National Library of Energy BETA

Sample records for kinetics chamber general

  1. General non-minimal kinetic coupling to gravity

    SciTech Connect (OSTI)

    Granda, L.N.; Cardona, W. E-mail: wilalbca@univalle.edu.co

    2010-07-01

    We study a model of scalar field with a general non-minimal kinetic coupling to itself and to the curvature, as a source of dark energy, and analyze the cosmological dynamics of this model and the issue of accelerated expansion. Solutions giving rise to power-law expansion have been found. The dynamical equation of state is studied for the two cases, without and with free kinetic term . In the first case, a behavior very close to that of the cosmological constant was found. In the second case, a solution was found, which match the current phenomenology of the dark energy. The model shows a rich variety of dynamical scenarios.

  2. Target Chamber

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Diagnostic ports are about one-half meter in diameter and are generally concentrated around the "waist" of the target chamber Target handling systems precisely position the target ...

  3. Exposure chamber

    DOE Patents [OSTI]

    Moss, Owen R.

    1980-01-01

    A chamber for exposing animals, plants, or materials to air containing gases or aerosols is so constructed that catch pans for animal excrement, for example, serve to aid the uniform distribution of air throughout the chamber instead of constituting obstacles as has been the case in prior animal exposure chambers. The chamber comprises the usual imperforate top, bottom and side walls. Within the chamber, cages and their associated pans are arranged in two columns. The pans are spaced horizontally from the walls of the chamber in all directions. Corresponding pans of the two columns are also spaced horizontally from each other. Preferably the pans of one column are also spaced vertically from corresponding pans of the other column. Air is introduced into the top of the chamber and withdrawn from the bottom. The general flow of air is therefore vertical. The effect of the horizontal pans is based on the fact that a gas flowing past the edge of a flat plate that is perpendicular to the flow forms a wave on the upstream side of the plate. Air flows downwardly between the chamber walls and the outer edges of the pan. It also flows downwardly between the inner edges of the pans of the two columns. It has been found that when the air carries aerosol particles, these particles are substantially uniformly distributed throughout the chamber.

  4. Flow chamber

    DOE Patents [OSTI]

    Morozov, Victor (Manassas, VA)

    2011-01-18

    A flow chamber having a vacuum chamber and a specimen chamber. The specimen chamber may have an opening through which a fluid may be introduced and an opening through which the fluid may exit. The vacuum chamber may have an opening through which contents of the vacuum chamber may be evacuated. A portion of the flow chamber may be flexible, and a vacuum may be used to hold the components of the flow chamber together.

  5. Exposure chamber

    DOE Patents [OSTI]

    Moss, Owen R.; Briant, James K.

    1983-01-01

    An exposure chamber includes an imperforate casing having a fluid inlet at the top and an outlet at the bottom. A single vertical series of imperforate trays is provided. Each tray is spaced on all sides from the chamber walls. Baffles adjacent some of the trays restrict and direct the flow to give partial flow back and forth across the chambers and downward flow past the lowermost pan adjacent a central plane of the chamber.

  6. Wire chamber

    DOE Patents [OSTI]

    Atac, Muzaffer

    1989-01-01

    A wire chamber or proportional counter device, such as Geiger-Mueller tube or drift chamber, improved with a gas mixture providing a stable drift velocity while eliminating wire aging caused by prior art gas mixtures. The new gas mixture is comprised of equal parts argon and ethane gas and having approximately 0.25% isopropyl alcohol vapor.

  7. Ionization chamber

    DOE Patents [OSTI]

    Walenta, Albert H. (Port Jefferson Station, NY)

    1981-01-01

    An ionization chamber has separate drift and detection regions electrically isolated from each other by a fine wire grid. A relatively weak electric field can be maintained in the drift region when the grid and another electrode in the chamber are connected to a high voltage source. A much stronger electric field can be provided in the detection region by connecting wire electrodes therein to another high voltage source. The detection region can thus be operated in a proportional mode when a suitable gas is contained in the chamber. High resolution output pulse waveforms are provided across a resistor connected to the detection region anode, after ionizing radiation enters the drift region and ionize the gas.

  8. A reaction-based paradigm to model reactive chemical transport in groundwater with general kinetic and equilibrium reactions

    SciTech Connect (OSTI)

    Zhang, Fan; Yeh, Gour-Tsyh; Parker, Jack C; Brooks, Scott C; Pace, Molly; Kim, Young Jin; Jardine, Philip M; Watson, David B

    2007-01-01

    This paper presents a reaction-based water quality transport model in subsurface flow systems. Transport of chemical species with a variety of chemical and physical processes is mathematically described by M partial differential equations (PDEs). Decomposition via Gauss-Jordan column reduction of the reaction network transforms M species reactive transport equations into two sets of equations: a set of thermodynamic equilibrium equations representing NE equilibrium reactions and a set of reactive transport equations of M-NE kinetic-variables involving no equilibrium reactions (a kinetic-variable is a linear combination of species). The elimination of equilibrium reactions from reactive transport equations allows robust and efficient numerical integration. The model solves the PDEs of kinetic-variables rather than individual chemical species, which reduces the number of reactive transport equations and simplifies the reaction terms in the equations. A variety of numerical methods are investigated for solving the coupled transport and reaction equations. Simulation comparisons with exact solutions were performed to verify numerical accuracy and assess the effectiveness of various numerical strategies to deal with different application circumstances. Two validation examples involving simulations of uranium transport in soil columns are presented to evaluate the ability of the model to simulate reactive transport with complex reaction networks involving both kinetic and equilibrium reactions.

  9. Two chamber reaction furnace

    DOE Patents [OSTI]

    Blaugher, R.D.

    1998-05-05

    A vertical two chamber reaction furnace is described. The furnace comprises a lower chamber having an independently operable first heating means for heating the lower chamber and a gas inlet means for admitting a gas to create an ambient atmosphere, and an upper chamber disposed above the lower chamber and having an independently operable second heating means for heating the upper chamber. Disposed between the lower chamber and the upper chamber is a vapor permeable diffusion partition. The upper chamber has a conveyor means for conveying a reactant there through. Of particular importance is the thallinating of long-length thallium-barium-calcium-copper oxide (TBCCO) or barium-calcium-copper oxide (BCCO) precursor tapes or wires conveyed through the upper chamber to thereby effectuate the deposition of vaporized thallium (being so vaporized as the first reactant in the lower chamber at a temperature between about 700 C and 800 C) on TBCCO or BCCO tape or wire (the second reactant) at its simultaneous annealing temperature in the upper chamber of about 800 to 950 C to thereby replace thallium oxide lost from TBCCO tape or wire because of the high annealing temperature or to deposit thallium on BCCO tape or wire. Continuously moving the tape or wire provides a single-step process that effectuates production of long-length TBCCO superconducting product. 2 figs.

  10. Sleeve reaction chamber system

    DOE Patents [OSTI]

    Northrup, M. Allen (Berkeley, CA); Beeman, Barton V. (San Mateo, CA); Benett, William J. (Livermore, CA); Hadley, Dean R. (Manteca, CA); Landre, Phoebe (Livermore, CA); Lehew, Stacy L. (Livermore, CA); Krulevitch, Peter A. (Pleasanton, CA)

    2009-08-25

    A chemical reaction chamber system that combines devices such as doped polysilicon for heating, bulk silicon for convective cooling, and thermoelectric (TE) coolers to augment the heating and cooling rates of the reaction chamber or chambers. In addition the system includes non-silicon-based reaction chambers such as any high thermal conductivity material used in combination with a thermoelectric cooling mechanism (i.e., Peltier device). The heat contained in the thermally conductive part of the system can be used/reused to heat the device, thereby conserving energy and expediting the heating/cooling rates. The system combines a micromachined silicon reaction chamber, for example, with an additional module/device for augmented heating/cooling using the Peltier effect. This additional module is particularly useful in extreme environments (very hot or extremely cold) where augmented heating/cooling would be useful to speed up the thermal cycling rates. The chemical reaction chamber system has various applications for synthesis or processing of organic, inorganic, or biochemical reactions, including the polymerase chain reaction (PCR) and/or other DNA reactions, such as the ligase chain reaction.

  11. Kathy Chambers | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Chambers - Senior Science and Technical Information Specialist, OSTI Most Recent by Kathy Chambers A Shining Example of Dr. King's legacy January 9...

  12. Automated soil gas monitoring chamber

    DOE Patents [OSTI]

    Edwards, Nelson T.; Riggs, Jeffery S.

    2003-07-29

    A chamber for trapping soil gases as they evolve from the soil without disturbance to the soil and to the natural microclimate within the chamber has been invented. The chamber opens between measurements and therefore does not alter the metabolic processes that influence soil gas efflux rates. A multiple chamber system provides for repetitive multi-point sampling, undisturbed metabolic soil processes between sampling, and an essentially airtight sampling chamber operating at ambient pressure.

  13. Improved wire chamber

    DOE Patents [OSTI]

    Atac, M.

    1987-05-12

    An improved gas mixture for use with proportional counter devices, such as Geiger-Mueller tubes and drift chambers. The improved gas mixture provides a stable drift velocity while eliminating wire aging caused by prior art gas mixtures. The new gas mixture is comprised of equal parts argon and ethane gas and having approximately 0.25% isopropyl alcohol vapor. 2 figs.

  14. Multi-chamber deposition system

    DOE Patents [OSTI]

    Jacobson, Richard L.; Jeffrey, Frank R.; Westerberg, Roger K.

    1989-06-27

    A system for the simultaneous deposition of different coatings onto a thin web within a large volume vacuum chamber is disclosed which chamber is provided with a plurality of deposition chambers in which the different layers are deposited onto the film as its moves from a supply roll to a finished take-up roll of coated web. The deposition chambers provided within the large vacuum chamber are provided with separate seals which minimize back diffusion of any dopant gas from adjacent deposition chambers.

  15. Multi-chamber deposition system

    DOE Patents [OSTI]

    Jacobson, Richard L.; Jeffrey, Frank R.; Westerberg, Roger K.

    1989-10-17

    A system for the simultaneous deposition of different coatings onto a thin web within a large volume vacuum chamber is disclosed which chamber is provided with a plurality of deposition chambers in which the different layers are deposited onto the film as its moves from a supply roll to a finished take-up roll of coated web. The deposition chambers provided within the large vacuum chamber are provided with separate seals which minimize back diffusion of any dopant gas from adjacent deposition chambers.

  16. Miniature reaction chamber and devices incorporating same

    DOE Patents [OSTI]

    Mathies, Richard A. (Moraga, CA); Woolley, Adam T. (Albany, CA)

    2000-10-17

    The present invention generally relates to miniaturized devices for carrying out and controlling chemical reactions and analyses. In particular, the present invention provides devices which have miniature temperature controlled reaction chambers for carrying out a variety of synthetic and diagnostic applications, such as PCR amplification, nucleic acid hybridization, chemical labeling, nucleic acid fragmentation and the like.

  17. Three chamber negative ion source

    DOE Patents [OSTI]

    Leung, Ka-Ngo (Hercules, CA); Ehlers, Kenneth W. (Alamo, CA); Hiskes, John R. (Livermore, CA)

    1985-01-01

    A negative ion vessel is divided into an excitation chamber, a negative ionization chamber and an extraction chamber by two magnetic filters. Input means introduces neutral molecules into a first chamber where a first electron discharge means vibrationally excites the molecules which migrate to a second chamber. In the second chamber a second electron discharge means ionizes the molecules, producing negative ions which are extracted into or by a third chamber. A first magnetic filter prevents high energy electrons from entering the negative ionization chamber from the excitation chamber. A second magnetic filter prevents high energy electrons from entering the extraction chamber from the negative ionizing chamber. An extraction grid at the end of the negative ion vessel attracts negative ions into the third chamber and accelerates them. Another grid, located adjacent to the extraction grid, carries a small positive voltage in order to inhibit positive ions from migrating into the extraction chamber and contour the plasma potential. Additional electrons can be suppressed from the output flux using ExB forces provided by magnetic field means and the extractor grid electric potential.

  18. Vertical two chamber reaction furnace

    DOE Patents [OSTI]

    Blaugher, R.D.

    1999-03-16

    A vertical two chamber reaction furnace is disclosed. The furnace comprises a lower chamber having an independently operable first heating means for heating the lower chamber and a gas inlet means for admitting a gas to create an ambient atmosphere, and an upper chamber disposed above the lower chamber and having an independently operable second heating means for heating the upper chamber. Disposed between the lower chamber and the upper chamber is a vapor permeable diffusion partition. The upper chamber has a conveyor means for conveying a reactant there through. Of particular importance is the thallinating of long-length thallium-barium-calcium copper oxide (TBCCO) or barium-calcium-copper oxide (BCCO) precursor tapes or wires conveyed through the upper chamber to thereby effectuate the deposition of vaporized thallium (being so vaporized as the first reactant in the lower chamber at a temperature between about 700 and 800 C) on TBCCO or BCCO tape or wire (the second reactant) at its simultaneous annealing temperature in the upper chamber of about 800 to 950 C to thereby replace thallium oxide lost from TBCCO tape or wire because of the high annealing temperature or to deposit thallium on BCCO tape or wire. Continuously moving the tape or wire provides a single-step process that effectuates production of long-length TBCCO superconducting product. 2 figs.

  19. Multi-anode ionization chamber

    DOE Patents [OSTI]

    Bolotnikov, Aleksey E. (South Setauket, NY); Smith, Graham (Port Jefferson, NY); Mahler, George J. (Rocky Point, NY); Vanier, Peter E. (Setauket, NY)

    2010-12-28

    The present invention includes a high-energy detector having a cathode chamber, a support member, and anode segments. The cathode chamber extends along a longitudinal axis. The support member is fixed within the cathode chamber and extends from the first end of the cathode chamber to the second end of the cathode chamber. The anode segments are supported by the support member and are spaced along the longitudinal surface of the support member. The anode segments are configured to generate at least a first electrical signal in response to electrons impinging thereon.

  20. Los Alamos ChamberFest

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Los Alamos ChamberFest Los Alamos ChamberFest WHEN: Jun 13, 2015 10:00 AM - 3:00 PM WHERE: Central Park Square, Los Alamos CATEGORY: Community INTERNAL: Calendar Login Event Description ChamberFest is the annual Los Alamos Chamber of Commerce event featuring Chamber Members. It is an opportunity for businesses and nonprofits alike to showcase their products and services to the public. Entertainment will include music, a car show, pet activity area, and the always popular, kids activity area

  1. Ionization chamber dosimeter

    DOE Patents [OSTI]

    Renner, Tim R. (Berkeley, CA); Nyman, Mark A. (Berkeley, CA); Stradtner, Ronald (Kensington, CA)

    1991-01-01

    A method for fabricating an ion chamber dosimeter collecting array of the type utilizing plural discrete elements formed on a uniform collecting surface which includes forming a thin insulating layer over an aperture in a frame having surfaces, forming a predetermined pattern of through holes in the layer, plating both surfaces of the layer and simultaneously tilting and rotating the frame for uniform plate-through of the holes between surfaces. Aligned masking and patterned etching of the surfaces provides interconnects between the through holes and copper leads provided to external circuitry.

  2. LRL 25-inch Bubble Chamber

    DOE R&D Accomplishments [OSTI]

    Alvarez, L. W.; Gow, J. D.; Barrera, F.; Eckman, G.; Shand, J.; Watt, R.; Norgren, D.; Hernandez, H. P.

    1964-07-08

    The recently completed 25-inch hydrogen bubble chamber combines excellent picture quality with a fast operating cycle. The chamber has a unique optical system and is designed to take several pictures each Bevatron pulse, in conjunction with the Bevatron rapid beam ejection system.

  3. Ion chamber based neutron detectors

    SciTech Connect (OSTI)

    Derzon, Mark S; Galambos, Paul C; Renzi, Ronald F

    2014-12-16

    A neutron detector with monolithically integrated readout circuitry, including: a bonded semiconductor die; an ion chamber formed in the bonded semiconductor die; a first electrode and a second electrode formed in the ion chamber; a neutron absorbing material filling the ion chamber; and the readout circuitry which is electrically coupled to the first and second electrodes. The bonded semiconductor die includes an etched semiconductor substrate bonded to an active semiconductor substrate. The readout circuitry is formed in a portion of the active semiconductor substrate. The ion chamber has a substantially planar first surface on which the first electrode is formed and a substantially planar second surface, parallel to the first surface, on which the second electrode is formed. The distance between the first electrode and the second electrode may be equal to or less than the 50% attenuation length for neutrons in the neutron absorbing material filling the ion chamber.

  4. Sandia National Laboratories: Mode Stirred Chamber

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mode Stirred Chamber The Mode Stirred chamber is essentially a large microwave oven. It consists of a metal room that serves as a high-Q chamber and a metal paddle wheel to "stir"...

  5. The multigap resistive plate chamber

    SciTech Connect (OSTI)

    Zeballos, E. Cerron; Crotty, I.; Hatzifotiadou, D.; Valverde, J. Lamas; Neupane, S.; Williams, M. C. S.; Zichichi, A.

    2015-02-03

    The paper describes the multigap resistive plate chamber (RPC). This is a variant of the wide gap RPC. However it has much improved time resolution, while keeping all the other advantages of the wide gap RPC design.

  6. Light diffusing fiber optic chamber

    DOE Patents [OSTI]

    Maitland, Duncan J. (Lafayette, CA)

    2002-01-01

    A light diffusion system for transmitting light to a target area. The light is transmitted in a direction from a proximal end to a distal end by an optical fiber. A diffusing chamber is operatively connected to the optical fiber for transmitting the light from the proximal end to the distal end and transmitting said light to said target area. A plug is operatively connected to the diffusing chamber for increasing the light that is transmitted to the target area.

  7. Inverse Kinetics

    Energy Science and Technology Software Center (OSTI)

    2000-03-20

    Given the space-independent, one energy group reactor kinetics equations and the initial conditions, this prgram determines the time variation of reactivity required to produce the given input of flux-time data.

  8. Ducted combustion chamber for direct injection engines and method

    DOE Patents [OSTI]

    Mueller, Charles

    2015-03-03

    An internal combustion engine includes an engine block having a cylinder bore and a cylinder head having a flame deck surface disposed at one end of the cylinder bore. A piston connected to a rotatable crankshaft and configured to reciprocate within the cylinder bore has a piston crown portion facing the flame deck surface such that a combustion chamber is defined within the cylinder bore and between the piston crown and the flame deck surface. A fuel injector having a nozzle tip disposed in fluid communication with the combustion chamber has at least one nozzle opening configured to inject a fuel jet into the combustion chamber along a fuel jet centerline. At least one duct defined in the combustion chamber between the piston crown and the flame deck surface has a generally rectangular cross section and extends in a radial direction relative to the cylinder bore substantially along the fuel jet centerline.

  9. Plasma chemistry in wire chambers

    SciTech Connect (OSTI)

    Wise, J.

    1990-05-01

    The phenomenology of wire chamber aging is discussed and fundamentals of proportional counters are presented. Free-radical polymerization and plasma polymerization are discussed. The chemistry of wire aging is reviewed. Similarities between wire chamber plasma (>1 atm dc-discharge) and low-pressure rf-discharge plasmas, which have been more widely studied, are suggested. Construction and use of a system to allow study of the plasma reactions occurring in wire chambers is reported. A proportional tube irradiated by an {sup 55}Fe source is used as a model wire chamber. Condensable species in the proportional tube effluent are concentrated in a cryotrap and analyzed by gas chromatography/mass spectrometry. Several different wire chamber gases (methane, argon/methane, ethane, argon/ethane, propane, argon/isobutane) are tested and their reaction products qualitatively identified. For all gases tested except those containing methane, use of hygroscopic filters to remove trace water and oxygen contaminants from the gas resulted in an increase in the average molecular weight of the products, consistent with results from low-pressure rf-discharge plasmas. It is suggested that because water and oxygen inhibit polymer growth in the gas phase that they may also reduce polymer deposition in proportional tubes and therefore retard wire aging processes. Mechanistic implications of the plasma reactions of hydrocarbons with oxygen are suggested. Unresolved issues in this work and proposals for further study are discussed.

  10. Test chamber for alpha spectrometry

    DOE Patents [OSTI]

    Larsen, Robert P.

    1977-01-01

    Alpha emitters for low-level radiochemical analysis by measurement of alpha spectra are positioned precisely with respect to the location of a surface-barrier detector by means of a chamber having a removable threaded planchet holder. A pedestal on the planchet holder holds a specimen in fixed engagement close to the detector. Insertion of the planchet holder establishes an O-ring seal that permits the chamber to be pumped to a desired vacuum. The detector is protected against accidental contact and resulting damage.

  11. Mass independent kinetic energy reducing inlet system for vacuum environment

    DOE Patents [OSTI]

    Reilly, Peter T. A. [Knoxville, TN

    2010-12-14

    A particle inlet system comprises a first chamber having a limiting orifice for an incoming gas stream and a micrometer controlled expansion slit. Lateral components of the momentum of the particles are substantially cancelled due to symmetry of the configuration once the laminar flow converges at the expansion slit. The particles and flow into a second chamber, which is maintained at a lower pressure than the first chamber, and then moves into a third chamber including multipole guides for electromagnetically confining the particle. The vertical momentum of the particles descending through the center of the third chamber is minimized as an upward stream of gases reduces the downward momentum of the particles. The translational kinetic energy of the particles is near-zero irrespective of the mass of the particles at an exit opening of the third chamber, which may be advantageously employed to provide enhanced mass resolution in mass spectrometry.

  12. Mass independent kinetic energy reducing inlet system for vacuum environment

    DOE Patents [OSTI]

    Reilly, Peter T.A.

    2013-12-03

    A particle inlet system comprises a first chamber having a limiting orifice for an incoming gas stream and a micrometer controlled expansion slit. Lateral components of the momentum of the particles are substantially cancelled due to symmetry of the configuration once the laminar flow converges at the expansion slit. The particles and flow into a second chamber, which is maintained at a lower pressure than the first chamber, and then moves into a third chamber including multipole guides for electromagnetically confining the particle. The vertical momentum of the particles descending through the center of the third chamber is minimized as an upward stream of gases reduces the downward momentum of the particles. The translational kinetic energy of the particles is near-zero irrespective of the mass of the particles at an exit opening of the third chamber, which may be advantageously employed to provide enhanced mass resolution in mass spectrometry.

  13. Mass independent kinetic energy reducing inlet system for vacuum environment

    DOE Patents [OSTI]

    Reilly, Peter T.A.

    2014-05-13

    A particle inlet system comprises a first chamber having a limiting orifice for an incoming gas stream and a micrometer controlled expansion slit. Lateral components of the momentum of the particles are substantially cancelled due to symmetry of the configuration once the laminar flow converges at the expansion slit. The particles and flow into a second chamber, which is maintained at a lower pressure than the first chamber, and then moves into a third chamber including multipole guides for electromagnetically confining the particle. The vertical momentum of the particles descending through the center of the third chamber is minimized as an upward stream of gases reduces the downward momentum of the particles. The translational kinetic energy of the particles is near-zero irrespective of the mass of the particles at an exit opening of the third chamber, which may be advantageously employed to provide enhanced mass resolution in mass spectrometry.

  14. Single wire drift chamber design

    SciTech Connect (OSTI)

    Krider, J.

    1987-03-30

    This report summarizes the design and prototype tests of single wire drift chambers to be used in Fermilab test beam lines. The goal is to build simple, reliable detectors which require a minimum of electronics. Spatial resolution should match the 300 ..mu..m rms resolution of the 1 mm proportional chambers that they will replace. The detectors will be used in beams with particle rates up to 20 KHz. Single track efficiency should be at least 99%. The first application will be in the MT beamline, which has been designed for calibration of CDF detectors. A set of four x-y modules will be used to track and measure the momentum of beam particles.

  15. Combustion Kinetics

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Kinetics - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste Management Programs Advanced Nuclear Energy

  16. Sandia National Laboratories: Mode Stirred Chamber

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mode Stirred Chamber The Mode Stirred chamber is essentially a large microwave oven. It consists of a metal room that serves as a high-Q chamber and a metal paddle wheel to "stir" the chamber modes. Mixing the modes in this manner allows test objects, in a single orientation to be exposed to EM energy in many different angles of incidence and polarization. Electronic susceptibility tests can be performed, or test object electromagnetic transfer functions can be determined through

  17. Automated soil gas monitoring chamber (Patent) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    Patent: Automated soil gas monitoring chamber Citation Details In-Document Search Title: Automated soil gas monitoring chamber A chamber for trapping soil gases as they evolve from...

  18. Vacuum Chamber - Facilities - Radiation Effects Facility / Cyclotron

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Institute / Texas A&M University Vacuum Chamber Inside of vacuum chamber. Mounting frame visible. Vacuum chamber closed and operational. Our traditional vacuum chamber is available for your testing needs. It has an inside diameter of 30” and a height 30”. It's features are described in detail below. Pumping System Pumping for the chamber is provided by a 1,500 L/min mechanical pump and 69,000 L/min turbo molecular pump. Pumping time to an operating pressure in the low 10 -4 Torr range

  19. Fluidized wall for protecting fusion chamber walls

    DOE Patents [OSTI]

    Maniscalco, James A. (Danville, CA); Meier, Wayne R. (Livermore, CA)

    1982-01-01

    Apparatus for protecting the inner wall of a fusion chamber from microexplosion debris, x-rays, neutrons, etc. produced by deuterium-tritium (DT) targets imploded within the fusion chamber. The apparatus utilizes a fluidized wall similar to a waterfall comprising liquid lithium or solid pellets of lithium-ceramic, the waterfall forming a blanket to prevent damage of the structural materials of the chamber.

  20. Georges Charpak, Particle Detectors, and Multiwire Chambers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Georges Charpak, Particle Detectors, and Multiwire Chambers Resources with Additional Information * Patents Georges Charpak Courtesy of CERN Nobel laureate Georges Charpak [was] a pioneer in the art and science of particle detection ... . [He] developed a host of particle detectors used throughout experimental particle physics. In 1968, he invented and developed the first multiwire proportional chamber, for which he won the [Physics] Nobel Prize in 1992 ... . The multiwire chamber differed from

  1. Internal combustion engine with rotary combustion chamber

    SciTech Connect (OSTI)

    Hansen, C.N.; Cross, P.C.

    1986-09-23

    This patent describes an internal combustion engine comprising: a block having at least one cylindrical wall surrounding a piston chamber, piston means located in the piston chamber means operable to reciprocate the piston means in the chamber, head means mounted on the block covering the chamber. The head means has an air and fuel intake passage, and exhaust gas passage, a rotary valve assembly operatively associated with the head means for controlling the flow of air and fuel into the rotary valve assembly and piston chamber and the flow of exhaust gas from rotary valve assembly and the piston chamber. The means has a housing with a bore open to the piston chamber accommodating the rotary valve assembly, the valve assembly comprising a cylindrical sleeve located in the bore, the sleeve having an inner surface, an ignition hole, and intake and exhaust ports aligned with the intake passage and exhaust gas passage, spark generating means mounted on the housing operable to generate a spark. The rotatable valving means is located within the sleeve for controlling the flow of air and fuel into the rotary valve assembly and piston chamber and the flow of exhaust gases out of the rotary valve assembly and piston chamber.

  2. Compact ion chamber based neutron detector

    SciTech Connect (OSTI)

    Derzon, Mark S.; Galambos, Paul C.; Renzi, Ronald F.

    2015-10-27

    A directional neutron detector has an ion chamber formed in a dielectric material; a signal electrode and a ground electrode formed in the ion chamber; a neutron absorbing material filling the ion chamber; readout circuitry which is electrically coupled to the signal and ground electrodes; and a signal processor electrically coupled to the readout circuitry. The ion chamber has a pair of substantially planar electrode surfaces. The chamber pressure of the neutron absorbing material is selected such that the reaction particle ion trail length for neutrons absorbed by the neutron absorbing material is equal to or less than the distance between the electrode surfaces. The signal processor is adapted to determine a path angle for each absorbed neutron based on the rise time of the corresponding pulse in a time-varying detector signal.

  3. Compact ion chamber based neutron detector

    SciTech Connect (OSTI)

    Derzon, Mark S; Galambos, Paul C; Renzi, Ronald F

    2015-11-05

    A directional neutron detector has an ion chamber formed in a dielectric material; a signal electrode and a ground electrode formed in the ion chamber; a neutron absorbing material filling the ion chamber; readout circuitry which is electrically coupled to the signal and ground electrodes; and a signal processor electrically coupled to the readout circuitry. The ion chamber has a pair of substantially planar electrode surfaces. The chamber pressure of the neutron absorbing material is selected such that the reaction particle ion trail length for neutrons absorbed by the neutron absorbing material is equal to or less than the distance between the electrode surfaces. The signal processor is adapted to determine a path angle for each absorbed neutron based on the rise time of the corresponding pulse in a time-varying detector signal.

  4. High Accuracy, Two-Dimensional Read-Out in Multiwire Proportional Chambers

    DOE R&D Accomplishments [OSTI]

    Charpak, G.; Sauli, F.

    1973-02-14

    In most applications of proportional chambers, especially in high-energy physics, separate chambers are used for measuring different coordinates. In general one coordinate is obtained by recording the pulses from the anode wires around which avalanches have grown. Several methods have been imagined for obtaining the position of an avalanche along a wire. In this article a method is proposed which leads to the same range of accuracies and may be preferred in some cases. The problem of accurate measurements for large-size chamber is also discussed.

  5. Stochastic Parallel PARticle Kinetic Simulator

    Energy Science and Technology Software Center (OSTI)

    2008-07-01

    SPPARKS is a kinetic Monte Carlo simulator which implements kinetic and Metropolis Monte Carlo solvers in a general way so that they can be hooked to applications of various kinds. Specific applications are implemented in SPPARKS as physical models which generate events (e.g. a diffusive hop or chemical reaction) and execute them one-by-one. Applications can run in paralle so long as the simulation domain can be partitoned spatially so that multiple events can be invokedmore » simultaneously. SPPARKS is used to model various kinds of mesoscale materials science scenarios such as grain growth, surface deposition and growth, and reaction kinetics. It can also be used to develop new Monte Carlo models that hook to the existing solver and paralle infrastructure provided by the code.« less

  6. Chemical Kinetic Modeling of Advanced Transportation Fuels

    SciTech Connect (OSTI)

    PItz, W J; Westbrook, C K; Herbinet, O

    2009-01-20

    Development of detailed chemical kinetic models for advanced petroleum-based and nonpetroleum based fuels is a difficult challenge because of the hundreds to thousands of different components in these fuels and because some of these fuels contain components that have not been considered in the past. It is important to develop detailed chemical kinetic models for these fuels since the models can be put into engine simulation codes used for optimizing engine design for maximum efficiency and minimal pollutant emissions. For example, these chemistry-enabled engine codes can be used to optimize combustion chamber shape and fuel injection timing. They also allow insight into how the composition of advanced petroleum-based and non-petroleum based fuels affect engine performance characteristics. Additionally, chemical kinetic models can be used separately to interpret important in-cylinder experimental data and gain insight into advanced engine combustion processes such as HCCI and lean burn engines. The objectives are: (1) Develop detailed chemical kinetic reaction models for components of advanced petroleum-based and non-petroleum based fuels. These fuels models include components from vegetable-oil-derived biodiesel, oil-sand derived fuel, alcohol fuels and other advanced bio-based and alternative fuels. (2) Develop detailed chemical kinetic reaction models for mixtures of non-petroleum and petroleum-based components to represent real fuels and lead to efficient reduced combustion models needed for engine modeling codes. (3) Characterize the role of fuel composition on efficiency and pollutant emissions from practical automotive engines.

  7. Evolution of silicic magma chambers and their relationship to...

    Office of Scientific and Technical Information (OSTI)

    Conference: Evolution of silicic magma chambers and their relationship to basaltic volcanism Citation Details In-Document Search Title: Evolution of silicic magma chambers and ...

  8. ON THE ANALYSIS OF BUBBLE CHAMBER TRACKS Bradner, H.; Solmitz...

    Office of Scientific and Technical Information (OSTI)

    ON THE ANALYSIS OF BUBBLE CHAMBER TRACKS Bradner, H.; Solmitz, F. 08 HYDROGEN; 43 PARTICLE ACCELERATORS; BEVATRON; BUBBLE CHAMBERS; DETECTION; HYDROCARBONS; HYDROGEN; INVENTIONS;...

  9. History of the superconducting-magnet bubble chambers

    SciTech Connect (OSTI)

    Derrick, M.; Hyman, L.G.; Pewitt, E.G.

    1980-01-01

    This review covers the development of superconducting magnets, small bubble chambers, and the early history of the 12-foot bubble chamber. (MOW)

  10. China New Energy Chamber of Commerce CNECC | Open Energy Information

    Open Energy Info (EERE)

    Chamber of Commerce CNECC Jump to: navigation, search Name: China New Energy Chamber of Commerce (CNECC) Place: Beijing, Beijing Municipality, China Zip: 100052 Product: A Chinese...

  11. General Information

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    General Information JLF Contacts Request a Tour

  12. Gas Injection Apparatus for Vacuum Chamber

    SciTech Connect (OSTI)

    Almabouada, F.; Louhibi, D.; Hamici, M.

    2011-12-26

    We present in this article a gas injection apparatus which comprises the gas injector and its electronic command for vacuum chamber applications. Some of these applications are thin-film deposition by a pulsed laser deposition (PLD) or a cathodic arc deposition (arc-PVD) and the plasma generation. The electronic part has been developed to adjust the flow of the gas inside the vacuum chamber by controlling both of the injector's opening time and the repetition frequency to allow a better gas flow. In this case, the system works either on a pulsed mode or a continuous mode for some applications. In addition, the repetition frequency can be synchronised with a pulsed laser by an external signal coming from the laser, which is considered as an advantage for users. Good results have been obtained using the apparatus and testing with Argon and Nitrogen gases.

  13. The American Chamber of Commerce of Trinidad & Tobago | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The American Chamber of Commerce of Trinidad & Tobago The American Chamber of Commerce of Trinidad & Tobago May 13, 2008 - 12:00pm Addthis Remarks As Prepared for Delivery by...

  14. Santa Fe Chamber of Commerce Business Awards Gala

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Santa Fe Chamber of Commerce Business Awards Gala Santa Fe Chamber of Commerce Business Awards Gala WHEN: Jun 04, 2015 5:30 PM - 7:30 PM WHERE: Skylight 139 West San Francisco...

  15. Minority Chamber of Commerce "How to do Business with Federal...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Minority Chamber of Commerce "How to do Business with Federal Government" Minority Chamber of Commerce "How to do Business with Federal Government" October 29, 2015 9:00AM to...

  16. Gas Electron Multiplier (GEM) Chamber Characteristics Test (Technical...

    Office of Scientific and Technical Information (OSTI)

    across the GEM gap, the uniformity of the chamber across the 8cm x 8cm area, cross talk and its distance dependence to the triggered pad, chamber rate capabilities, and the...

  17. Eco Kinetics | Open Energy Information

    Open Energy Info (EERE)

    Kinetics Jump to: navigation, search Name: eco-Kinetics Place: Stapylton, Queensland, Australia Zip: 4207 Sector: Renewable Energy Product: Queensland-based renewable energy...

  18. Vacuum chamber for containing particle beams

    DOE Patents [OSTI]

    Harvey, A.

    1985-11-26

    A vacuum chamber for containing a charged particle beam in a rapidly changing magnetic environment comprises a ceramic pipe with conducting strips oriented along the longitudinal axis of the pipe and with circumferential conducting bands oriented perpendicular to the longitudinal axis but joined with a single longitudinal electrical connection. When both strips and bands are on the outside of the ceramic pipe, insulated from each other, a high-resistance conductive layer such as nickel can be coated on the inside of the pipe.

  19. Vacuum chamber with a supersonic flow aerodynamic window

    DOE Patents [OSTI]

    Hanson, Clark L. (Livermore, CA)

    1982-01-01

    A supersonic flow aerodynamic window, whereby a steam ejector situated in a primary chamber at vacuum exhausts superheated steam toward an orifice to a region of higher pressure, creating a barrier to the gas in the region of higher pressure which attempts to enter through the orifice. In a mixing chamber outside and in fluid communication with the primary chamber, superheated steam and gas are combined into a mixture which then enters the primary chamber through the orifice. At the point of impact of the ejector/superheated steam and the incoming gas/superheated steam mixture, a barrier is created to the gas attempting to enter the ejector chamber. This barrier, coupled with suitable vacuum pumping means and cooling means, serves to keep the steam ejector and primary chamber at a negative pressure, even though the primary chamber has an orifice to a region of higher pressure.

  20. Vacuum chamber with a supersonic-flow aerodynamic window

    DOE Patents [OSTI]

    Hanson, C.L.

    1980-10-14

    A supersonic flow aerodynamic window is disclosed whereby a steam ejector situated in a primary chamber at vacuum exhausts superheated steam toward an orifice to a region of higher pressure, creating a barrier to the gas in the region of higher pressure which attempts to enter through the orifice. In a mixing chamber outside and in fluid communication with the primary chamber, superheated steam and gas are combined into a mixture which then enters the primary chamber through the orifice. At the point of impact of the ejector/superheated steam and the incoming gas/superheated steam mixture, a barrier is created to the gas attempting to enter the ejector chamber. This barrier, coupled with suitable vacuum pumping means and cooling means, serves to keep the steam ejector and primary chamber at a negative pressure, even though the primary chamber has an orifice to a region of higher pressure.

  1. Wire chamber radiation detector with discharge control

    DOE Patents [OSTI]

    Perez-Mendez, Victor (Berkeley, CA); Mulera, Terrence A. (Berkeley, CA)

    1984-01-01

    A wire chamber radiation detector (11) has spaced apart parallel electrodes (16) and grids (17, 18, 19) defining an ignition region (21) in which charged particles (12) or other ionizing radiations initiate brief localized avalanche discharges (93) and defining an adjacent memory region (22) in which sustained glow discharges (94) are initiated by the primary discharges (93). Conductors (29, 32) of the grids (18, 19) at each side of the memory section (22) extend in orthogonal directions enabling readout of the X-Y coordinates of locations at which charged particles (12) were detected by sequentially transmitting pulses to the conductors (29) of one grid (18) while detecting transmissions of the pulses to the orthogonal conductors (36) of the other grid (19) through glow discharges (94). One of the grids (19) bounding the memory region (22) is defined by an array of conductive elements (32) each of which is connected to the associated readout conductor (36) through a separate resistance (37). The wire chamber (11) avoids ambiguities and imprecisions in the readout of coordinates when large numbers of simultaneous or near simultaneous charged particles (12) have been detected. Down time between detection periods and the generation of radio frequency noise are also reduced.

  2. Nonlinear frequency shift of electrostatic waves in general collisionl...

    Office of Scientific and Technical Information (OSTI)

    Nonlinear frequency shift of electrostatic waves in general collisionless plasma: Unifying theory of fluid and kinetic nonlinearities Citation Details In-Document Search This...

  3. Quantum combustion chamber for the digital engine

    SciTech Connect (OSTI)

    Evers, L.W.; Baasch, V.

    1985-01-01

    For increasing fuel economy and reducing hydrocarbon emissions, a two-stoke-cycle, loop-scavenged single cylinder engine was modified by replacing the head with a head having three subchambers and incorporating a distributing pump fuel injection system. The fuel injection system allowed one subchamber to be operated at a time. The quantum combustion system demonstrated both lower fuel consumption and lower hydrocarbon emissions than a conventional homogeneous charge engine. The experimental evidence also indicates that the combustion essentially occurred in the one chamber into which fuel was injected. Establishing stratified charge combustion by mechanically separating the regions of air from the regions of air/fuel mixtures by means of subchambers is feasible.

  4. Erbium hydride decomposition kinetics.

    SciTech Connect (OSTI)

    Ferrizz, Robert Matthew

    2006-11-01

    Thermal desorption spectroscopy (TDS) is used to study the decomposition kinetics of erbium hydride thin films. The TDS results presented in this report are analyzed quantitatively using Redhead's method to yield kinetic parameters (E{sub A} {approx} 54.2 kcal/mol), which are then utilized to predict hydrogen outgassing in vacuum for a variety of thermal treatments. Interestingly, it was found that the activation energy for desorption can vary by more than 7 kcal/mol (0.30 eV) for seemingly similar samples. In addition, small amounts of less-stable hydrogen were observed for all erbium dihydride films. A detailed explanation of several approaches for analyzing thermal desorption spectra to obtain kinetic information is included as an appendix.

  5. Chamber of Commerce Recognizes Portsmouth Site Specific Advisory Board |

    Energy Savers [EERE]

    Department of Energy Chamber of Commerce Recognizes Portsmouth Site Specific Advisory Board Chamber of Commerce Recognizes Portsmouth Site Specific Advisory Board February 11, 2016 - 12:05pm Addthis The Portsmouth Site Specific Advisory Board was honored at the chamber’s annual dinner in January. Pictured, left to right, are Carlton Cave (Portsmouth SSAB member), Joel Bradburne (Portsmouth SSAB deputy designated federal official), Greg Simonton (Portsmouth SSAB federal coordinator),

  6. Paint decontamination kinetics

    SciTech Connect (OSTI)

    Thornton, E.W.

    1984-04-01

    Decontamination kinetics of a high-gloss polyurethane paint have been investigated using a novel flow cell experiment where the sample was counted in situ during decontamination. The /sup 134/Cs, /sup 137/Cs, and /sup 90/Y decontaminations follow a rate law that can be predicted theoretically for contaminant ion desorption from weakly heterogeneous random surface adsorption sites. Paint surfaces show the same decontamination kinetics after damage by abrasion or ultraviolet irradiation prior to contamination. The systems investigated exhibit Freundlich adsorption isotherm behavior during contamination; this is also characteristic of weakly heterogeneous random surfaces and is very commonly observed in ion adsorption studies at low concentrations.

  7. Chambers County, Texas: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    County, Texas Reliant Baytown Biomass Facility Places in Chambers County, Texas Anahuac, Texas Baytown, Texas Beach City, Texas Cove, Texas Mont Belvieu, Texas Old...

  8. Chambers County, Alabama: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Chambers County, Alabama: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 32.9028048, -85.354965 Show Map Loading map... "minzoom":false,"mappi...

  9. Donald Glaser, the Bubble Chamber, and Elementary Particles

    Office of Scientific and Technical Information (OSTI)

    Biotech Pioneer Donald Glaser ... Donald A. Glaser, Ph.D.; The Bubble Chamber, ... Neurobiology (an interview) -- accepting agreement results in receiving the document Invention...

  10. The Hydrogen Bubble Chamber and the Strange Resonances

    DOE R&D Accomplishments [OSTI]

    Alvarez, L. W.

    1985-06-01

    The author's recollections of his experience in the use of bubble chambers and the discoveries of strange resonances are given. (LEW)

  11. Continuous Flow Diffusion Chamber Measurements of IN Concentration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Flow Diffusion Chamber (CFDC) Measurements of IN Concentration Concentrations of Ice-Nucleating Aerosol (IN) as a function of Temperature and %Supersaturation Sarah Brooks and...

  12. Saku Chamber of Commers Indsutry | Open Energy Information

    Open Energy Info (EERE)

    Jump to: navigation, search Name: Saku Chamber of Commers&Indsutry Place: Saku, Nagano, Japan Zip: 3850051 Product: An organization engages in improving the collaboration and...

  13. Concept for Reducing Hall Thruster Chamber Wall Erosion with Lithium Vapor

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Shielding. | Princeton Plasma Physics Lab Concept for Reducing Hall Thruster Chamber Wall Erosion with Lithium Vapor Shielding. Hall thrusters have been established as a compact and reliable means for satellite applications. Erosion of the surfaces of such thrusters, however, has been a serious factor in limiting their lifetimes. Replacing eroded surfaces by replenishing them is generally unattractive because of the mechanical complexity and added weight that could be required. This

  14. Vacuum chamber for ion manipulation device

    DOE Patents [OSTI]

    Chen, Tsung-Chi; Tang, Keqi; Ibrahim, Yehia M; Smith, Richard D; Anderson, Gordon A; Baker, Erin M

    2014-12-09

    An ion manipulation method and device is disclosed. The device includes a pair of substantially parallel surfaces. An array of inner electrodes is contained within, and extends substantially along the length of, each parallel surface. The device includes a first outer array of electrodes and a second outer array of electrodes. Each outer array of electrodes is positioned on either side of the inner electrodes, and is contained within and extends substantially along the length of each parallel surface. A DC voltage is applied to the first and second outer array of electrodes. A RF voltage, with a superimposed electric field, is applied to the inner electrodes by applying the DC voltages to each electrode. Ions either move between the parallel surfaces within an ion confinement area or along paths in the direction of the electric field, or can be trapped in the ion confinement area. A predetermined number of pairs of surfaces are disposed in one or more chambers, forming a multiple-layer ion mobility cyclotron device.

  15. Paint coatings: Controlled field and chamber experiments

    SciTech Connect (OSTI)

    Edney, E.O.

    1989-04-01

    To determine the impact of pollution levels on the weathering rates of coatings, laboratory chamber experiments and controlled field exposures at North Carolina and Ohio sites were conducted in such a manner to separate the contributions due to dry deposition, wet deposition, precipitation pH, etc. The results of these studies confirm that acidic gases such as SO/sub 2/ and HNO/sub 3/, as well as acids within rain, promote the dissolution of alkaline components including CaCO/sub 3/, ZnO, and Al flake from paint films. It is unclear from these studies whether the removal of these components reduces the service life or protective properties of the paint film. Other researchers within the Coatings Effects Program are conducting subsequent analyses to determine micro-damage of these paints. The uptake of acidic gases to painted surfaces is a complex process that depends on several factors. The deposition rate of SO/sub 2/ to a wet, painted surface may be controlled by the level of oxidants such as H/sub 2/O/sub 2/.

  16. LLNL Chemical Kinetics Modeling Group

    SciTech Connect (OSTI)

    Pitz, W J; Westbrook, C K; Mehl, M; Herbinet, O; Curran, H J; Silke, E J

    2008-09-24

    The LLNL chemical kinetics modeling group has been responsible for much progress in the development of chemical kinetic models for practical fuels. The group began its work in the early 1970s, developing chemical kinetic models for methane, ethane, ethanol and halogenated inhibitors. Most recently, it has been developing chemical kinetic models for large n-alkanes, cycloalkanes, hexenes, and large methyl esters. These component models are needed to represent gasoline, diesel, jet, and oil-sand-derived fuels.

  17. Consistent description of kinetics and hydrodynamics of dusty plasma

    SciTech Connect (OSTI)

    Markiv, B.; Tokarchuk, M.; National University Lviv Polytechnic, 12 Bandera St., 79013 Lviv

    2014-02-15

    A consistent statistical description of kinetics and hydrodynamics of dusty plasma is proposed based on the Zubarev nonequilibrium statistical operator method. For the case of partial dynamics, the nonequilibrium statistical operator and the generalized transport equations for a consistent description of kinetics of dust particles and hydrodynamics of electrons, ions, and neutral atoms are obtained. In the approximation of weakly nonequilibrium process, a spectrum of collective excitations of dusty plasma is investigated in the hydrodynamic limit.

  18. Multidimensional simulation and chemical kinetics development...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Multidimensional simulation and chemical kinetics development for high efficiency clean combustion engines Multidimensional simulation and chemical kinetics development for high...

  19. CLEERS Coordination & Joint Development of Benchmark Kinetics...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications CLEERS Coordination & Joint Development of Benchmark Kinetics for LNT & SCR CLEERS Coordination & Development of Catalyst Process Kinetic...

  20. CLEERS Coordination & Development of Catalyst Process Kinetic...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications CLEERS Coordination & Joint Development of Benchmark Kinetics for LNT & SCR CLEERS Coordination & Joint Development of Benchmark Kinetics...

  1. General Engineers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    General Engineers The U.S. Energy Information Administration (EIA) within the Department of Energy has forged a world-class information program that stresses quality, teamwork, and employee growth. In support of our program, we offer a variety of profes- sional positions, including the General Engineer, whose work is associated with analytical studies and evaluation projects pertaining to the operations of the energy industry. Responsibilities: General Engineers perform or participate in one or

  2. Turbine component cooling channel mesh with intersection chambers

    DOE Patents [OSTI]

    Lee, Ching-Pang; Marra, John J

    2014-05-06

    A mesh (35) of cooling channels (35A, 35B) with an array of cooling channel intersections (42) in a wall (21, 22) of a turbine component. A mixing chamber (42A-C) at each intersection is wider (W1, W2)) than a width (W) of each of the cooling channels connected to the mixing chamber. The mixing chamber promotes swirl, and slows the coolant for more efficient and uniform cooling. A series of cooling meshes (M1, M2) may be separated by mixing manifolds (44), which may have film cooling holes (46) and/or coolant refresher holes (48).

  3. Donald Glaser, the Bubble Chamber, and Elementary Particles

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Donald Glaser and the Bubble Chamber Resources with Additional Information Donald Glaser Courtesy of and ©The University of California, Berkeley The 1960 Nobel Prize in Physics was awarded to Donald Glaser for his invention of the bubble chamber. "Glaser first conceived of the bubble chamber in 1952, at the age of 25, while a faculty member at the University of Michigan. According to scientific lore, Glaser was enjoying a cold beer when he observed the stream of bubbles in his brew. It was

  4. Chemical kinetics modeling

    SciTech Connect (OSTI)

    Westbrook, C.K.; Pitz, W.J.

    1993-12-01

    This project emphasizes numerical modeling of chemical kinetics of combustion, including applications in both practical combustion systems and in controlled laboratory experiments. Elementary reaction rate parameters are combined into mechanisms which then describe the overall reaction of the fuels being studied. Detailed sensitivity analyses are used to identify those reaction rates and product species distributions to which the results are most sensitive and therefore warrant the greatest attention from other experimental and theoretical research programs. Experimental data from a variety of environments are combined together to validate the reaction mechanisms, including results from laminar flames, shock tubes, flow systems, detonations, and even internal combustion engines.

  5. ON THE ANALYSIS OF BUBBLE CHAMBER TRACKS (Technical Report) ...

    Office of Scientific and Technical Information (OSTI)

    Since its invention by Glaser in 1953, the bubble chamber has become a most valuable tool in high-energy physics. It combines a number of advantages of various older methods of ...

  6. Carrying Semiautomatic Pistols with a Round in the Chamber

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    1999-10-28

    Sets forth requirements for a DOE security police officer who must carry a round in the chamber of a semiautomatic pistol while on duty. Does not cancel other directives.

  7. DEVELOPMENT OF TITANIUM NITRIDE COATING FOR SNS RING VACUUM CHAMBERS.

    SciTech Connect (OSTI)

    HE,P.; HSEUH,H.C.; MAPES,M.; TODD,R.; WEISS,D.

    2001-06-18

    The inner surface of the ring vacuum chambers of the US Spallation Neutron Source (SNS) will be coated with {approximately}100 nm of Titanium Nitride (TiN). This is to minimize the secondary electron yield (SEY) from the chamber wall, and thus avoid the so-called e-p instability caused by electron multipacting as observed in a few high-intensity proton storage rings. Both DC sputtering and DC-magnetron sputtering were conducted in a test chamber of relevant geometry to SNS ring vacuum chambers. Auger Electron Spectroscopy (AES) and Rutherford Back Scattering (RBS) were used to analyze the coatings for thickness, stoichiometry and impurity. Excellent results were obtained with magnetron sputtering. The development of the parameters for the coating process and the surface analysis results are presented.

  8. Effects of outgassing of loader chamber walls on hydriding of...

    Office of Scientific and Technical Information (OSTI)

    gas pressure. Complete process data for (1) a copper-(1.83 wt. %)beryllium wet hydrogen fired passivated (600 C-1 h) externally heated pipe hydriding chamber are reported....

  9. MHK Technologies/Multi Resonant Chambers MRC 1000 | Open Energy...

    Open Energy Info (EERE)

    Water Column OWC principles Consists of 3 x 500kW independent chambers each with a Dresser Rand HydroAir turbine driving an induction generator Full power conversion system...

  10. General Tables

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    General Tables The General Tables for the most recent TUNL evaluation of "Energy Levels of Light Nuclei, A = 8, 9, 10" published in Nuclear Physics A745 (2004) p.155 and "Energy Levels of Light Nuclei, A = 5, 6, 7" published in Nuclear Physics A708 (2002) p.3 are available below. Beginning with the A = 5, 6, 7 nuclei, the General Tables will no longer be included in the publications of "Energy Levels of Light Nuclei" in Nuclear Physics A. The tables will be placed

  11. Scaling Law of Coherent Synchrotron Radiation in a Rectangular Chamber

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect Journal Article: Scaling Law of Coherent Synchrotron Radiation in a Rectangular Chamber Citation Details In-Document Search Title: Scaling Law of Coherent Synchrotron Radiation in a Rectangular Chamber Authors: Cai, Yunhai ; /SLAC ; , Publication Date: 2014-01-06 OSTI Identifier: 1114162 Report Number(s): SLAC-PUB-15875 Journal ID: ISSN 1098--4402 DOE Contract Number: AC02-76SF00515 Resource Type: Journal Article Resource Relation: Journal Name: Physical

  12. Scaling law of coherent synchrotron radiation in a rectangular chamber

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect Scaling law of coherent synchrotron radiation in a rectangular chamber Citation Details In-Document Search Title: Scaling law of coherent synchrotron radiation in a rectangular chamber Authors: Cai, Yunhai Publication Date: 2014-02-12 OSTI Identifier: 1180843 Grant/Contract Number: AC02-76SF00515 Type: Published Article Journal Name: Physical Review Special Topics - Accelerators and Beams Additional Journal Information: Journal Volume: 17; Journal Issue:

  13. Kinetics of coal pyrolysis

    SciTech Connect (OSTI)

    Seery, D.J.; Freihaut, J.D.; Proscia, W.M. ); Howard, J.B.; Peters, W.; Hsu, J.; Hajaligol, M.; Sarofim, A. ); Jenkins, R.; Mallin, J.; Espindola-Merin, B. ); Essenhigh, R.; Misra, M.K. )

    1989-07-01

    This report contains results of a coordinated, multi-laboratory investigation of coal devolatilization. Data is reported pertaining to the devolatilization for bituminous coals over three orders of magnitude in apparent heating rate (100 to 100,000 + {degree}C/sec), over two orders of magnitude in particle size (20 to 700 microns), final particle temperatures from 400 to 1600{degree}C, heat transfer modes ranging from convection to radiative, ambient pressure ranging from near vacuum to one atmosphere pressure. The heat transfer characteristics of the reactors are reported in detail. It is assumed the experimental results are to form the basis of a devolatilization data base. Empirical rate expressions are developed for each phase of devolatilization which, when coupled to an awareness of the heat transfer rate potential of a particular devolatilization reactor, indicate the kinetics emphasized by a particular system reactor plus coal sample. The analysis indicates the particular phase of devolatilization that will be emphasized by a particular reactor type and, thereby, the kinetic expressions appropriate to that devolatilization system. Engineering rate expressions are developed from the empirical rate expressions in the context of a fundamental understanding of coal devolatilization developed in the course of the investigation. 164 refs., 223 figs., 44 tabs.

  14. Amber Kinetics | Open Energy Information

    Open Energy Info (EERE)

    search Name: Amber Kinetics Product: Start-up company developing a novel flywheel energy storage system with the Lawrence Livermore National Laboratory. References: Amber...

  15. Dark matter limits froma 15 kg windowless bubble chamber

    SciTech Connect (OSTI)

    Szydagis, Matthew Mark; /Chicago U.

    2010-12-01

    The COUPP collaboration has successfully used bubble chambers, a technology previously applied only to high-energy physics experiments, as direct dark matter detectors. It has produced the world's most stringent spin-dependent WIMP limits, and increasingly competitive spin-independent limits. These limits were achieved by capitalizing on an intrinsic rejection of the gamma background that all other direct detection experiments must address through high-density shielding and empirically-determined data cuts. The history of COUPP, including its earliest prototypes and latest results, is briefly discussed in this thesis. The feasibility of a new, windowless bubble chamber concept simpler and more inexpensive in design is discussed here as well. The dark matter limits achieved with a 15 kg windowless chamber, larger than any previous COUPP chamber (2 kg, 4 kg), are presented. Evidence of the greater radiopurity of synthetic quartz compared to natural is presented using the data from this 15 kg device, the first chamber to be made from synthetic quartz. The effective reconstruction of the three-dimensional positions of bubbles in a highly distorted optical field, with ninety-degree bottom lighting similar to cloud chamber lighting, is demonstrated. Another innovation described in this thesis is the use of the sound produced by bubbles recorded by an array of piezoelectric sensors as the primary means of bubble detection. In other COUPP chambers, cameras have been used as the primary trigger. Previous work on bubble acoustic signature differentiation using piezos is built upon in order to further demonstrate the ability to discriminate between alpha- and neutron-induced events.

  16. General Information

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    General Information General Information As a premier national research and development laboratory, LANL seeks to do business with qualified companies that offer value and high quality products and services. Contact Small Business Office (505) 667-4419 Email Are you a good fit for LANL? Need to find out more? LANL and its Small Business Program is only a phone call or email away. (See contact information, at left.) We want to be sure you can find a good fit with our procurement opportunities and

  17. GENERAL ASSIGNMENT

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    GENERAL ASSIGNMENT KNOW ALL MEN BY THESE PRESENTS, that ___________________________________, a corporation organized and existing under the laws of the State of ________________________, with its principal place of business at ___________________________________, ___________________________________ has been engaged in performing work under Award Number DE-__________________________with the UNITED STATES OF AMERICA (hereinafter called the "Government"), represented by the UNITED STATES

  18. Inertial confinement fusion reaction chamber and power conversion system study

    SciTech Connect (OSTI)

    Maya, I.; Schultz, K.R.; Battaglia, J.M.; Buksa, J.J.; Creedson, R.L.; Erlandson, O.D.; Levine, H.E.; Roelant, D.F.; Sanchez, H.W.; Schrader, S.A.

    1984-09-01

    GA Technologies has developed a conceptual ICF reactor system based on the Cascade rotating-bed reaction chamber concept. Unique features of the system design include the use of low activation SiC in a reaction chamber constructed of box-shaped tiles held together in compression by prestressing tendons to the vacuum chamber. Circulating Li/sub 2/O granules serve as the tritium breeding and energy transport material, cascading down the sides of the reaction chamber to the power conversion system. The total tritium inventory of the system is 6 kg; tritium recovery is accomplished directly from the granules via the vacuum system. A system for centrifugal throw transport of the hot Li/sub 2/O granules from the reaction chamber to the power conversion system has been developed. A number of issues were evaluated during the course of this study. These include the response of first-layer granules to the intense microexplosion surface heat flux, cost effective fabrication of Li/sub 2/O granules, tritium inventory and recovery issues, the thermodynamics of solids-flow options, vacuum versus helium-medium heat transfer, and the tradeoffs of capital cost versus efficiency for alternate heat exchange and power conversion system option. The resultant design options appear to be economically competitive, safe, and environmentally attractive.

  19. Initial Back-to-Back Fission Chamber Testing in ATRC

    SciTech Connect (OSTI)

    Benjamin Chase; Troy Unruh; Joy Rempe

    2014-06-01

    Development and testing of in-pile, real-time neutron sensors for use in Materials Test Reactor experiments is an ongoing project at Idaho National Laboratory. The Advanced Test Reactor National Scientific User Facility has sponsored a series of projects to evaluate neutron detector options in the Advanced Test Reactor Critical Facility (ATRC). Special hardware was designed and fabricated to enable testing of the detectors in the ATRC. Initial testing of Self-Powered Neutron Detectors and miniature fission chambers produced promising results. Follow-on testing required more experiment hardware to be developed. The follow-on testing used a Back-to-Back fission chamber with the intent to provide calibration data, and a means of measuring spectral indices. As indicated within this document, this is the first time in decades that BTB fission chambers have been used in INL facilities. Results from these fission chamber measurements provide a baseline reference for future measurements with Back-to-Back fission chambers.

  20. Atmosphere contamination following repainting of a human hyperbaric chamber complex

    SciTech Connect (OSTI)

    Lillo, R.S.; Morris, J.W.; Caldwell, J.M.; Balk, D.M.; Flynn, E.T. )

    1990-09-01

    The Naval Medical Research Institute currently conducts hyperbaric research in a Man-Rated Chamber Complex (MRCC) originally installed in 1977. Significant engineering alterations to the MRCC and rusting of some of its interior sections necessitated repainting, which was completed in 1988. Great care was taken in selecting an appropriate paint (polyamide epoxy) and in ensuring correct application and curing procedures. Only very low levels of hydrocarbons were found in the MRCC atmosphere before initial pressurization after painting and curing. After pressurization, however, significant chemical contamination was found. The primary contaminants were aromatic hydrocarbons: xylenes (which were a major component of both the primer and topcoat paint) and ethyl benzene. The role that pressure played in stimulating off-gassing from the paint is not clear; the off-gassing rate was observed to be similar over a large range in chamber pressures from 1.6 to 31.0 atm abs. Scrubbing the chamber atmosphere with the chemical absorbent Purafil was effective in removing the contaminants. Contamination has been observed to slowly decline with chamber use and is expected to continue to improve with time. However, this contamination experience emphasizes the need for a high precision gas analysis program at any diving facility to ensure the safety of the breathing gas and chamber atmosphere.

  1. Inspector General

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Inspector General Office of the Secretary Dr. Ernest J. Moniz Secretary Dr. Elizabeth Sherwood-Randall Deputy Secretary Chief of Staff Office of the Under Secretary for Nuclear Security and National Nuclear Security Administration Frank G. Klotz Under Secretary for Nuclear Security Administrator, NNSA Madelyn Creedon Principal Deputy Administrator NNSA DEPARTMENT OF ENERGY Office of the Under Secretary for Management & Performance Vacant Under Secretary for Management and Performance Office

  2. Extreme-UV lithography vacuum chamber zone seal

    DOE Patents [OSTI]

    Haney, Steven J. (Tracy, CA); Herron, Donald Joe (Manteca, CA); Klebanoff, Leonard E. (San Ramon, CA); Replogle, William C. (Livermore, CA)

    2003-04-15

    Control of particle contamination on the reticle and carbon contamination of optical surfaces in photolithography systems can be achieved by the establishment of multiple pressure zones in the photolithography systems. The different zones will enclose the reticle, projection optics, wafer, and other components of system. The system includes a vacuum apparatus that includes: a housing defining a vacuum chamber; one or more metrology trays situated within the vacuum chamber each of which is supported by at least one support member, wherein the tray separates the vacuum chamber into a various compartments that are maintained at different pressures; and conductance seal devices for adjoining the perimeter of each tray to an inner surface of the housing wherein the tray is decoupled from vibrations emanating from the inner surface of the housing.

  3. Extreme-UV lithography vacuum chamber zone seal

    DOE Patents [OSTI]

    Haney, Steven J. (Tracy, CA); Herron, Donald Joe (Manteca, CA); Klebanoff, Leonard E. (San Ramon, CA); Replogle, William C. (Livermore, CA)

    2003-04-08

    Control of particle contamination on the reticle and carbon contamination of optical surfaces in photolithography systems can be achieved by the establishment of multiple pressure zones in the photolithography systems. The different zones will enclose the reticle, projection optics, wafer, and other components of system. The system includes a vacuum apparatus that includes: a housing defining a vacuum chamber; one or more metrology trays situated within the vacuum chamber each of which is supported by at least one support member, wherein the tray separates the vacuum chamber into a various compartments that are maintained at different pressures; and conductance seal devices for adjoining the perimeter of each tray to an inner surface of the housing wherein the tray is decoupled from vibrations emanating from the inner surface of the housing.

  4. Extreme-UV lithography vacuum chamber zone seal

    DOE Patents [OSTI]

    Haney, Steven J. (Tracy, CA); Herron, Donald Joe (Manteca, CA); Klebanoff, Leonard E. (San Ramon, CA); Replogle, William C. (Livermore, CA)

    2001-01-01

    Control of particle contamination on the reticle and carbon contamination of optical surfaces in photolithography systems can be achieved by the establishment of multiple pressure zones in the photolithography systems. The different zones will enclose the reticle, projection optics, wafer, and other components of system. The system includes a vacuum apparatus that includes: a housing defining a vacuum chamber; one or more metrology trays situated within the vacuum chamber each of which is supported by at least one support member, wherein the tray separates the vacuum chamber into a various compartments that are maintained at different pressures; and conductance seal devices for adjoining the perimeter of each tray to an inner surface of the housing wherein the tray is decoupled from vibrations emanating from the inner surface of the housing.

  5. Fuel subassembly leak test chamber for a nuclear reactor

    DOE Patents [OSTI]

    Divona, Charles J.

    1978-04-04

    A container with a valve at one end is inserted into a nuclear reactor coolant pool. Once in the pool, the valve is opened by a mechanical linkage. An individual fuel subassembly is lifted into the container by a gripper; the valve is then closed providing an isolated chamber for the subassembly. A vacuum is drawn on the chamber to encourage gaseous fission product leakage through any defects in the cladding of the fuel rods comprising the subassembly; this leakage may be detected by instrumentation, and the need for replacement of the assembly ascertained.

  6. Gas Electron Multiplier (GEM) Chamber Characteristics Test (Technical

    Office of Scientific and Technical Information (OSTI)

    Report) | SciTech Connect Gas Electron Multiplier (GEM) Chamber Characteristics Test Citation Details In-Document Search Title: Gas Electron Multiplier (GEM) Chamber Characteristics Test Gas Electron Multipliers (GEMs) have been used in many HEP experiments as tracking detectors. They are sensitive to X-rays which allows use beyond that of HEP. The UTA High Energy group has been working on using GEMs as the sensitive gap detector in a DHCAL for the ILC. The physics goals at the ILC put a

  7. Federation of Indian Chambers of Commerce & Industry (FICCI) | Department

    Energy Savers [EERE]

    of Energy Federation of Indian Chambers of Commerce & Industry (FICCI) Federation of Indian Chambers of Commerce & Industry (FICCI) March 20, 2007 - 11:37am Addthis Thank you Geoff (Pyatt) for that introduction. I'd like to thank FICCI for hosting this event and thank its leadership for their kind words. I'm very pleased to be here in India - and to be with all of you today. Since his very first days in office, President Bush has considered growing and strengthening the United

  8. Development of Microstrip Gas Chambers for Radiation Detection and Tracking

    Office of Scientific and Technical Information (OSTI)

    at High Rates: Final Status Repor (Journal Article) | SciTech Connect Development of Microstrip Gas Chambers for Radiation Detection and Tracking at High Rates: Final Status Repor Citation Details In-Document Search Title: Development of Microstrip Gas Chambers for Radiation Detection and Tracking at High Rates: Final Status Repor Authors: Sauli, F. ; /CERN ; , Publication Date: 2013-10-21 OSTI Identifier: 1097431 Report Number(s): SLAC-PUB-15815 DOE Contract Number: AC02-76SF00515 Resource

  9. CLEERS Coordination & Joint Development of Benchmark Kinetics...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Catalyst Process Kinetic Data CLEERS Coordination & Joint Development of Benchmark Kinetics for LNT & SCR Functionality of Commercial NOx Storage-Reduction Catalysts...

  10. On the relationships between Michaelis–Menten kinetics, reverse Michaelis–Menten kinetics, Equilibrium Chemistry Approximation kinetics and quadratic kinetics

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Tang, J. Y.

    2015-09-03

    The Michaelis–Menten kinetics and the reverse Michaelis–Menten kinetics are two popular mathematical formulations used in many land biogeochemical models to describe how microbes and plants would respond to changes in substrate abundance. However, the criteria of when to use which of the two are often ambiguous. Here I show that these two kinetics are special approximations to the Equilibrium Chemistry Approximation kinetics, which is the first order approximation to the quadratic kinetics that solves the equation of enzyme-substrate complex exactly for a single enzyme single substrate biogeochemical reaction with the law of mass action and the assumption of quasi-steady-state formore » the enzyme-substrate complex and that the product genesis from enzyme-substrate complex is much slower than the equilibration between enzyme-substrate complexes, substrates and enzymes. In particular, I showed that the derivation of the Michaelis–Menten kinetics does not consider the mass balance constraint of the substrate, and the reverse Michaelis–Menten kinetics does not consider the mass balance constraint of the enzyme, whereas both of these constraints are taken into account in the Equilibrium Chemistry Approximation kinetics. By benchmarking against predictions from the quadratic kinetics for a wide range of substrate and enzyme concentrations, the Michaelis–Menten kinetics was found to persistently under-predict the normalized sensitivity ∂ ln v / ∂ ln k2+ of the reaction velocity v with respect to the maximum product genesis rate k2+, persistently over-predict the normalized sensitivity ∂ ln v / ∂ ln k1+ of v with respect to the intrinsic substrate affinity k1+, persistently over-predict the normalized sensitivity ∂ ln v / ∂ ln [ E ]T of v with respect the total enzyme concentration [ E ]T and persistently under-predict the normalized sensitivity ∂ ln v / ∂ ln [ S ]T of v with respect to the total substrate concentration [ S ]T. Meanwhile, the reverse Michaelis–Menten kinetics persistently under-predicts ∂ ln v / ∂ ln k2+ and ∂ ln v / ∂ ln [ E ]T, and persistently over-predicts ∂ ln v / ∂ ln k1+ and ∂ ln v / ∂ ln [ S ]T. In contrast, the Equilibrium Chemistry Approximation kinetics always gives consistent predictions of ∂ ln v / ∂ ln k2+, ∂ ln v / ∂ ln k1+, ∂ ln v / ∂ ln [ E ]T and ∂ ln v / ∂ ln [ S ]T. Since the Equilibrium Chemistry Approximation kinetics includes the advantages from both the Michaelis–Menten kinetics and the reverse Michaelis–Menten kinetics and it is applicable for almost the whole range of substrate and enzyme abundances, soil biogeochemical modelers therefore no longer need to choose when to use the Michaelis–Menten kinetics or the reverse Michaelis–Menten kinetics. I expect removing this choice ambiguity will make it easier to formulate more robust and consistent land biogeochemical models.« less

  11. General Publications

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    General Publications Print ALS Strategic Plan 2015-19 cover image An updated version of the ALS Strategic Plan, covering the five-year period from 2015 to 2019. As in the 2014-18 version, Section I gives a brief synopsis on beamline and endstation projects. The science drivers behind these projects are explained in greater detail in Section II, and a very brief description of emerging plans for a ALS-U are in Section III. Soft X-ray Science Opportunities Using Diffraction-Limited Storage Rings A

  12. Methyl Formate Oxidation: Speciation Data, Laminar Burning Velocities, Ignition Delay Times and a Validated Chemical Kinetic Model

    SciTech Connect (OSTI)

    Dooley, S.; Burke, M. P.; Chaos, M.; Stein, Y.; Dryer, F. L.; Zhukov, V. P.; Finch, O.; Simmie, J. M.; Curran, H. J.

    2010-07-16

    The oxidation of methyl formate (CH{sub 3}OCHO) has been studied in three experimental environments over a range of applied combustion relevant conditions: 1. A variable-pressure flow reactor has been used to quantify reactant, major intermediate and product species as a function of residence time at 3 atm and 0.5% fuel concentration for oxygen/fuel stoichiometries of 0.5, 1.0, and 1.5 at 900 K, and for pyrolysis at 975 K. 2. Shock tube ignition delays have been determined for CH{sub 3}OCHO/O{sub 2}/Ar mixtures at pressures of ? 2.7, 5.4, and 9.2 atm and temperatures of 12751935 K for mixture compositions of 0.5% fuel (at equivalence ratios of 1.0, 2.0, and 0.5) and 2.5% fuel (at an equivalence ratio of 1.0). 3. Laminar burning velocities of outwardly propagating spherical CH{sub 3}OCHO/air flames have been determined for stoichiometries ranging from 0.81.6, at atmospheric pressure using a pressure-release-type high-pressure chamber. A detailed chemical kinetic model has been constructed, validated against, and used to interpret these experimental data. The kinetic model shows that methyl formate oxidation proceeds through concerted elimination reactions, principally forming methanol and carbon monoxide as well as through bimolecular hydrogen abstraction reactions. The relative importance of elimination versus abstraction was found to depend on the particular environment. In general, methyl formate is consumed exclusively through molecular decomposition in shock tube environments, while at flow reactor and freely propagating premixed flame conditions, there is significant competition between hydrogen abstraction and concerted elimination channels. It is suspected that in diffusion flame configurations the elimination channels contribute more significantly than in premixed environments.

  13. QER- Comment of PA Chamber of Business and Industry

    Broader source: Energy.gov [DOE]

    On behalf of Gene Barr, President & CEO of the Pennsylvania Chamber of Business and Industry, please find attached our comments regarding Natural Gas Transmission, Storage & Distribution, Pittsburgh, Pennsylvania July 21, 2014. Thanks in advance for the attention to our comments and for holding a hearing today in our state. All the best, Kevin

  14. Verifying Sensor Response to Difficult Chemicals with a New Test Chamber Concept

    SciTech Connect (OSTI)

    Maughan, A. D.; Birnbaum, Jerome C.; Probasco, Kathleen M.

    2004-06-01

    In this article we discuss the application of technology innovations to optimize detection of hard-to-measure (less- or semi-volatile) compounds. These chemicals are found all around us: in pesticides and herbicides, the higher boiling polyaromatic hydrocarbons in diesel exhaust, and linked polyurethane foams in products ranging from hiking boots to acoustic ceilings. They appear in low concentrations and evaporate very slowly. These heavier chemicals are rarely measured accurately because they stick to surfaces and sampling equipment and, consequently, are not reliably sampled or delivered to analytical detectors. Its like trying to identify cold, sticky honey by getting it to flow in through a sampling tube to a detector it will hardly move. Honey generally coats out on surfaces and sample lines to the extent that even if it is detected, the amount present is vastly underestimated. Researchers at Pacific Northwest National Laboratory (PNNL) addressed the problem by developing a chamber facility with instrumentation that can overcome the under-reporting of these ubiquitous chemical compounds. The atmospheric chemistry chamber provides a controlled environment in which to certify the accuracy of and conditions under which sensors can best respond to volatile and semi-volatile chemicals. The facility is designed to handle and measure chemicals at the levels at which they are found in nature. Test environments can be created in which atmospheric concentrations are at low part-per-trillion concentrations. These concentrations are equivalent to an herbicide off-gassing from a commercially grown apple. The chamber can be set up to simulate releases ranging from industrial vents with high concentrations to releases from surfaces, soils, and/or vegetation where the concentrations are low.

  15. Chamber for the optical manipulation of microscopic particles

    DOE Patents [OSTI]

    Buican, Tudor N. (Los Alamos, NM); Upham, Bryan D. (Los Alamos, NM)

    1992-01-01

    A particle control chamber enables experiments to be carried out on biological cells and the like using a laser system to trap and manipulate the particles. A manipulation chamber provides a plurality of inlet and outlet ports for the particles and for fluids used to control or to contact the particles. A central manipulation area is optically accessible by the laser and includes first enlarged volumes for containing a selected number of particles for experimentation. A number of first enlarged volumes are connected by flow channels through second enlarged volumes. The second enlarged volumes act as bubble valves for controlling the interconnections between the first enlarged volumes. Electrode surfaces may be applied above the first enlarged volumes to enable experimentation using the application of electric fields within the first enlarged volumes. A variety of chemical and environmental conditions may be established within individual first enlarged volumes to enable experimental conditions for small scale cellular interactions.

  16. Luis Alvarez, the Hydrogen Bubble Chamber, Tritium, and Dinosaurs

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Luis Alvarez, the Hydrogen Bubble Chamber, Tritium, and Dinosaurs Resources with Additional Information * Patents Luis Alvarez Courtesy Lawrence Berkeley National Laboratory 'Luis W. Alvarez was an adventurer physicist. The two terms may seem an odd combination until one considers Alvarez's career. A member of the National Inventor's Hall of Fame, Alvarez developed the proton linear accelerator, patented three types of radar still used today, designed an instrument that for 15 years served as

  17. Using sputter coated glass to stabilize microstrip gas chambers

    DOE Patents [OSTI]

    Gong, Wen G. (Albany, CA)

    1997-01-01

    By sputter coating a thin-layer of low-resistive, electronically-conductive glass on various substrates (including quartz and ceramics, thin-film Pestov glass), microstrip gas chambers (MSGC) of high gain stability, low leakage current, and a high rate capability can be fabricated. This design can make the choice of substrate less important, save the cost of ion-implantation, and use less glass material.

  18. NIF Target Chamber Dedicated | National Nuclear Security Administration

    National Nuclear Security Administration (NNSA)

    NIF Target Chamber Dedicated | National Nuclear Security Administration Facebook Twitter Youtube Flickr RSS People Mission Managing the Stockpile Preventing Proliferation Powering the Nuclear Navy Emergency Response Recapitalizing Our Infrastructure Countering Nuclear Terrorism About Our Programs Our History Who We Are Our Leadership Our Locations Budget Our Operations Library Bios Congressional Testimony Fact Sheets Newsletters Press Releases Photo Gallery Jobs Apply for Our Jobs Our Jobs

  19. Dark Matter Search Results from the PICO-60 CF$_3$I Bubble Chamber...

    Office of Scientific and Technical Information (OSTI)

    Dark Matter Search Results from the PICO-60 CF3I Bubble Chamber Citation Details In-Document Search Title: Dark Matter Search Results from the PICO-60 CF3I Bubble Chamber...

  20. The Hydriding Kinetics of Organic Hydrogen Getters

    SciTech Connect (OSTI)

    Powell, G. L.

    2002-02-11

    The aging of hermetically sealed systems is often accompanied by the gradual production of hydrogen gas that is a result of the decay of environmental gases and the degradation of organic materials. In particular, the oxygen, water, hydrogen ''equilibrium'' is affected by the removal of oxygen due the oxidation of metals and organic materials. This shift of the above ''equilibrium'' towards the formation of hydrogen gas, particularly in crevices, may eventually reach an explosive level of hydrogen gas or degrade metals by hydriding them. The latter process is generally delayed until the oxidizing species are significantly reduced. Organic hydrogen getters introduced by Allied Signal Aerospace Company, Kansas City Division have proven to be a very effective means of preventing hydrogen gas accumulation in sealed containers. These getters are relatively unaffected by air and environmental gases. They can be packaged in a variety of ways to fit particular needs such as porous pellets, fine or coarse [gravel] powder, or loaded into silicone rubber. The hydrogen gettering reactions are extremely irreversible since the hydrogen gas is converted into an organic hydrocarbon. These getters are based on the palladium-catalyzed hydrogenation of triple bonds to double and then single bonds in aromatic aryl compounds. DEB (1,4 bis (phenyl ethynyl) benzene) typically mixed with 25% by weight carbon with palladium (1% by weight of carbon) is one of the newest and best of these organic hydrogen getters. The reaction mechanisms are complex involving solid state reaction with a heterogeneous catalyst leading to the many intermediates, including mixed alkyl and aryl hydrocarbons with the possibilities of many isomers. The reaction kinetics mechanisms are also strongly influenced by the form in which they are packaged. For example, the hydriding rates for pellets and gravel have a strong dependence on reaction extent (i.e., DEB reduction) and a kinetic order in pressure of 0.76. Silicone rubber based DEB getters hydride at a much lower rate, have little dependence on reaction extent, have a higher kinetic order in pressure (0.87), and have a lower activation energy. The kinetics of the reaction as a function of hydrogen pressure, stoichiometry, and temperature for hydrogen and deuterium near ambient temperature (0 to 75 C) for pressures near or below 100 Pa over a wide range (in some cases, the complete) hydrogenation range are presented along with multi-dimensional rate models.

  1. Detailed Kinetic Modeling of Gasoline Surrogate Mixtures

    SciTech Connect (OSTI)

    Mehl, M; Curran, H J; Pitz, W J; Westbrook, C K

    2009-03-09

    Real fuels are complex mixtures of thousands of hydrocarbon compounds including linear and branched paraffins, naphthenes, olefins and aromatics. It is generally agreed that their behavior can be effectively reproduced by simpler fuel surrogates containing a limited number of components. In this work, a recently revised version of the kinetic model by the authors is used to analyze the combustion behavior of several components relevant to gasoline surrogate formulation. Particular attention is devoted to linear and branched saturated hydrocarbons (PRF mixtures), olefins (1-hexene) and aromatics (toluene). Model predictions for pure components, binary mixtures and multi-component gasoline surrogates are compared with recent experimental information collected in rapid compression machine, shock tube and jet stirred reactors covering a wide range of conditions pertinent to internal combustion engines. Simulation results are discussed focusing attention on the mixing effects of the fuel components.

  2. Kinetics, Mechanics and Microstructure Changes in Storage Media...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Kinetics, Mechanics and Microstructure Changes in Storage Media Kinetics, Mechanics and Microstructure Changes in Storage Media Presentation on the Kinetics, Mechanics and ...

  3. AER NY Kinetics LLC | Open Energy Information

    Open Energy Info (EERE)

    AER NY Kinetics LLC Jump to: navigation, search Name: AER NY Kinetics LLC Address: PO Box 585 21 Entrance Avenue Place: Ogdensburg Zip: 13669 Region: United States Sector: Marine...

  4. Possibility of using cylindrical ionization chambers for percent depth-dose measurements in clinical electron beams

    SciTech Connect (OSTI)

    Ono, Takeshi; Araki, Fujio; Yoshiyama, Fumiaki

    2011-08-15

    Purpose: This study investigated the possibility of using cylindrical ionization chambers for percent depth-dose (PDD) measurements in high-energy clinical electron beams. Methods: The cavity correction factor, P{sub cav}, for cylindrical chambers with various diameters was calculated as a function of depth from the surface to R{sub 50}, in the energy range of 6-18 MeV electrons with the EGSnrc C ++ -based user-code CAVITY. The results were compared with those for IBA NACP-02 and PTW Roos parallel-plate ionization chambers. The effective point of measurement (EPOM) for the cylindrical chamber and the parallel-plate chamber was positioned according to the IAEA TRS-398 code of practice. The overall correction factor, P{sub Q}, and the percent depth-ionization (PDI) curve for a PTW30013 Farmer-type chamber were also compared with those of NACP-02 and Roos chambers. Results: The P{sub cav} values at depths between the surface and R{sub 50} for cylindrical chambers were all lower than those with parallel-plate chambers. However, the variation in depth for cylindrical chambers equal to or less than 4 mm in diameter was equivalent to or smaller than that for parallel-plate chambers. The P{sub Q} values for the PTW30013 chamber mainly depended on P{sub cav}, and for parallel-plate chambers depended on the wall correction factor, P{sub wall}, rather than P{sub cav}. P{sub Q} at depths from the surface to R{sub 50} for the PTW30013 chamber was consequently a lower value than that with parallel-plate chambers. However, the variation in depth was equivalent to that of parallel-plate chambers at electron energies equal to or greater than 9 MeV. The shift to match calculated PDI curves for the PTW30013 chamber and water (perturbation free) varied from 0.65 to 0 mm between 6 and 18 MeV beams. Similarly, the shifts for NACP-02 and Roos chambers were 0.5-0.6 mm and 0.2-0.3 mm, respectively, and were nearly independent of electron energy. Conclusions: Calculated PDI curves for PTW30013, NACP-02, and Roos chambers agreed well with that of water by using the optimal EPOM. Therefore, the possibility of using cylindrical ionization chambers can be expected for PDD measurements in clinical electron beams.

  5. Performance parameters of a liquid filled ionization chamber array

    SciTech Connect (OSTI)

    Poppe, B.; Stelljes, T. S.; Looe, H. K.; Chofor, N.; Harder, D.; Willborn, K.

    2013-08-15

    Purpose: In this work, the properties of the two-dimensional liquid filled ionization chamber array Octavius 1000SRS (PTW-Freiburg, Germany) for use in clinical photon-beam dosimetry are investigated.Methods: Measurements were carried out at an Elekta Synergy and Siemens Primus accelerator. For measurements of stability, linearity, and saturation effects of the 1000SRS array a Semiflex 31013 ionization chamber (PTW-Freiburg, Germany) was used as a reference. The effective point of measurement was determined by TPR measurements of the array in comparison with a Roos chamber (type 31004, PTW-Freiburg, Germany). The response of the array with varying field size and depth of measurement was evaluated using a Semiflex 31010 ionization chamber as a reference. Output factor measurements were carried out with a Semiflex 31010 ionization chamber, a diode (type 60012, PTW-Freiburg, Germany), and the detector array under investigation. The dose response function for a single detector of the array was determined by measuring 1 cm wide slit-beam dose profiles and comparing them against diode-measured profiles. Theoretical aspects of the low pass properties and of the sampling frequency of the detector array were evaluated. Dose profiles measured with the array and the diode detector were compared, and an intensity modulated radiation therapy (IMRT) field was verified using the Gamma-Index method and the visualization of line dose profiles.Results: The array showed a short and long term stability better than 0.1% and 0.2%, respectively. Fluctuations in linearity were found to be within 0.2% for the vendor specified dose range. Saturation effects were found to be similar to those reported in other studies for liquid-filled ionization chambers. The detector's relative response varied with field size and depth of measurement, showing a small energy dependence accounting for maximum signal deviations of 2.6% from the reference condition for the setup used. The ?-values of the Gaussian dose response function for a single detector of the array were found to be (0.72 0.25) mm at 6 MV and (0.74 0.25) mm at 15 MV and the corresponding low pass cutoff frequencies are 0.22 and 0.21 mm{sup ?1}, respectively. For the inner 5 5 cm{sup 2} region and the outer 11 11 cm{sup 2} region of the array the Nyquist theorem is fulfilled for maximum sampling frequencies of 0.2 and 0.1 mm{sup ?1}, respectively. An IMRT field verification with a Gamma-Index analysis yielded a passing rate of 95.2% for a 3 mm/3% criterion with a TPS calculation as reference.Conclusions: This study shows the applicability of the Octavius 1000SRS in modern dosimetry. Output factor and dose profile measurements illustrated the applicability of the array in small field and stereotactic dosimetry. The high spatial resolution ensures adequate measurements of dose profiles in regular and intensity modulated photon-beam fields.

  6. Dual chamber system providing simultaneous etch and deposition on opposing substrate sides for growing low defect density epitaxial layers

    DOE Patents [OSTI]

    Kulkarni, Nagraj S. (Knoxville, TN); Kasica, Richard J. (Ashburn, VA) ,

    2011-03-08

    A dual-chamber reactor can include a housing enclosing a volume having a divider therein, where the divider defines a first chamber and a second chamber. The divider can include a substrate holder that supports at least one substrate and exposes a first side of the substrate to the first chamber and a second side of the substrate to the second chamber. The first chamber can include an inlet for delivering at least one reagent to the first chamber for forming a film on the first side of the substrate, and the second chamber can include a removal device for removing material from the second side of the substrate.

  7. Benchmarking kinetic calculations of resistive wall mode stability

    SciTech Connect (OSTI)

    Berkery, J. W.; Sabbagh, S. A.; Liu, Y. Q.; Betti, R.

    2014-05-15

    Validating the calculations of kinetic resistive wall mode (RWM) stability is important for confidently predicting RWM stable operating regions in ITER and other high performance tokamaks for disruption avoidance. Benchmarking the calculations of the Magnetohydrodynamic Resistive SpectrumKinetic (MARS-K) [Y. Liu et al., Phys. Plasmas 15, 112503 (2008)], Modification to Ideal Stability by Kinetic effects (MISK) [B. Hu et al., Phys. Plasmas 12, 057301 (2005)], and Perturbed Equilibrium Nonambipolar Transport (PENT) [N. Logan et al., Phys. Plasmas 20, 122507 (2013)] codes for two Solov'ev analytical equilibria and a projected ITER equilibrium has demonstrated good agreement between the codes. The important particle frequencies, the frequency resonance energy integral in which they are used, the marginally stable eigenfunctions, perturbed Lagrangians, and fluid growth rates are all generally consistent between the codes. The most important kinetic effect at low rotation is the resonance between the mode rotation and the trapped thermal particle's precession drift, and MARS-K, MISK, and PENT show good agreement in this term. The different ways the rational surface contribution was treated historically in the codes is identified as a source of disagreement in the bounce and transit resonance terms at higher plasma rotation. Calculations from all of the codes support the present understanding that RWM stability can be increased by kinetic effects at low rotation through precession drift resonance and at high rotation by bounce and transit resonances, while intermediate rotation can remain susceptible to instability. The applicability of benchmarked kinetic stability calculations to experimental results is demonstrated by the prediction of MISK calculations of near marginal growth rates for experimental marginal stability points from the National Spherical Torus Experiment (NSTX) [M. Ono et al., Nucl. Fusion 40, 557 (2000)].

  8. Neoclassical toroidal viscosity in perturbed equilibria with general tokamak geometry

    SciTech Connect (OSTI)

    Logan, Nikolas C.; Park, Jong-Kyu; Kim, Kimin; Wang, Zhirui; Berkery, John W.

    2013-12-15

    This paper presents a calculation of neoclassical toroidal viscous torque independent of large-aspect-ratio expansions across kinetic regimes. The Perturbed Equilibrium Nonambipolar Transport (PENT) code was developed for this purpose, and is compared to previous combined regime models as well as regime specific limits and a drift kinetic ?f guiding center code. It is shown that retaining general expressions, without circular large-aspect-ratio or other orbit approximations, can be important at experimentally relevant aspect ratio and shaping. The superbanana plateau, a kinetic resonance effect recently recognized for its relevance to ITER, is recovered by the PENT calculations and shown to require highly accurate treatment of geometric effects.

  9. Nonlinear theory of drift-cyclotron kinetics and the possible breakdown of gyro-kinetics

    SciTech Connect (OSTI)

    Waltz, R. E.; Deng Zhao

    2013-01-15

    A nonlinear theory of drift-cyclotron kinetics (termed cyclo-kinetics here) is formulated to test the breakdown of the gyro-kinetic approximations. Six dimensional cyclo-kinetics can be regarded as an extension of five dimensional gyro-kinetics to include high-frequency cyclotron waves, which can interrupt the low-frequency gyro-averaging in the (sixth velocity grid) gyro-phase angle. Nonlinear cyclo-kinetics has no limit on the amplitude of the perturbations. Formally, there is no gyro-averaging when all cyclotron (gyro-phase angle) harmonics of the perturbed distribution function (delta-f) are retained. Retaining only the (low frequency) zeroth cyclotron harmonic in cyclo-kinetics recovers both linear and nonlinear gyro-kinetics. Simple recipes are given for converting continuum nonlinear delta-f gyro-kinetic transport simulation codes to cyclo-kinetics codes by retaining (at least some) higher cyclotron harmonics.

  10. Atmospheric-pressure plasma decontamination/sterilization chamber

    DOE Patents [OSTI]

    Herrmann, Hans W. (Los Alamos, NM); Selwyn, Gary S. (Los Alamos, NM)

    2001-01-01

    An atmospheric-pressure plasma decontamination/sterilization chamber is described. The apparatus is useful for decontaminating sensitive equipment and materials, such as electronics, optics and national treasures, which have been contaminated with chemical and/or biological warfare agents, such as anthrax, mustard blistering agent, VX nerve gas, and the like. There is currently no acceptable procedure for decontaminating such equipment. The apparatus may also be used for sterilization in the medical and food industries. Items to be decontaminated or sterilized are supported inside the chamber. Reactive gases containing atomic and metastable oxygen species are generated by an atmospheric-pressure plasma discharge in a He/O.sub.2 mixture and directed into the region of these items resulting in chemical reaction between the reactive species and organic substances. This reaction typically kills and/or neutralizes the contamination without damaging most equipment and materials. The plasma gases are recirculated through a closed-loop system to minimize the loss of helium and the possibility of escape of aerosolized harmful substances.

  11. Fuel, lubricant and additive effects in combustion chamber deposit formation

    SciTech Connect (OSTI)

    Kelemen, S.R.; Homan, H.S.

    1996-10-01

    CCD causes octane requirement increase (ORI) and can potentially contributes to exhaust emissions and combustion chamber deposit interference (CCDI). Experiments were conducted to identify the separate fuel, lubricant and additive contributions to the amount and composition of CCD. CCD originates from multiple sources. Gasoline hydrocarbon components, gasoline additives, engine lubricant, and atmospheric nitrogen contribute to CCD in different ways. With some fuels the engine lubricant is the main contributor to CCD and this is shown by the high ash level in the CCD. For other fuels CCD is predominantly organic. Significant amounts of nitrogen were found in the CCD even when the fuel and lubricant were nitrogen free. The pyrolysis reactivity of different CCDs was studied to gain an understanding about the transformations that potentially happen over longer times and lower temperatures on the combustion chamber walls. In all cases during mild pyrolysis (375{degrees}C) there was a substantial increase in the level of aromatic carbon and a decrease in the level of organic oxygen. The largest increases in the amount of aromatic carbon occurred for CCDs that were the least aromatic.

  12. Slag monitoring system for combustion chambers of steam boilers

    SciTech Connect (OSTI)

    Taler, J.; Taler, D.

    2009-07-01

    The computer-based boiler performance system presented in this article has been developed to provide a direct and quantitative assessment of furnace and convective surface cleanliness. Temperature, pressure, and flow measurements and gas analysis data are used to perform heat transfer analysis in the boiler furnace and evaporator. Power boiler efficiency is calculated using an indirect method. The on-line calculation of the exit flue gas temperature in a combustion chamber allows for an on-line heat flow rate determination, which is transferred to the boiler evaporator. Based on the energy balance for the boiler evaporator, the superheated steam mass flow rate is calculated taking into the account water flow rate in attemperators. Comparing the calculated and the measured superheated steam mass flow rate, the effectiveness of the combustion chamber water walls is determined in an on-line mode. Soot-blower sequencing can be optimized based on actual cleaning requirements rather than on fixed time cycles contributing to lowering of the medium usage in soot blowers and increasing of the water-wall lifetime.

  13. Wire-chamber radiation detector with discharge control

    DOE Patents [OSTI]

    Perez-Mendez, V.; Mulera, T.A.

    1982-03-29

    A wire chamber; radiation detector has spaced apart parallel electrodes and grids defining an ignition region in which charged particles or other ionizing radiations initiate brief localized avalanche discharges and defining an adjacent memory region in which sustained glow discharges are initiated by the primary discharges. Conductors of the grids at each side of the memory section extend in orthogonal directions enabling readout of the X-Y coordinates of locations at which charged particles were detected by sequentially transmitting pulses to the conductors of one grid while detecting transmissions of the pulses to the orthogonal conductors of the other grid through glow discharges. One of the grids bounding the memory region is defined by an array of conductive elements each of which is connected to the associated readout conductor through a separate resistance. The wire chamber avoids ambiguities and imprecisions in the readout of coordinates when large numbers of simultaneous or; near simultaneous charged particles have been detected. Down time between detection periods and the generation of radio frequency noise are also reduced.

  14. A = 5 General Tables

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    5 General Tables The General Table for 5H is subdivided into the following categories: Cluster Model Hypernuclei Model Calculations Photodisintegration Pions The General Table for...

  15. An Experimental and Chemical Kinetics Study of the Combustion of Syngas and High Hydrogen Content Fuels

    SciTech Connect (OSTI)

    Santoro, Robers; Dryer, Frederick; Ju, Yiguang

    2013-09-30

    An integrated and collaborative effort involving experiments and complementary chemical kinetic modeling investigated the effects of significant concentrations of water and CO2 and minor contaminant species (methane [CH4], ethane [C2H6], NOX, etc.) on the ignition and combustion of HHC fuels. The research effort specifically addressed broadening the experimental data base for ignition delay, burning rate, and oxidation kinetics at high pressures, and further refinement of chemical kinetic models so as to develop compositional specifications related to the above major and minor species. The foundation for the chemical kinetic modeling was the well validated mechanism for hydrogen and carbon monoxide developed over the last 25 years by Professor Frederick Dryer and his co-workers at Princeton University. This research furthered advance the understanding needed to develop practical guidelines for realistic composition limits and operating characteristics for HHC fuels. A suite of experiments was utilized that that involved a high-pressure laminar flow reactor, a pressure-release type high-pressure combustion chamber and a high-pressure turbulent flow reactor.

  16. Readout of TPC Tracking Chambers with GEMs and Pixel Chip

    SciTech Connect (OSTI)

    Kadyk, John; Kim, T.; Freytsis, M.; Button-Shafer, J.; Kadyk, J.; Vahsen, S.E.; Wenzel, W.A.

    2007-12-21

    Two layers of GEMs and the ATLAS Pixel Chip, FEI3, have been combined and tested as a prototype for Time Projection Chamber (TPC) readout at the International Linear Collider (ILC). The double-layer GEM system amplifies charge with gain sufficient to detect all track ionization. The suitability of three gas mixtures for this application was investigated, and gain measurements are presented. A large sample of cosmic ray tracks was reconstructed in 3D by using the simultaneous timing and 2D spatial information from the pixel chip. The chip provides pixel charge measurement as well as timing. These results demonstrate that a double GEM and pixel combination, with a suitably modified pixel ASIC, could meet the stringent readout requirements of the ILC.

  17. Conceptual Design Report for the Extreme Ecosystems Test Chambers

    SciTech Connect (OSTI)

    C. Barnes; J. Beller; K. Caldwell; K. Croft; R. Cherry; W. Landman

    1998-12-01

    This conceptual design supports the creation of Extreme Ecosystems Test Chambers, which will replicate deep subsurface and subocean environments characterized by high pressure (2,000 psi) and subfreezing to high temperature (-4 to 300 degrees F) with differing chemical and saturation conditions. The design provides a system to support research and development that includes heat transfer, phase change issues in porous media, microbiology in extreme environments, and carbon sequestration and extraction. The initial system design is based on the research needs to support the commercial production of methane hydrates from subsurface sediments. The design provides for three pressure vessels: a Down Hole Test Vessel, a Vertical Multi-phase Test Vessel, and a Horizontal Multi-phase Test Vessel.

  18. Effects of acidic deposition on paint: A chamber study

    SciTech Connect (OSTI)

    Spence, J.W.; Lemmons, T.J.; Hou, Y.; Schadt, R.J.; Fornes, R.E.

    1993-08-01

    Exterior acrylic latex and alkyd architectural coatings were exposed to different conditions in a chamber exposure system involving simulated sunlight, dew, and photochemical smog-containing sulfur dioxide (SO2). A simulated sunlight exposure of the coating films in the presence of clean air was also incorporated into the experimental design. Changes in surface features after 1,370 hours of exposure were characterized by scanning electron microscope (SEM) and energy dispersive analysis of x-rays (EDAX). Gaseous species that deposited to the films were determined by ion chromatography of the dew collections. Color-change measurements of the exposed films were recorded as Delta E values. Latex and alkyd films that were formulated with calcium carbonate (CACO3) as an extender pigment were found to undergo the most change in surface features, composition, and color.

  19. 8C General Tables

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    C General Tables The General Table for 8C is subdivided into the following categories: Reviews Other Theoretical Work

  20. 6Be General Tables

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    6Be General Table The General Table for 6Be is subdivided into the following categories: Cluster Model Model Calculations...

  1. Kinetic Modeling of Microbiological Processes

    SciTech Connect (OSTI)

    Liu, Chongxuan; Fang, Yilin

    2012-09-17

    Kinetic description of microbiological processes is vital for the design and control of microbe-based biotechnologies such as waste water treatment, petroleum oil recovery, and contaminant attenuation and remediation. Various models have been proposed to describe microbiological processes. This editorial article discusses the advantages and limiation of these modeling approaches in cluding tranditional, Monod-type models and derivatives, and recently developed constraint-based approaches. The article also offers the future direction of modeling researches that best suit for petroleum and environmental biotechnologies.

  2. Pressure Loads by Gas in an Enclosed Chamber in DYNA3D

    SciTech Connect (OSTI)

    Lin, J; Badders, D C

    2002-08-08

    New algorithms that efficiently calculate the volume of a closed chamber are presented in this paper. The current pressure in the enclosed chamber can then be computed, based on the user-specified gas law, from the updated volume and the initial volume and pressure of the chamber. This pressure load function is very useful in modeling common features, such as air pocket, airbag, piston, and gun barrel, in structural analyses.

  3. The American Chamber of Commerce of Trinidad & Tobago | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Chamber of Commerce of Trinidad & Tobago The American Chamber of Commerce of Trinidad & Tobago May 13, 2008 - 12:00pm Addthis Remarks As Prepared for Delivery by Secretary Bodman Thank you, Raymond. I appreciate the Chamber organizing this gathering this morning. The American Chamber here on Trinidad and Tobago is an important regional voice in support of the free market, so I want to commend you for hosting the Business Future of the Americas conference next month. Having

  4. Liquid fuel vaporizer and combustion chamber having an adjustable thermal conductor

    DOE Patents [OSTI]

    Powell, Michael R; Whyatt, Greg A; Howe, Daniel T; Fountain, Matthew S

    2014-03-04

    The efficiency and effectiveness of apparatuses for vaporizing and combusting liquid fuel can be improved using thermal conductors. For example, an apparatus having a liquid fuel vaporizer and a combustion chamber can be characterized by a thermal conductor that conducts heat from the combustion chamber to the vaporizer. The thermal conductor can be a movable member positioned at an insertion depth within the combustion chamber that corresponds to a rate of heat conduction from the combustion chamber to the vaporizer. The rate of heat conduction can, therefore, be adjusted by positioning the movable member at a different insertion depth.

  5. Los Alamos honored by Española Valley Chamber of Commerce

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    LANL Honored By Española Valley Chamber of Commerce Community Connections: Your link to news and opportunities from Los Alamos National Laboratory Latest Issue:Mar. 2016 all issues All Issues » submit Los Alamos honored by Española Valley Chamber of Commerce The Espanola Valley Chamber of Commerce recognized the Lab for its support to the chamber and the entire Espanola Valley with a President's Choice Award. February 1, 2013 dummy image Read our archives. Contacts Editor Linda Anderman Email

  6. Free surface modeling in OWC chamber with parabolic side walls using 3D BEM

    SciTech Connect (OSTI)

    Hasanabad, Madjid Ghodsi

    2015-03-10

    In this paper, BEM was used for free surface modeling in OWC chamber and out of it. Linear kinematic and dynamic boundary conditions were used for free surface out of OWC chamber and nonlinear forms were used for free surface in the chamber. These boundary conditions were discretized by finite differences method. Also, some thermodynamics relations were applied for trapped air behavior modeling in OWC chamber. Wave specifications in Chabahar region were used in modeling because these waves have an acceptable power for electricity generation. The results show a good agreement with results of other researches.

  7. Combustion kinetics and reaction pathways

    SciTech Connect (OSTI)

    Klemm, R.B.; Sutherland, J.W.

    1993-12-01

    This project is focused on the fundamental chemistry of combustion. The overall objectives are to determine rate constants for elementary reactions and to elucidate the pathways of multichannel reactions. A multitechnique approach that features three independent experiments provides unique capabilities in performing reliable kinetic measurements over an exceptionally wide range in temperature, 300 to 2500 K. Recent kinetic work has focused on experimental studies and theoretical calculations of the methane dissociation system (CH{sub 4} + Ar {yields} CH{sub 3} + H + Ar and H + CH{sub 4} {yields} CH{sub 3} + H{sub 2}). Additionally, a discharge flow-photoionization mass spectrometer (DF-PIMS) experiment is used to determine branching fractions for multichannel reactions and to measure ionization thresholds of free radicals. Thus, these photoionization experiments generate data that are relevant to both reaction pathways studies (reaction dynamics) and fundamental thermochemical research. Two distinct advantages of performing PIMS with high intensity, tunable vacuum ultraviolet light at the National Synchrotron Light Source are high detection sensitivity and exceptional selectivity in monitoring radical species.

  8. Thermodynamic and kinetic characterization of hydroxyethylamine

    Office of Scientific and Technical Information (OSTI)

    β-secretase-1 inhibitors (Journal Article) | SciTech Connect Thermodynamic and kinetic characterization of hydroxyethylamine β-secretase-1 inhibitors Citation Details In-Document Search Title: Thermodynamic and kinetic characterization of hydroxyethylamine β-secretase-1 inhibitors Highlights: *Kinetic and thermodynamic characterization of 10 hydroxyethylamine BACE-1 inhibitors. *Equilibrium binding of inhibitors was enthalpy driven for BACE-1. *Negative entropy of binding was observed

  9. Generalization of the Activated Complex Theory of Reaction Rates. II. Classical Mechanical Treatment

    DOE R&D Accomplishments [OSTI]

    Marcus, R. A.

    1964-01-01

    In its usual classical form activated complex theory assumes a particular expression for the kinetic energy of the reacting system -- one associated with a rectilinear motion along the reaction coordinate. The derivation of the rate expression given in the present paper is based on the general kinetic energy expression.

  10. Multiscale Mathematics For Plasma Kinetics Spanning Multiple...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: Multiscale Mathematics For Plasma Kinetics Spanning Multiple Collisionality Regimes Citation Details In-Document Search Title: Multiscale Mathematics For Plasma...

  11. CLEERS Coordination & Joint Development of Benchmark Kinetics...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications CLEERS Coordination & Joint Development of Benchmark Kinetics for LNT & SCR Emissions Control for Lean Gasoline Engines NH3 generation...

  12. Kinetic Wave Power | Open Energy Information

    Open Energy Info (EERE)

    Wave Power Jump to: navigation, search Name: Kinetic Wave Power Address: 2861 N Tupelo St Place: Midland Zip: 48642 Region: United States Sector: Marine and Hydrokinetic Phone...

  13. Direct Kinetic Measurements of a Criegee Intermediate

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Direct Kinetic Measurements of a Criegee Intermediate Print In the earth's troposphere, which blankets the planet surface where we live and breathe, dust particles, gas molecules,...

  14. Method and apparatus for active control of combustion rate through modulation of heat transfer from the combustion chamber wall

    DOE Patents [OSTI]

    Roberts, Jr., Charles E.; Chadwell, Christopher J.

    2004-09-21

    The flame propagation rate resulting from a combustion event in the combustion chamber of an internal combustion engine is controlled by modulation of the heat transfer from the combustion flame to the combustion chamber walls. In one embodiment, heat transfer from the combustion flame to the combustion chamber walls is mechanically modulated by a movable member that is inserted into, or withdrawn from, the combustion chamber thereby changing the shape of the combustion chamber and the combustion chamber wall surface area. In another embodiment, heat transfer from the combustion flame to the combustion chamber walls is modulated by cooling the surface of a portion of the combustion chamber wall that is in close proximity to the area of the combustion chamber where flame speed control is desired.

  15. Chemical kinetics and oil shale process design

    SciTech Connect (OSTI)

    Burnham, A.K.

    1993-07-01

    Oil shale processes are reviewed with the goal of showing how chemical kinetics influences the design and operation of different processes for different types of oil shale. Reaction kinetics are presented for organic pyrolysis, carbon combustion, carbonate decomposition, and sulfur and nitrogen reactions.

  16. 7He General Tables

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    He General Table The General Table for 7He is subdivided into the following categories: Experimental Theoretical Model Calculations Hypernuclei and Mesons Pions

  17. 9He General Tables

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    He General Table The General Table for 9He is subdivided into the following categories: Shell Model Other Model Calculations Theoretical

  18. 5He General Tables

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    He General Table The General Table for 5He is subdivided into the following categories: Ground State Properties Theoretical Special States Model Discussions Shell Model Cluster...

  19. 6He General Tables

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    He General Table The General Table for 6He is subdivided into the following categories: Ground State Properties Theoretical Special States Shell Model Cluster and alpha-particle...

  20. General | Open Energy Information

    Open Energy Info (EERE)

    General Jump to: navigation, search Informacin y Documentos Herramientas y Modelos <> Estadsticas de Energas Renovables Volver Pgina principal General banner.jpg Retrieved...

  1. 5H General Tables

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    H General Table The General Table for 5H is subdivided into the following categories: Cluster Model Hypernuclei Model Calculations Photodisintegration Pions...

  2. 10He General Tables

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    General Table The General Table for 10He is subdivided into the following categories: Theoretical Shell Model Cluster Model Other Models Special States Electromagnetic Transitions...

  3. Fluid intensifier having a double acting power chamber with interconnected signal rods

    DOE Patents [OSTI]

    Whitehead, John C. (Davis, CA)

    2001-01-01

    A fluid driven reciprocating apparatus having a double acting power chamber with signal rods serving as high pressure pistons, or to transmit mechanical power. The signal rods are connected to a double acting piston in the power chamber thereby eliminating the need for pilot valves, with the piston being controlled by a pair of intake-exhaust valves. The signal rod includes two spaced seals along its length with a vented space therebetween so that the driving fluid and driven fluid can't mix, and performs a switching function to eliminate separate pilot valves. The intake-exhaust valves can be integrated into a single housing with the power chamber, or these valves can be built into the cylinder head only of the power chamber, or they can be separate from the power chamber.

  4. Integrated Chamber Design for the Laser Inertial Fusion Energy (LIFE) Engine

    SciTech Connect (OSTI)

    Latkowski, J F; Kramer, K J; Abbott, R P; Morris, K R; DeMuth, J; Divol, L; El-Dasher, B; Lafuente, A; Loosmore, G; Reyes, S; Moses, G A; Fratoni, M; Flowers, D; Aceves, S; Rhodes, M; Kane, J; Scott, H; Kramer, R; Pantano, C; Scullard, C; Sawicki, R; Wilks, S; Mehl, M

    2010-12-07

    The Laser Inertial Fusion Energy (LIFE) concept is being designed to operate as either a pure fusion or hybrid fusion-fission system. A key component of a LIFE engine is the fusion chamber subsystem. The present work details the chamber design for the pure fusion option. The fusion chamber consists of the first wall and blanket. This integrated system must absorb the fusion energy, produce fusion fuel to replace that burned in previous targets, and enable both target and laser beam transport to the ignition point. The chamber system also must mitigate target emissions, including ions, x-rays and neutrons and reset itself to enable operation at 10-15 Hz. Finally, the chamber must offer a high level of availability, which implies both a reasonable lifetime and the ability to rapidly replace damaged components. An integrated LIFE design that meets all of these requirements is described herein.

  5. Kinetic advantage of controlled intermediate nuclear fusion

    SciTech Connect (OSTI)

    Guo Xiaoming

    2012-09-26

    The dominated process of controlled fusion is to let nuclei gain enough kinetic energy to overcome Coulomb barrier. As a result, a fusion scheme can consider two factors in its design: to increase kinetic energy of nuclei and to alter the Coulomb barrier. Cold Fusion and Hot fusion are all one-factor schemes while Intermediate Fusion is a twofactors scheme. This made CINF kinetically superior. Cold Fusion reduces deuteron-deuteron distance, addressing Coulomb barrier, and Hot Fusion heat up plasma into extreme high temperature, addressing kinetic energy. Without enough kinetic energy made Cold Fusion skeptical. Extreme high temperature made Hot Fusion very difficult to engineer. Because CIFN addresses both factors, CIFN is a more promising technique to be industrialized.

  6. Characterization of a multi-axis ion chamber array

    SciTech Connect (OSTI)

    Simon, Thomas A.; Kozelka, Jakub; Simon, William E.; Kahler, Darren; Li, Jonathan; Liu, Chihray

    2010-11-15

    Purpose: The aim of this work was to characterize a multi-axis ion chamber array (IC PROFILER; Sun Nuclear Corporation, Melbourne, FL USA) that has the potential to simplify the acquisition of LINAC beam data. Methods: The IC PROFILER (or panel) measurement response was characterized with respect to radiation beam properties, including dose, dose per pulse, pulse rate frequency (PRF), and energy. Panel properties were also studied, including detector-calibration stability, power-on time, backscatter dependence, and the panel's agreement with water tank measurements [profiles, fractional depth dose (FDD), and output factors]. Results: The panel's relative deviation was typically within ({+-}) 1% of an independent (or nominal) response for all properties that were tested. Notable results were (a) a detectable relative field shape change of {approx}1% with linear accelerator PRF changes; (b) a large range in backscatter thickness had a minimal effect on the measured dose distribution (typically less than 1%); (c) the error spread in profile comparison between the panel and scanning water tank (Blue Phantom, CC13; IBA Schwarzenbruck, DE) was approximately ({+-}) 0.75%. Conclusions: The ability of the panel to accurately reproduce water tank profiles, FDDs, and output factors is an indication of its abilities as a dosimetry system. The benefits of using the panel versus a scanning water tank are less setup time and less error susceptibility. The same measurements (including device setup and breakdown) for both systems took 180 min with the water tank versus 30 min with the panel. The time-savings increase as the measurement load is increased.

  7. Improving Combustion Software to Solve Detailed Chemical Kinetics...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Combustion Software to Solve Detailed Chemical Kinetics for HECC Improving Combustion Software to Solve Detailed Chemical Kinetics for HECC 2012 DOE Hydrogen and Fuel Cells Program...

  8. Evaluation of Thermal Evolution Profiles and Estimation of Kinetic...

    Office of Scientific and Technical Information (OSTI)

    of Kinetic Parameters for Pyrolysis of CoalCorn Stover Blends Using Thermogravimetric ... of Kinetic Parameters for Pyrolysis of CoalCorn Stover Blends Using Thermogravimetric ...

  9. Large kinetic asymmetry in the metal-insulator transition nucleated...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Large kinetic asymmetry in the metal-insulator transition nucleated at localized and extended defects Citation Details In-Document Search Title: Large kinetic...

  10. Modeling of Reactor Kinetics and Dynamics

    SciTech Connect (OSTI)

    Matthew Johnson; Scott Lucas; Pavel Tsvetkov

    2010-09-01

    In order to model a full fuel cycle in a nuclear reactor, it is necessary to simulate the short time-scale kinetic behavior of the reactor as well as the long time-scale dynamics that occur with fuel burnup. The former is modeled using the point kinetics equations, while the latter is modeled by coupling fuel burnup equations with the kinetics equations. When the equations are solved simultaneously with a nonlinear equation solver, the end result is a code with the unique capability of modeling transients at any time during a fuel cycle.

  11. On the relationships between the Michaelis–Menten kinetics, reverse Michaelis–Menten kinetics, equilibrium chemistry approximation kinetics, and quadratic kinetics

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Tang, J. Y.

    2015-12-01

    The Michaelis–Menten kinetics and the reverse Michaelis–Menten kinetics are two popular mathematical formulations used in many land biogeochemical models to describe how microbes and plants would respond to changes in substrate abundance. However, the criteria of when to use either of the two are often ambiguous. Here I show that these two kinetics are special approximations to the equilibrium chemistry approximation (ECA) kinetics, which is the first-order approximation to the quadratic kinetics that solves the equation of an enzyme–substrate complex exactly for a single-enzyme and single-substrate biogeochemical reaction with the law of mass action and the assumption of a quasi-steadymore » state for the enzyme–substrate complex and that the product genesis from enzyme–substrate complex is much slower than the equilibration between enzyme–substrate complexes, substrates, and enzymes. In particular, I show that the derivation of the Michaelis–Menten kinetics does not consider the mass balance constraint of the substrate, and the reverse Michaelis–Menten kinetics does not consider the mass balance constraint of the enzyme, whereas both of these constraints are taken into account in deriving the equilibrium chemistry approximation kinetics. By benchmarking against predictions from the quadratic kinetics for a wide range of substrate and enzyme concentrations, the Michaelis–Menten kinetics was found to persistently underpredict the normalized sensitivity ∂ ln v / ∂ ln k2+ of the reaction velocity v with respect to the maximum product genesis rate k2+, persistently overpredict the normalized sensitivity ∂ ln v / ∂ ln k1+ of v with respect to the intrinsic substrate affinity k1+, persistently overpredict the normalized sensitivity ∂ ln v / ∂ ln [E]T of v with respect the total enzyme concentration [E]T, and persistently underpredict the normalized sensitivity ∂ ln v / ∂ ln [S]T of v with respect to the total substrate concentration [S]T. Meanwhile, the reverse Michaelis–Menten kinetics persistently underpredicts ∂ ln v / ∂ ln k2+ and ∂ ln v / ∂ ln [E]T, and persistently overpredicts ∂ ln v / ∂ ln k1+ and ∂ ln v / ∂ ln [S]T. In contrast, the equilibrium chemistry approximation kinetics always gives consistent predictions of ∂ ln v / ∂ ln k2+, ∂ ln v / ∂ ln k1+, ∂ ln v / ∂ ln [E]T, and ∂ ln v / ∂ ln [S]T, indicating that ECA-based models will be more calibratable if the modeled processes do obey the law of mass action. Since the equilibrium chemistry approximation kinetics includes advantages from both the Michaelis–Menten kinetics and the reverse Michaelis–Menten kinetics and it is applicable for almost the whole range of substrate and enzyme abundances, land biogeochemical modelers therefore no longer need to choose when to use the Michaelis–Menten kinetics or the reverse Michaelis–Menten kinetics. I expect that removing this choice ambiguity will make it easier to formulate more robust and consistent land biogeochemical models.« less

  12. Comparison of secondary organic aerosol formed with an aerosol flow reactor and environmental reaction chambers: effect of oxidant concentration, exposure time and seed particles on chemical composition and yield

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lambe, A. T.; Chhabra, P. S.; Onasch, T. B.; Brune, W. H.; Hunter, J. F.; Kroll, J. H.; Cummings, M. J.; Brogan, J. F.; Parmar, Y.; Worsnop, D. R.; et al

    2014-12-02

    We performed a systematic intercomparison study of the chemistry and yields of SOA generated from OH oxidation of a common set of gas-phase precursors in a Potential Aerosol Mass (PAM) continuous flow reactor and several environmental chambers. In the flow reactor, SOA precursors were oxidized using OH concentrations ranging from 2.0×108 to 2.2×1010 molec cm-3 over exposure times of 100 s. In the environmental chambers, precursors were oxidized using OH concentrations ranging from 2×106 to 2×107 molec cm-3 over exposure times of several hours. The OH concentration in the chamber experiments is close to that found in the atmosphere, butmore » the integrated OH exposure in the flow reactor can simulate atmospheric exposure times of multiple days compared to chamber exposure times of only a day or so. A linear correlation analysis of the mass spectra (m=0.91–0.92, r2=0.93–0.94) and carbon oxidation state (m=1.1, r2=0.58) of SOA produced in the flow reactor and environmental chambers for OH exposures of approximately 1011 molec cm-3 s suggests that the composition of SOA produced in the flow reactor and chambers is the same within experimental accuracy as measured with an aerosol mass spectrometer. This similarity in turn suggests that both in the flow reactor and in chambers, SOA chemical composition at low OH exposure is governed primarily by gas-phase OH oxidation of the precursors, rather than heterogeneous oxidation of the condensed particles. In general, SOA yields measured in the flow reactor are lower than measured in chambers for the range of equivalent OH exposures that can be measured in both the flow reactor and chambers. The influence of sulfate seed particles on isoprene SOA yield measurements was examined in the flow reactor. The studies show that seed particles increase the yield of SOA produced in flow reactors by a factor of 3 to 5 and may also account in part for higher SOA yields obtained in the chambers, where seed particles are routinely used.« less

  13. Q-branch Raman scattering and modern kinetic thoery

    SciTech Connect (OSTI)

    Monchick, L.

    1993-12-01

    The program is an extension of previous APL work whose general aim was to calculate line shapes of nearly resonant isolated line transitions with solutions of a popular quantum kinetic equation-the Waldmann-Snider equation-using well known advanced solution techniques developed for the classical Boltzmann equation. The advanced techniques explored have been a BGK type approximation, which is termed the Generalized Hess Method (GHM), and conversion of the collision operator to a block diagonal matrix of symmetric collision kernels which then can be approximated by discrete ordinate methods. The latter method, which is termed the Collision Kernel method (CC), is capable of the highest accuracy and has been used quite successfully for Q-branch Raman scattering. The GHM method, not quite as accurate, is applicable over a wider range of pressures and has proven quite useful.

  14. 8Be General Tables

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Be General Tables The General Table for 8Be is subdivided into the following categories: Reviews Ground State Properties Shell Model Cluster Model Other Models Photodisintegration Fission and Fusion Astrophysical b-decay Hypernuclei

  15. 9B General Tables

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    B General Table The General Table for 9B is subdivided into the following categories: Shell Model Cluster Model Theoretical Other Model Calculations Complex Reactions Beta-Decay Pions Light-ion and Neutron Induced Reactions Hypernuclei

  16. 9C General Tables

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    C General Table The General Table for 9C is subdivided into the following categories: Shell Model Cluster Model Other Models Theoretical Beta-Decay Light-ion and Neutron Induced Reactions Astrophysical

  17. 6Li General Tables

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Li General Table The General Table for 6Li is subdivided into the following categories: Ground State Properties of 6Li Special States Theoretical Shell Model Cluster Models Complex...

  18. OFFICE OF INSPECTOR GENERAL

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    APP-005 Planning for and Measuring Office of Inspector General Results FY 2002 Annual Performance Report and FY 2003 Annual Performance Plan Office of Inspector General U.S. Department of Energy Inspector General's Message We are pleased to present the Office of Inspector General's (OIG) consolidated Fiscal Year 2002 Annual Performance Report and Fiscal Year 2003 Annual Performance Plan. This document evaluates our actual Fiscal Year (FY) 2002 performance and establishes the performance goals

  19. Direct Kinetic Measurements of a Criegee Intermediate

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Direct Kinetic Measurements of a Criegee Intermediate Direct Kinetic Measurements of a Criegee Intermediate Print Wednesday, 25 January 2012 00:00 In the earth's troposphere, which blankets the planet surface where we live and breathe, dust particles, gas molecules, water vapor, and sunlight provide the ingredients for a multitude of chemical reactions that can generate effects ranging from clouds and smog to acid rain and climate change. In 1949, chemist Rudolf Criegee proposed a novel chemical

  20. A = 7 General Tables

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    7 General Tables The General Table for 7He is subdivided into the following categories: Experimental Theoretical Model Calculations Hypernuclei and Mesons Pions The General Table for 7Li is subdivided into the following categories: Reviews Ground State Properties Shell Model Cluster Model Other Theoretical Work Model Calculations Photodisintegration Polarization Fission and Fusion Elastic and Inelastic Scattering Projectile Fragmentation and Multifragmentation Astrophysical Hyperfine Structure

  1. General Resources - Hanford Site

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Beryllium Program General Resources About Us Beryllium Program Beryllium Program Points of Contact Beryllium Facilities & Areas Beryllium Program Information Hanford CBDPP Committee Beryllium FAQs Beryllium Related Links Hanford Beryllium Awareness Group (BAG) Program Performance Assessments Beryllium Program Feedback Beryllium Health Advocates Primary Contractors/Employers Medical Testing and Surveillance Facilities General Resources General Resources Email Email Page | Print Print Page

  2. A sun-tracking environmental chamber for the outdoor quantification of CPV modules

    SciTech Connect (OSTI)

    Faiman, David Melnichak, Vladimir Bokobza, Dov Kabalo, Shlomo

    2014-09-26

    The paper describes a sun-tracking environmental chamber and its associated fast electronics, devised for the accurate outdoor characterization of CPV cells, receivers, mono-modules, and modules. Some typical measurement results are presented.

  3. Parameters of a supersonic combustion chamber with organization of combustion at the flame front

    SciTech Connect (OSTI)

    Solokhin, E.L.; Mironenko, V.A.; Ivanov, V.I.

    1985-10-25

    In some engineering problems, it is necessary to burn fuel in the combustion chamber with supersonic flow. As a rule, the scheme of organization of the process in such a chamber presupposes a separate accompanying feed of fuel and oxidant in which combustion of fuel takes place in a diffusion flame front. In this article we give theoretical results of investigation of a supersonic combustion chamber in which combustion of the fuel mixture takes place in a oblique flame front stabilized by an external source (analogous to the subsonic combustion chambers of ramjets). The possibility of the existence of such an oblique flame front in a supersonic flow of fuel mixture was previously proved experimentally.

  4. Impact of beam transport method on chamber and driver design for heavy ion inertial fusion energy

    SciTech Connect (OSTI)

    Rose, D.V.; Welch, D.R.; Olson, C.L.; Yu, S.S.; Neff, S.; Sharp, W.M.

    2002-12-01

    In heavy ion inertial fusion energy systems, intense beams of ions must be transported from the exit of the final focus magnet system through the target chamber to hit millimeter spot sizes on the target. In this paper, we examine three different modes of beam propagation: neutralized ballistic transport, assisted pinched transport, and self-pinched transport. The status of our understanding of these three modes is summarized, and the constraints imposed by beam propagation upon the chamber environment, as well as their compatibility with various chamber and target concepts, are considered. We conclude that, on the basis of our present understanding, there is a reasonable range of parameter space where beams can propagate in thick-liquid wall, wetted-wall, and dry-wall chambers.

  5. Method of correcting eddy current magnetic fields in particle accelerator vacuum chambers

    DOE Patents [OSTI]

    Danby, Gordon T. (Wading River, NY); Jackson, John W. (Shoreham, NY)

    1991-01-01

    A method for correcting magnetic field aberrations produced by eddy currents induced in a particle accelerator vacuum chamber housing is provided wherein correction windings are attached to selected positions on the housing and the windings are energized by transformer action from secondary coils, which coils are inductively coupled to the poles of electro-magnets that are powered to confine the charged particle beam within a desired orbit as the charged particles are accelerated through the vacuum chamber by a particle-driving rf field. The power inductively coupled to the secondary coils varies as a function of variations in the power supplied by the particle-accelerating rf field to a beam of particles accelerated through the vacuum chamber, so the current in the energized correction coils is effective to cancel eddy current flux fields that would otherwise be induced in the vacuum chamber by power variations in the particle beam.

  6. Method of correcting eddy current magnetic fields in particle accelerator vacuum chambers

    DOE Patents [OSTI]

    Danby, G.T.; Jackson, J.W.

    1990-03-19

    A method for correcting magnetic field aberrations produced by eddy currents induced in a particle accelerator vacuum chamber housing is provided wherein correction windings are attached to selected positions on the housing and the windings are energized by transformer action from secondary coils, which coils are inductively coupled to the poles of electro-magnets that are powered to confine the charged particle beam within a desired orbit as the charged particles are accelerated through the vacuum chamber by a particle-driving rf field. The power inductively coupled to the secondary coils varies as a function of variations in the power supplied by the particle-accelerating rf field to a beam of particles accelerated through the vacuum chamber, so the current in the energized correction coils is effective to cancel eddy current flux fields that would otherwise be induced in the vacuum chamber by power variations (dB/dt) in the particle beam.

  7. Monte Carlo calculations of electron beam quality conversion factors for several ion chamber types

    SciTech Connect (OSTI)

    Muir, B. R.; Rogers, D. W. O.

    2014-11-01

    Purpose: To provide a comprehensive investigation of electron beam reference dosimetry using Monte Carlo simulations of the response of 10 plane-parallel and 18 cylindrical ion chamber types. Specific emphasis is placed on the determination of the optimal shift of the chambers effective point of measurement (EPOM) and beam quality conversion factors. Methods: The EGSnrc system is used for calculations of the absorbed dose to gas in ion chamber models and the absorbed dose to water as a function of depth in a water phantom on which cobalt-60 and several electron beam source models are incident. The optimal EPOM shifts of the ion chambers are determined by comparing calculations of R{sub 50} converted from I{sub 50} (calculated using ion chamber simulations in phantom) to R{sub 50} calculated using simulations of the absorbed dose to water vs depth in water. Beam quality conversion factors are determined as the calculated ratio of the absorbed dose to water to the absorbed dose to air in the ion chamber at the reference depth in a cobalt-60 beam to that in electron beams. Results: For most plane-parallel chambers, the optimal EPOM shift is inside of the active cavity but different from the shift determined with water-equivalent scaling of the front window of the chamber. These optimal shifts for plane-parallel chambers also reduce the scatter of beam quality conversion factors, k{sub Q}, as a function of R{sub 50}. The optimal shift of cylindrical chambers is found to be less than the 0.5 r{sub cav} recommended by current dosimetry protocols. In most cases, the values of the optimal shift are close to 0.3 r{sub cav}. Values of k{sub ecal} are calculated and compared to those from the TG-51 protocol and differences are explained using accurate individual correction factors for a subset of ion chambers investigated. High-precision fits to beam quality conversion factors normalized to unity in a beam with R{sub 50} = 7.5 cm (k{sub Q}{sup ?}) are provided. These factors avoid the use of gradient correction factors as used in the TG-51 protocol although a chamber dependent optimal shift in the EPOM is required when using plane-parallel chambers while no shift is needed with cylindrical chambers. The sensitivity of these results to parameters used to model the ion chambers is discussed and the uncertainty related to the practical use of these results is evaluated. Conclusions: These results will prove useful as electron beam reference dosimetry protocols are being updated. The analysis of this work indicates that cylindrical ion chambers may be appropriate for use in low-energy electron beams but measurements are required to characterize their use in these beams.

  8. Invention and History of the Bubble Chamber (LBNL Summer Lecture Series)

    ScienceCinema (OSTI)

    Glaser, Don

    2011-04-28

    Summer Lecture Series 2006: Don Glaser won the 1960 Nobel Prize for Physics for his 1952 invention of the bubble chamber at Berkeley Lab, a type of particle detector that became the mainstay of high-energy physics research throughout the 1960s and 1970s. He discusses how, inspired by bubbles in a glass of beer, he invented the bubble chamber and detected cosmic-ray muons.

  9. The Effect of Heat Treatments and Coatings on the Outgassing Rate of Stainless Steel Chambers

    SciTech Connect (OSTI)

    Mamum, Md Abdullah A.; Elmustafa, Abdelmageed A,; Stutzman, Marcy L.; Adderley, Philip A.; Poelker, Matthew

    2014-03-01

    The outgassing rates of four nominally identical 304L stainless steel vacuum chambers were measured to determine the effect of chamber coatings and heat treatments. One chamber was coated with titanium nitride (TiN) and one with amorphous silicon (a-Si) immediately following fabrication. One chamber remained uncoated throughout, and the last chamber was first tested without any coating, and then coated with a-Si following a series of heat treatments. The outgassing rate of each chamber was measured at room temperatures between 15 and 30 deg C following bakes at temperatures between 90 and 400 deg C. Measurements for bare steel showed a significant reduction in the outgassing rate by more than a factor of 20 after a 400 deg C heat treatment (3.5 x 10{sup 12} TorrL s{sup -1}cm{sup -2} prior to heat treatment, reduced to 1.7 x 10{ sup -13} TorrL s{sup -1}cm{sup -2} following heat treatment). The chambers that were coated with a-Si showed minimal change in outgassing rates with heat treatment, though an outgassing rate reduced by heat treatments prior to a-Si coating was successfully preserved throughout a series of bakes. The TiN coated chamber exhibited remarkably low outgassing rates, up to four orders of magnitude lower than the uncoated stainless steel. An evaluation of coating composition suggests the presence of elemental titanium which could provide pumping and lead to an artificially low outgassing rate. The outgassing results are discussed in terms of diffusion-limited versus recombination-limited processes.

  10. PICASSO, COUPP and PICO - Search for dark matter with bubble chambers

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect PICASSO, COUPP and PICO - Search for dark matter with bubble chambers Citation Details In-Document Search Title: PICASSO, COUPP and PICO - Search for dark matter with bubble chambers The PICASSO and COUPP collaborations use superheated liquid detectors to search for cold dark matter through the direct detection of weakly interacting massive particles (WIMPs). These experiments, located in the underground laboratory of SNOLAB, Canada, detect phase

  11. Space Chamber Reaches Cold Target at Unprecedented Efficiency | U.S. DOE

    Office of Science (SC) Website

    Office of Science (SC) Space Chamber Reaches Cold Target at Unprecedented Efficiency Nuclear Physics (NP) NP Home About Research Facilities Science Highlights Benefits of NP Funding Opportunities Nuclear Science Advisory Committee (NSAC) Community Resources Contact Information Nuclear Physics U.S. Department of Energy SC-26/Germantown Building 1000 Independence Ave., SW Washington, DC 20585 P: (301) 903-3613 F: (301) 903-3833 E: Email Us More Information » 10.01.12 Space Chamber Reaches

  12. 10Li General Tables

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Li General Table The General Table for 10Li is subdivided into the following categories: Reviews Theoretical Ground State Properties Shell Model Cluster Model Other Models Special States Astrophysical Electromagnetic Transitions Hypernuclei Photodisintegration Light-Ion and Neutron Induced Reactions These General Tables correspond to the 2003 preliminary evaluation of ``Energy Levels of Light Nuclei, A = 10''. The prepublication version of A = 10 is available on this website in PDF format: A =

  13. General Service LED Lamps

    SciTech Connect (OSTI)

    2012-04-01

    Solid-state lighting program technology fact sheet that compares general service incandescent lamps—i.e., light bulbs—to LED and CFL alternatives.

  14. A = 10 General Tables

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Table for 10He is subdivided into the following categories: Theoretical Shell Model Cluster Model Other Models Special States Electromagnetic Transitions The General Table for...

  15. A = 9 General Tables

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The General Table for 9Li is subdivided into the following categories: Shell Model Cluster Model Theoretical Ground State Properties Special States Other Model Calculations...

  16. 10N General Tables

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    subdivided into the following categories: Reviews Ground-State Properties Shell Model Cluster Model Other Theoretical Work These General Tables correspond to "Energy Levels of...

  17. Neptunium Binding Kinetics with Arsenazo(III)

    SciTech Connect (OSTI)

    Leigh R. Martin; Aaron T. Johnson; Stephen P. Mezyk

    2014-08-01

    This document has been prepared to meet FCR&D level 2 milestone M2FT-14IN0304021, Report on the results of actinide binding kinetics with aqueous phase complexants This work was carried out under the auspices of the Thermodynamics and Kinetics of Advanced Separations Systems FCR&D work package. The report details kinetics experiments that were performed to measure rates of aqueous phase complexation for pentavalent neptunium with the chromotropic dye Arsenazo III (AAIII). The studies performed were designed to determine how pH, ionic strength and AAIII concentration may affect the rate of the reaction. A brief comparison with hexavalent neptunium is also made. It was identified that as pH was increased the rate of reaction also increased, however increasing the ionic strength and concentration of AAIII had the opposite effect. Interestingly, the rate of reaction of Np(VI) with AAIII was found to be slower than that of the Np(V) reaction.

  18. 7Be General Tables

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Be General Table The General Table for 7Be is subdivided into the following categories: Reviews Experimental Work Shell Model Cluster Model Other Theoretical Work Model Calculations Projectile Fragmentation and Multifragmentation Astrophysical b Decay Astrophysical Neutrinos Hypernuclei, Mesons and Other Exotic Particles Applications

  19. Chemical kinetic modeling of component mixtures relevant to gasoline

    SciTech Connect (OSTI)

    Mehl, M; Curran, H J; Pitz, W J; Westbrook, C K

    2009-02-13

    Real fuels are complex mixtures of thousands of hydrocarbon compounds including linear and branched paraffins, naphthenes, olefins and aromatics. It is generally agreed that their behavior can be effectively reproduced by simpler fuel surrogates containing a limited number of components. In this work, a recently revised version of the kinetic model by the authors is used to analyze the combustion behavior of several components relevant to gasoline surrogate formulation. Particular attention is devoted to linear and branched saturated hydrocarbons (PRF mixtures), olefins (1-hexene) and aromatics (toluene). Model predictions for pure components, binary mixtures and multi-component gasoline surrogates are compared with recent experimental information collected in rapid compression machine, shock tube and jet stirred reactors covering a wide range of conditions pertinent to internal combustion engines. Simulation results are discussed focusing attention on the mixing effects of the fuel components.

  20. Direct Kinetic Measurements of a Criegee Intermediate

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    J.D. Savee, D.L. Osborn, S.S. Vasu, C.J. Percival, D.E. Shallcross, and C.A. Taatjes, "Direct Kinetic Measurements of Criegee Intermediate (CH2OO) Formed by Reaction of CH2I...

  1. Symmetric generalized binomial distributions

    SciTech Connect (OSTI)

    Bergeron, H.; Curado, E. M. F.; Instituto Nacional de Cincia e Tecnologia - Sistemas Complexos, Rua Xavier Sigaud 150, 22290-180 - Rio de Janeiro, RJ ; Gazeau, J. P.; APC, UMR 7164, Univ Paris Diderot, Sorbonne Paris Cit, 75205 Paris ; Rodrigues, Ligia M. C. S. E-mail: evaldo@cbpf.br E-mail: ligia@cbpf.br

    2013-12-15

    In two recent articles, we have examined a generalization of the binomial distribution associated with a sequence of positive numbers, involving asymmetric expressions of probabilities that break the symmetry win-loss. We present in this article another generalization (always associated with a sequence of positive numbers) that preserves the symmetry win-loss. This approach is also based on generating functions and presents constraints of non-negativeness, similar to those encountered in our previous articles.

  2. 2011 IAEA General Conference

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1 IAEA General Conference Remarks as Prepared for Delivery Secretary Steven Chu Monday, September 19, 2011 Thank you, Ambassador Feruta. Congratulations on your election as President of this Conference. I also want to thank Director General Amano for his outstanding leadership. I am honored to represent the United States today, and I want to share a message from President Barack Obama: "On behalf of the United States, please accept my best wishes for a successful International Atomic Energy

  3. General User Proposals (GUPs)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    General User Proposals (GUPs) Print General Users are granted beam time through a peer review proposal process. They may use beamlines and endstations provided by the ALS or the Participating Research Team (PRT) that operates the beamline. Before Submitting a Proposal Review the ALS Beamlines Directory to learn about the research capabilities of individual beamlines at the ALS. Contact the beamline scientist or the local contact listed in the tables, for additional information about the

  4. Numerical Simulation of Earth Pressure on Head Chamber of Shield Machine with FEM

    SciTech Connect (OSTI)

    Li Shouju; Kang Chengang [State Key Laboratory of structural analysis for industrial equipment, Dalian University of Technology, Dalian 116023 (China); Sun, Wei [School of Mechanical Engineering, Dalian University of Technology, Dalian 116023 (China); Shangguan Zichang [School of Civil and Hydraulic Engineering, Dalian University of Technology, Dalian 116023 (China); Institute of Civil Engineering, Dalian Fishery University, Dalian 116023 (China)

    2010-05-21

    Model parameters of conditioned soils in head chamber of shield machine are determined based on tree-axial compression tests in laboratory. The loads acting on tunneling face are estimated according to static earth pressure principle. Based on Duncan-Chang nonlinear elastic constitutive model, the earth pressures on head chamber of shield machine are simulated in different aperture ratio cases for rotating cutterhead of shield machine. Relationship between pressure transportation factor and aperture ratio of shield machine is proposed by using aggression analysis.

  5. ON THE ANALYSIS OF BUBBLE CHAMBER TRACKS (Technical Report) | SciTech

    Office of Scientific and Technical Information (OSTI)

    Connect ON THE ANALYSIS OF BUBBLE CHAMBER TRACKS Citation Details In-Document Search Title: ON THE ANALYSIS OF BUBBLE CHAMBER TRACKS × You are accessing a document from the Department of Energy's (DOE) SciTech Connect. This site is a product of DOE's Office of Scientific and Technical Information (OSTI) and is provided as a public service. Visit OSTI to utilize additional information resources in energy science and technology. A paper copy of this document is also available for sale to the

  6. U.S. Chamber of Commerce Biofuels Dialogue Series: Outlook for an Emerging

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Global Biofuels Market | Department of Energy Commerce Biofuels Dialogue Series: Outlook for an Emerging Global Biofuels Market U.S. Chamber of Commerce Biofuels Dialogue Series: Outlook for an Emerging Global Biofuels Market January 29, 2008 - 10:53am Addthis Remarks as Prepared For Delivery by Secretary Bodman Thank you very much, Bruce, for that kind introduction. My thanks also to Tom Donahue and the leadership of the Chamber for inviting me to be with you today. I was quite pleased to

  7. ON THE ANALYSIS OF BUBBLE CHAMBER TRACKS (Technical Report) | SciTech

    Office of Scientific and Technical Information (OSTI)

    Connect ON THE ANALYSIS OF BUBBLE CHAMBER TRACKS Citation Details In-Document Search Title: ON THE ANALYSIS OF BUBBLE CHAMBER TRACKS × You are accessing a document from the Department of Energy's (DOE) SciTech Connect. This site is a product of DOE's Office of Scientific and Technical Information (OSTI) and is provided as a public service. Visit OSTI to utilize additional information resources in energy science and technology. A paper copy of this document is also available for sale to the

  8. Wafer chamber having a gas curtain for extreme-UV lithography

    DOE Patents [OSTI]

    Kanouff, Michael P. (Livermore, CA); Ray-Chaudhuri, Avijit K. (Livermore, CA)

    2001-01-01

    An EUVL device includes a wafer chamber that is separated from the upstream optics by a barrier having an aperture that is permeable to the inert gas. Maintaining an inert gas curtain in the proximity of a wafer positioned in a chamber of an extreme ultraviolet lithography device can effectively prevent contaminants from reaching the optics in an extreme ultraviolet photolithography device even though solid window filters are not employed between the source of reflected radiation, e.g., the camera, and the wafer. The inert gas removes the contaminants by entrainment.

  9. Kinetics and Mechanisms of Calcite Reactions with Saline Waters

    SciTech Connect (OSTI)

    Gorman, Brian P

    2015-09-02

    Project Description: The general objective of the proposed research is to determine the kinetics and mechanisms of calcite reactions with saline waters over a wide range of saline water composition, pCO2, and modest ranges in T and P. This will be accomplished by studying both reaction rates and solubility from changes in solution chemistry, and making nanoscale observations of calcite precipitate surface morphology and composition at the micro-to-nano-scale to provide an understanding of controlling reaction mechanisms and pathways. The specific objectives necessary to reach the general objective are: a) determination of how pCO2, Ca2+, ionic strength and foreign ions influence reaction rates; and b) investigate the influence of these parameters on apparent kinetic solubility from dissolution and precipitation reactions. This information will clearly be central to the construction of reliable reaction-transport models to predict reservoir and formation response to increased CO2 in saline waters. This program was initially collaborative with John Morse at Texas A&M, however his passing shortly after the beginning of this program resulted in abbreviated research time and effort. Summary of Results: Early studies using electron microscopy and spectroscopy indicated that carbonate precipitation from natural seawater (NSW) conditions onto aragonite substrates was mediated by a surface amorphous calcium carbonate layer. It was hypothesized that this ACC layer (observed after < 5days reaction time) was responsible for the abnormal reaction kinetics and also served as a metastable seed layer for growth of epitaxial aragonite. Further studies of the ACC formation mechanism indicated a strong dependence on the Mg concentration in solution. Subsequent studies at shorter times (10 hrs) on calcite substrates and in a wide range of supersaturation conditions did not indicate any ACC layer. Instead, an epitaxial layer by layer growth mechanism was confirmed by grazing incidence X-ray diffraction, -Raman spectroscopy, scanning electron microscopy, transmission electron microscopy, and electron diffraction. Extended time studies out to 45 days confirmed the epitaxial relationship of the overgrowth layer with the substrate. Under NSW conditions, overgrowths were found to have ~0.4 to 0.8 nm / hr growth rates and accommodating 4 at% Mg, resulting in a highly strained overgrowth layer. Following the initial layer by layer growth mechanism, the growth changes to Stranski-Krastanov type after a critical thickness of approximately 100 nm.

  10. Multi-gap Resistive Plate Chambers as a Time-of-Flight System for the PHENIX Experiment

    SciTech Connect (OSTI)

    Velkovska, Julia

    2013-12-08

    In this project a Time-of-Flight detector based on multi-gap resistive plate chambers was built and installed for the PHENIX experiment at RHIC.

  11. Reflected kinetics model for nuclear space reactor kinetics and control scoping calculations

    SciTech Connect (OSTI)

    Washington, K.E.

    1986-05-01

    The objective of this research is to develop a model that offers an alternative to the point kinetics (PK) modelling approach in the analysis of space reactor kinetics and control studies. Modelling effort will focus on the explicit treatment of control drums as reactivity input devices so that the transition to automatic control can be smoothly done. The proposed model is developed for the specific integration of automatic control and the solution of the servo mechanism problem. The integration of the kinetics model with an automatic controller will provide a useful tool for performing space reactor scoping studies for different designs and configurations. Such a tool should prove to be invaluable in the design phase of a space nuclear system from the point of view of kinetics and control limitations.

  12. The LANL atomic kinetics modeling effort and its application...

    Office of Scientific and Technical Information (OSTI)

    The LANL atomic kinetics modeling effort and its application to W plasmas Citation Details In-Document Search Title: The LANL atomic kinetics modeling effort and its application to...

  13. Kinetic and Performance Studies of the Regeneration Phase of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Kinetic and Performance Studies of the Regeneration Phase of Model PtRhBa NOx Traps for Design and Optimization Kinetic and Performance Studies of the Regeneration Phase of Model...

  14. Generalized galilean genesis

    SciTech Connect (OSTI)

    Nishi, Sakine; Kobayashi, Tsutomu

    2015-03-31

    The galilean genesis scenario is an alternative to inflation in which the universe starts expanding from Minkowski in the asymptotic past by violating the null energy condition stably. Several concrete models of galilean genesis have been constructed so far within the context of galileon-type scalar-field theories. We give a generic, unified description of the galilean genesis scenario in terms of the Horndeski theory, i.e., the most general scalar-tensor theory with second-order field equations. In doing so we generalize the previous models to have a new parameter (denoted by α) which results in controlling the evolution of the Hubble rate. The background dynamics is investigated to show that the generalized galilean genesis solution is an attractor, similarly to the original model. We also study the nature of primordial perturbations in the generalized galilean genesis scenario. In all the models described by our generalized genesis Lagrangian, amplification of tensor perturbations does not occur as opposed to what happens in quasi-de Sitter inflation. We show that the spectral index of curvature perturbations is determined solely from the parameter α and does not depend on the other details of the model. In contrast to the original model, a nearly scale-invariant spectrum of curvature perturbations is obtained for a specific choice of α.

  15. Intercalation Kinetics and Ion Mobility in Electrode Materials...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Intercalation Kinetics and Ion Mobility in Electrode Materials for Advanced Lithium Ion ... Electron Microscopy of Electrical Energy Storage Materials Composite ...

  16. CLEERS Coordination & Development of Catalyst Process Kinetic Data |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Development of Catalyst Process Kinetic Data CLEERS Coordination & Development of Catalyst Process Kinetic Data 2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. PDF icon ace_20_choi.pdf More Documents & Publications CLEERS Coordination & Joint Development of Benchmark Kinetics for LNT & SCR CLEERS Coordination & Joint Development of Benchmark Kinetics for LNT

  17. Multidimensional simulation and chemical kinetics development for high

    Office of Environmental Management (EM)

    efficiency clean combustion engines | Department of Energy Multidimensional simulation and chemical kinetics development for high efficiency clean combustion engines Multidimensional simulation and chemical kinetics development for high efficiency clean combustion engines Developing chemical kinetic mechanisms and applying them to simulating engine combustion processes. PDF icon deer09_aceves.pdf More Documents & Publications Chemical Kinetic Research on HCCI & Diesel Fuels Chemical

  18. GENERAL PRINCIPLES OF AGREEMENT

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    GENERAL PRINCIPLES OF AGREEMENT HWB-14-20 and HWB-14-21 These General Principles of Agreement ("Principles of Agreement") are agreed upon by the New Mexico Environment Department ("NMED"), and the United States Department of Energy ("DOE"), Los Alamos National Security, LLC ("LANS"), and Nuclear Waste Partnership, LLC ("NWP") (collectively, with DOE and LANS, the "DOE Permittees") for the purpose of resolving Compliance Order Nos.

  19. Modelling of e-cloud build-up in grooved vacuum chambers usingPOSINST

    SciTech Connect (OSTI)

    Venturini, Marco; Celata, C.; Furman, Miguel; Vay, Jean-Luc; Pivi, Mauro

    2007-06-29

    Use of grooved vacuum chambers have been suggested as a wayto limitelectron cloud accumulation in the ILC-DR. We report onsimulations carried out using an augmented version of POSINST, accountingfor e-cloud dynamics in the presence of grooves, and make contact withprevious estimates of an effective secondary electron yield for groovedsurfaces.

  20. Dark Matter Search Results from the PICO-60 CF$_3$I Bubble Chamber

    SciTech Connect (OSTI)

    Amole, C.

    2015-10-26

    We reported new data from the operation of the PICO-60 dark matter detector, a bubble chamber filled with 36.8 kg of CF3I and located in the SNOLAB underground laboratory. PICO-60 is the largest bubble chamber to search for dark matter to date. With an analyzed exposure of 92.8 live-days, PICO-60 exhibits the same excellent background rejection observed in smaller bubble chambers. Alpha decays in PICO-60 exhibit frequency-dependent acoustic calorimetry, similar but not identical to that reported recently in a C3F8 bubble chamber. PICO-60 also observes a large population of unknown background events, exhibiting acoustic, spatial, and timing behaviors inconsistent with those expected from a dark matter signal. We found these behaviors allow for analysis cuts to remove all background events while retaining 48.2%of the exposure. Stringent limits on WIMPs interacting via spin-dependent proton and spin-independent processes are set, and the interpretation of the DAMA/LIBRA modulation signal as dark matter interacting with iodine nuclei is ruled out.

  1. Multi-property characterization chamber for geophysical-hydrological investigations of hydrate bearing sediments

    SciTech Connect (OSTI)

    Seol, Yongkoo Choi, Jeong-Hoon; Dai, Sheng

    2014-08-01

    With the increase in the interest of producing natural gas from methane hydrates as well as potential risks of massive hydrate dissociation in the context of global warming, studies have recently shifted from pure hydrate crystals to hydrates in sediments. Such a research focus shift requires a series of innovative laboratory devices that are capable of investigating various properties of hydrate-bearing sediments (HBS). This study introduces a newly developed high pressure testing chamber, i.e., multi-property characterization chamber (MPCC), that allows simultaneous investigation of a series of fundamental properties of HBS, including small-strain stiffness (i.e., P- and S-waves), shear strength, large-strain deformation, stress-volume responses, and permeability. The peripheral coolant circulation system of the MPCC permits stable and accurate temperature control, while the core holder body, made of aluminum, enables X-ray computer tomography scanning to be easily employed for structural and morphological characterization of specimens. Samples of hydrate-bearing sediments are held within a rubber sleeve inside the chamber. The thick sleeve is more durable and versatile than thin membranes while also being much softer than oedometer-type chambers that are incapable of enabling flow tests. Bias introduced by the rubber sleeve during large deformation tests are also calibrated both theoretically and experimentally. This system provides insight into full characterization of hydrate-bearing sediments in the laboratory, as well as pressure core technology in the field.

  2. Nested reactor chamber and operation for Hg-196 isotope separation process

    DOE Patents [OSTI]

    Grossman, M.W.

    1991-10-08

    The present invention is directed to an apparatus for use in [sup 196]Hg separation and its method of operation. Specifically, the present invention is directed to a nested reactor chamber useful for [sup 196]Hg isotope separation reactions avoiding the photon starved condition commonly encountered in coaxial reactor systems. 6 figures.

  3. Nested reactor chamber and operation for Hg-196 isotope separation process

    DOE Patents [OSTI]

    Grossman, Mark W. (Belmont, MA)

    1991-01-01

    The present invention is directed to an apparatus for use in .sup.196 Hg separation and its method of operation. Specifically, the present invention is directed to a nested reactor chamber useful for .sup.196 Hg isotope separation reactions avoiding the photon starved condition commonly encountered in coaxial reactor systems.

  4. Report on Fission Time Projection Chamber M3FT-12IN0210052

    SciTech Connect (OSTI)

    James K. Jewell

    2012-08-01

    The Time Projection Chamber is a collaborative effort to implement an innovative approach and deliver unprecedented fission measurements to DOE programs. This 4?-detector system will provide unrivaled 3-D data about the fission process. Shown here is a half populated TPC (2?) at the LLNL TPC laboratory as it undergoes testing before being shipped to LANSCE for beam experiments.

  5. A Diffusion Cloud Chamber Study of Very Slow Mesons. II. Beta Decay of the Muon

    DOE R&D Accomplishments [OSTI]

    Lederman, L. M.; Sargent, C. P.; Rinehart, M.; Rogers, K.

    1955-03-01

    The spectrum of electrons arising from the decay of the negative mu meson has been determined. The muons are arrested in the gas of a high pressure hydrogen filled diffusion cloud chamber. The momenta of the decay electrons are determined from their curvature in a magnetic field of 7750 gauss. The spectrum of 415 electrons has been analyzed according to the theory of Michel.

  6. Chemical Kinetic Modeling of Fuels | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fuels Chemical Kinetic Modeling of Fuels 2010 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C. PDF icon ft010_pitz_2010_o.pdf More Documents & Publications Chemical Kinetic Modeling of Non-Petroleum Based Fuels Chemical Kinetic Modeling of Non-Petroleum Based

  7. Kinetics of Chronic Oxidation of NBG-17 Nuclear Graphite by Water Vapor

    SciTech Connect (OSTI)

    Contescu, Cristian I; Burchell, Timothy D; Mee, Robert

    2015-05-01

    This report presents the results of kinetic measurements during accelerated oxidation tests of NBG-17 nuclear graphite by low concentration of water vapor and hydrogen in ultra-high purity helium. The objective is to determine the parameters in the Langmuir-Hinshelwood (L-H) equation describing the oxidation kinetics of nuclear graphite in the helium coolant of high temperature gas-cooled reactors (HTGR). Although the helium coolant chemistry is strictly controlled during normal operating conditions, trace amounts of moisture (predictably < 0.2 ppm) cannot be avoided. Prolonged exposure of graphite components to water vapor at high temperature will cause very slow (chronic) oxidation over the lifetime of graphite components. This behavior must be understood and predicted for the design and safe operation of gas-cooled nuclear reactors. The results reported here show that, in general, oxidation by water of graphite NBG-17 obeys the L-H mechanism, previously documented for other graphite grades. However, the characteristic kinetic parameters that best describe oxidation rates measured for graphite NBG-17 are different than those reported previously for grades H-451 (General Atomics, 1978) and PCEA (ORNL, 2013). In some specific conditions, certain deviations from the generally accepted L-H model were observed for graphite NBG-17. This graphite is manufactured in Germany by SGL Carbon Group and is a possible candidate for the fuel elements and reflector blocks of HTGR.

  8. Constrained Generalized Supersymmetries

    SciTech Connect (OSTI)

    Toppan, Francesco; Kuznetsova, Zhanna

    2005-10-17

    We present a classification of admissible types of constraint (hermitian, holomorphic, with reality condition on the bosonic sectors, etc.) for generalized supersymmetries in the presence of complex spinors. A generalized supersymmetry algebra involving n-component real spinors Qa is given by the anticommutators {l_brace}Q{sub a},Q{sub b}{r_brace} = Z{sub ab} where the matrix Z appearing in the r.h.s. is the most general symmetric matrix. A complex generalized supersymmetry algebra is expressed in terms of complex spinors Qa and their complex conjugate Q* a. The most general (with a saturated r.h.s.) algebra is in this case given by {l_brace}Q{sub a},Q{sub b}{r_brace} P{sub ab}{l_brace}Q*{sub a}, Q*{sub b}{r_brace} = P*{sub ab}{l_brace}Q{sub a},Q*{sub b}{r_brace} = R{sub ab} where the matrix Pab is symmetric, while Rab is hermitian. The bosonic right hand side can be expressed in terms of the rank-k totally antisymmetric tensors P{sub ab} {sigma}k(C{gamma}{sub [{mu}}{sub 1...{mu}}{sub k]}){sub ab}P{sup [{mu}{sup 1...{mu}{sup k}]}.The decomposition in terms of anti-symmetric tensors for any space-time up to dimension D = 13 is presented. Real type, complex type, and quaternionic type space-times are classified. Any restriction on the saturated bosonic generators that allows all possible combinations of these tensors is in principle admissible by a Lorenz-covariant requirement. We investigate division algebra constraints and their influence on physical models. High spin theory models are presented as examples of the applications of such models.

  9. Direct Kinetic Measurements of a Criegee Intermediate

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Direct Kinetic Measurements of a Criegee Intermediate Print In the earth's troposphere, which blankets the planet surface where we live and breathe, dust particles, gas molecules, water vapor, and sunlight provide the ingredients for a multitude of chemical reactions that can generate effects ranging from clouds and smog to acid rain and climate change. In 1949, chemist Rudolf Criegee proposed a novel chemical pathway for one such reaction, known as ozonolysis: the destruction of alkenes (a type

  10. Direct Kinetic Measurements of a Criegee Intermediate

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Direct Kinetic Measurements of a Criegee Intermediate Print In the earth's troposphere, which blankets the planet surface where we live and breathe, dust particles, gas molecules, water vapor, and sunlight provide the ingredients for a multitude of chemical reactions that can generate effects ranging from clouds and smog to acid rain and climate change. In 1949, chemist Rudolf Criegee proposed a novel chemical pathway for one such reaction, known as ozonolysis: the destruction of alkenes (a type

  11. Direct Kinetic Measurements of a Criegee Intermediate

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Direct Kinetic Measurements of a Criegee Intermediate Print In the earth's troposphere, which blankets the planet surface where we live and breathe, dust particles, gas molecules, water vapor, and sunlight provide the ingredients for a multitude of chemical reactions that can generate effects ranging from clouds and smog to acid rain and climate change. In 1949, chemist Rudolf Criegee proposed a novel chemical pathway for one such reaction, known as ozonolysis: the destruction of alkenes (a type

  12. Direct Kinetic Measurements of a Criegee Intermediate

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Direct Kinetic Measurements of a Criegee Intermediate Print In the earth's troposphere, which blankets the planet surface where we live and breathe, dust particles, gas molecules, water vapor, and sunlight provide the ingredients for a multitude of chemical reactions that can generate effects ranging from clouds and smog to acid rain and climate change. In 1949, chemist Rudolf Criegee proposed a novel chemical pathway for one such reaction, known as ozonolysis: the destruction of alkenes (a type

  13. Direct Kinetic Measurements of a Criegee Intermediate

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Direct Kinetic Measurements of a Criegee Intermediate Print In the earth's troposphere, which blankets the planet surface where we live and breathe, dust particles, gas molecules, water vapor, and sunlight provide the ingredients for a multitude of chemical reactions that can generate effects ranging from clouds and smog to acid rain and climate change. In 1949, chemist Rudolf Criegee proposed a novel chemical pathway for one such reaction, known as ozonolysis: the destruction of alkenes (a type

  14. Direct Kinetic Measurements of a Criegee Intermediate

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Direct Kinetic Measurements of a Criegee Intermediate Print In the earth's troposphere, which blankets the planet surface where we live and breathe, dust particles, gas molecules, water vapor, and sunlight provide the ingredients for a multitude of chemical reactions that can generate effects ranging from clouds and smog to acid rain and climate change. In 1949, chemist Rudolf Criegee proposed a novel chemical pathway for one such reaction, known as ozonolysis: the destruction of alkenes (a type

  15. Direct Kinetic Measurements of a Criegee Intermediate

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Direct Kinetic Measurements of a Criegee Intermediate Print In the earth's troposphere, which blankets the planet surface where we live and breathe, dust particles, gas molecules, water vapor, and sunlight provide the ingredients for a multitude of chemical reactions that can generate effects ranging from clouds and smog to acid rain and climate change. In 1949, chemist Rudolf Criegee proposed a novel chemical pathway for one such reaction, known as ozonolysis: the destruction of alkenes (a type

  16. Detailed Chemical Kinetic Modeling of Cyclohexane Oxidation

    SciTech Connect (OSTI)

    Silke, E J; Pitz, W J; Westbrook, C K; Ribaucour, M

    2006-11-10

    A detailed chemical kinetic mechanism has been developed and used to study the oxidation of cyclohexane at both low and high temperatures. Reaction rate constant rules are developed for the low temperature combustion of cyclohexane. These rules can be used for in chemical kinetic mechanisms for other cycloalkanes. Since cyclohexane produces only one type of cyclohexyl radical, much of the low temperature chemistry of cyclohexane is described in terms of one potential energy diagram showing the reaction of cyclohexyl radical + O{sub 2} through five, six and seven membered ring transition states. The direct elimination of cyclohexene and HO{sub 2} from RO{sub 2} is included in the treatment using a modified rate constant of Cavallotti et al. Published and unpublished data from the Lille rapid compression machine, as well as jet-stirred reactor data are used to validate the mechanism. The effect of heat loss is included in the simulations, an improvement on previous studies on cyclohexane. Calculations indicated that the production of 1,2-epoxycyclohexane observed in the experiments can not be simulated based on the current understanding of low temperature chemistry. Possible 'alternative' H-atom isomerizations leading to different products from the parent O{sub 2}QOOH radical were included in the low temperature chemical kinetic mechanism and were found to play a significant role.

  17. Beamline 9.0.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    9.0.2 Print Chemical Dynamics Scientific disciplines: Chemical dynamics, aerosol chemistry, imaging mass spectrometry, chemical kinetics, laser ablation and clusters, combustion and flames. Endstations: Molecular-beam photoelectron/photoion imaging and spectroscopy Flame chamber Ablation chamber Aerosol chamber Kinetics chamber GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics 10-cm period undulator (U10) (fundamental) Energy range 7.4-30 eV Undulator beam White beam (straight

  18. Beamline 9.0.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    9.0.2 Print Chemical Dynamics Scientific disciplines: Chemical dynamics, aerosol chemistry, imaging mass spectrometry, chemical kinetics, laser ablation and clusters, combustion and flames. Endstations: Molecular-beam photoelectron/photoion imaging and spectroscopy Flame chamber Ablation chamber Aerosol chamber Kinetics chamber GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics 10-cm period undulator (U10) (fundamental) Energy range 7.4-30 eV Undulator beam White beam (straight

  19. Beamline 9.0.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    0.2 Print Chemical Dynamics Scientific disciplines: Chemical dynamics, aerosol chemistry, imaging mass spectrometry, chemical kinetics, laser ablation and clusters, combustion and flames. Endstations: Molecular-beam photoelectron/photoion imaging and spectroscopy Flame chamber Ablation chamber Aerosol chamber Kinetics chamber GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics 10-cm period undulator (U10) (fundamental) Energy range 7.4-30 eV Undulator beam White beam (straight

  20. Beamline 9.0.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    0.2 Print Chemical Dynamics Scientific disciplines: Chemical dynamics, aerosol chemistry, imaging mass spectrometry, chemical kinetics, laser ablation and clusters, combustion and flames. Endstations: Molecular-beam photoelectron/photoion imaging and spectroscopy Flame chamber Ablation chamber Aerosol chamber Kinetics chamber GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics 10-cm period undulator (U10) (fundamental) Energy range 7.4-30 eV Undulator beam White beam (straight

  1. Beamline 9.0.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    0.2 Print Chemical Dynamics Scientific disciplines: Chemical dynamics, aerosol chemistry, imaging mass spectrometry, chemical kinetics, laser ablation and clusters, combustion and flames. Endstations: Molecular-beam photoelectron/photoion imaging and spectroscopy Flame chamber Ablation chamber Aerosol chamber Kinetics chamber GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics 10-cm period undulator (U10) (fundamental) Energy range 7.4-30 eV Undulator beam White beam (straight

  2. Beamline 9.0.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    0.2 Print Chemical Dynamics Scientific disciplines: Chemical dynamics, aerosol chemistry, imaging mass spectrometry, chemical kinetics, laser ablation and clusters, combustion and flames. Endstations: Molecular-beam photoelectron/photoion imaging and spectroscopy Flame chamber Ablation chamber Aerosol chamber Kinetics chamber GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics 10-cm period undulator (U10) (fundamental) Energy range 7.4-30 eV Undulator beam White beam (straight

  3. Beamline 9.0.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    0.2 Print Chemical Dynamics Scientific disciplines: Chemical dynamics, aerosol chemistry, imaging mass spectrometry, chemical kinetics, laser ablation and clusters, combustion and flames. Endstations: Molecular-beam photoelectron/photoion imaging and spectroscopy Flame chamber Ablation chamber Aerosol chamber Kinetics chamber GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics 10-cm period undulator (U10) (fundamental) Energy range 7.4-30 eV Undulator beam White beam (straight

  4. Beamline 9.0.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    0.2 Print Chemical Dynamics Scientific disciplines: Chemical dynamics, aerosol chemistry, imaging mass spectrometry, chemical kinetics, laser ablation and clusters, combustion and flames. Endstations: Molecular-beam photoelectron/photoion imaging and spectroscopy Flame chamber Ablation chamber Aerosol chamber Kinetics chamber GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics 10-cm period undulator (U10) (fundamental) Energy range 7.4-30 eV Undulator beam White beam (straight

  5. Beamline 9.0.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    0.2 Print Chemical Dynamics Scientific disciplines: Chemical dynamics, aerosol chemistry, imaging mass spectrometry, chemical kinetics, laser ablation and clusters, combustion and flames. Endstations: Molecular-beam photoelectron/photoion imaging and spectroscopy Flame chamber Ablation chamber Aerosol chamber Kinetics chamber GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics 10-cm period undulator (U10) (fundamental) Energy range 7.4-30 eV Undulator beam White beam (straight

  6. Beamline 9.0.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    0.2 Print Chemical Dynamics Scientific disciplines: Chemical dynamics, aerosol chemistry, imaging mass spectrometry, chemical kinetics, laser ablation and clusters, combustion and flames. Endstations: Molecular-beam photoelectron/photoion imaging and spectroscopy Flame chamber Ablation chamber Aerosol chamber Kinetics chamber GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics 10-cm period undulator (U10) (fundamental) Energy range 7.4-30 eV Undulator beam White beam (straight

  7. Beamline 9.0.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    0.2 Print Chemical Dynamics Scientific disciplines: Chemical dynamics, aerosol chemistry, imaging mass spectrometry, chemical kinetics, laser ablation and clusters, combustion and flames. Endstations: Molecular-beam photoelectron/photoion imaging and spectroscopy Flame chamber Ablation chamber Aerosol chamber Kinetics chamber GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics 10-cm period undulator (U10) (fundamental) Energy range 7.4-30 eV Undulator beam White beam (straight

  8. Beamline 9.0.2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Beamline 9.0.2 Beamline 9.0.2 Print Tuesday, 20 October 2009 08:59 Chemical Dynamics Scientific disciplines: Chemical dynamics, aerosol chemistry, imaging mass spectrometry, chemical kinetics, laser ablation and clusters, combustion and flames. Endstations: Molecular-beam photoelectron/photoion imaging and spectroscopy Flame chamber Ablation chamber Aerosol chamber Kinetics chamber GENERAL BEAMLINE INFORMATION Operational Yes Source characteristics 10-cm period undulator (U10) (fundamental)

  9. Monte Carlo calculations for reference dosimetry of electron beams with the PTW Roos and NE2571 ion chambers

    SciTech Connect (OSTI)

    Muir, B. R. Rogers, D. W. O.

    2013-12-15

    Purpose: To investigate recommendations for reference dosimetry of electron beams and gradient effects for the NE2571 chamber and to provide beam quality conversion factors using Monte Carlo simulations of the PTW Roos and NE2571 ion chambers. Methods: The EGSnrc code system is used to calculate the absorbed dose-to-water and the dose to the gas in fully modeled ion chambers as a function of depth in water. Electron beams are modeled using realistic accelerator simulations as well as beams modeled as collimated point sources from realistic electron beam spectra or monoenergetic electrons. Beam quality conversion factors are calculated with ratios of the doses to water and to the air in the ion chamber in electron beams and a cobalt-60 reference field. The overall ion chamber correction factor is studied using calculations of water-to-air stopping power ratios. Results: The use of an effective point of measurement shift of 1.55 mm from the front face of the PTW Roos chamber, which places the point of measurement inside the chamber cavity, minimizes the difference betweenR{sub 50}, the beam quality specifier, calculated from chamber simulations compared to that obtained using depth-dose calculations in water. A similar shift minimizes the variation of the overall ion chamber correction factor with depth to the practical range and reduces the root-mean-square deviation of a fit to calculated beam quality conversion factors at the reference depth as a function of R{sub 50}. Similarly, an upstream shift of 0.34 r{sub cav} allows a more accurate determination of R{sub 50} from NE2571 chamber calculations and reduces the variation of the overall ion chamber correction factor with depth. The determination of the gradient correction using a shift of 0.22 r{sub cav} optimizes the root-mean-square deviation of a fit to calculated beam quality conversion factors if all beams investigated are considered. However, if only clinical beams are considered, a good fit to results for beam quality conversion factors is obtained without explicitly correcting for gradient effects. The inadequacy of R{sub 50} to uniquely specify beam quality for the accurate selection of k{sub Q} factors is discussed. Systematic uncertainties in beam quality conversion factors are analyzed for the NE2571 chamber and amount to between 0.4% and 1.2% depending on assumptions used. Conclusions: The calculated beam quality conversion factors for the PTW Roos chamber obtained here are in good agreement with literature data. These results characterize the use of an NE2571 ion chamber for reference dosimetry of electron beams even in low-energy beams.

  10. Methods and apparatus for cleaning objects in a chamber of an optical instrument by generating reactive ions using photon radiation

    DOE Patents [OSTI]

    Klebanoff, Leonard E.; Delgado, Gildardo R.; Hollenshead, Jeromy T.; Umstadter, Karl R.; Starodub, Elena; Zhuang, Guorong V.

    2015-10-13

    An optical instrument, including a chamber, an object exposed to an interior of the chamber, a source of low-pressure gas, the gas comprising at least one of low-pressure molecular hydrogen gas, low-pressure molecular oxygen and a low-pressure noble gas, the source of low pressure gas being fluidly coupled to the chamber, a low voltage source electrically coupled between the object and a remaining portion of the instrument that is exposed to the interior of the chamber so as to maintain the object at a low voltage relative to the remaining portion, and an EUV/VUV light source adapted to direct EUV/VUV light through the low pressure gas in the chamber onto the object. In such a system, when the EUV/VUV light source is activated ions of the low-pressure gas are formed and directed to the object. The ions may be ions of Hydrogen, Oxygen or a noble gas.

  11. Kinetics of coal combustion: Part 2, Mechanisms and kinetics of coal volatiles combustion

    SciTech Connect (OSTI)

    Essenhigh, R.H.; Bailey, E.G.; Shaw, D.W. )

    1988-12-01

    Values of global kinetic constants for the combustion of coal volatiles have been determined for the first time for volatiles from three coals (two bituminous coals and a Texas lignite). Global kinetic constants for methane and propane were also measured in the same apparatus to allow comparison with reference gases. Comparisons have also been made with values of global kinetics for pure hydrocarbons from a range of experiments as found in the literature. The volatiles were pyrolyzed from crushed coal drawn on weighed trays through a gas-fired muffle furnace, and they were burned at the top of a tube in an intense back-mix volume treated theoretically as a stirred reactor. Two types of experiment were carried out: partial combustion measurements near the stoichiometric for all coals from which the global kinetics were determined; and extinction limits for the Pittsburgh {number sign}8 coal volatiles to determine the extinction loop. The near stoichiometric generated kinetic data were used to predict the extinction limits with substantial agreement. Extinction loops for methane, propane and carbon monoxide were also measured for comparison.

  12. Generalized constructive tree weights

    SciTech Connect (OSTI)

    Rivasseau, Vincent E-mail: adrian.tanasa@ens-lyon.org; Tanasa, Adrian E-mail: adrian.tanasa@ens-lyon.org

    2014-04-15

    The Loop Vertex Expansion (LVE) is a quantum field theory (QFT) method which explicitly computes the Borel sum of Feynman perturbation series. This LVE relies in a crucial way on symmetric tree weights which define a measure on the set of spanning trees of any connected graph. In this paper we generalize this method by defining new tree weights. They depend on the choice of a partition of a set of vertices of the graph, and when the partition is non-trivial, they are no longer symmetric under permutation of vertices. Nevertheless we prove they have the required positivity property to lead to a convergent LVE; in fact we formulate this positivity property precisely for the first time. Our generalized tree weights are inspired by the Brydges-Battle-Federbush work on cluster expansions and could be particularly suited to the computation of connected functions in QFT. Several concrete examples are explicitly given.

  13. Generalized parton distributions: Status and perspectives (Conference...

    Office of Scientific and Technical Information (OSTI)

    PHYSICS; COMPTON EFFECT; DIFFRACTION; DIPOLES; ELECTROPRODUCTION; FACTORIZATION; IMPACT PARAMETER; MESONS; NUCLEONS; PHYSICS; PRODUCTION; QUANTUM CHROMODYNAMICS; REACTION KINETICS...

  14. General User Proposals (GUPs)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Proposals (GUPs) Print General Users are granted beam time through a peer review proposal process. They may use beamlines and endstations provided by the ALS or the Participating Research Team (PRT) that operates the beamline. Before Submitting a Proposal Review the ALS Beamlines Directory to learn about the research capabilities of individual beamlines at the ALS. Contact the beamline scientist or the local contact listed in the tables, for additional information about the beamline. You can

  15. Office of Inspector General

    Energy Savers [EERE]

    Office of Inspector General Office of Audits and Inspections Work Plan for FY 2013 Audits Central Audits Division  Ecotality  Funding Overlap  Follow-up on Smart Grid Investment Grant  DOE's Loan Program Office's Portfolio Management  Office of Fossil Energy's Regional Carbon Sequestration Partnerships  Advanced Manufacturing Office's Combined Heat and Power Systems  DOE's Management of Contaminated Non-EM Facilities  Unneeded Real Estate  Review of For-Profit Grantees

  16. General Employee Radiological Training

    Office of Environmental Management (EM)

    _______ Change Notice 1 June 2009 DOE HANDBOOK GENERAL EMPLOYEE RADIOLOGICAL TRAINING U.S. Department of Energy AREA TRNG Washington, D.C. 20585 DISTRIBUTION STATEMENT A. Approved for public release; distribution is unlimited. Not Measurement Sensitive This document is available on the Department of Energy Technical Standards Program Web Site at http://www.hss.energy.gov/nuclearsafety/techstds/ Change 1 DOE-HDBK-1131-2007 Original Change Part 2 page 5 The average annual radiation dose to a

  17. General Employee Radiological Training

    Office of Environmental Management (EM)

    Not Measurement Sensitive DOE-HDBK-1131-2007 December 2007_______ Change Notice 1 Reaffirmed 2013 DOE HANDBOOK GENERAL EMPLOYEE RADIOLOGICAL TRAINING U.S. Department of Energy AREA TRNG Washington, D.C. 20585 DISTRIBUTION STATEMENT A. Approved for public release; distribution is unlimited. This document is available on the Department of Energy Technical Standards Program Web Site at http://www.hss.energy.gov/nuclearsafety/techstds/ Change 1 DOE-HDBK-1131-2007 Original Change Part 2 page 5 The

  18. General Employee Radiological Training

    Office of Environmental Management (EM)

    DOE HANDBOOK GENERAL EMPLOYEE RADIOLOGICAL TRAINING U.S. Department of Energy AREA TRNG Washington, D.C. 20585 DISTRIBUTION STATEMENT A. Approved for public release; distribution is unlimited. Not Measurement Sensitive This document is available on the Department of Energy Technical Standards Program Web Site at http://www.hss.energy.gov/nuclearsafety/techstds/ DOE-HDBK-1131-2007 iii Foreword This Handbook describes an implementation process for core training as recommended in chapter 14,

  19. Energy Conservation Tests of a Coupled Kinetic-kinetic Plasma-neutral Transport Code

    SciTech Connect (OSTI)

    Stotler, D. P.; Chang, C. S.; Ku, S. H.; Lang, J.; Park, G.

    2012-08-29

    A Monte Carlo neutral transport routine, based on DEGAS2, has been coupled to the guiding center ion-electron-neutral neoclassical PIC code XGC0 to provide a realistic treatment of neutral atoms and molecules in the tokamak edge plasma. The DEGAS2 routine allows detailed atomic physics and plasma-material interaction processes to be incorporated into these simulations. The spatial pro le of the neutral particle source used in the DEGAS2 routine is determined from the uxes of XGC0 ions to the material surfaces. The kinetic-kinetic plasma-neutral transport capability is demonstrated with example pedestal fueling simulations.

  20. Pedestal Fueling Simulations with a Coupled Kinetic-kinetic Plasma-neutral Transport Code

    SciTech Connect (OSTI)

    D.P. Stotler, C.S. Chang, S.H. Ku, J. Lang and G.Y. Park

    2012-08-29

    A Monte Carlo neutral transport routine, based on DEGAS2, has been coupled to the guiding center ion-electron-neutral neoclassical PIC code XGC0 to provide a realistic treatment of neutral atoms and molecules in the tokamak edge plasma. The DEGAS2 routine allows detailed atomic physics and plasma-material interaction processes to be incorporated into these simulations. The spatial pro le of the neutral particle source used in the DEGAS2 routine is determined from the uxes of XGC0 ions to the material surfaces. The kinetic-kinetic plasma-neutral transport capability is demonstrated with example pedestal fueling simulations.

  1. PEMP General Information

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3-A - 01/01/13 to 06/30/13 WTP Contract No. DE-AC27-01RV14136 Page 1 WTP PERFORMANCE EVALUATION & MEASUREMENT PLAN - PERIOD 2013-A TABLE OF CONTENTS Num ber PEMP General Information A Introduction 2 B Roles and Responsibilities 3 C Process and Schedule 5 D Contractor Self-Assessment 5 E PEMP Numbering System and Definitions 6 F Performance Periods 7 G Incentive Ratings and Definitions 7 Attachment A - Incentive B.1 - Award Fee - Project Management Incentive 7 B.1 Aw ard Fee - Project Managem

  2. PEMP General Information

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2-B - 07/01/12 to 12/31/12 WTP Contract No. DE-AC27-01RV14136 Page 1 WTP PERFORMANCE EVALUATION & MEASUREMENT PLAN - PERIOD 2012-B TABLE OF CONTENTS Num ber PEMP General Information A Introduction 2 B Roles and Responsibilities 3 C Process and Schedule 5 D Contractor Self-Assessment 5 E PEMP Numbering System and Definitions 6 F Performance Periods 7 G Incentive Ratings and Definitions 7 Attachment A - Incentive B.1 - Award Fee - Project Management Incentive 8 B.1 Aw ard Fee - Project Managem

  3. Neutron and gamma detector using an ionization chamber with an integrated body and moderator

    DOE Patents [OSTI]

    Ianakiev, Kiril D.; Swinhoe, Martyn T.; Lestone, John Paul

    2006-07-18

    A detector for detecting neutrons and gamma radiation includes a cathode that defines an interior surface and an interior volume. A conductive neutron-capturing layer is disposed on the interior surface of the cathode and a plastic housing surrounds the cathode. A plastic lid is attached to the housing and encloses the interior volume of the cathode forming an ionization chamber, into the center of which an anode extends from the plastic lid. A working gas is disposed within the ionization chamber and a high biasing voltage is connected to the cathode. Processing electronics are coupled to the anode and process current pulses which are converted into Gaussian pulses, which are either counted as neutrons or integrated as gammas, in response to whether pulse amplitude crosses a neutron threshold. The detector according to the invention may be readily fabricated into single or multilayer detector arrays.

  4. The Drift Chamber for the Experiment to Study the Nature of the Confinement

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Berdnikov, Vladimir V.; Somov, S. V.; Pentchev, Lubomir; Zihlmann, Benedikt

    2015-01-01

    The GlueX experiment was designed to search for hybrid mesons with exotic quantum numbers using a beam of linearly polarized photons incident on a liquid hydrogen target. The spectrum of these states and their mass splitting from normal mesons may yield information on confinement. The description of the GlueX spectrometer and Forward Drift Chambers (FDC) as a part of track reconstruction system is presented in the text. FDC‘s are multiwire chambers with cathode and anode read-out. The system allows reconstructing tracks of charged particles with ~200mkm accuracy with angles from 20° up to 1°. One of the detector features ismore » 1.64% X0 material amount in the active area. The cathode gain calibration procedure is presented. The results of such calibration using cosmic data and beam data are presented as well.« less

  5. Hard disk drive based microsecond x-ray chopper for characterization of ionization chambers and photodiodes

    SciTech Connect (OSTI)

    Mller, O. Ltzenkirchen-Hecht, D.; Frahm, R.

    2015-03-15

    A fast X-ray chopper capable of producing ms long X-ray pulses with a typical rise time of few ?s was realized. It is ideally suited to investigate the temporal response of X-ray detectors with response times of the order of ?s to ms, in particular, any kind of ionization chambers and large area photo diodes. The drive mechanism consists of a brushless DC motor and driver electronics from a common hard disk drive, keeping the cost at an absolute minimum. Due to its simple construction and small dimensions, this chopper operates at home lab based X-ray tubes and synchrotron radiation sources as well. The dynamics of the most important detectors used in time resolved X-ray absorption spectroscopy, namely, ionization chambers and Passivated Implanted Planar Silicon photodiodes, were investigated in detail. The results emphasize the applicability of this X-ray chopper.

  6. Kinetic extensions of magnetohydrodynamic models for axisymmetric toroidal plasmas

    SciTech Connect (OSTI)

    Cheng, C.Z.

    1989-04-01

    A nonvariational kinetic-MHD stability code (NOVA-K) has been developed to integrate a set of non-Hermitian integro-differential eigenmode equations due to energetic particles for axisymmetric toroidal plasmas in a general flux coordinate system with an arbitrary Jacobian. The NOVA-K code employs the Galerkin method involving Fourier expansions in the generalized poloidal angle theta and generalized toroidal angle /zeta/ directions, and cubic-B spline finite elements in the radial /Psi/ direction. Extensive comparisons with the existing variational ideal MHD codes show that the ideal MHD version of the NOVA-K code converges faster and gives more accurate results. The NOVA-K code is employed to study the effects of energetic particles on MHD-type modes: the stabilization of ideal MHD internal kink modes and the excitation of ''fishbone'' internal kink modes; and the alpha particle destabilization of toroidicity-induced Alfven eigenmodes (TAE) via transit resonances. Analytical theories are also presented to help explain the NOVA-K results. For energetic trapped particles generated by neutral beam injection (NBI) or ion cyclotron resonant heating (ICRH), a stability window for the n = 1 internal kink mode in the hot particle beta space exists even in the absence of the core ion finite Larmor radius effect. On the other hand, the trapped alpha particles are found to have negligible effects on the stability of the n = 1 internal kink mode, but the circulating alpha particles can strongly destabilize TAE modes via inverse Landau damping associated with the spatial gradient of the alpha particle pressure. 60 refs., 24 figs., 1 tab.

  7. Apparatus for monitoring tritium in tritium-contaminating environments using a modified Kanne chamber

    DOE Patents [OSTI]

    Anderson, D.F.

    1981-01-27

    A conventional Kanne tritium monitor has been redesigned to reduce its sensitivity to such contaminants as tritiated water vapor and tritiated oil. The high voltage electrode has been replaced by a wire cylinder and the collector electrode has been reduced in diameter. The area sensitive to contamination has thereby been reduced by about a factor of forty while the overall apparatus sensitivity and operation has not been affected. The design allows for in situ decontamination of the chambers, if necessary.

  8. A study of electromagnetic showers in the high density projection chamber

    SciTech Connect (OSTI)

    Albrecht, E.; Berggren, M.; Cattai, A.; Fischer, H.G.; Flammier, M.; Gerutti, G.; Innocenti, P.G.; Iversen, P.S.

    1983-02-01

    A prototype module of a High density Projection Chamber (HPC) has been tested in an electron beam. The HPC, with the shower conversion separated from the charge collection, offers a simple, homogeneous large volume detector with an energy resolution of 12.5%/..sqrt..E and an exceptionally fine granularity both along and transverse to the shower axis. The results from the test are presented together with a description of the calorimeter system.

  9. Apparatus for monitoring tritium in tritium contaminating environments using a modified Kanne chamber

    DOE Patents [OSTI]

    Anderson, David F. (Los Alamos, NM)

    1984-01-01

    A conventional Kanne tritium monitor has been redesigned to reduce its sensitivity to such contaminants as tritiated water vapor and tritiated oil. The high voltage electrode has been replaced by a wire cylinder and the collector electrode has been reduced in diameter. The area sensitive to contamination has thereby been reduced by about a factor of forty while the overall apparatus sensitivity and operation has not been affected. The design allows for in situ decontamination of the chambers, if necessary.

  10. General Motors | Open Energy Information

    Open Energy Info (EERE)

    Motors Jump to: navigation, search Name: General Motors Place: Detroit, MI Website: www.generalmotors.com References: General Motors1 Information About Partnership with NREL...

  11. Microwave remote plasma enhanced-atomic layer deposition system with multicusp confinement chamber

    SciTech Connect (OSTI)

    Dechana, A.; Thamboon, P.; Boonyawan, D.

    2014-10-15

    A microwave remote Plasma Enhanced-Atomic Layer Deposition system with multicusp confinement chamber is established at the Plasma and Beam Physics research facilities, Chiang Mai, Thailand. The system produces highly-reactive plasma species in order to enhance the deposition process of thin films. The addition of the multicusp magnetic fields further improves the plasma density and uniformity in the reaction chamber. Thus, the system is more favorable to temperature-sensitive substrates when heating becomes unwanted. Furthermore, the remote-plasma feature, which is generated via microwave power source, offers tunability of the plasma properties separately from the process. As a result, the system provides high flexibility in choice of materials and design experiments, particularly for low-temperature applications. Performance evaluations of the system were carried on coating experiments of Al{sub 2}O{sub 3} layers onto a silicon wafer. The plasma characteristics in the chamber will be described. The resulted Al{sub 2}O{sub 3} filmsanalyzed by Rutherford Backscattering Spectrometry in channeling mode and by X-ray Photoelectron Spectroscopy techniqueswill be discussed.

  12. Small-Chamber Measurements of Chemical-Specific Emission Factors for Drywall

    SciTech Connect (OSTI)

    Maddalena, Randy; Russell, Marion; Apte, Michael G.

    2010-06-01

    Imported drywall installed in U.S. homes is suspected of being a source of odorous and potentially corrosive indoor pollutants. To support an investigation of those building materials by the Consumer Products Safety Commission (CPSC), Lawrence Berkeley National Laboratory (LBNL) measured chemical-specific emission factors for 30 samples of drywall materials. Emission factors are reported for 75 chemicals and 30 different drywall samples encompassing both domestic and imported stock and incorporating natural, synthetic, or mixed gypsum core material. CPSC supplied all drywall materials. First the drywall samples were isolated and conditioned in dedicated chambers, then they were transferred to small chambers where emission testing was performed. Four sampling and analysis methods were utilized to assess (1) volatile organic compounds, (2) low molecular weight carbonyls, (3) volatile sulfur compounds, and (4) reactive sulfur gases. LBNL developed a new method that combines the use of solid phase microextraction (SPME) with small emission chambers to measure the reactive sulfur gases, then extended that technique to measure the full suite of volatile sulfur compounds. The testing procedure and analysis methods are described in detail herein. Emission factors were measured under a single set of controlled environmental conditions. The results are compared graphically for each method and in detailed tables for use in estimating indoor exposure concentrations.

  13. Polymer Growth Rate in a Wire Chamber with Oxygen,Water, or Alcohol Gas Additives

    SciTech Connect (OSTI)

    Boyarski, Adam; /SLAC

    2008-07-02

    The rate of polymer growth on wires was measured in a wire chamber while the chamber was aged initially with helium-isobutane (80:20) gas, and then with either oxygen, water, or alcohol added to the gas. At the completion of the aging process for each gas mixture, the carbon content on the wires was measured in a SEM/EDX instrument. The same physical wires were used in all the gas mixtures, allowing measurement of polymer build up or polymer depletion by each gas additive. It is found that the rate of polymer growth is not changed by the presence of oxygen, water or alcohol. Conjecture that oxygen reduces breakdown by removing polymer deposits on field wires is negated by these measurements. Instead, it appears that the reduced breakdown is due to lower resistance in the polymer from oxygen ions being transported into the polymer. It is also observed that field wires bombarded by the electrons in the SEM and then placed back into the chamber show an abundance of single electrons being emitted, indicating that electron charge is stored in the polymer layer and that a high electric field is necessary to remove the charge.

  14. Steam supply system for superposed turbine and process chamber, such as coal gasification

    SciTech Connect (OSTI)

    Menger, W.M.

    1986-08-26

    A steam supply system is described for a process chamber consuming superheated steam at a pressure of about 600 psi or below which is driven by a boiler operating at a pressure of about 2000 psi, a pressure range above that needed by the process chamber for also driving a superposed turbine. The system consists of: (a) a high pressure boiler feed pump for supplying highly purified water to the boiler; (b) a condensing reboiler connected to receive steam from the superposed turbine in a high pressure side; (c) the condensing reboiler also having a low pressure side, essentially isolated from fluid contact with the high pressure side, for receiving water for use in the lower operating pressure steam processes; (d) the condensing reboiler further comprising integral superheating means for heating the water received in the low pressure side into superheated low pressure steam with the steam received in the high pressure side; (e) means for conveying fluid from the high pressure side of the condensing reboiler to the boiler feed pump; and (f) means for conveying the low pressure superheated steam from the condensing reboiler to the process chamber.

  15. Comparative study of ionization chamber detectors vis-a-vis a CCD detector for dispersive XAS measurement in transmission geometry

    SciTech Connect (OSTI)

    Poswal, A. K.; Agrawal, A.; Bhattachryya, D.; Jha, S. N.; Sahoo, N. K.

    2013-02-05

    We have designed and fabricated parallel plate ionization chamber detectors and voltage vs. current characteristics (V-I curve) of the detectors were recorded with synchrotron radiation to qualify for use in X-ray Absorption Spectroscopy (XAS) measurements. After qualifying the ionization chambers, the detectors were used in the dispersive EXAFS beamline (BL-08) at INDUS-2 SRS in Turbo-XAS geometry. Using the same setup and under the same setting, XAS spectra were also recorded with a CCD detector and the observation on relative performance of the ionization chamber vis-a-vis the CCD detector is presented in this paper.

  16. PBXN-9 Ignition Kinetics and Deflagration Rates

    SciTech Connect (OSTI)

    Glascoe, E; Maienschein, J; Burnham, A; Koerner, J; Hsu, P; Wemhoff, A

    2008-04-24

    The ignition kinetics and deflagration rates of PBXN-9 were measured using specially designed instruments at LLNL and compared with previous work on similar HMX based materials. Ignition kinetics were measured based on the One Dimensional Time-to-Explosion combined with ALE3D modeling. Results of these experiments indicate that PBXN-9 behaves much like other HMX based materials (i.e. LX-04, LX-07, LX-10 and PBX-9501) and the dominant factor in these experiments is the type of explosive, not the type of binder/plasticizer. In contrast, the deflagration behavior of PBXN-9 is quite different from similar high weight percent HMX based materials (i.e LX-10, LX-07 and PBX-9501). PBXN-9 burns in a laminar manner over the full pressure range studied (0-310 MPa) unlike LX-10, LX-07, and PBX-9501. The difference in deflagration behavior is attributed to the nature of the binder/plasticizer alone or in conjunction with the volume of binder present in PBXN-9.

  17. The response of the HMX-based material PBXN-9 to thermal insults: thermal decomposition kinetics and morphological changes

    SciTech Connect (OSTI)

    Glascoe, E A; Hsu, P C; Springer, H K; DeHaven, M R; Tan, N; Turner, H C

    2010-12-10

    PBXN-9, an HMX-formulation, is thermally damaged and thermally decomposed in order to determine the morphological changes and decomposition kinetics that occur in the material after mild to moderate heating. The material and its constituents were decomposed using standard thermal analysis techniques (DSC and TGA) and the decomposition kinetics are reported using different kinetic models. Pressed parts and prill were thermally damaged, i.e. heated to temperatures that resulted in material changes but did not result in significant decomposition or explosion, and analyzed. In general, the thermally damaged samples showed a significant increase in porosity and decrease in density and a small amount of weight loss. These PBXN-9 samples appear to sustain more thermal damage than similar HMX-Viton A formulations and the most likely reasons are the decomposition/evaporation of a volatile plasticizer and a polymorphic transition of the HMX from {beta} to {delta} phase.

  18. Kinetics, Mechanics and Microstructure Changes in Storage Media |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Kinetics, Mechanics and Microstructure Changes in Storage Media Kinetics, Mechanics and Microstructure Changes in Storage Media Presentation on the Kinetics, Mechanics and Microstructure Changes in Storage Media given at the DOE Theory Focus Session on Hydrogen Storage Materials on May 18, 2006. PDF icon storage_theory_session_eiazab.pdf More Documents & Publications Summary Report from Theory Focus Session on Hydrogen Storage Materials Documentation of Hybrid

  19. Approximate models for the ion-kinetic regime in

    Office of Scientific and Technical Information (OSTI)

    inertial-confinement-fusion capsule implosions (Journal Article) | SciTech Connect Journal Article: Approximate models for the ion-kinetic regime in inertial-confinement-fusion capsule implosions Citation Details In-Document Search This content will become publicly available on May 19, 2016 Title: Approximate models for the ion-kinetic regime in inertial-confinement-fusion capsule implosions "Reduced" (i.e., simplified or approximate) ion-kinetic (RIK) models in

  20. Benchmark Reaction Mechanisms and Kinetics for Lean NOx Traps | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Benchmark Reaction Mechanisms and Kinetics for Lean NOx Traps Benchmark Reaction Mechanisms and Kinetics for Lean NOx Traps 2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. PDF icon acep_01_larson.pdf More Documents & Publications Development of Chemical Kinetic Models for Lean NOx Traps Development of Optimal Catalyst Designs and Operating Strategies for Lean NOx Reduction in Coupled

  1. Coupled Kinetic, Thermal, and Mechanical Modeling of FIB Micro...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Kinetics and Ion Mobility in Electrode Materials for Advanced Lithium Ion Batteries Materials Characterization Capabilities at the High Temperature Materials Laboratory and...

  2. Pressure Dependent Decomposition Kinetics of the Energetic Material...

    Office of Scientific and Technical Information (OSTI)

    Sponsoring Org: USDOE Country of Publication: United States Language: English Subject: 37 INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY; ACCELERATION; DIAMONDS; KINETICS;...

  3. Ultrafast kinetics subsequent to shock compression in an oxygen...

    Office of Scientific and Technical Information (OSTI)

    to shock compression in an oxygen-balanced mixture of nitromethane and hydrogen peroxide Citation Details In-Document Search Title: Ultrafast kinetics subsequent to shock ...

  4. Ultrafast kinetics subsequent to shock in an unreacted, oxygen...

    Office of Scientific and Technical Information (OSTI)

    shock in an unreacted, oxygen balanced mixture of nitromethane and hydrogen peroxide Citation Details In-Document Search Title: Ultrafast kinetics subsequent to shock in an ...

  5. Microscale Electrode Design Using Coupled Kinetic, Thermal and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Documents & Publications track 3: enhanced geothermal systems (EGS) | geothermal 2015 peer review Coupled Kinetic, Thermal, and Mechanical Modeling of FIB Micro-machined...

  6. Desorption Kinetics of Methanol, Ethanol, and Water from Graphene...

    Office of Scientific and Technical Information (OSTI)

    desorption kinetics would be readily apparent in the experimental TPD spectra. Authors: Smith, R. Scott ; Matthiesen, Jesper ; Kay, Bruce D. Publication Date: 2014-09-18 OSTI...

  7. Microscale Electrode Design Using Coupled Kinetic, Thermal and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Modeling-Thermo-electrochemistry, Capacity Degradation and Mechanics with SEI Layer Coupled Kinetic, Thermal, and Mechanical Modeling of FIB ...

  8. Transport Phenomena and Interfacial Kinetics in Planar Microfluidic

    Office of Scientific and Technical Information (OSTI)

    Transport Phenomena and Interfacial Kinetics in Planar Microfluidic Membraneless Fuel Cells Abruna, Hector Daniel Cornell University 30 DIRECT ENERGY CONVERSION Our work is...

  9. Uranium and Strontium Batch Sorption and Diffusion Kinetics into...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Uranium and Strontium Batch Sorption and Diffusion Kinetics into Mesoporous Silica Friday, February 27, 2015 Figure 1 Figure 1. Transmission electron microscopy images of (A)...

  10. Micro Hydro Kinetic Turbines from Smart Hydro Power | Open Energy...

    Open Energy Info (EERE)

    Hydro Kinetic Turbines from Smart Hydro Power Jump to: navigation, search << Return to the MHK database homepage Tauchturbine.jpg Technology Profile Project(s) where this...

  11. MHK Projects/Ogdensburg Kinetic Energy Project | Open Energy...

    Open Energy Info (EERE)

    Project Phase Phase 1 Main Overseeing Organization AER NY Kinetics LLC Project Licensing Environmental Monitoring and Mitigation Efforts See Tethys << Return to the MHK database...

  12. Ultrafast kinetics subsequent to shock compression in an oxygen...

    Office of Scientific and Technical Information (OSTI)

    subsequent to shock compression in an oxygen-balanced mixture of nitromethane and hydrogen peroxide Citation Details In-Document Search Title: Ultrafast kinetics subsequent to...

  13. A Study and Comparison of SCR Reaction Kinetics from Reactor...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Optimal Catalyst Designs and Operating Strategies for Lean NOx Reduction in Coupled LNT-SCR Systems CLEERS Coordination & Joint Development of Benchmark Kinetics for LNT & SCR...

  14. Simulations of Kinetic Events at the Atomic Scale

    Broader source: Energy.gov [DOE]

    Presentation on the Simulations of Kinetic Events at the Atomic Scale given at the DOE Theory Focus Session on Hydrogen Storage Materials on May 18, 2006.

  15. Microsoft Word - Amber Kinetics - Final Technical Report (30...

    Office of Scientific and Technical Information (OSTI)

    December 30, 2015 ACKNOWLEDGMENT: Amber Kinetics would like ... or usefulness of any information, apparatus, product, or ... inputs such as current electricity prices, geographic ...

  16. Kinetic Theory of Turbulent Multiphase Flow | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Kinetic Theory of Turbulent Multiphase Flow FWPProject Description: Project Leader(s): Rodney Fox It is proposed to further the present understanding of turbulent gas-solid...

  17. A Comparison of HCCI Engine Performance Data and Kinetic Modeling...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Kinetic models of fuels are needed to allow the simulation of engine performance for research, design, or verification purposes. PDF icon deer09bunting.pdf More Documents &...

  18. Mechanism and kinetics of peptide partitioning into membranes

    SciTech Connect (OSTI)

    Ulmschneider, Martin [University of Oxford; Killian, J Antoinette [University of Utrecht; Doux, Jacques P. F. [University of Utrecht; Smith, Jeremy C [ORNL; Ulmschneider, Jakob [University of Heidelberg

    2010-02-01

    Partitioning properties of transmembrane (TM) polypeptide segments directly determine membrane protein folding, stability, and function, and their understanding is vital for rational design of membrane active peptides. However, direct determination of water-to-bilayer transfer of TM peptides has proved difficult. Experimentally, sufficiently hydrophobic peptides tend to aggregate, while atomistic computer simulations at physiological temperatures cannot yet reach the long time scales required to capture partitioning. Elevating temperatures to accelerate the dynamics has been avoided, as this was thought to lead to rapid denaturing. However, we show here that model TM peptides (WALP) are exceptionally thermostable. Circular dichroism experiments reveal that the peptides remain inserted into the lipid bilayer and are fully helical, even at 90 C. At these temperatures, sampling is 50 500 times faster, sufficient to directly simulate spontaneous partitioning at atomic resolution. A folded insertion pathway is observed, consistent with three-stage partitioning theory. Elevated temperature simulation ensembles further allow the direct calculation of the insertion kinetics, which is found to be first-order for all systems. Insertion barriers are Hin = 15 kcal/mol for a general hydrophobic peptide and 23 kcal/mol for the tryptophan-flanked WALP peptides. The corresponding insertion times at room temperature range from 8.5 s to 163 ms. High-temperature simulations of experimentally validated thermostable systems suggest a new avenue for systematic exploration of peptide partitioning properties.

  19. Utilization of Kinetic Isotope Effects for the Concentration of Tritium

    SciTech Connect (OSTI)

    Brown, Gilbert M.; Meyer, Thomas j.; Moyer, Bruce A.

    1999-06-01

    The objective of this research program is to develop methods for concentrating tritium in water based on large primary isotope effects in catalytic redox processes. Basic research is being conducted to develop the chemistry of a complete cyclic process. Because tritium (generally present as HTO) is in a rapidly established equilibrium with protio-water, it moves with groundwater and separation from water cannot be achieved by the usual pump-and-treat methods using sorbants. The general methodology developed in this work will be applicable to a number of DOE waste streams, and as a consequence of the process tritium will be incorporated into an organic compound that will not readily exchange the tritium with groundwater. The process to be developed will remove tritium from H2O by concentrating it with respect to protio-water. This research involves developing chemical cycles that produce high concentration factors for HTO and T2O based on the discrimination of C-H and C-T bonds in oxidation reactions. Several steps are required in a cyclic process for the concentration of tritium in water. In the first step the tritium is incorporated in an organic compound. H-T discrimination occurs as the tritium containing compound is oxidized in a step involving a Ru(IV) oxo complex. Strong primary kinetic isotope effects lead to the oxidation of C-H bonds in preference to C-T bonds, and this reaction leads to concentration of tritium in the organic compound. The reduced form of the ruthenium compound can be reoxidized so that the oxidation step can be made catalytic.

  20. Office of the Assistant General Counsel for General Law

    Broader source: Energy.gov [DOE]

    The Office of the Assistant General Counsel for General Law (GC-56) provides legal support for non-programmatic issues other than those involving procurement and intellectual property.  The office...

  1. Title 1 General Provisions Chapter 5 Common Law; General Rights...

    Open Energy Info (EERE)

    General Provisions Chapter 5 Common Law; General Rights 3 V.S.A. Section 2809 Jump to: navigation, search OpenEI Reference LibraryAdd to library Legal Document- StatuteStatute:...

  2. Spectroscopy, Kinetics, and Dynamics of Combustion Radicals

    SciTech Connect (OSTI)

    Nesbitt, David J.

    2013-08-06

    Spectroscopy, kinetics and dynamics of jet cooled hydrocarbon transients relevant to the DOE combustion mission have been explored, exploiting i) high resolution IR lasers, ii) slit discharge sources for formation of jet cooled radicals, and iii) high sensitivity detection with direct laser absorption methods and near the quantum shot noise limit. What makes this combination powerful is that such transients can be made under high concentrations and pressures characteristic of actual combustion conditions, and yet with the resulting species rapidly cooled (T ?10-15K) in the slit supersonic expansion. Combined with the power of IR laser absorption methods, this provides novel access to spectral detection and study of many critical combustion species.

  3. Kinetics of wet sodium vapor complex plasma

    SciTech Connect (OSTI)

    Mishra, S. K., E-mail: nishfeb@rediffmail.com [Institute for Plasma Research (IPR), Gandhinagar 382428 (India); Sodha, M. S. [Centre of Energy Studies, Indian Institute of Technology Delhi (IITD), New Delhi 110016 (India)] [Centre of Energy Studies, Indian Institute of Technology Delhi (IITD), New Delhi 110016 (India)

    2014-04-15

    In this paper, we have investigated the kinetics of wet (partially condensed) Sodium vapor, which comprises of electrons, ions, neutral atoms, and Sodium droplets (i) in thermal equilibrium and (ii) when irradiated by light. The formulation includes the balance of charge over the droplets, number balance of the plasma constituents, and energy balance of the electrons. In order to evaluate the droplet charge, a phenomenon for de-charging of the droplets, viz., evaporation of positive Sodium ions from the surface has been considered in addition to electron emission and electron/ion accretion. The analysis has been utilized to evaluate the steady state parameters of such complex plasmas (i) in thermal equilibrium and (ii) when irradiated; the results have been graphically illustrated. As a significant outcome irradiated, Sodium droplets are seen to acquire large positive potential, with consequent enhancement in the electron density.

  4. Brittle failure kinetics model for concrete

    SciTech Connect (OSTI)

    Silling, S.A.

    1997-03-01

    A new constitutive model is proposed for the modeling of penetration and large stress waves in concrete. Rate effects are incorporated explicitly into the damage evolution law, hence the term brittle failure kinetics. The damage variable parameterizes a family of Mohr-Coulomb strength curves. The model, which has been implemented in the CTH code, has been shown to reproduce some distinctive phenomena that occur in penetration of concrete targets. Among these are the sharp spike in deceleration of a rigid penetrator immediately after impact. Another is the size scale effect, which leads to a nonlinear scaling of penetration depth with penetrator size. This paper discusses the theory of the model and some results of an extensive validation effort.

  5. Research Laboratories General Motors Corporation General Motors Technical Center

    Office of Legacy Management (LM)

    MI. 1-q Research Laboratories General Motors Corporation General Motors Technical Center Warren, Michigan 48090 January 21, 1977 Occupational Health Standards Branch Office of Standards Development U. S. Nuclear Requlatory Commission Washington, D.C. 20555 Attention: Mr. Robert E. Alexander, Chief Dear Mr. Alexander: In 1974, General Motors Corporation acquired a manufacturing plant in Adrian, Michigan. On October 21, 1976, General Motors announced that work would begin immediately to prepare

  6. PICASSO, COUPP and PICO - Search for dark matter with bubble chambers

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Amole, C.; Ardid, M.; Asner, D. M.; Baxter, D.; Behnke, E.; Bhattacharjee, P.; Borsodi, H.; Bou-Cabo, M.; Brice, S. J.; Broemmelsiek, D.; et al

    2015-05-29

    The PICASSO and COUPP collaborations use superheated liquid detectors to search for cold dark matter through the direct detection of weakly interacting massive particles (WIMPs). These experiments, located in the underground laboratory of SNOLAB, Canada, detect phase transitions triggered by nuclear recoils in the keV range induced by interactions with WIMPs. We present details of the construction and operation of these detectors as well as the results, obtained by several years of observations. We also introduce PICO, a joint effort of the two collaborations to build a second generation ton-scale bubble chamber with 250 liters of active liquid.

  7. PICASSO, COUPP and PICO - search for dark matter with bubble chambers

    Office of Scientific and Technical Information (OSTI)

    EPJ Web of Conferences 95,04020 (2015) DOI: 10.1051/epjconf/ 20159504020 © Owned by the authors, published by EDP Sciences, 2015 PICASSO, COUPP and PICO - search for dark matter with bubble chambers C. Amole1, M. Ardid2, D. M. Asner3, D. Baxter4, E. Behnke5, P. Bhattacharjee6, H. Borsodi5, M. Bou-Cabo2, S. J. Brice7, D. Broemmelsiek7, K. Clark8, J. I. Collar9, P S. Cooper7, M. Crisler7, C. E. Dahl4, M. Das6, F. Debris10, N. Dhungana11, J. Farine11, I. Felis2, R. Filgas12,a, M. Fines-

  8. High-voltage crowbar protection for the large CDF axial drift chamber

    SciTech Connect (OSTI)

    Binkley, M.; Mukherjee, A.; Stuermer, W.; Wagner, R.L.; /Fermilab

    2004-01-01

    The Central Outer Tracker (COT) is a big cylindrical drift chamber that provides charged particle tracking for the Collider Detector at Fermilab experiment. To protect the COT, the large stored energy in the high voltage system needs to be removed quickly when a problem is sensed. For the high voltage switch, a special-order silicon-controlled-rectifier was chosen over more readily available integrated gate bipolar transistors because of layout and reliability questions. The considerations concerning the high voltage switch, the prototype performance, and the experience of more than two years of running are described.

  9. SU-E-T-343: Valencia Applicator Commissioning Using a Micro-Chamber Array

    SciTech Connect (OSTI)

    Carmona-Meseguer, V; Palomo-Llinares, R; Candela-Juan, C; Gimeno-Olmos, J; Lliso-Valverde, F; Garcia-Martinez, T; Richart-Sancho, J; Granero, D; Ballester, F; Perez-Calatayud, J

    2014-06-01

    Purpose: In the commissioning and QA of surface isotope-based applicators, source-indexer distance (SID) has a great influence in the flatness, symmetry and output. To these purposes, methods described in the literature are the use of a special insert at the entrance of dwell chamber or radiochromic films. Here we present the experience with a micro-chamber array to perform the commissioning and QA of Valencia applicators. Methods: Valencia applicators have been used, the classic and the new extra-shielded version. A micro-chamber array has been employed, 1000 SRS (PTW), with 977 liquid filled, 2.32.30.5 mm{sup 3} sized ion chambers covering 1111 cm{sup 2}, which spacing is 2.5 mm in the central 5.55.5 cm{sup 2}, dedicated mainly in principle, in conjunction with Octavius 4D (PTW), to IMRT, VMAT, SBRT verifications. Verisoft software that allows for 3D and planar analysis has been used to evaluate the results. Applicators were located on the surface of the array. To verify the SID, measurements corresponding to the reference value, SID 1 mm and SID 2 mm were acquired (integration time was fixed in order to discard the influence of the source entrance/exit). Once SID was determined, standard protocol treatments corresponding to 3 Gy and 7 Gy were acquired in order to establish typical patient dose distribution. Results: The method is fast and sensitive. The SID obtained was 1321 mm which is the nominal value included in the applicator manual. For example at 1319 mm an asymmetry of 8% with respect to the central value was measured, along with a central deviation of ?4% referred to 1321 mm. Conclusion: A practical method for the commissioning and QA of Valencia applicators has been described. It has been shown that it is an efficient and accurate tool for these purposes as well as for the verification of the absolute output constancy.

  10. U.S. Chamber of Commerce's 4th Annual North America Forum | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Commerce's 4th Annual North America Forum U.S. Chamber of Commerce's 4th Annual North America Forum June 16, 2008 - 1:30pm Addthis Remarks As Prepared for Delivery for Secretary Bodman Thank you very much, Ron, for that kind introduction and for the critically important work that you and your colleagues do at Lawrence Livermore. I also want to thank my good friend Secretary George Shultz - along with his esteemed co-chairs for this event, Peter Lougheed and Pedro Aspe, for inviting me

  11. Pressure distribution along the AGS vacuum chambers with new types of pump out conduits

    SciTech Connect (OSTI)

    Nayak, S.; Mapes, M.; Smart, L.; Weiss, D.

    2015-10-28

    The AGS HEBT and ring vacuum system is monitored by the discharge current of the magnet ion pumps, which is proportional to the pressure at the inlet port of these ion pumps. The discharge current is measured and suitably calibrated to indicate the ion pump pressure. In order to calculate the vacuum chamber pressure from the ion pump pressure, a detailed analysis is essential to compute their difference in different scenarios. Such analysis has been carried out numerically in the past for the system with the older type of pump out conduits and similar analysis using FEM in ANSYS is presented in this paper with the newer type of pump out conduit.

  12. High-Accuracy Measurements of the Centre of Gravity of Avalanches in Proportional Chambers

    DOE R&D Accomplishments [OSTI]

    Charpak, G.; Jeavons, A.; Sauli, F.; Stubbs, R.

    1973-09-24

    In a multiwire proportional chamber the avalanches occur close to the anode wires. The motion of the positive ions in the large electric fields at the vicinity of the wires induces fast-rising positive pulses on the surrounding electrodes. Different methods have been developed in order to determine the position of the centre of the avalanches. In the method we describe, the centre of gravity of the pulse distribution is measured directly. It seems to lead to an accuracy which is limited only by the stability of the spatial distribution of the avalanches generated by the process being measured.

  13. Fully kinetic simulations of megajoule-scale dense plasma focus

    SciTech Connect (OSTI)

    Schmidt, A.; Link, A.; Tang, V.; Halvorson, C.; May, M.; Welch, D.; Meehan, B. T.; Hagen, E. C.

    2014-10-15

    Dense plasma focus (DPF) Z-pinch devices are sources of copious high energy electrons and ions, x-rays, and neutrons. Megajoule-scale DPFs can generate 10{sup 12} neutrons per pulse in deuterium gas through a combination of thermonuclear and beam-target fusion. However, the details of the neutron production are not fully understood and past optimization efforts of these devices have been largely empirical. Previously, we reported on the first fully kinetic simulations of a kilojoule-scale DPF and demonstrated that both kinetic ions and kinetic electrons are needed to reproduce experimentally observed features, such as charged-particle beam formation and anomalous resistivity. Here, we present the first fully kinetic simulation of a MegaJoule DPF, with predicted ion and neutron spectra, neutron anisotropy, neutron spot size, and time history of neutron production. The total yield predicted by the simulation is in agreement with measured values, validating the kinetic model in a second energy regime.

  14. Response to high-energy photons of PTW31014 PinPoint ion chamber with a central aluminum electrode

    SciTech Connect (OSTI)

    Agostinelli, S.; Garelli, S.; Piergentili, M.; Foppiano, F.

    2008-07-15

    Since its introduction the PinPoint (PTW-Freiburg) micro-ionization chamber has been proposed for relative dosimetry (output factors, depth dose curves, and beam profiles) as well as for determination of absolute dose of small high-energy photon beams. This paper investigates the dosimetric performance of a new design (type 31014) of the PinPoint ion chamber with a central aluminum electrode. The study included characterization of inherent and radiation-induced leakage, ion collection efficiency and polarity effect, relative response of the chamber, measurement of beam profiles, and depth dose curves. The 6 and 15 MV photon beams of a Varian 2100 C/D were considered. At the nominal operating voltage of 400 V the PinPoint type 31014 chamber was found to present a strong field size dependence of the polarity correction factor and an excess of the collected charge, which can lead to an underestimation of the collection efficiency if determined with the conventional ''two-voltage'' method. In comparison to the original PinPoint design (type 31006) the authors found for type 31014 chamber no overresponse to large-area fields if polarity correction is applied. If no correction is taken into consideration, the authors found the chamber's output to be inaccurate for large-area fields (0.5% accuracy limited up to the 12x12 and 20x20 cm{sup 2} field for the 6 and 15 MV beams, respectively), which is a direct consequence of the stem and polarity effects due to the chamber's very small sensitive volume (0.015 cc) and cable irradiation. Beam profiles and depth dose curves measured with type 31014 PinPoint chamber for small and medium size fields were compared to data measured with a 0.125 cc ion chamber and with high-resolution Kodak EDR2 films. Analysis of the penumbra (80%-20% distance) showed that the spatial resolution of type 31014 PinPoint ion chamber approaches (penumbra broadening {<=}0.6 mm) EDR2 film results.

  15. Kinetic gating mechanism of DNA damage recognition by Rad4/XPC

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chen, Xuejing; Velmurugu, Yogambigai; Zheng, Guanqun; Park, Beomseok; Shim, Yoonjung; Kim, Youngchang; Liu, Lili; Van Houten, Bennett; He, Chuan; Ansari, Anjum; et al

    2015-01-06

    The xeroderma pigmentosum C (XPC) complex initiates nucleotide excision repair by recognizing DNA lesions before recruiting downstream factors. How XPC detects structurally diverse lesions embedded within normal DNA is unknown. Here we present a crystal structure that captures the yeast XPC orthologue (Rad4) on a single register of undamaged DNA. The structure shows that a disulphide-tethered Rad4 flips out normal nucleotides and adopts a conformations similar to that seen with damaged DNA. Contrary to many DNA repair enzymes that can directly reject non-target sites as structural misfits, our results suggest that Rad4/XPC uses a kinetic gating mechanism whereby lesion selectivitymore » arises from the kinetic competition between DNA opening and the residence time of Rad4/XPC per site. This mechanism is further supported by measurements of Rad4-induced lesion-opening times using temperature-jump pertubation spectroscopy. Kinetic gating may be a general mechanism used by site-specific DNA-binding proteins to minimize time-consuming interrogations of non-target sites.« less

  16. Kinetic electron and ion instability of the lunar wake simulated at physical mass ratio

    SciTech Connect (OSTI)

    Haakonsen, Christian Bernt Hutchinson, Ian H. Zhou, Chuteng

    2015-03-15

    The solar wind wake behind the moon is studied with 1D electrostatic particle-in-cell (PIC) simulations using a physical ion to electron mass ratio (unlike prior investigations); the simulations also apply more generally to supersonic flow of dense magnetized plasma past non-magnetic objects. A hybrid electrostatic Boltzmann electron treatment is first used to investigate the ion stability in the absence of kinetic electron effects, showing that the ions are two-stream unstable for downstream wake distances (in lunar radii) greater than about three times the solar wind Mach number. Simulations with PIC electrons are then used to show that kinetic electron effects can lead to disruption of the ion beams at least three times closer to the moon than in the hybrid simulations. This disruption occurs as the result of a novel wake phenomenon: the non-linear growth of electron holes spawned from a narrow dimple in the electron velocity distribution. Most of the holes arising from the dimple are small and quickly leave the wake, approximately following the unperturbed electron phase-space trajectories, but some holes originating near the center of the wake remain and grow large enough to trigger disruption of the ion beams. Non-linear kinetic-electron effects are therefore essential to a comprehensive understanding of the 1D electrostatic stability of such wakes, and possible observational signatures in ARTEMIS data from the lunar wake are discussed.

  17. Dark matter search results from the PICO-2L C$_3$F$_8$ bubble chamber

    SciTech Connect (OSTI)

    Amole, C.

    2015-06-11

    New data are reported from the operation of a 2 liter C3F8 bubble chamber in the SNOLAB underground laboratory, with a total exposure of 211.5 kg days at four different energy thresholds below 10 keV. These data show that C3F8 provides excellent electron-recoil and alpha rejection capabilities at very low thresholds. The chamber exhibits an electron-recoil sensitivity of < 3.5 1010 and an alpha rejection factor of > 98.2%. These data also include the first observation of a dependence of acoustic signal on alpha energy. Twelve single nuclear recoil event candidates were observed during the run. The candidate events exhibit timing characteristics that are not consistent with the hypothesis of a uniform time distribution, and no evidence for a dark matter signal is claimed. Lastly, these data provide the most sensitive direct detection constraints on WIMP-proton spin-dependent scattering to date, with significant sensitivity at low WIMP masses for spin-independent WIMP-nucleon scattering.

  18. Experimental and theoretical evaluation of a toroidal combustion chamber for stratified-charge engines

    SciTech Connect (OSTI)

    Quiros, E.N.; Adams, J.W.; Otis, D.R.; Myers, P.S.

    1990-03-02

    Maximum efficiency of cyclic combustion engines (CCE) is achieved when using stratified charge and high compression ratio with controlled air circulation and combustion. A description is given of a varying-area, toroidal-shaped combustion chamber designed to achieve the above objectives by: obtaining initial circulatory air motion induced by the piston late in the compression stroke; increasing this piston-induced velocity using the momentum of fuel injected tangentially to the center line of the toroid; and by using combustion to further increase the circulation rate. Four combustion chamber configurations were studied in a bomb with zero initial air velocity to ascertain whether significant rotation could be achieved by injection and combustion. Gas pressure was measured and high speed photographs were taken of the injection and combustion process. The ideal situation, at full load, is to have one rotation of the gas during the time allocated to combustion. The experimental results, with zero initial velocity, show that fuel momentum plus combustion produces from one-half to three-quarters of a rotation in the available time. Modeling suggests that the use of initial, piston-induced velocities would result in the desired one rotation in the available time.

  19. Dark matter search results from the PICO-2L C$_3$F$_8$ bubble chamber

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Amole, C.

    2015-06-11

    New data are reported from the operation of a 2 liter C3F8 bubble chamber in the SNOLAB underground laboratory, with a total exposure of 211.5 kg days at four different energy thresholds below 10 keV. These data show that C3F8 provides excellent electron-recoil and alpha rejection capabilities at very low thresholds. The chamber exhibits an electron-recoil sensitivity of < 3.5 × 10–10 and an alpha rejection factor of > 98.2%. These data also include the first observation of a dependence of acoustic signal on alpha energy. Twelve single nuclear recoil event candidates were observed during the run. The candidate eventsmore » exhibit timing characteristics that are not consistent with the hypothesis of a uniform time distribution, and no evidence for a dark matter signal is claimed. Lastly, these data provide the most sensitive direct detection constraints on WIMP-proton spin-dependent scattering to date, with significant sensitivity at low WIMP masses for spin-independent WIMP-nucleon scattering.« less

  20. Chamber wall interactions with HBr/Cl{sub 2}/O{sub 2} plasmas

    SciTech Connect (OSTI)

    Srivastava, Ashutosh K.; Ohashi, Tomohiro; Donnelly, Vincent M.

    2015-07-15

    The authors have studied the interaction of HBr/Cl{sub 2}/O{sub 2} inductively coupled plasmas with reactor chamber wall deposits, with and without Si etching, using the spinning wall technique. The spinning wall is part of the reactor chamber walls, allowing near-real-time analysis of the composition of surface layers via Auger electron spectrometry and determination of species desorbing off the walls by mass spectrometry. In HBr plasmas with no bias voltage on the Si substrate, and hence no Si etching, HBr is ?30% dissociated, and H{sub 2} and Br{sub 2} form in the plasma. Layers deposited on the reactor chamber contained little if any Br under these conditions. Adding O{sub 2} to an HBr plasma leads to formation of H{sub 2}O and increased Br{sub 2} (compared to a pure HBr plasma) products that desorb from the spinning wall. H{sub 2}O has a very long residence time on the surface. With bias voltage applied to the Si substrate in an HBr plasma, mass spectrometer signals are prominent for SiBr and SiBr{sub 3}, and weaker for SiBr{sub 2}, SiBr{sub 4}, Si{sub 2}Br{sub 4}, Si{sub 2}Br{sub 5}, and Si{sub 2}OBr{sub 5}. Under these conditions, a SiO{sub x}Br{sub y} layer deposits on the spinning wall. Adding 20% O{sub 2} to HBr stops etching and eliminates Br from the surface layer, indicating that Br on the reactor walls is a result of SiBr{sub x} impingement and not from bromination by impinging Br. With HBr/Cl{sub 2} plasmas and no bias on the stage, a SiO{sub x}Cl{sub y} layer deposits, and no Br is detected. HCl, BrCl, and Br{sub 2} were detected in the line-of-sight leak, around the spinning wall, of a HBr/Cl{sub 2} (1:1) gas mixture in the absence of a plasma. Residence time analysis of species in the chamber and a change in the product distribution with a change in the composition of the layer deposited on the chamber wall suggest that reactions forming these products in the absence of a plasma occur on the reactor walls. With a plasma and bias on the Si substrate, both Br and Cl incorporate in the layer, and a rich spectrum with numerous SiCl{sub x}Br{sub y} peaks was observed up to at least 500 amu. The spectrum does not change with the addition of 6% O{sub 2}. Adding 20% O{sub 2} suppresses Br adsorption, but Cl still adsorbs. In 40% O{sub 2}/HBr/Cl{sub 2} plasmas with stage bias, Cl adsorption also ceases and no etching products are observed in the mass spectrum.

  1. A Proposal for a Ton Scale Bubble Chamber for Dark Matter Detection

    SciTech Connect (OSTI)

    Collar, Juan; Dahl, C.Eric; Fustin, Drew; Robinson, Alan; Behnke, Ed; Behnke, Joshua; Breznau, William; Connor, Austin; Kuehnemund, Emily Grace; Levine, Ilan; Moan, Timothy; /Indiana U., South Bend /Fermilab

    2010-10-07

    The nature of non-baryonic dark matter is one of the most intriguing questions for particle physics at the start of the 21st century. There is ample evidence for its existence, but almost nothing is known of its properties. WIMPs are a very appealing candidate particle and several experimental campaigns are underway around the world to search for these particles via the nuclear recoils that they should induce. The COUPP series of bubble chambers has played a significant role in the WIMP search. Through a sequence of detectors of increasing size, a number of R&D issues have arisen and been solved, and the technology has now been advanced to the point where the construction of large chambers requires a modest research effort, some development, but mostly just engineering. It is within this context that we propose to build the next COUPP detector - COUPP-500, a ton scale device to be built over the next three years at Fermilab and then deployed deep underground at SNOLAB. The primary advantages of the COUPP approach over other technologies are: (1) The ability to reject electron and gamma backgrounds by arranging the chamber thermodynamics such that these particles do not even trigger the detector. (2) The ability to suppress neutron backgrounds by having the radioactively impure detection elements far from the active volume and by using the self-shielding of a large device and the high granularity to identify multiple bubbles. (3) The ability to build large chambers cheaply and with a choice of target fluids. (4) The ability to increase the size of the chambers without changing the size or complexity of the data acquisition. (5) Sensitivity to spin-dependent and spin-independent WIMP couplings. These key advantages should enable the goal of one background event in a ton-year of exposure to be achieved. The conceptual design of COUPP-500 is scaled from the preceding devices. In many cases all that is needed is a simple scaling up of components previously used. Calibration and R&D are still needed on some aspects of the system. We know we have the ability to distinguish alpha-induced events from nuclear recoils, but we do not yet know whether the combination of material purity and rejection are good enough to run for a year with no alpha background. We also need to have more detailed measurements of the detector threshold and a better understanding of its high gamma rejection. In addition, there are important checks to make on the longevity of the detector components in the hydraulic fluid and on the chemistry of the active fluid. The 2009 PASAG report explicitly supported the construction of the COUPP-500 device in all funding scenarios. The NSF has shown similar enthusiasm. It awarded one of its DUSEL S4 grants to assist in the engineering needed to build COUPP-500. The currently estimated cost of COUPP-500 is $8M, about half the $15M-$20M price tag expected by the PASAG report for a next generation dark matter search experiment. The COUPP-500 device will have a spin independent WIMP-nucleus cross-section sensitivity of 6 x 10{sup -47} cm{sup 2} after a background-free year of running. This device should then provide the benchmark against which all other WIMP searches are measured.

  2. HIGH PRESSURE COAL COMBUSTON KINETICS PROJECT

    SciTech Connect (OSTI)

    Stefano Orsino

    2005-03-30

    As part of the U.S. Department of Energy (DoE) initiative to improve the efficiency of coal-fired power plants and reduce the pollution generated by these facilities, DOE has funded the High-Pressure Coal Combustion Kinetics (HPCCK) Projects. A series of laboratory experiments were conducted on selected pulverized coals at elevated pressures with the specific goals to provide new data for pressurized coal combustion that will help extend to high pressure and validate models for burnout, pollutant formation, and generate samples of solid combustion products for analyses to fill crucial gaps in knowledge of char morphology and fly ash formation. Two series of high-pressure coal combustion experiments were performed using SRI's pressurized radiant coal flow reactor. The first series of tests characterized the near burner flame zone (NBFZ). Three coals were tested, two high volatile bituminous (Pittsburgh No.8 and Illinois No.6), and one sub-bituminous (Powder River Basin), at pressures of 1, 2, and 3 MPa (10, 20, and 30 atm). The second series of experiments, which covered high-pressure burnout (HPBO) conditions, utilized a range of substantially longer combustion residence times to produce char burnout levels from 50% to 100%. The same three coals were tested at 1, 2, and 3 MPa, as well as at 0.2 MPa. Tests were also conducted on Pittsburgh No.8 coal in CO2 entrainment gas at 0.2, 1, and 2 MPa to begin establishing a database of experiments relevant to carbon sequestration techniques. The HPBO test series included use of an impactor-type particle sampler to measure the particle size distribution of fly ash produced under complete burnout conditions. The collected data have been interpreted with the help of CFD and detailed kinetics simulation to extend and validate devolatilization, char combustion and pollutant model at elevated pressure. A global NOX production sub-model has been proposed. The submodel reproduces the performance of the detailed chemical reaction mechanism for the NBFZ tests.

  3. Galileons coupled to massive gravity: general analysis and cosmological solutions

    SciTech Connect (OSTI)

    Goon, Garrett; Trodden, Mark; Gmrko?lu, A. Emir; Hinterbichler, Kurt; Mukohyama, Shinji E-mail: Emir.Gumrukcuoglu@nottingham.ac.uk E-mail: shinji.mukohyama@ipmu.jp

    2014-08-01

    We further develop the framework for coupling galileons and Dirac-Born-Infeld (DBI) scalar fields to a massive graviton while retaining both the non-linear symmetries of the scalars and ghost-freedom of the theory. The general construction is recast in terms of vielbeins which simplifies calculations and allows for compact expressions. Expressions for the general form of the action are derived, with special emphasis on those models which descend from maximally symmetric spaces. We demonstrate the existence of maximally symmetric solutions to the fully non-linear theory and analyze their spectrum of quadratic fluctuations. Finally, we consider self-accelerating cosmological solutions and study their perturbations, showing that the vector and scalar modes have vanishing kinetic terms.

  4. Kinetic model for anaerobic digestion of biogas biological sludge

    SciTech Connect (OSTI)

    Pavlostathis, S.G.; Gossett, J.M.

    1986-10-01

    The principal objective of this study was the development and evaluation of a comprehensive kinetic model capable of predicting digester performance when fed biological sludge. Preliminary conversion mechanisms such as cell deaths, lysis, and hydrolysis responsible for rendering viable biological sludge organisms to available substrate were studied in depth. The results of this study indicate that hydrolysis of the dead, particulate biomass - primarily consisting of protein - is the slowest step, and therefore kinetically controls the overall process of an anaerobic digestion of biological sludge. A kinetic model was developed which could accurately describe digester performance and predict effluent quality.

  5. Chemical kinetic modeling of component mixtures relevant to gasoline

    SciTech Connect (OSTI)

    Mehl, M; Curran, H J; Pitz, W J; Dooley, S; Westbrook, C K

    2008-05-29

    Detailed kinetic models of pyrolysis and combustion of hydrocarbon fuels are nowadays widely used in the design of internal combustion engines and these models are effectively applied to help meet the increasingly stringent environmental and energetic standards. In previous studies by the combustion community, such models not only contributed to the understanding of pure component combustion, but also provided a deeper insight into the combustion behavior of complex mixtures. One of the major challenges in this field is now the definition and the development of appropriate surrogate models able to mimic the actual features of real fuels. Real fuels are complex mixtures of thousands of hydrocarbon compounds including linear and branched paraffins, naphthenes, olefins and aromatics. Their behavior can be effectively reproduced by simpler fuel surrogates containing a limited number of components. Aside the most commonly used surrogates containing iso-octane and n-heptane only, the so called Primary Reference Fuels (PRF), new mixtures have recently been suggested to extend the reference components in surrogate mixtures to also include alkenes and aromatics. It is generally agreed that, including representative species for all the main classes of hydrocarbons which can be found in real fuels, it is possible to reproduce very effectively in a wide range of operating conditions not just the auto-ignition propensity of gasoline or Diesel fuels, but also their physical properties and their combustion residuals [1]. In this work, the combustion behavior of several components relevant to gasoline surrogate formulation is computationally examined. The attention is focused on the autoignition of iso-octane, hexene and their mixtures. Some important issues relevant to the experimental and modeling investigation of such fuels are discussed with the help of rapid compression machine data and calculations. Following the model validation, the behavior of mixtures is discussed on the basis of computational results.

  6. Singularities of Generalized Parton Distributions

    SciTech Connect (OSTI)

    Anatoly Radyushkin

    2012-05-14

    The basic ideas of the theory of Generalized Parton Distributions (GPDs) are reviewed. Recent developments in the study of singularities of GPDs are discussed.

  7. General Biodiesel | Open Energy Information

    Open Energy Info (EERE)

    Biodiesel Jump to: navigation, search Name: General Biodiesel Address: 4034 West Marginal Way Place: Seattle, Washington Zip: 98106 Region: Pacific Northwest Area Sector: Biofuels...

  8. General Atomics | Open Energy Information

    Open Energy Info (EERE)

    Product: General Atomics offers research, development and consulting services to the nuclear industry, including nuclear energy production, manufacturing, defense and related...

  9. Focusing, in-chamber spectrometer triplet for high resolution measurements on the Sandia Z facility

    SciTech Connect (OSTI)

    Wenger, D. F.; Sinars, D. B.; Rochau, G. A.; Bailey, J. E.; Porter, J. L.; Faenov, A. Ya.; Pikuz, T. A.; Pikuz, S. A.

    2006-10-15

    An early prototype of a focusing spectrometer with one-dimensional (1D) spatial resolution (FSSR) instrument was previously developed for use in the vacuum chamber of the Sandia Z facility [Sinars et al., J. Quant. Spectrosc. Radiat. Transf. 99, 595 (2006)]. This instrument used a single, spherically bent crystal to measure time-integrated Ar spectra from 0.295-0.378 nm with {lambda}/{delta}{lambda}>2000 and a 1D axial spatial resolution of {approx}50 {mu}m. We present the design of a final version of this instrument that improves the shielding, can be aligned more accurately, and uses three crystals instead of one. The last change enables coverage of multiple spectral ranges if different crystals are used, or multiple times if identical crystals and time-gated detectors are used. We also present results from initial prototyping tests on the Z facility using two crystals in a time-integrated mode.

  10. Cryogenic argon ionization chamber detector for analysis of radioactive noble gases. Master's thesis

    SciTech Connect (OSTI)

    Berggren, S.R.

    1982-03-01

    Two ionization chamber detectors, using liquid or solid argon as their medium were designed, constructed and tested as an improved means of analyzing quantitatively xenon 131m and xenon 133. Problems with the first detector, including vibrational noise and inadequate temperature control, limited its use to studies using solid argon. In the second design, many operating problems of the first detector were corrected. Properties of the detectors were studied using external gamma sources and xenon 131m dispersed inside the detector medium. The xenon sample and argon were purified and cryogenically pumped into the detector for spectral analysis. Both the purity of the argon and bias voltages affected resolution by changing the trapping distance of the electrons in the medium. Lower temperatures increased detection efficiency by condensing more of the sample into the cell. No clearly recognizable energy peak could be found in spectra from external or internal sources.

  11. Environmental chamber measurements of mercury flux from coal utilization by-products

    SciTech Connect (OSTI)

    Pekney, Natalie J.; Martello, Donald; Schroeder, Karl; Granite, Evan

    2009-05-01

    An environmental chamber was constructed to measure the mercury flux from coal utilization by-product (CUB) samples. Samples of fly ash, FGD gypsum, and wallboard made from FGD gypsum were tested under both dark and illuminated conditions with or without the addition of water to the sample. Mercury releases varied widely, with 7- day experiment averages ranging from -6.8 to 73 ng/m(2) h for the fly ash samples and -5.2 to 335 ng/m(2) h for the FGD/wallboard samples. Initial mercury content, fly ash type, and light exposure had no observable consistent effects on the mercury flux. For the fly ash samples, the effect of a mercury control technology was to decrease the emission. For three of the four pairs of FGD gypsum and wallboard samples, the wallboard sample released less (or absorbed more) mercury than the gypsum.

  12. Environmental chamber measurements of mercury flux from coal utilization by-products

    SciTech Connect (OSTI)

    Pekney, N.J.; Martello, D.V.; Schroeder, K.T.; Granite, E.J.

    2009-05-01

    An environmental chamber was constructed to measure the mercury flux from coal utilization by-product (CUB) samples. Samples of fly ash, FGD gypsum, and wallboard made from FGD gypsum were tested under both dark and illuminated conditions with or without the addition of water to the sample. Mercury releases varied widely, with 7-day experiment averages ranging from -6.8 to 73 ng/m2 h for the fly ash samples and -5.2 to 335 ng/m2 h for the FGD/wallboard samples. Initial mercury content, fly ash type, and light exposure had no observable consistent effects on the mercury flux. For the fly ash samples, the effect of a mercury control technology was to decrease the emission. For three of the four pairs of FGD gypsum and wallboard samples, the wallboard sample released less (or absorbed more) mercury than the gypsum.

  13. Silicon nitride swirl lower-chamber for high power turbocharged diesel engines

    SciTech Connect (OSTI)

    Kamiya, S.; Murachi, M.; Kawamoto, H.; Kato, S.; Kawakami, S.; Suzuki, Y.

    1985-01-01

    This paper describes application of sintered silicon nitride to the swirl lower-chamber in order to improve performance of turbocharged diesel engines. Various stress analyses by finite element method and stress measurements have been applied to determine the design specifications for the component, which compromise brittleness of ceramic materials. Material development was conducted to evaluate strength, fracture toughness, and thermal properties for the sintered bodies. Ceramic injection molding has been employed to fabricate components with large quantities. In the present work. Quality assurance for the components can be made by reliability evaluation methods as well as non-destructive and stress loading inspections. It is found that the engine performance with ceramic component has been increased in the power out put of 9ps as compared to that of conventional engines.

  14. Microbial Community Analysis of a Single Chamber Microbial Fuel Cell Using Potato Wastewater

    SciTech Connect (OSTI)

    Zhen Li; Rishika Haynes; Eugene Sato; Malcolm Shields; Yoshiko Fujita; Chikashi Sato

    2014-04-01

    Microbial fuel cells (MFCs) convert chemical energy to electrical energy via bioelectrochemical reactions mediated by microorganisms. We investigated the diversity of the microbial community in an air cathode single chamber MFC that utilized potato-process wastewater as substrate. Terminal Restriction Fragment Length Polymorphism (T-RFLP) results indicated that the bacterial communities on the anode, cathode, control electrode, and MFC bulk fluid were similar, but differed dramatically from that of the anaerobic domestic sludge and potato wastewater inoculum. The 16S rDNA sequencing results showed that microbial species detected on the anode were predominantly within the phyla of Proteobacteria, Firmicutes, and Bacteroidetes. Fluorescent microscopy results indicated that there was a clear enhancement of biofilm formation on the anode. Results of this study could help improve understanding of the complexity of microbial communities and optimize the microbial composition for generating electricity by MFCs that utilize potato wastewater.

  15. Zero kinetic energy photoelectron spectroscopy of triphenylene

    SciTech Connect (OSTI)

    Harthcock, Colin; Zhang, Jie; Kong, Wei

    2014-06-28

    We report vibrational information of both the first electronically excited state and the ground cationic state of jet-cooled triphenylene via the techniques of resonantly enhanced multiphoton ionization (REMPI) and zero kinetic energy (ZEKE) photoelectron spectroscopy. The first excited electronic state S{sub 1} of the neutral molecule is of A{sub 1}? symmetry and is therefore electric dipole forbidden in the D{sub 3h} group. Consequently, there are no observable Franck-Condon allowed totally symmetric a{sub 1}? vibrational bands in the REMPI spectrum. All observed vibrational transitions are due to Herzberg-Teller vibronic coupling to the E? third electronically excited state S{sub 3}. The assignment of all vibrational bands as e? symmetry is based on comparisons with calculations using the time dependent density functional theory and spectroscopic simulations. When an electron is eliminated, the molecular frame undergoes Jahn-Teller distortion, lowering the point group to C{sub 2v} and resulting in two nearly degenerate electronic states of A{sub 2} and B{sub 1} symmetry. Here we follow a crude treatment by assuming that all e? vibrational modes resolve into b{sub 2} and a{sub 1} modes in the C{sub 2v} molecular frame. Some observed ZEKE transitions are tentatively assigned, and the adiabatic ionization threshold is determined to be 63?365 7 cm{sup ?1}. The observed ZEKE spectra contain a consistent pattern, with a cluster of transitions centered near the same vibrational level of the cation as that of the intermediate state, roughly consistent with the propensity rule. However, complete assignment of the detailed vibrational structure due to Jahn-Teller coupling requires much more extensive calculations, which will be performed in the future.

  16. Pressure Dependent Decomposition Kinetics of the Energetic Material...

    Office of Scientific and Technical Information (OSTI)

    Kinetics of the Energetic Material HMX up to 3.6 GPa The effect of pressure on the thermal decomposition rate of the energetic material HMX was studied. HMX was...

  17. Diffusion In Confinement: Kinetic Simulations of Self- and

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Collective-Diffusion Behavior of Adsorbed Gases | Center for Gas SeparationsRelevant to Clean Energy Technologies | Blandine Jerome Diffusion In Confinement: Kinetic Simulations of Self- and Collective-Diffusion Behavior of Adsorbed Gases

  18. Benchmark Reaction Mechanisms and Kinetics for Lean NOx Traps...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. PDF icon acep01larson.pdf More Documents & Publications Development of Chemical Kinetic Models for Lean NOx ...

  19. Elucidating Hydrogen Oxidation/Evolution Kinetics in Base and...

    Office of Scientific and Technical Information (OSTI)

    Elucidating Hydrogen OxidationEvolution Kinetics in Base and Acid by Enhanced Activities at the Optimized Pt Shell Thickness on the Ru Core Citation Details In-Document Search...

  20. The kinetics of the [omega] to [alpha] phase transformation in...

    Office of Scientific and Technical Information (OSTI)

    The kinetics of the omega to alpha phase transformation in Zr, Ti: Analysis of data from shock-recovered samples and atomistic simulations Citation Details In-Document Search ...

  1. Portable mass spectrometer with one or more mechanically adjustable electrostatic sectors and a mechanically adjustable magnetic sector all mounted in a vacuum chamber

    DOE Patents [OSTI]

    Andresen, Brian D. (Livermore, CA); Eckels, Joel D. (Livermore, CA); Kimmons, James F. (Manteca, CA); Martin, Walter H. (Byron, CA); Myers, David W. (Livermore, CA); Keville, Robert F. (Acampo, CA)

    1992-01-01

    A portable mass spectrometer is described having one or more electrostatic focusing sectors and a magnetic focusing sector, all of which are positioned inside a vacuum chamber, and all of which may be adjusted via adjustment means accessible from outside the vacuum chamber. Mounting of the magnetic sector entirely within the vacuum chamber permits smaller magnets to be used, thus permitting reductions in both weight and bulk.

  2. Portable mass spectrometer with one or more mechanically adjustable electrostatic sectors and a mechanically adjustable magnetic sector all mounted in a vacuum chamber

    DOE Patents [OSTI]

    Andresen, B.D.; Eckels, J.D.; Kimmons, J.F.; Martin, W.H.; Myers, D.W.; Keville, R.F.

    1992-10-06

    A portable mass spectrometer is described having one or more electrostatic focusing sectors and a magnetic focusing sector, all of which are positioned inside a vacuum chamber, and all of which may be adjusted via adjustment means accessible from outside the vacuum chamber. Mounting of the magnetic sector entirely within the vacuum chamber permits smaller magnets to be used, thus permitting reductions in both weight and bulk. 13 figs.

  3. Moisture desorption rates from TATB-formulations: experiments and kinetic

    Office of Scientific and Technical Information (OSTI)

    models (Journal Article) | SciTech Connect Moisture desorption rates from TATB-formulations: experiments and kinetic models Citation Details In-Document Search Title: Moisture desorption rates from TATB-formulations: experiments and kinetic models Authors: Glascoe, E A ; Dinh, L N ; Small, W ; Overturf, G E Publication Date: 2012-01-19 OSTI Identifier: 1093909 Report Number(s): LLNL-JRNL-528991 DOE Contract Number: W-7405-ENG-48 Resource Type: Journal Article Resource Relation: Journal Name:

  4. Kinetic Simulations of Particle Acceleration at Shocks (Conference) |

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect Kinetic Simulations of Particle Acceleration at Shocks Citation Details In-Document Search Title: Kinetic Simulations of Particle Acceleration at Shocks Collisionless shocks are mediated by collective electromagnetic interactions and are sources of non-thermal particles and emission. The full particle-in-cell approach and a hybrid approach are sketched, simulations of collisionless shocks are shown using a multicolor presentation. Results for SN 1006, a case involving ion

  5. Microfluidics: Kinetics of Hybridized DNA With Fluid Flow Variations.

    Office of Scientific and Technical Information (OSTI)

    (Conference) | SciTech Connect Microfluidics: Kinetics of Hybridized DNA With Fluid Flow Variations. Citation Details In-Document Search Title: Microfluidics: Kinetics of Hybridized DNA With Fluid Flow Variations. Abstract not provided. Authors: Sparks, Elizabeth Schares ; Manginell, Ronald Paul Publication Date: 2011-10-01 OSTI Identifier: 1106575 Report Number(s): SAND2011-7607C 464923 DOE Contract Number: AC04-94AL85000 Resource Type: Conference Resource Relation: Conference: MSEC 105

  6. Improving Combustion Software to Solve Detailed Chemical Kinetics for HECC

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    | Department of Energy Combustion Software to Solve Detailed Chemical Kinetics for HECC Improving Combustion Software to Solve Detailed Chemical Kinetics for HECC 2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon ace076_mcnenly_2012_o.pdf More Documents & Publications Vehicle Technologies Office Merit Review 2014: Improved Solvers for Advanced Engine Combustion Simulation Improved Solvers for Advanced Engine

  7. Transport Phenomena and Interfacial Kinetics in Planar Microfluidic

    Office of Scientific and Technical Information (OSTI)

    Membraneless Fuel Cells (Technical Report) | SciTech Connect Transport Phenomena and Interfacial Kinetics in Planar Microfluidic Membraneless Fuel Cells Citation Details In-Document Search Title: Transport Phenomena and Interfacial Kinetics in Planar Microfluidic Membraneless Fuel Cells Our work is focused on membraneless laminar flow fuel cells, an unconventional fuel cell technology, intended to create a system that not only avoids most typical fuel cell drawbacks, but also achieves the

  8. Ultrafast kinetics subsequent to shock in an unreacted, oxygen balanced

    Office of Scientific and Technical Information (OSTI)

    mixture of nitromethane and hydrogen peroxide (Conference) | SciTech Connect kinetics subsequent to shock in an unreacted, oxygen balanced mixture of nitromethane and hydrogen peroxide Citation Details In-Document Search Title: Ultrafast kinetics subsequent to shock in an unreacted, oxygen balanced mixture of nitromethane and hydrogen peroxide Authors: Armstrong, M R ; Zaug, J M ; Grant, C D ; Crowhurst, J C ; Bastea, S Publication Date: 2014-06-24 OSTI Identifier: 1149544 Report Number(s):

  9. Evaluation of Thermal Evolution Profiles and Estimation of Kinetic

    Office of Scientific and Technical Information (OSTI)

    Parameters for Pyrolysis of Coal/Corn Stover Blends Using Thermogravimetric Analysis (Journal Article) | SciTech Connect Journal Article: Evaluation of Thermal Evolution Profiles and Estimation of Kinetic Parameters for Pyrolysis of Coal/Corn Stover Blends Using Thermogravimetric Analysis Citation Details In-Document Search Title: Evaluation of Thermal Evolution Profiles and Estimation of Kinetic Parameters for Pyrolysis of Coal/Corn Stover Blends Using Thermogravimetric Analysis Authors:

  10. Ultrafast kinetics subsequent to shock in an unreacted, oxygen balanced

    Office of Scientific and Technical Information (OSTI)

    mixture of nitromethane and hydrogen peroxide (Conference) | SciTech Connect kinetics subsequent to shock in an unreacted, oxygen balanced mixture of nitromethane and hydrogen peroxide Citation Details In-Document Search Title: Ultrafast kinetics subsequent to shock in an unreacted, oxygen balanced mixture of nitromethane and hydrogen peroxide × You are accessing a document from the Department of Energy's (DOE) SciTech Connect. This site is a product of DOE's Office of Scientific and

  11. Microscale Electrode Design Using Coupled Kinetic, Thermal and Mechanical

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Modeling | Department of Energy 09 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. PDF icon es_17_sastry.pdf More Documents & Publications Modeling-Thermo-electrochemistry, Capacity Degradation and Mechanics with SEI Layer Coupled Kinetic, Thermal, and Mechanical Modeling of FIB Micro-machined Electrodes Intercalation Kinetics and Ion Mobility in Electrode Materials for Advanced Lithium Ion

  12. Transport Phenomena and Interfacial Kinetics in Planar Microfluidic

    Office of Scientific and Technical Information (OSTI)

    Membraneless Fuel Cells (Technical Report) | SciTech Connect SciTech Connect Search Results Technical Report: Transport Phenomena and Interfacial Kinetics in Planar Microfluidic Membraneless Fuel Cells Citation Details In-Document Search Title: Transport Phenomena and Interfacial Kinetics in Planar Microfluidic Membraneless Fuel Cells Our work is focused on membraneless laminar flow fuel cells, an unconventional fuel cell technology, intended to create a system that not only avoids most

  13. Ultrafast kinetics subsequent to shock in an unreacted, oxygen balanced

    Office of Scientific and Technical Information (OSTI)

    mixture of nitromethane and hydrogen peroxide (Conference) | SciTech Connect kinetics subsequent to shock in an unreacted, oxygen balanced mixture of nitromethane and hydrogen peroxide Citation Details In-Document Search Title: Ultrafast kinetics subsequent to shock in an unreacted, oxygen balanced mixture of nitromethane and hydrogen peroxide Authors: Armstrong, M R ; Zaug, J M ; Grant, C D ; Crowhurst, J C ; Bastea, S Publication Date: 2014-06-24 OSTI Identifier: 1149544 Report Number(s):

  14. Point kinetics calculations with fully coupled thermal fluids reactivity feedback

    SciTech Connect (OSTI)

    Zhang, H.; Zou, L.; Andrs, D.; Zhao, H.; Martineau, R.

    2013-07-01

    The point kinetics model has been widely used in the analysis of the transient behavior of a nuclear reactor. In the traditional nuclear reactor system safety analysis codes such as RELAP5, the reactivity feedback effects are calculated in a loosely coupled fashion through operator splitting approach. This paper discusses the point kinetics calculations with the fully coupled thermal fluids and fuel temperature feedback implemented into the RELAP-7 code currently being developed with the MOOSE framework. (authors)

  15. Kinetics of spin relaxation in quantum wires and channels: Boundary spin echo and formation of a persistent spin helix

    SciTech Connect (OSTI)

    Slipko, Valeriy A.; Pershin, Yuriy V.

    2011-10-15

    In this paper we use a spin kinetic equation to study spin-polarization dynamics in one-dimensional (1D) wires and 2D channels. The spin kinetic equation is valid in both diffusive and ballistic spin transport regimes and therefore is more general than the usual spin drift-diffusion equations. In particular, we demonstrate that in infinite 1D wires with Rashba spin-orbit interaction the exponential spin-relaxation decay can be modulated by an oscillating function. In the case of spin relaxation in finite length 1D wires, it is shown that an initially homogeneous spin polarization spontaneously transforms into a persistent spin helix. We find that a propagating spin-polarization profile reflects from a system boundary and returns back to its initial position similarly to the reflectance of sound waves from an obstacle. The Green's function of the spin kinetic equation is derived for both finite and infinite 1D systems. Moreover, we demonstrate explicitly that the spin relaxation in specifically oriented 2D channels with Rashba and Dresselhaus spin-orbit interactions of equal strength occurs similarly to that in 1D wires of finite length. Finally, a simple transformation mapping 1D spin kinetic equation into the Klein-Gordon equation with an imaginary mass is found thus establishing an interesting connection between semiconductor spintronics and relativistic quantum mechanics.

  16. ROLES OF THE KINETIC AND DYNAMIC MECHANISMS IN THE L{sub p} -E{sub p} RELATION

    SciTech Connect (OSTI)

    Qin, Yi-Ping; Chen, Zhi-Fu

    2013-04-10

    The L{sub p} -E{sub p} relation is a well-known relation in gamma-ray bursts (GRBs). Its implication remains unclear. We propose to investigate the underlying mechanisms of this relation by considering the corresponding kinetic and dynamic mechanisms separately. In this way, one can tell how much the kinetic or dynamic mechanism contributes to the index of the relationship. Our analysis gives rise to several conclusions. (1) The index of the kinetic effect in the L{sub p} -E{sub p} relation can simply be derived from the theory of special relativity, which is generally larger than 2, depending on the situation concerned. (2) The index of the dynamic effect in the relation can be deduced from observation once a model of jets is adopted. According to current GRB data, we find that the dynamic effect alone tends to give rise to an anti-correlation between L{sub p} and E{sub p} ; in terms of statistics, the dynamic effect is obviously smaller than the kinetic effect; in the situation of jets with moving discrete radio clouds that move directly toward the observer, the index of the dynamic effect is currently constrained within (- 1.6, -1), while in other situations of jets, the constraints are different; both internal and external shocks can account for the current data.

  17. SFS Exhibit A General Conditions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1, 4/9/13) Exhibit A General Conditions Page 1 of 29 EXHIBIT "A" GENERAL CONDITIONS TABLE OF CONTENTS GC Title Page GC-1 DEFINITIONS (Aug 2012) .......................................................................................................... 3 GC-2A AUTHORIZED REPRESENTATIVES, COMMUNICATIONS AND NOTICES (Jan 2010) ........................................................................................................................................... 3 GC-3 INDEPENDENT

  18. SFS Exhibit A General Conditions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2, 6/14/13) Exhibit A General Conditions Page 1 of 16 EXHIBIT "A" GENERAL CONDITIONS TABLE OF CONTENTS GC Title Page GC-1 DEFINITIONS (Aug 2012) .......................................................................................................... 3 GC-2A AUTHORIZED REPRESENTATIVES, COMMUNICATIONS AND NOTICES (Jan 2010) ........................................................................................................................................... 3 GC-3 INDEPENDENT

  19. CPFFS Exhibit A General Conditions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1, 4/9/13) Exhibit A General Conditions Page 1 of 33 EXHIBIT "A" GENERAL CONDITIONS TABLE OF CONTENTS GC Title Page GC-1 DEFINITIONS (Aug 2012) .......................................................................................................... 3 GC-2A AUTHORIZED REPRESENTATIVES, COMMUNICATIONS AND NOTICES (Jan 2010) ........................................................................................................................................... 3 GC-3 INDEPENDENT

  20. CPFFS Exhibit A General Conditions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2, 6/14/13) Exhibit A General Conditions Page 1 of 20 EXHIBIT "A" GENERAL CONDITIONS TABLE OF CONTENTS GC Title Page GC-1 DEFINITIONS (Aug 2012) .......................................................................................................... 3 GC-2A AUTHORIZED REPRESENTATIVES, COMMUNICATIONS AND NOTICES (Jan 2010) ........................................................................................................................................... 3 GC-3 INDEPENDENT

  1. CPFFS Exhibit A General Conditions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    5, 3/6/15) Exhibit A General Conditions Page 1 of 29 EXHIBIT "A" GENERAL CONDITIONS TABLE OF CONTENTS GC Title Page GC-1 DEFINITIONS (Aug 2014) .......................................................................................................... 3 GC-2A AUTHORIZED REPRESENTATIVES, COMMUNICATIONS AND NOTICES (Jan 2010) ........................................................................................................................................... 3 GC-3 INDEPENDENT

  2. AES Exhibit A General Conditions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1, 4/9/13) Exhibit A General Conditions Page 1 of 31 EXHIBIT "A" GENERAL CONDITIONS TABLE OF CONTENTS GC Title Page GC-1 DEFINITIONS (Aug 2012) .......................................................................................................... 3 GC-2A AUTHORIZED REPRESENTATIVES, COMMUNICATIONS AND NOTICES (Jan 2010) ........................................................................................................................................... 3 GC-3 INDEPENDENT

  3. AES Exhibit A General Conditions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1, 4/9/13) Exhibit A General Conditions Page 1 of 6 EXHIBIT "A" GENERAL CONDITIONS TABLE OF CONTENTS GC Title Page GC-1C DEFINITIONS (Jun 2010) ........................................................................................................... 2 GC-6C ORDER OF PRECEDENCE (Mar 2012) .................................................................................... 2 GC-8B COMPLIANCE WITH LAWS, RULES, REGULATIONS AND STANDARDS (Jun 2010) .......... 2 GC-11 NEW MEXICO GROSS

  4. AES Exhibit A General Conditions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    4, 3/6/15) Exhibit A General Conditions Page 1 of 21 EXHIBIT "A" GENERAL CONDITIONS TABLE OF CONTENTS GC Title Page GC-1 DEFINITIONS (Aug 2012) .......................................................................................................... 3 GC-2A AUTHORIZED REPRESENTATIVES, COMMUNICATIONS AND NOTICES (Jan 2010) ........................................................................................................................................... 3 GC-3 INDEPENDENT

  5. AES Exhibit A General Conditions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3, 12/15/14) Exhibit A General Conditions Page 1 of 20 EXHIBIT "A" GENERAL CONDITIONS TABLE OF CONTENTS GC Title Page GC-1 DEFINITIONS (Aug 2012) .......................................................................................................... 3 GC-2A AUTHORIZED REPRESENTATIVES, COMMUNICATIONS AND NOTICES (Jan 2010) ........................................................................................................................................... 3 GC-3 INDEPENDENT

  6. AES Exhibit A General Conditions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2, 3/6/15) Exhibit A General Conditions Page 1 of 8 EXHIBIT "A" GENERAL CONDITIONS TABLE OF CONTENTS GC Title Page GC-1C DEFINITIONS (Jun 2010) ........................................................................................................... 2 GC-6C ORDER OF PRECEDENCE (Mar 2012) .................................................................................... 2 GC-8B COMPLIANCE WITH LAWS, RULES, REGULATIONS AND STANDARDS (Jun 2010) .......... 2 GC-11 NEW MEXICO GROSS

  7. EFS Exhibit A General Conditions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1, 4/9/13) Exhibit A General Conditions Page 1 of 39 EXHIBIT "A" GENERAL CONDITIONS TABLE OF CONTENTS GC Title Page GC-1 DEFINITIONS (Aug 2012) .......................................................................................................... 3 GC-2 AUTHORIZED REPRESENTATIVES, COMMUNICATIONS AND NOTICES (Apr 2013) ........................................................................................................................................... 3 GC-3 INDEPENDENT

  8. EFS Exhibit A General Conditions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2, 6/14/13) Exhibit A General Conditions Page 1 of 26 EXHIBIT "A" GENERAL CONDITIONS TABLE OF CONTENTS GC Title Page GC-1 DEFINITIONS (Aug 2012) .......................................................................................................... 3 GC-2 AUTHORIZED REPRESENTATIVES, COMMUNICATIONS AND NOTICES (Apr 2013) ........................................................................................................................................... 3 GC-3 INDEPENDENT

  9. EFS Exhibit A General Conditions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    3, 12/15/14) Exhibit A General Conditions Page 1 of 29 EXHIBIT "A" GENERAL CONDITIONS TABLE OF CONTENTS GC Title Page GC-1 DEFINITIONS (Aug 2012) .......................................................................................................... 3 GC-2 AUTHORIZED REPRESENTATIVES, COMMUNICATIONS AND NOTICES (Apr 2013) ........................................................................................................................................... 3 GC-3 INDEPENDENT

  10. LFS Exhibit A General Conditions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1, 4/9/13) Exhibit A General Conditions Page 1 of 31 EXHIBIT "A" GENERAL CONDITIONS TABLE OF CONTENTS GC Title Page GC-1 DEFINITIONS (Aug 2012) .......................................................................................................... 3 GC-2A AUTHORIZED REPRESENTATIVES, COMMUNICATIONS AND NOTICES (Jan 2010) ........................................................................................................................................... 3 GC-3 INDEPENDENT

  11. LFS Exhibit A General Conditions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2, 6/14/13) Exhibit A General Conditions Page 1 of 19 EXHIBIT "A" GENERAL CONDITIONS TABLE OF CONTENTS GC Title Page GC-1 DEFINITIONS (Aug 2012) .......................................................................................................... 3 GC-2A AUTHORIZED REPRESENTATIVES, COMMUNICATIONS AND NOTICES (Jan 2010) ........................................................................................................................................... 3 GC-3 INDEPENDENT

  12. LFS Exhibit A General Conditions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    5, 3/6/15) Exhibit A General Conditions Page 1 of 22 EXHIBIT "A" GENERAL CONDITIONS TABLE OF CONTENTS GC Title Page GC-1 DEFINITIONS (Aug 2014) .......................................................................................................... 3 GC-2A AUTHORIZED REPRESENTATIVES, COMMUNICATIONS AND NOTICES (Jan 2010) ........................................................................................................................................... 3 GC-3 INDEPENDENT

  13. LFS Exhibit A General Conditions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    4, 9/26/14) Exhibit A General Conditions Page 1 of 22 EXHIBIT "A" GENERAL CONDITIONS TABLE OF CONTENTS GC Title Page GC-1 DEFINITIONS (Aug 2014) .......................................................................................................... 3 GC-2A AUTHORIZED REPRESENTATIVES, COMMUNICATIONS AND NOTICES (Jan 2010) ........................................................................................................................................... 3 GC-3 INDEPENDENT

  14. Peptide concentration alters intermediate species in amyloid ? fibrillation kinetics

    SciTech Connect (OSTI)

    Garvey, M., E-mail: megan.garvey@molbiotech.rwth-aachen.de [Max-Planck Research Unit for Enzymology of Protein Folding, Weinbergweg 22, 06120 Halle (Saale) (Germany); Morgado, I., E-mail: immorgado@ualg.pt [Max-Planck Research Unit for Enzymology of Protein Folding, Weinbergweg 22, 06120 Halle (Saale) (Germany)

    2013-04-12

    Highlights: ? A?(140) aggregation in vitro has been monitored at different concentrations. ? A?(140) fibrillation does not always follow conventional kinetic mechanisms. ? We demonstrate non-linear features in the kinetics of A?(140) fibril formation. ? At high A?(140) concentrations secondary processes dictate fibrillation speed. ? Intermediate species may play significant roles on final amyloid fibril development. -- Abstract: The kinetic mechanism of amyloid aggregation remains to be fully understood. Investigations into the species present in the different kinetic phases can assist our comprehension of amyloid diseases and further our understanding of the mechanism behind amyloid ? (A?) (140) peptide aggregation. Thioflavin T (ThT) fluorescence and transmission electron microscopy (TEM) have been used in combination to monitor A?(140) aggregation in vitro at both normal and higher than standard concentrations. The observed fibrillation behaviour deviates, in several respects, from standard concepts of the nucleationpolymerisation models and shows such features as concentration-dependent non-linear effects in the assembly mechanism. A?(140) fibrillation kinetics do not always follow conventional kinetic mechanisms and, specifically at high concentrations, intermediate structures become populated and secondary processes may further modify the fibrillation mechanism.

  15. Louisiana Title V General Permits

    SciTech Connect (OSTI)

    Boyer, B.E.; Neal, T.L.

    1995-12-31

    Title V of the Federal Clean Air Act Amendments of 1990 requires federal operating permits for all major sources of air pollution. In 1992, Title 40, Part 70 of the Code of Federal Regulations (40 CFR Part 70) codified the law s requirements. These federal regulations, entitled Operating Permit Program, define the minimum requirements for state administered operating permit programs. The intent of Title V is to put into one document all requirements of an operating permit. General Permits for oil and gas facilities may be preferred if the facility can comply with all permit requirements. If greater flexibility than allowed by the General Permit is required, then the facility should apply for an individual Title V permit. General Permits are designed to streamline the permitting process, shorten the time it takes to obtain approval for initial and modified permits. The advantages of the General Permit include reduced paperwork and greater consistency because the permits are standardized. There should be less uncertainty because permit requirements will be known at the time of application. Approval times for Initial and modified General Permits should be reduced. Lengthy public notice procedures (and possible hearings) will be required for only the initial approval of the General Permit and not for each applicant to the permit. A disadvantage of General Permits is reduced flexibility since the facility must comply with the requirements of a standardized permit.

  16. 2014 National Small Business Contracting Summit- US Women’s Chamber of Commerce & National Association of Small Business Contractors

    Broader source: Energy.gov [DOE]

    The National Association of Small Business Contractors and the U.S. Women's Chamber of Commerce present the 2014 National Small Business Federal Contracting Summit. The event will include sessions on securing a fair share of federal contracting, legal issues, trends and opportunities.

  17. General Electric | Open Energy Information

    Open Energy Info (EERE)

    General Electric Place: Fairfield, Connecticut Zip: 06828 Region: Northeast - NY NJ CT PA Area Year Founded: 1892 Website: www.ge.com Coordinates: 41.1758333, -73.2719444...

  18. A Concept for a Low Pressure Noble Gas Fill Intervention in the IFE Fusion Test Facility (FTF) Target Chamber

    SciTech Connect (OSTI)

    Gentile, C. A.; Blanchard, W. R.; Kozub, T. A.; Aristova, M.; McGahan, C.; Natta, S.; Pagdon, K.; Zelenty, J.

    2010-01-14

    An engineering evaluation has been initiated to investigate conceptual engineering methods for implementing a viable gas shield strategy in the Fusion Test Facility (FTF) target chamber. The employment of a low pressure noble gas in the target chamber to thermalize energetic helium ions prior to interaction with the wall could dramatically increase the useful life of the first wall in the FTF reactor1. For the purpose of providing flexibility, two target chamber configurations are addressed: a five meter radius sphere and a ten meter radius sphere. Experimental studies at Nike have indicated that a low pressure, ambient gas resident in the target chamber during laser pulsing does not appear to impair the ability of laser light from illuminating targets2. In addition, current investigations into delivering, maintaining, and processing low pressure gas appear to be viable with slight modification to current pumping and plasma exhaust processing technologies3,4. Employment of a gas fill solution for protecting the dry wall target chamber in the FTF may reduce, or possibly eliminate the need for other attenuating technologies designed for keeping He ions from implanting in first wall structures and components. The gas fill concept appears to provide an effective means of extending the life of the first wall while employing mostly commercial off the shelf (COTS) technologies. Although a gas fill configuration may provide a methodology for attenuating damage inflicted on chamber surfaces, issues associated with target injection need to be further analyzed to ensure that the gas fill concept is viable in the integrated FTF design5. In the proposed system, the ambient noble gas is heated via the energetic helium ions produced by target detonation. The gas is subsequently cooled by the chamber wall to approximately 800oC, removed from the chamber, and processed by the chamber gas processing system (CGPS). In an optimized scenario of the above stated concept, the chamber wall acts as the primary heat exchanger. During removal, gas is pumped through the laser ports by turbo molecular-drag pumps (TM-DP). For the purpose of reducing organic based lubricants and seals, a magnetically levitated TM-DP is being investigated with pump manufacturers. Currently, magnetically levitated turbo molecular pumps are commercially available. The pumps will be exposed to thermal loads and ionizing radiation (tritium, Ar-41, post detonation neutrons). Although the TM-DP's will be subjected to these various radiations, current designs for similar pumping devices have been hardened and have the ability of locating control electronics in remote radiation shielded enclosures4. The radiation hardened TM-DP's will be 5 required to operate with minimal maintenance for periods of up to 18 continuous months. As part of this initial investigation for developing a conceptual engineering strategy for a gas fill solution, commercial suppliers of low pressure gas pumping systems have been contacted and engaged in this evaluation. Current technology in the area of mechanical pumping systems indicates that the development of a robust pumping system to meet the requirements of the FTF gas fill concept is within the limits of COTS equipment3,4.

  19. The LANL atomic kinetics modeling effort and its application to W plasmas

    Office of Scientific and Technical Information (OSTI)

    (Conference) | SciTech Connect The LANL atomic kinetics modeling effort and its application to W plasmas Citation Details In-Document Search Title: The LANL atomic kinetics modeling effort and its application to W plasmas This is the work of the LANL group on atomic kinetics modelling. There are various levels of detail in the LANL suite of atomic physics codes: (1) Non-relativistic configuration average kinetics (nl{sup w}) + UTA spectra, (2) Relativistic configuration average kinetics

  20. General Renewable Energy Technology Resources | Department of...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    General Renewable Energy Technology Resources General Renewable Energy Technology Resources Below are general resources for Tribes on renewable energy technologies. Developing ...

  1. Reduction of combustion emissions using hydrogen peroxide in a pilot scale combustion chamber

    SciTech Connect (OSTI)

    Martinez, A.I.; Corredor, L.F.; Tamara, W.

    1997-12-31

    A hydrogen peroxide injection system was designed and installed in the stack of a 5,274 million J/hr industrial pilot plant scale combustion chamber using natural gas as fuel. The concentration of peroxide in the gas stream was precisely controlled by continuous injection using an electromagnetic dosage pump, the liquid 50% peroxide solution was finely dispersed into the gases by a water cooled custom designed delivery system with a spray nozzle at the tip. Residence times between 0.1 and 1.8 seconds and concentrations of H{sub 2}O{sub 2} between 280 ppm and 4,000 ppm were used during the test runs. CEMS for total hydrocarbons, carbon monoxide, nitrogen oxides, as well as an ultrasonic gas flow monitor were used to measure the effect of hydrogen peroxide in reducing the emissions of these pollutants. Destruction removal efficiencies between 25% and 100% were observed for hydrocarbons, and concentrations of CO, as well as NO{sub x}. were reduced about 50%. The results indicate that this labscale proved technology yields similar results in reducing combustion emissions in pilot applications, and also a reliable injection system has been developed and tested successfully.

  2. Performance of a Drift Chamber Candidate for a Cosmic Muon Tomography System

    SciTech Connect (OSTI)

    Anghel, V.; Jewett, C.; Jonkmans, G.; Thompson, M.; Armitage, J.; Botte, J.; Boudjemline, K.; Erlandson, A.; Oakham, G.; Bueno, J.; Bryman, D.; Liu, Z.; Charles, E.; Gallant, G.; Cousins, T.; Noel, S.; Drouin, P.-L.; Waller, D.; Stocki, T. J.

    2011-12-13

    In the last decade, many groups around the world have been exploring different ways to probe transport containers which may contain illicit Special Nuclear Materials such as uranium. The muon tomography technique has been proposed as a cost effective system with an acceptable accuracy. A group of Canadian institutions (see above), funded by Defence Research and Development Canada, is testing different technologies to track the cosmic muons. One candidate is the single wire Drift Chamber. With the capability of a 2D impact position measurement, two detectors will be placed above and two below the object to be probed. In order to achieve a good 3D image quality of the cargo content, a good angular resolution is required. The simulation showed that 1mrad was required implying the spatial resolution of the trackers must be in the range of 1 to 2 mm for 1 m separation. A tracking system using three prototypes has been built and tested. The spatial resolution obtained is 1.7 mm perpendicular to the wire and 3 mm along the wire.

  3. Kinetic extruder - a dry pulverized solid material pump

    DOE Patents [OSTI]

    Meyer, J. W.; Bonin, J. H.; Daniel, A. D. Jr.

    1983-03-15

    Method and apparatus are shown for the continuous feeding of pulverized material to a high pressure container. A rotor is located within the high pressure container. The pulverized material is fed from a feed hopper through a stationary feed pipe to a vented spin-up chamber to a plurality of two-stage sprues mounted in the rotor. Control nozzles downstream from the sprues meter the flow of coal through the sprues. 19 figs.

  4. Kinetic extruder - a dry pulverized solid material pump

    DOE Patents [OSTI]

    Meyer, John W. (Palo Alto, CA); Bonin, John H. (Sunnyvale, CA); Daniel, Jr., Arnold D. (Pleasanton, CA)

    1983-01-01

    Method and apparatus are shown for the continuous feeding of pulverized material to a high pressure container. A rotor is located within the high pressure container. The pulverized material is fed from a feed hopper through a stationary feed pipe to a vented spin-up chamber to a plurality of two-stage sprues mounted in the rotor. Control nozzles downstream from the sprues meter the flow of coal through the sprues.

  5. Kinetics of high-conversion hydrocracking of bitumen

    SciTech Connect (OSTI)

    Nagaishi, H.; Gray, M.R.; Chan, E.W.; Sanford, E.C.

    1995-12-31

    Residues are complex mixtures of thousands of components. This mixture will change during hydrocracking, so that high conversion may result in a residue material with different characteristics from the starting material. Our objective is to determine the kinetics of residue conversion and yields of distillates at high conversions, and to relate these observations to the underlying chemical reactions. Athabasca bitumen was reacted in a 1-L CSTR in a multipass operation. Product from the first pass was collected, then run through the reactor again and so on, giving kinetic data under conditions that simulated a multi-reactor or packed-bed operation. Experiments were run both with hydrocracking catalyst and without added catalyst. Products were analyzed by distillation, elemental analysis, NMR, and GPC. These data will be used to derive a kinetic model for hydrocracking of bitumen residue covering a wide range of conversion (from 30% to 95%+), based on the underlying chemistry.

  6. Kinetics of the carbon monoxide oxidation reaction under microwave heating

    SciTech Connect (OSTI)

    Perry, W.L.; Katz, J.D.; Rees, D.; Paffett, M.T. [Los Alamos National Lab., NM (United States); Datye, A. [Univ. of New Mexico, Albuquerque, NM (United States)

    1996-06-01

    915 MHz microwave heating has been used to drive the CO oxidation reaction over Pd/Al{sub 2}O{sub 3} with out significantly affecting the reaction kinetics. As compared to an identical conventionally heated system, the activation energy, pre-exponential factor, and reaction order with respect to CO were unchanged. Temperature was measured using a thermocouple extrapolation technique. Microwave-induced thermal gradients were found to play a significant role in kinetic observations. The authors chose the CO oxidation reaction over a supported metal catalyst because the reaction kinetics are well known, and because of the diverse dielectric properties of the various elements in the system: CO is a polar molecule, O{sub 2} and CO{sub 2} are non-polar, Al{sub 2}O{sub 3} is a dielectric, and Pt and Pd are conductors.

  7. Performance of non-conventional factorization approaches for neutron kinetics

    SciTech Connect (OSTI)

    Bulla, S.; Nervo, M.

    2013-07-01

    The use of factorization techniques provides a interesting option for the simulation of the time-dependent behavior of nuclear systems with a reduced computational effort. While point kinetics neglects all spatial and spectral effects, quasi-statics and multipoint kinetics allow to produce results with a higher accuracy for transients involving relevant modifications of the neutron distribution. However, in some conditions these methods can not work efficiently. In this paper, we discuss some possible alternative formulations for the factorization process for neutron kinetics, leading to mathematical models of reduced complications that can allow an accurate simulation of transients involving spatial and spectral effects. The performance of these innovative approaches are compared to standard techniques for some test cases, showing the benefits and shortcomings of the method proposed. (authors)

  8. Kinetic Alfvn wave turbulence and formation of localized structures

    SciTech Connect (OSTI)

    Sharma, R. P.; Modi, K. V.; Mechanical Engineering Department, Government Engineering College Valsad, Gujarat 396001

    2013-08-15

    This work presents non-linear interaction of magnetosonic wave with kinetic Alfvn wave for intermediate ?-plasma (m{sub e}/m{sub i}???1). A set of dimensionless equations have been developed for analysis by considering ponderomotive force due to pump kinetic Alfvn wave in the dynamics of magnetosonic wave. Stability analysis has been done to study modulational instability or linear growth rate. Further, numerical simulation has been carried out to study the nonlinear stage of instability and resulting power spectrum applicable to solar wind around 1 AU. Due to the nonlinearity, background density of magnetosonic wave gets modified which results in localization of kinetic Alfvn wave. From the obtained results, we observed that spectral index follows k{sup ?3.0}, consistent with observation received by Cluster spacecraft for the solar wind around 1 AU. The result shows the steepening of power spectrum which may be responsible for heating and acceleration of plasma particles in solar wind.

  9. Computer-Aided Construction of Chemical Kinetic Models

    SciTech Connect (OSTI)

    Green, William H.

    2014-12-31

    The combustion chemistry of even simple fuels can be extremely complex, involving hundreds or thousands of kinetically significant species. The most reasonable way to deal with this complexity is to use a computer not only to numerically solve the kinetic model, but also to construct the kinetic model in the first place. Because these large models contain so many numerical parameters (e.g. rate coefficients, thermochemistry) one never has sufficient data to uniquely determine them all experimentally. Instead one must work in predictive mode, using theoretical rather than experimental values for many of the numbers in the model, and as appropriate refining the most sensitive numbers through experiments. Predictive chemical kinetics is exactly what is needed for computer-aided design of combustion systems based on proposed alternative fuels, particularly for early assessment of the value and viability of proposed new fuels before those fuels are commercially available. This project was aimed at making accurate predictive chemical kinetics practical; this is a challenging goal which requires a range of science advances. The project spanned a wide range from quantum chemical calculations on individual molecules and elementary-step reactions, through the development of improved rate/thermo calculation procedures, the creation of algorithms and software for constructing and solving kinetic simulations, the invention of methods for model-reduction while maintaining error control, and finally comparisons with experiment. Many of the parameters in the models were derived from quantum chemistry calculations, and the models were compared with experimental data measured in our lab or in collaboration with others.

  10. GENERAL@ELECTtiIC COMPINY

    Office of Legacy Management (LM)

    GENERAL@ELECTtiIC COMPINY ~9013 ~APPROVAL NO. 143 Article II, Section 8(b) PICHLAND, WASHINGTON .~. "ANFORD ATOMlC PlOD"CTS O*Ert*,ION ,. u/S; Atomic Energy Comisaion Hailfbrd operations Office Richland, Washington Attention: Mr. J. E. Travis, Manager Gentlemen: EXTRUSION OF URANIUM DIOXIDE FOR GENERAL ~ED&'RIC - APED The Atoinic Power Equipment Depart!++ of ~the The uranium dioxide necess :Material License No. C-3351. for establishing the value'of the.material will be developed

  11. Generalized Comprehensive Mitigation Assessment Process (GCOMAP...

    Open Energy Info (EERE)

    Generalized Comprehensive Mitigation Assessment Process (GCOMAP) (Redirected from GCOMAP) Jump to: navigation, search Tool Summary LAUNCH TOOL Name: Generalized Comprehensive...

  12. Kinetics of silicide formation over a wide range of heating rates spanning six orders of magnitude

    SciTech Connect (OSTI)

    Molina-Ruiz, Manel; Lopeanda, Aitor F.; Gonzalez-Silveira, Marta; Garcia, Gemma; Clavaguera-Mora, Maria T. [Grup de Nanomaterials i Microsistemes, Departament de Fsica, Universitat Autnoma de Barcelona, 08193 Bellaterra (Spain); Peral, Inma [ALBA Synchrotron Light Facility, 08290 Cerdanyola del Valls (Spain); Rodrguez-Viejo, Javier, E-mail: javier.rodriguez@uab.cat [Grup de Nanomaterials i Microsistemes, Departament de Fsica, Universitat Autnoma de Barcelona, 08193 Bellaterra (Spain); MATGAS Research Centre, UAB Campus, 08193 Bellaterra (Spain)

    2014-07-07

    Kinetic processes involving intermediate phase formation are often assumed to follow an Arrhenius temperature dependence. This behavior is usually inferred from limited data over narrow temperature intervals, where the exponential dependence is generally fully satisfied. However, direct evidence over wide temperature intervals is experimentally challenging and data are scarce. Here, we report a study of silicide formation between a 12?nm film of palladium and 15?nm of amorphous silicon in a wide range of heating rates, spanning six orders of magnitude, from 0.1 to 10{sup 5?}K/s, or equivalently more than 300?K of variation in reaction temperature. The calorimetric traces exhibit several distinct exothermic events related to interdiffusion, nucleation of Pd{sub 2}Si, crystallization of amorphous silicon, and vertical growth of Pd{sub 2}Si. Interestingly, the thickness of the initial nucleation layer depends on the heating rate revealing enhanced mass diffusion at the fastest heating rates during the initial stages of the reaction. In spite of this, the formation of the silicide strictly follows an Arrhenius temperature dependence over the whole temperature interval explored. A kinetic model is used to fit the calorimetric data over the complete heating rate range. Calorimetry is complemented by structural analysis through transmission electron microscopy and both standard and in-situ synchrotron X-ray diffraction.

  13. Isobutane ignition delay time measurements at high pressure and detailed chemical kinetic simulations

    SciTech Connect (OSTI)

    Healy, D.; Curran, H.J.; Donato, N.S.; Aul, C.J.; Petersen, E.L.; Zinner, C.M.; Bourque, G.

    2010-08-15

    Rapid compression machine and shock-tube ignition experiments were performed for real fuel/air isobutane mixtures at equivalence ratios of 0.3, 0.5, 1, and 2. The wide range of experimental conditions included temperatures from 590 to 1567 K at pressures of approximately 1, 10, 20, and 30 atm. These data represent the most comprehensive set of experiments currently available for isobutane oxidation and further accentuate the complementary attributes of the two techniques toward high-pressure oxidation experiments over a wide range of temperatures. The experimental results were used to validate a detailed chemical kinetic model composed of 1328 reactions involving 230 species. This mechanism has been successfully used to simulate previously published ignition delay times as well. A thorough sensitivity analysis was performed to gain further insight to the chemical processes occurring at various conditions. Additionally, useful ignition delay time correlations were developed for temperatures greater than 1025 K. Comparisons are also made with available isobutane data from the literature, as well as with 100% n-butane and 50-50% n-butane-isobutane mixtures in air that were presented by the authors in recent studies. In general, the kinetic model shows excellent agreement with the data over the wide range of conditions of the present study. (author)

  14. Extension of the quantum-kinetic model to lunar and Mars return physics

    SciTech Connect (OSTI)

    Liechty, D. S.; Lewis, M. J.

    2014-02-15

    The ability to compute rarefied, ionized hypersonic flows is becoming more important as missions such as Earth reentry, landing high-mass payloads on Mars, and the exploration of the outer planets and their satellites are being considered. A recently introduced molecular-level chemistry model, the quantum-kinetic, or Q-K, model that predicts reaction rates for gases in thermal equilibrium and non-equilibrium using only kinetic theory and fundamental molecular properties, is extended in the current work to include electronic energy level transitions and reactions involving charged particles. Like the Q-K procedures for neutral species chemical reactions, these new models are phenomenological procedures that aim to reproduce the reaction/transition rates but do not necessarily capture the exact physics. These engineering models are necessarily efficient due to the requirement to compute billions of simulated collisions in direct simulation Monte Carlo (DSMC) simulations. The new models are shown to generally agree within the spread of reported transition and reaction rates from the literature for near equilibrium conditions.

  15. A coke oven model including thermal decomposition kinetics of tar

    SciTech Connect (OSTI)

    Munekane, Fuminori; Yamaguchi, Yukio; Tanioka, Seiichi

    1997-12-31

    A new one-dimensional coke oven model has been developed for simulating the amount and the characteristics of by-products such as tar and gas as well as coke. This model consists of both heat transfer and chemical kinetics including thermal decomposition of coal and tar. The chemical kinetics constants are obtained by estimation based on the results of experiments conducted to investigate the thermal decomposition of both coal and tar. The calculation results using the new model are in good agreement with experimental ones.

  16. Spectroscopy and kinetics of combustion gases at high temperatures

    SciTech Connect (OSTI)

    Hanson, R.K.; Bowman, C.T.

    1993-12-01

    This program involves two complementary activities: (1) development and application of cw ring dye laser absorption methods for sensitive detection of radical species and measurement of fundamental spectroscopic parameters at high temperatures; and (2) shock tube studies of reaction kinetics relevant to combustion. Species currently under investigation in the spectroscopic portion of the research include NO and CH{sub 3}; this has necessitated the continued operated at wavelengths in the range 210-230 nm. Shock tube studies of reaction kinetics currently are focussed on reactions involving CH{sub 3} radicals.

  17. Kinetic studies of protein L aggregation and disaggregation (Journal

    Office of Scientific and Technical Information (OSTI)

    Article) | SciTech Connect Kinetic studies of protein L aggregation and disaggregation Citation Details In-Document Search Title: Kinetic studies of protein L aggregation and disaggregation No abstract prepared. Authors: Cellmer, Troy ; Douma, Rutger ; Huebner, Ansgar ; Prausnitz, John ; Blanch, Harvey Publication Date: 2006-09-30 OSTI Identifier: 927250 Report Number(s): LBNL--62337 Journal ID: ISSN 0301-4622; BICIAZ; R&D Project: 402201; BnR: KC0302040; TRN: US200811%%72 DOE Contract

  18. Recent advances in the kinetics of oxygen reduction

    SciTech Connect (OSTI)

    Adzic, R.

    1996-07-01

    Oxygen reduction is considered an important electrocatalytic reaction; the most notable need remains improvement of the catalytic activity of existing metal electrocatalysts and development of new ones. A review is given of new advances in the understanding of reaction kinetics and improvements of the electrocatalytic properties of some surfaces, with focus on recent studies of relationship of the surface properties to its activity and reaction kinetics. The urgent need is to improve catalytic activity of Pt and synthesize new, possibly non- noble metal catalysts. New experimental techniques for obtaining new level of information include various {ital in situ} spectroscopies and scanning probes, some involving synchrotron radiation. 138 refs, 18 figs, 2 tabs.

  19. Historical Information H.1 General

    Office of Legacy Management (LM)

    1 . . General Book 1 Effects Evaluation- for Project Rulison, June 1969 DISCLAIMER Portions of this document may be illegible in electronic image products. Images are produced from the best available original document. . . . . . . . . . . - ,--- ..-... . . . 0 . , . , ~ , . . . . . . . . . . . . . . ... . . I . . . . . . . . . . . . . . . . . . . L . < - ....:.-. . . . . . . . . . . . . . . . . . - , , - . d - i , . .. * :=.:. 5 . . .:. : - . . . . . . : -.. .. ' . . - - .- - : . 7 : P . f l

  20. General purpose programmable accelerator board

    DOE Patents [OSTI]

    Robertson, Perry J.; Witzke, Edward L.

    2001-01-01

    A general purpose accelerator board and acceleration method comprising use of: one or more programmable logic devices; a plurality of memory blocks; bus interface for communicating data between the memory blocks and devices external to the board; and dynamic programming capabilities for providing logic to the programmable logic device to be executed on data in the memory blocks.

  1. Communication. Kinetics of scavenging of small, nucleating clusters. First nucleation theorem and sum rules

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Malila, Jussi; McGraw, Robert; Laaksonen, Ari; Lehtinen, Kari E. J.

    2015-01-07

    Despite recent advances in monitoring nucleation from a vapor at close-to-molecular resolution, the identity of the critical cluster, forming the bottleneck for the nucleation process, remains elusive. During past twenty years, the first nucleation theorem has been often used to extract the size of the critical cluster from nucleation rate measurements. However, derivations of the first nucleation theorem invoke certain questionable assumptions that may fail, e.g., in the case of atmospheric new particle formation, including absence of subcritical cluster losses and heterogeneous nucleation on pre-existing nanoparticles. Here we extend the kinetic derivation of the first nucleation theorem to give amore » general framework to include such processes, yielding sum rules connecting the size dependent particle formation and loss rates to the corresponding loss-free nucleation rate and the apparent critical size from a naïve application of the first nucleation theorem that neglects them.« less

  2. Kinetic Modeling of Gasoline Surrogate Components and Mixtures under Engine Conditions

    SciTech Connect (OSTI)

    Mehl, M; Pitz, W J; Westbrook, C K; Curran, H J

    2010-01-11

    Real fuels are complex mixtures of thousands of hydrocarbon compounds including linear and branched paraffins, naphthenes, olefins and aromatics. It is generally agreed that their behavior can be effectively reproduced by simpler fuel surrogates containing a limited number of components. In this work, an improved version of the kinetic model by the authors is used to analyze the combustion behavior of several components relevant to gasoline surrogate formulation. Particular attention is devoted to linear and branched saturated hydrocarbons (PRF mixtures), olefins (1-hexene) and aromatics (toluene). Model predictions for pure components, binary mixtures and multicomponent gasoline surrogates are compared with recent experimental information collected in rapid compression machine, shock tube and jet stirred reactors covering a wide range of conditions pertinent to internal combustion engines (3-50 atm, 650-1200K, stoichiometric fuel/air mixtures). Simulation results are discussed focusing attention on the mixing effects of the fuel components.

  3. Communication. Kinetics of scavenging of small, nucleating clusters. First nucleation theorem and sum rules

    SciTech Connect (OSTI)

    Malila, Jussi; McGraw, Robert; Laaksonen, Ari; Lehtinen, Kari E. J.

    2015-01-07

    Despite recent advances in monitoring nucleation from a vapor at close-to-molecular resolution, the identity of the critical cluster, forming the bottleneck for the nucleation process, remains elusive. During past twenty years, the first nucleation theorem has been often used to extract the size of the critical cluster from nucleation rate measurements. However, derivations of the first nucleation theorem invoke certain questionable assumptions that may fail, e.g., in the case of atmospheric new particle formation, including absence of subcritical cluster losses and heterogeneous nucleation on pre-existing nanoparticles. Here we extend the kinetic derivation of the first nucleation theorem to give a general framework to include such processes, yielding sum rules connecting the size dependent particle formation and loss rates to the corresponding loss-free nucleation rate and the apparent critical size from a nave application of the first nucleation theorem that neglects them.

  4. Characterization and use of a 2D-array of ion chambers for brachytherapy dosimetric quality assurance

    SciTech Connect (OSTI)

    Yewondwossen, Mammo

    2012-10-01

    The two-dimensional (2D) ionization chamber array MatriXX Evolution is one of the 2D ionization chamber arrays developed by IBA Dosimetry (IBA Dosimetry, Germany) for megavoltage real-time absolute 2D dosimetry and verification of intensity-modulated radiation therapy (IMRT). The purpose of this study was to (1) evaluate the performance of ion chamber array for submegavoltage range brachytherapy beam dose verification and quality assurance (QA) and (2) use the end-to-end dosimetric evaluation that mimics a patient treatment procedure and confirm the primary source strength calibration agrees in both the treatment planning system (TPS) and treatment delivery console computers. The dose linearity and energy dependence of the 2D ion chamber array was studied using kilovoltage X-ray beams (100, 180 and 300 kVp). The detector calibration factor was determined using 300 kVp X-ray beams so that we can use the same calibration factor for dosimetric verification of high-dose-rate (HDR) brachytherapy. The phantom used for this measurement consists of multiple catheters, the IBA MatriXX detector, and water-equivalent slab of RW3 to provide full scattering conditions. The treatment planning system (TPS) (Oncentra brachy version 3.3, Nucletron BV, Veenendaal, the Netherlands) dose distribution was calculated on the computed tomography (CT) scan of this phantom. The measured and TPS calculated distributions were compared in IBA Dosimetry OmniPro-I'mRT software. The quality of agreement was quantified by the gamma ({gamma}) index (with 3% delta dose and distance criterion of 2 mm) for 9 sets of plans. Using a dedicated phantom capable of receiving 5 brachytherapy intralumenal catheters a QA procedure was developed for end-to-end dosimetric evaluation for routine QA checks. The 2D ion chamber array dose dependence was found to be linear for 100-300 kVp and the detector response (k{sub user}) showed strong energy dependence for 100-300 kVp energy range. For the Ir-192 brachytherapy HDR source, dosimetric evaluation k{sub user} factor determined by photon beam of energy of 300 kVp was used. The maximum mean difference between ion chamber array measured and TPS calculated was 3.7%. Comparisons of dose distribution for different test plans have shown agreement with >94.5% for {gamma} {<=}1. Dosimetric QA can be performed with the 2D ion chamber array to confirm primary source strength calibration is properly updated in both the TPS and treatment delivery console computers. The MatriXX Evolution ionization chamber array has been found to be reliable for measurement of both absolute dose and relative dose distributions for the Ir-192 brachytherapy HDR source.

  5. Monte Carlo study of the depth-dependent fluence perturbation in parallel-plate ionization chambers in electron beams

    SciTech Connect (OSTI)

    Zink, K.; Czarnecki, D.; Voigts-Rhetz, P. von; Looe, H. K.; Harder, D.

    2014-11-01

    Purpose: The electron fluence inside a parallel-plate ionization chamber positioned in a water phantom and exposed to a clinical electron beam deviates from the unperturbed fluence in water in absence of the chamber. One reason for the fluence perturbation is the well-known inscattering effect, whose physical cause is the lack of electron scattering in the gas-filled cavity. Correction factors determined to correct for this effect have long been recommended. However, more recent Monte Carlo calculations have led to some doubt about the range of validity of these corrections. Therefore, the aim of the present study is to reanalyze the development of the fluence perturbation with depth and to review the function of the guard rings. Methods: Spatially resolved Monte Carlo simulations of the dose profiles within gas-filled cavities with various radii in clinical electron beams have been performed in order to determine the radial variation of the fluence perturbation in a coin-shaped cavity, to study the influences of the radius of the collecting electrode and of the width of the guard ring upon the indicated value of the ionization chamber formed by the cavity, and to investigate the development of the perturbation as a function of the depth in an electron-irradiated phantom. The simulations were performed for a primary electron energy of 6 MeV. Results: The Monte Carlo simulations clearly demonstrated a surprisingly large in- and outward electron transport across the lateral cavity boundary. This results in a strong influence of the depth-dependent development of the electron field in the surrounding medium upon the chamber reading. In the buildup region of the depth-dose curve, the inout balance of the electron fluence is positive and shows the well-known dose oscillation near the cavity/water boundary. At the depth of the dose maximum the inout balance is equilibrated, and in the falling part of the depth-dose curve it is negative, as shown here the first time. The influences of both the collecting electrode radius and the width of the guard ring are reflecting the deep radial penetration of the electron transport processes into the gas-filled cavities and the need for appropriate corrections of the chamber reading. New values for these corrections have been established in two forms, one converting the indicated value into the absorbed dose to water in the front plane of the chamber, the other converting it into the absorbed dose to water at the depth of the effective point of measurement of the chamber. In the Appendix, the inout imbalance of electron transport across the lateral cavity boundary is demonstrated in the approximation of classical small-angle multiple scattering theory. Conclusions: The inout electron transport imbalance at the lateral boundaries of parallel-plate chambers in electron beams has been studied with Monte Carlo simulation over a range of depth in water, and new correction factors, covering all depths and implementing the effective point of measurement concept, have been developed.

  6. Detailed chemical kinetic oxidation mechanism for a biodiesel surrogate

    SciTech Connect (OSTI)

    Herbinet, O; Pitz, W J; Westbrook, C K

    2007-09-17

    A detailed chemical kinetic mechanism has been developed and used to study the oxidation of methyl decanoate, a surrogate for biodiesel fuels. This model has been built by following the rules established by Curran et al. for the oxidation of n-heptane and it includes all the reactions known to be pertinent to both low and high temperatures. Computed results have been compared with methyl decanoate experiments in an engine and oxidation of rapeseed oil methyl esters in a jet stirred reactor. An important feature of this mechanism is its ability to reproduce the early formation of carbon dioxide that is unique to biofuels and due to the presence of the ester group in the reactant. The model also predicts ignition delay times and OH profiles very close to observed values in shock tube experiments fueled by n-decane. These model capabilities indicate that large n-alkanes can be good surrogates for large methyl esters and biodiesel fuels to predict overall reactivity, but some kinetic details, including early CO2 production from biodiesel fuels, can be predicted only by a detailed kinetic mechanism for a true methyl ester fuel. The present methyl decanoate mechanism provides a realistic kinetic tool for simulation of biodiesel fuels.

  7. Detailed chemical kinetic oxidation mechanism for a biodiesel surrogate

    SciTech Connect (OSTI)

    Herbinet, O; Pitz, W J; Westbrook, C K

    2007-09-20

    A detailed chemical kinetic mechanism has been developed and used to study the oxidation of methyl decanoate, a surrogate for biodiesel fuels. This model has been built by following the rules established by Curran et al. for the oxidation of n-heptane and it includes all the reactions known to be pertinent to both low and high temperatures. Computed results have been compared with methyl decanoate experiments in an engine and oxidation of rapeseed oil methyl esters in a jet stirred reactor. An important feature of this mechanism is its ability to reproduce the early formation of carbon dioxide that is unique to biofuels and due to the presence of the ester group in the reactant. The model also predicts ignition delay times and OH profiles very close to observed values in shock tube experiments fueled by n-decane. These model capabilities indicate that large n-alkanes can be good surrogates for large methyl esters and biodiesel fuels to predict overall reactivity, but some kinetic details, including early CO{sub 2} production from biodiesel fuels, can be predicted only by a detailed kinetic mechanism for a true methyl ester fuel. The present methyl decanoate mechanism provides a realistic kinetic tool for simulation of biodiesel fuels.

  8. Detailed chemical kinetic oxidation mechanism for a biodiesel surrogate

    SciTech Connect (OSTI)

    Herbinet, Olivier; Pitz, William J.; Westbrook, Charles K.

    2008-08-15

    A detailed chemical kinetic mechanism has been developed and used to study the oxidation of methyl decanoate, a surrogate for biodiesel fuels. This model has been built by following the rules established by Curran and co-workers for the oxidation of n-heptane and it includes all the reactions known to be pertinent to both low and high temperatures. Computed results have been compared with methyl decanoate experiments in an engine and oxidation of rapeseed oil methyl esters in a jet-stirred reactor. An important feature of this mechanism is its ability to reproduce the early formation of carbon dioxide that is unique to biofuels and due to the presence of the ester group in the reactant. The model also predicts ignition delay times and OH profiles very close to observed values in shock tube experiments fueled by n-decane. These model capabilities indicate that large n-alkanes can be good surrogates for large methyl esters and biodiesel fuels to predict overall reactivity, but some kinetic details, including early CO{sub 2} production from biodiesel fuels, can be predicted only by a detailed kinetic mechanism for a true methyl ester fuel. The present methyl decanoate mechanism provides a realistic kinetic tool for simulation of biodiesel fuels. (author)

  9. Desorption Kinetics of Methanol, Ethanol, and Water from Graphene

    SciTech Connect (OSTI)

    Smith, R. Scott; Matthiesen, Jesper; Kay, Bruce D.

    2014-09-18

    The desorption kinetics of methanol, ethanol, and water from graphene covered Pt(111) are investigated. The temperature programmed desorption (TPD) spectra for both methanol and ethanol have well-resolved first, second, third, and multilayer layer desorption peaks. The alignment of the leading edges is consistent with zero-order desorption kinetics from all layers. In contrast, for water the first and second layers are not resolved. At low water coverages (< 1 ML) the initial desorption leading edges are aligned but then fall out of alignment at higher temperatures. For thicker water layers (10 to 100 ML), the desorption leading edges are in alignment throughout the desorption of the film. The coverage dependence of the desorption behavoir suggests that at low water coverages the non-alignment of the desorption leading edges is due to water dewetting from the graphene substrate. Kinetic simulations reveal that the experimental results are consistent with zero-order desorption. The simulations also show that fractional order desorption kinetics would be readily apparent in the experimental TPD spectra.

  10. EDDY CURRENT EFFECT OF THE BNL-AGS VACUUM CHAMBER ON THE OPTICS OF THE BNL-AGS SYNCHROTRON.

    SciTech Connect (OSTI)

    TSOUPAS,N.; AHRENS,L.; BROWN,K.A.; GLENN,J.W.; GARDNER,K.

    1999-03-29

    During the acceleration cycle of the AGS synchrotron, eddy currents are generated within the walls of the vacuum chambers of the AGS main magnets. The vacuum chambers have elliptical cross section, are made of inconel material with a wall thickness of 2 mm and are placed within the gap of the combined-function main magnets of the AGS synchrotron. The generation of the eddy currents in the walls of the vacuum chambers, creates various magnetic multipoles, which affect the optics of the AGS machine. In this report these magnetic multipoles are calculated for various time interval starting at the acceleration cycle, where the magnetic field of the main magnet is {approx}0.1 T, and ending before the beam extraction process, where the magnetic field of the main magnet is almost constant at {approx}1.1 T. The calculations show that the magnetic multipoles generated by the eddy-currents affect the optics of the AGS synchrotron during the acceleration cycle and in particular at low magnetic fields of the main magnet. Their effect is too weak to affect the optics of the AGS machine during beam extraction at the nominal energies.

  11. Reactor Chamber and Balance-of-Plant Characteristics for a Fast-Ignition Heavy-Ion Fusion Power Plant

    SciTech Connect (OSTI)

    Medin, Stanislav; Churazov, Mikhail; Koshkarev, Dmitri; Sharkov, Boris; Orlov, Yurii; Suslin, Viktor; Zemskov, Eugeni

    2003-05-15

    The concept of a fast-ignition heavy-ion fusion (FIHIF) power plant involves a cylindrical target and superhigh energy ion beams. The driver produces one plus/minus charge state multimass platinum ions with energy of 100 GeV. The driver efficiency and the target gain are taken as 0.25 and 100, respectively. The preliminary data on the energy fluxes delivered to the reactor chamber wall by the 500-MJ fusion yield are presented. The reactor chamber designed has two sections. In the first section, the microexplosions occur, and in the second section of bigger volume the expansion and condensation of vapors take place. The response of the blanket and the thin liquid film at the first-wall surface is evaluated. Lithium-lead eutectic is taken as a coolant. The evaporated mass and the condensation time are estimated, taking into account major thermophysical effects. The estimated neutron spectrum from the FIHIF target gives an average neutron energy of 11.9 MeV. The mechanical stresses in the construction material due to neutron energy release are evaluated. The outlet coolant chamber temperature is taken as 550 deg. C. The heat conversion system consisting of three coolant loops provides a net efficiency of the FIHIF power plant of 0.37.

  12. GAT-280 CHEMISTRY-GENERAL

    Office of Scientific and Technical Information (OSTI)

    GAT-280 CHEMISTRY-GENERAL 1 URANIUM HEXAFLUORIDE: A SURVEY O F THE PHYSICO-CHEMICAL PROPERTIES R. DeWitt Information and Records Subdivision August 1 2 , 1960 GOODYEAR ATOMIC CORPORATION Portsmouth, Ohio DISCLAIMER This report was prepared as an account of work sponsored by an agency of the United States Government. Neither the United States Government nor any agency Thereof, nor any of their employees, makes any warranty, express or implied, or assumes any legal liability or responsibility for

  13. Experiment Report Instructions General Instructions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Report Instructions General Instructions * Experiment Reports must be submitted for all experiments conducted at LANSCE. * A compilation of Experiment Reports for each run cycle will be published as part of the LANSCE Annual Activity Report. * Experiment Reports are reviewed by the Program Advisory Committee for continuing expements. * Follow detailed form instructions below and complete entire form. * Reports must be written in English. * The available space on the form must be respected.

  14. Major General Kenneth David Nichols

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    General Kenneth David Nichols Oak Ridge Operations, formed September 15, 1947, was the result of changes made over several months after the Atomic Energy Commission formally took control of the nation's atomic energy program on January 1, 1947. Up until then, the daily operations of the entire nuclear program had been directed by Colonel Kenneth D. Nichols from Oak Ridge. Before exploring the early years of the Oak Ridge Operations, we should take a closer look at Colonel Nichols. His role was

  15. General Technical Base Qualification Standard

    Office of Environmental Management (EM)

    SENSITIVE DOE-STD-1146-2007 REAFFIRMED: March 2015 DOE STANDARD GENERAL TECHNICAL BASE QUALIFICATION STANDARD DOE Defense Nuclear Facilities Technical Personnel U.S. Department of Energy AREA TRNG Washington, D.C. 20585 DISTRIBUTION STATEMENT A: Approved for public release; distribution is unlimited ii This document is available on the Department of Energy Technical Standards Program Website at http://energy.gov/ehss/services/nuclear-safety/ department-energy-technical-standards-program

  16. II. GENERAL COMPLIANCE SUPPLEMENT INTRODUCTION

    Office of Environmental Management (EM)

    II. GENERAL COMPLIANCE SUPPLEMENT INTRODUCTION The objectives of most compliance requirements for DOE programs are generic in nature. For example, most programs have eligibility requirements. While the criteria for determining eligibility vary by program, the objective of the compliance requirement that only eligible entities participate is consistent across all programs. Rather than repeat these compliance requirements, audit objectives, and suggested audit procedures for each program, they are

  17. Map labeling and its generalizations

    SciTech Connect (OSTI)

    Doddi, S. |; Marathe, M.V.; Mirzaian, A.; Moret, B.M.E.; Zhu, B. |

    1997-01-01

    Map labeling is of fundamental importance in cartography and geographical information systems and is one of the areas targeted for research by the ACM Computational Geometry Impact Task Force. Previous work on map labeling has focused on the problem of placing maximal uniform, axis-aligned, disjoint rectangles on the plane so that each point feature to be labeled lies at the corner of one rectangle. Here, we consider a number of variants of the map labeling problem. We obtain three general types of results. First, we devise constant-factor polynomial-time-approximation algorithms for labeling point features by rectangular labels, where the feature may lie anywhere on the boundary of its label region and where labeling rectangles may be placed in any orientation. These results generalize to the case of elliptical labels. Secondly, we consider the problem of labeling a map consisting of disjoint rectilinear fine segments. We obtain constant-factor polynomial-time approximation algorithms for the general problem and an optimal algorithm for the special case where all segments are horizontal. Finally, we formulate a bicriteria version of the map-labeling problem and provide bicriteria polynomial- time approximation schemes for a number of such problems.

  18. SU-E-T-415: An Ionization Chamber Array with High Spatial Resolution for External Beam Radiotherapy

    SciTech Connect (OSTI)

    Togno, M; Wilkens, J; Menichelli, D

    2014-06-01

    Purpose: To characterize an ionization chamber array technology with high spatial resolution and high charge collection efficiency for external beam radiotherapy. Methods: The prototype under test is a linear array of air vented ionization chambers developed by IBA Dosimetry, consisting of 80 pixels with 3.5mm spatial resolution and 4mm{sup 3} sensitive volume. The detector was characterized in a plastic phantom with {sup 60} Co radiation and MV X-rays from an ELEKTA Agility LINAC (with flattened and unflattened beam qualities). Bias voltage was varied in order to evaluate charge collection efficiency. A commercial array of ionization chambers (MatriXX Evolution, IBA Dosimetry) and an amorphous silicon flat panel in direct conversion configuration were used as references. Results: Repeatability (0.4%) and stability under continuous gamma irradiation (0.3%) are very good, in spite of low active volume and sensitivity (?200pC/Gy). Charge collection efficiency is higher than 99% already at 150V with ?2mGy dose per pulse, leading to a 1.1% sensitivity change with dose per pulse in the range 0.09-2mGy (covering all flattened and unflattened applications). Measured dose profiles are in agreement with MatriXX for fields larger than 22cm{sup 2}, in which case the linear array offers a much better characterization of the penumbra region. Down to 11cm{sup 2}, measured profiles are in very good agreement with the flat panel. Conclusion: The array represents a valuable tool for the characterization of treatment fields in which high spatial resolution is required, together with the dosimetric performance of air vented ionization chambers. Such a technology would be particularly valuable in association with advanced treatment modalities such as rotational radiotherapy, stereotactic treatments (even with unflattened beam qualities) and proton therapy, due to the insensitivity of the chambers on dose per pulse. In the future, a two dimensional prototype based on this technology will be developed and tested. This research project has been supported by a Marie Curie Early Initial Training Network Fellowship of the European Community's Seventh Framework Programme under contract number (PITN-GA-2011-289198-.

  19. Fully Kinetic Simulations of MegaJoule-Scale Dense Plasma Focus...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Fully Kinetic Simulations of MegaJoule-Scale Dense Plasma Focus Citation Details In-Document Search Title: Fully Kinetic Simulations of MegaJoule-Scale Dense...

  20. PHASE-FIELD SIMULATION OF IRRADIATED METALS PART i: VOID KINETICS...

    Office of Scientific and Technical Information (OSTI)

    METALS PART i: VOID KINETICS Citation Details In-Document Search Title: PHASE-FIELD SIMULATION OF IRRADIATED METALS PART i: VOID KINETICS We present a phase-field model of void ...

  1. Chemical Kinetics Research on HCCI and Diesel Fuels | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Kinetics Research on HCCI and Diesel Fuels Chemical Kinetics Research on HCCI and Diesel Fuels Discusses detailed chemical kinetics mechanisms for complex hydrocarbon fuels and computationally efficiecnt, accurate methodologies for modeling advanced combustion strategies. PDF icon deer10_flowers.pdf More Documents & Publications Simulation of High Efficiency Clean Combustion Engines and Detailed Chemical Kinetic Mechanisms Development Improving Combustion Software to Solve Detailed Chemical

  2. Isotope exchange kinetics in metal hydrides I : TPLUG model.

    SciTech Connect (OSTI)

    Larson, Rich; James, Scott Carlton; Nilson, Robert H.

    2011-05-01

    A one-dimensional isobaric reactor model is used to simulate hydrogen isotope exchange processes taking place during flow through a powdered palladium bed. This simple model is designed to serve primarily as a platform for the initial development of detailed chemical mechanisms that can then be refined with the aid of more complex reactor descriptions. The one-dimensional model is based on the Sandia in-house code TPLUG, which solves a transient set of governing equations including an overall mass balance for the gas phase, material balances for all of the gas-phase and surface species, and an ideal gas equation of state. An energy equation can also be solved if thermodynamic properties for all of the species involved are known. The code is coupled with the Chemkin package to facilitate the incorporation of arbitrary multistep reaction mechanisms into the simulations. This capability is used here to test and optimize a basic mechanism describing the surface chemistry at or near the interface between the gas phase and a palladium particle. The mechanism includes reversible dissociative adsorptions of the three gas-phase species on the particle surface as well as atomic migrations between the surface and the bulk. The migration steps are more general than those used previously in that they do not require simultaneous movement of two atoms in opposite directions; this makes possible the creation and destruction of bulk vacancies and thus allows the model to account for variations in the bulk stoichiometry with isotopic composition. The optimization code APPSPACK is used to adjust the mass-action rate constants so as to achieve the best possible fit to a given set of experimental data, subject to a set of rigorous thermodynamic constraints. When data for nearly isothermal and isobaric deuterium-to-hydrogen (D {yields} H) and hydrogen-to-deuterium (H {yields} D) exchanges are fitted simultaneously, results for the former are excellent, while those for the latter show pronounced deviations at long times. These discrepancies can be overcome by postulating the presence of a surface poison such as carbon monoxide, but this explanation is highly speculative. When the method is applied to D {yields} H exchanges intentionally poisoned by known amounts of CO, the fitting results are noticeably degraded from those for the nominally CO-free system but are still tolerable. When TPLUG is used to simulate a blowdown-type experiment, which is characterized by large and rapid changes in both pressure and temperature, discrepancies are even more apparent. Thus, it can be concluded that the best use of TPLUG is not in simulating realistic exchange scenarios, but in extracting preliminary estimates for the kinetic parameters from experiments in which variations in temperature and pressure are intentionally minimized.

  3. A Novel Approach to Experimental Studies of Mineral Dissolution Kinetics

    SciTech Connect (OSTI)

    Chen Zhu

    2006-08-31

    Currently, DOE is conducting pilot CO{sub 2} injection tests to evaluate the concept of geological sequestration. One strategy that potentially enhances CO{sub 2} solubility and reduces the risk of CO{sub 2} leak back to the surface is dissolution of indigenous minerals in the geological formation and precipitation of secondary carbonate phases, which increases the brine pH and immobilizes CO{sub 2}. Clearly, the rates at which these dissolution and precipitation reactions occur directly determine the efficiency of this strategy. However, one of the fundamental problems in modern geochemistry is the persistent two to five orders of magnitude discrepancy between laboratory measured and field derived feldspar dissolution rates. To date, there is no real guidance as to how to predict silicate reaction rates for use in quantitative models. Current models for assessment of geological carbon sequestration have generally opted to use laboratory rates, in spite of the dearth of such data for compositionally complex systems, and the persistent disconnect between laboratory and field applications. Therefore, a firm scientific basis for predicting silicate reaction kinetics in CO2 injected geological formations is urgently needed to assure the reliability of the geochemical models used for the assessments of carbon sequestration strategies. The funded experimental and theoretical study attempts to resolve this outstanding scientific issue by novel experimental design and theoretical interpretation to measure silicate dissolution rates and iron carbonate precipitation rates at conditions pertinent to geological carbon sequestration. In the second year of the project, we completed CO{sub 2}-Navajo sandstone interaction batch and flow-through experiments and a Navajo sandstone dissolution experiment without the presence of CO{sub 2} at 200 C and 250-300 bars, and initiated dawsonite dissolution and solubility experiments. We also performed additional 5-day experiments at the same conditions as alkali-feldspar dissolution experiments with and without the presence of CO{sub 2} performed in the first year to check the validation of the experiments and analysis. The changes of solution chemistry as dissolution experiments progressed were monitored with on-line sampling of the aqueous phase at the constant temperature and pressure. These data allow calculating overall apparent mineral (feldspars and sandstones) dissolution rates and secondary mineral precipitation rates as a function of saturation states. State-of-the-art atomic resolution transmission electron microscopy (TEM), scanning electron microscopy (SEM), and electron microprobe was used to characterize the products and reactants. Reaction-path geochemical modeling was used to interpret the experimental results of alkali-feldspar dissolution experiments without the presence of CO{sub 2}. Two manuscripts are near completion. Also during the second year, our education goal of graduate student training has been advanced. A Ph. D. student at Indiana University is progressing well in the degree program and has taken geochemical modeling, SEM, and TEM courses, which will facilitate research in the third year. A Ph. D. student at University of Minnesota had graduated. With the success of training of graduate students and excellent experimental data in the second year, we anticipate a more fruitful year in the third year.

  4. Chemical Kinetic Modeling of Non-Petroleum Based Fuels | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy 2 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon ft010_pitz_2012_o.pdf More Documents & Publications Chemical Kinetic Modeling of Non-Petroleum Based Fuels Chemical Kinetic Modeling of Fuels Chemical Kinetic Research on HCCI & Diesel Fuels

  5. Chemical Kinetic Modeling of Non-Petroleum Based Fuels | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy 1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon ft010_pitz_2011_o.pdf More Documents & Publications Chemical Kinetic Modeling of Non-Petroleum Based Fuels Chemical Kinetic Modeling of Fuels Simulation of High Efficiency Clean Combustion Engines and Detailed Chemical Kinetic Mechanisms Development

  6. Chemical Kinetic Research on HCCI & Diesel Fuels | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon ace013_pitz_2011_o.pdf More Documents & Publications Chemical Kinetic Research on HCCI & Diesel Fuels Chemical Kinetics Research on HCCI and Diesel Fuels Chemical Kinetic Research on HCCI & Diesel Fuels

  7. Development of Chemical Kinetic Models for Lean NOx Traps | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy 1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon ace035_larson_2011_o.pdf More Documents & Publications Development of Chemical Kinetic Models for Lean NOx Traps Benchmark Reaction Mechanisms and Kinetics for Lean NOx Traps CLEERS Coordination & Development of Catalyst Process Kinetic Data

  8. Chemical Kinetic Research on HCCI & Diesel Fuels | Department of Energy

    Office of Environmental Management (EM)

    3 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon ace013_pitz_2013_o.pdf More Documents & Publications Chemical Kinetic Research on HCCI & Diesel Fuels Vehicle Technologies Office Merit Review 2014: Chemical Kinetic Models for Advanced Engine Combustion Chemical Kinetic Modeling of Non-Petroleum Based Fuels

  9. General Atomics (GA) | Princeton Plasma Physics Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    General Atomics (GA) Subscribe to RSS - General Atomics (GA) General Atomics Image: General Atomics (GA) The Scorpion's Strategy: "Catch and Subdue" Read more about The Scorpion's Strategy: "Catch and Subdue" Frozen Bullets Tame Unruly Edge Plasmas in Fusion Experiment Read more about Frozen Bullets Tame Unruly Edge Plasmas in Fusion Experiment General Atomics (GA) Fusion News: A New Spin on Understanding Plasma Confinement Read more about General Atomics (GA) Fusion News: A

  10. SWRCB General NPDES Permits | Open Energy Information

    Open Energy Info (EERE)

    NPDES PermitsLegal Abstract SWRCB General NPDES Permits, current through August 14, 2014. Published NA Year Signed or Took Effect 2014 Legal Citation SWRCB General NPDES...

  11. General Building Spa | Open Energy Information

    Open Energy Info (EERE)

    Spa Jump to: navigation, search Name: General Building Spa Place: Polverigi - Ancona, Italy Zip: 60020 Product: Ancona based developer of PV projects. References: General Building...

  12. Michigan: General Motors Optimizes Engine Valve Technology |...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Michigan: General Motors Optimizes Engine Valve Technology Michigan: General Motors Optimizes Engine Valve Technology November 8, 2013 - 12:00am Addthis An EERE-supported effort to ...

  13. Texas General Land Office | Open Energy Information

    Open Energy Info (EERE)

    Land Office Jump to: navigation, search Logo: Texas General Land Office Name: Texas General Land Office Address: 1700 Congress Ave Place: Austin, Texas Zip: 78701 Website:...

  14. General Biodiesel Incorporated | Open Energy Information

    Open Energy Info (EERE)

    Biodiesel Incorporated Jump to: navigation, search Name: General Biodiesel Incorporated Place: Seattle, Washington Zip: 98136 Product: General BioDiesel", Inc. specializes in...

  15. Alaska - CPCN General Information | Open Energy Information

    Open Energy Info (EERE)

    CPCN General Information Jump to: navigation, search OpenEI Reference LibraryAdd to library PermittingRegulatory Guidance - Instructions: Alaska - CPCN General...

  16. Shanghai Aerospace Industrial General Corporation aka Shanghai...

    Open Energy Info (EERE)

    Industrial General Corporation aka Shanghai Academy of Spaceflight Technology Jump to: navigation, search Name: Shanghai Aerospace Industrial General Corporation (aka Shanghai...

  17. Oregon General Industrial Water Pollution Control Facilities...

    Open Energy Info (EERE)

    General Industrial Water Pollution Control Facilities Webpage Jump to: navigation, search OpenEI Reference LibraryAdd to library Web Site: Oregon General Industrial Water Pollution...

  18. Aqueous fractionation of biomass based on novel carbohydrate hydrolysis kinetics

    DOE Patents [OSTI]

    Torget, Robert W.

    2001-01-01

    A multi-function process for hydrolysis and fractionation of lignocellulosic biomass to separate hemicellulosic sugars from other biomass components comprising extractives and proteins; a portion of a solubilized lignin; cellulose; glucose derived from cellulose; and insoluble lignin from said biomass comprising: a) introducing either solid fresh biomass or partially fractioned lignocellulosic biomass material with entrained acid or water into a reactor and heating to a temperature of up to about 185.degree. C.-205.degree. C. b) allowing the reaction to proceed to a point where about 60% of the hemicellulose has been hydrolyzed in the case of water or complete dissolution in case of acid; c) adding a dilute acid liquid at a pH below about 5 at a temperature of up to about 205.degree. C. for a period ranging from about 5 to about 10 minutes; to hydrolyze the remaining 40% of hemicellulose if water is used. d) quenching the reaction at a temperature of up to about 140.degree. C. to quench all degradation and hydrolysis reactions; and e) introducing into said reaction chamber and simultaneously removing from said reaction chamber, a volumetric flow rate of dilute acid at a temperature of up to about 140.degree. C. to wash out the majority of the solubilized biomass components, to obtain improved hemicellosic sugar yields.

  19. RESOLUTION OF URANIUM ISOTOPES WITH KINETIC PHOSPHORESCENCE ANALYSIS

    SciTech Connect (OSTI)

    Miley, Sarah M.; Hylden, Anne T.; Friese, Judah I.

    2013-04-01

    This study was conducted to test the ability of the Chemchek Kinetic Phosphorescence Analyzer Model KPA-11 with an auto-sampler to resolve the difference in phosphorescent decay rates of several different uranium isotopes, and therefore identify the uranium isotope ratios present in a sample. Kinetic phosphorescence analysis (KPA) is a technique that provides rapid, accurate, and precise determination of uranium concentration in aqueous solutions. Utilizing a pulsed-laser source to excite an aqueous solution of uranium, this technique measures the phosphorescent emission intensity over time to determine the phosphorescence decay profile. The phosphorescence intensity at the onset of decay is proportional to the uranium concentration in the sample. Calibration with uranium standards results in the accurate determination of actual concentration of the sample. Different isotopes of uranium, however, have unique properties which should result in different phosphorescence decay rates seen via KPA. Results show that a KPA is capable of resolving uranium isotopes.

  20. On consistent kinetic and derivative interactions for gravitons

    SciTech Connect (OSTI)

    Noller, Johannes

    2015-04-17

    The only known fully ghost-free and consistent Lorentz-invariant kinetic term for a graviton (or indeed for any spin-2 field) is the Einstein-Hilbert term. Here we propose and investigate a new candidate family of kinetic interactions and their extensions to derivative interactions involving several spin-2 fields. These new terms generically break diffeomorphism invariance(s) and as a result can lead to the propagation of 5 degrees of freedom for a single spin-2 field — analogous to ghost-free Massive Gravity. We discuss under what circumstances these new terms can be used to build healthy effective field theories and in the process establish the ‘Jordan’ and ‘Einstein’ frame pictures for Massive-, Bi- and Multi-Gravity.

  1. Microscale Electrode Design Using Coupled Kinetic, Thermal and Mechanical

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Modeling | Department of Energy 10 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C. PDF icon es082_sastry_2010_p.pdf More Documents & Publications track 3: enhanced geothermal systems (EGS) | geothermal 2015 peer review Coupled Kinetic, Thermal, and Mechanical Modeling of FIB Micro-machined Electrodes 2015 GTO Peer Review | Poster Session

  2. Kinetically tuned dimensional augmentation as a versatile synthetic route

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    towards robust metal-organic frameworks | Center for Gas SeparationsRelevant to Clean Energy Technologies | Blandine Jerome Kinetically tuned dimensional augmentation as a versatile synthetic route towards robust metal-organic frameworks Previous Next List Dawei Feng, Kecheng Wang, Zhangwen Wei, Ying-Pin Chen, Cory M. Simon, Ravi K. Arvapally, Richard L. Martin, Mathieu Bosch, Tian-Fu Liu, Stephen Fordham, Daqiang Yuan, Mohammad A. Omary, Maciej Haranczyk, Berend Smit & Hong-Cai Zhou,

  3. Diffusion in confinement: kinetic simulations of self- and collective

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    diffusion behavior of adsorbed gases | Center for Gas SeparationsRelevant to Clean Energy Technologies | Blandine Jerome confinement: kinetic simulations of self- and collective diffusion behavior of adsorbed gases Previous Next List M. K. F. Abouelnasr and B. Smit, PCCP 14 (33), 11600 (2012) DOI: 10.1039/C2CP41147D abo121 Abstract The self- and collective-diffusion behaviors of adsorbed methane, helium, and isobutane in zeolite frameworks LTA, MFI, AFI, and SAS were examined at various

  4. Chemical Kinetic Research on HCCI & Diesel Fuels

    Office of Environmental Management (EM)

    Laboratory Chemical Kinetic Research on HCCI & Diesel Fuels William J. Pitz (PI), Charles K. Westbrook, Marco Mehl, M. Lee Davisson Lawrence Livermore National Laboratory May 12, 2009 DOE National Laboratory Advanced Combustion Engine R&D Merit Review and Peer Evaluation Washington, DC This presentation does not contain any proprietary or confidential information This work performed under the auspices of the U.S. Department of Energy by Lawrence Livermore National Laboratory under

  5. Kinetic and reactor models for HDT of middle distillates

    SciTech Connect (OSTI)

    Cotta, R.M.; Filho, R.M.

    1996-12-31

    Hydrodesulfurization (HDS) and hydrodenitrogenation (HDN) of middle distillates over a commercial Ni-Mo/y-Al{sub 2}O{sub 3} has been studied under wide operating conditions just as 340 to 380{degrees}C and 38 to 98 atm. A Power Law model was presented to each one of those reactions. The parameters of kinetic equations were estimated solving the ordinary differential equations by the 4 order Runge-Kutta-Gill algorithm and Marquardt method for searching of set of kinetic parameters (kinetic constants as well as the orders of reactions). An adiabatic diesel hydrotreating trickle-bed reactor packed with the same catalyst was simulated numerically in order to check up the behavior of this specific reaction system. One dimensional pseudo-homogeneous model was used in this work. For each feed, the mass and energy balance equations were integrated along the length of the catalytic bed using the 4th Runge-Kutta-Gill method. The performance of two industrial reactors was checked. 5 refs., 2 tabs.

  6. Kinetic theory of nonlinear transport phenomena in complex plasmas

    SciTech Connect (OSTI)

    Mishra, S. K. [Institute for Plasma Research (IPR), Gandhinagar 382428 (India); Sodha, M. S. [Centre for Energy Studies (CES), Indian Institute of Technology Delhi (IITD), New Delhi 110016 (India)

    2013-03-15

    In contrast to the prevalent use of the phenomenological theory of transport phenomena, a number of transport properties of complex plasmas have been evaluated by using appropriate expressions, available from the kinetic theory, which are based on Boltzmann's transfer equation; in particular, the energy dependence of the electron collision frequency has been taken into account. Following the recent trend, the number and energy balance of all the constituents of the complex plasma and the charge balance on the particles is accounted for; the Ohmic loss has also been included in the energy balance of the electrons. The charging kinetics for the complex plasma comprising of uniformly dispersed dust particles, characterized by (i) uniform size and (ii) the Mathis, Rumpl, and Nordsieck power law of size distribution has been developed. Using appropriate expressions for the transport parameters based on the kinetic theory, the system of equations has been solved to investigate the parametric dependence of the complex plasma transport properties on the applied electric field and other plasma parameters; the results are graphically illustrated.

  7. Effect of morphology of hydrophobic surfaces on cavitation kinetics

    SciTech Connect (OSTI)

    LUZAR,ALENKA; LEUNG,KEVIN

    2000-04-24

    Cavitation has been suggested to be a possible source of long range interactions between mesoscopic hydrophobic surfaces. While evaporation is predicted by thermodynamics, little is known about its kinetics. Glauber dynamics Monte Carlo simulations of a lattice gas close to liquid-gas coexistence and confined between partially drying surfaces are used to model the effect of water confinement on the dynamics of surface-induced phase transition. Specifically, they examine how kinetics of induced evaporation change as the texture of hydrophobic surfaces is varied. Evaporation rates are considerably slowed with relatively small amount of hydrophilic coverage. However, the distribution of hydrophilic patches is found to be crucial, with the homogeneous one being much more effective in slowing the formation of vapor tubes which triggers the evaporation process. They estimate the free energy barrier of vapor tube formation via transition state theory, using a constrained forward-backward umbrella sampling technique applied to the metastable, confined liquid. Furthermore, to relate simulation rates to experimental ones, they perform simulations using the mass-conserving Kawasaki algorithm. They predict evaporation time scales that range from hundreds of picoseconds in the case of mesoscopic surfaces {approximately} 10{sup 4} nm{sup 2} to tens of nanoseconds for smaller surfaces {approximately} 40 nm{sup 2}, when the two surfaces are {approximately} 10 solvent layers apart. The present study demonstrates that cavitation is kinetically viable in real systems and should be considered in studies of processes at confined geometry.

  8. A Pore Scale Evaluation of the Kinetics of Mineral Dissolution and Precipitation Reactions (EMSI)

    SciTech Connect (OSTI)

    Steefel, Carl I.

    2006-06-01

    The chief goals for CEKA are to (1) collect and synthesize molecular-level kinetic data into a coherent framework that can be used to predict time evolution of environmental processes over a range of temporal and spatial scales; (2) train a cohort of talented and diverse students to work on kinetic problems at multiple scales; (3) develop and promote the use of new experimental techniques in environmental kinetics; (4) develop and promote the use of new modeling tools to conceptualize reaction kinetics in environmental systems; and (5) communicate our understanding of issues related to environmental kinetics and issues of scale to the broader scientific community and to the public.

  9. Experimental verification of the method for detection of water microleakages in plasma vacuum chambers by using the hydroxyl spectrum

    SciTech Connect (OSTI)

    Antipenkov, A. B.; Afonin, O. N.; Ochkin, V. N.; Savinov, S. Yu.; Tskhai, S. N.

    2012-03-15

    Experimental determination of the sensitivity of the method for detection of water microleakages in the cooling systems of the plasma vacuum chambers of complex electrophysical devices (such as tokamaks, fuel elements of nuclear reactors, and plasmachemical reactors) is considered. It was shown that the spectroscopic method for detection of water microleakages by using the hydroxyl radiation spectrum makes it possible to detect leakages at a level of 10{sup -5} Pa m{sup 3} s{sup -1}. The spatial resolution of the method allows one to localize defects with an accuracy of several centimeters.

  10. Enhancement of microarcing at a grounded chamber wall by nonvanishing ion sheath in a radio-frequency capacitive discharged plasma

    SciTech Connect (OSTI)

    Kwok, Dixon T.K.; Yin Yongbai; Bilek, Marcela M.M.; McKenzie, David

    2005-10-31

    One-dimensional hybrid particle-in-cell simulations in cylindrical r coordinate, with particle ions and Boltzmann's distribution of electrons, are used to investigate the arcing effect in radio-frequency (rf) capacitively coupled discharged plasma. The simulation shows that the arcing at the chamber wall is enhanced by the nonvanishing ion sheath at the surface, such that the emission electrons current will last for several tens of rf cycles. On the other hand, at the inner electrode, the electron emission occurs only during certain phases of the rf cycle and does not promote arc growth.

  11. General Service LED Lamps | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    General Service LED Lamps General Service LED Lamps A U.S. DOE SSL technology fact sheet that compares general service LED light bulbs with incandescent and CFL bulbs. PDF icon led_general-service-lamps.pdf More Documents & Publications LED Directional Lamps Emerging Lighting Technology LED T8 Replacement Lamps

  12. From General Mechanics to General Motors: Lynn Gantt's EcoCAR Experience

    Broader source: Energy.gov [DOE]

    How Lynn Gantt’s EcoCAR experience took him from studying general mechanics to working at General Motors.

  13. A kinetic approach to modeling the manufacture of high density strucutral foam: Foaming and polymerization

    SciTech Connect (OSTI)

    Rao, Rekha R.; Mondy, Lisa Ann; Noble, David R.; Brunini, Victor; Roberts, Christine Cardinal; Long, Kevin Nicholas; Soehnel, Melissa Marie; Celina, Mathias C.; Wyatt, Nicholas B.; Thompson, Kyle R.; Tinsley, James

    2015-09-01

    We are studying PMDI polyurethane with a fast catalyst, such that filling and polymerization occur simultaneously. The foam is over-packed to tw ice or more of its free rise density to reach the density of interest. Our approach is to co mbine model development closely with experiments to discover new physics, to parameterize models and to validate the models once they have been developed. The model must be able to repres ent the expansion, filling, curing, and final foam properties. PMDI is chemically blown foam, wh ere carbon dioxide is pr oduced via the reaction of water and isocyanate. The isocyanate also re acts with polyol in a competing reaction, which produces the polymer. A new kinetic model is developed and implemented, which follows a simplified mathematical formalism that decouple s these two reactions. The model predicts the polymerization reaction via condensation chemis try, where vitrification and glass transition temperature evolution must be included to correctly predict this quantity. The foam gas generation kinetics are determined by tracking the molar concentration of both water and carbon dioxide. Understanding the therma l history and loads on the foam due to exothermicity and oven heating is very important to the results, since the kinetics and ma terial properties are all very sensitive to temperature. The conservation eq uations, including the e quations of motion, an energy balance, and thr ee rate equations are solved via a stabilized finite element method. We assume generalized-Newtonian rheology that is dependent on the cure, gas fraction, and temperature. The conservation equations are comb ined with a level set method to determine the location of the free surface over time. Results from the model are compared to experimental flow visualization data and post-te st CT data for the density. Seve ral geometries are investigated including a mock encapsulation part, two configur ations of a mock stru ctural part, and a bar geometry to specifically test the density model. We have found that the model predicts both average density and filling profiles well. However, it under predicts density gradients, especially in the gravity direction. Thoughts on m odel improvements are also discussed.

  14. Turbulent Flame Speeds and NOx Kinetics of HHC Fuels with Contaminants and High Dilution Levels

    SciTech Connect (OSTI)

    Petersen, Eric; Krejci, Michael; Mathieu, Olivier; Vissotski, Andrew; Ravi, Sankar; Sikes, Travis; Levacque, Anthony; Aul, Christopher; Peterson, Eric

    2011-09-30

    This progress report documents the first year of the project, from October 1, 2010 through September 30, 2011. Laminar flame speeds and ignition delay times have been measured for hydrogen and various compositions of H2/CO (syngas) at elevated pressures and elevated temperatures. Two constant-volume cylindrical vessels were used to visualize the spherical growth of the flame through the use of a schlieren optical setup to measure the laminar flame speed of the mixture. Hydrogen experiments were performed at initial pressures up to 10 atm and initial temperatures up to 443 K. A syngas composition of 50/50 was chosen to demonstrate the effect of carbon monoxide on H2-O2 chemical kinetics at standard temperature and pressures up to 10 atm. All atmospheric mixtures were diluted with standard air, while all elevated-pressure experiments were diluted with a He:O2 of 7:1 to minimize hydrodynamic instabilities. The laminar flame speed measurements of hydrogen and syngas are compared to available literature data over a wide range of equivalence ratios where good agreement can be seen with several data sets. Additionally, an improved chemical kinetics model is shown for all conditions within the current study. The model and the data presented herein agree well, which demonstrates the continual, improved accuracy of the chemical kinetics model. A high-pressure shock tube was used to measure ignition delay times for several baseline compositions of syngas at three pressures across a wide range of temperatures. The compositions of syngas (H2/CO) presented in this study include 80/20, 50/50, 40/60, 20/80, and 10/90, all of which are compared to previously published ignition delay times from a hydrogen-oxygen mixture to demonstrate the effect of carbon monoxide addition. Generally, an increase in carbon monoxide increases the ignition delay time, but there does seem to be a pressure dependency. At low temperatures and pressures higher than about 12 atm, the ignition delay times appear to be indistinguishable with an increase in carbon monoxide. However, at high temperatures the composition of H2 and CO has a strong influence on ignition delay times. Model agreement is good across the range of the study, particularly at the elevated pressures. Also an increase in carbon monoxide causes the activation energy of the mixture to decrease.

  15. Deming's General Least Square Fitting

    Energy Science and Technology Software Center (OSTI)

    1992-02-18

    DEM4-26 is a generalized least square fitting program based on Deming''s method. Functions built into the program for fitting include linear, quadratic, cubic, power, Howard''s, exponential, and Gaussian; others can easily be added. The program has the following capabilities: (1) entry, editing, and saving of data; (2) fitting of any of the built-in functions or of a user-supplied function; (3) plotting the data and fitted function on the display screen, with error limits if requested,moreand with the option of copying the plot to the printer; (4) interpolation of x or y values from the fitted curve with error estimates based on error limits selected by the user; and (5) plotting the residuals between the y data values and the fitted curve, with the option of copying the plot to the printer. If the plot is to be copied to a printer, GRAPHICS should be called from the operating system disk before the BASIC interpreter is loaded.less

  16. General Reactive Atomistic Simulation Program

    Energy Science and Technology Software Center (OSTI)

    2004-09-22

    GRASP (General Reactive Atomistic Simulation Program) is primarily intended as a molecular dynamics package for complex force fields, The code is designed to provide good performance for large systems, either in parallel or serial execution mode, The primary purpose of the code is to realistically represent the structural and dynamic properties of large number of atoms on timescales ranging from picoseconds up to a microsecond. Typically the atoms form a representative sample of some material,more » such as an interface between polycrystalline silicon and amorphous silica. GRASP differs from other parallel molecular dynamics codes primarily due to it’s ability to handle relatively complicated interaction potentials and it’s ability to use more than one interaction potential in a single simulation. Most of the computational effort goes into the calculation of interatomic forces, which depend in a complicated way on the positions of all the atoms. The forces are used to integrate the equations of motion forward in time using the so-called velocity Verlet integration scheme. Alternatively, the forces can be used to find a minimum energy configuration, in which case a modified steepest descent algorithm is used.« less

  17. P-SV conversions at a shallow boundary beneath Campi Flegrei caldera (Italy) - evidence for the magma chamber

    SciTech Connect (OSTI)

    Ferrucci, F.; Hirn, A.; De Natale, G.; Virieux, J.; Mirabile, L. Inst. de Physique du Globe, Paris Osservatorio Vesuviano, Naples CNRS, Inst. de Geodynamique, Valbonne Ist. Universitario Navale, Naples )

    1992-10-01

    Seismograms from an active seismic experiment carried out at Campi Flegrei caldera (near Naples, Italy), show a large-amplitude SV-polarized shear wave, following by less than 1.5-s P waves reflected at wide angle from a deep crustal interface. Early arriving SV-polarized waves, with the same delay to direct P waves, are also observed in seismograms from a regional 280 km-deep, magnitude 5.1 earthquake. Such short delays of S to P waves are consistent with a P-SV conversion on transmission occurring at a shallow boundary beneath the receivers. The large amplitude of the converted-SV phase, along with that the P waves are near vertical, requires a boundary separating a very low rigidity layer from the upper caldera fill. The converted phases are interpreted as a seismic marker of a magma chamber. The top of this magma chamber is located slightly deeper than the deepest earthquakes observed during the 1982-1984 unrest of Campi Flegrei. 8 refs.

  18. Kinetics and mechanism of the thermal decomposition of dimethylzinc

    SciTech Connect (OSTI)

    Sokolovskii, A.E.; Baev, A.K.

    1985-05-01

    This paper studies the thermodecomposition of dimethylzinc in a vacuum in the temperature range 554.9-611.0 K and the concentration range 0.0027-0.0188 mole/liter. The investigations were conducted by the static method with a membrane wall manometer, an essential advantage of which is the possibility of the determination of the pressure in the reaction chamber with the complete absence of contact of the dimethylzinc with air and mercury. The results of the chromatographic study of the composition of the gas phase are presented. In the range of initial concentrations the content of the main decomposition products (methane, ethane, propane) scarcely changes, whereas at a concentration of 0.0027 mole/liter the yield of propane decreases somewhat.

  19. Kinetics and mechanisms of reactions involving small aromatic reactive intermediates

    SciTech Connect (OSTI)

    Lin, M.C.

    1993-12-01

    Small aromatic radicals such as C{sub 6}H{sub 5}, C{sub 6}H{sub 5}O and C{sub 6}H{sub 4} are key prototype species of their homologs. C{sub 6}H{sub 5} and its oxidation product, C{sub 6}H{sub 5}O are believed to be important intermediates which play a pivotal role in hydrocarbon combustion, particularly with regard to soot formation. Despite their fundamental importance, experimental data on the reaction mechanisms and reactivities of these species are very limited. For C{sub 6}H{sub 5}, most kinetic data except its reactions with NO and NO{sub 2}, were obtained by relative rate measurements. For C{sub 6}H{sub 5}O, the authors have earlier measured its fragmentation reaction producing C{sub 5}H{sub 5} + CO in shock waves. For C{sub 6}H{sub 4}, the only rate constant measured in the gas phase is its recombination rate at room temperature. The authors have proposed to investigate systematically the kinetics and mechanisms of this important class of molecules using two parallel laser diagnostic techniques--laser resonance absorption (LRA) and resonance enhanced multiphoton ionization mass spectrometry (REMPI/MS). In the past two years, study has been focused on the development of a new multipass adsorption technique--the {open_quotes}cavity-ring-down{close_quotes} technique for kinetic applications. The preliminary results of this study appear to be quite good and the sensitivity of the technique is at least comparable to that of the laser-induced fluorescence method.

  20. Evaluation of kinetic phosphorescence analysis for the determination of uranium

    SciTech Connect (OSTI)

    Croatto, P.V.; Frank, I.W.; Johnson, K.D.; Mason, P.B.; Smith, M.M.

    1997-12-01

    In the past, New Brunswick Laboratory (NBL) has used a fluorometric method for the determination of sub-microgram quantities of uranium. In its continuing effort to upgrade and improve measurement technology, NBL has evaluated the commercially-available KPA-11 kinetic phosphorescence analyzer (Chemchek, Richland, WA). The Chemchek KPA-11 is a bench-top instrument which performs single-measurement, quench-corrected analyses for trace uranium. It incorporates patented kinetic phosphorimetry techniques to measure and analyze sample phosphorescence as a function of time. With laser excitation and time-corrected photon counting, the KPA-11 has a lower detection limit than conventional fluorometric methods. Operated with a personal computer, the state-of-the-art KPA-11 offers extensive time resolution and phosphorescence lifetime capabilities for additional specificity. Interferences are thereby avoided while obtaining precise measurements. Routine analyses can be easily and effectively accomplished, with the accuracy and precision equivalent to the pulsed-laser fluorometric method presently performed at NBL, without the need for internal standards. Applications of kinetic phosphorimetry at NBL include the measurement of trace level uranium in retention tank, waste samples, and low-level samples. It has also been used to support other experimental activities at NBL by the measuring of nanogram amounts of uranium contamination (in blanks) in isotopic sample preparations, and the determining of elution curves of different ion exchange resins used for uranium purification. In many cases, no pretreatment of samples was necessary except to fume them with nitric acid, and then to redissolve and dilute them to an appropriate concentration with 1 M HNO{sub 3} before measurement. Concentrations were determined on a mass basis ({micro}g U/g of solution), but no density corrections were needed since all the samples (including the samples used for calibration) were in the same density matrix (1 M HNO{sub 3}). A statistical evaluation of the determination of uranium using kinetic phosphorimetry is described in this report, along with a discussion of the method, and an evaluation of the use of plastic versus quartz cuvettes. Measurement with a precision of {+-} 3--4% relative standard deviation (RSD) and an accuracy of better than {+-} 2% relative difference (RD) are obtained in the 0.0006 to 5 {micro}g U/g-solution range. The instrument detection limit is 0.04 ppb (4 x 10{sup {minus}5} {micro}g U/g solution) using quartz cells, and 0.11 ppb (11 x 10{sup {minus}5} {micro}g U/g solution) using disposable methacrylate cuvettes.

  1. Microsecond Microfluidic Mixing for Investigation of Protein Folding Kinetics

    SciTech Connect (OSTI)

    Hertzog, D E; Santiago, J G; Bakajin, O

    2005-02-10

    We have developed and characterized a mixer to study the reaction kinetics of protein folding on a microsecond timescale. The mixer uses hydrodynamic focusing of pressure-driven flow in a microfluidic channel to reduce diffusion times as first demonstrated by Knight et al.[1]. Features of the mixer include 1 {micro}s mixing times, sample consumptions of order 1 nl/s, loading sample volumes on the order of microliters, and the ability to manufacture in fused silica for compatibility with most spectroscopic methods.

  2. Bio-butanol: Combustion properties and detailed chemical kinetic model

    SciTech Connect (OSTI)

    Black, G.; Curran, H.J.; Pichon, S.; Simmie, J.M.; Zhukov, V.

    2010-02-15

    Autoignition delay time measurements were performed at equivalence ratios of 0.5, 1 and 2 for butan-1-ol at reflected shock pressures of 1, 2.6 and 8 atm at temperatures from 1100 to 1800 K. High-level ab initio calculations were used to determine enthalpies of formation and consequently bond dissociation energies for each bond in the alcohol. A detailed chemical kinetic model consisting of 1399 reactions involving 234 species was constructed and tested against the delay times and also against recent jet-stirred reactor speciation data with encouraging results. The importance of enol chemistry is highlighted. (author)

  3. Convergent synthesis of proteins by kinetically controlled ligation

    DOE Patents [OSTI]

    Kent, Stephen (Chicago, IL); Pentelute, Brad (Chicago, IL); Bang, Duhee (Boston, MA); Johnson, Erik (Chicago, IL); Durek, Thomas (Chicago, IL)

    2010-03-09

    The present invention concerns methods and compositions for synthesizing a polypeptide using kinetically controlled reactions involving fragments of the polypeptide for a fully convergent process. In more specific embodiments, a ligation involves reacting a first peptide having a protected cysteyl group at its N-terminal and a phenylthioester at its C-terminal with a second peptide having a cysteine residue at its N-termini and a thioester at its C-termini to form a ligation product. Subsequent reactions may involve deprotecting the cysteyl group of the resulting ligation product and/or converting the thioester into a thiophenylester.

  4. Uranium and Strontium Batch Sorption and Diffusion Kinetics into Mesoporous

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Silica | Stanford Synchrotron Radiation Lightsource Uranium and Strontium Batch Sorption and Diffusion Kinetics into Mesoporous Silica Friday, February 27, 2015 Figure 1 Figure 1. Transmission electron microscopy images of (A) washed, unreacted mesoporous silica (insert: cross section of a particle exhibiting the regular channel array structure), and mesoporous silica reacted with (B) 10 µM Sr, (C) 10 µM U at pH 4.0 with no carbonate and no calcium present, and (D) 10 µM U at pH 9.8 with

  5. Chemical Kinetics in Support of Syngas Turbine Combustion

    SciTech Connect (OSTI)

    Dryer, Frederick

    2007-07-31

    This document is the final report on an overall program formulated to extend our prior work in developing and validating kinetic models for the CO/hydrogen/oxygen reaction by carefully analyzing the individual and interactive behavior of specific elementary and subsets of elementary reactions at conditions of interest to syngas combustion in gas turbines. A summary of the tasks performed under this work are: 1. Determine experimentally the third body efficiencies in H+O{sub 2}+M = HO{sub 2}+M (R1) for CO{sub 2} and H{sub 2}O. 2. Using published literature data and the results in this program, further develop the present H{sub 2}/O{sub 2}/diluent and CO/H{sub 2}/O{sub 2}/diluent mechanisms for dilution with CO{sub 2}, H{sub 2}O and N{sub 2} through comparisons with new experimental validation targets for H{sub 2}-CO-O{sub 2}-N{sub 2} reaction kinetics in the presence of significant diluent fractions of CO{sub 2} and/or H{sub 2}O, at high pressures. (task amplified to especially address ignition delay issues, see below). 3. Analyze and demonstrate issues related to NOx interactions with syngas combustion chemistry (task amplified to include interactions of iron pentacarbonyl with syngas combustion chemistry, see below). 4. Publish results, including updated syngas kinetic model. Results are summarized in this document and its appendices. Three archival papers which contain a majority of the research results have appeared. Those results not published elsewhere are highlighted here, and will appear as part of future publications. Portions of the work appearing in the above publications were also supported in part by the Department of Energy under Grant No. DE-FG02-86ER-13503. As a result of and during the research under the present contract, we became aware of other reported results that revealed substantial differences between experimental characterizations of ignition delays for syngas mixtures and ignition delay predictions based upon homogenous kinetic modeling. We adjusted emphasis of Task 2 to understand the source of these noted disparities because of their key importance to developing lean premixed combustion technologies of syngas turbine applications. In performing Task 3, we also suggest for the first time the very significant effect that metal carbonyls may have on syngas combustion properties. This work is fully detailed. The work on metal carbonyl effects is entirely computational in nature. Pursuit of experimental verification of these interactions was beyond the scope of the present work.

  6. Non-minimal Kinetic coupling to gravity and accelerated expansion

    SciTech Connect (OSTI)

    Granda, L.N.

    2010-07-01

    We study a scalar field with kinetic term coupled to itself and to the curvature, as a source of dark energy, and analyze the role of this new coupling in the accelerated expansion at large times. In the case of scalar field dominance, the scalar field and potential giving rise to power-law expansion are found in some cases, and a dynamical equation of state is calculated for a given solution of the field equations. A behavior very close to that of the cosmological constant was found.

  7. Thermodynamic and kinetic control of the lateral Si wire growth

    SciTech Connect (OSTI)

    Dedyulin, Sergey N. Goncharova, Lyudmila V.

    2014-03-24

    Reproducible lateral Si wire growth has been realized on the Si (100) surface. In this paper, we present experimental evidence showing the unique role that carbon plays in initiating lateral growth of Si wires on a Si (100) substrate. Once initiated in the presence of ?5 ML of C, lateral growth can be achieved in the range of temperatures, T?=?450650?C, and further controlled by the interplay of the flux of incoming Si atoms with the size and areal density of Au droplets. Critical thermodynamic and kinetic aspects of the growth are discussed in detail.

  8. Characterization of a two-dimensional liquid-filled ion chamber detector array used for verification of the treatments in radiotherapy

    SciTech Connect (OSTI)

    Markovic, Miljenko Stathakis, Sotirios; Mavroidis, Panayiotis; Jurkovic, Ines-Ana; Papanikolaou, Nikos

    2014-05-15

    Purpose: The purpose of the study is to investigate the characteristics of a two-dimensional (2D) liquid-filled ion chamber detector array, which is used for the verification of radiotherapy treatment plans that use small field sizes of up to 10 10 cm. Methods: The device used in this study was Octavius 1000 SRS model (PTW, Freiburg, Germany). Its 2D array of detectors consists of 977 liquid-filled ion chambers arranged over an area of 11 11 cm. The size of the detectors is 2.3 2.3 0.5 mm (volume of 0.003 cm{sup 3}) and their spacing in the inner area of 5.5 5.5 cm is 2.5 mm center-to-center, whereas in the outer area it is 5 mm center-to-center. The detector reproducibility, dose linearity, and sensitivity to positional changes of the collimator were tested. Also, the output factors of field sizes ranging from 0.5 0.5 to 10 10 cm{sup 2} both for open and wedged fields have been measured and compared against those measured by a pin-point ionization chamber, liquid filled microchamber, SRS diode, and EDR2 film. Results: Its short-term reproducibility was within 0.2% and its medium and long-term reproducibility was within 0.5% (verified with air ionization chamber absolute dose measurements), which is an excellent result taking into account the daily fluctuation of the linear accelerator and the errors in the device setup reproducibility. The dose linearity and dose rate dependence were measured in the range of 0.585 Gy and 0.510 Gy?min{sup ?1}, respectively, and were verified with air ionization chamber absolute dose measurements was within 3%. The measurements of the sensitivity showed that the 2D Array could detect millimetric collimator positional changes. The measured output factors showed an agreement of better than 0.3% with the pinpoint chamber and microliquid filled chamber for the field sizes between 3 3 and 10 10 cm{sup 2}. For field sizes down to 1 1 cm{sup 2}, the agreement with SRS diode and microliquid filled chamber is better than 2%. The measurements of open and wedge-modulated field profiles were compared to the film and ionization chamber in water measurements. Conclusions: The Octavius Detector 1000 SRS is an accurate, precise, and reliable detector, very useful for the daily performance of the patient specific quality assurance of radiotherapy treatment plans.

  9. The generalized SchrdingerLangevin equation

    SciTech Connect (OSTI)

    Bargueo, Pedro; Miret-Arts, Salvador

    2014-07-15

    In this work, for a Brownian particle interacting with a heat bath, we derive a generalization of the so-called SchrdingerLangevin or Kostin equation. This generalization is based on a nonlinear interaction model providing a state-dependent dissipation process exhibiting multiplicative noise. Two straightforward applications to the measurement process are then analyzed, continuous and weak measurements in terms of the quantum Bohmian trajectory formalism. Finally, it is also shown that the generalized uncertainty principle, which appears in some approaches to quantum gravity, can be expressed in terms of this generalized equation. -- Highlights: We generalize the Kostin equation for arbitrary systembath coupling. This generalization is developed both in the Schrdinger and Bohmian formalisms. We write the generalized Kostin equation for two measurement problems. We reformulate the generalized uncertainty principle in terms of this equation.

  10. Princeton Plasma Physics Lab - General Atomics (GA)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    general-atomics-ga General Atomics en The Scorpion's Strategy: "Catch and Subdue" http:www.pppl.govnode1132

  11. Fermilab Office of General Counsel - Contact Us

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Contact Us General Counsel John Myer Deputy General Counsel Beth Fancsali Office Administrator Karen Bormann Administrative Support Georgianna Amundson Telephone Number (630) 840-3572 Facsimile Number (630) 840-8390 Department Office Wilson Hall, 4 West

  12. Unclassified Controlled Nuclear Information General Guideline...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Unclassified Controlled Nuclear Information General Guideline GG-5, is a record of decisions made by the Director, OC, as to what general subject areas are UCNI. Note: GG-5 may ...

  13. Multi-Sector General Permit (MSGP)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    MSGP Multi-Sector General Permit (MSGP) The Multi-Sector General Permit authorizes the discharge of stormwater associated with industrial activity. What's New Documents submitted to EPRR in last 30 Days TBD What is the Multi-Sector General Permit? Storm water discharges from EPA specified industrial activities are regulated under the National Pollutant Discharge Elimination System (NPDES) Multi-Sector General Permit (MSGP). LANL regulated industrial activities include: Metal fabrication Power

  14. Montana Construction Dewatering General Permit Application Information...

    Open Energy Info (EERE)

    overview of Construction Dewatering General Permit process. Author Montana Department of Environmental Quality - Water Protection Bureau Published Montana Department of...

  15. EPA - National Pollutant Discharge Elimination System General...

    Open Energy Info (EERE)

    This guidebook outlines the requirements for Construction General Permits issued from the Environmental Protection Agency. Author Environmental Protection Agency Published...

  16. Workplace Charging Challenge Partner: Portland General Electric |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Portland General Electric Workplace Charging Challenge Partner: Portland General Electric Workplace Charging Challenge Partner: Portland General Electric Since the late 1990s, Portland General Electric (PGE) has offered plug-in electric vehicle (PEV) charging for its employees. With the advent of the modern Level 2 and DC Quick-Charging standards, PGE embarked on an ambitious workplace charging expansion program. Over the past four years, PGE has installed 38 PEV

  17. Generalized Comprehensive Mitigation Assessment Process (GCOMAP...

    Open Energy Info (EERE)

    search Tool Summary LAUNCH TOOL Name: Generalized Comprehensive Mitigation Assessment Process (GCOMAP) AgencyCompany Organization: Lawrence Berkeley National Laboratory...

  18. General Privacy Act Guidance | Department of Energy

    Energy Savers [EERE]

    Privacy Act Guidance General Privacy Act Guidance This document provides information on Privacy Act Requests and responses to general FAQs PDF icon General Privacy Act Guidance More Documents & Publications DEPARTMENT OF ENERGY Privacy Awareness Training Visiting Speaker Program - October 28, 2009 DOE F 531

  19. Solar kinetics` photovoltaic concentrator module and tracker development

    SciTech Connect (OSTI)

    White, D.L.; Howell, B. [Solar Kinetics, Inc., Dallas, TX (United States)

    1995-11-01

    Solar Kinetics, Inc., has been developing a point-focus concentrating photovoltaic module and tracker system under contract to Sandia National Laboratories. The primary focus of the contract was to achieve a module design that was manufacturable and passed Sandia`s environmental testing. Nine modules of two variations were assembled, tested, and characterized in Phase 1, and results of these tests were promising, with module efficiency approaching the theoretical limit achievable with the components used. The module efficiency was 11.9% at a solar irradiance of 850 W/m{sup 2} and an extrapolated cell temperature of 25{degrees}C. Improvements in module performance are anticipated as cell efficiencies meet their expectations. A 2-kW tracker and controller accommodating 20 modules was designed, built, installed, and operated at Solar Kinetics` test site. The drive used many commercially available components in an innovative arrangement to reduce cost and increase reliability. Backlash and bearing play were controlled by use of preloaded, low slip-stick, synthetic slide bearings. The controller design used a standard industrial programmable logic controller to perform ephemeris calculations, operate the actuators, and monitor encoders.

  20. Kinetics and deactivation of sulfated zirconia catalysts for butane isomerization

    SciTech Connect (OSTI)

    Fogash, K.B.; Larson, R.B.; Gonzalez, M.R.

    1996-09-15

    Reaction kinetics studies were conducted of n-butane and isobutane isomerization over sulfated zirconia at 423 K. The kinetic data can be described well by a rate expression based on a reversible, bimolecular surface reaction between two adsorbed n-C{sub 4} species, probably through a C{sub 8} intermediate, to produce one i-C{sub 4} species, as well as surface reaction between two adsorbed i-C{sub 4} species to produce one n-C{sub 4} species. This reaction sequence also describes well the rates of C{sub 4}-disproportionation reactions to produce C{sub 3} and C{sub 5} species. The initial rate of catalyst deactivation is faster during n-butane isomerization than during isobutane isomerization, and the longer-term rate of deactivation during n-butane isomerization increases with the pressures of n-butane. The more rapid catalyst deactivation during n-butane isomerization may be related to the formation of n-C{sub 4}-diene species. 25 refs., 10 figs., 4 tabs.

  1. Kinetic neoclassical transport in the H-mode pedestal

    SciTech Connect (OSTI)

    Battaglia, D. J.; Chang, C. S.; Ku, S.; Grierson, B. A.; Burrell, K. H.; Grassie, J. S. de

    2014-07-15

    Multi-species kinetic neoclassical transport through the QH-mode pedestal and scrape-off layer on DIII-D is calculated using XGC0, a 5D full-f particle-in-cell drift-kinetic solver with self-consistent neutral recycling and sheath potentials. Quantitative agreement between the flux-driven simulation and the experimental electron density, impurity density, and orthogonal measurements of impurity temperature and flow profiles is achieved by adding random-walk particle diffusion to the guiding-center drift motion. The radial electric field (E{sub r}) that maintains ambipolar transport across flux surfaces and to the wall is computed self-consistently on closed and open magnetic field lines and is in excellent agreement with experiment. The E{sub r} inside the separatrix is the unique solution that balances the outward flux of thermal tail deuterium ions against the outward neoclassical electron flux and inward pinch of impurity and colder deuterium ions. Particle transport in the pedestal is primarily due to anomalous transport, while the ion heat and momentum transport are primarily due to the neoclassical transport. The full-f treatment quantifies the non-Maxwellian energy distributions that describe a number of experimental observations in low-collisionallity pedestals on DIII-D, including intrinsic co-I{sub p} parallel flows in the pedestal, ion temperature anisotropy, and large impurity temperatures in the scrape-off layer.

  2. Adding kinetics and hydrodynamics to the CHEETAH thermochemical code

    SciTech Connect (OSTI)

    Fried, L.E., Howard, W.M., Souers, P.C.

    1997-01-15

    In FY96 we released CHEETAH 1.40, which made extensive improvements on the stability and user friendliness of the code. CHEETAH now has over 175 users in government, academia, and industry. Efforts have also been focused on adding new advanced features to CHEETAH 2.0, which is scheduled for release in FY97. We have added a new chemical kinetics capability to CHEETAH. In the past, CHEETAH assumed complete thermodynamic equilibrium and independence of time. The addition of a chemical kinetic framework will allow for modeling of time-dependent phenomena, such as partial combustion and detonation in composite explosives with large reaction zones. We have implemented a Wood-Kirkwood detonation framework in CHEETAH, which allows for the treatment of nonideal detonations and explosive failure. A second major effort in the project this year has been linking CHEETAH to hydrodynamic codes to yield an improved HE product equation of state. We have linked CHEETAH to 1- and 2-D hydrodynamic codes, and have compared the code to experimental data. 15 refs., 13 figs., 1 tab.

  3. Simulating flame lift-off characteristics of diesel and biodiesel fuels using detailed chemical-kinetic mechanisms and LES turbulence model.

    SciTech Connect (OSTI)

    Som, S; Longman, D. E.; Luo, Z; Plomer, M; Lu, T; Senecal, P.K.; Pomraning, E

    2012-01-01

    Combustion in direct-injection diesel engines occurs in a lifted, turbulent diffusion flame mode. Numerous studies indicate that the combustion and emissions in such engines are strongly influenced by the lifted flame characteristics, which are in turn determined by fuel and air mixing in the upstream region of the lifted flame, and consequently by the liquid breakup and spray development processes. From a numerical standpoint, these spray combustion processes depend heavily on the choice of underlying spray, combustion, and turbulence models. The present numerical study investigates the influence of different chemical kinetic mechanisms for diesel and biodiesel fuels, as well as Reynolds-averaged Navier-Stokes (RANS) and large eddy simulation (LES) turbulence models on predicting flame lift-off lengths (LOLs) and ignition delays. Specifically, two chemical kinetic mechanisms for n-heptane (NHPT) and three for biodiesel surrogates are investigated. In addition, the RNG k-{epsilon} (RANS) model is compared to the Smagorinsky based LES turbulence model. Using adaptive grid resolution, minimum grid sizes of 250 {micro}m and 125 {micro}m were obtained for the RANS and LES cases respectively. Validations of these models were performed against experimental data from Sandia National Laboratories in a constant volume combustion chamber. Ignition delay and flame lift-off validations were performed at different ambient temperature conditions. The LES model predicts lower ignition delays and qualitatively better flame structures compared to the RNG k-{epsilon} model. The use of realistic chemistry and a ternary surrogate mixture, which consists of methyl decanoate, methyl 9-decenoate, and NHPT, results in better predicted LOLs and ignition delays. For diesel fuel though, only marginal improvements are observed by using larger size mechanisms. However, these improved predictions come at a significant increase in computational cost.

  4. Evaluating temperature and fuel stratification for heat-release rate control in a reactivity-controlled compression-ignition engine using optical diagnostics and chemical kinetics modeling

    SciTech Connect (OSTI)

    Musculus, Mark P. B.; Kokjohn, Sage L.; Reitz, Rolf D.

    2015-04-23

    We investigated the combustion process in a dual-fuel, reactivity-controlled compression-ignition (RCCI) engine using a combination of optical diagnostics and chemical kinetics modeling to explain the role of equivalence ratio, temperature, and fuel reactivity stratification for heat-release rate control. An optically accessible engine is operated in the RCCI combustion mode using gasoline primary reference fuels (PRF). A well-mixed charge of iso-octane (PRF = 100) is created by injecting fuel into the engine cylinder during the intake stroke using a gasoline-type direct injector. Later in the cycle, n-heptane (PRF = 0) is delivered through a centrally mounted diesel-type common-rail injector. This injection strategy generates stratification in equivalence ratio, fuel blend, and temperature. The first part of this study uses a high-speed camera to image the injection events and record high-temperature combustion chemiluminescence. Moreover, the chemiluminescence imaging showed that, at the operating condition studied in the present work, mixtures in the squish region ignite first, and the reaction zone proceeds inward toward the center of the combustion chamber. The second part of this study investigates the charge preparation of the RCCI strategy using planar laser-induced fluorescence (PLIF) of a fuel tracer under non-reacting conditions to quantify fuel concentration distributions prior to ignition. The fuel-tracer PLIF data show that the combustion event proceeds down gradients in the n-heptane distribution. The third part of the study uses chemical kinetics modeling over a range of mixtures spanning the distributions observed from the fuel-tracer fluorescence imaging to isolate the roles of temperature, equivalence ratio, and PRF number stratification. The simulations predict that PRF number stratification is the dominant factor controlling the ignition location and growth rate of the reaction zone. Equivalence ratio has a smaller, but still significant, influence. Lastly, temperature stratification had a negligible influence due to the NTC behavior of the PRF mixtures.

  5. KINETIC MODELING OF FUEL EFFECTS OVER A WIDE RANGE OF CHEMISTRY,

    Office of Scientific and Technical Information (OSTI)

    PROPERTIES, AND SOURCES (Conference) | SciTech Connect KINETIC MODELING OF FUEL EFFECTS OVER A WIDE RANGE OF CHEMISTRY, PROPERTIES, AND SOURCES Citation Details In-Document Search Title: KINETIC MODELING OF FUEL EFFECTS OVER A WIDE RANGE OF CHEMISTRY, PROPERTIES, AND SOURCES Kinetic modeling is an important tool for engine design and can also be used for engine tuning and to study response to fuel chemistry and properties before an engine configuration is physically built and tested.

  6. Chemical Kinetic Research on HCCI & Diesel Fuels | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon ace013_pitz_2012_o.pdf More Documents & Publications Simulation of High Efficiency Clean Combustion Engines and Detailed Chemical Kinetic Mechanisms Development Chemical Kinetic Research on HCCI & Diesel Fuels Vehicle Technologies Office Merit Review 2014: Chemical Kinetic Models for Advanced Engine Combustion

  7. Coupled Kinetic, Thermal, and Mechanical Modeling of FIB Micro-machined

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Electrodes | Department of Energy Coupled Kinetic, Thermal, and Mechanical Modeling of FIB Micro-machined Electrodes Coupled Kinetic, Thermal, and Mechanical Modeling of FIB Micro-machined Electrodes 2010 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C. PDF icon es093_daniel_2010_p.pdf More Documents & Publications Intercalation Kinetics and Ion Mobility in Electrode Materials for Advanced Lithium Ion

  8. CLEERS Coordination & Joint Development of Benchmark Kinetics for LNT & SCR

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    | Department of Energy 1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon ace022_daw_2011_o.pdf More Documents & Publications CLEERS Coordination & Joint Development of Benchmark Kinetics for LNT & SCR CLEERS Coordination & Development of Catalyst Process Kinetic Data CLEERS Coordination & Joint Development of Benchmark Kinetics for LNT & SCR

  9. Chemical Kinetic Research on HCCI & Diesel Fuels | Department of Energy

    Office of Environmental Management (EM)

    0 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C. PDF icon ace013_pitz_2010_o.pdf More Documents & Publications Chemical Kinetics Research on HCCI and Diesel Fuels Chemical Kinetic Research on HCCI & Diesel Fuels Vehicle Technologies Office Merit Review 2014: Chemical Kinetic Models for Advanced Engine Combustion

  10. Density functional theory based generalized effective fragment potential method

    SciTech Connect (OSTI)

    Nguyen, Kiet A. E-mail: ruth.pachter@wpafb.af.mil; Pachter, Ruth E-mail: ruth.pachter@wpafb.af.mil; Day, Paul N.

    2014-06-28

    We present a generalized Kohn-Sham (KS) density functional theory (DFT) based effective fragment potential (EFP2-DFT) method for the treatment of solvent effects. Similar to the original Hartree-Fock (HF) based potential with fitted parameters for water (EFP1) and the generalized HF based potential (EFP2-HF), EFP2-DFT includes electrostatic, exchange-repulsion, polarization, and dispersion potentials, which are generated for a chosen DFT functional for a given isolated molecule. The method does not have fitted parameters, except for implicit parameters within a chosen functional and the dispersion correction to the potential. The electrostatic potential is modeled with a multipolar expansion at each atomic center and bond midpoint using Stone's distributed multipolar analysis. The exchange-repulsion potential between two fragments is composed of the overlap and kinetic energy integrals and the nondiagonal KS matrices in the localized molecular orbital basis. The polarization potential is derived from the static molecular polarizability. The dispersion potential includes the intermolecular D3 dispersion correction of Grimme et al. [J. Chem. Phys. 132, 154104 (2010)]. The potential generated from the CAMB3LYP functional has mean unsigned errors (MUEs) with respect to results from coupled cluster singles, doubles, and perturbative triples with a complete basis set limit (CCSD(T)/CBS) extrapolation, of 1.7, 2.2, 2.0, and 0.5 kcal/mol, for the S22, water-benzene clusters, water clusters, and n-alkane dimers benchmark sets, respectively. The corresponding EFP2-HF errors for the respective benchmarks are 2.41, 3.1, 1.8, and 2.5 kcal/mol. Thus, the new EFP2-DFT-D3 method with the CAMB3LYP functional provides comparable or improved results at lower computational cost and, therefore, extends the range of applicability of EFP2 to larger system sizes.

  11. New structural limits on magma chamber locations at the Valley of Ten Thousand Smokes, Katmai National Park, Alaska

    SciTech Connect (OSTI)

    Wallmann, P.C.; Pollard, D.D. ); Hildreth, W. ); Eichelberger, J.C. )

    1990-12-01

    New structural data from the Novarupta basin, Katmai National Park, Alaska, site of the largest volcanic eruption of this century (1912), provide limits for the location of magma chambers associated with this eruption. To investigate the subsurface structure of the 1912 vents, and to support an interdisciplinary study of this young volcanic system, a project of geologic mapping of surficial and bedrock structures in the vent region of the 1912 eruption has been undertaken. Landslide scarps, arcuate grabens, a monoclinal fold, and truncated ridges circumscribe the Novarupta basin, marking the inferred outer rim of the vent. A set of radial fissures crosses the southern margin of the basin, striking {approximately}140{degree}, subparallel to the dominant bedrock joint set. These fissures and joints, along with the local plate-motion vector and the inferred regional stress orientation, are consistent with a feeder dike propagating from a reservoir beneath Trident volcano to the eruptive vent.

  12. An Integrated Front-End Readout And Feature Extraction System for the BaBar Drift Chamber

    SciTech Connect (OSTI)

    Zhang, Jinlong; /Colorado U.

    2006-08-10

    The BABAR experiment has been operating at SLAC's PEP-II asymmetric B-Factory since 1999. The accelerator has achieved more than three times its original design luminosity of 3 x 10{sup 33} cm{sup -2} s{sup -1}, with plans for an additional factor of three in the next two years. To meet the experiment's performance requirements in the face of significantly higher trigger and background rates, the drift chamber's front-end readout system has been redesigned around the Xilinx Spartan 3 FPGA. The new system implements analysis and feature-extraction of digitized waveforms in the front-end, reducing the data bandwidth required by a factor of four.

  13. Summary of the Second Workshop on Liquid Argon Time Projection Chamber Research and Development in the United States

    SciTech Connect (OSTI)

    Acciarri, R.; et al.

    2015-04-21

    The second workshop to discuss the development of liquid argon time projection chambers (LArTPCs) in the United States was held at Fermilab on July 8-9, 2014. The workshop was organized under the auspices of the Coordinating Panel for Advanced Detectors, a body that was initiated by the American Physical Society Division of Particles and Fields. All presentations at the workshop were made in six topical plenary sessions: i) Argon Purity and Cryogenics, ii) TPC and High Voltage, iii) Electronics, Data Acquisition and Triggering, iv) Scintillation Light Detection, v) Calibration and Test Beams, and vi) Software. This document summarizes the current efforts in each of these areas. It primarily focuses on the work in the US, but also highlights work done elsewhere in the world.

  14. Levitation and collection of diamond fine particles in the rf plasma chamber equipped with a hot filament

    SciTech Connect (OSTI)

    Shimizu, S.; Shimizu, T.; Thomas, H. M.; Morfill, G. E.; Jacob, W.

    2011-11-15

    We demonstrate the levitation of diamond fine particles in a H{sub 2} rf plasma chamber equipped with a hot filament and heated electrodes. The levitation conditions should be carefully chosen to compensate the strong thermophoretic forces caused by the filament and the electrodes. This levitation technique with the existence of a hot filament can be applied, e.g., for the efficient growth of diamond layers on seed particles injected and levitated in an rf plasma with reactive gases, e.g., CH{sub 4}/H{sub 2}. Additionally, the method for direct capture of levitated particles on a planar substrate was established, which is useful if it is necessary to analyze the particles after the levitation.

  15. Office of the Assistant General Counsel for General Law | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Services » Environment and Compliance » Office of the Assistant General Counsel for General Law Office of the Assistant General Counsel for General Law The Office of the Assistant General Counsel for General Law (GC-56) provides legal support for non-programmatic issues other than those involving procurement and intellectual property. The office serves as program counsel for the Offices of the Chief Financial Officer, Human Capital Management, Management and Administration (with the

  16. SU-E-T-242: Monte Carlo Simulations Used to Test the Perturbation of a Reference Ion Chamber Prototype Used for Small Fields

    SciTech Connect (OSTI)

    Vazquez Quino, L; Calvo, O; Huerta, C; DeWeese, M

    2014-06-01

    Purpose: To study the perturbation due to the use of a novel Reference Ion Chamber designed to measure small field dosimetry (KermaX Plus C by IBA). Methods: Using the Phase-space files for TrueBeam photon beams available by Varian in IAEA-compliant format for 6 and 15 MV. Monte Carlo simulations were performed using BEAMnrc and DOSXYZnrc to investigate the perturbation introduced by a reference chamber into the PDDs and profiles measured in water tank. Field sizes ranging from 11, 22,33, 55 cm2 were simulated for both energies with and without a 0.5 mm foil of Aluminum which is equivalent to the attenuation equivalent of the reference chamber specifications in a water phantom of 303030 cm3 and a pixel resolution of 2 mm. The PDDs, profiles, and gamma analysis of the simulations were performed as well as a energy spectrum analysis of the phase-space files generated during the simulation. Results: Examination of the energy spectrum analysis performed shown a very small increment of the energy spectrum at the build-up region but no difference is appreciated after dmax. The PDD, profiles and gamma analysis had shown a very good agreement among the simulations with and without the Al foil, with a gamma analysis with a criterion of 2% and 2mm resulting in 99.9% of the points passing this criterion. Conclusion: This work indicates the potential benefits of using the KermaX Plus C as reference chamber in the measurement of PDD and Profiles for small fields since the perturbation due to in the presence of the chamber the perturbation is minimal and the chamber can be considered transparent to the photon beam.

  17. KineticsFinal Report Cover Page Bakajin, O 59 BASIC BIOLOGICAL...

    Office of Scientific and Technical Information (OSTI)

    KineticsFinal Report Cover Page Bakajin, O 59 BASIC BIOLOGICAL SCIENCES; 42 ENGINEERING; CONSUMPTION RATES; DEAD TIME; DETECTION; DIFFUSION; DNA; ENERGY TRANSFER; FABRICATION;...

  18. Hydrolysis of late-washed, irradiated tetraphenylborate slurry simulants I: Phenylboric acid hydrolysis kinetics

    SciTech Connect (OSTI)

    Marek, J.C.

    2000-02-10

    The attached report details the kinetics of phenylboric acid reaction at 90 degrees C during precipitate hydrolysis processing of late-washed, irradiated tetraphenylborate slurry simulants.

  19. Photoelectrochemical etching of epitaxial InGaN thin films: kinetics...

    Office of Scientific and Technical Information (OSTI)

    films: kinetics and nanostructuring. Abstract not provided. Authors: Xiao, Xiaoyin ; Fischer, Arthur J. ; Coltrin, Michael E. ; Lu, Ping ; Koleske, Daniel ; Wang, George T. ;...

  20. KINETIC MODELING OF FUEL EFFECTS OVER A WIDE RANGE OF CHEMISTRY...

    Office of Scientific and Technical Information (OSTI)

    A WIDE RANGE OF CHEMISTRY, PROPERTIES, AND SOURCES Citation Details In-Document Search Title: KINETIC MODELING OF FUEL EFFECTS OVER A WIDE RANGE OF CHEMISTRY, PROPERTIES, AND ...