Sample records for ions miec oxides

  1. AP-XPS Measures MIEC Oxides in Action

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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  2. AP-XPS Measures MIEC Oxides in Action

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    H2O electrolysis and H2 oxidation, dense thin-film CeO2-x electrodes with Au current collectors were deposited onto YSZ electrolytes with a thin-film Pt counter electrode. The...

  3. AP-XPS Measures MIEC Oxides in Action

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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  4. AP-XPS Measures MIEC Oxides in Action

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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  5. AP-XPS Measures MIEC Oxides in Action

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItemResearchSOLICITATIONIMODI FICATION OF CONTRACT 1 OTATI OEP AEGraphic of09 I NAP-XPS

  6. AP-XPS Measures MIEC Oxides in Action

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032)8Li (59AJ76) (See theDoctoral20ALSNewstt^ \ #ANUDlSiTM-40AP-XPS

  7. AP-XPS Measures MIEC Oxides in Action

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032)8Li (59AJ76) (See theDoctoral20ALSNewstt^ \ #ANUDlSiTM-40AP-XPSAP-XPS

  8. AP-XPS Measures MIEC Oxides in Action

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032)8Li (59AJ76) (See theDoctoral20ALSNewstt^ \

  9. AP-XPS Measures MIEC Oxides in Action

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del(ANL-IN-03-032)8Li (59AJ76) (See theDoctoral20ALSNewstt^ \AP-XPS Measures MIECAP-XPS

  10. Graphene oxide oxidizes stannous ions to synthesize tin sulfidegraphene nanocomposites with small crystal size for high performance lithium ion

    E-Print Network [OSTI]

    Cao, Guozhong

    Graphene oxide oxidizes stannous ions to synthesize tin sulfide­graphene nanocomposites with small September 2012 DOI: 10.1039/c2jm34864k This study reports a novel strategy of preparing graphene composites by employing graphene oxide as precursor and oxidizer. It is demonstrated that graphene oxide can oxidize

  11. Finding Room for Improvement in Transition Metal Oxides Cathodes for Lithium-ion Batteries

    E-Print Network [OSTI]

    Kam, Kinson

    2012-01-01T23:59:59.000Z

    Metal Oxides Cathodes for Lithium-ion Batteries Kinson C.storage using rechargeable lithium-ion batteries has become

  12. Finding Room for Improvement in Transition Metal Oxides Cathodes for Lithium-ion Batteries

    E-Print Network [OSTI]

    Kam, Kinson

    2012-01-01T23:59:59.000Z

    Oxides Cathodes for Lithium-ion Batteries Kinson C. Kam andusing rechargeable lithium-ion batteries has become an

  13. THE ORIGIN OF UNUSUAL DISLOCATION STRUCTURES OBSERVED IN ION-THINNED NICKEL OXIDE

    E-Print Network [OSTI]

    Little, J.A.

    2013-01-01T23:59:59.000Z

    OBSERVED IN ION-THINNED NICKEL OXIDE J. A. Little, H.OBSERVED IN ION-THINNED NICKEL OXIDE By J. A. Little t , H.thinned single crystals of nickel oxide were examined and

  14. Perchlorate Degradation Using Partially Oxidized Titanium Ions and Ion Exchange Membrane Hybrid System

    E-Print Network [OSTI]

    Park, Sung Hyuk

    2011-08-08T23:59:59.000Z

    Perchlorate has entered human and environmental food chains and has received a great deal of attention because of its toxicity to humans. In this study, chemical degradation of perchlorate was investigated using partially oxidized titanium ions (Ti2...

  15. Coaxial Si/anodic titanium oxide/Si nanotube arrays for lithium-ion battery anode

    E-Print Network [OSTI]

    Zhou, Chongwu

    Nano Res 1 Coaxial Si/anodic titanium oxide/Si nanotube arrays for lithium-ion battery anode Titanium Oxide / Si Nanotube Arrays for Lithium-ion Battery Anode JiepengRong,,§Xin Fang Oxide / Si Nanotube Arrays for Lithium-ion Battery Anode Jiepeng Rong,1,§ Xin Fang,1,§ Mingyuan Ge,1

  16. Method for providing oxygen ion vacancies in lanthanide oxides

    DOE Patents [OSTI]

    Kay, D. Alan R. (4305 Lakeshore Rd., Burlington, CA); Wilson, William G. (820 Harden Dr., Pittsburgh, PA 15229)

    1989-12-05T23:59:59.000Z

    A method for desulfurization of fuel gases resulting from the incomplete combustion of sulfur containing hydrocarbons whereby the gases are treated with lanthanide oxides containing large numbers of oxygen-ion vacancies providing ionic porosity which enhances the ability of the lanthanide oxides to react more rapidly and completely with the sulfur in the fuel gases whereby the sulfur in such gases is reduced to low levels suitable for fuels for firing into boilers of power plants generating electricity with steam turbine driven generators, gas turbines, fuel cells and precursors for liquid fuels such as methanol and the like.

  17. Ion irradiation of Fe-Fe oxide core-shell nanocluster films:...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    irradiation of Fe-Fe oxide core-shell nanocluster films: Effect of interface on stability of magnetic properties. Ion irradiation of Fe-Fe oxide core-shell nanocluster films:...

  18. Modeling and simulation of Li-ion conduction in poly(ethylene oxide)

    E-Print Network [OSTI]

    Averbuch, Amir

    rechargeable batteries for consumer portable applications. A lithium-ion battery employs a metal oxide/discharge voltage depends on the current and resistance of all battery components. In most solid-state lithium-ion of Computational Physics 227 (2007) 1162­1175 www.elsevier.com/locate/jcp #12;1. Introduction Lithium and lithium-ion

  19. Stochastic model of lithium ion conduction in poly,,ethylene oxide... L. Gitelman,1

    E-Print Network [OSTI]

    Averbuch, Amir

    Stochastic model of lithium ion conduction in poly,,ethylene oxide... L. Gitelman,1 A. Averbuch,2,a of LiI salt. The current is due to diffusion and electric interactions with a permanent external field, the PEO charges, and ion-ion interactions. Potential barriers are created in the PEO by loops in structure

  20. Microstructural effects on capacity-rate performance of vanadium oxide cathodes in lithium-ion batteries

    E-Print Network [OSTI]

    Davis, Robin M. (Robin Manes)

    2005-01-01T23:59:59.000Z

    Vanadium oxide thin film cathodes were analyzed to determine whether smaller average grain size and/or a narrower average grain size distribution affects the capacity-rate performance in lithium-ion batteries. Vanadium ...

  1. Methane Oxidation to Methanol without CO2 Emission: Catalysis by Atomic Negative Ions

    E-Print Network [OSTI]

    Tesfamichael, Aron; Felfli, Zineb; Msezane, Alfred Z

    2014-01-01T23:59:59.000Z

    The catalytic activities of the atomic Y-, Ru-, At-, In-, Pd-, Ag-, Pt-, and Os- ions have been investigated theoretically using the atomic Au- ion as the benchmark for the selective partial oxidation of methane to methanol without CO2 emission. Dispersion-corrected density-functional theory has been used for the investigation. From the energy barrier calculations and the thermodynamics of the reactions, we conclude that the catalytic effect of the atomic Ag-, At-, Ru-, and Os- ions is higher than that of the atomic Au- ion catalysis of CH4 conversion to methanol. By controlling the temperature around 290K (Os-), 300K (Ag-), 310K (At-), 320K (Ru-) and 325K (Au-) methane can be completely oxidized to methanol without the emission of CO2. We conclude by recommending the investigation of the catalytic activities of combinations of the above negative ions for significant enhancement of the selective partial oxidation of methane to methanol.

  2. Ion-modulated nonlinear electronic transport in carbon nanotube bundle/RbAg{sub 4}I{sub 5} thin film composite nanostructures

    SciTech Connect (OSTI)

    Sun, Jia-Lin [State Key Laboratory of Low-Dimensional Quantum Physics, Department of Physics, Tsinghua University, Beijing 100084 (China); Collaborative Innovation Center of Quantum Matter, Beijing (China); Zhang, Wei, E-mail: zhang-wei@iapcm.ac.cn [Institute of Applied Physics and Computational Mathematics, P.O. Box 8009(28), Beijing 100088 (China); Wei, Jinquan [Key Laboratory for Advanced Materials Processing Technology of Education Ministry, Department of Mechanical Engineering, Tsinghua University, Beijing 100084 (China); Gu, Bingfu [State Key Laboratory of Low-Dimensional Quantum Physics, Department of Physics, Tsinghua University, Beijing 100084 (China)

    2014-01-28T23:59:59.000Z

    We have explored the ion-modulated electronic transport properties of mixed ionic-electronic conductor (MIEC) composite nanostructures made of superionic conductor RbAg{sub 4}I{sub 5} films and carbon nanotube (CNT) bundle spiderwebs. Our experimental and theoretical studies indicate that the formation of ion-electron bound states (IEBSs) leads to strong ion-electron interference effect and interesting electronic transport of CNT, such as nonlinear current-voltage (I–V) characteristics and novel temperature dependence of the current. With increasing temperature, the hybrid nanostructures show rich phases with different dependence of current on temperature, which is related to the structural phase transition of RbAg{sub 4}I{sub 5} and the transition of dissociation of IEBSs. The ion-modulation of the electric conductivity in such MIEC composite nanostructures with great tunability has been used to design new ionic-electronic composite nano-devices with function like field effect transistor.

  3. Cathode and electrolyte materials for solid oxide fuel cells and ion transport membranes

    DOE Patents [OSTI]

    Jacobson, Allan J; Wang, Shuangyan; Kim, Gun Tae

    2014-01-28T23:59:59.000Z

    Novel cathode, electrolyte and oxygen separation materials are disclosed that operate at intermediate temperatures for use in solid oxide fuel cells and ion transport membranes based on oxides with perovskite related structures and an ordered arrangement of A site cations. The materials have significantly faster oxygen kinetics than in corresponding disordered perovskites.

  4. Atomic-Layer-Deposition Oxide Nanoglue for Sodium Ion Batteries Xiaogang Han,,

    E-Print Network [OSTI]

    Li, Teng

    Atomic-Layer-Deposition Oxide Nanoglue for Sodium Ion Batteries Xiaogang Han,, Yang Liu,, Zheng Jia ABSTRACT: Atomic-layer-deposition (ALD) coatings have been increasingly used to improve battery performance/discharging. Battery tests in coin-cells further showed the ALD-Al2O3 coating remarkably boosts the cycling performance

  5. In situ analyses on negative ions in the indium-gallium-zinc oxide sputtering process

    SciTech Connect (OSTI)

    Jia, Junjun; Torigoshi, Yoshifumi; Shigesato, Yuzo [Graduate School of Science and Engineering, Aoyama Gakuin University, 5-10-1 Fuchinobe, Chuo, Sagamihara, Kanagawa 252-5258 (Japan)

    2013-07-01T23:59:59.000Z

    The origin of negative ions in the dc magnetron sputtering process using a ceramic indium-gallium-zinc oxide target has been investigated by in situ analyses. The observed negative ions are mainly O{sup -} with energies corresponding to the target voltage, which originates from the target and barely from the reactive gas (O{sub 2}). Dissociation of ZnO{sup -}, GaO{sup -}, ZnO{sub 2}{sup -}, and GaO{sub 2}{sup -} radicals also contributes to the total negative ion flux. Furthermore, we find that some sputtering parameters, such as the type of sputtering gas (Ar or Kr), sputtering power, total gas pressure, and magnetic field strength at the target surface, can be used to control the energy distribution of the O{sup -} ion flux.

  6. Oxide shell reduction and magnetic property changes in core-shell Fe nanoclusters under ion irradiation

    SciTech Connect (OSTI)

    Sundararajan, Jennifer A.; Kaur, Maninder; Qiang, You, E-mail: youqiang@uidaho.edu [Department of Physics, University of Idaho, Moscow, Idaho 83844 (United States); Jiang, Weilin [Pacific Northwest National Laboratory, P.O. Box 999, Richland, Washington 99352 (United States); McCloy, John S. [School of Mechanical and Materials Engineering, Washington State University, Pullman, Washington 99164 (United States)

    2014-05-07T23:59:59.000Z

    Ion irradiation effects are studied on the Fe-based core-shell nanocluster (NC) films with core as Fe and shell as Fe{sub 3}O{sub 4}/Fe{sub 3}N. These NC films were deposited on Si substrates to thickness of ?0.5 ?m using a NC deposition system. The films were irradiated at room temperature with 5.5?MeV Si{sup 2+} ions to ion fluences of 10{sup 15} and 10{sup 16} ions/cm{sup 2}. It is found that the irradiation induces grain growth, Fe valence reduction in the shell, and crystallization or growth of Fe{sub 3}N. The film retained its Fe-core and its ferromagnetic properties after irradiation. The nature and mechanism of oxide shell reduction and composition dependence after irradiation were studied by synthesizing additional NC films of Fe{sub 3}O{sub 4} and FeO?+?Fe{sub 3}N and irradiating them under the same conditions. The presence of nanocrystalline Fe is found to be a major factor for the oxide shell reduction. The surface morphologies of these films show dramatic changes in the microstructures due to cluster growth and agglomeration as a result of ion irradiation.

  7. Surface nanostructuring by ion-induced localized plasma expansion in zinc oxide

    SciTech Connect (OSTI)

    El-Said, A. S., E-mail: elsaid@kfupm.edu.sa, E-mail: a.s.el-said@hzdr.de [Physics Department, King Fahd University of Petroleum and Minerals, Dhahran 31261 (Saudi Arabia); Institute of Ion Beam Physics and Materials Research, Helmholtz-Zentrum Dresden-Rossendorf (HZDR), 01328 Dresden (Germany); Physics Department, Faculty of Science, Mansoura University, 35516 Mansoura (Egypt); Moslem, W. M. [Department of Physics, Faculty of Science, Port Said University, Port Said 42521 (Egypt); Centre for Theoretical Physics, British University in Egypt (BUE), El-Shorouk City, Cairo (Egypt); Djebli, M. [Theoretical Physics Laboratory, Faculty of Physics USTHB, B.P. 32 Bab Ezzour, 16079 Algiers (Algeria)

    2014-06-09T23:59:59.000Z

    Creation of hillock-like nanostructures on the surface of zinc oxide single crystals by irradiation with slow highly charged ions is reported. At constant kinetic energy, the nanostructures were only observed after irradiation with ions of potential energies above a threshold between 19.1?keV and 23.3?keV. The size of the nanostructures increases as a function of potential energy. A plasma expansion approach is used to explain the nanostructures creation. The calculations showed that the surface nanostructures became taller with the increase of ionic temperature. The influence of charged cluster formation and the relevance of their polarity are discussed.

  8. Cation-substituted spinel oxide and oxyfluoride cathodes for lithium ion batteries

    DOE Patents [OSTI]

    Manthiram, Arumugam; Choi, Wongchang

    2014-05-13T23:59:59.000Z

    The present invention includes compositions and methods of making cation-substituted and fluorine-substituted spinel cathode compositions by firing a LiMn.sub.2-y-zLi.sub.yM.sub.zO.sub.4 oxide with NH.sub.4HF.sub.2 at low temperatures of between about 300 and 700.degree. C. for 2 to 8 hours and a .eta. of more than 0 and less than about 0.50, mixed two-phase compositions consisting of a spinel cathode and a layered oxide cathode, and coupling them with unmodified or surface modified graphite anodes in lithium ion cells.

  9. Electronic structure of nitinol surfaces oxidized by low-energy ion bombardment

    SciTech Connect (OSTI)

    Petravic, M., E-mail: mpetravic@phy.uniri.hr; Varasanec, M.; Peter, R.; Kavre, I. [Department of Physics and Center for Micro and Nano Sciences and Technologies, University of Rijeka, 51000 Rijeka (Croatia); Metikos-Hukovic, M. [Department of Electrochemistry, Faculty of Chemical Engineering and Technology, University of Zagreb, 10000 Zagreb (Croatia); Yang, Y.-W. [National Synchrotron Radiation Research Center, Hsinchu 30077, Taiwan (China)

    2014-06-28T23:59:59.000Z

    We have studied the electronic structure of nitinol exposed to low-energy oxygen-ion bombardment, using x-ray photoemission spectroscopy (XPS) and near-edge x-ray absorption fine structure (NEXAFS) spectroscopy. XPS spectra reveal a gradual transformation of nitinol surfaces into TiO{sub 2} with increased dose of implanted oxygen. No oxidation of Ni atoms has been detected. NEXAFS spectra around O K-edge and Ti L{sub 2,3}-edge, reflecting the element-specific partial density of empty electronic states, exhibit features, which can be attributed to the creation of molecular orbitals, crystal field splitting, and the absence of long-range order, characteristic of the amorphous TiO{sub 2}. Based on these results, we discuss the oxidation kinetics of nitinol under low-energy oxygen-ion bombardment.

  10. Electrochemical investigation of polyhalide ion oxidation-reduction on carbon nanotube electrodes for redox flow batteries

    SciTech Connect (OSTI)

    Shao, Yuyan; Engelhard, Mark H.; Lin, Yuehe

    2009-10-01T23:59:59.000Z

    Polyhalide ions (Br-/BrCl2-) are an important redox couple for redox flow batteries. The oxidation-reduction behavior of polyhalide ions on a carbon nanotube (CNT) electrode has been investigated with cyclic voltammetry and electrochemical impedance spectroscopy. The onset oxidation potential of Br-/BrCl2- is negatively shifted by >100 mV, and the redox current peaks are greatly enhanced on a CNT electrode compared with that on the most widely-used graphite electrode. The reaction resistance of the redox couple (Br-/BrCl2-) is decreased on a CNT electrode. The redox reversibility is increased on a CNT electrode even though it still needs further improvement. CNT is a promising electrode material for redox flow batteries.

  11. Cation-substituted spinel oxide and oxyfluoride cathodes for lithium ion batteries

    DOE Patents [OSTI]

    Manthiram, Arumugam; Choi, Wonchang

    2010-05-18T23:59:59.000Z

    The present invention includes compositions and methods of making cation-substituted and fluorine-substituted spinel cathode compositions by firing a LiMn2-y-zLiyMzO4 oxide with NH4HF2 at low temperatures of between about 300 and 700.degree. C. for 2 to 8 hours and a .eta. of more than 0 and less than about 0.50, mixed two-phase compositions consisting of a spinel cathode and a layered oxide cathode, and coupling them with unmodified or surface modified graphite anodes in lithium ion cells.

  12. Graphene-oxide-coated LiNi0.5Mn1.5O4 as high voltage cathode for lithium ion batteries with high energy

    E-Print Network [OSTI]

    Zhou, Chongwu

    Graphene-oxide-coated LiNi0.5Mn1.5O4 as high voltage cathode for lithium ion batteries with high Since Sony rst commercialized lithium ion batteries in the early 1990s, the market for lithium ion of the great success of lithium ion battery technology developed for portable electronic devices, higher

  13. Amorphous Nb/Fe-oxide ion-storage films for counter electrode applications in electrochromic devices

    SciTech Connect (OSTI)

    Orel, B.; Macek, M.; Lavrencic-Stangar, U. [National Inst. of Chemistry, Ljubljana (Slovenia); Pihlar, B. [Univ. of Ljubljana (Slovenia). Faculty of Chemistry

    1998-05-01T23:59:59.000Z

    The electrochromic properties of mixed Nb/Fe-oxide films with amorphous structure which were prepared via the sol-gel route were determined. Films with Nb/Fe molar concentration ratios 0.2:1, 0.4:1, and 1:1 exhibit ion-storage capacities up to 18 mC/cm{sup 2} depending on Nb/Fe molar ratio. Electrochromically films behave as optically passive electrodes with a coloration efficiency of nearly zero at {lambda} > 480 nm, while at shorter wavelengths a relatively strong anodic coloring was observed, yielding negative coloration efficiencies up to {minus}20 cm{sup 2}/C. Coloring/bleaching changes of films are correlated with the ex situ IR spectroscopic measurements of charged/discharged films showing distortions of the film structure with Li{sup +} ion insertion/extraction reactions. Electrochemical stability of Nb/Fe (0.4:1)-oxide films was tested up to 2,000 cycles in a sol-gel electrochromic device consisting of sol-gel-derived WO{sub 3} films and hybrid organic/inorganic ionic conductor with ionic conductivity of about 10{sup {minus}4} S/cm serving for lamination of the electrodes.

  14. Nanostructured bilayered vanadium oxide electrodes for rechargeable sodium-ion batteries.

    SciTech Connect (OSTI)

    Tepavcevic, S.; Xiong, H.; Stamenkovic, V.R.; Zuo, X.; Balasubramanian, M.; Prakapenka, V.B.; Johnson, C.S.; Rajh, T. (Accelerator Systems Division (APS)); ( CNM); ( MSD); (University of Chicago)

    2012-01-01T23:59:59.000Z

    Tailoring nanoarchitecture of materials offers unprecedented opportunities in utilization of their functional properties. Nanostructures of vanadium oxide, synthesized by electrochemical deposition, are studied as a cathode material for rechargeable Na-ion batteries. Ex situ and in situ synchrotron characterizations revealed the presence of an electrochemically responsive bilayered structure with adjustable intralayer spacing that accommodates intercalation of Na{sup +} ions. Sodium intake induces organization of overall structure with appearance of both long- and short-range order, while deintercalation is accompanied with the loss of long-range order, whereas short-range order is preserved. Nanostructured electrodes achieve theoretical reversible capacity for Na{sub 2}V{sub 2}O{sub 5} stoichiometry of 250 mAh/g. The stability evaluation during charge-discharge cycles at room temperature revealed an efficient 3 V cathode material with superb performance: energy density of {approx}760 Wh/kg and power density of 1200 W/kg. These results demonstrate feasibility of development of the ambient temperature Na-ion rechargeable batteries by employment of electrodes with tailored nanoarchitectures.

  15. DEVELOPMENT OF WET-OXIDATION TREATMENT SYSTEM FOR FILTER BACKWASH SLUDGE AND ION EXCHANGE RESINS

    SciTech Connect (OSTI)

    Miyamoto, T.; Motoyama, M.; Shibuya, M.; Wada, H.; Yamazaki, K.

    2003-02-27T23:59:59.000Z

    Decomposition of organic compounds contained in filter backwash sludge and spent ion exchange resins is considered effective in reducing the waste volume. A system using the wet-oxidation process has been studied for the treatment of the sludge and resins stored at Tsuruga Power Station Unit 1, 357MWe BWR, owned by The Japan Atomic Power Company. Compared with various processes for treating sludge and resin, the wet-oxidation system is rather simple and the process conditions are mild. Waste samples collected from storage tanks were processed by wet-oxidation and appropriate decomposition of the organic compounds was verified. After the decomposition the residue can be solidified with cement or bitumen for final disposal. When compared with direct solidification without decomposition, the number of waste packages can be reduced by a factor of a few dozens for the sludge and three for the resin. Additional measures for conditioning secondary waste products have also been studied, and their applicability to the Tsuruga Power Station was verified. Some of the conditions studied were specific to the Tsuruga Power Station, but it is expected that the system will provide an effective solution for sludge and resin treatment at other NPPs.

  16. Solid oxide fuel cells having porous cathodes infiltrated with oxygen-reducing catalysts

    DOE Patents [OSTI]

    Liu, Meilin; Liu, Ze; Liu, Mingfei; Nie, Lifang; Mebane, David Spencer; Wilson, Lane Curtis; Surdoval, Wayne

    2014-08-12T23:59:59.000Z

    Solid-oxide fuel cells include an electrolyte and an anode electrically coupled to a first surface of the electrolyte. A cathode is provided, which is electrically coupled to a second surface of the electrolyte. The cathode includes a porous backbone having a porosity in a range from about 20% to about 70%. The porous backbone contains a mixed ionic-electronic conductor (MIEC) of a first material infiltrated with an oxygen-reducing catalyst of a second material different from the first material.

  17. Waste minimization pretreatment via pyrolysis and oxidative pyrolysis of organic ion exchange resin

    SciTech Connect (OSTI)

    Chun, U.K.; Choi, K.; Yang, K.H.; Park, J.K.; Song, M.J. [Korea Electric Power Research Inst., Taejon (Korea, Republic of). Nuclear Power Generation Lab.] [Korea Electric Power Research Inst., Taejon (Korea, Republic of). Nuclear Power Generation Lab.

    1998-12-31T23:59:59.000Z

    Pyrolysis and/or oxidative pyrolysis of organic ion exchange resins and other combustible waste may be effective pretreatment processes before vitrification. Three different methods were examined with the TGA to pretreat the resins: pyrolysis; oxidative pyrolysis; and oxidative pyrolyses of ash remaining after the pyrolysis of resin. The latter two methods were found to provide better volume reduction than the pyrolysis-only process. Between the two types of resins, cationic and anionic, the cationic exchange resin was less volatile. Pyrolysis and oxidative pyrolysis of mixed resin (50% cation and 50% anion by wt.) showed volatilization at the temperatures where volatilization was observed for each of the separate resins. Because of certain limitations of the commercial TGA, tube furnace experiments were performed, generally, to examine the pyrolysis of larger quantities of cationic, anionic, and mixed resin, and to examine off-gas characteristics. The cationic resin-only and anionic resin-only gravimetric results showed good agreement with the smaller-scale TGA results. SEM pictures of the different variants of the resin (cationic, anionic, and mixed) show a different morphology for each. Off-gas data showed the presence of H{sub 2}S, SO{sub 2}, CO, and NO during the pyrolysis of cationic resin. CO was observed during the pyrolysis of anionic resin. The mixed resin trials showed the presence of the gases approximately at the temperatures where the gases would evolve if the results of the two different resins (cationic and anionic) were superimposed. However, the amount of hydrogen sulfide relative to the sulfur dioxide was found to increase significantly compared to the results of the cationic resin-only trials.

  18. Finding Room for Improvement in Transition Metal Oxides Cathodes for Lithium-ion Batteries

    E-Print Network [OSTI]

    Kam, Kinson

    2012-01-01T23:59:59.000Z

    Cathodes for Lithium-ion Batteries Kinson C. Kam and Marcarechargeable lithium-ion batteries has become an integral

  19. Electronic transport in Lithium Nickel Manganese Oxide, a high-voltage cathode material for Lithium-Ion batteries

    E-Print Network [OSTI]

    Ransil, Alan Patrick Adams

    2013-01-01T23:59:59.000Z

    Potential routes by which the energy densities of lithium-ion batteries may be improved abound. However, the introduction of Lithium Nickel Manganese Oxide (LixNi1i/2Mn3/2O4, or LNMO) as a positive electrode material appears ...

  20. Performance improvement of gadolinium oxide resistive random access memory treated by hydrogen plasma immersion ion implantation

    SciTech Connect (OSTI)

    Wang, Jer-Chyi, E-mail: jcwang@mail.cgu.edu.tw; Hsu, Chih-Hsien; Ye, Yu-Ren [Department of Electronic Engineering, Chang Gung University, Kweishan 333, Taoyuan, Taiwan (China); Ai, Chi-Fong; Tsai, Wen-Fa [Institute of Nuclear Energy Research, Atomic Energy Council, Longtan 325, Taoyuan, Taiwan (China)

    2014-03-15T23:59:59.000Z

    Characteristics improvement of gadolinium oxide (Gd{sub x}O{sub y}) resistive random access memories (RRAMs) treated by hydrogen plasma immersion ion implantation (PIII) was investigated. With the hydrogen PIII treatment, the Gd{sub x}O{sub y} RRAMs exhibited low set/reset voltages and a high resistance ratio, which were attributed to the enhanced movement of oxygen ions within the Gd{sub x}O{sub y} films and the increased Schottky barrier height at Pt/Gd{sub x}O{sub y} interface, respectively. The resistive switching mechanism of Gd{sub x}O{sub y} RRAMs was dominated by Schottky emission, as proved by the area dependence of the resistance in the low resistance state. After the hydrogen PIII treatment, a retention time of more than 10{sup 4}?s was achieved at an elevated measurement temperature. In addition, a stable cycling endurance with the resistance ratio of more than three orders of magnitude of the Gd{sub x}O{sub y} RRAMs can be obtained.

  1. ReaxFF Reactive Force Field for Solid Oxide Fuel Cell Systems with Application to Oxygen Ion Transport in Yttria-Stabilized Zirconia

    E-Print Network [OSTI]

    Goddard III, William A.

    through yttria-stabilized zirconia (YSZ) solid oxide fuel cell (SOFC) membranes. All parameters for ReaxReaxFF Reactive Force Field for Solid Oxide Fuel Cell Systems with Application to Oxygen Ion temperature, leading to applications as oxygen sensors and as membranes for high temperature solid oxide fuel

  2. Observations of Oxygen Ion Behavior in the Lithium-Based Electrolytic Reduction of Uranium Oxide

    SciTech Connect (OSTI)

    Steven D. Herrmann; Shelly X. Li; Brenda E. Serrano-Rodriguez

    2009-09-01T23:59:59.000Z

    Parametric studies were performed on a lithium-based electrolytic reduction process at bench-scale to investigate the behavior of oxygen ions in the reduction of uranium oxide for various electrochemical cell configurations. Specifically, a series of eight electrolytic reduction runs was performed in a common salt bath of LiCl – 1 wt% Li2O. The variable parameters included fuel basket containment material (i.e., stainless steel wire mesh and sintered stainless steel) and applied electrical charge (i.e., 75 – 150% of the theoretical charge for complete reduction of uranium oxide in a basket to uranium metal). Samples of the molten salt electrolyte were taken at regular intervals throughout each run and analyzed to produce a time plot of Li2O concentrations in the bulk salt over the course of the runs. Following each run, the fuel basket was sectioned and the fuel was removed. Samples of the fuel were analyzed for the extent of uranium oxide reduction to metal and for the concentration of salt constituents, i.e., LiCl and Li2O. Extents of uranium oxide reduction ranged from 43 – 70% in stainless steel wire mesh baskets and 8 – 33 % in sintered stainless steel baskets. The concentrations of Li2O in the salt phase of the fuel product from the stainless steel wire mesh baskets ranged from 6.2 – 9.2 wt%, while those for the sintered stainless steel baskets ranged from 26 – 46 wt%. Another series of tests was performed to investigate the dissolution of Li2O in LiCl at 650 °C across various cathode containment materials (i.e., stainless steel wire mesh, sintered stainless steel and porous magnesia) and configurations (i.e., stationary and rotating cylindrical baskets). Dissolution of identical loadings of Li2O particulate reached equilibrium within one hour for stationary stainless steel wire mesh baskets, while the same took several hours for sintered stainless steel and porous magnesia baskets. Rotation of an annular cylindrical basket of stainless steel wire mesh accelerated the Li2O dissolution rate by more than a factor of six.

  3. Improved layered mixed transition metal oxides for Li-ion batteries

    E-Print Network [OSTI]

    Doeff, Marca M.

    2010-01-01T23:59:59.000Z

    M n , ^ for Advanced Lithium-Ion Batteries," J. Electrochem.of LiCoi/3Nii/ Mn 02 for lithium-ion batteries," Chem.Mni/ 0 for advanced lithium-ion batteries," J. Power

  4. Improved layered mixed transition metal oxides for Li-ion batteries

    E-Print Network [OSTI]

    Doeff, Marca M.

    2010-01-01T23:59:59.000Z

    for rechargeable lithium batteries," Science 311(5763), 977-^ for Advanced Lithium-Ion Batteries," J. Electrochem. Soc.02 for lithium-ion batteries," Chem. Lett. , [3] Yabuuchi,

  5. Solubility of, and hydrogen ion adsorption on, some metal oxides in aqueous solutions to high temperatures

    SciTech Connect (OSTI)

    Palmer, D.A.; Benezeth, P.; Wesolowski, D.J.; Anovitz, L.M. [Oak Ridge National Lab., TN (United States); Machesky, M.L. [Illinois State Water Survey, Champaign, IL (United States); Hayashi, Ken-ichiro [Tohoku Univ., Sendai (Japan). Inst. of Mineralogy, Petrology and Economic Geology; Hyde, K.E. [State Univ. of New York, Oswego, NY (United States). Dept. of Chemistry

    1997-08-01T23:59:59.000Z

    Solubility of boehmite (AlOOH), ferrous hydroxide (Fe(OH)2)/magnetite (Fe3O4), zincite (ZnO), and brucite (Mg(OH)2) were measured over a range of temperatures (AlOOH, 100-290 C; Fe(OH)2/Fe3O4, 100-250 C; ZnO, 50-290 C; Mg(OH)2, 60-200 C) using in situ pH measurements. A hydrogen-electrode concentration cell was used; the pH range depended on the oxide. The solubility results for boehmite mainly demonstrate the method viability, while those for zincite are mainly restricted to mildly acidic to neutral pH where Zn{sup 2+} predominates in solution. The magnetite (presumably coated with Fe(OH)2) solubilities extend from pHs > 5 and, because of relevance to water/steam cycles of power plants, are compared in detail with previous studies. The same cell was used to investigate the surface adsorption-desorption thermodynamics of H ions on rutile (TiO2) and zincite to 290 C. Behavior of pH at zero-point-of-charge as function of temperature and application of the Stern-3-layer model were determined for this solid. The zincite study is still incomplete; preliminary results show trends that can be rationalized only qualitatively now with the zero- point-of-charge being apparently affected by hydration of the surface in basic solutions and specific adsorption of Na ions under the same conditions.

  6. Improved layered mixed transition metal oxides for Li-ion batteries

    SciTech Connect (OSTI)

    Doeff, Marca M.; Conry, Thomas; Wilcox, James

    2010-03-05T23:59:59.000Z

    Recent work in our laboratory has been directed towards development of mixed layered transition metal oxides with general composition Li[Ni, Co, M, Mn]O2 (M=Al, Ti) for Li ion battery cathodes. Compounds such as Li[Ni1/3Co1/3Mn1/3]O2 (often called NMCs) are currently being commercialized for use in consumer electronic batteries, but the high cobalt content makes them too expensive for vehicular applications such as electric vehicles (EV), plug-in hybrid electric vehicles (PHEVs), or hybrid electric vehicles (HEVs). To reduce materials costs, we have explored partial or full substitution of Co with Al, Ti, and Fe. Fe substitution generally decreases capacity and results in poorer rate and cycling behavior. Interestingly, low levels of substitution with Al or Ti improve aspects of performance with minimal impact on energy densities, for some formulations. High levels of Al substitution compromise specific capacity, however, so further improvements require that the Ni and Mn content be increased and Co correspondingly decreased. Low levels of Al or Ti substitution can then be used offset negative effects induced by the higher Ni content. The structural and electrochemical characterization of substituted NMCs is presented in this paper.

  7. X-ray absorption spectroscopy study of the local structure of heavy metal ions incorporated into electrodeposited nickel oxide films

    SciTech Connect (OSTI)

    Balasubramanian, M.; Melendres, C.A. [Argonne National Lab., IL (United States). Chemical Technology Div.] [Argonne National Lab., IL (United States). Chemical Technology Div.; Mansour, A.N. [Naval Surface Warfare Center, Bethesda, MD (United States). Carderock Div.] [Naval Surface Warfare Center, Bethesda, MD (United States). Carderock Div.

    1999-02-01T23:59:59.000Z

    The incorporation of heavy metal ions into simulated corrosion films has been investigated using spectroscopic and electrochemical techniques. The films were formed by electrodeposition of the appropriate oxide (hydroxide) onto a graphite substrate. Synchrotron X-ray absorption spectroscopy (XAS) was used to determine the structure and composition of the host oxide film, as well as the local structure of the impurity ion. Results on the incorporation of Ce and Sr into surface films of Ni(OH){sub 2} and NiOOH are reported. Cathodically deposited Ni(OH){sub 2} was found to be mainly in the alpha form while anodically prepared NiOOH showed the presence of Ni{sup +2} and Ni{sup +4}. Cerium incorporated into Ni(OH){sub 2} exists as mixed Ce{sup +3} and Ce{sup +4} phases; a Ce{sup +4} species was found when Ce was codeposited with NiOOH. The structure of the Ce{sup +4} phase in anodic films appears similar to a Ce(OH){sub 4} standard. However, XAS, X-ray diffraction, and laser Raman measurements indicate that the latter chemical formulation is probably incorrect and that the material is really a disordered form of hydrous cerium oxide. The local structure of this material is similar to CeO{sub 2} but has much higher structural disorder. The significance of this finding on the question of the structure of Ce-based corrosion inhibitors in aluminum oxide films is pointed out. Moreover, the authors found it possible to form pure Ce oxide (hydroxide) films on graphite by both cathodic and anodic electrodeposition; their structures have also been elucidated. Strontium incorporated into nickel oxide films consists of Sr{sup +2} which is coordinated to oxygen atoms and is likely to exist as small domains of coprecipitated material.

  8. In-Situ Transmission Electron Microscopy Probing of Native Oxide and Artificial Layers on Silicon Nanoparticles for Lithium Ion Batteries

    SciTech Connect (OSTI)

    He, Yang; Piper, Daniela M.; Gu, Meng; Travis, Jonathan J.; George, Steven M.; Lee, Se-Hee; Genc, Arda; Pullan, Lee; Liu, Jun; Mao, Scott X.; Zhang, Jiguang; Ban, Chunmei; Wang, Chong M.

    2014-10-27T23:59:59.000Z

    Surface modification of silicon nanoparticle via molecular layer deposition (MLD) has been recently proved to be an effective way for dramatically enhancing the cyclic performance in lithium ion batteries. However, the fundamental mechanism as how this thin layer of coating function is not known, which is even complicated by the inevitable presence of native oxide of several nanometers on the silicon nanoparticle. Using in-situ TEM, we probed in detail the structural and chemical evolution of both uncoated and coated silicon particles upon cyclic lithiation/delithation. We discovered that upon initial lithiation, the native oxide layer converts to crystalline Li2O islands, which essentially increases the impedance on the particle, resulting in ineffective lithiation/delithiation, and therefore low coulombic efficiency. In contrast, the alucone MLD coated particles show extremely fast, thorough and highly reversible lithiation behaviors, which are clarified to be associated with the mechanical flexibility and fast Li+/e- conductivity of the alucone coating. Surprisingly, the alucone MLD coating process chemically changes the silicon surface, essentially removing the native oxide layer and therefore mitigates side reaction and detrimental effects of the native oxide. This study provides a vivid picture of how the MLD coating works to enhance the coulombic efficiency and preserve capacity and clarifies the role of the native oxide on silicon nanoparticles during cyclic lithiation and delithiation. More broadly, this work also demonstrated that the effect of the subtle chemical modification of the surface during the coating process may be of equal importance as the coating layer itself.

  9. Facile synthesis of nanostructured vanadium oxide as cathode materials for efficient Li-ion batteries

    E-Print Network [OSTI]

    Cao, Guozhong

    -ion batteries Yanyi Liu,a Evan Uchaker,a Nan Zhou,ab Jiangang Li,ac Qifeng Zhanga and Guozhong Cao*a Received 23 and VO2 (B) nanorods were tested as active cathode materials for Li-ion batteries. The V2O5 sheet for efficient Li-ion batteries. Introduction The expansion and demands for energy use in the past several

  10. Improved layered mixed transition metal oxides for Li-ion batteries

    E-Print Network [OSTI]

    Doeff, Marca M.

    2010-01-01T23:59:59.000Z

    for rechargeable lithium batteries," Science 311 (5763),for rechargeable lithium batteries," Science 311(5763), 977-M n , ^ for Advanced Lithium-Ion Batteries," J. Electrochem.

  11. Depth distribution of lithium in oxidized binary Al-Li alloys determined by secondary ion mass spectrometry and neutron depth profiling

    SciTech Connect (OSTI)

    Soni, K.K. (Univ. of Chicago, IL (United States)); Williams, D.B. (Lehigh Univ., Bethlehem, PA (United States)); Newbury, D.E.; Chi, P.; Downing, R.G.; Lamaza, G. (National Inst. of Standards and Technology, Gaithersburg, MD (United States))

    1993-01-01T23:59:59.000Z

    Oxidation of binary Al-Li alloys during short exposures at 530 C and long exposures at 200 C was studied with regard to the Li distribution. Secondary ion mass spectrometry (SIMS) and neutron depth profiling (NDP) were used to obtain quantitative Li depth profiles across the surface oxide layer and the underlying alloy. The underlying alloy was depleted in Li as a result of oxidation at 530 and 200 C. The SIMS and NDP results showed good mutual agreement and were used to evaluate the oxide thickness, the Li concentration at the oxide-ally interface, and the mass balance between oxide and alloy. The Li depletion profiles in the alloy were also calculated using the interdiffusion coefficients reported in the literature and compared with the measured profiles; the two profiles differed at 530 C but showed good agreement at 200 C.

  12. Preparation of anionic clay-birnessite manganese oxide composites by interlayer oxidation of oxalate ions by permanganate

    SciTech Connect (OSTI)

    Arulraj, James [Materials Research Group, Department of Chemistry, St. Joseph's College, 36 Langford Road, Bangalore 560 027 (India)] [Materials Research Group, Department of Chemistry, St. Joseph's College, 36 Langford Road, Bangalore 560 027 (India); Rajamathi, Michael, E-mail: mikerajamathi@rediffmail.com [Materials Research Group, Department of Chemistry, St. Joseph's College, 36 Langford Road, Bangalore 560 027 (India)] [Materials Research Group, Department of Chemistry, St. Joseph's College, 36 Langford Road, Bangalore 560 027 (India)

    2013-02-15T23:59:59.000Z

    Oxalate intercalated anionic clay-like nickel zinc hydroxysalt was obtained starting from nickel zinc hydroxyacetate, Ni{sub 3}Zn{sub 2}(OH){sub 8}(OAc){sub 2}{center_dot}2H{sub 2}O, by anion exchange. The intercalated oxalate species was reacted with potassium permanganate in such a way that the layered manganese oxide formed was within the interlayer region of the anionic clay resulting in a layered composite in which the negative charges on the birnessite type manganese oxide layers compensate the positive charges on the anionic clay layers. Birnessite to anionic clay ratio could be varied by varying the reaction time or the amount of potassium permanganate used. - Graphical abstract: Nickel zinc hydroxyoxalate was reacted with potassium permanganate to get nickel zinc hydroxide birnessite composites in which the positive charges on the hydroxide layers are neutralized by the negative charges on birnessite layers. Highlights: Black-Right-Pointing-Pointer Anionic and cationic layered solid composites prepared. Black-Right-Pointing-Pointer Ni-Zn hydroxyoxalate reacted with KMnO{sub 4} to deposit MnO{sub 2} in the interlayer. Black-Right-Pointing-Pointer Birnessite layers coexist with anionic clay layers in the composites. Black-Right-Pointing-Pointer Birnessite/anionic clay ratio controlled by amount of KMnO{sub 4} used and reaction time.

  13. Ab initio screening of lithium diffusion rates in transition metal oxide cathodes for lithium ion batteries

    E-Print Network [OSTI]

    Moore, Charles J. (Charles Jacob)

    2012-01-01T23:59:59.000Z

    A screening metric for diffusion limitations in lithium ion battery cathodes is derived using transition state theory and common materials properties. The metric relies on net activation barrier for lithium diffusion. ...

  14. A relation between surface oxide and oxygen-defect complexes in solid-phase epitaxial Si regrown from ion-beam-amorphized Si layers

    SciTech Connect (OSTI)

    Petkov, Mihail P. [Department of Physics, Washington State University, Pullman, Washington 99163-2814 (United States)] [Department of Physics, Washington State University, Pullman, Washington 99163-2814 (United States); Chen, Claudine M. [Thomas J. Watson Laboratory of Applied Physics, California Institute of Technology, Pasadena, California 91125 (United States)] [Thomas J. Watson Laboratory of Applied Physics, California Institute of Technology, Pasadena, California 91125 (United States); Atwater, Harry A. [Thomas J. Watson Laboratory of Applied Physics, California Institute of Technology, Pasadena, California 91125 (United States)] [Thomas J. Watson Laboratory of Applied Physics, California Institute of Technology, Pasadena, California 91125 (United States); Rassiga, Stefano [Department of Physics, Washington State University, Pullman, Washington 99163-2814 (United States)] [Department of Physics, Washington State University, Pullman, Washington 99163-2814 (United States); Lynn, Kelvin G. [Department of Physics, Washington State University, Pullman, Washington 99163-2814 (United States)] [Department of Physics, Washington State University, Pullman, Washington 99163-2814 (United States)

    2000-03-13T23:59:59.000Z

    We present a direct evidence that ion implantation through thin ({<=}5 nm) surface oxide layers is a source of O impurities, which form O-defect complexes during thermal treatment. The impurity-defect complexes are identified by correlating the results from positron annihilation spectroscopy, secondary-ion mass spectroscopy, and Monte Carlo simulations. The O atoms are introduced in the bulk by multiple recoil implantation by the primary ions. The signatures of large V{sub m}O{sub n} formations are observed at 800 degree sign C, which implies the existence of smaller species at lower temperatures. (c) 2000 American Institute of Physics.

  15. Magnetization measurements and XMCD studies on ion irradiated...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    measurements and XMCD studies on ion irradiated iron oxide and core-shell ironiron-oxide nanomaterials. Magnetization measurements and XMCD studies on ion irradiated iron oxide...

  16. Stability of nanoclusters in 14YWT oxide dispersion strengthened steel under heavy ion-irradiation by atom probe tomography

    SciTech Connect (OSTI)

    Jianchao He; Farong Wan; Kumar Sridharan; Todd R. Allen; A. Certain; V. Shutthanandan; Y.Q. Wu

    2014-12-01T23:59:59.000Z

    14YWT oxide dispersion strengthened (ODS) ferritic steel was irradiated with of 5 MeV Ni2+ ions, at 300 C, 450 C, and 600 C to a damage level of 100 dpa. The stability of Ti–Y–O nanoclusters was investigated by applying atom probe tomography (APT) in voltage mode, of the samples before and after irradiations. The average size and number density of the nanoclusters was determined using the maximum separation method. These techniques allowed for the imaging of nanoclusters to sizes well below the resolution limit of conventional transmission electron microscopy techniques. The most significant changes were observed for samples irradiated at 300 C where the size (average Guinier radius) and number density of nanoclusters were observed to decrease from 1.1 nm to 0.8 nm and 12 1023 to 3.6 1023, respectively. In this study, the nanoclusters are more stable at higher temperature.

  17. Stability Of Nanoclusters In 14YWT Oxide Dispersion Strengthened Steel Under Heavy Ion-irradiation By Atom Probe Tomography

    SciTech Connect (OSTI)

    He, Jianchao; Wan, F.; Sridharan, Kumar; Allen, Todd R.; Certain, Alicia G.; Shutthanandan, V.; Wu, Yaqiao

    2014-12-01T23:59:59.000Z

    14YWT oxide dispersion strengthened (ODS) ferritic steel was irradiated with of 5 MeV Ni2+ ions, at 300 °C, 450 °C, and 600 °C to a damage level of 100 dpa. The stability of Ti–Y–O nanoclusters was investigated by applying atom probe tomography (APT) in voltage mode, of the samples before and after irradiations. The average size and number density of the nanoclusters was determined using the maximum separation method. These techniques allowed for the imaging of nanoclusters to sizes well below the resolution limit of conventional transmission electron microscopy techniques. The most significant changes were observed for samples irradiated at 300 °C where the size (average Guinier radius) and number density of nanoclusters were observed to decrease from 1.1 nm to 0.8 nm and 12 × 1023 to 3.6 × 1023, respectively. In this study, the nanoclusters are more stable at higher temperature.

  18. Noncentrosymmetric salt inclusion oxides: Role of salt lattices and counter ions in bulk polarity

    SciTech Connect (OSTI)

    West, J. Palmer [Department of Chemistry, Clemson University, Clemson, SC 29634-0973 (United States)] [Department of Chemistry, Clemson University, Clemson, SC 29634-0973 (United States); Hwu, Shiou-Jyh, E-mail: shwu@clemson.edu [Department of Chemistry, Clemson University, Clemson, SC 29634-0973 (United States)] [Department of Chemistry, Clemson University, Clemson, SC 29634-0973 (United States)

    2012-11-15T23:59:59.000Z

    The synthesis and structural features of a newly emerged class of salt-inclusion solids (SISs) are reviewed. The descriptive chemistry with respect to the role of ionic salt and its correlation with bulk noncentrosymmetricity and polarity of the covalent oxide lattice in question is discussed by means of structure analysis. These unprecedented discoveries have opened doors to novel materials synthesis via the utilities of salt-inclusion chemistry (SIC) that are otherwise known as the molten-salt approach. The result of these investigations prove that the bulk acentricity, or cancellation of which, can be accounted for from the perspective of ionic and/or salt lattices. Highlights: Black-Right-Pointing-Pointer Synthesis and structure of newly emerged salt-inclusion solids are reviewed. Black-Right-Pointing-Pointer Salt lattice and its symmetry correlation with polar framework are discussed. Black-Right-Pointing-Pointer Preservation of acentricity is accounted for from the perspective of ionic and salt lattices.

  19. Photoluminescence properties of Ho{sup 3+} ion in lithium-fluoroborate glass containing different modifier oxides

    SciTech Connect (OSTI)

    Balakrishna, A., E-mail: ratnakaramsvu@gmail.com; Rajesh, D., E-mail: ratnakaramsvu@gmail.com; Ratnakaram, Y. C., E-mail: ratnakaramsvu@gmail.com [Department of Physics, S. V. University, Tirupati-517502 (India)

    2014-04-24T23:59:59.000Z

    Trivalent holmium (0.5 mol%) doped lithium fluoro-borate glasses with the chemical compositions 49.5Li{sub 2}B{sub 4}O{sub 7?}20BaF{sub 2?}10NaF?20MO (where M=Mg, Ca, Cd and Pb), 49.5Li{sub 2}B{sub 4}O{sub 7?}20BaF{sub 2?}10NaF?10MgO?10CaO and 49.5Li{sub 2}B{sub 4}O{sub 7?}20BaF{sub 2?}10NaF?10CdO?10PbO were synthesized and investigated their photoluminescence properties. The variation in chemical composition by varying modifier oxides causes changes in the structural spectroscopic behavior of Ho{sup 3+} ions. These changes are examined by UV-VIS- NIR and luminescence spectroscopic techniques. The visible luminescence spectra were obtained by exciting samples at 409 nm radiation.

  20. Properties of tungsten oxide thin films formed by ion-plasma and laser deposition methods for MOSiC-based hydrogen sensors

    SciTech Connect (OSTI)

    Fominski, V. Y., E-mail: vyfominskij@mephi.ru [National Research Nuclear University 'MEPhI' (Russian Federation); Grigoriev, S. N. [Moscow State Technological University 'Stankin' (Russian Federation); Romanov, R. I.; Zuev, V. V.; Grigoriev, V. V. [National Research Nuclear University 'MEPhI' (Russian Federation)

    2012-03-15T23:59:59.000Z

    Thin-film structures based on gas-sensitive tungsten oxide and catalytic platinum are fabricated by room-temperature deposition on a silicon carbide wafer using pulsed laser and ion-plasma methods. Oxide layer annealing in air to 600 Degree-Sign C caused the formation of microstructured and nanostructured crystalline states depending on the deposition conditions. Structural differences affect the electrical parameters and the stability of characteristics. The maximum response to hydrogen is detected in the structure fabricated by depositing a low-energy laser-induced flow of tungsten atoms in oxygen. The voltage shift of the currentvoltage curves for 2% H{sub 2} in air at 350 Degree-Sign C was 4.6 V at a current of {approx}10 {mu}A. The grown structures' metastability caused a significant decrease in the shift after long-term cyclic testing. The most stable shifts of {approx}2 V at positive bias on the Pt contact were detected for oxide films deposited by ion-plasma sputtering.

  1. One-pot synthesis of SnO{sub 2}/reduced graphene oxide nanocomposite in ionic liquid-based solution and its application for lithium ion batteries

    SciTech Connect (OSTI)

    Gu, Changdong, E-mail: cdgu@zju.edu.cn; Zhang, Heng; Wang, Xiuli; Tu, Jiangping

    2013-10-15T23:59:59.000Z

    Graphical abstract: - Highlights: • A facile and low-temperature method is developed for SnO{sub 2}/graphene composite. • Synthesis performed in a choline chloride-based ionic liquid. • The composite shows an enhanced cycling stability as anode for Li-ion batteries. • 4 nm SnO{sub 2} nanoparticles mono-dispersed on the surface of reduced graphene oxide. - Abstract: A facile and low-temperature method is developed for SnO{sub 2}/graphene composite which involves an ultrasonic-assistant oxidation–reduction reaction between Sn{sup 2+} and graphene oxide in a choline chloride–ethylene glycol based ionic liquid under ambient conditions. The reaction solution is non-corrosive and environmental-friendly. Moreover, the proposed technique does not require complicated infrastructures and heat treatment. The SnO{sub 2}/graphene composite consists of about 4 nm sized SnO{sub 2} nanoparticles with cassiterite structure mono-dispersed on the surface of reduced graphene oxide. As anode for lithium-ion batteries, the SnO{sub 2}/graphene composite shows a satisfying cycling stability (535 mAh g{sup ?1} after 50 cycles @100 mA g{sup ?1}), which is significantly prior to the bare 4 nm sized SnO{sub 2} nanocrsytals. The graphene sheets in the hybrid nanostructure could provide a segmentation effect to alleviate the volume expansion of the SnO{sub 2} and restrain the small and active Sn-based particles aggregating into larger and inactive clusters during cycling.

  2. In situ X-ray absorption fine structure studies of foreign metal ions in nickel hydrous oxide electrodes in alkaline electrolytes

    SciTech Connect (OSTI)

    Kim, Sunghyun; Tryk, D.A.; Scherson, D. (Case Western Reserve Univ., Cleveland, OH (United States)); Antonio, M.R. (Argonne National Lab., IL (United States)); Carr, R. (Stanford Synchrotron Radiation Lab., CA (United States))

    1994-10-06T23:59:59.000Z

    Aspects of the structural and electronic properties of hydrous oxide films of composite (9:1) Ni/Co and (9:1) Ni/Fe, prepared by electrodeposition, have been examined in alkaline electrolytes using in situ X-ray absorption fine structure (XAFS). An analysis of the X-ray absorption near the edge structure (XANES) and extended X-ray absorption fine structure (EXAFS) for the Co and Fe K-edges of these composite hydrous oxides revealed that, regardless of the oxidation state of nickel sites in the films, the guest metal ions are present as Co[sup 3+] and Fe[sup 3+] and that the cobalt-oxygen distance d(Co-O) = 1.9 [+-] 0.02 [angstrom] and d(Fe-O) = 1.92 [+-] 0.02 [angstrom]. The latter values are in excellent agreement with d(Me-O) (Me = Co or Fe) in CoOOH and [beta]- and [gamma]-FeOOH, respectively, determined by conventional X-ray diffraction. Two clearly defined Me-Ni first coordination shells could be observed in the Fourier transforms (FT) of the K-edge EXAFS of the guest metal recorded at a potential at which both Ni[sup 2+] and Ni[sup 3+] sites are expected to be present. 28 refs., 10 figs., 3 tabs.

  3. Fundamental studies of perovskite related oxide thin films for oxygen electrocatalysis at intermediate temperatures

    E-Print Network [OSTI]

    Lee, Dongkyu, Ph. D. Massachusetts Institute of Technology

    2014-01-01T23:59:59.000Z

    Discovering highly active and stable catalysts for electrochemical energy conversion and storage is essential to envision a new generation of renewable energy applications. Mixed ionic and electronic conductors (MIECs) ...

  4. Solid lithium ion conducting electrolytes and methods of preparation

    DOE Patents [OSTI]

    Narula, Chaitanya K; Daniel, Claus

    2013-05-28T23:59:59.000Z

    A composition comprised of nanoparticles of lithium ion conducting solid oxide material, wherein the solid oxide material is comprised of lithium ions, and at least one type of metal ion selected from pentavalent metal ions and trivalent lanthanide metal ions. Solution methods useful for synthesizing these solid oxide materials, as well as precursor solutions and components thereof, are also described. The solid oxide materials are incorporated as electrolytes into lithium ion batteries.

  5. Operation of staged membrane oxidation reactor systems

    DOE Patents [OSTI]

    Repasky, John Michael

    2012-10-16T23:59:59.000Z

    A method of operating a multi-stage ion transport membrane oxidation system. The method comprises providing a multi-stage ion transport membrane oxidation system with at least a first membrane oxidation stage and a second membrane oxidation stage, operating the ion transport membrane oxidation system at operating conditions including a characteristic temperature of the first membrane oxidation stage and a characteristic temperature of the second membrane oxidation stage; and controlling the production capacity and/or the product quality by changing the characteristic temperature of the first membrane oxidation stage and/or changing the characteristic temperature of the second membrane oxidation stage.

  6. Nuclear waste treatment - Studying the mixed ion type effects and concentration on the behaviour of oxide dispersions

    SciTech Connect (OSTI)

    Omokanye, Qanitalillahi; Biggs, Simon [Institute of Particle Science and Engineering, University of Leeds, Leeds LS2 9JT (United Kingdom)

    2007-07-01T23:59:59.000Z

    In order to gain good control over a particulate dispersion it is necessary to accurately characterise the strength of inter-particle forces that may be operating. Such control is not routinely used, as yet, in the nuclear industry despite the possible benefits. We are investigating the impact of mixed electrolyte systems, for example NaCl and Na{sub 2}SO{sub 4}, on the stability of oxide simulant particle dispersions. The electro-acoustic zeta potentials and shear yield stresses for concentrated dispersions have been measured across a range of pH conditions and electrolyte concentrations (0.001 M - 1.0 M). This paper summarizes initial data from these studies showing how the shear yield stress of concentrated aqueous oxide particle dispersions, can be adjusted through regulation of pH and the addition of background electrolytes (salt). The yield stress as a function of pH for these dispersions in mixed electrolytes showed a direct correlation with corresponding measurements of the zeta potential. Changes in the background electrolyte concentration or type were seen to cause a shift in the position of the isoelectric point (iep). Measurements of the shear yield stress showed a maximum at the iep corresponding to the position of maximum instability in the suspension. The consequences of these data for the efficient treatment of solid-liquid systems will be discussed. (authors)

  7. Strong reduction of V{sup 4+} amount in vanadium oxide/hexadecylamine nanotubes by doping with Co{sup 2+} and Ni{sup 2+} ions: Electron paramagnetic resonance and magnetic studies

    SciTech Connect (OSTI)

    Saleta, M. E.; Troiani, H. E.; Ribeiro Guevara, S.; Ruano, G.; Sanchez, R. D. [Centro Atomico Bariloche, CNEA, (8400) S. C. de Bariloche (Argentina); Malta, M. [Depto. de Cs. Exatas e da Terra, Univ. do Estado da Bahia, Cabula Salvador CP 2555 (Brazil); Torresi, R. M. [Instituto de Quimica, Universidad de Sao Paulo, Sao Paulo CP 26077, 05513-970 (Brazil)

    2011-05-01T23:59:59.000Z

    In this work we present a complete characterization and magnetic study of vanadium oxide/hexadecylamine nanotubes (VO{sub x}/Hexa NT's) doped with Co{sup 2+} and Ni{sup 2+} ions. The morphology of the NT's has been characterized by transmission electron microscopy, while the metallic elements have been quantified by the instrumental neutron activation analysis technique. The static and dynamic magnetic properties were studied by collecting data of magnetization as a function of magnetic field and temperature and by electron paramagnetic resonance. At difference of the majority reports in the literature, we do not observe magnetic dimers in vanadium oxide nanotubes. Also, we observed that the incorporation of metallic ions (Co{sup 2+}, S = 3/2 and Ni{sup 2+}, S = 1) decreases notably the amount of V{sup 4+} ions in the system, from 14-16% (nondoped case) to 2%-4%, with respect to the total vanadium atoms (fact corroborated by XPS experiments) anyway preserving the tubular nanostructure. The method to decrease the amount of V{sup 4+} in the nanotubes improves considerably their potential technological applications as Li-ion batteries cathodes.

  8. In-Situ Transmission Electron Microscopy Probing of Native Oxide...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Probing of Native Oxide and Artificial Layers on Silicon Nanoparticles for Lithium Ion In-Situ Transmission Electron Microscopy Probing of Native Oxide and Artificial...

  9. Stability Of Nanoclusters In 14YWT Oxide Dispersion Strengthened...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Stability Of Nanoclusters In 14YWT Oxide Dispersion Strengthened Steel Under Heavy Ion-irradiation By Atom Probe Tomography. Stability Of Nanoclusters In 14YWT Oxide Dispersion...

  10. Staged membrane oxidation reactor system

    DOE Patents [OSTI]

    Repasky, John Michael; Carolan, Michael Francis; Stein, VanEric Edward; Chen, Christopher Ming-Poh

    2013-04-16T23:59:59.000Z

    Ion transport membrane oxidation system comprising (a) two or more membrane oxidation stages, each stage comprising a reactant zone, an oxidant zone, one or more ion transport membranes separating the reactant zone from the oxidant zone, a reactant gas inlet region, a reactant gas outlet region, an oxidant gas inlet region, and an oxidant gas outlet region; (b) an interstage reactant gas flow path disposed between each pair of membrane oxidation stages and adapted to place the reactant gas outlet region of a first stage of the pair in flow communication with the reactant gas inlet region of a second stage of the pair; and (c) one or more reactant interstage feed gas lines, each line being in flow communication with any interstage reactant gas flow path or with the reactant zone of any membrane oxidation stage receiving interstage reactant gas.

  11. Staged membrane oxidation reactor system

    DOE Patents [OSTI]

    Repasky, John Michael; Carolan, Michael Francis; Stein, VanEric Edward; Chen, Christopher Ming-Poh

    2012-09-11T23:59:59.000Z

    Ion transport membrane oxidation system comprising (a) two or more membrane oxidation stages, each stage comprising a reactant zone, an oxidant zone, one or more ion transport membranes separating the reactant zone from the oxidant zone, a reactant gas inlet region, a reactant gas outlet region, an oxidant gas inlet region, and an oxidant gas outlet region; (b) an interstage reactant gas flow path disposed between each pair of membrane oxidation stages and adapted to place the reactant gas outlet region of a first stage of the pair in flow communication with the reactant gas inlet region of a second stage of the pair; and (c) one or more reactant interstage feed gas lines, each line being in flow communication with any interstage reactant gas flow path or with the reactant zone of any membrane oxidation stage receiving interstage reactant gas.

  12. Staged membrane oxidation reactor system

    DOE Patents [OSTI]

    Repasky, John Michael; Carolan, Michael Francis; Stein, VanEric Edward; Chen, Christopher Ming-Poh

    2014-05-20T23:59:59.000Z

    Ion transport membrane oxidation system comprising (a) two or more membrane oxidation stages, each stage comprising a reactant zone, an oxidant zone, one or more ion transport membranes separating the reactant zone from the oxidant zone, a reactant gas inlet region, a reactant gas outlet region, an oxidant gas inlet region, and an oxidant gas outlet region; (b) an interstage reactant gas flow path disposed between each pair of membrane oxidation stages and adapted to place the reactant gas outlet region of a first stage of the pair in flow communication with the reactant gas inlet region of a second stage of the pair; and (c) one or more reactant interstage feed gas lines, each line being in flow communication with any interstage reactant gas flow path or with the reactant zone of any membrane oxidation stage receiving interstage reactant gas.

  13. Buried oxide layer in silicon

    DOE Patents [OSTI]

    Sadana, Devendra Kumar (Pleasantville, NY); Holland, Orin Wayne (Lenoir, TN)

    2001-01-01T23:59:59.000Z

    A process for forming Silicon-On-Insulator is described incorporating the steps of ion implantation of oxygen into a silicon substrate at elevated temperature, ion implanting oxygen at a temperature below 200.degree. C. at a lower dose to form an amorphous silicon layer, and annealing steps to form a mixture of defective single crystal silicon and polycrystalline silicon or polycrystalline silicon alone and then silicon oxide from the amorphous silicon layer to form a continuous silicon oxide layer below the surface of the silicon substrate to provide an isolated superficial layer of silicon. The invention overcomes the problem of buried isolated islands of silicon oxide forming a discontinuous buried oxide layer.

  14. Surface reconstruction and chemical evolution of stoichiometric layered cathode materials for lithium-ion batteries

    E-Print Network [OSTI]

    Lin, Feng

    2014-01-01T23:59:59.000Z

    Layered Oxides for Lithium Batteries. Nano Lett. 13, 3857–O 2 Cathode Material in Lithium Ion Batteries. Adv. Energydecomposition in lithium ion batteries: first-principles

  15. Thin film ion conducting coating

    DOE Patents [OSTI]

    Goldner, Ronald B. (Lexington, MA); Haas, Terry (Sudbury, MA); Wong, Kwok-Keung (Watertown, MA); Seward, George (Arlington, MA)

    1989-01-01T23:59:59.000Z

    Durable thin film ion conducting coatings are formed on a transparent glass substrate by the controlled deposition of the mixed oxides of lithium:tantalum or lithium:niobium. The coatings provide durable ion transport sources for thin film solid state storage batteries and electrochromic energy conservation devices.

  16. A relation between surface oxide and oxygen-defect complexes in solid-phase epitaxial Si regrown from ion-beam-amorphized Si layers

    E-Print Network [OSTI]

    Atwater, Harry

    of Applied Physics, California Institute of Technology, Pasadena, California 91125 Stefano Rassiga and Kelvin positron annihilation spectroscopy, secondary-ion mass spectroscopy, and Monte Carlo simulations. The O was used to measure the incorporation of O atoms in the Si sub- strate, predicted by Monte Carlo TRIM 8

  17. Ti-substituted tunnel-type Na0.44MnO2 oxide as a negative electrode for aqueous sodium-ion batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wang, Yuesheng [Chinese Academy of Sciences (CAS), Beijing (China). Inst. of High Energy Physics (IHEP); Liu, Jue [Brookhaven National Lab. (BNL), Upton, NY (United States); Lee, Byungju [Seoul National Univ. (Korea, Republic of); Qiao, Ruimin [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source; Yang, Zhenzhong [Chinese Academy of Sciences (CAS), Beijing (China). Inst. of High Energy Physics (IHEP); Xu, Shuyin [Chinese Academy of Sciences (CAS), Beijing (China). Inst. of High Energy Physics (IHEP); Yu, Xiqian [Brookhaven National Lab. (BNL), Upton, NY (United States)] (ORCID:000000018513518X); Gu, Lin [Chinese Academy of Sciences (CAS), Beijing (China). Inst. of High Energy Physics (IHEP); Hu, Yong-Sheng [Chinese Academy of Sciences (CAS), Beijing (China). Inst. of High Energy Physics (IHEP)] (ORCID:0000000284306474); Yang, Wanli [Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States). Advanced Light Source] (ORCID:0000000306668063); Kang, Kisuk [Seoul National Univ. (Korea, Republic of); Li, Hong [Chinese Academy of Sciences (CAS), Beijing (China). Inst. of High Energy Physics (IHEP)] (ORCID:000000028659086X); Yang, Xiao-Qing [Brookhaven National Lab. (BNL), Upton, NY (United States); Chen, Liquan [Chinese Academy of Sciences (CAS), Beijing (China). Inst. of High Energy Physics (IHEP); Huang, Xuejie [Chinese Academy of Sciences (CAS), Beijing (China). Inst. of High Energy Physics (IHEP)

    2015-03-25T23:59:59.000Z

    The aqueous sodium-ion battery system is a safe and low-cost solution for large-scale energy storage, due to the abundance of sodium and inexpensive aqueous electrolytes. Although several positive electrode materials, e.g., Na0.44MnO2, were proposed, few negative electrode materials, e.g., activated carbon and NaTi2(PO4)3, are available. Here we show that Ti-substituted Na0.44MnO2 (Na0.44[Mn1-xTix]O2) with tunnel structure can be used as a negative electrode material for aqueous sodium-ion batteries. This material exhibits superior cyclability even without the special treatment of oxygen removal from the aqueous solution. Atomic-scale characterizations based on spherical aberration-corrected electron microscopy and ab initio calculations are utilized to accurately identify the Ti substitution sites and sodium storage mechanism. Ti substitution tunes the charge ordering property and reaction pathway, significantly smoothing the discharge/charge profiles and lowering the storage voltage. Both the fundamental understanding and practical demonstrations suggest that Na0.44[Mn1-xTix]O2 is a promising negative electrode material for aqueous sodium-ion batteries.

  18. Ti-substituted tunnel-type Na0.44MnO2 oxide as a negative electrode for aqueous sodium-ion batteries

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Wang, Yuesheng; Liu, Jue; Lee, Byungju; Qiao, Ruimin; Yang, Zhenzhong; Xu, Shuyin; Yu, Xiqian; Gu, Lin; Hu, Yong-Sheng; Yang, Wanli; et al

    2015-03-25T23:59:59.000Z

    The aqueous sodium-ion battery system is a safe and low-cost solution for large-scale energy storage, due to the abundance of sodium and inexpensive aqueous electrolytes. Although several positive electrode materials, e.g., Na0.44MnO2, were proposed, few negative electrode materials, e.g., activated carbon and NaTi2(PO4)3, are available. Here we show that Ti-substituted Na0.44MnO2 (Na0.44[Mn1-xTix]O2) with tunnel structure can be used as a negative electrode material for aqueous sodium-ion batteries. This material exhibits superior cyclability even without the special treatment of oxygen removal from the aqueous solution. Atomic-scale characterizations based on spherical aberration-corrected electron microscopy and ab initio calculations are utilized to accuratelymore »identify the Ti substitution sites and sodium storage mechanism. Ti substitution tunes the charge ordering property and reaction pathway, significantly smoothing the discharge/charge profiles and lowering the storage voltage. Both the fundamental understanding and practical demonstrations suggest that Na0.44[Mn1-xTix]O2 is a promising negative electrode material for aqueous sodium-ion batteries.« less

  19. Selective ion source

    DOE Patents [OSTI]

    Leung, K.N.

    1996-05-14T23:59:59.000Z

    A ion source is described wherein selected ions maybe extracted to the exclusion of unwanted ion species of higher ionization potential. Also described is a method of producing selected ions from a compound, such as P{sup +} from PH{sub 3}. The invention comprises a plasma chamber, an electron source, a means for introducing a gas to be ionized by electrons from the electron source, means for limiting electron energy from the electron source to a value between the ionization energy of the selected ion species and the greater ionization energy of an unwanted ion specie, and means for extracting the target ion specie from the plasma chamber. In one embodiment, the electrons are generated in a plasma cathode chamber immediately adjacent to the plasma chamber. A small extractor draws the electrons from the plasma cathode chamber into the relatively positive plasma chamber. The energy of the electrons extracted in this manner is easily controlled. The invention is particularly useful for doping silicon with P{sup +}, As{sup +}, and B{sup +} without the problematic presence of hydrogen, helium, water, or carbon oxide ions. Doped silicon is important for manufacture of semiconductors and semiconductor devices. 6 figs.

  20. Selective ion source

    DOE Patents [OSTI]

    Leung, Ka-Ngo (Hercules, CA)

    1996-01-01T23:59:59.000Z

    A ion source is described wherein selected ions maybe extracted to the exclusion of unwanted ion species of higher ionization potential. Also described is a method of producing selected ions from a compound, such as P.sup.+ from PH.sub.3. The invention comprises a plasma chamber, an electron source, a means for introducing a gas to be ionized by electrons from the electron source, means for limiting electron energy from the electron source to a value between the ionization energy of the selected ion species and the greater ionization energy of an unwanted ion specie, and means for extracting the target ion specie from the plasma chamber. In one embodiment, the electrons are generated in a plasma cathode chamber immediately adjacent to the plasma chamber. A small extractor draws the electrons from the plasma cathode chamber into the relatively positive plasma chamber. The energy of the electrons extracted in this manner is easily controlled. The invention is particularly useful for doping silicon with P.sup.+, AS.sup.+, and B.sup.+ without the problematic presence of hydrogen, helium, water, or carbon oxide ions. Doped silicon is important for manufacture of semiconductors and semiconductor devices.

  1. Morphological effects on the electrochemical performance of lithium-rich layered oxide cathodes, prepared by electrospinning technique, for lithium-ion battery applications

    SciTech Connect (OSTI)

    Min, Ji Won; Kalathil, Abdul Kareem; Yim, Chul Jin; Im, Won Bin, E-mail: imwonbin@jnu.ac.kr

    2014-06-01T23:59:59.000Z

    Li-rich Li{sub 1.2}Ni{sub 0.17}Co{sub 0.17}Mn{sub 0.5}O{sub 2} cathode materials were synthesized by electrospinning technique with different polymers, and their structural, morphological, and electrochemical performances were investigated. It was found that the electrospinning process leads to the formation of a fiber and flower-like morphology, by using different polymers and heat treatment conditions. The nanostructured morphology provided these materials with high initial discharge capacity. The cycling stability was improved with agglomerated nano-particles, as compared with porous materials. - Highlights: • Fiber and flower-like Li-rich cathode was synthesized by simple electrospinning. • Polymer dependent morphology and electrochemical performance was investigated. • Well-organized porous structure facilitates the diffusion of lithium ions. • Technique could be applicable to other cathode materials as well.

  2. Stability Of Nanoclusters In 14YWT Oxide Dispersion Strengthened...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ion-irradiation By Atom Probe Tomography. Abstract: 14YWT oxide dispersion strengthened (ODS) ferritic steel was irradiated with of 5 MeV Ni2+ ions, at 300 °C, 450 °C, and...

  3. Vitrification of ion exchange resins

    DOE Patents [OSTI]

    Cicero-Herman, Connie A. (Aiken, SC); Workman, Rhonda Jackson (North Augusta, SC)

    2001-01-01T23:59:59.000Z

    The present invention relates to vitrification of ion exchange resins that have become loaded with hazardous or radioactive wastes, in a way that produces a homogenous and durable waste form and reduces the disposal volume of the resin. The methods of the present invention involve directly adding borosilicate glass formers and an oxidizer to the ion exchange resin and heating the mixture at sufficient temperature to produce homogeneous glass.

  4. Radioactive ion detector

    DOE Patents [OSTI]

    Bower, K.E.; Weeks, D.R.

    1997-08-12T23:59:59.000Z

    Apparatus for detecting the presence, in aqueous media, of substances which emit alpha and/or beta radiation and determining the oxidation state of these radioactive substances, that is, whether they are in cationic or anionic form. In one embodiment, a sensor assembly has two elements, one comprised of an ion-exchange material which binds cations and the other comprised of an ion-exchange material which binds anions. Each ion-exchange element is further comprised of a scintillation plastic and a photocurrent generator. When a radioactive substance to which the sensor is exposed binds to either element and emits alpha or beta particles, photons produced in the scintillation plastic illuminate the photocurrent generator of that element. Sensing apparatus senses generator output and thereby indicates whether cationic species or anionic species or both are present and also provides an indication of species quantity. 2 figs.

  5. Oxygen ion conducting materials

    DOE Patents [OSTI]

    Carter, J. David; Wang, Xiaoping; Vaughey, John; Krumpelt, Michael

    2004-11-23T23:59:59.000Z

    An oxygen ion conducting ceramic oxide that has applications in industry including fuel cells, oxygen pumps, oxygen sensors, and separation membranes. The material is based on the idea that substituting a dopant into the host perovskite lattice of (La,Sr)MnO.sub.3 that prefers a coordination number lower than 6 will induce oxygen ion vacancies to form in the lattice. Because the oxygen ion conductivity of (La,Sr)MnO.sub.3 is low over a very large temperature range, the material exhibits a high overpotential when used. The inclusion of oxygen vacancies into the lattice by doping the material has been found to maintain the desirable properties of (La,Sr)MnO.sub.3, while significantly decreasing the experimentally observed overpotential.

  6. Oxygen ion conducting materials

    DOE Patents [OSTI]

    Vaughey, John; Krumpelt, Michael; Wang, Xiaoping; Carter, J. David

    2005-07-12T23:59:59.000Z

    An oxygen ion conducting ceramic oxide that has applications in industry including fuel cells, oxygen pumps, oxygen sensors, and separation membranes. The material is based on the idea that substituting a dopant into the host perovskite lattice of (La,Sr)MnO.sub.3 that prefers a coordination number lower than 6 will induce oxygen ion vacancies to form in the lattice. Because the oxygen ion conductivity of (La,Sr)MnO.sub.3 is low over a very large temperature range, the material exhibits a high overpotential when used. The inclusion of oxygen vacancies into the lattice by doping the material has been found to maintain the desirable properties of (La,Sr)MnO.sub.3, while significantly decreasing the experimentally observed overpotential.

  7. Oxygen ion conducting materials

    DOE Patents [OSTI]

    Vaughey, John (Elmhurst, IL); Krumpelt, Michael (Naperville, IL); Wang, Xiaoping (Downers Grove, IL); Carter, J. David (Bolingbrook, IL)

    2003-01-01T23:59:59.000Z

    An oxygen ion conducting ceramic oxide that has applications in industry including fuel cells, oxygen pumps, oxygen sensors, and separation membranes. The material is based on the idea that substituting a dopant into the host perovskite lattice of (La,Sr)MnO.sub.3 that prefers a coordination number lower than 6 will induce oxygen ion vacancies to form in the lattice. Because the oxygen ion conductivity of (La,Sr)MnO.sub.3 is low over a very large temperature range, the material exhibits a high overpotential when used. The inclusion of oxygen vacancies into the lattice by doping the material has been found to maintain the desirable properties of (La,Sr)MnO.sub.3, while significantly decreasing the experimentally observed overpotential.

  8. Unfamiliar oxidation states and their stabilization

    E-Print Network [OSTI]

    Kleinberg, Jacob

    1950-01-01T23:59:59.000Z

    appropriate conditions, either of free metals or of ions in lower states, has served for the preparation of higher oxidation states. Reference has already been made to the formation of the ferrate ion, FeOf2, and of Ago, by the electrolytic oxidation... compartments (Fig. 2), indicates (according to calculations based on Faraday's law) that the metal leaving the electrode has an average oxidation number in the neighborhood of 2.5.* The alu- * Oxidation numbers as low as 1.9 have recently been obtained...

  9. Microstructure of amorphous indium oxide and tin oxide thin films

    SciTech Connect (OSTI)

    Rauf, I.A.; Brown, L.M. (Univ. of Cambridge (United Kingdom))

    1994-03-15T23:59:59.000Z

    Indium oxide, tin oxide, and some other doped and undoped oxide semiconductors show an interesting and technologically important combination of properties. They have high luminous transparency, good electrical conductivity and high infrared reflectivity. Numerous techniques for depositing these materials have been developed and have undergone a number of changes during last two decades. An understanding of the basic physics of these materials has begun to dawn. Most of the literature on transparent conducting oxides consists of studying the dependence of the properties on the composition, preparation conditions, such as deposition rate, substrate temperature or post-deposition heat treatment. In this paper the authors have employed the transmission electron microscopy to study the microstructure of reactively evaporated, electron beam evaporated, ion-beam sputtered amorphous indium oxide and reactively evaporated amorphous tin oxide thin films. These films, which have received little attention in the past, can have enormous potential as transparent conductive coatings on heat-sensitive substrates and inexpensive solar cells.

  10. Investigation of layered intergrowth LixMyMn1-yO2+z (M=Ni,Co,Al) compounds as positive electrodes for Li-ion batteries

    E-Print Network [OSTI]

    Dolle, M.; Hollingsworth, J.; Richardson, T.J.; Doeff, M.M.

    2003-01-01T23:59:59.000Z

    as Positive Electrodes for Li-ion Batteries M. Dollé,* J.layered manganese oxide electrodes for lithium batteries.Keywords: Lithium batteries, layered manganese oxides,

  11. Paper-Based Lithium-Ion Battery Nojan Aliahmad, Mangilal Agarwal, Sudhir Shrestha, and Kody Varahramyan

    E-Print Network [OSTI]

    Zhou, Yaoqi

    Paper-Based Lithium-Ion Battery Nojan Aliahmad, Mangilal Agarwal, Sudhir Shrestha, and Kody Indianapolis (IUPUI), Indianapolis, IN 46202 Lithium-ion batteries have a wide range of applications including devices. Lithium titanium oxide (Li4Ti5O12), lithium magnesium oxide (LiMn2O4) and lithium cobalt oxide

  12. Ion colliders

    SciTech Connect (OSTI)

    Fischer, W.

    2011-12-01T23:59:59.000Z

    Ion colliders are research tools for high-energy nuclear physics, and are used to test the theory of Quantum Chromo Dynamics (QCD). The collisions of fully stripped high-energy ions create matter of a temperature and density that existed only microseconds after the Big Bang. Ion colliders can reach higher densities and temperatures than fixed target experiments although at a much lower luminosity. The first ion collider was the CERN Intersecting Storage Ring (ISR), which collided light ions [77Asb1, 81Bou1]. The BNL Relativistic Heavy Ion Collider (RHIC) is in operation since 2000 and has collided a number of species at numerous energies. The CERN Large Hadron Collider (LHC) started the heavy ion program in 2010. Table 1 shows all previous and the currently planned running modes for ISR, RHIC, and LHC. All three machines also collide protons, which are spin-polarized in RHIC. Ion colliders differ from proton or antiproton colliders in a number of ways: the preparation of the ions in the source and the pre-injector chain is limited by other effects than for protons; frequent changes in the collision energy and particle species, including asymmetric species, are typical; and the interaction of ions with each other and accelerator components is different from protons, which has implications for collision products, collimation, the beam dump, and intercepting instrumentation devices such a profile monitors. In the preparation for the collider use the charge state Z of the ions is successively increased to minimize the effects of space charge, intrabeam scattering (IBS), charge change effects (electron capture and stripping), and ion-impact desorption after beam loss. Low charge states reduce space charge, intrabeam scattering, and electron capture effects. High charge states reduce electron stripping, and make bending and acceleration more effective. Electron stripping at higher energies is generally more efficient. Table 2 shows the charge states and energies in the RHIC and LHC injector chains for the heaviest ion species used to date. The RHIC pulsed sputter source (PSC) and Tandem electrostatic accelerator are being replaced by an Electron Beam Ion Source (EBIS), Radio Frequency Quadrupole (RFQ) and short linac [08Ale1]. With EBIS beams of any element can be prepared for RHIC including uranium and spin-polarized 3He. At CERN an ECR ion source is used, followed by an RFQ and Linac. The ions are then accumulated, electron cooled, and accelerated in LEIR. After transfer to and acceleration in the PS, ion beams are injected into the SPS.

  13. Ion transport membrane module and vessel system

    DOE Patents [OSTI]

    Stein, VanEric Edward (Allentown, PA); Carolan, Michael Francis (Allentown, PA); Chen, Christopher M. (Allentown, PA); Armstrong, Phillip Andrew (Orefield, PA); Wahle, Harold W. (North Canton, OH); Ohrn, Theodore R. (Alliance, OH); Kneidel, Kurt E. (Alliance, OH); Rackers, Keith Gerard (Louisville, OH); Blake, James Erik (Uniontown, OH); Nataraj, Shankar (Allentown, PA); van Doorn, Rene Hendrik Elias (Obersulm-Willsbach, DE); Wilson, Merrill Anderson (West Jordan, UT)

    2008-02-26T23:59:59.000Z

    An ion transport membrane system comprising (a) a pressure vessel having an interior, an exterior, an inlet, and an outlet; (b) a plurality of planar ion transport membrane modules disposed in the interior of the pressure vessel and arranged in series, each membrane module comprising mixed metal oxide ceramic material and having an interior region and an exterior region, wherein any inlet and any outlet of the pressure vessel are in flow communication with exterior regions of the membrane modules; and (c) one or more gas manifolds in flow communication with interior regions of the membrane modules and with the exterior of the pressure vessel.The ion transport membrane system may be utilized in a gas separation device to recover oxygen from an oxygen-containing gas or as an oxidation reactor to oxidize compounds in a feed gas stream by oxygen permeated through the mixed metal oxide ceramic material of the membrane modules.

  14. Ion transport membrane module and vessel system

    DOE Patents [OSTI]

    Stein, VanEric Edward (Allentown, PA); Carolan, Michael Francis (Allentown, PA); Chen, Christopher M. (Allentown, PA); Armstrong, Phillip Andrew (Orefield, PA); Wahle, Harold W. (North Canton, OH); Ohrn, Theodore R. (Alliance, OH); Kneidel, Kurt E. (Alliance, OH); Rackers, Keith Gerard (Louisville, OH); Blake, James Erik (Uniontown, OH); Nataraj, Shankar (Allentown, PA); Van Doorn, Rene Hendrik Elias (Obersulm-Willsbach, DE); Wilson, Merrill Anderson (West Jordan, UT)

    2012-02-14T23:59:59.000Z

    An ion transport membrane system comprising (a) a pressure vessel having an interior, an exterior, an inlet, and an outlet; (b) a plurality of planar ion transport membrane modules disposed in the interior of the pressure vessel and arranged in series, each membrane module comprising mixed metal oxide ceramic material and having an interior region and an exterior region, wherein any inlet and any outlet of the pressure vessel are in flow communication with exterior regions of the membrane modules; and (c) one or more gas manifolds in flow communication with interior regions of the membrane modules and with the exterior of the pressure vessel. The ion transport membrane system may be utilized in a gas separation device to recover oxygen from an oxygen-containing gas or as an oxidation reactor to oxidize compounds in a feed gas stream by oxygen permeated through the mixed metal oxide ceramic material of the membrane modules.

  15. Catalysis using hydrous metal oxide ion exchangers

    DOE Patents [OSTI]

    Dosch, R.G.; Stephens, H.P.; Stohl, F.V.

    1983-07-21T23:59:59.000Z

    In a process which is catalyzed by a catalyst comprising an active metal on a carrier, said metal being active as a catalyst for the process, an improvement is provided wherein the catalyst is a hydrous, alkali metal or alkaline earth metal titanate, zirconate, niobate or tantalate wherein alkali or alkaline earth metal cations have been exchanged with a catalytically effective amount of cations of said metal.

  16. Growth of oxide exchange bias layers

    DOE Patents [OSTI]

    Chaiken, A.; Michel, R.P.

    1998-07-21T23:59:59.000Z

    An oxide (NiO, CoO, NiCoO) antiferromagnetic exchange bias layer produced by ion beam sputtering of an oxide target in pure argon (Ar) sputtering gas, with no oxygen gas introduced into the system. Antiferromagnetic oxide layers are used, for example, in magnetoresistive readback heads to shift the hysteresis loops of ferromagnetic films away from the zero field axis. For example, NiO exchange bias layers have been fabricated using ion beam sputtering of an NiO target using Ar ions, with the substrate temperature at 200 C, the ion beam voltage at 1000V and the beam current at 20 mA, with a deposition rate of about 0.2 {angstrom}/sec. The resulting NiO film was amorphous. 4 figs.

  17. Surface reconstruction and chemical evolution of stoichiometric layered cathode materials for lithium-ion batteries

    E-Print Network [OSTI]

    Lin, Feng

    2014-01-01T23:59:59.000Z

    Layered Oxides for Lithium Batteries. Nano Lett. 13, 3857–Material in Lithium Ion Batteries. Adv. Energy Mater. n/a–n/decomposition in lithium ion batteries: first-principles

  18. Composite catalyst for carbon monoxide and hydrocarbon oxidation

    DOE Patents [OSTI]

    Liu, Wei (Cambridge, MA); Flytzani-Stephanopoulos, Maria (Winchester, MA)

    1996-01-01T23:59:59.000Z

    A method and composition for the complete oxidation of carbon monoxide and/or hydrocarbon compounds. The method involves reacting the carbon monoxide and/or hydrocarbons with an oxidizing agent in the presence of a metal oxide composite catalyst. The catalyst is prepared by combining fluorite-type oxygen ion conductors with active transition metals. The fluorite oxide, selected from the group consisting of cerium oxide, zirconium oxide, thorium oxide, hafnium oxide, and uranium oxide, and may be doped by alkaline earth and rare earth oxides. The transition metals, selected from the group consisting of molybdnum, copper, cobalt, maganese, nickel, and silver, are used as additives. The atomic ratio of transition metal to fluorite oxide is less than one.

  19. Composite catalyst for carbon monoxide and hydrocarbon oxidation

    DOE Patents [OSTI]

    Liu, W.; Flytzani-Stephanopoulos, M.

    1996-03-19T23:59:59.000Z

    A method and composition are disclosed for the complete oxidation of carbon monoxide and/or hydrocarbon compounds. The method involves reacting the carbon monoxide and/or hydrocarbons with an oxidizing agent in the presence of a metal oxide composite catalyst. The catalyst is prepared by combining fluorite-type oxygen ion conductors with active transition metals. The fluorite oxide, selected from the group consisting of cerium oxide, zirconium oxide, thorium oxide, hafnium oxide, and uranium oxide, and may be doped by alkaline earth and rare earth oxides. The transition metals, selected from the group consisting of molybdenum, copper, cobalt, manganese, nickel, and silver, are used as additives. The atomic ratio of transition metal to fluorite oxide is less than one.

  20. Ion exchange purification of scandium

    DOE Patents [OSTI]

    Herchenroeder, L.A.; Burkholder, H.R.

    1990-10-23T23:59:59.000Z

    An improvement in purification of scandium through ion exchange chromatography is disclosed in which the oxidation potential of the eluting solution is altered by the addition of potassium chlorate or ammonium chloride so that removal of contaminants is encouraged. The temperature, pH and concentration of the eluent HEDTA are controlled in order to maintain the scandium in the column while minimizing dilution of the scandium band. Recovery of scandium is improved by pumping dilute scandium over the column prior to stripping the scandium and precipitation. This eliminates the HEDTA ion and other monovalent cations contaminating the scandium band. This method maximizes recovery of scandium while maintaining purity. 2 figs.

  1. Oxide Shell Reduction and Magnetic Property Changes in Core-Shell...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Shell Reduction and Magnetic Property Changes in Core-Shell Fe Nanoclusters under Ion Irradiation. Oxide Shell Reduction and Magnetic Property Changes in Core-Shell Fe Nanoclusters...

  2. Novel lanthanide-labeled metal oxide nanoparticles improve the measurement of in vivo clearance and translocation

    E-Print Network [OSTI]

    Abid, Aamir D; Anderson, Donald S; Das, Gautom K; Van Winkle, Laura S; Kennedy, Ian M

    2013-01-01T23:59:59.000Z

    and translocation of europium-doped gadolinium oxideemission from the lanthanide Europium ion, and has a similarcorrespond to monoclinic europium oxide (PDF 00-034-0072). [

  3. Method of forming buried oxide layers in silicon

    DOE Patents [OSTI]

    Sadana, Devendra Kumar (Pleasantville, NY); Holland, Orin Wayne (Lenoir City, TN)

    2000-01-01T23:59:59.000Z

    A process for forming Silicon-On-Insulator is described incorporating the steps of ion implantation of oxygen into a silicon substrate at elevated temperature, ion implanting oxygen at a temperature below 200.degree. C. at a lower dose to form an amorphous silicon layer, and annealing steps to form a mixture of defective single crystal silicon and polycrystalline silicon or polycrystalline silicon alone and then silicon oxide from the amorphous silicon layer to form a continuous silicon oxide layer below the surface of the silicon substrate to provide an isolated superficial layer of silicon. The invention overcomes the problem of buried isolated islands of silicon oxide forming a discontinuous buried oxide layer.

  4. Investigating Iron Ions | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Investigating Iron Ions Investigating Iron Ions Computer code provides detailed predictions of highly charged ions in water Using resources at EMSL, scientists obtained...

  5. Helium Ion Microscope | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Helium Ion Microscope Helium Ion Microscope The Helium Ion Microscope promises to advance biological, geochemical, biogeochemical, and surfaceinterface studies using its combined...

  6. Helium Ion Microscope | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Helium Ion Microscope Helium Ion Microscope Bruce Arey discusses the capabilities of EMSL's new helium ion microscope housed in EMSL's Quiet Wing....

  7. Electrochemical Characterization of Vanadium Oxide Nanostructured Electrode

    E-Print Network [OSTI]

    Sadoway, Donald Robert

    microstructures called aerogels in the case of supercritical or freeze-drying and ambigels in the case of solvent for intercalated ions.7 When cycled between 4.0 and 1.5 V, vanadium oxide aerogels achieved capaci- ties of 410 mAh/g at C/40.6 Baudrin et al. have used the vanadium oxide aerogel structure to access a metastable phase

  8. GeOx/Reduced Graphene Oxide Composite as an Anode for Li-ion Batteries: Enhanced Capacity via Reversible Utilization of Li2O along with Improved Rate Performance

    SciTech Connect (OSTI)

    Lv, Dongping; Gordin, Mikhail; Yi, Ran; Xu, Terrence (Tianren); Song, Jiangxuan; Jiang, Yingbing; Choi, Daiwon; Wang, Donghai

    2014-09-01T23:59:59.000Z

    A self-assembled GeOx/reduced graphene oxide (GeOx/RGO) composite, where GeOx nanoparticles were grown directly on reduced graphene oxide sheets, was synthesized via a facile one-step reduction approach and studied by X-ray diffraction, transmission electron microscopy, energy dispersive X-ray spectroscopy, electron energy loss spectroscopy elemental mapping, and other techniques. Electrochemical evaluation indicates that incorporation of reduced graphene oxide enhances both the rate capability and reversible capacity of GeOx, with the latter being due to the RGO enabling reversible utilization of Li2O. The composite delivers a high reversible capacity of 1600 mAhg-1 at a current density of 100 mAg-1, and still maintains a capacity of 410 mAhg-1 at a high current density of 20 Ag-1. Owing to the flexible reduced graphene oxide sheets enwrapping the GeOx particles, the cycling stability of the composite was also improved significantly. To further demonstrate its feasibility in practical applications, the synthesized GeOx/RGO composite anode was successfully paired with a high voltage LiNi0.5Mn1.5O4 cathode to form a full cell, which showed good cycling and rate performance.

  9. Oxidation catalyst

    DOE Patents [OSTI]

    Ceyer, Sylvia T. (Cambridge, MA); Lahr, David L. (Cambridge, MA)

    2010-11-09T23:59:59.000Z

    The present invention generally relates to catalyst systems and methods for oxidation of carbon monoxide. The invention involves catalyst compositions which may be advantageously altered by, for example, modification of the catalyst surface to enhance catalyst performance. Catalyst systems of the present invention may be capable of performing the oxidation of carbon monoxide at relatively lower temperatures (e.g., 200 K and below) and at relatively higher reaction rates than known catalysts. Additionally, catalyst systems disclosed herein may be substantially lower in cost than current commercial catalysts. Such catalyst systems may be useful in, for example, catalytic converters, fuel cells, sensors, and the like.

  10. Maskless, resistless ion beam lithography

    SciTech Connect (OSTI)

    Ji, Qing

    2003-03-10T23:59:59.000Z

    As the dimensions of semiconductor devices are scaled down, in order to achieve higher levels of integration, optical lithography will no longer be sufficient for the needs of the semiconductor industry. Alternative next-generation lithography (NGL) approaches, such as extreme ultra-violet (EUV), X-ray, electron-beam, and ion projection lithography face some challenging issues with complicated mask technology and low throughput. Among the four major alternative NGL approaches, ion beam lithography is the only one that can provide both maskless and resistless patterning. As such, it can potentially make nano-fabrication much simpler. This thesis investigates a focused ion beam system for maskless, resistless patterning that can be made practical for high-volume production. In order to achieve maskless, resistless patterning, the ion source must be able to produce a variety of ion species. The compact FIB system being developed uses a multicusp plasma ion source, which can generate ion beams of various elements, such as O{sub 2}{sup +}, BF{sub 2}{sup +}, P{sup +} etc., for surface modification and doping applications. With optimized source condition, around 85% of BF{sub 2}{sup +}, over 90% of O{sub 2}{sup +} and P{sup +} have been achieved. The brightness of the multicusp-plasma ion source is a key issue for its application to maskless ion beam lithography. It can be substantially improved by optimizing the source configuration and extractor geometry. Measured brightness of 2 keV He{sup +} beam is as high as 440 A/cm{sup 2} {center_dot} Sr, which represents a 30x improvement over prior work. Direct patterning of Si thin film using a focused O{sub 2}{sup +} ion beam has been investigated. A thin surface oxide film can be selectively formed using 3 keV O{sub 2}{sup +} ions with the dose of 10{sup 15} cm{sup -2}. The oxide can then serve as a hard mask for patterning of the Si film. The process flow and the experimental results for directly patterned poly-Si features are presented. The formation of shallow pn-junctions in bulk silicon wafers by scanning focused P{sup +} beam implantation at 5 keV is also presented. With implantation dose of around 10{sup 16} cm{sup -2}, the electron concentration is about 2.5 x 10{sup 18} cm{sup -3} and electron mobility is around 200 cm{sup 2}/V{center_dot}s. To demonstrate the suitability of scanning FIB lithography for the manufacture of integrated circuit devices, SOI MOSFET fabrication using the maskless, resistless ion beam lithography is demonstrated. An array of microcolumns can be built by stacking multi-aperture electrode and insulator layers. Because the multicusp plasma source can achieve uniform ion density over a large area, it can be used in conjunction with the array of microcolumns, for massively parallel FIB processing to achieve reasonable exposure throughput.

  11. Polyoxometalate water oxidation catalysts and methods of use thereof

    DOE Patents [OSTI]

    Hill, Craig L.; Gueletii, Yurii V.; Musaev, Djamaladdin G.; Yin, Qiushi; Botar, Bogdan

    2014-09-02T23:59:59.000Z

    Homogeneous water oxidation catalysts (WOCs) for the oxidation of water to produce hydrogen ions and oxygen, and methods of making and using thereof are described herein. In a preferred embodiment, the WOC is a polyoxometalate WOC which is hydrolytically stable, oxidatively stable, and thermally stable. The WOC oxidized waters in the presence of an oxidant. The oxidant can be generated photochemically, using light, such as sunlight, or electrochemically using a positively biased electrode. The hydrogen ions are subsequently reduced to form hydrogen gas, for example, using a hydrogen evolution catalyst (HEC). The hydrogen gas can be used as a fuel in combustion reactions and/or in hydrogen fuel cells. The catalysts described herein exhibit higher turn over numbers, faster turn over frequencies, and/or higher oxygen yields than prior art catalysts.

  12. Cycle Life Modeling of Lithium-Ion Batteries Gang Ning* and Branko N. Popov**,z

    E-Print Network [OSTI]

    Popov, Branko N.

    Cycle Life Modeling of Lithium-Ion Batteries Gang Ning* and Branko N. Popov**,z Department and Newman4 made a first attempt to model the parasitic reactions in lithium-ion batteries by incorporating a solvent oxidation into a lithium-ion battery model. Spotnitz5 developed polynomial expressions

  13. Solubility Behavior and Phase Stability of Transition Metal Oxides in Alkaline Hydrothermal Environments

    SciTech Connect (OSTI)

    S.E. Ziemniak

    2000-05-18T23:59:59.000Z

    The solubility behavior of transition metal oxides in high temperature water is interpreted by recognizing three types of chemical reaction equilibria: metal oxide hydration/dehydration, metal oxide dissolution and metal ion hydroxocomplex formation. The equilibria are quantified using thermodynamic concepts and the thermochemical properties of the metal oxides/ions representative of the most common constituents of construction metal alloys, i.e., element shaving atomic numbers between Z = 22 (Ti) and Z = 30 (Zn), are summarized on the basis of metal oxide solubility studies conducted in the laboratory. Particular attention is devoted to the uncharged metal ion hydrocomplex, M{sup Z}(OH){sub Z}(aq), since its thermochemical properties define minimum solubilities of the metal oxide at a given temperature. Experimentally-extracted values of standard partial molal entropy (S{sup 0}) for the transition metal ion neutral hydroxocomplex are shown to be influenced by ligand field stabilization energies and complex symmetry.

  14. Ion detector

    DOE Patents [OSTI]

    Tullis, Andrew M. (Livermore, CA)

    1987-01-01T23:59:59.000Z

    An improved ion detector device of the ionization detection device chamber ype comprises an ionization chamber having a central electrode therein surrounded by a cylindrical electrode member within the chamber with a collar frictionally fitted around at least one of the electrodes. The collar has electrical contact means carried in an annular groove in an inner bore of the collar to contact the outer surface of the electrode to provide electrical contact between an external terminal and the electrode without the need to solder leads to the electrode.

  15. C60 Secondary Ion Fourier Transform Ion Cyclotron Resonance Mass...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    C60 Secondary Ion Fourier Transform Ion Cyclotron Resonance Mass Spectrometry. C60 Secondary Ion Fourier Transform Ion Cyclotron Resonance Mass Spectrometry. Abstract: Secondary...

  16. Oxygen ion-beam microlithography

    DOE Patents [OSTI]

    Tsuo, Y. Simon (Lakewood, CO)

    1991-01-01T23:59:59.000Z

    A method of providing and developing a resist on a substrate for constructing integrated circuit (IC) chips includes the following steps: of depositing a thin film of amorphous silicon or hydrogenated amorphous silicon on the substrate and exposing portions of the amorphous silicon to low-energy oxygen ion beams to oxidize the amorphous silicon at those selected portions. The nonoxidized portions are then removed by etching with RF-excited hydrogen plasma. Components of the IC chip can then be constructed through the removed portions of the resist. The entire process can be performed in an in-line vacuum production system having several vacuum chambers. Nitrogen or carbon ion beams can also be used.

  17. Oxygen ion-beam microlithography

    DOE Patents [OSTI]

    Tsuo, Y.S.

    1991-08-20T23:59:59.000Z

    A method of providing and developing a resist on a substrate for constructing integrated circuit (IC) chips includes the following steps: of depositing a thin film of amorphous silicon or hydrogenated amorphous silicon on the substrate and exposing portions of the amorphous silicon to low-energy oxygen ion beams to oxidize the amorphous silicon at those selected portions. The nonoxidized portions are then removed by etching with RF-excited hydrogen plasma. Components of the IC chip can then be constructed through the removed portions of the resist. The entire process can be performed in an in-line vacuum production system having several vacuum chambers. Nitrogen or carbon ion beams can also be used. 5 figures.

  18. Composite oxygen ion transport element

    DOE Patents [OSTI]

    Chen, Jack C. (Getzville, NY); Besecker, Charles J. (Batavia, IL); Chen, Hancun (Williamsville, NY); Robinson, Earil T. (Mentor, OH)

    2007-06-12T23:59:59.000Z

    A composite oxygen ion transport element that has a layered structure formed by a dense layer to transport oxygen ions and electrons and a porous support layer to provide mechanical support. The dense layer can be formed of a mixture of a mixed conductor, an ionic conductor, and a metal. The porous support layer can be fabricated from an oxide dispersion strengthened metal, a metal-reinforced intermetallic alloy, a boron-doped Mo.sub.5Si.sub.3-based intermetallic alloy or combinations thereof. The support layer can be provided with a network of non-interconnected pores and each of said pores communicates between opposite surfaces of said support layer. Such a support layer can be advantageously employed to reduce diffusion resistance in any type of element, including those using a different material makeup than that outlined above.

  19. Spectra of Ions Produced by Corona Discharges

    SciTech Connect (OSTI)

    Skalny, J.; Hortvath, G. [Department of Experimental Physics, Comenius University, Mlynska dolina F-2, 84248 Bratislava (Slovakia); Mason, N. J. [Open University, Department of Physics and Astronomy, Walton Hall, Milton Keynes MK7 6AA (United Kingdom)

    2006-12-01T23:59:59.000Z

    A mass spectrometric study of ions extracted from both positive and negative DC corona discharges, initiated in point-to plane electrode system, has been carried out in ambient air at low air pressure (5 - 30) kPa. The average relative humidity of air was typically 40-50 %. Ions were extracted through a small orifice in the plane electrode into an intermediate gap where the low pressure prevented further ion-molecule reactions. Mass analysis of negative ions formed in the negative corona discharge using ambient air has shown that the yield of individual ions is strongly affected by trace concentrations of ozone, nitrogen oxides, carbon dioxide and water vapour. In dry air the CO{sub 3}{sup -} ion was found to be dominant. In presence of water this is converted very efficiently to cluster ions CO{sub 3}{sup -}{center_dot}(H{sub 2}O){sub n} containing one and more water molecules. The yield of O{sub 3}{sup -}{center_dot}(H{sub 2}O){sub n} clusters or core ions was found to be considerably lower than in some other studies at atmospheric pressure. The mass spectrum of ions extracted from drift region of a positive corona discharge was simpler being dominantly cluster ions H3O+{center_dot}(H2O)n most probably formed from O{sub 2}{sup +} ions, a two step process being active if water molecules are present in the discharge gap even at relatively low concentration.

  20. Lithium metal oxide electrodes for lithium batteries

    DOE Patents [OSTI]

    Thackeray, Michael M. (Naperville, IL); Kim, Jeom-Soo (Naperville, IL); Johnson, Christopher S. (Naperville, IL)

    2008-01-01T23:59:59.000Z

    An uncycled electrode for a non-aqueous lithium electrochemical cell including a lithium metal oxide having the formula Li.sub.(2+2x)/(2+x)M'.sub.2x/(2+x)M.sub.(2-2x)/(2+x)O.sub.2-.delta., in which 0.ltoreq.x<1 and .delta. is less than 0.2, and in which M is a non-lithium metal ion with an average trivalent oxidation state selected from two or more of the first row transition metals or lighter metal elements in the periodic table, and M' is one or more ions with an average tetravalent oxidation state selected from the first and second row transition metal elements and Sn. Methods of preconditioning the electrodes are disclosed as are electrochemical cells and batteries containing the electrodes.

  1. Electrospray ion source with reduced analyte electrochemistry

    DOE Patents [OSTI]

    Kertesz, Vilmos; Van Berkel, Gary J

    2013-07-30T23:59:59.000Z

    An electrospray ion (ESI) source and method capable of ionizing an analyte molecule without oxidizing or reducing the analyte of interest. The ESI source can include an emitter having a liquid conduit, a working electrode having a liquid contacting surface, a spray tip, a secondary working electrode, and a charge storage coating covering partially or fully the liquid contacting surface of the working electrode. The liquid conduit, the working electrode and the secondary working electrode can be in liquid communication. The electrospray ion source can also include a counter electrode proximate to, but separated from, said spray tip. The electrospray ion source can also include a power system for applying a voltage difference between the working electrodes and a counter-electrode. The power system can deliver pulsed voltage changes to the working electrodes during operation of said electrospray ion source to minimize the surface potential of the charge storage coating.

  2. Electrospray ion source with reduced analyte electrochemistry

    DOE Patents [OSTI]

    Kertesz, Vilmos [Knoxville, TN; Van Berkel, Gary [Clinton, TN

    2011-08-23T23:59:59.000Z

    An electrospray ion (ESI) source and method capable of ionizing an analyte molecule without oxidizing or reducing the analyte of interest. The ESI source can include an emitter having a liquid conduit, a working electrode having a liquid contacting surface, a spray tip, a secondary working electrode, and a charge storage coating covering partially or fully the liquid contacting surface of the working electrode. The liquid conduit, the working electrode and the secondary working electrode can be in liquid communication. The electrospray ion source can also include a counter electrode proximate to, but separated from, said spray tip. The electrospray ion source can also include a power system for applying a voltage difference between the working electrodes and a counter-electrode. The power system can deliver pulsed voltage changes to the working electrodes during operation of said electrospray ion source to minimize the surface potential of the charge storage coating.

  3. Ion Monitoring

    DOE Patents [OSTI]

    Orr, Christopher Henry (Calderbridge, GB); Luff, Craig Janson (Calderbridge, GB); Dockray, Thomas (Calderbridge, GB); Macarthur, Duncan Whittemore (Los Alamos, NM)

    2003-11-18T23:59:59.000Z

    The apparatus and method provide a technique for significantly reducing capacitance effects in detector electrodes arising due to movement of the instrument relative to the item/location being monitored in ion detection based techniques. The capacitance variations are rendered less significant by placing an electrically conducting element between the detector electrodes and the monitored location/item. Improved sensitivity and reduced noise signals arise as a result. The technique also provides apparatus and method suitable for monitoring elongate items which are unsuited to complete enclosure in one go within a chamber. The items are monitored part by part as the pass through the instrument, so increasing the range of items or locations which can be successfully monitored.

  4. The Mechanical and Tribological Properties or Ion Implanted Ceramics

    E-Print Network [OSTI]

    Bull, Stephen John

    1988-06-17T23:59:59.000Z

    by Wei et al (1987a. b) has shown that ion beam mixing of some ceramic discs with Ti, Ni or Co can result in reduced coefficients of friction at 800°C in a simulated diesel exhaust environment. 1.1.3 Oxidation and Corrosion Surface films have long... ions and defects below the surface to be determined both qualitatively and quantitatively. This has an important bearing on the other surface property changes produced by ion implantation discussed in the next chapter. 2.1 The Stopping of Ions...

  5. Ion funnel ion trap and process

    DOE Patents [OSTI]

    Belov, Mikhail E [Richland, WA; Ibrahim, Yehia M [Richland, WA; Clowers, Biran H [West Richland, WA; Prior, David C [Hermiston, OR; Smith, Richard D [Richland, WA

    2011-02-15T23:59:59.000Z

    An ion funnel trap is described that includes a inlet portion, a trapping portion, and a outlet portion that couples, in normal operation, with an ion funnel. The ion trap operates efficiently at a pressure of .about.1 Torr and provides for: 1) removal of low mass-to-charge (m/z) ion species, 2) ion accumulation efficiency of up to 80%, 3) charge capacity of .about.10,000,000 elementary charges, 4) ion ejection time of 40 to 200 .mu.s, and 5) optimized variable ion accumulation times. Ion accumulation with low concentration peptide mixtures has shown an increase in analyte signal-to-noise ratios (SNR) of a factor of 30, and a greater than 10-fold improvement in SNR for multiply charged analytes.

  6. Oxidative particle mixtures for groundwater treatment

    DOE Patents [OSTI]

    Siegrist, Robert L. (Boulder, CO); Murdoch, Lawrence C. (Clemson, SC)

    2000-01-01T23:59:59.000Z

    The invention is a method and a composition of a mixture for degradation and immobilization of contaminants in soil and groundwater. The oxidative particle mixture and method includes providing a material having a minimal volume of free water, mixing at least one inorganic oxidative chemical in a granular form with a carrier fluid containing a fine grained inorganic hydrophilic compound and injecting the resulting mixture into the subsurface. The granular form of the inorganic oxidative chemical dissolves within the areas of injection, and the oxidative ions move by diffusion and/or advection, therefore extending the treatment zone over a wider area than the injection area. The organic contaminants in the soil and groundwater are degraded by the oxidative ions, which form solid byproducts that can sorb significant amounts of inorganic contaminants, metals, and radionuclides for in situ treatment and immobilization of contaminants. The method and composition of the oxidative particle mixture for long-term treatment and immobilization of contaminants in soil and groundwater provides for a reduction in toxicity of contaminants in a subsurface area of contamination without the need for continued injection of treatment material, or for movement of the contaminants, or without the need for continuous pumping of groundwater through the treatment zone, or removal of groundwater from the subsurface area of contamination.

  7. Heavy Ion Event Displays

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    simulated collisions of lead ions in the LHC experiments. Additional photos, video and information are available at these links: Lead-ion collision images from the ALICE...

  8. Microfabricated ion frequency standard

    SciTech Connect (OSTI)

    Schwindt, Peter (Albuquerque, NM); Biedermann, Grant (Albuquerque, NM); Blain, Matthew G. (Albuquerque, NM); Stick, Daniel L. (Albuquerque, NM); Serkland, Darwin K. (Albuquerque, NM); Olsson, III, Roy H. (Albuquerque, NM)

    2010-12-28T23:59:59.000Z

    A microfabricated ion frequency standard (i.e. an ion clock) is disclosed with a permanently-sealed vacuum package containing a source of ytterbium (Yb) ions and an octupole ion trap. The source of Yb ions is a micro-hotplate which generates Yb atoms which are then ionized by a ultraviolet light-emitting diode or a field-emission electron source. The octupole ion trap, which confines the Yb ions, is formed from suspended electrodes on a number of stacked-up substrates. A microwave source excites a ground-state transition frequency of the Yb ions, with a frequency-doubled vertical-external-cavity laser (VECSEL) then exciting the Yb ions up to an excited state to produce fluorescent light which is used to tune the microwave source to the ground-state transition frequency, with the microwave source providing a precise frequency output for the ion clock.

  9. Surface Modification of Polymer Substrates by Oxygen Ion Irradiation

    SciTech Connect (OSTI)

    Takaoka, G. H.; Ryuto, H.; Araki, R.; Yakushiji, T. [Photonics and Electronics Science and Engineering Center, Kyoto University, Nishikyo, Kyoto 615-8510 (Japan)

    2008-11-03T23:59:59.000Z

    Oxygen cluster ions and/or monomer ions were used for the sputtering and the surface modification of polymers such as polycarbonate (PC) and polyethylene terephthalate (PET). For the case of oxygen cluster ion irradiation, the sputtered depth increased with increase of the acceleration voltage, and the sputtering yield was much larger than that by the monomer ion irradiation. The sputtered particles represented the polymer structure, which indicated that the bond scission by the cluster ion irradiation resulted in an ejection of monomer molecule through the intermolecular collision. On the other hand, for the oxygen monomer ion irradiation, the implanted depth increased with increase of the acceleration voltage, and the bond scission occurred at the deep region through the binary collision with the high energetic ions. Therefore, the sputtering yield for the polymer surfaces decreased, and the sputtering effect became very small. Furthermore, the simultaneous use of oxygen cluster and monomer ions was more effective for oxidation of the PET surfaces rather than the monomer ion irradiation or the cluster ion irradiation. As a result, the contact angle measurement showed that the wettability of the PET surfaces irradiated by the simultaneous use of oxygen cluster and monomer ions was much enhanced.

  10. Ion Coulomb Crystals

    E-Print Network [OSTI]

    Richard C. Thompson

    2014-11-18T23:59:59.000Z

    Ion Coulomb crystals (ICC), formed by atomic ions at low temperatures in radiofrequency and Penning ion traps, are structures that have remarkable properties and many applications. Images of Coulomb crystals are striking and reveal the crystal structure, which arises from a balance between the trapping forces acting on the ions and their mutual Coulomb repulsion. Applications of these structures range from frequency standards and quantum simulation through to measurement of the cross sections of chemical reactions of ions.

  11. Synthesis of carbon coated Li{sub 3}V{sub 2}(PO{sub 4}){sub 3}/reduced graphene oxide composite for high-performance lithium ion batteries

    SciTech Connect (OSTI)

    Wu, Keliang, E-mail: linxin66@126.com [Department of Petroleum and Chemical, Bayingolin Vocational and Technical College, Xinjiang Uygur Autonomous Region 841000 (China)] [Department of Petroleum and Chemical, Bayingolin Vocational and Technical College, Xinjiang Uygur Autonomous Region 841000 (China); Yang, Jinpeng [Department of Petroleum and Chemical, Bayingolin Vocational and Technical College, Xinjiang Uygur Autonomous Region 841000 (China)] [Department of Petroleum and Chemical, Bayingolin Vocational and Technical College, Xinjiang Uygur Autonomous Region 841000 (China)

    2013-02-15T23:59:59.000Z

    Graphical abstract: Display Omitted Highlights: ? Carbon coated LVP nanoparticles strongly anchored on rGO surface are prepared. ? LVP@C/rGO exhibits high electrical conductivity. ? LVP@C/rGO shows excellent cycleability and rate capability between 3.0 and 4.8 V. -- Abstract: The carbon coated Li{sub 3}V{sub 2}(PO{sub 4}){sub 3}/reduced graphene oxide (LVP@C/rGO) composite is successfully synthesized by a conventional solid-state reaction, which is easily scaled up. LVP grains coated with a thin layer (?8 nm) of carbon are adhered to the surface of the rGO layer and/or enwrapped into the rGO sheets, which can facilitate the fast charge transfer within the whole electrode and to the current collector. As a cathode material, the LVP@C/rGO electrode delivers an initial discharge capacity of 177 mAh g{sup ?1} at 0.5 C with capacity retention of 96% during the 50th cycle in a wide voltage range of 3.0–4.8 V. A superior rate capability is also achieved, e.g., exhibiting a discharge capacity of 96 mAh g{sup ?1} at a high C rate of 10 C.

  12. Fundamentals of Mercury Oxidation in Flue Gas

    SciTech Connect (OSTI)

    JoAnn Lighty; Geoffrey Silcox; Constance Senior; Joseph Helble; Balaji Krishnakumar

    2008-07-31T23:59:59.000Z

    The objective of this project was to understand the importance of and the contribution of gas-phase and solid-phase coal constituents in the mercury oxidation reactions. The project involved both experimental and modeling efforts. The team was comprised of the University of Utah, Reaction Engineering International, and the University of Connecticut. The objective was to determine the experimental parameters of importance in the homogeneous and heterogeneous oxidation reactions; validate models; and, improve existing models. Parameters studied include HCl, NO{sub x}, and SO{sub 2} concentrations, ash constituents, and temperature. The results suggested that homogeneous mercury oxidation is below 10% which is not consistent with previous data of others and work which was completed early in this research program. Previous data showed oxidation above 10% and up to 100%. However, the previous data are suspect due to apparent oxidation occurring within the sampling system where hypochlorite ion forms in the KCl impinger, which in turn oxidized mercury. Initial tests with entrained iron oxide particles injected into a flame reactor suggest that iron present on fly ash particle surfaces can promote heterogeneous oxidation of mercury in the presence of HCl under entrained flow conditions. Using the data generated above, with homogeneous reactions accounting for less than 10% of the oxidation, comparisons were made to pilot- and full-scale data. The results suggest that heterogeneous reactions, as with the case of iron oxide, and adsorption on solid carbon must be taking place in the full-scale system. Modeling of mercury oxidation using parameters from the literature was conducted to further study the contribution of homogeneous pathways to Hg oxidation in coal combustion systems. Calculations from the literature used rate parameters developed in different studies, in some cases using transition state theory with a range of approaches and basis sets, and in other cases using empirical approaches. To address this, rate constants for the entire 8-step homogeneous Hg oxidation sequence were developed using an internally consistent transition state approach. These rate constants when combined with the appropriate sub-mechanisms produced lower estimates of the overall extent of homogeneous oxidation, further suggesting that heterogeneous pathways play an important role in Hg oxidation in coal-fired systems.

  13. Asphalt Oxidation Kinetics and Pavement Oxidation Modeling

    E-Print Network [OSTI]

    Jin, Xin

    2012-07-16T23:59:59.000Z

    Most paved roads in the United States are surfaced with asphalt. These asphalt pavements suffer from fatigue cracking and thermal cracking, aggravated by the oxidation and hardening of asphalt. This negative impact of asphalt oxidation on pavement...

  14. Direct electrochemical reduction of metal-oxides

    DOE Patents [OSTI]

    Redey, Laszlo I. (Downers Grove, IL); Gourishankar, Karthick (Downers Grove, IL)

    2003-01-01T23:59:59.000Z

    A method of controlling the direct electrolytic reduction of a metal oxide or mixtures of metal oxides to the corresponding metal or metals. A non-consumable anode and a cathode and a salt electrolyte with a first reference electrode near the non-consumable anode and a second reference electrode near the cathode are used. Oxygen gas is produced and removed from the cell. The anode potential is compared to the first reference electrode to prevent anode dissolution and gas evolution other than oxygen, and the cathode potential is compared to the second reference electrode to prevent production of reductant metal from ions in the electrolyte.

  15. amicrowave-assisted h ion: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Edward T. 58 Effects of Fe(II)H2O2 Oxidation on Ubiquitin Conformers Measured by Ion Mobility-Mass Spectrometry Chemistry Websites Summary: modifications to proteins, lipids,...

  16. Lithium metal oxide electrodes for lithium cells and batteries

    DOE Patents [OSTI]

    Thackeray, Michael M.; Johnson, Christopher S.; Amine, Khalil; Kim, Jaekook

    2006-11-14T23:59:59.000Z

    A lithium metal oxide positive electrode for a non-aqueous lithium cell is disclosed. The cell is prepared in its initial discharged state and has a general formula xLiMO2.(1-x)Li2M'O3 in which 0ion with an average trivalent oxidation state and with at least one ion being Ni, and where M' is one or more ions with an average tetravalent oxidation state. Complete cells or batteries are disclosed with anode, cathode and electrolyte as are batteries of several cells connected in parallel or series or both.

  17. Lithium Metal Oxide Electrodes For Lithium Cells And Batteries

    DOE Patents [OSTI]

    Thackeray, Michael M. (Naperville, IL); Johnson, Christopher S. (Naperville, IL); Amine, Khalil (Downers Grove, IL); Kim, Jaekook (Naperville, IL)

    2004-01-20T23:59:59.000Z

    A lithium metal oxide positive electrode for a non-aqueous lithium cell is disclosed. The cell is prepared in its initial discharged state and has a general formula xLiMO.sub.2.(1-x)Li.sub.2 M'O.sub.3 in which 0ion with an average trivalent oxidation state and with at least one ion being Mn or Ni, and where M' is one or more ion with an average tetravalent oxidation state. Complete cells or batteries are disclosed with anode, cathode and electrolyte as are batteries of several cells connected in parallel or series or both.

  18. Lithium metal oxide electrodes for lithium cells and batteries

    DOE Patents [OSTI]

    Thackeray, Michael M. (Naperville, IL); Johnson, Christopher S. (Naperville, IL); Amine, Khalil (Oakbrook, IL)

    2008-12-23T23:59:59.000Z

    A lithium metal oxide positive electrode for a non-aqueous lithium cell is disclosed. The cell is prepared in its initial discharged state and has a general formula xLiMO.sub.2.(1-x)Li.sub.2M'O.sub.3 in which 0ion with an average trivalent oxidation state and with at least one ion being Mn or Ni, and where M' is one or more ion with an average tetravalent oxidation state. Complete cells or batteries are disclosed with anode, cathode and electrolyte as are batteries of several cells connected in parallel or series or both.

  19. Liners for ion transport membrane systems

    DOE Patents [OSTI]

    Carolan, Michael Francis (Allentown, PA); Miller, Christopher Francis (Macungie, PA)

    2010-08-10T23:59:59.000Z

    Ion transport membrane system comprising (a) a pressure vessel comprising an interior, an exterior, an inlet, an inlet conduit, an outlet, and an outlet conduit; (b) a plurality of planar ion transport membrane modules disposed in the interior of the pressure vessel and arranged in series, each membrane module comprising mixed metal oxide ceramic material and having an interior region and an exterior region, wherein the inlet and the outlet of the pressure vessel are in flow communication with exterior regions of the membrane modules; (c) a gas manifold having an interior surface wherein the gas manifold is in flow communication with the interior region of each of the planar ion transport membrane modules and with the exterior of the pressure vessel; and (d) a liner disposed within any of the inlet conduit, the outlet conduit, and the interior surface of the gas manifold.

  20. Broad beam ion implanter

    DOE Patents [OSTI]

    Leung, Ka-Ngo (Hercules, CA)

    1996-01-01T23:59:59.000Z

    An ion implantation device for creating a large diameter, homogeneous, ion beam is described, as well as a method for creating same, wherein the device is characterized by extraction of a diverging ion beam and its conversion by ion beam optics to an essentially parallel ion beam. The device comprises a plasma or ion source, an anode and exit aperture, an extraction electrode, a divergence-limiting electrode and an acceleration electrode, as well as the means for connecting a voltage supply to the electrodes.

  1. CONTROL-ORIENTED MODELING OF A SOLID-OXIDE FUEL CELL STACK USING AN LPV MODEL STRUCTURE

    E-Print Network [OSTI]

    Sanandaji, Borhan M.

    CONTROL-ORIENTED MODELING OF A SOLID-OXIDE FUEL CELL STACK USING AN LPV MODEL STRUCTURE Borhan M dynamic model of a solid oxide fuel cell stack. Using a detailed physical model as a starting point, we (usually air) on the cathode side. Solid-oxide fuel cells (SOFCs) utilize a ceramic oxygen-ion conducting

  2. Oxidation and characterization of FGD byproduct calcium sulfite and oxidized product

    E-Print Network [OSTI]

    Gupta, Anurag

    1993-01-01T23:59:59.000Z

    with absorbed sulfur dioxide, sulfite oxidation and CaSOs/CaSO4 crystallization. Calcium ion is formed during dissolution of calcium carbonate in water. z CaCO3 (s) ? -& CaCO3 (aq) (2-1) CaCO3 + H20 ? -& Ca~ + HCO3 + OH (2-2) Sulfur dioxide is absorbed... in the water and forms SO3= ion. SO2 (g) ? -& SO2 (aq) (2-3) SO2 (aq) + H20 ? -& H2SO3 ? -& HSO3- + H+ (2-4) HSO3- ? -& H+ + SO3= (2-5) The sulfite ions react with calcium ions to form calcium sulfite hemihydrate. Ca++ + SO3= + ? HpO ? -& CaSO3. ? HZO (s...

  3. Superconducting microfabricated ion traps

    E-Print Network [OSTI]

    Wang, Shannon Xuanyue

    We fabricate superconducting ion traps with niobium and niobium nitride and trap single [superscript 88]Sr ions at cryogenic temperatures. The superconducting transition is verified and characterized by measuring the ...

  4. ELECTRON SPECTROSCOPY STUDIES OF CLEAN OXIDE SURFACES, CHEMISORBED MOLECULES AND PHOTO-ASSISTED PROCESSES

    E-Print Network [OSTI]

    Lo, Wei Jen

    2011-01-01T23:59:59.000Z

    TITANIUM DIOXIDE (RUTILE) CRYSTAL SURFACES ABSTRACT Low-energytitanium film to -100 L oxygen at room temperature. Low energy (titanium ions with unusual oxidation states. Ultraviolet photoemission spectroscopy (UPS) and electron energy

  5. Single Ion Implantation

    ScienceCinema (OSTI)

    Thomas Schenkel

    2010-01-08T23:59:59.000Z

    On the equipment needed to implant ions in silicon and other materials. More information: http://newscenter.lbl.gov/f...

  6. Single Ion Implantation

    SciTech Connect (OSTI)

    Thomas Schenkel

    2008-10-21T23:59:59.000Z

    On the equipment needed to implant ions in silicon and other materials. More information: http://newscenter.lbl.gov/f...

  7. Photo-oxidation catalysts

    DOE Patents [OSTI]

    Pitts, J. Roland (Lakewood, CO); Liu, Ping (Irvine, CA); Smith, R. Davis (Golden, CO)

    2009-07-14T23:59:59.000Z

    Photo-oxidation catalysts and methods for cleaning a metal-based catalyst are disclosed. An exemplary catalyst system implementing a photo-oxidation catalyst may comprise a metal-based catalyst, and a photo-oxidation catalyst for cleaning the metal-based catalyst in the presence of light. The exposure to light enables the photo-oxidation catalyst to substantially oxidize absorbed contaminants and reduce accumulation of the contaminants on the metal-based catalyst. Applications are also disclosed.

  8. Lithium Ion Production NDE

    E-Print Network [OSTI]

    Lithium Ion Electrode Production NDE and QC Considerations David Wood, Debasish Mohanty, Jianlin Li, and Claus Daniel 12/9/13 EERE Quality Control Workshop #12;2 Presentation name Lithium Ion Electrode to be meaningful and provide electrode and cell QC. #12;3 Presentation name New Directions in Lithium Ion Electrode

  9. Lithium ion sources

    E-Print Network [OSTI]

    Roy, Prabir K.

    2014-01-01T23:59:59.000Z

    HIFAN 1866 Lithium ion sources by Prabir K. Roy, Wayne G.No. DE-AC02-05CH11231. Lithium ion sources Prabir K. RoyUSA Abstract A 10.9 cm diameter lithium alumino-silicate ion

  10. Applied Surface Science 323 (2014) 7177 Contents lists available at ScienceDirect

    E-Print Network [OSTI]

    Lin, Xi

    2014-01-01T23:59:59.000Z

    .8O3-i (LSCF-6428) were investigated. (0 0 1)-oriented LSCF-6428 thin films were deposited on lattice-i (LSCF-6428), is a commonly used perovskite-type material for cathodes in solid oxide fuel cells (SOFCs). The advantages of LSCF-6428 lie in its mixed ionic and electronic conductor (MIEC) behavior

  11. Lithium metal oxide electrodes for lithium batteries

    DOE Patents [OSTI]

    Thackeray, Michael M.; Johnson, Christopher S.; Amine, Khalil; Kang, Sun-Ho

    2010-06-08T23:59:59.000Z

    An uncycled preconditioned electrode for a non-aqueous lithium electrochemical cell including a lithium metal oxide having the formula xLi.sub.2-yH.sub.yO.xM'O.sub.2.(1-x)Li.sub.1-zH.sub.zMO.sub.2 in which 0ion with an average trivalent oxidation state selected from two or more of the first row transition metals or lighter metal elements in the periodic table, and M' is one or more ions with an average tetravalent oxidation state selected from the first and second row transition metal elements and Sn. The xLi.sub.2-yH.sub.y.xM'O.sub.2.(1-x)Li.sub.1-zH.sub.zMO.sub.2 material is prepared by preconditioning a precursor lithium metal oxide (i.e., xLi.sub.2M'O.sub.3.(1-x)LiMO.sub.2) with a proton-containing medium with a pH<7.0 containing an inorganic acid. Methods of preparing the electrodes are disclosed, as are electrochemical cells and batteries containing the electrodes.

  12. Silver manganese oxide electrodes for lithium batteries

    DOE Patents [OSTI]

    Thackeray, Michael M.; Vaughey, John T.; Dees, Dennis W.

    2006-05-09T23:59:59.000Z

    This invention relates to electrodes for non-aqueous lithium cells and batteries with silver manganese oxide positive electrodes, denoted AgxMnOy, in which x and y are such that the manganese ions in the charged or partially charged electrodes cells have an average oxidation state greater than 3.5. The silver manganese oxide electrodes optionally contain silver powder and/or silver foil to assist in current collection at the electrodes and to improve the power capability of the cells or batteries. The invention relates also to a method for preparing AgxMnOy electrodes by decomposition of a permanganate salt, such as AgMnO4, or by the decomposition of KMnO4 or LiMnO4 in the presence of a silver salt.

  13. Superconducting microfabricated ion traps

    E-Print Network [OSTI]

    Shannon X. Wang; Yufei Ge; Jaroslaw Labaziewicz; Eric Dauler; Karl Berggren; Isaac L. Chuang

    2010-12-14T23:59:59.000Z

    We fabricate superconducting ion traps with niobium and niobium nitride and trap single 88Sr ions at cryogenic temperatures. The superconducting transition is verified and characterized by measuring the resistance and critical current using a 4-wire measurement on the trap structure, and observing change in the rf reflection. The lowest observed heating rate is 2.1(3) quanta/sec at 800 kHz at 6 K and shows no significant change across the superconducting transition, suggesting that anomalous heating is primarily caused by noise sources on the surface. This demonstration of superconducting ion traps opens up possibilities for integrating trapped ions and molecular ions with superconducting devices.

  14. Method for preparing hydrous iron oxide gels and spherules

    DOE Patents [OSTI]

    Collins, Jack L.; Lauf, Robert J.; Anderson, Kimberly K.

    2003-07-29T23:59:59.000Z

    The present invention is directed to methods for preparing hydrous iron oxide spherules, hydrous iron oxide gels such as gel slabs, films, capillary and electrophoresis gels, iron monohydrogen phosphate spherules, hydrous iron oxide spherules having suspendable particles homogeneously embedded within to form composite sorbents and catalysts, iron monohydrogen phosphate spherules having suspendable particles of at least one different sorbent homogeneously embedded within to form a composite sorbent, iron oxide spherules having suspendable particles homogeneously embedded within to form a composite of hydrous iron oxide fiber materials, iron oxide fiber materials, hydrous iron oxide fiber materials having suspendable particles homogeneously embedded within to form a composite, iron oxide fiber materials having suspendable particles homogeneously embedded within to form a composite, dielectric spherules of barium, strontium, and lead ferrites and mixtures thereof, and composite catalytic spherules of barium or strontium ferrite embedded with oxides of Mg, Zn, Pb, Ce and mixtures thereof. These variations of hydrous iron oxide spherules and gel forms prepared by the gel-sphere, internal gelation process offer more useful forms of inorganic ion exchangers, catalysts, getters, dielectrics, and ceramics.

  15. Ion cyclotron resonance cell

    DOE Patents [OSTI]

    Weller, R.R.

    1995-02-14T23:59:59.000Z

    An ion cyclotron resonance cell is disclosed having two adjacent sections separated by a center trapping plate. The first section is defined by the center trapping plate, a first end trapping plate, and excitation and detector electrodes. The second section includes a second end trapping plate spaced apart from the center plate, a mirror, and an analyzer. The analyzer includes a wavelength-selective light detector, such as a detector incorporating an acousto-optical device (AOD) and a photodetector. One or more ion guides, grounded plates with holes for the ion beam, are positioned within the vacuum chamber of the mass spectrometer between the ion source and the cell. After ions are trapped and analyzed by ion cyclotron resonance techniques in the first section, the ions of interest are selected according to their mass and passed into the second section for optical spectroscopic studies. The trapped ions are excited by light from a laser and caused thereby to fluoresce. The fluorescent light emitted by the excited ions is reflected by the mirror and directed onto the detector. The AOD is scanned, and the photodetector output is recorded and analyzed. The ions remain in the second section for an extended period, enabling multiple studies to be carried out on the same ensemble of ions. 5 figs.

  16. Ion cyclotron resonance cell

    DOE Patents [OSTI]

    Weller, Robert R. (Aiken, SC)

    1995-01-01T23:59:59.000Z

    An ion cyclotron resonance cell having two adjacent sections separated by a center trapping plate. The first section is defined by the center trapping plate, a first end trapping plate, and excitation and detector electrodes. The second section includes a second end trapping plate spaced apart from the center plate, a mirror, and an analyzer. The analyzer includes a wavelength-selective light detector, such as a detector incorporating an acousto-optical device (AOD) and a photodetector. One or more ion guides, grounded plates with holes for the ion beam, are positioned within the vacuum chamber of the mass spectrometer between the ion source and the cell. After ions are trapped and analyzed by ion cyclotron resonance techniques in the first section, the ions of interest are selected according to their mass and passed into the second section for optical spectroscopic studies. The trapped ions are excited by light from a laser and caused thereby to fluoresce. The fluorescent light emitted by the excited ions is reflected by the mirror and directed onto the detector. The AOD is scanned, and the photodetector output is recorded and analyzed. The ions remain in the second section for an extended period, enabling multiple studies to be carried out on the same ensemble of ions.

  17. Microfabricated ion trap array

    DOE Patents [OSTI]

    Blain, Matthew G. (Albuquerque, NM); Fleming, James G. (Albuquerque, NM)

    2006-12-26T23:59:59.000Z

    A microfabricated ion trap array, comprising a plurality of ion traps having an inner radius of order one micron, can be fabricated using surface micromachining techniques and materials known to the integrated circuits manufacturing and microelectromechanical systems industries. Micromachining methods enable batch fabrication, reduced manufacturing costs, dimensional and positional precision, and monolithic integration of massive arrays of ion traps with microscale ion generation and detection devices. Massive arraying enables the microscale ion traps to retain the resolution, sensitivity, and mass range advantages necessary for high chemical selectivity. The reduced electrode voltage enables integration of the microfabricated ion trap array with on-chip circuit-based rf operation and detection electronics (i.e., cell phone electronics). Therefore, the full performance advantages of the microfabricated ion trap array can be realized in truly field portable, handheld microanalysis systems.

  18. Oxidation of propylene over copper oxide catalysts

    E-Print Network [OSTI]

    Billingsley, David Stuart

    1958-01-01T23:59:59.000Z

    results were obtained using an asbestos supported CuO-Cr203 catalyst. Venkataramam and his co-workers (66) studied the catalytic oxidation of ethylene to ethylene oxide by the fluidized bed technique using a static bed of catalyst. Precipitated Ag20... in the air-ethylene ratio to maintain good yields of ethylene oxide. Wan (68) reported the oxidation of ethylene to acetaldehyde by use of a silver catalyst in a 5/16 dnch inner diameter stainless steel tube with a catalyst bed up to 30. 3 centimeters...

  19. Cerium Oxide Coating for Oxidation Reduction

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Award In order to produce power more efficiently and cleanly, the next generation of power plant boilers, turbines, solid oxide fuel cells (SOFCs) and other essential...

  20. Polymer graphite composite anodes for Li-ion batteries

    E-Print Network [OSTI]

    Popov, Branko N.

    Polymer graphite composite anodes for Li-ion batteries Basker Veeraraghavan, Bala Haran, Ralph for the graphite particles by in-situ polymerization #12;Experimental Preparation of PPy/Graphite composites Dropwise addition of pyrrole into aqueous slurry of graphite at 0 °C with nitric acid acting as an oxidizer

  1. Electrostatic Control of Ions and Molecules in Nanofluidic Transistors

    E-Print Network [OSTI]

    Yang, Peidong

    Electrostatic Control of Ions and Molecules in Nanofluidic Transistors Rohit Karnik,,| Rong Fan report a nanofluidic transistor based on a metal-oxide-solution (MOSol) system that is similar to a metal the ionic conductance. Our results illustrate the efficacy of field-effect control in nanofluidics, which

  2. Lithium metal oxide electrodes for lithium cells and batteries

    DOE Patents [OSTI]

    Thackeray, Michael M. (Naperville, IL); Johnson, Christopher S. (Naperville, IL); Amine, Khalil (Downers Grove, IL); Kim, Jaekook (Naperville, IL)

    2004-01-13T23:59:59.000Z

    A lithium metal oxide positive electrode for a non-aqueous lithium cell is disclosed. The cell is prepared in its initial discharged state and has a general formula xLiMO.sub.2.(1-x)Li.sub.2 M'O.sub.3 in which 0ion with at least one ion being Mn or Ni, and where M' is one or more tetravalent ion. Complete cells or batteries are disclosed with anode, cathode and electrolyte as are batteries of several cells connected in parallel or series or both.

  3. ION-BY-ION COOLING EFFICIENCIES

    SciTech Connect (OSTI)

    Gnat, Orly [Theoretical Astrophysics, California Institute of Technology, MC 350-17, Pasadena, CA 91125 (United States) and Racah Institute of Physics, Hebrew University, 91904 Jerusalem (Israel); Ferland, Gary J., E-mail: orlyg@tapir.caltech.edu [Department of Physics and Astronomy, University of Kentucky, Lexington, KY 40506 (United States)

    2012-03-01T23:59:59.000Z

    We present ion-by-ion cooling efficiencies for low-density gas. We use Cloudy (version 10.00) to estimate the cooling efficiencies for each ion of the first 30 elements (H-Zn) individually. We present results for gas temperatures between 10{sup 4} and 10{sup 8} K, assuming low densities and optically thin conditions. When nonequilibrium ionization plays a significant role the ionization states deviate from those that obtain in collisional ionization equilibrium (CIE), and the local cooling efficiency at any given temperature depends on specific nonequilibrium ion fractions. The results presented here allow for an efficient estimate of the total cooling efficiency for any ionic composition. We also list the elemental cooling efficiencies assuming CIE conditions. These can be used to construct CIE cooling efficiencies for non-solar abundance ratios or to estimate the cooling due to elements not included in any nonequilibrium computation. All the computational results are listed in convenient online tables.

  4. Normal coordinate analysis of trimethyl-antimony oxide 

    E-Print Network [OSTI]

    Morris, Wayne A

    1974-01-01T23:59:59.000Z

    line from a Coherent Radiati. on model 52 argon ion laser. Pre aration of S ectrosco ic Sam les (a) rid-infrared spectra Mid-infrared spectra were recorded for sample. prepared in KI pellets. The KI was finely ground and dried in an oven... and using the 5145 A line of an argon laser. Results (a) Spectra Figures 1 and 2 show the mid-infrared spectra of trimethylantimony oxide and trimethylantimony oxide-d recorded as solids in potassium iodide 9 pellets. Figures 3 and 4 show the spectra...

  5. Modified cermet fuel electrodes for solid oxide electrochemical cells

    DOE Patents [OSTI]

    Ruka, Roswell J. (Churchill Boro, PA); Spengler, Charles J. (Murrysville, PA)

    1991-01-01T23:59:59.000Z

    An exterior porous electrode (10), bonded to a solid oxygen ion conducting electrolyte (13) which is in contact with an interior electrode (14), contains coarse metal particles (12) of nickel and/or cobalt, having diameters from 3 micrometers to 35 micrometers, where the coarse particles are coated with a separate, porous, multiphase layer (17) containing fine metal particles of nickel and/or cobalt (18), having diameters from 0.05 micrometers to 1.75 micrometers and conductive oxide (19) selected from cerium oxide, doped cerium oxide, strontium titanate, doped strontium titanate and mixtures thereof.

  6. High-capacity Li2Sgraphene oxide composite cathodes with stable cycling performance

    E-Print Network [OSTI]

    Cui, Yi

    oxide onto the surface of Li2S through favorable lithium­oxygen interactions helps to minimize and grid energy storage applica- tions.1­6 Although rechargeable lithium-ion batteries are widely used-mentioned applications.1­6 The major limiting factor in lithium-ion batteries today is the low theoretical capacity

  7. Charge exchange molecular ion source

    DOE Patents [OSTI]

    Vella, Michael C.

    2003-06-03T23:59:59.000Z

    Ions, particularly molecular ions with multiple dopant nucleons per ion, are produced by charge exchange. An ion source contains a minimum of two regions separated by a physical barrier and utilizes charge exchange to enhance production of a desired ion species. The essential elements are a plasma chamber for production of ions of a first species, a physical separator, and a charge transfer chamber where ions of the first species from the plasma chamber undergo charge exchange or transfer with the reactant atom or molecules to produce ions of a second species. Molecular ions may be produced which are useful for ion implantation.

  8. Methods of making metal oxide nanostructures and methods of controlling morphology of same

    DOE Patents [OSTI]

    Wong, Stanislaus S; Hongjun, Zhou

    2012-11-27T23:59:59.000Z

    The present invention includes a method of producing a crystalline metal oxide nanostructure. The method comprises providing a metal salt solution and providing a basic solution; placing a porous membrane between the metal salt solution and the basic solution, wherein metal cations of the metal salt solution and hydroxide ions of the basic solution react, thereby producing a crystalline metal oxide nanostructure.

  9. Sulfur control in ion-conducting membrane systems

    DOE Patents [OSTI]

    Stein, VanEric Edward; Richards, Robin Edward; Brengel, David Douglas; Carolan, Michael Francis

    2003-08-05T23:59:59.000Z

    A method for controlling the sulfur dioxide partial pressure in a pressurized, heated, oxygen-containing gas mixture which is contacted with an ion-conducting metallic oxide membrane which permeates oxygen ions. The sulfur dioxide partial pressure in the oxygen-depleted non-permeate gas from the membrane module is maintained below a critical sulfur dioxide partial pressure, p.sub.SO2 *, to protect the membrane material from reacting with sulfur dioxide and reducing the oxygen flux of the membrane. Each ion-conducting metallic oxide material has a characteristic critical sulfur dioxide partial pressure which is useful in determining the required level of sulfur removal from the feed gas and/or from the fuel gas used in a direct-fired feed gas heater.

  10. Niobium oxide compositions and methods for using same

    DOE Patents [OSTI]

    Goodenough, John B; Han, Jian-Tao

    2014-02-11T23:59:59.000Z

    The disclosure relates a niobium oxide useful in anodes of secondary lithium ion batteries. Such niobium oxide has formula Li.sub.xM.sub.1-yNb.sub.yNb.sub.2O.sub.7, wherein 0.ltoreq.x.ltoreq.3, 0.ltoreq.y.ltoreq.1, and M represents Ti or Zr. The niobium oxide may be in the form of particles, which may be carbon coated. The disclosure also relates to an electrode composition containing at least one or more niobium oxides of formula Li.sub.xM.sub.1-yNb.sub.yNb.sub.2O.sub.7. The disclosure further relates to electrodes, such as anodes, and batteries containing at least one or more niobium oxides of formula Li.sub.xM.sub.1-yNb.sub.yNb.sub.2O.sub.7. Furthermore, the disclosure relates to methods of forming the above.

  11. Damage Profile and Ion Distribution of Slow Heavy Ions in Compounds...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Profile and Ion Distribution of Slow Heavy Ions in Compounds. Damage Profile and Ion Distribution of Slow Heavy Ions in Compounds. Abstract: Slow heavy ions inevitably produce a...

  12. Ion beam generating apparatus

    DOE Patents [OSTI]

    Brown, Ian G. (1088 Woodside Rd., Berkeley, CA 94708); Galvin, James (2 Commodore #276, Emeryville, CA 94608)

    1987-01-01T23:59:59.000Z

    An ion generating apparatus utilizing a vacuum chamber, a cathode and an anode in the chamber. A source of electrical power produces an arc or discharge between the cathode and anode. The arc is sufficient to vaporize a portion of the cathode to form a plasma. The plasma is directed to an extractor which separates the electrons from the plasma, and accelerates the ions to produce an ion beam.

  13. Ion beam generating apparatus

    DOE Patents [OSTI]

    Brown, I.G.; Galvin, J.

    1987-12-22T23:59:59.000Z

    An ion generating apparatus utilizing a vacuum chamber, a cathode and an anode in the chamber. A source of electrical power produces an arc or discharge between the cathode and anode. The arc is sufficient to vaporize a portion of the cathode to form a plasma. The plasma is directed to an extractor which separates the electrons from the plasma, and accelerates the ions to produce an ion beam. 10 figs.

  14. Collection of ions

    DOE Patents [OSTI]

    Orr, Christopher Henry (Calderbridge, GB); Luff, Craig Janson (Calderbridge, GB); Dockray, Thomas (Calderbridge, GB); Macarthur, Duncan Whittemore (Los Alamos, NM); Bounds, John Alan (Los Alamos, NM); Koster, James E. (Los Alamos, NM)

    2001-01-01T23:59:59.000Z

    The apparatus and method provide an improved technique for detecting ions as the area from which ions are attracted to a detector is increased, consequently increasing the number of ions detected. This is achieved by providing the outer electrodes of the detector connected to the electrical potential, together with alternate intermediate electrodes. The other intermediate electrodes and preferably the housing are grounded. The technique renders such detection techniques more sensitive and gives them a lower threshold at which they can function.

  15. Correlation ion mobility spectroscopy

    DOE Patents [OSTI]

    Pfeifer, Kent B. (Los Lunas, NM); Rohde, Steven B. (Corrales, NM)

    2008-08-26T23:59:59.000Z

    Correlation ion mobility spectrometry (CIMS) uses gating modulation and correlation signal processing to improve IMS instrument performance. Closely spaced ion peaks can be resolved by adding discriminating codes to the gate and matched filtering for the received ion current signal, thereby improving sensitivity and resolution of an ion mobility spectrometer. CIMS can be used to improve the signal-to-noise ratio even for transient chemical samples. CIMS is especially advantageous for small geometry IMS drift tubes that can otherwise have poor resolution due to their small size.

  16. THE MICROSTRUCTURAL LOCATION OF THE INTERGRANULAR METAL OXIDE PHASE IN A ZINC OXIDE VARISTOR

    E-Print Network [OSTI]

    Clarke, D. E

    2011-01-01T23:59:59.000Z

    OXIDE PHASE IN A ZINC OXIDE VARISTOR MICROSI'RUCTIJRALMETAL OXIDE PHASE IN A ZINC OXIDE VARISTOR David R. Clarke

  17. Methane oxidation over dual redox catalysts

    SciTech Connect (OSTI)

    Klier, K.; Herman, R.G.; Sojka, Z.; DiCosimo, J.I.; DeTavernier, S.

    1992-06-01T23:59:59.000Z

    Catalytic oxidation of methane to partial oxidation products, primarily formaldehyde and C[sub 2] hydrocarbons, was found to be directed by the catalyst used. In this project, it was discovered that a moderate oxidative coupling catalyst for C[sub 2] hydrocarbons, zinc oxide, is modified by addition of small amounts of Cu and Fe dopants to yield fair yields of formaldehyde. A similar effect was observed with Cu/Sn/ZnO catalysts, and the presence of a redox Lewis acid, Fe[sup III] or Sn[sup IV], was found to be essential for the selectivity switch from C[sub 2] coupling products to formaldehyde. The principle of double doping with an oxygen activator (Cu) and the redox Lewis acid (Fe, Sn) was pursued further by synthesizing and testing the CuFe-ZSM-5 zeolite catalyst. The Cu[sup II](ion exchanged) Fe[sup III](framework)-ZSM-5 also displayed activity for formaldehyde synthesis, with space time yields exceeding 100 g/h-kg catalyst. However, the selectivity was low and earlier claims in the literature of selective oxidation of methane to methanol over CuFe-ZSM-5 were not reproduced. A new active and selective catalytic system (M=Sb,Bi,Sn)/SrO/La[sub 2]O[sub 3] has been discovered for potentially commercially attractive process for the conversion of methane to C[sub 2] hydrocarbons, (ii) a new principle has been demonstrated for selectivity switching from C[sub 2] hydrocarbon products to formaldehyde in methane oxidations over Cu,Fe-doped zinc oxide and ZSM-5, and (iii) a new approach has been initiated for using ultrafine metal dispersions for low temperature activation of methane for selective conversions. Item (iii) continues being supported by AMOCO while further developments related to items (i) and (ii) are the objective of our continued effort under the METC-AMOCO proposed joint program.

  18. Plasma ion sources and ion beam technology in microfabrications

    E-Print Network [OSTI]

    Ji, Lili

    2007-01-01T23:59:59.000Z

    in the right chamber (ion chamber) are confined in their ownwatts and that on the ion chamber is 50 watts. A permanent-column and the ion source chamber. The simulation is

  19. Improved hydrous oxide ion-exchange compound catalysts

    DOE Patents [OSTI]

    Dosch, R.G.; Stephens, H.P.

    1986-04-09T23:59:59.000Z

    Disclosed is a catalytic material of improved activity which comprises a hydrous, alkali metal or alkaline earth metal or quaternary ammonium titanate, zirconate, niobate, or tantalate, in which the metal or ammonium cations have been exchanged with a catalytically effective quantity of a catalyst metal, and which has been subsequently treated with a solution of a Bronsted acid.

  20. Microfabricated cylindrical ion trap

    DOE Patents [OSTI]

    Blain, Matthew G.

    2005-03-22T23:59:59.000Z

    A microscale cylindrical ion trap, having an inner radius of order one micron, can be fabricated using surface micromachining techniques and materials known to the integrated circuits manufacturing and microelectromechanical systems industries. Micromachining methods enable batch fabrication, reduced manufacturing costs, dimensional and positional precision, and monolithic integration of massive arrays of ion traps with microscale ion generation and detection devices. Massive arraying enables the microscale cylindrical ion trap to retain the resolution, sensitivity, and mass range advantages necessary for high chemical selectivity. The microscale CIT has a reduced ion mean free path, allowing operation at higher pressures with less expensive and less bulky vacuum pumping system, and with lower battery power than conventional- and miniature-sized ion traps. The reduced electrode voltage enables integration of the microscale cylindrical ion trap with on-chip integrated circuit-based rf operation and detection electronics (i.e., cell phone electronics). Therefore, the full performance advantages of microscale cylindrical ion traps can be realized in truly field portable, handheld microanalysis systems.

  1. Relativistic heavy ion research

    SciTech Connect (OSTI)

    Nagamiya, Shoji.

    1992-01-01T23:59:59.000Z

    This report discusses the following topics: antiproton production; Bose-Einstein correlations; high-transverse momentum spectra; strangeness enhancement in heavy ion collisions; search for rare negative secondaries of antiprotons and antinuclei produced in heavy ion collisions; quark matter; and time-of-flight systems test at Brookhaven AGS. (LSP).

  2. Ion-beam technologies

    SciTech Connect (OSTI)

    Fenske, G.R. [Argonne National Lab., IL (United States)

    1993-01-01T23:59:59.000Z

    This compilation of figures and diagrams reviews processes for depositing diamond/diamond-like carbon films. Processes addressed are chemical vapor deposition (HFCVD, PACVD, etc.), plasma vapor deposition (plasma sputtering, ion beam sputtering, evaporation, etc.), low-energy ion implantation, and hybrid processes (biased sputtering, IBAD, biased HFCVD, etc.). The tribological performance of coatings produced by different means is discussed.

  3. Comparison of the Catalytic Oxidation Reaction on Graphene Oxide and Reduced Graphene Oxide

    E-Print Network [OSTI]

    Kim, Sehun

    Comparison of the Catalytic Oxidation Reaction on Graphene Oxide and Reduced Graphene Oxide Laboratory (PAL), Pohang 790-784, Republic of Korea ABSTRACT: The capacities of graphene oxide (GO) and reduced graphene oxide (rGO) films grown on silicon substrate to cause the aniline to azobenzene oxidation

  4. Extracting metal ions with diphosphonic acid, or derivative thereof

    DOE Patents [OSTI]

    Horwitz, E.P.; Gatrone, R.C.; Nash, K.L.

    1994-07-26T23:59:59.000Z

    Thermodynamically-unstable complexing agents which are diphosphonic acids and diphosphonic acid derivatives (or sulfur containing analogs), like carboxyhydroxymethanediphosphonic acid and vinylidene-1,1-diphosphonic acid, are capable of complexing with metal ions, and especially metal ions in the II, III, IV, V and VI oxidation states, to form stable, water-soluble metal ion complexes in moderately alkaline to highly-acidic media. However, the complexing agents can be decomposed, under mild conditions, into non-organic compounds which, for many purposes are environmentally-nondamaging compounds thereby degrading the complex and releasing the metal ion for disposal or recovery. Uses for such complexing agents as well as methods for their manufacture are also described. 1 fig.

  5. HEAVY-ION RADIOGRAPHY AND HEAVY-ION COMPUTED TOMOGRAPHY

    E-Print Network [OSTI]

    Fabrikant, J.I.

    2010-01-01T23:59:59.000Z

    RADIOGRAPHY AND HEAVY-ION COMPUTED TOMOGRAPHY 1,2 Jacob I .RADIOGRAPHY AND HEAVY-ION COMPUTED TOMOGRAPHY J I Fabrikant,

  6. Ion mobility sensor system

    DOE Patents [OSTI]

    Xu, Jun; Watson, David B.; Whitten, William B.

    2013-01-22T23:59:59.000Z

    An ion mobility sensor system including an ion mobility spectrometer and a differential mobility spectrometer coupled to the ion mobility spectrometer. The ion mobility spectrometer has a first chamber having first end and a second end extending along a first direction, and a first electrode system that generates a constant electric field parallel to the first direction. The differential mobility spectrometer includes a second chamber having a third end and a fourth end configured such that a fluid may flow in a second direction from the third end to the fourth end, and a second electrode system that generates an asymmetric electric field within an interior of the second chamber. Additionally, the ion mobility spectrometer and the differential mobility spectrometer form an interface region. Also, the first end and the third end are positioned facing one another so that the constant electric field enters the third end and overlaps the fluid flowing in the second direction.

  7. Oxidation Resistant Graphite Studies

    SciTech Connect (OSTI)

    W. Windes; R. Smith

    2014-07-01T23:59:59.000Z

    The Very High Temperature Reactor (VHTR) Graphite Research and Development Program is investigating doped nuclear graphite grades exhibiting oxidation resistance. During a oxygen ingress accident the oxidation rates of the high temperature graphite core region would be extremely high resulting in significant structural damage to the core. Reducing the oxidation rate of the graphite core material would reduce the structural effects and keep the core integrity intact during any air-ingress accident. Oxidation testing of graphite doped with oxidation resistant material is being conducted to determine the extent of oxidation rate reduction. Nuclear grade graphite doped with varying levels of Boron-Carbide (B4C) was oxidized in air at nominal 740°C at 10/90% (air/He) and 100% air. The oxidation rates of the boronated and unboronated graphite grade were compared. With increasing boron-carbide content (up to 6 vol%) the oxidation rate was observed to have a 20 fold reduction from unboronated graphite. Visual inspection and uniformity of oxidation across the surface of the specimens were conducted. Future work to determine the remaining mechanical strength as well as graphite grades with SiC doped material are discussed.

  8. Influence of pH condition on colloidal suspension of exfoliated graphene oxide by electrostatic repulsion

    SciTech Connect (OSTI)

    Meng, Long-Yue [Department of Chemistry, Inha University, 253 Nam-gu, Incheon 402-751 (Korea, Republic of); Park, Soo-Jin, E-mail: sjpark@inha.ac.kr [Department of Chemistry, Inha University, 253 Nam-gu, Incheon 402-751 (Korea, Republic of)

    2012-02-15T23:59:59.000Z

    A facile chemical process is described to produce graphene oxide utilizing a zwitterions amino acid intermediate from graphite oxide sheets. 11-aminoundecanoic acid molecules were protonated to intercalate molecules into the graphite oxide sheets to achieve ion exchange, and the carboxyl groups were then ionized in a NaOH solution to exfoliate the graphite oxide sheets. In this way, the produced graphene oxide nanosheets were stably dispersed in water. The delaminated graphene nanosheets were confirmed by XRD, AFM, and TEM. XRD patterns indicated the d{sub 002}-spacing of the graphite greatly increased from 0.380 nm and 0.870 nm. AFM and TEM images showed that the ordered graphite crystal structure of graphene nanosheets was effectively exfoliated by this method. The prepared graphene nanosheets films showed 87.1% transmittance and a sheet resistance of 2.1 Multiplication-Sign 10{sup 3} {Omega}/square. - Graphical abstract: A stable graphene oxide suspension could be quickly prepared by exfoliating a graphite oxide suspension by a host-guest electrostatic repulsion in aqueous solution. Highlights: Black-Right-Pointing-Pointer Graphene nanosheets were prepared by a zwitterions amino acid intermediate from graphite oxide. Black-Right-Pointing-Pointer 11-aminoundecanoic acid was protonated to intercalate molecules into the graphene oxide to achieve ion exchange. Black-Right-Pointing-Pointer The d{sub 002}-spacing of the graphite oxide greatly increased from 0.330 nm to 0.415 nm after 11-aminoundecanoic acid treatment.

  9. Mn3O4-Graphene Hybrid as a High-Capacity Anode Material for Lithium Ion Hailiang Wang,,

    E-Print Network [OSTI]

    Cui, Yi

    Mn3O4-Graphene Hybrid as a High-Capacity Anode Material for Lithium Ion Batteries Hailiang Wang hybrid materials of Mn3O4 nanoparticles on reduced graphene oxide (RGO) sheets for lithium ion battery stability, owing to the intimate interactions between the graphene substrates and the Mn3O4 nanoparticles

  10. Performance study of commercial LiCoO2 and spinel-based Li-ion cells

    E-Print Network [OSTI]

    Popov, Branko N.

    -ion cells and Sony 18650 cells using non-stoichiometric spinel and LiCoO2, respectively, as positive at the cathode and loss of active material at both electrodes due to electrolyte oxidation. For the Sony cells Science B.V. All rights reserved. Keywords: Li-ion cells; LiCoO2; Cell-Batt1 ; Capacity fade; Sony 18650

  11. Kinetics-controlled growth of aligned mesocrystalline SnO2 nanorod arrays for lithium-ion batteries with

    E-Print Network [OSTI]

    Qi, Limin

    Kinetics-controlled growth of aligned mesocrystalline SnO2 nanorod arrays for lithium-ion batteries structures, lithium-ion batteries ABSTRACT A general method for facile kinetics-controlled growth of aligned foil, as well as many other inert substrates such as fluoride-doped tin oxide (FTO), Si, graphite

  12. METAL OXIDE NANOPARTICLES

    SciTech Connect (OSTI)

    FERNANDEZ-GARCIA,M.; RODGRIGUEZ, J.A.

    2007-10-01T23:59:59.000Z

    This chapter covers the fundamental science, synthesis, characterization, physicochemical properties and applications of oxide nanomaterials. Explains fundamental aspects that determine the growth and behavior of these systems, briefly examines synthetic procedures using bottom-up and top-down fabrication technologies, discusses the sophisticated experimental techniques and state of the art theory results used to characterize the physico-chemical properties of oxide solids and describe the current knowledge concerning key oxide materials with important technological applications.

  13. Relating to ion detection

    DOE Patents [OSTI]

    Orr, Christopher Henry (Calderbridge, GB); Luff, Craig Janson (Calderbridge, GB); Dockray, Thomas (Calderbridge, GB); Macarthur, Duncan Whittemore (Los Alamos, NM)

    2001-01-01T23:59:59.000Z

    The apparatus and method provide a technique for improving detection of alpha and/or beta emitting sources on items or in locations using indirect means. The emission forms generate ions in a medium surrounding the item or location and the medium is then moved to a detecting location where the ions are discharged to give a measure of the emission levels. To increase the level of ions generated and render the system particularly applicable for narrow pipes and other forms of conduits, the medium pressure is increased above atmospheric pressure. STATEMENT REGARDING FEDERALLY SPONSORED RESEARCH OR DEVELOPMENT

  14. Barium oxide, calcium oxide, magnesia, and alkali oxide free glass

    DOE Patents [OSTI]

    Lu, Peizhen Kathy; Mahapatra, Manoj Kumar

    2013-09-24T23:59:59.000Z

    A glass composition consisting essentially of about 10-45 mole percent of SrO; about 35-75 mole percent SiO.sub.2; one or more compounds from the group of compounds consisting of La.sub.2O.sub.3, Al.sub.2O.sub.3, B.sub.2O.sub.3, and Ni; the La.sub.2O.sub.3 less than about 20 mole percent; the Al.sub.2O.sub.3 less than about 25 mole percent; the B.sub.2O.sub.3 less than about 15 mole percent; and the Ni less than about 5 mole percent. Preferably, the glass is substantially free of barium oxide, calcium oxide, magnesia, and alkali oxide. Preferably, the glass is used as a seal in a solid oxide fuel/electrolyzer cell (SOFC) stack. The SOFC stack comprises a plurality of SOFCs connected by one or more interconnect and manifold materials and sealed by the glass. Preferably, each SOFC comprises an anode, a cathode, and a solid electrolyte.

  15. Mixed oxide solid solutions

    DOE Patents [OSTI]

    Magno, Scott (Dublin, CA); Wang, Ruiping (Fremont, CA); Derouane, Eric (Liverpool, GB)

    2003-01-01T23:59:59.000Z

    The present invention is a mixed oxide solid solution containing a tetravalent and a pentavalent cation that can be used as a support for a metal combustion catalyst. The invention is furthermore a combustion catalyst containing the mixed oxide solid solution and a method of making the mixed oxide solid solution. The tetravalent cation is zirconium(+4), hafnium(+4) or thorium(+4). In one embodiment, the pentavalent cation is tantalum(+5), niobium(+5) or bismuth(+5). Mixed oxide solid solutions of the present invention exhibit enhanced thermal stability, maintaining relatively high surface areas at high temperatures in the presence of water vapor.

  16. Recent developments in zinc oxide target chemistry

    SciTech Connect (OSTI)

    Heaton, R.C.; Taylor, W.A.; Phillips, D.R.; Jamriska, D.J. Sr.; Garcia, J.B.

    1994-04-01T23:59:59.000Z

    Zinc oxide targets irradiated with high energy protons at the Los Alamos Meson Physics Facility (LAMPF) contain a number of radioactive spallation products in quantities large enough to warrant recovery. This paper describes methods for recovering {sup 7}Be, {sup 46}Sc, and {sup 48}V from such targets and offers suggestions on possible ways to recover additional isotopes. The proposed methods are based on traditional precipitation and ion exchange techniques, are readily adaptable to hot cell use, and produce no hazardous waste components. The products are obtained in moderate to high yields and have excellent radiopurity.

  17. Wet oxidation of oil-bearing sulfide wastes

    SciTech Connect (OSTI)

    Miller, R.L.; Hotz, N.J.

    1991-01-01T23:59:59.000Z

    Oil-bearing metal sulfide sludges produced in treatment of an industrial wastewater, which includes plating wastes, have yielded to treatment by electrooxidation and hydrogen peroxide processes. The oxidation can be controlled to be mild enough to avoid decomposition of the organic phase while oxidizing the sulfides to sulfates. The pH is controlled to near neutral conditions where iron, aluminum and chromium(III) precipitate as hydrous oxides. Other metals, such as lead and barium, may be present as sulfate precipitates with limited solubility, while metals such as nickel and cadmium would be present as complexed ions in a sulfate solution. The oxidations were found to proceed smoothly, without vigorous reaction; heat liberation was minimal. 2 refs., 12 figs.

  18. Computational studies of polysiloxanes : oxidation potentials and decomposition reactions.

    SciTech Connect (OSTI)

    Assary, R. S.; Curtiss, L. A.; Redfern, P. C.; Zhang, Z.; Amine, K. (Center for Nanoscale Materials); ( CSE); ( MSD); (Northwestern Univ.)

    2011-06-23T23:59:59.000Z

    Silicon-containing solvents have tremendous potential for application as electrolytes for electrical energy storage devices such as lithium-ion (air) batteries and supercapacitors. Quantum chemical methods were employed to investigate trends in oxidation potentials and decomposition reactions of a series of polysiloxanes. Various electron-donating and -withdrawing substituents can be used to tune the oxidation potential in shorter chain siloxanes but not in longer ones. Decomposition reactions of siloxanes in their oxidized states were investigated and compared against their carbon analogues. These studies suggest that the Si-O group provides added stability for siloxanes over their carbon analogues. Computational studies have also been performed for various disiloxanes and siloxanes with spacer groups to understand their thermochemical stability and oxidation potentials.

  19. Fabrication of a graphene-cuprous oxide composite

    SciTech Connect (OSTI)

    Xu Chao [Key Laboratory for Soft Chemistry and Functional Materials of Ministry Education, Nanjing University of Science and Technology, Nanjing 210094 (China); Wang Xin, E-mail: wxin@public1.ptt.js.c [Key Laboratory for Soft Chemistry and Functional Materials of Ministry Education, Nanjing University of Science and Technology, Nanjing 210094 (China); Yang Lichun; Wu Yuping [Department of Chemistry and Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Fudan University, Shanghai 200433 (China)

    2009-09-15T23:59:59.000Z

    A composite of graphene-cuprous oxide (Cu{sub 2}O) was prepared using copper acetate-adsorbed graphene oxide (GO) sheets as precursors. In this composite, in-situ formed Cu{sub 2}O particles were derived from the adsorbed copper acetate which attached to graphene sheets and prevented the aggregation of the reduced graphene oxide sheets. The as-synthesized Cu{sub 2}O crystals were cube-like particles distributed randomly on the sheets due to the template effect of GO, consequently forming a graphene-Cu{sub 2}O cubes composite. A preliminary study on the electrochemical behavior of the graphene-Cu{sub 2}O composite used as anode material for lithium ion batteries was carried out. - Abstract: The graphene oxide sheets are reduced and almost exfoliated due to the in-situ formation of Cu{sub 2}O crystals deriving from the adsorbed copper acetate. Display Omitted

  20. Secondary ion collection and transport system for ion microprobe

    DOE Patents [OSTI]

    Ward, James W. (Canoga Park, CA); Schlanger, Herbert (Simi Valley, CA); McNulty, Jr., Hugh (Santa Monica, CA); Parker, Norman W. (Camarillo, CA)

    1985-01-01T23:59:59.000Z

    A secondary ion collection and transport system, for use with an ion microprobe, which is very compact and occupies only a small working distance, thereby enabling the primary ion beam to have a short focal length and high resolution. Ions sputtered from the target surface by the primary beam's impact are collected between two arcuate members having radii of curvature and applied voltages that cause only ions within a specified energy band to be collected. The collected ions are accelerated and focused in a transport section consisting of a plurality of spaced conductive members which are coaxial with and distributed along the desired ion path. Relatively high voltages are applied to alternate transport sections to produce accelerating electric fields sufficient to transport the ions through the section to an ion mass analyzer, while lower voltages are applied to the other transport sections to focus the ions and bring their velocity to a level compatible with the analyzing apparatus.

  1. An embryo of protocell membrane: The capsule of graphene oxide

    E-Print Network [OSTI]

    Zhan Li; Chunmei Wang; Longlong Tian; Jing Bai; Yang Zhao; Xin Zhang; Shiwei Cao; Wei Qi; Hongdeng Qiu; Suomin Wang; Keliang Shi; Youwen Xu; Zhang Mingliang; Bo Liu; Huijun Yao; Jie Liu; Wangsuo Wu; Xiaoli Wang

    2014-11-12T23:59:59.000Z

    Many signs indicate that the graphene could widely occur on the early Earth. Here, we report a new theory that graphene might be an embryo of protocell membrane, and found several evidences. Firstly, the graphene oxide and phospholipid-graphene oxide composite would curl into capsules in strongly acidic saturated solution of Pb(NO3)2 at low temperature, providing a protective space for biochemical reactions. Secondly, L-animi acids exhibit higher reactivity than D-animi acids for graphene oxides in favor of the formation of left-handed proteins. Thirdly, monolayer graphene with nanopores prepared by unfocused 84Kr25+ has high selectivity for permeation of the monovalent metal ions (Rb+ > K+ > Cs+ > Na+ > Li+), but does not allow Cl- through, which could be attributed to the ion exchange of oxygen-containing groups on the rim of nanopores. It is similar to K+ channels, which would cause efflux of some ions from capsule of graphene oxides with the decrease of pH in the primitive ocean, creating a suitable inner condition for the origin of life. Consequently, the strongly acidic, high salinity and strong radiation as well as temperature changes in the early Earth, regarded as negative factors, would be indispensable for the origin of protocell. In short, graphene bred life, but digested gradually by the evolution.

  2. Ion sensing method

    DOE Patents [OSTI]

    Smith, Richard Harding; Martin, Glenn Brian

    2004-05-18T23:59:59.000Z

    The present invention allows the determination of trace levels of ionic substances in a sample solution (ions, metal ions, and other electrically charged molecules) by coupling a separation method, such as liquid chromatography, with ion selective electrodes (ISE) prepared so as to allow detection at activities below 10.sup.-6 M. The separation method distributes constituent molecules into fractions due to unique chemical and physical properties, such as charge, hydrophobicity, specific binding interactions, or movement in an electrical field. The separated fractions are detected by means of the ISE(s). These ISEs can be used singly or in an array. Accordingly, modifications in the ISEs are used to permit detection of low activities, specifically, below 10.sup.-6 M, by using low activities of the primary analyte (the molecular species which is specifically detected) in the inner filling solution of the ISE. Arrays constructed in various ways allow flow-through sensing for multiple ions.

  3. Ion exchange phenomena

    SciTech Connect (OSTI)

    Bourg, I.C.; Sposito, G.

    2011-05-01T23:59:59.000Z

    Ion exchange phenomena involve the population of readily exchangeable ions, the subset of adsorbed solutes that balance the intrinsic surface charge and can be readily replaced by major background electrolyte ions (Sposito, 2008). These phenomena have occupied a central place in soil chemistry research since Way (1850) first showed that potassium uptake by soils resulted in the release of an equal quantity of moles of charge of calcium and magnesium. Ion exchange phenomena are now routinely modeled in studies of soil formation (White et al., 2005), soil reclamation (Kopittke et al., 2006), soil fertilitization (Agbenin and Yakubu, 2006), colloidal dispersion/flocculation (Charlet and Tournassat, 2005), the mechanics of argillaceous media (Gajo and Loret, 2007), aquitard pore water chemistry (Tournassat et al., 2008), and groundwater (Timms and Hendry, 2007; McNab et al., 2009) and contaminant hydrology (Chatterjee et al., 2008; van Oploo et al., 2008; Serrano et al., 2009).

  4. Ion manipulation device

    DOE Patents [OSTI]

    Anderson, Gordon A; Smith, Richard D; Ibrahim, Yehia M; Baker, Erin M

    2014-09-16T23:59:59.000Z

    An ion manipulation method and device is disclosed. The device includes a pair of substantially parallel surfaces. An array of inner electrodes is contained within, and extends substantially along the length of, each parallel surface. The device includes a first outer array of electrodes and a second outer array of electrodes. Each outer array of electrodes is positioned on either side of the inner electrodes, and is contained within and extends substantially along the length of each parallel surface. A DC voltage is applied to the first and second outer array of electrodes. A RF voltage, with a superimposed electric field, is applied to the inner electrodes by applying the DC voltages to each electrode. Ions either move between the parallel surfaces within an ion confinement area or along paths in the direction of the electric field, or can be trapped in the ion confinement area.

  5. Focused ion beam system

    DOE Patents [OSTI]

    Leung, K.; Gough, R.A.; Ji, Q.; Lee, Y.Y.

    1999-08-31T23:59:59.000Z

    A focused ion beam (FIB) system produces a final beam spot size down to 0.1 {mu}m or less and an ion beam output current on the order of microamps. The FIB system increases ion source brightness by properly configuring the first (plasma) and second (extraction) electrodes. The first electrode is configured to have a high aperture diameter to electrode thickness aspect ratio. Additional accelerator and focusing electrodes are used to produce the final beam. As few as five electrodes can be used, providing a very compact FIB system with a length down to only 20 mm. Multibeamlet arrangements with a single ion source can be produced to increase throughput. The FIB system can be used for nanolithography and doping applications for fabrication of semiconductor devices with minimum feature sizes of 0.1 m or less. 13 figs.

  6. HEAVY ION INERTIAL FUSION

    E-Print Network [OSTI]

    Keefe, D.

    2008-01-01T23:59:59.000Z

    Accelerators as Drivers for Inertially Confined Fusion, W.B.LBL-9332/SLAC-22l (1979) Fusion Driven by Heavy Ion Beams,OF CALIFORNIA f Accelerator & Fusion Research Division

  7. Pulsed ion beam source

    DOE Patents [OSTI]

    Greenly, John B. (Lansing, NY)

    1997-01-01T23:59:59.000Z

    An improved pulsed ion beam source having a new biasing circuit for the fast magnetic field. This circuit provides for an initial negative bias for the field created by the fast coils in the ion beam source which pre-ionize the gas in the source, ionize the gas and deliver the gas to the proper position in the accelerating gap between the anode and cathode assemblies in the ion beam source. The initial negative bias improves the interaction between the location of the nulls in the composite magnetic field in the ion beam source and the position of the gas for pre-ionization and ionization into the plasma as well as final positioning of the plasma in the accelerating gap. Improvements to the construction of the flux excluders in the anode assembly are also accomplished by fabricating them as layered structures with a high melting point, low conductivity material on the outsides with a high conductivity material in the center.

  8. High current ion source

    DOE Patents [OSTI]

    Brown, Ian G. (1088 Woodside Rd., Berkeley, CA 94708); MacGill, Robert A. (645 Kern St., Richmond, CA 94805); Galvin, James E. (2 Commodore Dr. #276, Emeryville, CA 94608)

    1990-01-01T23:59:59.000Z

    An ion source utilizing a cathode and anode for producing an electric arc therebetween. The arc is sufficient to vaporize a portion of the cathode to form a plasma. The plasma leaves the generation region and expands through another regon. The density profile of the plasma may be flattened using a magnetic field formed within a vacuum chamber. Ions are extracted from the plasma to produce a high current broad on beam.

  9. Ion electric propulsion unit

    DOE Patents [OSTI]

    Light, Max E; Colestock, Patrick L

    2014-01-28T23:59:59.000Z

    An electron cyclotron resonance (ECR) thruster is disclosed having a plasma chamber which is electrically biased with a positive voltage. The chamber bias serves to efficiently accelerate and expel the positive ions from the chamber. Electrons follow the exiting ions, serving to provide an electrically neutral exhaust plume. In a further embodiment, a downstream shaping magnetic field serves to further accelerate and/or shape the exhaust plume.

  10. Cerium Oxide Coating for Oxidation Reduction

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041clothAdvanced Materials Advanced. C o w l i t z C oCNMSStaffCerium Oxide Coating for Oxidation

  11. Ion optics of RHIC EBIS

    SciTech Connect (OSTI)

    Pikin, A.; Alessi, J.; Beebe, E.; Kponou, A.; Okamura, M.; Raparia, D.; Ritter, J.; Tan, Y.; Kuznetsov, G.

    2011-09-10T23:59:59.000Z

    RHIC EBIS has been commissioned to operate as a versatile ion source on RHIC injection facility supplying ion species from He to Au for Booster. Except for light gaseous elements RHIC EBIS employs ion injection from several external primary ion sources. With electrostatic optics fast switching from one ion species to another can be done on a pulse to pulse mode. The design of an ion optical structure and the results of simulations for different ion species are presented. In the choice of optical elements special attention was paid to spherical aberrations for high-current space charge dominated ion beams. The combination of a gridded lens and a magnet lens in LEBT provides flexibility of optical control for a wide range of ion species to satisfy acceptance parameters of RFQ. The results of ion transmission measurements are presented.

  12. Stabilized chromium oxide film

    DOE Patents [OSTI]

    Garwin, Edward L. (Los Altos, CA); Nyaiesh, Ali R. (Palo Alto, CA)

    1988-01-01T23:59:59.000Z

    Stabilized air-oxidized chromium films deposited on high-power klystron ceramic windows and sleeves having a thickness between 20 and 150.ANG. are useful in lowering secondary electron emission yield and in avoiding multipactoring and window failure due to overheating. The ceramic substrate for the film is chosen from alumina, sapphire or beryllium oxide.

  13. Stabilized chromium oxide film

    DOE Patents [OSTI]

    Nyaiesh, A.R.; Garwin, E.L.

    1986-08-04T23:59:59.000Z

    Stabilized air-oxidized chromium films deposited on high-power klystron ceramic windows and sleeves having a thickness between 20 and 150A are useful in lowering secondary electron emission yield and in avoiding multipactoring and window failure due to overheating. The ceramic substrate for the film is chosen from alumina, sapphire or beryllium oxide.

  14. Reducible oxide based catalysts

    DOE Patents [OSTI]

    Thompson, Levi T.; Kim, Chang Hwan; Bej, Shyamal K.

    2010-04-06T23:59:59.000Z

    A catalyst is disclosed herein. The catalyst includes a reducible oxide support and at least one noble metal fixed on the reducible oxide support. The noble metal(s) is loaded on the support at a substantially constant temperature and pH.

  15. Feed gas contaminant control in ion transport membrane systems

    DOE Patents [OSTI]

    Carolan, Michael Francis (Allentown, PA); Minford, Eric (Laurys Station, PA); Waldron, William Emil (Whitehall, PA)

    2009-07-07T23:59:59.000Z

    Ion transport membrane oxidation system comprising an enclosure having an interior and an interior surface, inlet piping having an internal surface and adapted to introduce a heated feed gas into the interior of the enclosure, and outlet piping adapted to withdraw a product gas from the interior of the enclosure; one or more planar ion transport membrane modules disposed in the interior of the enclosure, each membrane module comprising mixed metal oxide material; and a preheater adapted to heat a feed gas to provide the heated feed gas to the inlet piping, wherein the preheater comprises an interior surface. Any of the interior surfaces of the enclosure, the inlet piping, and the preheater may be lined with a copper-containing metal lining. Alternatively, any of the interior surfaces of the inlet piping and the preheater may be lined with a copper-containing metal lining and the enclosure may comprise copper.

  16. Modulational instability of ion acoustic wave with warm ions in electron-positron-ion plasmas

    SciTech Connect (OSTI)

    Mahmood, S. [Theoretical Plasma Physics Division, PINSTECH, P.O. Nilore, Islamabad 44000 (Pakistan); Department of Physics and Applied Mathematics, PIEAS, P.O. Nilore, Islamabad 44000 (Pakistan); Siddiqui, Sadiya [Department of Physics and Applied Mathematics, PIEAS, P.O. Nilore, Islamabad 44000 (Pakistan); Jehan, Nusrat [Pakistan Atomic Energy Commission, P.O. Box 1114, Islamabad 44000 (Pakistan)

    2011-05-15T23:59:59.000Z

    The nonlinear amplitude modulation of ion acoustic wave is studied in the presence of warm ions in unmagnetized electron-positron-ion plasmas. The Krylov-Bogoliubov-Mitropolsky (KBM) method is used to derive the nonlinear Schroedinger equation. The dispersive and nonlinear coefficients are obtained which depends on the ion temperature and positron density in electron-positron-ion plasmas. The modulationally stable and unstable regions are studied numerically for a wide range of wave number. It is found that both ion temperature and positron density play a significant role in the formation of bright and dark envelope solitons in electron-positron-ion plasmas.

  17. Electronuclear ion fusion in an ion cyclotron resonance reactor

    SciTech Connect (OSTI)

    Cowgill, Donald F.

    1996-12-01T23:59:59.000Z

    A method and apparatus for generating nuclear fusion by ion cyclotron resonance in an ion trap reactor. The reactor includes a cylindrical housing having an axial axis, an internal surface, and first and second ends. First and second end plates that are charged are respectively located at the first and second ends of the cylindrical housing. A gas layer is adsorbed on the internal surface of the cylindrical housing. Ions are desorbed from the gas layer, forming a plasma layer adjacent to the cylindrical housing that includes first ions that have a same charge sign as the first and second end plates. A uniform magnetic field is oriented along the axial axis of the cylindrical housing. Second ions, that are unlike the first ions, but have the same charge sign, are injected into the cylindrical housing along the axial axis of the cylindrical housing. A radio frequency field resonantly accelerates the injected second ions at the cyclotron resonance frequency of the second ions. The second ions circulate in increasing helical orbits and react with the first ions, at the optimum energy for nuclear fusion. The amplitude of the radio frequency field is adjusted to accelerate the second ions at a rate equal to the rate of tangential energy loss of the second ions by nuclear scattering in the first ions, causing the ions to continually interact until fusion occurs.

  18. Method of fabricating optical waveguides by ion implantation doping

    DOE Patents [OSTI]

    Appleton, B.R.; Ashley, P.R.; Buchal, C.J.

    1987-03-24T23:59:59.000Z

    A method for fabricating high-quality optical waveguides in optical quality oxide crystals by ion implantation doping and controlled epitaxial recrystallization is provided. Masked LiNbO/sub 3/ crystals are implanted with high concentrations of Ti dopant at ion energies of about 360 keV while maintaining the crystal near liquid nitrogen temperature. Ion implantation doping produces an amorphous, Ti-rich nonequilibrium phase in the implanted region. Subsequent thermal annealing in a water-saturated oxygen atmosphere at up to 1000/degree/C produces solid-phase epitaxial regrowth onto the crystalline substrate. A high-quality crystalline layer results which incorporates the Ti into the crystal structure at much higher concentrations than is possible by standard diffusion techniques, and this implanted region has excellent optical waveguiding properties.

  19. Standard test methods for analysis of sintered gadolinium oxide-uranium dioxide pellets

    E-Print Network [OSTI]

    American Society for Testing and Materials. Philadelphia

    2006-01-01T23:59:59.000Z

    1.1 These test methods cover procedures for the analysis of sintered gadolinium oxide-uranium dioxide pellets to determine compliance with specifications. 1.2 The analytical procedures appear in the following order: Section Carbon (Total) by Direct CombustionThermal Conductivity Method C1408 Test Method for Carbon (Total) in Uranium Oxide Powders and Pellets By Direct Combustion-Infrared Detection Method Chlorine and Fluorine by Pyrohydrolysis Ion-Selective Electrode Method C1502 Test Method for Determination of Total Chlorine and Fluorine in Uranium Dioxide and Gadolinium Oxide Gadolinia Content by Energy-Dispersive X-Ray Spectrometry C1456 Test Method for Determination of Uranium or Gadolinium, or Both, in Gadolinium Oxide-Uranium Oxide Pellets or by X-Ray Fluorescence (XRF) Hydrogen by Inert Gas Fusion C1457 Test Method for Determination of Total Hydrogen Content of Uranium Oxide Powders and Pellets by Carrier Gas Extraction Isotopic Uranium Composition by Multiple-Filament Surface-Ioni...

  20. Asymmetric ion trap

    DOE Patents [OSTI]

    Barlow, Stephan E. (Richland, WA); Alexander, Michael L. (Richland, WA); Follansbee, James C. (Pasco, WA)

    1997-01-01T23:59:59.000Z

    An ion trap having two end cap electrodes disposed asymmetrically about a center of a ring electrode. The inner surface of the end cap electrodes are conformed to an asymmetric pair of equipotential lines of the harmonic formed by the application of voltages to the electrodes. The asymmetry of the end cap electrodes allows ejection of charged species through the closer of the two electrodes which in turn allows for simultaneously detecting anions and cations expelled from the ion trap through the use of two detectors charged with opposite polarity.

  1. Asymmetric ion trap

    DOE Patents [OSTI]

    Barlow, S.E.; Alexander, M.L.; Follansbee, J.C.

    1997-12-02T23:59:59.000Z

    An ion trap having two end cap electrodes disposed asymmetrically about a center of a ring electrode is disclosed. The inner surface of the end cap electrodes are conformed to an asymmetric pair of equipotential lines of the harmonic formed by the application of voltages to the electrodes. The asymmetry of the end cap electrodes allows ejection of charged species through the closer of the two electrodes which in turn allows for simultaneously detecting anions and cations expelled from the ion trap through the use of two detectors charged with opposite polarity. 4 figs.

  2. Side Reactions in Lithium-Ion Batteries

    E-Print Network [OSTI]

    Tang, Maureen Han-Mei

    2012-01-01T23:59:59.000Z

    experimental data from plastic lithium ion cells. Journal ofelectrolyte additive for lithium-ion batteries. Elec-A. Aging Mechanisms in Lithium-Ion Batteries. Journal of

  3. HEAVY-ION RADIOBIOLOGY: CELLULAR STUDIES

    E-Print Network [OSTI]

    Blakely, Eleanor A.

    2013-01-01T23:59:59.000Z

    foiled parallel-plate ion chambers filled with pure nitrogenare made with a pair of ion chambers using an interposedbeen used to verify ion chamber dosimetry; (1) comparisons

  4. Titanate Anodes for Sodium Ion Batteries

    E-Print Network [OSTI]

    Doeff, Marca

    2014-01-01T23:59:59.000Z

    Company-v3832/Lithium-Ion-Batteries- Outlook-Alternative-Anodes for Sodium Ion Batteries Marca M. Doeff * , Jordirechargeable sodium ion batteries, particularly for large-

  5. Titanate Anodes for Sodium Ion Batteries

    E-Print Network [OSTI]

    Doeff, Marca M.

    2014-01-01T23:59:59.000Z

    Anodes for Sodium Ion Batteries Identification of a suitabledevelopment of sodium ion batteries, because graphite, theanode for lithium ion batteries, does not undergo sodium

  6. Advances in lithium-ion batteries

    E-Print Network [OSTI]

    Kerr, John B.

    2003-01-01T23:59:59.000Z

    Advances in Lithium-Ion Batteries Edited by Walter A. vanpuzzling mysteries of lithium ion batteries. The book beginssuch importance to lithium ion batteries one is amazed that

  7. Ion Distribution And Electronic Stopping Power For Au ions In...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    power for heavy ions in light targets is highly desired due to the large errors in prediction by the widely used Stopping and Range of Ions in Matter (SRIM) code. In this study,...

  8. Oxidative Tritium Decontamination System

    DOE Patents [OSTI]

    Gentile, Charles A. (Plainsboro, NJ), Guttadora, Gregory L. (Highland Park, NJ), Parker, John J. (Medford, NJ)

    2006-02-07T23:59:59.000Z

    The Oxidative Tritium Decontamination System, OTDS, provides a method and apparatus for reduction of tritium surface contamination on various items. The OTDS employs ozone gas as oxidizing agent to convert elemental tritium to tritium oxide. Tritium oxide vapor and excess ozone gas is purged from the OTDS, for discharge to atmosphere or transport to further process. An effluent stream is subjected to a catalytic process for the decomposition of excess ozone to diatomic oxygen. One of two configurations of the OTDS is employed: dynamic apparatus equipped with agitation mechanism and large volumetric capacity for decontamination of light items, or static apparatus equipped with pressurization and evacuation capability for decontamination of heavier, delicate, and/or valuable items.

  9. Synthesis, Characterization and Performance of Cathodes for Lithium Ion Batteries

    E-Print Network [OSTI]

    Zhu, Jianxin

    2014-01-01T23:59:59.000Z

    ion batteries In current lithium ion battery technology,ion batteries The first commercialized lithium-ion batteryfirst lithium-ion battery. Compared to the other batteries,

  10. Controlled CO preferential oxidation

    DOE Patents [OSTI]

    Meltser, M.A.; Hoch, M.M.

    1997-06-10T23:59:59.000Z

    Method is described for controlling the supply of air to a PROX (PReferential OXidation for CO cleanup) reactor for the preferential oxidation in the presence of hydrogen wherein the concentration of the hydrogen entering and exiting the PROX reactor is monitored, the difference there between correlated to the amount of air needed to minimize such difference, and based thereon the air supply to the PROX reactor adjusted to provide such amount and minimize such difference. 2 figs.

  11. ADVANCED OXIDATION PROCESS

    SciTech Connect (OSTI)

    Dr. Colin P. Horwitz; Dr. Terrence J. Collins

    2003-11-04T23:59:59.000Z

    The removal of recalcitrant sulfur species, dibenzothiophene and its derivatives, from automotive fuels is an integral component in the development of cleaner burning and more efficient automobile engines. Oxidative desulfurization (ODS) wherein the dibenzothiophene derivative is converted to its corresponding sulfoxide and sulfone is an attractive approach to sulfur removal because the oxidized species are easily extracted or precipitated and filtered from the hydrocarbon phase. Fe-TAML{reg_sign} activators of hydrogen peroxide (TAML is Tetra-Amido-Macrocyclic-Ligand) catalytically convert dibenzothiophene and its derivatives rapidly and effectively at moderate temperatures (50-60 C) and ambient pressure to the corresponding sulfoxides and sulfones. The oxidation process can be performed in both aqueous systems containing alcohols such as methanol, ethanol, or t-butanol, and in a two-phase hydrocarbon/aqueous system containing tert-butanol or acetonitrile. In the biphasic system, essentially complete conversion of the DBT to its oxidized products can be achieved using slightly longer reaction times than in homogeneous solution. Among the key features of the technology are the mild reaction conditions, the very high selectivity where no over oxidation of the sulfur compounds occurs, the near stoichiometric use of hydrogen peroxide, the apparent lack of degradation of sensitive fuel components, and the ease of separation of oxidized products.

  12. Emergent Phenomena at Oxide Interfaces

    SciTech Connect (OSTI)

    Hwang, H.Y.

    2012-02-16T23:59:59.000Z

    Transition metal oxides (TMOs) are an ideal arena for the study of electronic correlations because the s-electrons of the transition metal ions are removed and transferred to oxygen ions, and hence the strongly correlated d-electrons determine their physical properties such as electrical transport, magnetism, optical response, thermal conductivity, and superconductivity. These electron correlations prohibit the double occupancy of metal sites and induce a local entanglement of charge, spin, and orbital degrees of freedom. This gives rise to a variety of phenomena, e.g., Mott insulators, various charge/spin/orbital orderings, metal-insulator transitions, multiferroics, and superconductivity. In recent years, there has been a burst of activity to manipulate these phenomena, as well as create new ones, using oxide heterostructures. Most fundamental to understanding the physical properties of TMOs is the concept of symmetry of the order parameter. As Landau recognized, the essence of phase transitions is the change of the symmetry. For example, ferromagnetic ordering breaks the rotational symmetry in spin space, i.e., the ordered phase has lower symmetry than the Hamiltonian of the system. There are three most important symmetries to be considered here. (i) Spatial inversion (I), defined as r {yields} -r. In the case of an insulator, breaking this symmetry can lead to spontaneous electric polarization, i.e. ferroelectricity, or pyroelectricity once the point group belongs to polar group symmetry. (ii) Time-reversal symmetry (T) defined as t {yields} -t. In quantum mechanics, the time-evolution of the wave-function {Psi} is given by the phase factor e{sup -iEt/{h_bar}} with E being the energy, and hence time-reversal basically corresponds to taking the complex conjugate of the wave-function. Also the spin, which is induced by the 'spinning' of the particle, is reversed by time-reversal. Broken T-symmetry is most naturally associated with magnetism, since the spin operator changes sign with T-operation. (iii) Gauge symmetry (G), which is associated with a change in the phase of the wave-function as {Psi} {yields} e{sup i{theta}}{Psi}. Gauge symmetry is connected to the law of charge conservation, and broken G-symmetry corresponds to superconductivity/superfluidity. To summarize, the interplay among these electronic degrees of freedom produces various forms of symmetry breaking patterns of I, T, and G, leading to novel emergent phenomena, which can appear only by the collective behavior of electrons and cannot be expected from individual electrons. Figure 1 shows this schematically by means of several representative phenomena. From this viewpoint, the interfaces of TMOs offer a unique and important laboratory because I is already broken by the structure itself, and the detailed form of broken I-symmetry can often be designed. Also, two-dimensionality usually enhances the effects of electron correlations by reducing their kinetic energy. These two features of oxide interfaces produce many novel effects and functions that cannot be attained in bulk form. Given that the electromagnetic responses are a major source of the physical properties of solids, and new gauge structures often appear in correlated electronic systems, we put 'emergent electromagnetism' at the center of Fig. 1.

  13. Pulsed ion beam source

    DOE Patents [OSTI]

    Greenly, J.B.

    1997-08-12T23:59:59.000Z

    An improved pulsed ion beam source is disclosed having a new biasing circuit for the fast magnetic field. This circuit provides for an initial negative bias for the field created by the fast coils in the ion beam source which pre-ionize the gas in the source, ionize the gas and deliver the gas to the proper position in the accelerating gap between the anode and cathode assemblies in the ion beam source. The initial negative bias improves the interaction between the location of the nulls in the composite magnetic field in the ion beam source and the position of the gas for pre-ionization and ionization into the plasma as well as final positioning of the plasma in the accelerating gap. Improvements to the construction of the flux excluders in the anode assembly are also accomplished by fabricating them as layered structures with a high melting point, low conductivity material on the outsides with a high conductivity material in the center. 12 figs.

  14. Lithium ion conducting electrolytes

    DOE Patents [OSTI]

    Angell, Charles Austen (Mesa, AZ); Liu, Changle (Midland, MI); Xu, Kang (Montgomery Village, MD); Skotheim, Terje A. (Tucson, AZ)

    1999-01-01T23:59:59.000Z

    The present invention relates generally to highly conductive alkali-metal ion non-crystalline electrolyte systems, and more particularly to novel and unique molten (liquid), rubbery, and solid electrolyte systems which are especially well suited for use with high current density electrolytic cells such as primary and secondary batteries.

  15. Photo ion spectrometer

    DOE Patents [OSTI]

    Gruen, Dieter M. (Downers Grove, IL); Young, Charles E. (Westmont, IL); Pellin, Michael J. (Naperville, IL)

    1989-01-01T23:59:59.000Z

    A method and apparatus for extracting for quantitative analysis ions of selected atomic components of a sample. A lens system is configured to provide a slowly diminishing field region for a volume containing the selected atomic components, enabling accurate energy analysis of ions generated in the slowly diminishing field region. The lens system also enables focusing on a sample of a charged particle beam, such as an ion beam, along a path length perpendicular to the sample and extraction of the charged particles along a path length also perpendicular to the sample. Improvement of signal to noise ratio is achieved by laser excitation of ions to selected autoionization states before carrying out quantitative analysis. Accurate energy analysis of energetic charged particles is assured by using a preselected resistive thick film configuration disposed on an insulator substrate for generating predetermined electric field boundary conditions to achieve for analysis the required electric field potential. The spectrometer also is applicable in the fields of SIMS, ISS and electron spectroscopy.

  16. Photo ion spectrometer

    DOE Patents [OSTI]

    Gruen, D.M.; Young, C.E.; Pellin, M.J.

    1989-08-08T23:59:59.000Z

    A method and apparatus are described for extracting for quantitative analysis ions of selected atomic components of a sample. A lens system is configured to provide a slowly diminishing field region for a volume containing the selected atomic components, enabling accurate energy analysis of ions generated in the slowly diminishing field region. The lens system also enables focusing on a sample of a charged particle beam, such as an ion beam, along a path length perpendicular to the sample and extraction of the charged particles along a path length also perpendicular to the sample. Improvement of signal to noise ratio is achieved by laser excitation of ions to selected auto-ionization states before carrying out quantitative analysis. Accurate energy analysis of energetic charged particles is assured by using a preselected resistive thick film configuration disposed on an insulator substrate for generating predetermined electric field boundary conditions to achieve for analysis the required electric field potential. The spectrometer also is applicable in the fields of SIMS, ISS and electron spectroscopy. 8 figs.

  17. Oxidation of Mercury in Products of Coal Combustion

    SciTech Connect (OSTI)

    Peter Walsh; Giang Tong; Neeles Bhopatkar; Thomas Gale; George Blankenship; Conrad Ingram; Selasi Blavo Tesfamariam Mehreteab; Victor Banjoko; Yohannes Ghirmazion; Heng Ban; April Sibley

    2009-09-14T23:59:59.000Z

    Laboratory measurements of mercury oxidation during selective catalytic reduction (SCR) of nitric oxide, simulation of pilot-scale measurements of mercury oxidation and adsorption by unburned carbon and fly ash, and synthesis of new materials for simultaneous oxidation and adsorption of mercury, were performed in support of the development of technology for control of mercury emissions from coal-fired boilers and furnaces. Conversion of gas-phase mercury from the elemental state to water-soluble oxidized form (HgCl{sub 2}) enables removal of mercury during wet flue gas desulfurization. The increase in mercury oxidation in a monolithic V{sub 2}O{sub 5}-WO{sub 3}/TiO{sub 2} SCR catalyst with increasing HCl at low levels of HCl (< 10 ppmv) and decrease in mercury oxidation with increasing NH{sub 3}/NO ratio during SCR were consistent with results of previous work by others. The most significant finding of the present work was the inhibition of mercury oxidation in the presence of CO during SCR of NO at low levels of HCl. In the presence of 2 ppmv HCl, expected in combustion products from some Powder River Basin coals, an increase in CO from 0 to 50 ppmv reduced the extent of mercury oxidation from 24 {+-} 3 to 1 {+-} 4%. Further increase in CO to 100 ppmv completely suppressed mercury oxidation. In the presence of 11-12 ppmv HCl, increasing CO from 0 to {approx}120 ppmv reduced mercury oxidation from {approx}70% to 50%. Conversion of SO{sub 2} to sulfate also decreased with increasing NH{sub 3}/NO ratio, but the effects of HCl and CO in flue gas on SO{sub 2} oxidation were unclear. Oxidation and adsorption of mercury by unburned carbon and fly ash enables mercury removal in a particulate control device. A chemical kinetic mechanism consisting of nine homogeneous and heterogeneous reactions for mercury oxidation and removal was developed to interpret pilot-scale measurements of mercury oxidation and adsorption by unburned carbon and fly ash in experiments at pilot scale, burning bituminous coals (Gale, 2006) and blends of bituminous coals with Powder River Basin coal (Gale, 2005). The removal of mercury by fly ash and unburned carbon in the flue gas from combustion of the bituminous coals and blends was reproduced with satisfactory accuracy by the model. The enhancement of mercury capture in the presence of calcium (Gale, 2005) explained a synergistic effect of blending on mercury removal across the baghouse. The extent of mercury oxidation, on the other hand, was not so well described by the simulation, because of oversensitivity of the oxidation process in the model to the concentration of unburned carbon. Combined catalysts and sorbents for oxidation and removal of mercury from flue gas at low temperature were based on surfactant-templated silicas containing a transition metal and an organic functional group. The presence of both metal ions and organic groups within the pore structure of the materials is expected to impart to them the ability to simultaneously oxidize elemental mercury and adsorb the resulting oxidized mercury. Twelve mesoporous organosilicate catalysts/sorbents were synthesized, with and without metals (manganese, titanium, vanadium) and organic functional groups (aminopropyl, chloropropyl, mercaptopropyl). Measurement of mercury oxidation and adsorption by the candidate materials remains for future work.

  18. Ion Runaway in Lightning Discharges

    E-Print Network [OSTI]

    Landreman, Matt

    Runaway ions can be produced in plasmas with large electric fields, where the accelerating electric force is augmented by the low mean ionic charge due to the imbalance between the number of electrons and ions. Here we ...

  19. Purification of uranium alloys by differential solubility of oxides and production of purified fuel precursors

    DOE Patents [OSTI]

    McLean, W. II; Miller, P.E.

    1997-12-16T23:59:59.000Z

    A method is described for purifying metallic alloys of uranium for use as nuclear reactor fuels in which the metal alloy is first converted to an oxide and then dissolved in nitric acid. Initial removal of metal oxide impurities not soluble in nitric acid is accomplished by filtration or other physical means. Further purification can be accomplished by carbonate leaching of uranyl ions from the partially purified solution or using traditional methods such as solvent extraction. 3 figs.

  20. Purification of uranium alloys by differential solubility of oxides and production of purified fuel precursors

    DOE Patents [OSTI]

    McLean, II, William (Oakland, CA); Miller, Philip E. (Livermore, CA)

    1997-01-01T23:59:59.000Z

    A method for purifying metallic alloys of uranium for use as nuclear reactor fuels in which the metal alloy is first converted to an oxide and then dissolved in nitric acid. Initial removal of metal oxide impurities not soluble in nitric acid is accomplished by filtration or other physical means. Further purification can be accomplished by carbonate leaching of uranyl ions from the partially purified solution or using traditional methods such as solvent extraction.

  1. Inorganic ion sorbent method

    DOE Patents [OSTI]

    Teter, David M. (Edgewood, NM); Brady, Patrick V. (Albuquerque, NM); Krumhansl, James L. (Albuquerque, NM)

    2007-07-17T23:59:59.000Z

    A process and medium for decontamination of water containing anionic species including arsenic and chromium, wherein compounds comprising divalent and trivalent metal oxides and sulfides are used to form surface complexes with contaminants under pH conditions within the range of potable water. In one embodiment natural and synthetic spinels and spinel-like materials are used as the sorbent substance.

  2. Inorganic ion sorbents

    DOE Patents [OSTI]

    Teter, David M.; Brady, Patrick V.; Krumhansl, James L.

    2006-10-17T23:59:59.000Z

    A process and medium for decontamination of water containing anionic species including arsenic and chromium, wherein compounds comprising divalent and trivalent metal oxides and sulfides are used to form surface complexes with contaminants under pH conditions within the range of potable water. In one embodiment natural and synthetic spinels and spinel-like materials are used as the sorbent substance.

  3. Characterization of an RF plasma ion source for ion implantation

    SciTech Connect (OSTI)

    Kopalidis, Peter M.; Wan Zhimin [Advanced Ion Beam Technology Inc., 47370 Fremont Blvd., Fremont, CA 94538 (United States)

    2012-11-06T23:59:59.000Z

    A novel inductively coupled RF plasma ion source has been developed for use in a beamline ion implanter. Ion density data have been taken with an array of four Langmuir probes spaced equally at the source extraction arc slit. These provide ion density uniformity information as a function of source pressure, RF power and gas mixture composition. In addition, total extracted ion beam current data are presented for the same conditions. The comparative advantages of the RF source in terms of higher beam current, reduced maintenance and overall productivity improvement compared to a hot cathode source are discussed.

  4. Photoabsorption by Ions and Atoms

    SciTech Connect (OSTI)

    Manson, Steven T. [Department of Physics and Astronomy, Georgia State University, Atlanta, Georgia 30303 (United States)

    2004-12-01T23:59:59.000Z

    Recent progress in theoretical and experimental investigations of photoabsorption by atoms and ions is presented. Specifically, examples of near-chaotic behavior in photoionization of positive ions, low-energy manifestations of nondipole effects, high-energy breakdown of the single particle picture and new phenomenology uncovered in the inner-shell photoabsorption by negative ions are discussed.

  5. Unusual behavior of poly(ethylene-oxide) in aqueous mixtures.

    SciTech Connect (OSTI)

    Lal, J.; Hakem, I. F.; IPNS

    2004-10-01T23:59:59.000Z

    The model system of poly(ethylene-oxide) or PEO, where the changing hydrogen-bond connectivity of the water has large effect on the conformation of the polymer chain, in mixtures of water and acetonitrile, is experimentally studied. The results show the existence of a threshold water content in the system at which the 3d connectivity of the water network begins. Unusual expansion of the polymer chain, an effect larger than that observed in either of the pure solvents, is seen. Upon addition of small amounts of a monovalent salt, binding of ion to polymer takes place in pure acetonitrile solutions. Salt ions begin to co-ordinate with water molecules at the same solvent ratio as the threshold for water network formation. Ions now no longer complex to PEO; instead, hydrogen bonding of water to the polymer strongly dictates conformation in this regime.

  6. Fiber optic integration in planar ion traps

    E-Print Network [OSTI]

    George, Elizabeth Marie

    2008-01-01T23:59:59.000Z

    Atomic ion traps are are excellent tools in atomic physics for studying single ions. Accurate measurement of the ion's electronic state in these ion traps is required by both atomic clocks and quantum computation. Quantum ...

  7. Process for the displacement of cyanide ions from metal-cyanide complexes

    DOE Patents [OSTI]

    Smith, Barbara F. (Los Alamos, NM); Robinson, Thomas W. (Los Alamos, NM)

    1997-01-01T23:59:59.000Z

    The present invention relates to water-soluble polymers and the use of such water-soluble polymers in a process for the displacement of the cyanide ions from the metal ions within metal-cyanide complexes. The process waste streams can include metal-cyanide containing electroplating waste streams, mining leach waste streams, mineral processing waste streams, and related metal-cyanide containing waste streams. The metal ions of interest are metals that give very strong complexes with cyanide, mostly iron, nickel, and copper. The physical separation of the water-soluble polymer-metal complex from the cyanide ions can be accomplished through the use of ultrafiltration. Once the metal-cyanide complex is disrupted, the freed cyanide ions can be recovered for reuse or destroyed using available oxidative processes rendering the cyanide nonhazardous. The metal ions are released from the polymer, using dilute acid, metal ion oxidation state adjustment, or competing chelating agents, and collected and recovered or disposed of by appropriate waste management techniques. The water-soluble polymer can then be recycled. Preferred water-soluble polymers include polyethyleneimine and polyethyleneimine having a catechol or hydroxamate group.

  8. Fabrication of catalyzed ion transport membrane systems

    DOE Patents [OSTI]

    Carolan, Michael Francis; Kibby, Charles Leonard

    2013-06-04T23:59:59.000Z

    Process for fabricating a catalyzed ion transport membrane (ITM). In one embodiment, an uncatalyzed ITM is (a) contacted with a non-reducing gaseous stream while heating to a temperature and for a time period sufficient to provide an ITM possessing anion mobility; (b) contacted with a reducing gaseous stream for a time period sufficient to provide an ITM having anion mobility and essentially constant oxygen stoichiometry; (c) cooled while contacting the ITM with the reducing gaseous stream to provide an ITM having essentially constant oxygen stoichiometry and no anion mobility; and (d) treated by applying catalyst to at least one of (1) a porous mixed conducting multicomponent metallic oxide (MCMO) layer contiguous with a first side of a dense layer of MCMO and (2) a second side of the dense MCMO layer. In another embodiment, these steps are carried out in the alternative order of (a), (d), (b), and (c).

  9. Electrolytic process to produce sodium hypochlorite using sodium ion conductive ceramic membranes

    DOE Patents [OSTI]

    Balagopal, Shekar; Malhotra, Vinod; Pendleton, Justin; Reid, Kathy Jo

    2012-09-18T23:59:59.000Z

    An electrochemical process for the production of sodium hypochlorite is disclosed. The process may potentially be used to produce sodium hypochlorite from seawater or low purity un-softened or NaCl-based salt solutions. The process utilizes a sodium ion conductive ceramic membrane, such as membranes based on NASICON-type materials, in an electrolytic cell. In the process, water is reduced at a cathode to form hydroxyl ions and hydrogen gas. Chloride ions from a sodium chloride solution are oxidized in the anolyte compartment to produce chlorine gas which reacts with water to produce hypochlorous and hydrochloric acid. Sodium ions are transported from the anolyte compartment to the catholyte compartment across the sodium ion conductive ceramic membrane. Sodium hydroxide is transported from the catholyte compartment to the anolyte compartment to produce sodium hypochlorite within the anolyte compartment.

  10. Synthesis of Na1.25V3O8 Nanobelts with Excellent Long-Term Stability for Rechargeable Lithium-Ion Batteries

    E-Print Network [OSTI]

    Cao, Guozhong

    by the calcination temperatures. As cathode materials for lithium ion batteries, the Na1.25V3O8 nanobelts synthesized.25V3O8 nanobelts are promising cathode materials for secondary lithium batteries. KEYWORDS: sodium vanadium oxide, nanobelts, sol-gel, lithium-ion batteries, long-term stability 1. INTRODUCTION Because

  11. Method for preparing hydrous titanium oxide spherules and other gel forms thereof

    DOE Patents [OSTI]

    Collins, Jack L. (Knoxville, TN)

    1998-01-01T23:59:59.000Z

    The present invention are methods for preparing hydrous titanium oxide spherules, hydrous titanium oxide gels such as gel slabs, films, capillary and electrophoresis gels, titanium monohydrogen phosphate spherules, hydrous titanium oxide spherules having suspendible particles homogeneously embedded within to form a composite sorbent, titanium monohydrogen phosphate spherules having suspendible particles of at least one different sorbent homogeneously embedded within to form a composite sorbent having a desired crystallinity, titanium oxide spherules in the form of anatase, brookite or rutile, titanium oxide spherules having suspendible particles homogeneously embedded within to form a composite, hydrous titanium oxide fiber materials, titanium oxide fiber materials, hydrous titanium oxide fiber materials having suspendible particles homogeneously embedded within to form a composite, titanium oxide fiber materials having suspendible particles homogeneously embedded within to form a composite and spherules of barium titanate. These variations of hydrous titanium oxide spherules and gel forms prepared by the gel-sphere, internal gelation process offer more useful forms of inorganic ion exchangers, catalysts, getters and ceramics.

  12. Method for preparing hydrous titanium oxide spherules and other gel forms thereof

    DOE Patents [OSTI]

    Collins, J.L.

    1998-10-13T23:59:59.000Z

    The present invention are methods for preparing hydrous titanium oxide spherules, hydrous titanium oxide gels such as gel slabs, films, capillary and electrophoresis gels, titanium monohydrogen phosphate spherules, hydrous titanium oxide spherules having suspendible particles homogeneously embedded within to form a composite sorbent, titanium monohydrogen phosphate spherules having suspendible particles of at least one different sorbent homogeneously embedded within to form a composite sorbent having a desired crystallinity, titanium oxide spherules in the form of anatase, brookite or rutile, titanium oxide spherules having suspendible particles homogeneously embedded within to form a composite, hydrous titanium oxide fiber materials, titanium oxide fiber materials, hydrous titanium oxide fiber materials having suspendible particles homogeneously embedded within to form a composite, titanium oxide fiber materials having suspendible particles homogeneously embedded within to form a composite and spherules of barium titanate. These variations of hydrous titanium oxide spherules and gel forms prepared by the gel-sphere, internal gelation process offer more useful forms of inorganic ion exchangers, catalysts, getters and ceramics. 6 figs.

  13. Oxidation of propylene over copper oxide catalysts 

    E-Print Network [OSTI]

    Billingsley, David Stuart

    1958-01-01T23:59:59.000Z

    sulfate of either sodium, potassium, lithium, rubidium or cesium. The active agent was prepared in the form of a slurry which was deposited on the carrier by agitating the two materials together. The carrier was alumina or silicon carbide. Oxidation... welded on each end. On the bottom of the tank was a drain connection which was closed; the tank also contained a thermometer well. The tank was connected to the vent system through a needle valve and also through a safety valve which was set...

  14. Chemical Shuttle Additives in Lithium Ion Batteries

    SciTech Connect (OSTI)

    Patterson, Mary

    2013-03-31T23:59:59.000Z

    The goals of this program were to discover and implement a redox shuttle that is compatible with large format lithium ion cells utilizing LiNi{sub 1/3}Mn{sub 1/3}Co{sub 1/3}O{sub 2} (NMC) cathode material and to understand the mechanism of redox shuttle action. Many redox shuttles, both commercially available and experimental, were tested and much fundamental information regarding the mechanism of redox shuttle action was discovered. In particular, studies surrounding the mechanism of the reduction of the oxidized redox shuttle at the carbon anode surface were particularly revealing. The initial redox shuttle candidate, namely 2-(pentafluorophenyl)-tetrafluoro-1,3,2-benzodioxaborole (BDB) supplied by Argonne National Laboratory (ANL, Lemont, Illinois), did not effectively protect cells containing NMC cathodes from overcharge. The ANL-RS2 redox shuttle molecule, namely 1,4-bis(2-methoxyethoxy)-2,5-di-tert-butyl-benzene, which is a derivative of the commercially successful redox shuttle 2,5-di-tert-butyl-1,4-dimethoxybenzene (DDB, 3M, St. Paul, Minnesota), is an effective redox shuttle for cells employing LiFePO{sub 4} (LFP) cathode material. The main advantage of ANL-RS2 over DDB is its larger solubility in electrolyte; however, ANL-RS2 is not as stable as DDB. This shuttle also may be effectively used to rebalance cells in strings that utilize LFP cathodes. The shuttle is compatible with both LTO and graphite anode materials although the cell with graphite degrades faster than the cell with LTO, possibly because of a reaction with the SEI layer. The degradation products of redox shuttle ANL-RS2 were positively identified. Commercially available redox shuttles Li{sub 2}B{sub 12}F{sub 12} (Air Products, Allentown, Pennsylvania and Showa Denko, Japan) and DDB were evaluated and were found to be stable and effective redox shuttles at low C-rates. The Li{sub 2}B{sub 12}F{sub 12} is suitable for lithium ion cells utilizing a high voltage cathode (potential that is higher than NMC) and the DDB is useful for lithium ion cells with LFP cathodes (potential that is lower than NMC). A 4.5 V class redox shuttle provided by Argonne National Laboratory was evaluated which provides a few cycles of overcharge protection for lithium ion cells containing NMC cathodes but it is not stable enough for consideration. Thus, a redox shuttle with an appropriate redox potential and sufficient chemical and electrochemical stability for commercial use in larger format lithium ion cells with NMC cathodes was not found. Molecular imprinting of the redox shuttle molecule during solid electrolyte interphase (SEI) layer formation likely contributes to the successful reduction of oxidized redox shuttle species at carbon anodes. This helps to understand how a carbon anode covered with an SEI layer, that is supposed to be electrically insulating, can reduce the oxidized form of a redox shuttle.

  15. Ion aggregation in high salt solutions: Ion network versus ion cluster

    SciTech Connect (OSTI)

    Kim, Seongheun; Kim, Heejae; Choi, Jun-Ho; Cho, Minhaeng, E-mail: mcho@korea.ac.kr [Department of Chemistry, Korea University, Seoul 136-713 (Korea, Republic of)

    2014-09-28T23:59:59.000Z

    The critical aggregation phenomena are ubiquitous in many self-assembling systems. Ions in high salt solutions could also spontaneously form larger ion aggregates, but their effects on hydrogen-bond structures in water have long been controversial. Here, carrying out molecular dynamics (MD) simulation studies of high salt solutions and comparing the MD simulation results with infrared absorption and pump-probe spectroscopy of O–D stretch mode of HDO in highly concentrated salt solutions and {sup 13}C-NMR chemical shift of S{sup 13}CN{sup ?} in KSCN solutions, we find evidence on the onset of ion aggregate and large-scale ion-ion network formation that concomitantly breaks water hydrogen-bond structure in certain salt solutions. Despite that these experimental results cannot provide direct evidence on the three-dimensional morphological structures of ion aggregates, they serve as reference data for verifying MD simulation methods. The MD results suggest that disrupted water hydrogen-bond network is intricately intertwined with ion-ion network. This further shows morphological variation of ion aggregate structures from ion cluster to ion network in high salt solutions that are interrelated to the onset of macroscopic aggregate formation and the water hydrogen-bond structure making and breaking processes induced by Hofmeister ions.

  16. Hydrogen Reduction of Ferric Ions for Use in Copper Electrowinning

    SciTech Connect (OSTI)

    Karl S. Noah; Debby F. Bruhn; John E. Wey; Robert S. Cherry

    2005-01-01T23:59:59.000Z

    The conventional copper electrowinning process uses the water hydrolysis reaction as the anodic source of electrons. However this reaction generates acid mist and requires large quantities of energy. In order to improve energy efficiency and avoid acid mist, an alternative anodic reaction of ferrous ion oxidation has been proposed. This reaction does not involve evolution of acid mist and can be carried out at a lower cell voltage than the conventional process. However, because ferrous ions are converted to ferric ions at the anode in this process, there is a need for reduction of ferric ions to ferrous ions to continue this process. The most promising method for this reduction is the use of hydrogen gas since the resulting byproduct acid can be used elsewhere in the process and, unlike other reductants, hydrogen does not introduce other species that need subsequent removal. Because the hydrogen reduction technology has undergone only preliminary lab scale testing, additional research is needed to evaluate its commercial potential. Two issues for this research are the potentially low mass transfer rate of hydrogen into the electrolyte stream because of its low solubility in water, and whether other gaseous reductants less expensive than hydrogen, such as natural gas or syngas, might work. In this study various reductants were investigated to carry out the reduction of ferric ions to ferrous ions using a simulated electrolyte solution recycled through a trickle bed reactor packed with catalyst. The gases tested as reductants were hydrogen, methane, carbon monoxide, and a 50/50 mixture of H2 and CO. Nitrogen was also tested as an inert control. These gases were tested because they are constituents in either natural gas or syngas. The catalysts tested were palladium and platinum. Two gas flow rates and five electrolyte flow rates were tested. Pure hydrogen was an effective reductant of ferric ion. The rates were similar with both palladium and platinum. The ferric iron reduction increased with both the flow rate of gas as well as the liquid flow rate (up to ~0.1 g/L/min). Pure carbon monoxide also reduced the ferric ion, but at a rate about one tenth that of pure hydrogen at similar conditions. The syngas mixture of equimolar hydrogen and carbon monoxide reacted at a rate intermediate between each gas as a pure stream (up to ~ 0.06 g/L/min). This gas mixture shows that some form of unpurified reformer gas could be used to reduce the ferric ion in the electrolyte solution. Nitrogen was inert causing very little to no reduction of ferric ion.

  17. A REVISED METHOD FOR ESTIMATING OXIDE BASICITY PER THE SMITH SCALE WITH EXAMPLE APPLICATION TO GLASS DURABILITY

    SciTech Connect (OSTI)

    REYNOLDS JG

    2011-07-27T23:59:59.000Z

    Previous researchers have developed correlations between oxide electronegativity and oxide basicity. The present paper revises those correlations using a newer method of calculating electronegativity of the oxygen anion. Basicity is expressed using the Smith {alpha} parameter scale. A linear relation was found between the oxide electronegativity and the Smith {alpha} parameter, with an R{sup 2} of 0.92. An example application of this new correlation to the durability of high-level nuclear waste glass is demonstrated. The durability of waste glass was found to be directly proportional to the quantity and basicity of the oxides of tetrahedrally coordinated network forming ions.

  18. Enhanced mercury oxidation

    SciTech Connect (OSTI)

    Gretta, W.J.; Wu, S.; Kikkawa, H. [Hitachi Power Systems America, Basting Ridge, NJ (United States)

    2009-06-15T23:59:59.000Z

    A new catalyst offers a new way to enhance mercury control from bituminous coal-fired power plants. Hitachi has developed an SCR catalyst which satisfies high Hg{sup 0} oxidation and low SO{sub 2} oxidation requirements under high temperatures (716 to 770 F). This triple action catalysts, TRAC can significantly enhance mercury oxidation and reduce or eliminate the need for additional mercury control measures such as activated carbon injection. After laboratory testing, pilot-scale tests confirmed an activity of 1.4-1.7 times higher than that of conventional SCR catalyst. The new catalyst has been successfully applied in a commercial PRB-fired boiler without the need for halogens to be added to the fuel feed or flue gas. 2 figs.

  19. Methanol partial oxidation reformer

    DOE Patents [OSTI]

    Ahmed, Shabbir (Bolingbrook, IL); Kumar, Romesh (Naperville, IL); Krumpelt, Michael (Naperville, IL)

    1999-01-01T23:59:59.000Z

    A partial oxidation reformer comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell.

  20. Methanol partial oxidation reformer

    DOE Patents [OSTI]

    Ahmed, Shabbir (Bolingbrook, IL); Kumar, Romesh (Naperville, IL); Krumpelt, Michael (Naperville, IL)

    2001-01-01T23:59:59.000Z

    A partial oxidation reformer comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell.

  1. Methanol partial oxidation reformer

    DOE Patents [OSTI]

    Ahmed, S.; Kumar, R.; Krumpelt, M.

    1999-08-24T23:59:59.000Z

    A partial oxidation reformer is described comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell. 7 figs.

  2. Methanol partial oxidation reformer

    DOE Patents [OSTI]

    Ahmed, S.; Kumar, R.; Krumpelt, M.

    1999-08-17T23:59:59.000Z

    A partial oxidation reformer is described comprising a longitudinally extending chamber having a methanol, water and an air inlet and an outlet. An igniter mechanism is near the inlets for igniting a mixture of methanol and air, while a partial oxidation catalyst in the chamber is spaced from the inlets and converts methanol and oxygen to carbon dioxide and hydrogen. Controlling the oxygen to methanol mole ratio provides continuous slightly exothermic partial oxidation reactions of methanol and air producing hydrogen gas. The liquid is preferably injected in droplets having diameters less than 100 micrometers. The reformer is useful in a propulsion system for a vehicle which supplies a hydrogen-containing gas to the negative electrode of a fuel cell. 7 figs.

  3. Characterization and In-Situ Ion-Irradiation of MA957 ODS Steel Djamel Kaoumi1

    E-Print Network [OSTI]

    Motta, Arthur T.

    Characterization and In-Situ Ion-Irradiation of MA957 ODS Steel Djamel Kaoumi1 , Arthur Motta1 Laboratory, Argonne, IL 060493, USA INTRODUCTION Oxide dispersion strengthened (ODS) Ferritic. EXPERIMENT Material Characterization Prior to Irradiation MA957 ODS alloy (Fe­14Cr­1Ti­0.3Mo­0.25Y2O3

  4. Three-Dimensional Coherent Titania-Mesoporous Carbon Nanocomposite and Its Lithium-Ion Storage Properties

    E-Print Network [OSTI]

    Cao, Guozhong

    Three-Dimensional Coherent Titania-Mesoporous Carbon Nanocomposite and Its Lithium-Ion Storage Properties Laifa Shen,, Evan Uchaker, Changzhou Yuan, Ping Nie, Ming Zhang, Xiaogang Zhang,*, and Guozhong into the channels of surface- oxidized mesoporous carbon (CMK-3) by means of electrostatic interaction, followed

  5. Indoor air quality implications of using ion generators in residences Michael S. Waring*

    E-Print Network [OSTI]

    Siegel, Jeffrey

    (IAQ). Positively, ion generators remove the charged particle contaminants to collector plates, Denmark - Paper ID: 598 #12;mortality and exposures to indoor ozone and its oxidation products. Ozone and Shields, 1999). Terpenes are common indoors and are emitted from consumer products such as air fresheners

  6. A disiloxane-functionalized phosphonium-based ionic liquid as electrolyte for lithium-ion batteries

    SciTech Connect (OSTI)

    Weng, Wei [Argonne National Lab. (ANL), Argonne, IL (United States). Chemical Science and Engineering Div.; Zhang, Zhengcheng [Argonne National Lab. (ANL), Argonne, IL (United States). Chemical Science and Engineering Div.; Lu, Jun [Argonne National Lab. (ANL), Argonne, IL (United States). Chemical Science and Engineering Div.; Amine, Khalil [Argonne National Lab. (ANL), Argonne, IL (United States). Chemical Science and Engineering Div.

    2011-01-01T23:59:59.000Z

    A disiloxane-functionalized ionic liquid based on a phosphonium cation and a bis(trifluoromethylsulfonyl)imide (TFSI) anion was synthesized and characterized. This new ionic liquid electrolyte showed good stability with a lithium transition metal oxide cathode and a graphite anode in lithium ion cells.

  7. Low temperature oxidation of plutonium

    SciTech Connect (OSTI)

    Nelson, Art J. [Lawrence Livermore National Laboratory, Livermore, California 94551 (United States); Roussel, Paul [AWE, Aldermaston, Reading, Berkshire, RG7 4PR (United Kingdom)

    2013-05-15T23:59:59.000Z

    The initial oxidation of gallium stabilized {delta}-plutonium metal at 193 K has been followed using x-ray photoelectron spectroscopy. On exposure to Langmuir quantities of oxygen, plutonium rapidly forms a trivalent oxide followed by a tetravalent plutonium oxide. The growth modes of both oxides have been determined. Warming the sample in vacuum, the tetravalent oxide reduces to the trivalent oxide. The kinetics of this reduction reaction have followed and the activation energy has been determined to be 38.8 kJ mol{sup -1}.

  8. Characterization of Amorphous Zinc Tin Oxide Semiconductors....

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Amorphous Zinc Tin Oxide Semiconductors. Characterization of Amorphous Zinc Tin Oxide Semiconductors. Abstract: Amorphous zinc tin oxide (ZTO) was investigated to determine the...

  9. Electron string ion sources for carbon ion cancer therapy accelerators

    E-Print Network [OSTI]

    Boytsov, A Yu; Donets, E D; Donets, E E; Katagiri, K; Noda, K; Ponkin, D O; Ramzdorf, A Yu; Salnikov, V V; Shutov, V B

    2015-01-01T23:59:59.000Z

    The Electron String type of Ion Sources (ESIS) was developed, constructed and tested first in the Joint Institute for Nuclear Research. These ion sources can be the appropriate sources for production of pulsed C4+ and C6+ ion beams which can be used for cancer therapy accelerators. In fact the test ESIS Krion-6T already now at the solenoid magnetic field only 4.6 T provides more than 10^10 C4+ ions per pulse and about 5*10^9 C6+ ions per pulse. Such ion sources could be suitable for application at synchrotrons. It was also found, that Krion-6T can provide more than 10^11 C6+ ions per second at 100 Hz repetition rate, and the repetition rate can be increased at the same or larger ion output per second. This makes ESIS applicable at cyclotrons as well. As for production of 11C radioactive ion beams ESIS can be the most economic kind of ion source. To proof that the special cryogenic cell for pulse injection of gaseous species into electron string was successfully tested using the ESIS Krion-2M.

  10. Conceptual Design for the Pilot-Scale Plutonium Oxide Processing Unit in the Radiochemical Processing Laboratory

    SciTech Connect (OSTI)

    Lumetta, Gregg J.; Meier, David E.; Tingey, Joel M.; Casella, Amanda J.; Delegard, Calvin H.; Edwards, Matthew K.; Jones, Susan A.; Rapko, Brian M.

    2014-08-05T23:59:59.000Z

    This report describes a conceptual design for a pilot-scale capability to produce plutonium oxide for use as exercise and reference materials, and for use in identifying and validating nuclear forensics signatures associated with plutonium production. This capability is referred to as the Pilot-scale Plutonium oxide Processing Unit (P3U), and it will be located in the Radiochemical Processing Laboratory at the Pacific Northwest National Laboratory. The key unit operations are described, including plutonium dioxide (PuO2) dissolution, purification of the Pu by ion exchange, precipitation, and conversion to oxide by calcination.

  11. Improving Corrosion Behavior in SCWR, LFR and VHTR Reactor Materials by Formation of a Stable Oxide

    SciTech Connect (OSTI)

    Arthur T. Motta; Robert Comstock; Ning Li; Todd Allen; Gary Was

    2009-12-21T23:59:59.000Z

    The objective of this study is to understand the influence of the alloy microstructure and composition on the formation of a stable, protective oxide in the environments relevant to the SCWR and LFR reactor concepts, as well as to the VHTR. It is proposed to use state-of-the art techniques to study the fine structure of these oxides to identify the structural differences between stable and unstable oxide layers. The techniques to be used are microbeam synchrotron radiation diffraction and fluorescence, and cross-sectional transmission electron microcopy on samples prepared using focused ion beam.

  12. Tetraalklylammonium polyoxoanionic oxidation catalysts

    DOE Patents [OSTI]

    Ellis, P.E.; Lyons, J.E.; Myers, H.K. Jr.; Shaikh, S.N.

    1998-10-06T23:59:59.000Z

    Alkanes are catalytically oxidized in air or oxygen using iron-substituted polyoxoanions (POAs) of the formula: H{sub e{minus}z}[(n-C{sub 4}H{sub 9}){sub 4}N]{sub z}(XM{sub 11}M{prime}O{sub 39}){sup {minus}e}. The M{prime} (e.g., iron(III)/iron(II)) reduction potential of the POAs is affected by selection of the central atom X and the framework metal M, and by the number of tetrabutyl-ammonium groups. Decreased Fe(III)/Fe(II) reduction potential has been found to correlate to increased oxidation activity.

  13. Tetraalykylammonium polyoxoanionic oxidation catalysts

    DOE Patents [OSTI]

    Ellis, Paul E. (Downingtown, PA); Lyons, James E. (Wallingford, PA); Myers, Jr., Harry K. (Cochranville, PA); Shaikh, Shahid N. (Media, PA)

    1998-01-01T23:59:59.000Z

    Alkanes are catalytically oxidized in air or oxygen using iron-substituted polyoxoanions (POAs) of the formula: H.sub.e-z ›(n-C.sub.4 H.sub.9).sub.4 N!.sub.z (XM.sub.11 M'O.sub.39).sup.-e The M' (e.g., iron(III)/iron(II)) reduction potential of the POAs is affected by selection of the central atom X and the framework metal M, and by the number of tetrabutyl-ammonium groups. Decreased Fe(III)/Fe(II) reduction potential has been found to correlate to increased oxidation activity.

  14. Nanostructured transition metal oxides useful for water oxidation catalysis

    DOE Patents [OSTI]

    Frei, Heinz M; Jiao, Feng

    2013-12-24T23:59:59.000Z

    The present invention provides for a composition comprising a nanostructured transition metal oxide capable of oxidizing two H.sub.2O molecules to obtain four protons. In some embodiments of the invention, the composition further comprises a porous matrix wherein the nanocluster of the transition metal oxide is embedded on and/or in the porous matrix.

  15. SOLID OXIDE PLANAR AND TUBULAR SOLID OXIDE FUEL

    E-Print Network [OSTI]

    Mease, Kenneth D.

    SOLID OXIDE PLANAR AND TUBULAR SOLID OXIDE FUEL CELLS Dynamic Simulation Approach Modular Approach: Individual simulation modules for each fuel cell type · Tubular SOFC · Planar SOFC · MCFC · PEM Reformer · Slow pressure transients #12;Fuel Cell Assumptions · H2 electrochemically oxidized only · CO consumed

  16. Oxidative Reforming of Biodiesel Over Molybdenum (IV) Oxide

    E-Print Network [OSTI]

    Collins, Gary S.

    Oxidative Reforming of Biodiesel Over Molybdenum (IV) Oxide Jessica Whalen, Oscar Marin Flores, Su University INTRODUCTION Energy consumption continues to skyrocket worldwide. Biodiesel is a renewable fuel as potential feedstock in solid oxide fuel cells. Petroleum based fuels become scarcer daily, and biodiesel

  17. Atomic Scale Picture of the Ion Conduction Mechanism in Tetrahedral Network of Lanthanum Barium Gallate

    SciTech Connect (OSTI)

    Jalarvo, Niina H [ORNL] [ORNL; Gourdon, Olivier [ORNL] [ORNL; Bi, Zhonghe [ORNL] [ORNL; Gout, Delphine J [ORNL] [ORNL; Ohl, Michael E [ORNL] [ORNL; Paranthaman, Mariappan Parans [ORNL] [ORNL

    2013-01-01T23:59:59.000Z

    Combined experimental study of impedance spectroscopy, neutron powder diffraction and quasielastic neutron scattering was performed to shed light into the atomic scale ion migration processes in proton and oxide ion conductor; La0.8Ba1.2GaO3.9 . This material consist of tetrahedral GaO4 units, which are rather flexible and rocking motion of these units promotes the ionic migration process. The oxide ion (vacancy) conduction takes place on channels along c axis, involving a single elementary step, which occurs between adjacent tetrahedron (inter-tetrahedron jump). The proton conduction mechanism consists of intra-tetrahedron and inter-tetrahedron elementary processes. The intra-tetrahedron proton transport is the rate-limiting process, with activation energy of 0.44 eV. The rocking motion of the GaO4 tetrahedron aids the inter-tetrahedral proton transport, which has the activation energy of 0.068 eV.

  18. Doped zinc oxide microspheres

    DOE Patents [OSTI]

    Arnold, W.D. Jr.; Bond, W.D.; Lauf, R.J.

    1993-12-14T23:59:59.000Z

    A new composition and method of making same for a doped zinc oxide microsphere and articles made therefrom for use in an electrical surge arrestor which has increased solid content, uniform grain size and is in the form of a gel. 4 figures.

  19. Highly oxidized superconductors

    DOE Patents [OSTI]

    Morris, Donald E. (Kensington, CA)

    1994-01-01T23:59:59.000Z

    Novel superconducting materials in the form of compounds, structures or phases are formed by performing otherwise known syntheses in a highly oxidizing atmosphere rather than that created by molecular oxygen at atmospheric pressure or below. This leads to the successful synthesis of novel superconducting compounds which are thermodynamically stable at the conditions under which they are formed.

  20. Highly oxidized superconductors

    DOE Patents [OSTI]

    Morris, D.E.

    1994-09-20T23:59:59.000Z

    Novel superconducting materials in the form of compounds, structures or phases are formed by performing otherwise known synthesis in a highly oxidizing atmosphere rather than that created by molecular oxygen at atmospheric pressure or below. This leads to the successful synthesis of novel superconducting compounds which are thermodynamically stable at the conditions under which they are formed. 16 figs.

  1. Optically transparent yttrium oxide

    SciTech Connect (OSTI)

    Hartnett, T.; Greenberg, M.; Gentilman, R.L.

    1988-08-02T23:59:59.000Z

    A body is described comprising at least 99.9% yttrium oxide having a density of at least 99% of theoretically density, a sample of the body having a in-line transmission of at least 73%, over a wavelength range of 2-5 microns with the sample having a thickness of 0.375 inches.

  2. Controlling ion fluxes during reactive sputter-deposition of SnO{sub 2}:F

    SciTech Connect (OSTI)

    Jäger, Timo, E-mail: timo.jaeger@empa.ch; Romanyuk, Yaroslav E.; Tiwari, Ayodhya N. [Empa—Swiss Federal Laboratories for Materials Science and Technology, Laboratory for Thin Films and Photovoltaics, Überlandstrasse 129, 8600 Dübendorf (Switzerland); Anders, André [Lawrence Berkeley National Laboratory, 1 Cyclotron Road, Berkeley, California 94720 (United States)

    2014-07-21T23:59:59.000Z

    Magnetron sputtering of fluorine-doped tin oxide (FTO) is a scalable deposition method for large-area transparent conducting films used in fenestration, photovoltaics, and other applications. The electrical conductivity of sputtered FTO is, however, lower than that of spray-pyrolized FTO because of the ion damage induced by high energy ions leading to a reduction of the crystal quality in sputtered FTO films. In this study, various ion species present during the reactive sputtering of a metallic tin target in a mixed Ar/O{sub 2}/CF{sub 4} atmosphere are systematically characterized by energy and mass spectrometry, and possible ways of controlling the ion fluxes are explored. Ion energy distribution functions (IEDFs) of the negative ions F{sup ?} and O{sup ?} exhibit large peaks at an energy corresponding to the full target voltage. Although the applied partial pressure of CF{sub 4} is about 1/30 than that of O{sub 2}, the obtained IEDFs of F{sup ?} and O{sup ?} have comparable peak height, which can be attributed to a higher electronegativity of F. The IEDFs of positively charged O{sup +}, O{sub 2}{sup +}, Ar{sup +}, and Sn{sup +} species have their peaks around 2–8?eV. To control ion fluxes a solenoid or permanent magnets were placed between the target and the mass spectrometer. The flux of positive ions could be varied by several orders of magnitude as a function of the applied current through the solenoid, whereas the high-energy (>100?eV) negative F{sup ?} and O{sup ?} ions were not notably deflected. By using permanent magnets with the B-field orthogonal to the ion trajectory, the flux of O{sup ?} ions could be decreased by two orders and the exposure to the high-energy F{sup ?} ions was completely suppressed.

  3. Characterization of Ion Dynamics in Structures for Lossless Ion...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    in regard to the extent of collisional activation, similarly to RF-only multipole ion guides and traps. The segmentation of the RF rung electrodes and guards along...

  4. A novel planar ion funnel design for miniature ion optics

    SciTech Connect (OSTI)

    Chaudhary, A.; Amerom, Friso H. W. van; Short, R. T. [Space and Marine Technology Laboratory, SRI International, 450 8th Ave SE, St. Petersburg, Florida 33701 (United States)

    2014-10-15T23:59:59.000Z

    The novel planar ion funnel (PIF) design presented in this article emphasizes simple fabrication, assembly, and operation, making it amenable to extreme miniaturization. Simulations performed in SIMION 8.0 indicate that ion focusing can be achieved by using a gradient of electrostatic potentials on concentric metal rings in a plane. A prototype was fabricated on a 35 × 35 mm custom-designed printed circuit board (PCB) with a center hole for ions to pass through and a series of concentric circular metal rings of increasing diameter on the front side of the PCB. Metal vias on the PCB electrically connected each metal ring to a resistive potential divider that was soldered on the back of the PCB. The PIF was tested at 5.5 × 10{sup ?6} Torr in a vacuum test setup that was equipped with a broad-beam ion source on the front and a micro channel plate (MCP) ion detector on the back of the PIF. The ion current recorded on the MCP anode during testing indicated a 23× increase in the ion transmission through the PIF when electric potentials were applied to the rings. These preliminary results demonstrate the functionality of a 2D ion funnel design with a much smaller footprint and simpler driving electronics than conventional 3D ion funnels. Future directions to improve the design and a possible micromachining approach to fabrication are discussed in the conclusions.

  5. REVIEW OF PLUTONIUM OXIDATION LITERATURE

    SciTech Connect (OSTI)

    Korinko, P.

    2009-11-12T23:59:59.000Z

    A brief review of plutonium oxidation literature was conducted. The purpose of the review was to ascertain the effect of oxidation conditions on oxide morphology to support the design and operation of the PDCF direct metal oxidation (DMO) furnace. The interest in the review was due to a new furnace design that resulted in oxide characteristics that are different than those of the original furnace. Very little of the published literature is directly relevant to the DMO furnace operation, which makes assimilation of the literature data with operating conditions and data a convoluted task. The oxidation behavior can be distilled into three regimes, a low temperature regime (RT to 350 C) with a relatively slow oxidation rate that is influenced by moisture, a moderate temperature regime (350-450 C) that is temperature dependent and relies on more or less conventional oxidation growth of a partially protective oxide scale, and high temperature oxidation (> 500 C) where the metal autocatalytically combusts and oxidizes. The particle sizes obtained from these three regimes vary with the finest being from the lowest temperature. It is surmised that the slow growth rate permits significant stress levels to be achieved that help break up the oxides. The intermediate temperatures result in a fairly compact scale that is partially protective and that grows to critical thickness prior to fracturing. The growth rate in this regime may be parabolic or paralinear, depending on the oxidation time and consequently the oxide thickness. The high temperature oxidation is invariant in quiescent or nearly quiescent conditions due to gas blanketing while it accelerates with temperature under flowing conditions. The oxide morphology will generally consist of fine particles (<15 {micro}m), moderately sized particles (15 < x < 250 {micro}m) and large particles (> 250 {micro}m). The particle size ratio is expected to be < 5%, 25%, and 70% for fine, medium and large particles, respectively, for metal temperatures in the 500-600 C range.

  6. Molecular responses of mouse macrophages to copper and copper oxide nanoparticles inferred from proteomic analyses

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    enhanced cell vulnerability to copper-based nanoparticles but not to copper ion. Furthermore, functional1 Molecular responses of mouse macrophages to copper and copper oxide nanoparticles inferred from, Service de Chimie Inorganique et Biologique, Laboratoire Lésions des Acides Nucléiques (LAN), Grenoble 5

  7. Lithium manganese oxide films fabricated by electron beam directed vapor deposition

    E-Print Network [OSTI]

    Wadley, Haydn

    material for high energy den- sity battery applications.7,8 Lithium­transition metal oxide films can.2. After annealing in air at 700 °C, thin films grown with a low jet speed had a cubic spinel structure Li/Li-ion batteries. © 2008 American Vacuum Society. DOI: 10.1116/1.2823488 I. INTRODUCTION Thin film

  8. Doped palladium containing oxidation catalysts

    DOE Patents [OSTI]

    Mohajeri, Nahid

    2014-02-18T23:59:59.000Z

    A supported oxidation catalyst includes a support having a metal oxide or metal salt, and mixed metal particles thereon. The mixed metal particles include first particles including a palladium compound, and second particles including a precious metal group (PMG) metal or PMG metal compound, wherein the PMG metal is not palladium. The oxidation catalyst may also be used as a gas sensor.

  9. Mini ion trap mass spectrometer

    DOE Patents [OSTI]

    Dietrich, Daniel D. (Livermore, CA); Keville, Robert F. (Valley Springs, CA)

    1995-01-01T23:59:59.000Z

    An ion trap which operates in the regime between research ion traps which can detect ions with a mass resolution of better than 1:10.sup.9 and commercial mass spectrometers requiring 10.sup.4 ions with resolutions of a few hundred. The power consumption is kept to a minimum by the use of permanent magnets and a novel electron gun design. By Fourier analyzing the ion cyclotron resonance signals induced in the trap electrodes, a complete mass spectra in a single combined structure can be detected. An attribute of the ion trap mass spectrometer is that overall system size is drastically reduced due to combining a unique electron source and mass analyzer/detector in a single device. This enables portable low power mass spectrometers for the detection of environmental pollutants or illicit substances, as well as sensors for on board diagnostics to monitor engine performance or for active feedback in any process involving exhausting waste products.

  10. Mini ion trap mass spectrometer

    DOE Patents [OSTI]

    Dietrich, D.D.; Keville, R.F.

    1995-09-19T23:59:59.000Z

    An ion trap is described which operates in the regime between research ion traps which can detect ions with a mass resolution of better than 1:10{sup 9} and commercial mass spectrometers requiring 10{sup 4} ions with resolutions of a few hundred. The power consumption is kept to a minimum by the use of permanent magnets and a novel electron gun design. By Fourier analyzing the ion cyclotron resonance signals induced in the trap electrodes, a complete mass spectra in a single combined structure can be detected. An attribute of the ion trap mass spectrometer is that overall system size is drastically reduced due to combining a unique electron source and mass analyzer/detector in a single device. This enables portable low power mass spectrometers for the detection of environmental pollutants or illicit substances, as well as sensors for on board diagnostics to monitor engine performance or for active feedback in any process involving exhausting waste products. 10 figs.

  11. Ion exchange technology assessment report

    SciTech Connect (OSTI)

    Duhn, E.F.

    1992-01-01T23:59:59.000Z

    In the execution of its charter, the SRS Ion Exchange Technology Assessment Team has determined that ion exchange (IX) technology has evolved to the point where it should now be considered as a viable alternative to the SRS reference ITP/LW/PH process. The ion exchange media available today offer the ability to design ion exchange processing systems tailored to the unique physical and chemical properties of SRS soluble HLW's. The technical assessment of IX technology and its applicability to the processing of SRS soluble HLW has demonstrated that IX is unquestionably a viable technology. A task team was chartered to evaluate the technology of ion exchange and its potential for replacing the present In-Tank Precipitation and proposed Late Wash processes to remove Cs, Sr, and Pu from soluble salt solutions at the Savannah River Site. This report documents the ion exchange technology assessment and conclusions of the task team.

  12. Ion exchange technology assessment report

    SciTech Connect (OSTI)

    Duhn, E.F.

    1992-12-31T23:59:59.000Z

    In the execution of its charter, the SRS Ion Exchange Technology Assessment Team has determined that ion exchange (IX) technology has evolved to the point where it should now be considered as a viable alternative to the SRS reference ITP/LW/PH process. The ion exchange media available today offer the ability to design ion exchange processing systems tailored to the unique physical and chemical properties of SRS soluble HLW`s. The technical assessment of IX technology and its applicability to the processing of SRS soluble HLW has demonstrated that IX is unquestionably a viable technology. A task team was chartered to evaluate the technology of ion exchange and its potential for replacing the present In-Tank Precipitation and proposed Late Wash processes to remove Cs, Sr, and Pu from soluble salt solutions at the Savannah River Site. This report documents the ion exchange technology assessment and conclusions of the task team.

  13. Preparation of amorphous electrochromic tungsten oxide and molybdenum oxide by plasma enhanced chemical vapor deposition

    SciTech Connect (OSTI)

    Tracy, C.E.; Benson, D.K.

    1986-09-01T23:59:59.000Z

    Preliminary experiments have been performed to probe the feasibility of using plasma enhanced chemical vapor deposition (PE--CVD) to prepare electrochromic thin films of tungsten oxide and molybdenum oxide by plasma reaction of WF/sub 6/, W(CO)/sub 6/, and Mo(CO)/sub 6/ with oxygen. Thin films produced in a 300 W, electrodeless, radio-frequency (rf), capacitive discharge were found to be electrochromic when tested with either liquid or solid electrolytes. Optical spectroscopy was performed on two electrochromic coatings after Li/sup +/ ion insertion from a propylene carbonate liquid electrolyte. Broad absorption peaks at --900 nm for WO/sub 3/ and 600 nm for MoO/sub 3/ were observed. Optical results for PE--CVD MoO/sub 3/ films differ from those reported for evaporated MoO/sub 3/ films which have an absorption peak at --800 nm. The shorter wavelength absorption in the PE--CVD MoO/sub 3/ films offers the potential for fabricating electrochromic devices with higher contrast ratios and less color change. Optical emission spectroscopy, Auger, and x-ray diffraction analyses indicate these thin film deposits to be predominantly amorphous tungsten and molybdenum oxides.

  14. Improved ion detector

    DOE Patents [OSTI]

    Tullis, A.M.

    1986-01-30T23:59:59.000Z

    An improved ion detector device of the ionization detection device chamber type comprises an ionization chamber having a central electrode therein surrounded by a cylindrical electrode member within the chamber with a collar frictionally fitted around at least one of the electrodes. The collar has electrical contact means carried in an annular groove in an inner bore of the collar to contact the outer surface of the electrode to provide electrical contact between an external terminal and the electrode without the need to solder leads to the electrode.

  15. Ion beam lithography system

    DOE Patents [OSTI]

    Leung, Ka-Ngo

    2005-08-02T23:59:59.000Z

    A maskless plasma-formed ion beam lithography tool provides for patterning of sub-50 nm features on large area flat or curved substrate surfaces. The system is very compact and does not require an accelerator column and electrostatic beam scanning components. The patterns are formed by switching beamlets on or off from a two electrode blanking system with the substrate being scanned mechanically in one dimension. This arrangement can provide a maskless nano-beam lithography tool for economic and high throughput processing.

  16. Compact ion accelerator source

    DOE Patents [OSTI]

    Schenkel, Thomas; Persaud, Arun; Kapadia, Rehan; Javey, Ali

    2014-04-29T23:59:59.000Z

    An ion source includes a conductive substrate, the substrate including a plurality of conductive nanostructures with free-standing tips formed on the substrate. A conductive catalytic coating is formed on the nanostructures and substrate for dissociation of a molecular species into an atomic species, the molecular species being brought in contact with the catalytic coating. A target electrode placed apart from the substrate, the target electrode being biased relative to the substrate with a first bias voltage to ionize the atomic species in proximity to the free-standing tips and attract the ionized atomic species from the substrate in the direction of the target electrode.

  17. Model catalytic oxidation studies using supported monometallic and heterobimetallic oxides

    SciTech Connect (OSTI)

    Ekerdt, J.G.

    1992-02-03T23:59:59.000Z

    This research program is directed toward a more fundamental understanding of the effects of catalyst composition and structure on the catalytic properties of metal oxides. Metal oxide catalysts play an important role in many reactions bearing on the chemical aspects of energy processes. Metal oxides are the catalysts for water-gas shift reactions, methanol and higher alcohol synthesis, isosynthesis, selective catalytic reduction of nitric oxides, and oxidation of hydrocarbons. A key limitation to developing insight into how oxides function in catalytic reactions is in not having precise information of the surface composition under reaction conditions. To address this problem we have prepared oxide systems that can be used to study cation-cation effects and the role of bridging (-O-) and/or terminal (=O) surface oxygen anion ligands in a systematic fashion. Since many oxide catalyst systems involve mixtures of oxides, we selected a model system that would permit us to examine the role of each cation separately and in pairwise combinations. Organometallic molybdenum and tungsten complexes were proposed for use, to prepare model systems consisting of isolated monomeric cations, isolated monometallic dimers and isolated bimetallic dimers supported on silica and alumina. The monometallic and bimetallic dimers were to be used as models of more complex mixed- oxide catalysts. Our current program was to develop the systems and use them in model oxidation reactions.

  18. Graphene and Graphene Oxide: Biofunctionalization and Applications...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and Graphene Oxide: Biofunctionalization and Applications in Biotechnology. Graphene and Graphene Oxide: Biofunctionalization and Applications in Biotechnology. Abstract: Graphene...

  19. Model catalytic oxidation studies using supported monometallic and heterobimetallic oxides

    SciTech Connect (OSTI)

    Ekerdt, J.G.

    1991-04-30T23:59:59.000Z

    This research program is directed toward developing a fundamental understanding of how catalyst composition, redox ability, and structure control the catalytic properties of metal oxides. Oxide systems that permit examination of the role of metal oxide cations separately and in pairwise combinations are being developed. Organometallic complexes containing C{sub 3}-allyl, cyclopentadienyl, or carbonyl ligands are exchanged with the hydroxide ligands of silica, alumina, titania, zirconia and magnesia supports. The exchange technique is used to achieve high metal oxide loadings without the formation of supported crystallites over silica. The organometallic route may also lead to oxygen-bridged cations and/or cation pairs over the supports prior to full oxidation. The anchored complex is subsequently oxidized to generate a supported oxide. 2 refs., 1 tab.

  20. RHIC | Electron-Ion Collider

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    is a ripple, the product of those pre-smash particles flying at relativistic speeds. By examining accelerated ions directly, scientists might clearly identify physics phenomena...

  1. RHIC | Relativistic Heavy Ion Collider

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Photo of LINAC The Relativistic Heavy Ion Collider (RHIC) is a world-class particle accelerator at Brookhaven National Laboratory where physicists are exploring the most...

  2. DIVALENT ION EXCHANGE WITH ALKALI

    E-Print Network [OSTI]

    Bunge, A.L.

    2011-01-01T23:59:59.000Z

    Injection for Enhanced Oil Recovery - A Status Report," SPEDOE Symposium on Enhanced Oil Recovery, Tulsa, OK, Apri120-ions is important enhanced oil recovery with chemical addi-

  3. Electrospun and oxidized cellulose materials for environmental remediation of heavy metals in groundwater

    SciTech Connect (OSTI)

    Han, Dong [Stony Brook University (SUNY); Halada, Gary P. [Stony Brook University (SUNY); Spalding, Brian Patrick [ORNL; Brooks, Scott C [ORNL

    2009-12-01T23:59:59.000Z

    This chapter focuses on the use of modified cellulosic materials in the field of environmental remediation. Two different chemical methods were involved in fabricating oxidized cellulose (OC), which has shown promise as a metal ion chelator in environmental applications. Electrospinning was utilized to introduce a more porous structure into an oxidized cellulose matrix. FTIR and Raman spectroscopy were used to study both the formation of OC and its surface complexation with metal ions. IR and Raman spectroscopic data demonstrate the formation of characteristic carboxylic groups in the structure of the final products and the successful formation of OC-metal complexes. Subsequent field tests at the Field Research Site at Oak Ridge National Laboratory confirmed the value of OC for sorption of both U and Th ions.

  4. Methane oxidation over dual redox catalysts. Final report

    SciTech Connect (OSTI)

    Klier, K.; Herman, R.G.; Sojka, Z.; DiCosimo, J.I.; DeTavernier, S.

    1992-06-01T23:59:59.000Z

    Catalytic oxidation of methane to partial oxidation products, primarily formaldehyde and C{sub 2} hydrocarbons, was found to be directed by the catalyst used. In this project, it was discovered that a moderate oxidative coupling catalyst for C{sub 2} hydrocarbons, zinc oxide, is modified by addition of small amounts of Cu and Fe dopants to yield fair yields of formaldehyde. A similar effect was observed with Cu/Sn/ZnO catalysts, and the presence of a redox Lewis acid, Fe{sup III} or Sn{sup IV}, was found to be essential for the selectivity switch from C{sub 2} coupling products to formaldehyde. The principle of double doping with an oxygen activator (Cu) and the redox Lewis acid (Fe, Sn) was pursued further by synthesizing and testing the CuFe-ZSM-5 zeolite catalyst. The Cu{sup II}(ion exchanged) Fe{sup III}(framework)-ZSM-5 also displayed activity for formaldehyde synthesis, with space time yields exceeding 100 g/h-kg catalyst. However, the selectivity was low and earlier claims in the literature of selective oxidation of methane to methanol over CuFe-ZSM-5 were not reproduced. A new active and selective catalytic system (M=Sb,Bi,Sn)/SrO/La{sub 2}O{sub 3} has been discovered for potentially commercially attractive process for the conversion of methane to C{sub 2} hydrocarbons, (ii) a new principle has been demonstrated for selectivity switching from C{sub 2} hydrocarbon products to formaldehyde in methane oxidations over Cu,Fe-doped zinc oxide and ZSM-5, and (iii) a new approach has been initiated for using ultrafine metal dispersions for low temperature activation of methane for selective conversions. Item (iii) continues being supported by AMOCO while further developments related to items (i) and (ii) are the objective of our continued effort under the METC-AMOCO proposed joint program.

  5. Nickel vacancy behavior in the electrical conductance of nonstoichiometric nickel oxide film

    SciTech Connect (OSTI)

    Kim, Dong Soo; Lee, Hee Chul [Department of Electrical Engineering, Korea Advanced Institute of Science and Technology, 335 Gwahangno, Yuseong-gu, Daejeon 305-701 (Korea, Republic of)

    2012-08-01T23:59:59.000Z

    Nickel vacancy behavior in electrical conductance is systematically investigated using various analysis methods on nickel oxide films deposited at different oxygen partial pressures. The results of Rutherford backscattering, x-ray diffraction, and Auger electron spectroscopy analyses demonstrate that the sputtered nickel oxide films are nickel-deficient. Through the deconvolution of Ni2p and O1s spectra in the x-ray photoelectron spectroscopy data, the number of Ni{sup 3+} ions is found to increase with the O{sub 2} ratio during the deposition. According to the vacancy model, nickel vacancies created from the non-stoichiometry are concluded to produce Ni{sup 3+} ions which lead to an increment of the conductivity of the nickel oxide films due to the increase of the hole concentration.

  6. Feasibility study of a laser ion source for primary ion injection into the Relativistic Heavy Ion Collider electron beam ion sourcea...

    E-Print Network [OSTI]

    chamber to be able to change ion species on a pulse by pulse basis. The optimal plasma drift length variesFeasibility study of a laser ion source for primary ion injection into the Relativistic Heavy Ion Collider electron beam ion sourcea... Takeshi Kanesue Department of Applied Quantum Physics and Nuclear

  7. Efficient reversible electrodes for solid oxide electrolyzer cells

    DOE Patents [OSTI]

    Elangovan, S.; Hartvigsen, Joseph J.; Zhao, Feng

    2013-01-15T23:59:59.000Z

    An electrolyzer cell is disclosed which includes a cathode to reduce an oxygen-containing molecule, such as H2O, CO.sub.2, or a combination thereof, to produce an oxygen ion and a fuel molecule, such as H.sub.2, CO, or a combination thereof. An electrolyte is coupled to the cathode to transport the oxygen ion to an anode. The anode is coupled to the electrolyte to receive the oxygen ion and produce oxygen gas therewith. In one embodiment, the anode may be fabricated to include an electron-conducting phase having a perovskite crystalline structure or structure similar thereto. This perovskite may have a chemical formula of substantially (Pr(.sub.1-x)La.sub.x)(z-y)A'.sub.yBO(3-.differential.), wherein 0oxide intermixed with magnesium oxide.

  8. Efficient reversible electrodes for solid oxide electrolyzer cells

    DOE Patents [OSTI]

    Elangovan, Singaravelu (South Jordan, UT); Hartvigsen, Joseph J. (Kaysville, UT)

    2011-07-12T23:59:59.000Z

    An electrolyzer cell is disclosed which includes a cathode to reduce an oxygen-containing molecule, such as H2O, CO2, or a combination thereof, to produce an oxygen ion and a fuel molecule, such as H2, CO, or a combination thereof. An electrolyte is coupled to the cathode to transport the oxygen ion to an anode. The anode is coupled to the electrolyte to receive the oxygen ion and produce oxygen gas therewith. In one embodiment, the anode may be fabricated to include an electron-conducting phase having a perovskite crystalline structure or structure similar thereto. This perovskite may have a chemical formula of substantially (Pr(1-x)Lax)(z-y)A'yBO(3-.differential.), wherein 0.ltoreq.x.ltoreq.0.5, 0.ltoreq.y.ltoreq.0.5, and 0.8.ltoreq.z.ltoreq.1.1. In another embodiment, the cathode includes an electron-conducting phase that contains nickel oxide intermixed with magnesium oxide.

  9. Molecular dynamics simulations of ion range profiles for heavy...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    simulations of ion range profiles for heavy ions in light targets. Molecular dynamics simulations of ion range profiles for heavy ions in light targets. Abstract: The determination...

  10. asymmetric ion mobility: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    High-Field Ion Mobility ions, including isotopomers and isobars, using ion mobility spectrometry (IMS), specifically, the field) and ion mobility spectrometry (IMS).1,2 Though both...

  11. Apparatus and method of dissociating ions in a multipole ion guide

    DOE Patents [OSTI]

    Webb, Ian K.; Tang, Keqi; Smith, Richard D.; Ibrahim, Yehia M.; Anderson, Gordon A.

    2014-07-08T23:59:59.000Z

    A method of dissociating ions in a multipole ion guide is disclosed. A stream of charged ions is supplied to the ion guide. A main RF field is applied to the ion guide to confine the ions through the ion guide. An excitation RF field is applied to one pair of rods of the ion guide. The ions undergo dissociation when the applied excitation RF field is resonant with a secular frequency of the ions. The multipole ion guide is, but not limited to, a quadrupole, a hexapole, and an octopole.

  12. Millisecond Oxidation of Alkanes

    Broader source: Energy.gov [DOE]

    This factsheet describes a project whose goal is to commercialize a production process for propylene and acrylic acid from propane using a catalytic auto-thermal oxydehydrogenation process operating at short contact times. Auto-thermal oxidation for conversion of propane to propylene and acrylic acid promises energy savings of 20 trillion Btu per year by 2020. In addition to reducing energy consumption, this technology can reduce manufacturing costs by up to 25 percent, and reduce a variety of greenhouse gas emissions.

  13. Nonisostructural complex oxide heteroepitaxy

    SciTech Connect (OSTI)

    Wong, Franklin J., E-mail: fwong@seas.harvard.edu; Ramanathan, Shriram [School of Engineering and Applied Sciences, Harvard University, Cambridge, Massachusetts 02138 (United States)

    2014-07-01T23:59:59.000Z

    The authors present an overview of the fundamentals and representative examples of the growth of epitaxial complex oxide thin films on structurally dissimilar substrates. The authors will delineate how the details of particular crystal structures and symmetry of different oxide surfaces can be employed for a rational approach to the synthesis of nonisostructural epitaxial heterostructures. The concept of oxygen eutaxy can be widely applied. Materials combinations will be split into three categories, and in all cases the films and substrates occur in different crystal structures: (1) common translational and rotational symmetry between the film and substrate planes; (2) translational symmetry mismatch between the substrates and films that is distinct from a simple mismatch in lattice parameters; and (3) rotational symmetry mismatch. In case (1), in principle single-crystalline thin films can be attained despite the films and substrates possessing different crystal structures. In case (2), antiphase boundaries will be prevalent in the thin films. In case (3), thin-film rotational variants that are joined by tilt boundaries will be present. Diffraction techniques to determine crystallographic alignment and epitaxial variants are discussed, and transmission electron microscopy studies to investigate extended defects in the thin films will also be reviewed. The authors end with open problems in this field regarding the structure of oxide interfaces that can be topics for future research.

  14. Hydrophilic property by contact angle change of ion implanted polycarbonate

    SciTech Connect (OSTI)

    Lee, Chan Young; Kil, Jae Keun [Proton Engineering Frontier Project, Korea Atomic Energy Research Institute, P.O. Box 105, Yuseong, Daejeon, 305-600 (Korea, Republic of); R and D Team, Accel Korea, 146-1 Pyeongchon-dong Daeduck-gu Daejeon (Korea, Republic of)

    2008-02-15T23:59:59.000Z

    In this study, ion implantation was performed onto a polymer, polycarbonate (PC), in order to investigate surface hydrophilic property through contact angle measurement. PC was irradiated with N, Ar, and Xe ions at the irradiation energy of 20-50 keV and the dose range of 5x10{sup 15}, 1x10{sup 16}, 7x10{sup 16} ions/cm{sup 2}. The contact angle of water was estimated by means of the sessile drop method and was reduced with increasing fluence and ion mass but increased with increasing implanted energy. The changes of chemical and structural properties are discussed in view of Furier transform infrared and x-ray photoelectron spectroscopy, which shows increasing C-O bonding and C-C bonding. The surface roughness examined by atomic force microscopy measurement changed smoothly from 3.59 to 2.22 A as the fluence increased. It is concluded that the change in wettability may be caused by surface carbonization and oxidation as well as surface roughness.

  15. Cryogenic silicon surface ion trap

    E-Print Network [OSTI]

    Michael Niedermayr; Kirill Lakhmanskiy; Muir Kumph; Stefan Partel; Johannes Edlinger; Michael Brownnutt; Rainer Blatt

    2015-05-01T23:59:59.000Z

    Trapped ions are pre-eminent candidates for building quantum information processors and quantum simulators. They have been used to demonstrate quantum gates and algorithms, quantum error correction, and basic quantum simulations. However, to realise the full potential of such systems and make scalable trapped-ion quantum computing a reality, there exist a number of practical problems which must be solved. These include tackling the observed high ion-heating rates and creating scalable trap structures which can be simply and reliably produced. Here, we report on cryogenically operated silicon ion traps which can be rapidly and easily fabricated using standard semiconductor technologies. Single $^{40}$Ca$^+$ ions have been trapped and used to characterize the trap operation. Long ion lifetimes were observed with the traps exhibiting heating rates as low as $\\dot{\\bar{n}}=$ 0.33 phonons/s at an ion-electrode distance of 230 $\\mu$m. These results open many new avenues to arrays of micro-fabricated ion traps.

  16. Metal vapor arc ion plating

    DOE Patents [OSTI]

    Bertram, L.A.; Fisher, R.W.; Mattox, D.M.; Zanner, F.J.

    1986-09-09T23:59:59.000Z

    A method and apparatus for ion plating are described. The apparatus uses more negative than a first electrode voltage in a vacuum arc remelt system to attract low energy ions from the anode electrode to the article to be plated. 2 figs.

  17. Laser acceleration of ion beams

    E-Print Network [OSTI]

    I. A. Egorova; A. V. Filatov; A. V. Prozorkevich; S. A. Smolyansky; D. B. Blaschke; M. Chubaryan

    2007-02-01T23:59:59.000Z

    We consider methods of charged particle acceleration by means of high-intensity lasers. As an application we discuss a laser booster for heavy ion beams provided, e.g. by the Dubna nuclotron. Simple estimates show that a cascade of crossed laser beams would be necessary to provide additional acceleration to gold ions of the order of GeV/nucleon.

  18. Solid lithium-ion electrolyte

    DOE Patents [OSTI]

    Zhang, Ji-Guang (Golden, CO); Benson, David K. (Golden, CO); Tracy, C. Edwin (Golden, CO)

    1998-01-01T23:59:59.000Z

    The present invention relates to the composition of a solid lithium-ion electrolyte based on the Li.sub.2 O--CeO.sub.2 --SiO.sub.2 system having good transparent characteristics and high ion conductivity suitable for uses in lithium batteries, electrochromic devices and other electrochemical applications.

  19. Solid lithium-ion electrolyte

    DOE Patents [OSTI]

    Zhang, J.G.; Benson, D.K.; Tracy, C.E.

    1998-02-10T23:59:59.000Z

    The present invention relates to the composition of a solid lithium-ion electrolyte based on the Li{sub 2}O--CeO{sub 2}--SiO{sub 2} system having good transparent characteristics and high ion conductivity suitable for uses in lithium batteries, electrochromic devices and other electrochemical applications. 12 figs.

  20. Hysteresis-free high rate reactive sputtering of niobium oxide, tantalum oxide, and aluminum oxide

    SciTech Connect (OSTI)

    Särhammar, Erik, E-mail: erik.sarhammar@angstrom.uu.se; Berg, Sören; Nyberg, Tomas [Department of Solid State Electronics, The Ångström Laboratory, Uppsala University, Box 534, SE-751 21 Uppsala (Sweden)

    2014-07-01T23:59:59.000Z

    This work reports on experimental studies of reactive sputtering from targets consisting of a metal and its oxide. The composition of the targets varied from pure metal to pure oxide of Al, Ta, and Nb. This combines features from both the metal target and oxide target in reactive sputtering. If a certain relation between the metal and oxide parts is chosen, it may be possible to obtain a high deposition rate, due to the metal part, and a hysteresis-free process, due to the oxide part. The aim of this work is to quantify the achievable boost in oxide deposition rate from a hysteresis-free process by using a target consisting of segments of a metal and its oxide. Such an increase has been previously demonstrated for Ti using a homogeneous substoichiometric target. The achievable gain in deposition rate depends on transformation mechanisms from oxide to suboxides due to preferential sputtering of oxygen. Such mechanisms are different for different materials and the achievable gain is therefore material dependent. For the investigated materials, the authors have demonstrated oxide deposition rates that are 1.5–10 times higher than what is possible from metal targets in compound mode. However, although the principle is demonstrated for oxides of Al, Ta, and Nb, a similar behavior is expected for most oxides.

  1. Voltage, stability and diffusion barrier differences between sodium-ion and lithium-ion intercalation materials

    E-Print Network [OSTI]

    Ceder, Gerbrand

    Voltage, stability and diffusion barrier differences between sodium-ion and lithium-ion-ion systems. Introduction Rechargeable lithium-ion (Li-ion) batteries1­4 have become a mainstay of the digital), much research has targeted the development and optimization of lithium-ion batteries, in particular

  2. Photo ion spectrometer

    DOE Patents [OSTI]

    Gruen, Dieter M. (Downers Grove, IL); Young, Charles E. (Westmont, IL); Pellin, Michael J. (Naperville, IL)

    1989-01-01T23:59:59.000Z

    A charged particle spectrometer for performing ultrasensitive quantitative analysis of selected atomic components removed from a sample. Significant improvements in performing energy and angular refocusing spectroscopy are accomplished by means of a two dimensional structure for generating predetermined electromagnetic field boundary conditions. Both resonance and non-resonance ionization of selected neutral atomic components allow accumulation of increased chemical information. A multiplexed operation between a SIMS mode and a neutral atomic component ionization mode with EARTOF analysis enables comparison of chemical information from secondary ions and neutral atomic components removed from the sample. An electronic system is described for switching high level signals, such as SIMS signals, directly to a transient recorder and through a charge amplifier to the transient recorder for a low level signal pulse counting mode, such as for a neutral atomic component ionization mode.

  3. Photo ion spectrometer

    DOE Patents [OSTI]

    Gruen, D.M.; Young, C.E.; Pellin, M.J.

    1989-12-26T23:59:59.000Z

    A charged particle spectrometer is described for performing ultrasensitive quantitative analysis of selected atomic components removed from a sample. Significant improvements in performing energy and angular refocusing spectroscopy are accomplished by means of a two dimensional structure for generating predetermined electromagnetic field boundary conditions. Both resonance and non-resonance ionization of selected neutral atomic components allow accumulation of increased chemical information. A multiplexed operation between a SIMS mode and a neutral atomic component ionization mode with EARTOF analysis enables comparison of chemical information from secondary ions and neutral atomic components removed from the sample. An electronic system is described for switching high level signals, such as SIMS signals, directly to a transient recorder and through a charge amplifier to the transient recorder for a low level signal pulse counting mode, such as for a neutral atomic component ionization mode. 12 figs.

  4. Solenoid and monocusp ion source

    DOE Patents [OSTI]

    Brainard, J.P.; Burns, E.J.T.; Draper, C.H.

    1997-10-07T23:59:59.000Z

    An ion source which generates hydrogen ions having high atomic purity incorporates a solenoidal permanent magnets to increase the electron path length. In a sealed envelope, electrons emitted from a cathode traverse the magnetic field lines of a solenoid and a monocusp magnet between the cathode and a reflector at the monocusp. As electrons collide with gas, the molecular gas forms a plasma. An anode grazes the outer boundary of the plasma. Molecular ions and high energy electrons remain substantially on the cathode side of the cusp, but as the ions and electrons are scattered to the aperture side of the cusp, additional collisions create atomic ions. The increased electron path length allows for smaller diameters and lower operating pressures. 6 figs.

  5. Ion chamber based neutron detectors

    DOE Patents [OSTI]

    Derzon, Mark S; Galambos, Paul C; Renzi, Ronald F

    2014-12-16T23:59:59.000Z

    A neutron detector with monolithically integrated readout circuitry, including: a bonded semiconductor die; an ion chamber formed in the bonded semiconductor die; a first electrode and a second electrode formed in the ion chamber; a neutron absorbing material filling the ion chamber; and the readout circuitry which is electrically coupled to the first and second electrodes. The bonded semiconductor die includes an etched semiconductor substrate bonded to an active semiconductor substrate. The readout circuitry is formed in a portion of the active semiconductor substrate. The ion chamber has a substantially planar first surface on which the first electrode is formed and a substantially planar second surface, parallel to the first surface, on which the second electrode is formed. The distance between the first electrode and the second electrode may be equal to or less than the 50% attenuation length for neutrons in the neutron absorbing material filling the ion chamber.

  6. Oxidative stress and oxidative damage in chemical carcinogenesis

    SciTech Connect (OSTI)

    Klaunig, James E., E-mail: jklauni@indiana.edu; Wang Zemin; Pu Xinzhu; Zhou Shaoyu

    2011-07-15T23:59:59.000Z

    Reactive oxygen species (ROS) are induced through a variety of endogenous and exogenous sources. Overwhelming of antioxidant and DNA repair mechanisms in the cell by ROS may result in oxidative stress and oxidative damage to the cell. This resulting oxidative stress can damage critical cellular macromolecules and/or modulate gene expression pathways. Cancer induction by chemical and physical agents involves a multi-step process. This process includes multiple molecular and cellular events to transform a normal cell to a malignant neoplastic cell. Oxidative damage resulting from ROS generation can participate in all stages of the cancer process. An association of ROS generation and human cancer induction has been shown. It appears that oxidative stress may both cause as well as modify the cancer process. Recently association between polymorphisms in oxidative DNA repair genes and antioxidant genes (single nucleotide polymorphisms) and human cancer susceptibility has been shown.

  7. Challenges for Na-ion Negative Electrodes

    E-Print Network [OSTI]

    Chevrier, V. L.

    Na-ion batteries have been proposed as candidates for replacing Li-ion batteries. In this paper we examine the viability of Na-ion negative electrode materials based on Na alloys or hard carbons in terms of volumetric ...

  8. Advances in lithium-ion batteries

    E-Print Network [OSTI]

    Kerr, John B.

    2003-01-01T23:59:59.000Z

    Advances in Lithium-Ion Batteries Edited by Walter A. vanbook is intended for lithium-ion scientists and engineersof the state of the Lithium-ion art and in this they have

  9. MESON PRODUCTION IN RELATIVISTIC HEAVY ION COLLISIONS

    E-Print Network [OSTI]

    Schnetzer, S.R.

    2010-01-01T23:59:59.000Z

    by (kaon yield)*/*?. Fig. 27 Ion chamber voltage vs. T-Bcoincidences. Fig. ? 8 Ion chamber voltage vs. E tag29 Measured charge on the Ion chamber per beam particle vs.

  10. 4th Generation ECR Ion Sources

    E-Print Network [OSTI]

    Lyneis, Claude M.

    2010-01-01T23:59:59.000Z

    4th Generation ECR Ion Sources Claude M Lyneis, D. Leitner,to developing a 4 th generation ECR ion source with an RFover current 3 rd generation ECR ion sources, which operate

  11. Phosphonic acid based ion exchange resins

    DOE Patents [OSTI]

    Horwitz, E.P.; Alexandratos, S.D.; Gatrone, R.C.; Chiarizia, R.

    1994-01-25T23:59:59.000Z

    An ion exchange resin is described for extracting metal ions from a liquid waste stream. An ion exchange resin is prepared by copolymerizing a vinylidene diphosphonic acid with styrene, acrylonitrile and divinylbenzene. 9 figures.

  12. Phosphonic acid based ion exchange resins

    DOE Patents [OSTI]

    Horwitz, E.P.; Alexandratos, S.D.; Gatrone, R.C.; Chiarizia, R.

    1996-07-23T23:59:59.000Z

    An ion exchange resin is described for extracting metal ions from a liquid waste stream. An ion exchange resin is prepared by copolymerizing a vinylidene diphosphonic acid with styrene, acrylonitrile and divinylbenzene. 10 figs.

  13. Oxidation resistant alloys, method for producing oxidation resistant alloys

    DOE Patents [OSTI]

    Dunning, John S. (Corvallis, OR); Alman, David E. (Salem, OR)

    2002-11-05T23:59:59.000Z

    A method for producing oxidation-resistant austenitic alloys for use at temperatures below 800.degree. C. comprising of: providing an alloy comprising, by weight %: 14-18% chromium, 15-18% nickel, 1-3% manganese, 1-2% molybdenum, 2-4% silicon, 0% aluminum and the balance being iron; heating the alloy to 800.degree. C. for between 175-250 hours prior to use in order to form a continuous silicon oxide film and another oxide film. The method provides a means of producing stainless steels with superior oxidation resistance at temperatures above 700.degree. C. at a low cost

  14. Oxidation resistant alloys, method for producing oxidation resistant alloys

    DOE Patents [OSTI]

    Dunning, John S.; Alman, David E.

    2002-11-05T23:59:59.000Z

    A method for producing oxidation-resistant austenitic alloys for use at temperatures below 800 C. comprising of: providing an alloy comprising, by weight %: 14-18% chromium, 15-18% nickel, 1-3% manganese, 1-2% molybdenum, 2-4% silicon, 0% aluminum and the balance being iron; heating the alloy to 800 C. for between 175-250 hours prior to use in order to form a continuous silicon oxide film and another oxide film. The method provides a means of producing stainless steels with superior oxidation resistance at temperatures above 700 C. at a low cost

  15. Ion Rings for Magnetic Fusion

    SciTech Connect (OSTI)

    Greenly, John, B.

    2005-07-31T23:59:59.000Z

    This Final Technical Report presents the results of the program, Ion Rings for Magnetic Fusion, which was carried out under Department of Energy funding during the period August, 1993 to January, 2005. The central objective of the program was to study the properties of field-reversed configurations formed by ion rings. In order to reach this objective, our experimental program, called the Field-reversed Ion Ring Experiment, FIREX, undertook to develop an efficient, economical technology for the production of field-reversed ion rings. A field-reversed configuration (FRC) in which the azimuthal (field-reversing) current is carried by ions with gyro-radius comparable to the magnetic separatrix radius is called a field-reversed ion ring. A background plasma is required for charge neutralization of the ring, and this plasma will be confined within the ring's closed magnetic flux. Ion rings have long been of interest as the basis of compact magnetic fusion reactors, as the basis for a high-power accelerator for an inertial fusion driver, and for other applications of high power ion beams or plasmas of high energy density. Specifically, the FIREX program was intended to address the longstanding question of the contribution of large-orbit ions to the observed stability of experimental FRCs to the MHD tilt mode. Typical experimental FRCs with s {approx} 2-4, where s is the ratio of separatrix radius to ion gyro-radius, have been stable to tilting, but desired values for a fusion reactor, s > 20, should be unstable. The FIREX ring would consist of a plasma with large s for the background ions, but with s {approx} 1 for the ring ions. By varying the proportions of these two populations, the minimum proportion of large-orbit ions necessary for stability could be determined. The incorporation of large-orbit ions, perhaps by neutral-beam injection, into an FRC has been advanced for the purpose of stabilizing, heating, controlling angular momentum, and aiding the formation of a reactor-scale FRC, and the FIREX program was intended to test the ideas behind this approach. We will describe in this report the technological development path and advances in physics understanding that allowed FIREX to reach a regime in which ion rings were reproducibly created with up to about half the current necessary to produce field reversal. Unfortunately, the experiments were limited to this level by a fundamental, unanticipated aspect of the physics of strong ion rings in plasma. The FIREX ring is a strongly anisotropic, current-carrying population of ions moving faster than the Alfven speed in the background plasma. The rapidly changing ring current excites very large-amplitude Alfven waves in the plasma, and these waves strongly affect the ring, causing rapid energy loss in a way that is not compatible with the success of the ring trapping scenario around which FIREX was designed. The result was that FIREX rings were always very short-lived. We will discuss the implication of these results for possible future use of large-orbit ions in FRCs. In short, it appears that a certain range of the parameters characterizing the ring Alfven mach number and distribution function must be avoided to allow the existence of a long-lived energetic ion component in an FRC. This report will explain why FIREX experimental results cannot be directly scaled to quantitatively predict this range for a particular FRC configuration. This will require accurate, three-dimensional simulations. FIREX results do constitute a very good dataset for validating such a code, and simulations already carried out during this program provide a guide to the important physics involved.

  16. Zinc oxide varistors and/or resistors

    DOE Patents [OSTI]

    Arnold, Jr., Wesley D. (Oak Ridge, TN); Bond, Walter D. (Knoxville, TN); Lauf, Robert J. (Oak Ridge, TN)

    1993-01-01T23:59:59.000Z

    Varistors and/or resistors that includes doped zinc oxide gel microspheres. The doped zinc oxide gel microspheres preferably have from about 60 to about 95% by weight zinc oxide and from about 5 to about 40% by weight dopants based on the weight of the zinc oxide. The dopants are a plurality of dopants selected from silver salts, boron oxide, silicon oxide and hydrons oxides of aluminum, bismuth, cobalt, chromium, manganese, nickel, and antimony.

  17. Zinc oxide varistors and/or resistors

    DOE Patents [OSTI]

    Arnold, W.D. Jr.; Bond, W.D.; Lauf, R.J.

    1993-07-27T23:59:59.000Z

    Varistors and/or resistors are described that include doped zinc oxide gel microspheres. The doped zinc oxide gel microspheres preferably have from about 60 to about 95% by weight zinc oxide and from about 5 to about 40% by weight dopants based on the weight of the zinc oxide. The dopants are a plurality of dopants selected from silver salts, boron oxide, silicon oxide and hydrons oxides of aluminum, bismuth, cobalt, chromium, manganese, nickel, and antimony.

  18. Sodium Titanate Anodes for Sodium Ion Batteries

    E-Print Network [OSTI]

    Doeff, Marca M.

    2014-01-01T23:59:59.000Z

    for  Sodium  Ion  Batteries   One   of   the   challenges  of   sodium   ion   batteries   is   identification   of  for   use   in   batteries.   Our   recent   work   has  

  19. Creating a GPS for aluminum ions | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Creating a GPS for aluminum ions Creating a GPS for aluminum ions Released: August 14, 2014 New approach pinpoints locations in simple zeolite catalysts Aluminum EXAFS and zeolite...

  20. Cross-flow electrochemical reactor cells, cross-flow reactors, and use of cross-flow reactors for oxidation reactions

    DOE Patents [OSTI]

    Balachandran, Uthamalingam (Hinsdale, IL); Poeppel, Roger B. (Glen Ellyn, IL); Kleefisch, Mark S. (Naperville, IL); Kobylinski, Thaddeus P. (Lisle, IL); Udovich, Carl A. (Joliet, IL)

    1994-01-01T23:59:59.000Z

    This invention discloses cross-flow electrochemical reactor cells containing oxygen permeable materials which have both electron conductivity and oxygen ion conductivity, cross-flow reactors, and electrochemical processes using cross-flow reactor cells having oxygen permeable monolithic cores to control and facilitate transport of oxygen from an oxygen-containing gas stream to oxidation reactions of organic compounds in another gas stream. These cross-flow electrochemical reactors comprise a hollow ceramic blade positioned across a gas stream flow or a stack of crossed hollow ceramic blades containing a channel or channels for flow of gas streams. Each channel has at least one channel wall disposed between a channel and a portion of an outer surface of the ceramic blade, or a common wall with adjacent blades in a stack comprising a gas-impervious mixed metal oxide material of a perovskite structure having electron conductivity and oxygen ion conductivity. The invention includes reactors comprising first and second zones seprated by gas-impervious mixed metal oxide material material having electron conductivity and oxygen ion conductivity. Prefered gas-impervious materials comprise at least one mixed metal oxide having a perovskite structure or perovskite-like structure. The invention includes, also, oxidation processes controlled by using these electrochemical reactors, and these reactions do not require an external source of electrical potential or any external electric circuit for oxidation to proceed.

  1. Highly Stripped Ion Sources for MeV Ion Implantation

    SciTech Connect (OSTI)

    Hershcovitch, Ady

    2009-06-30T23:59:59.000Z

    Original technical objectives of CRADA number PVI C-03-09 between BNL and Poole Ventura, Inc. (PVI) were to develop an intense, high charge state, ion source for MeV ion implanters. Present day high-energy ion implanters utilize low charge state (usually single charge) ion sources in combination with rf accelerators. Usually, a MV LINAC is used for acceleration of a few rnA. It is desirable to have instead an intense, high charge state ion source on a relatively low energy platform (de acceleration) to generate high-energy ion beams for implantation. This de acceleration of ions will be far more efficient (in energy utilization). The resultant implanter will be smaller in size. It will generate higher quality ion beams (with lower emittance) for fabrication of superior semiconductor products. In addition to energy and cost savings, the implanter will operate at a lower level of health risks associated with ion implantation. An additional aim of the project was to producing a product that can lead to long­ term job creation in Russia and/or in the US. R&D was conducted in two Russian Centers (one in Tomsk and Seversk, the other in Moscow) under the guidance ofPVI personnel and the BNL PI. Multiple approaches were pursued, developed, and tested at various locations with the best candidate for commercialization delivered and tested at on an implanter at the PVI client Axcelis. Technical developments were exciting: record output currents of high charge state phosphorus and antimony were achieved; a Calutron-Bemas ion source with a 70% output of boron ion current (compared to 25% in present state-of-the-art). Record steady state output currents of higher charge state phosphorous and antimony and P ions: P{sup 2+} (8.6 pmA), P{sup 3+} (1.9 pmA), and P{sup 4+} (0.12 pmA) and 16.2, 7.6, 3.3, and 2.2 pmA of Sb{sup 3+} Sb {sup 4 +}, Sb{sup 5+}, and Sb{sup 6+} respectively. Ultimate commercialization goals did not succeed (even though a number of the products like high charge state phosphorus and antimony could have resulted in a lower power consumption of 30 kW/implanter) for the following reasons (which were discovered after R&D completion): record output of high charge state phosphorous would have thermally damage wafers; record high charge state of antimony requires tool (ion implanting machine in ion implantation jargon) modification, which did not make economic sense due to the small number of users. Nevertheless, BNL has benefited from advances in high-charge state ion generation, due to high charge state ions need for RHIC preinjection. High fraction boron ion was delivered to PVI client Axcelis for retrofit and implantation testing; the source could have reduced beam preinjector power consumption by a factor of 3.5. But, since the source generated some lithium (though in miniscule amounts); last minute decision was made not to employ the source in implanters. R&D of novel transport and gasless plasmaless deceleration, as well as decaborane molecular ion source to mitigate space charge problems in low energy shallow ion implantation was also conducted though results were not yet ready for commercialization. Future work should be focused on gasless plasmaless transport and deceleration as well as on molecular ions due to their significance to low energy, shallow implantation; which is the last frontier of ion implantation. To summarize the significant accomplishments: 1. Record steady state output currents of high charge state phosphorous, P, ions in particle milli-Ampere: P{sup 2+} (8.6 pmA), P{sup 3+} (1.9 pmA), and P{sup 4+} (0.12 pmA). 2. Record steady state output currents of high charge state antimony, Sb, ions in particle milli-Ampere: Sb{sup 3+} (16.2 pmA), Sb{sup 4+} (7.6 pmA), Sb{sup 5+} (3.3 pmA), and Sb{sup 6+} (2.2 pmA). 3. 70% output of boron ion current (compared to 25% in present state-of-the-art) from a Calutron-Bemas ion source. These accomplishments have the potential of benefiting the semiconductor manufacturing industry by lowering power consumption by as much as 30 kW per ion implanter. Major problem w

  2. Advanced quadrupole ion trap instrumentation for low level vehicle emissions measurements. CRADA final report for number ORNL93-0238

    SciTech Connect (OSTI)

    McLuckey, S.A.; Buchanan, M.V.; Asano, K.G.; Hart, K.J.; Goeringer, D.E. [Oak Ridge National Lab., TN (United States); Dearth, M.A. [Ford Motor Co., Dearborn, MI (United States). Environmental Research Consortium

    1997-09-01T23:59:59.000Z

    Quadrupole ion trap mass spectrometry has been evaluated for its potential use in vehicle emissions measurements in vehicle test facilities as an analyzer for the top 15 compounds contributing to smog generation. A variety of ionization methods were explored including ion trap in situ chemical ionization, atmospheric sampling glow discharge ionization, and nitric oxide chemical ionization in a glow discharge ionization source coupled with anion trap mass spectrometer. Emphasis was placed on the determination of hydrocarbons and oxygenated hydrocarbons at parts per million to parts per billion levels. Ion trap in situ water chemical ionization and atmospheric sampling glow discharge ionization were both shown to be amenable to the analysis of arenes, alcohols, aldehydes and, to some degree, alkenes. Atmospheric sampling glow discharge also generated molecular ions of methyl-t-butyl ether (MTBE). Neither of these ionization methods, however, were found to generate diagnostic ions for the alkanes. Nitric oxide chemical ionization, on the other hand, was found to yield diagnostic ions for alkanes, alkenes, arenes, alcohols, aldehydes, and MTBE. The ability to measure a variety of hydrocarbons present at roughly 15 parts per billion at measurement rates of 3 Hz was demonstrated. These results have demonstrated that the ion trap has an excellent combination of sensitivity, specificity, speed, and flexibility with respect to the technical requirements of the top 15 analyzer.

  3. A New Pulsed Glow Discharge Source With Enhanced Ion Extraction for Small Non-Conductive Samples or Atmospheric Sampling

    SciTech Connect (OSTI)

    Jackson, Glen P. [Ohio University, Athens; Haire, Richard {Dick} G [ORNL; Duckworth, Douglas {Doug} C [ORNL

    2003-04-01T23:59:59.000Z

    An ionization source designed to efficiently utilize sub-milligram quantities of electrically non-conducting compounds (i.e. oxides) for prolonged periods of mass spectrometric analysis is described. The source is coupled to a quadrupole ion trap mass spectrometer in this report, but could readily be modified for alternative types of mass spectrometers. The coaxial-design glow discharge ion source is unique in that it incorporates a focusing lens behind the discharge surface to steer ions towards the ion sampling plate and thereby improve sensitivity. Non-conducting oxide samples are infused in indium and set in one end of an electrically conductive rod, to which the voltage is applied. Transmission efficiency is sufficient to allow the measurement of isotopes of tungsten from a tungsten rod using glow discharge pulse widths as narrow as 2 {micro}s, which is on the order of single-atom layer sputtering. The sputtering and ionization processes occurring in the discharge produces mainly atomic metal ions, regardless of the chemical form of the metals in the samples. This latter aspect is particularly useful for intended applications involving actinide samples, and allows a minimal amount of sample handling. In a second application, a metal capillary is used in place of the rod to create an atmospheric sampling glow discharge. In this mode, the ion-focusing lens was also found to enhance ion signals arising from volatile vapors entering the discharge from the capillary.

  4. ARM - Oxides of Nitrogen

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadap Documentation TDMADAP : XDCnarrowbandheat fluxChinaNews : AMFAlaskaNewsOxides of Nitrogen

  5. Multi-source ion funnel

    DOE Patents [OSTI]

    Tang, Keqi; Belov, Mikhail B.; Tolmachev, Aleksey V.; Udseth, Harold R.; Smith, Richard D.

    2005-12-27T23:59:59.000Z

    A method for introducing ions generated in a region of relatively high pressure into a region of relatively low pressure by providing at least two electrospray ion sources, providing at least two capillary inlets configured to direct ions generated by the electrospray sources into and through each of the capillary inlets, providing at least two sets of primary elements having apertures, each set of elements having a receiving end and an emitting end, the primary sets of elements configured to receive a ions from the capillary inlets at the receiving ends, and providing a secondary set of elements having apertures having a receiving end and an emitting end, the secondary set of elements configured to receive said ions from the emitting end of the primary sets of elements and emit said ions from said emitting end of the secondary set of elements. The method may further include the step of providing at least one jet disturber positioned within at least one of the sets of primary elements, providing a voltage, such as a dc voltage, in the jet disturber, thereby adjusting the transmission of ions through at least one of the sets of primary elements.

  6. Enhanced Thermal Conductivity Oxide Fuels

    SciTech Connect (OSTI)

    Alvin Solomon; Shripad Revankar; J. Kevin McCoy

    2006-01-17T23:59:59.000Z

    the purpose of this project was to investigate the feasibility of increasing the thermal conductivity of oxide fuels by adding small fractions of a high conductivity solid phase.

  7. Continuous lengths of oxide superconductors

    DOE Patents [OSTI]

    Kroeger, Donald M. (Knoxville, TN); List, III, Frederick A. (Andersonville, TN)

    2000-01-01T23:59:59.000Z

    A layered oxide superconductor prepared by depositing a superconductor precursor powder on a continuous length of a first substrate ribbon. A continuous length of a second substrate ribbon is overlaid on the first substrate ribbon. Sufficient pressure is applied to form a bound layered superconductor precursor powder between the first substrate ribbon and the second substrate ribbon. The layered superconductor precursor is then heat treated to establish the oxide superconducting phase. The layered oxide superconductor has a smooth interface between the substrate and the oxide superconductor.

  8. Photooxidation of tetraanionic sensitizer ions by dihexadecyl phosphate vesicle-bound viologens

    SciTech Connect (OSTI)

    Hurst, J.K.; Thompson, D.H.P.; Connolly, J.S.

    1987-01-21T23:59:59.000Z

    Triplet state lifetimes of several photoredox-active anions were shortened by adding N-alkyl-N-methyl-4,4'-bipyridinium (C/sub n/MV/sup 2 +/) ions in the presence of dihexadecyl phosphate (DHP) vesicles. Optical spectroscopic measurements indicate that the predominant reaction mechanism is one-electron oxidative quenching. For (5,10,15,20-tetrakis(4-sulfonatophenyl)porphinato)zinc(II) (ZnTPPS/sup 4 -/) ion, yields of charge-separated product ions are high, so that overall quantum yields exceeding 0.5 redox pairs per photon absorbed can be realized; for tetrakis(diphosphito)diplatinate(II), tris(4,7-bis(4-sulfonato-benzyl)-1,10-phenanthroline)ruthenate(II), and tris(4,4'-dicarboxylato-2,2'-bipyridine)ruthenate(II) yields are markedly less, a consequence of their shorter intrinsic triplet lifetimes and poor cage escape yields. In the absence of vesicles, product formation is negligible because ion pairing of viologens with sensitizers is extensive, giving rise to static quenching of the photoexcited states. The ionic strength dependence of the kinetics of /sup 3/ZnTPPS/sup 4 -/ ion oxidation by C/sub n/MV/sup 2 +/-DHP particles suggests a diffusion-controlled mechanism with electron transfer occurring over a distance of separation approximating the hard-sphere collision diameter of sensitizer and viologen.

  9. Three chamber negative ion source

    DOE Patents [OSTI]

    Leung, K.N.; Ehlers, K.W.; Hiskes, J.R.

    1983-11-10T23:59:59.000Z

    It is an object of this invention provide a negative ion source which efficiently provides a large flux of negatively ionized particles. This invention provides a volume source of negative ions which has a current density sufficient for magnetic fusion applications and has electrons suppressed from the output. It is still another object of this invention to provide a volume source of negative ions which can be electrostatically accelerated to high energies and subsequently neutralized to form a high energy neutral beam for use with a magnetically confined plasma.

  10. Ion beam extractor with counterbore

    DOE Patents [OSTI]

    Ji, Qing; Standiford, Keith; King, Tsu-Jae; Leung, Ka-Ngo

    2006-08-01T23:59:59.000Z

    An extractor system for a plasma ion source has a single (first) electrode with one or more apertures, or a pair of spaced electrodes, a first or plasma forming electrode and a second or extraction electrode, with one or more aligned apertures. The aperture(s) in the first electrode (or the second electrode or both) have a counterbore on the downstream side (i.e. away from the plasma ion source or facing the second electrode). The counterbored extraction system reduces aberrations and improves focusing. The invention also includes an ion source with the counterbored extraction system, and a method of improving focusing in an extraction system by providing a counterbore.

  11. Plasma ion sources and ion beam technology inmicrofabrications

    SciTech Connect (OSTI)

    Ji, Lili

    2007-09-01T23:59:59.000Z

    For over decades, focused ion beam (FIB) has been playing a very important role in microscale technology and research, among which, semiconductor microfabrication is one of its biggest application area. As the dimensions of IC devices are scaled down, it has shown the need for new ion beam tools and new approaches to the fabrication of small-scale devices. In the meanwhile, nanotechnology has also deeply involved in material science research and bioresearch in recent years. The conventional FIB systems which utilize liquid gallium ion sources to achieve nanometer scale resolution can no longer meet the various requirements raised from such a wide application area such as low contamination, high throughput and so on. The drive towards controlling materials properties at nanometer length scales relies on the availability of efficient tools. In this thesis, three novel ion beam tools have been developed and investigated as the alternatives for the conventional FIB systems in some particular applications. An integrated focused ion beam (FIB) and scanning electron microscope (SEM) system has been developed for direct doping or surface modification. This new instrument employs a mini-RF driven plasma source to generate focused ion beam with various ion species, a FEI two-lens electron (2LE) column for SEM imaging, and a five-axis manipulator system for sample positioning. An all-electrostatic two-lens column has been designed to focus the ion beam extracted from the source. Based on the Munro ion optics simulation, beam spot sizes as small as 100 nm can be achieved at beam energies between 5 to 35 keV if a 5 {micro}m-diameter extraction aperture is used. Smaller beam spot sizes can be obtained with smaller apertures at sacrifice of some beam current. The FEI 2LE column, which utilizes Schottky emission, electrostatic focusing optics, and stacked-disk column construction, can provide high-resolution (as small as 20 nm) imaging capability, with fairly long working distance (25 mm) at 25 keV beam voltage. Such an integrated FIB/SEM dual-beam system will not only improve the accuracy and reproducibility when performing ion beam sculpting and direct implantation processes, but will also enable researchers to perform cross-sectioning, imaging, and analysis with the same tool. A major advantage of this approach is the ability to produce a wide variety of ion species tailored to the application.

  12. Structure study on electrochromic films of nickel oxide

    SciTech Connect (OSTI)

    Hu Xingfang; Chen Xiaofeng; Song Xiangyun [Chinese Academy of Sciences, Shanghai (China). Shanghai Inst. of Ceramics

    1993-12-31T23:59:59.000Z

    Using HREM, the relationship between structure and electrochromic properties of rf diode sputtered nickel oxide films with good and poor electrochromic performance has been investigated. The experimental results indicate that all kinds of the films consist of cubic nickel oxide with nano-crystal structure. For the films having good electrochromic properties, the grain size ranges about 5--10 nm. In the films exhibiting poor performance, an amorphous phase of nickel oxide as a continuous phase existing in the film has been observed and the cubic nickel oxide grains appear as isolated islands existing in the amorphous phase. From the structural features of the films, it may be concluded that the grain boundary of nano-polycrystalline structure plays an important role in the electrochromic reaction and the grain boundary would act as channel for the injection and extraction of alkali metal ions and electrons during the coloring and bleaching process. So, it is important to control the structure of films in the deposition process to prepare the film with good electrochromic performance.

  13. Electro-catalytic oxidation device for removing carbon from a fuel reformate

    DOE Patents [OSTI]

    Liu, Di-Jia (Naperville, IL)

    2010-02-23T23:59:59.000Z

    An electro-catalytic oxidation device (ECOD) for the removal of contaminates, preferably carbonaceous materials, from an influent comprising an ECOD anode, an ECOD cathode, and an ECOD electrolyte. The ECOD anode is at a temperature whereby the contaminate collects on the surface of the ECOD anode as a buildup. The ECOD anode is electrically connected to the ECOD cathode, which consumes the buildup producing electricity and carbon dioxide. The ECOD anode is porous and chemically active to the electro-catalytic oxidation of the contaminate. The ECOD cathode is exposed to oxygen, and made of a material which promotes the electro-chemical reduction of oxygen to oxidized ions. The ECOD electrolyte is non-permeable to gas, electrically insulating and a conductor to oxidized. The ECOD anode is connected to the fuel reformer and the fuel cell. The ECOD electrolyte is between and in ionic contact with the ECOD anode and the ECOD cathode.

  14. Low Temperature Constrained Sintering of Cerium Gadolinium Oxide Films for Solid Oxide Fuel Cell Applications

    E-Print Network [OSTI]

    Nicholas, Jason.D.

    2007-01-01T23:59:59.000Z

    Temperature Solid Oxide Fuel Cells, In: S.C. Singhal and M.Tubular Solid Oxide Fuel Cell Technology, U.S. Department ofOxide Films for Solid Oxide Fuel Cell Applications by Jason

  15. Superparamagnetic iron oxide nanoparticles as radiosensitizer via enhanced reactive oxygen species formation

    SciTech Connect (OSTI)

    Klein, Stefanie; Sommer, Anja [Department of Chemistry and Pharmacy, Physical Chemistry I and ICMM, Friedrich-Alexander University of Erlangen-Nuremberg, Egerlandstr. 3, D-91058 Erlangen (Germany)] [Department of Chemistry and Pharmacy, Physical Chemistry I and ICMM, Friedrich-Alexander University of Erlangen-Nuremberg, Egerlandstr. 3, D-91058 Erlangen (Germany); Distel, Luitpold V.R. [Department of Radiation Oncology, Friedrich Alexander University Erlangen-Nuremberg, Universitaetsstrasse 27, D-91054 Erlangen (Germany)] [Department of Radiation Oncology, Friedrich Alexander University Erlangen-Nuremberg, Universitaetsstrasse 27, D-91054 Erlangen (Germany); Neuhuber, Winfried [Department of Anatomy, Chair of Anatomy I, Friedrich Alexander University Erlangen-Nuremberg, Krankenhausstr. 9, D-91054 Erlangen (Germany)] [Department of Anatomy, Chair of Anatomy I, Friedrich Alexander University Erlangen-Nuremberg, Krankenhausstr. 9, D-91054 Erlangen (Germany); Kryschi, Carola, E-mail: kryschi@chemie.uni-erlangen.de [Department of Chemistry and Pharmacy, Physical Chemistry I and ICMM, Friedrich-Alexander University of Erlangen-Nuremberg, Egerlandstr. 3, D-91058 Erlangen (Germany)] [Department of Chemistry and Pharmacy, Physical Chemistry I and ICMM, Friedrich-Alexander University of Erlangen-Nuremberg, Egerlandstr. 3, D-91058 Erlangen (Germany)

    2012-08-24T23:59:59.000Z

    Highlights: Black-Right-Pointing-Pointer Ultrasmall citrate-coated SPIONs with {gamma}Fe{sub 2}O{sub 3} and Fe{sub 3}O{sub 4} structure were prepared. Black-Right-Pointing-Pointer SPIONs uptaken by MCF-7 cells increase the ROS production for about 240%. Black-Right-Pointing-Pointer The SPION induced ROS production is due to released iron ions and catalytically active surfaces. Black-Right-Pointing-Pointer Released iron ions and SPION surfaces initiate the Fenton and Haber-Weiss reaction. Black-Right-Pointing-Pointer X-ray irradiation of internalized SPIONs leads to an increase of catalytically active surfaces. -- Abstract: Internalization of citrate-coated and uncoated superparamagnetic iron oxide nanoparticles by human breast cancer (MCF-7) cells was verified by transmission electron microscopy imaging. Cytotoxicity studies employing metabolic and trypan blue assays manifested their excellent biocompatibility. The production of reactive oxygen species in iron oxide nanoparticle loaded MCF-7 cells was explained to originate from both, the release of iron ions and their catalytically active surfaces. Both initiate the Fenton and Haber-Weiss reaction. Additional oxidative stress caused by X-ray irradiation of MCF-7 cells was attributed to the increase of catalytically active iron oxide nanoparticle surfaces.

  16. Semiconductor Ion Implanters

    SciTech Connect (OSTI)

    MacKinnon, Barry A. [Isys, 2727 Walsh Ave., Suite 103, Santa Clara, CA 95051 (United States); Ruffell, John P. [Group 3, LLC, Sunnyvale, CA 94086 (United States)

    2011-06-01T23:59:59.000Z

    In 1953 the Raytheon CK722 transistor was priced at $7.60. Based upon this, an Intel Xeon Quad Core processor containing 820,000,000 transistors should list at $6.2 billion. Particle accelerator technology plays an important part in the remarkable story of why that Intel product can be purchased today for a few hundred dollars. Most people of the mid twentieth century would be astonished at the ubiquity of semiconductors in the products we now buy and use every day. Though relatively expensive in the nineteen fifties they now exist in a wide range of items from high-end multicore microprocessors like the Intel product to disposable items containing 'only' hundreds or thousands like RFID chips and talking greeting cards. This historical development has been fueled by continuous advancement of the several individual technologies involved in the production of semiconductor devices including Ion Implantation and the charged particle beamlines at the heart of implant machines. In the course of its 40 year development, the worldwide implanter industry has reached annual sales levels around $2B, installed thousands of dedicated machines and directly employs thousands of workers. It represents in all these measures, as much and possibly more than any other industrial application of particle accelerator technology. This presentation discusses the history of implanter development. It touches on some of the people involved and on some of the developmental changes and challenges imposed as the requirements of the semiconductor industry evolved.

  17. Ion transport membrane module and vessel system with directed internal gas flow

    DOE Patents [OSTI]

    Holmes, Michael Jerome (Thompson, ND); Ohrn, Theodore R. (Alliance, OH); Chen, Christopher Ming-Poh (Allentown, PA)

    2010-02-09T23:59:59.000Z

    An ion transport membrane system comprising (a) a pressure vessel having an interior, an inlet adapted to introduce gas into the interior of the vessel, an outlet adapted to withdraw gas from the interior of the vessel, and an axis; (b) a plurality of planar ion transport membrane modules disposed in the interior of the pressure vessel and arranged in series, each membrane module comprising mixed metal oxide ceramic material and having an interior region and an exterior region; and (c) one or more gas flow control partitions disposed in the interior of the pressure vessel and adapted to change a direction of gas flow within the vessel.

  18. Improving the Performance of Lithium Ion Batteries at Low Temperature

    SciTech Connect (OSTI)

    Trung H. Nguyen; Peter Marren; Kevin Gering

    2007-04-20T23:59:59.000Z

    The ability for Li-ion batteries to operate at low temperatures is extremely critical for the development of energy storage for electric and hybrid electric vehicle technologies. Currently, Li-ion cells have limited success in operating at temperature below –10 deg C. Electrolyte conductivity at low temperature is not the main cause of the poor performance of Li-ion cells. Rather the formation of a tight interfacial film between the electrolyte and the electrodes has often been an issue that resulted in a progressive capacity fading and limited discharge rate capability. The objective of our Phase I work is to develop novel electrolytes that can form low interfacial resistance solid electrolyte interface (SEI) films on carbon anodes and metal oxide cathodes. From the results of our Phase I work, we found that the interfacial impedance of Fluoro Ethylene Carbonate (FEC) electrolyte at the low temperature of –20degC is astonishingly low, compared to the baseline 1.2M LiPFEMC:EC:PC:DMC (10:20:10:60) electrolyte. We found that electrolyte formulations with fluorinated carbonate co-solvent have excellent film forming properties and better de-solvation characteristics to decrease the interfacial SEI film resistance and facilitate the Li-ion diffusion across the SEI film. The very overwhelming low interfacial impedance for FEC electrolytes will translate into Li-ion cells with much higher power for cold cranking and high Regen/charge at the low temperature. Further, since the SEI film resistance is low, Li interaction kinetics into the electrode will remain very fast and thus Li plating during Regen/charge period be will less likely to happen.

  19. Improving high-capacity Li1.2Ni0.15Mn0.55Co0.1O2-based lithium-ion cells by modifiying the positive electrode with alumina

    E-Print Network [OSTI]

    Spila, Timothy P.

    and EVs), they must meet a range of stringent criteria: for instance, energy densities high enoughImproving high-capacity Li1.2Ni0.15Mn0.55Co0.1O2-based lithium-ion cells by modifiying the positive-ion Atomic layer deposition Al2O3 Coating Secondary ion mass spectrometry Layered oxide a b s t r a c

  20. Anodic polymerization of vinyl ethylene carbonate in Li-Ion battery electrolyte

    SciTech Connect (OSTI)

    Chen, Guoying; Zhuang, Guorong V.; Richardson, Thomas J.; Gao, Liu; Ross Jr., Philip N.

    2005-02-28T23:59:59.000Z

    A study of the anodic oxidation of vinyl ethylene carbonate (VEC) was conducted with post-mortem analysis of reaction products by ATR-FTIR and gel permeation chromatography (GPC). The half-wave potential (E1/2) for oxidation of VEC is ca. 3.6 V producing a resistive film on the electrode surface. GPC analysis of the film on a gold electrode produced by anodization of a commercial Li-ion battery electrolyte containing 2 percent VEC at 4.1 V showed the presence of a high molecular weight polymer. IR analysis indicated polycarbonate with alkyl carbonate rings linked by aliphatic methylene and methyl branches.

  1. Improved ion optics for introduction of ions into a 9.4-T Fourier transform ion cyclotron resonance mass spectrometer

    SciTech Connect (OSTI)

    Chen, Yu; Leach, Franklin E.; Kaiser, Nathan K.; Dang, Xibei; Ibrahim, Yehia M.; Norheim, Randolph V.; Anderson, Gordon A.; Smith, Richard D.; Marshall, Alan G.

    2015-01-01T23:59:59.000Z

    Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometry provides unparalleled mass accuracy and resolving power.[1],[2] With electrospray ionization (ESI), ions are typically transferred into the mass spectrometer through a skimmer, which serves as a conductance-limiting orifice. However, the skimmer allows only a small fraction of incoming ions to enter the mass spectrometer. An ion funnel, originally developed by Smith and coworkers at Pacific Northwest National Laboratory (PNNL)[3-5] provides much more efficient ion focusing and transfer. The large entrance aperture of the ion funnel allows almost all ions emanating from a heated capillary to be efficiently captured and transferred, resulting in nearly lossless transmission.

  2. Surface trap for ytterbium ions

    E-Print Network [OSTI]

    Campbell, Jonathan A. (Jonathan Alan)

    2006-01-01T23:59:59.000Z

    We conducted an experiment to load a shallow planar ion trap from a cold atom source of Ytterbium using photoionization. The surface trap consisted of a three-rod radio frequency Paul trap fabricated using standard printed ...

  3. P-31 / Schlott P-31: Nodule Formation on Indium-Oxide Tin-Oxide

    E-Print Network [OSTI]

    P-31 / Schlott P-31: Nodule Formation on Indium-Oxide Tin-Oxide Sputtering Targets M. Schlott, M from indium-oxide tin-oxide (ITO) targets [1]. Unfor- tunately, black growths, or nodules, commonly isostatic pressing partly reduced powder mixtures of 90 wt.% indium-oxide and 10 wt.% tin-oxide [4

  4. Orthogonal ion injection apparatus and process

    DOE Patents [OSTI]

    Kurulugama, Ruwan T; Belov, Mikhail E

    2014-04-15T23:59:59.000Z

    An orthogonal ion injection apparatus and process are described in which ions are directly injected into an ion guide orthogonal to the ion guide axis through an inlet opening located on a side of the ion guide. The end of the heated capillary is placed inside the ion guide such that the ions are directly injected into DC and RF fields inside the ion guide, which efficiently confines ions inside the ion guide. Liquid droplets created by the ionization source that are carried through the capillary into the ion guide are removed from the ion guide by a strong directional gas flow through an inlet opening on the opposite side of the ion guide. Strong DC and RF fields divert ions into the ion guide. In-guide orthogonal injection yields a noise level that is a factor of 1.5 to 2 lower than conventional inline injection known in the art. Signal intensities for low m/z ions are greater compared to convention inline injection under the same processing conditions.

  5. Metal oxide films on metal

    DOE Patents [OSTI]

    Wu, Xin D. (Los Alamos, NM); Tiwari, Prabhat (Los Alamos, NM)

    1995-01-01T23:59:59.000Z

    A structure including a thin film of a conductive alkaline earth metal oxide selected from the group consisting of strontium ruthenium trioxide, calcium ruthenium trioxide, barium ruthenium trioxide, lanthanum-strontium cobalt oxide or mixed alkaline earth ruthenium trioxides thereof upon a thin film of a noble metal such as platinum is provided.

  6. Dual mode ion mobility spectrometer and method for ion mobility spectrometry

    DOE Patents [OSTI]

    Scott, Jill R [Idaho Falls, ID; Dahl, David A [Idaho Falls, ID; Miller, Carla J [Idaho Falls, ID; Tremblay, Paul L [Idaho Falls, ID; McJunkin, Timothy R [Idaho Falls, ID

    2007-08-21T23:59:59.000Z

    Ion mobility spectrometer apparatus may include an ion interface that is operable to hold positive and negative ions and to simultaneously release positive and negative ions through respective positive and negative ion ports. A first drift chamber is operatively associated with the positive ion port of the ion interface and encloses an electric field therein. A first ion detector operatively associated with the first drift chamber detects positive ions from the first drift chamber. A second drift chamber is operatively associated with the negative ion port of the ion interface and encloses an electric field therein. A second ion detector operatively associated with the second drift chamber detects negative ions from said second drift chamber.

  7. Detection of oxidation in human serum lipoproteins 

    E-Print Network [OSTI]

    Myers, Christine Lee

    2006-04-12T23:59:59.000Z

    A method for the oxidation of lipoproteins in vitro was developed using the free radical initiator, 2,2?-azobis-(2-amidinopropane) dihydrochloride (AAPH). Following in vitro oxidation, the susceptibility to oxidation of ...

  8. Electrostatic ion waves in non-Maxwellian pair-ion plasmas

    SciTech Connect (OSTI)

    Arshad, Kashif [Department of Physics, Quaid-i-Azam University, Islamabad 44000 (Pakistan); National Centre for Physics, Quaid-i-Azam University Campus, Shadhra Valley Road, Islamabad 44000 (Pakistan); Mahmood, S. [Theoretical Plasma Physics Division, PINSTECH, P.O. Nilore, Islamabad 44000 (Pakistan); National Centre for Physics, Quaid-i-Azam University Campus, Shadhra Valley Road, Islamabad 44000 (Pakistan)

    2010-12-15T23:59:59.000Z

    The electrostatic ion waves are studied for non-Maxwellian or Lorentzian distributed unmagnetized pair-ion plasmas. The Vlasov equation is solved and damping rates are calculated for electrostatic waves in Lorentzian pair-ion plasmas. The damping rates of the electrostatic ion waves are studied for the equal and different ion temperatures of pair-ion species. It is found that the Landau damping rate of the ion plasma wave is increased in Lorentzian plasmas in comparison with Maxwellian pair-ion plasmas. The numerical results are also presented for illustration by taking into account the parameters reported in fullerene pair-ion plasma experiments.

  9. Beyond Conventional Cathode Materials for Li-ion Batteries and Na-ion Batteries Nickel fluoride conversion materials and P2 type Na-ion intercalation cathodes /

    E-Print Network [OSTI]

    Lee, Dae Hoe

    2013-01-01T23:59:59.000Z

    Electrode for Sodium Ion Batteries. Chemistry of Materialsnickel fluoride in Li ion batteries. Electrochimica Actafor advanced lithium ion batteries. Materials Science and

  10. Unique battery with an active membrane separator having uniform physico-chemically functionalized ion channels and a method making the same

    DOE Patents [OSTI]

    Gerald, II, Rex E. (Brookfield, IL); Ruscic, Katarina J. (Chicago, IL); Sears, Devin N. (Spruce Grove, CA); Smith, Luis J. (Natick, MA); Klingler, Robert J. (Glenview, IL); Rathke, Jerome W. (Homer Glen, IL)

    2012-02-21T23:59:59.000Z

    The invention relates to a unique battery having an active, porous membrane and method of making the same. More specifically the invention relates to a sealed battery system having a porous, metal oxide membrane with uniform, physicochemically functionalized ion channels capable of adjustable ionic interaction. The physicochemically-active porous membrane purports dual functions: an electronic insulator (separator) and a unidirectional ion-transporter (electrolyte). The electrochemical cell membrane is activated for the transport of ions by contiguous ion coordination sites on the interior two-dimensional surfaces of the trans-membrane unidirectional pores. The membrane material is designed to have physicochemical interaction with ions. Control of the extent of the interactions between the ions and the interior pore walls of the membrane and other materials, chemicals, or structures contained within the pores provides adjustability of the ionic conductivity of the membrane.

  11. Swift heavy ion induced structural and optical properties of Y{sub 2}O{sub 3}:Eu{sup 3+} nanophosphor

    SciTech Connect (OSTI)

    Som, S. [Department of Applied Physics, Indian School of Mines, Dhanbad 826004 (India)] [Department of Applied Physics, Indian School of Mines, Dhanbad 826004 (India); Sharma, S.K., E-mail: sksharma.ism@gmail.com [Department of Applied Physics, Indian School of Mines, Dhanbad 826004 (India); Lochab, S.P. [Inter University Accelerator Centre, New Delhi 110067 (India)] [Inter University Accelerator Centre, New Delhi 110067 (India)

    2013-02-15T23:59:59.000Z

    Highlights: ? Europium doped yttrium oxide nanophosphor was synthesized via combustion method. ? Prepared nanophosphor was irradiated by 150 MeV Swift heavy ion (Ni{sup 7+}). ? Structural (XRD, FTIR, and TEM) and optical properties (DR and PL) after ion irradiation were studied. ? Band gap increases with ion fluence due to the decrease in average crystallite size. -- Abstract: This paper reports the structural and optical modifications of Y{sub 2}O{sub 3}:Eu{sup 3+} nanophosphor induced by 150 MeV Ni{sup 7+} swift heavy ions (SHI) in the fluence range 1 × 10{sup 11} to 1 × 10{sup 13} ions/cm{sup 2}. The XRD, TEM and FTIR studies confirm the loss of crystallinity of the nanophosphors after ion irradiation. Diffuse reflectance spectrum shows a blue shift in the absorption band for SHI induced nanophosphors. An increase in the intensity of photoluminescence peaks without any shift in the peak positions was observed.

  12. Influence of the chemical nature of implanted ions on the structure of a silicon layer damaged by implantation

    SciTech Connect (OSTI)

    Shcherbachev, K. D., E-mail: chterb@mail.ru; Voronova, M. I.; Bublik, V. T. [National University of Science and Technology “MISIS” (Russian Federation); Mordkovich, V. N., E-mail: mord36@mail.ru; Pazhin, D. M.; Zinenko, V. I.; Agafonov, Yu. A. [Russian Academy of Sciences, Institute of Microelectronic Technology and Ultra-High-Purity Materials (Russian Federation)

    2013-12-15T23:59:59.000Z

    The influence of the implantation of silicon single crystals by fluorine, nitrogen, oxygen, and neon ions on the distribution of strain and the static Debye-Waller factor in the crystal lattice over the implanted-layer depth has been investigated by high-resolution X-ray diffraction. The density depth distribution in the surface layer of native oxide has been measured by X-ray reflectometry. Room-temperature implantation conditions have ensured the equality of the suggested ranges of ions of different masses and the energies transferred by them to the target. It is convincingly shown that the change in the structural parameters of the radiation-damaged silicon layer and the native oxide layer depend on the chemical activity of the implanted ions.

  13. Correlation among electronegativity, cation polarizability, optical basicity and single bond strength of simple oxides

    SciTech Connect (OSTI)

    Dimitrov, Vesselin, E-mail: vesselin@uctm.edu [Department of Silicate Technology, University of Chemical Technology and Metallurgy, 8, Kl. Ohridski Blvd., Sofia 1756 (Bulgaria)] [Department of Silicate Technology, University of Chemical Technology and Metallurgy, 8, Kl. Ohridski Blvd., Sofia 1756 (Bulgaria); Komatsu, Takayuki, E-mail: komatsu@mst.nagaokaut.ac.jp [Department of Materials Science and Technology, Nagaoka University of Technology, 1603-1 Kamitomioka-cho, Nagaoka 940-2188 (Japan)] [Department of Materials Science and Technology, Nagaoka University of Technology, 1603-1 Kamitomioka-cho, Nagaoka 940-2188 (Japan)

    2012-12-15T23:59:59.000Z

    A suitable relationship between free-cation polarizability and electronegativity of elements in different valence states and with the most common coordination numbers has been searched on the basis of the similarity in physical nature of both quantities. In general, the cation polarizability increases with decreasing element electronegativity. A systematic periodic change in the polarizability against the electronegativity has been observed in the isoelectronic series. It has been found that generally the optical basicity increases and the single bond strength of simple oxides decreases with decreasing the electronegativity. The observed trends have been discussed on the basis of electron donation ability of the oxide ions and type of chemical bonding in simple oxides. - Graphical abstract: This figure shows the single bond strength of simple oxides as a function of element electronegativity. A remarkable correlation exists between these independently obtained quantities. High values of electronegativity correspond to high values of single bond strength and vice versa. It is obvious that the observed trend in this figure is closely related to the type of chemical bonding in corresponding oxide. Highlights: Black-Right-Pointing-Pointer A suitable relationship between free-cation polarizability and electronegativity of elements was searched. Black-Right-Pointing-Pointer The cation polarizability increases with decreasing element electronegativity. Black-Right-Pointing-Pointer The single bond strength of simple oxides decreases with decreasing the electronegativity. Black-Right-Pointing-Pointer The observed trends were discussed on the basis of type of chemical bonding in simple oxides.

  14. Ion-Acoustic Solitons in Bi-Ion Dusty Plasma

    E-Print Network [OSTI]

    V. V. Prudskikh

    2008-12-02T23:59:59.000Z

    The propagation of ion-acoustic solitons in a warm dusty plasma containing two ion species is investigated theoretically. Using an approach based on the Korteveg-de-Vries equation, it is shown that the critical value of the negative ion density that separates the domains of existence of compressi- on and rarefaction solitons depends continuously on the dust density. A modified Korteveg-de Vries equation for the critical density is derived in the higher order of the expansion in the small parameter. It is found that the nonlinear coefficient of this equation is positive for any values of the dust density and the masses of positive and negative ions. For the case where the negative ion density is close to its critical value, a soliton solution is found that takes into account both the quadratic and cubic nonlinearities. The propagation of a solitary wave of arbitrary amplitude is investigated by the quasi-potential method. It is shown that the range of the dust densities around the critical value within which solitary waves with positive and negative potentials can exist simultaneously is relatively wide.

  15. In situ examination of tin oxide atomic layer deposition using quartz crystal microbalance and Fourier transform infrared techniques

    E-Print Network [OSTI]

    George, Steven M.

    -type semiconductor metal oxide that has many applications in various fields due to its special optical, electrical capacity anode for next gen- eration lithium ion batteries.3,4 SnO2 can also be used as a catalyst typically around 10-2 cm. The adsorp- tion of O2 from air removes the electron charge carriers from

  16. Synthesis and characterization of the ((CO)/sub 4/MoS/sub 2/MS/sub 2/)/sup 2 -/ and ((CO)/sub 4/MoS/sub 2/MS/sub 2/Mo(CO)/sub 4/)/sup 2 -/ ions (M = Mo, W): species containing group VI (6) metals in widely separated formal oxidation states

    SciTech Connect (OSTI)

    Rosenhein, L.D.; McDonald, J.W.

    1987-10-07T23:59:59.000Z

    Dinuclear and trinuclear sulfide-bridged complexes of the types (Et/sub 4/N)/sub 2/(MS/sub 4/(Mo(CO)/sub 4/)) and (Et/sub 4/N)/sub 2/(MS/sub 4/(Mo(CO)/sub 4/)/sub 2/) were prepared by the reaction of one or two equivalents of Mo(CO)/sub 4/(C/sub 7/H/sub 8/) (C/sub 7/H/sub 8/ = norbornadiene) with (Et/sub 4/N)/sub 2/(MS/sub 4/) (M = Mo, W) in methyl alcohol. Elemental analyses were consistent with the proposed formulae. Infrared spectra of all four compounds contain strong bands in the carbonyl region and low-energy bands characteristic of terminal and bridging M-S vibrations in linear, polynuclear, and sulfido-bridged species. Electrochemical experimental results support the hypothesis that the di- and trinuclear species contain both M(IV) (M = Mo, W) and Mo(0) oxidation states in the same complex. 33 references, 2 tables.

  17. Spectroscopic Characterization of a Multiband Complex Oxide:...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    a Multiband Complex Oxide: Insulating and Conducting Cement 12CaO·7AlO. Spectroscopic Characterization of a Multiband Complex Oxide: Insulating and Conducting Cement...

  18. New manganese catalyst for light alkane oxidation

    DOE Patents [OSTI]

    Durante, Vincent A. (West Chester, PA); Lyons, James E. (Wallingford, PA); Walker, Darrell W. (Visalia, CA); Marcus, Bonita K. (Radnor, PA)

    1994-01-01T23:59:59.000Z

    Aluminophosphates containing manganese in the structural framework are employed for the oxidation of alkanes, for example the vapor phase oxidation of methane to methanol.

  19. Precise Application of Transparent Conductive Oxide Coatings...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Application of Transparent Conductive Oxide Coatings for Flat Panel Displays and Photovoltaic Cells Technology available for licensing: New transparent conducting oxide (TCO)...

  20. Chapter 6: Thallium-Oxide Superconductors

    SciTech Connect (OSTI)

    Bhattacharya, R. N.

    2010-01-01T23:59:59.000Z

    This chapter has 2 sections titled: (1) Spray-Deposited, TI-Oxide Films, and (2) Electrodeposited Ti-Oxide Superconductors.

  1. Manganese Oxide Composite Electrodes for Lithium Batteries |...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Manganese Oxide Composite Electrodes for Lithium Batteries Technology available for licensing: Improved spinel-containing "layered-layered" lithium metal oxide electrodes Materials...

  2. XPS Determination of Uranium Oxidations States. | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    extent, are relatively insensitive to compositionstructure within the oxide-hydroxide-hydrate system and can be used to both identify and help quantify U oxidation states in mixed...

  3. Preparation of silver nanoparticles/graphene nanosheets as a catalyst for electrochemical oxidation of methanol

    SciTech Connect (OSTI)

    Han, Kun; Miao, Peng; Tang, Yuguo, E-mail: tangyg@sibet.ac.cn [Suzhou Institute of Biomedical Engineering and Technology, Chinese Academy of Sciences, Suzhou 215163 (China); University of Chinese Academy of Sciences, Beijing 100049 (China); Tong, Hui; Zhu, Xiaoli [Laboratory of Biosensing Technology, School of Life Sciences, Shanghai University, Shanghai 200444 (China); Liu, Tao; Cheng, Wenbo [Suzhou Institute of Biomedical Engineering and Technology, Chinese Academy of Sciences, Suzhou 215163 (China)

    2014-02-03T23:59:59.000Z

    In this report, silver nanoparticles (AgNPs) decorated graphene nanosheets have been prepared based on the reduction of Ag ions by hydroquinone, and their catalytic performance towards the electrochemical oxidation of methanol is investigated. The synthesis of the nano-composite is confirmed by transmission electron microscope measurements and UV-vis absorption spectra. Excellent electrocatalytic performance of the material is demonstrated by cyclic voltammograms. This material also contributes to the low peak potential of methanol oxidation compared with most of the other materials.

  4. Comparison of beryllium oxide and pyrolytic graphite crucibles for boron doped silicon epitaxy

    SciTech Connect (OSTI)

    Ali, Dyan; Richardson, Christopher J. K. [Laboratory for Physical Sciences, University of Maryland, College Park, Maryland 20740 (United States)

    2012-11-15T23:59:59.000Z

    This article reports on the comparison of beryllium oxide and pyrolytic graphite as crucible liners in a high-temperature effusion cell used for boron doping in silicon grown by molecular beam epitaxy. Secondary ion mass spectroscopy analysis indicates decomposition of the beryllium oxide liner, leading to significant incorporation of beryllium and oxygen in the grown films. The resulting films are of poor crystal quality with rough surfaces and broad x-ray diffraction peaks. Alternatively, the use of pyrolytic graphite crucible liners results in higher quality films.

  5. X-ray absorption spectroscopy studies of electrochemically deposited thin oxide films.

    SciTech Connect (OSTI)

    Balasubramanian, M.

    1998-06-02T23:59:59.000Z

    We have utilized ''in situ'' X-ray Absorption Fine Structure Spectroscopy to investigate the structure and composition of thin oxide films of nickel and iron that have been prepared by electrodeposition on a graphite substrate from aqueous solutions. The films are generally disordered. Structural information has been obtained from the analysis of the data. We also present initial findings on the local structure of heavy metal ions, e.g. Sr and Ce, incorporated into the electrodeposited nickel oxide films. Our results are of importance in a number of technological applications, among them, batteries, fuel cells, electrochromic and ferroelectric materials, corrosion protection, as well as environmental speciation and remediation.

  6. Ethanol oxidation on metal oxide-supported platinum catalysts

    SciTech Connect (OSTI)

    L. M. Petkovic 090468; Sergey N. Rashkeev; D. M. Ginosar

    2009-09-01T23:59:59.000Z

    Ethanol is a renewable fuel that can be used as an additive to gasoline (or its substitute) with the advantage of octane enhancement and reduced carbon monoxide exhaust emissions. However, on Ethanol is a renewable fuel that can be used as an additive to gasoline (or its substitute) with the advantage of octane enhancement and reduced carbon monoxide exhaust emissions. However, on the standard three-way catalysts, the conversion of unburned ethanol is low because both ethanol and some of its partially oxidized derivatives are highly resistant to oxidation. A combination of first-principles density-functional theory (DFT) based calculations and in-situ diffuse reflectance infrared spectroscopy (DRIFTS) analysis was applied to uncover some of the fundamental phenomena associated with ethanol oxidation on Pt containing catalysts. In particular, the objective was to analyze the role of the oxide (i.e., ?-Al2O3 or SiO2) substrate on the ethanol oxidation activity. The results showed that Pt nanoparticles trap and accumulate oxygen at their surface and perimeter sites and play the role of “stoves” that burn ethanol molecules and their partially oxidized derivatives to the “final” products. The ?-Al2O3 surfaces provided higher mobility of the fragments of ethanol molecules than the SiO2 surface and hence increased the supply rate of these objects to the Pt particles. This will in turn produce a higher conversion rate of unburned ethanol.and some of its partially oxidized derivatives are highly resistant to oxidation. A combination of first-principles density-functional theory (DFT) based calculations and in-situ diffuse reflectance infrared spectroscopy (DRIFTS) analysis was applied to uncover some of the fundamental phenomena associated with ethanol oxidation on Pt containing catalysts. In particular, the objective was to analyze the role of the oxide (i.e., ?-Al2O3 or SiO2) substrate on the ethanol oxidation activity. The results showed that Pt nanoparticles trap and accumulate oxygen at their surface and perimeter sites and play the role of “stoves” that burn ethanol molecules and their partially oxidized derivatives to the “final” products. The ?-Al2O3 surfaces provided higher mobility of the fragments of ethanol molecules than the SiO2 surface and hence increased the supply rate of these objects to the Pt particles. This will in turn produce a higher conversion rate of unburned ethanol.

  7. Corrosion of lithium-ion battery current collectors

    SciTech Connect (OSTI)

    Braithwaite, J.W.; Gonzales, A.; Nagasubramanian, G.; Lucero, S.J.; Peebles, D.E.; Ohlhausen, J.A.; Cieslak, W.R. [Sandia National Labs., Albuquerque, NM (United States)] [Sandia National Labs., Albuquerque, NM (United States)

    1999-02-01T23:59:59.000Z

    The primary current-collector materials being used in lithium-ion cells are susceptible to environmental degradation: aluminum to pitting corrosion and copper to environmentally assisted cracking. Localized corrosion occurred on bare aluminum electrodes during simulated ambient-temperature cycling in an excess of electrolyte. The highly oxidizing potential associated with the positive-electrode charge condition was the primary factor. The corrosion mechanism differed from the pitting typically observed in aqueous electrolytes because each site was filled with a mixed metal/metal-oxide product, forming surface mounds or nodules. Electrochemical impedance spectroscopy was shown to be an effective analytical tool for characterizing the corrosion behavior of aluminum under these conditions. Based on X-ray photoelectron spectroscopy analyses, little difference existed in the composition of the surface film on aluminum and copper after immersion or cycling in LiPF{sub 6} electrolytes made with two different solvent formulations. Although Li and P were the predominant adsorbed surface species, the corrosion resistance of aluminum may simply be due to its native oxide. Finally, copper was shown to be susceptible to environmental cracking at or near the lithium potential when specific metallurgical conditions existed (work hardening and large grain size).

  8. Processing of Non-PFP Plutonium Oxide in Hanford Plants

    SciTech Connect (OSTI)

    Jones, Susan A.; Delegard, Calvin H.

    2011-03-10T23:59:59.000Z

    Processing of non-irradiated plutonium oxide, PuO2, scrap for recovery of plutonium values occurred routinely at Hanford’s Plutonium Finishing Plant (PFP) in glovebox line operations. Plutonium oxide is difficult to dissolve, particularly if it has been high-fired; i.e., calcined to temperatures above about 400°C and much of it was. Dissolution of the PuO2 in the scrap typically was performed in PFP’s Miscellaneous Treatment line using nitric acid (HNO3) containing some source of fluoride ion, F-, such as hydrofluoric acid (HF), sodium fluoride (NaF), or calcium fluoride (CaF2). The HNO3 concentration generally was 6 M or higher whereas the fluoride concentration was ~0.5 M or lower. At higher fluoride concentrations, plutonium fluoride (PuF4) would precipitate, thus limiting the plutonium dissolution. Some plutonium-bearing scrap also contained PuF4 and thus required no added fluoride. Once the plutonium scrap was dissolved, the excess fluoride was complexed with aluminum ion, Al3+, added as aluminum nitrate, Al(NO3)3•9H2O, to limit collateral damage to the process equipment by the corrosive fluoride. Aluminum nitrate also was added in low quantities in processing PuF4.

  9. LITERATURE REVIEW FOR OXALATE OXIDATION PROCESSES AND PLUTONIUM OXALATE SOLUBILITY

    SciTech Connect (OSTI)

    Nash, C.

    2012-02-03T23:59:59.000Z

    A literature review of oxalate oxidation processes finds that manganese(II)-catalyzed nitric acid oxidation of oxalate in precipitate filtrate is a viable and well-documented process. The process has been operated on the large scale at Savannah River in the past, including oxidation of 20 tons of oxalic acid in F-Canyon. Research data under a variety of conditions show the process to be robust. This process is recommended for oxalate destruction in H-Canyon in the upcoming program to produce feed for the MOX facility. Prevention of plutonium oxalate precipitation in filtrate can be achieved by concentrated nitric acid/ferric nitrate sequestration of oxalate. Organic complexants do not appear practical to sequester plutonium. Testing is proposed to confirm the literature and calculation findings of this review at projected operating conditions for the upcoming campaign. H Canyon plans to commence conversion of plutonium metal to low-fired plutonium oxide in 2012 for eventual use in the Mixed Oxide Fuel (MOX) Facility. The flowsheet includes sequential operations of metal dissolution, ion exchange, elution, oxalate precipitation, filtration, and calcination. All processes beyond dissolution will occur in HB-Line. The filtration step produces an aqueous filtrate that may have as much as 4 M nitric acid and 0.15 M oxalate. The oxalate needs to be removed from the stream to prevent possible downstream precipitation of residual plutonium when the solution is processed in H Canyon. In addition, sending the oxalate to the waste tank farm is undesirable. This report addresses the processing options for destroying the oxalate in existing H Canyon equipment.

  10. Voltage, Stability and Diffusion Barrier Differences between Sodium-ion and Lithium-ion Intercalation Materials

    E-Print Network [OSTI]

    Ong, Shyue Ping

    To evaluate the potential of Na-ion batteries, we contrast in this work the difference between Na-ion and Li-ion based intercalation chemistries in terms of three key battery properties—voltage, phase stability and diffusion ...

  11. Characterization of Electrode Materials for Lithium Ion and Sodium Ion Batteries using Synchrotron Radiation Techniques

    E-Print Network [OSTI]

    Doeff, Marca M.

    2013-01-01T23:59:59.000Z

    Rechargeable Sodium-Ion Batteries: Potential Alternatives toCurrent Lithium-Ion Batteries. Adv. Energy Mater. 2 (2012):J. , Rojo, T. Na-ion Batteries, Recent Advances and Present

  12. Characterization of an iodine-based ionic liquid ion source and studies on ion fragmentation

    E-Print Network [OSTI]

    Fedkiw, Timothy Peter

    2010-01-01T23:59:59.000Z

    Electrosprays are a well studied source of charged droplets and ions. A specific subclass is the ionic liquid ion source (ILIS), which produce ion beams from the electrostatically stressed meniscus of ionic liquids. ILIS ...

  13. Characterization of Electrode Materials for Lithium Ion and Sodium Ion Batteries using Synchrotron Radiation Techniques

    E-Print Network [OSTI]

    Doeff, Marca M.

    2013-01-01T23:59:59.000Z

    Alternatives to Current Lithium-Ion Batteries. Adv. EnergyMaterials for Lithium Ion Batteries. Materials Matters. 7 4.to the Study of Lithium Ion Batteries. J. Solid State

  14. Three chamber negative ion source

    DOE Patents [OSTI]

    Leung, Ka-Ngo (Hercules, CA); Ehlers, Kenneth W. (Alamo, CA); Hiskes, John R. (Livermore, CA)

    1985-01-01T23:59:59.000Z

    A negative ion vessel is divided into an excitation chamber, a negative ionization chamber and an extraction chamber by two magnetic filters. Input means introduces neutral molecules into a first chamber where a first electron discharge means vibrationally excites the molecules which migrate to a second chamber. In the second chamber a second electron discharge means ionizes the molecules, producing negative ions which are extracted into or by a third chamber. A first magnetic filter prevents high energy electrons from entering the negative ionization chamber from the excitation chamber. A second magnetic filter prevents high energy electrons from entering the extraction chamber from the negative ionizing chamber. An extraction grid at the end of the negative ion vessel attracts negative ions into the third chamber and accelerates them. Another grid, located adjacent to the extraction grid, carries a small positive voltage in order to inhibit positive ions from migrating into the extraction chamber and contour the plasma potential. Additional electrons can be suppressed from the output flux using ExB forces provided by magnetic field means and the extractor grid electric potential.

  15. Chemistry of heavy ion reactions

    SciTech Connect (OSTI)

    Hoffman, D.C.

    1988-10-01T23:59:59.000Z

    The use of heavy ions to induce nuclear reactions was reported as early as 1950. Since that time it has been one of the most active areas of nuclear research. Intense beams of ions as heavy as uranium with energies high enough to overcome the Coulomb barriers of even the heaviest elements are available. The wide variety of possible reactions gives rise to a multitude of products which have been studied by many ingenious chemical and physical techniques. Chemical techniques have been of special value for the separation and unequivocal identification of low yield species from the plethora of other nuclides present. Heavy ion reactions have been essential for the production of the trans-Md elements and a host of new isotopes. The systematics of compound nucleus reactions, transfer reactions, and deeply inelastic reactions have been elucidated using chemical techniques. A review of the variety of chemical procedures and techniques which have been developed for the study of heavy ion reactions and their products is given. Determination of the chemical properties of the trans-Md elements, which are very short-lived and can only be produced an ''atom-at-a-time'' via heavy ion reactions, is discussed. 53 refs., 19 figs.

  16. High Resolution Studies of the Origins of Polyatomic Ions in Inductively Coupled Plasma-Mass Spectrometry

    SciTech Connect (OSTI)

    Jill Wisnewski Ferguson

    2006-08-09T23:59:59.000Z

    The inductively coupled plasma (ICP) is an atmospheric pressure ionization source. Traditionally, the plasma is sampled via a sampler cone. A supersonic jet develops behind the sampler, and this region is pumped down to a pressure of approximately one Torr. A skimmer cone is located inside this zone of silence to transmit ions into the mass spectrometer. The position of the sampler and skimmer cones relative to the initial radiation and normal analytical zones of the plasma is key to optimizing the useful analytical signal [1]. The ICP both atomizes and ionizes the sample. Polyatomic ions form through ion-molecule interactions either in the ICP or during ion extraction [l]. Common polyatomic ions that inhibit analysis include metal oxides (MO{sup +}), adducts with argon, the gas most commonly used to make up the plasma, and hydride species. While high resolution devices can separate many analytes from common interferences, this is done at great cost in ion transmission efficiency--a loss of 99% when using high versus low resolution on the same instrument [2]. Simple quadrupole devices, which make up the bulk of ICP-MS instruments in existence, do not present this option. Therefore, if the source of polyatomic interferences can be determined and then manipulated, this could potentially improve the figures of merit on all ICP-MS devices, not just the high resolution devices often utilized to study polyatomic interferences.

  17. Pseudo ribbon metal ion beam source

    SciTech Connect (OSTI)

    Stepanov, Igor B., E-mail: stepanovib@tpu.ru; Ryabchikov, Alexander I.; Sivin, Denis O.; Verigin, Dan A. [Tomsk Polytechnic University, 30 Lenina Avenue, Tomsk 634050 (Russian Federation)] [Tomsk Polytechnic University, 30 Lenina Avenue, Tomsk 634050 (Russian Federation)

    2014-02-15T23:59:59.000Z

    The paper describes high broad metal ion source based on dc macroparticle filtered vacuum arc plasma generation with the dc ion-beam extraction. The possibility of formation of pseudo ribbon beam of metal ions with the parameters: ion beam length 0.6 m, ion current up to 0.2 A, accelerating voltage 40 kV, and ion energy up to 160 kV has been demonstrated. The pseudo ribbon ion beam is formed from dc vacuum arc plasma. The results of investigation of the vacuum arc evaporator ion-emission properties are presented. The influence of magnetic field strength near the cathode surface on the arc spot movement and ion-emission properties of vacuum-arc discharge for different cathode materials are determined. It was shown that vacuum-arc discharge stability can be reached when the magnetic field strength ranges from 40 to 70 G on the cathode surface.

  18. STABLE HIGH CONDUCTIVITY BILAYERED ELECTROLYTES FOR LOW TEMPERATURE SOLID OXIDE FUEL CELLS

    SciTech Connect (OSTI)

    Eric D. Wachsman; Keith L. Duncan

    2002-09-30T23:59:59.000Z

    A bilayer electrolyte consisting of acceptor-doped ceria (on the fuel/reducing side) and cubic-stabilized bismuth oxide (on the oxidizing side) was developed. The bilayer electrolyte that was developed showed significant improvement in open-circuit potential versus a typical ceria based SOFC. Moreover, the OCP of the bilayer cells increased as the thickness of the bismuth oxide layer increased relative to the ceria layer. Thereby, verifying the bilayer concept. Although, because of the absence of a suitable cathode (a problem we are still working assiduously to solve), we were unable to obtain power density curves, our modeling work predicts a reduction in electrolyte area specific resistance of two orders of magnitude over cubic-stabilized zirconia and projects a maximum power density of 9 W/m{sup 2} at 800 C and 0.09 W/m{sup 2} at 500 C. Towards the development of the bilayer electrolyte other significant strides were made. Among these were, first, the development of a, bismuth oxide based, oxide ion conductor with the highest conductivity (0.56 S/cm at 800 C and 0.043 S/cm at 500 C) known to date. Second, a physical model of the defect transport mechanisms and the driving forces for the ordering phenomena in bismuth oxide and other fluorite systems was developed. Third, a model for point defect transport in oxide mixed ionic-electronic conductors was developed, without the typical assumption of a uniform distribution of ions and including the effect of variable loads on the transport properties of an SOFC (with either a single or bilayer electrolyte).

  19. Investigation of Mixed Oxide Catalysts for NO Oxidation

    SciTech Connect (OSTI)

    Szanyi, Janos; Karim, Ayman M.; Pederson, Larry R.; Kwak, Ja Hun; Mei, Donghai; Tran, Diana N.; Herling, Darrell R.; Muntean, George G.; Peden, Charles HF; Howden, Ken; Qi, Gongshin; Li, Wei

    2014-12-09T23:59:59.000Z

    The oxidation of engine-generated NO to NO2 is an important step in the reduction of NOx in lean engine exhaust because NO2 is required for the performance of the LNT technology [2], and it enhances the activities of ammonia selective catalytic reduction (SCR) catalysts [1]. In particular, for SCR catalysts an NO:NO2 ratio of 1:1 is most effective for NOx reduction, whereas for LNT catalysts, NO must be oxidized to NO2 before adsorption on the storage components. However, NO2 typically constitutes less than 10% of NOx in lean exhaust, so catalytic oxidation of NO is essential. Platinum has been found to be especially active for NO oxidation, and is widely used in DOC and LNT catalysts. However, because of the high cost and poor thermal durability of Pt-based catalysts, there is substantial interest in the development of alternatives. The objective of this project, in collaboration with partner General Motors, is to develop mixed metal oxide catalysts for NO oxidation, enabling lower precious metal usage in emission control systems. [1] M. Koebel, G. Madia, and M. Elsener, Catalysis Today 73, 239 (2002). [2] C. H. Kim, G. S. Qi, K. Dahlberg, and W. Li, Science 327, 1624 (2010).

  20. Microscale ion trap mass spectrometer

    DOE Patents [OSTI]

    Ramsey, J. Michael (Knoxville, TN); Witten, William B. (Lancing, TN); Kornienko, Oleg (Lansdale, PA)

    2002-01-01T23:59:59.000Z

    An ion trap for mass spectrometric chemical analysis of ions is delineated. The ion trap includes a central electrode having an aperture; a pair of insulators, each having an aperture; a pair of end cap electrodes, each having an aperture; a first electronic signal source coupled to the central electrode; a second electronic signal source coupled to the end cap electrodes. The central electrode, insulators, and end cap electrodes are united in a sandwich construction where their respective apertures are coaxially aligned and symmetric about an axis to form a partially enclosed cavity having an effective radius r.sub.0 and an effective length 2z.sub.0, wherein r.sub.0 and/or z.sub.0 are less than 1.0 mm, and a ratio z.sub.0 /r.sub.0 is greater than 0.83.

  1. Trapped-ion Lissajous trajectories

    E-Print Network [OSTI]

    R. F. Rossetti; G. D. de Moraes Neto; J. Carlos Egues; M. H. Y. Moussa

    2015-02-25T23:59:59.000Z

    Here we present a protocol for generating Lissajous curves with a trapped ion by engineering Rashba- and the Dresselhaus-type spin-orbit interactions in a Paul trap. The unique anisotropic Rashba $\\alpha_{x}$, $\\alpha_{y}$ and Dresselhaus $\\beta_{x}$, $\\beta_{y}$ couplings afforded by our setup also enables us to obtain an "unusual" Zitterbewegung, i.e., the semiconductor analog of the relativistic trembling motion of electrons, with cycloidal trajectories in the absence of magnetic fields. We have also introduced bounded SO interactions, confined to an upper-bound vibrational subspace of the Fock states, as an additional mechanism to manipulate the Lissajous motion of the trapped ion. Finally, we accounted for dissipative effects on the vibrational degrees of freedom of the ion and find that the Lissajous trajectories are still robust and well defined for realistic parameters.

  2. Tachyon Physics with Trapped Ions

    E-Print Network [OSTI]

    Lee, Tony E; Cheng, Xiao-Hang; Lamata, Lucas; Solano, Enrique

    2015-01-01T23:59:59.000Z

    It has been predicted that particles with imaginary mass, called tachyons, would be able to travel faster than the speed of light. So far, there has not been any experimental evidence for tachyons in either natural or engineered systems. Here, we propose how to experimentally simulate Dirac tachyons with trapped ions. Quantum measurement on a Dirac particle simulated by a trapped ion causes it to have an imaginary mass so that it may travel faster than the effective speed of light. We show that a Dirac tachyon must have spinor-motion entanglement in order to be superluminal. We also show that it exhibits significantly more Klein tunneling than a normal Dirac particle. We provide numerical simulations with realistic ion systems and show that our scheme is feasible with current technology.

  3. Ion Sources for High Energy Ion Implantation at BNL | U.S. DOE...

    Office of Science (SC) Website

    Ion Sources for High Energy Ion Implantation at BNL Nuclear Physics (NP) NP Home About Research Facilities Science Highlights Benefits of NP Applications of Nuclear Science...

  4. Compositional Tuning of Ultrathin Surface Oxides on Metal and...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    that the native oxide on 5%Ni-Al alloy is primarily composed of aluminum oxide with no nickel oxide whereas the photon-assisted oxide comprises of both aluminum oxide and nickel...

  5. Engineering properties of superhard films with ion energy and post-deposition processing

    SciTech Connect (OSTI)

    Monteiro, Othon R.; Delplancke-Ogletree, Mari-Paule

    2002-10-14T23:59:59.000Z

    Recent developments in plasma synthesis of hard materials using energetic ions are described. Metal Plasma Immersion Ion Implantation and Deposition (MePIIID) has been used to prepare several hard films: from diamondlike carbon (DLC) to carbides, from nitrides to oxides. The energy of the depositing species is controlled to maximize adhesion as well as to change the physical and chemical properties of the films. Adhesion is promoted by the creation of a graded interface between the film and the substrate. The energy of the depositing ions is also used to modify and control the intrinsic stresses and the microstructure of the films. The deposition is carried out at room temperature, which is important for temperature sensitive substrates. A correlation between intrinsic stresses and the energetics of the deposition is presented for the case of DLC films, and means to reduce stress levels are discussed.

  6. Optical indices of lithiated electrochromic oxides

    SciTech Connect (OSTI)

    Rubin, M.; Rottkay, K. von; Wen, S.J.; Ozer, N.; Slack, J.

    1996-09-01T23:59:59.000Z

    Optical indices have been determined for thin films of several electrochromic oxide materials. One of the most important materials in electrochromic devices, WO{sub 3}, was thoroughly characterized for a range of electrochromic states by sequential injection of Li ions. Another promising material, Li{sub 0.5}Ni{sub 0.5}O, was also studied in detail. Less detailed results are presented for three other common lithium-intercalating electrochromic electrode materials: V{sub 2}O{sub 5}, LiCoO{sub 2}, and CeO{sub 2}-TiO{sub 2}. The films were grown by sputtering, pulsed laser deposition (PLD) and sol-gel techniques. Measurements were made using a combination of variable-angle spectroscopy ellipsometry and spectroradiometry. The optical constants were then extracted using physical and spectral models appropriate to each material. Optical indices of the underlying transparent conductors, determined in separate studies, were fixed in the models of this work. The optical models frequently agree well with independent physical measurements of film structure, particularly surface roughness by atomic force microscopy. Inhomogeneity due to surface roughness, gradient composition, and phase separation are common in both the transparent conductors and electrochromics, resulting sometimes in particularly complex models for these materials. Complete sets of data are presented over the entire solar spectrum for a range of colored states. This data is suitable for prediction of additional optical properties such as oblique transmittance and design of complete electrochromic devices.

  7. Prediction of new thermodynamically stable aluminum oxides

    E-Print Network [OSTI]

    Liu, Yue; Wang, Shengnan; Zhu, Qiang; Dong, Xiao; Kresse, Georg

    2015-01-01T23:59:59.000Z

    Recently, it has been shown that under pressure, unexpected and counterintuitive chemical compounds become stable. Laser shock experiments (A. Rode, unpublished) on alumina (Al2O3) have shown non-equilibrium decomposition of alumina with the formation of free Al and a mysterious transparent phase. Inspired by these observations, with have explored the possibility of the formation of new chemical compounds in the system Al-O. Using the variable-composition structure prediction algorithm USPEX, in addition to the well-known Al2O3, we have found two extraordinary compounds Al4O7 and AlO2 to be thermodynamically stable in the pressure range 330-443 GPa and above 332 GPa, respectively. Both of these compounds at the same time contain oxide O2- and peroxide O22- ions, and both are insulating. Peroxo-groups are responsible for gap states, which significantly reduce the electronic band gap of both Al4O7 and AlO2.

  8. Oxides having high energy densities

    DOE Patents [OSTI]

    Ceder, Gerbrand; Kang, Kisuk

    2013-09-10T23:59:59.000Z

    Certain disclosed embodiments generally relate to oxide materials having relatively high energy and/or power densities. Various aspects of the embodiments are directed to oxide materials having a structure B.sub.i(M.sub.jY.sub.k)O.sub.2, for example, a structure Li.sub.j(Ni.sub.jY.sub.k)O.sub.2 such as Li(Ni.sub.0.5Mn.sub.0.5)O.sub.2. In this structure, Y represents one or more atoms, each independently selected from the group consisting of alkaline earth metals, transition metals, Group 14 elements, Group 15, or Group 16 elements. In some embodiments, such an oxide material may have an O3 crystal structure, and/or a layered structure such that the oxide comprises a plurality of first, repeating atomic planes comprising Li, and a plurality of second, repeating atomic planes comprising Ni and/or Y.

  9. Thermal oxidation procedure PREPARATION........................................................................................................................................... 2

    E-Print Network [OSTI]

    Hochberg, Michael

    procedure - 2 - Preparation. The preparation procedure sets up the power, gas supplies, cooling water, (DI to check all the supplies. Cooling water Gas supplies Routing DI water for wet oxidation We start........................................................................................................................................... 2 Step 1 Turn on the cooling water

  10. Ion acoustic shock waves in degenerate plasmas

    SciTech Connect (OSTI)

    Akhtar, N. [Theoretical Plasma Physics Division, PINSTECH, Nilore, Islamabad 44000 Pakistan (Pakistan); Hussain, S. [Theoretical Plasma Physics Division, PINSTECH, Nilore, Islamabad 44000 Pakistan (Pakistan); Department of Physics and Applied Mathematics, PIEAS, Nilore, Islamabad 44000 Pakistan (Pakistan)

    2011-07-15T23:59:59.000Z

    Korteweg de Vries Burgers equation for negative ion degenerate dissipative plasma has been derived using reductive perturbation technique. The quantum hydrodynamic model is used to study the quantum ion acoustic shock waves. The effects of different parameters on quantum ion acoustic shock waves are studied. It is found that quantum parameter, electrons Fermi temperature, temperature of positive and negative ions, mass ratio of positive to negative ions, viscosity, and density ratio have significant impact on the shock wave structure in negative ion degenerate plasma.

  11. Microfabricated linear Paul-Straubel ion trap

    DOE Patents [OSTI]

    Mangan, Michael A. (Albuquerque, NM); Blain, Matthew G. (Albuquerque, NM); Tigges, Chris P. (Albuquerque, NM); Linker, Kevin L. (Albuquerque, NM)

    2011-04-19T23:59:59.000Z

    An array of microfabricated linear Paul-Straubel ion traps can be used for mass spectrometric applications. Each ion trap comprises two parallel inner RF electrodes and two parallel outer DC control electrodes symmetric about a central trap axis and suspended over an opening in a substrate. Neighboring ion traps in the array can share a common outer DC control electrode. The ions confined transversely by an RF quadrupole electric field potential well on the ion trap axis. The array can trap a wide array of ions.

  12. Ion mobility spectrometer with virtual aperture grid

    DOE Patents [OSTI]

    Pfeifer, Kent B. (Los Lunas, NM); Rumpf, Arthur N. (Albuquerque, NM)

    2010-11-23T23:59:59.000Z

    An ion mobility spectrometer does not require a physical aperture grid to prevent premature ion detector response. The last electrodes adjacent to the ion collector (typically the last four or five) have an electrode pitch that is less than the width of the ion swarm and each of the adjacent electrodes is connected to a source of free charge, thereby providing a virtual aperture grid at the end of the drift region that shields the ion collector from the mirror current of the approaching ion swarm. The virtual aperture grid is less complex in assembly and function and is less sensitive to vibrations than the physical aperture grid.

  13. Grafted methylenediphosphonate ion exchange resins

    DOE Patents [OSTI]

    Trochimcznk, A.W.; Gatrone, R.C.; Alexandratos, S.; Horwitz, E.P.

    1997-04-08T23:59:59.000Z

    An ion exchange resin is disclosed that is comprised of an insoluble copolymer onto which are grafted pendent groups that provide 1.0 to about 10 mmol/g dry weight phosphorus. The pendent groups have the formula as shown in the patent wherein R is hydrogen, a cation or mixtures thereof; and R{sup 1} is hydrogen or an C{sub 1}-C{sub 2} alkyl group. The resin also contains zero to about 5 mmol/g dry weight of pendent aromatic sulfonate groups. Processes for making and using an ion exchange resin are also disclosed.

  14. Pionic Fusion of Heavy Ions

    E-Print Network [OSTI]

    D. Horn; G. C. Ball; D. R. Bowman; W. G. Davies; D. Fox; A. Galindo-Uribarri; A. C. Hayes; G. Savard; L. Beaulieu; Y. Larochelle; C. St-Pierre

    1996-08-13T23:59:59.000Z

    We report the first experimental observation of the pionic fusion of two heavy ions. The 12C(12C,24Mg)pi0 and 12C(12C,24Na)pi+ cross sections have been measured to be 208 +/- 38 and 182 +/- 84 picobarns, respectively, at E_cm = 137 MeV. This cross section for heavy-ion pion production, at an energy just 6 MeV above the absolute energy-conservation limit, constrains possible production mechanisms to incorporate the kinetic energy of the entire projectile-target system as well as the binding energy gained in fusion.

  15. Relating to monitoring ion sources

    DOE Patents [OSTI]

    Orr, Christopher Henry (Calderbridge, GB); Luff, Craig Janson (Calderbridge, GB); Dockray, Thomas (Calderbridge, GB); Macarthur, Duncan Whittemore (Los Alamos, NM); Bounds, John Alan (Los Alamos, NM)

    2002-01-01T23:59:59.000Z

    The apparatus and method provide techniques for monitoring the position on alpha contamination in or on items or locations. The technique is particularly applicable to pipes, conduits and other locations to which access is difficult. The technique uses indirect monitoring of alpha emissions by detecting ions generated by the alpha emissions. The medium containing the ions is moved in a controlled manner frog in proximity with the item or location to the detecting unit and the signals achieved over time are used to generate alpha source position information.

  16. Non-destructive radiocarbon and stable isotopic analyses of archaeological materials using plasma oxidation

    E-Print Network [OSTI]

    Steelman, Karen Lynn

    2005-11-01T23:59:59.000Z

    contamination of modern carbon required to alter these measured radiocarbon dates to the archaeologically expected ages???????????? 130 18 Results of plasma oxidations and the radiocarbon age determination for the ?caribou? charcoal rock painting from... N, 13 CH, and 12 CH 2 . The use of high-energy mass spectrometry and a cesium sputter ion source in the late 1970s eliminated these interferences (Bennett et al. 1977; Nelson et al. 1977; and Muller et al. 1978). Muller (1977) proposed the use...

  17. The catalytic oxidation of propane 

    E-Print Network [OSTI]

    Sanderson, Charles Frederick

    1949-01-01T23:59:59.000Z

    THE CATALYTIC OXIDATION OP PROPANE A Thesis By Charles Frederick Sandersont * * June 1949 Approval as to style and content recommended: Head of the Department of Chemical Engineering THE CATALYTICi OXIDATTON OF PROPANE A Thesis By Charles... Frederick ;Sandersonit * June 1949 THE CATALYTIC OXIDATION OP PROPANE A Thesis Submitted to the Faculty of the Agricultural and Mechanical College of Texas in Partial Fulfillment of the Requirements for the Degree of Doctor of Philosophy Major...

  18. The catalytic oxidation of propane

    E-Print Network [OSTI]

    Sanderson, Charles Frederick

    1949-01-01T23:59:59.000Z

    THE CATALYTIC OXIDATION OP PROPANE A Thesis By Charles Frederick Sandersont * * June 1949 Approval as to style and content recommended: Head of the Department of Chemical Engineering THE CATALYTICi OXIDATTON OF PROPANE A Thesis By Charles... Frederick ;Sandersonit * June 1949 THE CATALYTIC OXIDATION OP PROPANE A Thesis Submitted to the Faculty of the Agricultural and Mechanical College of Texas in Partial Fulfillment of the Requirements for the Degree of Doctor of Philosophy Major...

  19. Surface-Driven Sodium Ion Energy Storage in Nanocellular Carbon...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Surface-Driven Sodium Ion Energy Storage in Nanocellular Carbon Foams. Surface-Driven Sodium Ion Energy Storage in Nanocellular Carbon Foams. Abstract: Sodium ion (Na+) batteries...

  20. Proceedings of the 8th High Energy Heavy Ion Study

    E-Print Network [OSTI]

    Harris Ed, J.W.

    2010-01-01T23:59:59.000Z

    and a high pressure ion chamber. Several of the gas modulesenergy measurement in the ion chamber. The calibrations werefield Frisch grid ion chamber, which is operated with

  1. Ion Energy Distribution in Collisionless and Collisional, Capacitive RF Sheath

    E-Print Network [OSTI]

    Wang, Ying

    2012-01-01T23:59:59.000Z

    Sheath 3 Model of Collisionless Ion Energy Distributions 3.1Ion Energy Distributions in Collisionless and Collisional,Fall 2012 Ion Energy Distributions in Collisionless and

  2. Pushing the Frontier of High-Definition Ion Mobility Spectrometry...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the Frontier of High-Definition Ion Mobility Spectrometry Using FAIMS. Pushing the Frontier of High-Definition Ion Mobility Spectrometry Using FAIMS. Abstract: Differential ion...

  3. Fundamentals of Traveling Wave Ion Mobility Spectrometry. | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fundamentals of Traveling Wave Ion Mobility Spectrometry. Fundamentals of Traveling Wave Ion Mobility Spectrometry. Abstract: Traveling-wave ion mobility spectrometry (TW IMS) is a...

  4. Intercalation Kinetics and Ion Mobility in Electrode Materials...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Intercalation Kinetics and Ion Mobility in Electrode Materials for Advanced Lithium Ion Batteries Intercalation Kinetics and Ion Mobility in Electrode Materials for Advanced...

  5. alloy ion source: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ions at radioactive ion beam facilities is discussed. The ability to combine high efficiency and element selectivity makes a resonance ionization laser ion source (RILIS) an...

  6. ambient ion sources: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ions at radioactive ion beam facilities is discussed. The ability to combine high efficiency and element selectivity makes a resonance ionization laser ion source (RILIS) an...

  7. Metal oxide nanostructures with hierarchical morphology

    DOE Patents [OSTI]

    Ren, Zhifeng (Newton, MA); Lao, Jing Yu (Saline, MI); Banerjee, Debasish (Ann Arbor, MI)

    2007-11-13T23:59:59.000Z

    The present invention relates generally to metal oxide materials with varied symmetrical nanostructure morphologies. In particular, the present invention provides metal oxide materials comprising one or more metallic oxides with three-dimensionally ordered nanostructural morphologies, including hierarchical morphologies. The present invention also provides methods for producing such metal oxide materials.

  8. Conflicting Roles Of Nickel In Controlling Cathode Performance In Lithium-ion Batteries

    SciTech Connect (OSTI)

    Gu, Meng; Belharouak, Ilias; Genc, Arda; Wang, Zhiguo; Wang, Dapeng; Amine, Khalil; Gao, Fei; Zhou, Guangwen; Thevuthasan, Suntharampillai; Baer, Donald R.; Zhang, Jiguang; Browning, Nigel D.; Liu, Jun; Wang, Chong M.

    2012-09-17T23:59:59.000Z

    A variety of approaches are being made to enhance the performance of lithium ion batteries. Incorporating multi-valence transition metal ions into metal oxide cathodes has been identified as an essential approach to achieve the necessary high voltage and high capacity. However, the fundamental mechanism that limits their power rate and cycling stability remains unclear. The power rate strongly depends on the lithium ion drift speed in the cathode. Crystallographically, these transition metal-based cathodes frequently have a layered structure. In the classic wisdom, it is accepted that lithium ion travels swiftly within the layers moving out/in of the cathode during the charge/discharge. Here, we report the unexpected discovery of a thermodynamically driven, yet kinetically controlled, surface modification in the widely explored lithium nickel manganese oxide cathode material, which may inhibit the battery charge/discharge rate. We found that during cathode synthesis and processing before electrochemical cycling in the cell nickel can preferentially move along the fast diffusion channels and selectively segregate at the surface facets terminated with a mix of anions and cations. This segregation essentially blocks the otherwise fast out/in pathways for lithium ions during the charge/discharge. Therefore, it appears that the transition metal dopant may help to provide high capacity and/or high voltage, but can be located in a “wrong” location that blocks or slows lithium diffusion, limiting battery performance. In this circumstance, limitations in the properties of Li-ion batteries using these cathode materials can be determined more by the materials synthesis issues than by the operation within the battery itself.

  9. Oxide Film Aging on Alloy 22 in Halide Containing Solutions

    SciTech Connect (OSTI)

    Rodriguez, Martin A.; Carranza, Ricardo M. [Dept. Materiales, Comision Nacional de Energia Atomica, Av. Gral. Paz 1499, Villa Maipu, 1650 (Argentina); Rebak, Raul B. [Lawrence Livermore National Laboratory, 7000 East Ave, L-631, Livermore, CA, 94550-9698 (United States)

    2007-07-01T23:59:59.000Z

    Passive and corrosion behaviors of Alloy 22 in chloride and fluoride containing solutions, changing the heat treatment of the alloy, the halide concentration and the pH of the solutions at 90 deg. C, was investigated. The study was implemented using electrochemical techniques, which included open circuit potential monitoring over time, potentiodynamic polarization and electrochemical impedance spectroscopy (EIS) measurements carried out at open circuit and at passivity potentials. Corrosion rates obtained by EIS measurements after 24 h immersion in naturally aerated solutions were below 0.5 {mu}m/year. The corrosion rates were practically independent of solution pH, alloy heat treatment and halide ion nature and concentration. EIS low frequency resistance values increased with applied potential in the passive domain and with polarization time in pH 6 - 1 M NaCl at 90 deg. C. This effect was attributed to an increase in the oxide film thickness and oxide film aging. High frequency capacitance measurements indicated that passive oxide on Alloy 22 presented a double n-type/p-type semiconductor behavior in the passive potential range. (authors)

  10. The positive ion temperature effect in magnetized electronegative plasma sheath with two species of positive ions

    SciTech Connect (OSTI)

    Shaw, A. K. [Centre of Plasma Physics, Institute for Plasma Research, Sonapur-782 402, Guwahati, Assam (India); Institute for Plasma Research, Bhat, Gandhinagar-382 428, Gujarat (India); Kar, S. [Institute for Plasma Research, Bhat, Gandhinagar-382 428, Gujarat (India); Goswami, K. S. [Centre of Plasma Physics, Institute for Plasma Research, Sonapur-782 402, Guwahati, Assam (India)

    2012-10-15T23:59:59.000Z

    The properties of a magnetized multi-component (two species of positive ions, negative ions and electrons) plasma sheath with finite positive ion temperature are studied. By using three fluid hydrodynamic model and some dimensionless variables, the ion (both lighter and heavier positive ions, and negative ions) densities, the ion (only for positive ions) velocities, and electric potential inside the sheath are investigated. In addition, the absence and presence of magnetic field and the orientation of magnetic field are considered. It is noticed that, with increase of positive ion temperature, the lighter positive ion density peaks increase only at the sheath edge and shift towards the sheath edge for both absence and presence of magnetic field. For heavier positive ions, in the absence of magnetic field, the density peaks increase at the sheath edge. But in the presence of magnetic field, the density fluctuations increase at the sheath edge. For both the cases, the density peaks shift towards the sheath edge.

  11. In situ reduction and oxidation of nickel from solid oxide fuel cells in a Titan ETEM

    E-Print Network [OSTI]

    Dunin-Borkowski, Rafal E.

    In situ reduction and oxidation of nickel from solid oxide fuel cells in a Titan ETEM A. Faes1, Denmark antonin.faes@epfl.ch Keywords: In situ ETEM, nickel oxide, reduction, RedOx, SOFC Solid Oxide Fuel. C. Singhal, K. Kendall, High Temperature Solid Oxide Fuel Cell - Fundamentals, Design

  12. Millisecond Oxidation of Alkanes

    SciTech Connect (OSTI)

    Scott Han

    2011-09-30T23:59:59.000Z

    This project was undertaken in response to the Department of Energy's call to research and develop technologies 'that will reduce energy consumption, enhance economic competitiveness, and reduce environmental impacts of the domestic chemical industry.' The current technology at the time for producing 140 billion pounds per year of propylene from naphtha and Liquified Petroleum Gas (LPG) relied on energy- and capital-intensive steam crackers and Fluidized Catalytic Cracking (FCC) units. The propylene is isolated from the product stream in a costly separation step and subsequently converted to acrylic acid and other derivatives in separate production facilities. This project proposed a Short Contact Time Reactor (SCTR)-based catalytic oxydehydrogenation process that could convert propane to propylene and acrylic acid in a cost-effective and energy-efficient fashion. Full implementation of this technology could lead to sizeable energy, economic and environmental benefits for the U. S. chemical industry by providing up to 45 trillion BTUs/year, cost savings of $1.8 billion/year and a combined 35 million pounds/year reduction in environmental pollutants such as COx, NOx, and SOx. Midway through the project term, the program directive changed, which approval from the DOE and its review panel, from direct propane oxidation to acrylic acid at millisecond contact times to a two-step process for making acrylic acid from propane. The first step was the primary focus, namely the conversion of propane to propylene in high yields assisted by the presence of CO2. The product stream from step one was then to be fed directly into a commercially practiced propylene-to-acrylic acid tandem reactor system.

  13. NEGATIVE ION PRODUCTION BY BACK-SCATTERING FROM ALKALI-METAL SURFACES BOMBARDED BY IONS OF HYDROGEN AND DEUTERIUM.

    E-Print Network [OSTI]

    Schneider, Peter Juergen

    2010-01-01T23:59:59.000Z

    and Neutralization of Negative Hydrogen Ions and Beams (and Neutralization of Negative Hydrogen Ions and Beams (and Neutralization of Negative Hydrogen Ions and Beams,

  14. Transparent conducting oxides and production thereof

    SciTech Connect (OSTI)

    Gessert, Timothy A.; Yoshida, Yuki; Coutts, Timothy J.

    2014-06-10T23:59:59.000Z

    Transparent conducting oxides and production thereof are disclosed. An exemplary method of producing a transparent conducting oxide (TCO) material may comprise: providing a TCO target doped with either a high-permittivity oxide or a low-permittivity oxide in a process chamber. The method may also comprise depositing a metal oxide on the target in the process chamber to form a thin film having enhanced optical properties without substantially decreasing electrical quality.

  15. Transparent conducting oxides and production thereof

    SciTech Connect (OSTI)

    Gessert, Timothy A; Yoshida, Yuki; Coutts, Timothy J

    2014-05-27T23:59:59.000Z

    Transparent conducting oxides and production thereof are disclosed. An exemplary method of producing a transparent conducting oxide (TCO) material may comprise: providing a TCO target (110) doped with either a high-permittivity oxide or a low-permittivity oxide in a process chamber (100). The method may also comprise depositing a metal oxide on the target (110) to form a thin film having enhanced optical properties without substantially decreasing electrical quality.

  16. Ion-induced nuclear radiotherapy

    DOE Patents [OSTI]

    Horn, Kevin M. (Albuquerque, NM); Doyle, Barney L. (Albuquerque, NM)

    1996-01-01T23:59:59.000Z

    Ion-induced Nuclear Radiotherapy (INRT) is a technique for conducting radiosurgery and radiotherapy with a very high degree of control over the spatial extent of the irradiated volume and the delivered dose. Based upon the concept that low energy, ion induced atomic and nuclear reactions can be used to produce highly energetic reaction products at the site of a tumor, the INRT technique is implemented through the use of a conduit-needle or tube which conducts a low energy ion beam to a position above or within the intended treatment area. At the end of the conduit-needle or tube is a specially fabricated target which, only when struck by the ion beam, acts as a source of energetic radiation products. The inherent limitations in the energy, and therefore range, of the resulting reaction products limits the spatial extent of irradiation to a pre-defined volume about the point of reaction. Furthermore, since no damage is done to tissue outside this irradiated volume, the delivered dose may be made arbitrarily large. INRT may be used both as a point-source of radiation at the site of a small tumor, or as a topical bath of radiation to broad areas of diseased tissue.

  17. Reactive Ion Etch Users Guide

    E-Print Network [OSTI]

    Wager, John F.

    RIE Reactive Ion Etch Users Guide Eric Sundholm 2-22-2007 Standby Condition: be sure that the tool the chamber to remove any potential hazards before the chamber can be opened. 9. Pump Down Chamber Utilities Pump Chamber 10. Check pressure to start turbo pump Display Sensor Display a. Wait for pressure

  18. The Electron-Ion Collider

    E-Print Network [OSTI]

    V. Guzey

    2009-07-23T23:59:59.000Z

    The future Electron-Ion Collider (EIC) is a proposed new facility to collide high-energy electrons with beams of polarized protons/light nuclei and unpolarized nuclei. We overview the goals of the project and key measurements at the EIC. We also briefly comment on recent developments of the project.

  19. Ion-induced nuclear radiotherapy

    DOE Patents [OSTI]

    Horn, K.M.; Doyle, B.L.

    1996-08-20T23:59:59.000Z

    Ion-induced Nuclear Radiotherapy (INRT) is a technique for conducting radiosurgery and radiotherapy with a very high degree of control over the spatial extent of the irradiated volume and the delivered dose. Based upon the concept that low energy, ion induced atomic and nuclear reactions can be used to produce highly energetic reaction products at the site of a tumor, the INRT technique is implemented through the use of a conduit-needle or tube which conducts a low energy ion beam to a position above or within the intended treatment area. At the end of the conduit-needle or tube is a specially fabricated target which, only when struck by the ion beam, acts as a source of energetic radiation products. The inherent limitations in the energy, and therefore range, of the resulting reaction products limits the spatial extent of irradiation to a pre-defined volume about the point of reaction. Furthermore, since no damage is done to tissue outside this irradiated volume, the delivered dose may be made arbitrarily large. INRT may be used both as a point-source of radiation at the site of a small tumor, or as a topical bath of radiation to broad areas of diseased tissue. 25 figs.

  20. Three-phase model for the reversible lithiation/delithiation of SnO anodes in Li-ion batteries

    E-Print Network [OSTI]

    Pedersen, Andreas; Luisier, Mathieu

    2015-01-01T23:59:59.000Z

    Using first-principles calculations, we propose a microscopic model to explain the reversible lithiation/delithiation of tin-oxide anodes in lithium-ion batteries. When the irreversible regime ends, the anode grains consist of layers of Li-oxide separated by Sn bilayers. During the following reversible lithiation, the Li-oxide undergoes two phase transformations that give rise to a Li-enrichment of the oxide and the formation of a SnLi composite. The anode grain structure stays layered and ordered with an effective theoretical reversible capacity of 4.5 Li per Sn atom. The predicted anode volume expansion and voltage profile agree well with experiments, contrary to existing models.

  1. Advances in lithium-ion batteries

    E-Print Network [OSTI]

    Kerr, John B.

    2003-01-01T23:59:59.000Z

    Advances in Lithium-Ion Batteries Edited by Walter A. vantolerance of these batteries this is a curious omission andmysteries of lithium ion batteries. The book begins with an

  2. Title Quantum Optics and Heavy Ion Physics

    E-Print Network [OSTI]

    Roy J. Glauber

    2006-04-10T23:59:59.000Z

    I shall try to say a few words about two particular ways in which my own work has a certain relation to your work with heavy ions. My title is therefore "Quantum Optics and Heavy Ion Physics".

  3. Laser ion source with solenoid field

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kanesue, Takeshi; Fuwa, Yasuhiro; Kondo, Kotaro; Okamura, Masahiro

    2014-11-10T23:59:59.000Z

    Pulse length extension of highly charged ion beam generated from a laser ion source is experimentally demonstrated. The laser ion source (LIS) has been recognized as one of the most powerful heavy ion source. However, it was difficult to provide long pulse beams. By applying a solenoid field (90 mT, 1 m) at plasma drifting section, a pulse length of carbon ion beam reached 3.2 ?s which was 4.4 times longer than the width from a conventional LIS. The particle number of carbon ions accelerated by a radio frequency quadrupole linear accelerator was 1.2 × 1011, which was provided bymore »a single 1 J Nd-YAG laser shot. A laser ion source with solenoid field could be used in a next generation heavy ion accelerator.« less

  4. Laser ion source with solenoid field

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kanesue, Takeshi [Brookhaven National Laboratory (BNL), Upton, NY (United States); Fuwa, Yasuhiro [Kyoto Univ., Kyoto (Japan); RIKEN, Saitama (Japan); Kondo, Kotaro [Tokyo Institute of Technology, Tokyo (Japan). Research Lab. for Nuclear Reactors; Okamura, Masahiro [Brookhaven National Laboratory (BNL), Upton, NY (United States)

    2014-11-10T23:59:59.000Z

    Pulse length extension of highly charged ion beam generated from a laser ion source is experimentally demonstrated. The laser ion source (LIS) has been recognized as one of the most powerful heavy ion source. However, it was difficult to provide long pulse beams. By applying a solenoid field (90 mT, 1 m) at plasma drifting section, a pulse length of carbon ion beam reached 3.2 ?s which was 4.4 times longer than the width from a conventional LIS. The particle number of carbon ions accelerated by a radio frequency quadrupole linear accelerator was 1.2 × 1011, which was provided by a single 1 J Nd-YAG laser shot. A laser ion source with solenoid field could be used in a next generation heavy ion accelerator.

  5. Laser ion source with solenoid field

    SciTech Connect (OSTI)

    Kanesue, Takeshi [Brookhaven National Laboratory (BNL), Upton, NY (United States); Fuwa, Yasuhiro [Kyoto Univ., Kyoto (Japan); RIKEN, Saitama (Japan); Kondo, Kotaro [Tokyo Institute of Technology, Tokyo (Japan). Research Lab. for Nuclear Reactors; Okamura, Masahiro [Brookhaven National Laboratory (BNL), Upton, NY (United States)

    2014-11-10T23:59:59.000Z

    Pulse length extension of highly charged ion beam generated from a laser ion source is experimentally demonstrated. The laser ion source (LIS) has been recognized as one of the most powerful heavy ion source. However, it was difficult to provide long pulse beams. By applying a solenoid field (90 mT, 1 m) at plasma drifting section, a pulse length of carbon ion beam reached 3.2 ?s which was 4.4 times longer than the width from a conventional LIS. The particle number of carbon ions accelerated by a radio frequency quadrupole linear accelerator was 1.2 × 1011, which was provided by a single 1 J Nd-YAG laser shot. A laser ion source with solenoid field could be used in a next generation heavy ion accelerator.

  6. The Electron Beam Ion Source (EBIS)

    ScienceCinema (OSTI)

    Brookhaven Lab

    2010-01-08T23:59:59.000Z

    Brookhaven National Lab has successfully developed a new pre-injector system, called the Electron Beam Ion Source, for the Relativistic Heavy Ion Collider (RHIC) and NASA Space Radiation Laboratory science programs. The first of several planned improvemen

  7. Side Reactions in Lithium-Ion Batteries

    E-Print Network [OSTI]

    Tang, Maureen Han-Mei

    2012-01-01T23:59:59.000Z

    Model for the Graphite Anode in Li-Ion Batteries. Journal ofgraphite Chapters 2-3 have developed a method using ferrocene to characterize the SEI in lithium- ion batteries.

  8. Heavy Ion Fusion Science Virtual National Laboratory

    E-Print Network [OSTI]

    line- of-sight damage from target debris, neutron and gamma radiation. · Target injection: Heavy ions-liquid-protected target chambers with 30 yr lifetimes. · Robust final optics: Focusing magnets for ion beams avoid direct

  9. Analysis of Interstitial Elements in Niobium with Secondary Ion Mass Spectrometry (SIMS)

    SciTech Connect (OSTI)

    Maheshwari, P.; Griffis, D. P. [Analytical Instrumentation Facility, North Carolina State University, Raleigh, NC 27607 (United States); Materials Science and Engineering, North Carolina State University, Raleigh, NC 27607 (United States); Stevie, F. A. [Analytical Instrumentation Facility, North Carolina State University, Raleigh, NC 27607 (United States); Myeneni, G.; Ciovati, G. [Jefferson Laboratory, Newport News, VA 23606 (United States); Rigsbee, J. M. [Materials Science and Engineering, North Carolina State University, Raleigh, NC 27607 (United States)

    2011-03-31T23:59:59.000Z

    Superconducting Radio Frequency (SRF) cavities provide enhanced efficiency and reduced energy utilization in present day particle accelerators. Niobium (Nb) is the material of choice for these cavities due to its high critical temperature and critical magnetic field. In order to understand why certain treatments, especially a low temperature bake, improve performance, it is important to study Nb surface characteristics and identify elemental contamination that can affect the performance of the cavity. H, C, O, and N are of interest because they are interstitial impurities in Nb. In earlier work, SIMS analysis using a CAMECA IMS-6F with Cs{sup +} primary beam showed that C and N were probably not significant factors impacting performance but there was a very high level of H in the Nb. Ion implants of C, N, O, and D into Nb provided quantification of C, N, O and indicated that D is very mobile in the Nb. Further analyses showed that heat treated Nb has lower levels of surface H than non heat treated Nb and subsequent removal of surface oxide by etching causes intake of H in a heat treated Nb sample. This result helps confirm the role of surface oxide as a hydrogen barrier. To further understand the oxide, Nb samples were anodized to obtain a thicker surface oxide and H and D were implanted into this oxide to check for the appearance of implant peaks. SIMS depth profile analyses were carried out and confirmed the presence of the implant shape for these elements in the oxide. Relative Sensitivity Factor (RSFs) could then be calculated for quantification of H in the oxide. Since the Nb matrix signal showed little change from the oxide to the substrate, the same RSF was used to estimate the H concentration in the Nb at 2x10{sup 22} atoms/cm{sup 3}(approximately 40% mole fraction H).

  10. Solution dewatering with concomitant ion removal

    DOE Patents [OSTI]

    Peterson, Eric S.; Marshall, Douglas W.; Stone, Mark L.

    2003-08-05T23:59:59.000Z

    One of the biggest needs in the separations and waste handling and reduction area is a method for dewatering ion-containing solutions. Unexpectedly, it has been found that phosphazene polymers can discriminate between water and metal ions, allowing water to pass through the membrane while retaining the ions. This unexpected result, along with the inherent chemical and thermal stability of the phosphazene polymers, yields a powerful tool for separating and dewatering metal-ion-containing solutions.

  11. Microbially-mediated method for synthesis of non-oxide semiconductor nanoparticles

    DOE Patents [OSTI]

    Phelps, Tommy J.; Lauf, Robert J.; Moon, Ji Won; Rondinone, Adam J.; Love, Lonnie J.; Duty, Chad Edward; Madden, Andrew Stephen; Li, Yiliang; Ivanov, Ilia N.; Rawn, Claudia Jeanette

    2014-06-24T23:59:59.000Z

    The invention is directed to a method for producing non-oxide semiconductor nanoparticles, the method comprising: (a) subjecting a combination of reaction components to conditions conducive to microbially-mediated formation of non-oxide semiconductor nanoparticles, wherein said combination of reaction components comprises i) anaerobic microbes, ii) a culture medium suitable for sustaining said anaerobic microbes, iii) a metal component comprising at least one type of metal ion, iv) a non-metal component containing at least one non-metal selected from the group consisting of S, Se, Te, and As, and v) one or more electron donors that provide donatable electrons to said anaerobic microbes during consumption of the electron donor by said anaerobic microbes; and (b) isolating said non-oxide semiconductor nanoparticles, which contain at least one of said metal ions and at least one of said non-metals. The invention is also directed to non-oxide semiconductor nanoparticle compositions produced as above and having distinctive properties.

  12. Thermal Stability of Li-Ion Cells

    SciTech Connect (OSTI)

    ROTH,EMANUEL P.

    1999-09-17T23:59:59.000Z

    The thermal stability of Li-ion cells with intercalating carbon anodes and metal oxide cathodes was measured as a function of state of charge and temperature for two advanced cell chemistries. Cells of the 18650 design with Li{sub x}CoO{sub 2} cathodes (commercial SONY cells) and Li{sub x}Ni{sub 0.8}Co{sub 0.2}O{sub 2} cathodes were measured for thermal reactivity in the open circuit cell condition. Accelerating rate calorimetry (ARC) was used to measure cell thermal runaway as a function of state of charge (SOC). Microcalorimetry was used to measure the time dependence of heat generating side reactions also as a function of SOC. Components of cells were measured using differential scanning calorimetry (DSC) to study the thermal reactivity of the individual electrodes to determine the temperature regimes and conditions of the major thermal reactions. Thermal decomposition of the SEI layer at the anodes was identified as the initiating source for thermal runaway. The cells with Li{sub x}CoO{sub 2} cathodes showed greater sensitivity to SOC and higher accelerating heating rates than seen for the cells with Li{sub x}Ni{sub 0.8}Co{sub 0.2}O{sub 2}cathodes. Lower temperature reactions starting as low as 40 C were also observed that were SOC dependent but not accelerating. These reactions were also measured in the microcalorimeter and observed to decay over time with a power-law dependence and are believed to result in irreversible capacity loss in the cells.

  13. The Heavy Ion Fusion Virtual National Laboratory The Heavy Ion Path to Fusion Energy

    E-Print Network [OSTI]

    , describes R&D needs for heavy-ion accelerator, target and chamber R&D. 44 pages. Defines goals and criteria tasks) - ion accelerator technologies - chamber and maintenance technologies - pulsed power technologiesThe Heavy Ion Fusion Virtual National Laboratory The Heavy Ion Path to Fusion Energy Grant Logan

  14. Hybrid deposition of thin film solid oxide fuel cells and electrolyzers

    DOE Patents [OSTI]

    Jankowski, A.F.; Makowiecki, D.M.; Rambach, G.D.; Randich, E.

    1998-05-19T23:59:59.000Z

    The use of vapor deposition techniques enables synthesis of the basic components of a solid oxide fuel cell (SOFC); namely, the electrolyte layer, the two electrodes, and the electrolyte-electrode interfaces. Such vapor deposition techniques provide solutions to each of the three critical steps of material synthesis to produce a thin film solid oxide fuel cell (TFSOFC). The electrolyte is formed by reactive deposition of essentially any ion conducting oxide, such as defect free, yttria stabilized zirconia (YSZ) by planar magnetron sputtering. The electrodes are formed from ceramic powders sputter coated with an appropriate metal and sintered to a porous compact. The electrolyte-electrode interface is formed by chemical vapor deposition of zirconia compounds onto the porous electrodes to provide a dense, smooth surface on which to continue the growth of the defect-free electrolyte, whereby a single fuel cell or multiple cells may be fabricated. 8 figs.

  15. Hybrid deposition of thin film solid oxide fuel cells and electrolyzers

    DOE Patents [OSTI]

    Jankowski, Alan F. (Livermore, CA); Makowiecki, Daniel M. (Livermore, CA); Rambach, Glenn D. (Livermore, CA); Randich, Erik (Endinboro, PA)

    1998-01-01T23:59:59.000Z

    The use of vapor deposition techniques enables synthesis of the basic components of a solid oxide fuel cell (SOFC); namely, the electrolyte layer, the two electrodes, and the electrolyte-electrode interfaces. Such vapor deposition techniques provide solutions to each of the three critical steps of material synthesis to produce a thin film solid oxide fuel cell (TFSOFC). The electrolyte is formed by reactive deposition of essentially any ion conducting oxide, such as defect free, yttria stabilized zirconia (YSZ) by planar magnetron sputtering. The electrodes are formed from ceramic powders sputter coated with an appropriate metal and sintered to a porous compact. The electrolyte-electrode interface is formed by chemical vapor deposition of zirconia compounds onto the porous electrodes to provide a dense, smooth surface on which to continue the growth of the defect-free electrolyte, whereby a single fuel cell or multiple cells may be fabricated.

  16. Hybrid deposition of thin film solid oxide fuel cells and electrolyzers

    DOE Patents [OSTI]

    Jankowski, Alan F. (Livermore, CA); Makowiecki, Daniel M. (Livermore, CA); Rambach, Glenn D. (Livermore, CA); Randich, Erik (Endinboro, PA)

    1999-01-01T23:59:59.000Z

    The use of vapor deposition techniques enables synthesis of the basic components of a solid oxide fuel cell (SOFC); namely, the electrolyte layer, the two electrodes, and the electrolyte-electrode interfaces. Such vapor deposition techniques provide solutions to each of the three critical steps of material synthesis to produce a thin film solid oxide fuel cell (TFSOFC). The electrolyte is formed by reactive deposition of essentially any ion conducting oxide, such as defect free, yttria stabilized zirconia (YSZ) by planar magnetron sputtering. The electrodes are formed from ceramic powders sputter coated with an appropriate metal and sintered to a porous compact. The electrolyte-electrode interface is formed by chemical vapor deposition of zirconia compounds onto the porous electrodes to provide a dense, smooth surface on which to continue the growth of the defect-free electrolyte, whereby a single fuel cell or multiple cells may be fabricated.

  17. Protective coating on positive lithium-metal-oxide electrodes for lithium batteries

    DOE Patents [OSTI]

    Johnson, Christopher S.; Thackeray, Michael M.; Kahaian, Arthur J.

    2006-05-23T23:59:59.000Z

    A positive electrode for a non-aqueous lithium cell comprising a LiMn2-xMxO4 spinel structure in which M is one or more metal cations with an atomic number less than 52, such that the average oxidation state of the manganese ions is equal to or greater than 3.5, and in which 0.ltoreq.x.ltoreq.0.15, having one or more lithium spine oxide LiM'2O4 or lithiated spinel oxide Li1+yM'2O4 compounds on the surface thereof in which M' are cobalt cations and in which 0.ltoreq.y.ltoreq.1.

  18. Inductively generated streaming plasma ion source

    DOE Patents [OSTI]

    Glidden, Steven C.; Sanders, Howard D.; Greenly, John B.

    2006-07-25T23:59:59.000Z

    A novel pulsed, neutralized ion beam source is provided. The source uses pulsed inductive breakdown of neutral gas, and magnetic acceleration and control of the resulting plasma, to form a beam. The beam supplies ions for applications requiring excellent control of ion species, low remittance, high current density, and spatial uniformity.

  19. Interaction of trapped ions with trapped atoms

    E-Print Network [OSTI]

    Grier, Andrew T. (Andrew Todd)

    2011-01-01T23:59:59.000Z

    In this thesis, I present results from two Paul-trap based ion traps carried out in the Vuleti? laboratory: the Atom-Ion trap for collision studies between cold atoms and cold ions, and the Cavity-Array trap for studying ...

  20. On the Design of Oxide Films, Nanomaterials, and Heterostructures for Solar Water Oxidation Photoanodes

    E-Print Network [OSTI]

    Kronawitter, Coleman

    2012-01-01T23:59:59.000Z

    lower oxides of titanium, 25 this energy gap, as defined inlies at greater energies than reference titanium oxides. Thetitanium oxides have been comprehensively documented. 25,26,27,28 The two sets of local maxima over this energy

  1. Berkeley Accelerator Space Effects (BASE) Light Ion Facility Upgrade

    E-Print Network [OSTI]

    Johnson, Michael B.; McMahan, Margaret A.; Gimpel, Thomas L.; Tiffany, William S.

    2006-01-01T23:59:59.000Z

    a position- sensitive ion chamber for online dosimetry, theBeam Exit Window The ion chamber (Fig. 3) monitors the beamthe nitrogen-filled ion chamber leave a trail of ions that

  2. Intense ion beam propagation in a reactor sized chamber

    E-Print Network [OSTI]

    Vay, J.L.; Deutsch, C.

    2000-01-01T23:59:59.000Z

    beams in a heavy ion fusion reactor chamber filled with lowIon Fusion, Intense Ion Beams, Reaction Chamber. P.A.C.S.heavy ion beam propagation in the reaction chamber, Fus.

  3. Isotopic Effect on Ion Mobility and Separation of Isotopomers...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Effect on Ion Mobility and Separation of Isotopomers by High-Field Ion Mobility Spectrometry . Isotopic Effect on Ion Mobility and Separation of Isotopomers by High-Field Ion...

  4. Landau damping of ion acoustic wave in Lorentzian multi-ion plasmas

    SciTech Connect (OSTI)

    Arshad, Kashif [National Center for Plasma Physics, Quaid-i-Azam University, Shadra Valley Road, Islamabad 44000 (Pakistan); Mahmood, S. [Theoretical Plasma Physics Division (TPPD), PINSTECH, P.O. Nilore, Islamabad 44000 (Pakistan); National Center for Plasma Physics, Quaid-i-Azam University, Shadra Valley Road, Islamabad 44000 (Pakistan); Mirza, Arshad M. [Department of Physics, Theoretical Plasma Physics Group, Quaid-i-Azam University, Islamabad 45320 (Pakistan)

    2011-09-15T23:59:59.000Z

    The Landau damping rates of ion acoustic wave are studied by using Vlasov-Poisson model for unmagnetized Lorentzian or kappa distributed plasma containing electrons, positively and negatively charged ions. It is found that the damping rate of ion acoustic wave is increased with the decrease of kappa (i.e., the spectral index of Lorentzian distribution) value. The damping rates of the electrostatic wave in multi-ion component plasmas are discussed in detail which depends on electron to ion temperature ratio and ions masses and density ratios. The numerical results are also shown by choosing some typical experimental parameters of multi-ion plasmas.

  5. Electric Potential Near The Extraction Region In Negative Ion Sources With Surface Produced Negative Ions

    SciTech Connect (OSTI)

    Fukano, A. [Monozukuri Department, Tokyo Metropolitan College of Industrial Technology, 1-10-40 Higashi-Ohi, Shinagawa-ku, Tokyo 140-0011 (Japan); Hatayama, A. [Graduate School of Science and Technology, Keio University, 3-14-1 Hiyoshi, Kouhoku-ku, Yokohama 223-8522 (Japan)

    2011-09-26T23:59:59.000Z

    The potential distribution near the extraction region in negative ion sources for the plasma with the surface produced negative ions is studied analytically. The potential is derived analytically by using a plasma-sheath equation, where negative ions produced on the Plasma Grid (PG) surface are considered in addition to positive ions and electrons. A negative potential peak is formed in the sheath region near the PG surface for the case of strong surface production of negative ions or for low energy negative ions. Negative ions are reflected by the negative potential peak near the PG and returned to the PG surface. This reflection mechanism by the negative potential peak possibly becomes a factor in negative ion extraction. It is also indicated that the potential difference between the plasma region and the wall decreases by the surface produced negative ions. This also has the possibility to contribute to the negative ion extraction.

  6. Study on space charge effect in an electrostatic ion analyzer applied to measure laser produced ions

    SciTech Connect (OSTI)

    Jin, Q. Y.; Li, Zh. M.; Liu, W. [Institute of Modern Physics, Chinese Academy of Sciences, Lanzhou 730000 (China) [Institute of Modern Physics, Chinese Academy of Sciences, Lanzhou 730000 (China); University of Chinese Academy of Sciences, Beijing 100049 (China); Zhao, H. Y., E-mail: zhaohy@impcas.ac.cn; Sha, S.; Zhang, J. J.; Zhang, X. Zh.; Sun, L. T.; Zhao, H. W. [Institute of Modern Physics, Chinese Academy of Sciences, Lanzhou 730000 (China)] [Institute of Modern Physics, Chinese Academy of Sciences, Lanzhou 730000 (China)

    2014-03-15T23:59:59.000Z

    The abundance of different ions produced by laser ion sources is usually analyzed by an electrostatic ion analyzer (EIA). Ion current intensities in the range of several mA/cm{sup 2} at the position of the EIA have been achieved from the laser ion source developed by the Institute of Modern Physics; this indicates that a noticeable influence of space charge effect during the ion transmission will occur. Hence, while the parameters of the EIA or the beams are changed, such as ion species, current intensity, the ions’ transmission efficiency through the EIA is different, which will result in an uncertainty in the estimation of the ions’ yields. Special attention is focused on this issue in this paper. Ion's transmissions through the EIA under different circumstances are studied with simulations and experiments, the results of which are consistent with each other.

  7. Distribution of ion current density on a rotating spherical cap substrate during ion-assisted deposition

    SciTech Connect (OSTI)

    Marushka, Viktor; Zabeida, Oleg, E-mail: oleg.zabeida@polymtl.ca; Martinu, Ludvik [Engineering Physics Department, Polytechnique Montréal, P.O. Box 6079, Downtown station, Montreal, Quebec H3C 3A7 (Canada)

    2014-11-01T23:59:59.000Z

    The uniformity of ion density is critical for applications relying on the ion assisted deposition technique for the fabrication of the high quality thin films. The authors propose and describe here a method allowing one to calculate the ion density distribution on spherical substrate holders under stationary and rotating conditions for different positions of the ion source. The ion beam shape was approximated by a cos{sup n} function, and the ion current density was represented by a function inversely proportional to the distance from the ion source in accordance with our experimental results. As an example, a calculation of the current density distribution on the spherical cap substrate was performed for a broad beam ion source operated with an anode current of 3?A. The authors propose an approach for process optimization with respect to the ion source position and its inclination, in terms of uniformity and absolute value of the ion current density.

  8. Solid oxide electrochemical reactor science.

    SciTech Connect (OSTI)

    Sullivan, Neal P. (Colorado School of Mines, Golden, CO); Stechel, Ellen Beth; Moyer, Connor J. (Colorado School of Mines, Golden, CO); Ambrosini, Andrea; Key, Robert J. (Colorado School of Mines, Golden, CO)

    2010-09-01T23:59:59.000Z

    Solid-oxide electrochemical cells are an exciting new technology. Development of solid-oxide cells (SOCs) has advanced considerable in recent years and continues to progress rapidly. This thesis studies several aspects of SOCs and contributes useful information to their continued development. This LDRD involved a collaboration between Sandia and the Colorado School of Mines (CSM) ins solid-oxide electrochemical reactors targeted at solid oxide electrolyzer cells (SOEC), which are the reverse of solid-oxide fuel cells (SOFC). SOECs complement Sandia's efforts in thermochemical production of alternative fuels. An SOEC technology would co-electrolyze carbon dioxide (CO{sub 2}) with steam at temperatures around 800 C to form synthesis gas (H{sub 2} and CO), which forms the building blocks for a petrochemical substitutes that can be used to power vehicles or in distributed energy platforms. The effort described here concentrates on research concerning catalytic chemistry, charge-transfer chemistry, and optimal cell-architecture. technical scope included computational modeling, materials development, and experimental evaluation. The project engaged the Colorado Fuel Cell Center at CSM through the support of a graduate student (Connor Moyer) at CSM and his advisors (Profs. Robert Kee and Neal Sullivan) in collaboration with Sandia.

  9. Nanostructuring superconductors by ion beams: A path towards materials engineering

    SciTech Connect (OSTI)

    Gerbaldo, Roberto; Ghigo, Gianluca; Gozzelino, Laura; Laviano, Francesco [Department of Applied Science and Technology, Politecnico di Torino c.so Duca degli Abruzzi 24, 10129 Torino, Italy and INFN Sez. Torino, via P. Giuria 1, 10125 Torino (Italy); Amato, Antonino; Rovelli, Alberto [INFN Laboratori Nazionali del Sud, via S. Sofia 62, 95125 Catania (Italy); Cherubini, Roberto [INFN Laboratori Nazionali di Legnaro, viale dell'Universita 2, 35020 Legnaro (Italy)

    2013-07-18T23:59:59.000Z

    The paper deals with nanostructuring of superconducting materials by means of swift heavy ion beams. The aim is to modify their structural, optical and electromagnetic properties in a controlled way, to provide possibility of making them functional for specific applications. Results are presented concerning flux pinning effects (implantation of columnar defects with nanosize cross section to enhance critical currents and irreversibility fields), confined flux-flow and vortex guidance, design of devices by locally tailoring the superconducting material properties, analysis of disorder-induced effects in multi-band superconductors. These studies were carried out on different kinds of superconducting samples, from single crystals to thin films, from superconducting oxides to magnesium diboride, to recently discovered iron-based superconductors.

  10. Method for hot pressing beryllium oxide articles

    DOE Patents [OSTI]

    Ballard, Ambrose H. (Oak Ridge, TN); Godfrey, Jr., Thomas G. (Oak Ridge, TN); Mowery, Erb H. (Clinton, TN)

    1988-01-01T23:59:59.000Z

    The hot pressing of beryllium oxide powder into high density compacts with little or no density gradients is achieved by employing a homogeneous blend of beryllium oxide powder with a lithium oxide sintering agent. The lithium oxide sintering agent is uniformly dispersed throughout the beryllium oxide powder by mixing lithium hydroxide in an aqueous solution with beryllium oxide powder. The lithium hydroxide is converted in situ to lithium carbonate by contacting or flooding the beryllium oxide-lithium hydroxide blend with a stream of carbon dioxide. The lithium carbonate is converted to lithium oxide while remaining fixed to the beryllium oxide particles during the hot pressing step to assure uniform density throughout the compact.

  11. High Current Ion Source Development for Heavy Ion Fusion

    SciTech Connect (OSTI)

    Westenskow, G A; Grote, D P; Kwan, J W

    2003-09-04T23:59:59.000Z

    We are developing high-current-density high-brightness sources for Heavy Ion Fusion applications. Heavy ion driven inertial fusion requires beams of high brightness in order to achieve high power density at the target for high target gain. At present, there are no existing ion source types that can readily meet all the driver HIF requirements, though sources exist which are adequate for present experiments and which with further development may achieve driver requirements. Our two major efforts have been on alumino-silicate sources and RF plasma sources. Experiments being performed on a 10-cm alumino-silicate source are described. To obtain a compact system for a HIF driver we are studying RF plasma sources where low current beamlets are combined to produce a high current beam. A 80-kV 20-{micro}s source has produced up to 5 mA of Ar{sup +} in a single beamlet. The extraction current density was 100 mA/cm{sup 2}. We present measurements of the extracted current density as a function of RF power and gas pressure, current density uniformity, emittance, and energy dispersion (due to charge exchange).

  12. Argon-ion-induced formation of nanoporous GaSb layer: Microstructure, infrared luminescence, and vibrational properties

    SciTech Connect (OSTI)

    Datta, D. P.; Som, T., E-mail: tsom@iopb.res.in [SUNAG Laboratory, Institute of Physics, Bhubaneswar, Odisha 751 005 (India); Kanjilal, A. [Department of Physics, Shiv Nadar University, Uttar Pradesh 201 314 (India); Satpati, B. [Surface Physics and Material Science Division, Saha Institute of Nuclear Physics, 1/AF Bidhannagar, Kolkata 700 064 (India); Dhara, S. [Surface and Nanoscience Division, Materials Science Group, Indira Gandhi Centre for Atomic Research, Kalpakkam 603 102 (India); Das, T. D. [Department of Electronic Science, University of Calcutta, APC Road, Kolkata 700 009 (India); Kanjilal, D. [Inter-University Accelerator Centre, Aruna Asaf Ali Marg, New Delhi 110 067 (India)

    2014-07-21T23:59:59.000Z

    Room temperature implantation of 60?keV Ar{sup +}-ions in GaSb to the fluences of 7?×?10{sup 16} to 3?×?10{sup 18} ions cm{sup ?2} is carried out at two incidence angles, viz 0° and 60°, leading to formation of a nanoporous layer. As the ion fluence increases, patches grow on the porous layer under normal ion implantation, whereas the porous layer gradually becomes embedded under a rough top surface for oblique incidence of ions. Grazing incidence x-ray diffraction and cross-sectional transmission electron microscopy studies reveal the existence of nanocrystallites embedded in the ion-beam amorphized GaSb matrix up to the highest fluence used in our experiment. Oxidation of the nanoporous layers becomes obvious from x-ray photoelectron spectroscopy and Raman mapping. The correlation of ion-beam induced structural modification with photoluminescence signals in the infrared region has further been studied, showing defect induced emission of additional peaks near the band edge of GaSb.

  13. Oxidation reactions on neutral cobalt oxide clusters: experimental and theoretical studies

    E-Print Network [OSTI]

    Rocca, Jorge J.

    oxidation,24­41 nitrogen monoxide reduction and oxidation,24,36a,42­44 and Fischer­Tropsch reactions.45

  14. Latent ion tracks in amorphous silicon

    SciTech Connect (OSTI)

    Bierschenk, Thomas [Australian National University, Canberra, Australia] [Australian National University, Canberra, Australia; Giulian, Raquel [Australian National University, Canberra, Australia] [Australian National University, Canberra, Australia; Afra, Boshra [Australian National University, Canberra, Australia] [Australian National University, Canberra, Australia; Rodriguez, Matias D [Australian National University, Canberra, Australia] [Australian National University, Canberra, Australia; Schauries, D [Australian National University, Canberra, Australia] [Australian National University, Canberra, Australia; Mudie, Stephen [Australian Synchrotron] [Australian Synchrotron; Pakarinen, Olli H [ORNL] [ORNL; Djurabekova, Flyura [University of Helsinki] [University of Helsinki; Nordlund, Kai [University of Helsinki] [University of Helsinki; Osmani, Orkhan [University of Duisburg-Essen, Germany] [University of Duisburg-Essen, Germany; Medvedev, Nikita [University of Kaiserslautern, Germany] [University of Kaiserslautern, Germany; Rethfield, Baerbel [University of Kaiserslautern, Germany] [University of Kaiserslautern, Germany; Ridgway, Mark C [Australian National University, Canberra, Australia] [Australian National University, Canberra, Australia; Kluth, Patrick [Australian National University, Canberra, Australia] [Australian National University, Canberra, Australia

    2013-01-01T23:59:59.000Z

    We present experimental evidence for the formation of ion tracks in amorphous Si induced by swift heavy ion irradiation. An underlying core-shell structure consistent with remnants of a high density liquid structure was revealed by small-angle x-ray scattering and molecular dynamics simulations. Ion track dimensions dier for as-implanted and relaxed Si as attributed to dierent microstructures and melting temperatures. The identication and characterisation of ion tracks in amorphous Si yields new insight into mechanisms of damage formation due to swift heavy ion irradiation in amorphous semiconductors.

  15. Influence of Ionic Surfactants on the Aggregation of Poly(Ethylene Oxide)-Poly(Propylene Oxide)-Poly(Ethylene Oxide) Block Copolymers Studied by Differential Scanning and

    E-Print Network [OSTI]

    Loh, Watson

    Influence of Ionic Surfactants on the Aggregation of Poly(Ethylene Oxide)-Poly(Propylene Oxide copolymers of poly(ethylene oxide) and poly(propylene oxide), EOnPOmEOn, and the ionic surfactants sodium the aggregates of all three polymers. Introduction Water-soluble poly(ethylene oxide)-poly(propylene oxide)- poly

  16. Using CrAIN Multilayer Coatings to Improve Oxidation Resistance...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Coatings to Improve Oxidation Resistance of Steel Interconnects for Solid Oxide Fuel Cell Stacks. Using CrAIN Multilayer Coatings to Improve Oxidation Resistance of Steel...

  17. MICROSTRUCTURE-PROPERTY RELATIONSHIPS OF A ZINC OXIDE VARISTOR MATERIAL

    E-Print Network [OSTI]

    Williama, Pamela Louise

    2011-01-01T23:59:59.000Z

    RELATIONSHIPS OF A ZINC OXIDE VARISTOR MATERIAL Pamelaresistors, and zinc oxide varistors are semiconductorRELATIONSHIPS OF A ZINC OXIDE VARISTOR MATERIAL CONTENTS

  18. Effects of Tungsten Oxide Addition on the Electrochemical Performance...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Tungsten Oxide Addition on the Electrochemical Performance of Nanoscale Tantalum Oxide-Based Electrocatalysts for Effects of Tungsten Oxide Addition on the Electrochemical...

  19. Focused electron and ion beam systems

    DOE Patents [OSTI]

    Leung, Ka-Ngo; Reijonen, Jani; Persaud, Arun; Ji, Qing; Jiang, Ximan

    2004-07-27T23:59:59.000Z

    An electron beam system is based on a plasma generator in a plasma ion source with an accelerator column. The electrons are extracted from a plasma cathode in a plasma ion source, e.g. a multicusp plasma ion source. The beam can be scanned in both the x and y directions, and the system can be operated with multiple beamlets. A compact focused ion or electron beam system has a plasma ion source and an all-electrostatic beam acceleration and focusing column. The ion source is a small chamber with the plasma produced by radio-frequency (RF) induction discharge. The RF antenna is wound outside the chamber and connected to an RF supply. Ions or electrons can be extracted from the source. A multi-beam system has several sources of different species and an electron beam source.

  20. PRTR ion exchange vault column sampling

    SciTech Connect (OSTI)

    Cornwell, B.C.

    1995-03-14T23:59:59.000Z

    This report documents ion exchange column sampling and Non Destructive Assay (NDA) results from activities in 1994, for the Plutonium Recycle Test Reactor (PRTR) ion exchange vault. The objective was to obtain sufficient information to prepare disposal documentation for the ion exchange columns found in the PRTR Ion exchange vault. This activity also allowed for the monitoring of the liquid level in the lower vault. The sampling activity contained five separate activities: (1) Sampling an ion exchange column and analyzing the ion exchange media for purpose of waste disposal; (2) Gamma and neutron NDA testing on ion exchange columns located in the upper vault; (3) Lower vault liquid level measurement; (4) Radiological survey of the upper vault; and (5) Secure the vault pending waste disposal.

  1. The ion pairs and superconducting bosons

    E-Print Network [OSTI]

    V. N. Minasyan

    2009-02-11T23:59:59.000Z

    First, it is shown that the creation of the spinless ion pairs in the lattice, which are hold by the binding with neighbor ion pairs together regarded as covalent. These ion pairs are created by the repulsive potential interaction of two ions which is bound as linear oscillator. The repulsive S-wave scattering between ion pairs and electrons is transformed to the attractive effective interaction between electrons which leads to a creation of electron pairs by a binding energy depending on the condensate fraction of ion pairs $\\frac{N_0}{N}$. In this respect, the absence of ion pairs in the condensate destroys a binding energy of electron pairs and in turn so-called superconductimg phase. As new result presented theory is that the number of the superconducting bosons is not changed in the superconducting phase.

  2. Solid oxide fuel cell generator

    DOE Patents [OSTI]

    Draper, R.; George, R.A.; Shockling, L.A.

    1993-04-06T23:59:59.000Z

    A solid oxide fuel cell generator has a pair of spaced apart tubesheets in a housing. At least two intermediate barrier walls are between the tubesheets and define a generator chamber between two intermediate buffer chambers. An array of fuel cells have tubes with open ends engaging the tubesheets. Tubular, axially elongated electrochemical cells are supported on the tubes in the generator chamber. Fuel gas and oxidant gas are preheated in the intermediate chambers by the gases flowing on the other side of the tubes. Gas leakage around the tubes through the tubesheets is permitted. The buffer chambers reentrain the leaked fuel gas for reintroduction to the generator chamber.

  3. Solid oxide fuel cell generator

    DOE Patents [OSTI]

    Draper, Robert (Churchill Boro, PA); George, Raymond A. (Pittsburgh, PA); Shockling, Larry A. (Plum Borough, PA)

    1993-01-01T23:59:59.000Z

    A solid oxide fuel cell generator has a pair of spaced apart tubesheets in a housing. At least two intermediate barrier walls are between the tubesheets and define a generator chamber between two intermediate buffer chambers. An array of fuel cells have tubes with open ends engaging the tubesheets. Tubular, axially elongated electrochemical cells are supported on the tubes in the generator chamber. Fuel gas and oxidant gas are preheated in the intermediate chambers by the gases flowing on the other side of the tubes. Gas leakage around the tubes through the tubesheets is permitted. The buffer chambers reentrain the leaked fuel gas for reintroduction to the generator chamber.

  4. Aromatic-radical oxidation chemistry

    SciTech Connect (OSTI)

    Glassman, I.; Brezinsky, K. [Princeton Univ., NJ (United States)

    1993-12-01T23:59:59.000Z

    The research effort has focussed on discovering an explanation for the anomalously high CO{sub 2} concentrations observed early in the reaction sequence of the oxidation of cyclopentadiene. To explain this observation, a number of plausible mechanisms have been developed which now await experimental verification. One experimental technique for verifying mechanisms is to probe the reacting system by perturbing the radical concentrations. Two forms of chemical perturbation of the oxidation of cyclopentadiene were begun during this past year--the addition of NO{sub 2} and CO to the reacting mixture.

  5. The rheology of oxide dispersions and the role of concentrated electrolyte solutions

    SciTech Connect (OSTI)

    Biggs, Simon; Tindley, Amy [Leeds University/Nexis Solutions URA in Particle Science and Technology, Institute of Particle Science and Engineering, School of Process, Environmental and Materials Engineering, The University of Leeds, Leeds LS2 9JT (United Kingdom)

    2007-07-01T23:59:59.000Z

    Stability control of particulate dispersions is critical to a wide range of industrial processes. In the UK nuclear industry, significant volumes of waste materials arising from the corrosion products of Magnox fuel rods currently require treatment and storage. The majority of this waste is present as aqueous dispersions of oxide particulates. Treatment of these dispersions will require a variety of unit operations including mobilisation, transport and solid- liquid separation. Typically these processes must operate across a narrow optimal range of pH and the dispersions are, almost without exception, found in complex electrolyte conditions of high overall concentration. Knowledge of the behaviour of oxides in various electrolyte conditions and over a large pH range is essential for the efficient design and control of any waste processing approach. The transport properties of particle dispersions are characterised by the rheological properties. It is well known that particle dispersion rheology is strongly influenced by particle-particle interaction forces, and that particle-particle interactions are strongly influenced by adsorbed ions on the particle surfaces. Here we correlate measurements of the shear yield stress and the particle zeta potentials to provide insight as to the role of ions in moderating particle interactions. The zeta potential of model TiO{sub 2} suspensions were determined (Colloidal Dynamics Zeta Probe) over a range of pH for a series of alkali metal halides and quaternary ammonium halides at a range of solution concentrations (0.001 M - 1 M). The results show some surprising co-ion effects at high electrolyte concentrations (>0.5 M) and indicate that even ions generally considered to be indifferent induce a shift in iso-electric point (i.e.p.) which is inferred as being due to specific adsorption of ions. The shear yield stress values of concentrated titania dispersions were measured using a Bohlin C-VOR stress controlled rheometer. The shear yield stress of a material is defined as the minimum applied shear stress required to induce flow. The yield stress vs. pH curves obtained reflected the shifts in i.e.p. seen in the zeta potential results. Interestingly, specific ion adsorption results in an unexplained increase in the value of the yield stress over that expected for simple systems with no such interfacial ion adsorption. Possible reasons for this effect such as ion-ion correlation effects are discussed. The importance of this increased attraction for the mobilisation of settled solids in an aqueous environment and especially the likely effects on the treatment of Magnox fuel waste materials is discussed. (authors)

  6. Cooling Techniques for Trapped Ions

    E-Print Network [OSTI]

    Daniel M. Segal; Christof Wunderlich

    2014-09-24T23:59:59.000Z

    This book chapter gives an introduction to, and an overview of, methods for cooling trapped ions. The main addressees are researchers entering the field. It is not intended as a comprehensive survey and historical account of the extensive literature on this topic. We present the physical ideas behind several cooling schemes, outline their mathematical description, and point to relevant literature useful for a more in-depth study of this topic.

  7. Electrolytes for lithium ion batteries

    DOE Patents [OSTI]

    Vaughey, John; Jansen, Andrew N.; Dees, Dennis W.

    2014-08-05T23:59:59.000Z

    A family of electrolytes for use in a lithium ion battery. The genus of electrolytes includes ketone-based solvents, such as, 2,4-dimethyl-3-pentanone; 3,3-dimethyl 2-butanone(pinacolone) and 2-butanone. These solvents can be used in combination with non-Lewis Acid salts, such as Li.sub.2[B.sub.12F.sub.12] and LiBOB.

  8. Hydrous metal oxide catalysts for oxidation of hydrocarbons

    SciTech Connect (OSTI)

    Miller, J.E.; Dosch, R.G.; McLaughlin, L.I. [Sandia National Labs., Albuquerque, NM (United States). Process Research Dept.

    1993-07-01T23:59:59.000Z

    This report describes work performed at Sandia under a CRADA with Shell Development of Houston, Texas aimed at developing hydrous metal oxide (HMO) catalysts for oxidation of hydrocarbons. Autoxidation as well as selective oxidation of 1-octene was studied in the presence of HMO catalysts based on known oxidation catalysts. The desired reactions were the conversion of olefin to epoxides, alcohols, and ketones, HMOs seem to inhibit autoxidation reactions, perhaps by reacting with peroxides or radicals. Attempts to use HMOs and metal loaded HMOs as epoxidation catalysts were unsuccessful, although their utility for this reaction was not entirely ruled out. Likewise, alcohol formation from olefins in the presence of HMO catalysts was not achieved. However, this work led to the discovery that acidified HMOs can lead to carbocation reactions of hydrocarbons such as cracking. An HMO catalyst containing Rh and Cu that promotes the reaction of {alpha}-olefins with oxygen to form methyl ketones was identified. Although the activity of the catalyst is relatively low and isomerization reactions of the olefin simultaneously occur, results indicate that these problems may be addressed by eliminating mass transfer limitations. Other suggestions for improving the catalyst are also made. 57 refs.

  9. Development of Pillared M(IV) Phosphate Phosphonate Inorganic Organic Hybrid Ion Exchange Materials for Applications in Separations found in the Nuclear Fuel Cycle 

    E-Print Network [OSTI]

    Burns, Jonathan

    2012-10-02T23:59:59.000Z

    ..................................................................................................... 105 5.5.1 Basic sorption .............................................................................. 105 5.5.2 Plutonium redox .......................................................................... 107 5.5.3 Americium oxidation....1. ................................ 104 xiii FIGURE Page 32 Schematic of the ion exchange equilibrium for the M(IV) hybrids. ............................................................................................. 106 33 Latimer diagram for plutonium in 1 M perchloric...

  10. Potentiometric Sensor for Real-Time Monitoring of Multivalent Ion Concentrations in Molten Salt

    SciTech Connect (OSTI)

    Peter A. Zink; Jan-Fong Jue; Brenda E. Serrano; Guy L. Fredrickson; Ben F. Cowan; Steven D. Herrmann; Shelly X. Li

    2010-07-01T23:59:59.000Z

    Electrorefining of spent metallic nuclear fuel in high temperature molten salt systems is a core technology in pyroprocessing, which in turn plays a critical role in the development of advanced fuel cycle technologies. In electrorefining, spent nuclear fuel is treated electrochemically in order to effect separations between uranium, noble metals, and active metals, which include the transuranics. The accumulation of active metals in a lithium chloride-potassium chloride (LiCl-KCl) eutectic molten salt electrolyte occurs at the expense of the UCl3-oxidant concentration in the electrolyte, which must be periodically replenished. Our interests lie with the accumulation of active metals in the molten salt electrolyte. The real-time monitoring of actinide concentrations in the molten salt electrolyte is highly desirable for controlling electrochemical operations and assuring materials control and accountancy. However, real-time monitoring is not possible with current methods for sampling and chemical analysis. A new solid-state electrochemical sensor is being developed for real-time monitoring of actinide ion concentrations in a molten salt electrorefiner. The ultimate function of the sensor is to monitor plutonium concentrations during electrorefining operations, but in this work gadolinium was employed as a surrogate material for plutonium. In a parametric study, polycrystalline sodium beta double-prime alumina (Na-ß?-alumina) discs and tubes were subject to vapor-phase exchange with gadolinium ions (Gd3+) using a gadolinium chloride salt (GdCl3) as a precursor to produce gadolinium beta double-prime alumina (Gd-ß?-alumina) samples. Electrochemical impedance spectroscopy and microstructural analysis were performed on the ion-exchanged discs to determine the relationship between ion exchange and Gd3+ ion conductivity. The ion-exchanged tubes were configured as potentiometric sensors in order to monitor real-time Gd3+ ion concentrations in mixtures of gadolinium chloride (GdCl3) in LiCl-KCl eutectic molten salts through measurement of the potential difference between a reference and working electrode.

  11. Dual and Triple Ion-Beam Irradiations of Fe, Fe(Cr) and Fe(Cr)-ODS Final Report: IAEA SMoRE CRP

    SciTech Connect (OSTI)

    Fluss, M J; Hsiung, L L; Marian, J

    2011-11-20T23:59:59.000Z

    Structures of nanoparticles in Fe-16Cr-4.5Al-0.3Ti-2W-0.37Y2O3 (K3) and Fe-20Cr-4.5Al-0.34Ti-0.5Y2O3 (MA956) oxide dispersion strengthened (ODS) ferritic steels produced by mechanical alloying (MA) and followed by hot extrusion have been studied using high-resolution transmission electron microscopy (HRTEM) techniques to gain insight about the formation mechanism of nanoparticles in MA/ODS steels. The observations of Y-Al-O complex-oxide nanoparticles in both ODS steels imply that decomposition of Y2O3 in association with internal oxidation of Al occurred during mechanical alloying. While the majority of oxide nanoparticles formed in both steels is Y4Al2O9, a few oxide particles of YAlO3 are also occasionally observed. These results reveal that Ti (0.3 wt %) plays an insignificant role in forming oxide nanoparticles in the presence of Al (4.5 wt %). HRTEM observations of crystalline nanoparticles larger than {approx}2 nm and amorphous or disordered cluster domains smaller than {approx}2 nm provide an insight into the formation mechanism of oxide nanoparticle in MA/ODS steels, which we believe from our observations involves a solid-state amorphous precursor followed by recrystallization. Dual ion-beam irradiations using He{sup +} + Fe{sup +8} ions were employed to gain more detailed insight about the role of nanoparticles in suppressing radiation-induced swelling. This is elaborated through TEM examinations of cavity distributions in ion-irradiated Fe-14Cr and K3-ODS ferritic steels. HRTEM observations of helium-filled cavities (helium bubbles) preferably trapped at nanoscale oxide particles and clusters in ion-irradiated K3-ODS are presented. Finally, we describe the results from triple ion-beam irradiations using H{sup +} + He{sup +} + Fe{sup +8} ions to emulate fusion first wall radiation effects. Preliminary work is reported that confirms the existence of significant hydrogen synergistic effects described earlier by Tanaka et al., for Fe(Cr) and by Wakai et al., for F82H reduced activation ferritic martensitic (RAF/M) steel. These previous results combined with our data suggest a complex new 'catalytic' mechanism whereby H interacts with the steady state population of defects and the embryonic cavities so as to accelerated cavity (void) growth in both Fe(Cr) and under special conditions in ODS steels.

  12. Genomic consequences of DNA oxidation by peroxynitrite

    E-Print Network [OSTI]

    Neeley, William Louis

    2006-01-01T23:59:59.000Z

    The radicals nitric oxide and superoxide are produced endogenously by activated macrophages and neutrophils and combine in a diffusion-limited reaction to form peroxynitrite, a powerful oxidizing and nitrating agent capable ...

  13. Solid Oxide Fuel Cell Manufacturing Overview

    E-Print Network [OSTI]

    Solid Oxide Fuel Cell Manufacturing Overview Hydrogen and Fuel Cell Technologies Manufacturing R Reserved. 3 The Solid Oxide Fuel Cell Electrochemistry #12;Copyright © 2011 Versa Power Systems. All Rights

  14. NANO - "Green" metal oxides ... | ornl.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    "Green" metal oxides ... Water and nano-sized particles isolated from trees, plants and algae are the ingredients of a new recipe for low-cost metal oxides that are widely used in...

  15. Complex oxides useful for thermoelectric energy conversion

    DOE Patents [OSTI]

    Majumdar, Arunava (Orinda, CA); Ramesh, Ramamoorthy (Moraga, CA); Yu, Choongho (College Station, TX); Scullin, Matthew L. (Berkeley, CA); Huijben, Mark (Enschede, NL)

    2012-07-17T23:59:59.000Z

    The invention provides for a thermoelectric system comprising a substrate comprising a first complex oxide, wherein the substrate is optionally embedded with a second complex oxide. The thermoelectric system can be used for thermoelectric power generation or thermoelectric cooling.

  16. Perovskite catalysts for oxidative coupling

    DOE Patents [OSTI]

    Campbell, Kenneth D. (Charleston, WV)

    1991-01-01T23:59:59.000Z

    Perovskites of the structure A.sub.2 B.sub.2 C.sub.3 O.sub.10 are useful as catalysts for the oxidative coupling of lower alkane to heavier hydrocarbons. A is alkali metal; B is lanthanide or lanthanum, cerium, neodymium, samarium, praseodymium, gadolinium or dysprosium; and C is titanium.

  17. Perovskite catalysts for oxidative coupling

    DOE Patents [OSTI]

    Campbell, K.D.

    1991-06-25T23:59:59.000Z

    Perovskites of the structure A[sub 2]B[sub 2]C[sub 3]O[sub 10] are useful as catalysts for the oxidative coupling of lower alkane to heavier hydrocarbons. A is alkali metal; B is lanthanide or lanthanum, cerium, neodymium, samarium, praseodymium, gadolinium or dysprosium; and C is titanium.

  18. Solid oxide fuel cell generator

    DOE Patents [OSTI]

    Di Croce, A. Michael (Murrysville, PA); Draper, Robert (Churchill Boro, PA)

    1993-11-02T23:59:59.000Z

    A solid oxide fuel cell generator has a plenum containing at least two rows of spaced apart, annular, axially elongated fuel cells. An electrical conductor extending between adjacent rows of fuel cells connects the fuel cells of one row in parallel with each other and in series with the fuel cells of the adjacent row.

  19. Solid oxide fuel cell generator

    DOE Patents [OSTI]

    Di Croce, A.M.; Draper, R.

    1993-11-02T23:59:59.000Z

    A solid oxide fuel cell generator has a plenum containing at least two rows of spaced apart, annular, axially elongated fuel cells. An electrical conductor extending between adjacent rows of fuel cells connects the fuel cells of one row in parallel with each other and in series with the fuel cells of the adjacent row. 5 figures.

  20. Formulations for iron oxides dissolution

    DOE Patents [OSTI]

    Horwitz, Earl P. (Argonne, IL); Chiarizia, Renato (Argonne, IL)

    1992-01-01T23:59:59.000Z

    A mixture of a di- or polyphosphonic acid and a reductant wherein each is present in a sufficient amount to provide a synergistic effect with respect to the dissolution of metal oxides and optionally containing corrosion inhibitors and pH adjusting agents.