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Note: This page contains sample records for the topic "kinetic en ergy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

MinnErgy LLC | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to:46 -Energieprojekte GmbHMilo, Maine: EnergyMinnErgy LLC Jump to: navigation, search

2

SunErgy AE | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 No revisionEnvReviewNonInvasiveExplorationUT-g GrantAtlas (PACAOpenSummerside Wind Farm JumpVenturesSunErgy AE Jump

3

use of renewable en-ergy options generally  

E-Print Network [OSTI]

regulation is underway. Oregon, for example, requires new power plants to offset their carbon emissions for carbon diox- ide, could increase compliance costs in the near future. Under the recently ratified Kyoto

Delaware, University of

4

Kinetic Alfv'en Eigenmodes in a Hot Tokamak Plasma  

E-Print Network [OSTI]

'en waves, with a power absorption occurring through resistive dissipation. The kinetic model is appropriate­100 44 Stockholm, Sweden 2 CRPP­EPFL, CH­1015 Lausanne, Switzerland 3 JET Joint Undertaking, Abingdon Resonant destabilization of Alfv'en waves by fusion produced ff\\Gammaparticles is an important issue

Jaun, André

5

University of Delaware EnErgy InstItUtE syMPOsIUM  

E-Print Network [OSTI]

Institute, and Symposium Objectives Mark A. Barteau Director, UD Energy Institute The Sustainable Energy. Birkmire Director, Institute of Energy Conversion Solar Demonstration Project Robin Morgan Dean for High Energy and Power Density I George Hadjipanayis Chair, Physics and Astronomy Novel Materials

Firestone, Jeremy

6

Applied Numerical Mathematics 68 (2013) 5872 Contents lists available at SciVerse ScienceDirect  

E-Print Network [OSTI]

. The experiments reported here indicate that the efficiency of our new schemes is clearly superior to previous H(q, p) = T (p)+ U(q), where the potential en- ergy U(q) depends on positions and the kinetic energy solution of a modified Hamiltonian. Moreover, although the energy is not conserved along the trajectory

Blanes, Sergio

7

Drift-/ Kinetic Alfven Eigenmodes in High Performance Tokamak Plasmas  

E-Print Network [OSTI]

Stockholm, Sweden 2) Plasma Science Fusion Centre, MIT, Cambridge MA 02139, USA 3) CRPP-EPFL, 1015 Lausanne to the kinetic Alfv´en wave. This stimulated the development of models such as continuum damping, complex-kinetic description for the bulk plasma. Such a model is required to calculate the power transfer between global fluid

Jaun, André

8

UC Energy Week 2010 May 10-12, 2010  

E-Print Network [OSTI]

UC Energy Week 2010 May 10-12, 2010 Inventing a New Energy Future Biomass Energy Geothermal Energy Solar Energy Wind Energy & Integrated Renewables InventIng a new energy Future UC EnErgy WEEk 2010 May 10­12, 2010 rgy intEgratEd rEnEWaBlEs Biomass EnErgy gEothErmal En nErgy gEothErmal EnErgy

9

Nonequilibrium quantum kinetics  

SciTech Connect (OSTI)

This paper contains viewgraphs on non-equilibrium quantum kinetics of nuclear reactions at the intermediate and high energy ranges.

Danielewicz, P.

1997-09-22T23:59:59.000Z

10

BIOLOGY AND MEDICINE DIVISION ANNUAL REPORT 1979-1980  

E-Print Network [OSTI]

deposit ~ 8000 times more en- ergy per unit length than an energetic proton, but will have a residual

Authors, Various

2013-01-01T23:59:59.000Z

11

Accurate Energy Attribution and Accounting for Multi-core Systems  

E-Print Network [OSTI]

us- age information. Our system utilizes runtime direct en- ergy measurements that provide accurate per-component energy usage

Ryffel, Sebi; Stathopoulos, Thanos; McIntire, Dustin; Kaiser, William; Thiele, Lothar

2009-01-01T23:59:59.000Z

12

Erbium hydride decomposition kinetics.  

SciTech Connect (OSTI)

Thermal desorption spectroscopy (TDS) is used to study the decomposition kinetics of erbium hydride thin films. The TDS results presented in this report are analyzed quantitatively using Redhead's method to yield kinetic parameters (E{sub A} {approx} 54.2 kcal/mol), which are then utilized to predict hydrogen outgassing in vacuum for a variety of thermal treatments. Interestingly, it was found that the activation energy for desorption can vary by more than 7 kcal/mol (0.30 eV) for seemingly similar samples. In addition, small amounts of less-stable hydrogen were observed for all erbium dihydride films. A detailed explanation of several approaches for analyzing thermal desorption spectra to obtain kinetic information is included as an appendix.

Ferrizz, Robert Matthew

2006-11-01T23:59:59.000Z

13

Kinetic theory viscosity  

E-Print Network [OSTI]

We show how the viscous evolution of Keplerian accretion discs can be understood in terms of simple kinetic theory. Although standard physics texts give a simple derivation of momentum transfer in a linear shear flow using kinetic theory, many authors, as detailed by Hayashi & Matsuda 2001, have had difficulties applying the same considerations to a circular shear flow. We show here how this may be done, and note that the essential ingredients are to take proper account of, first, isotropy locally in the frame of the fluid and, second, the geometry of the mean flow.

C. J. Clarke; J. E. Pringle

2004-03-17T23:59:59.000Z

14

Molecular Beam Kinetics | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas Conchas recovery challenge fundProject8Mistakes to AvoidKinetics Molecular Beam Kinetics

15

LLNL Chemical Kinetics Modeling Group  

SciTech Connect (OSTI)

The LLNL chemical kinetics modeling group has been responsible for much progress in the development of chemical kinetic models for practical fuels. The group began its work in the early 1970s, developing chemical kinetic models for methane, ethane, ethanol and halogenated inhibitors. Most recently, it has been developing chemical kinetic models for large n-alkanes, cycloalkanes, hexenes, and large methyl esters. These component models are needed to represent gasoline, diesel, jet, and oil-sand-derived fuels.

Pitz, W J; Westbrook, C K; Mehl, M; Herbinet, O; Curran, H J; Silke, E J

2008-09-24T23:59:59.000Z

16

Improving alternative fuel utilization: detailed kinetic combustion...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Improving alternative fuel utilization: detailed kinetic combustion modeling & experimental testing Improving alternative fuel utilization: detailed kinetic combustion modeling &...

17

Chemical kinetics modeling  

SciTech Connect (OSTI)

This project emphasizes numerical modeling of chemical kinetics of combustion, including applications in both practical combustion systems and in controlled laboratory experiments. Elementary reaction rate parameters are combined into mechanisms which then describe the overall reaction of the fuels being studied. Detailed sensitivity analyses are used to identify those reaction rates and product species distributions to which the results are most sensitive and therefore warrant the greatest attention from other experimental and theoretical research programs. Experimental data from a variety of environments are combined together to validate the reaction mechanisms, including results from laminar flames, shock tubes, flow systems, detonations, and even internal combustion engines.

Westbrook, C.K.; Pitz, W.J. [Lawrence Livermore National Laboratory, CA (United States)

1993-12-01T23:59:59.000Z

18

Multidimensional simulation and chemical kinetics development...  

Broader source: Energy.gov (indexed) [DOE]

processes. deer09aceves.pdf More Documents & Publications Chemical Kinetic Research on HCCI & Diesel Fuels Chemical Kinetic Research on HCCI & Diesel Fuels Simulation of High...

19

Nanostructured Materials for Energy Generation and Storage  

E-Print Network [OSTI]

waste-heat recovery allowing for energy reuse. The limited use of thermoelectric generatorswaste-heat recovery allowing for en- ergy reuse. The limited use of thermoelectric generators

Khan, Javed Miller

2012-01-01T23:59:59.000Z

20

Japans Approaches to DefenseTransparency: Perspectivesfrom the Japanese and ChineseDefense Establishments  

E-Print Network [OSTI]

En- ergy Basic Law confines Japanese nuclear activi- ties tonot a formal law, Japans three non-nuclear principles (

Fei, John

2012-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "kinetic en ergy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Harvesting nanoscale thermal radiation using pyroelectric materials  

E-Print Network [OSTI]

High-ef?ciency direct conversion of heat to electricaloffers a novel direct en- ergy conversion technology byDirect Pyroelectric Energy Converter Pyroelectric energy conversion

Fang, Jin; Frederich, Hugo; Pilon, Laurent

2010-01-01T23:59:59.000Z

22

Reciprocal Relations Between Kinetic Curves  

E-Print Network [OSTI]

We study coupled irreversible processes. For linear or linearized kinetics with microreversibility, $\\dot{x}=Kx$, the kinetic operator $K$ is symmetric in the entropic inner product. This form of Onsager's reciprocal relations implies that the shift in time, $\\exp (Kt)$, is also a symmetric operator. This generates reciprocity relations between kinetic curves. For example, for the Master equation, if we start the process from the $i$th pure state and measure the probability $p_j(t)$ of the $j$th state ($j\

Yablonsky, G S; Constales, D; Galvita, V; Marin, G B

2010-01-01T23:59:59.000Z

23

Chemical Looping Combustion Kinetics  

SciTech Connect (OSTI)

One of the most promising methods of capturing CO{sub 2} emitted by coal-fired power plants for subsequent sequestration is chemical looping combustion (CLC). A powdered metal oxide such as NiO transfers oxygen directly to a fuel in a fuel reactor at high temperatures with no air present. Heat, water, and CO{sub 2} are released, and after H{sub 2}O condensation the CO{sub 2} (undiluted by N{sub 2}) is ready for sequestration, whereas the nickel metal is ready for reoxidation in the air reactor. In principle, these processes can be repeated endlessly with the original nickel metal/nickel oxide participating in a loop that admits fuel and rejects ash, heat, and water. Our project accumulated kinetic rate data at high temperatures and elevated pressures for the metal oxide reduction step and for the metal reoxidation step. These data will be used in computational modeling of CLC on the laboratory scale and presumably later on the plant scale. The oxygen carrier on which the research at Utah is focused is CuO/Cu{sub 2}O rather than nickel oxide because the copper system lends itself to use with solid fuels in an alternative to CLC called 'chemical looping with oxygen uncoupling' (CLOU).

Edward Eyring; Gabor Konya

2009-03-31T23:59:59.000Z

24

Kinetic models of opinion formation  

E-Print Network [OSTI]

We introduce and discuss certain kinetic models of (continuous) opinion formation involving both exchange of opinion between individual agents and diffusion of information. We show conditions which ensure that the kinetic model reaches non trivial stationary states in case of lack of diffusion in correspondence of some opinion point. Analytical results are then obtained by considering a suitable asymptotic limit of the model yielding a Fokker-Planck equation for the distribution of opinion among individuals.

G. Toscani

2006-05-17T23:59:59.000Z

25

Nonlinear effects in kinetic resolutions  

E-Print Network [OSTI]

KTRIC AMPLIFICATION IN THE JACOBSEN HYDROLYTIC KINET RESOLUTION OF RACEMIC EPOXIDES 20 Applicability of Homocompetitive Reaction Kinetics to the Jacobsen HKR Effect of Catalyst EE and Choice of Epoxide on Amplification in the Jacobsen HKR.... . . . . . . . . . . . . . . . . . Effect of Temperature on Amplification and Reaction Rate in the Jacobsen HKR . Effect of Low EE Catalyst Generation on Amplification in the Jacobsen HKR. . . . 21 21 25 26 27 30 31 TABLE OF CONTENTS (Continued) CHAPTER Page V AS...

Johnson, Derrell W.

1999-01-01T23:59:59.000Z

26

Updated Eastern Interconnect Wind Power Output and Forecasts for ERGIS: July 2012  

SciTech Connect (OSTI)

AWS Truepower, LLC (AWST) was retained by the National Renewable Energy Laboratory (NREL) to update wind resource, plant output, and wind power forecasts originally produced by the Eastern Wind Integration and Transmission Study (EWITS). The new data set was to incorporate AWST's updated 200-m wind speed map, additional tall towers that were not included in the original study, and new turbine power curves. Additionally, a primary objective of this new study was to employ new data synthesis techniques developed for the PJM Renewable Integration Study (PRIS) to eliminate diurnal discontinuities resulting from the assimilation of observations into mesoscale model runs. The updated data set covers the same geographic area, 10-minute time resolution, and 2004?2006 study period for the same onshore and offshore (Great Lakes and Atlantic coast) sites as the original EWITS data set.

Pennock, K.

2012-10-01T23:59:59.000Z

27

ErgyCapital SpA formerly Greenergy Capital | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 NoPublic Utilities Address:011-DNA Jump37. It isInformation ContractsCGNPCEolianEnergyErdos TCH

28

Chemical kinetics and combustion modeling  

SciTech Connect (OSTI)

The goal of this program is to gain qualitative insight into how pollutants are formed in combustion systems and to develop quantitative mathematical models to predict their formation rates. The approach is an integrated one, combining low-pressure flame experiments, chemical kinetics modeling, theory, and kinetics experiments to gain as clear a picture as possible of the process in question. These efforts are focused on problems involved with the nitrogen chemistry of combustion systems and on the formation of soot and PAH in flames.

Miller, J.A. [Sandia National Laboratories, Livermore, CA (United States)

1993-12-01T23:59:59.000Z

29

Kinetic Modeling and Thermodynamic Closure Approximation of ...  

E-Print Network [OSTI]

Oct 5, 2007 ... Kinetic Modeling and Thermodynamic Closure. Approximation of Liquid Crystal Polymers. Haijun Yu. Program in Applied and Computational...

2007-10-03T23:59:59.000Z

30

14CME Kinetic Energy and Mass Kinetic energy is the energy that a  

E-Print Network [OSTI]

14CME Kinetic Energy and Mass Kinetic energy is the energy that a body has by virtue of its mass the table by determining the value of the missing entries using the formula for Kinetic Energy. Problem 2: What is the minimum and maximum range for the observed kinetic energies for the 10 CMEs? The largest

31

Estimating The Thermodynamics And Kinetics Of Chlorinated Hydrocarbon...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Estimating The Thermodynamics And Kinetics Of Chlorinated Hydrocarbon Degradation. Estimating The Thermodynamics And Kinetics Of Chlorinated Hydrocarbon Degradation. Abstract: Many...

32

Challenges and Progress Toward a Commercial Kinetic Hydropower System  

E-Print Network [OSTI]

Challenges and Progress Toward a Commercial Kinetic Hydropower System for its kinetic hydropower devices, and has made precise measurements

Walter, M.Todd

33

Kinetic Modeling of Microbiological Processes  

SciTech Connect (OSTI)

Kinetic description of microbiological processes is vital for the design and control of microbe-based biotechnologies such as waste water treatment, petroleum oil recovery, and contaminant attenuation and remediation. Various models have been proposed to describe microbiological processes. This editorial article discusses the advantages and limiation of these modeling approaches in cluding tranditional, Monod-type models and derivatives, and recently developed constraint-based approaches. The article also offers the future direction of modeling researches that best suit for petroleum and environmental biotechnologies.

Liu, Chongxuan; Fang, Yilin

2012-09-17T23:59:59.000Z

34

The Excitation Energy Dependence of the Total Kinetic Energy Release in 235U(n,f)  

E-Print Network [OSTI]

The total kinetic energy release in the neutron induced fission of $^{235}$U was measured (using white spectrum neutrons from LANSCE) for neutron energies from E$_{n}$ = 3.2 to 50 MeV. In this energy range the average post-neutron total kinetic energy release drops from 167.4 $\\pm$ 0.7 to 162.1 $\\pm$ 0.8 MeV, exhibiting a local dip near the second chance fission threshold. The values and the slope of the TKE vs. E$_{n}$ agree with previous measurements but do disagree (in magnitude) with systematics. The variances of the TKE distributions are larger than expected and apart from structure near the second chance fission threshold, are invariant for the neutron energy range from 11 to 50 MeV. We also report the dependence of the total excitation energy in fission, TXE, on neutron energy.

R. Yanez; L. Yao; J. King; W. Loveland; F. Tovesson; N. Fotiades

2014-03-18T23:59:59.000Z

35

Extension of high-order harmonic generation cutoff via coherent control of intense few-cycle chirped laser pulses  

E-Print Network [OSTI]

for larger dis- tances. #1;b#2; A second-order split-operator technique in the en- ergy representation, which allows the explicit elimination of undesirable fast-oscillating high-energy components, is used for the efficient time propagation of the wave... potential and the laser field. It then oscil- lates quasifreely driven by the Lorenz force and acquires kinetic energy from the laser field. Lastly, after the laser reverses its direction, the returning electron will emit har- monic photons by radiative...

Carrera, Juan J.; Chu, Shih-I

2007-03-16T23:59:59.000Z

36

Chemical Kinetic Research on HCCI & Diesel Fuels  

Broader source: Energy.gov (indexed) [DOE]

improved gasoline surrogate fuels for HCCI engines * Development of very efficient software to reduce the size of detailed chemical kinetic models for transportation fuels...

37

CLEERS Coordination & Development of Catalyst Process Kinetic...  

Broader source: Energy.gov (indexed) [DOE]

& coordinate DOE research efforts (CLEERS Coordination) * Develop detailed technical data required to simulate energy efficient emission controls (LNT & SCR Kinetics, Sulfur &...

38

Kinetic bounding volume hierarchies for deformable objects  

E-Print Network [OSTI]

We present novel algorithms for updating bounding volume hierarchies of objects undergoing arbitrary deformations. Therefore, we introduce two new data structures, the kinetic AABB tree and the kinetic BoxTree. The event-based approach of the kinetic data structures framework enables us to show that our algorithms are optimal in the number of updates. Moreover, we show a lower bound for the total number of BV updates, which is independent of the number of frames. We used our kinetic bounding volume hierarchies for collision detection and performed a comparison with the classical bottomup update method. The results show that our algorithms perform up to ten times faster in practically relevant scenarios.

Gabriel Zachmann; Tu Clausthal

2006-01-01T23:59:59.000Z

39

The Fractional Kinetic Equation and Thermonuclear Functions  

E-Print Network [OSTI]

The paper discusses the solution of a simple kinetic equation of the type used for the computation of the change of the chemical composition in stars like the Sun. Starting from the standard form of the kinetic equation it is generalized to a fractional kinetic equation and its solutions in terms of H-functions are obtained. The role of thermonuclear functions, which are also represented in terms of G- and H-functions, in such a fractional kinetic equation is emphasized. Results contained in this paper are related to recent investigations of possible astrophysical solutions of the solar neutrino problem.

H. J. Haubold; A. M. Mathai

2000-01-16T23:59:59.000Z

40

CLEERS Coordination & Development of Catalyst Process Kinetic...  

Energy Savers [EERE]

CLEERS Coordination & Development of Catalyst Process Kinetic Data - Pres. 1: Coordination of CLEERS Project; Pres. 2: ORNL Research on LNT Sulfation & Desulfation CLEERS...

Note: This page contains sample records for the topic "kinetic en ergy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Combustion kinetics and reaction pathways  

SciTech Connect (OSTI)

This project is focused on the fundamental chemistry of combustion. The overall objectives are to determine rate constants for elementary reactions and to elucidate the pathways of multichannel reactions. A multitechnique approach that features three independent experiments provides unique capabilities in performing reliable kinetic measurements over an exceptionally wide range in temperature, 300 to 2500 K. Recent kinetic work has focused on experimental studies and theoretical calculations of the methane dissociation system (CH{sub 4} + Ar {yields} CH{sub 3} + H + Ar and H + CH{sub 4} {yields} CH{sub 3} + H{sub 2}). Additionally, a discharge flow-photoionization mass spectrometer (DF-PIMS) experiment is used to determine branching fractions for multichannel reactions and to measure ionization thresholds of free radicals. Thus, these photoionization experiments generate data that are relevant to both reaction pathways studies (reaction dynamics) and fundamental thermochemical research. Two distinct advantages of performing PIMS with high intensity, tunable vacuum ultraviolet light at the National Synchrotron Light Source are high detection sensitivity and exceptional selectivity in monitoring radical species.

Klemm, R.B.; Sutherland, J.W. [Brookhaven National Laboratory, Upton, NY (United States)

1993-12-01T23:59:59.000Z

42

Kinetics of actinide complexation reactions  

SciTech Connect (OSTI)

Though the literature records extensive compilations of the thermodynamics of actinide complexation reactions, the kinetics of complex formation and dissociation reactions of actinide ions in aqueous solutions have not been extensively investigated. In light of the central role played by such reactions in actinide process and environmental chemistry, this situation is somewhat surprising. The authors report herein a summary of what is known about actinide complexation kinetics. The systems include actinide ions in the four principal oxidation states (III, IV, V, and VI) and complex formation and dissociation rates with both simple and complex ligands. Most of the work reported was conducted in acidic media, but a few address reactions in neutral and alkaline solutions. Complex formation reactions tend in general to be rapid, accessible only to rapid-scan and equilibrium perturbation techniques. Complex dissociation reactions exhibit a wider range of rates and are generally more accessible using standard analytical methods. Literature results are described and correlated with the known properties of the individual ions.

Nash, K.L.; Sullivan, J.C.

1997-09-01T23:59:59.000Z

43

Multiple temperature kinetic model and gas-kinetic method for hypersonic non-equilibrium flow computations  

E-Print Network [OSTI]

Multiple temperature kinetic model and gas-kinetic method for hypersonic non-equilibrium flow. For the non-equilibrium flow computations, i.e., the nozzle flow and hypersonic rarefied flow over flat plate-kinetic method; Hypersonic and rarefied flows 1. Introduction The development of aerospace technology has

Xu, Kun

44

Testing the kinetic energy functional: Kinetic energy density as a density functional  

E-Print Network [OSTI]

is to the exchange-correlation energy as a functional of the density. A large part of the total energy, the kinetic contexts. For finite systems these forms integrate to the same global ki- netic energy, but they differTesting the kinetic energy functional: Kinetic energy density as a density functional Eunji Sim

Burke, Kieron

45

Kinetic Theory of Dynamical Systems  

E-Print Network [OSTI]

It is generally believed that the dynamics of simple fluids can be considered to be chaotic, at least to the extent that they can be modeled as classical systems of particles interacting with short range, repulsive forces. Here we give a brief introduction to those parts of chaos theory that are relevant for understanding some features of non-equilibrium processes in fluids. We introduce the notions of Lyapunov exponents, Kolmogorov-Sinai entropy and related quantities using some simple low-dimensional systems as "toy" models of the more complicated systems encountered in the study of fluids. We then show how familiar methods used in the kinetic theory of gases can be employed for explicit, analytical calculations of the largest Lyapunov exponent and KS entropy for dilute gases composed of hard spheres in d dimensions. We conclude with a brief discussion of interesting, open problems.

R. van Zon; H. van Beijeren; J. R. Dorfman

1999-06-24T23:59:59.000Z

46

ADVANCES IN ENVIRONMENTAL REACTION KINETICS AND THERMODYNAMICS  

E-Print Network [OSTI]

1262 ADVANCES IN ENVIRONMENTAL REACTION KINETICS AND THERMODYNAMICS: LONG-TERM FATE thermodynamic and kinetic data is available with regard to the formation of these mixed metal precipitate phases to six months from the initial addition of aqueous nickel. Additionally, we have determined thermodynamic

Sparks, Donald L.

47

Chemical kinetics and oil shale process design  

SciTech Connect (OSTI)

Oil shale processes are reviewed with the goal of showing how chemical kinetics influences the design and operation of different processes for different types of oil shale. Reaction kinetics are presented for organic pyrolysis, carbon combustion, carbonate decomposition, and sulfur and nitrogen reactions.

Burnham, A.K.

1993-07-01T23:59:59.000Z

48

B r y n S a d o w n i k , M a r k J a c c a r d Shaping Sustainable Energy Use in Chinese Cities  

E-Print Network [OSTI]

, where the nature of energy use and urban spatial form are considerably dif- ferent. Per capita energy The Relevance of Community Energy Management A significant share of future urban en- ergy consumption- ergy consumption is predetermined when land-use and urban form are des- ignated. Patterns of urban form

49

Kinetic advantage of controlled intermediate nuclear fusion  

SciTech Connect (OSTI)

The dominated process of controlled fusion is to let nuclei gain enough kinetic energy to overcome Coulomb barrier. As a result, a fusion scheme can consider two factors in its design: to increase kinetic energy of nuclei and to alter the Coulomb barrier. Cold Fusion and Hot fusion are all one-factor schemes while Intermediate Fusion is a twofactors scheme. This made CINF kinetically superior. Cold Fusion reduces deuteron-deuteron distance, addressing Coulomb barrier, and Hot Fusion heat up plasma into extreme high temperature, addressing kinetic energy. Without enough kinetic energy made Cold Fusion skeptical. Extreme high temperature made Hot Fusion very difficult to engineer. Because CIFN addresses both factors, CIFN is a more promising technique to be industrialized.

Guo Xiaoming [Physics and Computer Science Department, Wilfrid Laurier University, Waterloo, Ontario, N2L 3C5 (Canada)

2012-09-26T23:59:59.000Z

50

Actuar en asociacin Asociaciones en el mundo  

E-Print Network [OSTI]

las contaminaciones por metales en los Andes, en Bolivia Taller sobre la variabilidad de El Nio y para la conservacin de la biodiversidad en Amazona boliviana, en Santa Cruz, Bolivia Taller

51

Long-term Kinetics of Uranyl Desorption from Sediments Under...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

term Kinetics of Uranyl Desorption from Sediments Under Advective Conditions. Long-term Kinetics of Uranyl Desorption from Sediments Under Advective Conditions. Abstract: Long-term...

52

Direct Visualization of Initial SEI Morphology and Growth Kinetics...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Initial SEI Morphology and Growth Kinetics During Lithium Deposition by in situ Electrochemical Direct Visualization of Initial SEI Morphology and Growth Kinetics During Lithium...

53

Structure, Kinetics, and Thermodynamics of the Aqueous Uranyl...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Kinetics, and Thermodynamics of the Aqueous Uranyl(VI) Cation. Structure, Kinetics, and Thermodynamics of the Aqueous Uranyl(VI) Cation. Abstract: Molecular simulation techniques...

54

Uncertainty analysis of multi-rate kinetics of uranium desorption...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Uncertainty analysis of multi-rate kinetics of uranium desorption from sediments. Uncertainty analysis of multi-rate kinetics of uranium desorption from sediments. Abstract: A...

55

Global Optimization of Chemical Reactors and Kinetic Optimization  

E-Print Network [OSTI]

Model; 3-D; Monolith; Reactor; Optimization Introduction TheAngeles Global Optimization of Chemical Reactors and KineticGlobal Optimization of Chemical Reactors and Kinetic

ALHUSSEINI, ZAYNA ISHAQ

2013-01-01T23:59:59.000Z

56

Transport-controlled kinetics of dissolution and precipitation...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Transport-controlled kinetics of dissolution and precipitation in the sediments under alkaline and saline conditions . Transport-controlled kinetics of dissolution and...

57

Microscale Electrode Design Using Coupled Kinetic, Thermal and...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Microscale Electrode Design Using Coupled Kinetic, Thermal and Mechanical Modeling Microscale Electrode Design Using Coupled Kinetic, Thermal and Mechanical Modeling 2010 DOE...

58

Microscale Electrode Design Using Coupled Kinetic, Thermal and...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Microscale Electrode Design Using Coupled Kinetic, Thermal and Mechanical Modeling Microscale Electrode Design Using Coupled Kinetic, Thermal and Mechanical Modeling 2009 DOE...

59

Coupled Kinetic, Thermal, and Mechanical Modeling of FIB Micro...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Coupled Kinetic, Thermal, and Mechanical Modeling of FIB Micro-machined Electrodes Coupled Kinetic, Thermal, and Mechanical Modeling of FIB Micro-machined Electrodes 2010 DOE...

60

A Comparison of HCCI Engine Performance Data and Kinetic Modeling...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

of HCCI Engine Performance Data and Kinetic Modeling Results over a Wide Rangeof Gasoline Range Surrogate Fuel Blends A Comparison of HCCI Engine Performance Data and Kinetic...

Note: This page contains sample records for the topic "kinetic en ergy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Improving Combustion Software to Solve Detailed Chemical Kinetics...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Combustion Software to Solve Detailed Chemical Kinetics for HECC Improving Combustion Software to Solve Detailed Chemical Kinetics for HECC 2012 DOE Hydrogen and Fuel Cells Program...

62

Modeling of Reactor Kinetics and Dynamics  

SciTech Connect (OSTI)

In order to model a full fuel cycle in a nuclear reactor, it is necessary to simulate the short time-scale kinetic behavior of the reactor as well as the long time-scale dynamics that occur with fuel burnup. The former is modeled using the point kinetics equations, while the latter is modeled by coupling fuel burnup equations with the kinetics equations. When the equations are solved simultaneously with a nonlinear equation solver, the end result is a code with the unique capability of modeling transients at any time during a fuel cycle.

Matthew Johnson; Scott Lucas; Pavel Tsvetkov

2010-09-01T23:59:59.000Z

63

Kinetic limits of dynamical systems  

E-Print Network [OSTI]

Since the pioneering work of Maxwell and Boltzmann in the 1860s and 1870s, a major challenge in mathematical physics has been the derivation of macroscopic evolution equations from the fundamental microscopic laws of classical or quantum mechanics. Macroscopic transport equations lie at the heart of many important physical theories, including fluid dynamics, condensed matter theory and nuclear physics. The rigorous derivation of macroscopic transport equations is thus not only a conceptual exercise that establishes their consistency with the fundamental laws of physics: the possibility of finding deviations and corrections to classical evolution equations makes this subject both intellectually exciting and relevant in practical applications. The plan of these lectures is to develop a renormalisation technique that will allow us to derive transport equations for the kinetic limits of two classes of simple dynamical systems, the Lorentz gas and kicked Hamiltonians (or linked twist maps). The technique uses the ergodic theory of flows on homogeneous spaces (homogeneous flows for short), and is based on joint work with Andreas Str\\"ombergsson.

Jens Marklof

2014-08-06T23:59:59.000Z

64

Kinetic description of mixtures of anisotropic fluids  

E-Print Network [OSTI]

A simple system of coupled kinetic equations for quark and gluon anisotropic systems is solved numerically. The solutions are compared with the predictions of the anisotropic hydrodynamics describing a mixture of anisotropic fluids. We find that the solutions of the kinetic equations can be well reproduced by anisotropic hydrodynamics if the initial distribution are oblate for both quarks and gluons. On the other hand, the solutions of the kinetic equations have a different qualitative behavior from those obtained in anisotropic hydrodynamics if the initial configurations are oblate-prolate or prolate-prolate. This suggests that an extension of the anisotropic hydrodynamics scheme for the mixture of anisotropic fluids is needed, where higher moments of the kinetic equations are used and present simplifications are avoided.

Wojciech Florkowski; Oskar Madetko

2014-02-11T23:59:59.000Z

65

Mechanistic studies using kinetic isotope effects  

E-Print Network [OSTI]

MECHANISTIC STUDIES USING KINETIC ISOTOPE EFFECTS A Thesis by BRIAN E. SCHULMFIER Submitted to the Office of Graduate Studies of Texas ARM University in partial fulfillment of the requtrements for the degree of MASTER OF SCIENCE December... 1999 Major Subject: Chemistry MECHANISTIC STUDIES USING KINETIC ISOTOPE EFFECTS A Thesis by BRIAN E. SCHULMEIER Submitted to Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE Approved...

Schulmeier, Brian E.

2012-06-07T23:59:59.000Z

66

Kinetic decoupling of WIMPs: analytic expressions  

E-Print Network [OSTI]

We present a general expression for the values of the average kinetic energy and of the temperature of kinetic decoupling of a WIMP, valid for any cosmological model. We show an example of the usage of our solution when the Hubble rate has a power-law dependence on temperature, and we show results for the specific cases of kination cosmology and low- temperature reheating cosmology.

Visinelli, Luca

2015-01-01T23:59:59.000Z

67

22nd IAEA-FEC Kinetic theory of Geodesic Acoustic Modes: ... 1 Kinetic theory of Geodesic Acoustic  

E-Print Network [OSTI]

22nd IAEA-FEC Kinetic theory of Geodesic Acoustic Modes: ... 1 Kinetic theory of Geodesic Acoustic Zonca, Liu Chen and Zhiyong Qiu #12;22nd IAEA-FEC Kinetic theory of Geodesic Acoustic Modes: ... 2 Chen and Zhiyong Qiu #12;22nd IAEA-FEC Kinetic theory of Geodesic Acoustic Modes: ... 3 2 Linear

Zonca, Fulvio

68

Inlichtingenblad, matlab-en simulink handleiding en  

E-Print Network [OSTI]

Inlichtingenblad, matlab- en simulink handleiding en practicumopgaven IWS 1 #12;4 2 Opmerkingen bij de Matlab-handleiding De voor dit practicum relevante informatie staat in de paragrafen 3.4, 4.1 en 4.2, en in de paragraaf 4.3 tot SIMULINK MENUS en vanaf ANALYSIS COMMANDS van de Matlab-handleiding die

Al Hanbali, Ahmad

69

MHD versus kinetic effects in the solar coronal heating: a two stage mechanism  

E-Print Network [OSTI]

Using Particle-In-Cell simulations i.e. in the kinetic plasma description the discovery of a new mechanism of parallel electric field generation was recently reported. Here we show that the electric field generation parallel to the uniform unperturbed magnetic field can be obtained in a much simpler framework using the ideal magnetohydrodynamics (MHD) description. In ideal MHD the electric field parallel to the uniform unperturbed magnetic field appears due to fast magnetosonic waves which are generated by the interaction of weakly non-linear Alfv\\'en waves with the transverse density inhomogeneity. In the context of the coronal heating problem a new {\\it two stage mechanism} of plasma heating is presented by putting emphasis, first, on the generation of parallel electric fields within an {\\it ideal MHD} description directly, rather than focusing on the enhanced dissipation mechanisms of the Alfv\\'en waves and, second, dissipation of these parallel electric fields via {\\it kinetic} effects. It is shown that for a single Alfv\\'en wave harmonic with frequency $\

David Tsiklauri

2006-06-27T23:59:59.000Z

70

7-Gate Kinetic AMPA Model Kinetics to match EPSCs from calyx of Held  

E-Print Network [OSTI]

7-Gate Kinetic AMPA Model · Kinetics to match EPSCs from calyx of Held · Multiple closed, open and EPSC amplitude Bruce Graham Department of Computing Science and Mathematics, University of Stirling, U, including the calyx of Held in the mammalian auditory system. Such depression may be mediated

Graham, Bruce

71

Chemical Kinetic Modeling of Advanced Transportation Fuels  

SciTech Connect (OSTI)

Development of detailed chemical kinetic models for advanced petroleum-based and nonpetroleum based fuels is a difficult challenge because of the hundreds to thousands of different components in these fuels and because some of these fuels contain components that have not been considered in the past. It is important to develop detailed chemical kinetic models for these fuels since the models can be put into engine simulation codes used for optimizing engine design for maximum efficiency and minimal pollutant emissions. For example, these chemistry-enabled engine codes can be used to optimize combustion chamber shape and fuel injection timing. They also allow insight into how the composition of advanced petroleum-based and non-petroleum based fuels affect engine performance characteristics. Additionally, chemical kinetic models can be used separately to interpret important in-cylinder experimental data and gain insight into advanced engine combustion processes such as HCCI and lean burn engines. The objectives are: (1) Develop detailed chemical kinetic reaction models for components of advanced petroleum-based and non-petroleum based fuels. These fuels models include components from vegetable-oil-derived biodiesel, oil-sand derived fuel, alcohol fuels and other advanced bio-based and alternative fuels. (2) Develop detailed chemical kinetic reaction models for mixtures of non-petroleum and petroleum-based components to represent real fuels and lead to efficient reduced combustion models needed for engine modeling codes. (3) Characterize the role of fuel composition on efficiency and pollutant emissions from practical automotive engines.

PItz, W J; Westbrook, C K; Herbinet, O

2009-01-20T23:59:59.000Z

72

Saffman-Taylor fingers with kinetic undercooling  

E-Print Network [OSTI]

The mathematical model of a steadily propagating Saffman-Taylor finger in a Hele-Shaw channel has applications to two-dimensional interacting streamer discharges which are aligned in a periodic array. In the streamer context, the relevant regularisation on the interface is not provided by surface tension, but instead has been postulated to involve a mechanism equivalent to kinetic undercooling, which acts to penalise high velocities and prevent blow-up of the unregularised solution. Previous asymptotic results for the Hele-Shaw finger problem with kinetic undercooling suggest that for a given value of the kinetic undercooling parameter, there is a discrete set of possible finger shapes, each analytic at the nose and occupying a different fraction of the channel width. In the limit in which the kinetic undercooling parameter vanishes, the fraction for each family approaches 1/2, suggesting that this 'selection' of 1/2 by kinetic undercooling is qualitatively similar to the well-known analogue with surface tens...

Gardiner, Bennett P J; Dallaston, Michael C; Moroney, Timothy J

2015-01-01T23:59:59.000Z

73

Neptunium Binding Kinetics with Arsenazo(III)  

SciTech Connect (OSTI)

This document has been prepared to meet FCR&D level 2 milestone M2FT-14IN0304021, Report on the results of actinide binding kinetics with aqueous phase complexants This work was carried out under the auspices of the Thermodynamics and Kinetics of Advanced Separations Systems FCR&D work package. The report details kinetics experiments that were performed to measure rates of aqueous phase complexation for pentavalent neptunium with the chromotropic dye Arsenazo III (AAIII). The studies performed were designed to determine how pH, ionic strength and AAIII concentration may affect the rate of the reaction. A brief comparison with hexavalent neptunium is also made. It was identified that as pH was increased the rate of reaction also increased, however increasing the ionic strength and concentration of AAIII had the opposite effect. Interestingly, the rate of reaction of Np(VI) with AAIII was found to be slower than that of the Np(V) reaction.

Leigh R. Martin; Aaron T. Johnson; Stephen P. Mezyk

2014-08-01T23:59:59.000Z

74

Kinetic studies of elementary chemical reactions  

SciTech Connect (OSTI)

This program concerning kinetic studies of elementary chemical reactions is presently focussed on understanding reactions of NH{sub x} species. To reach this goal, the author is pursuing experimental studies of reaction rate coefficients and product branching fractions as well as using electronic structure calculations to calculate transition state properties and reaction rate calculations to relate these properties to predicted kinetic behavior. The synergy existing between the experimental and theoretical studies allow one to gain a deeper insight into more complex elementary reactions.

Durant, J.L. Jr. [Sandia National Laboratories, Livermore, CA (United States)

1993-12-01T23:59:59.000Z

75

Model Independent Bounds on Kinetic Mixing  

SciTech Connect (OSTI)

New Abelian vector bosons can kinetically mix with the hypercharge gauge boson of the Standard Model. This letter computes the model independent limits on vector bosons with masses from 1 GeV to 1 TeV. The limits arise from the numerous e{sup +}e{sup -} experiments that have been performed in this energy range and bound the kinetic mixing by {epsilon} {approx}< 0.03 for most of the mass range studied, regardless of any additional interactions that the new vector boson may have.

Hook, Anson; Izaguirre, Eder; Wacker, Jay G.; /SLAC

2011-08-22T23:59:59.000Z

76

E-Print Network 3.0 - age-specific kinetic model Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

- Kinetic StabilizationNSTX Simple model... - Kinetic StabilizationNSTX Kinetic model: collisions decrease stability collision frequency (note... dissipation of mode...

77

Interpreting the Aggregation Kinetics of Amyloid Peptides  

E-Print Network [OSTI]

Amyloid fibrils are insoluble mainly -sheet aggregates of proteins or peptides. The multi-step process) and amyloid-protected states, is used to investigate the kinetics of aggregation and the pathways of fibril state. The minimal-size aggregate able to form a fibril is generated by collisions of oligomers

Caflisch, Amedeo

78

Radiation from Kinetic Poynting Flux Acceleration  

E-Print Network [OSTI]

We derive analytic formulas for the power output and critical frequency of radiation by electrons accelerated by relativistic kinetic Poynting flux, and validate these results with Particle-In-Cell plasma simulations. We find that the in-situ radiation power output and critical frequency are much below those predicted by the classical synchrotron formulae. We discuss potential astrophysical applications of these results.

Edison Liang; Koichi Noguchi

2007-11-18T23:59:59.000Z

79

CHEMICAL THERMODYNAMICS AND KINETICS Class Meetings  

E-Print Network [OSTI]

CHEM 6471 CHEMICAL THERMODYNAMICS AND KINETICS Class Meetings 9:35 10:55 am, Tuesday and Thursday of October 22-26 Textbooks Molecular Thermodynamics by D.A McQuarrie and J.D. Simon, University Science Books the laws of classical thermodynamics and some of their chemical applications. It also covers basic

Sherrill, David

80

Thermodynamic and kinetic modeling of transcriptional pausing  

E-Print Network [OSTI]

in the cotranscriptional RNA secondary structure upstream of the RNA exit channel. The calculations involve no adjustable of recovery of backtracked paused complexes. A crucial ingredient of our model is the incorporation of kinetic secondary structure, an aspect not included explicitly in previous attempts at modeling the transcrip- tion

Chen, Kuang-Yu

Note: This page contains sample records for the topic "kinetic en ergy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

STATISTICAL ANALYSIS OF PROTEIN FOLDING KINETICS  

E-Print Network [OSTI]

STATISTICAL ANALYSIS OF PROTEIN FOLDING KINETICS AARON R. DINNER New Chemistry Laboratory for Protein Folding: Advances in Chemical Physics, Volume 120. Edited by Richard A. Friesner. Series Editors Experimental and theoretical studies have led to the emergence of a unified general mechanism for protein

Dinner, Aaron

82

Direct kinetic correlation of carriers and ferromagnetism in...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

kinetic correlation of carriers and ferromagnetism in Co2+ : ZnO. Direct kinetic correlation of carriers and ferromagnetism in Co2+ : ZnO. Abstract: We report the use of controlled...

83

Adsorption, Desorption, and Displacement Kinetics of H2O and...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Displacement Kinetics of H2O and CO2 on TiO2(110). Adsorption, Desorption, and Displacement Kinetics of H2O and CO2 on TiO2(110). Abstract: The adsorption, desorption, and...

84

Ethylbenzene dehydrogenation into styrene: kinetic modeling and reactor simulation  

E-Print Network [OSTI]

detailed kinetic model for coke formation and gasification, which was coupled to the kinetic model for the main reactions. The calculation of the dynamic equilibrium coke content provided a crucial guideline for the selection of the steam to ethylbenzene...

Lee, Won Jae

2007-04-25T23:59:59.000Z

85

Where's the Beef?  

E-Print Network [OSTI]

organic matter to the soil with manure. Other anti-meat myths ... energy to produce enough beef or burgers to provide one megajoule of food en- ergy. The fuel...

2014-08-30T23:59:59.000Z

86

622 IEEE JOURNAL OF SOLID-STATE CIRCUITS, VOL. 49, NO. 3, MARCH 2014 Co-Design of a CMOS Rectifier and Small Loop  

E-Print Network [OSTI]

622 IEEE JOURNAL OF SOLID-STATE CIRCUITS, VOL. 49, NO. 3, MARCH 2014 Co-Design of a CMOS Rectifier (EM) en- ergy into electrical DC power. This DC power is locally stored in a capacitor or battery

Serdijn, Wouter A.

87

Impacts of Wind Turbine Proximity on Property Values in Massachusetts  

E-Print Network [OSTI]

Devine-Wright, P. (2012) Renewable Energy and the Public:EU. (2012) European Commission Renewable En- ergy Targets byU.S. Great Plains. Renewable & Sustainable Energy Reviews.

Atkinson-Palombo, Carol

2014-01-01T23:59:59.000Z

88

Legislative Developments in Solar Energy during 1980  

E-Print Network [OSTI]

In particular, the Solar Energy and Energy Conservation Bankthermal sytems is the Solar Energy and En- ergy ConservationREP. (CCH) 531. 26. Solar Energy and Energy Conservation Act

Krueger, Robert B.; Hoffman, Peter C.

1981-01-01T23:59:59.000Z

89

Dynamical mechanism for non-locality in dense granular flows Mehdi Bouzid, Martin Trulsson, Philippe Claudin, Eric Clement, and Bruno Andreotti  

E-Print Network [OSTI]

[2], free en- ergy for foams or emulsions (surface tension) as well as for soft elastomeric particles transition is accordingly named colloidal glass transition, elasto-plastic depinning tran- sition and jamming

Claudin, Philippe

90

Worldwide Oil Production Michaelis-Menten Kinetics Correlation and Regression  

E-Print Network [OSTI]

Worldwide Oil Production Michaelis-Menten Kinetics Topic 4 Correlation and Regression Transformed Variables 1 / 13 #12;Worldwide Oil Production Michaelis-Menten Kinetics Outline Worldwide Oil Production Michaelis-Menten Kinetics Lineweaver-Burke double reciprocal plot 2 / 13 #12;Worldwide Oil Production

Watkins, Joseph C.

91

The Inverse Kinetics Method and PID Compensation of the  

E-Print Network [OSTI]

The Inverse Kinetics Method and PID Compensation of the Annular Core Research Reactor by Benjamin Kinetics Method and PID Compensation of the Annular Core Research Reactor by Benjamin Garnas ABSTRACT Kinetics Method and PID Compensation of the Annular Core Research Reactor by Benjamin Garnas B.S. General

92

IMPACT Vol. 5 No. 1 | Spring 2010 CLeAn eneRGy DeMAnDS  

E-Print Network [OSTI]

IMPACT Vol. 5 No. 1 | Spring 2010 CLeAn eneRGy DeMAnDS: SCienCe, innovATion, PUBLiC PoLiCy Maryland on foreign oil and become the world leader in tomorrow's clean-energy economy," says Steve Fetter, a former researchers shape the new energy economy #12;impact overview impact overview EnErgy rEsEarcH EnErgy r

Hill, Wendell T.

93

E-Print Network 3.0 - approximate kinetic equations Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

equation. Reactor kinetics and Summary: equations, prompt jump approximation; subcritical reactor kinetics, circulating fuel reactor dynamics 5... solution to neutron...

94

Stability of global driftkinetic Alfv'en eigenmodes in A.JAUN 1 , J.VACLAVIK 2 , L.VILLARD 2  

E-Print Network [OSTI]

wavefield, the mode converted kinetic Alfv'en, ion­acoustic and drift waves. The power transfers between.VILLARD 2 1 Alfv'en Laboratory, EURATOM­NFR Association, KTH, SE­100 44 Stockholm, Sweden 2 CRPP­EPFL, CH the wave and the particles show that the drift character of the wavefield in the core destabilizes DKAE

Jaun, André

95

Ion mediated crosslink driven mucous swelling kinetics  

E-Print Network [OSTI]

We present an experimentally guided, multi-phasic, multi-species ionic gel model to compare and make qualitative predictions on the rheology of mucus of healthy individuals (Wild Type) versus those infected with Cystic Fibrosis. The mixture theory consists of the mucus (polymer phase) and water (solvent phase) as well as several different ions: H+, Na+ and Ca++. The model is linearized to study the hydration of spherically symmetric mucus gels and calibrated against the experimental data of mucus diffusivities. Near equilibrium, the linearized form of the equation describing the radial size of the gel, reduces to the well-known expression used in the kinetic theory of swelling hydrogels. Numerical studies reveal that the Donnan potential is the dominating mechanism driving the mucus swelling/deswelling transition. However, the altered swelling kinetics of the Cystic Fibrosis infected mucus is not merely governed by the hydroelectric composition of the swelling media, but also due to the altered movement of el...

Sircar, S

2015-01-01T23:59:59.000Z

96

Kinetics of atoms in a bichromatic field  

SciTech Connect (OSTI)

The kinetics of atoms in a bichromatic field is considered. Analytic solutions are obtained for the force, friction coefficient, and diffusion coefficient in the model of a two-level atom without limitations imposed on the intensity of light fields. This effect is observed in the domain of global minima and maxima of the optical potential (i.e., at points where the relative phase of two standing waves is Greek-Phi-Symbol = 0, {pi}/2.

Prudnikov, O. N., E-mail: llf@laser.nsc.ru [Novosibirsk State University (Russian Federation); Baklanov, A. S. [Russian Academy of Sciences, Institute of Laser Physics, Siberian Branch (Russian Federation)] [Russian Academy of Sciences, Institute of Laser Physics, Siberian Branch (Russian Federation); Taichenachev, A. V. [Novosibirsk State University (Russian Federation)] [Novosibirsk State University (Russian Federation); Tumaikin, A. M. [Russian Academy of Sciences, Institute of Laser Physics, Siberian Branch (Russian Federation)] [Russian Academy of Sciences, Institute of Laser Physics, Siberian Branch (Russian Federation); Yudin, V. I. [Novosibirsk State University (Russian Federation)] [Novosibirsk State University (Russian Federation)

2013-08-15T23:59:59.000Z

97

Philips Color Kinetics | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of InspectorConcentrating Solar Powerstories onFocusOskiPhilips Color Kinetics Jump to: navigation, search Name:

98

Kinetic Energy Systems | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data CenterFranconia, Virginia: Energy Resources Jump to:46 - 429 Throttled (botOpen6Kentwood, Michigan:Killingworth, Connecticut:105.Kinetic

99

Kinetic Energy LLC | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of InspectorConcentrating Solar Powerstories on climateJuno Beach, Florida:Kenyon MunicipalKinetic Energy LLC

100

Inertial range turbulence in kinetic plasmas  

E-Print Network [OSTI]

The transfer of turbulent energy through an inertial range from the driving scale to dissipative scales in a kinetic plasma followed by the conversion of this energy into heat is a fundamental plasma physics process. A theoretical foundation for the study of this process is constructed, but the details of the kinetic cascade are not well understood. Several important properties are identified: (a) the conservation of a generalized energy by the cascade; (b) the need for collisions to increase entropy and realize irreversible plasma heating; and (c) the key role played by the entropy cascade--a dual cascade of energy to small scales in both physical and velocity space--to convert ultimately the turbulent energy into heat. A strategy for nonlinear numerical simulations of kinetic turbulence is outlined. Initial numerical results are consistent with the operation of the entropy cascade. Inertial range turbulence arises in a broad range of space and astrophysical plasmas and may play an important role in the thermalization of fusion energy in burning plasmas.

G. G. Howes

2007-11-27T23:59:59.000Z

Note: This page contains sample records for the topic "kinetic en ergy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Kinetics and morphology of erbium silicide formation  

SciTech Connect (OSTI)

The growth kinetics and surface morphology of erbium silicide formation from Er layers on Si(100) substrates are examined using both fast e-beam annealing and furnace annealing. Very smooth erbium silicide layers have been grown using a line-source e beam to heat and react the Er overlayers with the substrate. This contrasts to the severe pitting observed when Er layers are reacted with Si in conventional furnace annealing. The pitting phenomenon can be explained by a thin contaminant layer at the interface between Er and Si. Our results suggest the contamination barrier is not due to oxygen, as usually assumed, but may be related to the presence of carbon. Rapid e-beam heating to reaction temperatures of approx.1200 K permits dispersion of the barrier layer before substantial silicide growth can occur, allowing smooth silicide growth. Heating to shorter times to just disperse the interface barrier allows uniform layer growth by subsequent furnace annealing and has permitted measurement of the kinetics of erbium silicide formation on crystalline Si. The reaction obeys (time)/sup 1//sup ///sup 2/ kinetics but is shown to be not totally diffusion limited by the ability to sustain multiple interface growth from a single Si source. The growth rates are nearly an order of magnitude slower for the Er/Si(100) interface than for the Er/amorphous-Si, but with a similar activation energy near 1.75 eV in both cases.

Knapp, J.A.; Picraux, S.T.; Wu, C.S.; Lau, S.S.

1985-11-15T23:59:59.000Z

102

Isothermal kinetics of new Albany oil shale  

SciTech Connect (OSTI)

From the development of technologies for the utilization of eastern U.S. oil shales, fluidized bed pyrolysis technology is emerging as one of the most promising in terms of oil yield, operating cost, and capital investment. Bench-scale testing of eastern shales has reached a level where scale-up represents the next logical step in the evolution of this technology. A major consideration in this development and an essential part of any fluidized bed reactor scale-up effort--isothermal kinetics-- has largely been ignored for eastern US shale with the exception of a recent study conducted by Richardson et al. with a Cleveland shale. The method of Richardson et al. was used previously by Wallman et al. with western shale and has been used most recently by Forgac, also with western shale. This method, adopted for the present study, entails injecting a charge of shale into a fluidized bed and monitoring the hydrocarbon products with a flame ionization detector (FID). Advantages of this procedure are that fluidized bed heat-up effects are simulated exactly and real-time kinetics are obtained due to the on-line FID. Other isothermal methods have suffered from heat-up and cool-down effects making it impossible to observe the kinetics at realistic operating temperatures. A major drawback of the FID approach, however, is that no differentiation between oil and gas is possible.

Carter, S.D.

1987-04-01T23:59:59.000Z

103

Studies of combustion kinetics and mechanisms  

SciTech Connect (OSTI)

The objective of the current research is to gain new quantitative knowledge of the kinetics and mechanisms of polyatomic free radicals which are important in hydrocarbon combustion processes. The special facility designed and built for these (which includes a heatable tubular reactor coupled to a photoionization mass spectrometer) is continually being improved. Where possible, these experimental studies are coupled with theoretical ones, sometimes conducted in collaboration with others, to obtain an improved understanding of the factors determining reactivity. The decomposition of acetyl radicals, isopropyl radicals, and n-propyl radicals have been studied as well as the oxidation of methylpropargyl radicals.

Gutman, D. [Catholic Univ. of America, Washington, DC (United States)

1993-12-01T23:59:59.000Z

104

Benchmarks for the point kinetics equations  

SciTech Connect (OSTI)

A new numerical algorithm is presented for the solution to the point kinetics equations (PKEs), whose accurate solution has been sought for over 60 years. The method couples the simplest of finite difference methods, a backward Euler, with Richardsons extrapolation, also called an acceleration. From this coupling, a series of benchmarks have emerged. These include cases from the literature as well as several new ones. The novelty of this presentation lies in the breadth of reactivity insertions considered, covering both prescribed and feedback reactivities, and the extreme 8- to 9- digit accuracy achievable. The benchmarks presented are to provide guidance to those who wish to develop further numerical improvements. (authors)

Ganapol, B. [Department of Aerospace and Mechanical Engineering (United States); Picca, P. [Department of Systems and Industrial Engineering, University of Arizona (United States); Previti, A.; Mostacci, D. [Laboratorio di Montecuccolino Alma Mater Studiorum, Universita di Bologna (Italy)

2013-07-01T23:59:59.000Z

105

Direct Kinetic Measurements of a Criegee Intermediate  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation Proposed Newcatalyst phasesDataTranslocation of Shewanella Oneidensis OuterDirect Kinetic

106

Direct Kinetic Measurements of a Criegee Intermediate  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-Series to UserProduct: CrudeOfficeNERSCDiesel prices topDirect Kinetic

107

Direct Kinetic Measurements of a Criegee Intermediate  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-Series to UserProduct: CrudeOfficeNERSCDiesel prices topDirect KineticDirect

108

Kinetic Bounding Volume Hierarchies for Collision Detection of Deformable Objects  

E-Print Network [OSTI]

We present novel algorithms for updating bounding volume hierarchies of objects undergoing arbitrary deformations. Therefore, we introduce two new data structures, the kinetic AABB tree and the kinetic BoxTree. The event-based approach of the kinetic data structures framework enables us to show that our algorithms are optimal in the number of updates. Moreover, we show a lower bound for the total number of BV updates, which is independent of the number of frames. Furthermore, we present a kinetic data structures which uses the kinetic AABB tree for collision detection and show that this structure can be easily extended for continuous collision detection of deformable objects. We performed a comparison of our kinetic approaches with the classical bottom-up update method. The results show that our algorithms perform up to ten times faster in practically relevant scenarios.

Gabriel Zachmann; Rene Weller

2006-01-01T23:59:59.000Z

109

3.205 Thermodynamics and Kinetics of Materials, Fall 2003  

E-Print Network [OSTI]

Laws of thermodynamics applied to materials and materials processes. Solution theory. Equilibrium diagrams. Overview of fluid transport processes. Kinetics of processes that occur in materials, including diffusion, phase ...

Allen, Samuel M.

110

average kinetic energy: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

energy by kinetic averaging Pierre-Emmanuel Jabin Ecole Normale Sup-Landau energy for two dimensional divergence free fields ap- pearing in the gradient theory of...

111

Geothermal: Sponsored by OSTI -- The solubility and kinetics...  

Office of Scientific and Technical Information (OSTI)

The solubility and kinetics of minerals under CO2-EGS geothermal conditions: Comparison of experimental and modeling results Geothermal Technologies Legacy Collection HelpFAQ |...

112

Uranium and Strontium Batch Sorption and Diffusion Kinetics into...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Uranium and Strontium Batch Sorption and Diffusion Kinetics into Mesoporous Silica Friday, February 27, 2015 Figure 1 Figure 1. Transmission electron microscopy images of (A)...

113

A Comparison of HCCI Engine Performance Data and Kinetic Modeling...  

Broader source: Energy.gov (indexed) [DOE]

of HCCI Engine Performance Data and Kinetic Modeling Results over a Wide Range of Gasoline Range Surrogate Fuel Blends Bruce G. Bunting and Scott Eaton, Oak Ridge National...

114

Design and operating characteristics of a transient kinetic analysis...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

catalysis reactor system employing in situ transmission Abstract: A novel apparatus for gas-phase heterogeneous catalysis kinetics is described. The apparatus enables fast...

115

Ion mediated crosslink driven mucous swelling kinetics  

E-Print Network [OSTI]

We present an experimentally guided, multi-phasic, multi-species ionic gel model to compare and make qualitative predictions on the rheology of mucus of healthy individuals (Wild Type) versus those infected with Cystic Fibrosis. The mixture theory consists of the mucus (polymer phase) and water (solvent phase) as well as several different ions: H+, Na+ and Ca++. The model is linearized to study the hydration of spherically symmetric mucus gels and calibrated against the experimental data of mucus diffusivities. Near equilibrium, the linearized form of the equation describing the radial size of the gel, reduces to the well-known expression used in the kinetic theory of swelling hydrogels. Numerical studies reveal that the Donnan potential is the dominating mechanism driving the mucus swelling/deswelling transition. However, the altered swelling kinetics of the Cystic Fibrosis infected mucus is not merely governed by the hydroelectric composition of the swelling media, but also due to the altered movement of electrolytes as well as due to the defective properties of the mucin polymer network.

S. Sircar; A. J. Roberts

2015-01-20T23:59:59.000Z

116

Detailed Kinetic Modeling of Gasoline Surrogate Mixtures  

SciTech Connect (OSTI)

Real fuels are complex mixtures of thousands of hydrocarbon compounds including linear and branched paraffins, naphthenes, olefins and aromatics. It is generally agreed that their behavior can be effectively reproduced by simpler fuel surrogates containing a limited number of components. In this work, a recently revised version of the kinetic model by the authors is used to analyze the combustion behavior of several components relevant to gasoline surrogate formulation. Particular attention is devoted to linear and branched saturated hydrocarbons (PRF mixtures), olefins (1-hexene) and aromatics (toluene). Model predictions for pure components, binary mixtures and multi-component gasoline surrogates are compared with recent experimental information collected in rapid compression machine, shock tube and jet stirred reactors covering a wide range of conditions pertinent to internal combustion engines. Simulation results are discussed focusing attention on the mixing effects of the fuel components.

Mehl, M; Curran, H J; Pitz, W J; Westbrook, C K

2009-03-09T23:59:59.000Z

117

A Chemical Kinetic Model of Transcriptional Elongation  

E-Print Network [OSTI]

A chemical kinetic model of the elongation dynamics of RNA polymerase along a DNA sequence is introduced. The proposed model governs the discrete movement of the RNA polymerase along a DNA template, with no consideration given to elastic effects. The model's novel concept is a ``look-ahead'' feature, in which nucleotides bind reversibly to the DNA prior to being incorporated covalently into the nascent RNA chain. Results are presented for specific DNA sequences that have been used in single-molecule experiments of the random walk of RNA polymerase along DNA. By replicating the data analysis algorithm from the experimental procedure, the model produces velocity histograms, enabling direct comparison with these published results.

Yujiro Richard Yamada; Charles S. Peskin

2006-05-23T23:59:59.000Z

118

Kinetics of wet sodium vapor complex plasma  

SciTech Connect (OSTI)

In this paper, we have investigated the kinetics of wet (partially condensed) Sodium vapor, which comprises of electrons, ions, neutral atoms, and Sodium droplets (i) in thermal equilibrium and (ii) when irradiated by light. The formulation includes the balance of charge over the droplets, number balance of the plasma constituents, and energy balance of the electrons. In order to evaluate the droplet charge, a phenomenon for de-charging of the droplets, viz., evaporation of positive Sodium ions from the surface has been considered in addition to electron emission and electron/ion accretion. The analysis has been utilized to evaluate the steady state parameters of such complex plasmas (i) in thermal equilibrium and (ii) when irradiated; the results have been graphically illustrated. As a significant outcome irradiated, Sodium droplets are seen to acquire large positive potential, with consequent enhancement in the electron density.

Mishra, S. K., E-mail: nishfeb@rediffmail.com [Institute for Plasma Research (IPR), Gandhinagar 382428 (India); Sodha, M. S. [Centre of Energy Studies, Indian Institute of Technology Delhi (IITD), New Delhi 110016 (India)] [Centre of Energy Studies, Indian Institute of Technology Delhi (IITD), New Delhi 110016 (India)

2014-04-15T23:59:59.000Z

119

MEANKINETIC ENERGY,EDDY ENERGY,AND KINETIC ENERGYEXCHANGEBETWEENFLUCTUATIONSAND MEAN  

E-Print Network [OSTI]

MEANKINETIC ENERGY,EDDY ENERGY,AND KINETIC ENERGYEXCHANGEBETWEENFLUCTUATIONSAND MEAN FLOWWITHIN by cornputing three quantities suggested by the theory of turbulence: the nean kinetic energy, the eddy energy, and the energy exchange between the nean and fluctuating portions of the flow field (ca11ed dE/dt). Contours

Luther, Douglas S.

120

Kinetics and Modeling of Reductive Dechlorination at High PCE  

E-Print Network [OSTI]

Kinetics and Modeling of Reductive Dechlorination at High PCE and TCE Concentrations Seungho Yu for anaerobic reductive dechlorination of tetrachloroethylene (PCE) and trichloroethylene (TCE) were developed. The models were compared with results from batch kinetic tests conducted over a wide range of PCE and TCE

Semprini, Lewis

Note: This page contains sample records for the topic "kinetic en ergy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Kinetic Modeling of Non-thermal Escape: Planets and Exoplanets  

E-Print Network [OSTI]

Kinetic Modeling of Non-thermal Escape: Planets and Exoplanets Valery I. Shematovich Institute of Astronomy, Russian Academy of Sciences Modeling Atmospheric Escape Workshop - Spring 2012 University are populated by the atoms and molecules with both thermal and suprathermal kinetic energies (Johnson et al

Johnson, Robert E.

122

Parametric and Kinetic Minimum Spanning Trees Pankaj K. Agarwal 1  

E-Print Network [OSTI]

Parametric and Kinetic Minimum Spanning Trees Pankaj K. Agarwal 1 David Eppstein 2 Leonidas J. Guibas 3 Monika R. Henzinger 4 Abstract We consider the parametric minimum spanning tree problem- pute the sequence of minimum spanning trees generated as varies. We also consider the kinetic minimum

Eppstein, David

123

Rotational and divergent kinetic energy in the mesoscale model ALADIN  

E-Print Network [OSTI]

energy, divergent energy, ALADIN, limited-area modelling 1. Introduction Horizontal divergenceRotational and divergent kinetic energy in the mesoscale model ALADIN By V. BLAZ ICA1 *, N. Z AGAR1 received 7 June 2012; in final form 7 March 2013) ABSTRACT Kinetic energy spectra from the mesoscale

Zagar, Nedjeljka

124

Detailed chemical kinetic oxidation mechanism for a biodiesel Olivier Herbineta  

E-Print Network [OSTI]

Detailed chemical kinetic oxidation mechanism for a biodiesel surrogate Olivier Herbineta , William of methyl decanoate, a surrogate for biodiesel fuels. This model has been built by following the rules and biodiesel fuels to predict overall reactivity, but some kinetic details, including early CO2 production from

Paris-Sud XI, Université de

125

An action with positive kinetic energy term for general relativity  

E-Print Network [OSTI]

At first, we state some results in arXiv: 0707.2639, and then, using a positive kinetic energy coordinate condition given by arXiv: 0707.2639, we present an action with positive kinetic energy term for general relativity. Based on this action, the corresponding theory of canonical quantization is discussed.

T. Mei

2007-11-02T23:59:59.000Z

126

Kinetics of coal pyrolysis and devolatilization  

SciTech Connect (OSTI)

An experimentally based, conceptual model of the devolatilization of a HV bituminous coal is outlined in this report. This model contends that the relative dominance of a process type-chemical kinetic, heat transport, mass transport -- varies with the extent of reaction for a given set of heating conditions and coal type and with experimental conditions for a given coal type and extent of reaction. The rate of devolatilization mass loss process is dominated initially by heat transfer processes, then coupled mass transfer and chemical kinetics, and finally by chemical processes alone. However, the chemical composition of the initial tars are determined primarily by the chemical characteristics of the parent coal. Chemically controlled gas phase reactions of the initial tars and coupled mass transfer and chemically controlled reactions of heavy tars determine the bulk of the light gas yields. For a HV bituminous coal this conceptual model serves to quantify the Two-Component Hypothesis'' of volatiles evolution. The model postulates that the overall rates of coal devolatilization should vary with coal type insofar as the characteristics of the parent coal determine the potential tar yield and the chemical characteristics of the initial tars. Experimental evidence indicates chemical characteristics and yields of primary'' tars vary significantly with coal type. Consequently, the conceptual model would indicate a shift from transport to chemical dominance of rate processes with variation in coal type. Using the conceptual model, United Technologies Research Center has been able to correlate initial mass loss with a heat transfer index for a wide range of conditions for high tar yielding coals. 33 refs., 30 figs., 6 tabs.

Not Available

1987-01-01T23:59:59.000Z

127

A Kinetic Theory Approach to Quantum Gravity  

E-Print Network [OSTI]

We describe a kinetic theory approach to quantum gravity -- by which we mean a theory of the microscopic structure of spacetime, not a theory obtained by quantizing general relativity. A figurative conception of this program is like building a ladder with two knotted poles: quantum matter field on the right and spacetime on the left. Each rung connecting the corresponding knots represent a distinct level of structure. The lowest rung is hydrodynamics and general relativity; the next rung is semiclassical gravity, with the expectation value of quantum fields acting as source in the semiclassical Einstein equation. We recall how ideas from the statistical mechanics of interacting quantum fields helped us identify the existence of noise in the matter field and its effect on metric fluctuations, leading to the establishment of the third rung: stochastic gravity, described by the Einstein-Langevin equation. Our pathway from stochastic to quantum gravity is via the correlation hierarchy of noise and induced metric fluctuations. Three essential tasks beckon: 1) Deduce the correlations of metric fluctuations from correlation noise in the matter field; 2) Reconstituting quantum coherence -- this is the reverse of decoherence -- from these correlation functions 3) Use the Boltzmann-Langevin equations to identify distinct collective variables depicting recognizable metastable structures in the kinetic and hydrodynamic regimes of quantum matter fields and how they demand of their corresponding spacetime counterparts. This will give us a hierarchy of generalized stochastic equations -- call them the Boltzmann-Einstein hierarchy of quantum gravity -- for each level of spacetime structure, from the macroscopic (general relativity) through the mesoscopic (stochastic gravity) to the microscopic (quantum gravity).

B. L. Hu

2002-04-22T23:59:59.000Z

128

Negative kinetic energy term of general relativity and its removing  

E-Print Network [OSTI]

We first present a new Lagrangian of general relativity, which can be divided into kinetic energy term and potential energy term. Taking advantage of vierbein formalism, we reduce the kinetic energy term to a sum of five positive terms and one negative term. Some gauge conditions removing the negative kinetic energy term are discussed. Finally, we present a Lagrangian that only include positive kinetic energy terms. To remove the negative kinetic energy term leads to a new field equation of general relativity in which there are at least five equations of constraint and at most five dynamical equations, this characteristic is different from the normal Einstein field equation in which there are four equations of constraint and six dynamical equations.

T. Mei

2009-03-30T23:59:59.000Z

129

E-Print Network 3.0 - accelerated search kinetics Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

dependence of the elongation kinetics. Marked acceleration... to the slowing of protein folding kinetics by other denaturants (28) and the acceleration of folding by TFE (26......

130

Inlichtingenblad, matlab-en simulink handleiding en  

E-Print Network [OSTI]

Inlichtingenblad, matlab- en simulink handleiding en practicumopgaven IWS 1 #12;6 3 Matlab 3.1 Fundamentals Matlab. The name Matlab stands for matrix laboratory. Main principle. Matlab works and commands in Matlab are intended to be natural in a matrix sense, not unlike how they might be indicated

Al Hanbali, Ahmad

131

Inlichtingenblad, matlab en simulink handleiding en  

E-Print Network [OSTI]

Inlichtingenblad, matlab­ en simulink handleiding en practicumopgaven IWS 1 #12; 6 3 Matlab 3.1 Fundamentals Matlab. The name Matlab stands for matrix laboratory. Main principle. Matlab works and commands in Matlab are intended to be natural in a matrix sense, not unlike how they might be indicated

Al Hanbali, Ahmad

132

HIGH PRESSURE COAL COMBUSTON KINETICS PROJECT  

SciTech Connect (OSTI)

As part of the U.S. Department of Energy (DoE) initiative to improve the efficiency of coal-fired power plants and reduce the pollution generated by these facilities, DOE has funded the High-Pressure Coal Combustion Kinetics (HPCCK) Projects. A series of laboratory experiments were conducted on selected pulverized coals at elevated pressures with the specific goals to provide new data for pressurized coal combustion that will help extend to high pressure and validate models for burnout, pollutant formation, and generate samples of solid combustion products for analyses to fill crucial gaps in knowledge of char morphology and fly ash formation. Two series of high-pressure coal combustion experiments were performed using SRI's pressurized radiant coal flow reactor. The first series of tests characterized the near burner flame zone (NBFZ). Three coals were tested, two high volatile bituminous (Pittsburgh No.8 and Illinois No.6), and one sub-bituminous (Powder River Basin), at pressures of 1, 2, and 3 MPa (10, 20, and 30 atm). The second series of experiments, which covered high-pressure burnout (HPBO) conditions, utilized a range of substantially longer combustion residence times to produce char burnout levels from 50% to 100%. The same three coals were tested at 1, 2, and 3 MPa, as well as at 0.2 MPa. Tests were also conducted on Pittsburgh No.8 coal in CO2 entrainment gas at 0.2, 1, and 2 MPa to begin establishing a database of experiments relevant to carbon sequestration techniques. The HPBO test series included use of an impactor-type particle sampler to measure the particle size distribution of fly ash produced under complete burnout conditions. The collected data have been interpreted with the help of CFD and detailed kinetics simulation to extend and validate devolatilization, char combustion and pollutant model at elevated pressure. A global NOX production sub-model has been proposed. The submodel reproduces the performance of the detailed chemical reaction mechanism for the NBFZ tests.

Stefano Orsino

2005-03-30T23:59:59.000Z

133

Kinetics of the reactions of hydrogen fluoride with calcium oxide  

SciTech Connect (OSTI)

This paper studies the kinetics of interaction of gaseous hydrogen fluoride with calcium oxide at temperatures 300-700 degrees. The experiments were conducted in a laboratory adsorption apparatus modified and adapted for work with corrosive hydrogen fluoride. Calcium oxide samples in granulated form and deposited on gamma-alumina were used in the experiments. Kinetic curves representing variations of the degree of conversion of the solid samples with time are shown. The influence of retardation dure to diffusion was observed in the experiments. The influence of diffusion control on the reaction rate was also observed in a study of the reaction kinetics on supported layers of calcium oxide.

Kossaya, A.M.; Belyakov, B.P.; Kuchma, Z.V.; Sandrozd, M.K.; Vasil'eva, V.G.

1986-08-01T23:59:59.000Z

134

Evidence of critical balance in kinetic Alfven wave turbulence simulations  

SciTech Connect (OSTI)

A numerical simulation of kinetic plasma turbulence is performed to assess the applicability of critical balance to kinetic, dissipation scale turbulence. The analysis is performed in the frequency domain to obviate complications inherent in performing a local analysis of turbulence. A theoretical model of dissipation scale critical balance is constructed and compared to simulation results, and excellent agreement is found. This result constitutes the first evidence of critical balance in a kinetic turbulence simulation and provides evidence of an anisotropic turbulence cascade extending into the dissipation range. We also perform an Eulerian frequency analysis of the simulation data and compare it to the results of a previous study of magnetohydrodynamic turbulence simulations.

TenBarge, J. M.; Howes, G. G. [Department of Physics and Astronomy, University of Iowa, Iowa City, Iowa 52242 (United States)

2012-05-15T23:59:59.000Z

135

Kinetics of methanation on nickel catalysts  

SciTech Connect (OSTI)

Extensive steady-state and transient measurements of the disproportionation of carbon monoxide, the hydrogenation of deposited carbon, and methanation of carbon monoxide were performed over 2 and 10% nickel on silica support. The results indicated that the methanation of carbon monoxide involves competitively adsorbed species; that the reaction is nearly zero order in carbon monoxide at 0.1-0.5 atm CO and 1 atm H/sub 2/, but negative at higher CO partial pressures and that it becomes less negative with increasing temperature or increasing hydrogen pressure; and that the reaction order with respect to hydrogen changes from 0.5 to 1.0 with increasing CO pressure and decreasing H/sub 2/ pressure. A reaction mechanism is proposed which consists of the molecular adsorption of CO, the dissociative adsorption of H/sub 2/, dissociation of the surface CO species, and reaction of two adsorbed hydrogen atoms with the oxygen; and a multistep hydrogenation and desorption process for the adsorbed carbon. The dissociation and reaction of adsorbed CO is probably the rate-limiting step. The kinetic behavior is best represented with the assumption of a heterogeneous catalyst surface, containing three types of sites of widely varying activity.

Ho, S.V.; Harriott, P.

1980-08-01T23:59:59.000Z

136

Simulating galactic outflows with kinetic supernova feedback  

E-Print Network [OSTI]

Feedback from star formation is thought to play a key role in the formation and evolution of galaxies, but its implementation in cosmological simulations is currently hampered by a lack of numerical resolution. We present and test a sub-grid recipe to model feedback from massive stars in cosmological smoothed particle hydrodynamics simulations. The energy is distributed in kinetic form among the gas particles surrounding recently formed stars. The impact of the feedback is studied using a suite of high-resolution simulations of isolated disc galaxies embedded in dark halos with total mass 10^{10} and 10^{12} Msol/h. We focus in particular on the effect of pressure forces on wind particles within the disc, which we turn off temporarily in some of our runs to mimic a recipe that has been widely used in the literature. We find that this popular recipe gives dramatically different results because (ram) pressure forces on expanding superbubbles determine both the structure of the disc and the development of large-scale outflows. Pressure forces exerted by expanding superbubbles puff up the disc, giving the dwarf galaxy an irregular morphology and creating a galactic fountain in the massive galaxy. Hydrodynamic drag within the disc results in a strong increase of the effective mass loading of the wind for the dwarf galaxy, but quenches much of the outflow in the case of the high-mass galaxy.

Claudio Dalla Vecchia; Joop Schaye

2008-05-07T23:59:59.000Z

137

BE.420J Biomolecular Kinetics and Cellular Dynamics, Fall 2004  

E-Print Network [OSTI]

This subject deals primarily with kinetic and equilibrium mathematical models of biomolecular interactions, as well as the application of these quantitative analyses to biological problems across a wide range of levels of ...

Wittrup, K. Dane

138

Phase IV Simulant Testing of Monosodium Titanate Adsorption Kinetics  

SciTech Connect (OSTI)

The Salt Disposition Systems Engineering Team identified the adsorption kinetics of actinides and strontium onto monosodium titanate (MST) as a technical risk in several of the processing alternatives selected for additional evaluation in Phase III of their effort.

Hobbs, D.T.

1999-09-29T23:59:59.000Z

139

Nonphotochemical hole burning and dispersive kinetics in amorphous solids.  

E-Print Network [OSTI]

??Results of an extensive study, covering burn intensities in the nW to {dollar}?{dollar}W/cm{dollar}2{dollar} range, of dispersive hole growth kinetics are reported for Oxazine 720 in (more)

Kenney, Michael Joseph

1990-01-01T23:59:59.000Z

140

A Study and Comparison of SCR Reaction Kinetics from Reactor...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Data A Study and Comparison of SCR Reaction Kinetics from Reactor and Engine Experimental Data Presents experimental study of a Cu-zeolite SCR in both reactor and engine test cell,...

Note: This page contains sample records for the topic "kinetic en ergy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

atom kinetic energy: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

.self-consistent Thomas Fermi TF atom discussed w Kais, Sabre 3 Towards an exact orbital-free single-particle kinetic energy density for the inhomogeneous electron liquid in the...

142

Kinetic energy error in the NIMROD spheromak simulations Carl Sovinec  

E-Print Network [OSTI]

Kinetic energy error in the NIMROD spheromak simulations Carl Sovinec 10/25/00 Dmitri Ryutov at the ends (as in the spheromak simulations), it may lead to compression in a boundary layer.] The maximum

Sovinec, Carl

143

Mechanistic kinetic modeling of the hydrocracking of complex feedstocks  

E-Print Network [OSTI]

Two separate mechanistic kinetic models have been developed for the hydrocracking of complex feedstocks. The first model is targeted for the hydrocracking of vacuum gas oil. The second one addresses specifically the hydrocracking of long...

Kumar, Hans

2009-05-15T23:59:59.000Z

144

RIS-M-2216 CHEMICAL KINETICS IN THE GAS PHASE  

E-Print Network [OSTI]

KINETICS, EXPERIMENTAL DATA, GASES, HYDROGEN SULFIDES, PULSED IRRADIATION, RADIATION CHEMISTRY, RADIOLYSIS is subjected to high energy radiation (e.g. a- particles, Y-radiation or fast electrons), the primary products

145

Topobo : a 3-D constructive assembly system with kinetic memory  

E-Print Network [OSTI]

We introduce Topobo, a 3-D constructive assembly system em- bedded with kinetic memory, the ability to record and playback physical motion. Unique among modeling systems is Topobo's coincident physical input and output ...

Raffle, Hayes Solos, 1974-

2004-01-01T23:59:59.000Z

146

Topobo : a gestural design tool with kinetic memory  

E-Print Network [OSTI]

The modeling of kinetic systems, both in physical materials and virtual simulations, provides a methodology to better understand and explore the forces and dynamics of our physical environment. The need to experiment, ...

Parkes, Amanda Jane

2004-01-01T23:59:59.000Z

147

Fully kinetic modeling of a divergent cusped-field thruster  

E-Print Network [OSTI]

A fully kinetic, particle-in-cell plasma simulation tool has been incrementally developed by members of the Massachusetts Institute of Technology Space Propulsion Laboratory. Adapting this model to simulate the performance ...

Gildea, Stephen Robert

2009-01-01T23:59:59.000Z

148

Kinetic studies of isoprene reactions with hydroxyl and chlorine radicals  

E-Print Network [OSTI]

Kinetic studies of the isoprene oxidation reactions initiated by the hydroxyl radical OH and the chlorine atom Cl have been investigated using a fast-flow reactor in conjunction with chemical ionization mass spectrometry (CIMS) and using laser...

Suh, Inseon

2012-06-07T23:59:59.000Z

149

astrophysical systems kinetic: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 1 Thermonuclear Kinetics in Astrophysics CERN Preprints Summary: Over the billions of years since...

150

Ducted kinetic Alfven waves in plasma with steep density gradients  

SciTech Connect (OSTI)

Given their high plasma density (n {approx} 10{sup 13} cm{sup -3}), it is theoretically possible to excite Alfven waves in a conventional, moderate length (L {approx} 2 m) helicon plasma source. However, helicon plasmas are decidedly inhomogeneous, having a steep radial density gradient, and typically have a significant background neutral pressure. The inhomogeneity introduces regions of kinetic and inertial Alfven wave propagation. Ion-neutral and electron-neutral collisions alter the Alfven wave dispersion characteristics. Here, we present the measurements of propagating kinetic Alfven waves in helium helicon plasma. The measured wave dispersion is well fit with a kinetic model that includes the effects of ion-neutral damping and that assumes the high density plasma core defines the radial extent of the wave propagation region. The measured wave amplitude versus plasma radius is consistent with the pile up of wave magnetic energy at the boundary between the kinetic and inertial regime regions.

Houshmandyar, Saeid [Solar Observatory Department, Prairie View A and M University, Prairie View, Texas 77446 (United States); Department of Physics, West Virginia University, Morgantown, West Virginia 26506-6315 (United States); Scime, Earl E. [Department of Physics, West Virginia University, Morgantown, West Virginia 26506-6315 (United States)

2011-11-15T23:59:59.000Z

151

Intercalation Kinetics and Ion Mobility in Electrode Materials...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

es093daniel2011o.pdf More Documents & Publications Coupled Kinetic, Thermal, and Mechanical Modeling of FIB Micro-machined Electrodes In-Situ Electron Microscopy of Electrical...

152

Kinetic and Performance Studies of the Regeneration Phase of...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Studies of the Regeneration Phase of Model PtRhBa NOx Traps for Design and Optimization Kinetic and Performance Studies of the Regeneration Phase of Model PtRhBa NOx...

153

Kinetic modeling and automated optimization in microreactor systems  

E-Print Network [OSTI]

The optimization, kinetic investigation, or scale-up of a reaction often requires significant time and materials. Silicon microreactor systems have been shown advantageous for studying chemical reactions due to their small ...

Moore, Jason Stuart

2013-01-01T23:59:59.000Z

154

Nonlinear Adaptive Control for Bioreactors with Unknown Kinetics  

E-Print Network [OSTI]

, unknown kinetics, wastewater treatment. 1 Introduction Biological processes have become widely used on a real life wastewater treatment plant. Key words: Nonlinear adaptive control, continuous bioprocesses a pollutant (wastewater treatment...). There- fore, bioreactors require advanced regulation procedures

Bernard, Olivier

155

A unified theory on electro-kinetic extraction of contaminants  

E-Print Network [OSTI]

of contaminants from fine-grained soils. Here, the experimental and the theoretical studies conducted to date are reviewed briefly 2. 3. 1. Experimental Studies The technique of electro-kinetic extraction of salts from alkaline soils was investigated by Puri...A VNIFIED THEORY ON ELECTRO-KINETIC EXTRACTION OF CONTAMINANTS A Thesis by SUBBARAJU DATLA Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE...

Datla, Subbaraju

1994-01-01T23:59:59.000Z

156

Kinetics of Mercury(II) Adsorption and Desorption on Soil  

E-Print Network [OSTI]

Kinetics of Mercury(II) Adsorption and Desorption on Soil Y U J U N Y I N , H E R B E R T E . A L L of Delaware, Newark, Delaware 19716 D O N A L D L . S P A R K S Department of Plant and Soil Sciences kinetics of Hg(II) on four soils at pH 6 were investigated to discern the mechanisms controlling

Sparks, Donald L.

157

Consistent description of kinetics and hydrodynamics of dusty plasma  

SciTech Connect (OSTI)

A consistent statistical description of kinetics and hydrodynamics of dusty plasma is proposed based on the Zubarev nonequilibrium statistical operator method. For the case of partial dynamics, the nonequilibrium statistical operator and the generalized transport equations for a consistent description of kinetics of dust particles and hydrodynamics of electrons, ions, and neutral atoms are obtained. In the approximation of weakly nonequilibrium process, a spectrum of collective excitations of dusty plasma is investigated in the hydrodynamic limit.

Markiv, B. [Institute for Condensed Matter Physics of the National Academy of Sciences of Ukraine, 1 Svientsitskii St., 79011 Lviv (Ukraine)] [Institute for Condensed Matter Physics of the National Academy of Sciences of Ukraine, 1 Svientsitskii St., 79011 Lviv (Ukraine); Tokarchuk, M. [Institute for Condensed Matter Physics of the National Academy of Sciences of Ukraine, 1 Svientsitskii St., 79011 Lviv (Ukraine) [Institute for Condensed Matter Physics of the National Academy of Sciences of Ukraine, 1 Svientsitskii St., 79011 Lviv (Ukraine); National University Lviv Polytechnic, 12 Bandera St., 79013 Lviv (Ukraine)

2014-02-15T23:59:59.000Z

158

HCCI in a CFR engine: experiments and detailed kinetic modeling  

SciTech Connect (OSTI)

Single cylinder engine experiments and chemical kinetic modeling have been performed to study the effect of variations in fuel, equivalence ratio, and intake charge temperature on the start of combustion and the heat release rate. Neat propane and a fuel blend of 15% dimethyl-ether in methane have been studied. The results demonstrate the role of these parameters on the start of combustion, efficiency, imep, and emissions. Single zone kinetic modeling results show the trends consistent with the experimental results.

Flowers, D; Aceves, S; Smith, R; Torres, J; Girard, J; Dibble, R

1999-11-05T23:59:59.000Z

159

OBJECT KINETIC MONTE CARLO SIMULATIONS OF MICROSTRUCTURE EVOLUTION  

SciTech Connect (OSTI)

The objective is to report the development of the flexible object kinetic Monte Carlo (OKMC) simulation code KSOME (kinetic simulation of microstructure evolution) which can be used to simulate microstructure evolution of complex systems under irradiation. In this report we briefly describe the capabilities of KSOME and present preliminary results for short term annealing of single cascades in tungsten at various primary-knock-on atom (PKA) energies and temperatures.

Nandipati, Giridhar; Setyawan, Wahyu; Heinisch, Howard L.; Roche, Kenneth J.; Kurtz, Richard J.; Wirth, Brian D.

2013-09-30T23:59:59.000Z

160

Theory of semicollisional kinetic Alfven modes in sheared magnetic fields  

SciTech Connect (OSTI)

The spectra of the semicollisional kinetic Alfven modes in a sheared slab geometry are investigated, including the effects of finite ion Larmor radius and diamagnetic drift frequencies. The eigenfrequencies of the damped modes are derived analytically via asymptotic analyses. In particular, as one reduces the resistivity, we find that, due to finite ion Larmor radius effects, the damped mode frequencies asymptotically approach finite real values corresponding to the end points of the kinetic Alfven continuum.

Hahm, T.S.; Chen, L.

1985-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "kinetic en ergy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Mineral dissolution kinetics at the pore scale  

SciTech Connect (OSTI)

Mineral dissolution rates in the field have been reported to be orders of magnitude slower than those measured in the laboratory, an unresolved discrepancy that severely limits our ability to develop scientifically defensible predictive or even interpretive models for many geochemical processes in the earth and environmental sciences. One suggestion links this discrepancy to the role of physical and chemical heterogeneities typically found in subsurface soils and aquifers in producing scale-dependent rates where concentration gradients develop. In this paper, we examine the possibility that scale-dependent mineral dissolution rates can develop even at the single pore and fracture scale, the smallest and most fundamental building block of porous media. To do so, we develop two models to analyze mineral dissolution kinetics at the single pore scale: (1) a Poiseuille Flow model that applies laboratory-measured dissolution kinetics at the pore or fracture wall and couples this to a rigorous treatment of both advective and diffusive transport, and (2) a Well-Mixed Reactor model that assumes complete mixing within the pore, while maintaining the same reactive surface area, average flow rate, and geometry as the Poiseuille Flow model. For a fracture, a 1D Plug Flow Reactor model is considered in addition to quantify the effects of longitudinal versus transverse mixing. The comparison of averaged dissolution rates under various conditions of flow, pore size, and fracture length from the three models is used as a means to quantify the extent to which concentration gradients at the single pore and fracture scale can develop and render rates scale-dependent. Three important minerals that dissolve at widely different rates, calcite, plagioclase, and iron hydroxide, are considered. The modeling indicates that rate discrepancies arise primarily where concentration gradients develop due to comparable rates of reaction and advective transport, and incomplete mixing via molecular diffusion. The magnitude of the reaction rate is important, since it is found that scaling effects (and thus rate discrepancies) are negligible at the single pore and fracture scale for plagioclase and iron hydroxide because of the slow rate at which they dissolve. In the case of calcite, where dissolution rates are rapid, scaling effects can develop at high flow rates from 0.1 cm/s to 1000 cm/s and for fracture lengths less than 1 cm. At more normal flow rates, however, mixing via molecular diffusion is effective in homogenizing the concentration field, thus eliminating any discrepancies between the Poiseuille Flow and the Well-Mixed Reactor model. This suggests that a scale dependence to mineral dissolution rates is unlikely at the single pore or fracture scale under normal geological/hydrologic conditions, implying that the discrepancy between laboratory and field rates must be attributed to other factors.

Li, L.; Steefel, C.I.; Yang, L.

2007-05-24T23:59:59.000Z

162

Neptunium_Oxide_Precipitation_Kinetics_AJohnsen  

SciTech Connect (OSTI)

We evaluate the proposed NpO{sub 2}{sup +}(aq)-NpO{sub 2}(cr) reduction-precipitation system at elevated temperatures to obtain primary information on the effects of temperature, ionic strength, O{sub 2} and CO{sub 2}. Experiments conducted on unfiltered solutions at 10{sup -4} M NpO{sub 2}{sup +}(aq), neutral pH, and 200 C indicated that solution colloids strongly affect precipitation kinetics. Subsequent experiments on filtered solutions at 200, 212, and 225 C showed consistent and distinctive temperature-dependent behavior at reaction times {le} 800 hours. At longer times, the 200 C experiments showed unexpected dissolution of neptunium solids, but experiments at 212 C and 225 C demonstrated quasi steady-state neptunium concentrations of 3 x 10{sup -6} M and 6 x 10{sup -6} M, respectively. Solids from a representative experiment analyzed by X-ray diffraction were consistent with NpO{sub 2}(cr). A 200 C experiment with a NaCl concentration of 0.05 M showed a dramatic increase in the rate of neptunium loss. A 200 C experiment in an argon atmosphere resulted in nearly complete loss of aqueous neptunium. Previously proposed NpO{sub 2}{sup +}(aq)-NpO{sub 2}(cr) reduction-precipitation mechanisms in the literature specified a 1:1 ratio of neptunium loss and H{sup +} production in solution over time. However, all experiments demonstrated ratios of approximately 0.4 to 0.5. Carbonate equilibria can account for only about 40% of this discrepancy, leaving an unexpected deficit in H+ production that suggests that additional chemical processes are occurring.

Johnsen, A M; Roberts, K E; Prussin, S G

2012-06-08T23:59:59.000Z

163

POLARIZATION AND COMPRESSIBILITY OF OBLIQUE KINETIC ALFVEN WAVES  

SciTech Connect (OSTI)

It is well known that a complete description of the solar wind requires a kinetic description and that, particularly at sub-proton scales, kinetic effects cannot be ignored. It is nevertheless usually assumed that at scales significantly larger than the proton gyroscale r{sub L} , magnetohydrodynamics or its extensions, such as Hall-MHD and two-fluid models with isotropic pressures, provide a satisfactory description of the solar wind. Here we calculate the polarization and magnetic compressibility of oblique kinetic Alfven waves and show that, compared with linear kinetic theory, the isotropic two-fluid description is very compressible, with the largest discrepancy occurring at scales larger than the proton gyroscale. In contrast, introducing anisotropic pressure fluctuations with the usual double-adiabatic (or CGL) equations of state yields compressibility values which are unrealistically low. We also show that both of these classes of fluid models incorrectly describe the electric field polarization. To incorporate linear kinetic effects, we use two versions of the Landau fluid model that include linear Landau damping and finite Larmor radius (FLR) corrections. We show that Landau damping is crucial for correct modeling of magnetic compressibility, and that the anisotropy of pressure fluctuations should not be introduced without taking into account the Landau damping through appropriate heat flux equations. We also show that FLR corrections to all the retained fluid moments appear to be necessary to yield the correct polarization. We conclude that kinetic effects cannot be ignored even for kr{sub L} << 1.

Hunana, P.; Goldstein, M. L. [NASA Goddard Space Flight Center, Greenbelt, MD 20771 (United States)] [NASA Goddard Space Flight Center, Greenbelt, MD 20771 (United States); Passot, T.; Sulem, P. L.; Laveder, D. [Laboratoire J. L. Lagrange, Universite de Nice Sophia Antipolis, CNRS, Observatoire de la Cote d'Azur, BP 4229, F-06304 Nice Cedex 4 (France)] [Laboratoire J. L. Lagrange, Universite de Nice Sophia Antipolis, CNRS, Observatoire de la Cote d'Azur, BP 4229, F-06304 Nice Cedex 4 (France); Zank, G. P. [Center for Space Plasma and Aeronomic Research (CSPAR), University of Alabama in Huntsville, Huntsville, AL 35805 (United States)] [Center for Space Plasma and Aeronomic Research (CSPAR), University of Alabama in Huntsville, Huntsville, AL 35805 (United States)

2013-04-01T23:59:59.000Z

164

Peptide concentration alters intermediate species in amyloid ? fibrillation kinetics  

SciTech Connect (OSTI)

Highlights: ? A?(140) aggregation in vitro has been monitored at different concentrations. ? A?(140) fibrillation does not always follow conventional kinetic mechanisms. ? We demonstrate non-linear features in the kinetics of A?(140) fibril formation. ? At high A?(140) concentrations secondary processes dictate fibrillation speed. ? Intermediate species may play significant roles on final amyloid fibril development. -- Abstract: The kinetic mechanism of amyloid aggregation remains to be fully understood. Investigations into the species present in the different kinetic phases can assist our comprehension of amyloid diseases and further our understanding of the mechanism behind amyloid ? (A?) (140) peptide aggregation. Thioflavin T (ThT) fluorescence and transmission electron microscopy (TEM) have been used in combination to monitor A?(140) aggregation in vitro at both normal and higher than standard concentrations. The observed fibrillation behaviour deviates, in several respects, from standard concepts of the nucleationpolymerisation models and shows such features as concentration-dependent non-linear effects in the assembly mechanism. A?(140) fibrillation kinetics do not always follow conventional kinetic mechanisms and, specifically at high concentrations, intermediate structures become populated and secondary processes may further modify the fibrillation mechanism.

Garvey, M., E-mail: megan.garvey@molbiotech.rwth-aachen.de [Max-Planck Research Unit for Enzymology of Protein Folding, Weinbergweg 22, 06120 Halle (Saale) (Germany); Morgado, I., E-mail: immorgado@ualg.pt [Max-Planck Research Unit for Enzymology of Protein Folding, Weinbergweg 22, 06120 Halle (Saale) (Germany)

2013-04-12T23:59:59.000Z

165

E-Print Network 3.0 - ash kinetics mechanism Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

. Some of these ash particles may contribute to surface sealing if rainfall kinetic energy is sufficient... ......

166

Phrases of the Kinetic: Dynamic Physicality as a Dimension of the Design Process  

E-Print Network [OSTI]

construction and dynamics physics education with children; Kinetic Sketchup, a system for motion construction

Ishii, Hiroshi

167

Polymerization and Bundling Kinetics of FtsZ Filaments Ganhui Lan,* Alex Dajkovic,y  

E-Print Network [OSTI]

Polymerization and Bundling Kinetics of FtsZ Filaments Ganhui Lan,* Alex Dajkovic,y Denis Wirtz a kinetic model that describes the polymerization and bundling mechanism of FtsZ filaments. The model polymerization kinetics data of another researcher, and explains the cooperativity observed in FtsZ kinetics

Sun, Sean

168

Phase-field Model for Interstitial Loop Growth Kinetics and Thermodynamic and Kinetic Models of Irradiated Fe-Cr Alloys  

SciTech Connect (OSTI)

Microstructure evolution kinetics in irradiated materials has strongly spatial correlation. For example, void and second phases prefer to nucleate and grow at pre-existing defects such as dislocations, grain boundaries, and cracks. Inhomogeneous microstructure evolution results in inhomogeneity of microstructure and thermo-mechanical properties. Therefore, the simulation capability for predicting three dimensional (3-D) microstructure evolution kinetics and its subsequent impact on material properties and performance is crucial for scientific design of advanced nuclear materials and optimal operation conditions in order to reduce uncertainty in operational and safety margins. Very recently the meso-scale phase-field (PF) method has been used to predict gas bubble evolution, void swelling, void lattice formation and void migration in irradiated materials,. Although most results of phase-field simulations are qualitative due to the lake of accurate thermodynamic and kinetic properties of defects, possible missing of important kinetic properties and processes, and the capability of current codes and computers for large time and length scale modeling, the simulations demonstrate that PF method is a promising simulation tool for predicting 3-D heterogeneous microstructure and property evolution, and providing microstructure evolution kinetics for higher scale level simulations of microstructure and property evolution such as mean field methods. This report consists of two parts. In part I, we will present a new phase-field model for predicting interstitial loop growth kinetics in irradiated materials. The effect of defect (vacancy/interstitial) generation, diffusion and recombination, sink strength, long-range elastic interaction, inhomogeneous and anisotropic mobility on microstructure evolution kinetics is taken into account in the model. The model is used to study the effect of elastic interaction on interstitial loop growth kinetics, the interstitial flux, and sink strength of interstitial loop for interstitials. In part II, we present a generic phase field model and discuss the thermodynamic and kinetic properties in phase-field models including the reaction kinetics of radiation defects and local free energy of irradiated materials. In particular, a two-sublattice thermodynamic model is suggested to describe the local free energy of alloys with irradiated defects. Fe-Cr alloy is taken as an example to explain the required thermodynamic and kinetic properties for quantitative phase-field modeling. Finally the great challenges in phase-field modeling will be discussed.

Li, Yulan; Hu, Shenyang Y.; Sun, Xin; Khaleel, Mohammad A.

2011-06-15T23:59:59.000Z

169

The Impact of Alternative Fuels on Combustion Kinetics  

SciTech Connect (OSTI)

The research targets the development of detailed kinetic models to quantitatively characterize the impact of alternative fuels on the performance of Navy turbines and diesel engines. Such impacts include kinetic properties such as cetane number, flame speed, and emissions as well as physical properties such as the impact of boiling point distributions on fuel vaporization and mixing. The primary focus will be Fischer-Tropsch liquids made from natural gas, coal or biomass. The models will include both the effects of operation with these alternative fuels as well as blends of these fuels with conventional petroleum-based fuels. The team will develop the requisite kinetic rules for specific reaction types and incorporate these into detailed kinetic mechanisms to predict the combustion performance of neat alternative fuels as well as blends of these fuels with conventional fuels. Reduced kinetic models will be then developed to allow solution of the coupled kinetics/transport problems. This is a collaboration between the Colorado School of Mines (CSM) and the Lawrence Livermore National Laboratory (LLNL). The CSM/LLNL team plans to build on the substantial progress made in recent years in developing accurate detailed chemical mechanisms for the oxidation and pyrolysis of conventional fuels. Particular emphasis will be placed upon reactions of the isoalkanes and the daughter radicals, especially tertiary radicals, formed by abstraction from the isoalkanes. The various components of the program are described. We have been developing the kinetic models for two iso-dodecane molecules, using the same kinetic modeling formalisms that were developed for the gasoline and diesel primary reference fuels. These mechanisms, and the thermochemical and transport coefficient submodels for them, are very close to completion at the time of this report, and we expect them to be available for kinetic simulations early in the coming year. They will provide a basis for prediction and selection of desirable F-T molecules for use in jet engine simulations, where we should be able to predict the ignition, combustion and emissions characteristics of proposed fuel components. These mechanisms include the reactions and chemical species needed to describe high temperature phenomena such as shock tube ignition and flammability behavior, and they will also include low temperature kinetics to describe other ignition phenomena such as compression ignition and knocking. During the past years, our hydrocarbon kinetics modeling group at LLNL has focused a great deal on fuels typical of gasoline and diesel fuel. About 10 years ago, we developed kinetic models for the fuel octane primary reference fuels, n-heptane [1] and iso-octane [2], which have 7 and 8 carbon atoms and are therefore representative of typical gasoline fuels. N-heptane represents the low limit of knock resistance with an octane number of 0, while iso-octane is very knock resistant with an octane number of 100. High knock resistance in iso-octane was attributed largely to the large fraction of primary C-H bonds in the molecule, including 15 of the 18 C-H bonds, and the high bond energy of these primary bonds plays a large role in this knock resistance. In contrast, in the much more ignitable n-heptane, 10 of its 16 C-H bonds are much less strongly bound secondary C-H bonds, leading to its very low octane number. All of these factors, as well as a similarly complex kinetic description of the equally important role of the transition state rings that transfer H atoms within the reacting fuel molecules, were quantified and collected into large kinetic reaction mechanisms that are used by many researchers in the fuel chemistry world.

Pitz, W J; Westbrook, C K

2009-07-30T23:59:59.000Z

170

En defensa de Elsinor  

E-Print Network [OSTI]

no "cercena," sino asume e incorpora las necesidades de renovacin, de bsqueda y experimentacin. Varias generaciones de teatristas cubanos han alentado y aplicado su talento artstico a la realizacin de procesos creadores y de puestas en escena con... proceso unido a sus intereses vitales mismos: profesionales, artstico-creativos, sociales, ideo-estticos . . . ; en sus contradicciones de estilos, de mtodos, de poticas teatrales, pero con principios comunes en torno al teatrista que reclama formar...

Martí nez, Gloria Marí a

1993-10-01T23:59:59.000Z

171

Chemical Kinetics of Hydrocarbon Ignition in Practical Combustion Systems  

SciTech Connect (OSTI)

Chemical kinetic factors of hydrocarbon oxidation are examined in a variety of ignition problems. Ignition is related to the presence of a dominant chain branching reaction mechanism that can drive a chemical system to completion in a very short period of time. Ignition in laboratory environments is studied for problems including shock tubes and rapid compression machines. Modeling of the laboratory systems are used to develop kinetic models that can be used to analyze ignition in practical systems. Two major chain branching regimes are identified, one consisting of high temperature ignition with a chain branching reaction mechanism based on the reaction between atomic hydrogen with molecular oxygen, and the second based on an intermediate temperature thermal decomposition of hydrogen peroxide. Kinetic models are then used to describe ignition in practical combustion environments, including detonations and pulse combustors for high temperature ignition, and engine knock and diesel ignition for intermediate temperature ignition. The final example of ignition in a practical environment is homogeneous charge, compression ignition (HCCI) which is shown to be a problem dominated by the kinetics intermediate temperature hydrocarbon ignition. Model results show why high hydrocarbon and CO emissions are inevitable in HCCI combustion. The conclusion of this study is that the kinetics of hydrocarbon ignition are actually quite simple, since only one or two elementary reactions are dominant. However, there are many combustion factors that can influence these two major reactions, and these are the features that vary from one practical system to another.

Westbrook, C.K.

2000-07-07T23:59:59.000Z

172

Kinetics of in situ combustion. SUPRI TR 91  

SciTech Connect (OSTI)

Oxidation kinetic experiments with various crude oil types show two reaction peaks at about 250{degree}C (482{degree}F) and 400{degree}C (725{degree}F). These experiments lead to the conclusion that the fuel during high temperature oxidation is an oxygenated hydrocarbon. A new oxidation reaction model has been developed which includes two partially-overlapping reactions: namely, low-temperature oxidation followed by high-temperature oxidation. For the fuel oxidation reaction, the new model includes the effects of sand grain size and the atomic hydrogen-carbon (H/C) and oxygen-carbon (O/C) ratios of the fuel. Results based on the new model are in good agreement with the experimental data. Methods have been developed to calculate the atomic H/C and O/C ratios. These methods consider the oxygen in the oxygenated fuel, and enable a direct comparison of the atomic H/C ratios obtained from kinetic and combustion tube experiments. The finding that the fuel in kinetic tube experiments is an oxygenated hydrocarbon indicates that oxidation reactions are different in kinetic and combustion tube experiments. A new experimental technique or method of analysis will be required to obtain kinetic parameters for oxidation reactions encountered in combustion tube experiments and field operations.

Mamora, D.D.; Ramey, H.J. Jr.; Brigham, W.E.; Castanier, L.M.

1993-07-01T23:59:59.000Z

173

Gravitationally Induced Particle Production: Thermodynamics and Kinetic Theory  

E-Print Network [OSTI]

A relativistic kinetic description for the irreversible thermodynamic process of gravitationally induced particle production is proposed in the context of an expanding Friedmann-Robertson-Walker (FRW) geometry. We show that the covariant thermodynamic treatment referred to as "adiabatic" particle production provoked by the cosmic time-varying gravitational field has a consistent kinetic counterpart. The variation of the distribution function is associated to a non-collisional kinetic term of quantum-gravitational origin which is proportional to the ratio $\\Gamma/H$, where $\\Gamma$ is the gravitational particle production rate and H is the Hubble parameter. For $\\Gamma gravitation. The resulting non-equilibrium distribution function has the same functional form of equilibrium with the evolution laws corrected by the particle production process. The macroscopic temperature evolution law is also kinetically derived for massive and massless particles. The present approach points to the possibility of an exact (semi-classical) quantum-gravitational kinetic treatment by incorporating back-reaction effects in the cosmic background.

J. A. S. Lima; I. P. Baranov

2014-11-24T23:59:59.000Z

174

Kinetic Alfvn wave turbulence and formation of localized structures  

SciTech Connect (OSTI)

This work presents non-linear interaction of magnetosonic wave with kinetic Alfvn wave for intermediate ?-plasma (m{sub e}/m{sub i}???1). A set of dimensionless equations have been developed for analysis by considering ponderomotive force due to pump kinetic Alfvn wave in the dynamics of magnetosonic wave. Stability analysis has been done to study modulational instability or linear growth rate. Further, numerical simulation has been carried out to study the nonlinear stage of instability and resulting power spectrum applicable to solar wind around 1 AU. Due to the nonlinearity, background density of magnetosonic wave gets modified which results in localization of kinetic Alfvn wave. From the obtained results, we observed that spectral index follows k{sup ?3.0}, consistent with observation received by Cluster spacecraft for the solar wind around 1 AU. The result shows the steepening of power spectrum which may be responsible for heating and acceleration of plasma particles in solar wind.

Sharma, R. P. [Centre for Energy Studies, Indian Institute of Technology Delhi, Delhi 110016 (India)] [Centre for Energy Studies, Indian Institute of Technology Delhi, Delhi 110016 (India); Modi, K. V. [Centre for Energy Studies, Indian Institute of Technology Delhi, Delhi 110016 (India) [Centre for Energy Studies, Indian Institute of Technology Delhi, Delhi 110016 (India); Mechanical Engineering Department, Government Engineering College Valsad, Gujarat 396001 (India)

2013-08-15T23:59:59.000Z

175

Chemical Kinetic Models for HCCI and Diesel Combustion  

SciTech Connect (OSTI)

Predictive engine simulation models are needed to make rapid progress towards DOE's goals of increasing combustion engine efficiency and reducing pollutant emissions. These engine simulation models require chemical kinetic submodels to allow the prediction of the effect of fuel composition on engine performance and emissions. Chemical kinetic models for conventional and next-generation transportation fuels need to be developed so that engine simulation tools can predict fuel effects. The objectives are to: (1) Develop detailed chemical kinetic models for fuel components used in surrogate fuels for diesel and HCCI engines; (2) Develop surrogate fuel models to represent real fuels and model low temperature combustion strategies in HCCI and diesel engines that lead to low emissions and high efficiency; and (3) Characterize the role of fuel composition on low temperature combustion modes of advanced combustion engines.

Pitz, W J; Westbrook, C K; Mehl, M; Sarathy, S M

2010-11-15T23:59:59.000Z

176

Kinetics of high-conversion hydrocracking of bitumen  

SciTech Connect (OSTI)

Residues are complex mixtures of thousands of components. This mixture will change during hydrocracking, so that high conversion may result in a residue material with different characteristics from the starting material. Our objective is to determine the kinetics of residue conversion and yields of distillates at high conversions, and to relate these observations to the underlying chemical reactions. Athabasca bitumen was reacted in a 1-L CSTR in a multipass operation. Product from the first pass was collected, then run through the reactor again and so on, giving kinetic data under conditions that simulated a multi-reactor or packed-bed operation. Experiments were run both with hydrocracking catalyst and without added catalyst. Products were analyzed by distillation, elemental analysis, NMR, and GPC. These data will be used to derive a kinetic model for hydrocracking of bitumen residue covering a wide range of conversion (from 30% to 95%+), based on the underlying chemistry.

Nagaishi, H.; Gray, M.R. [Univ. of Alberta, Edmonton (Canada); Chan, E.W.; Sanford, E.C. [Syncrude Canada, Edmonton, Alberta (Canada)

1995-12-31T23:59:59.000Z

177

Benchmarking kinetic calculations of resistive wall mode stability  

SciTech Connect (OSTI)

Validating the calculations of kinetic resistive wall mode (RWM) stability is important for confidently predicting RWM stable operating regions in ITER and other high performance tokamaks for disruption avoidance. Benchmarking the calculations of the Magnetohydrodynamic Resistive SpectrumKinetic (MARS-K) [Y. Liu et al., Phys. Plasmas 15, 112503 (2008)], Modification to Ideal Stability by Kinetic effects (MISK) [B. Hu et al., Phys. Plasmas 12, 057301 (2005)], and Perturbed Equilibrium Nonambipolar Transport (PENT) [N. Logan et al., Phys. Plasmas 20, 122507 (2013)] codes for two Solov'ev analytical equilibria and a projected ITER equilibrium has demonstrated good agreement between the codes. The important particle frequencies, the frequency resonance energy integral in which they are used, the marginally stable eigenfunctions, perturbed Lagrangians, and fluid growth rates are all generally consistent between the codes. The most important kinetic effect at low rotation is the resonance between the mode rotation and the trapped thermal particle's precession drift, and MARS-K, MISK, and PENT show good agreement in this term. The different ways the rational surface contribution was treated historically in the codes is identified as a source of disagreement in the bounce and transit resonance terms at higher plasma rotation. Calculations from all of the codes support the present understanding that RWM stability can be increased by kinetic effects at low rotation through precession drift resonance and at high rotation by bounce and transit resonances, while intermediate rotation can remain susceptible to instability. The applicability of benchmarked kinetic stability calculations to experimental results is demonstrated by the prediction of MISK calculations of near marginal growth rates for experimental marginal stability points from the National Spherical Torus Experiment (NSTX) [M. Ono et al., Nucl. Fusion 40, 557 (2000)].

Berkery, J. W.; Sabbagh, S. A. [Department of Applied Physics and Applied Mathematics, Columbia University, New York, New York 10027 (United States)] [Department of Applied Physics and Applied Mathematics, Columbia University, New York, New York 10027 (United States); Liu, Y. Q. [Euratom/CCFE Fusion Association, Culham Science Centre, Abingdon OX14 3DB (United Kingdom)] [Euratom/CCFE Fusion Association, Culham Science Centre, Abingdon OX14 3DB (United Kingdom); Wang, Z. R.; Logan, N. C.; Park, J.-K.; Manickam, J. [Princeton Plasma Physics Laboratory, Princeton University, Princeton, New Jersey 08543 (United States)] [Princeton Plasma Physics Laboratory, Princeton University, Princeton, New Jersey 08543 (United States); Betti, R. [Laboratory for Laser Energetics, University of Rochester, Rochester, New York 14623 (United States)] [Laboratory for Laser Energetics, University of Rochester, Rochester, New York 14623 (United States)

2014-05-15T23:59:59.000Z

178

Infrared absorption spectroscopy and chemical kinetics of free radicals  

SciTech Connect (OSTI)

This research is directed at the detection, monitoring, and study of chemical kinetic behavior by infrared absorption spectroscopy of small free radical species thought to be important intermediates in combustion. During the last year, infrared kinetic spectroscopy using excimer laser flash photolysis and color-center laser probing has been employed to study the high resolution spectrum of HCCN, the rate constant of the reaction between ethynyl (C{sub 2}H) radical and H{sub 2} in the temperature region between 295 and 875 K, and the recombination rate of propargyl (CH{sub 2}CCH) at room temperature.

Curl, R.F.; Glass, G.P. [Rice Univ., Houston, TX (United States)

1993-12-01T23:59:59.000Z

179

Spectroscopy and kinetics of combustion gases at high temperatures  

SciTech Connect (OSTI)

This program involves two complementary activities: (1) development and application of cw ring dye laser absorption methods for sensitive detection of radical species and measurement of fundamental spectroscopic parameters at high temperatures; and (2) shock tube studies of reaction kinetics relevant to combustion. Species currently under investigation in the spectroscopic portion of the research include NO and CH{sub 3}; this has necessitated the continued operated at wavelengths in the range 210-230 nm. Shock tube studies of reaction kinetics currently are focussed on reactions involving CH{sub 3} radicals.

Hanson, R.K.; Bowman, C.T. [Stanford Univ., CA (United States)

1993-12-01T23:59:59.000Z

180

A coke oven model including thermal decomposition kinetics of tar  

SciTech Connect (OSTI)

A new one-dimensional coke oven model has been developed for simulating the amount and the characteristics of by-products such as tar and gas as well as coke. This model consists of both heat transfer and chemical kinetics including thermal decomposition of coal and tar. The chemical kinetics constants are obtained by estimation based on the results of experiments conducted to investigate the thermal decomposition of both coal and tar. The calculation results using the new model are in good agreement with experimental ones.

Munekane, Fuminori; Yamaguchi, Yukio [Mitsubishi Chemical Corp., Yokohama (Japan); Tanioka, Seiichi [Mitsubishi Chemical Corp., Sakaide (Japan)

1997-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "kinetic en ergy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

A kinetic scheme for pressurized flows in non uniform pipes  

E-Print Network [OSTI]

The aim of this paper is to present a kinetic numerical scheme for the computations of transient pressurised flows in closed water pipes with variable sections. Firstly, we detail the derivation of the mathematical model in curvilinear coordinates under some hypothesis and we performe a formal asymptotic analysis. Then the obtained system is written as a conservative hyperbolic partial differential system of equations, and we recall how to obtain the corresponding kinetic formulation based on an upwinding of the source term due to the "pseudo topography" performed in a close manner described by Perthame and al.

Bourdarias, Christian; Gerbi, Stphane

2008-01-01T23:59:59.000Z

182

Chemical and kinetic equilibrations via radiative parton transport  

E-Print Network [OSTI]

A hot and dense partonic system can be produced in the early stage of a relativistic heavy ion collision. How it equilibrates is important for the extraction of Quark-Gluon Plasma properties. We study the chemical and kinetic equilibrations of the Quark-Gluon Plasma using a radiative transport model. Thermal and Color-Glass-Condensate motivated initial conditions are used. We observe that screened parton interactions always lead to partial pressure isotropization. Different initial pressure anisotropies result in the same asymptotic evolution. Comparison of evolutions with and without radiative processes shows that chemical equilibration interacts with kinetic equilibration and radiative processes can contribute significantly to pressure isotropization.

Bin Zhang; Warner A. Wortman

2011-02-21T23:59:59.000Z

183

Supercooled water and the kinetic glass transition F. Sciortino,1  

E-Print Network [OSTI]

-dynamics study of the self-dynamics of water molecules in deeply supercooled liquid states. We find the superheated, stretched, and supercooled states of liquid water 4­6 ; ii the existence of a meta- stable, lowSupercooled water and the kinetic glass transition F. Sciortino,1 P. Gallo,2 P. Tartaglia,1 and S

Sciortino, Francesco

184

Research Article Kinetic Study of Epoxy Resin Decomposition  

E-Print Network [OSTI]

Research Article Kinetic Study of Epoxy Resin Decomposition in Near-Critical Water A diglycidyl ether type epoxy resin from bisphenol A, E-51, was cured by methyl- hexahydrophthalic anhydride (Me, hydrogenolysis, and alcoholysis [1316] have been reported to decompose epoxy resin into its original mono- mers

Guo, John Zhanhu

185

SUPPORTING INFORMATION Dissecting the Kinetic Process of Amyloid Fiber Formation  

E-Print Network [OSTI]

eight Type-I amyloid proteins (the yeast prion Sup35 NW region, Csg Btrunc, Ure2 protein, 2SUPPORTING INFORMATION Dissecting the Kinetic Process of Amyloid Fiber Formation through Asymptotic 2 1 , where A represents proteins with specific conformations before fibrillation, B is proteins

Zhang, Yang

186

Detailed chemical kinetic oxidation mechanism for a biodiesel surrogate  

SciTech Connect (OSTI)

A detailed chemical kinetic mechanism has been developed and used to study the oxidation of methyl decanoate, a surrogate for biodiesel fuels. This model has been built by following the rules established by Curran et al. for the oxidation of n-heptane and it includes all the reactions known to be pertinent to both low and high temperatures. Computed results have been compared with methyl decanoate experiments in an engine and oxidation of rapeseed oil methyl esters in a jet stirred reactor. An important feature of this mechanism is its ability to reproduce the early formation of carbon dioxide that is unique to biofuels and due to the presence of the ester group in the reactant. The model also predicts ignition delay times and OH profiles very close to observed values in shock tube experiments fueled by n-decane. These model capabilities indicate that large n-alkanes can be good surrogates for large methyl esters and biodiesel fuels to predict overall reactivity, but some kinetic details, including early CO{sub 2} production from biodiesel fuels, can be predicted only by a detailed kinetic mechanism for a true methyl ester fuel. The present methyl decanoate mechanism provides a realistic kinetic tool for simulation of biodiesel fuels.

Herbinet, O; Pitz, W J; Westbrook, C K

2007-09-20T23:59:59.000Z

187

Detailed chemical kinetic oxidation mechanism for a biodiesel surrogate  

SciTech Connect (OSTI)

A detailed chemical kinetic mechanism has been developed and used to study the oxidation of methyl decanoate, a surrogate for biodiesel fuels. This model has been built by following the rules established by Curran et al. for the oxidation of n-heptane and it includes all the reactions known to be pertinent to both low and high temperatures. Computed results have been compared with methyl decanoate experiments in an engine and oxidation of rapeseed oil methyl esters in a jet stirred reactor. An important feature of this mechanism is its ability to reproduce the early formation of carbon dioxide that is unique to biofuels and due to the presence of the ester group in the reactant. The model also predicts ignition delay times and OH profiles very close to observed values in shock tube experiments fueled by n-decane. These model capabilities indicate that large n-alkanes can be good surrogates for large methyl esters and biodiesel fuels to predict overall reactivity, but some kinetic details, including early CO2 production from biodiesel fuels, can be predicted only by a detailed kinetic mechanism for a true methyl ester fuel. The present methyl decanoate mechanism provides a realistic kinetic tool for simulation of biodiesel fuels.

Herbinet, O; Pitz, W J; Westbrook, C K

2007-09-17T23:59:59.000Z

188

Linear Kinetic Heat Transfer: Moment Equations, Boundary Conditions, and Knudsen  

E-Print Network [OSTI]

] and phonons [6], and the radiative transfer equation [7]. The solution of any kinetic equation is usually][25], radiative transfer [7][26], and phonon transport in crystals [6]. Despite the long history, and success method, and the methods employed in [18][19][20], are based solely on the transport equations in the bulk, and

Struchtrup, Henning

189

Desorption Kinetics of Methanol, Ethanol, and Water from Graphene  

SciTech Connect (OSTI)

The desorption kinetics of methanol, ethanol, and water from graphene covered Pt(111) are investigated. The temperature programmed desorption (TPD) spectra for both methanol and ethanol have well-resolved first, second, third, and multilayer layer desorption peaks. The alignment of the leading edges is consistent with zero-order desorption kinetics from all layers. In contrast, for water the first and second layers are not resolved. At low water coverages (< 1 ML) the initial desorption leading edges are aligned but then fall out of alignment at higher temperatures. For thicker water layers (10 to 100 ML), the desorption leading edges are in alignment throughout the desorption of the film. The coverage dependence of the desorption behavoir suggests that at low water coverages the non-alignment of the desorption leading edges is due to water dewetting from the graphene substrate. Kinetic simulations reveal that the experimental results are consistent with zero-order desorption. The simulations also show that fractional order desorption kinetics would be readily apparent in the experimental TPD spectra.

Smith, R. Scott; Matthiesen, Jesper; Kay, Bruce D.

2014-09-18T23:59:59.000Z

190

Kinetic theory of geodesic acoustic and related modes  

E-Print Network [OSTI]

Kinetic theory of geodesic acoustic and related modes A.I. Smolyakov Department of Physics · Geodesic Acoustic Modes (GAM) are relatively high frequency eigen-modes supported by plasma compressibility history of GAM and related modes ·1968 : Geodesic acoustic modes: Winsor, Johnson, Dawson ·2000-05: Surge

191

ORBITAL-FREE KINETIC-ENERGY DENSITY FUNCTIONAL THEORY  

E-Print Network [OSTI]

Chapter 5 ORBITAL-FREE KINETIC-ENERGY DENSITY FUNCTIONAL THEORY Yan Alexander Wang and Emily A Theory (DFT), there was the Thomas-Fermi (TF) model, which uses the electron density ¢¡ r£ (a function-dependent DFT Density-Functional Theory DI density-independent DM1 first-order reduced density matrix EDF energy

Wang, Yan Alexander

192

AER1301: KINETIC THEORY OF GASES Assignment #2  

E-Print Network [OSTI]

AER1301: KINETIC THEORY OF GASES Assignment #2 1. Using the formalism of the text book is as follows. Assume that the particle number density is a slowly varying function of the z coordinate #27; ? is a constant. 3. Show that if the potential function, U(r), varies as 1=r 4

Groth, Clinton P. T.

193

AER1301: KINETIC THEORY OF GASES Assignment #2  

E-Print Network [OSTI]

AER1301: KINETIC THEORY OF GASES Assignment #2 1. Using the formalism of the text book the particle number density and temperature are both slowly varying functions of the z coordinate of the previous problem is as follows. Assume that the particle number density is a slowly varying function

Groth, Clinton P. T.

194

Plasmadynamics and ionization kinetics of thermionic energy conversion  

SciTech Connect (OSTI)

To reduce the plasma arc-drop, thermionic energy conversion is studied with both analytical and numerical tools. Simplifications are made in both the plasmadynamic and ionization-recombination theories. These are applied to a scheme proposed presently using laser irradiation to enhance the ionization kinetics of the thermionic plasma and thereby reduce the arc-drop. It is also predicted that it is possible to generate the required laser light from a thermionic-type cesium plasma. The analysis takes advantage of theoretical simplifications derived for the ionization-recombination kinetics. It is shown that large laser ionization enhancements can occur and that collisional cesium recombination lasing is expected. To complement the kinetic theory, a numerical method is developed to solve the thermionic plasma dynamics. To combine the analysis of ionization-recombination kinetics with the plasma dynamics of thermionic conversion, a finite difference computer program is constructed. It is capable of solving for both unsteady and steady thermionic converter behavior including possible laser ionization enhancement or atomic recombination lasing. A proposal to improve thermionic converter performance using laser radiation is considered. In this proposed scheme, laser radiation impinging on a thermionic plasma enhances the ionization process thereby raising the plasma density and reducing the plasma arc-drop. A source for such radiation may possibly be a cesium recombination laser operating in a different thermionic converter. The possibility of this being an energy efficient process is discussed. (WHK)

Lawless, J.L. Jr.; Lam, S.H.

1982-02-01T23:59:59.000Z

195

Kinetic Properties of Alfven Modes in Tokamak Plasmas  

SciTech Connect (OSTI)

The ability to predict the stability of fast-particle-driven Alfven eigenmodes in burning fusion plasmas requires a detailed understanding of the dissipative mechanisms that damp these modes. In order to address this question, the linear gyro-kinetic, electromagnetic code LIGKA is employed to investigate their behaviour in realistic tokamak geometry. The eigenvalue formulation of LIGKA allows to calculate self-consistently the coupling of large-scaled MHD modes to the gyroradius scale-length kinetic Alfven waves. Therefore, the properties of the kineticly modified TAE mode in or near the gap (KTAE, radiative damping or 'tunnelling') and its coupling to the continuum close to the edge can be analysed numerically. In addition, an antenna-like version of LIGKA allows for a frequency scan, analogous to an external antenna.The model and the implementation of LIGKA were recently extended in order to capture the coupling of the shear Alfven waves to the sound waves. This coupling becomes important for the investigation of kinetic effects on the low-frequency phase of cascade modes, where e.g. geodesic acoustic effects play a significant role.

Lauber, Ph.; Guenter, S.; Bruedgam, M. [Max-Planck-Institut fuer Plasmaphysik, EURATOM-Association, D-85748 Garching (Germany); Koenies, A. [Max-Planck Institut fuer Plasmaphysik, EURATOM-Association, D-17489 Greifswald (Germany); Pinches, S. D. [UKAEA Fusion Association Culham Science Centre, Abingdon, Oxfordshire OX143DB (United Kingdom)

2006-11-30T23:59:59.000Z

196

Polymerization dynamics of double-stranded biopolymers: Chemical kinetic approach  

E-Print Network [OSTI]

Polymerization dynamics of double-stranded biopolymers: Chemical kinetic approach Evgeny B 19 November 2004; accepted 20 December 2004; published online 10 March 2005 The polymerization by the processes that take place during their polymerization. However, our understanding of the coupling between

197

Determination of the Kinetic Parameters of Atom Transfer Radical Polymerizations  

E-Print Network [OSTI]

Determination of the Kinetic Parameters of Atom Transfer Radical Polymerizations Young-Je Kwark a novel catalyst system for atom transfer radical polymerization (ATRP), a parameter estimation method parameters of polymerization. From our model system considering small molecular atom transfer addition

198

Improve Claus simulation by integrating kinetic limitations into equilibrium calculations  

SciTech Connect (OSTI)

Since all existing Claus simulators are based on equilibrium calculations, it is not surprising that the simulation results, including the overall sulfur yield, air to acid gas ratio, and stream compositions are somewhat different from the plant data. One method for improving the simulation is to consider the kinetic limitations in the Claus reactions. This has been accomplished in this work by integrating kinetic considerations into equilibrium calculations. Kinetic limitations have been introduced in both the Claus reaction furnace and the catalytic converters. An interactive computer program SULPLT Version 3 was written to implement the proposed modifications. The computer program was used to simulate the Claus furnace, catalytic converters, and the effect of air to acid gas ratio on sulfur recovery to check against literature data. Three Claus plants for which data exist have also been simulated. The results show that the proposed model predicts sulfur recovery, sulfur emission, optimal air to acid gas ratio, and various stream compositions more accurately than the equilibrium model. The proposed model appears to be valid, reliable, and applicable over a wide range of operating conditions (acid gas feeds ranging from 13% to 95% H/sub 2/S with different levels of impurities). The methodology developed in this study should be applicable to any reaction systems where kinetic limitations are important but where equilibrium still prevails.

Wen, T.C.

1986-01-01T23:59:59.000Z

199

Optimization of a Microfluidic Mixer for Studying Protein Folding Kinetics  

E-Print Network [OSTI]

Optimization of a Microfluidic Mixer for Studying Protein Folding Kinetics David E. Hertzog with numerical simulations to minimize the mixing time of a microfluidic mixer developed for protein folding reported continuous flow mixer for protein folding. Fast events in protein folding often occur

Santiago, Juan G.

200

Femtomole Mixer for Microsecond Kinetic Studies of Protein Folding  

E-Print Network [OSTI]

Femtomole Mixer for Microsecond Kinetic Studies of Protein Folding David E. Hertzog,, Xavier a microfluidic mixer for studying protein folding and other reactions with a mixing time of 8 µs and sample) measurements of single-stranded DNA. We also demon- strate the feasibility of measuring fast protein folding

Michalet, Xavier

Note: This page contains sample records for the topic "kinetic en ergy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Statistical Analysis of Protein Folding Kinetics Aaron R. Dinner  

E-Print Network [OSTI]

Statistical Analysis of Protein Folding Kinetics Aaron R. Dinner , Sung-Sau So ¡ , and Martin and theoretical studies over several years have led to the emergence of a unified general mechanism for protein folding that serves as a framework for the design and interpretation of research in this area [1

Dinner, Aaron

202

Kinetics of the clay roofing tile convection drying  

SciTech Connect (OSTI)

Kinetics of the convection drying process of flat tile has been investigated experimentally in an industrial tunnel dryer. Several velocities of wet tile movement through the dryer were tested to obtain maximum allowable drying rate curve. As there are various models to describe the kinetics of convection drying, finding a model that would fairly well approximate the kinetics of the whole drying process was part of the research. Especially the polynomial and exponential models were tested. It was found that exponential model of the type: B(t) = (a[minus]B[sub e])[center dot]EXP([minus]bt[sup 2])+B[sub e], ([minus]dB(t)/dt) = 2bt(B(t)[minus]B[sub e]) significantly correlates the kinetics of the whole tile drying process. Applying the maximum allowable drying rate curve obtained for flat tile in the first period of drying, a grapho-analytic model for the optimal conducting of the process has been developed.

Thomas, S. (Univ. of Osijek (Croatia). Faculty of Food Technology); Skansi, D. (Univ. of Zagreb (Croatia). Faculty of Chemical Engineering and Technology); Sokele, M. (Croatian Post and Telecommunications, Zagreb (Croatia). Telecommunications Center)

1993-01-01T23:59:59.000Z

203

Nano Research Kinetics of Molecular Recognition Mediated Nanoparticle  

E-Print Network [OSTI]

Nano Research Kinetics of Molecular Recognition Mediated Nanoparticle Self-Assembly Chinmay Soman1 the streptavidin-biotin interaction [9] 0078 Nano Res (2009) 2: 78 84 DOI 10.1007/s12274-009-9005-z Research Article #12;79Nano Res (2009) 2: 78 84 are incubated with specific antigens in a physiological buffer

204

Detailed chemical kinetic oxidation mechanism for a biodiesel surrogate  

SciTech Connect (OSTI)

A detailed chemical kinetic mechanism has been developed and used to study the oxidation of methyl decanoate, a surrogate for biodiesel fuels. This model has been built by following the rules established by Curran and co-workers for the oxidation of n-heptane and it includes all the reactions known to be pertinent to both low and high temperatures. Computed results have been compared with methyl decanoate experiments in an engine and oxidation of rapeseed oil methyl esters in a jet-stirred reactor. An important feature of this mechanism is its ability to reproduce the early formation of carbon dioxide that is unique to biofuels and due to the presence of the ester group in the reactant. The model also predicts ignition delay times and OH profiles very close to observed values in shock tube experiments fueled by n-decane. These model capabilities indicate that large n-alkanes can be good surrogates for large methyl esters and biodiesel fuels to predict overall reactivity, but some kinetic details, including early CO{sub 2} production from biodiesel fuels, can be predicted only by a detailed kinetic mechanism for a true methyl ester fuel. The present methyl decanoate mechanism provides a realistic kinetic tool for simulation of biodiesel fuels. (author)

Herbinet, Olivier; Pitz, William J.; Westbrook, Charles K. [Lawrence Livermore National Laboratory, Livermore, CA 94550 (United States)

2008-08-15T23:59:59.000Z

205

Kinetics of Silicothermic Reduction of Calcined Dolomite in Flowing Argon  

E-Print Network [OSTI]

of Experimental Rig De oxi dat ion Fu rn ac e TC TC Copper Turning Reduction Furnace Argon Gas Condenser Gas wash. Disadvantages: high impurity, high condenser area #12;© Swinburne University of Technology Aim of the project the fundamental physical chemistry Thermodynamic modelling Kinetic analysis High temperature experiments

Liley, David

206

Hydrogen pickup measurements in zirconium alloys: Relation to oxidation kinetics  

E-Print Network [OSTI]

Hydrogen pickup measurements in zirconium alloys: Relation to oxidation kinetics Adrien Couet a to reduce hydrogen pickup during operation, and the associated cladding degradation. The present study focuses on precisely and accurately measuring hydrogen pickup fraction for a set of alloys to specifically

Motta, Arthur T.

207

KINETICS OF SLURRY PHASE FISCHER-TROPSCH SYNTHESIS  

SciTech Connect (OSTI)

This report covers the fourth year of a research project conducted under the University Coal Research Program. The overall objective of this project is to develop a comprehensive kinetic model for slurry-phase Fischer-Tropsch synthesis (FTS) employing iron-based catalysts. This model will be validated with experimental data obtained in a stirred-tank slurry reactor (STSR) over a wide range of process conditions. The model will be able to predict molar flow rates and concentrations of all reactants and major product species (water, carbon dioxide, linear 1- and 2-olefins, and linear paraffins) as a function of reaction conditions in the STSR. During the fourth year of the project, an analysis of experimental data collected during the second year of this project was performed. Kinetic parameters were estimated utilizing product distributions from 27 mass balances. During the reporting period two kinetic models were employed: a comprehensive kinetic model of Dr. Li and co-workers (Yang et al., 2003) and a hydrocarbon selectivity model of Van der Laan and Beenackers (1998, 1999) The kinetic model of Yang et al. (2003) has 24 parameters (20 parameters for hydrocarbon formation, and 4 parameters for the water-gas-shift (WGS) reaction). Kinetic parameters for the WGS reaction and FTS synthesis were estimated first separately, and then simultaneously. The estimation of these kinetic parameters employed the Levenberg-Marquardt (LM) method and the trust-region reflective Newton large-scale (LS) method. A genetic algorithm (GA) was incorporated into estimation of parameters for FTS reaction to provide initial estimates of model parameters. All reaction rate constants and activation energies were found to be positive, but at the 95% confidence level the intervals were large. Agreement between predicted and experimental reaction rates has been fair to good. Light hydrocarbons are predicted fairly accurately, whereas the model underpredicts values of higher molecular weight hydrocarbons. Van der Laan and Beenackers hydrocarbon selectivity model provides a very good fit of the experimental data for hydrocarbons up to about C{sub 20}. However, the experimental data shows higher paraffin formation rates in C{sub 12}-C{sub 25} region which is likely due to hydrocracking or other secondary reactions. The model accurately captures the observed experimental trends of decreasing olefin to paraffin ratio and increasing {alpha} (chain growth length) with increase in chain length.

Dragomir B. Bukur; Gilbert F. Froment; Tomasz Olewski

2006-09-29T23:59:59.000Z

208

Crystallization Kinetics and Excess Free Energy of H2O and D2O...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Crystallization Kinetics and Excess Free Energy of H2O and D2O Nanoscale Films of Amorphous Solid Water. Crystallization Kinetics and Excess Free Energy of H2O and D2O Nanoscale...

209

Phrases of the Kinetic: Dynamic Physicality as a Construct of Interaction Design  

E-Print Network [OSTI]

, a system for motion construction and dynamics physics education with children; Kinetic Sketchup, a system Backpacks for motion modulation Evaluations Kinetic Sketch-up Design Tools for motion prototyping

Ishii, Hiroshi

210

A comparison of the point kinetics equations with the QUANDRY analytic nodal diffusion method  

E-Print Network [OSTI]

The point kinetics equations were incorporated into QUANDRY, a nuclear reactor analysis computer program which uses the analytic nodal method to solve the neutron diffusion equation. Both the point kinetics equations, solved using the IMSL MATH...

Velasquez, Arthur

1993-01-01T23:59:59.000Z

211

Theory of Chemical Kinetics and Charge Transfer based on Nonequilibrium Thermodynamics  

E-Print Network [OSTI]

Advances in the fields of catalysis and electrochemical energy conversion often involve nanoparticles, which can have kinetics surprisingly different from the bulk material. Classical theories of chemical kinetics assume ...

Bazant, Martin Z.

212

Charge transport in micas: The kinetics of FeII/III electron...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

transport in micas: The kinetics of FeIIIII electron transfer in the octahedral sheet. Charge transport in micas: The kinetics of FeIIIII electron transfer in the octahedral...

213

Progress in an oxygen-carrier reaction kinetics experiment for rotary-bed chemical looping combustion  

E-Print Network [OSTI]

The design process for an experimental platform measuring reaction kinetics in a chemical looping combustion (CLC) process is documented and justified. To enable an experiment designed to characterize the reaction kinetics ...

Jester-Weinstein, Jack (Jack L.)

2013-01-01T23:59:59.000Z

214

Thesis for the Degree of Licentiate of Engineering A Compartmental Model for Kinetics of  

E-Print Network [OSTI]

Thesis for the Degree of Licentiate of Engineering A Compartmental Model for Kinetics The thesis This licentiate thesis is the mathematical result in an ongoing project in kinetics of lipopro

Patriksson, Michael

215

Detailed chemical kinetic mechanism for the oxidation of biodiesel fuels blend surrogate  

E-Print Network [OSTI]

1 Detailed chemical kinetic mechanism for the oxidation of biodiesel fuels blend surrogate of biodiesel fuels in diesel and homogeneous charge compression ignition engines. Keywords: Methyl decanoate; Methyl decenoate; Surrogate; Oxidation; Biodiesel fuels; Kinetic modeling; Engine; Low

Paris-Sud XI, Université de

216

Exploring Frontiers in Kinetics and Mechanisms of Geochemical Processes at the Mineral/Water Interface  

E-Print Network [OSTI]

Exploring Frontiers in Kinetics and Mechanisms of Geochemical Processes at the Mineral in the Earth's Critical Zone is the kinetics. The timescales for geochemical processes range from milliseconds geochemical processes including surface complexation, mineral transformations, and oxidation

Sparks, Donald L.

217

Application of Genetic Algorithms and Thermogravimetry to Determine the Kinetics of Polyurethane Foam in Smoldering Combustion  

E-Print Network [OSTI]

In this work, the kinetic parameters governing the thermal and oxidative degradation of flexible polyurethane foam are determined using thermogravimetric data and a genetic algorithm. These kinetic parameters are needed ...

Rein, Guillermo; Lautenberger, Chris; Fernandez-Pello, Carlos; Torero, Jose L; Urban, David

218

Zeolitic Imidazolate Frameworks for Kinetic Separation of Propane and David H. Olson,  

E-Print Network [OSTI]

Zeolitic Imidazolate Frameworks for Kinetic Separation of Propane and Propene Kunhao Li, David H the first examples of MMOFs that are capable of kinetic separation of propane and propene (propylene), which

Li, Jing

219

COMUNICACIN EN SISTEMAS DISTRIBUIDOS  

E-Print Network [OSTI]

COMUNICACI?N EN SISTEMAS DISTRIBUIDOS Tema # VI Sistemas de operación II Abril-Julio 2012 Yudith Protocolos de Transporte Construcción de Bloques para la Comunicación Modelo Cliente-Servidor (Operaciones

Cardinale Villarreal, Yudith C.

220

Adsorption kinetics taking account of the interaction of nearest and next-nearest neighbors  

SciTech Connect (OSTI)

A study was carried out on the effect of the interaction between nearest and next-nearest neighbors on adsorption and desorption kinetics. The interaction effect on the adsorption kinetics is much stronger than on the desorption kinetics. The suitability of an adsorption model taking account of the two nearest neighbors for describing the experimental data was examined. The effect of taking account of the ordering of adatoms on desorption kinetics was shown for the case of 2 x 2 super-structure.

Tovbin, Yu.K.; Surovtsev, S.Yu.

1986-04-01T23:59:59.000Z

Note: This page contains sample records for the topic "kinetic en ergy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Teatro en Colombia  

E-Print Network [OSTI]

194 LATIN AMERICAN THEATRE REVIEW v ;f Grupo Teatro Taller de Colombia. Festival al Aire Puro. Foto: Alfonso Gutirrez. SPRING 1998 195 Teatro en Colombia Alfonso Gutirrez I Encuentro Internacional de Teatro Callejero Fue una celebracin... con bombos y platillos los 25 aos de labores del Teatro Taller de Colombia. Jorge Vargas y Mario Matallana en 1972 montaron Gnesis (La creacin del mundo) y empezaron a trabajar por Centro Amrica. Despus de muchos aos de luchas lograron...

Gutié rrez, Alfonso

1998-04-01T23:59:59.000Z

222

Experto Universitario en Enfermera  

E-Print Network [OSTI]

Experto Universitario en Enfermería en Reproducción Asistida VI Edición Vicerrectorado de Alumnos Fertilidad Campus de Excelencia Internacional #12;PROGRAMA BLOQUE I ­ Anatomía y Fisiología de la varón: espermato- génesis 4. Fecundación e implantación embrionaria BLOQUE II ­ Pruebas diagnósticas 5

Rey Juan Carlos, Universidad

223

On Measuring the Terms of the Turbulent Kinetic Energy Budget from an AUV LOUIS GOODMAN  

E-Print Network [OSTI]

of production of turbulent kinetic energy (TKE). Heat flux is obtained by correlating the vertical velocityOn Measuring the Terms of the Turbulent Kinetic Energy Budget from an AUV LOUIS GOODMAN School of the steady-state, homogeneous turbulent kinetic energy budgets are obtained from mea- surements of turbulence

Goodman, Louis

224

Determination of kinetic parameters in laminar flow reactors. I. Theoretical aspects  

E-Print Network [OSTI]

is the numerical evaluation of kinetic data, obtained from controlled experiments in a flow reactorDetermination of kinetic parameters in laminar flow reactors. I. Theoretical aspects T. Carraro1- mization of chemical flow reactors. The goal is the reliable determination of unknown kinetic parameters

225

Accepted Manuscript Kinetic Modelling of High Density PolyEthylene Pyrolysis: Part 1. Comparison of  

E-Print Network [OSTI]

Accepted Manuscript Kinetic Modelling of High Density PolyEthylene Pyrolysis: Part 1. Comparison this article as: Gascoin N, Navarro-Rodriguez A, Gillard P, Mangeot A, Kinetic Modelling of High Density PolyEthylene.polymdegradstab.2012.05.008 #12;M ANUSCRIPT ACCEPTED ACCEPTED MANUSCRIPT 1 Kinetic Modelling of High Density PolyEthylene

Paris-Sud XI, Université de

226

Zonal flow and field generation by finite beta drift waves and kinetic drift-Alfven waves  

E-Print Network [OSTI]

Zonal flow and field generation by finite beta drift waves and kinetic drift-Alfve´n waves P. N magnetic fields by finite beta drift waves and kinetic drift-Alfve´n waves is presented. The analysis by electrostatic drift waves to finite beta drift waves and kinetic drift-Alfve´n waves. The drift wave driven

Rubloff, Gary W.

227

COPPER-UPTAKE KINETICS OF COASTAL AND OCEANIC DIATOMS1 , Amber L. Annett3  

E-Print Network [OSTI]

COPPER-UPTAKE KINETICS OF COASTAL AND OCEANIC DIATOMS1 Jian Guo2 , Amber L. Annett3 , Rebecca L We investigated copper (Cu) acquisition mecha- nisms and uptake kinetics of the marine diatoms organic Cu complexes. Key index words: copper; Cu; diatom; Fe; iron; kinetics; Thalassiosira; transport

228

CHAPTER 5. PLASMA DESCRIPTIONS I: KINETIC, TWO-FLUID 1 Plasma Descriptions I  

E-Print Network [OSTI]

CHAPTER 5. PLASMA DESCRIPTIONS I: KINETIC, TWO-FLUID 1 Chapter 5 Plasma Descriptions I: Kinetic, Two-Fluid Descriptions of plasmas are obtained from extensions of the kinetic theory of gases of charged particles in the plasma, and because the electric and magnetic fields in the plasma must

Callen, James D.

229

Using Stochastic Roadmap Simulation to Predict Experimental Quantities in Protein Folding Kinetics: Folding Rates and  

E-Print Network [OSTI]

Using Stochastic Roadmap Simulation to Predict Experimental Quantities in Protein Folding Kinetics for studying protein folding kinetics. It uses the recently intro- duced Stochastic Roadmap Simulation (SRS validate the SRS method and indicate its potential as a general tool for studying protein folding kinetics

Pratt, Vaughan

230

UW's HoUse of KnoWledge To BeCoMe A ReAlITY  

E-Print Network [OSTI]

Can issues the faCe of diversity at the university of Washington fAll 2008 Big Picture BioEnErgy's the fa OSTERHOUT, '76, '78, UWAA President lOIS PRICE SPRATlEN, '76, UW Ombudsperson Emeritus and Ombudsperson

Yetisgen-Yildiz, Meliha

231

Un exemple de conversion d'une table de production en volume en tables de production en biomasse  

E-Print Network [OSTI]

Un exemple de conversion d'une table de production en volume en tables de production en biomasse secteur ligérien, proposée par PARD? en 1962, est convertie en quatre tables de production en biomasse correspondant chacune à une partie de l'arbre ou à l'arbre entier, biomasse foliaire exclue. La conversion est

Paris-Sud XI, Université de

232

A Pore Scale Evaluation of the Kinetics of Mineral Dissolution and Precipitation Reactions (EMSI)  

SciTech Connect (OSTI)

The chief goals for CEKA are to (1) collect and synthesize molecular-level kinetic data into a coherent framework that can be used to predict time evolution of environmental processes over a range of temporal and spatial scales; (2) train a cohort of talented and diverse students to work on kinetic problems at multiple scales; (3) develop and promote the use of new experimental techniques in environmental kinetics; (4) develop and promote the use of new modeling tools to conceptualize reaction kinetics in environmental systems; and (5) communicate our understanding of issues related to environmental kinetics and issues of scale to the broader scientific community and to the public.

Steefel, Carl I.

2006-06-01T23:59:59.000Z

233

Nonequilibrium sensing and its analogy to kinetic proofreading  

E-Print Network [OSTI]

For a paradigmatic model of chemotaxis, we analyze the effect how a nonzero affinity driving receptors out of equilibrium affects sensitivity. This affinity arises whenever changes in receptor activity involve ATP hydrolysis. The sensitivity integrated over a ligand concentration range is shown to be enhanced by the affinity, providing a measure of how much energy consumption improves sensing. With this integrated sensitivity we can establish an intriguing analogy between sensing with nonequilibrium receptors and kinetic proofreading: the increase in integrated sensitivity is equivalent to the decrease of the error in kinetic proofreading. The influence of the occupancy of the receptor on the phosphorylation and dephosphorylation reaction rates is shown to be crucial for the relation between integrated sensitivity and affinity. This influence can even lead to a regime where a nonzero affinity decreases the integrated sensitivity, which corresponds to anti-proofreading.

Hartich, David; Seifert, Udo

2015-01-01T23:59:59.000Z

234

Species separation and kinetic effects in collisional plasma shocks  

SciTech Connect (OSTI)

The properties of collisional shock waves propagating in uniform plasmas are studied with ion-kinetic calculations, in both slab and spherical geometry and for the case of one and two ion species. Despite the presence of an electric field at the shock frontand in contrast to the case where an interface is initially present [C. Bellei et al., Phys. Plasmas 20, 044702 (2013)]essentially no ion reflection at the shock front is observed due to collisions, with a probability of reflection ?10{sup ?4} for the cases presented. A kinetic two-ion-species spherical convergent shock is studied in detail and compared against an average-species calculation, confirming effects of species separation and differential heating of the ion species at the shock front. The effect of different ion temperatures on the DT and D{sup 3}He fusion reactivity is discussed in the fluid limit and is estimated to be moderately important.

Bellei, C., E-mail: bellei1@llnl.gov; Wilks, S. C.; Amendt, P. A. [Lawrence Livermore National Laboratory, 7000 East Avenue, Livermore, California 94550 (United States)] [Lawrence Livermore National Laboratory, 7000 East Avenue, Livermore, California 94550 (United States); Rinderknecht, H.; Zylstra, A.; Rosenberg, M.; Sio, H.; Li, C. K.; Petrasso, R. [Plasma Science and Fusion Center, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States)] [Plasma Science and Fusion Center, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139 (United States)

2014-05-15T23:59:59.000Z

235

COMSOL-based Nuclear Reactor Kinetics Studies at the HFIR  

SciTech Connect (OSTI)

The computational ability to accurately predict the dynamic behavior of a nuclear reactor core in response to reactivity-induced perturbations is an important subject in reactor physics. Space-time and point kinetics methodologies were developed for the purpose of studying the transient-induced behavior of the High Flux Isotope Reactor s (HFIR) compact core. The space-time simulations employed the three-energy-group neutron diffusion equations, and transients initiated by control cylinder and hydraulic tube rabbit ejections were studied. The work presented here is the first step towards creating a comprehensive multiphysics methodology for studying the dynamic behavior of the HFIR core during reactivity perturbations. The results of these studies show that point kinetics is adequate for small perturbations in which the power distribution is assumed to be time-independent, but space-time methods must be utilized to determine localized effects.

Chandler, David [ORNL] [ORNL; Freels, James D [ORNL] [ORNL; Maldonado, G Ivan [ORNL] [ORNL; Primm, Trent [ORNL] [ORNL

2011-01-01T23:59:59.000Z

236

Gasification characteristics and kinetics for an eastern oil shale  

SciTech Connect (OSTI)

Gasification tests of Indiana New Albany oil shale fines have been conducted. Thermobalance test results indicate that over 95% of the organic carbon in the shale can be gasified at 1700{degree}F and 135 psig with 30 minutes residence time under a synthesis gas atmosphere and at 1800{degree}F and 15 psig with 30 minutes residence time under a hydrogen/steam atmosphere. A simple kinetic expression for hydrogen/steam gasification weight loss has been developed. Weight loss has been described as the sum of the weight loss from two independent, simultaneous reaction paths: a rapid (<2 minutes) first order reaction and a slower gasification reaction that can be expressed in terms of the steam/carbon reaction. Work is in progress to study the gasification of other Eastern shales and improve the kinetic description of weight loss.

Lau, F.S.; Rue, D.M.; Punwani, D.V.; Rex, R.C. Jr.

1987-04-01T23:59:59.000Z

237

Systems engineering analysis of kinetic energy weapon concepts  

SciTech Connect (OSTI)

This study examines, from a systems engineering design perspective, the potential of kinetic energy weapons being used in the role of a conventional strategic weapon. Within the Department of Energy (DOE) complex, strategic weapon experience falls predominantly in the nuclear weapons arena. The techniques developed over the years may not be the most suitable methodologies for use in a new design/development arena. For this reason a more fundamental approach was pursued with the objective of developing an information base from which design decisions might be made concerning the conventional strategic weapon system concepts. The study examined (1) a number of generic missions, (2) the effects of a number of damage mechanisms from a physics perspective, (3) measures of effectiveness (MOE`s), and (4) a design envelope for kinetic energy weapon concepts. With the base of information a cut at developing a set of high-level system requirements was made, and a number of concepts were assessed against these requirements.

Senglaub, M.

1996-06-01T23:59:59.000Z

238

Kinetic dielectric decrement revisited: phenomenology of finite ion concentrations  

E-Print Network [OSTI]

With the help of a recently developed non-equilibrium approach, we investigate the ionic strength dependence of the Hubbard--Onsager dielectric decrement. We compute the depolarization of water molecules caused by the motion of ions in sodium chloride solutions from the dilute regime (0.035 M) up close to the saturation concentration (4.24 M), and find that the kinetic decrement displays a strong nonmonotonic behavior, in contrast to the prediction of available models. We introduce a phenomenological modification of the Hubbard--Onsager continuum theory, that takes into account the screening due to the ionic cloud at mean field level, and, is able to describe the kinetic decrement at high concentrations including the presence of a pronounced minimum.

Marcello Sega; Sofia Kantorovich; Axel Arnold

2014-07-16T23:59:59.000Z

239

Kinetics of gasification of black liquor char by steam  

SciTech Connect (OSTI)

This paper reports on the steam gasification kinetics of kraft black liquor char that were studied in a thermogravimetric analysis reactor. The effect of steam and hydrogen concentration on gasification rate can be described by Langmuir-Hinshelwood type kinetics. An activation energy of 210 kJ/mol was obtained. Methane formation was negligible, and H{sub 2}S was the major gaseous sulfur-containing product obtained over the temperature range studied, 873-973 K. The CO{sub 2} concentration was higher than calculated for the water-shift reaction at equilibrium. A gasification mechanism is proposed whereby CO{sub 2} is one of the primary gasification products.

Li, J.; van Heiningen, A.R.P. (Dept. of Chemical Engineering, McGill Univ., Pulp and Paper Research Inst. of Canada, Montreal, Quebec (CA))

1991-07-01T23:59:59.000Z

240

Visualizing kinetic pathways of homogeneous nucleation in colloidal crystallization  

E-Print Network [OSTI]

When a system undergoes a transition from a liquid to a solid phase, it passes through multiple intermediate structures before reaching the final state. However, our knowledge on the exact pathways of this process is limited, mainly due to the difficulty of realizing direct observations. Here, we experimentally study the evolution of symmetry and density for various colloidal systems during liquid-to-solid phase transitions, and visualize kinetic pathways with single-particle resolution. We observe the formation of relatively-ordered precursor structures with different symmetries, which then convert into metastable solids. During this conversion, two major cross-symmetry pathways always occur, regardless of the final state and the interaction potential. In addition, we find a broad decoupling of density variation and symmetry development, and discover that nucleation rarely starts from the densest regions. These findings hold for all our samples, suggesting the possibility of finding a unified picture for the complex crystallization kinetics in colloidal systems.

Peng Tan; Ning Xu; Lei Xu

2014-12-18T23:59:59.000Z

Note: This page contains sample records for the topic "kinetic en ergy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
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We encourage you to perform a real-time search of NLEBeta
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241

Dissipative kinetic Alfvn solitary waves resulting from viscosity  

SciTech Connect (OSTI)

Nonlinear small-amplitude kinetic Alfvn solitary waves (KASWs) are investigated with their anomalous kinetic viscosity effect on electrons. It is found that the structure of a hump-type KASW solution develops into a shock-type (or double layer) KASW solution for large amplitude KASWs when viscosity exists. For small amplitude KASWs, the Korteweg-de Vries (KdV) equation with an approximate pseudopotential was solved, and it is found that the hump-type KASWs develop into oscillating shock-type (kink-type) KASWs. It is also found that the oscillating scale of this structure is related to the propagation velocity and plasma beta, while the damping scale is inversely proportional to the viscosity.

Choi, C.-R.; Kang, S.-B.; Min, K.-W. [Department of Physics, Korea Advanced Institute of Science and Technology, Daejeon 305-701 (Korea, Republic of)] [Department of Physics, Korea Advanced Institute of Science and Technology, Daejeon 305-701 (Korea, Republic of); Woo, M.-H. [National Fusion Research Institute, Daejeon 305-333 (Korea, Republic of)] [National Fusion Research Institute, Daejeon 305-333 (Korea, Republic of); Hwang, J.; Park, Y.-D. [Korea Astronomy and Space Science Institute, Daejeon 305-348 (Korea, Republic of)] [Korea Astronomy and Space Science Institute, Daejeon 305-348 (Korea, Republic of)

2013-11-15T23:59:59.000Z

242

Nonlinear simplified model to study localization of kinetic Alfvn wave  

SciTech Connect (OSTI)

We have presented the numerical simulation of the coupled equations governing the dynamics of kinetic Alfvn wave (KAW) and ion acoustic wave in the intermediate ? plasma, where ? is the ratio of thermal pressure to the background magnetic pressure. We have also developed a simplified model for this nonlinear interaction using the results obtained from the simulation to understand the physics of nonlinear evolution of KAW. Localization of magnetic field intensity of KAW has been studied by means of the simplified model.

Sharma, R. P., E-mail: rpsharma@ces.iitd.ac.in; Gaur, Nidhi, E-mail: nidhiphysics@gmail.com [Centre for Energy Studies, Indian Institute of Technology, Delhi 110016 (India)] [Centre for Energy Studies, Indian Institute of Technology, Delhi 110016 (India)

2014-04-15T23:59:59.000Z

243

Consistent neutron kinetics data generation for nodal transient calculations  

SciTech Connect (OSTI)

Current three-dimensional transient codes for thermal reactors are mostly based on two-group diffusion-theory nodal models. In the two-group approach no explicit distinction is made between prompt fission neutrons and delayed neutrons. Consequently, effective delayed neutron fractions have traditionally been used in an attempt to compensate for this shortcoming. A fundamentally better approach would be to solve the nodal kinetics equations in a sufficient number of energy groups to explicitly capture neutron emission spectrum effects. However, this would require the availability of a multi-group nodal transient code as well as a lattice code to generate the appropriate multi-group nodal data for the simulator. One such simulator is the PARCS nodal transient code, which is widely used and recognized as representative of the current state-of-the-art. Unfortunately, a proper nodal data preparation path between PARCS and a lattice code is not available. Even though several industrial lattice codes could be considered as candidates, most of them are tailored to producing two-group nodal data and would require modifications to produce multi-group prompt and delayed neutron emission spectra. In this paper, the particular modifications required to match the TransLAT lattice code and the PARCS nodal transient code for BWR transient applications are reported. Some modifications to PARCS were also required to make two-group and multi-group applications fully consistent. Numerical results are presented both to verify the proper functioning of these modifications and to illuminate the impact of various nodal kinetics data approximations in a selected transient calculation. In particular, the significance of blending rodded and un-rodded kinetics data in partially rodded nodes is demonstrated. It is also confirmed that the use of delayed neutron importance factors in two-group calculations notably reduces the differences between two-group and multi-group kinetics calculations. (authors)

Akdeniz, B. [Penn State Univ., Nuclear Engineering Program, Univ. Park, PA 16802 (United States); Mueller, E.; Panayotov, D. [Westinghouse Electric Sweden, SE - 721 63 Vaesteraas (Sweden); Ivanov, K. N. [Penn State Univ., Nuclear Engineering Program, Univ. Park, PA 16802 (United States)

2006-07-01T23:59:59.000Z

244

Chemical Kinetic Modeling of Combustion of Automotive Fuels  

SciTech Connect (OSTI)

The objectives of this report are to: (1) Develop detailed chemical kinetic reaction models for components of fuels, including olefins and cycloalkanes used in diesel, spark-ignition and HCCI engines; (2) Develop surrogate mixtures of hydrocarbon components to represent real fuels and lead to efficient reduced combustion models; and (3) Characterize the role of fuel composition on production of emissions from practical automotive engines.

Pitz, W J; Westbrook, C K; Silke, E J

2006-11-10T23:59:59.000Z

245

Plasmadynamics and ionization kinetics of thermionic energy conversion  

SciTech Connect (OSTI)

To reduce the plasma arc-drop, thermionic energy conversion is studied with both analytical and numerical tools. Simplifications are made in both the plasmadynamic and ionization-recombination theories. These are applied to a scheme proposed presently using laser irradiation to enhance the ionization kinetics of the thermionic plasma and thereby reduce the arc-drop. It is also predicted that it is possible to generate the required laser light from a thermionic-type Cesium plasma. The analysis takes advantage of theoretical simplifications derived for the ionization-recombination kinetics. It is shown that large laser ionization enhancements can occur and that collisional Cesium recombination lasing is expected. To complement the kinetic theory, a numerical method is developed to solve the thermionic plasma dynamics. The effects of the complete system of electron-atom inelastic collisions on the ionization-recombination problem are shown to reduce to a system nearly as simple as the well-known one-quantum approximation. To combine the above analysis of ionization-recombination kinetics with the plasma dynamics of thermionic conversion, a finite difference computer program is constructed. Using the above developments, a proposal to improve thermionic converter performance using laser radiation is considered. In this proposed scheme, laser radiation impinging on a thermionic plasma enhances the ionization process thereby raising the plasma density and reducing the plasma arc-drop. A source for such radiation may possibly be a Cesium recombination laser operating in a different thermionic converter. The possibility of this being an energy efficient process is discussed.

Lawless, J.L. Jr.

1981-01-01T23:59:59.000Z

246

Adiabatic trapping in coupled kinetic Alfven-acoustic waves  

SciTech Connect (OSTI)

In the present work, we have discussed the effects of adiabatic trapping of electrons on obliquely propagating Alfven waves in a low {beta} plasma. Using the two potential theory and employing the Sagdeev potential approach, we have investigated the existence of arbitrary amplitude coupled kinetic Alfven-acoustic solitary waves in both the sub and super Alfvenic cases. The results obtained have been analyzed and presented graphically and can be applied to regions of space where the low {beta} assumption holds true.

Shah, H. A.; Ali, Z. [Department of Physics, G.C. University, 54000 Lahore (Pakistan); Masood, W. [COMSATS, Institute of Information Technology, Park Road, Chak Shahzad, Islamabad 44000 (Pakistan); National Centre for Physics (NCP), Shahdara Valley Road, 44000 Islamabad (Pakistan); Theoretical Plasma Physics Division, P. O. Nilore, Islamabad (Pakistan)

2013-03-15T23:59:59.000Z

247

Development of Detailed Kinetic Models for Fischer-Tropsch Fuels  

SciTech Connect (OSTI)

Fischer-Tropsch (FT) fuels can be synthesized from a syngas stream generated by the gasification of biomass. As such they have the potential to be a renewable hydrocarbon fuel with many desirable properties. However, both the chemical and physical properties are somewhat different from the petroleum-based hydrocarbons that they might replace, and it is important to account for such differences when considering using them as replacements for conventional fuels in devices such as diesel engines and gas turbines. FT fuels generally contain iso-alkanes with one or two substituted methyl groups to meet the pour-point specifications. Although models have been developed for smaller branched alkanes such as isooctane, additional efforts are required to properly capture the kinetics of the larger branched alkanes. Recently, Westbrook et al. developed a chemical kinetic model that can be used to represent the entire series of n-alkanes from C{sub 1} to C{sub 16} (Figure 1). In the current work, the model is extended to treat 2,2,4,4,6,8,8-heptamethylnonane (HMN), a large iso-alkane. The same reaction rate rules used in the iso-octane mechanism were incorporated in the HMN mechanism. Both high and low temperature chemistry was included so that the chemical kinetic model would be applicable to advanced internal combustion engines using low temperature combustion strategies. The chemical kinetic model consists of 1114 species and 4468 reactions. Concurrently with this effort, work is underway to improve the details of specific reaction classes in the mechanism, guided by high-level electronic structure calculations. Attention is focused upon development of accurate rate rules for abstraction of the tertiary hydrogens present in branched alkanes and properly accounting for the pressure dependence of the ?-scission, isomerization, and R + O{sub 2} reactions.

Westbrook, C K; Pitz, W J; Carstensen, H; Dean, A M

2008-10-28T23:59:59.000Z

248

Master equation approach to protein folding and kinetic traps  

E-Print Network [OSTI]

The master equation for 12-monomer lattice heteropolymers is solved numerically and the time evolution of the occupancy of the native state is determined. At low temperatures, the median folding time follows the Arrhenius law and is governed by the longest relaxation time. For good folders, significant kinetic traps appear in the folding funnel whereas for bad folders, the traps also occur in non-native energy valleys.

Marek Cieplak; Malte Henkel; Jan Karbowski; Jayanth R. Banavar

1998-04-21T23:59:59.000Z

249

Potential digestibilities and digestion kinetics of forage cell wall components  

E-Print Network [OSTI]

LITERATURE REVIEW. EXPERIMENTAL PROCEDURES. Chemical Analysis Colorimetric Determinations Statistical Evaluation. 10 13 15 IV RESULTS AND DISCUSSION 16 V Characteristics of Forage Kinetics of Cell Wall Digestion SUMMARY AND CONCLUSIONS... and both of these variables appear to be the result of several dynamic processes. The amount of structural carbohydrates, the main constituents of the fibrous cell wall, ruminants can digest appears to be limited by the potential digestibility...

Tauskey, William Henry

1973-01-01T23:59:59.000Z

250

Nonphotochemical hole burning and dispersive kinetics in amorphous solids  

SciTech Connect (OSTI)

Results covering burn intensities in the nW to {mu}W/cm{sup 2} range, of dispersive hole growth kinetics are reported for Oxazine 720 in glycerol glasses and polyvinyl alcohol polymer films and their deuterated analogues. A theoretical model which employs a distribution function for the hole burning rate constant based upon a Gaussian distribution for the tunnel parameter is shown to accurately describe the kinetic data. This model incorporates the linear electron-phonon coupling. A method for calculating the nonphotochemical quantum yield is presented which utilizes the Gaussian distribution of tunnel parameters. The quantum yield calculation can be extended to determine a quantum yield as a function of hole depth. The effect of spontaneous hole filling is shown to be insignificant over the burn intensity range studied. Average relaxation rates for hole burning are {approximately}8 orders of magnitude greater than for hole filling. The dispersive kinetics of hole burning are observed to be independent over the temperature range of these experiments, 1.6 to 7.0 K. 6 refs., 20 figs., 1 tab.

Kenney, M.J.

1990-09-21T23:59:59.000Z

251

Kinetics of Cd Release from Some Contaminated Calcareous Soils  

SciTech Connect (OSTI)

Contamination of soils with heavy metals may pose long-term risk to groundwater quality leading to health implications. Bioavailability of heavy metals, like cadmium (Cd) is strongly affected by sorption and desorption processes. The release of heavy metals from contaminated soils is a major contamination risks to natural waters. The release of Cd from contaminated soils is strongly influenced by its mobility and bioavailability. In this study, the kinetics of Cd desorption from ten samples of contaminated calcareous soils, with widely varying physicochemical properties, were studied using 0.01 M EDTA extraction. The median percentage of Cd released was about 27.7% of the total extractable Cd in the soils. The release of Cd was characterized by an initial fast release rate (of labile fractions) followed by a slower release rate (of less labile fractions) and a model of two first-order reactions adequately describes the observed release of Cd from the studied soil samples. There was positive correlation between the amount of Cd released at first phase of release and Cd in exchangeable fraction, indicating that this fraction of Cd is the main fraction controlling the Cd in the kinetic experiments. There was strongly negative correlation between the amount of Cd released at first and second phases of release and residual fraction, suggesting that this fraction did not contribute in Cd release in the kinetic experiments. The results can be used to provide information for evaluation of Cd potential toxicity and ecological risk from contaminated calcareous soils.

Sajadi Tabar, S.; Jalali, M., E-mail: jalali@basu.ac.ir [Bu-Ali Sina University, Department of Soil Science, College of Agriculture (Iran, Islamic Republic of)

2013-03-15T23:59:59.000Z

252

Kinetic study of bitumen release from heated shale  

SciTech Connect (OSTI)

With rising temperature shales evolve hydrocarbons discontinuously. At low temperatures, bitumens are thermally distilled (Peak 1) while at higher temperatures kerogen is pyrolyzed to lower molecular weight products (Peak 2). Hydrocarbon release occurring between these two peaks is less well understood. They have studied the kinetics of thermal bitumen release (Peak 1) from samples of the Excello and Woodford Shales and find that they are second order with activation energies of 19,000 cals/mole and 17,048 cals/ mole, respectively. The thermal release of nC/sub 26/ adsorbed on a siliceous support also followed second order kinetics. Activation energies, along with the determined Arrhenius A factor, permits the calculation of Peak 1 shape so that its contribution can be subtracted from the total hydrocarbon release. The residual curve shows two smaller peaks between the bitumen and kerogen peaks. These are tentatively assigned to adsorption on the mineral matrix and adsorption on kerogen. An important consequence of second order kinetics is that the temperature for the Peak 1 maximum varies with the amount of bitumen in the rock.

Butler, E.B.; Barker, C.

1986-10-01T23:59:59.000Z

253

Hydrotreating process kinetics for bitumen and bitumen-derived liquids  

SciTech Connect (OSTI)

Hydrodenitrogenation, hydrodesulfurization and resid conversion data for the Whiterocks bitumen and bitumen-derived liquid were analyzed using a modified power rate law model. The model incorporated the space velocity and pressure since the plug flow equation may not be applicable to laboratory-scale reactors in which complete wetting of the catalyst may not be attained. The data were obtained with the reactor operating as a fixed bed reactor in the upflow mode. The space velocity (WHSV{sup {alpha}}) term was included to account for deviations from plug flow behavior. The exponents (a,p) and the kinetic parameters were obtained by combined non-linear regression and ODE solver techniques for the analysis of laboratory data. A simple nth order power rate law expression for hydrodenitrogenation and hydrodesulfurization was examined. The higher than first order kinetics for hydrodenitrogenation and hydrodesulfurization of the bitumen and bitumen-derived liquids were explained by invoking two parallel first-order reactions; one slow and the other fast. Parallel and consecutive reaction schemes were used to examine the extent of conversion of the resid fraction to middle distillate, gas oil and gasoline and the apparent kinetic parameters were determined. It was determined that the upflow operating mode was preferred to the trickle-bed mode in the laboratory reactor to insure plug flow behavior.

Kwak, S.; Longstaff, D.C.; Deo, M.D.; Hanson, F.V.

1993-03-01T23:59:59.000Z

254

KINETICS OF HOT-GAS DESULFURIZATION SORBENTS FOR TRANSPORT REACTORS  

SciTech Connect (OSTI)

Hot-gas desulfurization for the integrated gasification combined cycle (IGCC) process has been investigated by many researchers to remove effectively hydrogen sulfide with various metal oxide sorbents at elevated temperatures. Various metal oxide sorbents are formulated with metal oxides such as Fe, Co, Zn, and Ti. Initial reaction kinetics of formulated sorbents with hydrogen sulfide is studied in the presence of various amounts of moisture and hydrogen at various reaction temperatures. The objectives of this research are to study initial reaction kinetics for a sorbent-hydrogen sulfide heterogeneous reaction system, to investigate effects of concentrations of hydrogen sulfide, hydrogen, and moisture on dynamic absorption of H{sub 2}S into sorbents, and to evaluate effects of temperature and sorbent amounts on dynamic absorption of H{sub 2}S into sorbents. Experimental data on initial reaction kinetics of hydrogen sulfide with metal oxide sorbents were obtained with a 0.83-cm{sup 3} differential reactor. In this report, the reactivity of AHI-5 was examined. This sorbent was obtained from the Research Triangle Institute (RTI). The sorbent in the form of 70 {micro}m particles are reacted with 9000-18000 ppm hydrogen sulfide at 350-500 C. The range of space time of reaction gas mixtures is 0.071-0.088 s. The range of reaction duration is 4-10800 s.

K.C. Kwon

2001-01-01T23:59:59.000Z

255

KINETICS OF HOT-GAS DESULFURIZATION SORBENTS FOR TRANSPORT REACTORS  

SciTech Connect (OSTI)

Hot-gas desulfurization for the integrated gasification combined cycle (IGCC) process has been investigated by many researchers to remove effectively hydrogen sulfide with various metal oxide sorbents at elevated temperatures. Various metal oxide sorbents are formulated with metal oxides such as Fe, Co, Zn, and Ti. Initial reaction kinetics of formulated sorbents with hydrogen sulfide is studied in the presence of various amounts of moisture and hydrogen at various reaction temperatures. The objectives of this research are to study initial reaction kinetics for a sorbent-hydrogen sulfide heterogeneous reaction system, to investigate effects of concentrations of hydrogen sulfide, hydrogen, and moisture on dynamic absorption of H{sub 2}S into sorbents, and to evaluate effects of temperature and sorbent amounts on dynamic absorption of H{sub 2}S into sorbents. Experimental data on initial reaction kinetics of hydrogen sulfide with metal oxide sorbents were obtained with a 0.83-cm{sup 3} differential reactor. The reactivity of MCRH-67 was examined in this report. This sorbent was obtained from the Research Triangle Institute (RTI). The sorbent in the form of 130 mm particles are reacted with 18000-ppm hydrogen sulfide at 350-525 C. The range of space time of reaction gas mixtures is 0.069-0.088 s. The range of reaction duration is 4-180 s.

K.C. Kwon

2002-01-01T23:59:59.000Z

256

Kinetic theory of nonlinear transport phenomena in complex plasmas  

SciTech Connect (OSTI)

In contrast to the prevalent use of the phenomenological theory of transport phenomena, a number of transport properties of complex plasmas have been evaluated by using appropriate expressions, available from the kinetic theory, which are based on Boltzmann's transfer equation; in particular, the energy dependence of the electron collision frequency has been taken into account. Following the recent trend, the number and energy balance of all the constituents of the complex plasma and the charge balance on the particles is accounted for; the Ohmic loss has also been included in the energy balance of the electrons. The charging kinetics for the complex plasma comprising of uniformly dispersed dust particles, characterized by (i) uniform size and (ii) the Mathis, Rumpl, and Nordsieck power law of size distribution has been developed. Using appropriate expressions for the transport parameters based on the kinetic theory, the system of equations has been solved to investigate the parametric dependence of the complex plasma transport properties on the applied electric field and other plasma parameters; the results are graphically illustrated.

Mishra, S. K. [Institute for Plasma Research (IPR), Gandhinagar 382428 (India); Sodha, M. S. [Centre for Energy Studies (CES), Indian Institute of Technology Delhi (IITD), New Delhi 110016 (India)

2013-03-15T23:59:59.000Z

257

Un teatro campesino en Venezuela  

E-Print Network [OSTI]

102 LATIN AMERICAN THEATRE REVIEW Un teatro campesino en Venezuela GUILLERMO KORN Producto espontneo de la participacin colectiva naci el grupo de teatro del Asentamiento Campesino Sabaneta, en el Estado Aragua de Venezuela. Las obras de su..., despert inters. En la Universidad Central de Venezuela quieren saber ms de ustedes. Para eso he venido. . . ? Podran eventualmente hacer una representacin en la Escuela de Comuni cacin Social? Almeida: {Claro que s! Si nos dan un medio para...

Korn, Guillermo

1976-10-01T23:59:59.000Z

258

KINETICS OF SLURRY PHASE FISCHER-TROPSCH SYSTHESIS  

SciTech Connect (OSTI)

This report covers the third year of this research grant under the University Coal Research program. The overall objective of this project is to develop a comprehensive kinetic model for slurry phase Fischer-Tropsch synthesis (FTS) on iron catalysts. This model will be validated with experimental data obtained in a stirred tank slurry reactor (STSR) over a wide range of process conditions. The model will be able to predict molar flow rates and concentrations of all reactants and major product species (H{sub 2}O, CO{sub 2}, linear 1- and 2-olefins, and linear paraffins) as a function of reaction conditions in the STSR. During the reporting period we utilized experimental data from the STSR, that were obtained during the first two years of the project, to perform vapor-liquid equilibrium (VLE) calculations and estimate kinetic parameters. We used a modified Peng-Robinson (PR) equation of state (EOS) with estimated values of binary interaction coefficients for the VLE calculations. Calculated vapor phase compositions were in excellent agreement with experimental values from the STSR under reaction conditions. Occasional discrepancies (for some of the experimental data) between calculated and experimental values of the liquid phase composition were ascribed to experimental errors. The VLE calculations show that the vapor and the liquid are in thermodynamic equilibrium under reaction conditions. Also, we have successfully applied the Levenberg-Marquardt method (Marquardt, 1963) to estimate parameters of a kinetic model proposed earlier by Lox and Froment (1993b) for FTS on an iron catalyst. This kinetic model is well suited for initial studies where the main goal is to learn techniques for parameter estimation and statistical analysis of estimated values of model parameters. It predicts that the chain growth parameter ({alpha}) and olefin to paraffin ratio are independent of carbon number, whereas our experimental data show that they vary with the carbon number. Predicted molar flow rates of inorganic species, n-paraffins and total olefins were generally not in good agreement with the corresponding experimental values. In the future we'll use kinetic models based on non-constant value of {alpha}.

Dragomir B. Bukur; Gilbert F. Froment; Tomasz Olewski

2005-09-29T23:59:59.000Z

259

Mster Universitario en Negocios Internacionales.  

E-Print Network [OSTI]

Máster Universitario en Negocios Internacionales. Barcelona, octubre 2014 ­ junio 2015 Programa realizado junto con: #12;Introducción 02 Máster Universitario en Negocios Internacionales Presentación La UPF Barcelona School of Management imparte el Máster Universitario en Negocios Internacionales para

260

Kinetics and mechanisms of reactions involving small aromatic reactive intermediates  

SciTech Connect (OSTI)

Small aromatic radicals such as C{sub 6}H{sub 5}, C{sub 6}H{sub 5}O and C{sub 6}H{sub 4} are key prototype species of their homologs. C{sub 6}H{sub 5} and its oxidation product, C{sub 6}H{sub 5}O are believed to be important intermediates which play a pivotal role in hydrocarbon combustion, particularly with regard to soot formation. Despite their fundamental importance, experimental data on the reaction mechanisms and reactivities of these species are very limited. For C{sub 6}H{sub 5}, most kinetic data except its reactions with NO and NO{sub 2}, were obtained by relative rate measurements. For C{sub 6}H{sub 5}O, the authors have earlier measured its fragmentation reaction producing C{sub 5}H{sub 5} + CO in shock waves. For C{sub 6}H{sub 4}, the only rate constant measured in the gas phase is its recombination rate at room temperature. The authors have proposed to investigate systematically the kinetics and mechanisms of this important class of molecules using two parallel laser diagnostic techniques--laser resonance absorption (LRA) and resonance enhanced multiphoton ionization mass spectrometry (REMPI/MS). In the past two years, study has been focused on the development of a new multipass adsorption technique--the {open_quotes}cavity-ring-down{close_quotes} technique for kinetic applications. The preliminary results of this study appear to be quite good and the sensitivity of the technique is at least comparable to that of the laser-induced fluorescence method.

Lin, M.C. [Emory Univ., Atlanta, GA (United States)

1993-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "kinetic en ergy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Reaction Path Optimization with Holonomic Constraints and Kinetic Energy Potentials  

SciTech Connect (OSTI)

Two methods are developed to enhance the stability, efficiency, and robustness of reaction path optimization using a chain of replicas. First, distances between replicas are kept equal during path optimization via holonomic constraints. Finding a reaction path is, thus, transformed into a constrained optimization problem. This approach avoids force projections for finding minimum energy paths (MEPs), and fast-converging schemes such as quasi-Newton methods can be readily applied. Second, we define a new objective function - the total Hamiltonian - for reaction path optimization, by combining the kinetic energy potential of each replica with its potential energy function. Minimizing the total Hamiltonian of a chain determines a minimum Hamiltonian path (MHP). If the distances between replicas are kept equal and a consistent force constant is used, then the kinetic energy potentials of all replicas have the same value. The MHP in this case is the most probable isokinetic path. Our results indicate that low-temperature kinetic energy potentials (<5 K) can be used to prevent the development of kinks during path optimization and can significantly reduce the required steps of minimization by 2-3 times without causing noticeable differences between a MHP and MEP. These methods are applied to three test cases, the C?eq-to-Cax isomerization of an alanine dipeptide, the ?C?- to-C? transition of an ?-D-glucopyranose, and the helix-to-sheet transition of a GNNQQNY heptapeptide. By applying the methods developed in this work, convergence of reaction path optimization can be achieved for these complex transitions, involving full atomic details and a large number of replicas (>100). For the case of helix-to-sheet transition, we identify pathways whose energy barriers are consistent with experimental measurements. Further, we develop a method based on the work energy theorem to quantify the accuracy of reaction paths and to determine whether the atoms used to define a path are enough to provide quantitative estimation of energy barriers.

Brokaw, Jason B.; Haas, Kevin R.; Chu, Jhih-wei

2009-08-11T23:59:59.000Z

262

Kinetics of aluminum fluoride complexation in acidic waters  

SciTech Connect (OSTI)

Acidic deposition has an important effect on the transport and speciation of soluble aluminum. Toxicity of aqueous aluminum seems to be strongly dependent on aluminum speciation and the presence of complexing ligands such as fluoride. A study is reported of the complex formation kinetics of AlF/sup 2 +/ in the environmentally significant pH range 2.9-4.9. The pH and temperature dependencies of the overall rate of reaction are discussed along with environmental implications for areas subjected to acidic deposition. 22 references, 6 figures, 4 tables.

Plankey, B.J.; Patterson, H.H.; Cronan, C.S.

1986-02-01T23:59:59.000Z

263

Kinetic model of catalytic oxidation of carbon monoxide on nickel  

SciTech Connect (OSTI)

A mechanism is proposed for describing the previous disclosed multiplicity of equilibrium states in the oxidation of carbon monoxide on metallic nickel. In contrast to the known mechanism for oxidation of CO on platinum metals it includes a nonlinear stage of carbon monoxide adsorption and a linear stage of oxygen adsorption. A kinetic model has been obtained and stage velocity constants have been found, providing a basis for obtaining a quantitative agreement between the calculated and experimental relations between the reaction velocity and the reagent concentrations. Opinions are stated in relation to the causes for evolution of the CO oxidation reaction from platinum metals to nickel.

Pyatnitskii, Yu.I.; Ostapyuk, V.A.

1986-07-01T23:59:59.000Z

264

Electromigration kinetics and critical current of Pb-free interconnects  

SciTech Connect (OSTI)

Electromigration kinetics of Pb-free solder bump interconnects have been studied using a single bump parameter sweep technique. By removing bump to bump variations in structure, texture, and composition, the single bump sweep technique has provided both activation energy and power exponents that reflect atomic migration and interface reactions with fewer samples, shorter stress time, and better statistics than standard failure testing procedures. Contact metallurgies based on Cu and Ni have been studied. Critical current, which corresponds to the Blech limit, was found to exist in the Ni metallurgy, but not in the Cu metallurgy. A temperature dependence of critical current was also observed.

Lu, Minhua; Rosenberg, Robert [IBM T. J. Watson Research Center, Yorktown Heights, New York 10598 (United States)

2014-04-07T23:59:59.000Z

265

Kinetic modeling and reactor simulation in hydrodesulfurization of oil factions  

SciTech Connect (OSTI)

An adiabatic multiphase reactor for diesel hydrodesulfurization (HDS) was simulated with a one-dimensional heterogeneous model. A diesel-type mixture containing benzothiophene, dibenzothiophene, and 4,6-dimethyldibenzothiophene as sulfur components and quinoline as nitrogen components was chosen as feed. A kinetic modeling for the HDS of dibenzothiophene and alkyl-substituted dibenzothiophenes based upon structural contributions was developed. According to a molecular approach the total number of rate and adsorption parameters for the HDS of a set of (substituted)-dibenzothiophenes is 1,133. In the structural contribution approach introduced here the total number of parameters has been reduced to 93.

Froment, G.F.; Depauw, G.A.; Vanrysselberghe, V. (Univ. Gent (Belgium). Lab. voor Petrochemische Techniek)

1994-12-01T23:59:59.000Z

266

Kinetics of proton pumping in cytochrome c oxidase  

E-Print Network [OSTI]

We propose a simple model of cytochrome c oxidase, including four redox centers and four protonable sites, to study the time evolution of electrostatically coupled electron and proton transfers initiated by the injection of a single electron into the enzyme. We derive a system of master equations for electron and proton state probabilities and show that an efficient pumping of protons across the membrane can be obtained for a reasonable set of parameters. All four experimentally observed kinetic phases appear naturally from our model. We also calculate the dependence of the pumping efficiency on the transmembrane voltage at different temperatures and discuss a possible mechanism of the redox-driven proton translocation.

Anatoly Yu. Smirnov; Lev G. Mourokh; Franco Nori

2009-12-04T23:59:59.000Z

267

Convergent synthesis of proteins by kinetically controlled ligation  

DOE Patents [OSTI]

The present invention concerns methods and compositions for synthesizing a polypeptide using kinetically controlled reactions involving fragments of the polypeptide for a fully convergent process. In more specific embodiments, a ligation involves reacting a first peptide having a protected cysteyl group at its N-terminal and a phenylthioester at its C-terminal with a second peptide having a cysteine residue at its N-termini and a thioester at its C-termini to form a ligation product. Subsequent reactions may involve deprotecting the cysteyl group of the resulting ligation product and/or converting the thioester into a thiophenylester.

Kent, Stephen (Chicago, IL); Pentelute, Brad (Chicago, IL); Bang, Duhee (Boston, MA); Johnson, Erik (Chicago, IL); Durek, Thomas (Chicago, IL)

2010-03-09T23:59:59.000Z

268

Non-minimal Kinetic coupling to gravity and accelerated expansion  

E-Print Network [OSTI]

We study a scalar field with kinetic term coupled to itself and to the curvature, as a source of dark energy, and analyze the role of this new coupling in the accelerated expansion at large times. In the case of scalar field dominance, the scalar field and potential giving rise to power-law expansion are found in some cases, and a dynamical equation of state is calculated for a given solution of the field equations. A behavior very close to that of the cosmological constant was found.

L. N. Granda

2009-11-19T23:59:59.000Z

269

Kinetics of beneficiated fly ash by carbon burnout  

SciTech Connect (OSTI)

The presence of carbon in fly ash requires an increase in the dosage of the air-entraining admixture for concrete mix, and may cause the admixture to lose efficiency. Specifying authorities for the concrete producers have set maximum allowable levels of residual carbon. These levels are the so called Loss On Ignition (LOI). The concrete producers` day-to-day purchasing decisions sets the LOI at 4%. The objective of the project is to investigate the kinetics of oxidation of residual carbon present in coal fly ash as a possible first step toward producing low-carbon fly ash from high-carbon, low quality fly ash.

Okoh, J.M.; Dodoo, J.N.D.; Diaz, A. [Univ. of Maryland Eastern Shore, Princess Anne, MD (United States). Dept. of Natural Sciences; Ferguson, W.; Udinskey, J.R. Jr.; Christiana, G.A. [Delmarva Power, Wilmington, DE (United States)

1997-12-31T23:59:59.000Z

270

Evaluation of kinetic phosphorescence analysis for the determination of uranium  

SciTech Connect (OSTI)

In the past, New Brunswick Laboratory (NBL) has used a fluorometric method for the determination of sub-microgram quantities of uranium. In its continuing effort to upgrade and improve measurement technology, NBL has evaluated the commercially-available KPA-11 kinetic phosphorescence analyzer (Chemchek, Richland, WA). The Chemchek KPA-11 is a bench-top instrument which performs single-measurement, quench-corrected analyses for trace uranium. It incorporates patented kinetic phosphorimetry techniques to measure and analyze sample phosphorescence as a function of time. With laser excitation and time-corrected photon counting, the KPA-11 has a lower detection limit than conventional fluorometric methods. Operated with a personal computer, the state-of-the-art KPA-11 offers extensive time resolution and phosphorescence lifetime capabilities for additional specificity. Interferences are thereby avoided while obtaining precise measurements. Routine analyses can be easily and effectively accomplished, with the accuracy and precision equivalent to the pulsed-laser fluorometric method presently performed at NBL, without the need for internal standards. Applications of kinetic phosphorimetry at NBL include the measurement of trace level uranium in retention tank, waste samples, and low-level samples. It has also been used to support other experimental activities at NBL by the measuring of nanogram amounts of uranium contamination (in blanks) in isotopic sample preparations, and the determining of elution curves of different ion exchange resins used for uranium purification. In many cases, no pretreatment of samples was necessary except to fume them with nitric acid, and then to redissolve and dilute them to an appropriate concentration with 1 M HNO{sub 3} before measurement. Concentrations were determined on a mass basis ({micro}g U/g of solution), but no density corrections were needed since all the samples (including the samples used for calibration) were in the same density matrix (1 M HNO{sub 3}). A statistical evaluation of the determination of uranium using kinetic phosphorimetry is described in this report, along with a discussion of the method, and an evaluation of the use of plastic versus quartz cuvettes. Measurement with a precision of {+-} 3--4% relative standard deviation (RSD) and an accuracy of better than {+-} 2% relative difference (RD) are obtained in the 0.0006 to 5 {micro}g U/g-solution range. The instrument detection limit is 0.04 ppb (4 x 10{sup {minus}5} {micro}g U/g solution) using quartz cells, and 0.11 ppb (11 x 10{sup {minus}5} {micro}g U/g solution) using disposable methacrylate cuvettes.

Croatto, P.V.; Frank, I.W.; Johnson, K.D.; Mason, P.B.; Smith, M.M.

1997-12-01T23:59:59.000Z

271

Kinetic study of ion-acoustic plasma vortices  

SciTech Connect (OSTI)

The kinetic theory of electron plasma waves with finite orbital angular momentum has recently been introduced by Mendonca. This model shows possibility of new kind of plasma waves and instabilities. We have extended the theory to ion-acoustic plasma vortices carrying orbital angular momentum. The dispersion equation is derived under paraxial approximation which exhibits a kind of linear vortices and their Landau damping. The numerical solutions are obtained and compared with analytical results which are in good agreement. The physical interpretation of the ion-acoustic plasma vortices and their Landau resonance conditions are given for typical case of Maxwellian plasmas.

Khan, S. A. [National Centre for Physics (NCP), Quaid-i-Azam University Campus, Islamabad 45320 (Pakistan); Aman-ur-Rehman, E-mail: amansadiq@gmail.com [Pakistan Institute of Engineering and Applied Sciences (PIEAS), P.O. Nilore, Islamabad 45650 (Pakistan); Mendonca, J. T. [IPFN, Instituto Superior Tchnico, Av. Rovisco Pais 1, 1049-001 Lisboa (Portugal)

2014-09-15T23:59:59.000Z

272

Kinetic studies of the hydrolysis of organophosphate insecticides by phosphotriesterase  

E-Print Network [OSTI]

analogue. 14 The reaction of a thiol group with DTNB . . 20 The spectra of some of the P-0 bond-containing organophosphate insecticides and their hydrolysis products . . . The kinetic plots of the OP substrates where the rate of hydrolysis is plotted... and the efficiency in the 9 catalytic activity make PTE a potentially viable tool for the hydrolytic detoxification of OP insecticides-contaminated soils. ' Scheme 2 [I R, O ? & ? ORB 0 Not Present Oximes (P2-AM) D ? N=HC~Q CHa l II D H Late-coming Oxtme...

Zaitoun, Basel M.

2002-01-01T23:59:59.000Z

273

Microsecond Microfluidic Mixing for Investigation of Protein Folding Kinetics  

SciTech Connect (OSTI)

We have developed and characterized a mixer to study the reaction kinetics of protein folding on a microsecond timescale. The mixer uses hydrodynamic focusing of pressure-driven flow in a microfluidic channel to reduce diffusion times as first demonstrated by Knight et al.[1]. Features of the mixer include 1 {micro}s mixing times, sample consumptions of order 1 nl/s, loading sample volumes on the order of microliters, and the ability to manufacture in fused silica for compatibility with most spectroscopic methods.

Hertzog, D E; Santiago, J G; Bakajin, O

2003-06-25T23:59:59.000Z

274

A microfluidic device for investigating crystal nucleation kinetics  

E-Print Network [OSTI]

We have developed an original setup using microfluidic tools allowing one to produce continuously monodisperse microreactors ($\\approx 100$ nL), and to control their temperatures as they flow in the microdevice. With a specific microchannels geometry, we are able to apply large temperature quenches to droplets containing a KNO$_3$ solution (up to 50$^{\\circ}$C in 10 s), and then to follow nucleation kinetics at high supersaturations. By measuring the probability of crystal presence in the droplets as a function of time, we estimate the nucleation rate for different supersaturations, and confront our results to the classical nucleation theory.

Philippe Laval; Jean-Baptiste Salmon; Mathieu Joanicot

2006-12-20T23:59:59.000Z

275

Chemical Kinetic Modeling of Fuels | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-Up fromDepartmentTieCelebrate Earth DayFuels Chemical Kinetic Modeling of Fuels 2010 DOE

276

Chemical Kinetic Research on HCCI & Diesel Fuels  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-Up fromDepartmentTieCelebrate Earth DayFuels Chemical Kinetic Modeling of FuelsLaboratory

277

A kinetic model for the liquefaction of Texas lignite  

E-Print Network [OSTI]

shortages in the United States has led to investigations in alternative energy sources. Of particular interest is the lignite resource in Texas which is mainly situated in the east and central regions north of the Colorado River. There is an estimated...A KINETIC MODEL FOR THE LIQUEFACTION OF TEXAS LIGNITE 4 Thesis by SANDRA KAY BALKY Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement for the degree of MASTER OF SCIENCE y 1980 Major Subject...

Haley, Sandra Kay

1980-01-01T23:59:59.000Z

278

Electron kinetics in a microdischarge in nitrogen at atmospheric pressure  

SciTech Connect (OSTI)

Electron kinetics during a microdischarge in nitrogen at atmospheric pressure is studied using the one-dimensional Particle-in-Cell/Monte Carlo Collisions model. It is obtained that the electron energy distribution function can be divided into three parts, namely, the non-equilibrium low-energy part, the Maxwellian function at moderate energies, and the high-energy tail. Simulation results showed that the role of the high-energy tail of electron energy distribution increases, when the distance between electrodes increases.

Levko, Dmitry [LAPLACE (Laboratoire Plasma et Conversion d'Energie), Universite de Toulouse, UPS, INPT Toulouse, 118 route de Narbonne, F-31062 Toulouse cedex 9 (France)] [LAPLACE (Laboratoire Plasma et Conversion d'Energie), Universite de Toulouse, UPS, INPT Toulouse, 118 route de Narbonne, F-31062 Toulouse cedex 9 (France)

2013-12-14T23:59:59.000Z

279

Thermodynamic and kinetic control of the lateral Si wire growth  

SciTech Connect (OSTI)

Reproducible lateral Si wire growth has been realized on the Si (100) surface. In this paper, we present experimental evidence showing the unique role that carbon plays in initiating lateral growth of Si wires on a Si (100) substrate. Once initiated in the presence of ?5 ML of C, lateral growth can be achieved in the range of temperatures, T?=?450650?C, and further controlled by the interplay of the flux of incoming Si atoms with the size and areal density of Au droplets. Critical thermodynamic and kinetic aspects of the growth are discussed in detail.

Dedyulin, Sergey N., E-mail: sdedyuli@uwo.ca; Goncharova, Lyudmila V. [Department of Physics and Astronomy, The University of Western Ontario, 1151 Richmond St., London, Ontario N6A 3K7 (Canada)

2014-03-24T23:59:59.000Z

280

Kinetic Theory of Turbulent Multiphase Flow | The Ames Laboratory  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFunInfraredJeffersonJonathan PershingrelocatesKayeAnalysis of MicrobialKinetic

Note: This page contains sample records for the topic "kinetic en ergy" from the National Library of EnergyBeta (NLEBeta).
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281

A microrheological study of hydrogel kinetics and micro-heterogeneity  

E-Print Network [OSTI]

DOI 10.1140/epje/i2014-14044-y Regular Article Eur. Phys. J. E (2014) 37: 44 THE EUROPEAN PHYSICAL JOURNAL E A microrheological study of hydrogel kinetics and micro-heterogeneity Anders Aufderhorst-Roberts1,a, William J. Frith2, and Athene M. Donald... unique mechan- ical properties [5]. The range of available low-molecular-weight hydro- gelating systems has increased in recent years as their discovery has steadily relied more upon rational de- sign and less upon serendipity [6]. Hydrogelating sys- tems...

Aufderhorst-Roberts, Anders; Frith, William J.; Donald, Athene M.

2014-05-27T23:59:59.000Z

282

Pyrolysis Kinetics and Chemical Structure Considerations of a Green River Oil Shale and Its Derivatives.  

E-Print Network [OSTI]

??This work had the objective of determining both the kinetic parameters for the pyrolysis of oil shale and kerogen as well as using analytical techniques (more)

Hillier, James L

2011-01-01T23:59:59.000Z

283

Comparison of Palladium and Platinum Water Gas Shift Kinetics Using Density Functional Theory Models.  

E-Print Network [OSTI]

??The Water Gas Shift (WGS) reaction can be either thermodynamically or kinetically limited, depending on process conditions. Improved catalysts are of particular interest at low (more)

Clay, John

2014-01-01T23:59:59.000Z

284

Comparison of palladium and platinum Water Gas Shift reaction kinetics using density functional theory models.  

E-Print Network [OSTI]

?? The Water Gas Shift (WGS) reaction can be either thermodynamically or kinetically limited, depending on process conditions. Improved catalysts are of particular interest at (more)

Clay, John P.

2014-01-01T23:59:59.000Z

285

E-Print Network 3.0 - anodic reaction kinetics Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

CELLS Summary: with electrochemical kinetics in active regions of anode and cathode of a SOFC. In the following section, the model... occurs by the following reactions. Oxidation...

286

E-Print Network 3.0 - atomistic kinetic monte Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Materials Science ; Physics 5 Mesoscopic model for dynamic simulations of carbon nanotubes Leonid V. Zhigilei* Summary: of the potential energy and kinetic energy of a 395...

287

E-Print Network 3.0 - analysing kinetic models Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

changes. Dynamics, stability... and control of reactor systems. Modeling neutronic and thermal processes. System characterization in time... kinetics and power plant dynamics, and...

288

Fundamental Mechanisms of Copper CMP Passivation Kinetics of Copper in CMP Slurry Constituents  

E-Print Network [OSTI]

Tribochemical Mechanisms of Copper Chemical MechanicalE06-02 Fundamental Mechanisms of Copper CMP PassivationKinetics of Copper in CMP Slurry Constituents Shantanu

Tripathi, Shantanu; Doyle, F M; Dornfeld, David

2009-01-01T23:59:59.000Z

289

E-Print Network 3.0 - axial kinetic energy Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

axial flow fan systems. Despite... -vortex-driven flow structures to increase the energy efficiency of axial flow fan systems to provide high quality... the mean kinetic...

290

On spherically symmetric metric satisfying the positive kinetic energy coordinate condition  

E-Print Network [OSTI]

Generally speaking, there is a negative kinetic energy term in the Lagrangian of the Einstein-Hilbert action of general relativity; On the other hand, the negative kinetic energy term can be vanished by designating a special coordinate system. For general spherically symmetric metric, the question that seeking special coordinate system that satisfies the positive kinetic energy coordinate condition is referred to solving a linear first-order partial differential equation. And then, we present a metric corresponding to the Reissner-Nordstrom solution that satisfies the positive kinetic energy coordinate condition. Finally, we discuss simply the case of the Tolman metric.

T. Mei

2008-02-28T23:59:59.000Z

291

Kinetics and thermodynamics of hydrotreating synthetic middle distillates  

SciTech Connect (OSTI)

Middle distillates from the Tar Sands deposits in Alberta are an important component of diesel and jet fuels in the Canadian market. Commercial catalysts based on sulfided Ni-Mo and Ni-W are currently used to hydrogenate synthetic distillates to improve the cetane number and smoke point. In previous work {sup 13}C NMR was used to study the kinetics of overall hydrogenation of aromatics over sulfided Co-Mo, Ni-Mo and Ni-W catalysts. Arrhenius parameters were obtained for hydrogenation over sulfided Ni-W catalyst for a similar distillate feedstock. In the latter study, mass spectrometry was used to quantitate the three major aromatic hydrocarbon group types in the feed and products. In this study, liquid products from hydrotreating experiments with a hydrotreated distillate from delayed coking of Athabasca bitumen and sulfided Co-Mo and Ni-Mo catalysts have been analyzed by mass spectrometry. This completes a preliminary comparison of the kinetics of hydrogenation of alkylbenzenes, benzocycloparaffins and benzodicycloparaffins, the three major aromatic hydrocarbon types in these distillates.

Fisher, I.P. (Petro-Canada R and D Dept., Sheridan Park, Ontario (Canada)); Wilson, M.F. (CANMET, Ottawa, Ontario (Canada))

1987-04-01T23:59:59.000Z

292

Observation of a crossover in kinetic aggregation of Palladium colloids  

E-Print Network [OSTI]

We use field emission scanning electron microscope (FE-SEM) to investigate the growth of palladium colloids over the surface of thin films of WO3/glass. The film is prepared by Pulsed Laser Deposition (PLD) at different temperatures. A PdCl2 (aq) droplet is injected on the surface and in the presence of steam hydrogen the droplet is dried through a reduction reaction process. Two distinct aggregation regimes of palladium colloids are observed over the substrates. We argue that the change in aggregation dynamics emerges when the measured water drop Contact Angel (CA) for the WO3/glass thin films passes a certain threshold value, namely CA = 46 degrees, where a crossover in kinetic aggregation of palladium colloids occurs. Our results suggest that the mass fractal dimension of palladium aggregates follows a power-law behavior. The fractal dimension (Df) in the fast aggregation regime, where the measured CA values vary from 27 up to 46 degrees, according to different substrate deposition temperatures, is Df = 1.75 (0.02). This value of Df is in excellent agreement with kinetic aggregation of other colloidal systems in fast aggregation regime. Whereas for the slow aggregation regime, with CA = 58 degrees, the fractal dimension changes abruptly to Df=1.92 (0.03). We have also used a modified Box-Counting method to calculate fractal dimension of gray-level images and observe that the crossover at around CA = 46 degrees remains unchanged.

M. Ghafari; M. Ranjbar; S. Rouhani

2014-12-27T23:59:59.000Z

293

Progress in Chemical Kinetic Modeling for Surrogate Fuels  

SciTech Connect (OSTI)

Gasoline, diesel, and other alternative transportation fuels contain hundreds to thousands of compounds. It is currently not possible to represent all these compounds in detailed chemical kinetic models. Instead, these fuels are represented by surrogate fuel models which contain a limited number of representative compounds. We have been extending the list of compounds for detailed chemical models that are available for use in fuel surrogate models. Detailed models for components with larger and more complicated fuel molecular structures are now available. These advancements are allowing a more accurate representation of practical and alternative fuels. We have developed detailed chemical kinetic models for fuels with higher molecular weight fuel molecules such as n-hexadecane (C16). Also, we can consider more complicated fuel molecular structures like cyclic alkanes and aromatics that are found in practical fuels. For alternative fuels, the capability to model large biodiesel fuels that have ester structures is becoming available. These newly addressed cyclic and ester structures in fuels profoundly affect the reaction rate of the fuel predicted by the model. Finally, these surrogate fuel models contain large numbers of species and reactions and must be reduced for use in multi-dimensional models for spark-ignition, HCCI and diesel engines.

Pitz, W J; Westbrook, C K; Herbinet, O; Silke, E J

2008-06-06T23:59:59.000Z

294

Hydro-kinetic approach to relativistic heavy ion collisions  

E-Print Network [OSTI]

We develop a combined hydro-kinetic approach which incorporates a hydrodynamical expansion of the systems formed in \\textit{A}+\\textit{A} collisions and their dynamical decoupling described by escape probabilities. The method corresponds to a generalized relaxation time ($\\tau_{\\text{rel}}$) approximation for the Boltzmann equation applied to inhomogeneous expanding systems; at small $\\tau_{\\text{rel}}$ it also allows one to catch the viscous effects in hadronic component - hadron-resonance gas. We demonstrate how the approximation of sudden freeze-out can be obtained within this dynamical picture of continuous emission and find that hypersurfaces, corresponding to a sharp freeze-out limit, are momentum dependent. The pion $m_{T}$ spectra are computed in the developed hydro-kinetic model, and compared with those obtained from ideal hydrodynamics with the Cooper-Frye isothermal prescription. Our results indicate that there does not exist a universal freeze-out temperature for pions with different momenta, and support an earlier decoupling of higher $p_{T}$ particles. By performing numerical simulations for various initial conditions and equations of state we identify several characteristic features of the bulk QCD matter evolution preferred in view of the current analysis of heavy ion collisions at RHIC energies.

S. V. Akkelin; Y. Hama; Iu. A. Karpenko; Yu. M. Sinyukov

2008-08-28T23:59:59.000Z

295

Solar kinetics` photovoltaic concentrator module and tracker development  

SciTech Connect (OSTI)

Solar Kinetics, Inc., has been developing a point-focus concentrating photovoltaic module and tracker system under contract to Sandia National Laboratories. The primary focus of the contract was to achieve a module design that was manufacturable and passed Sandia`s environmental testing. Nine modules of two variations were assembled, tested, and characterized in Phase 1, and results of these tests were promising, with module efficiency approaching the theoretical limit achievable with the components used. The module efficiency was 11.9% at a solar irradiance of 850 W/m{sup 2} and an extrapolated cell temperature of 25{degrees}C. Improvements in module performance are anticipated as cell efficiencies meet their expectations. A 2-kW tracker and controller accommodating 20 modules was designed, built, installed, and operated at Solar Kinetics` test site. The drive used many commercially available components in an innovative arrangement to reduce cost and increase reliability. Backlash and bearing play were controlled by use of preloaded, low slip-stick, synthetic slide bearings. The controller design used a standard industrial programmable logic controller to perform ephemeris calculations, operate the actuators, and monitor encoders.

White, D.L.; Howell, B. [Solar Kinetics, Inc., Dallas, TX (United States)

1995-11-01T23:59:59.000Z

296

A comprehensive kinetics model for CO oxidation during char combustion  

SciTech Connect (OSTI)

The most important parameter in representing energy feedback to a particle during char combustion concerns the oxidation of CO to CO/sub 2/. If substantial oxidation of CO occurs near a particle, then the greater heat of combustion for the complete oxidation of carbon to CO/sub 2/ (94.1 kcal/mole vs. 26.4 kcal/mole for oxidation to CO) is available for energy feedback mechanisms. ''Energy feedback'' is here defined as any situation in which an individual particle receives a significant fraction of its heat of combustion directly, through the localized oxidation of emitted combustible species, i.e. CO. Conversely, if the oxidation of CO does not occur near a particle, then energy feedback will occur only indirectly, through heating of the bulk gas. The primary reaction product at the particle surface during char combustion is generally considered to be CO, and the location of the subsequent CO oxidation zone plays a very important role in determining the particle temperature. Ayling and Smith performed experimental and modeling work which indicates that CO oxidation is not of major importance under the conditions they investigated, although they noted the need for improved accuracy in measuring char reactivities, as well as for better modeling of the gas phase CO oxidation kinetics. The modeling work presented in this paper attempts to develop an improved understanding of the boundary layer oxidation of CO through the use of a comprehensive set of kinetic expressions.

Haussmann, G.; Kruger, C.

1986-04-01T23:59:59.000Z

297

Pulsed laser kinetic studies of liquids under high pressure  

SciTech Connect (OSTI)

A high pressure apparatus constructed for measuring the rates of reactions in liquids under pressures ranging from 1 atm to 2000 atm has been used to measure the complexation kinetics of molybdenum hexacarbonyl reacting with 2,2-bipyridine, 4,4{prime}-dimethyl-2-2{prime}-bipyridine and 4,4{prime}-diphenyl-2-2{prime} bipyridine in toluene. Pentacarbonyl reaction intermediates are created by a 10 nsec flash of frequency tripled Nd:YAG laser light. Measured activation volumes for chelate ligand ring closure indicate a change in mechanism from associative interchange to dissociative interchange as steric hindrance increases. A similar high pressure kinetics study of molybdenum carbonyl complexation by several substituted phenanthrolines is now well advanced that indicates that with the more rigid phenanthroline ligands steric effects from bulky substituents have less effect on the ring closure mechanism than in the case of the bipyridine ligands. An experimental concentration dependence of the fluorescence quantum yield of cresyl violet has been harmonized with previously published contradictory reports. Fluorescence of cresyl violet in various solvents and in micellar systems has also been systematically explored.

Eyring, E.M.

1991-11-25T23:59:59.000Z

298

Kinetic Alfvn solitary and rogue waves in superthermal plasmas  

SciTech Connect (OSTI)

We investigate the small but finite amplitude solitary Kinetic Alfvn waves (KAWs) in low ? plasmas with superthermal electrons modeled by a kappa-type distribution. A nonlinear Korteweg-de Vries (KdV) equation describing the evolution of KAWs is derived by using the standard reductive perturbation method. Examining the dependence of the nonlinear and dispersion coefficients of the KdV equation on the superthermal parameter ?, plasma ?, and obliqueness of propagation, we show that these parameters may change substantially the shape and size of solitary KAW pulses. Only sub-Alfvnic, compressive solitons are supported. We then extend the study to examine kinetic Alfvn rogue waves by deriving a nonlinear Schrdinger equation from the KdV equation. Rational solutions that form rogue wave envelopes are obtained. We examine how the behavior of rogue waves depends on the plasma parameters in question, finding that the rogue envelopes are lowered with increasing electron superthermality whereas the opposite is true when the plasma ? increases. The findings of this study may find applications to low ? plasmas in astrophysical environments where particles are superthermally distributed.

Bains, A. S.; Li, Bo, E-mail: bbl@sdu.edu.cn; Xia, Li-Dong [Shandong Provincial Key Laboratory of Optical Astronomy and Solar-Terrestrial Environment, School of Space Science and Physics, Shandong University at Weihai, 264209 Weihai (China)] [Shandong Provincial Key Laboratory of Optical Astronomy and Solar-Terrestrial Environment, School of Space Science and Physics, Shandong University at Weihai, 264209 Weihai (China)

2014-03-15T23:59:59.000Z

299

Kinetics of Elementary Processes Relevant to Incipient Soot Formation  

SciTech Connect (OSTI)

Soot formation and abatement processes are some of the most important and challenging problems in hydrocarbon combustion. The key reactions involved in the formation of polycyclic aromatic hydrocarbons (PAHâ??s), the precursors to soot, remain elusive. Small aromatic species such as C5H5, C6H6 and their derivatives are believed to play a pivotal role in incipient soot formation. The goal of this project is to establish a kinetic database for elementary reactions relevant to soot formation in its incipient stages. In the past year, we have completed by CRDS the kinetics for the formation and decomposition of C6H5C2H2O2 in the C6H5C2H2 +O2 reaction and the formation of C10H7O2 in the C10H7 + O2 reaction by directly monitoring C6H5C2H2O2 and C10H7O2 radicals in the visible region; their mechanisms have been elucidated computationally by quantum-chemical calculations. The O + C2H5OH reaction has been studied experimentally and computationally and the OH + HNCN reaction has been investigated by ab initio molecular orbital calculation. In addition, a new pulsed slit molecular beam system has been constructed and tested for spectroscopic studies of aromatic radicals and their derivatives by the cavity ringdown technique (CRDS).

M. C. Lin; M. C. Heaven

2008-04-30T23:59:59.000Z

300

Alterations in glucose kinetics induced by pentobarbital anesthesia  

SciTech Connect (OSTI)

Because pentobarbital is often used in investigations related to carbohydrate metabolism, the in vivo effect of this drug on glucose homeostasis was studied. Glucose kinetics assessed by the constant intravenous infusion of (6-{sup 3}H)- and (U-{sup 14}C)glucose, were determined in three groups of catheterized fasted rats: conscious, anesthetized and body temperature maintained, and anesthetized but body temperature not maintained. After induction of anesthesia, marked hypothermia developed in rats not provided with external heat. Anesthetized rats that developed hypothermia showed a decrease in mean arterial blood pressure (25%) and heart rate (40%). Likewise, the plasma lactate concentration and the rates of glucose appearance, recycling, and metabolic clearance were reduced by 30-50% in the hypothermic anesthetized rats. Changes in whole-body carbohydrate metabolism were prevented when body temperature was maintained. Because plasma pentobarbital levels were similar between the euthermic and hypothermic rats during the first 2 h of the experiment, the rapid reduction in glucose metabolism in this latter group appears related to the decrease in body temperature. The continuous infusion of epinephrine produced alterations in glucose kinetics that were not different between conscious animals and anesthetized rats with body temperature maintained. Thus pentobarbital-anesthetized rats became hypothermic when kept at room temperature and exhibited marked decreases in glucose metabolism. Such changes were absent when body temperature was maintained during anesthesia.

Lang, C.H.; Bagby, G.J.; Hargrove, D.M.; Hyde, P.M.; Spitzer, J.J. (Louisiana State Univ. Medical Center, New Orleans (USA))

1987-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "kinetic en ergy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Kinetic theory and numerical simulations of two-species coagulation  

E-Print Network [OSTI]

In this work we study the stochastic process of two-species coagulation. This process consists in the aggregation dynamics taking place in a ring. Particles and clusters of particles are set in this ring and they can move either clockwise or counterclockwise. They have a probability to aggregate forming larger clusters when they collide with another particle or cluster. We study the stochastic process both analytically and numerically. Analytically, we derive a kinetic theory which approximately describes the process dynamics. One of our strongest assumptions in this respect is the so called well-stirred limit, that allows neglecting the appearance of spatial coordinates in the theory, so this becomes effectively reduced to a zeroth dimensional model. We determine the long time behavior of such a model, making emphasis in one special case in which it displays self-similar solutions. In particular these calculations answer the question of how the system gets ordered, with all particles and clusters moving in the same direction, in the long time. We compare our analytical results with direct numerical simulations of the stochastic process and both corroborate its predictions and check its limitations. In particular, we numerically confirm the ordering dynamics predicted by the kinetic theory and explore properties of the realizations of the stochastic process which are not accessible to our theoretical approach.

Carlos Escudero; Fabricio Macia; Raul Toral; Juan J. L. Velazquez

2014-04-19T23:59:59.000Z

302

Nederland en Suriname: Een gemeenschappelijk verleden, heden en toekomst.  

E-Print Network [OSTI]

??1975 werd het jaar dat Suriname onafhankelijk werd van de kolonisator. Nederland liet haar kolonie in Zuid- Amerika gaan en wilde het op eigen benen (more)

Sewgobind, A.B.

2011-01-01T23:59:59.000Z

303

modelado en geofisica aplicado al transporte de nitrato en aguas ...  

E-Print Network [OSTI]

En los ltimos aos, diversas investigaciones han conducido al estudio del comportamiento del nitrato y su potencial impacto ambiental (Mehran et al., 1984

304

...ests en la unam ests en tu casa...  

E-Print Network [OSTI]

, aplicación de pintura antigraffiti en 64 mil metros cuadrados, sustitución de siete mil 250 luminarias y de

Islas, León

305

en partenariat Des partenariats  

E-Print Network [OSTI]

attribuées 5 jeunes équipes du Sud soutenues Au Maroc, accord intergouvernemental et accord- cadre avec l mathématique et informatique des systèmes complexes, implantée principalement au Maroc et en France. 1er et mathématiques appliquées, au Maroc. Congrès international de génétique, de biologie moléculaire et

306

Kinetics simulation for natural gas conversion to unsaturated C? hydrocarbons  

E-Print Network [OSTI]

value. The usual chemical composition range of natural gas is shown in Table I. l. Table 1. 1 Natural Gas Composition Component Methane Ethane Pro ane iso-Butane normal-Butane iso-Pentane normal-Pentane Hexane s lus Nitro en Carbon Dioxide... Acetylene Carbon Ethylene Hydrogen Methane Water Carbon Dioxide CHAPTER I INTRODUCTION Challenge for Natural Gas Natural Gas (NG), which is comprised priinarily of methane, is found throughout the world, burns cleanly, and processes a high caloric...

Yang, Li

2003-01-01T23:59:59.000Z

307

Kinetic Modeling of Toluene Oxidation for Surrogate Fuel Applications  

SciTech Connect (OSTI)

New environmental issues, like the effect of combustion-generated greenhouse gases, provide motivation to better characterize oxidation of hydrocarbons. Transportation, in particular, significantly contributes to energy consumption and CO{sub 2} emissions. Kinetic studies about the combustion of fuels under conditions typical of internal combustion engines provides important support to improve mechanism formulation and to eventually provide better computational tools that can be used to increase the engine performance. It is foreseeable that at least in the next 30 years the main transportation fuels will be either gasoline or diesel. Unfortunately, these fuels are very complex mixtures of many components. Moreover, their specifications and performance requirements significantly change the composition of these fuels: gasoline and diesel mixtures are different if coming from different refineries or they are different from winter to summer. At the same time a fuel with a well defined and reproducible composition is needed for both experimental and modeling work. In response to these issues, surrogate fuels are proposed. Surrogate fuels are defined as mixtures of a small number of hydrocarbons whose relative concentrations is adjusted in order to approximate the chemical and physical properties of a real fuel. Surrogate fuels are then very useful both for the design of reproducible experimental tests and also for the development of reliable kinetic models. The primary reference fuels (PRF) are a typical and old example of surrogate fuel: n-heptane and iso-octane mixtures are used to reproduce antiknock propensity of complex mixtures contained in a gasoline. PRFs are not able to surrogate gasoline in operating conditions different from standard ones and new surrogates have been recently proposed. Toluene is included in all of them as a species able to represent the behavior of aromatic compounds. On the other side, the toluene oxidation chemistry is not so well established and uncertainties still remain in the mechanism. This is especially true in the low temperature regime (< 850K). In these conditions, the toluene reactivity is too low to be conveniently investigated. Nonetheless, gasoline surrogates work in the engine at low temperatures, because of the presence of very reactive alkanes. The effect of these component interactions have to be taken into account. This work's aim is to present the model activity carried out by two different research groups, comparing the main pathways and results, matching data carried out in different devices both for pure toluene and mixtures. This is the starting point for a further activity to improve the two kinetic schemes.

Frassoldati, A; Mehl, M; Fietzek, R; Faravelli, T; Pitz, W J; Ranzi, E

2009-04-21T23:59:59.000Z

308

ESPECIALIZACIN EN GESTIN AMBIENTAL Objetivo del programa  

E-Print Network [OSTI]

impacto ambiental del desarrollo 3 Política y legislación ambiental 3 Planificación y gestión ambientalESPECIALIZACI?N EN GESTI?N AMBIENTAL Objetivo del programa La Especialización en Gestión Ambiental identificar, en un mundo cambiante, en lo social, en lo económico y en lo ambiental, las medidas de prevención

Vásquez, Carlos

309

Peltier A., 2008, La cartographie rglementaire des risques naturels en Suisse, en Italie et en France , La mise en carte des risques naturels, Diversit des approches, Montpellier : Presses Universitaires de la Mditerrane,  

E-Print Network [OSTI]

Peltier A., 2008, La cartographie rglementaire des risques naturels en Suisse, en Italie et en (2008) 61-67" #12;Peltier A., 2008, La cartographie rglementaire des risques naturels en Suisse, en

Paris-Sud XI, Universit de

310

Traduire Shmlu, pote iranien en franais.  

E-Print Network [OSTI]

??La littrature persane est surtout connue en Occident par les excellentes traductions en franais d'illustres potes classiques comme Omar Khayyam, Roumi, Hafz. Genre majeur de (more)

Hempartian, Azita

2013-01-01T23:59:59.000Z

311

Campusontwikkeling Over nut en noodzaak, en over lessen uit Amerika  

E-Print Network [OSTI]

Campusontwikkeling in Utrecht Over nut en noodzaak, en over lessen uit Amerika Oedzge Atzema #12; Colofon Deze uitgave werd mogelijk door bijdragen van: Gemeente Utrecht Hogeschool Utrecht SSH Utrecht UMC Utrecht Universiteit Utrecht Tekst: Oedzge Atzema Foto's: Ruut van Rossen e.a. Eindredactie: Marianne

Atzema, Oedzge

312

Q-branch Raman scattering and modern kinetic thoery  

SciTech Connect (OSTI)

The program is an extension of previous APL work whose general aim was to calculate line shapes of nearly resonant isolated line transitions with solutions of a popular quantum kinetic equation-the Waldmann-Snider equation-using well known advanced solution techniques developed for the classical Boltzmann equation. The advanced techniques explored have been a BGK type approximation, which is termed the Generalized Hess Method (GHM), and conversion of the collision operator to a block diagonal matrix of symmetric collision kernels which then can be approximated by discrete ordinate methods. The latter method, which is termed the Collision Kernel method (CC), is capable of the highest accuracy and has been used quite successfully for Q-branch Raman scattering. The GHM method, not quite as accurate, is applicable over a wider range of pressures and has proven quite useful.

Monchick, L. [The Johns Hopkins Univ., Laurel, MD (United States)

1993-12-01T23:59:59.000Z

313

Desorption and sublimation kinetics for fluorinated aluminum nitride surfaces  

SciTech Connect (OSTI)

The adsorption and desorption of halogen and other gaseous species from surfaces is a key fundamental process for both wet chemical and dry plasma etch and clean processes utilized in nanoelectronic fabrication processes. Therefore, to increase the fundamental understanding of these processes with regard to aluminum nitride (AlN) surfaces, temperature programmed desorption (TPD) and x-ray photoelectron spectroscopy (XPS) have been utilized to investigate the desorption kinetics of water (H{sub 2}O), fluorine (F{sub 2}), hydrogen (H{sub 2}), hydrogen fluoride (HF), and other related species from aluminum nitride thin film surfaces treated with an aqueous solution of buffered hydrogen fluoride (BHF) diluted in methanol (CH{sub 3}OH). Pre-TPD XPS measurements of the CH{sub 3}OH:BHF treated AlN surfaces showed the presence of a variety of Al-F, N-F, Al-O, Al-OH, C-H, and C-O surfaces species in addition to Al-N bonding from the AlN thin film. The primary species observed desorbing from these same surfaces during TPD measurements included H{sub 2}, H{sub 2}O, HF, F{sub 2}, and CH{sub 3}OH with some evidence for nitrogen (N{sub 2}) and ammonia (NH{sub 3}) desorption as well. For H{sub 2}O, two desorption peaks with second order kinetics were observed at 195 and 460?C with activation energies (E{sub d}) of 51??3 and 87??5?kJ/mol, respectively. Desorption of HF similarly exhibited second order kinetics with a peak temperature of 475?C and E{sub d} of 110??5?kJ/mol. The TPD spectra for F{sub 2} exhibited two peaks at 485 and 585?C with second order kinetics and E{sub d} of 62??3 and 270??10?kJ/mol, respectively. These values are in excellent agreement with previous E{sub d} measurements for desorption of H{sub 2}O from SiO{sub 2} and AlF{sub x} from AlN surfaces, respectively. The F{sub 2} desorption is therefore attributed to fragmentation of AlF{sub x} species in the mass spectrometer ionizer. H{sub 2} desorption exhibited an additional high temperature peak at 910?C with E{sub d}?=?370??10?kJ/mol that is consistent with both the dehydrogenation of surface AlOH species and H{sub 2} assisted sublimation of AlN. Similarly, N{sub 2} exhibited a similar higher temperature desorption peak with E{sub d}?=?535??40?kJ/mol that is consistent with the activation energy for direct sublimation of AlN.

King, Sean W., E-mail: sean.king@intel.com; Davis, Robert F. [Department of Materials Science and Engineering, North Carolina State University, Raleigh, North Carolina 27695 (United States); Nemanich, Robert J. [Department of Physics, North Carolina State University, Raleigh, North Carolina 27695 (United States)

2014-09-01T23:59:59.000Z

314

Kinetics of the heterogeneous photocatalytic oxidation of isopropanol  

SciTech Connect (OSTI)

Intrinsic kinetics for the ambient temperature photocatalytic oxidation (PCO) of dilute isopropanol (IPA) in humid air over near-ultraviolet (UV) irradiated titanium dioxide have been determined using a continuous microreactor flow system. The IPA disappearance rate exhibits a Langmuir-Hinshelwood-Hougen-Watson (LHHW) type dependence on IPA concentration. The rate is nearly first order in UV irradiance at low UV flux. The rate is independent of relative humidity R{sub H} at low R{sub H} levels, but is enhanced by water vapor concentration at higher levels. This relatively unique behavior is likely a direct consequence of the adsorption strength of alcohols on titania, which in general is considerably higher than the corresponding adsorption strengths for other classes of organic compounds. In addition to carbon dioxide, acetone is generated as a product of IPA destruction. This acetone is itself photocatalytically oxidized to carbon dioxide and water vapor at longer residence time. 10 refs., 3 figs.

Ameen, M.; Kalaga, M.; Annapragada, R.; Raupp, G.B. [Arizona State Univ., Tempe, AZ (United States)

1996-12-31T23:59:59.000Z

315

Chemical kinetic modeling of component mixtures relevant to gasoline  

SciTech Connect (OSTI)

Real fuels are complex mixtures of thousands of hydrocarbon compounds including linear and branched paraffins, naphthenes, olefins and aromatics. It is generally agreed that their behavior can be effectively reproduced by simpler fuel surrogates containing a limited number of components. In this work, a recently revised version of the kinetic model by the authors is used to analyze the combustion behavior of several components relevant to gasoline surrogate formulation. Particular attention is devoted to linear and branched saturated hydrocarbons (PRF mixtures), olefins (1-hexene) and aromatics (toluene). Model predictions for pure components, binary mixtures and multi-component gasoline surrogates are compared with recent experimental information collected in rapid compression machine, shock tube and jet stirred reactors covering a wide range of conditions pertinent to internal combustion engines. Simulation results are discussed focusing attention on the mixing effects of the fuel components.

Mehl, M; Curran, H J; Pitz, W J; Westbrook, C K

2009-02-13T23:59:59.000Z

316

Chemical Kinetic Models for HCCI and Diesel Combustion  

SciTech Connect (OSTI)

Hydrocarbon fuels for advanced combustion engines consist of complex mixtures of hundreds or even thousands of different components. These components can be grouped into a number of chemically distinct classes, consisting of n-paraffins, branched paraffins, cyclic paraffins, olefins, oxygenates, and aromatics. Biodiesel contains its own unique chemical class called methyl esters. The fractional amounts of these chemical classes are quite different in gasoline, diesel fuel, oil-sand derived fuels and bio-derived fuels, which contributes to the very different combustion characteristics of each of these types of combustion systems. The objectives of this project are: (1) Develop detailed chemical kinetic models for fuel components used in surrogate fuels for diesel and HCCI engines; (2) Develop surrogate fuel models to represent real fuels and model low temperature combustion strategies in HCCI and diesel engines that lead to low emissions and high efficiency; and (3) Characterize the role of fuel composition on low temperature combustion modes of advanced combustion engines.

Pitz, W J; Westbook, C K; Mehl, M

2008-10-30T23:59:59.000Z

317

Estimating The Thermodynamics And Kinetics Of Chlorinated Hydrocarbon Degradation  

SciTech Connect (OSTI)

Many different degradation reactions of chlorinated hydrocarbons are possible in natural ground waters. In order to identify which degradation reactions are important, a large number of possible reaction pathways must be sorted out. Recent advances in ab initio electronic structure methods have the potential to help identify relevant environmental degradation reactions by characterizing the thermodynamic properties of all relevant contaminant species and intermediates for which experimental data is usually not available, as well as provide activation energies for relevant pathways. In this paper, strategies based on ab initio electronic structure methods for estimating thermochemical and kinetic properties of reactions with chlorinated hydrocarbons are presented. Particular emphasis is placed on strategies that are computationally fast and can be used for large organochlorine compounds such as 4,4?-DDT.

Bylaska, Eric J.

2006-08-01T23:59:59.000Z

318

[Grain boundary and interface kinetics during ion irradiation  

SciTech Connect (OSTI)

Proposed here is renewed support of a research program focused on interface motion and phase transformation during ion irradiation, with emphasis on elemental semiconductors. Broadly speaking, the aims of this program are to explore defect kinetics in amorphous and crystalline semiconductors, and to relate defect dynamics to interface motion and phase transformations. Over the last three years, we initiated a program under DOE support to explore crystallization and amorphization of elemental semiconductors under irradiation. This research has enabled new insights about the nature of defects in amorphous semiconductors and about microstructural evolution in the early stages of crystallization. In addition, we have demonstrated almost arbitrary control over the relative rates of crystal nucleation and crystal growth in silicon. As a result, the impinged grain microstructure of thin (100 nm) polycrystalline films crystallized under irradiation can be controlled with grain sizes ranging from a few nanometers to several micrometers, which may have interesting technological implications.

Atwater, H.A.

1991-12-31T23:59:59.000Z

319

(Grain boundary and interface kinetics during ion irradiation)  

SciTech Connect (OSTI)

Proposed here is renewed support of a research program focused on interface motion and phase transformation during ion irradiation, with emphasis on elemental semiconductors. Broadly speaking, the aims of this program are to explore defect kinetics in amorphous and crystalline semiconductors, and to relate defect dynamics to interface motion and phase transformations. Over the last three years, we initiated a program under DOE support to explore crystallization and amorphization of elemental semiconductors under irradiation. This research has enabled new insights about the nature of defects in amorphous semiconductors and about microstructural evolution in the early stages of crystallization. In addition, we have demonstrated almost arbitrary control over the relative rates of crystal nucleation and crystal growth in silicon. As a result, the impinged grain microstructure of thin (100 nm) polycrystalline films crystallized under irradiation can be controlled with grain sizes ranging from a few nanometers to several micrometers, which may have interesting technological implications.

Atwater, H.A.

1991-01-01T23:59:59.000Z

320

Testing a dissipative kinetic k-essence model  

E-Print Network [OSTI]

In this work, we present a study of a purely kinetic k-essence model, characterized basically by a parameter $\\alpha$ in presence of a bulk dissipative term, whose relationship between viscous pressure $\\Pi$ and energy density $\\rho$ of the background follows a polytropic type law $\\Pi \\propto \\rho^{\\lambda+1/2}$, where $\\lambda$, in principle, is a parameter without restrictions. Analytical solutions for the energy density of the k-essence field are found in two specific cases: $\\lambda=1/2$ and $\\lambda=(1-\\alpha)/2\\alpha$, and then we show that these solutions posses the same functional form than the non-viscous counterpart. Finally, both approach are contrasted with observational data from type Ia supernova, and the most recent Hubble parameter measurements, and therefore, the best values for the parameters of the theory are founds.

Cardenas, V H; Villanueva, J R

2015-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "kinetic en ergy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Mass independent kinetic energy reducing inlet system for vacuum environment  

DOE Patents [OSTI]

A particle inlet system comprises a first chamber having a limiting orifice for an incoming gas stream and a micrometer controlled expansion slit. Lateral components of the momentum of the particles are substantially cancelled due to symmetry of the configuration once the laminar flow converges at the expansion slit. The particles and flow into a second chamber, which is maintained at a lower pressure than the first chamber, and then moves into a third chamber including multipole guides for electromagnetically confining the particle. The vertical momentum of the particles descending through the center of the third chamber is minimized as an upward stream of gases reduces the downward momentum of the particles. The translational kinetic energy of the particles is near-zero irrespective of the mass of the particles at an exit opening of the third chamber, which may be advantageously employed to provide enhanced mass resolution in mass spectrometry.

Reilly, Peter T.A.

2014-05-13T23:59:59.000Z

322

Pulsed laser kinetic studies of liquids under high pressure  

SciTech Connect (OSTI)

A laser flash photolysis kinetic study of 2,2{prime}-bipyridine bidentate chelating ligands with one claw in the first coordination sphere of a molybdenum carbonyl complex has been completed at pressures up to 150 MPa. The reaction mechanism for thermal ring closure is found from activation volumes to change from associative interchange to dissociative interchange as substituents on the 2,2{prime}-bipyridine ligands become bulkier. In a similar study of more rigid, substituted phenanthroline bidentate ligands it was found that substituent bulkiness had little effect on the thermal ring closure mechanism. Stability constants for lithium ion complexes with crown ethers in a room temperature molten salt, fluorescence quantum yields for cresyl violet and several other dyes in solution, and the oxidation of alcohols by OsO{sub 4} have also been investigated.

Eyring, E.M.

1992-09-22T23:59:59.000Z

323

Mass independent kinetic energy reducing inlet system for vacuum environment  

DOE Patents [OSTI]

A particle inlet system comprises a first chamber having a limiting orifice for an incoming gas stream and a micrometer controlled expansion slit. Lateral components of the momentum of the particles are substantially cancelled due to symmetry of the configuration once the laminar flow converges at the expansion slit. The particles and flow into a second chamber, which is maintained at a lower pressure than the first chamber, and then moves into a third chamber including multipole guides for electromagnetically confining the particle. The vertical momentum of the particles descending through the center of the third chamber is minimized as an upward stream of gases reduces the downward momentum of the particles. The translational kinetic energy of the particles is near-zero irrespective of the mass of the particles at an exit opening of the third chamber, which may be advantageously employed to provide enhanced mass resolution in mass spectrometry.

Reilly, Peter T. A. [Knoxville, TN

2010-12-14T23:59:59.000Z

324

Mass independent kinetic energy reducing inlet system for vacuum environment  

DOE Patents [OSTI]

A particle inlet system comprises a first chamber having a limiting orifice for an incoming gas stream and a micrometer controlled expansion slit. Lateral components of the momentum of the particles are substantially cancelled due to symmetry of the configuration once the laminar flow converges at the expansion slit. The particles and flow into a second chamber, which is maintained at a lower pressure than the first chamber, and then moves into a third chamber including multipole guides for electromagnetically confining the particle. The vertical momentum of the particles descending through the center of the third chamber is minimized as an upward stream of gases reduces the downward momentum of the particles. The translational kinetic energy of the particles is near-zero irrespective of the mass of the particles at an exit opening of the third chamber, which may be advantageously employed to provide enhanced mass resolution in mass spectrometry.

Reilly, Peter T.A.

2013-12-03T23:59:59.000Z

325

Utilization of rotor kinetic energy storage for hybrid vehicles  

DOE Patents [OSTI]

A power system for a motor vehicle having an internal combustion engine, the power system comprises an electric machine (12) further comprising a first excitation source (47), a permanent magnet rotor (28) and a magnetic coupling rotor (26) spaced from the permanent magnet rotor and at least one second excitation source (43), the magnetic coupling rotor (26) also including a flywheel having an inertial mass to store kinetic energy during an initial acceleration to an operating speed; and wherein the first excitation source is electrically connected to the second excitation source for power cycling such that the flywheel rotor (26) exerts torque on the permanent magnet rotor (28) to assist braking and acceleration of the permanent magnet rotor (28) and consequently, the vehicle. An axial gap machine and a radial gap machine are disclosed and methods of the invention are also disclosed.

Hsu, John S. (Oak Ridge, TN)

2011-05-03T23:59:59.000Z

326

On a Broken Formal Symmetry between Kinetic and Gravitational Energy  

E-Print Network [OSTI]

Historically, the discovery of symmetries has played an important role in the progress of our fundamental understanding of nature. This paper will demonstrate that there exists in Newtonian theory in a spherical gravitational field a formal symmetry between the kinetic (KE) and gravitational potential energy (GPE) of a test mass. Put differently, there exists a way of expressing GPE such that the form of the mathematical expression remains invariant under an interchange of KE and GPE. When extended to relativity by a suitable assumption, it leads to a framework that bridges the general relativistic and Newtonian conceptions of gravitational energy, even though the symmetry is broken except in the infinitesimal limit. Recognizing this symmetry at infinitesimal scales makes it possible to write a relativistic equation of an individual graviton, the properties of which under under one interpretation may be unexpected.

Armin Nikkhah Shirazi

2014-07-16T23:59:59.000Z

327

Kinetic and Fluid Ballooning Stability with Anisotropic Energetic Electron Layers  

SciTech Connect (OSTI)

A kinetic ballooning mode theory is developed from the gyrokinetic equation in the frequency range for which the ions are fluid, the thermal electron response is adiabatic and the hot electrons are non-interacting due to their large drift velocity. Trapped particle effects are ignored, The application of the quasineutrality condition together with the parallel and binomial components of Ampere's Law reduces the gyrokinetic equation to a second order ordinary differential equation along the equilibrium magnetic field lines. The instability dynamics are dominated by the pressure gradients of the thermal species in the fluid magnetohydrodynamic limit. The resulting equation combines features of both the Kruskal-Oberman energy principle and the rigid hot particle energy principle proposed by Johnson et al. to model the Astron device.

Cooper, W. A. [Ecole Polytechnique Federale de Lausanne, Centre de Recherches en Physique des Plasmas, Association Euratom-Confederation Suisse, CH-1015 Lausanne (Switzerland)

2006-11-30T23:59:59.000Z

328

Collective Modes of Chiral Kinetic Theory in Magnetic Field  

E-Print Network [OSTI]

We study collective excitations in systems described by chiral kinetic theory in external magnetic field. We consider high-temperature weak-coupling plasma, as well as high-density Landau Fermi liquid with interaction not restricted to be weak. We show that chiral magnetic wave (CMW) emerges in hydrodynamic regime (at frequencies smaller than collision relaxation rate) and the CMW velocity is determined by thermodynamic properties only. We find that in a plasma of opposite chiralities, at frequencies smaller than the chirality-flipping rate, the CMW excitation turns into a vector-like diffusion mode. In the interacting Fermi liquid, the CMW turns into the Landau zero sound mode in the high-frequency collisionless regime.

Mikhail Stephanov; Ho-Ung Yee; Yi Yin

2014-12-31T23:59:59.000Z

329

Collective Modes of Chiral Kinetic Theory in Magnetic Field  

E-Print Network [OSTI]

We study collective excitations in systems described by chiral kinetic theory in external magnetic field. We consider high-temperature weak-coupling plasma, as well as high-density Landau Fermi liquid with interaction not restricted to be weak. We show that chiral magnetic wave (CMW) emerges in hydrodynamic regime (at frequencies smaller than collision relaxation rate) and the CMW velocity is determined by thermodynamic properties only. We find that in a plasma of opposite chiralities, at frequencies smaller than the chirality-flipping rate, the CMW excitation turns into a vector-like diffusion mode. In the interacting Fermi liquid, the CMW turns into the Landau zero sound mode in the high-frequency collisionless regime.

Stephanov, Mikhail; Yin, Yi

2015-01-01T23:59:59.000Z

330

Synchronous parallel kinetic Monte Carlo Diffusion in Heterogeneous Systems  

SciTech Connect (OSTI)

A new hybrid Molecular Dynamics-kinetic Monte Carlo algorithm has been developed in order to study the basic mechanisms taking place in diffusion in concentrated alloys under the action of chemical and stress fields. Parallel implementation of the k-MC part based on a recently developed synchronous algorithm [1. Compo Phys. 227 (2008) 3804-3823] resorting on the introduction of a set of null events aiming at synchronizing the time for the different subdomains, added to the parallel efficiency of MD, provides the computer power required to evaluate jump rates 'on the flight', incorporating in this way the actual driving force emerging from chemical potential gradients, and the actual environment-dependent jump rates. The time gain has been analyzed and the parallel performance reported. The algorithm is tested on simple diffusion problems to verify its accuracy.

Martinez Saez, Enrique [Los Alamos National Laboratory; Hetherly, Jeffery [Los Alamos National Laboratory; Caro, Jose A [Los Alamos National Laboratory

2010-12-06T23:59:59.000Z

331

Atomistic Kinetic Monte Carlo Simulations of Polycrystalline Copper Electrodeposition  

E-Print Network [OSTI]

A high-fidelity kinetic Monte Carlo (KMC) simulation method (T. Treeratanaphitak, M. Pritzker, N. M. Abukhdeir, Electrochim. Acta 121 (2014) 407--414) using the semi-empirical multi-body embedded-atom method (EAM) potential has been extended to model polycrystalline metal electrodeposition. The presented KMC-EAM method enables true three-dimensional atomistic simulations of electrodeposition over experimentally relevant timescales. Simulations using KMC-EAM are performed over a range of overpotentials to predict the effect on deposit texture evolution. Results show strong agreement with past experimental results both with respect to deposition rates on various copper surfaces and roughness-time power law behaviour. It is found that roughness scales with time $\\propto t^\\beta$ where $\\beta=0.62 \\pm 0.12$, which is in good agreement with past experimental results. Furthermore, the simulations provide insights into sub-surface deposit morphologies which are not directly accessible from experimental measurements.

Treeratanaphitak, Tanyakarn; Abukhdeir, Nasser Mohieddin

2014-01-01T23:59:59.000Z

332

An Experimental and Kinetic Modeling Study of Methyl Decanoate Combustion  

SciTech Connect (OSTI)

Biodiesel is typically a mixture of long chain fatty acid methyl esters for use in compression ignition engines. Improving biofuel engine performance requires understanding its fundamental combustion properties and the pathways of combustion. This research study presents new combustion data for methyl decanoate in an opposed-flow diffusion flame. An improved detailed chemical kinetic model for methyl decanoate combustion is developed, which serves as the basis for deriving a skeletal mechanism via the direct relation graph method. The novel skeletal mechanism consists of 648 species and 2998 reactions. This mechanism well predicts the methyl decanoate opposed-flow diffusion flame data. The results from the flame simulations indicate that methyl decanoate is consumed via abstraction of hydrogen atoms to produce fuel radicals, which lead to the production of alkenes. The ester moiety in methyl decanoate leads to the formation of low molecular weight oxygenated compounds such as carbon monoxide, formaldehyde, and ketene.

Sarathy, S M; Thomson, M J; Pitz, W J; Lu, T

2010-02-19T23:59:59.000Z

333

Kinetically determined shapes of grain boundaries in CVD graphene  

E-Print Network [OSTI]

Predicting the shape of grain boundaries is essential to control results of the growth of large graphene crystals. A global energy minimum search predicting the most stable final structure contradicts experimental observations. Here we present Monte Carlo simulation of kinetic formation of grain boundaries (GB) in graphene during collision of two growing graphene flakes. Analysis of the resulting GBs for the full range of misorientation angles $\\alpha$ allowed us to identify a hidden (from post facto analysis such as microscopy) degree of freedom - the edge misorientation angle $\\beta$. Edge misorientation characterizes initial structure rather than final structure and therefore provides more information about growth conditions. Use of $\\beta$ enabled us to explain disagreements between the experimental observations and theoretical work. Finally, we report an analysis of an interesting special case of zero-tilt GBs for which structure is determined by two variables describing the relative shift of initial isl...

Bets, Ksenia V; Yakobson, Boris I

2014-01-01T23:59:59.000Z

334

Catalysis Letters Vol. 76, No. 12, 2001 35 Second order isothermal desorption kinetics  

E-Print Network [OSTI]

cycles of controlled heating and cooling of the sample, instead of the standard linear heat- ing rates, the kinetics of CO adsorption and desorption from Pd(110) [5], NH3/Re(0001) [6] monitored by optical second desorption that corresponds to second order de- sorption kinetics. Assuming high enough pumping speed

Asscher, Micha

335

Gas-Kinetic Scheme for Continuum and Near-Continuum Hypersonic Flows  

E-Print Network [OSTI]

Gas-Kinetic Scheme for Continuum and Near-Continuum Hypersonic Flows Wei Liao and Li-Shi Luo Old. The gas-kinetic schemes are validated with simulations of the hypersonic flow past a hollow flare at Mach and simulation of complex hypersonic flows become very challenging for computa- tional fluid dynamics (CFD) [1

Xu, Kun

336

Gas Kinetic Scheme for Continuum and Near-Continuum Hypersonic Flows  

E-Print Network [OSTI]

Gas Kinetic Scheme for Continuum and Near-Continuum Hypersonic Flows Wei Liao and Li-Shi Luo Old for the near-continuum flows. The gas-kinetic schemes are validated with simulations of the hypersonic flow thickness, modeling and simulation of complex hypersonic flows become very challenging for computational

Luo, Li-Shi

337

On the kinetic equation approach to pair production by time-dependent electric field  

E-Print Network [OSTI]

We investigate the quantum kinetic approach to pair production from vacuum by time-dependent electric field. Equivalence between this approach and the more familiar S-matrix approach is explicitly established for both scalar and fermion cases. For the particular case of a constant electric field exact solution for kinetic equations is provided and the accuracy of low-density approximation is estimated.

A. M. Fedotov; E. G. Gelfer; K. Yu. Korolev; S. A. Smolyansky

2010-08-12T23:59:59.000Z

338

Kinetic Part-Feeding Models for Assembly Lines in Automotive Industries  

E-Print Network [OSTI]

Kinetic Part-Feeding Models for Assembly Lines in Automotive Industries Michael Herty, Lena.ziegler@daimler.com. #12;KINETIC PART­FEEDING MODELS FOR ASSEMBLY LINES IN AUTOMOTIVE INDUSTRIES MICHAEL HERTY, LENA in automotive industries by models based on partial differential equations.The basic idea consists

Noelle, Sebastian

339

Zero electron kinetic energy spectroscopy of the ArCl anion Thomas Lenzer,a)  

E-Print Network [OSTI]

and the neutral complexes are observed in the ZEKE spectra. From our spectroscopic data we construct modelZero electron kinetic energy spectroscopy of the ArCl anion Thomas Lenzer,a) Ivan Yourshaw, Berkeley, California 94720 Received 19 January 1999; accepted 23 February 1999 Zero electron kinetic energy

Neumark, Daniel M.

340

Zero electron kinetic energy spectroscopy of the XeCl Thomas Lenzer,a)  

E-Print Network [OSTI]

measurements for the neutral state we construct a Morse­Morse-switching­van der Waals model potential functionZero electron kinetic energy spectroscopy of the XeCl? anion Thomas Lenzer,a) Ivan Yourshaw, Berkeley, California 94720 Received 9 November 2001; accepted 21 December 2001 Zero electron kinetic energy

Neumark, Daniel M.

Note: This page contains sample records for the topic "kinetic en ergy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

HYDRODYNAMIC LIMITS FOR KINETIC EQUATIONS AND THE DIFFUSIVE APPROXIMATION OF RADIATIVE  

E-Print Network [OSTI]

HYDRODYNAMIC LIMITS FOR KINETIC EQUATIONS AND THE DIFFUSIVE APPROXIMATION OF RADIATIVE TRANSPORT . The radiative transport equations, satisfied by the Wigner function for random acoustic waves, present#usive approximation of the radiative transport equation. 1. Introduction We consider a class of kinetic models

Tzavaras, Athanasios E.

342

HYDRODYNAMIC LIMITS FOR KINETIC EQUATIONS AND THE DIFFUSIVE APPROXIMATION OF RADIATIVE  

E-Print Network [OSTI]

HYDRODYNAMIC LIMITS FOR KINETIC EQUATIONS AND THE DIFFUSIVE APPROXIMATION OF RADIATIVE TRANSPORT of the radiative transport equation. 1. Introduction We consider a class of kinetic models equipped with a single. A general compactness frame- work is obtained for the diffusive scaling in L1 . The radiative transport

Tzavaras, Athanasios E.

343

RIS-M-2366 KINETICS OF THE REACTION OF HYDROXYL RADICALS WITH ETHANE AND  

E-Print Network [OSTI]

produced by pulse radiolysis of water vapour and the kinetics of OH was followed by kinetic spectroscopy studied at atmospheric pressure and over the temperature range 300-400 K. Hydroxyl radicals were produced by pulse radiolysis of water vapour and the decay rate was studied by monitoring the tran- sient light

344

Materials Science Forum, Vols. 426432, 2003, pp. 3542. Advances in the Kinetic Theory of Carbide Precipitation  

E-Print Network [OSTI]

Materials Science Forum, Vols. 426­432, 2003, pp. 35­42. Advances in the Kinetic Theory of Carbide Pembroke Street, Cambridge CB2 3QZ, U.K., www.msm.cam.ac.uk/phase­trans Keywords : Carbides, kinetics and reversion of carbides can determine the quality of steels. This paper is a review of efforts towards better

Cambridge, University of

345

Kinetic Theories of Geodesic Acoustic Modes: Radial Structure, Linear Excitation by Energetic Particles and Nonlinear Saturation  

E-Print Network [OSTI]

Kinetic Theories of Geodesic Acoustic Modes: Radial Structure, Linear Excitation by Energetic, Vol.13, No.3, Jun 2011 Kinetic Theories of Geodesic Acoustic Modes: Radial Structure, Linear, Univ. of California, Irvine CA 92697-4575, USA Abstract Geodesic acoustic modes (GAMs) are oscillating

Zonca, Fulvio

346

Kinetic effects of toluene blending on the extinction limit of n-decane diffusion flames  

E-Print Network [OSTI]

analyses of kinetic path ways and species transport on flame extinction were also conducted. The results and emission properties, such as the ignition delay times, extinction limits, flame speeds, species profilesKinetic effects of toluene blending on the extinction limit of n-decane diffusion flames Sang Hee

Ju, Yiguang

347

Kinetics of Initial Lithiation of Crystalline Silicon Electrodes of Lithium-Ion Batteries  

E-Print Network [OSTI]

Kinetics of Initial Lithiation of Crystalline Silicon Electrodes of Lithium-Ion Batteries Matt phase. KEYWORDS: Lithium-ion batteries, silicon, kinetics, plasticity Lithium-ion batteries already at the electrolyte/lithiated silicon interface, diffusion of lithium through the lithiated phase, and the chemical

348

Three distinct kinetic groupings of the synaptotagmin family: Candidate sensors for rapid and  

E-Print Network [OSTI]

Three distinct kinetic groupings of the synaptotagmin family: Candidate sensors for rapid, syt I, appears to function as a Ca2 sensor that triggers the rapid exocytosis of synaptic vesicles much slower disassembly kinetics than does syt I, might function as Ca2 sensors for asynchronous

Chapman, Edwin R.

349

Demonstrations: blocks on planes, scales, to find coefficients of static and kinetic friction  

E-Print Network [OSTI]

Demonstrations: ·blocks on planes, scales, to find coefficients of static and kinetic friction Text: Fishbane 5-1, 5-2 Problems: 18, 21, 28, 30, 34 from Ch. 5 What's important: ·frictional forces ·coefficients of static and kinetic friction Friction Where objects move in contact with other objects, we know

Boal, David

350

ON THE THERMODYNAMICS AND KINETICS OF THE COOPERATIVE BINDING OF BACTERIOPHAGE T4-  

E-Print Network [OSTI]

ON THE THERMODYNAMICS AND KINETICS OF THE COOPERATIVE BINDING OF BACTERIOPHAGE T4- CODED GENE 32 of thermodynamic, and preliminary kinetic, studies on the molecular details and specificity of interaction of phage into the molecular origins of binding cooperativity is obtained by determining these thermodynamic parameters also

Kowalczykowski, Stephen C.

351

Thermodynamics and kinetics of competing aggregation processes in a simple model system  

E-Print Network [OSTI]

Thermodynamics and kinetics of competing aggregation processes in a simple model system Ambarish 8 November 2007 A simple model system has been used to develop thermodynamics and kinetics for bulk and thermodynamics of the processes and to infer the conditions in which one process dominates another, in the high

Berry, R. Stephen

352

Intrinsic Primary and Secondary Hydrogen Kinetic Isotope Effects for Alanine Racemase from Global Analysis of  

E-Print Network [OSTI]

Intrinsic Primary and Secondary Hydrogen Kinetic Isotope Effects for Alanine Racemase from Global of the intrinsic primary kinetic isotope effects, the lower boundary on the energy of the quinonoid intermediate, making alanine racemase an attractive target for antibacterials. Global analysis of protiated

Toney, Michael

353

Power spectral analysis of Jupiter's clouds and kinetic energy from Cassini David S. Choi  

E-Print Network [OSTI]

of wind vectors and atmospheric kinetic energy within Jupiter's troposphere. We computed power spectraPower spectral analysis of Jupiter's clouds and kinetic energy from Cassini David S. Choi , Adam P o Article history: Received 16 December 2010 Revised 8 September 2011 Accepted 6 October 2011

354

Author's personal copy Power spectral analysis of Jupiter's clouds and kinetic energy from Cassini  

E-Print Network [OSTI]

full-longitudinal maps of wind vectors and atmospheric kinetic energy within Jupiter's troposphere. WeAuthor's personal copy Power spectral analysis of Jupiter's clouds and kinetic energy from Cassini 85721, USA a r t i c l e i n f o Article history: Received 16 December 2010 Revised 8 September 2011

Choi, David S.

355

A gas-kinetic scheme for reactive ows Yongsheng Lian, Kun Xu*  

E-Print Network [OSTI]

A gas-kinetic scheme for reactive ¯ows Yongsheng Lian, Kun Xu* Department of Mathematics, Hong Kong in revised form 22 July 1999; accepted 22 July 1999 Abstract In this paper, the gas-kinetic BGK scheme for the compressible ¯ow equations is extended to chemical reactive ¯ow. The mass fraction of the unburnt gas

Xu, Kun

356

Kinetic Modeling Of Solid-Gas Reactions At Reactor Scale: A General Approach Loc Favergeon1  

E-Print Network [OSTI]

the knowledge of the kinetic model for the calculation of the speed of reaction in one part of the reactorKinetic Modeling Of Solid-Gas Reactions At Reactor Scale: A General Approach Loïc Favergeon1 favergeon@emse.fr ABSTRACT A rigorous simulation of industrial reactors in the case of solid-gas reacting

Paris-Sud XI, Université de

357

Visualizing Chemical Compositions and Kinetics of Sol-Gel by Near-Infrared Multispectral Imaging  

E-Print Network [OSTI]

Visualizing Chemical Compositions and Kinetics of Sol-Gel by Near-Infrared Multispectral Imaging, Milwaukee, Wisconsin 53201 Kinetics of sol-gel formation were studied using the recently developed near-infrared been studied extensively by many different spectroscopic techniques.4-15 Among them, the near-infrared

Reid, Scott A.

358

EVAPORATION LAW IN KINETIC GRAVITATIONAL SYSTEMS DESCRIBED BY SIMPLIFIED LANDAU MODELS  

E-Print Network [OSTI]

EVAPORATION LAW IN KINETIC GRAVITATIONAL SYSTEMS DESCRIBED BY SIMPLIFIED LANDAU MODELS PIERRE to a mathematical and numerical study of a simplified kinetic model for evaporation phenomena in gravitational) is the gravitational potential and (u) is the following 3 ? 3 matrix (u)ij = |u|2ij - uiuj |u|2 , (1.2) 1 #12;2 P

Méhats, Florian

359

A multiple temperature kinetic model and its application to micro-scale gas flow simulations  

E-Print Network [OSTI]

A multiple temperature kinetic model and its application to micro-scale gas flow simulations model, micro-scale flows. 1. Introduction Gas flows can be classified according to the flow regimes_pku@yahoo.com.cn Abstract This paper presents a numerical approach to solve the multiple temperature kinetic model (MTKM

Xu, Kun

360

Application of Uncertainty and Sensitivity Analysis to a Kinetic Model for Enzymatic Biodiesel Production  

E-Print Network [OSTI]

Application of Uncertainty and Sensitivity Analysis to a Kinetic Model for Enzymatic Biodiesel benefits of using uncertainty and sensitivity analysis in the kinetics of enzymatic biodiesel production, Monte-Carlo Simulations, Enzymatic Biodiesel 1. INTRODUCTION In order to determine the optimal

Mosegaard, Klaus

Note: This page contains sample records for the topic "kinetic en ergy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Detailed chemical kinetic reaction mechanisms for soy and rapeseed biodiesel fuels  

E-Print Network [OSTI]

Detailed chemical kinetic reaction mechanisms for soy and rapeseed biodiesel fuels C.K. Westbrooka chemical kinetic reaction mechanism is developed for the five major components of soy biodiesel and rapeseed biodiesel fuels. These components, methyl stearate, methyl oleate, methyl linoleate, methyl

Paris-Sud XI, Université de

362

Major accidents scenarios used for LUP and off-site emergency planning : Importance of kinetic description  

E-Print Network [OSTI]

Major accidents scenarios used for LUP and off-site emergency planning : Importance of kinetic, INERIS shows a method enabling to integrate, as a second prioritisation criteria, the on-site and off-site. Keywords : Land Use Planning ; off-site emergency planning ; chemical accident scenario ; kinetic 1

Paris-Sud XI, Université de

363

Neutron kinetics in subcritical cores with application to the source modulation method  

E-Print Network [OSTI]

Neutron kinetics in subcritical cores with application to the source modulation method J. Wright for the measurement of reactivity in subcritical, source-driven cores. Methods of measuring reactivity by a single. Hence, first, the conditions of point kinetic behaviour in subcritical source-driven cores are revis

Pázsit, Imre

364

Development of a Rig and Testing Procedures for the Experimental Investigation of Horizontal Axis Kinetic Turbines  

E-Print Network [OSTI]

Kinetic Turbines by Catalina Lartiga B.Sc., Catholic University of Chile, 2001 A Thesis Submitted Turbines by Catalina Lartiga B.Sc., Catholic University of Chile, 2001 Supervisory Committee Dr. Curran system to characterize the non-dimensional performance coefficients of hor- izontal axis kinetic turbines

Victoria, University of

365

Kinetic Modeling of Cellulosic Biomass to Ethanol Via Simultaneous Saccharification and  

E-Print Network [OSTI]

ARTICLE Kinetic Modeling of Cellulosic Biomass to Ethanol Via Simultaneous Saccharification: cellulose; ethanol; kinetics; reactor design Introduction Plant biomass is the only foreseeable sustainable­803] for simultaneous saccharification of fermentation of cellulosic biomass is extended and modified to accommodate

California at Riverside, University of

366

Seasonal Modulation of Eddy Kinetic Energy and Its Formation Mechanism in the Southeast Indian Ocean  

E-Print Network [OSTI]

energy and exert profound impacts on large-scale ocean circulations. Satellite altimeter ob- servations- sociations with the large-scale oceanic circulations and the climate. The global eddy kinetic energy (EKESeasonal Modulation of Eddy Kinetic Energy and Its Formation Mechanism in the Southeast Indian

Qiu, Bo

367

Predicting Experimental Quantities in Protein Folding Kinetics using Stochastic Roadmap Simulation  

E-Print Network [OSTI]

Predicting Experimental Quantities in Protein Folding Kinetics using Stochastic Roadmap Simulation the transition state ensemble (TSE) and predict the rates and -values for protein folding. The new method as a gen- eral tool for studying protein folding kinetics. 1 Introduction Protein folding is a crucial

Pratt, Vaughan

368

This document will help you understand the statistics commonly used to describe wind when it is studied  

E-Print Network [OSTI]

Collaborative's Renewable En- ergy Trust Fund, the Renewable Energy Research Laboratory brings you this seriesThis document will help you understand the statistics commonly used to describe wind when Renewable Energy Research Laboratory, University of Massachusetts at Amherst Community Wind Power Fact Sheet

Massachusetts at Amherst, University of

369

Neighborhood Watch: Security and Privacy Analysis of Automatic Meter Reading Systems  

E-Print Network [OSTI]

Neighborhood Watch: Security and Privacy Analysis of Automatic Meter Reading Systems Ishtiaq Rouf gruteser@winlab.rutgers.edu ABSTRACT Research on smart meters has shown that fine-grained en- ergy usage data poses privacy risks since it allows inferences about activities inside the home. While smart meter

Xu, Wenyuan

370

BULLETIN OF SCIENCE, TECHNOLOGY & SOCIETY / De-cember 2001Byrne et al. / THE POSTMODERN GREENHOUSE The Postmodern Greenhouse  

E-Print Network [OSTI]

is developing the architecture of a policy response. Three serious flaws are examined: (a) the potential to secure the future of the world en- ergy regime. An alternative, based on principles of sustainability change, energy system, equity, sustainability, ecological justice Much has been made of the "new economy

Delaware, University of

371

Is Economic Volatility Detrimental to Global Sustainability?  

E-Print Network [OSTI]

, with the impacts exacerbated in some subsamples such as higher en- ergy intensity countries and lower trade share economy as a key factor influencing the low carbon development path. The finding is signifi- cant/huangyf.htm. 1 #12;1 Introduction In the 1990s the world economy grew at an averaged rate of 2.7 percent

Matthews, Adrian

372

Urban Computing: Concepts, Methodologies, and Applications YU ZHENG, Microsoft Research  

E-Print Network [OSTI]

people's lives but also engendered big challenges, such as air pollution, increased en- ergy consumption but also engendered big issues, such as traffic congestion, energy consumption, and pollution. Urban]: Database Applications--Data mining, Spatial databases and GIS; J.2 [Physical Sciences and Engineering

Wolfson, Ouri E.

373

Genome complexity in a lean, mean photosynthetic machine  

E-Print Network [OSTI]

, Dalhousie University, Sir Charles Tupper Medical Building, 5850 College Street, Halifax, NS, Canada B3H 1X5, invisible to the naked eye and unfathomably large in number, quietly harnessing solar en- ergy, fixing 1 m in diameter and practically invisible under the light microscope, O. tauri was detected by flow

Archibald, John

374

Abstract--An all-day tour to observe arid land reclamation on the Nevada Test Site was conducted in conjunction with the  

E-Print Network [OSTI]

participants were introduced to the U. S. Department of En- ergy reclamation programs for the Yucca Mountain of Energy must study and characterize Yucca Mountain, Nevada, as a potential site for long-term underground-disturbance conditions. The Reclamation Program of the Yucca Mountain Project Since limited information exists pertaining

375

Free Lunch: Exploiting Renewable Energy For Computing Sherif Akoush, Ripduman Sohan, Andrew Rice, Andrew W. Moore and Andy Hopper  

E-Print Network [OSTI]

Free Lunch: Exploiting Renewable Energy For Computing Sherif Akoush, Ripduman Sohan, Andrew Rice renewable en- ergy by (i) colocating datacentres with these remote energy sources, (ii) connecting them over that period. In anticipation of this growth, our industry is begin- ning to explore renewable energy

Cambridge, University of

376

A boot-strap PoissonBoltzmann theory for the structure and thermodynamics of charged colloidal solutions  

E-Print Network [OSTI]

A boot-strap Poisson­Boltzmann theory for the structure and thermodynamics of charged colloidal investigated by Monte Carlo simulation. A boot-strap Poisson­Boltzmann BSPB theory has been developed using a boot-strap Poisson­Boltzmann BSPB theory. Comparisons of the structure, internal en- ergy

Chan, Derek Y C

377

Nanograined half-Heusler semiconductors as advanced thermoelectrics: an ab-initio high-throughput statistical study  

E-Print Network [OSTI]

the thermoelectric effect to scavenge electric power from waste heat has long been an attractive route in the pursuit of sustainable en- ergy generation.1 Despite recent progress, the goal of producing efficient thermoelectricNanograined half-Heusler semiconductors as advanced thermoelectrics: an ab-initio high

Curtarolo, Stefano

378

EVIDENCE OF SMALL SCALE RECONNECTION IN A MOVING FEATURE Stephane Regnier1  

E-Print Network [OSTI]

Solar flares are often related to photospheric motions of magnetic polarities such as moving magnetic and the release of magnetic en- ergy in the solar corona and especially in active regions, we need to find what are the precursors of eruptive events and how the magnetic energy can be stored and/or re- leased even at small scale

Régnier, Stéphane

379

LETTER Earth Planets Space, 61, 577580, 2009 Flares and the chromosphere  

E-Print Network [OSTI]

LETTER Earth Planets Space, 61, 577­580, 2009 Flares and the chromosphere Hugh S. Hudson1 limited to the "semi-empirical" models, based on 1D radiative-transfer physics. Such an approach omits dy energetics (Section 2), en- ergy build-up (Section 3), and energy release (Section 4), attempting to use

Hudson, Hugh

380

arXiv:0706.3330v2[physics.flu-dyn]20Feb2008 Coherent structures in localised and global pipe turbulence  

E-Print Network [OSTI]

arXiv:0706.3330v2[physics.flu-dyn]20Feb2008 Coherent structures in localised and global pipe Walk, Bristol BS8 1TW, United Kingdom The recent discovery of unstable travelling waves (TWs) in pipe in both structure and en- ergy with known TWs using numerical simulations in a long pipe. These only occur

Willis, Ashley

Note: This page contains sample records for the topic "kinetic en ergy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

A Hardware Acceleration Unit for MPI Queue Processing Keith D. Underwood, K. Scott Hemmert, Arun Rodrigues, Richard Murphy, and Ron Brightwell  

E-Print Network [OSTI]

interface. With this important capability has come significant performance im- plications. Most notably- ing of moderate length queues in MPI. Simulations are used to compare the performance of an embedded, for the United States Department of En- ergy's National Nuclear Security Administration under contract DE- AC04

Brightwell, Ron

382

Energy Balance in Wireless Networks Using Connection Segmentation and Range Control  

E-Print Network [OSTI]

Energy Balance in Wireless Networks Using Connection Segmentation and Range Control Nitin Kumar are optimized to balance energy consumption across the network. This paper formulates an en­ ergy balance­ nalized for their important role in network operation. While route selection to balance energy [13], [31

Simha, Rahul

383

GEOPHYSICAL RESEARCH LETTERS, VOL. 27, NO. 1, PAGES 4l-44, JANUARY 1,200O Atmospheric gravity wave signatures in the infrared  

E-Print Network [OSTI]

extended to calculations of the vertical flux of wave en- ergy and the horizontal momentumcarried. A disadvantage of imagers operating in the l-2 pm region is the necessity of cooling the detector in order variations in OH airglow im- ages in the 1.4-1.5 pm infrared region. 2. Instrumentation and data analysis

California at Berkeley, University of

384

Low-Power Division: Comparison among implementations of radix 4, 8 and 16  

E-Print Network [OSTI]

produces the smallest en- ergy dissipation. 1 Introduction Energy consumption is becoming more important dissipated in a floating-point unit, similar to the one pre- sented in [8] shows that the energy consumption using PET [4], a power evaluation tool which com- putes the power dissipated in a circuit from

California at Davis, University of

385

EnergyBox: A Trace-driven Tool for Data Transmission Energy Consumption Studies  

E-Print Network [OSTI]

EnergyBox: A Trace-driven Tool for Data Transmission Energy Consumption Studies Ekhiotz Jon Vergara-awareness and propose EnergyBox, a tool that provides accurate and repeatable en- ergy consumption studies for 3G and WiFi transmissions at the user end. We recognize that the energy consumption of data transmission is highly

386

248 IEEE TRANSACTIONS ON POWER DELIVERY, VOL. 20, NO. 1, JANUARY 2005 Micro-Grid Autonomous Operation During  

E-Print Network [OSTI]

, low-head hydro units and geothermal systems and ii) battery storage, capacitor storage, low- and high regulation. I. INTRODUCTION DISTRIBUTED generation (DG) units, distributed storage (DS) units and integrated distributed generation/storage units constitute the broader family of distributed en- ergy resources (DR

Lehn, Peter W.

387

The Case for Efficient Renewable Energy Management in Smart Binghamton University  

E-Print Network [OSTI]

they produce back to the utility company--to offset their cost relative to grid energy. DG is a much lessThe Case for Efficient Renewable Energy Management in Smart Homes Ting Zhu Binghamton University (DG) uses many small on-site en- ergy sources deployed at individual buildings to generate electricity

Shenoy, Prashant

388

Identifying Energy Waste through Dense Power Sensing and Utilization Monitoring  

E-Print Network [OSTI]

Identifying Energy Waste through Dense Power Sensing and Utilization Monitoring Maria Kazandjieva the efficiency of such a computing system requires detailed data of both en- ergy consumption and energy waste to differentiate energy used well from energy waste. This is an important difference from pre- vious work [8, 14

Stanford University

389

Ris Energy Report 5 Summary, conclusions and recommendations 5 2 Summary, conclusions and recommendations  

E-Print Network [OSTI]

alleviation: in 2002, almost 1.6 billion people in developing countries did not have access to electricity in their homes. The International Energy Agency (IEA) predicts that by 2030, if governments stick, Chinese en- ergy consumption is increasing dramatically. Renewable energy resources already have

390

A File Allocation Strategy for Energy-Efficient Disk Storage Systems  

E-Print Network [OSTI]

capacity disks are deployed with increasing en- ergy costs and also as data intensive applications demand, that are accessed by collab- orating scientists around the world. Not only is long term retention of vital information essential, but meeting I/O response time requirements both in reading and writing long running

Geddes, Cameron Guy Robinson

391

Applied Catalysis B: Environmental 29 (2001) 327336 Gas-phase photo-oxidation of toluene using  

E-Print Network [OSTI]

for the excellent performance of 6 nm TiO2 catalyst for toluene photo-degradation. The structural differences for the degradation of volatile or- ganic pollutants (VOCs) [1­3]. It allows the oxidation of airborne VOCs) and UV or near-UV light source. When the catalyst absorbs photons having greater en- ergy than the band

392

Enhanced Specific Heat of Silica Donghyun Shin  

E-Print Network [OSTI]

, molten salt, lithium carbonate, potassium carbonate, solar energy, thermal en- ergy storage, phase change the operational efficiencies and reliability of solar thermal energy conversion systems. The materials material 1 Introduction Thermal energy storage TES systems at high temperatures are required to improve

Banerjee, Debjyoti

393

184 IEEE TRANSACTIONS ON ENERGY CONVERSION, VOL. 26, NO. 1, MARCH 2011 PEM Fuel Cell Stack Modeling for Real-Time  

E-Print Network [OSTI]

184 IEEE TRANSACTIONS ON ENERGY CONVERSION, VOL. 26, NO. 1, MARCH 2011 PEM Fuel Cell Stack Modeling membrane (PEM) fuel cell stack itself cannot be used directly as an en- ergy supply and require stack. In addition, fuel cell test costs (hydrogen consumption and the need of safety installations) are still

Simões, Marcelo Godoy

394

This article has been accepted for inclusion in a future issue of this journal. Content is final as presented, with the exception of pagination. IEEE TRANSACTIONS ON POWER SYSTEMS 1  

E-Print Network [OSTI]

) balancing market and the upcoming ERCOT "nodal"--that is, "locational marginal pricing," (LMP) market as in the Northeast U.S. restructured markets [2], competitive en- ergy prices must occasionally rise above the occasions of high competitive prices are also times when market participants have market power

Baldick, Ross

395

Border flow rights and Contracts for differences of differences  

E-Print Network [OSTI]

model, the owner of a transmission line or lines is paid at the locational marginal price for energy that it delivers to the rest of the system and pays at the locational marginal price for en- ergy that it receives" (CFDs) that are used to hedge locational marginal price variation at a given location [9, section 3

396

Energy Characterization of Hardware-Based Data Prefetching , Saurabh Chheda2  

E-Print Network [OSTI]

hardware-based data prefetching techniques from an energy perspective, and explores their en- ergy and potential energy-related issues of data prefetching mechanisms and to motivate new development of energy perspective, and explores their energy/performance tradeoffs. The prefetching techniques studied include

Massachusetts at Amherst, University of

397

Energy Efficiency Analysis of Link Layer Backoff Schemes on Point-to-Point  

E-Print Network [OSTI]

416 Energy Efficiency Analysis of Link Layer Backoff Schemes on Point-to-Point Markov Fading Links schemes are shown to achieve better energy ef- ficiency without compromising much on the link layer throughput performance. Keywords - Backoff algorithms, fading channels, en- ergy eficiency. 1 Introduction

Chockalingam, A.

398

ENERGY STRATEGY: THE ROAD NOT TAKEN?  

E-Print Network [OSTI]

ENERGY STRATEGY: THE ROAD NOT TAKEN? By Amory B. Lovins Two road5 diverged in a wood, and I-- I are America's formal or de facto energy policies leading us? Where might we choose to go instead? How can we concepts in energy strategy by outlining and contrasting two en- ergy paths tbat the United States might

Kammen, Daniel M.

399

33RD INTERNATIONAL COSMIC RAY CONFERENCE, RIO DE JANEIRO 2013 THE ASTROPARTICLE PHYSICS CONFERENCE  

E-Print Network [OSTI]

a good estimation of the energy of the primary cos- mic ray particle. The electromagnetic energy is proportional to the energy dissipated. Whereas the global process of energy deposit by charged particles a sizeable frac- tion of the primary electron energy may deposit their en- ergy at far distances from

Boyer, Edmond

400

IMAGING OF PORT WINE STAIN LESIONS USING A MULTI-SENSOR PHOTOACOUSTIC PROBE  

E-Print Network [OSTI]

oscilloscope 1000 µm optical fiber Human skin Figure 1. THE PHOTOACOUSTIC APPARATUS USED FOR MEA- SUREMENT-cools the epidermis to protect it from subsequent laser irradiation which raises the tempera- ture of both en- ergy, nanosecond pulses of laser light to induce acoustic waves in optically absorbing media

Aguilar, Guillermo

Note: This page contains sample records for the topic "kinetic en ergy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Variable Radii Connected Sensor Cover in Sensor Networks Zongheng Zhou, Samir Das, Himanshu Gupta  

E-Print Network [OSTI]

minimizing energy usage in the network. En- ergy is spent due to message transmissions by the radio interface a connected communication graph, so that they can autonomously respond to application queries and/or tasks is fixed. In this article, we address the problem of selecting a minimum energy-cost connected sensor cover

Gupta, Himanshu

402

Mechanical Engineering Turning Ideas into Reality  

E-Print Network [OSTI]

Mechanical Engineering Turning Ideas into Reality EnErgy Environ m Ent HEaltH matEria ls transpo rt u r s e s ? Home The Department Overview The Courses Mechanical Engineering (MEng / BEng) Mechanical Engineering With International Study (MEng / BEng) Aero-Mechanical Engineering (MEng / BEng) #12;tHE DEpartm

Mottram, Nigel

403

Plasma Imaging and Spectroscopy Diagnostics Developed on 100500-kA Pulsed Power Devices  

E-Print Network [OSTI]

Plasma Imaging and Spectroscopy Diagnostics Developed on 100500-kA Pulsed Power Devices DANIEL B-ray and ultraviolet en- ergy ranges developed and used on 100500 kA pulsed power facil- ities. Requiring just a few people to run and modest infrastructure investment, these facilities are cost-effective test beds for new

404

OPTIMAL CONTROL EXPERIMENTATION OF COMPRESSION TRAJECTORIES FOR A LIQUID PISTON AIR COMPRESSOR  

E-Print Network [OSTI]

compressor is the critical part of a Compressed Air En- ergy Storage (CAES) system. Efficient and fast and expansion has many applications in pneumatic and hydraulic systems, including in the Compressed Air Energy CAES system, high pressure (20-30MPa) compressed air is stored in a dual chamber storage vessel

Li, Perry Y.

405

Advances in Flash Memory SSD Technology for Enterprise Database Applications  

E-Print Network [OSTI]

in the storage market. Despite its superiority in access latency and energy consumption, the full-blown adoption Electronics Co., Ltd. San #16 Banwol-Ri Hwasung-City 445-701, Korea ci.park@samsung.com ABSTRACT The past few to transaction throughput, cost effectiveness and en- ergy consumption. Categories and Subject Descriptors H

Moon, Bongki

406

Mechanical & Aerospace Engineering Turning Ideas into Reality  

E-Print Network [OSTI]

Mechanical & Aerospace Engineering Turning Ideas into Reality EnErgy Environ m Ent HEaltH mat Overview The Courses Mechanical Engineering (MEng / BEng) Mechanical Engineering With International Study (MEng / BEng) Aero-Mechanical Engineering (MEng / BEng) E N T r y F A Q S A p p l y i n g C a m p u

Mottram, Nigel

407

Heavy residue production in the interaction of 29 MeV/nucleon 208 Pb with 197  

E-Print Network [OSTI]

University of Technology, Goteborg, Sweden 3 Studsvik Neutron Research Laboratory, S-611 82 Nyko mechanisms such as complete/ incomplete fusion, deep inelastic scattering, etc. or high en- ergy mechanisms be understood in terms of nucleon exchange models 19 used to describe low energy deep inelastic scattering 2

Menge, Duncan

408

Charge Migration Efficiency Optimization in Hybrid Electrical Energy Storage (HEES) Systems  

E-Print Network [OSTI]

Charge Migration Efficiency Optimization in Hybrid Electrical Energy Storage (HEES) Systems the excessive electric energy in the electrical energy storage (EES) rather than converting into a different) are typically not balanced with each other. Storage of excessive en- ergy and compensation of the energy

Pedram, Massoud

409

Supporting Energy-driven Adaptations in Distributed Environments  

E-Print Network [OSTI]

and Lionel Seinturier INRIA Lille ­ Nord Europe, Project-team ADAM University Lille 1 - LIFL CNRS UMR 8022. 2. MOTIVATION SCENARIO Watching streaming videos on a tablet PC Tom wishes to watch a movie on his and can be streamed over WiFi. When Tom starts playing the movie, the home en- ergy management system

Paris-Sud XI, Université de

410

Vacuum degeneracy of a circuit-QED system in the ultrastrong coupling regime Pierre Nataf1  

E-Print Network [OSTI]

N of artificial atoms, a degeneracy lifting occurs, with an en- ergy splitting dramatically of the proposed system is depicted in Fig. 1, namely a chain of N identical artificial two-level atomsVacuum degeneracy of a circuit-QED system in the ultrastrong coupling regime Pierre Nataf1

Paris-Sud XI, Université de

411

Recent Developments of the Modelica "Buildings" Library for Building Energy and Control Systems  

E-Print Network [OSTI]

Recent Developments of the Modelica "Buildings" Library for Building Energy and Control Systems 94720, USA Abstract At the Modelica 2009 conference, we introduced the Buildings library, a freely develop an open-source Modelica library for building en- ergy and control systems. The library is freely

412

Managing the Cost, Energy Consumption, and Carbon Footprint of Internet Services  

E-Print Network [OSTI]

or "green" energy. This paper introduces a general, optimization-based framework for enabling multi-data-center services to manage their brown en- ergy consumption and leverage green energy, while respecting their SLAs. "green" or renewable energy.) We argue that placing caps on the brown energy consumption of data centers

Bianchini, Ricardo

413

GreenHadoop: Leveraging Green Energy in Data-Processing Frameworks  

E-Print Network [OSTI]

GreenHadoop: Leveraging Green Energy in Data-Processing Frameworks ´I~nigo Goiri Dept. of Computer that energy demand and supply must be matched, if we are to take full advantage of the green en- ergy workload to match the green energy supply. In particular, we consider data-processing frameworks, in which

414

IEEE TRANSACTIONS ON POWER SYSTEMS, VOL. 7, NO. 3, AUGUST 1992, PP. 1001 1011. A VECTOR ENERGY FUNCTION APPROACH FOR  

E-Print Network [OSTI]

reasonably detailed third order HVDC dynamics along with ac system models that include reactive ows the derivationof individualcompo- nent Lyapunovfunctionsforsimpli edmodelsofHVDC links connected to in nitely. Keywords: HVDC, Lyapunov functions, transient en- ergy functions, transient stability, dynamic security as

Cañizares, Claudio A.

415

The idea of the neutrino was put forward in 1930 by Wolfgang Pauli in a desperate attempt to preserve energy  

E-Print Network [OSTI]

are neutrinos expected from cosmological point sources such as gamma-ray bursts and active galactic nuclei microwave en- ergies (10­4 eV) up to the highest cosmic-ray energies (1020 eV). The lowest-energy neutrinos Supernova 1987A Atmospheric GZK BigBang Gamma-raybursts Active galactic nuclei NEUTRINO ENERGY (e

Knowles, David William

416

Integrating Dynamic Pricing of Electricity into Energy Aware Scheduling for HPC Systems  

E-Print Network [OSTI]

- ure that the size of these jobs affects their energy efficiency or not. We hypothesizeIntegrating Dynamic Pricing of Electricity into Energy Aware Scheduling for HPC Systems Xu Yang aimed at reducing en- ergy consumption in HPC environments. In this paper we propose a job power aware

Sun, Xian-He

417

Datasheet Fujitsu EsPRiMO C5731 E-staR 5.0 DEsktOP PC Page 1 / 7 http://ts.fujitsu.com/esPRIMO  

E-Print Network [OSTI]

. Up to 500 GB hard drive and PCI Low Profile Slot eneRgy savIng Reduced power costs and consumption the environmental protection requirements of tomorrow, for example EnERGY staR® 5.0. COMPaCt DesIgn Fully fledged PC and vertical position. Ultra small form factor PC, power supply, legacy interfaces and powered serial ports

Fiebig, Peter

418

A Novel Position Sensitive Detector for Photons and Electrons K. W. Brown*, Z. Q. Gosser, J. M. Krupa*, A. Liao*, J. P. Smith*, T. K. Steinbach, S. Hudan, R.T. de Souza  

E-Print Network [OSTI]

The detection and identification of low energy heavy ions represent a special experimental chal- lenge dueV/c, which is typical of mo- mentum transfers in nuclear reactions, has an en- ergy of 5.5 MeV. Such an ion wishes to detect such particles with high efficiency and to measure their mass, nuclear charge and energy

de Souza, Romualdo T.

419

Experiments in the Use of Stable Limits Sets for Parts Handling Todd D. Murphey, David Choi, Jay Bernheisel, and Kevin M. Lynch  

E-Print Network [OSTI]

, or other properties or local control laws determining the inter- part coupling forces) and the environment they move in (e.g., global fixtures, templates, shaped force fields, and en- ergy input in the form of heating or agitation). When cen- tralized environmental control of the individual parts is lim- ited, so

Hartmann, Mitra J. Z.

420

Interactive Seismic Interpretation with Piecewise Global Energy Minimization  

E-Print Network [OSTI]

Information Administration, roughly 58% of the marketed energy in 2007 were oil and gas products resulted in the need for exploring smaller and more complex oil reservoirs. Planning of the reservoir. It is expected that in 2035 oil and gas will still account for more than 50% of the marketed en- ergy

Note: This page contains sample records for the topic "kinetic en ergy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Extracting Hydrogen Electricity from  

E-Print Network [OSTI]

. In the United States, energy security motivates the de- velopment of previously untapped sources of oil as well & TECHNOLOGY 161A C oncerns about climate change, in- creased global demand for finite oil and natural gas reserves, and national en- ergy security, among other factors, are driving the search for alternatives

422

On the Capacity of a Wireless Backhaul for the Distribution Level of the Smart Grid  

E-Print Network [OSTI]

1 On the Capacity of a Wireless Backhaul for the Distribution Level of the Smart Grid Babak Karimi limitations imposed by the proposed communication architecture. Index Terms--Smart Grids, Distribution Level of the Smart Grid approach. Title XIII of the En- ergy Independent and Security Act 2007 [1] requires improved

Namboodiri, Vinod

423

Design, Analysis, and Learning Control of a Robotic Wind Turbine J. Zico Kolter, Zachary Jackowski, Russ Tedrake*  

E-Print Network [OSTI]

% of the world's energy currently comes from (unsustainable) fossil fuels, and worldwide en- ergy demand, to be of similar cost to fossil fuels for electricity generation [2]. Despite this promise, significant projec- tions predicting wind, given good environmental conditions and proper government subsidies

Jackson, Daniel

424

sustAinABLe energy College of Rural and Community Development  

E-Print Network [OSTI]

sustAinABLe energy College of Rural and Community Development 907-842-5109 or 800-478-5109 www.uaf.edu/rural and training in energy efficiency and renewable en- ergy, the sustainable energy occupational endorsement addresses many of the energy issues that influence Alaska communities and provides the basic academic

Hartman, Chris

425

DEAD-END ELIMINATION AS A HEURISTIC FOR MIN-CUT IMAGE SEGMENTATION Mala L. Radhakrishnan  

E-Print Network [OSTI]

and branch-and-bound to eliminate solutions incompatible with global optimization of the objective functionV self(ip) + X i,jV, iself(ip) is the self energy of pixel i in state p are assigned to the same segment, their pairwise en- ergy is 0. The self energies are such that the energy

Su, Sara

426

The Danish Ministry of Economy and Business Affairs/The Danish Energy  

E-Print Network [OSTI]

for the district heating system should be prepared. · The possibilities of establishment of a major natural gas on these recommendations was elaborated in co- operation with Legionowo Municipality and the municipally owned district heating company in Legionowo. The proposal was submitted to the Danish En- ergy Authority in November 2001

427

AWEA Small Wind Turbine Global Market Study  

E-Print Network [OSTI]

Displaced Carbon Dioxide 17 Building-Mounted Turbines 17 Manufacturing 18 The Global Market 21 Solar Summary Table 1 #12;4 | AMERICAn WInD EnERGy ASSOCIATIOn Based on a 2010 AWEA survey of manufacturers and standardized interconnection regulations, and the appropriation and allocation of federal research

Leu, Tzong-Shyng "Jeremy"

428

Safe Upper-bounds Inference of Energy Consumption for Java Bytecode Applications  

E-Print Network [OSTI]

Safe Upper-bounds Inference of Energy Consumption for Java Bytecode Applications (Extended Abstract relying on autonomous on-board data analysis. Intermediate Representation Resource Usage Analysis Energy- mize energy consumption. Several approaches have been developed for estimating the en- ergy consumption

Politécnica de Madrid, Universidad

429

mong the biggest chal-lenges the world faces  

E-Print Network [OSTI]

EnErgy Consumption A Forrester Research report proj- ects the number of personal com- puters in use efficiency of lead- ing competitors ("The Potential of the Cell Processor for Scientific Computi stated goal is to reduce world energy use to 1990 levels, thereby stabilizing atmo- spheric CO2 emissions

Blevis, Eli

430

SANDIA REPORT SAND2012-1000  

E-Print Network [OSTI]

of Operating Reserve Markets in U.S. ISO/RTO-managed Electric Energy Regions James F. Ellison, Leigh S: A Survey of Operating Reserve Markets in U.S. ISO/RTO-managed Electric Energy Regions James F. Ellison. The goal of the project is to design a wholesale electric power market such that electric en- ergy storage

Tesfatsion, Leigh

431

Anisotropic Heat and Water Transport in a PEFC Cathode Gas Diffusion Layer  

E-Print Network [OSTI]

PEFCs , owing to their high en- ergy efficiency, low emission, and low noise, are widely considered. In addition, the latent heat effects due to condensation/evaporation of water on the temperature and water ohmic losses. Along with water man- agement, thermal management is also a key to high performance

432

John P. Verboncoeur Professor in Residence, Dept NE/ERL  

E-Print Network [OSTI]

. Applications include microwave-beam devices, charged particle beam optics, fusion and other en- ergy plasma code suite, including particle-in-cell Monte Carlo collision codes in 1D periodic, bounded (planar transport, laser and beam plasma wakefield acceler- ators, plasma thrusters, as well as basic plasma physics

Wurtele, Jonathan

433

Fusion11 Conference Summary Carlos A. Bertulani,a  

E-Print Network [OSTI]

, the international project for thermonuclear fusion. This project (presently estimated at 15 billion euros) will open physics and material science. The generation of commercial en- ergy by using thermonuclear fusionFusion11 Conference Summary Carlos A. Bertulani,a Department of Physics and Astronomy, Texas A

Bertulani, Carlos A. - Department of Physics and Astronomy, Texas A&M University

434

Strip, Bind, and Search: A Method for Identifying Abnormal Energy Consumption in Buildings  

E-Print Network [OSTI]

towards reducing the building's en- ergy consumption is to prevent electricity waste due to the improperStrip, Bind, and Search: A Method for Identifying Abnormal Energy Consumption in Buildings Romain, operators are relying more on historical data pro- cessing to uncover opportunities for energy-savings. How

California at Berkeley, University of

435

(This is a sample cover image for this issue. The actual cover is not yet available at this time.) This article appeared in a journal published by Elsevier. The attached  

E-Print Network [OSTI]

, thermal, light, etc.) that is pres- ent in the environment anyway. The efficiency and cost of the energy of thermal en- ergy to electricity. Thermal energy is commonly available in the environment due to waste heat the electrical resistivity. ? 2013 Elsevier Ltd. All rights reserved. 1. Introduction 1.1. Thermoelectric energy

Chung, Deborah D.L.

436

Steam Explosions, Earthquakes, and Volcanic Eruptions--What's in Yellowstone's Future?  

E-Print Network [OSTI]

Steam Explosions, Earthquakes, and Volcanic Eruptions-- What's in Yellowstone's Future? U. In the background, steam vigorously rises from the hot Each year, millions of visitors come to admire the hot, such as geysers. Steam and hot water carry huge quantities of thermal en- ergy to the surface from the magma cham

Torgersen, Christian

437

Multiple-relaxation-time lattice Boltzmann kinetic model for combustion  

E-Print Network [OSTI]

To probe both the Hydrodynamic Non-Equilibrium (HNE) and Thermodynamic Non-Equilibrium (TNE) in the combustion process, a two-dimensional Multiple-Relaxation-Time (MRT) version of Lattice Boltzmann Kinetic Model(LBKM) for combustion phenomena is presented. The chemical energy released in the progress of combustion is dynamically coupled into the system by adding a chemical term to the LB kinetic equation. Beside describing the evolutions of the conserved quantities, the density, momentum and energy, which are what the Navier-Stokes model describes, the MRT-LBKM presents also a coarse-grained description on the evolutions of some non-conserved quantities. The current model works for both subsonic and supersonic flows with or without chemical reaction. In this model both the specific-heat ratio and the Prandtl number are flexible, the TNE effects are naturally presented in each simulation step. The model is verified and validated via well-known benchmark tests. As an initial application, various non-equilibrium behaviours, including the complex interplays between various HNEs, between various TNEs and between the HNE and TNE, around the detonation wave in the unsteady and steady one-dimensional detonation processes are preliminarily probed. It is found that the system viscosity (or heat conductivity) decreases the local TNE, but increase the global TNE around the detonation wave, that even locally, the system viscosity (or heat conductivity) results in two kinds of competing trends, to increase and to decrease the TNE effects. The physical reason is that the viscosity (or heat conductivity) takes part in both the thermodynamic and hydrodynamic responses.

Aiguo Xu; Chuandong Lin; Guangcai Zhang; Yingjun Li

2015-03-13T23:59:59.000Z

438

Multiple-relaxation-time lattice Boltzmann kinetic model for combustion  

E-Print Network [OSTI]

To probe both the Mechanical Non-Equilibrium (MNE) and Thermodynamic Non-Equilibrium (TNE) in the combustion procedure, a two-dimensional Multiple-Relaxation-Time (MRT) version of the Lattice Boltzmann Kinetic Model(LBKM) for combustion phenomena is presented. The chemical energy released in the progress of combustion is dynamically coupled into the system by adding a chemical term to the LB kinetic equation. The LB model is required to recover the Navier-Stokes equations with chemical reaction in the hydrodynamic limit. To that aim, we construct a discrete velocity model with $24$ velocities divided into $3$ groups. In each group a flexible parameter is used to control the size of discrete velocities and a second parameter is used to describe the contribution of the extra degrees of freedom. The current model works for both subsonic and supersonic flows with or without chemical reaction. In this model both the specific-heat ratio and the Prandtl number are flexible, the TNE effects are naturally presented in each simulation step. Via the MRT model, it is more convenient to track the effects of TNE and how the TNE influence the MNE behaviors. The model is verified and validated via well-known benchmark tests. It is found that around the detonation wave there are competition between the viscous effect, thermal diffusion effect and the gradient effects of physical quantities. Consequently, with decreasing the collision parameters, (i) the nonequilibrium region becomes wider and the gradients of physical quantities decrease; (ii) the position where the internal energy in the shocking degree of freedom equals the one averaged over all degrees of freedom moves away from the position for the von Neumann peak.

Aiguo Xu; Chuandong Lin; Guangcai Zhang; Yingjun Li

2014-11-25T23:59:59.000Z

439

La experimentacin de formas dramticas en las escrituras femeninas/escrituras de la mujer en Chile  

E-Print Network [OSTI]

potencia los hallazgos anteriores. Los que van quedando en el camino (1969) tiene tres planos de accin y tiempo. El presente, contemporneo al montaje (1969), en el cual una anciana y su sobrina ven pasar una columna de manifestantes, fundamentalmente... circunstancias histricas tienen sus propios imperativos, de difcil resolucin moral y afectiva. Igual cosa ocurre en Dilogo de fin de siglo, situada en la sangrienta Guerra Civil ocurrida en 1891 en Chile. Como en Lautaro, la accin permanece siempre...

Hurtado, Marí a de la Luz

1998-04-01T23:59:59.000Z

440

Kinetic study of the reaction between nitric oxide and carbon monoxide catalyzed by clean polycrystalline platinum  

SciTech Connect (OSTI)

The kinetics of the platinum catalyzed reaction between NO and CO has been studied under conditions chosen to approximate those observed during operation of catalysts in automotive exhaust gas treatment applications. The catalysts were polycrystalline platinum foils and wires. The reaction was studied over a range of reactant partial pressures of 10 V Torr to 1 Torr and catalyst temperatures of 500 to 1500K. The steady-state kinetics results could not be fit by a simple Langmuir-Hinshelwood kinetic model over all experimental conditions studied. The kinetics at high coverage were most consistent with Langmuir-Hinshelwood kinetics assuming a bimolecular reaction between NO and CO as the rate-limiting step. At high temperature, the Langmuir-Hinshelwood assumption of fast adsorption-desorption equilibrium relative to the surface reaction rate was no longer appropriate and the mechanism of adsorption of NO had to be considered explicitly.

Klein, R.L.

1984-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "kinetic en ergy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

AUTOMNE 2013 MATRISE EN COMMUNICATION  

E-Print Network [OSTI]

AUTOMNE 2013 MA?TRISE EN COMMUNICATION LUNDI MARDI MERCREDI JEUDI VENDREDI 9 :00 ? 12 :00 CEP 6002 / COM 6502 COM 6331 COM 6535 (max 10) COM 6020 Approches en communication politique la communication Prof : Daniel Robichaud Salle A415 13 :00 ? 16 :00 COM 6420 COM 6285 COM

Parrott, Lael

442

DOI: 10.1002/ejic.200600960 Synthesis and Sublimation Kinetics of a Highly Volatile Asymmetric Iron(II)  

E-Print Network [OSTI]

FULL PAPER DOI: 10.1002/ejic.200600960 Synthesis and Sublimation Kinetics of a Highly Volatile: Asymmetric iron(II) amidinate / Bridging ligands / Metathesis / Sublimation kinetics / Thermochemistry properties have been the subject of intense investigations in chemistry, electronics, optics, energy

443

CHEMKIN-III: A FORTRAN chemical kinetics package for the analysis of gas-phase chemical and plasma kinetics  

SciTech Connect (OSTI)

This document is the user`s manual for the third-generation CHEMKIN package. CHEMKIN is a software package whose purpose is to facilitate the formation, solution, and interpretation of problems involving elementary gas-phase chemical kinetics. It provides a flexible and powerful tool for incorporating complex chemical kinetics into simulations of fluid dynamics. The package consists of two major software components: an Interpreter and a Gas-Phase Subroutine Library. The Interpreter is a program that reads a symbolic description of an elementary, user-specified chemical reaction mechanism. One output from the Interpreter is a data file that forms a link to the Gas-Phase Subroutine Library. This library is a collection of about 100 highly modular FORTRAN subroutines that may be called to return information on equations of state, thermodynamic properties, and chemical production rates. CHEMKIN-III includes capabilities for treating multi-fluid plasma systems, that are not in thermal equilibrium. These new capabilities allow researchers to describe chemistry systems that are characterized by more than one temperature, in which reactions may depend on temperatures associated with different species; i.e. reactions may be driven by collisions with electrons, ions, or charge-neutral species. These new features have been implemented in such a way as to require little or no changes to CHEMKIN implementation for systems in thermal equilibrium, where all species share the same gas temperature. CHEMKIN-III now has the capability to handle weakly ionized plasma chemistry, especially for application related to advanced semiconductor processing.

Kee, R.J.; Rupley, F.M.; Meeks, E.; Miller, J.A.

1996-05-01T23:59:59.000Z

444

Ion kinetic energy conservation and magnetic field strength constancy in multi-fluid solar wind Alfv\\'enic turbulence  

E-Print Network [OSTI]

We investigate properties of the plasma fluid motion in the large amplitude low frequency fluctuations of highly Alfv\\'enic fast solar wind. We show that protons locally conserve total kinetic energy when observed from an effective frame of reference comoving with the fluctuations. For typical properties of the fast wind, this frame can be reasonably identified by alpha particles, which, owing to their drift with respect to protons at about the Alfv\\'en speed along the magnetic field, do not partake in the fluid low frequency fluctuations. Using their velocity to transform proton velocity into the frame of Alfv\\'enic turbulence, we demonstrate that the resulting plasma motion is characterized by a constant absolute value of the velocity, zero electric fields, and aligned velocity and magnetic field vectors as expected for unidirectional Alfv\\'enic fluctuations in equilibrium. We propose that this constraint, via the correlation between velocity and magnetic field in Alfv\\'enic turbulence, is at the origin of ...

Matteini, L; Pantellini, F; Velli, M; Schwartz, S J

2015-01-01T23:59:59.000Z

445

Excitation of kinetic geodesic acoustic modes by drift waves in nonuniform plasmas Z. Qiu, L. Chen, and F. Zonca  

E-Print Network [OSTI]

Excitation of kinetic geodesic acoustic modes by drift waves in nonuniform plasmas Z. Qiu, L. Chen://scitation.aip.org/termsconditions. Downloaded to IP: 192.107.52.30 On: Thu, 06 Feb 2014 15:42:45 #12;Excitation of kinetic geodesic acoustic) Effects of system nonuniformities and kinetic dispersiveness on the spontaneous excitation of Geodesic

Zonca, Fulvio

446

An efficient high-order finite difference gas-kinetic scheme for the Euler and Navier-Stokes solutions  

E-Print Network [OSTI]

-kinetic scheme is constructed. Different from the previous high-order finite volume gas-kinetic method [Li, Xu) Preprint submitted to Elsevier April 17, 2013 #12;covers the gas evolution process from the particle free a new finite volume gas-kinetic scheme has been developed [27], which significantly reduces

Xu, Kun

447

Lattice Boltzmann method and gas-kinetic BGK scheme in the low-Mach number viscous flow simulations  

E-Print Network [OSTI]

and collisions process. On the other hand, the gas-kinetic BGK scheme is a finite volume scheme, where the timeLattice Boltzmann method and gas-kinetic BGK scheme in the low-Mach number viscous flow simulations method (LBM) and the gas-kinetic BGK scheme are based on the numerical discretization of the Boltzmann

Xu, Kun

448

Fundamental Chemical Kinetic And Thermodynamic Data For Purex Process Models  

SciTech Connect (OSTI)

To support either the continued operations of current reprocessing plants or the development of future fuel processing using hydrometallurgical processes, such as Advanced Purex or UREX type flowsheets, the accurate simulation of Purex solvent extraction is required. In recent years we have developed advanced process modeling capabilities that utilize modern software platforms such as Aspen Custom Modeler and can be run in steady state and dynamic simulations. However, such advanced models of the Purex process require a wide range of fundamental data including all relevant basic chemical kinetic and thermodynamic data for the major species present in the process. This paper will summarize some of these recent process chemistry studies that underpin our simulation, design and testing of Purex solvent extraction flowsheets. Whilst much kinetic data for actinide redox reactions in nitric acid exists in the literature, the data on reactions in the diluted TBP solvent phase is much rarer. This inhibits the accurate modelization of the Purex process particularly when species show a significant extractability in to the solvent phase or when cycling between solvent and aqueous phases occurs, for example in the reductive stripping of Pu(IV) by ferrous sulfamate in the Magnox reprocessing plant. To support current oxide reprocessing, we have investigated a range of solvent phase reactions: - U(IV)+HNO{sub 3}; - U(IV)+HNO{sub 2}; - U(IV)+HNO{sub 3} (Pu catalysis); - U(IV)+HNO{sub 3} (Tc catalysis); - U(IV)+ Np(VI); - U(IV)+Np(V); - Np(IV)+HNO{sub 3}; - Np(V)+Np(V); Rate equations have been determined for all these reactions and kinetic rate constants and activation energies are now available. Specific features of these reactions in the TBP phase include the roles of water and hydrolyzed intermediates in the reaction mechanisms. In reactions involving Np(V), cation-cation complex formation, which is much more favourable in TBP than in HNO{sub 3}, also occurs and complicates the redox chemistry. Whilst some features of the redox chemistry in TBP appear similar to the corresponding reactions in aqueous HNO{sub 3}, there are notable differences in rates, the forms of the rate equations and mechanisms. Secondly, to underpin the development of advanced single cycle flowsheets using the complexant aceto-hydroxamic acid, we have also characterised in some detail its redox chemistry and solvent extraction behaviour with both Np and Pu ions. We find that simple hydroxamic acids are remarkably rapid reducing agents for Np(VI). They also reduce Pu(VI) and cause a much slower reduction of Pu(IV) through a complex mechanism involving acid hydrolysis of the ligand. AHA is a strong hydrophilic and selective complexant for the tetravalent actinide ions as evidenced by stability constant and solvent extraction data for An(IV), M(III) and U(VI) ions. This has allowed the successful design of U/Pu+Np separation flowsheets suitable for advanced fuel cycles. (authors)

Taylor, R.J.; Fox, O.D.; Sarsfield, M.J.; Carrott, M.J.; Mason, C.; Woodhead, D.A.; Maher, C.J. [British Technology Centre, Nexia Solutions, Sellafield, Seascale, CA20 1PG (United Kingdom); Steele, H. [Nexia Solutions, inton House, Risley, Warrington, WA3 6AS (United Kingdom); Koltunov, V.S. [A.A. Bochvar All-Russia Institute of Inorganic Materials, VNIINM, PO Box 369, Moscow 123060 (Russian Federation)

2007-07-01T23:59:59.000Z

449

[Escribir texto] LA CIENCIA EN EUSKADI  

E-Print Network [OSTI]

INFORME SOBRE LA CIENCIA EN EUSKADI 2012 #12;[Escribir texto] LA CIENCIA EN EUSKADI Informe 2012 #12;i Índice 1. Resumen ejecutivo 01 2. La ciencia en euskadi entre 2003 y 2010 03 2.0. PREÁMBULO 03 2 DE EUSKADI 11 2.4. RENDIMIENTO CIENTÍFICO DE EUSKADI 16 3. Referencias 24 #12;LA CIENCIA EN EUSKADI

Cortes, Jesus

450

MsterUniversitario enBiodiversidadenreas  

E-Print Network [OSTI]

instituciones que desarrollen su tra-> bajo en los campos del inventario de la biodiversidad, desarrollo de

451

KNMI publicatie 221 Extreme klimaatverandering en  

E-Print Network [OSTI]

. Superstormen 16 5.1 Introductie: extreme wind en kustverdediging 16 5.2 Extreme wind en wateropzet in het verleden 17 5.3 Detectie van superstormen 18 5.4 Extreme wind en wateropzet in de toekomst 20 5.5 DiscussieKNMI publicatie 221 · · · · · · · · april 2008 Extreme klimaatverandering en waterveiligheid

Stoffelen, Ad

452

TOTAL SES SL EJ//EK EN IV EN III  

National Nuclear Security Administration (NNSA)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarlyEnergyDepartmentNationalRestart of the Reviewwill help prepare local studentsEJ/EK EN V EN IV EN

453

Turbulent Flame Speeds and NOx Kinetics of HHC Fuels with Contaminants and High Dilution Levels  

SciTech Connect (OSTI)

This final report documents the technical results of the 3-year project entitled, Turbulent Flame Speeds and NOx Kinetics of HHC Fuels with Contaminants and High Dilution Levels, funded under the NETL of DOE. The research was conducted under six main tasks: 1) program management and planning; 2) turbulent flame speed measurements of syngas mixtures; 3) laminar flame speed measurements with diluents; 4) NOx mechanism validation experiments; 5) fundamental NOx kinetics; and 6) the effect of impurities on NOx kinetics. Experiments were performed using primary constant-volume vessels for laminar and turbulent flame speeds and shock tubes for ignition delay times and species concentrations. In addition to the existing shock- tube and flame speed facilities, a new capability in measuring turbulent flame speeds was developed under this grant. Other highlights include an improved NOx kinetics mechanism; a database on syngas blends for real fuel mixtures with and without impurities; an improved hydrogen sulfide mechanism; an improved ammonia kintics mechanism; laminar flame speed data at high pressures with water addition; and the development of an inexpensive absorption spectroscopy diagnostic for shock-tube measurements of OH time histories. The Project Results for this work can be divided into 13 major sections, which form the basis of this report. These 13 topics are divided into the five areas: 1) laminar flame speeds; 2) Nitrogen Oxide and Ammonia chemical kinetics; 3) syngas impurities chemical kinetics; 4) turbulent flame speeds; and 5) OH absorption measurements for chemical kinetics.

Peterson, Eric; Krejci, Michael; Mathieu, Olivier; Vissotski, Andrew; Ravi, Sankat; Plichta, Drew; Sikes, Travis; Levacque, Anthony; Camou, Alejandro; Aul, Christopher

2013-09-30T23:59:59.000Z

454

Empirical and physics based mathematical models of uranium hydride decomposition kinetics with quantified uncertainties.  

SciTech Connect (OSTI)

Metal particle beds have recently become a major technique for hydrogen storage. In order to extract hydrogen from such beds, it is crucial to understand the decomposition kinetics of the metal hydride. We are interested in obtaining a a better understanding of the uranium hydride (UH3) decomposition kinetics. We first developed an empirical model by fitting data compiled from different experimental studies in the literature and quantified the uncertainty resulting from the scattered data. We found that the decomposition time range predicted by the obtained kinetics was in a good agreement with published experimental results. Secondly, we developed a physics based mathematical model to simulate the rate of hydrogen diffusion in a hydride particle during the decomposition. We used this model to simulate the decomposition of the particles for temperatures ranging from 300K to 1000K while propagating parametric uncertainty and evaluated the kinetics from the results. We compared the kinetics parameters derived from the empirical and physics based models and found that the uncertainty in the kinetics predicted by the physics based model covers the scattered experimental data. Finally, we used the physics-based kinetics parameters to simulate the effects of boundary resistances and powder morphological changes during decomposition in a continuum level model. We found that the species change within the bed occurring during the decomposition accelerates the hydrogen flow by increasing the bed permeability, while the pressure buildup and the thermal barrier forming at the wall significantly impede the hydrogen extraction.

Salloum, Maher N.; Gharagozloo, Patricia E.

2013-10-01T23:59:59.000Z

455

Pattern Formation and Growth Kinetics in Eutectic Systems  

SciTech Connect (OSTI)

Growth patterns during liquid/solid phase transformation are governed by simultaneous effects of heat and mass transfer mechanisms, creation of new interfaces, jump of the crystallization units from liquid to solid and their rearrangement in the solid matrix. To examine how the above processes influence the scale of microstructure, two eutectic systems are chosen for the study: a polymeric system polyethylene glycol-p-dibromobenzene (PEG-DBBZ) and a simple molecular system succinonitrile (SCN)-camphor. The scaling law for SCN-camphor system is found to follow the classical Jackson-Hunt model of circular rod eutectic, where the diffusion in the liquid and the interface energy are the main physics governing the two-phase pattern. In contrast, a significantly different scaling law is observed for the polymer system. The interface kinetics of PEG phase and its solute concentration dependence thus have been critically investigated for the first time by directional solidification technique. A model is then proposed that shows that the two-phase pattern in polymers is governed by the interface diffusion and the interface kinetics. In SCN-camphor system, a new branch of eutectic, elliptical shape rodl, is found in thin samples where only one layer of camphor rods is present. It is found that the orientation of the ellipse can change from the major axis in the direction of the thickness to the direction of the width as the velocity and/or the sample thickness is decreased. A theoretical model is developed that predicts the spacing and orientation of the elliptical rods in a thin sample. The single phase growth patterns of SCN-camphor system were also examined with emphasis on the three-dimensional single cell and cell/dendrite transition. For the 3D single cell in a capillary tube, the entire cell shape ahead of the eutectic front can be described by the Saffmann-Taylor finger only at extremely low growth rate. A 3D directional solidification model is developed to characterize the cell shape and tip undercooling and the experimental results are compared with the predictions of the model. From the investigation of cell/dendrite transition, a model is proposed, from which the condition for the onset of the transition can be obtained.

Jing Teng

2007-12-01T23:59:59.000Z

456

Reduced and Validated Kinetic Mechanisms for Hydrogen-CO-sir Combustion in Gas Turbines  

SciTech Connect (OSTI)

Rigorous experimental, theoretical, and numerical investigation of various issues relevant to the development of reduced, validated kinetic mechanisms for synthetic gas combustion in gas turbines was carried out - including the construction of new radiation models for combusting flows, improvement of flame speed measurement techniques, measurements and chemical kinetic analysis of H{sub 2}/CO/CO{sub 2}/O{sub 2}/diluent mixtures, revision of the H{sub 2}/O{sub 2} kinetic model to improve flame speed prediction capabilities, and development of a multi-time scale algorithm to improve computational efficiency in reacting flow simulations.

Yiguang Ju; Frederick Dryer

2009-02-07T23:59:59.000Z

457

The relationship between the Wigner-Weyl kinetic formalism and the complex geometrical optics method  

E-Print Network [OSTI]

The relationship between two different asymptotic techniques developed in order to describe the propagation of waves beyond the standard geometrical optics approximation, namely, the Wigner-Weyl kinetic formalism and the complex geometrical optics method, is addressed. More specifically, a solution of the wave kinetic equation, relevant to the Wigner-Weyl formalism, is obtained which yields the same wavefield intensity as the complex geometrical optics method. Such a relationship is also discussed on the basis of the analytical solution of the wave kinetic equation specific to Gaussian beams of electromagnetic waves propagating in a ``lens-like'' medium for which the complex geometrical optics solution is already available.

Omar Maj

2005-11-04T23:59:59.000Z

458

Maximum-Entropy Closures for Kinetic Theories of Neuronal Network Dynamics  

SciTech Connect (OSTI)

We analyze (1+1)D kinetic equations for neuronal network dynamics, which are derived via an intuitive closure from a Boltzmann-like equation governing the evolution of a one-particle (i.e., one-neuron) probability density function. We demonstrate that this intuitive closure is a generalization of moment closures based on the maximum-entropy principle. By invoking maximum-entropy closures, we show how to systematically extend this kinetic theory to obtain higher-order (1+1)D kinetic equations and to include coupled networks of both excitatory and inhibitory neurons.

Rangan, Aaditya V.; Cai, David [Courant Institute of Mathematical Sciences, New York University, New York, New York 10012 (United States)

2006-05-05T23:59:59.000Z

459

II Simposio de Teatro en Berln  

E-Print Network [OSTI]

refiere al espacio escnico, iluminacin, movimiento e idioma. En el Uruguay, despus de largos aos de dictadura y que regresara igualmente en 1985 a la democracia, existe, semejante a la Argentina, una fuerte tradicin del teatro crtico... apartan extensamente de la dramaturgia clsica, ellas deshacen historia en historia, vuelan las ininterrumpidas series de accin a travs de fragmentos y variaciones escnicas. En lugar de acciones clasificadas por dilogos, aparecen textos en prosa...

Panse, Barbara

1996-10-01T23:59:59.000Z

460

Stochastic cooling of bunched beams from fluctuation and kinetic theory  

SciTech Connect (OSTI)

A theoretical formalism for stochastic phase-space cooling of bunched beams in storage rings is developed on the dual basis of classical fluctuation theory and kinetic theory of many-body systems in phase-space. The physics is that of a collection of three-dimensional oscillators coupled via retarded nonconservative interactions determined by an electronic feedback loop. At the heart of the formulation is the existence of several disparate time-scales characterizing the cooling process. Both theoretical approaches describe the cooling process in the form of a Fokker-Planck transport equation in phase-space valid up to second order in the strength and first order in the auto-correlation of the cooling signal. With neglect of the collective correlations induced by the feedback loop, identical expressions are obtained in both cases for the coherent damping and Schottky noise diffusion coefficients. These are expressed in terms of Fourier coefficients in a harmonic decomposition in angle of the generalized nonconservative cooling force written in canonical action-angle variables of the particles in six-dimensional phase-space. Comparison of analytic results to a numerical simulation study with 90 pseudo-particles in a model cooling system is presented.

Chattopadhyay, S.

1982-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "kinetic en ergy" from the National Library of EnergyBeta (NLEBeta).
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to obtain the most current and comprehensive results.


461

Gasification characteristics and kinetics for an Eastern oil shale  

SciTech Connect (OSTI)

Gasification reactivity of an Eastern oil shale was studied in a three-year research project under a cooperative agreement between the Department of Energy, Morgantown Energy Technology Center, and HYCRUDE Corp. to expand the data base on the hydroretorting of Eastern oil shales. Gasification tests were conducted with the Indiana New Albany oil shale during the first year of the program. A total of six Eastern oil shales are planned to be tested during the program. A laboratory thermobalance and a 2-inch diameter fluidized bed were used to conduct gasification tests with Indiana New Albany oil shale. Temperature and pressure ranges used were 1600 to 1900/sup 0/F and 15 to 500 psig, respectively. Fifteen thermobalance tests were made in hydrogen/steam and synthesis gas/steam mixtures. Six fluidized-bed tests were made in the same synthesis gas/steam mixture. Carbon conversions as high as 95% were achieved. Thermobalance test results and a kinetic description of weight loss during hydrogen/steam gasification are presented. 14 refs., 6 figs., 4 tabs.

Lau, F.S.; Rue, D.M.; Punwani, D.V.; Rex, R.C. Jr.

1987-01-01T23:59:59.000Z

462

Coupled simulation of kinetic pedestal growth and MHD ELM crash  

SciTech Connect (OSTI)

Edge pedestal height and the accompanying ELM crash are critical elements of ITER physics yet to be understood and predicted through high performance computing. An entirely self-consistent first principles simulation is being pursued as a long term research goal, and the plan is planned for completion in time for ITER operation. However, a proof-of-principle work has already been established using a computational tool that employs the best first principles physics available at the present time. A kinetic edge equilibrium code XGC0, which can simulate the neoclassically dominant pedestal growth from neutral ionization (using a phenomenological residual turbulence diffusion motion superposed upon the neoclassical particle motion) is coupled to an extended MHD code M3D, which can perform the nonlinear ELM crash. The stability boundary of the pedestal is checked by an ideal MHD linear peeling-ballooning code, which has been validated against many experimental data sets for the large scale (type I) ELMs onset boundary. The coupling workflow and scientific results to be enabled by it are described.

Park, G. [New York University; Cummings, J. [California Institute of Technology, University of California, Davis; Chang, C. S. [New York University; Klasky, Scott A [ORNL; Ku, S. [New York University; Podhorszki, Norbert [University of California, Davis; Pankin, A. [Lehigh University, Bethlehem, PA; Samtaney, Ravi [Princeton Plasma Physics Laboratory (PPPL); Shoshani, A. [Lawrence Berkeley National Laboratory (LBNL); Snyder, P. [General Atomics, San Diego; Strauss, H. [New York University; Sugiyama, L. [Massachusetts Institute of Technology (MIT); CPES Team, the [SciDAC Prototype FSP Center for Plasma Edge Simulation

2007-01-01T23:59:59.000Z

463

Sigma phase formation kinetics in stainless steel laminate composites  

SciTech Connect (OSTI)

Stainless steel laminate composites were made to simulate weld microstructures. The use of laminates with variations in chemical composition allows for one dimensional analysis of phase transformation associated with the more complex three-dimensional solidification experience of weld metal. Alternate layers of austenitic (304L and 316L) and ferritic (Ebrite) stainless steels allowed for the study of sigma phase formation at the austenite-ferrite interface in duplex stainless steel. Two austenitic stainless steels, 304L (18.5Cr-9.2Ni-0.3Mo) and 316L (16.2Cr-10.1Ni-2.6Mo), and one ferritic stainless steel, Ebrite (26.3Cr-0Ni-1.0Mo) were received in the form of sheet which was laboratory cold rolled to a final thickness of 0.25 mm (0.030 in.). Laminate composites were prepared by laboratory hot rolling a vacuum encapsulated compact of alternating layers of the ferrite steel with either 304L or 316L stainless steel sheets. Laminate composite specimens, which simulate duplex austenite-ferrite weld metal structure, were used to establish the kinetics of nucleation and growth of sigma phase. The factors affecting sigma phase formation were identified. The effects of time, temperature, and transport of chromium and nickel were evaluated and used to establish a model for sigma phase formation in the austenite-ferrite interfacial region. Information useful for designing stainless steel welding consumables to be used for high temperature service was determined.

Wenmen, D.W.; Olson, D.L.; Matlock, D.K. [Colorado School of Mines, Golden, CO (United States)] [and others

1994-12-31T23:59:59.000Z

464

Reaction rates for mesoscopic reaction-diffusion kinetics  

E-Print Network [OSTI]

The mesoscopic reaction-diffusion master equation (RDME) is a popular modeling framework, frequently applied to stochastic reaction-diffusion kinetics in systems biology. The RDME is derived from assumptions about the underlying physical properties of the system, and it may produce unphysical results for models where those assumptions fail. In that case, other more comprehensive models are better suited, such as hard-sphere Brownian dynamics (BD). Although the RDME is a model in its own right, and not inferred from any specific microscale model, it proves useful to attempt to approximate a microscale model by a specific choice of mesoscopic reaction rates. In this paper we derive mesoscopic reaction rates by matching certain statistics of the RDME solution to statistics of the solution of a widely used microscopic BD model: the Smoluchowski model with a mixed boundary condition at the reaction radius of two molecules. We also establish fundamental limits for the range of mesh resolutions for which this approach yields accurate results, and show both theoretically and in numerical examples that as we approach the lower fundamental limit, the mesoscopic dynamics approach the microscopic dynamics.

Stefan Hellander; Andreas Hellander; Linda Petzold

2015-01-28T23:59:59.000Z

465

KINETICS OF SLURRY PHASE FISCHER-TROPSCH SYNTHESIS  

SciTech Connect (OSTI)

This report covers the first year of this three-year research grant under the University Coal Research program. The overall objective of this project is to develop a comprehensive kinetic model for slurry phase Fischer-Tropsch synthesis on iron catalysts. This model will be validated with experimental data obtained in a stirred tank slurry reactor (STSR) over a wide range of process conditions. The model will be able to predict concentrations of all reactants and major product species (H{sup 2}O, CO{sub 2}, linear 1- and 2-olefins, and linear paraffins) as a function of reaction conditions in the STSR. During the reporting period we have completed one STSR test with precipitated iron catalyst obtained from Ruhrchemie AG (Oberhausen-Holten, Germany). This catalyst was initially in commercial fixed bed reactors at Sasol in South Africa. The catalyst was tested at 13 different sets of process conditions, and had experienced a moderate deactivation during the first 500 h of testing (decrease in conversion from 56% to 50% at baseline process conditions). The second STSR test has been initiated and after 270 h on stream, the catalyst was tested at 6 different sets of process conditions.

Dragomir B. Bukur; Gilbert F. Froment; Lech Nowicki; Jiang Wang; Wen-Ping Ma

2003-09-29T23:59:59.000Z

466

KINETICS OF SLURRY PHASE FISCHER-TROPSCH SYNTHESIS  

SciTech Connect (OSTI)

This report covers the second year of this three-year research grant under the University Coal Research program. The overall objective of this project is to develop a comprehensive kinetic model for slurry phase Fischer-Tropsch synthesis on iron catalysts. This model will be validated with experimental data obtained in a stirred tank slurry reactor (STSR) over a wide range of process conditions. The model will be able to predict concentrations of all reactants and major product species (H{sub 2}O, CO{sub 2}, linear 1- and 2-olefins, and linear paraffins) as a function of reaction conditions in the STSR. During the second year of the project we completed the STSR test SB-26203 (275-343 h on stream), which was initiated during the first year of the project, and another STSR test (SB-28603 lasting 341 h). Since the inception of the project we completed 3 STSR tests, and evaluated catalyst under 25 different sets of process conditions. A precipitated iron catalyst obtained from Ruhrchemie AG (Oberhausen-Holten, Germany) was used in all tests. This catalyst was used initially in commercial fixed bed reactors at Sasol in South Africa. Also, during the second year we performed a qualitative analysis of experimental data from all three STSR tests. Effects of process conditions (reaction temperature, pressure, feed composition and gas space velocity) on water-gas-shift (WGS) activity and hydrocarbon product distribution have been determined.

Dragomir B. Bukur

2004-09-29T23:59:59.000Z

467

Kinetic Modeling of Combustion Characteristics of Real Biodiesel Fuels  

SciTech Connect (OSTI)

Biodiesel fuels are of much interest today either for replacing or blending with conventional fuels for automotive applications. Predicting engine effects of using biodiesel fuel requires accurate understanding of the combustion characteristics of the fuel, which can be acquired through analysis using reliable detailed reaction mechanisms. Unlike gasoline or diesel that consists of hundreds of chemical compounds, biodiesel fuels contain only a limited number of compounds. Over 90% of the biodiesel fraction is composed of 5 unique long-chain C{sub 18} and C{sub 16} saturated and unsaturated methyl esters. This makes modeling of real biodiesel fuel possible without the need for a fuel surrogate. To this end, a detailed chemical kinetic mechanism has been developed for determining the combustion characteristics of a pure biodiesel (B100) fuel, applicable from low- to high-temperature oxidation regimes. This model has been built based on reaction rate rules established in previous studies at Lawrence Livermore National Laboratory. Computed results are compared with the few fundamental experimental data that exist for biodiesel fuel and its components. In addition, computed results have been compared with experimental data for other long-chain hydrocarbons that are similar in structure to the biodiesel components.

Naik, C V; Westbrook, C K

2009-04-08T23:59:59.000Z

468

Kinetic effects on robustness of electron magnetohydrodynamic structures  

SciTech Connect (OSTI)

Following recent remarkable progress in the development of high-power short-pulse lasers, exploration is ongoing into hitherto unknown phenomena at fast time scales of electrons, the understanding of which is becoming crucial. For a simplified description of such phenomena, the Electron Magnetohydrodynamics (EMHDs) fluid description is often adopted. For the possibility of electron transport in high-density plasma, exact solutions of the EMHD model in the form of electron vortex currents, together with their associated magnetic fields, have been considered. However, the fluid EMHD model does not incorporate kinetic effects. Here, the finite Larmor radius effects owing to a finite electron temperature on the robustness of the exact EMHD structures are investigated using two-dimensional particle-in-cell simulations. It is found that larger EMHD vortex structures can sustain themselves for long periods, even in high temperature plasma; however, sustaining structures at higher temperatures tends to be difficult. With increasing temperature, electrons with finite Larmor radii become disengaged from the localized region. It is also shown that structures localized in smaller regions are more difficult to sustain. A quantitative criterion in terms of the structure size and Larmor radius has been established by simulations over a wide range of parameters. Finally, we conclude that a structure, larger than about eight times the typical Larmor radius at r=R, could form and exist even under the effects of finite electron temperature.

Hata, M. [Department of Physics, Nagoya University, Nagoya 464-8603 (Japan); Sakagami, H. [Fundamental Physics Simulation Research Division, National Institute for Fusion Science, Toki 509-5292 (Japan); Das, A. [Institute for Plasma Research, Bhat, Gandhinagar 382428 (India)

2013-04-15T23:59:59.000Z

469

Mechanism and kinetics of peptide partitioning into membranes  

SciTech Connect (OSTI)

Partitioning properties of transmembrane (TM) polypeptide segments directly determine membrane protein folding, stability, and function, and their understanding is vital for rational design of membrane active peptides. However, direct determination of water-to-bilayer transfer of TM peptides has proved difficult. Experimentally, sufficiently hydrophobic peptides tend to aggregate, while atomistic computer simulations at physiological temperatures cannot yet reach the long time scales required to capture partitioning. Elevating temperatures to accelerate the dynamics has been avoided, as this was thought to lead to rapid denaturing. However, we show here that model TM peptides (WALP) are exceptionally thermostable. Circular dichroism experiments reveal that the peptides remain inserted into the lipid bilayer and are fully helical, even at 90 C. At these temperatures, sampling is 50 500 times faster, sufficient to directly simulate spontaneous partitioning at atomic resolution. A folded insertion pathway is observed, consistent with three-stage partitioning theory. Elevated temperature simulation ensembles further allow the direct calculation of the insertion kinetics, which is found to be first-order for all systems. Insertion barriers are Hin = 15 kcal/mol for a general hydrophobic peptide and 23 kcal/mol for the tryptophan-flanked WALP peptides. The corresponding insertion times at room temperature range from 8.5 s to 163 ms. High-temperature simulations of experimentally validated thermostable systems suggest a new avenue for systematic exploration of peptide partitioning properties.

Ulmschneider, Martin [University of Oxford; Killian, J Antoinette [University of Utrecht; Doux, Jacques P. F. [University of Utrecht; Smith, Jeremy C [ORNL; Ulmschneider, Jakob [University of Heidelberg

2010-02-01T23:59:59.000Z

470

Kinetically Inhibited Order in a Diamond-Lattice Antiferromagnet  

SciTech Connect (OSTI)

Frustrated magnetic systems exhibit highly degenerate ground states and strong fluctuations, often leading to new physics. An intriguing example of current interest is the antiferromagnet on a diamond lattice, realized physically in the A-site spinel materials. This is a prototypical system in three dimensions where frustration arises from competing interactions rather than purely geometric constraints, and theory suggests the possibility of novel order at low temperature. Here we present a comprehensive single crystal neutron scattering study CoAl2O4, a highly frustrated A-site spinel. We observe strong diffuse scattering that peaks at wavevectors associated with Neel ordering. Below the temperature T*=6.5K, there is a dramatic change in elastic scattering lineshape accompanied by the emergence of well-defined spin-wave excitations. T* had previously been associated with the onset of glassy behavior. Our new results suggest instead that in fact T* signifies a first-order phase transition, but with true long-range order inhibited by the kinetic freezing of domain walls. This scenario might be expected to occur widely in frustrated systems containing first-order phase transitions and is a natural explanation for existing reports of anomalous glassy behavior in other materials.

MacDougall, Gregory J [ORNL; Gout, Delphine J [ORNL; Zarestky, Jerel L [ORNL; Ehlers, Georg [ORNL; Podlesnyak, Andrey A [ORNL; McGuire, Michael A [ORNL; Mandrus, David [ORNL; Nagler, Stephen E [ORNL

2011-01-01T23:59:59.000Z

471

Proyecto Arqueolgico Taraco: Excavaciones de 1996 en Chiripa, Bolivia  

E-Print Network [OSTI]

del Lago Titicaca en Bolivia. Miembros del equipo principalde la Independencia de Bolivia, siendo Taraco el cantn enRodriguez del Consulado de Bolivia en San Francisco nos

1997-01-01T23:59:59.000Z

472

REGIONES EMERGENTES EN URUGUAY, SUB-REGIN PLATA-MERCOSUR (NOUVEAUX TERRITOIRES EN URUGUAY, SOUS-RGION  

E-Print Network [OSTI]

colocarse cada vez más en la creatividad, en mantener un estilo en un ambiente o paisaje agradable, con

473

TOTAL SES EJ/EK EN V EN IV EN III  

National Nuclear Security Administration (NNSA)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarlyEnergyDepartmentNationalRestart of the Reviewwill help prepare local studentsEJ/EK EN V EN IV EN III

474

Fortapt i en god bok : en kommentert oversettelse av Jasper Ffordes Lost in a good book.  

E-Print Network [OSTI]

??Iflge konvensjonene er en god oversettelse en som er likeverdig (ekvivalent) med originalen. Dette forklares gjerne med at leserne av den oversatte teksten skal f (more)

Kristensen, Jana

2006-01-01T23:59:59.000Z

475

Evaluation of kinetic controls on sulfate reduction in a contaminated wetland-aquifer system  

E-Print Network [OSTI]

systems is identifying key kinetic controls on important redox reactions such as sulfate reduction. Anaerobic microbial activities like sulfate reduction are of particular interest because of the important role they play in the degradation of contaminants...

Kneeshaw, Tara Ann

2009-05-15T23:59:59.000Z

476

Pyrolysis kinetics of scrap tire rubbers. 1: Using DTG and TGA  

SciTech Connect (OSTI)

Tire pyrolysis kinetics was investigated to explore an economically viable design for the pyrolysis process. Derivative thermogravimetry (DTG) and thermogravimetric analysis (TGA) were found to provide valuable information on pyrolysis kinetics and mechanisms of a heterogeneous compound like scrap tire rubbers. Kinetic parameters of each compositional compound were obtained by analyzing DTG and TGA results with a series of mathematical methods proposed in this study. The pyrolysis kinetics of the scrap tire rubbers tested was well accounted for by the first-order irreversible independent reactions of three compositional compounds. The sidewall and tread rubber exhibited different thermal degradation patterns, suggesting a compositional difference between them. Isothermal pyrolysis results showed that the sidewall rubber would hardly be degraded at low temperature regions (<600 K), whereas it would be more rapidly degraded than the tread rubber at higher temperatures ({>=}746 K). Because of the shorter pyrolysis time, the higher isothermal pyrolysis temperature appeared to be more economically favorable.

Kim, S.; Park, J.K. [Univ. of Wisconsin, Madison, WI (United States); Chun, H.D. [Research Inst. of Industrial Science and Technology, Pohang (Korea, Republic of)

1995-07-01T23:59:59.000Z

477

Mass fluctuation kinetics : analysis and computation of equilibria and local dynamics  

E-Print Network [OSTI]

The mass fluctuation kinetics (MFK) model is a set of coupled first-order differential equations describing the temporal evolution of means, variances and covariances of species concentrations in systems of chemical ...

Azunre, Paul

2009-01-01T23:59:59.000Z

478

Detailed kinetic study of anisole pyrolysis and oxidation to understand tar formation during biomass  

E-Print Network [OSTI]

biomass combustion and gasification Milena Nowakowska, Olivier Herbinet, Anthony Dufour, Pierre. Methoxyphenols are one of the main precursors of PAH and soot in biomass combustion and gasification. Keywords: Anisole; Pyrolysis; Oxidation; Tars; Biomass; Kinetic modeling Corresponding author

Paris-Sud XI, Université de

479

ONE-DIMENSIONAL PSEUDO-HOMOGENEOUS PACKED BED REACTOR MODELING INCLUDING NO-CO KINETICS  

E-Print Network [OSTI]

the chemical species and energy equations for dynamically incompressible flow in one-dimension. Furthermore, the chemical kinetics on the reduction reaction of nitric oxide by carbon monoxide over rhodium-alumina and platinum-alumina catalysts is investigated...

Srinivasan, Anand

2011-08-31T23:59:59.000Z

480

Building KiMoSin : design requirements for kinetic interfaces in protein education  

E-Print Network [OSTI]

Design guidelines for tools to enhance protein education are developed and applied to a prototype tool. A literature search and personal experience suggest kinetic, tangible models fill the current gaps in protein education. ...

Brown, Ashlie (Ashlie M.)

2007-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "kinetic en ergy" from the National Library of EnergyBeta (NLEBeta).
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481

Accepted Manuscript Kinetic modelling of high density polyethylene pyrolysis: Part 2. Reduction of existing  

E-Print Network [OSTI]

Accepted Manuscript Kinetic modelling of high density polyethylene pyrolysis: Part 2. Reduction density polyethylene pyrolysis: Part 2. Reduction of existing detailed mechanism, Polymer Degradation Modelling of High Density PolyEthylene Pyrolysis: Part 2. Reduction of existing detailed mechanism. N

Paris-Sud XI, Université de

482

Kinetic viscoelasticity modeling applied to degradation during carboncarbon composite processing  

E-Print Network [OSTI]

Kinetic viscoelasticity modeling has been successfully utilized to describe phenomena during cure of thermoset based carbon fiber reinforced matrices. The basic difference from classic viscoelasticity is that the fundamental ...

Drakonakis, Vassilis M.

483

Kinetics of Reduction of Fe(III) Complexes by Outer Membrane...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Fe(III) Complexes by Outer Membrane Cytochromes MtrC and OmcA of Shewanella oneidensis MR-1. Kinetics of Reduction of Fe(III) Complexes by Outer Membrane Cytochromes MtrC and OmcA...

484

A kinetic scheme for unsteady pressurised flows in closed water pipes  

E-Print Network [OSTI]

he aim of this paper is to present a kinetic numerical scheme for the computations of transient pressurised flows in closed water pipes. Firstly, we detail the mathematical model written as a conservative hyperbolic partial differentiel system of equations, and the we recall how to obtain the corresponding kinetic formulation. Then we build the kinetic scheme ensuring an upwinding of the source term due to the topography performed in a close manner described by Perthame et al. using an energetic balance at microscopic level for the Shallow Water equations. The validation is lastly performed in the case of a water hammer in a uniform pipe: we compare the numerical results provided by an industrial code used at EDF-CIH (France), which solves the Allievi equation (the commonly used equation for pressurised flows in pipes) by the method of characteristics, with those of the kinetic scheme. It appears that they are in a very good agreement.

Bourdarias, Christian; Gerbi, Stphane

2008-01-01T23:59:59.000Z

485

Solution of the space-dependent reactor kinetics equations in three dimensions  

E-Print Network [OSTI]

A general class of two-step alternating-direction semi-implicit methods is proposed for the approximate solution of the semi-discrete form of the space-dependent reactor kinetics equations. An exponential transformation ...

Ferguson, Donald Ross

1971-01-01T23:59:59.000Z

486

Post-assembly Modification of Kinetically Metastable FeII 2L3 Triple Helicates  

E-Print Network [OSTI]

,4 which recently led to a report of living supramolecular polymerization by Sugiyasu et al.5 Kinetically metastable species also feature in biological self-assembly, such as during the initial stages of protein folding.6 Biological systems are able...

Roberts, Derrick A.; Castilla, Ana M.; Ronson, Tanya K.; Nitschke, Jonathan R.

2014-05-23T23:59:59.000Z

487

Development of a Grid-Based Gyro-Kinetic Simulation Code  

SciTech Connect (OSTI)

The 4D Semi-Lagrangian code CYGNE for solving electrostatic drift-kinetic equations is presented. The code simulates well the linear phase. In the non-linear, phase development of negative value regions are investigated.

Lapillonne, X.; Brunetti, M.; Brunner, S.; Tran, T.-M. [Ecole Polytechnique Federale de Lausanne (EPFL), Centre de Recherches en Physique des Plasmas, CH-1015 Lausanne (Switzerland)

2006-11-30T23:59:59.000Z

488

The Kinetics and Magnesium Requirements for the Folding of Antigenomic Ribozymes  

E-Print Network [OSTI]

The Kinetics and Magnesium Requirements for the Folding of Antigenomic Ribozymes Sirinart of antigenomic ri- bozyme was studied, it is demonstrated that its L3 loop requires magnesium and, apparently

Perreault, Jean-Pierre

489

The Influence of Equilibrium Reactions on the Kinetics of Calcite Dissolution in Lactic Acid Solutions  

E-Print Network [OSTI]

acid and calcite will allow for optimized treatment design. The kinetic model was also used to isolate the contributions of the transport of reactants, the surface reaction, and the transport of products to the overall resistance of the reaction...

Shedd, Daniel C

2014-08-07T23:59:59.000Z

490

Kinetic trajectory decoding using motor cortical ensembles Andrew H. Fagg1  

E-Print Network [OSTI]

0 Kinetic trajectory decoding using motor cortical ensembles Andrew H. Fagg1 , Greg Ojakangas2, Norman, OK 2 Dept. of Physics, Drury University 3 Dept. of Physiology, Northwestern University, Chicago

Fagg, Andrew H.

491

Addition and recombination reactions of unsaturated radicals using a novel laser kinetics spectrometer  

E-Print Network [OSTI]

This thesis describes the construction of a novel, low-noise laser kinetics spectrometer. A quasi-CW (picosecond pulse), tunable Ti:Sapphire laser is used to detect various transient species in laser flash photolysis ...

Ismail, Huzeifa

2008-01-01T23:59:59.000Z

492

Hydrogen Oxidation and Evolution Reaction Kinetics on Platinum: Acid vs Alkaline Electrolytes  

E-Print Network [OSTI]

The kinetics of the hydrogen oxidation reaction (HOR) and hydrogen evolution reaction (HER) on polycrystalline platinum [Pt(pc)] and high surface area carbon-supported platinum nanoparticles (Pt/C) were studied in 0.1 M ...

Sheng, Wenchao

493

Oxidation kinetics of methylphosphonic acid in supercritical water : experimental measurements and model development  

E-Print Network [OSTI]

(cont.) at well-defined operating conditions and to develop. both microscopic and macroscopic models, ranging from regressed global models to an elementary reaction mechanism, to quantify MPA oxidation kinetics in supercritical ...

Sullivan, Patricia A. (Patricia Ann), 1978-

2004-01-01T23:59:59.000Z

494

Systems, methods and computer-readable media to model kinetic performance of rechargeable electrochemical devices  

DOE Patents [OSTI]

A system includes an electrochemical cell, monitoring hardware, and a computing system. The monitoring hardware samples performance characteristics of the electrochemical cell. The computing system determines cell information from the performance characteristics. The computing system also analyzes the cell information of the electrochemical cell with a Butler-Volmer (BV) expression modified to determine exchange current density of the electrochemical cell by including kinetic performance information related to pulse-time dependence, electrode surface availability, or a combination thereof. A set of sigmoid-based expressions may be included with the modified-BV expression to determine kinetic performance as a function of pulse time. The determined exchange current density may be used with the modified-BV expression, with or without the sigmoid expressions, to analyze other characteristics of the electrochemical cell. Model parameters can be defined in terms of cell aging, making the overall kinetics model amenable to predictive estimates of cell kinetic performance along the aging timeline.

Gering, Kevin L.

2013-01-01T23:59:59.000Z

495

Charge transfer kinetics at the solidsolid interface in porous electrodes  

E-Print Network [OSTI]

Interfacial charge transfer is widely assumed to obey the ButlerVolmer kinetics. For certain liquidsolid interfaces, the MarcusHushChidsey theory is more accurate and predictive, but it has not been applied to porous ...

Bai, Peng

496

Kinetic modeling of amyloid fibrillation and synaptic plasticity as memory loss and formation mechanisms  

E-Print Network [OSTI]

The principles of biochemical kinetics and system engineering are applied to explain memory-related neuroscientific phenomena. Amyloid fibrillation and synaptic plasticity have been our focus of research due to their ...

Lee, Chuang-Chung

2008-01-01T23:59:59.000Z

497

Kinetics and Mechanism of Oxidative Dehydrogenation of Propane on Vanadium, Molybdenum, and Tungsten Oxides  

E-Print Network [OSTI]

Kinetics and Mechanism of Oxidative Dehydrogenation of Propane on Vanadium, Molybdenum catalysts confirmed that oxidative dehydrogenation of propane occurs via similar pathways, which involve for propane dehydrogenation and for propene combustion increase in the sequence VOx/ZrO2

Iglesia, Enrique

498

The distribution of eddy kinetic and potential energies in the global ocean  

E-Print Network [OSTI]

Understanding of the major sources, sinks, and reservoirs of energy in the ocean is briefly updated in a diagram. The nature of the dominant kinetic energy reservoir, that of the balanced variablity, is then found to be ...

Ferrari, Raffaele

499

Festivales de teatro en America.  

E-Print Network [OSTI]

(CENTRO LIBRE DE EXPERIMENTA CIN TEATRAL Y ARTSTICA), de Mxico: Azotea Fantoche/Laboratorio Katarsis La Calle Mascarones Nopalera Zopilote Vale mencionar en prrafo aparte el TEATRO AMBULANTE DE PUEBLA, MEXICO que caus gran impacto en el..., para una obra de tan atrevida concepcin, hacan falta tambin nuevos actores que Santana an no ha logrado formar. La actuacindedicada y voluntariosade 40 integrantes del grupo de la Universidad del Zulia no logr proyectar todo el impacto de la...

Castillo, Susana D.

1974-10-01T23:59:59.000Z

500

Jorge Enrique Adoum en Pars.  

E-Print Network [OSTI]

74 LATIN AMERICAN THEATRE REVIEW Jorge Enrique Adoum en Paris Con El sol bajo las patas de los caballos, del poeta ecuatoriano Adoum, el director Fabio Faccioni ofrece a los espectadores parisinos del Teatro de la Ciudad Universitaria una... individualismo. La mayor parte del teatro latinoamericano contemporneo evoca tragedias o problemas colectivos. En El sol bajo las patas de los caballos tambin, lo importante no es el encuentro de los individuos excep cionales y simblicos que son Atahualpa y...

Rozental, Geneviè ve

1975-04-01T23:59:59.000Z