Sample records for isotopic analysis activity

  1. Determination of isotopic thorium in biological samples by combined alpha spectrometry and neutron activation analysis.

    SciTech Connect (OSTI)

    Glover, S. E. (Samuel E.)

    2003-01-01T23:59:59.000Z

    Thorium is a naturally occurring element for whom all isotopes are radioactive . Many of these isotopes are alpha emitting radionuclides, some of which have limits for inhalation lower than plutonium in current regulations . Neutron activation analysis can provide for the low-level determination of 232Th but can not determine other isotopes of dosimetric importance . Biological and environmental samples often have large quantities of materials which activate strongly, limiting the capabilities of instrumental neutron activiation analysis . This paper will discuss the application of a combined technique using alpha spectrometry and radiochemical neutron activiation analysis for the determination of isotopic thorium .

  2. Isotopic Analysis At Lassen Volcanic National Park Area (Janik...

    Open Energy Info (EERE)

    navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Isotopic Analysis At Lassen Volcanic National Park Area (Janik & Mclaren, 2010) Exploration Activity...

  3. Isotopic Analysis At Valles Caldera - Redondo Geothermal Area...

    Open Energy Info (EERE)

    navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Isotopic Analysis At Valles Caldera - Redondo Geothermal Area (Phillips, 2004) Exploration Activity...

  4. Isotopic Analysis- Rock At Valles Caldera - Sulphur Springs Geothermal...

    Open Energy Info (EERE)

    navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Isotopic Analysis- Rock At Valles Caldera - Sulphur Springs Geothermal Area (Phillips, 2004)...

  5. Isotopic Analysis- Rock At Valles Caldera - Sulphur Springs Geothermal...

    Open Energy Info (EERE)

    navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Isotopic Analysis- Rock At Valles Caldera - Sulphur Springs Geothermal Area (Ito & Tanaka, 1995)...

  6. Isotopic Analysis- Rock At Valles Caldera - Sulphur Springs Area...

    Open Energy Info (EERE)

    navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Isotopic Analysis- Rock At Valles Caldera - Sulphur Springs Area (Ito & Tanaka, 1995) Exploration...

  7. Isotopic Analysis- Fluid At Indian Valley Hot Springs Geothermal...

    Open Energy Info (EERE)

    Activity: Isotopic Analysis- Fluid At Indian Valley Hot Springs Geothermal Area (1990) Exploration Activity Details Location Indian Valley Hot Springs Geothermal Area...

  8. Isotopic Analysis- Fluid At Roosevelt Hot Springs Geothermal...

    Open Energy Info (EERE)

    Details Location Roosevelt Hot Springs Geothermal Area Exploration Technique Isotopic Analysis- Fluid Activity Date 1981 - 1981 Usefulness useful DOE-funding Unknown Exploration...

  9. Isotopic Analysis- Fluid At Long Valley Caldera Geothermal Area...

    Open Energy Info (EERE)

    Farrar, Et Al., 2003) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Isotopic Analysis- Fluid At Long Valley Caldera Geothermal Area (Farrar, Et...

  10. Isotopic Analysis At Long Valley Caldera Geothermal Area (Evans...

    Open Energy Info (EERE)

    Isotopic Analysis At Long Valley Caldera Geothermal Area (Evans, Et Al., 2002) Exploration Activity Details Location Long Valley Caldera Geothermal Area Exploration Technique...

  11. Isotopic Analysis- Fluid At Long Valley Caldera Geothermal Area...

    Open Energy Info (EERE)

    Gerlach, 1983) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Isotopic Analysis- Fluid At Long Valley Caldera Geothermal Area (Taylor & Gerlach,...

  12. The computerized identification of reactor-produced isotopes in an activation analysis environment

    E-Print Network [OSTI]

    Schlueter, Daniel John

    1971-01-01T23:59:59.000Z

    (ELG ('V rG:", ) I ~ 22F 06(3) 657 80(1000) 1 884 ~ 50( 539) 1 706 80( 162) 1 1384. 30( LO8) 1 686 F 80( 64)1 817, on( 61)1 556. CC( 34) 4 744. 20( 38) 1 937. 30( 243) I 677. 50( 107) 1 1505. ?0( 55)1 1475. 90( 16!1 763. 80( 446. 20( 620. 10( 1562... the rerluirement for U&c d gree of MASTI R OF SCIENC1. December 1971 Major Subject: Computing Science THE COMPUTERIZED IDENTIFICATION OF REACTOR-PRODUCED PSOTOPES IN AN ACTIVATION ANALYSIS ENVIRONMENT A Thesis by DANIEL ZOHN SCIILUETER Approved...

  13. Assessment of Non-traditional Isotopic Ratios by Mass Spectrometry for Analysis of Nuclear Activities: Annual Report Year 2

    SciTech Connect (OSTI)

    Biegalski, S; Buchholz, B

    2009-08-26T23:59:59.000Z

    The objective of this work is to identify isotopic ratios suitable for analysis via mass spectrometry that distinguish between commercial nuclear reactor fuel cycles, fuel cycles for weapons grade plutonium, and products from nuclear weapons explosions. Methods will also be determined to distinguish the above from medical and industrial radionuclide sources. Mass spectrometry systems will be identified that are suitable for field measurement of such isotopes in an expedient manner. Significant progress has been made with this project within the past year: (1) Isotope production from commercial nuclear fuel cycles and nuclear weapons fuel cycles have been modeled with the ORIGEN and MCNPX codes. (2) MCNPX has been utilized to calculate isotopic inventories produced in a short burst fast bare sphere reactor (to approximate the signature of a nuclear weapon). (3) Isotopic ratios have been identified that are good for distinguishing between commercial and military fuel cycles as well as between nuclear weapons and commercial nuclear fuel cycles. (4) Mass spectrometry systems have been assessed for analysis of the fission products of interest. (5) A short-list of forensic ratios have been identified that are well suited for use in portable mass spectrometry systems.

  14. Analysis of hydrogen isotope mixtures

    DOE Patents [OSTI]

    Villa-Aleman, Eliel (Aiken, SC)

    1994-01-01T23:59:59.000Z

    An apparatus and method for determining the concentrations of hydrogen isotopes in a sample. Hydrogen in the sample is separated from other elements using a filter selectively permeable to hydrogen. Then the hydrogen is condensed onto a cold finger or cryopump. The cold finger is rotated as pulsed laser energy vaporizes a portion of the condensed hydrogen, forming a packet of molecular hydrogen. The desorbed hydrogen is ionized and admitted into a mass spectrometer for analysis.

  15. Atom trap trace analysis of krypton isotopes

    SciTech Connect (OSTI)

    Bailey, K.; Chen, C. Y.; Du, X.; Li, Y. M.; Lu, Z.-T.; O'Connor, T. P.; Young, L.

    1999-11-17T23:59:59.000Z

    A new method of ultrasensitive isotope trace analysis has been developed. This method, based on the technique of laser manipulation of neutral atoms, has been used to count individual {sup 85}Kr and {sup 81}Kr atoms present in a natural krypton gas sample with isotopic abundances in the range of 10{sup {minus}11} and 10{sup {minus}13}, respectively. This method is free of contamination from other isotopes and elements and can be applied to several different isotope tracers for a wide range of applications. The demonstrated detection efficiency is 1 x 10{sup {minus}7}. System improvements could increase the efficiency by many orders of magnitude.

  16. Isotopic Analysis At Nw Basin & Range Region (Kennedy & Van Soest...

    Open Energy Info (EERE)

    useful regional reconnaissance DOE-funding Unknown Notes The correspondence of helium isotope ratios and active transtensional deformation indicates a deformation-enhanced...

  17. Isotopic Analysis At Northern Basin & Range Region (Kennedy ...

    Open Energy Info (EERE)

    useful regional reconnaissance DOE-funding Unknown Notes The correspondence of helium isotope ratios and active transtensional deformation indicates a deformation-enhanced...

  18. Isotopic Analysis At Central Nevada Seismic Zone Region (Kennedy...

    Open Energy Info (EERE)

    useful regional reconnaissance DOE-funding Unknown Notes The correspondence of helium isotope ratios and active transtensional deformation indicates a deformation-enhanced...

  19. Isotopic Analysis At Walker-Lane Transitional Zone Region (Kennedy...

    Open Energy Info (EERE)

    useful regional reconnaissance DOE-funding Unknown Notes The correspondence of helium isotope ratios and active transtensional deformation indicates a deformation-enhanced...

  20. System and method for high precision isotope ratio destructive analysis

    DOE Patents [OSTI]

    Bushaw, Bruce A; Anheier, Norman C; Phillips, Jon R

    2013-07-02T23:59:59.000Z

    A system and process are disclosed that provide high accuracy and high precision destructive analysis measurements for isotope ratio determination of relative isotope abundance distributions in liquids, solids, and particulate samples. The invention utilizes a collinear probe beam to interrogate a laser ablated plume. This invention provides enhanced single-shot detection sensitivity approaching the femtogram range, and isotope ratios that can be determined at approximately 1% or better precision and accuracy (relative standard deviation).

  1. ISOTOPES

    E-Print Network [OSTI]

    Lederer, C. Michael

    2013-01-01T23:59:59.000Z

    rare (0.017%) isotope 36s at enrichments of 70% at a price32). The enrichment of carbon isotopes by C02-carbamatesulfur isotopes by S02-NaHS03 exchange and the enrichment of

  2. Standard practice for the ion exchange separation of uranium and plutonium prior to isotopic analysis

    E-Print Network [OSTI]

    American Society for Testing and Materials. Philadelphia

    2008-01-01T23:59:59.000Z

    Standard practice for the ion exchange separation of uranium and plutonium prior to isotopic analysis

  3. Isotopic abundance in atom trap trace analysis

    DOE Patents [OSTI]

    Lu, Zheng-Tian; Hu, Shiu-Ming; Jiang, Wei; Mueller, Peter

    2014-03-18T23:59:59.000Z

    A method and system for detecting ratios and amounts of isotopes of noble gases. The method and system is constructed to be able to measure noble gas isotopes in water and ice, which helps reveal the geological age of the samples and understand their movements. The method and system uses a combination of a cooled discharge source, a beam collimator, a beam slower and magneto-optic trap with a laser to apply resonance frequency energy to the noble gas to be quenched and detected.

  4. 137Cs Activities and 135Cs/137Cs Isotopic Ratios at Idaho National Laboratory: A Case Study in Environmental Nuclear Forensic Analysis

    SciTech Connect (OSTI)

    Mathew S Snow; Morgan Kelley; Darin C. Snyder; James E. Delmore; Sue B. Clark

    2015-01-01T23:59:59.000Z

    Abstract is still in progress. Below is the current outline: -Some statement regarding how Cs can be useful for nuclear forensic analysis of environmental samples. -Then some other statement stating how the SDA provides an excellent case study for such an analysis. -137Cs concentration patterns suggest that the 137Cs came from localized releases in the near vicinity of the SDA, while observations of thermal 135Cs/137Cs ratios suggests some contribution from thermal fission product waste buried within the SDA. -137Cs activity patterns, combined with 135Cs/137Cs ratios, known Cs environmental chemistry, and historical data, suggest the Cs was most likely released from Pit 9 and Trench 48 during the 1969 flood. -Knowledge of the release event and excavations narrows the possible window for waste disposed of at SDA to 5 months (Trench 48) to 1.2 years (Pit 9). -Only 3 waste generators disposed of waste during this timeframe, however, as Rocky Flats Site did not generate any appreciable 137Cs waste, and as best estimates suggest that the INL disposed 2000 times as much non-actinide waste at the SDA than off-site processes, INL related operations are determined to be the most likely contributor to the observed Cs contamination. -While 135Cs/137Cs ratios have the potential to reveal information regarding the reactor design and operating conditions which led to the fission event, the large number of different INL reactors which most likely contributed to waste within Trench 48 and Pit 9, combined with evidence of a mixture of thermal and fast fission product Cs (most likely originating from global + regional fallout) precludes the ability to further refine the 135Cs/137Cs ratios. -However, at other sites which do not contain such large quantities of highly diverse contamination, secondary nuclide monitors which have similar environmental mobilities to Cs (such as Pu or Sr) might enable correction for the quantity of fallout within samples.

  5. Stable carbon isotope ratio of polycyclic aromatic hydrocarbons (PAHs) in the environment: validation of isolation and stable carbon isotope analysis methods

    E-Print Network [OSTI]

    Kim, Moon Koo

    2004-11-15T23:59:59.000Z

    , purification and compound specific isotope analysis methods were developed to accurately measure the stable carbon isotope ratio of individual PAHs. Development of the method included improving accuracy and precision of the isotopic measurement by producing...

  6. RESOLUTION OF URANIUM ISOTOPES WITH KINETIC PHOSPHORESCENCE ANALYSIS

    SciTech Connect (OSTI)

    Miley, Sarah M.; Hylden, Anne T.; Friese, Judah I.

    2013-04-01T23:59:59.000Z

    This study was conducted to test the ability of the Chemchek™ Kinetic Phosphorescence Analyzer Model KPA-11 with an auto-sampler to resolve the difference in phosphorescent decay rates of several different uranium isotopes, and therefore identify the uranium isotope ratios present in a sample. Kinetic phosphorescence analysis (KPA) is a technique that provides rapid, accurate, and precise determination of uranium concentration in aqueous solutions. Utilizing a pulsed-laser source to excite an aqueous solution of uranium, this technique measures the phosphorescent emission intensity over time to determine the phosphorescence decay profile. The phosphorescence intensity at the onset of decay is proportional to the uranium concentration in the sample. Calibration with uranium standards results in the accurate determination of actual concentration of the sample. Different isotopes of uranium, however, have unique properties which should result in different phosphorescence decay rates seen via KPA. Results show that a KPA is capable of resolving uranium isotopes.

  7. activated bismuth isotopes: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CERN Preprints Summary: Currently, 31 actinium, 31 thorium, 28 protactinium, and 23 uranium isotopes have so far been observed; the discovery of these isotopes is discussed. For...

  8. Enabling online geospatial isotopic model development and analysis

    E-Print Network [OSTI]

    Zhang, Tonglin

    Enabling online geospatial isotopic model development and analysis Hyojeong Lee1 , Lan Zhao1 leverages the computation resources available on the TeraGrid to perform geospatial data operations and geostatistical model calculations. It builds on a variety of open source technologies for GIS, geospatial data

  9. Ion Mobility Mass Spectrometry Direct Isotope Abundance Analysis

    SciTech Connect (OSTI)

    Manuel J. Manard, Stephan Weeks, Kevin Kyle

    2010-05-27T23:59:59.000Z

    The nuclear forensics community is currently engaged in the analysis of illicit nuclear or radioactive material for the purposes of non-proliferations and attribution. One technique commonly employed for gathering nuclear forensics information is isotope analysis. At present, the state-of-the-art methodology for obtaining isotopic distributions is thermal ionization mass spectrometry (TIMS). Although TIMS is highly accurate at determining isotope distributions, the technique requires an elementally pure sample to perform the measurement. The required radiochemical separations give rise to sample preparation times that can be in excess of one to two weeks. Clearly, the nuclear forensics community is in need of instrumentation and methods that can expedite their decision making process in the event of a radiological release or nuclear detonation. Accordingly, we are developing instrumentation that couples a high resolution IM drift cell to the front end of a MS. The IM cell provides a means of separating ions based upon their collision cross-section and mass-to-charge ratio (m/z). Two analytes with the same m/z, but with different collision cross-sections (shapes) would exit the cell at different times, essentially enabling the cell to function in a similar manner to a gas chromatography (GC) column. Thus, molecular and atomic isobaric interferences can be effectively removed from the ion beam. The mobility selected chemical species could then be introduced to a MS for high-resolution mass analysis to generate isotopic distributions of the target analytes. The outcome would be an IM/MS system capable of accurately measuring isotopic distributions while concurrently eliminating isobaric interferences and laboratory radiochemical sample preparation. The overall objective of this project is developing instrumentation and methods to produce near real-time isotope distributions with a modular mass spectrometric system that performs the required gas-phase chemistry and separations. The system couples a high-resolution ion mobility (IM) drift cell to the front end of a mass spectrometer (MS) allowing for chemical separation prior to isotope distribution analyses. This will yield isotope ratio measurement capabilities with minimal sample preparation.

  10. A direct and rapid leaf water extraction method for isotopic analysis

    E-Print Network [OSTI]

    Yakir, Dan

    Department of Environmental Sciences and Energy Research, Weizmann Institute of Science, Rehovot, Israel for isotopic analysis via pyrolysis gas chromatography isotope ratio mass spectrometry (PYR/GC/IRMS). The new-scale studies that require high-throughput leaf water isotopic analysis. Copyright # 2008 John Wiley & Sons, Ltd

  11. LEAD ISOTOPIC ANALYSIS FOR THE IDENTIFICATION OF LATE BRONZE AGE POTTERY FROM HALA SULTAN

    E-Print Network [OSTI]

    Claeys, Philippe

    LEAD ISOTOPIC ANALYSIS FOR THE IDENTIFICATION OF LATE BRONZE AGE POTTERY FROM HALA SULTAN TEKKE, 9000 Ghent 5 Department of Geology, Université de Ličge, Allée du 6­Aoűt B18, 4000 Ličge Lead isotopic the effectiveness of using lead isotopic analysis in provenance studies, along with other analytical techniques

  12. Hanford Isotope Project strategic business analysis Cesium-137 (Cs-137)

    SciTech Connect (OSTI)

    NONE

    1995-10-01T23:59:59.000Z

    The purpose of this business analysis is to address the beneficial reuse of Cesium 137 (Cs-137) in order to utilize a valuable national asset and possibly save millions of tax dollars. Food irradiation is the front runner application along with other uses. This business analysis supports the objectives of the Department of Energy National Isotope Strategy distributed in August 1994 which describes the DOE plans for the production and distribution of isotope products and services. As part of the Department`s mission as stated in that document. ``The Department of Energy will also continue to produce and distribute other radioisotopes and enriched stable isotopes for medical diagnostics and therapeutics, industrial, agricultural, and other useful applications on a businesslike basis. This is consistent with the goals and objectives of the National Performance Review. The Department will endeavor to look at opportunities for private sector to co-fund or invest in new ventures. Also, the Department will seek to divest from ventures that can more profitably or reliably be operated by the private sector.``

  13. acfa isotope activation: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    N. Densmore a, Geosciences Websites Summary: -occur- ring radioactive isotopes such as uranium, and radium also have Maximum Contaminant Levels (MCL and 25 picoCuries per liter...

  14. COUPLING LEAD ISOTOPE ANALYSIS AND PETROGRAPHY TO CHARACTERIZE FABRICS OF STORAGE AND TRADE

    E-Print Network [OSTI]

    Claeys, Philippe

    COUPLING LEAD ISOTOPE ANALYSIS AND PETROGRAPHY TO CHARACTERIZE FABRICS OF STORAGE AND TRADE Brussels, Belgium 6 Director of research at Hala Sultan Tekke, Area 8, Cyprus Lead isotopes, thin sections and com- pared to lead isotope results on the same samples. This study shows that a specific

  15. Isotopic Analysis- Fluid At Dixie Valley Geothermal Area (Kennedy...

    Open Energy Info (EERE)

    geothermal resources with deep, fault hosted permeable fluid flow pathways and the helium Isotopic composition of the surface fluids. The authors suggest that helium isotopes...

  16. Isotopes

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHigh SchoolIn12 Investigation Peer ReviewIronNuclear Physics » Isotopes

  17. Identification of sources of lead exposure in French children by lead isotope analysis: a cross-

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Identification of sources of lead exposure in French children by lead isotope analysis: a cross://www.ehjournal.net/content/10/1/75 (28 August 2011) #12;RESEARCH Open Access Identification of sources of lead exposure in French children by lead isotope analysis: a cross- sectional study Youssef Oulhote1,2,3* , Barbara Le Bot

  18. A ROBUST ABSOLUTE DETECTION EFFICIENCY CALIBRATION METHOD UTILIZING BETA/GAMMA COINCIDENCE SIGNATURES AND ISOTOPICALLY PURIFIED NEUTRON ACTIVATED RADIOXENON ISOTOPES

    SciTech Connect (OSTI)

    McIntyre, Justin I.; Cooper, Matthew W.; Ely, James H.; Haas, Derek A.; Schrom, Brian T.

    2012-09-21T23:59:59.000Z

    Efforts to calibrate the absolute efficiency of gas cell radiations detectors have utilized a number of methodologies which allow adequate calibration but are time consuming and prone to a host of difficult-to-determine uncertainties. A method that extrapolates the total source strength from the measured beta and gamma gated beta coincidence signal was developed in the 1960’s and 1970’s. It has become clear that it is possible to achieve more consistent results across a range of isotopes and a range of activities using this method. Even more compelling is the ease with which this process can be used on routine samples to determine the total activity present in the detector. Additionally, recent advances in the generation of isotopically pure radioxenon samples of Xe-131m, Xe-133, and Xe-135 have allowed these measurement techniques to achieve much better results than would have been possible before when using mixed isotopic radioxenon source. This paper will discuss the beta/gamma absolute detection efficiency technique that utilizes several of the beta-gamma decay signatures to more precisely determine the beta and gamma efficiencies. It will than compare these results with other methods using pure sources of Xe-133, Xe-131m, and Xe-135 and a Xe-133/Xe-133m mix.

  19. Efficient Analysis of Mass Spectrometry Data Using the Isotope Wavelet

    SciTech Connect (OSTI)

    Hussong, Rene; Hildebrandt, Andreas [Center for Bioinformatics, Computer Science Department, Saarland University, 66041 Saarbruecken (Germany); Tholey, Andreas [Center for Bioinformatics, Institute of Biochemical Engineering, Functional Proteomics Group, Saarland University, 66041 Saarbruecken (Germany)

    2007-09-18T23:59:59.000Z

    Mass spectrometry (MS) has become today's de-facto standard for high-throughput analysis in proteomics research. Its applications range from toxicity analysis to MS-based diagnostics. Often, the time spent on the MS experiment itself is significantly less than the time necessary to interpret the measured signals, since the amount of data can easily exceed several gigabytes. In addition, automated analysis is hampered by baseline artifacts, chemical as well as electrical noise, and an irregular spacing of data points. Thus, filtering techniques originating from signal and image analysis are commonly employed to address these problems. Unfortunately, smoothing, base-line reduction, and in particular a resampling of data points can affect important characteristics of the experimental signal. To overcome these problems, we propose a new family of wavelet functions based on the isotope wavelet, which is hand-tailored for the analysis of mass spectrometry data. The resulting technique is theoretically well-founded and compares very well with standard peak picking tools, since it is highly robust against noise spoiling the data, but at the same time sufficiently sensitive to detect even low-abundant peptides.

  20. Comprehensive analysis of metabolic pathways through the combined use of multiple isotopic tracers

    E-Print Network [OSTI]

    Antoniewicz, Maciek Robert

    2006-01-01T23:59:59.000Z

    Metabolic Flux Analysis (MFA) has emerged as a tool of great significance for metabolic engineering and the analysis of human metabolic diseases. An important limitation of MFA, as carried out via stable isotope labeling ...

  1. Compound Specific Stable Nitrogen Isotope Analysis of Amino Acids: What can this Novel Technique tell us about

    E-Print Network [OSTI]

    Hawai'i at Manoa, University of

    enrichment #12;Novel tool: Compound specific nitrogen isotope analysis of amino acids (AA-CSIA) - ProteinsCompound Specific Stable Nitrogen Isotope Analysis of Amino Acids: What can this Novel Technique trophic models, but relationships often complex and dynamic #12;· Bulk tissue nitrogen isotope analysis

  2. Variations in the diet of introduced Norway rats (Rattus norvegicus) inferred using stable isotope analysis

    E-Print Network [OSTI]

    Jones, Ian L.

    Variations in the diet of introduced Norway rats (Rattus norvegicus) inferred using stable isotope predators; island ecosystem conservation; stable isotope analysis; Norway rats; diet. Correspondence Heather of introduced Norway rats Rattus norvegicus has raised concerns for the fate of the large least auklet Aethia

  3. High precision analysis of all four stable isotopes of sulfur S) at nanomole levels using a laser fluorination

    E-Print Network [OSTI]

    Long, Bernard

    compositions. This methodology increases the spatial resolution of the laser ablation in situ analysis) at nanomole levels using a laser fluorination isotope-ratio-monitoring gas chromatography­mass spectrometry.V. All rights reserved. Keywords: S-33; S-36; Sulfur isotope; Laser; Isotope analysis; Continuous flow

  4. Analysis Activities at Idaho National Engineering & Environmental...

    Broader source: Energy.gov (indexed) [DOE]

    Analysis Activities at Idaho National Engineering & Environmental Laboratory Analysis Activities at Idaho National Engineering & Environmental Laboratory Presentation on INEENL's...

  5. argon isotope analysis: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1.1 This is a quantitative test method applicable to determining the mass percent of uranium isotopes in uranium hexafluoride (UF6) samples with 235U concentrations between 0.1...

  6. Isotopic Analysis- Gas At Long Valley Caldera Geothermal Area...

    Open Energy Info (EERE)

    in a fumarole on the north side of Mammoth Mountain from 1989-1990, during which time helium isotope values increased from 3.6 x Ra to 5.5 x Ra from July to October 1989, and then...

  7. Isotopic Analysis- Gas At Long Valley Caldera Geothermal Area...

    Open Energy Info (EERE)

    in Menlo Park, CA. Gas samples collected in the copper tubes were analyzed for their helium isotope contents by B.M. Kennedy at the University of California at Berkeley, CA....

  8. Foraging Ecology of Green Turtles (Chelonia mydas) on the Texas Coast, as Determined by Stable Isotope Analysis

    E-Print Network [OSTI]

    Gorga, Catherine Concetta Theresa

    2011-10-21T23:59:59.000Z

    FORAGING ECOLOGY OF GREEN TURTLES (Chelonia mydas) ON THE TEXAS COAST, AS DETERMINED BY STABLE ISOTOPE ANALYSIS A Thesis by CATHERINE CONCETTA THERESA GORGA Submitted to the Office of Graduate Studies of Texas A&M University... Coast, as Determined by Stable Isotope Analysis Copyright 2010 Catherine Concetta Theresa Gorga FORAGING ECOLOGY OF GREEN TURTLES (Chelonia mydas) ON THE TEXAS COAST, AS DETERMINED BY STABLE ISOTOPE ANALYSIS A Thesis by CATHERINE...

  9. Activities of ?-ray emitting isotopes in rainwater from Greater Sudbury, Canada following the Fukushima incident

    E-Print Network [OSTI]

    B. T. Cleveland; F. A. Duncan; I. T. Lawson; N. J. T. Smith; E. Vazquez-Jauregui

    2012-02-29T23:59:59.000Z

    We report the activity measured in rainwater samples collected in the Greater Sudbury area of eastern Canada on 3, 16, 20, and 26 April 2011. The samples were gamma-ray counted in a germanium detector and the isotopes 131I and 137Cs, produced by the fission of 235U, and 134Cs, produced by neutron capture on 133Cs, were observed at elevated levels compared to a reference sample of ice-water. These elevated activities are ascribed to the accident at the Fukushima Dai-ichi nuclear reactor complex in Japan that followed the 11 March earthquake and tsunami. The activity levels observed at no time presented health concerns.

  10. SIMS ISOTOPIC ANALYSIS OF INTERPLANETARY DUST FROM SPACE-EXPOSED AEROGEL. F. J. Stadermann

    E-Print Network [OSTI]

    SIMS ISOTOPIC ANALYSIS OF INTERPLANETARY DUST FROM SPACE-EXPOSED AEROGEL. F. J. Stadermann 1: Aerogel is the medium of choice for the intact capture of small particles in space, because it is capable materials [1, 2]. After space-exposed aerogel is returned to the laboratory, the first step of analysis

  11. Characterization of Tank 48H Samples for Alpha Activity and Actinide Isotopics

    SciTech Connect (OSTI)

    Hobbs, D.T. [Westinghouse Savannah River Company, AIKEN, SC (United States); Coleman, C.J.; Hay, M.S.

    1995-12-04T23:59:59.000Z

    This document reports the total alpha activity and actinide isotopic results for samples taken from Tank 48H prior to the addition of sodium tetraphenylborate and MST in Batch {number_sign}1 of the ITP process. This information used to determine the quantity of MST for Batch {number_sign}1 of the ITP process and the total actinide content in the tank for dose calculations.

  12. alpha-active iridium isotopes: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CERN Preprints Summary: Currently, 31 actinium, 31 thorium, 28 protactinium, and 23 uranium isotopes have so far been observed; the discovery of these isotopes is discussed. For...

  13. Water Research 38 (2004) 25292536 The use of isotopic and lipid analysis techniques linking

    E-Print Network [OSTI]

    Alvarez, Pedro J.

    2004-01-01T23:59:59.000Z

    , ethylbenzene and xylenes (i.e., BTEX) are common ground water pollutants that threaten water suppliesWater Research 38 (2004) 2529­2536 The use of isotopic and lipid analysis techniques linking used recently as an environmental forensics tool to demonstrate microbial degradation of pollutants

  14. GRPAUT: a program for Pu isotopic analysis (a user's guide). ISPO task A. 76

    SciTech Connect (OSTI)

    Fleissner, J G

    1981-01-30T23:59:59.000Z

    GRPAUT is a modular program for performing automated Pu isotopic analysis supplied to the International Atomic Energy Agency (IAEA) per ISPO Task A.76. Section I of this user's guide for GRPAUT presents an overview of the various programs and disk files that are used in performing a Pu isotopic analysis. Section II describes the program GRFEDT which is used in creating and editing the analysis parameter file that contains all the spectroscopic information needed at runtime by GRPAUT. An example of the dialog and output of GRFEDT is shown in Appendix B. Section III describes the operation of the various GRPAUT modules: GRPNL2, the peak stripping module; EFFCH2, the efficiency calculation module; and ISOAUT, the isotopic calculation module. (A description of the peak fitting methodology employed by GRPNL2 is presented in Appendix A.) Finally, Section IV outlines the procedure for determining the peak shape constants for a detector system and describes the operation of the program used to create and edit the peak shape parameter files. An output of GRPAUT, showing an example of a complete isotopic analysis, is presented in Appendix C. Source listings of all the Fortran programs supplied to the Agency under ISPO Task A.76 are contained in Appendix E.

  15. Analysis of gas centrifuge cascade for separation of multicomponent isotopes and optimal feed position

    SciTech Connect (OSTI)

    Chuntong Ying; Hongjiang Wu; Mingsheng Zhou; Yuguang Nie; Guangjun Liu [Tsinghua Univ., Beijing (China)

    1997-10-01T23:59:59.000Z

    Analysis of the concentration distribution in a gas centrifuge cascade for separation of multicomponent isotope mixtures is different from that in a cascade for separation of two-component mixtures. This paper presents the governing equations for a multicomponent isotope separation cascade. Numerically predicted separation factors for the gas centrifuge cascade agree well with the experimental data. A theoretical optimal feed position is derived for a short square cascade for a two-component mixture in a close-separation case. The optimal feed position for a gas centrifuge cascade for separation of multicomponent mixture is discussed.

  16. Uranium Isotopic and Quantitative Analysis Using a Mechanically-Cooled HPGe Detector

    SciTech Connect (OSTI)

    Solodov, Alexander A [ORNL

    2008-01-01T23:59:59.000Z

    A new, portable high-resolution spectroscopy system based on a high-purity germanium detector cooled with a miniature Stirling-cycle cooler, ORTEC trans-SPEC, has recently become commercially available. The use of a long-life mechanical cooling system eliminates the need for liquid nitrogen. The purpose of this study was to determine the applicability of this new instrument for isotopic and quantitative analyses of uranium samples. The results of the performance of the trans-SPEC with the combination of PC-FRAM and ISOTOPIC software packages are described in this paper. An optimal set of analysis parameters for uranium measurements is proposed.

  17. Magnetically activated and guided isotope separation This article has been downloaded from IOPscience. Please scroll down to see the full text article.

    E-Print Network [OSTI]

    Raizen, Mark G.

    The world relies today on enriched isotopes for medicine, basic science and energy, and the need will only excitation, and similarly requires high-power lasers. A lower power laser isotope enrichment (LIE) methodMagnetically activated and guided isotope separation This article has been downloaded from

  18. Development of high through-put Sr isotope analysis for monitoring reservoir integrity for CO{sub 2} storage.

    SciTech Connect (OSTI)

    Wall, Andy; Jain, Jinesh; Stewart, Brian; Capo, Rosemary; Hakala, Alexandra J.; Hammack, Richard; Guthrie, George

    2012-01-01T23:59:59.000Z

    Recent innovations in multi-collector ICP-mass spectrometry (MC-ICP-MS) have allowed for rapid and precise measurements of isotope ratios in geological samples. Naturally occurring Sr isotopes has the potential for use in Monitoring, Verification, and Accounting (MVA) associated with geologic CO2 storage. Sr isotopes can be useful for: Sensitive tracking of brine migration; Determining seal rock leakage; Studying fluid/rock reactions. We have optimized separation chemistry procedures that will allow operators to prepare samples for Sr isotope analysis off site using rapid, low cost methods.

  19. Isotopic Analysis At Valles Caldera - Redondo Geothermal Area...

    Open Energy Info (EERE)

    White, Nancy J Chuma, Fraser E. Goff (1992) Mass Transfer Constraints On The Chemical Evolution Of An Active Hydrothermal System, Valles Caldera, New Mexico Additional References...

  20. Isotopic Analysis- Fluid At Valles Caldera - Sulphur Springs...

    Open Energy Info (EERE)

    White, Nancy J Chuma, Fraser E. Goff (1992) Mass Transfer Constraints On The Chemical Evolution Of An Active Hydrothermal System, Valles Caldera, New Mexico Additional References...

  1. Isotopic Analysis- Fluid At Valles Caldera - Redondo Geothermal...

    Open Energy Info (EERE)

    water for anions; 2) 125-mL filtered acidified water for cations; 3) a 500-mL glass bottle of unfiltered water for tritium analysis; 4) a 30-mL glass bottle of unfiltered...

  2. Analysis Activities at Pacific Northwest National Laboratory

    Broader source: Energy.gov [DOE]

    Presentation on PNNL’s analysis activities to the DOE Systems Analysis Workshop held in Washington, D.C. July 28-29, 2004.

  3. Analysis Activities at National Renewable Energy Laboratory

    Broader source: Energy.gov [DOE]

    Presentation on NREL’s analysis activities to the DOE Systems Analysis Workshop held in Washington, D.C. July 28-29, 2004.

  4. Analysis Activities at Lawrence Livermore National Laboratory

    Broader source: Energy.gov [DOE]

    Presentation on Lawrence Livermore’s analysis activities to the DOE Systems Analysis Workshop held in Washington, D.C. July 28-29, 2004.

  5. Analysis Activities at Sandia National Laboratory

    Broader source: Energy.gov [DOE]

    Presentation on SNL’s analysis activities to the DOE Systems Analysis Workshop held in Washington, D.C. July 28-29, 2004.

  6. Analysis Activities at Argonne National Laboratory

    Broader source: Energy.gov [DOE]

    Presentation on Argonne’s analysis activities to the DOE Systems Analysis Workshop held in Washington, D.C. July 28-29, 2004.

  7. Use of plutonium isotope activity ratios in dating recent sediments. [/sup 238/Pu//sup 239/Pu + /sup 240/Pu

    SciTech Connect (OSTI)

    Beasley, T. M.

    1982-01-01T23:59:59.000Z

    The majority of plutonium presently in the biosphere has come from the testing of nuclear devices. In the early 1950s, the Pu-238/239+240 activity ratio of fallout debris was > 0.04; in the more extensive test series of 1961 to 1962, the Pu-238/239+240 activity ratios were quite consistent at 0.02 to 0.03 and maximum fallout delivery occurred in mid-1963. A significant perturbation in Pu isotope activity ratios occurred in mid-1966 with the deposition of Pu-238 from the SNAP-9A reentry and burn-up. Recently deposited sediments have recorded these events and where accumulation rates are rapid (> 1 cm/y), changes in Pu isotope activity ratios can be used as a geochronological tool.

  8. Analysis and results of a hydrogen moderated isotope production assembly in the Fast Flux Test Facility

    SciTech Connect (OSTI)

    Wootan, D.W.; Rawlins, J.A.; Carter, L.L.; Brager, H.R.; Schenter, R.E.

    1988-06-01T23:59:59.000Z

    A cobalt test assembly containing yttrium hydride pins for neutron moderation was irradiated in the Fast Flux Test Facility during Cycle 9A for 137.7 equivalent full-power days at a power level of 291 MW. The 36 test pins consisted of a batch of 32 pins containing cobalt metal used to produce /sup 60/Co and a set of four pins with europium oxide to produce /sup 153/Gd, a radioisotope used in detection of the bone disease osteoporosis. Postirradiation examination of the cobalt pins determined the /sup 60/Co was produced with an accuracy of about 5%. The measured /sup 60/Co spatially distributed concentrations were within 20% of the calculated concentrations. The assembly average /sup 60/Co measured activity was 4% less than the calculated value. The europium oxide pins were gamma scanned for the europium isotopes /sup 152/Eu and /sup 154/Eu to an absolute accuracy of about 10%. The measured europium radioisotope and /sup 153/Gd concentrations were within 20% of calculated values. The hydride assembly performed well and is an excellent vehicle for many Fast Flux Test Facility isotope production applications. The results also demonstrate the accuracy of the calculational methods developed by the Westinghouse Hanford Company for predicting isotope production rates in this type of assembly. 4 refs., 5 figs., 2 tabs.

  9. Determination of thorium in seawater by neutron activation analysis and mass spectrometry

    SciTech Connect (OSTI)

    Huh, Chih-An

    1987-01-01T23:59:59.000Z

    The recent development of neutron activation analysis and mass spectrometric methods for the determination of /sup 232/Th in seawater has made possible rapid sampling and analysis of this long-lived, non-radiogenic thorium isotope on small-volume samples. The marine geochemical utility of /sup 232/Th, whose concentration in seawater is extremely low, warrants the development of these sensitive techniques. The analytical methods and some results are presented and discussed in this article. 24 refs., 3 figs.

  10. TPASS: a gamma-ray spectrum analysis and isotope identification computer code

    SciTech Connect (OSTI)

    Dickens, J.K.

    1981-03-01T23:59:59.000Z

    The gamma-ray spectral data-reduction and analysis computer code TPASS is described. This computer code is used to analyze complex Ge(Li) gamma-ray spectra to obtain peak areas corrected for detector efficiencies, from which are determined gamma-ray yields. These yields are compared with an isotope gamma-ray data file to determine the contributions to the observed spectrum from decay of specific radionuclides. A complete FORTRAN listing of the code and a complex test case are given.

  11. Activities of \\gamma-ray emitting isotopes in rainwater from Greater Sudbury, Canada following the Fukushima incident

    E-Print Network [OSTI]

    Cleveland, B T; Lawson, I T; Smith, N J T; Vazquez-Jauregui, E

    2012-01-01T23:59:59.000Z

    We report the activity measured in rainwater samples collected in the Greater Sudbury area of eastern Canada on 3, 16, 20, and 26 April 2011. The samples were gamma-ray counted in a germanium detector and the isotopes 131I and 137Cs, produced by the fission of 235U, and 134Cs, produced by neutron capture on 133Cs, were observed at elevated levels compared to a reference sample of ice-water. These elevated activities are ascribed to the accident at the Fukushima Dai-ichi nuclear reactor complex in Japan that followed the 11 March earthquake and tsunami. The activity levels observed at no time presented health concerns.

  12. Partial Safety Analysis for a Reduced Uranium Enrichment Core for the High Flux Isotope Reactor

    SciTech Connect (OSTI)

    Primm, Trent [ORNL; Gehin, Jess C [ORNL

    2009-04-01T23:59:59.000Z

    A computational model of the reactor core of the High Flux Isotope Rector (HFIR) was developed in order to analyze non-destructive accidents caused by transients during reactor operation. The reactor model was built for the latest version of the nuclear analysis software package called Program for the Analysis of Reactor Transients (PARET). Analyses performed with the model constructed were compared with previous data obtained with other tools in order to benchmark the code. Finally, the model was used to analyze the behavior of the reactor under transients using a different nuclear fuel with lower enrichment of uranium (LEU) than the fuel currently used, which has a high enrichment of uranium (HEU). The study shows that the presence of fertile isotopes in LEU fuel, which increases the neutron resonance absorption, reduces the impact of transients on the fuel and enhances the negative reactivity feedback, thus, within the limitations of this study, making LEU fuel appear to be a safe alternative fuel for the reactor core.

  13. ANALYSIS OF RICIN TOXIN PREPARATIONS FOR CARBOHYDRATE AND FATTY ACID ABUNDANCE AND ISOTOPE RATIO INFORMATION

    SciTech Connect (OSTI)

    Wunschel, David S.; Kreuzer-Martin, Helen W.; Antolick, Kathryn C.; Colburn, Heather A.; Moran, James J.; Melville, Angela M.

    2009-12-01T23:59:59.000Z

    This report describes method development and preliminary evaluation for analyzing castor samples for signatures of purifying ricin. Ricin purification from the source castor seeds is essentially a problem of protein purification using common biochemical methods. Indications of protein purification will likely manifest themselves as removal of the non-protein fractions of the seed. Two major, non-protein, types of biochemical constituents in the seed are the castor oil and various carbohydrates. The oil comprises roughly half the seed weight while the carbohydrate component comprises roughly half of the remaining “mash” left after oil and hull removal. Different castor oil and carbohydrate components can serve as indicators of specific toxin processing steps. Ricinoleic acid is a relatively unique fatty acid in nature and is the most abundant component of castor oil. The loss of ricinoleic acid indicates a step to remove oil from the seeds. The relative amounts of carbohydrates and carbohydrate-like compounds, including arabinose, xylose, myo-inositol fucose, rhamnose, glucosamine and mannose detected in the sample can also indicate specific processing steps. For instance, the differential loss of arabinose relative to mannose and N-acetyl glucosamine indicates enrichment for the protein fraction of the seed using protein precipitation. The methods developed in this project center on fatty acid and carbohydrate extraction from castor samples followed by derivatization to permit analysis by gas chromatography-mass spectrometry (GC-MS). Method descriptions herein include: the source and preparation of castor materials used for method evaluation, the equipment and description of procedure required for chemical derivatization, and the instrument parameters used in the analysis. Two types of derivatization methods describe analysis of carbohydrates and one procedure for analysis of fatty acids. Two types of GC-MS analysis is included in the method development, one employing a quadrupole MS system for compound identification and an isotope ratio MS for measuring the stable isotope ratios of deuterium and hydrogen (D/H) in fatty acids. Finally, the method for analyzing the compound abundance data is included. This study indicates that removal of ricinoleic acid is a conserved consequence of each processing step we tested. Furthermore, the stable isotope D/H ratio of ricinoleic acid distinguished between two of the three castor seed sources. Concentrations of arabinose, xylose, mannose, glucosamine and myo-inositol differentiated between crude or acetone extracted samples and samples produced by protein precipitation. Taken together these data illustrate the ability to distinguish between processes used to purify a ricin sample as well as potentially the source seeds.

  14. Stable nitrogen isotope measurements of marine bacterial proteins and nucleic acids: tracers of microbial activity

    E-Print Network [OSTI]

    Kovacs, Jeffrey Paul

    1996-01-01T23:59:59.000Z

    Stable nitrogen isotopes ([]15N) can trace elemental cycling in aquatic ecosystems if the enzyme mediated fractionations associated with nutrient uptake and assimilation are negligible or consistently predictable. In this study, bacterial proteins...

  15. Using phylogenetic probes for quantification of stable isotope labeling and microbial community analysis

    DOE Patents [OSTI]

    Brodie, Eoin L; DeSantis, Todd Z; Karaoz, Ulas; Andersen, Gary L

    2014-12-09T23:59:59.000Z

    Herein is described methods for a high-sensitivity means to measure the incorporation of stable isotope labeled substrates into RNA following stable isotope probing experiments (SIP). RNA is hybridized to a set of probes such as phylogenetic microarrays and isotope incorporation is quantified such as by secondary ion mass spectrometer imaging (NanoSIMS).

  16. Deterioration of plutonium isotopic analysis with neurtron damage to HPGe detectors

    SciTech Connect (OSTI)

    Koenig, Z.M.; Gunnink, R.; Ruhter, W.D.; Camp, D.C.

    1991-09-01T23:59:59.000Z

    The effects of neutron (n) damage on HPGe detectors used to measure Pu isotopic ratios were investigated. Both a p-type planar and an n-type coaxial detector were progressively neutron damaged up to a total integrated flux of >5{times}10{sup 9} n/cm{sup 2} from a {sup 252}Cf source. Severe deterioration of selected peak shapes and degradation in the Pu isotopic analysis capability were observed and quantified by using the GRPANL and MGA codes developed at LLNL. After an integrated exposure of 1{times}10{sup 9} n/cm{sup 2} the Pu spectrum from the coaxial detector could not be analyzed with MGA. The planar detector spectrum continued to be analyzable with MGA up to 4{times}10{sup 9} n/cm{sup 2}. Cooling the planar detector to 80 K with an electrically-cooled cryostat could extent its useful lifetime up to an exposure of 2{times}10{sup 10} n/cm{sup 2}. 11 refs., 7 figs. , 1 tab.

  17. Transportation activity analysis using smartphones

    E-Print Network [OSTI]

    Xiao, Yu

    Transportation activity surveys investigate when, where and how people travel in urban areas to provide information necessary for urban transportation planning. In Singapore, the Land Transport Authority (LTA) carries out ...

  18. Analysis & Design of Active Inductor

    E-Print Network [OSTI]

    Rana, Dibyendu

    2014-03-05T23:59:59.000Z

    Inductor DC bus voltage capped at 800 V by bleeder resistor .......... 59 Figure 39: Circuit diagram for experimental setup ........................................................ 60 Figure 40: Experimental setup for 200 W, three phase diode rectifier... ................................................................................. 79 Figure 57: Thyristor based CSI with Active Inductor emulating the reactor ................. 80 Figure 58: Relative core losses at 20 kHz. Reprinted with permission from [58] ......... 86 Figure 59: Nanocrystalline core (Vitoperm) core loss...

  19. Isotope Enrichment Detection by Laser Ablation - Laser Absorption Spectrometry: Automated Environmental Sampling and Laser-Based Analysis for HEU Detection

    SciTech Connect (OSTI)

    Anheier, Norman C.; Bushaw, Bruce A.

    2010-01-01T23:59:59.000Z

    The global expansion of nuclear power, and consequently the uranium enrichment industry, requires the development of new safeguards technology to mitigate proliferation risks. Current enrichment monitoring instruments exist that provide only yes/no detection of highly enriched uranium (HEU) production. More accurate accountancy measurements are typically restricted to gamma-ray and weight measurements taken in cylinder storage yards. Analysis of environmental and cylinder content samples have much higher effectiveness, but this approach requires onsite sampling, shipping, and time-consuming laboratory analysis and reporting. Given that large modern gaseous centrifuge enrichment plants (GCEPs) can quickly produce a significant quantity (SQ ) of HEU, these limitations in verification suggest the need for more timely detection of potential facility misuse. The Pacific Northwest National Laboratory (PNNL) is developing an unattended safeguards instrument concept, combining continuous aerosol particulate collection with uranium isotope assay, to provide timely analysis of enrichment levels within low enriched uranium facilities. This approach is based on laser vaporization of aerosol particulate samples, followed by wavelength tuned laser diode spectroscopy to characterize the uranium isotopic ratio through subtle differences in atomic absorption wavelengths. Environmental sampling (ES) media from an integrated aerosol collector is introduced into a small, reduced pressure chamber, where a focused pulsed laser vaporizes material from a 10 to 20-µm diameter spot of the surface of the sampling media. The plume of ejected material begins as high-temperature plasma that yields ions and atoms, as well as molecules and molecular ions. We concentrate on the plume of atomic vapor that remains after the plasma has expanded and then cooled by the surrounding cover gas. Tunable diode lasers are directed through this plume and each isotope is detected by monitoring absorbance signals on a shot-to-shot basis. The media is translated by a micron resolution scanning system, allowing the isotope analysis to cover the entire sample surface. We also report, to the best of our knowledge, the first demonstration of laser-based isotopic measurements on individual micron-sized particles that are minor target components in a much larger heterogeneous mix of ‘background’ particles. This composition is consistent with swipe and environmental aerosol samples typically collected for safeguards ES purposes. Single-shot detection sensitivity approaching the femtogram range and relative isotope abundance uncertainty better than 10% has been demonstrated using gadolinium isotopes as surrogate materials.

  20. Soraya Boudia, Radioisotopes "economy of promises : On the limits of biomedicine in public legitimization of nuclear activities" in X. Roqu et N. Herran(eds), Isotopes: Science, Medicine

    E-Print Network [OSTI]

    Boyer, Edmond

    in public legitimization of nuclear activities" in X. Roqué et N. Herran(eds), Isotopes: Science, Medicine": On the limits of biomedicine in public legitimization of nuclear activities Soraya Boudia 7 rue de l and the fall of biomedicine in the public legitimization of the development of nuclear energy. Until the late

  1. Standard Test Method for Isotopic Analysis of Uranium Hexafluoride by Single-Standard Gas Source Multiple Collector Mass Spectrometer Method

    E-Print Network [OSTI]

    American Society for Testing and Materials. Philadelphia

    2011-01-01T23:59:59.000Z

    1.1 This test method is applicable to the isotopic analysis of uranium hexafluoride (UF6) with 235U concentrations less than or equal to 5 % and 234U, 236U concentrations of 0.0002 to 0.1 %. 1.2 This test method may be applicable to the analysis of the entire range of 235U isotopic compositions providing that adequate Certified Reference Materials (CRMs or traceable standards) are available. 1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety health practices and determine the applicability of regulatory limitations prior to use.

  2. Analysis of the ecology of Anchialine Caves using carbon and nitrogen stable isotopes

    E-Print Network [OSTI]

    Pohlman, John William

    1995-01-01T23:59:59.000Z

    Carbon and nitrogen stable isotopes were used to investigate the biogeochemical and ecological processes that govern anchialine cave ecosystems in the Yucatan Peninsula, Quintana Roo, Mexico. Anchialine caves are subterranean passages...

  3. An informatics based analysis of the impact of isotope substitution on phonon modes in graphene

    SciTech Connect (OSTI)

    Broderick, Scott; Srinivasan, Srikant; Rajan, Krishna [Department of Material Science and Engineering, Iowa State University, Ames, Iowa 50011 (United States); Ray, Upamanyu; Balasubramanian, Ganesh, E-mail: bganesh@iastate.edu [Department of Mechanical Engineering, Iowa State University, Ames, Iowa 50011 (United States)

    2014-06-16T23:59:59.000Z

    It is shown by informatics that the high frequency short ranged modes exert a significant influence in impeding thermal transport through isotope substituted graphene nanoribbons. Using eigenvalue decomposition methods, we have extracted features in the phonon density of states spectra that reveal correlations between isotope substitution and phonon modes. This study also provides a data driven computational framework for the linking of materials chemistry and transport properties in 2D systems.

  4. Stable Isotope Analysis of a Middle Woodland Population from North Central Kansas

    E-Print Network [OSTI]

    Kauffman, Greg

    2013-08-31T23:59:59.000Z

    ; Kortschak et al. 1965; Thomas 1951) and their corresponding stable isotope value ranges (Craig 1953; Sackett and Thompson 1963; Wickman 1952). Following this discovery, Hall (1967) first recognized that high carbon isotope values in maize and other grasses... would have been around -5‰ to -6‰; slightly higher without the contribution of carbon from fossil fuels. Today’s value is approximately -7‰ (Keeling 1961; Bada et al 1990; Marino and McElroy 1991; Schoeninger and Moore 1992). Malainey (2011:178) places...

  5. Isotopic Analysis of Uranium in NIST SRM Glass by Femtosecond Laser Ablation

    SciTech Connect (OSTI)

    Duffin, Andrew M.; Hart, Garret L.; Hanlen, Richard C.; Eiden, Gregory C.

    2013-05-19T23:59:59.000Z

    We employed femtosecond Laser Ablation Multicollector Inductively Coupled Mass Spectrometry for the 11 determination of uranium isotope ratios in a series of standard reference material glasses (NIST 610, 612, 614, and 12 616). This uranium concentration in this series of SRM glasses is a combination of isotopically natural uranium in 13 the materials used to make the glass matrix and isotopically depleted uranium added to increase the uranium 14 elemental concentration across the series. Results for NIST 610 are in excellent agreement with literature values. 15 However, other than atom percent 235U, little information is available for the remaining glasses. We present atom 16 percent and isotope ratios for 234U, 235U, 236U, and 238U for all four glasses. Our results show deviations from the 17 certificate values for the atom percent 235U, indicating the need for further examination of the uranium isotopes in 18 NIST 610-616. Our results are fully consistent with a two isotopic component mixing between the depleted 19 uranium spike and natural uranium in the bulk glass.

  6. Analysis and results of a hydrogen-moderated isotope production assembly in the Fast Flux Test Facility

    SciTech Connect (OSTI)

    Wootan, D.W.; Rawlins, J.A.; Carter, L.L.; Brager, H.R.; Schenter, R.E. (Westinghouse Hanford Co., Richland, WA (USA))

    1989-10-01T23:59:59.000Z

    This paper reports on a cobalt test assembly containing yttrium hydride pins for neutron moderation irradiated in the Fast Flux Test Facility (FFTF) during cycle 9A for 137.7 equivalent full-power days at a power level of 291 MW. The 36 test pins consisted of a batch of 32 pins containing cobalt metal used to produce {sup 60}Co and a set of four pins with europium oxide to produce {sup 153}Gd, a radioisotope used in detection of the bone disease osteoporosis. Postirradiation examination of the cobalt pins determined the {sup 60}Co production to be predictable to an accuracy of {approximately} 5%. The measured {sup 60}Co spatially distributed concentrations were within 20% of the calculated concentrations. The assembly average {sup 60}Co measured activity was 4% less than the calculated value. The europium oxide pins were gamma scanned for the europium isotopes {sup 152}Eu and {sup 154}Eu to an absolute accuracy of {approx equal} 10%. The measured europium radioisotope and {sup 153}Gd concentrations were within 20% of calculated values. The hydride assembly performed well and is an excellent vehicle for many FFTF isotope production applications. The results also demonstrate the accuracy of the calculational methods developed by the Westinghouse Hanford Company for predicting isotope production rates in this type of assembly.

  7. Standard test method for isotopic analysis of uranium hexafluoride by double standard single-collector gas mass spectrometer method

    E-Print Network [OSTI]

    American Society for Testing and Materials. Philadelphia

    2010-01-01T23:59:59.000Z

    1.1 This is a quantitative test method applicable to determining the mass percent of uranium isotopes in uranium hexafluoride (UF6) samples with 235U concentrations between 0.1 and 5.0 mass %. 1.2 This test method may be applicable for the entire range of 235U concentrations for which adequate standards are available. 1.3 This test method is for analysis by a gas magnetic sector mass spectrometer with a single collector using interpolation to determine the isotopic concentration of an unknown sample between two characterized UF6 standards. 1.4 This test method is to replace the existing test method currently published in Test Methods C761 and is used in the nuclear fuel cycle for UF6 isotopic analyses. 1.5 The values stated in SI units are to be regarded as standard. No other units of measurement are included in this standard. 1.6 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appro...

  8. Compound and Elemental Analysis At Long Valley Caldera Geothermal...

    Open Energy Info (EERE)

    Compound and Elemental Analysis Activity Date - 2002 Usefulness not indicated DOE-funding Unknown Notes "Detailed chemical and isotopic studies not only help quantify the...

  9. Analysis of Integrated Safety Management at the Activity Level...

    Broader source: Energy.gov (indexed) [DOE]

    Integrated Safety Management at the Activity Level: Work Planning and Control, Final Report Analysis of Integrated Safety Management at the Activity Level: Work Planning and...

  10. Analysis Activities at Fossil Energy/ National Energy Technology Laboratory

    Broader source: Energy.gov [DOE]

    Presentation on NETL’s analysis activities to the DOE Systems Analysis Workshop held in Washington, D.C. July 28-29, 2004.

  11. Organic Matter Analysis of Sediments from Simpson Bay, Alaska using Elemental, Stable Isotopic, and Molecular Signatures

    E-Print Network [OSTI]

    Pondell, Christina

    2008-08-19T23:59:59.000Z

    profiles for lignin-derived biomarkers and stable carbon isotopes imply that the earthquake events did not disrupt the drainage basin of Simpson Bay enough to change the signatures of the organic matter deposited shortly after these occurrences. The OC, C...

  12. The analysis of the pantothenate synthetase reaction by positional isotope exchange 

    E-Print Network [OSTI]

    Williams, Lakenya Flatreese

    2003-01-01T23:59:59.000Z

    positional isotope exchange (PIX) reaction within ą?O-labeled ATP in the presence of D-pantoate. When [??-ą?O?]-ATP was incubated with pantothenate synthetase in the presence of D-pantoate, an ą?O label gradually appeared in the ??-bridge position from both...

  13. Low-Enriched Uranium Fuel Conversion Activities for the High Flux Isotope Reactor, Annual Report for FY 2011

    SciTech Connect (OSTI)

    Renfro, David G [ORNL; Cook, David Howard [ORNL; Freels, James D [ORNL; Griffin, Frederick P [ORNL; Ilas, Germina [ORNL; Sease, John D [ORNL; Chandler, David [ORNL

    2012-03-01T23:59:59.000Z

    This report describes progress made during FY11 in ORNL activities to support converting the High Flux Isotope Reactor (HFIR) from high-enriched uranium (HEU) fuel to low-enriched uranium (LEU) fuel. Conversion from HEU to LEU will require a change in fuel form from uranium oxide to a uranium-molybdenum (UMo) alloy. With both radial and axial contouring of the fuel foil and an increase in reactor power to 100 MW, calculations indicate that the HFIR can be operated with LEU fuel with no degradation in performance to users from the current levels achieved with HEU fuel. Studies are continuing to demonstrate that the fuel thermal safety margins can be preserved following conversion. Studies are also continuing to update other aspects of the reactor steady state operation and accident response for the effects of fuel conversion. Technical input has been provided to Oregon State University in support of their hydraulic testing program. The HFIR conversion schedule was revised and provided to the GTRI program. In addition to HFIR conversion activities, technical support was provided directly to the Fuel Fabrication Capability program manager.

  14. Neutron activation analysis applied to perspiration electrolytes

    E-Print Network [OSTI]

    McAndrew, Robert Gavin

    1969-01-01T23:59:59.000Z

    . In the choice of the polyethylene sheeting used, nine commercial polyethylene sheets or bags were analyzed for their sodium content by neutron activation analysis. A small sax:. .pie of each material was weighed and then irradiated in the reactor for one... 3. 46 3. 76 4. 2 1. 15 1. 16 . 59 1. 19 1. 82 1. 89 1. 50 . 54 1. 88 . 74 1. 20 1. 29 43 which were irradiated unshielded by cadmium in the center tube of the reactor where the fast neutron flux was much greater than at the reactor...

  15. Active Automobile Engine Vibration Analysis Technical Report Number 1

    E-Print Network [OSTI]

    Levi, Anthony F. J.

    Active Automobile Engine Vibration Analysis Technical Report Number 1 Page 1 of 26 DISTRIBUTION STATEMENT: Distribution authorized to all. Active Automobile Engine Vibration Analysis Technical Report at the University of Southern California #12;Active Automobile Engine Vibration Analysis Technical Report Number 1

  16. Application of copper vapour lasers for controlling activity of uranium isotopes

    SciTech Connect (OSTI)

    Barmina, E V; Sukhov, I A; Lepekhin, N M; Priseko, Yu S; Filippov, V G; Simakin, Aleksandr V; Shafeev, Georgii A

    2013-06-30T23:59:59.000Z

    Beryllium nanoparticles are generated upon ablation of a beryllium target in water by a copper vapour laser. The average size of single crystalline nanoparticles is 12 nm. Ablation of a beryllium target in aqueous solutions of uranyl chloride leads to a significant (up to 50 %) decrease in the gamma activity of radionuclides of the uranium-238 and uranium-235 series. Data on the recovery of the gamma activity of these nuclides to new steady-state values after laser irradiation are obtained. The possibility of application of copper vapour lasers for radioactive waste deactivation is discussed. (laser applications and other topics in quantum electronics)

  17. HETEROGENEOUS ISOTOPIC ANOMALIES OF SM AND GD IN THE NORTON COUNTY METEORITE: EVIDENCE FOR IRRADIATION FROM THE ACTIVE EARLY SUN

    SciTech Connect (OSTI)

    Hidaka, Hiroshi; Kondo, Tomoyo [Department of Earth and Planetary Systems Science, Hiroshima University, Higashi-Hiroshima 739-8526 (Japan); Yoneda, Shigekazu, E-mail: hidaka@hiroshima-u.ac.jp [Department of Science and Engineering, National Museum of Nature and Science, Tokyo 169-0073 (Japan)

    2012-02-20T23:59:59.000Z

    Large and heterogeneous isotopic variations of {sup 150}Sm/{sup 149}Sm and {sup 158}Gd/{sup 157}Gd due to neutron capture reactions caused by cosmic-ray irradiation were found in chemical and mineral separates from the Norton County meteorite. The light-colored separates, consisting mainly of enstatite (Mg{sub 2}Si{sub 2}O{sub 6}), have a very large neutron fluence of 1.98 Multiplication-Sign 10{sup 17} n cm{sup -2}, which is 10 times higher than that of the whole rock. Furthermore, four chemical separates showed a large variation in neutron fluences, ranging from 1.82 Multiplication-Sign 10{sup 16} to 1.87 Multiplication-Sign 10{sup 17} n cm{sup -2}. The variable amounts of neutron fluences from a small single fragment of the Norton County meteorite cannot be simply explained by single-stage cosmic-ray irradiation in space. Rare earth element (REE) analyses revealed that the fractions with high neutron fluences have similar chemical properties to those in the early condensates in the solar system, showing depletions of Eu and Yb in their REE abundance patterns. The data provide evidence for an activity of the early Sun (T Tauri), suggesting the migration of early and intense irradiation materials into the Norton County meteorite's parent body.

  18. Neutronic Analysis of an Advanced Fuel Design Concept for the High Flux Isotope Reactor

    SciTech Connect (OSTI)

    Xoubi, Ned [ORNL; Primm, Trent [ORNL; Maldonado, G. Ivan [University of Tennessee, Knoxville (UTK)

    2009-01-01T23:59:59.000Z

    This study presents the neutronic analysis of an advanced fuel design concept for the Oak Ridge National Laboratory (ORNL) High Flux Isotope Reactor (HFIR) that could significantly extend the current fuel cycle length under the existing design and safety criteria. A key advantage of the fuel design herein proposed is that it would not require structural changes to the present HFIR core, in other words, maintaining the same rated power and fuel geometry (i.e., fuel plate thickness and coolant channel dimensions). Of particular practical importance, as well, is the fact that the proposed change could be justified within the bounds of the existing nuclear safety basis. The simulations herein reported employed transport theory-based and exposure-dependent eigenvalue characterization to help improve the prediction of key fuel cycle parameters. These parameters were estimated by coupling a benchmarked three-dimensional MCNP5 model of the HFIR core to the depletion code ORIGEN via the MONTEBURNS interface. The design of an advanced HFIR core with an improved fuel loading is an idea that evolved from early studies by R. D. Cheverton, formerly of ORNL. This study contrasts a modified and increased core loading of 12 kg of 235U against the current core loading of 9.4 kg. The simulations performed predict a cycle length of 39 days for the proposed fuel design, which represents a 50% increase in the cycle length in response to a 25% increase in fissile loading, with an average fuel burnup increase of {approx}23%. The results suggest that the excess reactivity can be controlled with the present design and arrangement of control elements throughout the core's life. Also, the new power distribution is comparable or even improved relative to the current power distribution, displaying lower peak to average fission rate densities across the inner fuel element's centerline and bottom cells. In fact, the fission rate density in the outer fuel element also decreased at these key locations for the proposed design. Overall, it is estimated that the advanced core design could increase the availability of the HFIR facility by {approx}50% and generate {approx}33% more neutrons annually, which is expected to yield sizeable savings during the remaining life of HFIR, currently expected to operate through 2014. This study emphasizes the neutronics evaluation of a new fuel design. Although a number of other performance parameters of the proposed design check favorably against the current design, and most of the core design features remain identical to the reference, it is acknowledged that additional evaluations would be required to fully justify the thermal-hydraulic and thermal-mechanical performance of a new fuel design, including checks for cladding corrosion performance as well as for industrial and economic feasibility.

  19. Identification of the source of methane at a hazardous waste treatment facility using isotopic analysis

    SciTech Connect (OSTI)

    Hackley, K.C.; Liu, C.L. (Illinois State Geological Survey, Peabody, IL (United States)); Trainor, D.P. (Dames and Moore, Madison, WI (United States))

    1992-01-01T23:59:59.000Z

    Isotopic analyses have been used to determine the source of methane in subsurface sediments at a hazardous waste treatment facility in the Lake Calumet area of Chicago, Illinois. The study area is surrounded by landfills and other waste management operations and has a long history of waste disposal. The facility property consists of land constructed of approximately 15 feet of fill placed over lake sediments. The fill is underlain by successively older lacustrine and glacial till deposits to a maximum depth of approximately 80 feet. During a subsurface investigation of the site performed for a RCRA Facility Investigation of former solid waste management units (SWMUs) in the fill, significant quantities of methane were encountered in the natural deposits. Gas samples were collected from the headspace of 11 piezometers screened at depths of approximately 30, 40, and 50 feet beneath the surface. Methane concentrations up to 75% by volume were observed in some of the piezometers. Stable isotope analyses were completed on methane and associated CO[sub 2] separated from the gas samples. Radiocarbon (C-14) analyses were also completed on several of the samples. The delta C-13 results for the intermediate and deep zones are indicative of methane produced by microbial reduction of CO[sub 2]. The methane occurring in the shallow zone appears to be a mixture of methane from the intermediate zone and methane produced by microbial fermentation of naturally (nonanthropogenic) buried organic matter within the shallow lacustrine sediments. According to the isotopic and chemical results, the methane does not appear to be related to gas generation from nearby landfills or from organic wastes previously placed in the former facility SWMUs.

  20. The experimental and theoretical determination of combinatorial kinetic isotope effects for mechanistic analysis

    E-Print Network [OSTI]

    Christian, Chad F.

    2009-05-15T23:59:59.000Z

    in the ZPE of the reacting isotopomers as a reaction proceeds from starting material to the transition state ....................................................................... 3 1-2 Illustrates the relationship between the isotopic ratio, R/R 0... on the vibrational frequencies. k m ? = 1 2? (1-4) The quantum-mechanical treatment of the frequencies for the vibrational modes leads to the energy, E, in eq 1-5. (1-5) E = h?(n + 1/2) n = 0, 1, 2, ..... This energy is measured from the lowest...

  1. Analysis of Elemental and Isotopic Composition of a Substance Obtained in Experiments on Energy Concentration in a Solid-State Superdense Plasma

    E-Print Network [OSTI]

    S. V. Adamenko; A. S. Adamenko

    2003-04-23T23:59:59.000Z

    We present the results of the experimental study on synthesis of a wide range of isotopes in a superdense plasma. The initial conditions necessary for plasma bunch formation were provided by specially organized coherent impact on a solid target with a total energy up to 1 kJ. More than 4000 shots were performed with various targets made of light, medium, and heavy elements. Subsequent analysis of the products of the target explosion reveals the presence of a wide range of elements absent in the initial materials. Elements with nuclei three and more times heavier than the nucleus of the target main element are detected in the products. The isotopic composition of the produced elements significantly differs from the natural one. The presence of unknown superheavy elements at the border of the periodic table and beyond it was detected by several different spectroscopic methods of elemental and isotopic analyzes.

  2. GADRAS isotope ID users manual for analysis of gamma-ray measurements and API for Linux and Android .

    SciTech Connect (OSTI)

    Mitchell, Dean J; Harding, Lee T.

    2014-05-01T23:59:59.000Z

    Isotope identification algorithms that are contained in the Gamma Detector Response and Analysis Software (GADRAS) can be used for real-time stationary measurement and search applications on platforms operating under Linux or Android operating sys-tems. Since the background radiation can vary considerably due to variations in natu-rally-occurring radioactive materials (NORM), spectral algorithms can be substantial-ly more sensitive to threat materials than search algorithms based strictly on count rate. Specific isotopes or interest can be designated for the search algorithm, which permits suppression of alarms for non-threatening sources, such as such as medical radionuclides. The same isotope identification algorithms that are used for search ap-plications can also be used to process static measurements. The isotope identification algorithms follow the same protocols as those used by the Windows version of GADRAS, so files that are created under the Windows interface can be copied direct-ly to processors on fielded sensors. The analysis algorithms contain provisions for gain adjustment and energy lineariza-tion, which enables direct processing of spectra as they are recorded by multichannel analyzers. Gain compensation is performed by utilizing photopeaks in background spectra. Incorporation of this energy calibration tasks into the analysis algorithm also eliminates one of the more difficult challenges associated with development of radia-tion detection equipment.

  3. Non destructive multi elemental analysis using prompt gamma neutron activation analysis techniques: Preliminary results for concrete sample

    SciTech Connect (OSTI)

    Dahing, Lahasen Normanshah [School of Applied Physics, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor, Malaysia and Malaysian Nuclear Agency (Nuklear Malaysia), Bangi 43000, Kajang (Malaysia); Yahya, Redzuan [School of Applied Physics, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor (Malaysia); Yahya, Roslan; Hassan, Hearie [Malaysian Nuclear Agency (Nuklear Malaysia), Bangi 43000, Kajang (Malaysia)

    2014-09-03T23:59:59.000Z

    In this study, principle of prompt gamma neutron activation analysis has been used as a technique to determine the elements in the sample. The system consists of collimated isotopic neutron source, Cf-252 with HPGe detector and Multichannel Analysis (MCA). Concrete with size of 10×10×10 cm{sup 3} and 15×15×15 cm{sup 3} were analysed as sample. When neutrons enter and interact with elements in the concrete, the neutron capture reaction will occur and produce characteristic prompt gamma ray of the elements. The preliminary result of this study demonstrate the major element in the concrete was determined such as Si, Mg, Ca, Al, Fe and H as well as others element, such as Cl by analysis the gamma ray lines respectively. The results obtained were compared with NAA and XRF techniques as a part of reference and validation. The potential and the capability of neutron induced prompt gamma as tool for multi elemental analysis qualitatively to identify the elements present in the concrete sample discussed.

  4. Analysis of Experimental Data for High Burnup PWR Spent Fuel Isotopic Validation - Vandellos II Reactor

    SciTech Connect (OSTI)

    Ilas, Germina [ORNL; Gauld, Ian C [ORNL

    2011-01-01T23:59:59.000Z

    This report is one of the several recent NUREG/CR reports documenting benchmark-quality radiochemical assay data and the use of the data to validate computer code predictions of isotopic composition for spent nuclear fuel, to establish the uncertainty and bias associated with code predictions. The experimental data analyzed in the current report were acquired from a high-burnup fuel program coordinated by Spanish organizations. The measurements included extensive actinide and fission product data of importance to spent fuel safety applications, including burnup credit, decay heat, and radiation source terms. Six unique spent fuel samples from three uranium oxide fuel rods were analyzed. The fuel rods had a 4.5 wt % {sup 235}U initial enrichment and were irradiated in the Vandellos II pressurized water reactor operated in Spain. The burnups of the fuel samples range from 42 to 78 GWd/MTU. The measurements were used to validate the two-dimensional depletion sequence TRITON in the SCALE computer code system.

  5. USACE FUSRAP Maywood Team Identifies Challenges and Initiates Alternate Solutions Relating to the Radiochemical Analysis of Borosilicate Fiber Filters for Isotopes of Uranium and Thorium

    SciTech Connect (OSTI)

    Tucker, B. [Shaw Environmental and Infrastructure, Salem, NH (United States); Winters, M. [Shaw Environmental and Infrastructure, Maywood, NJ (United States); Hays, D. [Unites States Army Corps of Engineers, Maywood, NJ (United States)

    2008-07-01T23:59:59.000Z

    This presentation discusses the primary purposes of particulate radionuclide air monitoring at the US Army Corps of Engineers (USACE) Formerly Utilized Sites Remediation Program (FUSRAP) Maywood Superfund Site (FMSS), the challenges encountered by the team when standard radiochemistry analytical methods are attempted on borosilicate fiber filter samples, the surrogate evaluations used when sample specific isotopic analysis is unsuccessful, and current strategies for overcoming radiochemistry method deficiencies. Typical borosilicate fiber filter sample preparation procedures including tracer spike and digestion methods and their impact on uranium and thorium data quality are of particular interest. Analytes discussed include isotopic uranium (U-234, U-235, and U-238) and isotopic thorium (Th-228, Th-230, and Th-232). Efforts to obtain reproducible and defensible results also included discussions with commercial laboratory radiochemistry managers as well as industry experts. This presentation may benefit sites that use similar sample collection and analysis techniques, utilize data that may have unidentified method-related issues with diminished data quality, or have a similar isotopic signature. (authors)

  6. Recent activities for ?-decay half-lives and ?-delayed neutron emission of very neutron-rich isotopes

    SciTech Connect (OSTI)

    Dillmann, Iris [TRIUMF, Vancouver BC, V6T 2A3, Canada and GSI Helmholtzzentrum für Schwerionenforschung GmbH, D-64291 Darmstadt (Germany); Abriola, Daniel [Laboratorio Tandar, Comisión Nacional de Energía Atómica, B1650KINA, San Martín, Buenos Aires (Argentina); Singh, Balraj [Department of Physics and Astronomy, McMaster University, Hamilton ON, L8S 4M1 (Canada)

    2014-05-02T23:59:59.000Z

    Beta-delayed neutron (?n) emitters play an important, two-fold role in the stellar nucleosynthesis of heavy elements in the 'rapid neutron-capture process' (r process). On one hand they lead to a detour of the material ?-decaying back to stability. On the other hand, the released neutrons increase the neutron-to-seed ratio, and are re-captured during the freeze-out phase and thus influence the final solar r-abundance curve. A large fraction of the isotopes inside the r-process reaction path are not yet experimentally accessible and are located in the (experimental) 'Terra Incognita'. With the next generation of fragmentation and ISOL facilities presently being built or already in operation, one of the main motivation of all projects is the investigation of these very neutron-rich isotopes. A short overview of one of the planned programs to measure ?n-emitters at the limits of the presently know isotopes, the BRIKEN campaign (Beta delayed neutron emission measurements at RIKEN) will be given. Presently, about 600 ?-delayed one-neutron emitters are accessible, but only for a third of them experimental data are available. Reaching more neutron-rich isotopes means also that multiple neutron-emission becomes the dominant decay mechanism. About 460 ?-delayed two-, three-or four-neutron emitters are identified up to now but for only 30 of them experimental data about the neutron branching ratios are available, most of them in the light mass region below A=30. The International Atomic and Energy Agency (IAEA) has identified the urgency and picked up this topic recently in a 'Coordinated Research Project' on a 'Reference Database for Beta-Delayed Neutron Emission Data'. This project will review, compile, and evaluate the existing data for neutron-branching ratios and half-lives of ?-delayed neutron emitters and help to ensure a reliable database for the future discoveries of new isotopes and help to constrain astrophysical and theoretical models.

  7. GUM Analysis for TIMS Isotopic Ratios in BEP0 Graphite Qualification Samples, Round 2

    SciTech Connect (OSTI)

    Gerlach, David C.; Heasler, Patrick G.; Reid, Bruce D.

    2009-01-01T23:59:59.000Z

    In May 2007, one set of three samples from NBL were addressed to Steve Petersen for TIMS analysis, and included BEP0 samples numbered 27008, 30986, and 50846. All cores were trimmed by tooling, and lightly cleaned by CO2 pellet blasting. Small discs were cut from the second set of samples for SIMS analysis, with the remainder of each used for TIMS preparation.

  8. Activation-analysis determination of the gadolinium content in zirconium

    SciTech Connect (OSTI)

    Rudenko, V.S.; Medvedev, A.B.

    1987-05-01T23:59:59.000Z

    The authors consider a method of determining the gadolinium content in zirconium from the attenuation of the thermalized neutron flux of the isotopic source in the sample with the aid of an activation detector for monitoring the neutron flux. In the proposed method, use is made of the difference in the cross sections of gadolinium and zirconium nuclei for neutron absorption. In the energy range up to 0.1 MeV the total neutron absorption cross section of gadolinium is almost four orders of magnitude greater than that of zirconium. This situation makes it possible to devise a nondestructive rapid method of determining the gadolinium content from the attenuation of the thermalized neutron flux in the sample under study.

  9. International Workshop on Gamma Spectrometry Analysis Codes for U and Pu Isotopics: Workshop Results and Next Steps

    SciTech Connect (OSTI)

    McGinnis, Brent R [ORNL; Solodov, Alexander A [ORNL; Shipwash, Jacqueline L [ORNL; Zhernosek, Alena V [ORNL; McKinney, Teressa L [ORNL; Pickett, Chris A [ORNL; Peerani, Paolo [ORNL

    2009-01-01T23:59:59.000Z

    In November 2008, the Institute of Nuclear Materials Management (INMM) and the European Safeguards Research and Development Association (ESARDA) co-hosted the International Workshop on Gamma Spectrometry Analysis Codes for U and Pu Isotopics at the Oak Ridge National Laboratory (ORNL). This workshop was conducted in response to needs expressed by the international safeguards community to understand better the capabilities and limitations of the codes; to ensure these codes are sustained; and to ensure updates or revisions are performed in a controlled manner. The workshop was attended by approximately 100 participants. The participants included code developers, code suppliers, safeguards specialists, domestic and international inspectors, process operators, regulators, and programme sponsors from various government agencies. The workshop provided a unique opportunity for code developers, commercial distributors and end users to interact in a hands-on laboratory environment to develop solutions for programmatic and technical issues associated with the various codes. The workshop also provided an international forum for discussing development of an internationally accepted standard test method. This paper discusses the organization of the workshop, its goals and objectives and feedback received from the participants. The paper also describes the significance of the working group's contribution to improving codes that are commonly used during inspections to verify that nuclear facilities are compliant with treaty obligations that ensure nuclear fuel cycle facilities are used for peaceful purposes.

  10. Analysis of the Activation and Heterolytic Dissociation of H2...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Dissociation of H2 by Frustrated Lewis Pairs: NH3BX3 (X H, F, and Cl) . Analysis of the Activation and Heterolytic Dissociation of H2 by Frustrated Lewis Pairs: NH3...

  11. activation analysis radiochemical: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    treated cocoa, and untreatec, cocoa) and a total analyze'1 by activation sr'tn thermal reactor neutrons gamma ? ray spec . rometry . The ana' ysis o-. cccc- in... Analysis...

  12. activation analysis pgnaa: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    treated cocoa, and untreatec, cocoa) and a total analyze'1 by activation sr'tn thermal reactor neutrons gamma ? ray spec . rometry . The ana' ysis o-. cccc- in... Analysis...

  13. activation pixe analysis: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    treated cocoa, and untreatec, cocoa) and a total analyze'1 by activation sr'tn thermal reactor neutrons gamma ? ray spec . rometry . The ana' ysis o-. cccc- in... Analysis...

  14. activation analysis naa: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    treated cocoa, and untreatec, cocoa) and a total analyze'1 by activation sr'tn thermal reactor neutrons gamma ? ray spec . rometry . The ana' ysis o-. cccc- in... Analysis...

  15. activation dose analysis: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    treated cocoa, and untreatec, cocoa) and a total analyze'1 by activation sr'tn thermal reactor neutrons gamma ? ray spec . rometry . The ana' ysis o-. cccc- in... Analysis...

  16. activation analysis uso: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    treated cocoa, and untreatec, cocoa) and a total analyze'1 by activation sr'tn thermal reactor neutrons gamma ? ray spec . rometry . The ana' ysis o-. cccc- in... Analysis...

  17. activation analysis caracterizacion: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    treated cocoa, and untreatec, cocoa) and a total analyze'1 by activation sr'tn thermal reactor neutrons gamma ? ray spec . rometry . The ana' ysis o-. cccc- in... Analysis...

  18. activation analysis caracterizacao: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    treated cocoa, and untreatec, cocoa) and a total analyze'1 by activation sr'tn thermal reactor neutrons gamma ? ray spec . rometry . The ana' ysis o-. cccc- in... Analysis...

  19. activation analysis inaa: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    treated cocoa, and untreatec, cocoa) and a total analyze'1 by activation sr'tn thermal reactor neutrons gamma ? ray spec . rometry . The ana' ysis o-. cccc- in... Analysis...

  20. analysis activation: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    treated cocoa, and untreatec, cocoa) and a total analyze'1 by activation sr'tn thermal reactor neutrons gamma ? ray spec . rometry . The ana' ysis o-. cccc- in... Analysis...

  1. activation analysis: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    treated cocoa, and untreatec, cocoa) and a total analyze'1 by activation sr'tn thermal reactor neutrons gamma ? ray spec . rometry . The ana' ysis o-. cccc- in... Analysis...

  2. activation analysis pgaa: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    treated cocoa, and untreatec, cocoa) and a total analyze'1 by activation sr'tn thermal reactor neutrons gamma ? ray spec . rometry . The ana' ysis o-. cccc- in... Analysis...

  3. activation analysis estudo: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    treated cocoa, and untreatec, cocoa) and a total analyze'1 by activation sr'tn thermal reactor neutrons gamma ? ray spec . rometry . The ana' ysis o-. cccc- in... Analysis...

  4. activation analysis avaliacao: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    treated cocoa, and untreatec, cocoa) and a total analyze'1 by activation sr'tn thermal reactor neutrons gamma ? ray spec . rometry . The ana' ysis o-. cccc- in... Analysis...

  5. activation analysis metod: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    treated cocoa, and untreatec, cocoa) and a total analyze'1 by activation sr'tn thermal reactor neutrons gamma ? ray spec . rometry . The ana' ysis o-. cccc- in... Analysis...

  6. activation analysis analise: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    treated cocoa, and untreatec, cocoa) and a total analyze'1 by activation sr'tn thermal reactor neutrons gamma ? ray spec . rometry . The ana' ysis o-. cccc- in... Analysis...

  7. activation analysis wth: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    treated cocoa, and untreatec, cocoa) and a total analyze'1 by activation sr'tn thermal reactor neutrons gamma ? ray spec . rometry . The ana' ysis o-. cccc- in... Analysis...

  8. activation analysis enaa: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    treated cocoa, and untreatec, cocoa) and a total analyze'1 by activation sr'tn thermal reactor neutrons gamma ? ray spec . rometry . The ana' ysis o-. cccc- in... Analysis...

  9. activation analysis determinacao: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    treated cocoa, and untreatec, cocoa) and a total analyze'1 by activation sr'tn thermal reactor neutrons gamma ? ray spec . rometry . The ana' ysis o-. cccc- in... Analysis...

  10. Trace determination of lead by helium-4 activation analysis 

    E-Print Network [OSTI]

    Vargas Bernal, Maria E.

    1984-01-01T23:59:59.000Z

    TRACE DETERMINATION OF LEAD BY HELIUM-4 ACTIVATION ANALYSIS A Thesis by MARIA E. VARGAS BERNAL Submitted to the Graduate College of Texas ARM University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE August... 1984 Major Subject: Chemistry TRACE DETERMINATION OF LEAD BY HELIUM-4 ACTIVATION ANALYSIS A Thesis by MARIA E. VARGAS BERNAL Approved as to style and format by: Emile A. Schweikert (Chairman of Committee) Marvin W. Rowe (Member) Gerald A. Sc...

  11. Trace determination of lead by helium-4 activation analysis

    E-Print Network [OSTI]

    Vargas Bernal, Maria E.

    1984-01-01T23:59:59.000Z

    TRACE DETERMINATION OF LEAD BY HELIUM-4 ACTIVATION ANALYSIS A Thesis by MARIA E. VARGAS BERNAL Submitted to the Graduate College of Texas ARM University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE August... 1984 Major Subject: Chemistry TRACE DETERMINATION OF LEAD BY HELIUM-4 ACTIVATION ANALYSIS A Thesis by MARIA E. VARGAS BERNAL Approved as to style and format by: Emile A. Schweikert (Chairman of Committee) Marvin W. Rowe (Member) Gerald A. Sc...

  12. from Isotope Production Facility

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cancer-fighting treatment gets boost from Isotope Production Facility April 13, 2012 Isotope Production Facility produces cancer-fighting actinium 2:32 Isotope cancer treatment...

  13. Nuclear Magnetic Resonance Spectroscopy Studies of the Lipid-bound, Receptor Active Conformation of the Apolipoprotein E Amino-terminus

    E-Print Network [OSTI]

    Hauser, Paul Stephen

    2010-01-01T23:59:59.000Z

    overexpression, isotope enrichment, and NMR analysis of theoverexpression, isotope enrichment, and NMR analysis of theoverexpression, isotope enrichment, and NMR analysis of the

  14. Stable Isotope Protocols: Sampling and Sample Processing

    E-Print Network [OSTI]

    Levin, Lisa A; Currin, Carolyn

    2012-01-01T23:59:59.000Z

    plants, benthic microalgae [BMI], benthic macroalgae) andin a dessicator, prior to analysis. A.2 Benthic microalgaeBenthic microalgae (BMI) can be collected for isotope

  15. U235: a gamma ray analysis code for uranium isotopic determination

    SciTech Connect (OSTI)

    Clark, D.

    1997-12-01T23:59:59.000Z

    A {sup 235}U analysis code, U235, has been written that can nondestructively determine the percentage of {sup 235}U in a uranium sample from the analysis of the emitted gamma rays. The code is operational and work is now underway to improve the accuracy of the calculation, particularly at the high (>90%) and low (<0.7%) {sup 235}U concentrations. A technique has been found to evaluate low {sup 235}U concentrations that works well on the existing standards. Work is now under way to evaluate this technique for other detectors and other types of samples. Work is also proceeding on: (1) ways to better determine gamma backgrounds, (2) techniques to determine the equivalent thickness of the sample to correct for gamma attenuation, (3) evaluation of the existing data base of branching ratios of {sup 235}U, {sup 238}U and their daughters gamma rays to allow better results and (4) evaluation of the existing data base on the emission ratios for uranium, thorium, and protactinium x-rays.

  16. Transportation of medical isotopes

    SciTech Connect (OSTI)

    Nielsen, D.L.

    1997-11-19T23:59:59.000Z

    A Draft Technical Information Document (HNF-1855) is being prepared to evaluate proposed interim tritium and medical isotope production at the Fast Flux Test Facility (FFTF). This assessment examines the potential health and safety impacts of transportation operations associated with the production of medical isotopes. Incident-free and accidental impacts are assessed using bounding source terms for the shipment of nonradiological target materials to the Hanford Site, the shipment of irradiated targets from the FFTF to the 325 Building, and the shipment of medical isotope products from the 325 Building to medical distributors. The health and safety consequences to workers and the public from the incident-free transportation of targets and isotope products would be within acceptable levels. For transportation accidents, risks to works and the public also would be within acceptable levels. This assessment is based on best information available at this time. As the medical isotope program matures, this analysis will be revised, if necessary, to support development of a final revision to the Technical Information Document.

  17. Swimming active droplet: A theoretical analysis

    E-Print Network [OSTI]

    Maximilian Schmitt; Holger Stark

    2012-10-09T23:59:59.000Z

    Recently, an active microswimmer was constructed where a micron-sized droplet of bromine water was placed into a surfactant-laden oil phase. Due to a bromination reaction of the surfactant at the interface, the surface tension locally increases and becomes non-uniform. This drives a Marangoni flow which propels the squirming droplet forward. We develop a diffusion-advection-reaction equation for the order parameter of the surfactant mixture at the droplet interface using a mixing free energy. Numerical solutions reveal a stable swimming regime above a critical Marangoni number M but also stopping and oscillating states when M is increased further. The swimming droplet is identified as a pusher whereas in the oscillating state it oscillates between being a puller and a pusher.

  18. Application of thermal analysis techniques in activated carbon production

    SciTech Connect (OSTI)

    Donnals, G.L.; DeBarr, J.A.; Brady, T.A. [Illinois State Geological Survey, Champaign, IL (United States)] [and others

    1996-12-31T23:59:59.000Z

    Several current research programs at the Illinois State Geological Survey (ISGS) relate to the development of activated carbons from Illinois coal, fly ash, and scrap tires. Preparation of activated carbons involves thermal processing steps that include preoxidation, pyrolysis and activation. Reaction time, temperature and gas composition during these processing steps ultimately determine the nature of the activated carbon produced. Thermal analysis plays a significant role in developing carbons by providing fundamental and engineering data that are useful in carbon production and characterization for process development.

  19. Functional analysis of oxidative stress-activated mitogen-activated protein kinase cascade

    E-Print Network [OSTI]

    Sheen, Jen

    -changing environment. A common plant response to different abiotic and biotic stresses, such as heat, chillingFunctional analysis of oxidative stress-activated mitogen-activated protein kinase cascade for review December 1, 1999) Despite the recognition of H2O2 as a central signaling molecule in stress

  20. Isotopically controlled semiconductors

    E-Print Network [OSTI]

    Haller, Eugene E.

    2006-01-01T23:59:59.000Z

    16 Isotopically Controlled Semiconductors Eugene E. Hallerof isotopically engineered semiconductors; for outstandingisotopically controlled semiconductor crystals. This article

  1. Iodine-129 separation and determination by neutron activation analysis

    SciTech Connect (OSTI)

    Bate, L.C.; Stokely, J.R.

    1981-01-01T23:59:59.000Z

    A method is described for analysis of /sup 129/I in fission product mixtures originating from fuel reprocessing studies and low-level wastes. The method utilizes conventional iodine valence adjustment and solvent extraction techniques to chemically separate /sup 129/I from most fission products. The /sup 129/I is determined by neutron irradiation and measurement of the 12.4 h /sup 130/I produced by the neutron capture reaction. Special techniques were devised for neutron irradiation of /sup 129/I samples in the pneumatic tube irradiation facilities at the High Flux Isotope (HFIR) and Oak Ridge Research (ORR) Reactors. Chemically separated /sup 129/I is adsorbed on an anion exchange resin column made from an irradiation container. The loaded resin is then irradiated in either of the pneumatic facilities to produce /sup 130/I. Sensitivity of the analysis with the HFIR facility (flux: 5 x 10/sup 14/ n/cm/sup 2//sec) and a 100-second irradiation time is approximately 0.03 nanograms. Samples up to 250 ml in volume can be easily processed.

  2. Comparison of atmospheric hydrology over convective continental regions using water vapor isotope measurements from space

    E-Print Network [OSTI]

    . Correlation analysis shows that mixing with boundary layer air, enhanced isotopic fractionation during precipitation, and subsiding air parcels contribute to intraseasonal isotopic variability. These local controls distillation in a Lagrangrian framework underestimates the observed isotopic depletion during the monsoons

  3. Digital computer coupling techniques for automatic activation analysis

    E-Print Network [OSTI]

    Breen, Walter Michael

    1961-01-01T23:59:59.000Z

    isotope. Should there be no more than three channels difference between the sample peaks and the corresponding library peaks, an identification of an isotope present will result. The number of iso- topee found is increased by unity, and the correct.... The library storage registers AS are initialized to zero and the seven center channels in each library main photopeak are tabulated in the library storage registers AS. 15. The following constants are computed for each library iso- tope which has been...

  4. Isotope Ratio Analysis on Micron-Sized Particles in Complex Matrices by Laser Ablation – Absorption Ratio Spectrometry

    SciTech Connect (OSTI)

    Bushaw, Bruce A.; Anheier, Norman C.

    2009-12-01T23:59:59.000Z

    Laser ablation has been combined with dual tunable diode laser absorption spectrometry to measure 152Gd:160Gd isotope ratios in micron-size particles. The diode lasers are tuned to specific isotopes in two different atomic transitions at 405.9 nm (152Gd) and 413.4 nm (160Gd) and directed collinearly through the laser ablation plume, separated on a diffraction grating, and detected with photodiodes to monitor transient absorption signals on a shot-by-shot basis. The method has been characterized first using Gd metal foil and then with particles of GdCl3?xH20 as binary and ternary mixtures with 152Gd:160Gd isotope ratios ranging from 0.01 to 0.43. These particulate mixtures have been diluted with Columbia River sediment powder (SRM 4350B) to simulate environmental samples and we show the method is capable of detecting a few highly enriched particles in the presence of > 100-fold excess of low-enrichment particles, even when the Gd-bearing particles are a minor component (0.08%) in the SRM powder and widely dispersed (1178 particles detected in 800 000 ablation laser shots). The implications for monitoring 235U:238U enrichment ratios, as related to the nuclear industry, are discussed

  5. Structure-Function Analysis of Apolipoprotein A-V: Insight into Plasma Triglyceride Homeostasis

    E-Print Network [OSTI]

    Mauldin, Kasuen

    2010-01-01T23:59:59.000Z

    overexpression, isotope enrichment, and NMR analysis of theoverexpression, isotope enrichment, and NMR analysis of theefficient stable isotope enrichment of the peptide was

  6. Analysis of alternatives for immobilized low activity waste disposal

    SciTech Connect (OSTI)

    Burbank, D.A.

    1997-10-28T23:59:59.000Z

    This report presents a study of alternative disposal system architectures and implementation strategies to provide onsite near-surface disposal capacity to receive the immobilized low-activity waste produced by the private vendors. The analysis shows that a flexible unit strategy that provides a suite of design solutions tailored to the characteristics of the immobilized low-activity waste will provide a disposal system that best meets the program goals of reducing the environmental, health, and safety impacts; meeting the schedule milestones; and minimizing the life-cycle cost of the program.

  7. Analyses of Oxyanion Materials by Prompt Gamma Activation Analysis

    SciTech Connect (OSTI)

    Firestone, Richard B; Perry, D.L.; English, G.A.; Firestone, R.B.; Leung, K.-N.; Garabedian, G.; Molnar, G.L.; Revay, Zs.

    2008-03-24T23:59:59.000Z

    Prompt gamma activation analysis (PGAA) has been used to analyze metal ion oxyanion materials that have multiple applications, including medicine, materials, catalysts, and electronics. The significance for the need for accurate, highly sensitive analyses for the materials is discussed in the context of quality control of end products containing the parent element in each material. Applications of the analytical data for input to models and theoretical calculations related to the electronic and other properties of the materials are discussed.

  8. Image patch analysis of sunspots and active regions. I. Intrinsic dimension and correlation analysis

    E-Print Network [OSTI]

    Moon, Kevin R; Delouille, Veronique; De Visscher, Ruben; Watson, Fraser; Hero, Alfred O

    2015-01-01T23:59:59.000Z

    Complexity of an active region is related to its flare-productivity. Mount Wilson or McIntosh sunspot classifications measure such complexity but in a categorical way, and may therefore not use all the information present in the observations. Moreover, such categorical schemes hinder a systematic study of an active region's evolution for example. We propose fine-scale quantitative descriptors for an active region's complexity and relate them to the Mount Wilson classification. We analyze the local correlation structure within continuum and magnetogram data, as well as the cross-correlation between continuum and magnetogram data. We compute the intrinsic dimension, partial correlation, and canonical correlation analysis (CCA) of image patches of continuum and magnetogram active region images taken from the SOHO-MDI instrument. We use masks of sunspots derived from continuum as well as larger masks of magnetic active regions derived from the magnetogram to analyze separately the core part of an active region fr...

  9. Isotope Science and Production

    E-Print Network [OSTI]

    Isotope Science and Production 35 years of experience in isotope production, processing, and applications. Llllll Committed to the safe and reliable production of radioisotopes, products, and services nuclear materials in trucks and cargo containers. Isotopes for Threat Reduction Isotope production at Los

  10. Stable isotope studies

    SciTech Connect (OSTI)

    Ishida, T.

    1992-01-01T23:59:59.000Z

    The research has been in four general areas: (1) correlation of isotope effects with molecular forces and molecular structures, (2) correlation of zero-point energy and its isotope effects with molecular structure and molecular forces, (3) vapor pressure isotope effects, and (4) fractionation of stable isotopes. 73 refs, 38 figs, 29 tabs.

  11. Mantle Helium And Carbon Isotopes In Separation Creek Geothermal...

    Open Energy Info (EERE)

    Mantle Helium And Carbon Isotopes In Separation Creek Geothermal Springs, Three Sisters Area, Central Oregon- Evidence For Renewed Volcanic Activity Or A Long Term Steady State...

  12. Features of adsorbed radioactive chemical elements and their isotopes distribution in iodine air filters AU-1500 at nuclear power plants

    E-Print Network [OSTI]

    Neklyudov, I M; Dikiy, N P; Ledenyov, O P; Lyashko, Yu V

    2013-01-01T23:59:59.000Z

    The main aim of research is to investigate the physical features of spatial distribution of the adsorbed radioactive chemical elements and their isotopes in the granular filtering medium in the iodine air filters of the type of AU1500 in the forced exhaust ventilation systems at the nuclear power plant. The gamma activation analysis method is applied to accurately characterize the distribution of the adsorbed radioactive chemical elements and their isotopes in the granular filtering medium in the AU1500 iodine air filter after its long term operation at the nuclear power plant. The typical spectrum of the detected chemical elements and their isotopes in the AU1500 iodine air filter, which was exposed to the bremsstrahlung gamma quantum irradiation, produced by the accelerating electrons in the tantalum target, are obtained. The spatial distributions of the detected chemical element 127I and some other chemical elements and their isotopes in the layer of absorber, which was made of the cylindrical coal granule...

  13. Hafnium isotope evidence from Archean granitic rocks for deep-mantle origin of continental crust

    E-Print Network [OSTI]

    Mojzsis, Stephen J.

    of zircon crystallization. The advent of laser-ablation Lu­Hf isotope analysis of igneous and detrital

  14. activation analysis applied: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Websites Summary: barrier (SBA), fault tree (FTA) and failure mode and effect analysis (FMEA) into one method. Our approach Analysis (FTA), Failure Mode and Effect Analysis (FMEA),...

  15. Active cooling for downhole instrumentation: Preliminary analysis and system selection

    SciTech Connect (OSTI)

    Bennett, G.A.

    1988-03-01T23:59:59.000Z

    A feasibility study and a series of preliminary designs and analyses were done to identify candidate processes or cycles for use in active cooling systems for downhole electronic instruments. A matrix of energy types and their possible combinations was developed and the energy conversion process for each pari was identified. The feasibility study revealed conventional as well as unconventional processes and possible refrigerants and identified parameters needing further clarifications. A conceptual design or series od oesigns for each system was formulated and a preliminary analysis of each design was completed. The resulting coefficient of performance for each system was compared with the Carnot COP and all systems were ranked by decreasing COP. The system showing the best combination of COP, exchangeability to other operating conditions, failure mode, and system serviceability is chosen for use as a downhole refrigerator. 85 refs., 48 figs., 33 tabs.

  16. Underground Corrosion of Activated Metals, 6-Year Exposure Analysis

    SciTech Connect (OSTI)

    M. K. Adler Flitton; T. S. Yoder

    2006-03-01T23:59:59.000Z

    The subsurface radioactive disposal site located at the Idaho National Laboratory contains neutronactivated metals from non-fuel nuclear-reactor-core components. A long-term underground corrosion test is being conducted to obtain site-specific corrosion rates to support efforts to more accurately estimate the transfer of activated elements in the surrounding arid vadose zone environment. The test uses nonradioactive metal coupons representing the prominent neutron-activated materials buried at the disposal location, namely, Type 304L stainless steel (UNS S30403), Type 316L stainless steel (S31603), nickel-chromium alloy (UNS NO7718), beryllium, aluminum 6061-T6 (A96061), and a zirconium alloy (UNS R60804). In addition, carbon steel (the material presently used in the cask disposal liners and other disposal containers) and a duplex stainless steel (UNS S32550) are also included in the test. This paper briefly describes the ongoing test and presents the results of corrosion analysis from coupons exposed underground for 1, 3, and 6 years.

  17. Carbon Dioxide Information Analysis Center: FY 1991 activities

    SciTech Connect (OSTI)

    Cushman, R.M.; Stoss, F.W.

    1992-06-01T23:59:59.000Z

    During the course of a fiscal year, Oak Ridge National Laboratory's Carbon Dioxide Information Analysis Center (CDIAC) distributes thousands of specially publications-numeric data packages (NDPs), computer model packages (CMPs), technical reports, public communication publications, newsletters, article reprints, and reference books-in response to requests for information related to global environmental issues, primarily those pertaining to climate change. CDIAC's staff also provides technical responses to specific inquiries related to carbon dioxide (CO{sub 2}), other trace gases, and climate. Hundreds of referrals to other researchers, policy analysts, information specialists, or organizations are also facilitated by CDIAC's staff. This report provides an account of the activities accomplished by CDIAC during the period October 1, 1990 to September 30, 1991. An organizational overview of CDIAC and its staff is supplemented by a detailed description of inquiries received and CDIAC's response to those inquiries. An analysis and description of the preparation and distribution of numeric data packages, computer model packages, technical reports, newsletters, factsheets, specially publications, and reprints is provided. Comments and descriptions of CDIAC's information management systems, professional networking, and special bilateral agreements are also described.

  18. Carbon Dioxide Information Analysis Center: FY 1992 activities

    SciTech Connect (OSTI)

    Cushman, R.M. [Oak Ridge National Lab., TN (United States). Carbon Dioxide Information Analysis Center; Stoss, F.W. [Tennessee Univ., Knoxville, TN (United States). Energy, Environment and Resources Center

    1993-03-01T23:59:59.000Z

    During the course of a fiscal year, Oak Ridge National Laboratory`s Carbon Dioxide Information Analysis Center (CDIAC) distributes thousands of specialty publications-numeric data packages (NDPs), computer model packages (CMPs), technical reports, public communication publications, newsletters, article reprints, and reference books-in response to requests for information related to global environmental issues, primarily those pertaining to climate change. CDIACs staff also provides technical responses to specific inquiries related to carbon dioxide (CO{sub 2}), other trace gases, and climate. Hundreds of referrals to other researchers, policy analysts, information specialists, or organizations are also facilitated by CDIAC`s staff. This report provides an account of the activities accomplished by CDIAC during the period October 1, 1991 to September 30, 1992. An organizational overview of CDIAC and its staff is supplemented by a detailed description of inquiries received and CDIAC`s response to those inquiries. As analysis and description of the preparation and distribution of numeric data packages, computer model packages, technical reports, newsletters, fact sheets, specialty publications, and reprints is provided. Comments and descriptions of CDIAC`s information management systems, professional networking, and special bilateral agreements are also described.

  19. Carbon Dioxide Information Analysis Center: FY 1991 activities

    SciTech Connect (OSTI)

    Cushman, R.M.; Stoss, F.W.

    1992-06-01T23:59:59.000Z

    During the course of a fiscal year, Oak Ridge National Laboratory`s Carbon Dioxide Information Analysis Center (CDIAC) distributes thousands of specially publications-numeric data packages (NDPs), computer model packages (CMPs), technical reports, public communication publications, newsletters, article reprints, and reference books-in response to requests for information related to global environmental issues, primarily those pertaining to climate change. CDIAC`s staff also provides technical responses to specific inquiries related to carbon dioxide (CO{sub 2}), other trace gases, and climate. Hundreds of referrals to other researchers, policy analysts, information specialists, or organizations are also facilitated by CDIAC`s staff. This report provides an account of the activities accomplished by CDIAC during the period October 1, 1990 to September 30, 1991. An organizational overview of CDIAC and its staff is supplemented by a detailed description of inquiries received and CDIAC`s response to those inquiries. An analysis and description of the preparation and distribution of numeric data packages, computer model packages, technical reports, newsletters, factsheets, specially publications, and reprints is provided. Comments and descriptions of CDIAC`s information management systems, professional networking, and special bilateral agreements are also described.

  20. Features of adsorbed radioactive chemical elements and their isotopes distribution in iodine air filters AU-1500 at nuclear power plants

    E-Print Network [OSTI]

    I. M. Neklyudov; A. N. Dovbnya; N. P. Dikiy; O. P. Ledenyov; Yu. V. Lyashko

    2013-06-21T23:59:59.000Z

    The main aim of research is to investigate the physical features of spatial distribution of the adsorbed radioactive chemical elements and their isotopes in the granular filtering medium in the iodine air filters of the type of AU1500 in the forced exhaust ventilation systems at the nuclear power plant. The gamma activation analysis method is applied to accurately characterize the distribution of the adsorbed radioactive chemical elements and their isotopes in the granular filtering medium in the AU1500 iodine air filter after its long term operation at the nuclear power plant. The typical spectrum of the detected chemical elements and their isotopes in the AU1500 iodine air filter, which was exposed to the bremsstrahlung gamma quantum irradiation, produced by the accelerating electrons in the tantalum target, are obtained. The spatial distributions of the detected chemical element 127I and some other chemical elements and their isotopes in the layer of absorber, which was made of the cylindrical coal granules of the type of SKT3, in the AU1500 iodine air filter are also researched. The possible influences by the standing acoustic wave of air pressure in the iodine air filter on the spatial distribution of the chemical elements and their isotopes in the iodine air filter are discussed. The comprehensive analysis of obtained research results on the distribution of the adsorbed chemical elements and their isotopes in the absorber of iodine air filter is performed.

  1. activation analysis approach: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    concept drives the analysis to the aimed specification part whereas the second allows Zachmann, Gabriel 36 Multiresolution morphological approach to document image analysis...

  2. activation analysis technique: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Summary: Geography 478 Techniques of Remote Sensing Image Analysis (Earth Observation System Science) Dr of Remote Sensing Image Analysis (Earth Observation System Science) Remote...

  3. activation analysis techniques: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Summary: Geography 478 Techniques of Remote Sensing Image Analysis (Earth Observation System Science) Dr of Remote Sensing Image Analysis (Earth Observation System Science) Remote...

  4. Laser Isotope Enrichment for Medical and Industrial Applications

    SciTech Connect (OSTI)

    Leonard Bond

    2006-07-01T23:59:59.000Z

    Laser Isotope Enrichment for Medical and Industrial Applications by Jeff Eerkens (University of Missouri), Jay Kunze (Idaho State University), and Leonard Bond (Idaho National Laboratory) The principal isotope enrichment business in the world is the enrichment of uranium for commercial power reactor fuels. However, there are a number of other needs for separated isotopes. Some examples are: 1) Pure isotopic targets for irradiation to produce medical radioisotopes. 2) Pure isotopes for semiconductors. 3) Low neutron capture isotopes for various uses in nuclear reactors. 4) Isotopes for industrial tracer/identification applications. Examples of interest to medicine are targets to produce radio-isotopes such as S-33, Mo-98, Mo-100, W-186, Sn-112; while for MRI diagnostics, the non-radioactive Xe-129 isotope is wanted. For super-semiconductor applications some desired industrial isotopes are Si-28, Ga-69, Ge-74, Se-80, Te-128, etc. An example of a low cross section isotope for use in reactors is Zn-68 as a corrosion inhibitor material in nuclear reactor primary systems. Neutron activation of Ar isotopes is of interest in industrial tracer and diagnostic applications (e.g. oil-logging). . In the past few years there has been a sufficient supply of isotopes in common demand, because of huge Russian stockpiles produced with old electromagnetic and centrifuge separators previously used for uranium enrichment. Production of specialized isotopes in the USA has been largely accomplished using old ”calutrons” (electromagnetic separators) at Oak Ridge National Laboratory. These methods of separating isotopes are rather energy inefficient. Use of lasers for isotope separation has been considered for many decades. None of the proposed methods have attained sufficient proof of principal status to be economically attractive to pursue commercially. Some of the authors have succeeded in separating sulfur isotopes using a rather new and different method, known as condensation repression. In this scheme a gas, of the selected isotopes for enrichment, is irradiated with a laser at a particular wavelength that would excite only one of the isotopes. The entire gas is subject to low temperatures sufficient to cause condensation on a cold surface. Those molecules in the gas that the laser excited are not as likely to condense as are the unexcited molecules. Hence the gas drawn out of the system will be enriched in the isotope that was excited by the laser. We have evaluated the relative energy required in this process if applied on a commercial scale. We estimate the energy required for laser isotope enrichment is about 20% of that required in centrifuge separations, and 2% of that required by use of "calutrons".

  5. Nuclear criticality safety bounding analysis for the in-tank-precipitation (ITP) process, impacted by fissile isotopic weight fractions

    SciTech Connect (OSTI)

    Bess, C.E.

    1994-04-22T23:59:59.000Z

    The In-Tank Precipitation process (ITP) receives High Level Waste (HLW) supernatant liquid containing radionuclides in waste processing tank 48H. Sodium tetraphenylborate, NaTPB, and monosodium titanate (MST), NaTi{sub 2}O{sub 5}H, are added for removal of radioactive Cs and Sr, respectively. In addition to removal of radio-strontium, MST will also remove plutonium and uranium. The majority of the feed solutions to ITP will come from the dissolution of supernate that had been concentrated by evaporation to a crystallized salt form, commonly referred to as saltcake. The concern for criticality safety arises from the adsorption of U and Pt onto MST. If sufficient mass and optimum conditions are achieved then criticality is credible. The concentration of u and Pt from solution into the smaller volume of precipitate represents a concern for criticality. This report supplements WSRC-TR-93-171, Nuclear Criticality Safety Bounding Analysis For The In-Tank-Precipitation (ITP) Process. Criticality safety in ITP can be analyzed by two bounding conditions: (1) the minimum safe ratio of MST to fissionable material and (2) the maximum fissionable material adsorption capacity of the MST. Calculations have provided the first bounding condition and experimental analysis has established the second. This report combines these conditions with canyon facility data to evaluate the potential for criticality in the ITP process due to the adsorption of the fissionable material from solution. In addition, this report analyzes the potential impact of increased U loading onto MST. Results of this analysis demonstrate a greater safety margin for ITP operations than the previous analysis. This report further demonstrates that the potential for criticality in the ITP process due to adsorption of fissionable material by MST is not credible.

  6. A one-group parametric sensitivity analysis for the graphite isotope ratio method and other related techniques using ORIGEN 2.2 

    E-Print Network [OSTI]

    Chesson, Kristin Elaine

    2009-06-02T23:59:59.000Z

    Several methods have been developed previously for estimating cumulative energy production and plutonium production from graphite-moderated reactors. The Graphite Isotope Ratio Method (GIRM) is one well-known technique. This method is based...

  7. Spectroscopical Analysis of Mechano-chemically Activated Surfaces 

    E-Print Network [OSTI]

    Cooper, Rodrigo

    2012-10-19T23:59:59.000Z

    Mechano-chemical activation is fundamentally different than chemical activation in that energy is added to alter the state of bond energy instead of exciting electrons to produce a chemical reaction. Mechano-chemical ...

  8. Switching Activity Analysis and Pre-Layout Activity Prediction for FPGAs

    E-Print Network [OSTI]

    Najm, Farid N.

    activity on a net changes when delays are zero (zero delay activity) versus when logic delays values. Our approach is novel in that it estimates each net's routed delay activity using only zero activity). Low-power synthesis and early power esti- mation are typically done on the basis of zero delay

  9. Switching Activity Analysis and PreLayout Activity Prediction for FPGAs

    E-Print Network [OSTI]

    Najm, Farid N.

    activity on a net changes when delays are zero (zero delay activity) versus when logic delays values. Our approach is novel in that it estimates each net's routed delay activity using only zero activity). Low­power synthesis and early power esti­ mation are typically done on the basis of zero delay

  10. Hybrid isotope separation scheme

    DOE Patents [OSTI]

    Maya, J.

    1991-06-18T23:59:59.000Z

    A method is described for yielding selectively a desired enrichment in a specific isotope including the steps of inputting into a spinning chamber a gas from which a scavenger, radiating the gas with a wave length or frequency characteristic of the absorption of a particular isotope of the atomic or molecular gas, thereby inducing a photochemical reaction between the scavenger, and collecting the specific isotope-containing chemical by using a recombination surface or by a scooping apparatus. 2 figures.

  11. Hybrid isotope separation scheme

    DOE Patents [OSTI]

    Maya, Jakob (Brookline, MA)

    1991-01-01T23:59:59.000Z

    A method of yielding selectively a desired enrichment in a specific isotope including the steps of inputting into a spinning chamber a gas from which a scavenger, radiating the gas with a wave length or frequency characteristic of the absorption of a particular isotope of the atomic or molecular gas, thereby inducing a photochemical reaction between the scavenger, and collecting the specific isotope-containing chemical by using a recombination surface or by a scooping apparatus.

  12. activation analysis summary: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    HURRICANE FORECASTS FOR 2011 activity. 3 12;DEFINITIONS AND ACRONYMS Accumulated Cyclone Energy (ACE) - A measure of a named storm 146 SUMMARY OF 2014 ATLANTIC TROPICAL...

  13. analysis activities reporting: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ability of Penn State researchers to compete Lee, Dongwon 26 NOAA ARL Monthly Activity Report October 2000 Geosciences Websites Summary: for Climate Monitoring 8. CMDP CBRAMS...

  14. Sensitivity Analysis of Optimal Operation of an Activated Sludge Process Model for Economic Controlled Variable Selection

    E-Print Network [OSTI]

    Skogestad, Sigurd

    Sensitivity Analysis of Optimal Operation of an Activated Sludge Process Model for Economic operation conducted on an activated sludge process model based on the test-bed benchmark simulation model no. 1 (BSM1) and the activated sludge model no. 1 (ASM1). The objective is to search for a control

  15. Stable isotope enrichment

    ScienceCinema (OSTI)

    Egle, Brian

    2014-07-15T23:59:59.000Z

    Brian Egle is working to increase the nation's capacity to produce stable isotopes for use including medicine, industry and national security.

  16. Isotopically controlled semiconductors

    E-Print Network [OSTI]

    Haller, E.E.

    2004-01-01T23:59:59.000Z

    and phonons in semiconductors,” J. Non-Cryst. Solids 141 (LVM) Spectroscopy of Semiconductors,” Mat. Res. Soc. Symp.Isotopically Engineered Semiconductors – New Media for the

  17. Stable isotope enrichment

    SciTech Connect (OSTI)

    Egle, Brian

    2014-07-14T23:59:59.000Z

    Brian Egle is working to increase the nation's capacity to produce stable isotopes for use including medicine, industry and national security.

  18. active network analysis: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Summary: :www.iai.uni-bonn.dejzgenemodules2.csv 3. Perform a hierarchical cluster analysis and plot the dendrograms. What is the number these correlation diagrams? Are...

  19. activation instrumental analysis: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    car electronics industry. There are currently many electronic systems improving the safety Wieringa, Roel 17 Runtime Instrumentation for Precise Flow-Sensitive Type Analysis...

  20. analysis neutron activation: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    sr'tn thermal reactor neutrons gamma ? ray spec . rometry . The ana' ysis o-. cccc- in... Analysis Gamma-Ray Spectrometry Peak Area Computation Peak Energy Determination...

  1. activation analysis rates: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    pressure signal. Although it is known rate analysis often replaces electrocardiogram (ECG) devices with the advantage that it does a device, worn at the wrist for a great...

  2. Discovery of the Tungsten Isotopes

    E-Print Network [OSTI]

    A. Fritsch; J. Q. Ginepro; M. Heim; A. Schuh; A. Shore; M. Thoennessen

    2009-03-25T23:59:59.000Z

    Thirty-five tungsten isotopes have so far been observed; the discovery of these isotopes is discussed. For each isotope a brief summary of the first refereed publication, including the production and identification method, is presented.

  3. Discovery of the Titanium Isotopes

    E-Print Network [OSTI]

    D. Meierfrankenfeld; M. Thoennessen

    2010-09-08T23:59:59.000Z

    Twentyfive titanium isotopes have so far been observed; the discovery of these isotopes is discussed. For each isotope a brief summary of the first refereed publication, including the production and identification method, is presented.

  4. Discovery of the Tin Isotopes

    E-Print Network [OSTI]

    S. Amos; M. Thoennessen

    2010-09-08T23:59:59.000Z

    Thirty-eight tin isotopes have so far been observed; the discovery of these isotopes is discussed. For each isotope a brief summary of the first refereed publication, including the production and identification method, is presented.

  5. Discovery of the tungsten isotopes

    SciTech Connect (OSTI)

    Fritsch, A.; Ginepro, J.Q.; Heim, M.; Schuh, A.; Shore, A. [National Superconducting Cyclotron Laboratory and Department of Physics and Astronomy, Michigan State University, East Lansing, MI 48824 (United States); Thoennessen, M. [National Superconducting Cyclotron Laboratory and Department of Physics and Astronomy, Michigan State University, East Lansing, MI 48824 (United States)], E-mail: thoennessen@nscl.msu.edu

    2010-05-15T23:59:59.000Z

    Thirty-five tungsten isotopes have been observed so far and the discovery of these isotopes is discussed here. For each isotope a brief summary of the first refereed publication, including the production and identification method, is presented.

  6. Discovery of the Tungsten Isotopes

    E-Print Network [OSTI]

    Fritsch, A; Heim, M; Schuh, A; Shore, A; Thoennessen, M

    2009-01-01T23:59:59.000Z

    Thirty-five tungsten isotopes have so far been observed; the discovery of these isotopes is discussed. For each isotope a brief summary of the first refereed publication, including the production and identification method, is presented.

  7. Vibroacoustic launch analysis and alleviation of lightweight, active mirrors

    E-Print Network [OSTI]

    Cohan, Lucy E.

    Lightweight, active, silicon carbide mirrors can increase the capability of space-based optical systems. However, launch survival is a serious concern for such systems, with the vibrations and acoustics from launch threatening ...

  8. Unsupervised Activity Analysis and Monitoring Algorithms for Effective Surveillance Systems

    E-Print Network [OSTI]

    in escalators and at platforms as well as human presence at lift ) that provide a global view of the activ- ity of sensors deployed in the real world, being it in large scale sensor networks or closed-circuit television

  9. activation analysis inaa: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Design of Active Inductor Texas A&M University - TxSpace Summary: Inductor replacing a passive inductor is analyzed. The proposed topology emulates an inductance value which is...

  10. (Carbon isotope fractionation inplants)

    SciTech Connect (OSTI)

    O'Leary, M.H.

    1990-01-01T23:59:59.000Z

    The objectives of this research are: To develop a theoretical and experimental framework for understanding isotope fractionations in plants; and to develop methods for using this isotope fractionation for understanding the dynamics of CO{sub 2} fixation in plants. Progress is described.

  11. Laser isotope separation

    DOE Patents [OSTI]

    Robinson, C. Paul (Los Alamos, NM); Jensen, Reed J. (Los Alamos, NM); Cotter, Theodore P. (Munich, DE); Boyer, Keith (Los Alamos, NM); Greiner, Norman R. (Los Alamos, NM)

    1988-01-01T23:59:59.000Z

    A process and apparatus for separating isotopes by selective excitation of isotopic species of a volatile compound by tuned laser light. A highly cooled gas of the volatile compound is produced in which the isotopic shift is sharpened and defined. Before substantial condensation occurs, the cooled gas is irradiated with laser light precisely tuned to a desired wavelength to selectively excite a particular isotopic species in the cooled gas. The laser light may impart sufficient energy to the excited species to cause it to undergo photolysis, photochemical reaction or even to photoionize. Alternatively, a two-photon irradiation may be applied to the cooled gas to induce photolysis, photochemical reaction or photoionization. The process is particularly applicable to the separation of isotopes of uranium.

  12. Photochemical isotope separation

    DOE Patents [OSTI]

    Robinson, C. Paul (Los Alamos, NM); Jensen, Reed J. (Los Alamos, NM); Cotter, Theodore P. (Los Alamos, NM); Greiner, Norman R. (Los Alamos, NM); Boyer, Keith (Los Alamos, NM)

    1987-01-01T23:59:59.000Z

    A process for separating isotopes by selective excitation of isotopic species of a volatile compound by tuned laser light. A highly cooled gas of the volatile compound is produced in which the isotopic shift is sharpened and defined. Before substantial condensation occurs, the cooled gas is irradiated with laser light precisely tuned to a desired wavelength to selectively excite a particular isotopic species in the cooled gas. The laser light may impart sufficient energy to the excited species to cause it to undergo photochemical reaction or even to photoionize. Alternatively, a two-photon irradiation may be applied to the cooled gas to induce photochemical reaction or photoionization. The process is particularly applicable to the separation of isotopes of uranium and plutonium.

  13. Photochemical isotope separation

    DOE Patents [OSTI]

    Robinson, C.P.; Jensen, R.J.; Cotter, T.P.; Greiner, N.R.; Boyer, K.

    1987-04-28T23:59:59.000Z

    A process is described for separating isotopes by selective excitation of isotopic species of a volatile compound by tuned laser light. A highly cooled gas of the volatile compound is produced in which the isotopic shift is sharpened and defined. Before substantial condensation occurs, the cooled gas is irradiated with laser light precisely tuned to a desired wavelength to selectively excite a particular isotopic species in the cooled gas. The laser light may impart sufficient energy to the excited species to cause it to undergo photochemical reaction or even to photoionize. Alternatively, a two-photon irradiation may be applied to the cooled gas to induce photochemical reaction or photoionization. The process is particularly applicable to the separation of isotopes of uranium and plutonium. 8 figs.

  14. Isotopic fractionations associated with phosphoric acid digestion of carbonate minerals: Insights from first-principles theoretical

    E-Print Network [OSTI]

    Goddard III, William A.

    Isotopic fractionations associated with phosphoric acid digestion of carbonate minerals: Insights for oxygen- and carbon-isotope analysis of carbonate minerals since 1950, and was recently established of oxygen isotope acid digestion fractionations among different carbonate minerals. We suggest these results

  15. Design and analysis of active vibration control in a microgravity environment

    E-Print Network [OSTI]

    Atwood, Clay Brian

    1990-01-01T23:59:59.000Z

    DESIGN AND ANALYSIS OF ACTIVE VIBRATION CONTROL IN A MICROGRAVITY ENVIRONMENT A Thesis by CLAY BRIAN ATWOOD Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree... of MASTER OF SCIENCE May 1990 Major Subject: Mechanical Engineering DESXGN AND ANALYSIS OF ACTIVE VIBRATION CONTROL XN A MXCROGRAVXTY ENVIRONMENT A Thesis by CLAY BRIAN ATWOOD Approved as to style and content by: Richard'Alexander (Chair...

  16. Water Research 36 (2002) 11811192 Accuracy analysis of a respirometer for activated sludge

    E-Print Network [OSTI]

    2002-01-01T23:59:59.000Z

    Water Research 36 (2002) 1181­1192 Accuracy analysis of a respirometer for activated sludge dynamic transfer, pH, and the influence of sludge condition on ``start-up'' behaviour. It is shown to what extent Elsevier Science Ltd. All rights reserved. Keywords: Respirometry; Oxygen uptake rate; Activated sludge

  17. RELIABILITY ANALYSIS IN A FAULT TOLERANT CONTROL STRATEGY DEDICATED TO ACTIVE POWER FILTER

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    RELIABILITY ANALYSIS IN A FAULT TOLERANT CONTROL STRATEGY DEDICATED TO ACTIVE POWER FILTER P. WEBER reliability indicate the optimal structure. Keywords: Fault Tolerant Control, System Reliability, Active power control and nuclear power plant operation (Zhang and Jiang, 2003). Various studies on FTC are based

  18. Two-phase refrigerant flow instability analysis and active control in transient electronics cooling systems

    E-Print Network [OSTI]

    Peles, Yoav

    Two-phase refrigerant flow instability analysis and active control in transient electronics cooling Pressure-drop oscillation Refrigeration system Two-phase cooling Active control Transient heat load a b s t r a c t Two-loop refrigeration systems are being explored for two-phase cooling of ultra high power

  19. Analysis of Seismic Activity near Theodore Roosevelt Dam, Arizona, during the Occupation

    E-Print Network [OSTI]

    Fouch, Matthew J.

    E Analysis of Seismic Activity near Theodore Roosevelt Dam, Arizona, during the Occupation, and Lepolt Linkimer Online Material: Plot of viable focal mechanisms and table of regional seismic velocity model. INTRODUCTION Rate and distribution of seismic activity are important indica- tors of the overall

  20. Analysis of the Seismic Activity Associated with the 20101 Eruption of Merapi Volcano, Java2

    E-Print Network [OSTI]

    Boyer, Edmond

    Analysis of the Seismic Activity Associated with the 20101 Eruption of Merapi Volcano, Java2 3 4 Keywords16 Merapi Volcano, Volcano Seismology, Eruption Forecasting, Pre-eruptive Seismicity,17 RSAM. The main features of the seismic activity during the23 pre-eruptive period and the crisis are presented

  1. Isotopic studies of the environmental chemistry of lead 

    E-Print Network [OSTI]

    Sugden, Carol Louise

    Lead emitted into the environment, primarily from the combustion of leaded petrol and industrial activities, such as metal smelting and coal burning, retains the isotopic signature of the ores from which it is derived. Accordingly, it is possible...

  2. Burnup estimation of fuel sourcing radioactive material based on monitored Cs and Pu isotopic activity ratios in Fukushima N. P. S. accident

    SciTech Connect (OSTI)

    Yamamoto, T.; Suzuki, M.; Ando, Y. [Japan Nuclear Energy Safety Organization, Toranomon Towers Office, 14F, 4-1-28, Toranomon, Minato-ku, Tokyo 105-0001 (Japan)

    2012-07-01T23:59:59.000Z

    After the severe core damage of Fukushima Dai-Ichi Nuclear Power Station, radioactive material leaked from the reactor buildings. As part of monitoring of radioactivity in the site, measurements of radioactivity in soils at three fixed points have been performed for {sup 134}Cs and {sup 137}Cs with gamma-ray spectrometry and for Pu, Pu, and {sup 240}Pu with {alpha}-ray spectrometry. Correlations of radioactivity ratios of {sup 134}Cs to {sup 137}Cs, and {sup 238}Pu to the sum of {sup 239}Pu and {sup 240}Pu with fuel burnup were studied by using theoretical burnup calculations and measurements on isotopic inventories, and compared with the Cs and Pu radioactivity rations in the soils. The comparison indicated that the burnup of the fuel sourcing the radioactivity was from 18 to 38 GWd/t, which corresponded to that of the fuel in the highest power and, therefore, the highest decay heat in operating high-burnup fueled BWR cores. (authors)

  3. Isotope-labeled immunoassays without radiation waste

    E-Print Network [OSTI]

    Hammock, Bruce D.

    of California, Davis, CA 95616; and Center for Accelerator Mass Spectrometry, Lawrence Livermore National, such as liquid scintillation counting (LSC) and autoradiography, use the radiation generated in the isotope in areas such as environmental monitoring and food analysis. Accelerator mass spectrometry (AMS) developed

  4. The determination of phosphorus by fast neutron activation analysis

    E-Print Network [OSTI]

    To-On, Maen

    1964-01-01T23:59:59.000Z

    . Thomson, B. A. , Anal. Chem. , 31, 1492 (1959) . 12. Helwig, H. L. & Ashikawa, J. K. , and Smith, E. R. , UCRL- 2655, July 19, 1954, pp. 1-9. 13. Winteringham, F. P. W. , Bridges, P. M. , and Hellyer, G. C. , 5'ochmm. Z. , 59, 13 (1955). 14. Bouten, P..., " UCRL 5351, Part II, Volume I, 1958, pp. 35-38. 32. Prud'homme, J. T. , "Texas Nuclear Corporation Neutron Generators, " Austin, Tease, 1962, pp. 3-6. 33. Koch, R, C. , "Actiyation Analysis Handbook' " Academi, c Pxess, 'NeW York, 1960, p. 52. 34...

  5. High-purity, isotopically enriched bulk silicon

    E-Print Network [OSTI]

    2004-01-01T23:59:59.000Z

    Russia. The stated isotope enrichments are summarized inenrichments >99% have been achieved for each isotope andthe enrichment is highest, are presented. isotope at. % nat.

  6. Nitrogen and carbon isotope values of individual amino acids: a tool to study foraging ecology of penguins in the Southern Ocean

    E-Print Network [OSTI]

    Brest, Université de

    but further work is required to determine the trophic enrichment factors for compound-specific isotopeNitrogen and carbon isotope values of individual amino acids: a tool to study foraging ecology, 79360 Villiers-en-Bois, France Running header: Compound-specific isotope analysis and penguin isotopic

  7. Atomic line emission analyzer for hydrogen isotopes

    DOE Patents [OSTI]

    Kronberg, J.W.

    1991-05-08T23:59:59.000Z

    Apparatus for isotopic analysis of hydrogen comprises a low pressure chamber into which a sample of hydrogen is introduced and then exposed to an electrical discharge to excite the electrons of the hydrogen atoms to higher energy states and thereby cause the emission of light on the return to lower energy states, a Fresnel prism made at least in part of a material anomalously dispersive to the wavelengths of interest for dispersing the emitted light, and a photodiode array for receiving the dispersed light. The light emitted by the sample is filtered to pass only the desired wavelengths, such as one of the lines of the Balmer series for hydrogen, the wavelengths of which differ slightly from one isotope to another. The output of the photodiode array is processed to determine the relative amounts of each isotope present in the sample. Additionally, the sample itself may be recovered using, a metal hydride.

  8. Atomic line emission analyzer for hydrogen isotopes

    DOE Patents [OSTI]

    Kronberg, James W. (108 Independent Blvd., Aiken, SC 29801)

    1993-01-01T23:59:59.000Z

    Apparatus for isotopic analysis of hydrogen comprises a low pressure chamber into which a sample of hydrogen is introduced and then exposed to an electrical discharge to excite the electrons of the hydrogen atoms to higher energy states and thereby cause the emission of light on the return to lower energy states, a Fresnel prism made at least in part of a material anomalously dispersive to the wavelengths of interest for dispersing the emitted light, and a photodiode array for receiving the dispersed light. The light emitted by the sample is filtered to pass only the desired wavelengths, such as one of the lines of the Balmer series for hydrogen, the wavelengths of which differ slightly from one isotope to another. The output of the photodiode array is processed to determine the relative amounts of each isotope present in the sample. Additionally, the sample itself may be recovered using a metal hydride.

  9. Atomic line emission analyzer for hydrogen isotopes

    DOE Patents [OSTI]

    Kronberg, J.W.

    1993-03-30T23:59:59.000Z

    Apparatus for isotopic analysis of hydrogen comprises a low pressure chamber into which a sample of hydrogen is introduced and then exposed to an electrical discharge to excite the electrons of the hydrogen atoms to higher energy states and thereby cause the emission of light on the return to lower energy states, a Fresnel prism made at least in part of a material anomalously dispersive to the wavelengths of interest for dispersing the emitted light, and a photodiode array for receiving the dispersed light. The light emitted by the sample is filtered to pass only the desired wavelengths, such as one of the lines of the Balmer series for hydrogen, the wavelengths of which differ slightly from one isotope to another. The output of the photodiode array is processed to determine the relative amounts of each isotope present in the sample. Additionally, the sample itself may be recovered using a metal hydride.

  10. At tank Low Activity Feed Homogeneity Analysis Verification

    SciTech Connect (OSTI)

    DOUGLAS, J.G.

    2000-09-28T23:59:59.000Z

    This report evaluates the merit of selecting sodium, aluminum, and cesium-137 as analytes to indicate homogeneity of soluble species in low-activity waste (LAW) feed and recommends possible analytes and physical properties that could serve as rapid screening indicators for LAW feed homogeneity. The three analytes are adequate as screening indicators of soluble species homogeneity for tank waste when a mixing pump is used to thoroughly mix the waste in the waste feed staging tank and when all dissolved species are present at concentrations well below their solubility limits. If either of these conditions is violated, then the three indicators may not be sufficiently chemically representative of other waste constituents to reliably indicate homogeneity in the feed supernatant. Additional homogeneity indicators that should be considered are anions such as fluoride, sulfate, and phosphate, total organic carbon/total inorganic carbon, and total alpha to estimate the transuranic species. Physical property measurements such as gamma profiling, conductivity, specific gravity, and total suspended solids are recommended as possible at-tank methods for indicating homogeneity. Indicators of LAW feed homogeneity are needed to reduce the U.S. Department of Energy, Office of River Protection (ORP) Program's contractual risk by assuring that the waste feed is within the contractual composition and can be supplied to the waste treatment plant within the schedule requirements.

  11. SPECTRAL ANALYSIS OF RADIOXENON

    SciTech Connect (OSTI)

    Cooper, Matthew W.; Bowyer, Ted W.; Hayes, James C.; Heimbigner, Tom R.; Hubbard, Charles W.; McIntyre, Justin I.; Schrom, Brian T.

    2008-09-23T23:59:59.000Z

    Monitoring changes in atmospheric radioxenon concentrations is a major tool in the detection of an underground nuclear explosion. Ground based systems like the Automated Radioxenon Sampler /Analyzer (ARSA), the Swedish Unattended Noble gas Analyzer (SAUNA) and the Automatic portable radiometer of isotopes Xe (ARIX), can collect and detect several radioxenon isotopes by processing and transferring samples into a high efficiency beta-gamma coincidence detector. The high efficiency beta-gamma coincidence detector makes these systems highly sensitive to the radioxenon isotopes 133Xe, 131mXe, 133mXe and 135Xe. The standard analysis uses regions of interest (ROI) to determine the amount of a particular radioxenon isotope present. The ROI method relies on the peaks of interest falling within energy limits of the ROI. Some potential problems inherent in this method are the reliance on stable detector gains and a fixed resolution for each energy peak. In addition, when a high activity sample is measured there will be more interference among the ROI, in particular within the 133Xe, 133mXe, and 131mXe regions. A solution to some of these problems can be obtained through spectral fitting of the data. Spectral fitting is simply the fitting of the peaks using known functions to determine the number and relative peak positions and widths. By knowing this information it is possible to determine which isotopes are present. Area under each peak can then be used to determine an overall concentration for each isotope. Using the areas of the peaks several key detector characteristics can be determined: efficiency, energy calibration, energy resolution and ratios between interfering isotopes (Radon daughters).

  12. Isotope Production and Distribution Program`s Fiscal Year 1997 financial statement audit

    SciTech Connect (OSTI)

    NONE

    1998-03-27T23:59:59.000Z

    The Department of Energy Isotope Production and Distribution Program mission is to serve the national need for a reliable supply of isotope products and services for medicine, industry and research. The program produces and sells hundreds of stable and radioactive isotopes that are widely utilized by domestic and international customers. Isotopes are produced only where there is no U.S. private sector capability or other production capacity is insufficient to meet U.S. needs. The Department encourages private sector investment in new isotope production ventures and will sell or lease its existing facilities and inventories for commercial purposes. The Isotope Program reports to the Director of the Office of Nuclear Energy, Science and Technology. The Isotope Program operates under a revolving fund established by the Fiscal Year (FY) 1990 Energy and Water Appropriations Act and maintains financial viability by earning revenues from the sale of isotopes and services and through annual appropriations. The FY 1995 Energy and Water Appropriations Act modified predecessor acts to allow prices charged for Isotope Program products and services to be based on production costs, market value, the needs of the research community, and other factors. Although the Isotope Program functions as a business, prices set for small-volume, high-cost isotopes that are needed for research purposes may not achieve full-cost recovery. As a result, isotopes produced by the Isotope Program for research and development are priced to provide a reasonable return to the U.S. Government without discouraging their use. Commercial isotopes are sold on a cost-recovery basis. Because of its pricing structure, when selecting isotopes for production, the Isotope Program must constantly balance current isotope demand, market conditions, and societal benefits with its determination to operate at the lowest possible cost to U.S. taxpayers. Thus, this report provides a financial analysis of this situation.

  13. ISOTOPIC ANALYSIS OF SUPERNOVA SiC AND Si{sub 3}N{sub 4} GRAINS FROM THE QINGZHEN (EH3) CHONDRITE

    SciTech Connect (OSTI)

    Lin Yangting [Key Laboratory of the Earth's Deep Interior, Institute of Geology and Geophysics, Chinese Academy of Sciences, Beijing 100029 (China); Gyngard, Frank; Zinner, Ernst [Laboratory for Space Sciences and the Physics Department, Washington University, St. Louis, MO 63130 (United States)

    2010-02-01T23:59:59.000Z

    We report Al-Mg, Ca, and Ti isotopic data in 16 silicon carbide grains and four silicon nitride grains from the Qingzhen enstatite chondrite. Previous C, N, and Si isotopic measurements had identified these grains as type X grains, believed to have an origin in Type II supernovae (SNe). The grains analyzed include both subtypes X1 and X2. Twelve SiC and three Si{sub 3}N{sub 4} grains show evidence for initial {sup 26}Al, and eight SiC grains evidence for {sup 44}Ti; 11 SiC grains have {sup 49}Ti excesses, possibly indicating the initial presence of {sup 49}V. A correlation with subtype is shown for {sup 44}Ti: X2 grains that have the highest inferred {sup 44}Ti/{sup 48}Ti ratios. A weaker correlation exists for N ratios: X2 grains with {sup 12}C/{sup 13}C > 300 have higher {sup 14}N/{sup 15}N ratios than X1 grains. We compare our data and data from previous reports with the SN models by Rauscher et al. The SN models can explain the C and N isotopic ratios fairly well if material from the {sup 15}N-rich spike in the He/N zone of the 25 M{sub sun} SN model is used. They also can explain the {sup 44}Ti/{sup 48}Ti ratios of the X1 and X2 grains. For the latter, substantial contributions from the inner Ni core are required. They indicate that not for all grains the {sup 49}Ti excesses can be attributed to decay of {sup 49}V and material from the He/C zone, where {sup 49}Ti is produced by neutron capture, is needed. The SN models, however, fail in explaining the Si isotopic ratios of most of the grains in a satisfactory fashion and the distinction between X1 and X2 grains. They also fail in explaining the observed correlation between the {sup 26}Al/{sup 27}Al ratios and {sup 12}C/{sup 13}C (and {sup 14}N/{sup 15}N) ratios.

  14. Nitrogen isotope effects on glutamate decarboxylase from Escherichia coli

    SciTech Connect (OSTI)

    Abell, L.M.; O'Leary, M.H.

    1988-05-03T23:59:59.000Z

    The nitrogen isotope effect on the decarboxylation of glutamic acid by glutamate decarboxylase from Escherichia coli has been measured by comparison of the isotopic composition of the amino nitrogen of the product ..gamma..-aminobutyric acid isolated after 10-20% reaction with that of the starting glutamic acid. At pH 4.7, 37 /sup 0/C, the isotope effect is k/sup 14//k/sup 15/ = 0.9855 +/- 0.0006 when compared to unprotonated glutamic acid. Interpretation of this result requires knowledge of the equilibrium nitrogen isotope effect for Schiff base formation. This equilibrium isotope effect is K/sup 14//K/sup 15/ - 0.9824 for the formation of the unprotonated Schiff base between unprotonated valine and salicylaldehyde. Analysis of the nitrogen isotope effect on decarboxylation of glutamic acid and of the previously measured carbon isotope effect on this same reaction shows that decarboxylation and Schiff base formation are jointly rate limiting. The enzyme-bound Schiff base between glutamate and pyridoxal 5'-phosphate partitions approximately 2:1 between decarboxylation and return to the starting state. The nitrogen isotope effect also reveals that the Schiff base nitrogen is protonated in this intermediate.

  15. 7, 1271512750, 2007 Hydrogen isotope

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    imply that there must be a very strong concomitant isotopic enrichment in the radical channel (CH2O + hACPD 7, 12715­12750, 2007 Hydrogen isotope fractionation in the photolysis of formaldehyde T. S a Creative Commons License. Atmospheric Chemistry and Physics Discussions Hydrogen isotope fractionation

  16. Molecular genetic analysis of activation-tagged transcription factors thought to be involved in photomorphogenesis

    SciTech Connect (OSTI)

    Neff, Michael M.

    2011-06-23T23:59:59.000Z

    This is a final report for Department of Energy Grant No. DE-FG02-08ER15927 entitled “Molecular Genetic Analysis of Activation-Tagged Transcription Factors Thought to be Involved in Photomorphogenesis”. Based on our preliminary photobiological and genetic analysis of the sob1-D mutant, we hypothesized that OBP3 is a transcription factor involved in both phytochrome and cryptochrome-mediated signal transduction. In addition, we hypothesized that OBP3 is involved in auxin signaling and root development. Based on our preliminary photobiological and genetic analysis of the sob2-D mutant, we also hypothesized that a related gene, LEP, is involved in hormone signaling and seedling development.

  17. On the Modeling of Piezoelectric Wafer Active Sensor Impedance Analysis for Structural Health Monitoring

    E-Print Network [OSTI]

    Giurgiutiu, Victor

    damage assessment, and are considered as a new non-destructive evaluation method. The in-situ impedance of experimental results obtained from previous work. The real part of the measured PWAS impedance presents twoOn the Modeling of Piezoelectric Wafer Active Sensor Impedance Analysis for Structural Health

  18. Analysis of patent activity in the field of quantum information processing

    E-Print Network [OSTI]

    Ryszard Winiarczyk; Piotr Gawron; Jaros?aw Adam Miszczak; ?ukasz Pawela; Zbigniew Pucha?a

    2012-12-11T23:59:59.000Z

    This paper provides an analysis of patent activity in the field of quantum information processing. Data from the PatentScope database from the years 1993-2011 was used. In order to predict the future trends in the number of filed patents time series models were used.

  19. Analysis of patent activity in the field of quantum information processing

    E-Print Network [OSTI]

    Winiarczyk, Ryszard; Miszczak, Jaros?aw Adam; Pawela, ?ukasz; Pucha?a, Zbigniew

    2013-01-01T23:59:59.000Z

    This paper provides an analysis of patent activity in the field of quantum information processing. Data from the PatentScope database from the years 1993-2011 was used. In order to predict the future trends in the number of filed patents time series models were used.

  20. Interferogram Analysis using Active Instance-Based Olac Fuentes and Thamar Solorio

    E-Print Network [OSTI]

    Fuentes, Olac

    accurate predic- tions. To further reduce the running time, we use a principal component analysis experiments show very accurate results using both noiseless and noisy interferograms. Key Words: active, are combined an made to interfere, which results in a pattern, called interfero- gram, that characterizes

  1. European Wind Energy Conference 2007 Milan Measurement based analysis of active and reactive power

    E-Print Network [OSTI]

    European Wind Energy Conference 2007 ­ Milan 1 Measurement based analysis of active and reactive of the electricity is produced by wind turbines and combined heat and power plants (CHPs). Most of them are connected of reactive power between the 60 kV and the 150 kV networks. Further, the TSO is obligated to compensate

  2. Theoretical analysis of actively mode-locked fiber ring laser with semiconductor optical amplifier

    E-Print Network [OSTI]

    Xu, Qianfan

    -locking; Fiber laser; Semiconductor optical amplifier 1. Introduction Ultra-short pulse sources are key devices for generating ultra-short pulse series. Various mode-locked lasers with higher than 10 GHz repetition have beenTheoretical analysis of actively mode-locked fiber ring laser with semiconductor optical amplifier

  3. On the determination of trace elements in cocoa and coffee by instrumental neutron activation analysis

    E-Print Network [OSTI]

    Adanuvor, Prosper Kwasi

    1980-01-01T23:59:59.000Z

    , Mn, Fe, Cc, Zn, As, Br, Rb, Sr, Sb, Ce Ba La, and Au. Qui. ano-Rico al. (16) app' ied Instrumental !Jeutron Activation Analysis to study the trac, ele. , ent distri- bution in ccffe he f o1 low' ng elements, wi. l' c er t ation rang s porn, were...

  4. Precursor Systems Analysis of Automated Highway Systems Activity Area J--Entry/Exit Implementation

    E-Print Network [OSTI]

    Varaiya, Pravin

    Precursor Systems Analysis of Automated Highway Systems Activity Area J--Entry/Exit Implementation This is the final report of a study of the following issues in the implementation of entry and exit in an Automated dedicated ramps; ffl Communication protocols for coordinating entry and exit maneuvers, and lateral

  5. Isotope shifts in francium isotopes Fr 206 - 213 and Fr 221

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Collister, R.; Gwinner, G.; Tandecki, M.; Behr, J. A.; Pearson, M. R.; Zhang, J.; Orozco, L. A.; Aubin, S.; Gomez, E.; FrPNC Collaboration

    2014-11-01T23:59:59.000Z

    We present the isotope shifts of the 7s1/2 to 7p1/2 transition for francium isotopes ˛???˛ąłFr with reference to ˛˛ąFr collected from two experimental periods. The shifts are measured on a sample of atoms prepared within a magneto-optical trap by a fast sweep of radio-frequency sidebands applied to a carrier laser. King plot analysis, which includes literature values for 7s1/2 to 7p3/2 isotope shifts, provides a field shift constant ratio of 1.0520(10) and a difference between the specific mass shift constants of 170(100) GHz amu between the D? and D? transitions, of sufficient precision to differentiate between ab initio calculations.

  6. Sensitivity analysis in linear programming applied to the problems of activation analysis

    E-Print Network [OSTI]

    Sloan, Thomas Orville

    1969-01-01T23:59:59.000Z

    results were right-nand-side ranging and the assigning to the obJective function a ratio of cost coefficients so each charnel assume as much importance in fitting a curve to the Activation Analvsis data as any other channel iv A CKii0'1LZD GM!'. ITS... CHAPTER III DATA DIFFERENCES AND THE ZFFECTS OF CHANNEL SUMMING CHAPTER IV PROCEDURE QF RIGHT-HAND-SIDE RANGI NG 16 CHAPTER V RATIO COST COEFFICIENTS PROCEDURE CHAPTER VI ANALYS1S GF OUTPUT TO DETERMINE SEIISITIVITY CHAPTER VII UNIFORM VARIATIONS...

  7. Articulated Motion Modeling for Activity Analysis Jiang Gao, Robert T. Collins, Alexander G. Hauptmann and Howard D. Wactlar

    E-Print Network [OSTI]

    Wactlar, Howard D.

    on blobs and trajectories output from this tracking system. In Zelnik-Manor and Irani (2001), dynamicArticulated Motion Modeling for Activity Analysis Jiang Gao, Robert T. Collins, Alexander G at a nursing home. 1. Introduction Much recent research has been focused on activity analysis in videos

  8. Temperature dependence of carbon isotope fractionation in CAM plants

    SciTech Connect (OSTI)

    Deleens, E.; Treichel, I.; O'Leary, M.H.

    1985-09-01T23:59:59.000Z

    The carbon isotope fractionation associated with nocturnal malic acid synthesis in Kalanchoe daigremontiana and Bryophyllum tubiflorum was calculated from the isotopic composition of carbon-4 of malic acid, after appropriate corrections. In the lowest temperature treatment (17/sup 0/C nights, 23/sup 0/C days), the isotope fractionation for both plants is -4% per thousand (that is, malate is enriched in /sup 13/C relative to the atmosphere). For K. daigremontiana, the isotope fractionation decreases with increasing temperature, becoming approximately 0% per thousand at 27/sup 0/C/33/sup 0/C. Detailed analysis of temperature effects on the isotope fractionation indicates that stomatal aperture decreases with increasing temperature and carboxylation capacity increases. For B. tubiflorum, the temperature dependence of the isotope fractionation is smaller and is principally attributed to the normal temperature dependences of the rates of diffusion and carboxylation steps. The small change in the isotopic composition of remaining malic acid in both species which is observed during deacidification indicates that malate release, rather than decarboxylation, is rate limiting in the deacidification process. 28 references, 1 figure, 4 tables.

  9. ISOTOPE METHODS IN HOMOGENEOUS CATALYSIS.

    SciTech Connect (OSTI)

    BULLOCK,R.M.; BENDER,B.R.

    2000-12-01T23:59:59.000Z

    The use of isotope labels has had a fundamentally important role in the determination of mechanisms of homogeneously catalyzed reactions. Mechanistic data is valuable since it can assist in the design and rational improvement of homogeneous catalysts. There are several ways to use isotopes in mechanistic chemistry. Isotopes can be introduced into controlled experiments and followed where they go or don't go; in this way, Libby, Calvin, Taube and others used isotopes to elucidate mechanistic pathways for very different, yet important chemistries. Another important isotope method is the study of kinetic isotope effects (KIEs) and equilibrium isotope effect (EIEs). Here the mere observation of where a label winds up is no longer enough - what matters is how much slower (or faster) a labeled molecule reacts than the unlabeled material. The most careti studies essentially involve the measurement of isotope fractionation between a reference ground state and the transition state. Thus kinetic isotope effects provide unique data unavailable from other methods, since information about the transition state of a reaction is obtained. Because getting an experimental glimpse of transition states is really tantamount to understanding catalysis, kinetic isotope effects are very powerful.

  10. Applying observations of work activity in designing prototype data analysis tools

    SciTech Connect (OSTI)

    Springmeyer, R.R.

    1993-07-06T23:59:59.000Z

    Designers, implementers, and marketers of data analysis tools typically have different perspectives than users. Consequently, data analysis often find themselves using tools focused on graphics and programming concepts rather than concepts which reflect their own domain and the context of their work. Some user studies focus on usability tests late in development; others observe work activity, but fail to show how to apply that knowledge in design. This paper describes a methodology for applying observations of data analysis work activity in prototype tool design. The approach can be used both in designing improved data analysis tools, and customizing visualization environments to specific applications. We present an example of user-centered design for a prototype tool to cull large data sets. We revisit the typical graphical approach of animating a large data set from the point of view of an analysis who is culling data. Field evaluations using the prototype tool not only revealed valuable usability information, but initiated in-depth discussions about user`s work, tools, technology, and requirements.

  11. 1,2-CF bond activation of perfluoroarenes and alkylidene isomers of titanium. DFT analysis of the CeF bond activation pathway and rotation of the titanium

    E-Print Network [OSTI]

    Baik, Mu-Hyun

    1,2-CF bond activation of perfluoroarenes and alkylidene isomers of titanium. DFT analysis of the CeF bond activation pathway and rotation of the titanium alkylidene moiety José G. Andino, Hongjun Received in revised form 26 July 2011 Accepted 27 July 2011 Keywords: Alkylidene Titanium CeF bond

  12. Laser isotope separation of erbium and other isotopes

    DOE Patents [OSTI]

    Haynam, Christopher A. (3035 Ferdale Ct., Pleasanton, CA 94566); Worden, Earl F. (117 Vereda del Ciervo, Diablo, CA 94528)

    1995-01-01T23:59:59.000Z

    Laser isotope separation is accomplished using at least two photoionization pathways of an isotope simultaneously, where each pathway comprises two or more transition steps. This separation method has been applied to the selective photoionization of erbium isotopes, particularly for the enrichment of .sup.167 Er. The hyperfine structure of .sup.167 Er was used to find two three-step photoionization pathways having a common upper energy level.

  13. Laser isotope separation of erbium and other isotopes

    DOE Patents [OSTI]

    Haynam, C.A.; Worden, E.F.

    1995-08-22T23:59:59.000Z

    Laser isotope separation is accomplished using at least two photoionization pathways of an isotope simultaneously, where each pathway comprises two or more transition steps. This separation method has been applied to the selective photoionization of erbium isotopes, particularly for the enrichment of {sup 167}Er. The hyperfine structure of {sup 167}Er was used to find two three-step photoionization pathways having a common upper energy level. 3 figs.

  14. Analysis of neutral active particle loss in afterglow in krypton at 2.6 mbar pressure

    SciTech Connect (OSTI)

    Pejovic, Momcilo M.; Karamarkovic, Jugoslav P.; Ristic, Goran S.; Pejovic, Milic M. [Faculty of Electronic Engineering, University of Nis, P.O. Box 73, 18001 Nis (Serbia); Faculty of Civil Engineering and Architecture, University of Nis, A. Medvedeva 14, 18001 Nis (Serbia); Faculty of Electronic Engineering, University of Nis, P.O. Box 73, 18001 Nis (Serbia)

    2008-01-15T23:59:59.000Z

    This paper presents the analysis of the surface recombination and/or de-excitation of neutral active particles in two different volume krypton-filled tubes at pressure of 2.6 mbar with 1 ppm oxygen impurities. The analysis was performed on the basis of secondary electron emission from the cathode induced by positive ions and neutral active particles using the experimental data of electrical breakdown time delay mean value t{sub d} as a function of afterglow period {tau} ('memory curve'). It was shown that the main channel of neutral active particles' loss in afterglow is their recombination and/or de-excitation on the bulb walls. The loss rate increases with the increase of available wall surface per unit of gas volume. It was also shown that in early afterglow (15 ms for the tube with smaller bulb volume and 30 ms for the tube with bigger bulb volume) positive ions are formed in the mutual collisions of neutral active particles, and these ions dominantly influence the secondary electron emission from the cathode. In late afterglow (to 30 s for the tube with smaller bulb volume and to 150 s for the tube with bigger bulb volume) neutral active particles have dominant role in secondary electron emission from the cathode. The probability for this process decreases with the increase of afterglow period as a consequence of the decrease of the concentration of neutral active particles in gas, and this probability is smaller for the tube with smaller bulb volume. The influence of additional electron yield in the electrode gap caused by gamma radiation on breakdown initiation is also analyzed. It is shown that the influence of the neutral active particles in the process of secondary electron emission in the case of gamma radiation is also significant in both early and late afterglow.

  15. Water isotopes and the general circulation

    E-Print Network [OSTI]

    Noone, David

    is depleted. #12;Distillation: vapor and condensate Isotopic fractionation -35 -30 -25 -20 -15 -10 -5 0 5 0 0 of idealized isotopic fractionation Expression of isotopic fractionation in nature Attributing signals" 18 = (R/Rstandard-1)x1000 R = moles of H2 18O/moles of H2 16O #12;Isotopic fractionation Isotopic

  16. Trophic ecology of the invasive argentine ant: spatio-temporal variation in resource assimilation and isotopic enrichment

    E-Print Network [OSTI]

    Menke, Sean B.; Suarez, Andy V.; Tillberg, Chadwick V.; Chou, Cheng T.; Holway, David A.

    2010-01-01T23:59:59.000Z

    assimilation and isotopic enrichment Sean B. Menke • Andy V.determined nitrogen enrichment using a controlled laboratoryconsumer- diet d15N enrichment: a meta-analysis. Oecologia

  17. An analysis of grouping and activity among visitors to an urban leisure locale in Houston, Texas

    E-Print Network [OSTI]

    Frey, Linda Lou

    1979-01-01T23:59:59.000Z

    te 11mi ted. As an approach to examin1ng leisure behavior, 1t has been recom- mended that the unit of analysis should be the group (Cheek, 1971). Consequently this study has attempted to examine the grouping and activity characteristics... United States, State, Component. Counties and places of Z5, 000 or larger) 46 Distribution of Functional Aggregates Among Observation Sessions 56 Distribution of Functional Aggregates Across Time of Oay. . . . 57 Aggregation of Functional Aggregates...

  18. Second Research Coordination Meeting on Reference Database for Neutron Activation Analysis -- Summary Report

    SciTech Connect (OSTI)

    Firestone, Richard B.; Kellett, Mark A.

    2008-03-19T23:59:59.000Z

    The second meeting of the Co-ordinated Research Project on"Reference Database for Neutron Activation Analysis" was held at the IAEA, Vienna from 7-9 May, 2007. A summary of the presentations made by participants is given, along with reports on specifically assigned tasks and subsequent discussions. In order to meet the overall objectives of this CRP, the outputs have been reiterated and new task assignments made.

  19. Determination of selected trace elements in human head hair by neutron activation analysis

    E-Print Network [OSTI]

    Courson, Leonard Austin

    1981-01-01T23:59:59.000Z

    barber shops and beauty salons in the Bryan-College Station Met- ropolitan Area. The locations of the prospective collection sites were selected at random from the local telephone directory. Though some of these sites did not elect to participate... for the degree of MASTER OF SCIENCE December 1981 Major Subject: Nuclear Engineering DETERMINATION OF SELECTEO TRACE ELEMENTS IN HUMAN HEAD HAIR BY NEUTRON ACTIVATION ANALYSIS A Thesis by LEONARD AUSTIN COURSON Approved as to style and content by Chai r...

  20. Methods for preparing comparative standards and field samples for neutron activation analysis of soil

    SciTech Connect (OSTI)

    Glasgow, D.C.; Dyer, F.F.; Robinson, L.

    1994-06-01T23:59:59.000Z

    One of the more difficult problems associated with comparative neutron activation analysis (CNAA) is the preparation of standards which are tailor-made to the desired irradiation and counting conditions. Frequently, there simply is not a suitable standard available commercially, or the resulting gamma spectrum is convoluted with interferences. In a recent soil analysis project, the need arose for standards which contained about 35 elements. In response, a computer spreadsheet was developed to calculate the appropriate amount of each element so that the resulting gamma spectrum is relatively free of interferences. Incorporated in the program are options for calculating all of the irradiation and counting parameters including activity produced, necessary flux/bombardment time, counting time, and appropriate source-to-detector distance. The result is multi-element standards for CNAA which have optimal concentrations. The program retains ease of use without sacrificing capability. In addition to optimized standard production, a novel soil homogenization technique was developed which is a low cost, highly efficient alternative to commercially available homogenization systems. Comparative neutron activation analysis for large scale projects has been made easier through these advancements. This paper contains details of the design and function of the NAA spreadsheet and innovative sample handling techniques.

  1. Regulatory impact analysis of environmental standards for uranium mill tailings at active sites. Final report

    SciTech Connect (OSTI)

    Not Available

    1983-03-01T23:59:59.000Z

    The Environmental Protection Agency was directed by Congress, under PL 95-604, the Uranium Mill Tailings Radiation Control Act of 1978, to set standards of general application that provide protection from the hazards associated with uranium mill tailings. Title I of the Act pertains to tailings at inactive sites for which the Agency has developed standards as part of a separate rulemaking. Title II of the Act requires standards covering the processing and disposal of byproduct materials at mills which are currently licensed by the appropriate regulatory authorities. This Regulatory Impact Analysis (RIA) addresses the standards developed under Title II. There are two major parts of the standards for active mills: standards for control of releases from tailings during processing operations and prior to final disposal, and standards for protection of the public after the disposal of tailings. This report presents a detailed analysis of standards for disposal only, since the analysis required for the operations standards is very limited.

  2. Regulatory impact analysis of final environmental standards for uranium mill tailings at active sites

    SciTech Connect (OSTI)

    Not Available

    1983-09-01T23:59:59.000Z

    The Environmental Protection Agency was directed by Congress, under PL 95-604, the Uranium Mill Tailings Radiation Control Act of 1978 (UMTRCA), to set standards of general application that provide protection from the hazards associated with uranium mill tailings. Title II of the Act requires standards covering the processing and disposal of byproduct materials at mills which are currently licensed by the appropriate regulatory authorities. This Regulatory Impact Analysis (RIA) addresses the standards promulgated under Title II. There are two major parts of the standards for active mills: standards for control of releases from tailings during processing operations and prior to final disposal, and standards for protection of the public health and environment after the disposal of tailings. This report presents a detailed analysis of standards for disposal only, since the analysis required for the standards during mill operations is very limited.

  3. Novel Isotope Effects and Organic Reaction Mechanisms

    E-Print Network [OSTI]

    Kelly, Kelmara K.

    2010-07-14T23:59:59.000Z

    to account for the observed isotope effects. In the dimerization of cyclopentadiene, novel "dynamic" isotope effects are observed on the 13C distribution in the product, and a method for the prediction of these isotope effects is developed here...

  4. Artificial Alpha-Active Bismuth Isotopes

    E-Print Network [OSTI]

    Templeton, D.H.

    2010-01-01T23:59:59.000Z

    Laboratory Contract No. W-7405-eng-48 ARTIFICIAL ALPHA-thD." 203. Contract No. W-7405-eng-48 To be published as awith the Atom~c N~mber W~7405- eng-48 Enerp:y Commission in

  5. Integrated provenance analysis of a convergent retroarc foreland system: UPb ages, heavy minerals, Nd isotopes, and sandstone compositions of the Middle Magdalena

    E-Print Network [OSTI]

    Basu, Asish R.

    , Colombia Junsheng Nie a,b, , Brian K. Horton a,c , Joel E. Saylor a , Andrés Mora d , Maria Mange e Valley basin Colombia Sediment provenance analysis remains a powerful method for testing hypotheses

  6. Oxygen Isotope Effects as Probes of Electron Transfer Mechanisms and Structures of

    E-Print Network [OSTI]

    Roth, Justine P.

    Oxygen Isotope Effects as Probes of Electron Transfer Mechanisms and Structures of Activated O2, Maryland 21218 RECEIVED ON JULY 26, 2008 C O N S P E C T U S Competitively determined oxygen (18 O) isotope effects can be power- ful probes of chemical and biological transformations involving molec- ular oxygen

  7. Alpha-emitting isotopes and chromium in a coastal California aquifer Jill N. Densmore a,

    E-Print Network [OSTI]

    .epa.gov/drink/contaminants/#List, accessed December 3, 2013). Understanding the chemistry and distribution of isotopes within the uranium) of 15 pCi/L, when adjusted for uranium activity; there is concern that new wells in the area may exceed-dependent water-quality data collected from the wells in 2011 (with analyses for isotopes within the uranium

  8. Chromatographic hydrogen isotope separation

    DOE Patents [OSTI]

    Aldridge, Frederick T. (Livermore, CA)

    1981-01-01T23:59:59.000Z

    Intermetallic compounds with the CaCu.sub.5 type of crystal structure, particularly LaNiCo.sub.4 and CaNi.sub.5, exhibit high separation factors and fast equilibrium times and therefore are useful for packing a chromatographic hydrogen isotope separation colum. The addition of an inert metal to dilute the hydride improves performance of the column. A large scale mutli-stage chromatographic separation process run as a secondary process off a hydrogen feedstream from an industrial plant which uses large volumes of hydrogen can produce large quantities of heavy water at an effective cost for use in heavy water reactors.

  9. ARM - Measurement - Isotope ratio

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadap Documentation TDMADAP : XDC documentationBarrow,ice particleSizegovMeasurementsIsotope ratio

  10. The marine biogeochemistry of zinc isotopes

    E-Print Network [OSTI]

    John, Seth G

    2007-01-01T23:59:59.000Z

    Zinc (Zn) stable isotopes can record information about important oceanographic processes. This thesis presents data on Zn isotopes in anthropogenic materials, hydrothermal fluids and minerals, cultured marine phytoplankton, ...

  11. Stable Isotope Fractionations in Biogeochemical Reactive Transport

    E-Print Network [OSTI]

    Druhan, Jennifer Lea

    2012-01-01T23:59:59.000Z

    characteristic of stable isotope enrichment. The values of !isotope ratios of sulfur in these sulfate samples demonstrated a clear enrichmentisotope ( 34 S) (Canfield, 2001). The characteristic enrichment

  12. Strategic Isotope Production | ornl.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Strategic Isotope Production SHARE Strategic Isotope Production Typical capsules used in the transport of 252Cf source material inside heavily shielded shipping casks. ORNL's...

  13. Isotopic Trends in Production of Superheavies

    SciTech Connect (OSTI)

    Antonenko, N.V. [Institut fuer Theoretische Physik der Justus-Liebig-Universitaet, D-35392 Giessen (Germany); Joint Institute for Nuclear Research, 141980 Dubna (Russian Federation); Adamian, G.G.; Zubov, A.S. [Joint Institute for Nuclear Research, 141980 Dubna (Russian Federation); Scheid, W. [Institut fuer Theoretische Physik der Justus-Liebig-Universitaet, D-35392 Giessen (Germany)

    2005-11-21T23:59:59.000Z

    The isotopic trends are discussed for cold and hot fusion reactions leading to superheavies. The possibilities of production of new isotopes in incomplete fusion reactions are treated.

  14. Isotope Research 229 Th production

    E-Print Network [OSTI]

    Isotope Research ­ 229 Th production We recently completed an ARRA-funded project of this type on 229 Th production reactions [Str11]. This long-lived isotope is important as a precursor to 225 Ac of accelerator production of 229 Th via the 230 Th(p,2n)229 Pa reaction. The 229 Pa decays primarily by electron

  15. Method of separating boron isotopes

    DOE Patents [OSTI]

    Jensen, Reed J. (Los Alamos, NM); Thorne, James M. (Provo, UT); Cluff, Coran L. (Provo, UT); Hayes, John K. (Salt Lake City, UT)

    1984-01-01T23:59:59.000Z

    A method of boron isotope enrichment involving the isotope preferential photolysis of (2-chloroethenyl)dichloroborane as the feed material. The photolysis can readily be achieved with CO.sub.2 laser radiation and using fluences significantly below those required to dissociate BCl.sub.3.

  16. Method of separating boron isotopes

    DOE Patents [OSTI]

    Jensen, R.J.; Thorne, J.M.; Cluff, C.L.

    1981-01-23T23:59:59.000Z

    A method of boron isotope enrichment involving the isotope preferential photolysis of (2-chloroethenyl)-dichloroborane as the feed material. The photolysis can readily by achieved with CO/sub 2/ laser radiation and using fluences significantly below those required to dissociate BCl/sub 3/.

  17. Isotope separation by laser means

    DOE Patents [OSTI]

    Robinson, C. Paul (Los Alamos, NM); Jensen, Reed J. (Los Alamos, NM); Cotter, Theodore P. (Los Alamos, NM); Greiner, Norman R. (Los Alamos, NM); Boyer, Keith (Los Alamos, NM)

    1982-06-15T23:59:59.000Z

    A process for separating isotopes by selective excitation of isotopic species of a volatile compound by tuned laser light. A highly cooled gas of the volatile compound is produced in which the isotopic shift is sharpened and defined. Before substantial condensation occurs, the cooled gas is irradiated with laser light precisely tuned to a desired wavelength to selectively excite a particular isotopic species in the cooled gas. The laser light may impart sufficient energy to the excited species to cause it to undergo photochemical reaction or even to photoionize. Alternatively, a two-photon irradiation may be applied to the cooled gas to induce photochemical reaction or photoionization. The process is particularly applicable to the separation of isotopes of uranium and plutonium.

  18. Chemical, multi-isotopic (Li-B-Sr-U-H-O) and thermal characterization of Triassic formation waters from the Paris Basin

    E-Print Network [OSTI]

    Boyer, Edmond

    of around 45 to 50°C. The study of uranium activity ratios for these Triassic formation waters allows us with water essentially resulting from a seawater-derived brine endmember diluted by meteoric waters. The data, uranium isotopes, oxygen isotopes, hydrogen isotopes, geothermometry, Trias, Paris Basin 1 hal-00563924

  19. Ion Uptake Determination of Dendrochronologically-Dated Trees Using Neutron Activation Analysis

    SciTech Connect (OSTI)

    Kenan Unlu; P.I. Kuniholm; D.K.H. Schwarz; N.O. Cetiner; J.J. Chiment

    2009-03-30T23:59:59.000Z

    Uptake of metal ions by plan roots is a function of the type and concentration of metal in the soil, the nutrient biochemistry of the plant, and the immediate environment of the root. Uptake of gold (Au) is known to be sensitive to soil pH for many species. Soil acidification due to acid precipitation following volcanic eruptions can dramatically increase Au uptake by trees. Identification of high Au content in tree rings in dendrochronologically-dated, overlapping sequences of trees allows the identification of temporally-conscribed, volcanically-influenced periods of environmental change. Ion uptake, specifically determination of trace amounts of gold, was performed for dendrochronologically-dated tree samples utilizing Neutron Activation Analysis (NAA) technique. The concentration of gold was correlated with known enviironmental changes, e.g. volcanic activities, during historic periods.

  20. Model-driven multi-omic data analysis elucidates metabolic immunomodulators of macrophage activation

    SciTech Connect (OSTI)

    Bordbar, Aarash; Mo, Monica L.; Nakayasu, Ernesto S.; Rutledge, Alexandra C.; Kim, Young-Mo; Metz, Thomas O.; Jones, Marcus B.; Frank, Bryan C.; Smith, Richard D.; Peterson, Scott N.; Hyduke, Daniel R.; Adkins, Joshua N.; Palsson, Bernhard O.

    2012-06-26T23:59:59.000Z

    Macrophages are central players in the immune response, manifesting divergent phenotypes to control inflammation and innate immunity through the release of cytokines and other regulatory factor-dependent signaling pathways. In recent years, the focus on metabolism has been reemphasized as critical signaling and regulatory pathways of human pathophysiology, ranging from cancer to aging, often converge on metabolic responses. Here, we used genome-scale modeling and multi-omics (transcriptomics, proteomics, and metabolomics) analysis to assess metabolic features critical for macrophage functions. We constructed a genome-scale metabolic network for the RAW 264.7 cell line to determine metabolic modulators of macrophage activation. Metabolites well-known to be associated with immunoactivation (e.g., glucose and arginine) and immunosuppression (e.g., tryptophan and vitamin D3) were amongst the most critical effectors. Intracellular metabolic mechanisms linked to critical suppressive effectors were then assessed, identifying a suppressive role for de novo nucleotide synthesis. Finally, the underlying metabolic mechanisms of macrophage activation are identified by analyzing multi-omic data obtained from LPS-stimulated RAW cells in the context of our flux-based predictions. Our study demonstrates metabolism's role in regulating activation may be greater than previously anticipated and elucidates underlying metabolic connections between activation and metabolic effectors.

  1. Vehicle Technologies Office Merit Review 2014: Overview and Progress of the Battery Testing, Design and Analysis Activity

    Broader source: Energy.gov [DOE]

    Presentation given by the Department of Energy's Energy Storage area at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about the battery testing, design, and analysis activity.

  2. Achievements in testing of the MGA and FRAM isotopic software codes under the DOE/NNSA-IRSN cooperation of gamma-ray isotopic measurement systems

    SciTech Connect (OSTI)

    Vo, Duc [Los Alamos National Laboratory; Wang, Tzu - Fang [LLNL; Funk, Pierre [IRSN; Weber, Anne - Laure [IRSN; Pepin, Nicolas [IRSN; Karcher, Anna [IRSN

    2009-01-01T23:59:59.000Z

    DOE/NNSA and IRSN collaborated on a study of gamma-ray instruments and analysis methods used to perform isotopic measurements of special nuclear materials. The two agencies agreed to collaborate on the project in response to inconsistencies that were found in the various versions of software and hardware used to determine the isotopic abundances of uranium and plutonium. IRSN used software developed internally to test the MGA and FRAM isotopic analysis codes for criteria used to stop data acquisition. The stop-criterion test revealed several unusual behaviors in both the MGA and FRAM software codes.

  3. Feasibility Study of MOX Fuel Online Burnup Analysis

    SciTech Connect (OSTI)

    Dennis, M.L.; Usman, S. [University of Missouri-Rolla, 222 Fulton Hall, 1870 Miner Circle, Rolla, MO 65409-0170 (United States)

    2006-07-01T23:59:59.000Z

    This research is an extension of well established Non-Destructive Analysis of UO fuel using gamma spectroscopy of Cs-137 and other related isotopes. Given the performance similarities between UO fuel and MOX fuel, investigations are underway to develop similar correlation for MOX. MOX fuel burnup and decay simulations are being performed using ORIGEN-ARP (Oak Ridge Isotope Generation and Depletion Code - Automatic Rapid Processing). Simulation results are being analyzed and will be used to determine performance specifications of a detection system for field applications. Analysis of isotopic activity from irradiated fuel will be used to develop correlations to determine burn-up and Plutonium content of MOX fuel. These results will be particularly useful in view of the recent interest in MOX fuel. (authors)

  4. Teacher's activity analysis within a didactic perspective Patrice Venturini, Chantal AmadeEscot UMR EFTS Universit de Toulouse 2

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Teacher's activity analysis within a didactic perspective Patrice Venturini, Chantal AmadeEscot UMR framework (the Joint Action Theory in Didactics) we use to analyse ordinary teaching/learning activities in science classrooms. This theory has been developed in French didactic research and takes

  5. Global analysis of active longitudes of solar X-ray flares L. Zhang a,b,c

    E-Print Network [OSTI]

    Usoskin, Ilya G.

    Observatories, Chinese Academy of Sciences, Beijing, China c Key Laboratory of Solar Activity, Chinese AcademyGlobal analysis of active longitudes of solar X-ray flares L. Zhang a,b,c , K. Mursula a,Ă, I of Sciences, Beijing, China d University of Oulu, Sodankyl¨a Geophysical Observatory, Oulu, Finland a r t i c

  6. Apparatus and process for separating hydrogen isotopes

    DOE Patents [OSTI]

    Heung, Leung K; Sessions, Henry T; Xiao, Xin

    2013-06-25T23:59:59.000Z

    The apparatus and process for separating hydrogen isotopes is provided using dual columns, each column having an opposite hydrogen isotopic effect such that when a hydrogen isotope mixture feedstock is cycled between the two respective columns, two different hydrogen isotopes are separated from the feedstock.

  7. Method for laser induced isotope enrichment

    DOE Patents [OSTI]

    Pronko, Peter P.; Vanrompay, Paul A.; Zhang, Zhiyu

    2004-09-07T23:59:59.000Z

    Methods for separating isotopes or chemical species of an element and causing enrichment of a desired isotope or chemical species of an element utilizing laser ablation plasmas to modify or fabricate a material containing such isotopes or chemical species are provided. This invention may be used for a wide variety of materials which contain elements having different isotopes or chemical species.

  8. Compelling Research Opportunities using Isotopes

    SciTech Connect (OSTI)

    None

    2009-04-23T23:59:59.000Z

    Isotopes are vital to the science and technology base of the US economy. Isotopes, both stable and radioactive, are essential tools in the growing science, technology, engineering, and health enterprises of the 21st century. The scientific discoveries and associated advances made as a result of the availability of isotopes today span widely from medicine to biology, physics, chemistry, and a broad range of applications in environmental and material sciences. Isotope issues have become crucial aspects of homeland security. Isotopes are utilized in new resource development, in energy from bio-fuels, petrochemical and nuclear fuels, in drug discovery, health care therapies and diagnostics, in nutrition, in agriculture, and in many other areas. The development and production of isotope products unavailable or difficult to get commercially have been most recently the responsibility of the Department of Energy's Nuclear Energy program. The President's FY09 Budget request proposed the transfer of the Isotope Production program to the Department of Energy's Office of Science in Nuclear Physics and to rename it the National Isotope Production and Application program (NIPA). The transfer has now taken place with the signing of the 2009 appropriations bill. In preparation for this, the Nuclear Science Advisory Committee (NSAC) was requested to establish a standing subcommittee, the NSAC Isotope Subcommittee (NSACI), to advise the DOE Office of Nuclear Physics. The request came in the form of two charges: one, on setting research priorities in the short term for the most compelling opportunities from the vast array of disciplines that develop and use isotopes and two, on making a long term strategic plan for the NIPA program. This is the final report to address charge 1. NSACI membership is comprised of experts from the diverse research communities, industry, production, and homeland security. NSACI discussed research opportunities divided into three areas: (1) medicine, pharmaceuticals, and biology, (2) physical sciences and engineering, and (3) national security and other applications. In each area, compelling research opportunities were considered and the subcommittee as a whole determined the final priorities for research opportunities as the foundations for the recommendations. While it was challenging to prioritize across disciplines, our order of recommendations reflect the compelling research prioritization along with consideration of time urgency for action as well as various geopolitical market issues. Common observations to all areas of research include the needs for domestic availability of crucial stable and radioactive isotopes and the education of the skilled workforce that will develop new advances using isotopes in the future. The six recommendations of NSACI reflect these concerns and the compelling research opportunities for potential new discoveries. The science case for each of the recommendations is elaborated in the respective chapters.

  9. Electrochemical Isotope Effect and Lithium Isotope Separation Jay R. Black,

    E-Print Network [OSTI]

    Mcdonough, William F.

    results showing a large lithium isotope separation due to electrodeposition. The fractionation is tunable lithium were plated from solutions of 1 M LiClO4 in propylene carbonate (PC) on planar nickel electrodes

  10. alpha particle-emitting isotopes: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    -occur- ring radioactive isotopes such as uranium, and radium also have Maximum Contaminant Levels (MCL and 25 picoCuries per liter (pCiL). Although activities were below the...

  11. Novel hybrid isotope separation scheme and apparatus

    DOE Patents [OSTI]

    Maya, Jakob (Brookline, MA)

    1991-01-01T23:59:59.000Z

    A method of yielding selectively a desired enrichment in a specific isotope including the steps of inputting into a spinning chamber a gas from which the specific isotope is to be isolated, radiating the gas with frequencies characteristic of the absorption of a particular isotope of the atomic or molecular gas, thereby inducing a photoionization reaction of the desired isotope, and collecting the specific isotope ion by suitable ion collection means.

  12. Novel hybrid isotope separation scheme and apparatus

    DOE Patents [OSTI]

    Maya, J.

    1991-06-18T23:59:59.000Z

    A method is described for yielding selectively a desired enrichment in a specific isotope including the steps of inputting into a spinning chamber a gas from which the specific isotope is to be isolated, radiating the gas with frequencies characteristic of the absorption of a particular isotope of the atomic or molecular gas, thereby inducing a photoionization reaction of the desired isotope, and collecting the specific isotope ion by suitable ion collection means. 3 figures.

  13. ISOTOPIC SIGNATURES OF PRESOLAR MATERIALS IN INTERPLANETARY DUST

    E-Print Network [OSTI]

    Mukhopadhyay, Sujoy

    technical challenge, the molecule-specific isotopic analysis of molecular cloud material in IDPs would particles collected in the stratosphere frequently exhibit enrichments in deuterium D and 15 N relative, 1987). These particles are samples of both comets and asteroids, but the specific source of any given

  14. Selective photoionisation of lutetium isotopes

    SciTech Connect (OSTI)

    D'yachkov, Aleksei B; Kovalevich, S K; Labozin, Valerii P; Mironov, Sergei M; Panchenko, Vladislav Ya; Firsov, Valerii A; Tsvetkov, G O; Shatalova, G G [National Research Centre 'Kurchatov Institute', Moscow (Russian Federation)

    2012-10-31T23:59:59.000Z

    A three-stage laser photoionisation scheme intended for enriching the {sup 176}Lu isotope from natural lutetium was considered. An investigation was made of the hyperfine structure of the second excited state 5d6s7s {yields} {sup 4}D{sub 3/2} with an energy of 37194 cm{sup -1} and the autoionisation state with an energy of 53375 cm{sup -1} of the {sup 176}Lu and {sup 175}Lu isotopes. The total electron momentum of the autoionisation level and the constant A of hyperfine magnetic interaction were determined. Due to a small value of the isotopic shift between {sup 176}Lu and {sup 175}Lu, appreciable selectivity of their separation may be achieved with individual hyperfine structure components. The first tentative enrichment of the 176Lu isotope was performed to a concentration of 60 % - 70 %. (laser applications and other topics in quantum electronics)

  15. Physics with isotopically controlled semiconductors

    SciTech Connect (OSTI)

    Haller, E. E., E-mail: eehaller@lbl.gov [University of California at Berkeley, Department of Materials Science and Engineering (United States)

    2010-07-15T23:59:59.000Z

    This paper is based on a tutorial presentation at the International Conference on Defects in Semiconductors (ICDS-25) held in Saint Petersburg, Russia in July 2009. The tutorial focused on a review of recent research involving isotopically controlled semiconductors. Studies with isotopically enriched semiconductor structures experienced a dramatic expansion at the end of the Cold War when significant quantities of enriched isotopes of elements forming semiconductors became available for worldwide collaborations. Isotopes of an element differ in nuclear mass, may have different nuclear spins and undergo different nuclear reactions. Among the latter, the capture of thermal neutrons which can lead to neutron transmutation doping, is the most prominent effect for semiconductors. Experimental and theoretical research exploiting the differences in all the properties has been conducted and will be illustrated with selected examples.

  16. IUPAC Periodic Table of Isotopes for the Educational Community

    SciTech Connect (OSTI)

    Holden N. E.; Holden,N.E.; Coplen,T.B.

    2012-07-15T23:59:59.000Z

    John Dalton first proposed the concept of atomic weights of the elements in the first decade of the nineteenth century. These atomic weights of the chemical elements were thought of as constants of nature, similar to the speed of light. Dmitri Mendeleev arranged the atomic weights of the elements in ascending order of value and used the systematic variation of their chemical properties to produce his Periodic Table of the Elements in 1869. Measurement of atomic weight values became an important chemical activity for a century and a half. Theodore Richards received a Noble Prize for his work in this area. In 1913, Fredrick Soddy found a species of radium, which had an atomic weight value of 228, compared to the familiar radium gas value of 226. Soddy coined the term 'isotope' (Greek for 'in the same place') to account for this second atomic weight value in the radium position of the Periodic Table. Both of these isotopes of radium are radioactive. Radioactive isotopes are energetically unstable and will decay (disintegrate) over time. The time it takes for one half of a sample of a given radioactive isotope to decay is the half-life of that isotope. In addition to having different atomic weight values, radium-226 and radium-228 also have different half-life values. Around the same time as Soddy's work, J.J. Thomson (discoverer of the electron) identified two stable (non-radioactive) isotopes of the same element, neon. Over the next 40 years, the majority of the known chemical elements were found to have two or more stable (or long-lived radioactive isotopes that contribute significantly to the determination of the atomic weights of the elements).

  17. Stable Isotope Dynamics in Cownose Rays (Rhinoptera bonasus) within the Northwestern Gulf of Mexico

    E-Print Network [OSTI]

    St. Clair, Katherine I

    2014-07-25T23:59:59.000Z

    investigation, there is limited information available on feeding patterns of cownose rays in the northwestern Gulf of Mexico. Stable isotope analysis has been used to study the foraging ecology of various species, but only recently applied to elasmobranchs...

  18. Delayed neutron studies of separated isotopes of Br, Rb, I, and Cs

    E-Print Network [OSTI]

    Reeder, R L; Wright, J F

    1976-01-01T23:59:59.000Z

    Discusses delayed neutron studies of separated isotopes of Br, Rb, I, and Cs are currently in progress at the Spectrometer for On-Line Analysis of Radionuclides (SOLAR) facility operated by Battelle, Pacific Northwest Laboratories. (2 refs).

  19. Isotope production facility produces cancer-fighting actinium

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cancer therapy gets a boost from new isotope Isotope production facility produces cancer-fighting actinium A new medical isotope project shows promise for rapidly producing major...

  20. Fragment Isotope Distributions and the Isospin Dependent Equation of State

    E-Print Network [OSTI]

    W. P. Tan; B-A. Li; R. Donangelo; C. K. Gelbke; M-J. van Goetherm; X. D. Liu; W. G. Lynch; S. Souza; M. B. Tsang; G. Verde; A. Wagner; N. S. Xu

    2001-04-21T23:59:59.000Z

    Calculations predict a connection between the isotopic composition of particles emitted during an energetic nucleus-nucleus collision and the density dependence of the asymmetry term of the nuclear equation of state (EOS). This connection is investigated for central 112Sn+112Sn and 124Sn+124Sn collisions at E/A=50 MeV in the limit of an equilibrated freezeout condition. Comparisons between measured isotopic yields ratios and theoretical predictions in the equilibrium limit are used to assess the sensitivity to the density dependence of the asymmetry term of the EOS. This analysis suggests that such comparisons may provide an opportunity to constrain the asymmetry term of the EOS.

  1. Isotopes facilities deactivation project at Oak Ridge National Laboratory

    SciTech Connect (OSTI)

    Eversole, R.E.

    1997-05-01T23:59:59.000Z

    The production and distribution of radioisotopes for medical, scientific, and industrial applications has been a major activity at Oak Ridge National Laboratory (ORNL) since the late 1940s. As the demand for many of these isotopes grew and their sale became profitable, the technology for the production of the isotopes was transferred to private industry, and thus, many of the production facilities at ORNL became underutilized. In 1989, the U.S. Department of Energy (DOE) instructed ORNL to identify and prepare various isotopes production facilities for safe shutdown. In response, ORNL identified 19 candidate facilities for shutdown and established the Isotopes Facilities Shutdown Program. In 1993, responsibility for the program was transitioned from the DOE Office of Nuclear Energy to the DOE Office of Environmental Management and Uranium Enrichment Operation`s Office of Facility Transition and Management. The program was retitled the Isotopes Facilities Deactivation Project (IFDP), and implementation responsibility was transferred from ORNL to the Lockheed Martin Energy Systems, Inc. (LMES), Environmental Restoration (ER) Program.

  2. Measurement of chromium VI and chromium III in stainless steel welding fumes with electron spectroscopy for chemical analysis and neutron activation analysis 

    E-Print Network [OSTI]

    Lautner, Gerald Myron

    1977-01-01T23:59:59.000Z

    MEASUREMENT OF CHROMIUM VI AND CHROMIUM III IN STAINLESS STEEL WELDING FUMES WITH ELECTRON SPECTROSCOPY FOR CHEMICAL ANALYSIS AND NEUTRON ACTIVATION ANALYSIS A Thesis by GERALD MYRON LAUTNER Submitted to the Graduate College of Texas Al...!M University in partial fulfillment of the requirement for the degree of MASTER OF SCIENCE December 1977 Major Subject: Industrial Hygiene MEASUREMENT OF CHROMIUM VI AND CHROMIUM III IN STAINLESS STEEL WELDING FUMES WITH ELECTRON SPECTROSCOPY...

  3. Differential utilization of allochthonous and autochthonous carbon by aquatic insects of two shrub-steppe desert spring-streams: A stable carbon isotope analysis and critique of the method

    SciTech Connect (OSTI)

    Mize, A.L. [Old Dominion Univ., Norfolk, VA (United States)

    1993-06-01T23:59:59.000Z

    The purpose of this study is to assess whether the carbon supporting stream food webs comes principally from terrestrial sources or is produced within the stream. Lacking data to resolve the allochthonous/autochthonous issue with any finality, stream ecologists have alternately postulated that stream carbon was principally autochthonous or principally allochthonous. Others argued that autochthonous and allochthonous carbon resources cannot be separated and that the allochthonous/autochthonous dependence issue is unresolvable. Many investigators have seized upon stable carbon isotopes technology as the tool to resolve the controversy. Unfortunately most investigators have conceded that the results are rarely quantitative and that the qualitative relationships are ambiguous. This study points out the fallacies of trying to conjure single isotopic values for either allochthonous or autochthonous carbon. It suggests that stable carbon isotope technology is not reliable in establishing specific consumer/food source relations and that it is not suitable for assessing allochthonous/autochthonous carbon dependence in freshwater streams.

  4. A Visual Analytics Approach to Structured Data Analysis to Enhance Nonproliferation and Arms Control Verification Activities

    SciTech Connect (OSTI)

    Gillen, David S.

    2014-08-07T23:59:59.000Z

    Analysis activities for Nonproliferation and Arms Control verification require the use of many types of data. Tabular structured data, such as Excel spreadsheets and relational databases, have traditionally been used for data mining activities, where specific queries are issued against data to look for matching results. The application of visual analytics tools to structured data enables further exploration of datasets to promote discovery of previously unknown results. This paper discusses the application of a specific visual analytics tool to datasets related to the field of Arms Control and Nonproliferation to promote the use of visual analytics more broadly in this domain. Visual analytics focuses on analytical reasoning facilitated by interactive visual interfaces (Wong and Thomas 2004). It promotes exploratory analysis of data, and complements data mining technologies where known patterns can be mined for. Also with a human in the loop, they can bring in domain knowledge and subject matter expertise. Visual analytics has not widely been applied to this domain. In this paper, we will focus on one type of data: structured data, and show the results of applying a specific visual analytics tool to answer questions in the Arms Control and Nonproliferation domain. We chose to use the T.Rex tool, a visual analytics tool developed at PNNL, which uses a variety of visual exploration patterns to discover relationships in structured datasets, including a facet view, graph view, matrix view, and timeline view. The facet view enables discovery of relationships between categorical information, such as countries and locations. The graph tool visualizes node-link relationship patterns, such as the flow of materials being shipped between parties. The matrix visualization shows highly correlated categories of information. The timeline view shows temporal patterns in data. In this paper, we will use T.Rex with two different datasets to demonstrate how interactive exploration of the data can aid an analyst with arms control and nonproliferation verification activities. Using a dataset from PIERS (PIERS 2014), we will show how container shipment imports and exports can aid an analyst in understanding the shipping patterns between two countries. We will also use T.Rex to examine a collection of research publications from the IAEA International Nuclear Information System (IAEA 2014) to discover collaborations of concern. We hope this paper will encourage the use of visual analytics structured data analytics in the field of nonproliferation and arms control verification. Our paper outlines some of the challenges that exist before broad adoption of these kinds of tools can occur and offers next steps to overcome these challenges.

  5. Source and thermal maturity of bitumen in Precambrian Nonesuch Formation inferred from isotopic compositions of individual normal alkanes

    SciTech Connect (OSTI)

    Hieshima, G.B. (Indiana Univ., Bloomington (United States))

    1991-03-01T23:59:59.000Z

    As part of a continuing study of organic geochemistry of the 1.05 Ga Nonesuch Formation in the North American Mid-Continents rift, isotopic compositions of individual normal alkanes were measured using compound-specific isotopic analysis. This is a relatively new technique that can be used in conjunction with traditional biomarker analysis in interpretation of thermal maturity, oil-source rock correlation, and paleoecologic reconstruction. Carbon-isotopic compositions of individual normal alkanes from C{sub 15} to C{sub 25} in five bitumens and one oil from Nonesuch strata vary from {minus}28.8 to {minus}34.5{per thousand} (versus PDB). Within a given sample, isotopic compositions of n-alkanes span a range of 2 to 4 {per thousand}%. Homologues from C{sub 15} to C{sub 19} are isotopically light (depleted) by approximately 0.5{per thousand} relative to higher homologues from C{sub 20} to C{sub 25}. Two sources of normal alkanes are interpreted from the distribution of isotopic compositions. Based on chain length, the series from C{sub 15} to C{sub 19} may have been derived from algal components. Isotopically heavy, higher homologues are suspected to have been derived from bacterial sources. The pattern of isotopic compositions of bitumens is similar to that of the oil, demonstrating an oil-source rock relationship. Superimposed upon this primary, bimodal distribution of normal alkanes is the influence of thermal maturity on isotopic composition. Normal alkanes in samples of higher thermal maturity are enriched isotopically by 0.25 to 2{per thousand} relative to those of lower thermal maturity. Isotopic enrichment with increasing thermal maturity is interpreted to be the result of either addition of isotopically heavy components derived from kerogen and/or preferential loss through cracking of isotopically light components in bitumen.

  6. Crystallographic Analysis of a Hammerhead Ribozyme Variant and Its Impact on Catalytic Activity

    E-Print Network [OSTI]

    Schultz, Eric P.

    2013-01-01T23:59:59.000Z

    pH–activity relationships of G8 and G12 variants at thepH-activity relationships of G8 and G12 variants at thepH-activity relationships of G8 and G12 variants at the

  7. Nickel isotopes in stellar matter

    E-Print Network [OSTI]

    Jameel-Un Nabi

    2014-08-19T23:59:59.000Z

    Isotopes of nickel play a key role during the silicon burning phase up to the presupernova phase of massive stars. Electron capture rates on these nickel isotopes are also important during the phase of core contraction. I present here the microscopic calculation of ground and excited states Gamow-Teller (GT) strength distributions for key nickel isotopes. The calculation is performed within the frame-work of pn-QRPA model. A judicious choice of model parameters, specially of the Gamow-Teller strength parameters and the deformation parameter, resulted in a much improved calculation of GT strength functions. The excited state GT distributions are much different from the corresponding ground-state distributions resulting in a failure of the Brink's hypothesis. The electron capture and positron decay rates on nickel isotopes are also calculated within the framework of pn-QRPA model relevant to the presupernova evolution of massive stars. The electron capture rates on odd-A isotopes of nickel are shown to have dominant contributions from parent excited states during as early as silicon burning phases. Comparison is being made with the large scale shell model calculation. During the silicon burning phases of massive stars the electron capture rates on $^{57,59}$Ni are around an order of magnitude bigger than shell model rates and can bear consequences for core-collapse simulators.

  8. Analysis of the interaction between air transportation and economic activity : a worldwide perspective

    E-Print Network [OSTI]

    Ishutkina, Mariya A. (Mariya Aleksandrovna)

    2009-01-01T23:59:59.000Z

    Air transportation usage and economic activity are interdependent. Air transportation provides employment and enables certain economic activities which are dependent on the availability of air transportation services. The ...

  9. activity-based cost analysis: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Paris-Sud XI, Universit de 6 Le Time Driven Activity Based Costing (TDABC): "New Wine, or Just New Bottles?" Physics Websites Summary: Le Time Driven Activity Based...

  10. Carbon kinetic isotope effects on the hydration of carbon dioxide and the dehydration of bicarbonate ion

    SciTech Connect (OSTI)

    Marlier, J.F.; O'Leary, M.H.

    1984-09-05T23:59:59.000Z

    /sup 13/C kinetic isotope effects on the hydration of CO/sub 2/ and the dehydration of HCO/sub 3//sup -/ in aqueous solution have been measured by rapid removal of the product and conversion to an isotopically stable form, followed by isotope-ratio analysis. The isotope effect on hydration is k/sup 12//k/sup 13/ = 1.0069 +/- 0.0003 at 24/sup 0/C. The isotope effect on dehydration is 1.0147 +/- 0.0007. The ratio of these two values gives an equilibrium isotope effect of K/sup 12//K/sup 13/ = 1.0077, in good agreement with previously measured values. The small magnitudes of the kinetic isotope effects indicate that the transition state for conversion of HCO/sub 3//sup -/ to CO/sub 2/ is very similar to that of HCO/sub 3//sup -/. This information together with previously measured solvent isotope effects indicates that the mechanism of HCO/sub 3//sup -/ dehydration probably involves general-acid-catalyzed donation of a proton from H/sub 3/O/sup +/ to the departing oxygen, rather than unimolecular decomposition of the zwitterion H/sub 2/O/sup +/-CO/sub 2//sup -/ in the rate-determining step. 21 references, 2 figures.

  11. Mechanistic studies using kinetic isotope effects

    E-Print Network [OSTI]

    Schulmeier, Brian E.

    1999-01-01T23:59:59.000Z

    Understanding reaction mechanisms is an important aspect of chemistry. A now convenient way to study reaction mechanisms is kinetic isotope effects at natural abundance. This technique circumvents the cumbersome methods of traditional isotope effect...

  12. Critical analysis of the Hanford spent nuclear fuel project activity based cost estimate

    SciTech Connect (OSTI)

    Warren, R.N.

    1998-09-29T23:59:59.000Z

    In 1997, the SNFP developed a baseline change request (BCR) and submitted it to DOE-RL for approval. The schedule was formally evaluated to have a 19% probability of success [Williams, 1998]. In December 1997, DOE-RL Manager John Wagoner approved the BCR contingent upon a subsequent independent review of the new baseline. The SNFP took several actions during the first quarter of 1998 to prepare for the independent review. The project developed the Estimating Requirements and Implementation Guide [DESH, 1998] and trained cost account managers (CAMS) and other personnel involved in the estimating process in activity-based cost (ABC) estimating techniques. The SNFP then applied ABC estimating techniques to develop the basis for the December Baseline (DB) and documented that basis in Basis of Estimate (BOE) books. These BOEs were provided to DOE in April 1998. DOE commissioned Professional Analysis, Inc. (PAI) to perform a critical analysis (CA) of the DB. PAI`s review formally began on April 13. PAI performed the CA, provided three sets of findings to the SNFP contractor, and initiated reconciliation meetings. During the course of PAI`s review, DOE directed the SNFP to develop a new baseline with a higher probability of success. The contractor transmitted the new baseline, which is referred to as the High Probability Baseline (HPB), to DOE on April 15, 1998 [Williams, 1998]. The HPB was estimated to approach a 90% confidence level on the start of fuel movement [Williams, 1998]. This high probability resulted in an increased cost and a schedule extension. To implement the new baseline, the contractor initiated 26 BCRs with supporting BOES. PAI`s scope was revised on April 28 to add reviewing the HPB and the associated BCRs and BOES.

  13. Online Catalog of Isotope Products from DOE's National Isotope Development Center

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    The National Isotope Development Center (NIDC) interfaces with the User Community and manages the coordination of isotope production across the facilities and business operations involved in the production, sale, and distribution of isotopes. A virtual center, the NIDC is funded by the Isotope Development and Production for Research and Applications (IDPRA) subprogram of the Office of Nuclear Physics in the U.S. Department of Energy Office of Science. The Isotope subprogram supports the production, and the development of production techniques of radioactive and stable isotopes that are in short supply for research and applications. Isotopes are high-priority commodities of strategic importance for the Nation and are essential for energy, medical, and national security applications and for basic research; a goal of the program is to make critical isotopes more readily available to meet domestic U.S. needs. This subprogram is steward of the Isotope Production Facility (IPF) at Los Alamos National Laboratory (LANL), the Brookhaven Linear Isotope Producer (BLIP) facility at BNL, and hot cell facilities for processing isotopes at ORNL, BNL and LANL. The subprogram also coordinates and supports isotope production at a suite of university, national laboratory, and commercial accelerator and reactor facilities throughout the Nation to promote a reliable supply of domestic isotopes. The National Isotope Development Center (NIDC) at ORNL coordinates isotope production across the many facilities and manages the business operations of the sale and distribution of isotopes.

  14. Analysis of the Interaction Between Air Transportation and Economic Activity: A Worldwide Perspective

    E-Print Network [OSTI]

    Ishutkina, Mariya A.

    2011-10-14T23:59:59.000Z

    Air transportation usage and economic activity are interdependent. Air transportation provides employment

  15. Analysis of the Interaction Between Air Transportation and Economic Activity: A Worldwide Perspective

    E-Print Network [OSTI]

    Hansman, R. John

    2009-03-30T23:59:59.000Z

    Air transportation usage and economic activity are interdependent. Air transportation provides employment

  16. Isotope Development & Production | Nuclear Science | ORNL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Medical Radioisotope Radiochemical Separation & Processing Strategic Isotope Production Super Heavy Element Discovery Nuclear Security Science & Technology Nuclear Systems...

  17. Isotopic Analysis (Klein, 2007) | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are8COaBulkTransmissionSitingProcess.pdfGetecGtelInterias Solar Energy JumpIrem GeothermalIselin,Isofoton SAOpen

  18. Isotopic Analysis (Not Available) | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are8COaBulkTransmissionSitingProcess.pdfGetecGtelInterias Solar Energy JumpIremNot Available) Jump to: navigation,

  19. Isotopic Analysis- Fluid | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to: navigation, searchOf Kilauea Volcano, Hawaii | OpenSuperiorEnergyOpen Energy

  20. Isotopic Analysis- Rock | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are beingZealand Jump to: navigation, searchOf Kilauea Volcano, Hawaii | OpenSuperiorEnergyOpen EnergyAl., 1988)

  1. Nitrogen Isotopic Composition of Coal-Fired Power Plant NOx: Influence of Emission Controls and Implications for Global Emission

    E-Print Network [OSTI]

    Elliott, Emily M.

    Nitrogen Isotopic Composition of Coal-Fired Power Plant NOx: Influence of Emission Controls from coal-fired power plants in the U.S. at typical operating conditions with and without the presence this, a novel method for collection and isotopic analysis of coal-fired stack NOx emission samples

  2. Ultimate Isotope Precision for Carbonates Thermo Scientific

    E-Print Network [OSTI]

    Lachniet, Matthew S.

    Ultimate Isotope Precision for Carbonates Thermo Scientific KIEL IV Carbonate Device Part of Thermo integration cycle Ultimate Isotope Precision for Carbonates The Thermo Scientific KIEL IV Carbonate DeviceV Thermo Scientific MAT 253 or the 3-kV DELTA V isotope ratio mass spectrometer meets the requirements

  3. Isotope Cancer Treatment Research at LANL

    ScienceCinema (OSTI)

    Weidner, John; Nortier, Meiring

    2014-06-02T23:59:59.000Z

    Los Alamos National Laboratory has produced medical isotopes for diagnostic and imaging purposes for more than 30 years. Now LANL researchers have branched out into isotope cancer treatment studies. New results show that an accelerator-based approach can produce clinical trial quantities of actinium-225, an isotope that has promise as a way to kill tumors without damaging surrounding healthy cells.

  4. Environmental isotope and geochemical investigation of groundwater in Big Bend National Park, Texas

    E-Print Network [OSTI]

    Lopez Sepulveda, Hector Javier

    1984-01-01T23:59:59.000Z

    is based on the solute concentrations and radiocarbon activities distributions observed in the groundwater through the area. Four flow systems within this ground- water flow are defined in terms of their respective chemical and isotopic groundwater... 10 J. O 11 15 METHODS. Field Methods Laboratorv Methods. 20 20 24 RESULTS AND DISCUSSION 27 Hydrochemical Isotopic. Rock Dissolution Chemistrv. 32 64 94 CONCLUSION 99 Panther Junction Area Rio Grande Village Area 99 100...

  5. Photonuclear Reaction Cross Sections for Gallium Isotopes

    E-Print Network [OSTI]

    Serkan Akkoyun; Tuncay Bayram

    2014-09-08T23:59:59.000Z

    The photon induced reactions which are named as photonuclear reactions have a great importance in many field of nuclear, radiation physics and related fields. Since we have planned to perform photonuclear reaction on gallium target with bremmstrahlung photons from clinical linear accelerator in the future, the cross-sections of neutron (photo-neutron ({\\gamma},xn)) and proton (photo-proton ({\\gamma},xn)) productions after photon activation have been calculated by using TALYS 1.2 computer code in this study. The target nucleus has been considered gallium which has two stable isotopes, 69Ga and 71Ga. According to the results, we have seen that the calculations are in harmony in the limited literature values. Furthermore, the pre-equilibrium and compound process contributions to the total cross-section have been investigated.

  6. Chemical and isotopic determination from complex spectra

    SciTech Connect (OSTI)

    Zardecki, A.; Strittmatter, R.B.

    1995-07-01T23:59:59.000Z

    Challenges for proliferation detection include remote, high- sensitivity detection of chemical effluents from suspect facilities and enhanced detection sensitivity for nuclear material. Both the identification of chemical effluents with lidar and enhanced nuclear material detection from radiation sensors involve determining constituents from complex spectra. In this paper, we extend techniques used to analyze time series to the analysis of spectral data. Pattern identification methods are applied to spectral data for domains where standard matrix inversion may not be suitable because of detection statistics. We use a feed-forward, back-propagation neural network in which the nodes of the input layer are fed with the observed spectral data. The nodes of the output layer contain the identification and concentration of the isotope or chemical effluent the sensor is to identify. We will discuss the neural network architecture, together with preliminary results obtained from the training process.

  7. Generalized Modeling of Enrichment Cascades That Include Minor Isotopes

    SciTech Connect (OSTI)

    Weber, Charles F [ORNL

    2012-01-01T23:59:59.000Z

    The monitoring of enrichment operations may require innovative analysis to allow for imperfect or missing data. The presence of minor isotopes may help or hurt - they can complicate a calculation or provide additional data to corroborate a calculation. However, they must be considered in a rigorous analysis, especially in cases involving reuse. This study considers matched-abundanceratio cascades that involve at least three isotopes and allows generalized input that does not require all feed assays or the enrichment factor to be specified. Calculations are based on the equations developed for the MSTAR code but are generalized to allow input of various combinations of assays, flows, and other cascade properties. Traditional cascade models have required specification of the enrichment factor, all feed assays, and the product and waste assays of the primary enriched component. The calculation would then produce the numbers of stages in the enriching and stripping sections and the remaining assays in waste and product streams. In cases where the enrichment factor or feed assays were not known, analysis was difficult or impossible. However, if other quantities are known (e.g., additional assays in waste or product streams), a reliable calculation is still possible with the new code, but such nonstandard input may introduce additional numerical difficulties into the calculation. Thus, the minimum input requirements for a stable solution are discussed, and a sample problem with a non-unique solution is described. Both heuristic and mathematically required guidelines are given to assist the application of cascade modeling to situations involving such non-standard input. As a result, this work provides both a calculational tool and specific guidance for evaluation of enrichment cascades in which traditional input data are either flawed or unknown. It is useful for cases involving minor isotopes, especially if the minor isotope assays are desired (or required) to be important contributors to the overall analysis.

  8. Chromium Isotope Fractionation During Reduction of Cr(VI) Under Saturated Flow Conditions

    SciTech Connect (OSTI)

    Jamieson-Hanes, Julia H.; Gibson, Blair D.; Lindsay, Matthew B.J.; Kim, Yeongkyoo; Ptacek, Carol J.; Blowes, David W. (Waterloo); (Kyungpook National University)

    2012-10-25T23:59:59.000Z

    Chromium isotopes are potentially useful indicators of Cr(VI) reduction reactions in groundwater flow systems; however, the influence of transport on Cr isotope fractionation has not been fully examined. Laboratory batch and column experiments were conducted to evaluate isotopic fractionation of Cr during Cr(VI) reduction under both static and controlled flow conditions. Organic carbon was used to reduce Cr(VI) in simulated groundwater containing 20 mg L{sup -1} Cr(VI) in both batch and column experiments. Isotope measurements were performed on dissolved Cr on samples from the batch experiments, and on effluent and profile samples from the column experiment. Analysis of the residual solid-phase materials by scanning electron microscopy (SEM) and by X-ray absorption near edge structure (XANES) spectroscopy confirmed association of Cr(III) with organic carbon in the column solids. Decreases in dissolved Cr(VI) concentrations were coupled with increases in {delta}{sup 53}Cr, indicating that Cr isotope enrichment occurred during reduction of Cr(VI). The {delta}{sup 53}Cr data from the column experiment was fit by linear regression yielding a fractionation factor ({alpha}) of 0.9979, whereas the batch experiments exhibited Rayleigh-type isotope fractionation ({alpha} = 0.9965). The linear characteristic of the column {delta}{sup 53}Cr data may reflect the contribution of transport on Cr isotope fractionation.

  9. Molecular Analysis of Microglial Activation and Macrophage Recruitment in Murine Models of Neuroinflammation.

    E-Print Network [OSTI]

    Puntambekar, Shweta

    2009-01-01T23:59:59.000Z

    nitric oxide synthase ITAM: immunoreceptor tyrosine basedbased activation motif (ITAM). The TLTs, have longermotif (ITIM). S S S S (DAP-12) ITAM ITIM Charged amino acid

  10. Empirical Tracking and Analysis of the Dynamics in Activity Scheduling and Schedule Execution

    E-Print Network [OSTI]

    Zhou, Jianyu Jack

    2006-01-01T23:59:59.000Z

    Comparison of Schedule Horizon for Activities with Different Participants Table 21 ANOVA of Schedule Horizons by Gender 145 Table 22 K-Means

  11. E-Print Network 3.0 - activation analysis body Sample Search...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to some degree to maintain body temperature as heat production through activity and heat loss... remote-sensing logging units to study changes in body temperature as a...

  12. A Comparative Analysis of the Perceptions of Special Education Teachers Regarding Educative Activities To Further Develop Teaching Skills

    E-Print Network [OSTI]

    Arocha-Gill, Theresa A.

    2010-07-14T23:59:59.000Z

    A COMPARATIVE ANALYSIS OF THE PERCEPTIONS OF SPECIAL EDUCATION TEACHERS REGARDING EDUCATIVE ACTIVITIES TO FURTHER DEVELOP TEACHING SKILLS A Dissertation by THERESA AROCHA-GILL Submitted to the Office of Graduate Studies of Texas A&M University... DEVELOP TEACHING SKILLS A Dissertation by THERESA AROCHA-GILL Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of DOCTOR OF PHILOSOPHY Approved by: Co-Chairs of Committee, Homer...

  13. Development of a database for prompt gamma-ray neutron activation analysis: Summary report of the third research coordination meeting

    SciTech Connect (OSTI)

    Lindstrom, Richard M.; Firestone, Richard B.; Pavi, ???

    2003-04-01T23:59:59.000Z

    The main discussions and conclusions from the Third Co-ordination Meeting on the Development of a Database for Prompt Gamma-ray Neutron Activation Analysis are summarized in this report. All results were reviewed in detail, and the final version of the TECDOC and the corresponding software were agreed upon and approved for preparation. Actions were formulated with the aim of completing the final version of the TECDOC and associated software by May 2003.

  14. Analysis of Microbial Activity Under a Supercritical CO{sub 2} Atmosphere

    SciTech Connect (OSTI)

    Thompson, Janelle

    2012-11-30T23:59:59.000Z

    Because the extent and impact of microbial activity in deep saline aquifers during geologic sequestration is unknown, the objectives of this proposal were to: (1) characterize the growth requirements and optima of a biofilm-producing supercritical CO{sub 2}-tolerant microbial consortium (labeled MIT0212) isolated from hydrocarbons recovered from the Frio Ridge, TX carbon sequestration site; (2) evaluate the ability of this consortium to grow under simulated reservoir conditions associated with supercritical CO{sub 2} injection; (3) isolate and characterize individual microbial strains from this consortium; and (4) investigate the mechanisms of supercritical CO{sub 2} tolerance in isolated strains and the consortium through genome-enabled studies. Molecular analysis of genetic diversity in the consortium MIT0212 revealed a predominance of sequences closely related to species of the spore-forming genus Bacillus. Strain MIT0214 was isolated from this consortium and characterized by physiological profiling and genomic analysis. We have shown that the strain MIT0214 is an aerobic spore-former and capable of facultative anaerobic growth under both reducing N{sub 2} and CO{sub 2} atmospheres by fermentation and possibly anaerobic respiration. Strain MIT0214 is best adapted to anaerobic growth at pressures of 1 atm but is able to growth at elevated pressures After 1 week growth was observed at pressures as high as 27 atm (N{sub 2}) or 9 atm (CO{sub 2}) and after 26-30 days growth can be observed under supercritical CO{sub 2}. In addition, we have determined that spores of strain B. cereus MIT0214 are tolerant of both direct and indirect exposure to supercritical CO{sub 2}. Additional physiological characterization under aerobic conditions have revealed MIT0214 is able to grow from temperature of 21 to 45 °C and salinities 0.01 to 40 g/L NaCl with optimal growth occurring at 30°C and from 1 - 5 g NaCl/L. The genome sequence of B. cereus MIT0214 shared 89 to 91% of genes with other genome-sequenced strains with 93.3 to 97.8% nucleotide identity among shared genes. Comparison of the sequence of MIT0214 or a B. cereus strain isolated from an oil well in China to B. cereus isolates from surface environments revealed a higher proportion of genes involved in Cell wall and capsule biosynthesis and metabolism, metabolism of aromatic compounds, and stress response. Since Bacillus species, including B. cereus strains, have commonly been recovered from other “extreme” environments including the deep subsurface – the scCO{sub 2} tolerance of spores and growth under high pCO{sub 2} conditions is consistent with persistence in a subsurface environment after CO{sub 2} injection.

  15. ANALYSIS OF ELECTRIC CURRENT HELICITY IN ACTIVE REGIONS ON THE BASIS OF VECTOR MAGNETOGRAMS

    E-Print Network [OSTI]

    Yurchyshyn, Vasyl

    can suggest that the build up of large­scale currents in an active region due to small­scale of Sciences, Beijing 100080, China Abstract. The problem of (dc) magnetic field energy build up in the solar seemingly can occur in any active region, the energy build up mechanism must be easy accessible for all

  16. Motion Pattern Analysis for Modeling and Recognition of Complex Human Activities

    E-Print Network [OSTI]

    Chowdhury, Amit K. Roy

    , research in activity recognition is moving towards more complex scenes involving multiple objects-mail: amitrc@ee.ucr.edu 1 This work has been partially supported by the DARPA VIRAT program and NSF award IIS to several kinds of activity recognition systems. For example, in a surveillance system, the interest could

  17. Vehicle Technologies Office Merit Review 2015: Cell Analysis, Modeling, and Prototyping (CAMP) Facility Research Activities

    Broader source: Energy.gov [DOE]

    Presentation given by Argonne National Laboratory at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about Cell Analysis,...

  18. Vehicle Technologies Office Merit Review 2014: Cell Analysis, Modeling, and Prototyping (CAMP) Facility Research Activities

    Broader source: Energy.gov [DOE]

    Presentation given by Argonne National Laboratory at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about cell analysis,...

  19. Vehicle Technologies Office Merit Review 2015: Impact Analysis: VTO Baseline and Scenario (BaSce) Activities

    Broader source: Energy.gov [DOE]

    Presentation given by Argonne National Laboratory at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about impact analysis:...

  20. Vehicle Technologies Office Merit Review 2014: Impact Analysis: VTO Baseline and Scenario (BaSce) Activities

    Broader source: Energy.gov [DOE]

    Presentation given by Argonne National Laboratory at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about impact analysis...

  1. Stable Isotope Signatures for Microbial Forensics

    SciTech Connect (OSTI)

    Kreuzer, Helen W.

    2012-01-03T23:59:59.000Z

    The isotopic distribution of the atoms composing the molecules of microorganisms is a function of the substrates used by the organisms. The stable isotope content of an organism is fixed so long as no further substrate consumption and biosynthesis occurs, while the radioactive isotopic content decays over time. The distribution of stable isotopes of C, N, O and H in heterotrophic microorganisms is a direct function of the culture medium, and therefore the stable isotope composition can be used to associate samples with potential culture media and also with one another. The 14C content depends upon the 14C content, and therefore the age, of the organic components of the culture medium, as well as on the age of the culture itself. Stable isotope signatures can thus be used for sample matching, to associate cultures with specific growth media, and to predict characteristics of growth media.

  2. Stable Isotope Enrichment Capabilities at ORNL

    SciTech Connect (OSTI)

    Egle, Brian [ORNL; Aaron, W Scott [ORNL; Hart, Kevin J [ORNL

    2013-01-01T23:59:59.000Z

    The Oak Ridge National Laboratory (ORNL) and the US Department of Energy Nuclear Physics Program have built a high-resolution Electromagnetic Isotope Separator (EMIS) as a prototype for reestablishing a US based enrichment capability for stable isotopes. ORNL has over 60 years of experience providing enriched stable isotopes and related technical services to the international accelerator target community, as well as medical, research, industrial, national security, and other communities. ORNL is investigating the combined use of electromagnetic and gas centrifuge isotope separation technologies to provide research quantities (milligram to several kilograms) of enriched stable isotopes. In preparation for implementing a larger scale production facility, a 10 mA high-resolution EMIS prototype has been built and tested. Initial testing of the device has simultaneously collected greater than 98% enriched samples of all the molybdenum isotopes from natural abundance feedstock.

  3. Persistence of activity on Twitter triggered by a natural disaster: A data analysis

    E-Print Network [OSTI]

    Kawamoto, Tatsuro

    2015-01-01T23:59:59.000Z

    In this note, we list the results of a simple analysis of a Twitter dataset: the complete dataset of Japanese tweets in the 1-week period after the Great East Japan earthquake, which occurred on March 11, 2011. Our data analysis shows how people reacted to the earthquake on Twitter and how some users went inactive in the long-term.

  4. Design and analysis of active fluid-and-cellular solid composites for controllable stiffness robotic elements

    E-Print Network [OSTI]

    Cheng, Nadia G. (Nadia Gen San)

    2009-01-01T23:59:59.000Z

    The purpose of this thesis is to investigate the use of a new class of materials for realizing soft robots. Specifically, meso-scale composites--composed of cellular solids impregnated with active fluids-were be designed ...

  5. Graphical Models for Wide-Area Activity Analysis in Continuous Videos

    E-Print Network [OSTI]

    Nayak, Nandita Miyar

    2014-01-01T23:59:59.000Z

    2 Multi-person Activity Recognition in Wide-area Videos 2.1Context Modeling in Continuous Videos Using Graphical Modelsmethod. Given a continuous video with computed tracklets, a

  6. Analysis of genomic Regions of IncreaseD Gene Expression (RIDGE)s in immune activation 

    E-Print Network [OSTI]

    Hansson, Lena

    2009-01-01T23:59:59.000Z

    A RIDGE (Region of IncreaseD Gene Expression), as defined by previous studies, is a consecutive set of active genes on a chromosome that span a region around 110 kbp long. This study investigated RIDGE formation by ...

  7. EIS-0249: Medical Isotopes Production Project

    Broader source: Energy.gov [DOE]

    This EIS evaluates the potential environmental impacts of a proposal to establish a production capability for molybdenum-99 (Mo-99) and related medical isotopes.

  8. Integration of Nontraditional Isotopic Systems Into Reaction...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Water-Rock Interaction, and Impacts of Water Chemistry on Reservoir Sustainability Integration of Nontraditional Isotopic Systems Into Reaction-Transport Models of EGS For...

  9. Stable Isotope Fractionations in Biogeochemical Reactive Transport

    E-Print Network [OSTI]

    Druhan, Jennifer Lea

    2012-01-01T23:59:59.000Z

    34 S fractionation . Summary A mesoscale study of isotopicion exchange and ! 44 Ca . A mesoscale study of isotopicmodeling and ! 34 S . A mesoscale study of isotopic

  10. Method for isotope enrichment by photoinduced chemiionization

    DOE Patents [OSTI]

    Dubrin, James W. (Walnut Creek, CA)

    1985-01-01T23:59:59.000Z

    Isotope enrichment, particularly .sup.235 U enrichment, is achieved by irradiating an isotopically mixed vapor feed with radiant energy at a wavelength or wavelengths chosen to selectively excite the species containing a desired isotope to a predetermined energy level. The vapor feed if simultaneously reacted with an atomic or molecular reactant species capable of preferentially transforming the excited species into an ionic product by a chemiionization reaction. The ionic product, enriched in the desired isotope, is electrostatically or electromagnetically extracted from the reaction system.

  11. O isotopic composition of CaCO3 measured by continuous ow isotope ratio mass spectrometry

    E-Print Network [OSTI]

    d13 C and d18 O isotopic composition of CaCO3 measured by continuous Żow isotope ratio mass. This new method streamlines the classical phosphoric acid/calcium carbonate (H3PO4/CaCO3) reaction method XL continuous flow isotope ratio mass spectrometer. Conditions for which the H3PO4/CaCO3 reaction

  12. High flux isotope reactor cold source preconceptual design study report

    SciTech Connect (OSTI)

    Selby, D.L.; Bucholz, J.A.; Burnette, S.E. [and others

    1995-12-01T23:59:59.000Z

    In February 1995, the deputy director of Oak Ridge National Laboratory (ORNL) formed a group to examine the need for upgrades to the High Flux Isotope Reactor (HFIR) system in light of the cancellation of the Advanced Neutron Source Project. One of the major findings of this study was that there was an immediate need for the installation of a cold neutron source facility in the HFIR complex. The anticipated cold source will consist of a cryogenic LH{sub 2} moderator plug, a cryogenic pump system, a refrigerator that uses helium gas as a refrigerant, a heat exchanger to interface the refrigerant with the hydrogen loop, liquid hydrogen transfer lines, a gas handling system that includes vacuum lines, and an instrumentation and control system to provide constant system status monitoring and to maintain system stability. The scope of this project includes the development, design, safety analysis, procurement/fabrication, testing, and installation of all of the components necessary to produce a working cold source within an existing HFIR beam tube. This project will also include those activities necessary to transport the cold neutron beam to the front face of the present HFIR beam room. The cold source project has been divided into four phases: (1) preconceptual, (2) conceptual design and research and development (R and D), (3) detailed design and procurement, and (4) installation and operation. This report marks the conclusion of the preconceptual phase and establishes the concept feasibility. The information presented includes the project scope, the preliminary design requirements, the preliminary cost and schedule, the preliminary performance data, and an outline of the various plans for completing the project.

  13. Donaldson Active Regeneration PM System

    Broader source: Energy.gov (indexed) [DOE]

    Modeling - FEA * Failure Mode Analysis & Life Prediction - Reliability Analysis * FMEA, Fault Tree Analysis, Risk Assessment, etc. Active System Durability & Reliability...

  14. Discovery of Isotopes of Elements with Z $\\ge$ 100

    E-Print Network [OSTI]

    M. Thoennessen

    2012-03-09T23:59:59.000Z

    Currently, 163 isotopes of elements with Z $\\ge$ 100 have been observed and the discovery of these isotopes is discussed here. For each isotope a brief synopsis of the first refereed publication, including the production and identification method, is presented.

  15. Gamma Spectrum from Neutron Capture on Tungsten Isotopes

    E-Print Network [OSTI]

    Hurst, Aaron

    2011-01-01T23:59:59.000Z

    FROM NEUTRON CAPTURE ON TUNGSTEN ISOTOPES A. M. HURST ?1,2 ,capture on the stable tungsten isotopes is presented, withknown decay schemes of the tungsten isotopes from neutron

  16. Europium Isotopic Abundances in Very Metal-poor Stars

    E-Print Network [OSTI]

    Christopher Sneden; John J. Cowan; James E. Lawler; Scott Burles; Timothy C. Beers; George M. Fuller

    2002-01-28T23:59:59.000Z

    Europium isotopic abundance fractions are reported for the very metal-poor, neutron-capture-rich giant stars CS 22892-052, HD 115444, and BD +17 3248. The abundance fractions, derived from analysis of several strong Eu II lines appearing in high-resolution spectra of these stars, are in excellent agreement with each other and with their values in the Solar System: fraction(\\iso{Eu}{151}) ~= fraction(\\iso{Eu}{153}) ~= 0.5. Detailed abundance studies of very metal-poor stars have previously shown that the total elemental abundances of stable atoms with atomic numbers z >= 56 typically match very closely those of a scaled solar-system r-process abundance distribution. The present results for the first time extend this agreement to the isotopic level.

  17. analysis charged-particle activation: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    at center-of-mass energy sqrtsNN200 GeV with the STAR detector at RHIC. A hower-shape analysis is used to partially discriminate between gammadir and pi0....

  18. Loch Linnhe `94: Test operations description and on-site analysis, US activities

    SciTech Connect (OSTI)

    Mantrom, D.D.

    1994-11-01T23:59:59.000Z

    A field experiment named Loch Linnhe `94 (LL94) is described. This experiment was conducted in upper Loch Linnhe, Scotland, in September 1994, as an exercise involving UK and US investigators, under the Joint UK/US Radar Ocean Imaging Program. This experiment involved a dual-frequency, dual-polarization hillside real aperture radar operated by the UK, Lawrence Livermore National Laboratory`s (LLNL) current meter array (CMA), in-water hydrodynamic sensors, and meteorological measurements. The primary measurements involved imaging ship-generated and ambient internal waves by the radar and the CMA. This report documents test operations from a US perspective and presents on-site analysis results derived by US investigators. The rationale underlying complementary radar and CMA measurements is described. Descriptions of the test site, platforms, and major US instrument systems are given. A summary of test operations and examples of radar, CMA, water column profile, and meteorological data are provided. A description of the rather extensive analysis of these data performed at the LL94 test site is presented. The products of this analysis are presented and some implications for further analysis and future experiments are discussed. All experimental objectives were either fully or partially met. Powerful on-site analysis capabilities generated many useful products and helped improve subsequent data collection. Significant further data analysis is planned.

  19. Ring diagram analysis of the characteristics of solar oscillation modes in active regions

    E-Print Network [OSTI]

    S. P. Rajaguru; Sarbani Basu; H. M. Antia

    2001-08-14T23:59:59.000Z

    The presence of intense magnetic fields in and around sunspots is expected to modify the solar structure and oscillation frequencies. Applying the ring diagram technique to data from the Michelson Doppler Imager (MDI) on board the Solar and Heliospheric Observatory (SOHO), we analyze the characteristics of high-degree f and p modes near active regions and compare them with the characteristics of the modes in quiet regions. As expected from earlier results, the f- and p-mode frequencies of high degree modes are found to be significantly larger in magnetically active regions. In addition, we find that the power in both f and p modes is lower in active regions, while the widths of the peaks are larger, indicating smaller lifetimes. We also find that the oscillation modes are more asymmetric in active regions than those in quiet regions, indicating that modes in active regions are excited closer to the surface. While the increase in mode frequency is monotonic in frequency, all other characteristics show more complex frequency dependences.

  20. Tropical Pacific nutrient dynamics in the modern and pleistocene ocean : insights from the nitrogen isotope system

    E-Print Network [OSTI]

    Rafter, Patrick Anthony

    2009-01-01T23:59:59.000Z

    nitrogen isotopes, an enrichment that is conventionallyisotopes upon denitrification also imparts a strong isotopic enrichment

  1. Spatial periphery of lithium isotopes

    SciTech Connect (OSTI)

    Galanina, L. I., E-mail: galan_lidiya@mail.ru; Zelenskaja, N. S. [Moscow State University, Skobeltsyn Institute of Nuclear Physics (Russian Federation)

    2013-12-15T23:59:59.000Z

    The spatial structure of lithium isotopes is studied with the aid of the charge-exchange and (t, p) reactions on lithium nuclei. It is shown that an excited isobaric-analog state of {sup 6}Li (0{sup +}, 3.56MeV) has a halo structure formed by a proton and a neutron, that, in the {sup 9}Li nucleus, there is virtually no neutron halo, and that {sup 11}Li is a Borromean nucleus formed by a {sup 9}Li core and a two-neutron halo manifesting itself in cigar-like and dineutron configurations.

  2. Isotopic Scaling in Nuclear Reactions

    E-Print Network [OSTI]

    M. B. Tsang; W. A. Friedman; C. K. Gelbke; W. G. Lynch; G. Verde; H. Xu

    2001-03-26T23:59:59.000Z

    A three parameter scaling relationship between isotopic distributions for elements with Z$\\leq 8$ has been observed that allows a simple description of the dependence of such distributions on the overall isospin of the system. This scaling law (termed iso-scaling) applies for a variety of reaction mechanisms that are dominated by phase space, including evaporation, multifragmentation and deeply inelastic scattering. The origins of this scaling behavior for the various reaction mechanisms are explained. For multifragmentation processes, the systematics is influenced by the density dependence of the asymmetry term of the equation of state.

  3. Stable carbon and nitrogen isotope enrichment in primate tissues

    E-Print Network [OSTI]

    Crowley, Brooke E.; Carter, Melinda L.; Karpanty, Sarah M.; Zihlman, Adrienne L.; Koch, Paul L.; Dominy, Nathaniel J.

    2010-01-01T23:59:59.000Z

    carbon and nitrogen isotope enrichment in primate tissuesfactor (a) and isotope enrichment values (e), which provideisotope values from different modern primate tissues. Additionally, using these mean apparent enrichment

  4. CRAD, Engineering - Oak Ridge National Laboratory High Flux Isotope...

    Broader source: Energy.gov (indexed) [DOE]

    Engineering - Oak Ridge National Laboratory High Flux Isotope Reactor Contractor ORR CRAD, Engineering - Oak Ridge National Laboratory High Flux Isotope Reactor Contractor ORR...

  5. CRAD, Engineering - Oak Ridge National Laboratory High Flux Isotope...

    Broader source: Energy.gov (indexed) [DOE]

    Oak Ridge National Laboratory High Flux Isotope Reactor CRAD, Engineering - Oak Ridge National Laboratory High Flux Isotope Reactor February 2007 A section of Appendix C to DOE G...

  6. aluminium isotopes: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CERN Preprints Summary: Currently, 31 actinium, 31 thorium, 28 protactinium, and 23 uranium isotopes have so far been observed; the discovery of these isotopes is discussed. For...

  7. americium isotopes: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CERN Preprints Summary: Currently, 31 actinium, 31 thorium, 28 protactinium, and 23 uranium isotopes have so far been observed; the discovery of these isotopes is discussed. For...

  8. astatine isotopes: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CERN Preprints Summary: Currently, 31 actinium, 31 thorium, 28 protactinium, and 23 uranium isotopes have so far been observed; the discovery of these isotopes is discussed. For...

  9. A Helium Isotope Perspective On The Dixie Valley, Nevada, Hydrothermal...

    Open Energy Info (EERE)

    Helium Isotope Perspective On The Dixie Valley, Nevada, Hydrothermal System Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: A Helium Isotope...

  10. Fractionation of Oxygen Isotopes in Phosphate during its Interactions...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fractionation of Oxygen Isotopes in Phosphate during its Interactions with Iron Oxides. Fractionation of Oxygen Isotopes in Phosphate during its Interactions with Iron Oxides....

  11. applied isotope techniques: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    M. 22 Applied Radiation and Isotopes 55 (2001) 707713 Bronchial dosimeter for radon progeny Biology and Medicine Websites Summary: Applied Radiation and Isotopes 55 (2001)...

  12. Dynamical mean-field theory and weakly non-linear analysis for the phase separation of active Brownian particles

    E-Print Network [OSTI]

    Thomas Speck; Andreas M. Menzel; Julian Bialké; Hartmut Löwen

    2015-03-29T23:59:59.000Z

    Recently, we have derived an effective Cahn-Hilliard equation for the phase separation dynamics of active Brownian particles by performing a weakly non-linear analysis of the effective hydrodynamic equations for density and polarization [Phys. Rev. Lett. 112, 218304 (2014)]. Here we develop and explore this strategy in more detail and show explicitly how to get to such a large-scale, mean-field description starting from the microscopic dynamics. The effective free energy emerging from this approach has the form of a conventional Ginzburg-Landau function. On the coarsest scale, our results thus agree with the mapping of active phase separation onto that of passive fluids with attractive interactions through a global effective free energy (mobility-induced phase transition). Particular attention is paid to the square-gradient term necessary for the dynamics. We finally discuss results from numerical simulations corroborating the analytical results.

  13. Isotope Enrichment Detection by Laser Ablation - Dual Tunable Diode Laser Absorption Spectrometry

    SciTech Connect (OSTI)

    Anheier, Norman C.; Bushaw, Bruce A.

    2009-07-01T23:59:59.000Z

    The rapid global expansion of nuclear energy is motivating the expedited development of new safeguards technology to mitigate potential proliferation threats arising from monitoring gaps within the uranium enrichment process. Current onsite enrichment level monitoring methods are limited by poor sensitivity and accuracy performance. Offsite analysis has better performance, but this approach requires onsite hand sampling followed by time-consuming and costly post analysis. These limitations make it extremely difficult to implement comprehensive safeguards accounting measures that can effectively counter enrichment facility misuse. In addition, uranium enrichment by modern centrifugation leads to a significant proliferation threat, since the centrifuge cascades can quickly produce a significant quantity of highly enriched uranium (HEU). The Pacific Northwest National Laboratory is developing an engineered safeguards approach having continuous aerosol particulate collection and uranium isotope analysis to provide timely detection of HEU production in a low enriched uranium facility. This approach is based on laser vaporization of aerosol particulate samples, followed by wavelength tuned laser diode spectroscopy, to characterize the 235U/238U isotopic ratio by subtle differences in atomic absorption wavelengths arising from differences in each isotope’s nuclear mass, volume, and spin (hyperfine structure for 235U). Environmental sampling media is introduced into a small, reduced pressure chamber, where a focused pulsed laser vaporizes a 10 to 20-µm sample diameter. The ejected plasma forms a plume of atomic vapor. A plume for a sample containing uranium has atoms of the 235U and 238U isotopes present. Tunable diode lasers are directed through the plume to selectively excite each isotope and their presence is detected by monitoring absorbance signals on a shot-to-shot basis. Single-shot detection sensitivity approaching the femtogram range and abundance uncertainty less than 10% have been demonstrated with measurements on surrogate materials. In this paper we present measurement results on samples containing background materials (e.g., dust, minerals, soils) laced with micron-sized target particles having isotopic ratios ranging from 1 to 50%.

  14. Submited to Trans. on CAD Revised Version Probabilistic Modeling of Dependencies During Switching Activity Analysis

    E-Print Network [OSTI]

    Pedram, Massoud

    synthesis have become primary concerns for the CAD community. To calculate average power consumption lag-one Markov Chains and conditional probabilities to manage complex spatiotemporal correlations. Two on these notions, it is shown that the relative error in calculating the switching activity of a logic gate using

  15. Transportation impact analysis for the shipment of low specific activity nitric acid. Revisison 1

    SciTech Connect (OSTI)

    Green, J.R.

    1995-05-16T23:59:59.000Z

    This is in support of the Plutonium-Uranium Extraction (PUREX) Facility Low Specific Activity (LSA) Nitric Acid Shipment Environmental Assessment. It analyzes potential toxicological and radiological risks associated with transportation of PUREX Facility LSA Nitric Acid from the Hanford Site to Portsmouth VA, Baltimore MD, and Port Elizabeth NJ.

  16. Fusion-neutron-yield, activation measurements at the Z accelerator: Design, analysis, and sensitivity

    SciTech Connect (OSTI)

    Hahn, K. D., E-mail: kdhahn@sandia.gov; Ruiz, C. L.; Fehl, D. L.; Chandler, G. A.; Knapp, P. F.; Smelser, R. M.; Torres, J. A. [Sandia National Laboratories, Diagnostics and Target Physics, Albuquerque, New Mexico 87123 (United States)] [Sandia National Laboratories, Diagnostics and Target Physics, Albuquerque, New Mexico 87123 (United States); Cooper, G. W.; Nelson, A. J. [Department of Chemical and Nuclear Engineering, University of New Mexico, Albuquerque, New Mexico 87131 (United States)] [Department of Chemical and Nuclear Engineering, University of New Mexico, Albuquerque, New Mexico 87131 (United States); Leeper, R. J. [Los Alamos National Laboratories, Plasma Physics Group, Los Alamos, New Mexico 87545 (United States)] [Los Alamos National Laboratories, Plasma Physics Group, Los Alamos, New Mexico 87545 (United States)

    2014-04-15T23:59:59.000Z

    We present a general methodology to determine the diagnostic sensitivity that is directly applicable to neutron-activation diagnostics fielded on a wide variety of neutron-producing experiments, which include inertial-confinement fusion (ICF), dense plasma focus, and ion beam-driven concepts. This approach includes a combination of several effects: (1) non-isotropic neutron emission; (2) the 1/r{sup 2} decrease in neutron fluence in the activation material; (3) the spatially distributed neutron scattering, attenuation, and energy losses due to the fielding environment and activation material itself; and (4) temporally varying neutron emission. As an example, we describe the copper-activation diagnostic used to measure secondary deuterium-tritium fusion-neutron yields on ICF experiments conducted on the pulsed-power Z Accelerator at Sandia National Laboratories. Using this methodology along with results from absolute calibrations and Monte Carlo simulations, we find that for the diagnostic configuration on Z, the diagnostic sensitivity is 0.037% ± 17% counts/neutron per cm{sup 2} and is ? 40% less sensitive than it would be in an ideal geometry due to neutron attenuation, scattering, and energy-loss effects.

  17. REAL-TIME OBJECT RECOGNITION BASED ON ACTIVE VISION AND SEQUENTIAL ANALYSIS

    E-Print Network [OSTI]

    Behnke, Sven

    and invariant transformations, or by means of sensor adaptation. Active Vision can be defined as control of all noises. The simple pan-tilt movement of the camera allows to observe objects placed outside of the camera luminance simultaneously. Camera control means the change of internal electrical parameters or movement

  18. Advanced Mass Spectrometers for Hydrogen Isotope Analyses

    SciTech Connect (OSTI)

    Chastagner, P.

    2001-08-01T23:59:59.000Z

    This report is a summary of the results of a joint Savannah River Laboratory (SRL) - Savannah River Plant (SRP) ''Hydrogen Isotope Mass Spectrometer Evaluation Program''. The program was undertaken to evaluate two prototype hydrogen isotope mass spectrometers and obtain sufficient data to permit SRP personnel to specify the mass spectrometers to replace obsolete instruments.

  19. Positive and inverse isotope effect on superconductivity

    E-Print Network [OSTI]

    Tian De Cao

    2009-09-04T23:59:59.000Z

    This article improves the BCS theory to include the inverse isotope effect on superconductivity. An affective model can be deduced from the model including electron-phonon interactions, and the phonon-induced attraction is simply and clearly explained on the electron Green function. The focus of this work is on how the positive or inverse isotope effect occurs in superconductors.

  20. MARK E. CONRAD Center for Isotope Geochemistry

    E-Print Network [OSTI]

    Ajo-Franklin, Jonathan

    with stable isotopes, fate and transport of groundwater contaminants, vadose zone hydrology, metal uptake by lichens, paleoclimatic patterns in California and stable isotope systematics of clay minerals. Geologist of gold property in the Mother Lode of California. Exploration Geologist (Anaconda Minerals Company; 6

  1. The Quest for the Heaviest Uranium Isotope

    E-Print Network [OSTI]

    S. Schramm; D. Gridnev; D. V. Tarasov; V. N. Tarasov; W. Greiner

    2012-01-17T23:59:59.000Z

    We study Uranium isotopes and surrounding elements at very large neutron number excess. Relativistic mean field and Skyrme-type approaches with different parametrizations are used in the study. Most models show clear indications for isotopes that are stable with respect to neutron emission far beyond N=184 up to the range of around N=258.

  2. Isotope separation by selective photodissociation of glyoxal

    DOE Patents [OSTI]

    Marling, John B. (Pleasanton, CA)

    1976-01-01T23:59:59.000Z

    Dissociation products, mainly formaldehyde and carbon monoxide, enriched in a desired isotope of carbon, oxygen, or hydrogen are obtained by the selective photodissociation of glyoxal wherein glyoxal is subjected to electromagnetic radiation of a predetermined wavelength such that photon absorption excites and induces dissociation of only those molecules of glyoxal containing the desired isotope.

  3. [Carbon isotope fractionation inplants]. Final report

    SciTech Connect (OSTI)

    O`Leary, M.H.

    1990-12-31T23:59:59.000Z

    The objectives of this research are: To develop a theoretical and experimental framework for understanding isotope fractionations in plants; and to develop methods for using this isotope fractionation for understanding the dynamics of CO{sub 2} fixation in plants. Progress is described.

  4. Developing the Sandia National Laboratories transportation infrastructure for isotope products and wastes

    SciTech Connect (OSTI)

    Trennel, A.J.

    1995-12-31T23:59:59.000Z

    Certain radioactive isotopes for North American and especially the United States` needs are enormously important to the medical community and their numerous patients. The most important medical isotope is {sup 99}Mo, which is currently manufactured by Nordion International Inc. in a single, aging reactor operated by Atomic Energy of Canada, Ltd. The reactor`s useful life is expected to end at the turn of the century. Production loss because of reactor shutdown possibilities prompted the US Congress to direct the DOE to provide for a US backup source for this crucial isotope. The SNL Annular Core Research Reactor (ACRR) was evaluated as a site to provide {sup 99}Mo initially and other isotopes that can be economically extracted from the process. Medical isotope production at SNL is a new venture in manufacturing. Should SNL be selected and the project reach the manufacturing stage, SNL would expect to service up to 30% of the US market under normal circumstances as a backup to the Canadian supply with the capability to service 100% should the need arise. The demand for {sup 99}Mo increases each year; hence, the proposed action accommodates growth in demand to meet this increase. The proposed project would guarantee the supply of medical isotopes would continue if either the irradiation or processing activities in Canada were interrupted.

  5. Determination of arsenic, molybdenum, uranium and vanadium in seawater by neutron activation analysis after preconcentration by colloid flotation

    SciTech Connect (OSTI)

    Murthy, R.S.S.; Ryan, D.E.

    1983-04-01T23:59:59.000Z

    Colloid flotation of arsenic, molybdenum, uranium, and vanadium on hydrous iron(III) oxide permits rapid collection of the precipitate for neutron activation analysis. The precipitate is floated, in the presence of sodium dodecyl sulfate and tiny nitrogen bubbles, from 1 L of seawater at pH 5.7 +/- 0.2. Except for uranium, recoveries are better than 95%; about 75% of the uranium was recovered. Selenium(IV) and tungsten(VI) can be similarly collected but their natural concentration levels in seawater are below detection limits for 1 L volumes.

  6. Journal of the Geological Society, London, Vol. 155, 1998, pp. 773785. Printed in Great Britain Mineralogy, sulphur isotope geochemistry and the development of sulphide structures

    E-Print Network [OSTI]

    Mineralogy, sulphur isotope geochemistry and the development of sulphide structures at the Broken Spur mineralogy and sulphur isotope analysis. Young mound sulphides from Broken Spur have a pyrrhotite- dominated mineralogy unusual for bare ridge vent systems. However, pyrrhotite is metastable and is ultimately converted

  7. Calculational analysis of structural activation induced by 20-100 MeV proton beam loss in high-power linear accelerators

    E-Print Network [OSTI]

    Lee, Stacey Kirsten

    1994-01-01T23:59:59.000Z

    fulfillment of the requirements for the degree of MASTER OF SCIENCE August 1994 Major Subject: Nuclear Engineering CALCULATIONAL ANALYSIS OF STRUCTURAL ACTIVATION INDUCED BY 20-100 MEV PROTON BEAM LOSS IN HIGH-POWER LINEAR ACCELERATORS A Thesis...) Carl A. Beard (Member) / John . Poston (Head of Department) August 1994 Major Subject: Nuclear Engineering ABSTRACT Calculational Analysis of Structural Activation Induced by 20-100 MeV Proton Beam Loss in High-Power Linear Accelerators. (August...

  8. Analysis methods for solar heating and cooling applications: passive and active systems. 2nd edition

    SciTech Connect (OSTI)

    None

    1980-01-01T23:59:59.000Z

    Brief descriptions of analysis methods and design tools which are valuable in performing parametric studies of candidate designs are presented in this brochure. The methods included range from rules-of-thumb for builders to the simulation packages used by researchers. (MHR)

  9. Using multi-voxel pattern analysis of fMRI data to interpret overlapping functional activations

    E-Print Network [OSTI]

    Downing, Paul

    by the two experimental conditions (but not the respective controls). For example, this interpretation has.A. et al. (2006) Beyond mind-reading: multi-voxel pattern analysis of fMRI data. Trends Cogn. Sci. 10 di Pellegrino, G. et al. (1992) Understanding motor events: a neurophysiological study. Exp. Brain

  10. Proton induced activation in mercury: Comparison of measurements and calculations

    SciTech Connect (OSTI)

    Remec, Igor [ORNL; Glasgow, David C [ORNL; Haines, John R [ORNL; Johnson, Jeffrey O [ORNL

    2008-01-01T23:59:59.000Z

    Measurements and simulations of the proton beam interaction with the mercury target were performed to support Spallation Neutron Source design. Due to the abundance of isotopes produced in mercury, the long delay between the irradiation and the measurements, and the self-shielding of the mercury sample, the measurements were difficult to perform and the activities of several isotopes have large uncertainties. Calculations predicted the activities of the most reliably measured isotopes within 20%/40%; however, some large discrepancies were observed for some isotopes for which the measurements were considered less reliable. Predicted dose rates were in very good agreement with the measurements.

  11. Determination of oxygen in molten alkali halide salts by proton activation analysis

    SciTech Connect (OSTI)

    Wai, C.M.; Dysart, M.E.

    1986-12-01T23:59:59.000Z

    The authors have recently used a lanthanum fluoride precipitation method to separate /sup 18/F produced from proton activation of /sup 18/O in alkali chloride and fluoride salts. The procedure was developed for studying dissolved oxide species in alkali halide melts. Determination of oxygen in these systems is important for research in batteries and in extractive metallurgy utilizing molten salts as solvents. The details are given oxygen determination in alkali chloride and fluoride systems.

  12. Modeling and analysis of a semi-active permanent magnet damper

    E-Print Network [OSTI]

    Lin, Wayne Chinn-Tzu

    1992-01-01T23:59:59.000Z

    Committee: Dr. Robin C, Redfield A method for employing a linear electromagnetic motor as a semi-active damper is proposed. This strategy is based on two physical principles: Faraday's law and Lenz's law. Unlike a hydraulic damper, which has fluid... compressibility and inertia problems at high input frequencies, the magnetic damper, because of its low inductance, presents minimal complications due to compliance. Furthermore, the linear motor's damping levels can be adjusted electronically, either through a...

  13. ISOTOPES

    E-Print Network [OSTI]

    Lederer, C. Michael

    2013-01-01T23:59:59.000Z

    constructed to enrich liquid UF6 slightly as feed for thej) b. Optimum a. s: .X. UF6 feed, (kg per year) XBL 7912 -

  14. ISOTOPES

    E-Print Network [OSTI]

    Lederer, C. Michael

    2013-01-01T23:59:59.000Z

    lithium hydroxide (56, 14), A plant utilizing this reaction to produce 1000 kg per year of 99.99% 7Li at a price

  15. ISOTOPES

    E-Print Network [OSTI]

    Lederer, C. Michael

    2013-01-01T23:59:59.000Z

    §fissile materials in fast breeder reactors currently underwater reactor, FBR = fast breeder reactor. The band belowinc 1 udes heavy-water reactors, fast breeders, and 11

  16. ISOTOPES

    E-Print Network [OSTI]

    Lederer, C. Michael

    2013-01-01T23:59:59.000Z

    1978). United States Gas Centrifuge Program for 72. Energy~~;h)radius in a gas centrifuge with va 400 m/s. P 0 and U68,14) of a gas centrifuge with radius = 0.09145 m, length=

  17. ISOTOPES

    E-Print Network [OSTI]

    Lederer, C. Michael

    2013-01-01T23:59:59.000Z

    the columns used to separate UF5, which had a separativeof uranium by dissociation of UF5, by multiple vibrational

  18. Atomic vapor laser isotope separation of lead-210 isotope

    DOE Patents [OSTI]

    Scheibner, K.F.; Haynam, C.A.; Johnson, M.A.; Worden, E.F.

    1999-08-31T23:59:59.000Z

    An isotopically selective laser process and apparatus for removal of Pb-210 from natural lead that involves a one-photon near-resonant, two-photon resonant excitation of one or more Rydberg levels, followed by field ionization and then electrostatic extraction. The wavelength to the near-resonant intermediate state is counter propagated with respect to the second wavelength required to populate the final Rydberg state. This scheme takes advantage of the large first excited state cross section, and only modest laser fluences are required. The non-resonant process helps to avoid two problems: first, stimulated Raman Gain due to the nearby F=3/2 hyperfine component of Pb-207 and, second, direct absorption of the first transition process light by Pb-207. 5 figs.

  19. Atomic vapor laser isotope separation of lead-210 isotope

    DOE Patents [OSTI]

    Scheibner, Karl F. (Tracy, CA); Haynam, Christopher A. (Pleasanton, CA); Johnson, Michael A. (Pleasanton, CA); Worden, Earl F. (Diablo, CA)

    1999-01-01T23:59:59.000Z

    An isotopically selective laser process and apparatus for removal of Pb-210 from natural lead that involves a one-photon near-resonant, two-photon resonant excitation of one or more Rydberg levels, followed by field ionization and then electrostatic extraction. The wavelength to the near-resonant intermediate state is counter propagated with respect to the second wavelength required to populate the final Rydberg state. This scheme takes advantage of the large first excited state cross section, and only modest laser fluences are required. The non-resonant process helps to avoid two problems: first, stimulated Raman Gain due to the nearby F=3/2 hyperfine component of Pb-207 and, second, direct absorption of the first transition process light by Pb-207.

  20. Analysis and optimization of an active damping vehicle suspension subjected to random roadway disturbances

    E-Print Network [OSTI]

    Coker, Christopher Franklin

    1992-01-01T23:59:59.000Z

    the similarities between the transfer functions for the two systems. The numerators of the sprung mass acceleration and stroke transfer functions for the nominal system model, equations (3) and (4), are identical to the numerators of the corresponding transfer... damping, the nominal system model can exhibit marginally better performance than an idealized representation. Analysis of a cost function that combines sprung mass acceleration and suspension stroke shows that the optimal selection of the parameters...

  1. Selective trace determination of sulfur and aluminum using charged particle activation analysis

    E-Print Network [OSTI]

    Burton, Terrence Dale

    1974-01-01T23:59:59.000Z

    of aluminum, the detection limit for this method. Several high-purity metals ( gold, bismuth, antimony, palladium, and cobalt) with aluminum concentrations in the ppm range were examined with this nondestructive technique, and the data compared... in reagents used in chemical separation do not affect the analysis and surface contamination of an irradiated sample is usually not a source oi' error. Selectivity is inherently high because no two radioisotopes are the same with respect to their emissions...

  2. Rapid Detection of Biological and Chemical Threat Agents Using Physical Chemistry, Active Detection, and Computational Analysis

    SciTech Connect (OSTI)

    Chung, Myung; Dong, Li; Fu, Rong; Liotta, Lance; Narayanan, Aarthi; Petricoin, Emanuel; Ross, Mark; Russo, Paul; Zhou, Weidong; Luchini, Alessandra; Manes, Nathan; Chertow, Jessica; Han, Suhua; Kidd, Jessica; Senina, Svetlana; Groves, Stephanie

    2007-01-01T23:59:59.000Z

    Basic technologies have been successfully developed within this project: rapid collection of aerosols and a rapid ultra-sensitive immunoassay technique. Water-soluble, humidity-resistant polyacrylamide nano-filters were shown to (1) capture aerosol particles as small as 20 nm, (2) work in humid air and (3) completely liberate their captured particles in an aqueous solution compatible with the immunoassay technique. The immunoassay technology developed within this project combines electrophoretic capture with magnetic bead detection. It allows detection of as few as 150-600 analyte molecules or viruses in only three minutes, something no other known method can duplicate. The technology can be used in a variety of applications where speed of analysis and/or extremely low detection limits are of great importance: in rapid analysis of donor blood for hepatitis, HIV and other blood-borne infections in emergency blood transfusions, in trace analysis of pollutants, or in search of biomarkers in biological fluids. Combined in a single device, the water-soluble filter and ultra-sensitive immunoassay technique may solve the problem of early â??warning typeâ?ť detection of aerosolized pathogens. These two technologies are protected with five patent applications and are ready for commercialization.

  3. New Mexico Center for Isotopes in Medicine

    SciTech Connect (OSTI)

    Burchiel, Scott W.

    2012-12-13T23:59:59.000Z

    The purpose of the New Mexico Center for Isotopes in Medicine (NMCIM) is to support research, education and service missions of the UNM College of Pharmacy Radiopharmaceutical Sciences Program (COP RSP) and the Cancer Research and Treatment Center (CRTC). NMCIM developed and coordinated unique translational research in cancer radioimaging and radiotherapy agents based on novel molecules developed at UNM and elsewhere. NMCIM was the primary interface for novel radioisotopes and radiochemistries developed at the Los Alamos National Laboratory (LANL) for SPECT/PET imaging and therapy. NMCIM coordinated the use of the small animal imaging facility with the CRTC provided support services to assist investigators in their studies. NMCIM developed education and training programs that benefited professional, graduate, and postdoctoral students that utilized its unique facilities and technologies. UNM COP RSP has been active in writing research and training grants, as well as supporting contract research with industrial partners. The ultimate goal of NMCIM is to bring new radiopharmaceutical imaging and therapeutic agents into clinical trials that will benefit the health and well being of cancer and other patients in New Mexico and the U.S.

  4. Quality assurance guidance for laboratory assessment plates in support of EM environmental sampling and analysis activities

    SciTech Connect (OSTI)

    Not Available

    1994-05-01T23:59:59.000Z

    This document is one of several guidance documents developed to support the EM (DOE Environmental Restoration and Waste Management) Analytical Services program. Its purpose is to introduce assessment plates that can be used to conduct performance assessments of an organization`s or project`s ability to meet quality goals for analytical laboratory activities. These assessment plates are provided as non-prescriptive guidance to EM-support organizations responsible for collection of environmental data for remediation and waste management programs at DOE facilities. The assessments evaluate objectively all components of the analytical laboratory process to determine their proper selection and use.

  5. X-RAY FLUORESCENCE ANALYSIS OF HANFORD LOW ACTIVITY WASTE SIMULANTS METHOD DEVELOPMENT

    SciTech Connect (OSTI)

    Jurgensen, A; David Missimer, D; Ronny Rutherford, R

    2007-08-08T23:59:59.000Z

    The x-ray fluorescence laboratory (XRF) in the Analytical Development Directorate (ADD) of the Savannah River National Laboratory (SRNL) was requested to develop an x-ray fluorescence spectrometry method for elemental characterization of the Hanford Tank Waste Treatment and Immobilization Plant (WTP) pretreated low activity waste (LAW) stream to the LAW Vitrification Plant. The WTP is evaluating the potential for using XRF as a rapid turnaround technique to support LAW product compliance and glass former batching. The overall objective of this task was to develop an XRF analytical method that provides rapid turnaround time (<8 hours), while providing sufficient accuracy and precision to determine variations in waste.

  6. Applications of linear and nonlinear programming to the problems of curve fitting with special emphasis on a problem in activation analysis

    E-Print Network [OSTI]

    Berman, Bernard H

    1963-01-01T23:59:59.000Z

    IN ACTIVATION ANALYSIS A Thesis BERNARD Ho BERNAN Approved as to style and content bys Chairman of C t e 5c Head of Department August 1963 ACE NQIIIIZJMME?ZS I sincerely appreciate the assistance of Professor B. C. Moore~ chairman of my cosmittee... column vector, and 0 is the n-dimensional column vector whose components are all zeros CHAPTER 2 THE ACTIVATION ANALYSIS PROBLEN Ths Activation AnaIysis Laboratory at the A. and N. College of Texas is concerned w1tn the problem of analyzing the gamma...

  7. Crossing Active Faults on the Sakhalin II Onshore Pipeline Route: Pipeline Design and Risk Analysis

    SciTech Connect (OSTI)

    Mattiozzi, Pierpaolo [Snamprogetti-Saipem, Via Toniolo, 1, 61032 Fano (Italy); Strom, Alexander [Institute of Geospheres Dynamics, Leninskiy Avenue, 38, Building 1, 119334, Moscow (Russian Federation)

    2008-07-08T23:59:59.000Z

    Twin oil (20 and 24 inch) and gas (20 and 48 inch) pipeline systems stretching 800 km are being constructed to connect offshore hydrocarbon deposits from the Sakhalin II concession in the North to an LNG plant and oil export terminal in the South of Sakhalin island. The onshore pipeline route follows a regional fault zone and crosses individual active faults at 19 locations. Sakhalin Energy, Design and Construction companies took significant care to ensure the integrity of the pipelines, should large seismic induced ground movements occur during the Operational life of the facilities. Complex investigations including the identification of the active faults, their precise location, their particular displacement values and assessment of the fault kinematics were carried out to provide input data for unique design solutions. Lateral and reverse offset displacements of 5.5 and 4.5 m respectively were determined as the single-event values for the design level earthquake (DLE) - the 1000-year return period event. Within the constraints of a pipeline route largely fixed, the underground pipeline fault crossing design was developed to define the optimum routing which would minimize stresses and strain using linepipe materials which had been ordered prior to the completion of detailed design, and to specify requirements for pipe trenching shape, materials, drainage system, etc. Detailed Design was performed with due regard to actual topography and to avoid the possibility of the trenches freezing in winter, the implementation of specific drainage solutions and thermal protection measures.

  8. Crossing Active Faults on the Sakhalin II Onshore Pipeline Route: Analysis Methodology and Basic Design

    SciTech Connect (OSTI)

    Vitali, Luigino [Snamprogetti-Saipem, Via Toniolo, 1, 61032 Fano, Luigino (Italy); Mattiozzi, Pierpaolo [Snamprogetti-Saipem, Via Toniolo, 1, 61032 Fano (Italy)

    2008-07-08T23:59:59.000Z

    Twin oil (20 and 24 inch) and gas (20 and 48 inch) pipeline systems stretching 800 km are being constructed to connect offshore hydrocarbon deposits from the Sakhalin II concession in the North to an LNG plant and oil export terminal in the South of Sakhalin island. The onshore pipeline route follows a regional fault zone and crosses individual active faults at 19 locations. Sakhalin Energy, Design and Construction companies took significant care to ensure the integrity of the pipelines, should large seismic induced ground movements occur during the Operational life of the facilities. Complex investigations including the identification of the active faults, their precise location, their particular displacement values and assessment of the fault kinematics were carried out to provide input data for unique design solutions. Lateral and reverse offset displacements of 5.5 and 4.5 m respectively were determined as the single-event values for the design level earthquake (DLE)--the 1000-year return period event. Within the constraints of a pipeline route largely fixed, the underground pipeline fault crossing design was developed to define the optimum routing which would minimize stresses and strain using linepipe materials which had been ordered prior to the completion of detailed design, and to specify requirements for pipe trenching shape, materials, drainage system, etc. This Paper describes the steps followed to formulate the concept of the special trenches and the analytical characteristics of the Model.

  9. Analysis of ISM Activity-level Work Planning and Control Within DOE |

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613Portsmouth SitePresentations |StateNuclearWith all of theAdvancedAnalysis

  10. SAS2H Generated Isotopic Concentrations For B&W 15X15 PWR Assembly (SCPB:N/A)

    SciTech Connect (OSTI)

    J.W. Davis

    1996-08-29T23:59:59.000Z

    This analysis is prepared by the Mined Geologic Disposal System (MGDS) Waste Package Development Department (WPDD) to provide pressurized water reactor (PWR) isotopic composition data as a function of time for use in criticality analyses. The objectives of this evaluation are to generate burnup and decay dependant isotopic inventories and to provide these inventories in a form which can easily be utilized in subsequent criticality calculations.

  11. Isotopic composition of Silurian seawater

    SciTech Connect (OSTI)

    Knauth, L.P.; Kealy, S.; Larimer, S.

    1985-01-01T23:59:59.000Z

    Direct isotopic analyses of 21 samples of the Silurian hydrosphere preserved as fluid inclusions in Silurian halite deposits in the Michigan Basin Salina Group yield delta/sup 18/O, deltaD ranging from 0.2 to +5.9 and -26 to -73, respectively. delta/sup 18/O has the same range as observed for modern halite facies evaporite waters and is a few per thousand higher than 100 analyses of fluid inclusions in Permian halite. deltaD is about 20 to 30 per thousand lower than modern and Permian examples. The trajectory of evaporating seawater on a deltaD-delta/sup 18/O diagram initially has a positive slope of 3-6, but hooks strongly downward to negative values, the shape of the hook depending upon humidity. Halite begins to precipitate at delta values similar to those observed for the most /sup 18/O rich fluid inclusions. Subsequent evaporation yields progressively more negative delta values as observed for the fluid inclusions. The fluid inclusion data can be readily explained in terms of evaporating seawater and are consistent with the degree of evaporation deduced from measured bromide profiles. These data are strongly inconsistent with arguments that Silurian seawater was 5.5 per thousand depleted in /sup 18/O. delta/sup 18/O for evaporite waters is systematically related to that of seawater, and does not show a -5.5 per thousand shift in the Silurian, even allowing for variables which affect the isotope evaporation trajectory. The lower deltaD may indicate a component of gypsum dehydration waters or may suggest a D-depleted Silurian hydrosphere.

  12. The Role of Isotopes in Monitoring Water Quality Impacts Associated with Shale Gas Drilling

    E-Print Network [OSTI]

    Wang, Z. Jane

    The Role of Isotopes in Monitoring Water Quality Impacts Associated with Shale Gas Drilling Methane contamination is usually due to natural causes; however, it can also be the result of drilling activities, including shale gas drilling. Monitoring techniques exist for detecting methane and, in some cases

  13. Challenges in Determining the Isotopic Mixture for the Fukushima Daiichi Nuclear Power Plant

    SciTech Connect (OSTI)

    Shanks, Arthur [Sandia National Laboratories; Fournier, Sean [Sandia National Laboratories; Shanks, Sonoya [Sandia National Laboratories

    2012-05-01T23:59:59.000Z

    As part of the United States response to the Fukushima Daiichi Nuclear Power Plant emergency, the National Nuclear Security Administration (NNSA) Consequence Management (CM) Teams were activated with elements deploying to Japan. The NNSA CM teams faced the urgent need for information regarding the potential radiological doses that citizens of might experience. This paper discusses the challenges and lessons learned associated with the analysis of field collected samples and gamma spectra in an attempt to determine the isotopic mixture present on the ground around the Plant. There were several interesting and surprising lessons to be learned from the sample analysis portion of the response. The paper discusses several elements of the response that were unique to the event occurring in Japan, as well as several elements that would have occurred in a U.S. nuclear reactor event. Sections of this paper address details of the specific analytical challenges faced during the efforts to analyze samples and try to understand the overall release source term.

  14. Comparison of isotopic transmutation modelling codes

    E-Print Network [OSTI]

    Beard, Carl Allen

    1990-01-01T23:59:59.000Z

    . Numerical solutions to the equations that govern isotopic transmutation can be obtained in several ways. Each method possesses a certain amount of intrinsic error which is inherent in the solution scheme, but which can also vary depending upon... of the removed nuclide if it falls between two long-lived isotopes, or by adding the initial concentration of the short-lived isotope to the first long-lived nuclide which occurs in the production chain. In this second case, the final contribution from...

  15. Theory of the helium isotope shift

    E-Print Network [OSTI]

    Yerokhin, Vladimir A

    2015-01-01T23:59:59.000Z

    Theory of the isotope shift of the centroid energies of light few-electron atoms is reviewed. Numerical results are presented for the isotope shift of the $2^3P$-$2^3S$ and $2^1S$-$2^3S$ transition energies of $^3$He and $^4$He. By comparing theoretical predictions for the isotope shift with the experimental results, the difference of the squares of the nuclear charge radii of $^3$He and $^4$He, $\\delta R^2$, is determined with high accuracy.

  16. Elemental characterization of the Avogadro silicon crystal WASO 04 by neutron activation analysis

    E-Print Network [OSTI]

    D'Agostino, Giancarlo; Giordani, Laura; Mana, Giovanni; Massa, Enrico; Oddone, Massimo; 10.1088/0026-1394/49/6/696

    2013-01-01T23:59:59.000Z

    Analytical measurements of the 28Si crystal used for the determination of the Avogadro constant are essential to prevent biased results or under-estimated uncertainties. A review of the existing data confirms the high-purity of silicon with respect to a large number of elements. In order to obtain a direct evidence of purity, we developed a relative analytical method based on neutron activation. As a preliminary test, this method was applied to a sample of the Avogadro crystal WASO 04. The investigation concerned twenty-nine elements. The mass fraction of Au was quantified to be 1.03(18) x 10-12. For the remaining twenty-eight elements, the mass fractions are below the detection limits, which range between 1 x 10-12 and 1 x 10-5.

  17. Analysis, Dimensioning and Robust Control of Shunt Active Filter for Harmonic Currents Compensation in Electrical Mains

    E-Print Network [OSTI]

    Tilli, Andrea; Conficoni, Christian

    2011-01-01T23:59:59.000Z

    In this chapter some results related to Shunt Active Filters (SAFs) and obtained by the authors and some coauthors are reported. SAFs are complex power electronics equipments adopted to compensate for cur-rent harmonic pollution in electric mains, due to nonlinear loads. By using a proper "floating" capacitor as energy reservoir, the SAF purpose is to inject in the line grid currents canceling the polluting har-monics. Control algorithms play a key role for such devices and, in general, in many power electronics applications. Moreover, systems theory is crucial, since it is the mathematical tool that enables a deep understanding of the involved dynamics of such systems, allowing a correct dimensioning, beside an effective control. As a matter of facts, current injection objective can be straightforwardly formulated as an output tracking control problem. In this fashion, the structural and insidious marginally-stable internal/zero dynamics of SAFs can be immediately highlighted and characterized in terms of si...

  18. Stable isotope signatures for characterising the biological stability of landfilled municipal solid waste

    SciTech Connect (OSTI)

    Wimmer, Bernhard, E-mail: bernhard.wimmer@ait.ac.at [AIT Austrian Institute of Technology GmbH, Health and Environment Department, Environmental Resources and Technologies, Konrad-Lorenz-Strasse 24, 3430 Tulln (Austria); Hrad, Marlies; Huber-Humer, Marion [Institute of Waste Management, Department of Water-Atmosphere-Environment, University of Natural Resources and Life Sciences, Muthgasse 107, 1190 Vienna (Austria); Watzinger, Andrea; Wyhlidal, Stefan; Reichenauer, Thomas G. [AIT Austrian Institute of Technology GmbH, Health and Environment Department, Environmental Resources and Technologies, Konrad-Lorenz-Strasse 24, 3430 Tulln (Austria)

    2013-10-15T23:59:59.000Z

    Highlights: ? The isotopic signature of ?{sup 13}C-DIC of leachates is linked to the reactivity of MSW. ? Isotopic signatures of leachates depend on aerobic/anaerobic conditions in landfills. ? In situ aeration of landfills can be monitored by isotope analysis in leachate. ? The isotopic analysis of leachates can be used for assessing the stability of MSW. ? ?{sup 13}C-DIC of leachates helps to define the duration of landfill aftercare. - Abstract: Stable isotopic signatures of landfill leachates are influenced by processes within municipal solid waste (MSW) landfills mainly depending on the aerobic/anaerobic phase of the landfill. We investigated the isotopic signatures of ?{sup 13}C, ?{sup 2}H and ?{sup 18}O of different leachates from lab-scale experiments, lysimeter experiments and a landfill under in situ aeration. In the laboratory, columns filled with MSW of different age and reactivity were percolated under aerobic and anaerobic conditions. In landfill simulation reactors, waste of a 25 year old landfill was kept under aerobic and anaerobic conditions. The lysimeter facility was filled with mechanically shredded fresh waste. After starting of the methane production the waste in the lysimeter containments was aerated in situ. Leachate and gas composition were monitored continuously. In addition the seepage water of an old landfill was collected and analysed periodically before and during an in situ aeration. We found significant differences in the ?{sup 13}C-value of the dissolved inorganic carbon (?{sup 13}C-DIC) of the leachate between aerobic and anaerobic waste material. During aerobic degradation, the signature of ?{sup 13}C-DIC was mainly dependent on the isotopic composition of the organic matter in the waste, resulting in a ?{sup 13}C-DIC of ?20‰ to ?25‰. The production of methane under anaerobic conditions caused an increase in ?{sup 13}C-DIC up to values of +10‰ and higher depending on the actual reactivity of the MSW. During aeration of a landfill the aerobic degradation of the remaining organic matter caused a decrease to a ?{sup 13}C-DIC of about ?20‰. Therefore carbon isotope analysis in leachates and groundwater can be used for tracing the oxidation–reduction status of MSW landfills. Our results indicate that monitoring of stable isotopic signatures of landfill leachates over a longer time period (e.g. during in situ aeration) is a powerful and cost-effective tool for characterising the biodegradability and stability of the organic matter in landfilled municipal solid waste and can be used for monitoring the progress of in situ aeration.

  19. JOURNAL DE PHYSIQUE Collogue C6, supplement au n" 8, Tome 39, aout 1978, page C6-1395 ISOTOPE EFFECTS IN SUPERCONDUCTING TRANSITION METAL HYDRIDES

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    - tivite plus basse pour le deuteride, une energie d'octivation plus elevee pour la diffusion et une the normal isotope effect with a lower su- perconducting temperature for the deuteride, a higher activation

  20. Helium isotopes in historical lavas from Mount Vesuvius Comment on `Noble gas isotopic ratios from historical lavas

    E-Print Network [OSTI]

    Graham, David W.

    Discussion Helium isotopes in historical lavas from Mount Vesuvius Comment on `Noble gas isotopic. Introduction Helium isotope results recently published by Tedesco et al. [1] appear to show a decrease in 3 He. Results Helium isotope results from our laboratory are reported in Table 1. The 3 He/4 He ratio has been

  1. Developing the Sandia National Laboratories transportation infrastructure for isotope products and wastes

    SciTech Connect (OSTI)

    Trennel, A.J.

    1997-11-01T23:59:59.000Z

    The US Department of Energy (DOE) plans to establish a medical isotope project that would ensure a reliable domestic supply of molybdenum-99 ({sup 99}Mo) and related medical isotopes (Iodine-125, Iodine-131, and Xenon-133). The Department`s plan for production will modify the Annular Core Research Reactor (ACRR) and associated hot cell facility at Sandia National Laboratories (SNL)/New Mexico and the Chemistry and Metallurgy Research facility at Los Alamos National Laboratory (LANL). Transportation activities associated with such production is discussed.

  2. Formation of Light Isotopes by Protons and Deuterons of 3.65 GeV/nucleon on Separated Tin Isotopes

    E-Print Network [OSTI]

    A. R. Balabekyan; A. S. Danagulyan; J. R. Drnoyan; G. H. Hovhannisyan; J. Adam; V. G. Kalinnikov; M. I. Krivopustov; V. S. Pronskikh; V. I. Stegailov; A. A. Solnyshkin; P. Chaloun; V. M. Tsoupko-Sitnikov; S. G. Mashnik; K. K. Gudima

    2005-06-22T23:59:59.000Z

    We measure cross sections for residual nuclide formation in the mass range 6 tin isotopes (112-Sn, 118-Sn, 120-Sn, 124-Sn). The experimental data are compared with calculations by the codes FLUKA, LAHET, CEM03, and LAQGSM03. Scaling behavior is observed for the whole mass region of residual nuclei, showing a possible multifragmentation mechanism for the formation of light products (6 < A < 31). Our analysis of the isoscaling dependence also shows a possible contribution of multifragmentation to the production of heavier nuclides, in the mass region 39 < A < 81.

  3. Degradation of Isotopic Lactate and Acetate

    E-Print Network [OSTI]

    Aronoff, S.

    2010-01-01T23:59:59.000Z

    prescribed, BaC03 from the degradation of Ba acetnte co~~above procedure by the degradation of sjnthetic radio-lacticNo. W-7405-Eng o -48 DEGRADATION OF ISOTOPIC LACTATE AND

  4. The Isotopic Abundances of Magnesium in Stars

    E-Print Network [OSTI]

    Pamela Gay; David L. Lambert

    1999-11-11T23:59:59.000Z

    Isotopic abundance ratios 24^Mg:25^Mg:26^Mg are derived for 20 stars from high- resolution spectra of the MgH A-X 0-0 band at 5140AA. With the exception of the weak g-band giant HR 1299, the stars are dwarfs that sample the metallicity range -1.8 < [Fe/H] <0.0. The abundance of 25^Mg amd 26^Mg relative to the dominant isotope 24^Mg decreases with decreasing [Fe/H] in fair accord with predictions from a recent model of galactic chemical evolution in which the Mg isotopes are synthesised by massive stars. Several stars appear especially enriched in the heavier Mg isotopes suggesting contamination by material from the envelopes of intermediate-mass AGB stars.

  5. Nonequilibrium clumped isotope signals in microbial methane

    E-Print Network [OSTI]

    Wang, David T.

    Methane is a key component in the global carbon cycle with a wide range of anthropogenic and natural sources. Although isotopic compositions of methane have traditionally aided source identification, the abundance of its ...

  6. A SUPERCONDUCTING-SOLENOID ISOTOPE SPECTROMETER

    E-Print Network [OSTI]

    O'Donnell, Tom

    A SUPERCONDUCTING-SOLENOID ISOTOPE SPECTROMETER FOR PRODUCTION OF NEUTRON-RICH NUCLEI ( 136 Xe Superconducting Cyclotron Laboratory's weekly \\Green Sheet," 30 July 1999 #12; c Thomas W. O'Donnell 2000 All

  7. Measurements of stable isotope ratios in milk samples from a farm placed in the mountains of Transylvania

    SciTech Connect (OSTI)

    Magdas, D. A., E-mail: gabriela.cristea@itim-cj.ro; Cristea, G., E-mail: gabriela.cristea@itim-cj.ro; Bot, A.; Puscas, R.; Radu, S.; Mirel, V. [National Institute for Research and Development of Isotopic and Molecular Technologies, 65-103 Donath Str., 400293 Cluj-Napoca (Romania)] [National Institute for Research and Development of Isotopic and Molecular Technologies, 65-103 Donath Str., 400293 Cluj-Napoca (Romania); Cordea, D. V.; Mihaiu, M. [University of Agricultural Science and Veterinary Medicine, 3-5 Calea Manastur, 400372 Cluj-Napoca (Romania)] [University of Agricultural Science and Veterinary Medicine, 3-5 Calea Manastur, 400372 Cluj-Napoca (Romania)

    2013-11-13T23:59:59.000Z

    Product origin is of great importance for consumers especially because its association in consumer's perception with food quality, freedom from disease or pollution. Stable isotope ratio analysis is a powerful technique in food authenticity and traceability control which has been introduced within the European wine industry to ensure authenticity of wine provenance and to detect adulteration. Isotopic ratios measurements have also been successfully to other food commodities like: fruit juices, honey and dairy foods. The ?{sup 18}O and ?{sup 2}H content in milk water reflects the isotope composition of the ground water drunk by animals. Seasonal effects are also very important: in summer, milk water contains higher ?{sup 18}O and ?{sup 2}H values due to the fresh plants that are ate by animals. Relative carbon stable isotope abundances in total milk reflect the isotopic composition of the diet fed to the dairy cows. In this study the hydrogen, oxygen and carbon isotopic composition of 15 milk samples coming from a unit placed in the mountains of Transylvania was investigated. The distribution of the obtained isotopic values was than discussed taking into account that all the animals were feed with the same type of forage and consumed water was taken from the same source.

  8. Carbon isotope fractionation in autotrophic Chromatium

    E-Print Network [OSTI]

    Wong, William Wai-Lun

    1974-01-01T23:59:59.000Z

    CARSON ISOTOPE FRACTIONATION IN AUTOTPOPHIC CHROYATIUN A Thesis 'JILLIAJJ J JAI LJJN BONG Submitted to the Graduate College of Texas A&H University in partial fulfillment of the requirenent for the degree of PLASTER OF SCIENCE August 1974...) August 1974 ABSTRACT Carbon Isotope Fractionation in Autotrophic Chromatium (August 1974) blilliam Wai-Lun Wang, B. S. , Texas Lutheran College Co-Chairmen of Advisory Committee: Dr. Isilliam N. Sackett Dr. Chauncey P. . Benedict Bacterial cells...

  9. Mass Parameterizations and Predictions of Isotopic Observables

    E-Print Network [OSTI]

    S. R. Souza; P. Danielewicz; S. Das Gupta; R. Donangelo; W. A. Friedman; W. G. Lynch; W. P. Tan; M. B. Tsang

    2003-03-24T23:59:59.000Z

    We discuss the accuracy of mass models for extrapolating to very asymmetric nuclei and the impact of such extrapolations on the predictions of isotopic observables in multifragmentation. We obtain improved mass predictions by incorporating measured masses and extrapolating to unmeasured masses with a mass formula that includes surface symmetry and Coulomb terms. We find that using accurate masses has a significant impact on the predicted isotopic observables.

  10. Sulfur isotope fractionation during oxidation of sulfur dioxide: gas-phase oxidation by OH radicals and aqueous oxidation by H2O2, O3 and iron catalysis

    E-Print Network [OSTI]

    Harris, E.

    The oxidation of SO[subscript 2] to sulfate is a key reaction in determining the role of sulfate in the environment through its effect on aerosol size distribution and composition. Sulfur isotope analysis has been used to ...

  11. Ion desolvation as a mechanism for kinetic isotope fractionation in aqueous systems

    E-Print Network [OSTI]

    Hofmann, A.E.

    2014-01-01T23:59:59.000Z

    equilibrium light?isotope  enrichment is a key unknown in of light?isotope  enrichment  during  precipitation.  possible light? isotope enrichment from diffusion?limited 

  12. NATIONAL USES AND NEEDS FOR SEPARATED STABLE ISOTOPES IN PHYSICS, CHEMISTRY, AND GEOSCIENCE RESEARCH

    E-Print Network [OSTI]

    Zisman, M.S.

    2010-01-01T23:59:59.000Z

    of purchasing a low-enrichment isotope and having it furtherfour main areas: of isotopes, marginal enrichment and a highthe allowing isotope much interest enrichment into play, in

  13. Oxygen isotope fractionation in the vacuum ultraviolet photodissociation of carbon monoxide: Wavelength, pressure and temperature dependency.

    E-Print Network [OSTI]

    Chakraborty, Subrata

    2013-01-01T23:59:59.000Z

    Oxygen isotope fractionation in the vacuum ultravioletmeasurement of the associated oxygen isotopic composition ofwavelength dependency of the oxygen isotopic composition in

  14. 99.996 %{sup 12}C films isotopically enriched and deposited in situ

    SciTech Connect (OSTI)

    Dwyer, K. J. [Department of Materials Science and Engineering, University of Maryland, College Park, Maryland 20740 (United States) [Department of Materials Science and Engineering, University of Maryland, College Park, Maryland 20740 (United States); National Institute of Standards and Technology, Gaithersburg, Maryland 20899-8423 (United States); Pomeroy, J. M.; Simons, D. S. [National Institute of Standards and Technology, Gaithersburg, Maryland 20899-8423 (United States)] [National Institute of Standards and Technology, Gaithersburg, Maryland 20899-8423 (United States)

    2013-06-24T23:59:59.000Z

    Ionizing natural abundance carbon dioxide gas, we extract and mass select the ions, depositing thin films isotopically enriched to 99.9961(4) %{sup 12}C as measured by secondary ion mass spectrometry (SIMS). In solid state quantum information, coherence times of nitrogen-vacancy (NV) centers in {sup 12}C enriched diamond exceeding milliseconds demonstrate the viability of NV centers as qubits, motivating improved isotopic enrichment. NV centers in diamond are particularly attractive qubit candidates due to the optical accessibility of the spin states. We present SIMS analysis and cross-sectional scanning electron microscopy of {sup 12}C enriched thin film samples grown with this method.

  15. La138/139 Isotopic Data and Neutron Fluences for Oklo RZ10 Reactor

    E-Print Network [OSTI]

    C. R. Gould; E. I. Sharapov

    2012-08-23T23:59:59.000Z

    Recent years have seen a renewed interest in the Oklo phenomenon, particularly in relation to the study of time variation of the fine structure constant. The neutron fluence is one of the crucial parameters for Oklo reactors. Several approaches to its determination were elaborated in the past. We consider whether it possible to use the present isotopic La138/139 data for RZ10 as an additional indicator of neutron fluences in the active cores of the reactors. We calculate the dependence of the Oklo La138 abundance on neutron fluence and elemental lanthanum concentration. The neutron fluence in RZ10 can be deduced from lanthanum isotopic data, but requires reliable data on the primordial elemental abundance. Conversely, if the fluence is known, the isotope ratio provides information on the primordial lanthanum abundance that is not otherwise easily determined.

  16. Carbon Dioxide Information Analysis Center and World Data Center-A for atmospheric trace gases: FY 1993 activities

    SciTech Connect (OSTI)

    Cushman, R.M. [Oak Ridge National Lab., TN (United States). Carbon Dioxide Information Analysis Center; Stoss, F.W. [Oak Ridge National Lab., TN (United States). Carbon Dioxide Information Analysis Center]|[Univ. of Tennessee, Knoxville, TN (United States). Energy, Environment, and Resources Center

    1994-01-01T23:59:59.000Z

    During the course of a fiscal year, Oak Ridge National Laboratory`s Carbon Dioxide Information Analysis Center (CDIAC) distributes thousands of specialty publications-numeric data packages (NDPs), computer model packages (CMPs), technical reports, public communication publications, newsletters, article reprints, and reference books-in response to requests for information related to global environmental issues, primarily those pertaining to climate change. CDIAC`s staff also provide technical responses to specific inquiries related to carbon dioxide (CO{sub 2}), other trace gases, and climate. Hundreds of referrals to other researchers, policy analysts, information specialists, or organizations are also facilitated by CDIAC`s staff. This report provides an account of the activities accomplished by CDIAC (including World Data Center-A for Atmospheric Trace Gases) during the period October 1, 1992, to September 30, 1993. An organizational overview of CDIAC and its staff is supplemented by a detailed description of inquiries received and CDIAC`s response to those inquiries. An analysis and description of the preparation and distribution of NDPS, CMPS, technical reports, newsletters, fact sheets, specialty publications, and reprints are provided. Comments and descriptions of CDIAC`s information management systems, professional networking, and special bilateral agreements are also presented.

  17. ANALYSIS OF OPTICAL Fe II EMISSION IN A SAMPLE OF ACTIVE GALACTIC NUCLEUS SPECTRA

    SciTech Connect (OSTI)

    Kovacevic, Jelena; Popovic, Luka C.; Dimitrijevic, Milan S., E-mail: jkovacevic@aob.bg.ac.r [Astronomical Observatory, Volgina 7, 11060 Belgrade (Serbia)

    2010-07-15T23:59:59.000Z

    We present a study of optical Fe II emission in 302 active galactic nuclei (AGNs) selected from the Sloan Digital Sky Survey. We group the strongest Fe II multiplets into three groups according to the lower term of the transition (b{sup 4} F, a{sup 6} S, and a{sup 4} G terms). These approximately correspond to the blue, central, and red parts, respectively, of the 'iron shelf' around H{beta}. We calculate an Fe II template that takes into account transitions into these three terms and an additional group of lines, based on a reconstruction of the spectrum of I Zw 1. This Fe II template gives a more precise fit of the Fe II lines in broad-line AGNs than other templates. We extract Fe II, H{alpha}, H{beta}, [O III], and [N II] emission parameters and investigate correlations between them. We find that Fe II lines probably originate in an intermediate line region. We note that the blue, red, and central parts of the iron shelf have different relative intensities in different objects. Their ratios depend on continuum luminosity, FWHM H{beta}, the velocity shift of Fe II, and the H{alpha}/H{beta} flux ratio. We examine the dependence of the well-known anti-correlation between the equivalent widths of Fe II and [O III] on continuum luminosity. We find that there is a Baldwin effect for [O III] but an inverse Baldwin effect for the Fe II emission. The [O III]/Fe II ratio thus decreases with L {sub {lambda}5100}. Since the ratio is a major component of the Boroson and Green Eigenvector 1 (EV1), this implies a connection between the Baldwin effect and EV1 and could be connected with AGN evolution. We find that spectra are different for H{beta} FWHMs greater and less than {approx}3000 km s{sup -1}, and that there are different correlation coefficients between the parameters.

  18. Natural thorium isotopes in marine sediment core off Labuan port

    SciTech Connect (OSTI)

    Hafidz, B. Y.; Asnor, A. S.; Terence, R. C.; Mohamed, C. A. R. [School of Environmental and Natural Resource Sciences, Faculty of Science and Technology, Universiti Kebangsaan Malaysia 43600, Bangi, Selangor (Malaysia)

    2014-02-12T23:59:59.000Z

    Sediment core was collected from Labuan port and analyzed to determine the radioactivity of thorium (Th) isotopes. The objectives of this study are to determine the possible sources of Th isotopes at Labuan port and estimates the sedimentation rate based on {sup 228}Th/{sup 232}Th model. The results suggest the {sup 230}Th and {sup 232}Th might be originated from terrestrial sedimentary rock while {sup 228}Th originated by authigenic origin. High ratio value of {sup 230}Th/{sup 232}Th detected at the top surface sediment indicates the increasing of {sup 230}Th at the recent years which might be contributed from the anthropogenic sources. The sedimentation rate of core sediment from Labuan Port was successfully estimated by using {sup 228}Th/{sup 232}Th model. The result show high sedimentation rate with 4.67 cm/year indicates rapid deposition occurred at this study area due to the high physical activity at the Labuan port. By assume the constant sedimentation rate at this area; we estimated the age of 142 cm core sediment obtained from Labuan port is 32 years started from 1981 to 2012. This chronology will be used in forthcoming research to investigate the historical profile of anthropogenic activities affecting the Labuan port.

  19. The Isotopic Mixture of Barium in the Metal-poor Subgiant HD 140283

    E-Print Network [OSTI]

    David L. Lambert; Carlos Allende Prieto

    2002-05-22T23:59:59.000Z

    Analyses of the abundances of neutron-capture elements have led to the belief that these elements in metal-poor stars are r-process products with relative abundances closely resembling those found in the solar system. This picture was challenged by Magain (1995), who found that a pure r-process mix of the barium isotopes was inconsistent with the mix of odd to even barium isotopes derived from analysis of the Ba II line at 4554 A in the spectrum of the metal-poor subgiant HD 140283. In this paper, we address Magain's challenge using new high resolution high signal-to-noise spectra of HD 140283, and find, in contrast to his result, that a solar-like r-process isotopic mixture provides a fair fit to the observed 4554 A profile.

  20. RAPID FUSION METHOD FOR DETERMINATION OF PLUTONIUM ISOTOPES IN LARGE RICE SAMPLES

    SciTech Connect (OSTI)

    Maxwell, S.

    2013-03-01T23:59:59.000Z

    A new rapid fusion method for the determination of plutonium in large rice samples has been developed at the Savannah River National Laboratory (Aiken, SC, USA) that can be used to determine very low levels of plutonium isotopes in rice. The recent accident at Fukushima Nuclear Power Plant in March, 2011 reinforces the need to have rapid, reliable radiochemical analyses for radionuclides in environmental and food samples. Public concern regarding foods, particularly foods such as rice in Japan, highlights the need for analytical techniques that will allow very large sample aliquots of rice to be used for analysis so that very low levels of plutonium isotopes may be detected. The new method to determine plutonium isotopes in large rice samples utilizes a furnace ashing step, a rapid sodium hydroxide fusion method, a lanthanum fluoride matrix removal step, and a column separation process with TEVA Resin? cartridges. The method can be applied to rice sample aliquots as large as 5 kg. Plutonium isotopes can be determined using alpha spectrometry or inductively-coupled plasma mass spectrometry (ICP-MS). The method showed high chemical recoveries and effective removal of interferences. The rapid fusion technique is a rugged sample digestion method that ensures that any refractory plutonium particles are effectively digested. The MDA for a 5 kg rice sample using alpha spectrometry is 7E-5 mBq g{sup -1}. The method can easily be adapted for use by ICP-MS to allow detection of plutonium isotopic ratios.

  1. The Multi-Isotope Process (MIP) Monitor Project: FY13 Final Report

    SciTech Connect (OSTI)

    Meier, David E.; Coble, Jamie B.; Jordan, David V.; Mcdonald, Luther W.; Forrester, Joel B.; Schwantes, Jon M.; Unlu, Kenan; Landsberger, Sheldon; Bender, Sarah; Dayman, Kenneth J.; Reilly, Dallas D.

    2013-09-01T23:59:59.000Z

    The Multi-Isotope Process (MIP) Monitor provides an efficient approach to monitoring the process conditions in reprocessing facilities in support of the goal of “… (minimization of) the risks of nuclear proliferation and terrorism.” The MIP Monitor measures the distribution of the radioactive isotopes in product and waste streams of a nuclear reprocessing facility. These isotopes are monitored online by gamma spectrometry and compared, in near-real-time, to spectral patterns representing “normal” process conditions using multivariate analysis and pattern recognition algorithms. The combination of multivariate analysis and gamma spectroscopy allows us to detect small changes in the gamma spectrum, which may indicate changes in process conditions. By targeting multiple gamma-emitting indicator isotopes, the MIP Monitor approach is compatible with the use of small, portable, relatively high-resolution gamma detectors that may be easily deployed throughout an existing facility. The automated multivariate analysis can provide a level of data obscurity, giving a built-in information barrier to protect sensitive or proprietary operational data. Proof-of-concept simulations and experiments have been performed in previous years to demonstrate the validity of this tool in a laboratory setting for systems representing aqueous reprocessing facilities. However, pyroprocessing is emerging as an alternative to aqueous reprocessing techniques.

  2. Resolving the stellar sources of isotopically rare presolar silicate grains through Mg and Fe isotopic analyses

    SciTech Connect (OSTI)

    Nguyen, Ann N.; Messenger, Scott, E-mail: lan-anh.n.nguyen@nasa.gov [Robert M. Walker Laboratory for Space Science, Astromaterials Research and Exploration Science Directorate, NASA Johnson Space Center, Houston, TX 77058 (United States)

    2014-04-01T23:59:59.000Z

    We conducted multi-element isotopic analyses of 11 presolar silicate grains from the Acfer 094 meteorite having unusual O isotopic compositions. Eight grains are {sup 18}O-rich, one is {sup 16}O-rich, and two are extremely {sup 17}O-rich. We constrained the grains' stellar sources by measuring their Si and Mg isotopic ratios, and also the {sup 54}Fe/{sup 56}Fe and {sup 57}Fe/{sup 56}Fe ratios for five grains. The Mg and Fe isotopic measurements were conducted after surrounding matrix grains were removed for more accurate ratios. Most of the {sup 18}O-rich silicates had anomalous Mg isotopic ratios, and their combined isotopic constraints are consistent with origins in low-mass Type II supernovae (SNe II) rather than high-metallicity stars. The isotopic ratios of the {sup 16}O-rich silicate are also consistent with an SN origin. Mixing small amounts of interior stellar material with the stellar envelope replicated all measured isotopic ratios except for {sup 29}Si/{sup 28}Si and {sup 54}Fe/{sup 56}Fe in some grains. The {sup 29}Si/{sup 28}Si ratios of all SN-derived grains are matched by doubling the {sup 29}Si yield in the Ne- and Si-burning zones. The {sup 54}Fe/{sup 56}Fe ratios of the grains imply elemental fractionation in the Si/S zone, or introduction of isotopically solar Fe by secondary processing. The two highly {sup 17}O-rich silicates exhibited significant {sup 25}Mg and/or {sup 26}Mg enrichments and their isotopic ratios are best explained by strong dilution of 1.15 M {sub ?} CO nova matter. We estimate that ?12% and 1% of presolar silicates have SN and nova origins, respectively, similar to presolar SiC and oxides. This implies that asymptotic giant branch stars are the dominant dust producers in the galaxy.

  3. NID Copper Sample Analysis

    SciTech Connect (OSTI)

    Kouzes, Richard T.; Zhu, Zihua

    2011-09-12T23:59:59.000Z

    The current focal point of the nuclear physics program at PNNL is the MAJORANA DEMONSTRATOR, and the follow-on Tonne-Scale experiment, a large array of ultra-low background high-purity germanium detectors, enriched in 76Ge, designed to search for zero-neutrino double-beta decay (0???). This experiment requires the use of germanium isotopically enriched in 76Ge. The MAJORANA DEMONSTRATOR is a DOE and NSF funded project with a major science impact. The DEMONSTRATOR will utilize 76Ge from Russia, but for the Tonne-Scale experiment it is hoped that an alternate technology, possibly one under development at Nonlinear Ion Dynamics (NID), will be a viable, US-based, lower-cost source of separated material. Samples of separated material from NID require analysis to determine the isotopic distribution and impurities. DOE is funding NID through an SBIR grant for development of their separation technology for application to the Tonne-Scale experiment. The Environmental Molecular Sciences facility (EMSL), a DOE user facility at PNNL, has the required mass spectroscopy instruments for making isotopic measurements that are essential to the quality assurance for the MAJORANA DEMONSTRATOR and for the development of the future separation technology required for the Tonne-Scale experiment. A sample of isotopically separated copper was provided by NID to PNNL in January 2011 for isotopic analysis as a test of the NID technology. The results of that analysis are reported here. A second sample of isotopically separated copper was provided by NID to PNNL in August 2011 for isotopic analysis as a test of the NID technology. The results of that analysis are also reported here.

  4. Low-energy monopole strength in exotic Nickel isotopes

    E-Print Network [OSTI]

    E. Khan; N. Paar; D. Vretenar

    2011-10-13T23:59:59.000Z

    Low-energy strength is predicted for the isoscalar monopole response of neutron-rich Ni isotopes, in calculations performed using the microscopic Skyrme HF+RPA and relativistic RHB+RQRPA models. Both models, although based on different energy density functionals, predict the occurrence of pronounced monopole states in the energy region between 10 MeV and 15 MeV, well separated from the isoscalar GMR. The analysis of transition densities and corresponding particle-hole configurations shows that these states represent almost pure neutron single hole-particle excitations. Even though their location is not modified with respect to the corresponding unperturbed states, their (Q)RPA strength is considerably enhanced by the residual interaction. The theoretical analysis predicts the gradual enhancement of low-energy monopole strength with neutron excess.

  5. Design, construction, and operation of a laboratory scale reactor for the production of high-purity, isotopically enriched bulk silicon

    E-Print Network [OSTI]

    Ager III, J.W.; Beeman, J.W.; Hansen, W.L.; Haller, E.E.

    2004-01-01T23:59:59.000Z

    Russia. The stated isotope enrichments are summarized inenrichments >99% have been achieved for each isotope and

  6. Isotope Effects in C-H Bond Activation Reactions by

    E-Print Network [OSTI]

    Jones, William D.

    , the intermediacy of an alkane -complex is oftentimes demonstrated by prep- aration of an alkyl deuteride complex

  7. On the Alpha Activity of Natural Tungsten Isotopes

    E-Print Network [OSTI]

    F. A. Danevich A; A. Sh. Georgadze A; V. V. Kobychev A; S. S. Nagorny A; A. S. Nikolaiko A; W

    The indication for the ? decay of 180W with a half-life T ? 1/2 =1.1+0.8 ?0.4(stat)±0.3(syst)×1018 yr has been observed for the first time with the help of the super-low background 116CdWO4 crystal scintillators. In conservative approach the lower limit on half-life of 180W has been established as T ? 1/2 (180W) ? 0.7×1018 yr at 90 % C.L. Besides, new T ? 1/2 bounds were set for ? decay of

  8. Apparatus for separating and recovering hydrogen isotopes

    DOE Patents [OSTI]

    Heung, Leung K. (Aiken, SC)

    1994-01-01T23:59:59.000Z

    An apparatus for recovering hydrogen and separating its isotopes. The apparatus includes a housing bearing at least a fluid inlet and a fluid outlet. A baffle is disposed within the housing, attached thereto by a bracket. A hollow conduit is coiled about the baffle, in spaced relation to the baffle and the housing. The coiled conduit is at least partially filled with a hydride. The hydride can be heated to a high temperature and cooled to a low temperature quickly by circulating a heat transfer fluid in the housing. The spacing between the baffle and the housing maximizes the heat exchange rate between the fluid in the housing and the hydride in the conduit. The apparatus can be used to recover hydrogen isotopes (protium, deuterium and tritium) from gaseous mixtures, or to separate hydrogen isotopes from each other.

  9. Isotope effects in methanol synthesis and the reactivity of copper...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Isotope effects in methanol synthesis and the reactivity of copper formates on a CuSiO2 catalyst. Isotope effects in methanol synthesis and the reactivity of copper formates on a...

  10. Hydrogen isotope fractionation during lipid biosynthesis by Haloarcula marismortui

    E-Print Network [OSTI]

    Hydrogen isotope fractionation during lipid biosynthesis by Haloarcula marismortui Sitindra S studied the controls on the fractionation of hydrogen isotopes during lipid biosynthesis by Haloarcula marismortui, a halophilic archaea, in pure culture experiments by varying organic substrate, the hydrogen

  11. Oxygen isotope records of carboniferous seasonality on the Russian platform

    E-Print Network [OSTI]

    Wang, Huayu

    1998-01-01T23:59:59.000Z

    Seven isotopic and eight trace element (TE) profiles across shell growth lines are presented, based on over 1000 stable isotope and electron microprobe analyses on six brachiopod shells (Gigantoproductus), to quantify seasonal temperature change...

  12. Physiology of multiple sulfur isotope fractionation during microbial sulfate reduction

    E-Print Network [OSTI]

    Sim, Min Sub

    2012-01-01T23:59:59.000Z

    Microbial sulfate reduction (MSR) utilizes sulfate as an electron acceptor and produces sulfide that is depleted in heavy isotopes of sulfur relative to starting sulfate. The fractionation of S-isotopes is commonly used ...

  13. Delayed neutron measurements from fast fission of actinide waste isotopes

    E-Print Network [OSTI]

    Charlton, William S.

    1997-01-01T23:59:59.000Z

    A study was performed to determine the delayed neutron emission properties from fast fission of several actinide waste isotopes. The specific isotopes evaluated were U-235, Np-237, and Am-243. A calculational technique based on the microscopic...

  14. High Flux Isotope Reactor named Nuclear Historic Landmark | ornl...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    High Flux Isotope Reactor named Nuclear Historic Landmark The High Flux Isotope Reactor vessel at Oak Ridge National Laboratory resides in a pool of water illuminated by the blue...

  15. Stable carbon and nitrogen isotope enrichment in primate tissues

    E-Print Network [OSTI]

    Crowley, Brooke E.; Carter, Melinda L.; Karpanty, Sarah M.; Zihlman, Adrienne L.; Koch, Paul L.; Dominy, Nathaniel J.

    2010-01-01T23:59:59.000Z

    of sample treatment and diagenesis on the isotopic integrityHare PE (1986) Effects of diagenesis on strontium, carbon,

  16. Diffusion in silicon isotope heterostructures

    SciTech Connect (OSTI)

    Silvestri, Hughes Howland

    2004-05-14T23:59:59.000Z

    The simultaneous diffusion of Si and the dopants B, P, and As has been studied by the use of a multilayer structure of isotopically enriched Si. This structure, consisting of 5 pairs of 120 nm thick natural Si and {sup 28}Si enriched layers, enables the observation of {sup 30}Si self-diffusion from the natural layers into the {sup 28}Si enriched layers, as well as dopant diffusion from an implanted source in an amorphous Si cap layer, via Secondary Ion Mass Spectrometry (SIMS). The dopant diffusion created regions of the multilayer structure that were extrinsic at the diffusion temperatures. In these regions, the Fermi level shift due to the extrinsic condition altered the concentration and charge state of the native defects involved in the diffusion process, which affected the dopant and self-diffusion. The simultaneously recorded diffusion profiles enabled the modeling of the coupled dopant and self-diffusion. From the modeling of the simultaneous diffusion, the dopant diffusion mechanisms, the native defect charge states, and the self- and dopant diffusion coefficients can be determined. This information is necessary to enhance the physical modeling of dopant diffusion in Si. It is of particular interest to the modeling of future electronic Si devices, where the nanometer-scale features have created the need for precise physical models of atomic diffusion in Si. The modeling of the experimental profiles of simultaneous diffusion of B and Si under p-type extrinsic conditions revealed that both species are mediated by neutral and singly, positively charged Si self-interstitials. The diffusion of As and Si under extrinsic n-type conditions yielded a model consisting of the interstitialcy and vacancy mechanisms of diffusion via singly negatively charged self-interstitials and neutral vacancies. The simultaneous diffusion of P and Si has been modeled on the basis of neutral and singly negatively charged self-interstitials and neutral and singly positively charged P species. Additionally, the temperature dependence of the diffusion coefficient of Si in Ge was measured over the temperature range of 550 C to 900 C using a buried Si layer in an epitaxially grown Ge layer.

  17. Laser isotope separation by multiple photon absorption

    DOE Patents [OSTI]

    Robinson, C. Paul (Los Alamos, NM); Rockwood, Stephen D. (Los Alamos, NM); Jensen, Reed J. (Los Alamos, NM); Lyman, John L. (Los Alamos, NM); Aldridge, III, Jack P. (Los Alamos, NM)

    1987-01-01T23:59:59.000Z

    Multiple photon absorption from an intense beam of infrared laser light may be used to induce selective chemical reactions in molecular species which result in isotope separation or enrichment. The molecular species must have a sufficient density of vibrational states in its vibrational manifold that, is the presence of sufficiently intense infrared laser light tuned to selectively excite only those molecules containing a particular isotope, multiple photon absorption can occur. By this technique, for example, intense CO.sub.2 laser light may be used to highly enrich .sup.34 S in natural SF.sub.6 and .sup.11 B in natural BCl.sub.3.

  18. Laser isotope separation by multiple photon absorption

    DOE Patents [OSTI]

    Robinson, C.P.; Rockwood, S.D.; Jensen, R.J.; Lyman, J.L.; Aldridge, J.P. III.

    1987-04-07T23:59:59.000Z

    Multiple photon absorption from an intense beam of infrared laser light may be used to induce selective chemical reactions in molecular species which result in isotope separation or enrichment. The molecular species must have a sufficient density of vibrational states in its vibrational manifold that, is the presence of sufficiently intense infrared laser light tuned to selectively excite only those molecules containing a particular isotope, multiple photon absorption can occur. By this technique, for example, intense CO[sub 2] laser light may be used to highly enrich [sup 34]S in natural SF[sub 6] and [sup 11]B in natural BCl[sub 3]. 8 figs.

  19. Isotope Research Materials Laboratory | ornl.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHigh SchoolIn12 Investigation Peer ReviewIron isIsIsotope ProgramIsotope

  20. Method and apparatus for noble gas atom detection with isotopic selectivity

    DOE Patents [OSTI]

    Hurst, G. Samuel (Oak Ridge, TN); Payne, Marvin G. (Harriman, TN); Chen, Chung-Hsuan (Knoxville, TN); Parks, James E. (Oak Ridge, TN)

    1984-01-01T23:59:59.000Z

    Apparatus and methods of operation are described for determining, with isotopic selectivity, the number of noble gas atoms in a sample. The analysis is conducted within an evacuated chamber which can be isolated by a valve from a vacuum pumping system capable of producing a pressure of 10.sup.-8 Torr. Provision is made to pass pulses of laser beams through the chamber, these pulses having wavelengths appropriate for the resonance ionization of atoms of the noble gas under analysis. A mass filter within the chamber selects ions of a specific isotope of the noble gas, and means are provided to accelerate these selected ions sufficiently for implantation into a target. Specific types of targets are discussed. An electron measuring device produces a signal relatable to the number of ions implanted into the target and thus to the number of atoms of the selected isotope of the noble gas removed from the gas sample. The measurement can be continued until a substantial fraction, or all, of the atoms in the sample have been counted. Furthermore, additional embodiments of the apparatus are described for bunching the atoms of a noble gas for more rapid analysis, and for changing the target for repetitive cycling of the gas in the chamber. The number of repetitions of the cyclic steps depend upon the concentration of the isotope of interest, the separative efficiency of the mass filter, etc. The cycles are continued until a desired selectivity is achieved. Also described are components and a method of operation for a pre-enrichment operation for use when an introduction of a total sample would elevate the pressure within the chamber to levels in excess of those for operation of the mass filter, specifically a quadrupole mass filter. Specific examples of three noble gas isotope analyses are described.

  1. Hydrogen isotope fractionation during lipid biosynthesis by Tetrahymena thermophila

    E-Print Network [OSTI]

    Hydrogen isotope fractionation during lipid biosynthesis by Tetrahymena thermophila Sitindra S Accepted 7 September 2013 Available online 16 September 2013 a b s t r a c t Hydrogen isotope ratio values from recording the hydrogen isotope composition of ambient water, dD values of lipids also depend

  2. ORIGINAL RESEARCH Hydrogen and carbon isotope fractionation during

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    , enrichment in 13 C of untransformed CH3Cl was also observed, and similar isotope enrichment factors (e) of ŔORIGINAL RESEARCH Hydrogen and carbon isotope fractionation during degradation of chloromethane-Meitner-Weg 1, 55128 Mainz, Germany Keywords Carbon isotope fractionation, chloromethane biodegradation

  3. Research Article Peculiarities in the stable isotope composition of organisms

    E-Print Network [OSTI]

    Rasmussen, Joseph

    that dietary N content can affect trophic level 15 N enrichment. The anomalies in stable isotope concen; dietary N; 15 N enrichment. Introduction Over the last decade, stable isotopes have been used inResearch Article Peculiarities in the stable isotope composition of organisms from an alpine lake

  4. Discovery of the actinium, thorium, protactinium, and uranium isotopes

    E-Print Network [OSTI]

    C. Fry; M. Thoennessen

    2012-03-06T23:59:59.000Z

    Currently, 31 actinium, 31 thorium, 28 protactinium, and 23 uranium isotopes have so far been observed; the discovery of these isotopes is discussed. For each isotope a brief summary of the first refereed publication, including the production and identification method, is presented.

  5. Discovery of dysprosium, holmium, erbium, thulium, and ytterbium isotopes

    SciTech Connect (OSTI)

    Fry, C.; Thoennessen, M., E-mail: thoennessen@nscl.msu.edu

    2013-09-15T23:59:59.000Z

    Currently, thirty-one dysprosium, thirty-two holmium, thirty-two erbium, thirty-three thulium, and thirty-one ytterbium isotopes have been observed and the discovery of these isotopes is described here. For each isotope a brief synopsis of the first refereed publication, including the production and identification method, is presented.

  6. Discovery of palladium, antimony, tellurium, iodine, and xenon isotopes

    SciTech Connect (OSTI)

    Kathawa, J.; Fry, C.; Thoennessen, M., E-mail: thoennessen@nscl.msu.edu

    2013-01-15T23:59:59.000Z

    Currently, thirty-eight palladium, thirty-eight antimony, thirty-nine tellurium, thirty-eight iodine, and forty xenon isotopes have been observed and the discovery of these isotopes is described here. For each isotope a brief synopsis of the first refereed publication, including the production and identification method, is presented.

  7. Discovery of the astatine, radon, francium, and radium isotopes

    SciTech Connect (OSTI)

    Fry, C.; Thoennessen, M., E-mail: thoennessen@nscl.msu.edu

    2013-09-15T23:59:59.000Z

    Thirty-nine astatine, thirty-nine radon, thirty-five francium, and thirty-four radium isotopes have so far been observed; the discovery of these isotopes is described. For each isotope a brief summary of the first refereed publication, including the production and identification method, is presented.

  8. Discovery of samarium, europium, gadolinium, and terbium isotopes

    SciTech Connect (OSTI)

    May, E.; Thoennessen, M., E-mail: thoennessen@nscl.msu.edu

    2013-01-15T23:59:59.000Z

    Currently, thirty-four samarium, thirty-four europium, thirty-one gadolinium, and thirty-one terbium isotopes have been observed and the discovery of these isotopes is described here. For each isotope a brief synopsis of the first refereed publication, including the production and identification method, is presented.

  9. Discovery of Yttrium, Zirconium, Niobium, Technetium, and Ruthenium Isotopes

    E-Print Network [OSTI]

    A. Nystrom; M. Thoennessen

    2011-02-11T23:59:59.000Z

    Currently, thirty-four yttrium, thirty-five zirconium, thirty-four niobium, thirty-five technetium, and thirty-eight ruthenium isotopes have been observed and the discovery of these isotopes is discussed here. For each isotope a brief synopsis of the first refereed publication, including the production and identification method, is presented.

  10. Discovery of Yttrium, Zirconium, Niobium, Technetium, and Ruthenium Isotopes

    E-Print Network [OSTI]

    Nystrom, A

    2011-01-01T23:59:59.000Z

    Currently, thirty-four yttrium, thirty-five zirconium, thirty-four niobium, thirty-five technetium, and thirty-eight ruthenium isotopes have been observed and the discovery of these isotopes is discussed here. For each isotope a brief synopsis of the first refereed publication, including the production and identification method, is presented.

  11. Discovery of Scandium, Titanium, Mercury, and Einsteinium Isotopes

    E-Print Network [OSTI]

    D. Meierfrankenfeld; A. Bury; M. Thoennessen

    2010-09-08T23:59:59.000Z

    Currently, twenty-three scandium, twenty-five titanium, forty mercury and seventeen einsteinium isotopes have been observed and the discovery of these isotopes is discussed here. For each isotope a brief synopsis of the first refereed publication, including the production and identification method, is presented.

  12. Discovery of Samarium, Europium, Gadolinium, and Terbium Isotopes

    E-Print Network [OSTI]

    E. May; M. Thoennessen

    2012-01-19T23:59:59.000Z

    Currently, thirty-four samarium, thirty-four europium, thirty-one gadolinium, and thirty-one terbium isotopes have been observed and the discovery of these isotopes is discussed here. For each isotope a brief synopsis of the first refereed publication, including the production and identification method, is presented.

  13. Discovery of Samarium, Europium, Gadolinium, and Terbium Isotopes

    E-Print Network [OSTI]

    May, E

    2012-01-01T23:59:59.000Z

    Currently, thirty-four samarium, thirty-four europium, thirty-one gadolinium, and thirty-one terbium isotopes have been observed and the discovery of these isotopes is discussed here. For each isotope a brief synopsis of the first refereed publication, including the production and identification method, is presented.

  14. Heavy metals and lead isotopes in sdB stars

    E-Print Network [OSTI]

    S. O'Toole; U. Heber

    2006-12-19T23:59:59.000Z

    We present a detailed abundance analysis of high-resolution ultraviolet echelle spectra of five subdwarf B stars obtained with HST-STIS The goal of our observations was to test the hypothesis that pulsations in sdBs are correlated to the surface abundances of iron-group elements. We study two pulsators and three non-pulsators and determined abundances for 25 elements including the iron group and even heavier elements such as tin and lead using LTE spectrum synthesis techniques. We find strong enrichments of heavy elements up to 2.9dex with respect to solar which are probably caused by atomic diffusion processes. No clear-cut correlation between pulsations and metal abundances becomes apparent. Abundances for lead isotopes are derived from very high resolution spectra using an UV line of triply ionised lead. As Pb terminates the s-process sequence Pb isotopic abundance ratios yield important constraints. It is very difficult to measure them in hot stars. For the first time we were able to measure them in two subluminous B stars and conclude that the 207Pb/208Pb is solar.

  15. High Flux Isotopes Reactor (HFIR) Cooling Towers Demolition Waste Management

    SciTech Connect (OSTI)

    Pudelek, R. E.; Gilbert, W. C.

    2002-02-26T23:59:59.000Z

    This paper describes the results of a joint initiative between Oak Ridge National Laboratory, operated by UT-Battelle, and Bechtel Jacobs Company, LLC (BJC) to characterize, package, transport, treat, and dispose of demolition waste from the High Flux Isotope Reactor (HFIR), Cooling Tower. The demolition and removal of waste from the site was the first critical step in the planned HFIR beryllium reflector replacement outage scheduled. The outage was scheduled to last a maximum of six months. Demolition and removal of the waste was critical because a new tower was to be constructed over the old concrete water basin. A detailed sampling and analysis plan was developed to characterize the hazardous and radiological constituents of the components of the Cooling Tower. Analyses were performed for Resource Conservation and Recovery Act (RCRA) heavy metals and semi-volatile constituents as defined by 40 CFR 261 and radiological parameters including gross alpha, gross beta, gross gamma, alpha-emitting isotopes and beta-emitting isotopes. Analysis of metals and semi-volatile constituents indicated no exceedances of regulatory limits. Analysis of radionuclides identified uranium and thorium and associated daughters. In addition 60Co, 99Tc, 226Rm, and 228Rm were identified. Most of the tower materials were determined to be low level radioactive waste. A small quantity was determined not to be radioactive, or could be decontaminated. The tower was dismantled October 2000 to January 2001 using a detailed step-by-step process to aid waste segregation and container loading. The volume of waste as packaged for treatment was approximately 1982 cubic meters (70,000 cubic feet). This volume was comprised of plastic ({approx}47%), wood ({approx}38%) and asbestos transite ({approx}14%). The remaining {approx}1% consisted of the fire protection piping (contaminated with lead-based paint) and incidental metal from conduit, nails and braces/supports, and sludge from the basin. The waste, except for the asbestos, was volume reduced via a private contract mechanism established by BJC. After volume reduction, the waste was packaged for rail shipment. This large waste management project successfully met cost and schedule goals.

  16. A review of stable water isotopeA review of stable water isotope modellingmodelling

    E-Print Network [OSTI]

    Sturm, Christophe "Kristof"

    fractionation · Kinetic fractionation 2. Modelling the stable water isotope cycle · Rayleigh distillation model Institution of Oceanography) Harald SODEMANN (Norwegian Institute for Air Research) Kristof 18Ovapour=-40 18Oocean=0 18Osnow=-3018Orain=-2 Equilibrium fractionationEquilibrium fractionation

  17. Isotopically selective, Doppler-free, saturation spectroscopy of lutetium isotopes via resonance ionization mass spectrometry

    SciTech Connect (OSTI)

    Fearey, B.L.; Parent, D.C.; Keller, R.A.; Miller, C.M.

    1988-01-01T23:59:59.000Z

    A new technique utilizing RIMS to obtain very high resolution atomic spectra with isotopic selectivity has been demonstrated. This technique allows the precise determination of HF splitting constants, limited only by the transition's natural linewidth. In addition, it is also feasible with this technique to accurately determine atomic isotope shifts. The exact determination of HF component line positions provides data for isotopically selective ionization which, in turn, will increase RIMS' dynamic range. Future work includes the incorporation of a /open quotes/vibrating/close quotes/ mirror and the study of rarer isotopes, i.e., /sup 174/Lu, /sup 173/Lu, /sup 172/Lu, /sup 171/Lu, and possibly, /sup 170/Lu. 13 refs., 3 figs.

  18. O Isotopic Composition of CaCO3 Measured by Continuous Flow Isotope Ratio Mass Spectrometry: Statistical Evaluation and

    E-Print Network [OSTI]

    d13 C and d18 O Isotopic Composition of CaCO3 Measured by Continuous Flow Isotope Ratio Mass method streamlines the classical phosphoric acid ­ calcium carbonate (H3 PO4 ­ CaCO3 ) reaction method XL continuous flow isotope ratio mass spectrometer. Conditions for which the H3 PO4 ­ CaCO3 reaction

  19. Assessment of energetic costs of AhR activation by ?-naphthoflavone in rainbow trout (Oncorhynchus mykiss) hepatocytes using metabolic flux analysis

    SciTech Connect (OSTI)

    Nault, Rance, E-mail: naultran@msu.edu [Ottawa-Carleton Institute of Biology, Department of Biology and Centre for Advanced Research in Environmental Genomics, University of Ottawa, Ottawa, Ontario, K1N 6N5 (Canada); Abdul-Fattah, Hiba [Ottawa-Carleton Institute of Biology, Department of Biology and Centre for Advanced Research in Environmental Genomics, University of Ottawa, Ottawa, Ontario, K1N 6N5 (Canada); Mironov, Gleb G.; Berezovski, Maxim V. [Ottawa-Carleton Institute of Biology, Department of Biology and Centre for Advanced Research in Environmental Genomics, University of Ottawa, Ottawa, Ontario, K1N 6N5 (Canada); Department of Chemistry, University of Ottawa, Ottawa, Ontario, K1N 6N5 (Canada); Moon, Thomas W. [Ottawa-Carleton Institute of Biology, Department of Biology and Centre for Advanced Research in Environmental Genomics, University of Ottawa, Ottawa, Ontario, K1N 6N5 (Canada)

    2013-08-15T23:59:59.000Z

    Exposure to environmental contaminants such as activators of the aryl hydrocarbon receptor (AhR) leads to the induction of defense and detoxification mechanisms. While these mechanisms allow organisms to metabolize and excrete at least some of these environmental contaminants, it has been proposed that these mechanisms lead to significant energetic challenges. This study tests the hypothesis that activation of the AhR by the model agonist ?-naphthoflavone (?NF) results in increased energetic costs in rainbow trout (Oncorhynchus mykiss) hepatocytes. To address this hypothesis, we employed traditional biochemical approaches to examine energy allocation and metabolism including the adenylate energy charge (AEC), protein synthesis rates, Na{sup +}/K{sup +}-ATPase activity, and enzyme activities. Moreover, we have used for the first time in a fish cell preparation, metabolic flux analysis (MFA) an in silico approach for the estimation of intracellular metabolic fluxes. Exposure of trout hepatocytes to 1 ?M ?NF for 48 h did not alter hepatocyte AEC, protein synthesis, or Na{sup +}/K{sup +}-ATPase activity but did lead to sparing of glycogen reserves and changes in activities of alanine aminotransferase and citrate synthase suggesting altered metabolism. Conversely, MFA did not identify altered metabolic fluxes, although we do show that the dynamic metabolism of isolated trout hepatocytes poses a significant challenge for this type of approach which should be considered in future studies. - Highlights: • Energetic costs of AhR activation by ?NF was examined in rainbow trout hepatocytes. • Metabolic flux analysis was performed on a fish cell preparation for the first time. • Exposure to ?NF led to sparing of glycogen reserves and altered enzyme activities. • Adenylate energy charge was maintained despite temporal changes in metabolism.

  20. Comparison of IUPAC k0 Values and Neutron Cross Sections to Determine a Self-consistent Set of Data for Neutron Activation Analysis

    SciTech Connect (OSTI)

    Firestone, Richard B; Revay, Zsolt

    2009-12-01T23:59:59.000Z

    Independent databases of nuclear constants for Neutron Activation Analysis (NAA) have been independently maintained by the physics and chemistry communities for many year. They contain thermal neturon cross sections s0, standardization values k0, and transition probabilities Pg. Chemistry databases tend to rely upon direct measurements of the nuclear constants k0 and Pg which are often published in chemistry journals while the physics databases typically include evaluated s0 and Pg data from a variety of experiments published mainly in physics journals. The IAEA/LBNL Evaluated Gamma-ray Activation File (EGAF) also contains prompt and delayed g-ray cross sections sg from Prompt Gamma-ray Activation Analysis (PGAA) measurements that can also be used to determine k0 and s0 values. As a result several independent databases of fundamental constants for NAA have evolved containing slightly different and sometimes discrepant results. An IAEA CRP for a Reference Database for Neutron Activation Analysis was established to compare these databases and investigate the possibilitiy of producing a self-consistent set of s0, k0, sg, and Pg values for NAA and other applications. Preliminary results of this IAEA CRP comparison are given in this paper.

  1. Review of hydrogen isotope permeability through materials

    SciTech Connect (OSTI)

    Steward, S.A.

    1983-08-15T23:59:59.000Z

    This report is the first part of a comprehensive summary of the literature on hydrogen isotope permeability through materials that do not readily form hydrides. While we mainly focus on pure metals with low permeabilities because of their importance to tritium containment, we also give data on higher-permeability materials such as iron, nickel, steels, and glasses.

  2. Trace Element and Isotopic Fluxes/ Subducted Slab

    E-Print Network [OSTI]

    Bebout, Gray E.

    3.20.7.2.1 Devolatilization 34 3.20.7.2.2 Boron and lithium isotopes 35 3.20.7.3 Carbon and Nitrogen forearcs. In addi- tion, subduction erosion from the forearc hanging walls can impact geochemical evolut

  3. 5, 547577, 2008 Isotope hydrology of

    E-Print Network [OSTI]

    Boyer, Edmond

    HESSD 5, 547­577, 2008 Isotope hydrology of cave dripwaters L. Fuller et al. Title Page Abstract.hydrol-earth-syst-sci-discuss.net/5/547/2008/ © Author(s) 2008. This work is licensed under a Creative Commons License. Hydrology and Earth System Sciences Discussions Papers published in Hydrology and Earth System Sciences Discussions

  4. Radioactive isotopes in Danish drinking water

    E-Print Network [OSTI]

    Radioactive isotopes in Danish drinking water Sven P. Nielsen Risř National Laboratory Working OF INVESTIGATION 11 3 DESCRIPTION OF INVESTIGATION 12 4 RADIOACTIVITY IN DRINKING WATER 13 5 SAMPLING 15 6 27 #12;4 #12;5 Preface This project for investigation of radioactivity in drinking water shall

  5. Atomic-vapor-laser isotope separation

    SciTech Connect (OSTI)

    Davis, J.I.

    1982-10-01T23:59:59.000Z

    This paper gives a brief history of the scientific considerations leading to the development of laser isotope separation (LIS) processes. The close relationship of LIS to the broader field of laser-induced chemical processes is evaluated in terms of physical criteria to achieve an efficient production process. Atomic-vapor LIS processes under development at Livermore are reviwed. 8 figures.

  6. NID Copper Sample Analysis

    SciTech Connect (OSTI)

    Kouzes, Richard T.; Zhu, Zihua

    2011-02-01T23:59:59.000Z

    The current focal point of the nuclear physics program at PNNL is the MAJORANA DEMONSTRATOR, and the follow-on Tonne-Scale experiment, a large array of ultra-low background high-purity germanium detectors, enriched in 76Ge, designed to search for zero-neutrino double-beta decay (0???). This experiment requires the use of germanium isotopically enriched in 76Ge. The DEMONSTRATOR will utilize 76Ge from Russia, but for the Tonne-Scale experiment it is hoped that an alternate technology under development at Nonlinear Ion Dynamics (NID) will be a viable, US-based, lower-cost source of separated material. Samples of separated material from NID require analysis to determine the isotopic distribution and impurities. The MAJORANA DEMONSTRATOR is a DOE and NSF funded project with a major science impact. DOE is funding NID through an SBIR grant for development of their separation technology for application to the Tonne-Scale experiment. The Environmental Molecular Sciences facility (EMSL), a DOE user facility at PNNL, has the required mass spectroscopy instruments for making these isotopic measurements that are essential to the quality assurance for the MAJORANA DEMONSTRATOR and for the development of the future separation technology required for the Tonne-Scale experiment. A sample of isotopically separated copper was provided by NID to PNNL for isotopic analysis as a test of the NID technology. The results of that analysis are reported here.

  7. Model Proton-Coupled Electron Transfer Reactions in Solution: Predictions of Rates, Mechanisms, and Kinetic Isotope Effects

    E-Print Network [OSTI]

    Hammes-Schiffer, Sharon

    Model Proton-Coupled Electron Transfer Reactions in Solution: Predictions of Rates, Mechanisms isotope effects for proton-coupled electron transfer (PCET) reactions. These studies are based, the solvent is represented as a dielectric continuum, and the active electrons and transferring protons

  8. Isotopic and kinetic assessment of the mechanism of methane reforming and decomposition reactions on supported iridium catalysts

    E-Print Network [OSTI]

    Iglesia, Enrique

    Isotopic and kinetic assessment of the mechanism of methane reforming and decomposition reactions reforming reactions. 1. Introduction Methane is an essential raw material in the synthesis of liquid fuels and petrochemical, but its strong C­H bonds (439 kJ molŔ1 1 ) require active catalysts and severe reaction

  9. Isotope characterization of shallow aquifers in the Horombe region, South of Madagascar

    E-Print Network [OSTI]

    Fareze, L P; Ramaroson, V; Andriambololona, Raoelina; Andriamiarintsoa, G; Razafitsalama, P R; Rahobisoa, J J; Randrianarison, H; Ranaivoarisoa, A; Marah, H

    2012-01-01T23:59:59.000Z

    The present study deals with the problem of evaluation of the recharge mechanism and the characterization of the groundwater flow system in the basement shallow aquifer, which is one of the groundwater resource in the semi-arid South region of Madagascar. Stable isotopes (deuterium and oxygen-18) and tritium are used to achieve with accuracy the hydrogeological and geochemical dynamics study. Chemical analysis is used to provide complementary information to the investigation. A space distribution of tritium concentration and isotopic composition in groundwater shows evidence of two opposite categories of aquifers, which is confirmed by the chemical analysis results and by the geological features of the study site. Some groundwater flow path directions have been identified in the study area thanks to the tritium concentration space distribution and the geological formation. Besides, the groundwater recharge of the shallow aquifers in the South of Madagascar has been characterized by the exponential mixing mode...

  10. The Multi-Isotope Process (MIP) Monitor Project: FY12 Progress and Accomplishments

    SciTech Connect (OSTI)

    Coble, Jamie B.; Orton, Christopher R.; Jordan, David V.; Schwantes, Jon M.; Bender, Sarah; Dayman, Kenneth J.; Unlu, Kenan; Landsberger, Sheldon

    2012-09-27T23:59:59.000Z

    The Multi-Isotope Process (MIP) Monitor, being developed at Pacific Northwest National Laboratory (PNNL), provides an efficient approach to monitoring the process conditions in reprocessing facilities in support of the goal of "...(minimization of) the risks of nuclear proliferation and terrorism." The MIP Monitor measures distributions of a suite of indicator (radioactive) isotopes present within product and waste streams of a nuclear reprocessing facility. These indicator isotopes are monitored on-line by gamma spectrometry and compared, in near-real-time, to spectral patterns representing "normal" process conditions using multivariate pattern recognition software. The monitor utilizes this multivariate analysis and gamma spectroscopy of reprocessing streams to detect small changes in the gamma spectrum, which may indicate changes in process conditions. Multivariate analysis methods common in chemometrics, such as principal component analysis (PCA) and partial least squares regression (PLS), act as pattern recognition techniques, which can detect small deviations from the expected, nominal condition. By targeting multiple gamma-emitting indicator isotopes, the MIP Monitor approach is compatible with the use of small, portable, relatively high-resolution gamma detectors that may be easily deployed throughout an existing facility. The automated multivariate analysis can provide a level of data obscurity, giving a built-in information barrier to protect sensitive or proprietary operational data. Proof-of-concept simulations and experiments have been performed in previous years to demonstrate the validity of this tool in a laboratory setting. Development of the MIP Monitor approach continues to evaluate the efficacy of the monitor for automated, real-time or near-real-time application. This report details follow-on research and development efforts sponsored by the U.S. Department of Energy Fuel Cycle Research and Development related to the MIP Monitor for fiscal year 2012 (FY12).

  11. Measuring of fissile isotopes partial antineutrino spectra in direct experiment at nuclear reactor

    E-Print Network [OSTI]

    V. V. Sinev

    2009-02-22T23:59:59.000Z

    The direct measuring method is considered to get nuclear reactor antineutrino spectrum. We suppose to isolate partial spectra of the fissile isotopes by using the method of antineutrino spectrum extraction from the inverse beta decay positron spectrum applied at Rovno experiment. This admits to increase the accuracy of partial antineutrino spectra forming the total nuclear reactor spectrum. It is important for the analysis of the reactor core fuel composition and could be applied for non-proliferation purposes.

  12. Simulation of the Stable Water Isotopes in Precipitation over South America: Comparing Regional to Global Circulation Models

    E-Print Network [OSTI]

    Sturm, Christophe "Kristof"

    an isotopic signature similar to Rayleigh distillation, in accordance with experimental studies. Finally, in order to relate the simulation analysis to the fractionation mechanisms. This confirms that the amount effect, via Rayleigh distillation processes, is dominant during the wet season. During the dry season

  13. Compilation of the Dakota Aquifer Project isotope data and publications: The Isotope Hydrology Program of the Isotope Sciences Division

    SciTech Connect (OSTI)

    Davisson, M.L.; Smith, D.K.; Hudson, G.B.; Niemeyer, S. [Lawrence Livermore National Lab., CA (United States); Macfarlane, P.A.; Whittemore, D.O. [Kansas Geological Survey, Lawrence, KS (United States)

    1995-01-01T23:59:59.000Z

    In FY92 the then Nuclear Chemistry Division embarked on a scientific collaboration with the Kansas Geological Survey (KGS) to characterize with isotope techniques groundwater of the Dakota Formation of Kansas. The Dakota Formation is a Cretaceous-aged marine sandstone hosting potable groundwater in most regions of Kansas whose use will serve to partially offset the severe overdraft problems in the overlying Ogallala Formation. The isotope characterization of the Dakota groundwater has generated data that delineates sources, ages, and subsurface controls on the water quality. Initial interpretations of the data have been published in abstract volumes of (1) the 1993 Geological Society of America National Meeting, (2) the 8th International Conference on Geochronology, Cosmochronology and Isotope Geology, and (3) the 1994 Dakota Aquifer Workshop and Clinic. Copies of all abstracts are included in this brief review. One report will focus on the sources and ages of the groundwater, and the other will focus on the subsurface controls on the natural water quality.

  14. Activated Boron Nitride Derived from Activated Carbon

    E-Print Network [OSTI]

    Zettl, Alex

    combination of chemical, thermal, and electrical properties. The utility of activated carbon suggests is characterized by scanning electron microscopy, high-resolution transmission electron microscopy, electron energy loss spectroscopy, and surface area analysis. The activated BN microstructure is similar

  15. A strategic analysis study-based approach to integrated risk assessment: Occupational health risks from environmental restoration and waste management activities at Hanford

    SciTech Connect (OSTI)

    Mahaffey, J.A.; Doctor, P.G.; Buschbom, R.L.; Glantz, C.S.; Daling, P.M.; Sever, L.E.; Vargo, G.J. Jr.; Strachan, D.M. [Pacific Northwest Lab., Richland, WA (United States); Pajunen, A.L.; Hoyt, R.C.; Ludowise, J.D. [Westinghouse Hanford Co., Richland, WA (United States)

    1993-06-01T23:59:59.000Z

    The goal of environmental restoration and waste management activities is to reduce public health risks or to delay risks to the future when new technology will be available for improved cleanup solutions. Actions to remediate the wastes on the Hanford Site will entail risks to workers, the public, and the environment that do not currently exist. In some circumstances, remediation activities will create new exposure pathways that are not present without cleanup activities. In addition, cleanup actions will redistribute existing health risks over time and space, and will likely shift health risks to cleanup workers in the short term. This report describes an approach to occupational risk assessment based on the Hanford Strategic Analysis Study and illustrates the approach by comparing worker risks for two options for remediation of N/K fuels, a subcategory of unprocessed irradiated fuels at Hanford.

  16. Diffusional exchange of isotopes in a metal hydride sphere.

    SciTech Connect (OSTI)

    Wolfer, Wilhelm G.; Hamilton, John C.; James, Scott Carlton

    2011-04-01T23:59:59.000Z

    This report describes the Spherical Particle Exchange Model (SPEM), which simulates exchange of one hydrogen isotope by another hydrogen isotope in a spherical metal hydride particle. This is one of the fundamental physical processes during isotope exchange in a bed of spherical metal particles and is thus one of the key components in any comprehensive physics-based model of exchange. There are two important physical processes in the model. One is the entropy of mixing between the two isotopes; the entropy of mixing is increased by having both isotopes randomly placed at interstitial sites on the lattice and thus impedes the exchange process. The other physical process is the elastic interaction between isotope atoms on the lattice. The elastic interaction is the cause for {beta}-phase formation and is independent of the isotope species. In this report the coupled diffusion equations for two isotopes in the {beta}-phase hydride are solved. A key concept is that the diffusion of one isotope depends not only on its concentration gradient, but also on the concentration gradient of the other isotope. Diffusion rate constants and the chemical potentials for deuterium and hydrogen in the {beta}-phase hydride are reviewed because these quantities are essential for an accurate model of the diffusion process. Finally, a summary of some of the predictions from the SPEM model are provided.

  17. Far Infrared Conductivity of Charge Density Wave Materials and the Oxygen Isotope Effect in High-T{sub c}

    E-Print Network [OSTI]

    Creager, W.N.

    2009-01-01T23:59:59.000Z

    determined. With 180 isotope enrichments of approximatelyand consistent 180 isotope enrichments of approximately 80%.enrichment, 0.90; the same group has reported oxygen isotope

  18. Proton elastic scattering from tin isotopes at 295 MeV and systematic change of neutron density distributions

    E-Print Network [OSTI]

    S. Terashima; H. Sakaguchi; H. Takeda; T. Ishikawa; M. Itoh; T. Kawabata; T. Murakami; M. Uchida; Y. Yasuda; M. Yosoi; J. Zenihiro; H. P. Yoshida; T. Noro; T. Ishida; S. Asaji; T. Yonemura

    2008-02-02T23:59:59.000Z

    Cross sections and analyzing powers for proton elastic scattering from $^{116,118,120,122,124}$Sn at 295 MeV have been measured for a momentum transfer of up to about 3.5 fm$^{-1}$ to deduce systematic changes of the neutron density distribution. We tuned the relativistic Love-Franey interaction to explain the proton elastic scattering of a nucleus whose density distribution is well known. Then, we applied this interaction to deduce the neutron density distributions of tin isotopes. The result of our analysis shows the clear systematic behavior of a gradual increase in the neutron skin thickness of tin isotopes with mass number.

  19. Optically pumped isotopic ammonia laser system

    DOE Patents [OSTI]

    Buchwald, Melvin I. (Santa Fe, NM); Jones, Claude R. (Los Alamos, NM); Nelson, Leonard Y. (Seattle, WA)

    1982-01-01T23:59:59.000Z

    An optically pumped isotopic ammonia laser system which is capable of producing a plurality of frequencies in the middle infrared spectral region. Two optical pumping mechanisms are disclosed, i.e., pumping on R(J) and lasing on P(J) in response to enhancement of rotational cascade lasing including stimulated Raman effects, and, pumping on R(J) and lasing on P(J+2). The disclosed apparatus for optical pumping include a hole coupled cavity and a grating coupled cavity.

  20. Concerning the Facility for Rare Isotope Beams

    ScienceCinema (OSTI)

    Symons, James

    2013-05-29T23:59:59.000Z

    James Symons, Nuclear Science Division Director at Lawrence Berkeley Lab, and Daniela Leitner, head of operations at Berkeley Lab's 88-Inch Cyclotron, discuss major contributions to the new Facility for Rare Isotope Beams (FRIB) at Michigan State University, including ion source, which will based on the VENUS source built for the 88-Inch Cyclotron, and the GRETA gamma-ray detector now under construction there.

  1. Hydrogen isotope separation utilizing bulk getters

    DOE Patents [OSTI]

    Knize, Randall J. (Los Angeles, CA); Cecchi, Joseph L. (Lawrenceville, NJ)

    1990-01-01T23:59:59.000Z

    Tritium and deuterium are separated from a gaseous mixture thereof, derived from a nuclear fusion reactor or some other source, by providing a casing with a bulk getter therein for absorbing the gaseous mixture to produce an initial loading of the getter, partially desorbing the getter to produce a desorbed mixture which is tritium-enriched, pumping the desorbed mixture into a separate container, the remaining gaseous loading in the getter being deuterium-enriched, desorbing the getter to a substantially greater extent to produce a deuterium-enriched gaseous mixture, and removing the deuterium-enriched mixture into another container. The bulk getter may comprise a zirconium-aluminum alloy, or a zirconium-vanadium-iron alloy. The partial desorption may reduce the loading by approximately fifty percent. The basic procedure may be extended to produce a multistage isotope separator, including at least one additional bulk getter into which the tritium-enriched mixture is absorbed. The second getter is then partially desorbed to produce a desorbed mixture which is further tritium-enriched. The last-mentioned mixture is then removed from the container for the second getter, which is then desorbed to a substantially greater extent to produce a desorbed mixture which is deuterium-enriched. The last-mentioned mixture is then removed so that the cycle can be continued and repeated. The method of isotope separation is also applicable to other hydrogen isotopes, in that the method can be employed for separating either deuterium or tritium from normal hydrogen.

  2. Hydrogen isotope separation utilizing bulk getters

    DOE Patents [OSTI]

    Knize, Randall J. (Los Angeles, CA); Cecchi, Joseph L. (Lawrenceville, NJ)

    1991-01-01T23:59:59.000Z

    Tritium and deuterium are separated from a gaseous mixture thereof, derived from a nuclear fusion reactor or some other source, by providing a casing with a bulk getter therein for absorbing the gaseous mixture to produce an initial loading of the getter, partially desorbing the getter to produce a desorbed mixture which is tritium-enriched, pumping the desorbed mixture into a separate container, the remaining gaseous loading in the getter being deuterium-enriched, desorbing the getter to a substantially greater extent to produce a deuterium-enriched gaseous mixture, and removing the deuterium-enriched mixture into another container. The bulk getter may comprise a zirconium-aluminum alloy, or a zirconium-vanadium-iron alloy. The partial desorption may reduce the loading by approximately fifty percent. The basic procedure may be extended to produce a multistage isotope separator, including at least one additional bulk getter into which the tritium-enriched mixture is absorbed. The second getter is then partially desorbed to produce a desorbed mixture which is further tritium-enriched. The last-mentioned mixture is then removed from the container for the second getter, which is then desorbed to a substantially greater extent to produce a desorbed mixture which is deuterium-enriched. The last-mentioned mixture is then removed so that the cycle can be continued and repeated. The method of isotope separation is also applicable to other hydrogen isotopes, in that the method can be employed for separating either deuterium or tritium from normal hydrogen.

  3. FILTR: Flash Isotope Library and Training Resource

    SciTech Connect (OSTI)

    Campbell, D; Trombino, D

    2007-07-26T23:59:59.000Z

    The subject of radiation detection is replete with complex concepts and challenging nomenclature. Furthermore, a daunting variety of radioactive isotopes may be encountered during the routine operation of a radiation detector. Individuals tasked with searching for illicit sources of radiation must remain vigilant while navigating through more frequently encountered mundane and legitimate radioactive sources. The Flash Isotope Library and Training Resource (FILTR) is being developed as an easily accessible and intuitive reference tool to manage the high volume of complex information required for this task. FILTR is an extended version of the Primary Utility for Nuclear Terminology (PUNT) software developed by the Counter Measures Test Beds group at Lawrence Livermore National Laboratory for the United States Secret Service. Authored in the Flash multimedia development environment, FILTR contains detailed information on potentially encountered isotopes as well as training on radiation and operational procedures. Reference material is organized to present critical information quickly while facilitating more in-depth investigation through an intuitive interface and engaging content. FILTR is being developed for a diverse audience of law enforcement organizations and government agencies and a wide range of skill sets from expert analysts to officers whose primary role is not radiation detection. Additionally, the wide compatibility of Flash content will allow FILTR to be readily accessible through the growing number of multi-media enabled electronic devices, including PDAs and cellular phones.

  4. Hydrogen isotope separation utilizing bulk getters

    DOE Patents [OSTI]

    Knize, R.J.; Cecchi, J.L.

    1991-08-20T23:59:59.000Z

    Tritium and deuterium are separated from a gaseous mixture thereof, derived from a nuclear fusion reactor or some other source, by providing a casing with a bulk getter therein for absorbing the gaseous mixture to produce an initial loading of the getter, partially desorbing the getter to produce a desorbed mixture which is tritium-enriched, pumping the desorbed mixture into a separate container, the remaining gaseous loading in the getter being deuterium-enriched, desorbing the getter to a substantially greater extent to produce a deuterium-enriched gaseous mixture, and removing the deuterium-enriched mixture into another container. The bulk getter may comprise a zirconium-aluminum alloy, or a zirconium-vanadium-iron alloy. The partial desorption may reduce the loading by approximately fifty percent. The basic procedure may be extended to produce a multistage isotope separator, including at least one additional bulk getter into which the tritium-enriched mixture is absorbed. The second getter is then partially desorbed to produce a desorbed mixture which is further tritium-enriched. The last-mentioned mixture is then removed from the container for the second getter, which is then desorbed to a substantially greater extent to produce a desorbed mixture which is deuterium-enriched. The last-mentioned mixture is then removed so that the cycle can be continued and repeated. The method of isotope separation is also applicable to other hydrogen isotopes, in that the method can be employed for separating either deuterium or tritium from normal hydrogen. 4 figures.

  5. Stable isotope fractionation by thermal diffusion through partially molten wet and dry silicate rocks

    E-Print Network [OSTI]

    Bindeman, Ilya N.

    isotope redistribution by thermal diffusion leading to enrichment of light isotopes at the hot endStable isotope fractionation by thermal diffusion through partially molten wet and dry silicate 2012 Editor: T.M. Harrison Keywords: thermal diffusion hydrogen isotope separation oxygen isotopes

  6. Physics with Rare Isotope Beams

    SciTech Connect (OSTI)

    Segel, Ralph E. [Northwestern University] [Northwestern University

    2013-11-08T23:59:59.000Z

    Using stable and radioactive beams provided by ATLAS nuclear reactions of special interest in astrophysics have been studied with emphasis on breakout from the hot CNO cycle to the rp-process. The masses of nuclear fragments provided by a strong fission source have been measured in order to help trace the path of the r process. 8Li ions produced by the d(7Li,8Li)n reaction have been trapped and the electrons and alphas emitted in the ensuing beta-decay measured. The neutrino directions were therefore determined, which leads to a measurement of the electron-neutrino correlation. The energies and kinematics are such that a sensitive search for any tensor admixture could be performed and an upper limit of 0.6% was placed on any such admixture. Earlier work on the electromagnetic form factors of the proton was extended. Graduate students were active participants in all of these eperiments, which formed the basis for six PhD theses.

  7. Climate change deduced from isotopes in tree rings

    SciTech Connect (OSTI)

    Pendall, E.G.; Leavitt, S.W.

    1997-11-01T23:59:59.000Z

    This paper describes the theory of carbon, hydrogen, and oxygen isotopic signatures in cellulose for the purpose of paleoclimatic reconstruction. Mechanisms governing tree ring cellulose isotopic variability are investigated, and applications to the southwestern United States are delineated. A monitoring program of pinyon trees and comparison to climatic parameters is briefly described. Variables measured included deviations in hydrogen and oxygen-18 isotopic composition in precipitation, soil water, stem and leaf water, and atmospheric vapor. Water from phloem tissue was found to be isotopically identical to the xylem sap, suggesting that cellulose precursors can exchange isotopically with source water before cellulose is made in the trunk, thus removing most of the isotopic signal from the leaves. Overall results suggest that, on arid sites in the southwestern US receiving adequate summer rain, a precipitation seasonality signal may be recorded. 21 refs., 2 figs.

  8. Enriched Stable Isotope Materials and Chemistry | ornl.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Chemistry SHARE Enriched Stable Isotope Materials and Chemistry Reductiondistillation of calcium-48 metal valued at over 900,000. An inventory of 2,300 batches of...

  9. Copper isotope fractionation in acid mine drainage. | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in acid mine drainage. Abstract: We surveyed the Cu isotopic composition of primary minerals and stream water affected by acid mine drainage in a mineralized watershed located in...

  10. actinium isotopes including: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Topic Index 1 Discovery of the actinium, thorium, protactinium, and uranium isotopes CERN Preprints Summary: Currently, 31 actinium, 31 thorium, 28 protactinium, and 23 uranium...

  11. actinium isotopes: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Topic Index 1 Discovery of the actinium, thorium, protactinium, and uranium isotopes CERN Preprints Summary: Currently, 31 actinium, 31 thorium, 28 protactinium, and 23 uranium...

  12. Helium isotopes in geothermal systems- Iceland, The Geysers,...

    Open Energy Info (EERE)

    Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: Helium isotopes in geothermal systems- Iceland, The Geysers, Raft River and Steamboat Springs...

  13. Sulfur Isotopes as Indicators of Amended Bacterial Sulfate Reduction...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of Amended Bacterial Sulfate Reduction Processes Influencing Field Scale Uranium Bioremediation. Sulfur Isotopes as Indicators of Amended Bacterial Sulfate Reduction Processes...

  14. anomalous isotope effect: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the following recombination Reid, Scott A. 4 Anomalous quantum and isotope effects in water clusters: Physical phenomenon, model artifact, or bad approximation? CERN Preprints...

  15. Geothermal reservoir temperatures estimated from the oxygen isotope...

    Open Energy Info (EERE)

    reservoir temperatures estimated from the oxygen isotope compositions of dissolved sulfate and water from hot springs and shallow drillholes Jump to: navigation, search OpenEI...

  16. Geothermal Reservoir Temperatures Estimated from the Oxygen Isotope...

    Open Energy Info (EERE)

    Temperatures Estimated from the Oxygen Isotope Compositions of Dissolved Sulfate and Water from Hot Springs and Shallow Drillholes Jump to: navigation, search OpenEI Reference...

  17. An Oxygen Isotope Study Of Silicates In The Larderello Geothermal...

    Open Energy Info (EERE)

    Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: An Oxygen Isotope Study Of Silicates In The Larderello Geothermal Field, Italy Abstract...

  18. Chemical And Isotopic Investigation Of Warm Springs Associated...

    Open Energy Info (EERE)

    water (high TDS, > 5000 mgl). Deviations from the meteoric water line are the result of rock-water isotopic exchange, mixing or evaporation. Fluid source regions and residence...

  19. Hydrogeological And Isotopic Survey Of Geothermal Fields In The...

    Open Energy Info (EERE)

    Hydrogeological And Isotopic Survey Of Geothermal Fields In The Buyuk Menderes Graben, Turkey Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article:...

  20. Oxygen And Carbon Isotope Ratios Of Hydrothermal Minerals From...

    Open Energy Info (EERE)

    Oxygen And Carbon Isotope Ratios Of Hydrothermal Minerals From Yellowstone Drill Cores Jump to: navigation, search OpenEI Reference LibraryAdd to library Journal Article: Oxygen...