Sample records for js rogers sr

  1. MEMORANDUM 2013/14-9 To: Members of the Edward S. Rogers Sr. Department of Electrical and Computer Engineering

    E-Print Network [OSTI]

    Prodiæ, Aleksandar

    S. Rogers Sr. Department of Electrical and Computer Engineering I am very pleased to announce the re-appointment of Professor Farid Najm as Chair of the Edward S. Rogers Sr. Department of Electrical and Computer Engineering. Department of Electrical and Computer Engineering in 1999. He received his B.E. degree from the American

  2. Recovery Act update from Sr. Advisor Matt Rogers-- End of Obligations

    Broader source: Energy.gov [DOE]

    Matt Rogers, Senior Advisor to the Secretary for Recovery Act Implementation, shares his thoughts as the Recovery Act reaches a critical milestone -- the end of the 2010 fiscal year and the last...

  3. Recovery Act update from Sr. Advisor Matt Rogers -- End of Obligations

    SciTech Connect (OSTI)

    Rogers, Matt

    2010-01-01T23:59:59.000Z

    Senior Advisor to the Secretary for Recovery Act Implementation Matt Rogers shares his thoughts as the Recovery Act reaches a critical milestone -- the end of the 2010 fiscal year and the last day to obligation contract and grant funding under the Recovery Act. For more information about the Recovery Act at the Department of Energy: http://www.energy.gov/recovery Follow the Department of Energy! http://facebook.com/energygov http://twitter.com/energy

  4. Recovery Act update from Sr. Advisor Matt Rogers -- End of Obligations

    ScienceCinema (OSTI)

    Rogers, Matt

    2013-05-29T23:59:59.000Z

    Senior Advisor to the Secretary for Recovery Act Implementation Matt Rogers shares his thoughts as the Recovery Act reaches a critical milestone -- the end of the 2010 fiscal year and the last day to obligation contract and grant funding under the Recovery Act. For more information about the Recovery Act at the Department of Energy: http://www.energy.gov/recovery Follow the Department of Energy! http://facebook.com/energygov http://twitter.com/energy

  5. Trinity College Dublin JS Handbook

    E-Print Network [OSTI]

    O'Mahony, Donal E.

    ............................................................................ 2 Course Overview .............................................................................. 2 Credit Transfer System (ECTS) ............................................. 4 Placement and Pre in course handbooks, the provisions of the General Regulations will prevail. Course Overview The JS year

  6. Roger M. Claycomb- Biography

    Broader source: Energy.gov [DOE]

    Roger Claycomb has more than 30 years of experience in the nuclear industry in both nuclear facility operations and oversight.

  7. Water Waves Roger Grimshaw

    E-Print Network [OSTI]

    ,2) provide a kinematic description of water waves, which to this point means that the conditionsWater Waves Roger Grimshaw May 7, 2003 Abstract A short review of the theory of weakly nonlinear water waves, prepared for the forthcoming Encyclopedia of Nonlinear Science 1 Introduction Water waves

  8. Departure Roger Anthoine

    ScienceCinema (OSTI)

    None

    2011-04-25T23:59:59.000Z

    Remerciements et discours du D.G. H.Schopper à l'occasion du départ de Roger Anthoine (attaché de presse), qui travaillait dans la communication et quitte le Cern après 27 ans de service. Il gardait des relations avec des médias internationaux et la presse locale; remise des cadeaux: album photo avec images des musés de Genève et un radio aviation; R.A. fait un résumé de ses activités et souvenirs et remercie ses collaborateurs

  9. A Computable Approach to Validation Roger Ghanem

    E-Print Network [OSTI]

    , USA Roger Ghanem ()Uncertainty- PNNL- August 16 2010 1 / 53 #12;1 Objectives 2 Inspiration from Conclusion Roger Ghanem ()Uncertainty- PNNL- August 16 2010 2 / 53 #12;Historical Perspective Aristotle Wiener · · · Roger Ghanem ()Uncertainty- PNNL- August 16 2010 3 / 53 #12;Historical Perspective Aristotle

  10. Roger L. Berger University Address

    E-Print Network [OSTI]

    , Purdue University School of Science 1999 Elected Fellow of the American Statistical Association 1993 Association Eastern North American Region of the Institute of Mathematical Statistics International Biometric and Jian Tao." Journal of the American Statistical Association, 105, 1629­1630. Berger, Roger L. (2007

  11. Tom Rogers Director, Industrial Partnerships

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over OurThe Iron Spin Transition in2, 2003 (NextTime-ResolvedTo: Ms.CampbellTom Rogers,

  12. Faces of Science: Roger Wiens

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville Power AdministrationField8,Dist. Category UC-lFederalFY 2008 FOIAFabricatedJuan DuqueNateRoger

  13. Matt Rogers | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(FactDepartment3311, 3312), October 20122 DOEDepartment of EnergyComptonRogers

  14. Faces of Science: Roger Wiens

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Science (SC) Environmental Assessments (EA)Budget » FY 2014 BudgetNate McDowell Faces ofRoger

  15. A solar concentrating photovoltaic / thermal collector J.S. Coventry

    E-Print Network [OSTI]

    A solar concentrating photovoltaic / thermal collector J.S. Coventry Centre for Sustainable Energy.Coventry@anu.edu.au Abstract Australia is a good location for solar concentrator applications. Current activities in Australia OF THE SOLAR RESOURCE IN AUSTRALIA Australia has relatively high solar insolation, as shown in figure 1

  16. ME 4210: Manufacturing Processes and Engineering Prof. J.S. Colton GIT 2009

    E-Print Network [OSTI]

    Colton, Jonathan S.

    illegitimi carborundum ver. 1 #12;ME 4210: Manufacturing Processes and Engineering Prof. J.S. Colton © GIT

  17. Rogers, Minnesota: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere IRaghuraji Agro Industries Pvt Ltd Jump to: navigation,MazeOhio:Ohio:Rockwall County,Ridge,Roger MillsRogers,

  18. Matt Rogers on AES Energy Storage

    ScienceCinema (OSTI)

    Rogers, Matt

    2013-05-29T23:59:59.000Z

    The Department of Energy and AES Energy Storage recently agreed to a $17.1M conditional loan guarantee commitment. This project will develop the first battery-based energy storage system to provide a more stable and efficient electrical grid for New York State's high-voltage transmission network. Matt Rogers is the Senior Advisor to the Secretary for Recovery Act Implementation.

  19. Solitary waves propagating over variable Roger Grimshaw

    E-Print Network [OSTI]

    Solitary waves propagating over variable topography Roger Grimshaw Loughborough University waves that can propagate steadily over long distances. They were first observed by Russell in 1837 in a now famous report [26] on his observations of a solitary wave propagating along a Scottish canal

  20. Proton Absorber Feasibility Study Chris Rogers,

    E-Print Network [OSTI]

    McDonald, Kirk

    Proton Absorber ­ Feasibility Study Chris Rogers, ASTeC, Rutherford Appleton Laboratory 14 Sept 2010 #12;Overview We have a problem with secondary protons in the front end Deposit significant Need remote handling (ouch) One way to fix this is using a proton absorber Change in beam power

  1. CURRICULUM VITAE Dr. Dale S. Rogers

    E-Print Network [OSTI]

    Lin, Xiaodong

    Administration (1983) Michigan State University Major: Materials and Logistics Management Bachelor of Arts (19791 CURRICULUM VITAE Dr. Dale S. Rogers Rutgers University Supply Chain Management & Marketing Professor of Logistics and Supply Chain Management, Co-Director of the Center for Supply Chain Management

  2. Prof. Roger Wattenhofer http://www.dcg.ethz.ch

    E-Print Network [OSTI]

    @tik.ee.ethz.ch, ETZ G61.3, · Philipp Sommer: sommer@tik.ee.ethz.ch, ETZ G64.1 · Roger Wattenhofer: wattenhofer

  3. ME 4210: Manufacturing Processes and Engineering Prof. J.S. Colton GIT 2011

    E-Print Network [OSTI]

    Colton, Jonathan S.

    ME 4210: Manufacturing Processes and Engineering Prof. J.S. Colton © GIT 2011 1 Rapid Prototyping ver. 1 #12;ME 4210: Manufacturing Processes and Engineering Prof. J.S. Colton © GIT 2011 2 Process · Additive fabrication ­ material is added, not removed · Direct fabrication from a CAD file · Layered

  4. ME 4210: Manufacturing Processes and Engineering Prof. J.S. Colton GIT 2011

    E-Print Network [OSTI]

    Colton, Jonathan S.

    2011 9 Friction stir welding · used for aluminum · requires no filler · low distortion · low Processes and Engineering Prof. J.S. Colton © GIT 2011 10 Friction Stir Welding #12;ME 4210: Manufacturing Processes and Engineering Prof. J.S. Colton © GIT 2011 11 Friction Stir Welding FSW Normal weld #12;ME 4210

  5. ME 6222: Manufacturing Processes and Systems Prof. J.S. Colton GIT 2011

    E-Print Network [OSTI]

    Colton, Jonathan S.

    Thermit · Steel and cast iron welding · 3/4 Fe3O4 + 2 Al -> 9/4 Fe + Al2O3 + heat · 3 FeO + 2 Al -> 3 Fe: Manufacturing Processes and Systems Prof. J.S. Colton © GIT 2011 18 Thermit · Copper, brass and bronze welding: Manufacturing Processes and Systems Prof. J.S. Colton © GIT 2011 19 Thermit · Oxides of nickel, chromium

  6. ME 6222: Manufacturing Processes and Systems Prof. J.S. Colton GIT 2011

    E-Print Network [OSTI]

    Colton, Jonathan S.

    Processes and Systems Prof. J.S. Colton © GIT 2011 9 Forging pressure ­ sliding region h x 2011 10 Average forging pressure ­ sliding k x k x k x x ave x h xh x dx h x x dx k p k p kkk 000 2 exp: Manufacturing Processes and Systems Prof. J.S. Colton © GIT 2011 13 Average forging pressure ­ all sliding

  7. VBA-0032- In the Matter of Roger H. Hardwick

    Broader source: Energy.gov [DOE]

    This Decision considers an Appeal of an Initial Agency Decision issued on July 6, 1999, on a complaint filed by Roger H. Hardwick (Hardwick or the complainant) under the Department of Energy (DOE)...

  8. Genome Sequence of the Ethene- and Vinyl Chloride-Oxidizing Actinomycete Nocardioides sp Strain JS614

    SciTech Connect (OSTI)

    Coleman, Nicholas V [University of Sydney, Australia; Wilson, Neil L [University of Sydney, Australia; Barry, Kerrie [U.S. Department of Energy, Joint Genome Institute; Bruce, David [Los Alamos National Laboratory (LANL); Copeland, A [U.S. Department of Energy, Joint Genome Institute; Dalin, Eileen [U.S. Department of Energy, Joint Genome Institute; Detter, J. Chris [U.S. Department of Energy, Joint Genome Institute; Glavina Del Rio, Tijana [U.S. Department of Energy, Joint Genome Institute; Goodwin, Lynne A. [Los Alamos National Laboratory (LANL); Hammon, Nancy [U.S. Department of Energy, Joint Genome Institute; Han, Shunsheng [Los Alamos National Laboratory (LANL); Hauser, Loren John [ORNL; Israni, Sanjay [U.S. Department of Energy, Joint Genome Institute; Kim, Edwin [U.S. Department of Energy, Joint Genome Institute; Kyrpides, Nikos C [U.S. Department of Energy, Joint Genome Institute; Land, Miriam L [ORNL; Lapidus, Alla L. [U.S. Department of Energy, Joint Genome Institute; Larimer, Frank W [ORNL; Lucas, Susan [U.S. Department of Energy, Joint Genome Institute; Pitluck, Sam [U.S. Department of Energy, Joint Genome Institute; Richardson, Paul [U.S. Department of Energy, Joint Genome Institute; Schmutz, Jeremy [Stanford University; Tapia, Roxanne [Los Alamos National Laboratory (LANL); Thompson, Sue [Los Alamos National Laboratory (LANL); Tice, Hope [U.S. Department of Energy, Joint Genome Institute; Spain, Jim C [Georgia Institute of Technology; Gossett, James G [Cornell University; Mattes, Timothy E [University of Iowa

    2011-01-01T23:59:59.000Z

    Nocardioides sp. strain JS614 grows on ethene and vinyl chloride (VC) as sole carbon and energy sources and is of interest for bioremediation and biocatalysis. Sequencing of the complete genome of JS614 provides insight into the genetic basis of alkene oxidation, supports ongoing research into the physiology and biochemistry of growth on ethene and VC, and provides biomarkers to facilitate detection of VC/ethene oxidizers in the environment. This is the first genome sequence from the genus Nocardioides and the first genome of a VC/ethene-oxidizing bacterium.

  9. ME 4210: Manufacturing Processes and Engineering -Prof. J.S. Colton GIT 2011

    E-Print Network [OSTI]

    Colton, Jonathan S.

    or both · Open or closed (flash) · Key additional limitation ­ die pressure #12;ME 4210: ManufacturingME 4210: Manufacturing Processes and Engineering - Prof. J.S. Colton © GIT 2011 1 Topical Course Review No warranty as to completeness #12;ME 4210: Manufacturing Processes and Engineering - Prof. J

  10. John Marshall Particle Flow Calorimetry 1 J.S. Marshall, M.A. Thomson

    E-Print Network [OSTI]

    Glasgow, University of

    John Marshall Particle Flow Calorimetry 1 J.S. Marshall, M.A. Thomson University of Cambridge #12;John Marshall Particle Flow Calorimetry 2 Overview 1. e+e- Physics and LC Jet Energy Requirements 2 at CLIC 8. CLIC Benchmark Physics Analyses 9. Summary #12;John Marshall Particle Flow Calorimetry 3 e

  11. ME 6222: Manufacturing Processes and Systems Prof. J.S. Colton GIT 2009

    E-Print Network [OSTI]

    Colton, Jonathan S.

    ­ Air (oxygen), vacuum, inert gas (argon) · Heating ­ External - electric, gas, oil ­ Internal Prof. J.S. Colton © GIT 2009 11 Processes · Sand · Shell · Plaster · Ceramic · Investment · Lost foam Metals processed by casting · Sand casting ­ 60% · Investment casting ­ 7% · Die casting ­ 9% · Permanent

  12. Helium Jet-Cooled Tungsten Divertor Concept J.S. O'Della

    E-Print Network [OSTI]

    Raffray, A. René

    Helium Jet-Cooled Tungsten Divertor Concept J.S. O'Della and A.R. Raffrayb a Plasma Processes, Inc., Huntsville, Alabama, USA b University of California ­ San Diego, La Jolla, California, USA Abstract-- Helium helium cooling techniques for high heat flux (HHF) applications. However, because of the small size

  13. ME 6222: Manufacturing Processes and Systems Prof. J.S. Colton GIT 2011

    E-Print Network [OSTI]

    Colton, Jonathan S.

    temperatures, easy to diffusion bond. · Iron, titanium and copper also can be diffusion bonded, because · Diffusion bonding · Soldering and brazing · Fusion welding #12;ME 6222: Manufacturing Processes and Systems Prof. J.S. Colton © GIT 2011 3 Diffusion bonding · High pressure and temperature for extended periods

  14. ME 4210: Manufacturing Processes and Engineering Prof. J.S. Colton GIT 2011

    E-Print Network [OSTI]

    Colton, Jonathan S.

    Definition · A microscopic mixture of two or more different materials. One typically being the continuous 4210: Manufacturing Processes and Engineering Prof. J.S. Colton © GIT 2011 11 #12;Stealth Ships ME 4210-up Material on stiffening structure Vacuum bag and fittings attached #12;ME 4210: Manufacturing Processes

  15. SafeJS: Hermetic Sandboxing for JavaScript Damien Cassou Stphane Ducasse Nicolas Petton

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    This section presents some web standards (DOM and web workers) that are key to SafeJS design and implementation) as "an application programming interface (API) for HTML and XML documents" [ABC+ 98]. The DOM an API to let developers add, modify and delete elements from an HTML (in fact any XML) document. The DOM

  16. UO Retirement Recognition Reception Pap Reception Hall, J.S. Museum of Art

    E-Print Network [OSTI]

    Oregon, University of

    UO Retirement Recognition Reception Papé Reception Hall, J.S. Museum of Art Thursday, June 16, 2011 Information Services 29½ Years Richard Edwards Early Childhood CARES 11 Years Kayla Hinds Architecture will not be attending the retirement reception. They asked that we announce their retirement. Robert Barton Theatre Arts

  17. ME 4210: Manufacturing Processes and Engineering -Prof. J.S. Colton GIT 2011

    E-Print Network [OSTI]

    Colton, Jonathan S.

    float glass process · Bottle manufacture ­ Codd bottles ­ Ramune bottles #12;ME 4210: Manufacturing a system for keeping fizzy drinks in bottles with a glass marble stopper. · When the bottle is filledME 4210: Manufacturing Processes and Engineering - Prof. J.S. Colton © GIT 2011 1 Glass Manufacture

  18. Andrew D Booth Britain's Other "Fourth Man" Roger G. Johnson

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    . Keywords. Andrew Booth, Kathleen Booth, Norman Kitz, computer pioneer, Booth multiplier, magnetic drumAndrew D Booth ­ Britain's Other "Fourth Man" Roger G. Johnson Dept of Computer Science.johnson@bcs.org.uk Abstract. Andrew Donald Booth (1918-2009) was the leader of a team of computer pioneers at Birkbeck College

  19. Rendering Implicit Flow Volumes Daqing Xue, Caixia Zhang, Roger Crawfis*

    E-Print Network [OSTI]

    Crawfis, Roger

    Rendering Implicit Flow Volumes Daqing Xue, Caixia Zhang, Roger Crawfis* Department of Computer and then rendered using an unstructured volume rendering technique. Unless a detailed refinement of the flow volume-dimensional texture mapping and an interval volume segmentation coupled with a tetrahedron projection-based renderer

  20. Economics for a Creative World1 ROGER KOPPL

    E-Print Network [OSTI]

    Longo, Giuseppe

    Economics for a Creative World1 ROGER KOPPL Whitman School of Management, Syracuse University Economics, 2015, to appear. #12;#12;Abstract Drawing on current biology, we argue that the phase space of economic evolution is not stable. Thus, there are no entailing laws of economic dynamics. In this sense

  1. The Human Plutonium Injection Experiments William Moss and Roger Eckhardt

    E-Print Network [OSTI]

    Massey, Thomas N.

    177 The Human Plutonium Injection Experiments William Moss and Roger Eckhardt T he human plutonium that was pertinent to those and LouisHempelmann #12;similar radiation experi- ments with humans. This article injection experiments carried out during and after the Manhattan Project have received tremendous noto

  2. Dr. Dale S. Rogers Professor, Logistics & Supply Chain Management

    E-Print Network [OSTI]

    Lin, Xiaodong

    Dr. Dale S. Rogers Professor, Logistics & Supply Chain Management Co-Director, Center for Supply Chain Management Rutgers University Rutgers VICS Logistics Summit September 27, 2011 New Brunswick, NJ The Future of Global Logistics #12;The Future of Global Logistics Future of Global Logistics · Introduction

  3. ME 6222: Manufacturing Processes and Systems Prof. J.S. Colton GIT 2011

    E-Print Network [OSTI]

    Colton, Jonathan S.

    © GIT 2011 7 Forging pressure - sliding dr hp dp R rp flow r 2 2 rR h p flow r 2 exp 2 forging pressure ­ sliding drrrR hrR drr p rR p R rk R r flow r kflow ave kk 2 exp 2 2 Prof. J.S. Colton © GIT 2011 9 Average forging pressure ­ sliding

  4. Demo Abstract: The SpiderBat Ultrasound Positioning System Georg Oberholzer, Philipp Sommer, Roger Wattenhofer

    E-Print Network [OSTI]

    Demo Abstract: The SpiderBat Ultrasound Positioning System Georg Oberholzer, Philipp Sommer, Roger Wattenhofer Computer Engineering and Networks Laboratory ETH Zurich, Switzerland sommer

  5. Planipes: Mobile Foot Pressure Analysis Samuel Pfaffen, Philipp Sommer, Christian Stocker, Roger Wattenhofer, and Samuel Welten

    E-Print Network [OSTI]

    Planipes: Mobile Foot Pressure Analysis Samuel Pfaffen, Philipp Sommer, Christian Stocker, Roger, sommer, chstocke, wattenhofer, welten}@tik.ee.ethz.ch Abstract Analyzing foot pressure is helpful

  6. LANL Researcher Roger Wiens Discusses ChemCam

    ScienceCinema (OSTI)

    Wiens, Roger

    2014-08-12T23:59:59.000Z

    Discussion of the ChemCam instrument on the Curiosity Rover that occurred during the NASA press conference prior to launch of the Mars Science Laboratory. The ChemCam instrument was developed by Los Alamos National Laboratory and the French Space Institute. Los Alamos National Laboratory researcher Roger Wiens discusses the instrument on this video. ChemCam uses a laser to "zap" features of the Martian landscape and then uses a spectrometer to gather information about the composition of the sample. ChemCam will help the Curiosity Rover determine whether Mars is or was habitable. The Rover is expected to touch down on the Red Planet on August 5, 2012.

  7. Roger D. Kornberg Polymerase, DNA, RNA, and Transcription

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Scienceand Requirements RecentlyElectronicResources ResourcesRobust, High-ThroughputRocksRoger D.

  8. Roger Mills County, Oklahoma: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere IRaghuraji Agro Industries Pvt Ltd Jump to: navigation,MazeOhio:Ohio:Rockwall County,Ridge,Roger Mills County,

  9. Rogers County, Oklahoma: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov YouKizildere IRaghuraji Agro Industries Pvt Ltd Jump to: navigation,MazeOhio:Ohio:Rockwall County,Ridge,Roger Mills

  10. TECHNICAL PUBLICATIONS & BOOKS PRESENTED/PUBLISHED GOMES J.S. & ALVES, F.B. (2013): "The Universe of the Oil & Gas Industry From Exploration to Refining", 780

    E-Print Network [OSTI]

    Williams, John M.

    2013-01-01T23:59:59.000Z

    Universe of the Oil & Gas Industry ­ From Exploration to Refining", 780 pages University textbook published by PARTEX Oil & Gas, Lisbon, Portugal. ISBN 9789892037783. GOMES J.S. (2012): "New Technologies in the Oil and Gas Industry", edited by J.S. Gomes, published by INTECH open science (www

  11. Summary We analyzed assumptions and measurement er-rors in estimating canopy transpiration (EL) from sap flux (JS)

    E-Print Network [OSTI]

    Ewers, Brent E.

    - tively. Sap flux measured in stems did not lag JS measured in branches, and time and frequency domain. Introduction Stomata respond to environmental variation, regulate water loss and carbon dioxide gain, and thus biosphere­atmosphere exchange of mass and energy. From porometry measure- ments, leaf conductance (gS) can

  12. Gas Spring Losses in Linear Clearance Seal Compressors P.B. Bailey, M.W. Dadd, J.S. Reed*

    E-Print Network [OSTI]

    1 Gas Spring Losses in Linear Clearance Seal Compressors P.B. Bailey, M.W. Dadd, J.S. Reed* , C investigations on conventional crank driven reciprocating compressors, where the use of normal sliding seals would minimise seal losses. The widespread use of linear clearance seals in linear compressor has raised

  13. CORBA-JS: An Open-Standards Framework for Distributed Object Computing over the Web Tejal B. Parulekar1

    E-Print Network [OSTI]

    Zhou, Yaoqi

    CORBA-JS: An Open-Standards Framework for Distributed Object Computing over the Web Tejal B technological limitations, DOC was traditionally unavailable in Web-based applications (i.e., stateful applications that communicate over HTTP, and are accessible via a Web browser) without the use of proprietary

  14. Effect of Specimen Conditioning on Geosynthetic Clay Liner Shear J.S. McCartney & J.G. Zornberg

    E-Print Network [OSTI]

    Zornberg, Jorge G.

    635 Effect of Specimen Conditioning on Geosynthetic Clay Liner Shear Strength J.S. McCartney & J of geosynthetic clay liners (GCLs) must replicate field conditions while still accounting for time and cost to conditioning. 1 INTRODUCTION Geosynthetic clay liners (GCLs) are prefabricated geocomposite materials used

  15. Name Class PMAJ1 Abbas, Sami F SR MEE

    E-Print Network [OSTI]

    Wong, Pak Kin

    , William Reed SR OSE Broschat, Cary Jonathan SR EMG Brown, Bryant Patrick SR EMG Budinger, Timothy C SR EMGName Class PMAJ1 Abbas, Sami F SR MEE Alderink, Andrew SR CVE Anderson, Jonathan C SR EHY Araiza Bunting, Matthew Robert SR ELE Burr, Shawn P SR CHE Caglio, Joseph Matthew SR COE Candelaria, Patrick Ryan

  16. Global episodic beta/gamma synchrony 1 Freeman & Rogers A neurobiological theory of meaning in perception.

    E-Print Network [OSTI]

    Freeman, Walter J.

    Global episodic beta/gamma synchrony 1 Freeman & Rogers A neurobiological theory of meaning words: analytic phase, beta oscillation, EEG synchronization, gamma oscillation, Hilbert transform, phase transition Running Title: Global episodic beta/gamma synchrony #12;Global episodic beta

  17. LEGO AND AERONAUTICS IN KINDERGARTEN THROUGH COLLEGE Peter Capozolli and Chris Rogers

    E-Print Network [OSTI]

    LEGO AND AERONAUTICS IN KINDERGARTEN THROUGH COLLEGE Peter Capozolli and Chris Rogers Department arts students as well as first-year engineers. In particular, the lessons center around aeronautics

  18. A possible mechanism for ENSO turnabouts Bin Wang*, Renguang Wu, Roger Lukas, and Soon-Il An*

    E-Print Network [OSTI]

    Wang, Bin

    1 A possible mechanism for ENSO turnabouts Bin Wang*, Renguang Wu, Roger Lukas, and Soon-Il An to J. Climate July 8, 1999

  19. Ikarus: Large-Scale Participatory Sensing at High Altitudes Michael von Kaenel, Philipp Sommer, and Roger Wattenhofer

    E-Print Network [OSTI]

    Ikarus: Large-Scale Participatory Sensing at High Altitudes Michael von Kaenel, Philipp Sommer, and Roger Wattenhofer Computer Engineering and Networks Laboratory ETH Zurich, Switzerland {vkaenemi,sommer

  20. Name Class PMAJ1 Abbasi, Mahad SR OSE

    E-Print Network [OSTI]

    Wong, Pak Kin

    Balagopal, Tulika C. SR BE Balthazar, Michael A SR AEE Barnum, Matthew Nien Yi SO CHE Barzanjy, Zanyar, William Cyrus SR MEE Finkelstein, Aubrey J SR ENGR Fleischman, Megan Ashley SR MEE Fox, Bradley Hyland SR, Ari Joseph SR ENGR Goldstein, Samuel Jacob SR OSE Gosla, Calvin Bernard, III SR AEE Grosman, Joshua

  1. 305Sec. 4-9 Pump Placement To Avoid Cavitation -r-;0-J.s;,

    E-Print Network [OSTI]

    Kostic, Milivoje M.

    305Sec. 4-9 Pump Placement To Avoid Cavitation 6o q -.:.. 1.01 ll.oo -r-;0- J.s;, with permission, Worthington Division, McGraw-Edison Co.) changes in the downstream direction until the pump inletHt - g - (4-35a)Pfgc Pressure in suction tank P, Suction pressure Pump FIGURE 4-43 System schematic

  2. Long Term Dynamics of Inequalities between French Households concerning Automobile COLLET, Roger; BOUCQ, Elise; MADRE, Jean-Loup; HIVERT, Laurent.

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Long Term Dynamics of Inequalities between French Households concerning Automobile COLLET, Roger TERM DYNAMICS OF INEQUALITIES BETWEEN FRENCH HOUSEHOLDS CONCERNING AUTOMOBILE Roger Collet, INRETS of automobile. As the curves representing car ownership (number of cars per adult) and car use (annual mileage

  3. SR Newsletter. No. 31

    SciTech Connect (OSTI)

    Crowe, K.M.; Portis, A.M.; Yamazaki, T. (eds.)

    1985-10-30T23:59:59.000Z

    Topics covered in this issue include observation of decoupled diagmagnetic muon states in alkali halides by muon spin resonance, diffusion properties of the muon-produced soliton in trans-polyacetylene, pulsed muon spin resonance measurement of negative muon depolarization in muonic TC and UN, muonium to diamagnetic muon transition in KCl and NaCl revealed by time-differential muon spin resonance, recent topics in muon spin polarization phenomena and SR experiments, observation of muon-fluorine ''hydrogen'' bonding in ionic crystals, a spin rotator for muon-plus beams on the new M20 muon channel at TRIUMF, and resolved nuclear hyperfine structure of muonated free radicals using level crossing spectroscopy. (GHT)

  4. Roger E Husser, Jr., M.S., P.E. Planning, Design & Construction

    E-Print Network [OSTI]

    Harms, Kyle E.

    Roger E Husser, Jr., M.S., P.E. Director Planning, Design & Construction Herschel Hoffpauir Associate Director Campus Design & Construction Cliff Gillio Manager Mechanical Engineering Neal Pendleton Project Manager Architect Danielle Welborn Civil Engineer Planning, Design & Construction 1/13/2014 Hari

  5. IEAB Independent Economic Roger Mann, Chair Hans Radtke, Vice-Chair

    E-Print Network [OSTI]

    IEAB Independent Economic Roger Mann, Chair Hans Radtke, Vice-Chair Susan S. Hanna John Duffield Analysis Board Daniel D. Huppert Joel R. Hamilton Noelwah R. Netusil Economic Risk Associated with the Potential Establishment of Zebra and Quagga Mussels in the Columbia River Basin Independent Economic

  6. Layers for Effective Volume Rendering Sundaresan Raman, Oleg Mishchenko, and Roger Crawfis, Member, IEEE Computer Society

    E-Print Network [OSTI]

    Crawfis, Roger

    Layers for Effective Volume Rendering Sundaresan Raman, Oleg Mishchenko, and Roger Crawfis, Member, IEEE Computer Society Abstract--A multi-layer volume rendering framework is presented. The final image is obtained by compositing a number of renderings, each being represented as a separate layer. This layer

  7. Adsorption of Charge-Bidisperse Mixtures of Colloidal Jeffrey J. Gray and Roger T. Bonnecaze*

    E-Print Network [OSTI]

    Gray, Jeffrey J.

    Adsorption of Charge-Bidisperse Mixtures of Colloidal Particles Jeffrey J. Gray and Roger T with the number of components in the system. Here, we perform simulations of the adsorption of binary mixtures%. In sequential adsorption, small amounts of the second component adsorb only for parameter combinations

  8. Abduction in Model Generative Reasoning Roger T. Hartley and Michael J. Coombs

    E-Print Network [OSTI]

    Hartley, Roger

    Abduction in Model Generative Reasoning Roger T. Hartley and Michael J. Coombs Computer Science, 1990 1 Introduction Most of the abductive mechanisms in the literature are based on formalizations (binary) operations on these graphs. The equivalence of the method to logical abduction is noted

  9. Stochastic Differential Equations for Power Law Behaviors Bo Jiang Roger Brockett Weibo Gong Don Towsley

    E-Print Network [OSTI]

    Kurose, Jim

    Stochastic Differential Equations for Power Law Behaviors Bo Jiang Roger Brockett Weibo Gong Don- bridge, MA 02138, USA. Email: brockett@seas.harvard.edu. W. Gong is with the Deparment of Electrical and Computer Engineer- ing, University of Massachusetts, Amherst, MA 01003, USA. Email: gong

  10. Jason S.Lamoureux, David Stuart, Roger Tsang, Cynthia Wu and

    E-Print Network [OSTI]

    Glover, Mark

    Jason S.Lamoureux, David Stuart, Roger Tsang, Cynthia Wu and J.N.Mark Glover1 Department of Biochemistry, University of Alberta, Edmonton, AB, T6G 2H7, Canada 1 Corresponding author e-mail: mark.glover

  11. Mountain hydrology of the western United States Roger C. Bales,1

    E-Print Network [OSTI]

    California at Santa Barbara, University of

    Mountain hydrology of the western United States Roger C. Bales,1 Noah P. Molotch,2,3 Thomas H, population growth, and land use change drive the need for new hydrologic knowledge and understanding. In the mountainous West and other similar areas worldwide, three pressing hydrologic needs stand out: first

  12. A computational contact model for nanoscale rubber adhesion Roger A. Sauer

    E-Print Network [OSTI]

    A computational contact model for nanoscale rubber adhesion Roger A. Sauer Institute for Continuum Mechanics, Leibniz Universit¨at Hannover, Germany published in Constitutive Models for Rubber VI, G mechanical contact model which is capable of describing and simulating rubber adhesion at the nanometer scale

  13. United Nations Association -Nebraska Division Hears Roger Gold's "World's Water Problems"

    E-Print Network [OSTI]

    Nebraska-Lincoln, University of

    water problem there is the lack of water during the dry season. In the monsoons, water is collectedUnited Nations Association - Nebraska Division Hears Roger Gold's "World's Water Problems Dictionary (1980), and the New York Times Everyday Dictionary (1982). One-toorders are many of the 54 Water

  14. Non-Reflecting Internal Wave Beam Propagation in the Deep Ocean Roger Grimshaw1)

    E-Print Network [OSTI]

    ). Here we analyze theoretically the penetration of internal waves in an ocean with continuousNon-Reflecting Internal Wave Beam Propagation in the Deep Ocean Roger Grimshaw1) , Efim Pelinovsky1 2008 Using linear internal wave theory for an ocean stratified by both density and current, we identify

  15. The use and misuse of Vc,max in Earth System Models Alistair Rogers

    E-Print Network [OSTI]

    Ohta, Shigemi

    REVIEW The use and misuse of Vc,max in Earth System Models Alistair Rogers Received: 18 November Dordrecht (outside the USA) 2013 Abstract Earth System Models (ESMs) aim to project global change. Central Á Vc,max Á Leaf nitrogen Á Earth System Models Introduction The primary goal of Earth System Models

  16. Video Server on an ATM Connected Cluster of Workstations Olav Sandsta, Stein Langrgen, and Roger Midtstraum

    E-Print Network [OSTI]

    Video Server on an ATM Connected Cluster of Workstations Olav Sandst°a, Stein Langørgen, and Roger-7034 Trondheim, Norway folavsa, steinl, rogerg@idi.ntnu.no Abstract Video servers are important for applicationswhich make use of digital video. The video servers should provide better functionality than most

  17. A contact theory for surface tension driven systems Roger A. Sauer 1

    E-Print Network [OSTI]

    A contact theory for surface tension driven systems Roger A. Sauer 1 Aachen Institute for Advanced description for the contact of surface tension driven sys- tems. The example system of a liquid droplet liquids or two solids in contact. The surface kinematics, essential to the modeling of surface tension

  18. A FRESH LOOK AT OFFSHORE WIND OPPORTUNITIES IN MASSACHUSETTS Anthony L. Rogers, Ph.D.

    E-Print Network [OSTI]

    Massachusetts at Amherst, University of

    A FRESH LOOK AT OFFSHORE WIND OPPORTUNITIES IN MASSACHUSETTS Anthony L. Rogers, Ph.D. James F at Amherst Amherst, MA 01003 The utilization of offshore winds for generating electricity was first proposed that offshore wind development anywhere would be unlikely. More recently, a number of European countries have

  19. The porcine lung as a potential model for cystic fibrosis Christopher S. Rogers,1

    E-Print Network [OSTI]

    Engelhardt, John F.

    Review The porcine lung as a potential model for cystic fibrosis Christopher S. Rogers,1 William M, Prather RS, Sabater JR, Stoltz DA, Zabner J, Welsh MJ. The porcine lung as a potential model for cystic fibrosis. Am J Physiol Lung Cell Mol Physiol 295: L240­L263, 2008. First published May 16, 2008; doi:10

  20. STABLE SR VS 85SR SORPTION FROM SIMULATED WASTE SOLUTIONS BY MST AND MMST

    SciTech Connect (OSTI)

    Taylor-Pashow, K.; Hobbs, D.

    2012-04-02T23:59:59.000Z

    A series of tests were performed to examine the sorption of stable Sr versus the sorption of {sup 85}Sr by monosodium titanate (MST) and modified monosodium titanate (mMST) from simulated waste solutions. Earlier testing indicated a discrepancy between the decontamination factors (DFs) obtained by measuring the stable Sr concentrations by inductively coupled plasma - mass spectroscopy (ICP-MS) and the {sup 85}Sr activities by gamma spectroscopy. One hypothesis to explain this discrepancy was that the stable Sr and {sup 85}Sr were in different chemical forms in the simulated solutions. Several simulants were prepared using different methods for adding the Sr and performance tests were carried out using MST and mMST to determine the Sr and {sup 85}Sr DFs with the various simulants. Testing indicated no discrepancy between the Sr and {sup 85}Sr DFs in tests with these simulants.

  1. Automatic Classi cation of Subdwarf Spectra using a Neural Network C. Winter 1 , C.S. Je ery 1 and J.S. Drilling 2

    E-Print Network [OSTI]

    Jeffery, Simon

    1 and J.S. Drilling 2 1 Armagh Observatory, College Hill, Armagh BT61 9DG, N. Ireland 2 Dept@arm.ac.uk, drilling@rouge.phys.lsu.edu Abstract We apply a multilayer feed-forward back propagation arti#12;cial neural network to a sample of 380 subdwarf spectra classi#12;ed by Drilling et al. (2002), showing

  2. GPS World -With Racing Heart http://www.gpsworld.com/gpsworld/content/printContentPopup.js... 1 of 6 9/5/06 12:06 PM

    E-Print Network [OSTI]

    Vetterli, Martin

    GPS World - With Racing Heart http://www.gpsworld.com/gpsworld/content/printContentPopup.js... 1 of 6 9/5/06 12:06 PM Waist harness containing GPS receiver and helmet with antenna With Racing Heart of physics. A new Swiss system integrates GPS, video, and biosensors for precise position, velocity and heart

  3. Simulation of the Ionization Cooling of Muons in Linear RF Systems G. Penn, J.S. Wurtele, Department of Physics, University of California, Berkeley;

    E-Print Network [OSTI]

    Wurtele, Jonathan

    Simulation of the Ionization Cooling of Muons in Linear RF Systems G. Penn, J.S. Wurtele National Labs, Berkeley, CA 94720 Abstract Ionization cooling of muon beams is a crucial component of the proposed muon collider and neutrino factory. Cur- rent studies of cooling channels predominantly use simula

  4. Vertices of Lie Modules Roger M. Bryant, Susanne Danz, Karin Erdmann, and Jrgen Mller

    E-Print Network [OSTI]

    Mueller, Jürgen

    Vertices of Lie Modules Roger M. Bryant, Susanne Danz, Karin Erdmann, and Jürgen Müller September 9 studied by Erdmann#21;Tan [14], and by Bryant#21;Lim#21;Tan [5]. By [5, Thm. 1.2], one has dim(Lie pr F (n to the principal block of FS n , and Bryant#21;Erdmann [4] have studied indecomposable direct sum decompositions

  5. Charles Roger Alcock, 1996 | U.S. DOE Office of Science (SC)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041clothAdvanced Materials Advanced. C o w l i t z CPlasma of the Rotating WallCharles E.Charles Roger

  6. ROGER L. COPPLE ATTORNEY AT LAW FIRST NORTHERN PLAZA· P. O.

    Office of Legacy Management (LM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilA groupTuba City, Arizona, DisposalFourthN V O 1 8 7 +NewAugustr* R $ s- 0a \nROGER

  7. Policy on Building use during Ventilation Outage: School of Science Roger Bacon Hall and Morrell Science Center

    E-Print Network [OSTI]

    Policy on Building use during Ventilation Outage: School of Science Roger Bacon Hall and Morrell) are present. For this reason, the School of Science has a special policy for times when building ventilation is not functioning as designed. A common cause of inadequate building ventilation is a power outage. Laboratory

  8. Fluorocarbon impurities in KrF lasers Helen H. Hwang, Kristopher James, Roger Hui, and Mark J. KushneP)

    E-Print Network [OSTI]

    Kushner, Mark

    Fluorocarbon impurities in KrF lasers Helen H. Hwang, Kristopher James, Roger Hui, and Mark J, Urbana, Illinois 61801 (Received 24 January 1991; accepted for publication 7 March 1991) Fluorocarbon amounts of impurities, and flu- orocarbons in particular.' Fluorocarbons such as CF4 are common

  9. Vertices of Lie Modules Roger M. Bryant, Susanne Danz, Karin Erdmann, and J#rgen M#ller

    E-Print Network [OSTI]

    Mueller, Jürgen

    Vertices of Lie Modules Roger M. Bryant, Susanne Danz(LieprF(n))= dim(LieF(n)) has re* *cently been studied by Erdmann~Tan [14], and by Bryant~Lim~Tan [5]. By [5, Thm LiepfF(n) of LieF(n) always belongs to the principal block of F Sn, and Bryant~* *Erdmann [4] have

  10. A Case Study of Organizational Effects in a Distributed Sensor Network Bryan Horling, Roger Mailler and Victor Lesser

    E-Print Network [OSTI]

    Massachusetts at Amherst, University of

    A Case Study of Organizational Effects in a Distributed Sensor Network Bryan Horling, Roger the various effects that organizational characteristics have on the system's performance. We show how motivates the need for a better understanding of organizational effects. Introduction Distributed vehicle

  11. Utility Scale Wind Turbines on a Grid Connected Island Mohit Dua, Anthony L. Rogers, James F. Manwell,

    E-Print Network [OSTI]

    Massachusetts at Amherst, University of

    Utility Scale Wind Turbines on a Grid Connected Island Mohit Dua, Anthony L. Rogers, James F utility scale wind turbines on Fox Islands, located 12 miles from the coast of Maine in the United States of electricity itself. Three locations are analyzed in detail as potential sites for wind turbine installations

  12. Micrometeorological data for energy-budget studies near Rogers Spring, Ash Meadows National Wildlife Refuge, Nye County, Nevada, 1994

    SciTech Connect (OSTI)

    Nichols, W.D.; Rapp, T.R.

    1996-05-01T23:59:59.000Z

    The data were collected at two sites near Rogers Spring for use in energy-budget studies beginning in 1994. The data collected at each site included net radiation, air temperature at two heights, dew- point temperature at two heights, windspeed at two heights, soil heat flux, and soil temperature in the interval between the land surface and the buried heat-flux plates.

  13. Poster Abstract: Towards a Smart Home Framework Muddasser Alam, Alper T. Alan, Alex Rogers, and Sarvapali D. Ramchurn

    E-Print Network [OSTI]

    Poster Abstract: Towards a Smart Home Framework Muddasser Alam, Alper T. Alan, Alex Rogers. {moody,ata1g11,acr,sdr}@ecs.soton.ac.uk ABSTRACT We present our Smart Home Framework (SHF) which sim- plifies the modelling, prototyping and simulation of smart infrastructure (i.e., smart home and smart

  14. SR????

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Scienceand Requirements RecentlyElectronicResourcesjobsJuly through Sept8,5,Friday,SRS9,17,1,6,28,

  15. SR????

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Scienceand Requirements RecentlyElectronicResourcesjobsJuly through

  16. Delamere-JS

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville Power Administration wouldDECOMPOSITIONPortal Decision Support forDeepDehumidifying HeatImpact

  17. Demo Abstract: YETI -An Eclipse Plug-in for TinyOS 2.1 Nicolas Burri, Roland Flury, Silvan Nellen, Benjamin Sigg, Philipp Sommer, Roger Wattenhofer

    E-Print Network [OSTI]

    , Benjamin Sigg, Philipp Sommer, Roger Wattenhofer Computer Engineering and Networks Laboratory ETH Zurich, Switzerland {burri, rflury, snellen, besigg, sommer, wattenhofer}@tik.ee.ethz.ch Abstract We present YETI1

  18. A Review of "The Horrid Popish Plot’: Roger L’Estrange and the Circulation of Political Discourse in Late Seventeenth-Century London" by Peter Hinds

    E-Print Network [OSTI]

    Swann, Adam

    2011-01-01T23:59:59.000Z

    Horrid Popish Plot?: Roger L?Estrange and the Circulation of Political Discourse in Late Seventeenth-Century London. Oxford: Oxford University Press, 2010. xiv + 457 pp. + 37 illus. ?60.00. Review by adam swann, university of glasgow. Roger L... in reviews 39 Hinds? attempt to demonstrate the plausibility of the plot to Restora- tion Londoners: he explores the background anti-Catholic sentiment of the period and marshals a wealth of contemporary evidence to unpick the development of the Plot...

  19. Gunsch Jesse Andrew SR COE Spring 2009 Dean's List With Distinction

    E-Print Network [OSTI]

    Wong, Pak Kin

    , Chandra M SR CHE Klein, Joshua SR EMG Klug, Brian Robert SR OSE Krause, Jacob Andrew JR OSE Lacy, Tyler Stephen JR ELE Laughlin, Amanda Diane JR CHE Leavy, Matthew James SR MEE Leick, Mark B SR BE #12;g Lu MEE Milakovich, Andrew J SR ELE Miller, Marcus Florian JR NMS Mohan, Ritika SR CHE Morey, Erica

  20. ECG BIOMETRIC RECOGNITION WITHOUT FIDUCIAL DETECTION Konstantinos N. Plataniotis, Dimitrios Hatzinakos, Jimmy K. M. Lee

    E-Print Network [OSTI]

    Plataniotis, Konstantinos N.

    Hatzinakos, Jimmy K. M. Lee Edward S. Rogers Sr. Department of Electrical And Computer Engineering University

  1. 106:1038-1049, 2009. First published Feb 5, 2009; doi:10.1152/japplphysiol.90769.2008J Appl Physiol G. D. Mitsis, R. J. M. Governo, R. Rogers and K. T. S. Pattinson

    E-Print Network [OSTI]

    Mitsis, Georgios

    G. D. Mitsis, R. J. M. Governo, R. Rogers and K. T. S. Pattinson You might find this additional. Mitsis,1,2,3,4 R. J. M. Governo,3,5 R. Rogers,2,3 and K. T. S. Pattinson2,3 1 Institute of Communications February 2009 Mitsis GD, Governo RJ, Rogers R, Pattinson KT. The effect of remifentanil on respiratory

  2. Zajac, R.N. 1999. Understanding the seafloor landscape in relation to assessing and managing impacts on coastal environments. Pp 211-227 in: J.S. Gray, W. Ambrose Jr., A. Szaniawska (eds) Biogeochemical Cycling and Sediment

    E-Print Network [OSTI]

    Zajac, Roman N.

    of organisms, and have borne much of man's long history of development and associated environmental impacts IN RELATION TO IMPACT ASSESSMENT AND ENVIRONMENTAL MANAGEMENT IN COASTAL MARINE SEDIMENTS ROMAN N. ZAJAC impacts on coastal environments. Pp 211-227 in: J.S. Gray, W. Ambrose Jr., A. Szaniawska (eds

  3. Polarizabilities of the 87Sr Clock Transition

    E-Print Network [OSTI]

    Shi, C; Eismann, U; Zawada, M; Lorini, L; Targat, R Le; Lodewyck, J

    2015-01-01T23:59:59.000Z

    In this paper, we propose an in-depth review of the vector and tensor polarizabilities of the two energy levels of the 87Sr clock transition whose measurement was reported in [P. G. Westergaard et al., Phys. Rev. Lett. 106, 210801 (2011)]. We conduct a theoretical calculation that reproduces the measured coefficients. In addition, we detail the experimental conditions used for their measurement in two Sr optical lattice clocks, and exhibit the quadratic behaviour of the vector and tensor shifts with the depth of the trapping potential and evaluate their impact on the accuracy of the clock.

  4. High Power Testing of a 17 GHz Photocathode RF Gun S.C. Chen, B.G. Danly, J. Gonichon, C.L. Lin, R.J. Temkin, S.R. Trotz, J.S. Wurtele,

    E-Print Network [OSTI]

    Wurtele, Jonathan

    laser photoemission. I. Introduction To meet the stringent requirements set by future applications such as high-energy linear colliders and next generation free electron lasers, efforts have been made recently will be brazed. The 11 2 cell cavity length is about 1.3125 cm. Figure 2 is a schematic of the experiment. The RF

  5. Role of SrMoO{sub 4} in Sr{sub 2}MgMoO{sub 6} synthesis

    SciTech Connect (OSTI)

    Vasala, S.; Yamauchi, H. [Laboratory of Inorganic Chemistry, Department of Chemistry, School of Chemical Technology, Aalto University, P.O. Box 16100, FI-00076 Aalto (Finland); Karppinen, M., E-mail: maarit.karppinen@aalto.f [Laboratory of Inorganic Chemistry, Department of Chemistry, School of Chemical Technology, Aalto University, P.O. Box 16100, FI-00076 Aalto (Finland)

    2011-05-15T23:59:59.000Z

    Here we investigate the elemental and phase compositions during the solid-state synthesis of the promising SOFC-anode material, Sr{sub 2}MgMoO{sub 6}, and demonstrate that molybdenum does not notably evaporate under the normal synthesis conditions with temperatures up to 1200 {sup o}C due to the formation of SrMoO{sub 4} as an intermediate product at low temperatures, below 600 {sup o}C. However, partial decomposition of the Sr{sub 2}MgMoO{sub 6} phase becomes evident at the higher temperatures ({approx}1500 {sup o}C). The effect of SrMoO{sub 4} on the electrical conductivity of Sr{sub 2}MgMoO{sub 6} is evaluated by preparing a series of Sr{sub 2}MgMoO{sub 6} samples with different amounts of additional SrMoO{sub 4}. Under the reducing operation conditions of an SOFC anode the insulating SrMoO{sub 4} phase is apparently reduced to the highly conductive SrMoO{sub 3} phase. Percolation takes place with 20-30 wt% of SrMoO{sub 4} in a Sr{sub 2}MgMoO{sub 6} matrix, with a notable increase in electrical conductivity after reduction. Conductivity values of 14, 60 and 160 S/cm are determined at 800 {sup o}C in 5% H{sub 2}/Ar for the Sr{sub 2}MgMoO{sub 6} samples with 30, 40 and 50 wt% of added SrMoO{sub 4}, respectively. -- Graphical abstract: SrMoO{sub 4} is formed at low temperatures during the synthesis of Sr{sub 2}MgMoO{sub 6}, which prevents the volatilization of Mo from typical precursor mixtures of this promising SOFC anode material. SrMoO{sub 4} is insulating and it is often found as an impurity in Sr{sub 2}MgMoO{sub 6} samples. It is however readily reduced to highly conducting SrMoO{sub 3}. Composites of Sr{sub 2}MgMoO{sub 6} and SrMoO{sub 3} show increased electrical conductivities compared to pure Sr{sub 2}MgMoO{sub 6} under the reductive operation conditions of an SOFC anode. Display Omitted Highlights: {yields} Sr{sub 2}MgMoO{sub 6} is a promising SOFC anode material. {yields} During the Sr{sub 2}MgMoO{sub 6} synthesis SrMoO{sub 4} is formed at low temperatures. {yields} Formation of SrMoO{sub 4} effectively prevents volatilization of Mo at high temperatures. {yields} Insulating SrMoO{sub 4} reduces to highly conductive SrMoO{sub 3} under SOFC-anode conditions. {yields} Composites of Sr{sub 2}MgMoO{sub 6} and SrMoO{sub 3} show high electrical conductivities.

  6. Are seawater Sr/Ca variations preserved in Quaternary foraminifera?

    SciTech Connect (OSTI)

    Stoll, H.M.; Schrag, D.P.; Clemens, S.C.

    1999-11-01T23:59:59.000Z

    High precision measurements of Sr/Ca in planktonic foraminifera for the last 150 ka reveal Sr/Ca variations of up to 12% on glacial/interglacial time scales. Although records showing the largest variations appear to be strongly influenced by selective dissolution, other records show Sr/Ca variations of 3--5% that do not covary with indicators of dissolution intensity and that are reproduced in sites of contrasting Quaternary dissolution histories. These systematic variations are characterized by high Sr/Ca ratios during glacial maxima, followed by steep decreases during deglaciation and gradual increases through interstadial periods, closely following {delta}{sup 18}O curves. Foraminiferal Sr/Ca variations may reflect changes in the Sr/Ca ratio of seawater, or they may be due to kinetically or biologically induced changes in Sr partitioning. Coupled numerical models of the Sr and Ca budgets of the ocean reveal that sea level changes, together with large changes in river fluxes and carbonate accumulation rates, can produce seawater Sr/Ca variations that approximate both the shape and amplitude of foraminiferal Sr/Ca variations. However, such extreme changes in river and carbonate fluxes conflict with existing data on carbonate accumulation rates and Sr isotopic constraints on the magnitude of variations in the river flux. Smaller variations (1--3%) in the Sr/Ca ratio of seawater likely characterize Quaternary glacial cycles. Changes in Sr partitioning due to glacial-interglacial changes in the carbonate ion concentration and other environmental factors likely produce additional variation in the Sr/Ca record of planktonic foraminifera.

  7. UMASS MINI-CODES FOR WIND ENERGY ENGINEERING APPLICATIONS J. F. Manwell, A. L. Rogers, J. G. McGowan, U. Abdulwaid

    E-Print Network [OSTI]

    Massachusetts at Amherst, University of

    UMASS MINI-CODES FOR WIND ENERGY ENGINEERING APPLICATIONS J. F. Manwell, A. L. Rogers, J. G. Mc that these codes will be used for educational purposes, or for general use by the wind energy engineering community. ~TRODUCTIO~ BACKGROUND Computer codes are a valuable tool for practicing wind energy engineers. Wind

  8. ROGERS, MEGHAN LYNN. Identifying and Evaluating Risk Factors for Musculoskeletal Disorders in Equine Veterinary Work. (Under the direction of Dr. David B. Kaber).

    E-Print Network [OSTI]

    Kaber, David B.

    risk scores. Phase 2 involved collecting quantitative hand forces and wrist postures and using the data, palpations, lameness exams, and injections. Based on the quantitative data analysis, the tasks of ultrasoundABSTRACT ROGERS, MEGHAN LYNN. Identifying and Evaluating Risk Factors for Musculoskeletal Disorders

  9. Zero Kinetic Energy Photofragment Spectroscopy: The Threshold Dissociation of NO2 J. A. Mueller, S. A. Rogers, and Paul L. Houston*

    E-Print Network [OSTI]

    Houston, Paul L.

    at the dissociation threshold of, while for higher energies, a new peak occurs as the energy threshold is reachedZero Kinetic Energy Photofragment Spectroscopy: The Threshold Dissociation of NO2 J. A. Mueller, S. A. Rogers, and Paul L. Houston* Department of Chemistry, Cornell UniVersity, Ithaca, New York 14853

  10. A Lower Bound for the Risk in Estimating the Value of a Probability Density Author(s): Lawrence D. Brown and Roger H. Farrell

    E-Print Network [OSTI]

    Brown, Lawrence D.

    . Brown and Roger H. Farrell Source: Journal of the American Statistical Association, Vol. 85, No. 412 (Dec., 1990), pp. 1147- 1153 Published by: American Statistical Association Stable URL: http of scholarship. For more information about JSTOR, please contact support@jstor.org. American Statistical

  11. Interface mechanics of adhesiveless microtransfer printing processes H.-J. Kim-Lee, A. Carlson, D. S. Grierson, J. A. Rogers, and K. T. Turner

    E-Print Network [OSTI]

    Rogers, John A.

    electronics, advanced packaging schemes, and complex 3D microstructures that cannot be realizedInterface mechanics of adhesiveless microtransfer printing processes H.-J. Kim-Lee, A. Carlson, D microtransfer printing processes H.-J. Kim-Lee,1,a) A. Carlson,2 D. S. Grierson,1,b) J. A. Rogers,2 and K. T

  12. Fabrication of Sr silicate buffer layer on Si(100) substrate by pulsed laser deposition using a SrO target

    SciTech Connect (OSTI)

    Imanaka, Atsuhiro; Sasaki, Tsubasa [Department of Engineering, University of Hyogo, 2167 Shosha, Himeji, Hyogo 671-2280 (Japan); Hotta, Yasushi, E-mail: hotta@eng.u-hyogo.ac.jp; Satoh, Shin-ichi [Department of Engineering, University of Hyogo, 2167 Shosha, Himeji, Hyogo 671-2280, Japan and CREST, Japan Science and Technology Agency, 4-1-8 Honcho, Kawaguchi, Saitama 332-0012 (Japan)

    2014-09-01T23:59:59.000Z

    The authors fabricated 2?×?1 Sr-reconstructed Si(100) substrates using thin SrO layers, and used them to direct growth of crystalline perovskite oxide on Si. The SrO layers used to reconstruct the Si(100) substrates were grown by pulsed laser deposition from a SrO single crystal target, followed by postdeposition-annealing (PDA) of the SrO/Si(100) structure. In situ observations of reflective high-energy electron diffraction during PDA confirmed a 2?×?1 reconstruction of the Si surface and x-ray photoemission spectroscopy of the annealed samples confirmed the existence of Sr atoms in a silicate phase, which indicated that a 2?×?1 Sr-reconstructed Si surface was achieved. The optimal fabrication conditions were annealing at 720?°C for 1?min and an equivalent SrO layer thickness (ML{sub eq}) of 2.5 ML{sub eq}. The temperature condition was very narrow, at 720?±?20?°C, for an acceptable product. Subsequently, the authors demonstrated the growth of crystalline SrTiO{sub 3} films on the 2?×?1 Sr-reconstructed Si(100) surfaces.

  13. Photoionisation loading of large Sr+ ion clouds with ultrafast pulses

    E-Print Network [OSTI]

    Sébastien Removille; Romain Dubessy; Quentin Glorieux; Samuel Guibal; Thomas Coudreau; Luca Guidoni; Jean-Pierre Likforman

    2008-12-05T23:59:59.000Z

    This paper reports on photoionisation loading based on ultrafast pulses of singly-ionised strontium ions in a linear Paul trap. We take advantage of an autoionising resonance of Sr neutral atoms to form Sr+ by two-photon absorption of femtosecond pulses at a wavelength of 431nm. We compare this technique to electron-bombardment ionisation and observe several advantages of photoionisation. It actually allows the loading of a pure Sr+ ion cloud in a low radio-frequency voltage amplitude regime. In these conditions up to 4x10^4 laser-cooled Sr+ ions were trapped.

  14. Carrier-Controlled Ferromagnetism in SrTiO3

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Moetakef, Pouya; Williams, James R.; Ouellette, Daniel G.; Kajdos, Adam P.; Goldhaber-Gordon, David; Allen, S. James; Stemmer, Susanne

    2012-06-01T23:59:59.000Z

    Magnetotransport and superconducting properties are investigated for uniformly La-doped SrTiO3 films and GdTiO3/SrTiO3 heterostructures, respectively. GdTiO3/SrTiO3 interfaces exhibit a high-density 2D electron gas on the SrTiO3 side of the interface, while, for the SrTiO3 films, carriers are provided by the dopant atoms. Both types of samples exhibit ferromagnetism at low temperatures, as evidenced by a hysteresis in the magnetoresistance. For the uniformly doped SrTiO3 films, the Curie temperature is found to increase with doping and to coexist with superconductivity for carrier concentrations on the high-density side of the superconducting dome. The Curie temperature of the GdTiO3/SrTiO3 heterostructures scales with the thickness of the SrTiO3 quantum well. The results are used to construct a stability diagram for the ferromagnetic and superconducting phases of SrTiO3.

  15. Dr. Roger Beachy was appointed to be the first director of the National Institute of Food and Agriculture (NIFA) in October, 2009, and in January 2010 was appointed Chief Scientist of USDA. NIFA is responsible for

    E-Print Network [OSTI]

    Ferrara, Katherine W.

    of the world's first genetically modified food crop, a variety of tomato that was modified for resistanceDr. Roger Beachy was appointed to be the first director of the National Institute of Food

  16. CIRES/GSD Professional Research Assistant Sr. HPC Systems Engineer

    E-Print Network [OSTI]

    Colorado at Boulder, University of

    forecasts. ESRL/GSD is a part of NOAA's Research and Development High Performance Computing Systems Program of GSD is looking for a temporary (12 mo) full-time Sr. High Performance Computing (HPC) System Engineer to support multiple state-of-the-art High Performance Computers in Boulder, CO and Fairmont, WV. The Sr

  17. Superconducting and magnetic properties of Sr?Ir?Sn??

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Biswas, P. K.; Wang, Kefeng; Amato, A.; Khasanov, R.; Luetkens, H.; Petrovic, C.; Cook, R. M.; Lees, M. R.; Morenzoni, E.

    2014-10-01T23:59:59.000Z

    Magnetization and muon spin relaxation or rotation (µSR) measurements have been performed to study the superconducting and magnetic properties of Sr?Ir?Sn??. From magnetization measurements the lower and upper critical fields of Sr?Ir?Sn?? are found to be 81(1) Oe and 14.4(2) kOe, respectively. Zero-field µSR data show no sign of any magnetic ordering or weak magnetism in Sr?Ir?Sn??. Transverse-field µSR measurements in the vortex state provided the temperature dependence of the magnetic penetration depth ?. The dependence of ??² with temperature is consistent with the existence of single s-wave energy gap in the superconducting state of Sr?Ir?Sn?? with a gap valuemore »of 0.82(2) meV at absolute zero temperature. The magnetic penetration depth at zero temperature ?(0) is 291(3) nm. The ratio ?(0)/kBTc = 2.1(1) indicates that Sr?Ir?Sn?? should be considered as a strong-coupling superconductor.« less

  18. Superconducting and magnetic properties of Sr?Ir?Sn??

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Biswas, P. K. [Paul Scherrer Inst. (PSI), Villigen (Switzerland); Wang, Kefeng [Brookhaven National Lab. (BNL), Upton, NY (United States); Amato, A. [Paul Scherrer Inst. (PSI), Villigen (Switzerland); Khasanov, R. [Paul Scherrer Inst. (PSI), Villigen (Switzerland); Luetkens, H. [Paul Scherrer Inst. (PSI), Villigen (Switzerland); Petrovic, C. [Brookhaven National Lab. (BNL), Upton, NY (United States); Cook, R. M. [Univ. of Warwick, Coventry (United Kingdom); Lees, M. R. [Univ. of Warwick, Coventry (United Kingdom); Morenzoni, E. [Paul Scherrer Inst. (PSI), Villigen (Switzerland)

    2014-10-01T23:59:59.000Z

    Magnetization and muon spin relaxation or rotation (µSR) measurements have been performed to study the superconducting and magnetic properties of Sr?Ir?Sn??. From magnetization measurements the lower and upper critical fields of Sr?Ir?Sn?? are found to be 81(1) Oe and 14.4(2) kOe, respectively. Zero-field µSR data show no sign of any magnetic ordering or weak magnetism in Sr?Ir?Sn??. Transverse-field µSR measurements in the vortex state provided the temperature dependence of the magnetic penetration depth ?. The dependence of ??² with temperature is consistent with the existence of single s-wave energy gap in the superconducting state of Sr?Ir?Sn?? with a gap value of 0.82(2) meV at absolute zero temperature. The magnetic penetration depth at zero temperature ?(0) is 291(3) nm. The ratio ?(0)/kBTc = 2.1(1) indicates that Sr?Ir?Sn?? should be considered as a strong-coupling superconductor.

  19. VWA-0024- In the Matter of Russell P. Marler, Sr.

    Broader source: Energy.gov [DOE]

    This Decision involves a complaint filed by Russell P. Marler, Sr. (Marler or “the complainant”) under the Department of Energy (DOE) Contractor Employee Protection Program, codified at 10 C.F.R....

  20. Remedial investigation work plan for Chestnut Ridge Operable Unit 4 (Rogers Quarry/Lower McCoy Branch) at the Oak Ridge Y-12 Plant, Oak Ridge, Tennessee

    SciTech Connect (OSTI)

    Not Available

    1993-09-01T23:59:59.000Z

    The Oak Ridge Y-12 Plant includes - 800 acres near the northeast comer of the reservation and adjacent to the city of Oak Ridge (Fig. 1-1). The plant is a manufacturing and developmental engineering facility that produced components for various nuclear weapons systems and provides engineering support to other Energy Systems facilities. More than 200 contaminated sites have been identified at the Y-12 Plant that resulted from past waste management practices. Many of the sites have operable units (OUs) based on priority and on investigative and remediation requirements. This Remedial Investigation RI work plan specifically addresses Chestnut Ridge OU 4. Chestnut Ridge OU 4 consists of Rogers Quarry and Lower McCoy Branch (MCB). Rogers Quarry, which is also known as Old Rogers Quarry or Bethel Valley Quarry was used for quarrying from the late 1940s or early 1950s until about 1960. Since that time, the quarry has been used for disposal of coal ash and materials from Y-12 production operations, including classified materials. Disposal of coal ash ended in July 1993. An RI is being conducted at this site in response to CERCLA regulations. The overall objectives of the RI are to collect data necessary to evaluate the nature and extent of contaminants of concern, support an Ecological Risk Assessment and a Human Health Risk Assessment, support the evaluation of remedial alternatives, and ultimately develop a Record of Decision for the site. The purpose of this work plan is to outline RI activities necessary to define the nature and extent of suspected contaminants at Chestnut Ridge OU 4. Potential migration pathways also will be investigated. Data collected during the RI will be used to evaluate the risk posed to human health and the environment by OU 4.

  1. Optical and structural stability of blue SrO:Eu{sup 2+} phosphor

    SciTech Connect (OSTI)

    Komatsu, Keiji, E-mail: Keiji_Komatsu@mst.nagaokaut.ac.jp [Department of Material Science and Technology, Nagaoka University of Technology, 1603-1 Kamitomioka, Nagaoka, Niigata 940-2188 (Japan); Nakamura, Atsushi [Department of Material Science and Technology, Nagaoka University of Technology, 1603-1 Kamitomioka, Nagaoka, Niigata 940-2188 (Japan); Chubu Chelest Co. Ltd., 3-3-3 Hinagahigashi, Yokkaichi, Mie 510-0886 (Japan); Ohshio, Shigeo; Toda, Ikumi; Muramatsu, Hiroyuki; Saitoh, Hidetoshi [Department of Material Science and Technology, Nagaoka University of Technology, 1603-1 Kamitomioka, Nagaoka, Niigata 940-2188 (Japan)

    2013-08-15T23:59:59.000Z

    Chemical stability of 6-coodinated SrO is a fundamental problem when this is used for various applications. In this study, optical and chemical stabilities of 8-coordinated SrO:Eu{sup 2+} phosphor were investigated. SrO:Eu{sup 2+} phosphor was synthesized from thermal treatment of SrO:Eu powder located on a single crystalline MgO at 1500° C under reduction atmosphere. Obtained 8-coordinated SrO:Eu{sup 2+} phosphor exhibit strong blue luminescence and chemical stability in distilled water for 3 days. Our findings prove that obtained 8-coordinated SrO:Eu{sup 2+} possesses relative optical and chemical stabilities in water. - Graphical abstract: Obtained 8-coordinated SrO:Eu{sup 2+} phosphor exhibit strong blue luminescence in distilled water. Highlights: • We investigated optical and chemical stabilities of 8-coordinated SrO:Eu{sup 2+} phosphor in water. • Obtained 8-coordinated SrO:Eu{sup 2+} phosphor exhibit strong blue luminescence and chemical stability in distilled water for 3 days. • We found that the 8-coodrodinated SrO crystal structure changed to SrCO{sub 3} crystal structure after the 5 days immersion. • The obtained SrO:Eu{sup 2+} phosphor possesses high chemical stability under water, compared with commercial (6-coordinated) SrO.

  2. Marshall, J.S., Gardner, T.W., Protti, M., and Nourse, J.A., 2009, International geosciences field research with undergraduate students: Three models for expe-riential learning projects investigating active tectonics of the Nicoya Peninsula, Costa Rica, i

    E-Print Network [OSTI]

    Marshall, Jeffrey S.

    1 Marshall, J.S., Gardner, T.W., Protti, M., and Nourse, J.A., 2009, International geosciences. Marshall Geological Sciences Department, Cal Poly Pomona University, Pomona, California 91768, USA Thomas W of their home learning environment, international field #12;2 Marshall et al. spe461-08 page 2 of 22

  3. Laser system for secondary cooling of {sup 87}Sr atoms

    SciTech Connect (OSTI)

    Khabarova, K Yu; Slyusarev, S N; Strelkin, S A; Belotelov, G S; Kostin, A S; Pal'chikov, Vitaly G; Kolachevsky, Nikolai N

    2012-11-30T23:59:59.000Z

    A laser system with a narrow generation line for secondary laser cooling of {sup 87}Sr atoms has been developed and investigated. It is planned to use ultracold {sup 87}Sr atoms loaded in an optical lattice in an optical frequency standard. To this end, a 689-nm semiconductor laser has been stabilised using an external reference ultrastable cavity with vibrational and temperature compensation near the critical point. The lasing spectral width was 80 Hz (averaging time 40 ms), and the frequency drift was at a level of 0.3 Hz s{sup -1}. Comparison of two independent laser systems yielded a minimum Allan deviation: 2 Multiplication-Sign 10{sup -14} for 300-s averaging. It is shown that this system satisfies all requirements necessary for secondary cooling of 87Sr atoms using the spectrally narrow {sup 1}S{sub 0} - {sup 3}P{sub 1} transition ({lambda} = 689 nm). (cooling of atoms)

  4. Reversible nano-structuring of SrCrO3-? through oxidization...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    nano-structuring of SrCrO3- through oxidization and reduction at low temperatures. Reversible nano-structuring of SrCrO3- through oxidization and reduction at low temperatures....

  5. Structure, magnetic properties and magnetoelastic anisotropy in epitaxial Sr(Ti???Co?)O? films

    E-Print Network [OSTI]

    Bi, Lei

    We report the structure, magnetic properties and magnetoelastic anisotropy of epitaxial Sr(Ti???Co?)O? films grown on LaAlO? (001) and SrTiO? (001) substrates by pulsed laser deposition. Room temperature ferromagnetism was ...

  6. Oxidation and diffusion of Cu in SrS: Cu grown by MBE for blue phosphors

    E-Print Network [OSTI]

    Wang, Zhong L.

    Oxidation and diffusion of Cu in SrS: Cu grown by MBE for blue phosphors Y.B. Xina,b,*, W. Tonga, ON M9W 5AS, Canada Abstract Systematic studies of MBE grown SrS:Cu thin film blue phosphors Thin film SrS:Cu is a potential candidate for blue electro- luminescent (EL) phosphors. Although recent

  7. Synthesis of BiPbSrCaCuO superconductor

    DOE Patents [OSTI]

    Hults, William L. (Los Alamos, NM); Kubat-Martin, Kimberly A. (Espanola, NM); Salazar, Kenneth V. (Espanola, NM); Phillips, David S. (Los Alamos, NM); Peterson, Dean E. (Los Alamos, NM)

    1994-01-01T23:59:59.000Z

    A process and a precursor composition for preparing a lead-doped bismuth-strontium-calcium-copper oxide superconductor of the formula Bi.sub.a Pb.sub.b Sr.sub.c Ca.sub.d Cu.sub.e O.sub.f wherein a is from about 1.7 to about 1.9, b is from about 0.3 to about 0.45, c is from about 1.6 to about 2.2, d is from about 1.6 to about 2.2, e is from about 2.97 to about 3.2 and f is 10.+-.z by reacting a mixture of Bi.sub.4 Sr.sub.3 Ca.sub.3 Cu.sub.4 O.sub.16.+-.z, an alkaline earth metal cuprate, e.g., Sr.sub.9 Ca.sub.5 Cu.sub.24 O.sub.41, and an alkaline earth metal plumbate, e.g., Ca.sub.2-x Sr.sub.x PbO.sub.4 wherein x is about 0.5, is disclosed.

  8. SR/OIAF/2003-02 Analysis of S.139,

    E-Print Network [OSTI]

    Ford, Andrew

    and Greenhouse Gases Division and Acting Director of the Coal and Electric Power Division; James M. Kendell (jkendell@eia.doe.gov, 202/586 9646), Director, Oil and Gas Division; and Andy S. Kydes (andySR/OIAF/2003-02 Analysis of S.139, the Climate Stewardship Act of 2003 June 2003 Energy Information

  9. Synthesis of BiPbSrCaCuO superconductor

    DOE Patents [OSTI]

    Hults, W.L.; Kubat-Martin, K.A.; Salazar, K.V.; Phillips, D.S.; Peterson, D.E.

    1994-04-05T23:59:59.000Z

    A process and a precursor composition for preparing a lead-doped bismuth-strontium-calcium-copper oxide superconductor of the formula Bi[sub a]Pb[sub b]Sr[sub c]Ca[sub d]Cu[sub e]O[sub f] wherein a is from about 1.7 to about 1.9, b is from about 0.3 to about 0.45, c is from about 1.6 to about 2.2, d is from about 1.6 to about 2.2, e is from about 2.97 to about 3.2 and f is 10[+-]z by reacting a mixture of Bi[sub 4]Sr[sub 3]Ca[sub 3]Cu[sub 4]O[sub 16[+-]z], an alkaline earth metal cuprate, e.g., Sr[sub 9]Ca[sub 5]Cu[sub 24]O[sub 41], and an alkaline earth metal plumbate, e.g., Ca[sub 2[minus]x]Sr[sub x]PbO[sub 4] wherein x is about 0.5, is disclosed.

  10. Radioactive contamination of SrI2(Eu) crystal scintillator

    E-Print Network [OSTI]

    Belli, P; Cerulli, R; Danevich, F A; Galenin, E; Gektin, A; Incicchitti, A; Isaienko, V; Kobychev, V V; Laubenstein, M; Nagorny, S S; Podviyanuk, R B; Tkachenko, S; Tretyak, V I

    2011-01-01T23:59:59.000Z

    A strontium iodide crystal doped by europium (SrI2(Eu)) was produced by using the Stockbarger growth technique. The crystal was subjected to characterisation that included relative photoelectron output and energy resolution for gamma quanta. The intrinsic radioactivity of SrI2(Eu) crystal scintillator was tested both in scintillation mode and by using ultra-low background HPGe gamma spectrometry deep underground. The response of the SrI2(Eu) detector to alpha particles (alpha/beta ratio and pulse shape) was estimated by analysing the 226Ra trace contamination internal to the crystal. We have found alpha/beta=0.55 and no difference in scintillation decay for alpha particles and gamma quanta. The application of the obtained results in the search for the double electron capture and electron capture with positron emission in 84Sr has been investigated at a level of sensitivity T_1/2 \\sim 10^15-10^16 yr. The results of these studies demonstrate the potentiality of this material for a variety of scintillation appli...

  11. Brian Rogers Susan Henrichs

    E-Print Network [OSTI]

    Hartman, Chris

    & Alumni VACANT Dir, Alumni Relations Mark Myers Vice Chancellor Research John Blake Assoc. Vice Chancellor Chancellor Research, Intellectual Property & Commercialization (PT) Gary Gray Director Athletics Nettie

  12. Temperature dependence of magnetic properties of La0.7Sr0.3MnO3SrTiO3 thin films on silicon substrates

    E-Print Network [OSTI]

    Boyer, Edmond

    by a 20-nm-thick SrTiO3 001 buffer layer. X-ray diffraction and atomic force microscopy studies. INTRODUCTION Perovskite manganites RE 1-x AE xMnO3, where RE =rare earth and AE=alkaline earth formTemperature dependence of magnetic properties of La0.7Sr0.3MnO3Ã?SrTiO3 thin films on silicon

  13. NAME AWARD NAME COLLEGE CLASS Adler, Karen Robin Frederic J. Shepler Memorial Prize in French LA SR

    E-Print Network [OSTI]

    Dennett, Daniel

    Theresa McDermott Carzo Award LA SR Ammar, Maya Architectural Studies Prize LA SR Andrews, Tyler Cummings or Scholarly Work LA SR Berkowitz, Stacey B. R.M. Karapetoff Cobb Chemistry Fund Prize LA JR Bernstein, Esther Shulia Jane Ann Herman Prize LA SR Blumenthal, Scott B. Alex Elias Memorial Prize Scholarship LA JR

  14. Unconventional Switching Behavior in La0.7Sr0.3MnO3/La0.7Sr0...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Unconventional Switching Behavior in La0.7Sr0.3MnO3La0.7Sr0.3CoO3 Exchange-spring Bilayer Monday, March 30, 2015 Interfacial magnetic interactions between ferromagnetic...

  15. Ferromagnetic Mn moments at SrRuO3/SrMnO3 interfaces Materials Science Division, Argonne National Laboratory, Argonne, Illinois 60439

    E-Print Network [OSTI]

    Haskel, Daniel

    Ferromagnetic Mn moments at SrRuO3/SrMnO3 interfaces Y. Choia Materials Science Division, Argonne National Laboratory, Argonne, Illinois 60439 Y. Z. Yoo, O. Chmaissem, A. Ullah, S. Kolesnik, and C. W University, DeKalb, Illinois 60115 D. Haskel Advanced Photon Source, Argonne National Laboratory, Argonne

  16. S+R Optimization in Logistics Stochastic and Robust Optimization in Logistics

    E-Print Network [OSTI]

    Erera, Alan

    S+R Optimization in Logistics Stochastic and Robust Optimization in Logistics eln irerI 1he upply@isye.gatech.edu 1/ 78 #12;S+R Optimization in Logistics Introductions eout we et qeorgi eh for W yers eserhFisyeFgtehFeduGvlerer 2/ 78 #12;S+R Optimization in Logistics Introductions eout we et qeorgi eh for W yers eserh

  17. A Sr-Isotopic Comparison Between Thermal Waters, Rocks, And Hydrotherm...

    Open Energy Info (EERE)

    Sr-Isotopic Comparison Between Thermal Waters, Rocks, And Hydrothermal Calcites, Long Valley Caldera, California Jump to: navigation, search OpenEI Reference LibraryAdd to library...

  18. Molten salt synthesis of anisometric particles in the SrONb2O5BaO system

    E-Print Network [OSTI]

    Messing, Gary L.

    Molten salt synthesis of anisometric particles in the SrO­Nb2O5­BaO system Cihangir Duran* , Gary L.5Ba0.5Nb2O6, and SrNb2O6 were synthesized in the SrO­BaO­Nb2O5 system, using KCl or SrCl2Á6H2O salts the salt and Nb2O5. Large, irregularly shaped (Sr-rich) Sr2Nb2O7 particles formed with increasing reaction

  19. SR_SRNS_Proc_Cycle_Sys.pdf | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn'tOrigin ofEnergy atLLC - FE DKT. 10-160-LNG - ORDER 2913||Sys.pdf SR_SRNS_Proc_Cycle_Sys.pdf

  20. MHK Projects/SR 01 | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to: navigation, searchOf KilaueaInformationCygnet.7413°, -155.488° Project Phase PhaseSR 01

  1. Degradation Mechanism in La0.8Sr0.2CoO3 [La subscript 0.8 Sr subscript 0.2 CoO subscript 3] as Contact Layer on the Solid Oxide Electrolysis Cell Anode

    E-Print Network [OSTI]

    Sharma, Vivek Inder

    Detailed chemical and structural analyses are presented for the degradation mechanism of La0.8Sr0.2CoO3 [La subscript 0.8 Sr subscript 0.2 CoO subscript 3

  2. SR-2508 plus buthionine sulfoximine or SR-2508 alone: effects on the radiation response and the glutathione content of a human tumor xenograft

    SciTech Connect (OSTI)

    Lespinasse, F.; Biscay, P.; Malaise, E.P.; Guichard, M.

    1987-04-01T23:59:59.000Z

    This study determined the radiosensitivity of the human tumor xenograft HT29 and its glutathione (GSH) and cysteine (CYS) contents after treatment with both buthionine sulfoximine (BSO) and SR-2508 or SR-2508 alone. Tumor radiosensitivity was assessed by the in vitro colony assay and thiol content was measured by high-performance liquid chromatography. The radiosensitizing effect of SR-2508 is dose dependent and increases when higher doses of radiation are given. SR-2508 given alone does not modify GSH and CYS content; however, when given with BSO, the GSH level is significantly reduced, yet radiosensitivity of the HT29 tumor is only slightly increased. These results have been compared to our previously observed results of HT29 treatment with misonidazole (MISO), BSO, or MISO + BSO.

  3. Ordered vs. disordered perovskites; structural studies of Fe-doped SrIrO{sub 3} and SrRuO{sub 3}

    SciTech Connect (OSTI)

    Qasim, Ilyas; Blanchard, Peter E.R.; Liu, Samuel; Tang, Chunguang [School of Chemistry, The University of Sydney, Sydney, NSW 2006 (Australia); Kennedy, Brendan J., E-mail: B.Kennedy@chem.usyd.edu.au [School of Chemistry, The University of Sydney, Sydney, NSW 2006 (Australia); Avdeev, Maxim [Australian Nuclear Science and Technology Organisation, Lucas Heights, NSW 2234 (Australia); Kimpton, Justin A. [Australian Synchrotron, 800 Blackburn Road, Clayton, Victoria 3168 (Australia)

    2013-10-15T23:59:59.000Z

    The structures of the two Fe containing perovskites Sr{sub 2}IrFeO{sub 6} and SrRu{sub 0.5}Fe{sub 0.5}O{sub 3} have been established using a combination of synchrotron and neutron diffraction methods. Sr{sub 2}IrFeO{sub 6} and SrRu{sub 0.5}Fe{sub 0.5}O{sub 3} are shown to be monoclinic I2/m and tetragonal I4/mcm respectively The former exhibits a rock-salt like ordering of the Fe and Ir cations and displays a sequence of phase transitions associated with the loss of the octahedral tilts upon heating; 12/m?I4/m?Fm3{sup ¯}m. The Fe and Ru cations are disordered in SrRu{sub 0.5}Fe{sub 0.5}O{sub 3} and this shows a single structural phase transition upon heating due to the loss of the in-phase tilts, viz. I4/mcm?Pm3{sup ¯}m. In both cases XANES measurements show partial oxidation of the Fe{sup 3+} to Fe{sup 4+}. The difference in the structures between the two is remarkable given the similar size of Ir{sup 5+} and Ru{sup 5+}, and this is reflected in their magnetic properties. - Graphical abstract: Sr{sub 2}IrFeO{sub 6} and SrRu{sub 0.5}Fe{sub 0.5}O{sub 3} are shown, using a combination of synchrotron and neutron diffraction, to be monoclinic I2/m with cation ordering and tetragonal I4/mcm with disordered Fe and Ir, respectively. Both undergo phase transitions upon heating due to the loss of the octahedral tilts. Display Omitted - Highlights: • Sr{sub 2}IrFeO{sub 6} shown to be monoclinic and shows the transitions upon heating I2/m?I4/m? Fm3{sup ¯}m. • SrRu{sub 0.5}Fe{sub 0.5}O{sub 3} is tetragonal and shows a single I4/mcm?Pm3m transition upon heating. • The Fe and Ru cations are disordered in SrRu{sub 0.5}Fe{sub 0.5}O{sub 3} but ordered in Sr{sub 2}FeIrO{sub 6}. • XANES measurements show partial oxidation of the Fe{sup 3+} to Fe{sup 4+}.

  4. Oxygen Surface Exchange Kinetics on Sr-Substituted Lanthanum Manganite and Ferrite Thin-Film Microelectrodes

    E-Print Network [OSTI]

    la O', Gerardo Jose

    The surface oxygen exchange kinetics occurring on dense La0.8Sr0.2MnO3 (65nm thick) and La0.8Sr0.2FeO3 (110nm thick) thin films were investigated by electrochemical impedance spectroscopy (EIS). Rutherford backscattering ...

  5. Effect of doping in Bi-Pb-Sr-Ca-Cu-O superconductor composites

    E-Print Network [OSTI]

    Ertekin, Abdullah

    2001-01-01T23:59:59.000Z

    The goal of this thesis is to analyze the solid solubility limit of dopants in Bi-Pb-Sr-Ca-Cu-O superconductors. We have studied the effect of Mn doping Bi-Pb-Sr-Ca-Cu-O. The electrical resistivity and critical temperature were measured for samples...

  6. Creation Date: May 7, 2013 Version: 1 Edited by: SR Client Services ITS Managed Document

    E-Print Network [OSTI]

    Northern British Columbia, University of

    Creation Date: May 7, 2013 Version: 1 Edited by: SR Client Services ITS Managed Document VIEW Client Services ITS Managed Document VIEW CLIENT INSTALLATION - MAC Page 2 When prompted with the End Edited by: SR Client Services ITS Managed Document VIEW CLIENT INSTALLATION - MAC Page 3 In Launchpad

  7. Michael O. Rabin Thomas J. Watson Sr. Research Professor of Computer Science

    E-Print Network [OSTI]

    Michael O. Rabin Thomas J. Watson Sr. Research Professor of Computer Science Harvard University 1964-66 Chairman, Institute of Mathematics, Hebrew University 1970-71 Chairman, Computer Science Science, Harvard University 1983-2012 Thomas J. Watson Sr. Professor of Computer Science, Harvard

  8. Preservation of seawater Sr and Nd isotopes in fossil sh teeth: bad news and good news

    E-Print Network [OSTI]

    Martin, Ellen

    system, our Nd concentration data, combined with published isotopic and rare earth element data, suggest on the global seawater Sr isotope curve. For Sites 1090, 757, and 807 Sr isotopic values of the pore fluids Nd isotopic compositions from the time of deposition. Ã? 2004 Elsevier B.V. All rights reserved

  9. The Synthesis, Structure and Physical Properties of the Layered Ruthenocuprates RuSr2GdCu2O8 and Pb2Sr2Cu2RuO8Cl 

    E-Print Network [OSTI]

    MacLaughlin, A C; Attfield, J. Paul

    2003-01-01T23:59:59.000Z

    Studies of the structure and physical properties of the layered rutheno- cuprates RuSr2GdCu2O8 and Pb2Sr2Cu2RuO8Cl are reviewed. RuSr2GdCu2O8 is a weak ferromagnetic superconductor and doping studies have shown that it is possible to tune...

  10. Epitaxial Strain-Induced Chemical Ordering in La0.5Sr0.5CoO3-delta Films on SrTiO3

    SciTech Connect (OSTI)

    W Donner; C Chen; M Liu; A Jacobson; Y Lee; M Gadre; D Morgan

    2011-12-31T23:59:59.000Z

    Fast ion conductors are at the foundation of a number of important technologies, ranging from fuel cells to batteries to gas separators. Recent results suggest that strained interfaces and thin films may offer new mechanisms for achieving enhanced ionic transport. In this work, we investigate strained 40-nm films of perovskite La{sub 0.5}Sr{sub 0.5}CoO{sub 3-{delta}}, which is an important material for solid oxide fuel cell cathodes and oxygen separation membranes. We demonstrate that a strained thin film of La{sub 0.5}Sr{sub 0.5}CoO{sub 3-{delta}} on SrTiO{sub 3} can have dramatically different anion and cation thermodynamics and kinetics than bulk La{sub 0.5}Sr{sub 0.5}CaO{sub 3-{delta}}. We use synchrotron X-ray diffraction to show that La{sub 0.5}Sr{sub 0.5}CoO{sub 3-{delta}} thin films form an ordered phase at 650 K. The ordered phase consists of La and Sr cations in planes parallel to the surface and is associated with coherent expansion in the c-direction of {approx}5%. This chemical ordering is not observed in the bulk material and is ascribed to the interplay between the epitaxial strain imposed by the substrate, changes in oxygen vacancy content and cation mobility, and the ordering of oxygen vacancies.

  11. Premelting Dynamics J.S. Wettlaufer1

    E-Print Network [OSTI]

    Worster, M. Grae

    that are familiar to those working in fluid mechanics: wetting phenomena and thermophoretic (Marangoni) flows

  12. U-Sr isotopic speedometer: Fluid flow and chemical weatheringrates inaquifers

    SciTech Connect (OSTI)

    Maher, Kate; DePaolo, Donald J.; Christensen, John N.

    2005-12-27T23:59:59.000Z

    Both chemical weathering rates and fluid flow are difficultto measure in natural systems. However, these parameters are critical forunderstanding the hydrochemical evolution of aquifers, predicting thefate and transport of contaminants, and for water resources/water qualityconsiderations. 87Sr/86Sr and (234U/238U) activity ratios are sensitiveindicators of water-rock interaction, and thus provide a means ofquantifying both flow and reactivity. The 87Sr/86Sr values in groundwaters are controlled by the ratio of the dissolution rate to the flowrate. Similarly, the (234U/238U) ratio of natural ground waters is abalance between the flow rate and the dissolution of solids, andalpha-recoil loss of 234U from the solids. By coupling these two isotopesystems it is possible to constrain both the long-term (ca. 100's to1000's of years) flow rate and bulk dissolution rate along the flow path.Previous estimates of the ratio of the dissolution rate to theinfiltration flux from Sr isotopes (87Sr/86Sr) are combined with a modelfor (234U/238U) to constrain the infiltration flux and dissolution ratefor a 70-m deep vadose zone core from Hanford, Washington. The coupledmodel for both (234U/238U) ratios and the 87Sr/86Sr data suggests aninfiltration flux of 5+-2 mm/yr, and bulk silicate dissolution ratesbetween 10-15.7 and 10-16.5 mol/m2/s. The process of alpha-recoilenrichment, while primarily responsible for the observed variation in(234U/238U) of natural systems, is difficult to quantify. However, therate of this process in natural systems affects the interpretation ofmost U-series data. Models for quantifying the alpha-recoil loss fractionbased on geometric predictions, surface area constraints, and chemicalmethods are also presented. The agreement between the chemical andtheoretical methods, such as direct measurement of (234U/238U) of thesmall grain size fraction and geometric calculations for that sizefraction, is quite good.

  13. Genetic approaches to studying coronary heart disease in SR-BI/apoE double knockout mice

    E-Print Network [OSTI]

    Karackattu, Sharon Liz

    2006-01-01T23:59:59.000Z

    Coronary heart disease (CHD) is a major healthcare concern in both developed and developing nations. The principal cause of CHD is atherosclerosis, the buildup of fatty deposits in vessel walls. SR-BI/apoE double knockout ...

  14. UPS STUDY OF THE ADSORPTION OF OXYGEN ON REDUCED SrTi03 SURFACES

    E-Print Network [OSTI]

    Ferrer, S.

    2013-01-01T23:59:59.000Z

    Figure Captions Figure 1. UPS spectra of a reduced SrTi0 3 (Journal of Applied Physics UPS STUDY OF THE ADSORPTION OFof California. LBL 11614 UPS STUDY OF THE ADSORPTION OF

  15. Epitaxial Cr on n-SrTiO3(001)—An ideal Ohmic contact ....

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    beam epitaxy are shown to result in an ordered interface with Cr bound to O in the terminal TiO2 layer, no reduction of the SrTiO3, and a near-perfect Ohmic contact. Cr...

  16. Microstructure and dielectric properties of textured SrTiO3 thin films

    E-Print Network [OSTI]

    Schmidt, S; Lu, J W; Keane, S P; Bregante, L D; Klenov, D O; Stemmer, Susanne

    2005-01-01T23:59:59.000Z

    2003). D. O. Klenov, T. R. Taylor and S. Stemmer, "SrTiO 3Symp. Proc. 401 : T. R. Taylor, P. J. Hansen, B. Acikel, N.2003). B. Acikel, T. R. Taylor, P. J. Hansen, J. S. Speck

  17. Enhanced Magnetism in Epitaxial SrRuO3 Thin Films

    E-Print Network [OSTI]

    Grutter, A.J.

    2010-01-01T23:59:59.000Z

    Enhanced Magnetism in Epitaxial SrRuO 3 A. J. Grutter, 1, 2and their e?ects on magnetism. In this paper we demonstrateXMCD con?rmed that the magnetism originates from the Ru 4+

  18. Depletion, quantum jumps, and temperature measurements of ??Sr? ions in a linear Paul Trap

    E-Print Network [OSTI]

    Richerme, Philip J

    2006-01-01T23:59:59.000Z

    This thesis describes the design and construction of two laser systems to probe the 674nm transition of ??Sr? ions in a linear Paul trap. The first laser system made use of a molecular transition in Iodine to stabilize the ...

  19. Unproductive splicing of SR genes associated with highly conserved and ultraconserved

    E-Print Network [OSTI]

    elements Liana F. Lareau1 *, Maki Inada2 *, Richard E. Green1 {, Jordan C. Wengrod1 & Steven E. Brenner1 expressed sequence tag (EST) libraries for SR transcripts, aligned these ESTs to the human genome to infer

  20. {sup 89,90}Sr-determination in various environmental samples by collinear resonance ionization spectroscopy

    SciTech Connect (OSTI)

    Wendt, K.; Bushaw, B.A.; Bhowmick, G. [Institut fuer Physik, Johannes Gutenberg-Universitaet, D-55099 Mainz (Germany); Bystrow, V.A.; Kotovski, N. [Joint Institute for Nuclear Research, Dubna (Russian Federation); Kratz, J.; Lantzsch, J.; Mueller, P.; Noertershaeuser, W.; Otten, E.W. [Institut fuer Physik, Johannes Gutenberg-Universitaet, D-55099 Mainz (Germany); Seibert, A.; Trautmann, N.; Waldek, A. [Institut fuer Kernchemie, Johannes Gutenberg-Universitaet, D-55099 Mainz (Germany); Yushkevich, Y. [Joint Institute for Nuclear Research, Dubna (Russian Federation)

    1997-01-01T23:59:59.000Z

    The application of Collinear Resonance Ionization Spectroscopy for the determination of {sup 89,90}Sr contaminations in various environmental samples is presented, demonstrating the versatility of this highly specialized and isotope-selective ultra-trace determination technique. Additionally to these studies we have analysed the different processes, which lead to nonselective ionization and hence cause background. Optimization of the experimental conditions resulted in a significant lowering of the detection limit to a value of 3{times}10{sup 6} atoms of {sup 90}Sr (corresponding to an activity of 2mBq) in the presence of up to 10{sup 17}atoms of stable {sup 88}Sr. In a parallel measurement trace determination of both isotopes {sup 89}Sr and {sup 90}Sr is possible with a detection limit for {sup 89}Sr of 10{sup 8}atoms. Measurements on different samples, ranging from air filter samples of 1958 up to today, soil, vegetation, milk and human urine samples as well as cooling water from nuclear power plants document the applicability and the specifications of the technique. {copyright} {ital 1997 American Institute of Physics.}

  1. Galactic Evolution of Sr, Y, Zr: A Multiplicity of Nucleosynthetic Processes

    E-Print Network [OSTI]

    Claudia Travaglio; Roberto Gallino; Enrico Arnone; John Cowan; Faith Jordan; Chris Sneden

    2003-10-07T23:59:59.000Z

    We follow the Galactic enrichment of three easily observed light n-capture elements Sr,Y,and Zr.Input stellar yields have been first separated into their respective main and weak s-process,and r-process components.The s-process yields from AGB stars are computed,exploring a wide range of efficiencies of the major neutron source,13C,and covering both disk and halo metallicities.AGBs have been shown to reproduce the main s-component in the solar system.The concurrent weak s-process,which accounts for the major fraction of the light s-process isotopes in the solar system and occurs in massive stars by the operation of the 22Ne n-source,is discussed in detail.Neither the main s-,nor the weak s-components are shown to contribute significantly to the n-capture element abundances observed in unevolved halo stars.We present a detailed analysis of a large database of spectroscopic observations of Sr,Y,Zr, Ba,and Eu for Galactic stars at various metallicities.Spectroscopic observations of Sr,Y,and Zr to Ba and Eu abundance ratios versus metallicity provide useful diagnostics of the types of n-capture processes forming Sr,Y and Zr.The observed [Sr,Y,Zr/Ba,Eu] ratio is clearly not flat at low metallicities,as we would expect if Ba,Eu and Sr,Y,Zr all had the same r-process origin.We discuss our chemical evolution predictions, taking into account the interplay between different processes to produce Sr-Y-Zr.We find hints for a primary process in low-metallicity massive stars, different from the 'classical s-process' and from the 'classical r-process',that we tentatively define LEPP (Lighter Element Primary Process).This allows us to revise the estimates of the r-process contributions to the solar Sr,Y and Zr abundances,as well as of the contribution to the s-only isotopes 86Sr,87Sr,96Mo.

  2. Bandgap tuning in SrTi(N,O,F){sub 3} by anionic-lattice variation

    SciTech Connect (OSTI)

    Yoon, Songhak; Maegli, Alexandra E.; Karvonen, Lassi; Matam, Santhosh K.; Shkabko, Andrey [Laboratory for Solid State Chemistry and Catalysis, Empa-Swiss Federal Laboratories for Materials Science and Technology, CH-8600 Dübendorf (Switzerland); Riegg, Stefan [Lehrstuhl für Experimentalphysik 5, EKM, Universität Augsburg, Universitätsstraße 1, 86135 Augsburg (Germany); Großmann, Thomas; Ebbinghaus, Stefan G. [Institut für Chemie, Martin-Luther Universität Halle-Wittenberg, Kurt-Mothes-Straße 2, 06120 Halle/Saale (Germany); Pokrant, Simone [Laboratory for Solid State Chemistry and Catalysis, Empa-Swiss Federal Laboratories for Materials Science and Technology, CH-8600 Dübendorf (Switzerland); Weidenkaff, Anke, E-mail: anke.weidenkaff@empa.ch [Laboratory for Solid State Chemistry and Catalysis, Empa-Swiss Federal Laboratories for Materials Science and Technology, CH-8600 Dübendorf (Switzerland)

    2013-10-15T23:59:59.000Z

    Polycrystalline SrTiO{sub 3} and SrTi(O,F){sub 3} powders were synthesized by a solid-state reaction. A partial substitution of oxygen by nitrogen was subsequently carried out using thermal ammonolysis resulting in SrTi(N,O){sub 3} and SrTi(N,O,F){sub 3}. Powder X-ray diffraction (XRD) revealed a cubic perovskite structure with space group Pm-3m for all samples. The thermal ammonolysis slightly increased the lattice parameters, crystallite sizes and strain. As a result from the co-substitution of oxygen with nitrogen and fluorine for SrTi(N,O,F){sub 3}, highly distorted TiO{sub 6} octahedra were detected using X-ray absorption near edge structure (XANES) spectroscopy. The weakening of all active modes of the Raman spectra after thermal ammonolysis also indicated enhanced distortions in the local crystal structure. SrTi(N,O,F){sub 3} has the largest amount of nitrogen as well as fluorine among all four samples as determined by thermogravimetric analysis (TGA), elemental analysis and X-ray photoelectron spectroscopy (XPS). In the UV–vis spectra a distinctive shift of the absorption-edge energy was observed exclusively for the SrTi(N,O,F){sub 3} sample from 390 to 510 nm corresponding to a bandgap narrowing from 3.18 to 2.43 eV. - Graphical abstract: Figure shows the shift of the absorption-edge energy for the SrTi(N,O,F){sub 3} sample from 390 to 510 nm corresponding to a bandgap narrowing from 3.18 to 2.43 eV. Display Omitted - Highlights: • Synthesis of phase-pure SrTi(N,O,F){sub 3} via solid-state reaction. • The incorporated nitrogen contents increase by the presence of fluorine in SrTi(N,O,F){sub 3}. • Co-substitution with nitrogen and fluorine is beneficial for the bandgap narrowing compared to by only nitrogen or fluorine substitution.

  3. Evaluation of Adsorption Properties for Cs and Sr Selective Adsorbents-13171

    SciTech Connect (OSTI)

    Nakai, Tomonori; Wakabayashi, Syunya; Mimura, Hitoshi; Niibori, Yuichi; Kurosaki, Fumio; Matsukura, Minoru [Dept. of Quantum Science and Energy Engineering, Graduate School of Engineering, Tohoku University,Aramaki-Aza-Aoba 6-6-01-2,Sendai, 980-8579 (Japan)] [Dept. of Quantum Science and Energy Engineering, Graduate School of Engineering, Tohoku University,Aramaki-Aza-Aoba 6-6-01-2,Sendai, 980-8579 (Japan); Tanigawa, Hiroshi; Ishizaki, Eiji [UNION SHOWA K.K., 17-20, Mita 2-chome, Minato-ku, Tokyo 108-0073 (Japan)] [UNION SHOWA K.K., 17-20, Mita 2-chome, Minato-ku, Tokyo 108-0073 (Japan)

    2013-07-01T23:59:59.000Z

    The development of effective treatment and disposal methods is very urgent and important subject. Tohoku University and UNION SHOWA have developed various selective adsorbents (zeolites, zeolite sheets and composites loaded with insoluble ferrocyanides) for the effective decontamination of radioactive Cs{sup +} and Sr{sup 2+} As for Cs{sup +} adsorption, CST, chabazite and insoluble ferrocyanides composites had relatively large distribution coefficients (K{sub d}) above 10{sup 3} cm{sup 3}/g and excellent adsorption kinetics in seawater. Even after high temperature calcination at 1,100 deg. C, cesium was still immobilized in the calcined products of Cs{sup +}-zeolites, suggesting high immobilization ability of zeolites for Cs{sup +}. As for Sr{sup 2+} adsorption, A and X zeolites had relatively large K{sub d} values around 10{sup 2} cm{sup 3}/g, and zeolite sheet (A zeolite) exhibited excellent adsorption kinetics in seawater. Considering the decontamination of radioactive Sr{sup 2+} in groundwater, the effects of Ca{sup 2+} and Mg{sup 2+} ions on the K{sub d} value of Sr{sup 2+} were further examined by batch method. The K{sub d} value of Sr{sup 2+} was almost independent of Mg{sup 2+} concentration up to 2,500 ppm, while gradually lowered in the presence of Ca{sup 2+} above 200 ppm, due to the differences in the ionic radius of hydrated ion. The Cs{sup +} and Sr{sup 2+} adsorption ability for KNiFC-A (composite of A zeolite loaded with insoluble ferrocyanides) was examined by batch method. Here the matrix of composite (A zeolite) and loaded ferrocyanides (KNiFC) have high selectivity towards Sr{sup 2+} and Cs{sup +}, respectively. The K{sub d} values of Sr{sup 2+} and Cs{sup +} in seawater were estimated to be above 10{sup 2} and 10{sup 3} cm{sup 3}/g, respectively, indicating the effectiveness for the decontamination of both Sr{sup 2+} and Cs{sup +}. The basic data on the Cs{sup +} and Sr{sup 2+} adsorption properties for selective adsorbents are effective for the practical decontamination processes of these metal ions in seawater and groundwater. (authors)

  4. Approved Module Information for AM20SR, 2014/5 Module Title/Name: Stochastic Processes Module Code: AM20SR

    E-Print Network [OSTI]

    Neirotti, Juan Pablo

    : AM20SR School: Engineering and Applied Science Module Type: Standard Module New Module? No Module to work with appropriate probability distributions as required. 2.Be able to interpret problems using Hours: 100 hours Learning & Teaching Rationale: Lectures and Tutorials Module Assessment Methods

  5. Vale: Roger Charles LETHBRIDGE WE have lost Roger Charles

    E-Print Network [OSTI]

    , during his halcyon days as PVC (Development) and PVC (Academic) are really about bricks and mortar, about

  6. Spectroscopy of /sup 87,88,89/Sr with (n,. gamma. ) and (d,p) reactions

    SciTech Connect (OSTI)

    Winter, C.; Krusche, B.; Lieb, K.P.; Hlawatsch, G.; Egidy, T.V.; Hoyler, F.; Casten, R.F.

    1988-01-01T23:59:59.000Z

    Over the recent years the nuclear structure around the N = 50 shell closure, which is very pronounced in the strontium and zirconium isotopes, has been the subject of extensive experimental and theoretical work. On the proton side Z = 38 and Z = 40 provide fairly closed sub-shells. In the strontium isotopes the lg/sub 9/2/ neutron shell is closed at /sup 88/Sr, supplying relatively pure neutron-hole and neutron-particle states with large spectroscopic factors in /sup 87/Sr and /sup 89/Sr, as well as core-coupled states. The mass region is thus ideally suited to examine the transition from a correlated to an uncorrelated (chaotic.) excitational behavior. These two types are characterized e.g. by the density of excited states, the transition strengths, and the spectroscopic factors observed in transfer reactions. We conducted (n,..gamma..) and (d,p) reactions leading to /sup 87,88,89/Sr in addition to /sup 88/Sr(d,t)/sup 87/Sr and 24 keV neutron capture in /sup 88/Sr. The vast amounts of data were used to analyze the level densities and transition strengths in the statistical model. Correlations were found between the selective population of states dominating the (d,p) process, and the statistical decay of the compound state formed after thermal neutron capture. In the course of the analyses we established essentially complete level schemes (within limited spin windows centered around the spin of the capture state) up to around half the neutron binding energy. The E1 partial decay widths were found to agree with results of giant resonance calculations. We intend to give an overview of the experiments and outline the results of the model calculations. 24 refs., 4 figs.

  7. Roger Tuttle Engineering Public Relations

    E-Print Network [OSTI]

    Chiao, Jung-Chih

    Faculty Mentor: Dr. George Kondraske Honorable Mention - Sairam Geethanath (Biomedical Engineering) Title

  8. Roger Tuttle Engineering Public Relations

    E-Print Network [OSTI]

    Chiao, Jung-Chih

    Using General Systems Performance Theory Faculty Mentor: Dr. George Kondraske Honorable Mention - Sairam

  9. Front End Update Chris Rogers,

    E-Print Network [OSTI]

    McDonald, Kirk

    .42 3750 1 2 400 0.30556 4.894 3750 2 3 400 0.29393 4.17 3000 2 4 450 0.28546 5.34 2250 2 5 450 0.27859 6.36 2250 2 6 450 0.27205 4.94 2250 3 7 450 0.2658 5.61 2250 3 8 450 0.25983 6.3 2250 3 9 450 0.25413 6.97 2250 3 10 450 0.24867 7.65 2250 3 11 450 0.24344 8.31 2250 3 12 450 0.23842 9.01 2250 3 13 450 0

  10. TESTIMONY OF ROGER S. PULWARTY

    E-Print Network [OSTI]

    and services NOAA provides to improve management of sectors of our economy - including energy, agriculture in 2006 and for inviting me to provide the Committee with an update on the Program. It is an honor

  11. Aspects of the SrO-CuO-TiO2 Ternary System Related to the Deposition of SrTiO3 and Copper-Doped SrTiO3 Thin-Film Buffer Layers

    SciTech Connect (OSTI)

    A. Ayala

    2004-12-20T23:59:59.000Z

    YBa{sub 2}Cu{sub 3}O{sub 7-{delta}} (YBCO) coated conductors are promising materials for large-scale superconductivity applications. One version of a YBCO coated conductor is based on ion beam assisted deposition (IBAD) of magnesium oxide (MgO) onto polycrystalline metal substrates. SrTiO{sub 3} (STO) is often deposited by physical vapor deposition (PVD) methods as a buffer layer between the YBCO and IBAD MgO due to its chemical stability and lattice mismatch of only {approx}1.5% with YBCO. In this work, some aspects of the stability of STO with respect to copper (Cu) and chemical solution deposition of STO on IBAD MgO templates were examined. Solubility limits of Cu in STO were established by processing Cu-doped STO powders by conventional bulk preparation techniques. The maximum solubility of Cu in STO was {approx}1% as determined by transmission electron microscopy (TEM) and Rietveld refinements of x-ray diffraction (XRD) data. XRD analysis, performed in collaboration with NIST, on powder compositions on the STO/SrCuO{sub 2} tie line did not identify any ternary phases. SrCu{sub 0.10}Ti{sub 0.90}O{sub y} buffer layers were prepared by pulsed laser deposition (PLD) and CSD on IBAD MgO flexible metallic textured tapes. TEM analysis of a {approx}100 nm thick SrCu{sub 0.10}Ti{sub 0.90}O{sub y} buffer layer deposited by PLD showed a smooth Cu-doped STO/MgO interface. A {approx}600 nm thick YBCO film, deposited onto the SrCu{sub 0.10}Ti{sub 0.90}O{sub y} buffer by PLD, exhibited a T{sub c} of 87 K and critical current density (J{sub c}) of {approx}1 MA/cm{sup 2}. STO and Cu-doped STO thin films by CSD were {approx}30 nm thick. The in plane alignment (FWHM) after deposition of the STO improved by {approx}1{sup o} while it degraded by {approx}2{sup o} with the SrCu{sub 0.05}TiO{sub y} buffer. YBCO was deposited by PLD on the STO and SrCu{sub 0.05}TiO{sub y} buffers. The in plane alignment (FWHM) of the YBCO with the STO buffer layer slightly improved while that of the YBCO with the SrCu{sub 0.05}TiO{sub y} buffer layer remained constant. A goal of the CSD approach to fabrication of coated conductors is process simplicity. In this study, single layer textured films were obtained without a nucleating seed layer that has been deemed necessary by several investigators. These results indicate that Cu-doped STO buffer layers deposited by PLD or CSD are compatible with IBAD MgO and YBCO and that CSD is a viable approach to coated conductor fabrication.

  12. Time Resolved in Situ XAFS Study of the Electrochemical Oxygen Intercalation in SrFeO2.5 Brownmillerite Structure: Comparison with the Homologous SrCoO2.5 System

    E-Print Network [OSTI]

    Frenkel, Anatoly

    temperature oxygen ionic conductors are key materials for the development of the next generation solid oxideTime Resolved in Situ XAFS Study of the Electrochemical Oxygen Intercalation in SrFeO2 to reversibly intercalate oxygen in an electrochemical reaction at room temperature to reach SrMO3 stoichiometry

  13. Cerenkov Counter for In-situ Groundwater Monitoring of Sr90

    SciTech Connect (OSTI)

    Runkle, Robert C.; Brodzinski, Ronald L.; Jordan, David V.; Hartman, John S.; Hensley, Walter K.; Maynard, Melody A.; Sliger, William A.; Smart, John E.; Todd, Lindsay C.

    2005-01-15T23:59:59.000Z

    Groundwater contamination from 90Sr is an environmental challenge posed to present and former nuclear weapons related sites. Traditional methods of extracting groundwater samples and performing laboratory analyses are expensive, time consuming and induce significant disposal challenges. We present here a prototype counter capable of measuring in-situ 90Sr groundwater concentrations at or above the drinking water limit of 8 pCi/L. The beta-decay of 90Sr, and its daughter 90Y, emits high-energy electrons which create Cerenkov light. Photomultiplier tubes convert the Cerenkov light into an electronic pulse which then undergoes signal processing with standard electronics. Concentrations near the drinking water limit can be measured in a matter of hours if they exist in secular equilibrium. The prototype counter is compact, can be operated by a single person and transmits the results to a central monitoring location.

  14. Highly conducting SrMoO{sub 3} thin films for microwave applications

    SciTech Connect (OSTI)

    Radetinac, Aldin, E-mail: aldin@oxide.tu-darmstadt.de; Mani, Arzhang; Ziegler, Jürgen; Alff, Lambert; Komissinskiy, Philipp, E-mail: komissinskiy@oxide.tu-darmstadt.de [Institute of Materials Science, TU Darmstadt, Alarich-Weiss-Str. 2, 64287 Darmstadt (Germany); Melnyk, Sergiy; Nikfalazar, Mohammad; Zheng, Yuliang; Jakoby, Rolf [Institute for Microwave Engineering and Photonics, TU Darmstadt, Merckstraße 25, 64283 Darmstadt (Germany)

    2014-09-15T23:59:59.000Z

    We have measured the microwave resistance of highly conducting perovskite oxide SrMoO{sub 3} thin film coplanar waveguides. The epitaxial SrMoO{sub 3} thin films were grown by pulsed laser deposition and showed low mosaicity and smooth surfaces with a root mean square roughness below 0.3?nm. Layer-by-layer growth could be achieved for film thicknesses up to 400?nm as monitored by reflection high-energy electron diffraction and confirmed by X-ray diffraction. We obtained a constant microwave resistivity of 29???·cm between 0.1 and 20?GHz by refining the frequency dependence of the transmission coefficients. Our result shows that SrMoO{sub 3} is a viable candidate as a highly conducting electrode material for all-oxide microwave electronic devices.

  15. EXPLAINING THE Sr AND Ba SCATTER IN EXTREMELY METAL-POOR STARS

    SciTech Connect (OSTI)

    Aoki, W.; Suda, T.; Boyd, R. N.; Kajino, T.; Famiano, M. A., E-mail: aoki.wako@nao.ac.jp, E-mail: takuma.suda@nao.ac.jp, E-mail: richard11boyde@comcast.net, E-mail: kajino@nao.ac.jp, E-mail: michael.famiano@wmich.edu [National Astronomical Observatory of Japan, 2-21-1 Mitaka, Tokyo 181-8588 (Japan)

    2013-03-20T23:59:59.000Z

    Compilations of abundances of strontium and barium in extremely metal-poor stars show that an apparent cutoff is observed for [Sr/Ba] at [Fe/H] < -3.6 and large fluctuations for [Fe/H] > -3.6 with a clear upper bound depending on metallicity. We study the factors that place upper limits on the logarithmic ratio [Sr/Ba]. A model is developed in which the collapses of type II supernovae are found to reproduce many of the features seen in the data. This model is consistent with galactic chemical evolution constraints of light-element enrichment in metal-poor stars. Effects of turbulence in an explosive site have also been simulated, and are found to be important in explaining the large scatter observed in the [Sr/Ba] data.

  16. Crystallographic, electronic, thermal, and magnetic properties of single-crystal SrCo2As2

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Pandey, Abhishek [Ames Lab. and Iowa State Univ., Ames, IA (United States). Dept. of Physics and Astronomy; Quirinale, D. G. [Ames Lab. and Iowa State Univ., Ames, IA (United States). Dept. of Physics and Astronomy; Jayasekara, W. [Ames Lab. and Iowa State Univ., Ames, IA (United States). Dept. of Physics and Astronomy; Sapkota, A. [Ames Lab. and Iowa State Univ., Ames, IA (United States). Dept. of Physics and Astronomy; Kim, M. G. [Ames Lab. and Iowa State Univ., Ames, IA (United States). Dept. of Physics and Astronomy; Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Dhaka, R. S. [Ames Lab. and Iowa State Univ., Ames, IA (United States). Dept. of Physics and Astronomy; Lee, Y. [Ames Lab. and Iowa State Univ., Ames, IA (United States). Dept. of Physics and Astronomy; Heitmann, T. W. [Univ. of Missouri, Columbia, MO (United States). Missouri Research Reactor; Stephens, P. W. [State Univ. of New York (SUNY), Plattsburgh, NY (United States); Ogloblichev, V. [Russian Academy of Sciences, Urals Div., Ekaterinburg (Russian Federation). Inst. of Metal Physics; Kreyssig, A. [Ames Lab. and Iowa State Univ., Ames, IA (United States). Dept. of Physics and Astronomy; McQueeney, R. J. [Ames Lab. and Iowa State Univ., Ames, IA (United States). Dept. of Physics and Astronomy; Goldman, A. I. [Ames Lab. and Iowa State Univ., Ames, IA (United States). Dept. of Physics and Astronomy; Kaminski, Adam [Ames Lab. and Iowa State Univ., Ames, IA (United States). Dept. of Physics and Astronomy; Harmon, B. N. [Ames Lab. and Iowa State Univ., Ames, IA (United States). Dept. of Physics and Astronomy; Furukawa, Y. [Ames Lab. and Iowa State Univ., Ames, IA (United States). Dept. of Physics and Astronomy; Johnston, D. C. [Ames Lab. and Iowa State Univ., Ames, IA (United States). Dept. of Physics and Astronomy

    2013-07-01T23:59:59.000Z

    In tetragonal SrCo2As2 single crystals, inelastic neutron scattering measurements demonstrated that strong stripe-type antiferromagnetic (AFM) correlations occur at a temperature T = 5 K [W. Jayasekara et al., arXiv:1306.5174] that are the same as in the isostructural AFe2As2 (A = Ca, Sr, Ba) parent compounds of high-Tc superconductors. This surprising discovery suggests that SrCo2As2 may also be a good parent compound for high-Tc superconductivity. Here, structural and thermal expansion, electrical resistivity ?, angle-resolved photoemission spectroscopy (ARPES), heat capacity Cp, magnetic susceptibility ?, 75As NMR and neutron diffraction measurements of SrCo2As2 crystals are reported together with LDA band structure calculations that shed further light on this fascinating material. The c-axis thermal expansion coefficient ?c is negative from 7 to 300 K, whereas ?a is positive over this T range. The ?(T) shows metallic character. The ARPES measurements and band theory confirm the metallic character and in addition show the presence of a flat band near the Fermi energy EF. The band calculations exhibit an extremely sharp peak in the density of states D(EF) arising from a flat dx2-y2 band. A comparison of the Sommerfeld coefficient of the electronic specific heat with ?(T ? 0) suggests the presence of strong ferromagnetic itinerant spin correlations which on the basis of the Stoner criterion predicts that SrCo2As2 should be an itinerant ferromagnet, in conflict with the magnetization data. The ?(T) does have a large magnitude, but also exhibits a broad maximum at 115 K suggestive of dynamic short-range AFM spin correlations, in agreement with the neutron scattering data. The measurements show no evidence for any type of phase transition between 1.3 and 300 K and we propose that metallic SrCo2As2 has a gapless quantum spin-liquid ground state.

  17. Controlled Nanoparticle Metal Phosphates (Metal = Al, Fe, Ce, and Sr) Coatings on LiCoO2 Cathode Materials

    E-Print Network [OSTI]

    Cho, Jaephil

    Controlled Nanoparticle Metal Phosphates (Metal = Al, Fe, Ce, and Sr) Coatings on LiCoO2 Cathode and annealing temperature are used for MPO4 nanoparticle coatings M = Al, Fe, Ce, and SrH on a LiCoO2 cathode, the extent of the coating coverage is influenced by the nanoparticle size or morphology. Nanoparticles AlPO4

  18. NOx uptake on alkaline earth oxides (BaO, MgO, CaO and SrO) supported...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    uptake on alkaline earth oxides (BaO, MgO, CaO and SrO) supported on ?-Al2O3. NOx uptake on alkaline earth oxides (BaO, MgO, CaO and SrO) supported on ?-Al2O3....

  19. Tunable synthesis of TiO{sub 2}/SrO core/shell nanowire arrays with enhanced photocatalytic activity

    SciTech Connect (OSTI)

    Wang, Wenqi [Faculty of Earth Sciences, China University of Geosciences, Wuhan 430074 (China)] [Faculty of Earth Sciences, China University of Geosciences, Wuhan 430074 (China); Yang, Jie, E-mail: flyyangj@163.com [Faculty of Mechanical and Electronic Information, China University of Geosciences, Wuhan 430074 (China)] [Faculty of Mechanical and Electronic Information, China University of Geosciences, Wuhan 430074 (China); Gong, Yingpeng, E-mail: ypgong@jhust.edu.cn [School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074 (China)] [School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074 (China); Hong, Hanlie [Faculty of Earth Sciences, China University of Geosciences, Wuhan 430074 (China)] [Faculty of Earth Sciences, China University of Geosciences, Wuhan 430074 (China)

    2013-01-15T23:59:59.000Z

    Graphical abstract: TiO{sub 2} nanowires with tunable SrO shell layer are easily fabricated. The core/shell structure can enhance the photocatalytic activity of TiO{sub 2} nanowires and restrict the recombination of the electrons/holes. Display Omitted Highlights: ? A facile method to fabricate TiO{sub 2}/SrO core-shell nanowire array is reported. ? The thickness of SrO shell layer can be tunable by adjusting the dipping time. ? TiO{sub 2}/SrO core/shell nanowires shows enhanced photocatalytic activity. -- Abstract: We report a simple method to fabricate well-aligned TiO{sub 2}/SrO core/shell nanowire arrays. The core/shell structure is confirmed to have crystalline TiO{sub 2} nanowires core and amorphous SrO shell layer. The shell is composed of SrO with tunable thickness. Photocatalytic activity measurement shows that TiO{sub 2}/SrO core/shell nanowire arrays outperform uncovered TiO{sub 2} nanowires. Such core/shell nanowire arrays have potential applications for photovoltaic devices and as high performance photocatalyst.

  20. Hysteresis analysis of CoTi substituted M-type BaSr hexagonal ferrite Charanjeet Singh a,

    E-Print Network [OSTI]

    Koledintseva, Marina Y.

    Hysteresis analysis of Co­Ti substituted M-type Ba­Sr hexagonal ferrite Charanjeet Singh a, , S.5Sr0.5CoxTixFe(12 - 2x)O19 ferrite have been investigated by XRD, SEM and VSM. XRD and SEM confirm M ferrites are known for their strong uniaxial magne- tocrystalline anisotropy with ease of magnetization

  1. Degradation Mechanisms of La-Sr-Co-Fe-O3 SOFC Cathodes

    SciTech Connect (OSTI)

    Simner, Steve P.; Anderson, Michael D.; Engelhard, Mark H.; Stevenson, Jeffry W.

    2006-08-17T23:59:59.000Z

    The long-term stability of anode-supported YSZ electrolyte SOFCs utilizing (La0.6Sr0.4)0.98Co0.2Fe0.8O3-? (LSCF-6428) cathodes was assessed. Samples tested for 500 hours at 750 C and 0.7V indicated ?50% degradation. While scanning electron microscopy (SEM) and energy dispersive x-ray (EDX) analysis indicated no obvious microstructural or chemical phenomena that could explain the high degradation, x-ray photon spectroscopy (XPS) revealed that enrichment of Sr at the cathode-electrolyte and cathode-current collector interfaces was at least partially responsible for the observed degradation.

  2. Synthesis of highly phase pure (Bi, Pb)-Sr-Ca-Cu-O superconductor

    DOE Patents [OSTI]

    Dorris, S.E.; Poeppel, R.B.; Prorok, B.C.; Lanagan, M.T.; Maroni, V.A.

    1994-10-11T23:59:59.000Z

    An article and method of manufacture of (Bi,Pb)-Sr-Ca-Cu-O superconductor are disclosed. The superconductor is manufactured by preparing a first powdered mixture of bismuth oxide, lead oxide, strontium carbonate, calcium carbonate and copper oxide. A second powdered mixture is then prepared of strontium carbonate, calcium carbonate and copper oxide. The mixtures are calcined separately with the two mixtures then combined. The resulting combined mixture is then subjected to a powder in tube deformation and thermal processing to produce a substantially phase pure (Bi,Pb)-Sr-Ca-Cu-O superconductor. 5 figs.

  3. Synthesis of highly phase pure (Bi, Pb)-Sr-Ca-Cu-O superconductor

    DOE Patents [OSTI]

    Dorris, Stephen E. (La Grange Park, IL); Poeppel, Roger B. (Glen Ellyn, IL); Prorok, Barton C. (Harrisville, PA); Lanagan, Michael T. (Woodridge, IL); Maroni, Victor A. (Naperville, IL)

    1994-01-01T23:59:59.000Z

    An article and method of manufacture of (Bi,Pb)-Sr-Ca-Cu-O superconductor. The superconductor is manufactured by preparing a first powdered mixture of bismuth oxide, lead oxide, strontium carbonate, calcium carbonate and copper oxide. A second powdered mixture is then prepared of strontium carbonate, calcium carbonate and copper oxide. The mixtures are calcined separately with the two mixtures then combined. The resulting combined mixture is then subjected to a powder in tube deformation and thermal processing to produce a substantially phase pure (Bi,Pb)-Sr-Ca-Cu-O superconductor.

  4. Tuning the electronic structure of SrTiO{sub 3}/SrFeO{sub 3?x} superlattices via composition and vacancy control

    SciTech Connect (OSTI)

    Berger, Robert F. [Molecular Foundry, Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States); Department of Chemistry, Western Washington University, Bellingham, Washington 98225 (United States); Broberg, Daniel P. [Molecular Foundry, Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States); Neaton, Jeffrey B. [Molecular Foundry, Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States); Department of Physics, University of California, Berkeley, California 94720, USA and Kavli Institute for Energy Nanosciences, Berkeley, California 94720 (United States)

    2014-04-01T23:59:59.000Z

    Using density functional theory-based calculations, we explore the effects of oxygen vacancies and epitaxial layering on the atomic, magnetic, and electronic structure of (SrTiO{sub 3}){sub n}(SrFeO{sub 3?x}){sub 1} superlattices. While structures without oxygen vacancies (x = 0) possess small or non-existent band gaps and ferromagnetic ordering in their iron layers, those with large vacancy concentrations (x = 0.5) have much larger gaps and antiferromagnetic ordering. Though the computed gaps depend numerically on the delicate energetic balance of vacancy ordering and on the value of Hubbard U{sub eff} used in the calculations, we demonstrate that changes in layering can tune the band gaps of these superlattices below that of SrTiO{sub 3} (3.2 eV) by raising their valence band maxima. This suggests the possibility that these superlattices could absorb in the solar spectrum, and could serve as water-splitting photocatalysts.

  5. Design of highly ordered Ag-SrTiO{sub 3} nanotube arrays for photocatalytic degradation of methyl orange

    SciTech Connect (OSTI)

    Sun Yue [Key Laboratory of Design and Synthesis of Functional Materials and Green Catalysis, Colleges of Heilongjiang Province, College of Chemistry and Chemical Engineering, Harbin Normal University, Harbin 150025 (China); Liu Jiawen, E-mail: jiawenliu@yahoo.com.cn [Key Laboratory of Design and Synthesis of Functional Materials and Green Catalysis, Colleges of Heilongjiang Province, College of Chemistry and Chemical Engineering, Harbin Normal University, Harbin 150025 (China); Li Zhonghua, E-mail: lizh@hit.edu.cn [Key Laboratory of Microsystems and Microstructures Manufacturing, Ministry of Education, Harbin Institute of Technology, Harbin 150001 (China)

    2011-08-15T23:59:59.000Z

    Ag-SrTiO{sub 3} nanotube arrays were successfully prepared for the degradation of methyl orange (MO) under ultraviolet irradiation. In order to form highly ordered SrTiO{sub 3} nanotube arrays, the preparation of TiO{sub 2} nanotube arrays by anodic oxidation of titanium foil in different electrolytes was investigated. The selected organic solvents in electrolytes include glycerol, dimethyl sulfoxide and glycol. The results indicate that the morphology of TiO{sub 2} nanotube arrays prepared in glycol containing ammonium fluoride electrolyte is more regular. Then SrTiO{sub 3} nanotube arrays were synthesized by a hydrothermal method using TiO{sub 2} nanotube arrays as the precursor. In order to further improve the photocatalytic activity of SrTiO{sub 3} nanotube arrays, Ag nanoparticles were loaded on SrTiO{sub 3} nanotube arrays by two sets of experiments. The loaded Ag results in an enhancement of photocatalytic activity of SrTiO{sub 3} nanotube arrays. Moreover, the effect of pH on the photocatalytic degradation of MO was also studied. - Graphical abstract: Ag-SrTiO{sub 3} nanotube arrays were successfully prepared. The photocatalytic activity was evaluated by degradation of methyl orange under ultraviolet irradiation. Highlights: > TiO{sub 2} nanotube arrays prepared in glycol+NH{sub 4}F electrolyte are more regular. > Highly ordered Ag-SrTiO{sub 3} nanotube arrays were successfully synthesized. > Ag loading could enhance the photocatalytic activity of SrTiO{sub 3} nanotube arrays. > Ag-SrTiO{sub 3} nanotube arrays show excellent catalytic activity at a low pH value.

  6. PbSrYCaCuO : a new class of superconducting materials. Chemical analyses refined by Energy Dispersive X-rays

    E-Print Network [OSTI]

    Boyer, Edmond

    39 PbSrYCaCuO : a new class of superconducting materials. Chemical analyses refined by Energy of superconducting material - PbSrYCaCuO - has been recently synthesized. Energy Dispersive X-ray analyses synthesized a new class of superconducting materials, which can be represented by the general formula Pb2Sr2R1

  7. Lattice site location and annealing behaviour of Ca and Sr implanted GaN

    E-Print Network [OSTI]

    De Vries, Bart; Wahl, Ulrich; Correia, J G; Araújo, João Pedro; Lojkowski, W; Kolesnikov, D

    2006-01-01T23:59:59.000Z

    We report on the lattice location of ion-implanted Ca and Sr in thin films of single-crystalline wurtzite GaN. Using the emission channeling technique the angular distributions of $\\beta\\!^{-}$?particles emitted by the radioactive isotopes $^{45}$Ca(t$_{ 1/2}$=163.8 d) and $^{89}$Sr(t$_{ 1/2}$=50.53 d) were monitored with a position-sensitive detector following 60 keV room-temperature implantation. Our experiments give direct evidence that $\\sim$90% of Ca and > 60% of Sr atoms were occupying substitutional Ga sites with root mean square displacements of the order of 0.15–0.30 Å, i.e., larger than the expected thermal vibration amplitude of 0.074 Å. Annealing the Ca implanted samples at 1100–1350 °C in high-pressure N$_{2}$ atmosphere resulted in a better incorporation into the substitutional Ga site. The Sr implanted sample showed a small decrease in rms displacements for vacuum annealing up to 900 °C, while the substitutional fraction remained nearly constant. The annealing behavior of the rms disp...

  8. Preparation of Bi-Sr-Ca-Cu-O superconductors from oxide-glass precursors

    DOE Patents [OSTI]

    Hinks, David G. (Lemont, IL); Capone, II, Donald W. (Northbridge, MA)

    1992-01-01T23:59:59.000Z

    A superconductor and precursor therefor from oxide mixtures of Ca, Sr, Bi and Cu. Glass precursors quenched to elevated temperatures result in glass free of crystalline precipitates having enhanced mechanical properties. Superconductors are formed from the glass precursors by heating in the presence of oxygen to a temperature below the melting point of the glass.

  9. Neutron cross sections of the isomeric nuclei KPrn, Sr81m,and Nbgam

    E-Print Network [OSTI]

    Shlyakhter, Ilya

    ,, owing to multiple inelastic scattering. For the calculation of neutron spectra in real systemsNeutron cross sections of the isomeric nuclei KPrn, Sr81m,and Nbgam NJ. V. Petrov and A. I. Fiz. 23, 1186-1189 (June 1976) Inelastic neutron acceleration and retardation cross sections

  10. Sr radionuclide in cement: An atomistic modeling study Mostafa Youssef a

    E-Print Network [OSTI]

    Yildiz, Bilge

    Docking 90 Sr radionuclide in cement: An atomistic modeling study Mostafa Youssef a , Roland J: Available online xxxx Keywords: Molecular simulation Cement Nuclear waste storage Mechanical properties a b crystalline analog, the 9 Å-tobermorite. C­S­H is the major binding phase of cement. Strontium was shown

  11. November 1998 NREL/SR-500-24379 Fatigue of Composite Material Beam

    E-Print Network [OSTI]

    No. DE-AC36-83CH10093 #12;Fatigue of Composite Material Beam Elements Representative of Wind TurbineNovember 1998 · NREL/SR-500-24379 Fatigue of Composite Material Beam Elements Representative of Wind Turbine Blade Substructure John F. Mandell, Daniel D. Samborsky, David W. Combs, M. Ethan Scott

  12. RAPID COMMUNICATION / COMMUNICATION RAPIDE Validation of Sr isotopes in otoliths by laser

    E-Print Network [OSTI]

    California at Santa Cruz, University of

    RAPID COMMUNICATION / COMMUNICATION RAPIDE Validation of Sr isotopes in otoliths by laser ablation à plasma inductif avec multicollecteur après ablation au laser (LA-MC-ICPMS) et par spectrométrie de ratios using laser abla- tion multicollector inductively coupled plasma mass spectrometry (LA

  13. Haskins Laboratories Status Report on Speech Research 1992, SR-111 /112,111-120

    E-Print Network [OSTI]

    enhancement: alteration of auditory feedback and modification of speech production. INTRODUCTION The finding to fluency enhancement only because it alters the speech production characteristics of stutterers. WingateHaskins Laboratories Status Report on Speech Research 1992, SR-111 /112,111-120 Effects

  14. Chicago's Artisan Baker TM Job Title: Sr. Production Manager Department: Production

    E-Print Network [OSTI]

    Heller, Barbara

    Chicago's Artisan Baker TM Job Title: Sr. Production Manager Department: Production Revision Date is to oversee the operations of the production department. This position has the responsibility of coordinating all operational activities leading to the consistent achievement of product quality within yield

  15. Microstructure and properties of Bi-Sr-Ca-Cu-O with nanometer-scale alumina additions.

    SciTech Connect (OSTI)

    Goretta, K. C.

    1998-09-11T23:59:59.000Z

    Al{sub 2}O{sub 3} particles {approx}30 nm is size were added to Bi{sub 2}Sr{sub 2}CaCu{sub 2}O{sub x} in a 1:4 molar ratio. For comparison, 0.3 and {approx}3 pm Al{sub 2}O{sub 3} particles were added to separate batches. All materials were partial-melt processed. The Al{sub 2}O{sub 3} reacted during melting to primarily form stable compounds of approximate composition (Sr,Ca){sub 2}AlO{sub 4}. All additions caused slight decreases in the T{sub c} and melting point of the Bi{sub 2}Sr{sub 2}CaCu{sub 2}O{sub x}. The submicrometer Al{sub 2}O{sub 3} additions induced large expansions in magnetic-hysteresis width at 6 K. Electron microscopy examinations strongly suggested that the hysteresis expansion was related to alloying of the Bi{sub 2}Sr{sub 2}CaCu{sub 2}O{sub x} matrix rather than to pinning by volume defects.

  16. Frequency Ratio of ${}^{199}$Hg and ${}^{87}$Sr Optical Lattice Clocks beyond the SI Limit

    E-Print Network [OSTI]

    Yamanaka, Kazuhiro; Ushijima, Ichiro; Takamoto, Masao; Katori, Hidetoshi

    2015-01-01T23:59:59.000Z

    We report on a frequency ratio measurement of a ${}^{199}$Hg-based optical lattice clock referencing a ${}^{87}$Sr-based clock. Evaluations of lattice light shift, including atomic-motion-dependent shift, enable us to achieve a total systematic uncertainty of $7.2 \\times 10^{-17}$ for the Hg clock. The frequency ratio is measured to be $\

  17. SR-30 Soluble Support Material Safety Data Sheet 108454-0002

    E-Print Network [OSTI]

    Rollins, Andrew M.

    . HANDLING & STORAGE Handling Use good industrial hygiene practices. Provide adequate ventilation. Storage-irritating to skin. Ingestion No hazard in normal industrial use. Skin Absorption No absorption hazard in normal industrial use. 2011-04-27 Page 1 of 5 #12;SR-30 Soluble Support Material Safety Data Sheet 108454-0002 4

  18. Microsoft Word - U(VI)andSr(II)BatchSorption bh

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and mesoporous silica reacted with (B) 10 M Sr, (C) 10 M U at pH 4.0 with no carbonate and no calcium present, and (D) 10 M U at pH 9.8 with no carbonate and no...

  19. Magnetotransport properties of doped RuSr2GdCu2O8 

    E-Print Network [OSTI]

    McCrone, J E; Tallon, J L; Cooper, J R; MacLaughlin, A C; Attfield, J. Paul; Bernhard, C

    2003-01-01T23:59:59.000Z

    RuSr2GdCu2O8, in which magnetic order and superconductivity coexist with Tmag>Tc , is a complex material which poses new and important questions to our understanding of the interplay between magnetic and superconducting order. Resistivity, Hall...

  20. Graphic presentation of quarterly /sup 90/Sr fallout data, 1954-1982

    SciTech Connect (OSTI)

    Larsen, R.J.

    1984-01-01T23:59:59.000Z

    This report graphically presents all of the precipitation and /sup 90/Sr deposition data for all stations operated as part of the Environmental Measurements Laboratory's (EML) global fallout program since the initiation of the program in 1954. 3 references, 179 figures.

  1. Synthesis and Structure Determination of Ferromagnetic Semiconductors LaAMnSnO6 (A = Sr Ba)

    SciTech Connect (OSTI)

    T Yang; T Perkisas; J Hadermann; M Croft; A Ignatov; M Greenblatt

    2011-12-31T23:59:59.000Z

    LaAMnSnO{sub 6} (A = Sr, Ba) have been synthesized by high temperature solid-state reactions under dynamic 1% H{sub 2}/Ar flow. Rietveld refinements on room temperature powder X-ray diffraction data indicate that LaSrMnSnO{sub 6} crystallizes in the GdFeO{sub 3}-structure, with space group Pnma and, combined with transmission electron microscopy, LaBaMnSnO{sub 6} in Imma. Both space groups are common in disordered double-perovskites. The Mn{sup 3+} and Sn{sup 4+} ions whose valence states were confirmed by X-ray absorption spectroscopy, are completely disordered over the B-sites and the BO{sub 6} octahedra are slightly distorted. LaAMnSnO{sub 6} are ferromagnetic semiconductors with a T{sub C} = 83 K for the Sr- and 66 K for the Ba-compound. The title compounds, together with the previously reported LaCaMnSnO{sub 6} provide an interesting example of progression from Pnma to Imma as the tolerance factor increases. An analysis of the relationship between space group and tolerance factor for the series LaAMnMO{sub 6} (A = Ca, Sr, Ba; M = Sn, Ru) provides a better understanding of the symmetry determination for double perovskites.

  2. ATMOSPHERIC DUST AND MESOSCALE/MICROSCALE METEOROLOGY. A. Spiga1 , S.R. Lewis1

    E-Print Network [OSTI]

    Spiga, Aymeric

    ATMOSPHERIC DUST AND MESOSCALE/MICROSCALE METEOROLOGY. A. Spiga1 , S.R. Lewis1 , and F. For- get2 to advances in computational resources and modeling techniques. Note also that mesoscale modeling and Large: general circulation models, mesoscale models, microscale models [Large-Eddy Simulations]. Figure 1

  3. Structural studies of SrFeO{sub 3} and SrFe{sub 0.5}Nb{sub 0.5}O{sub 3} by employing XRD and XANES spectroscopic techniques

    SciTech Connect (OSTI)

    Akhtar, M. Javed, E-mail: javeda@pinstech.org.pk; Khan, R. Tahir Ali

    2011-10-15T23:59:59.000Z

    The perovskite based SrFeO{sub 3} and SrFe{sub 0.5}Nb{sub 0.5}O{sub 3} materials have been synthesized by solid state reaction methods. The structural properties are investigated using a combination of X-ray diffraction and X-ray absorption fine structure spectroscopic techniques. From the Rietveld refinement of the X-ray diffraction data it has been observed that SrFeO{sub 3} has a simple cubic perovskite structure, which is consistent with the previous literature results; whereas SrFe{sub 0.5}Nb{sub 0.5}O{sub 3} shows a tetragonal structure within P4mm space group. X-ray absorption results demonstrate that the valence state of Fe in SrFeO{sub 3} is (IV); however, it changes to (III) when 50% Nb{sup 5+} is substituted at the Fe sites. - Highlights: {yields} Structural studies by employing XRD and XANES spectroscopic techniques. {yields} Rietveld refinement confirmed SrFeO{sub 3} has cubic structure, space group Pm-3m. {yields} It is revealed that SrFe{sub 0.5}Nb{sub 0.5}O{sub 3} has tetragonal structure, in P4mm space group. {yields} From XANES results it is observed that Fe has valence state of (IV) in SrFeO{sub 3}. {yields} Doping of 50% Nb{sup 5+} at Fe sites, changes Fe valence to (III) in SrFe{sub 0.5}Nb{sub 0.5}O{sub 3}.

  4. An Injectable Apatite Permeable Reactive Barrier for In Situ 90Sr Immobilization

    SciTech Connect (OSTI)

    Vermeul, Vincent R.; Szecsody, James E.; Fritz, Brad G.; Williams, Mark D.; Moore, Robert C.; Fruchter, Jonathan S.

    2014-04-16T23:59:59.000Z

    An injectable permeable reactive barrier (PRB) technology was developed to sequester 90Sr in groundwater through the in situ formation of calcium-phosphate mineral phases, specifically apatite that incorporates 90Sr into the chemical structure. An integrated, multi-scale development and testing approach was used that included laboratory bench-scale experiments, an initial pilot-scale field test, and the emplacement and evaluation of a 300-ft-long treatability-test-scale PRB. Standard groundwater wells were used for emplacement of the treatment zone, allowing treatment of contaminants too deep below ground surface for trench-and-fill type PRB technologies. The apatite amendment formulation uses two separate precursor solutions, one containing a Ca-citrate complex and the other a Na-phosphate solution, to form apatite precipitate in situ. Citrate is needed to keep calcium in solution long enough to achieve a more uniform and areally extensive distribution of precipitate formation. In the summer of 2008, the apatite PRB technology was applied as a 91-m (300-ft) -long permeable reactive barrier on the downgradient edge of a 90Sr plume beneath the Hanford Site in Washington State. The technology was deployed to reduce 90Sr flux discharging to the Columbia River. Performance assessment monitoring data collected to date indicate the barrier is meeting performance objectives. The average reduction in 90Sr concentrations at four downgradient compliance monitoring locations was 95% relative to the high end of the baseline range approximately 1 year after treatment, and continues to meet remedial objectives more than 4 years after treatment.

  5. Processing & properties La{sub 1-x}A{sub x}Co{sub 1-y}Fe{sub y}O{sub 3}(A = Sr, Ca) perovskites

    SciTech Connect (OSTI)

    Stevenson, J.W.; Armstrong, T.R.; Pederson, L.R. [and others

    1995-04-01T23:59:59.000Z

    Selected compositions within the system La{sub 1-x}A{sub x}Co{sub 1-y}Fe{sub y}O{sub 3-{delta}}(A = Sr, Ca) were prepared by combustion synthesis and characterized by XRD, TGA, electrical conductivity, and oxygen permeation measurements. Substantial weight loss (due to loss of lattice oxygen) was observed in some compositions at high temperatures. For Sr containing materials, this weight loss increased with increasing Sr content. A substantial decrease in electronic conductivity was observed at high temperatures in Sr doped materials; this decrease was related to the decreased oxygen stoichiometry at these temperatures. In Sr doped compositions, oxygen flux increased with increasing Sr content. Calculated values of ionic conductivity were greater than the conductivity of yttria stabilized zirconia. Substitution of Ca for Sr resulted in substantially lower fluxes.

  6. Development of high through-put Sr isotope analysis for monitoring reservoir integrity for CO{sub 2} storage.

    SciTech Connect (OSTI)

    Wall, Andy; Jain, Jinesh; Stewart, Brian; Capo, Rosemary; Hakala, Alexandra J.; Hammack, Richard; Guthrie, George

    2012-01-01T23:59:59.000Z

    Recent innovations in multi-collector ICP-mass spectrometry (MC-ICP-MS) have allowed for rapid and precise measurements of isotope ratios in geological samples. Naturally occurring Sr isotopes has the potential for use in Monitoring, Verification, and Accounting (MVA) associated with geologic CO2 storage. Sr isotopes can be useful for: Sensitive tracking of brine migration; Determining seal rock leakage; Studying fluid/rock reactions. We have optimized separation chemistry procedures that will allow operators to prepare samples for Sr isotope analysis off site using rapid, low cost methods.

  7. Crystallographic, electronic, thermal, and magnetic properties of single-crystal SrCo2As2

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Pandey, Abhishek; Quirinale, D. G.; Jayasekara, W.; Sapkota, A.; Kim, M. G.; Dhaka, R. S.; Lee, Y.; Heitmann, T. W.; Stephens, P. W.; Ogloblichev, V.; et al

    2013-07-01T23:59:59.000Z

    In tetragonal SrCo2As2 single crystals, inelastic neutron scattering measurements demonstrated that strong stripe-type antiferromagnetic (AFM) correlations occur at a temperature T = 5 K [W. Jayasekara et al., arXiv:1306.5174] that are the same as in the isostructural AFe2As2 (A = Ca, Sr, Ba) parent compounds of high-Tc superconductors. This surprising discovery suggests that SrCo2As2 may also be a good parent compound for high-Tc superconductivity. Here, structural and thermal expansion, electrical resistivity ?, angle-resolved photoemission spectroscopy (ARPES), heat capacity Cp, magnetic susceptibility ?, 75As NMR and neutron diffraction measurements of SrCo2As2 crystals are reported together with LDA band structure calculations thatmore »shed further light on this fascinating material. The c-axis thermal expansion coefficient ?c is negative from 7 to 300 K, whereas ?a is positive over this T range. The ?(T) shows metallic character. The ARPES measurements and band theory confirm the metallic character and in addition show the presence of a flat band near the Fermi energy EF. The band calculations exhibit an extremely sharp peak in the density of states D(EF) arising from a flat dx2-y2 band. A comparison of the Sommerfeld coefficient of the electronic specific heat with ?(T ? 0) suggests the presence of strong ferromagnetic itinerant spin correlations which on the basis of the Stoner criterion predicts that SrCo2As2 should be an itinerant ferromagnet, in conflict with the magnetization data. The ?(T) does have a large magnitude, but also exhibits a broad maximum at 115 K suggestive of dynamic short-range AFM spin correlations, in agreement with the neutron scattering data. The measurements show no evidence for any type of phase transition between 1.3 and 300 K and we propose that metallic SrCo2As2 has a gapless quantum spin-liquid ground state.« less

  8. The elastic and piezoelectric properties of tungsten bronze ferroelectric crystals ,,Sr0.7Ba0.3...2NaNb5O15 and ,,Sr0.3Ba0.7...2NaNb5O15

    E-Print Network [OSTI]

    Cao, Wenwu

    The elastic and piezoelectric properties of tungsten bronze ferroelectric crystals ,,Sr0.7Ba0 and piezoelectric constants of tungsten bronze ferroelectric crystals Sr0.7Ba0.3 2NaNb5O15 SBNN70 and Sr0.3Ba0.7 2Na. INTRODUCTION Ferroelectric crystals with tungsten bronze structure are another attractive family beside

  9. Understanding the mechanism of conductivity at the LaAlO3/SrTiO3...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    two band insulators LaAlO3 and SrTiO3 is both fascinating and potentially useful for next-generation electronics. The reigning paradigm to explain the conductivity phenomenon is an...

  10. Thickness-dependent metal-insulator transition in epitaxial SrRuO? ultrathin films

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Shen, Xuan [Nanjing Univ. (China); Brookhaven National Lab. (BNL), Upton, NY (United States); Qiu, Xiangbiao [Nanjing Univ. (China); Su, Dong [Brookhaven National Lab. (BNL), Upton, NY (United States); Zhou, Shengqiang [Inst. of Ion Beam Physics and Materials Research, Dresden (Germany); Li., Aidong [Nanjing Univ. (China); Wu, Di [Nanjing Univ. (China)

    2015-01-07T23:59:59.000Z

    Transport characteristics of ultrathin SrRuO? films, deposited epitaxially on TiO?-terminated SrTiO? (001) single-crystal substrates, were studied as a function of film thickness. Evolution from a metallic to an insulating behavior is observed as the film thickness decreases from 20 to 4 unit cells. In films thicker than 4 unit cells, the transport behavior obeys the Drude low temperature conductivity with quantum corrections, which can be attributed to weak localization. Fitting the data with 2-dimensional localization model indicates that electron-phonon collisions are the main inelastic relaxation mechanism. In the film of 4 unit cells in thickness, the transport behavior follows variable range hopping model, indicating a strongly localized state. Magnetoresistance measurements reveal a likely magnetic anisotropy with the magnetic easy axis along the out-of-plane direction.

  11. Upper limit on spontaneous supercurrents in Sr2RuO4

    SciTech Connect (OSTI)

    Chung, Suk Bum

    2010-04-05T23:59:59.000Z

    It is widely believed that the perovskite Sr{sub 2}RuO{sub 4} is an unconventional superconductor with broken time reversal symmetry. It has been predicted that superconductors with broken time reversal symmetry should have spontaneously generated supercurrents at edges and domain walls. We have done careful imaging of the magnetic fields above Sr{sub 2}RuO{sub 4} single crystals using scanning Hall bar and SQUID microscopies, and see no evidence for such spontaneously generated supercurrents. We use the results from our magnetic imaging to place upper limits on the spontaneously generated supercurrents at edges and domain walls as a function of domain size. For a single domain, this upper limit is below the predicted signal by two orders of magnitude. We speculate on the causes and implications of the lack of large spontaneous supercurrents in this very interesting superconducting system.

  12. Disproof of solar influence on the decay rates of 90Sr/90Y

    E-Print Network [OSTI]

    Karsten Kossert; Ole Nähle

    2014-07-09T23:59:59.000Z

    A custom-built liquid scintillation counter was used for long-term measurements of 90Sr/90Y sources. The detector system is equipped with an automated sample changer and three photomultiplier tubes, which makes the application of the triple-to-double coincidence ratio (TDCR) method possible. After decay correction, the measured decay rates were found to be stable and no annual oscillation could be observed. Thus, the findings of this work are in strong contradiction to those of Parkhomov [1] who reported on annual oscillations when measuring 90Sr/90Y with a Geiger-M\\"uller counter. Sturrock et al. [2] carried out a more detailed analysis of the experimental data from Parkhomov and claimed to have found correlations between the decay rates and processes inside the Sun. These findings are questionable, since they are based on inappropriate experimental data as is demonstrated in this work. A frequency analysis of our activity data does not show any significant periodicity.

  13. Defects and persistent conductivity in SrTiO{sub 3}

    SciTech Connect (OSTI)

    McCluskey, Matthew D.; Tarun, Marianne C. [Department of Physics and Astronomy, Washington State University, Pullman, WA 99164-2814 (United States)

    2014-02-21T23:59:59.000Z

    Strontium titanate (SrTiO{sub 3}) is often used as a substrate for oxide thin films such as high-temperature superconductors. It has the perovskite structure and an indirect band gap of 3.25 eV. Our prior work showed that hydrogen impurities form a defect complex that contains two hydrogen atoms. The complex was tentatively attributed to a passivated strontium vacancy. Alternatively, it could be a partially passivated titanium vacancy. In order to create titanium vacancies, we annealed samples in an evacuated ampoule with SrO powder. These samples show unexpected behavior. After illuminating with sub-gap light, the free-electron concentration increases significantly. After the light is turned off, the high conductivity persists at room temperature. We attribute persistent photoconductivity (PPC) to the excitation of an electron from a vacancy into the conduction band, with a low recapture rate.

  14. LaSrVO4: a candidate for the spin-orbital liquid state

    SciTech Connect (OSTI)

    Dun, Z. L. [University of Tennessee, Knoxville (UTK)] [University of Tennessee, Knoxville (UTK); Garlea, Vasile O [ORNL] [ORNL; Ren, Y. [Argonne National Laboratory (ANL)] [Argonne National Laboratory (ANL); Choi, E. [National High Magnetic Field Laboratory (Magnet Lab), Florida] [National High Magnetic Field Laboratory (Magnet Lab), Florida; Zhang, H. M. [Southeast University, Nanjing, China] [Southeast University, Nanjing, China; Dong, S. [Southeast University, Nanjing, China] [Southeast University, Nanjing, China; Zhou, H. D. [University of Tennessee (UT)] [University of Tennessee (UT)

    2014-01-01T23:59:59.000Z

    A layered perovskite LaSrVO4 was studied by neutron diraction, pair distribution function measurement using synchrotron x-ray, susceptibility and specific heat measurements, and first-principles calculation. The results show (i) a weak structural distortion around 100 K with the existence of orbital fluctuations both above and below it; (ii) the absence of the long range magnetic ordering down to 0.35 K but the appearance of a short range magnetic ordering around 11 K with a T2 behavior of the specic heat below it. Meanwhile, the calculation based on the density functional theory predicts a magnetic ordered ground state. All facts indicate a melting of the magnetic ordering due to the orbital fluctuations in LaSrVO4, which makes it a rare candidate for the spin-orbital liquid state related to t2g orbitals.

  15. Thickness-dependent metal-insulator transition in epitaxial SrRuO? ultrathin films

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Shen, Xuan; Qiu, Xiangbiao; Su, Dong; Zhou, Shengqiang; Li., Aidong; Wu, Di

    2015-01-07T23:59:59.000Z

    Transport characteristics of ultrathin SrRuO? films, deposited epitaxially on TiO?-terminated SrTiO? (001) single-crystal substrates, were studied as a function of film thickness. Evolution from a metallic to an insulating behavior is observed as the film thickness decreases from 20 to 4 unit cells. In films thicker than 4 unit cells, the transport behavior obeys the Drude low temperature conductivity with quantum corrections, which can be attributed to weak localization. Fitting the data with 2-dimensional localization model indicates that electron-phonon collisions are the main inelastic relaxation mechanism. In the film of 4 unit cells in thickness, the transport behavior follows variablemore »range hopping model, indicating a strongly localized state. Magnetoresistance measurements reveal a likely magnetic anisotropy with the magnetic easy axis along the out-of-plane direction.« less

  16. On the Sr I 4607 A Hanle depolarization signals in the quiet Sun

    E-Print Network [OSTI]

    J. Sanchez Almeida

    2005-04-15T23:59:59.000Z

    The Hanle depolarization signals of Sr 4607 A have been used to estimate the unsigned magnetic flux and magnetic energy existing in the quiet Sun photosphere. However, the Sr 4607 A Hanle signals are not sensitive to the unsigned flux and energy. They only bear information on the fraction of photosphere occupied by magnetic field strengths smaller than the Hanle saturation, which do not contribute to the unsigned flux and energy. We deduce an approximate expression for the relationship between magnetic fill factor and Hanle signal. When applied to existing Hanle depolarization measurements, it indicates that only 40% of the quiet Sun is filled by magnetic fields with a strength smaller than 60 G. The remaining 60% of the surface has field strengths above this limit. Such constraint will be needed to determine the distribution of magnetic field strengths existing in the quiet Sun.

  17. Revealing the atomic and electronic structure of a SrTiO{sub 3}/LaNiO{sub 3}/SrTiO{sub 3} heterostructure interface

    SciTech Connect (OSTI)

    Zhang, Zaoli, E-mail: zaoli.zhang@oeaw.ac.at [Erich Schmid Institute of Materials Science, Austrian Academy of Sciences, Leoben (Austria); Electron Microscopy Group for Materials Science, University of Ulm, Ulm (Germany); Soltan, S. [Max-Planck Institute for Solid State Research, D-70561 Stuttgart (Germany); Faculty of Science, Helwan University, 11795 Cairo (Egypt); Schmid, H. [INM—Leibniz-Institut für Neue Materialien, 66123 Saarbrücken (Germany); Habermeier, H.-U.; Keimer, B. [Max-Planck Institute for Solid State Research, D-70561 Stuttgart (Germany); Kaiser, U. [Electron Microscopy Group for Materials Science, University of Ulm, Ulm (Germany)

    2014-03-14T23:59:59.000Z

    The atomic structures of SrTiO{sub 3} (STO)/LaNiO{sub 3} (LNO)/STO heterostructure interfaces were investigated by spherical aberration-corrected (C{sub S}) (scanning) transmission electron microscopy. Atomic displacement and lattice distortion measurements and electron energy loss spectroscopy (EELS) were used to quantitatively analyze the distortion of the interfacial octahedra and the bond length at the interfaces. Combined with high-resolution transmission electron microscopy (HRTEM) and scanning transmission electron microscopy analyses, two distinct interfacial atomic terminating layers are unambiguously determined. Ensuing quantitative HRTEM measurements revealed that the Ni-O bond length in the interfacial octahedral is elongated at the bottom interface (–NiO{sub 2}-SrO–). Atomic displacement shows structural relaxation effects when crossing the interfaces and lattice distortions across the interface is more pronounced in LNO than in STO. The Ti/O atomic ratio, La and Ti relative atomic ratio as derived by EELS quantification indicate non-stoichiometric composition at the interfaces. Distinct fine structures of Ti-L{sub 2,3} edge and O-K edge at the bottom and top interfaces are observed. By comparison, we are able to estimate Ti valency at both interfaces. Combining the structural distortions and Ti valency, the polar discontinuity and charge transfer at the interfaces are discussed.

  18. MAPPING H-BAND SCATTERED LIGHT EMISSION IN THE MYSTERIOUS SR21 TRANSITIONAL DISK

    SciTech Connect (OSTI)

    Follette, Katherine B.; Close, Laird [Steward Observatory, The University of Arizona, 933 N Cherry Ave, Tucson, AZ 85721 (United States)] [Steward Observatory, The University of Arizona, 933 N Cherry Ave, Tucson, AZ 85721 (United States); Tamura, Motohide; Hashimoto, Jun; Kwon, Jungmi; Kandori, Ryo [National Astronomical Observatory of Japan, 2-21-1 Osawa, Mitaka, Tokyo 181-8588 (Japan)] [National Astronomical Observatory of Japan, 2-21-1 Osawa, Mitaka, Tokyo 181-8588 (Japan); Whitney, Barbara [Astronomy Department, University of Wisconsin-Madison, 475 N. Charter Street, Madison, WI 53706 (United States)] [Astronomy Department, University of Wisconsin-Madison, 475 N. Charter Street, Madison, WI 53706 (United States); Grady, Carol [Eureka Scientific, 2452 Delmer, Suite 100, Oakland, CA 96002 (United States)] [Eureka Scientific, 2452 Delmer, Suite 100, Oakland, CA 96002 (United States); Andrews, Sean M. [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States)] [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States); Wisniewski, John [H.L. Dodge Department of Physics and Astronomy, University of Oklahoma, 440 W Brooks St Norman, OK 73019 (United States)] [H.L. Dodge Department of Physics and Astronomy, University of Oklahoma, 440 W Brooks St Norman, OK 73019 (United States); Brandt, Timothy D.; Dong, Ruobing [Department of Astrophysical Sciences, Princeton University, NJ 08544 (United States)] [Department of Astrophysical Sciences, Princeton University, NJ 08544 (United States); Mayama, Satoshi [The Center for the Promotion of Integrated Sciences, The Graduate University for Advanced Studies (Sokendai), Shonan International Village, Hayama-cho, Miura-gun, Kanagawa 240-0193 (Japan)] [The Center for the Promotion of Integrated Sciences, The Graduate University for Advanced Studies (Sokendai), Shonan International Village, Hayama-cho, Miura-gun, Kanagawa 240-0193 (Japan); Abe, Lyu [Laboratoire Lagrange, UMR7293, Universite de Nice-Sophia Antipolis, CNRS, Observatoire de la Cote d'Azur, F-06300 Nice (France)] [Laboratoire Lagrange, UMR7293, Universite de Nice-Sophia Antipolis, CNRS, Observatoire de la Cote d'Azur, F-06300 Nice (France); Brandner, Wolfgang; Feldt, Markus [Max Planck Institute for Astronomy, Koenigstuhl 17, D-69117 Heidelberg (Germany)] [Max Planck Institute for Astronomy, Koenigstuhl 17, D-69117 Heidelberg (Germany); Carson, Joseph [Department of Physics and Astronomy, College of Charleston, 58 Coming St., Charleston, SC 29424 (United States)] [Department of Physics and Astronomy, College of Charleston, 58 Coming St., Charleston, SC 29424 (United States); Currie, Thayne [Department of Astronomy and Astrophysics, University of Toronto, 50 St. George Street M5S 3H4, Toronto Ontario (Canada)] [Department of Astronomy and Astrophysics, University of Toronto, 50 St. George Street M5S 3H4, Toronto Ontario (Canada); Egner, Sebastian E. [Subaru Telescope, 650 North Aohoku Place, Hilo, HI 96720 (United States)] [Subaru Telescope, 650 North Aohoku Place, Hilo, HI 96720 (United States); Goto, Miwa, E-mail: kfollette@as.arizona.edu [Universitats-Sternwarte Munchen, Ludwig-Maximilians-Universitat, Scheinerstr. 1, D-81679 Munchen (Germany)] [Universitats-Sternwarte Munchen, Ludwig-Maximilians-Universitat, Scheinerstr. 1, D-81679 Munchen (Germany); and others

    2013-04-10T23:59:59.000Z

    We present the first near infrared (NIR) spatially resolved images of the circumstellar transitional disk around SR21. These images were obtained with the Subaru HiCIAO camera, adaptive optics, and the polarized differential imaging technique. We resolve the disk in scattered light at H-band for stellocentric 0.''1 {<=} r {<=} 0.''6 (12 {approx}< r {approx}< 75 AU). We compare our results with previously published spatially resolved 880 {mu}m continuum Submillimeter Array images that show an inner r {approx}< 36 AU cavity in SR21. Radiative transfer models reveal that the large disk depletion factor invoked to explain SR21's sub-mm cavity cannot be 'universal' for all grain sizes. Even significantly more moderate depletions ({delta} = 0.1, 0.01 relative to an undepleted disk) than those that reproduce the sub-mm cavity ({delta} {approx} 10{sup -6}) are inconsistent with our H-band images when they are assumed to carry over to small grains, suggesting that surface grains scattering in the NIR either survive or are generated by whatever mechanism is clearing the disk midplane. In fact, the radial polarized intensity profile of our H-band observations is smooth and steeply inwardly-increasing (r {sup -3}), with no evidence of a break at the 36 AU sub-mm cavity wall. We hypothesize that this profile is dominated by an optically thin disk envelope or atmosphere component. We also discuss the compatibility of our data with the previously postulated existence of a sub-stellar companion to SR21 at r {approx} 10-20 AU, and find that we can neither exclude nor verify this scenario. This study demonstrates the power of multiwavelength imaging of transitional disks to inform modeling efforts, including the debate over precisely what physical mechanism is responsible for clearing these disks of their large midplane grains.

  19. Optically pumped cerium-doped LiSrAlF{sub 6} and LiCaAlF{sub 6}

    DOE Patents [OSTI]

    Marshall, C.D.; Payne, S.A.; Krupke, W.F.

    1996-05-14T23:59:59.000Z

    Ce{sup 3+}-doped LiSrAlF{sub 6} crystals are pumped by ultraviolet light which is polarized along the c axis of the crystals to effectively energize the laser system. In one embodiment, the polarized fourth harmonic light output from a conventional Nd:YAG laser operating at 266 nm is arranged to pump Ce:LiSrAlF{sub 6} with the pump light polarized along the c axis of the crystal. The Ce:LiSrAlF{sub 6} crystal may be placed in a laser cavity for generating tunable coherent ultraviolet radiation in the range of 280-320 nm. Additionally, Ce-doped crystals possessing the LiSrAlF{sub 6} type of chemical formula, e.g. Ce-doped LiCaAlF{sub 6} and LiSrGaF{sub 6}, can be used. Alternative pump sources include an ultraviolet-capable krypton or argon laser, or ultraviolet emitting flashlamps. The polarization of the pump light will impact operation. The laser system will operate efficiently when light in the 280-320 nm gain region is injected or recirculated in the system such that the beam is also polarized along the c axis of the crystal. The Ce:LiSrAlF{sub 6} laser system can be configured to generate ultrashort pulses, and it may be used to pump other devices, such as an optical parametric oscillator. 10 figs.

  20. Optically pumped cerium-doped LiSrAlF.sub.6 and LiCaAlF.sub.6

    DOE Patents [OSTI]

    Marshall, Christopher D. (Livermore, CA); Payne, Stephen A. (Castro Valley, CA); Krupke, William F. (Pleasanton, CA)

    1996-01-01T23:59:59.000Z

    Ce.sup.3+ -doped LiSrAlF.sub.6 crystals are pumped by ultraviolet light which is polarized along the c axis of the crystals to effectively energize the laser system. In one embodiment, the polarized fourth harmonic light output from a conventional Nd:YAG laser operating at 266 nm is arranged to pump Ce:LiSrAlF.sub.6 with the pump light polarized along the c axis of the crystal. The Ce:LiSrAlF.sub.6 crystal may be placed in a laser cavity for generating tunable coherent ultraviolet radiation in the range of 280-320 nm. Additionally, Ce-doped crystals possessing the LiSrAlF.sub.6 type of chemical formula, e.g. Ce-doped LiCaAlF.sub.6 and LiSrGaF.sub.6, can be used. Alternative pump sources include an ultraviolet-capable krypton or argon laser, or ultraviolet emitting flashlamps. The polarization of the pump light will impact operation. The laser system will operate efficiently when light in the 280-320 nm gain region is injected or recirculated in the system such that the beam is also polarized along the c axis of the crystal. The Ce:LiSrAlF.sub.6 laser system can be configured to generate ultrashort pulses, and it may be used to pump other devices, such as an optical parametric oscillator.

  1. 110K Bi-Sr-Ca-Cu-O superconductor oxide and method for making same

    DOE Patents [OSTI]

    Veal, B.W.; Downey, J.W.; Lam, D.J.; Paulikas, A.P.

    1992-12-22T23:59:59.000Z

    A superconductor is disclosed consisting of a sufficiently pure phase of the oxides of Bi, Sr, Ca, and Cu to exhibit a resistive zero near 110K resulting from the process of forming a mixture of Bi[sub 2]O[sub 3], SrCO[sub 3], CaCO[sub 3] and CuO into a particulate compact wherein the atom ratios are Bi[sub 2], Sr[sub 1.2-2.2], Ca[sub 1.8-2.4], Cu[sub 3]. Thereafter, heating the particulate compact rapidly in the presence of oxygen to an elevated temperature near the melting point of the oxides to form a sintered compact, and then maintaining the sintered compact at the elevated temperature for a prolonged period of time. The sintered compact is cooled and reground. Thereafter, the reground particulate material is compacted and heated in the presence of oxygen to an elevated temperature near the melting point of the oxide and maintained at the elevated temperature for a time sufficient to provide a sufficiently pure phase to exhibit a resistive zero near 110K. 7 figs.

  2. High temperature crystal structures and superionic properties of SrCl{sub 2}, SrBr{sub 2}, BaCl{sub 2} and BaBr{sub 2}

    SciTech Connect (OSTI)

    Hull, Stephen, E-mail: stephen.hull@stfc.ac.uk [The ISIS Facility, STFC Rutherford Appleton Laboratory, Chilton, Didcot, Oxfordshire OX11 0QX (United Kingdom); Norberg, Stefan T. [The ISIS Facility, STFC Rutherford Appleton Laboratory, Chilton, Didcot, Oxfordshire OX11 0QX (United Kingdom); Department of Chemical and Biological Engineering, Chalmers University of Technology, SE-412 96 Gothenburg (Sweden); Ahmed, Istaq; Eriksson, Sten G. [Department of Chemical and Biological Engineering, Chalmers University of Technology, SE-412 96 Gothenburg (Sweden); Mohn, Chris E. [Department of Chemistry and Centre for Materials Science and Nanotechnology, University of Oslo, P.O. Box 1033 Blindern, N-0315 Oslo (Norway)

    2011-11-15T23:59:59.000Z

    The structural properties of the binary alkaline-earth halides SrCl{sub 2}, SrBr{sub 2}, BaCl{sub 2} and BaBr{sub 2} have been investigated from ambient temperature up to close to their melting points, using the neutron powder diffraction technique. Fluorite-structured SrCl{sub 2} undergoes a gradual transition to a superionic phase at 900-1100 K, characterised by an increasing concentration of anion Frenkel defects. At a temperature of 920(3) K, the tetragonal phase of SrBr{sub 2} undergoes a first-order transition to a cubic fluorite phase. This high temperature phase shows the presence of extensive disorder within the anion sublattice, which differs from that found in superionic SrCl{sub 2}. BaCl{sub 2} and BaBr{sub 2} both adopt the cotunnite crystal structure under ambient conditions. BaCl{sub 2} undergoes a first-order structural transition at 917(5) K to a disordered fluorite-structured phase. The relationship between the (disordered) crystal structures and the ionic conductivity behaviour is discussed and the influence of the size of the mobile anion on the superionic behaviour is explored. - Graphical abstract: Anomalous behaviour of the lattice expansion of SrCl{sub 2} at temperatures of {approx}1000 K is associated with the gradual transition to a superionic phase, whilst SrBr{sub 2} undergoes a first-order structural transition ({beta}{yields}{alpha}) to a fluorite-structured superionic phase at 920(3) K. Highlights: > Anomalous behaviour of the lattice expansion of SrCl{sub 2} occurs at temperatures {approx}1000 K. > Crystal structure of {beta}-SrBr{sub 2} is described in detail. > On heating, SrBr{sub 2} and BaCl{sub 2} transform to a fluorite-structured superionic phase. > Temperature dependence of the BaCl{sub 2} and BaBr{sub 2} structures is presented. > Nature of the superionic phases within the alkaline-earth halides is discussed.

  3. NNJ06JE86C DRD18 JS2011010 NNJ06JE86C DRD18 JS2011010 NNJ06JE86C DRD18 JS2011010

    E-Print Network [OSTI]

    International Space Station PAD PFR Attachment Device US United States IVA Intravehicular Activity Rapid resulted in or had a high likelihood for injury or death, loss of mission, or had significant relevance and as a broad indication of the failure rate. The metrics in the legend show the frequency of early termination

  4. Photoluminescence in the Ca{sub x}Sr{sub 1-x}WO{sub 4} system at room temperature

    SciTech Connect (OSTI)

    Porto, S.L. [Laboratorio de Combustiveis e Materiais (LACOM/DQ/CCEN), Universidade Federal da Paraiba, Campus I, Cidade Universitaria, Joao Pessoa, PB, CEP 58059-900 (Brazil); Longo, E. [CMDMC/LIEC, Instituto de Quimica, UNESP-Araraquara, Rua Prof. Francisco Degni s/n, Araraquara, SP, CEP 14800-900 (Brazil); Pizani, P.S.; Boschi, T.M. [Departamento de Fisica, Universidade Federal de Sao Carlos, Sao Carlos, Rodovia Washington Luiz km 235, SP, CEP 13565-905 (Brazil); Simoes, L.G.P. [Centro Multidisciplinar de Desenvolvimento de Materiais Ceramicos (LIEC/DQ), Universidade Federal de Sao Carlos, Rodovia Washington Luiz km 235, Sao Carlos, SP, CEP 13565-905 (Brazil); Lima, S.J.G. [Laboratorio de Solidificacao Rapida, Departamento de Tecnologia Mecanica (LSR/DTM/CT), Universidade Federal da Paraiba, Campus I, Cidade Universitaria, Joao Pessoa, PB, CEP 58059-900 (Brazil); Ferreira, J.M. [Laboratorio de Combustiveis e Materiais (LACOM/DQ/CCEN), Universidade Federal da Paraiba, Campus I, Cidade Universitaria, Joao Pessoa, PB, CEP 58059-900 (Brazil); COAMA, Area de Meio Ambiente, Centro Federal de Educacao Tecnologica da Paraiba, Av. 1o de Maio 720, Jaguaribe, Joao Pessoa, PB, CEP 58015-430 (Brazil); Soledade, L.E.B.; Espinoza, J.W.M.; Cassia-Santos, M.R.; Maurera, M.A.M.A. [Laboratorio de Combustiveis e Materiais (LACOM/DQ/CCEN), Universidade Federal da Paraiba, Campus I, Cidade Universitaria, Joao Pessoa, PB, CEP 58059-900 (Brazil); Paskocimas, C.A. [Departamento de Engenharia Mecanica, Universidade Federal do Rio Grande do Norte, Natal, RN, CEP 59072-970 (Brazil); Santos, I.M.G. [Laboratorio de Combustiveis e Materiais (LACOM/DQ/CCEN), Universidade Federal da Paraiba, Campus I, Cidade Universitaria, Joao Pessoa, PB, CEP 58059-900 (Brazil)], E-mail: ieda@quimica.ufpb.br; Souza, A.G. [Laboratorio de Combustiveis e Materiais (LACOM/DQ/CCEN), Universidade Federal da Paraiba, Campus I, Cidade Universitaria, Joao Pessoa, PB, CEP 58059-900 (Brazil)

    2008-08-15T23:59:59.000Z

    In this work, a study was undertaken about the structural and photoluminescent properties, at room temperature, of powder samples from the Ca{sub x}Sr{sub 1-x}WO{sub 4} (x=0-1.0) system, synthesized by a soft chemical method and heat treated between 400 and 700 deg. C. The material was characterized using Infrared, UV-vis and Raman spectroscopy and XRD. The most intense PL emission was obtained for the sample calcined at 600 deg. C, which is neither highly disordered (400-500 deg. C), nor completely ordered (700 deg. C). Corroborating the role of disorder in the PL phenomenon, the most intense PL response was not observed for pure CaWO{sub 4} or SrWO{sub 4}, but for Ca{sub 0.6}Sr{sub 0.4}WO{sub 4}. The PL emission spectra could be separated into two Gaussian curves. The lower wavelength peak is placed around 530 nm, and the higher wavelength peak at about 690 nm. Similar results were reported in the literature for both CaWO{sub 4} and SrWO{sub 4}. - Graphical abstract: The structural and room temperature photoluminescence of Ca{sub x}Sr{sub 1-x}WO4 synthesized by a soft chemical method was studied. The most intense PL emission was obtained for the sample calcined at 600 deg. C, that is neither highly disordered (400-500 deg. C), nor completely ordered (700 deg. C). Corroborating the role of disorder in the PL phenomenon, the most intense PL response was not observed for pure CaWO{sub 4} or SrWO{sub 4}, but for Ca{sub 0.6}Sr{sub 0.4}WO{sub 4}.

  5. Single-crystal epitaxial thin films of SrFeO{sub 2} with FeO{sub 2} 'infinite layers'

    SciTech Connect (OSTI)

    Inoue, Satoru; Kawai, Masanori; Shimakawa, Yuichi [Institute for Chemical Research, Kyoto University, Uji, Kyoto 611-0011 (Japan); Mizumaki, Masaichiro; Kawamura, Naomi [Japan Synchrotron Radiation Research Institute/SPring-8, Sayo, Hyogo 679-5198 (Japan); Watanabe, Takashi; Tsujimoto, Yoshihiro; Kageyama, Hiroshi; Yoshimura, Kazuyoshi [Department of Chemistry, Graduate School of Science, Kyoto University, Sakyo, Kyoto 606-8502 (Japan)

    2008-04-21T23:59:59.000Z

    Single-crystal thin films of SrFeO{sub 2}, which is an oxygen-deficient perovskite with ''infinite layers'' of Fe{sup 2+}O{sub 2}, were prepared by using CaH{sub 2} for low-temperature reduction of epitaxial SrFeO{sub 2.5} single-crystal films deposited on KTaO{sub 3} substrates. This reduction process, removing oxygen ions from the perovskite structure framework and causing rearrangements of oxygen ions, topotactically transforms the brownmillerite SrFeO{sub 2.5} to the c-axis oriented SrFeO{sub 2}.

  6. Tuning the Jeff=1/2 insulating state via electron doping and pressure in the double-layered iridate Sr3Ir2O7

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Li, L.; Kong, P. P.; Qi, T. F.; Jin, C. Q.; Yuan, S. J.; DeLong, L. E.; Schlottmann, P.; Cao, G.

    2013-06-01T23:59:59.000Z

    Sr3Ir2O7 exhibits a novel Jeff=12 insulating state that features a splitting between Jeff=1/2 and 3/2 bands due to spin-orbit interaction. We report a metal-insulator transition in Sr3Ir2O7 via either dilute electron doping (La3+ for Sr2+) or application of high pressure up to 35 GPa. Our study of single-crystal Sr3Ir2O7 and (Sr1?xLax)3Ir2O7 reveals that application of high hydrostatic pressure P leads to a drastic reduction in the electrical resistivity by as much as six orders of magnitude at a critical pressure PC = 13.2 GPa, manifesting a closing of the gap; but further increasing P up to 35 GPa produces no fully metallic state at low temperatures, possibly as a consequence of localization due to a narrow distribution of bonding angles ?. In contrast, slight doping of La3+ ions for Sr2+ ions in Sr3Ir2O7 readily induces a robust metallic state in the resistivity at low temperatures; the magnetic ordering temperature is significantly suppressed but remains finite for (Sr0.95La0.05)3Ir2O7 where the metallic state occurs. The results are discussed along with comparisons drawn with Sr2IrO4, a prototype of the Jeff=1/2 insulator.

  7. Radioactive contamination of cistern waters along the Croatian coast of the Adriatic Sea by [sup 90]Sr

    SciTech Connect (OSTI)

    Franic, Z.; Lokobauer, N.; Marovic, G. (Inst. for Medical Research and Occupational Health, Zagreb (Croatia). Radiation Protection Unit)

    1999-07-01T23:59:59.000Z

    Measurements of radioactive contamination of water samples from cisterns collecting rainwater containing fission products from roofs and other surfaces have been carried out along the Croatian coast of the Adriatic sea since 1968. An exponential decline of radioactivity followed the nuclear moratorium. After the nuclear accident at Chernobyl, higher levels of [sup 137]Cs and [sup 90]Sr were detected again, with cistern waters being the only environmental samples in Croatia in which elevated [sup 90]Sr activities persisted for several years. For the pre-Chernobyl period, the observed mean residence time of [sup 90]Sr in cistern waters, estimated to be 6.2 [+-] 1.9 y, was similar to that calculated for fallout. Contrary, for the post-Chernobyl time, observed [sup 90]Sr mean residence time was calculated to be considerably shorter, reflecting the tropospheric mean residence time. The annual dose for the critical adult population received from [sup 90]Sr and [sup 137]Cs by drinking cistern water was estimated to be very small, in the 1990's less than few [micro]Sv y[sup [minus]1].

  8. Electron spin resonance investigation of Mn^{2+} ions and their dynamics in manganese doped SrTiO_3

    E-Print Network [OSTI]

    V. V. Laguta; I. V. Kondakova; I. P. Bykov; M. D. Glinchuk; P. M. Vilarinho; A. Tkach; L. Jastrabik

    2007-02-28T23:59:59.000Z

    Using electron spin resonance, lattice position and dynamic properties of Mn2+ ions were studied in 0.5 and 2 % manganese doped SrTiO3 ceramics prepared by conventional mixed oxide method. The measurements showed that Mn2+ ions substitute preferably up to 97 % for Sr if the ceramics is prepared with a deficit of Sr ions. Motional narrowing of the Mn2+ ESR spectrum was observed when temperature increases from 120 K to 240-250 K that was explained as a manifestation of off-center position of this ion at the Sr site. From the analysis of the ESR spectra the activation energy Ea = 86 mV and frequency factor 1/?0 ? (2-10)x10^(-14) 1/s for jumping of the impurity between symmetrical off-center positions were determined. Both values are in agreement with those derived previously from dielectric relaxation. This proves the origin of dielectric anomalies in SrTiO3:Mn as those produced by the reorientation dynamics of Mn2+ dipoles.

  9. Ultrafast Magnetization Dynamics of SrRuO3 Thin Films

    SciTech Connect (OSTI)

    Langner, Matthew C

    2009-05-19T23:59:59.000Z

    Itinerant ferromagnet SrRuO3 has drawn interest from physicists due to its unusual transport and magnetic properties as well as from engineers due to its low resistivity and good lattice-matching to other oxide materials. The exact electronic structure remains a mystery, as well as details of the interactions between magnetic and electron transport properties. This thesis describes the use of time-resolved magneto-optical Kerr spectroscopy to study the ferromagnetic resonance of SrRuO3 thin films, where the ferromagnetic resonance is initiated by a sudden change in the easy axis direction in response to a pump pulse. The rotation of the easy axis is induced by laser heating, taking advantage of a temperature-dependent easy axis direction in SrRuO3 thin films. By measuring the change in temperature of the magnetic system in response to the laser pulse, we find that the specific heat is dominated by magnons up to unusually high temperature, ~;;100 K, and thermal diffusion is limited by a boundary resistance between the film and the substrate that is not consistent with standard phonon reflection and scattering models. We observe a high FMR frequency, 250 GHz, and large Gilbert damping parameter, alpha ~;; 1, consistent with strong spin-orbit coupling. We observe a time-dependent change in the easy axis direction on a ps time-scale, and we find that parameters associated with the change in easy axis, as well as the damping parameter, have a non-monotonic temperature dependence similar to that observed in anomalous Hall measurements.

  10. Shape mixing and beta-decay properties of neutron-deficient Kr and Sr isotopes

    E-Print Network [OSTI]

    P. Sarriguren

    2009-03-31T23:59:59.000Z

    Gamow-Teller strength distributions and beta-decay half-lives in neutron-deficient Kr and Sr isotopes are investigated within a deformed quasiparticle random phase approximation. The approach is based on a selfconsistent Skyrme Hartree-Fock mean field with pairing correlations and residual separable particle-hole and particle-particle forces. A simple two-level model is used to mix the nuclear shapes into the physical ground state. Good agreement with experiment is found with shape mixing coefficients which are consistent with those obtained phenomenologically from mixing of rotational bands.

  11. Weak interaction rates for Kr and Sr waiting-point nuclei under rp-process conditions

    E-Print Network [OSTI]

    P. Sarriguren

    2009-10-06T23:59:59.000Z

    Weak interaction rates are studied in neutron deficient Kr and Sr waiting-point isotopes in ranges of densities and temperatures relevant for the rp-process. The nuclear structure is described within a microscopic model (deformed QRPA) that reproduces not only the half-lives but also the Gamow-Teller strength distributions recently measured. The various sensitivities of the decay rates to both density and temperature are discussed. Continuum electron capture is shown to contribute significantly to the weak rates at rp-process conditions.

  12. La??xSrxCuO? superconductor nanowire devices

    SciTech Connect (OSTI)

    Litombe, N. E. [Harvard Univ., Cambridge, MA (United States); Brookhaven National Lab. (BNL), Upton, NY (United States); Bollinger, A. T. [Brookhaven National Lab. (BNL), Upton, NY (United States); Hoffman, J. E. [Harvard Univ., Cambridge, MA (United States); Bozovic, I. [Brookhaven National Lab. (BNL), Upton, NY (United States)

    2014-11-01T23:59:59.000Z

    La??xSrxCuO? nanowire devices have been fabricated and characterized using electrical transport measurements. Nanowires with widths down to 80 nm are patterned using high-resolution electron beam lithography. However, the narrowest nanowires show incomplete superconducting transitions with some residual resistance at T = 4 K. Here, we report on refinement of the fabrication process to achieve narrower nanowire devices with complete superconducting transitions, opening the path to the study of novel physics arising from dimension-limited superconductivity on the nanoscale.

  13. Note: Spatial resolution of Fuji BAS-TR and BAS-SR imaging plates

    SciTech Connect (OSTI)

    Fiksel, G.; Marshall, F. J.; Mileham, C.; Stoeckl, C. [Laboratory for Laser Energetics, University of Rochester, 250 East River Rd., Rochester, New York 14623-1299 (United States)

    2012-08-15T23:59:59.000Z

    The spatial resolution of two types of imaging plates, Fuji BAS-TR and Fuji BAS-SR, has been measured using a knife-edge x-ray source of 8-keV Cu K{sub {alpha}} radiation. The values for the spatial resolution, defined as the distance between 10% and 90% levels of the edge spread function, are 94 {mu}m and 109 {mu}m, respectively. The resolution values are important for quantitative analysis of x-ray and particle imaging and spectroscopic diagnostics.

  14. Luminescence Spectroscopy of Eu-doped (Ca,Sr)TiO{sub 3} Nanocrystals Prepared by Using Sonochemical Method

    SciTech Connect (OSTI)

    Kurniawan, C. [Chemistry Department of Semarang State University, Jl. Raya Sekaran Semarang (Indonesia); Prijamboedi, B. [Chemistry Department of Bandung Institute of Technology, Jl. Ganesha 10 Bandung (Indonesia)

    2010-10-24T23:59:59.000Z

    Perovskite-type compounds (ABO{sub 3}) of (Ca,Sr)TiO{sub 3} doped with trivalent europium (Eu{sup 3+}) were synthesized by sonochemical techniques. Powder X-ray diffraction measurement on (Ca,Sr)TiO{sub 3} were used to identify the perovskite crystal structure. The photoluminescence property in (Ca,Sr)TiO{sub 3} with europium substitution several atoms in the host lattice was also studied. Further, the photoluminescence spectra were taken at room temperature. The structural difference between fourth kinds of doped samples with different heating temperatures accounts for the intensification of the luminescence intensity. The presented measurements monitor the emission wavelengths of the Eu{sup 3+} with emission peaks at 593, 615 and 700 nm. The obtained results were discussed with respect to developed preparation method.

  15. Structural, optoelectronic, infrared and Raman spectra of orthorhombic SrSnO{sub 3} from DFT calculations

    SciTech Connect (OSTI)

    Moreira, E. [Departamento de Fisica Teorica e Experimental, Universidade Federal do Rio Grande do Norte, 59072-970 Natal-RN (Brazil); Henriques, J.M. [Centro de Educacao e Saude, Universidade Federal de Campina Grande, Campus Cuite, 58175-000 Cuite-PB (Brazil); Azevedo, D.L. [Departamento de Fisica, Universidade Federal do Maranhao, Centro de Ciencias Exatas e Tecnologia, 65085-580 Sao Luis-MA (Brazil); Departamento de Fisica Teorica e Experimental, Universidade Federal do Rio Grande do Norte, 59072-970 Natal-RN (Brazil); Caetano, E.W.S., E-mail: ewcaetano@gmail.co [Instituto Federal de Educacao, Ciencia e Tecnologia do Ceara, Av. 13 de Maio, 2081, Benfica, 60040-531 Fortaleza-CE (Brazil); Freire, V.N. [Departamento de Fisica, Universidade Federal do Ceara, Centro de Ciencias, Caixa Postal 6030, Campus do Pici, 60455-760 Fortaleza-CE (Brazil); Albuquerque, E.L. [Departamento de Biofisica e Farmacologia, Universidade Federal do Rio Grande do Norte, 59072-970 Natal-RN (Brazil)

    2011-04-15T23:59:59.000Z

    Orthorhombic SrSnO{sub 3} was investigated using density functional theory (DFT) considering both the local density and generalized gradient approximations, LDA and GGA, respectively. The electronic band structure, density of states, complex dielectric function, optical absorption, and the infrared and Raman spectra were computed. Calculated lattice parameters are close to the experimental measurements, and an indirect band gap E(S{yields}{Gamma})=1.97eV (2.27 eV) was obtained within the GGA (LDA) level of calculation. Effective masses for holes and electrons were estimated, being very anisotropic in comparison with similar results for orthorhombic CaSnO{sub 3}. The complex dielectric function and the optical absorption of SrSnO{sub 3} were shown to be sensitive to the plane of polarization of the incident light. The infrared spectrum between 100 and 600 cm{sup -1} was obtained, with its main peaks being assigned, and a nice agreement between experimental and theoretical peaks of the Raman spectrum of orthorhombic SrSnO{sub 3} was achieved. -- Graphical abstract: Orthorhombic SrSnO{sub 3}: a view of the unit cell (left) and plots showing the calculated and experimental Raman spectra (right). Display Omitted Research highlights: {yields} We have performed DFT calculations on orthorhombic SrSnO{sub 3} crystals, obtaining their structural, electronical and optical properties. {yields} An indirect band gap was obtained, and anisotropic effective masses were found for both electrons and holes. {yields} The complex dielectric function and the optical absorption of SrSnO{sub 3} were shown to be very sensitive to the plane of polarization of the incident light. {yields} The infrared spectrum between 100 and 600 cm{sup -1} was obtained, with its main peaks being assigned, and a nice agreement between experimental and theoretical peaks of the Raman spectrum was achieved.

  16. Isotope compositions (C, O, Sr, Nd) of vertebrate fossils from the Middle Eocene oil shale of Messel, Germany: Implications for their taphonomy

    E-Print Network [OSTI]

    Schöne, Bernd R.

    Isotope compositions (C, O, Sr, Nd) of vertebrate fossils from the Middle Eocene oil shale isotopes Diagenesis Enamel Messel Propalaeotherium The Middle Eocene oil shale deposits of Messel (~0.706) due to diagenetic Sr uptake from the lake water/oil shale. Enamel 18 Op values (~18 ± 0

  17. Isotope compositions (C, O, Sr, Nd) of vertebrate fossils from the Middle Eocene oil shale of Messel, Germany: Implications for their taphonomy

    E-Print Network [OSTI]

    Schöne, Bernd R.

    Isotope compositions (C, O, Sr, Nd) of vertebrate fossils from the Middle Eocene oil shale isotopes Diagenesis Enamel Messel Propalaeotherium The Middle Eocene oil shale deposits of Messel (~0.706) due to diagenetic Sr uptake from the lake water/oil shale. Enamel 18 Op values (~18 ± 0

  18. Ceramic SrTiO/sub 3/ photoanodes: enhancement of photoactivity through

    SciTech Connect (OSTI)

    Odedkirk, B.; Blakemore, J.S.

    1983-02-01T23:59:59.000Z

    Results are reported for the photoactivity of lanthanum-doped, strongly reduced SrTiO/sub 3/ in microcrystalline ceramic form. Photoanodes of ..cap alpha..Sr/sub 1/

  19. Durability of (Pr0.7sr0.3)Mn03 +/-delta/8ysz

    SciTech Connect (OSTI)

    An, Ke [ORNL; Reifsnider, K L [University of Connecticut, Storrs; Gao, C Y [University of Tennessee, Knoxville (UTK)

    2006-01-01T23:59:59.000Z

    Half cell SOFCs with Durability of (Pr{sub 0.7}Sr{sub 0.3})Mn0{sub 3}{+-}{delta}/8YSZ composite cathodes on 8YSZ electrolytes were aged up to 1000 h at 1000 C in air with/without 0.318 A cm{sup -2} cathodic polarization. During the aging, the performance of the half cell SOFCs was measured using electrochemical impedance spectroscopy (EIS). After aging, the surface of the composite cathode and the interface between the composite cathode and the electrolyte was investigated with scanning electron microscopy (SEM). Chemical element analysis was performed with energy dispersive X-ray spectroscopy (EDS). The performance of the half cell SOFCs degraded after aging with/without polarization compared to the initial state. The SOFCs had a larger polarization resistance after 1000 h of aging. The cathodic current was shown to have an impact on the performance by slowing down the rate of decrease of polarization resistance of the SOFCs. After aging, the microstructural properties--mean pore size increased and cumulative pore volume decreased, and growth of grains was found on the Durability of (Pr{sub 0.7}Sr{sub 0.3})Mn0{sub 3}{+-}{delta} phases.

  20. Magnetic, transport, and structural properties of SrRuO{sub 3} thin films

    SciTech Connect (OSTI)

    Majcher, A. M. [School of Physics and CRANN, Trinity College, Dublin 2 (Ireland); Institute of Physics, Jagiellonian University Krakow, Krakow (Poland); Rode, K.; Coey, J. M. D.; Stamenov, P., E-mail: stamenov.plamen@tcd.ie [School of Physics and CRANN, Trinity College, Dublin 2 (Ireland)

    2014-05-07T23:59:59.000Z

    Thin films of the oxide ferromagnetic metal SrRuO{sub 3} (SRO) are studied, in view of their potential use within oxide-based spin electronic devices. Here, their epitaxial growth on Si-compatible SrTiO{sub 3} substrates is demonstrated by pulsed laser deposition. Detail on their initial, structural, magnetic, and magnetotransport characterisation is also provided. In particular, resistivity and Hall data are interpreted within a two/three carrier model, above T{sub C.} Below T{sub C}, some information about the anisotropy of the Fermi surface effective elipsoids (?1:4) is recovered. The low-temperature saturation magnetisation approaches 1??{sub B}/Ru, with an uniaxial anisotropy of above 0.6 MJm{sup –3}. Despite its low T{sub C} = 160?K, and in view of its relatively low carrier mobility, it is reasoned that SRO could be utilized as the electrode layer in low-temperature all-oxide-MTJ (Magnetic Tunnel Junction) demonstrators and as a seed layer for other ferromagnetic oxides, at and above room temperature.

  1. SR0001

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  2. SR0002

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  3. SR0003

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  4. SR0004

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  5. SR0005

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  6. SR0006

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  7. SR0007

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  8. SR0008

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  9. SR0009

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  10. SR0010

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  11. SR0011

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  12. SR0012

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  13. SR0013

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  14. SR0014

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  15. SR0015

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  16. SR0016

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  17. SR0017

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  18. SR0018

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  19. SR0101

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  20. SR0102

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  1. SR0103

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  2. SR0104

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  3. SR0105

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  4. SR0106

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Scienceand Requirements RecentlyElectronicResourcesjobsJuly through Sept8, 2001 Media8, 200131,

  5. SR0107

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Scienceand Requirements RecentlyElectronicResourcesjobsJuly through Sept8, 2001 Media8, 200131,4,

  6. SR0108

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Scienceand Requirements RecentlyElectronicResourcesjobsJuly through Sept8, 2001 Media8,

  7. SR0109

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Scienceand Requirements RecentlyElectronicResourcesjobsJuly through Sept8, 2001 Media8,0, 2001

  8. SR0110

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Scienceand Requirements RecentlyElectronicResourcesjobsJuly through Sept8, 2001 Media8,0, 20014,

  9. SR0111

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Scienceand Requirements RecentlyElectronicResourcesjobsJuly through Sept8, 2001 Media8,0, 20014,4,

  10. SR0112

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Scienceand Requirements RecentlyElectronicResourcesjobsJuly through Sept8, 2001 Media8,0,

  11. SR0113?

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Scienceand Requirements RecentlyElectronicResourcesjobsJuly through Sept8, 2001 Media8,0,December

  12. SR0201

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Scienceand Requirements RecentlyElectronicResourcesjobsJuly through Sept8, 2001

  13. SR0203

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Scienceand Requirements RecentlyElectronicResourcesjobsJuly through Sept8, 200131, 2002 Media

  14. SR0204

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Scienceand Requirements RecentlyElectronicResourcesjobsJuly through Sept8, 200131, 2002 Media2

  15. SR0205

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Scienceand Requirements RecentlyElectronicResourcesjobsJuly through Sept8, 200131, 2002 Media219,

  16. SR0206

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Scienceand Requirements RecentlyElectronicResourcesjobsJuly through Sept8, 200131, 2002

  17. SR0207

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Scienceand Requirements RecentlyElectronicResourcesjobsJuly through Sept8, 200131, 200230, 2002

  18. SR0208

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Scienceand Requirements RecentlyElectronicResourcesjobsJuly through Sept8, 200131, 200230, 2002,

  19. SR0209

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Scienceand Requirements RecentlyElectronicResourcesjobsJuly through Sept8, 200131, 200230, 2002,4,

  20. SR0301

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Scienceand Requirements RecentlyElectronicResourcesjobsJuly through Sept8, 200131, 200230,

  1. SR0302

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Scienceand Requirements RecentlyElectronicResourcesjobsJuly through Sept8, 200131, 200230,8, 2003

  2. SR0303

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Scienceand Requirements RecentlyElectronicResourcesjobsJuly through Sept8, 200131, 200230,8,

  3. SR0304

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Scienceand Requirements RecentlyElectronicResourcesjobsJuly through Sept8, 200131, 200230,8,12,

  4. SR0305

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Scienceand Requirements RecentlyElectronicResourcesjobsJuly through Sept8, 200131, 200230,8,12,2,

  5. SR0501

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Scienceand Requirements RecentlyElectronicResourcesjobsJuly through Sept8, 200131,

  6. SR0503

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Scienceand Requirements RecentlyElectronicResourcesjobsJuly through Sept8, 200131,14, 2005 Media

  7. SR0505

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Scienceand Requirements RecentlyElectronicResourcesjobsJuly through Sept8, 200131,14, 2005 Media1,

  8. SR0601

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Scienceand Requirements RecentlyElectronicResourcesjobsJuly through Sept8, 200131,14, 2005

  9. SR0603

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Scienceand Requirements RecentlyElectronicResourcesjobsJuly through Sept8, 200131,14, 2005July 10,

  10. SR0604

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Scienceand Requirements RecentlyElectronicResourcesjobsJuly through Sept8, 200131,14, 2005July

  11. SR0605

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Scienceand Requirements RecentlyElectronicResourcesjobsJuly through Sept8, 200131,14,

  12. SR0606

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Scienceand Requirements RecentlyElectronicResourcesjobsJuly through Sept8, 200131,14,31, 2006

  13. SR0608

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Scienceand Requirements RecentlyElectronicResourcesjobsJuly through Sept8, 200131,14,31, 200630,

  14. SR0701?

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Scienceand Requirements RecentlyElectronicResourcesjobsJuly through Sept8, 200131,14,31, 200630,8,

  15. SR0703

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Scienceand Requirements RecentlyElectronicResourcesjobsJuly through Sept8, 200131,14,31,

  16. SR0704

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Scienceand Requirements RecentlyElectronicResourcesjobsJuly through Sept8, 200131,14,31,3, 2004

  17. SR0704

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Scienceand Requirements RecentlyElectronicResourcesjobsJuly through Sept8, 200131,14,31,3,

  18. SR0705

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Scienceand Requirements RecentlyElectronicResourcesjobsJuly through Sept8, 200131,14,31,3,June 13,

  19. SR0706

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Scienceand Requirements RecentlyElectronicResourcesjobsJuly through Sept8, 200131,14,31,3,June

  20. SR0708

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Scienceand Requirements RecentlyElectronicResourcesjobsJuly through Sept8,

  1. SR0804

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Scienceand Requirements RecentlyElectronicResourcesjobsJuly through Sept8,5, 2004 Media Contact:

  2. SR9805

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Scienceand Requirements RecentlyElectronicResourcesjobsJuly through Sept8,5,Friday,SRS Tank 516,

  3. SR9806

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Scienceand Requirements RecentlyElectronicResourcesjobsJuly through Sept8,5,Friday,SRS Tank 516,3,

  4. SR9807

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Scienceand Requirements RecentlyElectronicResourcesjobsJuly through Sept8,5,Friday,SRS Tank

  5. SR9901

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Scienceand Requirements RecentlyElectronicResourcesjobsJuly through Sept8,5,Friday,SRS Tank6, 1999

  6. SR9902

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Scienceand Requirements RecentlyElectronicResourcesjobsJuly through Sept8,5,Friday,SRS Tank6,

  7. SR9903

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Scienceand Requirements RecentlyElectronicResourcesjobsJuly through Sept8,5,Friday,SRS Tank6,22,

  8. SR9904

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Scienceand Requirements RecentlyElectronicResourcesjobsJuly through Sept8,5,Friday,SRS

  9. SR9908

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Scienceand Requirements RecentlyElectronicResourcesjobsJuly through Sept8,5,Friday,SRS9, 1999

  10. SR9909

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Scienceand Requirements RecentlyElectronicResourcesjobsJuly through Sept8,5,Friday,SRS9, 199913,

  11. SR9910

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Scienceand Requirements RecentlyElectronicResourcesjobsJuly through Sept8,5,Friday,SRS9, 199913,2,

  12. SR9911

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Scienceand Requirements RecentlyElectronicResourcesjobsJuly through Sept8,5,Friday,SRS9,

  13. SR9912

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Scienceand Requirements RecentlyElectronicResourcesjobsJuly through Sept8,5,Friday,SRS9,17, 1999

  14. SR9913

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Scienceand Requirements RecentlyElectronicResourcesjobsJuly through Sept8,5,Friday,SRS9,17,

  15. SR9914

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Scienceand Requirements RecentlyElectronicResourcesjobsJuly through Sept8,5,Friday,SRS9,17,1, 1999

  16. SR9916

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Scienceand Requirements RecentlyElectronicResourcesjobsJuly through Sept8,5,Friday,SRS9,17,1,

  17. SR9917

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Scienceand Requirements RecentlyElectronicResourcesjobsJuly through Sept8,5,Friday,SRS9,17,1,6,

  18. Autonomic Shutdown of Lithium-Ion Batteries Using Thermoresponsive...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Autonomic Shutdown of Lithium-Ion Batteries Using Thermoresponsive Microcapsules M. Baginska, B.J. Blaiszik, R.J. Merriman, J.S. Moore, N. R. Sottos, and S.R. White, University of...

  19. As[sub 2]S[sub 3]/Sr(Ti[sub 0.7]Co[sub 0.3])O[sub 3] and As[sub 2]S[sub 3]/Sr(Ti[sub 0.6]Fe[sub 0.4])O[sub 3] strip-loaded waveguides for integrated magneto-optical isolator applications

    E-Print Network [OSTI]

    Bi, Lei

    Sr(Ti[sub 0.6]Fe[sub 0.4])O[sub 3] (STF) and Sr(Ti[sub 0.7]Co[sub 0.3])O[sub 3] (STC) room-temperature ferromagnetic oxides were grown epitaxially on LaAlO[sub 3](001), (LaSr)(AlTa)O[sub 3] (001) and Si (001) substrates. ...

  20. ARTEMIS Summary Plots for J.S. Halekas

    E-Print Network [OSTI]

    California at Berkeley, University of

    (not lunar-tailored) available ­ hXp://artemis.ssl.berkeley.edu/summary.shtml · Come should be followed for data aXribuGon ­ hXp://artemis.ssl

  1. Revised 8/15/2008 JS Building Evacuation (Dixon Rec)

    E-Print Network [OSTI]

    Escher, Christine

    with EMS/public safety. Notify natatorium if it is necessary to exit the building. EXIT WEST ENTRY OR EMERGENCY EXIT WEST SIDE OF WEIGHT ROOM 1. West Entry Staff: Gather radio and 1st Aid Kit. Direct of the IM Track field. EXIT WEST ENTRY. Facility Services Staff: Go to 3rd Floor via stairs and check all RB

  2. Direct real space observation of magneto-electronic inhomogeneity in ultra-thin film La{sub 0.5}Sr{sub 0.5}CoO{sub 3??} on SrTiO{sub 3}(001)

    SciTech Connect (OSTI)

    Kelly, S.; Galli, F.; Aarts, J., E-mail: leighton@umn.edu, E-mail: aarts@physics.leidenuniv.nl [Department of Physics, Leiden University, 2300 RA Leiden (Netherlands); Bose, Shameek; Sharma, M.; Leighton, C., E-mail: leighton@umn.edu, E-mail: aarts@physics.leidenuniv.nl [Department of Chemical Engineering and Materials Science, University of Minnesota, Minneapolis, Minnesota 55455 (United States)

    2014-09-15T23:59:59.000Z

    Recent magnetotransport and neutron scattering measurements implicate interfacial magneto-electronic phase separation as the origin of the degradation in transport and magnetism in ultra-thin film La{sub 1?x}Sr{sub x}CoO{sub 3} on SrTiO{sub 3}(001). Here, using low temperature scanning tunneling microscopy and spectroscopy the first direct, real space observation of this nanoscopic electronic inhomogeneity is provided. Films of thickness 12.4?nm (32 unit cells) are found to exhibit spatially uniform conductance, in stark contrast to 4.7?nm (12 unit cell) films that display rich variations in conductance, and thus local density of states. The electronic heterogeneity occurs across a hierarchy of length scales (5–50?nm), with complex correlations with both topography and applied magnetic fields. These results thus provide a direct observation of magneto-electronic inhomogeneity in SrTiO{sub 3}(001)/La{sub 0.5}Sr{sub 0.5}CoO{sub 3} at thicknesses below 6–7?nm, in good agreement with less direct techniques.

  3. Analysis of the Impact of SR-ARQ on the IP Packet Delay Performance in Mobile Data

    E-Print Network [OSTI]

    Murphy, John

    Analysis of the Impact of SR-ARQ on the IP Packet Delay Performance in Mobile Data Networks By in wired enviroment . . . . . . . . . . . . . . . . . . . . 43 3.2.2 TCP in the wireless environment . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 49 3.3.1 Scheduling algorithms for wired (error free) enviroment . . 50 3.3.2 Scheduling algorithms

  4. Depletion of glutathione in vivo as a method of improving the therapeutic ratio of misonidazole and SR 2508. [BSO; DEM

    SciTech Connect (OSTI)

    Yu, N.Y.; Brown, J.M.

    1984-08-01T23:59:59.000Z

    Depletion of intracellular glutathione (GSH) can enhance misonidazole (MISO) radiosensitizing efficacy both in vivo and in vitro. However, such treatments may also enhance the systemic toxicity in animals. The purpose of the present study was to test various ways of depleting GSH levels in a variety of experimental mouse tumors, to measure the improvement in the efficacy of MISO and its less toxic analog SR 2508 by this depletion, and to determine the effect of daily GSH depletion on the toxicity MISO and SR 2508. GSH levels were measured daily for 5 days in tumors, livers and brains of mice injected daily with buthionine sulfoximine (BSO), with or without diethylmaleate (DEM). Daily doses of BSO depleted tumor levels of GSH to 20 to 40% of controls by 6 hr after each injection. Injection of DEM 6 hr after BSO further enhanced the depletion. Administration of MISO or SR 2508 at the time of maximum GSH depletion enhanced the MISO efficacy by factors of 2.6 to 8 for depletion to 8% of controls by BSO + DEM, but no enhancement of SR 2508 was seen with tumors at 20% GSH levels achieved with BSO alone in the preliminary experiment. The chronic toxicity of MISO was enhanced not at all or by a factor of up to 2 for BSO and BSO + DEM respectively.

  5. Review of the structural and electrical properties of the (La,Sr)(Co,Fe)O{sub 3} system

    SciTech Connect (OSTI)

    Anderson, H.U.; Tai, L.W.; Chen, C.C.; Nasrallah, M.M.; Huebner, W. [Univ. of Missouri, Rolla, MO (United States). Dept. of Ceramic Engineering

    1995-12-31T23:59:59.000Z

    The (La,Sr)(Co,Fe)O{sub 3} LSCF system has been extensively studied because of its potential use as oxygen permeable membranes and cathodes for solid oxide fuel cells. This paper reviews the results of some of these studies and describes the thermochemical and electrical conductivity behavior of this system as functions of composition, temperature (600 to 1,200 C) and oxygen activity (10{sup {minus}19} to 1 atm). The oxygen stoichiometry was measured thermogravimetrically. The results show that at 1,000 C for the composition of La{sub 0.6}Sr{sub 0.4}Co{sub 0.2}Fe{sub 0.8}O{sub 3} as many as 20% of the oxygen sites can become vacant upon reduction before dissociation occurs. The total electrical conductivity show that at 1000 C in air the electrical conductivity is about 200 S/cm for La{sub 0.6}Sr{sub 0.4}Co{sub 0.2}Fe{sub 0.8}O{sub 3}, but decreases with reduction as the oxygen vacancies reduce the number of carriers. Upon reduction, these oxides did not dissociate into binary oxides and metal in a simple step, but they formed transient compounds which with further reduction dissociated to La{sub 2}O{sub 3}, SrO, Co, and Fe.

  6. Tunable blue light source by intracavity frequency doubling of a Cr-LiSrAIF6 laser

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Tunable blue light source by intracavity frequency doubling of a Cr- LiSrAIF6 laser Franqois-switched operation at 10 kHz was intracavity frequency doubled by using a LiIOl crystal. The 230 ns tunable blue lasers emitting in the blue-green wavelength range are expected to be the key components for optical

  7. H: Advising/Sr Yr Plan Sheet.docx Rev.10/7/2010 CIVIL & ENVIRONMENTAL ENGINEERING

    E-Print Network [OSTI]

    H: Advising/Sr Yr Plan Sheet.docx Rev.10/7/2010 CIVIL & ENVIRONMENTAL ENGINEERING Senior Year Plan of engineering interest and for preparation for employment and/or graduate study. Instructions: Students: Prior this form to the Senior Year Plan Collect-It site at: https

  8. Geothermal waters from the Taupo Volcanic Zone, New Zealand: Li,1 B and Sr isotopes characterization2

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Geothermal waters from the Taupo Volcanic Zone, New Zealand: Li,1 B and Sr isotopes 13 In this study, we report chemical and isotope data for 23 geothermal water samples collected geothermal waters collected from deep boreholes16 in different geothermal fields (Ohaaki, Wairakei, Mokai

  9. Age, geochemical and SrNdPb isotopic constraints for mantle source characteristics and petrogenesis of Teru Volcanics,

    E-Print Network [OSTI]

    Stern, Robert J.

    Age, geochemical and Sr­Nd­Pb isotopic constraints for mantle source characteristics and petrogenesis of Teru Volcanics, Northern Kohistan Terrane, Pakistan S.D. Khana,*, R.J. Sternb , M.I. Mantonb, University of Peshawar, Pakistan Accepted 21 April 2004 Available online 23 September 2004 Abstract

  10. INTEGRATIVE GENOME-WIDE ANALYSIS OF ALTERNATIVE PRE-MRNA SPLICING REGULATION BY THE DROSOPHILA SR PROTEIN FAMILY

    E-Print Network [OSTI]

    Bradley, Todd Christopher

    2013-05-31T23:59:59.000Z

    to understanding organismal development and disease. The SR proteins are a well-conserved class of RNA-binding proteins that have an essential role in the regulation of splice site selection, and have also been implicated as key regulators during other stages...

  11. Inclusion property of Cs, Sr, and Ba impurities in LiCl crystal formed by layer-melt crystallization

    SciTech Connect (OSTI)

    Choi, Jung-Hoon; Cho, Yung-Zun; Lee, Tae-Kyo; Eun, Hee-Chul; Kim, Jun-Hong; Park, Hwan-Seo; Kim, In-Tae; Park, Geun-Il [Nuclear Fuel Cycle Waste Treatment Research Division, Korea Atomic Energy Research Institute, Daejeon, 305-353 (Korea, Republic of)

    2013-07-01T23:59:59.000Z

    Pyroprocessing is one of the promising technologies enabling the recycling of spent nuclear fuels from a commercial light water reactor (LWR). In general, pyroprocessing uses dry molten salts as electrolytes. In particular, LiCl waste salt after pyroprocessing contains highly radioactive I/II group fission products mainly composed of Cs, Sr, and Ba impurities. Therefore, it is beneficial to reuse LiCl salt in the pyroprocessing as an electrolyte for economic and environmental issues. Herein, to understand the inclusion property of impurities within LiCl crystal, the physical properties such as lattice parameter change, bulk modulus, and substitution enthalpy of a LiCl crystal having 0-6 at% Cs{sup +} or Ba{sup 2+} impurities under existence of 1 at% Sr{sup 2+} impurity were calculated via the first-principles density functional theory. The substitution enthalpy of LiCl crystals having 1 at% Sr{sup 2+} showed slightly decreased value than those without Sr{sup 2+} impurity. Therefore, through the substitution enthalpy calculation, it is expected that impurities will be incorporated within LiCl crystal as co-existed form rather than as a single component form. (authors)

  12. T-TV-T^ sr^i Ris-R-597(EN) A ComputerProgram forReliability

    E-Print Network [OSTI]

    T-TV-T^ sr^i Risø-R-597(EN) SIMON A ComputerProgram forReliability and Statistical Analysis using and Statistical Analysis using Monte Carlo Simulation Program Description and Manual Hans ErikKøngsø and Kmt for calculation of reliability and statistical analy- sis. The program is of the Monte Carlo type

  13. Crews conduct in-water geotechnical drilling near SR 520 in Seattle August 2012 FOR MORE INFORMATION

    E-Print Network [OSTI]

    Otis, Brian

    necessary approvals prior to conducting the work. WSDOT is observing best management practices to avoidCrews conduct in-water geotechnical drilling near SR 520 in Seattle August 2012 FOR MORE as they design foundations for the new bridges. A small crew will use a drill rig mounted on a barge to complete

  14. Uptakes of Cs and Sr on San Joaquin soil measured following ASTM method C1733.

    SciTech Connect (OSTI)

    Ebert, W.L.; Petri, E.T. (Chemical Sciences and Engineering Division)

    2012-04-04T23:59:59.000Z

    Series of tests were conducted following ASTM Standard Procedure C1733 to evaluate the repeatability of the test and the effects of several test parameters, including the solution-to-soil mass ratio, test duration, pH, and the concentrations of contaminants in the solution. This standard procedure is recommended for measuring the distribution coefficient (K{sub d}) of a contaminant in a specific soil/groundwater system. One objective of the current tests was to identify experimental conditions that can be used in future interlaboratory studies to determine the reproducibility of the test method. This includes the recommendation of a standard soil, the range of contaminant concentrations and solution matrix, and various test parameters. Quantifying the uncertainty in the distribution coefficient that can be attributed to the test procedure itself allows the differences in measured values to be associated with differences in the natural systems being studied. Tests were conducted to measure the uptake of Cs and Sr dissolved as CsCl and Sr(NO{sub 3}){sub 2} in a dilute NaHCO{sub 3}/SiO{sub 2} solution (representing contaminants in a silicate groundwater) by a NIST standard reference material of San Joaquin soil (SRM 2709a). Tests were run to measure the repeatability of the method and the sensitivity of the test response to the reaction time, the mass of soil used (at a constant soil-to-solution ratio), the solution pH, and the contaminant concentration. All tests were conducted in screw-top Teflon vessels at 30 C in an oven. All solutions were passed through a 0.45-{mu}m pore size cellulose acetate membrane filter and stabilized with nitric acid prior to analysis with inductively-coupled plasma mass spectrometry (ICP-MS). Scoping tests with soil in demineralized water resulted in a solution pH of about 8.0 and the release of small amounts of Sr from the soil. Solutions were made with targeted concentrations of 1 x 10{sup -6} m, 1 x 10{sup -5} m, 2.5 x 10{sup -5} m, 5 x 10{sup -5} m, 1 x 10{sup -4} m, and 5 x 10{sup -4} m to measure the effects of the Cs and Sr concentrations on their uptake by the soil. The pH values of all solutions were adjusted to about pH 8.5 so that the effects of pH and concentration could be measured separately. The 1 x 10{sup -4} m solutions were used to measure the repeatability of the test and the effects of duration, scale, and imposed pH on the test response.

  15. INTERFACE DISORDER CONTROLLED SUPERCONDUCTIVITY YBa2Cu3O7 / SrTiO3 SUPERLATTICES

    SciTech Connect (OSTI)

    Garcia-Barriocanal, Javier [Universidad Complutense, Spain; Rivera-Calzada, Alberto [Universidad Complutense, Spain; Sefrioui, Z. [Universidad Complutense, Spain; Arias, D [Universidad Complutense, Spain; Varela del Arco, Maria [ORNL; Leon, C. [Universidad Complutense, Spain; Pennycook, Stephen J [ORNL; Santamaria, J. [Universidad Complutense, Spain

    2013-01-01T23:59:59.000Z

    We report on the coherent growth of ultrathin YBa2Cu3O7 (YBCO) layers on SrTiO3 (STO) in YBCO/STO superlattices. The termination plane of the STO is TiO2 and the CuO chains are missing at the interface. Disorder (steps) at the STO interface cause alterations of the stacking sequence of the intra-cell YBCO atomic layers. Stacking faults give rise to antiphase boundaries which break the continuity of the CuO2 planes and depress superconductivity. We show that superconductivity is directly controlled by interface disorder outlining the importance of pair breaking and localization by disorder in ultrathin layers.

  16. GR without SR: A gravitational-domain description of first-order Doppler effects

    E-Print Network [OSTI]

    Eric Baird

    1998-07-30T23:59:59.000Z

    Equivalence principles are a major part of modern relativity theory. Gravitational shifts can already be calculated within the time domain as motion shifts, and we examine the consequences of reversing this argument and describing motion shifts outside the time domain, as effects of curvature associated with relative velocity. This unusual "Doppler mass shift" approach appears to resolve some of Einstein's own criticisms of the "SR+GR" model and seems to remove some barriers to the reconciliation of classical and quantum theory. The disadvantage of this model is that constant-velocity problems no longer obey Euclidean geometry. By bypassing special relativity and the special theory's flat-space assumptions, the model also suggests an alternative non-transverse frequency-shift relationship. This difference should be testable.

  17. Magnetic order in the frustrated Ising-like chain compound Sr3NiIrO6 E. Lefranois,1, 2, 3,

    E-Print Network [OSTI]

    Boyer, Edmond

    in CsCoCl3 for instance3 . The most studied compound in the frustrated regime is Ca3Co2O6 because of its show that Ca3CoRhO6 5 , Sr3CoIrO6 6 , Sr3NiRhO6 7 and Sr3NiIrO6 6,8,9 have a similar behavior to Ca3Co2 of their unconventional magnetic properties due to the interplay between low dimensionality, magnetic frustration

  18. 65GHz Doppler Sensor with On-Chip Antenna in 0.18m SiGe Terry Yao, Lamia Tchoketch-Kebir, Olga Yuryevich, Michael Gordon, and Sorin P. Voinigescu

    E-Print Network [OSTI]

    Voinigescu, Sorin Petre

    -Kebir, Olga Yuryevich, Michael Gordon, and Sorin P. Voinigescu Edward S. Rogers Sr. Department of Electrical]-[5]. Modeling accuracy of inductors at mm-waves using the ASITIC software [6], verified in previously fabricated

  19. VIRGINIA POLYTECHNIC INSTITUTE AND STATE UNIVERSIT Y COMMENCEMENT

    E-Print Network [OSTI]

    Buehrer, R. Michael

    W. Rogers Mr. James W. Severt, Sr. Mr. James R. Smith Dr. Lori L. Wagner Dr. Gary Long, Faculty for Finance and Chief Financial Officer Earving L. Blythe, Vice President for Information Technology and Chief

  20. Coordination Compounds of Strontium. Syntheses, Characterizations, and Crystal Structures of [Sr(u-ONc)(2)(HONc(4))]2 and Sr(5)(u(4)-O)(u(3)-ONep)(4)(u-ONep)(4)(HONep)(solv)(4) (ONc=O(2)CCH(2)CMe(3));Nep=CH(2)CMe(3); solv=tetrahydrofuran or 1-methyl-imida

    SciTech Connect (OSTI)

    Boyle, Timothy J.; Tafoya, Cory J.; Scott, Brian L.; Ziller, Joseph W.

    1999-07-21T23:59:59.000Z

    The authors have synthesized and characterized two novel Sr compounds: [Sr({mu}-ONc){sub 2}(HONc){sub 4}]{sub 2} (1, ONc = O{sub 2}CCH{sub 2}CMe{sub 3}), and Sr{sub 5}({mu}{sub 4}-O)({mu}{sub 3}-ONep){sub 4}({mu}-ONep){sub 4}(HONep)(solv){sub 4} [ONep = OCH{sub 2}CMe{sub 3}, solv = tetrahydrofuran (THF), 2a; 1-methyl-imidazole (MeIm), (2b)], that demonstrate increased solubility in comparison to the commercially available Sr precursors. The two metal centers of 1 share 4 unidentate bridging {mu}-ONc ligands and complete their octahedral geometry through the coordination of 4 monodentate terminal HONc ligands. The structure arrangement of the central core of 2a and b are identical, wherein 4 octahedral Sr atoms are arranged in a square geometry around a {mu}{sub 4}-O ligand. An additional 7-coordinated Sr atom sits directly atop the {mu}{sub 4}-O to form a square base pyramidal arrangement of the Sr atoms but the apical Sr-O distance is too long to be considered a bond. In solution, compound 1 is disrupted forming a monomer but 2a and b retain their structures.

  1. Hanford 100N Area Apatite Emplacement: Laboratory Results of Ca-Citrate-PO4 Solution Injection and Sr-90 Immobilization in 100N Sediments

    SciTech Connect (OSTI)

    Szecsody, James E.; Burns, Carolyn A.; Moore, Robert C.; Fruchter, Jonathan S.; Vermeul, Vincent R.; Williams, Mark D.; Girvin, Donald C.; McKinley, James P.; Truex, Michael J.; Phillips, Jerry L.

    2007-10-01T23:59:59.000Z

    This report summarizes laboratory scale studies investigating the remediation of Sr-90 by Ca-citrate-PO4 solution injection/infiltration to support field injection activities in the Hanford 100N area. This study is focused on experimentally testing whether this remediation technology can be effective under field scale conditions to mitigate Sr-90 migration 100N area sediments into the Columbia River. Sr-90 is found primarily adsorbed to sediments by ion exchange (99% adsorbed, < 1% in groundwater) in the upper portion of the unconfined aquifer and lower vadose zone. Although primarily adsorbed, Sr-90 is still considered a high mobility risk as it is mobilized by seasonal river stage increases and by plumes of higher ionic strength relative to groundwater. This remediation technology relies upon the Ca-citrate-PO4 solution forming apatite precipitate [Ca6(PO4)10(OH)2], which incorporates some Sr-90 during initial precipitation and additionally slowly incorporates Sr-90 by solid phase substitution for Ca. Sr substitution occurs because Sr-apatite is thermodynamically more stable than Ca-apatite. Once the Sr-90 is in the apatite structure, Sr-90 will decay to Y-90 (29.1 y half-life) then Zr-90 (64.1 h half-life) without the potential for migration into the Columbia River. For this technology to be effective, sufficient apatite needs to be emplaced in sediments to incorporate Sr and Sr-90 for 300 years (~10 half-lives of Sr-90), and the rate of incorporation needs to exceed the natural groundwater flux rate of Sr in the 100N area. A primary objective of this study is to supply an injection sequence to deliver sufficient apatite into subsurface sediments that minimizes initial mobility of Sr-90, which occurs because the injection solution has a higher ionic strength compared to groundwater. This can be accomplished by sequential injections of low, then high concentration injection of Ca-citrate-PO4 solutions. Assessment of low concentration Ca-citrate-PO4, citrate-PO4, and PO4 solutions show greater Sr and Sr-90 incorporation during initial precipitation and less initial mobilization with solutions with low Ca2+ concentration. While all solutions showed nearly the same Sr uptake into apatite (14 to 17% by 2 weeks, 21% to 30% by 5 weeks), the incorporation efficiency (i.e., mM Sr incorporated per mM PO4 injected) was higher for solutions containing citrate. The Sr incorporation rate into apatite during initial precipitation (by 1 month) averaged 4.64 ± 1.9 x 10-4 h-1 (half-life 1500 ± 430 h, 8.85 x 10-7 mg Sr/day/mg apatite). The injection solution used in field injections #3 to #18 (10 mM PO4, 1 mM Ca, 2.5 mM citrate), which is deficient in Ca (a total of 16.7 mM needed to form apatite with 10 mM of PO4), resulted in the initial Sr and Ca peak (24 h) at 4.7x groundwater. By 30 days, the aqueous Sr concentration was 0.28x groundwater and Ca 0.43x groundwater, as both Sr and Ca are used to form initial apatite precipitates. Reactive transport simulation of the complex ion exchange, biodegradation, and precipitation processes showed that the initial Sr groundwater increase mobilized only 1.5% of the Sr mass in sediments. Citrate biodegradation, a necessary step in Ca-citrate-PO4 solutions forming apatite, had an average half-life of 50 h (at aquifer sediment/water ratio and temperature), and decreased an order of magnitude with sediment depth as the microbial biomass decreased five orders of magnitude. The rate of citrate biodegradation was relatively invariant with biomass and water saturation (50% to 100%, for vadose zone infiltration) possibly due to significant microbial injection using river water and subsurface microbial mobilization.

  2. Targeting of Osseous Sites with Alpha-emitting Ra-223: Comparison with the Beta-emitter Sr-89 in Mice

    SciTech Connect (OSTI)

    Henriksen, Gjermund; Fisher, Darrell R.; Roeske, John C.; Bruland, Oyvind S.; Larsen, Roy H.

    2003-05-16T23:59:59.000Z

    The bone-seeking property of and the potential to irradiate red marrow by the alpha-particle emitter Ra-223 (t1/2 = 11.43 d) were compared to those of the beta-emitter Sr-89 (t1/2 = 50.53 d). Methods: The biodistributions of Ra-223 and Sr-89 were studied in mice. Tissue uptakes were determined at 1 h, 6 h, 1 d, 3 d, and 14 d after intravenous administration. The potential redistribution of progeny from Ra-223 located in bone was investigated. Radiation absorbed doses were calculated for soft tissues and bone. Doses were also estimated for marrow-containing cavities assuming spheric geometries. Results: We found that both Sr-89 and Ra-223 selectively concentrated on bone surfaces relative to soft tissues. The measured bone uptake of Ra-223 was slightly higher than that of Sr-89. At the 24 h time-point, the femur uptake of Ra-223 was 40.1% of the administered activity per gram tissue. The uptake in spleen and most other soft tissues was higher for Ra-223 than for Sr-89. We observed rapid clearance of Ra-223 from soft tissues within the first 24 hours, but the bone surface uptake of Ra-223 increased with time up to 24 h. Among the soft tissues, the spleen had the greatest accumulation and retention of Ra-223. The femur-to-spleen ratio increased with time, from 6.4 at 6 h to 23.7 at 3 days after injections. We found little redistribution of Ra-223 daughter products away from bone (about 2% at 6 h and less than 1% detectable at 3 d). Estimates of dose to marrow-containing cavities showed that the Ra-223 alpha-emitter might have a marrow-sparing advantage compared to beta-emitters due to high linear-energy-transfer and short alpha range targeting osteoid surfaces. The alpha-emitters irradiate a smaller fraction of the marrow-containing volumes--sparing marrow and enhancing survival of marrow cells. At the same time, the bone surfaces receives a therapeutically effective radiation dose. Conclusion: The results of this study indicate that Ra-223 is a promising candidate for high linear-energy-transfer alpha-particle irradiation of cancer cells on bone surfaces. Radium-223 can, together with its daughter radionuclides, deliver an intense and highly localized field of radiation to bone surfaces with substantially less irradiation of healthy bone marrow dose compared to standard, bone-seeking beta-emitters such as Sr-89.

  3. Structure and optical properties of a noncentrosymmetric borate RbSr{sub 4}(BO{sub 3}){sub 3}

    SciTech Connect (OSTI)

    Xia, M.J. [Beijing Center for Crystal Research and Development, Key Laboratory of Functional Crystals and Laser Technology, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190 (China); Li, R.K., E-mail: rkli@mail.ipc.ac.cn [Beijing Center for Crystal Research and Development, Key Laboratory of Functional Crystals and Laser Technology, Technical Institute of Physics and Chemistry, Chinese Academy of Sciences, Beijing 100190 (China)

    2013-01-15T23:59:59.000Z

    A new noncentrosymmetric borate, RbSr{sub 4}(BO{sub 3}){sub 3} (abbreviated as RSBO), has been grown from Rb{sub 2}O--B{sub 2}O{sub 3}--RbF flux and its crystal structure was determined by single crystal x-ray diffraction. It crystallizes in space group Ama2 with cell parameters of a=11.128(10) A, b=12.155(15) A, c=6.952(7) A, Z=4. The basic structural units are isolated planar BO{sub 3} groups. Second harmonic generation (SHG) test of the title compound by the Kurtz-Perry method shows that RSBO can be phase matchable with an effective SHG coefficient about two-thirds as large as that of KH{sub 2}PO{sub 4} (KDP). Finally, based on the anionic group approximation, the optical properties of the title compound are compared with those of the structure-related apatite-like compounds with the formula 'A{sub 5}(TO{sub n}){sub 3}X'. - Graphical abstract: RbSr{sub 4}(BO{sub 3}){sub 3} and some other borate NLO compounds, namely Ca{sub 5}(BO{sub 3}){sub 3}F RCa{sub 4}(BO{sub 3}){sub 3}O (R=Y or Gd) and Na{sub 3}La{sub 2}(BO{sub 3}){sub 3} can be viewed as the derivatives of apatite. They have similar formula composed of five cations and three anion groups (we call them 5/3 structures). The detailed SHG coefficients and optical properties of the apatite-like NLO crystals were compared and summarized. Highlights: Black-Right-Pointing-Pointer A new noncentrosymmetric borate RbSr{sub 4}(BO{sub 3}){sub 3} was grown from flux. Black-Right-Pointing-Pointer The RbSr{sub 4}(BO{sub 3}){sub 3} can be viewed as a derivative of the apatite-like structure. Black-Right-Pointing-Pointer The structure and its relationship to the optical properties of RbSr{sub 4}(BO{sub 3}){sub 3} are compared with other NLO crystals with apatite-like structures. Black-Right-Pointing-Pointer The basic structural units are the planar BO{sub 3} groups in the structure. Black-Right-Pointing-Pointer Second harmonic generation (SHG) test shows that RbSr{sub 4}(BO{sub 3}){sub 3} can be phase matchable with an effective SHG coefficient about two-thirds as large as that of KH{sub 2}PO{sub 4}.

  4. Front-End Lattice Update Chris Rogers,

    E-Print Network [OSTI]

    McDonald, Kirk

    by linear interpolation off grid points every 5 mm in r. In ICOOL a series of cylinders are used with inner

  5. Beam Pulse Structure and Targets Roger Bennett

    E-Print Network [OSTI]

    McDonald, Kirk

    in a target. The shock wave travels through matter at the speed of sound, where E is Young's modulus of elasticity and is the density. E s = #12;The time taken for the wave to travel from the outer surface

  6. Reoptimising Front End with proton Chris Rogers,

    E-Print Network [OSTI]

    McDonald, Kirk

    ;Optimisation Routine 1D Model RF Cavity model Energy gain is sine wave Standard transit time factor absorber time_energy_movie-100mm.avi #12;Optimisation Routine Performance in ICOOL Longitudinal emittance... Optimisation using a simple 1D model works when no proton absorber Introducing a proton absorber screws up

  7. 2002 Fusion Summer Study Roger Bangerter

    E-Print Network [OSTI]

    ............................................................................................................ 48 3.3.2 Plasma Facing Components/Heat Removal.............................................................................. 50 3.3.3 Heating, Current Drive and Fueling ........................................................................................ 53 3.3.4 Vacuum Vessel and Remote Handling

  8. June 24, 2012 Dear Dr. Rogers

    E-Print Network [OSTI]

    Moore, Paul A.

    undergraduate degree at Bowling Green State University, and my daughter Green State University. I have over twenty years of experience in higher interest the opportunity to serve as the Vice President for Advancement at Bowling

  9. First Look at Muon Chicane Chris Rogers,

    E-Print Network [OSTI]

    McDonald, Kirk

    radioactive Probably part of target remote handling area Beam dump has to handle significant beam energy for this momentum range e.g. used by mu2e experiments e.g. used by 6d cooling channels e.g. used by stellarators becomes radioactive Probably part of target remote handling area Beam dump has to handle significant

  10. Rue Durocher PavillonRoger-Gaudry

    E-Print Network [OSTI]

    Leclercq, Remi

    Consultation médicale 6 Vaccination­Soins infirmiers 6 Physiothérapie 6 Services de laboratoire 6 Divers

  11. Roger D.Peng Francesca Dominici

    E-Print Network [OSTI]

    Dominici, Francesca

    of ambient air pollution. The methods and software developed in this area are applicable to a wide array for investigating the health effects of air pollution and gives examples and case studies in R which demonstrate, and graduate students work- ing in the area of air pollution and health and others analyzing similar data

  12. G4MICE vs ICOOL Chris Rogers,

    E-Print Network [OSTI]

    McDonald, Kirk

    a field map Grid spacing 5 mm in r and 1 mm in z Disable dynamic step size allocation #12; FieldsMICE field map 1.8 T0 T abs(Bicool Bg4mice ) #12; ICOOL Self ConsistencyFields only Choose grid size for magnetic field map Quite a hard cutoff as z grid size changes Gradual cutoff for radial grid

  13. Roger Seitz Savannah River National Laboratory

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 1112011 Strategic2 OPAM615_CostNSAR -DepartmentRetail DemandEnergyRisktoOrderPractical

  14. THE FEDERAL ENERGY ADMINISTRATION By Roger Anders

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directed offOCHCO Overview OCHCOSystems Analysis Success Stories Systems AnalysisTESTIMONY OF WILLIAM

  15. THE TEMPERATURE-DEPENDENT SURFACE STRUCTURE, COMPOSITION AND ELECTRONIC PROPERTIES OF THE CLEAN SrTiO3(111) CRYSTAL FACE: LEED, AES, ELS AND UPS STUDIES

    E-Print Network [OSTI]

    Lo, Wei Jen

    2011-01-01T23:59:59.000Z

    CRYSTAL.FACE: LEED, AES, ELS AND UPS STUDIES Wei Jen Lo andtaken Fig. cont'd. Fig. 9. The UPS spectrum of the Ar ionclean SrTi03 surface Fig. 10. The UPS spectrum of the clean,

  16. Exchange integrals in magnetoelectric hexagonal ferrite (SrCo{sub 2}Ti{sub 2}Fe{sub 8}O{sub 19}): A density functional study

    SciTech Connect (OSTI)

    Feng, Min [School of Physics, Nankai University, Tianjin 300071 (China); Shao, Bin [Department of Physics, Tsinghua University, Beijing 100084 (China); Lu, Yuan; Zuo, Xu, E-mail: xzuonku@gmail.com [College of Electronic Information and Optical Engineering, Nankai University, Tianjin 300071 (China)

    2014-05-07T23:59:59.000Z

    The exchange integrals in magnetoelectric hexagonal ferrite SrCo{sub 2}Ti{sub 2}Fe{sub 8}O{sub 19} have been calculated by using density functional theory. To get 10 inter-sublattice and 3 intra-sublattice exchange integrals, the electronic structures and total energies of 20 spin arrangements have been calculated with General Gradient Approximation (GGA) + U method. The dependence of exchange integrals on U has been studied. The comparison between the exchange integrals in SrFe{sub 12}O{sub 19} and those in SrCo{sub 2}Ti{sub 2}Fe{sub 8}O{sub 19} shows that substitution of Co and Ti decreases the most interactions involving the 12?k sites. The investigation based on our exchange integrals indicates that magnetic interaction between R and S blocks reduces significantly in SrCo{sub 2}Ti{sub 2}Fe{sub 8}O{sub 19}.

  17. Development of Dodecaniobate Keggin Chain Materials as Alternative Sorbents for SR and Actinide Removal from High-Level Nuclear Waste Solutions

    SciTech Connect (OSTI)

    Nyman, May; Bonhomme, Francois

    2004-03-28T23:59:59.000Z

    The current baseline sorbent (monosodium titanate) for Sr and actinide removal from Savannah River Site's high level wastes has excellent adsorption capabilities for Sr but poor performance for the actinides. We are currently investigating the development of alternative materials that sorb radionuclides based on chemical affinity and/or size selectivity. The polyoxometalates, negatively-charged metal oxo clusters, have known metal binding properties and are of interest for radionuclide sequestration. We have developed a class of Keggin-ion based materials, where the Keggin ions are linked in 1- dimensional chains separated by hydrated, charge-balancing cations. These Nb-based materials are stable in the highly basic nuclear waste solutions and show good selectivity for Sr and Pu. Synthesis, characterization and structure of these materials in their native forms and Sr-exchanged forms will be presented.

  18. Tissue specific regulation of the high density lipoprotein (HDL) receptor, scavenger receptor Class B, Type I (SR-BI) by the scaffold protein PDZK1

    E-Print Network [OSTI]

    Fenske, Sara Anne

    2008-01-01T23:59:59.000Z

    PDZK1 is a four PDZ-domain containing cytoplasmic adaptor protein that binds the Cterminus of the high-density lipoprotein (HDL) receptor SR-BI. Abolishing PDZK1 expression in PDZK1 knockout (KO) mice leads to a ...

  19. Electronic Phase Separation in Pr sub 1 sub x (Ca, Sr) sub x MnO sub 3 subdelta and Tunneling Magnetoresistance in Sr sub 2 FeMoO sub 6

    E-Print Network [OSTI]

    Niebieskikwiat, D G

    2003-01-01T23:59:59.000Z

    In this work, we approach two aspects of the physics of magnetic perovskites presenting colossal magnetoresistance (CMR). Firstly, we go deeply into the phase separation (PS) between the ferromagnetic (FM) metallic state and the antiferro-magnetic (AFM) charge ordered (CO) insulating state, in manganites of the type Pr sub 1 sub x (Ca,Sr) sub x MnO sub 3 subdelta. Secondly, and more briefly, we analyze the problem of the influence of the grain boundary insulating barriers on the tunneling magnetoresistance in the Sr sub 2 FeMoO sub 6 double perovskite.The use of different measurement techniques allowed us to make a complete characterization of the PS state in the compounds Pr sub 0.65Ca sub 0 sub . sub 3 sub 5 sub - sub y Sr sub y MnO sub 3 for 0 ) keeping constant the carrier concentration (x = 0.35). This material presents an evolution from a CO insulating phase for small (y =0), towards the FM metallic phase for large (y = 0.20). In t

  20. IDENTIFICATION OF AN {sup 84}Sr-DEPLETED CARRIER IN PRIMITIVE METEORITES AND IMPLICATIONS FOR THERMAL PROCESSING IN THE SOLAR PROTOPLANETARY DISK

    SciTech Connect (OSTI)

    Paton, Chad; Schiller, Martin; Bizzarro, Martin, E-mail: chadpaton@gmail.com, E-mail: schiller@snm.ku.dk, E-mail: bizzarro@snm.ku.dk [Centre for Star and Planet Formation, Natural History Museum of Denmark, University of Copenhagen, Copenhagen DK-1350 (Denmark)

    2013-02-01T23:59:59.000Z

    The existence of correlated nucleosynthetic heterogeneities in solar system reservoirs is now well demonstrated for numerous nuclides. However, it has proven difficult to discriminate between the two disparate processes that can explain such correlated variability: incomplete mixing of presolar material or secondary processing of a well-mixed disk. Using stepwise acid-leaching of the Ivuna CI-chondrite, we show that unlike other nuclides such as {sup 54}Cr and {sup 50}Ti, Sr-isotope variability is the result of a carrier depleted in {sup 84}Sr. The carrier is most likely presolar SiC, which is known to have both high Sr-concentrations relative to solar abundances and extremely depleted {sup 84}Sr compositions. Thus, variability in {sup 84}Sr in meteorites and their components can be attributed to varying contributions from presolar SiC. The observed {sup 84}Sr excesses in calcium-aluminum refractory inclusions (CAIs) suggest their formation from an SiC-free gaseous reservoir, whereas the {sup 84}Sr depletions present in differentiated meteorites require their formation from material with an increased concentration of SiC relative to CI chondrites. The presence of a positive correlation between {sup 84}Sr and {sup 54}Cr, despite being hosted in carriers of negative and positive anomalies, respectively, is not compatible with incomplete mixing of presolar material but instead suggests that the solar system's nucleosynthetic heterogeneity reflects selective thermal processing of dust. Based on vaporization experiments of SiC under nebular conditions, the lack of SiC material in the CAI-forming gas inferred from our data requires that the duration of thermal processing of dust resulting in the vaporization of CAI precursors was extremely short-lived, possibly lasting only hours to days.

  1. Sr3PbNiO6: Trigonal Prismatic Lead in a Novel Inverse K4CdCl6-type Pseudo-One-Dimensional Oxide

    E-Print Network [OSTI]

    zur Loye, Hans-Conrad

    Sr3PbNiO6: Trigonal Prismatic Lead in a Novel Inverse K4CdCl6-type Pseudo-One-Dimensional Oxide example of lead in the 2H hexagonal perovskite-related family of oxides with the formula A3ABO6 Manuscript Received August 11, 1999 The new one-dimensional oxide Sr3PbNiO6 contains the first reported

  2. Application of LaSr2Fe2CrO9-in Solid Oxide Fuel Cell Jacob M. Haag,a

    E-Print Network [OSTI]

    Poeppelmeier, Kenneth R.

    28, 2008. Ni­yttria stabilized zirconia YSZ cermets are commonly used in solid oxide fuel cell SOFCApplication of LaSr2Fe2CrO9- in Solid Oxide Fuel Cell Anodes Jacob M. Haag,a Brian D. Madsen composition LaSr2Fe2CrO9- was tested for application as an anode material for solid oxide fuel cells. Despite

  3. Low Phase-Noise 5 GHz AlGaN/GaN HEMT Oscillator Integrated with BaxSr1-xTiO3 Thin Films

    E-Print Network [OSTI]

    York, Robert A.

    Low Phase-Noise 5 GHz AlGaN/GaN HEMT Oscillator Integrated with BaxSr1-xTiO3 Thin Films Hongtao Xu -- A C-band MMIC oscillator in GaN HEMT technology with BaxSr1-xTiO3 (BST) film capacitors integrated with the common gate HEMT to generate negative resistance. The oscillator, based on AlGaN/GaN HEMT with 0.7um gate

  4. Quantum paraelectric glass state in SrCu{sub 3}Ti{sub 4}O{sub 12}

    SciTech Connect (OSTI)

    Kumar, Jitender; Choudhary, Ram Janay; Awasthi, A. M., E-mail: amawasthi@csr.res.in [UGC-DAE Consortium for Scientific Research, University Campus, Khandwa Road, Indore 452001 (India)

    2014-06-30T23:59:59.000Z

    Magnetic and dielectric studies of SrCu{sub 3}Ti{sub 4}O{sub 12} carried out over 5–300?K confirm antiferromagnetic (AFM) ordering of Cu-spins at T{sub N}?=?23?K. Dielectric constant ?? measured across 1?Hz-1 MHz signifies quantum paraelectric character, Barrett-fittable almost down to T{sub N}. Competition of athermal fluctuations and the literature-reported magneto-phonon-softening near T{sub N} manifest a quantum paraelectric glass (QPG) state. Emergent AFM-field tunes the otherwise quantum ordering (at absolute-zero) of the dipoles to finite-temperature kinetic glass transition; spectral dispersion of dielectric constant was unambiguously manifested and characterized. Vogel-Fulcher glass-kinetics parameterization sets the almost relaxation-free QPG state in SrCu{sub 3}Ti{sub 4}O{sub 12} apart from an emergent scaling-class, to which typical ferroelectric relaxors belong.

  5. New neutron capture and total cross section measurements on {sup 88}Sr and their impact on s-process nucleosynthesis

    SciTech Connect (OSTI)

    Koehler, P.E.; Spencer, R.R.; Guber, K.H. [and others

    1998-11-01T23:59:59.000Z

    The authors have made new and improved measurements of the neutron capture and total cross sections of {sup 88}Sr at the Oak Ridge Electron Linear Accelerator (ORELA). Improvements over previous measurements include a wider incident neutron energy range, the use of metallic rather than carbonate samples, better background subtraction, reduced sensitivity to sample-dependent backgrounds, and better pulse-height weighting functions. Because of its small cross section, the {sup 88}Sr(n,{gamma}) reaction is an important bottleneck during the s-process nucleosynthesis. Hence, an accurate determination of this rate is needed to better constrain the neutron exposure in s-process models and to more fully exploit the recently discovered isotopic anomalies in certain meteorites. They describe the experimental procedures, compare the results to previous data, and discuss their astrophysical impact.

  6. Neutron powder diffraction study of phase transitions in Sr{sub 2}SnO{sub 4}

    SciTech Connect (OSTI)

    Fu, W.T. [Leiden Institute of Chemistry, Gorlaeus Laboratories, Leiden University, P.O. Box 9502, 2300 RA Leiden (Netherlands)]. E-mail: w.fu@chem.leidenuniv.nl; Visser, D. [NWO-Physics, ISIS Facility, Rutherford Appleton Laboratory, Chilton, Didcot, OX11 0QX (United Kingdom); Knight, K.S. [ISIS Facility, Rutherford Appleton Laboratory, Chilton, Didcot, OX11 0QX (United Kingdom); IJdo, D.J.W. [Leiden Institute of Chemistry, Gorlaeus Laboratories, Leiden University, P.O. Box 9502, 2300 RA Leiden (Netherlands)

    2004-11-01T23:59:59.000Z

    The phase transitions in Sr{sub 2}SnO{sub 4} at high temperature have been studied using high resolution time-of-flight powder neutron diffraction. The room temperature structure of Sr{sub 2}SnO{sub 4} is orthorhombic (Pccn), which can be derived from the tetragonal K{sub 2}NiF{sub 4} structure by tilting the SnO{sub 6} octahedra along the tetragonal [100]{sub T}- and [010]{sub T}-axes with non-equal tilts. At the temperature of about 423K, it transforms to another orthorhombic structure (Bmab) characterized by the SnO{sub 6} octahedral tilt around the [110]{sub T}-axis. At still higher temperatures ({approx}573K) the structure was found to be tetragonal K{sub 2}NiF{sub 4}-type (I4/mmm)

  7. Interplay of point defects, biaxial strain, and thermal conductivity in homoepitaxial SrTiO{sub 3} thin films

    SciTech Connect (OSTI)

    Wiedigen, S.; Kramer, T.; Knorr, I.; Nee, N.; Hoffmann, J.; Volkert, C. A.; Jooss, Ch. [University of Goettingen, Institute of Materials Physics, Friedrich-Hund-Platz 1, 37077 Goettingen (Germany); Feuchter, M.; Kamlah, M. [Karlsruhe Institute of Technology, Institute for Applied Materials, Hermann-von-Helmholtz-Platz 1, 76344 Eggenstein-Leopoldshafen (Germany)

    2012-02-06T23:59:59.000Z

    Separating out effects of point defects and lattice strain on thermal conductivity is essential for improvement of thermoelectric properties of SrTiO{sub 3}. We study relations between defects generated during deposition, induced lattice strain, and their impact on thermal conductivity {kappa} in homoepitaxial SrTiO{sub 3} films prepared by ion-beam sputtering. Lowering the deposition temperature gives rise to lattice expansion by enhancement of point defect density which increases the hardness of the films. Due to a fully coherent substrate-film interface, the lattice misfit induces a large biaxial strain. However, we can show that the temperature dependence of {kappa} is mainly sensitive on the defect concentration.

  8. Role of oxygen vacancies in resistive switching in Pt/Nb-doped SrTiO{sub 3}

    SciTech Connect (OSTI)

    Park, Jinho; Kwon, Deok-Hwang; Park, Hongwoo; Kim, M., E-mail: mkim@snu.ac.kr [Research Institute of Advanced Materials, Department of Material Science and Engineering, Seoul National University, Seoul 151-744 (Korea, Republic of); Jung, C. U. [Department of Physics, Hankuk University of Foreign Studies, Yongin, Kyungki 449-791 (Korea, Republic of)

    2014-11-03T23:59:59.000Z

    Oxygen vacancies at the metal/oxide interface, driven by an electric field, have been considered responsible for the switching to the low-resistance state. We studied the electrical properties, along with microscopic observations, of the Pt/Nb-doped SrTiO{sub 3} (001) single-crystal system. Electron energy loss spectroscopy revealed highly accumulated oxygen vacancies at the interface in the high-resistance state, contrasting to common explanation. Higher resistance state by more oxygen vacancies was further confirmed in Pt/H{sub 2}-annealed SrTiO{sub 3}. These results suggest the presence of an interfacial state which dominantly determined the resistivity by changing the barrier height at the interface.

  9. 137Cs(90Sr) and Pu isotopes in the Pacific Ocean sources & trends

    SciTech Connect (OSTI)

    Hamilton, T.F., Millies-Lacrox, J.C. [Service Mixte de Securite Radologique, Mondhery (France); Hong, G.H. [Korea Ocean Research and Development Institute, Ansan (Korea)

    1996-11-01T23:59:59.000Z

    The main source of artificial radioactivity in the world`s oceans can be attributed to worldwide fallout from atmospheric nuclear weapons testing. Measurements of selected artificial radionuclides in the Pacific Ocean were first conducted in the 1960`s where it was observed that fallout radioactivity had penetrated the deep ocean. Extensive studies carried out during the 1973-74 GEOSECS provided the first comprehensive data on the lateral and vertical distributions of {sup 9O}Sr, {sup 137}Cs and Pu isotopes in the Pacific on a basin wide scale. Estimates of radionuclide inventories in excess of amounts predicted to be delivered by global fallout alone were attributed to close-in fallout and tropospheric inputs from early U.S. tests conducted on Bikini and Enewetak Atolls in the Equatorial Pacific. In general, levels of fallout radionuclides (including {sup 9O}Sr, {sup 137}Cs and Pu isotopes) in the surface waters of the Pacific Ocean have decreased considerably over the past 4 decades and are now much more homogeneously distributed. Resuspension and the subsequent deposition of fallout radionuclides from previously deposited debris on land has become an important source term for the surface ocean. This can be clearly seen in measurements of fallout radionuclides in mineral aerosols over the Korean Peninsula (Yellow dust events). Radionuclides may also be transported from land to sea in river runoff-these transport mechanisms are more important in the Pacific Ocean where large quantities of river water and suspended sands/fluvial sediments reach the coastal zone. Another unique source of artificial radionuclides in the Pacific Ocean is derived from the slow resolubilization and transport of radionuclides deposited in contaminated lagoon and slope sediments near U.S. and French test sites. Although there is a small but significant flux of artificial radionuclides depositing on the sea floor, > 80% of the total 239, {sup 240}Pu inventory and > 95% of the total {sup 137}Cs inventory remains in the water column. Studies conducted through the 1980`s appear to be consistent with earlier findings and indicate that radionuclide inventories in mid-northern latitudes are at least a factor of two above those expected from global fallout alone. The long term persistence of close-in and/or stratospheric fallout from nuclear weapons testing in the Marshall Islands still appears to be the only plausible explanation for this anomaly.

  10. ASSESSMENT OF 90SR AND 137CS PENETRATION INTO REINFORCED CONCRETE (EXTENT OF 'DEEPENING') UNDER NATURAL ATMOSPHERIC CONDITIONS

    SciTech Connect (OSTI)

    Farfan, E.; Jannik, T.

    2011-10-01T23:59:59.000Z

    When assessing the feasibility of remediation following the detonation of a radiological dispersion device or improvised nuclear device in a large city, several issues should be considered including the levels and characteristics of the radioactive contamination, the availability of resources required for decontamination, and the planned future use of the city's structures and buildings. Currently, little is known about radionuclide penetration into construction materials in an urban environment. Knowledge in this area would be useful when considering costs of a thorough decontamination of buildings, artificial structures, and roads in an affected urban environment. Pripyat, a city substantially contaminated by the Chernobyl Nuclear Power Plant accident in April 1986, may provide some answers. The main objective of this study was to assess the depth of {sup 90}Sr and {sup 137}Cs penetration into reinforced concrete structures in a highly contaminated urban environment under natural weather conditions. Thirteen reinforced concrete core samples were obtained from external surfaces of a contaminated building in Pripyat. The concrete cores were drilled to obtain sample layers of 0-5, 5-10, 10-15, 15-20, 20-30, 30-40, and 40-50 mm. Both {sup 90}Sr and {sup 137}Cs were detected in the entire 0-50 mm profile of the reinforced cores sampled. In most of the cores, over 90% of the total {sup 137}Cs inventory and 70% of the total {sup 90}Sr inventory was found in the first 0-5 mm layer of the reinforced concrete. {sup 90}Sr had penetrated markedly deeper into the reinforced concrete structures than {sup 137}Cs.

  11. A Theoretical Study on the Hydrogen Transport Mechanism in SrTiO3 Perovskite. II. Scandium

    E-Print Network [OSTI]

    Helgaker, Trygve

    at Titanium Site Taku Onishi*[a,b,c] and Trygve Helgaker[c] Hybrid Kohn­Sham calculations are performed at an oxygen site or a trivalent cation may be doped at a titanium site. In part I, we discussed nitro- gen-doping at an oxygen site in SrTiO3 perovskite. There are then two cases to consider. In one case, the doped nitrogen

  12. The role of strontium in the densification of Sr-zeolite-A to the low dielectric ceramic, anorthite

    SciTech Connect (OSTI)

    Parise, J.B.; Corbin, D.R.; Subramanian, M.A. (Du Pont de Nemours (E.I.) and Co., Wilmington, DE (USA). Central Research and Development Dept.)

    1989-03-01T23:59:59.000Z

    Analysis, using x-ray diffraction and Extended X-ray Absorption Fine Structure Spectroscopy (EXAFS), of the reconstructive transition from strontium exchanged zeolite type-A through amorphous intermediates to Sr-anorthite shows that, although long range order is lost, the environment around strontium remains essentially intact. EXAFS allows the authors to follow the mechanism of the solid state reaction which is dictated by the coordination requirements of strontium.

  13. Voltage-controlled ferromagnetism and magnetoresistance in LaCoO{sub 3}/SrTiO{sub 3} heterostructures

    SciTech Connect (OSTI)

    Hu, Chengqing; Park, Keun Woo; Yu, Edward T. [Microelectronics Research Center, The University of Texas at Austin, 10100 Burnet Rd., Austin, Texas 78758 (United States)] [Microelectronics Research Center, The University of Texas at Austin, 10100 Burnet Rd., Austin, Texas 78758 (United States); Posadas, Agham; Demkov, Alexander A. [Department of Physics, The University of Texas at Austin, 1 University Station C1600, Austin, Texas 78712 (United States)] [Department of Physics, The University of Texas at Austin, 1 University Station C1600, Austin, Texas 78712 (United States); Jordan-Sweet, Jean L. [IBM Thomas J. Watson Research Center, Yorktown Heights, New York 10598 (United States)] [IBM Thomas J. Watson Research Center, Yorktown Heights, New York 10598 (United States)

    2013-11-14T23:59:59.000Z

    A LaCoO{sub 3}/SrTiO{sub 3} heterostructure grown on Si (001) is shown to provide electrically switchable ferromagnetism, a large, electrically tunable magnetoresistance, and a vehicle for achieving and probing electrical control over ferromagnetic behavior at submicron dimensions. Fabrication of devices in a field-effect transistor geometry enables application of a gate bias voltage that modulates strain in the heterostructure via the converse piezoelectric effect in SrTiO{sub 3}, leading to an artificial inverse magnetoelectric effect arising from the dependence of ferromagnetism in the LaCoO{sub 3} layer on strain. Below the Curie temperature of the LaCoO{sub 3} layer, this effect leads to modulation of resistance in LaCoO{sub 3} as large as 100%, and magnetoresistance as high as 80%, both of which arise from carrier scattering at ferromagnetic-nonmagnetic interfaces in LaCoO{sub 3}. Finite-element numerical modeling of electric field distributions is used to explain the dependence of carrier transport behavior on gate contact geometry, and a Valet-Fert transport model enables determination of spin polarization in the LaCoO{sub 3} layer. Piezoresponse force microscopy is used to confirm the existence of piezoelectric response in SrTiO{sub 3} grown on Si (001). It is also shown that this structure offers the possibility of achieving exclusive-NOR logic functionality within a single device.

  14. Synthesis and crystallographic study of Pb-Sr hydroxyapatite solid solutions by high temperature mixing method under hydrothermal conditions

    SciTech Connect (OSTI)

    Zhu Kongjun, E-mail: kjzhu@nuaa.edu.cn [Aeronautical Key Laboratory for Smart Materials and Structures, Nanjing University of Aeronautics and Astronautics, Nanjing 210016 (China); Yanagisawa, Kazumichi [Research Laboratory of Hydrothermal Chemistry, Faculty of Science, Kochi University, Kochi-shi 780-8520 (Japan); Shimanouchi, Rie [Department of Material Science, Faculty of Science, Kochi University, Kochi-shi, 780-8520 (Japan); Onda, Ayumu; Kajiyoshi, Koji [Research Laboratory of Hydrothermal Chemistry, Faculty of Science, Kochi University, Kochi-shi 780-8520 (Japan); Qiu Jinhao [Aeronautical Key Laboratory for Smart Materials and Structures, Nanjing University of Aeronautics and Astronautics, Nanjing 210016 (China)

    2009-06-03T23:59:59.000Z

    The solid solutions in the system of Pb and Sr hydroxyapatite, Sr{sub 10-x}Pb{sub x}HAp (x = 0-10), were successfully synthesized by high-temperature mixing method (HTMM) at 160 deg. C for 12 h under hydrothermal conditions. The samples were characterized by X-ray diffraction, chemical analysis and electron microscopic observation, and the site of the metal ions in the solid solutions was analyzed with the Rietveld method. The lattice constants, both a and c, of the solid solutions varied linearly with Pb content. It was found that Pb ions in the solid solutions preferentially occupied the M(2) site in the apatite structure. HTMM gives Sr-Pb HAp solid solutions much better crystallization. However, due to the formation of intermediate compound of Pb{sub 3}O{sub 2}(OH){sub 2} in the Pb(NO{sub 3}){sub 2}.4H{sub 2}O solution before mixing with (NH{sub 4}){sub 2}HPO{sub 4} solution at 160 deg. C, HTMM causes the decrease of crystallization of the samples with high Pb content.

  15. Dependence of Electronic Structure of SrRuO3 and the Degree of Correlation on Cation Off-Stoichiometry

    SciTech Connect (OSTI)

    Siemons, W.

    2011-08-19T23:59:59.000Z

    We have grown and studied high quality SrRuO{sub 3} films grown by MBE as well as PLD. By changing the oxygen activity during deposition we were able to make SrRuO{sub 3} samples that were stoichiometric (low oxygen activity) or with ruthenium vacancies (high oxygen activity). Samples with strontium vacancies were found impossible to produce since the ruthenium would precipitate out as RuO{sub 2}. The volume of the unit cell of SrRuO{sub 3} becomes larger as more ruthenium vacancies are introduced. The residual resistivity ratio (RRR) and room temperature resistivity were found to systematically depend on the volume of the unit cell and therefore on the amount of ruthenium vacancies. The RRR varied from {approx}30 for stoichiometric samples to less than two for samples that were very ruthenium poor. The room temperature resistivity varied from 190 {micro}{Omega} cm for stoichoimetric samples to over 300 {micro}{Omega} cm for very ruthenium poor samples. UPS spectra show a shift of weight from the coherent peak to the incoherent peak around the Fermi level when samples have more ruthenium vacancies. Core level XPS spectra of the ruthenium 3d lines show a strong screened part in the case of stoichiometric samples. This screened part disappears when ruthenium vacancies are introduced. Both the UPS and the XPS results are consistent with the view that correlation increases as the amount of ruthenium vacancies increase.

  16. Inter-staple Dithiol Crosslinking in Au25(SR)18 Nanomolecules: A Combined Mass Spectrometric and Computational Study

    SciTech Connect (OSTI)

    Dass, Amala [University of Mississippi, The; Jiang, Deen [ORNL; Jupally, Vijay [University of Mississippi, The; Kota, Rajesh [University of Mississippi, The; Mattern, Daniell [University of Mississippi, The; Tschumper, Gregory [University of Mississippi, The; Van Dornshuld, Eric [University of Mississippi, The

    2011-01-01T23:59:59.000Z

    A systematic study of cross-linking chemistry of the Au{sub 25}(SR){sub 18} nanomolecule by dithiols of varying chain length, HS-(CH{sub 2}){sub n}-SH where n = 2, 3, 4, 5, and 6, is presented here. Monothiolated Au{sub 25} has six [RSAuSRAuSR] staple motifs on its surface, and MALDI mass spectrometry data of the ligand exchanged clusters show that propane (C3) and butane (C4) dithiols have ideal chain lengths for interstaple cross-linking and that up to six C3 or C4 dithiols can be facilely exchanged onto the cluster surface. Propanedithiol predominately exchanges with two monothiols at a time, making cross-linking bridges, while butanedithiol can exchange with either one or two monothiols at a time. The extent of cross-linking can be controlled by the Au{sub 25}(SR){sub 18} to dithiol ratio, the reaction time of ligand exchange, or the addition of a hydrophobic tail to the dithiol. MALDI MS suggests that during ethane (C2) dithiol exchange, two ethanedithiols become connected by a disulfide bond; this result is supported by density functional theory (DFT) prediction of the optimal chain length for the intrastaple coupling. Both optical absorption spectroscopy and DFT computations show that the electronic structure of the Au{sub 25} nanomolecule retains its main features after exchange of up to eight monothiol ligands.

  17. Interstaple Dithiol Cross-Linking in Au(25)(SR)(18) Nanomolecules: A Combined Mass Spectrometric and Computational Study

    SciTech Connect (OSTI)

    Jiang, Deen [ORNL; Dass, Amala [University of Mississippi, The; Tschumper, Gregory [University of Mississippi, The; Mattern, Daniell [University of Mississippi, The; Van Dornshuld, Eric [University of Mississippi, The; Kota, Rajesh [University of Mississippi, The; Jupally, Vijay [University of Mississippi, The

    2011-01-01T23:59:59.000Z

    A systematic study of cross-linking chemistry of the Au{sub 25}(SR){sub 18} nanomolecule by dithiols of varying chain length, HS-(CH2)n-SH where n = 2, 3, 4, 5, and 6, is presented here. Monothiolated Au{sub 25} has six [RSAuSRAuSR] staple motifs on its surface, and MALDI mass spectrometry data of the ligand exchanged clusters show that propane (C3) and butane (C4) dithiols have ideal chain lengths for interstaple cross-linking and that up to six C3 or C4 dithiols can be facilely exchanged onto the cluster surface. Propanedithiol predominately exchanges with two monothiols at a time, making cross-linking bridges, while butanedithiol can exchange with either one or two monothiols at a time. The extent of cross-linking can be controlled by the Au{sub 25}(SR){sub 18} to dithiol ratio, the reaction time of ligand exchange, or the addition of a hydrophobic tail to the dithiol. MALDI MS suggests that during ethane (C2) dithiol exchange, two ethanedithiols become connected by a disulfide bond; this result is supported by density functional theory (DFT) prediction of the optimal chain length for the intrastaple coupling. Both optical absorption spectroscopy and DFT computations show that the electronic structure of the Au{sub 25} nanomolecule retains its main features after exchange of up to eight monothiol ligands.

  18. Characterization and Application of Superlig 620 Solid Phase Extraction Resin for Automated Process Monitoring of 90Sr

    SciTech Connect (OSTI)

    Devol, Timothy A.; Clements, John P.; Farawila, Anne F.; O'Hara, Matthew J.; Egorov, Oleg; Grate, Jay W.

    2009-11-30T23:59:59.000Z

    Characterization of SuperLig® 620 solid phase extraction resin was performed in order to develop an automated on-line process monitor for 90Sr. The main focus was on strontium separation from barium, with the goal of developing an automated separation process for 90Sr in high-level wastes. High-level waste contains significant 137Cs activity, of which 137mBa is of great concern as an interference to the quantification of strontium. In addition barium, yttrium and plutonium were studied as potential interferences to strontium uptake and detection. A number of complexants were studied in a series of batch Kd experiments, as SuperLig® 620 was not previously known to elute strontium in typical mineral acids. The optimal separation was found using a 2M nitric acid load solution with a strontium elution step of ~0.49M ammonium citrate and a barium elution step of ~1.8M ammonium citrate. 90Sr quantification of Hanford high-level tank waste was performed on a sequential injection analysis microfluidics system coupled to a flow-cell detector. The results of the on-line procedure are compared to standard radiochemical techniques in this paper.

  19. Structures and self-activating photoluminescent properties of Sr{sub 3-x}A{sub x}GaO{sub 4}F (A=Ba, Ca) materials

    SciTech Connect (OSTI)

    Green, Robert [Nanocenter and Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC 29208 (United States)] [Nanocenter and Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC 29208 (United States); Vogt, Thomas, E-mail: tvogt@mailbox.sc.edu [Nanocenter and Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC 29208 (United States)] [Nanocenter and Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC 29208 (United States)

    2012-10-15T23:59:59.000Z

    The synthesis, structures and photoluminescent properties of mixed oxyfluorides of the type Sr{sub 3-x}A{sub x}GaO{sub 4}F are compared to Sr{sub 3-x}A{sub x}AlO{sub 4}F (A=Ca, Ba) materials. In these compounds the F{sup -} and O{sup 2-} ions are ordered and located on two distinct crystallographic sites. When substituting Sr{sup 2+} by Ba{sup 2+} and Ca{sup 2+}, we find in Sr{sub 3-x}A{sub x}GaO{sub 4}F materials an ordering of the alkaline earth cations over the two crystallographic sites. The amount of Ba{sup 2+} ions that can be substituted into Sr{sub 3-x}A{sub x}GaO{sub 4}F is x{<=}1.2, which is slightly more than can be incorporated into the previously reported Al-analog Sr{sub 3-x}A{sub x}AlO{sub 4}F (x=1.0). Conversely, the amount of Ca{sup 2+} ions that can be substituted into Sr{sub 3-x}Ca{sub x}GaO{sub 4}F (x=0.3) is significantly less than in Sr{sub 3-x}Ca{sub x}AlO{sub 4}F (x=1.0). A post-synthesis reduction step causes these materials to exhibit self-activating broad band photoluminescence where the emitted colors vary with the amount of ions substituted into the host lattice. - Graphical abstract: TOC Statement The structures of the self-activating phosphors Sr{sub 3-x}A{sub x}MO{sub 4}F (A=Ba, Ca and M=Al, Ga) can be rationalized as alternating layers of bond compression and elongation, which impact the photoluminescence. Highlights: Black-Right-Pointing-Pointer Comparison of the structural changes in Sr{sub 3-x}A{sub x}AlO{sub 4}F and Sr{sub 3-x}A{sub x}GaO{sub 4}F (A=Ba, Ca) and its influence on the photoluminescence of these self-activating phosphors. Black-Right-Pointing-Pointer Analysis of the Global Instability Index of the Sr{sub 3-x}A{sub x}AlO{sub 4}F and Sr{sub 3-x}A{sub x}GaO{sub 4}F (A=Ba, Ca). Black-Right-Pointing-Pointer Comparison of the photoluminescence between the self-activating phosphors Sr{sub 3-x}A{sub x}AlO{sub 4}F and Sr{sub 3-x}A{sub x}GaO{sub 4}F (A=Ba, Ca).

  20. Isotope shifts of natural Sr+ measured by laser fluorescence in a sympathetically cooled Coulomb crystal

    E-Print Network [OSTI]

    Brice Dubost; Romain Dubessy; Benjamin Szymanski; Samuel Guibal; Jean-Pierre Likforman; Luca Guidoni

    2014-02-14T23:59:59.000Z

    We measured by laser spectroscopy the isotope shifts between naturally-occurring even-isotopes of strontium ions for both the $5s\\,\\,^2S_{1/2}\\to 5p\\,\\,^2P_{1/2}$ (violet) and the $4d\\,\\,^2D_{3/2}\\to 5p\\,\\,^2P_{1/2}$ (infrared) dipole-allowed optical transitions. Fluorescence spectra were taken by simultaneous measurements on a two-component Coulomb crystal in a linear Paul trap containing $10^3$--$10^4$ laser-cooled Sr$^+$ ions. The isotope shifts are extracted from the experimental spectra by fitting the data with the analytical solution of the optical Bloch equations describing a three-level atom in interaction with two laser beams. This technique allowed us to increase the precision with respect to previously reported data obtained by optogalvanic spectroscopy or fast atomic-beam techniques. The results for the $5s\\,\\,^2S_{1/2}\\to 5p\\,\\,^2P_{1/2}$ transition are $\

  1. Two charged states of hydrogen on the SrTiO{sub 3}(001) surface

    SciTech Connect (OSTI)

    Takeyasu, Kotaro, E-mail: takeyasu@iis.u-tokyo.ac.jp; Fukada, Keisuke; Ogura, Shohei; Matsumoto, Masuaki; Fukutani, Katsuyuki, E-mail: fukutani@iis.u-tokyo.ac.jp [Institute of Industrial Science, The University of Tokyo, 4-6-1 Komaba, Meguro-ku, Tokyo 153–8505 (Japan)] [Institute of Industrial Science, The University of Tokyo, 4-6-1 Komaba, Meguro-ku, Tokyo 153–8505 (Japan)

    2014-02-28T23:59:59.000Z

    The effects of hydrogen exposure on the electronic structure of two types of SrTiO{sub 3}(001) surfaces, oxygen-deficient (OD) and nearly-vacancy-free (NVF) surfaces, were investigated with ultraviolet photoemission spectroscopy and nuclear reaction analysis. Upon molecular hydrogen exposure to the OD surface which reveals in-gap states at 1.3 eV below the Fermi level, the in-gap state intensity was reduced to half the initial value at a hydrogen coverage of 0.9 ± 0.7 × 10{sup 14} cm{sup ?2}. On the NVF surface which has no in-gap state, on the other hand, atomic-hydrogen exposure induced in-gap states, and the hydrogen saturation coverage was evaluated to be 3.1 ± 0.8 × 10{sup 14} cm{sup ?2}. We argue that H is positively charged as H{sup ?0.3+} on the NVF surface by being coordinated to the O atom, whereas H is negatively charged as H{sup ?} on the OD surface by occupying the oxygen vacancy site. The stability of H{sup ?} at the oxygen vacancy site is discussed.

  2. Crystal structure and magnetic properties and Zn substitution effects on the spin-chain compound Sr{sub 3}Co{sub 2}O{sub 6}

    SciTech Connect (OSTI)

    Wang, Xia [Superconducting Properties Unit, National Institute for Materials Science, 1-1 Namiki, Tsukuba Ibaraki 305-0044 (Japan); Department of Chemistry, Graduate School of Science, Hokkaido University, Sapporo, Hokkaido 060-0810 (Japan); Guo, Yanfeng, E-mail: Yangfeng.Guo@physics.ox.ac.uk [Superconducting Properties Unit, National Institute for Materials Science, 1-1 Namiki, Tsukuba Ibaraki 305-0044 (Japan); Sun, Ying [International Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science, 1-1 Namiki, Tsukuba Ibaraki 305-0044 (Japan); Tsujimoto, Yoshihiro [Materials Processing Unit, National Institute for Materials Science, 1-2-1 Sengen, Tsukuba Ibaraki 305-0047 (Japan); Matsushita, Yoshitaka [Materials Analysis Station, National Institute for Materials Science, 1-2-1 Sengen, Tsukuba Ibaraki 305-0047 (Japan); Yamaura, Kazunari, E-mail: yamaura.kazunari@nims.go.jp [Superconducting Properties Unit, National Institute for Materials Science, 1-1 Namiki, Tsukuba Ibaraki 305-0044 (Japan); Department of Chemistry, Graduate School of Science, Hokkaido University, Sapporo, Hokkaido 060-0810 (Japan)

    2013-08-15T23:59:59.000Z

    The effects of substituting Co on the spin-chain compound Sr{sub 3}Co{sub 2}O{sub 6} with Zn were investigated by synchrotron X-ray diffraction, magnetic susceptibility, isothermal magnetization, and specific heat measurements. To the best of our knowledge, this is the first report to describe the successful substitution of Co in Sr{sub 3}Co{sub 2}O{sub 6} with Zn. The substitution was carried out by a method involving high pressures and temperatures to obtain Sr{sub 3}CoZnO{sub 6}, which crystalized into a K{sub 4}CdCl{sub 6}-derived rhombohedral structure with a space group of R-3c, similar to the host compound. With the Zn substitution, the Ising-type magnetic anisotropy of the host compound remarkably reduced; the newly formed Sr{sub 3}CoZnO{sub 6} became magnetically isotropic with Heisenberg-type characteristics. This could probably be ascribed to the establishment of a different interaction pathway, –Co{sup 4+}(S=1/2)–O–Zn{sup 2+}(S=0)–O–Co{sup 4+}(S=1/2)–. Details of the magnetic properties of Zn substituted Sr{sub 3}Co{sub 2}O{sub 6} were reported. - Graphical abstract: Crystal structure of the spin-chain compound Sr{sub 3}CoZnO{sub 6} synthesized at 6 GPa. Zn atoms preferably occupy the trigonal prism sites rather than the octahedral sites. As a result, the compound is much magnetically isotropic. Highlights: • Effects of substituting Co with Zn on spin-chain magnetism of Sr{sub 3}Co{sub 2}O{sub 6} were studied. • High-pressure synthesis resulted in a solid solution of Sr{sub 3}CoZnO{sub 6}. • Sr{sub 3}CoZnO{sub 6} showed more isotropic magnetism than the host Sr{sub 3}Co{sub 2}O{sub 6}.

  3. Bridgman Growth of Large SrI2:Eu2+ Single Crystals: A High-performance Scintillator for Radiation Detection Applications

    SciTech Connect (OSTI)

    Boatner, Lynn A [ORNL; Ramey, Joanne Oxendine [ORNL; Kolopus, James A [ORNL; Hawrami, Rastgo [Radiation Monitoring Devices, Watertown, MA; Higgins, William [Radiation Monitoring Devices, Watertown, MA; Van Loef, Edgar [Radiation Monitoring Devices, Watertown, MA; Glodo, J. [Radiation Monitoring Devices, Watertown, MA; Shah, Kanai [Radiation Monitoring Devices, Watertown, MA; Bhattacharya, P. [Fisk University, Nashville, TN; Tupitsyn, E [Fisk University, Nashville, TN; Groza, Michael [Fisk University, Nashville, TN; Burger, Arnold [Fisk University, Nashville, TN

    2013-01-01T23:59:59.000Z

    Single-crystal strontium iodide (SrI2) doped with relatively high levels (e.g., 3 - 6 %) of Eu2+ exhibits characteristics that make this material superior, in a number of respects, to other scintillators that are currently used for radiation detection. Specifically, SrI2:Eu2+ has a light yield that is significantly higher than LaBr3:Ce3+ -a currently employed commercial high-performance scintillator. Additionally, SrI2:Eu2+ is characterized by an energy resolution as high as 2.6% at the 137Cs gamma-ray energy of 662 keV, and there is no radioactive component in SrI2:Eu2+ - unlike LaBr3:Ce3+ that contains 138La. The Ce3+-doped LaBr3 decay time is, however, faster (30 nsec) than the 1.2 sec decay time of SrI2:Eu2+. Due to the relatively low melting point of strontium iodide (~515 oC), crystal growth can be carried out in quartz crucibles by the vertical Bridgman technique. Materials-processing and crystal-growth techniques that are specific to the Bridgman growth of europium-doped strontium iodide scintillators are described here. These techniques include the use of a porous quartz frit to physically filter the molten salt from a quartz antechamber into the Bridgman growth crucible and the use of a bent or bulb grain selector design to suppress multiple grain growth. Single crystals of SrI2:Eu2+ scintillators with good optical quality and scintillation characteristics have been grown in sizes up to 5.0 cm in diameter by applying these techniques. Other aspects of the SrI2:Eu2+ crystal-growth methods and of the still unresolved crystal-growth issues are described here.

  4. Spin-orbit tuned metal-insulator transitions in single-crystal Sr?Ir1–xRhxO? (0?x?1)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Qi, T. F.; Korneta, O. B.; Li, L.; Butrouna, K.; Cao, V. S.; Wan, Xiangang; Schlottmann, P.; Kaul, R. K.; Cao, G.

    2012-09-01T23:59:59.000Z

    Sr?IrO? is a magnetic insulator driven by spin-orbit interaction (SOI) whereas the isoelectronic and isostructural Sr?RhO? is a paramagnetic metal. The contrasting ground states have been shown to result from the critical role of the strong SOI in the iridate. Our investigation of structural, transport, magnetic, and thermal properties reveals that substituting 4d Rh?? (4d?) ions for 5d Ir?? (5d?) ions in Sr?IrO? directly reduces the SOI and rebalances the competing energies so profoundly that it generates a rich phase diagram for Sr?Ir1–xRhxO? featuring two major effects: (1) Light Rh doping (0 ? x ? 0.16) prompts a simultaneous and precipitous drop in both the electrical resistivity and the magnetic ordering temperature TC, which is suppressed to zero at x = 0.16 from 240 K at x = 0. (2) However, with heavier Rh doping [0.24 1–xRhxO? is further highlighted by comparison with Sr?Ir1–xRuxO? where Ru?? (4d?) drives a direct crossover from the insulating to metallic states.

  5. Interfacial mode coupling as the origin of the enhancement of Tc in FeSe films on SrTiO3

    SciTech Connect (OSTI)

    Lee, J.J.; Schmitt, F.T.; Moore, R.G.; Johnston, S.; Cui, Y.-T.; Li, W.; Yi, M.; Liu, Z.K.; Hashimoto, M.; Zhang, Y.; Lu, D.H.; Devereaux, T.P.; Lee, D.-H.; Shen, Z.-X.

    2014-11-12T23:59:59.000Z

    Films of iron selenide (FeSe) one unit cell thick grown on strontium titanate (SrTiO3 or STO) substrates have recently shown superconducting energy gaps opening at temperatures close to the boiling point of liquid nitrogen (77 K), which is a record for the iron-based superconductors. The gap opening temperature usually sets the superconducting transition temperature Tc, as the gap signals the formation of Cooper pairs, the bound electron states responsible for superconductivity. To understand why Cooper pairs form at such high temperatures, we examine the role of the SrTiO3 substrate. Here we report high-resolution angle-resolved photoemission spectroscopy results that reveal an unexpected characteristic of the single-unit-cell FeSe/SrTiO3 system: shake-off bands suggesting the presence of bosonic modes, most probably oxygen optical phonons in SrTiO3, which couple to the FeSe electrons with only a small momentum transfer. Such interfacial coupling assists superconductivity in most channels, including those mediated by spin fluctuations. Our calculations suggest that this coupling is responsible for raising the superconducting gap opening temperature in single-unit-cell FeSe/SrTiO3.

  6. Syntheses, crystal structures and optical properties of the first strontium selenium(IV) and tellurium(IV) oxychlorides: Sr{sub 3}(SeO{sub 3})(Se{sub 2}O{sub 5})Cl{sub 2} and Sr{sub 4}(Te{sub 3}O{sub 8})Cl{sub 4}

    SciTech Connect (OSTI)

    Jiang Hailong [State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002 (China); Graduate School of the Chinese Academy of Sciences, Beijing 100039 (China); Mao Jianggao [State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002 (China)], E-mail: mjg@fjirsm.ac.cn

    2008-02-15T23:59:59.000Z

    Two new quaternary strontium selenium(IV) and tellurium(IV) oxychlorides, namely, Sr{sub 3}(SeO{sub 3})(Se{sub 2}O{sub 5})Cl{sub 2} and Sr{sub 4}(Te{sub 3}O{sub 8})Cl{sub 4}, have been prepared by solid-state reaction. Sr{sub 3}(SeO{sub 3})(Se{sub 2}O{sub 5})Cl{sub 2} features a three-dimensional (3D) network structure constructed from strontium(II) interconnected by Cl{sup -}, SeO{sub 3}{sup 2-} as well as Se{sub 2}O{sub 5}{sup 2-} anions. The structure of Sr{sub 4}(Te{sub 3}O{sub 8})Cl{sub 4} features a 3D network in which the strontium tellurium oxide slabs are interconnected by bridging Cl{sup -} anions. The diffuse reflectance spectrum measurements and results of the electronic band structure calculations indicate that both compounds are wide band-gap semiconductors. - Graphical abstract: Solid-state reactions of SrO, SrCl{sub 2}, and SeO{sub 2} or TeO{sub 2} in different molar ratios and under different temperatures lead to two new strontium selenium(IV) or tellurium(IV) oxychlorides with two different types of structures, namely, Sr{sub 3}(SeO{sub 3})(Se{sub 2}O{sub 5})Cl{sub 2} and Sr{sub 4}(Te{sub 3}O{sub 8})Cl{sub 4}. Both compounds are wide band-gap semiconductors based on the diffuse reflectance spectra and the electronic band structures.

  7. (Sr,Ba)(Si,Ge){sub 2} for thin-film solar-cell applications: First-principles study

    SciTech Connect (OSTI)

    Kumar, Mukesh, E-mail: Kumar.Mukesh@nims.go.jp, E-mail: mkgarg79@gmail.com [Environmental Remediation Materials Unit, National Institute for Materials Science, Ibaraki 305-0044 (Japan); Umezawa, Naoto [Environmental Remediation Materials Unit, National Institute for Materials Science, Ibaraki 305-0044 (Japan); PRESTO, Japan Science and Technology Agency (JST), 4-1-8 Honcho Kawaguchi, Saitama 332-0012 (Japan); TU-NIMS Joint Research Center, School of Materials Science and Engineering, Tianjin University, 92 Weijin Road, Nankai District, Tianjin (China); Imai, Motoharu [Superconducting Properties Unit, National Institute for Materials Science, Ibaraki 305-0047 (Japan)

    2014-05-28T23:59:59.000Z

    In order to meet the increasing demand for electric power generation from solar energy conversion, the development of efficient light absorber materials has been awaited. To this end, the electronic and optical properties of advanced alkaline-earth-metals disilicides and digermanides (SrSi{sub 2}, BaSi{sub 2}, SrGe{sub 2}, and BaGe{sub 2}) are studied by means of the density functional theory using HSE06 exchange-correlation energy functional. Our calculations show that all these orthorhombic structured compounds have fundamental indirect band gaps in the range E{sub g} ? 0.89–1.25 eV, which is suitable for solar cell applications. The estimated lattice parameters and band gaps are in good agreement with experiments. Our calculations show that the electronic band structures of all four compounds are very similar except in the vicinity of the ?-point. The valence band of these compounds is made up by Si(Ge)-p states, whereas the conduction band is composed of Sr(Ba)-d states. Their band alignments are carefully determined by estimating the work function of each compound using slab model. The optical properties are discussed in terms of the complex dielectric function ?(?)?=??{sub 1}(?)?+?i?{sub 2}(?). The static and high-frequency dielectric constants are calculated, taking into account the ionic contribution. The absorption coefficient ?(?) demonstrates that a low energy dispersion of the conduction band, which results in a flat conduction band minimum, leads to large optical activity in these compounds. Therefore, alkaline-earth-metals disilicides and digermanides possess great potential as light absorbers for applications in thin-film solar cell technologies.

  8. Manipulation of subsurface carbon nanoparticles in Bi?Sr?CaCu?O8+? using a scanning tunneling microscope

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Stollenwerk, A. J.; Gu, G.; Hurley, N.; Beck, B.; Spurgeon, K.; Kidd, T. E.

    2015-03-01T23:59:59.000Z

    We present evidence that subsurface carbon nanoparticles in Bi?Sr?CaCu?O8+? can be manipulated with nanometer precision using a scanning tunneling microscope. High resolution images indicate that most of the carbon particles remain subsurface after transport observable as a local increase in height as the particle pushes up on the surface. Tunneling spectra in the vicinity of these protrusions exhibit semiconducting characteristics with a band gap of approximately 1.8 eV, indicating that the incorporation of carbon locally alters the electronic properties near the surface.

  9. Resistive switching in ultra-thin La{sub 0.7}Sr{sub 0.3}MnO{sub 3}/SrRuO{sub 3} superlattices

    SciTech Connect (OSTI)

    Jammalamadaka, S. Narayana, E-mail: surya@iith.ac.in [INPAC—Institute for Nanoscale Physics and Chemistry, K.U. Leuven, Celestijnenlaan 200D, B–3001 Leuven (Belgium); Magnetic Materials and Device Physics Laboratory, Department of Physics, Indian Institute of Technology Hyderabad, Hyderabad, Telangana 502 205 (India); Vanacken, Johan; Moshchalkov, V. V. [INPAC—Institute for Nanoscale Physics and Chemistry, K.U. Leuven, Celestijnenlaan 200D, B–3001 Leuven (Belgium)

    2014-07-21T23:59:59.000Z

    Superlattices may play an important role in next generation electronic and spintronic devices if the key-challenge of the reading and writing data can be solved. This challenge emerges from the coupling of low dimensional individual layers with macroscopic world. Here, we report the study of the resistive switching characteristics of a hybrid structure made out of a superlattice with ultrathin layers of two ferromagnetic metallic oxides, La{sub 0.7}Sr{sub 0.3}MnO{sub 3} (LSMO) and SrRuO{sub 3} (SRO). Bipolar resistive switching memory effects are measured on these LSMO/SRO superlattices, and the observed switching is explainable by ohmic and space charge-limited conduction laws. It is evident from the endurance characteristics that the on/off memory window of the cell is greater than 14, which indicates that this cell can reliably distinguish the stored information between high and low resistance states. The findings may pave a way to the construction of devices based on nonvolatile resistive memory effects.

  10. Test plan for composting studies involving weight and volume reduction of leaf and stalk biomass: DOE/OTD TTP{number_sign} SR17SS53 {ampersand} TTP{number_sign} SR18SS41

    SciTech Connect (OSTI)

    Wilde, E.W.; Kastner, J.; Murphy, C.; Santo Domingo, J.

    1997-05-28T23:59:59.000Z

    SRTC and a panel of experts from off-site previously determined that composting was the most attractive alternative for reducing the volume and weight of biomass that was slightly radioactive. The SRTC proposed scope of work for Subtask 2 of TTP{number_sign} SR17SS53 and TTP{number_sign} SR18SS41 involves bench scale studies to assess the rates and efficiencies of various composting schemes for volume and weight reduction of leaf and stalk biomass (SB). Ultimately, the data will be used to design a composting process for biomass proposed by MSE for phytoremediation studies at SRS. This could drastically reduce costs for transporting and disposing of contaminated biomass resulting from a future major phytoremediation effort for soil clean-up at the site. The composting studies at SRTC includes collaboration with personnel from the University of Georgia, who will conduct chemical analyses of the plant material after harvest, pre-treatment, and composting for specific time periods. Parameters to be measured will include: lignin, hemicellulose, cellulose, carbon and nitrogen. The overall objective of this project is to identify or develop: (1) an inexpensive source of inoculum (consisting of nutrients and/or microorganisms) capable of significantly enhancing biomass degradation, (2) an optimum range of operating parameters for the composting process, and (3) a process design for the solid state degradation of lignocellulosic biomass contaminated with radionuclides that is superior to existing alternatives for dealing with such waste.

  11. Role of phonon scattering by elastic strain field in thermoelectric Sr{sub 1?x}Y{sub x}TiO{sub 3??}

    SciTech Connect (OSTI)

    Bhattacharya, S., E-mail: bbhatta@clemson.edu, E-mail: ttritt@clemson.edu [Department of Physics and Astronomy, Clemson University, Clemson, South Carolina 29634 (United States); Mehdizadeh Dehkordi, A. [Department of Materials Science and Engineering, Clemson University, Clemson, South Carolina 29634 (United States); Tennakoon, S.; Adebisi, R.; Gladden, J. R. [Department of Physics and National Center for Physical Acoustics, University of Mississippi, University, Mississippi 38677 (United States); Darroudi, T. [Electron Microscope Facility, Clemson Research Park, Clemson University, Clemson, South Carolina 29625 (United States); Alshareef, H. N. [Materials Science and Engineering, King Abdullah University of Science and Technology (KAUST), Thuwal 23955-6900 (Saudi Arabia); Tritt, T. M., E-mail: bbhatta@clemson.edu, E-mail: ttritt@clemson.edu [Department of Physics and Astronomy, Clemson University, Clemson, South Carolina 29634 (United States); Department of Materials Science and Engineering, Clemson University, Clemson, South Carolina 29634 (United States)

    2014-06-14T23:59:59.000Z

    Perovskite-type SrTiO{sub 3??} ceramics are multifunctional materials with significant potential as n-type thermoelectric (TE) materials. The electronic and thermal transport properties of spark plasma sintered polycrystalline Sr{sub 1?x}Y{sub x}TiO{sub 3??} (x?=?0.05, 0.075, 0.1) ceramics are systematically investigated from (15–800) K. The Sr{sub 0.9}Y{sub 0.1}TiO{sub 3??} simultaneously exhibits a large Seebeck coefficient, ??>??80??V/K and moderately high electrical resistivity, ????0.8?m?-cm at a carrier concentration of ?10{sup 21}?cm{sup ?3} at 300?K resulting in a high TE power factor defined herein as (?{sup 2}?T)???0.84?W/m-K at 760?K. Despite the similar atomic masses of Sr (87.6?g/mol) and Y (88.9?g/mol), the lattice thermal conductivity (?{sub L}) of Sr{sub 1?x}Y{sub x}TiO{sub 3??} is significantly reduced with increased Y-doping, owing to the smaller ionic radii of Y{sup 3+} (?1.23?Å, coordination number 12) compared to Sr{sup 2+} (?1.44?Å, coordination number 12) ions. In order to understand the thermal conductivity reduction mechanism, the ?{sub L} in the Sr{sub 1?x}Y{sub x}TiO{sub 3??} series are phenomenologically modeled with a modified Callaway's equation from 30–600?K. Phonon scattering by elastic strain field due to ionic radii mismatch is found to be the prominent scattering mechanism in reducing ?{sub L} of these materials. In addition, the effect of Y-doping on the elastic moduli of Sr{sub 1?x}Y{sub x}TiO{sub 3??} (x?=?0, 0.1) is investigated using resonant ultrasound spectroscopy, which exhibits an anomaly in x?=?0.1 in the temperature range 300–600?K. As a result, the phonon mean free path is found to be further reduced in the Sr{sub 0.9}Y{sub 0.1}TiO{sub 3??} compared to that of SrTiO{sub 3??}, resulting in a considerably low thermal conductivity ????2.7?W/m-K at 760?K. Finally, we report a thermoelectric figure of merit (ZT)???0.3 at 760?K in the Sr{sub 0.9}Y{sub 0.1}TiO{sub 3??}, the highest ZT value reported in the Y-doped SrTiO{sub 3} ceramics thus far.

  12. Modulation of conductance and superconductivity by top-gating in LaAlO{sub 3}/SrTiO{sub 3} 2-dimensional electron systems

    SciTech Connect (OSTI)

    Eerkes, P. D.; Wiel, W. G. van der; Hilgenkamp, H. [MESA Institute for Nanotechnology, University of Twente, P.O. Box 217, 7500 AE Enschede (Netherlands)] [MESA Institute for Nanotechnology, University of Twente, P.O. Box 217, 7500 AE Enschede (Netherlands)

    2013-11-11T23:59:59.000Z

    We report the electrical top-gating of a 2-dimensional electron gas (2DEG) formed at the LaAlO{sub 3}/SrTiO{sub 3} interface, using electron-beam evaporated Au gate electrodes. In these structures, epitaxial LaAlO{sub 3} films grown by pulsed laser deposition induce the 2DEGs at the interface to the SrTiO{sub 3} substrate and simultaneously act as the gate dielectric. The structured top-gates enable a local tuning and complete on/off switching of the interface (super-)conductivity, while maintaining the usual, intrinsic characteristics for these LaAlO{sub 3}/SrTiO{sub 3} interfaces when no gate voltage is applied.

  13. Hysteretic electrical transport in BaTiO{sub 3}/Ba{sub 1?x}Sr{sub x}TiO{sub 3}/Ge heterostructures

    SciTech Connect (OSTI)

    Ngai, J. H.; Kumah, D. P.; Walker, F. J. [Department of Applied Physics and Center for Research on Interface Structures and Phenomena, Yale University, 15 Prospect Street, New Haven, Connecticut 06520-8284 (United States); Ahn, C. H. [Department of Applied Physics and Center for Research on Interface Structures and Phenomena, Yale University, 15 Prospect Street, New Haven, Connecticut 06520-8284 (United States); Department of Mechanical Engineering and Materials Science, Yale University, 10 Hillhouse Avenue, New Haven, Connecticut 06520-8267 (United States)

    2014-02-10T23:59:59.000Z

    We present electrical transport measurements of heterostructures comprised of BaTiO{sub 3} and Ba{sub 1?x}Sr{sub x}TiO{sub 3} epitaxially grown on Ge. Sr alloying imparts compressive strain to the BaTiO{sub 3}, which enables the thermal expansion mismatch between BaTiO{sub 3} and Ge to be overcome to achieve c-axis oriented growth. The conduction bands of BaTiO{sub 3} and Ba{sub 1?x}Sr{sub x}TiO{sub 3} are nearly aligned with the conduction band of Ge, which facilitates electron transport. Electrical transport measurements through the dielectric stack exhibit rectifying behavior and hysteresis, where the latter is consistent with ferroelectric switching.

  14. Obtaining Mixed Ionic/Electronic Conductivity in Perovskite Oxides in a Reducing Environment: A Computational Prediction for Doped SrTiO3

    SciTech Connect (OSTI)

    Suthirakun, Suwit; Ammal, Salai Cheettu; Xiao, Guoliang; Chen, Fanglin; Huang, Kevin; zur Loye, Hans-Conrad; Heyden, Andreas

    2012-11-30T23:59:59.000Z

    The electronic conductivity and thermodynamic stability of mixed p- and n-doped SrTiO3 perovskites have been investigated under anodic solid oxide fuel cell conditions using density functional theory (DFT). In particular, constrained ab initio thermodynamic calculations have been performed to evaluate the phase stability of various Ga- and La-doped SrTiO3 at synthesized and anodic SOFC conditions. The density of states (DOS) of these materials was analyzed to determine the number of charge carriers and the degree of electronic conductivity. We find that a mixed ionic/electronic conductor can be obtained when doping SrTiO3 perovskite oxide with both p-type and n-type dopants. Calculations show that 10% Ga- and 20% La-doped SrTiO3 exhibit mixed ionic/electronic conductivity at high temperature and low oxygen partial pressure whereas doping with higher concentrations of Ga, e.g., 20%, diminishes the electronic conductivity of the material. Furthermore, changing the n-dopant from La (A-site) to Nb (B-site) does not significantly affect the reducibility and number of charge carriers in p- and n-doped SrTiO3. However, a higher degree of oxygen vacancy clustering is observed for the La-doped material which reduces the oxygen ion diffusion rate and traps electrons. Nevertheless, our findings suggest that independent of doping site, mixed ionic/ electronic conductivity can be obtained in SrTiO3 perovskite oxides under reducing conditions and high temperatures when using a mixed p- and n-type doping strategy that uses a p-dopant concentration smaller than the n-dopant concentration.

  15. Thiolate ligands as a double-edged sword for CO oxidation on CeO2-supported Au25(SR)18 nanoclusters

    SciTech Connect (OSTI)

    Wu, Zili [ORNL; Jiang, Deen [ORNL; Mann, Amanda K [ORNL; Mullins, David R [ORNL; Qiao, Zhen-an [University of Tennessee, Knoxville (UTK); Allard Jr, Lawrence Frederick [ORNL; Zeng, Chenjie [Carnegie Mellon University (CMU); Jin, Rongchao [Carnegie Mellon University (CMU); Overbury, Steven {Steve} H [ORNL

    2014-01-01T23:59:59.000Z

    The effect of thiolate ligands was explored on the catalysis of CeO2-rod supported Au25(SR)18 (SR = -SCH2-CH2-Ph) by using CO oxidation as a probe reaction. Reaction kinetic tests, in situ IR and X-ray absorption spectroscopy, and density functional theory (DFT) were employed to understand how the thiolate ligands affect the nature of active sites, activation of CO and O2, as well as the reaction mechanism and kinetics. The intact Au25(SR)18 on CeO2-rod is found not able to adsorb CO. Only when the thiolate ligands are partially removed, starting from the interface between Au25(SR)18 and CeO2 at temperatures of 423 K and above, can the adsorption of CO be observed by IR. DFT calculations suggest that CO adsorbs favorably on the exposed gold atoms. Accordingly, the CO oxidation light-off temperature shifts to lower temperature. Several types of Au sites are probed by IR of CO adsorption during the ligand removal process. The cationic Au sites (charged between 0 and +1) are found to play the major role for low temperature CO oxidation. Similar activation energy and reaction rate are found for CO oxidation on differently treated Au25(SR)18/CeO2-rod, suggesting a simple site-blocking effect of the thiolate ligands in Au nanoclusters catalysis. Isotopic labelling experiments clearly indicate that CO oxidation on Au25(SR)18/CeO2-rod proceeds predominantly via the redox mechanism where CeO2 activates O2 while CO is activated on the de-thiolated gold sites. These results points to a double-edged sword role played by the thiolate ligands on Au25 nanoclusters for CO oxidation.

  16. Superconductivity up to 110 K in Bi2Sr2Ca2Cu3O10 compounds P. Lejay (1), P. de Rango (1), A. Sulpice (1), B. Giordanengo (1), R. Tournier (1), R. Retoux (2),

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    than 50 % for the samples doped with Pb. Because of the high reversibility of the magnetization versus. 2014 In the Bi-Sr-Ca-Cu-O system, we have studied the compound with the ideal formula Bi2Sr2Ca2Cu3O10, responsible for the superconductivity up to 110 K. The magnetic measurements reveal the presence of two phases

  17. Origin of the superior conductivity of perovskite Ba(Sr)SnO3 Heng-Rui Liu, Ji-Hui Yang, H. J. Xiang, X. G. Gong, and Su-Huai Wei

    E-Print Network [OSTI]

    Gong, Xingao

    Origin of the superior conductivity of perovskite Ba(Sr)SnO3 Heng-Rui Liu, Ji-Hui Yang, H. J. Xiang(Sr)SnO3 Heng-Rui Liu,1 Ji-Hui Yang,1 H. J. Xiang,1 X. G. Gong,1 and Su-Huai Wei2 1 Key Laboratory

  18. Electric field effects on spin accumulation in Nb-doped SrTiO{sub 3} using tunable spin injection contacts at room temperature

    SciTech Connect (OSTI)

    Kamerbeek, A. M.; Vries, E. K. de; Wees, B. J. van; Banerjee, T., E-mail: T.Banerjee@rug.nl [Physics of Nanodevices, Zernike Institute for Advanced Materials, University of Groningen, Nijenborgh 4, 9747 AG Groningen (Netherlands); Dankert, A.; Dash, S. P. [Department of Microtechnology and Nanoscience, Chalmers University of Technology, SE-41296 Gothenburg (Sweden)

    2014-05-26T23:59:59.000Z

    We report on features in charge transport and spin injection in an oxide semiconductor, Nb-doped SrTiO{sub 3}. This is demonstrated using electrically tunable spin injection contacts which exploit the large electric field at the interface and its interplay with the relative permittivity of the semiconductor. We realize spin accumulation in Nb-doped SrTiO{sub 3} which displays a unique dependence of the spin lifetime with bias polarity. These findings suggest a strong influence of the interface electric field on the charge transport as well as on spin accumulation unlike in conventional semiconductors and opens up promising avenues in oxide spintronics.

  19. Polarization-dependent infrared reflectivity study of Sr???Ca????Cu??O?? under pressure: Charge dynamics, charge distribution, and anisotropy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Frank, S.; Huecker, M.; Huber, A.; Ammerahl, U.; Kuntscher, C. A.

    2014-12-01T23:59:59.000Z

    We present a polarization-dependent infrared reflectivity study of the spin-ladder compound Sr???Ca????Cu??O?? under pressure. The optical response is strongly anisotropic, with the highest reflectivity along the ladders/chains (E?c) revealing a metallic character. For the polarization direction perpendicular to the ladder plane, an insulating behavior is observed. With increasing pressure the optical conductivity for E?c shows a strong increase, which is most pronounced below 2000cm?¹. According to the spectral weight analysis of the E?c optical conductivity the hole concentration in the ladders increases with increasing pressure and tends to saturate at high pressure. At ~7.5 GPa the number of holes permore »Cu atom in the ladders has increased by ??=0.09(±0.01), and the Cu valence in the ladders has reached the value +2.33. The optical data suggest that Sr???Ca????Cu??O?? remains electronically highly anisotropic up to high pressure, also at low temperatures.« less

  20. Critical thickness and strain relaxation in molecular beam epitaxy-grown SrTiO{sub 3} films

    SciTech Connect (OSTI)

    Wang, Tianqi; Ganguly, Koustav; Marshall, Patrick; Xu, Peng; Jalan, Bharat [Department of Chemical Engineering and Materials Science, University of Minnesota, Minneapolis, Minnesota 55455 (United States)] [Department of Chemical Engineering and Materials Science, University of Minnesota, Minneapolis, Minnesota 55455 (United States)

    2013-11-18T23:59:59.000Z

    We report on the study of the critical thickness and the strain relaxation in epitaxial SrTiO{sub 3} film grown on (La{sub 0.3}Sr{sub 0.7})(Al{sub 0.65}Ta{sub 0.35})O{sub 3} (001) (LSAT) substrate using the hybrid molecular beam epitaxy approach. No change in the film's lattice parameter (both the in-plane and the out-of-plane) was observed up to a film thickness of 180 nm, which is in sharp contrast to the theoretical critical thickness of ?12 nm calculated using the equilibrium theory of strain relaxation. For film thicknesses greater than 180 nm, the out-of-plane lattice parameter was found to decrease hyperbolically in an excellent agreement with the relaxation via forming misfit dislocations. Possible mechanisms are discussed by which the elastic strain energy can be accommodated prior to forming misfit dislocations leading to such anomalously large critical thickness.

  1. Surface electronic structure for various surface preparations of Nb-doped SrTiO{sub 3} (001)

    SciTech Connect (OSTI)

    Hatch, Richard C.; Fredrickson, Kurt D.; Choi, Miri; Lin, Chungwei; Seo, Hosung; Posadas, Agham B.; Demkov, Alexander A. [Department of Physics, The University of Texas at Austin, Austin, Texas 78712 (United States)] [Department of Physics, The University of Texas at Austin, Austin, Texas 78712 (United States)

    2013-09-14T23:59:59.000Z

    High-resolution angle-resolved photoemission spectroscopy (ARPES) was used to study the surface electronic structure of Nb-doped SrTiO{sub 3} (STO) single crystals prepared using a variety of surface preparations. ARPES measurements show that simple degreasing with subsequent anneal in vacuum is not an adequate surface preparation of STO, rather, preparations consisting of etching with buffered HF or HCl, and to a lesser extent, simple water leaching resulted in surfaces with much less disorder. A non-dispersing, mid-gap state was found ?800 meV above the top of the valence band for samples which underwent etching. This mid-gap state is not present for vacuum-annealed and water-leached samples, as well as for STO thin films grown using molecular beam epitaxy. Theoretical modeling using density functional theory suggests that this mid-gap state is not related to the SrO- and TiO{sub 2}-terminated surfaces, but rather, is due to a partial hydrogenation of the STO surface that occurs during etching.

  2. Polarization-dependent infrared reflectivity study of Sr???Ca????Cu??O?? under pressure: Charge dynamics, charge distribution, and anisotropy

    SciTech Connect (OSTI)

    Frank, S. [Univ. Augsburg, Augsburg (Germany); Huecker, M. [Brookhaven National Lab. (BNL), Upton, NY (United States); Huber, A. [Univ. Augsburg, Augsburg (Germany); Ammerahl, U. [Univ. Paris-Sud, Orsay (France); Kuntscher, C. A. [Univ. Augsburg, Augsburg (Germany)

    2014-12-01T23:59:59.000Z

    We present a polarization-dependent infrared reflectivity study of the spin-ladder compound Sr???Ca????Cu??O?? under pressure. The optical response is strongly anisotropic, with the highest reflectivity along the ladders/chains (E?c) revealing a metallic character. For the polarization direction perpendicular to the ladder plane, an insulating behavior is observed. With increasing pressure the optical conductivity for E?c shows a strong increase, which is most pronounced below 2000cm?¹. According to the spectral weight analysis of the E?c optical conductivity the hole concentration in the ladders increases with increasing pressure and tends to saturate at high pressure. At ~7.5 GPa the number of holes per Cu atom in the ladders has increased by ??=0.09(±0.01), and the Cu valence in the ladders has reached the value +2.33. The optical data suggest that Sr???Ca????Cu??O?? remains electronically highly anisotropic up to high pressure, also at low temperatures.

  3. Effect of charge compensation on the photoelectrochemical properties of Ho-doped SrTiO{sub 3} films

    SciTech Connect (OSTI)

    Zhao, Long; Fang, Liang; Dong, Wen; Zheng, Fengang; Shen, Mingrong [Jiangsu Key Laboratory of Thin Films and Department of Physics, Soochow University, Suzhou 215006 (China)] [Jiangsu Key Laboratory of Thin Films and Department of Physics, Soochow University, Suzhou 215006 (China); Wu, Tom [Division of Physics and Applied Physics, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371 (Singapore)] [Division of Physics and Applied Physics, School of Physical and Mathematical Sciences, Nanyang Technological University, Singapore 637371 (Singapore)

    2013-03-25T23:59:59.000Z

    When Ho{sup 3+} ions are substituted at Sr{sup 2+} sites in SrTiO{sub 3} (STO), the excess positive charges are compensated via three complementary routes: (1) strontium vacancies, (2) titanium vacancies, and (3) conduction electrons. In this study, we show that the photoelectrochemical properties of Ho-doped STO films are dependent on the charge compensation mechanisms. The compensation mechanism via the titanium vacancies exhibits the highest photocurrent density, which is 1.7 times higher than that of the pure STO sample. Based on the measured dielectric properties and electrochemical impedance spectroscopy data, we propose that the enhanced dielectric constant of the films can enlarge the width of the space charge region at the film/liquid interface, which eventually leads to the increase of the photocurrent density. Further enhancement of photocurrent density is obtained in the samples decorated with appropriate amounts of Pt nanoparticles, showing the advantage of composites for achieving the efficient photoelectrochemical property.

  4. Midcontinent rift volcanism in the Lake Superior region: Sr, Nd, and Pb isotopic evidence for a mantle plume origin

    SciTech Connect (OSTI)

    Nicholson, S.W. (Geological Survey, Reston, VA (USA) Univ. of Minnesota, MN (USA)); Shirey, S.B. (Carnegie Institution of Washington, DC (USA))

    1990-07-10T23:59:59.000Z

    Between 1091 and 1098 Ma, most of a 15- to 20-km thickness of dominantly tholeiitic basalt erupted in the Midcontinent Rift System of the Lake Superior region, North American. The Portage Lake Volcanics in Michigan, which are the youngest MRS flood basalts, fall into distinctly high- and low-TiO{sub 2} types having different liquid lines of descent. Incompatible trace elements in both types of tholeiites are enriched compared to depleted or primitive mantle (La/Yb = 4.3-5.3; Th/Ta = 2.12-2.16; Zr/Y = 4.3-4.4), and both basalt types are isotopically indistinguishable. Sr, Nd, and Pb isotopic compositions of the Portage Lake tholeiites have {sup 87}Sr/{sup 86}Sr{sub i} {approx}0.7038, {epsilon}{sub Nd(1095 Ma)} {approx}0 {plus minus} 2, and {mu}{sub 1} {approx}8.2. Model ages with respect to a depleted mantle source (T{sub DM}) average about 1950-2100 Ma. Portage Lake rhyolits fall into two groups. Type I rhyolites have Nd and Pb isotopic characteristics ({epsilon}{sub Nd(1095 Ma)} {approx}0 to {minus}4.7; {mu}{sub 1} {approx}8.2-7.8) consistent with contamination of tholeiitic rocks by 5-10% Archean crust. The one type II rhyolite analyzed has Nd and Pb isotopic compositions ({epsilon}{sub Nd(1095 Ma)} {approx}{minus}13 to {minus}16; {mu}{sub 1} {approx}7.6-7.7) which are consistent with partial melting of Archean crust. Early Proterozoic crust was not a major contaminant of MRS rocks in the Lake Superior region. Most reported Nd and Pb isotopic compositions of MRS tholeiites from the main stage of volcanism in the Lake Superior region and of the Duluth Complex are comparable to the Nd and Pb isotopic data for Portage lake tholeiites. The isotopic enrichment of the MRS source compared to depleted mantle is striking and must have occurred at least 700 m.y. before 1100 Ma.

  5. Varicella-Zoster Virus IE4 Protein Interacts with SR Proteins and Exports mRNAs through the TAP/NXF1

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Varicella-Zoster Virus IE4 Protein Interacts with SR Proteins and Exports mRNAs through the TAP experiments the presence of RNA stabilizes complexes containing IE4 and the cellular export factors TAP/NXF1 the export of reporter mRNAs and clearly showed, by TAP/NXF1 knockdown, that VZV infection requires the TAP

  6. Stochastic 3D Modeling of La0.6Sr0.4CoO3-Cathodes Based on Structural Segmentation of FIB-SEM Images

    E-Print Network [OSTI]

    Schmidt, Volker

    Graph, SOFC, Sphere Representation, Watershed Transformation 1. Introduction In this paper the microstructure of La0.6Sr0.4CoO3- (LSC) cathodes in solid oxide fuel cells (SOFC) is investigated. For classical SOFC electrodes (e.g. Ni- YSZ anodes or LSM-YSZ cathodes) microstructure effects are widely discussed

  7. Computational insights on crystal structures of the oxygen-evolving complex of photosystem II with either Ca²? or Ca²? substituted by Sr²?

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Vogt, Leslie [Yale Univ., New Haven, CT (United States); Ertem, Mehmed Z. [Yale Univ., New Haven, CT (United States); Brookhaven National Lab. (BNL), Upton, NY (United States); Pal, Rhitankar [Yale Univ., New Haven, CT (United States); Brudvig, Gary W. [Yale Univ., New Haven, CT (United States); Batista, Victor S. [Yale Univ., New Haven, CT (United States)

    2015-01-27T23:59:59.000Z

    The oxygen-evolving complex of photosystem II can function with either Ca²? or Sr²? as the heterocation, but the reason for differing turnover rates remains unresolved despite reported X-ray crystal structures for both forms. Using quantum mechanics/molecular mechanics (QM/MM) calculations, we optimize structures with each cation in both the resting state (S?) and in a series of reduced states (S?, S??, and S-?). Through comparison with experimental data, we determine that X-ray crystal structures with either Ca²? or Sr²? are most consistent with the S-? state, Mn?[III,III,III,II] with O4 and O5 protonated. As expected, the QM/MM models show that Ca²?/Sr²? substitution results in elongation of the heterocation bonds and displaces terminal waters W3 and W4. The optimized structures also show that hydrogen-bonded W5 is displaced in all S states with Sr²? as the heterocation, suggesting that this water may play a critical role during water oxidation.

  8. Proton-Conducting Films of Nanoscale Ribbons Formed by Exfoliation of the Layer Perovskite H2SrTa2O7

    E-Print Network [OSTI]

    Proton-Conducting Films of Nanoscale Ribbons Formed by Exfoliation of the Layer Perovskite H2SrTa2OTa2O7 were grown and characterized as solid-state proton conductors. The ribbons, made by exfoliation membranes made from layered materials such as exfoliated zirconium phosphate.12 Unfortunately, the proton

  9. Water adsorption on SrTiO3(001): II. Water, water, everywhere A.E. Becerra-Toledo a,

    E-Print Network [OSTI]

    Marks, Laurence D.

    Water adsorption on SrTiO3(001): II. Water, water, everywhere A.E. Becerra-Toledo a, , J January 2012 Available online 17 January 2012 Keywords: Strontium titanate Density functional theory Water adsorption Surface reconstruction X-ray photoelectron spectroscopy Oxide surfaces The role of water

  10. Computational insights on crystal structures of the oxygen-evolving complex of photosystem II with either Ca²? or Ca²? substituted by Sr²?

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Vogt, Leslie; Ertem, Mehmed Z.; Pal, Rhitankar; Brudvig, Gary W.; Batista, Victor S.

    2015-01-27T23:59:59.000Z

    The oxygen-evolving complex of photosystem II can function with either Ca²? or Sr²? as the heterocation, but the reason for differing turnover rates remains unresolved despite reported X-ray crystal structures for both forms. Using quantum mechanics/molecular mechanics (QM/MM) calculations, we optimize structures with each cation in both the resting state (S?) and in a series of reduced states (S?, S??, and S-?). Through comparison with experimental data, we determine that X-ray crystal structures with either Ca²? or Sr²? are most consistent with the S-? state, Mn?[III,III,III,II] with O4 and O5 protonated. As expected, the QM/MM models show that Ca²?/Sr²? substitutionmore »results in elongation of the heterocation bonds and displaces terminal waters W3 and W4. The optimized structures also show that hydrogen-bonded W5 is displaced in all S states with Sr²? as the heterocation, suggesting that this water may play a critical role during water oxidation.« less

  11. arXiv:1102.0242v3[astro-ph.SR]24Jun2012 A Bayesian approach to comparing theoretic models to observational data

    E-Print Network [OSTI]

    California at Berkeley, University of

    arXiv:1102.0242v3[astro-ph.SR]24Jun2012 A Bayesian approach to comparing theoretic models of theoretical models and observational data. From a statistical perspective, there are many challenges- porate into our analysis regarding Classical statistics. The thermal heat flux is proportional to the non

  12. Ferromagnetic Exchange Anisotropy from Antiferromagnetic Superexchange in the Mixed 3d 5d Transition-Metal Compound Sr3CuIrO6

    E-Print Network [OSTI]

    Ohta, Shigemi

    of Sciences, Beijing 100190, China 3 Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois of the unusual ferromagnetism in the one- dimensional copper-iridium oxide Sr3CuIrO6. Utilizing Ir L3 edge-insulator tran- sition was shown to exist in a variety of 5d iridium oxides [2­14]. An important consequence

  13. Effect of strain on tunability in Ba0.60Sr0.40TiO3 thin films on PtSi substrates

    E-Print Network [OSTI]

    Alpay, S. Pamir

    Effect of strain on tunability in Ba0.60Sr0.40TiO3 thin films on Pt­Si substrates D. M. Potrepkaa, M. W. Cole, and W. D. Nothwang Weapons & Materials Research Directorate, Active Materials Research discussed the effects that postannealing in oxygen can have to overcome limits on oxygen diffusion

  14. Electron Microscopy Study of Novel Ru Doped La0.8Sr0.2CrO3 as Anode Materials for Solid Oxide Fuel Cells (SOFCs)

    E-Print Network [OSTI]

    Marks, Laurence D.

    Electron Microscopy Study of Novel Ru Doped La0.8Sr0.2CrO3 as Anode Materials for Solid Oxide Fuel Fuel Cells (SOFCs) have been the center of research activities with the goal of improving energy Cells (SOFCs) Y. Wang,* B. D. Madsen,* W. Kobsiriphat,* S.A. Barnett* and L.D. Marks* * Department

  15. Unveiling Structure-Property Relationships in Sr2Fe1.5Mo0.5O6-, an Electrode Material for Symmetric Solid Oxide Fuel Cells

    E-Print Network [OSTI]

    Carter, Emily A.

    Solid Oxide Fuel Cells Ana B. Munoz-García, Daniel E. Bugaris, Michele Pavone,,§ Jason P. Hodges, Ashfia oxide fuel cells (SOFCs) can convert a wide variety of fuels with simpler and cheaper designs than those oxide fuel cell electrode material Sr2Fe1.5Mo0.5O6- (SFMO). Rietveld refinement of powder neutron

  16. Doping dependence of the superconducting gap in Bi2Sr2CaCu2O8 K. C. Hewitt* and J. C. Irwin

    E-Print Network [OSTI]

    Hewitt, Kevin

    Doping dependence of the superconducting gap in Bi2Sr2CaCu2O8¿ K. C. Hewitt* and J. C. Irwin.23) were studied to investigate the effects of doping on the symmetry and magnitude of the superconducting). The latter observations have led us to conclude that the doping dependence of the superconducting gap

  17. arXiv:0908.3746v1[astro-ph.SR]26Aug2009 Analytic modeling of the Moreton wave kinematics

    E-Print Network [OSTI]

    Temmer Manuela

    arXiv:0908.3746v1[astro-ph.SR]26Aug2009 Analytic modeling of the Moreton wave kinematics M. Temmer expansion of the CME flanks), we calculate the kinematics of the associated Moreton wave signature. Those model input parameters are deter- mined which fit the observed Moreton wave kinematics best. Using

  18. Oxygen-related dielectric relaxation and leakage characteristics of Pt,,Ba,Sr...TiO3 Pt thin-film capacitors

    E-Print Network [OSTI]

    Cao, Wenwu

    Oxygen-related dielectric relaxation and leakage characteristics of PtÕ,,Ba,Sr...TiO3 ÕPt thin to the postannealing temperature in oxygen and nitrogen atmosphere. High leakage currents and low-frequency dielectric and subsequently annealed in oxygen at 350 °C. Such results are related to the mobile oxygen ions and oxygen

  19. Fermi Surface of SrFe2P2 Determined by the de Haasvan Alphen Effect J. G. Analytis,1,2

    E-Print Network [OSTI]

    Fisher, Ian

    1 Stanford Institute for Materials and Energy Sciences, SLAC National Accelerator Laboratory, 2575 Sand Hill Road, Menlo Park, California 94025, USA 2 Geballe Laboratory for Advanced Materials 10 August 2009) We report measurements of the Fermi surface (FS) of the ternary iron-phosphide SrFe2P

  20. Alteration in the Porcupine Mountains, N. Michigan: O-and Sr-isotopic ratios of basalts of the 1. 1 Ga midcontinent rift

    SciTech Connect (OSTI)

    Nicholson, S.W.; Cannon, W.F. (Geological Survey, Reston, VA (United States)); Woodruff, L.G. (Geological Survey, St. Paul, MN (United States))

    1992-01-01T23:59:59.000Z

    Whole-rock oxygen (n = 32) and strontium (n = 12) isotopic compositions of basalts erupted during the 1.1 Ga Midcontinent rift event provide evidence for both regional hydrothermal alteration during subsidence and more local alteration related to native Cu mineralization. In the Porcupine Mountains area of northern Michigan, the fissure-fed rift basalts of the Portage Lake volcanics show delta O-18 ca 8--9[per thousand] and Sr-87/Sr-86 = 0.7029--0.7042. Overlying the Portage Lake volcanics are the remnants of a stratavolcano, the Porcupine volcanics. Basalts near the base of the Porcupine Volcanics have delta O-18 ca 8--9[per thousand] and Sr-87/Sr-86 = 0.7027-0.7049, similar to those of the Portage Lake Volcanics. In contrast, basalts near the top of the Porcupine volcanics show higher delta O-18. These values are similar to values for thin basalt flows (Lake Shore Traps) intercalated with conglomerates and sandstones overlying the stratavolcano. The Sr isotopic analyses for basalts from the Porcupine Volcanics, Portage Lake Volcanics and Lake Shore Traps yield an age of 1,060.8 [+-] 66.2 Ma, most probably reflecting the age of the regional hydrothermal alteration. Elevated delta O-18 values of basalts from the lower part of the section can be attributed to pervasive regional prehnite-pumpellyite alteration during burial shortly after eruption. Native Cu mineralization is minor or absent in these rocks. Heavier O-isotopic compositions of the Lake Shore Traps and of the basalts at the top of the Porcupine volcanics reflect localized alteration near deposits of native copper; thus, these upper basalts may have reacted with hydrothermal fluids channeled through adjacent thick conglomerates.

  1. Pulsed laser deposition of epitaxial BeO thin films on sapphire and SrTiO{sub 3}

    SciTech Connect (OSTI)

    Peltier, Thomas; Takahashi, Ryota; Lippmaa, Mikk, E-mail: mlippmaa@issp.u-tokyo.ac.jp [Institute for Solid State Physics, University of Tokyo, Chiba 277-8581 (Japan)

    2014-06-09T23:59:59.000Z

    Epitaxial beryllia thin films were grown by pulsed laser deposition on Al{sub 2}O{sub 3}(001) and SrTiO{sub 3}(111) substrates. Nearly relaxed epitaxial films were obtained on both substrates at growth temperatures of up to about 600?°C. Crystalline films with expanded lattice parameters were obtained even at room temperature. The maximum growth temperature was limited by a loss of beryllium from the film surface. The volatility of beryllium appeared to be caused by the slow oxidation kinetics at the film surface and the re-sputtering effect of high-energy Be and BeO species in the ablation plume. Time-of-flight plume composition analysis suggested that the target surface became Be metal rich at low oxygen pressures, reducing the growth rate of beryllia films.

  2. Probing single magnon excitations in Sr?IrO? using O K-edge resonant inelastic x-ray scattering

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Liu, X.; Dean, M. P. M.; Liu, J.; Chiuzbaian, S. G.; Jaouen, N.; Nicolaou, A.; Yin, W. G.; Rayan Serrao, C.; Ramesh, R.; Ding, H.; et al

    2015-05-27T23:59:59.000Z

    Resonant inelastic X-ray scattering (RIXS) at the L-edge of transition metal elements is now commonly used to probe single magnon excitations. Here we show that single magnon excitations can also be measured with RIXS at the K-edge of the surrounding ligand atoms when the center heavy metal elements have strong spin-orbit coupling. This is demonstrated with oxygen K-edge RIXS experiments on the perovskite Sr?IrO?, where low energy peaks from single magnon excitations were observed. This new application of RIXS has excellent potential to be applied to a wide range of magnetic systems based on heavy elements, for which the L-edgemore »RIXS energy resolutions in the hard X-ray region is usually poor.« less

  3. Heterojunction band offsets and dipole formation at BaTiO{sub 3}/SrTiO{sub 3} interfaces

    SciTech Connect (OSTI)

    Balaz, Snjezana [Department of Physics and Astronomy, Youngstown State University, One University Plaza, Youngstown, Ohio 44555 (United States)] [Department of Physics and Astronomy, Youngstown State University, One University Plaza, Youngstown, Ohio 44555 (United States); Zeng, Zhaoquan [Department of Electrical and Computer Engineering, The Ohio State University, 205 Dreese Lab, 2015 Neil Ave., Columbus, Ohio 43210 (United States)] [Department of Electrical and Computer Engineering, The Ohio State University, 205 Dreese Lab, 2015 Neil Ave., Columbus, Ohio 43210 (United States); Brillson, Leonard J. [Department of Electrical and Computer Engineering, The Ohio State University, 205 Dreese Lab, 2015 Neil Ave., Columbus, Ohio 43210 (United States) [Department of Electrical and Computer Engineering, The Ohio State University, 205 Dreese Lab, 2015 Neil Ave., Columbus, Ohio 43210 (United States); Department of Physics, The Ohio State University, 191 West Woodruff, Columbus, Ohio 43210 (United States)

    2013-11-14T23:59:59.000Z

    We used a complement of photoemission and cathodoluminescence techniques to measure formation of the BaTiO{sub 3} (BTO) on SrTiO{sub 3} (STO) heterojunction band offset grown monolayer by monolayer by molecular beam epitaxy. X-ray photoemission spectroscopy (XPS) provided core level and valence band edge energies to monitor the valence band offset in-situ as the first few crystalline BTO monolayers formed on the STO substrate. Ultraviolet photoemission spectroscopy (UPS) measured Fermi level positions within the band gap, work functions, and ionization potentials of the growing BTO film. Depth-resolved cathodoluminescence spectroscopy measured energies and densities of interface states at the buried heterojunction. Kraut-based XPS heterojunction band offsets provided evidence for STO/BTO heterojunction linearity, i.e., commutativity and transitivity. In contrast, UPS and XPS revealed a large dipole associated either with local charge transfer or strain-induced polarization within the BTO epilayer.

  4. Octahedral rotations in strained LaAlO{sub 3}/SrTiO{sub 3} (001) heterostructures

    SciTech Connect (OSTI)

    Fister, T. T.; Hruszkewycz, S. O.; Proffit, D. L.; Eastman, J. A.; Fuoss, P. H.; Baldo, P. M.; Fong, D. D. [Materials Science Division, Argonne National Laboratory, Argonne, Illinois 60439 (United States); Zhou, H. [X-Ray Science Division, Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois 60439 (United States); Luo, Z. [National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei 230029 (China); Seo, S. S. A.; Lee, H. N. [Materials Science and Technology Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 (United States)

    2014-02-01T23:59:59.000Z

    Many complex oxides display an array of structural instabilities often tied to altered electronic behavior. For oxide heterostructures, several different interfacial effects can dramatically change the nature of these instabilities. Here, we investigate LaAlO{sub 3}/SrTiO{sub 3} (001) heterostructures using synchrotron x-ray scattering. We find that when cooling from high temperature, LaAlO{sub 3} transforms from the Pm3{sup ¯}m to the Imma phase due to strain. Furthermore, the first 4 unit cells of the film adjacent to the substrate exhibit a gradient in rotation angle that can couple with polar displacements in films thinner than that necessary for 2D electron gas formation.

  5. Probing single magnon excitations in Sr?IrO? using O K-edge resonant inelastic x-ray scattering

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Liu, X. [Chinese Academy of Sciences (CAS), Beijing (China). Beijing National Lab. for Condensed Matter Physics (BNLCP-CAS); Brookhaven National Lab. (BNL), Upton, NY (United States); Collaborative Innovation Center of Quantum Matter, Beijing (China); Dean, M. P. M. [Brookhaven National Lab. (BNL), Upton, NY (United States); Liu, J. [Univ. of California, Berkeley, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Chiuzbaian, S. G. [Sorbonne Univ., Paris (France); Synchrotron SOLEIL, Saint-Aubin (France); Jaouen, N. [Synchrotron SOLEIL, Saint-Aubin (France); Nicolaou, A. [Synchrotron SOLEIL, Saint-Aubin (France); Yin, W. G. [Brookhaven National Lab. (BNL), Upton, NY (United States); Rayan Serrao, C. [Univ. of California, Berkeley, CA (United States); Ramesh, R. [Univ. of California, Berkeley, CA (United States); Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Ding, H. [Chinese Academy of Sciences (CAS), Beijing (China). Beijing National Lab. for Condensed Matter Physics (BNLCP-CAS); Collaborative Innovation Center of Quantum Matter, Beijing (China); Hill, J. P. [Brookhaven National Lab. (BNL), Upton, NY (United States)

    2015-05-27T23:59:59.000Z

    Resonant inelastic X-ray scattering (RIXS) at the L-edge of transition metal elements is now commonly used to probe single magnon excitations. Here we show that single magnon excitations can also be measured with RIXS at the K-edge of the surrounding ligand atoms when the center heavy metal elements have strong spin-orbit coupling. This is demonstrated with oxygen K-edge RIXS experiments on the perovskite Sr?IrO?, where low energy peaks from single magnon excitations were observed. This new application of RIXS has excellent potential to be applied to a wide range of magnetic systems based on heavy elements, for which the L-edge RIXS energy resolutions in the hard X-ray region is usually poor.

  6. Distinct oxygen hole doping in different layers of Sr?CuO4-?/La?CuO? superlattices

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Smadici, S.; Lee, J. C. T.; Rusydi, A.; Logvenov, G.; Bozovic, I.; Abbamonte, P.

    2012-03-01T23:59:59.000Z

    X-ray absorption in Sr?CuO4-?/La?CuO? (SCO/LCO) superlattices shows a variable occupation with doping of a hole state different from holes doped for x?xoptimal in bulk La2-xSrxCuO? and suggests that this hole state is on apical oxygen atoms and polarized in the a-b plane. Considering the surface reflectivity gives a good qualitative description of the line shapes of resonant soft x-ray scattering. The interference between superlattice and surface reflections was used to distinguish between scatterers in the SCO and the LCO layers, with the two hole states maximized in different layers of the superlattice.

  7. Effect of Eu–Ni substitution on electrical and dielectric properties of Co–Sr–Y-type hexagonal ferrite

    SciTech Connect (OSTI)

    Ali, Irshad, E-mail: irshadalibzu@gmail.com [Department of Physics, Bahauddin Zakariya University, Multan 60800 (Pakistan); Islam, M.U. [Department of Physics, Bahauddin Zakariya University, Multan 60800 (Pakistan); Ashiq, Muhammad Naeem, E-mail: naeemashiqqau@yahoo.com [Institute of Chemical Sciences, Bahauddin Zakariya University, Multan 60800 (Pakistan); Khan, Hasan M. [Department of Physics, Bahauddin Zakariya University, Multan 60800 (Pakistan); Iqbal, M. Asif [Department of Physics, Bahauddin Zakariya University, Multan 60800 (Pakistan); Nust College of Electrical and Mechanical Engineering, Islamabad (Pakistan); Najam-Ul-Haq, Muhammad [Institute of Chemical Sciences, Bahauddin Zakariya University, Multan 60800 (Pakistan)

    2014-01-01T23:59:59.000Z

    Graphical abstract: - Highlights: • Single phase nanostructured Sr{sub 2}Co{sub 2?x}Ni{sub x} Eu{sub y}Fe{sub 12?y}O{sub 22} were synthesized by the microemulsion method. • The materials show semiconducting behavior. • The high resistivity makes these materials useful for high frequency applications. • The Curie temperature decreases with the substituents. - Abstract: Single phase nanostructured Eu–Ni substituted Y-type hexaferrites with nominal composition Sr{sub 2}Co{sub 2?x}Ni{sub x} Eu{sub y}Fe{sub 12?y}O{sub 22} (x = 0.0–1, y = 0.0–0.1) were synthesized by the normal microemulsion method. X-ray diffraction (XRD) technique was employed for phase analysis and indexing of each pattern corroborates that well defined Y-type crystalline phase is formed. It is observed that DC resistivity enhanced which is accredited to room temperature resistivity differences of dopant and host ions. The hopping of electrons and jumping of holes are responsible for conduction below Curie temperature (T{sub C}), whereas above Curie temperature is due to polaron hopping. The decrease in T{sub C} may be due to the fact that Eu–Fe interactions on the B sites are weaker than Fe–Fe interaction. The dispersion in the dielectric constant ??(f) favor the occurrence of peaks in the tan ?(f). The extraordinary values of resistivity and small dielectric loss make these materials pre-eminent contestant for high frequency applications.

  8. Influence of misonidazole, SR-2508, RSU-1069 and WR-2721 on spontaneous metastases in C57BL mice

    SciTech Connect (OSTI)

    Kanclerz, A.; Chapman, J.D.

    1988-02-01T23:59:59.000Z

    The effect of treatments with the hypoxic cell radiosensitizers misonidazole (MISO), SR-2508, RSU-1069, and with the radioprotector WR-2721 on spontaneously disseminated Lewis lung carcinoma (LLC) and B16 melanoma (B16M) was investigated. Tumors were implanted into the tails of C57BL mice and were surgically removed after reaching volumes of approximately 40 mm3. This technique results in the induction of metastatic disease in lungs and at other anatomical sites and allows the independent treatment of disseminated tumor cells. The radiosensitizers and the radioprotector were administered 24 hr after surgery and animals were killed 14 and 30 days after removal of LLC and B16M, respectively. The time to death from spontaneous metastases was also measured. Both single treatments with large doses of MISO (1.0 g/kg) and fractionated therapy with smaller doses (0.5 g/kg on 5 consecutive days) promoted the formation of metastases to the lungs, lymph nodes and other organs. The survival times of MISO treated animals did not differ from control animals but manifestation of metastatic disease in the lungs and other organs occurred at earlier times. Administration of equitoxic doses of SR-2508 (3.0 g/kg) and RSU-1069 (0.1 g/kg) also promoted metastases formation. Mice treated with these radiosensitizers developed more metastases in the lungs and at other sites. Treatment with a single dose of WR-2721 (0.4 g/kg) promoted lung metastases but exerted a suppressive effect on lymph node tumors. When the radioprotector was given in fractionated schedules in three different doses (0.05 g/kg, 0.1 g/kg and 0.2 g/kg for 10 consecutive days) a slight enhancement of lung metastases and suppression of extrapulmonary metastases was observed.

  9. San Francisco Estuary Striped Bass Migration History Determined by Electron-microprobe Analysis of Otolith Sr/Ca Ratio

    SciTech Connect (OSTI)

    Ostrach, D J; Phillis, C C; Weber, P K; Ingram, B L; Zinkl, J G

    2004-09-17T23:59:59.000Z

    Habitat use has been shown to be an important factor in the bioaccumulation of contaminants in striped bass. This study examines migration in striped bass as part of a larger study investigating bioaccumulation and maternal transfer of xenobiotics to progeny in the San Francisco Estuary system. Habitat use, residence time and spawning migration over the life of females (n = 23) was studied. Female striped bass were collected between Knights Landing and Colusa on the Sacramento River during the spawning runs of 1999 and 2001. Otoliths were removed, processed and aged via otolith microstructure. Subsequently, otoliths were analyzed for strontium/calcium (Sr/Ca) ratio using an electron-microprobe to measure salinity exposure and to distinguish freshwater, estuary, and marine habitat use. Salinity exposure during the last year before capture was examined more closely for comparison of habitat use by the maternal parent to contaminant burden transferred to progeny. Results were selectively confirmed by ion microprobe analyses for habitat use. The Sr/Ca data demonstrate a wide range of migratory patterns. Age of initial ocean entry differs among individuals before returning to freshwater, presumably to spawn. Some fish reside in freshwater year-round, while others return to more saline habitats and make periodic migrations to freshwater. Frequency of habitat shifts and residence times differs among fish, as well as over the lifetime of individual fish. While at least one fish spent its final year in freshwater, the majority of spawning fish spent their final year in elevated salinity. However, not all fish migrated to freshwater to spawn in the previous year. Results from this investigation concerning migration history in striped bass can be combined with contaminant and histological developmental analyses to better understand the bioaccumulation of contaminants and the subsequent effects they and habitat use have on fish populations in the San Francisco Estuary system.

  10. Neutron diffraction study of the crystal structure and structural phase transition of La{sub 0.7}Ca{sub 0.3-x}Sr{sub x}CrO{sub 3} (0<=x<=0.3)

    SciTech Connect (OSTI)

    Omoto, Kazuki [Department of Integrated Sciences in Physics and Biology, College of Humanities and Sciences, Nihon University, 3-25-40 Sakurajousui, Setagaya-ku, Tokyo 156-8550 (Japan); Norberg, Stefan T. [Department of Chemical and Biological Engineering, Chalmers University of Technology, SE-412 96 Gothenburg (Sweden); ISIS Facility, Rutherford Appleton Laboratory, Chilton, Didcot, OX11 0QX (United Kingdom); Hull, Steve [ISIS Facility, Rutherford Appleton Laboratory, Chilton, Didcot, OX11 0QX (United Kingdom); Aoto, Akimitsu [Department of Integrated Sciences in Physics and Biology, College of Humanities and Sciences, Nihon University, 3-25-40 Sakurajousui, Setagaya-ku, Tokyo 156-8550 (Japan); Hashimoto, Takuya, E-mail: takuya@chs.nihon-u.ac.j [Department of Integrated Sciences in Physics and Biology, College of Humanities and Sciences, Nihon University, 3-25-40 Sakurajousui, Setagaya-ku, Tokyo 156-8550 (Japan)

    2010-02-15T23:59:59.000Z

    The crystal structure of the La{sub 0.7}Ca{sub 0.3-x}Sr{sub x}CrO{sub 3} series, including the compositional and temperature dependence of the structural parameters, has been studied by variable temperature neutron diffraction measurements. The extent of the distortions from the ideal cubic perovskite structure has been evaluated quantitatively using the average bond lengths and the mean volumes of the [CrO{sub 6}] octahedron and [(La/Ca/Sr)O{sub 12}] polyhedron, and has been shown to decrease with increase of Sr content or temperature. At the structural phase transition from the orthorhombic (Pnma) structure to the rhombohedral (R3-barc) one, the volume of the [CrO{sub 6}] octahedron decreases whereas that of the [(La/Ca/Sr)O{sub 12}] polyhedron shows little difference, resulting in an overall decrease in the level of distortion. The change in the degree of distortion at the phase transition decreases with increase of Sr content, in agreement with the smaller variation of the enthalpy and volume for the specimens with higher Sr content. - Graphical abstract: Temperature dependence of parameter, PHI, representing the extent of distortion from the ideal cubic perovskite structure, for La{sub 0.7}Ca{sub 0.3}CrO{sub 3} (diamonds) and La{sub 0.7}Ca{sub 0.15}Sr{sub 0.15}CrO{sub 3} (circles) calculated from neutron diffraction patterns.

  11. Electron-doping through La{sup III}-for-Sr{sup II} substitution in (Sr{sub 1-} {sub x} La {sub x} ){sub 2}FeTaO{sub 6}: Effects on the valences and ordering of the B-site cations, Fe and Ta

    SciTech Connect (OSTI)

    Rautama, E.-L. [Materials and Structures Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503 (Japan); Laboratory of Inorganic and Analytical Chemistry, Helsinki University of Technology, FIN-02015 HUT (Finland); Chan, T.S. [Department of Chemistry and Center for Nano Storage Research, National Taiwan University, Taipei, (China); Liu, R.S. [Department of Chemistry and Center for Nano Storage Research, National Taiwan University, Taipei, (China); Chen, J.M. [National Synchrotron Radiation Research Center, Hsinchu, (China); Yamauchi, H. [Materials and Structures Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503 (Japan); Karppinen, M. [Materials and Structures Laboratory, Tokyo Institute of Technology, 4259 Nagatsuta, Midori-ku, Yokohama 226-8503 (Japan)]. E-mail: karppinen@msl.titech.ac.jp

    2006-01-15T23:59:59.000Z

    We have employed aliovalent A-site cation substitution, La{sup III}-for-Sr{sup II}, to dope the Sr(Fe{sub 0.5}Ta{sub 0.5})O{sub 3} perovskite oxide with electrons. Essentially single-phase samples of (Sr{sub 1-} {sub x} La {sub x} )(Fe{sub 0.5}Ta{sub 0.5})O{sub 3} were successfully synthesized up to x{approx}0.3 in a vacuum furnace at 1400 deg. C. The samples were found to crystallize (rather than with orthorhombic symmetry) in monoclinic space group P2{sub 1}/n that accounts for the partial ordering of the B-site cations, Fe and Ta. With increasing La-substitution level, x, the degree of Fe/Ta order was found to increase such that the La-richest compositions are best described by the B-site ordered double-perovskite formula (Sr,La){sub 2}FeTaO{sub 6}. From Fe L {sub 3} and Ta L {sub 3} XANES spectra it was revealed that upon electron doping the two B-site cations, Fe{sup III} and Ta{sup V}, are both prone to reduction. Magnetic susceptibility measurements showed spin-glass type behaviour for all the samples with a transition temperature slightly increasing with increasing x. -- Graphical abstract: Valence states of Fe and Ta are controlled in the partially ordered perovskite oxide (Sr,La){sub 2}FeTaO{sub 6}, through aliovalent La{sup III}-for-Sr{sup II} substitu0010ti.

  12. Breakdown by magnetic field in a La{sub 0.7}Sr{sub 0.3}MnO{sub 3}/MgO/Fe spin valve

    SciTech Connect (OSTI)

    Wu Xiaojie; Meng Jian [State Key Laboratory of Rare Earth Resources Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, 5625 Renmin Street, Changchun 130022 (China); Zhang Zhenzhong [State Key Laboratory of Luminescence and Applications, Changchun Institute of Optics, Fine Mechanics and Physics, Chinese Academy of Sciences, 3888 Dongnanhu Road, Changchun 130033 (China)

    2012-03-19T23:59:59.000Z

    A La{sub 0.7}Sr{sub 0.3}MnO{sub 3}/MgO/Fe spin valve with inverse tunneling magnetoresistance (TMR) was fabricated on a (100) SrTiO{sub 3} substrate by radio frequency magnetron sputtering. Giant TMR ratios up to 540% were obtained. The breakdown of the spin valve was observed at high magnetic field, which was attributed to the joint action of the invalidation of MgO barrier and the shift of Fermi energy in La{sub 0.7}Sr{sub 0.3}MnO{sub 3} at high magnetic field.

  13. Crystallographic, electronic, thermal, and magnetic properties of single-crystal SrCo2As2

    SciTech Connect (OSTI)

    Pandey, Abhishek [Ames Lab. and Iowa State Univ., Ames, IA (United States). Dept. of Physics and Astronomy; Quirinale, D. G. [Ames Lab. and Iowa State Univ., Ames, IA (United States). Dept. of Physics and Astronomy; Jayasekara, W. [Ames Lab. and Iowa State Univ., Ames, IA (United States). Dept. of Physics and Astronomy; Sapkota, A. [Ames Lab. and Iowa State Univ., Ames, IA (United States). Dept. of Physics and Astronomy; Kim, M. G. [Ames Lab. and Iowa State Univ., Ames, IA (United States). Dept. of Physics and Astronomy; Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States); Dhaka, R. S. [Ames Lab. and Iowa State Univ., Ames, IA (United States). Dept. of Physics and Astronomy; Lee, Y. [Ames Lab. and Iowa State Univ., Ames, IA (United States). Dept. of Physics and Astronomy; Heitmann, T. W. [Univ. of Missouri, Columbia, MO (United States). Missouri Research Reactor; Stephens, P. W. [State Univ. of New York (SUNY), Plattsburgh, NY (United States); Ogloblichev, V. [Russian Academy of Sciences, Urals Div., Ekaterinburg (Russian Federation). Inst. of Metal Physics; Kreyssig, A. [Ames Lab. and Iowa State Univ., Ames, IA (United States). Dept. of Physics and Astronomy; McQueeney, R. J. [Ames Lab. and Iowa State Univ., Ames, IA (United States). Dept. of Physics and Astronomy; Goldman, A. I. [Ames Lab. and Iowa State Univ., Ames, IA (United States). Dept. of Physics and Astronomy; Kaminski, Adam [Ames Lab. and Iowa State Univ., Ames, IA (United States). Dept. of Physics and Astronomy; Harmon, B. N. [Ames Lab. and Iowa State Univ., Ames, IA (United States). Dept. of Physics and Astronomy; Furukawa, Y. [Ames Lab. and Iowa State Univ., Ames, IA (United States). Dept. of Physics and Astronomy; Johnston, D. C. [Ames Lab. and Iowa State Univ., Ames, IA (United States). Dept. of Physics and Astronomy

    2013-07-01T23:59:59.000Z

    In tetragonal SrCo2As2 single crystals, inelastic neutron scattering measurements demonstrated that strong stripe-type antiferromagnetic (AFM) correlations occur at a temperature T = 5 K [W. Jayasekara et al., arXiv:1306.5174] that are the same as in the isostructural AFe2As2 (A = Ca, Sr, Ba) parent compounds of high-Tc superconductors. This surprising discovery suggests that SrCo2As2 may also be a good parent compound for high-Tc superconductivity. Here, structural and thermal expansion, electrical resistivity ?, angle-resolved photoemission spectroscopy (ARPES), heat capacity Cp, magnetic susceptibility ?, 75As NMR and neutron diffraction measurements of SrCo2As2 crystals are reported together with LDA band structure calculations that shed further light on this fascinating material. The c-axis thermal expansion coefficient ?c is negative from 7 to 300 K, whereas ?a is positive over this T range. The ?(T) shows metallic character. The ARPES measurements and band theory confirm the metallic character and in addition show the presence of a flat band near the Fermi energy EF. The band calculations exhibit an extremely sharp peak in the density of states D(EF) arising from a flat dx2-y2 band. A comparison of the Sommerfeld coefficient of the electronic specific heat with ?(T ? 0) suggests the presence of strong ferromagnetic itinerant spin correlations which on the basis of the Stoner criterion predicts that SrCo2As2 should be an itinerant ferromagnet, in conflict with the magnetization data. The ?(T) does have a large magnitude, but also exhibits a broad maximum at 115 K suggestive of dynamic short-range AFM spin correlations, in agreement with the neutron scattering data. The measurements show no evidence for any type of phase transition between 1.3 and 300 K and we propose that metallic SrCo2As2 has a gapless quantum spin-liquid ground state.

  14. Perovskite-type SrTi{sub 1-x}Nb{sub x}(O,N){sub 3} compounds: Synthesis, crystal structure and optical properties

    SciTech Connect (OSTI)

    Maegli, Alexandra, E-mail: Alexandra.Maegli@empa.c [Empa - Swiss Federal Laboratories for Materials Science and Technology, Solid State Chemistry and Catalysis, Ueberlandstr. 129, CH-8600 Duebendorf (Switzerland); Yoon, Songhak, E-mail: Songhak.Yoon@empa.c [Empa - Swiss Federal Laboratories for Materials Science and Technology, Solid State Chemistry and Catalysis, Ueberlandstr. 129, CH-8600 Duebendorf (Switzerland); Otal, Eugenio, E-mail: Eugenio.Otal@empa.c [Empa - Swiss Federal Laboratories for Materials Science and Technology, Solid State Chemistry and Catalysis, Ueberlandstr. 129, CH-8600 Duebendorf (Switzerland); Karvonen, Lassi, E-mail: Lassi.Karvonen@empa.c [Empa - Swiss Federal Laboratories for Materials Science and Technology, Solid State Chemistry and Catalysis, Ueberlandstr. 129, CH-8600 Duebendorf (Switzerland); Mandaliev, Peter, E-mail: Petar.Mandaliev@env.ethz.c [Empa - Swiss Federal Laboratories for Materials Science and Technology, Solid State Chemistry and Catalysis, Ueberlandstr. 129, CH-8600 Duebendorf (Switzerland); Weidenkaff, Anke, E-mail: Anke.Weidenkaff@empa.c [Empa - Swiss Federal Laboratories for Materials Science and Technology, Solid State Chemistry and Catalysis, Ueberlandstr. 129, CH-8600 Duebendorf (Switzerland)

    2011-04-15T23:59:59.000Z

    The synthesis, crystal structure, thermal stability and absorbance spectra of perovskite-type oxynitrides with the general formula SrTi{sub 1-x}Nb{sub x}(O,N){sub 3} (x=0.05, 0.10, 0.20, 0.50, 0.80, 0.90, 0.95) have been investigated. Oxide samples were prepared by a polymerized complex synthesis route and post-treated under ammonia at 850 {sup o}C for 24 h to substitute nitrogen for oxygen. Synchrotron X-ray powder diffraction (XRD) evidenced that the mixed oxide phases were all transformed into oxynitrides with perovskite-type structure during a thermal ammonolysis. SrTi{sub 1-x}Nb{sub x}(O,N){sub 3} with compositions x{<=}0.80 crystallized in a cubic and samples with x{>=}0.90 in a tetragonal structure. The Rietveld refinement indicated a continuous enlargement of the lattice parameters towards higher niobium content of the samples. Thermogravimetric analysis (TGA) and hotgas extraction revealed the dependence of the nitrogen incorporation upon the degree of niobium substitution. It showed that more nitrogen was detected in the samples with higher niobium content. Furthermore, TGA disclosed stability for all oxynitrides at T{<=}400 {sup o}C. Diffuse reflectance spectroscopy indicated a continuous decrease of the band gap's width from 3.24 eV (SrTi{sub 0.95}Nb{sub 0.05} (O,N){sub 3}) to 1.82 eV (SrTi{sub 0.05}Nb{sub 0.95}(O,N){sub 3}) caused by the increasing amount of nitrogen towards the latter composition. -- Graphical Abstract: The system SrTi{sub 1-x}Nb{sub x}(O,N){sub 3} is described and the changes in crystal structure, nitrogen content and width of the band gap are discussed. Display Omitted Research highlights: {yields} Synthesis of SrTi{sub 1-x}Nb{sub x}(O,N){sub 3} perovskite-type oxynitrides via thermal ammonolysis. {yields} Co-substitution of Nb{sup 5+} enabled to adjust the amount nitrogen insertion. {yields} Tuning of the optical band gap through nitrogen.{yields} Changes of crystal structure from cubic to tetragonal with increasing niobium content.

  15. La{sub 0.5}Sr{sub 0.5}TiO{sub 3} nanopowders prepared by the hydrothermal method

    SciTech Connect (OSTI)

    Putjuso, Thanin [School of General Education, Faculty of Liberal Arts, Rajamangala University of Rattanakosin Wang Klai Kangwon Campus, 77110 (Thailand)] [School of General Education, Faculty of Liberal Arts, Rajamangala University of Rattanakosin Wang Klai Kangwon Campus, 77110 (Thailand); Maensiri, Santi [School of Physics, Institute of Science, Suranaree University of Technology, Nakhon Ratchasima 30000 (Thailand)] [School of Physics, Institute of Science, Suranaree University of Technology, Nakhon Ratchasima 30000 (Thailand); Hunpratub, Sitchai [Department of Physics, Faculty of Science, Khon Kaen University, Khon Kaen 40002 (Thailand)] [Department of Physics, Faculty of Science, Khon Kaen University, Khon Kaen 40002 (Thailand); Swatsitang, Ekaphan, E-mail: ekaphan@kku.ac.th [Department of Physics, Faculty of Science, Khon Kaen University, Khon Kaen 40002 (Thailand)] [Department of Physics, Faculty of Science, Khon Kaen University, Khon Kaen 40002 (Thailand)

    2012-09-15T23:59:59.000Z

    Graphical abstract: LRTEM image of the single-phase La{sub 0.5}Sr{sub 0.5}TiO{sub 3} particles. It is seen from the figure that the product has a plate-like morphology with average particles sizes in the range of 100–300 nm. In addition, the SAED data taken from an individual particle (lower inset) shows the presence of sharp diffraction rings, which are indicative of polycrystalline La{sub 0.5}Sr{sub 0.5}TiO{sub 3} formation. The high-resolution TEM image (upper inset) shows for further confirmation of a crystalline structure of La{sub 0.5}Sr{sub 0.5}TiO{sub 3} powder. This image shows a clearly resolved crystalline domain with uniform interplanar spacing of 0.276 nm. Highlights: ? La{sub 0.5}Sr{sub 0.5}TiO{sub 3} nanopowder is prepared in 2 M KOH solution by hydrothermal method. ? The solution is heat treated at 220 °C for 24 h in air. ? LRTEM reveals a plate-like morphology of particle with average size of 100–300 nm. ? HRTEM image shows a crystalline domain with interplanar spacing of 0.276 nm. -- Abstract: La{sub 0.5}Sr{sub 0.5}TiO{sub 3} nanopowders were prepared by the hydrothermal method. The influence of processing parameters, including KOH concentration, reaction temperature and reaction time on the obtained products were studied. The structure and morphology of the obtained products were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The XRD results show that pure phase La{sub 0.5}Sr{sub 0.5}TiO{sub 3} nanopowders can be successfully synthesized with 2 M KOH concentration at a low temperature of 220 °C for 24 h. In addition, the product has a plate-like shape with particle sizes in the range of 25–100 nm as estimated by TEM.

  16. Crystal structure of Sr{sub 6}Y{sub 2}Al{sub 4}O{sub 15}: XRD refinements and first-principle calculations

    SciTech Connect (OSTI)

    Wang Chunhai, E-mail: chwang81@163.com [National Key Laboratory of Shock Wave and Detonation Physics, Institute of Fluid Physics, CAEP, Mianyang 621900 (China) and Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871 (China); Guo Dongfang [College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000 (China); Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871 (China); Li Zhaofei; Wang Xiaoming; Lin Jianhua [Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871 (China); Zeng Zhengzhi [College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000 (China); Jing Xiping, E-mail: xpjing@pku.edu.cn [Beijing National Laboratory for Molecular Sciences, State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871 (China)

    2012-08-15T23:59:59.000Z

    The ternary oxide phase Sr{sub 6}Y{sub 2}Al{sub 4}O{sub 15} (SYA) was synthesized and the crystal structure was determined by using the X-ray powder diffraction data. Structure of the phase can be considered as an oxygen-deficient perovskite Sr(Y{sub 1/3}Al{sub 2/3})O{sub 2.5} and has a monoclinic C2 (S.G. No. 5) unit cell with the unit cell parameters: a=17.597(1) A, b=5.7408(1) A, c=7.6860(1) A, {beta}=90.7659(3) Degree-Sign , V{sub cell}=776.37(1) A{sup 3}, Z=2. By bond parameter analysis and first-principle calculations, we confirmed the reasonability of our crystal structure model. According to the calculated band structure, SYA has an indirect band gap {approx}4.3 eV and a direct band gap {approx}4.4 eV, which is wide to be transparent to UV and visible lights. We also synthesized other rare-earth isomorphs Sr{sub 6}Ln{sub 2}Al{sub 4}O{sub 15} (Ln=Tb, Dy, Ho, Er, Tm, Yb and Lu) and obtained their cell parameters. - Graphical abstract: Sr{sub 6}Y{sub 2}Al{sub 4}O{sub 15} has a monoclinic unit cell with space group C2 (5) with unit cell parameters: a=17.597(1) A, b=5.7408(1) A, c=7.6860(1) A, {beta}=90.7659(3) Degree-Sign . Highlights: Black-Right-Pointing-Pointer Sr{sub 6}Y{sub 2}Al{sub 4}O{sub 15} (SYA) has an oxygen-deficient perovskite structure Sr(Y{sub 1/3}Al{sub 2/3})O{sub 2.5}. Black-Right-Pointing-Pointer SYA shows C2 symmetry: a=17.597(1) A, b=5.7408(1) A, c=7.6860(1) A, {beta}=90.7659(3) Degree-Sign . Black-Right-Pointing-Pointer SYA has an indirect band gap {approx}4.3 eV and a direct band gap {approx}4.4 eV.

  17. Epitaxial properties of Al-doped ZnO thin films grown by pulsed laser deposition on SrTiO{sub 3}(001)

    SciTech Connect (OSTI)

    Karger, M.; Schilling, M. [Technische Universitaet Braunschweig, Institut fuer Elektrische Messtechnik und Grundlagen der Elektrotechnik, Hans-Sommer-Strasse 66, D-38106 Braunschweig (Germany)

    2005-02-15T23:59:59.000Z

    Undoped and Al-doped ZnO films with dopant concentrations of nominally 1% and 10% and a thickness of 100 nm have been grown on SrTiO{sub 3}(001) by pulsed laser deposition at substrate temperatures between 650 deg. C and 820 deg. C. The epitaxial conditions were examined with high pressure in-situ reflection high energy electron diffraction (RHEED) and ex-situ x-ray diffraction (XRD) measurements in different geometries. The films are highly (1120)-oriented with a lattice mismatch between the SrTiO{sub 3}[110] direction and the c-axis of about 3%. Atomic force microscopy (AFM) revealed smooth surfaces with a roughness of d{sub rms}<5 nm and different sized islands.

  18. Nanoscale Probing of Voltage Activated Oxygen Reduction/Evolution Reactions in Nanopatterned (LaxSr1-x)CoO3- Cathodes

    SciTech Connect (OSTI)

    Leonard, Donovan N [ORNL; Kumar, Amit [ORNL; Jesse, Stephen [ORNL; Biegalski, Michael D [ORNL; Christen, Hans M [ORNL; Mutoro, Eva [Massachusetts Institute of Technology (MIT); Crumlin, Ethan [Massachusetts Institute of Technology (MIT); Shao-Horn, Yang [Massachusetts Institute of Technology (MIT); Kalinin, Sergei V [ORNL; Borisevich, Albina Y [ORNL

    2013-01-01T23:59:59.000Z

    Bias-dependent mechanisms of reversible and irreversible electrochemical processes on a (La0.5Sr0.5)2CoO4 modified (LaxSr1-x)CoO3- surface are studied using dynamic electrochemical strain microscopy (D-ESM). The reversible oxygen reduction/evolution process is activated at voltages as low as 3 4 V and the degree of transformation increases linearly with applied bias. The irreversible processes associated with static surface deformation become apparent above 10 12 V. Post-mortem focused-ion milling combined with atomic resolution scanning transmission electron microscopy and electron energy loss spectroscopy is used to establish the mechanisms of irreversible transformations and attribute it to amorphization of the top layer of material. These studies both establish the framework for probing irreversible electrochemical processes in solids and illustrate rich spectrum of electrochemical transformations underpinning electrocatalytic activity in cobaltites.

  19. Epitaxial Ba{sub 2}IrO{sub 4} thin-films grown on SrTiO{sub 3} substrates by pulsed laser deposition

    SciTech Connect (OSTI)

    Nichols, J., E-mail: john.nichols@uky.edu; Korneta, O. B.; Terzic, J.; Cao, G.; Brill, J. W.; Seo, S. S. A. [Department of Physics and Astronomy, University of Kentucky, Lexington, Kentucky 40506 (United States)

    2014-03-24T23:59:59.000Z

    We have synthesized epitaxial Ba{sub 2}IrO{sub 4} (BIO) thin-films on SrTiO{sub 3} (001) substrates by pulsed laser deposition and studied their electronic structure by dc-transport and optical spectroscopic experiments. We have observed that BIO thin-films are insulating but close to the metal-insulator transition boundary with significantly smaller transport and optical gap energies than its sister compound, Sr{sub 2}IrO{sub 4}. Moreover, BIO thin-films have both an enhanced electronic bandwidth and electronic-correlation energy. Our results suggest that BIO thin-films have great potential for realizing the interesting physical properties predicted in layered iridates.

  20. MICROSTRUCTURE STUDY ON THE La0.7Sr0.3MnO3 AND RARE-EARTH OXIDE VERTICALLY ALIGNED NANOCOMPOSITE THIN FILMS

    E-Print Network [OSTI]

    Hazariwala, Harshad

    2011-05-05T23:59:59.000Z

    interfacial area where magnetoelectric coupling in BaTiO3:CoFe2O4 and BiFeO3:NiFe2O4, 3,4 and strain tuning in BiFeO3:Sm2O3 and La0.7Sr0.3MnO3:ZnO have been achieved. 5 In this work, epitaxial La0.7Sr0.3MnO3 and rare-earth oxide nanocomposites have... interfaces. At the beginning of the project, we processed ceramic composite targets by following the standard solid state reaction and analyze the target crystalline properties in order to _______________ This thesis follows the style of Applied Physics...

  1. Atomic and electronic structures of single-layer FeSe on SrTiO3(001): The role of oxygen deficiency

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bang, Junhyeok; Li, Zhi; Sun, Y. Y.; Samanta, Amit; Zhang, Y. Y.; Zhang, Wenhao; Wang, Lili; Chen, X.; Ma, Xucun; Xue, Q.-K.; Zhang, S. B.

    2013-06-01T23:59:59.000Z

    Using first-principles calculation, we propose an interface structure for single triple-layer FeSe on the SrTiO3(001) surface, a high-Tc superconductor found recently. The key component of this structure is the oxygen deficiency on the top layer of the SrTiO3 substrate, as a result of Se etching used in preparing the high-Tc samples. The O vacancies strongly bind the FeSe triple layer to the substrate giving rise to a (2×1) reconstruction, as observed by scanning tunneling microscopy. The enhanced binding correlates to the significant increase of Tc observed in experiment. The O vacancies also serve as the source of electron doping, which modifies the Fermi surface of the first FeSe layer by filling the hole pocket near the center of the surface Brillouin zone, as suggested from angle-resolved photoemission spectroscopy measurement.

  2. Influence of oxygen pressure and aging on LaAlO{sub 3} films grown by pulsed laser deposition on SrTiO{sub 3} substrates

    SciTech Connect (OSTI)

    Park, Jihwey; Aeppli, Gabriel [London Centre for Nanotechnology, University College London, London WC1H 0AH (United Kingdom); Soh, Yeong-Ah, E-mail: yeongahsoh@gmail.com [London Centre for Nanotechnology, University College London, London WC1H 0AH (United Kingdom); Department of Materials, Imperial College London, London SW7 2AZ (United Kingdom); David, Adrian; Lin, Weinan [Division of Physics and Applied Physics, Nanyang Technological University, Singapore 637371 (Singapore); Wu, Tom [Physical Sciences and Engineering Division, King Abdullah University of Science and Technology, Thuwal 23955-6900 (Saudi Arabia)

    2014-02-24T23:59:59.000Z

    The crystal structures of LaAlO{sub 3} films grown by pulsed laser deposition on SrTiO{sub 3} substrates at oxygen pressure of 10{sup ?3} millibars or 10{sup ?5} millibars, where kinetics of ablated species hardly depend on oxygen background pressure, are compared. Our results show that the interface between LaAlO{sub 3} and SrTiO{sub 3} is sharper when the oxygen pressure is lower. Over time, the formation of various crystalline phases is observed while the crystalline thickness of the LaAlO{sub 3} layer remains unchanged. X-ray scattering as well as atomic force microscopy measurements indicate three-dimensional growth of such phases, which appear to be fed from an amorphous capping layer present in as-grown samples.

  3. A New Class of Octahedral Molecular Sieve Materials for the Selective Removal and Sequestration of {sup 90}Sr{sup 2+}

    SciTech Connect (OSTI)

    NYMAN,MAY D.; NENOFF,TINA M.; TRIPATHI,AKHILESH; PARISE,JOHN B.; MAXWELL,ROBERT S.; HARRISON,WILLIAM T.A.

    2000-07-14T23:59:59.000Z

    The structure of Na{sub 16}Nb{sub 12.8}Ti{sub 3.2}O{sub 44.8}(OH){sub 3.2} {center_dot} 8H{sub 2}O, a member of a new family of Sandia Octahedral Molecular Sieves (SOMS) having a Nb/Na/M{sup IV} (M= Ti, Zr) oxide framework and exchangeable Na and water in open channels, was determined from Synchrotron X-ray data. The SOMS phases are isostructural with variable M{sup IV}:Nb(1:50--1:4) ratios. The SOMS are extremely selective for sorption of divalent cations, particularly Sr{sup 2+}. The ion-exchanged SOMS undergo direct thermal conversion to a perovskite-type phase, indicating this is a promising new method for removal and sequestration of radioactive Sr-90 from mixed nuclear wastes.

  4. Room temperature magnetoresistance in CoFeB/SrTiO{sub 3}/CoFeB magnetic tunnel junctions deposited by ion beam sputtering

    SciTech Connect (OSTI)

    Hassen, E. M. J. [CEA, LETI, MINATEC Campus, Grenoble (France); SPINTEC (UMR 8191 CEA-CNRS-UJF), CEA-INAC, 38054 Grenoble Cedex (France); Viala, B.; Cyrille, M. C.; Cartier, M.; Redon, O. [CEA, LETI, MINATEC Campus, Grenoble (France); Lima, P. [SPTS, Process Technology Systems, Ringland Way, Newport (United Kingdom); Belhadji, B.; Yang, H. X.; Chshiev, M. [SPINTEC (UMR 8191 CEA-CNRS-UJF), CEA-INAC, 38054 Grenoble Cedex (France); Velev, J. [Department of Physics, University of Puerto Rico, San Juan 00931 (Puerto Rico)

    2012-04-01T23:59:59.000Z

    Room temperature transport properties are reported in polycrystalline SrTiO{sub 3}-based magnetic tunnel junctions deposited by ion beam sputtering. The junctions comprise CoFeB electrodes and the SrTiO{sub 3} barrier with thickness varied between 0.9 and 1.9 nm. Resistance area product values between 3 {Omega}.{mu}m{sup 2} and 22 k{Omega}.{mu}m{sup 2} have been measured with a tunnel magnetoresistance ratio ranging from 3.1 to 13% at room temperature. At low barrier thickness (1.2 nm), ferromagnetic coupling between electrodes is observed, indicating the presence of defects in the structure. A post-oxidation step was found to improve transport properties at lower barrier thickness.

  5. Control of the Magnetic and Magnetotransport Properties of La0.67Sr0.33MnO3 Thin Films Through Epitaxial Strain

    SciTech Connect (OSTI)

    Arenholz, Elke; Takamura, Y.; Chopdekar, R.V.; Arenholz, E.; Suzuki, Y.

    2007-12-20T23:59:59.000Z

    The influence of epitaxial strain, in the form of tetragonal distortions, on the magnetic and magnetotransport properties of La{sub 0.67}Sr{sub 0.33}MnO{sub 3} thin films was studied. The tetragonal distortion (c/a ratio) was modulated through the choice of the substrate, ranging from c/a=1.007 on (001)-oriented (LaAlO{sub 3}){sub 0.3}(Sr{sub 2}AlTaO{sub 6}){sub 0.7} substrates to 0.952 on (110)-oriented GdScO{sub 3} substrates. In agreement with previous theoretical predictions, these large values of tensile strain cause the Curie temperature and the saturation magnetization to decrease, alter the temperature dependence of the resistivity and magnetoresistance, and increase the resistivity several orders of magnitude.

  6. Abnormal thermal conductivity in tetragonal tungsten bronze Ba{sub 6?x}Sr{sub x}Nb{sub 10}O{sub 30}

    SciTech Connect (OSTI)

    Kolodiazhnyi, T., E-mail: kolodiazhnyi.taras@nims.go.jp; Sakurai, H.; Vasylkiv, O.; Borodianska, H. [National Institute for Materials Science, Tsukuba, Ibaraki 305-0044 (Japan); Mozharivskyj, Y. [Department of Chemistry and Chemical Biology, McMaster University, 1280 Main Street West, Hamilton, Ontario L8S4M1 (Canada)

    2014-03-17T23:59:59.000Z

    Ba{sub 6?x}Sr{sub x}Nb{sub 10}O{sub 30} solid solution with 0???x???6 crystallizes in centrosymmetric tetragonal “tungsten bronze” structure (space group P4/mbm). We report on the x dependence of thermal conductivity of polycrystalline samples measured in the 2–400?K temperature interval. Substitution of Sr for Ba brings about a significant decrease in thermal conductivity at x???3 accompanied by development of a low-temperature (T???10–30?K) “plateau” region reminiscent of a glass-like compounds. We explain this behaviour based on a size-driven site occupancy and atomic displacement parameters associated with an alkaline earth atomic positions in the title compounds.

  7. Combined experimental and theoretical study of the low temperature dielectric and magnetic properties of trivalent Eu ion doped SrTiO{sub 3} ceramics

    SciTech Connect (OSTI)

    Yu Jiangzhou; Fang Liang; Cai Tianyi; Ju Sheng; Dong Wen; Zheng Fengang; Shen Mingrong [Jiangsu Key Laboratory of Thin Films and Department of Physics, Soochow University, Suzhou, 215006 (China)

    2012-03-15T23:59:59.000Z

    Single-phase Sr{sub 1-3x/2}Eu{sub x}TiO{sub 3} (SETO{sub x}) (x = 0-0.075) ceramics were prepared to study the effects of Eu substitution on their crystal structure, low temperature dielectric, and magnetic behaviors. Rietveld refinement of X-ray diffraction data yields direct evidence that the Eu ion substitutes Sr site at the perovskite. The measured dielectric properties can be well explained by the mean-field model. It has been found that the anomaly dielectric enhancement behavior exists in the SETO{sub x=0.005} sample, while more stable quantum paraelectric states are obtained in other doped samples. On the other hand, all the Eu doped samples exhibit doping concentration dependence of paramagnetism. Developing the linear response model, we conclude that a molecular field is acting on Eu ions possibly via the spin polarized Eu-O-Ti hybridization.

  8. Direct determination of {sup 90}Sr and {sup 147}Pm in Chernobyl hot particles collected in Kiev using beta absorption method

    SciTech Connect (OSTI)

    Papp, Z.; Bolyos, A.; Dezso, Z.; Daroczy, S. [Kossuth Univ., Debrecen (Hungary)

    1997-12-01T23:59:59.000Z

    59 hot particles were collected in Kiev, Ukraine, in 1987. All but one were prepared from a moss carpet of 360 cm{sup 2} area. Radionuclide composition of the hot particles was investigated by gamma-spectrometry and beta absorption method. Pure beta emitters {sup 90}Sr and {sup 147}Pm were determined in 25 hot particles measuring the beta absorption curves of the hot particles with an end-window Geiger-Mueller counter and decomposing the curves in order to obtain the contributions of {sup 90}Sr and {sup 147}Pm to the total beta counting rate. All but one of the hot particles were found to be the debris of the fuel. The activity ratio {sup 90}Sr:{sup 144}Ce was 0.078 which is half of the theoretical result. Although {sup 147}Pm is considered to be a refractory nuclide, it seems that significant part of {sup 147}Pm went to the homogeneous fraction of the general fallout. The surface density of hot particles (of higher than about 50 Bq activity) was about 1,600 m{sup -2} and that of the activities of the nuclides {sup 90}Sr, {sup 106}Ru, {sup 134}Cs, {sup 137}Cs, {sup 144}Ce and {sup 147}Pm as components of hot particles was 12.2, 54.3, 5.9, 9.7, 234 and 18.3 kBq m{sup -2} (activity values counted for 26 April 1986), respectively, in downtown Kiev city in 1987.

  9. Vortex line pinning in Bi{sub 2}Sr{sub 2}CaCu{sub 2}O{sub 8} single crystals with columnar defects

    SciTech Connect (OSTI)

    van der Beek, C.J.; Vinokur, V.M.; Crabtree, G.W. [Argonne National Lab., IL (United States); Schmidt, B.; Konczykowski, M. [CEA-Ecole Polytechnique, 91 - Palaiseau (France). Lab. d`Etudes des Solides Irradies

    1994-05-01T23:59:59.000Z

    The ac transmittivity of heavy-ion irradiated Bi{sub 2}Sr{sub 2}CaCu{sub 2}O{sub 8} single crystals shows a sharp cusp as function of the dc field orientation with respect to the columnar defects. This unambiguously demonstrates the connected nature of vortices in these samples. In contrast, the irreversibility line does not reveal a cusp.

  10. Metal-semiconductor-transition observed in Bi{sub 2}Ca(Sr, Ba){sub 2}Co{sub 2}O{sub 8+?} single crystals

    SciTech Connect (OSTI)

    Dong, Song-Tao [National Laboratory of Solid State Microstructures and Department of Material Science and Engineering, Nanjing University, Nanjing 210093 (China); Institute of Material Science and Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003 (China); Zhang, Bin-Bin; Zhang, Lun-Yong; Yao, Shu-Hua, E-mail: ybchen@nju.edu.cn, E-mail: shyao@nju.edu.cn; Zhou, Jian; Zhang, Shan-Tao; Gu, Zheng-Bin; Chen, Yan-Feng [National Laboratory of Solid State Microstructures and Department of Material Science and Engineering, Nanjing University, Nanjing 210093 (China); Chen, Y. B., E-mail: ybchen@nju.edu.cn, E-mail: shyao@nju.edu.cn [National Laboratory of Solid State Microstructures and Department of Physics and National Laboratory of Solid State Microstructures, Nanjing University, Nanjing 210093 (China)

    2014-07-28T23:59:59.000Z

    Electrical property evolution of Bi{sub 2}AE{sub 2}Co{sub 2}O{sub 8+?} single crystals (AE?=?Ca, Sr and Ba) is systematically explored. When AE changes from Ca to Ba, the electrical property of Bi{sub 2}Ca{sub 2}Co{sub 2}O{sub 8+?} and Bi{sub 2}Sr{sub 2}Co{sub 2}O{sub 8+?} demonstrates semiconductor-like properties. But Bi{sub 2}Ba{sub 2}Co{sub 2}O{sub 8+?} shows the metallic behavior. Analysis of temperature-dependent resistance substantiates that from metallic Bi{sub 2}Ba{sub 2}Co{sub 2}O{sub 8+?} to semiconductor-like Bi{sub 2}Sr{sub 2}Co{sub 2}O{sub 8+?} can be attributed to Anderson localization. However the semiconductor behaviour of Bi{sub 2}Sr{sub 2}Co{sub 2}O{sub 8+?} and Bi{sub 2}Ca{sub 2}Co{sub 2}O{sub 8+?} is related to electronic correlations effect that is inferred by large negative magnetoresistance (?70%). The theoretical electronic structures and valence X-ray photoemission spectroscopy substantiate that there is a relative large density of state around Fermi level in Bi{sub 2}Ba{sub 2}Co{sub 2}O{sub 8+?} compared with other two compounds. It suggests that Bi{sub 2}Ba{sub 2}Co{sub 2}O{sub 8+?} is more apt to be metal in this material system.

  11. Structural and electronic properties of Sr{sub x}Ba{sub 1-x}SnO{sub 3} from first principles calculations

    SciTech Connect (OSTI)

    Moreira, E. [Departamento de Fisica Teorica e Experimental, Universidade Federal do Rio Grande do Norte, 59072-970 Natal-RN (Brazil); Henriques, J.M. [Centro de Educacao e Saude, Universidade Federal de Campina Grande, Campus Cuite, 58175-000 Cuite-PB (Brazil); Azevedo, D.L. [Departamento de Fisica, Universidade Federal do Maranhao, Centro de Ciencias Exatas e Tecnologia, 65085-580 Sao Luis-MA (Brazil); Caetano, E.W.S., E-mail: ewcaetano@gmail.com [Instituto Federal de Educacao, Ciencia e Tecnologia do Ceara, 60040-531 Fortaleza-CE (Brazil); Freire, V.N. [Departamento de Fisica, Universidade Federal do Ceara, Centro de Ciencias, Caixa Postal 6030, Campus do Pici, 60455-760 Fortaleza-CE (Brazil); Albuquerque, E.L. [Departamento de Biofisica e Farmacologia, Universidade Federal do Rio Grande do Norte, 59072-970 Natal-RN (Brazil)

    2012-03-15T23:59:59.000Z

    Neutron diffraction data for Sr{sub x}Ba{sub 1-x}SnO{sub 3} (x=0.0, 0.2, 0.4, 0.6, 0.8 and 1.0) solid solutions were used as inputs to obtain optimized geometries and electronic properties using the density functional theory (DFT) formalism considering both the local density and generalized gradient approximations, LDA and GGA, respectively. The crystal structures and SnO{sub 6} octahedra tilting angles found after total energy minimization agree well with experiment, specially for the GGA data. Elastic constants were also obtained and compared with theoretical and experimental results for cubic BaSnO{sub 3}. While the alloys with cubic unit cell have an indirect band gap, tetragonal and orthorhombic alloys exhibit direct band gaps (exception made to x=1.0). The Kohn-Sham minimum electronic band gap oscillates from 1.52 eV (cubic x=0.0, LDA) to 2.61 eV (orthorhombic x=1.0, LDA), and from 0.74 eV (cubic BaSnO{sub 3}, GGA) to 1.97 eV (orthorhombic SrSnO{sub 3}, GGA). Parabolic interpolation of bands has allowed us to estimate the effective masses for charge carriers, which are shown to be anisotropic and larger for holes. - Graphical Abstract: Highlights: Black-Right-Pointing-Pointer DFT calculations were performed on Sr{sub x}Ba{sub 1-x}SnO{sub 3} solid solutions. Black-Right-Pointing-Pointer Calculated crystal structures agree well with experiment. Black-Right-Pointing-Pointer Alloys have direct or indirect gaps depending on the Sr molar fraction. Black-Right-Pointing-Pointer The Kohn-Sham gap variation from x=0.0 to x=1.0 is close to the experimental value. Black-Right-Pointing-Pointer Carrier effective masses are very anisotropic, specially for holes.

  12. Structural, chemical, and electrochemical characteristics of LaSr2Fe2CrO9--based solid oxide fuel cell anodes

    E-Print Network [OSTI]

    Poeppelmeier, Kenneth R.

    -of-the-art solid oxide fuel cell (SOFC) anode is Ni-8-mole% yttria stabilized zirconia (YSZ), which performs very Available online 5 March 2012 Keywords: Solid oxide fuel cell Perovskite Oxide anode Redox Sulfur tolerance Solid oxide fuel cells with LaSr2Fe2CrO9-­Gd0.1Ce0.9O2- composite anodes were tested in H2, H2S

  13. High-pressure X-ray diffraction study of SrMoO{sub 4} and pressure-induced structural changes

    SciTech Connect (OSTI)

    Errandonea, Daniel [MALTA Consolider Team-Departamento de Fisica Aplicada-ICMUV, Universitat de Valencia, Edificio de Investigacion, c/Dr. Moliner 50, 46100 Burjassot, Valencia (Spain)], E-mail: daniel.errandonea@uv.es; Kumar, Ravhi S. [Department of Physics and Astronomy, High Pressure Science and Engineering Center, University of Nevada, 4505 Maryland Parkway, Las Vegas, NV 89154-4002 (United States); Ma Xinghua; Tu Chaoyang [Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002 (China); Graduated School of Chinese Academy of Science, 100039 Beijing (China)

    2008-02-15T23:59:59.000Z

    SrMoO{sub 4} was studied under compression up to 25 GPa by angle-dispersive X-ray diffraction. A phase transition was observed from the scheelite-structured ambient phase (space group I4{sub 1}/a) to a monoclinic fergusonite phase (space group I2/a) at 12.2(9) GPa. The unit-cell parameters of the high-pressure phase are a=5.265(9) A, b=11.191(9) A, c=5.195 (5) A, and {beta}=90.9(1){sup o}, Z=4 at 13.1 GPa. There is no significant volume collapse at the phase transition. No additional phase transitions were observed and on release of pressure the initial phase is recovered, implying that the observed structural modifications are reversible. The reported transition appeared to be a ferroelastic second-order transformation producing a structure that is a monoclinic distortion of the low-pressure phase and was previously observed in compounds isostructural to SrMoO{sub 4}. A possible mechanism for the transition is proposed and its character is discussed in terms of the present data and the Landau theory. Finally, the room temperature equation of states is reported and the anisotropic compressibility of the studied crystal is discussed in terms of the compression of the Sr-O and Mo-O bonds. - Graphical abstract: The evolution of the structure of SrMoO{sub 4} upon compression was established using synchrotron X-ray diffraction and a diamond-anvil cell. A pressure-induced phase transition was found involving a symmetry decrease from tetragonal to monoclinic. A transition mechanism is proposed and its ferroelastic character is discussed in terms of the Landau theory.

  14. Rb-Sr and Sm-Nd isotopic study of the Glen Mountains layered complex: initiation of rifting within the southern Oklahoma aulacogen

    SciTech Connect (OSTI)

    Lambert, D.D.; Unruh, D.M.; Gilbert, M.C.

    1988-01-01T23:59:59.000Z

    Rb-Sr and Sm-Nd isotopic data for rocks and minerals of the Glen Mountains layered complex (GMLC), a midcontinent mafic layered intrusion in the Wichita Mountains of southwestern Oklahoma, constrain the time of initiation of rifting within the southern Oklahoma aulacogen and provide information on the chemistry of the early Paleozoic mantle. Four whole-rock samples define a Rb-Sr isochron corresponding to a maximum crystallization age of 577 +/- 165 Ma and an initial Sr isotopic composition of 0.70359 +/- 2. A three-point Sm-Nd mineral-whole-rock (internal) isochron for an anorthositic gabbro provides a crystallization age of 528 +/- 29 Ma. These data suggest that the GMLC was emplaced into the southern Oklahoma aulacogen during the initial phase of rifting along the southern margin of the North American craton in the early Paleozoic. This Sm-Nd internal isochron age is within analytical uncertainty of U-Pb zircon ages for granites and rhyolites from the Wichita Mountains; therefore, mafic and felsic magmatism may have been contemporaneous within the rift during the early stages of development. Hybrid rocks and composite dikes in the Wichita Mountains provide field evidence for contemporaneous mafic and felsic magmas. Initial Sr and Nd isotopic data suggest that magmas parental to the GMLC were derived from a depleted mantle source. However, Nd isotopic data for the GMLC plot distinctly below data for the depleted mantle source cited by DePaolo and thus suggest that the parental magmas of the GMLC were either contaminated by Proterozoic crust of the southern midcontinent or were derived from a heterogenous mantle source region that had variable initial Nd isotopic compositions.

  15. Synthesis of single-phase Sr{sub 3}Co{sub 2}Fe{sub 24}O{sub 41} Z-type ferrite by polymerizable complex method

    SciTech Connect (OSTI)

    Kikuchi, Takeyuki, E-mail: kikuchi@eng.u-hyogo.ac.jp [Department of Materials Science and Chemistry, Graduate School of Engineering, University of Hyogo, 2167 Syosya, Himeji-shi 671-2280 (Japan)] [Department of Materials Science and Chemistry, Graduate School of Engineering, University of Hyogo, 2167 Syosya, Himeji-shi 671-2280 (Japan); Nakamura, Tatsuya [Department of Electrical Engineering and Computer Sciences, Graduate School of Engineering, University of Hyogo, 2167 Syosya, Himeji-shi 671-2280 (Japan)] [Department of Electrical Engineering and Computer Sciences, Graduate School of Engineering, University of Hyogo, 2167 Syosya, Himeji-shi 671-2280 (Japan); Yamasaki, Tohru [Department of Materials Science and Chemistry, Graduate School of Engineering, University of Hyogo, 2167 Syosya, Himeji-shi 671-2280 (Japan)] [Department of Materials Science and Chemistry, Graduate School of Engineering, University of Hyogo, 2167 Syosya, Himeji-shi 671-2280 (Japan); Nakanishi, Makoto; Fujii, Tatsuo; Takada, Jun [Department of Applied Chemistry, Faculty of Engineering, Okayama University, 3-1-1 Tsushima-naka, Okayama 700-8530 (Japan)] [Department of Applied Chemistry, Faculty of Engineering, Okayama University, 3-1-1 Tsushima-naka, Okayama 700-8530 (Japan); Ikeda, Yasunori [Research Institute for Production Development, 15 Morimoto-cho, Shimogamo, Sakyo-ku, Kyoto-shi, Kyoto 606-0805 (Japan)] [Research Institute for Production Development, 15 Morimoto-cho, Shimogamo, Sakyo-ku, Kyoto-shi, Kyoto 606-0805 (Japan)

    2011-07-15T23:59:59.000Z

    Highlights: {yields} Single-phase Sr{sub 3}Co{sub 2}Z was obtained in a very narrow temperature range. {yields} Sr{sub 3}Co{sub 2}Z ferrite prepared by polymerizable complex method showed typical M-H curve of soft ferrite. -- Abstract: Synthesis of single-phase Sr{sub 3}Co{sub 2}Fe{sub 24}O{sub 41} Z-type (Sr{sub 3}Co{sub 2}Z) ferrite was realized by adopting the polymerizable complex method. Crystal structure of samples has been investigated by powder X-ray diffraction (XRD). Single-phase Sr{sub 3}Co{sub 2}Z ferrite was obtained by heating at 1473 K for 5 h in air. Magnetic properties were discussed by measurements of M-H curves with vibrating sample magnetometer (VSM). Sr{sub 3}Co{sub 2}Z ferrite prepared by polymerizable complex method showed typical M-H curve of soft ferrite, with a saturation magnetization of 21.5{mu}{sub B}/formula unit (50.5 emu/g) and a coercive force of 0.014 T at room temperature.

  16. Overcoming phase instability of RBaCo2O5+ (R = Y and Ho) by Sr substitution for application as cathodes in solid oxide fuel cells

    SciTech Connect (OSTI)

    Kim, Jung-Hyun [ORNL; Young Nam, Kim [University of Texas at Austin; Bi, Zhonghe [ORNL; Manthiram, Arumugam [University of Texas at Austin; Paranthaman, Mariappan Parans [ORNL; Huq, Ashfia [ORNL

    2013-01-01T23:59:59.000Z

    Phase instabilities of the RBaCo2O5+ (R = Y and Ho) layered-perovskites and their decompositions into RCoO3 and BaCoO3-z at 800 oC in air were investigated. This will restrict their high temperature applications such as cathodes in solid oxide fuel cell (SOFC). However, appropriate amount of Sr substitution ( 60 % for R = Y and 70 % for R = Ho) for Ba successfully stabilized the R(Ba1-xSrx)Co2O5+ phase at elevated temperatures. This can be explained by decreasing oxygen vacancies at R-O layer, decreasing R-O bonding length, and consequent improvement of structural integrity. In addition, the Sr substitution (x = 0.6 - 1.0) for Ba provided added benefit with respect to the chemical stability against Ce0.8Gd0.2O1.9 (GDC) electrolyte, which is a critical requirement for the cathodes in SOFC. Among the various compositions investigated, the Y(Ba0.3Sr0.7)Co2O5+ + GDC composite cathode delivered the optimum electrochemical performances with a stable phase demonstrating the potential as a cathode in SOFC.

  17. FREQUENCY DISTRIBUTIONS OF 90SR AND 137CS CONCENTRATIONS IN AN ECOSYSTEM OF THE 'RED FOREST' AREA IN THE CHERNOBYL EXCLUSION ZONE

    SciTech Connect (OSTI)

    Farfan, E.; Jannik, T.; Caldwell, E.

    2011-10-01T23:59:59.000Z

    In the most highly contaminated region of the Chernobyl Exclusion Zone: the 'Red Forest' site, the accumulation of the major dose-affecting radionuclides ({sup 90}Sr and {sup 137}Cs) within the components of an ecological system encompassing 3,000 m{sup 2} were characterized. The sampled components included soils (top 0-10 cm depth), Molina caerulea (blue moor grass), Camponotus vagus (carpenter ants) and Pelobates fuscus (spade-footed toad). In a comparison among the components of this ecosystem, the {sup 90}Sr and {sup 137}Cs concentrations measured in 40 separate grids exhibited significant differences, while the frequency distribution of the values were close to a logarithmically normal leptokurtic distribution with a significant right-side skew. While it is important to identify localized areas of high contamination or 'hot spots,' including these values in the arithmetic mean may overestimate the exposure risk. In component sample sets that exhibited logarithmically normal distribution, the geometrical mean more accurately characterizes a site. Ideally, risk assessment is most confidently achieved when the arithmetic and geometrical means are most similar, meaning the distribution approaches normal. Through bioaccumulation, the highest concentrations of {sup 90}Sr and {sup 137}Cs were measured in the blue moor grass and spade-footed toad. These components also possessed distribution parameters that shifted toward a normal distribution.

  18. Significant enhancement in thermoelectric properties of polycrystalline Pr-doped SrTiO{sub 3??} ceramics originating from nonuniform distribution of Pr dopants

    SciTech Connect (OSTI)

    Dehkordi, Arash Mehdizadeh, E-mail: amehdiz@g.clemson.edu [Department of Materials Science and Engineering, Clemson University, Clemson, South Carolina 29634 (United States); Bhattacharya, Sriparna; He, Jian [Department of Physics and Astronomy, Clemson University, Clemson, South Carolina 29634 (United States); Alshareef, Husam N. [Materials Science and Engineering, King Abdullah University of Science and Technology (KAUST), Thuwal 23955-6900 (Saudi Arabia); Tritt, Terry M., E-mail: ttritt@clemson.edu [Department of Materials Science and Engineering, Clemson University, Clemson, South Carolina 29634 (United States); Department of Physics and Astronomy, Clemson University, Clemson, South Carolina 29634 (United States)

    2014-05-12T23:59:59.000Z

    Recently, we have reported a significant enhancement (>70% at 500?°C) in the thermoelectric power factor (PF) of bulk polycrystalline Pr-doped SrTiO{sub 3} ceramics employing a novel synthesis strategy which led to the highest ever reported values of PF among doped polycrystalline SrTiO{sub 3}. It was found that the formation of Pr-rich grain boundary regions gives rise to an enhancement in carrier mobility. In this Letter, we investigate the electronic and thermal transport in Sr{sub 1?x}Pr{sub x}TiO{sub 3} ceramics in order to determine the optimum doping concentration and to evaluate the overall thermoelectric performance. Simultaneous enhancement in the thermoelectric power factor and reduction in thermal conductivity in these samples resulted in more than 30% improvement in the dimensionless thermoelectric figure of merit (ZT) for the whole temperature range over all previously reported maximum values. Maximum ZT value of 0.35 was obtained at 500?°C.

  19. Spatial density profile of electrons near the LaAlO{sub 3}/SrTiO{sub 3} heterointerface revealed by time-resolved photoluminescence spectroscopy

    SciTech Connect (OSTI)

    Yamada, Yasuhiro, E-mail: yamada.yasuhiro.6c@kyoto-u.ac.jp; Kanemitsu, Yoshihiko [Institute for Chemical Research, Kyoto University, Uji, Kyoto 611-0011 (Japan); Sato, Hiroki K. [SLAC National Accelerator Laboratory, Stanford Institute for Materials and Energy Sciences, Menlo Park, California 94025 (United States); Department of Advanced Materials Science, The University of Tokyo, Kashiwa, Chiba 277-8561 (Japan); Hikita, Yasuyuki [SLAC National Accelerator Laboratory, Stanford Institute for Materials and Energy Sciences, Menlo Park, California 94025 (United States); Hwang, Harold Y. [SLAC National Accelerator Laboratory, Stanford Institute for Materials and Energy Sciences, Menlo Park, California 94025 (United States); Geballe Laboratory for Advanced Materials, Department of Applied Physics, Stanford University, Stanford, California 94305 (United States)

    2014-04-14T23:59:59.000Z

    The depth profile of the electron density near the LaAlO{sub 3}/SrTiO{sub 3} heterointerface has been studied by means of time-resolved photoluminescence (PL) spectroscopy. A broad blue PL band is observed at 2.9?eV, originating from the two-carrier radiative recombination of interface-induced electrons and photoexcited holes. The PL lifetime of LaAlO{sub 3}/SrTiO{sub 3} heterointerface is dominated by the three-carrier Auger recombination of electrons and holes and is sensitive to electron density. We tuned the probing depth by changing the excitation photon energy and evaluated the carrier-density profile using the relation between the carrier density and the PL lifetime. Our non-contact probe method based on PL spectroscopy indicates that the carriers are confined within several nanometers in depth near the LaAlO{sub 3}/SrTiO{sub 3} heterostructures.

  20. Investigations of Ba{sub x}Sr{sub 1?x}TiO{sub 3} ceramics and powders prepared by direct current arc discharge technique

    SciTech Connect (OSTI)

    Li, Shuangbin; Wang, Xiaohan [Key Laboratory of Salt Lake Resources and Chemistry, Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining 810008 (China); University of Chinese Academy of Sciences, Beijing 100049 (China); Yao, Ying, E-mail: yaoy1125@hotmail.com; Jia, Yongzhong; Xie, Shaolei; Jing, Yan [Key Laboratory of Salt Lake Resources and Chemistry, Qinghai Institute of Salt Lakes, Chinese Academy of Sciences, Xining 810008 (China); Yuzyuk, Yu. I. [Faculty of Physics, Southern Federal University, 5, Zorge str., Rostov-on-Don 344090 (Russian Federation)

    2014-09-01T23:59:59.000Z

    Ba{sub x}Sr{sub 1?x}TiO{sub 3} ceramics with x ranging from 0 to 1 were prepared by direct current arc discharge technique and studied by means of x-ray diffraction (XRD) and Raman spectroscopy. The cubic-tetragonal ferroelectric phase transition in Ba{sub x}Sr{sub 1?x}TiO{sub 3} ceramics was found to occur at x???0.75. XRD investigation of as-grown BaTiO{sub 3} ceramics revealed co-existence of tetragonal and hexagonal modifications with a small amount of impurity phase BaTi{sub 4}O{sub 9}. No evidences of hexagonal phase were observed in Raman spectra of as-grown BaTiO{sub 3} ceramics, while Raman peaks related to hexagonal phase were clearly observed in the spectrum of fine-grain powders prepared from the same ceramics. A core-shell model for BaTiO{sub 3} ceramics prepared by direct current arc discharge technique is proposed. Absence of the hexagonal phase in any Ba{sub x}Sr{sub 1?x}TiO{sub 3} solid solution with x?

  1. METHOD FOR SIMULTANEOUS 90SR AND 137CS IN-VIVO MEASUREMENTS OF SMALL ANIMALS AND OTHER ENVIRONMENTAL MEDIA DEVELOPED FOR THE CONDITIONS OF THE CHERNOBYL EXCLUSION ZONE

    SciTech Connect (OSTI)

    Farfan, E.; Jannik, T.

    2011-10-01T23:59:59.000Z

    To perform in vivo simultaneous measurements of the {sup 90}Sr and {sup 137}Cs content in the bodies of animals living in the Chernobyl Exclusion Zone (ChEZ), an appropriate method and equipment were developed and installed in a mobile gamma beta spectrometry laboratory. This technique was designed for animals of relatively small sizes (up to 50 g). The {sup 90}Sr content is measured by a beta spectrometer with a 0.1 mm thick scintillation plastic detector. The spectrum processing takes into account the fact that the measured object is 'thick-layered' and contains a comparable quantity of {sup 137}Cs, which is a characteristic condition of the ChEZ. The {sup 137}Cs content is measured by a NaI scintillation detector that is part of the combined gamma beta spectrometry system. For environmental research performed in the ChEZ, the advantages of this method and equipment (rapid measurements, capability to measure live animals directly in their habitat, and the capability of simultaneous {sup 90}Sr and {sup 137}Cs measurements) far outweigh the existing limitations (considerations must be made for background radiation and the animal size, skeletal shape and body mass). The accuracy of these in vivo measurements is shown to be consistent with standard spectrometric and radiochemical methods. Apart from the in vivo measurements, the proposed methodology, after a very simple upgrade that is also described in the article, works even more accurately with samples of other media, such as soil and plants.

  2. [5] Suh JS, Jeong KS, Lee JS, Han IT. Study of the field-screening effect of highly ordered carbon nanotube arrays. Appl Phys Lett

    E-Print Network [OSTI]

    Chung, Deborah D.L.

    molecular weight polymer. The interfacial strength between carbon fillers and epoxy resin varies for improving and/or optimizing the manufacturing process of epoxy­matrix composites. Epoxy resin filled with various carbons (carbon fiber, carbon nanofiber and carbon black) was studied. The epoxy resin system

  3. Stoichiometry dependence of potential screening at La ( 1 - ? ) Al ( 1 + ? ) O 3 / SrTiO 3 interfaces

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Weiland, Conan; Sterbinsky, George E.; Rumaiz, Abdul K.; Hellberg, C. Stephen; Woicik, Joseph C.; Zhu, Shaobo; Schlom, Darrell G.

    2015-04-01T23:59:59.000Z

    Hard x-ray photoelectron spectroscopy (HAXPES) and variable kinetic energy x-ray photoelectron spectroscopy (VKE-XPS) analyses have been performed on ten-unit-cell-thick La(1-?)Al(1+?)O? films, with La:Al ratios of 1.1, 1.0, and 0.9, deposited on SrTiO?. Only Al-rich films are known to have a conductive interface. VKE-XPS, coupled with maximum entropy analysis, shows significant differences in the compositional depth profile among the Al-rich, La-rich, and stoichiometric films: significant La enrichment at the interface is observed in the La-rich and stoichiometric films, while the Al-rich film shows little to no intermixing. Additionally, the La-rich and stoichiometric films show a high concentration of Al at the surface, which is not observed in the Al-rich film. HAXPES valence band (VB) analysis shows a broadening of the VB for the Al-rich sample relative to the stoichiometric and La-rich samples. This broadening is consistent with an electric field across the Al-rich film. These results are consistent with a defect-driven electronic reconstruction.

  4. Carrier contribution to the specific heat coefficient of Sr 1 ? x K x Fe 1 ? x As 2

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wei, F. Y.; Lv, B.; Chen, F.; Xue, Y. Y.; Chu, C. W.

    2011-01-01T23:59:59.000Z

    The carrier contribution to the specific heat coefficient, Ce/T, of Sr1-xKxFe1-xAs? with 0?x?1 has been determined. The Ce/T at the optimal doping level appears to be T-independent above the superconducting transition temperature Tc. Systematic reductions and increases with cooling below 100 K, on the other hand, characterize the underdoped and overdoped samples, respectively. As the result, the low-T limit of the normal-state Ce/T increases almost linearly with x by a factor of 3 over 0 ?x?1. However, the Ce/T suppression across the magnetostructure transition of the underdoped samples is actually negligibly small. In particular, the extracted ?H-?L at x=0, which should include all suppression effects, is comparable to or even smaller than that of x=0.15, where ?H and ?L are the high- and low-T limits of the normal-state Ce/T. Therefore, it appears that, while the magnetostructure transition still plays a role, it may not be the main factor behind the Ce/T evolution.

  5. Spin and orbital Ti magnetism at LaMnO3/SrTiO3 interfaces

    SciTech Connect (OSTI)

    Garcial-Barriocanal, J [Universidad Complutense, Spain; Cezar, J. C. [European Synchrotron Radiation Facility (ESRF); Bruno, F. Y. [Universidad Complutense, Spain; Thakur, P. [European Synchrotron Radiation Facility (ESRF); Brookes, N. B. [European Synchrotron Radiation Facility (ESRF); Utfeld, C. [University of Bristol, UK; Riviera-Calzada, A. [Universidad Complutense, Spain; Giblin, S. R. [ISIS Facility, Rutherford Appleton Laboratory; Taylor, J. W. [ISIS Facility, Rutherford Appleton Laboratory; Duffy, J. A. [University of Warwick, UK; Dugdale, S. B. [University of Bristol, UK; Nakamura, T. [Japan Synchrotron Radiation Research Institute, SPring-8; Kodama, K. [Japan Synchrotron Radiation Research Institute, SPring-8; Leon, C. [Universidad Complutense, Spain; Okamoto, Satoshi [ORNL; Santamaria, J. [Universidad Complutense, Spain

    2010-01-01T23:59:59.000Z

    In systems with strong electron-lattice coupling, such as manganites, orbital degeneracy is lifted, what causes a null expectation value of the orbital moment. Magnetic structure is thus determined by spin-spin superexchange. In titanates, however, with much smaller Jahn-Teller distortions, orbital degeneracy might allow non-zero values of the orbital magnetic moment. Accordingly, novel forms of ferromagnetic superexchange interaction unique to t2g electrons systems have been theoretically predicted, although their experimental observation has remained elusive. Here we report a new kind of Ti3+ ferromagnetism at LaMnO3/SrTiO3 epitaxial interfaces. It results from charge transfer to the empty conduction band of the titanate and has spin and orbital contributions evidencing the role played by orbital degeneracy. The possibility of tuning magnetic alignment (ferromagnetic or antiferromagnetic) of Ti and Mn moments by structural parameters is demonstrated. This result will provide important clues for the understanding of the effects of orbital degeneracy in superexchange coupling.

  6. Tunable electronic structure in dilute magnetic semiconductor Sr{sub 3}SnO/c-YSZ/Si (001) epitaxial heterostructures

    SciTech Connect (OSTI)

    Lee, Y. F.; Narayan, J.; Schwartz, J. [Department of Materials Science and Engineering, North Carolina State University, 911 Partners Way, Raleigh, North Carolina 27695-7907 (United States)

    2014-10-28T23:59:59.000Z

    We report a systematic study of the structural, physical, and chemical properties of epitaxial thin films of emerging dilute magnetic semiconductor (DMS) Sr{sub 3}SnO (SSO) integrated with Si (100) prepared by various post-growth annealing treatments. The transport properties of these films are primarily governed by oxygen vacancies and the results are explained with the variable-range hopping model. The increased oxygen vacancy concentration generated by post-growth vacuum annealing results in a shorter hopping distance and reduced hopping energy and Coulomb gap, leading to lower resistivity; oxygen annealing shows the opposite effects. The work function ranges from 4.54 to 4.02?eV and shows a negative linear relationship with oxygen vacancy concentration, accompanied by a 0.42?eV shift in the surface Fermi level. The transport and ultraviolet photoelectron spectroscopy probes agree quantitatively on measurement of the resistivity and surface electronic structure. The results provide a direct and consistent explanation that the property changes in the bulk and at the surface are primarily attributed to oxygen vacancies, which are believed to be the carriers in the SSO thin films. The ability to manipulate the work function and oxygen vacancy concentration in epitaxial DMS SSO thin films offers great potential for the development of spintronic devices.

  7. Heavy d-electron Quasiparticle Interference and Real-space Electronic Structure of Sr3Ru2O7

    SciTech Connect (OSTI)

    Lee, J.; Allan, M.P.; Wang, M.A.; Farrell, J.; Grigera, S.A.; Baumberger, F.; Davis, J.C.; Mackenzie, A.P.

    2009-09-13T23:59:59.000Z

    The intriguing idea that strongly interacting electrons can generate spatially inhomogeneous electronic liquid-crystalline phases is over a decade old, but these systems still represent an unexplored frontier of condensed-matter physics. One reason is that visualization of the many-body quantum states generated by the strong interactions, and of the resulting electronic phases, has not been achieved. Soft condensed-matter physics was transformed by microscopies that enabled imaging of real-space structures and patterns. A candidate technique for obtaining equivalent data in the purely electronic systems is spectroscopic imaging scanning tunnelling microscopy (SI-STM). The core challenge is to detect the tenuous but 'heavy' momentum (k)-space components of the many-body electronic state simultaneously with its real-space constituents. Sr{sub 3}Ru{sub 2}O{sub 7} provides a particularly exciting opportunity to address these issues. It possesses a very strongly renormalized 'heavy' d-electron Fermi liquid and exhibits a field-induced transition to an electronic liquid-crystalline phase. Finally, as a layered compound, it can be cleaved to present an excellent surface for SI-STM.

  8. The Scattering Polarization of the Sr I 4607 ÅLine at the Diffraction Limit Resolution of a 1-m Telescope

    E-Print Network [OSTI]

    Javier Trujillo Bueno; Nataliya Shchukina

    2007-06-15T23:59:59.000Z

    One of the greatest challenges in solar and stellar physics in coming years will be to observe the Second Solar Spectrum with a spatial resolution significantly better than 1 arcsec. This type of scattering polarization observations would probably allow us to discover hitherto unknown aspects of the Sun's hidden magnetism. Here we report on some theoretical predictions for the photospheric line of Sr I at 4607 \\AA, which we have obtained by solving the three-dimensional (3D) radiative transfer problem of scattering line polarization in a realistic hydrodynamical model of the solar photosphere. We have taken into account not only the anisotropy of the radiation field in the 3D medium and the Hanle effect of a tangled magnetic field, but also the symmetry breaking effects caused by the horizontal atmospheric inhomogeneities produced by the solar surface convection. Interestingly, the Q/I and U/I linear polarization signals of the emergent spectral line radiation have sizable values and fluctuations, even at the very center of the solar disk where we meet the forward scattering case. The ensuing small-scale patterns in Q/I and U/I turn out to be sensitive to the assumed magnetic field model, and are of great diagnostic value. We argue that it should be possible to observe them with the help of a 1-m telescope equipped with adaptive optics and a suitable polarimeter.

  9. A novel yellow-emitting SrAlSi{sub 4}N{sub 7}:Ce{sup 3+} phosphor for solid state lighting: Synthesis, electronic structure and photoluminescence properties

    SciTech Connect (OSTI)

    Ruan, Jian [Sialon Group, Sialon Unit, Environment and Energy Materials Division, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Laboratory of Glasses and Nanostructured Functional Materials, 122 Luoshi Road, Wuhan, Hubei 430070 (China); Xie, Rong-Jun, E-mail: Xie.Rong-Jun@nims.go.jp [Sialon Group, Sialon Unit, Environment and Energy Materials Division, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Funahashi, Shiro [Sialon Group, Sialon Unit, Environment and Energy Materials Division, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Tanaka, Yoshinori [Green Computational Materials Science Group, Global Research Center for Environment and Energy based on Nanomaterials Science (Green), National Institute for Materials Science (NIMS), 1-2-1 Sengen, Tsukuba, Ibaraki 305-0044 (Japan); Takeda, Takashi; Suehiro, Takayuki; Hirosaki, Naoto [Sialon Group, Sialon Unit, Environment and Energy Materials Division, National Institute for Materials Science, 1-1 Namiki, Tsukuba, Ibaraki 305-0044 (Japan); Li, Yuan-Qiang [Dow Electronic Materials, 201 Washington Road, Princeton, NJ 08540 (United States)

    2013-12-15T23:59:59.000Z

    Ce{sup 3+}-doped and Ce{sup 3+}/Li{sup +}-codoped SrAlSi{sub 4}N{sub 7} phosphors were synthesized by gas pressure sintering of powder mixtures of Sr{sub 3}N{sub 2}, AlN, ?-Si{sub 3}N{sub 4}, CeN and Li{sub 3}N. The phase purity, electronic crystal structure, photoluminescence properties of SrAlSi{sub 4}N{sub 7}:Ce{sup 3+}(Ce{sup 3+}/Li{sup +}) were investigated in this work. The band structure calculated by the DMol{sup 3} code shows that SrAlSi{sub 4}N{sub 7} has a direct band gap of 3.87 eV. The single crystal analysis of Ce{sup 3+}-doped SrAlSi{sub 4}N{sub 7} indicates a disordered Si/Al distribution and nitrogen vacnacy defects. SrAlSi{sub 4}N{sub 7} was identified as a major phase of the fired powders, and Sr{sub 5}Al{sub 5}Si{sub 21}N{sub 35}O{sub 2} and AlN as minor phases. Both Ce{sup 3+} and Ce{sup 3+}/Li{sup +} doped SrAlSi{sub 4}N{sub 7} phosphors can be efficiently excited by near-UV or blue light and show a broadband yellow emission peaking around 565 nm. A highest external quantum efficiency of 38.3% under the 450 nm excitation was observed for the Ce{sup 3+}/Li{sup +}-doped SrAlSi{sub 4}N{sub 7} (5 mol%). A white light LED lamp with color temperature of 6300 K and color rendering index of Ra=78 was achieved by combining Sr{sub 0.97}Al{sub 1.03}Si{sub 3.997}N/94/maccounttest14=t0005{sub 1}8193 {sub 7}:Ce{sup 3+}{sub 0.03} with a commercial blue InGaN chip. It indicates that SrAlSi{sub 4}N{sub 7}:Ce{sup 3+} is a promising yellow emitting down-conversion phosphor for white LEDs. - Graphical abstract: One-phosphor converted white light-emitting diode (LED) was fabricated by combining a blue LED chip and a yellow-emitting SrAlSi4N7:Ce{sup 3+} phosphor (see inset), which has the color rendering index of 78 and color temperature of 6300 K. - Highlights: • We reported a new yellow nitride phosphor suitable for solid state lighting. • We solved the crystal structure and evidenced a disordered Si/Al distribution. • We fabricated a high color rendering white LEDs by using a single SrAlSi4N7:Ce.

  10. Improvement of the physical properties of novel (1 ? y) Co{sub 0.8}Cu{sub 0.2}Fe{sub 2}O{sub 4} + (y) SrTiO{sub 3} nanocomposite

    SciTech Connect (OSTI)

    Ahmed, M.A., E-mail: moala47@hotmail.com [Materials Science Lab (1), Physics Department, Faculty of Science, Cairo University, Giza (Egypt); Mansour, S.F.; Abdo, M.A. [Physics Department, Faculty of Science, Zagazig University (Egypt)

    2013-05-15T23:59:59.000Z

    Graphical abstract: The ME coefficient as a function of magnetic field for the composites (1 ? y) Co{sub 0.8}Cu{sub 0.2}Fe{sub 2}O{sub 4} + (y) SrTiO{sub 3} (y = 40, 50, 60 and 80%). Highlights: ? T{sub C} and M{sub s} decrease with the increase of SrTiO{sub 3} concentration. ? The P–E hysteresis loops were observed for all compositions. ? The maximum ME coefficient was observed for the composite with 60% SrTiO{sub 3}. - Abstract: Magnetoelectric (ME) nanocomposites (1 ? y) Co{sub 0.8}Cu{sub 0.2}Fe{sub 2}O{sub 4} + (y) SrTiO{sub 3} (y = 40, 50, 60, 80 and 100%) were prepared by standard ceramic method. Phase formation was checked using X-ray diffraction analysis. Both saturation magnetization (M{sub s}) and Curie temperature (T{sub C}) decrease with increasing SrTiO{sub 3} content. Temperature dependence of the dielectric constant reveals two maxima, one about 550 K corresponds to non-stoichiometry and lattice distortions while the second around 900 K corresponds to the Curie temperature (T{sub C}). The large value of ME output is due to the strain induced by lattice distortion in the ferrite phase by Jahn–Teller ions like Cu. Hence, Jahn–Teller effect in the ferrite leads to polarization in the piezoelectric phase.

  11. Probing local structure in the yellow phosphor LaSr[subscript 2]AlO[subscript 5]:Ce[superscript 3+], by the maximum entropy method and pair distribution function analysis

    SciTech Connect (OSTI)

    Im, Won Bin; Page, Katharine; DenBaars, Steven P.; Seshadri, Ram (UCSB); (LANL)

    2011-08-04T23:59:59.000Z

    The compound LaSr{sub 2}AlO{sub 5} was recently introduced as a competitive Ce{sup 3+} host material for blue-pumped yellow phosphors for use in white light emitting diodes. A crucial feature of the crystal structure of LaSr{sub 2}AlO{sub 5} is that La, which is the host site for Ce{sup 3+}, is located in the 8h positions of the I4/mcm crystal structure, a site equally shared with Sr. While the average crystal structure of LaSr{sub 2}AlO{sub 5} as revealed by Rietveld analysis of laboratory and synchrotron X-ray diffraction data suggests nothing untoward, maximum entropy method analysis of the synchrotron X-ray data reveals the existence of conspicuous non-sphericity of the electron density. Pair distribution function analysis of the data suggests that despite their occupying the same crystallographic site, La and Sr possess distinct coordination environments, and the environment around La is more compact and regular than the environment suggested by the Rietveld refinement of the average structure. The absorption and emission from Ce{sup 3+} centers is controlled by the local coordination and symmetry, and the use of powerful new tools in unraveling details of these strengthens the rational search for new phosphors for solid state white lighting.

  12. Itinerant electrons, local moments, and magnetic correlations in the pnictide superconductors CeFeAsO??xFxand Sr(Fe??xCox)?As?

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Vilmercati, Paolo; Fedorov, Alexei; Bondino, Federica; Offi, Francesco; Panaccione, Giancarlo; Lacovig, Paolo; Simonelli, Laura; McGuire, Michael A.; Sefat, Athena S. M.; Mandrus, David; Sales, Brian C.; Egami, Takeshi; Ku, Wei; Mannella, Norman

    2012-06-01T23:59:59.000Z

    A direct and element-specific measurement of the local Fe spin moment has been provided by analyzing the Fe 3s core level photoemission spectra in the parent and optimally doped CeFeAsO??xFx (x = 0, 0.11) and Sr(Fe??xCox)2As2 (x = 0, 0.10) pnictides. The rapid time scales of the photoemission process allowed the detection of large local spin moments fluctuating on a 10?¹? s time scale in the paramagnetic, antiferromagnetic, and superconducting phases, indicative of the occurrence of ubiquitous strong Hund's magnetic correlations. The magnitude of the spin moment is found to vary significantly among different families, 1.3?B in CeFeAsO and 2.1?B in SrFe?As?. Surprisingly, the spin moment is found to decrease considerably in the optimally doped samples, 0.9?B in CeFeAsO?.??F?.?? and 1.3?B in Sr(Fe?.?Co?.?)?As?. The strong variation of the spin moment against doping and material type indicates that the spin moments and the motion of itinerant electrons are influenced reciprocally in a self-consistent fashion, reflecting the strong competition between the antiferromagnetic superexchange interaction among the spin moments and the kinetic energy gain of the itinerant electrons in the presence of a strong Hund's coupling. By describing the evolution of the magnetic correlations concomitant with the appearance of superconductivity, these results constitute a fundamental step toward attaining a correct description of the microscopic mechanisms shaping the electronic properties in the pnictides, including magnetism and high-temperature superconductivity.

  13. Magnetic structure of Sr{sub 2}Fe{sub 2}O{sub 5} brownmillerite by single-crystal Mössbauer spectroscopy

    SciTech Connect (OSTI)

    Waerenborgh, J.C. [UCQR, IST/ITN, Instituto Superior Técnico, Universidade Técnica de Lisboa, CFMC-UL, Estrada Nacional 10, 2686-953 Sacavém (Portugal); Tsipis, E.V. [UCQR, IST/ITN, Instituto Superior Técnico, Universidade Técnica de Lisboa, CFMC-UL, Estrada Nacional 10, 2686-953 Sacavém (Portugal); Department of Materials and Ceramic Engineering, CICECO, University of Aveiro, 3810-193 Aveiro (Portugal); Auckett, J.E.; Ling, C.D. [School of Chemistry, The University of Sydney, Sydney 2006 (Australia); Kharton, V.V., E-mail: kharton@ua.pt [Department of Materials and Ceramic Engineering, CICECO, University of Aveiro, 3810-193 Aveiro (Portugal); Institute of Solid State Physics RAS, Chernogolovka 142432, Moscow Region (Russian Federation)

    2013-09-15T23:59:59.000Z

    In order to determine orientation of the Fe{sup 3+} magnetic moments and electric field gradient (efg) axes in the brownmillerite-type strontium ferrite structure for both iron sublattices where the efg tensor is not axially symmetric, the Mössbauer spectra of powdered and oriented single-crystal Sr{sub 2}Fe{sub 2}O{sub 5} were analyzed by solving the complete Hamiltonian for hyperfine interactions in the excited and ground states of the {sup 57}Fe nuclei. The magnetic moments of both octahedrally and tetrahedrally coordinated iron cations lie on the ac-plane of the orthorhombic unit cell and are parallel to the shortest c-axis, whilst the main efg axes are parallel to the longest crystallographic axis, b. This orientation is similar to that in Ca{sub 2}Fe{sub 2}O{sub 5}, in spite of the structural differences of strontium and calcium ferrite brownmillerites at low temperatures. - Graphical abstract: Mössbauer spectra of powdered and oriented single-crystal Sr{sub 2}Fe{sub 2}O{sub 5}, analyzed by solving the complete Hamiltonian for hyperfine interactions in the excited and ground states of the {sup 57}Fe nuclei, show that the magnetic moments of both octahedrally and tetrahedrally coordinated iron cations are parallel to the shortest c-axis of the orthorhombic brownmillerite unit cell . Display Omitted - Highlights: • Single-crystal Mössbauer spectroscopy is used to study magnetic structure of Sr{sub 2}Fe{sub 2}O{sub 5}. • Complete Hamiltonian for hyperfine interactions in excited and ground states was solved. • Fe{sup 3+} magnetic moments are parallel to the shortest crystallographic axis c. • The orientation of nuclear electric field gradient is similar to that in Ca{sub 2}Fe{sub 2}O{sub 5}.

  14. Reinterpretation of Rb/Sr isotopic data for the Little Elk Granite: Implications for the timing of deformational events, Black Hills, South Dakota

    SciTech Connect (OSTI)

    Dahl, P.S.; Gardner, E.T.; Holm, D.K. (Kent State Univ., OH (United States). Dept. of Geology)

    1993-04-01T23:59:59.000Z

    Early Proterozoic rift sediments in the Black Hills were multiply deformed (into refolded nappe structures) during the Trans-Hudson Orogeny, which culminated in Harney Peak Granite (HPG) emplacement at 1,715--1,697 Ma. A reset whole-rock Rb/Sr age of 1,840 [+-] 70 Ma obtained from the Archean (2,549 [+-] 11 Ma) Little Elk Granite (LEG, Zartman and Stern, 1967) is widely interpreted as being coeval with D2, based upon parallelism of gneissic foliation in the granite and F2 foliation predominant elsewhere in the Black Hills. However, the authors have recalculated the whole-rock Rb/Sr age by applying the IUGS-recommended [sup 87]Rb decay constant (Steiger and Jager, 1977) to the original isotopic data, obtaining a revised age of 1,905 [+-] 59 Ma. The authors interpret this age as representing a whole-rock isotopic resetting event associated with Early Proterozoic (2,170--1,880 Ma) rifting in the Black Hills. The authors envision the LEG to have experienced a convective hydrothermal fluid-flow regime associated with the rifting. This scenario would allow for the sustained heating and isotopic exchange between granite and abundant water-rich fluid (seawater ) that would be required to effect complete resetting of an Rb/Sr whole-rock isochron. They favor an age for the refolding event and the development of F2 structures that is more closely linked in time with HPG emplacement. Such an age is more compatible with published field/petrologic observations and Proterozoic tectonothermal models for the Black Hills.

  15. Itinerant electrons, local moments, and magnetic correlations in the pnictide superconductors CeFeAsO??xFxand Sr(Fe??xCox)?As?

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Vilmercati, Paolo; Fedorov, Alexei; Bondino, Federica; Offi, Francesco; Panaccione, Giancarlo; Lacovig, Paolo; Simonelli, Laura; McGuire, Michael A.; Sefat, Athena S. M.; Mandrus, David; et al

    2012-06-01T23:59:59.000Z

    A direct and element-specific measurement of the local Fe spin moment has been provided by analyzing the Fe 3s core level photoemission spectra in the parent and optimally doped CeFeAsO??xFx (x = 0, 0.11) and Sr(Fe??xCox)2As2 (x = 0, 0.10) pnictides. The rapid time scales of the photoemission process allowed the detection of large local spin moments fluctuating on a 10?¹? s time scale in the paramagnetic, antiferromagnetic, and superconducting phases, indicative of the occurrence of ubiquitous strong Hund's magnetic correlations. The magnitude of the spin moment is found to vary significantly among different families, 1.3?B in CeFeAsO and 2.1?Bmore »in SrFe?As?. Surprisingly, the spin moment is found to decrease considerably in the optimally doped samples, 0.9?B in CeFeAsO?.??F?.?? and 1.3?B in Sr(Fe?.?Co?.?)?As?. The strong variation of the spin moment against doping and material type indicates that the spin moments and the motion of itinerant electrons are influenced reciprocally in a self-consistent fashion, reflecting the strong competition between the antiferromagnetic superexchange interaction among the spin moments and the kinetic energy gain of the itinerant electrons in the presence of a strong Hund's coupling. By describing the evolution of the magnetic correlations concomitant with the appearance of superconductivity, these results constitute a fundamental step toward attaining a correct description of the microscopic mechanisms shaping the electronic properties in the pnictides, including magnetism and high-temperature superconductivity.« less

  16. Optimization of growth conditions of Bi?CaSr?Cu?O??x? superconducting films on NdGaO? substrates by LPE technique and their characterization

    E-Print Network [OSTI]

    Solayappan, Narayanan

    1991-01-01T23:59:59.000Z

    ? Zurich University of Tokyo LaBaCuO (under pressure) superconducting at 40 K University of Houston January 1987 February 1987 May 1987 October 1987 Lanthanum strontium copper oxide su erconductin at 36 K LaBaCuO supcrconducting at 70K Yurium... superconducting compounds discovered so far, the Bismuth-Calcium-Strontium-Copper-Oxide superconducting compound is an important family. This compound exists in three Phases as exPressed by the chemical formula Bi2CanSr2Cu?+tOS+x where n=l, 2 and 3...

  17. A neutron diffraction study of the magnetic structure for the perovskite-type mixed oxides La(Mn, Cr)03 and (La, Sr)Fe03

    E-Print Network [OSTI]

    Bents, Ulrich H.

    1956-01-01T23:59:59.000Z

    A NEUTRON DIFFRACTION STUDY OF THE MAGNETIC STRUCTURE FOR THE PEROVSKITE-TYPE MIXED OXIDES La(Mn,Cr)03 AND (La,Sr)Fe03 A Dissertation By ULRICH H. BENTS Submitted to the Graduate School of the Agricultural and Mechanical College of Texas... in partial fulfillment of the requirements for the degree of DOCTOR OF PHILOSOPHY May 1956 Major Subjectj Physics l i b r a r y l A i braayb?y r? ???l? A NEUTRON DIFFRACTION STUDY OF THE MAGNETIC STRUCTURE FOR THE PEROVSKITE-TYPE MIXED OXIDES La...

  18. Magneto-transport in LaTi{sub 1?x}Mn{sub x}O{sub 3}/SrTiO{sub 3} oxide heterostructures

    SciTech Connect (OSTI)

    Kumar, Pramod, E-mail: pramodnpl2011@gmail.com; Dogra, Anjana, E-mail: pramodnpl2011@gmail.com; Budhani, R. C., E-mail: pramodnpl2011@gmail.com [Quantum Phenomena and Applications Division, National Physical Laboratory (CSIR), Dr. K.S. Krishnan Marg, New Delhi-110012 (India)

    2014-04-24T23:59:59.000Z

    We report the growth of ultrathin film of Mn doped LaTiO{sub 3} on TiO{sub 2} terminated SrTiO{sub 3} (001) substrate by pulsed laser deposition (PLD) and their electrical transport characteristics including magnetoresistance (MR). Though the replacement of Mn in LaTiO{sub 3} at the Ti site in dilute limit does not affect the metallic behaviour of films but variation in resistance is observed. Normalised resistance behaviour is explained on the basis of variation in charge carriers and increased interaction between Mn atoms in the system under investigation.

  19. Sequestration of Sr-90 Subsurface Contamination in the Hanford 100-N Area by Surface Infiltration of a Ca-Citrate-Phosphate Solution

    SciTech Connect (OSTI)

    Szecsody, James E.; Rockhold, Mark L.; Oostrom, Martinus; Moore, R. C.; Burns, Carolyn A.; Williams, Mark D.; Zhong, Lirong; Fruchter, Jonathan S.; McKinley, James P.; Vermeul, Vincent R.; Covert, Matthew A.; Wietsma, Thomas W.; Breshears, Andrew T.; Garcia, Ben J.

    2009-03-01T23:59:59.000Z

    The objective of this project is to develop a method to emplace apatite precipitate in the 100N vadose zone, which results in sorption and ultimately incorporation of Sr-90 into the apatite structure. The Ca-citrate-PO4 solution can be infiltrated into unsaturated sediments to result in apatite precipitate to provide effective treatment of Sr-90 contamination. Microbial redistribution during solution infiltration and a high rate of citrate biodegradation for river water microbes (water used for solution infiltration) results in a relatively even spatial distribution of the citrate biodegradation rate and ultimately apatite precipitate in the sediment. Manipulation of the Ca-citrate-PO4 solution infiltration strategy can be used to result in apatite precipitate in the lower half of the vadose zone (where most of the Sr-90 is located) and within low-K layers (which are hypothesized to have higher Sr-90 concentrations). The most effective infiltration strategy to precipitate apatite at depth (and with sufficient lateral spread) was to infiltrate a high concentration solution (6 mM Ca, 15 mM citrate, 60 mM PO4) at a rapid rate (near ponded conditions), followed by rapid, then slow water infiltration. Repeated infiltration events, with sufficient time between events to allow water drainage in the sediment profile can be used to buildup the mass of apatite precipitate at greater depth. Low-K heterogeneities were effectively treated, as the higher residual water content maintained in these zones resulted in higher apatite precipitate concentration. High-K zones did not receive sufficient treatment by infiltration, although an alternative strategy of air/surfactant (foam) was demonstrated effective for targeting high-K zones. The flow rate manipulation used in this study to treat specific depths and heterogeneities are not as easy to implement at field scale due to the lack of characterization of heterogeneities and difficulty tracking the wetting front over a large subsurface area. However, the use of real-time surface and cross-borehole geophysics can be used to track the infiltrating Ca-citrate-PO4 front so some adjustments can be made in the infiltration rate to precipitate apatite in desired zones. In addition, the reactive transport code used in this study with field scale physical parameters for sediments can be used to evaluate infiltration strategies along with preliminary water infiltration tests at field scale.

  20. Photorefractive properties of Ce- and Ca-doped Sr/sub 0. 6/Ba/sub 0. 4/Nb/sub 2/O/sub 6/

    SciTech Connect (OSTI)

    Rakuljic, G.A.; Sayano, K.; Agranat, A.; Yariv, A.; Neurgaonkar, R.R.

    1988-10-17T23:59:59.000Z

    We present the results of experimental study of the absorption coefficient, two-beam photorefractive coupling constant, and photorefractive response time of a doubly Ce- and Ca-doped Sr/sub 0.6/Ba/sub 0.4/Nb/sub 2/O/sub 6/. This crystal displays enhanced photorefractive response at near infrared wavelengths when compared to Ce-doped SBN:60. The temperature dependence of the coupling constant over the range from -30 to 40 /sup 0/C has also been studied.

  1. Giant magnetoresistance due to magnetoelectric currents in Sr{sub 3}Co{sub 2}Fe{sub 24}O{sub 41} hexaferrites

    SciTech Connect (OSTI)

    Wang, Xian [Department of Electrical and Computer Engineering, Center for Microwave Magnetic Materials and Integrated Circuits, Northeastern University, Boston, Massachusetts 02115 (United States); School of Optical and Electronic Information, Huazhong University of Science and Technology, Wuhan 430074 (China); Su, Zhijuan; Sokolov, Alexander; Hu, Bolin; Andalib, Parisa; Chen, Yajie, E-mail: y.chen@neu.edu; Harris, Vincent G. [Department of Electrical and Computer Engineering, Center for Microwave Magnetic Materials and Integrated Circuits, Northeastern University, Boston, Massachusetts 02115 (United States)

    2014-09-15T23:59:59.000Z

    The giant magnetoresistance and magnetoelectric (ME) effects of Z-type hexaferrite Sr{sub 3}Co{sub 2}Fe{sub 24}O{sub 41} were investigated. The present experiments indicated that an induced magnetoelectric current in a transverse conical spin structure not only presented a nonlinear behavior with magnetic field and electric field but also depended upon a sweep rate of the applied magnetic field. More interestingly, the ME current induced magnetoresistance was measured, yielding a giant room temperature magnetoresistance of 32.2% measured at low magnetic fields (?125?Oe). These results reveal great potential for emerging applications of multifunctional magnetoelectric ferrite materials.

  2. The features of structural transformations in lanthanum manganites La{sub 1?x}A{sub x}MnO{sub 3+?} (A = Ca, Sr, Ba)

    SciTech Connect (OSTI)

    Sedykh, Vera D., E-mail: sedykh@issp.ac.ru [Institute of Solid State Physics, Russian Academy of Sciences, Chernogolovka (Russian Federation)

    2014-10-27T23:59:59.000Z

    In this work, the effect of the ionic radius and concentration of a doping element on the features of the structural transformations in polycrystalline lanthanum manganites, La{sub 1?x}A{sub x}MnO{sub 3+?} (A = Ca, Sr, Ba), has been studied by Mössbauer spectroscopy and X-ray diffraction analysis. For Mössbauer investigations, a small amount of {sup 57}Fe (2 at%) Mössbauer isotope was introduced into the samples. It follows from the analysis of the obtained data that both common features of the structural transformations and differences between them exist in lanthanum manganites depending on ionic radius and concentration of a doping element.

  3. SrAgZn and EuAgZn with KHg{sub 2}-type structure—Structure, magnetic properties, and {sup 151}Eu Mössbauer spectroscopy

    SciTech Connect (OSTI)

    Gerke, Birgit; Rodewald, Ute Ch.; Niehaus, Oliver; Pöttgen, Rainer, E-mail: pottgen@uni-muenster.de

    2013-07-15T23:59:59.000Z

    Samples of SrAgZn and EuAgZn were synthesized by reaction of the elements in sealed tantalum crucibles. Both structures were refined on the basis of single crystal X-ray diffractometer data: KHg{sub 2}-type, Imma, a=476.7(1), b=780.9(2), c=810.1(2) pm, R{sub 1}/wR{sub 2}=0.0189/0.0119, 381 F² values for SrAg{sub 1.12}Zn{sub 0.88} and a=474.43(9), b=760.8(2), c=799.0(2) pm, R{sub 1}/wR{sub 2}=0.0226/0.0483, 370 F² values for EuAg{sub 1.17}Zn{sub 0.83} with 13 variables per refinement. Silver and zinc are randomly distributed on the Hg position and build up three-dimensional networks. EuAgZn shows ferromagnetic ordering at 29(1) K. In the temperature range from 75 to 300 K the sample shows Curie–Weiss behaviour with ?{sub eff}=7.87(1) ?{sub B}/Eu atom and ?{sub P}=37.1(1) K, indicating divalent europium. {sup 151}Eu Mössbauer spectroscopic measurements confirmed the divalent state with an isomer shift of ?9.31 mm/s at 78 K. Temperature dependent {sup 151}Eu data show first magnetic hyperfine field splitting at 25 K and a saturated magnetization of 17 T at 5.2 K. The temperature dependence can be described by an S=7/2 Brillouin function. - Graphical abstract: The near neighbor coordination of the strontium and europium atoms in SrAg{sub 1.12}Zn{sub 0.88}, EuAg{sub 1.17}Zn{sub 0.83}, and EuAuZn. - Highlights: • Synthesis of new intermetallic zinc compounds SrAgZn and EuAgZn. • Ferromagnetic ordering of EuAgZn at 29 K. • Magnetic hyperfine field splitting in the {sup 151}Eu Mössbauer spectrum.

  4. Effects of Nb doping level on the electronic transport, photoelectric effect and magnetoresistance across La{sub 0.5}Ca{sub 0.5}MnO{sub 3}/Nb:SrTiO{sub 3} junctions

    SciTech Connect (OSTI)

    Wang, J. F., E-mail: jifewang@gmail.com [Department of Physics, The University of Hong Kong, Pokfulam Road (Hong Kong); College of Science, China Jiliang University, Hangzhou, Zhejiang 310018 (China); Jiang, Y. C.; Gao, J., E-mail: jugao@hku.hk [Department of Physics, The University of Hong Kong, Pokfulam Road (Hong Kong); Chen, M. G. [College of Science, China Jiliang University, Hangzhou, Zhejiang 310018 (China)] [College of Science, China Jiliang University, Hangzhou, Zhejiang 310018 (China)

    2013-12-16T23:59:59.000Z

    Heterojunctions composed of La{sub 0.5}Ca{sub 0.5}MnO{sub 3} and Nb doped SrTiO{sub 3} were fabricated, and the effects of the Nb doping level on their electronic transport, photoelectric effect, and magnetoresistance were investigated. A lower doping concentration of Nb led to better rectifying properties and higher open circuit voltages. The I-V curves for La{sub 0.5}Ca{sub 0.5}MnO{sub 3}/0.7?wt.?% Nb-SrTiO{sub 3} showed a negligible response to magnetic fields for all temperatures, whereas La{sub 0.5}Ca{sub 0.5}MnO{sub 3}/0.05?wt.?% Nb-SrTiO{sub 3} exhibited distinct magnetoresistance, which depended on both the bias voltage and temperature. These results are discussed with the assistance of conventional semiconductor theories.

  5. Crystal structure, oxidation state and magnetism of Sr{sub x}La{sub 2?x}Cu{sub 0.5}Ru{sub 0.5}O{sub 4} (x=1, 1.5)

    SciTech Connect (OSTI)

    Lü, Minfeng, E-mail: m.f.lv@ciac.jl.cn [State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022 (China); Deng, Xiaolong [State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022 (China); Waerenborgh, João C. [IST/ITN, Instituto Superior Técnico, Univ Técnica de Lisboa, CFMC-UL, EN 10, 2686-953 Sacavém (Portugal); Wu, Xiaojie [State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022 (China); Meng, Jian, E-mail: jmeng@ciac.jl.cn [State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun 130022 (China)

    2014-03-15T23:59:59.000Z

    Sr{sub x}La{sub 2?x}Cu{sub 0.5}Ru{sub 0.5}O{sub 4} (x=1, 1.5) oxides with K{sub 2}NiF{sub 4}-type structure were prepared by solid state reaction and characterized by powder X-ray diffraction, X-ray photoelectron spectroscopy, magnetic and electrical resistivity measurements. The SrLaCu{sub 0.5}Ru{sub 0.5}O{sub 4} phase was obtained for the first time with a negligible amount of impurities. The octahedral Cu/RuO{sub 6} units are more elongated in SrLaCu{sub 0.5}Ru{sub 0.5}O{sub 4} than in Sr{sub 1.5}La{sub 0.5}Cu{sub 0.5}Ru{sub 0.5}O{sub 4} indicating a greater extent of static Jahn–Teller distortion. XPS suggests that mixed ion pairs Ru{sup 5+}/Ru{sup 4+}?Cu{sup +}/Cu{sup 2+} are present in SrLaCu{sub 0.5}Ru{sub 0.5}O{sub 4}, while Ru remains as Ru{sup 5+} and Cu as Cu{sup 2+} in Sr{sub 1.5}La{sub 0.5}Cu{sub 0.5}Ru{sub 0.5}O{sub 4}. Both samples show spin-glass behavior, which can be explained by competition between ferromagnetic and antiferromagnetic superexchange interactions. The negative Weiss temperature estimated for SrLaCu{sub 0.5}Ru{sub 0.5}O{sub 4}, ?318 K, is significantly lower than ?11.5 K deduced for Sr{sub 1.5}La{sub 0.5}Cu{sub 0.5}Ru{sub 0.5}O{sub 4} which may be related to the higher static Jahn–Teller distortion in the former oxide. -- Graphical abstract: SrLaCu{sub 0.5}Ru{sub 0.5}O{sub 4} with K{sub 2}NiF{sub 4}-type structure show a larger static Jahn–Teller distortion than Sr{sub 1.5}La{sub 0.5}Cu{sub 0.5}Ru{sub 0.5}O{sub 4}, which may be related to stronger antiferromagnetic superexchange interactions. Highlights: • SrLaCu{sub 0.5}Ru{sub 0.5}O{sub 4} (I) larger Jahn–Teller (J–T) distortion than Sr{sub 1.5}La{sub 0.5}Cu{sub 0.5}Ru{sub 0.5}O{sub 4} (II). • Octahedral Cu/RuO{sub 6} units are more elongated in I than in II. • Mixed ion pairs Ru{sup 5+}/Ru{sup 4+}?Cu{sup +}/Cu{sup 2+} are present in I, while Ru remains as Ru{sup 5+} and Cu as Cu{sup 2+} in II. • Negative Weiss temperature of I significantly lower, consistent with higher J–T distortion.

  6. Microstructural and dielectric properties of Ba{sub 0.6}Sr{sub 0.4}Ti{sub 1-x}Zr{sub x}O{sub 3} based combinatorial thin film capacitors library

    SciTech Connect (OSTI)

    Liu Guozhen; Wolfman, Jerome; Autret-Lambert, Cecile; Sakai, Joe; Roger, Sylvain; Gervais, Monique; Gervais, Francois [Laboratoire d'Electrodynamique des Materiaux Avances (LEMA), UMR 6157 CNRS/CEA, Universite Francois Rabelais, Parc de Grandmont, 37200 Tours (France)

    2010-12-01T23:59:59.000Z

    Epitaxial growth of Ba{sub 0.6}Sr{sub 0.4}Ti{sub 1-x}Zr{sub x}O{sub 3} (0{<=}x{<=}0.3) composition spread thin film library on SrRuO{sub 3}/SrTiO{sub 3} layer by combinatorial pulsed laser deposition (PLD) is reported. X-ray diffraction and energy dispersive x-ray spectroscopy studies showed an accurate control of the film phase and composition by combinatorial PLD. A complex evolution of the microstructure and morphology with composition of the library is described, resulting from the interplay between epitaxial stress, increased chemical pressure, and reduced elastic energy upon Zr doping. Statistical and temperature-related capacitive measurements across the library showed unexpected variations in the dielectric properties. Doping windows with enhanced permittivity and tunability are identified, and correlated to microstructural properties.

  7. Fiscal year 1997 final report for task plan SR-16WT-31 task B, vitrification of ion exchange material

    SciTech Connect (OSTI)

    Ferrara, D.; Andrews, M.K.; Harbour, J.R.; Fellinger, T.L.; Herman, D.T.; Marshall, K.M.; Workman, P.J.

    1997-09-30T23:59:59.000Z

    In Fiscal Year 1997, the Department of Energy Tanks Focus Area (TFA) funded the Savannah River Technology Center (SRTC) to develop and demonstrate the vitrification of a CST ion exchange material loaded with radioactive cesium from one of the Melton Valley Storage Tanks at the Oak Ridge National Laboratory (ORNL). SRTC developed a patent-pending glass formulation that can be used to vitrify CST sorbent producing a quality borosilicate glass waste form. SRTC demonstrated this formulation by vitrifying the radioactive CST in the SRTC shielded cells melter.In addition to the formulation developed for vitrification of the `CST-only` glass waste form, SRTC also developed formulations for vitrification of CST coupled with High-Level Waste (HLW) sludges. A Defense Waste Processing Facility (DWPF) coupled feed formulation has been developed with up to 10 weight percent CST and 28 weight percent DWPF sludge oxides. A coupled Hanford formulation has also been developed for producing quality glass waste forms with up to 10 weight percent CST and 45 weight percent Hanford sludge oxides. The significant accomplishments of this project were then development of CST-only glass formulations incorporating up to 65 weight-percent CST, development of techniques for delivering a slurry or dry feed to a joule-heated melter, demonstration of a CST-only glass formulation in a continuous melter operation, demonstration of compliance with the Nevada Test Site (NTS) Waste Acceptance Criteria (WAC), development of CST-sludge glass formulations incorporating up to 10 weight percent CST and 28 weight percent DWPF sludges oxides, demonstration of CST-sludge glass formulations using radioactive sludge and radioactive CST, development of CST-sludge glass formulations incorporating up to 10 weight percent CST and 45 weight percent. All commitments made to the TFA have been met as indicated by the associated milestones. Milestones and the month in which they were completed: Initiate Immobilization of CST in Glass (completed 8/97); Demonstrate that Sludge-CST Glass Satisfied PC Specs in WAPS (completed 9/97); Determine Process Parameters of Sludge-CST Glass (completed 8/97); Demonstrate that CST-Only Glass Satisfied PC Specs in WAPS (completed 9/97); Determine Process Parameters of CST-Only Glass (completed 9/97). The results for Task B of Task Plan SR-16WT-31 have been documented in reports that have been included as attachments. The following is a summary of the attachments from the CST vitrification project.

  8. Nanocrystalline Sm{sub 0.5}Sr{sub 0.5}CoO{sub 3??} synthesized using a chelating route for use in IT-SOFC cathodes: Microstructure, surface chemistry and electrical conductivity

    SciTech Connect (OSTI)

    Scurtu, Rares [“IlieMurgulescu” Institute of Physical Chemistry, Romanian Academy, 202 SplaiulIndependentei, 060021 Bucharest (Romania); Romania National Institute for Research and Development in Microtechnologies(IMT), 023573 Bucharest (Romania); Somacescu, Simona, E-mail: ssimona@icf.ro [“IlieMurgulescu” Institute of Physical Chemistry, Romanian Academy, 202 SplaiulIndependentei, 060021 Bucharest (Romania); Calderon-Moreno, Jose Maria; Culita, Daniela [“IlieMurgulescu” Institute of Physical Chemistry, Romanian Academy, 202 SplaiulIndependentei, 060021 Bucharest (Romania); Bulimestru, Ion; Popa, Nelea; Gulea, Aurelian [Faculty of Chemistry and Chemical Technology State University of Moldova 60 Mateevici, Chisinau MD 2009 Republic of Moldova (Moldova, Republic of); Osiceanu, Petre [“IlieMurgulescu” Institute of Physical Chemistry, Romanian Academy, 202 SplaiulIndependentei, 060021 Bucharest (Romania)

    2014-02-15T23:59:59.000Z

    Nanocrystalline Sm{sub 0.5}Sr{sub 0.5}CoO{sub 3??} powders were synthesized by a chelating route using different polyfunctional H{sub x}APC acids (APC=aminopolycarboxylate; x=3, 4, 5). Different homologous aminopolycarboxylic acids, namely nitrilotriacetic (H{sub 3}nta), ethylenediaminetetraacetic (H{sub 4}edta), 1,2-cyclohexanediaminetetracetic (H{sub 4}cdta) and diethylenetriaminepentaacetic (H{sub 5}dtpa) acid, were used as chelating agents to combine Sm, Sr, Co elements into a perovskite structure. The effects of the chelating agents on the crystalline structure, porosity, surface chemistry and electrical properties were investigated. The electrical properties of the perovskite-type materials emphasized that their conductivities in the temperature range of interest (600–800 °C) depend on the nature of the precursors as well as on the presence of a residual Co oxide phase as shown by XRD and XPS analysis. The surface chemistry and the surface stoichiometries were determined by XPS revealing a complex chemical behavior of Sr that exhibits a peculiar “surface phase” and “bulk phase” chemistry within the detected volume (<10 nm). - Graphical abstract: Synthesis of nanocrystalline Sm{sub 0.5}Sr{sub 0.5}CoO{sub 3??} powders by a chelating route and the investigation of the microstructure, surface chemistry and electrical properties. Display Omitted - Highlights: • Nanocrystalline Sm{sub 0.5}Sr{sub 0.5}CoO{sub 3??} obtained by a chelating synthesis route. • Cubic perovskite structures with crystallite sizes ?23±2 nm. • The porous nature revealed by N{sub 2} adsorption/desorption (BET). • The surface chemistry and the surface stoichiometries highlighted by XPS. • A complex chemical behavior of Sr exhibits a peculiar “surface phase” and “bulk phase” chemistry.

  9. Structural characterization of the perovskite series Sr{sub 1?x}La{sub x}Ti{sub 0.5}Mn{sub 0.5}O{sub 3}

    SciTech Connect (OSTI)

    Qasim, Ilyas [School of Chemistry, The University of Sydney, Sydney, NSW 2006 (Australia); Kennedy, Brendan J., E-mail: B.Kennedy@chem.usyd.edu.au [School of Chemistry, The University of Sydney, Sydney, NSW 2006 (Australia)

    2013-04-15T23:59:59.000Z

    The perovskite-type compounds Sr{sub 1?x}La{sub x}Ti{sub 0.5}Mn{sub 0.5}O{sub 3}, x=0, 0.1, 0.2, 0.3, 0.4 and 0.5 have been synthesized by solid-state methods, and their room temperature structures determined using X-ray synchrotron powder diffraction. The x=0.0 end member, SrMn{sub 0.5}Ti{sub 0.5}O{sub 3} is cubic in space group Pm3{sup ¯}m; there being no evidence for ordering of the Ti{sup 4+} and Mn{sup 4+} cations. We find that x=0.5 compound is rhombohedral in R3{sup ¯}c rather than orthorhombic as reported previously. Magnetic measurements suggest that both SrMn{sub 0.5}Ti{sub 0.5}O{sub 3} and Sr{sub 0.5}La{sub 0.5}Mn{sub 0.5}Ti{sub 0.5}O{sub 3} are spin-glasses. - Graphical abstract: A cubic–rhombohedral phase-transition is observed cation disordered perovskites Sr{sub 1?x}La{sub x}Ti{sub 0.5}Mn{sub 0.5}O{sub 3}. Both end members are spin-glasses. Highlights: ? Structural studies of Sr{sub 1?x}La{sub x}Ti{sub 0.5}Nb{sub 0.5}O{sub 3} perovskites, show lack of long range Mn:Ti order. ? Magnetic properties indicative of spin-glass behavior. ? Changes of crystal structure from cubic to rhombohedral with increasing lanthanum content.

  10. Light scattering from ,,K0.5Na0.5...0.2,,Sr0.75Ba0.25...0.9Nb2O6 with the tungsten bronze structure: An analogy with relaxor ferroelectrics

    E-Print Network [OSTI]

    Light scattering from ,,K0.5Na0.5...0.2,,Sr0.75Ba0.25...0.9Nb2O6 with the tungsten bronze structure a complex single crystal from the tungsten­bronze family, K0.5Na0.5 0.2 Sr0.75Ba0.25 0.9Nb2O6 doped with Cu2 photorefractive material.1 KNSBN originates from the tungsten­bronze family of ferroelectrics. KNSBN has two close

  11. Extracting the spectral function of the cuprates by a full two-dimensional analysis: Angle-resolved photoemission spectra of Bi2Sr2CuO6

    SciTech Connect (OSTI)

    Meevasana, W.

    2010-04-30T23:59:59.000Z

    Recently, angle-resolved photoemission spectroscopy (ARPES) has revealed a dispersion anomaly at high binding energy near 0.3-0.5 eV in various families of the high-temperature superconductors. For further studies of this anomaly we present a new two-dimensional fitting-scheme and apply it to high-statistics ARPES data of the strongly-overdoped Bi{sub 2}Sr{sub 2}CuO{sub 6} cuprate superconductor. The procedure allows us to extract the self-energy in an extended energy and momentum range. It is found that the spectral function of Bi{sub 2}Sr{sub 2}CuO{sub 6} can be parameterized using a small set of tight-binding parameters and a weakly-momentum-dependent self-energy up to 0.7 eV in binding energy and over the entire first Brillouin zone. Moreover the analysis gives an estimate of the momentum dependence of the matrix element, a quantity, which is often neglected in ARPES analyses.

  12. Structural characterisation of BaTiO{sub 3} thin films deposited on SrRuO{sub 3}/YSZ buffered silicon substrates and silicon microcantilevers

    SciTech Connect (OSTI)

    Colder, H.; Jorel, C., E-mail: corentin.jorel@unicaen.fr; Méchin, L. [GREYC, UMR 6072, CNRS, ENSICAEN, UCBN, 6 bd du Maréchal Juin, 14050 Caen Cedex (France); Domengès, B. [LAMIPS, CRISMAT-NXP Semiconductors-Presto Engineering laboratory, CNRS-UMR 6508, ENSICAEN, UCBN, 2 rue de la Girafe, 14 000 Caen (France); Marie, P.; Boisserie, M. [CIMAP, UMR 6252, CNRS, ENSICAEN, UCBN, CEA, 6 bd du Maréchal Juin, 14050 Caen Cedex (France); Guillon, S.; Nicu, L. [LAAS, CNRS, Univ de Toulouse, 7 avenue du Colonel Roche, 31400 Toulouse (France); Galdi, A. [GREYC, UMR 6072, CNRS, ENSICAEN, UCBN, 6 bd du Maréchal Juin, 14050 Caen Cedex (France); Department of Industrial Engineering, CNR-SPIN Salerno, Università di Salerno, 84084 Fisciano, Salerno (Italy)

    2014-02-07T23:59:59.000Z

    We report on the progress towards an all epitaxial oxide layer technology on silicon substrates for epitaxial piezoelectric microelectromechanical systems. (101)-oriented epitaxial tetragonal BaTiO{sub 3} (BTO) thin films were deposited at two different oxygen pressures, 5.10{sup ?2} mbar and 5.10{sup ?3} mbar, on SrRuO{sub 3}/Yttria-stabilized zirconia (YSZ) buffered silicon substrates by pulsed laser deposition. The YSZ layer full (001) orientation allowed the further growth of a fully (110)-oriented conductive SrRuO{sub 3} electrode as shown by X-ray diffraction. The tetragonal structure of the BTO films, which is a prerequisite for the piezoelectric effect, was identified by Raman spectroscopy. In the BTO film deposited at 5.10{sup ?2} mbar strain was mostly localized inside the BTO grains whereas at 5.10{sup ?3} mbar, it was localized at the grain boundaries. The BTO/SRO/YSZ layers were finally deposited on Si microcantilevers at an O{sub 2} pressure of 5.10{sup ?3} mbar. The strain level was low enough to evaluate the BTO Young modulus. Transmission electron microscopy (TEM) was used to investigate the epitaxial quality of the layers and their epitaxial relationship on plain silicon wafers as well as on released microcantilevers, thanks to Focused-Ion-Beam TEM lamella preparation.

  13. Microstructural features and domain formation in (Ba,Sr){sub 2}TiSi{sub 2}O{sub 8} fresnoites

    SciTech Connect (OSTI)

    Wong, Chui Ling, E-mail: wong0233@e.ntu.edu.sg [School of Materials Science and Engineering, Nanyang Technological University, Singapore 639798 (Singapore); Ferraris, Cristiano [Laboratoire de Mineralogie et Cosmchimie du Museum National d'Historie Naturelle, UMR-CNRS 7202, CP 52, 61 Rue Buffon, 75005 Paris (France); White, T.J. [School of Materials Science and Engineering, Nanyang Technological University, Singapore 639798 (Singapore); Centre for Advanced Microscopy, The Australian National University, Canberra ACT 0200 (Australia)

    2011-07-15T23:59:59.000Z

    The formation and co-existence of crystallographically modulated and non-modulated regions in (Ba,Sr){sub 2}TiSi{sub 2}O{sub 8} fresnoites is reviewed, particularly the dependence on local composition. It is shown that perturbations of the average fresnoite structure, determined from appreciable single crystals, are in some cases better described as nanometric domain intergrowths where departures from ideal stoichiometry are characteristics of incommensuration, while modulation is absent from volumes that are less perturbed chemically. Evidence for this differentiation is obtained from selected area electron diffraction (SAED) patterns and high-resolution transmission electron microscopy (HRTEM) images. The domains are readily distinguished by their unique contrast in bright field electron micrographs. Fourier reconstructions of HRTEM images collected from areas with darker contrast show that modulation can change within relatively small volumes. Nearby areas with lighter contrast were found by SAED to be free of structural disorder and incommensurate reflections. - Graphical abstract: Fresnoite layers contain SiO{sub 4} and TiO{sub 5} polyhedra that undergo run rotation and tilting to create 3D, 4D and 5D structural modulations that can be directly observed by electron diffraction and high resolution imaging. Highlights: {yields}(Ba,Sr){sub 2}TiSi{sub 2}O{sub 8} fresnoites contain commensurate and incommensurate domains. > Departures in stoichiometry promote the formation of nanostructured domains. > Domains formation may provide a means for reducing strain in single crystals.

  14. Synthesis and photoluminescence study of Dy{sup 3+} doped Sr{sub 3}B{sub 2}O{sub 6}: Nanophosphors

    SciTech Connect (OSTI)

    Neharika,, E-mail: neharikasinghwazir@gmail.com; Kumar, Vinay, E-mail: neharikasinghwazir@gmail.com [School of Physics, Shri Mata Vaishno Devi University, Katra-182320, J and K (India); Ntwaeaborwa, O. M.; Swart, H. C. [Department of Physics, University of the Free State, P.O. Box 339, Bloemfontein ZA9300 (South Africa)

    2014-04-24T23:59:59.000Z

    In present paper, the combustion method synthesis of Dy{sup 3+} doped Sr{sub 3}B{sub 2}O{sub 6} nanophosphor and their luminescent properties have been reported. The crystalline structure and morphology of nanophosphors was confirmed and verify by the Xray powder diffraction (XRD) and transmission electron microscopy (TEM). The spectral properties of the Sr{sub 3}B{sub 2}O{sub 6}:Dy{sup 3+} nanophosphors have been studied with the photoluminescence (PL) spectroscopy. Under 300nm excitation, the PL emission shows three peaks at 482, 575 and 664 nm, corresponding to the {sup 4}F{sub 9/2}?{sup 6}H{sub 15/2}, {sup 4}F{sub 9/2}?{sup 6}H{sub 13/2} and {sup 4}F{sub 9/2}?{sup 4}H{sub 11/2} transition states. The 1931 CIE diagram gives the coordinates (x, y) as (0.38099, 0.40418) correspond to the shade of yellowish white emission of the Dy{sup 3+} ion which can be used as w-LED phosphors.

  15. Atomic and electronic structures of single-layer FeSe on SrTiO3(001): The role of oxygen deficiency

    SciTech Connect (OSTI)

    Bang, Junhyeok; Li, Zhi; Sun, Y. Y.; Samanta, Amit; Zhang, Y. Y.; Zhang, Wenhao; Wang, Lili; Chen, X.; Ma, Xucun; Xue, Q.-K.; Zhang, S. B.

    2013-06-01T23:59:59.000Z

    Using first-principles calculation, we propose an interface structure for single triple-layer FeSe on the SrTiO3(001) surface, a high-Tc superconductor found recently. The key component of this structure is the oxygen deficiency on the top layer of the SrTiO3 substrate, as a result of Se etching used in preparing the high-Tc samples. The O vacancies strongly bind the FeSe triple layer to the substrate giving rise to a (2×1) reconstruction, as observed by scanning tunneling microscopy. The enhanced binding correlates to the significant increase of Tc observed in experiment. The O vacancies also serve as the source of electron doping, which modifies the Fermi surface of the first FeSe layer by filling the hole pocket near the center of the surface Brillouin zone, as suggested from angle-resolved photoemission spectroscopy measurement.

  16. Structural phase transition and magnetism in hexagonal SrMnO{sub 3} by magnetization measurements and by electron, x-ray, and neutron diffraction studies

    SciTech Connect (OSTI)

    Daoud-Aladine, A.; Chapon, L. C.; Knight, K. S. [ISIS facility, Rutherford Appleton Laboratory-CCLRC, Chilton, Didcot, Oxfordshire, OX11 0QX (United Kingdom); Martin, C. [Laboratoire CRISMAT-UMR, 6508 ENSI CAEN, 6, Marechal Juin, 14050 Caen (France); ISIS facility, Rutherford Appleton Laboratory-CCLRC, Chilton, Didcot, Oxfordshire, OX11 0QX (United Kingdom); Hervieu, M. [Laboratoire CRISMAT-UMR, 6508 ENSI CAEN, 6, Marechal Juin, 14050 Caen (France); Brunelli, M. [European Synchrotron Radiation Facility, BP220, F-38043 Grenoble Cedex (France); Radaelli, P. G. [ISIS facility, Rutherford Appleton Laboratory-CCLRC, Chilton, Didcot, Oxfordshire, OX11 0QX (United Kingdom); Department of Physics and Astronomy, University College London, Gower Street, London WC1E 6BT (United Kingdom)

    2007-03-01T23:59:59.000Z

    The structural and magnetic properties of the hexagonal four-layer form of SrMnO{sub 3} have been investigated by combining magnetization measurements, electron diffraction, and high-resolution synchrotron x-ray and neutron powder diffraction. Below 350 K, there is subtle structural phase transition from hexagonal symmetry (space group P6{sub 3}/mmc) to orthorhombic symmetry (space group C222{sub 1}) where the hexagonal metric is preserved. The second-order phase transition involves a slight tilting of the corner-sharing Mn{sub 2}O{sub 9} units composed of two face-sharing MnO{sub 6} octahedra and the associated displacement of Sr{sup 2+} cations. The phase transition is described in terms of symmetry-adapted displacement modes of the high symmetry phase. Upon further cooling, long range magnetic order with propagation vector k=(0,0,0) sets in below 300 K. The antiferromagnetic structure, analyzed using representation theory, shows a considerably reduced magnetic moment indicating the crucial role played by direct exchange between Mn centers of the Mn{sub 2}O{sub 9} units.

  17. Structural distortions in the spin-gap regime of the quantum antiferromagnet SrCu{sub 2}(BO{sub 3}){sub 2}

    SciTech Connect (OSTI)

    Vecchini, C., E-mail: c.vecchini@rl.ac.u [Institute of Electronic Structure and Laser, Foundation for Research and Technology-Hellas, Vassilika Vouton, 711 10 Heraklion, Crete (Greece); ISIS Facility, Rutherford Appleton Laboratory, Chilton, Didcot, Oxfordshire, OX11 0QX (United Kingdom); Adamopoulos, O. [Institute of Electronic Structure and Laser, Foundation for Research and Technology-Hellas, Vassilika Vouton, 711 10 Heraklion, Crete (Greece); Department of Chemistry, University of Crete, Voutes, 710 03 Heraklion (Greece); Chapon, L.C. [ISIS Facility, Rutherford Appleton Laboratory, Chilton, Didcot, Oxfordshire, OX11 0QX (United Kingdom); Lappas, A., E-mail: lappas@iesl.forth.g [Institute of Electronic Structure and Laser, Foundation for Research and Technology-Hellas, Vassilika Vouton, 711 10 Heraklion, Crete (Greece); Kageyama, H. [Department of Chemistry, Graduate School of Science, Kyoto University, Kyoto 606-8502 (Japan); Ueda, Y. [Institute of Solid State Physics, University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8581 (Japan); Zorko, A. [Institute Jozef Stefan, Jamova 39, 1000 Ljubljana (Slovenia)

    2009-12-15T23:59:59.000Z

    We report the first crystallographic study within the low-temperature (<40 K) spin-gap region of the two-dimensional frustrated antiferromagnet SrCu{sub 2}(BO{sub 3}){sub 2}. The crystal system does not deviate from the tetragonal I-42m space group symmetry. However, our high-resolution neutron powder diffraction measurements uncover subtle structural modifications below 34 K, concomitant to the formation of the dimer singlet ground state. Intimate spin-lattice coupling leads to negative thermal expansion of the tetragonal structure, which reflects into particular local lattice adjustments. The extracted structural parameters suggest the reduction of the buckling found in the copper-borate planes and the strengthening of the leading, in-plane intra-dimer superexchange interaction. The observed contraction along the c-axis, associated with the inter-dimer exchange in adjacent layers, indicates the involvement of weaker three-dimensional interactions in the magnetic properties. The rules posed by the crystal symmetry do not preclude Dzyaloshinsky-Moriya interactions, which therefore remain as an important source of spin anisotropy necessary to rationalise the ground state behaviour. - Abstract: We report the first crystallographic study within the low-temperature spin-gap region of the two-dimensional frustrated antiferromagnet SrCu{sub 2}(BO{sub 3}){sub 2}. Subtle spin-lattice coupling was unveiled in the low-temperature region. Display Omitted

  18. Quantifying stoichiometry-induced variations in structure and energy of a SrTiO3 symmetric ?13 {510}/<100?>?grain boundary

    SciTech Connect (OSTI)

    Yang, Hao; Lee, H. S.; Sarahan, M. C.; Sato, Yoichi; Chi, Miaofang; Moeck, Peter; Ikuhara, Yuichi; Browning, Nigel D.

    2013-04-01T23:59:59.000Z

    shown to readily accommodate nonstoichiometry changing the electrostatic potential at the boundary plane and effectively controlling material properties such as capacitance, magnetoresistance and superconductivity. Understanding and quantifying exactly how variations in atomic scale nonstoichiometry at the boundary plane extend to the practical mesoscale operating length of the system is therefore critical for improving the overall properties. Bicrystals of SrTiO3 were fabricated to provide the model GB model structures that are analysed in this paper. We show that statistical analysis of aberration-corrected scanning transmission electron microscope images acquired from a large area of GB is an effective routine to understanding the variation in boundary structure that occurs to accommodate nonstoichiometry. In the case of the SrTiO3 22.6° ?13 (510)/[100] GB analysed here, the symmetric atomic structures observed from a micron-long GB can be categorized as two different competing structural arrangements, with and without a rigid-body translation along the boundary plane. How this quantified experimental approach can provide direct insights into the GB energetics is further confirmed from the first principles density functional theory, and the effect of nonstoichiometry in determining the GB energies is quantified.

  19. Band-Gap Reduction and Dopant Interaction in Epitaxial La,Cr Co-doped SrTiO3 Thin Films

    SciTech Connect (OSTI)

    Comes, Ryan B.; Sushko, Petr; Heald, Steve M.; Colby, Robert J.; Bowden, Mark E.; Chambers, Scott A.

    2014-12-03T23:59:59.000Z

    We show that by co-doping SrTiO3 (STO) epitaxial thin films with equal amounts of La and Cr it is possible to produce films with an optical band gap ~0.9 eV lower than that of undoped STO. Sr1-xLaxTi1-xCrxO3 thin films were deposited by molecular beam epitaxy and characterized using x-ray photoelectron spectroscopy and x-ray absorption near-edge spectroscopy to show that the Cr dopants are almost exclusively in the Cr3+ oxidation state. Extended x-ray absorption fine structure measurements and theoretical modeling suggest that it is thermodynamically preferred for La and Cr dopants to occupy nearest neighbor A- and B-sites in the lattice. Transport measurements show that the material exhibits variable-range hopping conductivity with high resistivity. These results create new opportunities for the use of doped STO films in photovoltaic and photocatalytic applications.

  20. Layer-by-layer resolved core-level shifts in CaF[sub 2] and SrF[sub 2] on Si(111): Theory and experiment

    SciTech Connect (OSTI)

    Rotenberg, E. (Department of Physics, University of California, Berkeley, California 94720 (United States)); Denlinger, J.D. (Department of Physics, University of Wisconsin, Milwaukee, Wisconsin 53211 (United States)); Leskovar, M.; Hessinger, U.; Olmstead, M.A. (Department of Physics, FM-15, University of Washington, Seattle, Washington 98195 (United States))

    1994-10-15T23:59:59.000Z

    Using x-ray-photoelectron spectroscopy and Auger-electron spectroscopy, we have resolved surface, bulk, and interface Ca and F core-level emission in thin films (3--8 triple layers) of CaF[sub 2] and SrF[sub 2] on Si(111). We confirmed these assignments using x-ray-photoelectron diffraction (XPD) and surface modification. XPD was also used to identify the growth modes of the films as being either laminar or layer plus islands; in the latter case we have resolved buried and uncovered interface F and Ca/Sr emission. We compare the observed energy differences between surface, bulk, and interface emission to theoretical estimates of the extra-atomic contributions to emission energies. We find excellent agreement considering only the Madelung (electrostatic) potentials for the initial-state contribution and polarization response for the final-state contribution, including the effect of tetragonal strain. Small discrepancies for emission from metal atoms bonded to the Si substrate are interpreted in terms of chemical shifts.