.; Gallucci, G.; Garca, B.; Garca-Lpez, R.; Gargiulo, C.; Gast, H.; Gebauer, I.; Gervasi, M.; Ghelfi, A.; Gillard, W.; Giovacchini, F.; Goglov, P.; Gong, J.; Goy, C.; Grabski, V.; Grandi, D.; Graziani, M.; Guandalini, C.; Guerri, I.; Guo, K.?H.; Habiby, M.; Haino, S.; Han, K.?C.; He, Z.?H.; Heil, M.; Hoffman, J.; Hsieh, T.?H.; Huang, Z.?C.; Huh, C.; Incagli, M.; Ionica, M.; Jang, W.?Y.; Jinchi, H.; Kanishev, K.; Kim, G.?N.; Kim, K.?S.; Kirn, Th.; Kossakowski, R.; Kounina, O.; Kounine, A.; Koutsenko, V.; Krafczyk, M.?S.; Kunz, S.; La Vacca, G.; Laudi, E.; Laurenti, G.; Lazzizzera, I.; Lebedev, A.; Lee, H.?T.; Lee, S.?C.; Leluc, C.; Li, H.?L.; Li, J.?Q.; Li, Q.; Li, Q.; Li, T.?X.; Li, W.; Li, Y.; Li, Z.?H.; Li, Z.?Y.; Lim, S.; Lin, C.?H.; Lipari, P.; Lippert, T.; Liu, D.; Liu, H.; Lomtadze, T.; Lu, M.?J.; Lu, Y.?S.; Luebelsmeyer, K.; Luo, F.; Luo, J.?Z.; Lv, S.?S.; Majka, R.; Malinin, A.; Ma, C.; Marn, J.; Martin, T.; Martnez, G.; Masi, N.; Maurin, D.; Menchaca-Rocha, A.; Meng, Q.; Mo, D.?C.; Morescalchi, L.; Mott, P.; Mller, M.; Ni, J.?Q.; Nikonov, N.; Nozzoli, F.; Nunes, P.; Obermeier, A.; Oliva, A.; Orcinha, M.; Palmonari, F.; Palomares, C.; Paniccia, M.; Papi, A.; Pauluzzi, M.; Pedreschi, E.; Pensotti, S.; Pereira, R.; Pilo, F.; Piluso, A.; Pizzolotto, C.; Plyaskin, V.; Pohl, M.; Poireau, V.; Postaci, E.; Putze, A.; Quadrani, L.; Qi, X.?M.; Rih, T.; Rancoita, P.?G.; Rapin, D.; Ricol, J.?S.; Rodrguez, I.; Rosier-Lees, S.; Rozhkov, A.; Rozza, D.; Sagdeev, R.; Sandweiss, J.; Saouter, P.; Sbarra, C.; Schael, S.; Schmidt, S.?M.; Schuckardt, D.; Schulz von Dratzig, A.; Schwering, G.; Scolieri, G.; Seo, E.?S.; Shan, B.?S.; Shan, Y.?H.; Shi, J.?Y.; Shi, X.?Y.; Shi, Y.?M.; Siedenburg, T.; Son, D.; Spada, F.; Spinella, F.; Sun, W.; Sun, W.?H.; Tacconi, M.; Tang, C.?P.; Tang, X.?W.; Tang, Z.?C.; Tao, L.; Tescaro, D.; Ting, Samuel C.?C.; Ting, S.?M.; Tomassetti, N.; Torsti, J.; Trko?lu, C.; Urban, T.; Vagelli, V.; Valente, E.; Vannini, C.; Valtonen, E.; Vaurynovich, S.; Vecchi, M.; Velasco, M.; Vialle, J.?P.; Wang, L.?Q.; Wang, Q.?L.; Wang, R.?S.; Wang, X.; Wang, Z.?X.; Weng, Z.?L.; Whitman, K.; Wienkenhver, J.; Wu, H.; Xia, X.; Xie, M.; Xie, S.; Xiong, R.?Q.; Xin, G.?M.; Xu, N.?S.; Xu, W.; Yan, Q.; Yang, J.; Yang, M.; Ye, Q.?H.; Yi, H.; Yu, Y.?J.; Yu, Z.?Q.; Zeissler, S.; Zhang, J.?H.; Zhang, M.?T.; Zhang, X.?B.; Zhang, Z.; Zheng, Z.?M.; Zhuang, H.?L.; Zhukov, V.; Zichichi, A.; Zimmermann, N.; Zuccon, P.; Zurbach, C.

    2014-11-26

    We present a measurement of the cosmic ray (e++e-) flux in the range 0.5 GeV to 1 TeV based on the analysis of 10.6 million (e++e-) events collected by AMS. The statistics and the resolution of AMS provide a precision measurement of the flux. The flux is smooth and reveals new and distinct information. Above 30.2 GeV, the flux can be described by a single power law with a spectral index ?= -3.170 0.008(stat+syst) 0.008(energy scale).

  8. State","County","NOAA Climate Division (Number)","NOAA Climate...

    U.S. Energy Information Administration (EIA) Indexed Site

    CENTRAL",3 "KS","SHERIDAN",1,"NORTHWEST",2 "KS","SHERMAN",1,"NORTHWEST",2 "KS","SMITH",2,"NORTH CENTRAL",2 "KS","STAFFORD",8,"SOUTH CENTRAL",3 "KS","STANTON",7,"SOUTHWEST",...

  9. Resonant ?<mo>+? stretchy='false'>?mo>?<mo>+>?0 amplitude from Quantum Chromodynamics

    SciTech Connect (OSTI)

    Briceo, Ral A.; Dudek, Jozef J.; Edwards, Robert G.; Shultz, Christian J.; Thomas, Christopher E.; Wilson, David J.

    2015-12-08

    We present the first ab initio calculation of a radiative transition of a hadronic resonance within Quantum Chromodynamics (QCD). We compute the amplitude for $\\pi\\pi \\to \\pi\\gamma^\\star$, as a function of the energy of the $\\pi\\pi$ pair and the virtuality of the photon, in the kinematic regime where $\\pi\\pi$ couples strongly to the unstable $\\rho$ resonance. This exploratory calculation is performed using a lattice discretization of QCD with quark masses corresponding to $m_\\pi \\approx 400$ MeV. As a result, we obtain a description of the energy dependence of the transition amplitude, constrained at 48 kinematic points, that we can analytically continue to the $\\rho$ pole and identify from its residue the $\\rho \\to \\pi\\gamma^\\star$ form-factor.

  10. First-Principles Calculations, Electrochemical and X-ray Absorption Studies of Li-Ni-PO4 Surface-Treated xLi2MnO3 (1 x)LiMO2 (M = Mn, Ni, Co) Electrodes for Li-Ion Batteries

    SciTech Connect (OSTI)

    Wolverton, Christopher; Croy, J R; Balasubramanian, M; Kang, Sun-Ho; Lopez-Rivera, C. M.; Thackeray, Michael M.

    2012-01-01

    It has been previously hypothesized that the enhanced rate capability of Li-Ni-PO{sub 4}-treated xLi{sub 2}MnO{sub 3} {center_dot} (1-x)LiMO{sub 2} positive electrodes (M = Mn, Ni, Co) in Li-ion batteries might be associated with a defect Ni-doped Li{sub 3}PO{sub 4} surface structure [i.e., Li{sub 3-2y}Ni{sub y}PO{sub 4} (0 < y < 1)], thereby promoting fast Li{sup +}-ion conduction at the xLi{sub 2}MnO{sub 3} {center_dot} (1-x)LiMO{sub 2} particle surface. In this paper, the solubility of divalent metals (Fe, Mn, Ni, Mg) in {gamma}-Li{sub 3}PO{sub 4} is predicted with the first-principles GGA+U method in an effort to understand the enhanced rate capability. The predicted solubility (x) is extremely small; this finding is consistent with experimental evidence: 1) X-ray diffraction data obtained from Li-Ni-PO{sub 4}-treated xLi{sub 2}MnO{sub 3} {center_dot} (1-x)LiMO{sub 2} electrodes that show that, after annealing at 550 C, a Li{sub 3}PO{sub 4}-like structure forms as a second phase at the electrode particle surface, and 2) X-ray absorption spectroscopy, which indicate that the nickel ions are accommodated in the transition metal layers of the Li{sub 2}MnO{sub 3} component during the annealing process. However, electrochemical studies of Li{sub 3-2y}Ni{sub y}PO{sub 4}-treated xLi{sub 2}MnO{sub 3} {center_dot} (1-x)LiMO{sub 2} electrodes indicate that their rate capability increases as a function of y over the range y = 0 (Li{sub 3}PO{sub 4}) to y = 1 (LiNiPO{sub 4}), strongly suggesting that, at some level, the nickel ions play a role in reducing electrochemical impedance and increasing electrode stability at the electrode particle surface.

  11. Arbitration_Guidance_for_MO_Contractors.pdf

    Office of Environmental Management (EM)

  12. Insurance under M&O Contracts

    National Nuclear Security Administration (NNSA)

    ... * No Special Nuclear Material protection requirements * Primary protection for Classified Information via Physical and Cyber means * NewModern concepts employed at NSC-KC and ...

  13. Quantification of corrosion resistance of a new-class of criticality control materials: thermal-spray coatings of high-boron iron-based amorphous metals - Fe49.7Cr17.7Mn1.9Mo7.4W1.6B15.2C3.8Si2.4

    SciTech Connect (OSTI)

    Farmer, J C; Choi, J S; Shaw, C K; Rebak, R; Day, S D; Lian, T; Hailey, P; Payer, J H; Branagan, D J; Aprigliano, L F

    2007-03-28

    An iron-based amorphous metal, Fe{sub 49.7}Cr{sub 17.7}Mn{sub 1.9}Mo{sub 7.4}W{sub 1.6}B{sub 15.2}C{sub 3.8}Si{sub 2.4} (SAM2X5), with very good corrosion resistance was developed. This material was produced as a melt-spun ribbon, as well as gas atomized powder and a thermal-spray coating. Chromium (Cr), molybdenum (Mo) and tungsten (W) provided corrosion resistance, and boron (B) enabled glass formation. The high boron content of this particular amorphous metal made it an effective neutron absorber, and suitable for criticality control applications. Earlier studies have shown that ingots and melt-spun ribbons of these materials have good passive film stability in these environments. Thermal spray coatings of these materials have now been produced, and have undergone a variety of corrosion testing, including both atmospheric and long-term immersion testing. The modes and rates of corrosion have been determined in the various environments, and are reported here.

  14. Study of CP violation in Dalitz-plot analyses of B0 to K K-KS, B to K K-K , and B to KSKSK

    SciTech Connect (OSTI)

    Lees, J.P.

    2012-03-20

    We perform amplitude analyses of the decays B{sup 0} {yields} K{sup +}K{sup -}K{sub s}{sup 0}, B{sup +} {yields} K{sup +}K{sup -}K{sup +}, and B{sup +} {yields}, and measure CP-violating parameters and partial branching fractions. The results are based on a data sample of approximately 470 x 10{sup 6} B{bar B} decays, collected with the BABAR detector at the PEP-II asymmetric-energy B factory at the SLAC National Accelerator Laboratory. For B{sup +} {yields} K{sup +}K{sup -}K{sup +}, we find a direct CP asymmetry in B{sup +} {yields} {phi}(1020)K{sup +} of A{sub CP} = (12.8 {+-} 4.4 {+-} 1.3)%, which differs from zero by 2.8{sigma}. For B{sup 0} {yields} K{sup +}K{sup -}K{sub s}{sup 0}, we measure the CP-violating phase {beta}{sub eff} ({phi}(1020)K{sub s}{sup 0}) = (21 {+-} 6 {+-} 2){sup o}. For B{sup +} {yields} K{sub s}{sup 0}K{sub s}{sup 0}K{sup +}, we measure an overall direct CP asymmetry of A{sub CP} = (4{sub -5}{sup +4} {+-} 2)%. We also perform an angular-moment analysis of the three channels, and determine that the f{sub X}(1500) state can be described well by the sum of the resonances f{sub 0}(1500), f{prime}{sub 2}(1525), and f{sub 0}(1710).

  15. Lattice dynamics of BaFe2X3<mo>(X=>S<mo>,>Se<mo>)> compounds

    SciTech Connect (OSTI)

    Popovi?, Z. V.; ?epanovi?, M.; Lazarevi?, N.; Opa?i?, M.; Radonji?, M. M.; Tanaskovi?, D.; Lei, Hechang; Petrovic, C.

    2015-02-27

    We present the Raman scattering spectra of the S=2 spin ladder compounds BaFe?X? (X=S,Se) in a temperature range between 20 and 400 K. Although the crystal structures of these two compounds are both orthorhombic and very similar, they are not isostructural. The unit cell of BaFe?S? (BaFe?Se?) is base-centered Cmcm (primitive Pnma), giving 18 (36) modes to be observed in the Raman scattering experiment. We have detected almost all Raman active modes, predicted by factor group analysis, which can be observed from the cleavage planes of these compounds. Assignment of the observed Raman modes of BaFe?S(Se)? is supported by the lattice dynamics calculations. The antiferromagnetic long-range spin ordering in BaFe?Se? below TN=255K leaves a fingerprint both in the A1g and B3g phonon mode linewidth and energy.

  16. Observation of a new charged charmoniumlike state inB<mo stretchy='false'>mo>0<mo stretchy='false'>?mo>J<mo>/mo>?K<mo>-mo>?<mo>+>decays

    SciTech Connect (OSTI)

    Chilikin, K.; Mizuk, R.; Adachi, I.; Aihara, H.; Al Said, S.; Arinstein, K.; Asner, D.?M.; Aulchenko, V.; Aushev, T.; Ayad, R.; Aziz, T.; Bakich, A.?M.; Bansal, V.; Bondar, A.; Bonvicini, G.; Bozek, A.; Bra?ko, M.; Browder, T.?E.; ?ervenkov, D.; Chekelian, V.; Chen, A.; Cheon, B.?G.; Chistov, R.; Cho, K.; Chobanova, V.; Choi, S.-K.; Choi, Y.; Cinabro, D.; Danilov, M.; Doleal, Z.; Drsal, Z.; Drutskoy, A.; Dutta, K.; Eidelman, S.; Epifanov, D.; Farhat, H.; Fast, J.?E.; Ferber, T.; Frost, O.; Gaur, V.; Gabyshev, N.; Ganguly, S.; Garmash, A.; Gillard, R.; Goh, Y.?M.; Golob, B.; Grzymkowska, O.; Haba, J.; Hara, T.; Hayasaka, K.; Hayashii, H.; He, X.?H.; Hou, W.-S.; Huschle, M.; Hyun, H.?J.; Ishikawa, A.; Itoh, R.; Iwasaki, Y.; Jaegle, I.; Joo, K.?K.; Julius, T.; Kawasaki, T.; Kiesling, C.; Kim, D.?Y.; Kim, H.?J.; Kim, J.?H.; Kim, M.?J.; Kim, Y.?J.; Kinoshita, K.; Ko, B.?R.; Korpar, S.; Krian, P.; Krokovny, P.; Kuhr, T.; Kuzmin, A.; Kwon, Y.-J.; Lange, J.?S.; Li, Y.; Li Gioi, L.; Libby, J.; Liu, Y.; Liventsev, D.; Lukin, P.; Miyabayashi, K.; Miyata, H.; Mohanty, G.?B.; Moll, A.; Mori, T.; Mussa, R.; Nakano, E.; Nakao, M.; Nanut, T.; Natkaniec, Z.; Nedelkovska, E.; Nisar, N.?K.; Nishida, S.; Ogawa, S.; Okuno, S.; Olsen, S.?L.; Pakhlov, P.; Pakhlova, G.; Park, C.?W.; Park, H.; Pedlar, T.?K.; Petri?, M.; Piilonen, L.?E.; Ribel, E.; Ritter, M.; Rostomyan, A.; Sakai, Y.; Sandilya, S.; Santelj, L.; Sanuki, T.; Sato, Y.; Savinov, V.; Schneider, O.; Schnell, G.; Schwanda, C.; Seon, O.; Shebalin, V.; Shen, C.?P.; Shibata, T.-A.; Shiu, J.-G.; Shwartz, B.; Sibidanov, A.; Simon, F.; Sohn, Y.-S.; Sokolov, A.; Solovieva, E.; Stari?, M.; Steder, M.; Sumisawa, K.; Sumiyoshi, T.; Tamponi, U.; Tanida, K.; Tatishvili, G.; Teramoto, Y.; Thorne, F.; Trabelsi, K.; Uchida, M.; Uehara, S.; Uglov, T.; Unno, Y.; Uno, S.; Urquijo, P.; Van Hulse, C.; Vanhoefer, P.; Varner, G.; Vinokurova, A.; Wagner, M.?N.; Wang, C.?H.; Wang, M.-Z.; Wang, P.; Wang, X.?L.; Watanabe, Y.; Wehle, S.; Williams, K.?M.; Won, E.; Yamaoka, J.; Yashchenko, S.; Zhang, Z.?P.; Zhilich, V.; Zhulanov, V.; Zupanc, A.

    2014-12-16

    We present the results of an amplitude analysis of B0?J/?K-?+ decays. A new charged charmoniumlike state Zc(4200)+ decaying to J/??+ is observed with a significance of 6.2?. The mass and width of the Zc(4200)+ are 4196+31-29+17-13 MeV/c2 and 370+70-70+70-132 MeV, respectively; the preferred assignment of the quantum numbers is JP=1+. In addition, we find evidence for Zc(4430)+?J/??+. The analysis is based on a 711 fb-1 data sample collected by the Belle detector at the asymmetric-energy e+e- collider KEKB.

  17. Measurement of the target-normal single-spin asymmetry in quasielastic scattering from the reaction He3<mo stretchy='false'>?mo> stretchy='false'>(mo>e<mo>,mo>e<mo>' stretchy='false'>)mo>

    SciTech Connect (OSTI)

    Zhang, Y. -W.; Long, E.; Mihovilovi?, M.; Jin, G.; Allada, K.; Anderson, B.; Annand, J. R. M.; Averett, T.; Ayerbe-Gayoso, C.; Boeglin, W.; Bradshaw, P.; Camsonne, A.; Canan, M.; Cates, G. D.; Chen, C.; Chen, J. P.; Chudakov, E.; De Leo, R.; Deng, X.; Deur, A.; Dutta, C.; El Fassi, L.; Flay, D.; Frullani, S.; Garibaldi, F.; Gao, H.; Gilad, S.; Gilman, R.; Glamazdin, O.; Golge, S.; Gomez, J.; Hansen, O.; Higinbotham, D. W.; Holmstrom, T.; Huang, J.; Ibrahim, H.; de Jager, C. W.; Jensen, E.; Jiang, X.; John, J. St.; Jones, M.; Kang, H.; Katich, J.; Khanal, H. P.; King, P.; Korsch, W.; LeRose, J.; Lindgren, R.; Lu, H. -J.; Luo, W.; Markowitz, P.; Meziane, M.; Michaels, R.; Moffit, B.; Monaghan, P.; Muangma, N.; Nanda, S.; Norum, B. E.; Pan, K.; Parno, D.; Piasetzky, E.; Posik, M.; Punjabi, V.; Puckett, A. J. R.; Qian, X.; Qiang, Y.; Qiu, X.; Riordan, S.; Ron, G.; Saha, A.; Sawatzky, B.; Schiavilla, R.; Schoenrock, B.; Shabestari, M.; Shahinyan, A.; irca, S.; Subedi, R.; Sulkosky, V.; Tobias, W. A.; Tireman, W.; Urciuoli, G. M.; Wang, D.; Wang, K.; Wang, Y.; Watson, J.; Wojtsekhowski, B.; Ye, Z.; Zhan, X.; Zhang, Y.; Zheng, X.; Zhao, B.; Zhu, L.

    2015-10-22

    We report the first measurement of the target single-spin asymmetry, Ay, in quasi-elastic scattering from the inclusive reaction 3He? (e,e') on a 3He gas target polarized normal to the lepton scattering plane. Assuming time-reversal invariance, this asymmetry is strictly zero for one-photon exchange. A non-zero Ay can arise from the interference between the one- and two-photon exchange processes which is sensitive to the details of the sub-structure of the nucleon. An experiment recently completed at Jefferson Lab yielded asymmetries with high statistical precision at Q2= 0.13, 0.46 and 0.97 GeV2. These measurements demonstrate, for the first time, that the 3He asymmetry is clearly non-zero and negative with a statistical significance of (8-10)?. Using measured proton-to-3He cross-section ratios and the effective polarization approximation, neutron asymmetries of -(1-3)% were obtained. The neutron asymmetry at high Q2 is related to moments of the Generalized Parton Distributions (GPDs). Our measured neutron asymmetry at Q2=0.97 GeV2 agrees well with a prediction based on two-photon exchange using a GPD model and in addition provides a new independent constraint on these distributions.

  18. ARM - VAP Product - 30baebbr

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Hillsboro, KS (Extended) retired SGP E4 Browse Data Plevna, KS (Extended) retired SGP E7 Browse Data Elk Falls, KS (Extended) retired SGP E8 Browse Data Coldwater, KS (Extended)...

  19. ALL GRADE 5 AND GRADE 8 FASTENERS ...

    Energy Savers [EERE]

    WITH THE FOLLOWING HEADMARKS: MARK A325 KS A325 KS A325 KS A325 KS KEY: CA-Canada, JP-Japan, TW-Taiwan, YU-Yugoslavia Type 1 Type 2 Type 3 Headmarkings are usually raised -...

  20. A novel organicinorganic hybrid with Anderson type polyanions as building blocks: (C{sub 6}H{sub 10}N{sub 3}O{sub 2}){sub 2}Na(H{sub 2}O){sub 2}[Al(OH){sub 6}Mo{sub 6}O{sub 18}]6H{sub 2}O

    SciTech Connect (OSTI)

    Thabet, Safa; Ayed, Brahim; Haddad, Amor

    2012-11-15

    Graphical abstract: Display Omitted Highlights: ? Synthesis of a novel inorganicorganic hybrid compound based on Anderson polyoxomolybdates. ? Characterization by X-ray diffraction, IR and UVVis spectroscopies of the new compound. ? Potential applications in catalysis, biochemical analysis and electrical conductivity of the organicinorganic compound. -- Abstract: A new organicinorganic hybrid compound based on Anderson polyoxomolybdates, (C{sub 6}H{sub 10}N{sub 3}O{sub 2}){sub 2}Na(H{sub 2}O){sub 2}[Al(OH){sub 6}Mo{sub 6}O{sub 18}]6H{sub 2}O (1) have been isolated by the conventional solution method and characterized by single-crystal X-ray diffraction, infrared, ultraviolet spectroscopy and Thermogravimetric Analysis (TGA). This compound crystallized in the triclinic system, space group P?1, with a = 94.635(1) ?, b = 10.958(1) ?, c = 11.602(1) ?, ? = 67.525(1), ? = 71.049(1), ? = 70.124(1) and Z = 1. The crystal structures of the compounds exhibit three-dimensional supramolecular assembly based on the extensive hydrogen bonding interactions between organic cations, sodium cations, water molecules and Anderson polyoxoanions. The infrared spectrum fully confirms the X-ray crystal structure and the UV spectrum of the title compound exhibits an absorption peak at 210 nm.