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Sample records for irradiance dni gef

  1. Solar: monthly and annual average direct normal (DNI) GIS data...

    Open Energy Info (EERE)

    Download Carribean Islands Central America DNI GIS Mexico NREL GEF SWERA UNEP atmospheric water v... solar Additional Info Field Value Source www.nrel.gov Author National Renewable...

  2. DNI-predictability_paper

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    predictable is DNI? An evaluation of hour ahead and day ahead DNI forecasts from four different providers Tobias Gerstmaier 1 , Michael Bührer 2 , Michael Röttger 2 , Andreas Gombert 2 , Clifford W. Hansen 3 , and Joshua S. Stein 3 1 Soitec Solar GmbH, Bötzinger Str. 31, D-79111 Freiburg, Germany, phone +4976121410842, e-mail tobias.gerstmaier@soitec.com 2 Soitec Solar GmbH, Freiburg, Germany 3 Sandia National Laboratories, Albuquerque, NM, USA Abstract. Forecast DNI values in hourly

  3. Turkmenistan-GEF Projects | Open Energy Information

    Open Energy Info (EERE)

    Topics Background analysis Website http:www.gefonline.orgproje Country Turkmenistan Central Asia References GEF Climate Projects1 For a list of GEF climate projects in...

  4. Kenya-GEF Projects | Open Energy Information

    Open Energy Info (EERE)

    database1 GEF Climate Projects in Kenya 1780 Kenya Joint Geophysical Imaging (JGI) Methodology for Geothermal Reservoir Assessment Climate Change UNEP Medium Size Project, GEF...

  5. Kenya Hourly DNI, GHI and Diffuse Solar Data - Datasets - OpenEI...

    Open Energy Info (EERE)

    Kenya Hourly DNI, GHI and Diffuse Solar Data Abstract Each data file is a set of hourly values of solar radiation (DNI, GHI and diffuse) and meteorological elements for a 1-year...

  6. Production of high Resoulution Irradiance Data for Central America...

    Open Energy Info (EERE)

    irradiance (GHI) and direct irradiance (DNI) data sets for the countries of Cuba, El Salvador, Guatemala, Honduras and Nicaragua. Much of our initial effort focused on building up...

  7. GE???F1????????? | GE Global Research

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    GEF1 Click to email this to a friend (Opens in new window) Share on Facebook (Opens in new window) Click to share (Opens in new window) Click...

  8. GEF-Colombia-Geothermal Energy Grant | Open Energy Information

    Open Energy Info (EERE)

    Colombia-Geothermal Energy Grant Jump to: navigation, search Name GEF-Colombia-Geothermal Energy Grant AgencyCompany Organization Global Environment Facility (GEF),...

  9. UNEP-GEF Renewable Energy Project Financial Risk Management in...

    Open Energy Info (EERE)

    GEF Renewable Energy Project Financial Risk Management in Developing Countries Jump to: navigation, search Name UNEP-GEF Renewable Energy Project Financial Risk Management in...

  10. Shock initiation of 2,4-dinitroimidazole (2,4-DNI)

    SciTech Connect (OSTI)

    Urtiew, P.A.; Tarver, C.M.; Simpson, R.L.

    1995-07-19

    The shock sensitivity of the pressed solid explosive 2,4-dinitroimidazole (2,4-DNI) was determined using the embedded manganin pressure gauge technique. At an initial shock pressure of 2 GPa, several microseconds were required before any exothermic reaction was observed. At 4 GPa, 2,4-DNI reacted more rapidly but did not transition to detonation at the 12 mm deep gauge position. At 6 GPa, detonation occurred in less than 6 mm of shock propagation. Thus, 2,4-DNI is more shock sensitive than TATB-based explosives but is considerably less shock sensitive than HMX-based explosives. An Ignition and Growth reactive flow model for 2,4-DNI based on these gauge records showed that 2,4-DNI exhibits shock initiation characteristics similar to TATB but reacts faster. The chemical structure of 2,4-DNI suggests that it may exhibit thermal decomposition reactions similar to nitroguanine and explosives with similar ring structures, such as ANTA and NTO.

  11. Peru-GEF Nationally Appropriate Mitigation Actions in the Energy...

    Open Energy Info (EERE)

    (Redirected from UNDP-Peru GEF Nationally Appropriate Mitigation Actions in the Energy Generation and End-Use Sectors)...

  12. GEF-Knowledge Management Initiative | Open Energy Information

    Open Energy Info (EERE)

    AgencyCompany Organization Global Environment Facility (GEF) Resource Type Dataset, Lessons learnedbest practices Website http:www.thegef.orggefsite Program Start 2010...

  13. UNDP-GEF Fuel Cell Bus Programme: Update | Open Energy Information

    Open Energy Info (EERE)

    GEF Fuel Cell Bus Programme: Update Jump to: navigation, search Tool Summary LAUNCH TOOL Name: UNDP-GEF Fuel Cell Bus Programme: Update AgencyCompany Organization: United Nations...

  14. China Renewable Energy Scale up Program CRESP GOC WB GEF | Open...

    Open Energy Info (EERE)

    up Program CRESP GOC WB GEF Jump to: navigation, search Name: China Renewable Energy Scale-up Program (CRESP) GOCWBGEF Place: Beijing, Beijing Municipality, China Zip: 100038...

  15. Direct normal irradiance related definitions and applications: The circumsolar issue

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Blanc, P.; Espinar, B.; Geuder, N.; Gueymard, C.; Meyer, R.; Pitz-Paal, R.; Reinhardt, B.; Renne, D.; Segupta, M.; Wald, L.; et al

    2014-10-21

    The direct irradiance received on a plane normal to the sun, called direct normal irradiance (DNI), is of particular relevance to concentrated solar technologies, including concentrating solar thermal plants and concentrated photovoltaic systems. Following various standards from the International Organization for Standardization (ISO), the DNI definition is related to the irradiance from a small solid angle of the sky, centered on the position of the sun. Half-angle apertures of pyrheliometers measuring DNI have varied over time, up to ≈10°. The current recommendation of the World Meteorological Organization (WMO) for this half-angle is 2.5°. Solar concentrating collectors have an angular acceptancemore » function that can be significantly narrower, especially for technologies with high concentration ratios. The disagreement between the various interpretations of DNI, from the theoretical definition used in atmospheric physics and radiative transfer modeling to practical definitions corresponding to specific measurements or conversion technologies is significant, especially in the presence of cirrus clouds or large concentration of aerosols. Under such sky conditions, the circumsolar radiation—i.e. the diffuse radiation coming from the vicinity of the sun—contributes significantly to the DNI ground measurement, although some concentrating collectors cannot utilize the bulk of it. These issues have been identified in the EU-funded projects MACC-II (Monitoring Atmospheric Composition and Climate-Interim Implementation) and SFERA (Solar Facilities for the European Research Area), and have been discussed within a panel of international experts in the framework of the Solar Heating and Cooling (SHC) program of the International Energy Agency’s (IEA’s) Task 46 “Solar Resource Assessment and Forecasting”. In accordance with these discussions, the terms of reference related to DNI are specified here. The important role of circumsolar radiation is evidenced, and its potential contribution is evaluated for typical atmospheric conditions. Thus, thorough analysis of performance of concentrating solar systems, it is recommended that, in addition to the conventional DNI related to 2.5° half-angle of today’s pyrheliometers, solar resource data sets also report the sunshape, the circumsolar contribution or the circumsolar ratio (CSR).« less

  16. Recognition of the Activated States of G[alpha]13 by the rgRGS Domain of PDZRhoGEF

    SciTech Connect (OSTI)

    Chen, Zhe; Singer, William D.; Danesh, Shahab M.; Sternweis, Paul C.; Sprang, Stephen R.

    2009-12-01

    G12 class heterotrimeric G proteins stimulate RhoA activation by RGS-RhoGEFs. However, p115RhoGEF is a GTPase Activating Protein (GAP) toward G{alpha}13, whereas PDZRhoGEF is not. We have characterized the interaction between the PDZRhoGEF rgRGS domain (PRG-rgRGS) and the alpha subunit of G13 and have determined crystal structures of their complexes in both the inactive state bound to GDP and the active states bound to GDP {center_dot} AlF (transition state) and GTP{gamma}S (Michaelis complex). PRG-rgRGS interacts extensively with the helical domain and the effector-binding sites on G{alpha}13 through contacts that are largely conserved in all three nucleotide-bound states, although PRG-rgRGS has highest affinity to the Michaelis complex. An acidic motif in the N terminus of PRG-rgRGS occupies the GAP binding site of G{alpha}13 and is flexible in the GDP {center_dot} AlF complex but well ordered in the GTPS complex. Replacement of key residues in this motif with their counterparts in p115RhoGEF confers GAP activity.

  17. Activated RhoA Binds to the Pleckstrin Homology (PH) Domain of PDZ-RhoGEF, a Potential Site for Autoregulation

    SciTech Connect (OSTI)

    Chen, Zhe; Medina, Frank; Liu, Mu-ya; Thomas, Celestine; Sprang, Stephen R.; Sternweis, Paul C.

    2010-07-19

    Guanine nucleotide exchange factors (GEFs) catalyze exchange of GDP for GTP by stabilizing the nucleotide-free state of the small GTPases through their Dbl homology/pleckstrin homology (DH {center_dot} PH) domains. Unconventionally, PDZ-RhoGEF (PRG), a member of the RGS-RhoGEFs, binds tightly to both nucleotide-free and activated RhoA (RhoA {center_dot} GTP). We have characterized the interaction between PRG and activated RhoA and determined the structure of the PRG-DH {center_dot} PH-RhoA {center_dot} GTP{gamma}S (guanosine 5{prime}-O-[{gamma}-thio]triphosphate) complex. The interface bears striking similarity to a GTPase-effector interface and involves the switch regions in RhoA and a hydrophobic patch in PRG-PH that is conserved among all Lbc RhoGEFs. The two surfaces that bind activated and nucleotide-free RhoA on PRG-DH {center_dot} PH do not overlap, and a ternary complex of PRG-DH {center_dot} PH bound to both forms of RhoA can be isolated by size-exclusion chromatography. This novel interaction between activated RhoA and PH could play a key role in regulation of RhoGEF activity in vivo.

  18. Insights into the Molecular Activation Mechanism of the RhoA-specific Guanine Nucleotide Exchange Factor, PDZRhoGEF

    SciTech Connect (OSTI)

    Bielnicki, Jakub A.; Shkumatov, Alexander V.; Derewenda, Urszula; Somlyo, Avril V.; Svergun, Dmitri I.; Derewenda, Zygmunt S.

    2012-10-09

    PDZRhoGEF (PRG) belongs to a small family of RhoA-specific nucleotide exchange factors that mediates signaling through select G-protein-coupled receptors via G{alpha}{sub 12/13} and activates RhoA by catalyzing the exchange of GDP to GTP. PRG is a multidomain protein composed of PDZ, regulators of G-protein signaling-like (RGSL), Dbl-homology (DH), and pleckstrin-homology (PH) domains. It is autoinhibited in cytosol and is believed to undergo a conformational rearrangement and translocation to the membrane for full activation, although the molecular details of the regulation mechanism are not clear. It has been shown recently that the main autoregulatory elements of PDZRhoGEF, the autoinhibitory 'activation box' and the 'GEF switch,' which is required for full activation, are located directly upstream of the catalytic DH domain and its RhoA binding surface, emphasizing the functional role of the RGSL-DH linker. Here, using a combination of biophysical and biochemical methods, we show that the mechanism of PRG regulation is yet more complex and may involve an additional autoinhibitory element in the form of a molten globule region within the linker between RGSL and DH domains. We propose a novel, two-tier model of autoinhibition where the activation box and the molten globule region act synergistically to impair the ability of RhoA to bind to the catalytic DH-PH tandem. The molten globule region and the activation box become less ordered in the PRG-RhoA complex and dissociate from the RhoA-binding site, which may constitute a critical step leading to PRG activation.

  19. Transforming on-grid renewable energy markets. A review of UNDP-GEF support for feed-in tariffs and related price and market-access instruments

    SciTech Connect (OSTI)

    Glemarec, Yannick; Rickerson, Wilson; Waissbein, Oliver

    2012-11-15

    As a Global Environment Facility (GEF) founding implementing agency, UNDP has worked on over 230 GEF-supported clean energy projects in close to 100 developing countries since 1992. About 100 of these projects in 80 countries have focused on renewable energy, supported by approximately US $ 293 million in GEF funds and leveraging US $1.48 billion in associated co-financing from national governments, international organizations, the private sector and non-governmental organizations. As part of UNDP efforts to codify and share lessons learnt from these initiatives, this report addresses how scarce public resources can be used to catalyze larger private financial flows for renewable energy. It provides an overview of UNDP-GEF’s extensive work supporting development of national renewable energy policies such as feed-in tariffs. In these activities UNDP-GEF assists developing countries to assess key risks and barriers to technology diffusion and then to identify a mix of policy and financial de-risking measures to remove these barriers and drive investment. This approach is illustrated through three case studies in Uruguay, Mauritius and Kazakhstan. This report is complemented by a companion publication presenting an innovative UNDP financial modeling tool to assist policymakers in appraising different public instruments to promote clean energy.

  20. Comminuting irradiated ferritic steel

    DOE Patents [OSTI]

    Bauer, Roger E. (Kennewick, WA); Straalsund, Jerry L. (Kennewick, WA); Chin, Bryan A. (Auburn, AL)

    1985-01-01

    Disclosed is a method of comminuting irradiated ferritic steel by placing the steel in a solution of a compound selected from the group consisting of sulfamic acid, bisulfate, and mixtures thereof. The ferritic steel is used as cladding on nuclear fuel rods or other irradiated components.

  1. Irradiation Creep in Graphite

    SciTech Connect (OSTI)

    Ubic, Rick; Butt, Darryl; Windes, William

    2014-03-13

    An understanding of the underlying mechanisms of irradiation creep in graphite material is required to correctly interpret experimental data, explain micromechanical modeling results, and predict whole-core behavior. This project will focus on experimental microscopic data to demonstrate the mechanism of irradiation creep. High-resolution transmission electron microscopy should be able to image both the dislocations in graphite and the irradiation-induced interstitial clusters that pin those dislocations. The team will first prepare and characterize nanoscale samples of virgin nuclear graphite in a transmission electron microscope. Additional samples will be irradiated to varying degrees at the Advanced Test Reactor (ATR) facility and similarly characterized. Researchers will record microstructures and crystal defects and suggest a mechanism for irradiation creep based on the results. In addition, the purchase of a tensile holder for a transmission electron microscope will allow, for the first time, in situ observation of creep behavior on the microstructure and crystallographic defects.

  2. Global Environment Fund GEF | Open Energy Information

    Open Energy Info (EERE)

    Invests in companies that make positive contributions to environmental quality, human health and sustainable management of resources. References: Global Environment Fund...

  3. SAND2014-4277C © Copyright 2013, First Solar, Inc.

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    277C © Copyright 2013, First Solar, Inc. 2 © Copyright 2013, First Solar, Inc. Summary * This is a preview of work of forthcoming publications (PVSC 40 oral presentation and paper, Sandia technical report) * Estimating plane of array (POA) irradiance often requires a sequence of models: - Decomposition: GHI to direct normal irradiance (DNI) and diffuse horizontal irradiance (DHI) - Transposition: GHI, DNI and DHI to total irradiance in POA * Many choices are available for each step - E.g.,

  4. File:NREL-bhutan-10kmsolar-dni.pdf | Open Energy Information

    Open Energy Info (EERE)

    navigation, search File File history File usage Bhutan - Annual Direct Normal Solar Radiation Size of this preview: 776 600 pixels. Full resolution (1,650 1,275 pixels,...

  5. Tritium Related Material Research -Irradiation Effect on Isotropic...

    Office of Environmental Management (EM)

    Related Material Research -Irradiation Effect on Isotropic Graphite Utilizing Heavy Ion-Irradiation- Tritium Related Material Research -Irradiation Effect on Isotropic Graphite...

  6. Neutron Irradiation of Hydrided Cladding Material in HFIR Summary...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    (HFIR). Irradiation of the capsules was conducted for post-irradiation examination (PIE) metallography. PDF icon Neutron Irradiation of Hydrided Cladding Material in HFIR...

  7. Statistical criteria for characterizing irradiance time series.

    SciTech Connect (OSTI)

    Stein, Joshua S.; Ellis, Abraham; Hansen, Clifford W.

    2010-10-01

    We propose and examine several statistical criteria for characterizing time series of solar irradiance. Time series of irradiance are used in analyses that seek to quantify the performance of photovoltaic (PV) power systems over time. Time series of irradiance are either measured or are simulated using models. Simulations of irradiance are often calibrated to or generated from statistics for observed irradiance and simulations are validated by comparing the simulation output to the observed irradiance. Criteria used in this comparison should derive from the context of the analyses in which the simulated irradiance is to be used. We examine three statistics that characterize time series and their use as criteria for comparing time series. We demonstrate these statistics using observed irradiance data recorded in August 2007 in Las Vegas, Nevada, and in June 2009 in Albuquerque, New Mexico.

  8. Ultrasonic Transducer Irradiation Test Results

    SciTech Connect (OSTI)

    Daw, Joshua; Palmer, Joe; Ramuhalli, Pradeep; Keller, Paul; Montgomery, Robert; Chien, Hual-Te; Kohse, Gordon; Tittmann, Bernhard; Reinhardt, Brian; Rempe, Joy

    2015-02-01

    Ultrasonic technologies offer the potential for high-accuracy and -resolution in-pile measurement of a range of parameters, including geometry changes, temperature, crack initiation and growth, gas pressure and composition, and microstructural changes. Many Department of Energy-Office of Nuclear Energy (DOE-NE) programs are exploring the use of ultrasonic technologies to provide enhanced sensors for in-pile instrumentation during irradiation testing. For example, the ability of small diameter ultrasonic thermometers (UTs) to provide a temperature profile in candidate metallic and oxide fuel would provide much needed data for validating new fuel performance models. Other ongoing efforts include an ultrasonic technique to detect morphology changes (such as crack initiation and growth) and acoustic techniques to evaluate fission gas composition and pressure. These efforts are limited by the lack of identified ultrasonic transducer materials capable of long term performance under irradiation test conditions. For this reason, the Pennsylvania State University (PSU) was awarded an ATR NSUF project to evaluate the performance of promising magnetostrictive and piezoelectric transducers in the Massachusetts Institute of Technology Research Reactor (MITR) up to a fast fluence of at least 1021 n/cm2. The goal of this research is to characterize and demonstrate magnetostrictive and piezoelectric transducer operation during irradiation, enabling the development of novel radiation-tolerant ultrasonic sensors for use in Material Testing Reactors (MTRs). As such, this test is an instrumented lead test and real-time transducer performance data is collected along with temperature and neutron and gamma flux data. The current work bridges the gap between proven out-of-pile ultrasonic techniques and in-pile deployment of ultrasonic sensors by acquiring the data necessary to demonstrate the performance of ultrasonic transducers. To date, one piezoelectric transducer and two magnetostrictive transducers have demonstrated reliable operation under irradiation. The irradiation is ongoing.

  9. RERTR-13 Irradiation Summary Report

    SciTech Connect (OSTI)

    D. M. Perez; M. A. Lillo; G. S. Chang; D. M. Wachs; G. A. Roth; N. E. Woolstenhulme

    2012-09-01

    The Reduced Enrichment for Research and Test Reactor (RERTR) experiment RERTR-13 was designed to assess performance of different types of neutron absorbers that can be potentially used as burnable poisons in the low enriched uranium-molybdenum based dispersion and monolithic fuels.1 The following report summarizes the life of the RERTR-13 experiment through end of irradiation, including as-run neutronic analysis results, thermal analysis results and hydraulic testing results.

  10. Investing in Sustainable Transport and Urban Systems: The GEF...

    Open Energy Info (EERE)

    expand clean public transportation choices that also have the added benefits of lowering air pollution and reducing traffic congestion. LEDSGP green logo.png This tool is included...

  11. UNDP/GEF-Cambodia-Sustainable Forest Management | Open Energy...

    Open Energy Info (EERE)

    be carried out through community forestry activities to engage rural communities in nature conservation and create markets for sustainable bio-energy technologies to help curb...

  12. Irradiation preservation of seafood: Literature review

    SciTech Connect (OSTI)

    Molton, P.M.

    1987-10-01

    The application of gamma-irradiation for extending the shelf life of seafood has been of interest for many years. This report reviews a number of studies on seafood irradiation conducted over the past several years. Topics covered include seafood irradiation techniques and dosages, species applicability and differences, the effects of packaging on seafood preservation, and changes in organoleptic acceptability as a result of irradiation. Particular attention is given to radiation effects (likely and unlikely) of concern to the public. These include the potential for generation of toxic chemical products, botulinum toxin production, and other health concerns. No scientifically defensible evidence of any kind was found for any harmful effect of irradiation of seafoods at the doses being considered (less than 300 krad), and all indications are that irradiation is an acceptable and needed additional tool for seafood preservation. 49 refs., 14 figs., 14 tabs.

  13. Enterprise Assessments, Oak Ridge National Laboratory Irradiated...

    Office of Environmental Management (EM)

    Fuels Examination Laboratory - April 2015 April 2015 Review of the Safety-Significant Ventilation Systems at the Irradiated Fuels Examination Laboratory Operated by UT-Battelle...

  14. A New Solar Irradiance Reference Spectrum

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A New Solar Irradiance Reference Spectrum Pilewskie, Peter University of Colorado Fontenla, Juan LASP University of Colorado Harder, Jerry LASP University of Colorado Category:...

  15. Modeling and Analysis of CSP Systems (Fact Sheet), Thermal Systems Group: CSP Capabilities (TSG)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Assessing the Solar Resource All CSP technologies use collectors to focus sunlight onto receivers in the process of converting solar energy to electricity. CSP systems rely on "seeing" the direct solar beam-known as Direct Normal Irradiance (DNI); consequently, measuring, mapping, and modeling the DNI resource are essential. In the Solar Resource and Meteorological Assessment Project (SOLRMAP), NREL collaborates with multiple industry partners to collect precise, long-term solar

  16. AGR-1 Post Irradiation Examination Final Report

    SciTech Connect (OSTI)

    Demkowicz, Paul Andrew

    2015-08-01

    The post-irradiation examination (PIE) of the Advanced Gas Reactor (AGR)-1 experiment was a multi-year, collaborative effort between Idaho National Laboratory (INL) and Oak Ridge National Laboratory (ORNL) to study the performance of UCO (uranium carbide, uranium oxide) tristructural isotropic (TRISO) coated particle fuel fabricated in the U.S. and irradiated at the Advanced Test Reactor at INL to a peak burnup of 19.6% fissions per initial metal atom. This work involved a broad array of experiments and analyses to evaluate the level of fission product retention by the fuel particles and compacts (both during irradiation and during post-irradiation heating tests to simulate reactor accident conditions), investigate the kernel and coating layer morphology evolution and the causes of coating failure, and explore the migration of fission products through the coating layers. The results have generally confirmed the excellent performance of the AGR-1 fuel, first indicated during the irradiation by the observation of zero TRISO coated particle failures out of 298,000 particles in the experiment. Overall release of fission products was determined by PIE to have been relatively low during the irradiation. A significant finding was the extremely low levels of cesium released through intact coatings. This was true both during the irradiation and during post-irradiation heating tests to temperatures as high as 1800C. Post-irradiation safety test fuel performance was generally excellent. Silver release from the particles and compacts during irradiation was often very high. Extensive microanalysis of fuel particles was performed after irradiation and after high-temperature safety testing. The results of particle microanalysis indicate that the UCO fuel is effective at controlling the oxygen partial pressure within the particle and limiting kernel migration. Post-irradiation examination has provided the final body of data that speaks to the quality of the AGR-1 fuel, building on the as-fabricated fuel characterization and irradiation data. In addition to the extensive volume of results generated, the work also resulted in a number of novel analysis techniques and lessons learned that are being applied to the examination of fuel from subsequent TRISO fuel irradiations. This report provides a summary of the results obtained as part of the AGR-1 PIE campaign over its approximately 5-year duration.

  17. RERTR-7 Irradiation Summary Report

    SciTech Connect (OSTI)

    D. M. Perez; M. A. Lillo; G. S. Chang; G. A. Roth; N. E. Woolstenhulme; D. M. Wachs

    2011-12-01

    The Reduced Enrichment for Research and Test Reactor (RERTR) experiment RERTR-7A, was designed to test several modified fuel designs to target fission densities representative of a peak low enriched uranium (LEU) burnup in excess of 90% U-235 at peak experiment power sufficient to generate a peak surface heat flux of approximately 300 W/cm2. The RERTR-7B experiment was designed as a high power test of 'second generation' dispersion fuels at peak experiment power sufficient to generate a surface heat flux on the order of 230 W/cm2.1 The following report summarizes the life of the RERTR-7A and RERTR-7B experiments through end of irradiation, including as-run neutronic analyses, thermal analyses and hydraulic testing results.

  18. PV Derived Data for Predicting Performance; NREL (National Renewable Energy Laboratory)

    SciTech Connect (OSTI)

    Marion, Bill

    2015-09-14

    A method is described for providing solar irradiance data for modeling PV performance by using measured PV performance data and back-solving for the unknown direct normal irradiance (DNI) and diffuse horizontal irradiance (DHI), which can then be used to model the performance of PV systems of any size, PV array tilt, or PV array azimuth orientation. Ideally situated for using the performance data from PV modules with micro-inverters, the PV module operating current is used to determine the global tilted irradiance (GTI), and a separation model is then used to determine the DNI and DHI from the GTI.

  19. Methods for Post Irradiation Examination of Tritium Producing...

    Office of Environmental Management (EM)

    Methods for Post Irradiation Examination of Tritium Producing Burnable Absorber Rods Methods for Post Irradiation Examination of Tritium Producing Burnable Absorber Rods...

  20. Irradiation Effects on Human Cortical Bone Fracture Behavior

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Irradiation Effects on Human Cortical Bone Fracture Behavior Irradiation Effects on Human Cortical Bone Fracture Behavior Print Wednesday, 28 July 2010 00:00 Human bone is strong...

  1. Post Irradiation Examination of Stainless Steel Cladding from...

    Office of Environmental Management (EM)

    Post Irradiation Examination of Stainless Steel Cladding from In-Reactor Permeation Experiment Post Irradiation Examination of Stainless Steel Cladding from In-Reactor Permeation...

  2. APPLICATION OF PHASE-FIELD MODELING TO IRRADIATION EFFECTS IN...

    Office of Scientific and Technical Information (OSTI)

    APPLICATION OF PHASE-FIELD MODELING TO IRRADIATION EFFECTS IN MATERIALS Citation Details In-Document Search Title: APPLICATION OF PHASE-FIELD MODELING TO IRRADIATION EFFECTS IN ...

  3. Working with SRNL - Our Facilities- Gamma Irradiation Facility

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for irradiating solid and liquid samples, allowing a wide range of tests to determine the effects of radiation on materials. Typically, the Gamma Irradiation Facility is used to...

  4. Measuring Degradation Rates Without Irradiance Data

    SciTech Connect (OSTI)

    Pulver, S.; Cormode, D.; Cronin, A.; Jordan, D.; Kurtz, S.; Smith, R.

    2011-02-01

    A method to report PV system degradation rates without using irradiance data is demonstrated. First, a set of relative degradation rates are determined by comparing daily AC final yields from a group of PV systems relative to the average final yield of all the PV systems. Then, the difference between relative and absolute degradation rates is found from a statistical analysis. This approach is verified by comparing to methods that utilize irradiance data. This approach is significant because PV systems are often deployed without irradiance sensors, so the analysis method described here may enable measurements of degradation using data that were previously thought to be unsuitable for degradation studies.

  5. Gamma-ray irradiated polymer optical waveguides

    SciTech Connect (OSTI)

    Lai, C.-C.; Wei, T.-Y.; Chang, C.-Y.; Wang, W.-S.; Wei, Y.-Y.

    2008-01-14

    Optical waveguides fabricated by gamma-ray irradiation on polymer through a gold mask are presented. The gamma-ray induced index change is found almost linearly dependent on the dose of the irradiation. And the measured propagation losses are low enough for practical application. Due to the high penetrability of gamma ray, uniform refractive index change in depth can be easily achieved. Moreover, due to large-area printing, the uniformity of waveguide made by gamma-ray irradiation is much better than that by e-beam direct writing.

  6. ARM - Measurement - Shortwave broadband diffuse downwelling irradiance

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    diffuse downwelling irradiance ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Shortwave broadband diffuse downwelling irradiance All of the solar radiation, across the wavelength range of 0.4 and 4 {mu}m, coming directly from the sky except for solar radiation coming directly from the sun and the circumsolar irradiance within approximately three degrees of the sun. Categories Radiometric Instruments

  7. Sandia National Laboratories: Research: Facilities: Gamma Irradiation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    second. The neutron irradiation system consisting of the AmBe source and a large polyethylene chamber provides neutron dose rates from 10-6 radsecond to 10-5 radsecond....

  8. Gamma irradiation effects in W films

    SciTech Connect (OSTI)

    Claro, Luiz H.; Santos, Ingrid A.; Silva, Cassia F.

    2013-05-06

    Using the van Der Pauw methodology, the surface resistivity of irradiated tungsten films deposited on Silicon substrate was measured. The films were exposed to {gamma} radiation using a isotopic {sup 60}Co source in three irradiation stages attaining 40.35 kGy in total dose. The obtained results for superficial resistivity display a time annealing features and their values are proportional to the total dose.

  9. Neutron Irradiation Resistance of RAFM Steels

    SciTech Connect (OSTI)

    Gaganidze, Ermile; Dafferner, Bernhard; Aktaa, Jarir

    2008-07-01

    The neutron irradiation resistance of the reduced-activation ferritic/martensitic (RAFM) steel EUROFER97 and international reference steels (F82H-mod, OPTIFER-Ia, GA3X and MANET-I) have been investigated after irradiation in the Petten High Flux Reactor up to 16.3 dpa at different irradiation temperatures (250-450 deg. C). The embrittlement behavior and hardening are investigated by instrumented Charpy-V tests with sub-size specimens. Neutron irradiation-induced embrittlement and hardening of EUROFER97 was studied under different heat treatment conditions. Embrittlement and hardening of as-delivered EUROFER97 steel are comparable to those of reference steels. Heat treatment of EUROFER97 at a higher austenitizing temperature substantially improves the embrittlement behaviour at low irradiation temperatures. Analysis of embrittlement vs. hardening behavior of RAFM steels within a proper model in terms of the parameter C={delta}DBTT/{delta}{sigma} indicates hardening-dominated embrittlement at irradiation temperatures below 350 deg. C with 0.17 {<=} C {<=} 0.53 deg. C/MPa. Scattering of C at irradiation temperatures above 400 deg. C indicates non hardening embrittlement. A role of He in a process of embrittlement is investigated in EUROFER97 based steels, that are doped with different contents of natural B and the separated {sup 10}B-isotope (0.008-0.112 wt.%). Testing on small scale fracture mechanical specimens for determination of quasi-static fracture toughness will be also presented in a view of future irradiation campaigns. (authors)

  10. ARM - Measurement - Longwave broadband downwelling irradiance

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    downwelling irradiance ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Longwave broadband downwelling irradiance The total diffuse and direct radiant energy, at wavelengths longer than approximately 4 {mu}m, that is being emitted downwards. Categories Radiometric Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file

  11. ARM - Measurement - Longwave broadband net irradiance

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    net irradiance ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Longwave broadband net irradiance The difference between upwelling and downwelling broadband longwave radiation. Categories Radiometric Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a list of all available

  12. ARM - Measurement - Longwave broadband upwelling irradiance

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    upwelling irradiance ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Longwave broadband upwelling irradiance The rate at which radiant energy, at a wavelength longer than approximately 4 {mu}m, is being emitted upwards into a radiation field and transferred across a surface area (real or imaginary) in a hemisphere of directions. Categories Radiometric Instruments The above measurement is considered

  13. ARM - Measurement - Longwave narrowband upwelling irradiance

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    narrowband upwelling irradiance ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Longwave narrowband upwelling irradiance The total radiant energy, in a narrow band of wavelengths longer than approximately 4 {mu}m, passing through a horizontal unit area in an upward direction. Categories Radiometric Instruments The above measurement is considered scientifically relevant for the following instruments.

  14. ARM - Measurement - Net broadband total irradiance

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    govMeasurementsNet broadband total irradiance ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Net broadband total irradiance The difference between upwelling and downwelling, covering longwave and shortwave radiation. Categories Radiometric Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each

  15. ARM - Measurement - Shortwave broadband direct downwelling irradiance

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    downwelling irradiance ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Shortwave broadband direct downwelling irradiance Radiant energy, across the wavelength range of 0.4 and 4 {mu}m, that is transferred directly from the sun to the receiver. Categories Radiometric Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf)

  16. ARM - Measurement - Shortwave broadband total downwelling irradiance

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    total downwelling irradiance ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Shortwave broadband total downwelling irradiance The total diffuse and direct radiant energy that comes from some continuous range of directions, at wavelengths between 0.4 and 4 {mu}m, that is being emitted downwards. Categories Radiometric Instruments The above measurement is considered scientifically relevant for the

  17. ARM - Measurement - Shortwave broadband total net irradiance

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    net irradiance ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Shortwave broadband total net irradiance The difference between upwelling and downwelling broadband shortwave radiation. Categories Radiometric Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream (netcdf) file headers of each instrument for a list of all available

  18. ARM - Measurement - Shortwave narrowband diffuse downwelling irradiance

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    downwelling irradiance ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Shortwave narrowband diffuse downwelling irradiance The rate at which radiant energy in narrow bands of wavelengths shorter than approximately 4 {mu}m, that has been scattered in the atmosphere at least once, passes through a horizontal unit area in a downward direction. Categories Radiometric Instruments The above measurement is

  19. ARM - Measurement - Shortwave narrowband diffuse upwelling irradiance

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    upwelling irradiance ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Shortwave narrowband diffuse upwelling irradiance The rate at which radiant energy in narrow bands of wavelengths shorter than approximately 4 {mu}m, that has been scattered in the atmosphere at least once, passes through a horizontal unit area in an upward direction. Categories Radiometric Instruments The above measurement is

  20. ARM - Measurement - Shortwave narrowband direct downwelling irradiance

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    downwelling irradiance ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Shortwave narrowband direct downwelling irradiance The direct unscattered radiant energy from the Sun, in a narrow band of wavelengths shorter than approximately 4 {mu}m, passing through a horizontal unit area in a downward direction. Categories Radiometric Instruments The above measurement is considered scientifically relevant for

  1. ARM - Measurement - Shortwave narrowband total downwelling irradiance

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    downwelling irradiance ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Shortwave narrowband total downwelling irradiance The rate at which radiant energy, in narrow bands of wavelengths shorter than approximately 4 {mu}m, passes through a horizontal unit area in a downward direction. Categories Radiometric Instruments The above measurement is considered scientifically relevant for the following

  2. ARM - Measurement - Shortwave narrowband total upwelling irradiance

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    upwelling irradiance ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Shortwave narrowband total upwelling irradiance The rate at which radiant energy, in narrow bands of wavelengths shorter than approximately 4 {mu}m, passes through a horizontal unit area in an upward direction. Categories Radiometric Instruments The above measurement is considered scientifically relevant for the following instruments.

  3. ARM - Measurement - Shortwave spectral diffuse downwelling irradiance

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    diffuse downwelling irradiance ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Shortwave spectral diffuse downwelling irradiance The rate at which spectrally resolved radiant energy at wavelengths shorter than approximately 4 {mu}m, that has been scattered in the atmosphere at least once, passes through a horizontal unit area in a downward direction. Categories Radiometric Instruments The above

  4. ARM - Measurement - Shortwave spectral direct normal irradiance

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    direct normal irradiance ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Shortwave spectral direct normal irradiance The narrow spectral range of measurements coming directly from the sun whose wavelength falls within the solar range of 0.4 and 4 {mu}m. Categories Radiometric Instruments The above measurement is considered scientifically relevant for the following instruments. Refer to the datastream

  5. Measurement of Diameter Changes during Irradiation Testing

    SciTech Connect (OSTI)

    Davis, K. L.; Knudson, D. L.; Crepeau, J. C.; Solstad, S.

    2015-03-01

    New materials are being considered for fuel, cladding, and structures in advanced and existing nuclear reactors. Such materials can experience significant dimensional and physical changes during irradiation. Currently in the US, such changes are measured by repeatedly irradiating a specimen for a specified period of time and then removing it from the reactor for evaluation. The time and labor to remove, examine, and return irradiated samples for each measurement makes this approach very expensive. In addition, such techniques provide limited data and handling may disturb the phenomena of interest. In-pile detection of changes in geometry is sorely needed to understand real-time behavior during irradiation testing of fuels and materials in high flux US Material and Test Reactors (MTRs). This paper presents development results of an advanced Linear Variable Differential Transformer-based test rig capable of detecting real-time changes in diameter of fuel rods or material samples during irradiation in US MTRs. This test rig is being developed at the Idaho National Laboratory and will provide experimenters with a unique capability to measure diameter changes associated with fuel and cladding swelling, pellet-clad interaction, and crud buildup.

  6. Review of recent irradiation-creep results

    SciTech Connect (OSTI)

    Coghlan, W.A.

    1982-05-01

    Materials deform faster under stress in the presence of irradiation by a process known as irradiation creep. This phenomenon is important to reactor design and has been the subject of a large number of experimental and theoretical investigations. The purpose of this work is to review the recent experimental results to obtain a summary of these results and to determine those research areas that require additional information. The investigations have been classified into four subgroups based on the different experimental methods used. These four are: (1) irradiation creep using stress relaxation methods, (2) creep measurements using pressurized tubes, (3) irradiation creep from constant applied load, and (4) irradiation creep experiments using accelerated particles. The similarity and the differences of the results from these methods are discussed and a summary of important results and suggested areas for research is presented. In brief, the important results relate to the dependence of creep on swelling, temperature, stress state and alloying additions. In each of these areas new results have been presented and new questions have arisen which require further research to answer. 65 references.

  7. Horizontal modular dry irradiated fuel storage system

    DOE Patents [OSTI]

    Fischer, Larry E. (Los Gatos, CA); McInnes, Ian D. (San Jose, CA); Massey, John V. (San Jose, CA)

    1988-01-01

    A horizontal, modular, dry, irradiated fuel storage system (10) includes a thin-walled canister (12) for containing irradiated fuel assemblies (20), which canister (12) can be positioned in a transfer cask (14) and transported in a horizontal manner from a fuel storage pool (18), to an intermediate-term storage facility. The storage system (10) includes a plurality of dry storage modules (26) which accept the canister (12) from the transfer cask (14) and provide for appropriate shielding about the canister (12). Each module (26) also provides for air cooling of the canister (12) to remove the decay heat of the irradiated fuel assemblies (20). The modules (26) can be interlocked so that each module (26) gains additional shielding from the next adjacent module (26). Hydraulic rams (30) are provided for inserting and removing the canisters (12) from the modules (26).

  8. Fission gas retention in irradiated metallic fuel

    SciTech Connect (OSTI)

    Fenske, G.R.; Gruber, E.E.; Kramer, J.M.

    1987-01-01

    Theoretical calculations and experimental measurements of the quantity of retained fission gas in irradiated metallic fuel (U-5Fs) are presented. The calculations utilize the Booth method to model the steady-state release of gases from fuel grains and a simplified grain-boundary gas model to predict the gas release from intergranular regions. The quantity of gas retained in as-irradiated fuel was determined by collecting the gases released from short segments of EBR-II driver fuel that were melted in a gas-tight furnace. Comparison of the calculations to the measurements shows quantitative agreement with both the magnitude and the axial variation of the retained gas content.

  9. Separation of sodium-22 from irradiated targets

    DOE Patents [OSTI]

    Taylor, Wayne A. (Los Alamos, NM); Jamriska, David (Los Alamos, NM)

    1996-01-01

    A process for selective separation of sodium-22 from an irradiated target including dissolving an irradiated target to form a first solution, contacting the first solution with hydrated antimony pentoxide to selectively separate sodium-22 from the first solution, separating the hydrated antimony pentoxide including the separated sodium-22 from the first solution, dissolving the hydrated antimony pentoxide including the separated sodium-22 in a mineral acid to form a second solution, and, separating the antimony from the sodium-22 in the second solution.

  10. ARM - Measurement - Shortwave broadband direct normal irradiance

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    direct normal irradiance ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Shortwave broadband direct normal irradiance The rate at which radiant energy in broad bands of wavelengths shorter than approximately 4{mu}m, that comes directly from the Sun without being scattered or absorbed in the atmosphere, passes through a unit area perpendicular to the direction from the Sun. Categories Radiometric

  11. ARM - Measurement - Shortwave broadband total upwelling irradiance

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    upwelling irradiance ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Shortwave broadband total upwelling irradiance The rate at which radiant energy, at a wavelength between 0.4 and 4 {mu}m, is being emitted upwards into a radiation field and transferred across a surface area (real or imaginary) in a hemisphere of directions. Categories Radiometric Instruments The above measurement is considered

  12. ARM - Measurement - Shortwave narrowband direct normal irradiance

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    normal irradiance ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Shortwave narrowband direct normal irradiance The rate at which radiant energy in narrow bands of wavelengths shorter than approximately 4{mu}m, that comes directly from the Sun without being scattered or absorbed in the atmosphere, passes through a unit area perpendicular to the direction from the Sun. Categories Radiometric Instruments

  13. ARM - Measurement - Shortwave spectral total downwelling irradiance

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    total downwelling irradiance ARM Data Discovery Browse Data Comments? We would love to hear from you! Send us a note below or call us at 1-888-ARM-DATA. Send Measurement : Shortwave spectral total downwelling irradiance The rate at which radiant energy, at specrally-resolved wavelengths between 0.4 and 4 {mu}m, is being emitted upwards and downwards into a radiation field and transferred across a surface area (real or imaginary) in a hemisphere of directions. Categories Radiometric Instruments

  14. Understanding the Irradiation Behavior of Zirconium Carbide

    SciTech Connect (OSTI)

    Motta, Arthur; Sridharan, Kumar; Morgan, Dane; Szlufarska, Izabela

    2013-10-11

    Zirconium carbide (ZrC) is being considered for utilization in high-temperature gas-cooled reactor fuels in deep-burn TRISO fuel. Zirconium carbide possesses a cubic B1-type crystal structure with a high melting point, exceptional hardness, and good thermal and electrical conductivities. The use of ZrC as part of the TRISO fuel requires a thorough understanding of its irradiation response. However, the radiation effects on ZrC are still poorly understood. The majority of the existing research is focused on the radiation damage phenomena at higher temperatures (>450{degree}C) where many fundamental aspects of defect production and kinetics cannot be easily distinguished. Little is known about basic defect formation, clustering, and evolution of ZrC under irradiation, although some atomistic simulation and phenomenological studies have been performed. Such detailed information is needed to construct a model describing the microstructural evolution in fast-neutron irradiated materials that will be of great technological importance for the development of ZrC- based fuel. The goal of the proposed project is to gain fundamental understanding of the radiation-induced defect formation in zirconium carbide and irradiation response (ZrC) by using a combination of state-of-the-art experimental methods and atomistic modeling. This project will combine (1) in situ ion irradiation at a specialized facility at a national laboratory, (2) controlled temperature proton irradiation on bulk samples, and (3) atomistic modeling to gain a fundamental understanding of defect formation in ZrC. The proposed project will cover the irradiation temperatures from cryogenic temperature to as high as 800{degree}C, and dose ranges from 0.1 to 100 dpa. The examination of this wide range of temperatures and doses allows us to obtain an experimental data set that can be effectively used to exercise and benchmark the computer calculations of defect properties. Combining the examination of radiation-induced microstructures mapped spatially and temporally, microstructural evolution during post-irradiation annealing, and atomistic modeling of defect formation and transport energetics will provide new, critical understanding about property changes in ZrC. The behavior of materials under irradiation is determined by the balance between damage production, defect clustering, and lattice response. In order to predict those effects at high temperatures so targeted testing can be expanded and extrapolated beyond the known database, it is necessary to determine the defect energetics and mobilities as these control damage accumulation and annealing. In particular, low-temperature irradiations are invaluable for determining the regions of defect mobility. Computer simulation techniques are particularly useful for identifying basic defect properties, especially if closely coupled with a well-constructed and complete experimental database. The close coupling of calculation and experiment in this project will provide mutual benchmarking and allow us to glean a deeper understanding of the irradiation response of ZrC, which can then be applied to the prediction of its behavior in reactor conditions.

  15. Strain engineering in graphene by laser irradiation

    SciTech Connect (OSTI)

    Papasimakis, N.; Mailis, S.; Huang, C. C.; Al-Saab, F.; Hewak, D. W.; Luo, Z.; Shen, Z. X.

    2015-02-09

    We demonstrate that the Raman spectrum of graphene on lithium niobate can be controlled locally by continuous exposure to laser irradiation. We interpret our results in terms of changes to doping and mechanical strain and show that our observations are consistent with light-induced gradual strain relaxation in the graphene layer.

  16. Continuous wave laser irradiation of explosives

    SciTech Connect (OSTI)

    McGrane, Shawn D.; Moore, David S.

    2010-12-01

    Quantitative measurements of the levels of continuous wave (CW) laser light that can be safely applied to bare explosives during contact operations were obtained at 532 nm, 785 nm, and 1550 nm wavelengths. A thermal camera was used to record the temperature of explosive pressed pellets and single crystals while they were irradiated using a measured laser power and laser spot size. A visible light image of the sample surface was obtained before and after the laser irradiation. Laser irradiation thresholds were obtained for the onset of any visible change to the explosive sample and for the onset of any visible chemical reaction. Deflagration to detonation transitions were not observed using any of these CW laser wavelengths on single crystals or pressed pellets in the unconfined geometry tested. Except for the photochemistry of DAAF, TATB and PBX 9502, all reactions appeared to be thermal using a 532 nm wavelength laser. For a 1550 nm wavelength laser, no photochemistry was evident, but the laser power thresholds for thermal damage in some of the materials were significantly lower than for the 532 nm laser wavelength. No reactions were observed in any of the studied explosives using the available 300 mW laser at 785 nm wavelength. Tables of laser irradiance damage and reaction thresholds are presented for pressed pellets of PBX9501, PBX9502, Composition B, HMX, TATB, RDX, DAAF, PETN, and TNT and single crystals of RDX, HMX, and PETN for each of the laser wavelengths.

  17. Irradiation Embritlement in Alloy HT-9

    SciTech Connect (OSTI)

    Serrano De Caro, Magdalena

    2012-08-27

    HT-9 steel is a candidate structural and cladding material for high temperature lead-bismuth cooled fast reactors. In typical advanced fast reactor designs fuel elements will be irradiated for an extended period of time, reaching up to 5-7 years. Significant displacement damage accumulation in the steel is expected (> 200 dpa) when exposed to dpa-rates of 20-30 dpa{sub Fe}/y and high fast flux (E > 0.1 MeV) {approx}4 x 10{sup 15} n/cm{sup 2}s. Core temperatures could reach 400-560 C, with coolant temperatures at the inlet as low as 250 C, depending on the reactor design. Mechanical behavior in the presence of an intense fast flux and high dose is a concern. In particular, low temperature operation could be limited by irradiation embrittlement. Creep and corrosion effects in liquid metal coolants could set a limit to the upper operating temperature. In this report, we focus on the low temperature operating window limit and describe HT-9 embrittlement experimental findings reported in the literature that could provide supporting information to facilitate the consideration of a Code Case on irradiation effects for this class of steels in fast reactor environments. HT-9 has an extensive database available on irradiation performance, which makes it the best choice as a possible near-term candidate for clad, and ducts in future fast reactors. Still, as it is shown in this report, embrittlement data for very low irradiation temperatures (< 200 C) and very high radiation exposure (> 150 dpa) is scarce. Experimental findings indicate a saturation of DBTT shifts as a function of dose, which could allow for long lifetime cladding operation. However, a strong increase in DBTT shift with decreasing irradiation temperature could compromise operation at low service temperatures. Development of a deep understanding of the physics involved in the radiation damage mechanisms, together with multiscale computer simulation models of irradiation embrittlement will provide the basis to derive trendlines and quantitative engineering predictions.

  18. Measurement of thermal conductivity in proton irradiated silicon (Journal

    Office of Scientific and Technical Information (OSTI)

    Article) | SciTech Connect Measurement of thermal conductivity in proton irradiated silicon Citation Details In-Document Search Title: Measurement of thermal conductivity in proton irradiated silicon We investigate the influence of proton irradiation on thermal conductivity in single crystal silicon. We apply laser based modulated thermoreflectance technique to extract the change in conductivity of the thin layer damaged by proton irradiation. Unlike time domain thermoreflectance techniques

  19. Low Dose Irradiation Facility | Savannah River Ecology Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Low Dose Irradiation Facility (LoDIF) The LoDIF is a unique facility designed to evaluate the impact of chronic, low-level radiation exposure on aquatic organisms. The facility is an array of 40 outdoor mesocosms equipped with cesium-137 irradiation sources or unexposed controls. Irradiation sources provide three biologically relevant levels of exposure: 2, 20, and 200 mGy/d mean exposure. Mesocosms are arranged into eight blocks, with five mesocosms per block (three levels of irradiation and

  20. Sensitivity of ultrasonic nonlinearity to irradiated, annealed, and re-irradiated microstructure changes in RPV steels

    SciTech Connect (OSTI)

    Matlack, Katie; Kim, J-Y.; Wall, J.J.; Jacobs, L.J.; Sokolov, Mikhail A

    2014-05-01

    The planned life extension of nuclear reactors throughout the US and abroad will cause reactor vessel and internals materials to be exposed to more neutron irradiation than was originally intended. A nondestructive evaluation (NDE) method to monitor radiation damage would enable safe and cost-effective continued operation of nuclear reactors. Radiation damage in reactor pressure vessel (RPV) steels causes microstructural changes that leave the material in an embrittled state. Nonlinear ultrasound is an NDE technique quantified by the measurable acoustic nonlinearity parameter, which is sensitive to microstructural changes in metallic materials such as dislocations, precipitates and their combinations. Recent research has demonstrated the sensitivity of the acoustic nonlinearity parameter to increasing neutron fluence in representative RPV steels. The current work considers nonlinear ultrasonic experiments conducted on similar RPV steel samples that had a combination of irradiation, annealing, re-irradiation, and/or re-annealing to a total neutron fluence of 0.5 5 1019 n/cm2 (E > 1 MeV) at an irradiation temperature of 290 C. The acoustic nonlinearity parameter generally increased with increasing neutron fluence, and consistently decreased from the irradiated to the annealed state over different levels of neutron fluence. Results of the measured acoustic nonlinearity parameter are compared with those from previous measurements on other RPV steel samples. This comprehensive set of results illustrates the dependence of the measured acoustic nonlinearity parameter on neutron fluence, material composition, irradiation temperature and annealing.

  1. Advanced Numerical Model for Irradiated Concrete

    SciTech Connect (OSTI)

    Giorla, Alain B.

    2015-03-01

    In this report, we establish a numerical model for concrete exposed to irradiation to address these three critical points. The model accounts for creep in the cement paste and its coupling with damage, temperature and relative humidity. The shift in failure mode with the loading rate is also properly represented. The numerical model for creep has been validated and calibrated against different experiments in the literature [Wittmann, 1970, Le Roy, 1995]. Results from a simplified model are shown to showcase the ability of numerical homogenization to simulate irradiation effects in concrete. In future works, the complete model will be applied to the analysis of the irradiation experiments of Elleuch et al. [1972] and Kelly et al. [1969]. This requires a careful examination of the experimental environmental conditions as in both cases certain critical information are missing, including the relative humidity history. A sensitivity analysis will be conducted to provide lower and upper bounds of the concrete expansion under irradiation, and check if the scatter in the simulated results matches the one found in experiments. The numerical and experimental results will be compared in terms of expansion and loss of mechanical stiffness and strength. Both effects should be captured accordingly by the model to validate it. Once the model has been validated on these two experiments, it can be applied to simulate concrete from nuclear power plants. To do so, the materials used in these concrete must be as well characterized as possible. The main parameters required are the mechanical properties of each constituent in the concrete (aggregates, cement paste), namely the elastic modulus, the creep properties, the tensile and compressive strength, the thermal expansion coefficient, and the drying shrinkage. These can be either measured experimentally, estimated from the initial composition in the case of cement paste, or back-calculated from mechanical tests on concrete. If some are unknown, a sensitivity analysis must be carried out to provide lower and upper bounds of the material behaviour. Finally, the model can be used as a basis to formulate a macroscopic material model for concrete subject to irradiation, which later can be used in structural analyses to estimate the structural impact of irradiation on nuclear power plants.

  2. Forward and reverse characteristics of irradiated MOSFETs

    SciTech Connect (OSTI)

    Paccagnella, A.; Ceschia, M.; Verzellesi, G.; Dalla Betta, G.F.; Soncini, G.; Bellutti, P.; Fuochi, P.G.

    1996-06-01

    pMOSFETs biased with V{sub gs} < V{sub gd} during Co{sup 60} {gamma} irradiation have shown substantial differences between the forward and reverse subthreshold characteristics, induced by a non-uniform charge distribution in the gate oxide. Correspondingly, modest differences have been observed in the over-threshold I-V characteristics. After irradiation, the forward subthreshold curves can shift at higher or lower gate voltages than the reverse ones. The former behavior has been observed in long-channel devices, in agreement with the classical MOS theory and numerical simulations. The latter result has been obtained in short-channel devices, and it has been correlated to a parasitic punch-through conduction mechanism.

  3. Fractionated total body irradiation for metastatic neuroblastoma

    SciTech Connect (OSTI)

    Kun, L.E.; Casper, J.T.; Kline, R.W.; Piaskowski, V.D.

    1981-11-01

    Twelve patients over one year old with neuroblastoma (NBL) metastatic to bone and bone marrow entered a study of adjuvant low-dose, fractionated total body irradiation (TBI). Six children who achieved a ''complete clinical response'' following chemotherapy (cyclophosphamide and adriamycin) and surgical resection of the abdominal primary received TBI (10 rad/fraction to totals of 100-120 rad/10-12 fx/12-25 days). Two children received concurrent local irradiation for residual abdominal tumor. The intervals from cessation of chemotherapy to documented progression ranged from 2-16 months, not substatially different from patients receiving similar chemotherapy and surgery without TBI. Three additional children with progressive NBL received similar TBI (80-120 rad/8-12 fx) without objective response.

  4. Nanodot formation induced by femtosecond laser irradiation

    SciTech Connect (OSTI)

    Abere, M. J.; Kang, M.; Goldman, R. S.; Yalisove, S. M. [Department of Materials Science and Engineering, University of Michigan, Ann Arbor, Michigan 48109 (United States); Chen, C. [Applied Physics Program, University of Michigan, Ann Arbor, Michigan 48109 (United States); Rittman, D. R. [Department of Nuclear Engineering and Radiological Sciences, University of Michigan, Ann Arbor, Michigan 48109 (United States); Phillips, J. D. [Department of Electrical Engineering and Computer Science, University of Michigan, Ann Arbor, Michigan 48109 (United States); Torralva, B. [Department of Atmospheric, Oceanic, and Space Sciences, University of Michigan, Ann Arbor, Michigan 48109 (United States)

    2014-10-20

    The femtosecond laser generation of ZnSe nanoscale features on ZnSe surfaces was studied. Irradiation with multiple exposures produces 10100?nm agglomerations of nanocrystalline ZnSe while retaining the original single crystal structure of the underlying material. The structure of these nanodots was verified using a combination of scanning transmission electron microscopy, scanning electron microscopy, and atomic force microscopy. The nanodots continue to grow hours after irradiation through a combination of bulk and surface diffusion. We suggest that in nanodot formation the result of ultrafast laser induced point defect formation is more than an order of magnitude below the ZnSe ultrafast melt threshold fluence. This unique mechanism of point defect injection will be discussed.

  5. Comparison of Diffuse Shortwave Irradiance Measurements

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Diffuse Shortwave Irradiance Measurements J. J. Michalsky and J. Schlemmer Atmospheric Sciences Research Center State University of New York Albany, New York B. C. Bush, S. Leitner, D. Marsden, and F. P. J. Valero Scripps Institution of Oceanography University of California, San Diego La Jolla, California R. Dolce and A. Los Kipp & Zonen, Inc. Bohemia, New York and Delft The Netherlands E. G. Dutton Climate Monitoring and Diagnostics Laboratory National Oceanic and Atmospheric Administration

  6. Irradiation Environment of the Materials Test Station

    SciTech Connect (OSTI)

    Pitcher, Eric John

    2012-06-21

    Conceptual design of the proposed Materials Test Station (MTS) at the Los Alamos Neutron Science Center (LANSCE) is now complete. The principal mission is the irradiation testing of advanced fuels and materials for fast-spectrum nuclear reactor applications. The neutron spectrum in the fuel irradiation region of MTS is sufficiently close to that of fast reactor that MTS can match the fast reactor fuel centerline temperature and temperature profile across a fuel pellet. This is an important characteristic since temperature and temperature gradients drive many phenomena related to fuel performance, such as phase stability, stoichiometry, and fission product transport. The MTS irradiation environment is also suitable in many respects for fusion materials testing. In particular, the rate of helium production relative to atomic displacements at the peak flux position in MTS matches well that of fusion reactor first wall. Nuclear transmutation of the elemental composition of the fusion alloy EUROFER97 in MTS is similar to that expected in the first wall of a fusion reactor.

  7. The spectral irradiance traceability chain at PTB

    SciTech Connect (OSTI)

    Sperfeld, P.; Pape, S.; Nevas, S.

    2013-05-10

    Spectral irradiance is a fundamental radiometric unit. Its application to measurement results requires qualified traceability to basic units of the international system of units (Systeme international d'unites, SI). The Physikalisch-Technische Bundesanstalt (PTB) is amongst other national metrological institutes (NMIs) responsible for the realization, maintenance and dissemination of various radiometric and photometric units based on and traceable to national standards. The unit of spectral irradiance is realized and represented by a blackbody-radiator as the national primary standard of the PTB. Based on Planck's radiation law, the irradiance is calculated and realized for any wavelength taking into account the exact knowledge of the radiation temperature and the geometrical parameters. Using a double-monochromator-based spectroradiometer system, secondary standard lamps can be calibrated by direct comparison to the blackbody-radiator (substitution method). These secondary standard lamps are then used at the PTB to calibrate standard lamps of customers. The customers themselves use these so-called transfer standards to calibrate their working standard lamps. These working standards are then used to calibrate own spectroradiometers or sources. This rather complex calibration chain is a common procedural method that for the customers generally leads to satisfying measurement results on site. Nevertheless, the standard lamps in use have to fulfill highest requirements concerning stability and reproducibility. Only this allows achieving comparably low transfer measurement uncertainties, which occur at each calibration step. Thus, the PTB is constantly investigating the improvement and further development of transfer standards and measurement methods for various spectral regions. The realization and dissemination of the spectral irradiance using the blackbody-radiator at the PTB is accomplished with worldwide approved minimized measurement uncertainties confirmed by international intercomparisons among NMIs. Ultimately, the spectral irradiance can be realized with expanded measurement uncertainties of far less than 1 % over a wide spectral range. Thus, for customers with high demands on low measurement uncertainties, it is possible to calibrate their working standards directly against the blackbody-radiator, taking into account the higher necessary effort. In special cases it is possible to calibrate the customer's spectroradiometric facilities directly in front of the blackbody-radiator. In the context of the European Metrology Research Project Traceability for surface spectral solar ultraviolet radiation, the traceability chain will be improved and adapted.

  8. Evaluation of Neutron Irradiated Silicon Carbide and Silicon Carbide Composites

    SciTech Connect (OSTI)

    Newsome G, Snead L, Hinoki T, Katoh Y, Peters D

    2007-03-26

    The effects of fast neutron irradiation on SiC and SiC composites have been studied. The materials used were chemical vapor deposition (CVD) SiC and SiC/SiC composites reinforced with either Hi-Nicalon{trademark} Type-S, Hi-Nicalon{trademark} or Sylramic{trademark} fibers fabricated by chemical vapor infiltration. Statistically significant numbers of flexural samples were irradiated up to 4.6 x 10{sup 25} n/m{sup 2} (E>0.1 MeV) at 300, 500 and 800 C in the High Flux Isotope Reactor at Oak Ridge National Laboratory. Dimensions and weights of the flexural bars were measured before and after the neutron irradiation. Mechanical properties were evaluated by four point flexural testing. Volume increase was seen for all bend bars following neutron irradiation. Magnitude of swelling depended on irradiation temperature and material, while it was nearly independent of irradiation fluence over the fluence range studied. Flexural strength of CVD SiC increased following irradiation depending on irradiation temperature. Over the temperature range studied, no significant degradation in mechanical properties was seen for composites fabricated with Hi-Nicalon{trademark} Type-S, while composites reinforced with Hi-Nicalon{trademark} or Sylramic fibers showed significant degradation. The effects of irradiation on the Weibull failure statistics are also presented suggesting a reduction in the Weibull modulus upon irradiation. The cause of this potential reduction is not known.

  9. Graphitization of polymer surfaces by scanning ion irradiation

    SciTech Connect (OSTI)

    Koval, Yuri [Department of Physics, Universitt Erlangen-Nrnberg, Erwin-Rommel-Str. 1, 91058 Erlangen (Germany)

    2014-10-20

    Graphitization of polymer surfaces was performed by low-energy Ar{sup +} and He{sup +} ion irradiation. A method of scanning irradiation was implemented. It was found that by scanning ion irradiation, a significantly higher electrical conductivity in the graphitized layers can be achieved in comparison with a conventional broad-beam irradiation. The enhancement of the conductance becomes more pronounced for narrower and better collimated ion beams. In order to analyze these results in more detail, the temperature dependence of conductance of the irradiated samples was investigated. The results of measurements are discussed in terms of weak localization corrections to conductance in disordered metals. The observed effects can be explained by enlargement of graphitic patches, which was achieved with the scanning ion irradiation method.

  10. Methods for Post Irradiation Examination of Tritium Producing Burnable

    Office of Environmental Management (EM)

    Absorber Rods | Department of Energy for Post Irradiation Examination of Tritium Producing Burnable Absorber Rods Methods for Post Irradiation Examination of Tritium Producing Burnable Absorber Rods Presentation from the 32nd Tritium Focus Group Meeting held in Germantown, Maryland on April 23-25, 2013. PDF icon Methods for Post Irradiation Examination of Tritium Producing Burnable Absorber Rods More Documents & Publications Design and Fabrication of In-Reactor Experiment to Measure

  11. Lanai high-density irradiance sensor network for characterizing solar

    Office of Scientific and Technical Information (OSTI)

    resource variability of MW-scale PV system. (Conference) | SciTech Connect Conference: Lanai high-density irradiance sensor network for characterizing solar resource variability of MW-scale PV system. Citation Details In-Document Search Title: Lanai high-density irradiance sensor network for characterizing solar resource variability of MW-scale PV system. Sandia National Laboratories (Sandia) and SunPower Corporation (SunPower) have completed design and deployment of an autonomous irradiance

  12. Irradiation Effects on Human Cortical Bone Fracture Behavior

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Irradiation Effects on Human Cortical Bone Fracture Behavior Irradiation Effects on Human Cortical Bone Fracture Behavior Print Wednesday, 28 July 2010 00:00 Human bone is strong but still fallible. To better predict fracturing in bone, researchers need a mechanistic framework to understand the changes taking place on different size scales within bone, as well as the role of sustained irradiation damage. Combining in situ mechanical testing with synchrotron x-ray diffraction imaging and/or

  13. Center for Materials at Irradiation and Mechanical Extremes: Los Alamos

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    National Laboratory EFRC Research Teams Irradiation Extremes and Mechanical Extremes are the two thrusts of CMIME. Currently, each thrust has two research teams. The Irradiation Extremes Thrust teams focus on metals and oxides. The Mechanical Extremes Thrust teams focus on severe plastic deformation (SPD) and deformation at high strain rates. CMIME org chart (pdf) IRRADIATION EXTREMES THRUST Amit Misra Amit Misra, LANL Fellow CMIME Director, Thrust Leader MECHANICAL EXTREMES THRUST beyerlein

  14. Enterprise Assessments, Oak Ridge National Laboratory Irradiated Fuels

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Examination Laboratory - April 2015 | Department of Energy Assessments, Oak Ridge National Laboratory Irradiated Fuels Examination Laboratory - April 2015 Enterprise Assessments, Oak Ridge National Laboratory Irradiated Fuels Examination Laboratory - April 2015 April 2015 Review of the Safety-Significant Ventilation Systems at the Irradiated Fuels Examination Laboratory Operated by UT-Battelle for the Oak Ridge National Laboratory Office of Science The Office of Nuclear Safety and

  15. Irradiation-induced effects of proton irradiation on zirconium carbides with different stoichiometries

    SciTech Connect (OSTI)

    Y. Huang; B.R. Maier; T.R. Allen

    2014-10-01

    Zirconium carbide (ZrC) is being considered for utilization in deep burn TRISO fuel particles for hightemperature, gas-cooled reactors. Zirconium carbide has a cubic B1 type crystal structure along with a very high melting point (3420 ?C), exceptional hardness and good thermal and electrical conductivities. Understanding the ZrC irradiation response is crucial for establishing ZrC as an alternative component in TRISO fuel. Until now, very few studies on irradiation effects on ZrC have been released and fundamental aspects of defect evolution and kinetics are not well understood although some atomistic simulations and phenomenological studies have been performed. This work was carried out to understand the damage evolution in float-zone refined ZrC with different stoichiometries. Proton irradiations at 800 ?C up to doses of 3 dpa were performed on ZrCx (where x ranges from 0.9 to 1.2) to investigate the damage evolution. The irradiation-induced defects, such as density of dislocation loops, at different stoichiometries and doses which were characterized by transmission electron microscopy (TEM) is presented and discussed.

  16. An Instrument Design Concept for Measuring Solar Diffuse Irradiance

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    An Instrument Design Concept for Measuring Solar Diffuse Irradiance Rutledge, Charles NASA Langley Research Center Schuster, Greg NASA Langley Research Center Category: Instruments...

  17. Emulation of reactor irradiation damage using ion beams

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Was, G. S.; Jiao, Z.; Getto, E.; Sun, K.; Monterrosa, A. M.; Maloy, S. A.; Anderoglu, O.; Sencer, B. H.; Hackett, M.

    2014-06-14

    The continued operation of existing light water nuclear reactors and the development of advanced nuclear reactor depend heavily on understanding how damage by radiation to levels degrades materials that serve as the structural components in reactor cores. The first high dose ion irradiation experiments on a ferritic-martensitic steel showing that ion irradiation closely emulates the full radiation damage microstructure created in-reactor are described. Ferritic-martensitic alloy HT9 (heat 84425) in the form of a hexagonal fuel bundle duct (ACO-3) accumulated 155 dpa at an average temperature of 443°C in the Fast Flux Test Facility (FFTF). Using invariance theory as a guide,more » irradiation of the same heat was conducted using self-ions (Fe++) at 5 MeV at a temperature of 460°C and to a dose of 188 displacements per atom. The void swelling was nearly identical between the two irradiation and the size and density of precipitates and loops following ion irradiation are within a factor of two of those for neutron irradiation. The level of agreement across all of the principal microstructure changes between ion and reactor irradiation establishes the capability of tailoring ion irradiation to emulate the reactor-irradiated microstructure.« less

  18. Emulation of reactor irradiation damage using ion beams

    SciTech Connect (OSTI)

    Was, G. S.; Jiao, Z.; Getto, E.; Sun, K.; Monterrosa, A. M.; Maloy, S. A.; Anderoglu, O.; Sencer, B. H.; Hackett, M.

    2014-06-14

    The continued operation of existing light water nuclear reactors and the development of advanced nuclear reactor depend heavily on understanding how damage by radiation to levels degrades materials that serve as the structural components in reactor cores. The first high dose ion irradiation experiments on a ferritic-martensitic steel showing that ion irradiation closely emulates the full radiation damage microstructure created in-reactor are described. Ferritic-martensitic alloy HT9 (heat 84425) in the form of a hexagonal fuel bundle duct (ACO-3) accumulated 155 dpa at an average temperature of 443C in the Fast Flux Test Facility (FFTF). Using invariance theory as a guide, irradiation of the same heat was conducted using self-ions (Fe++) at 5 MeV at a temperature of 460C and to a dose of 188 displacements per atom. The void swelling was nearly identical between the two irradiation and the size and density of precipitates and loops following ion irradiation are within a factor of two of those for neutron irradiation. The level of agreement across all of the principal microstructure changes between ion and reactor irradiation establishes the capability of tailoring ion irradiation to emulate the reactor-irradiated microstructure.

  19. Irradiation Effects on Human Cortical Bone Fracture Behavior

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Irradiation Effects on Human Cortical Bone Fracture Behavior Print Human bone is strong but still fallible. To better predict fracturing in bone, researchers need a mechanistic...

  20. Molecular Weight Distributions of Irradiated Siloxane-Based Elastomers...

    Office of Scientific and Technical Information (OSTI)

    Molecular Weight Distributions of Irradiated Siloxane-Based Elastomers: A Complementary Study by Statistical Modeling and Multiple Quantum Nuclear Magnetic Resonance. Citation...

  1. Irradiation Effects on Human Cortical Bone Fracture Behavior

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of sustained irradiation damage. Combining in situ mechanical testing with synchrotron x-ray diffraction imaging andor tomography, is a popular method of investigating...

  2. Emulation of reactor irradiation damage using ion beams

    SciTech Connect (OSTI)

    G. S. Was; Z. Jiao; E. Beckett; A. M. Monterrosa; O. Anderoglu; B. H. Sencer; M. Hackett

    2014-10-01

    The continued operation of existing light water nuclear reactors and the development of advanced nuclear reactor depend heavily on understanding how damage by radiation to levels degrades materials that serve as the structural components in reactor cores. The first high dose ion irradiation experiments on a ferritic-martensitic steel showing that ion irradiation closely emulates the full radiation damage microstructure created in-reactor are described. Ferritic-martensitic alloy HT9 (heat 84425) in the form of a hexagonal fuel bundle duct (ACO-3) accumulated 155 dpa at an average temperature of 443C in the Fast Flux Test Facility (FFTF). Using invariance theory as a guide, irradiation of the same heat was conducted using self-ions (Fe++) at 5 MeV at a temperature of 460C and to a dose of 188 displacements per atom. The void swelling was nearly identical between the two irradiations and the size and density of precipitates and loops following ion irradiation are within a factor of two of those for neutron irradiation. The level of agreement across all of the principal microstructure changes between ion and reactor irradiations establishes the capability of tailoring ion irradiations to emulate the reactor-irradiated microstructure.

  3. PRODUCING SATELLITE-DERIVED IRRADIANCES IN COMPLEX ARID TERRAIN

    Open Energy Info (EERE)

    the corrected monthly maps (see Fig. 3). 4. DISCUSSION We have presented a robust, straightforward two-step approach to correct irradiance estimated from weather satellites'...

  4. FY 2013 Summary Report: Post-Irradiation Examination of Zircaloy...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Summary Report: Post-Irradiation Examination of Zircaloy-4 Samples in Target Capsules and Initiation of Bending Fatigue Testing for Used Nuclear Fuel Vibration Integrity ...

  5. Irradiation Programs and Test Plans to Assess High-Fluence Irradiation Assisted Stress Corrosion Cracking Susceptibility.

    SciTech Connect (OSTI)

    Teysseyre, Sebastien

    2015-03-01

    . Irradiation assisted stress corrosion cracking (IASCC) is a known issue in current reactors. In a 60 year lifetime, reactor core internals may experience fluence levels up to 15 dpa for boiling water reactors (BWR) and 100+ dpa for pressurized water reactors (PWR). To support a safe operation of our fleet of reactors and maintain their economic viability it is important to be able to predict any evolution of material behaviors as reactors age and therefore fluence accumulated by reactor core component increases. For PWR reactors, the difficulty to predict high fluence behavior comes from the fact that there is not a consensus of the mechanism of IASCC and that little data is available. It is however possible to use the current state of knowledge on the evolution of irradiated microstructure and on the processes that influences IASCC to emit hypotheses. This report identifies several potential changes in microstructure and proposes to identify their potential impact of IASCC. The susceptibility of a component to high fluence IASCC is considered to not only depends on the intrinsic IASCC susceptibility of the component due to radiation effects on the material but to also be related to the evolution of the loading history of the material and interaction with the environment as total fluence increases. Single variation type experiments are proposed to be performed with materials that are representative of PWR condition and with materials irradiated in other conditions. To address the lack of IASCC propagation and initiation data generated with material irradiated in PWR condition, it is proposed to investigate the effect of spectrum and flux rate on the evolution of microstructure. A long term irradiation, aimed to generate a well-controlled irradiation history on a set on selected materials is also proposed for consideration. For BWR, the study of available data permitted to identify an area of concern for long term performance of component. The efficiency of hydrogen water chemistry mitigation technology may decrease as fluence increases for high-stress intensity factors. This report describes a program plan to determine the efficiency of hydrogen water chemistry as a function of the stress intensity factor applied and fluence. The use of existing, available, materials and the generation of additional materials via irradiation in a research reactor are considered.

  6. Optimisation of buildings' solar irradiation availability

    SciTech Connect (OSTI)

    Kaempf, Jerome Henri; Montavon, Marylene; Bunyesc, Josep; Robinson, Darren; Bolliger, Raffaele

    2010-04-15

    In order to improve the sustainability of new and existing urban settlements it is desirable to maximise the utilisation of the solar energy incident on the building envelope, whether by passive or active means. To this end we have coupled a multi-objective optimisation algorithm with the backwards ray tracing program RADIANCE which itself uses a cumulative sky model for the computation of incident irradiation (W h/m{sup 2}) in a single simulation. The parameters to optimise are geometric (the height of buildings up to their facade and the height and orientation of roofs), but with the constraint of maintaining an overall built volume, and the objective function is heating season solar irradiation offset by envelope heat losses. This methodology has been applied to a range of urban typologies and produces readily interpretable results. The focus of this work is on the design of new urban forms but the method could equally be applied to examine the relative efficiency of existing urban settlements, by comparison of existing forms with the calculated optima derived from relevant specifications of the building envelope. (author)

  7. Hafnium radioisotope recovery from irradiated tantalum

    DOE Patents [OSTI]

    Taylor, Wayne A. (Los Alamos, NM); Jamriska, David J. (Los Alamos, NM)

    2001-01-01

    Hafnium is recovered from irradiated tantalum by: (a) contacting the irradiated tantalum with at least one acid to obtain a solution of dissolved tantalum; (b) combining an aqueous solution of a calcium compound with the solution of dissolved tantalum to obtain a third combined solution; (c) precipitating hafnium, lanthanide, and insoluble calcium complexes from the third combined solution to obtain a first precipitate; (d) contacting the first precipitate of hafnium, lanthanide and calcium complexes with at least one fluoride ion complexing agent to form a fourth solution; (e) selectively adsorbing lanthanides and calcium from the fourth solution by cationic exchange; (f) separating fluoride ion complexing agent product from hafnium in the fourth solution by adding an aqueous solution of ferric chloride to obtain a second precipitate containing the hafnium and iron; (g) dissolving the second precipitate containing the hafnium and iron in acid to obtain an acid solution of hafnium and iron; (h) selectively adsorbing the iron from the acid solution of hafnium and iron by anionic exchange; (i) drying the ion exchanged hafnium solution to obtain hafnium isotopes. Additionally, if needed to remove residue remaining after the product is dried, dissolution in acid followed by cation exchange, then anion exchange, is performed.

  8. LWRS ATR Irradiation Testing Readiness Status

    SciTech Connect (OSTI)

    Kristine Barrett

    2012-09-01

    The Light Water Reactor Sustainability (LWRS) Program was established by the U.S. Department of Energy Office of Nuclear Energy (DOE-NE) to develop technologies and other solutions that can improve the reliability, sustain the safety, and extend the life of the current reactors. The LWRS Program is divided into four R&D Pathways: (1) Materials Aging and Degradation; (2) Advanced Light Water Reactor Nuclear Fuels; (3) Advanced Instrumentation, Information and Control Systems; and (4) Risk-Informed Safety Margin Characterization. This report describes an irradiation testing readiness analysis in preparation of LWRS experiments for irradiation testing at the Idaho National Laboratory (INL) Advanced Test Reactor (ATR) under Pathway (2). The focus of the Advanced LWR Nuclear Fuels Pathway is to improve the scientific knowledge basis for understanding and predicting fundamental performance of advanced nuclear fuel and cladding in nuclear power plants during both nominal and off-nominal conditions. This information will be applied in the design and development of high-performance, high burn-up fuels with improved safety, cladding integrity, and improved nuclear fuel cycle economics

  9. Final Report on MEGAPIE Target Irradiation and Post-Irradiation Examination

    SciTech Connect (OSTI)

    Yong, Dai

    2015-06-30

    Megawatt pilot experiment (MEGAPIE) was successfully performed in 2006. One of the important goals of MEGAPIE is to understand the behaviour of structural materials of the target components exposed to high fluxes of high-energy protons and spallation neutrons in flowing LBE (liquid lead-bismuth eutectic) environment by conducting post-irradiation examination (PIE). The PIE includes four major parts: non-destructive test, radiochemical analysis of production and distribution of radionuclides produced by spallation reaction in LBE, analysis of LBE corrosion effects on structural materials, T91 and SS 316L steels, and mechanical testing of the T91 and SS 316L steels irradiated in the lower part of the target. The non-destructive test (NDT) including visual inspection and ultrasonic measurement was performed in the proton beam window area of the T91 calotte of the LBE container, the most intensively irradiated part of the MEGAPIE target. The visual inspection showed no visible failure and the ultrasonic measurement demonstrated no detectable change in thickness in the beam window area. Gamma mapping was also performed in the proton beam window area of the AlMg3 safety-container. The gamma mapping results were used to evaluate the accumulated proton fluence distribution profile, the input data for determining irradiation parameters. Radiochemical analysis of radionuclides produced by spallation reaction in LBE is to improve the understanding of the production and distribution of radionuclides in the target. The results demonstrate that the radionuclides of noble metals, 207Bi, 194Hg/Au are rather homogeneously distributed within the target, while radionuclides of electropositive elements are found to be deposited on the steel-LBE interface. The corrosion effect of LBE on the structural components under intensive irradiation was investigated by metallography. The results show that no evident corrosion damages. However, unexpected deep cracks were found in the EBW (electron beam weld) of the LBE container in the intensive irradiation zone of the target, which should be formed during irradiation. In the SS 316L steel of the flow guide tube, inclusions or precipitates enriched with O, Si, S, Ca, Ti and Mn were observed. Many of them are very long, up to a few mm, and located on grain boundaries along the extrusion direction of the tube. The degradation of the mechanical properties of the T91 and SS 316L steels has been investigated by conducting tensile tests on the specimens extracted from the T91 and SS 316L components in the intensive irradiation region. The results obtained from the proton beam window of the T91 calotte exhibit a good ductility of T91 steel after irradiation at 6-7 dpa (displacement per atom) in contact with flowing LBE.

  10. Fowler-Nordheim characteristics of electron irradiated MOS capacitors

    SciTech Connect (OSTI)

    Candelori, A.; Paccagnella, A.; Cammarata, M.; Ghidini, G.; Fuochi, P.G.

    1998-12-01

    MOS capacitors with 8 nm thick oxides have been irradiated by an 8 MeV LINAC electron beam. C-V and I-V measurements have shown a positive trapped charge, higher for irradiation performed under negative gate bias, as a consequence of preferential charge recombination at the cathodic interface. No saturation of the positive trapped charge is measured up to 20 Mrad(Si). Neutral defects induced by irradiation have been studied, by performing positive and negative Fowler-Nordheim injection. The distribution of neutral defects is similar to that of trapped holes, indicating a correlation between trapped holes and neutral defects. Electrical stresses performed after irradiation have shown that the accumulation kinetics of oxide defects is similar in both unirradiated and irradiated devices.

  11. Identifying irradiated flours by photo-stimulated luminescence technique

    SciTech Connect (OSTI)

    Ramli, Ros Anita Ahmad; Yasir, Muhamad Samudi; Othman, Zainon; Abdullah, Wan Saffiey Wan

    2014-02-12

    Photo-stimulated luminescence (PSL) technique was used in this study to detect gamma irradiation treatment of five types of flours (corn, rice, tapioca, wheat and glutinous rice) at four different doses 0, 0.2, .05 and 1kGy. The signal level was compared with two threshold values (700 and 5000). With the exception of glutinous rice, all irradiated samples produced a strong signal above the upper threshold (5000 counts/60s). All control samples produced negative result with the signals below the lower threshold (700 counts/60s) suggesting that the samples have not been irradiated. Irradiated glutinous rice samples produced intermediate signals (700 - 5000 counts/60s) which were subsequently confirmed using calibrated PSL. The PSL signals remained stable after 90 days of storage. The findings of this study will be useful to facilitate control of food irradiation application in Malaysia.

  12. Surface modification of multilayer graphene using Ga ion irradiation

    SciTech Connect (OSTI)

    Wang, Quan; Shao, Ying; Ge, Daohan; Ren, Naifei; Yang, Qizhi

    2015-04-28

    The effect of Ga ion irradiation intensity on the surface of multilayer graphene was examined. Using Raman spectroscopy, we determined that the irradiation caused defects in the crystal structure of graphene. The density of defects increased with the increase in dwell times. Furthermore, the strain induced by the irradiation changed the crystallite size and the distance between defects. These defects had the effect of doping the multilayer graphene and increasing its work function. The increase in work function was determined using contact potential difference measurements. The surface morphology of the multilayer graphene changed following irradiation as determined by atomic force microscopy. Additionally, the adhesion between the atomic force microscopy tip and sample increased further indicating that the irradiation had caused surface modification, important for devices that incorporate graphene.

  13. Breakdown properties of irradiated MOS capacitors

    SciTech Connect (OSTI)

    Paccagnella, A.; Candelori, A.; Milani, A.; Formigoni, E.; Ghidini, G.; Drera, D.; Pellizzer, F.; Fuochi, P.G.; Lavale, M.

    1996-12-01

    The authors have studied the effects of ionizing and non-ionizing radiation on the breakdown properties of different types of MOS capacitors, with thick (200 nm) and thin (down to 8 nm) oxides. In general, no large variations of the average breakdown field, time-to-breakdown at constant voltage, or charge-to-breakdown at constant voltage, or charge-to-breakdown values have been observed after high dose irradiation (20 Mrad(Si) 9 MeV electrons on thin and thick oxides, 17(Si) Mrad Co{sup 60} gamma and 10{sup 14} neutrons/cm{sup 2} only on thick oxides). However, some modifications of the cumulative failure distributions have been observed in few of the oxides tested.

  14. Instrumentation to Enhance Advanced Test Reactor Irradiations

    SciTech Connect (OSTI)

    J. L. Rempe; D. L. Knudson; K. G. Condie; J. E. Daw; S. C. Taylor

    2009-09-01

    The Department of Energy (DOE) designated the Advanced Test Reactor (ATR) as a National Scientific User Facility (NSUF) in April 2007 to support U.S. leadership in nuclear science and technology. By attracting new research users - universities, laboratories, and industry - the ATR will support basic and applied nuclear research and development, further advancing the nation's energy security needs. A key component of the ATR NSUF effort is to prove new in-pile instrumentation techniques that are capable of providing real-time measurements of key parameters during irradiation. To address this need, an assessment of instrumentation available and under-development at other test reactors has been completed. Based on this review, recommendations are made with respect to what instrumentation is needed at the ATR and a strategy has been developed for obtaining these sensors. Progress toward implementing this strategy is reported in this document. It is anticipated that this report will be updated on an annual basis.

  15. Recovery of niobium from irradiated targets

    DOE Patents [OSTI]

    Phillips, Dennis R.; Jamriska, Sr., David J.; Hamilton, Virginia T.

    1994-01-01

    A process for selective separation of niobium from proton irradiated molybdenum targets is provided and includes dissolving the molybdenum target in a hydrogen peroxide solution to form a first ion-containing solution, contacting the first ion-containing solution with a cationic resin whereby ions selected form the group consisting of molybdenum, biobium, technetium, selenium, vanadium, arsenic, germanium, zirconium and rubidium remain in a second ion-containing solution while ions selected from the group consisting of rubidium, zinc, beryllium, cobalt, iron, manganese, chromium, strontium, yttrium and zirconium are selectively adsorbed by the cationic resin; adjusting the pH of the second ion-containing solution to within a range of from about 5.0 to about 6.0; contacting the pH adjusting second ion-containing solution with a dextran-based material for a time to selectively separate niobium from the solution and recovering the niobium from the dextran-based material.

  16. Irradiation effect on deuterium behaviour in low-dose HFIR neutron-irradiated tungsten

    SciTech Connect (OSTI)

    Shimada, Masashi; Cao, G.; Otsuka, T.; Hara, M.; Kobayashi, M.; Oya, Y.; Hatano, Y.

    2014-12-01

    Tungsten samples were irradiated by neutrons in the High Flux Isotope Reactor, Oak Ridge National Laboratory at reactor coolant temperatures of 50-70C to low displacement damage of 0.025 and 0.3 dpa under the framework of the US-Japan TITAN program (2007-2013). After cooling down, the HFIR neutron-irradiated tungsten samples were exposed to deuterium plasmas in the Tritium Plasma Experiment, Idaho National Laboratory at 100, 200 and 500 C twice at the ion fluence of 510? m? to reach a total ion fluence of 110? m? in order to investigate the near surface deuterium retention and saturation via nuclear reaction analysis. Final thermal desorption spectroscopy was performed to elucidate irradiation effect on total deuterium retention. Nuclear reaction analysis results showed that the maximum near surface (<5 m depth) deuterium concentration increased from 0.5 at % D/W in 0.025 dpa samples to 0.8 at. % D/W in 0.3 dpa samples. The large discrepancy between the total retention via thermal desorption spectroscopy and the near surface retention via nuclear reaction analysis indicated the deuterium was migrated and trapped in bulk (at least 50 m depth for 0.025 dpa and 35 m depth for 0.025 dpa) at 500 C case even in the relatively low ion fluence of 10? m?.

  17. Concurrent in situ ion irradiation transmission electron microscope

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hattar, K.; Bufford, D. C.; Buller, D. L.

    2014-08-29

    An in situ ion irradiation transmission electron microscope has been developed and is operational at Sandia National Laboratories. This facility permits high spatial resolution, real time observation of electron transparent samples under ion irradiation, implantation, mechanical loading, corrosive environments, and combinations thereof. This includes the simultaneous implantation of low-energy gas ions (0.8–30 keV) during high-energy heavy ion irradiation (0.8–48 MeV). In addition, initial results in polycrystalline gold foils are provided to demonstrate the range of capabilities.

  18. Ion irradiation tolerance of graphene as studied by atomistic simulations

    SciTech Connect (OSTI)

    Ahlgren, E. H.; Lehtinen, O.; Kotakoski, J.; Krasheninnikov, A. V.

    2012-06-04

    As impermeable to gas molecules and at the same time transparent to high-energy ions, graphene has been suggested as a window material for separating a high-vacuum ion beam system from targets kept at ambient conditions. However, accumulation of irradiation-induced damage in the graphene membrane may give rise to its mechanical failure. Using atomistic simulations, we demonstrate that irradiated graphene even with a high vacancy concentration does not show signs of such instability, indicating a considerable robustness of graphene windows. We further show that upper and lower estimates for the irradiation damage in graphene can be set using a simple model.

  19. Indoor and Outdoor Spectroradiometer Intercomparison for Spectral Irradiance Measurement

    SciTech Connect (OSTI)

    Habte, A.; Andreas, A.; Ottoson, L.; Gueymard, C.; Fedor, G.; Fowler, S.; Peterson, J.; Naranen, R.; Kobashi, T.; Akiyama, A.; Takagi, S.

    2014-05-01

    This report details the global spectral irradiance intercomparison using spectroradiometers that was organized by the National Renewable Energy Laboratory's Solar Radiation Research Laboratory. The intercomparison was performed both indoors and outdoors on September 17, 2013. Five laboratories participated in the intercomparison using 10 spectroradiometers, and a coordinated measurement setup and a common platform were employed to compare spectral irradiances under both indoor and outdoor conditions. The intercomparison aimed to understand the performance of the different spectroradiometers and to share knowledge in making spectral irradiance measurements. This intercomparison was the first of its kind in the United States.

  20. Solar spectral irradiance changes during cycle 24 (Journal Article) |

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect Solar spectral irradiance changes during cycle 24 Citation Details In-Document Search Title: Solar spectral irradiance changes during cycle 24 We use solar spectra obtained by the Ozone Monitoring Instrument (OMI) on board the Aura satellite to detect and follow long-term (years) and short-term (weeks) changes in the solar spectral irradiance (SSI) in the 265-500 nm spectral range. During solar Cycle 24, in the relatively line-free regions the SSI changed by ∼0.6% ± 0.2%

  1. Early Damage Mechanisms in Nuclear Grade Graphite under Irradiation

    SciTech Connect (OSTI)

    Eapen, Dr. Jacob [North Carolina State University] [North Carolina State University; Krishna, Dr Ram [North Carolina State University] [North Carolina State University; Burchell, Timothy D [ORNL] [ORNL; Murty, Prof K.L. [North Carolina State University] [North Carolina State University

    2014-01-01

    Using Raman and X-ray photoelectron spectroscopy,we delineate the bond and defect structures in nuclear block graphite (NBG-18) under neutron and ion irradiation. The strengthening of the defect (D) peak in the Raman spectra under irradiation is attributed to an increase in the topological, sp2-hybridized defects. Using transmission electron microscopy, we provide evidence for prismatic dislocations as well as a number of basal dislocations dissociating into Shockley partials. The non-vanishing D peak in the Raman spectra, together with a generous number of dislocations, even at low irradiation doses, indicates a dislocation-mediated amorphization process in graphite.

  2. Measurement of thermal conductivity in proton irradiated silicon

    SciTech Connect (OSTI)

    Marat Khafizov; Clarissa Yablinsky; Todd Allen; David Hurley

    2014-04-01

    We investigate the influence of proton irradiation on thermal conductivity in single crystal silicon. We apply laser based modulated thermoreflectance technique to extract the change in conductivity of the thin layer damaged by proton irradiation. Unlike time domain thermoreflectance techniques that require application of a metal film, we perform our measurement on uncoated samples. This provides greater sensitivity to the change in conductivity of the thin damaged layer. Using sample temperature as a parameter provides a means to deduce the primary defect structures that limit thermal transport. We find that under high temperature irradiation the degradation of thermal conductivity is caused primarily by extended defects.

  3. AGC-2 Irradiation Data Qualification Final Report

    SciTech Connect (OSTI)

    Laurence C. Hull

    2012-07-01

    The Graphite Technology Development Program will run a series of six experiments to quantify the effects of irradiation on nuclear grade graphite. The second Advanced Graphite Creep (AGC) experiment (AGC-2) began with Advanced Test Reactor (ATR) Cycle 149A on April 12, 2011, and ended with ATR Cycle 151B on May 5, 2012. The purpose of this report is to qualify AGC-2 irradiation monitoring data following INL Management and Control Procedure 2691, Data Qualification. Data that are Qualified meet the requirements for data collection and use as described in the experiment planning and quality assurance documents. Data that do not meet the requirements are Failed. Some data may not quite meet the requirements, but may still provide some useable information. These data are labeled as Trend. No Trend data were identified for the AGC-2 experiment. All thermocouples functioned throughout the AGC-2 experiment. There was one instance where spurious signals or instrument power interruption resulted in a recorded temperature value being well outside physical reality. This value was identified and labeled as Failed data. All other temperature data are Qualified. All helium and argon gas flow data are within expected ranges. Total gas flow was approximately 50 sccm through the capsule. Helium gas flow was briefly increased to 100 sccm during reactor shutdown. All gas flow data are Qualified. At the start of the experiment, moisture in the outflow gas line increased to 200 ppmv then declined to less than 10 ppmv over a period of 5 days. This increase in moisture coincides with the initial heating of the experiment and drying of the system. Moisture slightly exceeded 10 ppmv three other times during the experiment. While these moisture values exceed the 10 ppmv threshold value, the reported measurements are considered accurate and to reflect moisture conditions in the capsule. All moisture data are Qualified. Graphite creep specimens are subjected to one of three loads, 393 lbf, 491 lbf, or 589 lbf. Loads were consistently within 5% of the specified values throughout the experiment. Stack displacement increased consistently throughout the experiment with total displacement ranging from 1 to 1.5 inches. No anomalous values were identified. During reactor outages, a set of pneumatic rams are used to raise the stacks of graphite creep specimens to ensure the specimens have not become stuck within the test train. This stack raising was performed after all cycles when the capsule was in the reactor. All stacks were raised successfully after each cycle. The load and displacement data are Qualified

  4. Recovery of germanium-68 from irradiated targets

    DOE Patents [OSTI]

    Phillips, Dennis R.; Jamriska, Sr., David J.; Hamilton, Virginia T.

    1993-01-01

    A process for selective separation of germanium-68 from proton irradiated molybdenum targets is provided and includes dissolving the molybdenum target in a hydrogen peroxide solution to form a first ion-containing solution, contacting the first ion-containing solution with a cationic resin whereby ions selected from the group consisting of molybdenum, niobium, technetium, selenium, vanadium, arsenic, germanium, zirconium and rubidium remain in a second ion-containing solution while ions selected from the group consisting of rubidium, zinc, beryllium, cobalt, iron, manganese, chromium, strontium, yttrium and zirconium are selectively adsorbed by the first resin, adjusting the pH of the second ion-containing solution to within a range of from about 0.7 to about 3.0, adjusting the soluble metal halide concentration in the second ion-containing solution to a level adapted for subsequent separation of germanium, contacting the pH-adjusted, soluble metal halide-containing second ion-containing solution with a dextran-based material whereby germanium ions are separated by the dextran-based material, and recovering the germanium from the dextran-based material, preferably by distillation.

  5. Irradiation Assisted Grain Boundary Segregation in Steels

    SciTech Connect (OSTI)

    Lu, Zheng; Faulkner, Roy G.

    2008-07-01

    The understanding of radiation-induced grain boundary segregation (RIS) has considerably improved over the past decade. New models have been introduced and much effort has been devoted to obtaining comprehensive information on segregation from the literature. Analytical techniques have also improved so that chemical analysis of layers 1 nm thick is almost routine. This invited paper will review the major methods used currently for RIS prediction: namely, Rate Theory, Inverse Kirkendall, and Solute Drag approaches. A summary is made of the available data on phosphorus RIS in reactor pressure vessel (RPV) steels. This will be discussed in the light of the predictions of the various models in an effort to show which models are the most reliable and easy to use for forecasting P segregation behaviour in steels. A consequence of RIS in RPV steels is a radiation induced shift in the ductile to brittle transition temperature (DBTT). It will be shown how it is possible to relate radiation-induced P segregation levels to DBTT shift. Examples of this exercise will be given for RPV steels and for ferritic steels being considered for first wall fusion applications. Cr RIS in high alloy stainless steels and associated irradiation-assisted stress corrosion cracking (IASCC) will be briefly discussed. (authors)

  6. Small-scale irradiated fuel electrorefining

    SciTech Connect (OSTI)

    Benedict, R.W.; Krsul, J.R.; Mariani, R.D.; Park, K.; Teske, G.M.

    1993-09-01

    In support of the metallic fuel cycle development for the Integral Fast Reactor (IFR), a small scale electrorefiner was built and operated in the Hot Fuel Examination Facility (HFEF) at Argonne National Laboratory-West. The initial purpose of this apparatus was to test the single segment dissolution of irradiated metallic fuel via either direct dissolution in cadmium or anodic dissolution. These tests showed that 99.95% of the uranium and 99.99% of the plutonium was dissolved and separated from the fuel cladding material. The fate of various fission products was also measured. After the dissolution experiments, the apparatus was upgraded to stady fission product behavior during uranium electrotransport. Preliminary decontamination factors were estimated for different fission products under different processing conditions. Later modifications have added the following capabilities: Dissolution of multiple fuel segments simultaneously, electrotransport to a solid cathode or liquid cathode and actinide recovery with a chemical reduction crucible. These capabilities have been tested with unirradiated uranium-zirconium fuel and will support the Fuel Cycle Demonstration program.

  7. Irradiation effect on deuterium behaviour in low-dose HFIR neutron-irradiated tungsten

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Shimada, Masashi; Cao, G.; Otsuka, T.; Hara, M.; Kobayashi, M.; Oya, Y.; Hatano, Y.

    2014-12-01

    Tungsten samples were irradiated by neutrons in the High Flux Isotope Reactor, Oak Ridge National Laboratory at reactor coolant temperatures of 50-70°C to low displacement damage of 0.025 and 0.3 dpa under the framework of the US-Japan TITAN program (2007-2013). After cooling down, the HFIR neutron-irradiated tungsten samples were exposed to deuterium plasmas in the Tritium Plasma Experiment, Idaho National Laboratory at 100, 200 and 500 °C twice at the ion fluence of 5×10²⁵ m⁻² to reach a total ion fluence of 1×10²⁶ m⁻² in order to investigate the near surface deuterium retention and saturation via nuclear reaction analysis. Finalmore » thermal desorption spectroscopy was performed to elucidate irradiation effect on total deuterium retention. Nuclear reaction analysis results showed that the maximum near surface (<5 µm depth) deuterium concentration increased from 0.5 at % D/W in 0.025 dpa samples to 0.8 at. % D/W in 0.3 dpa samples. The large discrepancy between the total retention via thermal desorption spectroscopy and the near surface retention via nuclear reaction analysis indicated the deuterium was migrated and trapped in bulk (at least 50 µm depth for 0.025 dpa and 35 µm depth for 0.025 dpa) at 500 °C case even in the relatively low ion fluence of 10²⁶ m⁻².« less

  8. Carbon Characterization Laboratory Readiness to Receive Irradiated Graphite Samples

    SciTech Connect (OSTI)

    Karen A. Moore

    2011-05-01

    The Carbon Characterization Laboratory (CCL) is located in Labs C19 and C20 of the Idaho National Laboratory Research Center. The CCL was established under the Next Generation Nuclear Plant Project to support graphite and ceramic composite research and development activities. The research conducted in this laboratory will support the Advanced Graphite Creep experiments—a major series of material irradiation experiments within the Next Generation Nuclear Plant Graphite program. The CCL is designed to characterize and test low activated irradiated materials such as high purity graphite, carbon-carbon composites, silicon-carbide composite, and ceramic materials. The laboratory is fully capable of characterizing material properties for both irradiated and nonirradiated materials. Major infrastructural modifications were undertaken to support this new radiological facility at Idaho National Laboratory. Facility modifications are complete, equipment has been installed, radiological controls and operating procedures have been established and work management documents have been created to place the CCL in readiness to receive irradiated graphite samples.

  9. CASL - Effect of Grain Boundaries on Irradiation Growth of Zirconium...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    vacancy loops on the basal planes. In 2011, the ORNL-based team established a reaction-diffusion model for prediction of irradiation growth at an atomistic level, accounting for...

  10. Irradiation facilities at the Los Alamos Meson Physics Facility

    SciTech Connect (OSTI)

    Sandberg, V.

    1990-01-01

    The irradiation facilities for testing SSC components and detector systems are described. Very high intensity proton, neutron, and pion fluxes are available with beam kinetic energies of up to 800 MeV. 4 refs., 12 figs., 2 tabs.

  11. Enhanced structural stability of nanoporous zirconia under irradiation of He

    SciTech Connect (OSTI)

    Yang, Tengfei; Huang, Xuejun; Wang, Chenxu; Zhang, Yanwen; Xue, Jianming; Yan, Sha; Wang, Yuguang

    2012-01-01

    This work reports a greatly enhanced tolerance for He irradiation-induced swelling in nanocrystalline zirconia film with interconnected nanoporous structure (hereinafter referred as to NC-C). Compared to bulk yttria-stabilized zirconia (YSZ) and another nanocrystalline zirconia film only with discrete nano voids (hereinafter referred as to NC-V), the NC-C film reveals good tolerance for irradiation of high-fluence He. No appreciable surface blistering can be found even at the highest fluence of 6 1017 cm2 in NCC film. From TEM analysis of as-irradiated samples, the enhanced tolerance for volume swelling in NCC film is attributed to the enhanced diffusion mechanism of deposited He via widely distributed nano channels. Furthermore, the growth of grain size is quite small for both nanocrystalline zirconia films after irradiation, which is ascribed to the decreasing of area of grain boundary due to loose structure and low energy of primary knock-on atoms for He ions.

  12. Carbon dioxide laser irradiation of bacterial targets in vitro

    SciTech Connect (OSTI)

    Byrne, P.O.; Sisson, P.R.; Oliver, P.D.; Ingham, H.R.

    1987-05-01

    Agar targets seeded with Escherichia coli and Staphylococcus aureus in roll tubes simulating the vaginal vault were irradiated with a CO/sub 2/ laser at various power densities and durations. Viable bacteria were detected in the plume emissions in all instances. Staphylococcus aureus was found to be more resistant to the thermal effects of lasing than E. coli. This suggests that CO/sub 2/ irradiation of cervical lesions could disseminate viable particles which may be a hazard for patients and operators.

  13. Molecular Weight Distributions of Irradiated Siloxane-Based Elastomers: A

    Office of Scientific and Technical Information (OSTI)

    Complementary Study by Statistical Modeling and Multiple Quantum Nuclear Magnetic Resonance. (Journal Article) | SciTech Connect Molecular Weight Distributions of Irradiated Siloxane-Based Elastomers: A Complementary Study by Statistical Modeling and Multiple Quantum Nuclear Magnetic Resonance. Citation Details In-Document Search Title: Molecular Weight Distributions of Irradiated Siloxane-Based Elastomers: A Complementary Study by Statistical Modeling and Multiple Quantum Nuclear Magnetic

  14. PLUTONIUM-238 RECOVERY FROM IRRADIATED NEPTUNIUM TARGETS USING SOLVENT

    Office of Scientific and Technical Information (OSTI)

    EXTRACTION (Conference) | SciTech Connect PLUTONIUM-238 RECOVERY FROM IRRADIATED NEPTUNIUM TARGETS USING SOLVENT EXTRACTION Citation Details In-Document Search Title: PLUTONIUM-238 RECOVERY FROM IRRADIATED NEPTUNIUM TARGETS USING SOLVENT EXTRACTION The United States Department of Energy proposes to re-establish a domestic capability for producing plutonium-238 (238Pu) to fuel radioisotope power systems primarily in support of future space missions. A conceptual design report is currently

  15. PLUTONIUM-238 RECOVERY FROM IRRADIATED NEPTUNIUM TARGETS USING SOLVENT

    Office of Scientific and Technical Information (OSTI)

    EXTRACTION (Conference) | SciTech Connect PLUTONIUM-238 RECOVERY FROM IRRADIATED NEPTUNIUM TARGETS USING SOLVENT EXTRACTION Citation Details In-Document Search Title: PLUTONIUM-238 RECOVERY FROM IRRADIATED NEPTUNIUM TARGETS USING SOLVENT EXTRACTION × You are accessing a document from the Department of Energy's (DOE) SciTech Connect. This site is a product of DOE's Office of Scientific and Technical Information (OSTI) and is provided as a public service. Visit OSTI to utilize additional

  16. Irradiation Effects on Human Cortical Bone Fracture Behavior

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Irradiation Effects on Human Cortical Bone Fracture Behavior Print Human bone is strong but still fallible. To better predict fracturing in bone, researchers need a mechanistic framework to understand the changes taking place on different size scales within bone, as well as the role of sustained irradiation damage. Combining in situ mechanical testing with synchrotron x-ray diffraction imaging and/or tomography, is a popular method of investigating micrometer deformation and fracture behavior in

  17. Irradiation Effects on Human Cortical Bone Fracture Behavior

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Irradiation Effects on Human Cortical Bone Fracture Behavior Print Human bone is strong but still fallible. To better predict fracturing in bone, researchers need a mechanistic framework to understand the changes taking place on different size scales within bone, as well as the role of sustained irradiation damage. Combining in situ mechanical testing with synchrotron x-ray diffraction imaging and/or tomography, is a popular method of investigating micrometer deformation and fracture behavior in

  18. Irradiation Effects on Human Cortical Bone Fracture Behavior

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Irradiation Effects on Human Cortical Bone Fracture Behavior Print Human bone is strong but still fallible. To better predict fracturing in bone, researchers need a mechanistic framework to understand the changes taking place on different size scales within bone, as well as the role of sustained irradiation damage. Combining in situ mechanical testing with synchrotron x-ray diffraction imaging and/or tomography, is a popular method of investigating micrometer deformation and fracture behavior in

  19. Irradiation Effects on Human Cortical Bone Fracture Behavior

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Irradiation Effects on Human Cortical Bone Fracture Behavior Print Human bone is strong but still fallible. To better predict fracturing in bone, researchers need a mechanistic framework to understand the changes taking place on different size scales within bone, as well as the role of sustained irradiation damage. Combining in situ mechanical testing with synchrotron x-ray diffraction imaging and/or tomography, is a popular method of investigating micrometer deformation and fracture behavior in

  20. Irradiation Effects on Human Cortical Bone Fracture Behavior

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Irradiation Effects on Human Cortical Bone Fracture Behavior Print Human bone is strong but still fallible. To better predict fracturing in bone, researchers need a mechanistic framework to understand the changes taking place on different size scales within bone, as well as the role of sustained irradiation damage. Combining in situ mechanical testing with synchrotron x-ray diffraction imaging and/or tomography, is a popular method of investigating micrometer deformation and fracture behavior in

  1. Irradiation Effects on Human Cortical Bone Fracture Behavior

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Irradiation Effects on Human Cortical Bone Fracture Behavior Print Human bone is strong but still fallible. To better predict fracturing in bone, researchers need a mechanistic framework to understand the changes taking place on different size scales within bone, as well as the role of sustained irradiation damage. Combining in situ mechanical testing with synchrotron x-ray diffraction imaging and/or tomography, is a popular method of investigating micrometer deformation and fracture behavior in

  2. Thermoluminescence and dielectric response of gamma irradiated muscovite mica

    SciTech Connect (OSTI)

    Kaur, Sukhnandan Singh, Surinder Singh, Lakhwant; Lochab, S. P.

    2014-04-24

    The effect of gamma radiation dose on the thermoluminescence (TL) and dielectric properties of muscovite mica was studied. TL glow curves exhibited a single peak around 141 {sup 0}C and its activation energy was estimated to be about 0.89 eV. Different dielectric parameters like dielectric constant, dielectric loss and ac conductivity have been calculated in both pristine and gamma irradiated samples. These dielectric parameters have been studied as a function of irradiation dose.

  3. Improved Solar Power Plant Efficiency: Low Cost Solar Irradiance Sensor -

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Innovation Portal Solar Photovoltaic Solar Photovoltaic Industrial Technologies Industrial Technologies Electricity Transmission Electricity Transmission Find More Like This Return to Search Improved Solar Power Plant Efficiency: Low Cost Solar Irradiance Sensor University of Colorado Contact CU About This Technology Publications: PDF Document Publication CU3117D (Irradiance Sensor) Marketing Summary.pdf (149 KB) Technology Marketing Summary A University of Colorado research group led

  4. Stress/Strain Response of Irradiated Metallic Materials via Spherical

    Office of Scientific and Technical Information (OSTI)

    Nanoindentation (Conference) | SciTech Connect Conference: Stress/Strain Response of Irradiated Metallic Materials via Spherical Nanoindentation Citation Details In-Document Search Title: Stress/Strain Response of Irradiated Metallic Materials via Spherical Nanoindentation Authors: Pathak, Siddhartha [1] ; Mara, Nathan Allan [1] ; Kalidindi, Surya [2] ; Wang, Yongqiang [1] ; Doerner, Russ [3] ; Nelson, Andrew Thomas [1] + Show Author Affiliations Los Alamos National Laboratory Georgia Tech

  5. Ion irradiation testing of Improved Accident Tolerant Cladding Materials

    SciTech Connect (OSTI)

    Anderoglu, Osman [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Tesmer, Joseph R. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Maloy, Stuart A. [Los Alamos National Lab. (LANL), Los Alamos, NM (United States)

    2014-01-14

    This report summarizes the results of ion irradiations conducted on two FeCrAl alloys (named as ORNL A&B) for improving the accident tolerance of LWR nuclear fuel cladding. After irradiation with 1.5 MeV protons to ~0.5 to ~1 dpa and 300C nanoindentations were performed on the cross-sections along the ion range. An increase in hardness was observed in both alloys. Microstructural analysis shows radiation induced defects.

  6. Initiate test loop irradiations of ALSEP process solvent

    SciTech Connect (OSTI)

    Peterman, Dean R.; Olson, Lonnie G.; McDowell, Rocklan G.

    2014-09-01

    This report describes the initial results of the study of the impacts of gamma radiolysis upon the efficacy of the ALSEP process and is written in completion of milestone M3FT-14IN030202. Initial irradiations, up to 100 kGy absorbed dose, of the extraction section of the ALSEP process have been completed. The organic solvent used for these experiments contained 0.05 M TODGA and 0.75 M HEH[EHP] dissolved in n-dodecane. The ALSEP solvent was irradiated while in contact with 3 M nitric acid and the solutions were sparged with compressed air in order to maintain aerated conditions. The irradiated phases were used for the determination of americium and europium distribution ratios as a function of absorbed dose for the extraction and stripping conditions. Analysis of the irradiated phases in order to determine solvent composition as a function of absorbed dose is ongoing. Unfortunately, the failure of analytical equipment necessary for the analysis of the irradiated samples has made the consistent interpretation of the analytical results difficult. Continuing work will include study of the impacts of gamma radiolysis upon the extraction of actinides and lanthanides by the ALSEP solvent and the stripping of the extracted metals from the loaded solvent. The irradiated aqueous and organic phases will be analyzed in order to determine the variation in concentration of solvent components with absorbed gamma dose. Where possible, radiolysis degradation product will be identified.

  7. Heavy-ion irradiation induced diamond formation in carbonaceous materials.

    SciTech Connect (OSTI)

    Daulton, T. L.

    1999-01-08

    The basic mechanisms of metastable phase formation produced under highly non-equilibrium thermodynamic conditions within high-energy particle tracks are investigated. In particular, the possible formation of diamond by heavy-ion irradiation of graphite at ambient temperature is examined. This work was motivated, in part, by earlier studies which discovered nanometer-grain polycrystalline diamond aggregates of submicron-size in uranium-rich carbonaceous mineral assemblages of Precambrian age. It was proposed that the radioactive decay of uranium formed diamond in the fission particle tracks produced in the carbonaceous minerals. To test the hypothesis that nanodiamonds can form by ion irradiation, fine-grain polycrystalline graphite sheets were irradiated with 400 MeV Kr ions. The ion irradiated graphite (and unirradiated graphite control) were then subjected to acid dissolution treatments to remove the graphite and isolate any diamonds that were produced. The acid residues were then characterized by analytical and high-resolution transmission electron microscopy. The acid residues of the ion-irradiated graphite were found to contain ppm concentrations of nanodiamonds, suggesting that ion irradiation of bulk graphite at ambient temperature can produce diamond.

  8. Influence of irradiation upon few-layered graphene using electron-beams and gamma-rays

    SciTech Connect (OSTI)

    Wang, Yuqing; Feng, Yi, E-mail: fyhfut@163.com; Mo, Fei; Qian, Gang; Chen, Yangming; Yu, Dongbo; Wang, Yang; Zhang, Xuebin [School of Materials Science and Engineering, Hefei University of Technology, Hefei 230009 (China)

    2014-07-14

    Few-layered graphene (FLG) is irradiated by electron beams and gamma rays. After 100?keV electron irradiation, the edges of FLG start bending, shrinking, and finally generate gaps and carbon onions due to sputtering and knock-on damage mechanism. When the electron beam energy is increased further to 200?keV, FLG suffers rapid and catastrophic destruction. Unlike electron irradiation, Compton effect is the dominant damage mechanism in gamma irradiation. The irradiation results indicate the crystallinity of FLG decreases first, then restores as increasing irradiation doses, additionally, the ratio (O/C) of FLG surface and the relative content of oxygen groups increases after irradiation.

  9. Delivery of completed irradiation vehicles and the quality assurance document to the High Flux Isotope Reactor for irradiation

    SciTech Connect (OSTI)

    Petrie, Christian M.; McDuffee, Joel Lee; Katoh, Yutai; Terrani, Kurt A.

    2015-10-01

    This report details the initial fabrication and delivery of two Fuel Cycle Research and Development (FCRD) irradiation capsules (ATFSC01 and ATFSC02), with associated quality assurance documentation, to the High Flux Isotope Reactor (HFIR). The capsules and documentation were delivered by September 30, 2015, thus meeting the deadline for milestone M3FT-15OR0202268. These irradiation experiments are testing silicon carbide composite tubes in order to obtain experimental validation of thermo-mechanical models of stress states in SiC cladding irradiated under a prototypic high heat flux. This document contains a copy of the completed capsule fabrication request sheets, which detail all constituent components, pertinent drawings, etc., along with a detailed summary of the capsule assembly process performed by the Thermal Hydraulics and Irradiation Engineering Group (THIEG) in the Reactor and Nuclear Systems Division (RNSD). A complete fabrication package record is maintained by the THIEG and is available upon request.

  10. Irradiation-Assisted Stress Corrosion Cracking of Austenitic Stainless Steels and Alloy 690 from Halden Phase-II Irradiations

    SciTech Connect (OSTI)

    Chen, Y.; Chopra, O. K.; Soppet, W. K.; Dietz Rago, Nancy L.; Shack, W. J.

    2008-09-01

    This work is an ongoing effort at Argonne National Laboratory on the mechanistic study of irradiation-assisted stress corrosion cracking (IASCC) in the core internals of light water reactors.

  11. The effects of tungsten's pre-irradiation surface condition on helium-irradiated morphology

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Garrison, Lauren M.; Kulcinski, Gerald L.

    2015-07-17

    Erosion is a concern associated with the use of tungsten as a plasma-facing component in fusion reactors. To compare the damage progression, polycrystalline tungsten (PCW) and (110) single crystal tungsten (SCW) samples were prepared with (1) a mechanical polish (MP) with roughness values in the range of 0.018–0.020 μm and (2) an MP and electropolish (MPEP) resulting in roughness values of 0.010–0.020 μm for PCW and 0.003–0.005 μm for SCW samples. Samples were irradiated with 30 keV He+ at 1173 K to fluences between 3 × 1021 and 6 × 1022 He/m2. The morphologies that developed after low-fluence bombardment weremore » different for each type of sample—MP SCW, MPEP SCW, MP PCW, and MPEP PCW. At the highest fluence, the SCW MPEP sample lost significantly more mass and developed a different morphology than the MP SCW sample. The PCW samples developed a similar morphology and had similar mass loss at the highest fluence. Surface preparation can have a significant effect on post-irradiation morphology that should be considered for the design of future fusion reactors such as ITER and DEMO.« less

  12. Solar spectral irradiance changes during cycle 24

    SciTech Connect (OSTI)

    Marchenko, S. V.; DeLand, M. T.

    2014-07-10

    We use solar spectra obtained by the Ozone Monitoring Instrument (OMI) on board the Aura satellite to detect and follow long-term (years) and short-term (weeks) changes in the solar spectral irradiance (SSI) in the 265-500 nm spectral range. During solar Cycle 24, in the relatively line-free regions the SSI changed by ?0.6% 0.2% around 265 nm. These changes gradually diminish to 0.15% 0.20% at 500 nm. All strong spectral lines and blends, with the notable exception of the upper Balmer lines, vary in unison with the solar 'continuum'. Besides the lines with strong chromospheric components, the most involved species include Fe I blends and all prominent CH, NH, and CN spectral bands. Following the general trend seen in the solar 'continuum', the variability of spectral lines also decreases toward longer wavelengths. The long-term solar cycle SSI changes are closely, to within the quoted 0.1%-0.2% uncertainties, matched by the appropriately adjusted short-term SSI variations derived from the 27 day rotational modulation cycles. This further strengthens and broadens the prevailing notion about the general scalability of the UV SSI variability to the emissivity changes in the Mg II 280 nm doublet on timescales from weeks to years. We also detect subtle deviations from this general rule: the prominent spectral lines and blends at ? ? 350 nm show slightly more pronounced 27 day SSI changes when compared to the long-term (years) trends. We merge the solar data from Cycle 21 with the current Cycle 24 OMI and GOME-2 observations and provide normalized SSI variations for the 170-795 nm spectral region.

  13. EFFECTS OF GAMMA IRRADIATION ON EPDM ELASTOMERS (REVISION 1)

    SciTech Connect (OSTI)

    Clark, E.

    2013-09-13

    Two formulations of EPDM elastomer, one substituting a UV stabilizer for the normal antioxidant in this polymer, and the other the normal formulation, were synthesized and samples of each were exposed to gamma irradiation in initially pure deuterium gas to compare their radiation stability. Stainless steel containers having rupture disks were designed for this task. After 130 MRad dose of cobalt-60 radiation in the SRNL Gamma Irradiation Facility, a significant amount of gas was created by radiolysis; however the composition indicated by mass spectroscopy indicated an unexpected increase in the total amount deuterium in both formulations. The irradiated samples retained their ductility in a bend test. No change of sample weight, dimensions, or density was observed. No change of the glass transition temperature as measured by dynamic mechanical analysis was observed, and most of the other dynamic mechanical properties remained unchanged. There appeared to be an increase in the storage modulus of the irradiated samples containing the UV stabilizer above the glass transition, which may indicate hardening of the material by radiation damage. Revision 1 adds a comparison with results of a study of tritium exposed EPDM. The amount of gas produced by the gamma irradiation was found to be equivalent to about 280 days exposure to initially pure tritium gas at one atmosphere. The glass transition temperature of the tritium exposed EPDM rose about 10 ?C. over 280 days, while no glass transition temperature change was observed for gamma irradiated EPDM. This means that gamma irradiation in deuterium cannot be used as a surrogate for tritium exposure.

  14. AGR-2 IRRADIATION TEST FINAL AS-RUN REPORT

    SciTech Connect (OSTI)

    Blaise, Collin

    2014-07-01

    This document presents the as-run analysis of the AGR-2 irradiation experiment. AGR-2 is the second of the planned irradiations for the Advanced Gas Reactor (AGR) Fuel Development and Qualification Program. Funding for this program is provided by the U.S. Department of Energy as part of the Very High Temperature Reactor (VHTR) Technical Development Office (TDO) program. The objectives of the AGR-2 experiment are to: (a) Irradiate UCO (uranium oxycarbide) and UO2 (uranium dioxide) fuel produced in a large coater. Fuel attributes are based on results obtained from the AGR-1 test and other project activities. (b) Provide irradiated fuel samples for post-irradiation experiment (PIE) and safety testing. (c) Support the development of an understanding of the relationship between fuel fabrication processes, fuel product properties, and irradiation performance. The primary objective of the test was to irradiate both UCO and UO2 TRISO (tri-structural isotropic) fuel produced from prototypic scale equipment to obtain normal operation and accident condition fuel performance data. The UCO compacts were subjected to a range of burnups and temperatures typical of anticipated prismatic reactor service conditions in three capsules. The test train also includes compacts containing UO2 particles produced independently by the United States, South Africa, and France in three separate capsules. The range of burnups and temperatures in these capsules were typical of anticipated pebble bed reactor service conditions. The results discussed in this report pertain only to U.S. produced fuel. In order to achieve the test objectives, the AGR-2 experiment was irradiated in the B-12 position of the Advanced Test Reactor (ATR) at Idaho National Laboratory (INL) for a total irradiation duration of 559.2 effective full power days (EFPD). Irradiation began on June 22, 2010, and ended on October 16, 2013, spanning 12 ATR power cycles and approximately three and a half calendar years. The test contained six independently controlled and monitored capsules. Each U.S. capsule contained 12 compacts of either UCO or UO2 AGR coated fuel. No fuel particles failed during the AGR-2 irradiation. Final burnup values on a per compact basis ranged from 7.26 to 13.15% FIMA (fissions per initial heavy-metal atom) for UCO fuel, and 9.01 to 10.69% FIMA for UO2 fuel, while fast fluence values ranged from 1.94 to 3.471025 n/m2 (E >0.18 MeV) for UCO fuel, and from 3.05 to 3.531025 n/m2 (E >0.18 MeV) for UO2 fuel. Time-average volume-average (TAVA) temperatures on a capsule basis at the end of irradiation ranged from 987C in Capsule 6 to 1296C in Capsule 2 for UCO, and from 996 to 1062C in UO2-fueled Capsule 3. By the end of the irradiation, all of the installed thermocouples (TCs) had failed. Fission product release-to-birth (R/B) ratios were quite low. In the UCO capsules, R/B values during the first three cycles were below 10-6 with the exception of the hotter Capsule 2, in which the R/Bs reached 210-6. In the UO2 capsule (Capsule 3), the R/B values during the first three cycles were below 10-7. R/B values for all following cycles are not reliable due to gas flow and cross talk issues.

  15. Light ion irradiation for unfavorable soft tissue sarcoma

    SciTech Connect (OSTI)

    Linstadt, D.; Castro, J.R.; Phillips, T.L.; Petti, P.L.; Collier, J.M.; Daftari, I.; Schoethaler, R.; Rayner, A.

    1990-09-01

    Between 1978 and 1989, 32 patients with unfavorable soft tissue sarcoma underwent light ion (helium, neon) irradiation with curative intent at Lawrence Berkeley Laboratory. The tumors were located in the trunk in 22 patients and head and neck in 10. Macroscopic tumor was present in 22 at the time of irradiation. Two patients had tumors apparently induced by previous therapeutic irradiation. Follow-up times for surviving patients ranged from 4 to 121 months (median 27 months). The overall 3-year actuarial local control rate was 62%; the corresponding survival rate was 50%. The 3-year actuarial control rate for patients irradiated with macroscopic tumors was 48%, while none of the patients with microscopic disease developed local recurrence (100%). The corresponding 3-year actuarial survival rates were 40% (macroscopic) and 78% (microscopic). Patients with retroperitoneal sarcoma did notably well; the local control rate and survival rate were 64% and 62%, respectively. Complications were acceptable; there were no radiation related deaths, while two patients (6%) required operations to correct significant radiation-related injuries. These results appear promising compared to those achieved by low -LET irradiation, and suggest that this technique merits further investigation.

  16. Irradiation-induced phase transformations in zirconium alloys

    SciTech Connect (OSTI)

    Howe, L.M.; Phillips, D.; Motta, A.T.; Okamoto, P.R.

    1994-02-01

    {sup 40}Ar and {sup 209}Bi ion irradiations of Zr{sub 3}Fe were performed at 35--725 K using 15-1500 keV ions. Results are presented on role of deposited-energy density on nature of the damaged regions in individual cascades produced by ion bombardment of Zr{sub 3}Fe. Comparison is also made between irradiation-induced amorphization of Zr{sub 3}Fe during electron irradiation and under ion bombardments. Dependence of damage production on incident electron energy in Zr{sub 3}Fe was also determined. Preliminary results are also discussed for amorphization of ZrFe{sub 2}, Zr(Cr,Fe){sub 2} and ZrCr{sub 2} by electron irradiation. Results of a recent investigation on amorphization of Zr(Cr,Fe){sub 2} and Zr{sub 2}(Ni,Fe) precipitates in Zircaloy-4 are discussed in context of previous experimental results of neutron and electron irradiations and likely amorphization mechanisms are proposed.

  17. Irradiation-induced composition patterns in binary solid solutions

    SciTech Connect (OSTI)

    Dubey, Santosh; El-Azab, Anter [School of Nuclear Engineering, Purdue University, West Lafayette, Indiana 47906 (United States)] [School of Nuclear Engineering, Purdue University, West Lafayette, Indiana 47906 (United States)

    2013-09-28

    A theoretical/computational model for the irradiation-driven compositional instabilities in binary solid solutions has been developed. The model is suitable for investigating the behavior of structural alloys and metallic nuclear fuels in a reactor environment as well as the response of alloy thin films to ion beam irradiation. The model is based on a set of reaction-diffusion equations for the dynamics of vacancies, interstitials, and lattice atoms under irradiation. The dynamics of these species includes the stochastic generation of defects by collision cascades as well as the defect reactions and diffusion. The atomic fluxes in this model are derived based on the transitions of lattice defects. The set of reaction-diffusion equations are stiff, hence a stiffly stable method, also known as the Gear method, has been used to numerically approximate the equations. For the Cu-Au alloy in the solid solution regime, the model results demonstrate the formation of compositional patterns under high-temperature particle irradiation, with Fourier space properties (Fourier spectrum, average wavelength, and wavevector) depending on the cascade damage characteristics, average composition, and irradiation temperature.

  18. Irradiation-Accelerated Corrosion of Reactor Core Materials. Final Report

    SciTech Connect (OSTI)

    Jiao, Zhujie; Was, Gary; Bartels, David

    2015-04-02

    This project aims to understand how radiation accelerates corrosion of reactor core materials. The combination of high temperature, chemically aggressive coolants, a high radiation flux and mechanical stress poses a major challenge for the life extension of current light water reactors, as well as the success of most all GenIV concepts. Of these four drivers, the combination of radiation and corrosion places the most severe demands on materials, for which an understanding of the fundamental science is simply absent. Only a few experiments have been conducted to understand how corrosion occurs under irradiation, yet the limited data indicates that the effect is large; irradiation causes order of magnitude increases in corrosion rates. Without a firm understanding of the mechanisms by which radiation and corrosion interact in film formation, growth, breakdown and repair, the extension of the current LWR fleet beyond 60 years and the success of advanced nuclear energy systems are questionable. The proposed work will address the process of irradiation-accelerated corrosion that is important to all current and advanced reactor designs, but remains very poorly understood. An improved understanding of the role of irradiation in the corrosion process will provide the community with the tools to develop predictive models for in-reactor corrosion, and to address specific, important forms of corrosion such as irradiation assisted stress corrosion cracking.

  19. Neutron radiography of irradiated nuclear fuel at Idaho National Laboratory

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Craft, Aaron E.; Wachs, Daniel M.; Okuniewski, Maria A.; Chichester, David L.; Williams, Walter J.; Papaioannou, Glen C.; Smolinski, Andrew T.

    2015-09-10

    Neutron radiography of irradiated nuclear fuel provides more comprehensive information about the internal condition of irradiated nuclear fuel than any other non-destructive technique to date. Idaho National Laboratory (INL) has multiple nuclear fuels research and development programs that routinely evaluate irradiated fuels using neutron radiography. The Neutron Radiography reactor (NRAD) sits beneath a shielded hot cell facility where neutron radiography and other evaluation techniques are performed on these highly radioactive objects. The NRAD currently uses the foil-film transfer technique for imaging fuel that is time consuming but provides high spatial resolution. This study describes the NRAD and hot cell facilities,more » the current neutron radiography capabilities available at INL, planned upgrades to the neutron imaging systems, and new facilities being brought online at INL related to neutron imaging.« less

  20. The materials test station: a fast spectrum irradiation facility

    SciTech Connect (OSTI)

    Pitcher, Eric J.

    2007-07-01

    The Materials Test Station is a fast-neutron spectrum irradiation facility under design at the Los Alamos National Laboratory in support of the United States Department of Energy's Global Nuclear Energy Partnership. The facility will be capable of rodlets-scale irradiations of candidate fuel forms being developed to power the next generation of fast reactors. Driven by a powerful proton beam, the fuel irradiation region exhibits a neutron spectrum similar to that seen in a fast reactor, with a peak neutron flux of 1.6 x 10{sup 15} n.cm{sup -2}.s{sup -1}. Site preparation and construction are estimated to take four years, with a cost range of $60 M to $90 M. (author)

  1. A semiparametric spatio-temporal model for solar irradiance data

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Patrick, Joshua D.; Harvill, Jane L.; Hansen, Clifford W.

    2016-03-01

    Here, we evaluate semiparametric spatio-temporal models for global horizontal irradiance at high spatial and temporal resolution. These models represent the spatial domain as a lattice and are capable of predicting irradiance at lattice points, given data measured at other lattice points. Using data from a 1.2 MW PV plant located in Lanai, Hawaii, we show that a semiparametric model can be more accurate than simple interpolation between sensor locations. We investigate spatio-temporal models with separable and nonseparable covariance structures and find no evidence to support assuming a separable covariance structure. These results indicate a promising approach for modeling irradiance atmore » high spatial resolution consistent with available ground-based measurements. Moreover, this kind of modeling may find application in design, valuation, and operation of fleets of utility-scale photovoltaic power systems.« less

  2. AGR-1 Irradiation Test Final As-Run Report

    SciTech Connect (OSTI)

    Blaise P. Collin

    2012-06-01

    This document presents the as-run analysis of the AGR-1 irradiation experiment. AGR-1 is the first of eight planned irradiations for the Advanced Gas Reactor (AGR) Fuel Development and Qualification Program. Funding for this program is provided by the US Department of Energy (DOE) as part of the Next-Generation Nuclear Plant (NGNP) project. The objectives of the AGR-1 experiment are: 1. To gain experience with multi-capsule test train design, fabrication, and operation with the intent to reduce the probability of capsule or test train failure in subsequent irradiation tests. 2. To irradiate fuel produced in conjunction with the AGR fuel process development effort. 3. To provide data that will support the development of an understanding of the relationship between fuel fabrication processes, fuel product properties, and irradiation performance. In order to achieve the test objectives, the AGR-1 experiment was irradiated in the B-10 position of the Advanced Test Reactor (ATR) at the Idaho National Laboratory (INL) for a total duration of 620 effective full power days of irradiation. Irradiation began on December 24, 2006 and ended on November 6, 2009 spanning 13 ATR cycles and approximately three calendar years. The test contained six independently controlled and monitored capsules. Each capsule contained 12 compacts of a single type, or variant, of the AGR coated fuel. No fuel particles failed during the AGR-1 irradiation. Final burnup values on a per compact basis ranged from 11.5 to 19.6 %FIMA, while fast fluence values ranged from 2.21 to 4.39 ?1025 n/m2 (E >0.18 MeV). Well say something here about temperatures once thermal recalc is done. Thermocouples performed well, failing at a lower rate than expected. At the end of the irradiation, nine of the originally-planned 19 TCs were considered functional. Fission product release-to-birth (R/B) ratios were quite low. In most capsules, R/B values at the end of the irradiation were at or below 10-7 with only one capsule significantly exceeding this value. A maximum R/B of around 2?10-7 was reached at the end of the irradiation in Capsule 5. Several shakedown issues were encountered and resolved during the first three cycles. These include the repair of minor gas line leaks; repair of faulty gas line valves; the need to position moisture monitors in regions of low radiation fields for proper functioning; the enforcement of proper on-line data storage and backup, the need to monitor thermocouple performance, correcting for detector spectral gain shift, and a change in the mass flow rate range of the neon flow controllers.

  3. Neutron radiography of irradiated nuclear fuel at Idaho National Laboratory

    SciTech Connect (OSTI)

    Craft, Aaron E.; Wachs, Daniel M.; Okuniewski, Maria A.; Chichester, David L.; Williams, Walter J.; Papaioannou, Glen C.; Smolinski, Andrew T.

    2015-09-10

    Neutron radiography of irradiated nuclear fuel provides more comprehensive information about the internal condition of irradiated nuclear fuel than any other non-destructive technique to date. Idaho National Laboratory (INL) has multiple nuclear fuels research and development programs that routinely evaluate irradiated fuels using neutron radiography. The Neutron Radiography reactor (NRAD) sits beneath a shielded hot cell facility where neutron radiography and other evaluation techniques are performed on these highly radioactive objects. The NRAD currently uses the foil-film transfer technique for imaging fuel that is time consuming but provides high spatial resolution. This study describes the NRAD and hot cell facilities, the current neutron radiography capabilities available at INL, planned upgrades to the neutron imaging systems, and new facilities being brought online at INL related to neutron imaging.

  4. Apparatus for irradiating a continuously flowing stream of fluid

    DOE Patents [OSTI]

    Speir, Leslie G. (Espanola, NM); Adams, Edwin L. (Jemez Springs, NM)

    1984-01-01

    An apparatus for irradiating a continuously flowing stream of fluid is diosed. The apparatus consists of a housing having a spherical cavity and a spherical moderator containing a radiation source positioned within the spherical cavity. The spherical moderator is of lesser diameter than the spherical cavity so as to define a spherical annular volume around the moderator. The housing includes fluid intake and output conduits which open onto the spherical cavity at diametrically opposite positions. Fluid flows through the cavity around the spherical moderator and is uniformly irradiated due to the 4.pi. radiation geometry. The irradiation source, for example a .sup.252 CF neutron source, is removable from the spherical moderator through a radial bore which extends outwardly to an opening on the outside of the housing. The radiation source may be routinely removed without interrupting the flow of fluid or breaching the containment of the fluid.

  5. Neutron and gamma irradiation damage to organic materials.

    SciTech Connect (OSTI)

    White, Gregory Von, II; Bernstein, Robert

    2012-04-01

    This document discusses open literature reports which investigate the damage effects of neutron and gamma irradiation on polymers and/or epoxies - damage refers to reduced physical chemical, and electrical properties. Based on the literature, correlations are made for an SNL developed epoxy (Epon 828-1031/DDS) with an expected total fast-neutron fluence of {approx}10{sup 12} n/cm{sup 2} and a {gamma} dosage of {approx}500 Gy received over {approx}30 years at < 200 C. In short, there are no gamma and neutron irradiation concerns for Epon 828-1031/DDS. To enhance the fidelity of our hypotheses, in regards to radiation damage, we propose future work consisting of simultaneous thermal/irradiation (neutron and gamma) experiments that will help elucidate any damage concerns at these specified environmental conditions.

  6. Evaluation of global horizontal irradiance to plane-of-array irradiance models at locations across the United States

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Lave, Matthew; Hayes, William; Pohl, Andrew; Hansen, Clifford W.

    2015-02-02

    We report an evaluation of the accuracy of combinations of models that estimate plane-of-array (POA) irradiance from measured global horizontal irradiance (GHI). This estimation involves two steps: 1) decomposition of GHI into direct and diffuse horizontal components and 2) transposition of direct and diffuse horizontal irradiance (DHI) to POA irradiance. Measured GHI and coincident measured POA irradiance from a variety of climates within the United States were used to evaluate combinations of decomposition and transposition models. A few locations also had DHI measurements, allowing for decoupled analysis of either the decomposition or the transposition models alone. Results suggest that decompositionmore » models had mean bias differences (modeled versus measured) that vary with climate. Transposition model mean bias differences depended more on the model than the location. Lastly, when only GHI measurements were available and combinations of decomposition and transposition models were considered, the smallest mean bias differences were typically found for combinations which included the Hay/Davies transposition model.« less

  7. SLIGHTLY IRRADIATED FUEL (SIF) INTERIM DISPOSITION PROJECT

    SciTech Connect (OSTI)

    NORTON SH

    2010-02-23

    CH2M HILL Plateau Remediation Company (CH2M HILL PRC) is proud to submit the Slightly Irradiated Fuel (SIF) Interim Disposition Project for consideration by the Project Management Institute as Project of the Year for 2010. The SIF Project was a set of six interrelated sub-projects that delivered unique stand-alone outcomes, which, when integrated, provided a comprehensive and compliant system for storing high risk special nuclear materials. The scope of the six sub-projects included the design, construction, testing, and turnover of the facilities and equipment, which would provide safe, secure, and compliant Special Nuclear Material (SNM) storage capabilities for the SIF material. The project encompassed a broad range of activities, including the following: Five buildings/structures removed, relocated, or built; Two buildings renovated; Structural barriers, fencing, and heavy gates installed; New roadways and parking lots built; Multiple detection and assessment systems installed; New and expanded communication systems developed; Multimedia recording devices added; and A new control room to monitor all materials and systems built. Project challenges were numerous and included the following: An aggressive 17-month schedule to support the high-profile Plutonium Finishing Plant (PFP) decommissioning; Company/contractor changeovers that affected each and every project team member; Project requirements that continually evolved during design and construction due to the performance- and outcome-based nature ofthe security objectives; and Restrictions imposed on all communications due to the sensitive nature of the projects In spite of the significant challenges, the project was delivered on schedule and $2 million under budget, which became a special source of pride that bonded the team. For years, the SIF had been stored at the central Hanford PFP. Because of the weapons-grade piutonium produced and stored there, the PFP had some of the tightest security on the Hanford nuclear reservation. Workers had to pass through metal detectors when they arrived at the plant and materials leaving the plant had to be scanned for security reasons. Whereas other high-security nuclear materials were shipped from the PFP to Savannah River, S.C. as part ofa Department of Energy (DOE) program to consolidate weapons-grade plutonium, it was determined that the SIF should remain onsite pending disposition to a national repository. Nevertheless, the SIF still requires a high level of security that the PFP complex has always provided. With the 60-year PFP mission of producing and storing plutonium concluded, the environmental cleanup plans for Hanford call for the demolition of the 63-building PFP complex. Consequently, if the SIF remained at PFP it not only would have interfered with the environmental cleanup plans, but would have required $100 million in facility upgrades to meet increased national security requirements imposed after the 9/11 terrorist attacks. A new smaller and more cost-effective area was needed to store this material, which led to the SIF Project. Once the SIF project was successfully completed and the SIF was safely removed from PFP, the existing Protected Area at PFP could be removed, and demolition could proceed more quickly without being encumbered by restrictive security requirements that an active Protected Area requires. The lightened PFP security level brought by safely removing and storing the SIF would also yield lowered costs for deactivation and demolition, as well as reduce overall life-cycle costs.

  8. Measuring Broadband IR Irradiance in the Direct Solar Beam (Presentation)

    SciTech Connect (OSTI)

    Reda, I.

    2015-03-01

    Solar and atmospheric science radiometers, e.g. pyranometers, pyrheliometers, and photovoltaic cells are calibrated with traceability to a consensus reference, which is maintained by Absolute Cavity Radiometers (ACRs). The ACR is an open cavity with no window, developed to measure extended broadband direct solar irradiance beyond the ultraviolet and infrared bands below and above 0.2 um and 50 um, respectively. On the other hand, pyranometers and pyrheliometers are developed to measure broadband shortwave irradiance from approximately 0.3 um to 3 um, while the present photovoltaic cells are limited to approximately 0.3 um to 1 um. The broadband mismatch of ACR versus such radiometers causes discrepancy in radiometers' calibration methods that has not been discussed or addressed in the solar and atmospheric science literature. Pyrgeometers are also used for solar and atmospheric science applications and are calibrated with traceability to consensus reference, yet are calibrated during nighttime only, because no consensus reference has yet been established for the daytime longwave irradiance. This poster shows a method to measure the broadband IR irradiance in the direct solar beam from 3 um to 50 um, as a first step that might be used to help develop calibration methods to address the mismatch between broadband ACR and shortwave radiometers, and the lack of a daytime reference for pyrgeometers. The irradiance was measured from sunrise to sunset for 5 days when the sun disk was cloudless; the irradiance varied from approximately 1 Wm-2 to 16 Wm-2 for solar zenith angle from 80 degrees to 16 degrees respectively; estimated uncertainty is 1.5 Wm-2.

  9. Irradiated Microsphere Gamma Analyzer for Examination of Particle Fuel

    SciTech Connect (OSTI)

    Paul A. Demkowicz; Various

    2014-06-01

    Fabrication of the first series of fuel compacts for the current US tristructural isotropic (TRISO) coated particle fuel development and qualification effort was completed at Oak Ridge National Laboratory (ORNL) in 2006. In November of 2009, after almost 3 years and 620 effective full power days of irradiation in the Advanced Test Reactor at Idaho National Laboratory (INL), the first Advanced Gas Reactor irradiation test (AGR-1) was concluded. Compacts were irradiated at a calculated timeaveraged, volume-averaged temperature of 9551136C to a burnup ranging from 11.219.5% fissions per initial metal atom and a total fast fluence of 2.24.31025 n/m2 [1]. No indication of fission product release from TRISO coating failure was observed during the irradiation test, based on real-time monitoring of gaseous fission products. Post-irradiation examination (PIE) and hightemperature safety testing of the compacts has been in progress at both ORNL and INL since 2010, and have revealed small releases of a limited subset of fission products (such as silver, cesium, and europium). Past experience has shown that some elements can be released from TRISO particles when a defect forms in the SiC layer, even when one or more pyrocarbon layers remain intact and retain the gaseous fission products. Some volatile elements can also be released by diffusion through an intact SiC layer during safety testing if temperatures are high enough and the duration is long enough. In order to understand and quantify the release of certain radioactive fission products, it is sometimes necessary to individually examine each of the more than 4000 coated particles in a given compact. The Advanced Irradiated Microsphere Gamma Analyzer (Advanced- IMGA) was designed to perform this task in a remote hot cell environment. This paper describes the Advanced- IMGA equipment and examination process and gives results for a typical full compact evaluation.

  10. Measuring Broadband IR Irradiance in the Direct Solar Beam (Poster)

    SciTech Connect (OSTI)

    Reda, I.; Konings, J.; Xie, Y.; Dooraghi, M.; Sengupta, M.

    2015-03-01

    Solar and atmospheric science radiometers, e.g. pyranometers, pyrheliometers, and photovoltaic cells are calibrated with traceability to a consensus reference, which is maintained by Absolute Cavity Radiometers (ACRs). The ACR is an open cavity with no window, developed to measure extended broadband direct solar irradiance beyond the ultraviolet and infrared bands below and above 0.2 micrometers and 50 micrometers, respectively. On the other hand, pyranometers and pyrheliometers are developed to measure broadband shortwave irradiance from approximately 0.3 micrometers to 3 micrcometers, while the present photovoltaic cells are limited to approximately 0.3 micrometers to 1 micrometers. The broadband mismatch of ACR versus such radiometers causes discrepancy in radiometers' calibration methods that has not been discussed or addressed in the solar and atmospheric science literature. Pyrgeometers are also used for solar and atmospheric science applications and calibrated with traceability to consensus reference, yet calibrated during nighttime only, because no consensus reference has yet been established for the daytime longwave irradiance. This poster shows a method to measure the broadband IR irradiance in the direct solar beam from 3 micrometers to 50 micrometers, as first step that might be used to help develop calibration methods to address the mismatch between broadband ACR and shortwave radiometers, and the lack of a daytime reference for pyrgeometers. The irradiance was measured from sunrise to sunset for 5 days when the sun disk was cloudless; the irradiance varied from approximately 1 Wm-2 to 16 Wm-2 for solar zenith angle from 80 degres to 16 degrees respectively; estimated uncertainty is 1.5 Wm-2.

  11. Enhanced electrochemical etching of ion irradiated silicon by localized amorphization

    SciTech Connect (OSTI)

    Dang, Z. Y.; Breese, M. B. H.; Lin, Y.; Tok, E. S.; Vittone, E.

    2014-05-12

    A tailored distribution of ion induced defects in p-type silicon allows subsequent electrochemical anodization to be modified in various ways. Here we describe how a low level of lattice amorphization induced by ion irradiation influences anodization. First, it superposes a chemical etching effect, which is observable at high fluences as a reduced height of a micromachined component. Second, at lower fluences, it greatly enhances electrochemical anodization by allowing a hole diffusion current to flow to the exposed surface. We present an anodization model, which explains all observed effects produced by light ions such as helium and heavy ions such as cesium over a wide range of fluences and irradiation geometries.

  12. Effects of self-irradiation in plutonium alloys

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chung, B. W.; Lema, K. E.; Allen, P. G.

    2015-09-16

    In this paper, we present updated results of self-irradiation effects on 238Pu-enriched 239Pu alloys measured by immersion density, dilatometry, and tensile tests. We obtained the self-irradiation equivalent time of nearly 200 years, nearly 100 years longer than in our previous papers. At this extended aging, we find the rate of decrease in density has slowed significantly, stabilizing around 15.73 g/cc, without signs of void swelling. The volume expansion measured at 35°C also shows apparent saturation at less than 0.25%. Quasi-static tensile measurement still show gradual increase in the strength of plutonium alloys with age.

  13. Computation of glint, glare, and solar irradiance distribution

    SciTech Connect (OSTI)

    Ho, Clifford Kuofei; Khalsa, Siri Sahib Singh

    2015-08-11

    Described herein are technologies pertaining to computing the solar irradiance distribution on a surface of a receiver in a concentrating solar power system or glint/glare emitted from a reflective entity. At least one camera captures images of the Sun and the entity of interest, wherein the images have pluralities of pixels having respective pluralities of intensity values. Based upon the intensity values of the pixels in the respective images, the solar irradiance distribution on the surface of the entity or glint/glare corresponding to the entity is computed.

  14. Properties of solar gravity mode signals in total irradiance observations

    SciTech Connect (OSTI)

    Kroll, R.J.; Chen, J.; Hill, H.A.

    1988-01-01

    Further evidence has been found that a significant fraction of the gravity mode power density in the total irradiance observations appears in sidebands of classified eigenfrequencies. These sidebands whose amplitudes vary from year to year are interpreted as harmonics of the rotational frequencies of the nonuniform solar surface. These findings are for non axisymmetric modes and corroborate the findings of Kroll, Hill and Chen for axisymmetric modes. It is demonstrated the the generation of the sidebands lifts the usual restriction on the parity of the eigenfunctions for modes detectable in total irradiance observations. 14 refs.

  15. Distinct photoresponse in graphene induced by laser irradiation

    SciTech Connect (OSTI)

    Wang, Wen Hui; Nan, Hai Yan; Liu, Qi; Ni, Zhen Hua; Liang, Zheng; Yu, Zhi Hao; Liu, Feng Yuan; Wang, Xin Ran; Hu, Wei Da; Zhang, Wei

    2015-01-12

    The graphene-based photodetector with tunable p-p{sup +}-p junctions was fabricated through a simple laser irradiation process. Distinct photoresponse was observed at the graphene (G)-laser irradiated graphene (LIG) junction by scanning photocurrent measurements, and its magnitude can be modulated as a result of a positive correlation between the photocurrent and doping concentration in LIG region. Detailed investigation suggests that the photo-thermoelectric effect, instead of the photovoltaic effect, dominates the photocurrent generation at the G-LIG junctions. Such a simple and low-cost technique offers an alternative way for the fabrication of graphene-based optoelectronic devices.

  16. Fission product release from irradiated LWR fuel under accident conditions

    SciTech Connect (OSTI)

    Strain, R.V.; Sanecki, J.E.; Osborne, M.F.

    1984-01-01

    Fission product release from irradiated LWR fuel is being studied by heating fuel rod segments in flowing steam and an inert carrier gas to simulate accident conditions. Fuels with a range of irradiation histories are being subjected to several steam flow rates over a wide range of temperatures. Fission product release during each test is measured by gamma spectroscopy and by detailed examination of the collection apparatus after the test has been completed. These release results are complemented by a detailed posttest examination of samples of the fuel rod segment. Results of release measurements and fuel rod characterizations for tests at 1400 through 2000/sup 0/C are presented in this paper.

  17. Amorphization of nanocrystalline 3C-SiC irradiated with Si+ ions...

    Office of Scientific and Technical Information (OSTI)

    Amorphization of nanocrystalline 3C-SiC irradiated with Si+ ions Citation Details In-Document Search Title: Amorphization of nanocrystalline 3C-SiC irradiated with Si+ ions ...

  18. Bright x-ray sources from laser irradiation of foams with high...

    Office of Scientific and Technical Information (OSTI)

    Bright x-ray sources from laser irradiation of foams with high concentration of Ti Citation Details In-Document Search Title: Bright x-ray sources from laser irradiation of foams...

  19. Post Irradiation Capabilities at the Idaho National Laboratory

    SciTech Connect (OSTI)

    Schulthess, J.L.

    2011-08-01

    The U.S. Department of Energy (DOE) Office of Nuclear Energy (NE) oversees the research, development, and demonstration activities that ensure nuclear energy remains a viable energy option for the United States. Fuel and material development through fabrication, irradiation, and characterization play a significant role in accomplishing the research needed to support nuclear energy. All fuel and material development requires the understanding of irradiation effects on the fuel performance and relies on irradiation experiments ranging from tests aimed at targeted scientific questions to integral effects under representative and prototypic conditions. The DOE recently emphasized a solution-driven, goal-oriented, science-based approach to nuclear energy development. Nuclear power systems and materials were initially developed during the latter half of the 20th century and greatly facilitated by the United States ability and willingness to conduct large-scale experiments. Fifty-two research and test reactors with associated facilities for performing fabrication and pre and post irradiation examinations were constructed at what is now Idaho National Laboratory (INL), another 14 at Oak Ridge National Laboratory (ORNL), and a few more at other national laboratory sites. Building on the scientific advances of the last several decades, our understanding of fundamental nuclear science, improvements in computational platforms, and other tools now enable technological advancements with less reliance on large-scale experimentation.

  20. Fission gas retention and axial expansion of irradiated metallic fuel

    SciTech Connect (OSTI)

    Fenske, G.R.; Emerson, J.E.; Savoie, F.E.; Johanson, E.W.

    1986-05-01

    Out-of-reactor experiments utilizing direct electrical heating and infrared heating techniques were performed on irradiated metallic fuel. The results indicate accelerated expansion can occur during thermal transients and that the accelerated expansion is driven by retained fission gases. The results also demonstrate gas retention and, hence, expansion behavior is a function of axial position within the pin.

  1. Researchers Devise New Stress Test for Irradiated Materials

    Broader source: Energy.gov [DOE]

    How do you tell if materials are stressed-out? Conventional stress tests for irradiated materials require a significant amount of material, but a new nano-size technique can test the strength of materials using an infinitesimal amount. Learn more.

  2. THERMAL EVALUATION OF ALTERNATE SHIPPING CASK FOR IRRADIATED EXPERIMENTS

    SciTech Connect (OSTI)

    Donna Post Guillen

    2015-06-01

    Results of a thermal evaluation are provided for a new shipping cask under consideration for transporting irradiated experiments between the test reactor and post-irradiation examination (PIE) facilities. Most of the experiments will be irradiated in the Advanced Test Reactor (ATR) at Idaho National Laboratory (INL), then later shipped to the Hot Fuel Examination Facility (HFEF) located at the Materials and Fuels Complex for PIE. To date, the General Electric (GE)-2000 cask has been used to transport experiment payloads between these facilities. However, the availability of the GE-2000 cask to support future experiment shipping is uncertain. In addition, the internal cavity of the GE-2000 cask is too short to accommodate shipping the larger payloads. Therefore, an alternate shipping capability is being pursued. The Battelle Energy Alliance, LLC, Research Reactor (BRR) cask has been determined to be the best alternative to the GE-2000 cask. An evaluation of the thermal performance of the BRR cask is necessary before proceeding with fabrication of the newly designed cask hardware and the development of handling, shipping and transport procedures. This paper presents the results of the thermal evaluation of the BRR cask loaded with a representative set of fueled and non-fueled payloads. When analyzed with identical payloads, experiment temperatures were found to be lower with the BRR cask than with the GE-2000 cask. From a thermal standpoint, the BRR cask was found to be a suitable alternate to the GE-2000 cask for shipping irradiated experiment payloads.

  3. Irradiation performance of AGR-1 high temperature reactor fuel

    SciTech Connect (OSTI)

    Paul A. Demkowicz; John D. Hunn; Robert N. Morris; Charles A. Baldwin; Philip L. Winston; Jason M. Harp; Scott A. Ploger; Tyler Gerczak; Isabella J. van Rooyen; Fred C. Montgomery; Chinthaka M. Silva

    2014-10-01

    The AGR-1 experiment contained 72 low-enriched uranium oxide/uranium carbide TRISO-coated particle fuel compacts in six capsules irradiated to burnups of 11.2 to 19.5% FIMA, with zero TRISO coating failures detected during the irradiation. The irradiation performance of the fuelincluding the extent of fission product release and the evolution of kernel and coating microstructureswas evaluated based on detailed examination of the irradiation capsules, the fuel compacts, and individual particles. Fractional release of 110mAg from the fuel compacts was often significant, with capsule-average values ranging from 0.01 to 0.38. Analysis of silver release from individual compacts indicated that it was primarily dependent on fuel temperature history. Europium and strontium were released in small amounts through intact coatings, but were found to be significantly retained in the outer pyrocrabon and compact matrix. The capsule-average fractional release from the compacts was 110 4 to 510 4 for 154Eu and 810 7 to 310 5 for 90Sr. The average 134Cs release from compacts was <310 6 when all particles maintained intact SiC. An estimated four particles out of 2.98105 experienced partial cesium release due to SiC failure during the irradiation, driving 134Cs release in two capsules to approximately 10 5. Identification and characterization of these particles has provided unprecedented insight into the nature and causes of SiC coating failure in high-quality TRISO fuel. In general, changes in coating morphology were found to be dominated by the behavior of the buffer and inner pyrolytic carbon (IPyC), and infrequently observed SiC layer damage was usually related to cracks in the IPyC. Palladium attack of the SiC layer was relatively minor, except for the particles that released cesium during irradiation, where SiC corrosion was found adjacent to IPyC cracks. Palladium, silver, and uranium were found in the SiC layer of irradiated particles, and characterization of these elements within the SiC microstructure is the subject of ongoing focused study.

  4. Irradiation and annealing of p-type silicon carbide

    SciTech Connect (OSTI)

    Lebedev, Alexander A.; Bogdanova, Elena V.; Grigor'eva, Maria V.; Lebedev, Sergey P. [A.F. Ioffe Physical-Technical Institute, St. Petersburg, 194021 (Russian Federation); Kozlovski, Vitaly V. [St. Petersburg State Polytechnic University, St. Petersburg, 195251 (Russian Federation)

    2014-02-21

    The development of the technology of semiconductor devices based on silicon carbide and the beginning of their industrial manufacture have made increasingly topical studies of the radiation hardness of this material on the one hand and of the proton irradiation to form high-receptivity regions on the other hand. This paper reports on a study of the carrier removal rate (V{sub d}) in p-6H-SiC under irradiation with 8 MeV protons and of the conductivity restoration in radiation- compensated epitaxial layers of various p-type silicon carbide polytypes. V{sub d} was determined by analysis of capacitance-voltage characteristics and from results of Hall effect measurements. It was found that the complete compensation of samples with the initial value of Na - Nd ? 1.5 10{sup 18} cm{sup ?3} occurs at an irradiation dose of ?1.1 10{sup 16} cm{sup ?2}. It is shown that specific features of the sublimation layer SiC (compared to CVD layers) are clearly manifested upon the gamma and electron irradiation and are hardly noticeable under the proton and neutron irradiation. It was also found that the radiation-induced compensation of SiC is retained after its annealing at ?1000C. The conductivity is almost completely restored at T ? 1200C. This character of annealing of the radiation compensation is independent of a silicon carbide polytype and the starting doping level of the epitaxial layer. The complete annealing temperatures considerably exceed the working temperatures of SiC-based devices. It is shown that the radiation compensation is a promising method in the technology of high-temperature devices based on SiC.

  5. Microscopic analysis of irradiated AGR-1 coated particle fuel compacts

    SciTech Connect (OSTI)

    Scott Ploger; Paul Demkowicz; John Hunn; Robert Morris

    2012-10-01

    The AGR-1 experiment involved irradiation of 72 TRISO-coated particle fuel compacts to a peak burnup of 19.5% FIMA with no in-pile failures observed out of 3105 total particles. Irradiated AGR-1 fuel compacts have been cross-sectioned and analyzed with optical microscopy to characterize kernel, buffer, and coating behavior. Five compacts have been examined so far, spanning a range of irradiation conditions (burnup, fast fluence, and irradiation temperature) and including all four TRISO coating variations irradiated in the AGR-1 experiment. The cylindrical specimens were sectioned both transversely and longitudinally, then polished to expose between approximately 40-80 individual particles on each mount. The analysis focused primarily on kernel swelling and porosity, buffer densification and fracturing, buffer-IPyC debonding, and fractures in the IPyC and SiC layers. Characteristic morphologies have been identified, over 800 particles have been classified, and spatial distributions of particle types have been mapped. No significant spatial patterns were discovered in these cross sections. However, some trends were found between morphological types and certain behavioral aspects. Buffer fractures were found in approximately 23% of the particles, and these fractures often resulted in unconstrained kernel swelling into the open cavities. Fractured buffers and buffers that stayed bonded to IPyC layers appear related to larger pore size in kernels. Buffer-IPyC interface integrity evidently factored into initiation of rare IPyC fractures. Fractures through part of the SiC layer were found in only three particles, all in conjunction with IPyC-SiC debonding. Compiled results suggest that the deliberate coating fabrication variations influenced the frequencies of IPyC fractures, IPyC-SiC debonds, and SiC fractures.

  6. Characterization of the neutron irradiation system for use in the Low-Dose-Rate Irradiation Facility at Sandia National Laboratories.

    SciTech Connect (OSTI)

    Franco, Manuel,

    2014-08-01

    The objective of this work was to characterize the neutron irradiation system consisting of americium-241 beryllium (241AmBe) neutron sources placed in a polyethylene shielding for use at Sandia National Laboratories (SNL) Low Dose Rate Irradiation Facility (LDRIF). With a total activity of 0.3 TBq (9 Ci), the source consisted of three recycled 241AmBe sources of different activities that had been combined into a single source. The source in its polyethylene shielding will be used in neutron irradiation testing of components. The characterization of the source-shielding system was necessary to evaluate the radiation environment for future experiments. Characterization of the source was also necessary because the documentation for the three component sources and their relative alignment within the Special Form Capsule (SFC) was inadequate. The system consisting of the source and shielding was modeled using Monte Carlo N-Particle transport code (MCNP). The model was validated by benchmarking it against measurements using multiple techniques. To characterize the radiation fields over the full spatial geometry of the irradiation system, it was necessary to use a number of instruments of varying sensitivities. First, the computed photon radiography assisted in determining orientation of the component sources. With the capsule properly oriented inside the shielding, the neutron spectra were measured using a variety of techniques. A N-probe Microspec and a neutron Bubble Dosimeter Spectrometer (BDS) set were used to characterize the neutron spectra/field in several locations. In the third technique, neutron foil activation was used to ascertain the neutron spectra. A high purity germanium (HPGe) detector was used to characterize the photon spectrum. The experimentally measured spectra and the MCNP results compared well. Once the MCNP model was validated to an adequate level of confidence, parametric analyses was performed on the model to optimize for potential experimental configurations and neutron spectra for component irradiation. The final product of this work is a MCNP model validated by measurements, an overall understanding of neutron irradiation system including photon/neutron transport and effective dose rates throughout the system, and possible experimental configurations for future irradiation of components.

  7. AGR 3/4 Irradiation Test Final As Run Report

    SciTech Connect (OSTI)

    Collin, Blaise P.

    2015-06-01

    Several fuel and material irradiation experiments have been planned for the Idaho National Laboratory Advanced Reactor Technologies Technology Development Office Advanced Gas Reactor Fuel Development and Qualification Program (referred to as the INL ART TDO/AGR fuel program hereafter), which supports the development and qualification of tristructural-isotropic (TRISO) coated particle fuel for use in HTGRs. The goals of these experiments are to provide irradiation performance data to support fuel process development, qualify fuel for normal operating conditions, support development and validation of fuel performance and fission product transport models and codes, and provide irradiated fuel and materials for post irradiation examination and safety testing (INL 05/2015). AGR-3/4 combined the third and fourth in this series of planned experiments to test TRISO coated low enriched uranium (LEU) oxycarbide fuel. This combined experiment was intended to support the refinement of fission product transport models and to assess the effects of sweep gas impurities on fuel performance and fission product transport by irradiating designed-to-fail fuel particles and by measuring subsequent fission metal transport in fuel-compact matrix material and fuel-element graphite. The AGR 3/4 fuel test was successful in irradiating the fuel compacts to the burnup and fast fluence target ranges, considering the experiment was terminated short of its initial 400 EFPD target (Collin 2015). Out of the 48 AGR-3/4 compacts, 42 achieved the specified burnup of at least 6% fissions per initial heavy-metal atom (FIMA). Three capsules had a maximum fuel compact average burnup < 10% FIMA, one more than originally specified, and the maximum fuel compact average burnup was <19% FIMA for the remaining capsules, as specified. Fast neutron fluence fell in the expected range of 1.0 to 5.51025 n/m2 (E >0.18 MeV) for all compacts. In addition, the AGR-3/4 experiment was globally successful in keeping the temperature in the twelve capsules relatively flat in a range of temperatures suitable for the measurement of fission product diffusion in compact matrix and structural graphite materials.

  8. Irradiation of Metallic and Oxide Fuels for Actinide Transmutation in the ATR

    SciTech Connect (OSTI)

    MacLean, Heather J.; Hayes, Steven L.

    2007-07-01

    Metallic fuels containing minor actinides and rare earth additions have been fabricated and are prepared for irradiation in the ATR, scheduled to begin during the summer of 2007. Oxide fuels containing minor actinides are being fabricated and will be ready for irradiation in ATR, scheduled to begin during the summer of 2008. Fabrication and irradiation of these fuels will provide detailed studies of actinide transmutation in support of the Global Nuclear Energy Partnership. These fuel irradiations include new fuel compositions that have never before been tested. Results from these tests will provide fundamental data on fuel irradiation performance and will advance the state of knowledge for transmutation fuels. (authors)

  9. Microstructure and mechanical behavior of neutron irradiated ultrafine grained ferritic steel

    SciTech Connect (OSTI)

    Ahmad Alsabbagh; Apu Sarkar; Brandon Miller; Jatuporn Burns; Leah Squires; Douglas Porter; James I. Cole; K. L. Murty

    2014-10-01

    Neutron irradiation effects on ultra-fine grain (UFG) low carbon steel prepared by equal channel angular pressing (ECAP) has been examined. Counterpart samples with conventional grain (CG) sizes have been irradiated alongside with the UFG ones for comparison. Samples were irradiated in the Advanced Test Reactor (ATR) at Idaho National Laboratory (INL) to 1.24 dpa. Atom probe tomography revealed manganese, silicon-enriched clusters in both ECAP and CG steel after neutron irradiation. X-ray quantitative analysis showed that dislocation density in CG increased after irradiation. However, no significant change was observed in UFG steel revealing better radiation tolerance.

  10. Recent Accomplishments in the Irradiation Testing of Engineering-Scale Monolithic Fuel Specimens

    SciTech Connect (OSTI)

    N.E. Woolstenhulme; D.M. Wachs; M.K. Meyer; H.W. Glunz; R.B. Nielson

    2012-10-01

    The US fuel development team is focused on qualification and demonstration of the uranium-molybdenum monolithic fuel including irradiation testing of engineering-scale specimens. The team has recently accomplished the successful irradiation of the first monolithic multi-plate fuel element assembly within the AFIP-7 campaign. The AFIP-6 MKII campaign, while somewhat truncated by hardware challenges, exhibited successful irradiation of a large-scale monolithic specimen under extreme irradiation conditions. The channel gap and ultrasonic data are presented for AFIP-7 and AFIP-6 MKII, respectively. Finally, design concepts are summarized for future irradiations such as the base fuel demonstration and design demonstration experiment campaigns.

  11. Origins of ion irradiation-induced Ga nanoparticle motion on GaAs surfaces

    SciTech Connect (OSTI)

    Kang, M.; Wu, J. H.; Chen, H. Y.; Thornton, K.; Goldman, R. S. [Department of Materials Science and Engineering, University of Michigan, Ann Arbor, Michigan 48109-2136 (United States)] [Department of Materials Science and Engineering, University of Michigan, Ann Arbor, Michigan 48109-2136 (United States); Sofferman, D. L. [Department of Materials Science and Engineering, University of Michigan, Ann Arbor, Michigan 48109-2136 (United States) [Department of Materials Science and Engineering, University of Michigan, Ann Arbor, Michigan 48109-2136 (United States); Department of Physics, Adelphi University, Garden City, New York 11530-0701 (United States); Beskin, I. [Department of Physics, University of Michigan, Ann Arbor, Michigan 48109-1040 (United States)] [Department of Physics, University of Michigan, Ann Arbor, Michigan 48109-1040 (United States)

    2013-08-12

    We have examined the origins of ion irradiation-induced nanoparticle (NP) motion. Focused-ion-beam irradiation of GaAs surfaces induces random walks of Ga NPs, which are biased in the direction opposite to that of ion beam scanning. Although the instantaneous NP velocities are constant, the NP drift velocities are dependent on the off-normal irradiation angle, likely due to a difference in surface non-stoichiometry induced by the irradiation angle dependence of the sputtering yield. It is hypothesized that the random walks are initiated by ion irradiation-induced thermal fluctuations, with biasing driven by anisotropic mass transport.

  12. Characteristics of irradiation creep in the first wall of a fusion reactor

    SciTech Connect (OSTI)

    Coghlan, W.A.; Mansur, L.K.

    1981-01-01

    A number of significant differences in the irradiation environment of a fusion reactor are expected with respect to the fission reactor irradiation environment. These differences are expected to affect the characteristics of irradiation creep in the fusion reactor. Special conditions of importance are identified as the (1) large number of defects produced per pka, (2) high helium production rate, (3) cyclic operation, (4) unique stress histories, and (5) low temperature operations. Existing experimental data from the fission reactor environment is analyzed to shed light on irradiation creep under fusion conditions. Theoretical considerations are used to deduce additional characteristics of irradiation creep in the fusion reactor environment for which no experimental data are available.

  13. Deficiency in Homologous Recombination Renders Mammalian Cells More Sensitive to Proton Versus Photon Irradiation

    SciTech Connect (OSTI)

    Grosse, Nicole; Fontana, Andrea O. [Laboratory for Molecular Radiobiology, University Hospital Zurich, Zurich (Switzerland); Hug, Eugen B.; Lomax, Antony; Coray, Adolf [Center for Proton Therapy, Paul Scherrer Institute, Villigen (Switzerland); Augsburger, Marc [Laboratory for Molecular Radiobiology, University Hospital Zurich, Zurich (Switzerland); Paganetti, Harald [Department of Radiation Oncology, Massachusetts General Hospital and Harvard Medical School, Boston, Massachusetts (United States); Sartori, Alessandro A. [Institute of Molecular Cancer Research, University of Zurich, Zurich (Switzerland); Pruschy, Martin, E-mail: martin.pruschy@usz.ch [Laboratory for Molecular Radiobiology, University Hospital Zurich, Zurich (Switzerland)

    2014-01-01

    Purpose: To investigate the impact of the 2 major DNA repair machineries on cellular survival in response to irradiation with the 2 types of ionizing radiation. Methods and Materials: The DNA repair and cell survival endpoints in wild-type, homologous recombination (HR)-deficient, and nonhomologous end-joining-deficient cells were analyzed after irradiation with clinically relevant, low-linear energy transfer (LET) protons and 200-keV photons. Results: All cell lines were more sensitive to proton irradiation compared with photon irradiation, despite no differences in the induction of DNA breaks. Interestingly, HR-deficient cells and wild-type cells with small interfering RNA-down-regulated Rad51 were markedly hypersensitive to proton irradiation, resulting in an increased relative biological effectiveness in comparison with the relative biological effectiveness determined in wild-type cells. In contrast, lack of nonhomologous end-joining did not result in hypersensitivity toward proton irradiation. Repair kinetics of DNA damage in wild-type cells were equal after both types of irradiation, although proton irradiation resulted in more lethal chromosomal aberrations. Finally, repair kinetics in HR-deficient cells were significantly delayed after proton irradiation, with elevated amounts of residual ?H2AX foci after irradiation. Conclusion: Our data indicate a differential quality of DNA damage by proton versus photon irradiation, with a specific requirement for homologous recombination for DNA repair and enhanced cell survival. This has potential relevance for clinical stratification of patients carrying mutations in the DNA damage response pathways.

  14. Detection of irradiated spices using photo-stimulated luminescence technique (PSL)

    SciTech Connect (OSTI)

    Ramli, Ros Anita Ahmad; Yasir, Muhamad Samudi; Othman, Zainon; Abdullah, Wan Saffiey Wan

    2014-09-03

    Photo-stimulated luminescence (PSL) technique was applied to detect irradiated black pepper (Piper nigrum), cinnamon (Cinnamomum verum) and turmeric (Curcuma longa) after dark storage for 1 day, 3 and 6 months. Using screening and calibrated PSL, all samples were correctly discriminated between non-irradiated and spices irradiated with doses 1, 5 and 10 kGy. The PSL photon counts (PCs) of irradiated spices increased with increasing dose, with turmeric showing highest sensitivity index to irradiation compared to black pepper and cinnamon. The differences in response are possibly attributed to the varying quantity and quality of silicate minerals present in each spice sample. PSL signals of all irradiated samples reduced after 3 and 6 months storage. The results of this study provide a useful database on the applicability of PSL technique for the detection of Malaysian irradiated spices.

  15. He ion irradiation damage to Al/Nb multilayers

    SciTech Connect (OSTI)

    Misra, Amit; Li, Nan; Martin, M S; Anderoglu, Osman; Shao, L; Wang, H; Zhang, X

    2009-01-01

    We investigated the evolution of microstructure and mechanical properties of sputter-deposited Al/Nb multilayers with individual layer thickness, h, of 1-200 nm, subjected to helium ion irradiations: 100 keV He{sup +} ions with a dose of 6 x 10{sup 16}/cm{sup 2}. Helium bubbles, 1-2 nm in diameter, were observed. When h is greater than 25 nm, hardnesses of irradiated multilayers barely change, whereas radiation hardening is more significant at smaller h. Transmission electron microscopy and scanning transmission electron microscopy studies reveal the formation of a thin layer of Nb{sub 3}Al intermetallic along the Al/Nb interface as a consequence of radiation induced intermixing. The dependence of radiation hardening on h is interpreted by using a composite model considering the formation of the hard Nb{sub 3}Al intermetallic layer.

  16. Production of sodium-22 from proton irradiated aluminum

    DOE Patents [OSTI]

    Taylor, Wayne A. (Los Alamos, NM); Heaton, Richard C. (Los Alamos, NM); Jamriska, David J. (Los Alamos, NM)

    1996-01-01

    A process for selective separation of sodium-22 from a proton irradiated minum target including dissolving a proton irradiated aluminum target in hydrochloric acid to form a first solution including aluminum ions and sodium ions, separating a portion of the aluminum ions from the first solution by crystallization of an aluminum salt, contacting the remaining first solution with an anion exchange resin whereby ions selected from the group consisting of iron and copper are selectively absorbed by the anion exchange resin while aluminum ions and sodium ions remain in solution, contacting the solution with an cation exchange resin whereby aluminum ions and sodium ions are adsorbed by the cation exchange resin, and, contacting the cation exchange resin with an acid solution capable of selectively separating the adsorbed sodium ions from the cation exchange resin while aluminum ions remain adsorbed on the cation exchange resin is disclosed.

  17. Conceptual Design Report for the Irradiated Materials Characterization Laboratory (IMCL)

    SciTech Connect (OSTI)

    Stephanie Austad

    2010-06-01

    This document describes the design at a conceptual level for the Irradiated Materials Characterization Laboratory (IMCL) to be located at the Materials and Fuels Complex (MFC) at the Idaho National Laboratory (INL). The IMCL is an 11,000-ft2, Hazard Category-2 nuclear facility that is designed for use as a state of the-art nuclear facility for the purpose of hands-on and remote handling, characterization, and examination of irradiated and nonirradiated nuclear material samples. The IMCL will accommodate a series of future, modular, and reconfigurable instrument enclosures or caves. To provide a bounding design basis envelope for the facility-provided space and infrastructure, an instrument enclosure or cave configuration was developed and is described in some detail. However, the future instrument enclosures may be modular, integral with the instrument, or reconfigurable to enable various characterization environments to be configured as changes in demand occur. They are not provided as part of the facility.

  18. Advanced Post-Irradiation Examination Capabilities Alternatives Analysis Report

    SciTech Connect (OSTI)

    Jeff Bryan; Bill Landman; Porter Hill

    2012-12-01

    An alternatives analysis was performed for the Advanced Post-Irradiation Capabilities (APIEC) project in accordance with the U.S. Department of Energy (DOE) Order DOE O 413.3B, “Program and Project Management for the Acquisition of Capital Assets”. The Alternatives Analysis considered six major alternatives: ? No Action ? Modify Existing DOE Facilities – capabilities distributed among multiple locations ? Modify Existing DOE Facilities – capabilities consolidated at a few locations ? Construct New Facility ? Commercial Partnership ? International Partnerships Based on the alternatives analysis documented herein, it is recommended to DOE that the advanced post-irradiation examination capabilities be provided by a new facility constructed at the Materials and Fuels Complex at the Idaho National Laboratory.

  19. Ceramographic Examinations of Irradiated AGR-1 Fuel Compacts

    SciTech Connect (OSTI)

    Paul Demkowicz; Scott Ploger; John Hunn; Jay S. Kehn

    2012-09-01

    The AGR 1 experiment involved irradiating 72 cylindrical fuel compacts containing tri-structural isotropic (TRISO)-coated particles to a peak burnup of 19.5% fissions per initial metal atom with no in-pile failures observed out of almost 300,000 particles. Six irradiated AGR 1 fuel compacts were selected for microscopy that span a range of irradiation conditions (temperature, burnup, and fast fluence). These six compacts also included all four TRISO coating variations irradiated in the AGR experiment. The six compacts were cross-sectioned both transversely and longitudinally, mounted, ground, and polished after development of careful techniques for preserving particle structures against preparation damage. From 36 to 79 particles within each cross section were exposed near enough to midplane for optical microscopy of kernel, buffer, and coating behavior. The microstructural analysis focused on kernel swelling and porosity, buffer densification and fracture, debonding between the buffer and inner pyrolytic carbon (IPyC) layers, and fractures in the IPyC and SiC layers. Three basic particle morphologies were established according to the extent of bonding between the buffer and IPyC layers: complete debonding along the interface (Type A), no debonding along the interface (Type B), and partial debonding (Type AB). These basic morphologies were subdivided according to whether the buffer stayed intact or fractured. The resulting six characteristic morphologies were used to classify particles within each cross section, but no spatial patterns were clearly observed in any of the cross-sectional morphology maps. Although positions of particle types appeared random within compacts, examining a total of 931 classified particles allowed other relationships among morphological types to be established.

  20. Discrepancies in Shortwave Diffuse Measured and Modeled Irradiances in Antarctica

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Discrepancies in Shortwave Diffuse Measured and Modeled Irradiances in Antarctica A. Payton, P. Ricchiazzi, and C. Gautier University of California Santa Barbara, California D. Lubin Scripps Scripps Institution of Oceanography La Jolla, California Introduction Measurements of clear-sky shortwave (SW) radiation at the surface show discrepancies between measurements and model simulations, but only for certain measurements across time and space. Most of the observations entail broadband

  1. Center for Materials at Irradiation and Mechanical Extremes: Los National

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Alamos Laboratory Nastasi image of George Gray Contact Information Professor, University of Nebraska-Lincoln Email: Mike Nastasi Phone: 402-472-3852 Bio Education Ph.D., Materials Science and Engineering, Cornell University, 1986 M.S., Materials Science and Engineering, Cornell University, 1983 B.S., Materials Science and Engineering, Cornell University, 1981 Research and Professional Experience Director, Center for Materials at Irradiation and Mechanical Extremes, 2009-present Nano

  2. Center for Materials at Irradiation and Mechanical Extremes: Los Alamos

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    National Laboratory Traditional structural materials degrade and fail under intense irradiation, but certain nanocomposites contain high volume fractions of "super sink" interfaces that allow these materials to self-heal.Understanding how radiation damage is trapped and removed at such interfaces will help in designing a new class of radiation-tolerant materials that would make future nuclear reactors maximally safe, sustainable, and efficient. This (movie/figure) shows the

  3. Featured Projects: Center for Materials at Irradiation and Mechanical

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Extremes: Los Alamos Lab About CMIME The Center for Materials at Irradiation and Mechanical Extremes (CMIME) is a Department of Energy (DOE) Energy Frontier Research Center (EFRC) designed to understand, at the atomic scale, the behavior of materials subject to extreme radiation doses and mechanical stress in order to synthesize new materials that can tolerate such conditions. It is a collaborative effort led by Los Alamos National Laboratory (LANL) that includes the Massachusetts Institute

  4. Improved Method to Measure Glare and Reflected Solar Irradiance - Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Innovation Portal Solar Thermal Solar Thermal Industrial Technologies Industrial Technologies Energy Analysis Energy Analysis Early Stage R&D Early Stage R&D Find More Like This Return to Search Improved Method to Measure Glare and Reflected Solar Irradiance Sandia National Laboratories Contact SNL About This Technology Publications: PDF Document Publication Market Sheet (767 KB) Solar glare from aerial view Solar glare from aerial view Typical solar glare Typical solar glare

  5. Updated FY12 Ceramic Fuels Irradiation Test Plan

    SciTech Connect (OSTI)

    Nelson, Andrew T.

    2012-05-24

    The Fuel Cycle Research and Development program is currently devoting resources to study of numerous fuel types with the aim of furthering understanding applicable to a range of reactors and fuel cycles. In FY11, effort within the ceramic fuels campaign focused on planning and preparation for a series of rabbit irradiations to be conducted at the High Flux Isotope Reactor located at Oak Ridge National Laboratory. The emphasis of these planned tests was to study the evolution of thermal conductivity in uranium dioxide and derivative compositions as a function of damage induced by neutron damage. Current fiscal realities have resulted in a scenario where completion of the planned rabbit irradiations is unlikely. Possibilities for execution of irradiation testing within the ceramic fuels campaign in the next several years will thus likely be restricted to avenues where strong synergies exist both within and outside the Fuel Cycle Research and Development program. Opportunities to augment the interests and needs of modeling, advanced characterization, and other campaigns present the most likely avenues for further work. These possibilities will be pursued with the hope of securing future funding. Utilization of synthetic microstructures prepared to better understand the most relevant actors encountered during irradiation of ceramic fuels thus represents the ceramic fuel campaign's most efficient means to enhance understanding of fuel response to burnup. This approach offers many of the favorable attributes embraced by the Separate Effects Testing paradigm, namely production of samples suitable to study specific, isolated phenomena. The recent success of xenon-imbedded thick films is representative of this approach. In the coming years, this strategy will be expanded to address a wider range of problems in conjunction with use of national user facilities novel characterization techniques to best utilize programmatic resources to support a science-based research program.

  6. Center for Materials at Irradiation and Mechanical Extremes: Los Alamos

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    National Laboratory Others Participants Summer School Contacts Project Office Director Amit Misra (505) 667-9860 Co-Director Irene J. Beyerlein (505) 665-2231 Administrator Linda Chavez (505) 665-2266 cmime@lanl.gov Resources About CMIME Documents Employment Opportunities News & Highlights | Archive Related EFRC News Upcoming Events | Archive CMIME Featured Projects image for movie Irradiation Extremes Thrust The movie shows our molecular dynamics simulation of a collision cascade near

  7. Method for improving performance of irradiated structural materials

    DOE Patents [OSTI]

    Megusar, Janez (Belmont, MA); Harling, Otto K. (Hingham, MA); Grant, Nicholas J. (Winchester, MA)

    1989-01-01

    Method for extending service life of nuclear reactor components prepared from ductile, high strength crystalline alloys obtained by devitrification of metallic glasses. Two variations of the method are described: (1) cycling the temperature of the nuclear reactor between the operating temperature which leads to irradiation damage and a l The U.S. Government has rights in this invention by virtue of Department of Energy, Office of Fusion Energy, Grant No. DE-AC02-78ER-10107.

  8. Toluene nitration in irradiated nitric acid and nitrite solution

    SciTech Connect (OSTI)

    Gracy Elias; Bruce J. Mincher; Stephen P. Mezyk; Jim Muller; Leigh R. Martin

    2011-04-01

    The kinetics, mechanisms, and stable products produced for the aryl alkyl mild ortho-para director - toluene, in irradiated nitric acid and neutral nitrite solutions were investigated using ?, and pulse radiolysis. Electron pulse radiolysis was used to determine the bimolecular rate constants for the reaction of toluene with different transient species produced by irradiation. HPLC with UV detection was primarily used to assess the stable reaction products. GC-MS and LC-MS were used to confirm the results from HPLC. Free-radical nitration reaction products were found in irradiated acidic and neutral media. In acidic medium, the ring substitution and side chain substitution and oxidation produced different nitro products. In ring substitution, nitrogen oxide radicals were added mainly to hydroxyl radical-produced cyclohexadienyl radical, and in side chain substitution they were added to the carbon-centered benzyl radical produced by H-atom abstraction. In neutral nitrite toluene solution, radiolytic ring nitration products approached a statistically random distribution, suggesting a free-radical reaction involving addition of the NO2 radical.

  9. IRRADIATION PERFORMANCE OF U-Mo MONOLITHIC FUEL

    SciTech Connect (OSTI)

    M.K. Meyer; J. Gan; J.-F. Jue; D.D. Keiser; E. Perez; A. Robinson; D.M. Wachs; N. Woolstenhulme; G.L. Hofman; Y.-S. Kim

    2014-04-01

    High-performance research reactors require fuel that operates at high specific power to high fission density, but at relatively low temperatures. Research reactor fuels are designed for efficient heat rejection, and are composed of assemblies of thin-plates clad in aluminum alloy. The development of low-enriched fuels to replace high-enriched fuels for these reactors requires a substantially increased uranium density in the fuel to offset the decrease in enrichment. Very few fuel phases have been identified that have the required combination of very-high uranium density and stable fuel behavior at high burnup. UMo alloys represent the best known tradeoff in these properties. Testing of aluminum matrix U-Mo aluminum matrix dispersion fuel revealed a pattern of breakaway swelling behavior at intermediate burnup, related to the formation of a molybdenum stabilized high aluminum intermetallic phase that forms during irradiation. In the case of monolithic fuel, this issue was addressed by eliminating, as much as possible, the interfacial area between U-Mo and aluminum. Based on scoping irradiation test data, a fuel plate system composed of solid U-10Mo fuel meat, a zirconium diffusion barrier, and Al6061 cladding was selected for development. Developmental testing of this fuel system indicates that it meets core criteria for fuel qualification, including stable and predictable swelling behavior, mechanical integrity to high burnup, and geometric stability. In addition, the fuel exhibits robust behavior during power-cooling mismatch events under irradiation at high power.

  10. Solar Radiometric Data Quality Assessment of SIRS, SKYRAD and GNDRAD Measurements (Poster)

    SciTech Connect (OSTI)

    Habte, A.; Stoffel, T.; Reda, I.; Wilcox, S.; Kutchenreiter, M.; Gotseff, P.; Anderberg, M.

    2014-03-01

    Solar radiation is the driving force for the earth's weather and climate. Understanding the elements of this dynamic energy balance requires accurate measurements of broadband solar irradiance. Since the mid-1990's the ARM Program has deployed pyrheliometers and pyranometers for the measurement of direct normal irradiance (DNI), global horizontal irradiance (GHI), diffuse horizontal irradiance (DHI), and upwelling shortwave (US) radiation at permanent and mobile field research sites. This poster summarizes the basis for assessing the broadband solar radiation data available from the SIRS, SKYRAD, and GNDRAD measurement systems and provides examples of data inspections.

  11. Calibrating Pyrgeometers Outdoors Independent from the Reference Value of the Atmospheric Longwave Irradiance

    SciTech Connect (OSTI)

    Reda, I.; Hickey, J. R.; Grobner, J.; Andreas, A.; Stoffel, T.

    2006-08-01

    In this article, we describe a method for the calibration of thermopile pyrgeometers in the absence of a reference for measurement of atmospheric longwave irradiance. This is referred to as the incoming longwave irradiance in this article. The method is based on an indoor calibration using a low-temperature blackbody source to obtain the calibration coefficients that determine the pyrgeometer's radiation characteristics. From these coefficients the outgoing irradiance of the pyrgeometer can be calculated. The pyrgeometer is then installed outdoors on an aluminum plate that is connected to a circulating temperature bath. By adjusting the temperature bath to the approximate value of the effective sky temperature, the pyrgeometer's body temperature is lowered changing the pyrgeometer's thermopile output. If the incoming longwave irradiance is stable, the slope of the outgoing irradiance versus the pyrgeometer's thermopile output is the outdoor net irradiance responsivity (RSnet), independent of the absolute value of the atmospheric longwave irradiance. The indoor calibration coefficients and the outdoor RSnet are then used in the pyrgeometer equation to calculate the incoming longwave irradiance. To evaluate this method, the calculated irradiance using the derived coefficients was compared to the irradiance measured using a pyrgeometer with direct traceability to the World Infrared Standard Group (WISG). This is maintained at the Physikalisch-Meteorologisches Observatorium Davos, World Radiation Center, Switzerland. Based on results from four pyrgeometers calibrations, this method suggests measurement agreement with the WISG to within +/- 3 W/m2 for all sky conditions.

  12. Evaluating Solar Resource Data Obtained from Multiple Radiometers Deployed at the National Renewable Energy Laboratory: Preprint

    SciTech Connect (OSTI)

    Habte, A.; Sengupta, M.; Andreas, A.; Wilcox, S.; Stoffel, T.

    2014-09-01

    Solar radiation resource measurements from radiometers are used to predict and evaluate the performance of photovoltaic and concentrating solar power systems, validate satellite-based models for estimating solar resources, and advance research in solar forecasting and climate change. This study analyzes the performance of various commercially available radiometers used for measuring global horizontal irradiances (GHI) and direct normal irradiances (DNI). These include pyranometers, pyrheliometers, rotating shadowband irradiometers, and a pyranometer with a shading ring deployed at the National Renewable Energy Laboratory's Solar Radiation Research Laboratory (SRRL). The radiometers in this study were deployed for one year (from April 1, 2011, through March 31, 2012) and compared to measurements from radiometers with the lowest values of estimated measurement uncertainties for producing reference GHI and DNI.

  13. Irradiation of commercial, high-Tc superconducting tape for potential fusion applications: electromagnetic transport properties

    SciTech Connect (OSTI)

    Aytug, Tolga [ORNL; Gapud, Albert A. [University of South Alabama, Mobile; List III, Frederick Alyious [ORNL; Leonard, Keith J [ORNL; Rupich, Marty [American Superconductor Corporation, Westborough, MA; Zhang, Yanwen [ORNL; Greenwood, N T [University of South Alabama, Mobile; Alexander, J A [University of South Alabama, Mobile; Khan, A [University of South Alabama, Mobile

    2015-01-01

    Effects of low dose irradiation on the electrical transport current properties of commercially available high-temperature superconducting, coated-conductor tapes were investigated, in view of potential applications in the irradiative environment of fusion reactors. Three different tapes, each with unique as-grown flux-pinning structures, were irradiated with Au and Ni ions at energies that provide a range of damage effects, with accumulated damage levels near that expected for conductors in a fusion reactor environment. Measurements using transport current determined the pre- and post-irradiation resistivity, critical current density, and pinning force density, yielding critical temperatures, irreversibility lines, and inferred vortex creep rates. Results show that at the irradiation damage levels tested, any detriment to as-grown pre-irradiation properties is modest; indeed in one case already-superior pinning forces are enhanced, leading to higher critical currents.

  14. ARM Multi-Filter Rotating Shadowband Radiometer (MFRSR): irradiances

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Hodges, Gary

    1993-07-04

    The multifilter rotating shadowband radiometer (MFRSR) takes spectral measurements of direct normal, diffuse horizontal and total horizontal solar irradiances. These measurements are at nominal wavelengths of 415, 500, 615, 673, 870, and 940 nm. The measurements are made at a user-specified time interval, usually about one minute or less. The sampling rate for the Atmospheric Radiation Measurement (ARM) Climate Research Facility MFRSRs is 20 seconds. From such measurements, one may infer the atmosphere's optical depth at the wavelengths mentioned above. In turn, these optical depths may be used to derive information about the column abundances of ozone and water vapor (Michalsky et al. 1995), as well as aerosol (Michalsky et al. 1994) and other atmospheric constituents. A silicon detector is also part of the MFRSR. This detector provides a measure of the broadband direct normal, diffuse horizontal and total horizontal solar irradiances. A MFRSR head that is mounted to look vertically downward can measure upwelling spectral irradiances. In the ARM system, this instrument is called a multifilter radiometer (MFR). At the Southern Great Plains (SGP) there are two MFRs; one mounted at the 10-m height and the other at 25 m. At the North Slope of Alaska (NSA) sites, the MFRs are mounted at 10 m. MFRSR heads are also used to measure normal incidence radiation by mounting on a solar tracking device. These are referred to as normal incidence multi-filter radiometers (NIMFRs) and are located at the SGP and NSA sites. Another specialized use for the MFRSR is the narrow field of view (NFOV) instrument located at SGP. The NFOV is a ground-based radiometer (MFRSR head) that looks straight up.

  15. UNDERSTANDING TRENDS ASSOCIATED WITH CLOUDS IN IRRADIATED EXOPLANETS

    SciTech Connect (OSTI)

    Heng, Kevin; Demory, Brice-Olivier E-mail: demory@mit.edu

    2013-11-10

    Unlike previously explored relationships between the properties of hot Jovian atmospheres, the geometric albedo and the incident stellar flux do not exhibit a clear correlation, as revealed by our re-analysis of Q0-Q14 Kepler data. If the albedo is primarily associated with the presence of clouds in these irradiated atmospheres, a holistic modeling approach needs to relate the following properties: the strength of stellar irradiation (and hence the strength and depth of atmospheric circulation), the geometric albedo (which controls both the fraction of starlight absorbed and the pressure level at which it is predominantly absorbed), and the properties of the embedded cloud particles (which determine the albedo). The anticipated diversity in cloud properties renders any correlation between the geometric albedo and the stellar flux weak and characterized by considerable scatter. In the limit of vertically uniform populations of scatterers and absorbers, we use an analytical model and scaling relations to relate the temperature-pressure profile of an irradiated atmosphere and the photon deposition layer and to estimate whether a cloud particle will be lofted by atmospheric circulation. We derive an analytical formula for computing the albedo spectrum in terms of the cloud properties, which we compare to the measured albedo spectrum of HD 189733b by Evans et al. Furthermore, we show that whether an optical phase curve is flat or sinusoidal depends on whether the particles are small or large as defined by the Knudsen number. This may be an explanation for why Kepler-7b exhibits evidence for the longitudinal variation in abundance of condensates, while Kepler-12b shows no evidence for the presence of condensates despite the incident stellar flux being similar for both exoplanets. We include an 'observer's cookbook' for deciphering various scenarios associated with the optical phase curve, the peak offset of the infrared phase curve, and the geometric albedo.

  16. ARM Multi-Filter Rotating Shadowband Radiometer (MFRSR): irradiances

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Hodges, Gary

    The multifilter rotating shadowband radiometer (MFRSR) takes spectral measurements of direct normal, diffuse horizontal and total horizontal solar irradiances. These measurements are at nominal wavelengths of 415, 500, 615, 673, 870, and 940 nm. The measurements are made at a user-specified time interval, usually about one minute or less. The sampling rate for the Atmospheric Radiation Measurement (ARM) Climate Research Facility MFRSRs is 20 seconds. From such measurements, one may infer the atmosphere's optical depth at the wavelengths mentioned above. In turn, these optical depths may be used to derive information about the column abundances of ozone and water vapor (Michalsky et al. 1995), as well as aerosol (Michalsky et al. 1994) and other atmospheric constituents. A silicon detector is also part of the MFRSR. This detector provides a measure of the broadband direct normal, diffuse horizontal and total horizontal solar irradiances. A MFRSR head that is mounted to look vertically downward can measure upwelling spectral irradiances. In the ARM system, this instrument is called a multifilter radiometer (MFR). At the Southern Great Plains (SGP) there are two MFRs; one mounted at the 10-m height and the other at 25 m. At the North Slope of Alaska (NSA) sites, the MFRs are mounted at 10 m. MFRSR heads are also used to measure normal incidence radiation by mounting on a solar tracking device. These are referred to as normal incidence multi-filter radiometers (NIMFRs) and are located at the SGP and NSA sites. Another specialized use for the MFRSR is the narrow field of view (NFOV) instrument located at SGP. The NFOV is a ground-based radiometer (MFRSR head) that looks straight up.

  17. Dosimetry in Thermal Neutron Irradiation Facility at BMRR

    SciTech Connect (OSTI)

    Hu, J. P.; Holden, N. E.; Reciniello, R. N.

    2014-05-23

    Radiation dosimetry for Neutron Capture Therapy (NCT) has been performed since 1959 at Thermal Neutron Irradiation Facility (TNIF) of the three-megawatt light-water cooled Brookhaven Medical Research Reactor (BMRR). In the early 1990s when more effective drug carriers were developed for NCT, in which the eye melanoma and brain tumors in rats were irradiated in situ, extensive clinical trials of small animals began using a focused thermal neutron beam. To improve the dosimetry at irradiation facility, a series of innovative designs and major modifications made to enhance the beam intensity and to ease the experimental sampling at BMRR were performed; including (1) in-core fuel addition to increase source strength and balance flux of neutrons towards two ports, (2) out of core moderator remodeling, done by replacing thicker D2O tanks at graphite-shutter interfacial areas, to expedite neutron thermalization, (3) beam shutter upgrade to reduce strayed neutrons and gamma dose, (4) beam collimator redesign to optimize the beam flux versus dose for animal treatment, (5) beam port shielding installation around the shutter opening area (lithium-6 enriched polyester-resin in boxes, attached with polyethylene plates) to reduce prompt gamma and fast neutron doses, (6) sample holder repositioning to optimize angle versus distance for a single organ or whole body irradiation, and (7) holder wall buildup with neutron reflector materials to increase dose and dose rate from scattered thermal neutrons. During the facility upgrade, reactor dosimetry was conducted using thermoluminescent dosimeters TLD for gamma dose estimate, using ion chambers to confirm fast neutron and gamma dose rate, and by the activation of gold-foils with and without cadmium-covers, for fast and thermal neutron flux determination. Based on the combined effect from the size and depth of tumor cells and the location and geometry of dosimeters, the measured flux from cadmium-difference method was 4 - 7 % lower than the statistical mean derived from the Monte-Carlo modeling (5% uncertainty). The dose rate measured by ion chambers was 6 - 10 % lower than the output tallies (7% uncertainty). The detailed dosimetry that was performed at the TNIF for the NCT will be described.

  18. Portable instrument for inspecting irradiated nuclear fuel assemblies

    DOE Patents [OSTI]

    Nicholson, Nicholas (Los Alamos, NM); Dowdy, Edward J. (Los Alamos, NM); Holt, David M. (Los Alamos, NM); Stump, Jr., Charles J. (Santa Fe, NM)

    1985-01-01

    A portable instrument for measuring induced Cerenkov radiation associated with irradiated nuclear fuel assemblies in a water-filled storage pond is disclosed. The instrument includes a photomultiplier tube and an image intensifier which are operable in parallel and simultaneously by means of a field lens assembly and an associated beam splitter. The image intensifier permits an operator to aim and focus the apparatus on a submerged fuel assembly. Once the instrument is aimed and focused, an illumination reading can be obtained with the photomultiplier tube. The instrument includes a lens cap with a carbon-14/phosphor light source for calibrating the apparatus in the field.

  19. Effect of gamma irradiation on electrical properties of Cu nanowires

    SciTech Connect (OSTI)

    Rana, Pallavi Gehlawat, Devender Chauhan, R. P.

    2014-04-24

    Metallic nanowires are of great interest due to their unique electrical, optical, chemical and magnetic properties. Characterization and explanations of electronic properties of nanowires are extremely important due to their potential applications in the field of nanoelectronics and optoelectronics. In the present study, we synthesized the copper nanowires of different diameters (80nm, 100nm and 200nm) and exposed them with gamma rays of 100 KGy and 150 KGy doses. The I-V characteristics of different diameter of Cu nanowires before and after the irradiation were recorded.

  20. Irradiation creep of nano-powder sintered silicon carbide at low neutron fluences

    SciTech Connect (OSTI)

    Koyanagi, Takaaki; Shimoda, Kazuya; Kondo, Sosuke; Hinoki, Tatsuya; Ozawa, Kazumi; Katoh, Yutai

    2014-12-01

    The irradiation creep behavior of nano-powder sintered silicon carbide was investigated using the bend stress relaxation method under neutron irradiation up to 1.9 dpa. The creep deformation was observed at all temperatures ranging from 380 to 1180 C mainly from the irradiation creep but with the increasing contributions from the thermal creep at higher temperatures. Microstructural observation and data analysis were performed.

  1. Phase-field simulations of gas density within bubbles under irradiation

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect Phase-field simulations of gas density within bubbles under irradiation Citation Details In-Document Search Title: Phase-field simulations of gas density within bubbles under irradiation Phase-field simulations are used to study the evolution of gas density within irradiation-induced bubbles. In our simulations, the dpa rate, gas production rate, and defect diffusivities are systematically varied to understand their effect on bubble nucleation rates,

  2. Temperature dependence of fracture toughness in HT9 steel neutron-irradiated up to 145 dpa

    SciTech Connect (OSTI)

    Baek, Jong-Hyuk; Byun, Thak Sang; Maloy, S; Toloczko, M

    2014-01-01

    The temperature dependence of fracture toughness in HT9 steel irradiated to high doses was investigated using miniature three-point bend (TPB) fracture specimens. These specimens were from the ACO-3 fuel duct wall of the Fast Flux Test Facility (FFTF), in which irradiation doses were in the range of 3.2 144.8 dpa and irradiation temperatures in the range of 380.4 502.6 oC. A miniature specimen reuse technique has been established for this investigation: the specimens used were the tested halves of miniature Charpy impact specimens (~13 3 4 mm) with diamond-saw cut in the middle. The fatigue precracking for specimens and fracture resistance (J-R) tests were carried out in a MTS servo-hydraulic testing machine with a vacuum furnace following the standard procedure described in the ASTM Standard E 1820-09. For each of five irradiated and one archive conditions, 7 to 9 J-R tests were performed at selected temperatures ranging from 22 C to 600 C. The fracture toughness of the irradiated HT9 steel was strongly dependent on irradiation temperatures rather than irradiation dose. When the irradiation temperature was below about 430 C, the fracture toughness of irradiated HT9 increased with test temperature, reached an upper shelf of 180 200 MPa m at 350 450 C and then decreased with test temperature. When the irradiation temperature 430 C, the fracture toughness was nearly unchanged until about 450 C and decreased with test temperature in higher temperature range. Similar test temperature dependence was observed for the archive material although the highest toughness values are lower after irradiation. Ductile stable crack growth occurred except for a few cases where both the irradiation temperature and test temperature are relatively low.

  3. APPLICATION OF PHASE-FIELD MODELING TO IRRADIATION EFFECTS IN MATERIALS

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect APPLICATION OF PHASE-FIELD MODELING TO IRRADIATION EFFECTS IN MATERIALS Citation Details In-Document Search Title: APPLICATION OF PHASE-FIELD MODELING TO IRRADIATION EFFECTS IN MATERIALS This paper summarizes the recent advances in phase-field modeling in the field of radiation materials science. Conventional phase-field equations are first presented for the thermodynamic and kinetic description of irradiation-induced defects. Results of homogeneous and

  4. Formation of long-range ordered quantum dots arrays in amorphous matrix by ion beam irradiation

    SciTech Connect (OSTI)

    Buljan, M.; Bogdanovic-Radovic, I.; Karlusic, M.; Desnica, U. V.; Radic, N.; Dubcek, P.; Drazic, G.; Salamon, K.; Bernstorff, S.; Holy, V.

    2009-08-10

    We demonstrate the production of a well ordered three-dimensional array of Ge quantum dots in amorphous silica matrix. The ordering is achieved by ion beam irradiation and annealing of a multilayer film. Structural analysis shows that quantum dots nucleate along the direction of the ion beam used for irradiation, while the mutual distance of the quantum dots is determined by the diffusion properties of the multilayer material rather than the distances between traces of ions that are used for irradiation.

  5. Investigation of The Synergistic Influence of Irradiation Temperature and Atomic Displacement Rate on the Microstructural Evolution of Ion-Irradiated Model Austenitic Alloy Fe-15Cr-16Ni

    SciTech Connect (OSTI)

    Okita, Taira; Iwai, Takeo; Sekimura, Naoto; Garner, Francis A.

    2002-03-31

    A comprehensive experimental investigation of microstructural evolution has been conducted on Fe-15Cr-16Ni irradiated with 4.0 MeV nickel ions in the High Fluence Irradiation Facility of the University of Tokyo. Irradiations proceeded to dose levels ranging from ~0.2 to ~26 dpa at temperatures of 300, 400 and 500 degrees C at displacement rates of 1 x 10^-4, 4 x 10^-4 and 1 x 10^-3 dpa/sec. This experiment is one of two companion experiments directed toward the study of the dependence of void swelling on displacement rate. The other experiment proceeded at seven different but lower dpa rates in FFTF-MOTA at ~400 degrees C. In both experiments the swelling was found at every irradiation condition studied to monotonically increase with decreases in dpa rate. The microstructural evolution under ion irradiation was found to be very sensitive to the displacement rate at all three temperatures. The earliest and most sensitive component of microstructure to both temperature and especially displacement rate was found to be the Frank loops. The second most sensitive component was found to be the void microstructure, which co-evolves with the loop and dislocation microstructure. These data support the prediction that void swelling will probably be higher in lower-flux fusion devices and PWRs at a given irradiation temperature when compared to irradiations conducted at higher dpa rates in fast reactors.

  6. Hydrolysis of late-washed, irradiated tetraphenylborate slurry simulants I: Phenylboric acid hydrolysis kinetics

    SciTech Connect (OSTI)

    Marek, J.C.

    2000-02-10

    The attached report details the kinetics of phenylboric acid reaction at 90 degrees C during precipitate hydrolysis processing of late-washed, irradiated tetraphenylborate slurry simulants.

  7. Bright x-ray sources from laser irradiation of foams with high...

    Office of Scientific and Technical Information (OSTI)

    Country of Publication: United States Language: English Subject: 70 PLASMA PHYSICS AND FUSION TECHNOLOGY; CONCENTRATION RATIO; ELECTRON TEMPERATURE; FOAMS; IRRADIATION; LASER ...

  8. Effects of helium content of microstructural development in Type 316 stainless steel under neutron irradiation

    SciTech Connect (OSTI)

    Maziasz, P.J.

    1985-11-01

    This work investigated the sensitivity of microstructural evolution, particularly precipitate development, to increased helium content during thermal aging and during neutron irradiation. Helium (110 at. ppM) was cold preinjected into solution annealed (SA) DO-heat type 316 stainess steel (316) via cyclotron irradiation. These specimens were then exposed side by side with uninjected samples. Continuous helium generation was increased considerably relative to EBR-II irradiation by irradiation in HFIR. Data were obtained from quantitative analytical electron microscopy (AEM) in thin foils and on extraction replicas. 480 refs., 86 figs., 19 tabs.

  9. Conduction mechanisms in ion-irradiated InGaAs layers

    SciTech Connect (OSTI)

    Joulaud, L.; Mangeney, J.; Chimot, N.; Crozat, P.; Fishman, G.; Bourgoin, J.C.

    2005-03-15

    The electrical and optical properties of H{sup +}- and Au{sup +}-irradiated InGaAs layers were studied using Hall-effect, van der Pauw, and relaxation-time measurements. Comparing the different results allows us to obtain information on the nature of the defects created by these two irradiations. Proton irradiation introduces donor-acceptor paired defects. Gold-ion irradiation creates neutral defect clusters and ionized point defects. The carrier mobilities in all of the irradiated materials are degraded, decreasing with increasing irradiation dose. A scattering model taking into account the paired defects is developed and the mobility evolution calculated from this model agrees with the experimental data of both annealed and unannealed samples. The photocurrent spectra reveal a metallic conduction in the band gap in the case of light-ion irradiation, while such type of conduction does not appear for heavy-ion irradiation. This metallic conduction is a consequence of band tailing induced by shallow defects and vanishes when the material is annealed at 400 deg. C. The proton irradiation-induced defects appear to be related to the EL-2-like defects.

  10. Microstructure evolution in Xe-irradiated UO2 at room temperature

    SciTech Connect (OSTI)

    L.F. He; J. Pakarinen; M.A. Kirk; J. Gan; A.T. Nelson; X.-M. Bai; A. El-Azab; T.R. Allen

    2014-07-01

    In situ Transmission Electron Microscopy was conducted for single crystal UO2 to understand the microstructure evolution during 300 keV Xe irradiation at room temperature. The dislocation microstructure evolution was shown to occur as nucleation and growth of dislocation loops at low irradiation doses, followed by transformation to extended dislocation segments and tangles at higher doses. Xe bubbles with dimensions of 1-2 nm were observed after room-temperature irradiation. Electron Energy Loss Spectroscopy indicated that UO2 remained stoichiometric under room temperature Xe irradiation.

  11. Swift heavy ion irradiation of Pt nanocrystals: I. shape transformation and dissolution

    SciTech Connect (OSTI)

    Giulian, R.; Araujo, L.L.; Kluth, P.; Sprouster, D.J.; Schnohr, C.S.; Byrne, A.P.; Ridgway, M.C. (ANU)

    2014-09-24

    We report on the effects of swift heavy ion irradiation of embedded Pt nanocrystals (NCs), which change from spheres to prolate spheroids to rods upon irradiation. Using a broad range of ion irradiation energies and NC mean sizes we demonstrate that the elongation and dissolution processes are energy and size dependent, attaining comparable levels of shape transformation and dissolution upon a given energy density deposited in the matrix. The NC shape transformation remains operative despite discontinuous ion tracks in the matrix and exhibits a constant threshold size for elongation. In contrast, for ion irradiations in which the ion tracks are continuous, the threshold size for elongation is clearly energy dependent.

  12. Low-energy D{sup +} and H{sup +} ion irradiation effects on highly oriented pyrolytic graphite

    SciTech Connect (OSTI)

    Kue Park, Jun; Won Lee, Kyu; Hee Han, Jun; Jung Kweon, Jin; Kim, Dowan; Eui Lee, Cheol [Department of Physics and Institute for Nano Science, Korea University, Seoul 136-713 (Korea, Republic of)] [Department of Physics and Institute for Nano Science, Korea University, Seoul 136-713 (Korea, Republic of); Lim, Sun-Taek; Kim, Gon-Ho [Department of Nuclear Engineering, Seoul National University, Seoul 151-744 (Korea, Republic of)] [Department of Nuclear Engineering, Seoul National University, Seoul 151-744 (Korea, Republic of); Noh, S. J.; Kim, H. S. [Department of Applied Physics, Dankook University, Yongin 448-701 (Korea, Republic of)] [Department of Applied Physics, Dankook University, Yongin 448-701 (Korea, Republic of)

    2013-12-07

    We have investigated the low-energy (100 eV) D{sup +} and H{sup +} ion irradiation effects on the structural and chemical properties of highly oriented pyrolytic graphite (HOPG). Structural disorder due to the ion irradiation was identified by the Raman spectroscopy, the D{sup +} irradiation giving rise to greater structural disorder than the H{sup +} irradiation. Only sp{sup 2} bonding was identified in the X-ray photoemission spectroscopy of the D{sup +}-irradiated HOPG, indicating no change in the surface chemical structure. The H{sup +} irradiation, on the other hand, gave rise to sp{sup 3} bonding and ???{sup *} transition, the sp{sup 3} bonding increasing with increasing irradiation dose. It is thus shown that the chemical properties of the HOPG surface may be sensitively modified by the low-energy H{sup +} ion irradiation, but not by the low-energy D{sup +} ion irradiation.

  13. Neutron-Irradiated Samples as Test Materials for MPEX

    SciTech Connect (OSTI)

    Ellis, Ronald James; Rapp, Juergen

    2015-10-09

    Plasma Material Interaction (PMI) is a major concern in fusion reactor design and analysis. The Material-Plasma Exposure eXperiment (MPEX) will explore PMI under fusion reactor plasma conditions. Samples with accumulated displacements per atom (DPA) damage produced by fast neutron irradiations in the High Flux Isotope Reactor (HFIR) at Oak Ridge National Laboratory (ORNL) will be studied in the MPEX facility. This paper presents assessments of the calculated induced radioactivity and resulting radiation dose rates of a variety of potential fusion reactor plasma-facing materials (such as tungsten). The scientific code packages MCNP and SCALE were used to simulate irradiation of the samples in HFIR including the generation and depletion of nuclides in the material and the subsequent composition, activity levels, gamma radiation fields, and resultant dose rates as a function of cooling time. A challenge of the MPEX project is to minimize the radioactive inventory in the preparation of the samples and the sample dose rates for inclusion in the MPEX facility.

  14. Method for monitoring irradiated fuel using Cerenkov radiation

    DOE Patents [OSTI]

    Dowdy, E.J.; Nicholson, N.; Caldwell, J.T.

    1980-05-21

    A method is provided for monitoring irradiated nuclear fuel inventories located in a water-filled storage pond wherein the intensity of the Cerenkov radiation emitted from the water in the vicinity of the nuclear fuel is measured. This intensity is then compared with the expected intensity for nuclear fuel having a corresponding degree of irradiation exposure and time period after removal from a reactor core. Where the nuclear fuel inventory is located in an assembly having fuel pins or rods with intervening voids, the Cerenkov light intensity measurement is taken at selected bright sports corresponding to the water-filled interstices of the assembly in the water storage, the water-filled interstices acting as Cerenkov light channels so as to reduce cross-talk. On-line digital analysis of an analog video signal is possible, or video tapes may be used for later measurement using a video editor and an electrometer. Direct measurement of the Cerenkov radiation intensity also is possible using spot photometers pointed at the assembly.

  15. Neutron-Irradiated Samples as Test Materials for MPEX

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ellis, Ronald James; Rapp, Juergen

    2015-10-09

    Plasma Material Interaction (PMI) is a major concern in fusion reactor design and analysis. The Material-Plasma Exposure eXperiment (MPEX) will explore PMI under fusion reactor plasma conditions. Samples with accumulated displacements per atom (DPA) damage produced by fast neutron irradiations in the High Flux Isotope Reactor (HFIR) at Oak Ridge National Laboratory (ORNL) will be studied in the MPEX facility. This paper presents assessments of the calculated induced radioactivity and resulting radiation dose rates of a variety of potential fusion reactor plasma-facing materials (such as tungsten). The scientific code packages MCNP and SCALE were used to simulate irradiation of themore » samples in HFIR including the generation and depletion of nuclides in the material and the subsequent composition, activity levels, gamma radiation fields, and resultant dose rates as a function of cooling time. A challenge of the MPEX project is to minimize the radioactive inventory in the preparation of the samples and the sample dose rates for inclusion in the MPEX facility.« less

  16. Global horizontal irradiance clear sky models : implementation and analysis.

    SciTech Connect (OSTI)

    Stein, Joshua S.; Hansen, Clifford W.; Reno, Matthew J.

    2012-03-01

    Clear sky models estimate the terrestrial solar radiation under a cloudless sky as a function of the solar elevation angle, site altitude, aerosol concentration, water vapor, and various atmospheric conditions. This report provides an overview of a number of global horizontal irradiance (GHI) clear sky models from very simple to complex. Validation of clear-sky models requires comparison of model results to measured irradiance during clear-sky periods. To facilitate validation, we present a new algorithm for automatically identifying clear-sky periods in a time series of GHI measurements. We evaluate the performance of selected clear-sky models using measured data from 30 different sites, totaling about 300 site-years of data. We analyze the variation of these errors across time and location. In terms of error averaged over all locations and times, we found that complex models that correctly account for all the atmospheric parameters are slightly more accurate than other models, but, primarily at low elevations, comparable accuracy can be obtained from some simpler models. However, simpler models often exhibit errors that vary with time of day and season, whereas the errors for complex models vary less over time.

  17. Kr Ion Irradiation Study of the Depleted-Uranium Alloys

    SciTech Connect (OSTI)

    J. Gan; D. Keiser; B. Miller; M. Kirk; J. Rest; T. Allen; D. Wachs

    2010-12-01

    Fuel development for the Reduced Enrichment Research and Test Reactor program is tasked with the development of new low-enriched uranium nuclear fuels that can be employed to replace existing highly enriched uranium fuels currently used in some research reactors throughout the world. For dispersion-type fuels, radiation stability of the fuel/cladding interaction product has a strong impact on fuel performance. Three depleted uranium alloys are cast for the radiation stability studies of the fuel/cladding interaction product using Kr ion irradiation to investigate radiation damage from fission products. SEM analysis indicates the presence of the phases of interest: U(Si, Al)3, (U, Mo)(Si, Al)3, UMo2Al20, U6Mo4Al43, and UAl4. Irradiations of TEM disc samples were conducted with 500 keV Kr ions at 200C to ion doses up to 2.5 1015 ions/cm2 (~ 10 dpa) with an Kr ion flux of 1012 ions/cm2-sec (~ 4.0 10-3 dpa/sec). Microstructural evolution of the phases relevant to fuel-cladding interaction products was investigated using transmission electron microscopy.

  18. Analysis of clear hour solar irradiation for seven Canadian stations

    SciTech Connect (OSTI)

    Garrison, J.; Sahami, K.

    1995-12-31

    Hourly global and diffuse irradiation and corresponding surface meteorological data have been analyzed for the seven Canadian stations at Edmonton, Goose Bay, Montreal, Port Hardy, Resolute, Toronto, and Winnipeg. The variation of the most probable clear hour values of clearness index k{sub t}, diffuse index k{sub d}, direct beam index k{sub b}, and Angstrom turbidity coefficient {beta} with solar elevation, atmospheric precipitable water, and snow depth are obtained. Values of these quantities are presented which are consistent with the attenuation and scattering of solar radiation by the atmosphere which is expected. The most probable values of {beta} tend to be lower than the average values of {beta} recently reported by Gueymard. The data indicate a drift in the calibration of the instruments used for measurements of the irradiation data for the stations at Goose Bay and Resolute. The data for the other five stations indicate that the instrument calibration is maintained over the years of the data. 4 refs., 8 figs., 5 tabs.

  19. Janus Experiments: Data from Mouse Irradiation Experiments 1972 - 1989

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    The Janus Experiments, carried out at Argonne National Laboratory from 1972 to 1989 and supported by grants from the US Department of Energy, investigated the effects of neutron and gamma radiation on mouse tissues primarily from B6CF1 mice. 49,000 mice were irradiated: Death records were recorded for 42,000 mice; gross pathologies were recorded for 39,000 mice; and paraffin embedded tissues were preserved for most mice. Mouse record details type and source of radiation [gamma, neutrons]; dose and dose rate [including life span irradiation]; type and presence/absence of radioprotector treatment; tissue/animal morphology and pathology. Protracted low dose rate treatments, short term higher dose rate treatments, variable dose rates with a same total dose, etc. in some cases in conjunction with radioprotectors, were administered. Normal tissues, tumors, metastases were preserved. Standard tissues saved were : lung, liver, spleen, kidney, heart, any with gross lesions (including mammary glands, Harderian gland with eye, adrenal gland, gut, ovaries or testes, brain and pituitary, bone). Data are searchable and specimens can be obtained by request.

  20. A method for estimating direct normal solar irradiation from satellite data for a tropical environment

    SciTech Connect (OSTI)

    Janjai, Serm

    2010-09-15

    In order to investigate a potential use of concentrating solar power technologies and select an optimum site for these technologies, it is necessary to obtain information on the geographical distribution of direct normal solar irradiation over an area of interest. In this work, we have developed a method for estimating direct normal irradiation from satellite data for a tropical environment. The method starts with the estimation of global irradiation on a horizontal surface from MTSAT-1R satellite data and other ground-based ancillary data. Then a satellite-based diffuse fraction model was developed and used to estimate the diffuse component of the satellite-derived global irradiation. Based on this estimated global and diffuse irradiation and the solar radiation incident angle, the direct normal irradiation was finally calculated. To evaluate its performance, the method was used to estimate the monthly average hourly direct normal irradiation at seven pyrheliometer stations in Thailand. It was found that values of monthly average hourly direct normal irradiation from the measurements and those estimated from the proposed method are in reasonable agreement, with a root mean square difference of 16% and a mean bias of -1.6%, with respect to mean measured values. After the validation, this method was used to estimate the monthly average hourly direct normal irradiation over Thailand by using MTSAT-1R satellite data for the period from June 2005 to December 2008. Results from the calculation were displayed as hourly and yearly irradiation maps. These maps reveal that the direct normal irradiation in Thailand was strongly affected by the tropical monsoons and local topography of the country. (author)

  1. Status of the NGNP fuel experiment AGR-2 irradiated in the advanced test reactor

    SciTech Connect (OSTI)

    S. Blaine Grover; David A. Petti

    2014-05-01

    The United States Department of Energy's Next Generation Nuclear Plant (NGNP) Advanced Gas Reactor (AGR) Fuel Development and Qualification Program will be irradiating up to seven separate low enriched uranium (LEU) tri-isotopic (TRISO) particle fuel (in compact form) experiments in the Advanced Test Reactor (ATR) located at the Idaho National Laboratory (INL). These irradiations and fuel development are being accomplished to support development of the next generation reactors in the United States, and will be irradiated over the next several years to demonstrate and qualify new TRISO coated particle fuel for use in high temperature gas reactors. The goals of the irradiation experiments are to provide irradiation performance data to support fuel process development, to qualify fuel for normal operating conditions, to support development and validation of fuel performance and fission product transport models and codes, and to provide irradiated fuel and materials for post irradiation examination (PIE) and safety testing. The experiments, which will each consist of at least six separate capsules, will be irradiated in an inert sweep gas atmosphere with individual on-line temperature monitoring and control of each capsule. The sweep gas will also undergo on-line fission product monitoring to track performance of the fuel in each individual capsule during irradiation. The first experiment (designated AGR-1) started irradiation in December 2006 and was completed in November 2009. The second experiment (AGR-2), which utilized the same experiment design as well as control and monitoring systems as AGR-1, started irradiation in June 2010 and is currently scheduled to be completed in April 2013. The design of this experiment and sup

  2. Status of the NGNP Fuel Experiment AGR-2 Irradiated in the Advanced Test Reactor

    SciTech Connect (OSTI)

    Blaine Grover

    2012-10-01

    The United States Department of Energys Next Generation Nuclear Plant (NGNP) Advanced Gas Reactor (AGR) Fuel Development and Qualification Program will be irradiating up to seven separate low enriched uranium (LEU) tri-isotopic (TRISO) particle fuel (in compact form) experiments in the Advanced Test Reactor (ATR) located at the Idaho National Laboratory (INL). These irradiations and fuel development are being accomplished to support development of the next generation reactors in the United States, and will be irradiated over the next several years to demonstrate and qualify new TRISO coated particle fuel for use in high temperature gas reactors. The goals of the irradiation experiments are to provide irradiation performance data to support fuel process development, to qualify fuel for normal operating conditions, to support development and validation of fuel performance and fission product transport models and codes, and to provide irradiated fuel and materials for post irradiation examination (PIE) and safety testing. The experiments, which will each consist of at least six separate capsules, will be irradiated in an inert sweep gas atmosphere with individual on-line temperature monitoring and control of each capsule. The sweep gas will also have on-line fission product monitoring on its effluent to track performance of the fuel in each individual capsule during irradiation. The first experiment (designated AGR-1) started irradiation in December 2006 and was completed in November 2009. The second experiment (AGR-2), which utilized the same experiment design as well as control and monitoring systems as AGR-1, started irradiation in June 2010 and is currently scheduled to be completed in April 2013. The design of this experiment and support systems will be briefly discussed, followed by the progress and status of the experiment to date.

  3. Response of nanostructured ferritic alloys to high-dose heavy ion irradiation

    SciTech Connect (OSTI)

    Parish, Chad M.; White, Ryan M.; LeBeau, James M.; Miller, Michael K.

    2014-02-01

    A latest-generation aberration-corrected scanning/transmission electron microscope (STEM) is used to study heavy-ion-irradiated nanostructured ferritic alloys (NFAs). Results are presented for STEM X-ray mapping of NFA 14YWT irradiated with 10 MeV Pt to 16 or 160 dpa at -100°C and 750°C, as well as pre-irradiation reference material. Irradiation at -100°C results in ballistic destruction of the beneficial microstructural features present in the pre-irradiated reference material, such as Ti-Y-O nanoclusters (NCs) and grain boundary (GB) segregation. Irradiation at 750°C retains these beneficial features, but indicates some coarsening of the NCs, diffusion of Al to the NCs, and a reduction of the Cr-W GB segregation (or solute excess) content. Ion irradiation combined with the latest-generation STEM hardware allows for rapid screening of fusion candidate materials and improved understanding of irradiation-induced microstructural changes in NFAs.

  4. University of Wisconsin Ion Beam Laboratory: A facility for irradiated materials and ion beam analysis

    SciTech Connect (OSTI)

    Field, K. G.; Wetteland, C. J.; Cao, G.; Maier, B. R.; Gerczak, T. J.; Kriewaldt, K.; Sridharan, K.; Allen, T. R.; Dickerson, C.; Field, C. R.

    2013-04-19

    The University of Wisconsin Ion Beam Laboratory (UW-IBL) has recently undergone significant infrastructure upgrades to facilitate graduate level research in irradiated materials phenomena and ion beam analysis. A National Electrostatics Corp. (NEC) Torodial Volume Ion Source (TORVIS), the keystone upgrade for the facility, can produce currents of hydrogen ions and helium ions up to {approx}200 {mu}A and {approx}5 {mu}A, respectively. Recent upgrades also include RBS analysis packages, end station developments for irradiation of relevant material systems, and the development of an in-house touch screen based graphical user interface for ion beam monitoring. Key research facilitated by these upgrades includes irradiation of nuclear fuels, studies of interfacial phenomena under irradiation, and clustering dynamics of irradiated oxide dispersion strengthened steels. The UW-IBL has also partnered with the Advanced Test Reactor National Scientific User Facility (ATR-NSUF) to provide access to the irradiation facilities housed at the UW-IBL as well as access to post irradiation facilities housed at the UW Characterization Laboratory for Irradiated Materials (CLIM) and other ATR-NSUF partner facilities. Partnering allows for rapid turnaround from proposed research to finalized results through the ATR-NSUF rapid turnaround proposal system. An overview of the UW-IBL including CLIM and relevant research is summarized.

  5. The Next Generation Nuclear Plant Graphite Creep Experiment Irradiation in the Advanced Test Reactor

    SciTech Connect (OSTI)

    Blaine Grover

    2010-10-01

    The United States Department of Energys Next Generation Nuclear Plant (NGNP) Program will be irradiating six gas reactor graphite creep experiments in the Advanced Test Reactor (ATR) located at the Idaho National Laboratory (INL). The ATR has a long history of irradiation testing in support of reactor development and the INL has been designated as the United States Department of Energys lead laboratory for nuclear energy development. The ATR is one of the worlds premiere test reactors for performing long term, high flux, and/or large volume irradiation test programs. These graphite irradiations are being accomplished to support development of the next generation reactors in the United States. The graphite experiments will be irradiated over the next six to eight years to support development of a graphite irradiation performance data base on the new nuclear grade graphites now available for use in high temperature gas reactors. The goals of the irradiation experiments are to obtain irradiation performance data, including irradiation creep, at different temperatures and loading conditions to support design of the Next Generation Nuclear Plant (NGNP) Very High Temperature Gas Reactor, as well as other future gas reactors. The experiments will each consist of a single capsule that will contain six stacks of graphite specimens, with half of the graphite specimens in each stack under a compressive load, while the other half of the specimens will not be subjected to a compressive load during irradiation. The six stacks will have differing compressive loads applied to the top half of each pair of specimen stacks, while a seventh stack will not have a compressive load. The specimens will be irradiated in an inert sweep gas atmosphere with on-line temperature and compressive load monitoring and control. There will also be the capability of sampling the sweep gas effluent to determine if any oxidation or off-gassing of the specimens occurs during initial start-up of the experiment. The first experiment was inserted in the ATR in August 2009 and started its irradiation in September 2009. It is anticipated to complete its irradiation in early calendar 2011. This paper will discuss the design of the experiment including the test train and the temperature and compressive load monitoring, control, and the irradiation experience to date.

  6. The discrepancies in multistep damage evolution of yttria-stabilized zirconia irradiated with different ions

    SciTech Connect (OSTI)

    Yang, Tengfei; Taylor, Caitlin A.; Kong, Shuyan; Wang, Chenxu; Zhang, Yanwen; Huang, Xuejun; Xue, Jianming; Yan, Sha; Wang, Yugang

    2013-01-01

    This paper reports a comprehensive investigation of structural damage in yttria-stabilized zirconia irradiated with different ions over a wide fluence range. A similar multistep damage accumulation exists for the irradiations of different ions, but the critical doses for occurrence of second damage step, characterized by a faster increase in damage fraction, and the maximum elastic strain at the first damage step are varied and depend on ion mass. For irradiations of heavier ions, the second damage step occurs at a higher dose with a lower critical elastic strain. Furthermore, larger extended defects were observed in the irradiations of heavy ions at the second damage step. Associated with other experiment results and multistep damage accumulation model, the distinct discrepancies in the damage buildup under irradiations of different ions were interpreted by the effects of electronic excitation, energy of primary knock-on atom and chemistry contributions of deposited ions.

  7. Response of 9Cr-ODS Steel to Proton Irradiation at 400 C

    SciTech Connect (OSTI)

    Jianchao He; Farong Wan; Kumar Sridharan; Todd R. Allen; A. Certain; Y. Q. Wu

    2014-09-01

    The stability of YTiO nanoclusters, dislocation structure, and grain boundary segregation in 9Cr-ODS steels has been investigated following proton irradiation at 400 C with damage levels up to 3.7 dpa. A slight coarsening and a decrease in number density of nanoclusters were observed as a result of irradiation. The composition of nanoclusters was also observed to change with a slight increase of Y and Cr concentration in the nanoclusters following irradiation. Size, density, and composition of the nanoclusters were investigated as a function of nanocluster size, specifically classified to three groups. In addition to the changes in nanoclusters, dislocation loops were observed after irradiation. Finally, radiation-induced enrichment of Cr and depletion of W were observed at grain boundaries after irradiation.

  8. Irradiation-induced reduction of microcracking in zirconolite

    SciTech Connect (OSTI)

    Clinard, F.W. Jr.; Tucker, D.S.; Hurley, G.F.; Kise, C.D.; Rankin, J.

    1984-01-01

    /sup 238/Pu-substituted zirconolite (CaPuTi/sub 2/O/sub 7/) was stored near ambient temperature for 231 days, equivalent to an alpha decay dose of 3.1x10/sup 25/ ..cap alpha../m/sup 3/ or 3x10/sup 5/ years of storage time for SYNROC ceramic nuclear waste. Periodic indentation testing showed that hardness was decreased by alpha decay-induced conversion to the metamict state, while fracture toughness and resistance to cracking were increased, apparently as a consequence of the formation of a heterogeneous microstructure. These results imply improved stability of this nuclear waste phase as a result of self-irradiation damage. 21 references, 4 figures.

  9. Low Temperature Irradiation Embrittlement of Reactor Pressure Vessel Steels

    SciTech Connect (OSTI)

    Wang, Jy-An John

    2015-08-01

    The embrittlement trend curve development project for HFIR reactor pressure vessel (RPV) steels was carried out with three major tasks. Which are (1) data collection to match that used in HFIR steel embrittlement trend published in 1994 Journal Nuclear Material by Remec et. al, (2) new embrittlement data of A212B steel that are not included in earlier HFIR RPV trend curve, and (3) the adjustment of nil-ductility-transition temperature (NDTT) shift data with the consideration of the irradiation temperature effect. An updated HFIR RPV steel embrittlement trend curve was developed, as described below. NDTT( C) = 23.85 log(x) + 203.3 log (x) + 434.7, with 2- uncertainty of 34.6 C, where parameter x is referred to total dpa. The developed update HFIR RPV embrittlement trend curve has higher embrittlement rate compared to that of the trend curve developed in 1994.

  10. Crystallographic changes in lead zirconate titanate due to neutron irradiation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Henriques, Alexandra; Graham, Joseph T.; Landsberger, Sheldon; Ihlefeld, Jon F.; Brennecka, Geoff L.; Brown, Donald W.; Forrester, Jennifer S.; Jones, Jacob L.

    2014-11-17

    Piezoelectric and ferroelectric materials are useful as the active element in non-destructive monitoring devices for high-radiation areas. Here, crystallographic structural refinement (i.e., the Rietveld method) is used to quantify the type and extent of structural changes in PbZr0.5Ti0.5O3 after exposure to a 1 MeV equivalent neutron fluence of 1.7 × 1015 neutrons/cm2. The results show a measurable decrease in the occupancy of Pb and O due to irradiation, with O vacancies in the tetragonal phase being created preferentially on one of the two O sites. The results demonstrate a method by which the effects of radiation on crystallographic structure maymore » be investigated.« less

  11. Crystallographic changes in lead zirconate titanate due to neutron irradiation

    SciTech Connect (OSTI)

    Henriques, Alexandra; Graham, Joseph T.; Landsberger, Sheldon; Ihlefeld, Jon F.; Brennecka, Geoff L.; Brown, Donald W.; Forrester, Jennifer S.; Jones, Jacob L.

    2014-11-17

    Piezoelectric and ferroelectric materials are useful as the active element in non-destructive monitoring devices for high-radiation areas. Here, crystallographic structural refinement (i.e., the Rietveld method) is used to quantify the type and extent of structural changes in PbZr0.5Ti0.5O3 after exposure to a 1 MeV equivalent neutron fluence of 1.7 1015 neutrons/cm2. The results show a measurable decrease in the occupancy of Pb and O due to irradiation, with O vacancies in the tetragonal phase being created preferentially on one of the two O sites. The results demonstrate a method by which the effects of radiation on crystallographic structure may be investigated.

  12. Controlled synthesis of novel octapod platinum nanocrystals under microwave irradiation

    SciTech Connect (OSTI)

    Dai, Lei; Chi, Quan; Zhao, Yanxi; Liu, Hanfan; Zhou, Zhongqiang; Li, Jinlin; Huang, Tao

    2014-01-01

    Graphical abstract: Under microwave irradiation, novel octapod Pt nanocrystals were synthesized by reducing H{sub 2}PtCl{sub 6} in TEG with PVP as a stabilizer. The as-prepared Pt nanocrystals displayed a unique octapod nanostructure with five little mastoids in each concave center. The use of KI was crucial to the formation of novel Pt octapods. Novel Octapod Platinum Nanocrystals. - Highlights: A novel octapod Pt nanocrystals different from the common octapod were obtained. The use of KI was crucial to the formation of the novel Pt octapods. Microwave was readily employed in controlled synthesis of the novel Pt octapods. - Abstract: Microwave was employed in the shape-controlled synthesis of Pt nanoparticles. Novel octapod Pt nanocrystals enclosed with (1 1 1) facets were readily synthesized with H{sub 2}PtCl{sub 6} as a precursor, tetraethylene glycol (TEG) as both a solvent and a reducing agent, polyvinylpyrrolidone (PVP) as a stabilizer in the presence of an appropriate amount of KI under microwave irradiation for 140 s. The as-prepared Pt nanocrystals displayed a unique octapod nanostructure with five little mastoids in each concave center and exhibited higher electrocatalytic activity than commercial Pt black in the electro-oxidations of methanol and formic acid. The results demonstrated that the use of KI was crucial to the formation of Pt octapods. KI determined the formation of the novel octapod Pt nanocrystals by tuning up the reduction kinetics and adsorbing on the surfaces of growing Pt nanoparticles. The optimum molar ratio of H{sub 2}PtCl{sub 6}/KI/PVP was 1/30/45.

  13. AGC-3 Experiment Irradiation Monitoring Data Qualification Final Report

    SciTech Connect (OSTI)

    Laurence Hull

    2014-10-01

    The Graphite Technology Development Program will run a series of six experiments to quantify the effects of irradiation on nuclear grade graphite. The third experiment, Advanced Graphite Creep 3 (AGC 3), began with Advanced Test Reactor (ATR) Cycle 152B on November 27, 2012, and ended with ATR Cycle 155B on April 23, 2014. This report documents qualification of AGC 3 experiment irradiation monitoring data for use by the Very High Temperature Reactor (VHTR) Technology Development Office (TDO) Program for research and development activities required to design and license the first VHTR nuclear plant. Qualified data meet the requirements for data collection and use as described in the experiment planning and quality assurance documents. Failed data do not meet the requirements. Trend data may not meet the requirements, but may still provide some useable information. All thermocouples (TCs) functioned throughout the AGC 3 experiment. There was one interval between December 18, 2012, and December 20, 2012, where 10 NULL values were reported for various TCs. These NULL values were deleted from the Nuclear Data Management and Analysis System database. All temperature data are Qualified for use by the VHTR TDO Program. Argon, helium, and total gas flow data were within expected ranges and are Qualified for use by the VHTR TDO Program. Total gas flow was approximately 50 sccm through the AGC 3 experiment capsule. Helium gas flow was briefly increased to 100 sccm during ATR shutdowns. At the start of the AGC 3 experiment, moisture in the outflow gas line was stuck at a constant value of 335.6174 ppmv for the first cycle (Cycle 152B). When the AGC 3 experiment capsule was reinstalled in ATR for Cycle 154B, a new moisture filter was installed. Moisture data from Cycle 152B are Failed. All moisture data from the final three cycles (Cycles 154B, 155A, and 155B) are Qualified for use by the VHTR TDO Program.

  14. High dose rate intraluminal irradiation in recurrent endobronchial carcinoma

    SciTech Connect (OSTI)

    Seagren, S.L.; Harrell, J.H.; Horn, R.A.

    1985-12-01

    Palliative therapy for previously irradiated patients with symptomatic recurrent endobronchial malignancy is a difficult problem. We have had the opportunity to treat 20 such patients with high dose rate (50-100 rad/min) endobronchial brachytherapy. Eligible patients had received previous high dose thoracic irradiation (TDF greater than or equal to 90), a performance status of greater than or equal to 50, and symptoms caused by a bronchoscopically defined and implantable lesion. The radiation is produced by a small cobalt-60 source (0.7 Ci) remotely afterloaded by cable control. The source is fed into a 4 mm diameter catheter which is placed with bronchoscopic guidance; it may oscillate if necessary to cover the lesion. A dose of 1,000 rad at 1 cm from the source is delivered. We have performed 22 procedures in 20 patients, four following YAG laser debulking. Most had cough, some with hemoptysis. Eight had dyspnea secondary to obstruction and three had obstructive pneumonitis. In 12, symptoms recurred with a mean time to recurrence of 4.3 months (range 1-9 months). Eighteen patients were followed-up and reexamined via bronchoscope 1-2.5 months following the procedure; two were lost to follow-up. All had at least 50 percent clearance of tumor, and six had complete clearance; most regressions were documented on film or videotape. In six, the palliation was durable. The procedure has been well tolerated with no toxicity. We conclude that palliative endobronchial high dose rate brachytherapy is a useful palliative modality in patients with recurrent endobronchial symptomatic carcinoma.

  15. Irradiation-Assisted Stress Corrosion Cracking of Austenitic Stainless Steels in BWR Environments

    SciTech Connect (OSTI)

    Chen, Y.; Chopra, O. K.; Gruber, Eugene E.; Shack, William J.

    2010-06-01

    The internal components of light water reactors are exposed to high-energy neutron irradiation and high-temperature reactor coolant. The exposure to neutron irradiation increases the susceptibility of austenitic stainless steels (SSs) to stress corrosion cracking (SCC) because of the elevated corrosion potential of the reactor coolant and the introduction of new embrittlement mechanisms through radiation damage. Various nonsensitized SSs and nickel alloys have been found to be prone to intergranular cracking after extended neutron exposure. Such cracks have been seen in a number of internal components in boiling water reactors (BWRs). The elevated susceptibility to SCC in irradiated materials, commonly referred to as irradiation-assisted stress corrosion cracking (IASCC), is a complex phenomenon that involves simultaneous actions of irradiation, stress, and corrosion. In recent years, as nuclear power plants have aged and irradiation dose increased, IASCC has become an increasingly important issue. Post-irradiation crack growth rate and fracture toughness tests have been performed to provide data and technical support for the NRC to address various issues related to aging degradation of reactor-core internal structures and components. This report summarizes the results of the last group of tests on compact tension specimens from the Halden-II irradiation. The IASCC susceptibility of austenitic SSs and heat-affected-zone (HAZ) materials sectioned from submerged arc and shielded metal arc welds was evaluated by conducting crack growth rate and fracture toughness tests in a simulated BWR environment. The fracture and cracking behavior of HAZ materials, thermally sensitized SSs and grain-boundary engineered SSs was investigated at several doses (?3 dpa). These latest results were combined with previous results from Halden-I and II irradiations to analyze the effects of neutron dose, water chemistry, alloy compositions, and welding and processing conditions on IASCC. The effect of neutron irradiation on the fracture toughness of austenitic SSs was also evaluated at dose levels relevant to BWR internals.

  16. Irradiation Alters MMP-2/TIMP-2 System and Collagen Type IV Degradation in Brain

    SciTech Connect (OSTI)

    Lee, Won Hee; Warrington, Junie P.; Sonntag, William E.; Lee, Yong Woo

    2012-04-01

    Purpose: Blood-brain barrier (BBB) disruption is one of the major consequences of radiation-induced normal tissue injury in the central nervous system. We examined the effects of whole-brain irradiation on matrix metalloproteinases (MMPs)/tissue inhibitors of metalloproteinases (TIMPs) and extracellular matrix (ECM) degradation in the brain. Methods and Materials: Animals received either whole-brain irradiation (a single dose of 10 Gy {gamma}-rays or a fractionated dose of 40 Gy {gamma}-rays, total) or sham-irradiation and were maintained for 4, 8, and 24 h following irradiation. mRNA expression levels of MMPs and TIMPs in the brain were analyzed by real-time reverse transcriptase-polymerase chain reaction (PCR). The functional activity of MMPs was measured by in situ zymography, and degradation of ECM was visualized by collagen type IV immunofluorescent staining. Results: A significant increase in mRNA expression levels of MMP-2, MMP-9, and TIMP-1 was observed in irradiated brains compared to that in sham-irradiated controls. In situ zymography revealed a strong gelatinolytic activity in the brain 24 h postirradiation, and the enhanced gelatinolytic activity mediated by irradiation was significantly attenuated in the presence of anti-MMP-2 antibody. A significant reduction in collagen type IV immunoreactivity was also detected in the brain at 24 h after irradiation. In contrast, the levels of collagen type IV were not significantly changed at 4 and 8 h after irradiation compared with the sham-irradiated controls. Conclusions: The present study demonstrates for the first time that radiation induces an imbalance between MMP-2 and TIMP-2 levels and suggests that degradation of collagen type IV, a major ECM component of BBB basement membrane, may have a role in the pathogenesis of brain injury.

  17. The change in dielectric constant, AC conductivity and optical band gaps of polymer electrolyte film: Gamma irradiation

    SciTech Connect (OSTI)

    Raghu, S. Subramanya, K. Sharanappa, C. Mini, V. Archana, K. Sanjeev, Ganesh Devendrappa, H.

    2014-04-24

    The effects of gamma (?) irradiation on dielectric and optical properties of polymer electrolyte film were investigated. The dielectric constant and ac conductivity increases with ? dose. Also optical band gap decreased from 4.23 to 3.78ev after irradiation. A large dependence of the polymer properties on the irradiation dose was noticed. This suggests that there is a possibility of improving polymer electrolyte properties on gamma irradiation.

  18. Mechanism of Irradiation Assisted Cracking of Core Components in Light Water Reactors

    SciTech Connect (OSTI)

    Gary S. Was; Michael Atzmon; Lumin Wang

    2003-04-28

    The overall goal of the project is to determine the mechanism of irradiation assisted stress corrosion cracking (IASCC). IASCC has been linked to hardening, microstructural and microchemical changes during irradiation. Unfortunately, all of these changes occur simultaneously and at similar rates during irradiation, making attribution of IASCC to any one of these features nearly impossible to determine. The strategy set forth in this project is to develop means to separate microstructural from microchemical changes to evaluate each separately for their effect on IASCC. In the first part, post irradiation annealing (PIA) treatments are used to anneal the irradiated microstructure, leaving only radiation induced segregation (RIS) for evaluation for its contribution to IASCC. The second part of the strategy is to use low temperature irradiation to produce a radiation damage dislocation loop microstructure without radiation induced segregation in order to evaluate the effect of the dislocation microstructure alone. A radiation annealing model was developed based on the elimination of dislocation loops by vacancy absorption. Results showed that there were indeed, time-temperature annealing combinations that leave the radiation induced segregation profile largely unaltered while the dislocation microstructure is significantly reduced. Proton irradiation of 304 stainless steel irradiated with 3.2 MeV protons to 1.0 or 2.5 dpa resulted in grain boundary depletion of chromium and enrichment of nickel and a radiation damaged microstructure. Post irradiation annealing at temperatures of 500 ? 600C for times of up to 45 min. removed the dislocation microstructure to a greater degree with increasing temperatures, or times at temperature, while leaving the radiation induced segregation profile relatively unaltered. Constant extension rate tensile (CERT) experiments in 288C water containing 2 ppm O2 and with a conductivity of 0.2 mS/cm and at a strain rate of 3 x 10-7 s-1 showed that the IASCC susceptibility, as measured by the crack length per unit strain, decreased with very short anneals and was almost completely removed by an anneal at 500C for 45 min. This annealing treatment removed about 15% of the dislocation microstructure and the irradiation hardening, but did not affect the grain boundary chromium depletion or nickel segregation, nor did it affect the grain boundary content of other minor impurities. These results indicate that RIS is not the sole controlling feature of IASCC in irradiated stainless steels in normal water chemistry. The isolation of the irradiated microstructure was approached using low temperature irradiation or combinations of low and high temperature irradiations to achieve a stable, irradiated microstructure without RIS. Experiments were successful in achieving a high degree of irradiation hardening without any evidence of RIS of either major or minor elements. The low temperature irradiations to doses up to 0.3 dpa at T<75C were also very successful in producing hardening to levels considerably above that for irradiations conducted under nominal conditions of 1 dpa at 360C. However, the microstructure consisted of an extremely fine dispersion of defect clusters of sizes that are not resolvable by either transmission electron microscopy (TEM) or small angle x-ray scattering (SAXS). The microstructure was not stable at the 288C IASCC test temperature and resulted in rapid reduction of hardening and presumably, annealing of the defect clusters at this temperature as well. Nevertheless, the annealing studies showed that treatments that resulted in significant decreases in the hardening produced small changes in the dislocation microstructure that were confined to the elimination of the finest of loops (~1 nm). These results substantiate the importance of the very fine defect microstructure in the IASCC process. The results of this program provide the first definitive evidence that RIS is not the sole controlling factor in the irradiation assisted stress corrosion cracking of austenitic stain

  19. SU-E-T-492: Implementing a Method for Brain Irradiation in Rats Utilizing a Commercially Available Radiosurgery Irradiator

    SciTech Connect (OSTI)

    Cates, J; Drzymala, R

    2014-06-01

    Purpose: The purpose of the study was to implement a method for accurate rat brain irradiation using the Gamma Knife Perfexion unit. The system needed to be repeatable, efficient, and dosimetrically and spatially accurate. Methods: A platform (“rat holder”) was made such that it is attachable to the Leskell Gamma Knife G Frame. The rat holder utilizes two ear bars contacting bony anatomy and a front tooth bar to secure the rat. The rat holder fits inside of the Leskell localizer box, which utilizes fiducial markers to register with the GammaPlan planning system. This method allows for accurate, repeatable setup.A cylindrical phantom was made so that film can be placed axially in the phantom. We then acquired CT image sets of the rat holder and localizer box with both a rat and the phantom. Three treatment plans were created: a plan on the rat CT dataset, a phantom plan with the same prescription dose as the rat plan, and a phantom plan with the same delivery time as the rat plan. Results: Film analysis from the phantom showed that our setup is spatially accurate and repeatable. It is also dosimetrically accurate, with an difference between predicted and measured dose of 2.9%. Film analysis with prescription dose equal between rat and phantom plans showed a difference of 3.8%, showing that our phantom is a good representation of the rat for dosimetry purposes, allowing for +/- 3mm diameter variation. Film analysis with treatment time equal showed an error of 2.6%, which means we can deliver a prescription dose within 3% accuracy. Conclusion: Our method for irradiation of rat brain has been shown to be repeatable, efficient, and accurate, both dosimetrically and spatially. We can treat a large number of rats efficiently while delivering prescription doses within 3% at millimeter level accuracy.

  20. Comparison of absolute spectral irradiance responsivity measurement techniques using wavelength-tunable lasers

    SciTech Connect (OSTI)

    Ahtee, Ville; Brown, Steven W.; Larason, Thomas C.; Lykke, Keith R.; Ikonen, Erkki; Noorma, Mart

    2007-07-10

    Independent methods for measuring the absolute spectral irradiance responsivity of detectors have been compared between the calibration facilities at two national metrology institutes, the Helsinki University of Technology (TKK), Finland, and the National Institute of Standards and Technology (NIST). The emphasis is on the comparison of two different techniques for generating a uniform irradiance at a reference plane using wavelength-tunable lasers. At TKK's Laser Scanning Facility (LSF) the irradiance is generated by raster scanning a single collimated laser beam, while at the NIST facility for Spectral Irradiance and Radiance Responsivity Calibrations with Uniform Sources (SIRCUS), lasers are introduced into integrating spheres to generate a uniform irradiance at a reference plane. The laser-based irradiance responsivity results are compared to a traditional lamp-monochromator-based irradiance responsivity calibration obtained at the NIST Spectral Comparator Facility (SCF). A narrowband filter radiometer with a24 nm bandwidth and an effective band-center wavelength of 801 nm was used as the artifact. The results of the comparison between the different facilities, reported for the first time in the near-infrared wavelength range, demonstrate agreement at the uncertainty level of less than 0.1%. This result has significant implications in radiation thermometry and in photometry as well as in radiometry.

  1. Introducing an Absolute Cavity Pyrgeometer for Improving the Atmospheric Longwave Irradiance Measurement (Presentation)

    SciTech Connect (OSTI)

    Reda, I.; Hansen, L.; Zeng, J.

    2012-08-01

    Advancing climate change research requires accurate and traceable measurement of the atmospheric longwave irradiance. Current measurement capabilities are limited to an estimated uncertainty of larger than +/- 4 W/m2 using the interim World Infrared Standard Group (WISG). WISG is traceable to the Systeme international d'unites (SI) through blackbody calibrations. An Absolute Cavity Pyrgeometer (ACP) is being developed to measure absolute outdoor longwave irradiance with traceability to SI using the temperature scale (ITS-90) and the sky as the reference source, instead of a blackbody. The ACP was designed by NREL and optically characterized by the National Institute of Standards and Technology (NIST). Under clear-sky and stable conditions, the responsivity of the ACP is determined by lowering the temperature of the cavity and calculating the rate of change of the thermopile output voltage versus the changing net irradiance. The absolute atmospheric longwave irradiance is then calculated with an uncertainty of +/- 3.96 W/m2 with traceability to SI. The measured irradiance by the ACP was compared with the irradiance measured by two pyrgeometers calibrated by the World Radiation Center with traceability to the WISG. A total of 408 readings was collected over three different clear nights. The calculated irradiance measured by the ACP was 1.5 W/m2 lower than that measured by the two pyrgeometers that are traceable to WISG. Further development and characterization of the ACP might contribute to the effort of improving the uncertainty and traceability of WISG to SI.

  2. Method for Analyzing Passive SiC Thermometry with a Continuous Dilatometer to Determine Irradiation Temperature

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Campbell, Anne A; Porter, Wallace D; Katoh, Yutai; Snead, Lance Lewis

    2016-01-01

    Silicon carbide is used as a passive post-irradiation temperature monitor because the irradiation defects will anneal out above the irradiation temperature. The irradiation temperature is determined by measuring a property change after isochronal annealing, i.e., lattice spacing, dimensions, electrical resistivity, thermal diffusivity, or bulk density. However, such methods are time-consuming since the steps involved must be performed in a serial manner. This work presents the use of thermal expansion from continuous dilatometry to calculate the SiC irradiation temperature, which is an automated process requiring minimal setup time. Analysis software was written that performs the calculations to obtain the irradiation temperaturemoreand removes possible user-introduced error while standardizing the analysis. This method has been compared to an electrical resistivity and isochronal annealing investigation, and the results revealed agreement of the calculated temperatures. These results show that dilatometry is a reliable and less time-intensive process for determining irradiation temperature from passive SiC thermometry.less

  3. STATUS OF HIGH FLUX ISOTOPE REACTOR IRRADIATION OF SILICON CARBIDE/SILICON CARBIDE JOINTS

    SciTech Connect (OSTI)

    Katoh, Yutai; Koyanagi, Takaaki; Kiggans, Jim; Cetiner, Nesrin; McDuffee, Joel

    2014-09-01

    Development of silicon carbide (SiC) joints that retain adequate structural and functional properties in the anticipated service conditions is a critical milestone toward establishment of advanced SiC composite technology for the accident-tolerant light water reactor (LWR) fuels and core structures. Neutron irradiation is among the most critical factors that define the harsh service condition of LWR fuel during the normal operation. The overarching goal of the present joining and irradiation studies is to establish technologies for joining SiC-based materials for use as the LWR fuel cladding. The purpose of this work is to fabricate SiC joint specimens, characterize those joints in an unirradiated condition, and prepare rabbit capsules for neutron irradiation study on the fabricated specimens in the High Flux Isotope Reactor (HFIR). Torsional shear test specimens of chemically vapor-deposited SiC were prepared by seven different joining methods either at Oak Ridge National Laboratory or by industrial partners. The joint test specimens were characterized for shear strength and microstructures in an unirradiated condition. Rabbit irradiation capsules were designed and fabricated for neutron irradiation of these joint specimens at an LWR-relevant temperature. These rabbit capsules, already started irradiation in HFIR, are scheduled to complete irradiation to an LWR-relevant dose level in early 2015.

  4. Grain Growth and Phase Stability of Nanocrystalline Cubic Zirconia under Ion Irradiation

    SciTech Connect (OSTI)

    Zhang, Yanwen; Jiang, Weilin; Wang, Chongmin; Namavar, Fereydoon; Edmondson, Philip D.; Zhu, Zihua; Gao, Fei; Lian, Jie; Weber, William J

    2010-01-01

    Grain growth, oxygen stoichiometry and phase stability of nanostructurally-stabilized cubic zirconia (NSZ) are investigated under 2 MeV Au ion bombardment at 160 and 400 K to doses up to 35 displacements per atom (dpa). The NSZ films are produced by ion-beam-assisted deposition technique at room temperature with an average grain size of 7.7 nm. The grain size increases with dose, and follows a power law (n=6) to a saturation value of ~30 nm that decreases with temperature. Slower grain growth is observed under 400 K irradiations, as compared to 160 K irradiations, indicating that the grain growth is not thermally activated and irradiation-induced grain growth is the dominating mechanism. While the cubic structure is retained and no new phases are identified after the high-dose irradiations, oxygen reduction in the irradiated NSZ films is detected. The ratio of O to Zr decreases from ~2.0 for the as-deposited films to ~1.65 after irradiation to ~35 dpa. The loss of oxygen suggests a significant increase of oxygen vacancies in nanocrystalline zirconia under ion irradiation. The oxygen deficiency may be essential in stabilizing the cubic phase to larger grain sizes.

  5. Oxide shell reduction and magnetic property changes in core-shell Fe nanoclusters under ion irradiation

    SciTech Connect (OSTI)

    Sundararajan, Jennifer A.; Kaur, Maninder; Qiang, You, E-mail: youqiang@uidaho.edu [Department of Physics, University of Idaho, Moscow, Idaho 83844 (United States); Jiang, Weilin [Pacific Northwest National Laboratory, P.O. Box 999, Richland, Washington 99352 (United States); McCloy, John S. [School of Mechanical and Materials Engineering, Washington State University, Pullman, Washington 99164 (United States)

    2014-05-07

    Ion irradiation effects are studied on the Fe-based core-shell nanocluster (NC) films with core as Fe and shell as Fe{sub 3}O{sub 4}/Fe{sub 3}N. These NC films were deposited on Si substrates to thickness of ?0.5 ?m using a NC deposition system. The films were irradiated at room temperature with 5.5?MeV Si{sup 2+} ions to ion fluences of 10{sup 15} and 10{sup 16} ions/cm{sup 2}. It is found that the irradiation induces grain growth, Fe valence reduction in the shell, and crystallization or growth of Fe{sub 3}N. The film retained its Fe-core and its ferromagnetic properties after irradiation. The nature and mechanism of oxide shell reduction and composition dependence after irradiation were studied by synthesizing additional NC films of Fe{sub 3}O{sub 4} and FeO?+?Fe{sub 3}N and irradiating them under the same conditions. The presence of nanocrystalline Fe is found to be a major factor for the oxide shell reduction. The surface morphologies of these films show dramatic changes in the microstructures due to cluster growth and agglomeration as a result of ion irradiation.

  6. Method for analyzing passive silicon carbide thermometry with a continuous dilatometer to determine irradiation temperature

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Campbell, Anne A.; Porter, Wallace D.; Katoh, Yutai; Snead, Lance Lewis

    2016-01-14

    Silicon carbide is used as a passive post-irradiation temperature monitor because the irradiation defects will anneal out above the irradiation temperature. The irradiation temperature is determined by measuring a property change after isochronal annealing, i.e., lattice spacing, dimensions, electrical resistivity, thermal diffusivity, or bulk density. However, such methods are time-consuming since the steps involved must be performed in a serial manner. This work presents the use of thermal expansion from continuous dilatometry to calculate the SiC irradiation temperature, which is an automated process requiring minimal setup time. Analysis software was written that performs the calculations to obtain the irradiation temperaturemore » and removes possible user-introduced error while standardizing the analysis. In addition, this method has been compared to an electrical resistivity and isochronal annealing investigation, and the results revealed agreement of the calculated temperatures. These results show that dilatometry is a reliable and less time-intensive process for determining irradiation temperature from passive SiC thermometry.« less

  7. JOYO-1 Irradiation Test Campaign Technical Close-out, For Information

    SciTech Connect (OSTI)

    G. Borges

    2006-01-31

    The JOYO-1 irradiation testing was designed to screen the irradiation performance of candidate cladding, structural and reflector materials in support of space reactor development. The JOYO-1 designation refers to the first of four planned irradiation tests in the JOYO reactor. Limited irradiated material performance data for the candidate materials exists for the expected Prometheus-1 duration, fluences and temperatures. Materials of interest include fuel element cladding and core materials (refractory metal alloys and silicon carbide (Sic)), vessel and plant structural materials (refractory metal alloys and nickel-base superalloys), and control and reflector materials (BeO). Key issues to be evaluated were long term microstructure and material property stability. The JOYO-1 test campaign was initiated to irradiate a matrix of specimens at prototypical temperatures and fluences anticipated for the Prometheus-1 reactor [Reference (1)]. Enclosures 1 through 9 describe the specimen and temperature monitors/dosimetry fabrication efforts, capsule design, disposition of structural material irradiation rigs, and plans for post-irradiation examination. These enclosures provide a detailed overview of Naval Reactors Prime Contractor Team (NRPCT) progress in specific areas; however, efforts were in various states of completion at the termination of NRPCT involvement with and restructuring of Project Prometheus.

  8. EVALUATION OF U10MO FUEL PLATE IRRADIATION BEHAVIOR VIA NUMERICAL AND EXPERIMENTAL BENCHMARKING

    SciTech Connect (OSTI)

    Samuel J. Miller; Hakan Ozaltun

    2012-11-01

    This article analyzes dimensional changes due to irradiation of monolithic plate-type nuclear fuel and compares results with finite element analysis of the plates during fabrication and irradiation. Monolithic fuel plates tested in the Advanced Test Reactor (ATR) at Idaho National Lab (INL) are being used to benchmark proposed fuel performance for several high power research reactors. Post-irradiation metallographic images of plates sectioned at the midpoint were analyzed to determine dimensional changes of the fuel and the cladding response. A constitutive model of the fabrication process and irradiation behavior of the tested plates was developed using the general purpose commercial finite element analysis package, Abaqus. Using calculated burn-up profiles of irradiated plates to model the power distribution and including irradiation behaviors such as swelling and irradiation enhanced creep, model simulations allow analysis of plate parameters that are either impossible or infeasible in an experimental setting. The development and progression of fabrication induced stress concentrations at the plate edges was of primary interest, as these locations have a unique stress profile during irradiation. Additionally, comparison between 2D and 3D models was performed to optimize analysis methodology. In particular, the ability of 2D and 3D models account for out of plane stresses which result in 3-dimensional creep behavior that is a product of these components. Results show that assumptions made in 2D models for the out-of-plane stresses and strains cannot capture the 3-dimensional physics accurately and thus 2D approximations are not computationally accurate. Stress-strain fields are dependent on plate geometry and irradiation conditions, thus, if stress based criteria is used to predict plate behavior (as opposed to material impurities, fine micro-structural defects, or sharp power gradients), unique 3D finite element formulation for each plate is required.

  9. Advanced Gas Reactor (AGR)-5/6/7 Fuel Irradiation Experiments in the Advanced Test Reactor

    SciTech Connect (OSTI)

    A. Joseph Palmer; David A. Petti; S. Blaine Grover

    2014-04-01

    The United States Department of Energys Very High Temperature Reactor (VHTR) Advanced Gas Reactor (AGR) Fuel Development and Qualification Program will be irradiating up to seven separate low enriched uranium (LEU) tri-isotopic (TRISO) particle fuel (in compact form) experiments in the Advanced Test Reactor (ATR) located at the Idaho National Laboratory (INL). These irradiations and fuel development are being accomplished to support development of the next generation reactors in the United States. The goals of the irradiation experiments are to provide irradiation performance data to support fuel process development, to qualify fuel for normal operating conditions, to support development and validation of fuel performance and fission product transport models and codes, and to provide irradiated fuel and materials for post irradiation examination (PIE) and safety testing. The experiments, which each consist of at least five separate capsules, are being irradiated in an inert sweep gas atmosphere with individual on-line temperature monitoring and control of each capsule. The sweep gases also have on-line fission product monitoring the effluent from each capsule to track performance of the fuel during irradiation. The first two experiments (designated AGR-1 and AGR-2), have been completed. The third and fourth experiments have been combined into a single experiment designated AGR-3/4, which started its irradiation in December 2011 and is currently scheduled to be completed in April 2014. The design of the fuel qualification experiment, designated AGR-5/6/7, is well underway and incorporates lessons learned from the three previous experiments. Various design issues will be discussed with particular details related to selection of thermometry.

  10. Bright x-ray sources from laser irradiation of foams with high

    Office of Scientific and Technical Information (OSTI)

    concentration of Ti (Journal Article) | SciTech Connect Bright x-ray sources from laser irradiation of foams with high concentration of Ti Citation Details In-Document Search Title: Bright x-ray sources from laser irradiation of foams with high concentration of Ti Low-density foams irradiated by a 20 kJ laser at the Omega laser facility (Laboratory for Laser Energetics, Rochester, NY, USA) are shown to convert more than 5% of the laser energy into 4.6 to 6.0 keV x rays. This record

  11. Photoinduced currents in pristine and ion irradiated kapton-H polyimide

    SciTech Connect (OSTI)

    Sharma, Anu Sridharbabu, Y. Quamara, J. K.

    2014-10-15

    The photoinduced currents in pristine and ion irradiated kapton-H polyimide have been investigated for different applied electric fields at 200C. Particularly the effect of illumination intensity on the maximum current obtained as a result of photoinduced polarization has been studied. Samples were irradiated by using PELLETRON facility, IUAC, New Delhi. The photo-carrier charge generation depends directly on intensity of illumination. The samples irradiated at higher fluence show a decrease in the peak current with intensity of illumination. The secondary radiation induced crystallinity (SRIC) is responsible for the increase in maximum photoinduced currents generated with intensity of illumination.

  12. TH-C-12A-03: Development of Expanded Field Irradiation Technique with

    Office of Scientific and Technical Information (OSTI)

    Gimbaled X-Ray Head (Journal Article) | SciTech Connect TH-C-12A-03: Development of Expanded Field Irradiation Technique with Gimbaled X-Ray Head Citation Details In-Document Search Title: TH-C-12A-03: Development of Expanded Field Irradiation Technique with Gimbaled X-Ray Head Purpose: The Vero4DRT has a maximum field size of 150×150 mm{sup 2}. The purposes of this study were to develop an expanded field irradiation technique using a unique gimbaled x-ray head of Vero4DRT and to evaluate

  13. Atomic configuration of irradiation-induced planar defects in 3C-SiC

    SciTech Connect (OSTI)

    Lin, Y. R. [Department of Engineering and System Science, National Tsing-Hua University, Hsinchu 30013, Taiwan (China); National Synchrotron Radiation Center, 101 Hsin-Ann Road, Hsinchu Science Park, Hsinchu 30076, Taiwan (China); Ho, C. Y. [Institute of Nuclear Engineering and Science, National Tsing-Hua University, Hsinchu 30013, Taiwan (China); Hsieh, C. Y.; Chang, M. T.; Lo, S. C. [Material and Chemical Research Laboratories, Industrial Technology Research Institute, Hsinchu 31040, Taiwan (China); Chen, F. R. [Department of Engineering and System Science, National Tsing-Hua University, Hsinchu 30013, Taiwan (China); Kai, J. J., E-mail: ceer0001@gmail.com [Department of Engineering and System Science, National Tsing-Hua University, Hsinchu 30013, Taiwan (China); Institute of Nuclear Engineering and Science, National Tsing-Hua University, Hsinchu 30013, Taiwan (China)

    2014-03-24

    The atomic configuration of irradiation-induced planar defects in single crystal 3C-SiC at high irradiation temperatures was shown in this research. A spherical aberration corrected scanning transmission electron microscope provided images of individual silicon and carbon atoms by the annular bright-field (ABF) method. Two types of irradiation-induced planar defects were observed in the ABF images including the extrinsic stacking fault loop with two offset Si-C bilayers and the intrinsic stacking fault loop with one offset Si-C bilayer. The results are in good agreement with images simulated under identical conditions.

  14. Irradiation-induced nano-voids in strained tin precipitates in silicon

    SciTech Connect (OSTI)

    Gaiduk, P. I., E-mail: gaiduk@phys.au.dk [Department of Physics and Astronomy/iNANO, Aarhus University, Gustav Wieds Vej 14, DK-8000 Aarhus C (Denmark); Department of Physical Electronics and Nanotechnology, Belarusian State University, prosp. Nezavisimosti, 4, 220030 Minsk (Belarus); Lundsgaard Hansen, J., E-mail: johnlh@phys.au.dk; Nylandsted Larsen, A., E-mail: anl@phys.au.dk [Department of Physics and Astronomy/iNANO, Aarhus University, Gustav Wieds Vej 14, DK-8000 Aarhus C (Denmark)

    2014-04-14

    We report on self-assembling of spherically shaped voids in nanometer size strained Sn precipitates after irradiation with He{sup +} ions in different conditions. It is found that high-temperature irradiation induces vacancies which are collected by compressively strained Sn precipitates enhancing of out-diffusion of Sn atoms from the precipitates. Nano-voids formation takes place simultaneously with a ?- to ?-phase transformation in the Sn precipitates. Post-irradiation thermal treatment leads to the removal of voids and a backward transformation of the Sn phase to ?-phase. Strain-enhanced separation of point defects along with vacancy assisted Sn out-diffusion and precipitate dissolution are discussed.

  15. Effects of irradiation on the mechanical behavior of twined SiC nanowires

    SciTech Connect (OSTI)

    Jin Enze; Niu Lisha; Lin Enqiang; Duan Zheng [AML, Department of Engineering Mechanics, Tsinghua University, Beijing 100084 (China)

    2013-03-14

    Irradiation is known to bring new features in one-dimensional nano materials. In this study, we used molecular dynamics simulations to investigate the irradiation effects on twined SiC nanowires. Defects tend to accumulate from outside toward inside of the twined SiC nanowires with increasing irradiation dose, leading to a transition from brittle to ductile failure under tensile load. Atomic chains are formed in the ductile failure process. The first-principles calculations show that most of the atomic chains are metallic.

  16. Irradiation-induced grain growth in nanocrystalline reduced activation ferrite/martensite steel

    SciTech Connect (OSTI)

    Liu, W. B.; Chen, L. Q. [Key Laboratory of Advanced Materials of Ministry of Education, School of Materials Science and Engineering, Tsinghua University, Beijing 100084 (China); Department of Materials Science and Engineering, The Pennsylvania State University, University Park, Pennsylvania 16802 (United States); Zhang, C., E-mail: chizhang@tsinghua.edu.cn; Yang, Z. G. [Key Laboratory of Advanced Materials of Ministry of Education, School of Materials Science and Engineering, Tsinghua University, Beijing 100084 (China); Ji, Y. Z. [Department of Materials Science and Engineering, The Pennsylvania State University, University Park, Pennsylvania 16802 (United States); Zang, H. [Department of Nuclear Science and Technology, Xi'an Jiaotong University, Xi'an 710049 (China); Shen, T. L. [Institute of Modern Physics, Chinese Academy of Science, Lanzhou 730000 (China)

    2014-09-22

    In this work, we investigate the microstructure evolution of surface-nanocrystallized reduced activation ferrite/martensite steels upon high-dose helium ion irradiation (24.3 dpa). We report a significant irradiation-induced grain growth in the irradiated buried layer at a depth of 300500?nm, rather than at the peak damage region (at a depth of ?840?nm). This phenomenon can be explained by the thermal spike model: minimization of the grain boundary (GB) curvature resulting from atomic diffusion in the cascade center near GBs.

  17. System for target irradiation in the Iskra-6 high-power laser facility

    SciTech Connect (OSTI)

    Bondarenko, S V; Garanin, Sergey G; Eroshenko, V A; Kochemasov, G G; L'vov, L V; Mochalov, M R

    1999-03-31

    An analysis is made of various systems for direct irradiation of a target enabling achievement of a high degree of the irradiation uniformity. The required departure from uniformity of target irradiation, {delta}I/I {<=} 1% - 2%, may be attained when the number of laser beams is N {>=} 80, the diameter of the waist is approximately equal to the target diameter, and the intensity profile in the waist is Gaussian or super-Gaussian. Various methods of forming the necessary intensity distribution in a transverse cross section of a beam are considered. (interaction of laser radiation with matter. laser plasma)

  18. Concurrent in situ ion irradiation transmission electron microscope

    SciTech Connect (OSTI)

    Hattar, K.; Bufford, D. C.; Buller, D. L.

    2014-08-29

    An in situ ion irradiation transmission electron microscope has been developed and is operational at Sandia National Laboratories. This facility permits high spatial resolution, real time observation of electron transparent samples under ion irradiation, implantation, mechanical loading, corrosive environments, and combinations thereof. This includes the simultaneous implantation of low-energy gas ions (0.830 keV) during high-energy heavy ion irradiation (0.848 MeV). In addition, initial results in polycrystalline gold foils are provided to demonstrate the range of capabilities.

  19. Cool covered sky-splitting spectrum-splitting FK

    SciTech Connect (OSTI)

    Mohedano, Rubn; Chaves, Julio; Falicoff, Waqidi; Hernandez, Maikel; Sorgato, Simone; Miano, Juan C.; Benitez, Pablo; Buljan, Marina

    2014-09-26

    Placing a plane mirror between the primary lens and the receiver in a Fresnel Khler (FK) concentrator gives birth to a quite different CPV system where all the high-tech components sit on a common plane, that of the primary lens panels. The idea enables not only a thinner device (a half of the original) but also a low cost 1-step manufacturing process for the optics, automatic alignment of primary and secondary lenses, and cell/wiring protection. The concept is also compatible with two different techniques to increase the module efficiency: spectrum splitting between a 3J and a BPC Silicon cell for better usage of Direct Normal Irradiance DNI, and sky splitting to harvest the energy of the diffuse radiation and higher energy production throughout the year. Simple calculations forecast the module would convert 45% of the DNI into electricity.

  20. Irradiation Experiment Conceptual Design Parameters for NBSR Fuel Conversion

    SciTech Connect (OSTI)

    Brown N. R.; Brown,N.R.; Baek,J.S; Hanson, A.L.; Cuadra,A.; Cheng,L.Y.; Diamond, D.J.

    2013-03-31

    It has been proposed to convert the National Institute of Standards and Technology (NIST) research reactor, known as the NBSR, from high-enriched uranium (HEU) fuel to low-enriched uranium (LEU) fuel. The motivation to convert the NBSR to LEU fuel is to reduce the risk of proliferation of special nuclear material. This report is a compilation of relevant information from recent studies related to the proposed conversion using a metal alloy of LEU with 10 w/o molybdenum. The objective is to inform the design of the mini-plate and full-size plate irradiation experiments that are being planned. This report provides relevant dimensions of the fuel elements, and the following parameters at steady state: average and maximum fission rate density and fission density, fuel temperature distribution for the plate with maximum local temperature, and two-dimensional heat flux profiles of fuel plates with high power densities. . The latter profiles are given for plates in both the inner and outer core zones and for cores with both fresh and depleted shim arms (reactivity control devices). In addition, a summary of the methodology to obtain these results is presented.

  1. Replacement of tritiated water from irradiated fuel storage bay

    SciTech Connect (OSTI)

    Castillo, I.; Boniface, H.; Suppiah, S.; Kennedy, B.; Minichilli, A.; Mitchell, T.

    2015-03-15

    Recently, AECL developed a novel method to reduce tritium emissions (to groundwater) and personnel doses at the NRU (National Research Universal) reactor irradiated fuel storage bay (also known as rod or spent fuel bay) through a water swap process. The light water in the fuel bay had built up tritium that had been transferred from the heavy water moderator through normal fuel transfers. The major advantage of the thermal stratification method was that a very effective tritium reduction could be achieved by swapping a minimal volume of bay water and warm tritiated water would be skimmed off the bay surface. A demonstration of the method was done that involved Computational Fluid Dynamics (CFD) modeling of the swap process and a test program that showed excellent agreement with model prediction for the effective removal of almost all the tritium with a minimal water volume. Building on the successful demonstration, AECL fabricated, installed, commissioned and operated a full-scale system to perform a water swap. This full-scale water swap operation achieved a tritium removal efficiency of about 96%.

  2. RERTR-12 Post-irradiation Examination Summary Report

    SciTech Connect (OSTI)

    Rice, Francine; Williams, Walter; Robinson, Adam; Harp, Jason; Meyer, Mitch; Rabin, Barry

    2015-02-01

    The following report contains the results and conclusions for the post irradiation examinations performed on RERTR-12 Insertion 2 experiment plates. These exams include eddy-current testing to measure oxide growth; neutron radiography for evaluating the condition of the fuel prior to sectioning and determination of fuel relocation and geometry changes; gamma scanning to provide relative measurements for burnup and indication of fuel- and fission-product relocation; profilometry to measure dimensional changes of the fuel plate; analytical chemistry to benchmark the physics burnup calculations; metallography to examine the microstructural changes in the fuel, interlayer and cladding; and microhardness testing to determine the material-property changes of the fuel and cladding. These characterization activities are tailored specifically to define: The mechanical response of fuel meat, cladding, and interlayers, including diffusion barrier integrity Whether geometry is stable and predictable; that changes in channel gap do not compromise ability to cool fuel That fuel performance is known and predictable A limited set of physical properties that are important for the analysis of fuel burnup limits Whether swelling is stable and predictable.

  3. Stress-enhanced swelling of metal during irradiation

    SciTech Connect (OSTI)

    Garner, F.A.; Gilbert, E.R.; Porter, D.L.

    1980-04-01

    Data are available which show that stress plays a major role in the development of radiation-induced void growth in AISI 316 and many other alloys. Earlier experiments came to the opposite conclusion and are shown to have investigated stress levels which inadvertantly cold-worked the material. Stress-affected swelling spans the entire temperature range in fast reactor irradiations and accelerates with increasing irradiatin temperature. It also appears to operate in all alloy starting conditions investigated. Two major microstructural mechanisms appear to be causing the enhancement of swelling, which for tensile stresses is manifested primarily as a decrease in the incubation period. These mechanisms are stress-induced changes in the interstitial capture efficiency of voids and stress-induced changes in the vacancy emission rate of various microstructural components. There also appears to be an enhancement of intermetallic phase formation with applied stress and this is shown to increase swelling by accelerating the microchemical evolution that precedes void growth at high temperature. This latter consideration complicates the extrapolation of these data to compressive stress states.

  4. Cross-linking of polytetrafluoroethylene during room-temperature irradiation

    SciTech Connect (OSTI)

    Pugmire, David L; Wetteland, Chris J; Duncan, Wanda S; Lakis, Rollin E; Schwartz, Daniel S

    2008-01-01

    Exposure of polytetrafluoroethylene (PTFE) to {alpha}-radiation was investigated to detennine the physical and chemical effects, as well as to compare and contrast the damage mechanisms with other radiation types ({beta}, {gamma}, or thermal neutron). A number of techniques were used to investigate the chemical and physical changes in PTFE after exposure to {alpha}-radiation. These techniques include: Fourier transform infrared spectroscopy (FTIR), differential scanning calorimetry (DSC), and fluorescence spectroscopy. Similar to other radiation types at low doses, the primary damage mechanism for the exposure of PTFE to {alpha}-radiation appears to be chain scission. Increased doses result in a change-over of the damage mechanism to cross-linking. This result is not observed for any radiation type other than {alpha} when irradiation is performed at room temperature. Finally, at high doses, PTFE undergoes mass-loss (via smallfluorocarbon species evolution) and defluorination. The amount and type of damage versus sample depth was also investigated. Other types of radiation yield damage at depths on the order of mm to cm into PTFE due to low linear energy transfer (LET) and the correspondingly large penetration depths. By contrast, the {alpha}-radiation employed in this study was shown to only induce damage to a depth of approximately 26 {mu}m, except at very high doses.

  5. Irradiation Experiment Conceptual Design Parameters for NBSR Fuel Conversion

    SciTech Connect (OSTI)

    Brown, N. R.; Brown, N. R.; Baek, J. S; Hanson, A. L.; Cuadra, A.; Cheng, L. Y.; Diamond, D. J.

    2014-04-30

    It has been proposed to convert the National Institute of Standards and Technology (NIST) research reactor, known as the NBSR, from high-enriched uranium (HEU) fuel to low-Enriched uranium (LEU) fuel. The motivation to convert the NBSR to LEU fuel is to reduce the risk of proliferation of special nuclear material. This report is a compilation of relevant information from recent studies related to the proposed conversion using a metal alloy of LEU with 10 w/o molybdenum. The objective is to inform the design of the mini-plate and full-size-Plate irradiation experiments that are being planned. This report provides relevant dimensions of the fuel elements, and the following parameters at steady state: average and maximum fission rate density and fission density, fuel temperature distribution for the plate with maximum local temperature, and two-dimensional heat flux profiles of fuel plates with high power densities. The latter profiles are given for plates in both the inner and outer core zones and for cores with both fresh and depleted shim arms (reactivity control devices). A summary of the methodology to obtain these results is presented. Fuel element tolerance assumptions and hot channel factors used in the safety analysis are also given.

  6. Status of the NGNP Graphite Creep Experiments AGC-1 and AGC-2 Irradiated in the Advanced Test Reactor

    SciTech Connect (OSTI)

    Blaine Grover

    2012-10-01

    The United States Department of Energys Next Generation Nuclear Plant (NGNP) Program will be irradiating six nuclear graphite creep experiments in the Advanced Test Reactor (ATR) located at the Idaho National Laboratory (INL). The graphite experiments will be irradiated over the next six to eight years to support development of a graphite irradiation performance data base on the new nuclear grade graphites now available for use in high temperature gas reactors. The goals of the irradiation experiments are to obtain irradiation performance data, including irradiation creep, at different temperatures and loading conditions to support design of the Next Generation Nuclear Plant (NGNP) Very High Temperature Gas Reactor, as well as other future gas reactors. The experiments will each consist of a single capsule that will contain six peripheral stacks of graphite specimens, with half of the graphite specimens in each stack under a compressive load, while the other half of the specimens will not be subjected to a compressive load during irradiation. The six peripheral stacks will have different compressive loads applied to the top half of each pair of specimen stacks, while a seventh stack will not have a compressive load. The specimens will be irradiated in an inert sweep gas atmosphere with on-line temperature and compressive load monitoring and control. There will also be sampling the sweep gas effluent to determine if any oxidation or off-gassing of the specimens occurs during irradiation of the experiment. The first experiment, AGC-1, started its irradiation in September 2009, and the irradiation was completed in January 2011. The second experiment, AGC-2, started its irradiation in April 2011 and completed its irradiation in May 2012. This paper will briefly discuss the design of the experiment and control systems, and then present the irradiation results for each experiment to date.

  7. TH-C-12A-03: Development of Expanded Field Irradiation Technique...

    Office of Scientific and Technical Information (OSTI)

    TH-C-12A-03: Development of Expanded Field Irradiation Technique with Gimbaled X-Ray Head Citation Details In-Document Search Title: TH-C-12A-03: Development of Expanded Field ...

  8. Optimal measurement of surface shortwave irradiance using current instrumentation -- the ARM experience

    SciTech Connect (OSTI)

    Michalsky, J.; Rubes, M.; Stoffel, T.; Wesley, M.; Splitt, M.; DeLuisi, J.

    1997-03-01

    Shortwave (solar) measurements of surface irradiance for clear sky conditions disagree with a number of different models. Betts used the European Center for Medium-range Forecasts (ECMWF) shortwave model to calculate surface irradiance that were 5-10 percent higher than measurements. Wild used a different formulation of the ECMWF shortwave model, but found that the model overpredicted clear-sky shortwave and average of 3 percent. Ding and Wang used data from the Atmospheric Radiation Measurement (ARM) program and found that the GENESIS GCM shortwave model, likewise, overpredicted clear-sky irradiance by about 4 percent. To help resolve the measurement dilemma, reference instruments were deployed in April 1996 at the Southern Great Plains ARM site central facility very near the shortwave measurements. The rest of the paper describes the experiment undertaken to ascertain total horizontal shortwave irradiance at the surface, including a separation of the direct normal and diffuse horizontal components. Results and a discussion of same concludes the paper.

  9. Nonlinear increase of X-ray intensities from thin foils irradiated...

    Office of Scientific and Technical Information (OSTI)

    increase of X-ray intensities from thin foils irradiated with a 200 TW femtosecond laser Citation Details In-Document Search Title: Nonlinear increase of X-ray intensities...

  10. EIS-0017: Fusion Materials Irradiation Testing Facility, Hanford Reservation, Richland, Washington

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy developed this statement to evaluate the environmental impacts associated with proposed construction and operation of an irradiation test facility, the Deuterium-Lithium High Flux Neutron Source Facility, at the Hanford Reservation.

  11. Neutron Irradiation of Hydrided Cladding Material in HFIR Summary of Initial Activities

    Broader source: Energy.gov [DOE]

    Irradiation is known to have a significant impact on the properties and performance of Zircaloy cladding and structural materials (material degradation processes, e.g., effects of hydriding).  This...

  12. Modeling the irradiance and temperature rependence of photovoltaic modules in PVsyst

    SciTech Connect (OSTI)

    Sauer, Kenneth J.; Roessler, Thomas; Hansen, Clifford W.

    2014-11-10

    In order to reliably simulate the energy yield of photovoltaic (PV) systems, it is necessary to have an accurate model of how the PV modules perform with respect to irradiance and cell temperature. Building on previous work that addresses the irradiance dependence, two approaches to fit the temperature dependence of module power in PVsyst have been developed and are applied here to recent multi-irradiance and -temperature data for a standard Yingli Solar PV module type. The results demonstrate that it is possible to match the measured irradiance and temperature dependence of PV modules in PVsyst. As a result, improvements in energy yield prediction using the optimized models relative to the PVsyst standard model are considered significant for decisions about project financing.

  13. Characterization of LWRS Hybrid SiC-CMC-Zircaloy-4 Fuel Cladding after Gamma Irradiation

    SciTech Connect (OSTI)

    Isabella J van Rooyen

    2012-09-01

    The purpose of the gamma irradiation tests conducted at the Idaho National Laboratory (INL) was to obtain a better understanding of chemical interactions and potential changes in microstructural properties of a mock-up hybrid nuclear fuel cladding rodlet design (unfueled) in a simulated PWR water environment under irradiation conditions. The hybrid fuel rodlet design is being investigated under the Light Water Reactor Sustainability (LWRS) program for further development and testing of one of the possible advanced LWR nuclear fuel cladding designs. The gamma irradiation tests were performed in preparation for neutron irradiation tests planned for a silicon carbide (SiC) ceramic matrix composite (CMC) zircaloy-4 (Zr-4) hybrid fuel rodlet that may be tested in the INL Advanced Test Reactor (ATR) if the design is selected for further development and testing

  14. Modeling the irradiance and temperature rependence of photovoltaic modules in PVsyst

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sauer, Kenneth J.; Roessler, Thomas; Hansen, Clifford W.

    2014-11-10

    In order to reliably simulate the energy yield of photovoltaic (PV) systems, it is necessary to have an accurate model of how the PV modules perform with respect to irradiance and cell temperature. Building on previous work that addresses the irradiance dependence, two approaches to fit the temperature dependence of module power in PVsyst have been developed and are applied here to recent multi-irradiance and -temperature data for a standard Yingli Solar PV module type. The results demonstrate that it is possible to match the measured irradiance and temperature dependence of PV modules in PVsyst. As a result, improvements inmore » energy yield prediction using the optimized models relative to the PVsyst standard model are considered significant for decisions about project financing.« less

  15. Assessment of Initial Test Conditions for Experiments to Assess Irradiation Assisted Stress Corrosion Cracking Mechanisms

    Broader source: Energy.gov [DOE]

    Irradiation-assisted stress corrosion cracking is a key materials degradation issue in today’s nuclear power reactor fleet and affects critical structural components within the reactor core. The...

  16. Formation of TiO{sub 2} nanorods by ion irradiation

    SciTech Connect (OSTI)

    Zheng, X. D.; Ren, F., E-mail: fren@whu.edu.cn; Cai, G. X.; Hong, M. Q.; Xiao, X. H.; Wu, W.; Liu, Y. C.; Li, W. Q.; Ying, J. J.; Jiang, C. Z. [School of Physics and Technology, Center for Ion Beam Application and Center for Electron Microscopy, Wuhan University, Wuhan 430072 (China)

    2014-05-14

    Ion beam irradiation is a powerful method to fabricate and tailor the nanostructured surface of materials. Nanorods on the surface of single crystal rutile TiO{sub 2} were formed by N{sup +} ion irradiation. The dependence of nanorod morphology on ion fluence and energy was elaborated. With increasing ion fluence, nanopores grow in one direction perpendicular to the surface and burst finally to form nanorods. The length of nanorods increases with increasing ion energy under same fluence. The development of the nanorod structure is originated from the formation of the nanopores while N{sub 2} bubbles and aggregation of vacancies were responsible for the formation of nanopores and nanorods. Combining C{sup +} ion irradiation and post-irradiation annealing experiments, two qualitative models are proposed to explain the formation mechanism of these nanorods.

  17. PHASE-FIELD SIMULATION OF IRRADIATED METALS PART i: VOID KINETICS...

    Office of Scientific and Technical Information (OSTI)

    METALS PART i: VOID KINETICS Citation Details In-Document Search Title: PHASE-FIELD SIMULATION OF IRRADIATED METALS PART i: VOID KINETICS We present a phase-field model of void ...

  18. PHASE-FIELD SIMULATION OF IRRADIATED METALS: PART II: GAS BUBBLE...

    Office of Scientific and Technical Information (OSTI)

    METALS: PART II: GAS BUBBLE KINETICS Citation Details In-Document Search Title: PHASE-FIELD SIMULATION OF IRRADIATED METALS: PART II: GAS BUBBLE KINETICS We present a phase-field ...

  19. Transmission electron microscopy of oxide dispersion strengthened (ODS) molybdenum: effects of irradiation on material microstructure

    SciTech Connect (OSTI)

    Baranwal, R. and Burke, M.G.

    2003-03-03

    Oxide dispersion strengthened (ODS) molybdenum has been characterized using transmission electron microscopy (TEM) to determine the effects of irradiation on material microstructure. This work describes the results-to-date from TEM characterization of unirradiated and irradiated ODS molybdenum. The general microstructure of the unirradiated material consists of fine molybdenum grains (< 5 {micro}m average grain size) with numerous low angle boundaries and isolated dislocation networks. 'Ribbon'-like lanthanum oxides are aligned along the working direction of the product form and are frequently associated with grain boundaries, serving to inhibit grain boundary and dislocation movement. In addition to the 'ribbons', discrete lanthanum oxide particles have also been detected. After irradiation, the material is characterized by the presence of nonuniformly distributed large ({approx} 20 to 100 nm in diameter), multi-faceted voids, while the molybdenum grain size and oxide morphology appear to be unaffected by irradiation.

  20. Status of the Combined Third and Fourth NGNP Fuel Irradiations In the Advanced Test Reactor

    SciTech Connect (OSTI)

    S. Blaine Grover; David A. Petti; Michael E. Davenport

    2013-07-01

    The United States Department of Energys Next Generation Nuclear Plant (NGNP) Advanced Gas Reactor (AGR) Fuel Development and Qualification Program is irradiating up to seven low enriched uranium (LEU) tri-isotopic (TRISO) particle fuel (in compact form) experiments in the Advanced Test Reactor (ATR) located at the Idaho National Laboratory (INL). These irradiations and fuel development are being accomplished to support development of the next generation reactors in the United States. The experiments will be irradiated over the next several years to demonstrate and qualify new TRISO coated particle fuel for use in high temperature gas reactors. The goals of the experiments are to provide irradiation performance data to support fuel process development, to qualify fuel for normal operating conditions, to support development and validation of fuel performance and fission product transport models and codes, and to provide irradiated fuel and materials for post irradiation examination (PIE) and safety testing. The experiments, which will each consist of several independent capsules, will be irradiated in an inert sweep gas atmosphere with individual on-line temperature monitoring and control of each capsule. The sweep gas will also have on-line fission product monitoring on its effluent to track performance of the fuel in each individual capsule during irradiation. The first experiment (designated AGR-1) started irradiation in December 2006 and was completed in November 2009. The second experiment (AGR-2) started irradiation in June 2010 and is currently scheduled to be completed in September 2013. The third and fourth experiments have been combined into a single experiment designated (AGR-3/4), which started its irradiation in December 2011 and is currently scheduled to be completed in April 2014. Since the purpose of this combined experiment is to provide data on fission product migration and retention in the NGNP reactor, the design of this experiment is significantly different from the first two experiments, though the control and monitoring systems are extremely similar. The design of the experiment will be discussed followed by its progress and status to date.

  1. Increase of bulk optical damage threshold fluences of KDP crystals by laser irradiation and heat treatment

    DOE Patents [OSTI]

    Swain, J.E.; Stokowski, S.E.; Milam, D.; Kennedy, G.C.; Rainer, F.

    1982-07-07

    The bulk optical damage threshold fluence of potassium dihydrogen phosphate (KDP) crystals is increased by irradiating the crystals with laser pulses of duration 1 to 20 nanoseconds of increasing fluence, below the optical damage threshold fluence for untreated crystals, or by baking the crystals for times of the order of 24 hours at temperatures of 110 to 165/sup 0/C, or by a combination of laser irradiation and baking.

  2. Dose dependence of mechanical properties in tantalum and tantalum alloys after low temperature irradiation

    SciTech Connect (OSTI)

    Byun, Thak Sang

    2008-01-01

    The dose dependence of mechanical properties was investigated for tantalum and tantalum alloys after low temperature irradiation. Miniature tensile specimens of three pure tantalum metals, ISIS Ta, Aesar Ta1, Aesar Ta2, and one tantalum alloy, Ta-1W, were irradiated by neutrons in the High Flux Isotope Reactor (HFIR) at ORNL to doses ranging from 0.00004 to 0.14 displacements per atom (dpa) in the temperature range 60 C 100 oC. Also, two tantalum-tungsten alloys, Ta-1W and Ta-10W, were irradiated by protons and spallation neutrons in the LANSCE facility at LANL to doses ranging from 0.7 to 7.5 dpa and from 0.7 to 25.2 dpa, respectively, in the temperature range 50 C 160 oC. Tensile tests were performed at room temperature and at 250oC at nominal strain rates of about 10-3 s-1. All neutron-irradiated materials underwent progressive irradiation hardening and loss of ductility with increasing dose. The ISIS Ta experienced embrittlement at 0.14 dpa, while the other metals retained significant necking ductility. Such a premature embrittlement in ISIS Ta is believed to be because of high initial oxygen concentrations picked up during a pre-irradiation anneal. The Ta-1W and Ta-10W specimens irradiated in spallation condition experienced prompt necking at yield since irradiation doses for those specimens were high ( 0.7 dpa). At the highest dose, 25.2 dpa, the Ta-10W alloy specimen broke with little necking strain. Among the test materials, the Ta-1W alloy displayed the best combination of strength and ductility. The plastic instability stress and true fracture stress were nearly independent of dose. Increasing test temperature decreased strength and delayed the onset of necking at yield.

  3. PHASE-FIELD SIMULATION OF IRRADIATED METALS PART i: VOID KINETICS (Journal

    Office of Scientific and Technical Information (OSTI)

    Article) | SciTech Connect METALS PART i: VOID KINETICS Citation Details In-Document Search Title: PHASE-FIELD SIMULATION OF IRRADIATED METALS PART i: VOID KINETICS We present a phase-field model of void formation and evolution in irradiated metals by spatially and temporally evolving vacancy and self-interstitial concentration fields. By incorporating a coupled set of Cahn-Hilliard and Allen-Cahn equations, the model captures the processes of point defect generation and recombination,

  4. PHASE-FIELD SIMULATION OF IRRADIATED METALS: PART II: GAS BUBBLE KINETICS

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect METALS: PART II: GAS BUBBLE KINETICS Citation Details In-Document Search Title: PHASE-FIELD SIMULATION OF IRRADIATED METALS: PART II: GAS BUBBLE KINETICS We present a phase-field model for inert gas bubble formation and evolution in irradiated metals. The model evolves vacancy, self-interstitial, and fission gas atoms through a coupled set of Cahn-Hilliard and Allen-Cahn equations, capturing the processes of defect generation, recombination, annihilation

  5. Ultra high vacuum fracture and transfer device for AES analysis of irradiated austenitic stainless steel

    SciTech Connect (OSTI)

    Urie, M.W.; Panayotou, N.F.; Robinson, J.E.

    1980-01-01

    An ultrahigh vacuum fracture and transfer device for analysis of irradiated and non-irradiated SS 316 fuel cladding is described. Mechanical property tests used to study the behavior of cladding during reactor transient over-power conditions are reported. The stress vs temperature curves show minimal differences between unirradiated cladding and unfueled cladding. The fueled cladding fails at a lower temperature. All fueled specimens failed in an intergranular mode. (FS)

  6. The influence of mixed and phase clouds on surface shortwave irradiance during the Arctic spring

    SciTech Connect (OSTI)

    Lubin D.; Vogelmann A.

    2011-10-13

    The influence of mixed-phase stratiform clouds on the surface shortwave irradiance is examined using unique spectral shortwave irradiance measurements made during the Indirect and Semi-Direct Aerosol Campaign (ISDAC), supported by the U.S. Department of Energy Atmospheric Radiation Measurement (ARM) program. An Analytical Spectral Devices (ASD, Inc.) spectroradiometer measured downwelling spectral irradiance from 350 to 2200 nm in one-minute averages throughout April-May 2008 from the ARM Climate Research Facility's North Slope of Alaska (NSA) site at Barrow. This study examines spectral irradiance measurements made under single-layer, overcast cloud decks having geometric thickness < 3000 m. Cloud optical depth is retrieved from irradiance in the interval 1022-1033 nm. The contrasting surface radiative influences of mixed-phase clouds and liquid-water clouds are discerned using irradiances in the 1.6-{micro}m window. Compared with liquid-water clouds, mixed-phase clouds during the Arctic spring cause a greater reduction of shortwave irradiance at the surface. At fixed conservative-scattering optical depth (constant optical depth for wavelengths {lambda} < 1100 nm), the presence of ice water in cloud reduces the near-IR surface irradiance by an additional several watts-per-meter-squared. This additional reduction, or supplemental ice absorption, is typically {approx}5 W m{sup -2} near solar noon over Barrow, and decreases with increasing solar zenith angle. However, for some cloud decks this additional absorption can be as large as 8-10 W m{sup -2}.

  7. RTNS-II: irradiations at the Rotating Target Neutron Source-II. 1983 annual report

    SciTech Connect (OSTI)

    Not Available

    1983-01-01

    This is the second annual report summarizing irradiation experiments and operations at RTNS-II. It covers calendar year 1983 and includes reports on all irradiations, non-fusion as well as fusion, and on utilization of Monbusho's transmission electron microscope (TEM) a RTNS-II. Each summary article has been submitted by the investigator and has been altered only to meet the style and format requirements of this report.

  8. Correlation of Clinical and Dosimetric Factors With Adverse Pulmonary Outcomes in Children After Lung Irradiation

    SciTech Connect (OSTI)

    Venkatramani, Rajkumar; Kamath, Sunil; Wong, Kenneth; Malvar, Jemily; Sposto, Richard; Goodarzian, Fariba; Freyer, David R.; Keens, Thomas G.; and others

    2013-08-01

    Purpose: To identify the incidence and the risk factors for pulmonary toxicity in children treated for cancer with contemporary lung irradiation. Methods and Materials: We analyzed clinical features, radiographic findings, pulmonary function tests, and dosimetric parameters of children receiving irradiation to the lung fields over a 10-year period. Results: We identified 109 patients (75 male patients). The median age at irradiation was 13.8 years (range, 0.04-20.9 years). The median follow-up period was 3.4 years. The median prescribed radiation dose was 21 Gy (range, 0.4-64.8 Gy). Pulmonary toxic chemotherapy included bleomycin in 58.7% of patients and cyclophosphamide in 83.5%. The following pulmonary outcomes were identified and the 5-year cumulative incidence after irradiation was determined: pneumonitis, 6%; chronic cough, 10%; pneumonia, 35%; dyspnea, 11%; supplemental oxygen requirement, 2%; radiographic interstitial lung disease, 40%; and chest wall deformity, 12%. One patient died of progressive respiratory failure. Post-irradiation pulmonary function tests available from 44 patients showed evidence of obstructive lung disease (25%), restrictive disease (11%), hyperinflation (32%), and abnormal diffusion capacity (12%). Thoracic surgery, bleomycin, age, mean lung irradiation dose (MLD), maximum lung dose, prescribed dose, and dosimetric parameters between V{sub 22} (volume of lung exposed to a radiation dose ≥22 Gy) and V{sub 30} (volume of lung exposed to a radiation dose ≥30 Gy) were significant for the development of adverse pulmonary outcomes on univariate analysis. MLD, maximum lung dose, and V{sub dose} (percentage of volume of lung receiving the threshold dose or greater) were highly correlated. On multivariate analysis, MLD was the sole significant predictor of adverse pulmonary outcome (P=.01). Conclusions: Significant pulmonary dysfunction occurs in children receiving lung irradiation by contemporary techniques. MLD rather than prescribed dose should be used to perform risk stratification of patients receiving lung irradiation.

  9. FY 2013 Summary Report: Post-Irradiation Examination of Zircaloy-4 Samples

    Office of Environmental Management (EM)

    in Target Capsules and Initiation of Bending Fatigue Testing for Used Nuclear Fuel Vibration Integrity Investigations | Department of Energy Summary Report: Post-Irradiation Examination of Zircaloy-4 Samples in Target Capsules and Initiation of Bending Fatigue Testing for Used Nuclear Fuel Vibration Integrity Investigations FY 2013 Summary Report: Post-Irradiation Examination of Zircaloy-4 Samples in Target Capsules and Initiation of Bending Fatigue Testing for Used Nuclear Fuel Vibration

  10. In situ HVEM studies of phase transformation in Zr alloys and compounds under irradiation

    SciTech Connect (OSTI)

    Motta, A.T.; Faldowski, J.A.; Howe, L.M.; Okamoto, P.R.

    1996-01-01

    The High Voltage Electron Microscope (HVEM)/Tandem facility at Argonne National Laboratory has been used to conduct detailed studies of the phase stability and microstructural evolution in zirconium alloys and compounds under ion and electron irradiation. Detailed kinetic studies of the crystalline-to-amorphous transformation of the intermetallic compounds Zr{sub 3}(Fe{sub 1-x}Ni{sub x}), Zr(Fe{sub 1-x},Cr{sub x}){sub 2}, Zr{sub 3}Fe, and Zr{sub 1.5} Nb{sub 1.5} Fe, both as second phase precipitates and in bulk form, have been performed using the in-situ capabilities of the Argonne facility, under a variety of irradiation conditions (temperature, dose rate). Results include a verification of a dose rate effect on amorphization and the influence of material variables (stoichiometry x, presence of stacking faults, crystal structure) on the critical temperature and on the critical dose for amorphization. Studies were also conducted of the microstructural evolution under irradiation of specially tailored binary and ternary model alloys. The stability of the {omega}-phase in Zr-20%Nb under electron and Ar ion irradiation was investigated as well as the {beta}-phase precipitation in Zr-2.5%Nb under Ar ion irradiation. The ensemble of these results is discussed in terms of theoretical models of amorphization and of irradiation-altered solubility.

  11. Synthesis and magnetic characterization of magnetite obtained by monowavelength visible light irradiation

    SciTech Connect (OSTI)

    Lin, Yulong [Institute of Coal Chemistry, Chinese Academy of Science, Taiyuan 030001 (China) [Institute of Coal Chemistry, Chinese Academy of Science, Taiyuan 030001 (China); Graduate School of the Chinese Academy of Sciences, Beijing 100039 (China); School of Pharmaceutical Sciences, Hebei Medical University, Shijiazhuang 050017 (China); Wei, Yu, E-mail: weiyu@mail.hebtu.edu.cn [College of Chemistry and Materials Science, Hebei Normal University, Shijiazhuang 050016 (China)] [College of Chemistry and Materials Science, Hebei Normal University, Shijiazhuang 050016 (China); Sun, Yuhan, E-mail: yhsun@sxicc.ac.cn [Institute of Coal Chemistry, Chinese Academy of Science, Taiyuan 030001 (China)] [Institute of Coal Chemistry, Chinese Academy of Science, Taiyuan 030001 (China); Wang, Jing [School of Pharmaceutical Sciences, Hebei Medical University, Shijiazhuang 050017 (China)] [School of Pharmaceutical Sciences, Hebei Medical University, Shijiazhuang 050017 (China)

    2012-03-15

    Highlights: Black-Right-Pointing-Pointer Magnetite was synthesized under monowavelength LED irradiation at room temperature. Black-Right-Pointing-Pointer Different wavelength irradiations led to distinctive characteristics of magnetite. Black-Right-Pointing-Pointer Particle sizes of magnetite were controlled by different irradiation wavelengths. Black-Right-Pointing-Pointer Wavelength affects the magnetic characteristics of magnetite. -- Abstract: Magnetite (Fe{sub 3}O{sub 4}) nanoparticles were controllably synthesized by aerial oxidation Fe{sup II}EDTA solution under different monowavelength light-emitting diode (LED) lamps irradiation at room temperature. The results of the X-ray diffraction (XRD) spectra show the formation of magnetite nanoparticle further confirmed by Fourier transform infrared spectroscope (FTIR) and the difference in crystallinity of as-prepared samples. Fe{sub 3}O{sub 4} particles are nearly spherical in shape based on transmission electron microscopy (TEM). Average crystallite sizes of magnetite can be controlled by different irradiation light wavelengths from XRD and TEM: 50.1, 41.2, and 20.3 nm for red, green, and blue light irradiation, respectively. The magnetic properties of Fe{sub 3}O{sub 4} samples were investigated. Saturation magnetization values of magnetic nanoparticles were 70.1 (sample M-625), 65.3 (sample M-525), and 58.2 (sample M-460) emu/g, respectively.

  12. Introducing an Absolute Cavity Pyrgeometer (ACP) for Improving the Atmospheric Longwave Irradiance Measurement (Poster)

    SciTech Connect (OSTI)

    Reda, I.; Stoffel, T.

    2012-03-01

    Advancing climate change research requires accurate and traceable measurement of the atmospheric longwave irradiance. Current measurement capabilities are limited to an estimated uncertainty of larger than +/- 4 W/m2 using the interim World Infrared Standard Group (WISG). WISG is traceable to the Systeme international d'unites (SI) through blackbody calibrations. An Absolute Cavity Pyrgeometer (ACP) is being developed to measure absolute outdoor longwave irradiance with traceability to SI using the temperature scale (ITS-90) and the sky as the reference source, instead of a blackbody. The ACP was designed by NREL and optically characterized by the National Institute of Standards and Technology (NIST). Under clear-sky and stable conditions, the responsivity of the ACP is determined by lowering the temperature of the cavity and calculating the rate of change of the thermopile output voltage versus the changing net irradiance. The absolute atmospheric longwave irradiance is then calculated with an uncertainty of +/- 3.96 W/m2 with traceability to SI. The measured irradiance by the ACP was compared with the irradiance measured by two pyrgeometers calibrated by the World Radiation Center with traceability to the WISG.

  13. Facility for spectral irradiance and radiance responsivity calibrations using uniform sources

    SciTech Connect (OSTI)

    Brown, Steven W.; Eppeldauer, George P.; Lykke, Keith R

    2006-11-10

    Detectors have historically been calibrated for spectral power responsivity at the National Institute of Standards and Technology by using a lamp-monochromator system to tune the wavelength of the excitation source. Silicon detectors can be calibrated in the visible spectral region with combined standard uncertainties at the 0.1% level. However,uncertainties increase dramatically when measuring an instrument's spectral irradiance or radiance responsivity. We describe what we believe to be a new laser-based facility for spectral irradiance and radiance responsivity calibrations using uniform sources (SIRCUS) that was developed to calibrate instruments directly in irradiance or radiance mode with uncertainties approaching or exceeding those available for spectral power responsivity calibrations. In SIRCUS, the emission from high-power, tunable lasers is introduced into an integrating sphere using optical fibers, producing uniform, quasi-Lambertian, high-radiant-flux sources. Reference standard irradiance detectors, calibrated directly against national primary standards for spectral power responsivity and aperture area measurement,are used to determine the irradiance at a reference plane. Knowing the measurement geometry, the source radiance can be readily determined as well. The radiometric properties of the SIRCUS source coupled with state-of-the-art transfer standard radiometers whose responsivities are directly traceable to primary national radiometric scales result in typical combined standard uncertainties in irradiance and radiance responsivity calibrations of less than 0.1%. The details of the facility and its effect on primary national radiometric scales are discussed.

  14. Radiation Tolerance of Neutron-Irradiated Model Fe-Cr-Al Alloys

    SciTech Connect (OSTI)

    Field, Kevin G; Hu, Xunxiang; Littrell, Ken; Yamamoto, Yukinori; Snead, Lance Lewis

    2015-01-01

    The Fe Cr Al alloy system has the potential to form an important class of enhanced accident-tolerant cladding materials in the nuclear power industry owing to the alloy system's higher oxidation resistance in high-temperature steam environments compared with traditional zirconium-based alloys. However, radiation tolerance of Fe Cr Al alloys has not been fully established. In this study, a series of Fe Cr Al alloys with 10 18 wt % Cr and 2.9 4.9 wt % Al were neutron irradiated at 382 C to 1.8 dpa to investigate the irradiation-induced microstructural and mechanical property evolution as a function of alloy composition. Dislocation loops with Burgers vector of a/2 111 and a 100 were detected and quantified. Results indicate precipitation of Cr-rich is primarily dependent on the bulk chromium composition. Mechanical testing of sub-size-irradiated tensile specimens indicates the hardening response seen after irradiation is dependent on the bulk chromium composition. A structure property relationship was developed; it indicated that the change in yield strength after irradiation is caused by the formation of these radiation-induced defects and is dominated by the large number density of Cr-rich precipitates at sufficiently high chromium contents after irradiation.

  15. Grain growth and phase stability of nanocrystalline cubic zirconia under ion irradiation

    SciTech Connect (OSTI)

    Zhang, Yanwen; Jiang, Weilin; Wang, Chong M.; Namavar, Fereydoon; Edmondson, Philip D.; Zhu, Zihua; Gao, Fei; Lian, Jie; Weber, William J.

    2010-11-10

    Grain growth, oxygen stoichiometry and phase stability of nanostructurally-stabilized zirconia (NSZ) in pure cubic phase are investigated under 2 MeV Au ion bombardment at 160 and 400 K to doses up to 35 displacements per atom (dpa). The NSZ films are produced by ion-beam-assisted deposition technique at room temperature with an average grain size of 7.7 nm. The grain size increases with dose, and follows a power law (n=6) to a saturation value of ~30 nm that decreases with temperature. Slower grain growth is observed under 400 K irradiations, as compared to 160 K irradiations, indicating that thermal grain growth is not activated and defect-stimulated grain growth is the dominating mechanism. While cubic phase is perfectly retained and no new phases are identified after the high-dose irradiations, reduction of oxygen in the irradiated NSZ films is detected. The ratio of O to Zr decreases from ~2.0 for the as-deposited films to ~1.65 after irradiation to ~35 dpa. Significant increase of oxygen vacancies in nanocrystalline zirconia suggests substantially enhanced oxygen diffusion under ion irradiation, a materials behavior far from equilibrium. The oxygen deficiency may be essential in stabilizing cubic phase to larger grain sizes.

  16. Irradiation-induced Ag nanocluster nucleation in silicate glasses: Analogy with photography

    SciTech Connect (OSTI)

    Espiau de Lamaestre, R.; Bea, H.; Bernas, H.; Belloni, J.; Marignier, J. L.

    2007-11-15

    The synthesis of Ag nanoclusters in soda lime silicate glasses and silica was studied by optical absorption and electron spin resonance experiments under both low (gamma ray) and high (MeV ion) deposited energy density irradiation conditions. Both types of irradiation create electrons and holes whose density and thermal evolution--notably via their interaction with defects--are shown to determine the clustering and growth rates of Ag nanocrystals. We thus establish the influence of redox interactions of defects and silver (poly)ions. The mechanisms are similar to the latent image formation in photography: Irradiation-induced photoelectrons are trapped within the glass matrix, notably on dissolved noble metal ions and defects, which are thus neutralized (reverse oxidation reactions are also shown to exist). Annealing promotes metal atom diffusion, which, in turn, leads to cluster nuclei formation. The cluster density depends not only on the irradiation fluence but also--and primarily--on the density of deposited energy and the redox properties of the glass. Ion irradiation (i.e., large deposited energy density) is far more effective in cluster formation, despite its lower neutralization efficiency (from Ag{sup +} to Ag{sup 0}) as compared to gamma photon irradiation.

  17. Gamma irradiation effect on the chemical composition and the antioxidant activity of Ipomoea batatas L

    SciTech Connect (OSTI)

    Tahir, D., E-mail: dtahir@fmipa.unhas.ac.id; Halide, H., E-mail: dtahir@fmipa.unhas.ac.id; Kurniawan, D. [Department of Physics, Hasanuddin University, Makassar 90245 (Indonesia); Wahab, A. W. [Department of Chemistry, Hasanuddin University, Makassar 90245 (Indonesia)

    2014-09-25

    The chemical composition and antioxidant activity of Ipomoea batatas L. (sweet potato) were studied by x-ray fluorescence (XRF) spectroscopy, Fourier transform infrared spectroscopy, and by the 1,1-diphenyl-2-picrylhydrazyl (DPPH) radical scavenging capacity. The irradiation treatment was performed by using Cs-137 as a gamma sources in experimental equipment. Treatment by irradiation emerges as a possible conservation technique that has been tested successfully in several food products. The amount of chemical composition was changed and resulting new chemical for absorbed dose 40 mSv. Interestingly, it was found that gamma irradiation significantly increased the antioxidant activity, as measured by DPPH radical scavenging capacity. The antioxidant activity of Ipomoea batatas L. extract was dramatically increased in the non-irradiated sample to the sample irradiated at 40 mSv. These results indicate that gamma irradiation of Ipomoea batatas L. extract can enhance its antioxidant activity through the formation of a new chemical compound. Based on these results, increased antioxidant activity of Ipomoea batatas L. extracts by gamma rays can be applied to various industries, especially cosmetics, foodstuffs, and pharmaceuticals.

  18. Oxide Shell Reduction and Magnetic Property Changes in Core-Shell Fe Nanoclusters under Ion Irradiation

    SciTech Connect (OSTI)

    Sundararajan, Jennifer A.; Kaur, Maninder; Jiang, Weilin; McCloy, John S.; Qiang, You

    2014-02-12

    Ion irradiation effects are studied on the Fe-based core-shell nanocluster (NC) films with core as Fe and shell as Fe3O4/FeO. These NC films were were deposited on Si substrates to thickness of ~0.5 micrometers using a NC deposition system. The films were irradiated at room temperature with 5.5 MeV Si2+ ions to ion fluences of 1015 and 1016 ions/cm2. It is found that the irradiation induces grain growth, Fe valence reduction in the shell, and crystallization of Fe3N. The nature and mechanism of oxide shell reduction and composition dependence after irradiation were studied by synthesizing additional NC films of Fe3O4 and FeO+Fe3N and irradiating them under the same conditions. The presence of nanocrystalline Fe is found to be a major factor for the oxide shell reduction. The surface morphologies of these films show dramatic changes in the microstructures due to cluster growth and agglomeration as a result of ion irradiation.

  19. Lung Irradiation Increases Mortality After Influenza A Virus Challenge Occurring Late After Exposure

    SciTech Connect (OSTI)

    Manning, Casey M.; Johnston, Carl J.; Department of Pediatrics, University of Rochester Medical Center, Rochester, New York ; Reed, Christina K.; Lawrence, B. Paige; Department of Microbiology and Immunology, University of Rochester Medical Center, Rochester, New York ; Williams, Jacqueline P.; Finkelstein, Jacob N.

    2013-05-01

    Purpose: To address whether irradiation-induced changes in the lung environment alter responses to a viral challenge delivered late after exposure but before the appearance of late lung radiation injury. Methods and Materials: C57BL/6J mice received either lung alone or combined lung and whole-body irradiation (0-15 Gy). At 10 weeks after irradiation, animals were infected with 120 HAU influenza virus strain A/HKx31. Innate and adaptive immune cell recruitment was determined using flow cytometry. Cytokine and chemokine production and protein leakage into the lung after infection were assessed. Results: Prior irradiation led to a dose-dependent failure to regain body weight after infection and exacerbated mortality, but it did not affect virus-specific immune responses or virus clearance. Surviving irradiated animals displayed a persistent increase in total protein in bronchoalveolar lavage fluid and edema. Conclusions: Lung irradiation increased susceptibility to death after infection with influenza virus and impaired the ability to complete recovery. This altered response does not seem to be due to a radiation effect on the immune response, but it may possibly be an effect on epithelial repair.

  20. Axillary lymph node dose with tangential breast irradiation

    SciTech Connect (OSTI)

    Reed, Daniel R. . E-mail: drreed@u.washington.edu; Lindsley, Skyler Karen; Mann, Gary N.; Austin-Seymour, Mary; Korssjoen, Tammy; Anderson, Benjamin O.; Moe, Roger

    2005-02-01

    Purpose: The advent of sentinel lymph node mapping and biopsy in the staging of breast cancer has resulted in a significant decrease in the extent of axillary nodal surgery. As the extent of axillary surgery decreases, the radiation dose and distribution within the axilla becomes increasingly important for current therapy planning and future analysis of results. This analysis examined the radiation dose distribution delivered to the anatomically defined axillary level I and II lymph node volume and surgically placed axillary clips with conventional tangential breast fields and CT-based three-dimensional (3D) planning. Methods and materials: Fifty consecutive patients with early-stage breast cancer undergoing breast conservation therapy were evaluated. All patients underwent 3D CT-based planning with conventional breast tangential fields designed to encompass the entire breast parenchyma. Using CT-based 3D planning, the dose distribution of the standard tangential breast irradiation fields was examined in relationship to the axillary level I and II lymph node volumes. Axillary level I and II lymph node anatomic volumes were defined by CT and surgical clips placed during complete level I-II lymph node dissection. Axillary level I-II lymph node volume doses were examined on the basis of the prescribed breast radiation dose and 3D dose distribution. Results: All defined breast volumes received {>=}95% of the prescribed dose. By contrast, the 95% isodose line encompassed only an average of 55% (range, 23-87%) of the axillary level I-II lymph node anatomic volume. No patient had complete coverage of the axillary level I-II lymph node region by the 95% isodose line. The mean anatomic axillary level I-II volume was 146.3 cm{sup 3} (range, 83.1-313.0 cm{sup 3}). The mean anatomic axillary level I-II volume encompassed by the 95% isodose line was 84.9 cm{sup 3} (range, 25.1-219.0 cm{sup 3}). The mean 95% isodose coverage of the surgical clip volume was 80%, and the median value was 81% (range, 58-98%). The mean volume deficit between the axillary level I-II volume and the surgical clip volume was 41.7 cm{sup 3} (median, 30.0 cc). Conclusion: In this study, standard tangential breast radiation fields failed to deliver a therapeutic dose adequately to the axillary level I-II lymph node anatomic volume. No patient received complete coverage of the axillary level I-II lymph node volume. Surgically placed axillary clips also failed to delineate the level I-II axilla adequately. Definitive irradiation of the level I and II axillary lymph node region requires significant modification of standard tangential fields, best accomplished with 3D treatment planning, with specific targeting of anatomically defined axillary lymph node volumes as described, in addition to the breast parenchymal volumes.

  1. Separation of Plutonium from Irradiated Fuels and Targets

    SciTech Connect (OSTI)

    Gray, Leonard W.; Holliday, Kiel S.; Murray, Alice; Thompson, Major; Thorp, Donald T.; Yarbro, Stephen; Venetz, Theodore J.

    2015-09-30

    The production of electricity by nuclear fission is, at present, nearly 366- gigawatt electric (GWe), generated from 438 operating nuclear reactors. Unlike fossil fuel ash, with limited residual available energy content and negligible heat content, the spent nuclear fuel from power production reactors contains moderate amounts of transuranium (TRU) actinides and fission products in addition to the still slightly enriched uranium. Originally nuclear technology was developed to chemically separate and recover fissionable plutonium from irradiated nuclear fuel for military purposes. Military plutonium separations had essentially ceased by the mid-1990s. Reprocessing, however, can serve multiple purposes and the relative importance has changed over time. In the 1960’s the vision of the introduction of plutonium-fueled fast-neutron breeder reactors drove the civilian separation of plutonium. More recently, reprocessing has been regarded as a means to facilitate the disposal of high-level nuclear waste and thus requires development of radically different technical approaches. In the last decade or so, principal reason for reprocessing has shifted to spent power reactor fuel being reprocessed 1) so that unused uranium and plutonium being recycled reduce the volume, gaining some 25% to 30% more energy from the original uranium in the process and thus contributing to energy security and 2) reduce the volume and radioactivity of the waste by recovering all long-lived actinides and fission products followed by recycling them in fast reactors where they are transmuted to short-lived fission products; this reduces the volume to about 20%, reduces the long term radioactivity level in the high-level waste, and complicates the possibility of the plutonium being diverted from civil use – thereby increasing the proliferation resistance of the fuel cycle.

  2. High Dose Neutron Irradiation Performance of Dielectric Mirrors

    SciTech Connect (OSTI)

    Nimishakavi, Anantha Phani Kiran Kumar; Leonard, Keith J; Jellison Jr, Gerald Earle; Snead, Lance Lewis

    2015-01-01

    The study presents the high-dose behavior of dielectric mirrors specifically engineered for radiation-tolerance: alternating layers of Al2O3/SiO2 and HfO2/SiO2 were grown on sapphire substrates and exposed to neutron doses of 1 and 4 dpa at 458 10K in the High Flux Isotope Reactor (HFIR). In comparison to previously reported results, these higher doses of 1 and 4 dpa results in a drastic drop in optical reflectance, caused by a failure of the multilayer coating. HfO2/SiO2 mirrors failed completely when exposed to 1 dpa, whereas the reflectance of Al2O3/SiO2 mirrors reduced to 44%, eventually failing at 4 dpa. Transmission electron microscopy (TEM) observation of the Al2O3/SiO2 specimens showed SiO2 layer defects which increases size with irradiation dose. The typical size of each defect was 8 nm in 1 dpa and 42 nm in 4 dpa specimens. Buckling type delamination of the interface between the substrate and first layer was typically observed in both 1 and 4 dpa HfO2/SiO2 specimens. Composition changes across the layers were measured in high resolution scanning-TEM mode using energy dispersive spectroscopy. A significant interdiffusion between the film layers was observed in Al2O3/SiO2 mirror, though less evident in HfO2/SiO2 system. The ultimate goal of this work is the provide insight into the radiation-induced failure mechanisms of these mirrors.

  3. Irradiation and Bevacizumab in High-Grade Glioma Retreatment Settings

    SciTech Connect (OSTI)

    Niyazi, Maximilian; Ganswindt, Ute; Schwarz, Silke Birgit [Department of Radiation Oncology, Ludwig-Maximilians-University Munich, Munich (Germany); Kreth, Friedrich-Wilhelm; Tonn, Joerg-Christian [Department of Neurosurgery, Ludwig-Maximilians-University Munich, Munich (Germany); Geisler, Julia; Fougere, Christian la [Department of Nuclear Medicine, Ludwig-Maximilians-University Munich, Munich (Germany); Ertl, Lorenz; Linn, Jennifer [Department of Neuroradiology, Ludwig-Maximilians-University Munich, Munich (Germany); Siefert, Axel [Department of Radiation Oncology, Ludwig-Maximilians-University Munich, Munich (Germany); Belka, Claus, E-mail: claus.belka@med.uni-muenchen.de [Department of Radiation Oncology, Ludwig-Maximilians-University Munich, Munich (Germany)

    2012-01-01

    Purpose: Reirradiation is a treatment option for recurrent high-grade glioma with proven but limited effectiveness. Therapies directed against vascular endothelial growth factor have been shown to exert certain efficacy in combination with chemotherapy and have been safely tested in combination with radiotherapy in a small cohort of patients. To study the feasibility of reirradiation combined with bevacizumab treatment, the toxicity and treatment outcomes of this approach were analyzed retrospectively. Patients and Methods: After previous treatment with standard radiotherapy (with or without temozolomide) patients with recurrent malignant glioma received bevacizumab (10 mg/kg intravenous) on Day 1 and Day 15 during radiotherapy. Maintenance therapy was selected based on individual considerations, and mainly bevacizumab-containing regimens were chosen. Patients received 36 Gy in 18 fractions. Results: The data of the medical charts of the 30 patients were analyzed retrospectively. All were irradiated in a single institution and received either bevacizumab (n = 20), no additional substance (n = 7), or temozolomide (n = 3). Reirradiation was tolerated well, regardless of the added drug. In 1 patient treated with bevacizumab, a wound dehiscence occurred. Overall survival was significantly better in patients receiving bevacizumab (p = 0.03, log-rank test). In a multivariate proportional hazards Cox model, bevacizumab, Karnovsky performance status, and World Health Organization grade at relapse turned out to be the most important predictors for overall survival. Conclusion: Reirradiation with bevacizumab is a feasible and effective treatment for patients with recurrent high-grade gliomas. A randomized trial is warranted to finally answer the question whether bevacizumab adds substantial benefit to a radiotherapeutic retreatment setting.

  4. Strain-dependent Damage in Mouse Lung After Carbon Ion Irradiation

    SciTech Connect (OSTI)

    Moritake, Takashi; Proton Medical Research Center, University of Tsukuba, Tsukuba ; Fujita, Hidetoshi; Yanagisawa, Mitsuru; Nakawatari, Miyako; Imadome, Kaori; Nakamura, Etsuko; Iwakawa, Mayumi; Imai, Takashi

    2012-09-01

    Purpose: To examine whether inherent factors produce differences in lung morbidity in response to carbon ion (C-ion) irradiation, and to identify the molecules that have a key role in strain-dependent adverse effects in the lung. Methods and Materials: Three strains of female mice (C3H/He Slc, C57BL/6J Jms Slc, and A/J Jms Slc) were locally irradiated in the thorax with either C-ion beams (290 MeV/n, in 6 cm spread-out Bragg peak) or with {sup 137}Cs {gamma}-rays as a reference beam. We performed survival assays and histologic examination of the lung with hematoxylin-eosin and Masson's trichrome staining. In addition, we performed immunohistochemical staining for hyaluronic acid (HA), CD44, and Mac3 and assayed for gene expression. Results: The survival data in mice showed a between-strain variance after C-ion irradiation with 10 Gy. The median survival time of C3H/He was significantly shortened after C-ion irradiation at the higher dose of 12.5 Gy. Histologic examination revealed early-phase hemorrhagic pneumonitis in C3H/He and late-phase focal fibrotic lesions in C57BL/6J after C-ion irradiation with 10 Gy. Pleural effusion was apparent in C57BL/6J and A/J mice, 168 days after C-ion irradiation with 10 Gy. Microarray analysis of irradiated lung tissue in the three mouse strains identified differential expression changes in growth differentiation factor 15 (Gdf15), which regulates macrophage function, and hyaluronan synthase 1 (Has1), which plays a role in HA metabolism. Immunohistochemistry showed that the number of CD44-positive cells, a surrogate marker for HA accumulation, and Mac3-positive cells, a marker for macrophage infiltration in irradiated lung, varied significantly among the three mouse strains during the early phase. Conclusions: This study demonstrated a strain-dependent differential response in mice to C-ion thoracic irradiation. Our findings identified candidate molecules that could be implicated in the between-strain variance to early hemorrhagic pneumonitis after C-ion irradiation.

  5. INFLUENCE OF SPECIMEN SIZE/TYPE ON THE FRACTURE TOUGHNESS OF FIVE IRRADIATED RPV MATERIALS

    SciTech Connect (OSTI)

    Sokolov, Mikhail A; Lucon, Enrico

    2015-01-01

    The Heavy-Section Steel Irradiation (HSSI) Program had previously irradiated five reactor pressure vessel (RPV) steels/welds at fast neutron fluxes of about 4 to 8 1011 n/cm2/s (>1 MeV) to fluences from 0.5 to 3.4 1019 n/cm2 and at 288 C. The unirradiated fracture toughness tests were performed by Oak Ridge National Laboratory with 12.7-mm and 25.4-mm thick (0.5T and 1T) compact specimens, while the HSSI Program provided tensile and 5 10-mm three-point bend specimens to SCK CEN for irradiation in the in-pile section of the Belgian Reactor BR2 at fluxes >1013 n/cm2/s and subsequent testing by SCK CEN. The BR2 irradiations were conducted at about 2 and 4 1013 n/cm2/s with irradiation temperature between 295 C and 300 C (water temperature), and to fluences between 6 and10 1019 n/cm2. The irradiation-induced shifts of the Master Curve reference temperatures, T0, for most of the materials deviated from the embrittlement correlations much more than expected, motivating the testing of 5 10-mm three-point bend specimens of all five materials in the unirradiated condition to eliminate specimen size and geometry as a variable. Tests of the unirradiated small bend specimens resulted in Master Curve reference temperatures, T0, 25 C to 53 C lower than those from the larger compact specimens, meaning that the irradiation-induced reference temperature shifts, T0, were larger than the initial measurements, resulting in much improved agreement between the measured and predicted fracture toughness shifts.

  6. Impact of total ionizing dose irradiation on electrical property of ferroelectric-gate field-effect transistor

    SciTech Connect (OSTI)

    Yan, S. A.; Tang, M. H. Xiao, Y. G.; Zhang, W. L.; Ding, H.; Chen, J. W.; Zhou, Y. C.; Xiong, Y.; Li, Z.; Zhao, W.; Guo, H. X.

    2014-05-28

    P-type channel metal-ferroelectric-insulator-silicon field-effect transistors (FETs) with a 300?nm thick SrBi{sub 2}Ta{sub 2}O{sub 9} ferroelectric film and a 10?nm thick HfTaO layer on silicon substrate were fabricated and characterized. The prepared FeFETs were then subjected to {sup 60}Co gamma irradiation in steps of three dose levels. Irradiation-induced degradation on electrical characteristics of the fabricated FeFETs was observed after 1 week annealing at room temperature. The possible irradiation-induced degradation mechanisms were discussed and simulated. All the irradiation experiment results indicated that the stability and reliability of the fabricated FeFETs for nonvolatile memory applications will become uncontrollable under strong irradiation dose and/or long irradiation time.

  7. Effects of storage on irradiated red blood cells: An in-vitro and in-vivo study. Master's thesis

    SciTech Connect (OSTI)

    Knoll, S.E.

    1991-08-01

    Irradiation of red blood cell units has recently become a topic of special concern as the result of increasing reports of graft versus host disease in immunocompetent blood transfusion recipients. This study was designed to evaluate the potassium elevations observed in stored irradiated red blood cells and to evaluate the in vivo survival of stored irradiated red blood cells using a dog model. In the in vitro study ten units of human CPDA-1 packed red blood cells were made into paired aliquots; one aliquot of each pair was irradiated with 3000 rads of gamma radiation and the potassium content measured at points throughout 35 days of storage. A significant increase in potassium levels in the irradiated aliquots was observed from the first day after irradiation and continued through the entire storage period.

  8. AGR-2 irradiation test final as-run report, Rev. 1

    SciTech Connect (OSTI)

    Collin, Blaise

    2014-08-01

    This document presents the as-run analysis of the AGR-2 irradiation experiment. AGR-2 is the second of the planned irradiations for the Advanced Gas Reactor (AGR) Fuel Development and Qualification Program. Funding for this program is provided by the U.S. Department of Energy as part of the Very High Temperature Reactor (VHTR) Technical Development Office (TDO) program. The objectives of the AGR-2 experiment are to: (a) Irradiate UCO (uranium oxycarbide) and UO2 (uranium dioxide) fuel produced in a large coater. Fuel attributes are based on results obtained from the AGR-1 test and other project activities; (b) Provide irradiated fuel samples for post-irradiation experiment (PIE) and safety testing; and, (c) Support the development of an understanding of the relationship between fuel fabrication processes, fuel product properties, and irradiation performance. The primary objective of the test was to irradiate both UCO and UO2 TRISO (tri-structural isotropic) fuel produced from prototypic scale equipment to obtain normal operation and accident condition fuel performance data. The UCO compacts were subjected to a range of burnups and temperatures typical of anticipated prismatic reactor service conditions in three capsules. The test train also includes compacts containing UO2 particles produced independently by the United States, South Africa, and France in three separate capsules. The range of burnups and temperatures in these capsules were typical of anticipated pebble bed reactor service conditions. The results discussed in this report pertain only to U.S. produced fuel. In order to achieve the test objectives, the AGR-2 experiment was irradiated in the B-12 position of the Advanced Test Reactor (ATR) at Idaho National Laboratory (INL) for a total irradiation duration of 559.2 effective full power days (EFPD). Irradiation began on June 22, 2010, and ended on October 16, 2013, spanning 12 ATR power cycles and approximately three and a half calendar years. The test contained six independently controlled and monitored capsules. Each U.S. capsule contained 12 compacts of either UCO or UO2 AGR coated fuel. No fuel particles failed during the AGR-2 irradiation. Final burnup values on a per compact basis ranged from 7.26 to 13.15% FIMA (fissions per initial heavy-metal atom) for UCO fuel, and 9.01 to 10.69% FIMA for UO2 fuel, while fast fluence values ranged from 1.94 to 3.471025 n/m2 (E >0.18 MeV) for UCO fuel, and from 3.05 to 3.531025 n/m2 (E >0.18 MeV) for UO2 fuel. Time-average volume-average (TAVA) temperatures on a capsule basis at the end of irradiation ranged from 987C in Capsule 6 to 1296C in Capsule 2 for UCO, and from 996 to 1062C in UO2-fueled Capsule 3. By the end of the irradiation, all of the installed thermocouples (TCs) had failed. Fission product release-to-birth (R/B) ratios were quite low. In the UCO capsules, R/B values during the first three cycles were below 10-6 with the exception of the hotter Capsule 2, in which the R/Bs reached 210-6. In the UO2 capsule (Capsule 3), the R/B values during the first three cycles were below 10-7. R/B values for all following cycles are not reliable due to gas flow and cross talk issues.

  9. AGR-2 Irradiation Test Final As-Run Report, Rev 2

    SciTech Connect (OSTI)

    Blaise Collin

    2014-08-01

    This document presents the as-run analysis of the AGR-2 irradiation experiment. AGR-2 is the second of the planned irradiations for the Advanced Gas Reactor (AGR) Fuel Development and Qualification Program. Funding for this program is provided by the U.S. Department of Energy as part of the Very High Temperature Reactor (VHTR) Technical Development Office (TDO) program. The objectives of the AGR-2 experiment are to: (a) Irradiate UCO (uranium oxycarbide) and UO2 (uranium dioxide) fuel produced in a large coater. Fuel attributes are based on results obtained from the AGR-1 test and other project activities. (b) Provide irradiated fuel samples for post-irradiation experiment (PIE) and safety testing. (c) Support the development of an understanding of the relationship between fuel fabrication processes, fuel product properties, and irradiation performance. The primary objective of the test was to irradiate both UCO and UO2 TRISO (tri-structural isotropic) fuel produced from prototypic scale equipment to obtain normal operation and accident condition fuel performance data. The UCO compacts were subjected to a range of burnups and temperatures typical of anticipated prismatic reactor service conditions in three capsules. The test train also includes compacts containing UO2 particles produced independently by the United States, South Africa, and France in three separate capsules. The range of burnups and temperatures in these capsules were typical of anticipated pebble bed reactor service conditions. The results discussed in this report pertain only to U.S. produced fuel. In order to achieve the test objectives, the AGR-2 experiment was irradiated in the B-12 position of the Advanced Test Reactor (ATR) at Idaho National Laboratory (INL) for a total irradiation duration of 559.2 effective full power days (EFPD). Irradiation began on June 22, 2010, and ended on October 16, 2013, spanning 12 ATR power cycles and approximately three and a half calendar years. The test contained six independently controlled and monitored capsules. Each U.S. capsule contained 12 compacts of either UCO or UO2 AGR coated fuel. No fuel particles failed during the AGR-2 irradiation. Final burnup values on a per compact basis ranged from 7.26 to 13.15% FIMA (fissions per initial heavy-metal atom) for UCO fuel, and 9.01 to 10.69% FIMA for UO2 fuel, while fast fluence values ranged from 1.94 to 3.471025 n/m2 (E >0.18 MeV) for UCO fuel, and from 3.05 to 3.531025 n/m2 (E >0.18 MeV) for UO2 fuel. Time-average volume-average (TAVA) temperatures on a capsule basis at the end of irradiation ranged from 987C in Capsule 6 to 1296C in Capsule 2 for UCO, and from 996 to 1062C in UO2-fueled Capsule 3. By the end of the irradiation, all of the installed thermocouples (TCs) had failed. Fission product release-to-birth (R/B) ratios were quite low. In the UCO capsules, R/B values during the first three cycles were below 10-6 with the exception of the hotter Capsule 2, in which the R/Bs reached 210-6. In the UO2 capsule (Capsule 3), the R/B values during the first three cycles were below 10-7. R/B values for all following cycles are not reliable due to gas flow and cross talk issues.

  10. Monte Carlo Simulation of the Irradiation of Alanine Coated Film Dosimeters with Accelerated Electrons

    SciTech Connect (OSTI)

    Uribe, R. M.; Salvat, F.; Cleland, M. R.; Berejka, A.

    2009-03-10

    The Monte Carlo code PENELOPE was used to simulate the irradiation of alanine coated film dosimeters with electron beams of energies from 1 to 5 MeV being produced by a high-current industrial electron accelerator. This code includes a geometry package that defines complex quadratic geometries, such as those of the irradiation of products in an irradiation processing facility. In the present case the energy deposited on a water film at the surface of a wood parallelepiped was calculated using the program PENMAIN, which is a generic main program included in the PENELOPE distribution package. The results from the simulation were then compared with measurements performed by irradiating alanine film dosimeters with electrons using a 150 kW Dynamitron electron accelerator. The alanine films were placed on top of a set of wooden planks using the same geometrical arrangement as the one used for the simulation. The way the results from the simulation can be correlated with the actual measurements, taking into account the irradiation parameters, is described. An estimation of the percentage difference between measurements and calculations is also presented.

  11. Measurement and modeling of solar irradiance components on horizontal and tilted planes

    SciTech Connect (OSTI)

    Padovan, Andrea; Col, Davide del

    2010-12-15

    In this work new measurements of global and diffuse solar irradiance on the horizontal plane and global irradiance on planes tilted at 20 and 30 oriented due South and at 45 and 65 oriented due East are used to discuss the modeling of solar radiation. Irradiance data are collected in Padova (45.4 N, 11.9 E, 12 m above sea level), Italy. Some diffuse fraction correlations have been selected to model the hourly diffuse radiation on the horizontal plane. The comparison with the present experimental data shows that their prediction accuracy strongly depends on the sky characteristics. The hourly irradiance measurements taken on the tilted planes are compared with the estimations given by one isotropic and three anisotropic transposition models. The use of an anisotropic model, based on a physical description of the diffuse radiation, provides a much better accuracy, especially when measurements of the diffuse irradiance on the horizontal plane are not available and thus transposition models have to be applied in combination with a diffuse fraction correlation. This is particularly significant for the planes oriented away from South. (author)

  12. Microstructure and Mechanical Properties of n-irradiated Fe-Cr Model Alloys

    SciTech Connect (OSTI)

    Matijasevic, Milena; Al Mazouzi, Abderrahim

    2008-07-01

    High chromium ( 9-12 wt %) ferritic/martensitic steels are candidate structural materials for future fusion reactors and other advanced systems such as accelerator driven systems (ADS). Their use for these applications requires a careful assessment of their mechanical stability under high energy neutron irradiation and in aggressive environments. In particular, the Cr concentration has been shown to be a key parameter to be optimized in order to guarantee the best corrosion and swelling resistance, together with the least embrittlement. In this work, the characterization of the neutron irradiated Fe-Cr model alloys with different Cr % with respect to microstructure and mechanical tests will be presented. The behavior of Fe-Cr alloys have been studied using tensile tests at different temperature range ( from -160 deg. C to 300 deg. C). Irradiation-induced microstructure changes have been studied by TEM for two different irradiation doses at 300 deg. C. The density and the size distribution of the defects induced have been determined. The tensile test results indicate that Cr content affects the hardening behavior of Fe-Cr binary alloys. Hardening mechanisms are discussed in terms of Orowan type of approach by correlating TEM data to the measured irradiation hardening. (authors)

  13. Interpretation of solar irradiance monitor measurements through analysis of 3D MHD simulations

    SciTech Connect (OSTI)

    Criscuoli, S.; Uitenbroek, H.

    2014-06-20

    Measurements from the Spectral Irradiance Monitor (SIM) on board the Solar Radiation and Climate Experiment mission indicate that solar spectral irradiance at visible and IR wavelengths varies in counter phase with the solar activity cycle. The sign of these variations is not reproduced by most of the irradiance reconstruction techniques based on variations of surface magnetism employed so far, and it is not yet clear whether SIM calibration procedures need to be improved or if instead new physical mechanisms must be invoked to explain such variations. We employ three-dimensional magnetohydrodynamic simulations of the solar photosphere to investigate the dependence of solar radiance in SIM visible and IR spectral ranges on variations of the filling factor of surface magnetic fields. We find that the contribution of magnetic features to solar radiance is strongly dependent on the location on the disk of the features, which are negative close to disk center and positive toward the limb. If features are homogeneously distributed over a region around the equator (activity belt), then their contribution to irradiance is positive with respect to the contribution of HD snapshots, but decreases with the increase of their magnetic flux for average magnetic flux larger than 50 G in at least two of the visible and IR spectral bands monitored by SIM. Under the assumption that the 50 G snapshots are representative of quiet-Sun regions, we thus find that the Spectral Irradiance can be in counter-phase with the solar magnetic activity cycle.

  14. Effect of swift heavy ion irradiation on bare and coated ZnS quantum dots

    SciTech Connect (OSTI)

    Chowdhury, S. Hussain, A.M.P.; Ahmed, G.A.; Singh, F.; Avasthi, D.K.; Choudhury, A.

    2008-12-01

    The present study compares structural and optical modifications of bare and silica (SiO{sub 2}) coated ZnS quantum dots under swift heavy ion (SHI) irradiation. Bare and silica coated ZnS quantum dots were prepared following an inexpensive chemical route using polyvinyl alcohol (PVA) as the dielectric host matrix. X-ray diffraction (XRD) and transmission electron microscopy (TEM) study of the samples show the formation of almost spherical ZnS quantum dots. The UV-Vis absorption spectra reveal blue shift relative to bulk material in absorption energy while photoluminescence (PL) spectra suggests that surface state and near band edge emissions are dominating in case of bare and coated samples, respectively. Swift heavy ion irradiation of the samples was carried out with 160 MeV Ni{sup 12+} ion beam with fluences 10{sup 12} to 10{sup 13} ions/cm{sup 2}. Size enhancement of bare quantum dots after irradiation has been indicated in XRD and TEM analysis of the samples which has also been supported by optical absorption spectra. However similar investigations on irradiated coated quantum dots revealed little change in quantum dot size and emission. The present study thus shows that the coated ZnS quantum dots are stable upon SHI irradiation compared to the bare one.

  15. Validation of the Physics Analysis used to Characterize the AGR-1 TRISO Fuel Irradiation Test

    SciTech Connect (OSTI)

    Sterbentz, James W.; Harp, Jason M.; Demkowicz, Paul A.; Hawkes, Grant L.; Chang, Gray S.

    2015-05-01

    The results of a detailed physics depletion calculation used to characterize the AGR-1 TRISO-coated particle fuel test irradiated in the Advanced Test Reactor (ATR) at the Idaho National Laboratory are compared to measured data for the purpose of validation. The particle fuel was irradiated for 13 ATR power cycles over three calendar years. The physics analysis predicts compact burnups ranging from 11.30-19.56% FIMA and cumulative neutron fast fluence from 2.21?4.39E+25 n/m2 under simulated high-temperature gas-cooled reactor conditions in the ATR. The physics depletion calculation can provide a full characterization of all 72 irradiated TRISO-coated particle compacts during and post-irradiation, so validation of this physics calculation was a top priority. The validation of the physics analysis was done through comparisons with available measured experimental data which included: 1) high-resolution gamma scans for compact activity and burnup, 2) mass spectrometry for compact burnup, 3) flux wires for cumulative fast fluence, and 4) mass spectrometry for individual actinide and fission product concentrations. The measured data are generally in very good agreement with the calculated results, and therefore provide an adequate validation of the physics analysis and the results used to characterize the irradiated AGR-1 TRISO fuel.

  16. Technical Letter Report on the Cracking of Irradiated Cast Stainless Steels with Low Ferrite Content

    SciTech Connect (OSTI)

    Chen, Y.; Alexandreanu, B.; Natesan, K.

    2014-11-01

    Crack growth rate and fracture toughness J-R curve tests were performed on CF-3 and CF-8 cast austenite stainless steels (CASS) with 13-14% of ferrite. The tests were conducted at ~320C in either high-purity water with low dissolved oxygen or in simulated PWR water. The cyclic crack growth rates of CF-8 were higher than that of CF-3, and the differences between the aged and unaged specimens were small. No elevated SCC susceptibility was observed among these samples, and the SCC CGRs of these materials were comparable to those of CASS alloys with >23% ferrite. The fracture toughness values of unirradiated CF-3 were similar between unaged and aged specimens, and neutron irradiation decreased the fracture toughness significantly. The fracture toughness of CF-8 was reduced after thermal aging, and declined further after irradiation. It appears that while lowering ferrite content may help reduce the tendency of thermal aging embrittlement, it is not very effective to mitigate irradiation-induced embrittlement. Under a combined condition of thermal aging and irradiation, neutron irradiation plays a dominant role in causing embrittlement in CASS alloys.

  17. Status of the Norwegian thorium light water reactor (LWR) fuel development and irradiation test program

    SciTech Connect (OSTI)

    Drera, S.S.; Bjork, K.I.; Kelly, J.F.; Asphjell, O. [Thor Energy AS: Sommerrogaten 13-15, Oslo, NO255 (Norway)

    2013-07-01

    Thorium based fuels offer several benefits compared to uranium based fuels and should thus be an attractive alternative to conventional fuel types. In order for thorium based fuel to be licensed for use in current LWRs, material properties must be well known for fresh as well as irradiated fuel, and accurate prediction of fuel behavior must be possible to make for both normal operation and transient scenarios. Important parameters are known for fresh material but the behaviour of the fuel under irradiation is unknown particularly for low Th content. The irradiation campaign aims to widen the experience base to irradiated (Th,Pu)O{sub 2} fuel and (Th,U)O{sub 2} with low Th content and to confirm existing data for fresh fuel. The assumptions with respect to improved in-core fuel performance are confirmed by our preliminary irradiation test results, and our fuel manufacture trials so far indicate that both (Th,U)O{sub 2} and (Th,Pu)O{sub 2} fuels can be fabricated with existing technologies, which are possible to upscale to commercial volumes.

  18. Determination of the displacement energy of O, Si and Zr under electron beam irradiation

    SciTech Connect (OSTI)

    Edmondson, Philip D; Weber, William J; Namavar, Fereydoon; Zhang, Yanwen

    2012-01-01

    The response of nanocrystalline, stabilizer-free cubic zirconia thin films on a Si substrate to electron beam irradiation with energies of 4, 110 and 200 keV and fluences up to {approx}1.5 x 10{sup 22} e m{sup -2} has been studied to determine the displacement energies. The 110 and 200 keV irradiations were performed in situ using a transmission electron microscope; the 4 keV irradiations were performed ex situ using an electron gun. In all three irradiations, no structural modification of the zirconia was observed, despite the high fluxes and fluences. However the Si substrate on which the zirconia film was deposited was amorphized under the 200 keV electron irradiation. Examination of the electron-solid interactions reveals that the kinetic energy transfer from the 200 keV electrons to the silicon lattice is sufficient to cause atomic displacements, resulting in amorphization. The kinetic energy transfer from the 200 keV electrons to the oxygen sub-lattice of the zirconia may be sufficient to induce defect production, however, no evidence of defect production was observed. The displacement cross-section value of Zr was found to be {approx}400 times greater than that of O indicating that the O atoms are effectively screened from the electrons by the Zr atoms, and, therefore, the displacement of O is inefficient.

  19. Determination of the Displacement Energies of O, Si and Zr Under Electron Beam Irradiation

    SciTech Connect (OSTI)

    Edmondson, P. D.; Weber, William J.; Namavar, Fereydoon; Zhang, Yanwen

    2012-03-01

    The response of nanocrystalline, stabilizer-free cubic zirconia thin films on a Si substrate to electron beam irradiation with energies of 4, 110 and 200 keV and fluences up to ~1.5 x 10e m has been studied to determine the displacement energies. The 110 and 200 keV irradiations were performed in situ using a transmission electron microscope; the 4 keV irradiations were performed ex situ using an electron gun. In all three irradiations, no structural modification of the zirconia was observed, despite the high fluxes and fluences. However the Si substrate on which the zirconia film was deposited was amorphized under the 200 keV electron irradiation. Examination of the electronsolid interactions reveals that the kinetic energy transfer from the 200 keV electrons to the silicon lattice is sufficient to cause atomic displacements, resulting in amorphization. The kinetic energy transfer from the 200 keV electrons to the oxygen sub-lattice of the zirconia may be sufficient to induce defect production, however, no evidence of defect production was observed. The displacement cross-section value of Zr was found to be ~400 times greater than that of O indicating that the O atoms are effectively screened from the electrons by the Zr atoms, and, therefore, the displacement of O is inefficient.

  20. Microstructure and Cs Behavior of Ba-Doped Aluminosilicate Pollucite Irradiated with F+ Ions

    SciTech Connect (OSTI)

    Jiang, Weilin; Kovarik, Libor; Zhu, Zihua; Varga, Tamas; Engelhard, Mark H.; Bowden, Mark E.; Nenoff, Tina M.; Garino, Terry

    2014-08-07

    Radionuclide 137Cs is one of the major fission products that dominate heat generation in spent fuels over the first 300 hundred years. A durable waste form for 137Cs that decays to 137Ba is needed to minimize its environmental impact. Aluminosilicate pollucite CsAlSi2O6 is selected as a model waste form to study the decay-induced structural effects. While Ba-containing precipitates are not present in charge-balanced Cs0.9Ba0.05AlSi2O6, they are found in Cs0.9Ba0.1AlSi2O6 and identified as monoclinic Ba2Si3O8. Pollucite is susceptible to electron irradiation induced amorphization. The threshold density of the electronic energy deposition for amorphization is determined to be ~235 keV/nm3. Pollucite can be readily amorphized under F+ ion irradiation at 673 K. A significant amount of Cs diffusion and release from the amorphized pollucite is observed during the irradiation. However, cesium is immobile in the crystalline structure under He+ ion irradiation at room temperature. The critical temperature for amorphization is not higher than 873 K under F+ ion irradiation. If kept at or above 873 K all the time, the pollucite structure is unlikely to be amorphized; Cs diffusion and release are improbable. A general discussion regarding pollucite as a potential waste form is provided in this report.

  1. Status of the NGNP graphite creep experiments AGC-1 and AGC-2 irradiated in the advanced test reactor

    SciTech Connect (OSTI)

    S. Blaine Grover

    2014-05-01

    The United States Department of Energy's Next Generation Nuclear Plant (NGNP) Program will be irradiating six nuclear graphite creep experiments in the Advanced Test Reactor (ATR) located at the Idaho National Laboratory (INL). The graphite experiments will be irradiated over the next six to eight years to support development of a graphite irradiation performance data base on the new nuclear grade graphites now available for use in high temperature gas reactors. The goals of the irradiation experiments are to obtain irradiation performance data, including irradiation creep, at different temperatures and loading conditions to support design of the next generation nuclear plant (NGNP) very high temperature gas reactor, as well as other future gas reactors. The experiments will each consist of a single capsule that will contain six peripheral stacks of graphite specimens, with half of the graphite specimens in each stack under a compressive load, while the other half of the specimens will not be subjected to a compressive load during irradiation. The six peripheral stacks will have three different compressive loads applied to the top half of three diametrically opposite pairs of specimen stacks, while a seventh stack will not have a compressive load. The specimens will be irradiated in an inert sweep gas atmosphere with on-line temperature and compressive load monitoring and control. There will also be sampling the sweep gas effluent to determine if any oxidation or off-gassing of the specimens occurs during irradiation of the experiment.

  2. Ultrasonic irradiation of deuterium-loaded palladium particles suspended in heavy water

    SciTech Connect (OSTI)

    Jorne, J.

    1996-01-01

    Ultrasonic irradiation of a slurry of deuterium-loaded palladium powder (1 {mu}m) suspended in heavy water causes cavitation and high-speed collisions between the palladium particles. High local temperatures, estimated at above the melting point of palladium (1828 K), cause melting and interparticle fusion. The expectation that such collisions can induce high stresses within the palladium particles and lead to favorable conditions for nuclear cold fusion of the deuterium atoms within the palladium lattice is checked by measuring the neutron rates during ultrasonic irradiation. Several bursts of neutron counting are observed and can be accounted for as background anomalism, although the highest observed neutron rate is about four times the background and cannot be explained as background. The X-ray photoelectron spectroscopy analysis of the deuterium-loaded palladium powders reveals that after ultrasonic irradiation in heavy water, the palladium powder becomes partially oxidized and undergoes some compositional changes. 18 refs., 7 figs., 1 tab.

  3. Thermal stability of fission gas bubble superlattice in irradiated U10Mo fuel

    SciTech Connect (OSTI)

    Gan, J.; Keiser, D. D.; Miller, B. D.; Robinson, A. B.; Wachs, D. M.; Meyer, M. K.

    2015-09-01

    To investigate the thermal stability of the fission gas bubble superlattice, a key microstructural feature in both irradiated U-7Mo dispersion and U-10Mo monolithic fuel plates, a FIB-TEM sample of the irradiated U-10Mo fuel with a local fission density of 3.51021 fissions/cm3 was used for an in-situ heating TEM experiment. The temperature of the heating holder was raised at a ramp rate of approximately 10 C/min up to ~700 C, kept at that temperature for about 34 min, continued to 850 C with a reduced rate of 5 C/min. The result shows a high thermal stability of the fission gas bubble superlattice. The implication of this observation on the fuel microstructural evolution and performance under irradiation is discussed.

  4. Feasibility of irradiating Washington fruits and vegetables for Asian export markets

    SciTech Connect (OSTI)

    Eakin, D.E.; Hazelton, R.F.; Young, J.K.; Prenguber, B.A.; O'Rourke, A.D.; Heim, M.N.

    1987-05-01

    US agricultural export marketing opportunities are limited by the existence of trade barriers in many overseas countries. For example, Japan and South Korea do not permit the importation of apples due to their stated concern over codling moth infestation. One of the purposes of this study was to evaluate the potential of exporting irradiated fruits and vegetables from Washington State to overcome existing trade barriers and prevent the establishment of future barriers. The Asian countries specifically evaluated in this study are Japan, Hong Kong and Singapore. Another purpose of this project was to determine the feasibility of locating an irradiation facility in Washington State. Advantages that irradiated agricultural products would bring in terms of price and quality in export markets were also evaluated.

  5. Laser irradiance scaling in polar direct drive implosions on the National Ignition Facility

    SciTech Connect (OSTI)

    Murphy, T. J.; Krasheninnikova, N. S.; Kyrala, G. A.; Bradley, P. A.; Baumgaertel, J. A.; Cobble, J. A.; Hakel, P.; Hsu, S. C.; Kline, J. L.; Montgomery, D. S.; Obrey, K. A. D.; Shah, R. C.; Tregillis, I. L.; Schmitt, M. J.; Kanzleiter, R. J.; Batha, S. H.; Wallace, R. J.; Bhandarkar, S. D.; Fitzsimmons, P.; Hoppe, M. L.; Nikroo, A.; Hohenberger, M.; McKenty, P. W.; Rinderknecht, H. G.; Rosenberg, M. J.; Petrasso, R. D.

    2015-09-17

    Polar-direct-drive experiments conducted at the National Ignition Facility [E. I. Moses, Fusion Sci. Technol. 54, 361 (2008)] performed at laser irradiance between 1 and 2×1015 W/cm2 exhibit increased hard x-ray emission, decreased neutron yield, and reduced areal density as the irradiance is increased. Experimental x-ray images at the higher irradiances show x-ray emission at the equator, as well as degraded symmetry, that is not predicted in hydrodynamic simulations using flux-limited energy transport, but that appear when non-local electron transport together with a model to account for cross beam energy transfer (CBET) is utilized. The reduction in laser power for equatorial beams required in the simulations to reproduce the effects of CBET on the observed symmetry also reproduces the yield degradation consistent with experimental data.

  6. Microstructural Characterization of Irradiated U-7Mo/Al-5Si Dispersion to High Fission Density

    SciTech Connect (OSTI)

    J. Gan; B. D. Miller; D. D. Keiser, Jr.; A. B. Robinson; J. W. Madden; P. G. Medvedev; D. M. Wachs

    2014-11-01

    The fuel development program for research and test reactors calls for improved knowledge on the effect of microstructure on fuel performance in reactors. This work summarizes the recent TEM microstructural characterization of an irradiated U-7Mo/Al-5Si dispersion fuel plate (R3R050) irradiated in the Advanced Test Reactor (ATR) at Idaho National Laboratory to 5.21021 fissions/cm3. While a large fraction of the fuel grains is decorated with large bubbles, there is no evidence showing interlinking of these large bubbles at the specified fission density. The attachment of solid fission product precipitates to the bubbles is likely the result of fission product diffusion into these bubbles. The process of fission gas bubble superlattice collapse appears through bubble coalescence. The results are compared with the previous TEM work of the dispersion fuels irradiated to lower fission density from the same fuel plate.

  7. Laser irradiance scaling in polar direct drive implosions on the National Ignition Facility

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Murphy, T. J.; Krasheninnikova, N. S.; Kyrala, G. A.; Bradley, P. A.; Baumgaertel, J. A.; Cobble, J. A.; Hakel, P.; Hsu, S. C.; Kline, J. L.; Montgomery, D. S.; et al

    2015-09-17

    Polar-direct-drive experiments conducted at the National Ignition Facility [E. I. Moses, Fusion Sci. Technol. 54, 361 (2008)] performed at laser irradiance between 1 and 2×1015 W/cm2 exhibit increased hard x-ray emission, decreased neutron yield, and reduced areal density as the irradiance is increased. Experimental x-ray images at the higher irradiances show x-ray emission at the equator, as well as degraded symmetry, that is not predicted in hydrodynamic simulations using flux-limited energy transport, but that appear when non-local electron transport together with a model to account for cross beam energy transfer (CBET) is utilized. The reduction in laser power for equatorialmore » beams required in the simulations to reproduce the effects of CBET on the observed symmetry also reproduces the yield degradation consistent with experimental data.« less

  8. Performance and breakdown characteristics of irradiated vertical power GaN P-i-N diodes

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    King, M. P.; Armstrong, A. M.; Dickerson, J. R.; Vizkelethy, G.; Fleming, R. M.; Campbell, J.; Wampler, W. R.; Kizilyalli, I. C.; Bour, D. P.; Aktas, O.; et al

    2015-10-29

    Electrical performance and defect characterization of vertical GaN P-i-N diodes before and after irradiation with 2.5 MeV protons and neutrons is investigated. Devices exhibit increase in specific on-resistance following irradiation with protons and neutrons, indicating displacement damage introduces defects into the p-GaN and n- drift regions of the device that impact on-state device performance. The breakdown voltage of these devices, initially above 1700 V, is observed to decrease only slightly for particle fluence <; 1013 cm-2. Furthermore, the unipolar figure of merit for power devices indicates that while the on-resistance and breakdown voltage degrade with irradiation, vertical GaN P-i-Ns remainmore » superior to the performance of the best available, unirradiated silicon devices and on-par with unirradiated modern SiC-based power devices.« less

  9. Uncertainty Analysis of Spectral Irradiance Reference Standards Used for NREL Calibrations

    SciTech Connect (OSTI)

    Habte, A.; Andreas, A.; Reda, I.; Campanelli, M.; Stoffel, T.

    2013-05-01

    Spectral irradiance produced by lamp standards such as the National Institute of Standards and Technology (NIST) FEL-type tungsten halogen lamps are used to calibrate spectroradiometers at the National Renewable Energy Laboratory. Spectroradiometers are often used to characterize spectral irradiance of solar simulators, which in turn are used to characterize photovoltaic device performance, e.g., power output and spectral response. Therefore, quantifying the calibration uncertainty of spectroradiometers is critical to understanding photovoltaic system performance. In this study, we attempted to reproduce the NIST-reported input variables, including the calibration uncertainty in spectral irradiance for a standard NIST lamp, and quantify uncertainty for measurement setup at the Optical Metrology Laboratory at the National Renewable Energy Laboratory.

  10. Blue photoluminescence enhancement in laser-irradiated 6H-SiC at room temperature

    SciTech Connect (OSTI)

    Wu, Yan; Ji, Lingfei Lin, Zhenyuan; Jiang, Yijian; Zhai, Tianrui

    2014-01-27

    Blue photoluminescence (PL) of 6H-SiC irradiated by an ultraviolet laser can be observed at room temperature in dark condition. PL spectra with Gaussian fitting curve of the irradiated SiC show that blue luminescence band (?440?nm) is more pronounced than other bands. The blue PL enhancement is the combined result of the improved shallow N-donor energy level and the unique surface state with Si nanocrystals and graphene/Si composite due to the effect of photon energy input by the short-wavelength laser irradiation. The study can provide a promising route towards the preparation of well-controlled blue photoluminescence material for light-emitting devices.

  11. Apparatus for irradiating a continuously flowing stream of fluid. [For neutron activation analysis

    DOE Patents [OSTI]

    Speir, L.G.; Adams, E.L.

    1982-05-13

    An apparatus for irradiating a continuously flowing stream of fluid is disclosed. The apparatus consists of a housing having a spherical cavity and a spherical moderator containing a radiation source positioned within the spherical cavity. The spherical moderator is of lesser diameter than the spherical cavity so as to define a spherical annular volume around the moderator. The housing includes fluid intake and output conduits which open onto the spherical cavity at diametrically opposite positions. Fluid flows through the cavity around the spherical moderator and is uniformly irradiated due to the 4..pi.. radiation geometry. The irradiation source, for example a /sup 252/Cf neutron source, is removable from the spherical moderator through a radial bore which extends outwardly to an opening on the outside of the housing. The radiation source may be routinely removed without interrupting the flow of fluid or breaching the containment of the fluid.

  12. Microstructural, thermal and antibacterial properties of electron beam irradiated Bombyx mori silk fibroin films

    SciTech Connect (OSTI)

    Asha, S.; Sanjeev, Ganesh; Sangappa; Naik, Prashantha; Chandra, K. Sharat

    2014-04-24

    The Bombyx mori silk fibroin (SF) films were prepared by solution casting method and the effects of electron beam on structural, thermal and antibacterial responses of the prepared films were studied. The electron irradiation for different doses was carried out using 8 MeV Microtron facility at Mangalore University. The changes in microstructural parameters and thermal stability of the films were investigated using Wide Angle X-ray Scattering (WAXS) and thermogravimetric analysis (TGA) respectively. Both microstructuralline parameters (crystallite size and lattice strain (g in %)) and thermal stability of the irradiated films have increased with radiation dosage. Agar diffusion method demonstrated the antibacterial activity of SF film which was increased after irradiation on both Gram-positive and Gram-negative species.

  13. Manipulation of transport hysteresis on graphene field effect transistors with Ga ion irradiation

    SciTech Connect (OSTI)

    Wang, Quan, E-mail: wangq@mail.ujs.edu.cn [School of Mechanical Engineering, Jiangsu University, Zhenjiang 212013 (China); State Key Laboratory of Transducer Technology, Chinese Academy of Sciences, Shanghai 200050 (China); Liu, Shuai; Ren, Naifei [School of Mechanical Engineering, Jiangsu University, Zhenjiang 212013 (China)

    2014-09-29

    We have studied the effect of Ga ion irradiation on the controllable hysteretic behavior of graphene field effect transistors fabricated on Si/SO{sub 2} substrates. The various densities of defects in graphene were monitored by Raman spectrum. It was found that the Dirac point shifted to the positive gate voltage constantly, while the hysteretic behavior was enhanced first and then weakened, with the dose of ion irradiation increasing. By contrasting the trap charges density induced by dopant and the total density of effective trap charges, it demonstrated that adsorbate doping was not the decisive factor that induced the hysteretic behavior. The tunneling between the defect sites induced by ion irradiation was also an important cause for the hysteresis.

  14. THEORY OF A QUODON GAS WITH APPLICATION TO PRECIPITATION KINETICS IN SOLIDS UNDER IRRADIATION

    SciTech Connect (OSTI)

    Dubinko, Volodymyr; Shapovalov, Roman V.

    2014-06-17

    Rate theory of the radiation-induced precipitation in solids is modified with account of non-equilibrium fluctuations driven by the gas of lattice solitons (a.k.a. quodons) produced by irradiation. According to quantitative estimations, a steady-state density of the quodon gas under sufficiently intense irradiation can be comparable to the density of classical phonon gas. The modified rate theory is applied to modelling of copper precipitation in FeCu binary alloys under electron irradiation. In contrast to the classical rate theory, which disagrees strongly with experimental data on all precipitation parameters, the modified rate theory describes quite well both the evolution of precipitates and the matrix concentration of copper measured by different methods.

  15. Pyrolysis of Municipal Solid Waste for Syngas Production by Microwave Irradiation

    SciTech Connect (OSTI)

    Gedam, Vidyadhar V.; Regupathi, Iyyaswami

    2012-03-15

    In the present study, we discuss the application of microwave-irradiated pyrolysis of municipal solid waste (MSW) for total recovery of useful gases and energy. The MSW pyrolysis under microwave irradiation highly depends on the process parameters, like microwave power, microwave absorbers, and time of irradiation. The thoroughness of pyrolysis and product recovery were studied by changing the abovesaid variables. Pyrolysis of MSW occurs in the power rating range of 450-850 W-outside this power rating range, pyrolysis is not possible. Experiments were carried out using various microwave absorbers (i.e., graphite, charcoal, and iron) to enhance the pyrolysis even at lower power rating. The results show that the pyrolysis of MSW was possible even at low power ratings. The major composition of the pyrolysis gaseous product were analyzed with GC-MS which includes CO{sub 2}, CO, CH{sub 4}, etc.

  16. AGR-1 Irradiation Test Final As-Run Report, Rev. 3

    SciTech Connect (OSTI)

    Collin, Blaise P.

    2015-01-01

    This document presents the as-run analysis of the AGR-1 irradiation experiment. AGR-1 is the first of eight planned irradiations for the Advanced Gas Reactor (AGR) Fuel Development and Qualification Program. Funding for this program is provided by the US Department of Energy (DOE) as part of the Next-Generation Nuclear Plant (NGNP) project. The objectives of the AGR-1 experiment are: 1. To gain experience with multi-capsule test train design, fabrication, and operation with the intent to reduce the probability of capsule or test train failure in subsequent irradiation tests. 2. To irradiate fuel produced in conjunction with the AGR fuel process development effort. 3. To provide data that will support the development of an understanding of the relationship between fuel fabrication processes, fuel product properties, and irradiation performance. In order to achieve the test objectives, the AGR-1 experiment was irradiated in the B-10 position of the Advanced Test Reactor (ATR) at the Idaho National Laboratory (INL) for a total duration of 620 effective full power days of irradiation. Irradiation began on December 24, 2006 and ended on November 6, 2009 spanning 13 ATR cycles and approximately three calendar years. The test contained six independently controlled and monitored capsules. Each capsule contained 12 compacts of a single type, or variant, of the AGR coated fuel. No fuel particles failed during the AGR-1 irradiation. Final burnup values on a per compact basis ranged from 11.5 to 19.6 %FIMA, while fast fluence values ranged from 2.21 to 4.39 x 1025 n/m2 (E >0.18 MeV). Well say something here about temperatures once thermal recalc is done. Thermocouples performed well, failing at a lower rate than expected. At the end of the irradiation, nine of the originally-planned 19 TCs were considered functional. Fission product release-to-birth (R/B) ratios were quite low. In most capsules, R/B values at the end of the irradiation were at or below 10-7 with only one capsule significantly exceeding this value. A maximum R/B of around 2 x 10-7 was reached at the end of the irradiation in Capsule 5. Several shakedown issues were encountered and resolved during the first three cycles. These include the repair of minor gas line leaks; repair of faulty gas line valves; the need to position moisture monitors in regions of low radiation fields for proper functioning; the enforcement of proper on-line data storage and backup, the need to monitor thermocouple performance, correcting for detector spectral gain shift, and a change in the mass flow rate range of the neon flow controllers.

  17. Assessment of Initial Test Conditions for Experiments to Assess Irradiation Assisted Stress Corrosion Cracking Mechanisms

    SciTech Connect (OSTI)

    Busby, Jeremy T; Gussev, Maxim N

    2011-04-01

    Irradiation-assisted stress corrosion cracking is a key materials degradation issue in today s nuclear power reactor fleet and affects critical structural components within the reactor core. The effects of increased exposure to irradiation, stress, and/or coolant can substantially increase susceptibility to stress-corrosion cracking of austenitic steels in high-temperature water environments. . Despite 30 years of experience, the underlying mechanisms of IASCC are unknown. Extended service conditions will increase the exposure to irradiation, stress, and corrosive environment for all core internal components. The objective of this effort within the Light Water Reactor Sustainability program is to evaluate the response and mechanisms of IASCC in austenitic stainless steels with single variable experiments. A series of high-value irradiated specimens has been acquired from the past international research programs, providing a valuable opportunity to examine the mechanisms of IASCC. This batch of irradiated specimens has been received and inventoried. In addition, visual examination and sample cleaning has been completed. Microhardness testing has been performed on these specimens. All samples show evidence of hardening, as expected, although the degree of hardening has saturated and no trend with dose is observed. Further, the change in hardening can be converted to changes in mechanical properties. The calculated yield stress is consistent with previous data from light water reactor conditions. In addition, some evidence of changes in deformation mode was identified via examination of the microhardness indents. This analysis may provide further insights into the deformation mode under larger scale tests. Finally, swelling analysis was performed using immersion density methods. Most alloys showed some evidence of swelling, consistent with the expected trends for this class of alloy. The Hf-doped alloy showed densification rather than swelling. This observation may be related to the formation of second-phases under irradiation, although further examination is required

  18. A Method of Correcting for Tilt From Horizontal in Downwelling Shortwave Irradiance Measurements on Moving Platforms

    SciTech Connect (OSTI)

    Long, Charles N.; Bucholtz, Anthony; Jonsson, Haf; Schmid, Beat; Vogelmann, A. M.; Wood, John

    2010-04-14

    Significant errors occur in downwelling shortwave irradiance measurements made on moving platforms due to tilt from horizontal because, when the sun is not completely blocked by overhead cloud, the downwelling shortwave irradiance has a prominent directional component from the direct sun. A-priori knowledge of the partitioning between the direct and diffuse components of the total shortwave irradiance is needed to properly apply a correction for tilt. This partitioning information can be adequately provided using a newly available commercial radiometer that produces reasonable measurements of the total and diffuse shortwave irradiance, and by subtraction the direct shortwave irradiance, with no moving parts and regardless of azimuthal orientation. We have developed methodologies for determining the constant pitch and roll offsets of the radiometers for aircraft applications, and for applying a tilt correction to the total shortwave irradiance data. Results suggest that the methodology is for tilt up to +/-10, with 90% of the data corrected to within 10 Wm-2 at least for clear-sky data. Without a proper tilt correction, even data limited to 5 of tilt as is typical current practice still exhibits large errors, greater than 100 Wm-2 in some cases. Given the low cost, low weight, and low power consumption of the SPN1 total and diffuse radiometer, opportunities previously excluded for moving platform measurements such as small Unmanned Aerial Vehicles and solar powered buoys now become feasible using our methodology. The increase in measurement accuracy is important, given current concerns over long-term climate variability and change especially over the 70% of the Earths surface covered by ocean where long-term records of these measurements are sorely needed and must be made on ships and buoys.

  19. Defect evolution in single crystalline tungsten following low temperature and low dose neutron irradiation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hu, Xunxiang; Koyanagi, Takaaki; Fukuda, Makoto; Katoh, Yutai; Wirth, Brian D; Snead, Lance Lewis

    2016-01-01

    The tungsten plasma-facing components of fusion reactors will experience an extreme environment including high temperature, intense particle fluxes of gas atoms, high-energy neutron irradiation, and significant cyclic stress loading. Irradiation-induced defect accumulation resulting in severe thermo-mechanical property degradation is expected. For this reason, and because of the lack of relevant fusion neutron sources, the fundamentals of tungsten radiation damage must be understood through coordinated mixed-spectrum fission reactor irradiation experiments and modeling. In this study, high-purity (110) single-crystal tungsten was examined by positron annihilation spectroscopy and transmission electron microscopy following low-temperature (~90 °C) and low-dose (0.006 and 0.03 dpa) mixed-spectrum neutronmore » irradiation and subsequent isochronal annealing at 400, 500, 650, 800, 1000, 1150, and 1300 °C. The results provide insights into microstructural and defect evolution, thus identifying the mechanisms of different annealing behavior. Following 1 h annealing, ex situ characterization of vacancy defects using positron lifetime spectroscopy and coincidence Doppler broadening was performed. The vacancy cluster size distributions indicated intense vacancy clustering at 400 °C with significant damage recovery around 1000 °C. Coincidence Doppler broadening measurements confirm the trend of the vacancy defect evolution, and the S–W plots indicate that only a single type of vacancy cluster is present. Furthermore, transmission electron microscopy observations at selected annealing conditions provide supplemental information on dislocation loop populations and visible void formation. This microstructural information is consistent with the measured irradiation-induced hardening at each annealing stage. This provides insight into tungsten hardening and embrittlement due to irradiation-induced matrix defects.« less

  20. Post-Irradiation Examination of 237Np Targets for 238Pu Production

    SciTech Connect (OSTI)

    Morris, Robert Noel [ORNL; Baldwin, Charles A [ORNL; Hobbs, Randy W [ORNL; Schmidlin, Joshua E [ORNL

    2015-01-01

    Oak Ridge National Laboratory is recovering the US 238Pu production capability and the first step in the process has been to evaluate the performance of a 237Np target cermet pellet encased in an aluminum clad. The process proceeded in 3 steps; the first step was to irradiate capsules of single pellets composed of NpO2 and aluminum power to examine their shrinkage and gas release. These pellets were formed by compressing sintered NpO2 and aluminum powder in a die at high pressure followed by sintering in a vacuum furnace. Three temperatures were chosen for sintering the solution precipitated NpO2 power used for pellet fabrication. The second step was to irradiate partial targets composed of 8 pellets in a semi-prototypical arrangement at the two best performing sintering temperatures to determine which temperature gave a pellet that performed the best under the actual planned irradiation conditions. The third step was to irradiate ~50 pellets in an actual target configuration at design irradiation conditions to assess pellet shrinkage and gas release, target heat transfer, and dimensional stability. The higher sintering temperature appeared to offer the best performance after one cycle of irradiation by having the least shrinkage, thus keeping the heat transfer gap between the pellets and clad small minimizing the pellet operating temperature. The final result of the testing was a target that can meet the initial production goals, satisfy the reactor safety requirements, and can be fabricated in production quantities. The current focus of the program is to verify that the target can be remotely dissembled, the pellets dissolved, and the 238Pu recovered. Tests are being conducted to examine these concerns and to compare results to code predictions. Once the performance of the full length targets has been quantified, the pellet 237Np loading will be revisited to determine if it can be increased to increase 238Pu production.

  1. Factors Associated With the Development of Breast Cancer-Related Lymphedema After Whole-Breast Irradiation

    SciTech Connect (OSTI)

    Shah, Chirag; Wilkinson, John Ben; Baschnagel, Andrew; Ghilezan, Mihai; Riutta, Justin; Dekhne, Nayana; Balaraman, Savitha; Mitchell, Christina; Wallace, Michelle; Vicini, Frank

    2012-07-15

    Purpose: To determine the rates of breast cancer-related lymphedema (BCRL) in patients undergoing whole-breast irradiation as part of breast-conserving therapy (BCT) and to identify clinical, pathologic, and treatment factors associated with its development. Methods and Materials: A total of 1,861 patients with breast cancer were treated at William Beaumont Hospital with whole-breast irradiation as part of their BCT from January 1980 to February 2006, with 1,497 patients available for analysis. Determination of BCRL was based on clinical assessment. Differences in clinical, pathologic, and treatment characteristics between patients with BCRL and those without BCRL were evaluated, and the actuarial rates of BCRL by regional irradiation technique were determined. Results: The actuarial rate of any BCRL was 7.4% for the entire cohort and 9.9%, 14.7%, and 8.3% for patients receiving a supraclavicular field, posterior axillary boost, and internal mammary irradiation, respectively. BCRL was more likely to develop in patients with advanced nodal status (11.4% vs. 6.3%, p = 0.001), those who had a greater number of lymph nodes removed (14 nodes) (9.5% vs. 6.0%, p = 0.01), those who had extracapsular extension (13.4% vs. 6.9%, p = 0.009), those with Grade II/III disease (10.8% vs. 2.9%, p < 0.001), and those who received adjuvant chemotherapy (10.5% vs. 6.7%, p = 0.02). Regional irradiation showed small increases in the rates of BCRL (p = not significant). Conclusions: These results suggest that clinically detectable BCRL will develop after traditional BCT in up to 10% of patients. High-risk subgroups include patients with advanced nodal status, those with more nodes removed, and those who receive chemotherapy, with patients receiving regional irradiation showing a trend toward increased rates.

  2. Quantifying Aerosol Direct Effects from Broadband Irradiance and Spectral Aerosol Optical Depth Observations

    SciTech Connect (OSTI)

    Creekmore, Torreon N.; Joseph, Everette; Long, Charles N.; Li, Siwei

    2014-05-16

    We outline a methodology using broadband and spectral irradiances to quantify aerosol direct effects on the surface diffuse shortwave (SW) irradiance. Best Estimate Flux data span a 13 year timeframe at the Department of Energy Atmospheric Radiation Measurement Program’s Southern Great Plains (SGP) site. Screened clear-sky irradiances and aerosol optical depth (AOD), for solar zenith angles ≤ 65°, are used to estimate clear-sky diffuse irradiances. We validate against detected clear-sky observations from SGP’s Basic Radiation System (BRS). BRS diffuse irradiances were in accordance with estimates, producing a root-mean-square error and mean bias errors of 4.0 W/m2 and -1.4 W/m2, respectively. Absolute differences show 99% of estimates within ±10 W/m2 (10%) of the mean BRS observations. Clear-sky diffuse estimates are used to derive quantitative estimates of aerosol radiative effects, represented as the aerosol diffuse irradiance (ADI). ADI is the contribution of diffuse SW to global SW, attributable to scattering of atmospheric transmission by natural plus anthropogenic aerosols. Estimated slope for the ADI as a function of AOD indicates an increase of ~22 W/m2 in diffuse SW for every 0.1 increase in AOD. Such significant increases in the diffuse fraction could possibly increase photosynthesis. Annual mean ADI is 28.2 W/m2, and heavy aerosol loading at SGP provides up to a maximum increase of 120 W/m2 in diffuse SW over background conditions. With regard to seasonal variation, the mean diffuse forcings are 17.2, 33.3, 39.0, and 23.6 W/m2 for winter, spring, summer, and fall, respectively.

  3. ``Sleeping reactor`` irradiations: Shutdown reactor determination of short-lived activation products

    SciTech Connect (OSTI)

    Jerde, E.A.; Glasgow, D.C.

    1998-09-01

    At the High-Flux Isotope Reactor (HFIR) at the Oak Ridge National Laboratory, the principal irradiation system has a thermal neutron flux ({phi}) of {approximately} 4 {times} 10{sup 14} n/cm{sup 2} {center_dot} s, permitting the detection of elements via irradiation of 60 s or less. Irradiations of 6 or 7 s are acceptable for detection of elements with half-lives of as little as 30 min. However, important elements such as Al, Mg, Ti, and V have half-lives of only a few minutes. At HFIR, these can be determined with irradiation times of {approximately} 6 s, but the requirement of immediate counting leads to increased exposure to the high activity produced by irradiation in the high flux. In addition, pneumatic system timing uncertainties (about {+-} 0.5 s) make irradiations of < 6 s less reliable. Therefore, the determination of these ultra-short-lived species in mixed matrices has not generally been made at HFIR. The authors have found that very short lived activation products can be produced easily during the period after reactor shutdown (SCRAM), but prior to the removal of spent fuel elements. During this 24- to 36-h period (dubbed the ``sleeping reactor``), neutrons are produced in the beryllium reflector by the reaction {sup 9}Be({gamma},n){sup 8}Be, the gamma rays principally originating in the spent fuel. Upon reactor SCRAM, the flux drops to {approximately} 1 {times} 10{sup 10} n/cm{sup 2} {center_dot} s within 1 h. By the time the fuel elements are removed, the flux has dropped to {approximately} 6 {times} 10{sup 8}. Such fluxes are ideal for the determination of short-lived elements such as Al, Ti, Mg, and V. An important feature of the sleeping reactor is a flux that is not constant.

  4. Cracking behavior and microstructure of austenitic stainless steels and alloy 690 irradiated in BOR-60 reactor, phase I.

    SciTech Connect (OSTI)

    Chen, Y.; Chopra, O. K.; Soppet, W. K.; Shack, W. J.; Yang, Y.; Allen, T. R.; Univ. of Wisconsin at Madison

    2010-02-16

    Cracking behavior of stainless steels specimens irradiated in the BOR-60 at about 320 C is studied. The primary objective of this research is to improve the mechanistic understanding of irradiation-assisted stress corrosion cracking (IASCC) of core internal components under conditions relevant to pressurized water reactors. The current report covers several baseline tests in air, a comparison study in high-dissolved-oxygen environment, and TEM characterization of irradiation defect structure. Slow strain rate tensile (SSRT) tests were conducted in air and in high-dissolved-oxygen (DO) water with selected 5- and 10-dpa specimens. The results in high-DO water were compared with those from earlier tests with identical materials irradiated in the Halden reactor to a similar dose. The SSRT tests produced similar results among different materials irradiated in the Halden and BOR-60 reactors. However, the post-irradiation strength for the BOR-60 specimens was consistently lower than that of the corresponding Halden specimens. The elongation of the BOR-60 specimens was also greater than that of their Halden specimens. Intergranular cracking in high-DO water was consistent for most of the tested materials in the Halden and BOR-60 irradiations. Nonetheless, the BOR-60 irradiation was somewhat less effective in stimulating IG fracture among the tested materials. Microstructural characterization was also carried out using transmission electron microscopy on selected BOR-60 specimens irradiated to {approx}25 dpa. No voids were observed in irradiated austenitic stainless steels and cast stainless steels, while a few voids were found in base and grain-boundary-engineered Alloy 690. All the irradiated microstructures were dominated by a high density of Frank loops, which varied in mean size and density for different alloys.

  5. Degradation mechanism of Ni-based superalloy under extreme irradiation environments

    SciTech Connect (OSTI)

    Sun, Cheng

    2015-12-08

    This report is a description of various materials (in particular, Rene N4) and their resilience under chemical, physical, and radioactive changes caused by heavy ion irradiation in the MeV range. The following conclusions were reached: the γ' precipitates become fully disordered at a dose of 0.3 dpa: the γ' precipitates partially dissolve after irradiation up to 75 dpa, and the chemical intermixing mainly originates from thermal spike effects; and combining effects of defect clusters, disordering and dissolution determine the evolution of hardness. This work is relevant to materials challenges for Gen IV reactors.

  6. The effect of irradiation on extraction of various metals by C5-BTBP

    SciTech Connect (OSTI)

    Fermvik, A.; Retegan, T.; Skarnemark, G.; Ekberg, C.; Foreman, M.R.S.

    2008-07-01

    Different polycyclic molecules containing nitrogen have been developed to be used as extractants in the separation of actinides(III) from lanthanides(III) in the spent nuclear-fuel treatment. During a potential industrial process involving nuclear waste, the extractant will be exposed to high doses of ionizing radiation; hence, the extractant should be resistant towards irradiation. This study explores the capacity of an irradiated solution of C5-BTBP in cyclohexanone to extract Eu and Am but also the fission and corrosion products Pd, Ag, and Cd. (authors)

  7. Mobile computing device configured to compute irradiance, glint, and glare of the sun

    DOE Patents [OSTI]

    Gupta, Vipin P; Ho, Clifford K; Khalsa, Siri Sahib

    2014-03-11

    Described herein are technologies pertaining to computing the solar irradiance distribution on a surface of a receiver in a concentrating solar power system or glint/glare emitted from a reflective entity. A mobile computing device includes at least one camera that captures images of the Sun and the entity of interest, wherein the images have pluralities of pixels having respective pluralities of intensity values. Based upon the intensity values of the pixels in the respective images, the solar irradiance distribution on the surface of the entity or glint/glare corresponding to the entity is computed by the mobile computing device.

  8. Joint Summer School on "Atomic-level Response of Materials to Irradiation"

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    | U.S. DOE Office of Science (SC) Joint Summer School on "Atomic-level Response of Materials to Irradiation" Energy Frontier Research Centers (EFRCs) EFRCs Home Centers Research Science Highlights News & Events EFRC News EFRC Events DOE Announcements Publications History Contact BES Home 04.09.10 Joint Summer School on "Atomic-level Response of Materials to Irradiation" Print Text Size: A A A Subscribe FeedbackShare Page June 20 - 25, 2010 :: Joint Summer School on

  9. Lattice Distortions and Oxygen Vacancies Produced in Au+-Irradiated Nanocrystalline Cubic Zirconia

    SciTech Connect (OSTI)

    Edmondson, P. D.; Weber, William J.; Namavar, Fereydoon; Zhang, Yanwen

    2011-07-13

    The oxygen ion conductivity, attributed to an oxygen vacancy mechanism, of yttria-stabilized zirconia membranes used in solid oxide fuel cells is restricted due to trapping limitations. In this work, a high concentration of oxygen vacancies has been deliberately introduced into nanocrystalline stabilizer-free zirconia through ion-irradiation. Oxygen vacancies with different charge states can be produced by varying irradiation temperatures. Due to the reduced trapping sites and high oxygen vacancy concentration, this work suggests that the efficiency of solid oxide fuel cells can be improved.

  10. Self-irradiation damage to the local structure of plutonium and plutonium

    Office of Scientific and Technical Information (OSTI)

    intermetallics (Journal Article) | SciTech Connect Self-irradiation damage to the local structure of plutonium and plutonium intermetallics Citation Details In-Document Search Title: Self-irradiation damage to the local structure of plutonium and plutonium intermetallics Authors: Booth, C. H. ; Jiang, Yu ; Medling, S. A. ; Wang, D. L. ; Costello, A. L. ; Schwartz, D. S. ; Mitchell, J. N. ; Tobash, P. H. ; Bauer, E. D. ; McCall, S. K. ; Wall, M. A. ; Allen, P. G. Publication Date: 2013-01-01

  11. Evaluation of In-Situ Tritium Transport Parameters for Type 316 Stainless Steel during Irradiation

    Office of Environmental Management (EM)

    In-Situ Tritium Transport Parameters for Type 316 Stainless Steel during Irradiation D.J. Senor, W.G. Luscher K.K. Clayton, G.R. Longhurst Tritium Focus Group Meeting Savannah River National Laboratory Aiken, SC 23 April 2014 PNNL-SA-102143 Motivation and Scope TMIST-2 Experiment Measured in-reactor steady state tritium permeation through Type 316 stainless steel as a function of tritium partial pressure and temperature Tritium permeation irradiation enhancement of ~3X was observed relative to

  12. Integral Validation of Minor Actinide Nuclear Data by using Samples Irradiated at Dounreay Prototype Fast Reactor

    SciTech Connect (OSTI)

    Tsujimoto, Kazufumi; Oigawa, Hiroyuki; Shinohara, Nobuo [Japan Atomic Energy Research Institute, Shirakata Shirane 2-4, Tokai, Ibaraki 319-1195 (Japan)

    2005-05-24

    The reliability of nuclear data for minor actinides was evaluated by using the results of the post-irradiation experiment for actinide samples irradiated at the Dounreay Prototype Fast Reactor. The burnup calculations with JENDL-3.3, ENDF/B-VI.8, and JEFF-3.0 were performed. From the comparison between the experimental data and the calculational results, in general, the reliability of nuclear data for the minor actinides are at an adequate level for the conceptual design study of transmutation systems. It is, however, found that improvement of the accuracy is necessary for some nuclides, such as 238Pu, 242Pu, and 241Am.

  13. Physiological and molecular characterization of the enhanced salt tolerance induced by low-dose gamma irradiation in Arabidopsis seedlings

    SciTech Connect (OSTI)

    Qi, Wencai; Zhang, Liang; Xu, Hangbo; Wang, Lin; Jiao, Zhen

    2014-07-25

    Highlights: 50-Gy gamma irradiation markedly promotes the seedling growth under salt stress in Arabidopsis. The contents of H{sub 2}O{sub 2} and MDA are obviously reduced by low-dose gamma irradiation under salt stress. Low-dose gamma irradiation stimulates the activities of antioxidant enzymes under salt stress. Proline accumulation is required for the low-gamma-ray-induced salt tolerance. Low gamma rays differentially regulate the expression of genes related to salt stress. - Abstract: It has been established that gamma rays at low doses stimulate the tolerance to salt stress in plants. However, our knowledge regarding the molecular mechanism underlying the enhanced salt tolerance remains limited. In this study, we found that 50-Gy gamma irradiation presented maximal beneficial effects on germination index and root length in response to salt stress in Arabidopsis seedlings. The contents of H{sub 2}O{sub 2} and MDA in irradiated seedlings under salt stress were significantly lower than those of controls. The activities of antioxidant enzymes and proline levels in the irradiated seedlings were markedly increased compared with the controls. Furthermore, transcriptional expression analysis of selected genes revealed that some components of salt stress signaling pathways were stimulated by low-dose gamma irradiation under salt stress. Our results suggest that gamma irradiation at low doses alleviates the salt stress probably by modulating the physiological responses as well as stimulating the stress signal transduction in Arabidopsis seedlings.

  14. Cavity morphology in a Ni based superalloy under heavy ion irradiation with hot pre-injected helium. II

    SciTech Connect (OSTI)

    Zhang, He; Yao, Zhongwen, E-mail: yaoz@me.queensu.ca; Daymond, Mark R. [Department of Mechanical and Materials Engineering, Queen's University Kingston, Ontario K7L 3N6 (Canada); Kirk, Marquis A. [Material Science Division, Argonne National Laboratory Argonne, Illinois 60439 (United States)

    2014-03-14

    In the current investigation, TEM in-situ heavy ion (1?MeV Kr{sup 2+}) irradiation with helium pre-injected at elevated temperature (400?C) was conducted to simulate in-reactor neutron irradiation induced damage in CANDU spacer material Inconel X-750, in an effort to understand the effects of helium on irradiation induced cavity microstructures. Three different quantities of helium, 400 appm, 1000 appm, and 5000 appm, were pre-injected directly into TEM foils at 400?C. The samples containing helium were then irradiated in-situ with 1?MeV Kr{sup 2+} at 400?C to a final dose of 5.4 dpa (displacement per atom). Cavities were formed from the helium injection solely and the cavity density and size increased with increasing helium dosage. In contrast to previous heavy ion irradiations with cold pre-injected helium, heterogeneous nucleation of cavities was observed. During the ensuing heavy ion irradiation, dynamical observation showed noticeable size increase in cavities which nucleated close to the grain boundaries. A bubble-void transformation was observed after Kr{sup 2+} irradiation to high dose (5.4?dpa) in samples containing 1000 appm and 5000 appm helium. Cavity distribution was found to be consistent with in-reactor neutron irradiation induced cavity microstructures. This implies that the distribution of helium is greatly dependent on the injection temperature, and helium pre-injection at high temperature is preferred for simulating the migration of the transmutation produced helium.

  15. Irradiation dose and temperature dependence of fracture toughness in high dose HT9 steel from the fuel duct of FFTF

    SciTech Connect (OSTI)

    Byun, Thak Sang; Toloczko, Mychailo B.; Saleh, Tarik A.; Maloy, Stuart A.

    2013-01-14

    To expand the knowledge base for fast reactor core materials, fracture toughness has been evaluated for high dose HT9 steel using miniature disk compact tension (DCT) specimens. The HT9 steel DCT specimens were machined from the ACO-3 fuel duct of the Fast Flux Test Facility (FFTF), which achieved high doses in the range of 3148 dpa at 378504 C. The static fracture resistance (J-R) tests have been performed in a servohydraulic testing machine in vacuum at selected temperatures including room temperature, 200 C, and each irradiation temperature. Brittle fracture with a low toughness less than 50 MPa pm occurred in room temperature tests when irradiation temperature was below 400 C, while ductile fracture with stable crack growth was observed when irradiation temperature was higher. No fracture toughness less than 100 MPa pm was measured when the irradiation temperature was above 430 C. It was shown that the influence of irradiation temperature was dominant in fracture toughness while the irradiation dose has only limited influence over the wide dose range 3148 dpa. A slow decrease of fracture toughness with test temperature above room temperature was observed for the nonirradiated and high temperature (>430 *C) irradiation cases, which indicates that the ductilebrittle transition temperatures (DBTTs) in those conditions are lower than room temperature. A comparison with the collection of existing data confirmed the dominance of irradiation temperature in the fracture toughness of HT9 steels.

  16. Irradiation response in weldment and HIP joint of reduced activation ferritic/martensitic steel, F82H

    SciTech Connect (OSTI)

    Hirose, Takanori [Japan Atomic Energy Agency (JAEA); Sokolov, Mikhail A [ORNL; Ando, M. [Japan Atomic Energy Agency (JAEA); Tanigawa, H. [Japan Atomic Energy Agency (JAEA); Shiba, K. [Japan Atomic Energy Agency (JAEA); Stoller, Roger E [ORNL; Odette, G.R. [University of California, Santa Barbara

    2013-11-01

    This work investigates irradiation response in the joints of F82H employed for a fusion breeding blanket. The joints, which were prepared using welding and diffusion welding, were irradiated up to 6 dpa in the High Flux Isotope Reactor at the Oak Ridge National Laboratory. Post-irradiation tests revealed hardening in weldment (WM) and base metal (BM) greater than 300 MPa. However, the heat affected zones (HAZ) exhibit about half that of WM and BM. Therefore, neutron irradiation decreased the strength of the HAZ, leaving it in danger of local deformation in this region. Further the hardening in WM made with an electron beam was larger than that in WM made with tungsten inert gas welding. However the mechanical properties of the diffusion-welded joint were very similar to those of BM even after the irradiation.

  17. Structural Modification of Single Wall and Multiwalled Carbon Nanotubes under Carbon, Nickel and Gold Ion Beam Irradiation

    SciTech Connect (OSTI)

    Jeet, Kiran; Jindal, V. K.; Dharamvir, Keya; Bharadwaj, L. M.

    2011-12-12

    Thin film samples of carbon nanotubes were irradiated with ion beam of carbon, nickel and gold. The irradiation results were characterized using Raman Spectroscopy. Modifications of the disorder mode (D mode) and the tangential mode (G mode) under different irradiation fluences were studied in detail. Raman results of carbon ion beam indicate the interesting phenomenon of ordering of the system under irradiation. Under the effect of nickel and gold ion irradiation, the structural evolution of CNTs occurs in three different stages. At lower fluences the process of healing occurs; at intermediate fluences damages on the surface of CNTs occurs and finally at very high fluences of the order of 1x10{sup 14} ions/cm{sup 2} the system gets amorphised.

  18. In situ observation of defect annihilation in Kr ion-irradiated bulk Fe/amorphous-Fe 2 Zr nanocomposite alloy

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yu, K. Y.; Fan, Z.; Chen, Y.; Song, M.; Liu, Y.; Wang, H.; Kirk, M. A.; Li, M.; Zhang, X.

    2014-08-26

    Enhanced irradiation tolerance in crystalline multilayers has received significant attention lately. However, little is known on the irradiation response of crystal/amorphous nanolayers. We report on in situ Kr ion irradiation studies of a bulk Fe96Zr4 nanocomposite alloy. Irradiation resulted in amorphization of Fe2Zr and formed crystal/amorphous nanolayers. α-Fe layers exhibited drastically lower defect density and size than those in large α-Fe grains. In situ video revealed that mobile dislocation loops in α-Fe layers were confined by the crystal/amorphous interfaces and kept migrating to annihilate other defects. This study provides new insights on the design of irradiation-tolerant crystal/amorphous nanocomposites.

  19. Degradation of Nylon 6,6 Fire-Suppression Casing from Plutonium Glove Boxes Under Alpha and Neutron Irradiation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Millsap, Donald W.; Cournoyer, Michael E.; Landsberger, Sheldon; Tesmer, Joseph R.; Wang, Matthew Y.

    2015-04-23

    Nylon 6,6 tensile specimens, conforming to the casing for self-contained fire extinguisher systems, have been irradiated using both an accelerator He++ ion beam and a 5-Ci PuBe neutron source to model the radiation damage these systems would likely incur over a lifetime of operation within glove boxes. Following irradiation, these samples were mechanically tested using standard practices as described in ASTM D638. The results of the He++ study indicate that the tensile strength of the nylon specimens undergoes some slight (<10%) degradation while other properties of the samples, such as elongation and tangent modulus, appear to fluctuate with increasing dosemore » levels. The He++-irradiated specimens also have a noticeable level of discoloration corresponding to increasing levels of dose. The neutron-irradiated samples show a higher degree of mechanical degradation than the He++-irradiated samples.« less

  20. Effects of Irradiation on the Microstructure of U-7Mo Dispersion Fuel with Al-2Si Matrix

    SciTech Connect (OSTI)

    Dennis D. Keiser, Jr.; Jan-Fong Jue; Adam B. Robinson; Pavel Medvedev; Jian Gan; Brandon D. Miller; Daniel M. Wachs; Glenn A. Moore; Curtis R. Clark; Mitchell K. Meyer; M. Ross Finlay

    2012-06-01

    The Reduced Enrichment for Research and Test Reactor program is developing low-enriched uranium U-Mo dispersion fuels for application in research and test reactors around the world. As part of this development, fuel plates have been irradiated in the Advanced Test Reactor and then characterized using optical metallography (OM) and scanning electron microscopy (SEM) to determine the as-irradiated microstructure. To demonstrate the irradiation performance of U-7Mo dispersion fuel plates with 2 wt% Si added to the matrix, fuel plates were tested to medium burnups at intermediate fission rates as part of the RERTR-6 experiment. Further testing was performed to higher fission rates as part of the RERTR-7A experiment, and very aggressive testing (high temperature, high fission density, high fission rate) was performed in the RERTR-9A, RERTR-9B and AFIP-1 experiments. As-irradiated microstructures were compared to those observed after fabrication to determine the effects of irradiation on the microstructure. Based on comparison of the microstructural characterization results for each irradiated sample, some general conclusions can be drawn about how the microstructure evolves during irradiation: there is growth of the fuel/matrix interaction layer (FMI), which was present in the samples to some degree after fabrication, during irradiation; Si diffuses from the FMI layer to deeper depths in the U-7Mo particles as the irradiation conditions are made more aggressive; lowering of the Si content in the FMI layer results in an increase in the size of the fission gas bubbles; as the FMI layer grows during irradiation more Si diffuses from the matrix to the FMI layer/matrix interface, and interlinking of fission gas bubbles in the fuel plate microstructure that may indicate breakaway swelling is not observed.

  1. The Early Characterization of Irradiation Effects in Stainless Steels at the Experimental Breeder Reactor-II

    SciTech Connect (OSTI)

    D. L. Porter

    2008-01-01

    The new Global Nuclear Energy Partnership (GNEP) program is revitalizing interest in materials development for fast spectrum reactors. With this comes the need for new, high-performance materials that are resistant to property changes caused by radiation damage. In the 1970s there was an effort to monitor the irradiation effects on stainless steels used in fast reactor cores, largely because there were a number of surprises where materials subjected to a high flux of fast neutrons incurred dimensional and property changes that had not been expected. In the U.S., this applied to the Experimental Breeder Reactor-II. Void swelling and irradiation-induced creep caused dimensional changes in the reactor components that shortened their useful lifetime and impacted reactor operations by creating fuel handling difficulties and reactivity anomalies. The surveillance programs and early experiments studied the simplest of austenitic stainless steels, such as Types 304 and 304L stainless steel, and led to some basic understanding of the links between these irradiation effects and microchemical changes within the steel caused by operational variables such as temperature, neutron flux and neutron fluence. Some of the observations helped to define later alloy development programs designed to produce alloys that were much more resistant to the effects of neutron irradiation.

  2. Damage accumulation in ion-irradiated Ni-based concentrated solid-solution alloys

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ullah, Mohammad W.; Aidhy, Dilpuneet S.; Zhang, Yanwen; Weber, William J.

    2016-01-01

    We investigate Irradiation-induced damage accumulation in Ni0.8Fe0.2 and Ni0.8Cr0.2 alloys by using molecular dynamics simulations to assess possible enhanced radiation-resistance in these face-centered cubic (fcc), single-phase, concentrated solid-solution alloys, as compared with pure fcc Ni.

  3. High post-irradiation ductility thermomechanical treatment for precipitation strengthened austenitic alloys

    DOE Patents [OSTI]

    Laidler, James J. (Richland, WA); Borisch, Ronald R. (Kennewick, WA); Korenko, Michael K. (Rockville, MD)

    1982-01-01

    A method for improving the post-irradiation ductility is described which prises a solution heat treatment following which the materials are cold worked. They are included to demonstrate the beneficial effect of this treatment on the swelling resistance and the ductility of these austenitic precipitation hardenable alloys.

  4. Spatial disaggregation of satellite-derived irradiance using a high-resolution digital elevation model

    SciTech Connect (OSTI)

    Ruiz-Arias, Jose A.; Tovar-Pescador, Joaquin; Cebecauer, Tomas; Suri, Marcel

    2010-09-15

    Downscaling of the Meteosat-derived solar radiation ({proportional_to}5 km grid resolution) is based on decomposing the global irradiance and correcting the systematic bias of its components using the elevation and horizon shadowing that are derived from the SRTM-3 digital elevation model (3 arc sec resolution). The procedure first applies the elevation correction based on the difference between coarse and high spatial resolution. Global irradiance is split into direct, diffuse circumsolar and diffuse isotropic components using statistical models, and then corrections due to terrain shading and sky-view fraction are applied. The effect of reflected irradiance is analysed only in the theoretical section. The method was applied in the eastern Andalusia, Spain, and the validation was carried out for 22 days on April, July and December 2006 comparing 15-min estimates of the satellite-derived solar irradiance and observations from nine ground stations. Overall, the corrections of the satellite estimates in the studied region strongly reduced the mean bias of the estimates for clear and cloudy days from roughly 2.3% to 0.4%. (author)

  5. Measurements and modeling of total solar irradiance in X-class solar flares

    SciTech Connect (OSTI)

    Moore, Christopher Samuel; Chamberlin, Phillip Clyde; Hock, Rachel

    2014-05-20

    The Total Irradiance Monitor (TIM) from NASA's SOlar Radiation and Climate Experiment can detect changes in the total solar irradiance (TSI) to a precision of 2 ppm, allowing observations of variations due to the largest X-class solar flares for the first time. Presented here is a robust algorithm for determining the radiative output in the TIM TSI measurements, in both the impulsive and gradual phases, for the four solar flares presented in Woods et al., as well as an additional flare measured on 2006 December 6. The radiative outputs for both phases of these five flares are then compared to the vacuum ultraviolet (VUV) irradiance output from the Flare Irradiance Spectral Model (FISM) in order to derive an empirical relationship between the FISM VUV model and the TIM TSI data output to estimate the TSI radiative output for eight other X-class flares. This model provides the basis for the bolometric energy estimates for the solar flares analyzed in the Emslie et al. study.

  6. Spectral irradiance model for tungsten halogen lamps in 340-850 nm wavelength range

    SciTech Connect (OSTI)

    Ojanen, Maija; Kaerhae, Petri; Ikonen, Erkki

    2010-02-10

    We have developed a physical model for the spectral irradiance of 1 kW tungsten halogen incandescent lamps for the wavelength range 340-850 nm. The model consists of the Planck's radiation law, published values for the emissivity of tungsten, and a residual spectral correction function taking into account unknown factors of the lamp. The correction function was determined by measuring the spectra of a 1000 W, quartz-halogen, tungsten coiled filament (FEL) lamp at different temperatures. The new model was tested with lamps of types FEL and 1000 W, 120 V quartz halogen (DXW). Comparisons with measurements of two national standards laboratories indicate that the model can account for the spectral irradiance values of lamps with an agreement better than 1% throughout the spectral region studied. We further demonstrate that the spectral irradiance of a lamp can be predicted with an expanded uncertainty of 2.6% if the color temperature and illuminance values for the lamp are known with expanded uncertainties of 20 K and 2%, respectively. In addition, it is suggested that the spectral irradiance may be derived from resistance measurements of the filament with lamp on and off.

  7. High Specific Activity Sn-117m by Post Irradiation Isotope Separation

    SciTech Connect (OSTI)

    DAuria, John

    2015-04-16

    ElectroMagnetic Isotope Separation (EMIS) is used in the production of enriched stable isotopes. We demonstrated the feasibility of using EMIS to produce medium Specific Activity 117mSm using high purity 116Sn target material irradiated in a high flux reactor.

  8. Fuel Accident Condition Simulator (FACS) Furnace for Post-Irradiation Heating Tests of VHTR Fuel Compacts

    SciTech Connect (OSTI)

    Paul A Demkowicz; Paul Demkowicz; David V Laug

    2010-10-01

    Abstract Fuel irradiation testing and post-irradiation examination are currently in progress as part of the Next Generation Nuclear Plant Fuels Development and Qualification Program. The PIE campaign will include extensive accident testing of irradiated very high temperature reactor fuel compacts to verify fission product retention characteristics at high temperatures. This work will be carried out at both the Idaho National Laboratory (INL) and the Oak Ridge National Laboratory, beginning with accident tests on irradiated fuel from the AGR-1 experiment in 2010. A new furnace system has been designed, built, and tested at INL to perform high temperature accident tests. The Fuel Accident Condition Simulator furnace system is designed to heat fuel specimens at temperatures up to 2000C in helium while monitoring the release of volatile fission metals (e.g. Cs, Ag, Sr, Eu, and I) and fission gases (Kr, Xe). Fission gases released from the fuel to the sweep gas are monitored in real time using dual cryogenic traps fitted with high purity germanium detectors. Condensable fission products are collected on a plate attached to a water-cooled cold finger that can be exchanged periodically without interrupting the test. Analysis of fission products on the condensation plates involves dry gamma counting followed by chemical analysis of selected isotopes. This paper will describe design and operational details of the Fuel Accident Condition Simulator (FACS) furnace system, as well as preliminary system calibration results.

  9. Summary report on the fuel performance modeling of the AFC-2A, 2B irradiation experiments

    SciTech Connect (OSTI)

    Pavel G. Medvedev

    2013-09-01

    The primary objective of this work at the Idaho National Laboratory (INL) is to determine the fuel and cladding temperature history during irradiation of the AFC-2A, 2B transmutation metallic fuel alloy irradiation experiments containing transuranic and rare earth elements. Addition of the rare earth elements intends to simulate potential fission product carry-over from pyro-metallurgical reprocessing. Post irradiation examination of the AFC-2A, 2B rodlets revealed breaches in the rodlets and fuel melting which was attributed to the release of the fission gas into the helium gap between the rodlet cladding and the capsule which houses six individually encapsulated rodlets. This release is not anticipated during nominal operation of the AFC irradiation vehicle that features a double encapsulated design in which sodium bonded metallic fuel is separated from the ATR coolant by the cladding and the capsule walls. The modeling effort is focused on assessing effects of this unanticipated event on the fuel and cladding temperature with an objective to compare calculated results with the temperature limits of the fuel and the cladding.

  10. Void Swelling and Microstructure of Austenitic Stainless Steels Irradiated in the BOR - 60 Reactor

    SciTech Connect (OSTI)

    Chen, Y.; Yang, Yong; Huang, Yina; Allen, T.; Alexandreanu, B.; Natesan, K.

    2012-11-01

    As nuclear power plants age and neutron fluence increases, detrimental effects resulting from radiation damage have become an increasingly important issue for the operational safety and structural integrity of core internal components. In this study, irradiated specimens of reactor core internal components were characterized by transmission electron microscopy. The specimens had been irradiated to 5.5-45 dpa in the BOR-60 reactor at a dose rate close to 10-6 dpa/s and temperature of about 320C. No voids were observed in the austenitic stainless steels and nickel alloys at all doses. Despite the possibility that fine voids below the TEM resolution limit may be present, it was clear that void swelling was insignificant in all examined alloys up to 45 dpa. Irradiated microstructures of the studied alloys were dominated by a high density of Frank loops. The mean size and density of the Frank loops varied from one material to another, but saturated with increasing dose above ~10 dpa. While no irradiation-induced precipitations were present below 24.5 dpa, fine precipitates were evident in several alloys at 45 dpa.

  11. Comprehensive study of the effect of the irradiation temperature on the behavior of cubic zirconia

    SciTech Connect (OSTI)

    Debelle, A. Thom, L.; Dcamps, B.; Moll, S.; Garrido, F.; Behar, M.; Jagielski, J.

    2014-05-14

    Cubic zirconia single-crystals (yttria-stabilized zirconia (YSZ)) have been irradiated with 4?MeV Au{sup 2+} ions in a broad fluence range (namely from 5??10{sup 12} to 2??10{sup 16}?cm{sup ?2}) and at five temperatures: 80, 300, 573, 773, and 1073?K. Irradiated samples have been characterized by Rutherford backscattering spectroscopy in channeling mode, X-ray diffraction and transmission electron microscopy techniques in order to determine the disordering kinetics. All experimental results show that, whatever is the irradiation temperature, the damage build-up follows a multi-step process. In addition, the disorder level at high fluence is very similar for all temperatures. Thus, no enhanced dynamic annealing process is observed. On the other hand, transitions in the damage accumulation process occur earlier in fluence with increasing temperature. It is shown that temperature as low as 573?K is sufficient to accelerate the disordering process in ion-irradiated YSZ.

  12. Ablation and cone formation mechanism on CR-39 by ArF laser irradiation

    SciTech Connect (OSTI)

    Shakeri Jooybari, B. E-mail: hafarideh@aut.ac.ir; Afarideh, H. E-mail: hafarideh@aut.ac.ir; Lamehi-Rachti, M.; Ghergherehchi, M.

    2015-03-07

    In this work, chemical properties, surface modification, and micro structures formation on ablated polyallyl di-glycol carbonate (CR-39) polymer by ArF laser irradiation (??=?193?nm) at various fluences and pulse number were investigated. CR-39 samples have been irradiated with an ArF laser (193?nm) at a repetition rate of 1?Hz. Threshold fluence of ablation and effective absorption coefficient of CR-39 were determined. Conical microstructures (Taylor cone) formed on laser-ablated CR-39 exhibit: smooth, Taylor cone shape walls and sharp tips together with interference and well defined fringe-structure with a period of 230?nm, around cone base. Mechanism of cone formation and cone evolution of CR-39 ablated surface were investigated by change of fluences (at a given pulse number) and pulse number (at a given fluence). Cone height, cone base, and region of interface were increased in micrometer steps by increasing the total fluence. Depression on the base of the cone and the circular fringe were simulated. FTIR spectra were measured and energy dispersive x-ray analysis of irradiated and un-irradiated samples was performed.

  13. In-situ Study of Nanostructure and Electrical Resistance of Nanocluster Films Irradiated with Ion Beams

    SciTech Connect (OSTI)

    Jiang, Weilin; Sundararajan, Jennifer A.; Varga, Tamas; Bowden, Mark E.; Qiang, You; McCloy, John S.; Henager, Charles H.; Montgomery, Robert O.

    2014-08-11

    An in-situ study is reported on the structural evolution in nanocluster films under He+ ion irradiation using an advanced helium ion microscope. The films consist of loosely interconnected nanoclusters of magnetite or iron-magnetite (Fe-Fe3O4) core-shells. The nanostructure is observed to undergo dramatic changes under ion-beam irradiation, featuring grain growth, phase transition, particle aggregation, and formation of nanowire-like network and nano-pores. Studies based on ion irradiation, thermal annealing and election irradiation have indicated that the major structural evolution is activated by elastic nuclear collisions, while both electronic and thermal processes can play a significant role once the evolution starts. The electrical resistance of the Fe-Fe3O4 films measured in situ exhibits a super-exponential decay with dose. The behavior suggests that the nanocluster films possess an intrinsic merit for development of an advanced online monitor for neutron radiation with both high detection sensitivity and long-term applicability, which can enhance safety measures in many nuclear operations.

  14. Structural investigation of self-irradiation damaged AmO{sub 2}

    SciTech Connect (OSTI)

    Prieur, Damien; Vigier, Jean-Franois; Wiss, Thierry; Janssen, Arne; Rothe, Jrg; Cambriani, Andrea; Somers, Joseph

    2014-04-01

    Studying self-irradiated materials is an ideal means to investigate the effect of the damage on material structure and to better understand the behavior of irradiated nuclear fuels. In this context, X-ray diffraction, X-ray absorption spectroscopy and transmission electron microscopy have been used to investigate self-irradiation damaged AmO{sub 2}. Combining these techniques allows studying the microstructure and the variation of the fluorite structure at both short-range and long-range order. Thus, the increase of both interatomic distances and lattice parameter was shown, as well as the presence of nanometer sized He bubbles and dislocation loops. As confirmed by the observed high-level of crystallinity, the fluorite structure exhibits a high radiation tolerance, which is confirmed by the low increase of the lattice parameter. This could be explained by a self-annealing mechanism of the created defects at room temperature. - Graphical abstract: The structure of damaged AmO2 (36 dpa) has been studied by XRD, XAS and TEM. Thus, the effects of the self-irradiation on the oxidation state, the lattice distances, the structural disorder, the radiation stability and the microstructure have been discussed. - Highlights: The structure of highly self-irradiated AmO{sub 2} (36 dpa) was studied by XAS and TEM. XRD, EXAFS and TEM confirm the high stability of the fluorite structure. XRD and EXAFS show an increase of 0.3% of the structural distances. XANES shows that Am is tetravalent as well as the Np recoil nucleus. The presence of He bubbles was evidenced by TEM.

  15. Analyzing the Contribution of Aerosols to an Observed Increase in Direct Normal Irradiance in Oregon

    SciTech Connect (OSTI)

    Riihimaki, Laura D.; Vignola, F.; Long, Charles N.

    2009-01-22

    Annual average total irradiance increases by 1-2% per decade at three mon- itoring stations in Oregon over the period from 1980 to 2007. Direct normal irradiance measurements increase by 5% per decade over the same time pe- riod. The measurements show no sign of a dimming before 1990. The impact of high concentrations of stratospheric aerosols following the volcanic erup- tions of El Chichon and Mt. Pinatubo are clearly seen in the measurements. Removing these years from the annual average all-sky time series reduces the trends in both total and direct normal irradiance. Clear-sky periods from this long direct normal time series are used in conjunction with radiative trans- fer calculations to test whether part of the increase could be caused by an- thropogenic aerosols. All three sites show relatively low clear-sky measure- ments before the eruption of El Chichon in 1982, suggesting higher aerosol loads during this period. After removing the periods most strongly impacted by volcanic eruptions, two of the sites show statistically signicant increases in clear-sky direct normal irradiance from 1987 to 2007. Radiative transfer calculations of the impact of volcanic aerosols and tropospheric water vapor indicate that only about 20% of that clear-sky increase between background aerosol periods before and after the eruption of Mt. Pinatubo can be explained by these two factors. Thus, a statistically signicant clear-sky trend remains between 1987 and 2007 that is consistent with the hypothesis that at least some of the increase in surface irradiance could be caused by a reduction of anthropogenic aerosols. D

  16. Nano-Scale Fission Product Phases in an Irradiated U-7Mo Alloy Nuclear Fuel

    SciTech Connect (OSTI)

    Dennis Keiser, Jr.; Brandon Miller; James Madden; Jan-Fong Jue; Jian Gan

    2014-09-01

    Irradiated nuclear fuel is a very difficult material to characterize. Due to the large radiation fields associated with these materials, they are hard to handle and typically have to be contained in large hot cells. Even the equipment used for performing characterization is housed in hot cells or shielded glove boxes. The result is not only a limitation in the techniques that can be employed for characterization, but also a limitation in the size of features that can be resolved The most standard characterization techniques include light optical metallography (WM), scanning electron microscopy (SEM), and electron probe microanalysis (EPMA). These techniques are applied to samples that are typically prepared using grinding and polishing approaches that will always generate some mechanical damage on the sample surface. As a result, when performing SEM analysis, for example, the analysis is limited by the quality of the sample surface that can be prepared. However, a new approach for characterizing irradiated nuclear fuel has recently been developed at the Idaho National Laboratory (INL) in Idaho Falls, Idaho. It allows for a dramatic improvement in the quality of characterization that can be performed when using an instrument like an SEM. This new approach uses a dual-beam scanning microscope, where one of the beams isa focused ion beam (FIB), which can be used to generate specimens of irradiated fuel (-10m x 10m) for microstructural characterization, and the other beam is the electron beam of an SEM. One significant benefit of this approach is that the specimen surface being characterized has received much less damage (and smearing) than is caused by the more traditional approaches, which enables the imaging of nanometer sized microstructural features in the SEM. The process details are for an irradiated low-enriched uranium (LEU) U-Mo alloy fuel Another type of irradiated fuel that has been characterized using this technique is a mixed oxide fuel.

  17. Effects of Irradiation on Brain Vasculature Using an In Situ Tumor Model

    SciTech Connect (OSTI)

    Zawaski, Janice A.; Gaber, M. Waleed; Sabek, Omaima M.; Wilson, Christy M.; Duntsch, Christopher D.; Merchant, Thomas E.

    2012-03-01

    Purpose: Damage to normal tissue is a limiting factor in clinical radiotherapy (RT). We tested the hypothesis that the presence of tumor alters the response of normal tissues to irradiation using a rat in situ brain tumor model. Methods and Materials: Intravital microscopy was used with a rat cranial window to assess the in situ effect of rat C6 glioma on peritumoral tissue with and without RT. The RT regimen included 40 Gy at 8 Gy/day starting Day 5 after tumor implant. Endpoints included blood-brain barrier permeability, clearance index, leukocyte-endothelial interactions and staining for vascular endothelial growth factor (VEGF) glial fibrillary acidic protein, and apoptosis. To characterize the system response to RT, animal survival and tumor surface area and volume were measured. Sham experiments were performed on similar animals implanted with basement membrane matrix absent of tumor cells. Results: The presence of tumor alone increases permeability but has little effect on leukocyte-endothelial interactions and astrogliosis. Radiation alone increases tissue permeability, leukocyte-endothelial interactions, and astrogliosis. The highest levels of permeability and cell adhesion were seen in the model that combined tumor and irradiation; however, the presence of tumor appeared to reduce the volume of rolling leukocytes. Unirradiated tumor and peritumoral tissue had poor clearance. Irradiated tumor and peritumoral tissue had a similar clearance index to irradiated and unirradiated sham-implanted animals. Radiation reduces the presence of VEGF in peritumoral normal tissues but did not affect the amount of apoptosis in the normal tissue. Apoptosis was identified in the tumor tissue with and without radiation. Conclusions: We developed a novel approach to demonstrate that the presence of the tumor in a rat intracranial model alters the response of normal tissues to irradiation.

  18. Weapons-Grade MOX Fuel Burnup Characteristics in Advanced Test Reactor Irradiation

    SciTech Connect (OSTI)

    G. S. Chang

    2006-07-01

    Mixed oxide (MOX) test capsules prepared with weapons-derived plutonium have been irradiated to a burnup of 50 GWd/t. The MOX fuel was fabricated at Los Alamos National Laboratory (LANL) by a master-mix process and has been irradiated in the Advanced Test Reactor (ATR) at the Idaho National Laboratory (INL). Previous withdrawals of the same fuel have occurred at 9, 21, 30, 40, and 50 GWd/t. Oak Ridge National Laboratory (ORNL) manages this test series for the Department of Energys Fissile Materials Disposition Program (FMDP). A UNIX BASH (Bourne Again SHell) script CMO has been written and validated at the Idaho National Laboratory (INL) to couple the Monte Carlo transport code MCNP with the depletion and buildup code ORIGEN-2 (CMO). The new Monte Carlo burnup analysis methodology in this paper consists of MCNP coupling through CMO with ORIGEN-2(MCWO). MCWO is a fully automated tool that links the Monte Carlo transport code MCNP with the radioactive decay and burnup code ORIGEN-2. The fuel burnup analyses presented in this study were performed using MCWO. MCWO analysis yields time-dependent and neutron-spectrum-dependent minor actinide and Pu concentrations for the ATR small I-irradiation test position. The purpose of this report is to validate both the Weapons-Grade Mixed Oxide (WG-MOX) test assembly model and the new fuel burnup analysis methodology by comparing the computed results against the neutron monitor measurements and the irradiated WG-MOX post irradiation examination (PIE) data.

  19. Surface composition, microstructure and corrosion resistance of AZ31 magnesium alloy irradiated by high-intensity pulsed ion beam

    SciTech Connect (OSTI)

    Li, P., E-mail: pli@sqnc.edu.cn [Department of Physics and Information Engineering, Shangqiu Normal University, Shangqiu 476000 (China); Surface Engineering Laboratory, School of Materials Science and Engineering, Dalian University of Technology, Dalian 116024 (China); Lei, M.K., E-mail: surfeng@dlut.edu.cn [Surface Engineering Laboratory, School of Materials Science and Engineering, Dalian University of Technology, Dalian 116024 (China); Zhu, X.P. [Surface Engineering Laboratory, School of Materials Science and Engineering, Dalian University of Technology, Dalian 116024 (China)

    2011-06-15

    High-intensity pulsed ion beam (HIPIB) irradiation of AZ31 magnesium alloy is performed and electrochemical corrosion experiment of irradiated samples is carried out by using potentiodynamic polarization technology in order to explore the effect of HIPIB irradiation on corrosion resistance of magnesium alloy. The surface composition, cross-sectional morphology and microstructure are characterized by using electron probe microanalyzer, optical microscope and transmission electron microscope, respectively. The results indicated that HIPIB irradiation leads to a significant improvement in corrosion resistance of magnesium alloy, in terms of the considerable increase in both corrosion potential and pitting breakdown potential. The microstructural refinement and surface purification induced by HIPIB irradiation are responsible for the improved corrosion resistance. - Research Highlights: {yields} A modified layer about 30 {mu}m thick is obtained by HIPIB irradiation. {yields} Selective ablation of element/impurity phase having lower melting point is observed. {yields} More importantly, microstructural refinement occurred on the irradiated surface. {yields} The modified layer exhibited a significantly improved corrosion resistance. {yields} Improved corrosion resistance is ascribed to the combined effect induced by HIPIB.

  20. SU-E-T-457: Design and Characterization of An Economical 192Ir Hemi-Brain Small Animal Irradiator

    SciTech Connect (OSTI)

    Grams, M; Wilson, Z; Sio, T; Beltran, C; Tryggestad, E; Gupta, S; Blackwell, C; McCollough, K; Sarkaria, J; Furutani, K

    2014-06-01

    Purpose: To describe the design and dosimetric characterization of a simple and economical small animal irradiator. Methods: A high dose rate 192Ir brachytherapy source from a commercially available afterloader was used with a 1.3 centimeter thick tungsten collimator to provide sharp beam penumbra suitable for hemi-brain irradiation of mice. The unit is equipped with continuous gas anesthesia to allow robust animal immobilization. Dosimetric characterization of the device was performed with Gafchromic film. The penumbra from the small animal irradiator was compared under similar collimating conditions to the penumbra from 6 MV photons, 6 MeV electrons, and 20 MeV electrons from a linear accelerator as well as 300 kVp photons from an orthovoltage unit and Monte Carlo simulated 90 MeV protons. Results: The tungsten collimator provides a sharp penumbra suitable for hemi-brain irradiation, and dose rates on the order of 200 cGy/minute were achieved. The sharpness of the penumbra attainable with this device compares favorably to those measured experimentally for 6 MV photons, and 6 and 20 MeV electron beams from a linear accelerator. Additionally, the penumbra was comparable to those measured for a 300 kVp orthovoltage beam and a Monte Carlo simulated 90 MeV proton beam. Conclusions: The small animal irradiator described here can be built for under $1,000 and used in conjunction with any commercial brachytherapy afterloader to provide a convenient and cost-effective option for small animal irradiation experiments. The unit offers high dose rate delivery and sharp penumbra, which is ideal for hemi-brain irradiation of mice. With slight modifications to the design, irradiation of sites other than the brain could be accomplished easily. Due to its simplicity and low cost, the apparatus described is an attractive alternative for small animal irradiation experiments requiring a sharp penumbra.

  1. Lung autophagic response following exposure of mice to whole body irradiation, with and without amifostine

    SciTech Connect (OSTI)

    Zois, Christos E.; Giatromanolaki, Alexandra; Kainulainen, Heikki; Botaitis, Sotirios; Torvinen, Sira; Simopoulos, Constantinos; Kortsaris, Alexandros; Sivridis, Efthimios; Koukourakis, Michael I.

    2011-01-07

    Research highlights: {yields} We investigated the effect 6 Gy of WBI on the autophagic machinery of normal mouse lung. {yields} Irradiation induces dysfunction of the autophagic machinery in normal lung, characterized by decreased transcription of the LC3A/Beclin-1 mRNA and accumulation of the LC3A, and p62 proteins. {yields} The membrane bound LC3A-II protein levels increased in the cytosolic fraction (not in the pellet), contrasting the patterns noted after starvation-induced autophagy. {yields} Administration of amifostine, reversed all the LC3A and p62 findings, suggesting protection of the normal autophagic function. -- Abstract: Purpose: The effect of ionizing irradiation on the autophagic response of normal tissues is largely unexplored. Abnormal autophagic function may interfere the protein quality control leading to cell degeneration and dysfunction. This study investigates its effect on the autophagic machinery of normal mouse lung. Methods and materials: Mice were exposed to 6 Gy of whole body {gamma}-radiation and sacrificed at various time points. The expression of MAP1LC3A/LC3A/Atg8, beclin-1, p62/sequestosome-1 and of the Bnip3 proteins was analyzed. Results: Following irradiation, the LC3A-I and LC3A-II protein levels increased significantly at 72 h and 7 days. Strikingly, LC3A-II protein was increased (5.6-fold at 7 days; p < 0.001) only in the cytosolic fraction, but remained unchanged in the membrane fraction. The p62 protein, was significantly increased in both supernatant and pellet fraction (p < 0.001), suggesting an autophagosome turnover deregulation. These findings contrast the patterns of starvation-induced autophagy up-regulation. Beclin-1 levels remained unchanged. The Bnip3 protein was significantly increased at 8 h, but it sharply decreased at 72 h (p < 0.05). Administration of amifostine (200 mg/kg), 30 min before irradiation, reversed all the LC3A and p62 findings on blots, suggesting restoration of the normal autophagic function. The LC3A and Beclin1 mRNA levels significantly declined following irradiation (p < 0.01), whereas Bnip3 levels increased. Conclusions: It is suggested that irradiation induces dysfunction of the autophagic machinery in normal lung, characterized by decreased transcription of the LC3A/Beclin-1 mRNA and accumulation of the LC3A, and p62 proteins. Whether this is due to defective maturation or to aberrant degradation of the autophagosomes requires further investigation.

  2. Mechanical behavior of AISI 304SS determined by miniature test methods after neutron irradiation to 28 dpa

    SciTech Connect (OSTI)

    Ellen M. Rabenberg; Brian J. Jaques; Bulent H. Sencer; Frank A. Garner; Paula D. Freyer; Taira Okita; Darryl P. Butt

    2014-05-01

    The mechanical properties of AISI 304 stainless steel irradiated for over a decade in the Experimental Breeder Reactor (EBR-II) were measured using miniature mechanical testing methods. The shear punch method was used to evaluate the shear strengths of the neutron-irradiated steel and a correlation factor was empirically determined to predict its tensile strength. The strength of the stainless steel slightly decreased with increasing irradiation temperature, and significantly increased with increasing dose until it saturated above approximately 5 dpa. Ferromagnetic measurements were used to observe and deduce the effects of the stress-induced austenite to martensite transformation as a result of shear punch testing.

  3. Design and Status of the NGNP Fuel Experiment AGR-3/4 Irradiated in the Advanced Test Reactor

    SciTech Connect (OSTI)

    Blaine Grover

    2012-10-01

    The United States Department of Energys Next Generation Nuclear Plant (NGNP) Advanced Gas Reactor (AGR) Fuel Development and Qualification Program will be irradiating up to seven separate low enriched uranium (LEU) tri-isotopic (TRISO) particle fuel (in compact form) experiments in the Advanced Test Reactor (ATR) located at the Idaho National Laboratory (INL). These irradiations and fuel development are being accomplished to support development of the next generation reactors in the United States, and will be irradiated over the next several years to demonstrate and qualify new TRISO coated particle fuel for use in high temperature gas reactors. The goals of the irradiation experiments are to provide irradiation performance data to support fuel process development, to qualify fuel for normal operating conditions, to support development and validation of fuel performance and fission product transport models and codes, and to provide irradiated fuel and materials for post irradiation examination (PIE) and safety testing. The experiments, which will each consist of at least six separate capsules, will be irradiated in an inert sweep gas atmosphere with individual on-line temperature monitoring and control of each capsule. The sweep gas will also have on-line fission product monitoring on its effluent to track performance of the fuel in each individual capsule during irradiation. The first experiment (designated AGR-1) started irradiation in December 2006 and was completed in November 2009. The second experiment (AGR-2) started irradiation in June 2010 and is currently scheduled to be completed in April 2013. The third and fourth experiments have been combined into a single experiment designated AGR-3/4, which started its irradiation in December 2011 and is currently scheduled to be completed in November 2013. Since the purpose of this experiment is to provide data on fission product migration and retention in the NGNP reactor, the design of this experiment is significantly different from the first two experiments, though the control and monitoring systems are very similar. The purpose and design of this experiment will be discussed followed by its progress and status to date.

  4. The change of microstructure and thermal properties in ion irradiated carbon nanotube mats as a function of ion penetration depth

    SciTech Connect (OSTI)

    Aitkaliyeva, A. [Materials Science and Engineering Program, Texas A and M University, College Station, Texas 77843 (United States)] [Materials Science and Engineering Program, Texas A and M University, College Station, Texas 77843 (United States); Shao, L. [Materials Science and Engineering Program, Texas A and M University, College Station, Texas 77843 (United States) [Materials Science and Engineering Program, Texas A and M University, College Station, Texas 77843 (United States); Department of Nuclear Engineering, Texas A and M University, College Station, Texas 77843 (United States)

    2013-02-11

    A stack of three carbon nanotube (CNT) mats was irradiated with 3 MeV He ions. The change in structural and thermal properties of individual mats as a function of ion penetration depth was characterized using electron microscopy and laser flash techniques. Ion irradiation can enhance thermal conductivity of the mats by introducing inter-tube displacements, which improve phonon transport across adjacent nanotubes. The enhancement, however, is reduced at higher damage levels due to the increasing phonon-defect scattering within the tubes. This study demonstrates the feasibility of using ion irradiation to manipulate thermal transport in carbon nanotubes.

  5. THE INFLUENCE OF NEUTRON-IRRADIATION AT LOW TEMPERATURES ON THE DIELECTRIC PARAMETERS OF 3C-SiC

    SciTech Connect (OSTI)

    J.A.A. Engelbrecht; G. Deyzel; E. Minnaar; W.E. Goosen; I. J. van Rooyen

    2014-04-01

    3C-SiC wafers were irradiated with neutrons of various fluences and at low (200 - 400 ?C) irradiation temperatures. Fourier Transform infrared (FTIR) reflectance spectra were obtained for the samples, and the spectra used to extract the dielectric parameters for each specimen, using statistical curve-fitting procedures. Analysis of all data revealed trends in reflectance peak heights as well as in the dielectric parameters. The surface roughness of the irradiated samples was measured by atomic force spectroscopy (AFM) and certain trends could be ascribed to surface roughness.

  6. AFCI Fuel Irradiation Test Plan, Test Specimens AFC-1 and AFC-1F

    SciTech Connect (OSTI)

    D. C. Crawford; S. L. Hayes; B. A. Hilton; M. K. Meyer; R. G. Ambrosek; G. S. Chang; D. J. Utterbeck

    2003-11-01

    The U. S. Advanced Fuel Cycle Initiative (AFCI) seeks to develop and demonstrate the technologies needed to transmute the long-lived transuranic actinide isotopes contained in spent nuclear fuel into shorter-lived fission products, thereby dramatically decreasing the volume of material requiring disposition and the long-term radiotoxicity and heat load of high-level waste sent to a geologic repository (DOE, 2003). One important component of the technology development is actinide-bearing transmutation fuel forms containing plutonium, neptunium, americium (and possibly curium) isotopes. There are little irradiation performance data available on non-fertile fuel forms, which would maximize the destruction rate of plutonium, and low-fertile (i.e., uranium-bearing) fuel forms, which would support a sustainable nuclear energy option. Initial scoping level irradiation tests on a variety of candidate fuel forms are needed to establish a transmutation fuel form design and evaluate deployment of transmutation fuels.

  7. Dose rate dependence of the speciation of neptunium in irradiated solutions of nitric acid

    SciTech Connect (OSTI)

    Precek, M.; Paulenova, A.; Mincher, B.J.; Mezyk, S.P.

    2013-07-01

    The effects of radiation on the redox speciation of neptunium are of interest due to their impact on the performance of separation of neptunium from highly radioactive solutions of dissolved used nuclear fuel. In this study, the influence of dose rate change from 0.4 kGy/h to 6 kGy/h was examined during irradiation of solutions of initially hexavalent 2.0-2.5 mM neptunium in nitric acid of two different concentrations (0.5 and 1 M). Results indicate that the immediate radiolytic steady-state concentration of neptunium(V) were depressed and its initial radiolytic yield was up to 2-times lower (in 1 M HNO{sub 3} solutions)during irradiations with the higher dose rate. The finding is explained on the basis of the enhancement of the role of oxidizing radicals during the radiolytic process. (authors)

  8. Swift heavy ion irradiation of Pt nanocrystals: II. Structural changes and H desorption

    SciTech Connect (OSTI)

    Giulian, R.; Araujo, L.L.; Kluth, P.; Sprouster, D.J.; Schnohr, C.S.; Byrne, A.P.; Ridgway, M.C.

    2014-09-24

    The structural properties and H desorption from embedded Pt nanocrystals (NCs) following irradiation with swift heavy ions were investigated as a function of energy and fluence. From x-ray absorption near-edge spectroscopy analysis, Pt-H bonding was identified in NCs annealed in a forming gas (95% N{sub 2} + 5% H{sub 2}) ambient. The H content decreased upon irradiation and the desorption process was NC-size dependent such that larger NCs required a higher fluence to achieve a H-free state. Pt-H bonding and NC dissolution both perturbed the NC structural parameters (coordination number, bond-length and mean-square relative displacement) as determined with extended x-ray absorption fine structure measurements.

  9. Automatic analysis of flow cytometric DNA histograms from irradiated mouse male germ cells

    SciTech Connect (OSTI)

    Lampariello, F.; Mauro, F.; Uccelli, R.; Spano, M.

    1989-01-01

    An automatic procedure for recovering the DNA content distribution of mouse irradiated testis cells from flow cytometric histograms is presented. First, a suitable mathematical model is developed, to represent the pattern of DNA content and fluorescence distribution in the sample. Then a parameter estimation procedure, based on the maximum likelihood approach, is constructed by means of an optimization technique. This procedure has been applied to a set of DNA histograms relative to different doses of 0.4-MeV neutrons and to different time intervals after irradiation. In each case, a good agreement between the measured histograms and the corresponding fits has been obtained. The results indicate that the proposed method for the quantitative analysis of germ cell DNA histograms can be usefully applied to the study of the cytotoxic and mutagenic action of agents of toxicological interest such as ionizing radiations.18 references.

  10. Identification of periods of clear sky irradiance in time series of GHI measurements

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Reno, Matthew J.; Hansen, Clifford W.

    2016-01-18

    In this study, we present a simple algorithm for identifying periods of time with broadband global horizontal irradiance (GHI) similar to that occurring during clear sky conditions from a time series of GHI measurements. Other available methods to identify these periods do so by identifying periods with clear sky conditions using additional measurements, such as direct or diffuse irradiance. Our algorithm compares characteristics of the time series of measured GHI with the output of a clear sky model without requiring additional measurements. We validate our algorithm using data from several locations by comparing our results with those obtained from amore » clear sky detection algorithm, and with satellite and ground-based sky imagery.« less

  11. New metal-organic nanomaterials synthesized by laser irradiation of organic liquids

    SciTech Connect (OSTI)

    Kuzmin, Stanislav L.; Wesolowski, Michal J.; Duley, Walter W.

    2014-03-31

    A new type of metal-organic composition consisting of clusters of nanoparticles has been synthesised by laser irradiation of metallocene/benzene solutions. The metallocene molecules in this reaction become the source of the metal. Exposure to high-energy femtosecond laser pulses dehydrogenate benzene molecules and initiate the high-temperature high-pressure conditions that results in the synthesis of new materials. Irradiation experiments have been carried out on ferrocene/benzene and on other solutions. With ferrocene the synthesis of a new compound has been confirmed by X-ray powder diffraction as the peaks detected do not correspond to any known substance in the Crystallography Open Database. Theoretical simulation of the periodic structure of this new carbide predicts that it has hexagonal symmetry and a unit cell with a = 3.2A and c =2.8A. The exact structure is still uncertain but may be determined from scanning tunneling microscope (STM) studies.

  12. Flexible cadmium telluride thin films grown on electron-beam-irradiated graphene/thin glass substrates

    SciTech Connect (OSTI)

    Seo, Won-Oh; Kim, Jihyun, E-mail: hyunhyun7@korea.ac.kr [Department of Chemical and Biological Engineering, Korea University, Anam-dong, Sungbuk-gu, Seoul 136-713 (Korea, Republic of); Koo, Yong Hwan; Kim, Byungnam; Lee, Byung Cheol [Radiation Integrated System Research Division, Korea Atomic Energy Research Institute (KAERI), Daejeon 305-353 (Korea, Republic of); Kim, Donghwan [Department of Materials Science and Engineering, Korea University, Seoul 136-701 (Korea, Republic of)

    2014-08-25

    We demonstrate the close-spaced sublimation growth of polycrystalline cadmium telluride (CdTe) thin films on a flexible graphene electrode/thin glass substrate structure. Prior to the growth of CdTe films, chemical-vapor-deposited graphene was transferred onto a flexible glass substrate and subjected to electron-beam irradiation at an energy of 0.2?MeV in order to intentionally introduce the defects into it in a controlled manner. Micro-Raman spectroscopy and sheet resistance measurements were employed to monitor the damage and disorder in the electron-beam irradiated graphene layers. The morphology and optical properties of the CdTe thin films deposited on a graphene/flexible glass substrate were systematically characterized. The integration of the defective graphene layers with a flexible glass substrate can be a useful platform to grow various thin-film structures for flexible electronic and optoelectronic devices.

  13. Microstructural evolution of type 304 and 316 stainless steels under neutron irradiation at LWR relevant conditions

    SciTech Connect (OSTI)

    Tan, Lizhen; Stoller, Roger E.; Field, Kevin G.; Yang, Ying; Morgan, Dane; Wirth, Brian D.; Gussev, Maxim N.; Busby, Jeremy T.; Nam, H.

    2015-12-11

    Life extension of light water reactors will expose austenitic internal core components to irradiation damage levels beyond 100 displacements per atom (dpa), leading to profound microstructural evolution and consequent degradation of macroscopic properties. Microstructural evolution, including Frank loops, cavities, precipitates, and segregation at boundaries and the resultant radiation hardening in type 304 and 316 stainless steel (SS) variants were studied in this work via experimental characterization and multiple simulation methods. Experimental data for up to 40 heats of type 304SS and 316SS variants irradiated in different reactors to 0.6120 dpa at 275375C were generated from this work or collected from literature reports. These experimental data were then combined with models of Frank loop and cavity evolution, computational thermodynamics and precipitation, and ab initio and rate theory integrated radiation-induced segregation models to provide insights into microstructural evolution and degradation at higher doses.

  14. Generation kinetics of color centers in irradiated poly(4-methyl-1-pentene)

    SciTech Connect (OSTI)

    Peng, J. S.; Li, C. L.; Lee, Sanboh; Chou, K. F.

    2011-09-15

    The transient absorbance of poly(4-methyl-1-pentene) (PMP) irradiated with gamma rays at elevated temperatures has been investigated. The absorbance in the ultraviolet and visible range increases with gamma ray dose. A bathochromic shift in transmission spectra emerges significantly upon irradiation. A first-order generation model is proposed to analyze the kinetics of color centers during annealing. The activation energy of the color center increases with increasing gamma ray dose. The equilibrium behavior of color centers in PMP is similar to that of vacancies in metals, and the formation energy of color centers in PMP decreases with increasing gamma ray dose. However, annealable color centers are not observed in this study.

  15. Summary of Post Irradiation Examination Results of the AFIP-6 Failure

    SciTech Connect (OSTI)

    Adam Robinson; Daniel M. Wachs; Francine Rice; Danielle Perez

    2011-10-01

    The AFIP-6 test assembly was irradiated for one cycle in the Advanced Test Reactor at Idaho National Laboratory. The experiment was designed to test two monolithic fuel plates at power and burn-ups which bounded the operating conditions of both ATR and HFIR driver fuel. Both plates contain a solid U-Mo fuel foil with a zirconium diffusion barrier between 6061-aluminum cladding plates bonded by hot isostatic pressing. The experiment was designed with an orifice to restrict the coolant flow in order to obtain prototypic coolant temperature conditions. While these coolant temperatures were obtained, flow restriction resulted in low heat transfer coefficients and the failure of the fuel plates. The results from the post irradiation examinations and some observations of the failure mechanisms are outlined herein.

  16. Measurement of free ammonia produced by X irradiation of glycylglycine in aqueous solution

    SciTech Connect (OSTI)

    Yoshida, H.; Bolch, W.E.; Jacobson, K.B.; Turner, J.E. )

    1990-03-01

    This research was initiated to test the validity of predictions based on Monte Carlo calculations of the effect of ionizing radiation on a simple dipeptide. The mechanism for the formation of ammonia, proposed by Garrison, Sokol, and Bennett-Corniea, was reevaluated by measuring the yields under deoxygenated and oxygenated conditions. Although free ammonia was formed under both conditions, the yields were different, depending on the concentrations of solute and molecular oxygen. The reaction probabilities of the specific interactions of free radicals formed in pure water with solute and oxygen are discussed to account for the observed difference. Our results obtained after low-dose-rate X irradiation are compared with those obtained by Garrison et al. after high-dose-rate 60Co gamma irradiation.

  17. The Effect of Eectronic Energy Loss on Irradiation-Induced Grain Growth in Nanocrystalline Oxides

    SciTech Connect (OSTI)

    Zhang, Yanwen; Aidhy, Dilpuneet S.; Varga, Tamas; Moll, Sandra; Edmondson, P. D.; Namavar, Fereydoon; Jin, Ke; Ostrouchov, Christopher N.; Weber, William J.

    2014-01-01

    Grain growth of nanocrystalline materials is generally thermally activated, but can also be driven by irradiation at much lower temperature. In nanocrystalline ceria and zirconia, contributions from both displacement damage and ionization to the grain growth are identified. Our atomistic simulations have revealed fast grain boundary (GB) movements due to the high density of disorder near GBs. Our experimental results have shown that irradiation-induced grain growth is a function of total energy deposited, where the excitation of target electrons and displacement of lattice atoms both contribute to the overall disorder and both play important roles in grain growth. The coupling of energy deposition to the electronic and lattice structures should both be taken into consideration when engineering nanostructural materials.

  18. Irradiation-enhanced ?' precipitation in model FeCrAl alloys

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Edmondson, Philip D.; Briggs, Samuel A.; Yamamoto, Yukinori; Howard, Richard H.; Sridharan, Kumar; Terrani, Kurt A.; Field, Kevin G.

    2016-02-17

    Model FeCrAl alloys with varying compositions (Fe(1018)Cr(106)Al at.%) have been neutron irradiated at ~ 320 to damage levels of ~ 7 displacements per atom (dpa) to investigate the compositional influence on the formation of irradiation-induced Cr-rich ?' precipitates using atom probe tomography. In all alloys, significant number densities of these precipitates were observed. Cluster compositions were investigated and it was found that the average cluster Cr content ranged between 51.1 and 62.5 at.% dependent on initial compositions. This is significantly lower than the Cr-content of ?' in binary FeCr alloys. As a result, significant partitioning of the Al from themore?' precipitates was also observed.less

  19. Electric and magnetic behaviors observed in NiO-based thin films under light-irradiation

    SciTech Connect (OSTI)

    Luo, Yi-Dong; Song, Kenan; Shun, Li; Gao, Junqi; Xu, Ben, E-mail: xuben@mail.tsinghua.edu.cn, E-mail: linyh@mail.tsinghua.edu.cn; Lin, Yuan-Hua, E-mail: xuben@mail.tsinghua.edu.cn, E-mail: linyh@mail.tsinghua.edu.cn; Nan, Ce-Wen; Liu, Wei [State Key Laboratory of New Ceramics and Fine Processing, School of Materials Science and Engineering, Tsinghua University, Beijing 100084 (China)

    2014-09-07

    We report the room-temperature ferromagnetic properties that can be tuned by light irradiation in the Li and Mn co-doped NiO films (LMNO) grown by the spinning coating. The optical tunable magnetic behavior is enhanced by the increase of the Li doping concentration. First-principle calculations reveal that the Li doping plays key roles in the optical tuned magnetic behavior, which brings a 3d-like impurity state to enhance a significant hybridization between the Mn{sup 3+} 3d state and the impurity band, thus strengthening the ferromagnetic coupling effects. Additionally, it can tune the band gap of the LMNO films and produce more holes under the light irradiation, enhancing the optical tuned magnetic behavior.

  20. Design of quantum dot lattices in amorphous matrices by ion beam irradiation

    SciTech Connect (OSTI)

    Buljan, M.; Bogdanovic-Radovic, I.; Karlusic, M.; Desnica, U. V.; Radic, N.; Jaksic, M.; Salamon, K.; Drazic, G.; Bernstorff, S.; Holy, V.

    2011-10-15

    We report on the highly controllable self-assembly of semiconductor quantum dots and metallic nanoparticles in a solid amorphous matrix, induced by ion beam irradiation of an amorphous multilayer. We demonstrate experimentally and theoretically a possibility to tune the basic structural properties of the quantum dots in a wide range. Furthermore, the sizes, distances, and arrangement type of the quantum dots follow simple equations dependent on the irradiation and the multilayer properties. We present a Monte Carlo model for the simulation and prediction of the structural properties of the materials formed by this method. The presented results enable engineering and simple production of functional materials or simple devices interesting for applications in nanotechnology.

  1. Evaluation of FSV-1 cask for the transport of LWR irradiated fuel assemblies

    SciTech Connect (OSTI)

    Not Available

    1980-05-01

    The Model FSV-1 spent fuel shipping cask was designed by General Atomic Company (GA) to service the Fort St. Vrain (FSV) nuclear generating station, a High Temperature Gas Reactor (HTGR) owned and operated by Public Service Company of Colorado (PSC). This report presents an evaluation of the suitability of the FSV-1 cask for the transport of irradiated Light Water Reactor (LWR) fuel assemblies from both Pressurized Water Reactors (PWR) and Boiling Water Reactors (BWR). The FSV-1 cask evaluation parameters covered a wide spectrum of LWR fuel assemblies, based on burnup in Megawatt Days/Metric Ton of Heavy Metal (MWD/MTHM) and years of decay since irradiation. The criteria for suitability included allowable radiation dose rates, cask surface and interior temperatures and the Gross Vehicle Weight (GVW) of the complete shipping system.

  2. The Ontario Hydro dry irradiated fuel storage program and concrete integrated container demonstration

    SciTech Connect (OSTI)

    Armstrong, P.J.; Grande, L. )

    1990-05-01

    The practicality of loading irradiated fuel into a concrete cask underwater in an existing pool facility has been successfully demonstrated. The cask holds about 7.7 metric-tons-uranium. Special design features allow the cask to be used for dry storage, for transportation, and for disposal without re-handling the fuel. The cask, called the concrete integrated container, or CIC, has been developed. This paper describes the loading, monitoring, and IAEA-based transportation certification of testing of the CIC.

  3. Design Studies for a Multiple Application Thermal Reactor for Irradiation Experiments (MATRIX)

    SciTech Connect (OSTI)

    Pope, Michael A.; Gougar, Hans D.; Ryskamp, J. M.

    2015-03-01

    The Advanced Test Reactor (ATR) is a high power density test reactor specializing in fuel and materials irradiation. For more than 45 years, the ATR has provided irradiations of materials and fuels testing along with radioisotope production. Should unforeseen circumstances lead to the decommissioning of ATR, the U.S. Government would be left without a large-scale materials irradiation capability to meet the needs of its nuclear energy and naval reactor missions. In anticipation of this possibility, work was performed under the Laboratory Directed Research and Development (LDRD) program to investigate test reactor concepts that could satisfy the current missions of the ATR along with an expanded set of secondary missions. A survey was conducted in order to catalogue the anticipated needs of potential customers. Then, concepts were evaluated to fill the role for this reactor, dubbed the Multi-Application Thermal Reactor Irradiation eXperiments (MATRIX). The baseline MATRIX design is expected to be capable of longer cycle lengths than ATR given a particular batch scheme. The volume of test space in In-Pile-Tubes (IPTs) is larger in MATRIX than in ATR with comparable magnitude of neutron flux. Furthermore, MATRIX has more locations of greater volume having high fast neutron flux than ATR. From the analyses performed in this work, it appears that the lead MATRIX design can be designed to meet the anticipated needs of the ATR replacement reactor. However, this design is quite immature, and therefore any requirements currently met must be re-evaluated as the design is developed further.

  4. IFMIF - International Fusion Materials Irradiation Facility Conceptual Design Activity/Interim Report

    SciTech Connect (OSTI)

    Rennich, M.J.

    1995-12-01

    Environmental acceptability, safety, and economic viability win ultimately be the keys to the widespread introduction of fusion power. This will entail the development of radiation- resistant and low- activation materials. These low-activation materials must also survive exposure to damage from neutrons having an energy spectrum peaked near 14 MeV with annual radiation doses in the range of 20 displacements per atom (dpa). Testing of candidate materials, therefore, requires a high-flux source of high energy neutrons. The problem is that there is currently no high-flux source of neutrons in the energy range above a few MeV. The goal, is therefore, to provide an irradiation facility for use by fusion material scientists in the search for low-activation and damage-resistant materials. An accellerator-based neutron source has been established through a number of international studies and workshops` as an essential step for materials development and testing. The mission of the International Fusion Materials Irradiation Facility (IFMIF) is to provide an accelerator-based, deuterium-lithium (D-Li) neutron source to produce high energy neutrons at sufficient intensity and irradiation volume to test samples of candidate materials up to about a full lifetime of anticipated use in fusion energy reactors. would also provide calibration and validation of data from fission reactor and other accelerator-based irradiation tests. It would generate material- specific activation and radiological properties data, and support the analysis of materials for use in safety, maintenance, recycling, decommissioning, and waste disposal systems.

  5. Directly-irradiated Two-zone Solar Thermochemical Reactor for H2O/CO2

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Splitting - Energy Innovation Portal Solar Photovoltaic Solar Photovoltaic Hydrogen and Fuel Cell Hydrogen and Fuel Cell Find More Like This Return to Search Directly-irradiated Two-zone Solar Thermochemical Reactor for H2O/CO2 Splitting DOE Grant Recipients University of Minnesota Contact GRANT About This Technology Technology Marketing Summary Solar Thermochemical Reactor Produces Syngas A thermochemical reactor has been developed to produce syngas, a mixture of hydrogen and carbon

  6. Microgamma Scan System for analyzing radial isotopic profiles of irradiated transmutation fuels

    SciTech Connect (OSTI)

    Bruce A. Hilton; Christopher A. McGrath

    2008-05-01

    The U. S. Global Nuclear Energy Partnership / Advanced Fuel Cycle Initiative (GNEP/AFCI) is developing metallic transmutation alloys as a fuel form to transmute the long-lived transuranic actinide isotopes contained in spent nuclear fuel into shorter-lived fission products. The AFCI program has irradiated and examined eleven metallic alloy transmutation fuel specimens to evaluate the feasibility of actinide transmutation in advanced sodium-cooled fast reactors and thermal reactor implementation. Initial results of postirradiation examinations indicated the irradiation performance of the actinide-bearing compositions is similar to uranium-plutonium-zirconium ternary metallic alloy fuels (U-xPu-10Zr). Further studies to characterize radial burnup profile, constituent migration, and fuel cladding chemical interaction (FCCI) are in progress. A microgamma scan system is being developed to analyze the radial distribution of fission products, such as Cs-137, Cs-134, Ru-106, and Zr-95, in irradiated fuel cross-sections. The microgamma scan system consists of a set of indexed sample collimator blocks and a sample holder, which interfaces with the INL Analytical Laboratory Hot Cell (ALHC) Gamma Scan System high purity germanium detector, multichannel analyzer, and removable collimators. The microgamma scan results will be used to evaluate radial burnup profile, cesium migration to the sodium bond and constituent migration within the fuel. These data will further clarify the comparative irradiation performance of actinide-bearing metallic transmutation fuel forms and uranium-plutonium-zirconium alloys. Preliminary measurements of the microgamma scan system will be discussed. A simplified model of the microgamma scan system was developed in MCNP and used to investigate the system performance and to interpret data from the scoping studies. Recommendations for improving the MCGS analyses are discussed.

  7. Center for Materials at Irradiation and Mechanical Extremes: Los Alamos Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Center for Materials at Irradiation and Mechanical Extremes A BES Energy Frontier Research Center Home Teams Partners Others Summer School G. R. Odette Professional Preparation Department of Mechanical Engineering and Department of Materials University of California Santa Barbara, Santa Barbara, CA 93016 odette@engineering.ucsb.edu , 805-893-3525 1965 Rensselaer Polytechnic Institute, Engineering Science, B.S.; 1968 Massachusetts Institute of Technology, Nuclear Engineering, M.S; 1971

  8. MeV Au Ion Irradiation in Silicon and Nanocrystalline Zirconia Film Deposited on Silicon Substrate

    SciTech Connect (OSTI)

    Chang, Yongqin; Zhang, Yanwen; Zhu, Zihua; Edmondson, Philip D.; Weber, William J.

    2012-09-01

    Nanocrystalline zirconia (ZrO2) film with thickness of 305 nm deposited on a silicon substrate was irradiated with 2 MeV Au ions to different fluences at different temperatures. The implanted ion profiles were measured by time-of-flight secondary ion mass spectrometry (ToF-SIMS) and simulated using the stopping and range of ions inmatter (SRIM) code, respectively. The experimental results show that a large fraction of the incident Au ions penetrates through the ZrO2 film and are deposited into the Si substrate. At the interface of ZrO2 and Si, a sudden decrease of Au concentration is observed due to the much larger scattering cross section of Au in ZrO2 than in Si. The depth profile of the Au ions is measured in both the ZrO2 films and the Si substrates, and the results show that the Au distribution profiles do not exhibit a dependence on irradiation temperature. The local Au concentration increases proportionally with the irradiation fluence, suggesting that no thermal or irradiation-induced redistribution of the implanted Au ions. However, the Au concentration in the ZrO2 films, as determined by SIMS, is considerably lower than that predicted by the SRIM results, and the penetration depth from the SIMS measurements is much deeper than that from the SRIM predictions. These observations can be explained by an overestimation of the electronic stopping power, used in the SRIM program, for heavy incident ions in light targets. Over-estimation of the heavy-ion electronic stopping power may lead to errors in local dose calculation and underestimation of the projected range of slow heavy ions in targets that contain light elements. A quick estimate based on a reduced target density may be used to compensate the overestimation of the electronic stopping power in the SRIM program to provide better ion profile prediction.

  9. Lattice distortions and oxygen vacancies produced in Au+ irradiated nano-crystalline cubic zirconia

    SciTech Connect (OSTI)

    Edmondson, Philip D; Weber, William J; Namavar, Fereydoon; Zhang, Yanwen

    2011-01-01

    The structural impact of oxygen vacancies in nanocrystalline cubic zirconia is investigated. A non-equilibrium number of oxygen vacancies in introduced to the lattice by ion irradiation. The lattice is observed to be initially compressed, undergoes a relaxation at 0.7 displacements per atom (dpa), and experiences a contraction before reaching a temperature dependent steady state value at above 7 dpa. The level of lattice distortion is related to the charge state of the accumulating oxygen vacancies.

  10. MeV Au Ion Irradiation in Silicon and Nanocrystalline Zirconia Film Deposited on Silicon Substrate

    SciTech Connect (OSTI)

    Chang, Yongqin; Zhang, Yanwen; Zhu, Zihua; Edmondson, Dr. Philip; Weber, William J

    2012-01-01

    Nanocrystalline zirconia (ZrO2) film with thickness of 305 nm deposited on a silicon substrate was irradiated with 2 MeV Au ions to different fluences at different temperatures. The implanted ion profiles were measured by time-of-flight secondary ion mass spectrometry (ToF-SIMS) and simulated using the stopping and range of ions in matter (SRIM) code, respectively. The experimental results show that a large fraction of the incident Au ions penetrates through the ZrO2 film and are deposited into the Si substrate. At the interface of ZrO2 and Si, a sudden decrease of Au concentration is observed due to the much larger scattering cross section of Au in ZrO2 than in Si. The depth profile of the Au ions is measured in both the ZrO2 films and the Si substrates, and the results show that the Au distribution profiles do not exhibit a dependence on irradiation temperature. The local Au concentration increases proportionally with the irradiation fluence, suggesting that no thermal or irradiation-induced redistribution of the implanted Au ions. However, the Au concentration in the ZrO2 films, as determined by SIMS, is considerably lower than that predicted by the SRIM results, and the penetration depth from the SIMS measurements is much deeper than that from the SRIM predictions. These observations can be explained by an overestimation of the electronic stopping power, used in the SRIM program, for heavy incident ions in light targets. Overestimation of the heavy-ion electronic stopping power may lead to errors in local dose calculation and underestimation of the projected range of slow heavy ions in targets that contain light elements. A quick estimate based on a reduced target density may be used to compensate the overestimation of the electronic stopping power in the SRIM program to provide better ion profile prediction.

  11. Process for metallization of a substrate by irradiative curing of a catalyst applied thereto

    DOE Patents [OSTI]

    Chen, Ken S. (Albuquerque, NM); Morgan, William P. (Albuquerque, NM); Zich, John L. (Albuquerque, NM)

    1999-01-01

    An improved additive process for metallization of substrates is described whereby a catalyst solution is applied to a surface of a substrate. Metallic catalytic clusters can be formed in the catalyst solution on the substrate surface by irradiating the substrate. Electroless plating can then deposit metal onto the portion of the substrate surface having metallic clusters. Additional metallization thickness can be obtained by electrolytically plating the substrate surface after the electroless plating step.

  12. Ultraviolet and electron irradiation of DC-704 siloxane oil in zinc orthotitanate paint

    SciTech Connect (OSTI)

    Mossman, D.L.; Barsh, M.K.; Greenberg, S.A.

    1982-01-01

    Discrepancies exist between accelerated laboratory simulation and geosynchronous orbit flight data for zinc orthotitanate (ZOT) paint degradation. The effects of ultraviolet and electron irradiation on ZOT contaminated with DC-704 silicone oil are reported. In-situ solar absorptance and emittance changes for contaminated and clean specimens are discussed with reference to post-test surface morphology, determined by scanning electron microscope analysis. Features of the contaminated ZOT degradation kinetics correlate with orbital performance.

  13. Ablation experiment and threshold calculation of titanium alloy irradiated by ultra-fast pulse laser

    SciTech Connect (OSTI)

    Zheng, Buxiang; Jiang, Gedong; Wang, Wenjun Wang, Kedian; Mei, Xuesong; State Key Laboratory for Manufacturing Systems Engineering, Xi'an Jiaotong University, Xi'an 710054

    2014-03-15

    The interaction between an ultra-fast pulse laser and a material's surface has become a research hotspot in recent years. Micromachining of titanium alloy with an ultra-fast pulse laser is a very important research direction, and it has very important theoretical significance and application value in investigating the ablation threshold of titanium alloy irradiated by ultra-fast pulse lasers. Irradiated by a picosecond pulse laser with wavelengths of 1064 nm and 532 nm, the surface morphology and feature sizes, including ablation crater width (i.e. diameter), ablation depth, ablation area, ablation volume, single pulse ablation rate, and so forth, of the titanium alloy were studied, and their ablation distributions were obtained. The experimental results show that titanium alloy irradiated by a picosecond pulse infrared laser with a 1064 nm wavelength has better ablation morphology than that of the green picosecond pulse laser with a 532 nm wavelength. The feature sizes are approximately linearly dependent on the laser pulse energy density at low energy density and the monotonic increase in laser pulse energy density. With the increase in energy density, the ablation feature sizes are increased. The rate of increase in the feature sizes slows down gradually once the energy density reaches a certain value, and gradually saturated trends occur at a relatively high energy density. Based on the linear relation between the laser pulse energy density and the crater area of the titanium alloy surface, and the Gaussian distribution of the laser intensity on the cross section, the ablation threshold of titanium alloy irradiated by an ultra-fast pulse laser was calculated to be about 0.109 J/cm{sup 2}.

  14. X-ray irradiation induced changes in electron transport in stabilized a-Se photoconductors

    SciTech Connect (OSTI)

    Walornyj, M.; Kasap, S. O.

    2013-12-07

    We have examined the effect of high-dose x-ray irradiation on electron transport in stabilized amorphous selenium (a-Se) x-ray photoconductive films (of the type used in x-ray image detectors) by measuring the electron lifetime ?{sub e} through interrupted-field time-of-flight experiments. X-ray induced effects have been examined through two types of experiments. In recovery experiments, the a-Se was preirradiated with and without an applied field (5 V/?m) during irradiation with sufficient dose (typically ?20 Gy at 21 C) to significantly reduce the electron lifetime by ?50%, and then the recovery of the lifetime was monitored as a function of time at three different temperatures, 10 C, 21 C, and 35 C. The lifetime recovery kinetics was exponential with a relaxation time ?{sub r} that is thermally activated with an activation energy of 1.66 eV. ?{sub r} is a few hours at 21 C and only a few minutes at 35 C. In experiments examining the irradiation induced effects, the a-Se film was repeatedly exposed to x-ray radiation and the changes in the drift mobility and lifetime were monitored as a function of accumulated dose D. There was no observable change in the drift mobility. At 21 C, the concentration of x-ray induced deep traps (or capture centers), N{sub d}, increases linearly with D (N{sub d} ? D) whereas at 35 C, the recovery process prevents a linear increase in N{sub d} with D, and N{sub d} saturates. In all cases, even under high dose irradiation (?50 Gy), the lifetime was recoverable to its original equilibrium (pre-exposure) value within a few relaxation times.

  15. Removal of 14C from Irradiated Graphite for Graphite Recycle and Waste Volume Reduction

    SciTech Connect (OSTI)

    Dunzik-Gougar, Mary Lou; Windes, Will; Marsden, Barry

    2014-06-10

    The aim of the research presented here was to identify the chemical form of 14C in irradiated graphite. A greater understanding of the chemical form of this longest-lived isotope in irradiated graphite will inform not only management of legacy waste, but also development of next generation gas-cooled reactors. Approximately 250,000 metric tons of irradiated graphite waste exists worldwide, with the largest single quantity originating in the Magnox and AGR reactors of UK. The waste quantity is expected to increase with decommissioning of Generation II reactors and deployment of Generation I gas-cooled, graphite moderated reactors. Of greatest concern for long-term disposal of irradiated graphite is carbon-14 14C, with a half-life of 5730 years.

  16. Irradiation effects in low-alloy reactor pressure vessel steels (Heavy-Section Steel Technology Program Series 4 and 5)

    SciTech Connect (OSTI)

    Berggren, R.G.; McGowan, J.J.; Menke, B.H.; Nanstad, R.K.; Thoms, K.R.

    1984-01-01

    Multiple testing is done at two laboratories of typical nuclear pressure vessel materials (both irradiated and unirradiated) and statistical analyses of the test results. Multiple tests are conducted at each of several test temperatures for each material, standard deviations are determined, and results from the two laboratories are compared. The Fourth Heavy-Section Steel Technology (HSST) Irradiation Series, almost completed, was aimed at elastic-plastic and fully plastic fracture toughness of low-copper weldments (current practice welds). A typical nuclear pressure vessel plate steel was included for statistical purposes. The Fifth HSST Irradiation Series, now in progress, is aimed at determining the shape of the K/sub IR/ curve after significant radiation-induced shift of the transition temperatures. This series includes irradiated test specimens of thicknesses up to 100 mm and weldment compositions typical of early nuclear power reactor pressure vessel welds.

  17. Anisotropic swelling and microcracking of neutron irradiated Ti3AlC2-Ti5Al2C3 materials

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ang, Caen K.; Silva, Chinthaka M.; Shih, Chunghao Phillip; Koyanagi, Takaaki; Katoh, Yutai; Zinkle, Steven J.

    2015-12-17

    Mn + 1AXn (MAX) phase materials based on Ti–Al–C have been irradiated at 400 °C (673 K) with fission neutrons to a fluence of 2 × 1025 n/m2 (E > 0.1 MeV), corresponding to ~ 2 displacements per atom (dpa). We report preliminary results of microcracking in the Al-containing MAX phase, which contained the phases Ti3AlC2 and Ti5Al2C3. Equibiaxial ring-on-ring tests of irradiated coupons showed that samples retained 10% of pre-irradiated strength. Volumetric swelling of up to 4% was observed. Phase analysis and microscopy suggest that anisotropic lattice parameter swelling caused microcracking. Lastly, variants of titanium aluminum carbide may bemore » unsuitable materials for irradiation at light water reactor-relevant temperatures.« less

  18. Post Irradiation Evaluation of Thermal Control Coatings and Solid Lubricants to Support Fission Surface Power Systems

    SciTech Connect (OSTI)

    Bowman, Cheryl L.; Jaworske, Donald A.; Stanford, Malcolm K.; Persinger, Justin A.; Khorsandi, Behrooz; Blue, Thomas E.

    2007-01-30

    The development of a nuclear power system for space missions, such as the Jupiter Icy Moons Orbiter or a lunar outpost, requires substantially more compact reactor design than conventional terrestrial systems. In order to minimize shielding requirements and hence system weight, the radiation tolerance of component materials within the power conversion and heat rejection systems must be defined. Two classes of coatings, thermal control paints and solid lubricants, were identified as material systems for which limited radiation hardness information was available. Screening studies were designed to explore candidate coatings under a predominately fast neutron spectrum. The Ohio State Research Reactor Facility staff performed irradiation in a well characterized, mixed energy spectrum and performed post irradiation analysis of representative coatings for thermal control and solid lubricant applications. Thermal control paints were evaluated for 1 MeV equivalent fluences from 1013 to 1015 n/cm2. No optical degradation was noted although some adhesive degradation was found at higher fluence levels. Solid lubricant coatings were evaluated for 1 MeV equivalent fluences from 1015 to 1016 n/cm2 with coating adhesion and flexibility used for post irradiation evaluation screening. The exposures studied did not lead to obvious property degradation indicating the coatings would have survived the radiation environment for the previously proposed Jupiter mission. The results are also applicable to space power development programs such as fission surface power for future lunar and Mars missions.

  19. Studies of material properties under irradiation at BNL Linear Isotope Producer (BLIP)

    SciTech Connect (OSTI)

    Simos, N.; Kirk, H.; Ludewig, H.; Mokhov, N.; Hurh, P.; Misek, J.; /Fermilab

    2010-11-01

    Effects of proton beams irradiating materials considered for targets in high-power accelerator experiments have been under study using the Brookhaven National Laboratory's (BNL) 200 MeV Linac. The primary objectives of the study that includes a wide array of materials and alloys ranging between low and high-Z are to (a) observe changes in physio-mechanical properties which are important in maintaining high-power target functionality, (b) identify possible limits of proton flux or fluence above which certain material seize to maintain integrity, (c) study the role of material operating temperature in inducing or maintaining radiation damage reversal, and (d) correlate radiation damage effects of different species such as energetic protons and neutrons on materials by utilizing reactor and particle accelerator experience data. These objectives are specifically being addressed in the latest material irradiation study linked to the Long Baseline Neutrino Experiment (LBNE). Observations on irradiation effects on materials considered for high-power targets and other beam intercepting elements, such as collimators, from past studies and preliminary observations of the ongoing LBNE study are presented in this paper.

  20. Impact of proton irradiation on deep level states in n-GaN

    SciTech Connect (OSTI)

    Zhang, Z.; Arehart, A. R.; Cinkilic, E.; Ringel, S. A.; Chen, J.; Zhang, E. X.; Fleetwood, D. M.; Schrimpf, R. D.; McSkimming, B.; Speck, J. S.

    2013-07-22

    Deep levels in 1.8 MeV proton irradiated n-type GaN were systematically characterized using deep level transient spectroscopies and deep level optical spectroscopies. The impacts of proton irradiation on the introduction and evolution of those deep states were revealed as a function of proton fluences up to 1.1 10{sup 13} cm{sup ?2}. The proton irradiation introduced two traps with activation energies of E{sub C} - 0.13 eV and 0.16 eV, and a monotonic increase in the concentration for most of the pre-existing traps, though the increase rates were different for each trap, suggesting different physical sources and/or configurations for these states. Through lighted capacitance voltage measurements, the deep levels at E{sub C} - 1.25 eV, 2.50 eV, and 3.25 eV were identified as being the source of systematic carrier removal in proton-damaged n-GaN as a function of proton fluence.

  1. Method to Calculate Uncertainty Estimate of Measuring Shortwave Solar Irradiance using Thermopile and Semiconductor Solar Radiometers

    SciTech Connect (OSTI)

    Reda, I.

    2011-07-01

    The uncertainty of measuring solar irradiance is fundamentally important for solar energy and atmospheric science applications. Without an uncertainty statement, the quality of a result, model, or testing method cannot be quantified, the chain of traceability is broken, and confidence cannot be maintained in the measurement. Measurement results are incomplete and meaningless without a statement of the estimated uncertainty with traceability to the International System of Units (SI) or to another internationally recognized standard. This report explains how to use International Guidelines of Uncertainty in Measurement (GUM) to calculate such uncertainty. The report also shows that without appropriate corrections to solar measuring instruments (solar radiometers), the uncertainty of measuring shortwave solar irradiance can exceed 4% using present state-of-the-art pyranometers and 2.7% using present state-of-the-art pyrheliometers. Finally, the report demonstrates that by applying the appropriate corrections, uncertainties may be reduced by at least 50%. The uncertainties, with or without the appropriate corrections might not be compatible with the needs of solar energy and atmospheric science applications; yet, this report may shed some light on the sources of uncertainties and the means to reduce overall uncertainty in measuring solar irradiance.

  2. Ion irradiation testing and characterization of FeCrAl candidate alloys

    SciTech Connect (OSTI)

    Anderoglu, Osman; Aydogan, Eda; Maloy, Stuart Andrew; Wang, Yongqiang

    2014-10-29

    The Fuel Cycle Research and Development programs Advanced Fuels Campaign has initiated a multifold effort aimed at facilitating development of accident tolerant fuels. This effort involves development of fuel cladding materials that will be resistant to oxidizing environments for extended period of time such as loss of coolant accident. Ferritic FeCrAl alloys are among the promising candidates due to formation of a stable Al?O? oxide scale. In addition to being oxidation resistant, these promising alloys need to be radiation tolerant under LWR conditions (maximum dose of 10-15 dpa at 250 350C). Thus, in addition to a number of commercially available alloys, nuclear grade FeCrAl alloys developed at ORNL were tested using high energy proton irradiations and subsequent characterization of irradiation hardening and damage microstructure. This report summarizes ion irradiation testing and characterization of three nuclear grade FeCrAl cladding materials developed at ORNL and four commercially available Kanthal series FeCrAl alloys in FY14 toward satisfying FCRD campaign goals.

  3. Heritable Genetic Changes in Cells Recovered From Irradiated 3D Tissue Contracts. Final report

    SciTech Connect (OSTI)

    Cornforth, Michael N.

    2013-05-03

    Combining contemporary cytogenetic methods with DNA CGH microarray technology and chromosome flow-sorting increases substantially the ability to resolve exchange breakpoints associated with interstitial deletions and translocations, allowing the consequences of radiation damage to be directly measured at low doses, while also providing valuable insights into molecular mechanisms of misrepair processes that, in turn, identify appropriate biophysical models of risk at low doses. The aims of this work apply to cells recovered from 3D tissue constructs of human skin and, for the purpose of comparison, the same cells irradiated in traditional 2D cultures. These aims are: to analyze by multi-flour fluorescence in situ hybridization (mFISH) the chromosomes in clonal descendents of individual human fibroblasts that were previously irradiated; to examine irradiated clones from Aim 1 for submicroscopic deletions by subjecting their DNA to comparative genomic hybridization (CGH) microarray analysis; and to flow-sort aberrant chromosomes from clones containing stable radiation-induced translocations and map the breakpoints to within an average resolution of 100 kb using the technique of 'array painting'.

  4. Fracture properties of a neutron-irradiated stainless steel submerged arc weld cladding overlay

    SciTech Connect (OSTI)

    Corwin, W.R.; Berggren, R.G.; Nanstad, R.K.

    1984-01-01

    The ability of stainless steel cladding to increase the resistance of an operating nuclear reactor pressure vessel to extension of surface flaws depends greatly on the properties of the irradiated cladding. Therefore, weld overlay cladding irradiated at temperatures and fluences relevant to power reactor operation was examined. The cladding was applied to a pressure vessel steel plate by the submerged arc, single-wire, oscillating-electrode method. Three layers of cladding provided a thickness adequate for fabrication of test specimens. The first layer was type 309, and the upper two layers were type 308 stainless steel. The type 309 was diluted considerably by excessive melting of the base plate. Specimens were taken from near the base plate-cladding interface and also from the upper layers. Charpy V-notch and tensile specimens were irradiated at 288/sup 0/C to a fluence of 2 x 10/sup 23/ neutrons/m/sup 2/ (>1 MeV). 10 refs., 16 figs., 4 tabs.

  5. Uranium silicide pellet fabrication by powder metallurgy for accident tolerant fuel evaluation and irradiation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Harp, Jason Michael; Lessing, Paul Alan; Hoggan, Rita Elaine

    2015-06-21

    In collaboration with industry, Idaho National Laboratory is investigating uranium silicide for use in future light water reactor fuels as a more accident resistant alternative to uranium oxide base fuels. Specifically this project was focused on producing uranium silicide (U3Si2) pellets by conventional powder metallurgy with a density greater than 94% of the theoretical density. This work has produced a process to consistently produce pellets with the desired density through careful optimization of the process. Milling of the U3Si2 has been optimized and high phase purity U3Si2 has been successfully produced. Results are presented from sintering studies and microstructural examinationsmore » that illustrate the need for a finely ground reproducible particle size distribution in the source powder. The optimized process was used to produce pellets for the Accident Tolerant Fuel-1 irradiation experiment. The average density of these pellets was 11.54 ±0.06 g/cm3. Additional characterization of the pellets by scaning electron microscopy and X-ray diffraction has also been performed. As a result, pellets produced in this work have been encapsulated for irradiation, and irradiation in the Advanced Test Reactor is expected soon.« less

  6. Phenomena in oscillating downward propagating flames induced by external laser irradiation method

    SciTech Connect (OSTI)

    Park, June Sung; Fujita, Osamu; Honko, Teruaki; Yamada, Yuichiro; Ito, Hiroyuki; Nakamura, Yuji [Division of Mechanical and Space Engineering, Hokkaido University, Kita13 Nishi8, Kita-ku, Sapporo, Hokkaido (Japan)

    2010-11-15

    Experiments in C{sub 2}H{sub 4}/CO{sub 2}-O{sub 2} premixed flames (Le < 1) propagating downwardly in a tube have been conducted to observe transition phenomena from laminar flame front to turbulent flame propagation triggered by external laser irradiation method. To investigate the exact motions of flame tip fluctuation at the initial moment of irradiating CO{sub 2} laser, the completely flat flame front is selected as a default flame, which is corresponding to the primary acoustic instability as reported by Searby (1992). According to the time-resolved observation, the flame front exposed to CO{sub 2} laser beam shows extremely unstable flame motions in which highly curved flame front towards unburned mixture is subject to diffusive-thermal instability. Then, the sudden enhanced burning state (increased flame surface) caused by flame instability induces the secondary acoustic instability which is akin to the observation in Ref. In the present study, we report the detailed descriptions of flame fronts on the transient behaviors leading the primary acoustic instability to turbulent motions actively induced by the absorption of externally irradiated CO{sub 2} laser beam. (author)

  7. Minor antigen graft-versus-host reactions revealed in irradiated spleen and popliteal lymph node assays

    SciTech Connect (OSTI)

    Claman, H.N.; Jaffee, B.D.

    1984-10-01

    The graft-versus-hot (GVH) reaction across minor (non-H-2) histocompatibility barriers was studied in mice, in vivo. To increase GVH potential and to mimic clinical bone marrow transplantation protocols, we modified the popliteal lymph node (PLN) and the splenomegaly assays by irradiating the recipients before they received allogeneic lymphoid cell suspensions. In several combinations across major (H-2), minor (non-H-2) and multiple minor (non-H-2 plus minor lymphocyte stimulation) barriers, increased recipient organ weight (a measure of GVH activity) was seen with irradiated F1 recipients of parental cells. The irradiated splenomegaly (x-splenomegaly) assay was more sensitive than the (x-PLN) assay, but both correlated with in vivo GVH experiments of the P----F1 variety. The x-splenomegaly test indicated histoincompatibility in a system (B10.D2----BALB/c) in which the primary in vitro mixed leukocyte reactions is nonreactive, but in which systemic GVH can be induced. The x-splenomegaly test should be useful in analyzing complex reactions involving minor histocompatibility antigens in vivo.

  8. Alloy development for irradiation performance in fusion reactors. Annual report, September 1979-September 1980

    SciTech Connect (OSTI)

    Harling, O K; Grant, N J

    1980-12-01

    This report summarizes the research and development work performed during the second year of an M.I.T. project directed toward the development of improved structural alloys for the fusion reactor first wall application. Several new alloys have been produced by rapid solidification. Emphasis in alloy design and production has been placed on producing austenitic Type 316SS with fine dispersions of TiC and Al/sub 2/O/sub 3/ particles. Results of mechanical and microstructural tests are presented. A number of neutron irradiations have been initiated on samples fabricated from alloys produced in this project. A dual beam, heavy ion and helium ion, irradiation was completed using several alloys and a range of temperatures, damage rates and total doses. Modeling of irradiation phenomena has been continued with emphasis in the last year upon understanding the effect of recoil resolution on relatively stable second phase particles. Work continued to fully characterize the microstructure of several ZrB/sub 2/ doped stainless steels.

  9. Uranium silicide pellet fabrication by powder metallurgy for accident tolerant fuel evaluation and irradiation

    SciTech Connect (OSTI)

    Harp, Jason Michael; Lessing, Paul Alan; Hoggan, Rita Elaine

    2015-06-21

    In collaboration with industry, Idaho National Laboratory is investigating uranium silicide for use in future light water reactor fuels as a more accident resistant alternative to uranium oxide base fuels. Specifically this project was focused on producing uranium silicide (U3Si2) pellets by conventional powder metallurgy with a density greater than 94% of the theoretical density. This work has produced a process to consistently produce pellets with the desired density through careful optimization of the process. Milling of the U3Si2 has been optimized and high phase purity U3Si2 has been successfully produced. Results are presented from sintering studies and microstructural examinations that illustrate the need for a finely ground reproducible particle size distribution in the source powder. The optimized process was used to produce pellets for the Accident Tolerant Fuel-1 irradiation experiment. The average density of these pellets was 11.54 ±0.06 g/cm3. Additional characterization of the pellets by scaning electron microscopy and X-ray diffraction has also been performed. As a result, pellets produced in this work have been encapsulated for irradiation, and irradiation in the Advanced Test Reactor is expected soon.

  10. Multiscale Simulation of Thermo-mechancial Processes in Irradiated Fission-reactor Materials.

    SciTech Connect (OSTI)

    Simon R. Phillpot

    2012-06-08

    The work funded from this project has been published in six papers, with two more in draft form, with submission planned for the near future. The papers are: (1) Kinetically-Evolving Irradiation-Induced Point-Defect Clusters in UO{sub 2} by Molecular-Dynamics Simulation; (2) Kinetically driven point-defect clustering in irradiated MgO by molecular-dynamics simulation; (3) Grain-Boundary Source/Sink Behavior for Point Defect: An Atomistic Simulation Study; (4) Energetics of intrinsic point defects in uranium dioxide from electronic structure calculations; (5) Thermodynamics of fission products in UO{sub 2{+-}x}; and (6) Atomistic study of grain boundary sink strength under prolonged electron irradiation. The other two pieces of work that are currently being written-up for publication are: (1) Effect of Pores and He Bubbles on the Thermal Transport Properties of UO2 by Molecular Dynamics Simulation; and (2) Segregation of Ruthenium to Edge Dislocations in Uranium Dioxide.

  11. Tritium trapping in silicon carbide in contact with solid breeder under high flux isotope reactor irradiation

    SciTech Connect (OSTI)

    H. Katsui; Y. Katoh; A. Hasegawa; M. Shimada; Y. Hatano; T. Hinoki; S. Nogami; T. Tanaka; S. Nagata; T. Shikama

    2013-11-01

    The trapping of tritium in silicon carbide (SiC) injected from ceramic breeding materials was examined via tritium measurements using imaging plate (IP) techniques. Monolithic SiC in contact with ternary lithium oxide (lithium titanate and lithium aluminate) as a ceramic breeder was irradiated in the High Flux Isotope Reactor (HFIR) in Oak Ridge, Tennessee, USA. The distribution of photo-stimulated luminescence (PSL) of tritium in SiC was successfully obtained, which separated the contribution of 14C -rays to the PSL. The tritium incident from ceramic breeders was retained in the vicinity of the SiC surface even after irradiation at 1073 K over the duration of ~3000 h, while trapping of tritium was not observed in the bulk region. The PSL intensity near the SiC surface in contact with lithium titanate was higher than that obtained with lithium aluminate. The amount of the incident tritium and/or the formation of a Li2SiO3 phase on SiC due to the reaction with lithium aluminate under irradiation likely were responsible for this observation.

  12. Polymer surfaces graphitization by low-energy He{sup +} ions irradiation

    SciTech Connect (OSTI)

    Geworski, A.; Lazareva, I.; Gieb, K.; Koval, Y.; Mller, P. [Department of Physics, Universitt Erlangen-Nrnberg, Erwin-Rommel-Str. 1, 91058 Erlangen (Germany)

    2014-08-14

    The electrical and optical properties of surfaces of polyimide and AZ5214e graphitized by low-energy (1?keV) He{sup +} irradiation at different polymer temperatures were investigated. The conductivity of the graphitized layers can be controlled with the irradiation temperature within a broad range and can reach values up to ?1000?S/cm. We show that the electrical transport in low-conducting samples is governed by thermally activated hopping, while the samples with a high conductivity show a typical semimetallic behavior. The transition from thermally activated to semimetallic conductance governed by the irradiation temperature could also be observed in optical measurements. The semimetallic samples show an unusually high for graphitic materials carrier concentration, which results in a high extinction coefficient in the visible light range. By analyzing the temperature dependence of the conductance of the semimetallic samples, we conclude that the scattering of charge carriers is dominated by Coulomb interactions and can be described by a weak localization model. The transition from a three to two dimensional transport mechanism at low temperatures consistently explains the change in the temperature dependence of the conductance by cooling, observed in experiments.

  13. Narrowband filter radiometer for ground-based measurements of global ultraviolet solar irradiance and total ozone

    SciTech Connect (OSTI)

    Petkov, Boyan; Vitale, Vito; Tomasi, Claudio; Bonafe, Ubaldo; Scaglione, Salvatore; Flori, Daniele; Santaguida, Riccardo; Gausa, Michael; Hansen, Georg; Colombo, Tiziano

    2006-06-20

    The ultraviolet narrowband filter radiometer (UV-RAD) designed by the authors to take ground-based measurements of UV solar irradiance, total ozone, and biological dose rate is described, together with the main characteristics of the seven blocked filters mounted on it, all of which have full widths at half maxima that range 0.67 to 0.98 nm. We have analyzed the causes of cosine response and calibration errors carefully to define the corresponding correction terms, paying particular attention to those that are due to the spectral displacements of the filter transmittance peaks from the integer wavelength values. The influence of the ozone profile on the retrieved ozone at large solar zenith angles has also been examined by means of field measurements. The opportunity of carrying out nearly monochromatic irradiance measurements offered by the UV-RAD allowed us to improve the procedure usually followed to reconstruct the solar spectrum at the surface by fitting the computed results, using radiative transfer models with field measurements of irradiance. Two long-term comparison campaigns took place, showing that a mean discrepancy of+0.3% exists between the UV-RAD total ozone values and those given by the Brewer no. 63 spectroradiometer and that mean differences of+0.3% and-0.9% exist between the erythemal dose rates determined with the UV-RAD and those obtained with the Brewer no. 63 and the Brewer no. 104 spectroradiometers, respectively.

  14. Inhalation radiotoxicity of irradiated thorium as a heavy water reactor fuel

    SciTech Connect (OSTI)

    Edwards, G.W.R.; Priest, N.D.; Richardson, R.B.

    2013-07-01

    The online refueling capability of Heavy Water Reactors (HWRs), and their good neutron economy, allows a relatively high amount of neutron absorption in breeding materials to occur during normal fuel irradiation. This characteristic makes HWRs uniquely suited to the extraction of energy from thorium. In Canada, the toxicity and radiological protection methods dealing with personnel exposure to natural uranium (NU) spent fuel (SF) are well-established, but the corresponding methods for irradiated thorium fuel are not well known. This study uses software to compare the activity and toxicity of irradiated thorium fuel ('thorium SF') against those of NU. Thorium elements, contained in the inner eight elements of a heterogeneous high-burnup bundle having LEU (Low-enriched uranium) in the outer 35 elements, achieve a similar burnup to NU SF during its residence in a reactor, and the radiotoxicity due to fission products was found to be similar. However, due to the creation of such inhalation hazards as U-232 and Th-228, the radiotoxicity of thorium SF was almost double that of NU SF after sufficient time has passed for the decay of shorter-lived fission products. Current radio-protection methods for NU SF exposure are likely inadequate to estimate the internal dose to personnel to thorium SF, and an analysis of thorium in fecal samples is recommended to assess the internal dose from exposure to this fuel. (authors)

  15. Pre- and postirradiation evaluation of TRISO ThO/sub 2/ particles irradiated in capsule HT-34

    SciTech Connect (OSTI)

    Young, C.A.; Jones, C.S.

    1980-10-01

    Capsule HT-34 was irradiated jointly by General Atomic Company (GA) and Oak Ridge National Laboratory (ORNL). This report presents the pre- and postirradiation evaluation conducted by GA. The purpose of the test was to characterize the mechanical and chemical performance and fission product release of TRISO ThO/sub 2/ particles. Sixteen TRISO ThO/sub 2/ samples, which had been fabricated in the production-line (240-mm-ID) coater, were irradiated at approximately 1200 and 1450/sup 0/C to neutron fluences of 5.1 to 10.2 x 10/sup 25/ n/m/sup 2/ (E > 29 fJ)/sub HTGR/, and burnups of 5.1 to 12.7% FIMA. Following are the results of the postirradiation examination: the OPyC coating failure of the 800-..mu..m-diameter particles irradiated at 1200/sup 0/C was less than or equal to 1.8%; the pressure-vessel model overpredicted failure up to seven times the observed failure for the samples irradiated at 1200/sup 0/C; palladium attack and internal corrosion of the SiC coating was observed in the samples irradiated at 1200/sup 0/C; internal corrosion of the SiC coating caused SiC failure up to 100% in the samples irradiated at 1450/sup 0/C; and an average of 16 and 90% of the Cs was released from failed particles irradiated at 1200 and 1450/sup 0/C, respectively, after 2686 h of irradiation.

  16. LANAI HIGH-DENSITY IRRADIANCE SENSOR NETWORK FOR CHARACTERIZING SOLAR RESOURCE VARIABILITY OF MW-SCALE PV SYSTEM

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    LANAI HIGH-DENSITY IRRADIANCE SENSOR NETWORK FOR CHARACTERIZING SOLAR RESOURCE VARIABILITY OF MW-SCALE PV SYSTEM Scott Kuszamaul 1 , Abraham Ellis 1 , Joshua Stein 1 , and Lars Johnson 2 1 Sandia National Laboratories, Albuquerque, NM, USA 2 SunPower Corporation, Richmond, CA, USA ABSTRACT Sandia National Laboratories (Sandia) and SunPower Corporation (SunPower) have completed design and deployment of an autonomous irradiance monitoring system based on wireless mesh communications and a battery

  17. Current Status of Concentrator Photovoltaic (CPV) Technology

    SciTech Connect (OSTI)

    Philipps, S. P.; Bett, A. W.; Horowitz, K.; Kurtz, S.

    2015-01-01

    This report describes the current status of the market and technology for concentrator photovoltaic (CPV) cells and modules. Significant progress in CPV has been achieved, including record efficiencies for modules (36.7%) and cells (46%), as well as growth of large field installations in recent years. CPV technology may also have the potential to be cost-competitive on a levelized cost of energy (LCOE) basis in regions of high direct normal irradiance (DNI). The study includes an overview of all installations larger than 1 MW, information on companies currently active in the CPV field, efficiency data, and estimates of the LCOE in different scenarios.

  18. Microstructure changes and thermal conductivity reduction in UO2 following 3.9 MeV He2+ ion irradiation

    SciTech Connect (OSTI)

    Janne Pakrinen; Marat Khafizov; Lingfeng He; Chris Wetland; Jian Gan; Andrew T. Nelson; David H Hurley; Anter El-Azab; Todd R Allen

    2014-11-01

    The microstructural changes and associated effects on thermal conductivity were examined in UO2 after irradiation using 3.9 MeV He2+ ions. Lattice expansion of UO2 was observed in x-ray diffraction after ion irradiation up to 51016 He2+/cm2 at low-temperature (< 200 C). Transmission electron microscopy (TEM) showed homogenous irradiation damage across an 8 m thick plateau region, which consisted of small dislocation loops accompanied by dislocation segments. Dome-shaped blisters were observed at the peak damage region (depth around 8.5 m) in the sample subjected to 51016 He2+/cm2, the highest fluence reached, while similar features were not detected at 91015 He2+/cm2. Laser-based thermo-reflectance measurements showed that the thermal conductivity for the irradiated layer decreased about 55 % for the high fluence sample and 35% for the low fluence sample as compared to an un-irradiated reference sample. Detailed analysis for the thermal conductivity indicated that the conductivity reduction was caused by the irradiation induced point defects.

  19. High Dose Neutron Irradiation of Hi-Nicalon Type S Silicon Carbide Composites, Part 2. Mechanical and Physical Properties

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Katoh, Yutai; Nozawa, Takashi; Shih, Chunghao Phillip; Ozawa, Kazumi; Koyanagi, Takaaki; Porter, Wallace D; Snead, Lance Lewis

    2015-01-07

    Nuclear-grade silicon carbide (SiC) composite material was examined for mechanical and thermophysical properties following high-dose neutron irradiation in the High Flux Isotope Reactor at a temperature range of 573–1073 K. Likewise, the material was chemical vapor-infiltrated SiC-matrix composite with a two-dimensional satin weave Hi-Nicalon Type S SiC fiber reinforcement and a multilayered pyrocarbon/SiC interphase. Moderate (1073 K) to very severe (573 K) degradation in mechanical properties was found after irradiation to >70 dpa, whereas no evidence was found for progressive evolution in swelling and thermal conductivity. The swelling was found to recover upon annealing beyond the irradiation temperature, indicating themore » irradiation temperature, but only to a limited extent. Moreover, the observed strength degradation is attributed primarily to fiber damage for all irradiation temperatures, particularly a combination of severe fiber degradation and likely interphase damage at relatively low irradiation temperatures.« less

  20. Microstructure chemistry and mechanical properties of Ni-based superalloy Rene N4 under irradiation at room temperature

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sun, C.; Kirk, M.; Li, M.; Hattar, Khalid Mikhiel; Wang, Y.; Anderoglu, O.; Valdez, J.; Uberuaga, B. P.; Dickerson, R.; Maloy, S. A.

    2015-06-14

    Nickel superalloys with cubic L12 structured γ' (Ni3(Al, Ti)) precipitates exhibit high strength at high temperatures and excellent corrosion resistance when exposed to water. Unlike prior studies on irradiation damage of other Ni-based superalloys, our study on Rene N4 involves much larger γ' precipitates, ~450 nm in size, a size regime where the irradiation-induced disordering and dissolution kinetics and the corresponding mechanical property evolution are unknown. Under heavy ion irradiation at room temperature, the submicron-sized γ' precipitates were fully disordered at ~0.3 dpa and only later partially dissolved after 75 dpa irradiation. Nanoindentation experiments indicate that the mechanical properties ofmore » the alloy change significantly, with a dramatic decrease in hardness, with irradiation dose. Three contributions to the change in hardness were examined: defect clusters, disordering and dissolution. Moreover, the generation of defect clusters in the matrix and precipitates slightly increased the indentation hardness, while disordering of the submicron-sized γ' precipitates resulted in a dramatic decrease in the total hardness, which decreased further during the early stages of the intermixing between γ' precipitates and matrix (<18 dpa). As a result, controlling the long-range-ordering and chemical intermixing can be used to tailor the mechanical properties of Ni-based superalloys under irradiation.« less

  1. Analysis and synthesis of the variability of irradiance and PV power time series with the wavelet transform

    SciTech Connect (OSTI)

    Perpinan, O.; Lorenzo, E.

    2011-01-15

    The irradiance fluctuations and the subsequent variability of the power output of a PV system are analysed with some mathematical tools based on the wavelet transform. It can be shown that the irradiance and power time series are nonstationary process whose behaviour resembles that of a long memory process. Besides, the long memory spectral exponent {alpha} is a useful indicator of the fluctuation level of a irradiance time series. On the other side, a time series of global irradiance on the horizontal plane can be simulated by means of the wavestrapping technique on the clearness index and the fluctuation behaviour of this simulated time series correctly resembles the original series. Moreover, a time series of global irradiance on the inclined plane can be simulated with the wavestrapping procedure applied over a signal previously detrended by a partial reconstruction with a wavelet multiresolution analysis, and, once again, the fluctuation behaviour of this simulated time series is correct. This procedure is a suitable tool for the simulation of irradiance incident over a group of distant PV plants. Finally, a wavelet variance analysis and the long memory spectral exponent show that a PV plant behaves as a low-pass filter. (author)

  2. Irradiation effects on Charpy impact and tensile properties of low upper-shelf welds, HSSI series 2 and 3

    SciTech Connect (OSTI)

    Nanstad, R.K.; Berggren, R.G. )

    1991-08-01

    When reactor pressure vessel steels exhibit Charpy V-notch impact upper-shelf energy levels of less than 68 J (50 ft-lb), the requirements of Title 10, Code of Federal Regulations, Part 50, Appendix G, are not met. The regulations require, as an option, that a fracture mechanics analysis be performed that conservatively demonstrates adequate safety margins for continued operation. Under conditions where large prefracture crack-tip plastic zones are present, linear-elastic fracture mechanics concepts are not applicable, and the use of elastic-plastic fracture mechanics concepts has been recommended by the US Nuclear Regulatory Commission. A number of Babcock and Wilcox Company-fabricated reactor vessels in commercial pressurized water reactor plants include welds with both relatively low initial Charpy upper-shelf energies and high copper concentrations, which make them highly sensitive to neutron irradiation. As a result, the Charpy upper-shelf energies of many welds are expected to fall below 68 J (50 ft-lb) prior to reaching design life. The Heavy-Section Steel Irradiation Program conducted the Second and Third Irradiation Series to investigate the effects of irradiation on the ductile fracture toughness of seven commercially fabricated, low upper-shelf welds. This report represents analyses of the Charpy impact and tensile test data, including adjustments for irradiation temperature and fluence normalization, which make possible comparison of the irradiation sensitivity the different welds.

  3. Defect annealing and thermal desorption of deuterium in low dose HFIR neutron-irradiated tungsten

    SciTech Connect (OSTI)

    Masashi Shimada; M. Hara; T. Otsuka; Y. Oya; Y. Hatano

    2014-05-01

    Accurately estimating tritium retention in plasma facing components (PFCs) and minimizing its uncertainty are key safety issues for licensing future fusion power reactors. D-T fusion reactions produce 14.1 MeV neutrons that activate PFCs and create radiation defects throughout the bulk of the material of these components. Recent studies show that tritium migrates and is trapped in bulk (>> 10 m) tungsten beyond the detection range of nuclear reaction analysis technique [1-2], and thermal desorption spectroscopy (TDS) technique becomes the only established diagnostic that can reveal hydrogen isotope behavior in in bulk (>> 10 m) tungsten. Radiation damage and its recovery mechanisms in neutron-irradiated tungsten are still poorly understood, and neutron-irradiation data of tungsten is very limited. In this paper, systematic investigations with repeated plasma exposures and thermal desorption are performed to study defect annealing and thermal desorption of deuterium in low dose neutron-irradiated tungsten. Three tungsten samples (99.99 at. % purity from A.L.M.T. Co., Japan) irradiated at High Flux Isotope Reactor at Oak Ridge National Laboratory were exposed to high flux (ion flux of (0.5-1.0)x1022 m-2s-1 and ion fluence of 1x1026 m-2) deuterium plasma at three different temperatures (100, 200, and 500 C) in Tritium Plasma Experiment at Idaho National Laboratory. Subsequently, thermal desorption spectroscopy (TDS) was performed with a ramp rate of 10 C/min up to 900 C, and the samples were annealed at 900 C for 0.5 hour. These procedures were repeated three (for 100 and 200 C samples) and four (for 500 C sample) times to uncover damage recovery mechanisms and its effects on deuterium behavior. The results show that deuterium retention decreases approximately 90, 75, and 66 % for 100, 200, and 500 C, respectively after each annealing. When subjected to the same TDS recipe, the desorption temperature shifts from 800 C to 600 C after 1st annealing for the sample exposed to TPE at 500 C. Tritium Migration Analysis Program (TMAP) analysis reveals that the detrapping energy decreases from 1.8 eV to 1.4 eV, indicating the changes in trapping mechanisms. This paper also summarizes deuterium behavior studies in HFIR neutron-irradiated tungsten under US-Japan TITAN program.

  4. Comparison of fission product release predictions using PARFUME with results from the AGR-1 irradiation experiment

    SciTech Connect (OSTI)

    Blaise Collin

    2014-09-01

    This report documents comparisons between post-irradiation examination measurements and model predictions of silver (Ag), cesium (Cs), and strontium (Sr) release from selected tristructural isotropic (TRISO) fuel particles and compacts during the first irradiation test of the Advanced Gas Reactor program that occurred from December 2006 to November 2009 in the Advanced Test Reactor (ATR) at Idaho National Laboratory (INL). The modeling was performed using the particle fuel model computer code PARFUME (PARticle FUel ModEl) developed at INL. PARFUME is an advanced gas-cooled reactor fuel performance modeling and analysis code (Miller 2009). It has been developed as an integrated mechanistic code that evaluates the thermal, mechanical, and physico-chemical behavior of fuel particles during irradiation to determine the failure probability of a population of fuel particles given the particle-to-particle statistical variations in physical dimensions and material properties that arise from the fuel fabrication process, accounting for all viable mechanisms that can lead to particle failure. The code also determines the diffusion of fission products from the fuel through the particle coating layers, and through the fuel matrix to the coolant boundary. The subsequent release of fission products is calculated at the compact level (release of fission products from the compact) but it can be assessed at the particle level by adjusting the diffusivity in the fuel matrix to very high values. Furthermore, the diffusivity of each layer can be individually set to a high value (typically 10-6 m2/s) to simulate a failed layer with no capability of fission product retention. In this study, the comparison to PIE focused on fission product release and because of the lack of failure in the irradiation, the probability of particle failure was not calculated. During the AGR-1 irradiation campaign, the fuel kernel produced and released fission products, which migrated through the successive layers of the TRISO-coated particle and potentially through the compact matrix. The release of these fission products was measured in PIE and modeled with PARFUME.

  5. Prediction of Thermal Conductivity for Irradiated SiC/SiC Composites by Informing Continuum Models with Molecular Dynamics Data

    SciTech Connect (OSTI)

    Nguyen, Ba Nghiep; Gao, Fei; Henager, Charles H.; Kurtz, Richard J.

    2014-05-01

    This article proposes a new method to estimate the thermal conductivity of SiC/SiC composites subjected to neutron irradiation. The modeling method bridges different scales from the atomic scale to the scale of a 2D SiC/SiC composite. First, it studies the irradiation-induced point defects in perfect crystalline SiC using molecular dynamics (MD) simulations to compute the defect thermal resistance as a function of vacancy concentration and irradiation dose. The concept of defect thermal resistance is explored explicitly in the MD data using vacancy concentrations and thermal conductivity decrements due to phonon scattering. Point defect-induced swelling for chemical vapor deposited (CVD) SiC as a function of irradiation dose is approximated by scaling the corresponding MD results for perfect crystal ?-SiC to experimental data for CVD-SiC at various temperatures. The computed thermal defect resistance, thermal conductivity as a function of grain size, and definition of defect thermal resistance are used to compute the thermal conductivities of CVD-SiC, isothermal chemical vapor infiltrated (ICVI) SiC and nearly-stoichiometric SiC fibers. The computed fiber and ICVI-SiC matrix thermal conductivities are then used as input for an Eshelby-Mori-Tanaka approach to compute the thermal conductivities of 2D SiC/SiC composites subjected to neutron irradiation within the same irradiation doses. Predicted thermal conductivities for an irradiated Tyranno-SA/ICVI-SiC composite are found to be comparable to available experimental data for a similar composite ICVI-processed with these fibers.

  6. Intra- and Interfractional Variations for Prone Breast Irradiation: An Indication for Image-Guided Radiotherapy

    SciTech Connect (OSTI)

    Morrow, Natalya V.; Stepaniak, Christopher; White, Julia; Wilson, J. Frank [Department of Radiation Oncology, Medical College of Wisconsin, Milwaukee, WI (United States); Li, X. Allen [Department of Radiation Oncology, Medical College of Wisconsin, Milwaukee, WI (United States)], E-mail: ali@radonc.mcw.edu

    2007-11-01

    Purpose: Intra- and interfractional errors for breast cancer patients undergoing breast irradiation in the prone position were analyzed. Methods and Materials: To assess intrafractional error resulting from respiratory motion, four-dimensional computed tomography scans were acquired for 3 prone and 3 supine patients, and the respiratory motion was compared for the two positions. To assess the interfractional error caused by daily set-up variations, daily electronic portal images of one of the treatment beams were taken for 15 prone-positioned patients. Portal images were then overlaid with images from the planning system that included the breast contour and the isocenter, treatment beam portal, and isocenter. The shift between the planned and actual isocenter was recorded for each portal image, and descriptive statistics were collected for each patient. The margins were calculated using the 2{sigma}+0.7{sigma} recipe, as well as 95% confidence interval based on the pooled standard deviation of the datasets. Results: Respiratory motion of the chest wall is drastically reduced from 2.3 {+-} 0.9 mm in supine position to -0.1 {+-} 0.4 mm in prone position. The daily set-up errors vary in magnitude from 0.0 cm to 1.65 cm and are patient dependent. The margins were defined by considering only the standard deviation to be 1.1 cm, and 2.0 cm when the systematic errors were considered using the 2{sigma}+0.7{sigma} recipe. Conclusions: Prone positioning of patients for breast irradiation significantly reduces the uncertainty introduced by intrafractional respiratory motion. The presence of large systematic error in the interfractional variations necessitates a large clinical target volume-to-planning target volume margin and indicates the importance of image guidance for partial breast irradiation in the prone position, particularly using imaging modality capable of identifying the lumpectomy cavity.

  7. Role of Trapping Impurities on He Desorption and Clustering in Irradiated a-Fe

    SciTech Connect (OSTI)

    Ortiz, Christophe J.; Caturla, Maria Jose; Fu, Chu Chun; Willaime, Francois

    2008-07-01

    It is well-known that impurities affect the migration of intrinsic point defects in metals. For instance, carbon is a common impurity in Fe that significantly retards diffusion of vacancies. Under fusion irradiation conditions, high levels of He are produced by transmutation reactions. This element strongly interacts with vacancies produced during irradiation and agglomerate into stable He-vacancy clusters that can deteriorate the mechanical properties of the material. A physically-based model accounting for the interactions between He, point defects (interstitials and vacancies) and trapping impurities is therefore necessary to understand and predict damage evolution in Fe. We have used a multi-scale approach to predict the evolution of He in the presence of impurities in irradiated Fe. Density Functional Theory (DFT) calculations were performed to investigate the migration mechanisms and to determine the activation energies of the different atomistic processes. The influence of impurities - such as carbon - on the binding energies of small He-vacancy clusters was also studied. Using the information obtained by DFT a physically-based model was developed and implemented in a kinetic Monte Carlo (kMC) code to follow the evolution of He in Fe. In addition, a model based on the rate theory (RT) was developed in order to achieve larger simulation times and volumes. Results obtained with this model, which is based on a mean field approximation are compared to those obtained with kMC. Using this multi-scale approach, the simulation results are used to interpret the different stages of thermal He desorption experiments and to determine the predominant migration mechanism. The influence of impurities which affect the diffusion of point defects or modify the binding energies of He-vacancy type clusters is also studied. (authors)

  8. Dimensional isotropy of 6H and 3C SiC under neutron irradiation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Snead, Lance L.; Katoh, Yutai; Koyanagi, Takaaki; Terrani, Kurt A.; Specht, Eliot D.

    2016-01-16

    This investigation experimentally determines the as-irradiated crystal axes dimensional change of the common polytypes of SiC considered for nuclear application. Single crystal α-SiC (6H), β-SiC (3C), CVD β-SiC, and single crystal Si have been neutron irradiated near 60 °C from 2 × 1023 to 2 × 1026 n/m2 (E > 0.1 MeV), or about 0.02–20 dpa, in order to study the effect of irradiation on bulk swelling and strain along independent crystalline axes. Single crystal, powder diffractometry and density measurement have been carried out. For all neutron doses where the samples remained crystalline all SiC materials demonstrated equivalent swelling behavior.more » Moreover the 6H–SiC expanded isotropically. The magnitude of the swelling followed a ~0.77 power law against dose consistent with a microstructure evolution driven by single interstitial (carbon) mobility. Extraordinarily large ~7.8% volume expansion in SiC was observed prior to amorphization. Above ~0.9 × 1025 n/m2 (E > 0.1 MeV) all SiC materials became amorphous with an identical swelling: a 11.7% volume expansion, lowering the density to 2.84 g/cm3. As a result, the as-amorphized density was the same at the 2 × 1025 and 2 × 1026 n/m2 (E > 0.1 MeV) dose levels.« less

  9. Irradiation Test of Advanced PWR Fuel in Fuel Test Loop at HANARO

    SciTech Connect (OSTI)

    Yang, Yong Sik; Bang, Je Geon; Kim, Sun Ki; Song, Kun Woo; Park, Su Ki; Seo, Chul Gyo

    2007-07-01

    A new fuel test loop has been constructed in the research reactor HANARO at KAERI. The main objective of the FTL (Fuel Test Loop) is an irradiation test of a newly developed LWR fuel under PWR or Candu simulated conditions. The first test rod will be loaded within 2007 and its irradiation test will be continued until a rod average their of 62 MWd/kgU. A total of five test rods can be loaded into the IPS (In-Pile Section) and fuel centerline temperature, rod internal pressure and fuel stack elongation can be measured by an on-line real time system. A newly developed advanced PWR fuel which consists of a HANA{sup TM} alloy cladding and a large grain UO{sub 2} pellet was selected as the first test fuel in the FTL. The fuel cladding, the HANA{sup TM} alloy, is an Nb containing Zirconium alloy that has shown better corrosion and creep resistance properties than the current Zircaloy-4 cladding. A total of six types of HANA{sup TM} alloy were developed and two or three of these candidate alloys will be used as test rod cladding, which have shown a superior performance to the others. A large-grain UO{sub 2} pellet has a 14{approx}16 micron 2D diameter grain size for a reduction of a fission gas release at a high burnup. In this paper, characteristics of the FTL and IPS are introduced and the expected operation and irradiation conditions are summarized for the test periods. Also the preliminary fuel performance analysis results, such as the cladding oxide thickness, fission gas release and rod internal pressure, are evaluated from the test rod safety analysis aspects. (authors)

  10. Irradiation behaviour of the large grained UO{sub 2} fuel pellet in the transient conditions

    SciTech Connect (OSTI)

    Kosaka, Yuji; Watanabe, Seiichi; Arakawa, Yasushi

    2007-07-01

    In order to achieve a high duty fuel rod design, it is the key issue to suppress the fission gas release from the view point of the fuel rod inner pressure design. The large grain UO{sub 2} pellet is one of the candidates to meet such a requirement by reducing the fission gas release especially at high power and/or high burnup. We have demonstrated the fuel performance of the large grain pellet in the PWR irradiation conditions, which was fabricated with no additive but with active UO{sub 2} powder through the conventional pelletizing process for the normal grain size pellet. According to the mechanism of the fission gas retention, there may be a concern about the larger gas bubble swelling of the large grain pellet at the power transient conditions which may increase the potential of the PCMI failure. In this paper, we focus on the differences of the dimensional change in comparison among the pellets with the different grain sizes at the power transient conditions. The power ramp tests were carried out on the high burnup fuel rods of normal and large grain pellet with no additive, which had been irradiated in the PWR conditions up to around 60 GWd/t at peak position. The detailed PIE results revealed that the volume increment due to the power ramp clearly showed the dependence on the grain size as well as the fission gas release and suggested that the larger grain with no additive may suppress the gas bubble swelling at the power transient conditions. According to the experimental results, it is concluded that the large grain pellet with no additive does not deteriorate the irradiation performance during the power transient conditions from the view point of the gas bubble swelling. (authors)

  11. Gamma Knife irradiation method based on dosimetric controls to target small areas in rat brains

    SciTech Connect (OSTI)

    Constanzo, Julie; Paquette, Benoit; Charest, Gabriel; Masson-Côté, Laurence; Guillot, Mathieu

    2015-05-15

    Purpose: Targeted and whole-brain irradiation in humans can result in significant side effects causing decreased patient quality of life. To adequately investigate structural and functional alterations after stereotactic radiosurgery, preclinical studies are needed. The purpose of this work is to establish a robust standardized method of targeted irradiation on small regions of the rat brain. Methods: Euthanized male Fischer rats were imaged in a stereotactic bed, by computed tomography (CT), to estimate positioning variations relative to the bregma skull reference point. Using a rat brain atlas and the stereotactic bregma coordinates obtained from CT images, different regions of the brain were delimited and a treatment plan was generated. A single isocenter treatment plan delivering ≥100 Gy in 100% of the target volume was produced by Leksell GammaPlan using the 4 mm diameter collimator of sectors 4, 5, 7, and 8 of the Gamma Knife unit. Impact of positioning deviations of the rat brain on dose deposition was simulated by GammaPlan and validated with dosimetric measurements. Results: The authors’ results showed that 90% of the target volume received 100 ± 8 Gy and the maximum of deposited dose was 125 ± 0.7 Gy, which corresponds to an excellent relative standard deviation of 0.6%. This dose deposition calculated with GammaPlan was validated with dosimetric films resulting in a dose-profile agreement within 5%, both in X- and Z-axes. Conclusions: The authors’ results demonstrate the feasibility of standardizing the irradiation procedure of a small volume in the rat brain using a Gamma Knife.

  12. Proton and gamma irradiation of Fabry-Perot quantum cascade lasers for space qualification

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Myers, Tanya L.; Cannon, Bret D.; Brauer, Carolyn S.; Hansen, Stewart; Crowther, Blake

    2015-01-20

    Fabry-Perot quantum cascade lasers (QCLs) were characterized following irradiation by high energy (64 MeV) protons and Cobalt-60 gamma rays. Seven QCLs were exposed to radiation dosages that are typical for a space mission in which the total accumulated dosages from both radiation sources varied from 20 krad(Si) to 46.3 krad(Si). The QCLs did not show any measurable changes in threshold current or slope efficiency suggesting the suitability of QCLs for use in space-based missions.

  13. Lead test assembly irradiation and analysis Watts Bar Nuclear Plant, Tennessee and Hanford Site, Richland, Washington

    SciTech Connect (OSTI)

    1997-07-01

    The U.S. Department of Energy (DOE) needs to confirm the viability of using a commercial light water reactor (CLWR) as a potential source for maintaining the nation`s supply of tritium. The Proposed Action discussed in this environmental assessment is a limited scale confirmatory test that would provide DOE with information needed to assess that option. This document contains the environmental assessment results for the Lead test assembly irradiation and analysis for the Watts Bar Nuclear Plant, Tennessee, and the Hanford Site in Richland, Washington.

  14. Radiolysis to knock-on damage transition in zeolites under electron beam irradiation

    SciTech Connect (OSTI)

    Ugurlu, O.; Haus, J.; Gunawan, A. A.; Maheshwari, S.; Tsapatsis, M.; Mkhoyan, K. A.; Thomas, M. G.

    2011-03-15

    The electron-beam-induced damage in a zeolite under 60-200 keV energy beam irradiation has both radiolitic and knock-on components and can be described by linear superposition of these two processes. Theoretical predictions supported by experiments at 60 keV suggest that for electron beam energies smaller than 70 keV, the damage to the specimen follows a radiolitic path. For energies larger than 200 keV, knock-on based sputtering of the material will dominate, while considerable radiolitic movement of the atoms will still be present.

  15. Evaluation of Clear Sky Models for Satellite-Based Irradiance Estimates

    SciTech Connect (OSTI)

    Sengupta, M.; Gotseff, P.

    2013-12-01

    This report describes an intercomparison of three popular broadband clear sky solar irradiance model results with measured data, as well as satellite-based model clear sky results compared to measured clear sky data. The authors conclude that one of the popular clear sky models (the Bird clear sky model developed by Richard Bird and Roland Hulstrom) could serve as a more accurate replacement for current satellite-model clear sky estimations. Additionally, the analysis of the model results with respect to model input parameters indicates that rather than climatological, annual, or monthly mean input data, higher-time-resolution input parameters improve the general clear sky model performance.

  16. Vacancy defects in as-grown and neutron irradiated GaP studied by positrons

    SciTech Connect (OSTI)

    Dlubek, G.; Bruemmer, O.; Polity, A.

    1986-08-18

    Positron lifetime and Doppler-broadening measurements have been used to study vacancy defects in n-italic-type GaP. Vacancies in the P sublattice with a concentration of some 10/sup 17/ cm/sup -3/ were observed in as-grwon GaP. The vacancies disappear during annealing at 500--800 /sup 0/C. In neutron-irradiated GaP positrons are trapped by Ga vacancies which anneal out in two stages situated at 300--550 /sup 0/C and 550--700 /sup 0/C.

  17. Actinide extraction from simulated and irradiated spent nuclear fuel using TBP solutions in HFC-134a

    SciTech Connect (OSTI)

    Shadrin, A.; Babain, V.; Kamachev, V.; Murzin, A.; Shafikov, D.; Dormidonova, A.

    2008-07-01

    It was demonstrated that solutions of TBP-nitric acid adduct in liquid Freon HFC-134a (1.2 MPa, 25 deg. C) allowed for recovery of uranium with nearly the same effectiveness as supercritical CO{sub 2} at 30 MPa. At nearly quantitative recovery of U and Pu, a DF of ca. 10 can be attained on dissolution and extraction of simulated SNF samples. The possibility of recovery of actinides contained in cakes produced by oxide conversion of simulated and irradiated SNF with solutions of TBP and DBE in Freon HFC-134a was shown. (authors)

  18. Extraction of protactinium-233 and separation from thermal neutron-irradiated thorium-232 using crown ethers

    SciTech Connect (OSTI)

    Jalhoom, Moayyed G.; Mohammed, Dawood A.; Khalaf, Jumah S.

    2008-07-01

    A new method was developed for the extraction and separation of {sup 233}Pa from thermal neutron-irradiated {sup 232}Th. Solutions of Pa{sup 233} were prepared in LiCI-HCl solutions from which appreciable extraction was obtained using dibenzo-18-crown-6 in 1,2-dichloroethane. The effects of cavity size, substitutions on the crown ring, type of the organic solvent, and temperature on extraction are discussed. Very high separation factors were obtained for the pairs {sup 233}Pa/{sup 232}Th (>105), {sup 233}Pa/{sup 233}U (> 1000), and {sup 232}U/{sup 232}Th (>60). (authors)

  19. Facility for fast neutron irradiation tests of electronics at the ISIS spallation neutron source

    SciTech Connect (OSTI)

    Andreani, C.; Pietropaolo, A.; Salsano, A.; Gorini, G.; Tardocchi, M.; Paccagnella, A.; Gerardin, S.; Frost, C. D.; Ansell, S.; Platt, S. P.

    2008-03-17

    The VESUVIO beam line at the ISIS spallation neutron source was set up for neutron irradiation tests in the neutron energy range above 10 MeV. The neutron flux and energy spectrum were shown, in benchmark activation measurements, to provide a neutron spectrum similar to the ambient one at sea level, but with an enhancement in intensity of a factor of 10{sup 7}. Such conditions are suitable for accelerated testing of electronic components, as was demonstrated here by measurements of soft error rates in recent technology field programable gate arrays.

  20. Synthesis and characterization of some metal oxide nanocrystals by microwave irradiation

    SciTech Connect (OSTI)

    Rashad, M.; Gaber, A.; Abdelrahim, M. A.; Abdel-Baset, A. M.; Moharram, A. H.

    2013-12-16

    Copper oxide and cobalt oxide (CuO, Co3O4) nanocrystals (NCs) have been successfully prepared in a short time using microwave irradiation. The resulted powders of nanocrystals (NCs) were characterized by X-ray diffraction (XRD) and transmission electron microscopy (TEM). Thermogravimetric analysis (TGA) measurements are also studied. Fourier-transform infrared (FT-IR) and UVvisible absorption spectroscopy of both kind of nanoparticels are illustrated. Optical absorption analysis indicated the direct band gap for both kinds of nanocrystals.

  1. Laboratory investigations of irradiated acetonitrile-containing ices on an interstellar dust analog

    SciTech Connect (OSTI)

    Abdulgalil, Ali G. M.; Marchione, Demian; Rosu-Finsen, Alexander; Collings, Mark P.; McCoustra, Martin R. S.

    2012-07-15

    Reflection-absorption infrared spectroscopy is used to study the impact of low-energy electron irradiation of acetonitrile-containing ices, under conditions close to those in the dense star-forming regions in the interstellar medium. Both the incident electron energy and the surface coverage were varied. The experiments reveal that solid acetonitrile is desorbed from its ultrathin solid films with a cross section of the order of 10{sup -17} cm{sup 2}. Evidence is presented for a significantly larger desorption cross section for acetonitrile molecules at the water-ice interface, similar to that previously observed for the benzene-water system.

  2. Heritable Genetic Changes in Cells Recovered From Irradiated 3D Tissue Constructs

    SciTech Connect (OSTI)

    Michael Cornforth

    2012-03-26

    Combining contemporary cytogenetic methods with DNA CGH microarray technology and chromosome flow-sorting increases substantially the ability to resolve exchange breakpoints associated with interstitial deletions and translocations, allowing the consequences of radiation damage to be directly measured at low doses, while also providing valuable insights into molecular mechanisms of misrepair processes that, in turn, identify appropriate biophysical models of risk at low doses. Specific aims apply to cells recovered from 3D tissue constructs of human skin and, for the purpose of comparison, the same cells irradiated in traditional 2D cultures. The project includes research complementary to NASA/HRP space radiation project.

  3. Performance of AGR-1 High-Temperature Reactor Fuel During Post-Irradiation Heating Tests

    SciTech Connect (OSTI)

    Morris, Robert Noel [ORNL; Baldwin, Charles A [ORNL; Hunn, John D [ORNL; Demkowicz, Paul [Idaho National Laboratory (INL); Reber, Edward [Idaho National Laboratory (INL)

    2014-01-01

    The fission product retention of irradiated low-enriched uranium oxide/uranium carbide TRISO fuel compacts from the AGR-1 experiment has been evaluated at temperatures of 1600 1800 C during post-irradiation safety tests. Fourteen compacts (a total of ~58,000 particles) with a burnup ranging from 13.4 to 19.1% FIMA have been tested using dedicated furnace systems at Idaho National Laboratory and Oak Ridge National Laboratory. The release of fission products 110mAg, 134Cs, 137Cs, 154Eu, 155Eu, 90Sr, and 85Kr was monitored while heating the fuel specimens in flowing helium. The behavior of silver, europium, and strontium appears to be dominated by inventory that was originally released through intact SiC coating layers during irradiation, but was retained in the compact at the end of irradiation and subsequently released during the safety tests. However, at a test temperature of 1800 C, the data suggest that release of these elements through intact coatings may become significant after ~100 h. Cesium was very well retained by intact SiC layers, with a fractional release <5 10-6 after 300 h at 1600 C or 100 h at 1800 C. However, it was rapidly released from individual particles if the SiC layer failed, and therefore the overall cesium release fraction was dominated by the SiC defect and failure fractions in the fuel compacts. No complete TRISO coating layer failures were observed after 300 h at 1600 or 1700 C, and 85Kr release was very low during the tests (particles with breached SiC, but intact outer pyrocarbon, retained most of their krypton). Krypton release from TRISO failures was only observed after ~210 h at 1800 C in one compact. Post-safety-test examination of fuel compacts and particles has focused on identifying specific particles from each compact with notable fission product release and detailed analysis of the coating layers to understand particle behavior.

  4. AGR-1 Fuel Compact 6-3-2 Post-Irradiation Examination Results

    SciTech Connect (OSTI)

    Paul demkowicz; jason Harp; Scott Ploger

    2012-12-01

    Destructive post-irradiation examination was performed on fuel Compact 6-3-2, which was irradiated in the AGR-1 experiment to a final compact average burnup of 11.3% FIMA and a time-average, volume-average temperature of 1070C. The analysis of this compact was focused on characterizing the extent of fission product release from the particles and examining particles to determine the condition of the kernels and coating layers. The work included deconsolidation of the compact and leach-burn-leach analysis, visual inspection and gamma counting of individual particles, measurement of fuel burnup by several methods, metallurgical preparation of selected particles, and examination of particle cross-sections with optical microscopy. A single particle with a defective SiC layer was identified during deconsolidation-leach-burn-leach analysis, which is in agreement with previous measurements showing elevated cesium in the Capsule 6 graphite fuel holder associated with this fuel compact. The fraction of the compact europium inventory released from the particles and retained in the matrix was relatively high (approximately 6E-3), indicating release from intact particle coatings. The Ag-110m inventory in individual particles exhibited a very broad distribution, with some particles retaining =80% of the predicted inventory and others retaining less than 25%. The average degree of Ag-110m retention in 60 gamma counted particles was approximately 50%. This elevated silver release is in agreement with analysis of silver on the Capsule 6 components, which indicated an average release of 38% of the Capsule 6 inventory from the fuel compacts. In spite of the relatively high degree of silver release from the particles, virtually none of the Ag-110m released was found in the compact matrix, and presumably migrated out of the compact and was deposited on the irradiation capsule components. Release of all other fission products from the particles appears to be less than a single particle equivalent inventory. Burnup measurements based on gamma spectrometry of individual particles and mass spectrometry of dissolved fuel kernels were in very good agreement (11.0% and 10.9% FIMA, respectively), and were also in good agreement with measurements based on previous gamma spectrometry measurements of the whole compact (11.0% FIMA) and the predicted burnup based on physics simulations of the AGR-1 irradiation (11.3% FIMA).

  5. Theory of suppressing avalanche process of carrier in short pulse laser irradiated dielectrics

    SciTech Connect (OSTI)

    Deng, Hongxiang; Zu, Xiaotao; Zheng, WG; Yuan, XD; Xiang, Xia; Sun, Kai; Gao, Fei

    2014-05-28

    A theory for controlling avalanche process of carrier during short pulse laser irradiation is proposed. We show that avalanche process of conduction band electrons (CBEs) is determined by the occupation number of phonons in dielectrics. The theory provides a way to suppress avalanche process and a direct judgment for the contribution of avalanche process and photon ionization process to the generation of CBEs. The obtained temperature dependent rate equation shows that the laser induced damage threshold of dielectrics, e.g., fused silica, increase nonlinearly with the decreases of temperature. Present theory predicts a new approach to improve the laser induced damage threshold of dielectrics.

  6. Public information circular for shipments of irradiated reactor fuel. Revision 9

    SciTech Connect (OSTI)

    Not Available

    1993-03-01

    This circular has been prepared to provide information on the shipment of irradiated reactor fuel (spent fuel) subject to regulation by the Nuclear Regulatory Commission (NRC), and to meet the requirements of Public Law 96--295. The report provides a brief description of NRC authority for certain aspects of transporting spent fuel. It provides descriptive statistics on spent fuel shipments regulated by the NRC from 1979 to 1992. It also lists detailed highway and railway segments used within each state from October 1, 1987 through December 31, 1992.

  7. LABORATORY STUDIES ON THE IRRADIATION OF SOLID ETHANE ANALOG ICES AND IMPLICATIONS TO TITAN'S CHEMISTRY

    SciTech Connect (OSTI)

    Kim, Y. S.; Bennett, C. J.; Chen, L-H; Kaiser, R. I.; O'Brien, K.

    2010-03-10

    Pure ethane ices (C{sub 2}H{sub 6}) were irradiated at 10, 30, and 50 K under contamination-free, ultrahigh vacuum conditions with energetic electrons generated in the track of galactic cosmic-ray (GCR) particles to simulate the interaction of GCRs with ethane ices in the outer solar system. The chemical processing of the samples was monitored by a Fourier transform infrared spectrometer and a quadrupole mass spectrometer during the irradiation phase and subsequent warm-up phases on line and in situ in order to extract qualitative (products) and quantitative (rate constants and yields) information on the newly synthesized molecules. Six hydrocarbons, methane (CH{sub 4}), acetylene (C{sub 2}H{sub 2}), ethylene (C{sub 2}H{sub 4}), and the ethyl radical (C{sub 2}H{sub 5}), together with n-butane (C{sub 4}H{sub 10}) and butene (C{sub 4}H{sub 8}), were found to form at the radiation dose reaching 1.4 eV per molecule. The column densities of these species were quantified in the irradiated ices at each temperature, permitting us to elucidate the temperature and phase-dependent production rates of individual molecules. A kinetic reaction scheme was developed to fit column densities of those species produced during irradiation of amorphous/crystalline ethane held at 10, 30, or 50 K. In general, the yield of the newly formed molecules dropped consistently for all species as the temperature was raised from 10 K to 50 K. Second, the yield in the amorphous samples was found to be systematically higher than in the crystalline samples at constant temperature. A closer look at the branching ratios indicates that ethane decomposes predominantly to ethylene and molecular hydrogen, which may compete with the formation of n-butane inside the ethane matrix. Among the higher molecular products, n-butane dominates. Of particular relevance to the atmosphere of Saturn's moon Titan is the radiation-induced methane production from ethane-an alternative source of replenishing methane into the atmosphere. Finally, we discuss to what extent the n-butane could be the source of ''higher organics'' on Titan's surface thus resembling a crucial sink of condensed ethane molecules.

  8. Swelling in several commercial alloys irradiated to very high neutron fluence

    SciTech Connect (OSTI)

    Gelles, D.S.; Pintler, J.S.

    1983-01-01

    Swelling values have been obtained from a set of commercial alloys irradiated in EBR-II to a peak fluence of 2.5 x 10/sup 23/ n/cm/sup 2/ (E > 0.1 MeV) or approx. 125 dpa covering the range 400 to 650/sup 0/C. The alloys can be ranked for swelling resistance from highest to lowest as follows: the martensitic and ferritic alloys, the niobium based alloys, the precipitation strengthened iron and nickel based alloys, the molybdenum alloys and the austenitic alloys.

  9. Determination of Uranium Metal Concentration in Irradiated Fuel Storage Basin Sludge Using Selective Dissolution

    SciTech Connect (OSTI)

    Delegard, Calvin H.; Sinkov, Sergey I.; Chenault, Jeffrey W.; Schmidt, Andrew J.; Welsh, Terri L.; Pool, Karl N.

    2014-03-01

    Uranium metal corroding in water-saturated sludges now held in the US Department of Energy Hanford Site K West irradiated fuel storage basin can create hazardous hydrogen atmospheres during handling, immobilization, or subsequent transport and storage. Knowledge of uranium metal concentration in sludge thus is essential to safe sludge management and process design, requiring an expeditious routine analytical method to detect uranium metal concentrations as low as 0.03 wt% in sludge even in the presence of 30 wt% or higher total uranium concentrations.

  10. Internal stress distribution for generating closure domains in laser-irradiated Fe3%Si(110) steels

    SciTech Connect (OSTI)

    Iwata, Keiji; Imafuku, Muneyuki; Orihara, Hideto; Sakai, Yusuke; Ohya, Shin-Ichi; Suzuki, Tamaki; Shobu, Takahisa; Akita, Koichi; Ishiyama, Kazushi

    2015-05-07

    Internal stress distribution for generating closure domains occurring in laser-irradiated Fe3%Si(110) steels was investigated using high-energy X-ray analysis and domain theory based on the variational principle. The measured triaxial stresses inside the specimen were compressive and the stress in the rolling direction became more dominant than stresses in the other directions. The calculations based on the variational principle of magnetic energy for closure domains showed that the measured triaxial stresses made the closure domains more stable than the basic domain without closure domains. The experimental and calculation results reveal that the laser-introduced internal stresses result in the occurrence of the closure domains.

  11. Alloy development for irradiation performance. Quarterly progress report for period ending June 30, 1980

    SciTech Connect (OSTI)

    Ashdown, B.G.

    1980-10-01

    This report is organized along topical lines in parallel to a Program Plan of the same title so that activities and accomplishments may be followed readily relative to that Program Plan. Thus, the work of a given laboratory may appear throughout the report. Chapters 1, 2, 8, and 9 review activities on analysis and evaluation, test methods development, status of irradiation experiments, and corrosion testing and hydrogen permeation studies, respectively. These activities relate to each of the alloy development paths. Chapters 3, 4, 5, 6, and 7 present the ongoing work on each alloy development path. The Table of Contents is annotated for the convenience of the reader.

  12. Long-Term Effects of {sup 56}Fe Irradiation on Spatial Memory of Mice: Role of Sex and Apolipoprotein E Isoform

    SciTech Connect (OSTI)

    Villasana, Laura E.; Benice, Theodore S. [Department of Behavioral Neuroscience, Oregon Health and Science University, Portland, Oregon (United States); Raber, Jacob, E-mail: raberj@ohsu.ed [Department of Behavioral Neuroscience, Oregon Health and Science University, Portland, Oregon (United States); Department of Neurology, Oregon Health and Science University, Portland, Oregon (United States); Division of Neuroscience, Oregon Primate Research Center, Oregon Health and Science University, Portland, OR (United States)

    2011-06-01

    Purpose: To assess whether the effects of cranial {sup 56}Fe irradiation on the spatial memory of mice in the water maze are sex and apolipoprotein E (apoE) isoform dependent and whether radiation-induced changes in spatial memory are associated with changes in the dendritic marker microtubule-associated protein 2 (MAP-2) and the presynaptic marker synaptophysin. Methods and Materials: Two-month-old male and female mice expressing human apoE3 or apoE4 received either a 3-Gy dose of cranial {sup 56}Fe irradiation (600 MeV/amu) or sham irradiation. Mice were tested in a water maze task 13 months later to assess effects of irradiation on spatial memory retention. After behavioral testing, the brain tissues of these mice were analyzed for synaptophysin and MAP-2 immunoreactivity. Results: After irradiation, spatial memory retention of apoE3 female, but not male, mice was impaired. A general genotype deficit in spatial memory was observed in sham-irradiated apoE4 mice. Strikingly, irradiation prevented this genotype deficit in apoE4 male mice. A similar but nonsignificant trend was observed in apoE4 female mice. Although there was no change in MAP-2 immunoreactivity after irradiation, synaptophysin immunoreactivity was increased in irradiated female mice, independent of genotype. Conclusions: The effects of {sup 56}Fe irradiation on the spatial memory retention of mice are critically influenced by sex, and the direction of these effects is influenced by apoE isoform. Although in female mice synaptophysin immunoreactivity provides a sensitive marker for effects of irradiation, it cannot explain the apoE genotype-dependent effects of irradiation on the spatial memory retention of the mice.

  13. Absolute Cavity Pyrgeometer to Measure the Absolute Outdoor Longwave Irradiance with Traceability to International System of Units, SI

    SciTech Connect (OSTI)

    Reda, I.; Zeng, J.; Scheuch, J.; Hanssen, L.; Wilthan, B.; Myers, D.; Stoffel, T.

    2012-03-01

    This article describes a method of measuring the absolute outdoor longwave irradiance using an absolute cavity pyrgeometer (ACP), U.S. Patent application no. 13/049, 275. The ACP consists of domeless thermopile pyrgeometer, gold-plated concentrator, temperature controller, and data acquisition. The dome was removed from the pyrgeometer to remove errors associated with dome transmittance and the dome correction factor. To avoid thermal convection and wind effect errors resulting from using a domeless thermopile, the gold-plated concentrator was placed above the thermopile. The concentrator is a dual compound parabolic concentrator (CPC) with 180{sup o} view angle to measure the outdoor incoming longwave irradiance from the atmosphere. The incoming irradiance is reflected from the specular gold surface of the CPC and concentrated on the 11 mm diameter of the pyrgeometer's blackened thermopile. The CPC's interior surface design and the resulting cavitation result in a throughput value that was characterized by the National Institute of Standards and Technology. The ACP was installed horizontally outdoor on an aluminum plate connected to the temperature controller to control the pyrgeometer's case temperature. The responsivity of the pyrgeometer's thermopile detector was determined by lowering the case temperature and calculating the rate of change of the thermopile output voltage versus the changing net irradiance. The responsivity is then used to calculate the absolute atmospheric longwave irradiance with an uncertainty estimate (U{sub 95}) of {+-}3.96 W m{sup 02} with traceability to the International System of Units, SI. The measured irradiance was compared with the irradiance measured by two pyrgeometers calibrated by the World Radiation Center with traceability to the Interim World Infrared Standard Group, WISG. A total of 408 readings were collected over three different nights. The calculated irradiance measured by the ACP was 1.5 W/m{sup 2} lower than that measured by the two pyrgeometers that are traceable to WISG, with a standard deviation of {+-}0.7 W m{sup -2}. These results suggest that the ACP design might be used for addressing the need to improve the international reference for broadband outdoor longwave irradiance measurements.

  14. In situ measurements of a homogeneous to heterogeneous transition in the plastic response of ion-irradiated Ni microspecimens

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhao, Xinyu; Strickland, Daniel J.; Derlet, Peter M.; He, Mo-rigen; Cheng, You -Jung; Pu, Jue; Stanford Univ., Stanford, CA; Hattar, Khalid; Gianola, Daniel S.

    2015-02-11

    We report on the use of quantitative in situ microcompression experiments in a scanning electron microscope to systematically investigate the effect of self-ion irradiation damage on the full plastic response of Ni. In addition to the well-known irradiationinduced increases in the yield and flow strengths with increasing dose, we measure substantial changes in plastic flow intermittency behavior, manifested as stress drops accompanying energy releases as the driven material transits critical states. At low irradiation doses, the magnitude of stress drops reduces relative to the unirradiated material and plastic slip proceeds on multiple slip systems, leading to quasi-homogeneous plastic flow.more »In contrast, highly irradiated specimens exhibit pronounced shear localization on parallel slip planes, which we ascribe to the onset of defect free channels normally seen in bulk irradiated materials. Our in situ testing system and approach allows for a quantitative study of the energy release and dynamics associated with defect free channel formation and subsequent localization. As a result, this study provides fundamental insight to the nature of interactions between mobile dislocations and irradiation-mediated and damage-dependent defect structures.« less

  15. In situ measurements of a homogeneous to heterogeneous transition in the plastic response of ion-irradiated <111> Ni microspecimens

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhao, Xinyu; Strickland, Daniel J.; Derlet, Peter M.; He, Mo-rigen; Cheng, You -Jung; Pu, Jue; Stanford Univ., Stanford, CA; Hattar, Khalid; Gianola, Daniel S.

    2015-02-11

    We report on the use of quantitative in situ microcompression experiments in a scanning electron microscope to systematically investigate the effect of self-ion irradiation damage on the full plastic response of <111> Ni. In addition to the well-known irradiationinduced increases in the yield and flow strengths with increasing dose, we measure substantial changes in plastic flow intermittency behavior, manifested as stress drops accompanying energy releases as the driven material transits critical states. At low irradiation doses, the magnitude of stress drops reduces relative to the unirradiated material and plastic slip proceeds on multiple slip systems, leading to quasi-homogeneous plastic flow.more » In contrast, highly irradiated specimens exhibit pronounced shear localization on parallel slip planes, which we ascribe to the onset of defect free channels normally seen in bulk irradiated materials. Our in situ testing system and approach allows for a quantitative study of the energy release and dynamics associated with defect free channel formation and subsequent localization. As a result, this study provides fundamental insight to the nature of interactions between mobile dislocations and irradiation-mediated and damage-dependent defect structures.« less

  16. Charpy toughness and tensile properties of a neutron irradiated stainless steel submerged-arc weld cladding overlay

    SciTech Connect (OSTI)

    Corwin, W.R.; Berggren, R.G.; Nanstad, R.K.

    1984-01-01

    The possibility of stainless steel cladding increasing the resistance of an operating nuclear reactor pressure vessel to extension of surface flaws is highly dependent upon the irradiated properties of the cladding. Therefore, weld overlay cladding irradiated at temperatures and fluences relevant to power reactor operation was examined. The cladding was applied to a pressure vessel steel plate by the submerged-arc, single-wire, oscillating electrode method. Three layers of cladding were applied to provide a cladding thickness adequate for fabrication of test specimens. The first layer was type 309, and the upper two layers were type 308 stainless steel. There was considerable dilution of the type 309 in the first layer of cladding as a result of excessive melting of the base plate. Specimens for the irradiation study were taken from near the base plate/cladding interface and also from the upper layers of cladding. Charpy V-notch and tensile specimens were irradiated at 288/sup 0/C to neutron fluences of 2 x 10/sup 23/ n/m/sup 2/ (E > 1 MeV). When irradiated, both types 308 and 309 cladding showed a 5 to 40% increase in yield strength accompanied by a slight increase in ductility in the temperature range from 25 to 288/sup 0/C. All cladding exhibited ductile-to-brittle transition behavior during impact testing.

  17. Evaluation of ferritic alloy Fe-2-1/4Cr-1Mo after neutron irradiation - microstructure development

    SciTech Connect (OSTI)

    Gelles, D.S.

    1984-05-01

    Microstructural examinations are reported for nine specimen conditions of 2-1/4Cr-1Mo steel which had been irradiated by fast neutrons over the temperature range 390 to 510/sup 0/C. Two heats of material were involved, each with a different preirradiation heat treatment, one irradiated to a peak fluence of 5.1 x 10/sup 22/ n/cm/sup 2/ (E > 0.1 MeV) or 24 dpa and the other to 2.4 x 10/sup 23/ n/cm/sup 2/ (E > 0.1 MeV) or 116 dpa. Void swelling is found following irradiation at 400/sup 0/C in both conditions and to 480/sup 0/C in the higher fluence conditions. Concurrently dislocation structure and precipitation formed. Peak void swelling, void density, dislocation density and precipitate number density developed at the lowest temperature, approx. 400/sup 0/C, whereas mean void size, and mean precipitate size increased with increasing irradiation temperature. The examination results are used to provide interpretation of in-reactor creep, density change and post irradiation tensile behavior.

  18. High dose neutron irradiation of Hi-Nicalon Type S silicon carbide composites, Part 1: Microstructural evaluations

    SciTech Connect (OSTI)

    Perez-Bergquist, Alex G; Nozawa, Takashi; Shih, Chunghao Phillip; Leonard, Keith J; Snead, Lance Lewis; Katoh, Yutai

    2015-01-01

    Over the past decade, significant progress has been made in the development of silicon carbide (SiC) composites, composed of near-stoichiometric SiC fibers embedded in a crystalline SiC matrix, to the point that such materials can now be considered nuclear grade. Recent neutron irradiation studies of Hi-Nicalon Type S SiC composites showed excellent radiation response at damage levels of 30 40 dpa at temperatures of 300 800 C. However, more recent studies of these same fiber composites irradiated to damage levels of >70 dpa at similar temperatures showed a marked decrease in ultimate flexural strength, particularly at 300 C. Here, electron microscopy is used to analyze the microstructural evolution of these irradiated composites in order to investigate the cause of the degradation. While minimal changes were observed in Hi-Nicalon Type S SiC composites irradiated at 800 C, substantial microstructural evolution is observed in those irradiated at 300 C. Specifically, carbonaceous particles in the fibers grew by 25% compared to the virgin case, and severe cracking occurred at interphase layers.

  19. Formation of voids and secondary-phase precipitates in the Fe-16Cr-15Ni-2Mo-1Mn-Ti-Si steel under high-doze neutron irradiation and during post-irradiation annealing

    SciTech Connect (OSTI)

    Portnykh, I. A. Kozlov, A. V.; Shcherbakov, E. N.; Asiptsov, O. I.

    2009-12-15

    The effect of high-dose neutron irradiation on the structural changes in Fe-16Cr-15Ni-2Mo-1Mn-Ti-Si austenitic steel have been investigated. Samples irradiated at temperatures of 390, 500, and 600{sup o} to damage doses of 46, 86, and 46 dpa, respectively, were analyzed by electron microscopy and dilatometry. The quantitative characteristics of radiation voids and secondary-phase precipitates formed under neutron irradiation are obtained. Their behavior upon heating to 700{sup o}C and annealing at this temperature for 2 h is studied. It is shown that annealing leads to the dissociation of small voids, which is accompanied by the growth of large ones. The secondary-phase precipitates are partially dissolved upon annealing, and their volume fraction decreases.

  20. Controlled synthesis of snowflake-like self-assemblies palladium nanostructures under microwave irradiation

    SciTech Connect (OSTI)

    Xie, Ting; Ma, Yue; Yang, Hanmin Li, Jinlin

    2013-08-01

    Graphical abstract: - Highlights: We demonstrated the synthesis of snowflake-like palladium nanostructures for the first time. We discussed the influencing factors on the synthesis of snowflake-like Pd nanostructures. The molar ratio of H{sub 2}Pd{sub 4} to PVP at 5 is the optimal selection. The growth process was discussed. - Abstract: Self-assembly snowflake-like palladium nanostructures were synthesized under microwave irradiation using H{sub 2}PdCl{sub 4} as precursor, benzyl alcohol as both solvent and reducing agent, and PVP as stabilizer. The Pd snowflake-like nanostructures were formed and then characterized by transmission electron microscopy (TEM) and X-ray powder diffraction. The TEM images showed that the Pd nano-snowflakes were self-assemblies organized by hundreds of small spherical nanoparticles. Pd snowflake-like nanostructures with well-defined shape and uniform size can be obtained by tuning the concentration of palladium precursor, the molar ratio of H{sub 2}PdCl{sub 4}/PVP, as well as the heating time by microwave irradiation. The possible growing process of the snowflake-like Pd structures was also proposed on the basis of investigating the properties of as-synthesized Pd nanostructures under different conditions.