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1

An nual En ergy Re view 2001  

Gasoline and Diesel Fuel Update (EIA)

An nual En ergy Re view 2001 An nual En ergy Re view 2001 The An nual En ergy Re view (AER) pres ents the En ergy In for ma tion Ad min - is tra tion's his tor i cal en ergy sta tis tics. For many se ries, sta tis tics are given for ev ery year from 1949 through 2001. The sta tis tics, ex pressed in ei ther phys i cal units or Brit ish ther mal units, cover all ma jor en ergy ac tiv i ties, in - clud ing con sump tion, pro duc tion, trade, stocks, and prices, for all ma jor en - ergy com mod i ties, in clud ing fos sil fu els, elec tric ity, and re new able en ergy sources. Pub li ca tion of this re port is re quired un der Pub lic Law 95-91 (De part ment of En ergy Or ga ni za tion Act), Sec tion 205(c), and is in keep ing with re spon - si bil i ties given to the En ergy In for ma tion Ad min is tra tion un der Sec tion

2

TEAM HEV ARC HITECTURE ENGIN E FU EL TRANS MISSION EN ERGY STOR  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

TEAM TEAM HEV ARC HITECTURE ENGIN E FU EL TRANS MISSION EN ERGY STOR AGE MO TOR Michigan Technological University Through-the-road Parallel 2.0-L 4 Cylinder Spark Ignition Reformulated Gasoline 4-speed Automatic COBASYS, Nickel Metal Hydride - 288V 50 kW Solectria AC Induction Transaxle Mississippi State University Through-the-road Parallel 1.9-L GM Direct Injection Turbo Diesel Bio Diesel (B20) GM F40 6-speed Manual Johnson Controls, Nickel Metal Hydride - 330V 45 kW Ballard Integrated Power Transaxle The Ohio State University Through-the-road Parallel 1.9-L GM Direct Injection Turbo Diesel Bio Diesel (B20) Aisin-Warner AF40 6-speed Automatic Transaxle Panasonic, Nickel Metal Hydride - 300V 67 kW Ballard AC Induction Transaxle /10.6 kW Kollmorgen Brushless DC Generator Pennsylvania State

3

molecular resonances p1 and p2, whose en-ergies are 2.3 and 2.7 eV, respectively.  

E-Print Network (OSTI)

molecular resonances p1 and p2, whose en- ergies are ­2.3 and ­2.7 eV, respectively of the silicon substrate (24) to the molecule. Direct evidence of the existence of the two p1 and p2 molecular inside the molecule, different electronically excited states (p1 or p2 resonances) of the molecular

Gilli, Adrian

4

SunErgy AE | Open Energy Information  

Open Energy Info (EERE)

SunErgy AE SunErgy AE Jump to: navigation, search Name SunErgy AE Place Thessaloniki, Greece Zip 55133 Product Sunergy AE develops and manufactures installations for PV projects in Greece. References SunErgy AE[1] LinkedIn Connections CrunchBase Profile No CrunchBase profile. Create one now! This article is a stub. You can help OpenEI by expanding it. SunErgy AE is a company located in Thessaloniki, Greece . http://www.rtl-hessen.de/videos.php?video=7202&kategorie=25 http://www.giessener-allgemeine.de/Home/Stadt/Uebersicht/Artikel,-Schimmel-in-den-Gemeinschaftswaschraeumen-_Schimmel-in-den-Gemeinschaftswaschraeumen-,_arid,128431_regid,1_puid,1_pageid,113.html The college dormitory A.n.n.e.r.ö.d.e.r W.e.g 58 is a financial source for the following project of Amang Aziz: http://www.sunergyweb.eu

5

MinnErgy LLC | Open Energy Information  

Open Energy Info (EERE)

MinnErgy LLC MinnErgy LLC Jump to: navigation, search Name MinnErgy LLC Place Winona, Minnesota Zip 55987 Product MinnErgy is a development stage Minnesota-based firm created for a planned ethanol project. Coordinates 38.046946°, -80.992255° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":38.046946,"lon":-80.992255,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

6

Gasification REnEWABLE EnERGy FROM BIOMASS  

E-Print Network (OSTI)

. This Central Boiler E Classic Outdoor Wood Gasification System contains a furnace surrounded by a water jacket

Bamberg, Stacy Morris

7

ErgyCapital SpA formerly Greenergy Capital | Open Energy Information  

Open Energy Info (EERE)

ErgyCapital SpA formerly Greenergy Capital ErgyCapital SpA formerly Greenergy Capital Jump to: navigation, search Name ErgyCapital SpA (formerly Greenergy Capital) Place Milan, Italy Zip 20121 Sector Efficiency, Renewable Energy Product Investment company specializing in renewable energy and energy efficiency. Coordinates 45.468945°, 9.18103° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":45.468945,"lon":9.18103,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

8

Department of Physics & Astronomy University of Kansas Spring 2009 Department Promotes Renewable En-  

E-Print Network (OSTI)

Renewable En- ergy Research. Distinguished Professor Judy Wu is leading a multidisciplin- ary effort to establish KU as a center for renewable energy research. This past year Judy assembled a team of 29 re for Renewable En- ergy." Faculty members from Physics, Chemistry, Biology and Engineering worked on the proposal

Peterson, Blake R.

9

EnErgy IncEntIvEs: The Power behind The Power  

E-Print Network (OSTI)

of the transformational power of electricity led to government involvement in powerful public-private partnerships

Vertes, Akos

10

TEAM HEV ARC HITECTURE ENGIN E FU EL TRANS MISSION EN ERGY STOR  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Mississippi State University Through-the-road Parallel 1.9-L GM Direct Injection Turbo Diesel Bio Diesel (B20) GM F40 6-speed Manual Johnson Controls, Nickel Metal Hydride - 330V...

11

EnErgy rEsEarch Wind energy research and education  

E-Print Network (OSTI)

.4 The Power Triangle and Power Factor Correction 63 2.5 Three-Wire, Single-Phase Residential Wiring 67 2 118 3.3.2 Single-Phase Synchronous Generators 119 3.3.3 Three-Phase Synchronous Generators 121 3 Systems 307 6.1 Historical Development of Wind Power 307 6.2 Types of Wind Turbines 309 6.3 Power

Dekker, Cees

12

STATEMENT OF CONSIDERATIONS REQUEST BY SIEMENS E~ERGY, INC. ("SEIMENS") FOR AN ADVANCE WAIVER OF  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

SIEMENS SIEMENS E~ERGY, INC. ("SEIMENS") FOR AN ADVANCE WAIVER OF PATENT RIGHTS UN!DER DOE A WARD NO. DE-EE0005493; W(A) 2012-024 I . ~iemer:s has r,e~uested la. waiver, ~f p~tent rights of the United States of Ameri~ for all sub3ect mvent10ns ansmg from rts pmi1c1pat1on under the above referenced award entitled "Offshore 12 MW Turbine Rotor with Advanced Materials and Passive Design Concepts." I The purpose of the aw~rd is to develop, demonstrate, and commercialize wind turbine rotor technologies that will, if fUCcessful, enable a reduction in cost of energy by at least 20 percent. The technologies inc~ude development of a prototype rotor that will be installed on the Siemens 2.3 MW test turbine lbcated at the National Renewable Energy Laboratory's National

13

UC Energy Week 2010 May 10-12, 2010  

E-Print Network (OSTI)

Solar Energy Wind Energy & Integrated Renewables InventIng a new energy Future UC EnErgy WEEk 2010 May Biomass EnErgy solar EnErgy s y gEothErmal EnErgy solar EnErgy Wind EnErgy intEgratE Ed rE nErgy solar EnErgy Wind EnErgy & intEgratEd rEnEWaBlEs Ermal EnErgy solar EnErgy Wind EnErgy g

Yoo, S. J. Ben

14

RetRofitting CoRpoRate Campuses UC Davis EnErgy EffiCiEnCy forUm  

E-Print Network (OSTI)

· system-wide water and energy audits · Water-energy information systems · advanced water capture-generation, emerging lighting and daylighting technologies. Projects range from developing entire systems to converting-Tech Corporate Campus George Denise global account manager cushman & Wakefield at adobe systems Darrell Smith

Yoo, S. J. Ben

15

Api-do: Tools for Exploring the Wireless Attack Surface in Smart Meters  

E-Print Network (OSTI)

. Energy [Online]. Available: http://www.oe.en- ergy.gov/smartgrid.htm [3] R. Sridhar, R. Rajeev, and S

Smith, Sean W.

16

Kinetic Economies  

E-Print Network (OSTI)

We study a minimalist kinetic model for economies. A system of agents with local trading rules display emergent demand behaviour. We examine the resulting wealth distribution to look for non-thermal behaviour. We compare and contrast this model with other similar models.

Abdullah, Wan Ahmad Tajuddin Wan

2007-01-01T23:59:59.000Z

17

nemsoverview_928.vp  

Gasoline and Diesel Fuel Update (EIA)

9) 9) The Na tional En ergy Mod el ing Sys tem: An Over view 2009 October 2009 En ergy In for ma tion Ad min is tra tion Of fice of In te grated Anal y sis and Fore cast ing U.S. De part ment of En ergy Wash ing ton, DC 20585 This re port was pre pared by the En ergy In for ma tion Ad min is tra tion, the in de pend ent sta tis ti cal and an a lyt i cal agency within the U.S. De part ment of En ergy. The in for ma tion con tained herein should be at trib uted to the En ergy In for ma tion Ad min is tra tion and should not be con strued as ad vo cat ing or re flect ing any pol icy po si tion of the De part ment of En ergy or any other or ga ni za tion. This pub li ca tion is on the WEB at: www.eia.doe.gov/oiaf/aeo/over view/ The Na tional En ergy Mod el ing Sys tem: An Over view 2009 pro vides a sum mary de scrip tion of the Na tional En ergy

18

engineering laboratory  

Science Conference Proceedings (OSTI)

... one-fourth of the extra en- ergy actually used to cool and freeze ... 8 percent of the total energy consumed by 111 million US households ac- cording ...

2012-10-10T23:59:59.000Z

19

Designing a Carbon Tax: The Introduction of the Carbon-Burned Tax (CBT)  

E-Print Network (OSTI)

U.S. emissions and natural gas for about one-fifth, although each accounts for about one-fourth of en- ergy consumption

Cristian, Amy C.

1992-01-01T23:59:59.000Z

20

Section 1.3 Current Federal Regulations: Greening Federal Facilities...  

NLE Websites -- All DOE Office Websites (Extended Search)

by 2010 compared to 1985 levels; use of renewable en- ergy and support for the Million Solar Roofs Initiative; and water conservation. Executive Order 13101, "Greening the...

Note: This page contains sample records for the topic "kinetic en ergy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Plasma Kinetic Theory  

Science Conference Proceedings (OSTI)

Kinetic Theory / Proceedings of the Ninth Carolus Magnus Summer School on Plasma and Fusion Energy Physics

B. Weyssow

22

Creating an Energy Awareness Campaign - A Handbook for Federal...  

NLE Websites -- All DOE Office Websites (Extended Search)

n t li b a f Creating an EnErgy AwArEnEss ProgrAm A HAnDBooK For FEDErAL EnErgy mAnAgErs Energy Efficiency Renewable Energy is c ean, abu U.S. Department of Energy and Bringing you...

23

Plasma Kinetic Theory  

Science Conference Proceedings (OSTI)

Basic and Kinetic Theory / Proceedings of the Tenth Carolus Magnus Summer School on Plasma and Fusion Energy Physics

B. Weyssow

24

Computational Thermodynamics and Kinetics  

Science Conference Proceedings (OSTI)

Jul 31, 2011 ... About this Symposium. Meeting, 2012 TMS Annual Meeting & Exhibition. Symposium, Computational Thermodynamics and Kinetics.

25

Chapter 13. Chemical Kinetics  

E-Print Network (OSTI)

of chemical reactions. · Only gases, for which the kinetic theory of Chapter 4 is applicable, are consideredChapter 13. Chemical Kinetics #12;· Why do some chemical reactions proceed with lighting speed when the way in which molecules combine to form products? · All of these questions involve chemical kinetics

Ihee, Hyotcherl

26

A Look at Commercial Buldings in 1995: Characteristics, Energy Consumption, and Energy Expenditures  

U.S. Energy Information Administration (EIA) Indexed Site

DOE/EIA-0625(95) DOE/EIA-0625(95) Distribution Category UC-950 A Look at Commercial Buildings in 1995: Characteristics, Energy Consumption, and Energy Expenditures October 1998 En ergy In for ma tion Ad min istra tion Of fice of En ergy Mar kets and End Use U.S. De part ment of En ergy Wash ing ton, DC 20585 This re port was pre pared by the En ergy In for ma tion Ad min istra tion, the in de pend ent sta tis ti cal and ana lytic agency within the U.S. De part ment of En ergy. The in for ma tion con tained herein should be at trib uted to the En ergy In for ma tion Ad min istra tion and should not be con strued as ad vo cat ing or re flect ing any pol icy po si tion of the De part ment of En ergy or any other or gani za tion. Contacts The En ergy In for ma tion Ad min istra tion (EIA) pre pared this pub li ca tion un der the gen eral di rec tion of W. Cal vin

27

Computational Thermodynamics and Kinetics  

Science Conference Proceedings (OSTI)

A Comprehensive Investigation of Low Angle Grain Boundary Mobility in Pure Al ... A New Treatment for the Kinetics of Isothermal Oxidation of Zinc Powders.

28

Structure and Kinetics  

Science Conference Proceedings (OSTI)

Mar 4, 2013 ... Materials Science in Reduced Gravity: Structure and Kinetics ... Bias fields comprise weak interface energy sources that result from the vector...

29

Thermodynamic and Kinetic Modeling  

Science Conference Proceedings (OSTI)

Oct 11, 2012... capability of the coating and thus the achievable engine efficiency. ... Aluminide coating of steels enables more efficient power generation through ... and kinetic modeling in order to build a time and temperature dependent...

30

Thermodynamic & Kinetic Data for Sustainable Energy  

Science Conference Proceedings (OSTI)

Thermodynamic & Kinetic Data for Sustainable Energy. Summary: Industry needs thermodynamic and kinetic data for the ...

2012-10-05T23:59:59.000Z

31

International Energy Outlook 1998  

Gasoline and Diesel Fuel Update (EIA)

8) 8) Dis tri bu tion Cate gory UC-950 In ter na tional En ergy Out look 1998 April 1998 En ergy In for ma tion Ad min istra tion Of fice of In te grated Analy sis and Fore cast ing U.S. De part ment of En ergy Wash ing ton, DC 20585 This re port was pre pared by the En ergy In for ma tion Ad min istra tion, the in de pend ent sta tis ti cal and ana lyti cal agency within the De part ment of En ergy. The in for ma tion con tained herein should be at trib uted to the En ergy In for ma tion Ad min istra tion and should not be con strued as ad vo cat ing or re flect ing any pol icy po si tion of the De part ment of En ergy or of any other or gani za tion. Con tacts The Inter na tional Energy Out look is pre pared by the Energy Infor ma tion Admin istra tion (EIA). Gen eral

32

Erbium hydride decomposition kinetics.  

DOE Green Energy (OSTI)

Thermal desorption spectroscopy (TDS) is used to study the decomposition kinetics of erbium hydride thin films. The TDS results presented in this report are analyzed quantitatively using Redhead's method to yield kinetic parameters (E{sub A} {approx} 54.2 kcal/mol), which are then utilized to predict hydrogen outgassing in vacuum for a variety of thermal treatments. Interestingly, it was found that the activation energy for desorption can vary by more than 7 kcal/mol (0.30 eV) for seemingly similar samples. In addition, small amounts of less-stable hydrogen were observed for all erbium dihydride films. A detailed explanation of several approaches for analyzing thermal desorption spectra to obtain kinetic information is included as an appendix.

Ferrizz, Robert Matthew

2006-11-01T23:59:59.000Z

33

Kinetic Theory of Plasma Waves  

Science Conference Proceedings (OSTI)

Kinetic Wave Theory / Proceedings of the Tenth Carolus Magnus Summer School on Plasma and Fusion Energy Physics

D. Van Eester; E. Lerche

34

LLNL Chemical Kinetics Modeling Group  

DOE Green Energy (OSTI)

The LLNL chemical kinetics modeling group has been responsible for much progress in the development of chemical kinetic models for practical fuels. The group began its work in the early 1970s, developing chemical kinetic models for methane, ethane, ethanol and halogenated inhibitors. Most recently, it has been developing chemical kinetic models for large n-alkanes, cycloalkanes, hexenes, and large methyl esters. These component models are needed to represent gasoline, diesel, jet, and oil-sand-derived fuels.

Pitz, W J; Westbrook, C K; Mehl, M; Herbinet, O; Curran, H J; Silke, E J

2008-09-24T23:59:59.000Z

35

Kinetic equilibrium and relativistic thermodynamics  

E-Print Network (OSTI)

Relativistic thermodynamics is treated from the point of view of kinetic theory. It is shown that the generalized J\\"uttner distribution suggested in [1] is compatible with kinetic equilibrium. The requirement of compatibility of kinetic and thermodynamic equilibrium reveals several generalizations of the Gibbs relation where the velocity field is an independent thermodynamic variable.

Vn, P

2011-01-01T23:59:59.000Z

36

Kinetic equilibrium and relativistic thermodynamics  

E-Print Network (OSTI)

Relativistic thermodynamics is treated from the point of view of kinetic theory. It is shown that the generalized J\\"uttner distribution suggested in [1] is compatible with kinetic equilibrium. The requirement of compatibility of kinetic and thermodynamic equilibrium reveals several generalizations of the Gibbs relation where the velocity field is an independent thermodynamic variable.

P. Vn

2011-02-01T23:59:59.000Z

37

Updated Eastern Interconnect Wind Power Output and Forecasts for ERGIS: July 2012  

DOE Green Energy (OSTI)

AWS Truepower, LLC (AWST) was retained by the National Renewable Energy Laboratory (NREL) to update wind resource, plant output, and wind power forecasts originally produced by the Eastern Wind Integration and Transmission Study (EWITS). The new data set was to incorporate AWST's updated 200-m wind speed map, additional tall towers that were not included in the original study, and new turbine power curves. Additionally, a primary objective of this new study was to employ new data synthesis techniques developed for the PJM Renewable Integration Study (PRIS) to eliminate diurnal discontinuities resulting from the assimilation of observations into mesoscale model runs. The updated data set covers the same geographic area, 10-minute time resolution, and 2004?2006 study period for the same onshore and offshore (Great Lakes and Atlantic coast) sites as the original EWITS data set.

Pennock, K.

2012-10-01T23:59:59.000Z

38

Updated Eastern Interconnect Wind Power Output and Forecasts for ERGIS: July 2012  

SciTech Connect

AWS Truepower, LLC (AWST) was retained by the National Renewable Energy Laboratory (NREL) to update wind resource, plant output, and wind power forecasts originally produced by the Eastern Wind Integration and Transmission Study (EWITS). The new data set was to incorporate AWST's updated 200-m wind speed map, additional tall towers that were not included in the original study, and new turbine power curves. Additionally, a primary objective of this new study was to employ new data synthesis techniques developed for the PJM Renewable Integration Study (PRIS) to eliminate diurnal discontinuities resulting from the assimilation of observations into mesoscale model runs. The updated data set covers the same geographic area, 10-minute time resolution, and 2004?2006 study period for the same onshore and offshore (Great Lakes and Atlantic coast) sites as the original EWITS data set.

Pennock, K.

2012-10-01T23:59:59.000Z

39

Spatially-discretized high-temperature approximations and their O(N) implementation on a grid  

E-Print Network (OSTI)

average energy and the heat capacity, can be obtained fromthe average en- ergy and the heat capacity are not evaluatedformula E TABLE IV: Heat capacities for the one-dimensional

Predescu, Cristian

2006-01-01T23:59:59.000Z

40

References - Energy Information Administration  

U.S. Energy Information Administration (EIA)

References 1.En ergy In for ma tion Ad min istra tion. Natu ral Gas Pro - duc tive Ca pac ity for the Lower 48 States 1980 through 1991 . DOE/EIA- 0542 (Wash ing ton ...

Note: This page contains sample records for the topic "kinetic en ergy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Gone with the Wind - The Potential Tragedy of the Common Wind  

E-Print Network (OSTI)

42 In fact, the price of wind energy is decreas- ing at aprice of wind en- ergy is competitive with other forms of energyother energy production technologies: 43 the price for wind

Lifshitz-Goldberg, Yaei

2010-01-01T23:59:59.000Z

42

dg cover  

Office of Legacy Management (LM)

on Armed Services and the approval of the President, pursuant to 10 U.S.C. 7431(a). Oil Shale Conversion Facilities Section 19 of the Federal Non-Nuclear En- ergy Research and...

43

A High-Fidelity Energy Monitoring and Feedback Architecture for Reducing Electrical Consumption in Buildings  

E-Print Network (OSTI)

voltage conversion, en- ergy metering, AC/DC power supply,interface with any metering resource uniformly via sMAP. InADE7753 as the energy metering IC. . . . . . . . . . . . .

Jiang, Xiaofan

2010-01-01T23:59:59.000Z

44

Natural Gas Productive Capacity for the Lower 48 States 1986 ...  

U.S. Energy Information Administration (EIA)

con strued as ad vo cat ing or re flect ing any pol icy po si tion of the De part ment of En ergy o r any other or - gani za tion. Preface

45

Kinetics of coal pyrolysis  

Science Conference Proceedings (OSTI)

This report contains results of a coordinated, multi-laboratory investigation of coal devolatilization. Data is reported pertaining to the devolatilization for bituminous coals over three orders of magnitude in apparent heating rate (100 to 100,000 + {degree}C/sec), over two orders of magnitude in particle size (20 to 700 microns), final particle temperatures from 400 to 1600{degree}C, heat transfer modes ranging from convection to radiative, ambient pressure ranging from near vacuum to one atmosphere pressure. The heat transfer characteristics of the reactors are reported in detail. It is assumed the experimental results are to form the basis of a devolatilization data base. Empirical rate expressions are developed for each phase of devolatilization which, when coupled to an awareness of the heat transfer rate potential of a particular devolatilization reactor, indicate the kinetics emphasized by a particular system reactor plus coal sample. The analysis indicates the particular phase of devolatilization that will be emphasized by a particular reactor type and, thereby, the kinetic expressions appropriate to that devolatilization system. Engineering rate expressions are developed from the empirical rate expressions in the context of a fundamental understanding of coal devolatilization developed in the course of the investigation. 164 refs., 223 figs., 44 tabs.

Seery, D.J.; Freihaut, J.D.; Proscia, W.M. (United Technologies Research Center, East Hartford, CT (USA)); Howard, J.B.; Peters, W.; Hsu, J.; Hajaligol, M.; Sarofim, A. (Massachusetts Inst. of Tech., Cambridge, MA (USA)); Jenkins, R.; Mallin, J.; Espindola-Merin, B. (Pennsylvania State Univ., University Park, PA (USA)); Essenhigh, R.; Misra, M.K. (Ohio State Univ., Columbus, OH (USA))

1989-07-01T23:59:59.000Z

46

Amber Kinetics | Open Energy Information  

Open Energy Info (EERE)

search Name Amber Kinetics Product Start-up company developing a novel flywheel energy storage system with the Lawrence Livermore National Laboratory. References Amber...

47

Ca rlsbad Field Office  

NLE Websites -- All DOE Office Websites (Extended Search)

En ergy En ergy Ca rlsbad Field Office P. O . Box 3090 Carlsbad , New Mexico 88221 AUG 2 9 2013 Mr. John E. Kieling , Chief Hazardous Waste Bureau New Mexico Environment Department 2905 Rodeo Park Drive East, Building 1 Santa Fe, New Mexico 87505-6303 Subject: Notification of Class 1 Permit Modification to the Waste Isolation Pilot Plant Hazardous Waste Facility Permit Number: NM4890139088-TSDF

48

5, 86898714, 2005 The Kinetic  

E-Print Network (OSTI)

Technical Note: Simulating chemical systems in Fortran90 and Matlab with the Kinetic PreProcessor KPP-2.1 A estimation techniques, and variational chemical data assimilation applications require the development of ef- ficient tools for the computational simulation of chemical kinetics systems. From a numerical point

Paris-Sud XI, Université de

49

Nonlinear effects in kinetic resolutions  

E-Print Network (OSTI)

The impact of nonlinear effects in the asymmetric catalysis of kinetic resolutions is analyzed. It is found with minimal assumptions that the kinetics of homocompetitive reactions should apply generally to kinetic resolutions involving partially resolved catalysts, and this is supported by experimental observations with the Jacobsen hydrolytic kinetic resolution (HKR) of epoxides. The criterion for a nonlinear effect in asymmetric catalysis--a nonlinear correlation between the enantiomeric excess in a choral ligand and the product enantiomeric excess obtained from a reaction--is examined. The nonlinear effect idea is found to be generalizable to kinetic resolutions and other reactions by replacing consideration of the product enantiomeric excess with the quantity (k[]/k[]-1)/(k[]/k[]+1), a differential kinetic enantiomeric enhancement (DKEE). A nonlinear effect may then be defined by a nonlinear correlation between the DKEE and the chiral ligand enantiomeric excess. The application of these ideas to previously reported kinetic resolutions of sulfoxides and to nonlinear effects in the Jacobsen HKR is described. Relatively small nonlinear effects in kinetic resolutions are sufficient to obtain large asymmetric amplifications. A catalyst modification in the Jacobsen HKR also allows for the development of a novel recyclable system for the iterative enhancement of optical activity.

Johnson, Derrell W.

1999-01-01T23:59:59.000Z

50

Thermodynamics and Kinetics Information at NIST  

Science Conference Proceedings (OSTI)

... Staff (06/28/2013). Thermodynamic & Kinetic Data for Sustainable Energy (10/05/2012). Thermodynamics and Kinetics Group (07/06/2013 ...

2010-05-24T23:59:59.000Z

51

Metal reduction kinetics in Shewanella  

Science Conference Proceedings (OSTI)

Motivation: Metal reduction kinetics have been studied in cultures of dissimilatory metal reducing bacteria which include the Shewanella oneidensis strain MR-1. Estimation of system parameters from time-series data faces obstructions in ...

Raman Lall; Julie Mitchell

2007-09-01T23:59:59.000Z

52

Theoretical Studies in Chemical Kinetics  

NLE Websites -- All DOE Office Websites (Extended Search)

Theoretical Studies in Chemical Kinetics ^ ^ iCi| Theoretical Studies in Chemical Kinetics ^ ^ iCi| under AEC Contract A T (30-1)-3780 " ■ ' Annual Report (1970) Principal In-vestigator: Martin Karpins Institution: Harvard University The research performed under this contract can best be sunmarized under several headings. (a) Alkali-Halideg Alkali-Halide (MX^ M*X*) Exchange Reactions. This project is being continued. A careful study of certain

53

KINETICS OF GAS-GRAIN REACTIONS IN THE SOLAR NEBULA BRUCE FEGLEY, JR.  

E-Print Network (OSTI)

KINETICS OF GAS-GRAIN REACTIONS IN THE SOLAR NEBULA BRUCE FEGLEY, JR. Planetary Chemistry gas phase, gas-grain, and solid phase reactions as a function of pressure and temperature in the solar the local en- vironment cooled significantly or before the gaseous solar nebula was dispersed

Fegley Jr., Bruce

54

Kinetic Wave Power | Open Energy Information  

Open Energy Info (EERE)

Kinetic Wave Power Jump to: navigation, search Name Kinetic Wave Power Address 2861 N Tupelo St Place Midland Zip 48642 Sector Marine and Hydrokinetic Phone number 989-839-9757...

55

Oxidation Kinetics Modeling Applying Phase Field Approach  

Science Conference Proceedings (OSTI)

Presentation Title, Oxidation Kinetics Modeling Applying Phase Field Approach ... chemical reaction rates will increase exponentially and environmental attack...

56

Kinetics of Nano Ti Carbides Precipitation  

Science Conference Proceedings (OSTI)

About this Abstract. Meeting, Materials Science & Technology 2011. Symposium, Steel Product Metallurgy and Applications. Presentation Title, Kinetics of Nano...

57

Modeling & Characterization of Harvestable Kinetic Energy for ...  

Science Conference Proceedings (OSTI)

... gov 301.975-5479. Modeling & Characterization of Harvestable Kinetic Energy for Wearable Medical Sensors. RF-enabled ...

2011-03-14T23:59:59.000Z

58

On fast reactor kinetics studies  

Science Conference Proceedings (OSTI)

The results and the program of fast reactor core time and space kinetics experiments performed and planned to be performed at the IPPE critical facility is presented. The TIMER code was taken as computation support of the experimental work, which allows transient equations to be solved in 3-D geometry with multi-group diffusion approximation. The number of delayed neutron groups varies from 6 to 8. The code implements the solution of both transient neutron transfer problems: a direct one, where neutron flux density and its derivatives, such as reactor power, etc, are determined at each time step, and an inverse one for the point kinetics equation form, where such a parameter as reactivity is determined with a well-known reactor power time variation function. (authors)

Seleznev, E. F.; Belov, A. A. [Nuclear Safety Inst. of the Russian Academy of Sciences IBRAE (Russian Federation); Matveenko, I. P.; Zhukov, A. M.; Raskach, K. F. [Inst. for Physics and Power Engineering IPPE (Russian Federation)

2012-07-01T23:59:59.000Z

59

Kinetically Dominated FRII Radio Sources  

E-Print Network (OSTI)

The existence of FR II objects that are kinetically dominated, the jet kinetic luminosity, $Q$, is larger than the total thermal luminosity (IR to X-ray) of the accretion flow, $L_{bol}$, is of profound theoretical interest. Such objects are not expected in most theoretical models of the central engine of radio loud AGN. Thus, establishing such a class of objects is an important diagnostic for filtering through the myriad of theoretical possibilities. This paper attempts to establish a class of quasars that have existed in a state of kinetic dominance, $R(t)\\equiv Q(t)/L_{bol}(t)>1$, at some epoch, $t$. It is argued that the 10 quasars in this article with a long term time average $Q(t)$, $\\bar{Q}$, that exceed $L_{Edd}$ are likely to have satisfied the condition $R(t)>1$ either presently or in the past based on the rarity of $L_{bol}>L_{Edd}$ quasars. Finally, the existence of these sources is discussed in the context of the theory of the central engine.

Brian Punsly

2006-10-02T23:59:59.000Z

60

ESS 2012 Peer Review - Amber Kinetics Flywheel Energy Storage Demo - Ed Chiao, Amber Kinetics  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

amber_kinetics amber_kinetics DOE Peer Review September 2012 Ed Chiao, CEO amber_kinetics Amber Kinetics: Our Flywheel History Start-up launched in 2009, Stanford University Cleantech Entrepreneurship class Established a technology licensing & flywheel development partnership with LLNL; Amber Kinetics identified new material & lower-cost rotor designs for commercialization Awarded a Smart Grid Energy Storage Demonstration grant award for flywheels Awarded a matching grant for development & demonstration of flywheel technology Stanford University Lawrence Livermore National Laboratory U.S. Department of Energy California Energy Commission World-class institutions | innovative, deep flywheel technology owned by Amber Amber Kinetics, Inc. - Confidential and Proprietary, All Rights Reserved

Note: This page contains sample records for the topic "kinetic en ergy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Microreactor for fast chemical kinetics  

E-Print Network (OSTI)

The chemical reaction process in a T-shaped microchannel is studied experimentally through the reaction of Ca++ with a fluorescent tracer, Calcium-green. For thin channels (10 um), diffusion of species is found to behave in a way independent of the thickness direction. In such a situation, simulations of a two-dimensional reaction-diffusion model agree remarkably well with the experimental measurements. The comparison of experiments and simulations is used to measure the chemical kinetic constant, which we find to be k=3.2 x 10^5 dm^3/(mol s). Applications of the analysis to faster reactions and to micro-titration are also discussed.

Baroud, C N; Menetrier, L; Tabeling, P; Baroud, Charles N.; Okkels, Fridolin; Menetrier, Laure; Tabeling, Patrick

2003-01-01T23:59:59.000Z

62

Kinetic Modeling of Microbiological Processes  

Science Conference Proceedings (OSTI)

Kinetic description of microbiological processes is vital for the design and control of microbe-based biotechnologies such as waste water treatment, petroleum oil recovery, and contaminant attenuation and remediation. Various models have been proposed to describe microbiological processes. This editorial article discusses the advantages and limiation of these modeling approaches in cluding tranditional, Monod-type models and derivatives, and recently developed constraint-based approaches. The article also offers the future direction of modeling researches that best suit for petroleum and environmental biotechnologies.

Liu, Chongxuan; Fang, Yilin

2012-09-17T23:59:59.000Z

63

Shale oil cracking. 1. Kinetics  

DOE Green Energy (OSTI)

Experiments were conducted to determine kinetics for thermal cracking of shale oil vapor over shale. Cracking temperatures of 504 to 610/sup 0/C and residence times of 2 to 11 seconds were used. A first-order Arrhenius rate expression and stoichiometry were obtained. Also observed were changes in the oil quality. Cracking decreased the H/C ratio, increased the nitrogen content, and decreased the pour point of the oil. Gas-phase oil cracking is contrasted to liquid-phase oil coking as a loss mechanism in oil-shale retorting.

Burnham, A.K.; Taylor, J.R.

1979-10-01T23:59:59.000Z

64

Creating an Energy Awareness Campaign - A Handbook for Federal Energy Managers  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

l l n t li b a f Creating an EnErgy AwArEnEss ProgrAm A HAnDBooK For FEDErAL EnErgy mAnAgErs Energy Efficiency Renewable Energy is c ean, abu U.S. Department of Energy and Bringing you a prosperous future where energy dan , re a le, nd af ordable Creating an Energy Awareness Program A HAnDBooK For FEDErAL EnErgy mAnAgErs The Federal government is the single largest domestic user of energy, spending more than $17 billion to power its vehicles, operations, and approximately 500,000 facilities throughout the United States. Federal agencies impact every energy-consuming sector of our economy - commercial, industrial, residential, agricultural, and transportation. Efficient energy management at Federal facilities and operations: * Saves taxpayers money; * Reduces greenhouse gas emissions;

65

Nanocrystallization Reactions and Kinetics, Chemical Partitioning ...  

Science Conference Proceedings (OSTI)

Primary nanocrystallization reactions and kinetics will be discussed for selected FeCo-based ... Search of Half-Metallic Heusler Alloys and their Applications to...

66

Aluminium Dissolution Kinetics in Caustic Media  

uti?, V. and Stumm, W. (1984) Effect of organic acids and fluoride on the dissolution kinetics of hydrous alumina. A model study using the rotating disk

67

Investigating Grain Boundary Structure-Kinetic Property ...  

Science Conference Proceedings (OSTI)

Abstract Scope, Grain boundary energy landscapes contain all the information that is required to describe the kinetic behavior of grain boundaries (GBs).

68

Thermodynamic and Kinetic Simulation and Experimental Results ...  

Science Conference Proceedings (OSTI)

Through the use of thermodynamic and kinetic modeling software, NETL has designed a systematic method that has been successfully developed to design an...

69

ERNSTMORITZARNDTUNIVERSITAT Absolute number density and kinetic analysis  

E-Print Network (OSTI)

plasma-chemical reactions. Therefore, from the analysis of their kinetics, one can learn more about of the technical applications, many plasma­chemical processes within the discharges as well as mechanisms determines all electron induced plasma-chemical processes and hence influences the kinetics of species

Greifswald, Ernst-Moritz-Arndt-Universität

70

Kinetics of Enzymatic Depolymerization of Guar Galactomannan  

E-Print Network (OSTI)

is used as a rheology modifier in many of its applications, previous kinetic studies have been limitedKinetics of Enzymatic Depolymerization of Guar Galactomannan Shamsheer Mahammad, Robert K. Prud'homme, George W. Roberts,*, and Saad A. Khan*, Department of Chemical and Biomolecular Engineering, North

Khan, Saad A.

71

Chemical kinetics and oil shale process design  

SciTech Connect

Oil shale processes are reviewed with the goal of showing how chemical kinetics influences the design and operation of different processes for different types of oil shale. Reaction kinetics are presented for organic pyrolysis, carbon combustion, carbonate decomposition, and sulfur and nitrogen reactions.

Burnham, A.K.

1993-07-01T23:59:59.000Z

72

Kinetic advantage of controlled intermediate nuclear fusion  

SciTech Connect

The dominated process of controlled fusion is to let nuclei gain enough kinetic energy to overcome Coulomb barrier. As a result, a fusion scheme can consider two factors in its design: to increase kinetic energy of nuclei and to alter the Coulomb barrier. Cold Fusion and Hot fusion are all one-factor schemes while Intermediate Fusion is a twofactors scheme. This made CINF kinetically superior. Cold Fusion reduces deuteron-deuteron distance, addressing Coulomb barrier, and Hot Fusion heat up plasma into extreme high temperature, addressing kinetic energy. Without enough kinetic energy made Cold Fusion skeptical. Extreme high temperature made Hot Fusion very difficult to engineer. Because CIFN addresses both factors, CIFN is a more promising technique to be industrialized.

Guo Xiaoming [Physics and Computer Science Department, Wilfrid Laurier University, Waterloo, Ontario, N2L 3C5 (Canada)

2012-09-26T23:59:59.000Z

73

Model simplification of chemical kinetic systems under uncertainty  

E-Print Network (OSTI)

This thesis investigates the impact of uncertainty on the reduction and simplification of chemical kinetics mechanisms. Chemical kinetics simulations of complex fuels are very computationally expensive, especially when ...

Coles, Thomas Michael Kyte

2011-01-01T23:59:59.000Z

74

Modeling of Reactor Kinetics and Dynamics  

SciTech Connect

In order to model a full fuel cycle in a nuclear reactor, it is necessary to simulate the short time-scale kinetic behavior of the reactor as well as the long time-scale dynamics that occur with fuel burnup. The former is modeled using the point kinetics equations, while the latter is modeled by coupling fuel burnup equations with the kinetics equations. When the equations are solved simultaneously with a nonlinear equation solver, the end result is a code with the unique capability of modeling transients at any time during a fuel cycle.

Matthew Johnson; Scott Lucas; Pavel Tsvetkov

2010-09-01T23:59:59.000Z

75

Open Energy Information (en) Open Energy Information (en)  

Open Energy Info (EERE)

Open Energy Information (en) Open Energy Information (en) http:en.openei.orgfavicon.ico http:en.openei.orgwikiSpecial:Search...

76

Rainfall Kinetic Energy in Eastern Australia  

Science Conference Proceedings (OSTI)

Rainfall kinetic energy is a commonly used climatic parameter for the prediction of soil erosion by water. Such a parameter is difficult to measure and is usually estimated from relationships established between rainfall energy and rainfall ...

Colin John Rosewell

1986-11-01T23:59:59.000Z

77

Kinetic Energy LLC | Open Energy Information  

Open Energy Info (EERE)

Name Kinetic Energy LLC Place Texas Utility Id 56210 Utility Location Yes Ownership R NERC ERCOT Yes ISO Ercot Yes Activity Retail Marketing Yes References EIA Form EIA-861...

78

AER NY Kinetics LLC | Open Energy Information  

Open Energy Info (EERE)

Database. This company is involved in the following MHK Projects: Ogdensburg Kinetic Energy Project This article is a stub. You can help OpenEI by expanding it. Retrieved...

79

Kinetic Energy and the Equivalence Principle  

E-Print Network (OSTI)

According to the general theory of relativity, kinetic energy contributes to gravitational mass. Surprisingly, the observational evidence for this prediction does not seem to be discussed in the literature. I reanalyze existing experimental data to test the equivalence principle for the kinetic energy of atomic electrons, and show that fairly strong limits on possible violations can be obtained. I discuss the relationship of this result to the occasional claim that ``light falls with twice the acceleration of ordinary matter.''

S. Carlip

1999-09-03T23:59:59.000Z

80

A general kinetic model: Kinetics and atomic-scale mechanisms of feldspar dissolution.  

E-Print Network (OSTI)

??This thesis presents a general kinetic model and its application to feldspar dissolution. In the framework of Monte Carlo methods, the model simulates the stochastic (more)

Zhang, Li

2008-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "kinetic en ergy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

The Multiplexed Chemical Kinetic Photoionization Mass Spectrometer: A New Approach To Isomer-resolved Chemical Kinetics  

E-Print Network (OSTI)

instruments applied to analysis of complex chemical mixturesrelies on chemical separation (by chromatography) into pureThe multiplexed chemical kinetic photoionization mass

Osborne, David L.

2009-01-01T23:59:59.000Z

82

Kinetic Theory of Plasma Waves - Part III: Inhomogeneous Plasma  

Science Conference Proceedings (OSTI)

Kinetic Theory / Proceedings of the Ninth Carolus Magnus Summer School on Plasma and Fusion Energy Physics

P. U. Lamalle

83

Kinetic Theory of Plasma Waves - Part I: Introduction  

Science Conference Proceedings (OSTI)

Kinetic Theory / Proceedings of the Ninth Carolus Magnus Summer School on Plasma and Fusion Energy Physics

P. U. Lamalle

84

Kinetics of PBX9404 Aging  

DOE Green Energy (OSTI)

PBX 9404 is an early formulation of HMX from which we can learn about the effects of aging in the weapons stockpile. Of particular interest is the presence of 3% nitrocellulose in PBX 9404 as an energetic binder. Nitrocellulose is used pervasively in smokeless gunpowders and was formerly used extensively in the film and art preservation industries. It is well known that nitrocellulose decomposes autocatalytically, and stabilizers, such as the diphenylamine used in PBX 9404, are used to retard its decomposition. Even so, its lifetime is still limited, and the reactions eventually leading to catastrophic autocatalysis are still not understood well despite years of work. In addition to reducing the available energy in the explosive, degradation of nitrocellulose affects the mechanical properties of the pressed PBX 9404 parts by the associated reduction in molecular weight, which reduces the strength of the binder. A structural formula for a monomer of the nitrocellulose used in PBX 9404 is shown. The initial nitration level is 2.3 of 3.0 possible sites, and they have different reactivities. Degradation of nitrocellulose affects many properties. As an aid in examining historical chemical analysis data, several measures of degradation are given for the simple replacement of a nitro group with a hydrogen. The weight percent of nitrocellulose remaining for an initial concentration of 3% as used in PBX 9404 is also given. Of course, the real degradation reaction is more complicated, including chain scission and crosslinking reactions giving other gas species. During the course of this work, we spent considerable time addressing the question, ''Why is PBX 9404 blue?'' There was actually considerable controversy in the color evolution with aging, and the situation was clarified by Ben Richardson at Pantex. Workers there assured us that PBX 9404 starts with an ivory color. Drying the prill prior to pressing turns it a mottled blue, and well-preserved prill samples retain a blue color decades after formulation. Subsequently, heat and light both send it through a progression of colors from grayish blue, blue-green, green, brown, dirty yellow, mottled tan, and eventually pale tan. The progression is accelerated by oxygen and possibly moisture, as has been shown in several accelerated aging studies. The precise compounds causing the color evolution are uncertain, but they are undoubtedly a progression of quinoidal, nitroso, and nitrated DPA compounds. For example, paranitroso DPA is deep blue. Unfortunately, the location of various nitrated DPAs, which ranged from yellow to orange to red to brown and which were used by Pantex as analytical standards in the 1970s, is not currently known. While the color change is indicative of aging, it is by no means a quantitative measure of the extent of nitrocellulose degradation. Inspection of the literature yielded a variety of kinetic models, and the activation energy typically ranges from 25-35 kcal/mol for T<100 C. This literature qualitatively predicts times for 30% decomposition ranging from a few days at 100 C to 1-2 years at 50 C to 50 years at room temperature. To develop a quantitative model, we used the data of Leider and Seaton, which were collected at conditions most closely matching stockpile conditions for any data set we had available. They used PBX 9404 heated as pressed pellets in closed vessels at temperatures ranging from 50 to 100 C for times up to three years, and they report mass loss, gas yield and composition, and chemical analysis of the residual solid by methods used in stockpile surveillance. Initial kinetic analysis of the weight of remaining nitrocellulose as measured by liquid chromatography and the loss of nitrate esters by a colorimetric technique gave an activation energy of 27 kcal/mol. However, the reaction is complex due to the different stability of the three nitroester positions, and this complexity required either parallel first-order reactions or an nth-order reaction (n=3.6), which is mathematically equivalent to a Gamma distribution of frequency factors

Burnham, A K; Fried, L E

2006-09-11T23:59:59.000Z

85

Multiple temperature kinetic model and gas-kinetic method for hypersonic non-equilibrium flow computations  

Science Conference Proceedings (OSTI)

It is well known that for increasingly rarefied flowfields, the predictions from continuum formulation, such as the Navier-Stokes equations lose accuracy. For the high speed diatomic molecular flow in the transitional regime, the inaccuracies are partially ... Keywords: Gas-kinetic method, Hypersonic and rarefied flows, Multiple temperature kinetic model

Kun Xu; Xin He; Chunpei Cai

2008-07-01T23:59:59.000Z

86

Chemical Kinetic Modeling of Advanced Transportation Fuels  

DOE Green Energy (OSTI)

Development of detailed chemical kinetic models for advanced petroleum-based and nonpetroleum based fuels is a difficult challenge because of the hundreds to thousands of different components in these fuels and because some of these fuels contain components that have not been considered in the past. It is important to develop detailed chemical kinetic models for these fuels since the models can be put into engine simulation codes used for optimizing engine design for maximum efficiency and minimal pollutant emissions. For example, these chemistry-enabled engine codes can be used to optimize combustion chamber shape and fuel injection timing. They also allow insight into how the composition of advanced petroleum-based and non-petroleum based fuels affect engine performance characteristics. Additionally, chemical kinetic models can be used separately to interpret important in-cylinder experimental data and gain insight into advanced engine combustion processes such as HCCI and lean burn engines. The objectives are: (1) Develop detailed chemical kinetic reaction models for components of advanced petroleum-based and non-petroleum based fuels. These fuels models include components from vegetable-oil-derived biodiesel, oil-sand derived fuel, alcohol fuels and other advanced bio-based and alternative fuels. (2) Develop detailed chemical kinetic reaction models for mixtures of non-petroleum and petroleum-based components to represent real fuels and lead to efficient reduced combustion models needed for engine modeling codes. (3) Characterize the role of fuel composition on efficiency and pollutant emissions from practical automotive engines.

PItz, W J; Westbrook, C K; Herbinet, O

2009-01-20T23:59:59.000Z

87

Philips Color Kinetics | Open Energy Information  

Open Energy Info (EERE)

Color Kinetics Color Kinetics Jump to: navigation, search Name Philips Color Kinetics Address 3 Burlington Woods Drive, 4th Floor Place Burlington, Massachusetts Zip 01803 Sector Efficiency Product LED lighting systems Website http://www.colorkinetics.com/ Coordinates 42.5005723°, -71.2042619° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":42.5005723,"lon":-71.2042619,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

88

Chemical kinetic modelling of hydrocarbon ignition  

DOE Green Energy (OSTI)

Chemical kinetic modeling of hydrocarbon ignition is discussed with reference to a range of experimental configurations, including shock tubes, detonations, pulse combustors, static reactors, stirred reactors and internal combustion engines. Important conditions of temperature, pressure or other factors are examined to determine the main chemical reaction sequences responsible for chain branching and ignition, and kinetic factors which can alter the rate of ignition are identified. Hydrocarbon ignition usually involves complex interactions between physical and chemical factors, and it therefore is a suitable and often productive subject for computer simulations. In most of the studies to be discussed below, the focus of the attention is placed on the chemical features of the system. The other physical parts of each application are generally included in the form of initial or boundary conditions to the chemical kinetic parts of the problem, as appropriate for each type of application being addressed.

Westbrook, C.K.; Pitz, W.J.; Curran, H.J.; Gaffuri, P.; Marinov, N.M.

1995-08-25T23:59:59.000Z

89

Model Independent Bounds on Kinetic Mixing  

SciTech Connect

New Abelian vector bosons can kinetically mix with the hypercharge gauge boson of the Standard Model. This letter computes the model independent limits on vector bosons with masses from 1 GeV to 1 TeV. The limits arise from the numerous e{sup +}e{sup -} experiments that have been performed in this energy range and bound the kinetic mixing by {epsilon} {approx}< 0.03 for most of the mass range studied, regardless of any additional interactions that the new vector boson may have.

Hook, Anson; Izaguirre, Eder; Wacker, Jay G.; /SLAC

2011-08-22T23:59:59.000Z

90

Radiation from Kinetic Poynting Flux Acceleration  

E-Print Network (OSTI)

We derive analytic formulas for the power output and critical frequency of radiation by electrons accelerated by relativistic kinetic Poynting flux, and validate these results with Particle-In-Cell plasma simulations. We find that the in-situ radiation power output and critical frequency are much below those predicted by the classical synchrotron formulae. We discuss potential astrophysical applications of these results.

Edison Liang; Koichi Noguchi

2007-04-13T23:59:59.000Z

91

Reaction kinetics for remodeling oil shale retorting  

DOE Green Energy (OSTI)

Results from recent laboratory kinetic studies at the Lawrence Livermore Laboratory (LLL) on gasification, pyrolysis, and mineral reactions in oil shale are presented. The specific pyrolysis reactions investigated include the decomposition of kerogen, the evolution of oil, hydrogen and C/sub 2/ plus C/sub 3/ hydrocarbons and the formation of a carbonaceous residue. Data describing the evolution of H/sub 2/ and CH/sub 4/ during secondary pyrolysis of the carbonaceous residue are also presented. The mineral reaction kinetics discussed include the decomposition and/or reaction (with silica or silicates) of calcite, dolomite, dawsonite and nahcolite. Rate equations describing the effects of CO/sub 2/ and steam on the reactions of calcite and dolomite are presented. Finally, kinetics describing gasification of the carbonaceous residue by CO/sub 2/ and H/sub 2/O are examined. The above kinetic data are summarized in a set of rate expressions that can be used in numerical modeling of oil shale retorting. The rate equations are general enough for modeling both in-situ and surface retorting processes.

Campbell, J.H.; Burnham, A.K.

1979-01-01T23:59:59.000Z

92

Ocean Circulation Kinetic Energy: Reservoirs, Sources,  

E-Print Network (OSTI)

. The coupling of the generation of different energy forms in the dynamics (in either balanced or wave motions are almost nonexistent in the ocean. www.annualreviews.org · Ocean Circulation Kinetic Energy 255 Annu.Rev.Fluid processes? Are the seemingly different dynamical ranges coupled? 2. THE OCEANIC ENERGY BUDGET We begin

Ferrari, Raffaele

93

Thermodynamics and Kinetics of a Brownian Motor  

E-Print Network (OSTI)

Thermodynamics and Kinetics of a Brownian Motor R. Dean Astumian Nonequilibrium fluctuations particle separation and the design of molecular motors and pumps. A small particle in a liquid is subject in conjunction with an- isotropy to drive a motor in the context of a "ratchet and pawl" device shrunk to micro

Linke, Heiner

94

KINETICS, STABILITY, AND CONTROL. A Selected Bibliography  

SciTech Connect

References to 529 articles on nuclear reactor control, kinetics, and stability published before autumn 1962 are included. Emphasis is on calculations and theory since the references serve as an aid in analyzing the dynamic behavior of SNAP reactor systems. (D.C.W.)

Johnson, R.L.

1963-03-15T23:59:59.000Z

95

Chemical Kinetic Modeling of Hydrogen Combustion Limits  

Science Conference Proceedings (OSTI)

A detailed chemical kinetic model is used to explore the flammability and detonability of hydrogen mixtures. In the case of flammability, a detailed chemical kinetic mechanism for hydrogen is coupled to the CHEMKIN Premix code to compute premixed, laminar flame speeds. The detailed chemical kinetic model reproduces flame speeds in the literature over a range of equivalence ratios, pressures and reactant temperatures. A series of calculation were performed to assess the key parameters determining the flammability of hydrogen mixtures. Increased reactant temperature was found to greatly increase the flame speed and the flammability of the mixture. The effect of added diluents was assessed. Addition of water and carbon dioxide were found to reduce the flame speed and thus the flammability of a hydrogen mixture approximately equally well and much more than the addition of nitrogen. The detailed chemical kinetic model was used to explore the detonability of hydrogen mixtures. A Zeldovich-von Neumann-Doring (ZND) detonation model coupled with detailed chemical kinetics was used to model the detonation. The effectiveness on different diluents was assessed in reducing the detonability of a hydrogen mixture. Carbon dioxide was found to be most effective in reducing the detonability followed by water and nitrogen. The chemical action of chemical inhibitors on reducing the flammability of hydrogen mixtures is discussed. Bromine and organophosphorus inhibitors act through catalytic cycles that recombine H and OH radicals in the flame. The reduction in H and OH radicals reduces chain branching in the flame through the H + O{sub 2} = OH + O chain branching reaction. The reduction in chain branching and radical production reduces the flame speed and thus the flammability of the hydrogen mixture.

Pitz, W J; Westbrook, C K

2008-04-02T23:59:59.000Z

96

Evaluating Mesoscale NWP Models Using Kinetic Energy Spectra  

Science Conference Proceedings (OSTI)

Kinetic energy spectra derived from observations in the free atmosphere possess a wavenumber dependence of k?3 for large scales, characteristic of 2D turbulence, and transition to a k?5/3 dependence in the mesoscale. Kinetic energy spectra ...

William C. Skamarock

2004-12-01T23:59:59.000Z

97

Isothermal Ice Crystallization Kinetics in the Gas-Diffusion...  

NLE Websites -- All DOE Office Websites (Extended Search)

Isothermal Ice Crystallization Kinetics in the Gas-Diffusion Layer of a Proton-Exchange-Membrane Fuel Cell Title Isothermal Ice Crystallization Kinetics in the Gas-Diffusion Layer...

98

The Vertical Partition of Oceanic Horizontal Kinetic Energy  

Science Conference Proceedings (OSTI)

To produce an interpretation of the surface kinetic energy as measured by altimeters, a survey is made of the vertical structure of kinetic energy profiles in a large number of globally distributed long current meter records. Although the data ...

Carl Wunsch

1997-08-01T23:59:59.000Z

99

Liam (William) O'Brien, PhD is an Assistant Professor in Carleton University's new Architectural Conservation and Sustainability  

E-Print Network (OSTI)

Converting the Sun's Heat to Gasoline Solar Fuel Corporation is a clean tech company transforming technology for converting solar thermal en- ergy (the sun's heat) to fuel (e.g., gasoline, diesel, hydrogen: Strategically build the Solar Fuel, LLC brand such that key s strategic partners will see Solar Fuel's value

Dawson, Jeff W.

100

ing the distribution of those galaxies, the way they clump and spread out, scientists  

E-Print Network (OSTI)

illuminated realms as small as a single molecule and as large as a gamma ray burst. of the Year Agony ex- plosions in the universe: titanic blasts of en- ergy called gamma ray bursts (GRBs). Most notably of black holes and other phenomena in the gamma ray region of the spectrum. And the Wilkinson Microwave

Yildiz, Ahmet

Note: This page contains sample records for the topic "kinetic en ergy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Power-aware Provisioning of Cloud Resources for Real-time Services  

E-Print Network (OSTI)

in the systems. Datacenters consume 10 to 100 times more en- ergy per square foot than typical office buildings- nique for Cloud resources or datacenters, not only for oper- ational cost, but also for system their services without consideration of physical hardwares, while users also can access on-demand and pay-per

Buyya, Rajkumar

102

Free Lunch: Exploiting Renewable Energy For Computing Sherif Akoush, Ripduman Sohan, Andrew Rice, Andrew W. Moore and Andy Hopper  

E-Print Network (OSTI)

Free Lunch: Exploiting Renewable Energy For Computing Sherif Akoush, Ripduman Sohan, Andrew Rice renewable en- ergy by (i) colocating datacentres with these remote energy sources, (ii) connecting them over that period. In anticipation of this growth, our industry is begin- ning to explore renewable energy

Haddadi, Hamed

103

Ris Energy Report 5 Summary, conclusions and recommendations 5 2 Summary, conclusions and recommendations  

E-Print Network (OSTI)

. One of its main objectives is the development of renewable energy, par- ticularly biomass, wind power of the strategy. Among the East Asian nations, China stands out. In line with the country's rapid economic growth, Chinese en- ergy consumption is increasing dramatically. Renewable energy resources already have

104

International Power Engineering Research Collaborations  

E-Print Network (OSTI)

range from market mechanisms to renewable en- ergy integration and from specific power topics to inter- disciplinary projects. Index Terms Collaborative Research and Educa- tion, Renewable Energy, Market Mechanisms with foreign institutions in Spain, Brazil, China and Ma- laysia. The presentation discusses the objectives

Gross, George

105

Under consideration for publication in J. Fluid Mech. 1 Liquid-solid impacts with compressible gas  

E-Print Network (OSTI)

Under consideration for publication in J. Fluid Mech. 1 Liquid-solid impacts with compressible gas: The role played by gas compressibility in gas cushioned liquid-solid impacts is investigated within a viscous gas and inviscid liquid regime. A full analysis of the en- ergy conservation in the gas

Purvis, Richard

106

Islanded house operation using a micro CHP Albert Molderink, Vincent Bakker, Johann L. Hurink, Gerard J.M. Smit  

E-Print Network (OSTI)

of their en- ergy usage, due to rising energy prices and a growing awareness of the greenhouse effect. Because. Figure 1 shows the (measured) electricity usage of a house with a typical high-demand [4]. The total elec. These two models are schematic given in Figure 2. According to the measured energy usage given in Figure 1

Al Hanbali, Ahmad

107

Testing the Standard Model Precision Measurements of the Z and W; Search for the Higgs  

E-Print Network (OSTI)

13 Testing the Standard Model Precision Measurements of the Z and W; Search for the Higgs electrons lose en- ergy rapidly through synchrotron radiation, which varies as E4/, where is the radius first (Ref. 13.1), but with a disappointing luminosity. In July 1989, Mark II reported for the Z a mass

Murayama, Hitoshi

108

IEEE Transactions on Magn@ticS, V O l . MAG-13, No. 1, January 1977 LOSSESINTWISTEDCOMPOSITESUPERCONDUCTORS IN A HIGHPULSEDMAGNETIC FIELD  

E-Print Network (OSTI)

gas holder with a water seal. The entrainment of liquid droplets by the gas is precluded by means values with the aid of calibrated pulsed heaters. The scatter of the measured en- ergy values relative a so varies synchronously with For the theoretical analysis of losses in twisted compos- ite

Mints, Roman G.

109

Energy Efficient Buffer Cache Replacement Jianhui Yue  

E-Print Network (OSTI)

back to the active state. The transition from a lower power state to a higher one re- quires some significantly increases the en- ergy saving opportunities through DAM overlapping and power state transition replacement algorithms only aim to optimize cache hit rates and do not consider the power status of memory

Zhu, Yifeng

110

Ris Energy Report 5 Global drivers for transformation of energy systems 3 Global drivers for transformation of energy  

E-Print Network (OSTI)

by simulta- neous dramatic increases in oil and gas prices. The role of energy supply as a key facilitator decade. Developing countries are devoting more attention to securing their future energy supplies drivers for future en- ergy development activities: · security of supply; · climate change; · energy

111

Virginia Center for Coal+Energy Research VirginiaPolytechnicInstituteandStateUniversity  

E-Print Network (OSTI)

established a reliable set of benchmarks for Virginia's coal, gas and oil, and electricity industries. Future. Assessment of Virginia Coalfield Region Capability to Support an Electric Power Generation Industry. Carl E- sponded well to the changing chal- lenges faced by Virginia's coal and en- ergy industries. The center

112

Microbial Energizers: Fuel Cells That Keep on Going  

E-Print Network (OSTI)

Microbial Energizers: Fuel Cells That Keep on Going Microbes that produce electricity by oxidizing options for ignoring the current "grid" by generating electricity in an alternative, environmentally into electricity without combusting the fuel, which wastes substantial amounts of en- ergy as heat. Efforts

Lovley, Derek

113

Steam Explosions, Earthquakes, and Volcanic Eruptions--What's in Yellowstone's Future?  

E-Print Network (OSTI)

Steam Explosions, Earthquakes, and Volcanic Eruptions-- What's in Yellowstone's Future? U. In the background, steam vigorously rises from the hot Each year, millions of visitors come to admire the hot, such as geysers. Steam and hot water carry huge quantities of thermal en- ergy to the surface from the magma cham

Fleskes, Joe

114

Kinetic Controls on Cu and Pb Sorption by Ferrihydrite  

E-Print Network (OSTI)

nd ed.; Cambridge University Press: New York, 1993. (51) Sparks, D. L. Kinetics of Soil Chemical Processes; Academic Press: New York, 1989. (52) Espenson, J. H. Chemical Kinetics and Reaction Mechanisms, 2Kinetic Controls on Cu and Pb Sorption by Ferrihydrite A N D R E A S C . S C H E I N O

Sparks, Donald L.

115

Kinetic and stationary point-set embeddability for plane graphs  

Science Conference Proceedings (OSTI)

We investigate a kinetic version of point-set embeddability. Given a plane graph G(V,E) where |V|=n, and a set P of n moving points where the trajectory of each point is an algebraic function of constant ... Keywords: kinetic algorithm, kinetic graph drawing, plane graph, point-set embeddability

Zahed Rahmati; Sue H. Whitesides; Valerie King

2012-09-01T23:59:59.000Z

116

Asphalt Oxidation Kinetics and Pavement Oxidation Modeling  

E-Print Network (OSTI)

Most paved roads in the United States are surfaced with asphalt. These asphalt pavements suffer from fatigue cracking and thermal cracking, aggravated by the oxidation and hardening of asphalt. This negative impact of asphalt oxidation on pavement performance has not been considered adequately in pavement design. Part of the reason is that the process of asphalt oxidation in pavement is not well understood. This work focused on understanding the asphalt oxidation kinetics and on developing pavement oxidation model that predicts asphalt oxidation and hardening in pavement under environmental conditions. A number of asphalts were studied in laboratory condition. Based on kinetics data, a fast-rate ? constant-rate asphalt oxidation kinetics model was developed to describe the early nonlinear fast-rate aging period and the later constant-rate period of asphalt oxidation. Furthermore, reaction kinetics parameters for the fast-rate and constant-rate reactions were empirically correlated, leading to a simplified model. And the experimental effort and time to obtain these kinetics parameters were significantly reduced. Furthermore, to investigate the mechanism of asphalt oxidation, two antioxidants were studied on their effectiveness. Asphalt oxidation was not significantly affected. It was found that evaluation of antioxidant effectiveness based on viscosity only is not reliable. The asphalt oxidation kinetics model was incorporated into the pavement oxidation model that predicts asphalt oxidation in pavement. The pavement oxidation model mimics the oxidation process of asphalt in real mixture at pavement temperatures. A new parameter, diffusion depth, defined the oxygen diffusion region in the mastic. A field calibration factor accounted for the factors not considered in the model such as the effect of small aggregate particles on oxygen diffusion. Carbonyl area and viscosity of binders recovered from field cores of three pavements in Texas were measured and were used for model calibration and validation. Results demonstrated that the proposed model estimates carbonyl growth over time in pavement, layer-by-layer, quite well. Finally, this work can be useful for incorporating asphalt oxidation into a pavement design method that can predict pavement performance with time and for making strategic decisions such as optimal time for maintenance treatments.

Jin, Xin

2012-05-01T23:59:59.000Z

117

Analysis on kinetic chemotaxis models using a functional analytic approach Analysis on kinetic chemotaxis models using a  

E-Print Network (OSTI)

that are applicable at the molecular level. Copyright # 2004 John Wiley & Sons, Ltd. KEYWORDS: kinetic stability of that system are undergoing constant change. This chemical example of replicator kinetic stability is akin in circumstance may dramatically affect the kinetic stability of physical, chemical and biological, systems. So

Hille, Sander

118

React. Kinet.Catal.Lett., Vol.9, No. 4,377-381 (1978) WHAT IS ESSENTIAL TO EXOTIC KINETIC BEHAVIOR?  

E-Print Network (OSTI)

6= 10'. I = 1 I=I 378 #12;TOTH: EXOTIC KINETIC BEHAVIOR? COROLLARIES Immediate application). REFERENCES 1. M. Feinberg: Mathamatical Aspects of Mass Action Kinetics. Chapter 1 of Chemical Reactor Theory-London-New York 1972. 3. J. T6th, P. ~rdi: Models, Problems and Applications of Formal Reaction Kinetics (in

Tóth, János

119

Kinetic and hydrodynamic models of chemotactic aggregation  

E-Print Network (OSTI)

We derive general kinetic and hydrodynamic models of chemotactic aggregation that describe certain features of the morphogenesis of biological colonies (like bacteria, amoebae, endothelial cells or social insects). Starting from a stochastic model defined in terms of N coupled Langevin equations, we derive a nonlinear mean field Fokker-Planck equation governing the evolution of the distribution function of the system in phase space. By taking the successive moments of this kinetic equation and using a local thermodynamic equilibrium condition, we derive a set of hydrodynamic equations involving a damping term. In the limit of small frictions, we obtain a hyperbolic model describing the formation of network patterns (filaments) and in the limit of strong frictions we obtain a parabolic model which is a generalization of the standard Keller-Segel model describing the formation of clusters (clumps). Our approach connects and generalizes several models introduced in the chemotactic literature. We discuss the anal...

Chavanis, Pierre-Henri

2007-01-01T23:59:59.000Z

120

Auxiliary power supply with kinetic energy storage  

SciTech Connect

Alternating current is supplied to an auxiliary load on a from a power supply comprised of a dc-energized inverter and a synchronous machine coupled to the inverter. The inverter supplies the alternating current requirements of the load up to the normal steady state load current magnitude. The synchronous machine stores kinetic energy when the load current load does not exceed its normal steady state magnitude, and converts kinetic energy into electrical energy to supply the load current requirements in excess of its normal steady-state load magnitude and to supply load current whenever the dc source inverter connection is interrupted. Frequency and amplitude of load voltage are regulated by operator commands through control apparatus coupled to the inverter and the synchronous machine.

Plunkett, A.B.; Turnbull, F.G.

1982-03-23T23:59:59.000Z

Note: This page contains sample records for the topic "kinetic en ergy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

ET Kinetics of Bifunctional Redox Protein Maquettes  

NLE Websites -- All DOE Office Websites (Extended Search)

Kinetics of Bifunctional Redox Protein Maquettes Kinetics of Bifunctional Redox Protein Maquettes Mitchell W. Mutz, James F. Wishart and George L. McLendon Adv. Chem Ser. 254, Ch. 10, pp. 145-159 Abstract: We prepared three bifunctional redox protein maquettes based on 12-, 16-, and 20-mer three-helix bundles. In each case, the helix was capped with a Co(III) tris-bipyridyl electron acceptor and also functionalized with a C-terminal viologen (1-ethyl-1'-ethyl-4,4'-bipyridinium) donor. Electron transfer (ET) was initiated by pulse radiolysis and flash photolysis and followed spectrometrically to determined average, concentration-independent, first-order rates for the 16-mer and 20-mer maquettes. For the 16-mer bundle, the alpha-helical content was adjusted by the addition of urea or trifluoroethanol to solutions containing the metalloprotein. This

122

MEASUREMENTS, ERRORS, AND NEGATIVE KINETIC ENERGY  

E-Print Network (OSTI)

An analysis of errors in measurement yields new insight into the penetration of quantum particles into classically forbidden regions. In addition to physical values, realistic measurements yield unphysical values which, we show, can form a consistent pattern. An experiment to isolate a particle in a classically forbidden region obtains negative values for its kinetic energy. These values realize the concept of a weak value, discussed in previous works. 0

Yakir Aharonov; Sandu Popescu; Daniel Rohrlich; Lev Vaidman

1993-01-01T23:59:59.000Z

123

Chemical kinetics models for semiconductor processing  

SciTech Connect

Chemical reactions in the gas-phase and on surfaces are important in the deposition and etching of materials for microelectronic applications. A general software framework for describing homogeneous and heterogeneous reaction kinetics utilizing the Chemkin suite of codes is presented. Experimental, theoretical and modeling approaches to developing chemical reaction mechanisms are discussed. A number of TCAD application modules for simulating the chemically reacting flow in deposition and etching reactors have been developed and are also described.

Coltrin, M.E.; Creighton, J.R. [Sandia National Labs., Albuquerque, NM (United States); Meeks, E.; Grcar, J.F.; Houf, W.G. [Sandia National Labs., Livermore, CA (United States); Kee, R.J. [Colorado School of Mines, Golden, CO (United States)

1997-12-31T23:59:59.000Z

124

Rhodopsin kinetics in the cat retina  

SciTech Connect

The bleaching and regeneration of rhodopsin in the living cat retina was studied by means of fundus reflectometry. Bleaching was effected by continuous light exposures of 1 min or 20 min, and the changes in retinal absorbance were measured at 29 wavelengths. For all of the conditions studied (fractional bleaches of from 65 to 100%), the regeneration of rhodopsin to its prebleach levels required greater than 60 min in darkness. After the 1-min exposures, the difference spectra recorded during the first 10 min of dark adaptation were dominated by photoproduct absorption, and rhodopsin regeneration kinetics were obscured by these intermediate processes. Extending the bleaching duration to 20 min gave the products of photolysis an opportunity to dissipate, and it was possible to follow the regenerative process over its full time-course. It was not possible, however, to fit these data with the simple exponential function predicted by first-order reaction kinetics. Other possible mechanisms were considered and are presented in the text. Nevertheless, the kinetics of regeneration compared favorably with the temporal changes in log sensitivity determined electrophysiologically by other investigators. Based on the bleaching curve for cat rhodopsin, the photosensitivity was determined and found to approximate closely the value obtained for human rhodopsin; i.e., the energy Ec required to bleach 1-e-1 of the available rhodopsin was 7.09 log scotopic troland-seconds (corrected for the optics of the cat eye), as compared with approximately 7.0 in man.

Ripps, H.; Mehaffey, L.; Siegel, I.M.

1981-03-01T23:59:59.000Z

125

Inertial range turbulence in kinetic plasmas  

E-Print Network (OSTI)

The transfer of turbulent energy through an inertial range from the driving scale to dissipative scales in a kinetic plasma followed by the conversion of this energy into heat is a fundamental plasma physics process. A theoretical foundation for the study of this process is constructed, but the details of the kinetic cascade are not well understood. Several important properties are identified: (a) the conservation of a generalized energy by the cascade; (b) the need for collisions to increase entropy and realize irreversible plasma heating; and (c) the key role played by the entropy cascade--a dual cascade of energy to small scales in both physical and velocity space--to convert ultimately the turbulent energy into heat. A strategy for nonlinear numerical simulations of kinetic turbulence is outlined. Initial numerical results are consistent with the operation of the entropy cascade. Inertial range turbulence arises in a broad range of space and astrophysical plasmas and may play an important role in the ther...

Howes, G G

2007-01-01T23:59:59.000Z

126

Inertial range turbulence in kinetic plasmas  

E-Print Network (OSTI)

The transfer of turbulent energy through an inertial range from the driving scale to dissipative scales in a kinetic plasma followed by the conversion of this energy into heat is a fundamental plasma physics process. A theoretical foundation for the study of this process is constructed, but the details of the kinetic cascade are not well understood. Several important properties are identified: (a) the conservation of a generalized energy by the cascade; (b) the need for collisions to increase entropy and realize irreversible plasma heating; and (c) the key role played by the entropy cascade--a dual cascade of energy to small scales in both physical and velocity space--to convert ultimately the turbulent energy into heat. A strategy for nonlinear numerical simulations of kinetic turbulence is outlined. Initial numerical results are consistent with the operation of the entropy cascade. Inertial range turbulence arises in a broad range of space and astrophysical plasmas and may play an important role in the thermalization of fusion energy in burning plasmas.

G. G. Howes

2007-11-27T23:59:59.000Z

127

Energy Conservation Tests of a Coupled Kinetic-kinetic Plasma-neutral Transport Code  

SciTech Connect

A Monte Carlo neutral transport routine, based on DEGAS2, has been coupled to the guiding center ion-electron-neutral neoclassical PIC code XGC0 to provide a realistic treatment of neutral atoms and molecules in the tokamak edge plasma. The DEGAS2 routine allows detailed atomic physics and plasma-material interaction processes to be incorporated into these simulations. The spatial pro le of the neutral particle source used in the DEGAS2 routine is determined from the uxes of XGC0 ions to the material surfaces. The kinetic-kinetic plasma-neutral transport capability is demonstrated with example pedestal fueling simulations.

D.P. Stotler, C.S. Chang, S.H. Ku, J. Lang and G. Park

2012-08-29T23:59:59.000Z

128

Pedestal Fueling Simulations with a Coupled Kinetic-kinetic Plasma-neutral Transport Code  

Science Conference Proceedings (OSTI)

A Monte Carlo neutral transport routine, based on DEGAS2, has been coupled to the guiding center ion-electron-neutral neoclassical PIC code XGC0 to provide a realistic treatment of neutral atoms and molecules in the tokamak edge plasma. The DEGAS2 routine allows detailed atomic physics and plasma-material interaction processes to be incorporated into these simulations. The spatial pro le of the neutral particle source used in the DEGAS2 routine is determined from the uxes of XGC0 ions to the material surfaces. The kinetic-kinetic plasma-neutral transport capability is demonstrated with example pedestal fueling simulations.

D.P. Stotler, C.S. Chang, S.H. Ku, J. Lang and G.Y. Park

2012-08-29T23:59:59.000Z

129

Kinetics of Anionic Surfactant Anoxic Degradation  

E-Print Network (OSTI)

The biodegradation kinetics of Geropon TC-42 (trademark) by an acclimated culture was investigated in anoxic batch reactors to determine biokinetic coefficients to be implemented in two biofilm mathematical models. Geropon TC-42 (trademark) is the surfactant commonly used in space habitation. The two biofilm models differ in that one assumes a constant biofilm density and the other allows biofilm density changes based on space occupancy theory. Extant kinetic analysis of a mixed microbial culture using Geropon TC-42 (trademark) as sole carbon source was used to determine cell yield, specific growth rate, and the half-saturation constant for S0/X0 ratios of 4, 12.5, and 34.5. To estimate cell yield, linear regression analysis was performed on data obtained from three sets of simultaneous batch experiments for three S0/X0 ratios. The regressions showed non-zero intercepts, suggesting that cell multiplication is not possible at low substrate concentrations. Non-linear least-squares analysis of the integrated equation was used to estimate the specific growth rate and the half-saturation constant. Net specific growth rate dependence on substrate concentration indicates a self-inhibitory effect of Geropon TC-42 (trademark). The flow rate and the ratio of the concentrations of surfactant to nitrate were the factors that most affected the simulations. Higher flow rates resulted in a shorter hydraulic retention time, shorter startup periods, and faster approach to a steady-state biofilm. At steady-state, higher flow resulted in lower surfactant removal. Higher influent surfactant/nitrate concentration ratios caused a longer startup period, supported more surfactant utilization, and biofilm growth. Both models correlate to the empirical data. A model assuming constant biofilm density is computationally simpler and easier to implement. Therefore, a suitable anoxic packed bed reactor for the removal of the surfactant Geropon TC-42 (trademark) can be designed by using the estimated kinetic values and a model assuming constant biofilm density.

Camacho, Julianna G.

2010-05-01T23:59:59.000Z

130

Inflation by purely kinetic coupled gravity  

E-Print Network (OSTI)

We study a purely kinetic coupled scalar-tensor gravity. We use FRW metric and obtain the modified Friedmann equations subject to an effective perfect fluid including energy density $\\rho_{\\phi}=\\rho_{g}+\\rho_{_G}$ and pressure $p_{\\phi}=p_{g}+p_{_G}$, where $(\\rho_{g}, p_{g})$ and $(\\rho_{_G}, p_{_G})$ define the perfect fluids corresponding to the coupling of scalar field dynamics with metric and Einstein tensors, respectively. We find that the inflation can occur in this model provided that $p_{_G}=-\\rho_{_G}$. We define Hubble slow-role parameters and find that the Hubble slow-role regime means $\\rho_{_{g}}\\ll\\rho_{_{G}}$. It turns out that the energy is not conserved for the scalar field and its kinetic energy is growing exponentially during inflation. It is proposed that this energy may be supplied by the quantum fluctuations of vacuum. This rapid transfer of energy density from vacuum to the scalar field may solve the cosmological constant problem. When $\\rho_{_{g}}$ becomes sufficiently large, the Hubble parameter starts decreasing and $\\rho_{_{g}}$ becomes comparable with $\\rho_{_{G}}$, hence the slow-role approximation is violated, and the inflation is ended. The large energy density of the scalar field may be transformed, partly into the matter, and partly into the radiation, and the universe experiences a reheating phase. At late times, the kinetic energy of the scalar field decreases as $a^{-6}$ and the remnant energy density of the scalar field may become a source of dark matter. Also, we study the cosmological perturbations during the inflation and obtain the behaviors of perturbations inside and outside the horizon. These results are in agreement with those obtained in common inflationary scenarios.

F. Darabi; A. Parsiya

2013-12-04T23:59:59.000Z

131

The Hydriding Kinetics of Organic Hydrogen Getters  

DOE Green Energy (OSTI)

The aging of hermetically sealed systems is often accompanied by the gradual production of hydrogen gas that is a result of the decay of environmental gases and the degradation of organic materials. In particular, the oxygen, water, hydrogen ''equilibrium'' is affected by the removal of oxygen due the oxidation of metals and organic materials. This shift of the above ''equilibrium'' towards the formation of hydrogen gas, particularly in crevices, may eventually reach an explosive level of hydrogen gas or degrade metals by hydriding them. The latter process is generally delayed until the oxidizing species are significantly reduced. Organic hydrogen getters introduced by Allied Signal Aerospace Company, Kansas City Division have proven to be a very effective means of preventing hydrogen gas accumulation in sealed containers. These getters are relatively unaffected by air and environmental gases. They can be packaged in a variety of ways to fit particular needs such as porous pellets, fine or coarse [gravel] powder, or loaded into silicone rubber. The hydrogen gettering reactions are extremely irreversible since the hydrogen gas is converted into an organic hydrocarbon. These getters are based on the palladium-catalyzed hydrogenation of triple bonds to double and then single bonds in aromatic aryl compounds. DEB (1,4 bis (phenyl ethynyl) benzene) typically mixed with 25% by weight carbon with palladium (1% by weight of carbon) is one of the newest and best of these organic hydrogen getters. The reaction mechanisms are complex involving solid state reaction with a heterogeneous catalyst leading to the many intermediates, including mixed alkyl and aryl hydrocarbons with the possibilities of many isomers. The reaction kinetics mechanisms are also strongly influenced by the form in which they are packaged. For example, the hydriding rates for pellets and gravel have a strong dependence on reaction extent (i.e., DEB reduction) and a kinetic order in pressure of 0.76. Silicone rubber based DEB getters hydride at a much lower rate, have little dependence on reaction extent, have a higher kinetic order in pressure (0.87), and have a lower activation energy. The kinetics of the reaction as a function of hydrogen pressure, stoichiometry, and temperature for hydrogen and deuterium near ambient temperature (0 to 75 C) for pressures near or below 100 Pa over a wide range (in some cases, the complete) hydrogenation range are presented along with multi-dimensional rate models.

Powell, G. L.

2002-02-11T23:59:59.000Z

132

SPECTRUM OF KINETIC-ALFVEN TURBULENCE  

Science Conference Proceedings (OSTI)

A numerical study of strong kinetic-Alfven turbulence at scales smaller than the ion gyroscale is presented, and a phenomenological model is proposed that argues that magnetic and density fluctuations are concentrated mostly in two-dimensional structures, which leads to their Fourier energy spectra E(k ){proportional_to}k {sup -8/3} , where k is the wavevector component normal to the strong background magnetic field. The results may provide an explanation for recent observations of magnetic and density fluctuations in the solar wind at sub-proton scales.

Boldyrev, Stanislav; Perez, Jean Carlos [Department of Physics, University of Wisconsin, Madison, WI 53706 (United States)

2012-10-20T23:59:59.000Z

133

Spatial redistribution of turbulent and mean kinetic energy  

Science Conference Proceedings (OSTI)

The turbulent spatial redistribution of turbulent and mean kinetic energy and its exchange is investigated in the framework of an K-{epsilon} model in a magnetized plasma column. The kinetic energy is transferred from the turbulence into the zonal flow around the shear layer. The Reynolds stress profile adjusts to the shear layer, which results in a transport of mean kinetic energy from the region around the shear layer into the shear layer.

Manz, P.; Xu, M.; Fedorczak, N.; Thakur, S. C.; Tynan, G. R. [Center for Momentum Transport and Flow Organization,University of California at San Diego, San Diego, California 92093 (United States); Center for Energy Research, University of California at San Diego, San Diego, California 92093 (United States)

2012-01-15T23:59:59.000Z

134

PBXN-9 Ignition Kinetics and Deflagration Rates  

SciTech Connect

The ignition kinetics and deflagration rates of PBXN-9 were measured using specially designed instruments at LLNL and compared with previous work on similar HMX based materials. Ignition kinetics were measured based on the One Dimensional Time-to-Explosion combined with ALE3D modeling. Results of these experiments indicate that PBXN-9 behaves much like other HMX based materials (i.e. LX-04, LX-07, LX-10 and PBX-9501) and the dominant factor in these experiments is the type of explosive, not the type of binder/plasticizer. In contrast, the deflagration behavior of PBXN-9 is quite different from similar high weight percent HMX based materials (i.e LX-10, LX-07 and PBX-9501). PBXN-9 burns in a laminar manner over the full pressure range studied (0-310 MPa) unlike LX-10, LX-07, and PBX-9501. The difference in deflagration behavior is attributed to the nature of the binder/plasticizer alone or in conjunction with the volume of binder present in PBXN-9.

Glascoe, E; Maienschein, J; Burnham, A; Koerner, J; Hsu, P; Wemhoff, A

2008-04-24T23:59:59.000Z

135

Kinetics of zeolite dealumination in steam  

DOE Green Energy (OSTI)

Zeolite dealumination is a well known phenomenon that contributes to the deactivation or activation of catalysts in several different applications. The most obvious effect is in acid catalysis where dealumination under reaction conditions removes the Broensted sites, thus deactivating the catalyst. The authors are interested in the use of cation exchanged zeolites as selective reduction catalysts for removal of NO{sub x} from exhaust streams, particularly from automotive exhaust. In this case, copper exchanged ZSM-5 has been shown to be an effective catalyst for the generic reaction of NO{sub x} with hydrocarbons. However, high temperature and steam in combustion exhaust causes dealumination and consequent migration of copper out of the zeolite structure resulting in rapid deactivation of the catalyst. Dealumination of zeolites has been reported by many authors in uncountable papers and cannot be reviewed here. However, to the authors` knowledge there are no reports on the kinetics of dealumination under varying conditions of temperature and steam. By measuring the kinetics of dealumination with different zeolites and exchange cations they expect to develop working models of the dealumination process that will allow control of zeolite deactivation. This manuscript is a description of the basic techniques used and a progress report on the very beginning of this study.

Hughes, C.D.; Labouriau, A.; Crawford, S.N.; Romero, R.; Quirin, J.; Earl, W.L.

1998-08-01T23:59:59.000Z

136

Direct Kinetic Measurements of a Criegee Intermediate  

NLE Websites -- All DOE Office Websites (Extended Search)

Direct Kinetic Measurements of a Criegee Intermediate Print Direct Kinetic Measurements of a Criegee Intermediate Print In the earth's troposphere, which blankets the planet surface where we live and breathe, dust particles, gas molecules, water vapor, and sunlight provide the ingredients for a multitude of chemical reactions that can generate effects ranging from clouds and smog to acid rain and climate change. In 1949, chemist Rudolf Criegee proposed a novel chemical pathway for one such reaction, known as ozonolysis: the destruction of alkenes (a type of hydrocarbon), via reaction with ozone, a key pollutant in the troposphere. Although there has been much indirect evidence supporting Criegee's mechanism, breakthrough research done at the ALS by chemists from Sandia National Laboratories, the University of Manchester, and Bristol University has for the first time directly measured reaction rates for so-called "Criegee intermediates," elusive molecules formed at intermediate stages of ozonolysis. The surprising results may have important implications for subjects ranging from advanced engine design to air quality and climate modeling.

137

Thermo -Dynamic & -Kinetic Modeling to Quantify the Evolution of ...  

Science Conference Proceedings (OSTI)

The thermo-kinetic model is applied on various chemical compositions of type ... Application of the Phase-Field Model to Four-Phase Reactions in Ternary Alloys.

138

Kinetic Simulations of Fusion Energy Dynamics at the Extreme...  

NLE Websites -- All DOE Office Websites (Extended Search)

Kinetic Simulations of Fusion Energy Dynamics at the Extreme Scale PI Name: William Tang PI Email: tang@pppl.gov Institution: Princeton Plasma Physics Laboratory Allocation...

139

An Integrated CALPHAD Tool for Modeling Precipitation Kinetics ...  

Science Conference Proceedings (OSTI)

Presentation Title, An Integrated CALPHAD Tool for Modeling Precipitation Kinetics and Accelerating Materials Design. Author(s), Qing Chen, Herng-Jeng Jou,...

140

The Thermodynamics and Kinetics of Dissolution of Coarse Particles ...  

Science Conference Proceedings (OSTI)

A model of the kinetics of dissolution of Nb-rich and Nb2C particles in .... The Influence of Specimen Fabrication Method on the Measured Tensile...

Note: This page contains sample records for the topic "kinetic en ergy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Chemical Dynamics, Molecular Energetics, and Kinetics at the Synchrotron  

E-Print Network (OSTI)

novelmeasurementsofchemicaldynamicsforclusters,Chemical Dynamics, Molecular Energetics, and Kinetics at theUniversity of California Chemical Sciences Division,

Leone, Stephen R.

2010-01-01T23:59:59.000Z

142

Dissolution Kinetics of Steelmaking Slag and Its Promotion for the ...  

Science Conference Proceedings (OSTI)

Presentation Title, Dissolution Kinetics of Steelmaking Slag and Its Promotion for the Growth of Algae. Author(s), Chunfang Zi, Kai Huang, Lianyun Liu, Xiaohui...

143

Kinetics of Supercritical Water Reformation of Ethanol to H  

Science Conference Proceedings (OSTI)

Sep 16, 2007 ... Description Kinetics of the supercritical water reformation of ethanol was experimentally studied in a tubular reactor made of Inconel 625 alloy.

144

Kinetic characterization of enhanced lipase activity on oil bodies  

Science Conference Proceedings (OSTI)

reaction kinetics of oil bodies versus oil emulsions as sub- strates for lipolytic ... of hydrolysis for the oil body system was comparatively very low due to a brief...

145

Defect Chemistry and Kinetics of Electrons in Ion Conducting Materials  

Science Conference Proceedings (OSTI)

Presentation Title, Defect Chemistry and Kinetics of Electrons in Ion Conducting Materials Recent Results and Applications. Author(s), Hans D. Wiemhfer.

146

Particle Size Distribution Model for Leaching Kinetics of Alumina  

Science Conference Proceedings (OSTI)

Presentation Title, Particle Size Distribution Model for Leaching Kinetics of Alumina. Author(s), Li Bao, Ting-an Zhang, Weimin Long, Anh V Nguyen, Guozhi Lv,...

147

A Kinetic Monte Carlo Model for Material Aging: Simulations of ...  

Science Conference Proceedings (OSTI)

In this paper, we develop a kinetic Monte Carlo framework aiming at ... A Controlled Stress Energy Minimization Method for Coarse-grained Atomistic Simulation.

148

Thermal Stabilization of Nanocrystalline Grain Size by Kinetic and ...  

Science Conference Proceedings (OSTI)

This talk will review both kinetic and thermodynamic mechanisms and ... Basic Criteria for Formation of Growth Twins in High Stacking Fault Energy Metals.

149

Oxygen Exchange Kinetics on SOFC Cathode Materials: Importance ...  

Science Conference Proceedings (OSTI)

Presentation Title, Oxygen Exchange Kinetics on SOFC Cathode Materials: Importance of Ionic and Electronic Carriers. Author(s), Rotraut Merkle, Lei Wang,

150

Kinetic Modeling of Esterification of Ethylene Glycol with Acetic Acid  

SciTech Connect

The reaction kinetics of the esterification of ethylene glycol with acetic acid in the presence of cation exchange resin has been studied and kinetic models based on empirical and Langmuir approach has been developed. The Langmuir based model involving eight kinetic parameters fits experimental data much better compared to empirical model involving four kinetic parameters. The effect of temperature and catalyst loading on the reaction system has been analyzed. Further, the activation energy and frequency factor of the rate constants for Langmuir based model has been estimated.

Yadav, Vishnu P.; Maity, Sunil K. [Department of Chemical Engineering, Indian Institute of Technology, Hyderabad, Ordnance Factory Estate, Yeddumailiram-502205, Andhra Pradesh (India); Mukherjee, Rudra Palash [Department of Chemical Engineering, National Institute of Technology, Durgapur, Mahatma Gandhi Avenue, Durgapur-713209, West Bengal (India); Bantraj, Kandi [Department of Chemical Engineering, National Institute of Technology, Rourkela-769008, Orissa (India)

2010-10-26T23:59:59.000Z

151

3.205 Thermodynamics and Kinetics of Materials, Fall 2003  

E-Print Network (OSTI)

Laws of thermodynamics applied to materials and materials processes. Solution theory. Equilibrium diagrams. Overview of fluid transport processes. Kinetics of processes that occur in materials, including diffusion, phase ...

Allen, Samuel M.

152

Kinetics, Transport, and Structure in Hard and Soft Materials - TMS  

Science Conference Proceedings (OSTI)

Jul 25, 2007 ... REVIEWED BY: Stephen Rankin, associate professor, University of Kentucky. In his book Kinetics, Transport, and Structure in Hard and Soft...

153

ON THE EMERGENCE OF BIOLOGICAL COMPLEXITY: LIFE AS A KINETIC STATE OF MATTER  

E-Print Network (OSTI)

, whereas for replicating chemical systems selection is effectively kinetic. Building on an extension. Keywords: biological complexification, chemical evolution, kinetic stability, kinetic state of matter that are kinetically more stable. So though all chemical reactions are governed by a combination of kinetic

Pross, Addy

154

Kinetic Energy Systems | Open Energy Information  

Open Energy Info (EERE)

Systems Systems Jump to: navigation, search Name Kinetic Energy Systems Place Ocala, Florida Zip 34476 Sector Hydro Product Designs and develops tidal generators. Has notably patented the KESC Tidal Generator which is based on free flow hydrodynamics. Coordinates 29.187525°, -82.140394° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":29.187525,"lon":-82.140394,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

155

Detailed Kinetic Modeling of Gasoline Surrogate Mixtures  

DOE Green Energy (OSTI)

Real fuels are complex mixtures of thousands of hydrocarbon compounds including linear and branched paraffins, naphthenes, olefins and aromatics. It is generally agreed that their behavior can be effectively reproduced by simpler fuel surrogates containing a limited number of components. In this work, a recently revised version of the kinetic model by the authors is used to analyze the combustion behavior of several components relevant to gasoline surrogate formulation. Particular attention is devoted to linear and branched saturated hydrocarbons (PRF mixtures), olefins (1-hexene) and aromatics (toluene). Model predictions for pure components, binary mixtures and multi-component gasoline surrogates are compared with recent experimental information collected in rapid compression machine, shock tube and jet stirred reactors covering a wide range of conditions pertinent to internal combustion engines. Simulation results are discussed focusing attention on the mixing effects of the fuel components.

Mehl, M; Curran, H J; Pitz, W J; Westbrook, C K

2009-03-09T23:59:59.000Z

156

A Chemical Kinetic Model of Transcriptional Elongation  

E-Print Network (OSTI)

A chemical kinetic model of the elongation dynamics of RNA polymerase along a DNA sequence is introduced. The proposed model governs the discrete movement of the RNA polymerase along a DNA template, with no consideration given to elastic effects. The model's novel concept is a ``look-ahead'' feature, in which nucleotides bind reversibly to the DNA prior to being incorporated covalently into the nascent RNA chain. Results are presented for specific DNA sequences that have been used in single-molecule experiments of the random walk of RNA polymerase along DNA. By replicating the data analysis algorithm from the experimental procedure, the model produces velocity histograms, enabling direct comparison with these published results.

Yujiro Richard Yamada; Charles S. Peskin

2006-03-12T23:59:59.000Z

157

Kinetics driving high-density chlorine plasmas  

Science Conference Proceedings (OSTI)

A simple fluid model was developed in order to investigate the driving kinetics of neutral and charged species in high-density chlorine plasmas. It was found that the dissociation degree of Cl{sub 2} molecules is directly linked to the power balance of the discharge which controls the electron density. The model was also used to identify those reactions that could be neglected in the particle balance of charged species and those that must be included. Our results further indicate that diffusion losses need to be considered up to a pressure that depends on magnetic-field intensity and reactor aspect ratio. Finally, it is shown that the dominant charged carriers are linked to the dissociation level of Cl{sub 2} molecules.

Stafford, L.; Margot, J.; Vidal, F.; Chaker, M.; Giroux, K.; Poirier, J.-S.; Quintal-Leonard, A.; Saussac, J. [Department de physique, Universite de Montreal, Montreal, Quebec (Canada); INRS-Energie, Materiaux et Telecommunications, Varennes, Quebec (Canada); Department de physique, Universite de Montreal, Montreal, Quebec (Canada)

2005-09-15T23:59:59.000Z

158

Spectroscopy, Kinetics, and Dynamics of Combustion Radicals  

SciTech Connect

Spectroscopy, kinetics and dynamics of jet cooled hydrocarbon transients relevant to the DOE combustion mission have been explored, exploiting i) high resolution IR lasers, ii) slit discharge sources for formation of jet cooled radicals, and iii) high sensitivity detection with direct laser absorption methods and near the quantum shot noise limit. What makes this combination powerful is that such transients can be made under high concentrations and pressures characteristic of actual combustion conditions, and yet with the resulting species rapidly cooled (T ?10-15K) in the slit supersonic expansion. Combined with the power of IR laser absorption methods, this provides novel access to spectral detection and study of many critical combustion species.

Nesbitt, David J. [Research/Professor

2013-08-06T23:59:59.000Z

159

Extracting biochemical reaction kinetics from time series data  

E-Print Network (OSTI)

Abstract. We consider the problem of inferring kinetic mechanisms for biochemical reactions from time series data. Using a priori knowledge about the structure of chemical reaction kinetics we develop global nonlinear models which use elementary reactions as a basis set, and discuss model construction using top-down and bottom-up approaches. 1

Edmund J. Crampin; Patrick E. Mcsharry; Santiago Schnell

2004-01-01T23:59:59.000Z

160

Computing realizations of reaction kinetic networks with given properties  

E-Print Network (OSTI)

engineering­chemical kinetics, chemical thermodynamics, and fluid mechanics­are developed in the second CHEME 3900 Chemical Kinetics and Reactor Design CHEME 4320 Chemical Engineering Laboratory CHEME 4620UndergradUate degree Program as a chemical engineer you'll work with chemical change and chemical

Gorban, Alexander N.

Note: This page contains sample records for the topic "kinetic en ergy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Nonlinear adaptive control for bioreactors with unknown kinetics  

Science Conference Proceedings (OSTI)

We consider a control problem for a single bioreaction occurring in a continuous and well-mixed bioreactor, assuming that the bioreaction's kinetics is not represented by a validated model. We develop a nonlinear controller and prove the global asymptotic ... Keywords: Continuous bioprocesses, Nonlinear adaptive control, Unknown kinetics, Wastewater treatment

Ludovic Mailleret; Olivier Bernard; Jean-Philippe Steyer

2004-08-01T23:59:59.000Z

162

Towards cleaner combustion engines through groundbreaking detailed chemical kinetic models  

E-Print Network (OSTI)

Towards cleaner combustion engines through groundbreaking detailed chemical kinetic models of more predictive and more accurate detailed chemical kinetic models for the combustion of fuels that the combustion of liquid fuels will remain the main source of energy for transportation for the next 50 years.1

163

Kinetics of Diuron Adsorption onto Activated Carbon Fiber  

Science Conference Proceedings (OSTI)

A study was conducted on the adsorption kinetics of diuron from aqueous solutions onto activated carbon fiber. The results showed that the formation of hydrogen bonds between diuron and water, and temperature variations may possibly affect the adsorption ... Keywords: activated carbon fiber, diuron adsorption, kinetic models, hydrogen bonds

Jianhua Xu; Yabing Sun; Zhenyu Li; Jingwei Feng

2011-03-01T23:59:59.000Z

164

Pyrolysis kinetics for western and eastern oil shale  

DOE Green Energy (OSTI)

Oil yield and kinetic results are reviewed for Western (Colorado Mahogany zone) and Eastern (Sunbury and Ohio (Cleveland member)) oil shales for conditions ranging from those encountered in in-situ processing to those in fluidized-bed retorting. The authors briefly summarize kinetic models for the pyrolysis reactions. Oil yields from Eastern shale are much more sensitive to pyrolysis conditions than Western shale.

Burnham, A.K.; Coburn, T.T.; Richardson, J.H.

1982-08-01T23:59:59.000Z

165

Reconciling competing models: a case study of wine fermentation kinetics  

Science Conference Proceedings (OSTI)

Mathematical models of wine fermentation kinetics promise early diagnosis of stuck or sluggish winemaking processes as well as better matching of industrial yeast strains to specific vineyards. The economic impact of these challenges is significant: ... Keywords: combined and refined model, fermentation problems, mechanistic kinetic models, statistical comparison with experimental data, wine fermentation

Rodrigo Assar; Felipe A. Vargas; David J. Sherman

2010-07-01T23:59:59.000Z

166

Solubilty and growth kinetics of silver nitrate in ethanol  

Science Conference Proceedings (OSTI)

The solubility of silver nitrate in ethanol was determined at various temperatures. The growth kinetics of silver nitrate in ethanol were then determined using initial derivaties of temperature and desupersaturation in a mixed-batch crystallizer. For ... Keywords: ethanol, growth kinetics, initial derivatives, silver nitrate, solubility

M. Manteghian; A. Ebrahimi

2002-08-01T23:59:59.000Z

167

Computational Energy Sciences Program  

NLE Websites -- All DOE Office Websites (Extended Search)

Computational EnErgy SCiEnCES program Computational EnErgy SCiEnCES program Description Led by the National Energy Technology Laboratory (NETL), the Advanced Research (AR) Computational Energy Sciences (CES) Program provides high-performance computational modeling and simulation resources to the Office of Fossil Energy (FE) and other programs of the U.S. Department of Energy (DOE). These resources are dedicated to speeding development and reducing costs associated with advanced power system design and performance modeling. CES research is focused on developing a set of complex but flexible computational tools that allow more rapid and efficient scale-up of new subsystems, devices, and components, thereby reducing the need for large and expensive demonstration-scale testing of integrated energy systems,

168

Doc...~En.  

Office of Legacy Management (LM)

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169

HIGH PRESSURE COAL COMBUSTON KINETICS PROJECT  

SciTech Connect

As part of the U.S. Department of Energy (DoE) initiative to improve the efficiency of coal-fired power plants and reduce the pollution generated by these facilities, DOE has funded the High-Pressure Coal Combustion Kinetics (HPCCK) Projects. A series of laboratory experiments were conducted on selected pulverized coals at elevated pressures with the specific goals to provide new data for pressurized coal combustion that will help extend to high pressure and validate models for burnout, pollutant formation, and generate samples of solid combustion products for analyses to fill crucial gaps in knowledge of char morphology and fly ash formation. Two series of high-pressure coal combustion experiments were performed using SRI's pressurized radiant coal flow reactor. The first series of tests characterized the near burner flame zone (NBFZ). Three coals were tested, two high volatile bituminous (Pittsburgh No.8 and Illinois No.6), and one sub-bituminous (Powder River Basin), at pressures of 1, 2, and 3 MPa (10, 20, and 30 atm). The second series of experiments, which covered high-pressure burnout (HPBO) conditions, utilized a range of substantially longer combustion residence times to produce char burnout levels from 50% to 100%. The same three coals were tested at 1, 2, and 3 MPa, as well as at 0.2 MPa. Tests were also conducted on Pittsburgh No.8 coal in CO2 entrainment gas at 0.2, 1, and 2 MPa to begin establishing a database of experiments relevant to carbon sequestration techniques. The HPBO test series included use of an impactor-type particle sampler to measure the particle size distribution of fly ash produced under complete burnout conditions. The collected data have been interpreted with the help of CFD and detailed kinetics simulation to extend and validate devolatilization, char combustion and pollutant model at elevated pressure. A global NOX production sub-model has been proposed. The submodel reproduces the performance of the detailed chemical reaction mechanism for the NBFZ tests.

Stefano Orsino

2005-03-30T23:59:59.000Z

170

Hydrogen & Our Energy Future  

NLE Websites -- All DOE Office Websites (Extended Search)

Hydrogen Program Hydrogen Program www.hydrogen.energy.gov Hydrogen & Our Energy Future  | HydrOgEn & Our EnErgy FuturE U.S. Department of Energy Hydrogen Program www.hydrogen.energy.gov u.S. department of Energy |  www.hydrogen.energy.gov Hydrogen & Our Energy Future Contents Introduction ................................................... p.1 Hydrogen - An Overview ................................... p.3 Production ..................................................... p.5 Delivery ....................................................... p.15 Storage ........................................................ p.19 Application and Use ........................................ p.25 Safety, Codes and Standards ............................... p.33

171

State Bioenergy Primer: Information and Resources for States on Issues, Opportunities, and Options for Advancing Bioenergy  

NLE Websites -- All DOE Office Websites (Extended Search)

State State Bioenergy Primer information and resources for States on issues, opportunities, and options for Advancing Bioenergy U.S. EnvironmEntal ProtEction agEncy and national rEnEwablE EnErgy laboratory SEPtEmbEr 15, 2009 TABle of ConTenTS Acknowledgements ________________________________________________________________ iv Key Acronyms and Abbreviations ______________________________________________________ v executive Summary ___________________________________________________ 1 introduction _________________________________________________________ 3 1.1 How the Primer Is Organized ____________________________________________________ 5 1.2 References ____________________________________________________________________ 5 What is Bioenergy? ____________________________________________________

172

Kinetics of the reactions of hydrogen fluoride with calcium oxide  

Science Conference Proceedings (OSTI)

This paper studies the kinetics of interaction of gaseous hydrogen fluoride with calcium oxide at temperatures 300-700 degrees. The experiments were conducted in a laboratory adsorption apparatus modified and adapted for work with corrosive hydrogen fluoride. Calcium oxide samples in granulated form and deposited on gamma-alumina were used in the experiments. Kinetic curves representing variations of the degree of conversion of the solid samples with time are shown. The influence of retardation dure to diffusion was observed in the experiments. The influence of diffusion control on the reaction rate was also observed in a study of the reaction kinetics on supported layers of calcium oxide.

Kossaya, A.M.; Belyakov, B.P.; Kuchma, Z.V.; Sandrozd, M.K.; Vasil'eva, V.G.

1986-08-01T23:59:59.000Z

173

Evidence of critical balance in kinetic Alfven wave turbulence simulations  

Science Conference Proceedings (OSTI)

A numerical simulation of kinetic plasma turbulence is performed to assess the applicability of critical balance to kinetic, dissipation scale turbulence. The analysis is performed in the frequency domain to obviate complications inherent in performing a local analysis of turbulence. A theoretical model of dissipation scale critical balance is constructed and compared to simulation results, and excellent agreement is found. This result constitutes the first evidence of critical balance in a kinetic turbulence simulation and provides evidence of an anisotropic turbulence cascade extending into the dissipation range. We also perform an Eulerian frequency analysis of the simulation data and compare it to the results of a previous study of magnetohydrodynamic turbulence simulations.

TenBarge, J. M.; Howes, G. G. [Department of Physics and Astronomy, University of Iowa, Iowa City, Iowa 52242 (United States)

2012-05-15T23:59:59.000Z

174

[en] ANALYSIS OF AN IN SITU TABULATION STRATEGY OF COMBUSTION CHEMICAL KINETICS.  

E-Print Network (OSTI)

??[pt] A simulao numrica de processos de combusto uma ferramenta cada vez mais utilizada para o projeto, a anlise e a otimizao de turbinas, (more)

ANDREA CRISTINA CARVALHO DOS ANJOS

2012-01-01T23:59:59.000Z

175

Application of Ice Nucleation Kinetics in Orographic Clouds  

Science Conference Proceedings (OSTI)

Ice nucleation by silver iodide-sodium iodide aerosol particles has been characterized in the Colorado State University isothermal cloud chamber using the techniques of chemical kinetics. Two separate mechanisms of condensation-freezing ice ...

Rochelle R. Blumenstein; Robert M. Rauber; Lewis O. Grant; William G. Finnegan

1987-10-01T23:59:59.000Z

176

INFRARED ABSORPTION SPECTROSCOPY AND CHEMICAL KINETICS OF FREE RADICALS  

NLE Websites -- All DOE Office Websites (Extended Search)

mNAL PERFORMANCE REPORT mNAL PERFORMANCE REPORT for INFRARED ABSORPTION SPECTROSCOPY AND CHEMICAL KINETICS OF FREE RADICALS DE-FG05-85ER13439 1-AUG-1985 to 31-JUL-1994 Robert F. Curl and Graham P. Glass Principal Investigators Introduction This research was directed at the detection, monitoring, and study (by infrared absorption spectroscopy) of the chemical kinetic behavior of small free radical species thought to be important intermediates in combustion. The work typically progressed from the detection and analysis of the infrared spectrum of combustion radical to the utilization of the infrared spectrum thus obtained in the investigation of chemical kinetics of the radical species. The methodology employed was infrared kinetic spectroscopy. In this technique the radical is produced by UV flash photolysis using an excimer laser and then

177

An Improved Equilibrium-Kinetics Speciation Algorithm For Redox Reactions  

Open Energy Info (EERE)

Improved Equilibrium-Kinetics Speciation Algorithm For Redox Reactions Improved Equilibrium-Kinetics Speciation Algorithm For Redox Reactions In Variably Saturated Subsurface Flow Systems Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Journal Article: An Improved Equilibrium-Kinetics Speciation Algorithm For Redox Reactions In Variably Saturated Subsurface Flow Systems Details Activities (0) Areas (0) Regions (0) Abstract: Reactive chemical transport occurs in a variety of geochemical environments, and over a broad range of space and time scales. Efficiency of the chemical speciation and water-rock-gas interaction calculations is important for modeling field-scale multidimensional reactive transport problems. An improved efficient model, REACT, for simulating water-rock-gas interaction under equilibrium and kinetic conditions, has been developed.

178

Momentum and Kinetic Energy Budgets of Simulated Supercell Thunderstorms  

Science Conference Proceedings (OSTI)

The results of numerical simulations of severe thunderstorms with rotating updrafts and supercell characteristics are analyzed to determine their sources, sinks, and transports of momentum and kinetic energy. Two simulations are used, one ...

Douglas K. Lilly; Brian F. Jewett

1990-03-01T23:59:59.000Z

179

Development of Novel Density Functionals for Thermochemical Kinetics  

E-Print Network (OSTI)

A new density functional theory (DFT) exchange-correlation functional for the exploration of reaction mechanisms is proposed. This new functional, denoted BMK (Boese-Martin for Kinetics), has an accuracy in the 2 kcal/mol range for transition state barriers but, unlike previous attempts at such a functional, this improved accuracy does not come at the expense of equilibrium properties. This makes it a general-purpose functional whose domain of applicability has been extended to transition states, rather than a specialized functional for kinetics. The improvement in BMK rests on the inclusion of the kinetic energy density together with a large value of the exact exchange mixing coefficient. For this functional, the kinetic energy density appears to correct `back' the excess exact exchange mixing for ground-state properties, possibly simulating variable exchange.

Boese, A D; Martin, Jan M. L.

2004-01-01T23:59:59.000Z

180

Kinetic Monte Carlo simulations of nanocrystalline film deposition  

E-Print Network (OSTI)

A full diffusion kinetic Monte Carlo algorithm is used to model nanocrystalline film deposition, and study the mechanisms of grain nucleation and microstructure formation in such films. The major finding of this work is ...

Ruan, Shiyun

Note: This page contains sample records for the topic "kinetic en ergy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Kinetic modeling and automated optimization in microreactor systems  

E-Print Network (OSTI)

The optimization, kinetic investigation, or scale-up of a reaction often requires significant time and materials. Silicon microreactor systems have been shown advantageous for studying chemical reactions due to their small ...

Moore, Jason Stuart

2013-01-01T23:59:59.000Z

182

Kinetics, Mechanics and Microstructure Changes in Storage Media  

NLE Websites -- All DOE Office Websites (Extended Search)

Program Review Crystal Gateway Marriott, Crystal City, VA May 18, 2006 Kinetics, Mechanics and Microstructure Changes in Storage Media Anter El-Azab Tel: 850-410-6655, E-mail...

183

Turbulence Kinetic Energy Budget Profiles Derived from Doppler Sodar Measurements  

Science Conference Proceedings (OSTI)

Doppler sodar wind measurements made in light wind conditions in September 1979 near a power plant in Turbigo, Italy, are used to derive terms in the turbulence kinetic energy (TKE) budget. Measurements on five days are grouped into two classes: ...

Gary K. Greenhut; Giangiuseppe Mastrantonio

1989-02-01T23:59:59.000Z

184

Reversibility and Non-reversibility in Stochastic Chemical Kinetics  

E-Print Network (OSTI)

Mathematical problems with mean field and local type interaction related to stochastic chemical kinetics,are considered. Our main concern various definitions of reversibility, their corollaries (Boltzmann type equations, fluctuations, Onsager relations, etc.) and emergence of irreversibility.

Malyshev, V A

2011-01-01T23:59:59.000Z

185

Solar wind plasma : kinetic properties and micro-instabilities  

E-Print Network (OSTI)

The kinetic properties of ions in the solar wind plasma are studied. Observations of solar wind +H and +2He by the Faraday Cup instrument component of the Solar Wind Experiment on the Wind spacecraft show that these ions ...

Kasper, Justin Christophe, 1977-

2003-01-01T23:59:59.000Z

186

Kinetic Energy Transfer between Internal Gravity Waves and Turbulence  

Science Conference Proceedings (OSTI)

We describe a reliable method for distinguishing the mean, wave and turbulence fields when internal waves with changing amplitude perturb the turbulent boundary layer. By integrating the component wave and turbulence kinetic energy budgets ...

J. J. Finnigan

1988-02-01T23:59:59.000Z

187

Ducted kinetic Alfven waves in plasma with steep density gradients  

SciTech Connect

Given their high plasma density (n {approx} 10{sup 13} cm{sup -3}), it is theoretically possible to excite Alfven waves in a conventional, moderate length (L {approx} 2 m) helicon plasma source. However, helicon plasmas are decidedly inhomogeneous, having a steep radial density gradient, and typically have a significant background neutral pressure. The inhomogeneity introduces regions of kinetic and inertial Alfven wave propagation. Ion-neutral and electron-neutral collisions alter the Alfven wave dispersion characteristics. Here, we present the measurements of propagating kinetic Alfven waves in helium helicon plasma. The measured wave dispersion is well fit with a kinetic model that includes the effects of ion-neutral damping and that assumes the high density plasma core defines the radial extent of the wave propagation region. The measured wave amplitude versus plasma radius is consistent with the pile up of wave magnetic energy at the boundary between the kinetic and inertial regime regions.

Houshmandyar, Saeid [Solar Observatory Department, Prairie View A and M University, Prairie View, Texas 77446 (United States); Department of Physics, West Virginia University, Morgantown, West Virginia 26506-6315 (United States); Scime, Earl E. [Department of Physics, West Virginia University, Morgantown, West Virginia 26506-6315 (United States)

2011-11-15T23:59:59.000Z

188

The Mesoscale Kinetic Energy Spectrum of a Baroclinic Life Cycle  

Science Conference Proceedings (OSTI)

The atmospheric mesoscale kinetic energy spectrum is investigated through numerical simulations of an idealized baroclinic wave life cycle, from linear instability to mature nonlinear evolution and with high horizontal and vertical resolution (?x ...

Michael L. Waite; Chris Snyder

2009-04-01T23:59:59.000Z

189

Sources of Eddy Kinetic Energy in the Labrador Sea  

Science Conference Proceedings (OSTI)

Experiments with a suite of North Atlantic general circulation models are used to examine the sources of eddy kinetic energy (EKE) in the Labrador Sea. A high-resolution model version (112) quantitatively reproduces the observed signature. A ...

Carsten Eden; Claus Bning

2002-12-01T23:59:59.000Z

190

Determining Turbulent Kinetic Energy Dissipation from Batchelor Curve Fitting  

Science Conference Proceedings (OSTI)

An algorithm is presented for obtaining the rate of turbulent kinetic energy dissipation by fitting the theoretical Batchelor spectrum to the temperature gradient spectrum at high wavenumbers. The algorithm is relatively robust in selecting the ...

David A. Luketina; Jrg Imberger

2001-01-01T23:59:59.000Z

191

Automated generation of kinetic chemical mechanisms using rewriting  

Science Conference Proceedings (OSTI)

Several software systems have been developed recently for the automated generation of combustion reactions kinetic mechanisms using different representations of species and reactions and different generation algorithms. In parallel, several software ...

Olivier Bournez; Guy-Marie Cme; Valrie Conraud; Hlne Kirchner; Liliana Ib?nescu

2003-06-01T23:59:59.000Z

192

Evaluation of the Turbulent Kinetic Energy Dissipation Rate Inside ...  

Science Conference Proceedings (OSTI)

Abstract Inferring the vertical variation of the mean turbulent kinetic energy ..... the times at which a threshold-crossings occurs are defined by the indicator function .... of noise infection and noise intensity, introducing a threshold Tc significantly...

193

Estimates of Kinetic Energy Dissipation under Breaking Waves  

Science Conference Proceedings (OSTI)

The dissipation of kinetic energy at the surface of natural water bodies has important consequences for many Physical and biochemical processes including wave dynamics, gas transfer, mixing of nutrients and pollutants, and photosynthetic ...

E.A. Terray; M.A. Donelan; Y.C. Agrawal; W.M. Drennan; K.K. Kahma; A.J. Williams; P.A. Hwang; S.A. Kitaigorodskii

1996-05-01T23:59:59.000Z

194

The Track Integrated Kinetic Energy of Atlantic Tropical Cyclones  

Science Conference Proceedings (OSTI)

In this paper the concept of track integrated kinetic energy (TIKE) is introduced as a measure of seasonal Atlantic tropical cyclone activity and applied to seasonal variability in the Atlantic. It is similar in concept to the more commonly used ...

V. Misra; S. DiNapoli; M. Powell

2013-07-01T23:59:59.000Z

195

Kinetic model reduction using integer and semi-infinite programming  

E-Print Network (OSTI)

In this work an optimization-based approach to kinetic model reduction was studied with a view to generating reduced-model libaries for reacting-flow simulations. A linear integer formulation of the reaction elimination ...

Bhattacharjee, Binita, 1976-

2004-01-01T23:59:59.000Z

196

Fundamental kinetic modeling of the catalytic reforming process  

Science Conference Proceedings (OSTI)

In this work, a fundamental kinetic model for the catalytic reforming process has been developed. The complex network of elementary steps and molecular reactions occurring in catalytic reforming has been generated through a computer algorithm characterizing ...

Rogelio Sotelo-Boyas / Gilbert F. Froment; Rayford G. Anthony

2005-01-01T23:59:59.000Z

197

LLNL researchers develop first kinetic model of plasma focus...  

NLE Websites -- All DOE Office Websites (Extended Search)

13013device 01302013 LLNL researchers develop first kinetic model of plasma focus device Anne M Stark, LLNL, (925) 422-9799, stark8@llnl.gov Printer-friendly Deuterium ion...

198

ESS 2012 Peer Review - Amber Kinetics Flywheel Energy Storage...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

7700 RPM - Spin testing accelerates rotor to: 530 ms and 11,000 RPM - Rotor stores 10 kWh of kinetic energy @ 11,000 RPM (2x more than design speed) - All testing conducted in...

199

Topobo : a 3-D constructive assembly system with kinetic memory  

E-Print Network (OSTI)

We introduce Topobo, a 3-D constructive assembly system em- bedded with kinetic memory, the ability to record and playback physical motion. Unique among modeling systems is Topobo's coincident physical input and output ...

Raffle, Hayes Solos, 1974-

2004-01-01T23:59:59.000Z

200

Defect aggregation kinetics in calcium fluoride  

Science Conference Proceedings (OSTI)

Defects in solid materials are responsible for many of their most interesting and critical properties. The authors have developed a site-selective laser technique that allows us to monitor the aggregation of rare earth ion defects in solids on the microscopic scale. This excitation absorption laser method enables us to derive kinetic rate information and thermodynamic parameters for the distribution of defects in solids. For doped materials, various types of defects arise when the dopant ions have ionic charges that differ from the charges of host crystal ions. In model systems such as alkaline earth fluorides doped with trivalent rare earth ions, some defect sites consist of a single dopant ion, while others consist of clusters of dopant cations and interstitial anions. Heat treatment of doped samples leads to a distribution of the various types of defect sites that is characteristic of the temperature and length of heat treatment and the total dopant ion concentration. The results from a study of the formation of trivalent europium ion defect aggregates in calcium fluoride indicate that our method successfully monitors changes in individual site concentrations resulting from heat treatment. The results of this study are consistent with the formation of negatively charged dimer and trimer defects in Eu{sup 3+}:CaF{sub 2} crystals from isolated europium ion and (Eu:F{sub i}) single pair defects. In addition, he presents evidence for rapid equilibrium between the isolated ion and the single pair. Other work presented in this thesis includes the development of a high-temperature fluorine oxidation apparatus that was used to convert divalent europium ions to the trivalent state in calcium fluoride single crystals. This apparatus was also used to increase the superconducting {Tc}'s of YBa{sub 2}Cu{sub 3}O{sub 7-x} through modification of copper-oxygen oxidation states.

Cirillo, K.M.

1989-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "kinetic en ergy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Neptunium_Oxide_Precipitation_Kinetics_AJohnsen  

SciTech Connect

We evaluate the proposed NpO{sub 2}{sup +}(aq)-NpO{sub 2}(cr) reduction-precipitation system at elevated temperatures to obtain primary information on the effects of temperature, ionic strength, O{sub 2} and CO{sub 2}. Experiments conducted on unfiltered solutions at 10{sup -4} M NpO{sub 2}{sup +}(aq), neutral pH, and 200 C indicated that solution colloids strongly affect precipitation kinetics. Subsequent experiments on filtered solutions at 200, 212, and 225 C showed consistent and distinctive temperature-dependent behavior at reaction times {le} 800 hours. At longer times, the 200 C experiments showed unexpected dissolution of neptunium solids, but experiments at 212 C and 225 C demonstrated quasi steady-state neptunium concentrations of 3 x 10{sup -6} M and 6 x 10{sup -6} M, respectively. Solids from a representative experiment analyzed by X-ray diffraction were consistent with NpO{sub 2}(cr). A 200 C experiment with a NaCl concentration of 0.05 M showed a dramatic increase in the rate of neptunium loss. A 200 C experiment in an argon atmosphere resulted in nearly complete loss of aqueous neptunium. Previously proposed NpO{sub 2}{sup +}(aq)-NpO{sub 2}(cr) reduction-precipitation mechanisms in the literature specified a 1:1 ratio of neptunium loss and H{sup +} production in solution over time. However, all experiments demonstrated ratios of approximately 0.4 to 0.5. Carbonate equilibria can account for only about 40% of this discrepancy, leaving an unexpected deficit in H+ production that suggests that additional chemical processes are occurring.

Johnsen, A M; Roberts, K E; Prussin, S G

2012-06-08T23:59:59.000Z

202

Kinetic effects on ballooning modes in mirror machines  

SciTech Connect

A general procedure for examining the influence of kinetic effects on the stability of magnetohydrodynamic ballooning modes in mirror machines is presented. In particular, the basic kinetic ballooning mode equation for a nonaxisymmetric, arbitrary beta system with anisotropic pressure is derived. Considering a long-thin equilibrium typical of the tandem mirror, it is shown that this governing eigenmode equation reduces to a simple form independent of wave-particle resonant effects.

Tang, W.M.; Catto, P.J.

1981-07-01T23:59:59.000Z

203

HCCI in a CFR engine: experiments and detailed kinetic modeling  

DOE Green Energy (OSTI)

Single cylinder engine experiments and chemical kinetic modeling have been performed to study the effect of variations in fuel, equivalence ratio, and intake charge temperature on the start of combustion and the heat release rate. Neat propane and a fuel blend of 15% dimethyl-ether in methane have been studied. The results demonstrate the role of these parameters on the start of combustion, efficiency, imep, and emissions. Single zone kinetic modeling results show the trends consistent with the experimental results.

Flowers, D; Aceves, S; Smith, R; Torres, J; Girard, J; Dibble, R

1999-11-05T23:59:59.000Z

204

One-dimensional kinetics modifications for BWR reload methods  

SciTech Connect

Yankee Atomic Electric Company (YAEC) currently uses RETRAN-02 to analyze limiting transients and establish operating minimum critical power ratio (MCPR) limits for Vermont Yankee (VY) boiling water reactor (BWR) reload analysis. The US Nuclear Regulatory Commission-approved analysis methods, used in previous cycles, use the point-kinetics modeling option in RETRAN-02 to represent transient-induced neutronic feedback. RETRAN-02 also contains a one-dimensional (1-D) kinetics neutronic feedback model option that provides a more accurate transient power prediction than the point-kinetics model. In the past few fuel cycles, the thermal or MCPR operating margin at VY has eroded due to increases in fuel cycle length. To offset this decrease, YAEC has developed the capability to use the more accurate 1-D kinetics RETRAN option. This paper reviews the qualification effort for the YAEC BWR methods. This paper also presents a comparison between RETRAN-02 predictions using 1-D and point kinetics for the limiting transient, and demonstrates the typical gain in thermal margin from 1-D kinetics.

Chandola, V.; Robichaud, J.D.

1990-01-01T23:59:59.000Z

205

Phase-field Model for Interstitial Loop Growth Kinetics and Thermodynamic and Kinetic Models of Irradiated Fe-Cr Alloys  

Science Conference Proceedings (OSTI)

Microstructure evolution kinetics in irradiated materials has strongly spatial correlation. For example, void and second phases prefer to nucleate and grow at pre-existing defects such as dislocations, grain boundaries, and cracks. Inhomogeneous microstructure evolution results in inhomogeneity of microstructure and thermo-mechanical properties. Therefore, the simulation capability for predicting three dimensional (3-D) microstructure evolution kinetics and its subsequent impact on material properties and performance is crucial for scientific design of advanced nuclear materials and optimal operation conditions in order to reduce uncertainty in operational and safety margins. Very recently the meso-scale phase-field (PF) method has been used to predict gas bubble evolution, void swelling, void lattice formation and void migration in irradiated materials,. Although most results of phase-field simulations are qualitative due to the lake of accurate thermodynamic and kinetic properties of defects, possible missing of important kinetic properties and processes, and the capability of current codes and computers for large time and length scale modeling, the simulations demonstrate that PF method is a promising simulation tool for predicting 3-D heterogeneous microstructure and property evolution, and providing microstructure evolution kinetics for higher scale level simulations of microstructure and property evolution such as mean field methods. This report consists of two parts. In part I, we will present a new phase-field model for predicting interstitial loop growth kinetics in irradiated materials. The effect of defect (vacancy/interstitial) generation, diffusion and recombination, sink strength, long-range elastic interaction, inhomogeneous and anisotropic mobility on microstructure evolution kinetics is taken into account in the model. The model is used to study the effect of elastic interaction on interstitial loop growth kinetics, the interstitial flux, and sink strength of interstitial loop for interstitials. In part II, we present a generic phase field model and discuss the thermodynamic and kinetic properties in phase-field models including the reaction kinetics of radiation defects and local free energy of irradiated materials. In particular, a two-sublattice thermodynamic model is suggested to describe the local free energy of alloys with irradiated defects. Fe-Cr alloy is taken as an example to explain the required thermodynamic and kinetic properties for quantitative phase-field modeling. Finally the great challenges in phase-field modeling will be discussed.

Li, Yulan; Hu, Shenyang Y.; Sun, Xin; Khaleel, Mohammad A.

2011-06-15T23:59:59.000Z

206

Soliton Kinetic Equations with Non-Kolmogorovian Structure: A New Tool for Biological Modeling?  

E-Print Network (OSTI)

is nonlinear kinetics of a chemical type). Another application is a simple two-qubit system whose evolution-Kolmogorovian aspects of chemical kinetics. Next, we briefly discuss the links between kinetic equations and their Lax equations becomes then especially clear. NON-KOLMOGOROVIAN ASPECTS OF CHEMICAL KINETICS Consider

Aerts, Diederik

207

Visualizing Chemical Compositions and Kinetics of Sol-Gel by Near-Infrared Multispectral Imaging  

E-Print Network (OSTI)

Visualizing Chemical Compositions and Kinetics of Sol-Gel by Near-Infrared Multispectral Imaging in order to determine the presence of any chemical and kinetic inhomogeneity. Unfortunately, to date, NIR to determine the chemical and kinetic inho- mogeneity of sol-gel. Preliminary results on the kinetics of sol

Reid, Scott A.

208

The Impact of Alternative Fuels on Combustion Kinetics  

DOE Green Energy (OSTI)

The research targets the development of detailed kinetic models to quantitatively characterize the impact of alternative fuels on the performance of Navy turbines and diesel engines. Such impacts include kinetic properties such as cetane number, flame speed, and emissions as well as physical properties such as the impact of boiling point distributions on fuel vaporization and mixing. The primary focus will be Fischer-Tropsch liquids made from natural gas, coal or biomass. The models will include both the effects of operation with these alternative fuels as well as blends of these fuels with conventional petroleum-based fuels. The team will develop the requisite kinetic rules for specific reaction types and incorporate these into detailed kinetic mechanisms to predict the combustion performance of neat alternative fuels as well as blends of these fuels with conventional fuels. Reduced kinetic models will be then developed to allow solution of the coupled kinetics/transport problems. This is a collaboration between the Colorado School of Mines (CSM) and the Lawrence Livermore National Laboratory (LLNL). The CSM/LLNL team plans to build on the substantial progress made in recent years in developing accurate detailed chemical mechanisms for the oxidation and pyrolysis of conventional fuels. Particular emphasis will be placed upon reactions of the isoalkanes and the daughter radicals, especially tertiary radicals, formed by abstraction from the isoalkanes. The various components of the program are described. We have been developing the kinetic models for two iso-dodecane molecules, using the same kinetic modeling formalisms that were developed for the gasoline and diesel primary reference fuels. These mechanisms, and the thermochemical and transport coefficient submodels for them, are very close to completion at the time of this report, and we expect them to be available for kinetic simulations early in the coming year. They will provide a basis for prediction and selection of desirable F-T molecules for use in jet engine simulations, where we should be able to predict the ignition, combustion and emissions characteristics of proposed fuel components. These mechanisms include the reactions and chemical species needed to describe high temperature phenomena such as shock tube ignition and flammability behavior, and they will also include low temperature kinetics to describe other ignition phenomena such as compression ignition and knocking. During the past years, our hydrocarbon kinetics modeling group at LLNL has focused a great deal on fuels typical of gasoline and diesel fuel. About 10 years ago, we developed kinetic models for the fuel octane primary reference fuels, n-heptane [1] and iso-octane [2], which have 7 and 8 carbon atoms and are therefore representative of typical gasoline fuels. N-heptane represents the low limit of knock resistance with an octane number of 0, while iso-octane is very knock resistant with an octane number of 100. High knock resistance in iso-octane was attributed largely to the large fraction of primary C-H bonds in the molecule, including 15 of the 18 C-H bonds, and the high bond energy of these primary bonds plays a large role in this knock resistance. In contrast, in the much more ignitable n-heptane, 10 of its 16 C-H bonds are much less strongly bound secondary C-H bonds, leading to its very low octane number. All of these factors, as well as a similarly complex kinetic description of the equally important role of the transition state rings that transfer H atoms within the reacting fuel molecules, were quantified and collected into large kinetic reaction mechanisms that are used by many researchers in the fuel chemistry world.

Pitz, W J; Westbrook, C K

2009-07-30T23:59:59.000Z

209

Kinetic dispersion of Langmuir waves. I. The Langmuir decay instability  

SciTech Connect

We derive a fully kinetic, three-dimensional dispersion relation for Langmuir waves with a focus on the Langmuir decay instability (LDI). The kinetic dispersion is compared to the standard fluid dispersion found with an equation of state (EOS) closure. The EOS closure fails to capture the intricacies of the nonlinear pressure when high frequency electron plasma waves (EPWs) couple to low frequency ion acoustic waves (IAWs). In particular, we find discrepancies in the k{lambda}{sub d} scaling of the LDI growth rate, where k is the wavenumber of the incident EPW and {lambda}{sub d} is the Debye length. As a result, the kinetic dispersion relation for LDI results in instability thresholds that can be in excess of twice those predicted by the fluid theory. Both the fluid and kinetic dispersion relations predict a nonlinear frequency shift due to the beating of the pump and scattered EPWs, but again the k{lambda}{sub d} scaling of these frequency shifts differ. In addition, the kinetic dispersion predicts a nonlinear reduction in the IAW damping from the three-wave interaction.

Palastro, J. P.; Williams, E. A.; Hinkel, D. E.; Divol, L.; Strozzi, D. J. [Lawrence Livermore National Laboratory, Livermore, California 94551 (United States)

2009-09-15T23:59:59.000Z

210

PKS 1018-42: A Powerful Kinetically Dominated Quasar  

E-Print Network (OSTI)

We have identified PKS 1018-42 as a radio galaxy with extraordinarily powerful jets, over twice as powerful as any 3CR source of equal or lesser redshift except for one (3C196). It is perhaps the most intrinsically powerful extragalactic radio source in the, still poorly explored, Southern Hemisphere. PKS 1018-42 belongs to the class of FR II objects that are kinetically dominated, the jet kinetic luminosity, $Q \\sim 6.5 \\times 10^{46}\\mathrm{ergs/s}$ (calculated at 151 MHz), is 3.4 times larger than the total thermal luminosity (IR to X-ray) of the accretion flow, $L_{bol} \\sim 1.9 \\times 10^{46}\\mathrm{ergs/s}$. It is the fourth most kinetically dominated quasar that we could verify from existing radio data. From a review of the literature, we find that kinetically dominated sources such as PKS 1018-42 are rare, and list the 5 most kinetically dominated sources found from our review. Our results for PKS 1018-42 are based on new observations from the Australia Telescope Compact Array.

Brian Punsly; Steven Tingay

2006-02-13T23:59:59.000Z

211

NETL: Mercury Emissions Control Technologies - Bench Scale Kinetics of  

NLE Websites -- All DOE Office Websites (Extended Search)

Bench Scale Kinetics of Mercury Reactions in FGD Liquors Bench Scale Kinetics of Mercury Reactions in FGD Liquors When research into the measurement and control of Hg emissions from coal-fired power plants began in earnest in the early 1990s, it was observed that oxidized mercury can be scrubbed at high efficiency in wet FGD systems, while elemental mercury can not. In many cases, elemental mercury concentrations were observed to increase slightly across wet FGD systems, but this was typically regarded as within the variability of the measurement methods. However, later measurements have shown substantial re-emissions from some FGD systems. The goal of this project is to develop a fundamental understanding of the aqueous chemistry of mercury (Hg) absorbed by wet flue gas desulfurization (FGD) scrubbing liquors. Specifically, the project will determine the chemical reactions that oxidized mercury undergoes once absorbed, the byproducts of those reactions, and reaction kinetics.

212

Amber Kinetics, Inc. Smart Grid Demonstration Project | Open Energy  

Open Energy Info (EERE)

Kinetics, Inc. Smart Grid Demonstration Project Kinetics, Inc. Smart Grid Demonstration Project Jump to: navigation, search Project Lead Amber Kinetics, Inc. Country United States Headquarters Location Fremont, California Recovery Act Funding $4,000,000.00 Total Project Value $10,000,000.00 Coordinates 37.5482697°, -121.9885719° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[]}

213

On kinetic description of electromagnetic processes in a quantum plasma  

E-Print Network (OSTI)

A nonlinear kinetic equation for nonrelativistic quantum plasma with electromagnetic interaction of particles is obtained in the Hartree's mean-field approximation. It is cast in a convenient form of Vlasov-Boltzmann-type equation with "quantum interference integral", that allows for relatively straightforward modification of existing classical Vlasov codes to incorporate quantum effects (quantum statistics and quantum interference of overlapping particles wave functions), without changing the bulk of the codes. Such modification (upgrade) of existing Vlasov codes may provide a direct and effective path to numerical simulations of nonlinear electrostatic and electromagnetic phenomena in quantum plasmas, especially of processes where kinetic effects are important (e.g., modulational interactions and stimulated scattering phenomena involving plasma modes at short wavelengths or high-order kinetic modes, dynamical screening and interaction of charges in quantum plasma, etc.) Moreover, numerical approaches involv...

Tyshetskiy, Y O; Kompaneets, R

2011-01-01T23:59:59.000Z

214

Chemical Kinetic Models for HCCI and Diesel Combustion  

DOE Green Energy (OSTI)

Predictive engine simulation models are needed to make rapid progress towards DOE's goals of increasing combustion engine efficiency and reducing pollutant emissions. These engine simulation models require chemical kinetic submodels to allow the prediction of the effect of fuel composition on engine performance and emissions. Chemical kinetic models for conventional and next-generation transportation fuels need to be developed so that engine simulation tools can predict fuel effects. The objectives are to: (1) Develop detailed chemical kinetic models for fuel components used in surrogate fuels for diesel and HCCI engines; (2) Develop surrogate fuel models to represent real fuels and model low temperature combustion strategies in HCCI and diesel engines that lead to low emissions and high efficiency; and (3) Characterize the role of fuel composition on low temperature combustion modes of advanced combustion engines.

Pitz, W J; Westbrook, C K; Mehl, M; Sarathy, S M

2010-11-15T23:59:59.000Z

215

Kinetic Alfven double layer formed by electron viscosity  

SciTech Connect

The effect of the electron viscosity on the kinetic Alfven solitary wave is investigated. It is found that small electron viscosity changes the electron motion along the magnetic field producing a boundary layer, and thus that in a low beta electron-ion plasma({beta} Much-Less-Than m{sub e}/m{sub i}), an obliquely propagating kinetic solitary Alfven wave can become a double layer. This double layer can exist in the sub-Alfvenic and super-Alfvenic regimes. The length scale of density drop for this double layer is on the order of that of the conventional kinetic solitary Alfven wave, and thus this double layer can accelerate electrons on a very short length scale.

Woo, M. H.; Ryu, C.-M. [Department of Physics, Pohang University of Science and Technology, Pohang 790-784 (Korea, Republic of); Choi, C. R. [Department of Physics, Korea Advanced Institute of Science and Technology, Taejon 305-701 (Korea, Republic of)

2012-07-15T23:59:59.000Z

216

Energy Storage Research and Development 2006 Annual Progress Report  

NLE Websites -- All DOE Office Websites (Extended Search)

EnErgy StoragE rESEarch EnErgy StoragE rESEarch and dEvElopmEnt U.S. Department of Energy Office of FreedomCAR and Vehicle Technologies 1000 Independence Avenue S.W. Washington, D.C. 20585-0121 FY 2006 Progress Report for Energy Storage Research and Development Energy Efficiency and Renewable Energy FreedomCAR and Vehicle Technologies Approved by: David Howell Manager, Energy Storage R&D January 2007 Energy Storage Research and Development FY 2006 Annual Progress Report TABLE OF CONTENTS I. INTRODUCTION ............................................................................................................... 1 I.A FreedomCAR and Vehicle Technologies Program Overview .................................. 1 I.B Energy Storage Research & Development Overview ............................................... 1

217

DOE-EERC Fossil Energy Base Program and Jointly Sponsored Research Program  

NLE Websites -- All DOE Office Websites (Extended Search)

DOE-EERC FOssil EnERgy BasE PROgRam DOE-EERC FOssil EnERgy BasE PROgRam anD JOintly sPOnsORED REsEaRCh PROgRam Description Since 1998, the U.S. Department of Energy (DOE), through the Advanced Research Program of the National Energy Technology Laboratory (NETL), has been providing financial support to the University of North Dakota's Energy and Environmental Research Center (EERC). Within the framework of two cooperative agreements, the EERC performs research, development, and demonstration (RD&D) projects aimed at advancing the deployment of technologies that will improve energy efficiency and environmental performance of fossil energy systems in areas that would otherwise not be adequately addressed by the private sector. Under a Base agreement, the EERC focuses on new concepts for highly efficient,

218

En couleur sur le web www.ens.fr/actualites/  

E-Print Network (OSTI)

partenaires en Europe centrale et orientale. #12;3Juin 2005 de la linguistique à la politique en passant par seulement à la linguistique,mais à une poétique,une éthique,une politi- que enfin avec tous leurs enjeux langue uni- verselle, le rapport entre logique et linguistique,le « tournant linguistique » en

Gutkin, Boris

219

Recent advances in the kinetics of oxygen reduction  

DOE Green Energy (OSTI)

Oxygen reduction is considered an important electrocatalytic reaction; the most notable need remains improvement of the catalytic activity of existing metal electrocatalysts and development of new ones. A review is given of new advances in the understanding of reaction kinetics and improvements of the electrocatalytic properties of some surfaces, with focus on recent studies of relationship of the surface properties to its activity and reaction kinetics. The urgent need is to improve catalytic activity of Pt and synthesize new, possibly non- noble metal catalysts. New experimental techniques for obtaining new level of information include various {ital in situ} spectroscopies and scanning probes, some involving synchrotron radiation. 138 refs, 18 figs, 2 tabs.

Adzic, R.

1996-07-01T23:59:59.000Z

220

Chemical and kinetic equilibrations via radiative parton transport  

E-Print Network (OSTI)

A hot and dense partonic system can be produced in the early stage of a relativistic heavy ion collision. How it equilibrates is important for the extraction of Quark-Gluon Plasma properties. We study the chemical and kinetic equilibrations of the Quark-Gluon Plasma using a radiative transport model. Thermal and Color-Glass-Condensate motivated initial conditions are used. We observe that screened parton interactions always lead to partial pressure isotropization. Different initial pressure anisotropies result in the same asymptotic evolution. Comparison of evolutions with and without radiative processes shows that chemical equilibration interacts with kinetic equilibration and radiative processes can contribute significantly to pressure isotropization.

Bin Zhang; Warner A. Wortman

2011-02-21T23:59:59.000Z

Note: This page contains sample records for the topic "kinetic en ergy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Plasma outflow from a corrugated trap in the kinetic regime  

SciTech Connect

The problem of stationary plasma outflow from an open corrugated trap in the kinetic regime is considered with allowance for pair collisions in the framework of a kinetic equation with the Landau collision integral. The distribution function is studied in the limit of small-scale corrugation and a large mirror ratio. In considering a single corrugation cell, a correction for the distribution function is calculated analytically. An equation describing variations of the distribution function along the system is derived and used to study the problem of plasma outflow into vacuum.

Skovorodin, D. I.; Beklemishev, A. D. [Russian Academy of Sciences, Budker Institute of Nuclear Physics, Siberian Branch (Russian Federation)

2012-03-15T23:59:59.000Z

222

Kinetic energy principle and neoclassical toroidal torque in tokamaks  

Science Conference Proceedings (OSTI)

It is shown that when tokamaks are perturbed, the kinetic energy principle is closely related to the neoclassical toroidal torque by the action invariance of particles. Especially when tokamaks are perturbed from scalar pressure equilibria, the imaginary part of the potential energy in the kinetic energy principle is equivalent to the toroidal torque by the neoclassical toroidal viscosity. A unified description therefore should be made for both physics. It is also shown in this case that the potential energy operator can be self-adjoint and thus the stability calculation can be simplified by minimizing the potential energy.

Park, Jong-Kyu [Princeton Plasma Physics Laboratory, Princeton, New Jersey 08543 (United States)

2011-11-15T23:59:59.000Z

223

Kinetic Energy Principle And Neoclassical Toroidal Torque In Tokamaks  

Science Conference Proceedings (OSTI)

It is shown that when tokamaks are perturbed the kinetic energy principle is closely related to the neoclassical toroidal torque by the action invariance of particles. Especially when tokamaks are perturbed from scalar pressure equilibria, the imaginary part of the potential energy in the kinetic energy principle is equivalent to the toroidal torque by the Neoclassical Toroidal Viscosity (NTV). A unified description therefore should be made for both physics. It is also shown in this case that the potential energy operator can be self-adjoint and thus the stability calculation can be simplified by minimizing the potential energy

Jong-Kyu Park

2011-11-07T23:59:59.000Z

224

Fragmentation of water by ion impact: Kinetic energy release spectra  

SciTech Connect

The fragmentation of isolated water molecules on collision with 450-keV Ar{sup 9+} has been studied using time-of-flight mass spectrometry employing multihit detection. The kinetic energy release spectrum for the dissociation of [H{sub 2}O]{sup 2+ White-Star} into (H{sup White-Star },H{sup +},O{sup +}) fragments has been measured where H{sup White-Star} is a neutral Rydberg hydrogen atom. Ab initio calculations are carried out for the lowest states of [H{sub 2}O]{sup q+} with q=2 and 3 to help interpret the kinetic energy release spectra.

Rajput, Jyoti; Safvan, C. P. [Department of Physics and Astrophysics, University of Delhi, Delhi 110007 (India); Inter-University Accelerator Centre, Aruna Asaf Ali Marg, New Delhi 110067 (India)

2011-11-15T23:59:59.000Z

225

Kinetic description of electron plasma waves with orbital angular momentum  

SciTech Connect

We describe the kinetic theory of electron plasma waves with orbital angular momentum or twisted plasmons. The conditions for a twisted Landau resonance to exist are established, and this concept is introduced for the first time. Expressions for the kinetic dispersion relation and for the electron Landau damping are derived. The particular case of a Maxwellian plasma is examined in detail. The new contributions to wave dispersion and damping due the orbital angular momentum are discussed. It is shown that twisted plasmons can be excited by rotating electron beams.

Mendonca, J. T. [IPFN, Instituto Superior Tecnico, Av. Rovisco Pais 1, 1049-001 Lisboa (Portugal)

2012-11-15T23:59:59.000Z

226

Detailed chemical kinetic modeling of diesel combustion with oxygenated fuels  

DOE Green Energy (OSTI)

The influence of oxygenated hydrocarbons as additives to diesel fuels on ignition, NOx emissions and soot production has been examined using a detailed chemical kinetic reaction mechanism. N-heptane was used as a representative diesel fuel, and methanol, ethanol, dimethyl ether and dimethoxymethane were used as oxygenated fuel additives. It was found that addition of oxygenated hydrocarbons reduced NOx levels and reduced the production of soot precursors. When the overall oxygen content in the fuel reached approximately 25% by mass, production of soot precursors fell effectively to zero, in agreement with experimental studies. The kinetic factors responsible for these observations are discussed.

Pitz, W J; Curran, H J; Fisher, E; Glaude, P A; Marinov, N M; Westbrook, C K

1999-10-28T23:59:59.000Z

227

El comportamiento del mercado de trabajo en Amrica Latina en el contexto de la globalizacin econmica  

E-Print Network (OSTI)

Colombia Chile Per Venezuela a Ocupados correspondientes aColombia, Chile, Per y Venezuela. Conviene hacer unaregistrarse en Chile y en Venezuela, en general, situndose

Ruesga, Santos; Fujii, Gerardo

2006-01-01T23:59:59.000Z

228

METALLIQUES EN MILIEU AQUEUX  

E-Print Network (OSTI)

Interfaces Environnement Marin et pour lattention quil a pu port mon travail en tant que directeur de thse, et cela au cours de ces trois annes. Je tiens galement remercier Catherine Branger, co-directrice de thse, pour son dynamisme et ses comptences scientifiques qui m'ont permis de mener bien cette tude. Je suis reconnaissante la rgion PACA ainsi qu la ville de Toulon, reprsente par son laboratoire dAnalyses, pour le financement de mon travail de thse. Je suis honore que Mme. Camel et Mr. Fontaine aient accept dtre rapporteurs de cette thse et je les en remercie. Je tiens remercier Mr. Bartolomo, initiateur de ce projet, et Mr. Denoyel de participer ma thse en tant que membres du jury.

Spcialit Chimie; Et Physico-chimie; Des Polymeres; Greffage Du; Catechol Pour; Phase Solide Despeces; Julie Bernard; Universits Aix-marseille I; M. L. Fontaine Professeur; Mairie De Toulon Examinateur; Universit Du Sud Toulon

2009-01-01T23:59:59.000Z

229

Task 1: Hydrate Code release, Maintenance and Support  

NLE Websites -- All DOE Office Websites (Extended Search)

DOE Award No.: DE-NT0005666 Microbial Ecological Work on the "Methane in the Arctic Shelf/Slope (MITAS)" Expedition September 15-25, 2009 School of Marine Science and Policy Submitted by: University of Delaware Lewes, Delaware 19958 Principal Investigator: David L. Kirchman Prepared for: United States Department of Energy National En aboratory ergy Technology L October 30, 2009 Office of Fossil Energy TABLE OF CONTENTS EXECUTIVE SUMMARY ................................................................................................. 1

230

From continuum Fokker-Planck models to discrete kinetic models  

E-Print Network (OSTI)

ABSTRACT Two theoretical formalisms are widely used in modeling mechanochemical systems such as protein motors: continuum Fokker-Planck models and discrete kinetic models. Both have advantages and disadvantages. Here we present a finite volume procedure to solve Fokker-Planck equations. The procedure relates the continuum equations to a discrete mechanochemical kinetic model while retaining many of the features of the continuum formulation. The resulting numerical algorithm is a generalization of the algorithm developed previously by Fricks, Wang, and Elston through relaxing the local linearization approximation of the potential functions, and a more accurate treatment of chemical transitions. The new algorithm dramatically reduces the number of numerical cells required for a prescribed accuracy. The kinetic models constructed in this fashion retain some features of the continuum potentials, so that the algorithm provides a systematic and consistent treatment of mechanical-chemical responses such as load-velocity relations, which are difficult to capture with a priori kinetic models. Several numerical examples are given to illustrate the performance of the method.

Jianhua Xing; Hongyun Wang; George Oster

2005-01-01T23:59:59.000Z

231

Kinetic Isotope Effects from Hybrid Classical and Quantum  

E-Print Network (OSTI)

-order perturbation (KP2) is sufficiently accurate for chemical applications.7 We describe an automated, numerical in chemical applications to determine KIEs for chemical reactions, and because of its fast convergenceCHAPTER 5 Kinetic Isotope Effects from Hybrid Classical and Quantum Path Integral Computations

Minnesota, University of

232

Abyssal Eddy Kinetic Energy Levels in the Western North Pacific  

Science Conference Proceedings (OSTI)

An earlier observation of about 50 cm2 s?2 for the maximum abyssal (4000 m depth) eddy kinetic energy (KE) in the western North Pacific along 152E, occurring in the vicinity of the Kuroshio Extension, is now supported by nearly two years of ...

Willeam J. Schmitz Jr.

1984-01-01T23:59:59.000Z

233

Comments on Estimates of Kinetic Energy Dissipation under Breaking Waves  

Science Conference Proceedings (OSTI)

It is noted that the results of recent experiments on the enhancement of turbulent kinetic energy (TKE) dissipation below surface waves can be stated as follows. TKE dissipation is enhanced by a factor 15Hws/z at depths 0.5Hws < z < 20Hws with ...

Gerrit Burgers

1997-10-01T23:59:59.000Z

234

Kinetics of hot-gas desulfurization sorbents for transport reactors  

DOE Green Energy (OSTI)

Hot-gas desulfurization for the integrated gasification combined cycle (IGCC) process has been investigated by many researchers to remove effectively hydrogen sulfide with various metal oxide sorbents at elevated temperatures. Various metal oxide sorbents are formulated with metal oxides such as Fe, Co, Zn, and Ti. Initial reaction kinetics of formulated sorbents with hydrogen sulfide is studied in the presence of various amounts of moisture and hydrogen at various reaction temperatures. The objectives of this research are to study initial reaction kinetics for a sorbent-hydrogen sulfide heterogeneous reaction system, to investigate effects of concentrations of hydrogen sulfide, hydrogen, and moisture on dynamic absorption of H{sub 2}S into sorbents, to understand effects of space time of reaction gas mixtures on initial reaction kinetics of the sorbent-hydrogen sulfide system, and to evaluate effects of temperature and sorbent amounts on dynamic absorption of H{sub 2}S into sorbents. Experimental data on initial reaction kinetics of hydrogen sulfide with metal oxide sorbents were obtained with a 0.83-cm{sup 3} differential reactor. The reactivity of MCRH-67 sorbent and AHI-1 was examined. These sorbents were obtained from the Research Triangle Institute (RTI). The sorbents in the form of 70 {micro}m particles are reacted with 1,000--4,000 ppm hydrogen sulfide at 450--600 C. The range of space time of reaction gas mixtures is 0.03--0.09 s. The range of reaction duration is 4--14,400 s.

K.C. Kwon

2000-01-01T23:59:59.000Z

235

Viscous Dissipation of Turbulence Kinetic Energy in Storms  

Science Conference Proceedings (OSTI)

In this note the magnitude of the viscous dissipation of turbulence kinetic energy in the surface layer of storms is investigated. It is shown that the layer-integrated dissipative heating is a cubic function of the wind speed. The magnitude of ...

Steven Businger; Joost A. Businger

2001-12-01T23:59:59.000Z

236

Simulations of kinetic events at the atomic scale Graeme Henkelman  

E-Print Network (OSTI)

Simulations of kinetic events at the atomic scale Graeme Henkelman UT Austin Al / Al(100) B3I / Si Need to find saddle points on the energy surface Rate of escape through each saddle point region: E (KMC): 1. Find low energy saddle points using a min-mode method. 2. Choose one processes from

237

Overview of nonlinear theory of kinetically driven instabilities  

Science Conference Proceedings (OSTI)

An overview is presented of the theory for the nonlinear behavior of instabilities driven by the resonant wave particle interaction. The approach should be applicable to a wide variety of kinetic systems in magnetic fusion devices and accelerators. Here the authors emphasize application to Alfven were driven instability, and the principles of the theory are used to interpret experimental data.

Berk, H.L.; Breizman, B.N.

1998-09-01T23:59:59.000Z

238

Nano Research Kinetics of Molecular Recognition Mediated Nanoparticle  

E-Print Network (OSTI)

Nano Research Kinetics of Molecular Recognition Mediated Nanoparticle Self-Assembly Chinmay Soman1 the streptavidin-biotin interaction [9] 0078 Nano Res (2009) 2: 78 84 DOI 10.1007/s12274-009-9005-z Research Article #12;79Nano Res (2009) 2: 78 84 are incubated with specific antigens in a physiological buffer

239

Plasmadynamics and ionization kinetics of thermionic energy conversion  

DOE Green Energy (OSTI)

To reduce the plasma arc-drop, thermionic energy conversion is studied with both analytical and numerical tools. Simplifications are made in both the plasmadynamic and ionization-recombination theories. These are applied to a scheme proposed presently using laser irradiation to enhance the ionization kinetics of the thermionic plasma and thereby reduce the arc-drop. It is also predicted that it is possible to generate the required laser light from a thermionic-type cesium plasma. The analysis takes advantage of theoretical simplifications derived for the ionization-recombination kinetics. It is shown that large laser ionization enhancements can occur and that collisional cesium recombination lasing is expected. To complement the kinetic theory, a numerical method is developed to solve the thermionic plasma dynamics. To combine the analysis of ionization-recombination kinetics with the plasma dynamics of thermionic conversion, a finite difference computer program is constructed. It is capable of solving for both unsteady and steady thermionic converter behavior including possible laser ionization enhancement or atomic recombination lasing. A proposal to improve thermionic converter performance using laser radiation is considered. In this proposed scheme, laser radiation impinging on a thermionic plasma enhances the ionization process thereby raising the plasma density and reducing the plasma arc-drop. A source for such radiation may possibly be a cesium recombination laser operating in a different thermionic converter. The possibility of this being an energy efficient process is discussed. (WHK)

Lawless, J.L. Jr.; Lam, S.H.

1982-02-01T23:59:59.000Z

240

Macro and Micro Scale Electromagnetic Kinetic Energy Harvesting Generators  

E-Print Network (OSTI)

This paper is concerned with generators that harvest electrical energy from the kinetic energy present in the sensor nodes environment. These generators have the potential to replace or augment battery power which has a limited lifetime and requires periodic replacement which limits the placement and application of the sensor node.

Beeby, S -P; Torah, R -N; Koukharenko, E; Roberts, S; O'Donnell, T; Roy, S

2007-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "kinetic en ergy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Kinetic analysis of anaerobic fermentation of dry beef cattle manure  

SciTech Connect

Influent total solids levels of 10, 20, 30 and 40% were tested for biogas production at 35/sup 0/C and C/N ratios of 11 and 25. Organic loading rates ranging from 5.0 to 10.6 kg VS m/sup -3/ d/sup -1/ were used and the Contois kinetic model was used to evaluate the data.

Schult, D.D.; Luis, V.

1983-06-01T23:59:59.000Z

242

Seasonal Kinetic Energy Variability of Near-Inertial Motions  

Science Conference Proceedings (OSTI)

Seasonal variability of near-inertial horizontal kinetic energy is examined using observations from a series of McLane Moored Profiler moorings located at 39N, 69W in the western North Atlantic Ocean in combination with a one-dimensional, depth-...

Katherine E. Silverthorne; John M. Toole

2009-04-01T23:59:59.000Z

243

Kinetic ballooning-interchange modes in tandem mirrors  

SciTech Connect

A hybrid fluid-gyrokinetic derivation of the kinetic modifications to the ballooning-interchange eigenmode equation is presented which removes the large and small wave frequency restrictions of Tang and Catto. The derivation employs a long-thin ordering and an eikonal ansatz, but otherwise allows arbitrary asymmetry, beta, pressure anisotropy, and unperturbed parallel and perpendicular electrostatic field.

Lee, X.S.; Catto, P.J.

1981-11-01T23:59:59.000Z

244

Di usive Kinetic Explicit Schemes for Nonlinear Degenerate Parabolic Systems  

E-Print Network (OSTI)

Di#11;usive Kinetic Explicit Schemes for Nonlinear Degenerate Parabolic Systems #3; D. Aregba parabolic systems. These schemes are based on discrete BGK models where both characteristic velocities. Evje and K.H. Karlsen [15] and of M. Espedal and K.H. Karlsen [14]. For the theory of general parabolic

245

Kinetics of Oxygen Reduction in LSM and LSCF  

NLE Websites -- All DOE Office Websites (Extended Search)

1.00E-05 1.00E-04 1.00E-03 1.00E-02 1.00E-01 1.00E+00 -30 -25 -20 -15 -10 -5 0 5 LogpO2atm VA''' VB''' VO** MnB* MnBx MnB' Kinetic Measurements Using Polycrystalline...

246

Detailed chemical kinetic oxidation mechanism for a biodiesel surrogate  

DOE Green Energy (OSTI)

A detailed chemical kinetic mechanism has been developed and used to study the oxidation of methyl decanoate, a surrogate for biodiesel fuels. This model has been built by following the rules established by Curran et al. for the oxidation of n-heptane and it includes all the reactions known to be pertinent to both low and high temperatures. Computed results have been compared with methyl decanoate experiments in an engine and oxidation of rapeseed oil methyl esters in a jet stirred reactor. An important feature of this mechanism is its ability to reproduce the early formation of carbon dioxide that is unique to biofuels and due to the presence of the ester group in the reactant. The model also predicts ignition delay times and OH profiles very close to observed values in shock tube experiments fueled by n-decane. These model capabilities indicate that large n-alkanes can be good surrogates for large methyl esters and biodiesel fuels to predict overall reactivity, but some kinetic details, including early CO2 production from biodiesel fuels, can be predicted only by a detailed kinetic mechanism for a true methyl ester fuel. The present methyl decanoate mechanism provides a realistic kinetic tool for simulation of biodiesel fuels.

Herbinet, O; Pitz, W J; Westbrook, C K

2007-09-17T23:59:59.000Z

247

Detailed chemical kinetic oxidation mechanism for a biodiesel surrogate  

DOE Green Energy (OSTI)

A detailed chemical kinetic mechanism has been developed and used to study the oxidation of methyl decanoate, a surrogate for biodiesel fuels. This model has been built by following the rules established by Curran et al. for the oxidation of n-heptane and it includes all the reactions known to be pertinent to both low and high temperatures. Computed results have been compared with methyl decanoate experiments in an engine and oxidation of rapeseed oil methyl esters in a jet stirred reactor. An important feature of this mechanism is its ability to reproduce the early formation of carbon dioxide that is unique to biofuels and due to the presence of the ester group in the reactant. The model also predicts ignition delay times and OH profiles very close to observed values in shock tube experiments fueled by n-decane. These model capabilities indicate that large n-alkanes can be good surrogates for large methyl esters and biodiesel fuels to predict overall reactivity, but some kinetic details, including early CO{sub 2} production from biodiesel fuels, can be predicted only by a detailed kinetic mechanism for a true methyl ester fuel. The present methyl decanoate mechanism provides a realistic kinetic tool for simulation of biodiesel fuels.

Herbinet, O; Pitz, W J; Westbrook, C K

2007-09-20T23:59:59.000Z

248

Stepping and crowding: statistical kinetics from an exclusion process perspective  

E-Print Network (OSTI)

Motor enzymes are remarkable molecular machines that use the energy derived from the hydrolysis of a nucleoside triphosphate to generate mechanical movement, achieved through different steps that constitute their kinetic cycle. These macromolecules, nowadays investigated with advanced experimental techniques to unveil their molecular mechanisms and the properties of their kinetic cycles, are implicated in many biological processes, ranging from biopolymerisation (RNA polymerases, ribosomes,...) to intracellular transport (motor proteins such as kinesins or dyneins). Although the kinetics of individual motors is well studied on both theoretical and experimental grounds, the repercussions of their stepping cycle on the collective dynamics is still to be understood. Advances in this direction will improve our comprehension of transport process in the natural intracellular medium, where processive motor enzymes might operate in crowded conditions. In this work, we therefore extend the current statistical kinetic analysis to study collective transport phenomena of motors in terms of lattice gas models belonging to the exclusion process class. Via numerical simulations, we show how to interpret and use the randomness calculated from single particle trajectories in crowded conditions. Importantly, we also show that time fluctuations and non-Poissonian behavior are intrinsically related to spatial correlations and the emergence of large, but finite, clusters of co-moving motors. The properties unveiled by our analysis have important biological implications on the collective transport characteristics of processive motor enzymes in crowded conditions.

Luca Ciandrini; M. Carmen Romano; A. Parmeggiani

2013-12-06T23:59:59.000Z

249

Airfoil sampling of a pulsed Laval beam with tunable vacuum ultraviolet (VUV) synchrotron ionization quadrupole mass spectrometry: Application to low--temperature kinetics and product detection  

E-Print Network (OSTI)

flows suitable for kinetic studies of chemical reactions infor a chemical reaction in the available kinetic window ofa complex kinetic behavior. The rate of chemical reactions

Soorkia, Satchin

2012-01-01T23:59:59.000Z

250

Ethylbenzene dehydrogenation into styrene: kinetic modeling and reactor simulation  

E-Print Network (OSTI)

A fundamental kinetic model based upon the Hougen-Watson formalism was derived as a basis not only for a better understanding of the reaction behavior but also for the design and simulation of industrial reactors. Kinetic experiments were carried out using a commercial potassium-promoted iron catalyst in a tubular reactor under atmospheric pressure. Typical reaction conditions were temperature = 620oC, steam to ethylbenzene mole ratio = 11, and partial pressure of N2 diluent = 0.432 bar. Experimental data were obtained for different operating conditions, i.e., temperature, feed molar ratio of steam to ethylbenzene, styrene to ethylbenzene, and hydrogen to ethylbenzene and space time. The effluent of the reactor was analyzed on-line using two GCs. Kinetic experiments for the formation of minor by-products, i.e. phenylacetylene, ?±-methylstyrene, ?²-methylstyrene, etc, were conducted as well. The reaction conditions were: temperature = 600oC ~ 640oC, a molar ratio of steam to ethylbenzene = 6.5, and partial pressure of N2 diluent = 0.43 bar and 0.64 bar. The products were analyzed by off-line GC. The mathematical model developed for the ethylbenzene dehydrogenation consists of nonlinear simultaneous differential equations in multiple dependent variables. The parameters were estimated from the minimization of the multiresponse objective function which was performed by means of the Marquardt algorithm. All the estimated parameters satisfied the statistical tests and physicochemical criteria. The kinetic model yielded an excellent fit of the experimental data. The intrinsic kinetic parameters were used with the heterogeneous fixed bed reactor model which is explicitly accounting for the diffusional limitations inside the porous catalyst. Multi-bed industrial adiabatic reactors with axial flow and radial flow were simulated and the effect of the operating conditions on the reactor performance was investigated. The dynamic equilibrium coke content was calculated using detailed kinetic model for coke formation and gasification, which was coupled to the kinetic model for the main reactions. The calculation of the dynamic equilibrium coke content provided a crucial guideline for the selection of the steam to ethylbenzene ratio leading to optimum operating conditions.

Lee, Won Jae

2005-12-01T23:59:59.000Z

251

Kinetic modelling of molecular hydrogen transport in microporous carbon materials.  

DOE Green Energy (OSTI)

The proposal of kinetic molecular sieving of hydrogen isotopes is explored by employing statistical rate theory methods to describe the kinetics of molecular hydrogen transport in model microporous carbon structures. A Lennard-Jones atom-atom interaction potential is utilized for the description of the interactions between H{sub 2}/D{sub 2} and the carbon framework, while the requisite partition functions describing the thermal flux of molecules through the transition state are calculated quantum mechanically in view of the low temperatures involved in the proposed kinetic molecular sieving application. Predicted kinetic isotope effects for initial passage from the gas phase into the first pore mouth are consistent with expectations from previous modeling studies, namely, that at sufficiently low temperatures and for sufficiently narrow pore mouths D{sub 2} transport is dramatically favored over H{sub 2}. However, in contrast to expectations from previous modeling, the absence of any potential barrier along the minimum energy pathway from the gas phase into the first pore mouth yields a negative temperature dependence in the predicted absolute rate coefficients - implying a negative activation energy. In pursuit of the effective activation barrier, we find that the minimum potential in the cavity is significantly higher than in the pore mouth for nanotube-shaped models, throwing into question the common assumption that passage through the pore mouths should be the rate-determining step. Our results suggest a new mechanism that, depending on the size and shape of the cavity, the thermal activation barrier may lie in the cavity rather than at the pore mouth. As a consequence, design strategies for achieving quantum-mediated kinetic molecular sieving of H{sub 2}/D{sub 2} in a microporous membrane will need, at the very least, to take careful account of cavity shape and size in addition to pore-mouth size in order to ensure that the selective step, namely passage through the pore mouth, is also the rate determining step.

Hankel, M.; Zhang, H.; Nguyen, T. X.; Bhatia, S. K.; Gray, S. K.; Smith, S. C. (Center for Nanoscale Materials); (The Univ. of Queensland)

2011-01-01T23:59:59.000Z

252

Analysis of Lipid OxidationChapter 10 Kinetic Analysis of Lipid Oxidation Data  

Science Conference Proceedings (OSTI)

Analysis of Lipid Oxidation Chapter 10 Kinetic Analysis of Lipid Oxidation Data Methods and Analyses eChapters Methods - Analyses Books Downloadable pdf of Chapter 10 Kinetic Analysis of Lipid Oxidation Data from ...

253

Kinetic Energy Budget during Strong Jet Stream Activity over the Eastern United States  

Science Conference Proceedings (OSTI)

Kinetic energy budgets are computed during a cold air outbreak in association with strong jet stream activity over the eastern United States. The period is characterized by large generation of kinetic energy due to cross-contour flow. Horizontal ...

Henry E. Fuelberg; James R. Scoggins

1980-01-01T23:59:59.000Z

254

Kinetic Energy Budgets of a Subtropical Squall Line Determined from TAMEX Dual-Doppler Measurements  

Science Conference Proceedings (OSTI)

Dual-Doppler data collected during the Taiwan Area Mesoscale Experiment (TAMEX) are used to study the kinetic energy balance of a subtropical squall line over the Taiwan Straits. Values of each term in the kinetic energy budget equation are ...

Yeong-Jer Lin; Hsi Shen; Robert W. Pasken

1991-11-01T23:59:59.000Z

255

Kinetic Modeling of Halogen-Based Plasma Etching of Complex Oxide Films and its Application to Predictive Feature Profile Simulation  

E-Print Network (OSTI)

amounts of kinetic data (such as chemical reaction sets)kinetic parameters related to specific chemical reactionsChemical Engineering by Nathan Philip Marchack ABSTRACT OF THE DISSERTATION Kinetic

Marchack, Nathan

2012-01-01T23:59:59.000Z

256

An Analysis of the Kinetic Energy Budget for Two Extratropical Cyclones: The Vertically Averaged Flow and the Vertical Shear Flow  

Science Conference Proceedings (OSTI)

An analysis of the kinetic energy budget is made for two intensely developing cyclones over North America. The principal kinetic energy source for the first cyclone is the net horizontal transport of kinetic energy across the boundaries of the ...

Jordan C. Alpert

1981-06-01T23:59:59.000Z

257

The Troposphere-to-Stratosphere Transition in Kinetic Energy Spectra and Nonlinear Spectral Fluxes as Seen in ECMWF Analyses  

Science Conference Proceedings (OSTI)

Global horizontal wavenumber kinetic energy spectra and spectral fluxes of rotational kinetic energy and enstrophy are computed for a range of vertical levels using a T799 ECMWF operational analysis. Above 250 hPa, the kinetic energy spectra ...

B. H. Burgess; Andre R. Erler; Theodore G. Shepherd

2013-02-01T23:59:59.000Z

258

Resistive-Glass Drift Tube for Use as a Controlled Kinetic Energy ...  

externally formed ions for spectroscopy and other applications. ... Controlled Kinetic Energy Ion Source for Miniature Ion Trap ... Chemical Sciences Division

259

Exact results for parallel-chain kinetic models of biological transport Anatoly B. Kolomeisky  

E-Print Network (OSTI)

-state models. Thus, the application of phenomenological simple chemical kinetic models20­22,25 which provide ``chemical'' approach is based on a kinetic multistate description of the molecular motor transport.17 or conformations leads to the motion of motor proteins. In the simplest chemical kinetic model see Fig. 1 , a motor

260

Nested stochastic simulation algorithms for chemical kinetic systems with multiple time scales  

E-Print Network (OSTI)

Nested stochastic simulation algorithms for chemical kinetic systems with multiple time scales an efficient numerical algorithm for simulating chemical kinetic systems with multiple time scales. This algo. Our analysis of such multi-scale chemical kinetic systems allows us to identify the slow variables

Van Den Eijnden, Eric

Note: This page contains sample records for the topic "kinetic en ergy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Non-meanfield deterministic limits in chemical reaction kinetics R. E. Lee DeVille  

E-Print Network (OSTI)

Non-meanfield deterministic limits in chemical reaction kinetics R. E. Lee DeVille Courant. An important class of such micro- scopic systems are kinetic Monte Carlo KMC schemes13,14 for chemical is demonstrated for the kinetic Monte Carlo version of the Schnakenberg reaction where we identified a scaling

Van Den Eijnden, Eric

262

Diffusion-limited kinetics of the solutionsolid phase transition of molecular substances  

E-Print Network (OSTI)

of the applicability of this mech- anism to small molecules comes from the unusually narrow grouping of the kinetic) Basic Chemical Kinetics (Wiley, New York). 3. Neilsen, A. E. (1967) in Crystal Growth, ed. Peiser, S Chemical Kinetics (John Wiley and Sons, New York). 14. Zwanzig, R. (2001) Nonequilibrium Statistical

Vekilov, Peter

263

Kinetics of Chromium(III) Oxidation by Manganese(IV) Oxides Using  

E-Print Network (OSTI)

. This represents the first study to determine the chemical kinetics of Cr(III) oxidation on Mn-oxides. The results focusing on the "chemical" kinetics of Cr(III) oxidation on manganese oxides, i.e., the initial rates of Obtaining and Analyzing Kinetic Data. In Rates of Soil Chemical Processes, Sparks, D. L., Suarez, D. L., Eds

Sparks, Donald L.

264

"Kinetics of Chemical Reactions in Environmental Systems: Research Needs and Challenges"  

E-Print Network (OSTI)

-purposeful. Naturally, kinetic factors also affect chemical reactivity, but the influence of those factors is secondary. If a chemical reaction is disallowed thermodynamically, no combination of kinetic factors will enable that reaction to proceed. The bottom line: chemical reactions are governed by both thermodynamic and kinetic

Sparks, Donald L.

265

Nested stochastic simulation algorithm for chemical kinetic systems with disparate rates  

E-Print Network (OSTI)

Nested stochastic simulation algorithm for chemical kinetic systems with disparate rates Weinan Ea online 14 November 2005 An efficient simulation algorithm for chemical kinetic systems with disparate This paper addresses two important issues on stochastic models of chemical kinetic systems with disparate

Van Den Eijnden, Eric

266

Band-trap capture and emission in the generalized kinetic theory of electrons and holes  

E-Print Network (OSTI)

of the applications. These assumptions amount to discard the kinetic equation for phonons, and to replace np The Boltzmann Equation and its Applications (New York: Springer Verlag). [8] Spiga G 1992 On extended kinetic theory with chemical reaction Nonlinear Kinetic Theory and Mathematical Aspects of Hyperbolic Systems ed

Spiga, Giampiero

267

All Kinds of Behavior are Possible in Chemical Kinetics: A Theorem and Its Potential  

E-Print Network (OSTI)

All Kinds of Behavior are Possible in Chemical Kinetics: A Theorem and Its Potential Applications by the equations of chemical kinetics are simple: the process of each chemical reaction, concentrations of some shown to occur in chemical kinetics, it has been not know whether all types of behavior are possible

Ward, Karen

268

All Kinds of Behavior are Possible in Chemical Kinetics: A Theorem and Its Potential  

E-Print Network (OSTI)

All Kinds of Behavior are Possible in Chemical Kinetics: A Theorem and Its Potential Applications by the equations of chemical kinetics are simple: in the course of each chemical reaction, concentrations of some shown to occur in chemical kinetics, it has been not know whether all types of behavior are possible

Kreinovich, Vladik

269

A study on the effect of particle size on coal flotation kinetics using fuzzy logic  

Science Conference Proceedings (OSTI)

This paper investigates the effect of particle size on the flotation kinetics of coal in a batch flotation cell. The relationship between flotation kinetics constant and theoretical flotation recovery with particle size was estimated with nonlinear equations. ... Keywords: Coal, Flotation kinetics, Fuzzy logic, Modeling

Emad Abkhoshk; Mohammad Kor; Bahram Rezai

2010-07-01T23:59:59.000Z

270

Optimization of Parameters of the Chemic Kinetic Model by Improved Genetic Algorithms  

Science Conference Proceedings (OSTI)

Detailed kinetic model is one of the most important basic research items that the chemic synthesis techniques will have been commercialized from laboratory. A great breakthrough has been made in the detailed mechanistic kinetics of the chemic synthesis, ... Keywords: Genetic Algorithm, kinetic model, parameter

Rui-feng Han; Yu-li Yang; Yong-kui Zhang

2009-01-01T23:59:59.000Z

271

Accelerating moderately stiff chemical kinetics in reactive-flow simulations using GPUs  

Science Conference Proceedings (OSTI)

The chemical kinetics ODEs arising from operator-split reactive-flow simulations were solved on GPUs using explicit integration algorithms. Nonstiff chemical kinetics of a hydrogen oxidation mechanism (9 species and 38 irreversible reactions) were computed ... Keywords: CUDA, Chemical kinetics, GPU, Reactive-flow modeling, Stiff chemistry

Kyle E. Niemeyer, Chih-Jen Sung

2014-01-01T23:59:59.000Z

272

Higher-order quadrature-based moment methods for kinetic equations  

Science Conference Proceedings (OSTI)

Kinetic equations containing terms for spatial transport, body forces, and particle-particle collisions occur in many applications (e.g., rarefied gases, dilute granular gases, fluid-particle flows). The direct numerical solution of the kinetic equation ... Keywords: Boltzmann equation, Dilute particle flows, Kinetic equation, Quadrature method of moments, Rarefied gas flows, Velocity distribution function

R. O. Fox

2009-11-01T23:59:59.000Z

273

Parallel implementation of kinetic cellular automata for modeling CO oxidation over Pd(110) surface  

Science Conference Proceedings (OSTI)

For simulating CO catalytic oxidation on platinum-group metals asynchronous cellular automata (CA) with probabilistic transition rules (kinetic CA) are used. Based on the properties of surface kinetic CA has to have a huge cellular arrays and long evolution. ... Keywords: asynchronous mode, block-synchronous mode, catalytic oxidation reaction, kinetic cellular automata, synchronous mode

Valentina Markova; Anastasia Sharifulina

2010-05-01T23:59:59.000Z

274

A unified moving grid gas-kinetic method in Eulerian space for viscous flow computation  

Science Conference Proceedings (OSTI)

Under a generalized coordinate transformation with arbitrary grid velocity, the gas-kinetic BGK equation is reformulated in a moving frame of reference. Then, a unified conservative gas-kinetic scheme is developed for the viscous flow computation in ... Keywords: 65M06, 76P05, 76T05, Gas-kinetic scheme, Moving grid, Navier-Stokes equations, Unified coordinate system

Changqiu Jin; Kun Xu

2007-03-01T23:59:59.000Z

275

Climate Change Action in Arizona  

E-Print Network (OSTI)

requirement, including biogas and biomass electricityen- ergy resources (defined as biogas, biomass, geothermal,

Owens, Steve

2009-01-01T23:59:59.000Z

276

En couleur sur le web www.ens.fr/actualites/  

E-Print Network (OSTI)

département des sciences de l'Antiquité et spécialiste de linguistique grecque,lui succède.CHRISTOPHE DUPRAZ'?cole normale supérieure (ENS) de Paris organise sa troisième ?cole inter- nationale d'automne en linguistique large de la théorie linguistique et de quelques approches en sciences cognitives basées sur des modèles

277

MHK Projects/Ogdensburg Kinetic Energy Project | Open Energy Information  

Open Energy Info (EERE)

Ogdensburg Kinetic Energy Project Ogdensburg Kinetic Energy Project < MHK Projects Jump to: navigation, search << Return to the MHK database homepage Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":5,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"500px","height":"350px","centre":false,"title":"","label":"","icon":"File:Aquamarine-marker.png","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":44.6942,"lon":-75.4863,"alt":0,"address":"","icon":"http:\/\/prod-http-80-800498448.us-east-1.elb.amazonaws.com\/w\/images\/7\/74\/Aquamarine-marker.png","group":"","inlineLabel":"","visitedicon":""}]}

278

Conformational Analysis of ET Kinetics across Oligoproline Peptides  

NLE Websites -- All DOE Office Websites (Extended Search)

Analysis of the Electron-Transfer Kinetics across Analysis of the Electron-Transfer Kinetics across Oligoproline Peptides Using N,N-Dimethyl-1,4-benzenediamine Donors and Pyrene-1-sulfonyl Acceptors Joseph B. Issa, Abdu S. Salameh, Edward W. Castner, Jr., James F. Wishart, and Stephan S. Isied J. Phys. Chem. B 111, 6878-6886 (2007). [Find paper at ACS Publications] or use ACS Articles on Request Abstract: Photoinduced intramolecular charge separation across proline-bridged donor-acceptor complexes of the type Pyr-(Pro)n-DMPD (where Pyr = pyrene-1-sulfonyl and DMPD = N,N-dimethyl-1,4-phenylenediamine) was studied. The steady-state emission spectrum for n = 0, 1, 2, 3 showed an increase in emission intensity with the number of proline residues. Time-dependent emission measured by streak camera showed increasing

279

Stochastic kinetic models: Dynamic independence, modularity and graphs  

E-Print Network (OSTI)

The dynamic properties and independence structure of stochastic kinetic models (SKMs) are analyzed. An SKM is a highly multivariate jump process used to model chemical reaction networks, particularly those in biochemical and cellular systems. We identify SKM subprocesses with the corresponding counting processes and propose a directed, cyclic graph (the kinetic independence graph or KIG) that encodes the local independence structure of their conditional intensities. Given a partition $[A,D,B]$ of the vertices, the graphical separation $A\\perp B|D$ in the undirected KIG has an intuitive chemical interpretation and implies that $A$ is locally independent of $B$ given $A\\cup D$. It is proved that this separation also results in global independence of the internal histories of $A$ and $B$ conditional on a history of the jumps in $D$ which, under conditions we derive, corresponds to the internal history of $D$. The results enable mathematical definition of a modularization of an SKM using its implied dynamics. Gra...

Bowsher, Clive G

2010-01-01T23:59:59.000Z

280

Simulations of Kinetic Events at the Atomic Scale  

NLE Websites -- All DOE Office Websites (Extended Search)

of kinetic events at the atomic scale of kinetic events at the atomic scale Graeme Henkelman UT Austin Al / Al(100) B 3 I / Si Pd / MgO How can we simulate the dynamics of molecular systems over experimental time scales? Objective: To calculate dynamics of a surface over time scales which are much longer than can be calculated with direct classical dynamics. Problem: time scale gap fs ps ns ms ms s mins atomic dynamics thermally activated experimental vibrations simulations reaction dynamics time scales Most interesting transitions are rare 0.5 eV 1000/s events (much slower than vibrations) Simulating a transition for a typical rare event with classical dynamics can require ~10 12 force evaluations Transition state theory A statistical theory for calculating the rate of slow thermal processes

Note: This page contains sample records for the topic "kinetic en ergy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Chemistry Resolved Kinetic Flow Modeling of TATB Based Explosives  

SciTech Connect

Detonation waves in insensitive, TATB based explosives are believed to have multi-time scale regimes. The initial burn rate of such explosives has a sub-microsecond time scale. However, significant late-time slow release in energy is believed to occur due to diffusion limited growth of carbon. In the intermediate time scale concentrations of product species likely change from being in equilibrium to being kinetic rate controlled. They use the thermo-chemical code CHEETAH linked to an ALE hydrodynamics code to model detonations. They term their model chemistry resolved kinetic flow as CHEETAH tracks the time dependent concentrations of individual species in the detonation wave and calculates EOS values based on the concentrations. A HE-validation suite of model simulations compared to experiments at ambient, hot, and cold temperatures has been developed. They present here a new rate model and comparison with experimental data.

Vitello, P A; Fried, L E; Howard, W M; Levesque, G; Souers, P C

2011-07-21T23:59:59.000Z

282

An Independent Derivation of the Oxford Jet Kinetic Luminosity Formula  

E-Print Network (OSTI)

This letter presents a theoretical derivation of an estimate for a radio source jet kinetic luminosity. The expression yields jet powers that are quantitatively similar to a more sophisticated empirical relation published by the Willott, Blundell and Rawlings at Oxford. The formula allows one to estimate the jet kinetic luminosity from the measurement of the optically thin radio lobe emission in quasars and radio galaxies. Motivated by recent X-ray observation, the derivation assumes that most of the energy in the lobes is in plasma thermal energy with a negligible contribution from magnetic energy (not equipartition). The close agreement of the two independent expressions makes the veracity of these estimates seem very plausible.

Brian Punsly

2005-03-11T23:59:59.000Z

283

Active transport: A kinetic description based on thermodynamic grounds  

E-Print Network (OSTI)

We show that active transport processes in biological systems can be understood through a local equilibrium description formulated at the mesoscale, the scale to describe stochastic processes. This new approach uses the method established by nonequilibrium thermodynamics to account for the irreversible processes occurring at this scale and provides nonlinear kinetic equations for the rates in terms of the driving forces. The results show that the application domain of nonequilibrium thermodynamics method to biological systems goes beyond the linear domain. A model for transport of Ca$^{2+}$ by the Ca$^{2+}$-ATPase, coupled to the hydrolysis of adenosine-triphosphate is analyzed in detail showing that it depends on the reaction Gibbs energy in a non-linear way. Our results unify thermodynamic and kinetic descriptions, thereby opening new perspectives in the study of different transport phenomena in biological systems.

S. Kjelstrup; J. M. Rubi; D. Bedeaux

2004-12-17T23:59:59.000Z

284

Propagation of radiation in fluctuating multiscale plasmas. II. Kinetic simulations  

Science Conference Proceedings (OSTI)

A numerical algorithm is developed and tested that implements the kinetic treatment of electromagnetic radiation propagating through plasmas whose properties have small scale fluctuations, which was developed in a companion paper. This method incorporates the effects of refraction, damping, mode structure, and other aspects of large-scale propagation of electromagnetic waves on the distribution function of quanta in position and wave vector, with small-scale effects of nonuniformities, including scattering and mode conversion approximated as causing drift and diffusion in wave vector. Numerical solution of the kinetic equation yields the distribution function of radiation quanta in space, time, and wave vector. Simulations verify the convergence, accuracy, and speed of the methods used to treat each term in the equation. The simulations also illustrate the main physical effects and place the results in a form that can be used in future applications.

Pal Singh, Kunwar; Robinson, P. A.; Cairns, Iver H.; Tyshetskiy, Yu. [School of Physics, University of Sydney, Sydney, NSW 2006 (Australia)

2012-11-15T23:59:59.000Z

285

Propagation of radiation in fluctuating multiscale plasmas. I. Kinetic theory  

SciTech Connect

A theory for propagation of radiation in a large scale plasma with small scale fluctuations is developed using a kinetic description in terms of the probability distribution function of the radiation in space, time, and wavevector space. Large scale effects associated with spatial variations in the plasma density and refractive index of the plasma wave modes and small scale effects such as scattering of radiation by density clumps in fluctuating plasma, spontaneous emission, damping, and mode conversion are included in a multiscale kinetic description of the radiation. Expressions for the Stokes parameters in terms of the probability distribution function of the radiation are used to enable radiation properties such as intensity and polarization to be calculated.

Tyshetskiy, Yu.; Pal Singh, Kunwar; Thirunavukarasu, A.; Robinson, P. A.; Cairns, Iver H. [School of Physics, University of Sydney, NSW 2006 (Australia)

2012-11-15T23:59:59.000Z

286

Unified Fractional Kinetic Equation and a Fractional Diffusion Equation  

E-Print Network (OSTI)

In earlier papers Saxena et al. (2002, 2003) derived the solutions of a number of fractional kinetic equations in terms of generalized Mittag-Leffler functions which extended the work of Haubold and Mathai (2000). The object of the present paper is to investigate the solution of a unified form of fractional kinetic equation in which the free term contains any integrable function f(t), which provides the unification and extension of the results given earlier recently by Saxena et al. (2002, 2003). The solution has been developed in terms of the Wright function in a closed form by the method of Laplace transform. Further we derive a closed-form solution of a fractional diffusion equation. The asymptotic expansion of the derived solution with respect to the space variable is also discussed. The results obtained are in a form suitable for numerical computation.

R. K. Saxena; A. M. Mathai; H. J. Haubold

2004-06-22T23:59:59.000Z

287

COMSOL-based Nuclear Reactor Kinetics Studies at the HFIR  

Science Conference Proceedings (OSTI)

The computational ability to accurately predict the dynamic behavior of a nuclear reactor core in response to reactivity-induced perturbations is an important subject in reactor physics. Space-time and point kinetics methodologies were developed for the purpose of studying the transient-induced behavior of the High Flux Isotope Reactor s (HFIR) compact core. The space-time simulations employed the three-energy-group neutron diffusion equations, and transients initiated by control cylinder and hydraulic tube rabbit ejections were studied. The work presented here is the first step towards creating a comprehensive multiphysics methodology for studying the dynamic behavior of the HFIR core during reactivity perturbations. The results of these studies show that point kinetics is adequate for small perturbations in which the power distribution is assumed to be time-independent, but space-time methods must be utilized to determine localized effects.

Chandler, David [ORNL; Freels, James D [ORNL; Maldonado, G Ivan [ORNL; Primm, Trent [ORNL

2011-01-01T23:59:59.000Z

288

On Kinetic Equations Modeling Evolution of Systems in Mathematical Biology  

E-Print Network (OSTI)

We develop a rigorous formalism for the description of the kinetic evolution of interacting entities modeling systems in mathematical biology within the framework of the evolution of marginal observables. For this purpose we construct the mean field asymptotic behavior of a solution of the Cauchy problem of the dual BBGKY hierarchy for marginal observables of the dynamical systems based on the Markov jump processes, exhibiting the intrinsic properties of the living entities. The constructed scaling limit is governed by the set of recurrence evolution equations, namely by the dual Vlasov-type hierarchy. Moreover, the relationships of the dual Vlasov hierarchy for the limit marginal observables with the Vlasov-type kinetic equation is established.

Yu. Yu. Fedchun; V. I. Gerasimenko

2013-08-21T23:59:59.000Z

289

Hydro-kinetic approach to relativistic heavy ion collisions  

E-Print Network (OSTI)

We develop a combined hydro-kinetic approach which incorporates hydrodynamical expansion of the systems formed in \\textit{A}+\\textit{A} collisions and their dynamical decoupling described by escape probabilities. The method corresponds to a generalized relaxation time ($\\tau_{\\text{rel}}$) approximation for Boltzmann equation applied to inhomogeneous expanding systems; at small $\\tau_{\\text{rel}}$ it also allows one to catch the viscous effects in hadronic component - hadron-resonance gas. We demonstrate how the approximation of sudden freeze-out can be obtained within this dynamical picture of continuous emission and find that hypersurfaces, corresponding to sharp freeze-out limit, are momentum dependent. The pion $m_{T}$ spectra are computed in the developed hydro-kinetic model, and compared with those obtained from ideal hydrodynamics with the Cooper-Frye isothermal prescription. Our results indicate that there does not exist a universal freeze-out temperature for pions with different momenta, and support ...

Akkelin, S V; Karpenko, Iu A; Sinyukov, Yu M

2008-01-01T23:59:59.000Z

290

Kinetic Method for Hydrogen-Deuterium-Tritium Mixture Distillation Simulation  

Science Conference Proceedings (OSTI)

Simulation of hydrogen distillation plants requires mathematical procedures suitable for multicomponent systems. In most of the present-day simulation methods a distillation column is assumed to be composed of theoretical stages, or plates. However, in the case of a multicomponent mixture theoretical plate does not exist.An alternative kinetic method of simulation is depicted in the work. According to this method a system of mass-transfer differential equations is solved numerically. Mass-transfer coefficients are estimated with using experimental results and empirical equations.Developed method allows calculating the steady state of a distillation column as well as its any non-steady state when initial conditions are given. The results for steady states are compared with ones obtained via Thiele-Geddes theoretical stage technique and the necessity of using kinetic method is demonstrated. Examples of a column startup period and periodic distillation simulations are shown as well.

Sazonov, A.B.; Kagramanov, Z.G.; Magomedbekov, E.P. [Mendeleyev University of Chemical Technology of Russia (Russian Federation)

2005-07-15T23:59:59.000Z

291

Esterification kinetics of triglycerides in n-hexane catalyzed by an immobilized lipase  

E-Print Network (OSTI)

The kinetics of enzyme-catalyzed esterification of triglycerides over immobilized lipase in n-hexane was investigated. The reaction kinetics were described in terms of a mechanism developed following the Langmuir-Hinshelwood-Hougen-Watson (LHHW) approach with surface reaction as the rate-controlling step. Sets of data obtained from batch experiments were used to determine the kinetic parameters. A good description of the esterification reaction by the suggested kinetic mechanism was achieved. The reaction was then run in a fixed bed flow reactor and the reactor performance was predicted using the batch reactor kinetics.

Gomez Ruiz, Alejandro

1998-01-01T23:59:59.000Z

292

Dynamic stability of spindles controlled by molecular motor kinetics  

E-Print Network (OSTI)

We analyze the role of the force-dependent kinetics of motor proteins in the stability of antiparallel arrays of polar filaments, such as those in the mitotic spindle. We determine the possible stable structures and show that there exists an instability associated to the collective behavior of motors that leads to the collapse of the spindle. Our analysis provides a general framework to understand several experimental observations in eukaryotic cell division.

Otger Campas; Jaume Casademunt; Ignacio Pagonabarraga

2006-03-30T23:59:59.000Z

293

Domain growth and ordering kinetics in dense quark matter  

Science Conference Proceedings (OSTI)

The kinetics of chiral transitions in quark matter is studied in a two-flavor Nambu-Jona-Lasinio model. We focus on the phase-ordering dynamics subsequent to a temperature quench from the massless quark phase to the massive quark phase. We study the dynamics by considering a phenomenological model (Ginzburg-Landau free-energy functional). The morphology of the ordering system is characterized by the scaling of the order-parameter correlation function.

Singh, A.; Puri, S. [Jawaharlal Nehru University, School of Physical Sciences (India); Mishra, H., E-mail: hm@prl.res.in [Physical Research Laboratory, Theory Division (India)

2012-06-15T23:59:59.000Z

294

Development of Detailed Kinetic Models for Fischer-Tropsch Fuels  

DOE Green Energy (OSTI)

Fischer-Tropsch (FT) fuels can be synthesized from a syngas stream generated by the gasification of biomass. As such they have the potential to be a renewable hydrocarbon fuel with many desirable properties. However, both the chemical and physical properties are somewhat different from the petroleum-based hydrocarbons that they might replace, and it is important to account for such differences when considering using them as replacements for conventional fuels in devices such as diesel engines and gas turbines. FT fuels generally contain iso-alkanes with one or two substituted methyl groups to meet the pour-point specifications. Although models have been developed for smaller branched alkanes such as isooctane, additional efforts are required to properly capture the kinetics of the larger branched alkanes. Recently, Westbrook et al. developed a chemical kinetic model that can be used to represent the entire series of n-alkanes from C{sub 1} to C{sub 16} (Figure 1). In the current work, the model is extended to treat 2,2,4,4,6,8,8-heptamethylnonane (HMN), a large iso-alkane. The same reaction rate rules used in the iso-octane mechanism were incorporated in the HMN mechanism. Both high and low temperature chemistry was included so that the chemical kinetic model would be applicable to advanced internal combustion engines using low temperature combustion strategies. The chemical kinetic model consists of 1114 species and 4468 reactions. Concurrently with this effort, work is underway to improve the details of specific reaction classes in the mechanism, guided by high-level electronic structure calculations. Attention is focused upon development of accurate rate rules for abstraction of the tertiary hydrogens present in branched alkanes and properly accounting for the pressure dependence of the ?-scission, isomerization, and R + O{sub 2} reactions.

Westbrook, C K; Pitz, W J; Carstensen, H; Dean, A M

2008-10-28T23:59:59.000Z

295

Catalyst Screening and Kinetic Studies Using Microchannel Reactors  

SciTech Connect

A multi-parallel microchannel reactor system is described, as related to catalyst screening and discovery for heat-intensive heterogeneous catalytic reactions. Example systems are detailed, in which the rapid heat transfer of the screening device is utilized to maintain isothermal operation in multiple channels for catalyst screening as well as kinetic investigations. The advantages of the system and pertinent results are discussed, specifically for Fischer-Tropsch synthesis, methanol oxidation to formaldehyde, and methanol steam reforming.

Cao, Chunshe; Palo, Daniel R.; Tonkovich, Annalee Y.; Wang, Yong

2007-07-15T23:59:59.000Z

296

Adiabatic trapping in coupled kinetic Alfven-acoustic waves  

SciTech Connect

In the present work, we have discussed the effects of adiabatic trapping of electrons on obliquely propagating Alfven waves in a low {beta} plasma. Using the two potential theory and employing the Sagdeev potential approach, we have investigated the existence of arbitrary amplitude coupled kinetic Alfven-acoustic solitary waves in both the sub and super Alfvenic cases. The results obtained have been analyzed and presented graphically and can be applied to regions of space where the low {beta} assumption holds true.

Shah, H. A.; Ali, Z. [Department of Physics, G.C. University, 54000 Lahore (Pakistan); Masood, W. [COMSATS, Institute of Information Technology, Park Road, Chak Shahzad, Islamabad 44000 (Pakistan); National Centre for Physics (NCP), Shahdara Valley Road, 44000 Islamabad (Pakistan); Theoretical Plasma Physics Division, P. O. Nilore, Islamabad (Pakistan)

2013-03-15T23:59:59.000Z

297

Fundamental diagrams for kinetic equations of traffic flow  

E-Print Network (OSTI)

In this paper we investigate the ability of some recently introduced discrete kinetic models of vehicular traffic to catch, in their large time behavior, typical features of theoretical fundamental diagrams. Specifically, we address the so-called "spatially homogeneous problem" and, in the representative case of an exploratory model, we study the qualitative properties of its solutions for a generic number of discrete microstates. This includes, in particular, asymptotic trends and equilibria, whence fundamental diagrams originate.

Luisa Fermo; Andrea Tosin

2013-05-20T23:59:59.000Z

298

Application of kinetic inductance thermometers to x-ray calorimetry  

SciTech Connect

A kinetic inductance thermometer is applied to x-ray calorimetry, and its operation over a wide range of frequencies and geometries is discussed. Three amplifier configurations are described, one using a superconducting quantum interference device (SQUID) amplifier, another incorporating an FET amplifier in an amplitude modulated system, and the third, using a tunnel diode frequency modulated oscillator circuit. The predicted performance of each configuration is presented. 13 refs., 6 figs., 1 tab.

Wai, Y.C.; Labov, S.E.; Silver, E.H.

1990-08-13T23:59:59.000Z

299

Comparison of kinetic theory models of laser ablation of carbon  

SciTech Connect

The paper compares the predictions of three-dimensional kinetic theory models of laser ablation of carbon. All the models are based on the moment solution of the Boltzmann equation for arbitrary strong evaporation but use different approximations. Comparison of the model predictions demonstrated that the choice of the particular model has very little influence on the results. The influence of the heat conduction from the gas to the solid phase was also found to be negligible in this problem.

Shusser, Michael [Faculty of Mechanical Engineering, Technion, Haifa 32000 (Israel)

2010-05-15T23:59:59.000Z

300

Kinetics of Cd Release from Some Contaminated Calcareous Soils  

SciTech Connect

Contamination of soils with heavy metals may pose long-term risk to groundwater quality leading to health implications. Bioavailability of heavy metals, like cadmium (Cd) is strongly affected by sorption and desorption processes. The release of heavy metals from contaminated soils is a major contamination risks to natural waters. The release of Cd from contaminated soils is strongly influenced by its mobility and bioavailability. In this study, the kinetics of Cd desorption from ten samples of contaminated calcareous soils, with widely varying physicochemical properties, were studied using 0.01 M EDTA extraction. The median percentage of Cd released was about 27.7% of the total extractable Cd in the soils. The release of Cd was characterized by an initial fast release rate (of labile fractions) followed by a slower release rate (of less labile fractions) and a model of two first-order reactions adequately describes the observed release of Cd from the studied soil samples. There was positive correlation between the amount of Cd released at first phase of release and Cd in exchangeable fraction, indicating that this fraction of Cd is the main fraction controlling the Cd in the kinetic experiments. There was strongly negative correlation between the amount of Cd released at first and second phases of release and residual fraction, suggesting that this fraction did not contribute in Cd release in the kinetic experiments. The results can be used to provide information for evaluation of Cd potential toxicity and ecological risk from contaminated calcareous soils.

Sajadi Tabar, S.; Jalali, M., E-mail: jalali@basu.ac.ir [Bu-Ali Sina University, Department of Soil Science, College of Agriculture (Iran, Islamic Republic of)

2013-03-15T23:59:59.000Z

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301

KINETICS OF HOT-GAS DESULFURIZATION SORBENTS FOR TRANSPORT REACTORS  

SciTech Connect

Hot-gas desulfurization for the integrated gasification combined cycle (IGCC) process has been investigated by many researchers to remove effectively hydrogen sulfide with various metal oxide sorbents at elevated temperatures. Various metal oxide sorbents are formulated with metal oxides such as Fe, Co, Zn, and Ti. Initial reaction kinetics of formulated sorbents with hydrogen sulfide is studied in the presence of various amounts of moisture and hydrogen at various reaction temperatures. The objectives of this research are to study initial reaction kinetics for a sorbent-hydrogen sulfide heterogeneous reaction system, to investigate effects of concentrations of hydrogen sulfide, hydrogen, and moisture on dynamic absorption of H{sub 2}S into sorbents, and to evaluate effects of temperature and sorbent amounts on dynamic absorption of H{sub 2}S into sorbents. Experimental data on initial reaction kinetics of hydrogen sulfide with metal oxide sorbents were obtained with a 0.83-cm{sup 3} differential reactor. The reactivity of MCRH-67 was examined in this report. This sorbent was obtained from the Research Triangle Institute (RTI). The sorbent in the form of 130 mm particles are reacted with 18000-ppm hydrogen sulfide at 350-525 C. The range of space time of reaction gas mixtures is 0.069-0.088 s. The range of reaction duration is 4-180 s.

K.C. Kwon

2002-01-01T23:59:59.000Z

302

KINETICS OF HOT-GAS DESULFURIZATION SORBENTS FOR TRANSPORT REACTORS  

DOE Green Energy (OSTI)

Hot-gas desulfurization for the integrated gasification combined cycle (IGCC) process has been investigated by many researchers to remove effectively hydrogen sulfide with various metal oxide sorbents at elevated temperatures. Various metal oxide sorbents are formulated with metal oxides such as Fe, Co, Zn, and Ti. Initial reaction kinetics of formulated sorbents with hydrogen sulfide is studied in the presence of various amounts of moisture and hydrogen at various reaction temperatures. The objectives of this research are to study initial reaction kinetics for a sorbent-hydrogen sulfide heterogeneous reaction system, to investigate effects of concentrations of hydrogen sulfide, hydrogen, and moisture on dynamic absorption of H{sub 2}S into sorbents, and to evaluate effects of temperature and sorbent amounts on dynamic absorption of H{sub 2}S into sorbents. Experimental data on initial reaction kinetics of hydrogen sulfide with metal oxide sorbents were obtained with a 0.83-cm{sup 3} differential reactor. The reactivity of EX-SO3 was examined in this report. This sorbent was obtained from the Research Triangle Institute (RTI). The sorbent in the form of 110 {micro}m particles are reacted with 18000-ppm hydrogen sulfide at 350-550 C. The range of space time of reaction gas mixtures is 0.069-0.088 s. The range of reaction duration is 4-180 s.

K.C. Kwon

2003-02-01T23:59:59.000Z

303

KINETICS OF HOT-GAS DESULFURIZATION SORBENTS FOR TRANSPORT REACTORS  

DOE Green Energy (OSTI)

Hot-gas desulfurization for the integrated gasification combined cycle (IGCC) process has been investigated by many researchers to remove effectively hydrogen sulfide with various metal oxide sorbents at elevated temperatures. Various metal oxide sorbents are formulated with metal oxides such as Fe, Co, Zn, and Ti. Initial reaction kinetics of formulated sorbents with hydrogen sulfide is studied in the presence of various amounts of moisture and hydrogen at various reaction temperatures. The objectives of this research are to study initial reaction kinetics for a sorbent-hydrogen sulfide heterogeneous reaction system, to investigate effects of concentrations of hydrogen sulfide, hydrogen, and moisture on dynamic absorption of H{sub 2}S into sorbents, and to evaluate effects of temperature and sorbent amounts on dynamic absorption of H{sub 2}S into sorbents. Experimental data on initial reaction kinetics of hydrogen sulfide with metal oxide sorbents were obtained with a 0.83-cm{sup 3} differential reactor. In this report, the reactivity of AHI-5 was examined. This sorbent was obtained from the Research Triangle Institute (RTI). The sorbent in the form of 70 {micro}m particles are reacted with 9000-18000 ppm hydrogen sulfide at 350-500 C. The range of space time of reaction gas mixtures is 0.071-0.088 s. The range of reaction duration is 4-10800 s.

K.C. Kwon

2001-01-01T23:59:59.000Z

304

Theoretical validation of chemical kinetic mechanisms : combustion of methanol.  

DOE Green Energy (OSTI)

A new technique is proposed that uses theoretical methods to systematically improve the performance of chemical kinetic mechanisms. Using a screening method, the chemical reaction steps that most strongly influence a given kinetic observable are identified. The associated rate coefficients are then improved by high-level quantum chemistry and transition-state-theory calculations, which leads to new values for the coefficients and smaller uncertainty ranges. This updating process is continued as new reactions emerge as the most important steps in the target observable. The screening process employed is a global sensitivity analysis that involves Monte Carlo sampling of the full N-dimensional uncertainty space of rate coefficients, where N is the number of reaction steps. The method is applied to the methanol combustion mechanism of Li et al. (Int. J. Chem. Kinet. 2007, 39, 109.). It was found that the CH{sub 3}OH + HO{sub 2} and CH{sub 3}OH + O{sub 2} reactions were the most important steps in setting the ignition delay time, and the rate coefficients for these reactions were updated. The ignition time is significantly changed for a broad range of high-concentration methanol/oxygen mixtures in the updated mechanism.

Skodje, R. T.; Tomlin, A. S.; Klippenstein, S. J.; Harding, L. B.; Davis, M. J.; Chemical Sciences and Engineering Division; Univ. of Colorado; Univ. of Leeds

2010-08-19T23:59:59.000Z

305

Kinetic theory of nonlinear transport phenomena in complex plasmas  

SciTech Connect

In contrast to the prevalent use of the phenomenological theory of transport phenomena, a number of transport properties of complex plasmas have been evaluated by using appropriate expressions, available from the kinetic theory, which are based on Boltzmann's transfer equation; in particular, the energy dependence of the electron collision frequency has been taken into account. Following the recent trend, the number and energy balance of all the constituents of the complex plasma and the charge balance on the particles is accounted for; the Ohmic loss has also been included in the energy balance of the electrons. The charging kinetics for the complex plasma comprising of uniformly dispersed dust particles, characterized by (i) uniform size and (ii) the Mathis, Rumpl, and Nordsieck power law of size distribution has been developed. Using appropriate expressions for the transport parameters based on the kinetic theory, the system of equations has been solved to investigate the parametric dependence of the complex plasma transport properties on the applied electric field and other plasma parameters; the results are graphically illustrated.

Mishra, S. K. [Institute for Plasma Research (IPR), Gandhinagar 382428 (India); Sodha, M. S. [Centre for Energy Studies (CES), Indian Institute of Technology Delhi (IITD), New Delhi 110016 (India)

2013-03-15T23:59:59.000Z

306

Split kinetic energy method for quantum systems with competing potentials  

SciTech Connect

For quantum systems with competing potentials, the conventional perturbation theory often yields an asymptotic series and the subsequent numerical outcome becomes uncertain. To tackle such a kind of problems, we develop a general solution scheme based on a new energy dissection idea. Instead of dividing the potential energy into 'unperturbed' and 'perturbed' terms, a partition of the kinetic energy is performed. By distributing the kinetic energy term in part into each individual potential, the Hamiltonian can be expressed as the sum of the subsystem Hamiltonians with respective competing potentials. The total wavefunction is expanded by using a linear combination of the basis sets of respective subsystem Hamiltonians. We first illustrate the solution procedure using a simple system consisting of a particle under the action of double {delta}-function potentials. Next, this method is applied to the prototype systems of a charged harmonic oscillator in strong magnetic field and the hydrogen molecule ion. Compared with the usual perturbation approach, this new scheme converges much faster to the exact solutions for both eigenvalues and eigenfunctions. When properly extended, this new solution scheme can be very useful for dealing with strongly coupling quantum systems. - Highlights: Black-Right-Pointing-Pointer A new basis set expansion method is proposed. Black-Right-Pointing-Pointer Split kinetic energy method is proposed to solve quantum eigenvalue problems. Black-Right-Pointing-Pointer Significant improvement has been obtained in converging to exact results. Black-Right-Pointing-Pointer Extension of such methods is promising and discussed.

Mineo, H.; Chao, Sheng D., E-mail: sdchao@spring.iam.ntu.edu.tw

2012-09-15T23:59:59.000Z

307

Hydrotreating process kinetics for bitumen and bitumen-derived liquids  

DOE Green Energy (OSTI)

Hydrodenitrogenation, hydrodesulfurization and resid conversion data for the Whiterocks bitumen and bitumen-derived liquid were analyzed using a modified power rate law model. The model incorporated the space velocity and pressure since the plug flow equation may not be applicable to laboratory-scale reactors in which complete wetting of the catalyst may not be attained. The data were obtained with the reactor operating as a fixed bed reactor in the upflow mode. The space velocity (WHSV{sup {alpha}}) term was included to account for deviations from plug flow behavior. The exponents (a,p) and the kinetic parameters were obtained by combined non-linear regression and ODE solver techniques for the analysis of laboratory data. A simple nth order power rate law expression for hydrodenitrogenation and hydrodesulfurization was examined. The higher than first order kinetics for hydrodenitrogenation and hydrodesulfurization of the bitumen and bitumen-derived liquids were explained by invoking two parallel first-order reactions; one slow and the other fast. Parallel and consecutive reaction schemes were used to examine the extent of conversion of the resid fraction to middle distillate, gas oil and gasoline and the apparent kinetic parameters were determined. It was determined that the upflow operating mode was preferred to the trickle-bed mode in the laboratory reactor to insure plug flow behavior.

Kwak, S.; Longstaff, D.C.; Deo, M.D.; Hanson, F.V.

1993-03-01T23:59:59.000Z

308

Quantum instanton evaluation of the kinetic isotope effects  

DOE Green Energy (OSTI)

A general quantum-mechanical method for computing kinetic isotope effects is presented. The method is based on the quantum instanton approximation for the rate constant and on the path integral Metropolis Monte-Carlo evaluation of the Boltzmann operator matrix elements. It computes the kinetic isotope effect directly, using a thermodynamic integration with respect to the mass of the isotope, thus avoiding the more computationally expensive process of computing the individual rate constants. The method is more accurate than variational transition-state theories or the semiclassical instanton method since it does not assume a single reaction path and does not use a semiclassical approximation of the Boltzmann operator. While the general Monte-Carlo implementation makes the method accessible to systems with a large number of atoms, we present numerical results for the Eckart barrier and for the collinear and full three-dimensional isotope variants of the hydrogen exchange reaction H+H{sub 2} {yields} H{sub 2}+H. In all seven test cases, for temperatures between 250 K and 600 K, the error of the quantum instanton approximation for the kinetic isotope effects is less than {approx}10%.

Vanicek, Jiri; Miller, William H.; Castillo, Jesus F.; Aoiz, F.Javier

2005-04-19T23:59:59.000Z

309

Les mots et les couleurs en mouvement  

E-Print Network (OSTI)

que sur le bleu clair. en bas de la loile el sur le lilas.progression \\'a de haut en bas, alors qu'au centre de ladislingue une progression de bas en haut Le bleu tres clair

Akli, Madalina

2004-01-01T23:59:59.000Z

310

brevets cl en particul  

E-Print Network (OSTI)

car e National de iFePO4 un contrat d vers la te ur la fabr 13 mars 20 contrat de s oduction et l rformances e atteries, nota e automobile t Hydro-Québ che scientifiq riant, ont sig cette technol apidement à. L en a obtenu conductivité ffisamment fi biais des bre dont Hydro-Q he Scientifiq ensing A nce

Pouyanne, Nicolas

311

Fragilizacin por hidrgeno en tuberas de acero.  

E-Print Network (OSTI)

??Se pretende analizar el comportamiento en presencia de hidrogeno de las tuberas de acero de sistemas de transporte de combustibles gaseosos en uso para ello: (more)

Gutirrez-Solana Salcedo, Federico

1981-01-01T23:59:59.000Z

312

Kinetic Lattice Monte Carlo Simulation ofKinetic Lattice Monte Carlo Simulation of Polycrystalline Thin film growthPolycrystalline Thin film growth  

E-Print Network (OSTI)

grain orientations s The first application of this code is to the growth of Mo tips, including chemicalKinetic Lattice Monte Carlo Simulation ofKinetic Lattice Monte Carlo Simulation of Polycrystalline Applications Motorola National Science Foundation National Center for Supercomputer Applications Motorola #12

Adams, James B

313

Influence of diffusion on the kinetics of excited-state associationdissociation reactions: Comparison of theory and simulation  

E-Print Network (OSTI)

-state proton transfer to solvent.1 In this context, Weller has solved the rate equations of chemical kinetics: Technological Institute, Kemerovo 650060, Russia. b On leave from the Institute of Chemical Kinetics kinetics We begin with the chemical kinetic approach where one solves two coupled ordinary differential

Agmon, Noam

314

Energetics and kinetics of anaerobic aromatic and fatty acid degradation  

DOE Green Energy (OSTI)

The kinetics of benzoate degradation by the anaerobic syntrophic bacterium, Syntrophus buswellii, was studied in coculture with Desulfovibrio strain G11. The threshold value for benzoate degradation was dependent on the acetate concentration with benzoate threshold values ranging from 2.4 [mu]M at 20 mM acetate to 30.0 [mu]M at 65 mM acetate. Increasing acetate concentrations also inhibited the rate of benzoate degradation with a apparent K[sub i] for acetate inhibition of 7.0 mM. Lower threshold values were obtained when nitrate rather than sulfate was the terminal electron acceptor. These data are consistent with a thermodynamic explanation for the threshold, and suggest that there is a minimum Gibbs free energy value required for the degradation of benzoate. An acetoacetyl-CoA thiolase has been isolated from Syntrophomonas wolfei; it is apparently a key enzyme controlling the synthesis of poly-B-hydroxyalkanoate from acetyl-CoA in this organism. Kinetic characterization of the acetoacetyl-CoA thiolase from S. wolfei showed that it is similar in its structural, kinetic, and apparent regulatory properties to other biosynthetic acetoacetyl-CoA thiolases from phylogenetically distinct bacteria that synthesize PHA. Intracellular concentrations of CoA and acetyl-CoA are believed to be critical factors regulating the activity of the acetoacetyl-CoA thiolase in S. wolfei. We have also isolated and characterized several new halophilic anaerobic fermentative anaerobes. Phylogenetic analysis indicates that one of these bacteria is a new species in the genus, Haloanaerobium. Two other species appear to be members of the genus, Halobacteroides. Several halophilic acetoclastic methanogenic bacteria have also been isolated and their physiological properties are currently under investigation. We have also isolated an acetate-using dissimilatory iron-reducing bacterium.

McInerney, M.J.

1992-11-16T23:59:59.000Z

315

Isopiestic Kinetics of Pd/C/DPB Composite: Temperature Dependence  

DOE Green Energy (OSTI)

In 2007, a continuation of experiments studying the uptake kinetics of a DPB getter material was conducted. In these experiments, a powder formed from ground pellets of DPB getter as currently deployed was subject to multiple hydrogenations in an isopiestic hydrogen reactor. The objective was to observe the reaction kinetics of the powdered material as a function of ambient hydrogen pressure at room temperature, with the intention of resolving key issues of the DPB reaction mechanism that could relate to its aging and capacity characteristics. The results indicated, in agreement with work performed in 2006 as part of the same project, that the likely mechanism of DPB/Hydrogen reaction occurs via the diffusion of unreacted DPB toward the catalyst surface. They also demonstrated that at a sufficiently high pressure (on the order of a few torr) of hydrogen, the reaction was vigorous enough to release sufficient heat to vaporize both the DPB getter and its hydrogenate away from the surface of the Pd catalyst at which the reaction takes place. The consequence was a premature slowing of the reaction kinetics and a drop in overall capacity. In the present work, the isopiestic reaction scheme is expanded to study the dependence of the reaction rate of this material on both hydrogen pressure and temperature. The dependence of the reaction rate on both temperature and pressure can provide both valuable clues about the reaction mechanism, as well as the activation energy of the principal reaction. The activation energy is an especially important term for purposes of doing lifetime predictions for getters under conditions of varying temperature.

Dinh, L N; Meulenberg, R; Saab, A P

2009-05-27T23:59:59.000Z

316

Bio-butanol: Combustion properties and detailed chemical kinetic model  

Science Conference Proceedings (OSTI)

Autoignition delay time measurements were performed at equivalence ratios of 0.5, 1 and 2 for butan-1-ol at reflected shock pressures of 1, 2.6 and 8 atm at temperatures from 1100 to 1800 K. High-level ab initio calculations were used to determine enthalpies of formation and consequently bond dissociation energies for each bond in the alcohol. A detailed chemical kinetic model consisting of 1399 reactions involving 234 species was constructed and tested against the delay times and also against recent jet-stirred reactor speciation data with encouraging results. The importance of enol chemistry is highlighted. (author)

Black, G.; Curran, H.J.; Pichon, S.; Simmie, J.M.; Zhukov, V. [Combustion Chemistry Centre, National University of Ireland, Galway (Ireland)

2010-02-15T23:59:59.000Z

317

Advanced quasi-steady state approximation for chemical kinetics  

E-Print Network (OSTI)

Computational feasibility of turbulent reacting flows hinges on the reduction of large chemical kinetics systems to smaller more manageable reaction sets. Recently, several sophisticated reduction techniques have been developed but they continue to be computationally prohibitive for practical three-dimensional unsteady computations. For such applications, the classical quasi-steady state assumption (QSSA), despite serious shortcomings, continues to be popular due to its conceptual clarity and computational simplicity. Starting from invariant manifold description, we develop an advanced quasi-steady state assumption which (i) is independent of the choice of the retained (slow) species; (ii) possesses much improved physical and mathematical characteristics; and (iii) can be specialized for any objective function.

Girimaji, Sharath

2011-01-01T23:59:59.000Z

318

Kinetic Simulations of Solar Type II Radio Burst Emission Processes  

SciTech Connect

Using our kinetic Particle-in-Cell simulation code, we have examined the behavior of different plasma modes in the environment close to a CME shock front, with special focus on the modes that may contribute to the formation of type II radio bursts. Apart from electron velocity spectra, numerical dispersion plots obtained from simulation data allow for analysis of wave modes in the simulated plasma, especially showing growth and damping of these modes over time. These plots reveal features at 2omega{sub p} which are not predicted by linear wave theory, that may be results of nonlinear three wave interaction processes as theoretically predicted for type II emission processes.

Ganse, Urs; Burkart, Thomas; Spanier, Felix [Lehrstuhl fuer Astronomie, Universitaet Wuerzburg (Germany); Vainio, Rami [Department of Physics, University of Helsinki (Finland)

2010-03-25T23:59:59.000Z

319

Kinetics of beneficiated fly ash by carbon burnout  

Science Conference Proceedings (OSTI)

The presence of carbon in fly ash requires an increase in the dosage of the air-entraining admixture for concrete mix, and may cause the admixture to lose efficiency. Specifying authorities for the concrete producers have set maximum allowable levels of residual carbon. These levels are the so called Loss On Ignition (LOI). The concrete producers` day-to-day purchasing decisions sets the LOI at 4%. The objective of the project is to investigate the kinetics of oxidation of residual carbon present in coal fly ash as a possible first step toward producing low-carbon fly ash from high-carbon, low quality fly ash.

Okoh, J.M.; Dodoo, J.N.D.; Diaz, A. [Univ. of Maryland Eastern Shore, Princess Anne, MD (United States). Dept. of Natural Sciences; Ferguson, W.; Udinskey, J.R. Jr.; Christiana, G.A. [Delmarva Power, Wilmington, DE (United States)

1997-12-31T23:59:59.000Z

320

KINETIC STUDIES OF THE TWO LIGHT REACTIONS IN PHOTOSYNTHESIS  

SciTech Connect

The decay kinetics of the photo-induced absorbance changes in red and green algae are very sensitive to the wavelength of the actinic 11ght. A four to twofold increase in half-decay time is noted in going from short wavelength (550-650 mu) to long wavelength (> 700 mu) excitation. The slow decay ratios, produced by long wavelength light can be enhanced with a steady background of short wavelength light. A relationship between initial decay rates and 02 evolution rates is described. This relationship allows a direct correspondence between these spectroscopic studies and the 'red-drop' and 'enhancement' experiments of Emerson.

Kuntz Jr., I.D.; Calvin, Melvin

1964-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "kinetic en ergy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Parity violating quantum kinetic theory in (2+1)-dimensions  

E-Print Network (OSTI)

We study the kinetic theory for a (2+1)-dimensional fermionic system with special emphasis on the parity violating properties associated with the fermion mass. The Wigner function approach is used to derive hydrodynamical transport coefficients to the first spatial derivative order. As a first attempt, the collisions between fermions are neglected. The resulting system is dissipationless. The parity violating Hall electric conductivity has the same temperature and chemical potential dependence as the quantum field theory result at one-loop. Vorticity dependent transport properties, which were not considered before, also emerge naturally in this approach.

Jiunn-Wei Chen; Jian-Hua Gao; Juan Liu; Shi Pu; Qun Wang

2013-05-08T23:59:59.000Z

322

Kinetic theory of the interdiffusion coefficient in dense plasmas  

DOE Green Energy (OSTI)

Naive applications of Spitzer's theory to very dense plasmas can lead to negative diffusion coefficients. The interdiffusion coefficients in Binary Ionic Mixtures (two species of point ions in a uniform neutralizing background) have been calculated recently using molecular dynamics techniques. These calculations can provide useful benchmarks for theoretical evaluations of the diffusion coefficient in dense plasma mixtures. This paper gives a brief description of a kinetic theoretic approximation to the diffusion coefficient which generalizes Spitzer to high density and is in excellent agreement with the computer simulations. 15 refs., 1 fig., 2 tabs.

Boercker, D.B.

1986-08-01T23:59:59.000Z

323

Kinetic analysis of two dimensional metallic grating Cerenkov maser  

Science Conference Proceedings (OSTI)

The dispersion relation of two dimensional metallic grating Cerenkov maser has been given by using kinetic analysis, in which the influence of electron movement is directly considered without using an equivalent dielectric medium assumption. The effects of structural parameters and beam state on the interaction gain and synchronous frequency have also been investigated in detail by numerical calculations. To an illustrative case, the quantitative relations produced from varying the gap distance between electron beam and metallic grating, beam current, electron transverse to axial velocity ratio, and electron axial velocity spread have been obtained. The developed method can be used to predict the real interaction system performances.

Zhao Ding [Key Laboratory of High Power Microwave Sources and Technologies, Institute of Electronics, Chinese Academy of Sciences, Beijing 100190 (China)

2011-08-15T23:59:59.000Z

324

Fundamental kinetic modeling of the catalytic reforming process  

E-Print Network (OSTI)

In this work, a fundamental kinetic model for the catalytic reforming process has been developed. The complex network of elementary steps and molecular reactions occurring in catalytic reforming has been generated through a computer algorithm characterizing the various species by vectors and Boolean relation matrices. The algorithm is based on the fundamental chemistry occurring on both acid and metal sites of the catalyst. Rates are expressed for each of the elementary steps involved in the transformation of the intermediates. The Hougen-Watson approach is used to express the rates of the molecular reactions occurring on the metal sites of the catalyst. The single event approach is used to account for the effect of structure of reactant and activated complex on the rate coefficients of the elementary steps occurring on the acid sites. This approach recognizes that even if the number of elementary steps is very large they belong to a very limited number of types, and therefore it is possible to express the kinetics of elementary steps by a reduced number of parameters. In addition, the single event approach leads to rate coefficients that are independent of the feedstock, due to their fundamental chemical nature. The total number of parameters at isothermal conditions is 45. To estimate these parameters, an objective function based upon the sum of squares of the residuals was minimized through the Marquardt algorithm. Intraparticle mass transport limitations and deactivation of the catalyst by coke formation are considered in the model. Both the Wilke and the Stefan-Maxwell approaches were used to calculate the concentration gradients inside of the particle. The heterogeneous kinetic model was applied in the simulation of the process for typical industrial conditions for both axial and radial flow fixed bed reactors. The influence of the main process variables on the octane number and reformate volume was investigated and optimal conditions were obtained. Additional aspects studied with the kinetic model are the reduction of aromatics, mainly benzene. The results from the simulations agree with the typical performance found in the industrial process.

Sotelo-Boyas, Rogelio

2005-12-01T23:59:59.000Z

325

Kinetic phenomena in charged particle transport in gases and plasmas  

SciTech Connect

The key difference between equilibrium (thermal) and non-equilibrium (low temperature - a.k.a. cold) plasmas is in the degree in which the shape of the cross sections influences the electron energy distribution function (EEDF). In this paper we will discuss the issue of kinetic phenomena from two different angles. The first will be how to take advantage of the strong influence and use low current data to obtain the cross sections. This is also known as the swarm technique and the product of a ''swarm analysis'' is a set of cross sections giving good number, momentum and energy balances of electrons or other charged particles. At the same time understanding the EEDF is based on the cross section data. Nevertheless sometimes the knowledge of the cross sections and even the behaviour of individual particles are insufficient to explain collective behaviour of the ensemble. The resulting ''kinetic'' effects may be used to favour certain properties of non-equilibrium plasmas and even may be used as the basis of some new plasma applications.

Petrovic, Zoran Lj.; Dujko, Sasa; Sasic, Olivera; Stojanovic, Vladimir; Malovic, Gordana [Institute of Physics, University of Belgrade, POB 68 11080 Zemun (Serbia); Faculty of Traffic Engineering, University of Belgrade Belgrade (Serbia); Institute of Physics, University of Belgrade, POB 68 11080 Zemun (Serbia)

2012-05-25T23:59:59.000Z

326

Hydro-kinetic approach to relativistic heavy ion collisions  

E-Print Network (OSTI)

We develop a combined hydro-kinetic approach which incorporates a hydrodynamical expansion of the systems formed in \\textit{A}+\\textit{A} collisions and their dynamical decoupling described by escape probabilities. The method corresponds to a generalized relaxation time ($\\tau_{\\text{rel}}$) approximation for the Boltzmann equation applied to inhomogeneous expanding systems; at small $\\tau_{\\text{rel}}$ it also allows one to catch the viscous effects in hadronic component - hadron-resonance gas. We demonstrate how the approximation of sudden freeze-out can be obtained within this dynamical picture of continuous emission and find that hypersurfaces, corresponding to a sharp freeze-out limit, are momentum dependent. The pion $m_{T}$ spectra are computed in the developed hydro-kinetic model, and compared with those obtained from ideal hydrodynamics with the Cooper-Frye isothermal prescription. Our results indicate that there does not exist a universal freeze-out temperature for pions with different momenta, and support an earlier decoupling of higher $p_{T}$ particles. By performing numerical simulations for various initial conditions and equations of state we identify several characteristic features of the bulk QCD matter evolution preferred in view of the current analysis of heavy ion collisions at RHIC energies.

S. V. Akkelin; Y. Hama; Iu. A. Karpenko; Yu. M. Sinyukov

2008-04-25T23:59:59.000Z

327

CONSERVATIVE CASCADE OF KINETIC ENERGY IN COMPRESSIBLE TURBULENCE  

SciTech Connect

The physical nature of compressible turbulence is of fundamental importance in a variety of astrophysical settings. We investigate the question: 'At what scales does the mechanism of pressure-dilatation operate?' and present the first direct evidence that mean kinetic energy cascades conservatively beyond a transitional 'conversion' scale range despite not being an invariant of the dynamics. We use high-resolution 1024{sup 3} subsonic and transonic simulations. The key quantity we measure is the pressure-dilatation cospectrum, E{sup PD}(k), where we show that it decays at a rate faster than k{sup -1} in wavenumber in at least the subsonic and transonic regimes. This is sufficient to imply that mean pressure-dilatation acts primarily at large scales and that kinetic and internal energy budgets statistically decouple beyond a transitional scale range. However, we observe that small-scale dynamics remains highly compressible locally in space and that the statistical decoupling in the energy budgets is unrelated to the existence of a subsonic scale range. Our results suggest that an extension of Kolmogorov's inertial-range theory to compressible turbulence is possible.

Aluie, Hussein; Li Shengtai; Li, Hui [Los Alamos National Laboratory, Los Alamos, NM 87545 (United States)

2012-06-01T23:59:59.000Z

328

Progress in Chemical Kinetic Modeling for Surrogate Fuels  

DOE Green Energy (OSTI)

Gasoline, diesel, and other alternative transportation fuels contain hundreds to thousands of compounds. It is currently not possible to represent all these compounds in detailed chemical kinetic models. Instead, these fuels are represented by surrogate fuel models which contain a limited number of representative compounds. We have been extending the list of compounds for detailed chemical models that are available for use in fuel surrogate models. Detailed models for components with larger and more complicated fuel molecular structures are now available. These advancements are allowing a more accurate representation of practical and alternative fuels. We have developed detailed chemical kinetic models for fuels with higher molecular weight fuel molecules such as n-hexadecane (C16). Also, we can consider more complicated fuel molecular structures like cyclic alkanes and aromatics that are found in practical fuels. For alternative fuels, the capability to model large biodiesel fuels that have ester structures is becoming available. These newly addressed cyclic and ester structures in fuels profoundly affect the reaction rate of the fuel predicted by the model. Finally, these surrogate fuel models contain large numbers of species and reactions and must be reduced for use in multi-dimensional models for spark-ignition, HCCI and diesel engines.

Pitz, W J; Westbrook, C K; Herbinet, O; Silke, E J

2008-06-06T23:59:59.000Z

329

The conservative cascade of kinetic energy in compressible turbulence  

E-Print Network (OSTI)

The physical nature of compressible turbulence is of fundamental importance in a variety of astrophysical settings. We present the first direct evidence that mean kinetic energy cascades conservatively beyond a transitional "conversion" scale-range despite not being an invariant of the compressible flow dynamics. We use high-resolution three-dimensional simulations of compressible hydrodynamic turbulence on $512^3$ and $1024^3$ grids. We probe regimes of forced steady-state isothermal flows and of unforced decaying ideal gas flows. The key quantity we measure is pressure dilatation cospectrum, $E^{PD}(k)$, where we provide the first numerical evidence that it decays at a rate faster than $k^{-1}$ as a function of wavenumber. This is sufficient to imply that mean pressure dilatation acts primarily at large-scales and that kinetic and internal energy budgets statistically decouple beyond a transitional scale-range. Our results suggest that an extension of Kolmogorov's inertial-range theory to compressible turbulence is possible.

Hussein Aluie; Shengtai Li; Hui Li

2011-07-28T23:59:59.000Z

330

The conservative cascade of kinetic energy in compressible turbulence  

E-Print Network (OSTI)

The physical nature of compressible turbulence is of fundamental importance in a variety of astrophysical settings. We present the first direct evidence that mean kinetic energy cascades conservatively beyond a transitional "conversion" scale-range despite not being an invariant of the compressible flow dynamics. We use high-resolution three-dimensional simulations of compressible hydrodynamic turbulence on $512^3$ and $1024^3$ grids. We probe regimes of forced steady-state isothermal flows and of unforced decaying ideal gas flows. The key quantity we measure is pressure dilatation cospectrum, $E^{PD}(k)$, where we provide the first numerical evidence that it decays at a rate faster than $k^{-1}$ as a function of wavenumber. This is sufficient to imply that mean pressure dilatation acts primarily at large-scales and that kinetic and internal energy budgets statistically decouple beyond a transitional scale-range. Our results suggest that an extension of Kolmogorov's inertial-range theory to compressible turbu...

Aluie, Hussein; Li, Hui

2011-01-01T23:59:59.000Z

331

Kinetics and deactivation of sulfated zirconia catalysts for butane isomerization  

Science Conference Proceedings (OSTI)

Reaction kinetics studies were conducted of n-butane and isobutane isomerization over sulfated zirconia at 423 K. The kinetic data can be described well by a rate expression based on a reversible, bimolecular surface reaction between two adsorbed n-C{sub 4} species, probably through a C{sub 8} intermediate, to produce one i-C{sub 4} species, as well as surface reaction between two adsorbed i-C{sub 4} species to produce one n-C{sub 4} species. This reaction sequence also describes well the rates of C{sub 4}-disproportionation reactions to produce C{sub 3} and C{sub 5} species. The initial rate of catalyst deactivation is faster during n-butane isomerization than during isobutane isomerization, and the longer-term rate of deactivation during n-butane isomerization increases with the pressures of n-butane. The more rapid catalyst deactivation during n-butane isomerization may be related to the formation of n-C{sub 4}-diene species. 25 refs., 10 figs., 4 tabs.

Fogash, K.B.; Larson, R.B.; Gonzalez, M.R. [Univ. of Wisconsin, Madison, WI (United States)] [and others] [Univ. of Wisconsin, Madison, WI (United States); and others

1996-09-15T23:59:59.000Z

332

Solar kinetics` photovoltaic concentrator module and tracker development  

DOE Green Energy (OSTI)

Solar Kinetics, Inc., has been developing a point-focus concentrating photovoltaic module and tracker system under contract to Sandia National Laboratories. The primary focus of the contract was to achieve a module design that was manufacturable and passed Sandia`s environmental testing. Nine modules of two variations were assembled, tested, and characterized in Phase 1, and results of these tests were promising, with module efficiency approaching the theoretical limit achievable with the components used. The module efficiency was 11.9% at a solar irradiance of 850 W/m{sup 2} and an extrapolated cell temperature of 25{degrees}C. Improvements in module performance are anticipated as cell efficiencies meet their expectations. A 2-kW tracker and controller accommodating 20 modules was designed, built, installed, and operated at Solar Kinetics` test site. The drive used many commercially available components in an innovative arrangement to reduce cost and increase reliability. Backlash and bearing play were controlled by use of preloaded, low slip-stick, synthetic slide bearings. The controller design used a standard industrial programmable logic controller to perform ephemeris calculations, operate the actuators, and monitor encoders.

White, D.L.; Howell, B. [Solar Kinetics, Inc., Dallas, TX (United States)

1995-11-01T23:59:59.000Z

333

Development of kinetic model reduction framework and its application in realistic flow simulation.  

E-Print Network (OSTI)

??The main objective of this research is to develop a kinetic model reduction framework that enables incorporation of detailed chemistry with realistic flow simulation. Comprehensive (more)

He, Kaiyuan, 1986-

2010-01-01T23:59:59.000Z

334

Redox Kinetics and Diffusion in Lithium Niobate by Optical In Situ ...  

Science Conference Proceedings (OSTI)

Redox kinetics upon oxygen activity jumps and the associated chemical diffusion coefficients are found in close agreement at a given temperature, indicating a...

335

Application of chemical kinetic modeling to improve design and performance criteria for a practical incineration system.  

E-Print Network (OSTI)

??In this study, detailed thermo-chemical kinetics with networked ideal reactor model were applied to simulate a practical combustion system -the Secondary Combustion Chamber (SCC) of (more)

Bass, Jr., Charles A.

2002-01-01T23:59:59.000Z

336

Application of chemical probes to study the kinetic mechanism of DNA polymerases.  

E-Print Network (OSTI)

??Kinetic and structural basis of high-fidelity DNA replication by DNA polymerases has been the subject of extensive studies for several decades; however, it is still (more)

Bakhtina, Marina M.

2006-01-01T23:59:59.000Z

337

Specialized power-electronic apparatus for harnessing electrical power from kinetic hydropower plants.  

E-Print Network (OSTI)

??This thesis introduces a power electronic interface for a kinetic hydropower generation platform that enables extraction of electric power from a free-flowing water source such (more)

Mosallat, Farid

2012-01-01T23:59:59.000Z

338

Kinetic analysis of coal and biomass co-gasification with carbon dioxide.  

E-Print Network (OSTI)

??Based on Thermogravimetric Analysis (TGA) experimental data, a kinetic analysis of the Boudouard reaction was studied for three different coal chars, three different biomass chars, (more)

Bu, Jiachuan.

2009-01-01T23:59:59.000Z

339

C-1: A Kinetic Study of the Leaching of Germanium Dust and Fume ...  

Science Conference Proceedings (OSTI)

The apparent activation energy for the dissolution of germanium has been evaluated ... Moreover, the apparent reaction order and the kinetic equation for the...

340

The inverse kinetics method and PID compensation of the Annular Core Research Reactor.  

E-Print Network (OSTI)

??This thesis explores the development of a model describing the Annular Core Research Reactor (ACRR), the application of the inverse kinetics method to calculate the (more)

Garnas, Benjamin

2008-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "kinetic en ergy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Development of 3-D Neutronic Kinetic Model and Control for CANDU Reactors.  

E-Print Network (OSTI)

??The development of a three dimensional (3-D) neutronic kinetic modeling process aiming at control system design for CANadian Deuterium Uranium (CANDU) reactors is carried out (more)

Xia, Lingzhi

2012-01-01T23:59:59.000Z

342

Pyrolysis Kinetics and Chemical Structure Considerations of a Green River Oil Shale and Its Derivatives.  

E-Print Network (OSTI)

??This work had the objective of determining both the kinetic parameters for the pyrolysis of oil shale and kerogen as well as using analytical techniques (more)

Hillier, James L

2011-01-01T23:59:59.000Z

343

71 clueweb09-en0000-04-05221 clueweb09-en0007-91 ...  

Science Conference Proceedings (OSTI)

... clueweb09-en0029-93-31582 0 18446744073709551615 0 0 79 clueweb09-en0082-62-40299 clueweb09-en0133-75-42321 0 thailand 0 1 ...

2012-02-17T23:59:59.000Z

344

Comparison of point kinetics, improved quasistatic and theta method as space-time kinetics solvers in DONJON-3 simulations  

Science Conference Proceedings (OSTI)

To ensure the safety of nuclear reactors, we have to simulate accurately their normal operation and also accident cases. To perform transient calculations, coupled neutronic and fhermo-hydraulic codes are used. This article compares three neutronic solvers. The first one is the point kinetic approach where the flux shape is constant during all the transient. For the second method (the improved quasistatic method), the flux shape is constant but only during small time steps. Finally, we used the theta approach where both flux and precursors distributions vary with time and space. Transients of Lost Of Coolant Accident in CANDU-6 reactors have been simulated with DONJON and the outputs of a thermalhydraulic system code. Results show that the point kinetics is inappropriate for transient with large distortion of the flux shape. Improved quasistatic and theta methods give relatively similar results. However, the improved quasistatic approach is less stable and a little bit more sensitive on time-step and spatial discretization than the theta method is. (authors)

Chambon, R.; Marleau, G. [Institut de Genie Nucleaire, Ecole Polytechnique de Montreal, 2500 chemin de la Polytechnique, Montreal, QC H3C 3A7 (Canada)

2012-07-01T23:59:59.000Z

345

MHK Technologies/Kinetic Hydropower System KHPS | Open Energy Information  

Open Energy Info (EERE)

Kinetic Hydropower System KHPS Kinetic Hydropower System KHPS < MHK Technologies Jump to: navigation, search << Return to the MHK database homepage Verdantpower.jpg Technology Profile Primary Organization Verdant Power Project(s) where this technology is utilized *MHK Projects/Roosevelt Island Tidal Energy RITE *MHK Projects/Cornwall Ontario River Energy CORE Technology Resource Click here Current/Tidal Technology Type Click here Axial Flow Turbine Technology Readiness Level Click here TRL 7/8: Open Water System Testing & Demonstration & Operation Technology Description Verdant Power's central technology is the Kinetic Hydropower System (KHPS), a water-to-wire system that consists of three main components: 1) KHPS TURBINE: a three-bladed horizontal-axis turbine with four major assemblies: a) Composite rotor with 3-fixed blades that rotate at the relatively slow and constant speed of approximately 40 RPM, with tip-speeds of 35 feet per second. This is well below normal water vessel propeller speeds and conventional hydropower turbine blade speeds. b) Sealed nacelle, pylon and passive yaw mechanism that is hydrodynamically designed to allow the turbine to self-rotate into the prevailing current (like a weathervane) so that the blades are optimally aligned to generate energy. c) Custom-designed drivetrain unit (with induction generator) enclosed within the nacelle that integrates the bearing housing with a special long-life planetary gearbox, with mechanical shaft seals and a minimum of sealed lubricants. d) Streambed mounting system that can vary depending on site conditions as a single drilled monopile, a single gravity-based structure, or a gravity-based triframe mount that supports 3 turbines. 2) UNDERWATER CABLING: low-voltage shielded cable of short distance; and shoreline switchgear vaults, control room, and interconnection point(s). 3) APPURTENANT FACILITIES: for navigation safety, such as Public Aides to Navigation (PATON) buoys and lighted warning signs, as well as instrumentation including Acoustic Doppler Current Profilers (ADCPs). In order to maximize the application of the KHPS within the global MHK resource, Verdant Power has designed the technology as a simple and uniquely scalable system that can be operated in tidal, river and ocean current settings. Possible KHPS installations range from distributed generation arrangements in near-shore urban and village settings to base power generation at offshore deepwater locales.

346

Kinetic Modeling of Toluene Oxidation for Surrogate Fuel Applications  

SciTech Connect

New environmental issues, like the effect of combustion-generated greenhouse gases, provide motivation to better characterize oxidation of hydrocarbons. Transportation, in particular, significantly contributes to energy consumption and CO{sub 2} emissions. Kinetic studies about the combustion of fuels under conditions typical of internal combustion engines provides important support to improve mechanism formulation and to eventually provide better computational tools that can be used to increase the engine performance. It is foreseeable that at least in the next 30 years the main transportation fuels will be either gasoline or diesel. Unfortunately, these fuels are very complex mixtures of many components. Moreover, their specifications and performance requirements significantly change the composition of these fuels: gasoline and diesel mixtures are different if coming from different refineries or they are different from winter to summer. At the same time a fuel with a well defined and reproducible composition is needed for both experimental and modeling work. In response to these issues, surrogate fuels are proposed. Surrogate fuels are defined as mixtures of a small number of hydrocarbons whose relative concentrations is adjusted in order to approximate the chemical and physical properties of a real fuel. Surrogate fuels are then very useful both for the design of reproducible experimental tests and also for the development of reliable kinetic models. The primary reference fuels (PRF) are a typical and old example of surrogate fuel: n-heptane and iso-octane mixtures are used to reproduce antiknock propensity of complex mixtures contained in a gasoline. PRFs are not able to surrogate gasoline in operating conditions different from standard ones and new surrogates have been recently proposed. Toluene is included in all of them as a species able to represent the behavior of aromatic compounds. On the other side, the toluene oxidation chemistry is not so well established and uncertainties still remain in the mechanism. This is especially true in the low temperature regime (< 850K). In these conditions, the toluene reactivity is too low to be conveniently investigated. Nonetheless, gasoline surrogates work in the engine at low temperatures, because of the presence of very reactive alkanes. The effect of these component interactions have to be taken into account. This work's aim is to present the model activity carried out by two different research groups, comparing the main pathways and results, matching data carried out in different devices both for pure toluene and mixtures. This is the starting point for a further activity to improve the two kinetic schemes.

Frassoldati, A; Mehl, M; Fietzek, R; Faravelli, T; Pitz, W J; Ranzi, E

2009-04-21T23:59:59.000Z

347

Isopiestic Kinetics of Powdered Pd/C/DPB Composite  

DOE Green Energy (OSTI)

In a 2006 LLNL internal report, a study of DEB and DPB based hydrogen getter materials was described. The materials, consisting of DEB or DPB physically blended with amorphous carbon on which palladium nanoparticle catalyst was supported, were studied during the course of reaction with fixed aliquots of hydrogen gas in order to observe their hydrogen consumption capacities as a function of ambient hydrogen pressure. The experiments demonstrated that the getter capacity was directly proportional to hydrogen fugacity: the lower the initial hydrogen pressure, the lower the resultant capacity at correspondingly low steady-state pressures. In the course of these experiments, further interesting observations were made of DEB and DPB reduction by hydrogen gas that painted a picture of a complicated reaction mechanism. To summarize, it was determined that reaction rate was controlled partly by diffusion of the organic diacetylene toward the catalyst surface. The results indicated this diffusion was in turn enhanced by phase changes in the course of the reaction that result in a liquid phase of the getter, and also by the heat of reaction, itself being proportional to initial reaction rate. However, these same two terms were speculated to have negative impacts on the net reaction kinetics, as well. It was suggested the liquid phase served to block gas access, and that excessively fast initial rates limited rate and capacity at later times by creating a depletion zone of reactant around the catalyst. Because of the nature of the experiments, whereby both hydrogen pressure and getter activity were changing in time, actual kinetic information could not be gathered. Knowledge of the reaction rate characteristics of these materials as a function of pressure and temperature is crucial to understanding the overall behavior of this material in service. Further, direct observation of the reaction rate can permit estimates of the diffusion of the reactive species. The present work centers on the development of an understanding of the kinetics for the hydrogenation of DPB and DEB as a function of temperature and pressure.

Dinh, L; Saab, A

2008-05-30T23:59:59.000Z

348

En Neo | Open Energy Information  

Open Energy Info (EERE)

includes development, planning, construction and operation of wind power plants and photovoltaic plants. References En-Neo1 LinkedIn Connections CrunchBase Profile No CrunchBase...

349

Kinetics of nonisothermal adsorption by biporous adsorbents. Communication 6. Description of kinetic adsorption curves with account of the temperature dependence of the intracrystalline diffusion coefficients  

SciTech Connect

An analytical description has been given of the kinetic adsorption curves with account of the influence of the change in adsorbent temperature due to the evolution of heat and adsorption on the coefficient of intracrystalline diffusion of the adsorbate. The deviation of the experimental kinetic curves for the adsorption of trans-2-butene by finely crystalline NaA zeolite from those calculated from the equation of isothermal diffusion is due to the influence of temperature on the coefficient of intracrystalline diffusion.

Broddak, R.; Voloshchuk, A.M.; Gorlov, V.A.; Dubinin, M.M.; Kochirzhik, M.

1987-01-10T23:59:59.000Z

350

Chemical Dynamics, Molecular Energetics, and Kinetics at the Synchrotron  

SciTech Connect

Scientists at the Chemical Dynamics Beamline of the Advanced Light Source in Berkeley are continuously reinventing synchrotron investigations of physical chemistry and chemical physics with vacuum ultraviolet light. One of the unique aspects of a synchrotron for chemical physics research is the widely tunable vacuum ultraviolet light that permits threshold ionization of large molecules with minimal fragmentation. This provides novel opportunities to assess molecular energetics and reaction mechanisms, even beyond simple gas phase molecules. In this perspective, significant new directions utilizing the capabilities at the Chemical Dynamics Beamline are presented, along with an outlook for future synchrotron and free electron laser science in chemical dynamics. Among the established and emerging fields of investigations are cluster and biological molecule spectroscopy and structure, combustion flame chemistry mechanisms, radical kinetics and product isomer dynamics, aerosol heterogeneous chemistry, planetary and interstellar chemistry, and secondary neutral ion-beam desorption imaging of biological matter and materials chemistry.

Leone, Stephen R.; Ahmed, Musahid; Wilson, Kevin R.

2010-03-14T23:59:59.000Z

351

Kinetic damping of resistive wall modes in ITER  

SciTech Connect

Full drift kinetic modelling including finite orbit width effects has been used to assess the passive stabilisation of the resistive wall mode (RWM) that can be expected in the ITER advanced scenario. At realistic plasma rotation frequency, the thermal ions have a stabilising effect on the RWM, but the stability limit remains below the target plasma pressure to achieve Q = 5. However, the inclusion of damping arising from the fusion-born alpha particles, the NBI ions, and ICRH fast ions extends the RWM stability limit above the target {beta} for the advanced scenario. The fast ion damping arises primarily from finite orbit width effects and is not due to resonance between the particle frequencies and the instability.

Chapman, I. T.; Liu, Y. Q. [EURATOM/CCFE Fusion Association, Culham Science Centre, Abingdon, Oxfordshire OX14 3DB (United Kingdom); Asunta, O. [Department of Applied Physics, Association EURATOM-Tekes, Aalto University, P.O. Box 14100 FI-00076 AALTO (Finland); Graves, J. P. [CRPP, Association EURATOM/Confederation Suisse, EPFL, 1015 Lausanne (Switzerland); Johnson, T. [EURATOM-VR Association, EES, KTH, Stockholm (Sweden); Jucker, M. [GFDL/Princeton University, AOS Program, Princeton, New Jersey 08544 (United States)

2012-05-15T23:59:59.000Z

352

An Experimental and Kinetic Modeling Study of Methyl Decanoate Combustion  

DOE Green Energy (OSTI)

Biodiesel is typically a mixture of long chain fatty acid methyl esters for use in compression ignition engines. Improving biofuel engine performance requires understanding its fundamental combustion properties and the pathways of combustion. This research study presents new combustion data for methyl decanoate in an opposed-flow diffusion flame. An improved detailed chemical kinetic model for methyl decanoate combustion is developed, which serves as the basis for deriving a skeletal mechanism via the direct relation graph method. The novel skeletal mechanism consists of 648 species and 2998 reactions. This mechanism well predicts the methyl decanoate opposed-flow diffusion flame data. The results from the flame simulations indicate that methyl decanoate is consumed via abstraction of hydrogen atoms to produce fuel radicals, which lead to the production of alkenes. The ester moiety in methyl decanoate leads to the formation of low molecular weight oxygenated compounds such as carbon monoxide, formaldehyde, and ketene.

Sarathy, S M; Thomson, M J; Pitz, W J; Lu, T

2010-02-19T23:59:59.000Z

353

A Novel Approach to Experimental Studies of Mineral DIsoolution Kinetics  

NLE Websites -- All DOE Office Websites (Extended Search)

Novel ApproAch to experimeNtAl Novel ApproAch to experimeNtAl StudieS of miNerAl diSSolutioN KiNeticS Background DOE is conducting pilot CO 2 injection tests to evaluate the concept of geologic sequestration. One strategy that has the potential to enhance CO 2 solubility and reduce the risk of CO 2 leaking back to the surface is dissolution of indigenous minerals in the geological formation and formation of secondary carbonate precipitates. This both increases the brine pH and immobilizes the CO 2 . Clearly, the rates at which these dissolution and precipitation reactions occur directly determine the efficiency of this option. However, one of the fundamental problems in modern geochemistry is the persistent two to five orders of magnitude discrepancy between laboratory-measured and field-derived

354

Quantum kinetic theory model of a continuous atom laser  

E-Print Network (OSTI)

We investigate the feasible limits for realising a continuously evaporated atom laser with high-temperature sources. A plausible scheme for realising a truly continuous atom laser is to outcouple atoms from a partially condensed Bose gas, whilst continuously reloading the system with non-condensed thermal atoms and performing evaporative cooling. Here we use quantum kinetic theory to model this system and estimate feasible limits for the operation of such a scheme. For sufficiently high temperatures, the figure of merit for the source is shown to be the phase-space flux. The dominant process limiting the usage of sources with low phase-space flux is the three-body loss of the condensed gas. We conclude that certain double-magneto-optical trap (MOT) sources may produce substantial mean condensate numbers through continuous evaporation, and provide an atom laser source with a narrow linewidth and reasonable flux.

G. R. Dennis; Matthew J. Davis; J. J. Hope

2010-11-24T23:59:59.000Z

355

Kinetic Solvers with Adaptive Mesh in Phase Space  

E-Print Network (OSTI)

An Adaptive Mesh in Phase Space (AMPS) methodology has been developed for solving multi-dimensional kinetic equations by the discrete velocity method. A Cartesian mesh for both configuration (r) and velocity (v) spaces is produced using a tree of trees data structure. The mesh in r-space is automatically generated around embedded boundaries and dynamically adapted to local solution properties. The mesh in v-space is created on-the-fly for each cell in r-space. Mappings between neighboring v-space trees implemented for the advection operator in configuration space. We have developed new algorithms for solving the full Boltzmann and linear Boltzmann equations with AMPS. Several recent innovations were used to calculate the full Boltzmann collision integral with dynamically adaptive mesh in velocity space: importance sampling, multi-point projection method, and the variance reduction method. We have developed an efficient algorithm for calculating the linear Boltzmann collision integral for elastic and inelastic...

Arslanbekov, Robert R; Frolova, Anna A

2013-01-01T23:59:59.000Z

356

Advances in petascale kinetic plasma simulation with VPIC and Roadrunner  

SciTech Connect

VPIC, a first-principles 3d electromagnetic charge-conserving relativistic kinetic particle-in-cell (PIC) code, was recently adapted to run on Los Alamos's Roadrunner, the first supercomputer to break a petaflop (10{sup 15} floating point operations per second) in the TOP500 supercomputer performance rankings. They give a brief overview of the modeling capabilities and optimization techniques used in VPIC and the computational characteristics of petascale supercomputers like Roadrunner. They then discuss three applications enabled by VPIC's unprecedented performance on Roadrunner: modeling laser plasma interaction in upcoming inertial confinement fusion experiments at the National Ignition Facility (NIF), modeling short pulse laser GeV ion acceleration and modeling reconnection in magnetic confinement fusion experiments.

Bowers, Kevin J [Los Alamos National Laboratory; Albright, Brian J [Los Alamos National Laboratory; Yin, Lin [Los Alamos National Laboratory; Daughton, William S [Los Alamos National Laboratory; Roytershteyn, Vadim [Los Alamos National Laboratory; Kwan, Thomas J T [Los Alamos National Laboratory

2009-01-01T23:59:59.000Z

357

Consistent description of kinetic equation with triangle anomaly  

SciTech Connect

We provide a consistent description of the kinetic equation with a triangle anomaly which is compatible with the entropy principle of the second law of thermodynamics and the charge/energy-momentum conservation equations. In general an anomalous source term is necessary to ensure that the equations for the charge and energy-momentum conservation are satisfied and that the correction terms of distribution functions are compatible to these equations. The constraining equations from the entropy principle are derived for the anomaly-induced leading order corrections to the particle distribution functions. The correction terms can be determined for the minimum number of unknown coefficients in one charge and two charge cases by solving the constraining equations.

Pu Shi; Gao Jianhua; Wang Qun [Interdisciplinary Center for Theoretical Study and Department of Modern Physics, University of Science and Technology of China, Hefei 230026 (China)

2011-05-01T23:59:59.000Z

358

Propagation of Chaos for a Thermostated Kinetic Model  

E-Print Network (OSTI)

We consider a system of N point particles moving on a d-dimensional torus. Each particle is subject to a uniform field E and random speed conserving collisions. This model is a variant of the Drude-Lorentz model of electrical conduction. In order to avoid heating by the external field, the particles also interact with a Gaussian thermostat which keeps the total kinetic energy of the system constant. The thermostat induces a mean-field type of interaction between the particles. Here we prove that, starting from a product measure, in the large N limit, the one particle velocity distribution satisfies a self consistent Vlasov-Boltzmann equation.. This is a consequence of "propagation of chaos", which we also prove for this model.

F. Bonetto; E. A. Carlen; R. Esposito; J. L. Lebowitz; R. Marra

2013-05-31T23:59:59.000Z

359

Utilization of rotor kinetic energy storage for hybrid vehicles  

DOE Patents (OSTI)

A power system for a motor vehicle having an internal combustion engine, the power system comprises an electric machine (12) further comprising a first excitation source (47), a permanent magnet rotor (28) and a magnetic coupling rotor (26) spaced from the permanent magnet rotor and at least one second excitation source (43), the magnetic coupling rotor (26) also including a flywheel having an inertial mass to store kinetic energy during an initial acceleration to an operating speed; and wherein the first excitation source is electrically connected to the second excitation source for power cycling such that the flywheel rotor (26) exerts torque on the permanent magnet rotor (28) to assist braking and acceleration of the permanent magnet rotor (28) and consequently, the vehicle. An axial gap machine and a radial gap machine are disclosed and methods of the invention are also disclosed.

Hsu, John S. (Oak Ridge, TN)

2011-05-03T23:59:59.000Z

360

Mass independent kinetic energy reducing inlet system for vacuum environment  

Science Conference Proceedings (OSTI)

A particle inlet system comprises a first chamber having a limiting orifice for an incoming gas stream and a micrometer controlled expansion slit. Lateral components of the momentum of the particles are substantially cancelled due to symmetry of the configuration once the laminar flow converges at the expansion slit. The particles and flow into a second chamber, which is maintained at a lower pressure than the first chamber, and then moves into a third chamber including multipole guides for electromagnetically confining the particle. The vertical momentum of the particles descending through the center of the third chamber is minimized as an upward stream of gases reduces the downward momentum of the particles. The translational kinetic energy of the particles is near-zero irrespective of the mass of the particles at an exit opening of the third chamber, which may be advantageously employed to provide enhanced mass resolution in mass spectrometry.

Reilly, Peter T. A. [Knoxville, TN

2010-12-14T23:59:59.000Z

Note: This page contains sample records for the topic "kinetic en ergy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Kinetics of quasi-isoenergetic transition processes in biological macromolecules  

E-Print Network (OSTI)

A master equation describing the evolution of averaged molecular state occupancies in molecular systems where alternation of molecular energy levels is caused by discrete dichotomous and trichotomous stochastic fields, is derived. This study is focused on the kinetics of quasi-isoenergetic transition processes in the presence of moderately high frequency stochastic field. A novel physical mechanism for temperature-independent transitions in flexible molecular systems is proposed. This mechanism becomes effective when the conformation transitions between quasi-isoenergetic molecular states take place. At room temperatures, stochastic broadening of molecular energy levels predominates the energy of low frequency vibrations accompanying the transition. This leads to a cancellation of the temperature dependence in the stochastically averaged rate constants. As examples, physical interpretations of the temperature-independent onset of P2X$_3$ receptor desensitization in neuronal membranes, as well as degradation of PER2 protein in embrionic fibroblasts, are provided.

E. G. Petrov; V. I. Teslenko

2012-12-05T23:59:59.000Z

362

Kinetic Study of the Combustion of Phosphorus Containing Species  

DOE Green Energy (OSTI)

The combustion of organophosphorus compounds is of great interest for the incineration of chemical warfare agent and their use in flame inhibition as halon replacement. The thermochemical data of these species and the reactions involved at high temperature are not well known, despite some recent experimental studies. With BAC-MP4 ab initio estimations as a basis and semi-empirical estimations for many new compounds, the thermochemistry of organophosphorus compounds is studied. New group additivity values are proposed for enthalpies of formation at 298K, entropies and heat capacities of species involving pentavalent phosphorus bonded to carbon, hydrogen, oxygen, fluorine, nitrogen and sulfur atoms. The kinetic of unimolecular elimination is investigated by modeling pyrolysis experiments of DEMP, TEP and DIMP. A new combustion mechanism is described and applied to the modeling of DMMP reaction in a H{sub 2}/O{sub 2} flame.

Glaude, P.A.; Curran, H.J.; Pitz, W.J.; Westbrook, C.K.

1999-10-22T23:59:59.000Z

363

Solids decomposition kinetics for LASL bismuth sulfate cycle  

DOE Green Energy (OSTI)

The LASL Bismuth Sulfate Cycle includes a solid-decomposition step as an alternative to the high-temperature evaporation and decomposition of concentrated sulfuric acid, with its attendant drying and materials problems. A solids decomposition facility was constructed and used to study the handling of solid sulfates and the kinetics of their decomposition. The decomposition of Bi/sub 2/O(SO/sub 4/)/sub 2/ has been measured as a function of temperature and transit time through a laboratory-scale rotary kiln, constructed from quartz. Temperatures from 973 to 1143/sup 0/K were investigated. The transit time was controlled by varying the slope of the kiln, its rotational speed, and the rate of feed of a bismuth oxysulfate prepared in the prescribed manner. The preparation and characterization of this solid, which has reasonable feeding properties and minimal solution retention, are described. Significant amounts of decomposition were measured in short reaction times at the temperatures investigated.

Peterson, C.L.; Bowman, M.G.

1980-01-01T23:59:59.000Z

364

High Temperature Chemical Kinetic Combustion Modeling of Lightly Methylated Alkanes  

DOE Green Energy (OSTI)

Conventional petroleum jet and diesel fuels, as well as alternative Fischer-Tropsch (FT) fuels and hydrotreated renewable jet (HRJ) fuels, contain high molecular weight lightly branched alkanes (i.e., methylalkanes) and straight chain alkanes (n-alkanes). Improving the combustion of these fuels in practical applications requires a fundamental understanding of large hydrocarbon combustion chemistry. This research project presents a detailed high temperature chemical kinetic mechanism for n-octane and three lightly branched isomers octane (i.e., 2-methylheptane, 3-methylheptane, and 2,5-dimethylhexane). The model is validated against experimental data from a variety of fundamental combustion devices. This new model is used to show how the location and number of methyl branches affects fuel reactivity including laminar flame speed and species formation.

Sarathy, S M; Westbrook, C K; Pitz, W J; Mehl, M

2011-03-01T23:59:59.000Z

365

Hybrid fluid/kinetic modeling of Pluto's escaping atmosphere  

E-Print Network (OSTI)

Predicting the rate of escape and thermal structure of Pluto's upper atmosphere in preparation for the New Horizons Spacecraft encounter in 2015 is important for planning and interpreting the expected measurements. Having a moderate Jeans parameter Pluto's atmosphere does not fit the classic definition of Jeans escape for light species escaping from the terrestrial planets, nor does it fit the hydrodynamic outflow from comets and certain exoplanets. It has been proposed for some time that Pluto lies in the region of slow-hydrodynamic escape. Using a hybrid fluid/molecular-kinetic model, we previously demonstrated the typical implementation of this model fails to correctly describe the appropriate temperature structure for the upper atmosphere for solar minimum conditions. Here we used a time-dependent solver to allow us to extend those simulations to higher heating rates and we examined fluid models in which Jeans-like escape expressions are used for the upper boundary conditions. We compare these to our hybr...

Erwin, Justin T; Johnson, Robert E

2012-01-01T23:59:59.000Z

366

Chemical Kinetic Models for HCCI and Diesel Combustion  

DOE Green Energy (OSTI)

Hydrocarbon fuels for advanced combustion engines consist of complex mixtures of hundreds or even thousands of different components. These components can be grouped into a number of chemically distinct classes, consisting of n-paraffins, branched paraffins, cyclic paraffins, olefins, oxygenates, and aromatics. Biodiesel contains its own unique chemical class called methyl esters. The fractional amounts of these chemical classes are quite different in gasoline, diesel fuel, oil-sand derived fuels and bio-derived fuels, which contributes to the very different combustion characteristics of each of these types of combustion systems. The objectives of this project are: (1) Develop detailed chemical kinetic models for fuel components used in surrogate fuels for diesel and HCCI engines; (2) Develop surrogate fuel models to represent real fuels and model low temperature combustion strategies in HCCI and diesel engines that lead to low emissions and high efficiency; and (3) Characterize the role of fuel composition on low temperature combustion modes of advanced combustion engines.

Pitz, W J; Westbook, C K; Mehl, M

2008-10-30T23:59:59.000Z

367

Combined Ideal and Kinetic Effects on Reversed Shear Alfven Eigenmodes  

SciTech Connect

A theory of Reversed Shear Alfven Eigenmodes (RSAEs) is developed for reversed magnetic field shear plasmas when the safety factor minimum, qmin, is at or above a rational value. The modes we study are known sometimes as either the bottom of the frequency sweep or the down sweeping RSAEs. We show that the ideal MHD theory is not compatible with the eigenmode solution in the reversed shear plasma with qmin above integer values. Corrected by special analytic FLR condition MHD dispersion of these modes nevertheless can be developed. Large radial scale part of the analytic RSAE solution can be obtained from ideal MHD and expressed in terms of the Legendre functions. The kinetic equation with FLR effects for the eigenmode is solved numerically and agrees with the analytic solutions. Properties of RSAEs and their potential implications for plasma diagnostics are discussed.

N.N. Gorelenkov, G.J. Kramer, and R. Nazikian

2011-05-23T23:59:59.000Z

368

DNA hybridization kinetics: zippering, internal displacement and sequence dependence  

E-Print Network (OSTI)

While the thermodynamics of DNA hybridization is well understood, much less is known about the kinetics of this classic system. Filling this gap in our understanding has new urgency because DNA nanotechnology often depends critically on binding rates. Here we use a coarse-grained model to explore the hybridization kinetics of DNA oligomers, finding that strand association proceeds through a complex set of intermediate states. Successful binding events start with the formation of a few metastable base-pairing interactions, followed by zippering of the remaining bonds. However, despite reasonably strong interstrand interactions, initial contacts frequently fail to lead to zippering because the typical configurations in which they form differ from typical states of similar enthalpy in the double-stranded equilibrium ensemble. Therefore, if the association process is analyzed on the base-pair (secondary structure) level, it shows non-Markovian behavior. Initial contacts must be stabilized by two or three base pairs before full zippering is likely, resulting in negative effective activation enthalpies. Non-Arrhenius behavior is observed as the number of base pairs in the effective transition state increases with temperature. In addition, we find that alternative pathways involving misbonds can increase association rates. For repetitive sequences, misaligned duplexes frequently rearrange to form fully paired duplexes by two distinct processes which we label `pseudoknot' and `inchworm' internal displacement. We show how the above processes can explain why experimentally observed association rates of GC-rich oligomers are higher than rates of AT-rich equivalents. More generally, we argue that association rates can be modulated by sequence choice.

Thomas E. Ouldridge; Petr ulc; Flavio Romano; Jonathan P. K. Doye; Ard A. Louis

2013-03-14T23:59:59.000Z

369

Gas Kinetic Study of Magnetic Field Effects on Plasma Plumes  

E-Print Network (OSTI)

Plasma flow physics in magnetic nozzles must be clearly understood for optimal design of plasma propulsion devices. Toward that end, in this thesis we: i) perform an extensive literature survey of magnetic nozzle physics, ii) assess the validity of magnetohydrodynamics for studying magnetic nozzle physics, and iii) illustrate the effects of the Hall term in simple flows as well as in magnetic nozzle configurations through numerical experiments with the Magneto-Gas Kinetic Method (MGKM). The crucial steps necessary for thrust generation in magnetic nozzles are energy conversion, plasma detachment, and momentum transfer. These three physical phenomena must be understood to optimize magnetic nozzle design. The operating dimensionless parameter ranges of six prominent experiments are considered and the corresponding mechanisms are discussed. An order of magnitude analysis of the governing equations reveal: i) most magnetic nozzles under consideration operate at the edge of the continuum regime rendering continuum-based description and computation valid; ii) in the context of MHD framework, the generalized Ohms law must be used to capture all of the relevant physics. This work also continues the development of the Magneto Gas Kinetic Method (MGKM) computational tool. Validation of the solver is performed in shock-tube and Hartmann channel flows in the Hall physics regime. Comparison with theory and available data is made whenever possible. Novel numerical experiments of magnetic nozzle plasma jets in the Hall regime are performed, confirming the theoretically predicted azimuthal rotation of the plasma jet due to Hall physics. The primary conclusion from this work is that the addition of the Hall effect generates helical structures in magnetic nozzle plasma flows. Preliminary results are encouraging for future magnetic nozzle studies and further challenges are identified.

Ebersohn, Frans 1987-

2012-12-01T23:59:59.000Z

370

Engineering model reduction of bio-chemical kinetic David Csercsik, Katalin M. Hangos  

E-Print Network (OSTI)

of Hydrosystems Chemical and Thermal Non-Equilibrium: Kinetic Mass & Energy Transfer Motivation Modeling Non is actually driven by difference in chemical potential influence of thermal non-equilibrium on kinetic mass situation of clear non-equilibrium extending range of applicability Support of the German Research

Gorban, Alexander N.

371

Adsorption and desorption kinetics for hydrophilic and hydrophobic vapors on activated carbon  

E-Print Network (OSTI)

]. It is apparent that the LDF kinetic model is applicable for a wide variety of adsorbate­adsorbent systemsAdsorption and desorption kinetics for hydrophilic and hydrophobic vapors on activated carbon are of fundamental importance in applications of adsorbents in real situations. The adsorption/desorption char

Thomas, Mark

372

A First-Passage Kinetic Monte Carlo algorithm for complex diffusion-reaction systems  

Science Conference Proceedings (OSTI)

We develop an asynchronous event-driven First-Passage Kinetic Monte Carlo (FPKMC) algorithm for continuous time and space systems involving multiple diffusing and reacting species of spherical particles in two and three dimensions. The FPKMC algorithm ... Keywords: Asynchronous algorithms, Diffusion-reaction, First-passage, Kinetic Monte Carlo

Aleksandar Donev; Vasily V. Bulatov; Tomas Oppelstrup; George H. Gilmer; Babak Sadigh; Malvin H. Kalos

2010-05-01T23:59:59.000Z

373

Development of a predictive kinetic model for homogeneous Hg oxidation data  

Science Conference Proceedings (OSTI)

Several researchers have developed kinetic models to predict the effects of various flue gas components on homogeneous mercury (Hg) oxidation. Most of these models make use of over 50 reversible reactions that involve radicals in a combustion or post-combustion ... Keywords: Chlorine gas, Homogeneous mercury oxidation, Kinetic model, Simulated flue gas

Hans Agarwal; Harvey G. Stenger

2007-01-01T23:59:59.000Z

374

1 Kinetics of Initial Lithiation of Crystalline Silicon Electrodes of 2 Lithium-Ion Batteries  

E-Print Network (OSTI)

1 Kinetics of Initial Lithiation of Crystalline Silicon Electrodes of 2 Lithium-Ion Batteries 3 the lithiated silicon phase. 20 KEYWORDS: Lithium-ion batteries, silicon, kinetics, plasticity 21 Lithium-ion by the National Science Foundation 648through a grant on Lithium-ion Batteries (CMMI-1031161). 649This work

Liu, X. Shirley

375

THERMALIZATION OF THE ION KINETIC ENERGY IN A Ne GAS PUFF PINCH MODEL*  

E-Print Network (OSTI)

THERMALIZATION OF THE ION KINETIC ENERGY IN A Ne GAS PUFF PINCH MODEL* J. L. Giuliani, J. W Department of Energy/NNSA, Washington DC USA Full understanding of the dynamics, population kinetics, and energy budget of a K-shell radiating Z-pinch remains a challenging problem in high energy density plasma

376

Kinetics of Ni Sorption in Soils: Roles of Soil Organic Matter and Ni Precipitation  

E-Print Network (OSTI)

Aqueous Model (WHAM),6,20 which is able to account for the effects of solution chemistry and SOM WHAM VI was integrated into the kinetics model to account for the effects of SOM concentrations by an electrostatic model built in WHAM VI for cation exchange on clay minerals. Ni precipitation kinetics were

Sparks, Donald L.

377

Detailed chemical kinetic reaction mechanisms for soy and rapeseed biodiesel fuels  

E-Print Network (OSTI)

properties between the two biodiesel fuels, derived from soy and rapeseed oils, are traced to the differencesDetailed chemical kinetic reaction mechanisms for soy and rapeseed biodiesel fuels C.K. Westbrooka chemical kinetic reaction mechanism is developed for the five major components of soy biodiesel

Paris-Sud XI, Université de

378

Efficient kinetic schemes for steady and unsteady flow simulations on unstructured meshes  

Science Conference Proceedings (OSTI)

This paper presents efficient second-order kinetic schemes on unstructured meshes for both compressible unsteady and incompressible steady flows. For compressible unsteady flows, a time-dependent gas distribution function with a discontinuous particle ... Keywords: Compressible unsteady flows, Efficient second-order kinetic schemes, Incompressible steady flows, Unstructured meshes

Guoxi Ni; Song Jiang; Kun Xu

2008-03-01T23:59:59.000Z

379

Molecular-level Thermodynamic and Kinetic Parameters for the Self-assembly of Apoferritin  

E-Print Network (OSTI)

Molecular-level Thermodynamic and Kinetic Parameters for the Self-assembly of Apoferritin Molecules at the molecular level the processes responsible for crystal growth. To evaluate the governing thermodynamic and the molecular-level thermodynamic and kinetic parameters determined here. We found that step growth velocity

Vekilov, Peter

380

Time scales and pathways for kinetic energy relaxation in solvated proteins: Application to carbonmonoxy myoglobin  

E-Print Network (OSTI)

of ki- netic energy equipartitioning compared to that of the hydro- gen atoms. These backbone atomsTime scales and pathways for kinetic energy relaxation in solvated proteins: Application, the rates of kinetic energy partitioning for various elements of solvated carboxy-myoglobin were calculated

Straub, John E.

Note: This page contains sample records for the topic "kinetic en ergy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Sobre la cultura iconogrfica de Cervantes (Ejemplos en el Quijote)  

E-Print Network (OSTI)

rpido efecto. Ya en 1610, Guillen de Castro compone unaacomoda lo que deca C. Guillen al respecto, en el Quijote

Lezcano, Margarita; Rodrguez Cepeda, Enrique

2005-01-01T23:59:59.000Z

382

Nonlinear evolution of the magnetized Kelvin-Helmholtz instability: from fluid to kinetic modeling  

E-Print Network (OSTI)

The nonlinear evolution of collisionless plasmas is typically a multi-scale process where the energy is injected at large, fluid scales and dissipated at small, kinetic scales. Accurately modelling the global evolution requires to take into account the main micro-scale physical processes of interest. This is why comparison of different plasma models is today an imperative task aiming at understanding cross-scale processes in plasmas. We report here the first comparative study of the evolution of a magnetized shear flow, through a variety of different plasma models by using magnetohydrodynamic, Hall-MHD, two-fluid, hybrid kinetic and full kinetic codes. Kinetic relaxation effects are discussed to emphasize the need for kinetic equilibriums to study the dynamics of collisionless plasmas in non trivial configurations. Discrepancies between models are studied both in the linear and in the nonlinear regime of the magnetized Kelvin-Helmholtz instability, to highlight the effects of small scale processes on the nonl...

Henri, P; Califano, F; Pegoraro, F; Rossi, C; Faganello, M; ebek, O; Trvn?ek, P M; Hellinger, P; Frederiksen, J T; Nordlund, ; Markidis, S; Keppens, R; Lapenta, G

2013-01-01T23:59:59.000Z

383

A new water anomaly: the temperature dependence of the proton mean kinetic energy  

E-Print Network (OSTI)

The mean kinetic energy of protons in water is determined by Deep Inelastic Neutron Scattering experiments, performed above and below the temperature of maximum density and in the supercooled phase. The temperature dependence of this energy shows an anomalous behavior, as it occurs for many water properties. In particular two regions of maximum kinetic energy are identified: the first one, in the supercooled phase in the range 269 K - 272 K, and a second one above 273 K. In both these regions the measured proton kinetic energy exceedes the theoretical prediction based on a semi-classical model. Noteworthy, the proton mean kinetic energy has a maximum at 277 K, the temperature of the maximum density of water. In the supercooled metastable phase the measured mean kinetic energy and the proton momentum distribution clearly indicate proton delocalization between two H-bonded oxygens.

Davide Flammini; Fabio Bruni; Maria Antonietta Ricci

2009-01-27T23:59:59.000Z

384

Effects of adsorbed water vapor on the Wheeler kinetic rate constant and kinetic adsorption capacity for activated carbon adsorbents  

SciTech Connect

Activated carbon plays a key role reducing organic vapor emissions to the environment from synthetic chemical manufacturing, pesticide manufacturing, in odor control, for removal of contaminant vapors during remediation of hazardous waste sites, and as an adsorption matrix for collection of organic vapors from ambient air in occupational and environmental settings to assess exposure. The Wheeler dynamic adsorption model has been evaluated under laboratory conditions and has shown potential for predicting activated carbon bed penetration. Water vapor is a normal constituent of ambient air that is present at concentrations 1-2 orders of magnitude greater than the concentrations of potentially toxic air contaminants. Many investigations have shown that adsorbed water vapor can reduce the breakthrough-time of activated charcoal beds. The effect of adsorbed water vapor on the predictive power of the Wheeler model has not been evaluated. The research evaluated the effect of water vapor adsorbed on activated charcoal on the subsequent adsorption of four air contaminants, carbon tetrachloride, 1,1,1-trichloroethane, 1,1,2-trichloroethylene, and 1-propanol. The adsorbent used in this research had a large surface area, 1200 m[sup 2]/g and that 95% of the surface area was associated with micropores (pores with diameters less than 2 micrometers). Kinetic adsorption capacities for all four adsorbates were not affected by the presence of water vapor except for some observed enhancement. The kinetic trial data suggest that the primary effect of adsorbed water vapor was to reduce the effective pore radius of the smaller mesopores thus restricting pore diffusion. This results in an increase in the critical bed capacity with shorter breakthrough times for adsorbent beds.

Hall, T.A.

1992-01-01T23:59:59.000Z

385

1 0 clueweb09-en0120-13-20479 0 1 1 clueweb09-en0120 ...  

Science Conference Proceedings (OSTI)

1 0 clueweb09-en0120-13-20479 0 1 1 clueweb09-en0120-13-20479 0 1 2 clueweb09-en0120-13-20479 0 1 3 clueweb09-en0120-13-20479 0 1 ...

2012-02-28T23:59:59.000Z

386

A Novel Approach to Experimental Studies of Mineral Dissolution Kinetics  

SciTech Connect

Currently, DOE is conducting pilot CO{sub 2} injection tests to evaluate the concept of geological sequestration. The injected CO{sub 2} is expected to react with the host rocks and these reactions can potentially alter the porosity, permeability, and mechanical properties of the host or cap rocks. Reactions can also result in precipitation of carbonate-containing minerals that favorably and permanently trap CO{sub 2} underground. Many numerical models have been used to predict these reactions for the carbon sequestration program. However, a firm experimental basis for predicting silicate reaction kinetics in CO{sub 2} injected geological formations is urgently needed to assure the reliability of the geochemical models used for the assessments of carbon sequestration strategies. The funded experimental and theoretical study attempts to resolve this outstanding scientific issue by novel experimental design and theoretical interpretation of silicate dissolution rates at conditions pertinent to geological carbon sequestration. In this four year research grant (three years plus a one year no cost extension), seven (7) laboratory experiments of CO{sub 2}-rock-water interactions were carried out. An experimental design allowed the collection of water samples during experiments in situ and thus prevented back reactions. Analysis of the in situ samples delineated the temporal evolution of aqueous chemistry because of CO{sub 2}-rock-water interactions. The solid products of the experiments were retrieved at the end of the experimental run, and analyzed with a suite of advanced analytical and electron microscopic techniques (i.e., atomic resolution transmission electron microscopy (TEM), scanning electron microscopy (SEM), electron microprobe, X-ray diffraction, X-ray photoelectron spectroscopy (XPS)). As a result, the research project probably has produced one of the best data sets for CO{sub 2}-rock-water interactions in terms of both aqueous solution chemistry and solid characterization. Three experiments were performed using the Navajo sandstone. Navajo sandstone is geologically equivalent to the Nugget sandstone, which is a target formation for a regional partnership injection project. Our experiments provided the experimental data on the potential CO{sub 2}-rock-water interactions that are likely to occur in the aquifer. Geochemical modeling was performed to interpret the experimental results. Our single mineral (feldspar) experiments addressed a basic research need. i.e., the coupled nature of dissolution and precipitation reactions, which has universal implication to the reaction kinetics as it applied to CO{sub 2} sequestration. Our whole rock experiments (Navajo sandstone) addressed the applied research component, e.g., reacting Navajo sandstone with brine and CO{sub 2} has direct relevance on the activities of a number of regional partnerships. The following are the major findings from this project: (1) The project generated a large amount of experimental data that is central to evaluating CO{sub 2}-water-rock interactions and providing ground truth to predictive models, which have been used and will inevitably be increasingly more used in carbon sequestration. (2) Results from the feldspar experiments demonstrated stronger coupling between dissolution and precipitation reactions. We show that the partial equilibrium assumption did not hold in the feldspar hydrolysis experiments (Zhu and Lu, submitted, Appendix A-2). The precipitation of clay minerals influenced dissolution of primary silicate in a much stronger way as previously envisioned. Therefore, our experimental data indicated a much more complex chemical kinetics as it has been applied to carbon sequestration program in terms of preliminary predictive models of CO{sub 2}-rock-water interactions. Adopting this complexity (strong coupling) may influence estimates of mineral trapping and porosity/permeability for geological carbon sequestration. In general, our knowledge of the coupling of different reactions is poor, and we must consider the uncertainties resultin

Chen Zhu

2008-08-31T23:59:59.000Z

387

A new class of accelerated kinetic Monte Carlo algorithms  

Science Conference Proceedings (OSTI)

Kinetic (aka dynamic) Monte Carlo (KMC) is a powerful method for numerical simulations of time dependent evolution applied in a wide range of contexts including biology, chemistry, physics, nuclear sciences, financial engineering, etc. Generally, in a KMC the time evolution takes place one event at a time, where the sequence of events and the time intervals between them are selected (or sampled) using random numbers. While details of the method implementation vary depending on the model and context, there exist certain common issues that limit KMC applicability in almost all applications. Among such is the notorious 'flicker problem' where the same states of the systems are repeatedly visited but otherwise no essential evolution is observed. In its simplest form the flicker problem arises when two states are connected to each other by transitions whose rates far exceed the rates of all other transitions out of the same two states. In such cases, the model will endlessly hop between the two states otherwise producing no meaningful evolution. In most situation of practical interest, the trapping cluster includes more than two states making the flicker somewhat more difficult to detect and to deal with. Several methods have been proposed to overcome or mitigate the flicker problem, exactly [1-3] or approximately [4,5]. Of the exact methods, the one proposed by Novotny [1] is perhaps most relevant to our research. Novotny formulates the problem of escaping from a trapping cluster as a Markov system with absorbing states. Given an initial state inside the cluster, it is in principle possible to solve the Master Equation for the time dependent probabilities to find the walker in a given state (transient or absorbing) of the cluster at any time in the future. Novotny then proceeds to demonstrate implementation of his general method to trapping clusters containing the initial state plus one or two transient states and all of their absorbing states. Similar methods have been subsequently proposed in [refs] but applied in a different context. The most serious deficiency of the earlier methods is that size of the trapping cluster size is fixed and often too small to bring substantial simulation speedup. Furthermore, the overhead associated with solving for the probability distribution on the trapping cluster sometimes makes such simulations less efficient than the standard KMC. Here we report on a general and exact accelerated kinetic Monte Carlo algorithm generally applicable to arbitrary Markov models1. Two different implementations are attempted both based on incremental expansion of trapping sub-set of Markov states: (1) numerical solution of the Master Equation with absorbing states and (2) incremental graph reduction followed by randomization. Of the two implementations, the 2nd one performs better allowing, for the first time, to overcome trapping basins spanning several million Markov states. The new method is used for simulations of anomalous diffusion on a 2D substrate and of the kinetics of diffusive 1st order phase transformations in binary alloys. Depending on temperature and (alloy) super-saturation conditions, speedups of 3 to 7 orders of magnitude are demonstrated, with no compromise of simulation accuracy.

Bulatov, V V; Oppelstrup, T; Athenes, M

2011-11-30T23:59:59.000Z

388

MotorWeek Videos en espaol  

NLE Websites -- All DOE Office Websites (Extended Search)

(52.1 MB) Versin en Texto (pdf) Hbridos Elctricos Enchufables Hbridos Elctricos Enchufables Flash (35.0 MB) Flota CNG Flota CNG Flash (33.7 MB) Versin en Texto (pdf)...

389

Pattern Formation and Growth Kinetics in Eutectic Systems  

Science Conference Proceedings (OSTI)

Growth patterns during liquid/solid phase transformation are governed by simultaneous effects of heat and mass transfer mechanisms, creation of new interfaces, jump of the crystallization units from liquid to solid and their rearrangement in the solid matrix. To examine how the above processes influence the scale of microstructure, two eutectic systems are chosen for the study: a polymeric system polyethylene glycol-p-dibromobenzene (PEG-DBBZ) and a simple molecular system succinonitrile (SCN)-camphor. The scaling law for SCN-camphor system is found to follow the classical Jackson-Hunt model of circular rod eutectic, where the diffusion in the liquid and the interface energy are the main physics governing the two-phase pattern. In contrast, a significantly different scaling law is observed for the polymer system. The interface kinetics of PEG phase and its solute concentration dependence thus have been critically investigated for the first time by directional solidification technique. A model is then proposed that shows that the two-phase pattern in polymers is governed by the interface diffusion and the interface kinetics. In SCN-camphor system, a new branch of eutectic, elliptical shape rodl, is found in thin samples where only one layer of camphor rods is present. It is found that the orientation of the ellipse can change from the major axis in the direction of the thickness to the direction of the width as the velocity and/or the sample thickness is decreased. A theoretical model is developed that predicts the spacing and orientation of the elliptical rods in a thin sample. The single phase growth patterns of SCN-camphor system were also examined with emphasis on the three-dimensional single cell and cell/dendrite transition. For the 3D single cell in a capillary tube, the entire cell shape ahead of the eutectic front can be described by the Saffmann-Taylor finger only at extremely low growth rate. A 3D directional solidification model is developed to characterize the cell shape and tip undercooling and the experimental results are compared with the predictions of the model. From the investigation of cell/dendrite transition, a model is proposed, from which the condition for the onset of the transition can be obtained.

Jing Teng

2007-12-01T23:59:59.000Z

390

Constructive Methods of Invariant Manifolds for Kinetic Problems  

E-Print Network (OSTI)

We present the Constructive Methods of Invariant Manifolds for model reduction in physical and chemical kinetics, developed during last two decades. The problem of reduced description is studied as a problem of constructing the slow invariant manifold. The invariance conditions are formulated as the differential equation for a manifold immersed in the phase space (the invariance equation). The equation of motion for immersed manifolds is obtained (the film extension of the dynamics). Invariant manifolds are fixed points for this equation, and slow invariant manifolds are Lyapunov stable fixed points, thus slowness is presented as stability. A collection of methods for construction of slow invariant manifolds is presented, in particular the analogue of KAM methods for dissipative systems. We systematically consider a discrete analogue of the slow (stable) positively invariant manifolds for dissipative systems, invariant grids. The following examples of applications are presented: Nonperturbative deviation of physically consistent hydrodynamics from the Boltzmann equation and from the reversible dynamics, for Knudsen numbers ~ 1; construction of the moment equations for nonequilibrium media and their dynamical correction (instead of extension of list of variables) to gain more accuracy in description of highly nonequilibrium flows; invariant grids for chemical reactions; universal continuous media description of dilute polymeric solution, etc.

A. N. Gorban; I. V. Karlin; A. Yu. Zinovyev

2003-11-02T23:59:59.000Z

391

Simplified jet-A kinetic mechanism for combustor application  

SciTech Connect

Successful modeling of combustion and emissions in gas turbine engine combustors requires an adequate description of the reaction mechanism. For hydrocarbon oxidation, detailed mechanisms are only available for the simplest types of hydrocarbons such as methane, ethane, acetylene, and propane. These detailed mechanisms contain a large number of chemical species participating simultaneously in many elementary kinetic steps. Current computational fluid dynamic (CFD) models must include fuel vaporization, fuel-air mixing, chemical reactions, and complicated boundary geometries. To simulate these conditions a very sophisticated computer model is required, which requires large computer memory capacity and long run times. Therefore, gas turbine combustion modeling has frequently been simplified by using global reaction mechanisms, which can predict only the quantities of interest: heat release rates, flame temperature, and emissions. Jet fuels are wide-boiling-range hydrocarbons with ranges extending through those of gasoline and kerosene. These fuels are chemically complex, often containing more than 300 components. Jet fuel typically can be characterized as containing 70 vol pct paraffin compounds and 25 vol pct aromatic compounds. A five-step Jet-A fuel mechanism which involves pyrolysis and subsequent oxidation of paraffin and aromatic compounds is presented here. This mechanism is verified by comparing with Jet-A fuel ignition delay time experimental data, and species concentrations obtained from flametube experiments. This five-step mechanism appears to be better than the current one- and two-step mechanisms.

Lee, Chiming; Kundu, K.; Ghorashi, B.

1993-01-01T23:59:59.000Z

392

Stochastic cooling of bunched beams from fluctuation and kinetic theory  

Science Conference Proceedings (OSTI)

A theoretical formalism for stochastic phase-space cooling of bunched beams in storage rings is developed on the dual basis of classical fluctuation theory and kinetic theory of many-body systems in phase-space. The physics is that of a collection of three-dimensional oscillators coupled via retarded nonconservative interactions determined by an electronic feedback loop. At the heart of the formulation is the existence of several disparate time-scales characterizing the cooling process. Both theoretical approaches describe the cooling process in the form of a Fokker-Planck transport equation in phase-space valid up to second order in the strength and first order in the auto-correlation of the cooling signal. With neglect of the collective correlations induced by the feedback loop, identical expressions are obtained in both cases for the coherent damping and Schottky noise diffusion coefficients. These are expressed in terms of Fourier coefficients in a harmonic decomposition in angle of the generalized nonconservative cooling force written in canonical action-angle variables of the particles in six-dimensional phase-space. Comparison of analytic results to a numerical simulation study with 90 pseudo-particles in a model cooling system is presented.

Chattopadhyay, S.

1982-09-01T23:59:59.000Z

393

Kinetic Modeling of Combustion Characteristics of Real Biodiesel Fuels  

DOE Green Energy (OSTI)

Biodiesel fuels are of much interest today either for replacing or blending with conventional fuels for automotive applications. Predicting engine effects of using biodiesel fuel requires accurate understanding of the combustion characteristics of the fuel, which can be acquired through analysis using reliable detailed reaction mechanisms. Unlike gasoline or diesel that consists of hundreds of chemical compounds, biodiesel fuels contain only a limited number of compounds. Over 90% of the biodiesel fraction is composed of 5 unique long-chain C{sub 18} and C{sub 16} saturated and unsaturated methyl esters. This makes modeling of real biodiesel fuel possible without the need for a fuel surrogate. To this end, a detailed chemical kinetic mechanism has been developed for determining the combustion characteristics of a pure biodiesel (B100) fuel, applicable from low- to high-temperature oxidation regimes. This model has been built based on reaction rate rules established in previous studies at Lawrence Livermore National Laboratory. Computed results are compared with the few fundamental experimental data that exist for biodiesel fuel and its components. In addition, computed results have been compared with experimental data for other long-chain hydrocarbons that are similar in structure to the biodiesel components.

Naik, C V; Westbrook, C K

2009-04-08T23:59:59.000Z

394

Kinetic effects on robustness of electron magnetohydrodynamic structures  

SciTech Connect

Following recent remarkable progress in the development of high-power short-pulse lasers, exploration is ongoing into hitherto unknown phenomena at fast time scales of electrons, the understanding of which is becoming crucial. For a simplified description of such phenomena, the Electron Magnetohydrodynamics (EMHDs) fluid description is often adopted. For the possibility of electron transport in high-density plasma, exact solutions of the EMHD model in the form of electron vortex currents, together with their associated magnetic fields, have been considered. However, the fluid EMHD model does not incorporate kinetic effects. Here, the finite Larmor radius effects owing to a finite electron temperature on the robustness of the exact EMHD structures are investigated using two-dimensional particle-in-cell simulations. It is found that larger EMHD vortex structures can sustain themselves for long periods, even in high temperature plasma; however, sustaining structures at higher temperatures tends to be difficult. With increasing temperature, electrons with finite Larmor radii become disengaged from the localized region. It is also shown that structures localized in smaller regions are more difficult to sustain. A quantitative criterion in terms of the structure size and Larmor radius has been established by simulations over a wide range of parameters. Finally, we conclude that a structure, larger than about eight times the typical Larmor radius at r=R, could form and exist even under the effects of finite electron temperature.

Hata, M. [Department of Physics, Nagoya University, Nagoya 464-8603 (Japan); Sakagami, H. [Fundamental Physics Simulation Research Division, National Institute for Fusion Science, Toki 509-5292 (Japan); Das, A. [Institute for Plasma Research, Bhat, Gandhinagar 382428 (India)

2013-04-15T23:59:59.000Z

395

CURRENT SHEETS AND COLLISIONLESS DAMPING IN KINETIC PLASMA TURBULENCE  

SciTech Connect

We present the first study of the formation and dissipation of current sheets at electron scales in a wave-driven, weakly collisional, three-dimensional kinetic turbulence simulation. We investigate the relative importance of dissipation associated with collisionless damping via resonant wave-particle interactions versus dissipation in small-scale current sheets in weakly collisional plasma turbulence. Current sheets form self-consistently from the wave-driven turbulence, and their filling fraction is well correlated to the electron heating rate. However, the weakly collisional nature of the simulation necessarily implies that the current sheets are not significantly dissipated via Ohmic dissipation. Rather, collisionless damping via the Landau resonance with the electrons is sufficient to account for the measured heating as a function of scale in the simulation, without the need for significant Ohmic dissipation. This finding suggests the possibility that the dissipation of the current sheets is governed by resonant wave-particle interactions and that the locations of current sheets correspond spatially to regions of enhanced heating.

TenBarge, J. M.; Howes, G. G., E-mail: jason-tenbarge@uiowa.edu [Department of Physics and Astronomy, University of Iowa, Iowa City, IA 52242 (United States)

2013-07-10T23:59:59.000Z

396

Gasification characteristics and kinetics for an Eastern oil shale  

DOE Green Energy (OSTI)

Gasification reactivity of an Eastern oil shale was studied in a three-year research project under a cooperative agreement between the Department of Energy, Morgantown Energy Technology Center, and HYCRUDE Corp. to expand the data base on the hydroretorting of Eastern oil shales. Gasification tests were conducted with the Indiana New Albany oil shale during the first year of the program. A total of six Eastern oil shales are planned to be tested during the program. A laboratory thermobalance and a 2-inch diameter fluidized bed were used to conduct gasification tests with Indiana New Albany oil shale. Temperature and pressure ranges used were 1600 to 1900/sup 0/F and 15 to 500 psig, respectively. Fifteen thermobalance tests were made in hydrogen/steam and synthesis gas/steam mixtures. Six fluidized-bed tests were made in the same synthesis gas/steam mixture. Carbon conversions as high as 95% were achieved. Thermobalance test results and a kinetic description of weight loss during hydrogen/steam gasification are presented. 14 refs., 6 figs., 4 tabs.

Lau, F.S.; Rue, D.M.; Punwani, D.V.; Rex, R.C. Jr.

1987-01-01T23:59:59.000Z

397

Plasma transport induced by kinetic Alfven wave turbulence  

SciTech Connect

At the Earth's magnetopause that separates the hot-tenuous magnetospheric plasma from the cold dense solar wind plasma, often seen is a boundary layer where plasmas of both origins coexist. Plasma diffusions of various forms have been considered as the cause of this plasma mixing. Here, we investigate the plasma transport induced by wave-particle interaction in kinetic Alfven wave (KAW) turbulence, which is one of the candidate processes. We clarify that the physical origin of the KAW-induced cross-field diffusion is the drift motions of those particles that are in Cerenkov resonance with the wave: E Multiplication-Sign B-like drift that emerges in the presence of non-zero parallel electric field component and grad-B drift due to compressional magnetic fluctuations. We find that KAW turbulence, which has a spectral breakpoint at which an MHD inertial range transits to a dissipation range, causes selective transport for particles whose parallel velocities are specified by the local Alfven velocity and the parallel phase velocity at the spectral breakpoint. This finding leads us to propose a new data analysis method for identifying whether or not a mixed plasma in the boundary layer is a consequence of KAW-induced transport across the magnetopause. The method refers to the velocity space distribution function data obtained by a spacecraft that performs in situ observations and, in principle, is applicable to currently available dataset such as that provided by the NASA's THEMIS mission.

Izutsu, T. [Department of Earth and Planetary Science, University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 133-0033 (Japan); Institute of Space and Astronautical Science, Japan Aerospace Exploration Agency, 3-1-1 Yoshinodai, Chuo-ku, Sagamihara, Kanagawa 252-5210 (Japan); Hasegawa, H.; Fujimoto, M. [Institute of Space and Astronautical Science, Japan Aerospace Exploration Agency, 3-1-1 Yoshinodai, Chuo-ku, Sagamihara, Kanagawa 252-5210 (Japan); Nakamura, T. K. M. [X-Computational Physics Division, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States)

2012-10-15T23:59:59.000Z

398

Carbon-13 kinetic isotope effects in CO oxidation by Ag  

SciTech Connect

In the catalytic oxidation of carbon monoxide over silver wool the {sup 13}C kinetic isotope effects in the 343--453 K temperature range were experimentally determined and the following temperature dependence was found: 100 ln(k{sub 12}/k{sub 13}) = (3.398--630/T) {+-} 0.083. A reaction CO/O{sub 2}gas mixture of 1:2 ratio was used in a static system with initial pressures ranging from 20 to 40 kPa. Under these conditions the reaction is of order 1 with respect to CO and order 0 with respect to O{sub 2} and CO{sub 2} pressure. The apparent activation energy is 59.3 {+-} 1.7 kJ/mol. In the authors theoretical interpretation of the experimental data various geometries of (CO{sub 2})* and (CO{sub 3})* transition states were applied, and only a (CO{sub 2})* with an interbond angle of 110{degree} and CO stretching force constants of 1,700 and 1,000--1,400 N/m, respectively, with an asymmetric reaction coordinate was found to be acceptable.

Kobal, I.; Burghaus, U.; Senegacnik, M.; Ogrinc, N.

1999-08-31T23:59:59.000Z

399

Biological conversion of synthesis gas. Mass transfer/kinetic studies  

DOE Green Energy (OSTI)

Mass transfer and kinetic studies were carried out for the Rhodospirillum rubrum and Chlorobium thiosulfatophilum bacterial systems. R. rubrum is a photosynthetic anaerobic bacterium which catalyzes the biological water gas shift reaction: CO + H{sub 2}0 {yields} CO{sub 2} + H{sub 2}. C. thiosulfatophilum is also a H{sub 2}S and COS to elemental sulfur. The growth of R. rubrum may be satisfactorily carried out at 25{degree} and 30{degree}C, while CO uptake and thus the conversion of CO best occurs at temperatures of either 30{degree}, 32{degree} or 34{degree}C. The rate of conversion of COs and H{sub 2}O to CO{sub 2} and H{sub 2}S may be modeled by a first order rate expression. The rate constant at 30{degree}C was found to be 0.243 h{sup {minus}1}. The growth of C. thiosulfatophilum may be modeled in terms of incoming light intensity using a Monod equation: {mu} = {sub 351} + I{sub o}/{sup 0.152}I{sub o}. Comparisons of the growth of R. rubrum and C. thiosulfatophilum shows that the specific growth rate of C. thiosulfatophilum is much higher at a given light intensity.

Klasson, K.T.; Basu, R.; Johnson, E.R.; Clausen, E.C.; Gaddy, J.L.

1992-03-01T23:59:59.000Z

400

Detailed and global chemical kinetics model for hydrogen  

DOE Green Energy (OSTI)

Detailed and global chemical kinetic computations for hydrogen-air mixtures have been performed to describe flame propagation, flame structure and ignition phenomena. Simulations of laminar flame speeds, flame compositions and shock tube ignition delay times have been successfully performed. Sensitivity analysis was applied to determine the governing rate-controlling reactions for the experimental data sets examined. In the flame propagation and structure studies, the reactions, OH + H{sub 2} = H{sub 2}0 + H, 0 + H{sub 2} = OH + H and 0 + OH = 0{sub 2} + H were the most important in flames. The shock tube ignition delay time study indicated the H + 0{sub 2} + M = H0{sub 2} + M (M = N{sub 2}, H{sub 2}) and 0 + OH = 0{sub 2} + H reactions controlled ignition. A global rate expression for a one-step overall reaction was developed and validated against experimental hydrogen-air laminar flame speed data. The global reaction expression was determined to be 1.8 {times} 10{sup 13} exp({minus}17614K/T)[H{sub 2}]{sup 1.0}[O{sub 2}]{sup 0.5} for the single step reaction H{sub 2} + 1/2O{sub 2} = H{sub 2}O.

Marinov, N.M.; Westbrook, C.K.; Pitz, W.J.

1995-03-01T23:59:59.000Z

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401

Complex (dusty) plasmas-kinetic studies of strong coupling phenomena  

SciTech Connect

'Dusty plasmas' can be found almost everywhere-in the interstellar medium, in star and planet formation, in the solar system in the Earth's atmosphere, and in the laboratory. In astrophysical plasmas, the dust component accounts for only about 1% of the mass, nevertheless this component has a profound influence on the thermodynamics, the chemistry, and the dynamics. Important physical processes are charging, sputtering, cooling, light absorption, and radiation pressure, connecting electromagnetic forces to gravity. Surface chemistry is another important aspect. In the laboratory, there is great interest in industrial processes (e.g., etching, vapor deposition) and-at the fundamental level-in the physics of strong coupling phenomena. Here, the dust (or microparticles) are the dominant component of the multi-species plasma. The particles can be observed in real time and space, individually resolved at all relevant length and time scales. This provides an unprecedented means for studying self-organisation processes in many-particle systems, including the onset of cooperative phenomena. Due to the comparatively large mass of the microparticles (10{sup -12}to10{sup -9}g), precision experiments are performed on the ISS. The following topics will be discussed: Phase transitions, phase separation, electrorheology, flow phenomena including the onset of turbulence at the kinetic level.

Morfill, Gregor E.; Ivlev, Alexei V.; Thomas, Hubertus M. [Max-Planck-Institut fuer Extraterrestrische Physik, D-85740 Garching (Germany)

2012-05-15T23:59:59.000Z

402

Thermodynamics and Kinetics of Carbon Dioxide Binding to Two Stereoisomers  

NLE Websites -- All DOE Office Websites (Extended Search)

Binding to Stereoisomers of a Cobalt(I) Macrocycle Binding to Stereoisomers of a Cobalt(I) Macrocycle Carol Creutz, Harold A. Schwarz, James F. Wishart, Etsuko Fujita and Norman Sutin J. Am. Chem. Soc. 113, 3361-3371 (1991) Abstract: The thermodynamics and kinetics of binding of CO2, CO, and H+ to N-racemic and N-meso stereoisomers of the cobalt(I) macrocycle CoL+ (L=5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacyclotetradeca-4,11-diene) have been determined in aqueous media with use of the pulse radiolysis technique and transient ultraviolet-visible spectroscopy. N-rac or N-meso-CoL+ was produced by the hydrated electron reduction of N-rac or N-meso-CoL2+, with tert-butyl alcohol generally added to scavenge hydroxyl radicals. Reactions of both N-rac- and N-meso CoL+ are readily followed by the disappearance of intense ([epsilon] 1 x 104 M-1 cm-1) absorption bands

403

Reduced and Validated Kinetic Mechanisms for Hydrogen-CO-sir Combustion in Gas Turbines  

DOE Green Energy (OSTI)

Rigorous experimental, theoretical, and numerical investigation of various issues relevant to the development of reduced, validated kinetic mechanisms for synthetic gas combustion in gas turbines was carried out - including the construction of new radiation models for combusting flows, improvement of flame speed measurement techniques, measurements and chemical kinetic analysis of H{sub 2}/CO/CO{sub 2}/O{sub 2}/diluent mixtures, revision of the H{sub 2}/O{sub 2} kinetic model to improve flame speed prediction capabilities, and development of a multi-time scale algorithm to improve computational efficiency in reacting flow simulations.

Yiguang Ju; Frederick Dryer

2009-02-07T23:59:59.000Z

404

Time-dependent corrections to effective rate and event statistics in Michaelis-Menten kinetics  

E-Print Network (OSTI)

We generalize the concept of the geometric phase in stochastic kinetics to a noncyclic evolution. Its application is demonstrated on kinetics of the Michaelis-Menten reaction. It is shown that the nonperiodic geometric phase is responsible for the correction to the Michaelis-Menten law when parameters, such as a substrate concentration, are changing with time. We apply these ideas to a model of chemical reactions in a bacterial culture of a growing size, where the geometric correction qualitatively changes the outcome of the reaction kinetics.

Sinitsyn, N A

2010-01-01T23:59:59.000Z

405

Autoignition chemistry of the hexane isomers: An experimental and kinetic modeling study  

DOE Green Energy (OSTI)

Autoignition of the five distinct isomers of hexane is studied experimentally under motored engine conditions and computationally using a detailed chemical kinetic reaction mechanism. Computed and experimental results are compared and used to help understand the chemical factors leading to engine knock in spark-ignited engines and the molecular structure factors contributing to octane rating for hydrocarbon fuels. The kinetic model reproduces observed variations in critical compression ratio with fuel structure, and it also provides intermediate and final product species concentrations in very dose agreement with observed results. In addition, the computed results provide insights into the kinetic origins of fuel octane sensitive.

Curran, H.J.; Gaffuri, P.; Pitz, W.J.; Westbrook, C.K. [Lawrence Livermore National Lab., CA (United States); Leppard, W.R. [General Motors Research Labs., Warren, MI (United States)

1995-06-01T23:59:59.000Z

406

Mundos en Granos de Arena: Estudios en el Infrarrojo de  

E-Print Network (OSTI)

habituales en un gas macrosc??opico n # NA /22,4l = 2,7?10 25 m -3 y usamos la masa del gas hidr??ogeno, H 2 a la cin??etica. De hecho, la mayor??�a de gases (incluyendo el hidr??ogeno) son ya s??olidos a esas

Moro-Martin, Amaya

407

NETL: C&CBTL - Development of Kinetics and Mathematical Models for High  

NLE Websites -- All DOE Office Websites (Extended Search)

Kinetics and Mathematical Models for High Pressure Gasification of Lignite-Switchgrass Blends Kinetics and Mathematical Models for High Pressure Gasification of Lignite-Switchgrass Blends Georgia Tech Research Corporation Project Number: FE0005339 Project Description The objectives of the proposed study are to obtain experimental reactor data and develop kinetic rate expressions for pyrolysis and char gasification for the coal-biomass blends under conditions free from transport limitations, to develop a detailed understanding of the effect of pyrolysis conditions on the porous char structure, to build mathematical models that combine true kinetic rate expressions with transport models for predicting gasification behavior for a broad range of pressures and temperatures, and to investigate the physical and chemical parameters that might lead to synergistic effects in coal-biomass blends gasification.

408

January 28, 2011 Kinetic Isotope Effects Predicted Correctly for a Mass Ratio of 36  

E-Print Network (OSTI)

January 28, 2011 Kinetic Isotope Effects Predicted Correctly for a Mass, and it has chemical properties very similar to a hydrogen atom, but very large), and the dynamics was thermally averaged to yield temperature-dependent chemical reaction rate

Truhlar, Donald G

409

Budgets of Divergent and Rotational Kinetic Energy during Two Periods of Intense Convection  

Science Conference Proceedings (OSTI)

Budgets of divergent and rotational components of kinetic energy (KD and KR) are investigated for two periods of intense convection. Derivations of the budget equations are presented for limited volumes in terms of VD and VR. The two periods ...

Dennis E. Buechler; Henry E. Fuelberg

1986-01-01T23:59:59.000Z

410

Seasonal and Spatial Variability of Near-Inertial Kinetic Energy from Historical Moored Velocity Records  

Science Conference Proceedings (OSTI)

Temporal and spatial patterns of near-inertial kinetic energy (KEmoor) are investigated in a database of 2480 globally distributed, moored current-meter records (deployed on 690 separate moorings) and compared with the distribution of wind-forced ...

Matthew H. Alford; Maya Whitmont

2007-08-01T23:59:59.000Z

411

A Surface Flux Parameterization Based on the Vertically Averaged Turbulence Kinetic Energy  

Science Conference Proceedings (OSTI)

A new bulk transfer formulation for the surface turbulent fluxes of momentum, heat, and moisture has been developed by using the square root of the vertically averaged turbulent kinetic energy (TKE) in the atmospheric boundary layer as a velocity ...

Changan Zhang; David A. Randall; Chin-Hoh Moeng; Mark Branson; Kerry A. Moyer; Qing Wang

1996-11-01T23:59:59.000Z

412

Heating and Kinetic Energy Dissipation in the NCAR Community Atmosphere Model  

Science Conference Proceedings (OSTI)

Conservation of energy and the incorporation of parameterized heating in an atmospheric model are discussed. Energy conservation is used to unify the treatment of heating and kinetic energy dissipation within the Community Atmosphere Model, ...

Byron A. Boville; Christopher S. Bretherton

2003-12-01T23:59:59.000Z

413

Measurement of Turbulent Kinetic Energy Dissipation Rate with a Lagrangian Float  

Science Conference Proceedings (OSTI)

This study tests the ability of a neutrally buoyant float to estimate the dissipation rate of turbulent kinetic energy ? from its vertical acceleration spectrum using an inertial subrange method. A Lagrangian float was equipped with a SonTek ...

Ren-Chieh Lien; Eric A. D'Asaro

2006-07-01T23:59:59.000Z

414

The Kinetic Energy Budgets of Two Severe Storm Producing Extratropical Cyclones  

Science Conference Proceedings (OSTI)

Eulerian kinetic energy budgets for the synoptic-scale flow over North America were computed for two cases of cyclone development associated with severe prefrontal convection. Horizontal flux convergence constitutes the major energy source in ...

Franklin R. Robertson; Phillip J. Smith

1980-02-01T23:59:59.000Z

415

An Approach to Kinetic Energy Diagnosis of MesoSynoptic Scale interactions  

Science Conference Proceedings (OSTI)

To explicitly describe the energy exchange between meso and synoptic-scale motions, a diagnostic scheme of kinetic energy has been developed. By using a horizontal filtering technique, meteorological variables are separated into synoptic and ...

Shou-Jun Chen; Le-Sheng Bai; Ernest C. Kung

1990-12-01T23:59:59.000Z

416

Pyrolysis kinetics of scrap tire rubbers. 1: Using DTG and TGA  

Science Conference Proceedings (OSTI)

Tire pyrolysis kinetics was investigated to explore an economically viable design for the pyrolysis process. Derivative thermogravimetry (DTG) and thermogravimetric analysis (TGA) were found to provide valuable information on pyrolysis kinetics and mechanisms of a heterogeneous compound like scrap tire rubbers. Kinetic parameters of each compositional compound were obtained by analyzing DTG and TGA results with a series of mathematical methods proposed in this study. The pyrolysis kinetics of the scrap tire rubbers tested was well accounted for by the first-order irreversible independent reactions of three compositional compounds. The sidewall and tread rubber exhibited different thermal degradation patterns, suggesting a compositional difference between them. Isothermal pyrolysis results showed that the sidewall rubber would hardly be degraded at low temperature regions (=}746 K). Because of the shorter pyrolysis time, the higher isothermal pyrolysis temperature appeared to be more economically favorable.

Kim, S.; Park, J.K. [Univ. of Wisconsin, Madison, WI (United States); Chun, H.D. [Research Inst. of Industrial Science and Technology, Pohang (Korea, Republic of)

1995-07-01T23:59:59.000Z

417

Buoyant Production and Consumption of Turbulence Kinetic Energy in Cloud-Topped Mixed Layers  

Science Conference Proceedings (OSTI)

Entrainment closure theories for mixed-layer models entail assumptions about how the net rate of buoyant production of turbulence kinetic energy is partitioned into gross production and consumption. Three alternative partitioning theories are ...

David A. Randall

1984-02-01T23:59:59.000Z

418

Recent Advances in Detailed Chemical Kinetic Models for Large Hydrocarbon and Biodiesel Transportation Fuels  

DOE Green Energy (OSTI)

n-Hexadecane and 2,2,4,4,6,8,8-heptamethylnonane represent the primary reference fuels for diesel that are used to determine cetane number, a measure of the ignition property of diesel fuel. With the development of chemical kinetics models for these two primary reference fuels for diesel, a new capability is now available to model diesel fuel ignition. Also, we have developed chemical kinetic models for a whole series of large n-alkanes and a large iso-alkane to represent these chemical classes in fuel surrogates for conventional and future fuels. Methyl decanoate and methyl stearate are large methyl esters that are closely related to biodiesel fuels, and kinetic models for these molecules have also been developed. These chemical kinetic models are used to predict the effect of the fuel molecule size and structure on ignition characteristics under conditions found in internal combustion engines.

Westbrook, C K; Pitz, W J; Curran, H J; Herbinet, O; Mehl, M

2009-03-30T23:59:59.000Z

419

Coherency Strain and the Kinetics of Phase Separation in LiFePO [subscript 4  

E-Print Network (OSTI)

A theoretical investigation of the effects of elastic coherency strain on the thermodynamics, kinetics, and morphology of intercalation in single LiFePO4 nanoparticles yields new insights into this important battery material. ...

Cogswell, Daniel A.

420

Roles of Divergent and Rotational Winds in the Kinetic Energy Balance Intense Convective Activity  

Science Conference Proceedings (OSTI)

Contibutions of divergent and rotational wind components to the synoptic-scale kinetic energy balance are described using rawinsonde data at 3 and 6 h intervals from NASAs fourth Atmospheric Variability Experiment (AVE 4). Two intense ...

Henry E. Fuelberg; Peter A. Browning

1983-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "kinetic en ergy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Oxidation kinetics of methylphosphonic acid in supercritical water : experimental measurements and model development  

E-Print Network (OSTI)

(cont.) at well-defined operating conditions and to develop. both microscopic and macroscopic models, ranging from regressed global models to an elementary reaction mechanism, to quantify MPA oxidation kinetics in supercritical ...

Sullivan, Patricia A. (Patricia Ann), 1978-

2004-01-01T23:59:59.000Z

422

Lipid Oxidation PathwaysChapter 4 Kinetic Evaluation of the Antioxidant Activity in Lipid Oxidation  

Science Conference Proceedings (OSTI)

Lipid Oxidation Pathways Chapter 4 Kinetic Evaluation of the Antioxidant Activity in Lipid Oxidation Health Nutrition Biochemistry eChapters Health - Nutrition - Biochemistry Press Downloadable pdf of Chapter 4

423

Surface Circulation and Kinetic Energy Distributions in the Southern Hemisphere Oceans from FGGE Drifting Buoys  

Science Conference Proceedings (OSTI)

Trajectories of approximately 300 satellite-tracked drifting buoys deployed throughout the Southern Hemisphere oceans during the Fiat GARP Global Experiment (FGGE) have been analyzed to infer the mean surface circulation and kinetic energy ...

Steven L. Patterson

1985-07-01T23:59:59.000Z

424

Aging Effects on the Kinetics of Cesium Desorption from Vermiculite And Contaminated Soil  

E-Print Network (OSTI)

Aging Effects on the Kinetics of Cesium Desorption from Vermiculite And Contaminated Soil A. M), it is important to determine how aging affects 137 Cs desorption. This study uses a batch technique to measure 0

Sparks, Donald L.

425

Systems, methods and computer-readable media to model kinetic performance of rechargeable electrochemical devices  

DOE Patents (OSTI)

A system includes an electrochemical cell, monitoring hardware, and a computing system. The monitoring hardware samples performance characteristics of the electrochemical cell. The computing system determines cell information from the performance characteristics. The computing system also analyzes the cell information of the electrochemical cell with a Butler-Volmer (BV) expression modified to determine exchange current density of the electrochemical cell by including kinetic performance information related to pulse-time dependence, electrode surface availability, or a combination thereof. A set of sigmoid-based expressions may be included with the modified-BV expression to determine kinetic performance as a function of pulse time. The determined exchange current density may be used with the modified-BV expression, with or without the sigmoid expressions, to analyze other characteristics of the electrochemical cell. Model parameters can be defined in terms of cell aging, making the overall kinetics model amenable to predictive estimates of cell kinetic performance along the aging timeline.

Gering, Kevin L.

2013-01-01T23:59:59.000Z

426

The Kinetic Energy of Hailfalls. Part IV: Patterns of Hailpad and Radar Data  

Science Conference Proceedings (OSTI)

Ground-and radar-measured patterns of hail kinetic energy from eight hailstorms have been compared. The radar patterns were shifted horizontally in such a way that the correlation coefficient between the ground and radar data reaches a maximum. ...

W. Schmid; H. H. Schiesser; A. Waldvogel

1992-10-01T23:59:59.000Z

427

Using a Stochastic Kinetic Energy Backscatter Scheme to Improve MOGREPS Probabilistic Forecast Skill  

Science Conference Proceedings (OSTI)

An improved stochastic kinetic energy backscatter scheme, version 2 (SKEB2) has been developed for the Met Office Global and Regional Ensemble Prediction System (MOGREPS). Wind increments at each model time step are derived from a streamfunction ...

Warren J. Tennant; Glenn J. Shutts; Alberto Arribas; Simon A. Thompson

2011-04-01T23:59:59.000Z

428

Reflectivity, Rain Rate, and Kinetic Energy Flux Relationships Based on Raindrop Spectra  

Science Conference Proceedings (OSTI)

The relationships between radar reflectivity factor Z, rainfall rate R, and rainfall kinetic energy flux E were analyzed based on a multiyear raindrop spectra dataset recorded by a JossWaldvogel disdrometer in the Goodwin Creek research ...

Matthias Steiner; James A. Smith

2000-11-01T23:59:59.000Z

429

An Experimental Study of the Role of Plasticity in the Rafting Kinetics ...  

Science Conference Proceedings (OSTI)

This is consistent with the symmetry of the corresponding Fourier transform. ... components of the scattering vector k, perpendicular to, .... enhanced kinetics due to the supply of fast diffusion paths ... the total strain energy of the single crystal is.

430

Evaluation of the Kinetic Energy Approach for Modeling Turbulent Fluxesin Stratocumulus  

Science Conference Proceedings (OSTI)

The modeling of vertical mixing by a turbulence scheme on the basis of prognostic turbulent kinetic energy (E) and a diagnostic length scale (l) is investigated with particular emphasis on the representation of entrainment. The behavior of this E...

G. Lenderink; A. A. M. Holtslag

2000-01-01T23:59:59.000Z

431

Hydrogen Oxidation and Evolution Reaction Kinetics on Platinum: Acid vs Alkaline Electrolytes  

E-Print Network (OSTI)

The kinetics of the hydrogen oxidation reaction (HOR) and hydrogen evolution reaction (HER) on polycrystalline platinum [Pt(pc)] and high surface area carbon-supported platinum nanoparticles (Pt/C) were studied in 0.1 M ...

Sheng, Wenchao

432

Kinetic viscoelasticity modeling applied to degradation during carboncarbon composite processing  

E-Print Network (OSTI)

Kinetic viscoelasticity modeling has been successfully utilized to describe phenomena during cure of thermoset based carbon fiber reinforced matrices. The basic difference from classic viscoelasticity is that the fundamental ...

Drakonakis, Vassilis M.

433

A kinetic scheme for unsteady pressurised flows in closed water pipes  

E-Print Network (OSTI)

he aim of this paper is to present a kinetic numerical scheme for the computations of transient pressurised flows in closed water pipes. Firstly, we detail the mathematical model written as a conservative hyperbolic partial differentiel system of equations, and the we recall how to obtain the corresponding kinetic formulation. Then we build the kinetic scheme ensuring an upwinding of the source term due to the topography performed in a close manner described by Perthame et al. using an energetic balance at microscopic level for the Shallow Water equations. The validation is lastly performed in the case of a water hammer in a uniform pipe: we compare the numerical results provided by an industrial code used at EDF-CIH (France), which solves the Allievi equation (the commonly used equation for pressurised flows in pipes) by the method of characteristics, with those of the kinetic scheme. It appears that they are in a very good agreement.

Bourdarias, Christian; Gerbi, Stphane

2008-01-01T23:59:59.000Z

434

On Measuring the Terms of the Turbulent Kinetic Energy Budget from an AUV  

Science Conference Proceedings (OSTI)

The terms of the steady-state, homogeneous turbulent kinetic energy budgets are obtained from measurements of turbulence and fine structure from the small autonomous underwater vehicle (AUV) Remote Environmental Measuring Units (REMUS). The ...

Louis Goodman; Edward R. Levine; Rolf G. Lueck

2006-07-01T23:59:59.000Z

435

Microprocessor Field Impactometer Calibration: Do We Measure Drops Momentum or Their Kinetic Energy?  

Science Conference Proceedings (OSTI)

This study presents the construction and calibration of a low-cost piezoelectric microprocessor impactometer designed for the field measurements of the rainfall kinetic energy (KE) flux. Its precise calibration was performed in laboratory ...

Pawe? Licznar; Janusz ?omotowski; S?awomir B?o?ski; Grzegorz J. Ciach

2008-05-01T23:59:59.000Z

436

Influences of ENSO on Western North Pacific Tropical Cyclone Kinetic Energy and Its Meridional Transport  

Science Conference Proceedings (OSTI)

This study investigates the influences of ENSO on tropical cyclone (TC) kinetic energy and its meridional transport in the western North Pacific (WNP) using the TC wind field obtained after a method for removing TC vortices from reanalysis data is ...

Yao Ha; Zhong Zhong; Yijia Hu; Xiuqun Yang

2013-01-01T23:59:59.000Z

437

A rule-based approach for automated generation of kinetic chemical mechanisms  

Science Conference Proceedings (OSTI)

Several software systems have been developed recently for the automated generation of combustion reactions kinetic mechanisms using different representations of species and reactions and different generation algorithms. In parallel, several software ...

Olivier Bournez; Guy-Marie Cme; Valrie Conraud; Hlne Kirchner; Liliana Ib?nescu

2003-06-01T23:59:59.000Z

438

Millisecond Kinetics of Nanocrystal Cation Exchange Using Microfluidic X-ray Absorption Spectroscopy  

E-Print Network (OSTI)

nanocrystal with DDA, R CdSe was calculated to be 3.4 nm. Rto measure the kinetics of the CdSe-to-Ag 2 Se nanocrystalthe millisecond mixing of CdSe nanocrystal and Ag + reactant

Chan, Emory M.; Marcus, Matthew A.; Fakra, Sirine; Elnaggar, Mariam S.; Mathies, Richard A.; Alivisatos, A. Paul

2007-01-01T23:59:59.000Z

439

The Path of Carbon in Photosynthesis. XVI. Kinetic Relationships of the Intermediates in Steady State Photosynthesis  

E-Print Network (OSTI)

OF CARBON I N PHOTOSYNTHESIS, X U , KINETIC REIATIORSEIPS OFof steady. state photosynthesis in cUO2 provides informationThe path of carbon i n photosynthesis begins with a small

Benson, A.A.; Kawaguchi, S.; Hayes, P.; Calvin, M.

1952-01-01T23:59:59.000Z

440

Mesoscale Energy Spectra of Mei-Yu Front System. Part I: Kinetic Energy Spectra  

Science Conference Proceedings (OSTI)

The mesoscale kinetic energy (KE) spectra of Mei-Yu front system are investigated through idealized numerical simulations. In the mature stage, the upper tropospheric KE spectrum resembles a -3 power law for wavelengths between 1000 and 400 km and ...

Jun Peng; Lifeng Zhang; Yu Luo; Yun Zhang

Note: This page contains sample records for the topic "kinetic en ergy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Derivation of Turbulent Kinetic Energy from a First-Order Nonlocal Planetary Boundary Layer Parameterization  

Science Conference Proceedings (OSTI)

Turbulent kinetic energy (TKE) is derived from a first-order planetary boundary layer (PBL) parameterization for convective boundary layers: the nonlocal K-profile Yonsei University (YSU) PBL. A parameterization for the TKE equation is developed ...

Hyeyum Hailey Shin; Song-You Hong; Yign Noh; Jimy Dudhia

2013-06-01T23:59:59.000Z

442

The Kinetic Energy of Hailfalls. Part III: Sampling Errors Inferred, from Radar Data  

Science Conference Proceedings (OSTI)

The representativeness of hailfall kinetic energies derived from point measurements of networks is studied by means of radar data of hail cells. The 202 cells were observed within a radius of 60 km from the 10 cm radar. Different Cartesian ...

A. Waldvogel; W. Schmid

1982-09-01T23:59:59.000Z

443

Kinetics of Cloud Drop Formation and Its Parameterization for Cloud and Climate Models  

Science Conference Proceedings (OSTI)

To study the kinetics of drop nucleation in clouds, the integrodifferential equation for integral water supersaturation in cloud is derived and analyzed. Solving the supersaturation equation with an algebraic form of the cloud condensation ...

Vitaly I. Khvorostyanov; Judith A. Curry

2008-09-01T23:59:59.000Z

444

Including Surface Kinetic Effects in Simple Models of Ice Vapor Diffusion  

Science Conference Proceedings (OSTI)

A model for kinetically-limited vapor growth and aspect ratio evolution of atmospheric single ice crystals is presented. The method is based on the adaptive habit model of Chen and Lamb (1994), but is modified to include the deposition ...

Chengzhu Zhang; Jerry Y. Harrington

445

Steady state kinetic analyses of nitroalkane oxidase mutants  

E-Print Network (OSTI)

Nitroalkane oxidase (NAO) catalyzes the oxidation of neutral nitroalkanes to aldehydes and ketones with oxygen consumption and the production of hydrogen peroxide and nitrite. The enzyme is a flavoprotein from the fungus Fusarium oxysporum. The active site base, Asp402, abstracts one proton from the substrate to give a carbanion which then attacks the flavin adenine dinucleotide (FAD). The three dimensional crystal structure of NAO shows that Arg409 is 3.6 from Asp402. When Arg409 is mutated to Lys, the rate constant for proton abstraction decreases 100-fold. The three-dimensional structure of NAO also reveals the existence of a tunnel which extends from the protein exterior and terminates at the FAD N5 atom and the residues Asp402 and Phe401. We mutated amino acids in the tunnel into tryptophan, phenylalanine and leucine. The L99W, S276W and S276A enzymes showed the biggest decreases in both kcat and kcat/Km; these amino acids are closest to the FAD molecule and the active site. Mutation of amino acids farther away from the active site showed very small changes in the kinetic parameters. Ser276 is hydrogen bonded to Asp402 in the wild-type enzyme. When this amino acid is mutated to alanine or tryptophan, k3, the rate constant for proton abstraction, decreases around 35 fold. Asp402, Arg409 and Ser276 constitute a catalytic triad in the active site of nitroalkane oxidase, and both Arg409 and Ser276 are important for positioning Asp402 and catalysis.

Bozinovski, Dragana Milivoj

2008-05-01T23:59:59.000Z

446

Kinetic Modeling and Assessment of Lime Pretreatment of Poplar Wood  

E-Print Network (OSTI)

Because of widespread availability, low cost, sustainability, and potential supply far greater than that of food crops, lignocellulosic biomass is one of the most promising feedstocks for producing biofuels through fermentation processes. Among lignocellulose choices, poplar wood is appealing because of high energy potential, above-average carbon mitigation potential, fast growth, and high yields. Lignocellulose structural features limit accessibility of enzymes or microorganisms. To overcome these limitations, pretreatment is required. Among several choices of pretreatment, lime pretreatment is preferred because lime is the cheapest alkali, safest to handle, easy to recover, and compatible with oxidants. The main effect of lime pretreatment is to degrade lignin, which occurs with good carbohydrate preservation and is enhanced with oxidants. Among several choices of oxidant, oxygen and air are preferred because of low cost and widespread availability. This study systematically assesses the effects of lime pretreatment on poplar wood using four different modes: long-term oxidative, long-term non-oxidative, short-term constant pressure, and short-term varying pressure. Long-term pretreatments use temperatures between 25 and 65 C, air if oxidant is used, and last several weeks. Short-term pretreatments use temperatures between 110 and 180 C, pressurized oxygen, and last several minutes to hours. Pretreatment was assessed on the basis of 3-day enzymatic digestibility using enzyme loadings of 15 FPU/g glucan in raw biomass. The results were used to recommend pretreatment conditions based on highest overall yield of glucan (after combined pretreatment and enzymatic hydrolysis) for each pretreatment mode. For each pretreatment mode, kinetic models for delignification and carbohydrates degradation were obtained and used to determine the conditions (temperature, pressure, and time) that maximize glucan preservation subjected to a target lignin yield. This study led to conclude that the most robust, and selective mode of lime pretreatment is varying pressure.

Sierra Ramirez, Rocio

2010-12-01T23:59:59.000Z

447

Chemical kinetic studies on dry sorbents. Final report. [Sodium bicarbonate  

Science Conference Proceedings (OSTI)

The scope of this research investigation has included a review of potential additives suitable for dry flue-gas desulfurization (FGD) and a bench scale laboratory study to determine the chemical kinetics for the reaction of five different sorbents with sulfur dioxide. The sorbents chosen included sodium bicarbonate (NaHCO/sub 3/), soda ash (Na/sub 2/CO/sub 3/), trona, lime (CaO) and hydrated lime (Ca(OH)/sub 2/). This study has shown that: (1) The reaction rate increases with temperature for soda ash and calcium oxide. The reaction temperature has an inverse effect on sodium bicarbonate and trona due, primarily, to the simultaneous thermal activation reaction. The calcium hydroxide-SO/sub 2/ reaction increased up to 550/sup 0/F, and then decreased, due to uneven gas flow distribution. (2) The reaction rates for soda ash, calcium oxide and calcium hydroxide were increased by decreasing their particle size. This effect was not confirmed for sodium bicarbonate and trona where reaction temperature was the most important reaction parameter. (3) Reaction with soda ash was found to be limited by the presence of an impervious ash layer which prevented interparticle gaseous diffusion. Calcium oxide and calcium hydroxide were found to be limited by a slow chemical reaction rate. Results on the rate-limiting steps for sodium bicarbonate and trona were inconclusive because of the simultaneous thermal activation reaction. (4) The effect of thermal activation was to increase the reaction rate for sodium bicarbonate and trona at lower temperatures. This effect was less pronounced at higher temperatures. (5) Results obtained for nitric oxide show limited adsorption for the five sorbents tested as compared to the finding for sulfur dioxide.

Davis, W.T.; Keener, T.C.

1982-02-15T23:59:59.000Z

448

Pseudo-isothermal ice-crystallization kinetics in the gas-diffusion layer  

NLE Websites -- All DOE Office Websites (Extended Search)

Pseudo-isothermal ice-crystallization kinetics in the gas-diffusion layer Pseudo-isothermal ice-crystallization kinetics in the gas-diffusion layer of a fuel cell from differential scanning calorimetry Title Pseudo-isothermal ice-crystallization kinetics in the gas-diffusion layer of a fuel cell from differential scanning calorimetry Publication Type Journal Article Year of Publication 2013 Authors Dursch, Thomas J., Monica A. Ciontea, Gregory J. Trigub, Clayton J. Radke, and Adam Z. Weber Journal International Journal of Heat and Mass Transfer Volume 60 Pagination 450 - 458 Date Published 5/2013 ISSN 00179310 Keywords crystallization, differential scanning calorimetry, gas-diffusion layer, Heat Transfer, kinetics, melt, nonisothermal crystallization, nucleation, polyesters, polymer crystallization, solidification Abstract Non-isothermal ice-crystallization kinetics in the fibrous gas-diffusion layer (GDL) of a proton-exchange-membrane fuel cell is investigated using differential scanning calorimetry (DSC). Non-isothermal ice-crystallization rates and ice-crystallization temperatures are obtained from heat-flow measurements in a water-saturated commercial GDL at cooling rates of 2.5, 5, 10, and 25 K/min. Our previously developed isothermal ice-crystallization rate expression is extended to non-isothermal crystallization to predict ice-crystallization kinetics in a GDL at various cooling rates. Agreement between DSC experimental results and theory is good. Both show that as the cooling rate increases, ice-crystallization rates increase and crystallization temperatures decrease monotonically. Importantly, we find that the cooling rate during crystallization has a negligible effect on the crystallization rate when crystallization times are much faster than the time to decrease the sample temperature by the subcooling. Based on this finding, we propose a pseudo-isothermal method for obtaining non-isothermal crystallization kinetics using isothermal crystallization kinetics evaluated at the non-isothermal crystallization temperature.

449

Development of Kinetics and Mathematical Models for High Pressure Gasification of Lignite-Switchgrass Blends  

NLE Websites -- All DOE Office Websites (Extended Search)

Kinetics and Mathematical Kinetics and Mathematical Models for High Pressure Gasification of Lignite-Switchgrass Blends Background Significant progress has been made in recent years in controlling emissions resulting from coal-fired electricity generation in the United States through the research, development, and deployment of innovative technologies such as gasification. Gasification is a process that converts solid feedstocks such as coal, biomass, or blends

450

Modification of {Delta}{sup Prime} by magnetic feedback and kinetic effects  

SciTech Connect

Two possible ways of modifying the linear tearing mode index, by active magnetic feedback and by drift kinetic effects of deeply trapped particles, are analytically investigated. Magnetic feedback schemes, studied in this work, are found generally stabilizing for {Delta}{sup Prime }. The drift kinetic effects from both thermal particles and hot ions tend to reduce the power of the large solution from the outer region. This generally leads to a destabilization of {Delta} Prime for the toroidal analytic equilibria considered here.

Liu Yueqiang; Hastie, R. J.; Hender, T. C. [Euratom/CCFE Fusion Association, Culham Science Centre, Abingdon OX14 3DB (United Kingdom)

2012-09-15T23:59:59.000Z

451

Kinetic description of rotating Tokamak plasmas with anisotropic temperatures in the collisionless regime  

SciTech Connect

A largely unsolved theoretical issue in controlled fusion research is the consistent kinetic treatment of slowly-time varying plasma states occurring in collisionless and magnetized axisymmetric plasmas. The phenomenology may include finite pressure anisotropies as well as strong toroidal and poloidal differential rotation, characteristic of Tokamak plasmas. Despite the fact that physical phenomena occurring in fusion plasmas depend fundamentally on the microscopic particle phase-space dynamics, their consistent kinetic treatment remains still essentially unchallenged to date. The goal of this paper is to address the problem within the framework of Vlasov-Maxwell description. The gyrokinetic treatment of charged particles dynamics is adopted for the construction of asymptotic solutions for the quasi-stationary species kinetic distribution functions. These are expressed in terms of the particle exact and adiabatic invariants. The theory relies on a perturbative approach, which permits to construct asymptotic analytical solutions of the Vlasov-Maxwell system. In this way, both diamagnetic and energy corrections are included consistently into the theory. In particular, by imposing suitable kinetic constraints, the existence of generalized bi-Maxwellian asymptotic kinetic equilibria is pointed out. The theory applies for toroidal rotation velocity of the order of the ion thermal speed. These solutions satisfy identically also the constraints imposed by the Maxwell equations, i.e., quasi-neutrality and Ampere's law. As a result, it is shown that, in the presence of nonuniform fluid and EM fields, these kinetic equilibria can sustain simultaneously toroidal differential rotation, quasi-stationary finite poloidal flows and temperature anisotropy.

Cremaschini, Claudio [International School for Advanced Studies (SISSA) and INFN, Trieste (Italy); Tessarotto, Massimo [Department of Mathematics and Informatics, University of Trieste (Italy)

2011-11-15T23:59:59.000Z

452

The folding kinetics of ribonuclease Sa and a charge-reversal variant  

E-Print Network (OSTI)

The primary objective was to study the kinetics of folding of RNase Sa. Wild-type RNase Sa does not contain tryptophan. A tryptophan was substituted at residue 81 (WT*) to allow fluorescence spectroscopy to be used to monitor folding. This tryptophan mutation did not change the stability. An analysis of the folding kinetics of RNase Sa showed two folding phases, indicating the presence of an intermediate and consistent with the following mechanism: D ? I ? N. Both refolding limbs of the chevron plot (abcissa = final conc. of denaturant and ordinate = kinetic rate) had non-zero slopes suggesting that proline isomerization was not rate-limiting. The conformational stability of a charge-reversed variant, WT*(D17R), of a surface exposed residue on RNase Sa has been studied by equilibrium techniques. This mutant with a single amino acid charge reversal of a surface exposed residue resulted in decreased stability. Calculations using Coulomb?s Law suggested that favorable electrostatic interactions in the denatured state were the cause for the decreased stability for the charge-reversed variant. Folding and unfolding kinetic studies were designed and conducted to study the charge-reversal effect. Unfolding kinetics showed a 10-fold increase in the unfolding rate constant for WT*(D17R) over WT* and no difference in the rate of refolding. Kinetics experiments were also conducted at pH 3 where protonation of Asp17 (charge reversal site) would be expected to negate the observed kinetic effect. At pH 3 the kinetics of unfolding of WT* RNase Sa and the WT*(D17R) mutant were more similar. These kinetic results indicate that a single-site charge reversal lowered the free energy of the denatured state as suspected. Additionally, the results showed that the transition state was stabilized as well. These results show that a specific Coulombic interaction lowered the free energy in the denatured and transition state of the charge-reversal mutant, more than in WT*. To our knowledge, this is the first demonstration that a favorable electrostatic interaction in the denatured state ensemble has been shown to influence the unfolding kinetics of a protein.

Trefethen, Jared M.

2004-12-01T23:59:59.000Z

453

Kinetic models of current sheets with a sheared magnetic field  

Science Conference Proceedings (OSTI)

Thin current sheets, whose existence in the Earth's magnetotail is confirmed by numerous spacecraft measurements, are studied analytically and numerically. The thickness of such sheets is on the order of the ion Larmor radius, and the normal component of the magnetic field (B{sub z}) in the sheet is almost constant, while the tangential (B{sub x}) and shear (B{sub y}) components depend on the transverse coordinate z. The current density in the sheet also has two self-consistent components (j{sub x} and j{sub y}, respectively), and the magnetic field lines are deformed and do not lie in a single plane. To study such quasi-one-dimensional current configurations, two kinetic models are used, in particular, a numerical model based on the particle-in-cell method and an analytical model. The calculated results show that two different modes of the self-consistent shear magnetic field B{sub y} and, accordingly, two thin current sheet configurations can exist for the same input parameters. For the mode with an antisymmetric z profile of the B{sub y} component, the magnetic field lines within the sheet are twisted, whereas the profiles of the plasma density, current density component j{sub y}, and magnetic field component B{sub x} differ slightly from those in the case of a shearless magnetic field (B{sub y} = 0). For the symmetric B{sub y} mode, the magnetic field lines lie in a curved surface. In this case, the plasma density in the sheet varies slightly and the current sheet is two times thicker. Analysis of the dependence of the current sheet structure on the flow anisotropy shows that the sheet thickness decreases significantly with decreasing ratio between the thermal and drift plasma velocities, which is caused by the dynamics of quasi-adiabatic ions. It is shown that the results of the analytical and numerical models are in good agreement. The problems of application of these models to describe current sheets at the magnetopause and near magnetic reconnection regions are discussed.

Mingalev, O. V.; Mingalev, I. V.; Mel'nik, M. N. [Russian Academy of Sciences, Polar Geophysical Institute, Cola Science Center (Russian Federation); Artemyev, A. V.; Malova, H. V.; Popov, V. Yu. [Russian Academy of Sciences, Space Research Institute (Russian Federation); Chao, Shen [Chinese Academy of Sciences, Center for Space Science and Applied Research (China); Zelenyi, L. M. [Russian Academy of Sciences, Space Research Institute (Russian Federation)

2012-04-15T23:59:59.000Z

454

En couleur sur le web www.ens.fr/actualites/  

E-Print Network (OSTI)

face au tournant linguistique du XVIIIe s. 16h45 Pause 17h Thierry Gineste -- L'enfant sauvage de l »,Benjamin Spector (ENS) :« Approche linguistique du jugement analytique ». Lundi 30 mai, 17h-19h30, salle,(professeur,NewYork University) dans le cadre du séminaire DECS 11.Séminaire de linguistique théorique sur quatre semaines. Les

455

The LANL atomic kinetics modeling effort and its application to W plasmas  

SciTech Connect

This is the work of the LANL group on atomic kinetics modelling. There are various levels of detail in the LANL suite of atomic physics codes: (1) Non-relativistic configuration average kinetics (nl{sup w}) + UTA spectra, (2) Relativistic configuration average kinetics (nlj{sup w}) + UTA spectra, (3) Mixed UTA (MUTA) - configuration average kinetics and spectra composed of mixture of UTAs and fine-structure features and (4) Fine-structure levels. The LANL suite of atomic physics codes consists of 5 codes: (1) CATS/RATS atomic structure codes (semi-relativistic Cowan code or Dirac-Fock-Slater code), (2) ACE collisional excitation code (Plane-wave Born, Columb-Born and distorted-wave methods) and (3) GIPPER ionization code (scaled-hydrogenic and distorted-wave methods). An on-line version of the codes is available at http://aphysics2.lanl.gov/tempweb. ATOMIC kinetics modelling code uses the atomic data for LTE or NLTE population kinetics models and spectral modelling of a broad range of plasma applications. The mixed UTA (MUTA) approach was developed for the spectra of complex ions and the results are in very good agreement with the Sandia-Z Iron opacity experiments. The LANL configuration-average/MUTA calculations were applied to tungsten problems of the non-LTE kinetics code comparison workshops. The LANL group plans to perform much larger calculations to assess the accuracy of the older results and to investigate low-temperature tungsten processes relevant to the divertor modelling.

Colgan, James [Los Alamos National Laboratory; Abdallah, Joseph [Los Alamos National Laboratory; Fontes, Christopher [Los Alamos National Laboratory; Zhang, Honglin [Los Alamos National Laboratory

2010-12-10T23:59:59.000Z

456

Heat Transfer Analysis and Assessment of Kinetics Systems for PBX 9501  

SciTech Connect

The study of thermal decomposition in high explosive (HE) charges has been an ongoing process since the early 1900s. This work is specifically directed towards the analysis of PBX 9501. In the early 1970s, Dwight Jaeger of Los Alamos National Laboratory (LANL) developed a single-step, two-species kinetics system that was used in the development of one of the first finite element codes for thermal analyses known as EXPLO. Jaeger's research focused on unconfined spherical samples of HE charges to determine if varied heating ramps would cause detonation or deflagration. Tarver and McGuire of Lawrence Livermore National Laboratory (LLNL) followed soon after with a three-step, four-species kinetics system that was developed for confined spheres under relatively fast heating conditions. Peter Dickson et al. of LANL then introduced a kinetics system with four steps and five species that included bimolecular products to capture the effects of the endothermic phase change that the HE undergoes. The results of four experiments are examined to study the effectiveness of these kinetics systems. The experiments are: (1) The LLNL scaled thermal explosion (STEX) experiments on confined cylindrical charges with long heating ramps in the range of 90 hours. (2) The LLNL one-dimensional time to explosion (ODTX) experiments on spherical charges that include confined, partially confined, and aged HE experiments. (3) The LANL unconfined one-dimensional experiments for small spheres. (4) The Naval Air Warfare Center Weapons Division at China Lake experiments on small confined cylinders. The three kinetics systems are applied to each of the four experiments with the use of the finite element analysis (FEA) heat conduction solver COYOTE. The numerical results using the kinetics systems are compared to each other and to the experimental data to determine which kinetics systems are best suited for analyzing conditions such as time to ignition, containment, heating time, and location of ignition.

Jeffrey W. Jorenby

2006-07-31T23:59:59.000Z

457

Emissions anthropiques d'arosols carbons en Afrique en 2005 et en 2030 : laboration d'inventaires et valuation.  

E-Print Network (OSTI)

??La croissance dmographique rapide que connait le continent africain ces dernires dcennies ainsi que l'exode rural, tendent de plus en plus concentrer dans quelques (more)

Assamoi, Ab Yapo Eric-Michel

2011-01-01T23:59:59.000Z

458

Master franco-allemand en conomie  

E-Print Network (OSTI)

Rennes 1 qu'ils ont choisi. Les étudiants rennais bénéficient en outre d'une préparation linguistique'une licence (ou d'un bachelor) de spécialité qui justifient en outre d'un niveau linguistique suf- fisant. Les'inscription en janvier entretien de motivation entre janvier et mars #12; Aides Outre la formation linguistique

Rennes, Université de

459

Licence franco-allemande en conomie  

E-Print Network (OSTI)

linguistique spécifique en licence. Atouts > Aptitudes requises : très bonnes connaissances en allemand avoir déroule à Rennes entre janvier et mars. Aides : Outre la formation linguistique en langue générale et de candidats sélectionnés pour la doublelicence bénéficient d'une forma- tion linguistique intensive gratuite

Rennes, Université de

460

Mise en correspondance par correlation avec prise en compte des occultations  

E-Print Network (OSTI)

Mise en correspondance par corr´elation avec prise en compte des occultations Occlusions handling cours de l'appariement, provient des occultations. C'est pourquoi le second objectif est de pr compte le probl`eme des occultations. Les r´esultats mettent en ´evidence la meilleure m´ethode qui

Chambon, Sylvie

Note: This page contains sample records for the topic "kinetic en ergy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Traian Sandu Docteur en histoire, Professeur agrg  

E-Print Network (OSTI)

Basescu, sur la légitimité historique de l'annexion de la Bessarabie par la Roumanie en 1917 ne laissent

Paris-Sud XI, Université de

462

A Comparison of Isoconversional and Model-Fitting Approaches to Kinetic Parameter Estimation and Application Predictions  

SciTech Connect

Chemical kinetic modeling has been used for many years in process optimization, estimating real-time material performance, and lifetime prediction. Chemists have tended towards developing detailed mechanistic models, while engineers have tended towards global or lumped models. Many, if not most, applications use global models by necessity, since it is impractical or impossible to develop a rigorous mechanistic model. Model fitting acquired a bad name in the thermal analysis community after that community realized a decade after other disciplines that deriving kinetic parameters for an assumed model from a single heating rate produced unreliable and sometimes nonsensical results. In its place, advanced isoconversional methods (1), which have their roots in the Friedman (2) and Ozawa-Flynn-Wall (3) methods of the 1960s, have become increasingly popular. In fact, as pointed out by the ICTAC kinetics project in 2000 (4), valid kinetic parameters can be derived by both isoconversional and model fitting methods as long as a diverse set of thermal histories are used to derive the kinetic parameters. The current paper extends the understanding from that project to give a better appreciation of the strengths and weaknesses of isoconversional and model-fitting approaches. Examples are given from a variety of sources, including the former and current ICTAC round-robin exercises, data sets for materials of interest, and simulated data sets.

Burnham, A K

2006-05-17T23:59:59.000Z

463

A comparison of the point kinetics equations with the QUANDRY analytic nodal diffusion method  

E-Print Network (OSTI)

The point kinetics equations were incorporated into QUANDRY, a nuclear reactor analysis computer program which uses the analytic nodal method to solve the neutron diffusion equation. Both the point kinetics equations, solved using the IMSL MATH/LIBRARY subroutine DIVPAG, and the analytic nodal method were coupled to the WIGL thermal-hydraulic model. The Langenbuch-Maurer-Werner (LMW) model was adapted for use as a test core. The QUANDRY model was used to generate point kinetics parameters. equations. The two neutronics methods were then compared for a range of typical transients encountered in a light water nuclear reactor core. The temperature reactivity coefficients found for the modified LMW core and used with point kinetics were shown to be grossly inaccurate, but the rod worth curve generated using QUANDRY only slightly overestimated the amount of reactivity inserted by rod movement. While the small rod worth errors caused point kinetics to give poor approximations for high rates of reactivity insertions of over one dollar, these large amounts and insertion rates are well above those found during most operational transients in commercial reactors.

Velasquez, Arthur

1993-01-01T23:59:59.000Z

464

Comparison of kinetic and equilibrium reaction models insimulating the behavior of porous media  

SciTech Connect

In this study we compare the use of kinetic and equilibriumreaction models in the simulation of gas (methane) hydrate behavior inporous media. Our objective is to evaluate through numerical simulationthe importance of employing kinetic versus equilibrium reaction modelsfor predicting the response of hydrate-bearing systems to externalstimuli, such as changes in pressure and temperature. Specifically, we(1) analyze and compare the responses simulated using both reactionmodels for natural gas production from hydrates in various settings andfor the case of depressurization in a hydrate-bearing core duringextraction; and (2) examine the sensitivity to factors such as initialhydrate saturation, hydrate reaction surface area, and numericaldiscretization. We find that for large-scale systems undergoing thermalstimulation and depressurization, the calculated responses for bothreaction models are remarkably similar, though some differences areobserved at early times. However, for modeling short-term processes, suchas the rapid recovery of a hydrate-bearing core, kinetic limitations canbe important, and neglecting them may lead to significantunder-prediction of recoverable hydrate. Assuming validity of the mostaccurate kinetic reaction model that is currently available, the use ofthe equilibrium reaction model often appears to be justified andpreferred for simulating the behavior of gas hydrates, given that thecomputational demands for the kinetic reaction model far exceed those forthe equilibrium reaction model.

Kowalsky, Michael B.; Moridis, George J.

2006-11-29T23:59:59.000Z

465

Electricity demand as frequency controlled reserves, ENS (Smart...  

Open Energy Info (EERE)

Electricity demand as frequency controlled reserves, ENS (Smart Grid Project) Jump to: navigation, search Project Name Electricity demand as frequency controlled reserves, ENS...

466

En studie av Toyotas miljarbete genom Human-Centered Design.  

E-Print Network (OSTI)

?? Det ligger ngot motsgelsefullt i att bilfretag arbetar med miljfrgor. kad globalisering och urbanisering har haft en stor inverkan p vr milj. Som en (more)

Webert, Nina

2011-01-01T23:59:59.000Z

467

Feb 06 Seq newsletter_NO IMAGE.pub  

NLE Websites -- All DOE Office Websites (Extended Search)

February 2006 February 2006 *Sequestration in the News *Geology *Terrestrial *Legislative Activity *Science *Technology *Trading *Events and Announcements *Policy *Ocean *Recent Publications *Contact Information Sequestration in the News THE CARBON SEQUESTRATION NEWSLETTER http://www.netl.doe.gov/publications/carbon_seq/subscribe.html Page 1 CNN.com, "US to Attend Asia-Pacific Climate Talks," En- ergy Secretary Samuel Bodman, Secretary of State Con- dolezza Rice (who cancelled due to the health condition of Ariel Sharon), and Presidential advisor James Connaughton are to meet in Sydney Australia on January 11-12 with repre- sentatives from five Asia and Pacific Nations: Australia, China, India, Japan and South Korea. Along with the US,

468

untitled  

NLE Websites -- All DOE Office Websites (Extended Search)

January 2006 January 2006 *Sequestration in the News *Geology *Terrestrial *Legislative Activity *Science *Technology *Trading *Events and Announcements *Policy *Ocean *Recent Publications *Contact Information Sequestration in the News THE CARBON SEQUESTRATION NEWSLETTER http://www.netl.doe.gov/technologies/carbon_seq/index.html Page 1 Department of Energy Press Release, "FutureGen Project Launched." In a press release issued on December 6, Sec- retary of Energy Samuel W. Bodman announced the official "kick off" of the FutureGen project by the Department of En- ergy with the signing of the FutureGen Industrial Alliance agreement. The FutureGen Industrial Alliance consists of: American Electric Power (Columbus, OH); BHP Billiton

469

Lactonization and protonation of gluconic acid: a thermodynamic and kinetic study by potentiometry, nmr and esi-ms  

E-Print Network (OSTI)

of Gluconic Acid: A Thermodynamic and Kinetic Study byin solutions of low pH, and thermodynamic data that describewaste streams requires thermodynamic data concerning the f-

Zhang, Z.; Gibson, P.; Clark, S.B.; Tian, G.; Zanonato, P.; Rao, L.

2008-01-01T23:59:59.000Z

470

Crisis en Medio Oriente y Norte de frica Su Impacto en los Mercados Burstiles de Amrica Latina .  

E-Print Network (OSTI)

??Esta tesis busca examinar el efecto de las revueltas en los pases del Medio Oriente y Norte de frica, especialmente lo ocurrido en Libia, sobre (more)

Ureta Portales, Mara Cecilia

2011-01-01T23:59:59.000Z

471

Argonne CNM Highlight: Self-Assembly Kinetics of Two-Dimensional  

NLE Websites -- All DOE Office Websites (Extended Search)

Self-Assembly Kinetics of Two-Dimensional Nanocrystal Superlattices Self-Assembly Kinetics of Two-Dimensional Nanocrystal Superlattices Two-dimensional nanocrystal superlattices Two-dimensional assembly of gold nanocrystals at a toluene-air interface during colloidal droplet evaporation process: in situ optical microscopy (top panel, inset is a TEM image of the array after drying) and time-resolved GISAXS (bottom panel a-b). Self-assembly of a crystalline phase with quasi-long-range positional order for two-dimensional nanocrystal superlattice (NSC) domains at the liquid-air interface during droplet evaporation has been observed. The NSCs were formed by depositing a colloidal suspension of highly monodisperse dodecanethiol-ligated gold nanocrystals. The kinetics of the self-assembly were immediately captured by in situ time-resolved grazing-incidence

472

Kinetic instability of drift-Alfven waves in solar corona and stochastic heating  

E-Print Network (OSTI)

The solar atmosphere is structured and inhomogeneous both horizontally and vertically. The omnipresence of coronal magnetic loops implies gradients of the equilibrium plasma quantities like the density, magnetic field and temperature. These gradients are responsible for the excitation of drift waves that grow both within the two-component fluid description (in the presence of collisions and without it) and within the two-component kinetic descriptions (due to purely kinetic effects). In the present work the effects of the density gradient in the direction perpendicular to the magnetic field vector are investigated within the kinetic theory, in both electrostatic and electromagnetic regimes. The electromagnetic regime implies the coupling of the gradient-driven drift wave with the Alfven wave. The growth rates for the two cases are calculated and compared. It is found that, in general, the electrostatic regime is characterized by stronger growth rates, as compared with the electromagnetic perturbations. Also d...

Vranjes, J

2010-01-01T23:59:59.000Z

473

Hydration kinetics modeling of Portland cement considering the effects of curing temperature and applied pressure  

Science Conference Proceedings (OSTI)

A hydration kinetics model for Portland cement is formulated based on thermodynamics of multiphase porous media. The mechanism of cement hydration is discussed based on literature review. The model is then developed considering the effects of chemical composition and fineness of cement, water-cement ratio, curing temperature and applied pressure. The ultimate degree of hydration of Portland cement is also analyzed and a corresponding formula is established. The model is calibrated against the experimental data for eight different Portland cements. Simple relations between the model parameters and cement composition are obtained and used to predict hydration kinetics. The model is used to reproduce experimental results on hydration kinetics, adiabatic temperature rise, and chemical shrinkage of different cement pastes. The comparisons between the model reproductions and the different experimental results demonstrate the applicability of the proposed model, especially for cement hydration at elevated temperature and high pressure.

Lin Feng [Department of Civil Engineering and Engineering Mechanics, Columbia University, New York, NY 10027 (United States); Department of Civil Engineering, Tsinghua University, Beijing 100084 (China)], E-mail: fl2040@columbia.edu; Meyer, Christian [Department of Civil Engineering and Engineering Mechanics, Columbia University, New York, NY 10027 (United States)

2009-04-15T23:59:59.000Z

474

Thermodynamic, Kinetic, and Structural Factors in the Synthesis of Imine-Linked Dynamic Covalent Frameworks.  

SciTech Connect

The formation of imine-linked dynamic covalent frameworks (DCFs) has been systematically studied to determine how different factors such as reaction solvent and composition, reaction kinetics and thermodynamics, and structure of the building units influence the yield, degree of condensation, and homogeneity of the resulting products. Using molecular tetraimine analogs, we first investigated the kinetics and thermodynamics of imine condensation reactions under a variety of conditions, as well as the structures of the basic tetraimine units by X-ray crystallography. These model systems allowed us to identify conditions that favored both high reversibility and fast reaction kinetics for the imine condensation, leading in the end to the development of effective synthetic routes toward imine-linked DCFs with high degrees of cross-linking and homogeneity.

Duncan, Nathan C [ORNL; Hay, Benjamin [ORNL; Hagaman, Edward {Ed} W [ORNL; Custelcean, Radu [ORNL

2012-01-01T23:59:59.000Z

475

Kinetic model of product distribution over Fe catalyst for Fischer-Tropsch synthesis  

Science Conference Proceedings (OSTI)

A new kinetic model of the Fischer-Tropsch synthesis (FTS) is proposed to describe the non-Anderson-Schulz-Flory (ASF) product distribution. The model is based on the double-polymerization monomers hypothesis, in which the surface C{sub 2}{asterisk} species acts as a chain-growth monomer in the light-product range, while C{sub 1}{asterisk} species acts as a chain-growth monomer in the heavy-product range. The detailed kinetic model in the Langmuir-Hinshelwood-Hougen-Watson type based on the elementary reactions is derived for FTS and the water-gas-shift reaction. Kinetic model candidates are evaluated by minimization of multiresponse objective functions with a genetic algorithm approach. The model of hydrocarbon product distribution is consistent with experimental data (

Rongle Zhang; Jie Chang; Yuanyuan Xu; Liren Cao; Yongwang Li; Jinglai Zhou [Chinese Academy of Sciences, Taiyuan (China). Institute of Coal Chemistry

2009-09-15T23:59:59.000Z

476

Assessment report on the kinetics of radionuclide adsorption on Yucca Mountain tuff  

SciTech Connect

The kinetics of sorption was measured by observing the uptake of radionuclides by tuff wafers and crushed tuff as a function of time. In addition, the broadening of breakthrough curves for cations eluted through crushed-tuff columns was interpreted in terms of adsorption kinetics. The results of these measurements are consistent with a diffusion-limited adsorption mechanism for simple cations, such as strontium, cesium, and barium. The adsorption kinetics for these simple cations is sufficiently fast so that equilibrium can be assumed for the retardation of these chemical species in the groundwater velocities that would be reasonable for most release scenarios. The actinides, in particular plutonium, exhibited a slow time dependence for adsorption. 23 refs., 61 figs., 12 tabs.

Rundberg, R.S.

1987-07-01T23:59:59.000Z

477

Identification of intermittent multi-fractal turbulence in fully kinetic simulations of magnetic reconnection  

E-Print Network (OSTI)

Recent fully nonlinear, kinetic three-dimensional simulations of magnetic reconnection [Daughton et al. 2011] evolve structures and exhibit dynamics on multiple scales, in a manner reminiscent of turbulence. These simulations of reconnection are among the first to be performed at sufficient spatio-temporal resolution to allow formal quantitative analysis of statistical scaling which we present here. We find that the magnetic field fluctuations generated by reconnection are anisotropic, have non-trivial spatial correlation and exhibit the hallmarks of finite range fluid turbulence; they have non-Gaussian distributions, exhibit Extended Self-Similarity in their scaling and are spatially multifractal. Furthermore, we find that the field J.E is also multifractal, so that magnetic energy is converted to plasma kinetic energy in a manner that is spatially intermittent. This suggests that dissipation in this sense in collisionless reconnection on kinetic scales has an analogue in fluid-like turbulent phenomenology, ...

Leonardis, E; Daughton, W; Roytershteyn, V; Karimabadi, H

2013-01-01T23:59:59.000Z

478

Crossing the mesoscale no-mans land via parallel kinetic Monte Carlo.  

Science Conference Proceedings (OSTI)

The kinetic Monte Carlo method and its variants are powerful tools for modeling materials at the mesoscale, meaning at length and time scales in between the atomic and continuum. We have completed a 3 year LDRD project with the goal of developing a parallel kinetic Monte Carlo capability and applying it to materials modeling problems of interest to Sandia. In this report we give an overview of the methods and algorithms developed, and describe our new open-source code called SPPARKS, for Stochastic Parallel PARticle Kinetic Simulator. We also highlight the development of several Monte Carlo models in SPPARKS for specific materials modeling applications, including grain growth, bubble formation, diffusion in nanoporous materials, defect formation in erbium hydrides, and surface growth and evolution.

Garcia Cardona, Cristina (San Diego State University); Webb, Edmund Blackburn, III; Wagner, Gregory John; Tikare, Veena; Holm, Elizabeth Ann; Plimpton, Steven James; Thompson, Aidan Patrick; Slepoy, Alexander (U. S. Department of Energy, NNSA); Zhou, Xiao Wang; Battaile, Corbett Chandler; Chandross, Michael Evan

2009-10-01T23:59:59.000Z

479

Crossing the mesoscale no-mans land via parallel kinetic Monte Carlo.  

SciTech Connect

The kinetic Monte Carlo method and its variants are powerful tools for modeling materials at the mesoscale, meaning at length and time scales in between the atomic and continuum. We have completed a 3 year LDRD project with the goal of developing a parallel kinetic Monte Carlo capability and applying it to materials modeling problems of interest to Sandia. In this report we give an overview of the methods and algorithms developed, and describe our new open-source code called SPPARKS, for Stochastic Parallel PARticle Kinetic Simulator. We also highlight the development of several Monte Carlo models in SPPARKS for specific materials modeling applications, including grain growth, bubble formation, diffusion in nanoporous materials, defect formation in erbium hydrides, and surface growth and evolution.

Garcia Cardona, Cristina (San Diego State University); Webb, Edmund Blackburn, III; Wagner, Gregory John; Tikare, Veena; Holm, Elizabeth Ann; Plimpton, Steven James; Thompson, Aidan Patrick; Slepoy, Alexander (U. S. Department of Energy, NNSA); Zhou, Xiao Wang; Battaile, Corbett Chandler; Chandross, Michael Evan

2009-10-01T23:59:59.000Z

480

Air Oxidation Kinetics for Zr-based Alloys [Corrosion and Mechanics of  

NLE Websites -- All DOE Office Websites (Extended Search)

Air Oxidation Kinetics for Air Oxidation Kinetics for Zr-based Alloys Capabilities Materials Testing Environmentally Assisted Cracking (EAC) of Reactor Materials Corrosion Performance/Metal Dusting Overview Light Water Reactors Fatigue Testing of Carbon Steels and Low-Alloy Steels Environmentally Assisted Cracking of Ni-Base Alloys Irradiation-Induced Stress Corrosion Cracking of Austenitic Stainless Steels Steam Generator Tube Integrity Program Air Oxidation Kinetics for Zr-based Alloys Fossil Energy Fusion Energy Metal Dusting Publications List Irradiated Materials Steam Generator Tube Integrity Other Facilities Work with Argonne Contact us For Employees Site Map Help Join us on Facebook Follow us on Twitter NE on Flickr Corrosion and Mechanics of Materials Light Water Reactors Bookmark and Share

Note: This page contains sample records for the topic "kinetic en ergy" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Application of fundamental kinetic modeling to industrial chlorination and partial oxidation processes  

E-Print Network (OSTI)

The Fundamental Kinetic Modeling (FKM) method is able to use a growing amount of elementary kinetic rate constant data to simulate industrial reactions and therefore gain insight and predictive capabilities beyond those of traditional empirical kinetic models. Because traditional empirical kinetic models often simplify the underlying kinetics into a single overall reaction, these recently determined values cannot be used directly. In addition to simulating irreducible chemical events as opposed to an overall reaction, the FKM does not make assumptions about microscopic reversibility. To obtain the reverse rate constants, the thermophysical properties for the species are required. Advances in computing technology have made ab initio quantum chemical calculations feasible for oxygenated and chlorinated hydrocarbons. Thermophysical properties for species that cannot be obtained experimentally are now available with greater accuracy than using prior estimating techniques. The FKM method is able to use these values to obtain information about temperature and concentration profiles as well as product distributions and selectivities for a variety of reactor configurations. The application of the FKM method to industrial reactions could be used to optimize existing operating conditions or to predict novel processes. One such chemistry is the oxychlorination of ethane to vinyl chloride. The problem is most easily solved in three steps: the development of a thermal chlorination model, the development of a partial oxidation model, and the combination of the two models with the necessary additional species and reactions. This work focuses on the first two steps. A thermal chlorination model is verified against two sources of experimental data with good quantitative agreement. In addition, differences in product distributions are explained by examining the kinetic pathways. Also, an existing partial oxidation model is combined with newly calculated thermophysical properties. The agreement with two experimental data sources is not as good quantitatively; however, qualitative agreement is observed. Areas for improvement to obtain quantitative agreement are determined.

Han, Joseph Hsiao-Tien

2000-01-01T23:59:59.000Z

482

Bench-scale Kinetics Study of Mercury Reactions in FGD Liquors  

SciTech Connect

This document is the final report for Cooperative Agreement DE-FC26-04NT42314, 'Kinetics Study of Mercury Reactions in FGD Liquors'. The project was co-funded by the U.S. DOE National Energy Technology Laboratory and EPRI. The objective of the project has been to determine the mechanisms and kinetics of the aqueous reactions of mercury absorbed by wet flue gas desulfurization (FGD) systems, and develop a kinetics model to predict mercury reactions in wet FGD systems. The model may be used to determine optimum wet FGD design and operating conditions to maximize mercury capture in wet FGD systems. Initially, a series of bench-top, liquid-phase reactor tests were conducted and mercury species concentrations were measured by UV/visible light spectroscopy to determine reactant and byproduct concentrations over time. Other measurement methods, such as atomic absorption, were used to measure concentrations of vapor-phase elemental mercury, that cannot be measured by UV/visible light spectroscopy. Next, a series of bench-scale wet FGD simulation tests were conducted. Because of the significant effects of sulfite concentration on mercury re-emission rates, new methods were developed for operating and controlling the bench-scale FGD experiments. Approximately 140 bench-scale wet FGD tests were conducted and several unusual and pertinent effects of process chemistry on mercury re-emissions were identified and characterized. These data have been used to develop an empirically adjusted, theoretically based kinetics model to predict mercury species reactions in wet FGD systems. The model has been verified in tests conducted with the bench-scale wet FGD system, where both gas-phase and liquid-phase mercury concentrations were measured to determine if the model accurately predicts the tendency for mercury re-emissions. This report presents and discusses results from the initial laboratory kinetics measurements, the bench-scale wet FGD tests, and the kinetics modeling efforts.

Gary Blythe; John Currie; David DeBerry

2008-03-31T23:59:59.000Z

483

Structural characterization and dehydration kinetics of Kirka inderite mineral: Application of non-isothermal models  

SciTech Connect

Coats-Redfern, Arrhenius, Ozawa, Kissinger, and Doyle non-isothermal kinetic models were used to calculate the dynamic kinetic parameters for dehydration reaction of Mg-borate mineral, inderite (Kirka - Turkey) based on thermogravimetric analysis, derivative thermogravimetric analysis and differential thermal analysis. Dehydration experiments were carried out at different heating rates of 2, 5, 10, 15, and 20 deg. C/min in a pure nitrogen atmosphere. Structural and morphological properties have been characterized by X-Ray diffraction, Fourier transform-infrared spectroscopy, Scanning electron microscopy-energy dispersive spectroscopy, and Inductively coupled plasma-optical emission spectroscopy techniques.

Figen, Aysel Kantuerk, E-mail: akanturk@yildiz.edu.tr [Yildiz Technical University, Department of Chemical Engineering, Davutpasa Campus., N.127, Esenler, Istanbul (Turkey); Yilmaz, Muege Sari, E-mail: mugesari@yildiz.edu.tr [Yildiz Technical University, Department of Chemical Engineering, Davutpasa Campus., N.127, Esenler, Istanbul (Turkey); Piskin, Sabriye, E-mail: piskin@yildiz.edu.tr [Yildiz Technical University, Department of Chemical Engineering, Davutpasa Campus., N.127, Esenler, Istanbul (Turkey)

2010-06-15T23:59:59.000Z

484

Computational model, method, and system for kinetically-tailoring multi-drug chemotherapy for individuals  

DOE Patents (OSTI)

A method and system for tailoring treatment regimens to individual patients with diseased cells exhibiting evolution of resistance to such treatments. A mathematical model is provided which models rates of population change of proliferating and quiescent diseased cells using cell kinetics and evolution of resistance of the diseased cells, and pharmacokinetic and pharmacodynamic models. Cell kinetic parameters are obtained from an individual patient and applied to the mathematical model to solve for a plurality of treatment regimens, each having a quantitative efficacy value associated therewith. A treatment regimen may then be selected from the plurlaity of treatment options based on the efficacy value.

Gardner, Shea Nicole (San Leandro, CA)

2007-10-23T23:59:59.000Z

485

Unstable kinetic roughening during the island coalescence stage of sputtered tantalum films  

Science Conference Proceedings (OSTI)

Kinetic roughening of tantalum films during the initial growth stages has been studied by atomic force microscopy, scanning electron microscopy, and dynamic scaling theory. Different from the time-independent scaling behavior for continuous film growth, an intriguing unstable kinetic roughening occurs during island coalescence. In such case, roughness exponent {alpha} increases with growth time, accompanied by lower growth exponent {beta} and higher coarsening exponent {eta}. Detailed analysis of film surface morphology and simple phenomenological models suggests that this unstable behavior is related to the pronounced lateral growth of surface islands, which arises from the combined effect of the formation of grain boundary and the covering of heterogeneous substrate surface.

Yang, J. J.; Tang, J.; Liu, N. [Key Laboratory of Radiation Physics and Technology, Ministry of Education, Institute of Nuclear Science and Technology, Sichuan University, Chengdu 610064 (China); Ma, F.; Xu, K. W. [State Key Laboratory of Mechanical Behavior of Materials, Xi'an Jiaotong University, Xi'an 710049 (China); Tang, W. [State Key Laboratory of Electronic Thin Films and Integrated Devices, University of Electronic Science and Technology of China, Chengdu 610054 (China)

2012-05-15T23:59:59.000Z

486

Novel Kinetic 3D MHD Algorithm for High Performance Parallel Computing Systems  

E-Print Network (OSTI)

The impressive progress of the kinetic schemes in the solution of gas dynamics problems and the development of effective parallel algorithms for modern high performance parallel computing systems led to the development of advanced methods for the solution of the magnetohydrodynamics problem in the important area of plasma physics. The novel feature of the method is the formulation of the complex Boltzmann-like distribution function of kinetic method with the implementation of electromagnetic interaction terms. The numerical method is based on the explicit schemes. Due to logical simplicity and its efficiency, the algorithm is easily adapted to modern high performance parallel computer systems including hybrid computing systems with graphic processors.

B. Chetverushkin; N. D'Ascenzo; V. Saveliev

2013-05-03T23:59:59.000Z

487

Kinetics of simultaneous two-phase precipitation in the Fe-C system  

Science Conference Proceedings (OSTI)

A theoretical approach for the interpretation of the kinetics of simultaneous stable and metastable phase precipitation in a binary system is proposed. The model, based on the nucleation and growth theory, defines a critical size different for each phase. The size of the clusters evolves by adding or subtracting a single atom one at a time. A set of coupled differential equations is obtained for the chemical rate whose solution reproduces the kinetics of thermoelectric power measurements in the Fe-C multiphase system. Suppositions about the growing and dissolution rate constants reduce the size of the equation system with a gain in computation time.

Luiggi, N.; Betancourt, A. [Univ. de Oriente, Cumana (Venezuela)

1997-02-01T23:59:59.000Z

488

Energy stability analysis for a hybrid fluid-kinetic plasma model  

E-Print Network (OSTI)

In plasma physics, a hybrid fluid-kinetic model is composed of a magnetohydrodynamics (MHD) part that describes a bulk fluid component and a Vlasov kinetic theory part that describes an energetic plasma component. While most hybrid models in the plasma literature are non-Hamiltonian, this paper investigates a recent Hamiltonian variant in its two-dimensional configuration. The corresponding Hamiltonian structure is described along with its Casimir invariants. Then, the energy-Casimir method is used to derive explicit sufficient stability conditions, which imply a stable spectrum and suggest nonlinear stability.

Philip J. Morrison; Emanuele Tassi; Cesare Tronci

2013-06-11T23:59:59.000Z

489

Kinetics of decomposition of Colorado oil shale. I. Oil generation. [Use of isothermal and nonisothermal methods  

DOE Green Energy (OSTI)

Isothermal and nonisothermal methods were used to investigate the kinetics of oil generation during decomposition of 91.7 l/tonne (22-gal/ton) Colorado oil shale. The average of the results from these two methods gives an activation energy of 52.0 kcal/mole and a frequency factor of 3 x 10/sup 13/s/sup -1/. The process is found to be first order to within experimental error. These results compare favorably with data reported in the literature. The reliability and ease of carrying out nonisothermal kinetic experiments to study solid decomposition reactions is demonstrated. Moreover, nonisothermal experiments more accurately simulate actual in situ processing conditions.

Campbell, J.H.; Koskinas, G.; Stout, N.

1976-06-25T23:59:59.000Z

490

Time-dependent gas phase kinetics in a hydrogen diluted silane plasma  

SciTech Connect

The gas phase kinetics in a high-pressure hydrogen diluted silane plasma has been studied at time scales of 10{sup -2}-6x10{sup 2} s. The time-resolved gas phase composition shows the following kinetics at different time scales: silane decomposition and polysilane generation in < or approx. 2x10{sup -1} s, nanoparticle formation and plasma density reduction in 10{sup -1}-10{sup 0} s, polysilane accumulation in 10{sup 0}-10{sup 2} s, and silane depletion and electrode heating in > or approx. 10{sup 1} s. Disilane radicals are implied to be the dominant film precursors in addition to silyl radicals.

Nunomura, S.; Kondo, M. [Research Center for Photovoltaics, National Institute of Advanced Industrial Science and Technology, 1-1-1 Umezono, Tsukuba, Ibaraki 305-8568 (Japan); Yoshida, I. [Research Center for Photovoltaics, National Institute of Advanced Industrial Science and Technology, 1-1-1 Umezono, Tsukuba, Ibaraki 305-8568 (Japan); Advanced Photovoltaics Development Center, Advanced Energy Research Center, Sanyo Electric Co., Ltd., 108 Ohmori, Anpachi-cho, Anpachi-gun, Gifu 503-0195 (Japan)

2009-02-16T23:59:59.000Z