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Sample records for joe white ash

  1. Joe Kilkenny

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    joe kilkenny Joe Kilkenny Joe Kilkenny Chief NIF Experimentalist for Measurements National Ignition Facility Joe Kilkenny, vice president for high energy density physics at General Atomics, currently is assigned to the NIF diagnostic program as the chief NIF experimentalist for measurements. He has made major contributions to experimental inertial confinement fusion (ICF) for more than 35 years. He has some 200 refereed publications on ICF. Dr. Kilkenny was an academic at Imperial College,

  2. Joe Hagerman | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Joe Hagerman About Us Joe Hagerman - Senior Policy Advisor, Building Technologies Office Joe Hagerman manages the Buildings-to-Grid portfolio in DOE's Building Technologies Office. Email Joe Hagerman ► Most Recent Laying the Foundation for a Future of Connected Buildings July 12

  3. Joe Garcia | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Joe Garcia About Us Joe Garcia - Congressman Representing the 26th District of Florida Joe Garcia Congressman Joe Garcia was elected to the United States House of Representatives in 2012. He is a dedicated public servant who has called South Florida home for his entire life. With scholarships and money he had saved from cutting grass with his grandfather on weekends, Congressman Garcia put himself through Miami Dade College and later the University of Miami where he completed his undergraduate

  4. Joe Gettler | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Joe Gettler About Us Joe Gettler - Senior Public Affairs Representative, Brookhaven National Laboratory Joe Gettler is a Senior Public Affairs Representative at Brookhaven National Laboratory, one of the Department of Energy's 17 National Laboratories. Most Recent How to Hunt a Higgs June 1

  5. Joe Olencz | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Joe Olencz About Us Joe Olencz - Director, Office of the Departmental Representative to the Defense Nuclear Facilities Safety Board Joe Olencz Mr. Olencz has approximately 25 years of experience working in both the private and public sectors, with the last 23 years working at both the U.S. Department of Energy and the U.S. Nuclear Regulatory Commission. From October 1991 to April 1997, Mr. Olencz worked at the U.S. Department of Energy in the Office of Defense Programs serving as Project Manager

  6. ORISE Research Team Experiences: Joe Lake

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Joe Lake One-Time Student Intern has 'Second Life' as ORNL Mentor Joe Lake Joe Lake, a full-time software engineer for Oak Ridge National Laboratory's Computational Science and Engineering Division, is doing his part to help foster the next generation of scientists. As a former participant of both the ORISE-administered DOE Science Undergraduate Laboratory Internships (SULI) and Higher Education Research Experiences (HERE) programs, Lake is currently co-mentoring his fourth student. As a former

  7. Jefferson Lab Leadership Council - Joe Scarcello

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Council Privacy and Security Notice Skip over navigation search Search Please upgrade your browser. This site's design is only visible in a graphical browser that supports web standards, but its content is accessible to any browser. Concerns? Jefferson Lab Navigation Home Search News Insight print version Org Charts Accelerator COO CFO CIO CTO ESH&Q HR IT Physics Theory/Comp Physics Leadership Council Chief Financial Officer, Joe Scarcello Joe Scarcello Chief Financial Officer Joe Scarcello

  8. Joe Sortino | Argonne Leadership Computing Facility

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Joe Sortino Research Aide - VIZ Team Argonne National Laboratory 9700 S. Cass Avenue Building 240 - Wkstn. 4E7 Argonne, IL 60439 jsortino@anl...

  9. Joe Wheeler Elec Member Corp | Open Energy Information

    Open Energy Info (EERE)

    Joe Wheeler Elec Member Corp Jump to: navigation, search Name: Joe Wheeler Elec Member Corp Place: Alabama Phone Number: (256) 552-2300 Website: www.jwemc.org Twitter: @jwemc...

  10. TBH-0080- In the Matter of Billy Joe Baptist

    Broader source: Energy.gov [DOE]

    This decision will consider an Order to Show Cause that I issued on February 3, 2009, regarding a March 6, 2008, whistleblower complaint filed by Billy Joe Baptist (Baptist) under the Department of...

  11. TBA-0080- In the Matter of Billy Joe Baptist

    Broader source: Energy.gov [DOE]

    This Decision considers an Appeal of an Initial Agency Decision (IAD) issued on May 7, 2009, involving a complaint of retaliation filed by Billy Joe Baptist (“Baptist,” or “Complainant”) under the...

  12. TBZ-0080- In the Matter of Billy Joe Baptist

    Broader source: Energy.gov [DOE]

    This decision will consider an Order to Show Cause that I issued on February 3, 2009, regarding a March 6, 2008, whistleblower complaint filed by Billy Joe Baptist (Baptist) under the Department of...

  13. Joe Henry named COO for B&W Y-12 | Y-12 National Security Complex

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Joe Henry named COO for ... Joe Henry named COO for B&W Y-12 Posted: September 10, 2012 - 3:30pm Joe Henry, Chief Operating Officer B&W Y-12 announced today that Joe Henry has been named Chief Operating Officer, a new position that has been created to assist the president and general manager in overall site management with a particular focus on operations. Henry currently is president of Nuclear Fuel Services, Inc. (NFS) in Erwin, Tenn., and is expected to temporarily serve in the COO

  14. Jizhong (Joe) Zhou, 2014 | U.S. DOE Office of Science (SC)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Jizhong (Joe) Zhou, 2014 The Ernest Orlando Lawrence Award Lawrence Award Home Nomination & Selection Guidelines Award Laureates 2010's 2000's 1990's 1980's 1970's 1960's Ceremony The Life of Ernest Orlando Lawrence Contact Information The Ernest Orlando Lawrence Award U.S. Department of Energy SC-2/Germantown Building 1000 Independence Ave., SW Washington, DC 20585 P: (301) 903-2411 E: Email Us 2010's Jizhong (Joe) Zhou, 2014 Print Text Size: A A A FeedbackShare Page Biological and

  15. Joe Grange Nov. 30 2012 FNAL Joint Experimental-Theoretical Seminar

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    February 21, 13 f Joe Grange Nov. 30 2012 FNAL Joint Experimental-Theoretical Seminar 1. Introduction ν cross sections in a single-detector oscillation exp't recent σ interest from MiniBooNE neutrino-mode data 2. Anti-neutrino analyses ν μ background (wrong signs) ν μ CCQE σ (new!) ν μ NCE σ (new!) 3. Outlook and summary Outline 2 Thursday, February 21, 13 f Joe Grange Nov. 30 2012 FNAL Joint Experimental-Theoretical Seminar 1. Introduction ν cross sections in a single-detector

  16. Joe W. Gray, 1986 | U.S. DOE Office of Science (SC)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Joe W. Gray, 1986 The Ernest Orlando Lawrence Award Lawrence Award Home Nomination & Selection Guidelines Award Laureates 2010's 2000's 1990's 1980's 1970's 1960's Ceremony The Life of Ernest Orlando Lawrence Contact Information The Ernest Orlando Lawrence Award U.S. Department of Energy SC-2/Germantown Building 1000 Independence Ave., SW Washington, DC 20585 P: (301) 903-2411 E: Email Us 1980's Joe W. Gray, 1986 Print Text Size: A A A FeedbackShare Page Life Sciences: For his exceptional

  17. Presentation V: Joe Grange, University of Florida Experiments I: MiniBooNE

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Presentation V: Joe Grange, University of Florida Experiments I: MiniBooNE West Wing (WH10W) 5:30 PM Thursday July 15 Refreshments at 5 PM Neutrino University (NeutU) is a series of informal, informative, and interactive presentations for summer students in the Fermilab Neutrino Program (Minerva, MiniBooNE, Minos, MicroBooNE, and Nova). These presentations are intended to introduce students to some of the important ideas and experiments of neutrino physics, particularly those that are running or

  18. Joe Hezir

    Broader source: Energy.gov [DOE]

    Mr. Hezir was confirmed as the Department of Energy's Chief Financial Officer (CFO) on December 17, 2014.

  19. Activation of fly ash

    DOE Patents [OSTI]

    Corbin, David R.; Velenyi, Louis J.; Pepera, Marc A.; Dolhyj, Serge R.

    1986-01-01

    Fly ash is activated by heating a screened magnetic fraction of the ash in a steam atmosphere and then reducing, oxidizing and again reducing the hydrothermally treated fraction. The activated fly ash can be used as a carbon monoxide disproportionating catalyst useful in the production of hydrogen and methane.

  20. Activation of fly ash

    DOE Patents [OSTI]

    Corbin, D.R.; Velenyi, L.J.; Pepera, M.A.; Dolhyj, S.R.

    1986-08-19

    Fly ash is activated by heating a screened magnetic fraction of the ash in a steam atmosphere and then reducing, oxidizing and again reducing the hydrothermally treated fraction. The activated fly ash can be used as a carbon monoxide disproportionating catalyst useful in the production of hydrogen and methane.

  1. Fly ash carbon passivation

    DOE Patents [OSTI]

    La Count, Robert B; Baltrus, John P; Kern, Douglas G

    2013-05-14

    A thermal method to passivate the carbon and/or other components in fly ash significantly decreases adsorption. The passivated carbon remains in the fly ash. Heating the fly ash to about 500 and 800 degrees C. under inert gas conditions sharply decreases the amount of surfactant adsorbed by the fly ash recovered after thermal treatment despite the fact that the carbon content remains in the fly ash. Using oxygen and inert gas mixtures, the present invention shows that a thermal treatment to about 500 degrees C. also sharply decreases the surfactant adsorption of the recovered fly ash even though most of the carbon remains intact. Also, thermal treatment to about 800 degrees C. under these same oxidative conditions shows a sharp decrease in surfactant adsorption of the recovered fly ash due to the fact that the carbon has been removed. This experiment simulates the various "carbon burnout" methods and is not a claim in this method. The present invention provides a thermal method of deactivating high carbon fly ash toward adsorption of AEAs while retaining the fly ash carbon. The fly ash can be used, for example, as a partial Portland cement replacement in air-entrained concrete, in conductive and other concretes, and for other applications.

  2. White Roofs

    ScienceCinema (OSTI)

    Chu, Steven

    2013-05-29

    Secretary Steven Chu discusses the benefits of switching to white roofs and light colored pavements.

  3. Franny White

    Broader source: Energy.gov [DOE]

    Franny White is a News & Media Relations Specialist at the Energy Department’s Pacific Northwest National Laboratory.

  4. White Papers

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    White Papers White Papers This page contains a collection of white papers on IS&T topics and presentations about ISTI. Contact Institute Director Stephan Eidenbenz (505) 667-3742 Email Professional Staff Assistant Nickole Aguilar Garcia (505) 665-3048 Email What is ISTI? Slide deck, Author: S. Eidenbenz, November 2015

  5. Engineering Model for Ash Formation

    Energy Science and Technology Software Center (OSTI)

    1994-12-02

    Ash deposition is controlled by the impaction and sticking of individual ash particles to heat transfer surfaces. Prediction of deposition therefore requires that the important factors in this process be predictable from coal and operational parameters. Coal combustion, boiler heat transfer, ash formation, ash particle aerodynamic, and ash particle sticking models are all essential steps in this process. The model described herein addresses the prediction of ash particle size and composition distributions based upon combustionmore » conditions and coal parameters. Key features of the model include a mineral redistribution routine to invert CCSEM mineralogical data, and a mineral interaction routine that simulates the conversion of mineral matter into ash during coal burning and yields ash particle size and composition distributions.« less

  6. High-performance, high-volume fly ash concrete

    SciTech Connect (OSTI)

    2008-01-15

    This booklet offers the construction professional an in-depth description of the use of high-volume fly ash in concrete. Emphasis is placed on the need for increased utilization of coal-fired power plant byproducts in lieu of Portland cement materials to eliminate increased CO{sub 2} emissions during the production of cement. Also addressed is the dramatic increase in concrete performance with the use of 50+ percent fly ash volume. The booklet contains numerous color and black and white photos, charts of test results, mixtures and comparisons, and several HVFA case studies.

  7. Modeling volcanic ash dispersal

    ScienceCinema (OSTI)

    None

    2011-10-06

    Explosive volcanic eruptions inject into the atmosphere large amounts of volcanic material (ash, blocks and lapilli). Blocks and larger lapilli follow ballistic and non-ballistic trajectories and fall rapidly close to the volcano. In contrast, very fine ashes can remain entrapped in the atmosphere for months to years, and may affect the global climate in the case of large eruptions. Particles having sizes between these two end-members remain airborne from hours to days and can cover wide areas downwind. Such volcanic fallout entails a serious threat to aircraft safety and can create many undesirable effects to the communities located around the volcano. The assessment of volcanic fallout hazard is an important scientific, economic, and political issue, especially in densely populated areas. From a scientific point of view, considerable progress has been made during the last two decades through the use of increasingly powerful computational models and capabilities. Nowadays, models are used to quantify hazard scenarios and/or to give short-term forecasts during emergency situations. This talk will be focused on the main aspects related to modeling volcanic ash dispersal and fallout with application to the well known problem created by the Eyjafjöll volcano in Iceland. Moreover, a short description of the main volcanic monitoring techniques is presented.

  8. Fly ash quality and utilization

    SciTech Connect (OSTI)

    Barta, L.E.; Lachner, L.; Wenzel, G.B.; Beer, M.J.

    1995-12-01

    The quality of fly ash is of considerable importance to fly ash utilizers. The fly ash puzzolanic activity is one of the most important properties that determines the role of fly ash as a binding agent in the cementing process. The puzzolanic activity, however is a function of fly ash particle size and chemical composition. These parameters are closely related to the process of fly ash formation in pulverized coal fired furnaces. In turn, it is essential to understand the transformation of mineral matter during coal combustion. Due to the particle-to-particle variation of coal properties and the random coalescence of mineral particles, the properties of fly ash particles e.g. size, SiO{sub 2} content, viscosity can change considerably from particle to particle. These variations can be described by the use of the probability theory. Since the mean values of these randomly changing parameters are not sufficient to describe the behavior of individual fly ash particles during the formation of concrete, therefore it is necessary to investigate the distribution of these variables. Examples of these variations were examined by the Computer Controlled Scanning Electron Microscopy (CCSEM) for particle size and chemical composition for Texas lignite and Eagel Butte mineral matter and fly ash. The effect of combustion on the variations of these properties for both the fly ash and mineral matter were studied by using a laminar flow reactor. It is shown in our paper, that there are significant variations (about 40-50% around the mean values) of the above-listed properties for both coal samples. By comparing the particle size and chemical composition distributions of the mineral matter and fly ash, it was possible to conclude that for the Texas lignite mineral matter, the combustion did not effect significantly the distribution of these properties, however, for the Eagel Butte coal the combustion had a major impact on these mineral matter parameters.

  9. Incineration and incinerator ash processing

    SciTech Connect (OSTI)

    Blum, T.W.

    1991-01-01

    Parallel small-scale studies on the dissolution and anion exchange recovery of plutonium from Rocky Flats Plant incinerator ash were conducted at the Los Alamos National Laboratory and at the Rocky Flats Plant. Results from these two studies are discussed in context with incinerator design considerations that might help to mitigate ash processing related problems. 11 refs., 1 fig., 1 tab.

  10. Landfilling ash/sludge mixtures

    SciTech Connect (OSTI)

    Benoit, J.; Eighmy, T.T.; Crannell, B.S.

    1999-10-01

    The geotechnical properties of a mixture of municipal solid waste incinerator bottom ash and municipal wastewater treatment plant sludge was investigated for a proposed ash/sludge secure landfill. The components as well as mixtures ranging from 10:1 to 5:1 (ash:sludge, by volume) were evaluated, where appropriate, for a number of geotechnical index and mechanical properties including particle size, water content, specific gravity, density-moisture relationships, shear strength, and compressibility. The results from a compactibility study and stability analysis of the proposed landfill were used to help approve a landfill codisposal concept; a full-scale facility was constructed and is currently operating successfully.

  11. ITER helium ash accumulation

    SciTech Connect (OSTI)

    Hogan, J.T.; Hillis, D.L.; Galambos, J.; Uckan, N.A. ); Dippel, K.H.; Finken, K.H. . Inst. fuer Plasmaphysik); Hulse, R.A.; Budny, R.V. . Plasma Physics Lab.)

    1990-01-01

    Many studies have shown the importance of the ratio {upsilon}{sub He}/{upsilon}{sub E} in determining the level of He ash accumulation in future reactor systems. Results of the first tokamak He removal experiments have been analysed, and a first estimate of the ratio {upsilon}{sub He}/{upsilon}{sub E} to be expected for future reactor systems has been made. The experiments were carried out for neutral beam heated plasmas in the TEXTOR tokamak, at KFA/Julich. Helium was injected both as a short puff and continuously, and subsequently extracted with the Advanced Limiter Test-II pump limiter. The rate at which the He density decays has been determined with absolutely calibrated charge exchange spectroscopy, and compared with theoretical models, using the Multiple Impurity Species Transport (MIST) code. An analysis of energy confinement has been made with PPPL TRANSP code, to distinguish beam from thermal confinement, especially for low density cases. The ALT-II pump limiter system is found to exhaust the He with maximum exhaust efficiency (8 pumps) of {approximately}8%. We find 1<{upsilon}{sub He}/{upsilon}{sub E}<3.3 for the database of cases analysed to date. Analysis with the ITER TETRA systems code shows that these values would be adequate to achieve the required He concentration with the present ITER divertor He extraction system.

  12. Long duration ash probe

    DOE Patents [OSTI]

    Hurley, J.P.; McCollor, D.P.; Selle, S.J.

    1994-07-26

    A long duration ash probe includes a pressure shell connected to a port in a combustor with a sample coupon mounted on a retractable carriage so as to retract the sample coupon within the pressure shell during soot blowing operation of the combustor. A valve mounted at the forward end of the pressure shell is selectively closeable to seal the sample coupon within the shell, and a heating element in the shell is operable to maintain the desired temperature of the sample coupon while retracted within the shell. The carriage is operably mounted on a pair of rails within the shell for longitudinal movement within the shell. A hollow carrier tube connects the hollow cylindrical sample coupon to the carriage, and extends through the carriage and out the rearward end thereof. Air lines are connected to the rearward end of the carrier tube and are operable to permit coolant to pass through the air lines and thence through the carrier tube to the sample coupon so as to cool the sample coupon. 8 figs.

  13. Long duration ash probe

    DOE Patents [OSTI]

    Hurley, John P.; McCollor, Don P.; Selle, Stanley J.

    1994-01-01

    A long duration ash probe includes a pressure shell connected to a port in a combustor with a sample coupon mounted on a retractable carriage so as to retract the sample coupon within the pressure shell during sootblowing operation of the combustor. A valve mounted at the forward end of the pressure shell is selectively closeable to seal the sample coupon within the shell, and a heating element in the shell is operable to maintain the desired temperature of the sample coupon while retracted within the shell. The carriage is operably mounted on a pair of rails within the shell for longitudinal movement within the shell. A hollow carrier tube connects the hollow cylindrical sample coupon to the carriage, and extends through the carriage and out the rearward end thereof. Air lines are connected to the rearward end of the carrier tube and are operable to permit coolant to pass through the air lines and thence through the carrier tube to the sample coupon so as to cool the sample coupon.

  14. Jonathan White

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    White - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Energy Defense Waste Management Programs Advanced Nuclear Energy Nuclear

  15. Trophic structure and metal bioaccumulation differences in multiple fish species exposed to coal ash-associated metals

    SciTech Connect (OSTI)

    Otter, Ryan; Bailey, Frank; Fortner, Allison M; Adams, Marshall

    2012-01-01

    On December 22, 2008 a dike containing coal fly ash from the Tennessee Valley Authority Kingston Fossil Plant near Kingston Tennessee USA failed and resulted in the largest coal ash spill in U.S. history. Coal ash, the by-product of coal combustion, is known to contain multiple contaminants of concern, including arsenic and selenium. The purpose of this study was to investigate the bioaccumulation of arsenic and selenium and to identify possible differences in trophic dynamics in feral fish at various sites in the vicinity of the Kingston coal ash spill. Elevated levels of arsenic and selenium were observed in various tissues of largemouth bass, white crappie, bluegill and redear sunfish from sites associated with the Kingston coal ash spill. Highest concentrations of selenium were found in redear sunfish with liver concentrations as high as 24.83 mg/kg dry weight and ovary concentrations up to 10.40 mg/kg dry weight at coal ash-associated sites. To help explain the elevated selenium levels observed in redear sunfish, investigations into the gut pH and trophic dynamics of redear sunfish and bluegill were conducted which demonstrated a large difference in the gut physiology between these two species. Redear sunfish stomach and intestinal pH was found to be 1.1 and 0.16 pH units higher than in bluegill, respectively. In addition, fish from coal ash-associated sites showed enrichment of 15N & 13C compared to no ash sites, indicating differences in food web dynamics between sites. These results imply the incorporation of coal ash-associated compounds into local food webs and/or a shift in diet at ash sites compared to the no ash reference sites. Based on these results, further investigation into a broader food web at ash-associated sites is warranted.

  16. Fly ash chemical classification based on lime

    SciTech Connect (OSTI)

    Fox, J.

    2007-07-01

    Typically, total lime content (CaO) of fly ash is shown in fly ash reports, but its significance is not addressed in US specifications. For certain applications a low lime ash is preferred. When a class C fly ash must be cementitious, lime content above 20% is required. A ternary S-A-C phase diagram pilot is given showing the location of fly ash compositions by coal rank and source in North America. Fly ashes from subbituminous coal from the Powder River Basin usually contain sufficient lime to be cementitious but blending with other coals may result in calcium being present in phases other than tricalcium aluminate. 9 refs., 1 fig.

  17. Gasification of high ash, high ash fusion temperature bituminous coals

    DOE Patents [OSTI]

    Liu, Guohai; Vimalchand, Pannalal; Peng, WanWang

    2015-11-13

    This invention relates to gasification of high ash bituminous coals that have high ash fusion temperatures. The ash content can be in 15 to 45 weight percent range and ash fusion temperatures can be in 1150.degree. C. to 1500.degree. C. range as well as in excess of 1500.degree. C. In a preferred embodiment, such coals are dealt with a two stage gasification process--a relatively low temperature primary gasification step in a circulating fluidized bed transport gasifier followed by a high temperature partial oxidation step of residual char carbon and small quantities of tar. The system to process such coals further includes an internally circulating fluidized bed to effectively cool the high temperature syngas with the aid of an inert media and without the syngas contacting the heat transfer surfaces. A cyclone downstream of the syngas cooler, operating at relatively low temperatures, effectively reduces loading to a dust filtration unit. Nearly dust- and tar-free syngas for chemicals production or power generation and with over 90%, and preferably over about 98%, overall carbon conversion can be achieved with the preferred process, apparatus and methods outlined in this invention.

  18. Rising from the ashes: Coal ash in recycling and construction

    SciTech Connect (OSTI)

    Naquin, D.

    1998-02-01

    Beneficial Ash Management (BAM, Clearfield, Pa.) has won an environmental award for its use of ash and other waste to fight acid mine drainage. The company`s workers take various waste materials, mainly fly ash from coal-burning plants, to make a cement-like material or grouting, says Ernest Roselli, BAM president. The grouting covers the soil, which helps prevent water from contacting materials. This, in turn, helps control chemical reactions, reducing or eliminating formation of acid mine drainage. The company is restoring the 1,400-acre Bark Camp coal mine site near Penfield in Clearfield County, Pa. Under a no-cost contract with the state of Pennsylvania, BAM is using boiler slag, causticizing byproducts (lime) and nonreclaimable clarifier sludge from International Paper Co. (Erie, Pa.). The mine reclamation techniques developed and monitored at the site include using man-made wetlands to treat acid mine drainage and testing anhydrous ammonia as a similar treatment agent. BAM researches and tests fly ash mixed with lime-based activators as fill material for land reclamation, and develops and uses artificial soil material from paper mill and tannery biosolids.

  19. Publication sites productive uses of combustion ash

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Publication Sites Productive Uses of Combustion Ash For more information contact: e:mail: Public Affairs Golden, Colo., Jan. 23, 1997 -- A new technology brief published by the U.S. Department of Energy's National Renewable Energy Laboratory (NREL) describes how ash use can reduce the cost of waste management and not harm the environment. Communities in the United States typically dump municipal solid waste combustion ash in landfills. The new technology brief describes recent studies where ash

  20. A comparison between sludge ash and fly ash on the improvement in soft soil

    SciTech Connect (OSTI)

    Deng-Fong Lin; Kae-Long Lin; Huan-Lin Luo

    2007-01-15

    In this study, the strength of soft cohesive subgrade soil was improved by applying sewage sludge ash as a soil stabilizer. Test results obtained were compared with earlier tests conducted on soil samples treated with fly ash. Five different proportions of sludge ash and fly ash were mixed with soft cohesive soil, and tests such as pH value, compaction, California bearing ratio, unconfined compressive strength (UCS), and triaxial compression were performed to understand soil strength improvement because of the addition of both ashes. Results indicate that pH values increase with extending curing age for soil with sludge ash added. The UCS of sludge ash/soil were 1.4 2 times better than untreated soil. However, compressive strength of sludge ash/soil was 20 30 kPa less than fly ash/soil. The bearing capacities for both fly ash/soil and sludge ash/soil were five to six times and four times, respectively, higher than the original capacity. Moreover, the cohesive parameter of shear strength rose with increased amounts of either ash added. Friction angle, however, decreased with increased amounts of either ash. Consequently, results show that sewage sludge ash can potentially replace fly ash in the improvement of the soft cohesive soil. 9 refs., 5 figs., 2 tabs.

  1. Petrographic characterization of economizer fly ash

    SciTech Connect (OSTI)

    Valentim, B.; Hower, J.C.; Soares, S.; Guedes, A.; Garcia, C.; Flores, D.; Oliveira, A.

    2009-11-15

    Policies for reducing NOx emissions have led power plants to restrict O{sub 2}, resulting in high-carbon fly ash production. Therefore, some potentially useful fly ash, such as the economizer fly ash, is discarded without a thorough knowledge of its composition. In order to characterize this type of fly ash, samples were collected from the economizer Portuguese power plant burning two low-sulfur bituminous coals. Characterization was also performed on economizer fly ash subsamples after wet sieving, density and magnetic separation. Analysis included atomic absorption spectroscopy, loss-on-ignition, scanning electron microscopy/energy-dispersive X-ray spectroscopy, optical microscopy, and micro-Raman spectroscopy.

  2. ACAA fly ash basics: quick reference card

    SciTech Connect (OSTI)

    2006-07-01

    Fly ash is a fine powdery material created when coal is burned to generate electricity. Before escaping into the environment via the utility stacks, the ash is collected and may be stored for beneficial uses or disposed of, if necessary. The use of fly ash provides environmental benefits, such as the conservation of natural resources, the reduction of greenhouse gas emissions and eliminating the needed for ash disposal in landfills. It is also a valuable mineral resource that is used in construction and manufacturing. Fly ash is used in the production of Portland cement, concrete, mortars and stuccos, manufactured aggregates along with various agricultural applications. As mineral filler, fly ash can be used for paints, shingles, carpet backing, plastics, metal castings and other purposes. This quick reference card is intended to provide the reader basic source, identification and composition, information specifically related to fly ash.

  3. Combustion with reduced carbon in the ash

    DOE Patents [OSTI]

    Kobayashi, Hisashi; Bool, III, Lawrence E.

    2005-12-27

    Combustion of coal in which oxygen is injected into the coal as it emerges from burner produces ash having reduced amounts of carbon.

  4. Characterization of ash cenospheres in fly ash from Australian power stations

    SciTech Connect (OSTI)

    Ling-ngee Ngu; Hongwei Wu; Dong-ke Zhang

    2007-12-15

    Ash cenospheres in fly ashes from five Australian power stations have been characterized. The experimental data show that ash cenosphere yield varies across the power stations. Ash partitioning occurred in the process of ash cenosphere formation during combustion. Contradictory to conclusions from the literature, iron does not seem to be essential to ash cenosphere formation in the cases examined in the present work. Further investigation was also undertaken on a series of size-fractioned ash cenosphere samples from Tarong power station. It is found that about 70 wt% of ash cenospheres in the bulk sample have sizes between 45 and 150 {mu}m. There are two different ash cenosphere structures, that is, single-ring structure and network structure. The percentage of ash cenospheres of a network structure increases with increasing ash cenosphere size. Small ash cenospheres (in the size fractions {lt}150 {mu}m) have a high SiO{sub 2}/Al{sub 2}O{sub 3} ratio, and the majority of the ash cenospheres are spherical and of a single-ring structure. Large ash cenosphere particles (in the size fractions of 150-250 {mu}m and {gt}250 {mu}m) have a low SiO{sub 2}/Al{sub 2}O{sub 3} ratio, and a high proportion of the ash cenospheres are nonspherical and of a network structure. A novel quantitative technique has been developed to measure the diameter and wall thickness of ash cenospheres on a particle-to-particle basis. A monolayer of size-fractioned ash cenospheres was dispersed on a pellet, which was then polished carefully before being examined using a scanning electron microscope and image analysis. The ash cenosphere wall thickness broadly increases with increasing ash cenosphere size. The ratios between wall thickness and diameter of ash cenospheres are limited between an upper bound of about 10.5% and a lower bound of about 2.5%, irrespective of the ash cenosphere size. 52 refs., 9 figs., 4 tabs.

  5. Treatment of fly ash for use in concrete

    DOE Patents [OSTI]

    Boxley, Chett

    2012-05-15

    A process for treating fly ash to render it highly usable as a concrete additive. A quantity of fly ash is obtained that contains carbon and which is considered unusable fly ash for concrete based upon foam index testing. The fly ash is mixed with a quantity of spray dryer ash (SDA) and water to initiate a geopolymerization reaction and form a geopolymerized fly ash. The geopolymerized fly ash is granulated. The geopolymerized fly ash is considered usable fly ash for concrete according to foam index testing. The geopolymerized fly ash may have a foam index less than 40%, and in some cases less than 20%, of the foam index of the untreated fly ash. An optional alkaline activator may be mixed with the fly ash and SDA to facilitate the geopolymerization reaction. The alkaline activator may contain an alkali metal hydroxide, carbonate, silicate, aluminate, or mixtures thereof.

  6. Hunt's Ash Springs Pool & Spa Low Temperature Geothermal Facility...

    Open Energy Info (EERE)

    Hunt's Ash Springs Pool & Spa Low Temperature Geothermal Facility Jump to: navigation, search Name Hunt's Ash Springs Pool & Spa Low Temperature Geothermal Facility Facility Hunt's...

  7. Impact of Biodiesel on Ash Emissions and Lubricant Properties...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Biodiesel on Ash Emissions and Lubricant Properties Affecting Fuel Economy and Engine Wear Impact of Biodiesel on Ash Emissions and Lubricant Properties Affecting Fuel Economy and ...

  8. Settlement of footing on compacted ash bed

    SciTech Connect (OSTI)

    Ramasamy, G.; Pusadkar, S.S.

    2007-11-15

    Compacted coal ash fills exhibit capillary stress due to contact moisture and preconsolidation stress due to the compaction process. As such, the conventional methods of estimating settlement of footing on cohesionless soils based on penetration tests become inapplicable in the case of footings on coal ash fills, although coal ash is also a cohesionless material. Therefore, a method of estimating load-settlement behavior of footings resting on coal ash fills accounting for the effect of capillary and preconsolidation stresses is presented here. The proposed method has been validated by conducting plate load tests on laboratory prepared compacted ash beds and comparing the observed and predicted load-settlement behavior. Overestimation of settlement greater than 100% occurs when capillary and preconsolidation stresses are not accounted for, as is the case in conventional methods.

  9. Geotechnical characterization of some Indian fly ashes

    SciTech Connect (OSTI)

    Das, S.K.; Yudhbir

    2005-10-01

    This paper reports the findings of experimental studies with regard to some common engineering properties (e.g., grain size, specific gravity, compaction characteristics, and unconfined compression strength) of both low and high calcium fly ashes, to evaluate their suitability as embankment materials and reclamation fills. In addition, morphology, chemistry, and mineralogy of fly ashes are studied using scanning electron microscope, electron dispersive x-ray analyzer, x-ray diffractometer, and infrared absorption spectroscopy. In high calcium fly ash, mineralogical and chemical differences are observed for particles, {gt}75 {mu} m and the particles of {lt} 45 {mu} m size. The mode and duration of curing significantly affect the strength and stress-strain behavior of fly ashes. The geotechnical properties of fly ash are governed by factors like lime content (CaO), iron content (Fe{sub 2}O{sub 3}) and loss on ignition. The distinct difference between self-hardening and pozzolanic reactivity has been emphasized.

  10. Treatment of fly ash for use in concrete

    DOE Patents [OSTI]

    Boxley, Chett; Akash, Akash; Zhao, Qiang

    2013-01-08

    A process for treating fly ash to render it highly usable as a concrete additive. A quantity of fly ash is obtained that contains carbon and which is considered unusable fly ash for concrete based upon foam index testing. The fly ash is mixed with an activator solution sufficient to initiate a geopolymerization reaction and for a geopolymerized fly ash. The geopolymerized fly ash is granulated. The geopolymerized fly ash is considered usable fly ash for concrete according to foam index testing. The geopolymerized fly ash may have a foam index less than 35% of the foam index of the untreated fly ash, and in some cases less than 10% of the foam index of the untreated fly ash. The activator solution may contain an alkali metal hydroxide, carbonate, silicate, aluminate, or mixtures thereof.

  11. Treatment of fly ash for use in concrete

    DOE Patents [OSTI]

    Boxley, Chett; Akash, Akash; Zhao, Qiang

    2012-05-08

    A process for treating fly ash to render it highly usable as a concrete additive. A quantity of fly ash is obtained that contains carbon and which is considered unusable fly ash for concrete based upon foam index testing. The fly ash is mixed with an activator solution sufficient to initiate a geopolymerization reaction and for a geopolymerized fly ash. The geopolymerized fly ash is granulated. The geopolymerized fly ash is considered usable fly ash for concrete according to foam index testing. The geopolymerized fly ash may have a foam index less than 35% of the foam index of the untreated fly ash, and in some cases less than 10% of the foam index of the untreated fly ash. The activator solution may contain an alkali metal hydroxide, carbonate, silicate, aluminate, or mixtures thereof.

  12. Rocky Flats ash test procedure (sludge stabilization)

    SciTech Connect (OSTI)

    Winstead, M.L.

    1995-09-14

    Rocky Flats Ash items have been identified as the next set of materials to be stabilized. This test is being run to determine charge sizes and soak times to completely stabilize the Rocky Flats Ash items. The information gathered will be used to generate the heating rampup cycle for stabilization. This test will also gain information on the effects of the glovebox atmosphere (moisture) on the stabilized material. This document provides instructions for testing Rocky Flats Ash in the HC-21C muffle furnace process.

  13. Potential products from North Dakota lignite fly ash. Final report

    SciTech Connect (OSTI)

    Anderson, G R

    1980-06-01

    Four major areas where fly ash can be used are explored. Concrete building blocks with fly ash replacing 50% of the portland cement have proven to be successful using current ASTM standards. Results in the ceramics area show that a ceramic-like product using fly ash and crushed glass with a small amount of clay as a green binder. Some preliminary results using sulfur ash in building materials are reported and with results of making wallboard from ash. (MHR)

  14. Fluidized bed gasification ash reduction and removal process

    DOE Patents [OSTI]

    Schenone, Carl E.; Rosinski, Joseph

    1984-12-04

    In a fluidized bed gasification system an ash removal system to reduce the particulate ash to a maximum size or smaller, allow the ash to cool to a temperature lower than the gasifier and remove the ash from the gasifier system. The system consists of a crusher, a container containing level probes and a means for controlling the rotational speed of the crusher based on the level of ash within the container.

  15. Fluidized bed gasification ash reduction and removal system

    DOE Patents [OSTI]

    Schenone, Carl E.; Rosinski, Joseph

    1984-02-28

    In a fluidized bed gasification system an ash removal system to reduce the particulate ash to a maximum size or smaller, allow the ash to cool to a temperature lower than the gasifier and remove the ash from the gasifier system. The system consists of a crusher, a container containing level probes and a means for controlling the rotational speed of the crusher based on the level of ash within the container.

  16. Ashe County- Wind Energy System Ordinance

    Broader source: Energy.gov [DOE]

    In 2007 Ashe County adopted a wind ordinance to regulate the use of wind-energy systems in unincorporated areas of the county and to describe the conditions by which a permit for installing such a...

  17. Fly ash system technology improves opacity

    SciTech Connect (OSTI)

    2007-06-15

    Unit 3 of the Dave Johnston Power Plant east of Glenrock, WY, USA had problems staying at or below the opacity limits set by the state. The unit makes use of a Lodge Cottrell precipitator. When the plant changed to burning Power River Basin coal, ash buildup became a significant issue as the fly ash control system was unable to properly evacuate hoppers on the unit. To overcome the problem, the PLC on the unit was replaced with a software optimization package called SmartAsh for the precipitator fly ash control system, at a cost of $500,000. After the upgrade, there have been no plugged hoppers and the opacity has been reduced from around 20% to 3-5%. 2 figs.

  18. Rocky Flats Ash test procedure (sludge stabilization)

    SciTech Connect (OSTI)

    Funston, G.A.

    1995-06-14

    Rocky Flats Ash items have been identified as the next set of materials to be stabilized. This test is being run to determine charge sizes and soak times to completely stabilize the Rocky Flats Ash items. The information gathered will be used to generate the heating rampup cycle for stabilization. The test will provide information to determine charge sizes, soak times and mesh screen sizes (if available at time of test) for stabilization of Rocky Flats Ash items to be processed in the HC-21C Muffle Furnace Process. Once the charge size and soak times have been established, a program for the temperature controller of the HC-21C Muffle Furnace process will be generated for processing Rocky Flats Ash.

  19. Flue gas desulfurization gypsum and fly ash

    SciTech Connect (OSTI)

    Not Available

    1992-05-01

    The Cumberland Fossil Plant (CUF) is located in Stewart County, Tennessee, and began commercial operation in 1972. This is the Tennessee Valley Authority`s newest fossil (coal-burning) steam electric generating plant. Under current operating conditions, the plant burns approximately seven million tons of coal annually. By-products from the combustion of coal are fly ash, approximately 428,000 tons annually, and bottom ash, approximately 115,000 tons annually. Based on historical load and projected ash production rates, a study was initially undertaken to identify feasible alternatives for marketing, utilization and disposal of ash by-products. The preferred alternative to ensure that facilities are planned for all by-products which will potentially be generated at CUF is to plan facilities to handle wet FGD gypsum and dry fly ash. A number of different sites were evaluated for their suitability for development as FGD gypsum and ash storage facilities. LAW Engineering was contracted to conduct onsite explorations of sites to develop information on the general mature of subsurface soil, rock and groundwater conditions in the site areas. Surveys were also conducted on each site to assess the presence of endangered and threatened species, wetlands and floodplains, archaeological and cultural resources, prime farmland and other site characteristics which must be considered from an environmental perspective.

  20. White Light Creation Architectures

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Frontier Research Centers: Solid-State Lighting Science Center for Frontiers of ... White Light Creation Architectures HomeEnergy ResearchEFRCsSolid-State Lighting Science ...

  1. Comparative study on the characteristics of fly ash and bottom ash geopolymers

    SciTech Connect (OSTI)

    Chindaprasirt, Prinya; Jaturapitakkul, Chai; Chalee, Wichian; Rattanasak, Ubolluk

    2009-02-15

    This research was conducted to compare geopolymers made from fly ash and ground bottom ash. Sodium hydroxide (NaOH) and sodium silicate (Na{sub 2}SiO{sub 3}) solutions were used as activators. A mass ratio of 1.5 Na{sub 2}SiO{sub 3}/NaOH and three concentrations of NaOH (5, 10, and 15 M) were used; the geopolymers were cured at 65 deg. C for 48 h. A Fourier transform infrared spectrometer (FT-IR), differential scanning calorimeter (DSC), and scanning electron microscope (SEM) were used on the geopolymer pastes. Geopolymer mortars were also prepared in order to investigate compressive strength. The results show that both fly ash and bottom ash can be utilized as source materials for the production of geopolymers. The properties of the geopolymers are dependent on source materials and the NaOH concentration. Fly ash is more reactive and produces a higher degree of geopolymerization in comparison with bottom ash. The moderate NaOH concentration of 10 M is found to be suitable and gives fly ash and bottom ash geopolymer mortars with compressive strengths of 35 and 18 MPa.

  2. Scale-Up and Demonstration of Fly Ash Ozonation Technology

    SciTech Connect (OSTI)

    Rui Afonso; R. Hurt; I. Kulaots

    2006-03-01

    The disposal of fly ash from the combustion of coal has become increasingly important. When the fly ash does not meet the required specification for the product or market intended, it is necessary to beneficiate it to achieve the desired quality. This project, conducted at PPL's Montour SES, is the first near full-scale ({approx}10 ton/day), demonstration of ash ozonation technology. Bituminous and sub bituminous ashes, including two ash samples that contained activated carbon, were treated during the project. Results from the tests were very promising. The ashes were successfully treated with ozone, yielding concrete-suitable ash quality. Preliminary process cost estimates indicate that capital and operating costs to treat unburned carbon are competitive with other commercial ash beneficiation technologies at a fraction of the cost of lost sales and/or ash disposal costs. This is the final technical report under DOE Cooperative Agreement No.: DE-FC26-03NT41730.

  3. BPA White Book (generation/planning)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    White Book 2011 White Book 2010 White Book 2009 White Book 2008 White Book The 2008 White Book was not formally published due to work load constraints associated with completion of...

  4. Hydrothermal reaction of fly ash. Final report

    SciTech Connect (OSTI)

    Brown, P.W.

    1994-12-31

    The reactions which occur when fly ash is treated under hydrothermal conditions were investigated. This was done for the following primary reasons. The first of these is to determine the nature of the phases that form to assess the stabilities of these phases in the ambient environment and, finally, to assess whether these phases are capable of sequestering hazardous species. The second reason for undertaking this study was whether, depending on the composition of the ash and the presence of selected additives, it would be possible under hydrothermal conditions to form compounds which have cementitious properties. Formation of four classes of compounds, which bracket likely fly ash compositional ranges, were selected for study. The classes are calcium silicate hydrates, calcium selenates, and calcium aluminosulfates, and silicate-based glasses. Specific compounds synthesized were determined and their stability regions assessed. As part of stability assessment, the extent to which selected hazardous species are sequestered was determined. Finally, the cementing properties of these compounds were established. The results obtained in this program have demonstrated that mild hydrothermal conditions can be employed to improve the reactivity of fly ash. Such improvements in reactivity can result in the formation of monolithic forms which may exhibit suitable mechanical properties for selected applications as building materials. If the ashes involved are considered hazardous, the mechanical properties exhibited indicated the forms could be handled in a manner which facilitates their disposal.

  5. Extraction of trace metals from fly ash

    DOE Patents [OSTI]

    Blander, Milton; Wai, Chien M.; Nagy, Zoltan

    1984-01-01

    A process for recovering silver, gallium and/or other trace metals from a fine grained industrial fly ash associated with a process for producing phosphorous, the fly ash having a silicate base and containing surface deposits of the trace metals as oxides, chlorides or the like, with the process being carried out by contacting the fly ash with AlCl.sub.3 in an alkali halide melt to react the trace metals with the AlCl.sub.3 to form compositions soluble in the melt and a residue containing the silicate and aluminum oxide or other aluminum precipitate, and separating the desired trace metal or metals from the melt by electrolysis or other separation techniques.

  6. Extraction of trace metals from fly ash

    DOE Patents [OSTI]

    Blander, M.; Wai, C.M.; Nagy, Z.

    1983-08-15

    A process is described for recovering silver, gallium and/or other trace metals from a fine grained industrial fly ash associated with a process for producing phosphorous. The fly ash has a silicate base and contains surface deposits of the trace metals as oxides, chlorides or the like. The process is carried out by contacting the fly ash with AlCl/sub 3/ in an alkali halide melt to react the trace metals with the AlCl/sub 3/ to form compositions soluble in the melt and a residue containing the silicate and aluminum oxide or other aluminum precipitate, and separating the desired trace metal or metals from the melt by electrolysis or other separation techniques.

  7. White Tail | Open Energy Information

    Open Energy Info (EERE)

    Tail Jump to: navigation, search Name White Tail Facility White Tail Sector Wind energy Facility Type Commercial Scale Wind Facility Status In Service Owner Exelon Wind Developer...

  8. Correlation between the critical viscosity and ash fusion temperatures of coal gasifier ashes

    SciTech Connect (OSTI)

    Hsieh, Peter Y.; Kwong, Kyei-Sing; Bennett, James

    2015-09-27

    Coal gasification yields synthesis gas, an important intermediate in chemical manufacturing. It is also vital to the production of liquid fuels through the Fischer-Tropsch process and electricity in Integrated Gasification Combined Cycle power generation. Minerals naturally present in coal become molten in entrained-flow slagging gasifiers. Molten coal ash slag penetrates and dissolves refractory bricks, leading to costly plant shutdowns. The extent of coal ash slag penetration and refractory brick dissolution depends on the slag viscosity, the gasification temperature, and the composition of slag and bricks. Here, we measured the viscosity of several synthetic coal ash slags with a high-temperature rotary viscometer and their ash fusion temperatures through optical image analysis. We made all measurements in a carbon monoxide-carbon dioxide reducing atmosphere that approximates coal gasification conditions. Empirical correlation models based on ash fusion temperatures were used to calculate critical viscosity temperatures based on the coal ash compositions. These values were then compared with those obtained from thermodynamic phase-transition models. Finally, an understanding of slag viscosity as a function of ash composition is important to reducing refractory wear in slagging coal gasifiers, which would help to reduce the cost and environmental impact of coal for chemical and electricity production.

  9. Market assessment and technical feasibility study of PFBC ash use

    SciTech Connect (OSTI)

    Smith, V.E.; Bland, A.E.; Brown, T.H.; Georgiou, D.N.; Wheeldon, J.

    1994-10-01

    The overall objectives of this study are to determine the market potential and the technical feasibility of using PFBC ash in high volume ash use applications. The information will be of direct use to the utility industry in assessing the economics of PFBC power generation in light of ash disposal avoidance through ash marketing. In addition, the research is expected to result in the generation of generic data on the use of PFBC ash that could lead to novel processing options and procedures. The specific objectives of the proposed research and demonstration effort are: Define resent and future market potential of PFBC ash for a range of applications (Phase I); assess the technical feasibility of PFBC ash use in construction, civil engineering and agricultural applications (Phase II); and demonstrate the most promising of the market and ash use options in full-scale field demonstrations (Phase III).

  10. High carbon fly ash finds uses in highway construction

    SciTech Connect (OSTI)

    Wen, H.; Patton, R.

    2008-07-01

    The beneficial use of high carbon fly ash in a highway construction project is discussed. The fly ash also had a relatively high content of mercury and some other heavy metals. 1 fig., 4 photos.

  11. Eco-friendly fly ash utilization: potential for land application

    SciTech Connect (OSTI)

    Malik, A.; Thapliyal, A.

    2009-07-01

    The increase in demand for power in domestic, agricultural, and industrial sectors has increased the pressure on coal combustion and aggravated the problem of fly ash generation/disposal. Consequently the research targeting effective utilization of fly ash has also gained momentum. Fly ash has proved to be an economical substitute for expensive adsorbents as well as a suitable raw material for brick manufacturing, zeolite synthesis, etc. Fly ash is a reservoir of essential minerals but is deficient in nitrogen and phosphorus. By amending fly ash with soil and/or various organic materials (sewage sludge, bioprocess materials) as well as microbial inoculants like mycorrhizae, enhanced plant growth can be realized. Based on the sound results of large scale studies, fly ash utilization has grown into prominent discipline supported by various internationally renowned organizations. This paper reviews attempts directed toward various utilization of fly ash, with an emphasis on land application of organic/microbial inoculants amended fly ash.

  12. Uncovering Fundamental Ash-Formation Mechanisms and Potential...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Results illustrate ash particle growth and formation pathways, and influence of lubricant chemistry and exhaust conditions on fundamental ash properties deer12kamp.pdf (9.21 MB) ...

  13. Recovery Act Workers Complete Environmental Cleanup of Coal Ash...

    Office of Environmental Management (EM)

    Site (SRS) recently cleaned up a 17- acre basin containing coal ash residues from Cold War ... Recovery Act Workers Complete Environmental Cleanup of Coal Ash Basin U.S. Depar tment of ...

  14. Utilization of blended fluidized bed combustion (FBC) ash and pulverized coal combustion (PCC) fly ash in geopolymer

    SciTech Connect (OSTI)

    Chindaprasirt, Prinya; Rattanasak, Ubolluk

    2010-04-15

    In this paper, synthesis of geopolymer from fluidized bed combustion (FBC) ash and pulverized coal combustion (PCC) fly ash was studied in order to effectively utilize both ashes. FBC-fly ash and bottom ash were inter-ground to three different finenesses. The ashes were mixed with as-received PCC-fly ash in various proportions and used as source material for synthesis of geopolymer. Sodium silicate (Na{sub 2}SiO{sub 3}) and 10 M sodium hydroxide (NaOH) solutions at mass ratio of Na{sub 2}SiO{sub 3}/NaOH of 1.5 and curing temperature of 65 deg. C for 48 h were used for making geopolymer. X-ray diffraction (XRD), scanning electron microscopy (SEM), degree of reaction, and thermal gravimetric analysis (TGA) were performed on the geopolymer pastes. Compressive strength was also tested on geopolymer mortars. The results show that high strength geopolymer mortars of 35.0-44.0 MPa can be produced using mixture of ground FBC ash and as-received PCC-fly ash. Fine FBC ash is more reactive and results in higher degree of reaction and higher strength geopolymer as compared to the use of coarser FBC ash. Grinding increases reactivity of ash by means of increasing surface area and the amount of reactive phase of the ash. In addition, the packing effect due to fine particles also contributed to increase in strength of geopolymers.

  15. Using fly ash to mitigate explosions

    SciTech Connect (OSTI)

    Taulbee, D.

    2008-07-01

    In 2005 the University of Kentucky's Center for Applied Energy Research was given funding to evaluate the use of coal combustion by-products (CCBs) to reduce the explosive potential of ammonium nitrate (AN) fertilizers. Fly ash C (FAC), fly ash F (FAF) and flue gas desulfurization by-product (FGD) were evaluated. It was found that applying a CCB coating to the AN particles at concentrations of 5 wt% or greater prevented the AN explosion from propagating. The article reports on results so far and outlines further work to be done. 6 figs.

  16. Fly Ash Characteristics and Carbon Sequestration Potential

    SciTech Connect (OSTI)

    Palumbo, Anthony V.; Amonette, James E.; Tarver, Jana R.; Fagan, Lisa A.; McNeilly, Meghan S.; Daniels, William L.

    2007-07-20

    Concerns for the effects of global warming have lead to an interest in the potential for inexpensive methods to sequester carbon dioxide (CO2). One of the proposed methods is the sequestration of carbon in soil though the growth of crops or forests.4,6 If there is an economic value placed on sequestration of carbon dioxide in soil there may be an an opportunity and funding to utilize fly ash in the reclamation of mine soils and other degraded lands. However, concerns associated with the use of fly ash must be addressed before this practice can be widely adopted. There is a vast extent of degraded lands across the world that has some degree of potential for use in carbon sequestration. Degraded lands comprise nearly 2 X 109 ha of land throughout the world.7 Although the potential is obviously smaller in the United States, there are still approximately 4 X 106 ha of degraded lands that previously resulted from mining operations14 and an additional 1.4 X 108 ha of poorly managed lands. Thus, according to Lal and others the potential is to sequester approximately 11 Pg of carbon over the next 50 years.1,10 The realization of this potential will likely be dependent on economic incentives and the use of soil amendments such as fly ash. There are many potential benefits documented for the use of fly ash as a soil amendment. For example, fly ash has been shown to increase porosity, water-holding capacity, pH, conductivity, and dissolved SO42-, CO32-, HCO3-, Cl- and basic cations, although some effects are notably decreased in high-clay soils.8,13,9 The potential is that these effects will promote increased growth of plants (either trees or grasses) and result in greater carbon accumulation in the soil than in untreated degraded soils. This paper addresses the potential for carbon sequestration in soils amended with fly ash and examines some of the issues that should be considered in planning this option. We describe retrospective studies of soil carbon accumulation on

  17. Utilization options for fly ash, bottom ash, and slag in Eastern Europe

    SciTech Connect (OSTI)

    Manz, O.E.

    1995-12-01

    Since 1967, at least six ash utilization symposiums have been held in the United States, with papers presented by several European authors on the utilization of coal by-products in Eastern Europe. There is currently over 80,000 megawatts of installed coal-fired capacity available in that region. Unfortunately, of the 117,778,000 tonnes of fly ash, bottom ash, and slag produced in Eastern Europe in 1989, only 13% was utilized. This paper outlines the research and levels and kinds of coal by-product utilization taking place in Eastern Europe since the late 1960s.

  18. Uncovering Fundamental Ash-Formation Mechanisms and Potential Means to

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Control the Impact on DPF Performance and Engine Efficiency | Department of Energy Uncovering Fundamental Ash-Formation Mechanisms and Potential Means to Control the Impact on DPF Performance and Engine Efficiency Uncovering Fundamental Ash-Formation Mechanisms and Potential Means to Control the Impact on DPF Performance and Engine Efficiency Results illustrate ash particle growth and formation pathways, and influence of lubricant chemistry and exhaust conditions on fundamental ash

  19. Technical White Papers

    Broader source: Energy.gov [DOE]

    The following technical white papers explore potential options to increase widespread deployment of distributed generation (DG) and combined heat and power (CHP). Issues such as the treatment of CHP in renewable portfolio standards and CHP commissioning are discussed.

  20. DICE Diagnostic Service Joe Metzger

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (NNSA) DHS/National Operations Center The Department of Energy (DOE)/ Department of Homeland Security (DHS) Watch Office Desk in DHS's National Operations Center (NOC) represents DOE/NNSA within the NOC. In conjunction with over 80 federal, state, and local government agencies, the DOE/DHS Operations Center Watch Officer(s) collect, analyze and facilitate the exchange of vital information between DHS and DOE supporting the DHS mission of preventing and/or responding to acts of terrorism in

  1. Utilization of CFB fly ash for construction applications

    SciTech Connect (OSTI)

    Conn, R.E.; Sellakumar, K.; Bland, A.E.

    1999-07-01

    Disposal in landfills has been the most common means of handling ash in circulating fluidized bed (CFB) boiler power plants. Recently, larger CFB boilers with generating capacities up to 300 MWe are currently being planned, resulting in increased volumes and disposal cost of ash by-product. Studies have shown that CFB ashes do not pose environmental concerns that should significantly limit their potential utilization. Many uses of CFB ash are being investigated by Foster Wheeler, which can provide more cost-effective ash management. Construction applications have been identified as one of the major uses for CFB ashes. Typically, CFB ash cannot be used as a cement replacement in concrete due to its unacceptably high sulfur content. However, CFB ashes can be used for other construction applications that require less stringent specifications including soil stabilization, road base, structural fill, and synthetic aggregate. In this study, potential construction applications were identified for fly ashes from several CFB boilers firing diverse fuels such as petroleum coke, refuse derived fuel (RDF) and coal. The compressive strength of hydrated fly ashes was measured in order to screen their potential for use in various construction applications. Based on the results of this work, the effects of both ash chemistry and carbon content on utilization potential were ascertained. Actual beneficial uses of ashes evaluated in this study are also discussed.

  2. Oil ash corrosion; A review of utility boiler experience

    SciTech Connect (OSTI)

    Paul, L.D. ); Seeley, R.R. )

    1991-02-01

    In this paper a review of experience with oil ash corrosion is presented along with current design practices used to avoid excessive tube wastage. Factors influencing oil ash corrosion include fuel chemistry, boiler operation, and boiler design. These factors are interdependent and determine the corrosion behavior in utility boilers. Oil ash corrosion occurs when vanadium-containing ash deposits on boiler tube surfaces become molten. These molten ash deposits dissolve protective oxides and scales causing accelerated tube wastage. Vanadium is the major fuel constituent responsible for oil ash corrosion. Vanadium reacts with sodium, sulfur, and chlorine during combustion to produce lower melting temperature ash compositions, which accelerate tube wastage. Limiting tube metal temperatures will prevent ash deposits from becoming molten, thereby avoiding the onset of oil ash corrosion. Tube metal temperatures are limited by the use of a parallel stream flow and by limiting steam outlet temperatures. Operating a boiler with low excess air has helped avoid oil ash corrosion by altering the corrosive combustion products. Air mixing and distribution are essential to the success of this palliative action. High chromium alloys and coatings form more stable protective scaled on tubing surfaces, which result in lower oil ash corrosion rates. However, there is not material totally resistant to oil ash corrosion.

  3. Screening technology reduces ash in spiral circuits

    SciTech Connect (OSTI)

    Brodzik, P.

    2007-05-15

    In 2006, the James River Coal Co. selected the Stack Sizer to remove the minus 100 mesh high ash clay fraction from the clean coal spiral product circuits at the McCoy-Elkhorn Bevins Branch prep plant and at the Blue Diamond Leatherwood prep plant in Kentucky. The Stack Sizer is a multi-deck, high-frequency vibrating screen capable of separations as fine as 75 microns when fitted with Derrick Corp.'s patented high open area urethane screen panels. Full-scale lab tests and more than 10 months of continuous production have confirmed that the Stack Sizer fitted with Derrick 100 micron urethane screen panels consistently produces a clean coal fraction that ranges from 8 to 10% ash. Currently, each five-deck Stack Sizer operating at the Bevins Branch and Leatherwood prep plants is producing approximately 33 tons per hour of clean coal containing about 9% ash. This represents a clean coal yield of about 75% and an ash reduction of about 11% from the feed slurry. 3 figs. 2 tabs.

  4. Phase relationship in coal ash corrosion products

    SciTech Connect (OSTI)

    Kalmanovitch, D.

    1996-12-31

    The corrosion of heat transfer surfaces in coal-fired utility boilers is a major concern to the efficient operation of these units. Despite the importance of the corrosion there has been limited research on the relationship between the ash components on the tube surface and the interactions and reactions between the various components and the steel surface. Mechanisms such as molten phase corrosion, sulfidation, and high temperature oxidation have been identified as leading to extensive wastage oftube metal. However, while the corrosion process can be identified using techniques such as metallography and x-ray diffraction there is limited insight into the role ofthe coal mineralogy and ash deposits on the surface in the corrosion process. This paper describes research into the formation of molten or sernimolten phases within ash deposits which are associated with corrosion of superheater and reheater fireside surfaces. For example, the phases potassium pyrosulfate (K{sub 2}S{sub 2}O{sub 7}) and potassium aluminum sulfate (K{sub 2}Al{sub 2}SO{sub 7}) have been determined by x-ray diffraction to be present in deposits where fireside corrosion has occurred. However, both these phases are not directly derived from coal minerals or the common matrix observed in ash deposits. The examination of the reactions and interactions within deposits which result in the formation of these and other phases associated with corrosion will be discussed in the paper.

  5. Stabilizing soft fine-grained soils with fly ash

    SciTech Connect (OSTI)

    Edil, T.B.; Acosta, H.A.; Benson, C.H.

    2006-03-15

    The objective of this study was to evaluate the effectiveness of self-cementing fly ashes derived from combustion of subbituminous coal at electric power plants for stabilization of soft fine-grained soils. California bearing ratio (CBR) and resilient modulus (M{sub r}) tests were conducted on mixtures prepared with seven soft fine-grained soils (six inorganic soils and one organic soil) and four fly ashes. The soils were selected to represent a relatively broad range of plasticity, with plasticity indices ranging between 15 and 38. Two of the fly ashes are high quality Class C ashes (per ASTM C 618) that are normally used in Portland cement concrete. The other ashes are off-specification ashes, meaning they do not meet the Class C or Class F criteria in ASTM C 618. Tests were conducted on soils and soil-fly ash mixtures prepared at optimum water content (a standardized condition), 7% wet of optimum water content (representative of the typical in situ condition in Wisconsin), and 9-18% wet of optimum water content (representative of a very wet in situ condition). Addition of fly ash resulted in appreciable increases in the CBR and M{sub r} of the inorganic soils. For water contents 7% wet of optimum, CBRs of the soils alone ranged between 1 and 5. Addition of 10% fly ash resulted in CBRs ranging between 8 and 17, and 18% fly ash resulted in CBRs between 15 and 31. Similarly, M{sub r} of the soil alone ranged between 3 and 15 MPa at 7% wet of optimum, whereas addition of 10% fly ash resulted in M{sub r} between 12 and 60 MPa and 18% fly ash resulted in M{sub r} between 51 and 106 MPa. In contrast, except for one fly ash, addition of fly ash generally had little effect on CBR or M{sub r} of the organic soil.

  6. White light velocity interferometer

    DOE Patents [OSTI]

    Erskine, D.J.

    1997-06-24

    The invention is a technique that allows the use of broadband and incoherent illumination. Although denoted white light velocimetry, this principle can be applied to any wave phenomenon. For the first time, powerful, compact or inexpensive sources can be used for remote target velocimetry. These include flash and arc lamps, light from detonations, pulsed lasers, chirped frequency lasers, and lasers operating simultaneously in several wavelengths. The technique is demonstrated with white light from an incandescent source to measure a target moving at 16 m/s. 41 figs.

  7. White light velocity interferometer

    DOE Patents [OSTI]

    Erskine, David J.

    1997-01-01

    The invention is a technique that allows the use of broadband and incoherent illumination. Although denoted white light velocimetry, this principle can be applied to any wave phenomenon. For the first time, powerful, compact or inexpensive sources can be used for remote target velocimetry. These include flash and arc lamps, light from detonations, pulsed lasers, chirped frequency lasers, and lasers operating simultaneously in several wavelengths. The technique is demonstrated with white light from an incandescent source to measure a target moving at 16 m/s.

  8. White light velocity interferometer

    DOE Patents [OSTI]

    Erskine, David J.

    1999-01-01

    The invention is a technique that allows the use of broadband and incoherent illumination. Although denoted white light velocimetry, this principle can be applied to any wave phenomenon. For the first time, powerful, compact or inexpensive sources can be used for remote target velocimetry. These include flash and arc lamps, light from detonations, pulsed lasers, chirped frequency lasers, and lasers operating simultaneously in several wavelengths. The technique is demonstrated with white light from an incandescent source to measure a target moving at 16 m/s.

  9. White light velocity interferometer

    DOE Patents [OSTI]

    Erskine, D.J.

    1999-06-08

    The invention is a technique that allows the use of broadband and incoherent illumination. Although denoted white light velocimetry, this principle can be applied to any wave phenomenon. For the first time, powerful, compact or inexpensive sources can be used for remote target velocimetry. These include flash and arc lamps, light from detonations, pulsed lasers, chirped frequency lasers, and lasers operating simultaneously in several wavelengths. The technique is demonstrated with white light from an incandescent source to measure a target moving at 16 m/s. 41 figs.

  10. Fly ash and concrete: a study determines whether biomass, or coal co-firing fly ash, can be used in concrete

    SciTech Connect (OSTI)

    Wang, Shuangzhen; Baxter, Larry

    2006-08-01

    Current US national standards for using fly ash in concrete (ASTM C618) state that fly ash must come from coal combustion, thus precluding biomass-coal co-firing fly ash. The co-fired ash comes from a large and increasing fraction of US power plants due to rapid increases in co-firing opportunity fuels with coal. The fly ashes include coal fly ash, wood fly ash from pure wood combustion, biomass and coal co-fired fly ash SW1 and SW2. Also wood fly ash is blended with Class C or Class F to produce Wood C and Wood E. Concrete samples were prepared with fly ash replacing cement by 25%. All fly ash mixes except wood have a lower water demand than the pure cement mix. Fly ashes, either from coal or non coal combustion, increase the required air entraining agent (AEA) to meet the design specification of the mixes. If AEA is added arbitrarily without considering the amount or existence of fly ash results could lead to air content in concrete that is either too low or too high. Biomass fly ash does not impact concrete setting behaviour disproportionately. Switch grass-coal co-fired fly ash and blended wood fly ash generally lie within the range of pure coal fly ash strength. The 56 day flexure strength of all the fly ash mixes is comparable to that of the pure cement mix. The flexure strength from the coal-biomass co-fired fly ash does not differ much from pure coal fly ash. All fly ash concrete mixes exhibit lower chloride permeability than the pure cement mixes. In conclusion biomass coal co-fired fly ash perform similarly to coal fly ash in fresh and hardened concrete. As a result, there is no reason to exclude biomass-coal co-fired fly ash in concrete.

  11. Application of solid ash based catalysts in heterogeneous catalysis

    SciTech Connect (OSTI)

    Shaobin Wang

    2008-10-01

    Solid wastes, fly ash, and bottom ash are generated from coal and biomass combustion. Fly ash is mainly composed of various metal oxides and possesses higher thermal stability. Utilization of fly ash for other industrial applications provides a cost-effective and environmentally friendly way of recycling this solid waste, significantly reducing its environmental effects. On the one hand, due to the higher stability of its major component, aluminosilicates, fly ash could be employed as catalyst support by impregnation of other active components for various reactions. On the other hand, other chemical compounds in fly ash such as Fe{sub 2}O{sub 3} could also provide an active component making fly ash a catalyst for some reactions. In this paper, physicochemical properties of fly ash and its applications for heterogeneous catalysis as a catalyst support or catalyst in a variety of catalytic reactions were reviewed. Fly-ash-supported catalysts have shown good catalytic activities for H{sub 2} production, deSOx, deNOx, hydrocarbon oxidation, and hydrocracking, which are comparable to commercially used catalysts. As a catalyst itself, fly ash can also be effective for gas-phase oxidation of volatile organic compounds, aqueous-phase oxidation of organics, solid plastic pyrolysis, and solvent-free organic synthesis. 107 refs., 4 figs., 2 tabs.

  12. The leaching characteristics of selenium from coal fly ashes

    SciTech Connect (OSTI)

    Wang, T.; Wang, J.; Burken, J.G.; Ban, H.; Ladwig, K.

    2007-11-15

    The leaching characteristics of selenium from several bituminous and subbituminous coal fly ashes under different pH conditions were investigated using batch methods. Results indicated that pH had a significant effect on selenium leaching from bituminous coal ash. The minimum selenium leaching occurred in the pH range between 3 and 4, while the maximum selenium leaching occurred at pH 12. The release of selenium from subbituminous coal ashes was very low for the entire experimental pH range, possibly due to the high content of calcium which can form hydration or precipitation products as a sink for selenium. The adsorption results for different selenium species indicated that Se(VI) was hardly adsorbable on either bituminous coal ashes or subbitumminous coal ashes at any pH. However, Se(I) was highly adsorbed by bituminous coal ashes under acidic pH conditions and was mostly removed by subbitumminous coal ashes across the entire pH range. This result suggests that the majority of selenium released from the tested fly ashes was Se(IV). A speciation-based model was developed to simulate the adsorption of Se(IV) on bituminous coal fly ash, and the pH-independent adsorption constants of HSeO{sup 3-} and SeO{sub 3}{sup 2-} were determined. The modeling approach is useful for understanding and predicting the release process of selenium from fly ash.

  13. Water quality investigation of Kingston Fossil Plant dry ash stacking

    SciTech Connect (OSTI)

    Bohac, C.E.

    1990-04-01

    Changing to a dry ash disposal systems at Kingston Fossil Plant (KFP) raises several water quality issues. The first is that removing the fly ash from the ash pond could alter the characteristics of the ash pond discharge to the river. The second concerns proper disposal of the runoff and possibly leachate from the dry ash stack. The third is that dry ash stacking might change the potential for groundwater contamination at the KFP. This report addresses each of these issues. The effects on the ash pond and its discharge are described first. The report is intended to provide reference material to TVA staff in preparation of environmental review documents for new ash disposal areas at Kingston. Although the investigation was directed toward analysis of dry stacking, considerations for other disposal options are also discussed. This report was reviewed in draft form under the title Assessment of Kingston Fossil Plant Dry Ash Stacking on the Ash Pond and Groundwater Quality.'' 11 refs., 3 figs., 18 tabs.

  14. Fundamental Study of Low NOx Combustion Fly Ash Utilization

    SciTech Connect (OSTI)

    E. M. Suubert; I. Kuloats; K. Smith; N. Sabanegh; R.H. Hurt; W. D. Lilly; Y. M. Gao

    1997-05-01

    This study is principally concerned with characterizing the organic part of coal combustion fly ashes. High carbon fly ashes are becoming more common as by-products of low-NOx combustion technology, and there is need to learn more about this fraction of the fly ash. The project team consists of two universities, Brown and Princeton, and an electrical utility, New England Power. A sample suite of over forty fly ashes has been gathered from utilities across the United States, and includes ashes from a coals ranging in rank from bituminous to lignite. The characterizations of these ashes include standard tests (LOI, Foam Index), as well as more detailed characterizations of their surface areas, porosity, extractability and adsorption behavior. The ultimate goal is, by better characterizing the material, to enable broadening the range of applications for coal fly ash re-use beyond the current main market as a pozzolanic agent for concretes. The potential for high carbon-content fly ashes to substitute for activated carbons is receiving particular attention. The work performed to date has already revealed how very different the surfaces of different ashes produced by the same utility can be, with respect to polarity of the residual carbon. This can help explain the large variations in acceptability of these ashes as concrete additives.

  15. Fundamental Study of Low-Nox Combustion Fly Ash Utilization

    SciTech Connect (OSTI)

    E. M. Suuberg; I. Kuloats; K. Smith; N. Sabanegh; R. H. Hurt; W. D. Lilly; Y. M. Gao

    1997-11-01

    This study is principally concerned with characterizing the organic part of coal combustion fly ashes. High carbon fly ashes are becoming more common as by-products of low-NOx combustion technology, and there is need to learn more about this fraction of the fly ash. The project team consists of two universities, Brown and Princeton, and an electrical utility, New England Power. A sample suite of over forty fly ashes has been gathered from utilities across the United States, and includes ashes from a coals ranging in rank from bituminous to lignite. The characterizations of these ashes include standard tests (LOI, Foam Index), as well as more detailed characterizations of their surface areas, porosity, extractability and adsorption behavior. The ultimate goal is, by better characterizing the material, to enable broadening the range of applications for coal fly ash re-use beyond the current main market as a pozzolanic agent for concretes. The potential for high carbon-content fly ashes to substitute for activated carbons is receiving particular attention. The work performed to date has already revealed how very different the surfaces of different ashes produced by the same utility can be, with respect to polarity of the residual carbon. This can help explain the large variations in acceptability of these ashes as concrete additives.

  16. Helium transport and ash control studies

    SciTech Connect (OSTI)

    Miley, G.H.

    1992-01-01

    The Primary goal of this research is to develop a helium (ash) transport scaling law based on experimental data from devices such as TFTR and JET. To illustrate the importance of this, we have studied ash accumulation effects on ignition requirements using a O-D transport model. Ash accumulation is characterized in the model by the ratio of the helium particle confinement time to the energy confinement time t{sub {alpha}}/t{sub E}. Results show that the ignition window'' shrinks rapidly as t{sub {alpha}}/t{sub E} increases, closing for high t{sub {alpha}}/t{sub E} increases, closing for high t{sub {alpha}}/t{sub E}. A best'' value for t{sub {alpha}}/t{sub E} will ultimately be determined from our scaling law studies. A helium transport scaling law is being sought that expresses the transport coefficients (D{sub {alpha}}, V{sub {alpha}}) as a function of the local plasma parameters. This is necessary for use in transport code calculations, e.g. for BALDUR. Based on experimental data from L-mode plasma operation in TFTR, a scaling law to a power law expression has been obtained using a least-square fit method. It is found that the transport coefficients are strongly affected by the local magnetic field and safety factor q. A preliminary conclusion from this work is that active control of ash buildup must be developed. To study control, we have developed a O-D plasma model which employs a simple pole-placement control model. Some preliminary calculations with this model are presented.

  17. Eirich technology for the preparation of ashes

    SciTech Connect (OSTI)

    Eirich, G.

    1994-12-31

    The paper describes a mixer manufactured by Maschinenfabrik Gustav Eirich that can be used in the agglomeration of power plant ashes and residues. No matter whether the power plant burns coal, fuel oil, wood, peat, or garbage or whether the power plant plans to dispose or utilize the residue, most flowsheets will contain an agglomeration step. The paper describes some of the uses to which this mixer can be put.

  18. Manufacture of ceramic tiles from fly ash

    DOE Patents [OSTI]

    Hnat, James G.; Mathur, Akshay; Simpson, James C.

    1999-01-01

    The present invention relates to a process for forming glass-ceramic tiles. Fly ash containing organic material, metal contaminants, and glass forming materials is oxidized under conditions effective to combust the organic material and partially oxidize the metallic contaminants and the glass forming materials. The oxidized glass forming materials are vitrified to form a glass melt. This glass melt is then formed into tiles containing metallic contaminants.

  19. Manufacture of ceramic tiles from fly ash

    DOE Patents [OSTI]

    Hnat, J.G.; Mathur, A.; Simpson, J.C.

    1999-08-10

    The present invention relates to a process for forming glass-ceramic tiles. Fly ash containing organic material, metal contaminants, and glass forming materials is oxidized under conditions effective to combust the organic material and partially oxidize the metallic contaminants and the glass forming materials. The oxidized glass forming materials are vitrified to form a glass melt. This glass melt is then formed into tiles containing metallic contaminants. 6 figs.

  20. Market assessment of PFBC ash use

    SciTech Connect (OSTI)

    Bland, A. E.; Brown, T. H., Western Research Institute

    1998-01-01

    Pressurized fluidized bed combustion (PFBC) of coal is undergoing demonstration in the United States, as well as throughout the world. American Electric Power`s (AEP`s) bubbling PFBC 70 MWe Tidd demonstration program in Ohio and pilot-scale development at Foster Wheeler Energia Oy 10 MWth circulating PFBC at Karhula, Finland, have demonstrated the advantages of PFBC technology. Further technology development in the US is planned with the deployment of the technology at the MacIntosh Clean Coal project in Lakeland, Florida. Development of uses for solid wastes from PFBC coal-fired power systems is being actively pursued as part of the demonstration of PFBC technologies. Ashes collected from Foster Wheeler Energia Oy pilot circulating PFBC tests in Karhula, Finland, operating on (1) low sulfur subbituminous and (2) high sulfur bituminous coal; and ash from the AEP`s high-sulfur bituminous coal-fired bubbling PFBC in Brilliant, Ohio, were evaluated in laboratory and pilot-scale ash use testing at Western Research Institute (WRI).

  1. Phase relationships in coal ash corrosion products

    SciTech Connect (OSTI)

    Kalmanovitch, D.

    1996-10-01

    The corrosion of heat transfer surfaces in coal-fired utility boilers is a major concern to the efficient operation of these units. Despite the importance of the corrosion there has been limited research on the relationship between the ash components on the tube surface and the interactions and reactions between the various components and the steel surface. Mechanisms such as molten phase corrosion, sulfidation, and high temperature oxidation have been identified as leading to extensive wastage of tube metal. This paper describes research into the formation of molten or semimolten phases within ash deposits which are associated with corrosion of superheater and reheater fireside surfaces. For example, the phases potassium pyrosulfate (K{sub 2}S{sub 2}O{sub 7}) and potassium aluminum sulfate (K{sub 2}Al{sub 2}SO{sub 7}) have been determined by x-ray diffraction to be present in deposits where fireside corrosion has occurred. However, both these phases are not directly derived from coal minerals or the common matrix observed in ash deposits. The examination of the reactions and interactions within deposits which result a the formation of these and other phases associated with corrosion will be discussed in the paper.

  2. THE WHITE HOUSE | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    THE WHITE HOUSE THE WHITE HOUSE THE WHITE HOUSE (13.56 KB) More Documents & Publications Audit Report: IG-0473 Lapse Documents Inspection Report: IG-0397

  3. Franny White | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Franny White About Us Franny White - Pacific Northwest National Laboratory Franny White is a Public Information Officer at Pacific Northwest National Laboratory, one of the Department of Energy's 17 National Laboratories. Most Recent How to Make a Battery in 7 Steps May 24

  4. White House Tribal Youth Gathering

    Broader source: Energy.gov [DOE]

    The White House will host the first-ever White House Tribal Youth Gathering to provide American Indian and Alaska Native youth from across the country the opportunity to interact directly with senior Administration officials and the White House Council on Native American Affairs. Registration is due May 8, 2015.

  5. Utilization of ash from municipal solid waste combustion

    SciTech Connect (OSTI)

    Jones, C.; Hahn, J.; Magee, B.; Yuen, N.; Sandefur, K.; Tom, J.; Yap, C.

    1999-09-01

    This ash study investigated the beneficial use of municipal waste combustion combined ash from the H-POWER facility in Oahu. These uses were grouped into intermediate cover for final closure of the Waipahu landfill, daily cover at the Waimanalo Gulch Landfill, and partial replacement for aggregate in asphalt for road paving. All proposed uses examine combined fly and bottom ash from a modern waste-to-energy facility that meets requirements of the Clean Air Act Amendments for Maximum Achievable Control Technology.

  6. Development of Artificial Ash Accelerated Accumulation Test | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Artificial Ash Accelerated Accumulation Test Development of Artificial Ash Accelerated Accumulation Test Poster presented at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) Conference in Detroit, MI, September 27-30, 2010. p-04_fujii.pdf (138.91 KB) More Documents & Publications Impact of Honeycomb Ceramics Geometrical Cell Design on Urea SCR System Controlled Experiments on the Effects of Lubricant/Additive (Low-Ash, Ashless) Characteristics on DPF

  7. Lubricant Formulation and Consumption Effects on Diesel Exhaust Ash

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Emissions: | Department of Energy Lubricant Formulation and Consumption Effects on Diesel Exhaust Ash Emissions: Lubricant Formulation and Consumption Effects on Diesel Exhaust Ash Emissions: 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters 2005_deer_plumley.pdf (398.5 KB) More Documents & Publications Detailed Characterization of Lubricant-Derived Ash-Related Species in Diesel Exhaust and Aftertreatment Systems Unraveling DPF Degradation using Chemical

  8. Recovery of aluminum and other metal values from fly ash

    DOE Patents [OSTI]

    McDowell, William J.; Seeley, Forest G.

    1981-01-01

    The invention described herein relates to a method for improving the acid leachability of aluminum and other metal values found in fly ash which comprises sintering the fly ash, prior to acid leaching, with a calcium sulfate-containing composition at a temperature at which the calcium sulfate is retained in said composition during sintering and for a time sufficient to quantitatively convert the aluminum in said fly ash into an acid-leachable form.

  9. Recovery of aluminum and other metal values from fly ash

    DOE Patents [OSTI]

    McDowell, W.J.; Seeley, F.G.

    1979-11-01

    The invention relates to a method for improving the acid leachability of aluminum and other metal values found in fly ash which comprises sintering the fly ash, prior to acid leaching, with a calcium sulfate-containing composition at a temperature at which the calcium sulfate is retained in said composition during sintering and for a time sufficient to quantitatively convert the aluminum in said fly ash into an acid-leachable form.

  10. High Carbon Fly Ash Treatment | netl.doe.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    High Carbon Fly Ash Treatment NETL Collaborators Invent Method for Treating High Carbon Fly Ash The U.S. Patent and Trademark Office has assigned Patent No. 8,440,015 to researchers from Waynesburg University and the National Energy Technology Laboratory (NETL) for a thermal method that retains yet passivates carbon and/or other components in fly ash. John Baltrus, a research chemist at NETL, along with Professor Robert LaCount and Douglas Kern of Waynesburg University cooperated on the

  11. Reducing Lubricant Ash Impact on Exhaust Aftertreatment with...

    Office of Environmental Management (EM)

    Reducing Lubricant Ash Impact on Exhaust Aftertreatment with a Oil Conditioning Filter Under the test conditions used in this study, the strong base filter had a significant and ...

  12. Retention of elemental mercury in fly ashes in different atmospheres

    SciTech Connect (OSTI)

    M.A. Lopez-Anton; M. Diaz-Somoano; M.R. Martinez-Tarazona

    2007-01-15

    Mercury is an extremely volatile element, which is emitted from coal combustion to the environment mostly in the vapor phase. To avoid the environmental problems that the toxic species of this element may cause, control technologies for the removal of mercury are necessary. Recent research has shown that certain fly ash materials have an affinity for mercury. Moreover, it has been observed that fly ashes may catalyze the oxidation of elemental mercury and facilitate its capture. However, the exact nature of Hg-fly ash interactions is still unknown, and mercury oxidation through fly ash needs to be investigated more thoroughly. In this work, the influence of a gas atmosphere on the retention of elemental mercury on fly ashes of different characteristics was evaluated. The retention capacity was estimated comparatively in inert and two gas atmospheres containing species present in coal gasification and coal combustion. Fly ashes produced in two pulverized coal combustion (PCC) plants, produced from coals of different rank (CTA and CTSR), and a fly ash (CTP) produced in a fluidized bed combustion (FBC) plant were used as raw materials. The mercury retention capacity of these fly ashes was compared to the retention obtained in different activated carbons. Although the capture of mercury is very similar in the gasification atmosphere and N{sub 2}, it is much more efficient in a coal combustion retention, being greater in fly ashes from PCC than those from FBC plants. 22 refs., 6 figs., 3 tabs.

  13. Data Summary Report for Hanford Site Coal Ash Characterization

    SciTech Connect (OSTI)

    Sulloway, H. M.

    2012-03-06

    The purpose of this report is to present data and findings from sampling and analysis of five distinct areas of coal ash within the Hanford Site River Corridor

  14. Development of an Accelerated Ash-Loading Protocol for Diesel...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Development of an Accelerated Ash-Loading Protocol for Diesel Particulate Filters Poster presentation at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER ...

  15. Ashe County, North Carolina: Energy Resources | Open Energy Informatio...

    Open Energy Info (EERE)

    Ashe County, North Carolina: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 36.4339674, -81.4718387 Show Map Loading map......

  16. Ash Fork, Arizona: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Ash Fork, Arizona: Energy Resources Jump to: navigation, search Equivalent URI DBpedia Coordinates 35.2250114, -112.4840675 Show Map Loading map... "minzoom":false,"mappingser...

  17. Using fly ash and natural pozzolans in long life structures

    SciTech Connect (OSTI)

    Ramme, B.; Jacobsmeyer, J.

    2008-07-01

    The use of fly ash and natural pozzolans in various structures (roads, temples, bridges, buildings etc.) in the USA and Canada is discussed. 22 refs., 4 photos.

  18. Minimizing Lubricant-Ash Requirement and Impact on Emission Aftertreat...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Reducing Lubricant Ash Impact on Exhaust Aftertreatment with a Oil Conditioning Filter Effects of Fuel Dilution with Biodiesel on Lubricant Acidity, Oxidation and Corrosion ...

  19. white-98.pdf

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    whistleblower Whistleblower Program The DOE National Nuclear Security Administration Employee (NNSA) Concerns Program (ECP) is responsible for the 10 CFR Part 708 Contractor Employee Protection Program (weblink). Part 708 processes complaints by employees of DOE/NNSA contractors alleging retaliation by their employers for disclosure

    5 A Comparison of Shipboard and Island Observations from the Combined Sensor Program A. B. White Cooperative Institute for Research in Environmental Sciences

  20. Coal Ash Corrosion Resistant Materials Testing

    SciTech Connect (OSTI)

    D. K. McDonald; P. L. Daniel; D. J. DeVault

    2003-08-31

    In April 1999, three identical superheater test sections were installed into the Niles Unit No.1 for the purpose of testing and ranking the coal ash corrosion resistance of candidate superheater alloys. The Niles boiler burns high sulfur coal (3% to 3.5%) that has a reasonably high alkali content, thus the constituents necessary for coal ash corrosion are present in the ash. The test sections were controlled to operate with an average surface metal temperature from approximately 1060 F to 1210 F which was well within the temperature range over which coal ash corrosion occurs. Thus, this combination of aggressive environment and high temperature was appropriate for testing the performance of candidate corrosion-resistant tube materials. Analyses of the deposit and scale confirmed that the aggressive alkali-iron-trisulfate constituent was present at the metal surface and active in tube metal wastage. The test sections were constructed so that the response of twelve different candidate tube and/or coating materials could be studied. The plan was to remove and evaluate one of the three test sections at time intervals of 1 year, 3 years, and 5 years. This would permit an assessment of performance of the candidate materials as a function of time. This report provides the results of the evaluation of Test Section C, including the samples that remained in the Test Section for the full exposure period as well as those that were removed early. The analysis of Test Section C followed much the same protocol that was employed in the assessment of Test Section A. Again, the focus was on determining and documenting the relative corrosion rates of the candidate materials. The detailed results of the investigation are included in this report as a series of twelve appendices. Each appendix is devoted to the performance of one of the candidate alloys. The table below summarizes metal loss rate for the worst case sample of each of the candidate materials for both Test Sections A and C

  1. Effects of chemical composition of fly ash on efficiency of metal separation in ash-melting of municipal solid waste

    SciTech Connect (OSTI)

    Okada, Takashi; Tomikawa, Hiroki

    2013-03-15

    Highlights: ► Separation of Pb and Zn from Fe and Cu in ash-melting of municipal solid waste. ► Molar ratio of Cl to Na and K in fly ash affected the metal-separation efficiency. ► The low molar ratio and a non-oxidative atmosphere were better for the separation. - Abstract: In the process of metal separation by ash-melting, Fe and Cu in the incineration residue remain in the melting furnace as molten metal, whereas Pb and Zn in the residue are volatilized. This study investigated the effects of the chemical composition of incineration fly ash on the metal-separation efficiency of the ash-melting process. Incineration fly ash with different chemical compositions was melted with bottom ash in a lab-scale reactor, and the efficiency with which Pb and Zn were volatilized preventing the volatilization of Fe and Cu was evaluated. In addition, the behavior of these metals was simulated by thermodynamic equilibrium calculations. Depending on the exhaust gas treatment system used in the incinerator, the relationships among Na, K, and Cl concentrations in the incineration fly ash differed, which affected the efficiency of the metal separation. The amounts of Fe and Cu volatilized decreased by the decrease in the molar ratio of Cl to Na and K in the ash, promoting metal separation. The thermodynamic simulation predicted that the chlorination volatilization of Fe and Cu was prevented by the decrease in the molar ratio, as mentioned before. By melting incineration fly ash with the low molar ratio in a non-oxidative atmosphere, most of the Pb and Zn in the ash were volatilized leaving behind Fe and Cu.

  2. Process for the recovery of alumina from fly ash

    DOE Patents [OSTI]

    Murtha, M.J.

    1983-08-09

    An improvement in the lime-sinter process for recovering alumina from pulverized coal fly ash is disclosed. The addition of from 2 to 10 weight percent carbon and sulfur to the fly ash-calcium carbonate mixture increase alumina recovery at lower sintering temperatures.

  3. The recycling of the coal fly ash in glass production

    SciTech Connect (OSTI)

    Erol, M.M.; Kucukbayrak, S.; Ersoy-Mericboyu, A.

    2006-09-15

    The recycling of fly ash obtained from the combustion of coal in thermal power plant has been studied. Coal fly ash was vitrified by melting at 1773 K for 5 hours without any additives. The properties of glasses produced from coal fly ash were investigated by means of Differential Thermal Analysis (DTA), X-ray Diffraction (XRD) and Scanning Electron Microscopy (SEM) techniques. DTA study indicated that there was only one endothermic peak at 1003 K corresponding to the glass transition temperature. XRD analysis showed the amorphous state of the glass sample produced from coal fly ash. SEM investigations revealed that the coal fly ash based glass sample had smooth surface. The mechanical, physical and chemical properties of the glass sample were also determined. Recycling of coal fly ash by using vitrification technique resulted to a glass material that had good mechanical, physical and chemical properties. Toxicity characteristic leaching procedure (TCLP) results showed that the heavy metals of Pb, Cr, Zn and Mn were successfully immobilized into the glass. It can be said that glass sample obtained by the recycling of coal fly ash can be taken as a non-hazardous material. Overall, results indicated that the vitrification technique is an effective way for the stabilization and recycling of coal fly ash.

  4. Optimizing the use of fly ash in concrete

    SciTech Connect (OSTI)

    Thomas, M.

    2007-07-01

    The optimum amount of fly ash varies not only with the application, but also with composition and proportions of all the materials in the concrete mixture (especially the fly ash), the conditions during placing (especially temperature), construction practices (for example, finishing and curing) and the exposure conditions. This document discusses issues related to using low to very high levels of fly ash in concrete and provides guidance for the use of fly ash without compromising the construction process or the quality of the finished product. The nature of fly ashes including their physical, mineralogical and chemical properties is covered in detail, as well as fly ash variability due to coal composition and plant operating conditions. A discussion on the effects of fly ash characteristics on fresh and hardened concrete properties includes; workability, bleeding, air entrainment, setting time, heat of hydration, compressive strength development, creep, drying shrinkage, abrasion resistance, permeability, resistance to chlorides, alkali-silica reaction (ASR), sulfate resistance, carbonation, and resistance to freezing and thawing and deicer salt scaling. Case studies were selected as examples of some of the more demanding applications of fly ash concrete for ASR mitigation, chloride resistance, and green building.

  5. Fly ash and coal mineral matter surface transformations during heating

    SciTech Connect (OSTI)

    Baer, D R; Smith, R D

    1982-05-01

    A study is reported of surface segregation phenomena for fly ash and aluminosilicates representative of coal mineral matter during heating. The materials studied included a 20-..mu..m average diameter fly ash powder, a glass prepared from the fly ash, and Ca- and K-rich aluminosilicate minerals. The samples were heated both in air and under vacuum for extended periods at temperatures up to 1100/sup 0/C. XPS, Auger and SIMS methods were used to obtain relative surface elemental concentrations for major and minor components and depth profiles for some of the samples. Major differences were noted between samples heated in air (oxidizing) and those heated in vacuum (reducing) environments. For the fly ash glass heated in air Fe, Ti and Mg become enriched on the surfaces while heating in vacuum leads to Si surface segregation. Different trends upon heating were also observed for the Ca- and K-rich aluminosilicates. The results indicate two levels of surface enrichment upon the fly ash glass; a thin (< 500 A) layer and a thicker (1- to 2-..mu..m) layer most evident for heating in air where an Fe-rich layer is formed. The present results indicate that the rates of surface segregation may not be sufficiently fast on the time scale of fly ash formation to result in equilibrium surface segregation. It is concluded that condensation processes during fly ash formation probably play a major role in the observed fly ash surface enrichments.

  6. Hot-Gas Filter Ash Characterization Project

    SciTech Connect (OSTI)

    Swanson, M.L.; Hurley, J.P.; Dockter, B.A.; O`Keefe, C.A.

    1997-07-01

    Large-scale hot-gas filter testing over the past 10 years has revealed numerous cases of cake buildup on filter elements that has been difficult, if not impossible, to remove. At times, the cake can blind or bridge between candle filters, leading to filter failure. Physical factors, including particle-size distribution, particle shape, the aerodynamics of deposition, and system temperature, contribute to the difficulty in removing the cake, but chemical factors such as surface composition and gas-solid reactions also play roles in helping to bond the ash to the filters or to itself. This project is designed to perform the research necessary to determine the fuel-, sorbent-, and operations-related conditions that lead to blinding or bridging of hot-gas particle filters. The objectives of the project are threefold: (1) Determine the mechanisms by which a difficult-to-clean ash is formed and how it bridges hot-gas filters (2) Develop a method to determine the rate of bridging based on analyses of the feed coal and sorbent, filter properties, and system operating conditions and (3) Suggest and test ways to prevent filter bridging.

  7. STRATEGIES AND TECHNOLOGY FOR MANAGING HIGH-CARBON ASH

    SciTech Connect (OSTI)

    Robert Hurt; Eric Suuberg; John Veranth; Xu Chen

    2002-09-10

    The overall objective of the present project is to identify and assess strategies and solutions for the management of industry problems related to carbon in ash. Specific research issues to be addressed include: (1) the effect of parent fuel selection on ash properties and adsorptivity, including a first ever examination of the air entrainment behavior of ashes from alternative (non-coal) fuels; (2) the effect of various low-NOx firing modes on ash properties and adsorptivity; and (3) the kinetics and mechanism of ash ozonation. This data will provide scientific and engineering support of the ongoing process development activities. During this fourth project period we completed the characterization of ozone-treated carbon surfaces and wrote a comprehensive report on the mechanism through which ozone suppresses the adsorption of concrete surfactants.

  8. Ward Co. Dunn Co. McLean Co. McHenry Co. Mountrail Co. McKenzie Co.

    U.S. Energy Information Administration (EIA) Indexed Site

    WHISKEY JOE WHITE ASH SPRING COULEE DES LACS MAGPIE HARTLAND BEICEGEL CREEK RANCH COULEE WINNER CRAZY MAN CREEK GROS VENTRE BANK W BULLSNAKE UPLAND COULEE REFUGE LARSON GARNET ALKALI CREEK PLUMER RATTLESNAKE POINT ELLSWORTH CHURCH BORDER HANSON GROVER HULSE COULEE SAKAKAWEA AURELIA ROUND TOP BUTTE GORHAM BUTTE W MARMON MANITOU SHEALEY CLAYTON SERGIS N SADDLE BUTTE HAYLAND CEDAR COULEE BOWLINE LITTLE BUTTE LONG CREEK RHOADES HEDBERG FILLMORE EIDSVOLD FAIRFIELD WOLF BAY TOBACCO GARDEN N SPRING

  9. COAL-FIRED UTILITY BOILERS: SOLVING ASH DEPOSITION PROBLEMS

    SciTech Connect (OSTI)

    Christopher J. Zygarlicke; Donald P. McCollor; Steven A. Benson; Jay R. Gunderson

    2001-04-01

    The accumulation of slagging and fouling ash deposits in utility boilers has been a source of aggravation for coal-fired boiler operators for over a century. Many new developments in analytical, modeling, and combustion testing methods in the past 20 years have made it possible to identify root causes of ash deposition. A concise and comprehensive guidelines document has been assembled for solving ash deposition as related to coal-fired utility boilers. While this report accurately captures the current state of knowledge in ash deposition, note that substantial research and development is under way to more completely understand and mitigate slagging and fouling. Thus, while comprehensive, this document carries the title ''interim,'' with the idea that future work will provide additional insight. Primary target audiences include utility operators and engineers who face plant inefficiencies and significant operational and maintenance costs that are associated with ash deposition problems. Pulverized and cyclone-fired coal boilers are addressed specifically, although many of the diagnostics and solutions apply to other boiler types. Logic diagrams, ash deposit types, and boiler symptoms of ash deposition are used to aid the user in identifying an ash deposition problem, diagnosing and verifying root causes, determining remedial measures to alleviate or eliminate the problem, and then monitoring the situation to verify that the problem has been solved. In addition to a step-by-step method for identifying and remediating ash deposition problems, this guideline document (Appendix A) provides descriptions of analytical techniques for diagnostic testing and gives extensive fundamental and practical literature references and addresses of organizations that can provide help in alleviating ash deposition problems.

  10. Assessment of the impact of radionuclides in coal ash

    SciTech Connect (OSTI)

    Styron, C.E.; Bishop, C.T.; Casella, V.R.; Jenkins, P.H.; Yanko, W.H.

    1981-01-01

    An assessment of the potential environmental and health impacts of radionuclides in the coal fuel cycle is being conducted at Mound. This paper describes our studies evaluating the potential for migration of radionuclides from ash disposal sites. Studies at a power plant burning western US coal dealt with an assessment of potential radiation doses from coal ash ponds and leachate discharges of radionuclides from the ponds. Emanation of radon-222 from the ash is relatively low. The emanation of radon-222 from the ash pond (radium-226 at 4.5 pCi/g) is predicted to be about six times less than from soil (radium-226 at 1 pCi/g). Ash with radium-226 at 25 pCi/g would approximate emanation of radon-222 from soil. At 1000 m from the center of the ash pond area, radon-222 from the ash pond is predicted to be 1000 to 6000 times less than background (0.1 to 0.5 pCi/liter). Pathways exist for transport of radionuclides leached from ash into the aquifer beneath the holding ponds, but concentrations of radionuclides in water leaving the pond are lower than concentrations in groundwater which is upgradient of the ponds. Leachability of the ash is quite low, on the order of 0.002% in one month, and flow of ash sluicing water (3% of the volume of the ponds each day) has actually diluted normal background concentrations of radionuclides in the aquifer between the ponds and the adjacent river.

  11. Toxicity mitigation and solidification of municipal solid waste incinerator fly ash using alkaline activated coal ash

    SciTech Connect (OSTI)

    Ivan Diaz-Loya, E.; Allouche, Erez N.; Eklund, Sven; Joshi, Anupam R.; Kupwade-Patil, Kunal

    2012-08-15

    Highlights: Black-Right-Pointing-Pointer Incinerator fly ash (IFA) is added to an alkali activated coal fly ash (CFA) matrix. Black-Right-Pointing-Pointer Means of stabilizing the incinerator ash for use in construction applications. Black-Right-Pointing-Pointer Concrete made from IFA, CFA and IFA-CFA mixes was chemically characterized. Black-Right-Pointing-Pointer Environmentally friendly solution to IFA disposal by reducing its toxicity levels. - Abstract: Municipal solid waste (MSW) incineration is a common and effective practice to reduce the volume of solid waste in urban areas. However, the byproduct of this process is a fly ash (IFA), which contains large quantities of toxic contaminants. The purpose of this research study was to analyze the chemical, physical and mechanical behaviors resulting from the gradual introduction of IFA to an alkaline activated coal fly ash (CFA) matrix, as a mean of stabilizing the incinerator ash for use in industrial construction applications, where human exposure potential is limited. IFA and CFA were analyzed via X-ray fluorescence (XRF), X-ray diffraction (XRD) and Inductive coupled plasma (ICP) to obtain a full chemical analysis of the samples, its crystallographic characteristics and a detailed count of the eight heavy metals contemplated in US Title 40 of the Code of Federal Regulations (40 CFR). The particle size distribution of IFA and CFA was also recorded. EPA's Toxicity Characteristic Leaching Procedure (TCLP) was followed to monitor the leachability of the contaminants before and after the activation. Also images obtained via Scanning Electron Microscopy (SEM), before and after the activation, are presented. Concrete made from IFA, CFA and IFA-CFA mixes was subjected to a full mechanical characterization; tests include compressive strength, flexural strength, elastic modulus, Poisson's ratio and setting time. The leachable heavy metal contents (except for Se) were below the maximum allowable limits and in many cases

  12. Fluidization characteristics of power-plant fly ashes and fly ash-charcoal mixtures. [MS Thesis; 40 references

    SciTech Connect (OSTI)

    Nguyen, C.T.

    1980-03-01

    As a part of the continuing research on aluminum recovery from fly ash by HiChlor process, a plexiglass fluidization column system was constructed for measurement of fluidization parameters for power-plant fly ashes and fly ash-charcoal mixtures. Several bituminous and subbituminous coal fly ashes were tested and large differences in fluidization characteristics were observed. Fly ashes which were mechanically collected fluidized uniformly at low gas flow rates. Most fly ashes which were electrostatically precipitated exhibited channeling tendency and did not fluidize uniformly. Fluidization characteristics of electrostatically collected ashes improve when the finely divided charcoal powder is added to the mixture. The fluidization of the mixture was aided initially by a mechanical stirrer. Once the fluidization had succeeded, the beds were ready to fluidize without the assistance of a mechanical action. Smooth fluidization and large bed expansion were usually observed. The effects of charcoal size and aspect ratio on fluidization characteristics of the mixtures were also investigated. Fluidization characteristics of a fly ash-coal mixture were tested. The mixture fluidized only after being oven-dried for a few days.

  13. Erick A. White | Bioenergy | NREL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Erick A. White Erick A. White Research Engineer Erick.White@nrel.gov | 303-384-6238 Research Interests Electrochemical and thermochemical conversion of biomass-derived compounds to chemicals and fuels Numeric modeling of chemical reaction kinetics and reactor hydrodynamics Process modeling to assist techno-economic analyses Electrochemical impedance spectroscopy techniques for the characterization of electrochemical systems Developing and characterizing reactors and systems for energy generation

  14. Effect of fuel properties on the bottom ash generation rate by a laboratory fluidized bed combustor

    SciTech Connect (OSTI)

    Rozelle, P.L.; Pisupati, S.V.; Scaroni, A.W.

    2007-06-15

    The range of fuels that can be accommodated by an FBC boiler system is affected by the ability of the fuel, sorbent, and ash-handling equipment to move the required solids through the boiler. Of specific interest is the bottom ash handling equipment, which must have sufficient capacity to remove ash from the system in order to maintain a constant bed inventory level, and must have sufficient capability to cool the ash well below the bed temperature. Quantification of a fuel's bottom ash removal requirements can be useful for plant design. The effect of fuel properties on the rate of bottom ash production in a laboratory FBC test system was examined. The work used coal products ranging in ash content from 20 to 40+ wt. %. The system's classification of solids by particle size into flyash and bottom ash was characterized using a partition curve. Fuel fractions in the size range characteristic of bottom ash were further analyzed for distributions of ash content with respect to specific gravity, using float sink tests. The fuel fractions were then ashed in a fixed bed. In each case, the highest ash content fraction produced ash with the coarsest size consist (characteristic of bottom ash). The lower ash content fractions were found to produce ash in the size range characteristic of flyash, suggesting that the high ash content fractions were largely responsible for the production of bottom ash. The contributions of the specific gravity fractions to the composite ash in the fuels were quantified. The fuels were fired in the laboratory test system. Fuels with higher amounts of high specific gravity particles, in the size ranges characteristic of bottom ash, were found to produce more bottom ash, indicating the potential utility of float sink methods in the prediction of bottom ash removal requirements.

  15. Mutagenicity and genotoxicity of coal fly ash water leachate

    SciTech Connect (OSTI)

    Chakraborty, R.; Mukherjee, A.

    2009-03-15

    Fly ash is a by-product of coal-fired electricity generation plants. The prevalent practice of disposal is as slurry of ash and water to storage or ash ponds located near power stations. This has lain to waste thousands of hectares of land all over the world. Since leaching is often the cause of off-site contamination and pathway of introduction into the human environment, a study on the genotoxic effects of fly ash leachate is essential. Leachate prepared from the fly ash sample was analyzed for metal content, and tested for mutagenicity and genotoxicity. Analyses of metals show predominance of the metals - sodium, silicon, potassium, calcium, magnesium, iron, manganese, zinc, and sulphate. The Ames Salmonella mutagenicity assay, a short-term bacterial reverse mutation assay, was conducted on two-tester strains of Salmonella typhimurium strains TA97a and TA102. For genotoxicity, the alkaline version of comet assay on fly ash leachate was carried in vitro on human blood cells and in vivo on Nicotiana plants. The leachate was directly mutagenic and induced significantconcentration-dependent increases in DNA damage in whole blood cells, lymphocytes, and in Nicotiana plants. The comet parameters show increases in tail DNA percentage (%), tail length (mu m), and olive tail moment (arbitrary units). Our results indicate that leachate from fly ash dumpsites has the genotoxic potential and may lead to adverse effects on vegetation and on the health of exposed human populations.

  16. Water holding capacities of fly ashes: Effect of size fractionation

    SciTech Connect (OSTI)

    Sarkar, A.; Rano, R.

    2007-07-01

    Water holding capacities of fly ashes from different thermal power plants in Eastern India have been compared. Moreover, the effect of size fractionation (sieving) on the water holding capacities has also been determined. The desorption rate of water held by the fly ash fractions at ambient temperature (25-30{sup o}C) has been investigated. The effect of mixing various size fractions of fly ash in increasing the water holding capacities of fly ash has been studied. It is observed that the fly ash obtained from a thermal power plant working on stoker-fired combustor has the highest water holding capacity, followed by the one that works on pulverized fuel combustor. Fly ash collected from super thermal power plant has the least water holding capacity (40.7%). The coarser size fractions of fly ashes in general have higher water holding capacities than the finer ones. An attempt has been made to correlate the results obtained, with the potential use in agriculture.

  17. Characterization and possible uses of ashes from wastewater treatment plants

    SciTech Connect (OSTI)

    Merino, Ignacio; Arevalo, Luis F. . E-mail: fromero@ehu.es

    2005-07-01

    This work, on the ashes from the wastewater treatment plant of Galindo (Vizcaya, Spain), has been outlined with the purpose of finding their physico-chemical properties and suggesting possible applications. Ashes contain important quantities of iron, calcium, silica, alumina and phosphates. X-Ray diffraction data make it possible to estimate the mineralogical compositions of the original ashes and also, after thermal treatment at 1200 and 1300 deg. C, the main reactions occurring in thermal treatment. Particle size analysis makes it possible to classify ashes as a very fine powdered material. The thermal treatment leads to a densification of the material and provokes losses of weight mainly due to the elimination of water, carbon dioxide and sulphur trioxide. Application tests show that ashes are not suitable for landfill and similar applications, because of their plastic properties. Testing for pozzolanic character, after the ashes had been heated at 1200 deg. C, did not lead to a strong material probably due to low contents in silica and alumina or to requiring a higher heating temperature. Thermal treatment leads to densification of the material with a considerable increase of compressive strength of the probes. The use of additives (clays and powdered glass) to improve ceramic properties of ashes will be the aim of a future work.

  18. Coal Ash Corrosion Resistant Materials Testing Program

    SciTech Connect (OSTI)

    McDonald, D K

    2003-04-22

    The "Coal Ash Corrosion Resistant Materials Testing Program" is being conducted by The Babcock & Wilcox Company (B&W), the U.S. Department of Energy (DOE) and the Ohio Coal Development Office (OCDO) at Reliant Energy's Niles plant in Niles, Ohio to provide full-scale, in-situ testing of recently developed boiler superheater materials. Fireside corrosion is a key issue for improving efficiency of new coal fired power plants and improving service life in existing plants. In November 1998, B&W began development of a system to permit testing of advanced tube materials at metal temperatures typical of advanced supercritical steam temperatures (1100°F and higher) in a boiler exhibiting coal ash corrosive conditions. Several materials producers including Oak Ridge National Laboratory (ORNL) contributed advanced materials to the project. In the spring of 1999 a system consisting of three identical sections, each containing multiple segments of twelve different materials, was installed. The sections are cooled by reheat steam, and are located just above the furnace entrance in Niles' Unit #1, a 110 MWe unit firing high sulfur Ohio coal. In November 2001 the first section was removed for thorough metallurgical evaluation after 33 months of operation. The second and third sections remain in service and the second is expected to be removed in the fall of 2003; the last is tentatively planned for the fall of 2004. This paper describes the program; its importance; the design, fabrication, installation and operation of the test system; materials utilized; experience to date; and results of the evaluation of the first section.

  19. Distribution of arsenic and mercury in lime spray dryer ash

    SciTech Connect (OSTI)

    Panuwat Taerakul; Ping Sun; Danold W. Golightly; Harold W. Walker; Linda K. Weavers

    2006-08-15

    The partitioning of As and Hg in various components of lime spray dryer (LSD) ash samples from a coal-fired boiler was characterized to better understand the form and fate of these elements in flue gas desulfurization byproducts. LSD ash samples, collected from the McCracken Power Plant on the Ohio State University campus, were separated by a 140-mesh (106 {mu}m) sieve into two fractions: a fly-ash-/unburned-carbon-enriched fraction (> 106 {mu}m) and a calcium-enriched fraction (< 106 {mu}m). Unburned carbon and fly ash in the material > 106 {mu}m were subsequently separated by density using a lithium heteropolytungstate solution. The concentrations of As and Hg were significant in all fractions. The level of As was consistently greater in the calcium-enriched fraction, while Hg was evenly distributed in all components of LSD ash. Specific surface area was an important factor controlling the distribution of Hg in the different components of LSD ash, but not for As. Comparing the LSD ash data to samples collected from the economizer suggests that As was effectively captured by fly ash at 600{sup o}C, while Hg was not. Leaching tests demonstrated that As and Hg were more stable in the calcium-enriched fraction than in the fly-ash- or carbon-enriched fractions, potentially because of the greater pH of the leachate and subsequently greater stability of small amounts of calcium solids containing trace elements in these fractions. 37 refs., 8 figs., 2 tabs.

  20. Ash formation, deposition, corrosion, and erosion in conventional boilers

    SciTech Connect (OSTI)

    Benson, S.A.; Jones, M.L.

    1995-12-01

    The inorganic components (ash-forming species) associated with coals significantly affect boiler design, efficiency of operation, and lifetimes of boiler parts. During combustion in conventional pulverized fuel boilers, the inorganic components are transformed into inorganic gases, liquids, and solids. This partitioning depends upon the association of the inorganic components in the coal and combustion conditions. The inorganic components are associated as mineral grains and as organically associated elements, and these associations of inorganic components in the fuel directly influence their fate upon combustion. Combustion conditions, such as temperature and atmosphere, influence the volatility and the interaction of inorganic components during combustion and gas cooling, which influences the state and size composition distribution of the particulate and condensed ash species. The intermediate species are transported with the bulk gas flow through the combustion systems, during which time the gases and entrained ash are cooled. Deposition, corrosion, and erosion occur when the ash intermediate species are transported to the heat-transfer surface, react with the surface, accumulate, sinter, and develop strength. Research over the past decade has significantly advanced understanding of ash formation, deposition, corrosion, and erosion mechanisms. Many of the advances in understanding and predicting ash-related issues can be attributed to advanced analytical methods to determine the inorganic composition of fuels and the resulting ash materials. These new analytical techniques have been the key to elucidation of the mechanisms of ash formation and deposition. This information has been used to develop algorithms and computer models to predict the effects of ash on combustion system performance.

  1. Increasing Class C fly ash reduces alkali silica reactivity

    SciTech Connect (OSTI)

    Hicks, J.K.

    2007-07-01

    Contrary to earlier studies, it has been found that incremental additions of Class C fly ash do reduce alkali silica reactivity (ASR), in highly reactive, high alkali concrete mixes. AST can be further reduced by substituting 5% metakaolin or silica fume for the aggregate in concrete mixes with high (more than 30%) Class C fly ash substitution. The paper reports results of studies using Class C fly ash from the Labadie Station plant in Missouri which typically has between 1.3 and 1.45% available alkalis by ASTM C311. 7 figs.

  2. Recovery of iron oxide from coal fly ash

    DOE Patents [OSTI]

    Dobbins, Michael S.; Murtha, Marlyn J.

    1983-05-31

    A high quality iron oxide concentrate, suitable as a feed for blast and electric reduction furnaces is recovered from pulverized coal fly ash. The magnetic portion of the fly ash is separated and treated with a hot strong alkali solution which dissolves most of the silica and alumina in the fly ash, leaving a solid residue and forming a precipitate which is an acid soluble salt of aluminosilicate hydrate. The residue and precipitate are then treated with a strong mineral acid to dissolve the precipitate leaving a solid residue containing at least 90 weight percent iron oxide.

  3. Novel microorganism for selective separation of coal from pyrite and ash. Final report

    SciTech Connect (OSTI)

    Misra, M.; Smith, R.W.

    1995-09-01

    The separation of fine coal from ash and pyrite was evaluated using a microorganism Mycobacterium phlei.

  4. Coal Ash Corrosion Resistant Materials Testing

    SciTech Connect (OSTI)

    D. K. McDonald; P. L. Daniel; D. J. DeVault

    2007-12-31

    In April 1999, three identical superheater test sections were installed into the Niles Unit No.1 for the purpose of testing and ranking the coal ash corrosion resistance of candidate superheater alloys. The Niles boiler burns high sulfur coal (3% to 3.5%) that has a moderate alkali content (0.2% sodium equivalents), thus the constituents necessary for coal ash corrosion are present in the ash. The test sections were controlled to operate with an average surface metal temperature from approximately 1060 F to 1210 F which was within the temperature range over which coal ash corrosion occurs. Thus, this combination of aggressive environment and high temperature was appropriate for testing the performance of candidate corrosion-resistant tube materials. Analyses of the deposit and scale confirmed that aggressive alkali sulfate constituents were present at the metal surface and active in tube metal wastage. The test sections were constructed so that the response of twelve different candidate tube and/or coating materials could be studied. The plan was to remove and evaluate one of the three test sections at time intervals of 1 year, 3 years, and 5 years. This would permit an assessment of performance of the candidate materials as a function of time. Test Section A was removed in November 2001 after about 24 months of service at the desired steam temperature set point, with about 15.5 months of exposure at full temperature. A progress report, issued in October 2002, was written to document the performance of the candidate alloys in that test section. The evaluation described the condition of each tube sample after exposure. It involved a determination of the rate of wall thickness loss for these samples. In cases where there was more than one sample of a candidate material in the test section, an assessment was made of the performance of the alloy as a function of temperature. Test Sections B and C were examined during the November 2001 outage, and it was decided that

  5. Blue Ash, Ohio: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Hide Map This article is a stub. You can help OpenEI by expanding it. Blue Ash is a city in Hamilton County, Ohio. It falls under Ohio's 2nd congressional...

  6. Recoverable immobilization of transuranic elements in sulfate ash

    DOE Patents [OSTI]

    Greenhalgh, Wilbur O.

    1985-01-01

    Disclosed is a method of reversibly immobilizing sulfate ash at least about 20% of which is sulfates of transuranic elements. The ash is mixed with a metal which can be aluminum, cerium, samarium, europium, or a mixture thereof, in amounts sufficient to form an alloy with the transuranic elements, plus an additional amount to reduce the transuranic element sulfates to elemental form. Also added to the ash is a fluxing agent in an amount sufficient to lower the percentage of the transuranic element sulfates to about 1% to about 10%. The mixture of the ash, metal, and fluxing agent is heated to a temperature sufficient to melt the fluxing agent and the metal. The mixture is then cooled and the alloy is separated from the remainder of the mixture.

  7. Transcending Portland Cement with 100 percent fly ash concrete

    SciTech Connect (OSTI)

    Cross, D.; Akin, M.; Stephens, J.; Cuelh, E.

    2009-07-01

    The use of concrete, made with 100% fly ash and no Portland cement, in buildings at the Transportation Institute in Bozeman, MT, USA, is described. 3 refs., 7 figs.

  8. Recovery Act Workers Complete Environmental Cleanup of Coal Ash Basin

    Broader source: Energy.gov [DOE]

    The Savannah River Site (SRS) recently cleaned up a 17-acre basin containing coal ash residues from Cold War operations. The American Recovery and Reinvestment Act project was safely completed at a...

  9. Compressive strength of concrete and mortar containing fly ash

    DOE Patents [OSTI]

    Liskowitz, J.W.; Wecharatana, M.; Jaturapitakkul, C.; Cerkanowicz, A.E.

    1998-12-29

    The present invention relates to concrete, mortar and other hardenable mixtures comprising cement and fly ash for use in construction. The invention includes a method for predicting the compressive strength of such a hardenable mixture, which is very important for planning a project. The invention also relates to hardenable mixtures comprising cement and fly ash which can achieve greater compressive strength than hardenable mixtures containing only concrete over the time period relevant for construction. In a specific embodiment, a formula is provided that accurately predicts compressive strength of concrete containing fly ash out to 180 days. In other specific examples, concrete and mortar containing about 15% to 25% fly ash as a replacement for cement, which are capable of meeting design specification required for building and highway construction, are provided. Such materials can thus significantly reduce construction costs. 33 figs.

  10. Compressive strength of concrete and mortar containing fly ash

    DOE Patents [OSTI]

    Liskowitz, John W.; Wecharatana, Methi; Jaturapitakkul, Chai; Cerkanowicz, deceased, Anthony E.

    1997-01-01

    The present invention relates to concrete, mortar and other hardenable mixtures comprising cement and fly ash for use in construction. The invention includes a method for predicting the compressive strength of such a hardenable mixture, which is very important for planning a project. The invention also relates to hardenable mixtures comprising cement and fly ash which can achieve greater compressive strength than hardenable mixtures containing only concrete over the time period relevant for construction. In a specific embodiment, a formula is provided that accurately predicts compressive strength of concrete containing fly ash out to 180 days. In other specific examples, concrete and mortar containing about 15% to 25% fly ash as a replacement for cement, which are capable of meeting design specifications required for building and highway construction, are provided. Such materials can thus significantly reduce construction costs.

  11. Compressive strength of concrete and mortar containing fly ash

    DOE Patents [OSTI]

    Liskowitz, John W.; Wecharatana, Methi; Jaturapitakkul, Chai; Cerkanowicz, deceased, Anthony E.

    1998-01-01

    The present invention relates to concrete, mortar and other hardenable mixtures comprising cement and fly ash for use in construction. The invention includes a method for predicting the compressive strength of such a hardenable mixture, which is very important for planning a project. The invention also relates to hardenable mixtures comprising cement and fly ash which can achieve greater compressive strength than hardenable mixtures containing only concrete over the time period relevant for construction. In a specific embodiment, a formula is provided that accurately predicts compressive strength of concrete containing fly ash out to 180 days. In other specific examples, concrete and mortar containing about 15% to 25% fly ash as a replacement for cement, which are capable of meeting design specification required for building and highway construction, are provided. Such materials can thus significantly reduce construction costs.

  12. Compressive strength of concrete and mortar containing fly ash

    DOE Patents [OSTI]

    Liskowitz, J.W.; Wecharatana, M.; Jaturapitakkul, C.; Cerkanowicz, A.E.

    1997-04-29

    The present invention relates to concrete, mortar and other hardenable mixtures comprising cement and fly ash for use in construction. The invention includes a method for predicting the compressive strength of such a hardenable mixture, which is very important for planning a project. The invention also relates to hardenable mixtures comprising cement and fly ash which can achieve greater compressive strength than hardenable mixtures containing only concrete over the time period relevant for construction. In a specific embodiment, a formula is provided that accurately predicts compressive strength of concrete containing fly ash out to 180 days. In other specific examples, concrete and mortar containing about 15% to 25% fly ash as a replacement for cement, which are capable of meeting design specifications required for building and highway construction, are provided. Such materials can thus significantly reduce construction costs. 33 figs.

  13. Optical properties of fly ash. Volume 2, Final report

    SciTech Connect (OSTI)

    Self, S.A.

    1994-12-01

    Research performed under this contract was divided into four tasks under the following headings: Task 1, Characterization of fly ash; Task 2, Measurements of the optical constants of slags; Task 3, Calculations of the radiant properties of fly ash dispersions; and Task 4, Measurements of the radiant properties of fly ash dispersions. Tasks 1 and 4 constituted the Ph.D. research topic of Sarbajit Ghosal, while Tasks 2 and 3 constituted the Ph.D. research topic of Jon Ebert. Together their doctoral dissertations give a complete account of the work performed. This final report, issued in two volumes consists of an executive summary of the whole program followed by the dissertation of Ghosal and Ebert. Volume 2 contains the dissertation of Ebert which covers the measurements of the optical constants of slags, and calculations of the radiant properties of fly ash dispersions. A list of publications and conference presentations resulting from the work is also included.

  14. How toxic is coal ash? A laboratory toxicity case study

    SciTech Connect (OSTI)

    Sherrard, Rick M.; Carriker, Neil; Greeley, Jr., Mark Stephen

    2014-12-08

    Under a consent agreement among the Environmental Protection Agency (EPA) and proponents both for and against stricter regulation, EPA is to issue a new coal ash disposal rule by the end of 2014. Laboratory toxicity investigations often yield conservative estimates of toxicity because many standard test species are more sensitive than resident species, thus could provide information useful to the rule-making. However, few laboratory studies of coal ash toxicity are available; most studies reported in the literature are based solely on field investigations. In this paper, we describe a broad range of toxicity studies conducted for the Tennessee Valley Authority (TVA) Kingston ash spill, results of which help provide additional perspective on the toxicity of coal ash.

  15. How toxic is coal ash? A laboratory toxicity case study

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sherrard, Rick M.; Carriker, Neil; Greeley, Jr., Mark Stephen

    2014-12-08

    Under a consent agreement among the Environmental Protection Agency (EPA) and proponents both for and against stricter regulation, EPA is to issue a new coal ash disposal rule by the end of 2014. Laboratory toxicity investigations often yield conservative estimates of toxicity because many standard test species are more sensitive than resident species, thus could provide information useful to the rule-making. However, few laboratory studies of coal ash toxicity are available; most studies reported in the literature are based solely on field investigations. In this paper, we describe a broad range of toxicity studies conducted for the Tennessee Valley Authoritymore » (TVA) Kingston ash spill, results of which help provide additional perspective on the toxicity of coal ash.« less

  16. Minimizing Lubricant-Ash Requirement and Impact on Emission Aftertreatment

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Systems via an Oil Conditioning Filter | Department of Energy Minimizing Lubricant-Ash Requirement and Impact on Emission Aftertreatment Systems via an Oil Conditioning Filter Minimizing Lubricant-Ash Requirement and Impact on Emission Aftertreatment Systems via an Oil Conditioning Filter Presentation given at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007, Detroit, Michigan. Sponsored by the U.S. Department of Energy's (DOE) Office of

  17. White Energy Ltd | Open Energy Information

    Open Energy Info (EERE)

    White Energy Ltd Place: Dallas, Texas Zip: 75240 Product: White Energy plans to invest in the development, acquisition and construction of biofuel plants in the USA. Coordinates:...

  18. Whites Renewable Energy | Open Energy Information

    Open Energy Info (EERE)

    Whites Renewable Energy Jump to: navigation, search Name: Whites Renewable Energy Place: United Kingdom Zip: YO8 8EF Sector: Biomass, Renewable Energy Product: UK based company...

  19. Ash Reduction of Corn Stover by Mild Hydrothermal Preprocessing

    SciTech Connect (OSTI)

    M. Toufiq Reza; Rachel Emerson; M. Helal Uddin; Garold Gresham; Charles J. Coronella

    2014-04-22

    Lignocellulosic biomass such as corn stover can contain high ash content, which may act as an inhibitor in downstream conversion processes. Most of the structural ash in biomass is located in the cross-linked structure of lignin, which is mildly reactive in basic solutions. Four organic acids (formic, oxalic, tartaric, and citric) were evaluated for effectiveness in ash reduction, with limited success. Because of sodium citrates chelating and basic characteristics, it is effective in ash removal. More than 75 % of structural and 85 % of whole ash was removed from the biomass by treatment with 0.1 g of sodium citrate per gram of biomass at 130 C and 2.7 bar. FTIR, fiber analysis, and chemical analyses show that cellulose and hemicellulose were unaffected by the treatment. ICPAES showed that all inorganics measured were reduced within the biomass feedstock, except sodium due to the addition of Na through the treatment. Sodium citrate addition to the preconversion process of corn stover is an effective way to reduced physiological ash content of the feedstock without negatively impacting carbohydrate and lignin content.

  20. Ash level meter for a fixed-bed coal gasifier

    DOE Patents [OSTI]

    Fasching, George E.

    1984-01-01

    An ash level meter for a fixed-bed coal gasifier is provided which utilizes the known ash level temperature profile to monitor the ash bed level. A bed stirrer which travels up and down through the extent of the bed ash level is modified by installing thermocouples to measure the bed temperature as the stirrer travels through the stirring cycle. The temperature measurement signals are transmitted to an electronic signal process system by an FM/FM telemetry system. The processing system uses the temperature signals together with an analog stirrer position signal, taken from a position transducer disposed to measure the stirrer position to compute the vertical location of the ash zone upper boundary. The circuit determines the fraction of each total stirrer cycle time the stirrer-derived bed temperature is below a selected set point, multiplies this fraction by the average stirrer signal level, multiplies this result by an appropriate constant and adds another constant such that a 1 to 5 volt signal from the processor corresponds to a 0 to 30 inch span of the ash upper boundary level. Three individual counters in the processor store clock counts that are representative of: (1) the time the stirrer temperature is below the set point (500.degree. F.), (2) the time duration of the corresponding stirrer travel cycle, and (3) the corresponding average stirrer vertical position. The inputs to all three counters are disconnected during any period that the stirrer is stopped, eliminating corruption of the measurement by stirrer stoppage.

  1. Alumni: Claire White, Princeton University

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Claire White, Princeton University Alumni Link: Opportunities, News and Resources for Former Employees Latest Issue:September 2015 all issues All Issues » submit Alumni: Claire White, Princeton University Reducing air emissions with new ways to make concrete May 1, 2015 The site offers a variety of Los Alamos-developed biosurveillance tools that can be used for decision support in disease surveillance. The site offers a variety of Los Alamos-developed biosurveillance tools that can be used for

  2. Inside the White House: Solar Panels | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Inside the White House: Solar Panels Inside the White House: Solar Panels

  3. Leaching of Mixtures of Biochar and Fly Ash

    SciTech Connect (OSTI)

    Palumbo, Anthony Vito; Porat, Iris; Phillips, Jana Randolph; Amonette, J. E.; Drake, Meghan M; Brown, Steven D; Schadt, Christopher Warren

    2009-01-01

    Increasing atmospheric levels of greenhouse gases, especially CO2, and their effects on global temperature have led to interest in the possibility of carbon storage in terrestrial environments.2, 5, 6 Both the residual char from biomass pyrolysis7-9, 12 (biochar) and fly ash from coal combustion1, 13, 14 have the potential to significantly expand terrestrial sequestration options. Both biochar and fly ash also have potentially beneficial effects on soil properties. Fly ash has been shown to increase porosity, water-holding capacity, pH, conductivity, and dissolved SO42-, CO32-, Cl- and basic cations.10, 11, 16 Adding biochar to soil generally raises pH, increases total nitrogen and total phosphorous, encourages greater root development, improves cation exchange capacity and reduces available aluminum.3, 17 Combinations of these benefits likely lead to the observed increased yields for crops including corn and sugarcane.17 with biochar addition to soil. In addition, it has been found that soils with added biochar emit lower amounts of other greenhouse gases (methane and nitrous oxide) 8, 17 than do unammended soils. Biochar and fly ash amendments may be useful in promoting terrestrial carbon sequestration on currently underutilized and degraded lands. For example, about 1% of the US surface lands consist of previously mined lands or highway rights-of-way.18 Poorly managed lands could count for another 15% of US area. Biochar and fly ash amendments could increase productivity of these lands and increase carbon storage in the soil Previous results showed minimal leaching of organic carbon and metals from a variety of fly ashes.15 Here, we are examining the properties of mixtures of biochar, fly ash, and soil and evaluating leaching of organic carbon and metals from the mixtures.

  4. ADVANCED POWER SYSTEMS ASH BEHAVIOR IN POWER SYSTEMS

    SciTech Connect (OSTI)

    CHRISTOPHER J. ZYGARLICKE; DONALD P. MCCOLLOR; JOHN P. KAY; MICHAEL L. SWANSON

    1998-09-01

    The overall goal of this initiative is to develop fundamental knowledge of ash behavior in power systems for the purpose of increasing power production efficiency, reducing operation and maintenance costs, and reducing greenhouse gas emissions into the atmosphere. The specific objectives of this initiative focus primarily on ash behavior related to advanced power systems and include the following: ? Determine the current status of the fundamental ash interactions and deposition formation mechanisms as already reported through previous or ongoing projects at the EERC or in the literature. ? Determine sintering mechanisms for temperatures and particle compositions that are less well known and remain for the most part undetermined. ? Identify the relationship between the temperature of critical viscosity (Tcv ) as measured in a viscometer and the crystallization occurring in the melt. ? Perform a literature search on the use of heated-stage microscopy (HSM) for examining in situ ash-sintering phenomena and then validate the use of HSM in the determination of viscosity in spherical ash particles. ? Ascertain the formation and stability of specific mineral or amorphous phases in deposits typical of advanced power systems. ? Evaluate corrosion for alloys being used in supercritical combustion systems.

  5. Chloride chemical form in various types of fly ash

    SciTech Connect (OSTI)

    Fenfen Zhu; Masaki Takaoka; Kenji Shiota; Kazuyuki Oshita; Yoshinori Kitajima

    2008-06-01

    Chloride content is a critical problem for the reuse of fly ash as a raw material in cement, and the method used by recyclers to reduce the fly ash chloride content depends on the chemical form of the chlorides. However, limited information is available on the quantitative distribution of chlorides and the identity of some chlorides such as Friedel's salt. We examined chloride forms and percentages using X-ray absorption near edge structure and X-ray diffraction analyses, as well as corresponding washing experiments. Approximately 15% of the chlorine in raw fly ash was estimated to be in the form of NaCl, 10% in KCl, 50% in CaCl{sub 2}, and the remainder in the form of Friedel's salt. Fly ash collected in a bag filter with the injection of calcium hydroxide for acid gas removal (CaFA) contained 35% chlorine as NaCl, 11% as KCl, 37% as CaCl{sub 2}, 13% as Friedel's salt, and the remaining 4% as CaClOH. In fly ash collected in a bag filter with the injection of sodium bicarbonate for acid gas removal (NaFA), approximately 79% of chlorine was in NaCl, 12% was in KCl, and 9% was in Friedel's salt. 25 refs., 4 figs., 4 tabs.

  6. Release of Ammonium and Mercury from NOx Controlled Fly Ash

    SciTech Connect (OSTI)

    Schroeder, K.T.; Cardone, C.R.; Kim, A.G

    2007-07-01

    One of the goals of the Department of Energy is to increase the reuse of coal utilization byproducts (CUB) to 50% by 2010. This will require both developing new markets and maintaining traditional ones such as the use of fly ash in concrete. However, the addition of pollution control devices can introduce side-effects that affect the marketability of the CUB. Such can be the case when NOx control is achieved using selective catalytic or non-catalytic reduction (SCR or SNCR). Depending on site-specific details, the ammonia slip can cause elevated levels of NH3 in the fly ash. Disposal of ammoniated fly ash can present environmental concerns related to the amount of ammonia that might be released, the amount of water that might become contaminated, and the extent to which metals might be mobilized by the presence of the ammonia. Ammonia retained in fly ash appears to be present as either an ammonium salt or as a chemisorbed species. Mercury in the leachates correlated to neither the amount of leachable ammonium nor to the total amount of Hg in the ash. The strongest correlation was between the decreases in the amount of Hg leached with increased LOI.

  7. Ash bed level control system for a fixed-bed coal gasifier

    DOE Patents [OSTI]

    Fasching, George E.; Rotunda, John R.

    1984-01-01

    An ash level control system is provided which incorporates an ash level meter to automatically control the ash bed level of a coal gasifier at a selected level. The ash level signal from the ash level meter is updated during each cycle that a bed stirrer travels up and down through the extent of the ash bed level. The ash level signal is derived from temperature measurements made by thermocouples carried by the stirrer as it passes through the ash bed and into the fire zone immediately above the ash bed. The level signal is compared with selected threshold level signal to determine if the ash level is above or below the selected level once each stirrer cycle. A first counter is either incremented or decremented accordingly. The registered count of the first counter is preset in a down counter once each cycle and the preset count is counted down at a selected clock rate. A grate drive is activated to rotate a grate assembly supporting the ash bed for a period equal to the count down period to maintain the selected ash bed level. In order to avoid grate binding, the controller provides a short base operating duration time each stirrer cycle. If the ash bed level drops below a selected low level or exceeds a selected high level, means are provided to notify the operator.

  8. Cementation and solidification of Rocky Flats Plant incinerator ash

    SciTech Connect (OSTI)

    Phillips, J.A.; Semones, G.B.

    1994-04-01

    Cementation studies on various aqueous waste streams at Rocky Flats have shown this technology to be effective for immobilizing the RCRA constituents in the waste. Cementation is also being evaluated for encapsulation of incinerator ash. Experiments will initially evaluate a surrogate ash waste using a Taguchi experimental design to optimize the cement formulation and waste loading levels for this application. Variables of waste loading, fly ash additions, water/cement ratio, and cement type will be tested at three levels each during the course of this work. Tests will finally be conducted on actual waste using the optimized cement formulation developed from this testing. This progression of tests will evaluate the effectiveness of cement encapsulation for this waste stream without generating any additional wastes.

  9. Carter Co. Harding Co. Perkins Co. Dunn Co. Dawson Co. Fallon...

    U.S. Energy Information Administration (EIA) Indexed Site

    BICENTENNIAL MEDICINE POLE HILLS BIG STICK ROOSEVELT ROUGH RIDER MONARCH TREE TOP LOOKOUT BUTTE BUCKHORN MEDORA FLAT TOP BUTTE ELAND DEMORES ASH COULEE WHISKEY JOE GAS CITY DAVIS ...

  10. Carter Co. Harding Co. Perkins Co. Dunn Co. Dawson Co. Fallon...

    U.S. Energy Information Administration (EIA) Indexed Site

    MEDICINE POLE HILLS BICENTENNIAL ROOSEVELT BIG STICK ROUGH RIDER MONARCH TREE TOP LOOKOUT BUTTE BUCKHORN MEDORA FLAT TOP BUTTE ELAND DEMORES ASH COULEE WHISKEY JOE GAS CITY DAVIS ...

  11. Non-Destructive X-ray Measurement of Soot, Ash, Washcoat and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    X-ray Measurement of Soot, Ash, Washcoat and Regeneration Damage for DPFs Non-Destructive X-ray Measurement of Soot, Ash, Washcoat and Regeneration Damage for DPFs New commercially ...

  12. Geotechnical properties of fly and bottom ash mixtures for use in highway embankments

    SciTech Connect (OSTI)

    Kim, B.; Prezzi, M.; Salgado, R.

    2005-07-01

    Class F fly ash and bottom ash are the solid residue byproducts produced by coal-burning electric utilities. They are usually disposed of together as a waste in utility disposal sites with a typical disposal rate of 80% fly ash and 20% bottom ash. Direct use of these materials in construction projects consuming large volumes of materials, such as highway embankment construction, not only provides a promising solution to the disposal problem, but also an economic alternative to the use of traditional materials. Representative samples of class F fly and bottom ash were collected from two utility power plants in Indiana and tested for their mechanical properties (compaction, permeability, strength, stiffness, and compressibility). Three mixtures of fly and bottom ash with different mixture ratios (i.e., 50, 75, and 100% fly ash content by weight) were prepared for testing. Test results indicated that ash mixtures compare favorably with conventional granular materials.

  13. Structure of the SPRY domain of human Ash2L and its interactions...

    Office of Scientific and Technical Information (OSTI)

    Structure of the SPRY domain of human Ash2L and its interactions with RbBP5 and DPY30 Citation Details In-Document Search Title: Structure of the SPRY domain of human Ash2L and its ...

  14. Ashe County, North Carolina ASHRAE 169-2006 Climate Zone | Open...

    Open Energy Info (EERE)

    Ashe County, North Carolina ASHRAE 169-2006 Climate Zone Jump to: navigation, search County Climate Zone Place Ashe County, North Carolina ASHRAE Standard ASHRAE 169-2006 Climate...

  15. Ash reduction system using electrically heated particulate matter filter

    DOE Patents [OSTI]

    Gonze, Eugene V [Pinckney, MI; Paratore, Jr., Michael J; He, Yongsheng [Sterling Heights, MI

    2011-08-16

    A control system for reducing ash comprises a temperature estimator module that estimates a temperature of an electrically heated particulate matter (PM) filter. A temperature and position estimator module estimates a position and temperature of an oxidation wave within the electrically heated PM filter. An ash reduction control module adjusts at least one of exhaust flow, fuel and oxygen levels in the electrically heated PM filter to adjust a position of the oxidation wave within the electrically heated PM filter based on the oxidation wave temperature and position.

  16. Continuous air agglomeration method for high carbon fly ash beneficiation

    DOE Patents [OSTI]

    Gray, McMahon L.; Champagne, Kenneth J.; Finseth, Dennis H.

    2000-01-01

    The carbon and mineral components of fly ash are effectively separated by a continuous air agglomeration method, resulting in a substantially carboree mineral stream and a highly concentrated carbon product. The method involves mixing the fly ash comprised of carbon and inorganic mineral matter with a liquid hydrocarbon to form a slurry, contacting the slurry with an aqueous solution, dispersing the hydrocarbon slurry into small droplets within the aqueous solution by mechanical mixing and/or aeration, concentrating the inorganic mineral matter in the aqueous solution, agglomerating the carbon and hydrocarbon in the form of droplets, collecting the droplets, separating the hydrocarbon from the concentrated carbon product, and recycling the hydrocarbon.

  17. The Sensitivity of DPF Performance to the Spatial Distribution of Ash Generated from Six Lubricant Formulations

    Broader source: Energy.gov [DOE]

    Discusses potential of DPF pressure drop reduction by optimizing the spatial distribution of ash inside DPF inlet channel

  18. Comparison of leaching characteristics of heavy metals from bottom and fly ashes in Korea and Japan

    SciTech Connect (OSTI)

    Shim, Young-Sook; Rhee, Seung-Whee; Lee, Woo-Keun . E-mail: woklee@kangwon.ac.kr

    2005-07-01

    The objective of this research was to compare the leaching characteristics of heavy metals such as cadmium, chromium, copper, nickel, lead, etc., in Korean and Japanese municipal solid waste incineration (MSWI) ash. The rate of leaching of heavy metal was measured by KSLT and JTL-13, and the amount of heavy metals leached was compared with the metal content in each waste component. Finally, bio-availability testing was performed to assess the risks associated with heavy metals leached from bottom ash and fly ash. From the results, the value of neutralization ability in Japanese fly ash was four times higher than that in Korean fly ash. The reason was the difference in the content of Ca(OH){sub 2} in fly ash. The amount of lead leached exceeded the regulatory level in both Japanese and Korean fly ash. The rate of leaching was relatively low in ash with a pH in the range of 6-10. The bio-availability test in fly ash demonstrated that the amount of heavy metals leached was Pb > Cd > Cr, but the order was changed to Pb > Cr > Cd in the bottom ash. The leaching concentration of lead exceeded the Japanese risk level in all fly ashes from the two countries, but the leaching concentration of cadmium exceeded the regulatory level in Korean fly ash only.

  19. Hydration and strength development of binder based on high-calcium oil shale fly ash

    SciTech Connect (OSTI)

    Freidin, C. [Ben-Gurion Univ. of the Negev, Sede-Boqer (Israel)] [Ben-Gurion Univ. of the Negev, Sede-Boqer (Israel)

    1998-06-01

    The properties of high-calcium oil shale fly ash and low-calcium coal fly ash, which are produced in Israeli power stations, were investigated. High-calcium oil shale fly ash was found to contain a great amount of CaO{sub free} and SO{sub 3} in the form of lime and anhydrite. Mixtures of high-calcium oil shale fly ash and low-calcium coal fly ash, termed fly ash binder, were shown to cure and have improved strength. The influence of the composition and curing conditions on the compressive strength of fly ash binders was examined. The microstructure and the composition of fly ash binder after curing and long-term exposure in moist air, water and open air conditions were studied. It was determined that ettringite is the main variable in the strength and durability of cured systems. The positive effect of calcium silicate hydrates, CSH, which are formed by interaction of high-calcium oil shale fly ash and low-calcium coal fly ash components, on the carbonation and dehydration resistance of fly ash binder in open air is pronounced. It was concluded that high-calcium oil shale fly ash with high CaO{sub free} and SO{sub 3} content can be used as a binder for building products.

  20. Sandia Energy - White House Business Council Roundtable on Water

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Protected: White House Business Council Roundtable on Water Home Climate Water Security Protected: White House Business Council Roundtable on Water Previous Next Protected: White...

  1. Report 23: Photometric Testing of White Tunable LED Luminaires...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Report 23: Photometric Testing of White Tunable LED Luminaires Report 23: Photometric Testing of White Tunable LED Luminaires PDF icon caliper23white-tunable-led-luminaires.pdf ...

  2. Report 23: Photometric Testing of White Tunable LED Luminaires...

    Energy Savers [EERE]

    3: Photometric Testing of White Tunable LED Luminaires Report 23: Photometric Testing of White Tunable LED Luminaires PDF icon caliper23white-tunable-led-luminaires.pdf More ...

  3. Distribution of polycyclic aromatic hydrocarbons in lime spray dryer ash

    SciTech Connect (OSTI)

    Ping Sun; Panuwat Taerakul; Linda K. Weavers; Harold W. Walker

    2005-10-01

    Four lime spray dryer (LSD) ash samples were collected from a spreader stoker boiler and measured for their concentrations of 16 U.S. EPA specified polycyclic aromatic hydrocarbons (PAHs). Results showed that the total measured PAH concentration correlated with the organic carbon content of the LSD ash. Each LSD ash sample was then separated using a 140 mesh sieve into two fractions: a carbon-enriched fraction ({gt}140 mesh) and a lime-enriched fraction ({lt}140 mesh). Unburned carbon was further separated from the carbon-enriched fraction with a lithiumheteropolytungstate (LST) solution. PAH measurements on these different fractions showed that unburned carbon had the highest PAH concentrations followed by the carbon-enriched fraction, indicating that PAHs were primarily associated with the carbonaceous material in LSD ash. However, detectable levels of PAHs were also found in the lime-enriched fraction, suggesting that the fine spray of slaked lime may sorb PAH compounds from the flue gas in the LSD process. 37 refs., 5 figs., 4 tabs.

  4. White Sturgeon Bibliography, 1985 Final Report.

    SciTech Connect (OSTI)

    Fickeisen, Duane H.

    1986-03-01

    This bibliography presents citations to the majority of published materials on white sturgeon (Acipenser transmontanus). The purpose was to assist in planning and implementing research on white sturgeon in the Columbia River system. (ACR)

  5. Joe Mescan Windmill LLC | Open Energy Information

    Open Energy Info (EERE)

    Station, Ohio Zip: 44028 Sector: Wind energy Product: Agriculture; Installation; Maintenance and repair;Manufacturing; Retail product sales and distribution Phone Number:...

  6. Women @ Energy: Cindy Joe | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Women @ Energy: Christina Swinson Christina Swinson is a post doc. in Accelerator Physics at Brookhaven National Lab. She has a BSc. In Physics with Computing, Queen Mary College, University of London, United Kingdom, and a DPhil. (PhD.) in Accelerator Physics from the University of Oxford, United Kingtom. 1) What inspired you to work in STEM? My decision to work in STEM didn't come until I was in my twenties but the journey first began in high school. Unfortunately at the time I wasn't

  7. White Papers | OpenEI Community

    Open Energy Info (EERE)

    Alaska analysis appropriations Categorical Exclusions Coordinating Permit Office Cost Mechanisms Cost Recovery geothermal Hawaii NEPA permitting quarterly meeting White...

  8. Women @ Energy: Karen White | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Karen White Women @ Energy: Karen White August 28, 2015 - 10:51am Addthis Karen S. White is controls group leader and data operations manager at the Spallation Neutron Source at Oak Ridge National Laboratory. She attended Old Dominion University, where she earned a bachelor's degree in computer engineering and master's degree in computer science, and George Washington University, where she earned an M.E. in engineering management. Karen S. White is controls group leader and data operations

  9. Soil stabilization and pavement recycling with self-cementing coal fly ash

    SciTech Connect (OSTI)

    2008-01-15

    This manual provides design information for self-cementing coal fly ash as the sole stabilizing agent for a wide range of engineering applications. As in any process, the application of sound engineering practices, appropriate testing, and evaluation of fly ash quality and characteristics will lend themselves to successful projects using the guidelines in this manual. Topics discussed include: self-cementing coal fly ash characteristics; laboratory mix design; stabilization of clay soils; stabilisation of granular materials; construction considerations; high sulfate ash; environmental considerations for fly ash stabilization; design considerations; state specification/guidelines/standards; and a sample of a typical stabilization specification.

  10. Mechanical characterization of filler sandcretes with rice husk ash additions. Study applied to Senegal

    SciTech Connect (OSTI)

    Cisse, I.K.; Laquerbe, M.

    2000-01-01

    To capitalize on the local materials of Senegal (agricultural and industrial wastes, residual fines from crushing process, sands from dunes, etc.), rise husk ash and residues of industrial and agricultural wastes have been used as additions in sandcretes. The mechanical resistance of sandcrete blocks obtained when unground ash (and notably the ground ash) is added reveals that there is an increase in performance over the classic mortar blocks. In addition, the use of unground rice husk ash enables production of a lightweight sandcrete with insulating properties, at a reduced cost. The ash pozzolanic reactivity explains the high strengths obtained.

  11. White House Forum on Minorites in Energy

    Office of Energy Efficiency and Renewable Energy (EERE)

    On November 13, 2013, the Department of Energy and the White House Office of Science and Technology Policy, the Council for Environmental Quality, and the White House Office of Public Engagement co-hosted the White House Forum on Minorities in Energy. The event included the announcement of the Ambassadors for the Minorities in Energy Initiative.

  12. THE WHITE HOUSE | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    THE WHITE HOUSE THE WHITE HOUSE THE WHITE HOUSE (66.14 KB) More Documents & Publications FACT SHEET: U.S.-China Clean Energy Cooperation Announcements US-China Clean Energy Cooperation Progress Report on U.S.-China Energy Cooperation

  13. Automated system for removal and pneumatic transport of fly ash from electric precipitator hoppers

    SciTech Connect (OSTI)

    V.K. Konovalov; O.V. Yashkin; V.V. Ermakov

    2008-03-15

    A system for removal and pneumatic transport of fly ash is examined, in which air pulses act on batches (pistons) of ash formed in a duct. Studies are made of the effect of several physical parameters on the force required to displace a piston of ash and these serve as a basis for choosing a system for removal and pneumatic transport of ash simultaneously from several hoppers of an electric precipitator. This makes it possible to separate the ash particles according to size without introducing additional components. Formulas are given for calculating the structural and dynamic parameters of this system and measurements of indirect dynamic parameters are used to calculate the input-output characteristics of the system. In order to optimize the system, configurations for summing several ducts into a single transport duct for pneumatic ash transport are proposed. Some variants of dry ash utilization and the advantages of producing of size-separated particles are considered.

  14. Regeneratively cooled coal combustor/gasifier with integral dry ash removal

    DOE Patents [OSTI]

    Beaufrere, A.H.

    1982-04-30

    A coal combustor/gasifier is disclosed which produces a low or medium combustion gas fired furnances or boilers. Two concentric shells define a combustion air flows to provide regenerative cooling of the inner shell for dry ash operation. A fuel flow and a combustion air flow having opposed swirls are mixed and burned in a mixing-combustion portion of the combustion volume and the ash laden combustion products flow with a residual swirl into an ash separation region. The ash is cooled below the fusion temperature and is moved to the wall by centrifugal force where it is entrained in the cool wall boundary layer. The boundary layer is stabilized against ash re-entrainment as it is moved to an ash removal annulus by a flow of air from the plenum through slots in the inner shell, and by suction on an ash removal skimmer slot.

  15. Method for increasing the rate of compressive strength gain in hardenable mixtures containing fly ash

    DOE Patents [OSTI]

    Liskowitz, John W.; Wecharatana, Methi; Jaturapitakkul, Chai; Cerkanowicz, deceased, Anthony E.

    1997-01-01

    The present invention relates to concrete, mortar and other hardenable mixtures comprising cement and fly ash for use in construction. The invention provides a method for increasing the rate of strength gain of a hardenable mixture containing fly ash by exposing the fly ash to an aqueous slurry of calcium oxide (lime) prior to its incorporation into the hardenable mixture. The invention further relates to such hardenable mixtures, e.g., concrete and mortar, that contain fly ash pre-reacted with calcium oxide. In particular, the fly ash is added to a slurry of calcium oxide in water, prior to incorporating the fly ash in a hardenable mixture. The hardenable mixture may be concrete or mortar. In a specific embodiment, mortar containing fly ash treated by exposure to an aqueous lime slurry are prepared and tested for compressive strength at early time points.

  16. Method for increasing the rate of compressive strength gain in hardenable mixtures containing fly ash

    DOE Patents [OSTI]

    Liskowitz, J.W.; Wecharatana, M.; Jaturapitakkul, C.; Cerkanowicz, A.E.

    1997-10-28

    The present invention relates to concrete, mortar and other hardenable mixtures comprising cement and fly ash for use in construction. The invention provides a method for increasing the rate of strength gain of a hardenable mixture containing fly ash by exposing the fly ash to an aqueous slurry of calcium oxide (lime) prior to its incorporation into the hardenable mixture. The invention further relates to such hardenable mixtures, e.g., concrete and mortar, that contain fly ash pre-reacted with calcium oxide. In particular, the fly ash is added to a slurry of calcium oxide in water, prior to incorporating the fly ash in a hardenable mixture. The hardenable mixture may be concrete or mortar. In a specific embodiment, mortar containing fly ash treated by exposure to an aqueous lime slurry are prepared and tested for compressive strength at early time points. 2 figs.

  17. Leaching of mixtures of biochar and fly ash

    SciTech Connect (OSTI)

    Palumbo, Anthony V.; Porat, Iris; Phillips, Jana R.; Amonette, James E.; Drake, Meghan M.; Brown, Steven D.; Schadt, Christopher W.

    2009-06-22

    Increasing atmospheric levels of greenhouse gases, especially CO2, and their effects on global temperature have led to interest in the possibility of carbon storage in terrestrial environments. Both the residual char from biomass pyrolysis (biochar) and fly ash from coal combustion have the potential to significantly expand terrestrial sequestration options. Both biochar and fly ash also have potentially beneficial effects on soil properties. Fly ash has been shown to increase porosity, water-holding capacity, pH, conductivity, and dissolved SO42-, CO32-, Cl- and basic cations. Adding biochar to soil generally raises pH, increases total nitrogen and total phosphorous, encourages greater root development, improves cation exchange capacity and decreases available aluminum. A combination of these benefits likely is responsible for observed increases in yields for crops such as corn and sugarcane. In addition, it has been found that soils with added biochar emit lower amounts of other greenhouse gases (methane and nitrous oxide) than do unamended soils. Biochar and fly ash amendments may be useful in promoting terrestrial carbon sequestration on currently underutilized and degraded lands. For example, about 1% of the US surface lands consist of previously mined lands or highway rights-of-way. Poorly managed lands could count for another 15% of US area. Biochar and fly ash amendments could increase productivity of these lands and increase carbon storage in the soil. Previous results showed minimal leaching of organic carbon and metals from a variety of fly ashes. In the present study, we examined the properties of mixtures of biochar, fly ash, and soil and evaluated the leaching of organic carbon and metals from these mixtures. The carbon sorption experiments showed release of carbon from biochar, rather than sorption, except at the highest concentrations in the Biochar HW sample. Similar results were obtained by others for oxidative leaching of bituminous coal, in

  18. Brick manufacture with fly ash from Illinois coals. Technical report, March 1, 1995--May 31, 1995

    SciTech Connect (OSTI)

    Hughes, R.E.; Dreher, G.; Moore, D.; Rostam-Abadi, M.; Fiocchi, T.; Swartz, D.

    1995-12-31

    This investigation seeks to utilize fly ash in fired-clay products such as building and patio bricks, ceramic blocks, field and sewer tile, and flower pots. This goal is accomplished by 1) one or more plant-scale, 5000-brick tests of fly ash mixed with brick clays at the 20% or higher level; 2) a laboratory-scale study to measure the firing reactions of a range of compositions of clay and fly ash mixtures; 3) a preliminary study to evaluate the potential environmental and economic benefits of brick manufacture with fly ash. Bricks and feed materials will be tested for compliance with market specifications and for leachability of pollutants derived from fly ash. The laboratory study will combine ISGS databases, ICCI-supported characterization methods, and published information to improve predictions of the firing characteristics of Illinois fly ash and brick clay mixtures. Because identical methods are used to test clay firing and coal ash fusion, and because melting mechanisms are the same, improved coal ash fusion predictions are and additional expected result of this research. During this quarter we completed a manufacturing run at Colonial Brick Co. and began laboratory testing of samples from that run: clays, fly ash (from Illinois Power Company`s Wood River plant), and green and fired bricks, with and without fly ash. Bricks with 20% fly ash ``scummed`` during firing, and the fly ash failed to increase oxidation rate or water absorption, which were both expected. We obtained chemical and mineralogical analyses of the fireclays and shales at Colonial and Marseilles Brick Companies and began a series of selective dissolution analyses to more accurately determine the composition of the principal clay minerals in brick clays and the components in fly ash. We began related work of calculating normative mineralogical analyses for all clays and fly ashes that we sample.

  19. Determination of slagging behavior of various coal ash samples by using DTF

    SciTech Connect (OSTI)

    Kim, H.T.; Choi, B.C.; Park, S.W.

    1999-07-01

    The objective of this study is to investigate slagging behavior of various ash samples with the conjunction to the properties of ashes and original coal such as concentration of each ash components, ash slagging temperature and slag viscosity. To simulate actual ash melting condition in coal combustion as well as gasification, DTF (drop tube furnace) is utilized for the acquisition of slag sample with different reaction condition. The sampled slag is photographed for the visual inspection and the shape of the slag is evaluated with ash properties. The sampled ash slag is also analyzed with XRD for the determination of phase transition during the ash melting. Furthermore, coal ashes are processed with Ash Fusion Determinator for the fusion temperature and High-Temperature Viscometer for the slag viscosity. Such ash-related properties are also determined by empirical formulation for the refinement of the result. So far, three different coal samples, Alaska, Datong, Cyprus are investigated. For the 3 ash samples, slag formation shows similar shape in combustion as well as gasification condition and completely different shape with different coal types. Alaska slag, which represents higher fluidity, is penetrated into alumina disk so that small half-cone shape of slag is produced. However, Cyprus slag is formed with more circular shape of sphere and Datong slag represents an in-between shape. More coal samples will be studied for the determination of slag behavior. The shape data will be analyzed with ash composition, fluidity behavior and ash fusion determination of original coal. Such relationship will be the baseline to determine the operation parameter of slag removal in the 3 ton/day coal gasifier located in the Ajou University, Suwon, Korea.

  20. Fly Ash and Mercury Oxidation/Chlorination Reactions

    SciTech Connect (OSTI)

    Sukh Sidhu; Patanjali Varanasi

    2008-12-31

    Mercury is a known pollutant that has detrimental effect on human health and environment. The anthropogenic emissions of mercury account for 10 to 30% of worldwide mercury emissions. There is a need to control/reduce anthropogenic mercury emissions. Many mercury control technologies are available but their effectiveness is dependent on the chemical form of mercury, because different chemical forms of mercury have different physical and chemical properties. Mercury leaves the boiler in its elemental form but goes through various transformations in the post-combustion zone. There is a need to understand how fly ash and flue gas composition affect speciation, partitioning, and reactions of mercury under the full range of post-combustion zone conditions. This knowledge can then be used to predict the chemical transformation of mercury (elemental, oxidized or particulate) in the post combustion zone and thus help with the control of mercury emissions from coal-burning power plants. To accomplish this goal present study was conducted using five coal fly ashes. These ashes were characterized and their catalytic activity was compared under selected reaction conditions in a fixed bed reactor. Based on the results from these fly ash experiments, three key components (carbon, iron oxide and calcium oxide) were chosen. These three components were then used to prepare model fly ashes. Silica/alumina was used as a base for these model fly ashes. One, two or three component model fly ashes were then prepared to investigate mercury transformation reactions. The third set of experiments was performed with CuO and CuCl2 catalysts to further understand the mercury oxidation process. Based on the results of these three studies the key components were predicted for different fly ash compositions under variety of flue gas conditions. A fixed bed reactor system was used to conduct this study. In all the experiments, the inlet concentration of Hg0(g) was maintained at 35 {micro}g/m3 using

  1. Ash reduction in clean coal spiral product circuits

    SciTech Connect (OSTI)

    Brodzik, P.

    2007-04-15

    The article describes the Derrick Corporation's Stack Sizer{trademark} technology for high capacity fine wet cleaning with long-lasting high open-area urethane screen panels. After field trials, a Stack Sizer fitted with a 100-micron urethane panel is currently processing approximately 40 stph of clean coal spiral product having about 20% ash at McCoy-Elkhorn's Bevin Branch coal preparation plant in Kentucky, USA. Product yield is about 32.5 short tons per hour with 10% ash. The material is then fed to screen bowl centrifuges for further processing. At Blue Diamond Coal's Leatherwood preparation plant similar Stacker Sizers are achieving the same results. 2 figs., 3 tabs., 2 photo.

  2. Utilization of ash from municipal solid waste combustion. Final report, Phase I

    SciTech Connect (OSTI)

    Jones, C.M.; Hartman, R.M.; Kort, D.; Rapues, N.

    1994-09-01

    This ash study investigates several aspects of Municipal Waste Combustion (MWC) ash utilization to develop an alternative to the present disposal practice of landfilling in a lined monofill. Ash was investigated as a daily or final cover for municipal waste in the landfill to prevent erosion and as a road construction aggregate. Samples of eight mixtures of ash and other materials, and one sample of soil were analyzed for chemical constituents. Biological tests on these mixters were conducted, along with erosion tests and sieve analyses. A chemical analysis of each sieve size was conducted. Geotechnical properties of the most promising materials were made. Findings to this point include: all ash samples take have passed the EPA TCLP testing; chemical analysis of bottom and combined ash samples indicate less than expected variability; selected ash mixtures exhibited very low coefficients of hydraulic conductivity; all but one of the ash mixtures exhibited greater erosion resistance than the currently used landfill cover material; MWC combined analysis indicates this is a viable alternative for landfill cover; MWC ash size reactions and chemical analysis show bottom and combined ash to be a viable alternative for road construction.

  3. Effects of pulverized coal fly-ash addition as a wet-end filler in papermaking

    SciTech Connect (OSTI)

    Sinha, A.S.K.

    2008-09-15

    This experimental study is based on the innovative idea of using pulverized coal fly ash as a wet-end filler in papermaking. This is the first evaluation of the possible use of fly ash in the paper industry. Coal-based thermal power plants throughout the world are generating fly ash as a solid waste product. The constituents of fly ash can be used effectively in papermaking. Fly ash has a wide variation in particle size, which ranges from a few micrometers to one hundred micrometers. Fly ash acts as an inert material in acidic, neutral, and alkaline papermaking processes. Its physical properties such as bulk density (800-980 kg/m{sup 3}), porosity (45%-57%), and surface area (0.138-2.3076 m{sup 2}/g) make it suitable for use as a paper filler. Fly ash obtained from thermal power plants using pulverized coal was fractionated by a vibratory-sieve stack. The fine fraction with a particle size below 38 micrometers was used to study its effect on the important mechanical-strength and optical properties of paper. The effects of fly-ash addition on these properties were compared with those of kaolin clay. Paper opacity was found to be much higher with fly ash as a filler, whereas brightness decreased as the filler percentage increased Mechanical strength properties of the paper samples with fly ash as filler were superior to those with kaolin clay.

  4. Construction of an embankment with a fly and bottom ash mixture: field performance study

    SciTech Connect (OSTI)

    Yoon, S.; Balunaini, U.; Yildirim, I.Z.; Prezzi, M.; Siddiki, N.Z.

    2009-06-15

    Fly ash and bottom ash are coal combustion by-products (CCBPs) that are generated in large quantities throughout the world. It is often economical to dispose ash as mixtures rather than separately; that notwithstanding, only a few studies have been performed to investigate the behavior of fly and bottom ash mixtures, particularly those with high contents of fly ash. Also, there is very limited data available in the literature on the field performance of structures constructed using ash mixtures. This paper describes the construction and the instrumentation of a demonstration embankment built with an ash mixture (60:40 by weight of fly ash:bottom ash) on State Road 641, Terre Haute, Ind. Monitoring of the demonstration embankment was conducted for a period of 1 year from the start of construction of the embankment. The settlement of the embankment stabilized approximately 5 months after the end of its construction. According to horizontal inclinometer readings, the differential settlement at the top of the embankment is about 5 mm. Results from field quality control tests performed during construction of the demonstration embankment and monitoring data from vertical and horizontal inclinometers and settlement plates indicate that the ash mixture investigated can be considered an acceptable embankment construction material.

  5. Differences in gasification behaviors and related properties between entrained gasifier fly ash and coal char

    SciTech Connect (OSTI)

    Jing Gu; Shiyong Wu; Youqing Wu; Ye Li; Jinsheng Gao

    2008-11-15

    In the study, two fly ash samples from Texaco gasifiers were compared to coal char and the physical and chemical properties and reactivity of samples were investigated by scanning electron microscopy (SEM), SEM-energy-dispersive spectrometry (EDS), X-ray diffraction (XRD), N{sub 2} and CO{sub 2} adsorption method, and isothermal thermogravimetric analysis. The main results were obtained. The carbon content of gasified fly ashes exhibited 31-37%, which was less than the carbon content of 58-59% in the feed coal. The fly ashes exhibited higher Brunauer-Emmett-Teller (BET) surface area, richer meso- and micropores, more disordered carbon crystalline structure, and better CO{sub 2} gasification reactivity than coal char. Ashes in fly ashes occurred to agglomerate into larger spherical grains, while those in coal char do not agglomerate. The minerals in fly ashes, especial alkali and alkaline-earth metals, had a catalytic effect on gasification reactivity of fly ash carbon. In the low-temperature range, the gasification process of fly ashes is mainly in chemical control, while in the high-temperature range, it is mainly in gas diffusion control, which was similar to coal char. In addition, the carbon in fly ashes was partially gasified and activated by water vapor and exhibited higher BET surface area and better gasification activity. Consequently, the fact that these carbons in fly ashes from entrained flow gasifiers are reclaimed and reused will be considered to be feasible. 15 refs., 7 figs., 5 tabs.

  6. Idaho Nuclear Technology and Engineering Center (INTEC) (formerly ICPP) ash reutilization study

    SciTech Connect (OSTI)

    Langenwalter, T.; Pettet, M.; Ochoa, R.; Jensen, S.

    1998-05-01

    Since 1984, the coal-fired plant at the Idaho Nuclear Technology and Engineering Center (INTEC, formerly Idaho Chemical Processing Plant) has been generating fly ash at a rate of approximately 1,000 tons per year. This ash is hydrated and placed in an ash bury pit near the coal-fired plant. The existing ash bury pit will be full in less than 1 year at its present rate of use. A conceptual design to build a new ash bury pit was completed, and the new pit is estimated to cost $1.7 million. This report evaluates ash reutilization alternatives that propose to eliminate this waste stream and save the $1.7 million required to build a new pit. The alternatives include using ash for landfill day cover, concrete admixture, flowable fill, soil stabilization, waste remediation, and carbon recovery technology. Both physical and chemical testing, under the guidance of the American Society for Testing and Materials, have been performed on ash from the existing pit and from different steps within the facility`s processes. The test results have been evaluated, compared to commercial ash, and are discussed as they relate to reutilization alternatives. This study recommends that the ash be used in flowable fill concrete for Deactivation and Demolition work at the Idaho National Engineering and Environmental Laboratory.

  7. Leaching characteristics of arsenic and selenium from coal fly ash: role of calcium

    SciTech Connect (OSTI)

    Tian Wang; Jianmin Wang; Yulin Tang; Honglan Shi; Ken Ladwig

    2009-05-15

    Understanding the leaching behavior of arsenic (As) and selenium (Se) in coal fly ash is important in evaluating the potential environmental impact of coal fly ash. Batch experiments were employed to systematically investigate the leaching behavior of As and Se in two major types of coal fly ashes, bituminous coal ash and sub-bituminous coal ash, and to determine the underlying processes that control As and Se leaching. The effects of pH, solid/liquid (S/L) ratio, calcium addition, and leaching time on the release of As and Se were studied. Overall, bituminous coal ash leached significantly more As and Se than sub-bituminous coal ash, and Se was more readily leachable, in both absolute concentration and relative fraction, than As for both types of fly ashes. Adsorption/desorption played a major role on As and Se leaching from bituminous coal ashes. However, calcium precipitation played the most important role in reducing As and Se leaching from sub-bituminous coal ashes in the entire experimental pH range. The leaching of As and Se from bituminous coal ashes generally increased with increases in the S/L ratio and leaching time. However, for sub-bituminous coal ashes, the leaching of As was not detected under most experimental conditions, while the leaching of Se increased with increases in the S/L ratio and leaching time. As{sup V} and Se{sup IV} were found to be the major species in all ash leachates in this study. 46 refs., 7 figs., 1 tab.

  8. Oil shale ash-layer thickness and char combustion kinetics

    SciTech Connect (OSTI)

    Aldis, D.F.; Singleton, M.F.; Watkins, B.E.; Thorsness, C.B.; Cena, R.J.

    1992-04-15

    A Hot-Recycled-Solids (HRS) oil shale retort is being studied at Lawrence Livermore National Laboratory. In the HRS process, raw shale is heated by mixing it with burnt retorted shale. Retorted shale is oil shale which has been heated in an oxygen deficient atmosphere to pyrolyze organic carbon, as kerogen into oil, gas, and a nonvolatile carbon rich residue, char. In the HRS retort process, the char in the spent shale is subsequently exposed to an oxygen environment. Some of the char, starting on the outer surface of the shale particle, is burned, liberating heat. In the HRS retort, the endothermic pyrolysis step is supported by heat from the exothermic char combustion step. The rate of char combustion is controlled by three resistances; the resistance of oxygen mass transfer through the gas film surrounding the solid particle, resistance to mass transfer through a ash layer which forms on the outside of the solid particles as the char is oxidized and the resistance due to the intrinsic chemical reaction rate of char and oxygen. In order to estimate the rate of combustion of the char in a typical oil shale particle, each of these resistances must be accurately estimated. We begin by modeling the influence of ash layer thickness on the over all combustion rate of oil shale char. We then present our experimental measurements of the ash layer thickness of oil shale which has been processed in the HRS retort.

  9. The initiation and propagation of helium detonations in white dwarf envelopes

    SciTech Connect (OSTI)

    Shen, Ken J. [Department of Astronomy and Theoretical Astrophysics Center, University of California, Berkeley, CA 94720 (United States); Moore, Kevin, E-mail: kenshen@astro.berkeley.edu [Department of Applied Mathematics and Statistics, University of California, Santa Cruz, CA 95064 (United States)

    2014-12-10

    Detonations in helium-rich envelopes surrounding white dwarfs have garnered attention as triggers of faint thermonuclear '.Ia' supernovae and double detonation Type Ia supernovae. However, recent studies have found that the minimum size of a hotspot that can lead to a helium detonation is comparable to, or even larger than, the white dwarf's pressure scale height, casting doubt on the successful ignition of helium detonations in these systems. In this paper, we examine the previously neglected effects of C/O pollution and a full nuclear reaction network, and we consider hotspots with spatially constant pressure in addition to constant density hotspots. We find that the inclusion of these effects significantly decreases the minimum hotspot size for helium-rich detonation ignition, making detonations far more plausible during turbulent shell convection or during double white dwarf mergers. The increase in burning rate also decreases the minimum shell mass in which a helium detonation can successfully propagate and alters the composition of the shell's burning products. The ashes of these low-mass shells consist primarily of silicon, calcium, and unburned helium and metals and may explain the high-velocity spectral features observed in most Type Ia supernovae.

  10. Effects of Sediment Containing Coal Ash from the Kingston Ash Release on Embryo-Larval Development in the Fathead Minnow, Pimephales promelas (Rafinesque, 1820)

    SciTech Connect (OSTI)

    Greeley Jr, Mark Stephen; Elmore, Logan R; McCracken, Kitty; Sherrard, Rick

    2014-01-01

    The largest environmental release of coal ash in U.S. history occurred in December 2008 with the failure of a retention structure at the Tennessee Valley Authority (TVA) Kingston Fossil Plant in East Tennessee. A byproduct of coal-burning power plants, coal ash is enriched in metals and metalloids such as selenium and arsenic with known toxicity to fish including embryonic and larval stages. The effects of contact exposure to sediments containing up to 78 % coal ash from the Kingston spill on the early development of fish embryos and larvae were examined in 7-day laboratory tests with the fathead minnow (Pimephales promelas). No significant effects were observed on hatching success, incidences of gross developmental abnormalities, or embryo-larval survival. Results suggest that direct exposures to sediment containing residual coal ash from the Kingston ash release may not present significant risks to fish eggs and larvae in waterways affected by the spill.

  11. Relationship between textural properties, fly ash carbons, and Hg capture in fly ashes derived from the combustion of anthracitic pulverized feed blends

    SciTech Connect (OSTI)

    Isabel Surez-Ruiz; Jose B. Parra

    2007-08-15

    In this work, the textural properties of a series of whole anthracitic-derived fly ashes sampled in eight hoppers from the electrostatic precipitators and their sized fractions (from {gt}150 to {lt}25 {mu}m) are investigated. Data from N{sub 2} adsorption isotherms at 77 K, helium density, and mercury porosimetry have contributed to establish a relationship between the Brunauer-Emmett-Teller (BET) surface areas, VTOT, porosity, carbon content (the type of fly ash carbons), and Hg retention in these fly ashes. The unburned carbons in these ashes are macroporous materials, and they are different from the carbons in fly ashes from classes C and F (the latter derived from the combustion of bituminous coals) and show different textural properties. These ashes represent the end member of the fly ash classes C and F with respect to certain textural properties. Although the BET surface area and VTOT values for the studied samples are the lowest reported, they increase with the increase in carbon content, anisotropic carbon content, and particle size of the ashes. Thus, a positive relationship between all these parameters and Hg capture by the coarser ash fractions was found. The finest fraction of carbons ({lt}25 {mu}m) represented an exception. Although it makes a significant contribution to the total carbon of the whole fly ashes and shows relatively higher surface areas and VTOT values, its Hg concentration was found to be the lowest. This suggests that the type of unburned carbons in the finest fraction and/or other adsorption mechanisms may play a role in Hg concentration. Because the textural properties of anisotropic carbons depend on their subtype and on their origin, the need for its differentiation has been evidenced. 54 refs., 8 figs., 3 tabs.

  12. Comparative performance of geopolymers made with metakaolin and fly ash after exposure to elevated temperatures

    SciTech Connect (OSTI)

    Kong, Daniel L.Y.; Sanjayan, Jay G. Sagoe-Crentsil, Kwesi

    2007-12-15

    This paper presents the results of a study on the effect of elevated temperatures on geopolymers manufactured using metakaolin and fly ash of various mixture proportions. Both types of geopolymers (metakaolin and fly ash) were synthesized with sodium silicate and potassium hydroxide solutions. The strength of the fly ash-based geopolymer increased after exposure to elevated temperatures (800 deg. C). However, the strength of the corresponding metakaolin-based geopolymer decreased after similar exposure. Both types of geopolymers were subjected to thermogravimetric, scanning electron microscopy and mercury intrusion porosimetry tests. The paper concludes that the fly ash-based geopolymers have large numbers of small pores which facilitate the escape of moisture when heated, thus causing minimal damage to the geopolymer matrix. On the other hand, metakaolin geopolymers do not possess such pore distribution structures. The strength increase in fly ash geopolymers is also partly attributed to the sintering reactions of un-reacted fly ash particles.

  13. Integrated production/use of ultra low-ash coal, premium liquids and clean char

    SciTech Connect (OSTI)

    Kruse, C.W.

    1991-01-01

    This integrated, multi-product approach for utilizing Illinois coal starts with the production of ultra low-ash coal and then converts it to high-vale, coal-derived, products. The ultra low-ash coal is produced by solubilizing coal in a phenolic solvent under ChemCoal{trademark} process conditions, separating the coal solution from insoluble ash, and then precipitating the clean coal by dilution of the solvent with methanol. Two major products, liquids and low-ash char, are then produced by mild gasification of the low-ash coal. The low ash-char is further upgraded to activated char, and/or an oxidized activated char which has catalytic properties. Characterization of products at each stage is part of this project.

  14. Ash reduction strategies in corn stover facilitated by anatomical and size fractionation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lacey, Jeffrey A.; Emerson, Rachel M.; Thompson, David N.; Westover, Tyler L.

    2016-04-22

    There is growing interest internationally to produce fuels from renewable biomass resources. Inorganic components of biomass feedstocks, referred to collectively as ash, damage equipment and decrease yields in thermal conversion processes, and decrease feedstock value for biochemical conversion processes. Decreasing the ash content of feedstocks improves conversion efficiency and lowers process costs. Because physiological ash is unevenly distributed in the plant, mechanical processes can be used to separate fractions of the plant based on ash content. This study focuses on the ash separation that can be achieved by separating corn stover by particle size and anatomical fraction. Baled corn stovermore » was hand-separated into anatomical fractions, ground to <19.1 mm, and size separated using six sieves ranging from 9.5 to 0.150 mm. Size fractions were analyzed for total ash content and ash composition. Particle size distributions observed for the anatomical fractions varied considerably. Cob particles were primarily 2.0 mm or greater, while most of the sheath and husk particles were 2.0 mm and smaller. Particles of leaves greater than 0.6 mm contained the greatest amount of total ash, ranging from approximately 8 to 13% dry weight of the total original material, while the fractions with particles smaller than 0.6 mm contained less than 2% of the total ash of the original material. As a result, based on the overall ash content and the elemental ash, specific anatomical and size fractions can be separated to optimize the feedstocks being delivered to biofuels conversion processes and minimize the need for more expensive ash reduction treatments.« less

  15. White Mountain Group LLC | Open Energy Information

    Open Energy Info (EERE)

    Group LLC Jump to: navigation, search Name: White Mountain Group, LLC Place: Delaware Product: The company has entered an agreement with Australian Biodiesel Group for a share...

  16. The White House's Week of Making

    Broader source: Energy.gov [DOE]

    The White House's Week of Making from June 12-18 will coincide with a National Maker Faire event in Washington, D.C.

  17. The Development of a Small Engine Based Accelerated Ash Loading Protocol |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Accelerated Ash Loading Protocol The Development of a Small Engine Based Accelerated Ash Loading Protocol Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs. 2006_deer_bunting.pdf (371.89 KB) More Documents & Publications The Development of a Small Engine Based Ash Loading Protocol Development of an Accelerated Ash-Loading Protocol for Diesel

  18. The Development of a Small Engine Based Ash Loading Protocol | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Ash Loading Protocol The Development of a Small Engine Based Ash Loading Protocol When 5% lubrication oil is added to diesel fuel in a small engine test, ash increases linearly and at the back of a filter, the amount depending on the differences in substrate and wash-coat type. deer08_bunting.pdf (322.41 KB) More Documents & Publications Development of an Accelerated Ash-Loading Protocol for Diesel Particulate Filters Requirements-Driven Diesel Catalyzed Particulate Trap Design

  19. 2.8-Ma Ash-Flow Caldera At Chegem River In The Northern Caucasus...

    Open Energy Info (EERE)

    .8-Ma Ash-Flow Caldera At Chegem River In The Northern Caucasus Mountains (Russia), Contemporaneous Granites, And Associated Ore Deposits Jump to: navigation, search OpenEI...

  20. Experimental and numerical analysis of metal leaching from fly ash-amended highway bases

    SciTech Connect (OSTI)

    Cetin, Bora; Aydilek, Ahmet H.; Li, Lin

    2012-05-15

    Highlights: Black-Right-Pointing-Pointer This study is the evaluation of leaching potential of fly ash-lime mixed soils. Black-Right-Pointing-Pointer This objective is met with experimental and numerical analysis. Black-Right-Pointing-Pointer Zn leaching decreases with increase in fly ash content while Ba, B, Cu increases. Black-Right-Pointing-Pointer Decrease in lime content promoted leaching of Ba, B and Cu while Zn increases. Black-Right-Pointing-Pointer Numerical analysis predicted lower field metal concentrations. - Abstract: A study was conducted to evaluate the leaching potential of unpaved road materials (URM) mixed with lime activated high carbon fly ashes and to evaluate groundwater impacts of barium, boron, copper, and zinc leaching. This objective was met by a combination of batch water leach tests, column leach tests, and computer modeling. The laboratory tests were conducted on soil alone, fly ash alone, and URM-fly ash-lime kiln dust mixtures. The results indicated that an increase in fly ash and lime content has significant effects on leaching behavior of heavy metals from URM-fly ash mixture. An increase in fly ash content and a decrease in lime content promoted leaching of Ba, B and Cu whereas Zn leaching was primarily affected by the fly ash content. Numerically predicted field metal concentrations were significantly lower than the peak metal concentrations obtained in laboratory column leach tests, and field concentrations decreased with time and distance due to dispersion in soil vadose zone.

  1. Recovery Act Workers Accomplish Cleanup of Second Cold War Coal Ash Basin

    Broader source: Energy.gov [DOE]

    American Recovery and Reinvestment Act workers recently cleaned up a second basin containing coal ash residues from Cold War operations at the Savannah River Site (SRS).

  2. MARKET ASSESSMENT AND TECHNICAL FEASIBILITY STUDY OF PRESSURIZED FLUIDIZED BED COMBUSTION ASH USE

    SciTech Connect (OSTI)

    A.E. Bland; T.H. Brown

    1997-04-01

    Western Research Institute, in conjunction with the Electric Power Research Institute, Foster Wheeler International, Inc. and the US Department of Energy, has undertaken a research and demonstration program designed to examine the market potential and the technical feasibility of ash use options for PFBC ashes. Ashes from the Foster Wheeler Energia Oy pilot-scale circulating PFBC tests in Karhula, Finland, combusting (1) low-sulfur subbituminous and (2) high-sulfur bituminous coal, and ash from the AEP's high-sulfur bituminous coal-fired bubbling PFBC in Brilliant, Ohio, were evaluated in laboratory and pilot-scale ash use testing at WR1. The technical feasibility study examined the use of PFBC ash in construction-related applications, including its use as a cementing material in concrete and use in cement manufacturing, fill and embankment materials, soil stabilization agent, and use in synthetic aggregate production. Testing was also conducted to determine the technical feasibility of PFBC ash as a soil amendment for acidic and sodic problem soils and spoils encountered in agricultural and reclamation applications. The results of the technical feasibility testing indicated the following conclusions. PFBC ash does not meet the chemical requirements as a pozzolan for cement replacement. However, it does appear that potential may exist for its use in cement production as a pozzolan and/or as a set retardant. PFBC ash shows relatively high strength development, low expansion, and low permeability properties that make its use in fills and embankments promising. Testing has also indicated that PFBC ash, when mixed with low amounts of lime, develops high strengths, suitable for soil stabilization applications and synthetic aggregate production. Synthetic aggregate produced from PFBC ash is capable of meeting ASTM/AASHTO specifications for many construction applications. The residual calcium carbonate and calcium sulfate in the PFE3C ash has been shown to be of value in

  3. Savannah River Site Takes on Another Environmental Cleanup Challenge: Coal-Fired Ash

    Broader source: Energy.gov [DOE]

    AIKEN, S.C. – Workers have begun excavating a thick layer of coal ash covering approximately 100 acres of the Savannah River Site (SRS).

  4. Coal-ash Corrosion of Alloys for Combustion Power Plants

    SciTech Connect (OSTI)

    Natesan, K.; Purohit, A.; Rink, D.L.

    2003-04-22

    A program on coal-ash corrosion is being conducted at Argonne National Laboratory to evaluate the performance of several structural alloys in the presence of mixtures of synthetic coal ash, alkali sulfates, and alkali chlorides. Candidate alloys are also exposed in a small-scale coal-fired combustor at the National Energy Technology Laboratory in Pittsburgh. Experiments in the present program, which addresses the effects of deposit chemistry, temperature, and alloy chemistry on the corrosion response of alloys, were conducted at temperatures in the range of 575-800 C for time periods up to {approx}1850 h. Fe-base alloys selected for the study included HR3C, 310TaN, HR120, SAVE 25, NF709, modified 800, 347HFG, and HCM12A. In addition, 800H clad with Alloy 671 was included in several of the exposures. Ni-base alloys selected for the study included 600, 601, 617, 690, 625, 602CA, 214, 230, 45TM, HR 160, and 693. Data were obtained on weight change, scale thickness, internal penetration, microstructural characteristics of corrosion products, mechanical integrity of the scales, and cracking of scales. Results showed that the relationship of corrosion rates to temperature followed a bell-shaped curve for Fe-base alloys, with peak rates at {approx}725 C, but the rate itself was dependent on the alloy chemistry. Several Fe-base alloys showed acceptable rates in the sulfate-containing coal-ash environment; but NaCl in the deposit led to catastrophic corrosion at 650 and 800 C. Ni-base alloys generally exhibited less corrosion than the Fe-base alloys under similar exposure conditions; however, they were susceptible to localized corrosion in the form of pits.

  5. White House | National Nuclear Security Administration

    National Nuclear Security Administration (NNSA)

    White House White House Honors Four Early-Career Sandia Researchers Sandia National Laboratories researchers Matthew Brake, Adrian Chavez, Seth Root and Daniel Stick have been named by President Barack Obama as recipients of the Presidential Early Career Award for Scientists and Engineers (PECASE). The PECASE is the highest honor the U.S. government gives

  6. Speciation of Selenium, Arsenic, and Zinc in Class C Fly Ash

    SciTech Connect (OSTI)

    Luo, Yun; Giammar, Daniel E.; Huhmann, Brittany L.; Catalano, Jeffrey G.

    2011-11-17

    A major environmental concern associated with coal fly ash is the mobilization of trace elements that may contaminate water. To better evaluate proper use of fly ash, determine appropriate disposal methods, and monitor postdisposal conditions, it is important to understand the speciation of trace elements in fly ash and their possible environmental impact. The speciation of selenium, arsenic, and zinc was determined in five representative Class C fly ash samples from combustion of sub-bituminous Powder River Basin coal using synchrotron-based X-ray absorption spectroscopy to provide an improved understanding of the mechanisms of trace element association with the fly ash. Selenium in all fly ash samples occurs predominantly as Se(IV), with the exception of one sample, in which there was a minor amount of Se(0). Se(0) is likely associated with the high content of unburned coal in the sample. Arsenic exists in the fly ash as a single phase most consistent with calcium pyroarsenate. In contrast, zinc occurs as two distinct species in the silicate glass matrix of the fly ash. This work demonstrates that residual carbon in fly ash may reduce potential Se mobility in the environment by retaining it as less soluble elemental Se instead of Se(IV). Further, this work suggests that As and Zn in Class C fly ash will display substantially different release and mobilization behaviors in aquatic environments. While As release will primarily depend upon the dissolution and hydrolysis of calcium pyroarsenate, Zn release will be controlled by the dissolution of alkaline aluminosilicate glass in the ash.

  7. Growth and elemental accumulation by canola on soil amended with coal fly ash

    SciTech Connect (OSTI)

    Yunusa, I.A.M.; Manoharan, V.; DeSilva, D.L.; Eamus, D.; Murray, B.R.; Nissanka, S.P.

    2008-05-15

    To explore the agronomic potential of an Australian coal fly ash, we conducted two glasshouse experiments in which we measured chlorophyll fluorescence, CO{sub 2} assimilation (A), transpiration, stomatal conductance, biomass accumulation, seed yield, and elemental uptake for canola (Brassica napus) grown on soil amended with an alkaline fly ash. In Experiment 1, application of up to 25 Mg/ha of fly ash increased A and plant weight early in the season before flowering and seed yield by up to 21%. However, at larger rates of ash application A, plant growth, chlorophyll concentration, and yield were all reduced. Increases in early vigor and seed yield were associated with enhanced uptake of phosphorus (P) by the plants treated with fly ash. Fly ash application did not influence accumulation of B, Cu, Mo, or Zn in the stems at any stage of plant growth or in the seed at harvest, except Mo concentration, which was elevated in the seed. Accumulation of these elements was mostly in the leaves, where concentrations of Cu and Mo increased with any amount of ash applied while that of B occurred only with ash applied at 625 Mg/ha. In Experiment 2, fly ash applied at 500 Mg/ha and mixed into the whole 30 cm soil core was detrimental to growth and yield of canola, compared with restricting mixing to 5 or 15 cm depth. In contrast, application of ash at 250 Mg/ha with increasing depth of mixing increased A and seed yield. We concluded that fly ash applied at not more than 25 Mg/ha and mixed into the top 10 to 15 cm of soil is sufficient to obtain yield benefits.

  8. Influence of combustion conditions and coal properties on physical properties of fly ash generated from pulverized coal combustion

    SciTech Connect (OSTI)

    Hiromi Shirai; Hirofumi Tsuji; Michitaka Ikeda; Toshinobu Kotsuji

    2009-07-15

    To develop combustion technology for upgrading the quality of fly ash, the influences of the coal properties, such as the size of pulverized coal particles and the two-stage combustion ratio during the combustion, on the fly ash properties were investigated using our test furnace. The particle size, density, specific surface area (obtained by the Blaine method), and shape of fly ash particles of seven types of coal were measured. It was confirmed that the size of pulverized coal particles affects the size of the ash particles. Regarding the coal properties, the fuel ratio affected the ash particle size distribution. The density and shape of the ash particles strongly depended on their ash size. Our results indicated that the shape of the ash particles and the concentration of unburned carbon affected the specific surface area. The influence of the two-stage combustion ratio was limited. 8 refs., 13 figs., 3 tabs.

  9. Controlled Experiments on the Effects of Lubricant/Additive (Low-Ash, Ashless) Characteristics on DPF Degradation

    Broader source: Energy.gov [DOE]

    Effects of lubricant additive chemistries and exhaust conditions on ash properties affecting diesel particulate filter performance. Comparison of ash characteristics such as packing density and elemental composition in field and laboratory aged DPFs.

  10. Determination of Total Solids and Ash in Algal Biomass: Laboratory Analytical Procedure (LAP)

    SciTech Connect (OSTI)

    Van Wychen, S.; Laurens, L. M. L.

    2013-12-01

    This procedure describes the methods used to determine the amount of moisture or total solids present in a freeze-dried algal biomass sample, as well as the ash content. A traditional convection oven drying procedure is covered for total solids content, and a dry oxidation method at 575?C is covered for ash content.

  11. California bearing ratio behavior of soil-stabilized class F fly ash systems

    SciTech Connect (OSTI)

    Leelavathamma, B.; Mini, K.M.; Pandian, N.S.

    2005-11-01

    Fly ash is a finely divided mineral residue resulting from the combustion of coal in power plants that occupies large extents of land and also causes environmental problems. Hence, concerted attempts are being made to effectively use fly ash in an environmentally friendly way instead of dumping. Several studies have been carried out for its bulk utilization, such as its addition to improve the California bearing ratio (CBR) of soil in roads and embankments. But a thorough mixing of fly ash with soil may not be possible in the field. Hence a study has been carried out on the CBR behavior of black cotton soil and Raichur fly ash (which is class F) in layers and compared with the same in mixes. The results show that the CBR values of soil-fly ash mixes are better than layers, as expected. To improve the strength of layers, cement is used as an additive to fly ash. The results show that black cotton soil can be improved with stabilized fly ash, solving its strength problem as well as the disposal problem of fly ash.

  12. Stabilization of Oklahoma expensive soils using lime and class C fly ash

    SciTech Connect (OSTI)

    Buhler, R.L.; Cerato, A.B.

    2007-01-15

    This study uses lime and class C fly ash, an industrial byproduct of electric power production produced from burning lignite and subbituminous coal, to study the plasticity reduction in highly expensive natural clays from Idabel, Oklahoma. This study is important, especially in Oklahoma, because most of the native soils are expansive and cause seasonal damage to roadways and structures. The addition of lime or fly ash helps to arrest the shrinkage and swelling behavior of soil. Four soil samples with the same AASHTO classification were used in this study to show shrinkage variability within a soil group with the addition of lime and class C fly ash. The plasticity reduction in this study was quantified using the linear shrinkage test. It was found that soils classified within the same AASHTO group had varying shrinkage characteristics. It was also found that both lime and fly ash reduced the lienar shrinkage, however, the addition of lime reduced the linear shrinkage to a greater degree than the same percentage of class C fly ash. Even though it takes much less lime than fly ash to reduce the plasticity of a highly expansive soil, it may be less expensive to utilize fly ash, which is a waste product of electric power production. Lime also has a lower unit weight than fly ash so weight percentage results may be misleading.

  13. INVESTIGATION OF FLY ASH AND ACTIVATED CARBON OBTAINED FROM PULVERIZED COAL BOILERS

    SciTech Connect (OSTI)

    Edward K. Levy; Christopher Kiely

    2004-11-01

    One of the techniques for Hg capture in coal-fired boilers involves injection of activated carbon (AC) into the boiler downstream of the air preheater. Hg is adsorbed onto the AC particles and fly ash, which are then both removed in an electrostatic precipitator or baghouse. This project addresses the issues of Hg on activated carbon and on fly ash from a materials re-use point of view. It also addresses the possible connection between SCR reactors, fly ash properties and Hg capture. The project is determining the feasibility of separating AC from fly ash in a fluidized bed and of regenerating the separated AC by heating the AC to elevated temperatures in a fluidized bed. The temperatures needed to drive off the Hg from the ash in a fluidized bed are also being determined. Finally, samples of fly ash from power plants with SCR reactors for NO{sub x} control, are being analyzed to determine the effect of SCR on the ash. These analyses will also determine the properties of ash which are important for Hg capture.

  14. Site-specific study on stabilization of acid-generating mine tailings using coal fly ash

    SciTech Connect (OSTI)

    Shang, J.Q.; Wang, H.L.; Kovac, V.; Fyfe, J.

    2006-03-15

    A site-specific study on stabilizing acid-generating mine tailings from Sudbury Mine using a coal fly ash from Nanticoke Generating Station is presented in this paper. The objective of the study is to evaluate the feasibility of codisposal of the fly ash and mine tailings to reduce environmental impacts of Sudbury tailings disposal sites. The study includes three phases, i.e., characterization of the mine tailings, and coal fly ash, oxidation tests on the mine tailings and kinetic column permeation tests. The results of the experiments indicate that when permeated with acid mine drainage, the hydraulic conductivity of Nanticoke coal fly ash decreased more than three orders of magnitude (from 1 x 10{sup -6} to 1 x 10{sup -9} cm/s), mainly due to chemical reactions between the ash solids and acid mine drainage. Furthermore, the hydraulic gradient required for acid mine drainage to break through the coal fly ash is increased up to ten times (from 17 to 150) as compared with that for water. The results also show that the leachate from coal fly ash neutralizes the acidic pore fluid of mine tailings. The concentrations of trace elements in effluents from all kinetic column permeation tests indicated that coplacement of coal fly ash with mine tailings has the benefit of immobilizing trace elements, especially heavy metals. All regulated element concentrations from effluent during testing are well below the leachate quality criteria set by the local regulatory authority.

  15. Power-plant fly-ash utilization: a chemical processing perspective

    SciTech Connect (OSTI)

    Burnet, G.; Murtha, M.J.

    1981-01-01

    The 1976 Resource Conservation and Recovery Act (RCRA) deals with the management of solid and hazardous wastes, and encourages energy and resource recovery. Recent research has indicated that solid wastes from coal combustion, including fly ash, could be classified as hazardous under present EPA definitions. The seriousness of this possibility has been recognized and new rules for coal ash waste disposal are being considered. Ames Laboratory research on fly ash utilization as an alternative to disposal includes extraction of metals from the ash and discovery of uses for the process residues. Recovery of alumina and iron oxides by physical and chemical processing would permit large scale utilization of fly ash and help reduce dependency on imports. One of the processes investigated uses a lime-soda sinter method to form soluble aluminate compounds from mixtures of fly ash, limestone, and soda ash. The aluminates are extracted, treated to remove silicates, and precipitated: the precipitate is calcined to metallurgical grade alumina. The extract residue shows promise as a raw material for the production of Portland cement. Process economics are presented, and the effects of alumina and silica contents of the fly ash, sintering temperatures and time, and sales credits for by-products are discussed.

  16. White Plains, New York: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    in White Plains, New York 3 Registered Financial Organizations in White Plains, New York 4 References US Recovery Act Smart Grid Projects in White Plains, New York Power Authority...

  17. City of White, South Dakota (Utility Company) | Open Energy Informatio...

    Open Energy Info (EERE)

    White, South Dakota (Utility Company) Jump to: navigation, search Name: City of White Place: South Dakota Phone Number: 605-629-2601 Website: www.white.govoffice2.comindex Outage...

  18. Quantification of the degree of reaction of fly ash

    SciTech Connect (OSTI)

    Ben Haha, M.; De Weerdt, K.; Lothenbach, B.

    2010-11-15

    The quantification of the fly ash (FA) in FA blended cements is an important parameter to understand the effect of the fly ash on the hydration of OPC and on the microstructural development. The FA reaction in two different blended OPC-FA systems was studied using a selective dissolution technique based on EDTA/NaOH, diluted NaOH solution, the portlandite content and by backscattered electron image analysis. The amount of FA determined by selective dissolution using EDTA/NaOH is found to be associated with a significant possible error as different assumptions lead to large differences in the estimate of FA reacted. In addition, at longer hydration times, the reaction of the FA is underestimated by this method due to the presence of non-dissolved hydrates and MgO rich particles. The dissolution of FA in diluted NaOH solution agreed during the first days well with the dissolution as observed by image analysis. At 28 days and longer, the formation of hydrates in the diluted solutions leads to an underestimation. Image analysis appears to give consistent results and to be most reliable technique studied.

  19. 488-D Ash Basin Vegetative Cover Treatibility Study

    SciTech Connect (OSTI)

    Barton, Christopher; Marx, Don; Blake, John; Adriano, Domy; Koo, Bon-Jun; Czapka, Stephen

    2003-01-01

    The 488-D Ash Basin is an unlined containment basin that received ash and coal reject material from the operation of a powerhouse at the USDOE's Savannah River Site, SC. They pyretic nature of the coal rejects has resulted in the formation of acidic drainage (AD), which has contributed to groundwater deterioration and threatens biota in down gradient wetlands. Establishment of a vegetative cover was examined as a remedial alternative for reducing AD generation within this system by enhanced utilization of rainwater and subsequent non-point source water pollution control. The low nutrient content, high acidity, and high salinity of the basin material, however, was deleterious to plant survivability. As such, studies to identify suitable plant species and potential adaptations, and pretreatment techniques in the form of amendments, tilling, and/or chemical stabilization were needed. A randomized block design consisting of three subsurface treatments (blocks) and five duplicated surface amendments (treatments) was developed. One hundred inoculated pine trees were planted on each plot. Herbaceous species were also planted on half of the plots in duplicated 1-m2 beds. After two growing seasons, deep ripping, subsurface amendments and surface covers were shown to be essential for the successful establishment of vegetation on the basin. This is the final report of the study.

  20. Evaluation of rice husk ash as filler in tread compounds

    SciTech Connect (OSTI)

    Fernandes, M. R. S.; Furtado, C. R. G. E-mail: ana.furtado.sousa@gmail.com; Sousa, A. M. F. de E-mail: ana.furtado.sousa@gmail.com

    2014-05-15

    Rice which is one of the largest agriculture crops produces around 22% of rice rusk during its milling process. This material is mainly used as fuel for energy generation, which results in an ash, which disposal represents an environmental issue. The rice husk ash (RHA) contains over than 70% of silica in an amorphous form and a lot of applications is being developed for it all over the world. The use of silica as a filler in the tire industry is growing since it contributes significantly to the reduction of fuel consumption of the automobiles, allowing at the same time better traction (safety). This paper presents an evaluation of the use of RHA as filler in rubber tread compounds prepared in lab scale and compares its performance with compounds prepared with commercial silica and carbon black, the fillers normally used in tire industry. Mechanical and rheological properties are evaluated, with emphasis for tan delta as an indicator of tread performance related with rolling resistance (fuel consumption) and wet grip/traction (safety)

  1. pH-dependent leaching of dump coal ash - retrospective environmental analysis

    SciTech Connect (OSTI)

    Popovic, A.; Djordjevic, D. [University of Belgrade, Belgrade (Serbia). Dept. of Chemistry

    2009-07-01

    Trace and major elements in coal ash particles from dump of 'Nikola Tesla A' power plant in Obrenovac near Belgrade (Serbia) can cause pollution, due to leaching by atmospheric and surface waters. In order to assess this leaching potential, dump ash samples were subjected to extraction with solutions of decreasing pH values (8.50, 7.00, 5.50, and 4.00), imitating the reactions of the alkaline ash particles with the possible alkaline, neutral, and acidic (e.g., acid rain) waters. The most recently deposited ash represents the greatest environmental threat, while 'aged' ash, because of permanent leaching on the dump, was shown to have already lost this pollution potential. On the basis of the determined leachability, it was possible to perform an estimation of the acidity of the regional rainfalls in the last decades.

  2. Mercury retention by fly ashes from coal combustion: Influence of the unburned carbon content

    SciTech Connect (OSTI)

    Lopez-Anton, M.A.; Diaz-Somoano, M.; Martinez-Tarazona, M.R.

    2007-01-31

    The objective of this study was to evaluate the effect of unburned carbon particles present in fly ashes produced by coal combustion on mercury retention. To achieve this objective, the work was divided into two parts. The aim of the first part of the study was to estimate the amount of mercury captured by the fly ashes during combustion in power stations and the relationship of this retention to the unburned carbon content. The second part was a laboratory-scale study aimed at evaluating the retention of mercury concentrations greater than those produced in power stations by fly ashes of different characteristics and by unburned carbon particles. From the results obtained it can be inferred that the unburned carbon content is not the only variable that controls mercury capture in fly ashes. The textural characteristics of these unburned particles and of other components of fly ashes also influence retention.

  3. Gypsum treated fly ash as a liner for waste disposal facilities

    SciTech Connect (OSTI)

    Sivapullaiah, Puvvadi V.; Baig, M. Arif Ali

    2011-02-15

    Fly ash has potential application in the construction of base liners for waste containment facilities. While most of the fly ashes improve in the strength with curing, the ranges of permeabilities they attain may often not meet the basic requirement of a liner material. An attempt has been made in the present context to reduce the hydraulic conductivity by adding lime content up to 10% to two selected samples of class F fly ashes. The use of gypsum, which is known to accelerate the unconfined compressive strength by increasing the lime reactivity, has been investigated in further improving the hydraulic conductivity. Hydraulic conductivities of the compacted specimens have been determined in the laboratory using the falling head method. It has been observed that the addition of gypsum reduces the hydraulic conductivity of the lime treated fly ashes. The reduction in the hydraulic conductivity of the samples containing gypsum is significantly more for samples with high amounts of lime contents (as high as 1000 times) than those fly ashes with lower amounts of lime. However there is a relatively more increase in the strengths of the samples with the inclusion of gypsum to the fly ashes at lower lime contents. This is due to the fact that excess lime added to fly ash is not effectively converted into pozzolanic compounds. Even the presence of gypsum is observed not to activate these reactions with excess lime. On the other hand the higher amount of lime in the presence of sulphate is observed to produce more cementitious compounds which block the pores in the fly ash. The consequent reduction in the hydraulic conductivity of fly ash would be beneficial in reducing the leachability of trace elements present in the fly ash when used as a base liner.

  4. Simulation of Coal Ash Particle Deposition Experiments (Copyright 2011, American Chemical Society)

    SciTech Connect (OSTI)

    Ai, Weiguo; Kuhlman, John M

    2011-01-20

    Existing experimental ash particle deposition measurements from the literature have been simulated using the computational fluid dynamics (CFD) discrete phase model (DPM) Lagrangian particle tracking method and an existing ash particle deposition model based on the Johnson−Kendall−Roberts (JKR) theory, in the Fluent commercial CFD code. The experimental heating tube was developed to simulate ash temperature histories in a gasifier; ash-heating temperatures ranged from 1873 to 1573 K, spanning the ash-melting temperature. The present simulations used the realizable k−ε turbulence model to compute the gas flow field and the heat transfer to a cooled steel particle impact probe and DPM particle tracking for the particle trajectories and temperatures. A user-defined function (UDF) was developed to describe particle sticking/rebounding and particle detachment on the impinged wall surface. Expressions for the ash particle Young’s modulus in the model, E, versus the particle temperature and diameter were developed by fitting to the E values that were required to match the experimental ash sticking efficiencies from several particle size cuts and ash-heating temperatures for a Japanese bituminous coal. A UDF that implemented the developed stiffness parameter equations was then used to predict the particle sticking efficiency, impact efficiency, and capture efficiency for the entire ash-heating temperature range. Frequency histogram comparisons of adhesion and rebound behavior by particle size between model and experiments showed good agreement for each of the four ash-heating temperatures. However, to apply the present particle deposition model to other coals, a similar validation process would be necessary to develop the effective Young’s modulus versus the particle diameter and temperature correlation for each new coal.

  5. White LED with High Package Extraction Efficiency (Technical...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: White LED with High Package Extraction Efficiency Citation Details In-Document Search Title: White LED with High Package Extraction Efficiency The goal of this ...

  6. Sandia Energy - Four-color laser white illuminant demonstrating...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    laser white illuminant demonstrating high color-rendering quality Home Solid-State Lighting News Four-color laser white illuminant demonstrating high color-rendering quality...

  7. Tribal Leaders Provide White House with Input on Bolstering Climate...

    Office of Environmental Management (EM)

    Leaders Provide White House with Input on Bolstering Climate Resilience Tribal Leaders Provide White House with Input on Bolstering Climate Resilience January 7, 2015 - 10:29am ...

  8. White House Leadership Summit on Women, Climate and Energy |...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    White House Leadership Summit on Women, Climate and Energy White House Leadership Summit on Women, Climate and Energy Addthis Topic Energy Efficiency Energy Usage Science & ...

  9. The origin of white luminescence from silicon oxycarbide thin...

    Office of Scientific and Technical Information (OSTI)

    origin of white luminescence from silicon oxycarbide thin films Citation Details In-Document Search Title: The origin of white luminescence from silicon oxycarbide thin films ...

  10. White County, Tennessee: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Number 4 Climate Zone Subtype A. Places in White County, Tennessee Doyle, Tennessee Sparta, Tennessee Retrieved from "http:en.openei.orgwindex.php?titleWhiteCounty,Tennes...