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Sample records for ir mt ni

  1. Carbon-Supported IrNi Core-Shell Nanoparticles: Synthesis Characterization and Catalytic Activity

    SciTech Connect (OSTI)

    K Sasaki; K Kuttiyiel; L Barrio; D Su; A Frenkel; N Marinkovic; D Mahajan; R Adzic

    2011-12-31

    We synthesized carbon-supported IrNi core-shell nanoparticles by chemical reduction and subsequent thermal annealing in H{sub 2}, and verified the formation of Ir shells on IrNi solid solution alloy cores by various experimental methods. The EXAFS analysis is consistent with the model wherein the IrNi nanoparticles are composed of two-layer Ir shells and IrNi alloy cores. In situ XAS revealed that the Ir shells completely protect Ni atoms in the cores from oxidation or dissolution in an acid electrolyte under elevated potentials. The formation of Ir shell during annealing due to thermal segregation is monitored by time-resolved synchrotron XRD measurements, coupled with Rietveld refinement analyses. The H{sub 2} oxidation activity of the IrNi nanoparticles was found to be higher than that of a commercial Pt/C catalyst. This is predominantly due to Ni-core-induced Ir shell contraction that makes the surface less reactive for IrOH formation, and the resulting more metallic Ir surface becomes more active for H{sub 2} oxidation. This new class of core-shell nanoparticles appears promising for application as hydrogen anode fuel cell electrocatalysts.

  2. The role of the (111) texture on the exchange bias and interlayer coupling effects observed in sputtered NiFe/IrMn/Co trilayers

    SciTech Connect (OSTI)

    Castro, I. L.; Nascimento, V. P.; Passamani, E. C.; Takeuchi, A. Y.; Larica, C.; Tafur, M.; Pelegrini, F.

    2013-05-28

    Magnetic properties of sputtered NiFe/IrMn/Co trilayers grown on different seed layers (Cu or Ta) deposited on Si (100) substrates were investigated by magnetometry and ferromagnetic resonance measurements. Exchange bias effect and magnetic spring behavior have been studied by changing the IrMn thickness. As shown by X-ray diffraction, Ta and Cu seed layers provoke different degrees of (111) fcc-texture that directly affect the exchange bias and indirectly modify the exchange spring coupling behavior. Increasing the IrMn thickness, it was observed that the coupling angle between the Co and NiFe ferromagnetic layers increases for the Cu seed system, but it reduces for the Ta case. The results were explained considering (i) different anisotropies of the Co and IrMn layers induced by the different degree of the (111) texture and (ii) the distinct exchange bias set at the NiFe/IrMn and IrMn/Co interfaces in both systems. The NiFe and Co interlayer coupling angle is strongly correlated with both exchange bias and exchange magnetic spring phenomena. It was also shown that the highest exchange bias field occurs when an unstressed L1{sub 2} IrMn structure is stabilized.

  3. Magnetic order in the frustrated Ising-like chain compound Sr3NiIrO6 E. Lefranois,1, 2, 3,

    E-Print Network [OSTI]

    Boyer, Edmond

    in CsCoCl3 for instance3 . The most studied compound in the frustrated regime is Ca3Co2O6 because of its show that Ca3CoRhO6 5 , Sr3CoIrO6 6 , Sr3NiRhO6 7 and Sr3NiIrO6 6,8,9 have a similar behavior to Ca3Co2 of their unconventional magnetic properties due to the interplay between low dimensionality, magnetic frustration

  4. Mixing antiferromagnets to tune NiFe-[IrMn/FeMn] interfacial spin-glasses, grains thermal stability, and related exchange bias properties

    SciTech Connect (OSTI)

    Akmaldinov, K.; Ducruet, C.; Portemont, C.; Joumard, I.; Prejbeanu, I. L.; Dieny, B.; Baltz, V.

    2014-05-07

    Spintronics devices and in particular thermally assisted magnetic random access memories require a wide range of ferromagnetic/antiferromagnetic (F/AF) exchange bias (EB) properties and subsequently of AF materials to fulfil diverse functionality requirements for the reference and storage. For the reference layer, large EB energies and high blocking temperature (T{sub B}) are required. In contrast, for the storage layer, mostly moderate T{sub B} are needed. One of the present issues is to find a storage layer with properties intermediate between those of IrMn and FeMn and in particular: (i) with a T{sub B} larger than FeMn for better stability at rest-T but lower than IrMn to reduce power consumption at write-T and (ii) with improved magnetic interfacial quality, i.e., with reduced interfacial glassy character for lower properties dispersions. To address this issue, the EB properties of F/AF based stacks were studied for various mixed [IrMn/FeMn] AFs. In addition to EB loop shifts, the F/AF magnetic interfacial qualities and the AF grains thermal stability are probed via measurements of the low- and high-temperature contributions to the T{sub B} distributions, respectively. A tuning of the above three parameters is observed when evolving from IrMn to FeMn via [IrMn/FeMn] repetitions.

  5. Saving Mt. Fuji

    E-Print Network [OSTI]

    Hacker, Randi

    2013-09-12

    Broadcast Transcript: Mt. Fuji, or Fujisan is it is known here in Japan, has just been added to Unesco's World Heritage list as a cultural asset, honoring it for providing thousands of years of inspiration to artists, poets ...

  6. Pipeline MT Instructions Identification Number

    E-Print Network [OSTI]

    Hong, Don

    Pipeline MT Instructions Identification Number For identification purposes, you will be assigned a special identification number. M# You can activate your MT email, login to PipelineMT to register for classes or pay tuition and fees. Activating the MTSU Email and PipelineMT accounts: Visit the website

  7. Photosensitivity of the Ni-A state of [NiFe] hydrogenase from Desulfovibrio vulgaris Miyazaki F with visible light

    SciTech Connect (OSTI)

    Osuka, Hisao; Graduate School of Materials Science, Nara Institute of Science and Technology, 8916-5, Takayama-cho, Ikoma-shi, Nara 630-0192 ; Shomura, Yasuhito; Komori, Hirofumi; Shibata, Naoki; Nagao, Satoshi; Higuchi, Yoshiki; CREST, JST, Gobancho, Chiyoda-ku, Tokyo 102-0076 ; Hirota, Shun; CREST, JST, Gobancho, Chiyoda-ku, Tokyo 102-0076

    2013-01-04

    Highlights: Black-Right-Pointing-Pointer Ni-A state of [NiFe] hydrogenase showed light sensitivity. Black-Right-Pointing-Pointer New FT-IR bands were observed with light irradiation of the Ni-A state. Black-Right-Pointing-Pointer EPR g-values of the Ni-A state shifted upon light irradiation. Black-Right-Pointing-Pointer The light-induced state converted back to the Ni-A state under the dark condition. -- Abstract: [NiFe] hydrogenase catalyzes reversible oxidation of molecular hydrogen. Its active site is constructed of a hetero dinuclear Ni-Fe complex, and the oxidation state of the Ni ion changes according to the redox state of the enzyme. We found that the Ni-A state (an inactive unready, oxidized state) of [NiFe] hydrogenase from Desulfovibrio vulgaris Miyazaki F (DvMF) is light sensitive and forms a new state (Ni-AL) with irradiation of visible light. The Fourier transform infrared (FT-IR) bands at 1956, 2084 and 2094 cm{sup -1} of the Ni-A state shifted to 1971, 2086 and 2098 cm{sup -1} in the Ni-AL state. The g-values of g{sub x} = 2.30, g{sub y} = 2.23 and g{sub z} = 2.01 for the signals in the electron paramagnetic resonance (EPR) spectrum of the Ni-A state at room temperature varied for -0.009, +0.012 and +0.010, respectively, upon light irradiation. The light-induced Ni-AL state converted back immediately to the Ni-A state under dark condition at room temperature. These results show that the coordination structure of the Fe site of the Ni-A state of [NiFe] hydrogenase is perturbed significantly by light irradiation with relatively small coordination change at the Ni site.

  8. Mt. Baker Geothermal Project | Open Energy Information

    Open Energy Info (EERE)

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  9. Mt Rainier Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History ViewMayo, Maryland: EnergyInformationOliver, Pennsylvania:(CTI PFAN) | Open Energy(RECP)MtMt

  10. IR Kuiper Belt Constraints

    E-Print Network [OSTI]

    Teplitz, V L; Anderson, J D; Rosenbaum, D C; Scalise, R J; Wentzler, P; Teplitz, Vigdor L.; Anderson, John D.; Rosenbaum, Doris; Scalise, Randall J.; Wentzler, Paul

    1999-01-01

    We compute the temperature and IR signal of particles of radius $a$ and albedo $\\alpha$ at heliocentric distance $R$, taking into account the emissivity effect, and give an interpolating formula for the result. We compare with analyses of COBE DIRBE data by others (including recent detection of the cosmic IR background) for various values of heliocentric distance, $R$, particle radius, $a$, and particle albedo, $\\alpha$. We then apply these results to a recently-developed picture of the Kuiper belt as a two-sector disk with a nearby, low-density sector (40IR spectra for various parameter v...

  11. Developing Mt. Hope: The megawatt line

    SciTech Connect (OSTI)

    Rodzianko, P.; Fisher, F.S.

    1992-12-01

    After facing numerous obstacles, including opposition and competition, the Mt. Hope pumped-storage project in New Jersey has been licensed by FERC. That license will allow a former iron ore mine site to be used in producing a new resource-hydroelectricity. In early August 1992, after more than seven years of effort, the 2,000-MW Mt. Hope Waterpower Project was licensed by the Federal Energy Regulatory Commission (FERC). Getting the $1.8 billion pumped-storage project licensed was not an easy task. It involved 54 submittals to FERC, six public meetings, and costs of more than $12 million. Along the way, the project has withstood competing applications, community opposition, and legal battles. Getting a project of this magnitude off the ground is a challenge for even the most experienced developer. The effort was especially challenging for the Halecrest Company, a local family-owned and operated firm with no previous experience in hydroelectric development. When financing became tight, creative ways were found to raise seed capital for the project. When hydroelectric experience was needed, the company developed a world-class corporate team that carried Mt. Hope through the complexities of the licensing process and beyond. With license now in hand, the project developers are ready to move forward with negotiating power sales contracts and securing construction financing. The resulting project will be the second largest pumped-storage facility in the country-second only to the 2,100-MW Bath County project in Virginia. Mt. Hope will take six years to construct and is scheduled to be phased into operation beginning in 1999.

  12. Mt Rainier Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

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  13. Mt Wheeler Power, Inc | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoop Inc Jump to: navigation,Mereg GmbHMontebalitoMt Princeton Hot Springs

  14. Marysville Mt Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIXsource HistoryScenariosMarysville Mt Geothermal Area Jump to: navigation, search

  15. Mt Signal Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIXsourceII Jump to: navigation, searchsource HistoryCharleston,Peak Utility Jump to:PosoMt

  16. Water Sampling At Mt Princeton Hot Springs Geothermal Area (Olson...

    Open Energy Info (EERE)

    Water Sampling At Mt Princeton Hot Springs Geothermal Area (Olson & Dellechaie, 1976) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Water...

  17. Refraction Survey At Mt Princeton Hot Springs Geothermal Area...

    Open Energy Info (EERE)

    Refraction Survey At Mt Princeton Hot Springs Geothermal Area (Lamb, Et Al., 2012) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Refraction...

  18. 3D Mt Resistivity Imaging For Geothermal Resource Assessment...

    Open Energy Info (EERE)

    3D Mt Resistivity Imaging For Geothermal Resource Assessment And Environmental Mitigation At The Glass Mountain Kgra, California Jump to: navigation, search OpenEI Reference...

  19. Vertical Electrical Sounding Configurations At Mt Princeton Hot...

    Open Energy Info (EERE)

    Vertical Electrical Sounding Configurations At Mt Princeton Hot Springs Geothermal Area (Zohdy, Et Al., 1971) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home...

  20. Direct-Current Resistivity Survey At Mt Princeton Hot Springs...

    Open Energy Info (EERE)

    Direct-Current Resistivity Survey At Mt Princeton Hot Springs Area (Richards, Et Al., 2010) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity:...

  1. Geothermometry At Mt Princeton Hot Springs Geothermal Area (Pearl...

    Open Energy Info (EERE)

    Et Al., 1976) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Geothermometry At Mt Princeton Hot Springs Geothermal Area (Pearl, Et Al., 1976)...

  2. Ni Ni: University of California - Los Angeles

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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  3. MT3DMS v5.3 Supplemental User's Guide

    E-Print Network [OSTI]

    Zheng, Chunmiao

    published by the U.S. Army Corps of Engineers (Zheng and Wang, 1999; available at http://hydro.geo.ua.edu/mt3d). Readers should refer to Zheng and Wang (1999) for complete information on the theoretical Tonkin, Henning Prommer, Chris Langevin, Ned Banta, Eileen Poeter, and Rui Ma in various aspects of MT3

  4. MOBILE INTERACTIVE VISITOR INFORMATION SERVICE: PUKAHA MT. BRUCE TRIAL RESULTS

    E-Print Network [OSTI]

    Zealand Tourism Research Institute Sept 2005 #12;New Zealand Tourism Research Institute September 2005 www Information Service (MIVIS) mobile phones to access audio information at Pukaha Mt Bruce (PMB) were collected and range of visitors using the MIVIS phones in the Pukaha Mt Bruce setting. #12;New Zealand Tourism

  5. WPA Omnibus Award MT Wind Power Outreach

    SciTech Connect (OSTI)

    Brian Spangler, Manager Energy Planning and Renewables

    2012-01-30

    The objective of this grant was to further the development of Montanaâ??s vast wind resources for small, medium, and large scale benefits to Montana and the nation. This was accomplished through collaborative work with wind industry representatives, state and local governments, the agricultural community, and interested citizens. Through these efforts MT Dept Environmental Quality (DEQ) was able to identify development barriers, educate and inform citizens, as well as to participate in regional and national dialogue that will spur the development of wind resources. The scope of DEQâ??s wind outreach effort evolved over the course of this agreement from the development of the Montana Wind Working Group and traditional outreach efforts, to the current focus on working with the stateâ??s university system to deliver a workforce trained to enter the wind industry.

  6. Chi tit mn hc mt bn kia.

    E-Print Network [OSTI]

    California at Davis, University of

    v xã hi, ý n môi trng và sáng to. "Th ô xe p ca Hoa K," Davis là mt cng ng a dng và nng ng chào ón, Phát �m và Nghe Trong Lãnh Vc Hc Tp, và các lãnh vc khác. Ngoài ra cng có nhiu c hi tham gia các t chc ti trng và phc v cng ng. Mun bit ngày tháng, hc phí và các chi tit khác, hãy n: www

  7. IRS-Impersonation SCAMS IRS-Impersonation Telephone Scam

    E-Print Network [OSTI]

    Dennett, Daniel

    making the rounds throughout the country. Callers claim to be employees of the IRS, but are not directory (http://whitepages.tufts.edu) as the fraudulent caller appears to be obtaining mobile phone numbers from this directory. This may help reduce your exposure to telephone scams and other unwanted

  8. Introduction: Bencubbin-like meteorites (CB) are metal-rich chondritic breccias containing about 60 vol% metallic (Fe,Ni) [1]. Unlike the CBa (Becubbin, Weatherford,

    E-Print Network [OSTI]

    vol% metallic (Fe,Ni) [1]. Unlike the CBa (Becubbin, Weatherford, Gujba) subgroup, the CBb (HH 237 al. [4] found that the Ir/Fe, Pd/Fe and Ni/Fe ratios in unzoned metal grains in the CBa chondrites that the components of CBa and CBb chondrites formed in a giant impact: SO chondrules and unzoned metal in Gujba

  9. Recycling Lingware in a Multilingual MT System Steffen Leo Hansen

    E-Print Network [OSTI]

    Recycling Lingware in a Multilingual MT System Steffen Leo Hansen Manny Rayner David Carter Ivan (Rayner and Carter, 1997). The first is the most obvious: we start with a function- ing grammar

  10. Ground Gravity Survey At Mt Princeton Hot Springs Geothermal...

    Open Energy Info (EERE)

    lithologic distrubtions Notes Gravity low associated with Mt. Princeton Batholith; density contrast of -0.5 gcm3 of valley-fill sediments relative to batholith References J.E....

  11. Summary of CARE-HHH IR’07

    E-Print Network [OSTI]

    Scandale, Walter

    2008-01-01

    We summarize the highlights and main conclusions of the CARE-HHH-APD mini-workshop on the LHC Interaction Region (IR) upgrade “IR’07” held in Frascati from the 7th to the 9th of November 2007.

  12. NEAFS Y-mtDNA Workshop (Butler and Coble) November 1, 2006

    E-Print Network [OSTI]

    NEAFS Y-mtDNA Workshop (Butler and Coble) mtDNA November 1, 2006 http://www.cstl.nist.gov/biotech) mtDNA November 1, 2006 http://www.cstl.nist.gov/biotech/strbase/training.htm 2 Data Review-mtDNA Workshop (Butler and Coble) mtDNA November 1, 2006 http://www.cstl.nist.gov/biotech/strbase/training.htm 3

  13. Effect of Sodium Sulfide on Ni-Containing Carbon Monoxide Dehydrogenases

    SciTech Connect (OSTI)

    Jian Feng; Paul A. Lindahl

    2004-07-28

    OAK-B135 The structure of the active-site C-cluster in CO dehydrogenase from Carboxythermus hydrogenoformans includes a {mu}{sup 2}-sulfide ion bridged to the Ni and unique Fe, while the same cluster in enzymes from Rhodospirillum rubrum (CODH{sub Rr}) and Moorella thermoacetica (CODH{sub Mt}) lack this ion. This difference was investigated by exploring the effects of sodium sulfide on activity and spectral properties. Sulfide partially inhibited the CO oxidation activity of CODH{sub Rr} and generated a lag prior to steady-state. CODH{sub Mt} was inhibited similarly but without a lag. Adding sulfide to CODH{sub Mt} in the C{sub red1} state caused the g{sub av} = 1.82 EPR signal to decline and new features to appear, including one with g = 1.95, 1.85 and (1.70 or 1.62). Removing sulfide caused the g{sub av} = 1.82 signal to reappear and activity to recover. Sulfide did not affect the g{sub av} = 1.86 signal from the C{sub red2} state. A model was developed in which sulfide binds reversibly to C{sub red1}, inhibiting catalysis. Reducing this adduct causes sulfide to dissociate, C{sub red2} to develop, and activity to recover. Using this model, apparent K{sub I} values are 40 {+-} 10 nM for CODH{sub Rr} and 60 {+-} 30 {micro}M for CODH{sub Mt}. Effects of sulfide are analogous to those of other anions, including the substrate hydroxyl group, suggesting that these ions also bridge the Ni and unique Fe. This proposed arrangement raises the possibility that CO binding labilizes the bridging hydroxyl and increases its nucleophilic tendency towards attacking Ni-bound carbonyl.

  14. Temperature dependence of anisotropic magnetoresistance in antiferromagnetic Sr{sub 2}IrO{sub 4}

    SciTech Connect (OSTI)

    Wang, C.; Seinige, H.; Tsoi, M.; Cao, G.; Zhou, J.-S.; Goodenough, J. B.

    2015-05-07

    Temperature-dependent magnetotransport properties of the antiferromagnetic semiconductor Sr{sub 2}IrO{sub 4} are investigated with point-contact devices. The point-contact technique allows to probe very small volumes and, therefore, to look for electronic transport on a microscopic scale. Point-contact measurements with single crystals of Sr{sub 2}IrO{sub 4} were intended to see whether the additional local resistance associated with a small contact area between a sharpened Cu tip and the antiferromagnet shows magnetoresistance (MR) such as that seen in bulk crystals. Point-contact measurements at liquid nitrogen temperature revealed large MRs (up to 28%) for modest magnetic fields (250?mT) applied within an IrO{sub 2} (ab) plane with angular dependence showing a crossover from four-fold to two-fold symmetry with an increasing magnetic field. Point contact measurement exhibits distinctive anisotropic magnetoresistance (AMR) in comparison to a bulk experiment, imposing intriguing questions about the mechanism of AMR in this material. Temperature-dependent MR measurements show that the MR falls to zero at the Neel temperature, but the temperature dependence of the MR ratio differs qualitatively from that of the resistivity. This AMR study helps to unveil the entanglement between electronic transport and magnetism in Sr{sub 2}IrO{sub 4} while the observed magnetoresistive phenomena can be potentially used to sense the antiferromagnetic order parameter in spintronic applications.

  15. IR-2003- | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

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  16. Mt St Helens Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History ViewMayo, Maryland: EnergyInformationOliver, Pennsylvania:(CTI PFAN) | OpenMt St HelensMt St

  17. Probing the lexicon in evaluating commercial MT systems Martin Volk

    E-Print Network [OSTI]

    for self evaluation consisted of technical, linguistic and ergonomic issues. As part of the linguisticProbing the lexicon in evaluating commercial MT systems Martin Volk University of Zurich Department Abstract In the past the evaluation of machine trans- lation systems has focused on single sys- tem

  18. (Have we found the Holy Grail?) Panel at MT-Summit 2003

    E-Print Network [OSTI]

    Wu, Dekai

    (Have we found the Holy Grail?) Panel at MT-Summit 2003 #12;The HKUST Leading Question Translation? If not, is the Holy Grail just around the corner? Translation Are we just about done? #12;Dekai Wu, MT

  19. Phosphorus content effect on the magnetoelectric properties of the NiP(Ni)/PZT/NiP(Ni) cylindrical layered composites

    E-Print Network [OSTI]

    Volinsky, Alex A.

    were polarized along the radial direction after electroplating a thin Ni layer on its inside and outside surfaces. The samples were pretreated with supersonic cleaning prior to Ni electroplating composite is shown else- where [13]. The final thickness of the inside and the outside coatings

  20. Geothermal energy resource investigations at Mt. Spurr, Alaska

    SciTech Connect (OSTI)

    Turner, D.L.; Wescott, E.M. (eds.)

    1986-12-01

    Spurr volcano is a composite Quaternary cone of largely andesitic composition located on the west side of Cook Inlet about 80 miles west of Anchorage and about 40 miles from the Beluga electrical transmission line. Geologic mapping (Plate 1-1) shows that the present summit depression was produced by a Mt. St. Helens-type sector collapse, rather than by a caldera collapse. Geochronologic and previous tephrachronologic studies show that there has been an active magmatic system at Spurr volcano during the late Pleistocene-to-Holocene time interval that is of critical interest for geothermal energy resource assessment. Major effort was devoted to geochemical and geophysical surveys of the accessible area south of Mt. Spurr, in addition to geologic mapping and geochronologic studies. Many coincident mercury and helium anomalies were found, suggesting the presence of geothermal systems at depth. Extremely large electrical self-potential anomalies were also found, together with extensive zones of low resistivity discovered by our controlled-source audiomagnetotelluric survey. The juxtaposition of all of these different types of anomalies at certain areas on the south slope of Crater Peak indicates the presence of a geothermal system which should be accessible by drilling to about 2000 ft depth. It is also evident that there is a strong volcanic hazard to be evaluated in considering any development on the south side of Mt. Spurr. This hazardous situation may require angle drilling of production wells from safer areas and placement of power generation facilities at a considerable distance from hazardous areas.

  1. Magnetic properties of double perovskite La2BMnO6 (B = Ni or Co) nanoparticles

    SciTech Connect (OSTI)

    Mao, Yuanbing; Parsons, Jason; McCloy, John S.

    2013-03-31

    Double perovskite La2BMnO6 (B = Ni and Co) nanoparticles with average particle size of ~50 nm were synthesized using a facile, environmentally friendly, scalable molten-salt reaction at 700 °C in air. Their structural and morphological properties were characterized by x-ray diffraction and transmission electron microscopy. Magnetic properties were evaluated using dc magnetic M-T and M-H, and ac magnetic susceptibility versus frequency, temperature, and field. The magnetization curve shows a paramagnetic-ferromagnetic transition at TC ~275 and 220 K for La2NiMnO6 (LNMO) and La2CoMnO6 (LCMO) nanoparticles, respectively. ac susceptibility revealed that the LCMO had a single magnetic transition indicative of Co2+-O2--Mn4+ ordering, whereas the LNMO showed more complex magnetic behavior suggesting a re-entrant spin glass.

  2. Materials Data on Sr3NiIrO6 (SG:167) by Materials Project

    SciTech Connect (OSTI)

    Kristin Persson

    2014-11-02

    Computed materials data using density functional theory calculations. These calculations determine the electronic structure of bulk materials by solving approximations to the Schrodinger equation. For more information, see https://materialsproject.org/docs/calculations

  3. Mt St Helens Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

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  4. MT Energie GmbH Co KG | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History View NewTexas:Montezuma,Information MHKMHK5 < MHKKemblaSolar Jump to:Industries Inc JumpMT

  5. RAPID/Roadmap/12-MT-a | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onRAPID/Geothermal/Exploration/Colorado <RAPID/Geothermal/Water Use/Nevada <UtahMontanasourceWA-aCA-aMT-a <

  6. RAPID/Roadmap/15-MT-a | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onRAPID/Geothermal/Exploration/Colorado <RAPID/Geothermal/Water Use/Nevadaa < RAPID‎ | RoadmapCO-ceWA-eb <MT-a

  7. RAPID/Roadmap/17-MT-c | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onRAPID/Geothermal/Exploration/Colorado <RAPID/Geothermal/Water Use/Nevadaa < RAPID‎ |a < RAPID‎CA-aHI-aaMT-c

  8. RAPID/Roadmap/18-MT-b | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onRAPID/Geothermal/Exploration/Colorado <RAPID/Geothermal/Water Use/Nevadaa < RAPID‎ |a <-AK-b <CO-badMT-b

  9. RAPID/Roadmap/4-MT-a | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onRAPID/Geothermal/Exploration/Colorado <RAPID/Geothermal/Water Use/Nevadaa < RAPID‎f <CA-aab <cdMT-a <

  10. RAPID/Roadmap/6-MT-d | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onRAPID/Geothermal/Exploration/Colorado <RAPID/Geothermal/Water Use/Nevadaa < RAPID‎fRAPID/Roadmap/6-CO-bacMT-d

  11. RAPID/Roadmap/6-MT-f | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onRAPID/Geothermal/Exploration/Colorado <RAPID/Geothermal/Water Use/Nevadaa < RAPID‎fRAPID/Roadmap/6-CO-bacMT-df

  12. City of Mt Pleasant, Utah (Utility Company) | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LISTStar EnergyLawler, Iowa (UtilityIowa Phone Number: (319) 385-2121City of Mt

  13. Mt Princeton Hot Springs Geothermal Area | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoop Inc Jump to: navigation,Mereg GmbHMontebalitoMt Princeton Hot Springs Geothermal

  14. RAPID/Roadmap/14-MT-b | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmental Jump to:EA EIS Report UrlNM-b < RAPID‎ | Roadmap JumpNV-a <CA-cID-aMT-b <

  15. RAPID/Roadmap/14-MT-c | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmental Jump to:EA EIS Report UrlNM-b < RAPID‎ | Roadmap JumpNV-a <CA-cID-aMT-b

  16. RAPID/Roadmap/14-MT-d | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmental Jump to:EA EIS Report UrlNM-b < RAPID‎ | Roadmap JumpNV-a <CA-cID-aMT-bd

  17. RAPID/Roadmap/17-MT-d | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmental Jump to:EA EIS Report UrlNM-b < RAPID‎ | Roadmap JumpNV-ad-MT-d < RAPID‎ |

  18. RAPID/Roadmap/20-MT-a | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmental Jump to:EA EIS Report UrlNM-b < RAPID‎ | RoadmapAK-a < RAPID‎ |MT-a <

  19. RAPID/Roadmap/8-MT-a | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION JEnvironmental Jump to:EA EIS Report UrlNM-b < RAPID‎ | RoadmapAK-abFD-a < RAPID‎ID-eMT-a

  20. Micro-Earthquake At Marysville Mt Area (Blackwell) | Open Energy

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIXsource HistoryScenariosMarysville MtMedicalInformation 2-2005)1995) |Information

  1. HERO Ski Trip to Mt. Hood Meadows February

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would likeUniverse (Journalvivo Low-Dose Lowď‚— WeUpdateScienceForTrip to Mt. Hood Meadows

  2. Which Oxidation State Leads to O-O Bond Formation in Cp*Ir(bpy)Cl-Catalyzed Water Oxidation, Ir(V), Ir(VI), or Ir(VII)?

    E-Print Network [OSTI]

    Liao, Rongzhen

    the catalytic IrIII species. Water oxidation at IrVII has a slightly higher barrier, but it may also contributeWhich Oxidation State Leads to O-O Bond Formation in Cp*Ir(bpy)Cl-Catalyzed Water Oxidation, Ir: Density functional calculations are used to revisit the reaction mechanism of water oxidation catalyzed

  3. IRS Warns of Pervasive Telephone Scam IRS YouTube Video

    E-Print Network [OSTI]

    Bermúdez, José Luis

    as described above), then call and report the incident to the Treasury Inspector General for Tax Administration use fake names and IRS badge numbers. They generally use common names and surnames to identify in the message. Instead, forward the e-mail to phishing@irs.gov. More information on how to report phishing scams

  4. Influence of nuclear structure on sub-barrier hindrance in Ni+Ni fusion

    E-Print Network [OSTI]

    C. L. Jiang; K. E. Rehm; R. V. F. Janssens; H. Esbensen; I. Ahmad; B. B. Back; P. Collon; C. N. Davids; J. P. Greene; D. J. Henderson; G. Mukherjee; R. C. Pardo; M. Paul; T. O. Pennington; D. Seweryniak; S. Sinha; Z. Zhou

    2004-02-25

    Fusion-evaporation cross sections for $^{64}$Ni+$^{64}$Ni have been measured down to the 10 nb level. For fusion between two open-shell nuclei, this is the first observation of a maximum in the $S$-factor, which signals a strong sub-barrier hindrance. A comparison with the $^{58}$Ni+$^{58}$Ni, $^{58}$Ni+$^{60}$Ni, and $^{58}$Ni+$^{64}$Ni systems indicates a strong dependence of the energy where the hindrance occurs on the stiffness of the interacting nuclei.

  5. Getting Our Feet Wet: Water Management at Mt. Laguna in Cleveland National Forest

    E-Print Network [OSTI]

    Mumby, William Cade

    2013-01-01

    Strategies for Rural Communities. ” National Conference onallocation facing the rural community of Mt. Laguna? (EquityStrategies for Rural Communities. ” National Conference on

  6. DC Resistivity Survey (Dipole-Dipole Array) At Mt Princeton Hot...

    Open Energy Info (EERE)

    1971) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: DC Resistivity Survey (Dipole-Dipole Array) At Mt Princeton Hot Springs Geothermal Area...

  7. Visual Field Maps, Population Receptive Field Sizes, and Visual Field Coverage in the Human MT Complex

    E-Print Network [OSTI]

    Dumoulin, Serge O.

    of processing in human motion-selective cortex. I N T R O D U C T I O N Neuroimaging experiments localize human by additional experiments. Defining human MT based on stimulus selectivity means that the identificationVisual Field Maps, Population Receptive Field Sizes, and Visual Field Coverage in the Human MT

  8. Bitcoin Transaction Malleability and MtGox Christian Decker and Roger Wattenhofer

    E-Print Network [OSTI]

    Bitcoin Transaction Malleability and MtGox Christian Decker and Roger Wattenhofer ETH Zurich International Publishing Switzerland 2014 #12;314 C. Decker and R. Wattenhofer exchanges its monopoly slowly doubled the withdrawn bitcoins, once from the withdrawal and once on its account on MtGox. In this work we

  9. An assessment of regional climate trends and changes to the Mt. Jaya glaciers of Irian Jaya 

    E-Print Network [OSTI]

    Kincaid, Joni L.

    2007-09-17

    on the Mt. Jaya glaciers has been lacking since the early 1970s. Using IKONOS satellite images, the ice extents of the Mt. Jaya glaciers in 2000, 2002, 2003, 2004, and 2005 were mapped. The mapping indicates that the recessional trend which began in the mid...

  10. Mt. Etna tropospheric ash retrieval and sensitivity analysis using Moderate Resolution Imaging

    E-Print Network [OSTI]

    Oxford, University of

    Mt. Etna tropospheric ash retrieval and sensitivity analysis using Moderate Resolution Imaging.pugnaghi@unimore.it, gabriele.gangale@unimore.it Abstract. A retrieval of tropospheric volcanic ash from Mt Etna has been. In order to derive the ash plume optical thickness, the particle effective radius and the total mass

  11. A MT System from Turkmen to Turkish Employing Finite State and Statistical Methods

    E-Print Network [OSTI]

    Yanikoglu, Berrin

    between close language pairs can be relatively easier and can still benefit from simple(r) paradigms in MT with a disambiguation post-processing stage based on statistical language models. The very productive inflectionalA MT System from Turkmen to Turkish Employing Finite State and Statistical Methods A. Cüneyd TANTU

  12. Sample & Assay Technologies Ni-NTA Superflow

    E-Print Network [OSTI]

    Lebendiker, Mario

    March 2007 Sample & Assay Technologies Ni-NTA Superflow Cartridge Handbook For manual or FPLCTM purification of His-tagged proteins #12;2 Ni-NTA Superflow Cartridge Handbook 03/2007 Trademarks: QIAGEN, are not to be considered unprotected by law. © 2007 QIAGEN, all rights reserved. #12;Ni-NTA Superflow Cartridge Handbook 03

  13. Monopole Strength in Ni-58 

    E-Print Network [OSTI]

    Youngblood, David H.; Lui, YW.

    1991-01-01

    Differential cross-section data from 0-degrees to 8-degrees for inelastic scattering of 129 MeV alpha particles exciting Ni-58 in the region of 14-22 MeV have been analyzed to explore the existence of monopole strength at approximately E(x) = 17 Me...

  14. Vehicle Technologies Office Merit Review 2015: IR Thermography...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    IR Thermography as a Non-Destructive Evaluation (NDE) Tool for Lithium-Ion Battery Manufacturing Vehicle Technologies Office Merit Review 2015: IR Thermography as a Non-Destructive...

  15. Microstructural Characterization and Shape Memory Response of Ni-Rich NiTiHf and NiTiZr High Temperature Shape Memory Alloys 

    E-Print Network [OSTI]

    Evirgen, Alper

    2014-08-14

    NiTiHf and NiTiZr high temperature shape memory alloys (HTSMAs) have drawn a great deal of attention as cheaper alternatives to Pt, Pd and Au alloyed NiTi-based HTSMAs while NiTiZr alloys also providing at least 20% weight reduction then its Ni...

  16. Improving the phase stability and oxidation resistance of B-NiAl

    SciTech Connect (OSTI)

    Brammer, Travis

    2011-08-15

    High temperature alloys are essential to many industries that require a stable material to perform in harsh oxidative environments. Many of these alloys are suited for specific applications such as jet engine turbine blades where most other materials would either melt or oxidize and crumble (1). These alloys must have a high melting temperature, excellent oxidation resistance, good creep resistance, and decent fracture toughness to be successfully used in such environments. The discovery of Ni based superalloys in the 1940s revolutionized the high temperature alloy industry and there has been continued development of these alloys since their advent (2). These materials are capable of operating in oxidative environments in the presence of combustion gases, water vapor and at temperatures around 1050 C. Demands for increased f uel efficiency, however, has highlighted the need for materials that can be used under similar atmospheres and at temperatures in excess of 1200 C. The current Ni based superalloys are restricted to lower temperatures due to the presence of a number of low melting phases that result in softening of the alloys above 1000 C. Therefore, recent research has been aimed at exploring and developing newer alloy systems that can meet the escalating requirements. This thesis comprises a part of such an effort. The motivation of this work is to develop a novel high temperature alloy system that shows improved performance at higher temperatures than the currently employed alloys. The desired alloy should be in accordance with the requirements established in the National Energy Technology Laboratory (NETL) FutureGen program having an operating temperature around 1300 C. Alloys based on NiAl offer significant potential payoffs as structural materials in gas turbine applications due to a unique range of physical and mechanical properties. Alloying additions to NiAl could be used to further improve the pertinent properties that currently limit this system from replacing Ni based superalloys. Modifications to NiAl were explored to increase the phase stability and oxidation resistance which would allow these alloys to be used at even higher temperatures yielding greater efficiencies. The extended Miedema model was an effective tool that screened all of the potential phase space for ternary substitutions to NiAl and found the few potential systems worth further investigation. After production of the alloys it was determined that Ir, Rh, and Pd were the top candidates for substitution on Ni site up to 12 at%. The melting temperature of NiAl could be increased as much as 150 C with 12 at% Ir and 130 C with 12 at% Rh substitution. Pall adium on the other hand decreased the melting temperature by 50 C at the 12 at% substitution level. The grain size was found to have a profound influence on the oxidation resistance. Both Ir and Rh substitutions resulted in finer grain sizes compared to Pd substitutions or base NiAl. The grain size increased drastically during high temperature annealing with the PGM substitutions hindering grain growth only slightly. However, the addition of 0.05 at% Hf limited the grain growth dramatically during high temperature annealing. NiAl inherently has respectable oxidation resistance up to 1100 C. It was found through experimental testing that both Ir and Rh substitutions improve the oxidation resistance of NiAl at ultra-high temperatures with Ir performing the best. Both PGM substitutions decreased the growth rate as well as forming a more adherent oxide scale. Pd substitutions appeared to have a negligible effect to the oxidation resistance of NiAl. Hafnium addition of 0.05 at% was found to decrease the oxidation rate as well as increase the scale adherence. The combination of both Ir substitution (6-9 at%) and Hf addition (0.05 at%) produced the alloy with the best oxidation resistance. Although improvements in phase stability and oxidation resistance have been made to the NiAl system, more development and testing are still needed. Two major issues yet to be resolved are the low fracture toughn

  17. MT3D: a 3 dimensional magnetotelluric modeling program (user's guide and documentation for Rev. 1)

    SciTech Connect (OSTI)

    Nutter, C.; Wannamaker, P.E.

    1980-11-01

    MT3D.REV1 is a non-interactive computer program written in FORTRAN to do 3-dimensional magnetotelluric modeling. A 3-D volume integral equation has been adapted to simulate the MT response of a 3D body in the earth. An integro-difference scheme has been incorporated to increase the accuracy. This is a user's guide for MT3D.REV1 on the University of Utah Research Institute's (UURI) PRIME 400 computer operating under PRIMOS IV, Rev. 17.

  18. IMPROVED Ni I log(gf) VALUES AND ABUNDANCE DETERMINATIONS IN THE PHOTOSPHERES OF THE SUN AND METAL-POOR STAR HD 84937

    SciTech Connect (OSTI)

    Wood, M. P.; Lawler, J. E.; Sneden, C.; Cowan, J. J. E-mail: jelawler@wisc.edu E-mail: cowan@nhn.ou.edu

    2014-04-01

    Atomic transition probability measurements for 371 Ni I lines in the UV through near-IR are reported. Branching fractions from data recorded using a Fourier transform spectrometer and a new echelle spectrograph are combined with published radiative lifetimes to determine these transition probabilities. Generally good agreement is found in comparisons to previously reported Ni I transition probability measurements. Use of the new echelle spectrograph, independent radiometric calibration methods, and independent data analysis routines enable a reduction of systematic errors and overall improvement in transition probability uncertainty over previous measurements. The new Ni I data are applied to high-resolution visible and UV spectra of the Sun and metal-poor star HD 84937 to derive new, more accurate Ni abundances. Lines covering a wide range of wavelength and excitation potential are used to search for non-LTE effects.

  19. Graphene-silicon layered structures on single-crystalline Ir(111) thin films

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Que, Yande D.; Tao, Jing; Zhang, Yong; Wang, Yeliang L.; Wu, Lijun J.; Zhu, Yimei M.; Kim, Kisslinger; Weinl, Michael; Schreck, Matthias; Shen, Chengmin M.; et al

    2015-01-20

    Epitaxial growth of graphene on transition metal crystals, such as Ru,?ą?ł? Ir,????? and Ni,??? provides large-area, uniform graphene layers with controllable defect density, which is crucial for practical applications in future devices. To decrease the high cost of single-crystalline metal bulks, single-crystalline metal films are strongly suggested as the substrates for epitaxial growth large-scale high-quality graphene.???ą?? Moreover, in order to weaken the interactions of graphene with its metal host, which may result in a suppression of the intrinsic properties of graphene,?ąą ą˛? the method of element intercalation of semiconductors at the interface between an epitaxial graphene layer and a transitionmore »metal substrate has been successfully realized.?ął?ą??« less

  20. In Situ Diffuse Reflectance IR Spectroscopy and X-ray Absorption Spectroscopy for Fast Catalytic Processes

    SciTech Connect (OSTI)

    N Marinkovic; Q Wang; A Frenkel

    2011-12-31

    A new instrument for synchronous in situ investigations of catalytic materials by IR and X-ray absorption spectroscopies was designed and built at the X18A beamline of the National Synchrotron Light Source of Brookhaven National Laboratory. It provides analytical tools for solving structural, electronic and kinetic problems in catalysis science by two complementary methods. Among the features attractive for catalysis research are the broad range of catalytically active elements that can be investigated (starting with Ni and beyond), the wide range of reaction conditions (temperatures up to 873 K, various reactive gases) and time scales (starting from tens of seconds). The results of several representative experiments that illustrate the attractive capabilities of the new set-up are discussed.

  1. A Ni-Fe Layered Double Hydroxide-Carbon Nanotube Complex for Water Oxidation

    E-Print Network [OSTI]

    Gong, Ming; Wang, Hailiang; Liang, Yongye; Wu, Justin Zachary; Zhou, Jigang; Wang, Jian; Regier, Tom; Wei, Fei; Dai, Hongjie

    2013-01-01

    Highly active, durable and cost-effective electrocatalysts for water oxidation to evolve oxygen gas hold a key to a range of renewable energy solutions including water splitting and rechargeable metal-air batteries. Here, we report the synthesis of ultrathin nickel iron layered double hydroxide nanoplates on mildly oxidized multi-walled carbon nanotubes. Incorporation of Fe into the nickel hydroxide induced the formation of NiFe-layered double hydroxide. The nanoplates were covalently attached to a network of nanotubes, affording excellent electrical wiring to the nanoplates. The ultra-thin Ni-Fe layered double hydroxide nanoplates/carbon nanotube complex was found to exhibit unusually high electro-catalytic activity and stability for oxygen evolution and outperformed commercial precious metal Ir catalysts.

  2. Two Keggin-type heteropolytungstates with transition metal as a central atom: Crystal structure and magnetic study with 2D-IR correlation spectroscopy

    SciTech Connect (OSTI)

    Chai, Feng [Department of Chemistry, Fuzhou University, Fuzhou 350108 (China); Chen, YiPing, E-mail: ypchen007@sina.com [Department of Chemistry, Fuzhou University, Fuzhou 350108 (China); State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002 (China); You, ZhuChai; Xia, ZeMin; Ge, SuZhi; Sun, YanQiong; Huang, BiHua [Department of Chemistry, Fuzhou University, Fuzhou 350108 (China)

    2013-06-01

    Two Keggin-type heteropolytungstates, [Co(phen)?]?[CoW??O??]·9H?O 1 (phen=1,10-phenanthroline) and [Fe(phen)?]?[FeW??O??]·H?O·H?O 2, have been synthesized via the hydrothermal technique and characterized by single crystal X-ray diffraction analyses, IR, XPS, TG analysis, UV–DRS, XRD, thermal-dependent and magnetic-dependent 2D-COS IR (two-dimensional infrared correlation spectroscopy). Crystal structure analysis reveals that the polyanions in compound 1 are linked into 3D supramolecule through hydrogen bonding interactions between lattice water molecules and terminal oxygen atoms of polyanion units, and [Co(phen)?]˛? cations distributed in the polyanion framework with many hydrogen bonding interactions. The XPS spectra indicate that all the Co atoms in 1 are +2 oxidation state, the Fe atoms in 2 existing with +2 and +3 mixed oxidation states. - Graphical abstract: The magnetic-dependent synchronous 2D correlation IR spectra of 1 (a), 2 (b) over 0–50 mT in the range of 600–1000 cm?ą, the obvious response indicate two Keggin polyanions skeleton susceptible to applied magnetic field. Highlights: • Two Keggin-type heteropolytungstates with transition metal as a central atom has been obtained. • Compound 1 forms into 3D supramolecular architecture through hydrogen bonding between water molecules and polyanions. • Magnetic-dependent 2D-IR correlation spectroscopy was introduced to discuss the magnetism of polyoxometalate.

  3. NEAFS Y-mtDNA Workshop (Butler and Coble) Markers, Core Loci, and Kits

    E-Print Network [OSTI]

    ) ­ Ann Gross (MN) ­ Jill Smerick (FBI) ­ Sam Baechtel (FBI) ­ Roger Frappier (CFS) ­ Phil Kinsey (OR now MT) ­ Gary Sims (CA DOJ) ­ George Carmody (retired) ­ Mike Adamowicz (CT) ­ Bruce Budowle (FBI

  4. TIME-VARIABLEFILTERING OF MtTLTI[CHANNELSIGNALS USING MULTIPLE WINDOWS COHERENCEAND THE WEYL TRANSFORM

    E-Print Network [OSTI]

    Sandsten, Maria

    TIME-VARIABLEFILTERING OF MtTLTI[CHANNELSIGNALS USING MULTIPLE WINDOWS COHERENCEAND THE WEYL between all channel pairs. Time-frequency coherence functions are estimated using the multiple window

  5. The Genetic Structure of the Kuwaiti Population: mtDNA Inter- and Intra-population Variation

    E-Print Network [OSTI]

    Theyab, Jasem; Al-Bustan, Suzanne; Crawford, Michael H.

    2012-08-01

    it to their neighboring populations. These subpopulations were tested for genetic homogeneity and shown to be heterogeneous. Restriction fragment length polymorphism (RFLP) and mtDNA sequencing analyses of HVRI were used to reconstruct the genetic structure of Kuwait...

  6. Implied motion activation in cortical area MT can be explained by visual low-level features

    E-Print Network [OSTI]

    Oram, Mike

    ForReview Only Implied motion activation in cortical area MT can be explained by visual low Neuroscience #12;ForReview Only 1 Implied motion activation in cortical area MT can be explained by visual low, The Netherlands Page 1 of 51 Jounal of Cognitive Neuroscience 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20

  7. Engineering the Martensitic Transformation Hysteresis of Ni-Rich NiTi Alloys 

    E-Print Network [OSTI]

    Franco, Brian Eelan

    2014-12-18

    The shape memory behavior in NiTi alloys can be exploited for a wide variety of applications that require active materials. The application dictates the transformation temperatures and hysteresis of the alloy. NiTi alloys ...

  8. Transformation Induced Fatigue of Ni-Rich NiTi Shape Memory Alloy Actuators 

    E-Print Network [OSTI]

    Schick, Justin Ryan

    2011-02-22

    In this work the transformation induced fatigue of Ni-rich NiTi shape memory alloys (SMAs) was investigated. The aerospace industry is currently considering implementing SMA actuators into new applications. However, before ...

  9. Simultaneous determination of Ni-63 and Ni-59 in radioactive wastes by liquid scintillation spectrometry 

    E-Print Network [OSTI]

    Kim, Esther Miyeun

    1988-01-01

    SIMULTANEOUS DETERMINATION OF Ni-63 AND Ni-59 IN RADIOACTIVE WASTES BY LIQUID SCINTILLATION SPECTROMETRY A Thesis by ESTHER MIYEUN KIM Submitted to the Office of Graduate Studies of Texas AgtM University in partial fulfillment... of the requirements for the degree of MASTER OF SCIENCE May 1988 Major Subject: Health Physics SIMULTANEOUS DETERMINATION OF Ni-63 AND Ni-59 IN RADIOACTIVE WASTES BY LIQUID SCINTILLATION SPECTROMETRY A Thesis by ESTHER MIYEUN KIM Approved as to style...

  10. łNi˛ Clusterbank Replacement Project | Argonne Leadership Computing...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ni Clusterbank Replacement Project Event Sponsor: Argonne Leadership Computing Facility Seminar Start Date: Oct 20 2015 - 12:00pm BuildingRoom: Building 241Room D173...

  11. Magnetic structure near the Co/NiO(001) interface

    E-Print Network [OSTI]

    Arenholz, Elke

    2008-01-01

    are perpendicular to the NiO moments, hence demonstrating2+ L 3,2 XA spectra and NiO domain pattern (inset). SpectraThe 100 directions of the NiO(001) plane and the orientation

  12. Summary of the Optics, IR, Injection, Operations, Reliability...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: Summary of the Optics, IR, Injection, Operations, Reliability and Instrumentation Working Group Citation Details In-Document Search Title: Summary of the Optics,...

  13. Ir-based alloys for ultra-high temperature applications

    DOE Patents [OSTI]

    Liu, Chain T.; George, Easo P.; Bloom, Everett E.

    2006-01-03

    An alloy composition includes, in atomic percent: about 1 to about 10% of at least one element selected from the group consisting of Zr and Hf, balance Ir.

  14. Giant Quadrupole-Resonance in Ni Isotopes 

    E-Print Network [OSTI]

    Youngblood, David H.; Lui, YW; Garg, U.; Peterson, R. J.

    1992-01-01

    VOLUME 45, NUMBER 5 MAY 1992 Giant quadrupole resonance in Ni isotopes D. H. Youngblood and Y.-%. Lui Texas A&M UniUersity, College Station, Texas 77843 U. Garg University of Notre Dame, South Bend, Indiana 46556 R. J. Peterson University... (%) 58+12 76+14 78+14 90+16 Cp 0.80+0.04 0.84+0.04 0.82+0. 12 1.05+0. 10 2174 YOUNGBLOOD, LUI, GARG, AND PETERSON 45 1000 100 60Ni(n, n') E = 129 MeV 1 000 100 58Ni(n, n') 10 10 100 z' 1000 64Ni(n, n') 1OO~y 64 Ni 100 10 I s & & I...

  15. Moving Object Detection and Compression in IR Sequences

    E-Print Network [OSTI]

    Agrawal, Amit

    infrared (IR) sensors. The aim is to use IR image sequences to detect moving objects (humans or vehicles computational power of computing devices attached to the sensor, the algorithms should be computationally simple implemented in C/C++ and their performance has been evaluated the using Hitachi's SH4 platform with software

  16. A New DBMS Architecture for DB-IR Integration

    E-Print Network [OSTI]

    Whang, Kyu-Young

    A New DBMS Architecture for DB-IR Integration Kyu-Young Whang Computer Science Department. Nowadays, as there is an increasing need to integrate the DBMS (for structured data) with Information is required. In this talk, we present a new DBMS architecture applica- ble to DB-IR integration, which we call

  17. Modeling IR Radiative Loss from Eppley PSP Pyranometers Frank Vignola

    E-Print Network [OSTI]

    Oregon, University of

    Renewable Energy Laboratory ABSTRACT A method has been developed to estimate IR radiative losses using solar, irradiance, IR, modeling, global, diffuse, PSP 1. INTRODUCTION Since the 1970s, solar radiation data has been Energy Laboratory (NREL) data page3 along with the original global data. Corrections to the PSP

  18. Enthalpy of mixing of liquid Ni-Zr and Cu-Ni-Zr alloys

    SciTech Connect (OSTI)

    Witusiewicz, V.T.; Sommer, F.

    2000-04-01

    Since the Al-Cu-Ni-Zr system is a basis for the production of bulk amorphous materials by rapid solidification techniques from the liquid state, it is of great scientific interest to determine the partial and the integral thermodynamic functions of liquid and undercooled liquid alloys. Such data, as was pointed out previously, are important in order to understand their extremely good glass-forming ability in multicomponent metallic systems as well as for processing improvements. In order to measure the thermodynamic properties of the Al-Cu-Ni-Zr quaternary, it is necessary to have reliable thermochemical data for its constituent canaries and ternaries first. In a series of articles, the authors have reported in detail the thermodynamic properties of liquid Al-Cu, Al-Ni, Cu-Ni, Cu-Zr, Al-Zr, Al-Cu-Ni, and Al-Cu-Zr alloys. This article deals with the direct calorimetric measurements of the partial and the integral enthalpies of mixing of liquid Ni-Zr and Cu-Ni-Zr alloys and the heat capacity of liquid Ni{sub 26}Zr{sub 74}. In a subsequent article, the authors will present similar data for the liquid ternary Al-Ni-Zr and for the liquid quaternary Al-Cu-Ni-Zr alloys.

  19. Simultaneous multi-beam planar array IR (pair) spectroscopy

    DOE Patents [OSTI]

    Elmore, Douglas L.; Rabolt, John F.; Tsao, Mei-Wei

    2005-09-13

    An apparatus and method capable of providing spatially multiplexed IR spectral information simultaneously in real-time for multiple samples or multiple spatial areas of one sample using IR absorption phenomena requires no moving parts or Fourier Transform during operation, and self-compensates for background spectra and degradation of component performance over time. IR spectral information and chemical analysis of the samples is determined by using one or more IR sources, sampling accessories for positioning the samples, optically dispersive elements, a focal plane array (FPA) arranged to detect the dispersed light beams, and a processor and display to control the FPA, and display an IR spectrograph. Fiber-optic coupling can be used to allow remote sensing. Portability, reliability, and ruggedness is enhanced due to the no-moving part construction. Applications include determining time-resolved orientation and characteristics of materials, including polymer monolayers. Orthogonal polarizers may be used to determine certain material characteristics.

  20. NaIrO3—A Pentavalent Post-perovskite

    SciTech Connect (OSTI)

    M Bremholm; S Dutton; P Stephens; R Cava

    2011-12-31

    Sodium iridium (V) oxide, NaIrO{sub 3}, was synthesized by a high pressure solid state method and recovered to ambient conditions. It is found to be isostructural with CaIrO{sub 3}, the much-studied structural analog of the high-pressure post-perovskite phase of MgSiO{sub 3}. Among the oxide post-perovskites, NaIrO{sub 3} is the first example with a pentavalent cation. The structure consists of layers of corner- and edge-sharing IrO{sub 6} octahedra separated by layers of NaO{sub 8} bicapped trigonal prisms. NaIrO{sub 3} shows no magnetic ordering and resistivity measurements show non-metallic behavior. The crystal structure, electrical and magnetic properties are discussed and compared to known post-perovskites and pentavalent perovskite metal oxides.

  1. Experiment operations plan for the MT-4 experiment in the NRU reactor. [PWR

    SciTech Connect (OSTI)

    Russcher, G.E.; Wilson, C.L.; Parchen, L.J.; Marshall, R.K.; Hesson, G.M.; Webb, B.J.; Freshley, M.D.

    1983-06-01

    A series of thermal-hydraulic and cladding materials deformation experiments were conducted using light-water reactor fuel bundles as part of the Pacific Northwest Laboratory Loss-of-Coolant Accident (LOCA) Simulation Program. This report is the formal operations plan for MT-4 - the fourth materials deformation experiment conducted in the National Research Universal (NRU) reactor, Chalk River, Ontario, Canada. A major objective of MT-4 was to simulate a pressurized water reactor LOCA that could induce fuel rod cladding deformation and rupture due to a short-term adiabatic transient and a peak fuel cladding temperature of 1200K (1700/sup 0/F).

  2. Spectromicroscopy study of interfacial Co/NiO(001)

    E-Print Network [OSTI]

    van der Laan, Gerrit

    2011-01-01

    study of interfacial Co/NiO(001) G. van der Laan, 1 N. D.the Co moments. The Ni moments in NiO prefer to be orienteda component of the moments in the NiO collinear to the Co.

  3. Layering and temperature-dependent magnetization and anisotropy of naturally produced Ni/NiO multilayers

    SciTech Connect (OSTI)

    Pappas, S. D.; Trachylis, D.; Velgakis, M. J.; Kapaklis, V.; Joensson, P. E.; Papaioannou, E. Th.; Delimitis, A.; Poulopoulos, P.; Fumagalli, P.; Politis, C.

    2012-09-01

    Ni/NiO multilayers were grown by magnetron sputtering at room temperature, with the aid of the natural oxidation procedure. That is, at the end of the deposition of each single Ni layer, air is let to flow into the vacuum chamber through a leak valve. Then, a very thin NiO layer ({approx}1.2 nm) is formed. Simulated x-ray reflectivity patterns reveal that layering is excellent for individual Ni-layer thickness larger than 2.5 nm, which is attributed to the intercalation of amorphous NiO between the polycrystalline Ni layers. The magnetization of the films, measured at temperatures 5-300 K, has almost bulk-like value, whereas the films exhibit a trend to perpendicular magnetic anisotropy (PMA) with an unusual significant positive interface anisotropy contribution, which presents a weak temperature dependence. The power-law behavior of the multilayers indicates a non-negligible contribution of higher order anisotropies in the uniaxial anisotropy. Bloch-law fittings for the temperature dependence of the magnetization in the spin-wave regime show that the magnetization in the multilayers decreases faster as a function of temperature than the one of bulk Ni. Finally, when the individual Ni-layer thickness decreases below 2 nm, the multilayer stacking vanishes, resulting in a dramatic decrease of the interface magnetic anisotropy and consequently in a decrease of the perpendicular magnetic anisotropy.

  4. Dr. Joseph A. Shaw Electrical & Computer Engineering Dept., Montana State University, Bozeman, MT 59717

    E-Print Network [OSTI]

    Lawrence, Rick L.

    Dr. Joseph A. Shaw Electrical & Computer Engineering Dept., Montana State University, Bozeman, MT M.S. Electrical Engineering University of Utah 1987 B.S. Electrical Engineering University of Alaska Experience: 2008 ­ present Professor ­ Electrical & Computer Engineering (ECE) Department, Montana State

  5. Synchronous Dependency Insertion Grammars A Grammar Formalism for Syntax Based Statistical MT

    E-Print Network [OSTI]

    Synchronous Dependency Insertion Grammars A Grammar Formalism for Syntax Based Statistical MT Yuan formalism specifically designed for syntax-based sta- tistical machine translation. The synchro- nous between lan- guages, which many other synchronous grammars are unable to model. A Depend- ency Insertion

  6. MONTANA OUTDOORS 3130 MARCH APRIL 2014 FWP.MT.GOV/MTOUTDOORS Why mountain bluebirds

    E-Print Network [OSTI]

    Duckworth, Renée

    MONTANA OUTDOORS 3130 MARCH APRIL 2014 FWP.MT.GOV/MTOUTDOORS TURF WAR TWIST Why mountain bluebirds are good for this species in western Montana valleys but don't benefit, in the long run, mountain bluebirds. Although mountain blue- birds also lost nesting sites, they had evolved to also use habitats at higher

  7. Intermountain GIS Conference. April 1923 2010, Bozeman, MT. Patrick Lawrence, Maxwell BD, Rew LJ

    E-Print Network [OSTI]

    Maxwell, Bruce D.

    Intermountain GIS Conference. April 1923 2010, Bozeman, MT. Patrick Lawrence, Maxwell BD, Rew in the Python programming language, drawing on Python's builtin library, the RPy extension, ArcGIS geoprocessing and ArcGIS Server. As inputs, it accepts transect shapefiles, transect text files, or point

  8. MT3DMS, A Modular Three-Dimensional Multispecies Transport Model User Guide to the

    E-Print Network [OSTI]

    Zheng, Chunmiao

    .M. Cozzarelli, M.H. Lahvis, and B.A. Bekins. 1998. Ground water contamination by crude oil near Bemidji (LNAPL) contaminant through the unsaturated zone and the formation of an oil lens on the water tableMT3DMS, A Modular Three-Dimensional Multispecies Transport Model ­ User Guide to the Hydrocarbon

  9. Hybrid Rule-Based Example-Based MT: Feeding Apertium with Sub-sentential Translation Units

    E-Print Network [OSTI]

    Way, Andy

    Hybrid Rule-Based ­ Example-Based MT: Feeding Apertium with Sub-sentential Translation Units Felipe S´anchez-Mart´inez Mikel L. Forcada Andy Way Dept. Llenguatges i Sistemes Inform`atics Universitat University Dublin 9, Ireland {mforcada,away}@computing.dcu.ie Abstract This paper describes a hybrid machine

  10. Stress magnitude and its temporal variation at Mt. Asama Volcano, Japan, from seismic anisotropy and GPS

    E-Print Network [OSTI]

    Utrecht, Universiteit

    Stress magnitude and its temporal variation at Mt. Asama Volcano, Japan, from seismic anisotropy stress Japan The Earth's stress regime is fundamental to its physical processes, yet few methods can determine absolute stress, and measurements of temporal variations in stress are controversial. The Global

  11. Some Effects of Mt. St. Helens Volcanic Ash on Juvenile Salmon Smolts

    E-Print Network [OSTI]

    Some Effects of Mt. St. Helens Volcanic Ash on Juvenile Salmon Smolts TIMOTHY W. NEWCOMB and THOMAS. Helens, which was completely decimated with vol- canic ash and mud slides. Heavy sediment loads smolts were exposed to various concentrations ofairborne volcanic ash from the 18 May 1980 eruption

  12. High-latitude vegetation dynamics: 850 years of vegetation development on Mt Hekla, Iceland 

    E-Print Network [OSTI]

    Cutler, Nick

    2008-01-01

    on Mt Hekla in south-central Iceland. The chronosequence approach was used to infer 850 years of vegetation development from a suite of 14 lava flows (five of which had been disturbed by the deposition of volcanic tephra). The thesis is organised around...

  13. Geophys. 1. R. astr. Soc. (1987),89,7-18 MT and reflection: an essential combination

    E-Print Network [OSTI]

    Jones, Alan G.

    1987-01-01

    ) studies and seismic reflection profiles conducted. Unfortunately, over many more regions the seismic of the magnetotelluric (MT) technique as having a vertical resolution equivalent to the seismic refraction method, in almost every case, be made wherever a seismic reflection survey is undertaken. Examples are shown from

  14. Electrical, optical and magnetic investigations on LiNiPO{sub 4} based olivines synthesized by solution combustion technique

    SciTech Connect (OSTI)

    Vijayan, Lakshmi [St. Aloysius College, Edathua, Alappuzha (District), Kerala 689573 (India); Cheruku, Rajesh [Department of Physics, School of Physical, Chemical and Applied Sciences, Pondicherry University, R.V. Nagar, Kalapet, Pondicherry 605 014 (India); Govindaraj, G., E-mail: ggraj_7@yahoo.com [Department of Physics, School of Physical, Chemical and Applied Sciences, Pondicherry University, R.V. Nagar, Kalapet, Pondicherry 605 014 (India)

    2014-02-01

    Highlights: • Solution combustion technique and preparation of nanocrystalline olivine materials. • Olivine type LiNiPO{sub 4} based nanocrystalline materials and characterization. • AC electrical studies on olivine type LiNi{sub 1?x}M{sub x}PO{sub 4}(M = Cu{sup 2+}/Mg{sup 2+})based materials. • Enhancement of ionic conductivity in the nanocrystalline phase of LiNiPO{sub 4} material. - Abstract: Citric acid assisted solution combustion technique is explored for synthesis of supervalent Cu{sup 2+}/Mg{sup 2+} ion doped LiNiPO{sub 4} system. XRD, FT-IR and microscopy studies confirmed the formation of a well crystallized material at low concentration of dopants. Ionic conductivity increases for lower concentrations of dopants due to the increased channel size for Li{sup +} diffusion. Owing to inherent anti-site defects, ionic conductivity decreases with increase of dopant concentration. Magnetic studies are explored for confirmation of antiferromagnetic nature of ions. Wagner polarization method is used to elucidate the negligible contribution of electrons to total conductivity.

  15. IRS Announces New Tribal Economic Development Bond Allocation Guidance

    Broader source: Energy.gov [DOE]

    Treasury and the IRS published new guidance today allocating Tribal Economic Development Bonds (TEDBs) for Tribes that have projects that are in the final stages of going to the market to receive financing.

  16. DWEA Webinar: IRS Guidance for Small Wind Turbines

    Broader source: Energy.gov [DOE]

    The U.S. Internal Revenue Service (IRS) has issued Notice 2015-4 providing new performance and quality standards of small wind turbines – defined as having a nameplate capacity of up to 100 kW – in...

  17. New IRS Rules for Small and Medium Wind Turbines

    Broader source: Energy.gov [DOE]

    The Small Wind Certification Council (SWCC) will host a webinar on how certification is being used to meet the new Internal Revenue Service (IRS) requirements for small and medium wind turbines...

  18. Fig. 1. Magnetic hysteresis of NiO-doped NiF2 conversion materials

    E-Print Network [OSTI]

    Siegel, Paul H.

    member with CMRR, is leading her group to design, optimize and develop new materials for energy storage materials for higher energy lithium ion batteries (at least double the energy density of today's technologyFig. 1. Magnetic hysteresis of NiO-doped NiF2 conversion materials CMRR Newsletter Shirley Meng

  19. Electronic circuits having NiAl and Ni.sub.3 Al substrates

    DOE Patents [OSTI]

    Deevi, Seetharama C. (Midlothian, VA); Sikka, Vinod K. (Oak Ridge, TN)

    1999-01-01

    An electronic circuit component having improved mechanical properties and thermal conductivity comprises NiAl and/or Ni.sub.3 Al, upon which an alumina layer is formed prior to applying the conductive elements. Additional layers of copper-aluminum alloy or copper further improve mechanical strength and thermal conductivity.

  20. Antiproton Production in Ni+ni Collisions at 1.85 Gev/nucleon 

    E-Print Network [OSTI]

    LI, GQ; Ko, Che Ming.

    1994-01-01

    Antiproton production in Ni+Ni collisions at 1.85 GeV/nucleon is studied in the relativistic Vlasov-Uehling-Uhlenbeck model. The self-energies of the antiproton are determined from the nucleon self-energies by the G-parity transformation. Also...

  1. IR-laser initiated combustion -- A step toward complete combustion

    SciTech Connect (OSTI)

    Laghai, A.; Nabavi, S.H.; Servati, H.B.; Syed, F.

    1996-09-01

    The new global environmental regulations for reducing the engine emissions from both moving and stationary sources, as well as improvement in fuel economy are the major motifs to obtain a perfect combustion process and exhaust aftertreatment methods. Infrared (IR)-Laser initiated combustion provides a very high initial temperature, which produces propagation of a turbulent thermopressure pulse that results in a fast burning and improved combustion. The role of IR is to maximize the heat generation efficiency.

  2. Liquid chromatography/Fourier transform IR spectrometry interface flow cell

    DOE Patents [OSTI]

    Johnson, Charles C. (Fairfield, OH); Taylor, Larry T. (Blacksburg, VA)

    1986-01-01

    A zero dead volume (ZDV) microbore high performance liquid chromatography (.mu.HPLC)/Fourier transform infrared (FTIR) interface flow cell includes an IR transparent crystal having a small diameter bore therein through which a sample liquid is passed. The interface flow cell further includes a metal holder in combination with a pair of inner, compressible seals for directly coupling the thus configured spectrometric flow cell to the outlet of a .mu.HPLC column end fitting to minimize the transfer volume of the effluents exiting the .mu.HPLC column which exhibit excellent flow characteristics due to the essentially unencumbered, open-flow design. The IR beam passes transverse to the sample flow through the circular bore within the IR transparent crystal, which is preferably comprised of potassium bromide (KBr) or calcium fluoride (CaF.sub.2), so as to minimize interference patterns and vignetting encountered in conventional parallel-plate IR cells. The long IR beam pathlength and lensing effect of the circular cross-section of the sample volume in combination with the refractive index differences between the solvent and the transparent crystal serve to focus the IR beam in enhancing sample detection sensitivity by an order of magnitude.

  3. Liquid chromatography/Fourier transform IR spectrometry interface flow cell

    DOE Patents [OSTI]

    Johnson, C.C.; Taylor, L.T.

    1985-01-04

    A zero dead volume (ZDV) microbore high performance liquid chromatography (..mu.. HPLC)/Fourier transform infrared (FTIR) interface flow cell includes an IR transparent crystal having a small diameter bore therein through which a sample liquid is passed. The interface flow cell further includes a metal holder in combination with a pair of inner, compressible seals for directly coupling the thus configured spectrometric flow cell to the outlet of a ..mu.. HPLC column end fitting to minimize the transfer volume of the effluents exiting the ..mu.. HPLC column which exhibit excellent flow characteristics due to the essentially unencumbered, open-flow design. The IR beam passes transverse to the sample flow through the circular bore within the IR transparent crystal, which is preferably comprised of potassium bromide (KBr) or calcium fluoride (CaF/sub 2/), so as to minimize interference patterns and vignetting encountered in conventional parallel-plate IR cells. The long IR beam pathlength and lensing effect of the circular cross-section of the sample volume in combination with the refractive index differences between the solvent and the transparent crystal serve to focus the IR beam in enhancing sample detection sensitivity by an order of magnitude.

  4. NGC 7538 : Multiwavelength Study of Stellar Cluster Regions associated with IRS 1-3 and IRS 9 sources

    E-Print Network [OSTI]

    Mallick, K K; Tamura, M; Pandey, A K; Dib, S; Ghosh, S K; Sunada, K; Zinchenko, I; Pirogov, L; Tsujimoto, M

    2014-01-01

    We present deep and high-resolution (FWHM ~ 0.4 arcsec) near-infrared (NIR) imaging observations of the NGC 7538 IRS 1-3 region (in JHK bands), and IRS 9 region (in HK bands) using the 8.2m Subaru telescope. The NIR analysis is complemented with GMRT low-frequency observations at 325, 610, and 1280 MHz, molecular line observations of H13CO+ (J=1-0), and archival Chandra X-ray observations. Using the 'J-H/H-K' diagram, 144 Class II and 24 Class I young stellar object (YSO) candidates are identified in the IRS 1-3 region. Further analysis using 'K/H-K' diagram yields 145 and 96 red sources in the IRS 1-3 and IRS 9 regions, respectively. A total of 27 sources are found to have X-ray counterparts. The YSO mass function (MF), constructed using a theoretical mass-luminosity relation, shows peaks at substellar (~0.08-0.18 Msolar) and intermediate (~1-1.78 Msolar) mass ranges for the IRS 1-3 region. The MF can be fitted by a power law in the low mass regime with a slope of Gamma ~ 0.54-0.75, which is much shallower t...

  5. Highly Active and Stable MgAl2O4 Supported Rh and Ir Catalysts for Methane Steam Reforming: A Combined Experimental and Theoretical Study

    SciTech Connect (OSTI)

    Mei, Donghai; Glezakou, Vassiliki Alexandra; Lebarbier, Vanessa MC; Kovarik, Libor; Wan, Haiying; Albrecht, Karl O.; Gerber, Mark A.; Rousseau, Roger J.; Dagle, Robert A.

    2014-07-01

    In this work we present a combined experimental and theoretical investigation of stable MgAl2O4 spinel-supported Rh and Ir catalysts for the steam methane reforming (SMR) reaction. Firstly, catalytic performance for a series of noble metal catalysts supported on MgAl2O4 spinel was evaluated for SMR at 600-850°C. Turnover rate at 850°C follows the order: Pd > Pt > Ir > Rh > Ru > Ni. However, Rh and Ir were found to have the best combination of activity and stability for methane steam reforming in the presence of simulated biomass-derived syngas. It was found that highly dispersed ~2 nm Rh and ~1 nm Ir clusters were formed on the MgAl2O4 spinel support. Scanning Transition Electron Microscopy (STEM) images show that excellent dispersion was maintained even under challenging high temperature conditions (e.g. at 850°C in the presence of steam) while Ir and Rh catalysts supported on Al2O3 were observed to sinter at increased rates under the same conditions. These observations were further confirmed by ab initio molecular dynamics (AIMD) simulations which find that ~1 nm Rh and Ir particles (50-atom cluster) bind strongly to the MgAl2O4 surfaces via a redox process leading to a strong metal-support interaction, thus helping anchor the metal clusters and reduce the tendency to sinter. Density functional theory (DFT) calculations suggest that these supported smaller Rh and Ir particles have a lower work function than larger more bulk-like ones, which enables them to activate both water and methane more effectively than larger particles, yet have a minimal influence on the relative stability of coke precursors. In addition, theoretical mechanistic studies were used to probe the relationship between structure and reactivity. Consistent with the experimental observations, our theoretical modeling results also suggest that the small spinel-supported Ir particle catalyst is more active than the counterpart of Rh catalyst for SMR. This work was financially supported by the United States Department of Energy (DOE)’s Bioenergy Technologies Office (BETO) and performed at the Pacific Northwest National Laboratory (PNNL). PNNL is a multi-program national laboratory operated for DOE by Battelle Memorial Institute. Computing time was granted by a user proposal at the Molecular Science Computing Facility in the William R. Wiley Environmental Molecular Sciences Laboratory (EMSL) located at PNNL. Part of the computational time was provided by the National Energy Research Scientific Computing Center (NERSC).

  6. Preparation of PtNi Nanoparticles for the Electrocatalytic Oxidation of Methanol

    E-Print Network [OSTI]

    Deivaraj, T.C.

    Carbon supported PtNi nanoparticles were prepared by hydrazine reduction of Pt and Ni precursor salts under different conditions, namely by conventional heating (PtNi-1), by prolonged reaction at room temperature (PtNi-2) ...

  7. Blending Cr2O3 into a NiO-Ni electrocatalyst for sustained water splitting

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gong, Ming; Zhou, Wu; Kenney, Michael James; Kapusta, Rich; Cowley, Sam; Wu, Yingpeng; Lu, Bingan; Lin, Meng -Chang; Wang, Di -Yan; Yang, Jiang; et al

    2015-08-24

    The rising H2 economy demands active and durable electrocatalysts based on low-cost, earth-abundant materials for water electrolysis/photolysis. Here we report nanoscale Ni metal cores over-coated by a Cr2O3-blended NiO layer synthesized on metallic foam substrates. The Ni@NiO/Cr2O3 triphase material exhibits superior activity and stability similar to Pt for the hydrogen-evolution reaction in basic solutions. The chemically stable Cr2O3 is crucial for preventing oxidation of the Ni core, maintaining abundant NiO/Ni interfaces as catalytically active sites in the heterostructure and thus imparting high stability to the hydrogen-evolution catalyst. The highly active and stable electrocatalyst enables an alkaline electrolyzer operating at 20more »mA cm–2 at a voltage lower than 1.5 V, lasting longer than 3 weeks without decay. Thus, the non-precious metal catalysts afford a high efficiency of about 15 % for light-driven water splitting using GaAs solar cells.« less

  8. Hazard assessment in geothermal exploration: The case of Mt. Parker, Southern Philippines

    SciTech Connect (OSTI)

    Delfin, F.G. Jr.; Salonga, N.D.; Bayon, F.E.B.

    1996-12-31

    Hazard assessment of the Mt. Parker geothermal prospect, conducted in parallel with the surface exploration from 1992 to 1994, was undertaken to determine the long-term suitability of the prospect for development. By comparison with other acidic magmatic-hydrothermal systems in the Philippines, the geochemical data indicated minimal input of acidic magmatic fluids into Mt. Parker`s hydrothermal system. This system was regarded to be a neutral-pH and high-enthalpy chloride reservoir with temperature of at least 200-250{degrees}C. These favorable geochemical indications contrasted sharply with the C-14 and volcanological data indicating a shallow magmatic body with a potential for future eruption. This hazard led PNOC EDC to discontinue the survey and abandon the prospect by late 1994. On September 6, 1995, a flashflood of non-volcanic origin from the caldera lake killed nearly 100 people on the volcano`s northwestern flank.

  9. Energy absorption in Ni-Mn-Ga/ polymer composites

    E-Print Network [OSTI]

    Feuchtwanger, Jorge

    2006-01-01

    In recent years Ni-Mn-Ga has attracted considerable attention as a new kind of actuator material. Off-stoichiometric single crystals of Ni2MnGa can regularly exhibit 6% strain in tetragonal martensites and orthorhombic ...

  10. Carbon Nanotube Growth Using Ni Catalyst in Different Layouts

    E-Print Network [OSTI]

    Nguyen, H. Q.

    Vertically aligned carbon nanotubes have been grown using Ni as catalyst by plasma enhanced chemical vapor deposition system (PECVD) in various pre-patterned substrates. Ni was thermally evaporated on silicon substrates ...

  11. Superconducting and magnetic properties of Sr?Ir?Sn??

    SciTech Connect (OSTI)

    Biswas, P. K. [Paul Scherrer Inst. (PSI), Villigen (Switzerland); Wang, Kefeng [Brookhaven National Lab. (BNL), Upton, NY (United States); Amato, A. [Paul Scherrer Inst. (PSI), Villigen (Switzerland); Khasanov, R. [Paul Scherrer Inst. (PSI), Villigen (Switzerland); Luetkens, H. [Paul Scherrer Inst. (PSI), Villigen (Switzerland); Petrovic, C. [Brookhaven National Lab. (BNL), Upton, NY (United States); Cook, R. M. [Univ. of Warwick, Coventry (United Kingdom); Lees, M. R. [Univ. of Warwick, Coventry (United Kingdom); Morenzoni, E. [Paul Scherrer Inst. (PSI), Villigen (Switzerland)

    2014-10-01

    Magnetization and muon spin relaxation or rotation (µSR) measurements have been performed to study the superconducting and magnetic properties of Sr?Ir?Sn??. From magnetization measurements the lower and upper critical fields of Sr?Ir?Sn?? are found to be 81(1) Oe and 14.4(2) kOe, respectively. Zero-field µSR data show no sign of any magnetic ordering or weak magnetism in Sr?Ir?Sn??. Transverse-field µSR measurements in the vortex state provided the temperature dependence of the magnetic penetration depth ?. The dependence of ??˛ with temperature is consistent with the existence of single s-wave energy gap in the superconducting state of Sr?Ir?Sn?? with a gap value of 0.82(2) meV at absolute zero temperature. The magnetic penetration depth at zero temperature ?(0) is 291(3) nm. The ratio ?(0)/kBTc = 2.1(1) indicates that Sr?Ir?Sn?? should be considered as a strong-coupling superconductor.

  12. Superconducting and magnetic properties of Sr?Ir?Sn??

    SciTech Connect (OSTI)

    Biswas, P. K.; Wang, Kefeng; Amato, A.; Khasanov, R.; Luetkens, H.; Petrovic, C.; Cook, R. M.; Lees, M. R.; Morenzoni, E.

    2014-10-10

    Magnetization and muon spin relaxation or rotation (µSR) measurements have been performed to study the superconducting and magnetic properties of Sr?Ir?Sn??. From magnetization measurements the lower and upper critical fields of Sr?Ir?Sn?? are found to be 81(1) Oe and 14.4(2) kOe, respectively. Zero-field µSR data show no sign of any magnetic ordering or weak magnetism in Sr?Ir?Sn??. Transverse-field µSR measurements in the vortex state provided the temperature dependence of the magnetic penetration depth ?. The dependence of ??˛ with temperature is consistent with the existence of single s-wave energy gap in the superconducting state of Sr?Ir?Sn?? with a gap value of 0.82(2) meV at absolute zero temperature. The magnetic penetration depth at zero temperature ?(0) is 291(3) nm. The ratio ?(0)/kBTc = 2.1(1) indicates that Sr?Ir?Sn?? should be considered as a strong-coupling superconductor.

  13. Superconducting and magnetic properties of Sr?Ir?Sn??

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Biswas, P. K.; Wang, Kefeng; Amato, A.; Khasanov, R.; Luetkens, H.; Petrovic, C.; Cook, R. M.; Lees, M. R.; Morenzoni, E.

    2014-10-10

    Magnetization and muon spin relaxation or rotation (µSR) measurements have been performed to study the superconducting and magnetic properties of Sr?Ir?Sn??. From magnetization measurements the lower and upper critical fields of Sr?Ir?Sn?? are found to be 81(1) Oe and 14.4(2) kOe, respectively. Zero-field µSR data show no sign of any magnetic ordering or weak magnetism in Sr?Ir?Sn??. Transverse-field µSR measurements in the vortex state provided the temperature dependence of the magnetic penetration depth ?. The dependence of ??˛ with temperature is consistent with the existence of single s-wave energy gap in the superconducting state of Sr?Ir?Sn?? with a gap valuemore »of 0.82(2) meV at absolute zero temperature. The magnetic penetration depth at zero temperature ?(0) is 291(3) nm. The ratio ?(0)/kBTc = 2.1(1) indicates that Sr?Ir?Sn?? should be considered as a strong-coupling superconductor.« less

  14. Rock Sampling At Mt Ranier Area (Frank, 1995) | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page onRAPID/Geothermal/Exploration/ColoradoRemsenburg-Speonk, NewMichigan: Energy Resources JumpMt Ranier Area (Frank, 1995)

  15. EC305 Problem Set 1 1. Let x(t) = m(t) cos 2fct, where m(t) is a real lowpass signal with bandwidth W and

    E-Print Network [OSTI]

    Bhashyam, Srikrishna

    EC305 Problem Set 1 1. Let x(t) = m(t) cos 2fct, where m(t) is a real lowpass signal with bandwidth a bandpass signal x(t) = m1(t) cos 2fct - m2(t) sin 2fct. (a) Determine the in-phase and quadrature components of this signal when the local os- cillators used have a phase offset of , i.e., they are cos (2fct

  16. Tidally dominated depositional environment for the Mt. Simon Sandstone in central Illinois

    SciTech Connect (OSTI)

    Sargent, M.L.; Lasemi, Z. (Illinois State Geological Survey, Champaign, IL (United States))

    1993-03-01

    Several hundred feet of core from the upper part of the Mt. Simon in central Illinois have been examined macroscopically. Grain sizes and their systematics, bedding characteristics, sedimentary structures, and relationships among beds show that the upper Mt. Simon Sandstone is composed of a series of fining-upward cycles up to 10 m (30 feet) thick. A typical cycle consists, in ascending order, of a sandy subtidal facies, a mixed sand and mud intertidal-flat facies, and a muddy upper tidal-flat facies upward through the succession, the maximum and average grain size becomes progressively finer and the cycles thinner. The lower sandstone of each cycle contains beds that are massive to cross bedded and cross laminated; some beds show scoured reactivation surfaces. A few cycles contain a middle unit characterized by flaser and lenticular bedding and abundant mudcracks. Mudcracks also are common in the shale beds at the top of each cycle. Sedimentary structures such as reactivation surfaces, flaser and lenticular bedding, and mudcracks suggest that these cycles were deposited in peritidal environments. The presence of Skolithos in some cycles suggests very shallow marine conditions. The within-cycle upward fining is caused by regression or progradation that reflects a progressive decrease in current velocity from subtidal to intertidal parts of the tidal flat. Frequent flooding of the tidal flat resulted in repeated fining-upward cycles within the upper part of the Mt. Simon Sandstone.

  17. Oxygen Adsorption on Au–Ni(111) Surface Alloys

    E-Print Network [OSTI]

    Lee, Jae-Gook

    Molecular O[subscript 2] dissociates upon interaction with a Ni(111) surface, as the spatial and energetic overlap between the Ni 3d electrons and the O[subscript 2] antibonding orbitals is quite favorable. On a Au–Ni(111) ...

  18. High Temperature coatings based on {beta}-NiAI

    SciTech Connect (OSTI)

    Severs, Kevin

    2012-07-10

    High temperature alloys are reviewed, focusing on current superalloys and their coatings. The synthesis, characerization, and oxidation performance of a NiAl–TiB{sub 2} composite are explained. A novel coating process for Mo–Ni–Al alloys for improved oxidation performance is examined. The cyclic oxidation performance of coated and uncoated Mo–Ni–Al alloys is discussed.

  19. Application of Remote Sensing Technology and Ecological Modeling of Forest Carbon Stocks in Mt. Apo Natural Park, Philippines 

    E-Print Network [OSTI]

    Leal, Ligaya Rubas

    2015-01-23

    This dissertation work explored the application of remote sensing technology for the assessment of forest carbon storage in Mt. Apo Natural Park. Biomass estimation is traditionally conducted using destructive sampling with high levels...

  20. Sequence Stratigraphy and Detrital Zircon Geochronology of Middle-Late Ordovician Mt. Wilson Quartzite, British Columbia, Canada 

    E-Print Network [OSTI]

    Hutto, Andrew Paul

    2012-07-16

    STRATIGRAPHY AND DETRITAL ZIRCON GEOCHRONOLOGY OF MIDDLE-LATE ORDOVICIAN MT. WILSON QUARTZITE, BRITISH COLUMBIA CANADA A Thesis by ANDREW PAUL HUTTO Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment... of the requirements for the degree of MASTER OF SCIENCE May 2012 Major Subject: Geology Sequence Stratigraphy and Detrital Zircon Geochronology of Middle-Late Ordovician Mt. Wilson...

  1. Giant monopole strength in Ni-58 

    E-Print Network [OSTI]

    Lui, YW; Clark, HL; Youngblood, David H.

    2000-01-01

    The strength distribution of the giant monopole resonance in Ni-58 has been measured from E-x = 10 to 35 MeV using small-angle scattering of 240-MeV alpha particles. E0 strength corresponding to 74(-12)(+22)% of the E0 EWSR was found between E-x...

  2. Low Dose IR Creates an Oncogenic Microenvironment by Inducing Premature

    SciTech Connect (OSTI)

    Yuan, Zhi-Min

    2013-04-28

    Introduction Much of the work addressing ionizing radiation-induced cellular response has been carried out mainly with the traditional cell culture technique involving only one cell type, how cellular response to IR is influenced by the tissue microenvironment remains elusive. By use of a three-dimensional (3D) co-culture system to model critical interactions of different cell types with their neighbors and with their environment, we recently showed that low-dose IR-induced extracellular signaling via the tissue environment affects profoundly cellular responses. This proposal aims at determining the response of mammary epithelial cells in a tissue-like setting.

  3. A Ni/surface-modified Diamond Composite Electroplating Coating on Superelastic NiTi Alloy as Potential Dental Bur Design

    E-Print Network [OSTI]

    Zheng, Yufeng

    A Ni/surface-modified Diamond Composite Electroplating Coating on Superelastic NiTi Alloy: Composite Electroplating; Surface-modified Diamond Particles; Interfacial Adhesion; NiTi alloy; Dental Bur into nickel coating, and its shank made of stainless steel. There are strong demands from the dentist

  4. In Situ XAS of Ni-W Hydrocracking Catalysts

    SciTech Connect (OSTI)

    Yang, N. [Argonne National Laboratory, Argonne, IL 60439 (United States); Mickelson, G. E.; Greenlay, N.; Bare, Simon R. [UOP LLC, Des Plaines, IL 60016 (United States); Kelly, S. D. [EXAFS Analysis, Bolingbrook, IL 60440 (United States)

    2007-02-02

    Ni-W based catalysts are very attractive in hydrotreating of heavy oil due to their high hydrogenation activity. In the present research, two catalyst samples, prepared by different methods, that exhibit significant differences in activity were sulfided in situ, and the local structure of the Ni and W were studied using X-ray absorption spectroscopy (XAS). The Ni XANES spectra were analyzed using a linear component fitting, and the EXAFS spectra of the WS2 platelets in the sulfided catalysts were modeled. The Ni and W are fully sulfided in the higher activity sample, and there are both unsulfided Ni ({approx}25%) and W (<10%) in the lower activity sample.

  5. Saving and accessing the old IR literature Donna Harman

    E-Print Network [OSTI]

    Hiemstra, Djoerd

    there are many scanning projects underway, such as Google books and the Open Library Alliance, these projects library for just us IR folks. The ACM digital library had little interest in what they called the "grey they maintain their library in a proprietary format that would not allow us to insert our own search engine (or

  6. Growth of graphene on Ir(111) Johann Coraux1

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    a renewed interest as a route towards high quality graphene prepared in a reproducible manner. Here weC) substrate has attracted much interest. Whatever the recent progress in the preparation of grapheneGrowth of graphene on Ir(111) Johann Coraux1 ,, Alpha T. N'Diaye1 §, Martin Engler1 , Carsten Busse

  7. Experiment 6. QUANTINTATIVE ANALYSIS OF XYLENES USING IR SPECTROSCOPY

    E-Print Network [OSTI]

    Nazarenko, Alexander

    with a syringe full of the solvent. Dry the cell. 2. Refill the clean, dry sample cell with solution #1 and run syringe for loading sealed infrared cells. 4. A 0.1 mm sealed IR cell. These cells are kept version of the baseline technique to the unknown and standards. II Sealed Cells. The sealed cells used

  8. Resources for Chinese-English Cross-Language IR

    E-Print Network [OSTI]

    Oard, Doug

    1 Resources for Chinese-English Cross-Language IR Douglas W. Oard College of Library supported in part by DARPA contract N6600197C8540 #12;2 Part I. Introduction Specific evaluation criteria for resource selection and for gap analysis to focus additional search for specific resources that could

  9. Periodic Accretion Instabilities in the Protostar L1634 IRS 7

    E-Print Network [OSTI]

    Hodapp, Klaus W

    2015-01-01

    The small molecular cloud Lynds 1634 contains at least three outflow sources. We found one of these, IRS 7, to be variable with a period of 37.14 +/- 0.04 days and an amplitude of approximately 2 mag in the Ks band. The light curve consists of a quiescent phase with little or no variation, and a rapid outburst phase. During the outburst phase, the rapid brightness variation generates light echoes that propagate into the surrounding molecular cloud, allowing a measurement of the distance to IRS 7 of 404 pc +/- 35 pc. We observed only a marginally significant change in the H - K color during the outburst phase. The K-band spectrum of IRS 7 shows CO bandhead emission but its equivalent width does not change significantly with the phase of the light curve. The H_2 1-0 S(1) line emission does not follow the variability of the continuum flux. We also used the imaging data for a proper motion study of the outflows originating from the IRS 7 and the FIR source IRAS 05173-0555, and confirm that these are indeed distin...

  10. Sr2IrO4: Gateway to cuprate superconductivity?

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Mitchell, J. F.

    2015-06-05

    High temperature superconductivity in cuprates remains a defining challenge in condensed matter physics. Recently, a new set of related compounds based on Ir rather than Cu has been discovered that may be on the verge of superconductivity themselves or be able to shed new light on the underlying interactions responsible for superconductivity in the cuprates.

  11. Testing a model of IR radiative losses Frank Vignola

    E-Print Network [OSTI]

    Oregon, University of

    losses associated with the pyranometers. High quality data from the Solar Radiation Research Laboratory Energy Laboratory (NREL) operates a very high quality solar monitoring station at the Solar Radiation Energy Laboratory ABSTRACT Thermopile pyranometers exhibit IR radiative losses that affect global

  12. Score Region Algebra: Building a Transparent XML-IR Database

    E-Print Network [OSTI]

    Hiemstra, Djoerd

    imple- mented the algebra operators in a prototype system on top of a low-level database kernel algebra framework on top of any low-level physical database engine or existing RDBMS, allowing a more sysScore Region Algebra: Building a Transparent XML-IR Database Vojkan Mihajlovi´c Henk Ernst Blok

  13. Havre, MT Natural Gas Pipeline Imports From Canada (Million Cubic Feet)

    Gasoline and Diesel Fuel Update (EIA)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustments (Billion Cubic Feet) Wyoming963 1.969CentralWellsMillion Cubic Feet) Havre, MT Natural Gas Pipeline

  14. Thermonuclear supernovae: probing magnetic fields by positrons and late-time IR line profiles

    SciTech Connect (OSTI)

    Penney, R.; Hoeflich, P., E-mail: phoeflich77@gmail.com, E-mail: rpenney@g.clemson.edu [Department of Physics, Florida State University, Tallahassee, FL 32305 (United States)

    2014-11-01

    We show the importance of ? and positron transport for the formation of late-time spectra in Type Ia supernovae (SNe Ia). The goal is to study the imprint of magnetic fields (B) on late-time IR line profiles, particularly the [Fe II] feature at 1.644 ?m, which becomes prominent two to three months after the explosion. As a benchmark, we use the explosion of a Chandrasekhar mass (M {sub Ch}) white dwarf (WD) and, specifically, a delayed detonation model that can reproduce the light curves and spectra for a Branch-normal SN Ia. We assume WDs with initial magnetic surface fields between 1 and 10{sup 9} G. We discuss large-scale dipole and small-scale magnetic fields. We show that positron transport effects must be taken into account for the interpretation of emission features starting at about one to two years after maximum light, depending on the size of B. The [Fe II] line profile and its evolution with time can be understood in terms of the overall energy input by radioactive decay and the transition from a ?-ray to a positron-dominated regime. We find that the [Fe II] line at 1.644 ?m can be used to analyze the overall chemical and density structure of the exploding WD up to day 200 without considering B. At later times, positron transport and magnetic field effects become important. After about day 300, the line profile allows one to probe the size of the B-field. The profile becomes sensitive to the morphology of B at about day 500. In the presence of a large-scale dipole field, a broad line is produced in M {sub Ch} mass explosions that may appear flat-topped or rounded depending on the inclination at which the SN is observed. Small or no directional dependence of the spectra is found for small-scale B. We note that narrow-line profiles require central {sup 56}Ni as shown in our previous studies. Persistent broad-line, flat-topped profiles require high-density burning, which is the signature of a WD close to M {sub Ch}. Good time coverage is required to separate the effects of optical depth, the size and morphology of B, and the aspect angle of the observer. The spectra require a resolution of about 500 km s{sup –1} and a signal-to-noise ratio of about 20%. Two other strong near-IR spectral features at about 1.5 and 1.8 ?m are used to demonstrate the importance of line blending, which may invalidate a kinematic interpretation of emission lines. Flat-topped line profiles between 300 and 400 days have been observed and reported in the literature. They lend support for M {sub Ch} mass explosions in at least some cases and require magnetic fields equal to or in excess of 10{sup 6} G. We briefly discuss the effects of the size and morphology of B on light curves, as well as limitations. We argue that line profiles are a more direct measurement of B than light curves because they measure both the distribution of {sup 56}Ni and the redistribution of the energy input by positrons rather than the total energy input. Finally, we discuss possible mechanisms for the formation of high B-fields and the limitations of our analysis.

  15. The IR-resummed Effective Field Theory of Large Scale Structures...

    Office of Scientific and Technical Information (OSTI)

    The IR-resummed Effective Field Theory of Large Scale Structures Citation Details In-Document Search Title: The IR-resummed Effective Field Theory of Large Scale Structures We...

  16. 5 Hz Catalytic Emissions FT-IR Monitoring during Lean-Rich Engine...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hz Catalytic Emissions FT-IR Monitoring during Lean-Rich Engine Cycles: Comparison to Reference Methods 5 Hz Catalytic Emissions FT-IR Monitoring during Lean-Rich Engine Cycles:...

  17. SESAM FT-IR: A Comparison of the R&D Workhorse to Standard Emission...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    SESAM FT-IR: A Comparison of the R&D Workhorse to Standard Emission Benches SESAM FT-IR: A Comparison of the R&D Workhorse to Standard Emission Benches Data for a number of...

  18. Novel Techniques for Single-Pulse Spectrum and Pulsewidth Measurements for an IR-FEL

    E-Print Network [OSTI]

    Leemans, W.P.

    2011-01-01

    ofthe LBL/Stanford diagnostics. FEL Thespectral andtemporalMeasurements for an IR-FEL W.P. Leemans, J.A. Edighoffer, K-Measurements for an IR-FEL* W. P. Leemans, J. A. Edighoffer,

  19. NiW and NiRu Bimetallic Catalysts for Ethylene Steam Reforming: Alternative Mechanisms for Sulfur Resistance

    SciTech Connect (OSTI)

    Rangan, M.; Yung, M. M.; Medlin, J. W.

    2012-06-01

    Previous investigations of Ni-based catalysts for the steam reforming of hydrocarbons have indicated that the addition of a second metal can reduce the effects of sulfur poisoning. Two systems that have previously shown promise for such applications, NiW and NiRu, are considered here for the steam reforming of ethylene, a key component of biomass derived tars. Monometallic and bimetallic Al{sub 2}O{sub 3}-supported Ni and W catalysts were employed for ethylene steam reforming in the presence and absence of sulfur. The NiW catalysts were less active than Ni in the absence of sulfur, but were more active in the presence of 50 ppm H{sub 2}S. The mechanism for the W-induced improvements in sulfur resistance appears to be different from that for Ru in NiRu. To probe reasons for the sulfur resistance of NiRu, the adsorption of S and C{sub 2}H{sub 4} on several bimetallic NiRu alloy surfaces ranging from 11 to 33 % Ru was studied using density functional theory (DFT). The DFT studies reveal that sulfur adsorption is generally favored on hollow sites containing Ru. Ethylene preferentially adsorbs atop the Ru atom in all the NiRu (111) alloys investigated. By comparing trends across the various bimetallic models considered, sulfur adsorption was observed to be correlated with the density of occupied states near the Fermi level while C{sub 2}H{sub 4} adsorption was correlated with the number of unoccupied states in the d-band. The diverging mechanisms for S and C{sub 2}H{sub 4} adsorption allow for bimetallic surfaces such as NiRu that enhance ethylene binding without accompanying increases in sulfur binding energy. In contrast, bimetallics such as NiSn and NiW appear to decrease the affinity of the surface for both the reagent and the poison.

  20. Relative Infrared (IR) and Terahertz (THz) Signatures of Common Explosives

    SciTech Connect (OSTI)

    Sharpe, Steven W.; Johnson, Timothy J.; Sheen, David M.; Atkinson, David A.

    2006-11-13

    Pacific Northwest National Laboratory (PNNL) has recently recorded the infrared (IR) and far-infrared (sometimes called the terahertz, THz) spectral signatures of four common explosives, in the condensed phase. The signatures of RDX, PETN, TNT and Tetryl were recorded both in the infrared and the THz domains, using Fourier transform infrared (FTIR) spectroscopy. Samples consisted of thin films and were made by depositing and subsequent evaporation of an acetone-explosive mixture. The complete spectrum spanned the range from 4,000 to 8 cm-1 at 2.0 cm-1 spectral resolution. Preliminary results in the infrared agree with those of previous workers, while the THz signatures are one order of magnitude weaker than the strongest IR bands.

  1. Microstructures in rapidly solidified Ni-Mo alloys

    SciTech Connect (OSTI)

    Jayaraman, N.; Tewari, S.N.; Hemker, K.J.; Glasgow, T.K.

    1985-01-01

    Ni-Mo alloys of compositions ranging from pure Ni to Ni-40 at % Mo were rapidly solidified by chill block melt spinning in vacuum and were examined by optical metallography, x-ray diffraction and transmission electron microscopy. Rapid solidification resulted in an extension of molybdenum solubility in nickel from 28 to 37.5 at %. A number of different phases and microstructures were seen at different depths (solidification conditions) from the quenched surface of the melt spun ribbons.

  2. Spatially Resolved Observations of the Galactic Center Source, IRS 21

    E-Print Network [OSTI]

    Tanner, A; Morris, M; Becklin, E E; Cotera, A S; Ressler, M E; Werner, M; Wizinowich, P

    2002-01-01

    We present diffraction-limited 2-25 micron images obtained with the W. M. Keck 10-m telescopes that spatially resolve the cool source, IRS 21, one of a small group of enigmatic objects in the central parsec of our Galaxy that have eluded classification. Modeled as a Gaussian, the azimuthally-averaged intensity profile of IRS 21 has a half-width half-maximum (HWHM) size of 650+/-80 AU at 2.2 microns and an average HWHM size of 1600+/-200 AU at mid-infrared wavelengths. These large apparent sizes imply an extended distribution of dust. The mid-infrared color map indicates that IRS 21 is a self-luminous source rather than an externally heated dust clump as originally suggested. The spectral energy distribution has distinct near- and mid-infrared components. A simple radiative transfer code, which simultaneously fits the near- and mid- infrared photometry and intensity profiles, supports a model in which the near-infrared radiation is scattered and extincted light from an embedded central source, while the mid-in...

  3. An IR study of pure and ion irradiated frozen formamide

    E-Print Network [OSTI]

    John R. Brucato; Giuseppa A. Baratta; Giovanni Strazzulla

    2006-04-28

    Context. The chemical evolution of formamide (HCONH2), a molecule of astrobiological interest that has been tentatively identified in interstellar ices and in cometary coma, has been studied in laboratory under simulated astrophysical conditions such as ion irradiation at low temperature. Aims. To evaluate the abundances of formamide observed in space or in laboratory, the integrated absorbances for all the principal IR features of frozen amorphous pure formamide deposited at 20 K were measured. Further evidence that energetic processing of ices occurring in space is extremely relevant both to astrochemistry and to astrobiology has been found, showing that new molecular species are synthesized by ion irradiation at a low temperature. Methods. Pure formamide were deposited at 20 K and IR transmission spectra measured for different ice thicknesses. The ice thickness was derived by looking at the interference pattern (intensity versus time) of a He-Ne laser beam reflected at an angle of 45 deg by the vacuum-film and film-substrate interfaces. Samples of formamide ice were irradiated with 200 keV H+ ions and IR spectra recorded at different ion fluences. Results. New molecules were synthesized among which are CO, CO2, N2O, isocyanic acid (HNCO), and ammonium cyanate (NH4+OCN-). Some of these species remain stable after warming up to room temperature.

  4. Uncooled thin film pyroelectric IR detector with aerogel thermal isolation

    SciTech Connect (OSTI)

    Ruffner, J.A.; Clem, P.G.; Tuttle, B.A. [and others

    1998-01-01

    Uncooled pyroelectric IR imaging systems, such as night vision goggles, offer important strategic advantages in battlefield scenarios and reconnaissance surveys. Until now, the current technology for fabricating these devices has been limited by low throughput and high cost which ultimately limit the availability of these sensor devices. We have developed and fabricated an alternative design for pyroelectric IR imaging sensors that utilizes a multilayered thin film deposition scheme to create a monolithic thin film imaging element on an active silicon substrate for the first time. This approach combines a thin film pyroelectric imaging element with a thermally insulating SiO{sub 2} aerogel thin film to produce a new type of uncooled IR sensor that offers significantly higher thermal, spatial, and temporal resolutions at a substantially lower cost per unit. This report describes the deposition, characterization and optimization of the aerogel thermal isolation layer and an appropriate pyroelectric imaging element. It also describes the overall integration of these components along with the appropriate planarization, etch stop, adhesion, electrode, and blacking agent thin film layers into a monolithic structure. 19 refs., 8 figs., 6 tabs.

  5. Oxidation-resistant, solution-processed plasmonic Ni nanochain...

    Office of Scientific and Technical Information (OSTI)

    solution-processed plasmonic Ni nanochain-SiOsub x (x < 2) selective solar thermal absorbers Citation Details In-Document Search Title: Oxidation-resistant,...

  6. Fusion of radioactive $^{132}$Sn with $^{64}$Ni

    E-Print Network [OSTI]

    J. F. Liang; D. Shapira; J. R. Beene; C. J. Gross; R. L. Varner; A. Galindo-Uribarri; J. Gomez del Campo; P. A. Hausladen; P. E. Mueller; D. W. Stracener; H. Amro; J. J. Kolata; J. D. Bierman; A. L. Caraley; K. L. Jones; Y. Larochelle; W. Loveland; D. Peterson

    2007-04-05

    Evaporation residue and fission cross sections of radioactive $^{132}$Sn on $^{64}$Ni were measured near the Coulomb barrier. A large sub-barrier fusion enhancement was observed. Coupled-channel calculations including inelastic excitation of the projectile and target, and neutron transfer are in good agreement with the measured fusion excitation function. When the change in nuclear size and shift in barrier height are accounted for, there is no extra fusion enhancement in $^{132}$Sn+$^{64}$Ni with respect to stable Sn+$^{64}$Ni. A systematic comparison of evaporation residue cross sections for the fusion of even $^{112-124}$Sn and $^{132}$Sn with $^{64}$Ni is presented.

  7. The combustion synthesis of Ni-Ti shape memory alloys

    SciTech Connect (OSTI)

    Moore, J.J.; Yi, H.C. (Colorado School of Mines, Golden (USA))

    1990-08-01

    Combustion synthesis of Ni-Ti-series shape-memory alloys yields both time and energy savings over conventional production methods. The solidified combustion synthesis process products have been cold-rolled into plates which exhibit the shape-memory effect, and it was noted that shape-memory transition temperatures may be tailored over a -78 to 460 C temperature range through the substitution of a third element for Ni; this element may be Pd or Fe. Accounts are given of the experimental combustion syntheses of Ni-Ti-Fe and Ti-Ni-Pd. 24 refs.

  8. Ni{sub 0.5}Zn{sub 0.5}Fe{sub 2}O{sub 4} nanoparticles dispersed in a SiO{sub 2} matrix synthesized by sol-gel processing

    SciTech Connect (OSTI)

    Pozo Lopez, G.; Condo, A.M.; Instituto Balseiro, Universidad Nacional de Cuyo, Av. Bustillo 9500, 8400, San Carlos de Bariloche; Consejo Nacional de Investigaciones Cientificas y Tecnicas ; Urreta, S.E.; Silvetti, S.P.; Aguirre, M. del C.; Instituto de Fisica Enrique Gaviola - CONICET

    2012-12-15

    (Ni{sub 0.5}Zn{sub 0.5}Fe{sub 2}O{sub 4})x/(SiO{sub 2})(100 - x) (x = 5, 20 and 50 wt.%) nanocomposites are synthesized by a sol-gel method using tetraethylorthosilicate (TEOS) and metallic nitrates as precursors, and by further annealing the powders for 1 h at 1273 K. X-ray diffraction (XRD), transmission electron microscopy (TEM), room temperature vibrating sample magnetometry (VSM) and SQUID measurements are employed for structural, morphological and magnetic sample characterization. For all the concentrations analyzed, the powder nanocomposites actually consist of spinel NiZn ferrite nanoparticles, dispersed in an amorphous silica matrix. TEM studies reveal different particle size distributions and particle morphologies for the three ferrite contents. The 20 wt.%-NiZn ferrite samples consist of nearly spherical nanoparticles, of about 8 nm, mainly superparamagnetic, well-dispersed in the amorphous silica matrix, while the 5 wt.%-NiZn ferrite samples exhibit a bimodal particle size distribution (5 and 30 nm) of single-domain nanoparticles embedded in the silica. In the 50 wt.%-NiZn ferrite samples, two particle families are observed: small round superparamagnetic nanoparticles of about 8 nm embedded in the amorphous silica matrix and large, non-spherical, ferrimagnetic ones, forming agglomerates outside the matrix. In all the synthesized samples, thickness fringes are observed inside some of the ferrite nanoparticles in dark field images. This contrast is explained using the theory of electron diffraction in a weak beam dark field (WBDF) condition and considering spherical ferrite nanoparticles. A large range of tailored magnetic properties varying the fraction, dispersion and mean size of the ferrimagnetic NiZn ferrite particles is obtained. Room temperature saturation magnetization values are found in the range 3.0-30.4 Am{sup 2}/kg for the different concentration samples. Coercivity values, between 1.9 and 7.6 mT, are more than 50% higher than those measured in powders of pure stoichiometric NiZn ferrite nanoparticles and somewhat higher than those reported for similar NiZn ferrite/SiO{sub 2} nanocomposites also synthesized by sol-gel processes. A correlation between the nanocomposite microstructure and the observed magnetic properties is established. - Highlights: Black-Right-Pointing-Pointer NiZn ferrite/SiO{sub 2} nanocomposites are successfully synthesized by a sol-gel route. Black-Right-Pointing-Pointer Depending on the NiZn ferrite content single or bimodal size distributions result. Black-Right-Pointing-Pointer Coercivity (1.9-7.6 mT) is 50% higher than in stoichiometric NiZn ferrite powders. Black-Right-Pointing-Pointer Microstructure and magnetic properties are correlated.

  9. Enhanced photocatalytic efficiency in zirconia buffered n-NiO/p-NiO single crystalline heterostructures by nanosecond laser treatment

    SciTech Connect (OSTI)

    Molaei, R.; Bayati, M. R.; Alipour, H. M.; Nori, S.; Narayan, J.

    2013-06-21

    We report the formation of NiO based single crystalline p-n junctions with enhanced photocatalytic activity induced by pulsed laser irradiation. The NiO epilayers were grown on Si(001) substrates buffered with cubic yttria-stabilized zirconia (c-YSZ) by using pulsed laser deposition. The NiO/c-YSZ/Si heterostructures were subsequently laser treated by 5 pulses of KrF excimer laser (pulse duration = 25 Multiplication-Sign 10{sup -9} s) at lower energies. Microstructural studies, conducted by X-ray diffraction ({theta}-2{theta} and {phi} techniques) and high resolution transmission electron microscope, showed a cube-on-cube epitaxial relationship at the c-YSZ/Si interface; the epitaxial relationship across the NiO/c-YSZ interface was established as NiO<111 > Double-Vertical-Line Double-Vertical-Line c-YSZ<001> and in-plane NiO<110> Double-Vertical-Line Double-Vertical-Line c-YSZ<100>. Electron microscopy studies showed that the interface between the laser annealed and the pristine region as well as the NiO/c-YSZ interface was atomically sharp and crystallographically continuous. The formation of point defects, namely oxygen vacancies and NiO, due to the coupling of the laser photons with the NiO epilayers was confirmed by XPS. The p-type electrical characteristics of the pristine NiO epilayers turned to an n-type behavior and the electrical conductivity was increased by one order of magnitude after laser treatment. Photocatalytic activity of the pristine (p-NiO/c-YSZ/Si) and the laser-annealed (n-NiO/p-NiO/c-YSZ/Si) heterostructures were assessed by measuring the decomposition rate of 4-chlorophenol under UV light. The photocatalytic reaction rate constants were determined to be 0.0059 and 0.0092 min{sup -1} for the as-deposited and the laser-treated samples, respectively. The enhanced photocatalytic efficiency was attributed to the suppressed charge carrier recombination in the NiO based p-n junctions and higher electrical conductivity. Besides, the oxygen vacancies ease the adsorption of 4-chlorophenol, hydroxyl, and water molecules to the surface. Thus, n-NiO/p-NiO single crystalline catalysts can be introduced as a potent candidate to remediate the environmental pollution.

  10. Energies of Electronic States of Ni (II) Ion in NiO-Al2O3 Catalyst Prepared by Impregnation

    SciTech Connect (OSTI)

    Obadovic, D. Z.; Kiurski, J.; Marinkovic-Neducin, R. P.

    2007-04-23

    The behavior of NiO-Al2O3 catalysts is strongly dependent on the preparation method, as well as on pretreatment conditions. In the present work we investigated the influences of Ni(II) ion on NiO-Al2O3 catalysts properties due to the preparation by impregnation method. Based on experimental diffuse reflectance spectroscopy (DRS) data of electronic d-d transitions of Ni (II) promoter ion the energies of electronic states in spinel-like structure were calculated, and the most probable scheme of molecular orbital have been proposed.

  11. SF 6432-NI (04-95)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home RoomPreservation of Fe(II) byMultidayAlumni > The EnergyRyanPhysics6/14/11 Page 1 of6432-NI

  12. Ni(II) Salts and 2-Propanol Effect Catalytic Reductive Coupling of Epoxides and Alkynes

    E-Print Network [OSTI]

    Beaver, Matthew G.

    A Ni-catalyzed reductive coupling of alkynes and epoxides using Ni(II) salts and simple alcohol reducing agents is described. Whereas previously reported conditions relied on Ni(cod)2 and Et3B, this system has several ...

  13. Continuous spin reorientation transition in epitaxially grown antiferromagnetic NiO thin films

    E-Print Network [OSTI]

    Li, J.

    2011-01-01

    along certain crystal axis [e.g. , NiO(100)]. Thusthe r 2 p S z 2, NiO ( dMgO ) / S NiO should be an approximation in the small limit.

  14. Solution-based thermodynamic modeling of the Ni-Al-Mo system...

    Office of Scientific and Technical Information (OSTI)

    (Al,Mo,Ni)0.75(Al,Mo,Ni)0.25. Thus, -fcc and -Ni3Al are modeled with a single Gibbs free energy function with appropriate treatment of the chemical ordering contribution. In...

  15. MT1-MMP promotes cell growth and ERK activation through c-Src and paxillin in three-dimensional collagen matrix

    SciTech Connect (OSTI)

    Takino, Takahisa; Tsuge, Hisashi; Ozawa, Terumasa [Department of Molecular Virology and Oncology, Cancer Research Institute, Kanazawa University, Kakuma-machi, Kanazawa 920-1192 (Japan)] [Department of Molecular Virology and Oncology, Cancer Research Institute, Kanazawa University, Kakuma-machi, Kanazawa 920-1192 (Japan); Sato, Hiroshi, E-mail: vhsato@kenroku.kanazawa-u.ac.jp [Department of Molecular Virology and Oncology, Cancer Research Institute, Kanazawa University, Kakuma-machi, Kanazawa 920-1192 (Japan)] [Department of Molecular Virology and Oncology, Cancer Research Institute, Kanazawa University, Kakuma-machi, Kanazawa 920-1192 (Japan)

    2010-06-11

    Membrane-type 1 matrix metalloproteinase (MT1-MMP) is essential for tumor invasion and growth. We show here that MT1-MMP induces extracellular signal-regulated kinase (ERK) activation in cancer cells cultured in collagen gel, which is indispensable for their proliferation. Inhibition of MT1-MMP by MMP inhibitor or small interfering RNA suppressed activation of focal adhesion kinase (FAK) and ERK in MT1-MMP-expressing cancer cells, which resulted in up-regulation of p21{sup WAF1} and suppression of cell growth in collagen gel. Cell proliferation was also abrogated by the inhibitor against ERK pathway without affecting FAK phosphorylation. MT1-MMP and integrin {alpha}{sub v}{beta}{sub 3} were shown to be involved in c-Src activation, which induced FAK and ERK activation in collagen gel. These MT1-MMP-mediated signal transductions were paxillin dependent, as knockdown of paxillin reduced cell growth and ERK activation, and co-expression of MT1-MMP with paxillin induced ERK activation. The results suggest that MT1-MMP contributes to proliferation of cancer cells in the extracellular matrix by activating ERK through c-Src and paxillin.

  16. Uranium hydrogeochemical and stream sediment reconnaissance of the Mt. Hayes NTMS quadrangle, Alaska

    SciTech Connect (OSTI)

    Not Available

    1981-05-01

    Results of a hydrogeochemical and stream sediment reconnaissance of the Mt. Hayes quadrangle, Alaska, are presented. In addition to this abbreviated data release, more complete data are available to the public in machine-readable form. In this data release are location data, field analyses, and Laboratory analyses of several different sample media. For the sake of brevity, many field site observations have not been included in this volume. These data are, however, available on the magnetic tape. Appendices A to D describe the sample media and summarize the analytical results for each medium. The data were subsetted by one of the Los Alamos National Laboratory (LANL) sorting programs into groups of stream sediment, lake sediment, stream water, lake water, and ground water samples. For each group which contains a sufficient number of observations, statistical tables, tables of raw data, and 1:1000000 scale maps of pertinent elements have been included in this report.

  17. Synthesis and electrochemical properties of NiO nanospindles

    SciTech Connect (OSTI)

    Zhou, Hai; Lv, Baoliang; Xu, Yao; Wu, Dong

    2014-02-01

    Graphical abstract: NiO nanospindles with a different electrochemical activity as compared to those previous reports were synthesized via an agglomeration–dissolution–recrystallization growth process without the addition of any surfactant. - Highlights: • NiO nanospindles were synthesized without the addition of any surfactant. • The agglomeration–dissolution–recrystallization growth process was used to explain the precursors’ formation process of the spindle-like NiO. • As-obtained spindle-like NiO showed a different electrochemical activity as compared to those previous reports. - Abstract: NiO nanospindles were successfully synthesized via a hydrothermal and post-treatment method. The as-synthesized nanospindles were about several hundred nanometers in width and about one micrometer in length. X-ray diffraction (XRD) analysis revealed that the spindle-like structure was cubic NiO phase crystalline. Scanning electron microscopy (SEM) and high-resolution transmission electron microscopy (HRTEM) analysis indicated that these NiO nanospindles were of single crystal nature. On the basis of time-dependent experiments, a possible agglomeration–dissolution–recrystallization growth process was proposed to explain the formation process of the spindle-like precursors. The cyclic voltammetry (CV) measurement showed that the as-prepared spindle-like NiO exhibited a pseudo-capacitance behavior.

  18. Lanthanide Al-Ni base Ericsson cycle magnetic refrigerants

    DOE Patents [OSTI]

    Gschneidner, K.A. Jr.; Takeya, Hiroyuki

    1995-10-31

    A magnetic refrigerant for a magnetic refrigerator using the Ericsson thermodynamic cycle comprises DyAlNi and (Gd{sub 0.54}Er{sub 0.46})AlNi alloys having a relatively constant {Delta}Tmc over a wide temperature range. 16 figs.

  19. Luminescence properties of the hybrid Si-Ni nanoparticles system

    E-Print Network [OSTI]

    Lalayan, A A; Movsesyan, H A

    2015-01-01

    The luminescence properties of the colloidal hybrid Si - Ni nanoparticles system fabricated in the pure water by pulsed laser ablation is considered. The red-shifted photoluminescence of this system because of the Stark effect in the Coulomb field of the charged Ni nanoparticles has been registered in the blue range of the spectrum.

  20. Theoretical Investigation of Iridium (II) Sulfides Ir2(?-S)2(PH3)4 AND Ir2(?-S)2(PPh3)4 

    E-Print Network [OSTI]

    Kritikou, Stella

    2014-02-27

    Density functional theory results of the electronic structure of an iridium sulfide, Ir_(2)S_(2)(PPh_(3))_(4) (2), are presented here, along with a discussion of the reaction mechanism of dihydrogen activation on this sulfide. This Ir (II...

  1. EIS-0092: Conversion to Coal, Holyoke Water Power Company, Mt. Tom Generating Station Unit 1 Holyoke, Hampden County, Massachusetts

    Broader source: Energy.gov [DOE]

    The Economic Regulatory Administration prepared this statement to assess the environmental impacts of prohibiting Unit 1 of the Mt. Tom Generation Station Unit 1 from using either natural gas or petroleum products as a primary energy source, which would result in the utility burning low-sulfur coal.

  2. The Mechanism of Inhibition of Antibody-based Inhibitors of Membrane-type Serine Protease 1 (MT-SP1)

    E-Print Network [OSTI]

    Craik, Charles S.

    The Mechanism of Inhibition of Antibody-based Inhibitors of Membrane-type Serine Protease 1 (MT-SP1, 600 16th St. Genentech Hall, San Francisco, CA 94143, USA The mechanisms of inhibition of two novel sc-SP1 at low pH, and is a standard mechanism inhibitor of the protease. The mechanisms of inhibition

  3. IR Spectral Bands and Performance | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIXsource History View NewGuam:on Openei | Open Energy2010) |OutlookINDEX JumpIR Spectral

  4. In situ XAS of Ni-W hydrocracking catalysts.

    SciTech Connect (OSTI)

    Yang, N.; Mickelson, G. E.; Greenlay, N.; Kelly, S. D.; Bare, S. R.; UOP LLC; EXAFS Analysis

    2007-01-01

    Ni-W based catalysts are very attractive in hydrotreating of heavy oil due to their high hydrogenation activity. In the present research, two catalyst samples, prepared by different methods, that exhibit significant differences in activity were sulfided in situ, and the local structure of the Ni and W were studied using X-ray absorption spectroscopy (XAS). The Ni XANES spectra were analyzed using a linear component fitting, and the EXAFS spectra of the WS{sub 2} platelets in the sulfided catalysts were modeled. The Ni and W are fully sulfided in the higher activity sample, and there are both unsulfided Ni ({approx}25%) and W (<10%) in the lower activity sample.

  5. Large exchange bias enhancement in (Pt(or Pd)/Co)/IrMn/Co trilayers with ultrathin IrMn thanks to interfacial Cu dusting

    SciTech Connect (OSTI)

    Vinai, G. [SPINTEC, UMR 8191 CEA/CNRS/UJF/Grenoble-INP, CEA/INAC, 17, rue des Martyrs, 38054 Grenoble (France); Crocus Technology, 4 Place Robert Schuman, 38054 Grenoble (France); Moritz, J. [Institut Jean Lamour, UMR 7198 CNRS - Université de Lorraine, Bd des Aiguillettes, BP 70239, F-54506 Vandoeuvre-les-Nancy Cedex (France); Bandiera, S. [Crocus Technology, 4 Place Robert Schuman, 38054 Grenoble (France); Prejbeanu, I. L.; Dieny, B. [SPINTEC, UMR 8191 CEA/CNRS/UJF/Grenoble-INP, CEA/INAC, 17, rue des Martyrs, 38054 Grenoble (France)

    2014-04-21

    The magnitude of exchange bias (H{sub ex}) at room temperature can be significantly enhanced in IrMn/Co and (Pt(or Pd)/Co)/IrMn/Co structures thanks to the insertion of an ultrathin Cu dusting layer at the IrMn/Co interface. The combination of trilayer structure and interfacial Cu dusting leads to a three-fold increase in H{sub ex} as compared to the conventional IrMn/Co bilayer structure, with an increased blocking temperature (T{sub B}) and a concave curvature of the temperature dependence H{sub ex}(T), ideal for improved Thermally Assisted-Magnetic Random Access Memory storage layer. This exchange bias enhancement is ascribed to a reduction of the spin frustration at the IrMn/Co interface thanks to interfacial Cu addition.

  6. Hydrides of CeNi/sub 5/, MmNi/sub 5/, Ca/sub 0/ /sub 2/(Ce/sub 0/ /sub 65/Mm/sub 0/ /sub 35/)/sub 0/ /sub 8/Ni/sub 5/, Ca/sub 0/ /sub 2/Ce/sub 0/ /sub 8/Ni/sub 5/, Ca/sub 0/ /sub 2/Mm/sub 0/ /sub 8/Ni/sub 5/, and mixed CeNi/sub 5//MmNi/sub 5/

    SciTech Connect (OSTI)

    Lakner, J.F.; Chow, T.S.

    1982-09-01

    Six intermetallic alloys (CeNi/sub 5/, MmNi/sub 5/, Ca/sub 0/ /sub 2/(Ce/sub 0/ /sub 65/Mm/sub 0/ /sub 35/)/sub 0/ /sub 8/Ni/sub 5/, Ca/sub 0/ /sub 2/Ce/sub 0/ /sub 8/Ni/sub 5/, Ca/sub 0/ /sub 2/Mm/sub 0/ /sub 8/Ni/sub 5/, and a mixed alloy, CeNi/sub 5//MmNi/sub 5/) were investigated with respect to their suitability to provide high hydrogen capacity and their potential for use in providing substantial hydrogen pressure at both low and high temperatures. A second phase of our investigation dealt with ball-milling and hydriding and dehydriding cycles to produce fine particles for use in hydride powder transfer studies. A summary of several Van't Hoff plots is also included for hydride-forming alloys.

  7. Effects of Cr and Ni on Interdiffusion and Reaction between U and Fe-Cr-Ni Alloys

    SciTech Connect (OSTI)

    K. Huang; Y. Park; L. Zhou; K.R. Coffey; Y.H. Sohn; B.H. Sencer; J. R. Kennedy

    2014-08-01

    Metallic U-alloy fuel cladded in steel has been examined for high temperature fast reactor technology wherein the fuel cladding chemical interaction is a challenge that requires a fundamental and quantitative understanding. In order to study the fundamental diffusional interactions between U with Fe and the alloying effect of Cr and Ni, solid-to-solid diffusion couples were assembled between pure U and Fe, Fe–15 wt.%Cr or Fe–15 wt.%Cr–15 wt.%Ni alloy, and annealed at high temperature ranging from 580 to 700 °C. The microstructures and concentration profiles that developed from the diffusion anneal were examined by scanning electron microscopy, and X-ray energy dispersive spectroscopy (XEDS), respectively. Thick U6Fe and thin UFe2 phases were observed to develop with solubilities: up to 2.5 at.% Ni in U6(Fe,Ni), up to 20 at.%Cr in U(Fe, Cr)2, and up to 7 at.%Cr and 14 at.% Ni in U(Fe, Cr, Ni)2. The interdiffusion and reactions in the U vs. Fe and U vs. Fe–Cr–Ni exhibited a similar temperature dependence, while the U vs. Fe–Cr diffusion couples, without the presence of Ni, yielded greater activation energy for the growth of intermetallic phases – lower growth rate at lower temperature but higher growth rate at higher temperature.

  8. Time dynamics of photothermal vs optoacoustic response in mid IR nanoscale biospectroscopy

    E-Print Network [OSTI]

    Tovee, Peter D; Kjoller, Kevin; Allsop, David; Weightman, Peter; Surman, Mark; Siggel-King, Michele R F; Wolski, Andy; Kolosov, Oleg V

    2015-01-01

    Infrared (IR) spectroscopy, a well established tool for chemical analysis of diverse materials, has significant potential in biomedical applications. While the spatial resolution of traditional IR spectroscopy is limited by the wavelength of the IR light to the few micrometres, it has been shown that nanoscale chemical analysis can be obtained by detecting IR induced local heating photothermal response via Scanning Thermal Microscopy (SThM) or local thermomechanical expansion using Atomic Force Microscopy (AFM). This paper explores the potential of a pulsed ps pulse duration high power free electron laser (FEL) light source for AFM-IR and SThM-IR spectroscopy employing standard AFM and SThM probes. The SThM-IR response was found to have a detrimental strong background signal due to the direct heating of the probe, whereas the AFM IR thermomechanical response allowed to eliminate such a problem for both top down and bottom up illuminations with the FEL IR source. The SThM IR characteristic response time was ap...

  9. The Chandra COSMOS Legacy survey: optical/IR identifications

    E-Print Network [OSTI]

    Marchesi, S; Elvis, M; Salvato, M; Brusa, M; Comastri, A; Gilli, R; Hasinger, G; Lanzuisi, G; Miyaji, T; Treister, E; Urry, C M; Vignali, C; Zamorani, G; Allevato, V; Cappelluti, N; Cardamone, C; Finoguenov, A; Griffiths, R E; Karim, A; Laigle, C; LaMassa, S M; Jahnke, K; Ranalli, P; Schawinski, K; Schinnerer, E; Silverman, J D; Smolcic, V; Suh, H; Trakhtenbrot, B

    2015-01-01

    We present the catalog of optical and infrared counterparts of the Chandra COSMOS-Legacy Survey, a 4.6 Ms Chandra program on the 2.2 square degrees of the COSMOS field, combination of 56 new overlapping observations obtained in Cycle 14 with the previous C-COSMOS survey. In this Paper we report the i, K, and 3.6 micron identifications of the 2273 X-ray point sources detected in the new Cycle 14 observations. We use the likelihood ratio technique to derive the association of optical/infrared (IR) counterparts for 97% of the X-ray sources. We also update the information for the 1743 sources detected in C-COSMOS, using new K and 3.6 micron information not available when the C-COSMOS analysis was performed. The final catalog contains 4016 X-ray sources, 97% of which have an optical/IR counterpart and a photometric redshift, while 54% of the sources have a spectroscopic redshift. The full catalog, including spectroscopic and photometric redshifts and optical and X-ray properties described here in detail, is availa...

  10. Qualification tests for {sup 192}Ir sealed sources

    SciTech Connect (OSTI)

    Iancso, Georgeta Iliescu, Elena Iancu, Rodica

    2013-12-16

    This paper describes the results of qualification tests for {sup 192}Ir sealed sources, available in Testing and Nuclear Expertise Laboratory of National Institute for Physics and Nuclear Engineering 'Horia Hulubei' (I.F.I.N.-HH), Romania. These sources had to be produced in I.F.I.N.-HH and were tested in order to obtain the authorization from The National Commission for Nuclear Activities Control (CNCAN). The sources are used for gammagraphy procedures or in gammadefectoscopy equipments. Tests, measurement methods and equipments used, comply with CNCAN, AIEA and International Quality Standards and regulations. The qualification tests are: 1. Radiological tests and measurements: dose equivalent rate at 1 m; tightness; dose equivalent rate at the surface of the transport and storage container; external unfixed contamination of the container surface. 2. Mechanical and climatic tests: thermal shock; external pressure; mechanic shock; vibrations; boring; thermal conditions for storage and transportation. Passing all tests, it was obtained the Radiological Security Authorization for producing the {sup 192}Ir sealed sources. Now IFIN-HH can meet many demands for this sealed sources, as the only manufacturer in Romania.

  11. The first principle study of Ni{sub 2}ScGa and Ni{sub 2}TiGa

    SciTech Connect (OSTI)

    Özduran, Mustafa; Turgut, Kemal; Arikan, Nihat; ?yigör, Ahmet; Candan, Abdullah

    2014-10-06

    We computed the electronic structure, elastic moduli, vibrational properties, and Ni{sub 2}TiGa and Ni{sub 2}ScGa alloys in the cubic L2{sub 1} structure. The obtained equilibrium lattice constants of these alloys are in good agreement with available data. In cubic systems, there are three independent elastic constants, namely C{sub 11}, C{sub 12} and C{sub 44}. We calculated elastic constants in L2{sub 1} structure for Ni{sub 2}TiGa and Ni{sub 2}ScGa using the energy-strain method. The electronic band structure, total and partial density of states for these alloys were investigated within density functional theory using the plane-wave pseudopotential method implemented in Quantum-Espresso program package. From band structure, total and projected density of states, we observed metallic characters of these compounds. The electronic calculation indicate that the predominant contributions of the density of states at Fermi level come from the Ni 3d states and Sc 3d states for Ni{sub 2}TiGa, Ni 3d states and Sc 3d states for Ni{sub 2}ScGa. The computed density of states at Fermi energy are 2.22 states/eV Cell for Ni{sub 2}TiGa, 0.76 states/eV Cell for Ni{sub 2}ScGa. The vibrational properties were obtained using a linear response in the framework at the density functional perturbation theory. For the alloys, the results show that the L2{sub 1} phase is unstable since the phonon calculations have imagine modes.

  12. Oblikoslovje v panonski nare?ni skupini

    E-Print Network [OSTI]

    Zorko, Zinka

    2010-01-01

    glagole: nes?, neseši, neset?; nesev?, neseta, nesete; nesem?, nesete, nes?t?; za atematske glagole: jesm?, jesi, jest?; jesv?, jesta, jeste; jesm?, jeste, s?t?. Slovenski knjižni jezik – tematska spregatev: nes-em, -eš, -e; -va, -ta, -ta; -mo, -te, -jo...; atematska spregatev: sem, si, je; sva, sta, sta; smo, ste, so. Prekmurš?ina (vsi glagoli se spregajo po temati?nem vzorcu): ne?s?:n, ne?s?:š, ne?s?:; ne?s?:va (m. sp.), ne?s?:ve (ž. sp.), ne?s?:ta, ne?s?:ta; ne?s?:mo, ne?s?:te, ne?s?:jo; ?sĺn, ?si, ?je; s...

  13. Ni/metal hydride secondary element

    DOE Patents [OSTI]

    Bauerlein, Peter

    2005-04-19

    A Ni/metal hydride secondary element having a positive nickel hydroxide electrode, a negative electrode having a hydrogen storage alloy, and an alkaline electrolyte, the positive electrode, provided with a three-dimensional metallic conductive structure, also contains an aluminum compound which is soluble in the electrolyte, in addition to nickel hydroxide and cobalt oxide. The aluminum compound is aluminum hydroxide and/or aluminum oxide, and the mass of the aluminum compound which is present in the positive bulk material mixture is 0.1 to 2% by weight relative to the mass of the nickel hydroxide which is present. In combination with aluminum hydroxide or aluminum oxide, the positive electrode further contains lanthanoid oxidic compounds Y.sub.2 O.sub.3, La.sub.2 O.sub.3 and Ca(OH).sub.2, as well as mixtures of these compounds.

  14. Asymptotic freedom and IR freezing in QCD: the role of gluon paramagnetism

    E-Print Network [OSTI]

    Yu. A. Simonov

    2010-11-24

    Paramagnetism of gluons is shown to play the basic role in establishing main properties of QCD: IR freezing and asymptotic freedom (AF). Starting with Polyakov background field approach the first terms of background perturbation theory are calculated and shown to ensure not only the classical result of AF but also IR freezing. For the latter only the confining property of the background is needed, and the effective mass entering the IR freezing logarithms is calculated in good agreement with phenomenology and lattice data.

  15. Graphene Monolayer Rotation on Ni(111) Facilities Bilayer Graphene Growth

    SciTech Connect (OSTI)

    Batzill M.; Sutter P.; Dahal, A.; Addou, R.

    2012-06-11

    Synthesis of bilayer graphene by chemical vapor deposition is of importance for graphene-based field effect devices. Here, we demonstrate that bilayer graphene preferentially grows by carbon-segregation under graphene sheets that are rotated relative to a Ni(111) substrate. Rotated graphene monolayer films can be synthesized at growth temperatures above 650 C on a Ni(111) thin-film. The segregated second graphene layer is in registry with the Ni(111) substrate and this suppresses further C-segregation, effectively self-limiting graphene formation to two layers.

  16. Effects of Process Conditions on Properties of Electroplated Ni Thin Films for Microsystem Applications

    E-Print Network [OSTI]

    Fleck, Norman A.

    Effects of Process Conditions on Properties of Electroplated Ni Thin Films for Microsystem, Southampton SO17 1QJ, United Kingdom The properties of electroplated Ni thin films have been systematically, micromotors, and pneumatic actuators.3-11 Ni and NiFe are the electroplated metals most commonly used for MEMS

  17. TiNi shape memory alloy thin films for microactuator application

    E-Print Network [OSTI]

    Fu, Yongqing

    TiNi films were prepared by co-sputtering TiNi target and a separate Ti target. Crystalline structure and phase transformation behaviors of TiNi films were investigated. Results showed that TiNi films had fine grain size ...

  18. Perpendicular magnetic anisotropy in ion beam sputtered Co/Ni multilayers

    E-Print Network [OSTI]

    Rasin, Boris

    2009-01-01

    Co/Ni multilayers display perpendicular magnetic anisotropy and have applications in magnetic devices that could lead to a large increase in the density of magnetic storage. Co/Ni 10-(2 Ĺ Co/ 8Ĺ Ni) and 10-(2 Ĺ Co/ 4 Ĺ Ni) ...

  19. IR ranking proposal and new beam parameter sets for the LHC upgrade the view of HHH

    E-Print Network [OSTI]

    Scandale, Walter

    2007-01-01

    We propose a ranking for the interaction-region (IR) optics based on the presentations and results from the first two days of the LUMI’06 workshop.

  20. Platinum Monolayer on IrFe Core–Shell Nanoparticle Electrocatalysts for the Oxygen Reduction Reaction

    SciTech Connect (OSTI)

    Sasaki K.; Kuttiyiel, K.A.; Su, D.; Adzic, R.R.

    2012-04-19

    We synthesized high activity and stability platinum monolayer on IrFe core-shell nanoparticle electrocatalysts. Carbon-supported IrFe core-shell nanoparticles were synthesized by chemical reduction and subsequent thermal annealing. The formation of Ir shells on IrFe solid-solution alloy cores has been verified by scanning transmission electron microscopy coupled with energy-loss spectroscopy (EELS) and in situ X-ray absorption spectroscopy. The Pt monolayers were deposited on IrFe core-shell nanoparticles by galvanic replacement of underpotentially deposited Cu adatoms on the Ir shell surfaces. The specific and Pt mass activities for the ORR on the Pt monolayer on IrFe core-shell nanoparticle electrocatalyst are 0.46 mA/cm{sup 2} and 1.1 A/mg{sub Pt}, which are much higher than those on a commercial Pt/C electrocatalyst. High durability of Pt{sub ML}/IrFe/C has also been demonstrated by potential cycling tests. These high activity and durability observed can be ascribed to the structural and electronic interaction between the Pt monolayer and the IrFe core-shell nanoparticles.

  1. Evaluation of PC-ISO for customized, 3D printed, gynecologic 192Ir HDR brachytherapy applicators

    E-Print Network [OSTI]

    2015-01-01

    equiva- lent to water within the energy range of interest,properties to water at 192 Ir energies to be compatible with

  2. Application of cluster-plus-glue-atom model to barrierless Cu–Ni–Ti and Cu–Ni–Ta films

    SciTech Connect (OSTI)

    Li, Xiaona, E-mail: lixiaona@dlut.edu.cn; Ding, Jianxin; Wang, Miao; Dong, Chuang [Key Laboratory of Materials Modification by Laser, Ion and Electron Beams (Dalian University of Technology), Ministry of Education, Dalian 116024 (China); Chu, Jinn P. [Department of Materials Science and Engineering, National Taiwan University of Science and Technology, Taipei 10607, Taiwan (China)

    2014-11-01

    To improve the thermal stability of copper and avoid its diffusion into surrounding dielectrics or interfacial reactions with them, the authors applied the cluster-plus-glue-atom model to investigate barrierless Cu–Ni–M (M?=?Ti or Ta) seed layers. The dissolution of the third element (Ti or Ta) in the Cu lattice with the aid of Ni significantly improved the thermal stability of the Cu seed layer. The appropriate M/Ni (M?=?Ti or Ta) ratio was selected to obtain a low resistivity: the resistivity was as low as 2.5??? cm for the (Ti{sub 1.5/13.5}Ni{sub 12/13.5}){sub 0.3}Cu{sub 99.7} film and 2.8??? cm for the (Ta{sub 1.1/13.1}Ni{sub 12/13.1}){sub 0.4}Cu{sub 99.6} film after annealing at 500?°C for 1?h. After annealing at 500?°C for 40?h, the two films remained stable without forming a Cu{sub 3}Si compound. The authors confirmed that the range of applications of the cluster-plus-glue-atom model could be extended. Therefore, a third element M with negative enthalpies of mixing with both Cu and Ni could be selected, under the premise that the mixing enthalpy of M–Ni is more negative than that of M–Cu.

  3. Ni(NiO)/single-walled carbon nanotubes composite: Synthesis of electro-deposition, gas sensing property for NO gas and density functional theory calculation

    SciTech Connect (OSTI)

    Li, Li; Zhang, Guo; Chen, Lei; Bi, Hong-Mei; Shi, Ke-Ying

    2013-02-15

    Graphical abstract: The Ni(NiO)/semiconducting single-walled carbon nanotubes composite collected from the cathode after electro-deposition shows a high sensitivity to low-concentration NO gas at room temperature (18 °C). Display Omitted Highlights: ? Ni(NiO) nanoparticles were deposited on semiconducting SWCNTs by electro-deposition. ? Ni(NiO)/semiconducting SWCNTs film shows a high sensitivity to NO gas at 18 °C. ?Theoretical calculation reveals electron transfer from SWCNTs to NO via Ni. -- Abstract: Single-walled carbon nanotubes which contains metallic SWCNTs (m-SWCNTs) and semiconducting SWCNTs (s-SWCNTs) have been obtained under electric arc discharge. Their separation can be effectively achieved by the electro-deposition method. The Ni(NiO)/s-SWCNTs composite was found on cathode where Ni was partially oxidized to NiO at ambient condition with Ni(NiO) nanoparticles deposited uniformly on the bundles of SWCNTs. These results were confirmed by Raman spectra, transmission electron microscopy (TEM), scanning electron microscopy (SEM), UV–vis–NIR and TG characterizations. Furthermore, investigation of the gas sensing property of Ni(NiO)/s-SWCNTs composite film to NO gas at 18 °C demonstrated the sensitivity was approximately 5% at the concentration of 97 ppb. Moreover, density functional theory (DFT) calculations were performed to explore the sensing mechanism which suggested the adsorption of NO molecules onto the composite through N–Ni interaction as well as the proposition of electron transfer mechanisms from SWCNTs to NO via the Ni medium.

  4. $^{64}$Ni+$^{64}$Ni fusion reaction calculated with the density-constrained time-dependent Hartree-Fock formalism

    E-Print Network [OSTI]

    A. S. Umar; V. E. Oberacker

    2007-09-25

    We study fusion reactions of the $^{64}$Ni+$^{64}$Ni system using the density-constrained time-dependent Hartree-Fock (TDHF) formalism. In this formalism the fusion barriers are directly obtained from TDHF dynamics. In addition, we incorporate the entrance channel alignments of the slightly deformed (oblate) $^{64}$Ni nuclei due to dynamical Coulomb excitation. We show that alignment leads to a fusion barrier distribution and alters the naive picture for defining which energies are actually sub-barrier. We also show that core polarization effects could play a significant role in fusion cross section calculations.

  5. Applications of stable isotopes in hydrological studies of Mt. Apo geothermal field, Philippines

    SciTech Connect (OSTI)

    Salonga, N.D.; Aragon, G.M.; Nogara, J.B.; Sambrano, B.G.

    1996-12-31

    The local precipitation in Mt. Apo is depleted of heavy isotopes owing to high elevation and landward location of the field. Rainwaters infiltrate the shallow grounds, circulate in short distances with almost no interaction with the host bed rocks, and effuse in the surface as cold springs. Lakes and rivers are affected by surface evaporation while the acid SO{sub 4} springs are affected by both evaporation and steam-heating. Only the neutral-pH Cl springs have the signature of the deep thermal fluids. The parent fluids of the deep thermal brine contain Cl of 4,800 to 5,000 mg/kg, {delta}{sup 18}O of -4.62 to -4.13 {per_thousand} and {delta}{sup 2}H of -60.0 to -57.8 {per_thousand}. Inside the Sandawa Collapse, boiling of the parent fluids resulted in a two-phase reservoir with lighter isotope contents. The thermal fluids laterally flow towards the west where they are affected by cooling and mixing of cold waters. Deep water recharge has {delta}{sup 18}O of -10.00 {per_thousand} and {delta}{sup 2}H = -61.20 {per_thousand} which come from the upper slopes of Sandawa Collapse (1580-1700 mASL).

  6. Four-year prospective study of the respiratory effects of volcanic ash from Mt. St. Helens

    SciTech Connect (OSTI)

    Buist, A.S.; Vollmer, W.M.; Johnson, L.R.; Bernstein, R.S.; McCamant, L.E.

    1986-04-01

    This report describes the 4-yr follow-up of 712 loggers exposed over an extended period to varying levels of fresh volcanic ash from the 1980 eruptions of Mt. St. Helens. Concerns related to the irritant effect the ash might have on the airways and also to its fibrogenic potential if exposures were intense and continued over many years. Our subjects were divided into 3 groups: high, low, and no exposure. Baseline testing was begun in June 1980, 1 month after the major eruption, and follow-up testing continued on an annual basis through 1984; 88% of the loggers have been tested at least 3 times. Analysis of lung function data showed that a significant, exposure-related decline in FEV1 occurred during the first year after the eruption. The decline was short-lived, however, and by 1984 the differences between exposure groups were no longer significant. Self-reported symptoms of cough, phlegm, and wheeze showed a similar pattern. No ash-related changes were seen in chest roentgenograms taken in 1980 and in 1984. Our findings are consistent with the hypothesis that the inhaled ash caused mucus hypersecretion and/or airway inflammation that reversed when the exposure levels decreased. The ash levels to which the loggers were exposed were low compared with permissible occupational levels for nuisance dusts, but generally higher than the total suspended particulate levels permissible in ambient air.

  7. CO2 flood tests on whole core samples of the Mt. Simon sandstone, Illinois Basin

    SciTech Connect (OSTI)

    O'Connor, William K.; Rush, Gilbert E.

    2005-09-01

    Geological sequestration of CO2, whether by enhanced oil recovery (EOR), coal-bed methane (CBM) recovery, or saline aquifer injection is a promising near-term sequestration methodology. While tremendous experience exists for EOR, and CBM recovery has been demonstrated in existing fields, saline aquifer injection studies have only recently been initiated. Studies evaluating the availability of saline aquifers suitable for CO2 injection show great potential, however, the long-term fate of the CO2 injected into these ancient aqueous systems is still uncertain. For the subject study, a series of laboratory-scale CO2 flood tests were conducted on whole core samples of the Mt. Simon sandstone from the Illinois Basin. By conducting these tests on whole core samples rather than crushed core, an evaluation of the impact of the CO2 flood on the rock mechanics properties as well as the geochemistry of the core and brine solution has been possible. This empirical data could provide a valuable resource for the validation of reservoir models under development for these engineered CO2 systems.

  8. Electrodeposition of amorphous matrix Ni-W/WpĚł composites

    E-Print Network [OSTI]

    Jenket, Donald R. (Donald Robert)

    2005-01-01

    An amorphous Ni-W alloy matrix was incorporated with W particulate through two types of electrodeposition. The plating bath for the electrodeposition contained nickel sulfate, sodium tungstate, sodium citrate, ammonium ...

  9. Double dumbbell shaped AgNi alloy by pulsed electrodeposition

    SciTech Connect (OSTI)

    Dhanapal, K.; Vasumathi, M.; Santhi, Kalavathy [Materials Science Centre, Department of Nuclear Physics, University of Madras, Guindy Campus, Chennai 600 025 (India); Narayanan, V., E-mail: stephen-arum@hotmail.com; Stephen, A., E-mail: stephen-arum@hotmail.com [Department of Inorganic Chemistry, University of Madras, Guindy Campus, Chennai-600 025 (India)

    2014-01-28

    Silver-Nickel is the well-known thermally immiscible system that makes them quite complex for the formation of alloy. This kind of alloy can be attained from electrodeposition method. In the present work, AgNi alloy was synthesized by pulsed electrodeposition in a single bath two electrode system with the use of anodic alumina membrane. The prepared AgNi alloy and pure Ag were characterized with X-ray Diffraction (XRD) for structural confirmation, Scanning Electron Microscopy (SEM) for morphological, and magnetic properties by Vibrating Sample Magnetometer, respectively. The X-ray Diffraction study shows the formation of cubic structure for pure Ag. SEM analysis reveals the double dumbbell morphology for AgNi alloy and spherically agglomeration for pure silver. Hysteresis behaviour from VSM measurement indicates that the AgNi alloy have good ferro-magnetic properties.

  10. TiNi-based thin films for MEMS applications

    E-Print Network [OSTI]

    Fu, Yongqing

    In this paper, some critical issues and problems in the development of TiNi thin films were discussed, including preparation and characterization considerations, residual stress and adhesion, frequency improvement, fatigue ...

  11. Grain boundary relaxation strengthening of nanocrystalline Ni–W alloys

    E-Print Network [OSTI]

    Rupert, Timothy J.

    The hardening effect caused by the relaxation of nonequilibrium grain boundary structure has been explored in nanocrystalline Ni–W alloys. First, the kinetics of relaxation hardening are studied, showing that higher annealing ...

  12. Assignment 4 BS4a Actuarial Science Oxford MT 2011 IX A.4 Inflation, taxation and project appraisal

    E-Print Network [OSTI]

    Winkel, Matthias

    Assignment 4 ­ BS4a Actuarial Science ­ Oxford MT 2011 IX A.4 Inflation, taxation and project are indexed by reference to the value of a retail price index with a time lag of 8 months. The retail price index value in September 1996 was Q(-8/12) = 200 and in March 1997 was Q(-2/12) = 206. The issue price

  13. Anomalous magnetic behavior in nanocomposite materials of reduced graphene oxide-Ni/NiFe{sub 2}O{sub 4}

    SciTech Connect (OSTI)

    Kollu, Pratap E-mail: anirmalagrace@vit.ac.in; Prathapani, Sateesh; Varaprasadarao, Eswara K.; Mallick, Sudhanshu; Bahadur, D. E-mail: anirmalagrace@vit.ac.in; Santosh, Chella; Grace, Andrews Nirmala E-mail: anirmalagrace@vit.ac.in

    2014-08-04

    Magnetic Reduced Graphene Oxide-Nickel/NiFe{sub 2}O{sub 4} (RGO-Ni/NF) nanocomposite has been synthesized by one pot solvothermal method. Respective phase formations and their purities in the composite are confirmed by High Resolution Transmission Electron Microscope and X Ray Diffraction, respectively. For the RGO-Ni/NF composite material finite-size effects lead to the anomalous magnetic behavior, which is corroborated in temperature and field dependent magnetization curves. Here, we are reporting the behavior of higher magnetization values for Zero Field Cooled condition to that of Field Cooled for the RGO-Ni/NF nanocomposite. Also, the observed negative and positive moments in Hysteresis loops at relatively smaller applied fields (100?Oe and 200?Oe) are explained on the basis of surface spin disorder.

  14. Shape memory behavior of ultrafine grained NiTi and TiNiPd shape memory alloys 

    E-Print Network [OSTI]

    Kockar, Benat

    2009-05-15

    The cyclic instability in shape memory characteristics of NiTi-based shape memory alloys (SMAs), such as transformation temperatures, transformation and irrecoverable strains and transformation hysteresis upon thermal and ...

  15. Mechanism of Homogeneous Ir(III) Catalyzed Regioselective Arylation of Olefins

    E-Print Network [OSTI]

    Goddard III, William A.

    . On the basis of this mechanism, we suggest new catalysts expected to have improved activity. Initiation by reduction. Recently, Matsumoto2-4 and Periana5 reported the synthesis of a novel Ir complex, [Ir (turn- over-frequency (TOF) of 10-3 s-1 at 200 °C), but there are also problems with selectivity, cost

  16. Raman and IR spectra of butane: Anharmonic calculations and interpretation of room temperature spectra

    E-Print Network [OSTI]

    Potma, Eric Olaf

    Raman and IR spectra of butane: Anharmonic calculations and interpretation of room temperature-principles anharmonic calculations are carried out for the IR and Raman spectra of the CAH stretch- ing bands in butane.V. All rights reserved. 1. Introduction n-Butane is of great importance in several disciplines

  17. Monitoring Nonadiabatic Dynamics of the RNA Base Uracil by UV Pump-IR Probe Spectroscopy

    E-Print Network [OSTI]

    Mukamel, Shaul

    Monitoring Nonadiabatic Dynamics of the RNA Base Uracil by UV Pump-IR Probe Spectroscopy Benjamin P dynamics simulations of the UV pump-IR probe signal of the pyrimidine nucleobase uracil using a novel or visible pump-probe or photoelectron spectroscopy offer a high sub-100 fs temporal resolution.9

  18. NaIrO{sub 3}-A pentavalent post-perovskite

    SciTech Connect (OSTI)

    Bremholm, M.; Dutton, S.E.; Stephens, P.W.; Cava, R.J.

    2011-03-15

    Sodium iridium (V) oxide, NaIrO{sub 3,} was synthesized by a high pressure solid state method and recovered to ambient conditions. It is found to be isostructural with CaIrO{sub 3}, the much-studied structural analog of the high-pressure post-perovskite phase of MgSiO{sub 3}. Among the oxide post-perovskites, NaIrO{sub 3} is the first example with a pentavalent cation. The structure consists of layers of corner- and edge-sharing IrO{sub 6} octahedra separated by layers of NaO{sub 8} bicapped trigonal prisms. NaIrO{sub 3} shows no magnetic ordering and resistivity measurements show non-metallic behavior. The crystal structure, electrical and magnetic properties are discussed and compared to known post-perovskites and pentavalent perovskite metal oxides. -- Graphical abstract: Sodium iridium(V) oxide, NaIrO{sub 3}, synthesized by a high pressure solid state method and recovered to ambient conditions is found to crystallize as the post-perovskite structure and is the first example of a pentavalent ABO{sub 3} post-perovskite. Research highlights: {yields} NaIrO{sub 3} post-perovskite stabilized by pressure. {yields} First example of a pentavalent oxide post-perovskite. {yields} Non-metallic and non-magnetic behavior of NaIrO{sub 3}.

  19. ORIGINAL PAPER Thermal equation of state of CaIrO3 post-perovskite

    E-Print Network [OSTI]

    Duffy, Thomas S.

    ORIGINAL PAPER Thermal equation of state of CaIrO3 post-perovskite Wei Liu · Matthew L. Whitaker-Verlag 2011 Abstract The pressure­volume­temperature (P­V­T) relation of CaIrO3 post-perovskite (ppv for several oxide post-perovskites can be described approximately by the relationship KT0 = 5406.0/ V

  20. Evaluation of Methods to Correct for IR Loss in Eppley PSP Diffuse Measurements

    E-Print Network [OSTI]

    Oregon, University of

    is proportional to the incident solar radiation. Since both the black and white surfaces radiate approximately the same amount of IR, the measured solar radiation does not significantly suffer from the IR radiation irradiance were uncovered by the Atmospheric Radiation Measurement (ARM) Program during comparisons between

  1. Isotope correlations as a probe for freeze-out characterization: central 124Sn+64Ni, 112Sn+58Ni collisions

    E-Print Network [OSTI]

    E. Geraci; Reverse collaboration

    2003-10-15

    124Sn+64Ni and 112Sn+58Ni reactions at 35 AMeV incident energy were studied with the forward part of CHIMERA multi-detector. The most central collisions were selected by means of a multidimensional analysis. The characteristics of the source formed in the central collisions, as size, temperature and volume, were inspected. The measured isotopes of light fragments (3 <= Z <=8) were used to examine isotope yield ratios that provide information on the free neutron to proton densities.

  2. Electronic and structural influence of Ni by Pd substitution on the hydrogenation properties of TiNi

    SciTech Connect (OSTI)

    Emami, Hoda; Souques, Raphaeel; Crivello, Jean-Claude; Cuevas, Fermin

    2013-02-15

    In Ti (Ni,Pd) compounds, the hydrogen capacity and the stability of their hydrides decreases when Ni is partially substituted by larger in size Pd atoms. To understand this peculiar behaviour, the crystal structure of TiNi{sub 1-x}Pd{sub x}D{sub y} (x=0.1, 0.3 and 0.5) deuterides and the stability of TiNi{sub 1-x}Pd{sub x} (0{<=}x{<=}0.5) intermetallics and their hydrides have been investigated by both neutron diffraction experiments and Density Functional Theory (DFT) calculations. Neutron diffraction shows that at x=0.1 and 0.3, deuterium absorption induces tetragonal distortion in intermetallics sublattice whereas at x=0.5 the cubic symmetry is preserved. The structural properties and the heat of formation of TiNi{sub 1-x}Pd{sub x} (0{<=}x{<=}0.5) intermetallics and their hydrides have been determined by DFT. These results show that Pd substitution increases the stability of the intermetallics and decreases the stability of the hydrides, which confirms the rule of reverse stability. - Graphical abstract: Crystal structure of Ti(Ni,Pd)Hy hydrides in the I4/mmm space group. Highlights: Black-Right-Pointing-Pointer Neutron Diffraction and DFT calculations have been done on TiNi{sub 1-x}Pd{sub x}H{sub y} compounds. Black-Right-Pointing-Pointer Electronic effect of Pd substitution governs the hydrogenation properties in TiNi. Black-Right-Pointing-Pointer The rule of reverse stability in intermetallics/hydrides is observed with Pd substitution. Black-Right-Pointing-Pointer The hydrogen atoms in the I4/mmm structure prefer to occupy the 16n site.

  3. Dark Matter Particle Spectroscopy at the LHC: Generalizing M(T2) to Asymmetric Event Topologies

    SciTech Connect (OSTI)

    Konar, Partha; Kong, Kyoungchul; Matchev, Konstantin T.; Park, Myeonghun; /Florida U.

    2012-04-03

    We consider SUSY-like missing energy events at hadron colliders and critically examine the common assumption that the missing energy is the result of two identical missing particles. In order to experimentally test this hypothesis, we generalize the subsystem M{sub T2} variable to the case of asymmetric event topologies, where the two SUSY decay chains terminate in different 'children' particles. In this more general approach, the endpoint M{sub T2(max)} of the M{sub T2} distribution now gives the mass {tilde M}p({tilde M}{sub c}{sup (a)}, {tilde M}{sub c}{sup (b)}) of the parent particles as a function of two input children masses {tilde M}{sub c}{sup (a)} and {tilde M}{sub c}{sup (b)}. We propose two methods for an independent determination of the individual children masses M{sub c}{sup (a)} and M{sub c}{sup (b)}. First, in the presence of upstream transverse momentum PUTM the corresponding function {tilde M}p({tilde M}{sub c}{sup (a)}, {tilde M}{sub c}{sup (b)}, P{sub UTM}) is independent of P{sub UTM} at precisely the right values of the children masses. Second, the previously discussed MT2 'kink' is now generalized to a 'ridge' on the 2-dimensional surface {tilde M}p({tilde M}{sub c}{sup (a)}, {tilde M}{sub c}{sup (b)}). As we show in several examples, quite often there is a special point along that ridge which marks the true values of the children masses. Our results allow collider experiments to probe a multi-component dark matter sector directly and without any theoretical prejudice.

  4. Uranium hydrogeochemical and stream-sediment reconnaissance of the Mt. Michelson NTMS quadrangle, Alaska

    SciTech Connect (OSTI)

    Zinkl, R.J.; Shettel, D.L. Jr.; Langfeldt, S.L.; Hardy, L.C.; D'Andrea, R.F. Jr.

    1982-04-01

    This report presents results of a Hydrogeochemical and Stream Sediment Reconnaissance (HSSR) of the Mt. Michelson NTMS quadrangle, Alaska. In addition to this abbreviated data release, more complete data are available to the public in machine-readable form. These machine-readable data, as well as quarterly or semiannual program progress reports containing further information on the HSSR program in general, or on the Los Alamos National Laboratory (LANL) portion of the program in particular, are available from DOE's Technical Library at its Grand Junction Area Office. Presented in this data release are location data, field analyses, and laboratory analyses of several different sample media. For the sake of brevity, many field site observations have not been included in this volume; these data are, however, available on the magnetic tape. Appendices A and B describe the sample media and summarize the analytical results for each medium. The data have been subdivided by one of the Los Alamos National Laboratory sorting programs of Zinkl and others (1981a) into groups of stream-sediment and lake-sediment samples. For each group which contains a sufficient number of observations, statistical tables, tables of raw data, and 1:1,000,000 scale maps of pertinent elements have been included in this report. Also included are maps showing results of multivariate statistical analyses. Information on the field and analytical procedures used by the Los Alamos National Laboratory during sample collection and analysis may be found in any HSSR data release prepared by the Laboratory and will not be included in this report.

  5. Warm formaldehyde in the Oph IRS 48 transitional disk

    E-Print Network [OSTI]

    van der Marel, Nienke; Bruderer, Simon; van Kempen, Tim A

    2014-01-01

    Simple molecules like H2CO and CH3OH in protoplanetary disks are the starting point for the production of more complex organic molecules. So far, the observed chemical complexity in disks has been limited due to freeze out of molecules onto grains in the bulk of the cold outer disk. Complex molecules can be studied more directly in transitional disks with large inner holes, as these have a higher potential of detection, through UV heating of the outer disk and the directly exposed midplane at the wall. We use Atacama Large Millimeter/submillimeter Array (ALMA) Band 9 (~680 GHz) line data of the transitional disk Oph IRS 48, previously shown to have a large dust trap, to search for complex molecules in regions where planetesimals are forming. We report the detection of the H2CO 9(1,8)-8(1,7) line at 674 GHz, which is spatially resolved as a semi-ring at ~60 AU radius centered south from the star. The inferred H2CO abundance is ~10^{-8} derived by combining a physical disk model of the source with a non-LTE exc...

  6. Solving the stellar 62Ni problem with AMS

    E-Print Network [OSTI]

    I. Dillmann; T. Faestermann; G. Korschinek; J. Lachner; M. Maiti; M. Poutivtsev; G. Rugel; S. Walter; F. Käppeler; M. Erhard; A. R. Junghans; C. Nair; R. Schwengner; A. Wagner

    2009-07-01

    An accurate knowledge of the neutron capture cross sections of 62,63Ni is crucial since both isotopes take key positions which affect the whole reaction flow in the weak s process up to A=90. No experimental value for the 63Ni(n,gamma) cross section exists so far, and until recently the experimental values for 62Ni(n,gamma) at stellar temperatures (kT=30 keV) ranged between 12 and 37 mb. This latter discrepancy could now be solved by two activations with following AMS using the GAMS setup at the Munich tandem accelerator which are also in perfect agreement with a recent time-of-flight measurement. The resulting (preliminary) Maxwellian cross section at kT=30 keV was determined to be 30keV = 23.4 +/- 4.6 mb. Additionally, we have measured the 64Ni(gamma,n)63Ni cross section close to threshold. Photoactivations at 13.5 MeV, 11.4 MeV and 10.3 MeV were carried out with the ELBE accelerator at Forschungszentrum Dresden-Rossendorf. A first AMS measurement of the sample activated at 13.5 MeV revealed a cross section smaller by more than a factor of 2 compared to NON-SMOKER predictions.

  7. Modified Ni-Cu catalysts for ethanol steam reforming

    SciTech Connect (OSTI)

    Dan, M.; Mihet, M.; Almasan, V.; Borodi, G.; Katona, G.; Muresan, L.; Lazar, M. D.

    2013-11-13

    Three Ni-Cu catalysts, having different Cu content, supported on ?-alumina were synthesized by wet co-impregnation method, characterized and tested in the ethanol steam reforming (ESR) reaction. The catalysts were characterized for determination of: total surface area and porosity (N{sub 2} adsorption - desorption using BET and Dollimer Heal methods), Ni surface area (hydrogen chemisorption), crystallinity and Ni crystallites size (X-Ray Diffraction), type of catalytic active centers (Hydrogen Temperature Programmed Reduction). Total surface area and Ni crystallites size are not significantly influenced by the addition of Cu, while Ni surface area is drastically diminished by increasing of Cu concentration. Steam reforming experiments were performed at atmospheric pressure, temperature range 150-350°C, and ethanol - water molar ration of 1 at 30, using Ar as carrier gas. Ethanol conversion and hydrogen production increase by the addition of Cu. At 350°C there is a direct connection between hydrogen production and Cu concentration. Catalysts deactivation in 24h time on stream was studied by Transmission Electron Microscopy (TEM) and temperature-programmed reduction (TPR) on used catalysts. Coke deposition was observed at all studied temperatures; at 150°C amorphous carbon was evidenced, while at 350°C crystalline, filamentous carbon is formed.

  8. Superior performance of Ni-W-Ce mixed-metal oxide catalysts for ethanol steam reforming: Synergistic effects of W- and Ni-dopants

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Rodriguez, Jose A.; Liu, Zongyuan; Xu, Wenqian; Yao, Siyu; Johnson-Peck, Aaron C.; Zhao, Fuzhen; Michorczyk, Piotr; Kubacka, Anna; Stach, Eric A.; Fernandez-Garica, Marcos; et al

    2014-11-26

    The ethanol steam reforming (ESR) reaction was studied over a series of Ni-W-Ce oxide catalysts. The structures of the catalysts were characterized using in-situ techniques including X-ray diffraction, Pair Distribution Function, X-ray absorption fine structure and transmission electron microscopy; while possible surface intermediates for the ESR reaction were investigated by Diffuse Reflectance Infrared Fourier Transform Spectroscopy. In these materials, all the W and part of the Ni were incorporated into the CeO? lattice, with the remaining Ni forming highly dispersed nano NiO (more »The Ni-W-Ce systeme exhibited a much larger lattice strain than those seen for Ni-Ce and W-Ce. Synergistic effects between Ni and W inside ceria produced a substantial amount of defects and O vacancies that led to high catalytic activity, selectivity and stability (i.e. resistance to coke formation) during ethanol steam reforming.« less

  9. US-LARP Progress on LHC IR Upgrades Tanaji Sen, John Johnstone, Nikolai Mokhov, FNAL, Batavia, IL 60510

    E-Print Network [OSTI]

    Sen, Tanaji

    of a long-range interaction on the beams. IR DESIGNS Design and construction of next generation IR magnets in determining these parameters. The required field quality is another key input to the magnet designers. An IR to higher luminosity. In the designs to be presented here, we consider the inner triplet magnets

  10. Synchrotron IR microspectroscopy for protein structure analysis: Potential and questions

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Yu, Peiqiang

    2006-01-01

    Synchrotron radiation-based Fourier transform infrared microspectroscopy (S-FTIR) has been developed as a rapid, direct, non-destructive, bioanalytical technique. This technique takes advantage of synchrotron light brightness and small effective source size and is capable of exploring the molecular chemical make-up within microstructures of a biological tissue without destruction of inherent structures at ultra-spatial resolutions within cellular dimension. To date there has been very little application of this advanced technique to the study of pure protein inherent structure at a cellular level in biological tissues. In this review, a novel approach was introduced to show the potential of the newly developed, advancedmore »synchrotron-based analytical technology, which can be used to localize relatively “pure“ protein in the plant tissues and relatively reveal protein inherent structure and protein molecular chemical make-up within intact tissue at cellular and subcellular levels. Several complex protein IR spectra data analytical techniques (Gaussian and Lorentzian multi-component peak modeling, univariate and multivariate analysis, principal component analysis (PCA), and hierarchical cluster analysis (CLA) are employed to relatively reveal features of protein inherent structure and distinguish protein inherent structure differences between varieties/species and treatments in plant tissues. By using a multi-peak modeling procedure, RELATIVE estimates (but not EXACT determinations) for protein secondary structure analysis can be made for comparison purpose. The issues of pro- and anti-multi-peaking modeling/fitting procedure for relative estimation of protein structure were discussed. By using the PCA and CLA analyses, the plant molecular structure can be qualitatively separate one group from another, statistically, even though the spectral assignments are not known. The synchrotron-based technology provides a new approach for protein structure research in biological tissues at ultraspatial resolutions.« less

  11. PAH chemistry and IR emission from circumstellar disks

    E-Print Network [OSTI]

    R. Visser; V. C. Geers; C. P. Dullemond; J. -C. Augereau; K. M. Pontoppidan; E. F. van Dishoeck

    2007-01-22

    Aims. The chemistry of, and infrared (IR) emission from, polycyclic aromatic hydrocarbons (PAHs) in disks around Herbig Ae/Be and T Tauri stars are investigated. The equilibrium distribution of the PAHs over all accessible charge/hydrogenation states depends on the size and shape of the PAHs and on the physical properties of the star and surrounding disk. Methods. A chemistry model is created to calculate this equilibrium distribution. Destruction of PAHs by ultraviolet (UV) photons, possibly in multi-photon absorption events, is taken into account. The chemistry model is coupled to a radiative transfer code to provide the physical parameters and to combine the PAH emission with the spectral energy distribution (SED) from the star+disk system. Results. Normally hydrogenated PAHs in Herbig Ae/Be disks account for most of the observed PAH emission, with neutral and positively ionized species contributing in roughly equal amounts. Close to the midplane, the PAHs are more strongly hydrogenated and negatively ionized, but these species do not contribute to the overall emission because of the low UV/optical flux deep inside the disk. PAHs of 50 carbon atoms are destroyed out to 100 AU in the disk's surface layer, and the resulting spatial extent of the emission does not agree well with observations. Rather, PAHs of about 100 carbon atoms or more are predicted to cause most of the observed emission. The emission is extended on a scale similar to that of the size of the disk. Furthermore, the emission from T Tauri disks is much weaker and concentrated more towards the central star than that from Herbig Ae/Be disks. Positively ionized PAHs are predicted to be largely absent in T Tauri disks because of the weaker radiation field.

  12. Mitigation of Sulfur Poisoning of Ni/Zirconia SOFC Anodes by Antimony and Tin

    SciTech Connect (OSTI)

    Marina, Olga A.; Coyle, Christopher A.; Engelhard, Mark H.; Pederson, Larry R.

    2011-02-28

    Surface Ni/Sb and Ni/Sb alloys were found to efficiently minimize the negative effects of sulfur on the performance of Ni/zirconia anode-supported solid oxide fuel cells (SOFC). Prior to operating on fuel gas containing low concentrations of H2S, the nickel/zirconia anodes were briefly exposed to antimony or tin vapor, which only slightly affected the SOFC performance. During the subsequent exposures to 1 and 5 ppm H2S, increases in anodic polarization losses were minimal compared to those observed for the standard nickel/zirconia anodes. Post-test XPS analyses showed that Sb and Sn tended to segregate to the surface of Ni particles, and further confirmed a significant reduction of adsorbed sulfur on the Ni surface in Ni/Sn and Ni/Sb samples compared to the Ni. The effect may be the result of weaker sulfur adsorption on bimetallic surfaces, adsorption site competition between sulfur and Sb or Sn on Ni, or other factors. The use of dilute binary alloys of Ni-Sb or Ni-Sn in the place of Ni, or brief exposure to Sb or Sn vapor, may be effective means to counteract the effects of sulfur poisoning in SOFC anodes and Ni catalysts. Other advantages, including suppression of coking or tailoring the anode composition for the internal reforming, are also expected.

  13. Bimetallic Fe-Ni Oxygen Carriers for Chemical Looping Combustion

    SciTech Connect (OSTI)

    Bhavsar, Saurabh; Veser, Goetz

    2013-11-06

    The relative abundance, low cost, and low toxicity of iron make Fe-based oxygen carriers of great interest for chemical looping combustion (CLC), an emerging technology for clean and efficient combustion of fossil and renewable fuels. However, Fe also shows much lower reactivity than other metals (such as Ni and Cu). Here, we demonstrate strong improvement of Fe-based carriers by alloying the metal phase with Ni. Through a combination of carrier synthesis and characterization with thermogravimetric and fixed-bed reactor studies, we demonstrate that the addition of Ni results in a significant enhancement in activity as well as an increase in selectivity for total oxidation. Furthermore, comparing alumina and ceria as support materials highlights the fact that reducible supports can result in a strong increase in oxygen carrier utilization.

  14. MRI of the lung using hyperpolarized He-3 at very low magnetic field (3 mT)

    E-Print Network [OSTI]

    Bidinosti, C P; Tastevin, G; Vignaud, A; Nacher, P J

    2004-01-01

    Optical pumping of He-3 produces large (hyper) nuclear-spin polarizations independent of the magnetic resonance imaging (MRI) field strength. This allows lung MRI to be performed at reduced fields with many associated benefits, such as lower tissue susceptibility gradients and decreased power absorption rates. Here we present results of 2D imaging as well as accurate 1D gas diffusion mapping of the human lung using He-3 at very low field (3 mT). Furthermore, measurements of transverse relaxation in zero applied gradient are shown to accurately track pulmonary oxygen partial pressure, opening the way for novel imaging sequences.

  15. Healing of graphene on single crystalline Ni(111) films

    SciTech Connect (OSTI)

    Zeller, Patrick; Wintterlin, Joost; Speck, Florian; Ostler, Markus; Weinl, Michael; Schreck, Matthias; Seyller, Thomas

    2014-11-10

    The annealing of graphene layers grown on 150?nm thick single crystal Ni(111) films was investigated in situ by low energy electron microscopy and photoemission electron microscopy. After growth, by means of chemical vapor deposition of ethylene, the graphene layers consist of several domains showing different orientations with respect to the underlying Ni surface and also of small bilayer areas. It is shown that, in a controlled process, the rotated domains can be transformed into lattice-aligned graphene, and the bilayer areas can be selectively dissolved, so that exclusively the aligned monolayer graphene is obtained. The ordering mechanism involves transport of C atoms across the surface and solution in the bulk.

  16. Ternary rare-earth ruthenium and iridium germanides RE{sub 3}M{sub 2}Ge{sub 3} (RE=Y, Gd–Tm, Lu; M=Ru, Ir)

    SciTech Connect (OSTI)

    Oliynyk, Anton O.; Stoyko, Stanislav S.; Mar, Arthur, E-mail: arthur.mar@ualberta.ca

    2013-06-15

    Through arc-melting reactions of the elements and annealing at 800 °C, the ternary rare-earth germanides RE{sub 3}Ru{sub 2}Ge{sub 3} and RE{sub 3}Ir{sub 2}Ge{sub 3} have been prepared for most of the smaller RE components (RE=Y, Gd–Tm, Lu). In the iridium-containing reactions, the new phases RE{sub 2}IrGe{sub 2} were also generally formed as by-products. Powder X-ray diffraction revealed orthorhombic Hf{sub 3}Ni{sub 2}Si{sub 3}-type structures (space group Cmcm, Z=4) for RE{sub 3}M{sub 2}Ge{sub 3} (M=Ru, Ir) and monoclinic Sc{sub 2}CoSi{sub 2}-type structures (space group C2/m, Z=4) for RE{sub 2}IrGe{sub 2}. Full crystal structures were determined by single-crystal X-ray diffraction for all members of RE{sub 3}Ru{sub 2}Ge{sub 3} (a=4.2477(6) Ĺ, b=10.7672(16) Ĺ, c=13.894(2) Ĺ for RE=Y; a=4.2610(3)–4.2045(8) Ĺ, b=10.9103(8)–10.561(2) Ĺ, c=14.0263(10)–13.639(3) Ĺ in the progression of RE from Gd to Lu) and for Tb{sub 3}Ir{sub 2}Ge{sub 3} (a=4.2937(3) Ĺ, b=10.4868(7) Ĺ, c=14.2373(10) Ĺ). Both structures can be described in terms of CrB- and ThCr{sub 2}Si{sub 2}-type slabs built from Ge-centred trigonal prisms. However, band structure calculations on Y{sub 3}Ru{sub 2}Ge{sub 3} support an alternative description for RE{sub 3}M{sub 2}Ge{sub 3} based on [M{sub 2}Ge{sub 3}] layers built from linked MGe{sub 4} tetrahedra, which emphasizes the strong M–Ge covalent bonds present. The temperature dependence of the electrical resistivity of RE{sub 3}Ru{sub 2}Ge{sub 3} generally indicates metallic behaviour but with low-temperature transitions visible for some members (RE=Gd, Tb, Dy) that are probably associated with magnetic ordering of the RE atoms. Anomalously, Y{sub 3}Ru{sub 2}Ge{sub 3} exhibits semiconductor-like behaviour of uncertain origin. Magnetic measurements on Dy{sub 3}Ru{sub 2}Ge{sub 3} reveal antiferromagnetic ordering at 3 K and several unusual field-dependent transitions suggestive of complex spin reorientation processes. - Graphical abstract: RE{sub 3}M{sub 2}Ge{sub 3} (M=Ru, Ir) adopts the Hf{sub 3}Ni{sub 2}Si{sub 3}-type structure containing slabs built up from Ge-centred trigonal prisms. - Highlights: • Crystal structures of RE{sub 3}Ru{sub 2}Ge{sub 3} (RE=Y, Gd–Tm, Lu) and Tb{sub 3}Ir{sub 2}Ge{sub 3} were determined. • Strong M–Ge covalent bonds were confirmed by band structure calculations. • Most RE{sub 3}Ru{sub 2}Ge{sub 3} members except Y{sub 3}Ru{sub 2}Ge{sub 3} exhibit metallic behaviour. • Dy{sub 3}Ru{sub 2}Ge{sub 3} displays unusual field-dependent magnetic transitions.

  17. Synthesis, electrochemistry and First Principles Calculation studies of layered Li-Ni-Ti-O compounds

    E-Print Network [OSTI]

    Kang, Kisuk

    New layered cathode materials, Li?.?Ni?.??Ti?.??O?, were synthesized by means of ion-exchange from Na?.?Ni?.??Ti?.??O?. The degree of cation disordering in the material depends critically on the synthesis conditions. Longer ...

  18. Effect of Aging Heat Treatments on Ni52Ti48 Shape Memory Alloy 

    E-Print Network [OSTI]

    Akin, Erhan

    2011-10-21

    Ni-rich NiTi shape memory alloys (SMAs) are capable of attaining a wide range of transformation temperatures depending on the heat treatment conditions and superior thermo-mechanical cycling stability, which are desired for repeated solid...

  19. Mechanism(s) of Ni Sorption on Al-Hydroxy-Interlayered Vermiculite Using Time-Resolved EXAFS

    E-Print Network [OSTI]

    Sparks, Donald L.

    Mechanism(s) of Ni Sorption on Al-Hydroxy-Interlayered Vermiculite Using Time-Resolved EXAFS D. R sorbed and the mechanism of Ni sorption. #12;

  20. A polymorphism in metallothionein 1A (MT1A) is associated with cadmium-related excretion of urinary beta 2?microglobulin

    SciTech Connect (OSTI)

    Lei, Lijian; Department of Epidemiology, School of Public Health, Shanxi Medical University, Shanxi ; Chang, Xiuli; Rentschler, Gerda; Tian, Liting; Zhu, Guoying; Chen, Xiao; Jin, Taiyi; Broberg, Karin

    2012-12-15

    Objectives: Cadmium (Cd) toxicity of the kidney varies between individuals despite similar exposure levels. In humans Cd is mainly bound to metallothioneins (MT), which scavenge its toxic effects. Here we analyzed whether polymorphisms in MT genes MT1A and MT2A influence Cd-related kidney damage. Methods: In a cross-sectional study N = 512 volunteers were selected from three areas in South-Eastern China, which to varying degree were Cd-polluted from a smelter (control area [median Cd in urine U-Cd = 2.67 ?g/L], moderately [U-Cd = 4.23 ?g/L] and highly [U-Cd = 9.13 ?g/L] polluted areas). U-Cd and blood Cd (B-Cd) concentrations were measured by graphite-furnace atomic absorption spectrometry. MT1A rs11076161 (G/A), MT2A rs10636 (G/C) and MT2A rs28366003 (A/G) were determined by Taqman assays; urinary N-Acetyl-beta-(D)-Glucosaminidase (UNAG) by spectrometry, and urinary ?2-microglobulin (UB2M) by ELISA. Results: Higher B-Cd (natural log-transformed) with increasing number of MT1A rs11076161 A-alleles was found in the highly polluted group (p-value trend = 0.033; all p-values adjusted for age, sex, and smoking). In a linear model a significant interaction between rs11076161 genotype and B-Cd was found for UNAG (p = 0.001) and UB2M concentrations (p = 0.001). Carriers of the rs11076161 AA genotype showed steeper slopes for the associations between Cd in blood and natural log-transformed UB2M (? = 1.2, 95% CI 0.72–1.6) compared to GG carriers (? = 0.30, 95% CI 0.15–0.45). Also for UNAG (natural log-transformed) carriers of the AA genotype had steeper slopes (? = 0.55, 95% CI 0.27–0.84) compared to GG carriers (? = 0.018, 95% CI ? 0.79–0.11). Conclusions: MT1A rs11076161 was associated with B-Cd concentrations and Cd-induced kidney toxicity at high exposure levels. -- Highlights: ? Cadmium is toxic to the kidney but the susceptibility differs between individuals. ? The toxic effect of cadmium is scavenged by metallothioneins. ? A common variant of metallothionein 1A was genotyped in 512 cadmium exposed humans. ? Variant carriers of this polymorphism showed more kidney damage from cadmium. ? The frequency of these variants needs to be taken into account in risk assessment.

  1. Mid-IR Fiber-Based Light Sources (~2 to 6.5 microns)

    E-Print Network [OSTI]

    Cafarella, Michael J.

    1 Mid-IR Fiber-Based Light Sources (~2 to 6.5 microns) Prof. Mohammed N. Islam Department) Combustion Monitoring Infr (Cha Cone Penetrometer Contaminated Soil In L SCAPS* truck * (Site

  2. A Calibrated Measurement of the Near-IR Continuum Sky Brightness Using Magellan/FIRE

    E-Print Network [OSTI]

    Sullivan, Peter William

    We characterize the near-IR sky background from 308 observations with the Folded-port InfraRed Echellette (FIRE) spectrograph at Magellan. A subset of 105 observations selected to minimize lunar and thermal effects gives ...

  3. An IR-based Evaluation Framework for Web Search Query Segmentation

    E-Print Network [OSTI]

    Ganguly, Niloy

    An IR-based Evaluation Framework for Web Search Query Segmentation Author 1 Author 1 Affiliation Author 1 Address Author 1 Email Author 2 Author 2 Affiliation Author 2 Address Author 2 Email ABSTRACT

  4. DESIGN AND CONSTRUCTION OF A 15 T, 120 MM BORE IR QUADRUPOLE MAGNET FOR LARP

    E-Print Network [OSTI]

    Caspi, S.

    2011-01-01

    is developing a large bore (120 mm) IR quadrupole ( H Q )quadrupole ( H Q ) that extends the bore size from 90 mm to120 mm and pushes the field at the conductor just over 15 T.

  5. Hydrogen Bond Rearrangements in Water Probed with Temperature-Dependent 2D IR

    E-Print Network [OSTI]

    Nicodemus, Rebecca A.

    We use temperature-dependent two-dimensional infrared spectroscopy (2D IR) of dilute HOD in H2O to investigate hydrogen bond rearrangements in water. The OD stretching frequency is sensitive to its environment, and loss ...

  6. Giantically blue-shifted visible light in femtosecond mid-IR filament in fluorides

    E-Print Network [OSTI]

    Dormidonov, A E; Chekalin, S V; Kandidov, V P

    2015-01-01

    A giant blue shift of an isolated visible band of supercontinuum was discovered and studied in the single filament regime of Mid-IR femtosecond laser pulse at powers slightly exceeding critical power for self-focusing in fluorides.

  7. While catching estrildids for the Museum's Aviary along the Vaal River ir Acacla veld

    E-Print Network [OSTI]

    de Villiers, Marienne

    While catching estrildids for the Museum's Aviary along the Vaal River ir Acacla veld at the farm trained'. Well, a staternent like that rnade our irnacirrations run wild. TIrere you are u ith a silall r

  8. FT-IR spectroscopy technology, market evolution and future strategies of Bruker Optics Inc.

    E-Print Network [OSTI]

    Higdon, Thomas (Thomas Charles)

    2010-01-01

    This thesis explores the technology and market evolution of FT-IR spectroscopy over its nearly forty year history to aid in determining future product design and marketing strategies for an industry-leading firm, Bruker ...

  9. Superior performance of Ni-W-Ce mixed-metal oxide catalysts for ethanol steam reforming: Synergistic effects of W- and Ni-dopants

    SciTech Connect (OSTI)

    Rodriguez, Jose A.; Liu, Zongyuan; Xu, Wenqian; Yao, Siyu; Johnson-Peck, Aaron C.; Zhao, Fuzhen; Michorczyk, Piotr; Kubacka, Anna; Stach, Eric A.; Fernandez-Garica, Marcos; Senanayake, Sanjaya D.

    2014-11-26

    The ethanol steam reforming (ESR) reaction was studied over a series of Ni-W-Ce oxide catalysts. The structures of the catalysts were characterized using in-situ techniques including X-ray diffraction, Pair Distribution Function, X-ray absorption fine structure and transmission electron microscopy; while possible surface intermediates for the ESR reaction were investigated by Diffuse Reflectance Infrared Fourier Transform Spectroscopy. In these materials, all the W and part of the Ni were incorporated into the CeO? lattice, with the remaining Ni forming highly dispersed nano NiO (< 2 nm) outside the Ni-W-Ce oxide structure. The nano NiO was reduced to Ni under ESR conditions. The Ni-W-Ce systeme exhibited a much larger lattice strain than those seen for Ni-Ce and W-Ce. Synergistic effects between Ni and W inside ceria produced a substantial amount of defects and O vacancies that led to high catalytic activity, selectivity and stability (i.e. resistance to coke formation) during ethanol steam reforming.

  10. Superior performance of Ni-W-Ce mixed-metal oxide catalysts for ethanol steam reforming: Synergistic effects of W- and Ni-dopants

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Rodriguez, Jose A. [Brookhaven National Lab. (BNL), Upton, NY (United States); State Univ. of New York Stony Brook, Stony Brook, NY (United States); Liu, Zongyuan [Brookhaven National Lab. (BNL), Upton, NY (United States); State Univ. of New York Stony Brook, Stony Brook, NY (United States); Xu, Wenqian [Brookhaven National Lab. (BNL), Upton, NY (United States); Yao, Siyu [Brookhaven National Lab. (BNL), Upton, NY (United States); Johnson-Peck, Aaron C. [Brookhaven National Lab. (BNL), Upton, NY (United States); Zhao, Fuzhen [Brookhaven National Lab. (BNL), Upton, NY (United States); Michorczyk, Piotr [Inst. de Catalisis y Petroleoquimica, Madrid (Spain); Kubacka, Anna [Inst. de Catalisis y Petroleoquimica, Madrid (Spain); Stach, Eric A. [Brookhaven National Lab. (BNL), Upton, NY (United States); Fernandez-Garica, Marcos [State Univ. of New York Stony Brook, Stony Brook, NY (United States); Senanayake, Sanjaya D. [Brookhaven National Lab. (BNL), Upton, NY (United States)

    2015-01-01

    The ethanol steam reforming (ESR) reaction was studied over a series of Ni-W-Ce oxide catalysts. The structures of the catalysts were characterized using in-situ techniques including X-ray diffraction, Pair Distribution Function, X-ray absorption fine structure and transmission electron microscopy; while possible surface intermediates for the ESR reaction were investigated by Diffuse Reflectance Infrared Fourier Transform Spectroscopy. In these materials, all the W and part of the Ni were incorporated into the CeO? lattice, with the remaining Ni forming highly dispersed nano NiO (< 2 nm) outside the Ni-W-Ce oxide structure. The nano NiO was reduced to Ni under ESR conditions. The Ni-W-Ce systeme exhibited a much larger lattice strain than those seen for Ni-Ce and W-Ce. Synergistic effects between Ni and W inside ceria produced a substantial amount of defects and O vacancies that led to high catalytic activity, selectivity and stability (i.e. resistance to coke formation) during ethanol steam reforming.

  11. Estimated IR and phosphorescence emission fluxes for specific Polycyclic Aromatic Hydrocarbons in the Red Rectangle

    E-Print Network [OSTI]

    G. Mulas; G. Malloci; C. Joblin; D. Toublanc

    2005-09-20

    Following the tentative identification of the blue luminescence in the Red Rectangle by Vijh et al. (2005), we compute absolute fluxes for the vibrational IR emission and phosphorescence bands of three small polycyclic aromatic hydrocarbons. The calculated IR spectra are compared with available ISO observations. A subset of the emission bands are predicted to be observable using presently available facilities, and can be used for an immediate, independent, discriminating test on their alleged presence in this well-known astronomical object.

  12. DRIVER ACCELERATOR DESIGN FOR THE 10 KW UPGRADE OF THE JEFFERSON LAB IR FEL

    E-Print Network [OSTI]

    DRIVER ACCELERATOR DESIGN FOR THE 10 KW UPGRADE OF THE JEFFERSON LAB IR FEL D. Douglas, S. V, Newport News, VA23606, USA Abstract An upgrade of the Jefferson Lab IR FEL [1] is now un- der construction. It will provide 10 kW output light power in a wavelength range of 2­10 µm. The FEL will be driven by a modest

  13. XES Nanoprobe for Hard X-Ray Region: Mitigating Degradation in Ni-ZEBRA Batteries Research Team: Mark Bowden, Kyle Alvine, Nancy Hess, Guosheng Li, Tamas Varga

    E-Print Network [OSTI]

    XES Nanoprobe for Hard X-Ray Region: Mitigating Degradation in Ni-ZEBRA Batteries Research Team scientific understanding of link between Ni-NiCl2 ZEBRA battery cycle degradation and FeS additive Chemical battery performance by poisoning Ni surfaces ­ optimizing Ni/NiCl2 distributions and conductive pathways

  14. Shape memory response of ni2mnga and nimncoin magnetic shape memory alloys under compression 

    E-Print Network [OSTI]

    Brewer, Andrew Lee

    2009-05-15

    In this study, the shape memory response of Ni2MnGa and NiMnCoIn magnetic shape memory alloys was observed under compressive stresses. Ni2MnGa is a magnetic shape memory alloy (MSMA) that has been shown to exhibit fully ...

  15. Oxygen Reduction Activity of PtxNi1-x Alloy Nanoparticles on Multiwall Carbon Nanotubes

    E-Print Network [OSTI]

    Kim, Junhyung

    PtxNi1 - x nanoparticles (Pt:Ni; 1:0, 4:1, 3:1 and 0.7:1) of ~5 nm, were synthesized on carboxylic acid-functionalized multiwall carbon nanotubes (PtxNi1 - x NPs/MWNT). The oxygen reduction reaction (ORR) activity measurements ...

  16. CO2 hydrogenation to formic acid on Ni(110) Guowen Peng a

    E-Print Network [OSTI]

    Sibener, Steven

    CO2 hydrogenation to formic acid on Ni(110) Guowen Peng a , S.J. Sibener b , George C. Schatz c of subsurface H for hydrogenating carbon dioxide (CO2) on Ni(110). The energetics of surface and subsurface H reacting with surface CO2 to form for- mate, carboxyl, and formic acid on Ni(110) is systematically studied

  17. LENS MODELS OF HERSCHEL-SELECTED GALAXIES FROM HIGH-RESOLUTION NEAR-IR OBSERVATIONS

    SciTech Connect (OSTI)

    Calanog, J. A.; Cooray, A.; Ma, B.; Casey, C. M. [Department of Physics and Astronomy, University of California, Irvine, CA 92697 (United States); Fu, Hai [Department of Physics and Astronomy, University of Iowa, Van Allen Hall, Iowa City, IA 52242 (United States); Wardlow, J. [Dark Cosmology Centre, Niels Bohr Institute, University of Copenhagen, Juliane Maries Vej 30, DK-2100 Copenhagen (Denmark); Amber, S. [Department of Physical Sciences, The Open University, Milton Keynes MK7 6AA (United Kingdom); Baker, A. J. [Department of Physics and Astronomy, Rutgers, The State University of New Jersey, 136 Frelinghuysen Road, Piscataway, NJ 08854 (United States); Baes, M. [1 Sterrenkundig Observatorium, Universiteit Gent, Krijgslaan 281, B-9000 Gent (Belgium); Bock, J. [California Institute of Technology, 1200 E. California Blvd., Pasadena, CA 91125 (United States); Bourne, N.; Dye, S. [School of Physics and Astronomy, University of Nottingham, NG7 2RD (United Kingdom); Bussmann, R. S. [Department of Astronomy, Space Science Building, Cornell University, Ithaca, NY 14853-6801 (United States); Chapman, S. C. [Institute of Astronomy, University of Cambridge, Madingley Road, Cambridge CB3 0HA (United Kingdom); Clements, D. L. [Astrophysics Group, Imperial College London, Blackett Laboratory, Prince Consort Road, London SW7 2AZ (United Kingdom); Conley, A. [Center for Astrophysics and Space Astronomy 389-UCB, University of Colorado, Boulder, CO 80309 (United States); Dannerbauer, H. [Laboratoire AIM-Paris-Saclay, CEA/DSM/Irfu-CNRS-Université Paris Diderot, CE-Saclay, pt courrier 131, F-91191 Gif-sur-Yvette (France); De Zotti, G. [INAF-Osservatorio Astronomico di Padova, Vicolo dell'Osservatorio 5, I-35122 Padova (Italy); Dunne, L.; Eales, S. [School of Physics and Astronomy, Cardiff University, Queens Buildings, The Parade, Cardiff CF24 3AA (United Kingdom); and others

    2014-12-20

    We present Keck-Adaptive Optics and Hubble Space Telescope high resolution near-infrared (IR) imaging for 500 ?m bright candidate lensing systems identified by the Herschel Multi-tiered Extragalactic Survey and Herschel Astrophysical Terahertz Large Area Survey. Out of 87 candidates with near-IR imaging, 15 (?17%) display clear near-IR lensing morphologies. We present near-IR lens models to reconstruct and recover basic rest-frame optical morphological properties of the background galaxies from 12 new systems. Sources with the largest near-IR magnification factors also tend to be the most compact, consistent with the size bias predicted from simulations and previous lensing models for submillimeter galaxies (SMGs). For four new sources that also have high-resolution submillimeter maps, we test for differential lensing between the stellar and dust components and find that the 880 ?m magnification factor (?{sub 880}) is ?1.5 times higher than the near-IR magnification factor (?{sub NIR}), on average. We also find that the stellar emission is ?2 times more extended in size than dust. The rest-frame optical properties of our sample of Herschel-selected lensed SMGs are consistent with those of unlensed SMGs, which suggests that the two populations are similar.

  18. New insulating antiferromagnetic quaternary iridates MLa10Ir4O24 (M=Sr, Ba)

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhao, Qingbiao; Han, Fei; Stoumpos, Constantinos C.; Han, Tian -Heng; Li, Hao; Mitchell, J. F.

    2015-07-01

    Recently, oxides of Ir4+ have received renewed attention in the condensed matter physics community, as it has been reported that certain iridates have a strongly spin-orbital coupled (SOC) electronic state, Jeff = ˝, that defines the electronic and magnetic properties. The canonical example is the Ruddlesden-Popper compound Sr2IrO4, which has been suggested as a potential route to a new class of high temperature superconductor due to the formal analogy between Jeff = ˝ and the S = ˝ state of the cuprate superconductors. The quest for other iridium oxides that present tests of the underlying SOC physics is underway. Inmore »this spirit, here we report the synthesis and physical properties of two new quaternary tetravalent iridates, MLa10Ir4O24 (M = Sr, Ba). The crystal structure of both compounds features isolated IrO6 octahedra in which the electronic configuration of Ir is d5. As a result, both compounds order antiferromagnetically despite the lack of obvious superexchange pathways, and resistivity measurement shows that SrLa10Ir4O24 is an insulator.« less

  19. LOCA simulation in the national research universal reactor program: postirradiation examination results for the third materials experiment (MT-3)

    SciTech Connect (OSTI)

    Rausch, W.N.

    1984-04-01

    A series of in-reactor experiments were conducted using full-length 32-rod pressurized water reactor (PWR) fuel bundles as part of the Loss-of-Coolant Accident (LOCA) Simulation Program. The third materials experiment (MT-3) was the sixth in the series of thermal-hydraulic and materials deformation/rutpure experiments conducted in the National Research Universal (NRU) reactor, Chalk River, Ontario, Canada. The main objective of the experiment was to evaluate ballooning and rupture during active two-phase cooling in the temperature range from 1400 to 1500/sup 0/F (1030 to 1090 K). The 12 test rods in the center of the 32-rod bundle were initially pressurized to 550 psi (3.8 MPa) to insure rupture in the correct temperature range. All 12 of the rods ruptured, with an average peak bundle strain of approx. 55%. The UKAEA also funded destructive postirradiation examination (PIE) of several of the ruptured rods from the MT-3 experiment. This report describes the work performed and presents the PIE results. Information obtained during the PIE included cladding thickness measurements metallography, and particle size analysis of the cracked and broken fuel pellets.

  20. Searches for supersymmetry using the MT2 variable in hadronic events produced in pp collisions at 8 TeV

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Khachatryan, V.

    2015-05-15

    Searches for supersymmetry (SUSY) are performed using a sample of hadronic events produced in 8 TeV pp collisions at the CERN LHC. The searches are based on the MT2 variable, which is a measure of the transverse momentum imbalance in an event. The data were collected with the CMS detector and correspond to an integrated luminosity of 19.5 fb?ą. Two related searches are performed. The first is an inclusive search based on signal regions defined by the value of the MT2 variable, the hadronic energy in the event, the jet multiplicity, and the number of jets identified as originating frommore »bottom quarks. The second is a search for a mass peak corresponding to a Higgs boson decaying to a bottom quark-antiquark pair, where the Higgs boson is produced as a decay product of a SUSY particle. For both searches, the principal backgrounds are evaluated with data control samples. No significant excess over the expected number of background events is observed, and exclusion limits on various SUSY models are derived.« less

  1. Investigation of Ni Sorption on Pyrophyllite: An XAFS Study

    E-Print Network [OSTI]

    Sparks, Donald L.

    , * , G E R A L D I N E M . L A M B L E , A N D D O N A L D L . S P A R K S Department of Plant and SoilInvestigation of Ni Sorption on Pyrophyllite: An XAFS Study A N D R E M . S C H E I D E G G E R

  2. Semantic Sensor Net: An Extensible Framework Lionel M. Ni1

    E-Print Network [OSTI]

    Liu, Yunhao

    (MEMS) have led to the wide deployment of large-scale wireless sensor networks (WSN), which promisesSemantic Sensor Net: An Extensible Framework Lionel M. Ni1 , Yanmin Zhu1 , Jian Ma1 , Minglu Li2-ml@cs.sjtu.edu.cn Abstract. Existing approaches for sensor networks suffer from a number of critical drawbacks. First

  3. High strain rate deformation of NiAl

    SciTech Connect (OSTI)

    Maloy, S.A.; Gray, G.T. III; Darolia, R.

    1994-07-01

    NiAl is a potential high temperature structural material. Applications for which NiAl is being considered (such as rotating components in jet engines) requires knowledge of mechanical properties over a wide range of strain rates. Single crystal NiAl (stoichiometric and Ni 49.75Al 0.25Fe) has been deformed in compression along [100] at strain rates of 0.001, 0.1/s and 2000/s and temperatures of 76,298 and 773K. <111> slip was observed after 76K testing at a strain rate of 0.001/s and 298K testing at a strain rate of 2000/s. Kinking was observed after deformation at 298K and a strain rate of 0.001/s and sometimes at 298 K and a strain rate of 0.1/s. Strain hardening rates of 8200 and 4000 MPa were observed after 773 and 298K testing respectively, at a strain rate of 2000/s. Results are discussed in reference to resulting dislocation substructure.

  4. 90° magnetic coupling in a NiFe/FeMn/biased NiFe multilayer spin valve component investigated by polarized neutron reflectometry

    SciTech Connect (OSTI)

    Callori, S. J., E-mail: sara.callori@ansto.gov.au; Bertinshaw, J. [School of Physics, The University of New South Wales, Sydney, New South Wales 2052 (Australia); Bragg Institute, Australian Nuclear Science and Technology Organization, Lucas Heights, New South Wales 2234 (Australia); Cortie, D. L. [The Institute for Superconducting and Electronic Materials, The University of Wollongong, Wollongong, New South Wales 2522 (Australia); Bragg Institute, Australian Nuclear Science and Technology Organization, Lucas Heights, New South Wales 2234 (Australia); Cai, J. W., E-mail: jwcai@aphy.iphy.ac.cn; Zhu, T. [Institute of Physics, Chinese Academy of Sciences, Beijing 100190 (China); Le Brun, A. P. [Bragg Institute, Australian Nuclear Science and Technology Organization, Lucas Heights, New South Wales 2234 (Australia); Klose, F. [Bragg Institute, Australian Nuclear Science and Technology Organization, Lucas Heights, New South Wales 2234 (Australia); Department of Physics and Materials Science, City University of Hong Kong (Hong Kong)

    2014-07-21

    We have observed 90° magnetic coupling in a NiFe/FeMn/biased NiFe multilayer system using polarized neutron reflectometry. Magnetometry results show magnetic switching for both the biased and free NiFe layers, the latter of which reverses at low applied fields. As these measurements are only capable of providing information about the total magnetization within a sample, polarized neutron reflectometry was used to investigate the reversal behavior of the NiFe layers individually. Both the non-spin-flip and spin-flip neutron reflectometry signals were tracked around the free NiFe layer hysteresis loop and were used to detail the evolution of the magnetization during reversal. At low magnetic fields near the free NiFe coercive field, a large spin-flip signal was observed, indicating magnetization aligned perpendicular to both the applied field and pinned layer.

  5. Low-temperature magnetization in Ni-rich gamma-Ni100-x-yFexVy alloys 

    E-Print Network [OSTI]

    Chakraborty, S.; Mukherjee, GD; Rathnayaka, KDD; Naugle, Donald G.; Majumdar, AK.

    2000-01-01

    Detailed studies of the temperature dependence of the spontaneous magnetization have been made in eight different compositions of gamma-Ni100-x-yFexVy (4 less than or equal to x less than or equal to 17; 2 less than or equal to y less than or equal...

  6. Probing antiferromagnetism in NiMn/Ni/(Co)/Cu3Au(001) single-crystalline epitaxial thin films

    E-Print Network [OSTI]

    Kuch, Wolfgang

    hexagonal-close- packed and composition-modulated atomic layer stacking Appl. Phys. Lett. 102, 012407 (2013-of-plane (OoP) as well as in-plane (IP) magnetized Ni films, the latter stabilized by Co under-layer deposition) Electron molecular beam epitaxy: Layer-by-layer growth of complex oxides via pulsed electron

  7. First-principles investigations of Ni3Al(111) and NiAl(110) surfaces at metal dusting conditions

    SciTech Connect (OSTI)

    Saadi, Souheil

    2011-03-01

    We investigate the structure and surface composition of the {gamma}{prime}-Ni{sub 3}Al(111) and {beta}-NiAl(110) alloy surfaces at conditions relevant for metal dusting corrosion related to catalytic steam reforming of natural gas. In regular service as protective coatings, nickel-aluminum alloys are protected by an oxide scale, but in case of oxide scale spallation, the alloy surface may be directly exposed to the reactive gas environment and vulnerable to metal dusting. By means of density functional theory and thermochemical calculations for both the Ni{sub 3}Al and NiAl surfaces, the conditions under which CO and OH adsorption is to be expected and under which it is inhibited, are mapped out. Because CO and OH are regarded as precursors for nucleating graphite or oxide on the surfaces, phase diagrams for the surfaces provide a simple description of their stability. Specifically, this study shows how the CO and OH coverages depend on the steam to carbon ratio (S/C) in the gas and thereby provide a ranking of the carbon limits on the different surface phases.

  8. STRUCTURAL DETERMINATION OF MOLECULAR OVERLAYER SYSTEMS WITH NORMAL PHOTOELECTRON DIFFRACTION: c(2x2)CO-Ni(001) AND (/3 x /3)R30| Co-Ni(111)

    E-Print Network [OSTI]

    Kevan, S.D.

    2012-01-01

    electron diffraction (LEED), for subsequent, quantitativeadsorption system and because LEED structure analysis has° CO-Ni(lll) system, for which no LEED data presently exist.

  9. The thermal stability of TiB[sub 2] in Ni-43 a% Al

    SciTech Connect (OSTI)

    Korinko, P.S. (General Motors, Indianapolis, IN (United States). Allison Gas Turbine Div.); Duquette, D.J. (Rensselaer Polytechnic Inst., Troy, NY (United States))

    1994-02-01

    The intermetallic compound NiAl has been suggested for use as a matrix for high temperature composites. Interest in this compound is derived from its low density compared to conventional superalloys, high melting point, and excellent oxidation resistance. It has been demonstrated that a composite of stoichiometric NiAl and TiB[sub 2] is stable when exposed at elevated temperatures for extended periods of time. However, it has been shown that a composite consisting of Ni[sub 3]Al and TiB[sub 2] is not stable in the same temperature range. In the case of Ni[sub 3]Al, the TiB[sub 2] particles dissolve and the matrix is enriched with Ti and transforms to Ni[sub 3](Al,Ti) and NiTi. If stoichiometric NiAl reinforced with TiB[sub 2] is used in a high temperature oxidizing atmosphere, then there is also a possibility that the Al may be depleted as it is oxidized. If this occurs, the composition of the matrix may shift to nickel-rich NiAl or even to Ni[sub 3]Al. This work was conducted to determine if TiB[sub 2] is used in a high temperature oxidizing atmosphere, then there is also a possibility that the Al may be depleted as it is oxidized. If this occurs, the composition of the matrix may shift to nickel-rich NiAl or even to Ni[sub 3]Al. This work was conducted to determine if TiB[sub 2] is stable in nickel-rich NiAl. The Ni-Al phase diagram is shown, and the composition of NiAl used in this study is indicated.

  10. Temperature-induced sign change of the magnetic interlayer coupling in Ni/Ni{sub 25}Mn{sub 75}/Ni trilayers on Cu{sub 3}Au(001)

    SciTech Connect (OSTI)

    Shokr, Y. A.; Zhang, B.; Sandig, O.; Kuch, W.; Erkovan, M.; Wu, C.-B.

    2015-05-07

    We investigated the magnetic interlayer coupling between two ferromagnetic (FM) Ni layers through an antiferromagnetic (AFM) Ni{sub 25}Mn{sub 75} layer and the influence of this coupling on the exchange bias phenomenon. The interlayer coupling energy of an epitaxial trilayer of 14 atomic monolayers (ML) Ni/45 ML Ni{sub 25}Mn{sub 75}/16 ML Ni on Cu{sub 3}Au(001) was extracted from minor-loop magnetization measurements using in-situ magneto-optical Kerr effect. The interlayer coupling changes from ferromagnetic to antiferromagnetic when the temperature is increased above 300?K. This sign change is interpreted as the result of the competition between an antiparallel Ruderman-Kittel-Kasuya-Yosida (RKKY)-type interlayer coupling, which dominates at high temperature, and a stronger direct exchange coupling across the AFM layer, which is present only below the Néel temperature of the AFM layer.

  11. Superconducting and magnetic properties of Sr3Ir4Sn13

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Biswas, P. K.; Amato, A.; Khasanov, R.; Luetkens, H.; Wang, Kefeng; Petrovic, C.; Cook, R. M.; Lees, M. R.; Morenzoni, E.

    2014-10-10

    In this research, magnetization and muon spin relaxation or rotation (µSR) measurements have been performed to study the superconducting and magnetic properties of Sr?Ir?Sn??. From magnetization measurements the lower and upper critical fields of Sr?Ir?Sn?? are found to be 81(1) Oe and 14.4(2) kOe, respectively. Zero-field µSR data show no sign of any magnetic ordering or weak magnetism in Sr?Ir?Sn??. Transverse-field µSR measurements in the vortex state provided the temperature dependence of the magnetic penetration depth ?. The dependence of ??˛ with temperature is consistent with the existence of single s-wave energy gap in the superconducting state of Sr?Ir?Sn?? withmore »a gap value of 0.82(2) meV at absolute zero temperature. The magnetic penetration depth at zero temperature ?(0) is 291(3) nm. The ratio ?(0)/kBTc = 2.1(1) indicates that Sr?Ir?Sn?? should be considered as a strong-coupling superconductor.« less

  12. Activity and structure of hydrotreating Ni, Mo, and Ni-Mo sulfide catalysts supported on {gamma}-Al{sub 2}O{sub 3}--USY zeolite

    SciTech Connect (OSTI)

    Li, D.; Nishijima, A.; Morris, D.E.; Guthrie, G.D.

    1999-11-15

    The catalytic hydrocracking (HC) of diphenylmethane (DPM) and hydrodesulfurization (HDS) of dibenzothiophene (DBT) over Ni, Mo, and Ni-Mo sulfide catalysts supported on a mixed ultrastable Y (USY) zeolite and gamma-Al{sub 2}O{sub 3} were studied. The catalysts were characterized using NH{sub 3} temperature-programmed desorption (TPD), X-ray photoelectron spectroscopy (XPS), UV-Vis-NIR diffuse reflectance spectroscopy (DRS), high-resolution transmission electron microscopy (HRTEM), and chemical composition analysis. Because addition of zeolite to a conventional alumina support improves acidity, Ni, Mo, and Ni-Mo catalysts supported on the combined supports had much higher HC activity. Ni was found to be uniformly distributed throughout the catalysts; however, Mo preferentially entered the structure of {gamma}-Al{sub 2}O{sub 3} or was accommodated as oxide aggregates on {gamma}-Al{sub 2}O{sub 3}, rather than associating with zeolite. Ni and Mo catalysts supported on {gamma}-Al{sub 2}O{sub 3}-USY zeolite were good HDS catalysts and showed a shallow maximum in catalytic activity at a NiO and MoO{sub 3} content of 5 mol%. The higher activity at this content occurred because Ni or Mo species had higher surface concentrations, higher dispersion, and were more easily sulfided. Ni-Mo catalysts supported on {gamma}-Al{sub 2}O{sub 3}-USY zeolite had high HDS activity, which showed a prominent maximum at a NiO/(NiO + MoO{sub 3}) ratio of about 0.4, because at this ratio the surface species of Ni and Mo were well dispersed and more easily sulfided to form a Ni-Mo-S phase responsible for the high HDS activity. The Ni-Mo catalysts supported on gamma-Al{sub 2}O{sub 3}-USY zeolite have slightly higher HDS activity than {gamma}-Al{sub 2}O{sub 3}-USY zeolite have slightly higher HDS activity than {gamma}-Al{sub 2}O{sub 3}-supported Ni-Mo catalysts.

  13. ''Bare'' single-particle energies in Ni-56 

    E-Print Network [OSTI]

    Trache, L.; Kolomiets, A.; Shlomo, S.; Heyde, K.; Dejbakhsh, H.; Gagliardi, Carl A.; Tribble, Robert E.; Zhou, XG; Jacob, VE; Oros, AM.

    1996-01-01

    of 57Ni and 57Cu that the lowest orbital in the N53 shell is 2p3/2 @1#. The first and second excited states in 57Ni at E*50.768 MeV, Jp55/22 and E*51.113 MeV, Jp51/22 have good single-particle character @2# and corre- spond to the next two orbitals.... A quick look higher into the energy spectrum shows a group of three levels of negative parity and spins Jp55/22, 7/22, and 3/22 around the energy of the first excited state in the core at E(211)52701 keV with half-lives T1/25 31, 47, and 12 fs...

  14. Soil Science Society of America Journal This work was presented at the 12th North American Forest Soils Conference, Whitefish, MT, 1620

    E-Print Network [OSTI]

    Martin, Timothy

    Soils Conference, Whitefish, MT, 16­20 June 2013, in the Production Systems for Biomass and Bioenergy silvicultural practices used, and when combined with suitable site preparation techniques and the deployment fourfold higher aboveground pine biomass than the C treatment (7.7 Mg ha-1); the untreated CF (17.9 Mg ha-1

  15. NEAFS Y-mtDNA Workshop (Butler and Coble) November 1, 2006 http://www.cstl.nist.gov/biotech/strbase/training.htm 1

    E-Print Network [OSTI]

    NEAFS Y-mtDNA Workshop (Butler and Coble) November 1, 2006 http://www.cstl.nist.gov/biotech textbook (now in its 2nd Edition) · STRBase website: http://www.cstl.nist.gov/biotech/strbase/ · Family: wife Terilynne and 6 children · Hobbies: reading and writing http://www.cstl.nist.gov/biotech

  16. Comment on ``A modified leapfrog scheme for shallow water equations'' by Wen-Yih Sun and Oliver M.T. Sun

    E-Print Network [OSTI]

    Williams, Paul

    Commentary Comment on ``A modified leapfrog scheme for shallow water equations'' by Wen-Yih Sun and Oliver M.T. Sun Paul D. Williams Department of Meteorology, University of Reading, UK a r t i c l e i n f integration of the shallow-water equa- tions using the leapfrog time-stepping scheme [Sun Wen-Yih, Sun Oliver

  17. Modulated IR radiometry for determining thermal properties and basic characteristics of titanium thin films

    SciTech Connect (OSTI)

    Apreutesei, Mihai; Lopes, Claudia; Vaz, Filipe; Macedo, Francisco; Borges, Joel

    2014-07-01

    Titanium thin films of different thicknesses were prepared by direct current magnetron sputtering to study modulated infrared (IR) radiometry as a tool for analyzing film thickness. Thickness was varied by regularly increasing the deposition time, keeping all the other deposition parameters constant. The influence of film thickness on morphological, structural, and electrical properties of the titanium coatings also was investigated. The experimental results revealed a systematic grain growth with increasing film thickness, along with enhanced film crystallinity, which led to increased electrical conductivity. Using the results obtained by modulated IR radiometry, the thickness of each thin film was calculated. These thickness values were then compared with the coating thickness measurements obtained by scanning electron microscopy. The values confirmed the reliability of modulated IR radiometry as an analysis tool for thin films and coatings, and for determining thicknesses in the micrometer range, in particular.

  18. Auxiliary Ligand-Dependent Assembly of Several Ni/Ni-Cd Compounds with N2O2 Donor Tetradentate Symmetrical Schiff Base Ligand

    SciTech Connect (OSTI)

    Ge, Ying Ying; Li, Guo-Bi; Fang, Hua-Cai; Zhan, Xu Lin; Gu, Zhi-Gang; Chen, Jin Hao; Sun, Feng; Cai, Yue-Peng; Thallapally, Praveen K.

    2010-09-18

    Several low-dimensional Ni/Ni-Cd complexes containing N2O2 donor tetradentate symmetrical Schiff base ligand bis(acetylacetone)ethylene-diamine (sy-H2L2), namely, [Ni(sy-L2)]2?HLa?ClO4 (2), (HLa)2?(ClO4)?(NO3) (3), [Ni(sy-L2)X]2](4,4’-bipy) (where La = 5,7-dimethyl-3,6-dihydro-2H-1,4-diazepine, X = ClO4 (4), X=NO3 (5), [Ni(sy-L2)Cd(SCN)2]n (6) and [Ni(sy-L2)?Cd(N3)2]n (7) have been synthesized from [Ni(sy-L2)]2?H2O (1). Complex 2, is three component discrete assembly generated from (HLa)+ moiety bridged with [Ni(sy-L2)] unit and ClO4- anion. A solution containing complex 2 and Cd(NO3)2 results in a mixture of 1 and 3. Further re-crystallization of 1 and 3 with various auxiliary ligands, provides coordination complexes 4 – 7 stabilized by weak hydrogen bonds in which 6 and 7 represent the first 1D heteronuclear complexes based on symmetric acacen-base Schiff base ligand.

  19. Magnetic field-induced phase transformation and variant reorientation in Ni2MnGa and NiMnCoIn magnetic shape memory alloys 

    E-Print Network [OSTI]

    Karaca, Haluk Ersin

    2009-05-15

    The purpose of this work is to reveal the governing mechanisms responsible for the magnetic field-induced i) martensite reorientation in Ni2MnGa single crystals, ii) stress-assisted phase transformation in Ni2MnGa single ...

  20. Effects of thermo-mechanical treatment on the shape memory behavior of NiTi and CoNiAl alloys 

    E-Print Network [OSTI]

    Karaca, Haluk Ersin

    2004-09-30

    Nickel-Titanium (NiTi) shape memory alloys have been the focus of extensive research due to its unique characteristics such as high recoverable strain and ductility. However, solutionized samples of NiTi do not demonstrate good shape memory...

  1. Ni(OH){sub 2} nanoflakes electrodeposited on Ni foam-supported vertically oriented graphene nanosheets for application in asymmetric supercapacitors

    SciTech Connect (OSTI)

    Wang, Xin; Liu, Jiyue; Wang, Yayu; Zhao, Cuimei; Zheng, Weitao

    2014-04-01

    Highlights: • Ni(OH){sub 2}/vertically oriented graphene nanosheets (V-GNs) was prepared. • Ni(OH){sub 2}/V-GNs had enhanced specific capacitance, cycling reversibility and stability. • Performance of Ni(OH){sub 2}/GNs/NF-AC asymmetric supercapacitor was studied. - Abstract: Binderless Ni(OH){sub 2} nanoflakes grown on Ni foam (NF)-supported vertically oriented graphene nanosheets (V-GNs) has been fabricated as a positive electrode material for asymmetric supercapacitor (ASC), coupled with activated carbon (AC) as a counter electrode material. The introduction of V-GNs leads to dense growth of nanocrystalline ?-Ni(OH){sub 2} that is confirmed by X-ray diffraction, transmission electron microscopic and scanning electron microscopic analyses. The electrochemical performances of the Ni(OH){sub 2}/GNs/NF electrode are characterized by cyclic voltammetry and charge–discharge tests, which exhibit high specific capacitance of 2215 F g{sup ?1} at a scan current density of 2.3 A g{sup ?1}, enhanced cycling stability and high rate capability. The Ni(OH){sub 2}/GNs/NF-AC-based ASC can achieve a cell voltage of 1.4 V and a specific energy density of 11.11 Wh kg{sup ?1} at 0.5 mA cm{sup ?2} with a nearly 100% coulombic efficiency at room temperature.

  2. Sources of stress gradients in electrodeposited Ni MEMS.

    SciTech Connect (OSTI)

    Hearne, Sean Joseph; Floro, Jerrold Anthony; Dyck, Christopher William

    2004-06-01

    The ability of future integrated metal-semiconductor micro-systems such as RF MEMS to perform highly complex functions will depend on developing freestanding metal structures that offer improved conductivity and reflectivity over polysilicon structures. For example, metal-based RF MEMS technology could replace the bulky RF system presently used in communications, navigation, and avionics systems. However, stress gradients that induce warpage of active components have prevented the implementation of this technology. Figure 1, is an interference micrograph image of a series of cantilever beams fabricated from electrodeposited Ni. The curvature in the beams was the result of stress gradients intrinsic to the electrodeposition process. To study the sources of the stress in electrodeposition of Ni we have incorporated a wafer curvature based stress sensor, the multibeam optical stress sensor, into an electrodeposition cell. We have determined that there are two regions of stress induced by electrodepositing Ni from a sulfamate-based bath (Fig 2). The stress evolution during the first region, 0-1000{angstrom}, was determined to be dependent only on the substrate material (Au vs. Cu), whereas the stress evolution during the second region, >1000{angstrom}, was highly dependent on the deposition conditions. In this region, the stress varied from +0.5 GPa to -0.5GPa, depending solely on the deposition rate. We examined four likely sources for the compressive intrinsic stress, i.e. reduction in tensile stress, and determined that only the adatom diffusion into grain boundaries model of Sheldon, et al. could account for the observed compressive stress. In the presentation, we shall discuss the compressive stress generation mechanisms considered and the ramifications of these results on fabrication of electrodeposited Ni for MEMS applications.

  3. Precipitation in 18 wt% Ni maraging steel of grade 350

    SciTech Connect (OSTI)

    Tewari, R.; Mazumder, S.; Batra, I.S.; Dey, G.K.; Banerjee, S.

    2000-03-14

    The evolution of precipitates in maraging steel of grade 350 was studied using the complementary techniques of small angle X-ray scattering (SACS) and transmission electron microscopy (TEM). These investigations revealed that ageing the steel at 703 K involved a rhombohedral distortion of the supersaturated b.c.c. martensite accompanied by the appearance of diffuse {omega}-like structures. This was followed by the appearance of well-defined {omega} particles containing chemical order. At the ageing temperature of 783 K, Ni{sub 3}(Ti,Mo) precipitates were the first to appear with a growth exponent of 1/3. The values of the Pored exponent obtained from the SAXS profiles indicated that the {omega} particles, formed below 723 K, had diffuse interfaces up to an ageing time of 48 h. On the other hand, Ni{sub 3}(Ti,Mo) precipitates, formed above 723 K, developed sharp interfaces in just about an hour. Also, the steel exhibited scaling in phase separation both at 703 and 783 K, but only during the early stages. Through this study it was established that at temperatures of ageing less than 723 K, evolution of {omega} particles takes place through the collapse of the unstable b.c.c. lattice and, at temperatures above 723 K, precipitation of A{sub 3}B type of phases through the mechanism of clustering and ordering of atomic species. Sharp interfaces develop rather quickly when the mechanism of precipitation involves development and amplification of a concentration wave along as in the nucleation of Ni{sub 3}(Ti,Mo) at 783 K than when an interplay of both the displacement and concentration waves is required as in the evolution of {omega} at 703 K. These results indicate towards the possibility of existence of two separate time-temperature-transformation (TTT) curves, one for the evolution of {omega}-phase and another for nucleation and growth of Ni{sub 3}(Ti,Mo).

  4. Facile approach to prepare hollow core–shell NiO microspherers for supercapacitor electrodes

    SciTech Connect (OSTI)

    Han, Dandan; Xu, Pengcheng; Jing, Xiaoyan; Wang, Jun; Song, Dalei; Liu, Jingyuan; Zhang, Milin

    2013-07-15

    A facile lamellar template method (see image) has been developed for the preparation of uniform hollow core–shell structure NiO (HCS–NiO) with a nanoarchitectured wall structure. The prepared NiO was found to be highly crystalline in uniform microstructures with high specific surface area and pore volume. The results indicated that ethanol interacted with trisodium citrate played an important role for the formation of hollow core–shell spheres. On the basis of the analysis of the composition and the morphology, a possible formation mechanism was investigated. NiO microspheres with hollow core–shell showed excellent capacitive properties. The exceptional cyclic, structural and electrochemical stability with ?95% coulombic efficiency, and very low ESR value from impedance measurements promised good utility value of hollow core–shell NiO material in fabricating a wide range of high-performance electrochemical supercapacitors. - The hollow core–shell NiO was prepared with a facile lamellar template method. The prepared NiO show higher capacitance, lower ion diffusion resistance and better electroactive surface utilization for Faradaic reactions. - Highlights: • Formation of hollow core–shell NiO via a novel and facile precipitation route. • Exhibited uniform feature sizes and high surface area of hollow core–shell NiO. • Synthesized NiO has high specific capacitance ( 448 F g{sup 1}) and very low ESR value. • Increased 20% of long life cycles capability after 500 charge–discharge cycles.

  5. Present status of the KADoNiS database

    E-Print Network [OSTI]

    I. Dillmann; R. Plag; M. Heil; F. Käppeler; T. Rauscher

    2008-06-12

    The "Karlsruhe Astrophysical Database of Nucleosynthesis in Stars" (KADoNiS) project is an online database for experimental cross sections relevant to the $s$ process and $p$ process. It is available under \\http://nuclear-astrophysics.fzk.de/kadonis and consists of two parts. Part 1 is an updated sequel to the well-known Bao et al. compilations from 1987 and 2000, which is online since April 2005. An extension of this $s$-process database to $(n,p)$ and $(n,\\alpha)$ cross sections at $kT$= 30 keV, as in the first version of the Bao compilation, is planned. The second part of KADoNiS is a $p$-process library, which includes all available experimental data from $(p,\\gamma)$, $(p,n)$, $(\\alpha,\\gamma)$, $(\\alpha,n)$, $(\\alpha,\\alpha)$, $(n,\\alpha)$ and $(\\gamma,n)$ reactions in or close to the respective Gamow window. Despite the great number of reactions required for a $p$-process reaction network, experimental data is still scarce and up to now restricted to stable targets. Given here is a short overview about the present status of the KADoNiS database.

  6. Handling collision debris in quad- and dipole-first LHC IR options

    SciTech Connect (OSTI)

    Mokhov, N.V.; Rakhno, I.L.; /Fermilab

    2006-12-01

    Detailed MARS15 Monte Carlo energy deposition calculations are performed for two main designs of the LHC interaction regions (IR) capable to achieve a luminosity of 10{sup 35} cm{sup -2} s{sup -1}: a traditional quadrupole-first scheme and the one with a dual-bore inner triplet with separation dipoles placed in front of the quadrupoles. It is shown that with the appropriate design of the Nb3Sn magnets, IR layout and a number of protective measures implemented, both schemes are feasible for the LHC luminosity upgrade up to 10{sup 35} cm{sup -2} s{sup -1}.

  7. Mechanism of Efficient Anti-Markovnikov Olefin Hydroarylation Catalyzed by Homogeneous Ir(III) Complexes

    SciTech Connect (OSTI)

    Bhalla, Gaurav; Bischof, Steven M; Ganesh, Somesh K; Liu, Xiang Y; Jones, C J; Borzenko, Andrey; Tenn, William J; Ess, Daniel H; Hashiguchi, Brian G; Lokare, Kapil S; Leung, Chin Hin; Oxgaard, Jonas; Goddard, William A; Periana, Roy A

    2011-01-01

    The mechanism of the hydroarylation reaction between unactivated olefins (ethylene, propylene, and styrene) and benzene catalyzed by [(R)Ir(?-acac-O,O,C{sup 3})-(acac-O,O){sub 2}]{sub 2} and [R-Ir(acac-O,O){sub 2}(L)] (R = acetylacetonato, CH{sub 3}, CH{sub 2}CH{sub 3}, Ph, or CH{sub 2}CH{sub 2}Ph, and L = H{sub 2}O or pyridine) Ir(III) complexes was studied by experimental methods. The system is selective for generating the anti-Markovnikov product of linear alkylarenes (61:39 for benzene + propylene and 98:2 for benzene + styrene). The reaction mechanism was found to follow a rate law with first-order dependence on benzene and catalyst, but a non-linear dependence on olefin. {sup 13}C-labelling studies with CH{sub 3}{sup 13}CH{sub 2}-Ir-Py showed that reversible ?-hydride elimination is facile, but unproductive, giving exclusively saturated alkylarene products. The migration of the {sup 13}C-label from the ? to ?-positions was found to be slower than the C–H activation of benzene (and thus formation of ethane and Ph-d{sub 5}-Ir-Py). Kinetic analysis under steady state conditions gave a ratio of the rate constants for CH activation and ?-hydride elimination (k{sub CH}: k{sub ?}) of ~0.5. The comparable magnitude of these rates suggests a common rate determining transition state/intermediate, which has been shown previously with B3LYP density functional theory (DFT) calculations. Overall, the mechanism of hydroarylation proceeds through a series of pre-equilibrium dissociative steps involving rupture of the dinuclear species or the loss of L from Ph-Ir-L to the solvento, 16-electron species, Ph-Ir(acac-O,O){sub 2}-Sol (where Sol refers to coordinated solvent). This species then undergoes trans to cisisomerization of the acetylacetonato ligand to yield the pseudo octahedral species cis-Ph-Ir-Sol, which is followed by olefin insertion (the regioselective and rate determining step), and then activation of the C–H bond of an incoming benzene to generate the product and regenerate the catalyst.

  8. Filamentation of IR and UV femtosecond pulses upon focusing in air

    SciTech Connect (OSTI)

    Dergachev, A A; Ionin, Andrei A; Kandidov, V P; Seleznev, L V; Sinitsyn, D V; Sunchugasheva, E S; Shlenov, Svyatoslav A

    2013-01-31

    The filamentation of IR and UV laser pulses has been studied numerically and experimentally for different initial beam focusing geometries, and linear electron density profiles along the plasma channel of filaments have been obtained. The results demonstrate that changes in laser beam focusing have a stronger effect on filament and plasma channel parameters for UV radiation than for IR radiation. Focusing causes individual high fluence regions produced by refocusing to merge to form a continuous extended filament with a continuous plasma channel. (nonlinear optical phenomena)

  9. Origin of the phase transition in IrTe2: structural modulation and local bonding instability

    SciTech Connect (OSTI)

    Cao, Huibo [ORNL; Chakoumakos, Bryan C [ORNL; Yan, Jiaqiang [ORNL; Zhou, Haidong [ORNL; Custelcean, Radu [ORNL; Mandrus, D. [University of Tennessee (UTK) and Oak Ridge National Laboratory (ORNL); McGuire, Michael A [ORNL; Singh, David J [ORNL; Chen, Xin [ORNL; Yang, Hui [University of Tennessee, Knoxville (UTK)

    2013-01-01

    We used X-ray/neutron diffraction to determine the low temperature (LT) structure of IrTe2. A structural modulation was observed with a wavevector of k =(1/5, 0, 1/5) below Ts285 K, accompanied by a structural transition from a trigonal to a triclinic lattice. We also performed the first principles calculations for high temperature (HT) and LT structures, which elucidate the nature of the phase transition and the LT structure. A local bonding instability associated with the Te 5p states is likely the origin of the structural phase transition in IrTe2.

  10. Low temperature spin dynamics in Cr{sub 7}Ni-Cu-Cr{sub 7}Ni coupled molecular rings

    SciTech Connect (OSTI)

    Bordonali, L.; Furukawa, Y.; Mariani, M.; Sabareesh, K. P. V.; Garlatti, E.; Borsa, F.

    2014-05-07

    Proton Nuclear Magnetic Resonance (NMR) relaxation measurements have been performed down to very low temperature (50?mK) to determine the effect of coupling two Cr{sub 7}Ni molecular rings via a Cu{sup 2+} ion. No difference in the spin dynamics was found from nuclear spin lattice relaxation down to 1.5?K. At lower temperature, the {sup 1}H-NMR line broadens dramatically indicating spin freezing. From the plot of the line width vs. magnetization, it is found that the freezing temperature is higher (260?mK) in the coupled ring with respect to the single Cr{sub 7}Ni ring (140?mK)

  11. $^{62}$Ni($n,?$) and $^{63}$Ni($n,?$) cross sections measured at n_TOF/CERN

    E-Print Network [OSTI]

    C. Lederer; C. Massimi; E. Berthoumieux; N. Colonna; R. Dressler; C. Guerrero; F. Gunsing; F. Käppeler; N. Kivel; M. Pignatari; R. Reifarth; D. Schumann; A. Wallner; S. Altstadt; S. Andriamonje; J. Andrzejewski; L. Audouin; M. Barbagallo; V. Becares; F. Becvar; F. Belloni; B. Berthier; J. Billowes; V. Boccone; D. Bosnar; M. Brugger; M. Calviani; F. Calvino; D. Cano-Ott; C. Carrapico; F. Cerutti; E. Chiaveri; M. Chin; G. Cortes; M. A. Cortes-Giraldo; I. Dillmann; C. Domingo-Pardo; I. Duran; N. Dzysiuk; C. Eleftheriadis; M. Fernandez-Ordonez; A. Ferrari; K. Fraval; S. Ganesan; A. R. Garc?a; G. Giubrone; M. B. Gomez-Hornillos; I. F. Goncalves; E. Gonzalez-Romero; F. Gramegna; E. Griesmayer; P. Gurusamy; S. Harrisopulos; M. Heil; K. Ioannides; D. G. Jenkins; E. Jericha; Y. Kadi; D. Karadimos; G. Korschinek; M. Krticka; J. Kroll; C. Langer; E. Lebbos; H. Leeb; L. S. Leong; R. Losito; M. Lozano; A. Manousos; J. Marganiec; S. Marrone; T. Martinez; P. F. Mastinu; M. Mastromarco; M. Meaze; E. Mendoza; A. Mengoni; P. M. Milazzo; F. Mingrone; M. Mirea; W. Mondalaers; C. Paradela; A. Pavlik; J. Perkowski; R. Plag; A. Plompen; J. Praena; J. M. Quesada; T. Rauscher; A. Riego; F. Roman; C. Rubbia; R. Sarmento; P. Schillebeeckx; S. Schmidt; G. Tagliente; J. L. Tain; D. Tarr?o; L. Tassan-Got; A. Tsinganis; L. Tlustos; S. Valenta; G. Vannini; V. Variale; P. Vaz; A. Ventura; M. J. Vermeulen; R. Versaci; V. Vlachoudis; R. Vlastou; T. Ware; M. Weigand; C. Weiß; T. J. Wright; P. Zugec

    2014-03-19

    The cross section of the $^{62}$Ni($n,\\gamma$) reaction was measured with the time-of-flight technique at the neutron time-of-flight facility n_TOF at CERN. Capture kernels of 42 resonances were analyzed up to 200~keV neutron energy and Maxwellian averaged cross sections (MACS) from $kT=5-100$ keV were calculated. With a total uncertainty of 4.5%, the stellar cross section is in excellent agreement with the the KADoNiS compilation at $kT=30$ keV, while being systematically lower up to a factor of 1.6 at higher stellar temperatures. The cross section of the $^{63}$Ni($n,\\gamma$) reaction was measured for the first time at n_TOF. We determined unresolved cross sections from 10 to 270 keV with a systematic uncertainty of 17%. These results provide fundamental constraints on $s$-process production of heavier species, especially the production of Cu in massive stars, which serve as the dominant source of Cu in the solar system.

  12. PT AND PT/NI "NEEDLE" ELETROCATALYSTS ON CARBON NANOTUBES WITH HIGH ACTIVITY FOR THE ORR

    SciTech Connect (OSTI)

    Colon-Mercado, H.

    2011-11-10

    Platinum and platinum/nickel alloy electrocatalysts supported on graphitized (gCNT) or nitrogen doped carbon nanotubes (nCNT) are prepared and characterized. Pt deposition onto carbon nanotubes results in Pt 'needle' formations that are 3.5 nm in diameter and {approx}100 nm in length. Subsequent Ni deposition and heat treatment results in PtNi 'needles' with an increased diameter. All Pt and Pt/Ni materials were tested as electrocatalysts for the oxygen reduction reaction (ORR). The Pt and Pt/Ni catalysts showed excellent performance for the ORR, with the heat treated PtNi/gCNT (1.06 mA/cm{sup 2}) and PtNi/nCNT (0.664 mA/cm{sup 2}) showing the highest activity.

  13. Structural and Mössbauer spectroscopic study of Fe-Ni alloy nanoparticles

    SciTech Connect (OSTI)

    Kumar, Asheesh; Banerjee, S. Sudarsan, V.; Meena, S. S.

    2014-04-24

    Nano-crystalline Fe-Ni alloys have been synthesized in ethylene glycol medium. Based on XRD studies it is confirmed that, in these alloys Fe atoms are incorporated at Ni site to form Ni-Fe solid solutions. Mössbauer studies have established that for alloy particles having smaller size there is significant concentration of two different types of paramagnetic Fe species and their relative concentration decreased with increase in particle size.

  14. Prompt Proton Decay and Deformed Bands in 56Ni

    SciTech Connect (OSTI)

    Johansson, E. K.; Rudolph, D.; Andersson, L. L.; Torres, D. A.; Ragnarsson, I.; Andreoiu, C.; Baktash, Cyrus; Carpenter, M. P.; Charity, R. J.; Chiara, C. J.; Ekman, J.; Fahlander, C.; Hoel, C.; Pechenaya, O. L.; Reviol, W.; du Rietz, R.; Sarantites, D. G.; Seweryniak, D.; Sobotka, L. G.; Yu, Chang-Hong; Zhu, S.

    2008-06-01

    High-spin states in the doubly magic N=Z nucleus {sup 56}Ni have been investigated with three fusion-evaporation reaction experiments. New {gamma}-ray transitions are added, and a confirmation of a previously suggested prompt proton decay from a rotational band in {sup 56}Ni into the ground state of {sup 55}Co is presented. The rotational bands in {sup 56}Ni are discussed within the framework of cranked Nilsson-Strutinsky calculations.

  15. NISTIR 8056 http://dx.doi.org/10.6028/NIST.IR.8056

    E-Print Network [OSTI]

    Summary of Activities for Fiscal Year 2014 #12;#12;NISTIR 8056 Applied and Computational Mathematics Division Summary of Activities for Fiscal Year 2014 Ronald F. Boisvert, Editor Applied and Computational Mathematics Division Information Technology Laboratory http://dx.doi.org/10.6028/NIST.IR.8056 April 2015 U

  16. ELSEVIER International Journal of Industrial Ergonomics 17 (1996) 285-290 Ir~ernattonatlournalc~

    E-Print Network [OSTI]

    Radwin, Robert G.

    1996-01-01

    ELSEVIER International Journal of Industrial Ergonomics 17 (1996) 285-290 Ir~ernattonatlournalc~ Industrial Ergonomics Short communication A new method for extending the range of conductive polymer sensors measurement instruments are important for providing ergonomics practitioners with a quantitative means

  17. Effective temperatures and radii of planet-hosting stars from IR photometry

    E-Print Network [OSTI]

    I. Ribas; E. Solano; E. Masana; A. Gimenez

    2003-10-16

    In this paper we present and analyse determinations of effective temperatures of planet-hosting stars using infrared (IR) photometry. One of our goals is the comparison with spectroscopic temperatures to evaluate the presence of systematic effects that could alter the determination of metal abundances. To estimate the stellar temperatures we have followed a new approach based on fitting the observed 2MASS IR photometry with accurately calibrated synthetic photometry. Special care has been put in evaluating all sources of possible errors and incorporating them in the analysis. A comparison of our temperature determinations with spectroscopic temperatures published by different groups reveals the presence of no systematic trends and a scatter compatible with the quoted uncertainties of 0.5-1.3%. This mutual agreement strengthens the results of both the spectroscopic and IR photometry analyses. Comparisons with other photometric temperature calibrations, generally with poorer performances, are also presented. In addition, the method employed of fitting IR photometry naturally yields determinations of the stellar semi-angular diameters, which, when combined with the distances, results in estimations of the stellar radii with remarkable accuracies of ~2-4%. A comparison with the only star in the sample with an empirically determined radius (HD 209458 -- from transit photometry) indicates excellent agreement.

  18. Trans Mountain Response to SFU IR No. 2 Trans Mountain Pipeline ULC

    E-Print Network [OSTI]

    Kavanagh, Karen L.

    Trans Mountain Response to SFU IR No. 2 Trans Mountain Pipeline ULC Trans Mountain Expansion Terminal as well as key civil tasks. Request: (1) Please advise whether Trans Mountain has investigated Way and Burnaby Mountain Parkway either during normal operation of the tank farm, or in the event

  19. Water Dynamics in Salt Solutions Studied with Ultrafast Two-Dimensional Infrared (2D IR)

    E-Print Network [OSTI]

    Fayer, Michael D.

    Water Dynamics in Salt Solutions Studied with Ultrafast Two-Dimensional Infrared (2D IR. Many of these species are charged. In the ocean, water interacts with dissolved salts. In biological systems, water interacts with dissolved salts as well as charged amino acids, the zwitterionic head groups

  20. Hydrogen Bond Migration between Molecular Sites Observed with Ultrafast 2D IR Chemical Exchange Spectroscopy

    E-Print Network [OSTI]

    Fayer, Michael D.

    Hydrogen Bond Migration between Molecular Sites Observed with Ultrafast 2D IR Chemical ExchangeVed: January 12, 2010 Hydrogen-bonded complexes between phenol and phenylacetylene are studied using ultrafast hydrogen bonding acceptor sites (phenyl or acetylene) that compete for hydrogen bond donors in solution

  1. AutomaticallyExtracted Thesauri for CrossLanguage IR: When Better is Worse

    E-Print Network [OSTI]

    Brown, Ralf

    the accuracy of the extracted thesaurus can in fact reduce the performance of an IR system using it to perform et al., 1997) was a corpus­based bilingual term­substitution thesaurus, called EBT (for example this thesaurus (Brown, 1997) was originally developed for use in word­ level alignment in an example

  2. Advantageous GOES IR results for ash mapping at high latitudes: Cleveland eruptions 2001

    E-Print Network [OSTI]

    Bluth, Gregg

    Advantageous GOES IR results for ash mapping at high latitudes: Cleveland eruptions 2001 Yingxin Gu] The February 2001 eruption of Cleveland Volcano, Alaska allowed for comparisons of volcanic ash detection using angle also influences the results. The MODIS and AVHRR data give consistent retrievals of the ash cloud

  3. The chemical instability of Na{sub 2}IrO{sub 3} in air

    SciTech Connect (OSTI)

    Krizan, J.W., E-mail: jkrizan@princeton.edu; Roudebush, J.H.; Fox, G.M.; Cava, R.J.

    2014-04-01

    Highlights: • Na{sub 2}IrO{sub 3} decomposes rapidly in laboratory air. • The decomposition requires the simultaneous presence of CO{sub 2} and H{sub 2}O. • Decomposition results in a dramatic change in the magnetic properties. • Second 5 K feature in magnetic susceptibility not previously reported. - Abstract: We report that Na{sub 2}IrO{sub 3}, which has a layered honeycomb iridium oxide sublattice interleaved by Na planes, decomposes in laboratory air while maintaining the same basic crystal structure. The decomposition reaction was monitored by time-dependent powder X-ray diffraction under different ambient atmospheres, through which it was determined that it occurs only in the simultaneous presence of both CO{sub 2} and H{sub 2}O. A hydrated sodium carbonate is the primary decomposition product along with altered Na{sub 2}IrO{sub 3}. The diffraction signature of the altered Na{sub 2}IrO{sub 3} is quite similar to that of the pristine material, which makes the detection of decomposition difficult in a sample handled under ordinary laboratory conditions. The decomposed samples show a significantly decreased magnetic susceptibility and the disappearance of the low temperature antiferromagnetic transition considered to be characteristic of the phase. Samples that have never been exposed to air after synthesis display a previously unreported magnetic transition at 5 K.

  4. The mid-IR spectra of 9-ethyl guanine, guanosine, and 2-deoxyguanosine

    E-Print Network [OSTI]

    de Vries, Mattanjah S.

    they are blind to species with sub picosecond lifetime excited states. The detection in helium droplets relies. Choi and Miller have observed the keto tautomers in helium droplets, showing their IR frequencies between the R2PI and the helium droplet work is not only in the degree of cooling but also

  5. The system for delivery of IR laser radiaton into high vacuum

    E-Print Network [OSTI]

    Abakumova, E V; Krasnov, A A; Muchnoi, N Yu; Pyata, E E

    2015-01-01

    The system for insertion of a laser beam into the vacuum chamber of high-energy storage ring is described. The main part of the system is the high-vacuum viewport for the IR radiation, based on ZnSe or GaAs crystals. The design of the viewports is presented.

  6. Neuroglobin dynamics observed with ultrafast 2D-IR vibrational echo spectroscopy

    E-Print Network [OSTI]

    Fayer, Michael D.

    Neuroglobin dynamics observed with ultrafast 2D-IR vibrational echo spectroscopy Haruto Ishikawa Contributed by Michael D. Fayer, August 15, 2007 (sent for review July 25, 2007) Neuroglobin (Ngb), a protein energy minimum. myoglobin mutants protein dynamics energy landscape Neuroglobin (Ngb) is a recently

  7. The TIJAH XML-IR system at INEX 2003 Johan List1

    E-Print Network [OSTI]

    Hiemstra, Djoerd

    its mapping into a query execution strategy. The logical layer exploits probabilistic region algebra components. The logical algebra expressions are mapped into efficient rela- tional algebra expressions over participated with the TIJAH XML-IR retrieval system, a research pro- totype built on top of the Monet

  8. Ion Impacts on Graphene/Ir(111): Interface Channeling, Vacancy Funnels, and a Nanomesh

    E-Print Network [OSTI]

    Krasheninnikov, Arkady V.

    simulations we study the production of defects in graphene on Ir(111) under grazing incidence of low energy Xe Koln, Zulpicher Straße 77, 50937 Koln, Germany Department of Physics, University of Helsinki, P.O. Box of Materials Science, University of Ulm, 89081 Ulm, Germany Department of Physics, University of Vienna

  9. Minimizing Energy Consumption in IR-UWB Based Wireless Sensor Networks

    E-Print Network [OSTI]

    Heinzelman, Wendi

    Minimizing Energy Consumption in IR-UWB Based Wireless Sensor Networks Tianqi Wang, Wendi communications systems, where transmit power can be flexibly adjusted to minimize the energy consumption [3] [4 Heinzelman and Alireza Seyedi Department of Electrical and Computer Engineering, University of Rochester

  10. Ductile Ni[sub 3]Al alloys as bonding agents for ceramic materials

    DOE Patents [OSTI]

    Tiegs, T.N.; McDonald, R.R.

    1990-04-24

    An improved ceramic-metal composite is described comprising a mixture of a ceramic material with a ductile intermetallic alloy, preferably Ni[sub 3]Al. 2 figs.

  11. Ductile Ni.sub.3 Al alloys as bonding agents for ceramic materials in cutting tools

    DOE Patents [OSTI]

    Tiegs, Terry N. (Lenoir City, TN); McDonald, Robert R. (Traverse City, MI)

    1991-01-01

    An improved ceramic-metal composite comprising a mixture of a ceramic material with a ductile intermetallic alloy, preferably Ni.sub.3 Al.

  12. Ductile Ni[sub 3]Al alloys as bonding agents for ceramic materials in cutting tools

    DOE Patents [OSTI]

    Tiegs, T.N.; McDonald, R.R.

    1991-05-14

    An improved ceramic-metal composite comprising a mixture of a ceramic material with a ductile intermetallic alloy, preferably Ni[sub 3]Al is disclosed. 2 figures.

  13. Neutron Scattering of CeNi at the Spallation Neutron Source at...

    Office of Scientific and Technical Information (OSTI)

    Spallation Neutron Source at Oak Ridge National Laboratory: A Preliminary Report Citation Details In-Document Search Title: Neutron Scattering of CeNi at the Spallation Neutron...

  14. Strain mediated coupling in magnetron sputtered multiferroic PZT/Ni-Mn-In/Si thin film heterostructure

    SciTech Connect (OSTI)

    Singh, Kirandeep; Kaur, Davinder, E-mail: dkaurfph@iitr.ernet.in [Functional Nanomaterials Research Lab, Department of Physics and Centre of Nanotechnology, Indian Institute of Technology Roorkee, Roorkee-247667, Uttarakhand (India); Singh, Sushil Kumar [Functional Materials Division, Solid State Physics Lab (SSPL), DRDO, Lucknow Road, Timarpur, Delhi 110054 (India)

    2014-09-21

    The strain mediated electrical and magnetic properties were investigated in PZT/Ni-Mn-In heterostructure deposited on Si (100) by dc/rf magnetron sputtering. X-ray diffraction pattern revealed that (220) orientation of Ni-Mn-In facilitate the (110) oriented tertragonal phase growth of PZT layer in PZT/Ni-Mn-In heterostructure. A distinctive peak in dielectric constant versus temperature plots around martensitic phase transformation temperature of Ni-Mn-In showed a strain mediated coupling between Ni-Mn-In and PZT layers. The ferroelectric measurement taken at different temperatures exhibits a well saturated and temperature dependent P-E loops with a highest value of P{sub sat}~55 ?C/cm˛ obtained during martensite-austenite transition temperature region of Ni-Mn-In. The stress induced by Ni-Mn-In layer on upper PZT film due to structural transformation from martensite to austenite resulted in temperature modulated Tunability of PZT/Ni-Mn-In heterostructure. A tunability of 42% was achieved at 290 K (structural transition region of Ni-Mn-In) in these heterostructures. I-V measurements taken at different temperatures indicated that ohmic conduction was the main conduction mechanism over a large electric field range in these heterostructures. Magnetic measurement revealed that heterostructure was ferromagnetic at room temperature with a saturation magnetization of ~123 emu/cmł. Such multiferroic heterostructures exhibits promising applications in various microelectromechanical systems.

  15. Synthesis and Magnetic Properties of Ni-Zirconia Composites I. Zhitomirsky,* M. Niewczas, and A. Petric

    E-Print Network [OSTI]

    Niewczas, Marek

    Synthesis and Magnetic Properties of Ni-Zirconia Composites I. Zhitomirsky,* M. Niewczas, and A of the composites. Key Words: Electrodeposition; Hydrolysis; Polynuclear species; Zirconia; Nickel; Composite

  16. SF6432-NI Fixed Price Contracts with the Newly Independent States...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CORPORATION SF 6432-NI (112015) SECTION II STANDARD TERMS AND CONDITIONS FOR FIXED PRICE CONTRACTS WITH THE NEWLY INDEPENDENT STATES OF THE FORMER SOVIET UNION THE FOLLOWING...

  17. Simple route for the synthesis of supercapacitive Co-Ni mixed hydroxide thin films

    SciTech Connect (OSTI)

    Dubal, D.P.; Department of Materials Science and Engineering, Gwangju Institute of Science and Technology, 261 Cheomdan-gwagiro, Buk-gu, Gwangju 500-712 ; Jagadale, A.D.; Patil, S.V.; Lokhande, C.D.

    2012-05-15

    Highlights: Black-Right-Pointing-Pointer Novel method for deposition of Co-Ni mixed hydroxide. Black-Right-Pointing-Pointer Nanoparticle network of Co-Ni hydroxide. Black-Right-Pointing-Pointer High specific capacitance of 672 F g{sup -1}. Black-Right-Pointing-Pointer High discharge/charge rates. -- Abstract: Facile synthesis of Co-Ni mixed hydroxides films with interconnected nanoparticles networks through two step route is successfully established. These films have been characterized by X-ray diffraction (XRD), Fourier transform infrared technique (FTIR), scanning electron microscopy (SEM) and wettability test. Co-Ni film formation is confirmed from XRD and FTIR study. SEM shows that the surface of Co-Ni films is composed of interconnected nanoparticles. Contact angle measurement revealed the hydrophilic nature of films which is feasible for the supercapacitor. The electrochemical performance of the film is evaluated by cyclic voltammetry, and constant-current charge/discharge cycling techniques. Specific capacitance of the Co-Ni mixed hydroxide electrode achieved 672 F g{sup -1}. Impedance analysis shows that Co-Ni mixed hydroxide electrode provides less resistance for the intercalation and de-intercalation of ions. The Co-Ni mixed electrode exhibited good charge/discharge rate at different current densities. The results demonstrated that Co-Ni mixed hydroxide composite is very promising for the next generation high performance electrochemical supercapacitors.

  18. Comparative Investigation of Benzene Steam Reforming over Spinel Supported Rh and Ir Catalysts

    SciTech Connect (OSTI)

    Mei, Donghai; Lebarbier, Vanessa MC; Rousseau, Roger J.; Glezakou, Vassiliki Alexandra; Albrecht, Karl O.; Kovarik, Libor; Flake, Matthew D.; Dagle, Robert A.

    2013-06-01

    In a combined experimental and first-principles density functional theory (DFT) study, benzene steam reforming (BSR) over MgAl2O4 supported Rh and Ir catalysts was investigated. Experimentally, it has been found that both highly dispersed Rh and Ir clusters (1-2 nm) on the MgAl2O4 spinel support are stable during the BSR in the temperature range of 700-850?C. Compared to the Ir/MgAl2O4 catalyst, the Rh/MgAl2O4 catalyst is more active with higher benzene turnover frequency and conversion. At typical steam conditions with the steam-to-carbon ratio > 12, the benzene conversion is only a weak function of the H2O concentration in the feed. This suggests that the initial benzene decomposition step rather than the benzene adsorption is most likely the rate-determined step in BSR over supported Rh and Ir catalysts. In order to understand the differences between the two catalysts, we followed with a comparative DFT study of initial benzene decomposition pathways over two representative model systems for each supported metal (Rh and Ir) catalysts. A periodic terrace (111) surface and an amorphous 50-atom metal cluster with a diameter of 1.0 nm were used to represent the two supported model catalysts under low and high dispersion conditions. Our DFT results show that the decreasing catalyst particle size enhances the benzene decomposition on supported Rh catalysts by lowering both C-C and C-H bond scission. The activation barriers of the C-C and the C-H bond scission decrease from 1.60 and 1.61 eV on the Rh(111) surface to 1.34 and 1.26 eV on the Rh50 cluster. For supported Ir catalysts, the decreasing particle size only affects the C-C scission. The activation barrier of the C-C scission of benzene decreases from 1.60 eV on the Ir(111) surface to 1.35 eV on the Ir50 cluster while the barriers of the C-H scission are practically the same. The experimentally measured higher BSR activity on the supported highly dispersed Rh catalyst can be rationalized by the thermodynamic limitation for the very first C-C bond scission of benzene on the small Ir50 catalyst. The C-C bond scission of benzene on the small Ir50 catalyst is highly endothermic although the barrier is competitive with the barriers of both the C-C and the C-H bond-breakings on the small Rh50 catalyst. The calculations also imply that, for the supported Rh catalysts the C-C and C-H bond scissions are competitive, independently of the Rh cluster sizes. After the initial dissociation step via either the C-C or the C-H bond scission, the C-H bond breaking seems to be more favorable rather than the C-C bond breaking on the larger Rh terrace surface. This work was financially supported by the United States Department of Energy’s Office of Biomass Program’s. Computing time was granted by a user project at the Molecular Science Computing Facility in the William R. Wiley Environmental Molecular Sciences Laboratory (EMSL), a national scientific user facility sponsored by the Department of Energy's Office of Biological and Environmental Research and located at Pacific Northwest National Laboratory.

  19. Superior performance of Ni–W–Ce mixed-metal oxide catalysts for ethanol steam reforming: Synergistic effects of W- and Ni-dopants

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Liu, Zongyuan; Xu, Wenqian; Yao, Siyu; Johnson-Peck, Aaron C.; Zhao, Fuzhen; Michorczyk, Piotr; Kubacka, Anna; Stach, Eric A.; Fernández-García, Marcos; Senanayake, Sanjaya D.; et al

    2014-11-26

    In this study, the ethanol steam reforming (ESR) reaction was examined over a series of Ni-W-Ce oxide catalysts. The structures of the catalysts were characterized using in-situ techniques including X-ray diffraction, Pair Distribution Function, X-ray absorption fine structure and transmission electron microscopy; while possible surface intermediates for the ESR reaction were investigated by Diffuse Reflectance Infrared Fourier Transform Spectroscopy. In these materials, all the W and part of the Ni were incorporated into the CeO? lattice, with the remaining Ni forming highly dispersed nano NiO (more »under ESR conditions. The Ni-W-Ce systeme exhibited a much larger lattice strain than those seen for Ni-Ce and W-Ce. Synergistic effects between Ni and W inside ceria produced a substantial amount of defects and O vacancies that led to high catalytic activity, selectivity and stability (i.e. resistance to coke formation) during ethanol steam reforming.« less

  20. Synthesis, Structure, and Reactivity of O-Donor Ir(III) Complexes: C-H Activation Studies with Benzene

    E-Print Network [OSTI]

    Goddard III, William A.

    with Benzene Gaurav Bhalla, Xiang Yang Liu, Jonas Oxgaard, William A. Goddard, III, and Roy A. Periana. All the R-Ir-Py complexes undergo quantitative, intermolecular CH activation reactions with benzene to benzene to generate a discrete benzene complex, cis-R-Ir-PhH; and (D) rapid C-H cleavage. Kinetic isotope

  1. Big picture Ads Duplicate detection Spam Web IR Size of the web Web Search and Text Mining

    E-Print Network [OSTI]

    Gray, Alexander

    Big picture Ads Duplicate detection Spam Web IR Size of the web Web Search and Text Mining http://www.cc.gatech.edu/~agray/6240spr11 IIR 19: Web Search Basics Alexander Gray Georgia Institute of Technology, College of Computing 2011 Gray: Web Search Basics 1 / 117 #12;Big picture Ads Duplicate detection Spam Web IR Size

  2. Paving the road in virtual spaces IRS Workshop Territoriality of the Commons 29.-30. Sept.2011 Rainer Kuhlen

    E-Print Network [OSTI]

    Kuhlen, Rainer

    Paving the road in virtual spaces­ IRS Workshop Territoriality of the Commons 29.-30. Sept.2011 the road in virtual spaces How to materialize rights to immaterial commons #12;Openness ­ Grundprinzip des;Openness ­ Grundprinzip des Handelns in elektronischen Räumen 4 #12;Paving the road in virtual spaces­ IRS

  3. An X-ray, IR, and Submillimeter Flare of Sagittarius A*

    E-Print Network [OSTI]

    D. P. Marrone; F. K. Baganoff; M. R. Morris; J. M. Moran; A. M. Ghez; S. D. Hornstein; C. D. Dowell; D. J. Munoz; M. W. Bautz; G. R. Ricker; W. N. Brandt; G. P. Garmire; J. R. Lu; K. Matthews; J. -H. Zhao; R. Rao; G. C. Bower

    2008-07-14

    Energetic flares are observed in the Galactic supermassive black hole Sagittarius A* from radio to X-ray wavelengths. On a few occasions, simultaneous flares have been detected in IR and X-ray observations, but clear counterparts at longer wavelengths have not been seen. We present a flare observed over several hours on 2006 July 17 with the Chandra X-Ray Observatory, the Keck II telescope, the Caltech Submillimeter Observatory, and the Submillimeter Array. All telescopes observed strong flare events, but the submillimeter peak is found to occur nearly 100 minutes after the X-ray peak. Submillimeter polarization data show linear polarization in the excess flare emission, increasing from 9% to 17% as the flare passes through its peak, consistent with a transition from optically thick to thin synchrotron emission. The temporal and spectral behavior of the flare require that the energetic electrons responsible for the emission cool faster than expected from their radiative output. This is consistent with adiabatic cooling in an expanding emission region, with X-rays produced through self-Compton scattering, although not consistent with the simplest model of such expansion. We also present a submillimeter flare that followed a bright IR flare on 2005 July 31. Compared to 2006, this event had a larger peak IR flux and similar submillimeter flux, but it lacked measurable X-ray emission. It also showed a shorter delay between the IR and submillimeter peaks. Based on these events we propose a synchrotron and self-Compton model to relate the submillimeter lag and the variable IR/X-ray luminosity ratio.

  4. Effect of the accumulation of excess Ni atoms in the crystal structure of the intermetallic semiconductor n-ZrNiSn

    SciTech Connect (OSTI)

    Romaka, V. A.; Rogl, P.; Romaka, V. V.; Stadnyk, Yu. V.; Hlil, E. K.; Krajovskii, V. Ya.; Horyn, A. M.

    2013-07-15

    The crystal structure, electron density distribution, and energy, kinetic, and magnetic properties of the n-ZrNiSn intermetallic semiconductor heavily doped with a Ni impurity are investigated. The effect of the accumulation of an excess number of Ni{sub 1+x} atoms in tetrahedral interstices of the crystal structure of the semiconductor is found and the donor nature of such structural defects that change the properties of the semiconductor is established. The results obtained are discussed within the Shklovskii-Efros model of a heavily doped and strongly compensated semiconductor.

  5. Platinum-monolayer Electrocatalysts: Palladium Interlayer on IrCo Alloy Core Improves Activity in Oxygen-reduction Reaction

    SciTech Connect (OSTI)

    Gong, K.; Chen, W.-F.; Sasaki, K.; Su, D.; Vukmirovic, M.B.; Zhou, W.; Izzo, E.L.; Perez-Acosta, C.; Hirunsit, P.; Balbuena, P.B.; Adzic, R.R.

    2010-11-15

    We describe the synthesis and electrocatalytic properties of a new low-Pt electrocatalyst consisting of an IrCo core, a Pd interlayer, and a surface Pt monolayer, emphasizing the interlayer's role in improving electrocatalytic activity for the oxygen-reduction reaction on Pt in HClO{sub 4} solution. We prepared the IrCo alloys by decomposing, at 800 C, hexacyanometalate, KCoIr(CN){sub 6}, adsorbed on the carbon surfaces. The synthesis of Ir{sub 3}Co/C involved heating a mix of metal salts and carbon in hydrogen at 500 C. Thereafter, we placed a palladium and/or platinum monolayer on them via the galvanic displacement of an underpotentially deposited copper monolayer. The electrocatalysts were characterized using structural- and electrochemical-techniques. For PtML/PdML/IrCo/C, we observed a Pt mass activity of 1.18 A/mg{sub (Pt)} and the platinum-group-metals mass of 0.16 A/mg{sub (Pt, Pd, Ir)}. In comparison, without a Pd interlayer, i.e., Pt{sub ML}/IrCo/C, the activities of 0.15 A/mg{sub (Pt)} and 0.036 A/mg{sub (Pt, Pd, Ir)} were considerably lower. We consider that the palladium interlayer plays an essential role in achieving high catalytic activity by adjusting the electronic interaction of the platinum monolayer with the IrCo core, so that it accelerates the kinetics of adsorption and desorption of the intermediates of oxygen reduction. A similar trend was observed for Pt{sub ML}/Pd{sub ML} and Pt{sub ML} deposited on Ir{sub 3}Co/C alloy core. We used density functional theory to interpret the observed phenomena.

  6. Improved oxidation sulfidation resistance of Fe-Cr-Ni alloys

    DOE Patents [OSTI]

    Natesan, K.; Baxter, D.J.

    1983-07-26

    High temperature resistance of Fe-Cr-Ni alloy compositions to oxidative and/or sulfidative conditions is provided by the incorporation of about 1 to 8 wt % of Zr or Nb and results in a two-phase composition having an alloy matrix as the first phase and a fine grained intermetallic composition as the second phase. The presence and location of the intermetallic composition between grains of the matrix provides mechanical strength, enhanced surface scale adhesion, and resistance to corrosive attack between grains of the alloy matrix at temperatures of 500 to 1000/sup 0/C.

  7. Oxidation sulfidation resistance of Fe-Cr-Ni alloys

    DOE Patents [OSTI]

    Natesan, Ken (Naperville, IL); Baxter, David J. (Woodridge, IL)

    1984-01-01

    High temperature resistance of Fe-Cr-Ni alloy compositions to oxidative and/or sulfidative conditions is provided by the incorporation of about 1-8 wt. % of Zr or Nb and results in a two-phase composition having an alloy matrix as the first phase and a fine grained intermetallic composition as the second phase. The presence and location of the intermetallic composition between grains of the matrix provides mechanical strength, enhanced surface scale adhesion, and resistance to corrosive attack between grains of the alloy matrix at temperatures of 500.degree.-1000.degree. C.

  8. Stable atomic structure of NiTi austenite

    SciTech Connect (OSTI)

    Zarkevich, Nikolai A [Ames Laboratory; Johnson, Duane D [Ames Laboratory

    2014-08-01

    Nitinol (NiTi), the most widely used shape-memory alloy, exhibits an austenite phase that has yet to be identified. The usually assumed austenitic structure is cubic B2, which has imaginary phonon modes, hence it is unstable. We suggest a stable austenitic structure that “on average” has B2 symmetry (observed by x-ray and neutron diffraction), but it exhibits finite atomic displacements from the ideal B2 sites. The proposed structure has a phonon spectrum that agrees with that from neutron scattering, has diffraction spectra in agreement with x-ray diffraction, and has an energy relative to the ground state that agrees with calorimetry data.

  9. An analysis of the x-ray linear dichroism spectrum for NiO thin films grown on vicinal Ag(001)

    E-Print Network [OSTI]

    Wu, Y.Z.

    2008-01-01

    dichroism spectrum for NiO thin films grown on vicinal Ag(Antiferromagnetic (AFM) NiO thin films are grown epitaxiallyXLD). We find that the NiO AFM spin exhibits an in- plane

  10. Improvements in the M-T relation and mass function and the measured Omega_m through clusters evolution

    E-Print Network [OSTI]

    A. Del Popolo

    2003-09-05

    In this paper, I revisit the constraints obtained by several authors (Reichart et al. 1999; Eke et al. 1998; Henry 2000) on the estimated values of Omega_m, n and sigma_8 in the light of recent theoretical developments: 1) new theoretical mass functions (Sheth & Tormen 1999, Sheth, Mo & Tormen 1999, Del Popolo 2002b); 2) a more accurate mass-temperature relation, also determined for arbitrary Omega_m and Omega_{\\Lambda} (Voit 2000, Pierpaoli et al. 2001, Del Popolo 2002a). Firstly, using the quoted improvements, I re-derive an expression for the X-ray Luminosity Function (XLF), similarly to Reichart et al. (1999), and then I get some constraints to \\Omega_m and n, by using the ROSAT BCS and EMSS samples and maximum-likelihood analysis. Then I re-derive the X-ray Temperature Function (XTF), similarly to Henry (2000) and Eke et al. (1999), re-obtaining the constraints on Omega_m, n, sigma_8. Both in the case of the XLF and XTF, the changes in the mass function and M-T relation produces an increase in Omega_m of \\simeq 20% and similar results in sigma_8 and n.

  11. A Complete Solution Classification and Unified Algorithmic Treatment for the One- and Two-Step Asymmetric S-Transverse Mass (MT2) Event Scale Statistic

    E-Print Network [OSTI]

    Joel W. Walker

    2014-08-29

    The MT2 or "s-transverse mass" statistic was developed to associate a parent mass scale to a missing transverse energy signature, given that escaping particles are generally expected in pairs, while collider experiments are sensitive to just a single transverse momentum vector sum. This document focuses on the generalized extension of that statistic to asymmetric one- and two-step decay chains, with arbitrary child particle masses and upstream missing transverse momentum. It provides a unified theoretical formulation, complete solution classification, taxonomy of critical points, and technical algorithmic prescription for treatment of the MT2 event scale. An implementation of the described algorithm is available for download, and is also a deployable component of the author's selection cut software package AEACuS (Algorithmic Event Arbiter and Cut Selector). Appendices address combinatoric event assembly, algorithm validation, and a complete pseudocode.

  12. Probing the Mechanism of the Mycobacterium tuberculosis [beta]-Ketoacyl-Acyl Carrier Protein Synthase III mtFabH: Factors Influencing Catalysis and Substrate Specificity

    SciTech Connect (OSTI)

    Brown, Alistair K.; Sridharan, Sudharsan; Kremer, Laurent; Lindenberg, Sandra; Dover, Lynn G.; Sacchettini, James C.; Besra, Gurdyal S.

    2010-11-30

    Mycolic acids are the dominant feature of the Mycobacterium tuberculosis cell wall. These {alpha}-alkyl, {beta}-hydroxy fatty acids are formed by the condensation of two fatty acids, a long meromycolic acid and a shorter C{sub 24}-C{sub 26} fatty acid. The component fatty acids are produced via a combination of type I and II fatty acid synthases (FAS) with FAS-I products being elongated by FAS-II toward meromycolic acids. The {beta}-ketoacyl-acyl carrier protein (ACP) synthase III encoded by mtfabH (mtFabH) links FAS-I and FAS-II, catalyzing the condensation of FAS-I-derived acyl-CoAs with malonyl-acyl carrier protein (ACP). The acyl-CoA chain length specificity of mtFabH was assessed in vitro; the enzyme extended longer, physiologically relevant acyl-CoA primers when paired with AcpM, its natural partner, than with Escherichia coli ACP. The ability of the enzyme to use E. coli ACP suggests that a similar mode of binding is likely with both ACPs, yet it is clear that unique factors inherent to AcpM modulate the substrate specificity of mtFabH. Mutation of proposed key mtFabH residues was used to define their catalytic roles. Substitution of supposed acyl-CoA binding residues reduced transacylation, with double substitutions totally abrogating activity. Mutation of Arg{sup 46} revealed its more critical role in malonyl-AcpM decarboxylation than in the acyl-CoA binding role. Interestingly, this effect was suppressed intragenically by Arg{sup 161} {yields} Ala substitution. Our structural studies suggested that His{sup 258}, previously implicated in malonyl-ACP decarboxylation, also acts as an anchor point for a network of water molecules that we propose promotes deprotonation and transacylation of Cys{sup 122}.

  13. Structural and tectonic implications of pre-Mt. Simon strata -- or a lack of such -- in the western part of the Illinois basin

    SciTech Connect (OSTI)

    Sargent, M.L. (Illinois State Geological Survey, Champaign, IL (United States))

    1993-03-01

    The discovery of a pre-Mt. Simon lithic arenite (arkose) in southwestern Ohio has lead to reevaluation of many basement tests in the region. Several boreholes in adjacent states have been reexamined by others and are now believed to bottom in the Middle Run Formation. Seismic-reflection sections in western Ohio and Indiana have indicated pre-Mt. Simon basins filled with layered rocks that are interpreted to be Middle Run, however, the pre-Mt. Simon basins and east of Illinois. Samples from Illinois basement tests were reexamined to determine whether they had encountered similar strata. All reported crystalline-basement tests in Illinois show diagnostic igneous textures and mineralogical associations. Coarsely crystalline samples in cores show intergrown subhedral grains of quartz, microcline, and sodic plagioclase. Medium-crystalline rocks in cuttings samples show numerous examples of micrographic intergrowths of quartz and K-feldspar. This texture cannot be authigenically grown in a sediment and probably could not have survived a single cycle of erosion and deposition. Aphanitic rocks show porphyritic and spherulitic textures that are distinctly igneous and would be destroyed by weathering. Substantial relief on the Precambrian crystalline surface in Illinois is postulated for major structural features like the LaSalle Anticlinorium, the Sparta Shelf, the Ste. Genevieve Fault zone, etc. Paleotopographic relief up to 300 m (1,000 feet) is documented from drilling on the western flank of the basin.

  14. Deformations and magnetic rotations in the {sup 60}Ni nucleus

    SciTech Connect (OSTI)

    Torres, D. A.; Cristancho, F.; Andersson, L.-L.; Johansson, E. K.; Rudolph, D.; Fahlander, C.; Ekman, J.; Rietz, R. du; Andreoiu, C.; Carpenter, M. P.; Seweryniak, D.; Zhu, S.; Charity, R. J.; Chiara, C. J.; Hoel, C.; Pechenaya, O. L.; Reviol, W.; Sarantites, D. G.; Sobotka, L. G.; Baktash, C.

    2008-11-15

    Data from three experiments using the heavy-ion fusion evaporation-reaction {sup 36}Ar+{sup 28}Si have been combined to study high-spin states in the residual nucleus {sup 60}Ni, which is populated via the evaporation of four protons from the compound nucleus {sup 64}Ge. The GAMMASPHERE array was used for all the experiments in conjunction with a 4{pi} charged-particle detector arrays (MICROBALL, LUWUSIA) and neutron detectors (NEUTRON SHELL) to allow for the detection of {gamma} rays in coincidence with the evaporated particles. An extended {sup 60}Ni level scheme is presented, comprising more than 270{gamma}-ray transitions and 110 excited states. Their spins and parities have been assigned via directional correlations of {gamma} rays emitted from oriented states. Spherical shell-model calculations in the fp-shell characterize some of the low-spin states, while the experimental results of the rotational bands are analyzed with configuration-dependent cranked Nilsson-Strutinsky calculations.

  15. Fabrication of NiTi shape memory alloy from elemental powders by hot isostatic pressing 

    E-Print Network [OSTI]

    McNeese, Matthew Doyle

    1997-01-01

    .0 and 50.6at.% Ni, packed and sealed into stainless steel containers, hot isostatically pressed (HIPed) at 20OMPa and 900-1050 'C, and machined to expose a gauge section of consolidated NiTi material for thennomechanical testing. Some samples of material...

  16. COMPARATIVE LIFE CYCLE ASSESSMENT OF ALCALINE CELLS AND NI-MH RECHARGEABLE BATTERIES

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Page 1 COMPARATIVE LIFE CYCLE ASSESSMENT OF ALCALINE CELLS AND NI-MH RECHARGEABLE BATTERIES Jean by applying the LCA methodology to evaluate the environmental footprint of alkaline cells and Ni-MH batteries phase. Besides, the emphasis on rechargeable batteries is only justified from an environmental point

  17. Nanoscale compositional analysis of NiTi shape memory alloy films deposited by DC magnetron sputtering

    SciTech Connect (OSTI)

    Sharma, S. K.; Mohan, S.; Bysakh, S.; Kumar, A.; Kamat, S. V.

    2013-11-15

    The formation of surface oxide layer as well as compositional changes along the thickness for NiTi shape memory alloy thin films deposited by direct current magnetron sputtering at substrate temperature of 300 °C in the as-deposited condition as well as in the postannealed (at 600 °C) condition have been thoroughly studied by using secondary ion mass spectroscopy, x-ray photoelectron spectroscopy, and scanning transmission electron microscopy-energy dispersive x-ray spectroscopy techniques. Formation of titanium oxide (predominantly titanium dioxide) layer was observed in both as-deposited and postannealed NiTi films, although the oxide layer was much thinner (8 nm) in as-deposited condition. The depletion of Ti and enrichment of Ni below the oxide layer in postannealed films also resulted in the formation of a graded microstructure consisting of titanium oxide, Ni{sub 3}Ti, and B2 NiTi. A uniform composition of B2 NiTi was obtained in the postannealed film only below a depth of 200–250 nm from the surface. Postannealed film also exhibited formation of a ternary silicide (Ni{sub x}Ti{sub y}Si) at the film–substrate interface, whereas no silicide was seen in the as-deposited film. The formation of silicide also caused a depletion of Ni in the film in a region ?250–300 nm just above the film substrate interface.

  18. Method For Making Electronic Circuits Having Nial And Ni3al Substrates

    DOE Patents [OSTI]

    Deevi, Seetharama C. (Midlothian, VA); Sikka, Vinod K. (Oak Ridge, TN)

    2001-01-30

    A method for making electronic circuit component having improved mechanical properties and thermal conductivity comprises steps of providing NiAl and/or Ni.sub.3 Al, and forming an alumina layer thereupon prior to applying the conductive elements. Additional layers of copper-aluminum alloy or copper further improve mechanical strength and thermal conductivity.

  19. Dehydrogenation of Propane to Propylene over Supported Model NiAu Catalysts

    E-Print Network [OSTI]

    Goodman, Wayne

    Dehydrogenation of Propane to Propylene over Supported Model Ni­Au Catalysts Zhen Yan · Yunxi Yao 2012 Ó Springer Science+Business Media, LLC 2012 Abstract Hydrogenolysis and dehydrogenation of propane. For the conversionofpropane in the presence of hydrogen, the dehydrogenation of propane to propylene was observed onthe Ni

  20. Evolution of Graphene Growth on Ni and Cu by Carbon Isotope Labeling

    E-Print Network [OSTI]

    and acceptance by the semiconductor industry, Ni and Cu have received the most attention as a graphene substrateEvolution of Graphene Growth on Ni and Cu by Carbon Isotope Labeling Xuesong Li, Weiwei Cai, Luigi Instruments Incorporated, Dallas, Texas 75243 Received August 3, 2009 ABSTRACT Large-area graphene growth

  1. A Linear Combination Analyses Approach For Directly Speciating Ni Contaminated Soils.

    E-Print Network [OSTI]

    Sparks, Donald L.

    A Linear Combination Analyses Approach For Directly Speciating Ni Contaminated Soils. (S02-trivedi215458-Oral) Abstract: To provide an accurate description of the fate of Ni in aerial- contaminated soils to combine multiple analytical techniques to accurately determine metal speciation in complex soil systems

  2. Finite Element Based Micromechanical Analysis of Precipitated NiTi Shape Memory Alloys 

    E-Print Network [OSTI]

    Cox, Austin Edward

    2015-07-22

    into the material and its thermomechanical response than ever before. The most widely modeled and produced SMA class in industry today is one which hosts Ni as a core component of its composition, and usually takes the form of NiTi. When these SMA materials are heat...

  3. Ni-dispersed fullerenes: Hydrogen storage and desorption properties Weon Ho Shin and Seong Ho Yang

    E-Print Network [OSTI]

    Goddard III, William A.

    Ni-dispersed fullerenes: Hydrogen storage and desorption properties Weon Ho Shin and Seong Ho Yang could be viable alternatives to reversible hydrogen storage. It is demonstrated that a single Ni coated-dispersed fullerenes are considered to be the novel hydrogen storage media capable of storing 6.8 wt % H2, thus

  4. Biomaterials 24 (2003) 39313939 Corrosion and wear-corrosion behavior of NiTi modified

    E-Print Network [OSTI]

    Crone, Wendy C.

    2003-01-01

    Biomaterials 24 (2003) 3931­3939 Corrosion and wear-corrosion behavior of NiTi modified by plasma, aerospace, and automotive industries. NiTi alloys are important materials for biomedical and dental devices. The alloy has been used for making orthodontic dental arch wires and medical guide wires for diagnostic

  5. Effect of Mo Addition on Structure and Magnetocaloric Effect in c-FeNi Nanocrystals

    E-Print Network [OSTI]

    Laughlin, David E.

    - tion metals have been investigated to replace rare- earth metals for cost reduction. Researchers have comparable to those of rare-earth metals. Recently, Fe-Ni alloys were suggested as economical alterna- tives3 refrigerants without critical rare-earth materials. Key words: Nanostructured FeNi, magnetocaloric effect

  6. Superelastic and cyclic response of NiTi SMA at various strain rates and temperatures

    E-Print Network [OSTI]

    Nemat-Nasser, Sia

    in the range of 77­400 K. The influence of the annealing temperature on the fatigue response is also examined of NiTi SMAs depend on the annealing temperature; (2) in cyclic loading, the dissipated energy over loading rates, NiTi SMAs show properties similar to ordinary steels, as has been established by the first

  7. Formation and Stability of Ni-Al Hydroxide Phases in Soils

    E-Print Network [OSTI]

    Sparks, Donald L.

    surface precipitate phases on kaolinite surfaces as the humic acid content of the system was increased. At 1% humic acid by weight, mixed Ni-Al hydroxide precipitates formed on the kaolinite surface after 4 days. At 5 wt % humic acid, however, precipitate formation was slower and resulted in Ni(OH)2

  8. Bilayer thickness effects on nanoindentation behavior of Ag/Ni multilayers

    E-Print Network [OSTI]

    Hong, Soon Hyung

    by nanoindentation hardness and creep tests. The hardness increased with decreasing bilayer thickness, although of nanoindentation creep tests on Ag/Ni nanomultilayers with various bilayer thicknesses. Multilayered Ag/Ni films thickness. A nanoindentation creep test was used to study the creep behavior of nano- scale multilayers

  9. THREE-DIMENSIONAL ATOMIC STRUCTURE OF NiO ZrO2(CUBIC) INTERFACES

    E-Print Network [OSTI]

    Pennycook, Steve

    THREE-DIMENSIONAL ATOMIC STRUCTURE OF NiO± ZrO2(CUBIC) INTERFACES E. C. DICKEY{1 , V. P. DRAVID1-dimensional atomic structure of low-energy NiO±ZrO2(cubic) interfaces is determined through a combination of electron the structural and chemical aspects of the interface and associ- ated interfacial relaxation mechaubic) interface

  10. Ferromagnetic interactions and martensitic transformation in Fe doped Ni-Mn-In shape memory alloys

    SciTech Connect (OSTI)

    Lobo, D. N.; Priolkar, K. R.; Emura, S.; Nigam, A. K.

    2014-11-14

    The structure, magnetic, and martensitic properties of Fe doped Ni-Mn-In magnetic shape memory alloys have been studied by differential scanning calorimetry, magnetization, resistivity, X-ray diffraction (XRD), and EXAFS. While Ni{sub 2}MnIn{sub 1?x}Fe{sub x} (0???x???0.6) alloys are ferromagnetic and non martensitic, the martensitic transformation temperature in Ni{sub 2}Mn{sub 1.5}In{sub 1?y}Fe{sub y} and Ni{sub 2}Mn{sub 1.6}In{sub 1?y}Fe{sub y} increases for lower Fe concentrations (y???0.05) before decreasing sharply for higher Fe concentrations. XRD analysis reveals presence of cubic and tetragonal structural phases in Ni{sub 2}MnIn{sub 1?x}Fe{sub x} at room temperature with tetragonal phase content increasing with Fe doping. Even though the local structure around Mn and Ni in these Fe doped alloys is similar to martensitic Mn rich Ni-Mn-In alloys, presence of ferromagnetic interactions and structural disorder induced by Fe affect Mn-Ni-Mn antiferromagnetic interactions resulting in suppression of martensitic transformation in these Fe doped alloys.

  11. The Influence of Ni-Coated TiC on Laser-Deposited IN625 Metal Matrix Composites

    E-Print Network [OSTI]

    2010-01-01

    The In?uence of Ni-Coated TiC on Laser-Deposited IN625 Metalwith Ni-coated and uncoated TiC reinforcement particles toand spatial distribution of TiC particles in the deposited

  12. Frying Doughnuts: What can the reprocessing of X-rays to IR tell us about the AGN environment?

    E-Print Network [OSTI]

    B. McKernan; K. E. S. Ford; N. Chang; C. S. Reynolds

    2008-12-04

    Active galactic nuclei (AGN) produce vast amounts of high energy radiation deep in their central engines. X-rays either escape the AGN or are absorbed and re-emitted mostly as IR. By studying the dispersion in the ratio of observed mid-IR luminosity to observed 2-10keV X-ray luminosity (R_{ir/x}) in AGN we can investigate the reprocessing material (possibly a torus or donut of dust) in the AGN central engine, independent of model assumptions. We studied the ratio of observed mid-IR and 2-10keV X-ray luminosities in a heterogeneous sample of 245 AGN from the literature. We found that when we removed AGN with prominent jets, ~90% of Type I AGN lay within a very tight dispersion in luminosity ratio (1ir/x}<30). This implies that the AGN central engine is extremely uniform and models of the physical AGN environment (e.g. cloud cover, turbulent disk, opening angle of absorbing structures such as dusty tori) must span a very narrow range of parameters. We also found that the far-IR(100um) to mid-IR (12um) observed luminosity ratio is an effective descriminator between heavily obscured AGN and relatively unobscured AGN.

  13. Direct synthesis of porous NiO nanowall arrays on conductive substrates for supercapacitor application

    SciTech Connect (OSTI)

    Zhu, Jianhui; Jiang, Jian; Liu, Jingping; Ding, Ruimin; Ding, Hao; Feng, Yamin; Wei, Guangming; Huang, Xintang

    2011-03-15

    Porous NiO nanowall arrays (NWAs) grown on flexible Fe-Co-Ni alloy have been successfully synthesized by using nullaginite (Ni{sub 2}(OH){sub 2}CO{sub 3}) as precursor and investigated as supercapacitor electrodes. In details, we adopted a simple hydrothermal method to realize Ni{sub 2}(OH){sub 2}CO{sub 3} NWAs and examined their robust mechanical adhesion to substrate via a long-time ultrasonication test. Porous NiO NWAs were then obtained by a post-calcination towards precursors at 500 {sup o}C in nitrogen atmosphere. Electrochemical properties of as-synthesized NiO NWAs were evaluated by cyclic voltammetry and galvanostatic charge/discharge; porous NiO NWAs electrode delivered a specific capacitance of 270 F/g (0.67 A/g); even at high current densities, the electrode could still deliver a high capacitance up to 236 F/g (13.35 A/g). Meanwhile, it exhibited excellent cycle lifetime with {approx}93% specific capacitance kept after 4000 cycles. These results suggest that as-made porous NiO NWAs electrode is a promising candidate for future thin-film supercapacitors and other microelectronic systems. -- Graphical abstract: Porous NiO nanowall arrays (NWAs) grown on alloy substrate have been made using nullaginite as precursor and studied as supercapacitor electrodes. Porous nanowalls interconnected with each other resulting in the formation of extended-network architectures and exhibited excellent capacitor properties. NiO NWAs electrode delivered a capacitance of 270 F/g (0.67 A/g); even at high current density, the electrode could still deliver a high capacitance up to 236 F/g (13.35 A/g). Besides, it exhibited excellent cycle lifetime with {approx}93% capacitance kept after 4000 cycles. These remarkable results made it possible for mass production of NiO NWAs and future thin-film microelectronic applications. Display Omitted Research highlights: {yields} Large-scale nullaginite (Ni{sub 2}(OH){sub 2}CO{sub 3}) nanowall arrays (NWAs) have been synthesized on flexible alloy substrate by a facile hydrothermal method. {yields} Ultrasonication test has been conducted to demonstrate the robust mechanical adhesion between NWAs and substrate. {yields} As supercapacitor electrodes porous NiO NWAs obtained by a post-calcination towards Ni{sub 2}(OH){sub 2}CO{sub 3} precursors have exhibited excellent electrochemical properties.

  14. Understanding and engineering of NiGe/Ge junction formed by phosphorus ion implantation after germanidation

    SciTech Connect (OSTI)

    Oka, Hiroshi, E-mail: oka@asf.mls.eng.osaka-u.ac.jp; Minoura, Yuya; Hosoi, Takuji; Shimura, Takayoshi; Watanabe, Heiji [Department of Material and Life Science, Graduate School of Engineering, Osaka University, 2-1 Yamadaoka, Suita, Osaka 565-0871 (Japan)

    2014-08-11

    Modulation of the effective electron Schottky barrier height (eSBH) of NiGe/Ge contacts induced by phosphorus ion implantation after germanide formation was investigated by considering local inhomogeneity in the eSBH. Systematic studies of NiGe/Ge contact devices having various germanide thicknesses and ion implantation areas indicated the threshold dopant concentration at the NiGe/Ge interface required for eSBH modulation and negligible dopant diffusion even at NiGe/Ge interface during drive-in annealing, leading to variation in the eSBH between the bottom and sidewall portions of the NiGe regions. Consequently, this method makes it possible to design source/drain contacts with low-resistivity Ohmic and ideal rectifying characteristics for future Ge-based transistors.

  15. Thermal plasma synthesis of Fe{sub 1?x}Ni{sub x} alloy nanoparticles

    SciTech Connect (OSTI)

    Raut, Suyog A.; Kanhe, Nilesh S.; Bhoraskar, S. V.; Mathe, V. L.; Das, A. K.

    2014-04-24

    Fe-Ni alloy nanoparticles are of great interest because of diverse practical applications in the fields such as magnetic fluids, high density recording media, catalysis and medicine. We report the synthesis of Fe-Ni nanoparticles via thermal plasma route. Thermal plasma assisted synthesis is a high temperature process and gives high yields of production. Here, we have used direct arc thermal plasma plume of 6kw as a source of energy at operating pressure 500 Torr. The mixture of Fe-Ni powder in required proportion (Fe{sub 1?x}Ni{sub x}; x=0.30, 0.32, 0.34, 0.36, 0.38 and 0.40) was made to evaporate simultaneously from the graphite anode in thermal plasma reactor to form Fe-Ni bimetallic nanoparticles. The as synthesized particles were characterized by X-Ray Diffraction (XRD), Thermo-Gravimetric Analysis/Differential Scanning Calorimtry (TGA/DSC)

  16. Electrochemical sensing behaviour of Ni doped Fe{sub 3}O{sub 4} nanoparticles

    SciTech Connect (OSTI)

    Suresh, R.; Giribabu, K.; Manigandan, R.; Narayanan, V., E-mail: vnnara@yahoo.co.in [Department of Inorganic Chemistry, University of Madras, Guindy Campus, Chennai 600 025 (India); Vijayalakshmi, L. [Annai Veilankanni's College for Women (Arts and Science), Saidapet, Chennai 600015 (India); Stephen, A. [Department of Nuclear Physics, University of Madras, Guindy Campus, Chennai 600 025 (India)

    2014-01-28

    Ni doped Fe{sub 3}O{sub 4} nanoparticles were synthesized by simple hydrothermal method. The prepared nanomaterials were characterized by X-ray diffraction analysis, DRS-UV-Visible spectroscopy and field emission scanning electron microscopy. The XRD confirms the phase purity of the synthesized Ni doped Fe{sub 3}O{sub 4} nanoparticles. The optical property of Ni doped Fe{sub 3}O{sub 4} nanoparticles were studied by DRS UV-Visible analysis. The electrochemical sensing property of pure and Ni doped Fe{sub 3}O{sub 4} nanoparticles were examined using uric acid as an analyte. The obtained results indicated that the Ni doped Fe{sub 3}O{sub 4} nanoparticles exhibited higher electrocatalytic activity towards uric acid.

  17. Eutectic bonding of a Ti sputter coated, carbon aerogel wafer to a Ni foil

    SciTech Connect (OSTI)

    Jankowski, A.F.; Hayes, J.P.; Kanna, R.L.

    1994-06-01

    The formation of high energy density, storage devices is achievable using composite material systems. Alternate layering of carbon aerogel wafers and Ni foils with rnicroporous separators is a prospective composite for capacitor applications. An inherent problem exists to form a physical bond between Ni and the porous carbon wafer. The bonding process must be limited to temperatures less than 1000{degrees}C, at which point the aerogel begins to degrade. The advantage of a low temperature eutectic in the Ni-Ti alloy system solves this problem. Ti, a carbide former, is readily adherent as a sputter deposited thin film onto the carbon wafer. A vacuum bonding process is then used to join the Ni foil and Ti coating through eutectic phase formation. The parameters required for successfld bonding are described along with a structural characterization of the Ni foil-carbon aerogel wafer interface.

  18. Fabrication of NiO thin film electrode for supercapacitor applications

    SciTech Connect (OSTI)

    Mali, V. V.; Navale, S. T.; Chougule, M. A.; Khuspe, G. D.; Godse, P. R.; Patil, V. B., E-mail: drvbpatil@gmail.com [Functional Materials Research Laboratory, School of Physical Sciences, Solapur University, Solapur-413255 (India); Pawar, S. A. [Department of Electronics, Shri Shivaji Mahavidhyala, Barshi, Solapur-413411 (India)

    2014-04-24

    Nanocrystalline NiO electrode is successfully electrosynthesized for supercapacitor application. The nanocrystalline NiO electrode is characterized using scanning electron microscope (SEM). Nickel oxide is a highly porous and the film surface looked smooth and composed of fine elongated particles. The supercapacitive performance of NiO electrode is tested using cyclic voltammetry (C-V) technique in 0.5M Na{sub 2}S{sub 2}O{sub 3} electrolyte within potential range of ?1.2 to +1.2 V. The effect of scan rate on the capacitance of NiO electrode is studied. The highest specific capacitance of 439 Fg{sup ?1} at the voltage scan rate of 50mVs{sup ?1} is achieved. Additionally stability and charging–discharging of NiO electrode are studied.

  19. Spitzer-IRS Sectroscopy of the Prototype Wolf-Rayet star EZ CMa (HD 50896)

    E-Print Network [OSTI]

    P W Morris; P A Crowther; J R Houck

    2004-06-03

    We present mid-infrared Spitzer-IRS spectroscopy of the prototype WN star EZ CMa (HD50896, WN4b). Numerous stellar wind lines of HeII are revealed, plus fine-structure lines of [NeIII] 15.5um and [OIV] 25.9um. We carry out a spectroscopic analysis of HD50896 allowing for line blanketing and clumping, which is compared to the mid-IR observations. We make use of these stellar properties to accurately derive Ne/He=1.2-1.8E-4 and O/He=4.2-4.8E-5 by number, for the first time in an early WN star. In addition, we obtain N/C=40 and N/O=50 by number, values in perfect agreement with current predictions for rotating massive stars at the end of interior hydrogen burning.

  20. Probing the Invisible Universe: The Case for Far-IR/Submillimeter Interferometry

    E-Print Network [OSTI]

    D. Leisawitz; T. Armstrong; D. Benford; A. Blain; K. Borne W. Danchi; N. Evans; J. Gardner; D. Gezari; M. Harwit; A. Kashlinsky; W. Langer; C. Lawrence; P. Lawson; D. Lester; J. Mather; S. H. Moseley; L. Mundy; G. Rieke; S. Rinehart; M. Shao; R. Silverberg; D. Spergel; J. Staguhn; M. Swain; W. Traub; S. Unwin; E. Wright; H. Yorke

    2002-02-04

    The question "How did we get here and what will the future bring?" captures the human imagination and the attention of the National Academy of Science's Astronomy and Astrophysics Survey Commitee (AASC). Fulfillment of this "fundamental goal" requires astronomers to have sensitive, high angular and spectral resolution observations in the far-infrared/submillimeter (far-IR/sub-mm) spectral region. With half the luminosity of the universe and vital information about galaxy, star and planet formation, observations in this spectral region require capabilities similar to those currently available or planned at shorter wavelengths. In this paper we summarize the scientific motivation, some mission concepts and technology requirements for far-IR/sub-mm space interferometers that can be developed in the 2010-2020 timeframe.

  1. Curing the UV/IR mixing for field theories with translation-invariant star products

    SciTech Connect (OSTI)

    Tanasa, Adrian; Vitale, Patrizia

    2010-03-15

    The ultraviolet/infrared (UV/IR) mixing of noncommutative field theories has been recently shown to be a generic feature of translation-invariant associative products. In this paper we propose to take into account the quantum corrections of the model to modify in this way the noncommutative action. This idea was already used to cure the UV/IR mixing for theories on Moyal space. We show that in the present framework also, this proposal proves successful for curing the mixing. We achieve this task by explicit calculations of one and higher loops Feynman amplitudes. For the sake of completeness, we compute the form of the new action in the matrix base for the Wick-Voros product.

  2. Monodisperse core/shell Ni/FePt nanoparticles and their con-version to Ni/Pt to catalyze oxygen reduction

    SciTech Connect (OSTI)

    Zhang, Sen; Su, Dong; Doan-Nguyen, Vicky V. T.; Wu, Yaoting; Li, Jing; Sun, Shouheng; Murray, Christopher B.; Hao, Yizhou

    2014-11-12

    We report a size-controllable synthesis of monodisperse core/shell Ni/FePt nanoparticles (NPs) via a seed-mediated growth and their subsequent conversion to Ni/Pt NPs. Preventing surface oxidation of the Ni seeds is essential for the growth of uniform FePt shells. These Ni/FePt NPs have a thin (? 1 nm) FePt shell, and can be converted to Ni/Pt by acetic acid wash to yield active catalysts for oxygen reduction reaction (ORR). Tuning the core size allow for optimization of their electrocatalytic activity. The specific activity and mass activity of 4.2 nm/0.8 nm core/shell Ni/FePt reach 1.95 mA/cm˛ and 490 mA/mgPt at 0.9 V (vs. reversible hydrogen electrode, RHE), which are much higher than those of benchmark commercial Pt catalyst (0.34 mA/cm˛ and 92 mA/mgPt at 0.9 V). Our studies provide a robust approach to monodisperse core/shell NPs with non-precious metal core, making it possible to develop advanced NP catalysts with ultralow Pt content for ORR and many other heterogeneous reactions.

  3. An APFIM and TEM study of Ni{sub 4}Mo precipitation in a commercial Ni-28% Mo-1.4% Fe-0.4% Cr wt. % alloy

    SciTech Connect (OSTI)

    Thomson, R.C.; Brown, N.; Bates, J.S. [Loughborough Univ. (United Kingdom). Inst. of Polymer Technology and Materials Engineering; Russell, K.F.; Miller, M.K. [Oak Ridge National Lab., TN (United States). Metals and Ceramics Div.

    1998-02-01

    Ni-Mo alloys containing at least 26 wt.% Mo have a negligible corrosion rate in boiling 10% hydrochloric acid and are therefore used in corrosive environments. A series of commercial Ni-Mo alloys has been developed with subtle variations in chemical composition. These alloys usually contain {approximately} 28 wt.% Mo with additions of up to 5% Fe and Cr. A significant amount of research has been performed to understand the microstructure and properties of these alloys, although most of the effort has concentrated on the Ni-Mo binary system. In some alloys with low Fe and Cr contents, a severe embrittlement problem has been observed due to the formation of the Ni{sub 4}Mo (D1{sub a}-ordered) phase within the microstructure. This research focuses on a commercial alloy with nominal composition Ni-28% Mo-1.4% Fe-0.4% Cr-0.1% Mn-0.003 wt.% C. The material supplied was a heat treatment coupon which had been attached to a large vessel during fabrication. Assessment of the chemical analysis of the alloy suggested that detrimental phases could be present or might appear during subsequent repair work. Therefore, it was important to assess the microstructural condition of the vessel, and in particular the kinetics of precipitation of Ni{sub 4}Mo.

  4. Correlating Extent of Pt–Ni Bond Formation with Low-temperature Hydrogenation of Benzene and 1,3-butadiene over Supported Pt/Ni Bimetallic Catalysts

    SciTech Connect (OSTI)

    Lonergan, W.; Vlachos, D; Chen, J

    2010-01-01

    Low-temperature hydrogenation of benzene and 1,3-butadiene on supported Pt/Ni catalysts have been used as probe reactions to correlate hydrogenation activity with the extent of Pt-Ni bimetallic bond formation. Pt/Ni bimetallic and Pt and Ni monometallic catalysts were supported on {gamma}-Al{sub 2}O{sub 3} using incipient wetness impregnation. Two sets of bimetallic catalysts were synthesized: one set to study the effect of metal atomic ratio and the other to study the effect of impregnation sequence. Fourier transform infrared spectroscopy (FTIR) CO adsorption studies were performed to characterize the surface composition of the bimetallic nanoparticles, and transmission electron microscopy (TEM) was utilized to characterize the particle size distribution. Batch reactor studies with FTIR demonstrated that all bimetallic catalysts outperformed monometallic catalysts for both benzene and 1,3-butadiene hydrogenation. Within the two sets of bimetallic catalysts, it was found that catalysts with a smaller Pt:Ni ratio possessed higher hydrogenation activity and that catalysts synthesized using co-impregnation had greater activity than sequentially impregnated catalysts. Extended X-ray absorption fine structure (EXAFS) measurements were performed in order to verify the extent of Pt-Ni bimetallic bond formation, which was found to correlate with the hydrogenation activity.

  5. Monodisperse core/shell Ni/FePt nanoparticles and their con-version to Ni/Pt to catalyze oxygen reduction

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhang, Sen [Univ. of Pennsylvania, Philadelphia, PA (United States); Su, Dong [Brookhaven National Lab. (BNL), Upton, NY (United States); Doan-Nguyen, Vicky V. T. [Univ. of Pennsylvania, Philadelphia, PA (United States); Wu, Yaoting [Univ. of Pennsylvania, Philadelphia, PA (United States); Li, Jing [Brookhaven National Lab. (BNL), Upton, NY (United States); Sun, Shouheng [Brown Univ., Providence, RI (United States); Murray, Christopher B. [Univ. of Pennsylvania, Philadelphia, PA (United States); Hao, Yizhou [Univ. of Pennsylvania, Philadelphia, PA (United States)

    2014-11-12

    We report a size-controllable synthesis of monodisperse core/shell Ni/FePt nanoparticles (NPs) via a seed-mediated growth and their subsequent conversion to Ni/Pt NPs. Preventing surface oxidation of the Ni seeds is essential for the growth of uniform FePt shells. These Ni/FePt NPs have a thin (? 1 nm) FePt shell, and can be converted to Ni/Pt by acetic acid wash to yield active catalysts for oxygen reduction reaction (ORR). Tuning the core size allow for optimization of their electrocatalytic activity. The specific activity and mass activity of 4.2 nm/0.8 nm core/shell Ni/FePt reach 1.95 mA/cm˛ and 490 mA/mgPt at 0.9 V (vs. reversible hydrogen electrode, RHE), which are much higher than those of benchmark commercial Pt catalyst (0.34 mA/cm˛ and 92 mA/mgPt at 0.9 V). Our studies provide a robust approach to monodisperse core/shell NPs with non-precious metal core, making it possible to develop advanced NP catalysts with ultralow Pt content for ORR and many other heterogeneous reactions.

  6. Monodisperse core/shell Ni/FePt nanoparticles and their con-version to Ni/Pt to catalyze oxygen reduction

    SciTech Connect (OSTI)

    Zhang, Sen; Hao, Yizhou; Su, Dong; Doan-Nguyen, Vicky V. T.; Wu, Yaoting; Li, Jing; Sun, Shouheng; Murray, Christopher B.

    2014-10-28

    We report a size-controllable synthesis of monodisperse core/shell Ni/FePt nanoparticles (NPs) via a seed-mediated growth and their subsequent conversion to Ni/Pt NPs. Preventing surface oxidation of the Ni seeds is essential for the growth of uniform FePt shells. These Ni/FePt NPs have a thin (? 1 nm) FePt shell, and can be converted to Ni/Pt by acetic acid wash to yield active catalysts for oxygen reduction reaction (ORR). Tuning the core size allow for optimization of their electrocatalytic activity. The specific activity and mass activity of 4.2 nm/0.8 nm core/shell Ni/FePt reach 1.95 mA/cm˛ and 490 mA/mgPt at 0.9 V (vs. reversible hydrogen electrode, RHE), which are much higher than those of benchmark commercial Pt catalyst (0.34 mA/cm˛ and 92 mA/mgPt at 0.9 V). Our studies provide a robust approach to monodisperse core/shell NPs with non-precious metal core, making it possible to develop advanced NP catalysts with ultralow Pt content for ORR and many other heterogeneous reactions.

  7. Monodisperse core/shell Ni/FePt nanoparticles and their con-version to Ni/Pt to catalyze oxygen reduction

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zhang, Sen; Hao, Yizhou; Su, Dong; Doan-Nguyen, Vicky V. T.; Wu, Yaoting; Li, Jing; Sun, Shouheng; Murray, Christopher B.

    2014-10-28

    We report a size-controllable synthesis of monodisperse core/shell Ni/FePt nanoparticles (NPs) via a seed-mediated growth and their subsequent conversion to Ni/Pt NPs. Preventing surface oxidation of the Ni seeds is essential for the growth of uniform FePt shells. These Ni/FePt NPs have a thin (? 1 nm) FePt shell, and can be converted to Ni/Pt by acetic acid wash to yield active catalysts for oxygen reduction reaction (ORR). Tuning the core size allow for optimization of their electrocatalytic activity. The specific activity and mass activity of 4.2 nm/0.8 nm core/shell Ni/FePt reach 1.95 mA/cm˛ and 490 mA/mgPt at 0.9 Vmore »(vs. reversible hydrogen electrode, RHE), which are much higher than those of benchmark commercial Pt catalyst (0.34 mA/cm˛ and 92 mA/mgPt at 0.9 V). Our studies provide a robust approach to monodisperse core/shell NPs with non-precious metal core, making it possible to develop advanced NP catalysts with ultralow Pt content for ORR and many other heterogeneous reactions.« less

  8. Hybrid Composite Ni(OH)(2)@NiCo2O4 Grown on Carbon Fiber Paper for High-Performance Supercapacitors

    SciTech Connect (OSTI)

    Huang, L; Chen, DC; Ding, Y; Wang, ZL; Zeng, ZZ; Liu, ML

    2013-11-13

    We have successfully fabricated and tested the electrochemical performance of supercapacitor electrodes consisting of Ni(OH)(2) nanosheets coated on NiCo2O4 nanosheets grown on carbon fiber paper (CFP) current collectors. When the NiCo2O4 nanosheets are replaced by Co3O4 nanosheets, however, the energy and power density as well as the rate capability of the electrodes are significantly reduced, most likely due to the lower conductivity of Co3O4 than that of NiCo2O4. The 3D hybrid composite Ni(OH)(2)/ NiCo2O4/CFP electrodes demonstrate a high areal capacitance of 5.2 F/cm(2) at a cycling current density of 2 rnA/cm(2), with a capacitance retention of 79% as the cycling current density was increased from 2 to 50 mA/cm(2). The remarkable performance of these hybrid composite electrodes implies that supercapacitors based on them have potential for many practical applications.

  9. Resonant two-photon ionization spectroscopy of NiC Dale J. Brugh and Michael D. Morse

    E-Print Network [OSTI]

    Morse, Michael D.

    Resonant two-photon ionization spectroscopy of NiC Dale J. Brugh and Michael D. Morse University investigation of jet-cooled diatomic NiC has revealed a complex pattern of vibronic levels in the wave number as far to the blue as 26 951 cm 1 indicates that D0 NiC 3.34 eV, and the ionization energy of NiC has

  10. Structurally Integrated Coatings for Wear and Corrosion (SICWC): Arc Lamp, InfraRed (IR) Thermal Processing

    SciTech Connect (OSTI)

    Mackiewicz-Ludtka, G.; Sebright, J.

    2007-12-15

    The primary goal of this Cooperative Research and Development Agreement (CRADA) betwe1311 UT-Battelle (Contractor) and Caterpillar Inc. (Participant) was to develop the plasma arc lamp (PAL), infrared (IR) thermal processing technology 1.) to enhance surface coating performance by improving the interfacial bond strength between selected coatings and substrates; and 2.) to extend this technology base for transitioning of the arc lamp processing to the industrial Participant. Completion of the following three key technical tasks (described below) was necessary in order to accomplish this goal. First, thermophysical property data sets were successfully determined for composite coatings applied to 1010 steel substrates, with a more limited data set successfully measured for free-standing coatings. These data are necessary for the computer modeling simulations and parametric studies to; A.) simulate PAL IR processing, facilitating the development of the initial processing parameters; and B.) help develop a better understanding of the basic PAL IR fusing process fundamentals, including predicting the influence of melt pool stirring and heat tnmsfar characteristics introduced during plasma arc lamp infrared (IR) processing; Second, a methodology and a set of procedures were successfully developed and the plasma arc lamp (PAL) power profiles were successfully mapped as a function of PAL power level for the ORNL PAL. The latter data also are necessary input for the computer model to accurately simulate PAL processing during process modeling simulations, and to facilitate a better understand of the fusing process fundamentals. Third, several computer modeling codes have been evaluated as to their capabilities and accuracy in being able to capture and simulate convective mixing that may occur during PAL thermal processing. The results from these evaluation efforts are summarized in this report. The intention of this project was to extend the technology base and provide for transitioning of the arc lamp processing to the industrial Participant.

  11. Practical Analysis of materials with depth varying compositions using FT-IR photoacoustic spectroscopy (PAS)

    SciTech Connect (OSTI)

    J.F. McClelland; R.W. Jones; Siquan Luo

    2004-09-30

    FT-IR photoacoustic spectroscopy (PAS) is discussed as a nondestructive method to probe the molecular composition of materials versus depth on the basis of the analysis of layers of experimentally controllable thickness, which are measured from the sample surface to depths of some tens of micrometers, depending on optical and thermal properties. Computational methods are described to process photoacoustic amplitude and phase spectra for both semi-quantitative and quantitative depth analyses. These methods are demonstrated on layered and gradient samples.

  12. Axion decay and anisotropy of near-IR extragalactic background light

    E-Print Network [OSTI]

    Yan Gong; Asantha Cooray; Ketron Mitchell-Wynne; Xuelei Chen; Michael Zemcov; Joseph Smidt

    2015-11-05

    The extragalactic background light is expected to be comprised of the cumulative radiation from all galaxies and active galactic nuclei over the cosmic history. In addition to point sources, EBL also contains information from diffuse sources of radiation. An example is the intra-halo light, associated with diffuse stars in dark matter halos resulting from galaxy mergers and tidal interactions, identified based on measurements involving the angular power spectrum of infrared background anisotropies. The angular power spectra of the near-infrared intensities could still contain additional signals and a complete understanding of the nature of the IR background is still lacking in the literature. Here we explore the constraints that can be placed on the decay products associated with particle decays, especially candidate dark matter models involving axions that trace dark matter halos of galaxies. Axions with a mass around a few eV will decay via two photons with wavelengths in the near-IR band, and will leave a signature in the IR background intensity power spectrum. Using recent power spectra measurements from the Hubble Space Telescope (HST) and Cosmic Infrared Background Experiment (CIBER), we find that the 0.6 to 1.6 micron power spectra can be explained with an axion mass of around 4 eV and a total axion abundance as a fractional energy density Omega_a~0.05. Such an abundance is comparable to the baryon density of the Universe. The absolute EBL intensity of axion decay photons is slightly below 1 nW m^-2 sr^-1 at near-IR wavelengths, roughly a factor of 10 to 20 below the total integrated light from galaxies. The suggested axion mass and abundance are not ruled out by existing cosmological observations.

  13. Influence of Mn and Ni on the microstructure and toughness of C-Mn-Ni weld metals

    SciTech Connect (OSTI)

    Zhang, Z.; Farrar, R.A. [Univ. of Southampton (United Kingdom). Dept. of Mechanical Engineering

    1997-05-01

    A systematic investigation has been carried out to study the microstructure and toughness of C-Mn-Ni low-alloy shielded metal arc (SMA) weld metals. The manganese and nickel concentrations were progressively changed to determine their influence on weld microstructure and mechanical properties as well as to identify their interactions. The results obtained showed that manganese and nickel have considerable effect on the weld metal microstructure, and both Mn and Ni affect the microstructure in a similar way, i.e., promoting acicular ferrite at the expense of proeutectoid ferrite (grain boundary ferrite and ferrite sideplates). The results in the top bead also showed that there is an optimum composition range that produces an optimum balance of weld metal microstructures. For optimum toughness, a combination of 0.6--1.4% manganese and 1.0--3.7% nickel is suggested. Additions beyond this limit promotes the formation of martensite and other microstructural features, which may be detrimental to weld metal toughness.

  14. Light-Like Noncommutativity, Light-Front Quantization and New Light on UV/IR Mixing

    E-Print Network [OSTI]

    M. M. Sheikh-Jabbari; A. Tureanu

    2010-10-02

    We revisit the problem of quantizing field theories on noncommutative Moyal spacetime with \\emph{light-like} noncommutativity. To tackle the issues arising from noncommuting and hence nonlocal time, we argue that for this case light-front quantization procedure should be employed. In this appropriate quantization scheme we perform the non-planar loop analysis for the light-like noncommutative field theories. One of the important and peculiar features of light-front quantization is that the UV cutoff of the light-cone Hamiltonian manifests itself as an IR cutoff for the light-cone momentum, $p^+$. Due to this feature, the naive results of covariant quantization for the light-like case allude to the absence of the UV/IR mixing in the light-front quantization. However, by a careful analysis of non-planar loop integrals we show that this is not the case and the UV/IR mixing persists. In addition, we argue in favour of the perturbative unitarity of light-like noncommutative field theories in the light-front quantization scheme.

  15. NGC 7538 IRS. 1. Interaction of a polarized dust spiral and a molecular outflow

    SciTech Connect (OSTI)

    Wright, M. C. H.; Hull, Charles L. H. [Department of Astronomy, University of California, Berkeley, CA 94720 (United States); Pillai, Thushara [Max Planck Institut für Radioastronomie, Auf dem Hügel 69, D-53121 Bonn (Germany); Zhao, Jun-Hui [Harvard-Smithsonian Center for Astrophysics, 60 Garden Street, Cambridge, MA 02138 (United States); Sandell, Göran, E-mail: jzhao@cfa.harvard.edu [SOFIA-USRA, NASA Ames Research Center, MS 232-12, Building N232, Room 146, PO Box 1, Moffett Field, CA 94035-0001 (United States)

    2014-12-01

    We present dust polarization and CO molecular line images of NGC 7538 IRS 1. We combined data from the Submillimeter Array, the Combined Array for Research in Millimeter-wave Astronomy, and the James Clerk Maxwell Telescope to make images with ?2.''5 resolution at 230 and 345 GHz. The images show a remarkable spiral pattern in both the dust polarization and molecular outflow. These data dramatically illustrate the interplay between a high infall rate onto IRS 1 and a powerful outflow disrupting the dense, clumpy medium surrounding the star. The images of the dust polarization and the CO outflow presented here provide observational evidence for the exchange of energy and angular momentum between the infall and the outflow. The spiral dust pattern, which rotates through over 180° from IRS 1, may be a clumpy filament wound up by conservation of angular momentum in the infalling material. The redshifted CO emission ridge traces the dust spiral closely through the MM dust cores, several of which may contain protostars. We propose that the CO maps the boundary layer where the outflow is ablating gas from the dense gas in the spiral.

  16. Emergent IR dual 2d CFTs in charged AdS5 black holes

    E-Print Network [OSTI]

    Jan de Boer; Maria Johnstone; M. M. Sheikh-Jabbari; Joan Simon

    2011-12-20

    We study the possible dynamical emergence of IR conformal invariance describing the low energy excitations of near-extremal R-charged global AdS5 black holes. We find interesting behavior especially when we tune parameters in such a way that the relevant extremal black holes have classically vanishing horizon area, i.e. no classical ground-state entropy, and when we combine the low energy limit with a large N limit of the dual gauge theory. We consider both near-BPS and non-BPS regimes and their near horizon limits, emphasize the differences between the local AdS3 throats emerging in either case, and discuss potential dual IR 2d CFTs for each case. We compare our results with the predictions obtained from the Kerr/CFT correspondence, and obtain a natural quantization for the central charge of the near-BPS emergent IR CFT which we interpret in terms of the open strings stretched between giant gravitons.

  17. The interfacial reaction of Ni on (100) Si?â??xGex (x=0, 0.25) and (111) Ge

    E-Print Network [OSTI]

    Jin, Lijuan

    The interfacial reaction of Ni with Si, Si?.??Ge?.??, and Ge at 400°C has been investigated. A uniform epitaxial NiSi film was obtained at 400°C for Ni-Silicidation on Si using rapid thermal annealing method. Similarly, ...

  18. Development of ZnNiCd coatings by pulse electrodeposition process Prabhu Ganesan, Swaminatha P. Kumaraguru, Branko N. Popov

    E-Print Network [OSTI]

    Popov, Branko N.

    Development of Zn­Ni­Cd coatings by pulse electrodeposition process Prabhu Ganesan, Swaminatha P indicated that Zn­Ni­Cd alloys exhibit superior barrier properties when compared to Cd or Zn­Ni coatings of corrosion resistant coating in aerospace, electrical, and fastener industries due to its excel- lent

  19. The corrosion behavior and hemocompatibility of TiNi alloys coated with DLC by plasma based ion implantation

    E-Print Network [OSTI]

    Zheng, Yufeng

    The corrosion behavior and hemocompatibility of TiNi alloys coated with DLC by plasma based ion successfully deposited on Ti­50.8 at.% Ni alloys using plasma based ion implantation (PBII) technique on the surface modification of TiNi alloys, including ion implan- tation, multi arc ion-plating as well as Ti

  20. Ni(III)/(IV) Bis(dicarbollide) as a Fast, Noncorrosive Redox Shuttle for Dye-Sensitized Solar Cells

    E-Print Network [OSTI]

    multiple redox transformations involving net charges of -2, -1, and 0, with Ni(II), Ni(III) (3), and Ni at the electrolyte interface. Previous DSC Fc/Fc+ couple work showed that dark currents can be suppressed by TiO2/Fc+ vs SCE (translating to a smaller potential difference between the dark electrode and quasi

  1. Chemically anchored NiOxcarbon composite fibers for Li-ion batteries with long cycle-life and

    E-Print Network [OSTI]

    Cao, Guozhong

    the research hot-pot of NiO based anodes for LIBs. Amorphous carbon, carbon nanotubes, graphene, and carbon enhanced properties.16,17 Carbon nanotubes were also used to prepare NiO­carbon composites via a surfaceO­gra- phene commonly began with nickel salts and graphene oxide, and the resultant NiO­graphene composites

  2. A numerical method for predicting the bending fatigue life of NiTi and stainless steel root canal

    E-Print Network [OSTI]

    Zheng, Yufeng

    A numerical method for predicting the bending fatigue life of NiTi and stainless steel root canal. A numerical method for predicting the bending fatigue life of NiTi and stainless steel root canal instruments­titanium alloy (NiTi) and stainless steel (SS) endodontic files using finite element analysis. Methodology

  3. High Temperature Oxidation Behavior of gamma-Ni+gamma'-Ni3Al Alloys and Coatings Modified with Pt and Reactive Elements

    SciTech Connect (OSTI)

    Nan Mu

    2007-12-01

    Materials for high-pressure turbine blades must be able to operate in the high-temperature gases (above 1000 C) emerging from the combustion chamber. Accordingly, the development of nickel-based superalloys has been constantly motivated by the need to have improved engine efficiency, reliability and service lifetime under the harsh conditions imposed by the turbine environment. However, the melting point of nickel (1455 C) provides a natural ceiling for the temperature capability of nickel-based superalloys. Thus, surface-engineered turbine components with modified diffusion coatings and overlay coatings are used. Theses coatings are capable of forming a compact and adherent oxide scale, which greatly impedes the further transport of reactants between the high-temperature gases and the underlying metal and thus reducing attack by the atmosphere. Typically, these coatings contain {beta}-NiAl as a principal constituent phase in order to have sufficient aluminum content to form an Al{sub 2}O{sub 3} scale at elevated temperatures. The drawbacks to the currently-used {beta}-based coatings, such as phase instabilities, associated stresses induced by such phase instabilities, and extensive coating/substrate interdiffusion, are major motivations in this study to seek next-generation coatings. The high-temperature oxidation resistance of novel Pt + Hf-modified {gamma}-Ni + {gamma}-Ni{sub 3}Al-based alloys and coatings were investigated in this study. Both early-stage and 4-days isothermal oxidation behavior of single-phase {gamma}-Ni and {gamma}{prime}-Ni{sub 3}Al alloys were assessed by examining the weight changes, oxide-scale structures, and elemental concentration profiles through the scales and subsurface alloy regions. It was found that Pt promotes Al{sub 2}O{sub 3} formation by suppressing the NiO growth on both {gamma}-Ni and {gamma}{prime}Ni{sub 3}Al single-phase alloys. This effect increases with increasing Pt content. Moreover, Pt exhibits this effect even at lower temperatures ({approx}970 C) in the very early stage of oxidation. It was also inferred that Pt enhances the diffusive flux of aluminum from the substrate to the scale/alloy interface. Relatively low levels of hafnium addition to Pt-free {gamma}{prime}-Ni{sub 3}Al increased the extent of external NiO formation due to non-protective HfO{sub 2} formation. Accordingly, this effect intensified with increasing Hf content from 0.2 to 0.5 at.%.

  4. Advertising rates for 4NI, the Directory Portal for Northern IrelandAdd to the Guestbook of 4NI, the Directory Portal for Northern IreBack to 4NI, the Directory Portal for No 24 February 2004 @ 10:33:27 AM

    E-Print Network [OSTI]

    West, Stuart

    Advertising rates for 4NI, the Directory Portal for Northern IrelandAdd to the Guestbook of 4NI, the Directory Portal for Northern IreBack to 4NI, the Directory Portal for No 24 February 2004 @ 10:33:27 AM Directory Portal For Northern Ireland Industry News 20 February 2004 Some mammals can adjust sex

  5. FT-IR Study of CO2 Interaction with Na-rich Montmorillonite

    SciTech Connect (OSTI)

    Krukowski, Elizabeth G [ORNL; Goodman, Angela [National Energy Technology Laboratory (NETL); Rother, Gernot [ORNL; Ilton, Eugene [Pacific Northwest National Laboratory (PNNL); Guthrie, George [National Energy Technology Laboratory (NETL); Bodnar, Robert [Virginia Polytechnic Institute and State University

    2015-01-01

    Carbon capture, utilization and storage (CCUS) in saline reservoirs in sedimentary formations has the potential to reduce the impact of fossil fuel combustion on climate change by reducing CO2 emissions to the atmosphere and storing the CO2 in geologic formations in perpetuity. At pressure and temperature (PT) conditions relevant to CCUS, CO2 is less dense than the pre-existing brine in the formation, and the more buoyant CO2 will migrate to the top of the formation where it will be in contact with cap rock. Interactions between clay-rich shale cap rocks and CO2 are poorly understood at PT conditions appropriate for CCUS in saline formations. In this study, the interaction of CO2 with clay minerals in the cap rock overlying a saline formation has been examined using Na+ exchanged montmorillonite (Mt) (Na+-STx-1) (Na+ Mt) as an analog for clay-rich shale. Attenuated Total Reflectance-Fourier Transform Infrared Spectroscopy (ATR-FTIR) was used to discern mechanistic information for CO2 interaction with hydrated (both one- and two-water layers) and relatively dehydrated (both dehydrated layers and one-water layers) Na+-STx-1 at 35 C and 50 C and CO2 pressure from 0 5.9 MPa. CO2-induced perturbations associated with the water layer and Na+-STx-1 vibrational modes such as AlAlOH and AlMgOH were examined. Data indicate that CO2 is preferentially incorporated into the interlayer space, with relatively dehydrated Na+-STx-1 capable of incorporating more CO2 compared to hydrated Na+-STx-1. Spectroscopic data provide no evidence of formation of carbonate minerals or the interaction of CO2 with sodium cations in the Na+-STx-1 structure.

  6. In situ carbonyl extraction of Ni from gaseous diffusion cells

    SciTech Connect (OSTI)

    Visnapuu, A. [USBM Salt Lake Research Center, Salt Lake City, UT (United States); Hollenberg, G.W. [Battelle Pacific Northwest Lab., Richland, WA (United States); Bundy, R.D. [Battelle Memorial Institute, Oak Ridge, TN (United States)

    1995-12-31

    This paper discusses the use of carbonyl processing technology for recovery of nickel from uranium isotope separation diffusion cells, and potential applications to recover nickel, iron, chromium, cobalt, and other carbonyl forming metals from nuclear waste while reducing the volume of the high level residue for more economic disposal. Nickel powder was carbonylated under static and dynamic conditions using only carbon monoxide to determine if the nickel powder would react rapidly enough to require no promoter. Nickel to Ni(CO){sub 4} conversion was realized in all cases and nickel metal was vapor deposited in the thermal decomposer, but the conversion rates in all cases the reaction were too slow for practical recovery. Addition of hydrogen sulfide gas as a promoter increased the conversion rate more than 500-fold over conversion with no promoter. Test summaries are provided in the paper; results indicate that promoter activated carbonylation is a viable approach for recovery of nickel from uranium isotope diffusion cells.

  7. Properties of Ni-Al under shock loading

    SciTech Connect (OSTI)

    Koskelo, A. C.; McClellan, K. J.; Brooks, J. D.; Paisley, Dennis L.; Swift, D. C.

    2002-01-01

    New models for the dynamic response of materials will be based increasingly on better understanding and representation of processes occurring at the microstructural level. These developments require advances in diagnostics and models which can be applied explicitly to microstructural response. Various phenomena occur at the microstructural level which are generally ignored or averaged out in continuum-level models. One example of such 'irregular hydrodynamics' is the roughness imparted to a shock wave as it propagates through a polycrystalline material. We have developed imaging techniques to study spatial variations in shock propagation through polycrystalline materials. In order to interpret spatially-resolved data from polycrystal samples, we need to compare with simulations which represent the microstructure. Here we describe work undertaken to develop a model of the dynamic response of individual grains. The material chosen was Ni-Al alloy, because it exhibits a relatively large degree of elastic anisotropy, and it is relatively easy to manufacture.

  8. Monopole resonance strengths in Ni-58 and Pb-208 

    E-Print Network [OSTI]

    Youngblood, David H.

    1997-01-01

    . Unfortunately, those data did not ex- tend to the small angles necessary to identify the GMR and to separate it from other multipoles. Both authors speculate of the E0 EWSR @7# are shown in Table I. Folded potentials and form factors were obtained using... and TABLE I. Parameters for folding model calculations. Nucleus c ~fm! a ~fm! ^r2& ~fm2! a02 Ex ~MeV! V ~MeV! W ~MeV! 58Ni 4.08 0.515 13.653 0.0194 17.0 35.5 21.5 208Pb 6.67 0.545 30.798 0.00297 13.7 40.5 26.0 both nuclei, with 160% of the E0...

  9. Thermomechanical behavior of 55Ni45Ti nitinol

    SciTech Connect (OSTI)

    Ford, D.S.; White, S.R. [Univ. of Illinois, Urbana, IL (United States)] [Univ. of Illinois, Urbana, IL (United States)

    1996-06-01

    Extensive and full range mechanical testing of 55Ni45Ti nitinol alloy wire up to failure over a wide range of testing temperatures is reported. Thermomechanical properties are obtained including: initial modulus, secondary modulus, critical martensitic start and finish stresses, plastic flow stress, recovery strain limit, failure stress and plastic modulus. The data is correlated with the Brinson constitutive model modified to account for full range loading. The ratio of austenite to martensite moduli was found to be 5.8 and the secondary modulus (stress-induced martensite) was found to be smaller by a factor of two when compared to the modulus of (stress-free) thermally induced martensite. The influence of the initial temperature treatment of the nitinol was shown to be pronounced within the transformation range. Reasonably accurate correlation is obtained with the modified Brinson constitutive model although there is some discrepancy in critical stress predictions which is partially attributed to experimental scatter.

  10. Undercooled and rapidly quenched Ni-Mo alloys

    SciTech Connect (OSTI)

    Tewari, S.N.; Glasgow, T.K.

    1986-01-01

    Hypoeutectic, eutectic, and hypereutectic nickel-molybdenum alloys were rapidly solidified by both bulk undercooling and melt spinning techniques. Alloys were undercooled in both electromagnetic levitation and differential thermal analysis equipment. The rate of recalescence depended upon the degree of initial undercooling and the nature (faceted or nonfaceted) of the primary nucleating phase. Alloy melts were observed to undercool more in the presence of primary Beta (NiMo intermetallic) phase than in gamma (fcc solid solution) phase. Melt spinning resulted in an extension of molybdenum solid solubility in gamma nickel, from 28 to 37.5 at % Mo. Although the microstructures observed by undercooling and melt spinning were similar the microsegregation pattern across the gamma dendries was different. The range of microstructures evolved was analyzed in terms of the nature of the primary phase to nucleate, its subsequent dendritic growth, coarsening and fragmentation, and final solidification of interfenderitic liquid.

  11. PECULIAR OPTICAL AND IR BEHAVIOUR IN TYPE I SUPERNOVAE, AND THE ORIGIN OF THE 1.2 ABSORPTION

    E-Print Network [OSTI]

    Graham, J.R.

    2011-01-01

    Wheeler, le. , 1984. In "Supernovae as distance indicators",lR. , 1985. In "Dust in supernovae and supernova remnants",and IR behaviour in type I supernovae, and the origin of the

  12. CH{sub 4}-CO{sub 2} reforming over Ni-substituted barium hexaaluminate catalysts

    SciTech Connect (OSTI)

    Gardner, Todd H. [U.S. DOE; Spivey, James J. [ORISE; Kugler, Edwin L.; Pakhare, Devendra

    2013-03-30

    A series of Ni-substituted barium hexaaluminate catalysts, Ba{sub 0.75}Ni{sub y}Al{sub 12?y}O{sub 19??} (y = 0.4, 0.6 and 1.0), were tested for CO{sub 2} reforming of CH{sub 4} at temperatures between 200 and 900 °C. Temperature programmed surface reaction results show that the reaction lights-off in a temperature range between 448 and 503 °C with a consistent decrease in light-off temperature with increasing Ni substitution. Isothermal runs performed at 900 °C show near equilibrium conversion and stable product concentrations for 18 h on all catalysts. Temperature programmed oxidation of the used catalysts show that the amount of carbon deposited on the catalyst increases with Ni substitution. High resolution XRD of the used Ba{sub 0.75}Ni{sub 0.4}Al{sub 11.6}O{sub 19??} catalyst shows a statistically significant contraction of the unit cell which is the result of NiO reduction from the lattice. XRD of the used catalyst also confirms the presence of graphitic carbon. XPS and ICP measurements of the as prepared catalysts show that lower levels of Ni substitution result in an increasing proportion of Ba at the surface.

  13. Structural and Electrical Functionality of NiO Interfacial Films in Bulk Heterojunction Organic Solar Cells

    SciTech Connect (OSTI)

    Irwin, M.D.; Servaites, J.D.; Buchholz, B.D.; Leever, B.J.; Liu, J.; Emery, J.D.; Zhang, M.; Song, J.H.; Durstock, M.F.; Freeman, Arthur J.; Bedzyk, M.J.; Hersam, Mark C.; Chang, R.P.H.; Ratner, Mark A.; Marks, Tobin J.

    2011-01-01

    The functionality of NiO interfacial layers in enhancing bulk heterojunction (BHJ) organic photovoltaic (OPV) cell performance is investigated by integrated characterization of the electrical properties, microstructure, electronic structure, and optical properties of thin NiO films grown on glass/ITO electrodes. These NiO layers are found to be advantageous in BHJ OPV applications due to favorable energy band levels, interface passivation, p-type character, crystallinity, smooth surfaces, and optical transparency. The NiO overlayers are fabricated via pulsed-laser deposition and found to have a work function of ?5.3 eV. They are investigated by both topographic and conductive atomic force microscopy and shown to passivate interfacial charge traps. The films also have an average optical transparency of >80% in the visible range, crucial for efficient OPV function, and have a near-stoichiometric Ni:O surface composition. By grazing-incidence X-ray diffraction, the NiO thin films are shown to grow preferentially in the (111) direction and to have the fcc NaCl crystal structure. Diodes of p?n structure and first-principles electronic structure calculations indicate that the NiO interlayer is preferentially conductive to holes, with a lower hole charge carrier effective mass versus that of electrons. Finally, the implications of these attributes in advancing efficiencies for state-of-the-art OPV systems—in particular, improving the open circuit voltage (V{sub OC})—are discussed.

  14. On characterisation of wire-arc-plasma-sprayed Ni on alumina substrate

    SciTech Connect (OSTI)

    Laik, A.; Chakravarthy, D.P.; Kale, G.B. . E-mail: gbkale@apsara.barc.ernet.in

    2005-08-15

    A study was carried out on metal-ceramic bonding produced by the technique of wire-arc-plasma spraying of Ni on Al{sub 2}O{sub 3} substrate. The Ni layer and the Ni/Al{sub 2}O{sub 3} interface were characterised using optical and electro-optic techniques. The plasma-deposited Ni layer shows a uniform lamellar microstructure throughout the cross-section. The metal-ceramic interface was found to be well bonded with no pores, flaws or cracks in the as-sprayed condition. The optical metallography and concentration profiles established with the help of an electron probe microanalyser confirmed the absence of any intermediate phase at the interface. An annealing treatment at 1273 K for 24 h on the plasma-coated samples did not result in formation of any intermetallic compound or spinel at the Ni/Al{sub 2}O{sub 3} interface. This indicates that the oxygen picked up by Ni during the spraying operation is less than the threshold value required to form the spinel NiAl{sub 2}O{sub 4}.

  15. (001) Oriented piezoelectric films prepared by chemical solution deposition on Ni foils

    SciTech Connect (OSTI)

    Yeo, Hong Goo, E-mail: hxy162@psu.edu; Trolier-McKinstry, Susan [Materials Research Institute, The Pennsylvania State University, University Park, Pennsylvania 16802 (United States)

    2014-07-07

    Flexible metal foil substrates are useful in some microelectromechanical systems applications including wearable piezoelectric sensors or energy harvesters based on Pb(Zr,Ti)O? (PZT) thin films. Full utilization of the potential of piezoelectrics on metal foils requires control of the film crystallographic texture. In this study, (001) oriented PZT thin films were grown by chemical solution deposition (CSD) on Ni foil and Si substrates. Ni foils were passivated using HfO? grown by atomic layer deposition in order to suppress substrate oxidation during subsequent thermal treatment. To obtain the desired orientation of PZT film, strongly (100) oriented LaNiO? films were integrated by CSD on the HfO? coated substrates. A high level of (001) LaNiO? and PZT film orientation were confirmed by X-ray diffraction patterns. Before poling, the low field dielectric permittivity and loss tangents of (001) oriented PZT films on Ni are near 780 and 0.04 at 1 kHz; the permittivity drops significantly on poling due to in-plane to out-of-plane domain switching. (001) oriented PZT film on Ni displayed a well-saturated hysteresis loop with a large remanent polarization ~36 ?C/cm˛, while (100) oriented PZT on Si showed slanted P-E hysteresis loops with much lower remanent polarizations. The |e{sub 31,f}| piezoelectric coefficient was around 10.6 C/m˛ for hot-poled (001) oriented PZT film on Ni.

  16. Effect of Spin-Crossover-Induced Pore Contraction on CO{sub 2}-Host Interactions in the Porous Coordination Polymers [Fe(pyrazine)M(CN){sub 4}] (M = Ni, Pt)

    SciTech Connect (OSTI)

    Culp, Jeffrey T.; Chen, De-Li; Liu, Jinchen; Chirdon, Danielle; Kauffman, Kristi; Goodman, Angela; Johnson, J. Karl

    2013-02-01

    Variable-temperature in situ ATR-FTIR spectra are presented for the porous spin-crossover compounds [Fe(pyrazine)- Ni(CN){sub 4}] and [Fe(pyrazine)Pt(CN){sub 4}] under CO{sub 2} pressures of up to 8 bar. Significant shifts in the ?{sub 3} and ?{sub 2} IR absorption bands of adsorbed CO{sub 2} are observed as the host materials undergo transition between low- and high-spin states. Computational models used to determine the packing arrangement of CO{sub 2} within the pore structures show a preferred orientation of one of the adsorbed CO{sub 2} molecules with close O=C=O···H contacts with the pyrazine pillar ligands. The interaction is a consequence of the commensurate distance of the inter-pyrazine separations and the length of the CO{sub 2} molecule, which allows the adsorbed CO{sub 2} to effectively bridge the pyrazine pillars in the structure. The models were used to assign the distinct shifts in the IR absorption bands of the adsorbed CO{sub 2} that arise from changes in the O=C=O···H contacts that strengthen and weaken in correlation with changes in the Fe–N bond lengths as the spin state of Fe changes. The results indicate that spin-crossover compounds can function as a unique type of flexible sorbent in which the pore contractions associated with spin transition can affect the strength of CO{sub 2}–host interactions.

  17. Littleton Mt. Washington

    E-Print Network [OSTI]

    Pringle, James "Jamie"

    · Across New Hampshire IN TRAVELING NEW HAMPSHIRE HIGHWAYS AND BACK ROADS, you'll discover New Hampshire, Keene Nashua Community College, Nashua BAE Systems of N.A., Nashua University of New Hampshire, Durham Great Bay Community College, Portsmouth New Hampshire Space grant Consortium 1 23 4 56 7 8 9 10 11 12 13

  18. versity (MT Assistant o

    E-Print Network [OSTI]

    discipline um vitae, s and contac electronica cmsearch@ 2011, an trategic Fac nitiative ates are en rsities

  19. Fabrication of hollow mesoporous NiO hexagonal microspheres via hydrothermal process in ionic liquid

    SciTech Connect (OSTI)

    Zhao, Jinbo; School of Materials Science and Engineering, Shandong University, 250061, Jinan ; Wu, Lili; School of Materials Science and Engineering, Shandong University, 250061, Jinan ; Zou, Ke; School of Materials Science and Engineering, Shandong University, 250061, Jinan

    2011-12-15

    Highlights: Black-Right-Pointing-Pointer Ni(OH){sub 2} precursors were synthesized in ionic liquid and water solution by hydrothermal method. Black-Right-Pointing-Pointer NiO hollow microspheres were prepared by thermal treatment of Ni(OH){sub 2} precursors. Black-Right-Pointing-Pointer NiO hollow microspheres were self-assembled by mesoporous cubic and hexagonal nanocrystals with high specific surface area. Black-Right-Pointing-Pointer The mesoporous structure is stable at 773 K. Black-Right-Pointing-Pointer The ionic liquid absorbed on the O-terminate surface of the crystals to form hydrogen bond and played key roles in determining the final shape of the NiO novel microstructure. -- Abstract: The novel NiO hexagonal hollow microspheres have been successfully prepared by annealing Ni(OH){sub 2}, which was synthesized via an ionic liquid-assisted hydrothermal method. The samples were characterized by X-ray diffraction (XRD), field emission scanning electron microscope (FE-SEM), transmission electron microscopy (TEM), N{sub 2} adsorption-desorption and Fourier transform infrared spectrometer (FTIR). The results show that the hollow NiO microstructures are self-organized by mesoporous cubic and hexagonal nanocrystals. The mesoporous structure possessed good thermal stability and high specific surface area (ca. 83 m{sup 2}/g). The ionic liquid 1-butyl-3methylimidazolium tetrafluoroborate ([Bmim][BF{sub 4}]) was found to play a key role in controlling the morphology of NiO microstructures during the hydrothermal process. The special hollow mesoporous architectures will have potential applications in many fields, such as catalysts, absorbents, sensors, drug-delivery carriers, acoustic insulators and supercapacitors.

  20. Understanding the water emission in the mid- and far-IR from protoplanetary disks around T~Tauri stars

    E-Print Network [OSTI]

    Antonellini, S; Riviere-Marichalar, P; Meijerink, R; Woitke, P; Thi, W -F; Spaans, M; Aresu, G; Lee, G

    2015-01-01

    We investigate which properties of protoplanetary disks around T Tauri stars affect the physics and chemistry in the regions where mid- and far-IR water lines originate and their respective line fluxes. We search for diagnostics for future observations. With the code ProDiMo, we build a series of models exploring a large parameter space, computing rotational and rovibrational transitions of water in nonlocal thermodynamic equilibrium (non-LTE). We select a sample of transitions in the mid- IR regime and the fundamental ortho and para water transitions in the far-IR. We investigate the chemistry and the local physical conditions in the line emitting regions. We calculate Spitzer spectra for each model and compare far-IR and mid-IR lines. In addition, we use mid-IR colors to tie the water line predictions to the dust continuum. Parameters affecting the water line fluxes in disks by more than a factor of three are : the disk gas mass, the dust-to-gas mass ratio, the dust maximum grain size, ISM(InterStellarMediu...

  1. Features of a priori heavy doping of the n-TiNiSn intermetallic semiconductor

    SciTech Connect (OSTI)

    Romaka, V. A.; Rogl, P.; Romaka, V. V.; Hlil, E. K.; Stadnyk, Yu. V.; Budgerak, S. M.

    2011-07-15

    The crystal structure, the distribution of electron density, and the energy, kinetic, and magnetic properties of the n-TiNiSn intermetallic semiconductor are investigated. It is shown that a priori doping of n-TiNiSn with donors originates from partial, up to 0.5 at %, redistribution of Ti and Ni atoms in crystallographic sites of Ti atoms. The correlation is established between the donor concentration, amplitude of modulation of the continuous energy bands, and degree of filling of low-scale fluctuation potential wells with charge carriers. The results obtained are discussed within the Shklovskii-Efros model of a heavily doped and compensated semiconductor.

  2. In Situ Observations of the Atomistic Mechanisms of Ni Catalyzed Low Temperature Graphene Growth

    E-Print Network [OSTI]

    Patera, Laerte L.; Africh, Cristina; Weatherup, Robert S.; Blume, Raoul; Bhardwaj, Sunil; Castellarin-Cudia, Carla; Knop-Gericke, Axel; Schloegl, Robert; Comelli, Giovanni; Hofmann, Stephan; Cepek, Cinzia

    2013-08-08

    , CA (283.2eV), CDis (283.8eV), CGr (284.4eV), and CB (284.8eV). The C1s spectrum of the graphene covered Ni(111) surface in Figure 3c shows a dominant CB component, ?72% of the total C1s intensity, with the CDis and CGr contributing ?12% and ?15... -range ordered structure, would show a component of similar binding energy resulting from a similar charge transfer from Ni to embedded C atoms. This broader assignment of CA could account for previous observations of a CA peak under conditions where Ni2C may...

  3. Improved synthesis and crystal structure of the flexible pillared layer porous coordination polymer: Ni(1,2-bis(4-pyridyl)ethylene)[Ni(CN)(4)

    SciTech Connect (OSTI)

    Wong-Ng, W.; Culp, J. T.; Chen, Y. S.; Zavalij, P.; Espinal, L.; Siderius, D. W.; Allen, A. J.; Scheins, S Matranga, C

    2013-04-04

    This paper reports our synthesis of flexible coordination polymer, Ni(L)[Ni(CN){sub 4}], (L = 1,2-bis(4- pyridyl)ethylene (nicknamed bpene)), and its structural characterization using synchrotron single crystal X-ray diffraction. The structure of the purplish crystals has been determined to be monoclinic, space group P2{sub 1}/m, a = 13.5941(12) Ĺ, b = 14.3621(12) Ĺ, c = 14.2561(12) Ĺ, {beta} = 96.141(2){degrees|, V = 2767.4(4) Ĺ{sup 3}, Z = 4, D{sub c} = 1.46 g cm{sup -1}. Ni(bpene)[Ni(CN){sub 4}] assumes a pillared layer structure with layers defined by Ni[Ni(CN){sub 4}]{sub n} nets and bpene ligands acting as pillars. With the present crystallization technique which involves the use of concentrated ammonium hydroxide solution and dimethyl sulfoxide (DMSO), disordered free bpene ligands and solvents of crystallization (DMSO and water molecules) occupy the pores, resulting in a formula of Ni(bpene)[Ni(CN){sub 4}](1/2)bpene.DMSO.2H{sub 2}O, or Ni{sub 2}N{sub 7}C{sub 24}H{sub 2}.5SO{sub 3}. Without the inclusion of free bpene ligands and solvent molecules, the free volume is approximately 61% of the total volume; this free volume fraction is reduced to 50% with the free ligands present. Pores without the free ligands were found to have a local diameter of 5.7 Ĺ and a main aperture of 3.5 Ĺ. Based on the successful crystal synthesis, we also devised a new bulk synthetic technique which yielded a polycrystalline material with a significantly improved CO{sub 2} uptake as compared to the originally reported powder material. The improved synthetic technique yielded a polycrystalline material with 40% higher CO{sub 2} uptake compared to the previously reported powder material. An estimated 14.4 molecules of CO{sub 2} per unit cell was obtained.

  4. A semisynthetic strategy leads to alteration of the backbone amidate ligand in the NiSOD active site

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Campecińo, Julius O.; Dudycz, Lech W.; Tumelty, David; Berg, Volker; Cabelli, Diane E.; Maroney, Michael J.

    2015-07-01

    Computational investigations have implicated the amidate ligand in nickel superoxide dismutase (NiSOD) in stabilizing Ni-centered redox catalysis and in preventing cysteine thiolate ligand oxidation. To test these predictions, we have used an experimental approach utilizing a semisynthetic scheme that employs native chemical ligation of a pentapeptide (HCDLP) to recombinant S. coelicolor NiSOD lacking these N-terminal residues, N?5-NiSOD. Wild-type enzyme produced in this manner exhibits the characteristic spectral properties of recombinant WT-NiSOD and is as catalytically active. The semisynthetic scheme was also employed to construct a variant where the amidate ligand was converted to a secondary amine, H1*-NiSOD, a novel strategymore »that retains a backbone N-donor atom. The H1*-NiSOD variant was found to have only ~1% of the catalytic activity of the recombinant wild-type enzyme, and had altered spectroscopic properties. X-ray absorption spectroscopy reveals a four-coordinate planar site with N2S2-donor ligands, consistent with electronic absorption spectroscopic results indicating that the Ni center in H1*-NiSOD is mostly reduced in the as-isolated sample, as opposed to 50:50 Ni(II)/Ni(III) mixture that is typical for the recombinant wild-type enzyme. The EPR spectrum of as-isolated H1*-NiSOD accounts for ~11% of the Ni in the sample and is similar to WT-NiSOD, but more axial, with gz x,y. 14N-hyperfine is observed on gz« less

  5. Transition from the infalling envelope to the Keplerian disk around L1551 IRS 5

    SciTech Connect (OSTI)

    Chou, Ti-Lin [Department of Physics, National Taiwan University, No. 1, Sec. 4, Roosevelt Road, Taipei 106, Taiwan (China); Takakuwa, Shigehisa; Yen, Hsi-Wei; Ohashi, Nagayoshi; Ho, Paul T. P., E-mail: tlchou@asiaa.sinica.edu.tw [Academia Sinica Institute of Astronomy and Astrophysics, P. O. Box 23-141, Taipei 10617, Taiwan (China)

    2014-11-20

    We present combined Submillimeter Array (SMA) +Atacama Submillimeter Telescope Experiment (ASTE) images of the Class I protobinary L1551 IRS 5 in the CS (J = 7-6) line, the submillimeter images of L1551 IRS 5 with the most complete spatial sampling ever achieved (0.''9-36''). The SMA image of L1551 IRS 5 in the 343 GHz dust-continuum emission is also presented, which shows an elongated feature along the northwest to southeast direction (?160 AU × 80 AU), perpendicular to the associated radio jets. The combined SMA+ASTE images show that the high-velocity (?1.5 km s{sup –1}) CS emission traces the structure of the dust component and shows a velocity gradient along the major axis, which is reproduced by a geometrically thin Keplerian-disk model with a central stellar mass of ?0.5 M {sub ?}. The low-velocity (?1.3 km s{sup –1}) CS emission shows an extended (?1000 AU) feature that exhibits slight south (blueshifted) to north (redshifted) emission offsets, which is modeled with a rotating and infalling envelope with a conserved angular momentum. The rotational motion of the envelope connects smoothly to the inner Keplerian rotation at a radius of ?64 AU. The infalling velocity of the envelope is ?three times lower than the free-fall velocity toward the central stellar mass of 0.5 M {sub ?}. These results demonstrate transition from the infalling envelope to the Keplerian disk, consistent with the latest theoretical studies of disk formation. We suggest that sizable (r ? 50-200 AU) Keplerian disks are already formed when the protostars are still deeply embedded in the envelopes.

  6. An Optical Offgas Sensor Network Incorporating a HG Cavity Ringdown Spectrometer and IR Diode Lasers

    SciTech Connect (OSTI)

    George P. Miller

    2007-12-30

    A multi-element cavity ringdown system was evaluated with the objective of developing an intelligent sensor network to be incorporated into the control systems for advanced coal combustion facilities. Using a combination of a YAG-pumped dye laser and a tunable NIR/IR laser a dual cavity was constructed and a labview program was developed to provide multi-channel, real-time data to permit the real-time monitoring of typical exhaust emission gases, (for example: CO{sub 2}, SO{sub 2}, and mercury) of concern to the next generation of coal-powered facilities.

  7. Observations of the 6 Centimeter Lines of OH in Evolved (OH/IR) Stars

    E-Print Network [OSTI]

    Vincent L. Fish; Laura K. Zschaechner; Loránt O. Sjouwerman; Ylva M. Pihlström; Mark J. Claussen

    2006-10-24

    Recent observational and theoretical advances have called into question traditional OH maser pumping models in evolved (OH/IR) stars. The detection of excited-state OH lines would provide additional constraints to discriminate amongst these theoretical models. In this Letter, we report on VLA observations of the 4750 MHz and 4765 MHz lines of OH toward 45 sources, mostly evolved stars. We detect 4765 MHz emission in the star forming regions Mon R2 and LDN 1084, but we do not detect excited-state emission in any evolved stars. The flux density and velocity of the 4765 MHz detection in Mon R2 suggests that a new flaring event has begun.

  8. Phase-matched generation of coherent soft and hard X-rays using IR lasers

    DOE Patents [OSTI]

    Popmintchev, Tenio V.; Chen, Ming-Chang; Bahabad, Alon; Murnane, Margaret M.; Kapteyn, Henry C.

    2013-06-11

    Phase-matched high-order harmonic generation of soft and hard X-rays is accomplished using infrared driving lasers in a high-pressure non-linear medium. The pressure of the non-linear medium is increased to multi-atmospheres and a mid-IR (or higher) laser device provides the driving pulse. Based on this scaling, also a general method for global optimization of the flux of phase-matched high-order harmonic generation at a desired wavelength is designed.

  9. Near-UV to near-IR disk-averaged Earth's spectra from Moon's Earthshine observations

    E-Print Network [OSTI]

    S. Hamdani; L. Arnold; C. Foellmi; J. Berthier; D. Briot; P. Francois; P. Riaud; J. Schneider

    2005-10-13

    We discuss a series of Earthshine spectra obtained with the NTT/EMMI instrument between 320nm and 1020nm with a resolution of R~450 in the blue and R~250 in the red. These ascending and descending Moon's Earthshine spectra taken from Chile give disk-averaged spectra for two different Earth's phases. The spectra show the ozone (Huggins and Chappuis bands), oxygen and water vapour absorption bands, and also the stronger Rayleigh scattering in the blue. Removing the known telluric absorptions reveals a spectral feature around 700nm which is attributed to the vegetation stronger reflectivity in the near-IR, so-called vegetation red-edge.

  10. Integrating Interactive Visualizations in the Search Process of Digital Libraries and IR Systems

    E-Print Network [OSTI]

    Hienert, Daniel; Schaer, Philipp; Mayr, Philipp

    2012-01-01

    Interactive visualizations for exploring and retrieval have not yet become an integral part of digital libraries and information retrieval systems. We have integrated a set of interactive graphics in a real world social science digital library. These visualizations support the exploration of search queries, results and authors, can filter search results, show trends in the database and can support the creation of new search queries. The use of weighted brushing supports the identification of related metadata for search facets. We discuss some use cases of the combination of IR systems and interactive graphics. In a user study we verify that users can gain insights from statistical graphics intuitively and can adopt interaction techniques.

  11. On-Line Weld NDE with IR Thermography | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCED MANUFACTURINGEnergy Bills and ReduceNovemberDOE'sManagement ofOh,ofOn-Line Weld NDE with IR

  12. Shape memory and superelasticity in polycrystalline Cu-Al-Ni microwires

    E-Print Network [OSTI]

    Chen, Ying

    We report a strategy to significantly improve the ductility and achieve large superelastic and shape memory strains in polycrystalline Cu–Al–Ni shape memory alloys that are normally brittle. We use a liquid-phase (Taylor) ...

  13. Contact-induced spin polarization of monolayer hexagonal boron nitride on Ni(111)

    SciTech Connect (OSTI)

    Ohtomo, Manabu; Entani, Shiro; Matsumoto, Yoshihiro; Naramoto, Hiroshi; Sakai, Seiji; Yamauchi, Yasushi; Kuzubov, Alex A.; Eliseeva, Natalya S.; Avramov, Pavel V.

    2014-02-03

    Hexagonal boron nitride (h-BN) is a promising barrier material for graphene spintronics. In this Letter, spin-polarized metastable de-excitation spectroscopy (SPMDS) is employed to study the spin-dependent electronic structure of monolayer h-BN/Ni(111). The extreme surface sensitivity of SPMDS enables us to elucidate a partial filling of the in-gap states of h-BN without any superposition of Ni 3d signals. The in-gap states are shown to have a considerable spin polarization parallel to the majority spin of Ni. The positive spin polarization is attributed to the ?-d hybridization and the effective spin transfer to the nitrogen atoms at the h-BN/Ni(111) interface.

  14. Understanding and development of combined acoustic and magnetic actuation of Ni?MnGa single crystals

    E-Print Network [OSTI]

    Techapiesancharoenkij, Ratchatee, 1979-

    2007-01-01

    Ni-Mn-Ga based ferromagnetic shape memory alloys (FSMAs) have emerged as a promising new class of active materials capable of producing a large (several %) magnetic-field-induced strain (MFIS). FSMAs still have several ...

  15. Thermodynamic modeling and experimental validation of the Fe-Al-Ni-Cr-Mo alloy system

    SciTech Connect (OSTI)

    Teng, Zhenke; Zhang, F; Miller, Michael K; Liu, Chain T; Huang, Shenyan; Chou, Y.T.; Tien, R; Chang, Y A; Liaw, Peter K

    2012-01-01

    NiAl-type precipitate-strengthened ferritic steels have been known as potential materials for the steam turbine applications. In this study, thermodynamic descriptions of the B2-NiAl type nano-scaled precipitates and body-centered-cubic (BCC) Fe matrix phase for four alloys based on the Fe-Al-Ni-Cr-Mo system were developed as a function of the alloy composition at the aging temperature. The calculated phase structure, composition, and volume fraction were validated by the experimental investigations using synchrotron X-ray diffraction and atom probe tomography. With the ability to accurately predict the key microstructural features related to the mechanical properties in a given alloy system, the established thermodynamic model in the current study may significantly accelerate the alloy design process of the NiAl-strengthened ferritic steels.

  16. Hydroxyl and molecular H2O diffusivity in a haploandesitic melt Huaiwei Ni a,b,

    E-Print Network [OSTI]

    Zhang, Youxue

    Hydroxyl and molecular H2O diffusivity in a haploandesitic melt Huaiwei Ni a,b, , Zhengjiu Xu c) rather than hydroxyl group (OH), water diffusivity has been experimentally determined for a variety

  17. Thermal properties of Ni-substituted LaCoO{sub 3} perovskite

    SciTech Connect (OSTI)

    Thakur, Rasna Thakur, Rajesh K. Gaur, N. K.; Srivastava, Archana

    2014-04-24

    With the objective of exploring the unknown thermodynamic behavior of LaCo{sub 1?x}Ni{sub x}O{sub 3} family, we present here an investigation of the temperature-dependent (10K ? T ? 300K) thermodynamic properties of LaCo{sub 1?x}Ni{sub x}O{sub 3} (x=0.1, 0.3, 0.5). The specific heat of LaCoO3 with Ni doping in the perovskite structure at B-site has been studied by means of a Modified Rigid Ion Model (MRIM). This replacement introduces large cation variance at B-site hence the specific heat increases appreciably. We report here probably for the first time the cohesive energy, Reststrahlen frequency (?) and Debye temperature (?{sub D}) of LaCo{sub 1?x}Ni{sub x}O{sub 3} compounds.

  18. Measuring relative performance of an EDS detector using a NiO...

    Office of Scientific and Technical Information (OSTI)

    performance of energy dispersive spectrometers (EDS) on a TEM is discussed. A NiO thin-film standard fabricated at Sandia CA is used. A performance parameter,, is measured and...

  19. Scattering of xenon from Ni,,111...: Collision-induced corrugation and energy transfer dynamics

    E-Print Network [OSTI]

    , Stanford, California 94305 Received 19 April 1999; accepted 26 October 1999 Experiments have been conducted in which a beam of xenon atoms collides with a clean Ni 111 surface, and the speed and angular super- sonic molecular

  20. Fabrication and characterization of porous NiTi Shape Memory Alloy by elevated pressure sintering 

    E-Print Network [OSTI]

    Vandygriff, Eric Layton

    2002-01-01

    have not been adequately developed. Currently, three methods are commonly used for producing porous NiTi SMAs from elemental powders. These methods include conventional sintering, Self-propagating High-temperature Synthesis (SHS), and sintering...

  1. Study on Degradation of Solid Oxide Fuel Cell With Pure Ni Anode Zhenjun Jiaoa

    E-Print Network [OSTI]

    Kasagi, Nobuhide

    Study on Degradation of Solid Oxide Fuel Cell With Pure Ni Anode Zhenjun Jiaoa , Naoki Shikazonoa Solid oxide fuel cell (SOFC) has attracted more and more attentions in the last few decades

  2. Isoscalar and neutron modes in the E 1 spectra of Ni isotopes...

    Office of Scientific and Technical Information (OSTI)

    Isoscalar and neutron modes in the E 1 spectra of Ni isotopes and the relevance of shell effects and the continuum Citation Details In-Document Search This content will become...

  3. Pressure-Induced Structural Phase Transition in CeNi: X-ray and...

    Office of Scientific and Technical Information (OSTI)

    Pressure-Induced Structural Phase Transition in CeNi: X-ray and Neutron Scattering Studies and First-Principles Calculations Citation Details In-Document Search This content will...

  4. Shape-Memory Transformations of NiTi: Minimum-Energy Pathways...

    Office of Scientific and Technical Information (OSTI)

    Details In-Document Search This content will become publicly available on December 24, 2015 Title: Shape-Memory Transformations of NiTi: Minimum-Energy Pathways between Austenite,...

  5. Low Spring Index NiTi Coil Actuators for Use in Active Compression Garments

    E-Print Network [OSTI]

    Holschuh, Bradley T.

    This paper describes the modeling, development, and testing of low spring index nickel titanium (NiTi) coil actuators designed for use in wearable compression garments, and presents a prototype tourniquet system using these ...

  6. Computational Thermodynamics of CoNiGa High Temperature Shape Memory Alloys 

    E-Print Network [OSTI]

    Chari, Arpita

    2012-10-19

    Shape Memory Alloys (SMAs) are advanced materials with interesting properties such as pseudoelasticity (PE) and the shape memory effect (SME). Recently, the CoNiGa system has emerged as the basis for very promising High ...

  7. Structure and magnetic properties of Ce?(Ni/Al/Ga)??-A...

    Office of Scientific and Technical Information (OSTI)

    Ce(NiAlGa)-A new phase with the LaAl structure type Janka, Oliver Univ. of California, Davis, CA (United States); Westfalische Wilhelms-Universitat, Munster...

  8. Graphene-on-Insulator Transistors Made Using C on Ni Chemical-Vapor Deposition

    E-Print Network [OSTI]

    Keast, Craig L.

    Graphene transistors are made by transferring a thin graphene film grown on Ni onto an insulating SiO[subscript 2] substrate. The properties and integration of these graphene-on-insulator transistors are presented and ...

  9. The thermomechanical constitutive experimentation of NiTi shape memory alloy strips and rods 

    E-Print Network [OSTI]

    Howard, Stephen David

    1995-01-01

    The purpose of this thesis was to study the effect of temperature on the thermomechanical constitutive behavior of NiTi shape memory alloy strip and rod specimens. The stress-strain relationship is analyzed for isothermal monotonic tensile testing...

  10. Hydrogen absorption characteristics of amorphous LaNi[sub 5. 0] films prepared by reactive sputtering

    SciTech Connect (OSTI)

    Sakaguchi, H.; Tsujimoto, T.; Adachi, Ginya (Osaka University, Suita (Japan))

    1993-01-01

    Amorphous LaNi[sub 5] thin films are expected to be one of the promising materials for use in hydrogen separation and battery electrodes, because the durability of the films is great in regard to the hydrogen absorption-desorption cycling process and the films have excellent resistance to harmful impurities in the hydrogen gas in comparison with the crystalline bulk material. An amorphous LaNi[sub 5.0] film having high hydrogen density and low hydrogen-induced stress was obtained by means of a reactive sputtering method using an Ar-H[sub 2] gas mixture. Pressure-composition isotherms show that the amount of hydrogen (H/LaNi[sub 5.0]) taken up by a formula weight of LaNi[sub 5.0] is about 1.5 times larger for the reactive sputtered film than for the conventional sputtered film prepared by using Ar gas. 18 refs., 1 fig, 1 tabs.

  11. Magnetism of NiMn2O4-Fe3O4 spinel interfaces

    E-Print Network [OSTI]

    Nelson-Cheeseman, B. B.

    2007-01-01

    2 O 4 –Fe 3 O 4 spinel interfaces B. B. Nelson-Cheeseman,isostructural spinel-spinel interface of NiMn 2 O 4 (NMO)–Feis preserved, both bulk and interface sensitive measurements

  12. Experimental determination of band offsets of NiO-based thin film heterojunctions

    SciTech Connect (OSTI)

    Kawade, Daisuke; Sugiyama, Mutsumi, E-mail: mutsumi@rs.noda.tus.ac.jp [Faculty of Science and Technology/Research Institute for Science and Technology, Tokyo University of Science, 2641 Yamazaki, Noda 278-8510 (Japan); Chichibu, Shigefusa F. [Institute of Multidisciplinary Research for Advanced Materials, Tohoku University, 2-1-1 Katahira, Aoba, Sendai 980–8577 (Japan)

    2014-10-28

    The energy band diagrams of NiO-based solar cell structures that use various n-type oxide semiconductors such as ZnO, Mg{sub 0.3}Zn{sub 0.7}O, Zn{sub 0.5}Sn{sub 0.5}O, In{sub 2}O{sub 3}:Sn (ITO), SnO{sub 2}, and TiO{sub 2} were evaluated by photoelectron yield spectroscopy. The valence band discontinuities were estimated to be 1.6?eV for ZnO/NiO and Mg{sub 0.3}Zn{sub 0.7}O/NiO, 1.7?eV for Zn{sub 0.5}Sn{sub 0.5}O/NiO and ITO/NiO, and 1.8?eV for SnO{sub 2}/NiO and TiO{sub 2}/NiO heterojunctions. By using the valence band discontinuity values and corresponding energy bandgaps of the layers, energy band diagrams were developed. Judging from the band diagram, an appropriate solar cell consisting of p-type NiO and n-type ZnO layers was deposited on ITO, and a slight but noticeable photovoltaic effect was obtained with an open circuit voltage (V{sub oc}) of 0.96?V, short circuit current density (J{sub sc}) of 2.2??A/cm{sup 2}, and fill factor of 0.44.

  13. Heat treatment of NiCrFe alloy to optimize resistance to intergrannular stress corrosion

    DOE Patents [OSTI]

    Steeves, Arthur F. (Schenectady, NY); Bibb, Albert E. (Clifton Park, NY)

    1984-01-01

    A process of producing a NiCrFe alloy having a high resistance to stress corrosion cracking comprising heating a NiCrFe alloy to a temperature sufficient to enable the carbon present in the alloy body in the form of carbide deposits to enter into solution, rapidly cool the alloy body, and heat the cooled body to a temperature between 1100.degree. to 1500.degree. F. for about 1 to 30 hours.

  14. Determination of mechanical properties of Ni-Cr-P amorphous alloys 

    E-Print Network [OSTI]

    Kondlapudi, Swaroop Kumar R

    1991-01-01

    DETERMINATION OF MECHANICAL PROPERTIES OF Ni-Cr-P AMORPHOUS ALLOYS A Thesis by SWAROOP KUMAR R. KONDLAPUDI Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree... of MASTER OF SCIENCE August 1991 Major Subject: Mechanical Engineering DETERMINATION OF MECHANICAL PROPERTIES OF Ni-Cr-P AMORPHOUS ALLOYS A Thesis by SWAROOP KUMAR R. KONDLAPUDI Approved as to style and content by I-t (, :()o . e, ~&am A. Wolfenden...

  15. Axion decay and anisotropy of near-IR extragalactic background light

    E-Print Network [OSTI]

    Gong, Yan; Mitchell-Wynne, Ketron; Chen, Xuelei; Zemcov, Michael; Smidt, Joseph

    2015-01-01

    The extragalactic background light is expected to be comprised of the cumulative radiation from all galaxies and active galactic nuclei over the cosmic history. In addition to point sources, EBL also contains information from diffuse sources of radiation. An example is the intra-halo light, associated with diffuse stars in dark matter halos resulting from galaxy mergers and tidal interactions, identified based on measurements involving the angular power spectrum of infrared background anisotropies. The angular power spectra of the near-infrared intensities could still contain additional signals and a complete understanding of the nature of the IR background is still lacking in the literature. Here we explore the constraints that can be placed on the decay products associated with particle decays, especially candidate dark matter models involving axions that trace dark matter halos of galaxies. Axions with a mass around a few eV will decay via two photons with wavelengths in the near-IR band, and will leave a ...

  16. IRS Spectra of Debris Disks in the Scorpius-Centaurus OB Association

    E-Print Network [OSTI]

    Jang-Condell, Hannah; Manoj, P; Watson, Dan; Lisse, Carey M; Nesvold, Erika; Kuchner, Marc

    2015-01-01

    We analyze Spitzer/IRS spectra of 110 B-, A-, F-, and G-type stars with optically thin infrared excess in the Scorpius-Centaurus (ScoCen) OB association. The age of these stars ranges from 11-17 Myr. We fit the infrared excesses observed in these sources by Spitzer/IRS and Spitzer/MIPS to simple dust models according to Mie theory. We find that nearly all the objects in our study can be fit by one or two belts of dust. Dust around lower mass stars appears to be closer in than around higher mass stars, particularly for the warm dust component in the two-belt systems, suggesting mass-dependent evolution of debris disks around young stars. For those objects with stellar companions, all dust distances are consistent with trunction of the debris disk by the binary companion. The gaps between several of the two-belt systems can place limits on the planets that might lie between the belts, potentially constraining the mass and locations of planets that may be forming around these stars.

  17. Spatially Resolved Spitzer-IRS Spectral Maps of the Superwind in M82

    E-Print Network [OSTI]

    Beirăo, P; Lehnert, M D; Guillard, P; Heckman, T; Draine, B; Hollenbach, D; Walter, F; Sheth, K; Smith, J D; Shopbell, P; Boulanger, F; Surace, J; Hoopes, C; Engelbracht, C

    2015-01-01

    We have mapped the superwind/halo region of the nearby starburst galaxy M82 in the mid-infrared with $Spitzer-IRS$. The spectral regions covered include the H$_2 S(1)-S(3)$, [NeII], [NeIII] emission lines and PAH features. We estimate the total warm H$_2$ mass and the kinetic energy of the outflowing warm molecular gas to be between $M_{warm}\\sim5-17\\times10^6$ M$_{\\odot}$ and $E_{K}\\sim6-20\\times10^{53}$ erg. Using the ratios of the 6.2, 7.7 and 11.3 micron PAH features in the IRS spectra, we are able to estimate the average size and ionization state of the small grains in the superwind. There are large variations in the PAH flux ratios throughout the outflow. The 11.3/7.7 and the 6.2/7.7 PAH ratios both vary by more than a factor of five across the wind region. The Northern part of the wind has a significant population of PAH's with smaller 6.2/7.7 ratios than either the starburst disk or the Southern wind, indicating that on average, PAH emitters are larger and more ionized. The warm molecular gas to PAH f...

  18. New algorithms and technologies for the un-supervised reduction of Optical/IR images

    E-Print Network [OSTI]

    Benoit Vandame

    2002-08-12

    This paper presents some of the main aspects of the software library that has been developed for the reduction of optical and infrared images, an integral part of the end-to-end survey system being built to support public imaging surveys at ESO. Some of the highlights of the new library are: unbiased estimates of the background, critical for deep IR observations; efficient and accurate astrometric solutions, using multi-resolution techniques; automatic identification and masking of satellite tracks; weighted co-addition of images; creation of optical/IR mosaics, and appropriate management of multi-chip instruments. These various elements have been integrated into a system using XML technology for setting input parameters, driving the various processes, producing comprehensive history logs and storing the results, binding them to the supporting database and to the web. The system has been extensively tested using deep images as well as images of crowded fields (e.g. globular clusters, LMC), processing at a rate of 0.5 Mega-pixels per second using a DS20E ALPHA computer with two processors. The goal of this presentation is to review some of the main features of this package.

  19. Sonic IR crack detection of aircraft turbine engine blades with multi-frequency ultrasound excitations

    SciTech Connect (OSTI)

    Zhang, Ding; Han, Xiaoyan; Newaz, Golam

    2014-02-18

    Effectively and accurately detecting cracks or defects in critical engine components, such as turbine engine blades, is very important for aircraft safety. Sonic Infrared (IR) Imaging is such a technology with great potential for these applications. This technology combines ultrasound excitation and IR imaging to identify cracks and flaws in targets. In general, failure of engine components, such as blades, begins with tiny cracks. Since the attenuation of the ultrasound wave propagation in turbine engine blades is small, the efficiency of crack detection in turbine engine blades can be quite high. The authors at Wayne State University have been developing the technology as a reliable tool for the future field use in aircraft engines and engine parts. One part of the development is to use finite element modeling to assist our understanding of effects of different parameters on crack heating while experimentally hard to achieve. The development has been focused with single frequency ultrasound excitation and some results have been presented in a previous conference. We are currently working on multi-frequency excitation models. The study will provide results and insights of the efficiency of different frequency excitation sources to foster the development of the technology for crack detection in aircraft engine components.

  20. Experimental determination and thermodynamic modeling of the Ni-Re binary system

    SciTech Connect (OSTI)

    Yaqoob, Khurram [Chimie Metallurgique des Terres Rares (CMTR), Institut de Chimie et des Materiaux Paris-Est (ICMPE), 2-8 rue Henri Dunant, 94320 Thiais Cedex (France)] [Chimie Metallurgique des Terres Rares (CMTR), Institut de Chimie et des Materiaux Paris-Est (ICMPE), 2-8 rue Henri Dunant, 94320 Thiais Cedex (France); Joubert, Jean-Marc, E-mail: jean-marc.joubert@icmpe.cnrs.fr [Chimie Metallurgique des Terres Rares (CMTR), Institut de Chimie et des Materiaux Paris-Est (ICMPE), 2-8 rue Henri Dunant, 94320 Thiais Cedex (France)] [Chimie Metallurgique des Terres Rares (CMTR), Institut de Chimie et des Materiaux Paris-Est (ICMPE), 2-8 rue Henri Dunant, 94320 Thiais Cedex (France)

    2012-12-15

    The phase diagram of the Ni-Re binary system has been partially reinvestigated by chemical, structural and thermal characterization of the arc melted alloys. The experimental results obtained during the present investigation were combined with the literature data and a new phase diagram of the Ni-Re binary system is proposed. In comparison with the Ni-Re phase diagram proposed by Nash et al. in 1985 [1], significant differences in the homogeneity domains, freezing ranges and peritectic reaction temperature were evidenced. On the other hand, thermodynamic modeling of the studied system by using the new experimental information has also been carried out with the help of the CALPHAD method. The calculated Ni-Re phase diagram showed a good agreement with the selected experimental information. - Graphical abstract: Ni-Re phase diagram according to the present study. Highlights: Black-Right-Pointing-Pointer Re-investigation of the Ni-Re phase diagram. Black-Right-Pointing-Pointer Extended phase field of the hcp phase. Black-Right-Pointing-Pointer Different freezing ranges and peritectic reaction temperature. Black-Right-Pointing-Pointer Thermodynamic modeling of the studied system by using the CALPHAD method.

  1. An Update on Improvements to NiCE Support for RELAP-7

    SciTech Connect (OSTI)

    McCaskey, Alex; Wojtowicz, Anna; Deyton, Jordan H.; Patterson, Taylor C.; Billings, Jay Jay

    2015-01-01

    The Multiphysics Object-Oriented Simulation Environment (MOOSE) is a framework that facilitates the development of applications that rely on finite-element analysis to solve a coupled, nonlinear system of partial differential equations. RELAP-7 represents an update to the venerable RELAP-5 simulator that is built upon this framework and attempts to model the balance-of-plant concerns in a full nuclear plant. This report details the continued support and integration of RELAP-7 and the NEAMS Integrated Computational Environment (NiCE). RELAP-7 is fully supported by the NiCE due to on-going work to tightly integrate NiCE with the MOOSE framework, and subsequently the applications built upon it. NiCE development throughout the first quarter of FY15 has focused on improvements, bug fixes, and feature additions to existing MOOSE-based application support. Specifically, this report will focus on improvements to the NiCE MOOSE Model Builder, the MOOSE application job launcher, and the 3D Nuclear Plant Viewer. This report also includes a comprehensive tutorial that guides RELAP-7 users through the basic NiCE workflow: from input generation and 3D Plant modeling, to massively parallel job launch and post-simulation data visualization.

  2. Interplay between out-of-plane anisotropic L1{sub 1}-type CoPt and in-plane anisotropic NiFe layers in CoPt/NiFe exchange springs

    SciTech Connect (OSTI)

    Saravanan, P.; Hsu, Jen-Hwa Tsai, C. L.; Tsai, C. Y.; Lin, Y. H.; Kuo, C. Y.; Wu, J.-C.; Lee, C.-M.

    2014-06-28

    Films of L1{sub 1}-type CoPt/NiFe exchange springs were grown with different NiFe (Permalloy) layer thickness (t{sub NiFe}?=?0–10?nm). X-ray diffraction analysis reveals that the characteristic peak position of NiFe(111) is not affected by the CoPt-layer—confirming the absence of any inter-diffusion between the CoPt and NiFe layers. Magnetic studies indicate that the magnetization orientation of NiFe layer can be tuned through varying t{sub NiFe} and the perpendicular magnetic anisotropy of L1{sub 1}-type CoPt/NiFe films cannot sustain for t{sub NiFe} larger than 3.0?nm due to the existence of exchange interaction at the interface of L1{sub 1}-CoPt and NiFe layers. Magnetic force microscopy analysis on the as-grown samples shows the changes in morphology from maze-like domains with good contrast to hazy domains when t{sub NiFe}???3.0?nm. The three-dimensional micro-magnetic simulation results demonstrate that the magnetization orientation in NiFe layer is not uniform, which continuously increases from the interface to the top of NiFe layer. Furthermore, the tilt angle of the topmost NiFe layers can be changed over a very wide range from a small number to about 75° by varying t{sub NiFe} from 1 to 10?nm. It is worth noting that there is an abrupt change in the magnetization direction at the interface, for all the t{sub NiFe} investigated. The results of present study demonstrate that the tunable tilted exchange springs can be realized with L1{sub 1}-type CoPt/NiFe bilayers for future applications in three-axis magnetic sensors or advanced spintronic devices demanding inclined magnetic anisotropy.

  3. Metallic glass alloys of Zr, Ti, Cu and Ni

    DOE Patents [OSTI]

    Lin, Xianghong (Pasadena, CA); Peker, Atakan (Pasadena, CA); Johnson, William L. (Pasadena, CA)

    1997-01-01

    At least quaternary alloys form metallic glass upon cooling below the glass transition temperature at a rate less than 10.sup.3 K/s. Such alloys comprise titanium from 19 to 41 atomic percent, an early transition metal (ETM) from 4 to 21 atomic percent and copper plus a late transition metal (LTM) from 49 to 64 atomic percent. The ETM comprises zirconium and/or hafnium. The LTM comprises cobalt and/or nickel. The composition is further constrained such that the product of the copper plus LTM times the atomic proportion of LTM relative to the copper is from 2 to 14. The atomic percentage of ETM is less than 10 when the atomic percentage of titanium is as high as 41, and may be as large as 21 when the atomic percentage of titanium is as low as 24. Furthermore, when the total of copper and LTM are low, the amount of LTM present must be further limited. Another group of glass forming alloys has the formula (ETM.sub.1-x Ti.sub.x).sub.a Cu.sub.b (Ni.sub.1-y Co.sub.y).sub.c wherein x is from 0.1 to 0.3, y.cndot.c is from 0 to 18, a is from 47 to 67, b is from 8 to 42, and c is from 4 to 37. This definition of the alloys has additional constraints on the range of copper content, b.

  4. Electrochemical Testing of Ni-Cr-Mo-Gd Alloys

    SciTech Connect (OSTI)

    T. E. Lister; R. E. Mizia; H. Tian

    2005-10-01

    The waste package site recommendation design specified a boron-containing stainless steel, Neutronit 976/978, for fabrication of the internal baskets that will be used as a corrosion-resistant neutron-absorbing material. Recent corrosion test results gave higher-than-expected corrosion rates for this material. The material callout for these components has been changed to a Ni-Cr-Mo-Gd alloy (ASTM-B 932-04, UNS N06464) that is being developed at the Idaho National Laboratory. This report discusses the results of initial corrosion testing of this material in simulated in-package environments that could contact the fuel baskets after breach of the waste package outer barrier. The corrosion test matrix was executed using the potentiodynamic and potentiostatic electrochemical test techniques. The alloy performance shows low rates of general corrosion after initial removal of a gadolinium-rich second phase that intersects the surface. The high halide-containing test solutions exhibited greater tendencies toward initiation of crevice corrosion.

  5. Insulating and metallic spin glass in Ni-doped KxFe2-ySe? single crystals

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ryu, Hyejin; Abeykoon, Milinda; Wang, Kefeng; Lei, Hechang; Lazarevic, N.; Warren, J. B.; Bozin, E. S.; Popovic, Z. V.; Petrovic, C.

    2015-05-04

    We report electron doping effects by Ni in KxFe2-?-yNiySe? (0.06 ? y ? 1.44) single crystal alloys. A rich ground state phase diagram is observed. A small amount of Ni (~ 4%) suppressed superconductivity below 1.8 K, inducing insulating spin glass magnetic ground state for higher Ni content. With further Ni substitution, metallic resistivity is restored. For high Ni concentration in the lattice the unit cell symmetry is high symmetry I4/mmm with no phase separation whereas both I4/m + I4/mmm space groups were detected in the phase separated crystals when concentration of Ni more »with the absence of crystalline Fe vacancy order.« less

  6. Observation of Precipitation Evolution in Fe-Ni-Mn-Ti-Al Maraging Steel using Atom Probe Tomography

    SciTech Connect (OSTI)

    Pereloma, E. V.; Stohr, R A; Miller, Michael K; Ringer, S. P.

    2009-01-01

    We describe the full decomposition sequence in an Fe-Ni-Mn-Ti-Al maraging steel during isothermal annealing at 550 C. Following significant pre-precipitation clustering reactions within the supersaturated martensitic solid solution, (Ni,Fe){sub 3}Ti and (Ni,Fe){sub 3}(Al,Mn) precipitates eventually form after isothermal aging for {approx}60 seconds. The morphology of the (Ni,Fe){sub 3}Ti particles changes gradually during aging from predominantly plate-like to rod-like, and, importantly, Mn and Al were observed to segregate to these precipitate/matrix interfaces. The (Ni,Fe){sub 3}(Al,Mn) precipitates occurred at two main locations: uniformly within the matrix and at the periphery of the (Ni,Fe){sub 3}Ti particles. We relate this latter mode of precipitation to the Mn-Al segregation.

  7. Insulating and metallic spin glass in Ni-doped K x Fe 2 - y Se 2 single crystals

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ryu, Hyejin; Abeykoon, Milinda; Wang, Kefeng; Lei, Hechang; Lazarevic, N.; Warren, J. B.; Bozin, E. S.; Popovic, Z. V.; Petrovic, C.

    2015-05-01

    We report electron doping effects by Ni in KxFe2-?-yNiySe?(0.06?y?1.44) single-crystal alloys. A rich ground-state phase diagram is observed. A small amount of Ni (~4%) suppressed superconductivity below 1.8 K, inducing insulating spin-glass magnetic ground state for higher Ni content. With further Ni substitution, metallic resistivity is restored. For high Ni concentration in the lattice the unit cell symmetry is high symmetry I4/mmm with no phase separation whereas both I4/m+I4/mmm space groups were detected in the phase separated crystals when concentration of Ni < Fe. The absence of superconductivity coincides with the absence of crystalline Fe vacancy order.

  8. TSNo s02-roberts104537-O Microscopic and Spectroscopic Speciation of Ni in Soils in the Vicinity of a Ni Refinery.

    E-Print Network [OSTI]

    Sparks, Donald L.

    . Quantification of Ni species in these soils will be presented using a principle component analysis approach. D.R. Authors ROBERTS* UNIV. OF DELAWARE G.S. SENESI UNIV. OF DELAWARE U. KUKIER USDA-ARS, BELTSVILLE, MD R. CHANEY USDA-ARS, BELTSVILLE, MD D.L. SPARKS UNIV. OF DELAWARE For more information, please contact

  9. Symmetry energy and the isoscaling properties of the fragments in multifragmentation of 40Ca+58Ni, 40Ar+58Ni, and 40Ar+58Fe reactions 

    E-Print Network [OSTI]

    Iglio, Jennifer Ann

    2007-09-17

    The symmetry energy and the isoscaling properties of the fragments produced in multifragmentation of 40Ar, 40Ca + 58Fe, 58Ni reactions at 25, 33, 45 and 53 MeV/nucleon were investigated within the framework of a statistical multifragmentation model...

  10. Exploring the influence of transfer channels on fusion reactions: The case of 40 Ca + 58,64 Ni

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bourgin, D.; Courtin, S.; Haas, F.; Goasduff, A.; Stefanini, A. M.; Montagnoli, G.; Montanari, D.; Corradi, L.; Huiming, J.; Scarlassara, F.; et al

    2015-01-29

    Fusion cross sections have been measured in the 40Ca + 58Ni and 40Ca + 64Ni systems at beam energies ranging from Elab = 104.75 MeV to 153.5 MeV using the Laboratori Nazionali di Legnaro electrostatic deflector. Distributions of barriers have been extracted from the experimental data. Preliminary coupled channel calculations were performed and hints of effects of neutron transfers on the fusion below the barrier in the 40Ca + 64Ni are discussed.

  11. Hydrogen Insertion Effects on the Electronic Structure of Equiatomic MgNi Traced by ab initio Calculations.

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Hydrogen Insertion Effects on the Electronic Structure of Equiatomic MgNi Traced by ab initio-xxx / Received October 18, 2012. Doi: 10.5560/ ZNB.2012-xxx For equiatomic MgNi which can be hydrogenated up to the composition MgNiH1.6 at an absorption/desorption temperature of 200 °C, the effects of hydrogen are approached

  12. Effect of temperature and time on properties of Spark Plasma Sintered NiCuZn: Co ferrite

    E-Print Network [OSTI]

    Effect of temperature and time on properties of Spark Plasma Sintered NiCuZn: Co ferrite K. Zehani hundred MHz, and a high resistivity, but the conventional sintering temperature is too high for co. EXPERIMENTAL: Powders of basic oxides Fe2O3, NiO, CuO and ZnO and Co2O3 were used for the preparation of Ni

  13. In Situ Time-Resolved Characterization of Ni-MoO2 Catalysts for the Water-Gas Shift Reaction

    SciTech Connect (OSTI)

    Wen,W.; Calderon, J.; Brito, J.; Marinkovic, N.; Hanson, J.; Rodriquez, J.

    2008-01-01

    Active catalysts for the water-gas shift (WGS, CO + H2O ? H2 + CO2) reaction were synthesized from nickel molybdates ({beta}-NiMoO4 and nH2O{center_dot}NiMoO4) as precursors, and their structural transformations were monitored using in situ time-resolved X-ray diffraction and X-ray absorption near-edge spectroscopy. In general, the nickel molybdates were not stable and underwent partial reduction in the presence of CO or CO/H2O mixtures at high temperatures. The interaction of {beta}-NiMoO4 with the WGS reactants at 500 C led to the formation of a mixture of Ni (24 nm particle size) and MoO2 (10 nm particle size). These Ni-MoO2 systems displayed good catalytic activity at 350, 400, and 500 C. At 350 and 400 C, catalytic tests revealed that the Ni-MoO2 system was much more active than isolated Ni (some activity) or isolated MoO2 (negligible activity). Thus, cooperative interactions between the admetal and oxide support were probably responsible for the high WGS activity of Ni-MoO2. In a second synthetic approach, the NiMoO4 hydrate was reduced to a mixture of metallic Ni, NiO, and amorphous molybdenum oxide by direct reaction with H2 gas at 350 C. In the first pass of the water-gas shift reaction, MoO2 appeared gradually at 500 C with a concurrent increase of the catalytic activity. For these catalysts, the particle size of Ni (4 nm) was much smaller than that of the MoO2 (13 nm). These systems were found to be much more active WGS catalysts than Cu-MoO2, which in turn is superior to commercial low-temperature Cu-ZnO catalysts.

  14. Ternary Electrocatalysts for Oxidizing Ethanol to Carbon Dioxide: Making Ir Capable of Splitting C-C bond

    SciTech Connect (OSTI)

    Li, Meng; Cullen, David A; Sasaki, Kotaro; Marinkovic, N.; More, Karren Leslie; Adzic, Radoslav R.

    2013-01-01

    Splitting the C-C bond is the main obstacle to electroxidation of ethanol (EOR) to CO2. We recently demonstrated that the ternary PtRhSnO2 electrocatalyst can accomplish that reaction at room temperature with Rh having a unique capability to split the C-C bond. In this article we report the finding that Ir can be induced to split the C-C bond as a component of the ternary catalyst. We synthesized, characterized and compared the properties of several ternary electrocatalysts. Carbon-supported nanoparticle (NP) electrocatalysts comprising a SnO2 NP core decorated with multi-metallic nanoislands (MM = PtIr, PtRh, IrRh, PtIrRh) were prepared using a seeded growth approach. An array of characterization techniques were employed to establish the composition and architecture of the synthesized MM /SnO2 NPs, while electrochemical and in situ infrared reflection absorption spectroscopy studies elucidated trends in activity and the nature of the reaction intermediates and products. Both EOR reactivity and selectivity towards CO2 formation of several of these MM /SnO2/C electrocatalysts are significantly higher compared to conventional Pt/C and Pt/SnO2/C catalysts. We demonstrate that the PtIr/SnO2/C catalyst with high Ir content shows outstanding catalytic property with the most negative EOR onset potential and reasonably good selectivity towards ethanol complete oxidation to CO2. PtRh/SnO2/C catalysts with a moderate Rh content exhibit the highest EOR selectivity, as deduced from infrared studies.

  15. IR-Laser Welding and Ablation of Biotissue Stained with Metal Nanoparticles

    E-Print Network [OSTI]

    Lalayan, A A

    2015-01-01

    In the present work we have studied the possibility of laser welding and ablation of biological tissue by the using of spherical metal nanoparticles (NPs) and infrared laser irradiation which spectrally located far from plasmon resonances. YAG:Nd laser with 1064 nm wavelength, 8 ns pulse duration, and operating in transverse electromagnetic modes TEM$_{00}$ was used for the synthesis of metal NPs. The Au,Ti Ni and Cu as well as Au-Ag and Au-Cu hybrid metal NPs were formed in the liquid medium. Effectiveness of laser ablation in the case of the biotissue sample that stained with the metal NPs was approximately on 4-5 times larger than for the native sample. Also the scheme of a laser point welding for the deep-located biotissue layer selectively stained by the metal NPs has been demonstrated.

  16. Metallic glass alloys of Zr, Ti, Cu and Ni

    DOE Patents [OSTI]

    Lin, X.; Peker, A.; Johnson, W.L.

    1997-04-08

    At least quaternary alloys form metallic glass upon cooling below the glass transition temperature at a rate less than 10{sup 3} K/s. Such alloys comprise titanium from 19 to 41 atomic percent, an early transition metal (ETM) from 4 to 21 atomic percent and copper plus a late transition metal (LTM) from 49 to 64 atomic percent. The ETM comprises zirconium and/or hafnium. The LTM comprises cobalt and/or nickel. The composition is further constrained such that the product of the copper plus LTM times the atomic proportion of LTM relative to the copper is from 2 to 14. The atomic percentage of ETM is less than 10 when the atomic percentage of titanium is as high as 41, and may be as large as 21 when the atomic percentage of titanium is as low as 24. Furthermore, when the total of copper and LTM are low, the amount of LTM present must be further limited. Another group of glass forming alloys has the formula (ETM{sub 1{minus}x}Ti{sub x}){sub a} Cu{sub b} (Ni{sub 1{minus}y}Co{sub y}){sub c} wherein x is from 0.1 to 0.3, y{center_dot}c is from 0 to 18, a is from 47 to 67, b is from 8 to 42, and c is from 4 to 37. This definition of the alloys has additional constraints on the range of copper content, b. 2 figs.

  17. A Si Photocathode Protected and Activated with a Catalytic Ti and Ni Composite Film for Solar Hydrogen Production in Water

    E-Print Network [OSTI]

    Lai, Yi-Hsuan; Park, Hyun S.; Zhang, Jenny Z.; Matthews, Peter D.; Wright, Dominic S.; Reisner, Erwin

    2015-02-04

    is consistent with the Ni species having a higher formal oxidation state than TiNicat and similar electronic characteristics to Ni(OH)2 and NiO. The Fourier-transformed Ni extended X-ray absorption fine structure (FT EXAFS) c(k)k2 spectrum of hydro- lyzed Ti... -based O2 evolution electrocata- lysts and photoanodes are only functional in neutral or alkaline conditions. However, operating close to pH neutral conditions can give rise to a pH gradient at the electrode surface.[13] This may lead to a non-optimal fill...

  18. Synthesis of nanocrystalline aluminum matrix composites reinforced with in situ devitrified Al-Ni-La amorphous particles

    E-Print Network [OSTI]

    Zhang, Zhihui H; Han, B Q; Witkin, D; Ajdelsztajn, L; Laverna, E J

    2006-01-01

    metals, RE = rare earth metals) alloys [4] provides a newwith Al and Ni, the rare earth metal La, however, has the

  19. Direct Measurement of the Nanoscale Mechanical Properties of NiTi Shape Memory Gordon A. Shaw1

    E-Print Network [OSTI]

    Crone, Wendy C.

    .035 µm with Nitinol (roughly 49.5 atomic % Ni). Subsequent to annealing, the 10 and 1.7 µm films were

  20. Three-dimensional multimodal imaging and analysis of biphasic microstructure in a Ti-Ni-Sn thermoelectric material

    E-Print Network [OSTI]

    Douglas, Jason E; Echlin, McLean P; Lenthe, William C; Seshadri, Ram; Pollock, Tresa M

    2015-01-01

    microstructure in a Ti–Ni–Sn thermoelectric material Jasonsolid-state option. Thermoelectric materials, which convertin biphasic hH- based thermoelectric materials. This work

  1. On the Relative Utility of Infrared (IR) versus Terahertz (THz) for Optical Sensors

    SciTech Connect (OSTI)

    Johnson, Timothy J.; Valentine, Nancy B.; Gassman, Paul L.; Atkinson, David A.; Sharpe, Steven W.; Williams, Stephen D.

    2007-11-30

    Pacific Northwest National Laboratory (PNNL) has active programs investigating the optical absorption strengths of several types of molecules including toxic industrial chemicals (TICs), microbiological threats such as bacteria, as well as explosives such as RDX, PETN and TNT. While most of our work has centered on the mid-infrared domain (600 to 6,500 cm-1), more recent work has also included work in the far-infrared, also called the terahertz (THz) region (500 to ~8 cm-1). Using Fourier transform infrared spectroscopy, we have been able to compare the relative, and in some cases absolute, IR/THz cross sections of a number of species in the solid and liquid phases. The relative band strengths of a number of species of interest are discussed in terms of both experimental and computational results.

  2. Far-UV to mid-IR properties of nearby radio galaxies

    E-Print Network [OSTI]

    de Ruiter, Hans R; Fanti, Roberto; Fanti, Carla

    2015-01-01

    We investigate whether the far-UV continuum of nearby radio galaxies reveals evidence for the presence of star forming or non-stellar components. If a UV excess due to an extra radiation component exists we compare this with other properties such as radio power, optical spectral type and the strength of the emission lines. We also discuss the possible correlation between the ultra-violet flux, IR properties and central black hole mass. We use two sampes of low luminosity radio galaxies with comparable redshifts ($z measures the excess slope of the UV continuum between 4500 and 2000 \\AA, with respect to the UV radiation produced by the underlying old galaxy component. We find that the UV excess is usually small or absent in low luminosity sources, but sets in abruptly at the transition radio power above which we find mostly FRII sources. $XUV$ beh...

  3. Spitzer IRS Spectra and Envelope Models of Class I Protostars in Taurus

    E-Print Network [OSTI]

    E. Furlan; M. McClure; N. Calvet; L. Hartmann; P. D'Alessio; W. J. Forrest; D. M. Watson; K. I. Uchida; B. Sargent; J. D. Green; T. L. Herter

    2007-11-26

    We present Spitzer Infrared Spectrograph spectra of 28 Class I protostars in the Taurus star-forming region. The 5 to 36 micron spectra reveal excess emission from the inner regions of the envelope and accretion disk surrounding these predecessors of low-mass stars, as well as absorption features due to silicates and ices. Together with shorter- and longer-wavelength data from the literature, we construct spectral energy distributions and fit envelope models to 22 protostars of our sample, most of which are well-constrained due to the availability of the IRS spectra. We infer that the envelopes of the Class I objects in our sample cover a wide range in parameter space, particularly in density and centrifugal radius, implying different initial conditions for the collapse of protostellar cores.

  4. High-resolution IR absorption spectroscopy of polycyclic aromatic hydrocarbons: the realm of anharmonicity

    E-Print Network [OSTI]

    Maltseva, Elena; Candian, Alessandra; Mackie, Cameron J; Huang, Xinchuan; Lee, Timothy J; Tielens, Alexander G G M; Oomens, Jos; Buma, Wybren Jan

    2015-01-01

    We report on an experimental and theoretical investigation of the importance of anharmonicity in the 3 micron CH stretching region of Polycyclic Aromatic Hydrocarbon (PAH) molecules. We present mass-resolved, high-resolution spectra of the gas-phase cold (~4K) linear PAH molecules naphthalene, anthracene, and tetracene. The measured IR spectra show a surprisingly high number of strong vibrational bands. For naphthalene, the observed bands are well separated and limited by the rotational contour, revealing the band symmetries. Comparisons are made to the harmonic and anharmonic approaches of the widely used Gaussian software. We also present calculated spectra of these acenes using the computational program SPECTRO, providing anharmonic predictions enhanced with a Fermi-resonance treatment that utilises intensity redistribution. We demonstrate that the anharmonicity of the investigated acenes is strong, dominated by Fermi resonances between the fundamental and double combination modes, with triple combination ...

  5. Water Absorption from Gas Very Near the Massive Protostar AFGL 2136 IRS 1

    E-Print Network [OSTI]

    Indriolo, Nick; Seifahrt, A; Richter, M J

    2013-01-01

    We present ground-based observations of the nu_1 and nu_3 fundamental bands of H2O toward the massive protostar AFGL 2136 IRS 1, identifying absorption features due to 47 different ro-vibrational transitions between 2.468 micron and 2.561 micron. Analysis of these features indicates the absorption arises in warm (T=506+-25 K), very dense (n(H2)>5*10^9 cm^-3) gas, suggesting an origin close to the central protostar. The total column density of warm water is estimated to be N(H2O)=(1.02+-0.02)*10^19 cm^-2, giving a relative abundance of N(H2O)/N(H2)~10^-4. Our study represents the first extensive use of water vapor absorption lines in the near infrared, and demonstrates the utility of such observations in deriving physical parameters.

  6. Neutronic safety and transient analyses for potential LEU conversion of the IR-8 research reactor.

    SciTech Connect (OSTI)

    Deen, J. R.; Hanan, N. A.; Smith, R. S.; Matos, J. E.; Egorenkov, P. M.; Nasonov, V. A.

    1999-09-27

    Kinetic parameters, isothermal reactivity feedback coefficients and three transients for the IR-8 research reactor cores loaded with either HEU(90%), HEU(36%), or LEU (19.75%) fuel assemblies (FA) were calculated using three dimensional diffusion theory flux solutions, RELAP5/MOD3.2 and PARET. The prompt neutron generation time and effective delayed neutron fractions were calculated for fresh and beginning-of-equilibrium-cycle cores. Isothermal reactivity feedback coefficients were calculated for changes in coolant density, coolant temperature and fuel temperature in fresh and equilibrium cores. These kinetic parameters and reactivity coefficients were used in transient analysis models to predict power histories, and peak fuel, clad and coolant temperatures. The transients modeled were a rapid and slow loss-of-flow, a slow reactivity insertion, and a fast reactivity insertion.

  7. Effect of Field Errors in Muon Collider IR Magnets on Beam Dynamics

    SciTech Connect (OSTI)

    Alexahin, Y.; Gianfelice-Wendt, E.; Kapin, V.V.; /Fermilab

    2012-05-01

    In order to achieve peak luminosity of a Muon Collider (MC) in the 10{sup 35} cm{sup -2}s{sup -1} range very small values of beta-function at the interaction point (IP) are necessary ({beta}* {le} 1 cm) while the distance from IP to the first quadrupole can not be made shorter than {approx}6 m as dictated by the necessity of detector protection from backgrounds. In the result the beta-function at the final focus quadrupoles can reach 100 km making beam dynamics very sensitive to all kind of errors. In the present report we consider the effects on momentum acceptance and dynamic aperture of multipole field errors in the body of IR dipoles as well as of fringe-fields in both dipoles and quadrupoles in the ase of 1.5 TeV (c.o.m.) MC. Analysis shows these effects to be strong but correctable with dedicated multipole correctors.

  8. Regular "Breathing" of Single-Cycle Light Bullets in Mid-IR Filament

    E-Print Network [OSTI]

    Chekalin, S V; Kuznetzov, A V; Dormidonov, A E; Shlenov, S A; Kandidov, V P

    2015-01-01

    Experimental and numerical studies of a temporal evolution of a light bullet formed in isotropic LiF by Mid IR femtosecond pulse (2500 to 3250 nm) of power, slightly exceeding the critical power for self-focusing, are presented. For the first time regular oscillations of the light bullet intensity during its propagation in a filament were registered by investigation of induced color centers in LiF. It was revealed that color centers in a single laser pulse filament have a strictly periodic structure with a length of separate sections about 30 mcm, which increases with a laser pulse wavelength decreasing. It was shown that the origin of light bullet modulation is a periodical change of the light field amplitude of an extremely compressed single cycle wave packet in a filament, due to the difference of the wave packet group velocity and the carrier wave phase velocity.

  9. Express quality analysis of coal concentrates by diffuse reflection IR spectroscopy

    SciTech Connect (OSTI)

    V.N. Egorov; I.I. Mel'nikov; N.A. Tarasov; V.I. Butakova; Y.M. Posokhov [ZAO RMK (Russian Federation)

    2007-07-01

    Ongoing quality monitoring of coal concentrates is important today on account of instability in the raw materials for coking at OAO Magnitogorskii Metallurgicheskii Kombinat (MMK) and the variable composition of the coal batch for enrichment plants. Currently, numerous standardized methods permit the determination of the classificational and quality characteristics of coal and batch. These methods are slow, laborious, and relatively ineffective in industrial conditions. In May 2005, an automated Spektrotest express-analysis system developed by ECCI was installed in the coke laboratory at ZAO RMK in order to determine the quality of the coal concentrate and batch. The basic equipment is an IR spectrometer with a unit for Fourier transformation and a special optical module yielding the reflect on spectra of the pulverized coal. A control station based on a high-speed computer runs an algorithm for information analysis and storage and for printing out the test protocol. The Spektrotest system includes complex algorithms and software specially developed at ECCI.

  10. Anisotropic intermediate valence in Yb2M3Ga9 (M = Rh, Ir)

    SciTech Connect (OSTI)

    Christianson, A.D.; Lawrence, J.M.; Lobos, A.M.; Aligia, A.A.; Bauer, E.D.; Moreno, N.O.; Booth, C.H.; Goremychkin, E.A.; Sarrao, J.L.; Thompson, J.D.; Batista, C.D.; Trouw, F.R.; Hehlen, M.P.

    2005-04-26

    The intermediate valence compounds Yb{sub 2}M{sub 3}Ga{sub 9} (M = Rh, Ir) exhibit an anisotropic magnetic susceptibility. We report measurements of the temperature dependence of the 4f occupation number, n{sub f}(T), for Yb{sub 2}M{sub 3}Ga{sub 9} as well as the magnetic inelastic neutron scattering spectrum S{sub mag}({Delta}E) at 12 and 300 K for Yb{sub 2}Rh{sub 3}Ga{sub 9}. Both n{sub f}(T) and S{sub mag}({Delta}E) were calculated for the Anderson impurity model with crystal field terms within an approach based on the non-crossing approximation. These results corroborate the importance of crystal field effects in these materials; they also suggest that Anderson lattice effects are important to the physics of Yb{sub 2}M{sub 3}Ga{sub 9}.

  11. Interaction of mineral surfaces with simple organci molecules by diffuse reflectance IR spectroscopy (DRIFT)

    SciTech Connect (OSTI)

    Joan Thomas; Michael Kelley

    2007-06-18

    Diffuse reflectance Fourier-transform infrared spectroscopy (DRIFTS) was used to characterize multi-layers of lysine, glutamic acid and salicylic acid on ?-alumina and kaolinite surfaces. The results agreed well with those previously obtained by ATR-IR in aqueous media where available, indicating that DRIFT may be regarded as effectively an in-situ spectroscopy for these materials. In the case of salicylic acid adsorption onto ?-alumina, DRIFTS was used to identify monolayer coverage and to detect molecules down to coverage of 3% of a monolayer. The spectroscopic results as to coverage were confirmed by analysis of the solutions used for treatment. The spectra obtained allowed identification of changes in the bonding environment with increasing surface coverage. DRIFTS, offers several advantages in terms of materials, experimental technique and data treatment, motivating further investigations.

  12. Production of Ni-Cr-Ti-natural fibres composite and investigation of mechanical properties

    SciTech Connect (OSTI)

    Pesmen, G.; Erol, A.

    2015-03-30

    Intermetallic materials such as Ni{sub 2}Ti, Cr{sub 2}Ti are among advanced technology materials that have outstanding mechanical and physical properties for high temperature applications. Especially creep resistance, low density and high hardness properties stand out in such intermetallics. The microstructure, mechanical properties of (%50Ni-%48Cr-%2Ti)-%10Naturel Fibres and (%64Ni-%32Cr-%4Ti)-%10Naturel Fibres powders were investigated using specimens produced by tube furnace sintering at 1000-1200-1400°C temperature. A composite consisting of ternary additions, a metallic phase, Ti,Cr and Ni have been prepared under Ar shroud and then tube furnace sintered. XRD, SEM (Scanning Electron Microscope), were investigated to characterize the properties of the specimens. Experimental results carried out for composition (%64Ni-%32Cr-%4Ti)-%10Naturel at 1400°C suggest that the best properties as 112.09HV and 5,422g/cm{sup 3} density were obtained at 1400°C.

  13. Effect of Surface Termination on the Electonic Properties of LaNiO? Films

    SciTech Connect (OSTI)

    Kumah, Divine P.; Malashevich, Andrei; Disa, Ankit S.; Arena, Dario A.; Walker, Fred J.; Ismail-Beigi, Sohrab; Ahn, Charles H.

    2014-11-06

    The electronic and structural properties of thin LaNiO? films grown by using molecular beam epitaxy are studied as a function of the net ionic charge of the surface terminating layer. We demonstrate that electronic transport in nickelate heterostructures can be manipulated through changes in the surface termination due to a strong coupling of the surface electrostatic properties to the structural properties of the Ni—O bonds that govern electronic conduction. We observe experimentally and from first-principles theory an asymmetric response of the structural properties of the films to the sign of the surface charge, which results from a strong interplay between electrostatic and mechanical boundary conditions governing the system. The structural response results in ionic buckling in the near-surface NiO? planes for films terminated with negatively charged NiO? and bulklike NiO? planes for films terminated with positively charged LaO planes. The ability to modify transport properties by the deposition of a single atomic layer can be used as a guiding principle for nanoscale device fabrication.

  14. Effect of Surface Termination on the Electonic Properties of LaNiO? Films

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kumah, Divine P.; Malashevich, Andrei; Disa, Ankit S.; Arena, Dario A.; Walker, Fred J.; Ismail-Beigi, Sohrab; Ahn, Charles H.

    2014-11-06

    The electronic and structural properties of thin LaNiO? films grown by using molecular beam epitaxy are studied as a function of the net ionic charge of the surface terminating layer. We demonstrate that electronic transport in nickelate heterostructures can be manipulated through changes in the surface termination due to a strong coupling of the surface electrostatic properties to the structural properties of the Ni—O bonds that govern electronic conduction. We observe experimentally and from first-principles theory an asymmetric response of the structural properties of the films to the sign of the surface charge, which results from a strong interplay betweenmore »electrostatic and mechanical boundary conditions governing the system. The structural response results in ionic buckling in the near-surface NiO? planes for films terminated with negatively charged NiO? and bulklike NiO? planes for films terminated with positively charged LaO planes. The ability to modify transport properties by the deposition of a single atomic layer can be used as a guiding principle for nanoscale device fabrication.« less

  15. Conceptual design study of Nb3Sn low-beta quadrupoles for 2nd generation LHC IRs

    SciTech Connect (OSTI)

    Alexander V Zlobin et al.

    2002-10-22

    Conceptual designs of 90-mm aperture high-gradient quadrupoles based on the Nb{sub 3}Sn superconductor, are being developed at Fermilab for possible 2nd generation IRs with the similar optics as in the current low-beta insertions. Magnet designs and results of magnetic, mechanical, thermal and quench protection analysis for these magnets are presented and discussed.

  16. Review of exposure limits and experimental data for corneal and lenticular damage from short pulsed UV and IR laser radiation

    E-Print Network [OSTI]

    at the international level by ICNIRP the International Commission on Non-Ionizing Radiation Protection.1,2 Other Commission on Non-Ionizing Radiation Protection are compared to relevant experimental animal injury data UV and IR laser radiation Karl Schulmeistera Austrian Research Centers, A-2444 Seibersdorf, Austria

  17. On-chip methane sensing by near-IR absorption signatures in a photonic crystal slot waveguide

    E-Print Network [OSTI]

    Chen, Ray

    On-chip methane sensing by near-IR absorption signatures in a photonic crystal slot waveguide Wei­Lambert law for the detection of methane gas. The device combines slow light in a PC waveguide with high absorption path length. A methane concentration of 100 ppm (parts per million) in nitrogen was measured

  18. Transposing Molecular Fluorescent Switches into the Near-IR: Development of Luminogenic Reporter Substrates for Redox Metabolism

    E-Print Network [OSTI]

    Turro, Nicholas J.

    Transposing Molecular Fluorescent Switches into the Near-IR: Development of Luminogenic Reporter communicate the development of a NIR luminescent redox switch, based on a Nd(III) complex, that serves to afford a good luminescent switch.9 Since the sensitization of lanthanide metals is assumed to occur via

  19. Photometric and Near-IR Spectroscopic Observations of a D-type Asteroid, 773 Irmintraud, by SUBARU / IRCS

    E-Print Network [OSTI]

    Hiroi, Takahiro

    / IRCS A. Kanno (Univ. of Tokyo), T. Hiroi (Brown Univ.), R. Nakamura(NASDA), M. Abe(ISAS), M. Ishiguro-IR photometric and spectroscopic observations of 773 Irmintraud by SUBARU/IRCS on February 23rd, 2002 (UT). We to the lightcurve and the rotation period, we calibrated the data taken with SUBARU/IRCS by removing the effect

  20. Crystalline ZnMgSe:Cr2+: a new material for active elements of tunable IR-lasers

    E-Print Network [OSTI]

    Yu. A. Zagoruiko; N. O. Kovalenko; O. A. Fedorenko; V. A. Khristyan

    2008-07-01

    Obtained is a new thermostable material for active elements of tunable IR-lasers - Zn1-xMgxSe:Cr2+ single crystals. The position of the absorption band of Cr2+ ions in wurtzite-type Zn0.8Mg0.2Se matrix is established.

  1. Electrophoresis 1997, IR, 1259-1313 Predicted versus observed E. c d i proteins 1259 Andrew J. Link'*

    E-Print Network [OSTI]

    Church, George M.

    Electrophoresis 1997, IR, 1259-1313 Predicted versus observed E. c d i proteins 1259 Andrew J. Link Medical School, Boston, MA, USA Comparing the predicted and observed properties of proteins encoded proteins for their mature N-termini, in vivo abundances, isoelectric points, molecular masses, and cellular

  2. Hydrogen Bond Lifetimes and Energetics for Solute/Solvent Complexes Studied with 2D-IR Vibrational Echo Spectroscopy

    E-Print Network [OSTI]

    Fayer, Michael D.

    Hydrogen Bond Lifetimes and Energetics for Solute/Solvent Complexes Studied with 2D-IR Vibrational@stanford.edu Abstract: Weak hydrogen-bonded solute/solvent complexes are studied with ultrafast two the dissociation and formation rates of the hydrogen-bonded complexes. The dissociation rates of the weak hydrogen

  3. Solute-Solvent Complex Kinetics and Thermodynamics Probed by 2D-IR Vibrational Echo Chemical Exchange Spectroscopy

    E-Print Network [OSTI]

    Fayer, Michael D.

    Solute-Solvent Complex Kinetics and Thermodynamics Probed by 2D-IR Vibrational Echo Chemical, 2008 The formation and dissociation kinetics of a series of triethylsilanol/solvent weakly hydrogen with previous observations on eight phenol/solvent complexes with enthalpies of formation from -0.6 to -2.5 kcal

  4. IR laser ablative desulfurization of poly(1,4-phenylene sulfide) Sardar M.A. Durani a

    E-Print Network [OSTI]

    Masoudi, Husain M.

    IR laser ablative desulfurization of poly(1,4-phenylene sulfide) Sardar M.A. Durani a , Ehsan E,* a Center for Applied Physical Sciences, Research Institute, King Fahd University of Petroleum and Minerals similar to those in PPS. The PLAD of PPS thus represents a unique example of the desulfurization of S

  5. Ultrafast UV Pump/IR Probe Studies of C-H Activation in Linear, Cyclic, and Aryl Hydrocarbons

    E-Print Network [OSTI]

    Harris, Charles B.

    Ultrafast UV Pump/IR Probe Studies of C-H Activation in Linear, Cyclic, and Aryl Hydrocarbons, cyclic, and aromatic hydrocarbon solvents on a femtosecond to microsecond time scale. These results have revealed that the structure of the hydrocarbon substrate affects the final C-H bond activation step, which

  6. Micro-PIXE measurement of Ni distribution over supported nickel oxide catalyst

    SciTech Connect (OSTI)

    Ahmed, M.; Rahman, A.; Nickel, J. [King Fahd Univ., Dhahran (Saudi Arabia)] [and others

    1994-12-31

    Supported nickel oxide catalysts have a wide range of applications in petrochemical industry. This work reports the results of a micro-PIXE measurement of Ni distribution in a supported nickel oxide catalyst over individual silica base particles, 60-200 {mu}m in size. These catalysts were synthesized with 1% and 5% then calcined at 400 {degrees}C. A 2.5 MeV proton microbeam was used to scan the samples of individual grains. Two dimensional distribution maps of Ni and Si have been measured. This paper discusses the important effects of the process of calcination on the distribution of Ni. The effects of different nickel loading and other synthesis conditions will also be discussed.

  7. Mass Measurements of Proton-Rich Nuclei Fe-50 and Ni-54 

    E-Print Network [OSTI]

    Tribble, Robert E.; Cossairt, J. D.; May, D. P.; Kenefick, R. A.

    1977-01-01

    to different kinematic shifts for the 'He' s from the light (A=12) and heavy (A =54, 58) mass targets. Calibrated 'He spectra from Fe and "Ni are shown in Fig. 1. From previous ('He, 'He) measurements, the cross sections to "Fe and ' Ni were expected... are TABLE I. Properties of Fe and 5 Ni. All entries are in MeV. Nuclide Expt. Mass excess Garvey and Kelson ~ Coulomb energy ~ip ~2p Coulomb energy 50Fe -34.48 +0.06 -39.21 +0.05 -34.50 39.27 -34.472 +0.013 -39.296 +0.013 4.16 6.24 8.93 +0.06 3...

  8. Surface roughness and interface width scaling of magnetron sputter deposited Ni/Ti multilayers

    SciTech Connect (OSTI)

    Maidul Haque, S.; Biswas, A.; Tokas, R. B.; Bhattacharyya, D.; Sahoo, N. K.; Bhattacharya, Debarati

    2013-09-14

    Using an indigenously built r.f. magnetron sputtering system, several single layer Ti and Ni films have been deposited at varying deposition conditions. All the samples have been characterized by Grazing Incidence X-ray Reflectivity (GIXR) and Atomic Force Microscopy to estimate their thickness, density, and roughness and a power law dependence of the surface roughness on the film thickness has been established. Subsequently, at optimized deposition condition of Ti and Ni, four Ni/Ti multilayers of 11-layer, 21-layer, 31-layer, and 51-layer having different bilayer thickness have been deposited. The multilayer samples have been characterized by GIXR and neutron reflectivity measurements and the experimental data have been fitted assuming an appropriate sample structure. A power law correlation between the interface width and bilayer thickness has been observed for the multilayer samples, which was explained in the light of alternate roughening/smoothening of multilayers and assuming that at the interface the growth “restarts” every time.

  9. Quantifying Uncertainty in Chemical Systems Modeling M.T. Reagan1, H.N. Najm1, P.P. Pebay1, O.M. Knio2 and R.G. Ghanem2

    E-Print Network [OSTI]

    Frey, Pascal

    Quantifying Uncertainty in Chemical Systems Modeling M.T. Reagan1, H.N. Najm1, P.P. P´ebay1, O The Johns Hopkins University, Baltimore, MD 21218, USA Abstract. This study compares two techniques of Chemical Kinetics 1. Introduction Chemical kinetics computations require the specification of a number

  10. A new A&P Food Market in Mt. Kisco, New York, is enjoying annual energy cost savings of nearly $130,000 with the installation of an integrated microturbine power system

    E-Print Network [OSTI]

    Pennycook, Steve

    Background A new A&P Food Market in Mt. Kisco, New York, is enjoying annual energy cost savings, heating and power solutions, was installed in 2005 in the 57,000- square-foot facility. The New York supermarket was the first U.S. customer to take delivery of the new system. The PureComfort system is designed

  11. Visualizing the Surface Infrastructure Used to Move 2 MtCO2/year from the Dakota Gasification Company to the Weyburn CO2 Enhanced Oil Recovery Project: Version of July 1, 2009

    SciTech Connect (OSTI)

    Dooley, James J.

    2009-07-09

    Google Earth Pro has been employed to create an interactive flyover of the world’s largest operational carbon dioxide capture and storage project. The visualization focuses on the transport and storage of 2 MtCO2/year which is captured from the Dakota Gasification Facility (Beula, North Dakota) and transported 205 miles and injected into the Weyburn oil field in Southeastern Saskatchewan.

  12. Comparison of junction temperature evaluations in a power IGBT module using an IR camera and three thermo-sensitive electrical parameters

    E-Print Network [OSTI]

    and electrical methods. The main optical methods are local infrared sensors [3,4], optical fibers [5], infraredComparison of junction temperature evaluations in a power IGBT module using an IR camera and three information of the actual chip temperature distribution. In this paper, we propose to use infrared (IR

  13. Zelftest chemie voor 1 Ba Bio-ir, Chemie, Fysica en sterrenkunde Voor meer informatie: contacteer csb.etterbeek@vub.ac.be

    E-Print Network [OSTI]

    Einmahl, Uwe

    Zelftest chemie voor 1 Ba Bio-ir, Chemie, Fysica en sterrenkunde Voor meer informatie: contacteer opgenomen in het bijhorend overzicht van de verwachte voorkennis chemie. 1. Elementaire chemie en chemisch, whisky, fruitsap met pulp, keukenzout #12;Zelftest chemie voor 1 Ba Bio-ir, Chemie, Fysica en

  14. PHYSICAL REVIEW B 88, 144102 (2013) Mechanism of the CaIrO3 post-perovskite phase transition under pressure

    E-Print Network [OSTI]

    Henkelman, Graeme

    2013-01-01

    PHYSICAL REVIEW B 88, 144102 (2013) Mechanism of the CaIrO3 post-perovskite phase transition under that the perovskite to post-perovskite phase transformation in CaIrO3 occurs more readily at room temperature when mantle, MgSiO3 perovskite (Pv), was recently found to transform into a post-perovskite (pPv) structure

  15. Symmetry Analysis for Tetrahedrane Tetrahedrane, C4H4, belongs to the Td point group. Use group theory to predict the number of IR and Raman

    E-Print Network [OSTI]

    Rioux, Frank

    Symmetry Analysis for Tetrahedrane Tetrahedrane, C4H4, belongs to the Td point group. Use group have three IR active modes (3T2) and seven Raman active modes (2A1 + 2E + 3T2). Two of the IR modes

  16. Characterization and corrosion behaviour of CoNi alloys obtained by mechanical alloying

    SciTech Connect (OSTI)

    Olvera, S. [Instituto Politécnico Nacional, ESIQIE, Departamento de Ingeniería en Metalurgia y Materiales, México, D. F. (Mexico); Universidad Autónoma de Madrid, Facultad de Ciencias, Departamento de Química-Física Aplicada, 28049 Madrid (Spain); Sánchez-Marcos, J. [Universidad Autónoma de Madrid, Facultad de Ciencias, Departamento de Química-Física Aplicada, 28049 Madrid (Spain); Palomares, F.J. [Instituto de Ciencia de Materiales de Madrid, ICMM-CSIC, Cantoblanco, 28049 Madrid (Spain); Salas, E. [Spline Spanish CRG Beamline at the European Synchrotron Radiation Facilities, ESRF, BP 220-38043, Grenoble Cedex (France); Arce, E.M. [Instituto Politécnico Nacional, ESIQIE, Departamento de Ingeniería en Metalurgia y Materiales, México, D. F. (Mexico); Herrasti, P., E-mail: pilar.herrasti@uam.es [Universidad Autónoma de Madrid, Facultad de Ciencias, Departamento de Química-Física Aplicada, 28049 Madrid (Spain)

    2014-07-01

    CoNi alloys including Co{sub 30}Ni{sub 70}, Co{sub 50}Ni{sub 50} and Co{sub 70}Ni{sub 30} were prepared via mechanical alloying using Co and Ni powders. The crystallinity and short-range order were studied using X-ray diffraction and X-ray absorption spectroscopy. The results show that the milling process increases the number of vacancies, especially around the Co atoms, while the milling time decreases the crystalline size and enhances the crystallinity. X-ray photoelectron spectroscopy was used to characterise the chemical composition of the samples surface. The magnetic properties were analysed using zero-field cooling, field cooling and a magnetic hysteresis loops. The magnetic saturation moment is approximately 1.05 ?{sub B}/atom; this value decreases with the mechanical alloying time, and it is proportional to the cobalt concentration. The polarization and impedance curves in different media (NaCl, H{sub 2}SO{sub 4} and NaOH) showed similar corrosion resistance values. The corrosion resistance increased in the order NaCl, H{sub 2}SO{sub 4} and NaOH. A good passivation layer was formed in NaOH due to the cobalt and nickel oxides on the particle surfaces. - Highlights: • Ni{sub x}Co{sub 100-x} alloys were synthesized by mechanical alloying • Milling time decrease size and enhances crystallinity. • Oxygen is not present in a significant percentage in bulk but is detected on the surface. • Magnetic saturation moment is 1.05 mB/atom and decrease with mechanical allowing time • Corrosion resistance is higher in NaOH than in NaCl or HCl solutions.

  17. [TiII] and [NiII] emission from the strontium filament of eta Carinae

    E-Print Network [OSTI]

    M. A. Bautista; H. Hartman; T. R. Gull; N. Smith; K. Lodders

    2006-06-12

    We study the nature of the [TiII] and [NiII] emission from the so-called strontium filament found in the ejecta of eta Carinae. To this purpose we employ multilevel models of the TiII and NiII systems which are used to investigate the physical condition of the filament and the excitation mechanisms of the observed lines. For the TiII ion, for which no atomic data was previously available, we carry out ab initio calculations of radiative transition rates and electron impact excitation rate coefficients. It is found that the observed spectrum is consistent with the lines being excited in a mostly neutral region with an electron density of the order of $10^7$ cm$^{-3}$ and a temperature around 6000 K. In analyzing three observations with different slit orientations recorded between March~2000 and November~2001 we find line ratios that change among various observations, in a way consistent with changes of up to an order of magnitude in the strength of the continuum radiation field. These changes result from different samplings of the extended filament, due to the different slit orientations used for each observation, and yield clues on the spatial extent and optical depth of the filament. The observed emission indicates a large Ti/Ni abundance ratio relative to solar abundances. It is suggested that the observed high Ti/Ni ratio in gas is caused by dust-gas fractionation processes and does not reflect the absolute Ti/Ni ratio in the ejecta of \\etacar. We study the condensation chemistry of Ti, Ni and Fe within the filament and suggest that the observed gas phase overabundance of Ti

  18. Preparation and characterization of nanodiamond cores coated with a thin Ni-Zn-P alloy film

    SciTech Connect (OSTI)

    Wang Rui; Ye Weichun; Ma Chuanli; Wang Chunming

    2008-02-15

    Nanodiamond cores coated with a thin Ni-Zn-P alloy film were prepared by an electroless deposition method under the conditions of tin chloride sensitization and palladium chloride activation. The prepared materials were analyzed by Fourier transform infrared (FTIR) spectrometry and X-ray diffraction (XRD). The nanostructure of the materials was then characterized by transmission electron microscopy (TEM). The alloy film composition was characterized by Energy Dispersive X-ray (EDX) analysis. The results indicated the approximate composition 49.84%Ni-37.29%Zn-12.88%P was obtained.

  19. KADoNiS-$p$: The astrophysical $p$-process database

    E-Print Network [OSTI]

    T. Szücs; I. Dillmann; R. Plag; Zs. Fülöp

    2015-03-02

    The KADoNiS-$p$ project is an online database for cross sections relevant to the $p$-process. All existing experimental data was collected and reviewed. With this contribution a user-friendly database using the KADoNiS (Karlsruhe Astrophysical Database of Nucleosynthesis in Stars) framework is launched, including all available experimental data from (p,$\\gamma$), (p,n), (p,$\\alpha$), ($\\alpha$,$\\gamma$), ($\\alpha$,n) and ($\\alpha$,p) reactions in or close to the respective Gamow window with cut-off date of August 2012 (www.kadonis.org/pprocess).

  20. Contact-induced spin polarization in BNNT(CNT)/TM (TM=Co, Ni) nanocomposites

    SciTech Connect (OSTI)

    Kuzubov, Alexander A.; Kovaleva, Evgenia A. Avramov, Paul; Kuklin, Artem V.; Mikhaleva, Natalya S.; Tomilin, Felix N.; Sakai, Seiji; Entani, Shiro; Matsumoto, Yoshihiro; Naramoto, Hiroshi

    2014-08-28

    The interaction between carbon and BN nanotubes (NT) and transition metal Co and Ni supports was studied using electronic structure calculations. Several configurations of interfaces were considered, and the most stable ones were used for electronic structure analysis. All NT/Co interfaces were found to be more energetically favorable than NT/Ni, and conductive carbon nanotubes demonstrate slightly stronger bonding than semiconducting ones. The presence of contact-induced spin polarization was established for all nanocomposites. It was found that the contact-induced polarization of BNNT leads to the appearance of local conductivity in the vicinity of the interface while the rest of the nanotube lattice remains to be insulating.