National Library of Energy BETA

Sample records for ionic-electronic conductivity miec

  1. AP-XPS Measures MIEC Oxides in Action

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AP-XPS Measures MIEC Oxides in Action Print Oxide materials with mixed ionic-electronic conductivity (MIEC) can conduct both electrons and oxygen ions. MIEC oxides have broad...

  2. AP-XPS Measures MIEC Oxides in Action

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Measures MIEC Oxides in Action Print Wednesday, 25 May 2011 00:00 Oxide materials with mixed ionic-electronic conductivity (MIEC) can conduct both electrons and oxygen ions....

  3. AP-XPS Measures MIEC Oxides in Action

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AP-XPS Measures MIEC Oxides in Action AP-XPS Measures MIEC Oxides in Action Print Wednesday, 25 May 2011 00:00 Oxide materials with mixed ionic-electronic conductivity (MIEC) can conduct both electrons and oxygen ions. MIEC oxides have broad applications, including use in solid-oxide fuel cells, high-temperature electrolysis for synthetic fuel production, and oxygen-separating membranes for chemical processes or NOx-free combustion; however, their surface activity under reaction conditions has

  4. AP-XPS Measures MIEC Oxides in Action

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AP-XPS Measures MIEC Oxides in Action Print Oxide materials with mixed ionic-electronic conductivity (MIEC) can conduct both electrons and oxygen ions. MIEC oxides have broad applications, including use in solid-oxide fuel cells, high-temperature electrolysis for synthetic fuel production, and oxygen-separating membranes for chemical processes or NOx-free combustion; however, their surface activity under reaction conditions has been difficult, if not impossible, to ascertain, until recently. A

  5. AP-XPS Measures MIEC Oxides in Action

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AP-XPS Measures MIEC Oxides in Action Print Oxide materials with mixed ionic-electronic conductivity (MIEC) can conduct both electrons and oxygen ions. MIEC oxides have broad applications, including use in solid-oxide fuel cells, high-temperature electrolysis for synthetic fuel production, and oxygen-separating membranes for chemical processes or NOx-free combustion; however, their surface activity under reaction conditions has been difficult, if not impossible, to ascertain, until recently. A

  6. AP-XPS Measures MIEC Oxides in Action

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AP-XPS Measures MIEC Oxides in Action Print Oxide materials with mixed ionic-electronic conductivity (MIEC) can conduct both electrons and oxygen ions. MIEC oxides have broad applications, including use in solid-oxide fuel cells, high-temperature electrolysis for synthetic fuel production, and oxygen-separating membranes for chemical processes or NOx-free combustion; however, their surface activity under reaction conditions has been difficult, if not impossible, to ascertain, until recently. A

  7. AP-XPS Measures MIEC Oxides in Action

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AP-XPS Measures MIEC Oxides in Action Print Oxide materials with mixed ionic-electronic conductivity (MIEC) can conduct both electrons and oxygen ions. MIEC oxides have broad applications, including use in solid-oxide fuel cells, high-temperature electrolysis for synthetic fuel production, and oxygen-separating membranes for chemical processes or NOx-free combustion; however, their surface activity under reaction conditions has been difficult, if not impossible, to ascertain, until recently. A

  8. AP-XPS Measures MIEC Oxides in Action

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AP-XPS Measures MIEC Oxides in Action Print Oxide materials with mixed ionic-electronic conductivity (MIEC) can conduct both electrons and oxygen ions. MIEC oxides have broad applications, including use in solid-oxide fuel cells, high-temperature electrolysis for synthetic fuel production, and oxygen-separating membranes for chemical processes or NOx-free combustion; however, their surface activity under reaction conditions has been difficult, if not impossible, to ascertain, until recently. A

  9. Mixed ionic-electronic conductor-based radiation detectors and methods of fabrication

    DOE Patents [OSTI]

    Conway, Adam; Beck, Patrick R; Graff, Robert T; Nelson, Art; Nikolic, Rebecca J; Payne, Stephen A; Voss, Lars; Kim, Hadong

    2015-04-07

    A method of fabricating a mixed ionic-electronic conductor (e.g. TlBr)-based radiation detector having halide-treated surfaces and associated methods of fabrication, which controls polarization of the mixed ionic-electronic MIEC material to improve stability and operational lifetime.

  10. Nonlinear space charge dynamics in mixed ionic-electronic conductors: Resistive switching and ferroelectric-like hysteresis of electromechanical response

    SciTech Connect (OSTI)

    Morozovska, Anna N.; Morozovsky, Nicholas V.; Eliseev, Eugene A.; Varenyk, Olexandr V.; Kim, Yunseok; Strelcov, Evgheni; Tselev, Alexander; Kalinin, Sergei V.

    2014-08-14

    We performed self-consistent modelling of nonlinear electrotransport and electromechanical response of thin films of mixed ionic-electronic conductors (MIEC) allowing for steric effects of mobile charged defects (ions, protons, or vacancies), electron degeneration, and Vegard stresses. We establish correlations between the features of the nonlinear space-charge dynamics, current-voltage, and bending-voltage curves for different types of the film electrodes. A pronounced ferroelectric-like hysteresis of the bending-voltage loops and current maxima on the double hysteresis current-voltage loops appear for the electron-transport electrodes. The double hysteresis loop with pronounced humps indicates a memristor-type resistive switching. The switching occurs due to the strong nonlinear coupling between the electronic and ionic subsystems. A sharp meta-stable maximum of the electron density appears near one open electrode and moves to another one during the periodic change of applied voltage. Our results can explain the nonlinear nature and correlation of electrical and mechanical memory effects in thin MIEC films. The analytical expression proving that the electrically induced bending of MIEC films can be detected by interferometric methods is derived.

  11. Improvement of SOFC electrodes using mixed ionic-electronic conductors

    SciTech Connect (OSTI)

    Matsuzaki, Y.; Hishinuma, M.

    1996-12-31

    Since the electrode reaction of SOFC is limited to the proximity of a triple phase boundary (TPB), the local current density at the electrode and electrolyte interface is larger than mean current density, which causes large ohmic and electrode polarization. This paper describes an application of mixed ionic-electronic conductors to reduce such polarization by means of (1) enhancing ionic conductivity of the electrolyte surface layer by coating a high ionic conductors, and (2) reducing the local current density by increasing the electrochemically active sites.

  12. AP-XPS Measures MIEC Oxides in Action

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    improved strategies and materials to move these technologies forward for clean power generation and fuel production. Research conducted by C. Zhang, S. DeCaluwe, G. Jackson,...

  13. AP-XPS Measures MIEC Oxides in Action

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    for synthetic fuel production, and oxygen-separating membranes for chemical processes or NOx-free combustion; however, their surface activity under reaction conditions has been...

  14. AP-XPS Measures MIEC Oxides in Action

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    model materials that may be used in high-temperature water splitting to make hydrogen gas (H2). Understanding how the surfaces react under different conditions provides a...

  15. AP-XPS Measures MIEC Oxides in Action

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    like electrolysis, from renewable power sources, like water, allowing for either a sustainable hydrogen economy or sustainable production of synthetic hydrocarbon fuels. The...

  16. AP-XPS Measures MIEC Oxides in Action

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of active electrode surfaces using x-ray photoelectron spectroscopy (XPS); therefore, the research community has lacked quantitative data on these materials' surface redox cycles...

  17. Structural control of mixed ionic and electronic transport in conducting polymers

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Rivnay, Jonathan; Inal, Sahika; Collins, Brian A.; Sessolo, Michele; Stavrinidou, Eleni; Strakosas, Xenofon; Tassone, Christopher; Delongchamp, Dean M.; Malliaras, George G.

    2016-04-19

    Poly(3,4-ethylenedioxythiophene) doped with poly(styrenesulfonate), PEDOT:PSS, has been utilized for over two decades as a stable, solution-processable hole conductor. While its hole transport properties have been the subject of intense investigation, recent work has turned to PEDOT:PSS as a mixed ionic/electronic conductor in applications including bioelectronics, energy storage and management, and soft robotics. Conducting polymers can efficiently transport both holes and ions when sufficiently hydrated, however, little is known about the role of morphology on mixed conduction. Here, we show that bulk ionic and electronic mobilities are simultaneously affected by processing-induced changes in nano- and meso-scale structure in PEDOT:PSS films. Wemore » quantify domain composition, and find that domain purification on addition of dispersion co-solvents limits ion mobility, even while electronic conductivity improves. We show that an optimal morphology allows for the balanced ionic and electronic transport that is critical for prototypical mixed conductor devices. As a result, these findings may pave the way for the rational design of polymeric materials and processing routes to enhance devices reliant on mixed conduction.« less

  18. Code of Conduct

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Governance » Ethics, Accountability, Contract » Code of Conduct Code of Conduct Helping employees recognize and resolve the ethics and compliance issues that may arise in their daily work. Contact Ethics and Compliance Group (505) 667-7506 Email Code of Conduct Los Alamos National Laboratory is committed to operating in accordance with the highest standards of ethics and compliance and with its core values of service to our nation, ethical conduct and personal accountability, excellence in our

  19. Electrically conductive composite material

    DOE Patents [OSTI]

    Clough, Roger L.; Sylwester, Alan P.

    1989-01-01

    An electrically conductive composite material is disclosed which comprises a conductive open-celled, low density, microcellular carbon foam filled with a non-conductive polymer or resin. The composite material is prepared in a two-step process consisting of first preparing the microcellular carbon foam from a carbonizable polymer or copolymer using a phase separation process, then filling the carbon foam with the desired non-conductive polymer or resin. The electrically conductive composites of the present invention has a uniform and consistant pattern of filler distribution, and as a result is superior over prior art materials when used in battery components, electrodes, and the like.

  20. Electrically conductive composite material

    DOE Patents [OSTI]

    Clough, R.L.; Sylwester, A.P.

    1989-05-23

    An electrically conductive composite material is disclosed which comprises a conductive open-celled, low density, microcellular carbon foam filled with a non-conductive polymer or resin. The composite material is prepared in a two-step process consisting of first preparing the microcellular carbon foam from a carbonizable polymer or copolymer using a phase separation process, then filling the carbon foam with the desired non-conductive polymer or resin. The electrically conductive composites of the present invention has a uniform and consistent pattern of filler distribution, and as a result is superior over prior art materials when used in battery components, electrodes, and the like. 2 figs.

  1. Electrically conductive composite material

    DOE Patents [OSTI]

    Clough, R.L.; Sylwester, A.P.

    1988-06-20

    An electrically conductive composite material is disclosed which comprises a conductive open-celled, low density, microcellular carbon foam filled with a non-conductive polymer or resin. The composite material is prepared in a two-step process consisting of first preparing the microcellular carbon foam from a carbonizable polymer or copolymer using a phase separation process, then filling the carbon foam with the desired non-conductive polymer or resin. The electrically conductive composites of the present invention has a uniform and consistent pattern of filler distribution, and as a result is superior over prior art materials when used in battery components, electrodes, and the like. 2 figs.

  2. High conductance surge cable

    DOE Patents [OSTI]

    Murray, Matthew M.; Wilfong, Dennis H.; Lomax, Ralph E.

    1998-01-01

    An electrical cable for connecting transient voltage surge suppressers to ectrical power panels. A strip of electrically conductive foil defines a longitudinal axis, with a length of an electrical conductor electrically attached to the metallic foil along the longitudinal axis. The strip of electrically conductive foil and the length of an electrical conductor are covered by an insulating material. For impedance matching purposes, triangular sections can be removed from the ends of the electrically conductive foil at the time of installation.

  3. High conductance surge cable

    DOE Patents [OSTI]

    Murray, M.M.; Wilfong, D.H.; Lomax, R.E.

    1998-12-08

    An electrical cable for connecting transient voltage surge suppressors to electrical power panels. A strip of electrically conductive foil defines a longitudinal axis, with a length of an electrical conductor electrically attached to the metallic foil along the longitudinal axis. The strip of electrically conductive foil and the length of an electrical conductor are covered by an insulating material. For impedance matching purposes, triangular sections can be removed from the ends of the electrically conductive foil at the time of installation. 6 figs.

  4. Electrically conductive cellulose composite

    DOE Patents [OSTI]

    Evans, Barbara R.; O'Neill, Hugh M.; Woodward, Jonathan

    2010-05-04

    An electrically conductive cellulose composite includes a cellulose matrix and an electrically conductive carbonaceous material incorporated into the cellulose matrix. The electrical conductivity of the cellulose composite is at least 10 .mu.S/cm at 25.degree. C. The composite can be made by incorporating the electrically conductive carbonaceous material into a culture medium with a cellulose-producing organism, such as Gluconoacetobacter hansenii. The composites can be used to form electrodes, such as for use in membrane electrode assemblies for fuel cells.

  5. Electrically conductive diamond electrodes

    DOE Patents [OSTI]

    Swain, Greg; Fischer, Anne ,; Bennett, Jason; Lowe, Michael

    2009-05-19

    An electrically conductive diamond electrode and process for preparation thereof is described. The electrode comprises diamond particles coated with electrically conductive doped diamond preferably by chemical vapor deposition which are held together with a binder. The electrodes are useful for oxidation reduction in gas, such as hydrogen generation by electrolysis.

  6. Conductive fabric seal

    SciTech Connect (OSTI)

    Livesay, Ronald Jason; Mason, Brandon William; Kuhn, Michael Joseph; Rowe, Nathan Carl

    2015-10-13

    Disclosed are several examples of a system and method for detecting if an article is being tampered with. Included is a covering made of a substrate that is coated with a layer of an electrically conductive material that forms an electrically conductive surface having an electrical resistance. The covering is configured to at least partially encapsulate the article such that the article cannot be tampered with, without modifying the electrical resistance of the electrically conductive surface of the covering. A sensing device is affixed to the electrically conductive surface of the covering and the sensing device monitors the condition of the covering by producing a signal that is indicative of the electrical resistance of the electrically conductive surface of the covering. A measured electrical resistance that differs from a nominal electrical resistance is indicative of a covering that is being tampered with and an alert is communicated to an observer.

  7. Conduct of Operations

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2010-06-29

    This Order defines the requirements for establishing and implementing Conduct of Operations Programs at Department of Energy (DOE), including National Nuclear Security Administration (NNSA), facilities and projects. Admin Chg 2, dated 12-3-14, supersedes Admin Chg 1.

  8. Conductive open frameworks

    DOE Patents [OSTI]

    Yaghi, Omar M.; Wan, Shun; Doonan, Christian J.; Wang, Bo; Deng, Hexiang

    2016-02-23

    The disclosure relates generally to materials that comprise conductive covalent organic frameworks. The disclosure also relates to materials that are useful to store and separate gas molecules and sensors.

  9. Conduct of Operations

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2010-06-29

    This Order defines the requirements for establishing and implementing Conduct of Operations Programs at Department of Energy (DOE), including National Nuclear Security Administration (NNSA), facilities and projects. Cancels DOE O 5480.19. Admin Chg 1, 6-25-13

  10. Electrically conductive material

    DOE Patents [OSTI]

    Singh, Jitendra P.; Bosak, Andrea L.; McPheeters, Charles C.; Dees, Dennis W.

    1993-01-01

    An electrically conductive material for use in solid oxide fuel cells, electrochemical sensors for combustion exhaust, and various other applications possesses increased fracture toughness over available materials, while affording the same electrical conductivity. One embodiment of the sintered electrically conductive material consists essentially of cubic ZrO.sub.2 as a matrix and 6-19 wt. % monoclinic ZrO.sub.2 formed from particles having an average size equal to or greater than about 0.23 microns. Another embodiment of the electrically conductive material consists essentially at cubic ZrO.sub.2 as a matrix and 10-30 wt. % partially stabilized zirconia (PSZ) formed from particles having an average size of approximately 3 microns.

  11. Electrically conductive material

    DOE Patents [OSTI]

    Singh, J.P.; Bosak, A.L.; McPheeters, C.C.; Dees, D.W.

    1993-09-07

    An electrically conductive material is described for use in solid oxide fuel cells, electrochemical sensors for combustion exhaust, and various other applications possesses increased fracture toughness over available materials, while affording the same electrical conductivity. One embodiment of the sintered electrically conductive material consists essentially of cubic ZrO[sub 2] as a matrix and 6-19 wt. % monoclinic ZrO[sub 2] formed from particles having an average size equal to or greater than about 0.23 microns. Another embodiment of the electrically conductive material consists essentially at cubic ZrO[sub 2] as a matrix and 10-30 wt. % partially stabilized zirconia (PSZ) formed from particles having an average size of approximately 3 microns. 8 figures.

  12. Conducting fiber compression tester

    DOE Patents [OSTI]

    DeTeresa, Steven J.

    1990-01-01

    The invention measures the resistance across a conductive fiber attached to a substrate place under a compressive load to determine the amount of compression needed to cause the fiber to fail.

  13. Solid oxide fuel cells having porous cathodes infiltrated with oxygen-reducing catalysts

    DOE Patents [OSTI]

    Liu, Meilin; Liu, Ze; Liu, Mingfei; Nie, Lifang; Mebane, David Spencer; Wilson, Lane Curtis; Surdoval, Wayne

    2014-08-12

    Solid-oxide fuel cells include an electrolyte and an anode electrically coupled to a first surface of the electrolyte. A cathode is provided, which is electrically coupled to a second surface of the electrolyte. The cathode includes a porous backbone having a porosity in a range from about 20% to about 70%. The porous backbone contains a mixed ionic-electronic conductor (MIEC) of a first material infiltrated with an oxygen-reducing catalyst of a second material different from the first material.

  14. Transparent Conductive Nanostructures

    SciTech Connect (OSTI)

    2008-06-22

    The objectives of this program between UT-Battelle, LLC (the ''Contractor'') and (Battelle Memorial Institute) (the "Participant") were directed towards achieving significant improvement: in the electrical conductivity and optical/infrared transmission of single-wall carbon nanotube (SWNT)-based composite materials. These materials will be used in coating applications that range from aircraft canopies to display applications. The goal of the project was to obtain supported mats of SWNTs with sheet conductivities approaching 10 ohms/square combined with high optical transmission (>85% transmission at 550 nm), thereby permitting their application as a replacement for indium tin oxide (ITO) in a variety of applications such as flexible displays.

  15. Control of Test Conduct

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2 Revision 1 Effective June 2008 Control of Test Conduct Prepared by Electric Transportation Applications Prepared by: _______________________________ Date:__________ Garrett P. Beauregard Approved by: _________________________________________________ Date: _______________ Donald B. Karner Procedure ETA-GAC002 Revision 1 2 Table of Contents 1 Objective ..................................................................................................................... 3 2

  16. Conductance Steamflow relationship

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Whitney Trainor-Guitton

    2015-04-01

    These histograms represent our calibration of conductance of a volcanic geothermal field (with a clay cap) and the observed steam flow rates. See the following paper for further description: Trainor-Guitton, Hoversten,Nordquist, Intani, Value of information analysis using geothermal field data: accounting for multiple interpretations & determining new drilling locations. SEG Abstracts 2015.

  17. Lithium ion conducting electrolytes

    DOE Patents [OSTI]

    Angell, C. Austen; Liu, Changle

    1996-01-01

    A liquid, predominantly lithium-conducting, ionic electrolyte having exceptionally high conductivity at temperatures of 100.degree. C. or lower, including room temperature, and comprising the lithium salts selected from the group consisting of the thiocyanate, iodide, bromide, chloride, perchlorate, acetate, tetrafluoroborate, perfluoromethane sulfonate, perfluoromethane sulfonamide, tetrahaloaluminate, and heptahaloaluminate salts of lithium, with or without a magnesium-salt selected from the group consisting of the perchlorate and acetate salts of magnesium. Certain of the latter embodiments may also contain molecular additives from the group of acetonitrile (CH.sub.3 CN) succinnonitrile (CH.sub.2 CN).sub.2, and tetraglyme (CH.sub.3 --O--CH.sub.2 --CH.sub.2 --O--).sub.2 (or like solvents) solvated to a Mg.sup.+2 cation to lower the freezing point of the electrolyte below room temperature. Other particularly useful embodiments contain up to about 40, but preferably not more than about 25, mol percent of a long chain polyether polymer dissolved in the lithium salts to provide an elastic or rubbery solid electrolyte of high ambient temperature conductivity and exceptional 100.degree. C. conductivity. Another embodiment contains up to about but not more than 10 mol percent of a molecular solvent such as acetone.

  18. Lithium ion conducting electrolytes

    DOE Patents [OSTI]

    Angell, C.A.; Liu, C.

    1996-04-09

    A liquid, predominantly lithium-conducting, ionic electrolyte is described having exceptionally high conductivity at temperatures of 100 C or lower, including room temperature, and comprising the lithium salts selected from the group consisting of the thiocyanate, iodide, bromide, chloride, perchlorate, acetate, tetrafluoroborate, perfluoromethane sulfonate, perfluoromethane sulfonamide, tetrahaloaluminate, and heptahaloaluminate salts of lithium, with or without a magnesium-salt selected from the group consisting of the perchlorate and acetate salts of magnesium. Certain of the latter embodiments may also contain molecular additives from the group of acetonitrile (CH{sub 3}CN), succinnonitrile (CH{sub 2}CN){sub 2}, and tetraglyme (CH{sub 3}--O--CH{sub 2}--CH{sub 2}--O--){sub 2} (or like solvents) solvated to a Mg{sup +2} cation to lower the freezing point of the electrolyte below room temperature. Other particularly useful embodiments contain up to about 40, but preferably not more than about 25, mol percent of a long chain polyether polymer dissolved in the lithium salts to provide an elastic or rubbery solid electrolyte of high ambient temperature conductivity and exceptional 100 C conductivity. Another embodiment contains up to about but not more than 10 mol percent of a molecular solvent such as acetone. 2 figs.

  19. Lithium ion conducting electrolytes

    DOE Patents [OSTI]

    Angell, Charles Austen; Liu, Changle; Xu, Kang; Skotheim, Terje A.

    1999-01-01

    The present invention relates generally to highly conductive alkali-metal ion non-crystalline electrolyte systems, and more particularly to novel and unique molten (liquid), rubbery, and solid electrolyte systems which are especially well suited for use with high current density electrolytic cells such as primary and secondary batteries.

  20. Conduct of Operations

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2010-06-29

    This Order defines the requirements for establishing and implementing Conduct of Operations Programs at Department of Energy (DOE), including National Nuclear Security Administration (NNSA), facilities and projects. Cancels DOE O 5480.19. Admin Chg 1, dated 6-25-13, cancels DOE O 422.1. Certified 12-3-14.

  1. Electrically conductive alternating copolymers

    DOE Patents [OSTI]

    Aldissi, M.; Jorgensen, B.S.

    1987-08-31

    Polymers which are soluble in common organic solvents and are electrically conductive, but which also may be synthesized in such a manner that they become nonconductive. Negative ions from the electrolyte used in the electrochemical synthesis of a polymer are incorporated into the polymer during the synthesis and serve as a dopant. A further electrochemical step may be utilized to cause the polymer to be conductive. The monomer repeat unit is comprised of two rings, a pyrrole molecule joined to a thienyl group, or a furyl group, or a phenyl group. The individual groups of the polymers are arranged in an alternating manner. For example, the backbone arrangement of poly(furylpyrrole) is -furan-pyrrole-furan-pyrrole- furan-pyrrole. An alkyl group or phenyl group may be substituted for either or both of the hydrogen atoms of the pyrrole ring.

  2. Super ionic conductive glass

    DOE Patents [OSTI]

    Susman, S.; Volin, K.J.

    Described is an ionically conducting glass for use as a solid electrolyte in a power or secondary cell containing an alkali metal-containing anode and a cathode separated by an alkali metal ion conducting glass having an ionic transference number of unity and the general formula: A/sub 1 + x/D/sub 2-x/3/Si/sub x/P/sub 3 - x/O/sub 12 - 2x/3/, wherein A is a network modifier for the glass and is an alkali metal of the anode, D is an intermediate for the glass and is selected from the class consisting of Zr, Ti, Ge, Al, Sb, Be, and Zn and X is in the range of from 2.25 to 3.0. Of the alkali metals, Na and Li are preferred and of the intermediate, Zr, Ti and Ge are preferred.

  3. Super ionic conductive glass

    DOE Patents [OSTI]

    Susman, Sherman; Volin, Kenneth J.

    1984-01-01

    An ionically conducting glass for use as a solid electrolyte in a power or secondary cell containing an alkali metal-containing anode and a cathode separated by an alkali metal ion conducting glass having an ionic transference number of unity and the general formula: A.sub.1+x D.sub.2-x/3 Si.sub.x P.sub.3-x O.sub.12-2x/3, wherein A is a network modifier for the glass and is an alkali metal of the anode, D is an intermediate for the glass and is selected from the class consisting of Zr, Ti, Ge, Al, Sb, Be, and Zn and X is in the range of from 2.25 to 3.0. Of the alkali metals, Na and Li are preferred and of the intermediate, Zr, Ti and Ge are preferred.

  4. Oxygen ion conducting materials

    DOE Patents [OSTI]

    Carter, J. David; Wang, Xiaoping; Vaughey, John; Krumpelt, Michael

    2004-11-23

    An oxygen ion conducting ceramic oxide that has applications in industry including fuel cells, oxygen pumps, oxygen sensors, and separation membranes. The material is based on the idea that substituting a dopant into the host perovskite lattice of (La,Sr)MnO.sub.3 that prefers a coordination number lower than 6 will induce oxygen ion vacancies to form in the lattice. Because the oxygen ion conductivity of (La,Sr)MnO.sub.3 is low over a very large temperature range, the material exhibits a high overpotential when used. The inclusion of oxygen vacancies into the lattice by doping the material has been found to maintain the desirable properties of (La,Sr)MnO.sub.3, while significantly decreasing the experimentally observed overpotential.

  5. Oxygen ion conducting materials

    DOE Patents [OSTI]

    Vaughey, John; Krumpelt, Michael; Wang, Xiaoping; Carter, J. David

    2005-07-12

    An oxygen ion conducting ceramic oxide that has applications in industry including fuel cells, oxygen pumps, oxygen sensors, and separation membranes. The material is based on the idea that substituting a dopant into the host perovskite lattice of (La,Sr)MnO.sub.3 that prefers a coordination number lower than 6 will induce oxygen ion vacancies to form in the lattice. Because the oxygen ion conductivity of (La,Sr)MnO.sub.3 is low over a very large temperature range, the material exhibits a high overpotential when used. The inclusion of oxygen vacancies into the lattice by doping the material has been found to maintain the desirable properties of (La,Sr)MnO.sub.3, while significantly decreasing the experimentally observed overpotential.

  6. Oxygen ion conducting materials

    DOE Patents [OSTI]

    Vaughey, John; Krumpelt, Michael; Wang, Xiaoping; Carter, J. David

    2003-01-01

    An oxygen ion conducting ceramic oxide that has applications in industry including fuel cells, oxygen pumps, oxygen sensors, and separation membranes. The material is based on the idea that substituting a dopant into the host perovskite lattice of (La,Sr)MnO.sub.3 that prefers a coordination number lower than 6 will induce oxygen ion vacancies to form in the lattice. Because the oxygen ion conductivity of (La,Sr)MnO.sub.3 is low over a very large temperature range, the material exhibits a high overpotential when used. The inclusion of oxygen vacancies into the lattice by doping the material has been found to maintain the desirable properties of (La,Sr)MnO.sub.3, while significantly decreasing the experimentally observed overpotential.

  7. Low Temperature Proton Conductivity

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and MEAs at Freezing Temperatures Thomas A. Zawodzinski, Jr. Case Western Reserve University Cleveland, Ohio 2 Freezing Fuel Cells: Impact on MEAS Below 0 o C *Transport processes/motions slow down: questions re: lower conductivity,water mobility etc *Residual water will have various physical effects in different portions of the MEA questions re: durability of components 3 3 'States' of Water in Proton Conductors ? Freezing (bulk), bound freezable, bound non freezable water states claimed based

  8. High conductivity composite metal

    DOE Patents [OSTI]

    Zhou, Ruoyi; Smith, James L.; Embury, John David

    1998-01-01

    Electrical conductors and methods of producing them, where the conductors possess both high strength and high conductivity. Conductors are comprised of carbon steel and a material chosen from a group consisting of copper, nickel, silver, and gold. Diffusion barriers are placed between these two materials. The components of a conductor are assembled and then the assembly is subjected to heat treating and mechanical deformation steps.

  9. High conductivity composite metal

    DOE Patents [OSTI]

    Zhou, R.; Smith, J.L.; Embury, J.D.

    1998-01-06

    Electrical conductors and methods of producing them are disclosed, where the conductors possess both high strength and high conductivity. Conductors are comprised of carbon steel and a material chosen from a group consisting of copper, nickel, silver, and gold. Diffusion barriers are placed between these two materials. The components of a conductor are assembled and then the assembly is subjected to heat treating and mechanical deformation steps. 10 figs.

  10. Sandia National Laboratories conducts

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    conducts research and development (R&D) in solar power, including photovoltaics and concentrating solar power, to strengthen the U.S. solar industry and improve the manufacturability, reliability, and cost competitiveness of solar energy technologies and systems. Researchers at Sandia partner with the U.S. Department of Energy (DOE) and other government agencies, industry, academia, and other laboratories to accelerate development and acceptance of current and emerging solar power

  11. Conduction cooled tube supports

    DOE Patents [OSTI]

    Worley, Arthur C.; Becht, IV, Charles

    1984-01-01

    In boilers, process tubes are suspended by means of support studs that are in thermal contact with and attached to the metal roof casing of the boiler and the upper bend portions of the process tubes. The support studs are sufficiently short that when the boiler is in use, the support studs are cooled by conduction of heat to the process tubes and the roof casing thereby maintaining the temperature of the stud so that it does not exceed 1400.degree. F.

  12. Conducting polymer ultracapacitor

    DOE Patents [OSTI]

    Shi, Steven Z.; Davey, John R.; Gottesfeld, Shimshon; Ren, Xiaoming

    2002-01-01

    A sealed ultracapacitor assembly is formed with first and second electrodes of first and second conducting polymers electrodeposited on porous carbon paper substrates, where the first and second electrodes each define first and second exterior surfaces and first and second opposing surfaces. First and second current collector plates are bonded to the first and second exterior surfaces, respectively. A porous membrane separates the first and second opposing surfaces, with a liquid electrolyte impregnating the insulating membrane. A gasket formed of a thermoplastic material surrounds the first and second electrodes and seals between the first and second current collector plates for containing the liquid electrolyte.

  13. Borehole Fluid Conductivity Model

    Energy Science and Technology Software Center (OSTI)

    2004-03-15

    Dynamic wellbore electrical conductivity logs provide a valuable means to determine the flow characteristics of fractures intersectin a wellbore, in order to study the hydrologic behavior of fractured rocks. To expedite the analysis of log data, a computer program called BORE II has been deveoloped that considers multiple inflow or outflow points along the wellbore, including the case of horizontal flow across the wellbore, BORE II calculates the evolution of fluid electrical conducivity (FEC) profilesmorein a wellbore or wellbore section, which may be pumped at a low rate, and compares model results to log data in a variety of ways. FEC variations may arise from inflow under natural-state conditions or due to tracer injected in a neighboring well (interference tests). BORE II has an interactive, graphical user interface and runs on a personal computer under the Windows operating system. BORE II is a modification and extension of older codes called BORE and BOREXT, which considered inflow points only. Finite difference solution of the one-dimensional advection-diffusion equation with explicit time stepping; feed points treated as prescribed-mass sources or sinks; assume quadratic relationship between fluid electrical conductivity and ion consentration. Graphical user interface; interactive modification of model parameters and graphical display of model results and filed data in a variety of ways. Can examine horizontal flow or arbitarily complicated combination of upflow, downflow, and horizontal flow. Feed point flow rate and/or concentration may vary in time.less

  14. Lateral conduction infrared photodetector

    DOE Patents [OSTI]

    Kim, Jin K.; Carroll, Malcolm S.

    2011-09-20

    A photodetector for detecting infrared light in a wavelength range of 3-25 .mu.m is disclosed. The photodetector has a mesa structure formed from semiconductor layers which include a type-II superlattice formed of alternating layers of InAs and In.sub.xGa.sub.1-xSb with 0.ltoreq.x.ltoreq.0.5. Impurity doped regions are formed on sidewalls of the mesa structure to provide for a lateral conduction of photo-generated carriers which can provide an increased carrier mobility and a reduced surface recombination. An optional bias electrode can be used in the photodetector to control and vary a cut-off wavelength or a depletion width therein. The photodetector can be formed as a single-color or multi-color device, and can also be used to form a focal plane array which is compatible with conventional read-out integrated circuits.

  15. Normal Conducting CLIC Technology

    SciTech Connect (OSTI)

    Jensen, Erk

    2006-01-03

    The CLIC (Compact Linear Collider) multi-lateral study group based at CERN is studying the technology for an electron-positron linear collider with a centre-of-mass energy up to 5 TeV. In contrast to the International Linear Collider (ILC) study which has chosen to use super-conducting cavities with accelerating gradients in the range of 30-40 MV/m to obtain centre-of-mass collision energies of 0.5-1 TeV, the CLIC study aims to use a normal-conducting system based on two-beam technology with gradients of 150 MV/m. It is generally accepted that this change in technology is not only necessary but the only viable choice for a cost-effective multi-TeV collider. The CLIC study group is studying the technology issues of such a machine, and is in particular developing state-of-the-art 30 GHz molybdenum-iris accelerating structures and power extraction and transfer structures (PETS). The accelerating structure has a new geometry which includes fully-profiled RF surfaces optimised to minimize surface fields, and hybrid damping using both iris slots and radial waveguides. A newly-developed structure-optimisation procedure has been used to simultaneously balance surface fields, power flow, short and long-range transverse wakefields, RF-to-beam efficiency and the ratio of luminosity to input power. The slotted irises allow a simple structure fabrication by high-precision high-speed 3D milling of just four pieces, and an even easier bolted assembly in a vacuum chamber.

  16. Conductive lithium storage electrode

    DOE Patents [OSTI]

    Chiang, Yet-Ming; Chung, Sung-Yoon; Bloking, Jason T.; Andersson, Anna M.

    2012-04-03

    A compound comprising a composition A.sub.x(M'.sub.1-aM''.sub.a).sub.y(XD.sub.4).sub.z, A.sub.x(M'.sub.1-aM''.sub.a).sub.y(DXD.sub.4).sub.z, or A.sub.x(M'.sub.1-aM''.sub.a).sub.y(X.sub.2D.sub.7).sub.z, and have values such that x, plus y(1-a) times a formal valence or valences of M', plus ya times a formal valence or valence of M'', is equal to z times a formal valence of the XD.sub.4, X.sub.2D.sub.7, or DXD.sub.4 group; or a compound comprising a composition (A.sub.1-aM''.sub.a).sub.xM'.sub.y(XD.sub.4).sub.z, (A.sub.1-aM''.sub.a).sub.xM'.sub.y(DXD.sub.4).sub.z (A.sub.1-aM''.sub.a).sub.xM'.sub.y(X.sub.2D.sub.7).sub.z and have values such that (1-a).sub.x plus the quantity ax times the formal valence or valences of M'' plus y times the formal valence or valences of M' is equal to z times the formal valence of the XD.sub.4, X.sub.2D.sub.7 or DXD.sub.4 group. In the compound, A is at least one of an alkali metal and hydrogen, M' is a first-row transition metal, X is at least one of phosphorus, sulfur, arsenic, molybdenum, and tungsten, M'' any of a Group IIA, IIIA, IVA, VA, VIA, VIIA, VIIIA, IB, IIB, IIIB, IVB, VB, and VIB metal, D is at least one of oxygen, nitrogen, carbon, or a halogen, 0.0001conductivity at 27.degree. C. of at least about 10.sup.-8 S/cm. The compound can be a doped lithium phosphate that can intercalate lithium or hydrogen. The compound can be used in an electrochemical device including electrodes and storage batteries and can have a gravimetric capacity of at least about 80 mAh/g while being charged/discharged at greater than about C rate of the compound.

  17. Conductive lithium storage electrode

    DOE Patents [OSTI]

    Chiang, Yet-Ming; Chung, Sung-Yoon; Bloking, Jason T.; Andersson, Anna M.

    2008-03-18

    A compound comprising a composition A.sub.x(M'.sub.1-aM''.sub.a).sub.y(XD.sub.4).sub.z, A.sub.x(M'.sub.1-aM''.sub.a).sub.y(DXD.sub.4).sub.z, or A.sub.x(M'.sub.1-aM''.sub.a).sub.y(X.sub.2D.sub.7).sub.z, and have values such that x, plus y(1-a) times a formal valence or valences of M', plus ya times a formal valence or valence of M'', is equal to z times a formal valence of the XD.sub.4, X.sub.2D.sub.7, or DXD.sub.4 group; or a compound comprising a composition (A.sub.1-aM''.sub.a).sub.xM'.sub.y(XD.sub.4).sub.z, (A.sub.1-aM''.sub.a).sub.xM'.sub.y(DXD.sub.4).sub.z(A.sub.1-aM''.sub.a).s- ub.xM'.sub.y(X.sub.2D.sub.7).sub.z and have values such that (1-a).sub.x plus the quantity ax times the formal valence or valences of M'' plus y times the formal valence or valences of M' is equal to z times the formal valence of the XD.sub.4, X.sub.2D.sub.7 or DXD.sub.4 group. In the compound, A is at least one of an alkali metal and hydrogen, M' is a first-row transition metal, X is at least one of phosphorus, sulfur, arsenic, molybdenum, and tungsten, M'' any of a Group IIA, IIIA, IVA, VA, VIA, VIIA, VIIIA, IB, IIB, IIIB, IVB, VB, and VIB metal, D is at least one of oxygen, nitrogen, carbon, or a halogen, 0.0001conductivity at 27.degree. C. of at least about 10.sup.-8 S/cm. The compound can be a doped lithium phosphate that can intercalate lithium or hydrogen. The compound can be used in an electrochemical device including electrodes and storage batteries and can have a gravimetric capacity of at least about 80 mAh/g while being charged/discharged at greater than about C rate of the compound.

  18. Rapid prototype extruded conductive pathways

    DOE Patents [OSTI]

    Bobbitt, III, John T.

    2016-06-21

    A process of producing electrically conductive pathways within additively manufactured parts and similar parts made by plastic extrusion nozzles. The process allows for a three-dimensional part having both conductive and non-conductive portions and allows for such parts to be manufactured in a single production step.

  19. Synthesis and characterization of R{sub 2}MnTiO{sub 7} (R = Y and Er) pyrochlores oxides

    SciTech Connect (OSTI)

    Martnez-Coronado, R.; Alonso, J.A.; Fernndez, M.T.

    2013-09-01

    Graphical abstract: - Abstract: New pyrochlore-like phases of composition R{sub 2}MnTiO{sub 7} (R = Er and Y) have been synthesized by a soft-chemistry procedure involving citrates of the different metal ions followed by thermal treatments at moderate temperatures (850 C for 12 h in air). A characterization by X-ray diffraction and neutron powder diffraction (NPD) has been carried out in order to determine the crystal structure features: these phyrochlores are cubic, space group Fd-3m, defining an intrinsically frustrated three-dimensional system. The Rietveld-refinement from NPD data at room temperature evidences an antisite cation disorder (distribution of Mn between A and B positions) that is accompanied by an increment of the oxygen-vacancy concentration due to the reduction of Mn{sup 4+} at the B position to Mn{sup 2+} at the A position. Thermogravimetric analysis (TGA) was useful to evaluate the stability of these oxides in reducing conditions up to 500 C. Magnetic susceptibility measurements indicate a ferromagnetic behavior, due to the random distribution of Mn{sup 4+} ions in the octahedral sublattice. At lower temperatures there is a polarization of the R{sup +3} magnetic moments, which also participate in the magnetic structure. Aiming to evaluate these materials as possible electrodes for solid oxide fuel cells (SOFC) we determined that the thermal expansion coefficients between 100 and 900 C perfectly match with those of the usual electrolytes; however, these pyrochlore oxides display a semiconductor-like behavior with poor conductivity values, e.g. 6 10{sup ?3} cm{sup ?1} at 850 C for Er, which would prevent its use as MIEC (mixed ionic-electronic conductors) oxides in SOFC devices.

  20. Appendix C Conducting Structured Walkthroughs

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    1997-05-21

    This guide describes how to conduct a structured walkthroughs during the lifecycle stages of software engineering projects, regardless of hardware platform.

  1. Conductive polymer-based material

    DOE Patents [OSTI]

    McDonald, William F.; Koren, Amy B.; Dourado, Sunil K.; Dulebohn, Joel I.; Hanchar, Robert J.

    2007-04-17

    Disclosed are polymer-based coatings and materials comprising (i) a polymeric composition including a polymer having side chains along a backbone forming the polymer, at least two of the side chains being substituted with a heteroatom selected from oxygen, nitrogen, sulfur, and phosphorus and combinations thereof; and (ii) a plurality of metal species distributed within the polymer. At least a portion of the heteroatoms may form part of a chelation complex with some or all of the metal species. In many embodiments, the metal species are present in a sufficient concentration to provide a conductive material, e.g., as a conductive coating on a substrate. The conductive materials may be useful as the thin film conducting or semi-conducting layers in organic electronic devices such as organic electroluminescent devices and organic thin film transistors.

  2. Thermal conductivity of semitransparent materials

    SciTech Connect (OSTI)

    Fine, H.A.; Jury, S.H.; McElroy, D.L.; Yarbrough, D.W.

    1981-01-01

    The three-region approximate solution for coupled conductive and radiative heat transfer and an exact solution for uncoupled conductive and radiative heat transfer in a grey semitransparent medium bounded by infinite parallel isothermal plates are employed to establish the dependence of the apparent thermal conductivity of semitransparent materials on other material properties and boundary conditions. An application of the analyses which uses apparent thermal conductivity versus density data to predict the dependence of apparent thermal conductivity on temperature is demonstrated. The predictions for seven sets of R-11 fiberglass and rock wool insulations agree with published measured values to within the limits of experimental error (+- 3%). Agreement for three sets of R-19 fiberglass insulations was, however, not good.

  3. Calibration-free electrical conductivity measurements for highly conductive slags

    SciTech Connect (OSTI)

    MACDONALD,CHRISTOPHER J.; GAO,HUANG; PAL,UDAY B.; VAN DEN AVYLE,JAMES A.; MELGAARD,DAVID K.

    2000-05-01

    This research involves the measurement of the electrical conductivity (K) for the ESR (electroslag remelting) slag (60 wt.% CaF{sub 2} - 20 wt.% CaO - 20 wt.% Al{sub 2}O{sub 3}) used in the decontamination of radioactive stainless steel. The electrical conductivity is measured with an improved high-accuracy-height-differential technique that requires no calibration. This method consists of making continuous AC impedance measurements over several successive depth increments of the coaxial cylindrical electrodes in the ESR slag. The electrical conductivity is then calculated from the slope of the plot of inverse impedance versus the depth of the electrodes in the slag. The improvements on the existing technique include an increased electrochemical cell geometry and the capability of measuring high precision depth increments and the associated impedances. These improvements allow this technique to be used for measuring the electrical conductivity of highly conductive slags such as the ESR slag. The volatilization rate and the volatile species of the ESR slag measured through thermogravimetric (TG) and mass spectroscopy analysis, respectively, reveal that the ESR slag composition essentially remains the same throughout the electrical conductivity experiments.

  4. Electrical conductivity of pyrolyzed polyacrylonitrile

    SciTech Connect (OSTI)

    Teoh, H.; Metz, P.D.; Wilhelm, W.G.

    1981-01-01

    Using ultrapure samples of polyacrylonitrile (PAN) of 485,000 or 150,000 average molecular weight solution cast in dimethylformamide, the dc conductivity (sigma) of pyrolyzed PAN (PANP) films has been studied for pyrolysis temperatures (T/ sub p/) of 280 to 435/sup 0/C. Conductivity measurements made during pyrolysis indicate the onset of a dramatic increase in sigma for T/sub p/ of 390 to 435/sup 0/C. Conductivities as high as 5 (ohm-cm)/sup -1/ have been observed for T/sub p/ < 435/sup 0/C.

  5. Analysis of Hydraulic Conductivity Calculations

    SciTech Connect (OSTI)

    Green, R.E.

    2003-01-06

    Equations by Marshall and by Millington and Quirk for calculating hydraulic conductivity from pore-size distribution data are dependent on an arbitrary choice of the exponent on the porosity term and a correct estimate of residual water. This study showed that a revised equation, based on the pore-interaction model of Marshall, accurately predicts hydraulic conductivity for glass beads and a loam soil from the pressure-water content relationships of these porous materials.

  6. Conductive Channel for Energy Transmission

    SciTech Connect (OSTI)

    Apollonov, Victor V.

    2011-11-10

    For many years the attempts to create conductive channels of big length were taken in order to study the upper atmosphere and to settle special tasks, related to energy transmission. There upon the program of creation of 'Impulsar' represents a great interest, as this program in a combination with high-voltage high repetition rate electrical source can be useful to solve the above mentioned problems (N. Tesla ideas for the days of high power lasers). The principle of conductive channel production can be shortly described as follows. The 'Impulsar' - laser jet engine vehicle - propulsion take place under the influence of powerful high repetition rate pulse-periodic laser radiation. In the experiments the CO{sub 2}-laser and solid state Nd:YAG laser systems had been used. Active impulse appears thanks to air breakdown (<30 km) or to the breakdown of ablated material on the board (>30 km), placed in the vicinity of the focusing mirror-acceptor of the breakdown waves. With each pulse of powerful laser the device rises up, leaving a bright and dense trace of products with high degree of ionization and metallization by conductive nano-particles due to ablation. Conductive dust plasma properties investigation in our experiments was produced by two very effective approaches: high power laser controlled ablation and by explosion of wire. Experimental and theoretical results of conductive canal modeling will be presented. The estimations show that with already experimentally demonstrated figures of specific thrust impulse the lower layers of the Ionosphere can be reached in several ten seconds that is enough to keep the high level of channel conductivity and stability with the help of high repetition rate high voltage generator. Some possible applications for new technology are highlighted.

  7. Lithium ion conducting ionic electrolytes

    DOE Patents [OSTI]

    Angell, C. Austen; Xu, Kang; Liu, Changle

    1996-01-01

    A liquid, predominantly lithium-conducting, ionic electrolyte is described which has exceptionally high conductivity at temperatures of 100.degree. C. or lower, including room temperature. It comprises molten lithium salts or salt mixtures in which a small amount of an anionic polymer lithium salt is dissolved to stabilize the liquid against recrystallization. Further, a liquid ionic electrolyte which has been rubberized by addition of an extra proportion of anionic polymer, and which has good chemical and electrochemical stability, is described. This presents an attractive alternative to conventional salt-in-polymer electrolytes which are not cationic conductors.

  8. Lithium ion conducting ionic electrolytes

    DOE Patents [OSTI]

    Angell, C.A.; Xu, K.; Liu, C.

    1996-01-16

    A liquid, predominantly lithium-conducting, ionic electrolyte is described which has exceptionally high conductivity at temperatures of 100 C or lower, including room temperature. It comprises molten lithium salts or salt mixtures in which a small amount of an anionic polymer lithium salt is dissolved to stabilize the liquid against recrystallization. Further, a liquid ionic electrolyte which has been rubberized by addition of an extra proportion of anionic polymer, and which has good chemical and electrochemical stability, is described. This presents an attractive alternative to conventional salt-in-polymer electrolytes which are not cationic conductors. 4 figs.

  9. Quick estimating for thermal conductivity

    SciTech Connect (OSTI)

    Sastri, S.R.S.; Rao, K.K. )

    1993-08-01

    Accurate values for thermal conductivity--an important engineering property used in heat transfer calculations of liquids--are not as readily available as those for other physical properties. Therefore, it often becomes necessary to use estimated data. A new estimating method combines ease of use with an accuracy that is generally better than existing procedures. The paper discusses how to select terms and testing correlations, then gives two examples of the use of the method for calculation of the thermal conductivity of propionic acid and chlorobenzene.

  10. Thin film ion conducting coating

    DOE Patents [OSTI]

    Goldner, Ronald B.; Haas, Terry; Wong, Kwok-Keung; Seward, George

    1989-01-01

    Durable thin film ion conducting coatings are formed on a transparent glass substrate by the controlled deposition of the mixed oxides of lithium:tantalum or lithium:niobium. The coatings provide durable ion transport sources for thin film solid state storage batteries and electrochromic energy conservation devices.

  11. Electrically conductive rigid polyurethane foam

    DOE Patents [OSTI]

    Neet, Thomas E. (Grandview, MO); Spieker, David A. (Olathe, KS)

    1985-03-19

    A rigid, polyurethane foam comprises about 2-10 weight percent, based on the total foam weight, of a carbon black which is CONDUCTEX CC-40-220 or CONDUCTEX SC, whereby the rigid polyurethane foam is electrically conductive and has essentially the same mechanical properties as the same foam without carbon black added.

  12. Planning and Conducting Readiness Reviews

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2010-05-06

    This Standard provides standardized methods and approaches for planning and conducting RRs. This Standard also provides guidance for preparation of exemption requests in accordance with DOE O 251.1C. DOE O 425.1D requirements for RRs apply both to responsible contractors and to DOE

  13. Electrically conductive rigid polyurethane foam

    DOE Patents [OSTI]

    Neet, T.E.; Spieker, D.A.

    1983-12-08

    A rigid, moldable polyurethane foam comprises about 2 to 10 weight percent, based on the total foam weight, of a carbon black which is CONDUCTEX CC-40-220 or CONDUCTEX SC, whereby the rigid polyurethane foam is electrically conductive and has essentially the same mechanical properties as the same foam without carbon black added.

  14. Conduction at a ferroelectric interface

    SciTech Connect (OSTI)

    Marshall, Matthew S. J.; Malashevich, Andrei; Disa, Ankit S.; Han, Myung -Geun; Chen, Hanghui; Zhu, Yimei; Ismail-Beigi, Sohrab; Walker, Frederick J.; Ahn, Charles H.

    2014-11-05

    Typical logic elements utilizing the field effect rely on the change in carrier concentration due to the field in the channel region of the device. Ferroelectric-field-effect devices provide a nonvolatile version of this effect due to the stable polarization order parameter in the ferroelectric. In this study, we describe an oxide/oxide ferroelectric heterostructure device based on (001)-oriented PbZr??.?Ti?.?O?-LaNiO? where the dominant change in conductivity is a result of a significant mobility change in the interfacial channel region. The effect is confined to a few atomic layers at the interface and is reversible by switching the ferroelectric polarization. More interestingly, in one polarization state, the field effect induces a 1.7 eV shift of the interfacial bands to create a new conducting channel in the interfacial PbO layer of the ferroelectric.

  15. Conduction at a ferroelectric interface

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Marshall, Matthew S. J.; Malashevich, Andrei; Disa, Ankit S.; Han, Myung -Geun; Chen, Hanghui; Zhu, Yimei; Ismail-Beigi, Sohrab; Walker, Frederick J.; Ahn, Charles H.

    2014-11-05

    Typical logic elements utilizing the field effect rely on the change in carrier concentration due to the field in the channel region of the device. Ferroelectric-field-effect devices provide a nonvolatile version of this effect due to the stable polarization order parameter in the ferroelectric. In this study, we describe an oxide/oxide ferroelectric heterostructure device based on (001)-oriented PbZr₀̣.₂Ti₀.₈O₃-LaNiO₃ where the dominant change in conductivity is a result of a significant mobility change in the interfacial channel region. The effect is confined to a few atomic layers at the interface and is reversible by switching the ferroelectric polarization. More interestingly, inmore » one polarization state, the field effect induces a 1.7 eV shift of the interfacial bands to create a new conducting channel in the interfacial PbO layer of the ferroelectric.« less

  16. Conduction at a ferroelectric interface

    SciTech Connect (OSTI)

    Marshall, Matthew S. J.; Malashevich, Andrei; Disa, Ankit S.; Han, Myung-Guen; Chen, Hanghui; Zhu, Yimei; Ismail-Beigi, Sohrab; Walker, Frederick J.; Ahn, Charles H.

    2014-11-05

    Typical logic elements utilizing the field effect rely on the change in carrier concentration due to the field in the channel region of the device. Ferroelectric-field-effect devices provide a nonvolatile version of this effect due to the stable polarization order parameter in the ferroelectric. In this work, we describe an oxide/ oxide ferroelectric heterostructure device based on (001)-oriented PbZr??.?Ti?.?O?-LaNiO? where the dominant change in conductivity is a result of a significant mobility change in the interfacial channel region. The effect is confined to a few atomic layers at the interface and is reversible by switching the ferroelectric polarization. More interestingly, in one polarization state, the field effect induces a 1.7-eV shift of the interfacial bands to create a new conducting channel in the interfacial PbO layer of the ferroelectric.

  17. Electrically conductive polymer concrete coatings

    DOE Patents [OSTI]

    Fontana, J.J.; Elling, D.; Reams, W.

    1990-03-13

    A sprayable electrically conductive polymer concrete coating for vertical d overhead applications is described. The coating is permeable yet has low electrical resistivity (<10 ohm-cm), good bond strength to concrete substrates, and good weatherability. A preferred formulation contains about 60 wt % calcined coke breeze, 40 wt % vinyl ester with 3.5 wt % modified bentonite clay. Such formulations apply evenly and provide enough rigidity for vertical or overhead structures so there is no drip or sag.

  18. Electrically conductive polymer concrete coatings

    DOE Patents [OSTI]

    Fontana, Jack J.; Elling, David; Reams, Walter

    1990-01-01

    A sprayable electrically conductive polymer concrete coating for vertical d overhead applications is described. The coating is permeable yet has low electrical resistivity (<10 ohm-cm), good bond strength to concrete substrates, and good weatherability. A preferred formulation contains about 60 wt % calcined coke breeze, 40 wt % vinyl ester with 3.5 wt % modified bentonite clay. Such formulations apply evenly and provide enough rigidity for vertical or overhead structures so there is no drip or sag.

  19. Planning and Conducting Readiness Reviews

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    3006-2010 ________________________ Superseding DOE-STD-3006-2000 June 2000 DOE STANDARD PLANNING AND CONDUCTING READINESS REVIEWS U.S. Department of Energy AREA OPER Washington, D.C. 20585 DISTRIBUTION STATEMENT A. Approved for public release; distribution is unlimited. TS This document has been reproduced directly from the best available copy. Available to DOE and DOE contractors from ES&H Technical Information Services, U.S. Department of Energy, (800) 473-4375, fax: (301) 903-9823.

  20. Electrically conductive polymer concrete coatings

    DOE Patents [OSTI]

    Fontana, J.J.; Elling, D.; Reams, W.

    1988-05-26

    A sprayable electrically conductive polymer concrete coating for vertical and overhead applications is described. The coating is permeable yet has low electrical resistivity (<10 ohm-cm), good bond strength to concrete substrates, and good weatherability. A preferred formulation contains about 60 wt% calcined coke breeze, 40 wt% vinyl ester resin with 3.5 wt% modified bentonite clay. Such formulations apply evenly and provide enough rigidity for vertical or overhead structures so there is no drip or sag. 4 tabs.

  1. Conduct of operations implementation plan

    SciTech Connect (OSTI)

    Anderson, C.K.; Hall, R.L.

    1991-02-20

    This implementation plan describes the process and provides information and schedules that are necessary to implement and comply with the Department of Energy (DOE) Order 5480.19, {open_quotes}Conduct of Operations{close_quotes} (CoOp). This plan applies to all Pinellas Plant operations and personnel. Generally, this Plan discusses how DOE Order 5480.19 will be implemented at the Pinellas Plant.

  2. Hydraulic Conductivity Measurements Barrow 2014

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Katie McKnight; Tim Kneafsey; Craig Ulrich; Jil Geller

    2015-02-22

    Six individual ice cores were collected from Barrow Environmental Observatory in Barrow, Alaska, in May of 2013 as part of the Next Generation Ecosystem Experiment (NGEE). Each core was drilled from a different location at varying depths. A few days after drilling, the cores were stored in coolers packed with dry ice and flown to Lawrence Berkeley National Laboratory (LBNL) in Berkeley, CA. 3-dimensional images of the cores were constructed using a medical X-ray computed tomography (CT) scanner at 120kV. Hydraulic conductivity samples were extracted from these cores at LBNL Richmond Field Station in Richmond, CA, in February 2014 by cutting 5 to 8 inch segments using a chop saw. Samples were packed individually and stored at freezing temperatures to minimize any changes in structure or loss of ice content prior to analysis. Hydraulic conductivity was determined through falling head tests using a permeameter [ELE International, Model #: K-770B]. After approximately 12 hours of thaw, initial falling head tests were performed. Two to four measurements were collected on each sample and collection stopped when the applied head load exceeded 25% change from the original load. Analyses were performed between 2 to 3 times for each sample. The final hydraulic conductivity calculations were computed using methodology of Das et al., 1985.

  3. One-Dimensional Heat Conduction

    Energy Science and Technology Software Center (OSTI)

    1992-03-09

    ICARUS-LLNL was developed to solve one-dimensional planar, cylindrical, or spherical conduction heat transfer problems. The IBM PC version is a family of programs including ICARUSB, an interactive BASIC heat conduction program; ICARUSF, a FORTRAN heat conduction program; PREICAR, a BASIC preprocessor for ICARUSF; and PLOTIC and CPLOTIC, interpretive BASIC and compiler BASIC plot postprocessor programs. Both ICARUSB and ICARUSF account for multiple material regions and complex boundary conditions, such as convection or radiation. In addition,more » ICARUSF accounts for temperature-dependent material properties and time or temperature-dependent boundary conditions. PREICAR is a user-friendly preprocessor used to generate or modify ICARUSF input data. PLOTIC and CPLOTIC generate plots of the temperature or heat flux profile at specified times, plots of the variation of temperature or heat flux with time at selected nodes, or plots of the solution grid. First developed in 1974 to allow easy modeling of complex one-dimensional systems, its original application was in the nuclear explosive testing program. Since then it has undergone extensive revision and been applied to problems dealing with laser fusion target fabrication, heat loads on underground tests, magnetic fusion switching tube anodes, and nuclear waste isolation canisters.« less

  4. Hydraulic Conductivity Measurements Barrow 2014

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    Katie McKnight; Tim Kneafsey; Craig Ulrich; Jil Geller

    Six individual ice cores were collected from Barrow Environmental Observatory in Barrow, Alaska, in May of 2013 as part of the Next Generation Ecosystem Experiment (NGEE). Each core was drilled from a different location at varying depths. A few days after drilling, the cores were stored in coolers packed with dry ice and flown to Lawrence Berkeley National Laboratory (LBNL) in Berkeley, CA. 3-dimensional images of the cores were constructed using a medical X-ray computed tomography (CT) scanner at 120kV. Hydraulic conductivity samples were extracted from these cores at LBNL Richmond Field Station in Richmond, CA, in February 2014 by cutting 5 to 8 inch segments using a chop saw. Samples were packed individually and stored at freezing temperatures to minimize any changes in structure or loss of ice content prior to analysis. Hydraulic conductivity was determined through falling head tests using a permeameter [ELE International, Model #: K-770B]. After approximately 12 hours of thaw, initial falling head tests were performed. Two to four measurements were collected on each sample and collection stopped when the applied head load exceeded 25% change from the original load. Analyses were performed between 2 to 3 times for each sample. The final hydraulic conductivity calculations were computed using methodology of Das et al., 1985.

  5. THERMAL CONDUCTIVITY ANALYSIS OF GASES

    DOE Patents [OSTI]

    Clark, W.J.

    1949-06-01

    This patent describes apparatus for the quantitative analysis of a gaseous mixture at subatmospheric pressure by measurement of its thermal conductivity. A heated wire forms one leg of a bridge circuit, while the gas under test is passed about the wire at a constant rate. The bridge unbalance will be a measure of the change in composition of the gas, if compensation is made for the effect due to gas pressure change. The apparatus provides a voltage varying with fluctuations of pressure in series with the indicating device placed across the bridge, to counterbalance the voltage change caused by fluctuations in the pressure of the gaseous mixture.

  6. Water-soluble conductive polymers

    DOE Patents [OSTI]

    Aldissi, Mahmoud

    1990-01-01

    Polymers which are soluble in water and are electrically conductive. The monomer repeat unit is a thiophene or pyrrole molecule having an alkyl group substituted for the hydrogen atom located in the beta position of the thiophene or pyrrole ring and having a surfactant molecule at the end of the alkyl chain. Polymers of this class having 8 or more carbon atoms in the alkyl chain exhibit liquid crystalline behavior, resulting in high electrical anisotropy. The monomer-to-monomer bonds are located between the carbon atoms which are adjacent to the sulfur or nitrogen atoms. The number of carbon atoms in the alkyl group may vary from 1 to 20 carbon atoms. The surfactant molecule consists of a sulfonate group, or a sulfate group, or a carboxylate group, and hydrogen or an alkali metal. Negative ions from a supporting electrolyte which may be used in the electrochemical synthesis of a polymer may be incorporated into the polymer during the synthesis and serve as a dopant to increase the conductivity.

  7. Water-soluble conductive polymers

    DOE Patents [OSTI]

    Aldissi, Mahmoud

    1989-01-01

    Polymers which are soluble in water and are electrically conductive. The monomer repeat unit is a thiophene or pyrrole molecule having an alkyl group substituted for the hydrogen atom located in the beta position of the thiophene or pyrrole ring and having a surfactant molecule at the end of the alkyl chain. Polymers of this class having 8 or more carbon atoms in the alkyl chain exhibit liquid crystalline behavior, resulting in high electrical anisotropy. The monomer-to-monomer bonds are located between the carbon atoms which are adjacent to the sulfur or nitrogen atoms. The number of carbon atoms in the alkyl group may vary from 1 to 20 carbon atoms. The surfactant molecule consists of a sulfonate group, or a sulfate group, or a carboxylate group, and hydrogen or an alkali metal. Negative ions from a supporting electrolyte which may be used in the electrochemical synthesis of a polymer may be incorporated into the polymer during the synthesis and serve as a dopant to increase the conductivity.

  8. Water-soluble conductive polymers

    DOE Patents [OSTI]

    Aldissi, M.

    1988-02-12

    Polymers which are soluble in water and are electrically conductive. The monomer repeat unit is a thiophene or pyrrole molecule having an alkyl group substituted for the hydrogen atom located in the beta position of the thiophene or pyrrole ring and having a surfactant molecule at the end of the alkyl chain. Polymers of this class having 8 or more carbon atoms in the alkyl chain exhibit liquid crystalline behavior, resulting in high electrical anisotropy. The monomer-to-monomer bonds are located between the carbon atoms which are adjacent to the sulfur or nitrogen atoms. The number of carbon atoms in the alkyl group may vary from 1 to 20 carbon atoms. The surfactant molecule consists of a sulfonate group, or a sulfate group, or a carboxylate group, and hydrogen or an alkali metal. Negative ions from a supporting electrolyte which may be used in the electrochemical synthesis of a polymer may be incorporated into the polymer during the synthesis and serve as a dopant to increase the conductivity.

  9. Electrolytic decontamination of conductive materials

    SciTech Connect (OSTI)

    Nelson, T.O.; Campbell, G.M.; Parker, J.L.; Getty, R.H.; Hergert, T.R.; Lindahl, K.A.; Peppers, L.G.

    1993-10-01

    Using the electrolytic method, the authors have demonstrated removal of Pu from contaminated conductive material. At EG&G Rocky Flats, they electrolytically decontaminated stainless steel. Results from this work show removal of fixed contamination, including the following geometries: planar, large radius, bolt holes, glove ports, and protruding studs. More specifically, fixed contamination was reduced from levels ranging > 1,000,000 counts per minute (cpm) down to levels ranging from 1,500 to < 250 cpm with the electrolytic method. More recently, the electrolytic work has continued at LANL as a joint project with EG&G. Impressively, electrolytic decontamination experiments on removal of Pu from oralloy coupons have shown decreases in swipable contamination that initially ranged from 500,000 to 1,500,000 disintegrations per minute (dpm) down to 0--2 dpm.

  10. Anion Exchange Membranes - Transport/Conductivity | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    - TransportConductivity Anion Exchange Membranes - TransportConductivity Presentation at the AMFC Workshop, May 8-9, 2011, Arlington, VA PDF icon amfc110811aemstransport.pdf ...

  11. Precise Application of Transparent Conductive Oxide Coatings...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Precise Application of Transparent Conductive Oxide Coatings for Flat Panel Displays and Photovoltaic Cells Technology available for licensing: New transparent conducting oxide ...

  12. California: Conducting Polymer Binder Boosts Storage Capacity...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Conducting Polymer Binder Boosts Storage Capacity, Wins R&D 100 Award California: Conducting Polymer Binder Boosts Storage Capacity, Wins R&D 100 Award August 19, 2013 - 10:17am ...

  13. CRAD, NNSA- Conduct of Operations (OP)

    Broader source: Energy.gov [DOE]

    CRAD for Conduct of Operations (OP). Criteria Review and Approach Documents (CRADs) that can be used to conduct a well-organized and thorough assessment of elements of safety and health programs.

  14. NNSA Conducts International Radiological Response Training in...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NNSA Conducts International Radiological Response Training in Vienna August 01, 2013 ... Radiological Assistance Program Training for Emergency Response Advanced ...

  15. Fabrication of glass microspheres with conducting surfaces

    DOE Patents [OSTI]

    Elsholz, William E.

    1984-01-01

    A method for making hollow glass microspheres with conducting surfaces by adding a conducting vapor to a region of the glass fabrication furnace. As droplets or particles of glass forming material pass through multiple zones of different temperature in a glass fabrication furnace, and are transformed into hollow glass microspheres, the microspheres pass through a region of conducting vapor, forming a conducting coating on the surface of the microspheres.

  16. Fabrication of glass microspheres with conducting surfaces

    DOE Patents [OSTI]

    Elsholz, W.E.

    1982-09-30

    A method for making hollow glass microspheres with conducting surfaces by adding a conducting vapor to a region of the glass fabrication furnace. As droplets or particles of glass forming material pass through multiple zones of different temperature in a glass fabrication furnace, and are transformed into hollow glass microspheres, the microspheres pass through a region of conducting vapor, forming a conducting coating on the surface of the microspheres.

  17. Organic conductive films for semiconductor electrodes

    DOE Patents [OSTI]

    Frank, A.J.

    1984-01-01

    According to the present invention, improved electrodes overcoated with conductive polymer films and preselected catalysts are provided. The electrodes typically comprise an inorganic semiconductor over-coated with a charge conductive polymer film comprising a charge conductive polymer in or on which is a catalyst or charge-relaying agent.

  18. The Workshop on Conductive Polymers: Final Report

    DOE R&D Accomplishments [OSTI]

    1985-10-01

    Reports are made by groups on: polyacetylene, polyphenylene, polyaniline, and related systems; molecular, crystallographic, and defect structures in conducting polymers; heterocyclic polymers; synthesis of new and improved conducting polymers; future applications possibilities for conducting polymers; and challenges for improved understanding of properties. (DLC)

  19. Organic conductive films for semiconductor electrodes

    DOE Patents [OSTI]

    Frank, Arthur J.

    1984-01-01

    According to the present invention, improved electrodes overcoated with conductive polymer films and preselected catalysts are provided. The electrodes typically comprise an inorganic semiconductor overcoated with a charge conductive polymer film comprising a charge conductive polymer in or on which is a catalyst or charge-relaying agent.

  20. Enhanced Mixed Electronic-Ionic Conductors through Cation Ordering

    SciTech Connect (OSTI)

    Jacobson, Allan J.; Morgan, Dane; Grey, Clare

    2014-08-31

    The performance of many energy conversion and storage devices depend on the properties of mixed ionic-electronic conducting (miec) materials. Mixed or ambipolar conductors simultaneously transport ions and electrons and provide the critical interface between chemical and electrical energy in devices such as fuel cells, ion transport membranes, and batteries. Enhancements in storage capacity, reversibility, power density and device lifetime all require new materials and a better understanding of the fundamentals of ambipolar conductivity and surface reactivity.The high temperature properties of the ordered perovksites AA’B2O5+x, where A = rare earth ion, Y and B = Ba, Sr were studied. The work was motivated by the high oxygen transport and surface exchange rates observed for members of this class of mixed ionic and electronic conductors. A combined experimental and computational approach, including structural, electrochemical, and transport characterization and modeling was used. The approach attacks the problem simultaneously at global (e.g., neutron diffraction and impedance spectroscopy), local (e.g., pair distribution function, nuclear magnetic resonance) and molecular (ab initio thermokinetic modeling) length scales. The objectives of the work were to understand how the cation and associated anion order lead to exceptional ionic and electronic transport properties and surface reactivity in AA’B2O5+x perovskites. A variety of compounds were studied by X-ray and neutron diffraction, measurements of thermodynamics and transport and theoretically. These included PrBaCo2O5+x and NdBaCo2O5+x, PrBaCo2-xFexO6- δ (x = 0, 0.5, 1.0, 1.5 and 2) and LnBaCoFeO6- δ (Ln = La, Pr, Nd, Sm, Eu and Gd), Sr3YCo4O10.5, YBaMn2O5+x. A0.5A’0.5BO3 (where A=Y, Sc, La, Ce, Pr, Nd, Pm, Sm; A’= Sr

  1. Cascade solar cell having conductive interconnects

    DOE Patents [OSTI]

    Borden, Peter G.; Saxena, Ram R.

    1982-10-26

    Direct ohmic contact between the cells in an epitaxially grown cascade solar cell is obtained by means of conductive interconnects formed through grooves etched intermittently in the upper cell. The base of the upper cell is directly connected by the conductive interconnects to the emitter of the bottom cell. The conductive interconnects preferably terminate on a ledge formed in the base of the upper cell.

  2. Conductivities and Seebeck Coefficients of Boron Carbides:'...

    Office of Scientific and Technical Information (OSTI)

    Coefficients of Boron Carbides: ''Softening-Bipolaron'' Hopping Citation Details In-Document Search Title: Conductivities and Seebeck Coefficients of Boron Carbides: ...

  3. Continuous Processing of High Thermal Conductivity Polyethylene...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Continuous Processing of High Thermal Conductivity Polyethylene Fibers and Sheets Massachusetts Institute of Technology (MIT) - Cambridge, MA A new, continuous manufacturing ...

  4. Continuous Processing of High Thermal Conductivity Polyethylene...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    conductivity polyethylene fibers and sheets will be developed to replace metals and ceramics in heat-transfer devices. Project innovations include using massively parallel...

  5. Conductive polymeric compositions for lithium batteries (Patent...

    Office of Scientific and Technical Information (OSTI)

    The conductivity at high temperatures and wide electrochemical window make these materials especially suitable as electrolytes for rechargeable lithium batteries. Inventors: ...

  6. Conductivities and Seebeck Coefficients of Boron Carbides:'...

    Office of Scientific and Technical Information (OSTI)

    Country of Publication: United States Language: English Subject: 36 MATERIALS SCIENCE; BORON CARBIDES; STABILIZATION; THERMAL CONDUCTIVITY; SEEBECK EFFECT Word Cloud More Like This ...

  7. Morphology in electrochemically grown conducting polymer films

    DOE Patents [OSTI]

    Rubinstein, I.; Gottesfeld, S.; Sabatani, E.

    1992-04-28

    A conducting polymer film with an improved space filling is formed on a metal electrode surface. A self-assembling monolayer is formed directly on the metal surface where the monolayer has a first functional group that binds to the metal surface and a second chemical group that forms a chemical bonding site for molecules forming the conducting polymer. The conducting polymer is then conventionally deposited by electrochemical deposition. In one example, a conducting film of polyaniline is formed on a gold electrode surface with an intermediate monolayer of p-aminothiophenol. 2 figs.

  8. EPA -- Addressing Children's Health through Reviews Conducted...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    EPA -- Addressing Children's Health through Reviews Conducted Pursuant to the National Environmental Policy Act and Section 309 of the Clean Air Act EPA -- Addressing Children's ...

  9. CRAD, Conduct of Operations Assessment Plan

    Office of Energy Efficiency and Renewable Energy (EERE)

    The purpose of this assessment is to verify programmatic implementation of DOE O 5480.19, "Conduct of Operations Requirements of DOE Facilities"

  10. Low temperature proton conducting oxide devices

    DOE Patents [OSTI]

    Armstrong, Timothy R.; Payzant, Edward A.; Speakman, Scott A.; Greenblatt, Martha

    2008-08-19

    A device for conducting protons at a temperature below 550.degree. C. includes a LAMOX ceramic body characterized by an alpha crystalline structure.

  11. Synthesis of polymer nanostructures with conductance switching...

    Office of Scientific and Technical Information (OSTI)

    The present invention is directed to crystalline organic polymer nanoparticles comprising a conductive organic polymer; wherein the crystalline organic polymer nanoparticles have a size ...

  12. Lithium Ion Conducting Ionic Electrolytes - Energy Innovation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Storage Energy Storage Find More Like This Return to Search Lithium Ion Conducting ... electrolytes which combine lithium salts with high molecular weight anionic polymers. ...

  13. Morphology in electrochemically grown conducting polymer films

    DOE Patents [OSTI]

    Rubinstein, Israel; Gottesfeld, Shimshon; Sabatani, Eyal

    1992-01-01

    A conducting polymer film with an improved space filling is formed on a metal electrode surface. A self-assembling monolayer is formed directly on the metal surface where the monolayer has a first functional group that binds to the metal surface and a second chemical group that forms a chemical bonding site for molecules forming the conducting polymer. The conducting polymer is then conventioonally deposited by electrochemical deposition. In one example, a conducting film of polyaniline is formed on a gold electrode surface with an intermediate monolayer of p-aminothiophenol.

  14. Industrial Energy Audit Guidebook: Guidelines for Conducting...

    Open Energy Info (EERE)

    audit, conducting an inventory and measuring energy use, analyzing energy bills, benchmarking, analyzing energy use patterns, identifying energy-efficiency opportunities,...

  15. Controlling thermal conductance through quantum dot roughening...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Controlling thermal conductance through quantum dot roughening at interfaces. Citation Details ... Publication Date: 2011-01-01 OSTI Identifier: 1110382 Report ...

  16. Flexible moldable conductive current-limiting materials

    DOE Patents [OSTI]

    Shea, John Joseph; Djordjevic, Miomir B.; Hanna, William Kingston

    2002-01-01

    A current limiting PTC device (10) has two electrodes (14) with a thin film of electric conducting polymer material (20) disposed between the electrodes, the polymer material (20) having superior flexibility and short circuit performance, where the polymer material contains short chain aliphatic diepoxide, conductive filler particles, curing agent, and, preferably, a minor amount of bisphenol A epoxy resin.

  17. Proton conducting membrane for fuel cells

    DOE Patents [OSTI]

    Colombo, Daniel G.; Krumpelt, Michael; Myers, Deborah J.; Kopasz, John P.

    2005-12-20

    An ion conducting membrane comprising dendrimeric polymers covalently linked into a network structure. The dendrimeric polymers have acid functional terminal groups and may be covalently linked via linking compounds, cross-coupling reactions, or copolymerization reactions. The ion conducting membranes may be produced by various methods and used in fuel cells.

  18. Proton conducting membrane for fuel cells

    DOE Patents [OSTI]

    Colombo, Daniel G.; Krumpelt, Michael; Myers, Deborah J.; Kopasz, John P.

    2007-03-27

    An ion conducting membrane comprising dendrimeric polymers covalently linked into a network structure. The dendrimeric polymers have acid functional terminal groups and may be covalently linked via linking compounds, cross-coupling reactions, or copolymerization reactions. The ion conducting membranes may be produced by various methods and used in fuel cells.

  19. Liquid crystal-templated conducting organic polymers

    DOE Patents [OSTI]

    Stupp, Samuel I.; Hulvat, James F.

    2004-01-20

    A method of preparing a conductive polymeric film, includes providing a liquid crystal phase comprising a plurality of hydrophobic cores, the phase on a substrate, introducing a hydrophobic component to the phase, the component a conductive polymer precursor, and applying an electric potential across the liquid crystal phase, the potential sufficient to polymerize the said precursor.

  20. Proton conducting ceramic membranes for hydrogen separation

    DOE Patents [OSTI]

    Elangovan, S.; Nair, Balakrishnan G.; Small, Troy; Heck, Brian

    2011-09-06

    A multi-phase proton conducting material comprising a proton-conducting ceramic phase and a stabilizing ceramic phase. Under the presence of a partial pressure gradient of hydrogen across the membrane or under the influence of an electrical potential, a membrane fabricated with this material selectively transports hydrogen ions through the proton conducting phase, which results in ultrahigh purity hydrogen permeation through the membrane. The stabilizing ceramic phase may be substantially structurally and chemically identical to at least one product of a reaction between the proton conducting phase and at least one expected gas under operating conditions of a membrane fabricated using the material. In a barium cerate-based proton conducting membrane, one stabilizing phase is ceria.

  1. WETTING AND REACTIVE AIR BRAZING OF BSCF FOR OXYGEN SEPARATION DEVICES

    SciTech Connect (OSTI)

    LaDouceur, Richard M.; Meier, Alan; Joshi, Vineet V.

    2014-10-13

    Reactive air brazes Ag-CuO and Ag-V2O5 were evaluated for brazing Ba0.5Sr0.5Co0.8Fe0.2O(3-δ) (BSCF). BSCF has been determined in previous work to have the highest potential mixed ionic/electronic conducting (MIEC) ceramic material based on the design and oxygen flux requirements of an oxy-fuel plant such as an integrated gasification combined cycle (IGCC) used to facilitate high-efficiency carbon capture. Apparent contact angles were observed for Ag-CuO and Ag-V2O5 mixtures at 1000 °C for isothermal hold times of 0, 10, 30, and 60 minutes. Wetting apparent contact angles (θ<90°) were obtained for 1%, 2%, and 5% Ag-CuO and Ag-V2O5 mixtures, with the apparent contact angles between 74° and 78° for all compositions and furnace dwell times. Preliminary microstructural analysis indicates that two different interfacial reactions are occurring: Ag-CuO interfacial microstructures revealed the same dissolution of copper oxide into the BSCF matrix to form copper-cobalt-oxygen rich dissolution products along the BSCF grain boundaries and Ag-V2O5 interfacial microstructures revealed the infiltration and replacement of cobalt and iron with vanadium and silver filling pores in the BSCF microstructure. The Ag-V2O5 interfacial reaction product layer was measured to be significantly thinner than the Ag-CuO reaction product layer. Using a fully articulated four point flexural bend test fixture, the flexural fracture strength for BSCF was determined to be 95 ± 33 MPa. The fracture strength will be used to ascertain the success of the reactive air braze alloys. Based on these results, brazes were fabricated and mechanically tested to begin to optimize the brazing parameters for this system. Ag-2.5% CuO braze alloy with a 2.5 minute thermal cycle achieved a hermetic seal with a joint flexural strength of 34 ± 15 MPa and Ag-1% V2O5 with a 30 minute thermal cycle had a joint flexural strength of 20 ± 15 MPa.

  2. Thermal conductivity measurements of Summit polycrystalline silicon.

    SciTech Connect (OSTI)

    Clemens, Rebecca; Kuppers, Jaron D.; Phinney, Leslie Mary

    2006-11-01

    A capability for measuring the thermal conductivity of microelectromechanical systems (MEMS) materials using a steady state resistance technique was developed and used to measure the thermal conductivities of SUMMiT{trademark} V layers. Thermal conductivities were measured over two temperature ranges: 100K to 350K and 293K to 575K in order to generate two data sets. The steady state resistance technique uses surface micromachined bridge structures fabricated using the standard SUMMiT fabrication process. Electrical resistance and resistivity data are reported for poly1-poly2 laminate, poly2, poly3, and poly4 polysilicon structural layers in the SUMMiT process from 83K to 575K. Thermal conductivity measurements for these polysilicon layers demonstrate for the first time that the thermal conductivity is a function of the particular SUMMiT layer. Also, the poly2 layer has a different variation in thermal conductivity as the temperature is decreased than the poly1-poly2 laminate, poly3, and poly4 layers. As the temperature increases above room temperature, the difference in thermal conductivity between the layers decreases.

  3. Increased thermal conductivity monolithic zeolite structures

    DOE Patents [OSTI]

    Klett, James; Klett, Lynn; Kaufman, Jonathan

    2008-11-25

    A monolith comprises a zeolite, a thermally conductive carbon, and a binder. The zeolite is included in the form of beads, pellets, powders and mixtures thereof. The thermally conductive carbon can be carbon nano-fibers, diamond or graphite which provide thermal conductivities in excess of about 100 W/mK to more than 1,000 W/mK. A method of preparing a zeolite monolith includes the steps of mixing a zeolite dispersion in an aqueous colloidal silica binder with a dispersion of carbon nano-fibers in water followed by dehydration and curing of the binder is given.

  4. Electrical and thermal conductivities in dense plasmas

    SciTech Connect (OSTI)

    Faussurier, G. Blancard, C.; Combis, P.; Videau, L.

    2014-09-15

    Expressions for the electrical and thermal conductivities in dense plasmas are derived combining the Chester-Thellung-Kubo-Greenwood approach and the Kramers approximation. The infrared divergence is removed assuming a Drude-like behaviour. An analytical expression is obtained for the Lorenz number that interpolates between the cold solid-state and the hot plasma phases. An expression for the electrical resistivity is proposed using the Ziman-Evans formula, from which the thermal conductivity can be deduced using the analytical expression for the Lorenz number. The present method can be used to estimate electrical and thermal conductivities of mixtures. Comparisons with experiment and quantum molecular dynamics simulations are done.

  5. How the 2003 CBECS Was Conducted

    U.S. Energy Information Administration (EIA) Indexed Site

    to an establishment, is the basic unit of analysis for the CBECS because the building is the energy-consuming unit. The 2003 CBECS was the eighth survey conducted since...

  6. Program Evaluation: Planning and Conducting Evaluations

    Broader source: Energy.gov [DOE]

    This area of the website takes you through step-by-step processes for planning and conducting the In-progress Peer Reviews and Impact Evaluations described on this website. In general, for each...

  7. Thermal conductivity of thermal-battery insulations

    SciTech Connect (OSTI)

    Guidotti, R.A.; Moss, M.

    1995-08-01

    The thermal conductivities of a variety of insulating materials used in thermal batteries were measured in atmospheres of argon and helium using several techniques. (Helium was used to simulate the hydrogen atmosphere that results when a Li(Si)/FeS{sub 2} thermal battery ages.) The guarded-hot-plate method was used with the Min-K insulation because of its extremely low thermal conductivity. For comparison purposes, the thermal conductivity of the Min-K insulating board was also measured using the hot-probe method. The thermal-comparator method was used for the rigid Fiberfrax board and Fiberfrax paper. The thermal conductivity of the paper was measured under several levels of compression to simulate the conditions of the insulating wrap used on the stack in a thermal battery. The results of preliminary thermal-characterization tests with several silica aerogel materials are also presented.

  8. Domain wall conduction in multiaxial ferroelectrics

    SciTech Connect (OSTI)

    Eliseev, E. A.; Morozovska, A. N.; Svechnikov, S. V.; Maksymovych, Petro; Kalinin, Sergei V

    2012-01-01

    The conductance of domain wall structures consisting of either stripes or cylindrical domains in multiaxial ferroelectric-semiconductors is analyzed. The effects of the flexoelectric coupling, domain size, wall tilt, and curvature on charge accumulation are analyzed using the Landau-Ginsburg Devonshire theory for polarization vector combined with the Poisson equation for charge distributions. The proximity and size effect of the electron and donor accumulation/depletion by thin stripe domains and cylindrical nanodomains are revealed. In contrast to thick domain stripes and wider cylindrical domains, in which the carrier accumulation (and so the static conductivity) sharply increases at the domain walls only, small nanodomains of radii less than 5-10 correlation lengths appeared conducting across the entire cross-section. Implications of such conductive nanosized channels may be promising for nanoelectronics.

  9. Conductive polymeric compositions for lithium batteries

    DOE Patents [OSTI]

    Angell, Charles A.; Xu, Wu

    2009-03-17

    Novel chain polymers comprising weakly basic anionic moieties chemically bound into a polyether backbone at controllable anionic separations are presented. Preferred polymers comprise orthoborate anions capped with dibasic acid residues, preferably oxalato or malonato acid residues. The conductivity of these polymers is found to be high relative to that of most conventional salt-in-polymer electrolytes. The conductivity at high temperatures and wide electrochemical window make these materials especially suitable as electrolytes for rechargeable lithium batteries.

  10. Transparent conducting oxides and production thereof

    DOE Patents [OSTI]

    Gessert, Timothy A.; Yoshida, Yuki; Coutts, Timothy J.

    2014-06-10

    Transparent conducting oxides and production thereof are disclosed. An exemplary method of producing a transparent conducting oxide (TCO) material may comprise: providing a TCO target doped with either a high-permittivity oxide or a low-permittivity oxide in a process chamber. The method may also comprise depositing a metal oxide on the target in the process chamber to form a thin film having enhanced optical properties without substantially decreasing electrical quality.

  11. Transparent conducting oxides and production thereof

    DOE Patents [OSTI]

    Gessert, Timothy A; Yoshida, Yuki; Coutts, Timothy J

    2014-05-27

    Transparent conducting oxides and production thereof are disclosed. An exemplary method of producing a transparent conducting oxide (TCO) material may comprise: providing a TCO target (110) doped with either a high-permittivity oxide or a low-permittivity oxide in a process chamber (100). The method may also comprise depositing a metal oxide on the target (110) to form a thin film having enhanced optical properties without substantially decreasing electrical quality.

  12. High quality transparent conducting oxide thin films

    DOE Patents [OSTI]

    Gessert, Timothy A.; Duenow, Joel N.; Barnes, Teresa; Coutts, Timothy J.

    2012-08-28

    A transparent conducting oxide (TCO) film comprising: a TCO layer, and dopants selected from the elements consisting of Vanadium, Molybdenum, Tantalum, Niobium, Antimony, Titanium, Zirconium, and Hafnium, wherein the elements are n-type dopants; and wherein the transparent conducting oxide is characterized by an improved electron mobility of about 42 cm.sup.2/V-sec while simultaneously maintaining a high carrier density of .about.4.4e.times.10.sup.20 cm.sup.-3.

  13. Electrically conductive connection for an electrode

    DOE Patents [OSTI]

    Hornack, Thomas R.; Chilko, Robert J.

    1986-01-01

    An electrically conductive connection for an electrode assembly of an electrolyte cell in which aluminum is produced by electrolysis in a molten salt is described. The electrode assembly comprises an electrode flask and a conductor rod. The flask has a collar above an area of minimum flask diameter. The electrically conductive connection comprises the electrode flask, the conductor rod and a structure bearing against the collar and the conductor rod for pulling the conductor rod into compressive and electrical contact with the flask.

  14. Method and apparatus for casting conductive and semi-conductive materials

    DOE Patents [OSTI]

    Ciszek, T.F.

    1984-08-13

    A method and apparatus is disclosed for casting conductive and semi-conductive materials. The apparatus includes a plurality of conductive members arranged to define a container-like area having a desired cross-sectional shape. A portion or all of the conductive or semi-conductive material which is to be cast is introduced into the container-like area. A means is provided for inducing the flow of an electrical current in each of the conductive members, which currents act collectively to induce a current flow in the material. The induced current flow through the conductive members is in a direction substantially opposite to the induced current flow in the material so that the material is repelled from the conductive members during the casting process.

  15. Local measurement of thermal conductivity and diffusivity

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hurley, David H.; Schley, Robert S.; Khafizov, Marat; Wendt, Brycen L.

    2015-12-01

    Simultaneous measurement of local thermal diffusivity and conductivity is demonstrated on a range of ceramic samples. This was accomplished by measuring the temperature field spatial profile of samples excited by an amplitude modulated continuous wave laser beam. A thin gold film is applied to the samples to ensure strong optical absorption and to establish a second boundary condition that introduces an expression containing the substrate thermal conductivity. The diffusivity and conductivity are obtained by comparing the measured phase profile of the temperature field to a continuum based model. A sensitivity analysis is used to identify the optimal film thickness formore » extracting the both substrate conductivity and diffusivity. Proof of principle studies were conducted on a range of samples having thermal properties that are representative of current and advanced accident tolerant nuclear fuels. It is shown that by including the Kapitza resistance as an additional fitting parameter, the measured conductivity and diffusivity of all the samples considered agree closely with literature values. Lastly, a distinguishing feature of this technique is that it does not require a priori knowledge of the optical spot size which greatly increases measurement reliability and reproducibility.« less

  16. Local measurement of thermal conductivity and diffusivity

    SciTech Connect (OSTI)

    Hurley, David H.; Schley, Robert S.; Khafizov, Marat; Wendt, Brycen L.

    2015-12-01

    Simultaneous measurement of local thermal diffusivity and conductivity is demonstrated on a range of ceramic samples. This was accomplished by measuring the temperature field spatial profile of samples excited by an amplitude modulated continuous wave laser beam. A thin gold film is applied to the samples to ensure strong optical absorption and to establish a second boundary condition that introduces an expression containing the substrate thermal conductivity. The diffusivity and conductivity are obtained by comparing the measured phase profile of the temperature field to a continuum based model. A sensitivity analysis is used to identify the optimal film thickness for extracting the both substrate conductivity and diffusivity. Proof of principle studies were conducted on a range of samples having thermal properties that are representative of current and advanced accident tolerant nuclear fuels. It is shown that by including the Kapitza resistance as an additional fitting parameter, the measured conductivity and diffusivity of all the samples considered agree closely with literature values. Lastly, a distinguishing feature of this technique is that it does not require a priori knowledge of the optical spot size which greatly increases measurement reliability and reproducibility.

  17. Local measurement of thermal conductivity and diffusivity

    SciTech Connect (OSTI)

    Hurley, David H.; Schley, Robert S.; Khafizov, Marat; Wendt, Brycen L.

    2015-12-15

    Simultaneous measurement of local thermal diffusivity and conductivity is demonstrated on a range of ceramic samples. This was accomplished by measuring the temperature field spatial profile of samples excited by an amplitude modulated continuous wave laser beam. A thin gold film is applied to the samples to ensure strong optical absorption and to establish a second boundary condition that introduces an expression containing the substrate thermal conductivity. The diffusivity and conductivity are obtained by comparing the measured phase profile of the temperature field to a continuum based model. A sensitivity analysis is used to identify the optimal film thickness for extracting the both substrate conductivity and diffusivity. Proof of principle studies were conducted on a range of samples having thermal properties that are representatives of current and advanced accident tolerant nuclear fuels. It is shown that by including the Kapitza resistance as an additional fitting parameter, the measured conductivity and diffusivity of all the samples considered agreed closely with the literature values. A distinguishing feature of this technique is that it does not require a priori knowledge of the optical spot size which greatly increases measurement reliability and reproducibility.

  18. Gas storage carbon with enhanced thermal conductivity

    DOE Patents [OSTI]

    Burchell, Timothy D.; Rogers, Michael Ray; Judkins, Roddie R.

    2000-01-01

    A carbon fiber carbon matrix hybrid adsorbent monolith with enhanced thermal conductivity for storing and releasing gas through adsorption and desorption is disclosed. The heat of adsorption of the gas species being adsorbed is sufficiently large to cause hybrid monolith heating during adsorption and hybrid monolith cooling during desorption which significantly reduces the storage capacity of the hybrid monolith, or efficiency and economics of a gas separation process. The extent of this phenomenon depends, to a large extent, on the thermal conductivity of the adsorbent hybrid monolith. This invention is a hybrid version of a carbon fiber monolith, which offers significant enhancements to thermal conductivity and potential for improved gas separation and storage systems.

  19. Electrochemical characterization of aminated acrylic conducting polymer

    SciTech Connect (OSTI)

    Rashid, Norma Mohammad; Heng, Lee Yook; Ling, Tan Ling

    2015-09-25

    New attempt has been made to synthesize aminated acrylic conducting polymer (AACP) using precursor of phenylvinylsulfoxide (PVS). The process was conducted via the integration of microemulsion and photopolymerization techniques. It has been utilized for covalent immobilization of amino groups by the adding of N-achryiloxisuccinimide (NAS). Thermal eliminating of benzene sulfenic acids from PVS has been done at 250 °C to form electroactive polyacetylene (PA) segment. Characterization of AACP has been conducted using fourier transform infrared (FTIR), scanning electron microscopy (SEM) and linear sweep cyclic voltammetry (CV). A range of 0.3-1.25μm particle size obtained from SEM characterization. A quasi-reversible system performed as shown in electrochemical study.

  20. Proton conduction in biopolymer exopolysaccharide succinoglycan

    SciTech Connect (OSTI)

    Kweon, Jin Jung; Lee, Kyu Won; Kim, Hyojung; Lee, Cheol Eui; Jung, Seunho; Kwon, Chanho

    2014-07-07

    Protonic currents play a vital role in electrical signalling in living systems. It has been suggested that succinoglycan plays a specific role in alfalfa root nodule development, presumably acting as the signaling molecules. In this regard, charge transport and proton dynamics in the biopolymer exopolysaccharide succinoglycan have been studied by means of electrical measurements and nuclear magnetic resonance (NMR) spectroscopy. In particular, a dielectric dispersion in the system has revealed that the electrical conduction is protonic rather electronic. Besides, our laboratory- and rotating-frame {sup 1}H NMR measurements have elucidated the nature of the protonic conduction, activation of the protonic motion being associated with a glass transition.

  1. 2-D Finite Element Heat Conduction

    Energy Science and Technology Software Center (OSTI)

    1989-10-30

    AYER is a finite element program which implicitly solves the general two-dimensional equation of thermal conduction for plane or axisymmetric bodies. AYER takes into account the effects of time (transient problems), in-plane anisotropic thermal conductivity, a three-dimensional velocity distribution, and interface thermal contact resistance. Geometry and material distributions are arbitrary, and input is via subroutines provided by the user. As a result, boundary conditions, material properties, velocity distributions, and internal power generation may be mademore » functions of, e.g., time, temperature, location, and heat flux.« less

  2. Lesson 6: Conduct a School Energy Audit

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Lesson 6: Conduct a School Energy Audit Adopted/Revised From National Energy Education Development Project, U.S. Department of Energy Grade Level 6-12 Objectives * Identify different ways in which energy is used in the school * Examine different ways energy use can be reduced in the school * Create a plan to reduce school energy use Overview Students conduct a school energy audit. Materials * One or more flicker checkers per class * One or more light meters per class * One or more power monitors

  3. Electrically conductive containment vessel for molten aluminum

    DOE Patents [OSTI]

    Holcombe, Cressie E.; Scott, Donald G.

    1985-01-01

    The present invention is directed to a containment vessel which is particularly useful in melting aluminum. The vessel of the present invention is a multilayered vessel characterized by being electrically conductive, essentially nonwettable by and nonreactive with molten aluminum. The vessel is formed by coating a tantalum substrate of a suitable configuration with a mixture of yttria and particulate metal borides. The yttria in the coating inhibits the wetting of the coating while the boride particulate material provides the electrical conductivity through the vessel. The vessel of the present invention is particularly suitable for use in melting aluminum by ion bombardment.

  4. Electrically conductive containment vessel for molten aluminum

    DOE Patents [OSTI]

    Holcombe, C.E.; Scott, D.G.

    1984-06-25

    The present invention is directed to a containment vessel which is particularly useful in melting aluminum. The vessel of the present invention is a multilayered vessel characterized by being electrically conductive, essentially nonwettable by and nonreactive with molten aluminum. The vessel is formed by coating a tantalum substrate of a suitable configuration with a mixture of yttria and particulate metal 10 borides. The yttria in the coating inhibits the wetting of the coating while the boride particulate material provides the electrical conductivity through the vessel. The vessel of the present invention is particularly suitable for use in melting aluminum by ion bombardment.

  5. Conducting polymer for high power ultracapacitor

    DOE Patents [OSTI]

    Shi, Steven Z.; Gottesfeld, Shimshon

    2002-01-01

    In accordance with the purposes of the present invention, as embodied and broadly described herein, the present invention is directed to an electrode having a conducting polymer active material for use in an ultracapacitor. The conducting polymer active material is electropolymerized onto a carbon paper substrate from a mixed solution of a dimer of (3,3' bithiophene) (BT) and a monomer that is selected from the group of thiophenes derived in the 3-position, having an aryl group attached to thiophene in the 3-position or having aryl and alkly groups independently attached to thiophene in the 3 and 4 positions.

  6. Nanostructured transparent conducting oxide electrochromic device

    DOE Patents [OSTI]

    Milliron, Delia; Tangirala, Ravisubhash; Llordes, Anna; Buonsanti, Raffaella; Garcia, Guillermo

    2016-05-17

    The embodiments described herein provide an electrochromic device. In an exemplary embodiment, the electrochromic device includes (1) a substrate and (2) a film supported by the substrate, where the film includes transparent conducting oxide (TCO) nanostructures. In a further embodiment, the electrochromic device further includes (a) an electrolyte, where the nanostructures are embedded in the electrolyte, resulting in an electrolyte, nanostructure mixture positioned above the substrate and (b) a counter electrode positioned above the mixture. In a further embodiment, the electrochromic device further includes a conductive coating deposited on the substrate between the substrate and the mixture. In a further embodiment, the electrochromic device further includes a second substrate positioned above the mixture.

  7. Electrically conductive connection for an electrode

    DOE Patents [OSTI]

    Hornack, T.R.; Chilko, R.J.

    1986-09-02

    An electrically conductive connection for an electrode assembly of an electrolyte cell in which aluminum is produced by electrolysis in a molten salt is described. The electrode assembly comprises an electrode flask and a conductor rod. The flask has a collar above an area of minimum flask diameter. The electrically conductive connection comprises the electrode flask, the conductor rod and a structure bearing against the collar and the conductor rod for pulling the conductor rod into compressive and electrical contact with the flask. 2 figs.

  8. Electrochemical cell with high conductivity glass electrolyte

    DOE Patents [OSTI]

    Nelson, P.A.; Bloom, I.D.; Roche, M.F.

    1986-04-17

    A secondary electrochemical cell with sodium-sulfur or other molten reactants is provided with an ionically conductive glass electrolyte. The cell is contained within an electrically conductive housing with a first portion at negative potential and a second portion insulated therefrom at positive electrode potential. The glass electrolyte is formed into a plurality of elongated tubes and placed lengthwise within the housing. The positive electrode material, for instance sulfur, is sealed into the glass electrolyte tubes and is provided with an elongated axial current collector. The glass electrolyte tubes are protected by shield tubes or sheets that also define narrow annuli for wicking of the molten negative electrode material.

  9. Electrochemical cell with high conductivity glass electrolyte

    DOE Patents [OSTI]

    Nelson, P.A.; Bloom, I.D.; Roche, M.F.

    1987-04-21

    A secondary electrochemical cell with sodium-sulfur or other molten reactants is provided with a ionically conductive glass electrolyte. The cell is contained within an electrically conductive housing with a first portion at negative potential and a second portion insulated therefrom at positive electrode potential. The glass electrolyte is formed into a plurality of elongated tubes and placed lengthwise within the housing. The positive electrode material, for instance sulfur, is sealed into the glass electrolyte tubes and is provided with an elongated axial current collector. The glass electrolyte tubes are protected by shield tubes or sheets that also define narrow annuli for wicking of the molten negative electrode material. 6 figs.

  10. Electrochemical cell with high conductivity glass electrolyte

    DOE Patents [OSTI]

    Nelson, Paul A.; Bloom, Ira D.; Roche, Michael F.

    1987-01-01

    A secondary electrochemical cell with sodium-sulfur or other molten reactants is provided with a ionically conductive glass electrolyte. The cell is contained within an electrically conductive housing with a first portion at negative potential and a second portion insulated therefrom at positive electrode potential. The glass electrolyte is formed into a plurality of elongated tubes and placed lengthwise within the housing. The positive electrode material, for instance sulfur, is sealed into the glass electrolyte tubes and is provided with an elongated axial current collector. The glass electrolyte tubes are protected by shield tubes or sheets that also define narrow annuli for wicking of the molten negative electrode material.

  11. Bipolaron Hopping Conduction in Boron Carbides (Journal Article...

    Office of Scientific and Technical Information (OSTI)

    Bipolaron Hopping Conduction in Boron Carbides Citation Details In-Document Search Title: Bipolaron Hopping Conduction in Boron Carbides The electrical conductivities of boron ...

  12. CRAD, NNSA - Conduct of Engineering (CE) | Department of Energy

    Office of Environmental Management (EM)

    Conduct of Engineering (CE) CRAD, NNSA - Conduct of Engineering (CE) CRAD for Conduct of Engineering (CE). Criteria Review and Approach Documents (CRADs) that can be used to...

  13. Standard of Ethical Conduct of Employee | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Standard of Ethical Conduct of Employee Standard of Ethical Conduct of Employee Principles of Ethical Conduct for Federal Employees Ethical Briefing Certification

  14. NNSA conducts second seismic source physics experiment | National...

    National Nuclear Security Administration (NNSA)

    conducts second seismic source physics experiment | National Nuclear Security ... Home NNSA Blog NNSA conducts second seismic source physics experiment NNSA conducts ...

  15. Application of conducting polymers to electroanalysis

    SciTech Connect (OSTI)

    Josowicz, M.A.

    1994-04-01

    Conducting polymers can be used as sensitive layers in chemical microsensors leading to new applications of theses devices. They offer the potential for developing material properties that are critical to the sensor sensitivity, selectivity and fabrication. The advantages and limitations of the use of thin polymer layers in electrochemical sensors are discussed.

  16. Conducting polymers: Synthesis and industrial applications

    SciTech Connect (OSTI)

    Gottesfeld, S.

    1997-04-01

    The Conducting Polymer project funded by the AIM Program has developed new methods for the synthesis of conducting polymers and evaluated new industrial applications for these materials which will result in significant reductions in energy usage or industrial waste. The applications specifically addressed during FY 1996 included two ongoing efforts on membranes for gas separation and on electrochemical capacitors and a third new application: electrochemical reactors (ECRs) based on polymeric electrolytes. As a gas separation membrane, conducting polymers offer high selectivity and the potential to chemically or electrically adapt the membrane for specific gas combinations. Potential energy savings in the US for this application are estimated at 1 to 3 quads/yr. As an active material in electrochemical capacitors, electronically conducting polymers have the potential of storing large amounts of electric energy in low cost materials. Potential energy savings estimated at 1 quad/yr would result from introduction of electrochemical capacitors as energy storage devices in power trains of electric and hybrid vehicles, once such vehicles reach 20% of the total transportation market in the US. In the chlor-alkali industry, electrochemical reactors based on polymer electrolyte membranes consume around 1 % of the total electric power in the US. A new activity, started in FY 1996, is devoted to energy efficient ECRs. In the case of the chlor-alkali industry, energy savings as high as 50% seem possible with the novel ECR technology demonstrated by the author in 1996.

  17. Metal nanoparticles as a conductive catalyst

    SciTech Connect (OSTI)

    Coker, Eric N.

    2010-08-03

    A metal nanocluster composite material for use as a conductive catalyst. The metal nanocluster composite material has metal nanoclusters on a carbon substrate formed within a porous zeolitic material, forming stable metal nanoclusters with a size distribution between 0.6-10 nm and, more particularly, nanoclusters with a size distribution in a range as low as 0.6-0.9 nm.

  18. Conduct of Operations Requirements for DOE Facilities

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    1990-07-09

    "To provide requirements and guidelines for Departmental Elements, including the National Nuclear Security Administration (NNSA), to use in developing directives, plans, and/or procedures relating to the conduct of operations at DOE facilities. The implementation of these requirements and guidelines should result in improved quality and uniformity of operations. Change 2, 10-23-2001. Canceled by DOE O 422.1.

  19. Electrically conductive proppant and methods for detecting, locating and characterizing the electrically conductive proppant

    DOE Patents [OSTI]

    Cannan, Chad; Bartel, Lewis; Palisch, Terrence; Aldridge, David

    2015-01-13

    Electrically conductive proppants and methods for detecting, locating, and characterizing same are provided. The electrically conductive proppant can include a substantially uniform coating of an electrically conductive material having a thickness of at least 500 nm. The method can include injecting a hydraulic fluid into a wellbore extending into a subterranean formation at a rate and pressure sufficient to open a fracture therein, injecting into the fracture a fluid containing the electrically conductive proppant, electrically energizing the earth at or near the fracture, and measuring three dimensional (x, y, and z) components of electric and magnetic field responses at a surface of the earth or in an adjacent wellbore.

  20. Liquid Propane Injection Technology Conductive to Today's North...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Technology Conductive to Today's North American Specification Liquid Propane Injection Technology Conductive to Today's North American Specification Liquid propane injection ...

  1. Thermal conductance of metallic interface in vacuum

    SciTech Connect (OSTI)

    Mortazavi, P.; Shu, D.

    1985-01-01

    In most heat transfer applications, the deposited heat is transferred by any of the following classical methods: conduction, convection, radiation, or any combinations of these three. Depending on how critical the nature is of the designed equipment, the response time must be short enough in order to safeguard the proper performance of the devices. For instance, currently at the National Synchrotron Light Source (NSLS), various hardware equipment are being designed to intercept or to stop intense radiation beams induced by insertion devices such as wiggler and undulators. Due to the nature of some of these designs, the deposited high flux thermal load must be transferred across unbonded contact surfaces. Since any miscalculation would result in the disintegration of exposed material and therefore cause substantial problems, a true actual conductance measurement of the material in question is highly desirable. In the following three sections, background summary, the method of measurement, and the obtained results are discussed.

  2. Effective thermal conductivity in thermoelectric materials

    SciTech Connect (OSTI)

    Baranowski, LL; Snyder, GJ; Toberer, ES

    2013-05-28

    Thermoelectric generators (TEGs) are solid state heat engines that generate electricity from a temperature gradient. Optimizing these devices for maximum power production can be difficult due to the many heat transport mechanisms occurring simultaneously within the TEG. In this paper, we develop a model for heat transport in thermoelectric materials in which an "effective thermal conductivity" (kappa(eff)) encompasses both the one dimensional steady-state Fourier conduction and the heat generation/consumption due to secondary thermoelectric effects. This model is especially powerful in that the value of kappa(eff) does not depend upon the operating conditions of the TEG but rather on the transport properties of the TE materials themselves. We analyze a variety of thermoelectric materials and generator designs using this concept and demonstrate that kappa(eff) predicts the heat fluxes within these devices to 5% of the exact value. (C) 2013 AIP Publishing LLC.

  3. Helicopter magnetic survey conducted to locate wells

    SciTech Connect (OSTI)

    Veloski, G.A.; Hammack, R.W.; Stamp, V.; Hall, R.; Colina, K.

    2008-07-01

    A helicopter magnetic survey was conducted in August 2007 over 15.6 sq mi at the Naval Petroleum Reserve No. 3s (NPR-3) Teapot Dome Field near Casper, Wyoming. The surveys purpose was to accurately locate wells drilled there during more than 90 years of continuous oilfield operation. The survey was conducted at low altitude and with closely spaced flight lines to improve the detection of wells with weak magnetic response and to increase the resolution of closely spaced wells. The survey was in preparation for a planned CO2 flood for EOR, which requires a complete well inventory with accurate locations for all existing wells. The magnetic survey was intended to locate wells missing from the well database and to provide accurate locations for all wells. The ability of the helicopter magnetic survey to accurately locate wells was accomplished by comparing airborne well picks with well locations from an intense ground search of a small test area.

  4. Micro-machined thermo-conductivity detector

    DOE Patents [OSTI]

    Yu, Conrad

    2003-01-01

    A micro-machined thermal conductivity detector for a portable gas chromatograph. The detector is highly sensitive and has fast response time to enable detection of the small size gas samples in a portable gas chromatograph which are in the order of nanoliters. The high sensitivity and fast response time are achieved through micro-machined devices composed of a nickel wire, for example, on a silicon nitride window formed in a silicon member and about a millimeter square in size. In addition to operating as a thermal conductivity detector, the silicon nitride window with a micro-machined wire therein of the device can be utilized for a fast response heater for PCR applications.

  5. Anisotropic conducting films for electromagnetic radiation applications

    DOE Patents [OSTI]

    Cavallo, Francesca; Lagally, Max G.; Rojas-Delgado, Richard

    2015-06-16

    Electronic devices for the generation of electromagnetic radiation are provided. Also provided are methods for using the devices to generate electromagnetic radiation. The radiation sources include an anisotropic electrically conducting thin film that is characterized by a periodically varying charge carrier mobility in the plane of the film. The periodic variation in carrier mobility gives rise to a spatially varying electric field, which produces electromagnetic radiation as charged particles pass through the film.

  6. Nonlinear optical and conductive polymeric material

    DOE Patents [OSTI]

    Barton, Thomas J.; Ijadi-Maghsoodi, Sina; Pang, Yi

    1992-05-19

    A polymeric material which exhibits nonlinear optical properties if undoped and conductive properties if doped. The polymer is prepared by polymerizing diethynylsilane compositions, the resulting polymeric material having a weight average molecular weight between about 20,000 and about 200,000 grams per mole. The polymer is prepared and catalytically polymerized by exposure to a catalyst, such as MoCl.sub.5 or W(CO).sub.6 /hv.

  7. GUIDANCE ON CONDUCTING ADVERSE DIVERSITY ANALYSIS

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    GUIDANCE ON CONDUCTING ADVERSE DIVERSITY ANALYSIS The Uniform Guidelines for Employee Selection Procedures adopted by the Equal Employment Opportunity Commission (EEOC), Department of Labor's Office of Federal Contract Compliance Programs (OFCCP), and U.S. Department of Justice in 1978 set out accepted statistical tests for assessing possible discriminatory impact of employment actions on protected classifications of employees. See 29 CFR Part 1607. Agencies and litigants commonly use

  8. Proton conducting ceramics in membrane separations

    SciTech Connect (OSTI)

    Brinkman, Kyle S; Korinko, Paul S; Fox, Elise B; Chen, Frank

    2015-04-14

    Perovskite materials of the general formula SrCeO.sub.3 and BaCeO.sub.3 are provided having improved conductivity while maintaining an original ratio of chemical constituents, by altering the microstructure of the material. A process of making Pervoskite materials is also provided in which wet chemical techniques are used to fabricate nanocrystalline ceramic materials which have improved grain size and allow lower temperature densification than is obtainable with conventional solid-state reaction processing.

  9. Normal Conducting RF Cavity for MICE

    SciTech Connect (OSTI)

    Li, D.; DeMello, A.; Virostek, S.; Zisman, M.; Summers, D.

    2010-05-23

    Normal conducting RF cavities must be used for the cooling section of the international Muon Ionization Cooling Experiment (MICE), currently under construction at Rutherford Appleton Laboratory (RAL) in the UK. Eight 201-MHz cavities are needed for the MICE cooling section; fabrication of the first five cavities is complete. We report the cavity fabrication status including cavity design, fabrication techniques and preliminary low power RF measurements.

  10. Method of synthesis of proton conducting materials

    DOE Patents [OSTI]

    Garzon, Fernando Henry; Einsla, Melinda Lou; Mukundan, Rangachary

    2010-06-15

    A method of producing a proton conducting material, comprising adding a pyrophosphate salt to a solvent to produce a dissolved pyrophosphate salt; adding an inorganic acid salt to a solvent to produce a dissolved inorganic acid salt; adding the dissolved inorganic acid salt to the dissolved pyrophosphate salt to produce a mixture; substantially evaporating the solvent from the mixture to produce a precipitate; and calcining the precipitate at a temperature of from about 400.degree. C. to about 1200.degree. C.

  11. Oxygen ion-conducting dense ceramic

    DOE Patents [OSTI]

    Balachandran, Uthamalingam; Kleefisch, Mark S.; Kobylinski, Thaddeus P.; Morissette, Sherry L.; Pei, Shiyou

    1998-01-01

    Preparation, structure, and properties of mixed metal oxide compositions and their uses are described. Mixed metal oxide compositions of the invention have stratified crystalline structure identifiable by means of powder X-ray diffraction patterns. In the form of dense ceramic membranes, the present compositions demonstrate an ability to separate oxygen selectively from a gaseous mixture containing oxygen and one or more other volatile components by means of ionic conductivities.

  12. Nonlinear optical and conductive polymeric material

    DOE Patents [OSTI]

    Barton, T.J.; Ijadi-Maghsooodi, S; Yi Pang.

    1993-10-19

    A polymeric material is described which exhibits nonlinear optical properties if undoped and conductive properties if doped. The polymer is prepared by polymerizing diethynylsilane compositions, the resulting polymeric material having a weight average molecular weight between about 20,000 and about 200,000 grams per mole. The polymer is prepared and catalytically polymerized by exposure to a catalyst, such as MoCl[sub 5] or W(CO)[sub 6].

  13. Nonlinear optical and conductive polymeric material

    DOE Patents [OSTI]

    Barton, Thomas J.; Ijadi-Maghsoodi, Sina; Pang, Yi

    1993-10-19

    A polymeric material which exhibits nonlinear optical properties if undoped and conductive properties if doped. The polymer is prepared by polymerizing diethynylsilane compositions, the resulting polymeric material having a weight average molecular weight between about 20,000 and about 200,000 grams per mole. The polymer is prepared and catalytically polymerized by exposure to a catalyst, such as MoCl.sub.5 or W(CO).sub.6 /hv.

  14. Nonlinear optical and conductive polymeric material

    DOE Patents [OSTI]

    Barton, T.J.; Ijadi-Maghsoodi, S.; Pang, Y.

    1992-05-19

    A polymeric material which exhibits nonlinear optical properties if undoped and conductive properties if doped. The polymer is prepared by polymerizing diethynylsilane compositions, the resulting polymeric material having a weight average molecular weight between about 20,000 and about 200,000 grams per mole. The polymer is prepared and catalytically polymerized by exposure to a catalyst, such as MoCl[sub 5] or W(CO)[sub 6]/hv.

  15. Anisotropy of electrical conductivity in dry olivine

    SciTech Connect (OSTI)

    Du Frane, W L; Roberts, J J; Toffelmier, D A; Tyburczy, J A

    2005-04-13

    [1] The electrical conductivity ({sigma}) was measured for a single crystal of San Carlos olivine (Fo{sub 89.1}) for all three principal orientations over oxygen fugacities 10{sup -7} < fO{sub 2} < 10{sup 1} Pa at 1100, 1200, and 1300 C. Fe-doped Pt electrodes were used in conjunction with a conservative range of fO{sub 2}, T, and time to reduce Fe loss resulting in data that is {approx}0.15 log units higher in conductivity than previous studies. At 1200 C and fO{sub 2} = 10{sup -1} Pa, {sigma}{sub [100]} = 10{sup -2.27} S/m, {sigma}{sub [010]} = 10{sup -2.49} S/m, {sigma}{sub [001]} = 10{sup -2.40} S/m. The dependences of {sigma} on T and fO{sub 2} have been simultaneously modeled with undifferentiated mixed conduction of small polarons and Mg vacancies to obtain steady-state fO{sub 2}-independent activation energies: Ea{sub [100]} = 0.32 eV, Ea{sub [010]} = 0.56 eV, Ea{sub [001]} = 0.71 eV. A single crystal of dry olivine would provide a maximum of {approx}10{sup 0.4} S/m azimuthal {sigma} contrast for T < 1500 C. The anisotropic results are combined to create an isotropic model with Ea = 0.53 eV.

  16. Thermal conductivity of tubrostratic carbon nanofiber networks

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bauer, Matthew L.; Saltonstall, Chris B.; Leseman, Zayd C.; Beechem, Thomas E.; Hopkins, Patrick E.; Norris, Pamela M.

    2016-01-01

    Composite material systems composed of a matrix of nano materials can achieve combinations of mechanical and thermophysical properties outside the range of traditional systems. While many reports have studied the intrinsic thermal properties of individual carbon fibers, to be useful in applications in which thermal stability is critical, an understanding of heat transport in composite materials is required. In this work, air/ carbon nano fiber networks are studied to elucidate the system parameters influencing thermal transport. Sample thermal properties are measured with varying initial carbon fiber fill fraction, environment pressure, loading pressure, and heat treatment temperature through a bidirectional modificationmore » of the 3ω technique. The nanostructures of the individual fibers are characterized with small angle x-ray scattering and Raman spectroscopy providing insight to individual fiber thermal conductivity. Measured thermal conductivity varied from 0.010 W/(m K) to 0.070 W/(m K). An understanding of the intrinsic properties of the individual fibers and the interactions of the two phase composite is used to reconcile low measured thermal conductivities with predictive modeling. This methodology can be more generally applied to a wide range of fiber composite materials and their applications.« less

  17. Thermal conductivity of tubrostratic carbon nanofiber networks

    SciTech Connect (OSTI)

    Bauer, Matthew L.; Saltonstall, Chris B.; Leseman, Zayd C.; Beechem, Thomas E.; Hopkins, Patrick E.; Norris, Pamela M.

    2016-01-01

    Composite material systems composed of a matrix of nano materials can achieve combinations of mechanical and thermophysical properties outside the range of traditional systems. While many reports have studied the intrinsic thermal properties of individual carbon fibers, to be useful in applications in which thermal stability is critical, an understanding of heat transport in composite materials is required. In this work, air/ carbon nano fiber networks are studied to elucidate the system parameters influencing thermal transport. Sample thermal properties are measured with varying initial carbon fiber fill fraction, environment pressure, loading pressure, and heat treatment temperature through a bidirectional modification of the 3ω technique. The nanostructures of the individual fibers are characterized with small angle x-ray scattering and Raman spectroscopy providing insight to individual fiber thermal conductivity. Measured thermal conductivity varied from 0.010 W/(m K) to 0.070 W/(m K). An understanding of the intrinsic properties of the individual fibers and the interactions of the two phase composite is used to reconcile low measured thermal conductivities with predictive modeling. This methodology can be more generally applied to a wide range of fiber composite materials and their applications.

  18. Conductance valve and pressure-to-conductance transducer method and apparatus

    DOE Patents [OSTI]

    Schoeniger, Joseph S.; Cummings, Eric B.; Brennan, James S.

    2005-01-18

    A device for interrupting or throttling undesired ionic transport through a fluid network is disclosed. The device acts as a fluid valve by reversibly generating a fixed "bubble" in the conducting solvent solution carried by the network. The device comprises a porous hydrophobic structure filling a portion of a connecting channel within the network and optionally incorporates flow restrictor elements at either end of the porous structure that function as pressure isolation barriers, and a fluid reservoir connected to the region of the channel containing the porous structure. Also included is a pressure pump connected to the fluid reservoir. The device operates by causing the pump to vary the hydraulic pressure to a quantity of solvent solution held within the reservoir and porous structure. At high pressures, most or all of the pores of the structure are filled with conducting liquid so the ionic conductance is high. At lower pressures, only a fraction of the pores are filled with liquid, so ionic conductivity is lower. Below a threshold pressure, the porous structure contains only vapor, so there is no liquid conduction path. The device therefore effectively throttles ionic transport through the porous structure and acts as a "conductance valve" or "pressure-to-conductance" transducer within the network.

  19. Synthesis of transparent conducting oxide coatings

    DOE Patents [OSTI]

    Elam, Jeffrey W.; Martinson, Alex B. F.; Pellin, Michael J.; Hupp, Joseph T.

    2010-05-04

    A method and system for preparing a light transmitting and electrically conductive oxide film. The method and system includes providing an atomic layer deposition system, providing a first precursor selected from the group of cyclopentadienyl indium, tetrakis (dimethylamino) tin and mixtures thereof, inputting to the deposition system the first precursor for reaction for a first selected time, providing a purge gas for a selected time, providing a second precursor comprised of an oxidizer, and optionally inputting a second precursor into the deposition system for reaction and alternating for a predetermined number of cycles each of the first precursor, the purge gas and the second precursor to produce the oxide film.

  20. Method for conducting nonlinear electrochemical impedance spectroscopy

    DOE Patents [OSTI]

    Adler, Stuart B.; Wilson, Jamie R.; Huff, Shawn L.; Schwartz, Daniel T.

    2015-06-02

    A method for conducting nonlinear electrochemical impedance spectroscopy. The method includes quantifying the nonlinear response of an electrochemical system by measuring higher-order current or voltage harmonics generated by moderate-amplitude sinusoidal current or voltage perturbations. The method involves acquisition of the response signal followed by time apodization and fast Fourier transformation of the data into the frequency domain, where the magnitude and phase of each harmonic signal can be readily quantified. The method can be implemented on a computer as a software program.

  1. Exploding conducting film laser pumping apparatus

    DOE Patents [OSTI]

    Ware, Kenneth D.; Jones, Claude R.

    1986-01-01

    Exploding conducting film laser optical pumping apparatus. The 342-nm molecular iodine and the 1.315-.mu.m atomic iodine lasers have been optically pumped by intense light from exploding-metal-film discharges. Brightness temperatures for the exploding-film discharges were approximately 25,000 K. Although lower output energies were achieved for such discharges when compared to exploding-wire techniques, the larger surface area and smaller inductance inherent in the exploding-film should lead to improved efficiency for optically-pumped gas lasers.

  2. Conductive ceramic composition and method of preparation

    DOE Patents [OSTI]

    Smith, James L.; Kucera, Eugenia H.

    1991-01-01

    A ceramic anode composition is formed of a multivalent metal oxide or oxygenate such as an alkali metal, transition metal oxygenate. The anode is prepared as a non-stoichiometric crystalline structure by reaction and conditioning in a hydrogen gas cover containing minor proportions of carbon dioxide and water vapor. The structure exhibits a single phase and substantially enhanced electrical conductivity over that of the corresponding stoichiometric structure. Unexpectedly, such oxides and oxygenates are found to be stable in the reducing anode fuel gas of a molten carbonate fuel cell.

  3. Conductive ceramic composition and method of preparation

    DOE Patents [OSTI]

    Smith, J.L.; Kucera, E.H.

    1991-04-16

    A ceramic anode composition is formed of a multivalent metal oxide or oxygenate such as an alkali metal, transition metal oxygenate. The anode is prepared as a non-stoichiometric crystalline structure by reaction and conditioning in a hydrogen gas cover containing minor proportions of carbon dioxide and water vapor. The structure exhibits a single phase and substantially enhanced electrical conductivity over that of the corresponding stoichiometric structure. Unexpectedly, such oxides and oxygenates are found to be stable in the reducing anode fuel gas of a molten carbonate fuel cell. 4 figures.

  4. Actuator device utilizing a conductive polymer gel

    DOE Patents [OSTI]

    Chinn, Douglas A.; Irvin, David J.

    2004-02-03

    A valve actuator based on a conductive polymer gel is disclosed. A nonconductive housing is provided having two separate chambers separated by a porous frit. The conductive polymer is held in one chamber and an electrolyte solution, used as a source of charged ions, is held in the second chamber. The ends of the housing a sealed with a flexible elastomer. The polymer gel is further provide with electrodes with which to apply an electrical potential across the gel in order to initiate an oxidation reaction which in turn drives anions across the porous frit and into the polymer gel, swelling the volume of the gel and simultaneously contracting the volume of the electrolyte solution. Because the two end chambers are sealed the flexible elastomer expands or contracts with the chamber volume change. By manipulating the potential across the gel the motion of the elastomer can be controlled to act as a "gate" to open or close a fluid channel and thereby control flow through that channel.

  5. Guidance manual for conducting technology demonstration activities

    SciTech Connect (OSTI)

    Jolley, Robert L.; Morris, Michael I.; Singh, Suman P.N.

    1991-12-01

    This demonstration guidance manual has been prepared to assist Martin Marietta Energy Systems, Inc. (Energy Systems), staff in conducting demonstrations. It is prepared in checklist style to facilitate its use and assumes that Energy Systems personnel have project management responsibility. In addition to a detailed step-by-step listing of procedural considerations, a general checklist, logic flow diagram, and several examples of necessary plans are included to assist the user in developing an understanding of the many complex activities required to manage technology demonstrations. Demonstrations are pilot-scale applications of often innovative technologies to determine the commercial viability of the technologies to perform their designed function. Demonstrations are generally conducted on well-defined problems for which existing technologies or processes are less than satisfactory in terms of effectiveness, cost, and/or regulatory compliance. Critically important issues in demonstration management include, but are not limited to, such factors as communications with line and matrix management and with the US Department of Energy (DOE) and Energy Systems staff responsible for management oversight, budgetary and schedule requirements, regulatory compliance, and safety.

  6. Formed Core Sampler Hydraulic Conductivity Testing

    SciTech Connect (OSTI)

    Miller, D. H.; Reigel, M. M.

    2012-09-25

    A full-scale formed core sampler was designed and functionally tested for use in the Saltstone Disposal Facility (SDF). Savannah River National Laboratory (SRNL) was requested to compare properties of the formed core samples and core drilled samples taken from adjacent areas in the full-scale sampler. While several physical properties were evaluated, the primary property of interest was hydraulic conductivity. Differences in hydraulic conductivity between the samples from the formed core sampler and those representing the bulk material were noted with respect to the initial handling and storage of the samples. Due to testing conditions, the site port samples were exposed to uncontrolled temperature and humidity conditions prior to testing whereas the formed core samples were kept in sealed containers with minimal exposure to an uncontrolled environment prior to testing. Based on the results of the testing, no significant differences in porosity or density were found between the formed core samples and those representing the bulk material in the test stand.

  7. Enhanced ionic conductivity in oxide heterostructures

    SciTech Connect (OSTI)

    Garcia-Barriocanal, Javier; Rivera-Calzada, Alberto; Varela del Arco, Maria; Sefrioui, Z.; Iborra, Enrique; Leon, C.; Pennycook, Stephen J; Santamaria, J.

    2010-01-01

    Fuel cells are electrochemical devices used to generate energy out of hydrogen. In a fuel cell, two conducting electrodes are separated by an electrolyte that is permeable to ions (either hydrogen or oxygen, depending on the fuel-cell category) but not to electrons. An electrode catalytic process yields the ionic species, which are transported through the electrolyte, while electrons blocked by the electrolyte pass through the external circuit. Polymeric membrane (PEMFC) or phosphoric acid fuel cells (PAFC) operating at low temperatures are the preferred option for transportation because of their quite large efficiencies (50%), compared with gasoline combustion engines (25%). Other uses are also being considered, such as battery replacements for personal electronics and stationary or portable emergency power. Solid-oxide fuel cells (SOFCs), operating at high temperatures, are a better option for stationary power generation because of their scalability. Here O{sup 2-} ions are the mobile species that travel at elevated temperatures (800-1000 C) through a solid electrolyte material to react with H{sup +} ions in the anode to produce water (Fig. 1). The high operating temperatures of solid oxide fuel cells are a major impediment to their widespread use in power generation. Thus, reducing this operating temperature is currently a major materials research goal, involving the search for novel electrolytes as well as active catalysts for electrode kinetics (oxygen reduction and hydrogen oxidation). Among oxide-ion conductors, those of anion-deficient fluorite structures such as yttria-stabilized zirconia (YSZ), xY{sub 2}O{sub 3}:(1-x) ZrO{sub 2}, are extensively used as electrolytes in SOFCs. Doping with Y{sub 2}O{sub 3} is known to stabilize the cubic fluorite structure of ZrO{sub 2} and to supply the oxygen vacancies responsible for the ionic conduction. These materials are characterized by a large number of mobile oxygen vacancies, which are randomly distributed in the

  8. Ion-/proton-conducting apparatus and method

    DOE Patents [OSTI]

    Yates, Matthew; Liu, Dongxia

    2011-05-17

    A c-axis-oriented HAP thin film synthesized by seeded growth on a palladium hydrogen membrane substrate. An exemplary synthetic process includes electrochemical seeding on the substrate, and secondary and tertiary hydrothermal treatments under conditions that favor growth along c-axes and a-axes in sequence. By adjusting corresponding synthetic conditions, an HAP this film can be grown to a controllable thickness with a dense coverage on the underlying substrate. The thin films have relatively high proton conductivity under hydrogen atmosphere and high temperature conditions. The c-axis oriented films may be integrated into fuel cells for application in the intermediate temperature range of 200-600.degree. C. The electrochemical-hydrothermal deposition technique may be applied to create other oriented crystal materials having optimized properties, useful for separations and catalysis as well as electronic and electrochemical applications, electrochemical membrane reactors, and in chemical sensors.

  9. Nanostructured polymer membranes for proton conduction

    DOE Patents [OSTI]

    Balsara, Nitash Pervez; Park, Moon Jeong

    2013-06-18

    Polymers having an improved ability to entrain water are characterized, in some embodiments, by unusual humidity-induced phase transitions. The described polymers (e.g., hydrophilically functionalized block copolymers) have a disordered state and one or more ordered states (e.g., a lamellar state, a gyroid state, etc.). In one aspect, the polymers are capable of undergoing a disorder-to-order transition while the polymer is exposed to an increasing temperature at a constant relative humidity. In some aspects the polymer includes a plurality of portions, wherein a first portion forms proton-conductive channels within the membrane and wherein the channels have a width of less than about 6 nm. The described polymers are capable of entraining and preserving water at high temperature and low humidity. Surprisingly, in some embodiments, the polymers are capable of entraining greater amounts of water with the increase of temperature. The polymers can be used in Polymer Electrolyte Membranes in fuel cells.

  10. Microscale Heat Conduction Models and Doppler Feedback

    SciTech Connect (OSTI)

    Hawari, Ayman I.; Ougouag, Abderrafi

    2015-01-22

    The objective of this project is to establish an approach for providing the fundamental input that is needed to estimate the magnitude and time-dependence of the Doppler feedback mechanism in Very High Temperature reactors. This mechanism is the foremost contributor to the passive safety of gas-cooled, graphite-moderated high temperature reactors that use fuel based on Tristructural-Isotropic (TRISO) coated particles. Therefore, its correct prediction is essential to the conduct of safety analyses for these reactors. Since the effect is directly dependent on the actual temperature reached by the fuel during transients, the underlying phenomena of heat deposition, heat transfer and temperature rise must be correctly predicted. To achieve the above objective, this project will explore an approach that accounts for lattice effects as well as local temperature variations and the correct definition of temperature and related local effects.

  11. Oxygen ion-conducting dense ceramic

    DOE Patents [OSTI]

    Balachandran, Uthamalingam; Kleefisch, Mark S.; Kobylinski, Thaddeus P.; Morissette, Sherry L.; Pei, Shiyou

    1996-01-01

    Preparation, structure, and properties of mixed metal oxide compositions containing at least strontium, cobalt, iron and oxygen are described. The crystalline mixed metal oxide compositions of this invention have, for example, structure represented by Sr.sub..alpha. (Fe.sub.1-x Co.sub.x).sub..alpha.+.beta. O.sub..delta. where x is a number in a range from 0.01 to about 1, .alpha. is a number in a range from about 1 to about 4, .beta. is a number in a range upward from 0 to about 20, and .delta. is a number which renders the compound charge neutral, and wherein the composition has a non-perovskite structure. Use of the mixed metal oxides in dense ceramic membranes which exhibit oxygen ionic conductivity and selective oxygen separation, are described as well as their use in separation of oxygen from an oxygen-containing gaseous mixture.

  12. Oxygen ion-conducting dense ceramic

    DOE Patents [OSTI]

    Balachandran, Uthamalingam; Kleefisch, Mark S.; Kobylinski, Thaddeus P.; Morissette, Sherry L.; Pei, Shiyou

    1997-01-01

    Preparation, structure, and properties of mixed metal oxide compositions containing at least strontium, cobalt, iron and oxygen are described. The crystalline mixed metal oxide compositions of this invention have, for example, structure represented by Sr.sub..alpha. (Fe.sub.1-x Co.sub.x).sub..alpha.+.beta. O.sub..delta. where x is a number in a range from 0.01 to about 1, .alpha. is a number in a range from about 1 to about 4, .beta. is a number in a range upward from 0 to about 20, and .delta. is a number which renders the compound charge neutral, and wherein the composition has a non-perovskite structure. Use of the mixed metal oxides in dense ceramic membranes which exhibit oxygen ionic conductivity and selective oxygen separation, are described as well as their use in separation of oxygen from an oxygen-containing gaseous mixture.

  13. Chemical synthesis of chiral conducting polymers

    DOE Patents [OSTI]

    Wang, Hsing-Lin; Li, Wenguang

    2009-01-13

    An process of forming a chiral conducting polymer, e.g., polyaniline, is provided including reacting a monomer, e.g., an aniline monomer, in the presence of a chiral dopant acid to produce a first reaction mixture by addition of a solution including a first portion of an oxidizing agent, the first portion of oxidizing agent characterized as insufficient to allow complete reaction of the monomer, and further reacting the first reaction mixture in the presence of the chiral dopant acid by addition of a solution including a second portion of the oxidizing agent, the second portion of oxidizing agent characterized as insufficient to allow complete reaction of the monomer, and repeating the reaction by addition of further portions of the oxidizing agent until the monomer reaction is complete to produce a chiral conducting polymer, e.g., polyaniline. A preferred process includes addition of a catalyst during the reaction, the catalyst selected from among the group consisting of phenylene diamine, aniline oligomers and amino-capped aniline oligomers and metal salts.The processes of the present invention further provide a resultant polyaniline product having a chirality level defined by a molar ellipticity of from about 40.times.10.sup.3 degree-cm.sup.2/decimole to about 700.times.10.sup.3 degree-cm.sup.2/decimole. The processes of the present invention further provide a resultant polyaniline product having a nanofiber structure with a diameter of from about 30 nanometers to about 120 nanometers and from about 1 micron to about 5 microns in length.

  14. Chemical synthesis of chiral conducting polymers

    DOE Patents [OSTI]

    Wang, Hsing-Lin; Li, Wenguang

    2006-07-11

    An process of forming a chiral conducting polymer, e.g., polyaniline, is provided including reacting a monomer, e.g., an aniline monomer, in the presence of a chiral dopant acid to produce a first reaction mixture by addition of a solution including a first portion of an oxidizing agent, the first portion of oxidizing agent characterized as insufficient to allow complete reaction of the monomer, and further reacting the first reaction mixture in the presence of the chiral dopant acid by addition of a solution including a second portion of the oxidizing agent, the second portion of oxidizing agent characterized as insufficient to allow complete reaction of the monomer, and repeating the reaction by addition of further portions of the oxidizing agent until the monomer reaction is complete to produce a chiral conducting polymer, e.g., polyaniline. A preferred process includes addition of a catalyst during the reaction, the catalyst selected from among the group consisting of phenylene diamine, aniline oligomers and amino-capped aniline oligomers and metal salts. The processes of the present invention further provide a resultant polyaniline product having a chirality level defined by a molar ellipticity of from about 40.times.103 degree-cm2/decimole to about 700.times.103 degree-cm2/decimole. The processes of the present invention further provide a resultant polyaniline product having a nanofiber structure with a diameter of from about 30 nanometers to about 120 nanometers and from about 1 micron to about 5 microns in length.

  15. Suspension chemistry and electrophoretic deposition of zirconia electrolyte on conducting and non-conducting substrates

    SciTech Connect (OSTI)

    Das, Debasish; Basu, Rajendra N.

    2013-09-01

    Graphical abstract: - Highlights: Stable suspension of yttria stabilized zirconia (YSZ) obtained in isopropanol medium. Suspension chemistry and process parameters for electrophoretic deposition optimized. Deposited film quality changed with iodine and water (dispersants) concentration. Dense YSZ film (?5 ?m) fabricated onto non-conducting porous NiO-YSZ anode substrate. - Abstract: Suspensions of 8 mol% yttria stabilized zirconia (YSZ) particulates in isopropanol medium are prepared using acetylacetone, iodine and water as dispersants. The effect of dispersants concentration on suspension stability, particle size distribution, electrical conductivity and pH of the suspensions are studied in detail to optimize the suspension chemistry. Electrophoretic deposition (EPD) has been conducted to produce thin and dense YSZ electrolyte films. Deposition kinetics have been studied in depth and good quality films on conducting substrate are obtained at an applied voltage of 15 V for 3 min. YSZ films are also fabricated on non-conducting NiO-YSZ anode substrate using a steel plate on the reverse side of the substrate. Upon co-firing at 1400 C for 6 h a dense YSZ film of thickness ?5 ?m is obtained. Such a half cell (anode + electrolyte) can be used to fabricate a solid oxide fuel cell on applying a suitable cathode layer.

  16. Modeling heat conduction and radiation transport with the diffusion...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    heat conduction and radiation transport with the diffusion equation in NIF ALE-AMR This ... IOPscience Modeling Heat Conduction and Radiation Transport with the Diffusion Equation in ...

  17. ENSURING ACCESS TO FEDERALLY CONDUCTED PROGRAMS AND ACTIVITIES...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Information On FEDERALLY CONDUCTED PROGRAMS AND ACTIVITIES ENSURING ACCESS TO FEDERALLY CONDUCTED PROGRAMS AND ACTIVITIES BY INDIVIDUALS WITH LIMITED ENGLISH PROFICIENCY (LEP) PLAN ...

  18. Glass-like thermal conductivity in high efficiency thermoelectric...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    thermal conductivity in high efficiency thermoelectric materials Glass-like thermal conductivity in high efficiency thermoelectric materials Discusses strategies to design ...

  19. Bipolaron Hopping Conduction in Boron Carbides (Journal Article...

    Office of Scientific and Technical Information (OSTI)

    Bipolaron Hopping Conduction in Boron Carbides Citation Details In-Document Search Title: Bipolaron Hopping Conduction in Boron Carbides You are accessing a document from the ...

  20. Vehicle Technologies Office Merit Review 2015: Wireless & Conductive...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Wireless & Conductive Charging Testing to support Code & Standards Vehicle Technologies Office Merit Review 2015: Wireless & Conductive Charging Testing to support Code & Standards ...

  1. Vehicle Technologies Office Merit Review 2016: Wireless & Conductive...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Wireless & Conductive Charging Testing to Support Code & Standards Vehicle Technologies Office Merit Review 2016: Wireless & Conductive Charging Testing to Support Code & Standards ...

  2. First Subcritical Experiment Conducted at Nevada Test Site |...

    National Nuclear Security Administration (NNSA)

    Subcritical Experiment Conducted at Nevada Test Site First Subcritical Experiment Conducted at Nevada Test Site Nevada Test Site, NV The first "subcritical" physics experiment at ...

  3. Equilibration dynamics and conductivity of warm dense hydrogen...

    Office of Scientific and Technical Information (OSTI)

    and conductivity of warm dense hydrogen Citation Details In-Document Search Title: Equilibration dynamics and conductivity of warm dense hydrogen You are accessing a document ...

  4. The Organic Chemistry of Conducting Polymers (Technical Report...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: The Organic Chemistry of Conducting Polymers Citation Details In-Document Search Title: The Organic Chemistry of Conducting Polymers For the last several years, ...

  5. V-155: Apache Tomcat FORM Authenticator Lets Remote Users Conduct...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    5: Apache Tomcat FORM Authenticator Lets Remote Users Conduct Session Fixation Attacks V-155: Apache Tomcat FORM Authenticator Lets Remote Users Conduct Session Fixation Attacks...

  6. Hydrogen production by water dissociation using mixed conducting...

    Office of Scientific and Technical Information (OSTI)

    by water dissociation using mixed conducting dense ceramic membranes. Citation Details In-Document Search Title: Hydrogen production by water dissociation using mixed conducting dense ...

  7. Tunable Electrical Conductivity in Metal-Organic Framework Thin...

    Office of Scientific and Technical Information (OSTI)

    Tunable Electrical Conductivity in Metal-Organic Framework Thin-Film Devices Citation Details In-Document Search Title: Tunable Electrical Conductivity in Metal-Organic Framework...

  8. Through-thickness Membrane Conductivity Measurement for HTM Program...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Through-thickness Membrane Conductivity Measurement for HTM Program: Issues and Approach Through-thickness Membrane Conductivity Measurement for HTM Program: Issues and Approach ...

  9. Thermal conductivity and diffusion-mediated localization in Fe1...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Thermal conductivity and diffusion-mediated localization in Fe1-xCrx alloys from first principles Citation Details In-Document Search Title: Thermal conductivity ...

  10. Intrinsic charge and spin conductivities of doped graphene in...

    Office of Scientific and Technical Information (OSTI)

    Intrinsic charge and spin conductivities of doped graphene in the Fermi-liquid regime Prev Next Title: Intrinsic charge and spin conductivities of doped graphene in the ...

  11. Flowing Electrical Conductivity At Jemez Pueblo Area (DOE GTP...

    Open Energy Info (EERE)

    Flowing Electrical Conductivity At Jemez Pueblo Area (DOE GTP) Jump to: navigation, search GEOTHERMAL ENERGYGeothermal Home Exploration Activity: Flowing Electrical Conductivity At...

  12. Equilibration dynamics and conductivity of warm dense hydrogen...

    Office of Scientific and Technical Information (OSTI)

    Equilibration dynamics and conductivity of warm dense hydrogen Citation Details In-Document Search Title: Equilibration dynamics and conductivity of warm dense hydrogen Authors: ...

  13. T I ENHANCING THERMAL CONDUCTIVITY OF FLUIDS WITH NANOPARTICLES...

    Office of Scientific and Technical Information (OSTI)

    ... particles have been conducted since Maxwell's theoretical work was published more than ... Maxwell's model shows that the effective thermal conductivity of suspensions that contain ...

  14. Enterprise Assessments Assessment of Conduct of Maintenance at...

    Energy Savers [EERE]

    Conduct of Maintenance at the Waste Isolation Pilot Plant - June 2016 Enterprise Assessments Assessment of Conduct of Maintenance at the Waste Isolation Pilot Plant - June 2016 ...

  15. Commonwealth Aluminum: Manufacturer Conducts Plant-Wide Energy...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Commonwealth Aluminum: Manufacturer Conducts Plant-Wide Energy Assessments at Two Aluminum Sheet Production Operations Commonwealth Aluminum: Manufacturer Conducts Plant-Wide ...

  16. Magnetic flowmeter for electrically conductive liquid

    DOE Patents [OSTI]

    Skladzien, Stanley B.; Raue, Donald J.

    1982-01-01

    A magnetic flowmeter includes first and second tube sections each having ls of non-magnetic material. The first tube is suitably connected to a process for passing a flow of an electrically conductive fluid to be measured. The second tube is established as a reference containing a still medium and is maintained at the same temperature as the first tube. A rotatable magnet assembly is disposed between the two tubes with at least two magnets attached to radially extending arms from a central shaft. Each magnet includes an air gap suitably sized to pass astraddle the diameter along a portion of the length of each of the two tubes. The magnets are provided in matched pairs spaced 180.degree. apart such that signals will be simultaneously generated in signal leads attached to each of the two tubes. By comparing the signals from the two tubes and varying the rotating speed of the magnet assembly until the signals are equal, or attain a maximum, the flow velocity of the fluid within the first tube can be determined. Through temperature monitoring and appropriate heaters, the two tubes are maintained at the same temperature.

  17. Magnetic flowmeter for electrically conductive liquid

    DOE Patents [OSTI]

    Skladzien, S.B.; Raue, D.J.

    1980-08-18

    A magnetic flowmeter includes first and second tube sections each having walls of non-magnetic material. The first tube is suitably connected to a process for passing a flow of an electrically conductive fluid to be measured. The second tube is established as a reference containing a still medium and is maintained at the same temperature as the first tube. A rotatable magnet assembly is disposed between the two tubes with at least two magnets attached to radially extending arms from a central shaft. Each magnet includes an air gap suitably sized to pass astraddle the diameter along a portion of the length of each of the two tubes. Two magnets are provided in matched pairs spaced 180/sup 0/ apart such that signals will be simultaneously generated in signal leads attached to each of the two tubes. By comparing the signals from the two tubes and varying the rotating speed of the magnet assembly until the signals are equal, or attain a maximum, the flow velocity of the fluid within the first tube can be determined. Through temperature monitoring and appropriate heaters, the two tubes are maintained at the same temperature.

  18. Ion/proton-conducting apparatus and method

    DOE Patents [OSTI]

    Yates, Matthew; Xue, Wei

    2014-12-23

    A c-axis-oriented HAP thin film synthesized by seeded growth on a palladium hydrogen membrane substrate. An exemplary synthetic process includes electrochemical seeding on the substrate, and secondary and tertiary hydrothermal treatments under conditions that favor growth along c-axes and a-axes in sequence. By adjusting corresponding synthetic conditions, an HAP this film can be grown to a controllable thickness with a dense coverage on the underlying substrate. The thin films have relatively high proton conductivity under hydrogen atmosphere and high temperature conditions. The c-axis oriented films may be integrated into fuel cells for application in the intermediate temperature range of 200-600.degree. C. The electrochemical-hydrothermal deposition technique may be applied to create other oriented crystal materials having optimized properties, useful for separations and catalysis as well as electronic and electrochemical applications, electrochemical membrane reactors, and in chemical sensors. Additional high-density and gas-tight HAP film compositions may be deposited using a two-step deposition method that includes an electrochemical deposition method followed by a hydrothermal deposition method. The two-step method uses a single hydrothermal deposition solution composition. The method may be used to deposit HAP films including but not limited to at least doped HAP films, and more particularly including carbonated HAP films. In addition, the high-density and gas-tight HAP films may be used in proton exchange membrane fuel cells.

  19. Thin transparent conducting films of cadmium stannate

    DOE Patents [OSTI]

    Wu, Xuanzhi; Coutts, Timothy J.

    2001-01-01

    A process for preparing thin Cd.sub.2 SnO.sub.4 films. The process comprises the steps of RF sputter coating a Cd.sub.2 SnO.sub.4 layer onto a first substrate; coating a second substrate with a CdS layer; contacting the Cd.sub.2 SnO.sub.4 layer with the CdS layer in a water- and oxygen-free environment and heating the first and second substrates and the Cd.sub.2 SnO.sub.4 and CdS layers to a temperature sufficient to induce crystallization of the Cd.sub.2 SnO.sub.4 layer into a uniform single-phase spinel-type structure, for a time sufficient to allow full crystallization of the Cd.sub.2 SnO.sub.4 layer at that temperature; cooling the first and second substrates to room temperature; and separating the first and second substrates and layers from each other. The process can be conducted at temperatures less than 600.degree. C., allowing the use of inexpensive soda lime glass substrates.

  20. Thin film method of conducting lithium-ions (Patent) | DOEPatents

    Office of Scientific and Technical Information (OSTI)

    uses in lithium batteries, electrochromic devices and other electrochemical applications. ... conductivity; suitable; lithium; batteries; electrochromic; devices; ...

  1. Materials and methods for autonomous restoration of electrical conductivity

    DOE Patents [OSTI]

    Blaiszik, Benjamin J; Odom, Susan A; Caruso, Mary M; Jackson, Aaron C; Baginska, Marta B; Ritchey, Joshua A; Finke, Aaron D; White, Scott R; Moore, Jeffrey S; Sottos, Nancy R; Braun, Paul V; Amine, Khalil

    2014-03-25

    An autonomic conductivity restoration system includes a solid conductor and a plurality of particles. The particles include a conductive fluid, a plurality of conductive microparticles, and/or a conductive material forming agent. The solid conductor has a first end, a second end, and a first conductivity between the first and second ends. When a crack forms between the first and second ends of the conductor, the contents of at least a portion of the particles are released into the crack. The cracked conductor and the released contents of the particles form a restored conductor having a second conductivity, which may be at least 90% of the first conductivity.

  2. Enterprise Assessments Assessment of Conduct of Maintenance at the Waste

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Isolation Pilot Plant - June 2016 | Department of Energy Conduct of Maintenance at the Waste Isolation Pilot Plant - June 2016 Enterprise Assessments Assessment of Conduct of Maintenance at the Waste Isolation Pilot Plant - June 2016 June 2016 Assessment of Conduct of Maintenance at the Waste Isolation Pilot Plant The U.S. Department of Energy Office of Environment, Safety and Health Assessments, within the independent Office of Enterprise Assessments, conducted an assessment of the conduct

  3. LM Conducts Groundwater and Soil Investigation at Riverton, Wyoming, in

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Response to 2010 Flood | Department of Energy Conducts Groundwater and Soil Investigation at Riverton, Wyoming, in Response to 2010 Flood LM Conducts Groundwater and Soil Investigation at Riverton, Wyoming, in Response to 2010 Flood October 16, 2012 - 10:50am Addthis LM Conducts Groundwater and Soil Investigation at Riverton, Wyoming, in Response to 2010 Flood LM Conducts Groundwater and Soil Investigation at Riverton, Wyoming, in Response to 2010 Flood LM Conducts Groundwater and Soil

  4. Procedure for Performing In-Plane Membrane Conductivity Testing |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy In-Plane Membrane Conductivity Testing Procedure for Performing In-Plane Membrane Conductivity Testing Presented at the 2009 High Temperature Membrane Working Group Meeting held May 18, 2009, in Arlington, Virginia htmwg_may09_conductivity_testing.pdf (1.01 MB) More Documents & Publications In-Plane Conductivity Testing Procedures and Results High Temperature Membrane Working Group Minutes In Plane Conductivity Testing, BekkTech LLC

  5. Los Alamos probes mysteries of uranium dioxide's thermal conductivity

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mysteries of uranium dioxide's thermal conductivity Los Alamos probes mysteries of uranium dioxide's thermal conductivity New research is showing that the thermal conductivity of cubic uranium dioxide is strongly affected by interactions between phonons carrying heat and magnetic spins. August 4, 2014 Illustration of anisotropic thermal conductivity in uranium dioxide (UO2). Scientists are studying the thermal conductivity related to the material's different crystallographic directions, hoping

  6. Variation in Hydraulic Conductivity Over Time at the Monticello Permeable

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Reactive Barrier | Department of Energy Variation in Hydraulic Conductivity Over Time at the Monticello Permeable Reactive Barrier Variation in Hydraulic Conductivity Over Time at the Monticello Permeable Reactive Barrier Variation in Hydraulic Conductivity Over Time at the Monticello Permeable Reactive Barrier Variation in Hydraulic Conductivity Over Time at the Monticello Permeable Reactive Barrier (13.57 MB) More Documents & Publications Hydraulic Conductivity of the Monticello

  7. Current conducting end plate of fuel cell assembly

    DOE Patents [OSTI]

    Walsh, Michael M.

    1999-01-01

    A fuel cell assembly has a current conducting end plate with a conductive body formed integrally with isolating material. The conductive body has a first surface, a second surface opposite the first surface, and an electrical connector. The first surface has an exposed portion for conducting current between a working section of the fuel cell assembly and the electrical connector. The isolating material is positioned on at least a portion of the second surface. The conductive body can have support passage(s) extending therethrough for receiving structural member(s) of the fuel cell assembly. Isolating material can electrically isolate the conductive body from the structural member(s). The conductive body can have service passage(s) extending therethrough for servicing one or more fluids for the fuel cell assembly. Isolating material can chemically isolate the one or more fluids from the conductive body. The isolating material can also electrically isolate the conductive body from the one or more fluids.

  8. Beam spoiling a reflector antenna with conducting shim. (Technical...

    Office of Scientific and Technical Information (OSTI)

    Beam spoiling a reflector antenna with conducting shim. Citation Details In-Document Search Title: Beam spoiling a reflector antenna with conducting shim. A horn-fed dish reflector...

  9. NO.sub.x sensing devices having conductive oxide electrodes

    SciTech Connect (OSTI)

    Montgomery, Frederick C.; West, David L.; Armstrong, Timothy R.; Maxey, Lonnie C.

    2010-03-16

    A NO.sub.x sensing device includes at least one pair of spaced electrodes, at least one of which is made of a conductive oxide, and an oxygen-ion conducting material in bridging electrical communication with the electrodes.

  10. ENSURING ACCESS TO FEDERALLY CONDUCTED PROGRAMS AND ACTIVITIES BY

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    INDIVIDUALS WITH LIMITED ENGLISH PROFICIENCY (LEP) PLAN | Department of Energy Information On FEDERALLY CONDUCTED PROGRAMS AND ACTIVITIES ENSURING ACCESS TO FEDERALLY CONDUCTED PROGRAMS AND ACTIVITIES BY INDIVIDUALS WITH LIMITED ENGLISH PROFICIENCY (LEP) PLAN (55.86

  11. Excellent Stability of a Lithium-Ion-Conducting Solid Electrolyte...

    Office of Scientific and Technical Information (OSTI)

    Excellent Stability of a Lithium-Ion-Conducting Solid Electrolyte upon Reversible Li+H+ Exchange in Aqueous Solutions Title: Excellent Stability of a Lithium-Ion-Conducting Solid ...

  12. T I ENHANCING THERMAL CONDUCTIVITY OF FLUIDS WITH NANOPARTICLES...

    Office of Scientific and Technical Information (OSTI)

    JAM 1 1 1935 b T I ENHANCING THERMAL CONDUCTIVITY OF FLUIDS WITH NANOPARTICLES* Stephen U. ... THERMAL CONDUCTIVITY OF FLUIDS WITH NANOPARTICLES Stephen U. S. Choi 1 and Jeffrey A. ...

  13. Controlling Surface Properties of Transparent Conducting Oxides | ANSER

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Center | Argonne-Northwestern National Laboratory Controlling Surface Properties of Transparent Conducting Oxides Home > Research > ANSER Research Highlights > Controlling Surface Properties of Transparent Conducting Oxides

  14. Status of High Power Tests of Normal Conducting Short Standing...

    Office of Scientific and Technical Information (OSTI)

    Status of High Power Tests of Normal Conducting Short Standing Wave Structures Citation Details In-Document Search Title: Status of High Power Tests of Normal Conducting Short Standing ...

  15. LANL Conducts Watusi Experiment | National Nuclear Security Administration

    National Nuclear Security Administration (NNSA)

    | (NNSA) Conducts Watusi Experiment LANL Conducts Watusi Experiment Nevada Test Site, NV The Los Alamos National Laboratory conducts Watusi, a spectacular high-explosives experiment with a yield equivalent to about 37,000 pounds of TNT, at the Nevada Test Site's Big Explosive Experimental Facility (BEEF). The experiment seeks to demonstrate that existing seismic and infrasound sensors at the test site and across the West used when DOE was conducting underground nuclear tests still can detect

  16. ENSURING ACCESS TO FEDERALLY CONDUCTED PROGRAMS AND ACTIVITIES...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    EEO ENSURING ACCESS TO FEDERALLY CONDUCTED PROGRAMS AND ACTIVITIES BY INDIVIDUALS WITH LIMITED ENGLISH PROFICIENCY (LEP) PLAN (61.75

  17. PROCEDURE FOR CONDUCTING A RECORDS INVENTORY | Department of...

    Energy Savers [EERE]

    FOR CONDUCTING A RECORDS INVENTORY More Documents & Publications Records Management Handbook Records Management Handbook Information and Records Management Transition Guidance...

  18. Alternating-current conductivity and dielectric relaxation of...

    Office of Scientific and Technical Information (OSTI)

    Language: English Subject: 36 MATERIALS SCIENCE; ACTIVATION ENERGY; ALTERNATING CURRENT; COPPER COMPOUNDS; DIELECTRIC MATERIALS; DIELECTRIC PROPERTIES; ELECTRIC CONDUCTIVITY; ...

  19. Photovoltaic device having light transmitting electrically conductive stacked films

    DOE Patents [OSTI]

    Weber, Michael F.; Tran, Nang T.; Jeffrey, Frank R.; Gilbert, James R.; Aspen, Frank E.

    1990-07-10

    A light transmitting electrically conductive stacked film, useful as a light transmitting electrode, including a first light transmitting electrically conductive layer, having a first optical thickness, a second light transmitting layer, having a second optical thickness different from the optical thickness of the first layer, and an electrically conductive metallic layer interposed between and in initimate contact with the first and second layers.

  20. Deposition and post-processing techniques for transparent conductive films

    DOE Patents [OSTI]

    Christoforo, Mark Greyson; Mehra, Saahil; Salleo, Alberto; Peumans, Peter

    2015-01-13

    In one embodiment, a method is provided for fabrication of a semitransparent conductive mesh. A first solution having conductive nanowires suspended therein and a second solution having nanoparticles suspended therein are sprayed toward a substrate, the spraying forming a mist. The mist is processed, while on the substrate, to provide a semitransparent conductive material in the form of a mesh having the conductive nanowires and nanoparticles. The nanoparticles are configured and arranged to direct light passing through the mesh. Connections between the nanowires provide conductivity through the mesh.

  1. A Sensitivity Analysis of a Thin Film Conductivity Estimation Method

    SciTech Connect (OSTI)

    McMasters, Robert L; Dinwiddie, Ralph Barton

    2010-01-01

    An analysis method was developed for determining the thermal conductivity of a thin film on a substrate of known thermal properties using the flash diffusivity method. In order to determine the thermal conductivity of the film using this method, the volumetric heat capacity of the film must be known, as determined in a separate experiment. Additionally, the thermal properties of the substrate must be known, including conductivity and volumetric heat capacity. The ideal conditions for the experiment are a low conductivity film adhered to a higher conductivity substrate. As the film becomes thinner with respect to the substrate or, as the conductivity of the film approaches that of the substrate, the estimation of thermal conductivity of the film becomes more difficult. The present research examines the effect of inaccuracies in the known parameters on the estimation of the parameter of interest, the thermal conductivity of the film. As such, perturbations are introduced into the other parameters in the experiment, which are assumed to be known, to find the effect on the estimated thermal conductivity of the film. A baseline case is established with the following parameters: Substrate thermal conductivity 1.0 W/m-K Substrate volumetric heat capacity 106 J/m3-K Substrate thickness 0.8 mm Film thickness 0.2 mm Film volumetric heat capacity 106 J/m3-K Film thermal conductivity 0.01 W/m-K Convection coefficient 20 W/m2-K Magnitude of heat absorbed during the flash 1000 J/m2 Each of these parameters, with the exception of film thermal conductivity, the parameter of interest, is varied from its baseline value, in succession, and placed into a synthetic experimental data file. Each of these data files is individually analyzed by the program to determine the effect on the estimated film conductivity, thus quantifying the vulnerability of the method to measurement errors.

  2. Using electrical impedance tomography to map subsurface hydraulic conductivity

    DOE Patents [OSTI]

    Berryman, James G.; Daily, William D.; Ramirez, Abelardo L.; Roberts, Jeffery J.

    2000-01-01

    The use of Electrical Impedance Tomography (EIT) to map subsurface hydraulic conductivity. EIT can be used to map hydraulic conductivity in the subsurface where measurements of both amplitude and phase are made. Hydraulic conductivity depends on at least two parameters: porosity and a length scale parameter. Electrical Resistance Tomography (ERT) measures and maps electrical conductivity (which can be related to porosity) in three dimensions. By introducing phase measurements along with amplitude, the desired additional measurement of a pertinent length scale can be achieved. Hydraulic conductivity controls the ability to flush unwanted fluid contaminants from the surface. Thus inexpensive maps of hydraulic conductivity would improve planning strategies for subsequent remediation efforts. Fluid permeability is also of importance for oil field exploitation and thus detailed knowledge of fluid permeability distribution in three-dimension (3-D) would be a great boon to petroleum reservoir analysts.

  3. Anisotropy of heat conduction in Mo/Si multilayers

    SciTech Connect (OSTI)

    Medvedev, V. V.; Yakshin, A. E.; Kruijs, R. W. E. van de; Bijkerk, F.; Yang, J.; Schmidt, A. J.; Zoethout, E.

    2015-08-28

    This paper reports on the studies of anisotropic heat conduction phenomena in Mo/Si multilayers with individual layer thicknesses selected to be smaller than the mean free path of heat carriers. We applied the frequency-domain thermoreflectance technique to characterize the thermal conductivity tensor. While the mechanisms of the cross-plane heat conduction were studied in detail previously, here we focus on the in-plane heat conduction. To analyze the relative contribution of electron transport to the in-plane heat conduction, we applied sheet-resistance measurements. Results of Mo/Si multilayers with variable thickness of the Mo layers indicate that the net in-plane thermal conductivity depends on the microstructure of the Mo layers.

  4. Method and apparatus for casting conductive and semiconductive materials

    DOE Patents [OSTI]

    Ciszek, Theodore F.

    1986-01-01

    A method and apparatus is disclosed for casting conductive and semiconduce materials. The apparatus includes a plurality of conductive members arranged to define a container-like area having a desired cross-sectional shape. A portion or all of the conductive or semiconductive material which is to be cast is introduced into the container-like area. A means is provided for inducing the flow of an electrical current in each of the conductive members, which currents act collectively to induce a current flow in the material. The induced current flow through the conductive members is in a direction substantially opposite to the induced current flow in the material so that the material is repelled from the conductive members during the casting process.

  5. NNSA Conducts Pollux Subcritical Experiment at Nevada National Security

    National Nuclear Security Administration (NNSA)

    Site | National Nuclear Security Administration | (NNSA) Conducts Pollux Subcritical Experiment at Nevada National Security Site December 06, 2012 LAS VEGAS - The National Nuclear Security Administration (NNSA) today announced that Pollux, a subcritical experiment, was successfully conducted yesterday at its Nevada National Security Site (NNSS). The experiment, conducted by staff from NNSS, Los Alamos National Laboratory and Sandia National Laboratories, gathered scientific data that will

  6. Enterprise Assessments Assessment of Selected Conduct of Operations

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Processes at the Waste Isolation Pilot Plant - April 2016 | Department of Energy Selected Conduct of Operations Processes at the Waste Isolation Pilot Plant - April 2016 Enterprise Assessments Assessment of Selected Conduct of Operations Processes at the Waste Isolation Pilot Plant - April 2016 April 2016 Assessment of Selected Conduct of Operations Processes at the Waste Isolation Pilot Plant - April 2016 The U.S. Department of Energy's Office of Environment, Safety and Health Assessments,

  7. Ethics - Fourteen Principles of Ethical Conduct for Federal Employees |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Fourteen Principles of Ethical Conduct for Federal Employees Ethics - Fourteen Principles of Ethical Conduct for Federal Employees This guide provides a brief overview of the ethics rules and standards of ethical conduct that all employees should know and follow. Discuss any question not answered here with your supervisor or ethics counsel. Your ethics counsel is: For Field Office employees, your respective field counsel. For Headquarters employees, the Office of the

  8. A Discussion of Conductivity Testing in High Temperature Membranes (lessons

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    learned in assessing transport) | Department of Energy of Conductivity Testing in High Temperature Membranes (lessons learned in assessing transport) A Discussion of Conductivity Testing in High Temperature Membranes (lessons learned in assessing transport) Presentation on conductivity testing in high temperature membranes given by Jim Boncella of Los Alamos National Laboratory at the High Temperature Membrane Working Group meeting in October 2005. htmwg05_boncella.pdf (567.61 KB) More

  9. Teachers Conduct Research at Prestigious Department of Energy Laboratory |

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Jefferson Lab Conduct Research at Prestigious Department of Energy Laboratory Teachers Conduct Research at Prestigious Department of Energy Laboratory Twenty-nine high school and middle school physics, physical science, and engineering/technology teachers from four states are participating in the Continuous Electron Beam Accelerator Facility's Summer Institute for Teacher Enhancement (SITE). The four week Institute enables teachers to conduct practical and essential group research on a

  10. Public Comments Received on the Draft Voluntary Code of Conduct |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Received on the Draft Voluntary Code of Conduct Public Comments Received on the Draft Voluntary Code of Conduct OE and the Federal Smart Grid Task Force facilitated a multi-stakeholder process to develop a Voluntary Code of Conduct (VCC) for utilities and third parties providing consumer energy use services that will address privacy related to data enabled by smart grid technologies. Industry stakeholders attended open meetings and participated in work group activities

  11. Through-thickness Membrane Conductivity Measurement for HTM Program: Issues

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    and Approach | Department of Energy Through-thickness Membrane Conductivity Measurement for HTM Program: Issues and Approach Through-thickness Membrane Conductivity Measurement for HTM Program: Issues and Approach DOE HTMWG Meeting, Presented by Kevin Cooper of Scribner Associates, Inc. on September 14, 2006. htmwg_cooper.pdf (566.46 KB) More Documents & Publications Progress and Status on Through-Plane Resistance and Conductivity Measurement of Fuel Cell Membranes High Temperature

  12. Vehicle Technologies Office Merit Review 2015: Wireless & Conductive

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Charging Testing to support Code & Standards | Department of Energy Wireless & Conductive Charging Testing to support Code & Standards Vehicle Technologies Office Merit Review 2015: Wireless & Conductive Charging Testing to support Code & Standards Presentation given by Idaho National Laboratory at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about wireless and conductive charging testing to

  13. NNSA's Summary of Experiments Conducted in Support of Stockpile

    National Nuclear Security Administration (NNSA)

    Stewardship now available | National Nuclear Security Administration | (NNSA) Summary of Experiments Conducted in Support of Stockpile Stewardship now available Tuesday, March 25, 2014 - 2:38pm The most recent NNSA quarterly summary of experiments conducted as part of its science-based stockpile stewardship program is now available here. The quarterly summary prepared by NNSA's Office of Defense Programs provides descriptions of key NNSA facilities that conduct stockpile stewardship

  14. News Release: DOE to Conduct Additional Groundwater Tests at...

    Office of Environmental Management (EM)

    The U.S. Department of Energy will conduct additional characterization work at the Riverton, WY, Uranium Mill Tailings Radiation Control Act (UMTRCA) Site this summer, including ...

  15. NNSA to conduct Aerial Radiation Assessment Survey over Boston...

    National Nuclear Security Administration (NNSA)

    conduct Aerial Radiation Assessment Survey over Boston area March 31, 2015 BOSTON- A ... 2015. The purpose of the flyovers is to measure naturally occurring background radiation. ...

  16. NNSA to conduct Aerial Radiation Assessment Survey over Boston...

    National Nuclear Security Administration (NNSA)

    conduct Aerial Radiation Assessment Survey over Boston area April 11, 2016 BOSTON - On ... helicopter flights around Boston to measure naturally occurring background radiation. ...

  17. NNSA to Conduct Aerial Radiation Monitoring Survey Over Philadelphia...

    National Nuclear Security Administration (NNSA)

    Conduct Aerial Radiation Monitoring Survey Over Philadelphia July 18-20 July 19, 2016 ... naturally occurring background radiation in support of the Democratic National Convention. ...

  18. Continuous Processing of High Thermal Conductivity Polyethylene Fibers and Sheets

    Broader source: Energy.gov [DOE]

    Project to develop and validate a continuous manufacturing process for polyethylene fibers and sheets yielding a thermal conductivity value greater than 60 W/m.K.

  19. Effect of Doping on Surface Reactivity and Conduction Mechanism...

    Office of Scientific and Technical Information (OSTI)

    proton conduction is prevalent, featured by lower activation energy and higher mobility. ... 3 ; Lee, Tien-Lin 3 ; Baddorf, Arthur P. 2 ; Wisinger, Nina 2 ; Jesse, Stephen ...

  20. Chemical anchoring of organic conducting polymers to semiconducting surfaces

    DOE Patents [OSTI]

    Frank, A.J.; Honda, K.

    1984-01-01

    According to the present invention, an improved method of coating electrodes with conductive polymer films and/or preselected catalysts is provided. The charge conductive polymer is covalently or coordinatively attached to the electrode surface to strengthen the adhesion characteristics of the polymer to the electrode surface or to improve charge conductive properties between the conductive polymer and the electrode surface. Covalent or coordinative attachment is achieved by a number of alternative methods including covalently or coordinatively attaching the desired monomer to the electrode by means of a suitable coupling reagent and, thereafter, electrochemically polymerizing the monomer in situ.

  1. Oscillatory Magneto Conductance in Carbon Atom Wires | Energy...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Our calculation shows a spin valve behavior with the parallel magnetization state between the two Co atoms giving higher conductance than the respective antiparallel magnetization ...

  2. Leading-order calculation of electric conductivity in hot quantum...

    Office of Scientific and Technical Information (OSTI)

    Subject: 72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS; ACTION INTEGRAL; CALCULATION METHODS; ELECTRIC CONDUCTIVITY; FEYNMAN DIAGRAM; GAUGE INVARIANCE; INTEGRAL EQUATIONS; QUANTUM ...

  3. Unique Carbon-Coated Cathodes Improve Electrical Conductivity...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Unique Carbon-Coated Cathodes Improve Electrical Conductivity (ANL-IN-09-043) Procedure Using Carbon Precursors Have Proved Superior to Conventional Methods Argonne National...

  4. Bac2 Conductive Composites formerly Bac2 Electrode Materials...

    Open Energy Info (EERE)

    scale, commercially available electrically conductive polymer for use in fuel cell bipolar plates. Coordinates: 40.175472, -75.041471 Show Map Loading map......

  5. Community Wind Handbook/Understand Your Wind Resource and Conduct...

    Open Energy Info (EERE)

    * Engage with Neighbors * Conduct a Wind Resource Estimate * Research Interconnecting behind Your Meter * Research Project Economics & Financing * Select the Final Design &...

  6. Bureau of Land Management - Notice of Intent to Conduct Geothermal...

    Open Energy Info (EERE)

    to: navigation, search OpenEI Reference LibraryAdd to library Form: Bureau of Land Management - Notice of Intent to Conduct Geothermal Resource Exploration Operations Abstract...

  7. First-principles prediction of phononic thermal conductivity...

    Office of Scientific and Technical Information (OSTI)

    There has been great interest in two-dimensional materials, beyond graphene, for both ... SILICENE; THERMAL CONDUCTIVITY; TRANSPORT THEORY; TWO-DIMENSIONAL SYSTEMS; VISIBLE ...

  8. NNSA, NATO Conduct Emergency Response Training in the Czech Republic...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    NNSA, NATO Conduct Emergency Response Training in the Czech Republic June 04, 2014 ... Radiological Assistance Program Training for Emergency Response (I-RAPTER) course ...

  9. LLNL Conducts First Plutonium Shot Using the JASPER Gas Gun ...

    National Nuclear Security Administration (NNSA)

    LLNL Conducts First Plutonium Shot Using the JASPER Gas Gun Nevada Test Site, NV The ... Actinide Shock Physics Experimental Research (JASPER) gas gun at NNSA's Nevada Test Site. ...

  10. ETA-NAC002 - Control of Test Conduct

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Control of Test Conduct Prepared by Electric Transportation Applications Prepared by: ... APPENDICES Appendix A - Test Exception Report 10 Appendix B - Non-Conformance Report 11 ...

  11. Conducting and Using Energy Efficiency Studies for States Presentation

    Broader source: Energy.gov [DOE]

    This presentation, given through the DOE's Technical Assistance Program (TAP), provides information on how to effectively conduct and use Energy Efficiency Studies for States.

  12. Glass-like thermal conductivity in high efficiency thermoelectric materials

    Broader source: Energy.gov [DOE]

    Discusses strategies to design thermoelectric materials with extremely low lattice thermal conductivity through modifications of the phonon band structure and phonon relaxation time.

  13. Erratum: Leading-order calculation of electric conductivity in...

    Office of Scientific and Technical Information (OSTI)

    Subject: 72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS; CALCULATION METHODS; ELECTRIC CONDUCTIVITY; ERRORS; FEYNMAN DIAGRAM; QUANTUM ELECTRODYNAMICS Word Cloud More Like This Full ...

  14. Stiff and Electrically Conductive Composites of Carbon Nanotube...

    Office of Scientific and Technical Information (OSTI)

    Composites of Carbon Nanotube Aerogels and Polymers Citation Details In-Document Search Title: Stiff and Electrically Conductive Composites of Carbon Nanotube Aerogels and ...

  15. Fast lithium-ion conducting thin film electrolytes integrated...

    Office of Scientific and Technical Information (OSTI)

    Fast lithium-ion conducting thin film electrolytes integrated directly on flexible substrates for high power solid-state batteries. Citation Details In-Document Search Title: Fast ...

  16. Seven Universities Selected To Conduct Advanced Turbine Technology...

    Broader source: Energy.gov (indexed) [DOE]

    by the U.S. Department of Energy (DOE) to conduct advanced turbine technology studies under the Office of Fossil Energy's (FE) University Turbine Systems Research (UTSR) Program. ...

  17. Experimental and numerical study of the effective thermal conductivity...

    Office of Scientific and Technical Information (OSTI)

    to describe interface resistance of particles in modern TIMs, aka particulate composites. ... Country of Publication: United States Language: English Subject: Thermal Conductivity; ...

  18. Rechargeable Aluminum Batteries with Conducting Polymers as Positive...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Rechargeable Aluminum Batteries with Conducting Polymers as Positive Electrodes. Citation Details In-Document Search Title: Rechargeable Aluminum Batteries with ...

  19. Rechargeable aluminum batteries with conducting polymers as positive...

    Office of Scientific and Technical Information (OSTI)

    Technical Report: Rechargeable aluminum batteries with conducting polymers as positive electrodes. Citation Details In-Document Search Title: Rechargeable aluminum batteries with ...

  20. Rechargeable Aluminum Batteries with Conducting Polymers as Active...

    Office of Scientific and Technical Information (OSTI)

    Conference: Rechargeable Aluminum Batteries with Conducting Polymers as Active Cathode Materials. Citation Details In-Document Search Title: Rechargeable Aluminum Batteries with ...

  1. Chemical anchoring of organic conducting polymers to semiconducting surfaces

    DOE Patents [OSTI]

    Frank, Arthur J. (Lakewood, CO); Honda, Kenji (Wheatridge, CO)

    1984-01-01

    According to the present invention, an improved method of coating electrodes with conductive polymer films and/or preselected catalysts is provided. The charge-conductive polymer is covalently or coordinatively attached to the electrode surface to strengthen the adhesion characteristics of the polymer to the electrode surface or to improve charge-conductive properties between the conductive polymer and the electrode surface. Covalent or coordinative attachment is achieved by a number of alternative methods including covalently or coordinatively attaching the desired monomer to the electrode by means of a suitable coupling reagent and, thereafter, electrochemically polymerizing the monomer in situ.

  2. Progress and Status on Through-Plane Resistance and Conductivity...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Presentation at the High Temperature Membrane Working Group Meeting, Oct. 14, 2010 ... High Temperature, Low Relative Humidity Membrane Program In Plane Conductivity Testing, ...

  3. Conducting Quantitative Electrochemistry on a TEM to Study Rate...

    Office of Scientific and Technical Information (OSTI)

    Conducting Quantitative Electrochemistry on a TEM to Study Rate Dependencies in the ... Research Org: Sandia National Laboratories Livermore, CA; Sandia National Laboratories ...

  4. Excellent Stability of a Lithium-Ion-Conducting Solid Electrolyte...

    Office of Scientific and Technical Information (OSTI)

    Excellent Stability of a Lithium-Ion-Conducting Solid Electrolyte upon Reversible Li+H+ Exchange in Aqueous Solutions Citation Details In-Document Search Title: Excellent ...

  5. Enterprise Assessments Assessment of Selected Conduct of Operations...

    Office of Environmental Management (EM)

    Assessment of Selected Conduct of Operations Processes at the Waste Isolation Pilot Plant ... Manager LOTO LockoutTagout NWP Nuclear Waste Partnership, LLC OFI Opportunity for ...

  6. Enterprise Assessments Assessment of Conduct of Maintenance at...

    Office of Environmental Management (EM)

    Assessment of Conduct of Maintenance at the Waste Isolation Pilot Plant June 2016 Office ... Nuclear Safety Organization NWP Nuclear Waste Partnership, LLC NMMP Nuclear Maintenance ...

  7. Specific heat and thermal conductivity of explosives, mixtures...

    Office of Scientific and Technical Information (OSTI)

    Specific heat and thermal conductivity of explosives, mixtures, and plastic-bonded explosives determined experimentally Baytos, J.F. 45 MILITARY TECHNOLOGY, WEAPONRY, AND NATIONAL...

  8. Last U.S. Underground Nuclear Test Conducted | National Nuclear...

    National Nuclear Security Administration (NNSA)

    U.S. Underground Nuclear Test Conducted | National Nuclear Security Administration Facebook Twitter Youtube Flickr RSS People Mission Managing the Stockpile Preventing...

  9. Tetraarylborate Polymer Networks as Single-Ion Conducting Solid...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Tetraarylborate Polymer Networks as Single-Ion Conducting Solid Electrolytes 2 Previous Next List Van Humbeck, Jeffrey F.; Aubrey, Michael L.; Alsbaiee, Alaaeddin; Ameloot, Rob;...

  10. Compliant Glass-Polymer Hybrid Single Ion-ConductingElectrolytes...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Compliant Glass-Polymer Hybrid Single Ion-ConductingElectrolytes for Lithium Batteries ... excellent electrochemical stability, and limit the dissolution of lithium polysulfides. ...

  11. High thermal conductivity lossy dielectric using co-densified...

    Office of Scientific and Technical Information (OSTI)

    Title: High thermal conductivity lossy dielectric using co-densified multilayer configuration Systems and methods are described for loss dielectrics. A method of manufacturing a ...

  12. STUDENTS WHO RECEIVED GRADUATE DEGREES FROM THESIS WORK CONDUCTED...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    CONDUCTED AT THE CYCLOTRON INSTITUTE April 1, 2001 - March 31, 2001 Name Year Thesis Title Advisor First Position Present Position Douglas Rowland 2000 A Study of the Projectile...

  13. STUDENTS WHO RECEIVED GRADUATE DEGREES FROM THESIS WORK CONDUCTED...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    2 STUDENTS WHO RECEIVED GRADUATE DEGREES FROM THESIS WORK CONDUCTED AT THE CYCLOTRON INSTITUTE April 1, 2010 - March 31, 2011 Name Year Thesis Title Advisor Present Position Zach...

  14. Center for Inverse Design Highlight: Anomalous Surface Conductivity...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    O 3 ) films grown by pulsed laser deposition. This desirable, but unexpected, effect produces conductivities at the surface comparable to intentionally doped commercial materials. ...

  15. Measurement of thermal conductivity in proton irradiated silicon

    SciTech Connect (OSTI)

    Marat Khafizov; Clarissa Yablinsky; Todd Allen; David Hurley

    2014-04-01

    We investigate the influence of proton irradiation on thermal conductivity in single crystal silicon. We apply laser based modulated thermoreflectance technique to extract the change in conductivity of the thin layer damaged by proton irradiation. Unlike time domain thermoreflectance techniques that require application of a metal film, we perform our measurement on uncoated samples. This provides greater sensitivity to the change in conductivity of the thin damaged layer. Using sample temperature as a parameter provides a means to deduce the primary defect structures that limit thermal transport. We find that under high temperature irradiation the degradation of thermal conductivity is caused primarily by extended defects.

  16. Abnormal thermal conductivity in tetragonal tungsten bronze Ba...

    Office of Scientific and Technical Information (OSTI)

    temperature interval. Substitution of Sr for Ba brings about a significant decrease in thermal conductivity at x???3 accompanied by development of a low-temperature...

  17. Alan J. Heeger, Conductive Polymers, and Plastic Solar Cells

    Office of Scientific and Technical Information (OSTI)

    Alan J. Heeger, Conductive Polymers, and Plastic Solar Cells Resources with Additional Information Patents Videos After receiving 'his physics Ph.D. at the University of...

  18. Method of forming an electrically conductive cellulose composite

    DOE Patents [OSTI]

    Evans, Barbara R.; O'Neill, Hugh M.; Woodward, Jonathan

    2011-11-22

    An electrically conductive cellulose composite includes a cellulose matrix and an electrically conductive carbonaceous material incorporated into the cellulose matrix. The electrical conductivity of the cellulose composite is at least 10 .mu.S/cm at 25.degree. C. The composite can be made by incorporating the electrically conductive carbonaceous material into a culture medium with a cellulose-producing organism, such as Gluconoacetobacter hansenii. The composites can be used to form electrodes, such as for use in membrane electrode assemblies for fuel cells.

  19. Electrical and thermal conductivity of low temperature CVD graphene...

    Office of Scientific and Technical Information (OSTI)

    temperature CVD graphene: the effect of disorder Citation Details In-Document Search Title: Electrical and thermal conductivity of low temperature CVD graphene: the effect of ...

  20. Conduct an In-Plant Pumping System Survey; Industrial Technologies...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1 * September 2005 Conduct an In-Plant Pumping System Survey In the United States, more ... BestPractices emphasizes plant systems, where significant efficiency improvements and ...

  1. Enterprise Assessments Assessment of Selected Conduct of Operations...

    Energy Savers [EERE]

    Waste Isolation Pilot Plant - April 2016 Enterprise Assessments Assessment of Selected Conduct of Operations Processes at the Waste Isolation Pilot Plant - April 2016 April 2016 ...

  2. Monitoring of temperature-compensated conductivity in fossil power plants

    SciTech Connect (OSTI)

    Bursik, A.

    1995-01-01

    Specific conductivity is an inexpensive, reliable, on-line method for monitoring the overall level of contaminants and its trends in fossil plant cycles. The most important applications are the monitoring in makeup water and at the economizer inlet. In the makeup, the specific conductivity is related to the content of makeup ionic impurities and carbon dioxide. Specific conductivity at the economizer inlet is an indication of the ammonia level during normal operation, since other ionic impurity levels are relatively very low in relation to the ammonia content. Cation conductivity serves as an excellent diagnostic tool. The advantage of using strong-acid cation exchanger for the alkalizing agents elimination and for the great sensitivity improvement has already been recognized in the 1950`s. The cation conductivity is currently one of the most important {open_quotes}core parameters{close_quotes} in the Cycle Chemistry Improvement Project. In this project, the most important plant cycle locations where cation conductivity on-line monitoring is strongly advised are: condensate pump discharge; polisher outlet or economizer inlet; and hot reheat steam or main steam. An additional monitoring location is the blowdown or the downcomer of drum boilers. The cation conductivity monitoring at this location is becoming vital with the introduction of oxygenated chemistry and OH (sodium hydroxide) treatment in cycles with drum boilers. Degassed cation conductivity has been addressed. Applying this method, the effect of carbon dioxide on cation conductivity is eliminated by boiling off gaseous carbon dioxide before the actual cation conductivity monitoring. Therefore, the degassed cation conductivity reflects only the total non-volatile anionic impurity level.

  3. First Subcritical Experiment Conducted at Nevada Test Site | National

    National Nuclear Security Administration (NNSA)

    Nuclear Security Administration | (NNSA) Subcritical Experiment Conducted at Nevada Test Site First Subcritical Experiment Conducted at Nevada Test Site Nevada Test Site, NV The first "subcritical" physics experiment at the Nevada Test Site, code-name "Rebound," provides scientific data on the behavior of plutonium without underground nuclear-weapons testing

  4. Mechanically stiff, electrically conductive composites of polymers and carbon nanotubes

    DOE Patents [OSTI]

    Worsley, Marcus A.; Kucheyev, Sergei O.; Baumann, Theodore F.; Kuntz, Joshua D.; Satcher, Jr., Joe H.; Hamza, Alex V.

    2015-07-21

    Using SWNT-CA as scaffolds to fabricate stiff, highly conductive polymer (PDMS) composites. The SWNT-CA is immersing in a polymer resin to produce a SWNT-CA infiltrated with a polymer resin. The SWNT-CA infiltrated with a polymer resin is cured to produce the stiff and electrically conductive composite of carbon nanotube aerogel and polymer.

  5. High carrier concentration p-type transparent conducting oxide films

    DOE Patents [OSTI]

    Yan, Yanfa; Zhang, Shengbai

    2005-06-21

    A p-type transparent conducting oxide film is provided which is consisting essentially of, the transparent conducting oxide and a molecular doping source, the oxide and doping source grown under conditions sufficient to deliver the doping source intact onto the oxide.

  6. Method and apparatus for detecting flaws in conductive material

    DOE Patents [OSTI]

    Hockey, R.L.; Riechers, D.M.

    1998-07-07

    The present invention uses a magnet in relative motion to a conductive material, and a coil that is stationary with respect to the magnet to measure perturbation or variation in the magnetic field in the presence of an inclusion. The magnet and coil sensor may be on the same side of the conductive material. 18 figs.

  7. Transparent Conductive Nano-Composites - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Solar Photovoltaic Solar Photovoltaic Electricity Transmission Electricity Transmission Advanced Materials Advanced Materials Find More Like This Return to Search Transparent Conductive Nano-Composites Nanomaterials for Applications Ranging From Photovoltaic Cells to Display Technologies Oak Ridge National Laboratory Contact ORNL About This Technology Technology Marketing Summary Indium Tin Oxide, the most widely used commercial transparent conducting coating, has severe limitations such

  8. Thin Film Electronic Devices with Conductive and Transparent Gas and

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Moisture Permeation Barriers - Energy Innovation Portal Solar Photovoltaic Solar Photovoltaic Electricity Transmission Electricity Transmission Advanced Materials Advanced Materials Find More Like This Return to Search Thin Film Electronic Devices with Conductive and Transparent Gas and Moisture Permeation Barriers National Renewable Energy Laboratory Contact NREL About This Technology Technology Marketing Summary Transparent conducting (TC) materials are extensively used in electronics and

  9. Catalytic synthesis of metal crystals using conductive polymers

    DOE Patents [OSTI]

    Wang, Hsing-Lin; Li, Wenguang

    2008-01-15

    A method of forming metal nanoparticles using a polymer colloid that includes at least one conductive polymer and at least one polyelectrolyte. Metal ions are reduced in water by the conductive polymer to produce the nanoparticles, which may be then incorporated in the colloidal structure to form a colloid composite. The method can also be used to separate selected metal ions from aqueous solutions.

  10. Method and apparatus for detecting flaws in conductive material

    DOE Patents [OSTI]

    Hockey, Ronald L.; Riechers, Douglas M.

    1998-01-01

    The present invention uses a magnet in relative motion to a conductive material, and a coil that is stationary with respect to the magnet to measure perturbation or variation in the magnetic field in the presence of an inclusion. The magnet and coil sensor may be on the same side of the conductive material.

  11. Anisotropic thermal conductivity of thin polycrystalline oxide samples

    SciTech Connect (OSTI)

    Tiwari, A.; Boussois, K.; Nait-Ali, B.; Smith, D. S.; Blanchart, P.

    2013-11-15

    This paper reports about the development of a modified laser-flash technique and relation to measure the in-plane thermal diffusivity of thin polycrystalline oxide samples. Thermal conductivity is then calculated with the product of diffusivity, specific heat and density. Design and operating features for evaluating in-plane thermal conductivities are described. The technique is advantageous as thin samples are not glued together to measure in-plane thermal conductivities like earlier methods reported in literature. The approach was employed to study anisotropic thermal conductivity in alumina sheet, textured kaolin ceramics and montmorillonite. Since it is rare to find in-plane thermal conductivity values for such anisotropic thin samples in literature, this technique offers a useful variant to existing techniques.

  12. Nuclear Spin Lattice Relaxation and Conductivity Studies of the Non-Arrhenius Conductivity Behavior in Lithium Fast Ion Conducting Sulfide Glasses

    SciTech Connect (OSTI)

    Benjamin Michael Meyer

    2003-05-31

    As time progresses, the world is using up more of the planet's natural resources. Without technological advances, the day will eventually arrive when these natural resources will no longer be sufficient to supply all of the energy needs. As a result, society is seeing a push for the development of alternative fuel sources such as wind power, solar power, fuel cells, and etc. These pursuits are even occurring in the state of Iowa with increasing social pressure to incorporate larger percentages of ethanol in gasoline. Consumers are increasingly demanding that energy sources be more powerful, more durable, and, ultimately, more cost efficient. Fast Ionic Conducting (FIC) glasses are a material that offers great potential for the development of new batteries and/or fuel cells to help inspire the energy density of battery power supplies. This dissertation probes the mechanisms by which ions conduct in these glasses. A variety of different experimental techniques give a better understanding of the interesting materials science taking place within these systems. This dissertation discusses Nuclear Magnetic Resonance (NMR) techniques performed on FIC glasses over the past few years. These NMR results have been complimented with other measurement techniques, primarily impedance spectroscopy, to develop models that describe the mechanisms by which ionic conduction takes place and the dependence of the ion dynamics on the local structure of the glass. The aim of these measurements was to probe the cause of a non-Arrhenius behavior of the conductivity which has been seen at high temperatures in the silver thio-borosilicate glasses. One aspect that will be addressed is if this behavior is unique to silver containing fast ion conducting glasses. more specifically, this study will determine if a non-Arrhenius correlation time, {tau}, can be observed in the Nuclear Spin Lattice Relaxation (NSLR) measurements. If so, then can this behavior be modeled with a new single distribution

  13. Characterization of unsaturated hydraulic conductivity at the Hanford Site

    SciTech Connect (OSTI)

    Rockhold, M.L.; Fayler, M.J.; Gee, G.W.

    1988-07-01

    This report details some recent field measurements and compares predicted and measured values of hydraulic conductivities for three locations at the Hanford Site. Measurements from small (6-cm-dia) /open quotes/point/close quotes/ and large (2-m by 2-m) /open quotes/plot/close quotes/ areas utilized inflitration and drainage techniques to obtain in situ data for field-saturated and unsaturated hydraulic conductivity. The Guelph permeameter was used for point sampling, and the unsteady drainage-flux method was used on plots for field-saturated and unsaturated hydraulic conductivity measurements. Steady-state techniques were used to measure unsaturated hydraulic conductivities in small columns in the laboratory for one of the three soils tested to provide a comparison with data obtained from the field. Measured unsaturated hydraulic conductivities and those predicted from particle-size distribution and bulk density data agree within one-half to one and one-half orders of magnitude, depending on soil type. To use a particle-size distribution to estimate water retention characteristics and, subsequently, to predict unsaturated hydraulic conductivities, measurements of water-retention characteristics are necessary to determine a parameter value used in one of the models. No single method for measuring or calculating unsaturated hydraulic conductivities was found appropriate for all Hanford Site soils. Ideally, several methods should be used to take advantage of the strengths of each method, considering the data needs and resources available. 45 refs., 24 figs., 19 tabs.

  14. Relationship between Anisotropy in Soil Hydraulic Conductivity and Saturation

    SciTech Connect (OSTI)

    Zhang, Z. Fred

    2014-01-01

    Anisotropy in unsaturated hydraulic conductivity is saturation-dependent. Accurate characterization of soil anisotropy is very important in simulating flow and contaminant (e.g., radioactive nuclides in Hanford) transport. A recently developed tensorial connectivity-tortuosity (TCT) concept describes the hydraulic conductivity tensor of the unsaturated anisotropic soils as the product of a scalar variable, the symmetric connectivity tortuosity tensor, and the hydraulic conductivity tensor at saturation. In this study, the TCT model is used to quantify soil anisotropy in unsaturated hydraulic conductivity. The TCT model can describe different types of soil anisotropy; e.g., the anisotropy coefficient, C, can be monotonically increase or decrease with saturation and can vary from greater than unity to less than unity and vice versa. Soil anisotropy is independent of soil water retention properties and can be characterized by the ratio of the saturated hydraulic conductivities and the difference of the tortuosity-connectivity coefficients in two directions. ln(C) is linearly proportional to ln(Se) with Se being the effective saturation. The log-linear relationship between C and Se allows the saturation-dependent anisotropy to be determined using linear regression with the measurements of the directional hydraulic conductivities at a minimum of two water content levels, of which one may be at full saturation. The model was tested using measurements of directional hydraulic conductivities.

  15. Electrical studies on silver based fast ion conducting glassy materials

    SciTech Connect (OSTI)

    Rao, B. Appa Kumar, E. Ramesh Kumari, K. Rajani Bhikshamaiah, G.

    2014-04-24

    Among all the available fast ion conductors, silver based glasses exhibit high conductivity. Further, glasses containing silver iodide enhances fast ion conducting behavior at room temperature. Glasses of various compositions of silver based fast ion conductors in the AgI−Ag{sub 2}O−[(1−x)B{sub 2}O{sub 3}−xTeO{sub 2}] (x=0 to1 mol% in steps of 0.2) glassy system have been prepared by melt quenching method. The glassy nature of the compounds has been confirmed by X-ray diffraction. The electrical conductivity (AC) measurements have been carried out in the frequency range of 1 KHz–3MHz by Impedance Analyzer in the temperature range 303–423K. The DC conductivity measurements were also carried out in the temperature range 300–523K. From both AC and DC conductivity studies, it is found that the conductivity increases and activation energy decreases with increasing the concentration of TeO{sub 2} as well as with temperature. The conductivity of the present glass system is found to be of the order of 10{sup −2} S/cm at room temperature. The ionic transport number of these glasses is found to be 0.999 indicating that these glasses can be used as electrolyte in batteries.

  16. QUASI-STEADY CONFIGURATIONS OF CONDUCTIVE INTRACLUSTER MEDIA

    SciTech Connect (OSTI)

    Voit, G. M.

    2011-10-10

    The radial distributions of temperature, density, and gas entropy among cool-core clusters tend to be quite similar, suggesting that they have entered a quasi-steady state. If that state is regulated by a combination of thermal conduction and feedback from a central active galactic nucleus (AGN), then the characteristics of those radial profiles ought to contain information about the spatial distribution of AGN heat input and the relative importance of thermal conduction. This paper addresses those topics by deriving steady-state solutions for clusters in which radiative cooling, electron thermal conduction, and thermal feedback fueled by accretion are all present, with the aim of interpreting the configurations of cool-core clusters in terms of steady-state models. It finds that the core configurations of many cool-core clusters have entropy levels just below those of conductively balanced solutions in which magnetic fields have suppressed electron thermal conduction to {approx}1/3 of the full Spitzer value, suggesting that AGN feedback is triggered when conduction can no longer compensate for radiative cooling. And even when feedback is necessary to heat the central {approx}30 kpc, conduction may still be the most important heating mechanism within a cluster's central {approx}100 kpc.

  17. Cosmological simulations of isotropic conduction in galaxy clusters

    SciTech Connect (OSTI)

    Smith, Britton; O'Shea, Brian W.; Voit, G. Mark; Ventimiglia, David; Skillman, Samuel W.

    2013-12-01

    Simulations of galaxy clusters have a difficult time reproducing the radial gas-property gradients and red central galaxies observed to exist in the cores of galaxy clusters. Thermal conduction has been suggested as a mechanism that can help bring simulations of cluster cores into better alignment with observations by stabilizing the feedback processes that regulate gas cooling, but this idea has not yet been well tested with cosmological numerical simulations. Here we present cosmological simulations of 10 galaxy clusters performed with five different levels of isotropic Spitzer conduction, which alters both the cores and outskirts of clusters, though not dramatically. In the cores, conduction flattens central temperature gradients, making them nearly isothermal and slightly lowering the central density, but failing to prevent a cooling catastrophe there. Conduction has little effect on temperature gradients outside of cluster cores because outward conductive heat flow tends to inflate the outer parts of the intracluster medium (ICM), instead of raising its temperature. In general, conduction tends reduce temperature inhomogeneity in the ICM, but our simulations indicate that those homogenizing effects would be extremely difficult to observe in ?5 keV clusters. Outside the virial radius, our conduction implementation lowers the gas densities and temperatures because it reduces the Mach numbers of accretion shocks. We conclude that, despite the numerous small ways in which conduction alters the structure of galaxy clusters, none of these effects are significant enough to make the efficiency of conduction easily measurable, unless its effects are more pronounced in clusters hotter than those we have simulated.

  18. Humidifier for fuel cell using high conductivity carbon foam

    DOE Patents [OSTI]

    Klett, James W.; Stinton, David P.

    2006-12-12

    A method and apparatus of supplying humid air to a fuel cell is disclosed. The extremely high thermal conductivity of some graphite foams lends itself to enhance significantly the ability to humidify supply air for a fuel cell. By utilizing a high conductivity pitch-derived graphite foam, thermal conductivity being as high as 187 W/m.dot.K, the heat from the heat source is more efficiently transferred to the water for evaporation, thus the system does not cool significantly due to the evaporation of the water and, consequently, the air reaches a higher humidity ratio.

  19. Measurements of prompt radiation induced conductivity of Kapton.

    SciTech Connect (OSTI)

    Preston, Eric F.; Zarick, Thomas Andrew; Sheridan, Timothy J.; Hartman, E. Frederick; Stringer, Thomas Arthur

    2010-10-01

    We performed measurements of the prompt radiation induced conductivity in thin samples of Kapton (polyimide) at the Little Mountain Medusa LINAC facility in Ogden, UT. Three mil samples were irradiated with a 0.5 {mu}s pulse of 20 MeV electrons, yielding dose rates of 1E9 to 1E10 rad/s. We applied variable potentials up to 2 kV across the samples and measured the prompt conduction current. Analysis rendered prompt conductivity coefficients between 6E-17 and 2E-16 mhos/m per rad/s, depending on the dose rate and the pulse width.

  20. A New Route to Nanoscale Conducting Channels in Insulating Oxides

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A New Route to Nanoscale Conducting Channels in Insulating Oxides A New Route to Nanoscale Conducting Channels in Insulating Oxides Print Wednesday, 29 August 2012 00:00 Two-dimensional electron gases (2DEGs)-narrow conducting channels at the surfaces and interfaces of semiconductor materials-are the bedrock of conventional electronics. The startling 2004 discovery that such 2DEGs could be engineered at the interface between two insulating transition-metal oxides, SrTiO3 and LaAlO3, initiated a

  1. THERMAL CONDUCTIVITY AND OTHER PROPERTIES OF CEMENTITIOUS GROUTS

    SciTech Connect (OSTI)

    ALLAN,M.

    1998-05-01

    The thermal conductivity and other properties cementitious grouts have been investigated in order to determine suitability of these materials for grouting vertical boreholes used with geothermal heat pumps. The roles of mix variables such as water/cement ratio, sand/cement ratio and superplasticizer dosage were measured. In addition to thermal conductivity, the cementitious grouts were also tested for bleeding, permeability, bond to HDPE pipe, shrinkage, coefficient of thermal expansion, exotherm, durability and environmental impact. This paper summarizes the results for selected grout mixes. Relatively high thermal conductivities were obtained and this leads to reduction in predicted bore length and installation costs. Improvements in shrinkage resistance and bonding were achieved.

  2. May 20, 2015 Webinar - Guidance for Conducting Technical Analyses...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Performance & RIsk Assessment (P&RA) Community of Practice (CoP) Webinar - May 20, 2015 - Guidance for Conducting Technical Analyses for 10 CFR Part 61 by Mr. Chris Grossman (NRC) ...

  3. Differentiation of surface and bulk conductivities in topological...

    Office of Scientific and Technical Information (OSTI)

    We derive a scaling relation of measured resistance with respect to varying inter-probe ... insulators by comparing the conductance scaling of Bi2Se3, Bi2Te2Se, and Sb-doped Bi2Se3 ...

  4. ETA-HAC02 - Control of Test Conduct

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Control of Test Conduct Prepared by Electric Transportation Applications Prepared by: ... 5 6.0 Activity Requirements 5 6.1 Test Activities 5 6.2 Test Exceptions 6 7.0 ...

  5. NNSA Conducts Successful W78 JTA Flight Test | National Nuclear...

    National Nuclear Security Administration (NNSA)

    Test July 08, 2011 WASHINGTON, D.C. - The National Nuclear Security Administration (NNSA), working with the U.S. Air Force, recently conducted a successful W78 Joint Test ...

  6. EERE Success Story-California: Conducting Polymer Binder Boosts...

    Energy Savers [EERE]

    EERE Success Story-California: Conducting Polymer Binder Boosts Storage Capacity, Wins R&D ... Nine R&D 100 Awards EERE Success Story-California: Heliotrope Technologies Wins R&D 100 ...

  7. Process for fabricating composite material having high thermal conductivity

    DOE Patents [OSTI]

    Colella, Nicholas J.; Davidson, Howard L.; Kerns, John A.; Makowiecki, Daniel M.

    2001-01-01

    A process for fabricating a composite material such as that having high thermal conductivity and having specific application as a heat sink or heat spreader for high density integrated circuits. The composite material produced by this process has a thermal conductivity between that of diamond and copper, and basically consists of coated diamond particles dispersed in a high conductivity metal, such as copper. The composite material can be fabricated in small or relatively large sizes using inexpensive materials. The process basically consists, for example, of sputter coating diamond powder with several elements, including a carbide forming element and a brazeable material, compacting them into a porous body, and infiltrating the porous body with a suitable braze material, such as copper-silver alloy, thereby producing a dense diamond-copper composite material with a thermal conductivity comparable to synthetic diamond films at a fraction of the cost.

  8. ENSURING ACCESS TO FEDERALLY CONDUCTED PROGRAMS AND ACTIVITIES BY

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    INDIVIDUALS WITH LIMITED ENGLISH PROFICIENCY (LEP) PLAN | Department of Energy EEO ENSURING ACCESS TO FEDERALLY CONDUCTED PROGRAMS AND ACTIVITIES BY INDIVIDUALS WITH LIMITED ENGLISH PROFICIENCY (LEP) PLAN (61.75

  9. High-Pressure Multi-Mbar Conductivity Experiments on Hydrogen...

    Office of Scientific and Technical Information (OSTI)

    High-Pressure Multi-Mbar Conductivity Experiments on Hydrogen: The Quest for Solid Metallic Hydrogen Citation Details In-Document Search Title: High-Pressure Multi-Mbar ...

  10. Electrical Conductivity of Soils and Rocks | Open Energy Information

    Open Energy Info (EERE)

    Reference LibraryAdd to library Report: Electrical Conductivity of Soils and Rocks Author J.D. McNeill Organization Geonics Limited Published Geonics Limited, 1980 Report Number...

  11. Organic photovoltaic cell incorporating electron conducting exciton blocking layers

    SciTech Connect (OSTI)

    Forrest, Stephen R.; Lassiter, Brian E.

    2014-08-26

    The present disclosure relates to photosensitive optoelectronic devices including a compound blocking layer located between an acceptor material and a cathode, the compound blocking layer including: at least one electron conducting material, and at least one wide-gap electron conducting exciton blocking layer. For example, 3,4,9,10 perylenetetracarboxylic bisbenzimidazole (PTCBI) and 1,4,5,8-napthalene-tetracarboxylic-dianhydride (NTCDA) function as electron conducting and exciton blocking layers when interposed between the acceptor layer and cathode. Both materials serve as efficient electron conductors, leading to a fill factor as high as 0.70. By using an NTCDA/PTCBI compound blocking layer structure increased power conversion efficiency is achieved, compared to an analogous device using a conventional blocking layers shown to conduct electrons via damage-induced midgap states.

  12. Determining the Porosity and Saturated Hydraulic Conductivity of Binary Mixtures

    SciTech Connect (OSTI)

    Zhang, Z. F.; Ward, Anderson L.; Keller, Jason M.

    2009-09-27

    Gravels and coarse sands make up significant portions of some environmentally important sediments, while the hydraulic properties of the sediments are typically obtained in the laboratory using only the fine fraction (e.g., <2 mm or 4.75 mm). Researchers have found that the content of gravel has significant impacts on the hydraulic properties of the bulk soils. Laboratory experiments were conducted to measure the porosity and the saturated hydraulic conductivity of binary mixtures with different fractions of coarse and fine components. We proposed a mixing-coefficient model to estimate the porosity and a power-averaging method to determine the effective particle diameter and further to predict the saturated hydraulic conductivity of binary mixtures. The proposed methods could well estimate the porosity and saturated hydraulic conductivity of the binary mixtures for the full range of gravel contents and was successfully applied to two data sets in the literature.

  13. EM Conducts Third Annual Spanish Language Training with Record Participation

    Broader source: Energy.gov [DOE]

    SAN DIEGO – EM conducted a training program with mock exercises in radiological accident response this year that drew record attendance, more than twice the participants from the year prior.

  14. Conductive layer for biaxially oriented semiconductor film growth

    DOE Patents [OSTI]

    Findikoglu, Alp T.; Matias, Vladimir

    2007-10-30

    A conductive layer for biaxially oriented semiconductor film growth and a thin film semiconductor structure such as, for example, a photodetector, a photovoltaic cell, or a light emitting diode (LED) that includes a crystallographically oriented semiconducting film disposed on the conductive layer. The thin film semiconductor structure includes: a substrate; a first electrode deposited on the substrate; and a semiconducting layer epitaxially deposited on the first electrode. The first electrode includes a template layer deposited on the substrate and a buffer layer epitaxially deposited on the template layer. The template layer includes a first metal nitride that is electrically conductive and has a rock salt crystal structure, and the buffer layer includes a second metal nitride that is electrically conductive. The semiconducting layer is epitaxially deposited on the buffer layer. A method of making such a thin film semiconductor structure is also described.

  15. Microsoft Word - S0162200_VariationHydraulicConductivity-PRB...

    Office of Legacy Management (LM)

    ... row 4: ZVI row 5: ZVI U.S. Department of Energy Variation in Hydraulic Conductivity Over ... PRB Wells Redupgradient alluvium (row 1) Greengravel + zvi (row 2 and 3) Gray ZVI (row ...

  16. NNSA Conducts Radiological Training at Newly Operational Megaport in

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Explosions | National Nuclear Security Administration | (NNSA) NNSA Conducts Experiment to Improve U.S. Ability to Detect Foreign Nuclear Explosions May 26, 2015 Last week, a National Nuclear Security Administration's (NNSA) led-team successfully conducted the fourth in a series of experiments designed to improve our ability to detect underground nuclear explosions. The Source Physics Experiment (SPE-4 Prime) is a fundamental step forward in the U.S. effort to improve arms control

  17. Non carbon mixed conducting materials for PEFC electrocatalysts and

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    electrodes | Department of Energy Non carbon mixed conducting materials for PEFC electrocatalysts and electrodes Non carbon mixed conducting materials for PEFC electrocatalysts and electrodes These slides were presented at the 2010 New Fuel Cell Projects Meeting on September 28, 2010. 11_iit_ramani.pdf (633.7 KB) More Documents & Publications DOE's Fuel Cell Catalyst R&D Activities Analysis of the Durability of PEM FC Membrane Electrode Assemblies in Automotive Applications

  18. Conduct of Engineering and Technical Support Procedure Manual | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Conduct of Engineering and Technical Support Procedure Manual Conduct of Engineering and Technical Support Procedure Manual This procedure defines a standard approach for the control of software and firmware that is not exempt per Manual 1Q, Procedure 20-1, Software Quality Assurance. The software functional classification is based on the intended use of the software and the impact of the results/output on safety, security, and business risk. The provisions of this procedure apply

  19. Recommendation 165: Recommendation on Conducting Future Verifications of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Cleanup | Department of Energy 165: Recommendation on Conducting Future Verifications of Cleanup Recommendation 165: Recommendation on Conducting Future Verifications of Cleanup The ORSSAB commends the DOE policy of obtaining independent verification of DOE Environmental Management-related activities. Recommendation 165 (96.84 KB) DOE response to recommendation 165 (1.39 MB) More Documents & Publications OREM Accomplishments Timeline ORSSAB Meeting - April 2013 Recommendation 170:

  20. NanoCapillary Network Proton Conducting Membranes for High Temperature

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Hydrogen/Air Fuel Cells | Department of Energy NanoCapillary Network Proton Conducting Membranes for High Temperature Hydrogen/Air Fuel Cells NanoCapillary Network Proton Conducting Membranes for High Temperature Hydrogen/Air Fuel Cells A presentation to the High Temperature Membranes Working Group meeting, May 19, 2006. pintauro.pdf (276.25 KB) More Documents & Publications High Temperature Membrane Working Group Vehicle Technologies Office Merit Review 2016: Li-Ion Battery Anodes from

  1. A New Route to Nanoscale Conducting Channels in Insulating Oxides

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A New Route to Nanoscale Conducting Channels in Insulating Oxides Print Two-dimensional electron gases (2DEGs)-narrow conducting channels at the surfaces and interfaces of semiconductor materials-are the bedrock of conventional electronics. The startling 2004 discovery that such 2DEGs could be engineered at the interface between two insulating transition-metal oxides, SrTiO3 and LaAlO3, initiated a worldwide effort to harness the functionality of oxide materials for advanced electronic

  2. A New Route to Nanoscale Conducting Channels in Insulating Oxides

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    New Route to Nanoscale Conducting Channels in Insulating Oxides Print Two-dimensional electron gases (2DEGs)-narrow conducting channels at the surfaces and interfaces of semiconductor materials-are the bedrock of conventional electronics. The startling 2004 discovery that such 2DEGs could be engineered at the interface between two insulating transition-metal oxides, SrTiO3 and LaAlO3, initiated a worldwide effort to harness the functionality of oxide materials for advanced electronic

  3. A New Route to Nanoscale Conducting Channels in Insulating Oxides

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A New Route to Nanoscale Conducting Channels in Insulating Oxides Print Two-dimensional electron gases (2DEGs)-narrow conducting channels at the surfaces and interfaces of semiconductor materials-are the bedrock of conventional electronics. The startling 2004 discovery that such 2DEGs could be engineered at the interface between two insulating transition-metal oxides, SrTiO3 and LaAlO3, initiated a worldwide effort to harness the functionality of oxide materials for advanced electronic

  4. A New Route to Nanoscale Conducting Channels in Insulating Oxides

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A New Route to Nanoscale Conducting Channels in Insulating Oxides Print Two-dimensional electron gases (2DEGs)-narrow conducting channels at the surfaces and interfaces of semiconductor materials-are the bedrock of conventional electronics. The startling 2004 discovery that such 2DEGs could be engineered at the interface between two insulating transition-metal oxides, SrTiO3 and LaAlO3, initiated a worldwide effort to harness the functionality of oxide materials for advanced electronic

  5. A New Route to Nanoscale Conducting Channels in Insulating Oxides

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A New Route to Nanoscale Conducting Channels in Insulating Oxides Print Two-dimensional electron gases (2DEGs)-narrow conducting channels at the surfaces and interfaces of semiconductor materials-are the bedrock of conventional electronics. The startling 2004 discovery that such 2DEGs could be engineered at the interface between two insulating transition-metal oxides, SrTiO3 and LaAlO3, initiated a worldwide effort to harness the functionality of oxide materials for advanced electronic

  6. A New Route to Nanoscale Conducting Channels in Insulating Oxides

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A New Route to Nanoscale Conducting Channels in Insulating Oxides Print Two-dimensional electron gases (2DEGs)-narrow conducting channels at the surfaces and interfaces of semiconductor materials-are the bedrock of conventional electronics. The startling 2004 discovery that such 2DEGs could be engineered at the interface between two insulating transition-metal oxides, SrTiO3 and LaAlO3, initiated a worldwide effort to harness the functionality of oxide materials for advanced electronic

  7. A New Route to Nanoscale Conducting Channels in Insulating Oxides

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    A New Route to Nanoscale Conducting Channels in Insulating Oxides Print Two-dimensional electron gases (2DEGs)-narrow conducting channels at the surfaces and interfaces of semiconductor materials-are the bedrock of conventional electronics. The startling 2004 discovery that such 2DEGs could be engineered at the interface between two insulating transition-metal oxides, SrTiO3 and LaAlO3, initiated a worldwide effort to harness the functionality of oxide materials for advanced electronic

  8. Federal Register Notice: Plan for Conduct of 2012 Electric Transmission

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Congestion Study | Department of Energy Federal Register Notice: Plan for Conduct of 2012 Electric Transmission Congestion Study Federal Register Notice: Plan for Conduct of 2012 Electric Transmission Congestion Study November 10, 2011 - 1:42pm Addthis The Department has issued a Federal Register Notice initiating preparations for development of the 2012 National Electric Transmission Congestion Study. The Department is seeking comments on what publicly-available data and information should

  9. GC Guidance on Conducting and Participating in Conferences | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Guidance on Conducting and Participating in Conferences GC Guidance on Conducting and Participating in Conferences Guidance and FAQs on DOE Employees Participating in and/or Hosting Conferences GC Conference Guidance.pdf (83.86 KB) Conference Co-sponsorship Template.pdf (26.97 KB) More Documents & Publications Acquisition Letter No. AL 2015-09 POLICY FLASH 2015-36 - AL 2015-09 Inspection Report: IG-0433

  10. NNSA to Conduct Aerial Radiation Monitoring Survey Over Philadelphia July

    National Nuclear Security Administration (NNSA)

    18-20 | National Nuclear Security Administration | (NNSA) Conduct Aerial Radiation Monitoring Survey Over Philadelphia July 18-20 July 19, 2016 Philadelphia - On July 18 through July 20, the U.S. Department of Energy's National Nuclear Security Administration's (NNSA) will conduct low-altitude helicopter flights around Philadelphia to measure naturally occurring background radiation in support of the Democratic National Convention. Officials from NNSA announced that the radiation assessment

  11. NNSA to conduct Aerial Radiation Assessment Survey over Boston area |

    National Nuclear Security Administration (NNSA)

    National Nuclear Security Administration | (NNSA) conduct Aerial Radiation Assessment Survey over Boston area April 11, 2016 BOSTON - On April 12 through April 15, the U.S. Department of Energy's National Nuclear Security Administration's (NNSA) will conduct low-altitude helicopter flights around Boston to measure naturally occurring background radiation. Officials from NNSA announced that the radiation assessment will cover approximately 13 square miles. A twin-engine Bell 412 helicopter,

  12. Nanoparticle-Driven Assembly of Highly Conducting Hybrid Block Copolymer

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electrolytes - Joint Center for Energy Storage Research January 13, 2015, Research Highlights Nanoparticle-Driven Assembly of Highly Conducting Hybrid Block Copolymer Electrolytes (Top) The addition of 2 wt% nanoparticles (SEO-LiTFSI-POSS-2) results in an increase in ionic conductivity. STEM images show the bicontinuous morphology of the electrolyte with 2 wt% of nanoparticles. (Bottom) The value of morphology factor, f, for SEO-LiTFSI-POSS-2 is close to unity, the value expected for an

  13. Progress and Status on Through-Plane Resistance and Conductivity

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Measurement of Fuel Cell Membranes | Department of Energy Progress and Status on Through-Plane Resistance and Conductivity Measurement of Fuel Cell Membranes Progress and Status on Through-Plane Resistance and Conductivity Measurement of Fuel Cell Membranes Presentation at the High Temperature Membrane Working Group Meeting, Oct. 14, 2010 high_temp_cooper.pdf (915.85 KB) More Documents & Publications Lead Research and Development Activity for High Temperature, Low Relative Humidity

  14. Jefferson Lab to Conduct Emergency Response Exercise | Jefferson Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    to Conduct Emergency Response Exercise Jefferson Lab to Conduct Emergency Response Exercise on Aug. 9 NEWPORT NEWS, VA, Aug. 9, 2016 - Today, City of Newport News first responders and staff at the Thomas Jefferson National Accelerator Facility will participate in an emergency response exercise. The objective of the exercise is to provide a training opportunity for members of the lab community and for Newport News emergency responders. Local fire department personnel plan to participate in the

  15. Los Alamos conducts important hydrodynamic experiment in Nevada

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    LANL conducts hydrodynamic experiment in Nevada Los Alamos conducts important hydrodynamic experiment in Nevada Hydrodynamic experiments such as Leda involve non-nuclear surrogate materials that mimic many of the properties of nuclear materials. September 8, 2014 Technicians at the Nevada National Security Site make final adjustments to the "Leda" experimental vessel in the "Zero Room" at the underground U1a facility. Technicians at the Nevada National Security Site make

  16. Finite element model for heat conduction in jointed rock masses

    SciTech Connect (OSTI)

    Gartling, D.K.; Thomas, R.K.

    1981-01-01

    A computatonal procedure for simulating heat conduction in a fractured rock mass is proposed and illustrated in the present paper. The method makes use of a simple local model for conduction in the vicinity of a single open fracture. The distributions of fractures and fracture properties within the finite element model are based on a statistical representation of geologic field data. Fracture behavior is included in the finite element computation by locating local, discrete fractures at the element integration points.

  17. Precise Application of Transparent Conductive Oxide Coatings for Flat Panel

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Displays and Photovoltaic Cells | Argonne National Laboratory Precise Application of Transparent Conductive Oxide Coatings for Flat Panel Displays and Photovoltaic Cells Technology available for licensing: New transparent conducting oxide (TCO) coatings are deposited using atomic layer deposition (ALD). Provides uniform coating of complex, 3D nanostructures such as electrodes for next-generation PV cells Improved coating precision uses less material and reduces cost PDF icon

  18. Vehicle Technologies Office Merit Review 2016: Wireless & Conductive

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Charging Testing to Support Code & Standards | Department of Energy Wireless & Conductive Charging Testing to Support Code & Standards Vehicle Technologies Office Merit Review 2016: Wireless & Conductive Charging Testing to Support Code & Standards Presentation given by Idaho National Laboratory (INL) at the 2016 DOE Vehicle Technologies Office and Hydrogen and Fuel Cells Program Annual Merit Review and Peer Evaluation Meeting about Vehicle Systems

  19. Conductive Polymer/Fullerene Blend Thin Films with Honeycomb Framework -

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Energy Innovation Portal Advanced Materials Advanced Materials Find More Like This Return to Search Conductive Polymer/Fullerene Blend Thin Films with Honeycomb Framework Brookhaven National Laboratory Contact BNL About This Technology Publications: PDF Document Publication Structural dynamics and charge transfer via complexation with fullerene in large area conjugated polymer honeycomb thin films (728 KB) Technology Marketing Summary This composite conductive polymer/fullerene blend

  20. Heat conduction in partial vacuum. Final technical progress report

    SciTech Connect (OSTI)

    Thomas, J R

    1980-09-01

    Methods developed for computing conduction heat losses from evacuated solar collectors are reported. Results of such calculations are given, including the minimum vacuum necessary to effectively eliminate conduction. Experiments performed at Owens-Illinois, Inc. to assess helium penetration rates into evacuated collectors are analyzed, and estimates are given as to the likely penetration rate of atmospheric helium. Conclusions are drawn as to the probable effect of helium penetration on the lifetimes of evacuated solar collectors.

  1. Contributions of anharmonic phonon interactions to thermal boundary conductance.

    SciTech Connect (OSTI)

    Hopkins, Patrick E.; Norris, Pamela M.; Duda, John C.

    2010-05-01

    Continued reduction of characteristic dimensions in nanosystems has given rise to increasing importance of material interfaces on the overall system performance. With regard to thermal transport, this increases the need for a better fundamental understanding of the processes affecting interfacial thermal transport, as characterized by the thermal boundary conductance. When thermal boundary conductance is driven by phononic scattering events, accurate predictions of interfacial transport must account for anharmonic phononic coupling as this affects the thermal transmission. In this paper, a new model for phononic thermal boundary conductance is developed that takes into account anharonic coupling, or inelastic scattering events, at the interface between two materials. Previous models for thermal boundary conductance are first reviewed, including the Diffuse Mismatch Model, which only consdiers elastic phonon scattering events, and earlier attempts to account for inelastic phonon scattering, namely, the Maximum Transmission Model and the Higher Harmonic Inelastic model. A new model is derived, the Anharmonic Inelastic Model, which provides a more physical consideration of the effects of inelastic scattering on thermal boundary conductance. This is accomplished by considering specific ranges of phonon frequency interactions and phonon number density conservation. Thus, this model considers the contributions of anharmonic, inelastically scattered phonons to thermal boundary conductance. This new Anharmonic Inelastic Model shows excellent agreement between model predictions and experimental data at the Pb/diamond interface due to its ability to account for the temperature dependent changing phonon population in diamond, which can couple anharmonically with multiple phonons in Pb.

  2. Effects of hydrogen atoms on surface conductivity of diamond film

    SciTech Connect (OSTI)

    Liu, Fengbin Cui, Yan; Qu, Min; Di, Jiejian

    2015-04-15

    To investigate the effects of surface chemisorbed hydrogen atoms and hydrogen atoms in the subsurface region of diamond on surface conductivity, models of hydrogen atoms chemisorbed on diamond with (100) orientation and various concentrations of hydrogen atoms in the subsurface layer of the diamond were built. By using the first-principles method based on density functional theory, the equilibrium geometries and densities of states of the models were studied. The results showed that the surface chemisorbed hydrogen alone could not induce high surface conductivity. In addition, isolated hydrogen atoms in the subsurface layer of the diamond prefer to exist at the bond centre site of the C-C bond. However, such a structure would induce deep localized states, which could not improve the surface conductivity. When the hydrogen concentration increases, the C-H-C-H structure and C-3H{sub bc}-C structure in the subsurface region are more stable than other configurations. The former is not beneficial to the increase of the surface conductivity. However, the latter would induce strong surface states near the Fermi level, which would give rise to high surface conductivity. Thus, a high concentration of subsurface hydrogen atoms in diamond would make significant contributions to surface conductivity.

  3. Spatial dependence of polycrystalline FTOs conductance analyzed by conductive atomic force microscope (C-AFM)

    SciTech Connect (OSTI)

    Peixoto, Alexandre Pessoa; Costa, J. C. da

    2014-05-15

    Fluorine-doped Tin oxide (FTO) is a highly transparent, electrically conductive polycrystalline material frequently used as an electrode in organic solar cells and optical-electronic devices [12]. In this work a spatial analysis of the conductive behavior of FTO was carried out by Conductive-mode Atomic Force Microscopy (C-AFM). Rare highly oriented grains sample give us an opportunity to analyze the top portion of polycrystalline FTO and compare with the border one. It is shown that the current flow essentially takes place through the polycrystalline edge at grain boundaries.

  4. Mixed-conducting dense ceramics for gas separation applications.

    SciTech Connect (OSTI)

    Balachandran, U.; Dorris, S. E.; Dusek, J. T.; Guan, J.; Liu, M.; Ma, B.; Maiya, P. S.; Picciolo, J. J.

    1999-06-22

    Mixed-conducting (electronic and ionic conducting) dense ceramics are used in many applications, including fuel cells, gas separation membranes, batteries, sensors, and electrocatalysis. This paper describes mixed-conducting ceramic membranes that are being developed to selectively remove oxygen and hydrogen from gas streams in a nongalvanic mode of operation (i.e., with no electrodes or external power supply). Ceramic membranes made of Sr-Fe-Co oxide (SFC), which exhibits high combined electronic and oxygen ionic conductivities, can be used for high-purity oxygen separation and/or partial oxidation of methane to synthesis gas (syngas, a mixture of CO and H{sub 2}). The electronic and ionic conductivities of SFC were found to be comparable in magnitude. Steady-state oxygen permeability of SFC has been measured as a function of oxygen-partial-pressure gradient and temperature. For an {approx}3-mm-thick membrane, the oxygen permeability was {approx}2.5 scc{center_dot}cm{sup {minus}2}{center_dot}min{sup {minus}1} at 900 C. Oxygen permeation increases as membrane thickness decreases. Tubular SFC membranes have been fabricated and operated at 900 C for {approx}1000 h in converting methane into syngas. The oxygen permeated through the membrane reacted with methane in the presence of a catalyst and produced syngas. We also studied the transport properties of yttria-doped BaCeO{sub 3{minus}{delta}} (BCY) by impedance spectroscopy and open-cell voltage (OCV) measurement. Total conductivity of the BCY sample increased from {approx}5 x 10{sup {minus}3} {Omega}{sup {minus}1}{center_dot}cm{sup {minus}1} to {approx}2 x 10{sup {minus}2} {Omega}{sup {minus}1}{center_dot}cm{sup {minus}1}, whereas the protonic transference number decreased from 0.87 to 0.63 and the oxygen transference number increased from 0.03 to 0.15 as temperature increased from 600 to 800 C. Unlike SFC, in which the ionic and electronic conductivities are nearly equivalent BCY exhibits protonic conductivity that

  5. Method of forming macro-structured high surface area transparent conductive oxide electrodes

    DOE Patents [OSTI]

    Forman, Arnold J.; Chen, Zhebo; Jaramillo, Thomas F.

    2016-01-05

    A method of forming a high surface area transparent conducting electrode is provided that includes depositing a transparent conducting thin film on a conductive substrate, where the transparent conducting thin film includes transparent conductive particles and a solution-based transparent conducting adhesive layer which serves to coat and bind together the transparent conducting particles, and heat treating the transparent conducting adhesion layer on the conductive substrate, where an increased surface area transparent conducting electrode is formed.

  6. Mixed oxygen ion/electron-conducting ceramics for oxygen separation

    SciTech Connect (OSTI)

    Stevenson, J.W.; Armstrong, B.L.; Armstrong, T.R.; Bates, J.L.; Pederson, L.R.; Weber, W.J.

    1995-05-01

    Solid mixed-conducting electrolytes in the series La{sub l-x}A{sub x}Co{sub l-y}Fe{sub y}O{sub 3-{delta}} (A = Sr,Ca,Ba) are potentially useful as passive membranes to separate high purity oxygen from air and as cathodes in fuel cells. All of the compositions studied exhibited very high electrical conductivities. At lower temperatures, conductivities increased with increasing temperature, characterized by activation energies of 0.05 to 0.16 eV that are consistent with a small polaron (localized electronic carrier) conduction mechanism. At higher temperatures, electronic conductivities tended to decrease with increasing temperature, which is attributed to decreased electronic carrier populations associated with lattice oxygen loss. Oxygen ion conductivities were higher than that of yttria stabilized zirconia and increased with the cobalt content and also increased with the extent of divalent A-site substitution. Thermogravimetric studies were conducted to establish the extent of oxygen vacancy formation as a function of temperature, oxygen partial pressure, and composition. These vacancy populations strongly depend on the extent of A-site substitution. Passive oxygen permeation rates were established for each of the compositions as a function of temperature and oxygen partial pressure gradient. For 2.5 mm thick membranes in an oxygen vs nitrogen partial pressure gradient, oxygen fluxes at 900 C ranged from approximately 0.3 sccm/cm{sup 2} for compositions high in iron and with low amounts of strontium A-site substitution to approximately 0.8 sccm/cm{sup 2} for compositions high in cobalt and strontium. A-site substitution with calcium instead of strontium resulted in substantially lower fluxes.

  7. Developing a High Thermal Conductivity Fuel with Silicon Carbide Additives

    SciTech Connect (OSTI)

    baney, Ronald; Tulenko, James

    2012-11-20

    The objective of this research is to increase the thermal conductivity of uranium oxide (UO{sub 2}) without significantly impacting its neutronic properties. The concept is to incorporate another high thermal conductivity material, silicon carbide (SiC), in the form of whiskers or from nanoparticles of SiC and a SiC polymeric precursor into UO{sub 2}. This is expected to form a percolation pathway lattice for conductive heat transfer out of the fuel pellet. The thermal conductivity of SiC would control the overall fuel pellet thermal conductivity. The challenge is to show the effectiveness of a low temperature sintering process, because of a UO{sub 2}-SiC reaction at 1,377°C, a temperature far below the normal sintering temperature. Researchers will study three strategies to overcome the processing difficulties associated with pore clogging and the chemical reaction of SiC and UO{sub 2} at temperatures above 1,300°C:

  8. Error and uncertainty in Raman thermal conductivity measurements

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Thomas Edwin Beechem; Yates, Luke; Graham, Samuel

    2015-04-22

    We investigated error and uncertainty in Raman thermal conductivity measurements via finite element based numerical simulation of two geometries often employed -- Joule-heating of a wire and laser-heating of a suspended wafer. Using this methodology, the accuracy and precision of the Raman-derived thermal conductivity are shown to depend on (1) assumptions within the analytical model used in the deduction of thermal conductivity, (2) uncertainty in the quantification of heat flux and temperature, and (3) the evolution of thermomechanical stress during testing. Apart from the influence of stress, errors of 5% coupled with uncertainties of ±15% are achievable for most materialsmore » under conditions typical of Raman thermometry experiments. Error can increase to >20%, however, for materials having highly temperature dependent thermal conductivities or, in some materials, when thermomechanical stress develops concurrent with the heating. A dimensionless parameter -- termed the Raman stress factor -- is derived to identify when stress effects will induce large levels of error. Together, the results compare the utility of Raman based conductivity measurements relative to more established techniques while at the same time identifying situations where its use is most efficacious.« less

  9. Mixed-conducting oxides for gas separation applications.

    SciTech Connect (OSTI)

    Balachandran, U.

    1999-04-20

    Mixed-conducting oxides are attracting increased attention because of their potential uses in high-temperature electrochemical applications such as solid-oxide fuel cells, batteries, sensors, and gas-permeable membranes. We are developing mixed-conducting, dense ceramic membranes to selectively transport oxygen and hydrogen. Ceramic membranes made of Sr-Fe-Co oxide (SFC), which exhibits high combined electronic and oxygen ionic conductivities, can be used to selectively transport oxygen during the partial oxidation of methane to synthesis gas (syngas, a mixture of CO and H{sub 2}). Steady-state oxygen permeability of SrFeCo{sub 0.5}O{sub x} has been measured as a function of oxygen-partial-pressure gradient and temperature. At 900 C, oxygen permeability was {approx}2.5 scc{center_dot}cm{sup {minus}2}-min{sup {minus}1} for a 2.9-mm-thick membrane, and this value increases as membrane thickness decreases. We have fabricated tubular SrFeCo{sub 0.5}O{sub x} membranes and operated them at 900 C for >1000 h during conversion of methane into syngas. Yttria-doped BaCeO{sub 3} (BCY) is a good protonic conductor; however, its lack of electronic conductivity can potentially limit its hydrogen permeability. To enhance the electronic conductivity and thus improve hydrogen permeation, a membrane composite material was developed. Nongalvanic permeation of hydrogen through the composite membrane was characterized as a function of thickness.

  10. Error and uncertainty in Raman thermal conductivity measurements

    SciTech Connect (OSTI)

    Thomas Edwin Beechem; Yates, Luke; Graham, Samuel

    2015-04-22

    We investigated error and uncertainty in Raman thermal conductivity measurements via finite element based numerical simulation of two geometries often employed -- Joule-heating of a wire and laser-heating of a suspended wafer. Using this methodology, the accuracy and precision of the Raman-derived thermal conductivity are shown to depend on (1) assumptions within the analytical model used in the deduction of thermal conductivity, (2) uncertainty in the quantification of heat flux and temperature, and (3) the evolution of thermomechanical stress during testing. Apart from the influence of stress, errors of 5% coupled with uncertainties of ±15% are achievable for most materials under conditions typical of Raman thermometry experiments. Error can increase to >20%, however, for materials having highly temperature dependent thermal conductivities or, in some materials, when thermomechanical stress develops concurrent with the heating. A dimensionless parameter -- termed the Raman stress factor -- is derived to identify when stress effects will induce large levels of error. Together, the results compare the utility of Raman based conductivity measurements relative to more established techniques while at the same time identifying situations where its use is most efficacious.

  11. The State of Water in Proton Conducting Membranes

    SciTech Connect (OSTI)

    Allcock, Harry R., Benesi, Alan, Macdonald, Digby, D.

    2010-08-27

    The research carried out under grant No. DE-FG02-07ER46371, "The State of Water in Proton Conducting Membranes", during the period June 1, 2008 -May 31, 2010 was comprised of three related parts. These are: 1. An examination of the state of water in classical proton conduction membranes with the use of deuterium T1 NMR spectroscopy (Allcock and Benesi groups). 2. A dielectric relaxation examination of the behavior of water in classical ionomer membranes (Macdonald program). 3. Attempts to synthesize new proton-conduction polymers and membranes derived from the polyphosphazene system. (Allcock program) All three are closely related, crucial aspects of the design and development of new and improved polymer electrolyte fuel cell membranes on which the future of fuel cell technology for portable applications depends.

  12. Comparative thermal conductivity measurements at Sandia National Laboratories. [Pyroceram

    SciTech Connect (OSTI)

    Sweet, J.N.; Roth, E.P.; Moss, M.; Haseman, G.M.; Anaya, J.A.

    1986-06-01

    A detailed examination has been made on the use of the comparative method for measuring the thermal conductivity of solid materials. Existing data analysis methods are discussed and new techniques, based on generalized linear least squares methods, are presented. An error analysis is made to determine the potential accuracy, reproducibility, and repeatability of the technique. For the case in which the reference conductivity is known to a relative accuracy of +-5%, the overall relative accuracy of the measurement is shown to be about +-6%. Experimental data are presented for the conductivities of commonly used reference materials; Pyrex 7740, Pyroceram 9606, Inconel 718, and Armco iron. Data are also given for two potential reference materials: fused silica and 304 stainless steel.

  13. Hot wire needle probe for thermal conductivity detection

    SciTech Connect (OSTI)

    Condie, Keith Glenn; Rempe, Joy Lynn; Knudson, Darrell lee; Daw, Joshua Earl; Wilkins, Steven Curtis; Fox, Brandon S.; Heng, Ban

    2015-11-10

    An apparatus comprising a needle probe comprising a sheath, a heating element, a temperature sensor, and electrical insulation that allows thermal conductivity to be measured in extreme environments, such as in high-temperature irradiation testing. The heating element is contained within the sheath and is electrically conductive. In an embodiment, the heating element is a wire capable of being joule heated when an electrical current is applied. The temperature sensor is contained within the sheath, electrically insulated from the heating element and the sheath. The electrical insulation electrically insulates the sheath, heating element and temperature sensor. The electrical insulation fills the sheath having electrical resistance capable of preventing electrical conduction between the sheath, heating element, and temperature sensor. The control system is connected to the heating element and the temperature sensor.

  14. Measurements of prompt radiation induced conductivity of alumina and sapphire.

    SciTech Connect (OSTI)

    Hartman, E. Frederick; Zarick, Thomas Andrew; Sheridan, Timothy J.; Preston, Eric F.

    2011-04-01

    We performed measurements of the prompt radiation induced conductivity in thin samples of Alumina and Sapphire at the Little Mountain Medusa LINAC facility in Ogden, UT. Five mil thick samples were irradiated with pulses of 20 MeV electrons, yielding dose rates of 1E7 to 1E9 rad/s. We applied variable potentials up to 1 kV across the samples and measured the prompt conduction current. Analysis rendered prompt conductivity coefficients between 1E10 and 1E9 mho/m/(rad/s), depending on the dose rate and the pulse width for Alumina and 1E7 to 6E7 mho/m/(rad/s) for Sapphire.

  15. Thermally conductive cementitious grout for geothermal heat pump systems

    DOE Patents [OSTI]

    Allan, Marita

    2001-01-01

    A thermally conductive cement-sand grout for use with a geothermal heat pump system. The cement sand grout contains cement, silica sand, a superplasticizer, water and optionally bentonite. The present invention also includes a method of filling boreholes used for geothermal heat pump systems with the thermally conductive cement-sand grout. The cement-sand grout has improved thermal conductivity over neat cement and bentonite grouts, which allows shallower bore holes to be used to provide an equivalent heat transfer capacity. In addition, the cement-sand grouts of the present invention also provide improved bond strengths and decreased permeabilities. The cement-sand grouts can also contain blast furnace slag, fly ash, a thermoplastic air entraining agent, latex, a shrinkage reducing admixture, calcium oxide and combinations thereof.

  16. Magnetic Transparent Conducting Oxide Film And Method Of Making

    DOE Patents [OSTI]

    Windisch, Jr., Charles F.; Exarhos, Gregory J.; Sharma, Shiv K.

    2006-03-14

    Cobalt-nickel oxide films of nominal 100 nm thickness, and resistivity as low as 0.06 O·cm have been deposited by spin-casting from both aqueous and organic precursor solutions followed by annealing at 450° C. in air. An increase in film resistivity was found upon substitution of other cations (e.g., Zn2+, Al3+) for Ni in the spinel structure. However, some improvement in the mechanical properties of the films resulted. On the other hand, addition of small amounts of Li decreased the resistivity. A combination of XRD, XPS, UV/Vis and Raman spectroscopy indicated that NiCo2O4 is the primary conducting component and that the conductivity reaches a maximum at this stoichiometry. When x<0.67, NiO forms leading to an increase in resistivity; when x>0.67, the oxide was all spinel but the increased Co content lowered the conductivity.

  17. Electrically conductive resinous bond and method of manufacture

    DOE Patents [OSTI]

    Snowden, T.M. Jr.; Wells, B.J.

    1985-01-01

    A method of bonding elements together with a bond of high strength and good electrical conductivity which comprises: applying an unfilled polyimide resin between surfaces of the elements to be bonded, heat treating said unfilled polyimide resin in stages between a temperature range of about 40 to 365/sup 0/C to form a strong adhesive bond between said elements, applying a metal-filled polyimide resin overcoat between said elements so as to provide electrical connection therebetween, and heat treating said metal-filled polyimide resin with substantially the same temperature profile as the unfilled polyimide resin. The present invention is also concerned with an adhesive, resilient, substantially void free bonding combination for providing a high strength, electrically conductive adhesive attachment between electrically conductive elements which comprises a major amount of an unfilled polyimide resin and a minor amount of a metal-filled polyimide resin.

  18. The State of Water in Proton Conducting Membranes

    SciTech Connect (OSTI)

    Allcock, Harry R.; Benesi, Alan; Macdonald, Digby D.

    2010-08-27

    The research carried out under grant No. DE-FG02-07ER46371, "The State of Water in Proton Conducting Membranes", during the period June 1, 2008 - May 31, 2010 was comprised of three related parts. These are: 1. An examination of the state of water in classical proton conduction membranes with the use of deuterium T1 NMR spectroscopy (Allcock and Benesi groups). 2. A dielectric relaxation examination of the behavior of water in classical ionomer membranes (Macdonald program). 3. Attempts to synthesize new proton-conduction polymers and membranes derived from the polyphosphazene system. (Allcock program) All three are closely related, crucial aspects of the design and development of new and improved polymer electrolyte fuel cell membranes on which the future of fuel cell technology for portable applications depends.

  19. Conduction in alumina with atomic scale copper filaments

    SciTech Connect (OSTI)

    Xu, Xu; Liu, Jie; Anantram, M. P.

    2014-10-28

    The conductance of atomic scale filaments with three and seven Cu atoms in ?-alumina are calculated using ab initio density functional theory. We find that the filament with 3 Cu atoms is sufficient to increase the conductance of 1.3?nm thick alumina film by more than 10{sup 3} times in linear response. As the applied voltage increases, the current quickly saturates and differential resistance becomes negative. Compared to the filament with three Cu atoms, while the conductance of the filament with seven Cu atoms is comparable in linear response, they carry as much as twenty times larger current at large biases. The electron transport is analyzed based on local density of states, and the negative differential resistance in the seven Cu filaments occurs due to their narrow bandwidth.

  20. Electrically conductive resinous bond and method of manufacture

    DOE Patents [OSTI]

    Snowden, Jr., Thomas M.; Wells, Barbara J.

    1987-01-01

    A method of bonding elements together with a bond of high strength and good electrical conductivity which comprises: applying an unfilled polyimide resin between surfaces of the elements to be bonded, heat treating said unfilled polyimide resin in stages between a temperature range of about 40.degree. to 365.degree. C. to form a strong adhesive bond between said elements, applying a metal-filled polyimide resin overcoat between said elements so as to provide electrical connection therebetween, and heat treating said metal-filled polyimide resin with substantially the same temperature profile as the unfilled polyimide resin. The present invention is also concerned with an adhesive, resilient, substantially void free bonding combination for providing a high strength, electrically conductive adhesive attachment between electrically conductive elements which comprises a major amount of an unfilled polyimide resin and a minor amount of a metal-filled polyimide resin.

  1. Magnetic Transparent Conducting Oxide Film And Method Of Making

    DOE Patents [OSTI]

    Windisch, Jr., Charles F. (Richland, WA); Exarhos, Gregory J. (Richland, WA); Sharma, Shiv K. (Honolulu, HI)

    2006-03-14

    Cobalt-nickel oxide films of nominal 100 nm thickness, and resistivity as low as 0.06 Ocm have been deposited by spin-casting from both aqueous and organic precursor solutions followed by annealing at 450 C. in air. An increase in film resistivity was found upon substitution of other cations (e.g., Zn2+, Al3+) for Ni in the spinel structure. However, some improvement in the mechanical properties of the films resulted. On the other hand, addition of small amounts of Li decreased the resistivity. A combination of XRD, XPS, UV/Vis and Raman spectroscopy indicated that NiCo2O4 is the primary conducting component and that the conductivity reaches a maximum at this stoichiometry. When x<0.67, NiO forms leading to an increase in resistivity; when x>0.67, the oxide was all spinel but the increased Co content lowered the conductivity.

  2. Structural Basis for Metallic-Like Conductivity in Microbial Nanowires

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Malvankar, Nikhil S.; Vargas, Madeline; Nevin, Kelly; Tremblay, Pier-Luc; Evans-Lutterodt, Kenneth; Nykypanchuk, Dmytro; Martz, Eric; Tuominen, Mark T.; Lovley, Derek R.

    2015-03-03

    Direct measurement of multiple physical properties of Geobacter sulfurreducens pili have demonstrated that they possess metallic-like conductivity, but several studies have suggested that metallic-like conductivity is unlikely based on the structures of the G. sulfurreducens pilus predicted from homology models. In order to further evaluate this discrepancy, pili were examined with synchrotron X-ray microdiffraction and rocking-curve X-ray diffraction. Both techniques revealed a periodic 3.2-Å spacing in conductive, wild-type G. sulfurreducens pili that was missing in the nonconductive pili of strain Aro5, which lack key aromatic acids required for conductivity. The intensity of the 3.2-Å peak increased 100-fold when the pHmore » was shifted from 10.5 to 2, corresponding with a previously reported 100-fold increase in pilus conductivity with this pH change. These results suggest a clear structure-function correlation for metallic-like conductivity that can be attributed to overlapping π-orbitals of aromatic amino acids. A homology model of the G. sulfurreducens pilus was constructed with a Pseudomonas aeruginosa pilus model as a template as an alternative to previous models, which were based on a Neisseria gonorrhoeae pilus structure. This alternative model predicted that aromatic amino acids in G. sulfurreducens pili are packed within 3 to 4 Å, consistent with the experimental results. Thus, the predictions of homology modeling are highly sensitive to assumptions inherent in the model construction. Finally, the experimental results reported here further support the concept that the pili of G. sulfurreducens represent a novel class of electronically functional proteins in which aromatic amino acids promote long-distance electron transport.« less

  3. Electronically conductive polymer binder for lithium-ion battery electrode

    DOE Patents [OSTI]

    Liu, Gao; Xun, Shidi; Battaglia, Vincent S; Zheng, Honghe

    2014-10-07

    A family of carboxylic acid group containing fluorene/fluorenon copolymers is disclosed as binders of silicon particles in the fabrication of negative electrodes for use with lithium ion batteries. These binders enable the use of silicon as an electrode material as they significantly improve the cycle-ability of silicon by preventing electrode degradation over time. In particular, these polymers, which become conductive on first charge, bind to the silicon particles of the electrode, are flexible so as to better accommodate the expansion and contraction of the electrode during charge/discharge, and being conductive promote the flow battery current.

  4. High thermal conductivity lossy dielectric using a multi layer configuration

    DOE Patents [OSTI]

    Tiegs, Terry N.; Kiggans, Jr., James O.

    2003-01-01

    Systems and methods are described for loss dielectrics. A loss dielectric includes at least one high dielectric loss layer and at least one high thermal conductivity-electrically insulating layer adjacent the at least one high dielectric loss layer. A method of manufacturing a loss dielectric includes providing at least one high dielectric loss layer and providing at least one high thermal conductivity-electrically insulating layer adjacent the at least one high dielectric loss layer. The systems and methods provide advantages because the loss dielectrics are less costly and more environmentally friendly than the available alternatives.

  5. Assessing the RELAPS-3D Heat Conduction Enclosure Model

    SciTech Connect (OSTI)

    McCann, Larry D.

    2008-09-30

    Three heat conduction problems that have exact solutions are modeled with RELAP5-3D using the conduction enclosure model. These comparisons are designed to be used in the RELAP5-3D development assessment scheduled to be completed in 2009. It is shown that with proper input choices and adequate model detail the exact solutions can be matched. In addition, this analysis identified an error and the required correction in the cylindrical and spherical heat conductor models in RELAP5-3D which will be corrected in a future version of RELAP5-3D.

  6. Conductivity fuel cell collector plate and method of fabrication

    DOE Patents [OSTI]

    Braun, James C.

    2002-01-01

    An improved method of manufacturing a PEM fuel cell collector plate is disclosed. During molding a highly conductive polymer composite is formed having a relatively high polymer concentration along its external surfaces. After molding the polymer rich layer is removed from the land areas by machining, grinding or similar process. This layer removal results in increased overall conductivity of the molded collector plate. The polymer rich surface remains in the collector plate channels, providing increased mechanical strength and other benefits to the channels. The improved method also permits greater mold cavity thickness providing a number of advantages during the molding process.

  7. Electrically conductive doped block copolymer of polyacetylene and polyisoprene

    DOE Patents [OSTI]

    Aldissi, Mahmoud

    1985-01-01

    An electrically conductive block copolymer of polyisoprene and polyacetyl and a method of making the same are disclosed. The polymer is prepared by first polymerizing isoprene with n-butyllithium in a toluene solution to form an active isoprenyllithium polymer. The active polymer is reacted with an equimolar amount of titanium butoxide and subsequently exposed to gaseous acetylene. A block copolymer of polyisoprene and polyacetylene is formed. The copolymer is soluble in common solvents and may be doped with I.sub.2 to give it an electrical conductivity in the metallic regime.

  8. Em Response of a Conductive, Permeable Spherical Shell

    Energy Science and Technology Software Center (OSTI)

    2005-10-24

    This code calculates the spectral response of conductive, permeable, shell in a conductive whole space using a closed form solution. The source is either a uniform field (approximately valid when the size of the sphere is small compared to the distance to the source) or the field of dipole (and by superposition, the field of a finite loop). The code is particularly useful in showing that the typical UXO (usually shells), the response is significantlymore » different at intermediate to late times compared to solids of the same materials.« less

  9. Assembly for electrical conductivity measurements in the piston cylinder device

    DOE Patents [OSTI]

    Watson, Heather Christine; Roberts, Jeffrey James

    2012-06-05

    An assembly apparatus for measurement of electrical conductivity or other properties of a sample in a piston cylinder device wherein pressure and heat are applied to the sample by the piston cylinder device. The assembly apparatus includes a body, a first electrode in the body, the first electrode operatively connected to the sample, a first electrical conductor connected to the first electrode, a washer constructed of a hard conducting material, the washer surrounding the first electrical conductor in the body, a second electrode in the body, the second electrode operatively connected to the sample, and a second electrical conductor connected to the second electrode.

  10. Measurements of prompt radiation induced conductivity in Teflon (PTFE).

    SciTech Connect (OSTI)

    Hartman, E. Frederick; Zarick, Thomas Andrew; Sheridan, Timothy J.; Preston, E.

    2013-05-01

    We performed measurements of the prompt radiation induced conductivity (RIC) in thin samples of Teflon (PTFE) at the Little Mountain Medusa LINAC facility in Ogden, UT. Three mil (76.2 microns) samples were irradiated with a 0.5 %CE%BCs pulse of 20 MeV electrons, yielding dose rates of 1E9 to 1E11 rad/s. We applied variable potentials up to 2 kV across the samples and measured the prompt conduction current. Details of the experimental apparatus and analysis are reported in this report on prompt RIC in Teflon.

  11. Topological Hall conductivity of vortex and skyrmion spin textures

    SciTech Connect (OSTI)

    Jalil, M. B. A. Ghee Tan, Seng; Eason, Kwaku; Kong, Jian Feng

    2014-05-07

    We analyze the topological Hall conductivity experienced by conduction electrons whose spins are strongly coupled to axially symmetric spin textures, such as magnetic vortex and skyrmion of types I and II, theoretically by gauge theory, and numerically via micromagnetic simulations. The numerical results are in agreement with the theoretical predictions. Divergence between the two is seen when the vortex/skyrmion core radius is comparable or larger than the element size, and when the skyrmion configuration breaks down at high Dzyaloshinskii-Moriya interaction strength.

  12. Conductive and robust nitride buffer layers on biaxially textured substrates

    DOE Patents [OSTI]

    Sankar, Sambasivan; Goyal, Amit; Barnett, Scott A.; Kim, Ilwon; Kroeger, Donald M.

    2004-08-31

    The present invention relates to epitaxial, electrically conducting and mechanically robust, cubic nitride buffer layers deposited epitaxially on biaxially textured substrates such as metal and alloys. The invention comprises of a biaxially textured substrate with epitaxial layers of nitrides. The invention also discloses a method to form such epitaxial layers using a high rate deposition method as well as without the use of forming gases. The invention further comprises epitaxial layers of oxides on the biaxially textured nitride layers. In some embodiments the article further comprises electromagnetic devices which may be super conducting properties.

  13. Electrically conducting porphyrin and porphyrin-fullerene electropolymers

    DOE Patents [OSTI]

    Gust, Jr., John Devens; Liddell, Paul Anthony; Gervaldo, Miguel Andres; Bridgewater, James Ward; Brennan, Bradley James; Moore, Thomas Andrew; Moore, Ana Lorenzelli

    2014-03-11

    Compounds with aryl ring(s) at porphyrin meso position(s) bearing an amino group in position 4 relative to the porphyrin macrocycle, and at least one unsubstituted 5 (hydrogen-bearing) meso position with the 10-, 15-, and/or 20-relationship to the aryl ring bearing the amino group, and metal complexes thereof, feature broad spectral absorption throughout the visible region. These compounds are electropolymerized to form electrically conducting porphyrin and porphyrin-fullerene polymers that are useful in photovoltaic applications. The structure of one such electrically conducting porphyrin polymer is shown below. ##STR00001##

  14. Electronically conductive ceramics for high temperature oxidizing environments

    DOE Patents [OSTI]

    Kucera, Gene H. (Downers Grove, IL); Smith, James L. (Lemont, IL); Sim, James W. (Evergreen Park, IL)

    1986-01-01

    A high temperature, ceramic composition having electronic conductivity as measured by resistivity below about 500 ohm-cm, chemical stability particularly with respect to cathode conditions in a molten carbonate fuel cell, and composed of an alkali metal, transition metal oxide containing a dopant metal in the crystalline structure to replace a portion of the alkali metal or transition metal.

  15. Method and apparatus for conducting variable thickness vapor deposition

    DOE Patents [OSTI]

    Nesslage, G.V.

    1984-08-03

    A method of vapor depositing metal on a substrate in variable thickness comprises conducting the deposition continuously without interruption to avoid formation of grain boundaries. To achieve reduced deposition in specific regions a thin wire or ribbon blocking body is placed between source and substrate to partially block vapors from depositing in the region immediately below.

  16. Stretchable transistors with buckled carbon nanotube films as conducting channels

    DOE Patents [OSTI]

    Arnold, Michael S; Xu, Feng

    2015-03-24

    Thin-film transistors comprising buckled films comprising carbon nanotubes as the conductive channel are provided. Also provided are methods of fabricating the transistors. The transistors, which are highly stretchable and bendable, exhibit stable performance even when operated under high tensile strains.

  17. Regulatory Guide on Conducting a Security Vulnerability Assessment

    SciTech Connect (OSTI)

    Ek, David R.

    2016-01-01

    This document will provide guidelines on conducting a security vulnerability assessment at a facility regulated by the Radiation Protection Centre. The guidelines provide a performance approach assess security effectiveness. The guidelines provide guidance for a review following the objectives outlined in IAEA NSS#11 for Category 1, 2, & 3 sources.

  18. Fourier analysis of conductive heat transfer for glazed roofing materials

    SciTech Connect (OSTI)

    Roslan, Nurhana Lyana; Bahaman, Nurfaradila; Almanan, Raja Noorliyana Raja; Ismail, Razidah; Zakaria, Nor Zaini

    2014-07-10

    For low-rise buildings, roof is the most exposed surface to solar radiation. The main mode of heat transfer from outdoor via the roof is conduction. The rate of heat transfer and the thermal impact is dependent on the thermophysical properties of roofing materials. Thus, it is important to analyze the heat distribution for the various types of roofing materials. The objectives of this paper are to obtain the Fourier series for the conductive heat transfer for two types of glazed roofing materials, namely polycarbonate and polyfilled, and also to determine the relationship between the ambient temperature and the conductive heat transfer for these materials. Ambient and surface temperature data were collected from an empirical field investigation in the campus of Universiti Teknologi MARA Shah Alam. The roofing materials were installed on free-standing structures in natural ventilation. Since the temperature data are generally periodic, Fourier series and numerical harmonic analysis are applied. Based on the 24-point harmonic analysis, the eleventh order harmonics is found to generate an adequate Fourier series expansion for both glazed roofing materials. In addition, there exists a linear relationship between the ambient temperature and the conductive heat transfer for both glazed roofing materials. Based on the gradient of the graphs, lower heat transfer is indicated through polyfilled. Thus polyfilled would have a lower thermal impact compared to polycarbonate.

  19. Thermal conductivity of III-V semiconductor superlattices

    SciTech Connect (OSTI)

    Mei, S. Knezevic, I.

    2015-11-07

    This paper presents a semiclassical model for the anisotropic thermal transport in III-V semiconductor superlattices (SLs). An effective interface rms roughness is the only adjustable parameter. Thermal transport inside a layer is described by the Boltzmann transport equation in the relaxation time approximation and is affected by the relevant scattering mechanisms (three-phonon, mass-difference, and dopant and electron scattering of phonons), as well as by diffuse scattering from the interfaces captured via an effective interface scattering rate. The in-plane thermal conductivity is obtained from the layer conductivities connected in parallel. The cross-plane thermal conductivity is calculated from the layer thermal conductivities in series with one another and with thermal boundary resistances (TBRs) associated with each interface; the TBRs dominate cross-plane transport. The TBR of each interface is calculated from the transmission coefficient obtained by interpolating between the acoustic mismatch model (AMM) and the diffuse mismatch model (DMM), where the weight of the AMM transmission coefficient is the same wavelength-dependent specularity parameter related to the effective interface rms roughness that is commonly used to describe diffuse interface scattering. The model is applied to multiple III-arsenide superlattices, and the results are in very good agreement with experimental findings. The method is both simple and accurate, easy to implement, and applicable to complicated SL systems, such as the active regions of quantum cascade lasers. It is also valid for other SL material systems with high-quality interfaces and predominantly incoherent phonon transport.

  20. Conduction Mechanisms and Structure of Ionomeric Single-Ion Conductors

    SciTech Connect (OSTI)

    Colby, Ralph H.; Maranas, Janna K; Mueller, Karl T; Runt, James; Winey, Karen I

    2015-03-05

    Our team has designed using DFT (Gaussian) and synthesized low glass transition temperature single-ion conductors that are either polyanions that conduct small cations Li, Na, Cs or polycations that conduct small anions F, OH, Br. We utilize a wide range of complimentary experimental materials charactization tools to understand ion transport; differential scanning calorimetry, dielectric relaxation spectroscopy, infrared spectroscopy, nuclear magnetic resonance spectroscopy, linear viscoelasticity, X-ray scattering and molecular dynamics simulations. The glass transition temperature Tg needs to be as low as possible to facilitate ion transport, so the nonionic parts of the polymer need to be polar, flexible and have strong solvation interactions with the ions. The lowest Tg we have managed for polyanions conducting Li is -60 C. In contrast, polysiloxanes with PEO side chains and tetrabutylphosphonium cationic side groups have Tg ~ -75C that barely increases with ion content, as anticipated by DFT. A survey of all polyanions in the literature suggests that Tg < -80C is needed to achieve the 10-4 S/cm conductivity needed for battery separators.

  1. Development of mixed-conducting oxides for gas separation

    SciTech Connect (OSTI)

    Balachandran, U.; Ma, B.; Maiya, P.S.

    1997-08-01

    Mixed-conducting oxides have been used in many applications, including fuel cells, gas separation membranes, sensors, and electrocatalysis. The authors are developing a mixed-conducting, dense ceramic membrane for selectively transporting oxygen and hydrogen. Ceramic membranes made of Sr-Fe-Co oxide, which has high combined electronic and oxygen ionic conductions, can be used to selectively transport oxygen during the partial oxidation of methane to synthesis gas (syngas, CO + H{sub 2}). The authors have measured the steady-state oxygen permeability of SrFeCo{sub 0.5}O{sub x} as a function of oxygen-partial-pressure gradient and temperature. At 900{degrees}C, oxygen permeability was {approx}2.5 scc{center_dot}cm{sup {minus}2}{center_dot}min{sup {minus}1} for a 2.9-mm-thick membrane and this value increases as membrane thickness decreases. The authors have fabricated tubular SrFeCo{sub 0.5}O{sub x} membranes and operated them at 900{degrees}C for >1000 h during conversion of methane into syngas. The hydrogen ion (proton) transport properties of yttria-doped BaCeO{sub 3} were investigated by impedance spectroscopy and open-cell voltage measurements. High proton conductivity and a high protonic transference number make yttria-doped BaCeO{sub 3} a potential membrane for hydrogen separation.

  2. Thin film method of conducting lithium-ions

    DOE Patents [OSTI]

    Zhang, J.G.; Benson, D.K.; Tracy, C.E.

    1998-11-10

    The present invention relates to the composition of a solid lithium-ion electrolyte based on the Li{sub 2}O-CeO{sub 2}-SiO{sub 2} system having good transparent characteristics and high ion conductivity suitable for uses in lithium batteries, electrochromic devices and other electrochemical applications. 12 figs.

  3. CRAD, Conduct of Operations- Idaho MF-628 Drum Treatment Facility

    Broader source: Energy.gov [DOE]

    A section of Appendix C to DOE G 226.1-2 "Federal Line Management Oversight of Department of Energy Nuclear Facilities." Consists of Criteria Review and Approach Documents (CRADs) used for a May, 2007 readiness assessment of the Conduct of Operations program at the Advanced Mixed Waste Treatment Project.

  4. Thermal conductivity in nanocrystalline-SiC/C superlattices

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Habermehl, S.; Serrano, J. R.

    2015-11-17

    We reported the formation of thin film superlattices consisting of alternating layers of nitrogen-doped SiC (SiC:N) and C. Periodically terminating the SiC:N surface with a graphitic C boundary layer and controlling the SiC:N/C thickness ratio yield nanocrystalline SiC grains ranging in size from 365 to 23 nm. Frequency domain thermo-reflectance is employed to determine the thermal conductivity, which is found to vary from 35.5 W m-1 K-1 for monolithic undoped α-SiC films to 1.6 W m-1 K-1 for a SiC:N/C superlattice with a 47 nm period and a SiC:N/C thickness ratio of 11. A series conductance model is employed tomore » explain the dependence of the thermal conductivity on the superlatticestructure. Our results indicate that the thermal conductivity is more dependent on the SiC:N/C thickness ratio than the SiC:N grain size, indicative of strong boundary layerphonon scattering.« less

  5. Thermal conductivity in nanocrystalline-SiC/C superlattices

    SciTech Connect (OSTI)

    Habermehl, S.; Serrano, J. R.

    2015-11-17

    We reported the formation of thin film superlattices consisting of alternating layers of nitrogen-doped SiC (SiC:N) and C. Periodically terminating the SiC:N surface with a graphitic C boundary layer and controlling the SiC:N/C thickness ratio yield nanocrystalline SiC grains ranging in size from 365 to 23 nm. Frequency domain thermo-reflectance is employed to determine the thermal conductivity, which is found to vary from 35.5 W m-1 K-1 for monolithic undoped α-SiC films to 1.6 W m-1 K-1 for a SiC:N/C superlattice with a 47 nm period and a SiC:N/C thickness ratio of 11. A series conductance model is employed to explain the dependence of the thermal conductivity on the superlatticestructure. Our results indicate that the thermal conductivity is more dependent on the SiC:N/C thickness ratio than the SiC:N grain size, indicative of strong boundary layerphonon scattering.

  6. Thin film method of conducting lithium-ions

    DOE Patents [OSTI]

    Zhang, Ji-Guang; Benson, David K.; Tracy, C. Edwin

    1998-11-10

    The present invention relates to the composition of a solid lithium-ion electrolyte based on the Li.sub.2 O--CeO.sub.2 --SiO.sub.2 system having good transparent characteristics and high ion conductivity suitable for uses in lithium batteries, electrochromic devices and other electrochemical applications.

  7. Draft Voluntary Code of Conduct Available for Public Comment

    Broader source: Energy.gov [DOE]

    The Department of Energy (DOE) has issued a Notice of Public Comment in the Federal Register, inviting the public to comment on DOE’s draft Voluntary Code of Conduct which addresses data privacy surrounding smart grid technologies. Comments must be received on or before October 14, 2014.

  8. (Tenth international conference on conduction and breakdown in dielectric liquids)

    SciTech Connect (OSTI)

    Christophorou, L.G.

    1990-10-05

    The traveler attended the 10th International Conference on Conduction and Breakdown in dielectric Liquids held in Grenoble, France, September 10--14, 1990. He chaired the opening session of the conference, presented one paper, co-authored a second paper presented at the meeting, participated in the discussions during the formal sessions, and had informal discussions with many of the participants.

  9. Electrically conductive polycrystalline diamond and particulate metal based electrodes

    DOE Patents [OSTI]

    Swain, Greg M.; Wang, Jian

    2005-04-26

    An electrically conducting and dimensionally stable diamond (12, 14) and metal particle (13) electrode produced by electrodepositing the metal on the diamond is described. The electrode is particularly useful in harsh chemical environments and at high current densities and potentials. The electrode is particularly useful for generating hydrogen, and for reducing oxygen and oxidizing methanol in reactions which are of importance in fuel cells.

  10. Mode dependent lattice thermal conductivity of single layer graphene

    SciTech Connect (OSTI)

    Wei, Zhiyong; Yang, Juekuan; Bi, Kedong; Chen, Yunfei

    2014-10-21

    Molecular dynamics simulation is performed to extract the phonon dispersion and phonon lifetime of single layer graphene. The mode dependent thermal conductivity is calculated from the phonon kinetic theory. The predicted thermal conductivity at room temperature exhibits important quantum effects due to the high Debye temperature of graphene. But the quantum effects are reduced significantly when the simulated temperature is as high as 1000 K. Our calculations show that out-of-plane modes contribute about 41.1% to the total thermal conductivity at room temperature. The relative contribution of out-of-plane modes has a little decrease with the increase of temperature. Contact with substrate can reduce both the total thermal conductivity of graphene and the relative contribution of out-of-plane modes, in agreement with previous experiments and theories. Increasing the coupling strength between graphene and substrate can further reduce the relative contribution of out-of-plane modes. The present investigations also show that the relative contribution of different mode phonons is not sensitive to the grain size of graphene. The obtained phonon relaxation time provides useful insight for understanding the phonon mean free path and the size effects in graphene.

  11. Conductive inks for metalization in integrated polymer microsystems

    DOE Patents [OSTI]

    Davidson, James Courtney; Krulevitch, Peter A.; Maghribi, Mariam N.; Benett, William J.; Hamilton, Julie K.; Tovar, Armando R.

    2006-02-28

    A system of metalization in an integrated polymer microsystem. A flexible polymer substrate is provided and conductive ink is applied to the substrate. In one embodiment the flexible polymer substrate is silicone. In another embodiment the flexible polymer substrate comprises poly(dimethylsiloxane).

  12. CRAD, Conduct of Operations- Idaho Accelerated Retrieval Project Phase II

    Broader source: Energy.gov [DOE]

    A section of Appendix C to DOE G 226.1-2 "Federal Line Management Oversight of Department of Energy Nuclear Facilities." Consists of Criteria Review and Approach Documents (CRADs) used for a February, 2006 Commencement of Operations assessment of the Conduct of Operations program at the Idaho Accelerated Retrieval Project Phase II.

  13. Effect of interfacial interactions on the thermal conductivity and interfacial thermal conductance in tungstengraphene layered structure

    SciTech Connect (OSTI)

    Jagannadham, K.

    2014-09-01

    Graphene film was deposited by microwave plasma assisted deposition on polished oxygen free high conductivity copper foils. Tungstengraphene layered film was formed by deposition of tungsten film by magnetron sputtering on the graphene covered copper foils. Tungsten film was also deposited directly on copper foil without graphene as the intermediate film. The tungstengraphenecopper samples were heated at different temperatures up to 900?C in argon atmosphere to form an interfacial tungsten carbide film. Tungsten film deposited on thicker graphene platelets dispersed on silicon wafer was also heated at 900?C to identify the formation of tungsten carbide film by reaction of tungsten with graphene platelets. The films were characterized by scanning electron microscopy, Raman spectroscopy, and x-ray diffraction. It was found that tungsten carbide film formed at the interface upon heating only above 650?C. Transient thermoreflectance signal from the tungsten film surface on the samples was collected and modeled using one-dimensional heat equation. The experimental and modeled results showed that the presence of graphene at the interface reduced the cross-plane effective thermal conductivity and the interfacial thermal conductance of the layer structure. Heating at 650 and 900?C in argon further reduced the cross-plane thermal conductivity and interface thermal conductance as a result of formation nanocrystalline tungsten carbide at the interface leading to separation and formation of voids. The present results emphasize that interfacial interactions between graphene and carbide forming bcc and hcp elements will reduce the cross-plane effective thermal conductivity in composites.

  14. Hot wire thermal conductivity measurements in high temperature refractories

    SciTech Connect (OSTI)

    Dils, R.R.; Allen, J.D.; Richmond, J.C.; McNeil, M.B.

    1982-01-01

    In the hot wire thermal conductivity test, a wire embedded in the material to be tested is heated with constant power input, and the temperature is measured at short time intervals. The thermal conductivity is computed from the known power input to the wire and the measured rate of increase in the wire temperature after about 700 s of heating. A finite-difference computer simulation of the hot wire test was developed to evaluate the effects of several variables in the properties of the materials tested and in the test procedures on the measured thermal conductivity. Equations relating the radiant heat transfer in a material to its optical properties were developed and a radiant heat transfer component was developed for the finite-difference simulation. Equations were derived to compute the spectral optical properties of a test material from the measured spectral normal-hemispherical transmittance of a sample of the material of known thickness that is thin enough to have a measurable transmittance over the wavelength range of about 500 to 20,000 nm, and the spectral near-normal hemispherical reflectance of a sample of the material thick enough to be completely opaque, over the same wavelength range. The optical extinction coefficient, and the ratio of the scattering coefficient, to the absorption coefficient, of MinK 2000 and K3000 brick were evaluated from their measured spectral transmittances and reflectances, and used to compute the radiant heat transfer component in these materials. The hot wire test measures an average thermal conductivity for all directions away from the wire in a plane normal to the wire. Extensive tests were made of MinK 2000 and K3000, and the measured values are compared to the guarded hot plate thermal conductivity, which is unidirectional normal to the face of a brick. 67 references, 31 figures, 23 tables.

  15. Pretest Caluculations of Temperature Changes for Field Thermal Conductivity Tests

    SciTech Connect (OSTI)

    N.S. Brodsky

    2002-07-17

    A large volume fraction of the potential monitored geologic repository at Yucca Mountain may reside in the Tptpll (Tertiary, Paintbrush Group, Topopah Spring Tuff, crystal poor, lower lithophysal) lithostratigraphic unit. This unit is characterized by voids, or lithophysae, which range in size from centimeters to meters. A series of thermal conductivity field tests are planned in the Enhanced Characterization of the Repository Block (ECRB) Cross Drift. The objective of the pretest calculation described in this document is to predict changes in temperatures in the surrounding rock for these tests for a given heater power and a set of thermal transport properties. The calculation can be extended, as described in this document, to obtain thermal conductivity, thermal capacitance (density x heat capacity, J {center_dot} m{sup -3} {center_dot} K{sup -1}), and thermal diffusivity from the field data. The work has been conducted under the ''Technical Work Plan For: Testing and Monitoring'' (BSC 2001). One of the outcomes of this analysis is to determine the initial output of the heater. This heater output must be sufficiently high that it will provide results in a reasonably short period of time (within several weeks or a month) and be sufficiently high that the heat increase is detectable by the instruments employed in the test. The test will be conducted in stages and heater output will be step increased as the test progresses. If the initial temperature is set too high, the experiment will not have as many steps and thus fewer thermal conductivity data points will result.

  16. Mixed ionic and electronic conducting ceramic membranes for hydrocarbon processing

    DOE Patents [OSTI]

    Van Calcar, Pamela (Superior, CO); Mackay, Richard (Lafayette, CO); Sammells, Anthony F. (Boulder, CO)

    2002-01-01

    The invention relates to mixed phase materials for the preparation of catalytic membranes which exhibit ionic and electronic conduction and which exhibit improved mechanical strength compared to single phase ionic and electronic conducting materials. The mixed phase materials are useful for forming gas impermeable membranes either as dense ceramic membranes or as dense thin films coated onto porous substrates. The membranes and materials of this invention are useful in catalytic membrane reactors in a variety of applications including synthesis gas production. One or more crystalline second phases are present in the mixed phase material at a level sufficient to enhance the mechanical strength of the mixture to provide membranes for practical application in CMRs.

  17. Lattice thermal conductivity of filled skutterudites: An anharmonicity perspective

    SciTech Connect (OSTI)

    Geng, Huiyuan, E-mail: genghuiyuan@hit.edu.cn; Meng, Xianfu; Zhang, Hao; Zhang, Jian [State Key Laboratory of Advanced Welding and Joining, Harbin Institute of Technology, Harbin 150001 (China)

    2014-10-28

    We report a phenomenological model to calculate the high-temperature lattice thermal conductivity of filled skutterudite antimonides. The model needs no phonon resonant scattering terms. Instead, we assume that umklapp processes dominate the high-temperature phonon scattering. In order to represent the anharmonicity introduced by the filling atom, we introduce a Gaussian term into the relaxation time of the umklapp process. The developed model agrees remarkably well with the experimental results of RE{sub f}Co{sub 4}Sb{sub 12} and RE{sub f}Fe{sub 4}Sb{sub 12} (RE?=?Yb, Ba, and Ca) alloys. To further test the validity of our model, we calculate the lattice thermal conductivity of nanostructured or multi-filled skutterudites. The calculation results are also in good agreement with experiment, increasing our confidence in the developed anharmonicity model.

  18. Pressure effects on the optical conductivity of Kondo insulators

    SciTech Connect (OSTI)

    Zhang, Sun

    2001-06-01

    The effects of pressure on the optical conductivity of Kondo insulators are studied in the framework of the slave-boson mean-field theory under the coherent potential approximation. A unified picture is presented for both the hole-type Kondo insulators [H. Okamura , Phys. Rev. B >58, R7496 (1998)] and the electron-type Kondo insulators [B. Bucher , Phys. Rev. Lett. >72, 522 (1994)]. The density of states of f electrons under the applied pressure and its variation with the concentration of the impurity doping are calculated self-consistently. The Kondo temperature and the optical conductivity are obtained, in agreement with the experiments qualitatively. The two contrasting pressure-dependent effects for the hole-type Kondo insulators and the electron-type Kondo insulators are also given as predictions for further observations.

  19. Electronically conductive polymer binder for lithium-ion battery electrode

    SciTech Connect (OSTI)

    Liu, Gao; Xun, Shidi; Battaglia, Vincent S.; Zheng, Honghe; Wu, Mingyan

    2015-07-07

    A family of carboxylic acid groups containing fluorene/fluorenon copolymers is disclosed as binders of silicon particles in the fabrication of negative electrodes for use with lithium ion batteries. Triethyleneoxide side chains provide improved adhesion to materials such as, graphite, silicon, silicon alloy, tin, tin alloy. These binders enable the use of silicon as an electrode material as they significantly improve the cycle-ability of silicon by preventing electrode degradation over time. In particular, these polymers, which become conductive on first charge, bind to the silicon particles of the electrode, are flexible so as to better accommodate the expansion and contraction of the electrode during charge/discharge, and being conductive promote the flow battery current.

  20. Electronically conductive polymer binder for lithium-ion battery electrode

    SciTech Connect (OSTI)

    Liu, Gao; Battaglia, Vincent S.; Park, Sang -Jae

    2015-10-06

    A family of carboxylic acid groups containing fluorene/fluorenon copolymers is disclosed as binders of silicon particles in the fabrication of negative electrodes for use with lithium ion batteries. Triethyleneoxide side chains provide improved adhesion to materials such as, graphite, silicon, silicon alloy, tin, tin alloy. These binders enable the use of silicon as an electrode material as they significantly improve the cycle-ability of silicon by preventing electrode degradation over time. In particular, these polymers, which become conductive on first charge, bind to the silicon particles of the electrode, are flexible so as to better accommodate the expansion and contraction of the electrode during charge/discharge, and being conductive promote the flow battery current.

  1. Sulfur control in ion-conducting membrane systems

    DOE Patents [OSTI]

    Stein, VanEric Edward; Richards, Robin Edward; Brengel, David Douglas; Carolan, Michael Francis

    2003-08-05

    A method for controlling the sulfur dioxide partial pressure in a pressurized, heated, oxygen-containing gas mixture which is contacted with an ion-conducting metallic oxide membrane which permeates oxygen ions. The sulfur dioxide partial pressure in the oxygen-depleted non-permeate gas from the membrane module is maintained below a critical sulfur dioxide partial pressure, p.sub.SO2 *, to protect the membrane material from reacting with sulfur dioxide and reducing the oxygen flux of the membrane. Each ion-conducting metallic oxide material has a characteristic critical sulfur dioxide partial pressure which is useful in determining the required level of sulfur removal from the feed gas and/or from the fuel gas used in a direct-fired feed gas heater.

  2. Contactless measurement of alternating current conductance in quantum Hall structures

    SciTech Connect (OSTI)

    Drichko, I. L.; Diakonov, A. M.; Malysh, V. A.; Smirnov, I. Yu.; Ilyinskaya, N. D.; Usikova, A. A.; Galperin, Y. M.; Kummer, M.; Känel, H. von

    2014-10-21

    We report a procedure to determine the frequency-dependent conductance of quantum Hall structures in a broad frequency domain. The procedure is based on the combination of two known probeless methods—acoustic spectroscopy and microwave spectroscopy. By using the acoustic spectroscopy, we study the low-frequency attenuation and phase shift of a surface acoustic wave in a piezoelectric crystal in the vicinity of the electron (hole) layer. The electronic contribution is resolved using its dependence on a transverse magnetic field. At high frequencies, we study the attenuation of an electromagnetic wave in a coplanar waveguide. To quantitatively calibrate these data, we use the fact that in the quantum-Hall-effect regime the conductance at the maxima of its magnetic field dependence is determined by extended states. Therefore, it should be frequency independent in a broad frequency domain. The procedure is verified by studies of a well-characterized p-SiGe/Ge/SiGe heterostructure.

  3. Conductance matrix of multiterminal semiconductor devices with edge channels

    SciTech Connect (OSTI)

    Danilovskii, E. Yu. Bagraev, N. T.

    2014-12-15

    A method for determining the conductance matrix of multiterminal semiconductor structures with edge channels is proposed. The method is based on the solution of a system of linear algebraic equations based on Kirchhoff equations, made up of potential differences U{sub ij} measured at stabilized currents I{sub kl}, where i, j, k, l are terminal numbers. The matrix obtained by solving the system of equations completely describes the structure under study, reflecting its configuration and homogeneity. This method can find wide application when using the known Landauer-Buttiker formalism to analyze carrier transport in the quantum Hall effect and quantum spin Hall effect modes. Within the proposed method, the contribution of the contact area resistances R{sub c} to the formation of conductance matrix elements is taken into account. The possibilities of practical application of the results obtained in developing analog cryptographic devices are considered.

  4. Enhanced Semiconductor Nanocrystal Conductance via Solution Grown Contacts

    SciTech Connect (OSTI)

    Sheldon, Matthew T.; Trudeau, Paul-Emile; Mokari, Taleb; Wang, Lin-Wang; Alivisatos, A. Paul

    2009-08-19

    We report a 100,000-fold increase in the conductance of individual CdSe nanorods when they are electrically contacted via direct solution phase growth of Au tips on the nanorod ends. Ensemble UV-Vis and X-Ray photoelectron spectroscopy indicate this enhancement does not result from alloying of the nanorod. Rather, low temperature tunneling and high temperature (250-400 K) thermionic emission across the junction at the Au contact reveal a 75percent lower interface barrier to conduction compared to a control sample. We correlate this barrier lowering with the electronic structure at the Au-CdSe interface. Our results emphasize the importance of nanocrystal surface structure for robust device performance and the advantage of this contact method.

  5. Fluorine compounds for doping conductive oxide thin films

    DOE Patents [OSTI]

    Gessert, Tim; Li, Xiaonan; Barnes, Teresa M; Torres, Jr., Robert; Wyse, Carrie L

    2013-04-23

    Methods of forming a conductive fluorine-doped metal oxide layer on a substrate by chemical vapor deposition are described. The methods may include heating the substrate in a processing chamber, and introducing a metal-containing precursor and a fluorine-containing precursor to the processing chamber. The methods may also include adding an oxygen-containing precursor to the processing chamber. The precursors are reacted to deposit the fluorine-doped metal oxide layer on the substrate. Methods may also include forming the conductive fluorine-doped metal oxide layer by plasma-assisted chemical vapor deposition. These methods may include providing the substrate in a processing chamber, and introducing a metal-containing precursor, and a fluorine-containing precursor to the processing chamber. A plasma may be formed that includes species from the metal-containing precursor and the fluorine-containing precursor. The species may react to deposit the fluorine-doped metal oxide layer on the substrate.

  6. Method for conducting electroless metal-plating processes

    DOE Patents [OSTI]

    Petit, George S.; Wright, Ralph R.

    1978-01-01

    This invention is an improved method for conducting electroless metal-plating processes in a metal tank which is exposed to the plating bath. The invention solves a problem commonly encountered in such processes: how to determine when it is advisable to shutdown the process in order to clean and/or re-passivate the tank. The new method comprises contacting the bath with a current-conducting, non-catalytic probe and, during plating operations, monitoring the gradually changing difference in electropotential between the probe and tank. It has been found that the value of this voltage is indicative of the extent to which nickel-bearing decomposition products accumulate on the tank. By utilizing the voltage to determine when shutdown for cleaning is advisable, the operator can avoid premature shutdown and at the same time avoid prolonging operations to the point that spontaneous decomposition occurs.

  7. P-type conductivity in annealed strontium titanate

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Poole, Violet M.; Corolewski, Caleb D.; McCluskey, Matthew D.

    2015-12-17

    In this study, Hall-effect measurements indicate p-type conductivity in bulk, single-crystal strontium titanate (SrTiO3, or STO) samples that were annealed at 1200°C. Room temperature mobilities above 100 cm2/Vs were measured, an order of magnitude higher than those for electrons (5-10 cm2/Vs). Average hole densities were in the 109-1010 cm-3 range, consistent with a deep acceptor.

  8. NNSA to Conduct Aerial Radiological Surveys Over San Francisco, Pacifica,

    National Nuclear Security Administration (NNSA)

    Berkeley, And Oakland, CA Areas | National Nuclear Security Administration | (NNSA) Conduct Aerial Radiological Surveys Over San Francisco, Pacifica, Berkeley, And Oakland, CA Areas August 27, 2015 A U.S. Department of Energy National Nuclear Security Administration (NNSA) helicopter may be seen flying at low altitudes around the California Bay Area from September 1 - 6, 2015. The purpose of the flyovers is to measure naturally occurring background radiation. A twin-engine Bell 412

  9. NNSA to Conduct Background Radiation Testing | National Nuclear Security

    National Nuclear Security Administration (NNSA)

    Administration | (NNSA) to Conduct Background Radiation Testing July 20, 2015 The National Nuclear Security Administration (NNSA) and Federal Emergency Management Agency (FEMA) under the Nuclear Incident Response Team (NIRT) program will be sponsoring an Aerial Measuring System (AMS) WINGS exercise July 20 - 24, 2015 in conjunction with the national level exercise Southern Exposure to be held in Florence, SC. Local, state and federal agencies will participate in an interoperability exercise

  10. NNSA to conduct Aerial Radiation Assessment Survey over Boston Harbor |

    National Nuclear Security Administration (NNSA)

    National Nuclear Security Administration | (NNSA) conduct Aerial Radiation Assessment Survey over Boston Harbor June 02, 2015 BOSTON- A helicopter may be seen flying at low altitudes around Boston Harbor from June 5 - 7, 2015. The purpose of the flyovers is to measure naturally occurring background radiation. Officials from U.S. Department of Energy's National Nuclear Security Administration (NNSA) announced that the radiation assessment will cover approximately 13 square miles. A

  11. Graphitized Conductive Carbon Coatings for Composite Electrodes - Energy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Innovation Portal Energy Storage Energy Storage Advanced Materials Advanced Materials Find More Like This Return to Search Graphitized Conductive Carbon Coatings for Composite Electrodes Lawrence Berkeley National Laboratory Contact LBL About This Technology Technology Marketing SummaryRobert Kostecki and Marek Marcinek of Lawrence Berkeley National Laboratory have developed a method to improve the performance and operational life of composite electrodes by direct deposition of a continuous,

  12. Solid lithium ion conducting electrolytes and methods of preparation

    SciTech Connect (OSTI)

    Narula, Chaitanya K.; Daniel, Claus

    2015-11-19

    A composition comprised of nanoparticles of lithium ion conducting solid oxide material, wherein the solid oxide material is comprised of lithium ions, and at least one type of metal ion selected from pentavalent metal ions and trivalent lanthanide metal ions. Solution methods useful for synthesizing these solid oxide materials, as well as precursor solutions and components thereof, are also described. The solid oxide materials are incorporated as electrolytes into lithium ion batteries.

  13. Alan J. Heeger, Conductive Polymers, and Plastic Solar Cells

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Alan J. Heeger, Conductive Polymers, and Plastic Solar Cells Resources with Additional Information * Patents * Videos After receiving 'his physics Ph.D. at the University of California at Berkeley in 1961, [Alan J.] Heeger would spend the next 20 years teaching the subject at the University of Pennsylvania - while also designing and then launching one of the nation's premiere scientific think tanks: the Laboratory for Research on the Structure of Matter. Alan J. Heeger Courtesy of Randy Lamb,

  14. Alan MacDiarmid, Conductive Polymers, and Plastic Batteries

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Alan MacDiarmid, Conductive Polymers, and Plastic Batteries Resources with Additional Information * Patents Alan MacDiarmid ©Alan MacDiarmid/ University of Pennsylvania Photo by Felice Macera Until 1987, the billions of batteries that had been marketed in myriad sizes and shapes all had one thing in common. To make electricity, they depended exclusively upon chemical reactions involving metal components of the battery. But today a revolutionary new type of battery is available commercially. It

  15. An Investigation of the Ionic Conductivity and Species Crossover of

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Lithiated Nafion 117 in Nonaqueous Electrolytes - Joint Center for Energy Storage Research December 9, 2015, Research Highlights An Investigation of the Ionic Conductivity and Species Crossover of Lithiated Nafion 117 in Nonaqueous Electrolytes (a) SAXS of Li-N117 in different solvents. (b) Mass transfer resistance of the active species across the membrane. (c ) The performance of Li-N117 compared to the performance metric. (d) Minimum required selectivity as a function of the maximum energy

  16. ORISE: REAC/TS Cytogenetic Biodosimetry Laboratory conducts international

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    exercise to assess radiation dose estimation REAC/TS Cytogenetic Biodosimetry Laboratory conducts international exercise to assess radiation dose estimation Cytogenetics biodosimetry dicentric analysis ORISE and the Radiation Emergency Assistance Center/Training Site (REAC/TS) recently designed a collaborative chromosome analysis platform to accommodate an international exercise that involved the scoring of abnormal chromosomes used for radiation dose estimation. Cytogeneticists from six

  17. Physicist Fatima Ebrahimi conducts computer simulations that indicate the

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    efficiency of an innovative fusion start-up technique | Princeton Plasma Physics Lab Fatima Ebrahimi conducts computer simulations that indicate the efficiency of an innovative fusion start-up technique By Raphael Rosen May 31, 2016 Tweet Widget Google Plus One Share on Facebook Physicist Fatima Ebrahimi (Photo by Elle Starkman / PPPL Office of Communications) Physicist Fatima Ebrahimi Physicist Fatima Ebrahimi at the U.S. Department of Energy's (DOE) Princeton Plasma Physics Laboratory

  18. Methods of conducting simultaneous exothermic and endothermic reactions

    DOE Patents [OSTI]

    Tonkovich, Anna Lee; Roberts, Gary L.; Perry, Steven T.; Fitzgerald, Sean P.

    2005-11-29

    Integrated Combustion Reactors (ICRs) and methods of making ICRs are described in which combustion chambers (or channels) are in direct thermal contact to reaction chambers for an endothermic reaction. Superior results were achieved for combustion chambers which contained a gap for free flow through the chamber. Particular reactor designs are also described. Processes of conducting reactions in integrated combustion reactors are described and results presented. Some of these processes are characterized by unexpected and superior results.

  19. Magnetic transparent conducting oxide film and method of making

    DOE Patents [OSTI]

    Windisch, Jr., Charles F.; Exarhos, Gregory J.; Sharma, Shiv K.

    2004-07-13

    Cobalt-nickel oxide films of nominal 100 nm thickness, and resistivity as low as 0.06 .OMEGA..multidot.cm have been deposited by spin-casting from both aqueous and organic precursor solutions followed by annealing at 450.degree. C. in air. Films deposited on sapphire substrates exhibit a refractive index of about 1.7 and are relatively transparent in the wavelength region from 0.6 to 10.0 .mu.m. They are also magnetic. The electrical and spectroscopic properties of the oxides have been studied as a function of x=Co/(Co+Ni) ratio. An increase in film resistivity was found upon substitution of other cations (e.g., Zn.sup.2+, Al.sup.3+) for Ni in the spinel structure. However, some improvement in the mechanical properties of the films resulted. On the other hand, addition of small amounts of Li decreased the resistivity. A combination of XRD, XPS, UV/Vis and Raman spectroscopy indicated that NiCo.sub.2 O.sub.4 is the primary conducting component and that the conductivity reaches a maximum at this stoichiometry. When x<0.67, NiO forms leading to an increase in resistivity; when x>0.67, the oxide was all spinel but the increased Co content lowered the conductivity. The influence of cation charge state and site occupancy in the spinel structure markedly affects calculated electron band structures and contributes to a reduction of p-type conductivity, the formation of polarons, and the reduction in population of mobile charge carriers that tend to limit transmission in the infrared.

  20. Conducting business under the Foreign Corrupt Practices Act

    SciTech Connect (OSTI)

    Ittig, J.

    1982-07-01

    The Foreign Corrupt Practices Act inhibits many businesses conducting international transactions. Although the Senate has proposed revisions to the FCPA to alleviate some of the handicaps of U.S. citizens doing business abroad, the House of Representatives has yet to approve a bill. This study identifies the critical interpretive problems, and suggests protective measures a company can take to avoid problems until the FCPA is amended.

  1. Solid lithium ion conducting electrolytes and methods of preparation

    DOE Patents [OSTI]

    Narula, Chaitanya K; Daniel, Claus

    2013-05-28

    A composition comprised of nanoparticles of lithium ion conducting solid oxide material, wherein the solid oxide material is comprised of lithium ions, and at least one type of metal ion selected from pentavalent metal ions and trivalent lanthanide metal ions. Solution methods useful for synthesizing these solid oxide materials, as well as precursor solutions and components thereof, are also described. The solid oxide materials are incorporated as electrolytes into lithium ion batteries.

  2. Precise Application of Transparent Conductive Oxide Coatings for Flat Panel

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Displays and Photovoltaic Cells - Energy Innovation Portal Solar Photovoltaic Solar Photovoltaic Advanced Materials Advanced Materials Find More Like This Return to Search Precise Application of Transparent Conductive Oxide Coatings for Flat Panel Displays and Photovoltaic Cells Argonne National Laboratory Contact ANL About This Technology <p align="center"> New <em>ALD reaction chamber containing 12-in x 12-in piece of plate glass</em></p> New ALD reaction

  3. Physicist Fatima Ebrahimi conducts computer simulations that indicate the

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    efficiency of an innovative fusion start-up technique | Princeton Plasma Physics Lab Fatima Ebrahimi conducts computer simulations that indicate the efficiency of an innovative fusion start-up technique By Raphael Rosen May 31, 2016 Tweet Widget Google Plus One Share on Facebook Physicist Fatima Ebrahimi (Photo by Elle Starkman / PPPL Office of Communications) Physicist Fatima Ebrahimi Physicist Fatima Ebrahimi at the U.S. Department of Energy's (DOE) Princeton Plasma Physics Laboratory

  4. EFFECT OF COMPRESSION ON CONDUCTIVITY AND MORPHOLOGY OF PFSA MEMBRANES

    SciTech Connect (OSTI)

    Kusoglu, Ahmet; Weber, Adam; Jiang, Ruichin; Gittleman, Craig

    2011-07-20

    Polymer-Electrolyte-Fuel-Cells (PEFCs) are promising candidates for powering vehicles and portable devices using renewable-energy sources. The core of a PEFC is the solid electrolyte membrane that conducts protons from anode to cathode, where water is generated. The conductivity of the membrane, however, depends on the water content of the membrane, which is strongly related to the cell operating conditions. The membrane and other cell components are typically compressed to minimize various contact resistances. Moreover, the swelling of a somewhat constrained membrane in the cell due to the humidity changes generates additional compressive stresses in the membrane. These external stresses are balanced by the internal swelling pressure of the membrane and change the swelling equilibrium. It was shown using a fuel-cell setup that compression could reduce the water content of the membrane or alter the cell resistance. Nevertheless, the effect of compression on the membrane’s transport properties is yet to be understood, as well as its implications in the structure-functions relationships of the membrane. We previously studied, both experimentally and theoretically, how compression affects the water content of the membrane.6 However, more information is required the gain a fundamental understanding of the compression effects. In this talk, we present the results of our investigation on the in-situ conductivity of the membrane as a function of humidity and cell compression pressure. Moreover, to better understand the morphology of compressed membrane, small-angle X-ray-scattering (SAXS) experiments were performed. The conductivity data is then analyzed by investigating the size of the water domains of the compressed membrane determined from the SAXS measurements.

  5. Small Electric Voltage Alters Conductivity in Key Materials

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electric Voltage Alters Conductivity in Key Materials - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Energy Defense Waste

  6. Large piezoresistive effect in surface conductive nanocrystalline diamond

    SciTech Connect (OSTI)

    Janssens, S. D. Haenen, K.; Drijkoningen, S.

    2014-09-08

    Surface conductivity in hydrogen-terminated single crystal diamond is an intriguing phenomenon for fundamental reasons as well as for application driven research. Surface conductivity is also observed in hydrogen-terminated nanocrystalline diamond although the electronic transport mechanisms remain unclear. In this work, the piezoresistive properties of intrinsic surface conductive nanocrystalline diamond are investigated. A gauge factor of 35 is calculated from bulging a diamond membrane of 350 nm thick, with a diameter of 656 μm and a sheet resistance of 1.45 MΩ/sq. The large piezoresistive effect is reasoned to originate directly from strain-induced changes in the resistivity of the grain boundaries. Additionally, we ascribe a small time-dependent fraction of the piezoresistive effect to charge trapping of charge carriers at grain boundaries. In conclusion, time-dependent piezoresistive effect measurements act as a tool for deeper understanding the complex electronic transport mechanisms induced by grain boundaries in a polycrystalline material or nanocomposite.

  7. Numerical Model for Conduction-Cooled Current Lead Heat Loads

    SciTech Connect (OSTI)

    White, M.J.; Wang, X.L.; Brueck, H.D.; /DESY

    2011-06-10

    Current leads are utilized to deliver electrical power from a room temperature junction mounted on the vacuum vessel to a superconducting magnet located within the vacuum space of a cryostat. There are many types of current leads used at laboratories throughout the world; however, conduction-cooled current leads are often chosen for their simplicity and reliability. Conduction-cooled leads have the advantage of using common materials, have no superconducting/normal state transition, and have no boil-off vapor to collect. This paper presents a numerical model for conduction-cooled current lead heat loads. This model takes into account varying material and fluid thermal properties, varying thicknesses along the length of the lead, heat transfer in the circumferential and longitudinal directions, electrical power dissipation, and the effect of thermal intercepts. The model is validated by comparing the numerical model results to ideal cases where analytical equations are valid. In addition, the XFEL (X-Ray Free Electron Laser) prototype current leads are modeled and compared to the experimental results from testing at DESY's XFEL Magnet Test Stand (XMTS) and Cryomodule Test Bench (CMTB).

  8. Performance objectives and criteria for conducting DOE environmental audits

    SciTech Connect (OSTI)

    1994-01-01

    This document contains the Performance Objectives and Criteria (POC) that have been developed for environmental audits and assessments conducted by the Office of the Assistant Secretary for Environment, Safety and Health. The Environmental POC can serve multiple purposes. Primarily, they are to serve as guidelines for the technical specialists conducted the audits and assessments, and for the team management. The POC can also serve as supporting documents for training of technical discipline specialists and Team Leaders and as bases for DOE programs and field offices and contractors conducting audit or assessment activities or improving environmental protection programs. It must be recognized that not all of the POC will necessarily apply to all DOE facilities. The users of this document must rely upon their knowledge of the facility and their professional judgment, or the judgment of qualified environmental professionals to determine the applicability of each POC. The POC cover eleven technical disciplines: air; surface water and drinking water quality; groundwater; waste management; toxic and chemical materials; radiation; quality assurance; inactive waste sites and releases; ecological and cultural resources; the National Environmental Policy Act (NEPA); and environmental management systems.

  9. Negative terahertz conductivity in disordered graphene bilayers with population inversion

    SciTech Connect (OSTI)

    Svintsov, D.; Otsuji, T.; Ryzhii, V.; Mitin, V.; Shur, M. S.

    2015-03-16

    The gapless energy band spectra make the structures based on graphene and graphene bilayer with the population inversion to be promising media for the interband terahertz (THz) lasing. However, a strong intraband absorption at THz frequencies still poses a challenge for efficient THz lasing. In this paper, we show that in the pumped graphene bilayer, the indirect interband radiative transitions accompanied by scattering of carriers by disorder can provide a substantial negative contribution to the THz conductivity (together with the direct interband transitions). In the graphene bilayer on high-? substrates with point charged defects, these transitions substantially compensate the losses due to the intraband (Drude) absorption. We also demonstrate that the indirect interband contribution to the THz conductivity in a graphene bilayer with the extended defects (such as the charged impurity clusters) can surpass by several times the fundamental limit associated with the direct interband transitions, and the Drude conductivity as well. These predictions can affect the strategy of the graphene-based THz laser implementation.

  10. Steady-state magnetohydrodynamic flow around an unmagnetized conducting sphere

    SciTech Connect (OSTI)

    Romanelli, N.; Gmez, D.; Bertucci, C.; Delva, M. E-mail: Magda.Delva@oeaw.ac.at

    2014-07-01

    The noncollisional interaction between conducting obstacles and magnetized plasma winds can be found in different scenarios, from the interaction occurring between regions inside galaxy clusters to the interaction between the solar wind and Mars, Venus, and active comets, or even the interaction between Titan and the Saturnian magnetospheric flow. These objects generate, through several current systems, perturbations in the streaming magnetic field leading to its draping around the obstacle's effective conducting surface. Recent observational results suggest that several properties associated with magnetic field draping, such as the location of the polarity reversal layer of the induced magnetotail, are affected by variations in the conditions of the streaming magnetic field. To improve our understanding of these phenomena, we perform a characterization of several magnetic field draping signatures by analytically solving an ideal problem in which a perfectly conducting magnetized plasma (with frozen-in magnetic field conditions) flows around a spherical body for various orientations of the streaming magnetic field. In particular, we compute the shift of the inverse polarity reversal layer as the orientation of the background magnetic field is changed.

  11. On the complex conductivity signatures of calcite precipitation

    SciTech Connect (OSTI)

    Wu, Yuxin; Hubbard, Susan; Williams, Kenneth Hurst; Ajo-Franklin, Jonathan

    2009-11-01

    Calcite is a mineral phase that frequently precipitates during subsurface remediation or geotechnical engineering processes. This precipitation can lead to changes in the overall behavior of the system, such as flow alternation and soil strengthening. Because induced calcite precipitation is typically quite variable in space and time, monitoring its distribution in the subsurface is a challenge. In this research, we conducted a laboratory column experiment to investigate the potential of complex conductivity as a mean to remotely monitor calcite precipitation. Calcite precipitation was induced in a glass bead (3 mm) packed column through abiotic mixing of CaCl{sub 2} and Na{sub 2}CO{sub 3} solutions. The experiment continued for 12 days with a constant precipitation rate of {approx}0.6 milimole/d. Visual observations and scanning electron microscopy imaging revealed two distinct phases of precipitation: an earlier phase dominated by well distributed, discrete precipitates and a later phase characterized by localized precipitate aggregation and associated pore clogging. Complex conductivity measurements exhibited polarization signals that were characteristic of both phases of calcite precipitation, with the precipitation volume and crystal size controlling the overall polarization magnitude and relaxation time constant. We attribute the observed responses to polarization at the electrical double layer surrounding calcite crystals. Our experiment illustrates the potential of electrical methods for characterizing the distribution and aggregation state of nonconductive minerals like calcite. Advancing our ability to quantify geochemical transformations using such noninvasive methods is expected to facilitate our understanding of complex processes associated with natural subsurface systems as well as processes induced through engineered treatments (such as environmental remediation and carbon sequestration).

  12. Voltage tunability of thermal conductivity in ferroelectric materials

    DOE Patents [OSTI]

    Ihlefeld, Jon; Hopkins, Patrick Edward

    2016-02-09

    A method to control thermal energy transport uses mobile coherent interfaces in nanoscale ferroelectric films to scatter phonons. The thermal conductivity can be actively tuned, simply by applying an electrical potential across the ferroelectric material and thereby altering the density of these coherent boundaries to directly impact thermal transport at room temperature and above. The invention eliminates the necessity of using moving components or poor efficiency methods to control heat transfer, enabling a means of thermal energy control at the micro- and nano-scales.

  13. Fabrication Routes for High Strength High Conductivity Wires

    SciTech Connect (OSTI)

    Han, K.; Embury, J.D.; Sims, J.R.; Pantsyrnyi, V.I.; Shikov, A.; Bochvar, A.A.

    1998-10-01

    The development of suitable wires for magnet windings requires both the attainment of suitable combinations of properties (electrical conductivity and strength), the development of a production route capable of fabricating suitable quantity of wire of required dimension (5.2x7.6mm{sup 2} cross-section and 120 m in length) and a product with acceptable fabricability, joinability and service life. In this survey, the authors consider methods of producing suitable wire products by the codeformation of in-situ composites. This will include details of the quality control of the processing of Cu-Ag and Cu-Nb and the assessment of their detailed mechanical properties.

  14. Conductive polymeric cable anodes for pipelines with deteriorating coatings

    SciTech Connect (OSTI)

    Gibson, W.F.; Pikas, J.L. )

    1993-03-01

    Deteriorating pipeline coating systems have been a dilemma in the industry for many years. The interaction between coatings and cathodic protection (CP) is based on the type of coating and the amount of deterioration. There are two primary strategies to approach the problem: recoat, which is very expensive and may require taking the line out of service and cause loss of revenue; or install additional conventional CP groundbed systems. This article presents a state-of-the-art groundbed system using close-coupled conductive polymeric cable anodes that eliminate the problems of conventional groundbeds.

  15. Piecewise uniform conduction-like flow channels and method therefor

    DOE Patents [OSTI]

    Cummings, Eric B.; Fiechtner, Gregory J.

    2006-02-28

    A low-dispersion methodology for designing microfabricated conduction channels for on-chip electrokinetic-based systems is presented. The technique relies on trigonometric relations that apply for ideal electrokinetic flows, allowing faceted channels to be designed on chips using common drafting software and a hand calculator. Flows are rotated and stretched along the abrupt interface between adjacent regions with differing permeability. Regions bounded by interfaces form flow "prisms" that can be combined with other designed prisms to obtain a wide range of turning angles and expansion ratios while minimizing dispersion. Designs are demonstrated using two-dimensional numerical solutions of the Laplace equation.

  16. Devices, systems, and methods for conducting sandwich assays using sedimentation

    DOE Patents [OSTI]

    Schaff, Ulrich Y; Sommer, Gregory J; Singh, Anup K; Hatch, Anson V

    2015-02-03

    Embodiments of the present invention are directed toward devices, systems, and method for conducting sandwich assays using sedimentation. In one example, a method includes generating complexes on a plurality of beads in a fluid sample, individual ones of the complexes comprising a capture agent, a target analyte, and a labeling agent. The plurality of beads including the complexes may be transported through a density media, wherein the density media has a density lower than a density of the beads and higher than a density of the fluid sample, and wherein the transporting occurs, at least in part, by sedimentation. Signal may be detected from the labeling agents of the complexes.

  17. Planning and Conduct of Operational Readiness Reviews (ORR)

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    DOE-STD-3006-2000 June 2000 Superseding DOE-STD-3006-95 November 1995 DOE STANDARD PLANNING AND CONDUCT OF OPERATIONAL READINESS REVIEWS (ORR) U.S. Department of Energy AREA OPER Washington, D.C. 20585 DISTRIBUTION STATEMENT A. Approved for public release; distribution is unlimited. NOT MEASUREMENT SENSITIVE This document has been reproduced directly from the best available copy. Available to DOE and DOE contractors from ES&H Technical Information Services, U.S. Department of Energy, (800)

  18. Continuous Processing of High Thermal Conductivity Fibers and Sheets

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Professor Gang Chen, Carl Richard Soderberg Professor of Power Engineering 617-253-0006 (phone), 617-324-5545 (fax) gchen2@mit.edu U.S. DOE Advanced Manufacturing Office Peer Review Meeting Washington, D.C. May 6-7, 2014 This presentation does not contain any proprietary, confidential, or otherwise restricted information. Project Objective  Plastics are less expensive, lighter, and require less energy to process than metals; however, they have low thermal conductivity values (~0.3 W/mK) 

  19. Mixed anion materials and compounds for novel proton conducting membranes

    DOE Patents [OSTI]

    Poling, Steven Andrew; Nelson, Carly R.; Martin, Steve W.

    2006-09-05

    The present invention provides new amorphous or partially crystalline mixed anion chalcogenide compounds for use in proton exchange membranes which are able to operate over a wide variety of temperature ranges, including in the intermediate temperature range of about 100 .degree. C. to 300.degree. C., and new uses for crystalline mixed anion chalcogenide compounds in such proton exchange membranes. In one embodiment, the proton conductivity of the compounds is between about 10.sup.-8 S/cm and 10.sup.-1 S/cm within a temperature range of between about -60 and 300.degree. C. and a relative humidity of less than about 12%..

  20. P-type conductivity in annealed strontium titanate

    SciTech Connect (OSTI)

    Poole, Violet M.; Corolewski, Caleb D.; McCluskey, Matthew D.

    2015-12-17

    In this study, Hall-effect measurements indicate p-type conductivity in bulk, single-crystal strontium titanate (SrTiO3, or STO) samples that were annealed at 1200°C. Room temperature mobilities above 100 cm2/Vs were measured, an order of magnitude higher than those for electrons (5-10 cm2/Vs). Average hole densities were in the 109-1010 cm-3 range, consistent with a deep acceptor.

  1. P-type conductivity in annealed strontium titanate

    SciTech Connect (OSTI)

    Poole, Violet M.; Corolewski, Caleb D.; McCluskey, Matthew D.

    2015-12-15

    Hall-effect measurements indicate p-type conductivity in bulk, single-crystal strontium titanate (SrTiO{sub 3}, or STO) samples that were annealed at 1200°C. Room-temperature mobilities above 100 cm{sup 2}/V s were measured, an order of magnitude higher than those for electrons (5-10 cm{sup 2}/V s). Average hole densities were in the 10{sup 9}-10{sup 10} cm{sup −3} range, consistent with a deep acceptor.

  2. DOE Selects Ten Projects to Conduct Advanced Turbine Technology Research

    Broader source: Energy.gov [DOE]

    Ten university projects to conduct advanced turbine technology research under the Office of Fossil Energy’s University Turbine Systems Research Program have been selected by the U.S. Department of Energy for additional development. Developing gas turbines that run with greater cleanness and efficiency than current models is of great benefit both to the environment and the power industry, but development of such advanced turbine systems requires significant advances in high-temperature materials science, an understanding of combustion phenomena, and development of innovative cooling techniques to maintain integrity of turbine components.

  3. Conductive and robust nitride buffer layers on biaxially textured substrates

    DOE Patents [OSTI]

    Sankar, Sambasivan [Chicago, IL; Goyal, Amit [Knoxville, TN; Barnett, Scott A [Evanston, IL; Kim, Ilwon [Skokie, IL; Kroeger, Donald M [Knoxville, TN

    2009-03-31

    The present invention relates to epitaxial, electrically conducting and mechanically robust, cubic nitride buffer layers deposited epitaxially on biaxially textured substrates such as metals and alloys. The invention comprises of a biaxially textured substrate with epitaxial layers of nitrides. The invention also discloses a method to form such epitaxial layers using a high rate deposition method as well as without the use of forming gases. The invention further comprises epitaxial layers of oxides on the biaxially textured nitride layer. In some embodiments the article further comprises electromagnetic devices which may have superconducting properties.

  4. Tetraarylborate polymer networks as single-ion conducting solid electrolytes

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Van Humbeck, Jeffrey F.; Aubrey, Michael L.; Alsbaiee, Alaaeddin; Ameloot, Rob; Coates, Geoffrey W.; Dichtel, William R.; Long, Jeffrey R.

    2015-06-23

    A new family of solid polymer electrolytes based upon anionic tetrakis(phenyl)borate tetrahedral nodes and linear bis-alkyne linkers is reported. Sonogashira polymerizations using tetrakis(4-iodophenyl)borate, tetrakis(4-iodo-2,3,5,6-tetrafluorophenyl)borate and tetrakis(4-bromo-2,3,5,6-tetrafluorophenyl)borate delivered highly cross-linked polymer networks with both 1,4-diethynylbeznene and a tri(ethylene glycol) substituted derivative. Promising initial conductivity metrics have been observed, including high room temperature conductivities (up to 2.7 × 10-4 S cm-1), moderate activation energies (0.25–0.28 eV), and high lithium ion transport numbers (up to tLi+ = 0.93). Initial investigations into the effects of important materials parameters such as bulk morphology, porosity, fluorination, and other chemical modification, provide starting design parameters for furthermore » development of this new class of solid electrolytes.« less

  5. Tetraarylborate polymer networks as single-ion conducting solid electrolytes

    SciTech Connect (OSTI)

    Van Humbeck, Jeffrey F.; Aubrey, Michael L.; Alsbaiee, Alaaeddin; Ameloot, Rob; Coates, Geoffrey W.; Dichtel, William R.; Long, Jeffrey R.

    2015-06-23

    A new family of solid polymer electrolytes based upon anionic tetrakis(phenyl)borate tetrahedral nodes and linear bis-alkyne linkers is reported. Sonogashira polymerizations using tetrakis(4-iodophenyl)borate, tetrakis(4-iodo-2,3,5,6-tetrafluorophenyl)borate and tetrakis(4-bromo-2,3,5,6-tetrafluorophenyl)borate delivered highly cross-linked polymer networks with both 1,4-diethynylbeznene and a tri(ethylene glycol) substituted derivative. Promising initial conductivity metrics have been observed, including high room temperature conductivities (up to 2.7 × 10-4 S cm-1), moderate activation energies (0.25–0.28 eV), and high lithium ion transport numbers (up to tLi+ = 0.93). Initial investigations into the effects of important materials parameters such as bulk morphology, porosity, fluorination, and other chemical modification, provide starting design parameters for further development of this new class of solid electrolytes.

  6. Magnetoresistance, electrical conductivity, and Hall effect of glassy carbon

    SciTech Connect (OSTI)

    Baker, D.F.

    1983-02-01

    These properties of glassy carbon heat treated for three hours between 1200 and 2700/sup 0/C were measured from 3 to 300/sup 0/K in magnetic fields up to 5 tesla. The magnetoresistance was generally negative and saturated with reciprocal temperature, but still increased as a function of magnetic field. The maximum negative magnetoresistance measured was 2.2% for 2700/sup 0/C material. Several models based on the negative magnetoresistance being proportional to the square of the magnetic moment were attempted; the best fit was obtained for the simplest model combining Curie and Pauli paramagnetism for heat treatments above 1600/sup 0/C. Positive magnetoresistance was found only in less than 1600/sup 0/C treated glassy carbon. The electrical conductivity, of the order of 200 (ohm-cm)/sup -1/ at room temperature, can be empirically written as sigma = A + Bexp(-CT/sup -1/4) - DT/sup -1/2. The Hall coefficient was independent of magnetic field, insensitive to temperature, but was a strong function of heat treatment temperature, crossing over from negative to positive at about 1700/sup 0/C and ranging from -0.048 to 0.126 cm/sup 3//coul. The idea of one-dimensional filaments in glassy carbon suggested by the electrical conductivity is compatible with the present consensus view of the microstructure.

  7. The role of probe oxide in local surface conductivity measurements

    SciTech Connect (OSTI)

    Barnett, C. J.; Kryvchenkova, O.; Wilson, L. S. J.; Maffeis, T. G. G.; Cobley, R. J.; Kalna, K.

    2015-05-07

    Local probe methods can be used to measure nanoscale surface conductivity, but some techniques including nanoscale four point probe rely on at least two of the probes forming the same low resistivity non-rectifying contact to the sample. Here, the role of probe shank oxide has been examined by carrying out contact and non-contact I V measurements on GaAs when the probe oxide has been controllably reduced, both experimentally and in simulation. In contact, the barrier height is pinned but the barrier shape changes with probe shank oxide dimensions. In non-contact measurements, the oxide modifies the electrostatic interaction inducing a quantum dot that alters the tunneling behavior. For both, the contact resistance change is dependent on polarity, which violates the assumption required for four point probe to remove probe contact resistance from the measured conductivity. This has implications for all nanoscale surface probe measurements and macroscopic four point probe, both in air and vacuum, where the role of probe oxide contamination is not well understood.

  8. Solar conductive spa water heater and safety cover

    SciTech Connect (OSTI)

    Ely, G.W.

    1987-04-28

    This patent describes a solar conductive portable cover for a spa which has an opening for access comprising a rigid plastic member vacuum formed in a series of interconnected parallel U-shaped channels. Each channel is separated from an adjacent channel by a wall. A shape conforms plastic top solvent or heat is welded to a top surface of the walls to form a cover wider in diameter than the opening of the spa, such that the cover rests on coping at the top of the spa. Method is described for heating water for a spa comprising covering the top of the spa with a portable rigid thin plastic member forming a cover wider than the opening of the spa such that the cover rests on coping at the top of the spa and having a series of parallel U-shaped channels.

  9. High Thermal Conductivity of a Hydrogenated Amorphous Silicon Film

    SciTech Connect (OSTI)

    Liu, X.; Feldman, J. L.; Cahill, D. G.; Crandall, R. S.; Bernstein, N.; Photiadis, D. M.; Mehl, M. J.; Papaconstantopoulos, D. A.

    2009-01-23

    We measured the thermal conductivity {kappa} of an 80 {micro}m thick hydrogenated amorphous silicon film prepared by hot-wire chemical-vapor deposition with the 3{omega} (80-300 K) and the time-domain thermoreflectance (300 K) methods. The {kappa} is higher than any of the previous temperature dependent measurements and shows a strong phonon mean free path dependence. We also applied a Kubo based theory using a tight-binding method on three 1000 atom continuous random network models. The theory gives higher {kappa} for more ordered models, but not high enough to explain our results, even after extrapolating to lower frequencies with a Boltzmann approach. Our results show that this material is more ordered than any amorphous silicon previously studied.

  10. Ion-conducting ceramic apparatus, method, fabrication, and applications

    DOE Patents [OSTI]

    Yates, Matthew; Liu, Dongxia

    2012-03-06

    A c-axis-oriented HAP thin film synthesized by seeded growth on a palladium hydrogen membrane substrate. An exemplary synthetic process includes electrochemical seeding on the substrate, and secondary and tertiary hydrothermal treatments under conditions that favor growth along c-axes and a-axes in sequence. By adjusting corresponding synthetic conditions, an HAP this film can be grown to a controllable thickness with a dense coverage on the underlying substrate. The thin films have relatively high proton conductivity under hydrogen atmosphere and high temperature conditions. The c-axis oriented films may be integrated into fuel cells for application in the intermediate temperature range of 200-600.degree. C. The electrochemical-hydrothermal deposition technique may be applied to create other oriented crystal materials having optimized properties, useful for separations and catalysis as well as electronic and electrochemical applications, electrochemical membrane reactors, and in chemical sensors.

  11. Development of high performance proton-conducting solid electrolytes

    SciTech Connect (OSTI)

    Linkous, C.A.; Kopitzke, R.W.

    1998-08-01

    This work seeks to improve the efficiency of fuel cell and electrolyzer operation by developing solid electrolytes that will function at higher temperatures. Two objectives were pursued: (1) determine the mechanism of hydrolytic decomposition of aromatic sulfonic acid ionomers, with the intent of identifying structural weaknesses that can be avoided in future materials; and (2) identify new directions in solid electrolyte development. After evaluating a number of aromatic sulfonates, it became apparent that no common mechanism was going to be found; instead, each polymer had its own sequence of degradation steps, involving some combination of desulfonation and/or chain scission. For electrochemical cell operation at temperatures > 200 C, it will be necessary to develop solid electrolytes that do not require sulfonic acids and do not require water to maintain its conductivity mechanism.

  12. Transparent electrical conducting films by activated reactive evaporation

    DOE Patents [OSTI]

    Bunshah, Rointan; Nath, Prem

    1982-01-01

    Process and apparatus for producing transparent electrical conducting thin films by activated reactive evaporation. Thin films of low melting point metals and alloys, such as indium oxide and indium oxide doped with tin, are produced by physical vapor deposition. The metal or alloy is vaporized by electrical resistance heating in a vacuum chamber, oxygen and an inert gas such as argon are introduced into the chamber, and vapor and gas are ionized by a beam of low energy electrons in a reaction zone between the resistance heater and the substrate. There is a reaction between the ionized oxygen and the metal vapor resulting in the metal oxide which deposits on the substrate as a thin film which is ready for use without requiring post deposition heat treatment.

  13. Materials for use as proton conducting membranes for fuel cells

    DOE Patents [OSTI]

    Einsla, Brian R.; McGrath, James E.

    2009-01-06

    A family of polymers having pendent sulfonate moieties connected to polymeric main chain phenyl groups are described. These polymers are prepared by the steps of polymerization (using a monomer with a phenyl with an alkoxy substitution), deportation by converting the alkoxy to a hydroxyl, and functionalization of the polymer with a pendant sulfonate group. As an example, sulfonated poly(arylene ether sulfone) copolymers with pendent sulfonic acid groups are synthesized by the direct copolymerization of methoxy-containing poly(arylene ether sulfone)s, then converting the methoxy groups to the reactive hydroxyl form, and finally functionalizing the hydroxyl form with proton-conducting sites through nucleophilic substitution. The family of polymers may have application in proton exchange membranes and in other applications.

  14. Glass capable of ionic conduction and method of preparation

    DOE Patents [OSTI]

    Susman, Sherman (Park Forest, IL); Boehm, Leah (Jerusalem, IL); Volin, Kenneth J. (Fort Collins, CO); Delbacq, Charles J. (Downers Grove, IL)

    1985-01-01

    Sulfide glasses capable of conducting alkali metal ions are prepared from a nonmetal glass former such as GeS.sub.2, B.sub.2 S.sub.3 and SiS.sub.2 in mixture with a glass modifier such as Na.sub.2 S or another alkali metal sulfide. A molten mixture of the constituents is rapidly quenched to below the glass transition temperature by contact with a metal mold. The rapid quench is sufficient to prevent crystallization and permit solidification as an amorphous solid mixture. An oxygen-free atmosphere is maintained over the mixture to prevent oxidation. A new glass system of (1-X) Na.sub.2 O:XB.sub.2 S.sub.3 is disclosed.

  15. Glass capable of ionic conduction and method of preparation

    DOE Patents [OSTI]

    Susman, Sherman (Park Forest, IL); Delbecq, Charles J. (Downers Grove, IL); Volin, Kenneth J. (Fort Collins, CO); Boehm, Leah (Jerusalem, IL)

    1984-01-01

    Sulfide glasses capable of conducting alkali metal ions are prepared from a nonmetal glass former such as GeS.sub.2, B.sub.2 S.sub.3 and SiS.sub.2 in mixture with a glass modifier such as Na.sub.2 S or another alkali metal sulfide. A molten mixture of the constituents is rapidly quenched to below the glass transition temperature by contact with a metal mold. The rapid quench is sufficient to prevent crystallization and permit solidification as an amorphous solid mixture. An oxygen-free atmosphere is maintained over the mixture to prevent oxidation. A new glass system of (1-X) Na.sub.2 O:XB.sub.2 S.sub.3 is disclosed.

  16. Glass capable of ionic conduction and method of preparation

    DOE Patents [OSTI]

    Susman, S.; Boehm, L.; Volin, K.J.; Delbecq, C.J.

    1982-05-06

    Sulfide glasses capable of conducting alkali metal ions are prepared from a nonmetal glass former such as GeS/sub 2/, B/sub 2/S/sub 2/ and SiS/sub 2/ in mixture with a glass modifier such as Na/sub 2/S or another alkali metal sulfide. A molten mixture of the constituents is rapidly quenched to below the glass transition temperature by contact with a metal mold. The rapid quench is sufficient to prevent crystallization and permit solidification as an amorphous solid mixture. An oxygen-free atmosphere is maintained over the mixture to prevent oxidation. A new glass system of (1 - X) Na/sub 2/O:XB/sub 2/S/sub 3/ is disclosed.

  17. Glass capable of ionic conduction and method of preparation

    DOE Patents [OSTI]

    Susman, S.; Delbecq, C.J.; Volin, K.J.; Boehm, L.

    1984-02-21

    Sulfide glasses capable of conducting alkali metal ions are prepared from a nonmetal glass former such as GeS[sub 2], B[sub 2]S[sub 3] and SiS[sub 2] in mixture with a glass modifier such as Na[sub 2]S or another alkali metal sulfide. A molten mixture of the constituents is rapidly quenched to below the glass transition temperature by contact with a metal mold. The rapid quench is sufficient to prevent crystallization and permit solidification as an amorphous solid mixture. An oxygen-free atmosphere is maintained over the mixture to prevent oxidation. A new glass system of (1-X) Na[sub 2]O:XB[sub 2]S[sub 3] is disclosed. 4 figs.

  18. Synthesis of polymer nanostructures with conductance switching properties

    DOE Patents [OSTI]

    Su, Kai; Nuraje, Nurxat; Zhang, Lingzhi; Matsui, Hiroshi; Yang, Nan Loh

    2015-03-03

    The present invention is directed to crystalline organic polymer nanoparticles comprising a conductive organic polymer; wherein the crystalline organic polymer nanoparticles have a size of from 10 nm to 200 nm and exhibits two current-voltage states: (1) a high resistance current-voltage state, and (2) a low resistance current-voltage state, wherein when a first positive threshold voltage (V.sub.th1) or higher positive voltage, or a second negative threshold voltage (V.sub.th2) or higher negative voltage is applied to the nanoparticle, the nanoparticle exhibits the low-resistance current-voltage state, and when a voltage less positive than the first positive threshold voltage or a voltage less negative than the second negative threshold voltage is applied to the nanoparticle, the nanoparticle exhibits the high-resistance current-voltage state. The present invention is also directed methods of manufacturing the nanoparticles using novel interfacial oxidative polymerization techniques.

  19. Polymeric salt bridges for conducting electric current in microfluidic devices

    DOE Patents [OSTI]

    Shepodd, Timothy J.; Tichenor, Mark S.; Artau, Alexander

    2009-11-17

    A "cast-in-place" monolithic microporous polymer salt bridge for conducting electrical current in microfluidic devices, and methods for manufacture thereof is disclosed. Polymeric salt bridges are formed in place in capillaries or microchannels. Formulations are prepared with monomer, suitable cross-linkers, solvent, and a thermal or radiation responsive initiator. The formulation is placed in a desired location and then suitable radiation such as UV light is used to polymerize the salt bridge within a desired structural location. Embodiments are provided wherein the polymeric salt bridges have sufficient porosity to allow ionic migration without bulk flow of solvents therethrough. The salt bridges form barriers that seal against fluid pressures in excess of 5000 pounds per square inch. The salt bridges can be formulated for carriage of suitable amperage at a desired voltage, and thus microfluidic devices using such salt bridges can be specifically constructed to meet selected analytical requirements.

  20. Diffusion-controlled creep in mixed-conducting oxides

    SciTech Connect (OSTI)

    Routbort, J.L.; Goretta, K.C.; Cook, R.E.; Wolfenstine, J.; Armstrong, T.R.; Clauss, C.; Dominguez-Rodriguez, A.

    1996-06-01

    Steady-state creep rate of the mixed conducting oxides La{sub 1-x}Sr{sub x}MnO{sub 3} (x=0.1, 0.15, 0.25) and La{sub 0.7}Ca{sub 0.3}MnO{sub 3} has been investigated between 1150 and 1300 C. Creep parameters and TEM indicate that deformation is controlled by lattice diffusion of one of the cations. Dependence of creep rate on Sr concentration, combined with a point-defect model, confirms this hypothesis; however the oxygen partial pressure dependence of creep (from 10{sup -1} to 2x10{sup 4} Pa) cannot be accounted for within the framework of a simple point-defect model.

  1. REDUCING PRODUCED WATER WITH DENSITY AND CONDUCTIVITY METERS

    SciTech Connect (OSTI)

    Jason T. Smith

    2004-08-01

    The work performed was an attempt to reduce the amount of produced water by using the well bore as an oil-water separator. The use of a flow meter, density meter and/or conductivity meter controlling a pumping unit would be used to achieve this goal. The natural physical differences between oil and water are easily detected inside the production stream with proper equipment. A coriolis mass meter, conductivity meter, data recorder, timer and relays were purchased and housed in a purpose-built field cabinet. The metering unit was hooked to four wells over the course of the project, Spencer No.8, Applegate Gray Unit No.1 (AGU No.1), Vollmer No.4 and Mohr No.1. All are located in the Illinois Basin, three with artificial lift pumps and one flowing well. Depth of producing formations ranges from a maximum of 846.13 m (2776 ft) to minimum of 316.69 m (1039 ft). All wells were completed in one formation of Mississippian or Pennsylvanian age. The data recorded were analyzed to determine what events could be detected. Events included pure oil or higher oil-cut fluid reaching the pump or reaching the metering equipment, the pump operating under capacity, and the well ''pumped down''. Based on how much oil and water is present in a fluid column, the pressure the fluid column imparts on a formation can be calculated. By knowing the amount of oil and water in a well bore and the maximum height water can reach, production equipment can be configured to only produce oil. However, the configuration may not be profitable. It became apparent during the course of this research the wells tested do not have an oil-water contact deep enough so traditional pumping equipment can be configured to recover oil by the proposed method. This method may work more successfully in deeper basins. Other interesting anomalies were also detected in the data.

  2. Stacked mechanical nanogenerator comprising piezoelectric semiconducting nanostructures and Schottky conductive contacts

    DOE Patents [OSTI]

    Wang, Zhong L.; Xu, Sheng

    2011-08-23

    An electric power generator includes a first conductive layer, a plurality of semiconducting piezoelectric nanostructures, a second conductive layer and a plurality of conductive nanostructures. The first conductive layer has a first surface from which the semiconducting piezoelectric nanostructures extend. The second conductive layer has a second surface and is parallel to the first conductive layer so that the second surface faces the first surface of the first conductive layer. The conductive nanostructures depend downwardly therefrom. The second conductive layer is spaced apart from the first conductive layer at a distance so that when a force is applied, the semiconducting piezoelectric nanostructures engage the conductive nanostructures so that the piezoelectric nanostructures bend, thereby generating a potential difference across the at semiconducting piezoelectric nanostructures and also thereby forming a Schottky barrier between the semiconducting piezoelectric nanostructures and the conductive nanostructures.

  3. CRAD, Conduct of Engineering - May 4, 2015 (EA CRAD 31-13, Rev...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Conduct of Engineering - May 4, 2015 (EA CRAD 31-13, Rev. 0 CRAD, Conduct of Engineering - May 4, 2015 (EA CRAD 31-13, Rev. 0 May 2015 Conduct of Engineering (EA CRAD 31-13, Rev....

  4. Metallic conductance below T{sub c} inferred by quantum interference...

    Office of Scientific and Technical Information (OSTI)

    Metallic conductance below Tsub c inferred by quantum interference effects in layered ... Title: Metallic conductance below Tsub c inferred by quantum interference effects in ...

  5. Data Privacy and the Smart Grid: A Voluntary Code of Conduct...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Conduct Data Privacy and the Smart Grid: A Voluntary Code of Conduct The Office of ... use services that addresses privacy related to data enabled by smart grid technologies. ...

  6. PROTON-CONDUCTING DENSE CERAMIC MEMBRANES FOR HYDROGEN SEPARATION

    SciTech Connect (OSTI)

    Jerry Y. S. Lin; Scott Cheng; Vineet Gupta

    2003-12-01

    Dense perovskite-type structured ceramic membranes, SrCe{sub 0.95}Tm{sub 0.05}O{sub 3} (SCTm), of different thickness, were prepared by the dry-press method. Membrane thickness was varied from 3 mm to 150 {micro}m. The hydrogen permeation flux was found to be inversely proportional to the thickness of the dense films, indicating that the bulk diffusion rather than the surface reaction played a dominant role in the H{sub 2} transport through these dense membranes within the studied thickness range. Hydrogen permeation flux increases with increasing upstream hydrogen partial pressure and decreasing downstream hydrogen partial pressure. The activation energy for hydrogen permeation through the SCTm membrane is about 116 kJ/mol in 600-700 C and 16 kJ/mol in 750-950 C. This indicates a change in the electrical and protonic conduction mechanism at around 700 C. Pd-Cu thin films were synthesized with elemental palladium and copper targets by the sequential R.F. sputter deposition on porous substrates. Pd-Cu alloy films could be formed after proper annealing. The deposited Pd-Cu films were gas-tight. This result demonstrated the feasibility of obtaining an ultrathin SCTm film by the sequential sputter deposition of Sr, Ce and Tm metals followed by proper annealing and oxidation. Such ultrathin SCTm membranes will offer sufficiently high hydrogen permeance for practical applications.

  7. High-performance, transparent conducting oxides based on cadmium stannate

    SciTech Connect (OSTI)

    Coutts, T.J.; Wu, X.; Mulligan, W.P.; Webb, J.M.

    1996-06-01

    We discuss the modeling of thin films of transparent conducting oxides and we compare the predictions with the observed properties of cadmium stannate. Thin films of this material were deposited using radio-frequency magnetron sputtering. The Drude free-carrier model is used to model the optical and electrical properties. The model demonstrates the need for high mobilities. The free-carrier absorbance in the visible spectrum is used as a comparative figure-of-merit for cadmium stannate and tin oxide. This shows that free-carrier absorbance is much less in cadmium stannate than in tin oxide. X-ray diffraction shows that annealed films consist of a single-phase spinel structure. The post-deposition annealing sequence is shown to be crucial to forming a single phase, which is vital for optimal optical and electrical properties. The films are typically high mobility (up to 65 cm{sup 2}V{sup -1}s{sup -1}) and have carrier concentrations as high as 10{sup 21} cm{sup -3}. Resistivities are as low as 1.3 10{sup -4} {Omega} cm, the lowest values reported for cadmium stannate. Atomic force microscopy indicates that the root-mean-square surface roughness is approximately {+-}15A. Cadmium stannate etches readily in both hydrofluoric and hydrochloric acid, which is a commanding advantage over tin oxide. 11 refs., 15 figs.

  8. Thermal conductivity of graphene mediated by strain and size

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kuang, Youdi; Shi, Sanqiang; Wang, Xinjiang; Huang, Baoling; Lindsay, Lucas

    2016-06-09

    Based on first-principles calculations and full iterative solution of the linearized Boltzmann–Peierls transport equation for phonons, we systematically investigate effects of strain, size and temperature on the thermal conductivity k of suspended graphene. The calculated size-dependent and temperature-dependent k for finite samples agree well with experimental data. The results show that, contrast to the convergent room-temperature k = 5450 W/m-K of unstrained graphene at a sample size ~8 cm, k of strained graphene diverges with increasing the sample size even at high temperature. Out-of-plane acoustic phonons are responsible for the significant size effect in unstrained and strained graphene due tomore » their ultralong mean free path and acoustic phonons with wavelength smaller than 10 nm contribute 80% to the intrinsic room temperature k of unstrained graphene. Tensile strain hardens the flexural modes and increases their lifetimes, causing interesting dependence of k on sample size and strain due to the competition between boundary scattering and intrinsic phonon–phonon scattering. k of graphene can be tuned within a large range by strain for the size larger than 500 μm. These findings shed light on the nature of thermal transport in two-dimensional materials and may guide predicting and engineering k of graphene by varying strain and size.« less

  9. Washing of Rocky Flats Combustible Residues (Conducted March - May 1995)

    SciTech Connect (OSTI)

    Mary E. Barr; Ann R. Schake; David A. Romero; Gordon D. Jarvinen

    1999-03-01

    The scope of this project is to determine the feasibility of washing plutonium-containing combustible residues using ultrasonic disruption as a method for dislodging particulate. Removal of plutonium particulate and, to a lesser extent, solubilized plutonium from the organic substrate should substantially reduce potential fire, explosion or radioactive release hazards due to radiolytic hydrogen generation or high flammability. Tests were conducted on polypropylene filters which were used as pre-filters in the rich-residue ion-exchange process at the Los Alamos Plutonium Facility. These filters are similar to the Ful-Flo{reg_sign} cartridges used at Rocky Flats that make up a substantial fraction of the combustible residues with the highest hazard rating. Batch experiments were run on crushed filter material in order to determine the amount of Pu removed by stirring, stirring and sonication, and stirring and sonication with the introduction of Pu-chelating water-soluble polymers or surfactants. Significantly more Pu is removed using sonication and sonication with chelators than is removed with mechanical stirring alone.

  10. Strong and Electrically Conductive Graphene Based Composite Fibers and Laminates

    SciTech Connect (OSTI)

    Vlassiouk, Ivan V.; Polyzos, Georgios; Cooper, Ryan C.; Ivanov, Ilia N.; Keum, Jong Kahk; Paulauskas, Felix L.; Datskos, Panos G.; Smirnov, Sergei

    2015-04-28

    Graphene is an ideal candidate for lightweight, high-strength composite materials given its superior mechanical properties (specific strength of 130 GPa and stiffness of 1 TPa). To date, easily scalable graphene-like materials in a form of separated flakes (exfoliated graphene, graphene oxide, and reduced graphene oxide) have been investigated as candidates for large-scale applications such as material reinforcement. These graphene-like materials do not fully exhibit all the capabilities of graphene in composite materials. In this study, we show that macro (2 inch 2 inch) graphene laminates and fibers can be produced using large continuous sheets of single-layer graphene grown by chemical vapor deposition. The resulting composite structures have potential to outperform the current state-of-the-art composite materials in both mechanical properties and electrical conductivities (>8 S/cm with only 0.13% volumetric graphene loading and 5 103 S/cm for pure graphene fibers) with estimated graphene contributions of >10 GPa in strength and 1 TPa in stiffness.

  11. Iterative electromagnetic Born inversion applied to earth conductivity imaging

    SciTech Connect (OSTI)

    Alumbaugh, D.L.

    1993-08-01

    This thesis investigates the use of a fast imaging technique to deduce the spatial conductivity distribution in the earth from low frequency (< 1 MHz), cross well electromagnetic (EM) measurements. The theory embodied in this work is the extension of previous strategies and is based on the Born series approximation to solve both the forward and inverse problem. Nonlinear integral equations are employed to derive the series expansion which accounts for the scattered magnetic fields that are generated by inhomogeneities embedded in either a homogenous or a layered earth. A sinusoidally oscillating, vertically oriented magnetic dipole is employed as a source, and it is assumed that the scattering bodies are azimuthally symmetric about the source dipole axis. The use of this model geometry reduces the 3-D vector problem to a more manageable 2-D scalar form. The validity of the cross well EM method is tested by applying the imaging scheme to two sets of field data. Images of the data collected at the Devine, Texas test site show excellent correlation with the well logs. Unfortunately there is a drift error present in the data that limits the accuracy of the results. A more complete set of data collected at the Richmond field station in Richmond, California demonstrates that cross well EM can be successfully employed to monitor the position of an injected mass of salt water. Both the data and the resulting images clearly indicate the plume migrates toward the north-northwest. The plausibility of these conclusions is verified by applying the imaging code to synthetic data generated by a 3-D sheet model.

  12. High Temperature Variable Conductance Heat Pipes for Radioisotope Stirling Systems

    SciTech Connect (OSTI)

    Tarau, Calin; Walker, Kara L.; Anderson, William G.

    2009-03-16

    In a Stirling radioisotope system, heat must continually be removed from the GPHS modules, to maintain the GPHS modules and surrounding insulation at acceptable temperatures. Normally, the Stirling converter provides this cooling. If the Stirling engine stops in the current system, the insulation is designed to spoil, preventing damage to the GPHS, but also ending the mission. An alkali-metal Variable Conductance Heat Pipe (VCHP) is under development to allow multiple stops and restarts of the Stirling engine. The status of the ongoing effort in developing this technology is presented in this paper. An earlier, preliminary design had a radiator outside the Advanced Stirling Radioisotope Generator (ASRG) casing, used NaK as the working fluid, and had the reservoir located on the cold side adapter flange. The revised design has an internal radiator inside the casing, with the reservoir embedded inside the insulation. A large set of advantages are offered by this new design. In addition to reducing the overall size and mass of the VCHP, simplicity, compactness and easiness in assembling the VCHP with the ASRG are significantly enhanced. Also, the permanently elevated temperatures of the entire VCHP allows the change of the working fluid from a binary compound (NaK) to single compound (Na). The latter, by its properties, allows higher performance and further mass reduction of the system. Preliminary design and analysis shows an acceptable peak temperature of the ASRG case of 140 deg. C while the heat losses caused by the addition of the VCHP are 1.8 W.

  13. Apparent thermal conductivity measurements by an unguarded technique

    SciTech Connect (OSTI)

    Graves, R.S.; Yarbrough, D.W.; McElroy, D.L.

    1983-01-01

    An unguarded longitudinal heat-flow apparatus for measuring the apparent thermal conductivity (lambda/sub a) of insulations was tested with mean specimen temperatures from 300 to 330/sup 0/K on samples up to 0.91 m wide, 1.52 m long, and 0.15 m thick. Heat flow is provided by a horizontal electrically heated Nichrome screen sandwiched between test samples that are bounded by temperature controlled copper plates and 9 cm of mineral fiber insulation. A determinate error analysis shows lambda/sub a/ measurement uncertainty to be less than +- 1.7% for insulating materials as thin as 3 cm. Three-dimensional thermal modeling indicates negligible error in lambda/sub a/ due to edge loss for insulations up to 7.62 cm thick when the temperature difference across the sample is measured at the sceen center. System repeatability and reproducibility were determined to be +- 0.2%. Differences of lambda/sub a/ results from the screen tester and results from the National Bureau of Standards were 0.1% for a 10-kg/m/sup 3/ Calibration Transfer Standard and 0.9% for 127-kg/m/sup 3/ fibrous glass board (SRM 1450b). Measurements on fiberglass and rock wool batt insulations showed the dependence of lambda/sub a/ on density, temperature, temperature difference, plate emittance, and heat flow direction. Results obtained for lambda/sub a/ as a function of density at 24/sup 0/C differed by less than 2% from values obtained with a guarded hot plate. These results demonstrate that this simple technique has the accuracy and sensitivity needed for useful lambda/sub a/ measurements on thermal insulating materials.

  14. PROTON-CONDUCTING DENSE CERAMIC MEMBRANES FOR HYDROGEN SEPARATION

    SciTech Connect (OSTI)

    Jerry Y.S. Lin; Vineet Gupta; Scott Cheng

    2004-11-01

    /ionic conductivities. The H{sub 2} permeation rates were found to be inversely proportional to the thickness of the dense film indicating that bulk diffusion rather than surface reaction played a dominant role in H{sub 2} transport through these dense films within the studied thickness range (150 {micro}m - 1 mm).

  15. Radiation and gas conduction heat transport across a helium dewer multilayer insulation system

    SciTech Connect (OSTI)

    Green, M.A.

    1995-02-01

    This report describes a method for calculating mixed heat transfer through the multilayer insulation used to insulated a 4K liquid helium cryostat. The method described permits one to estimate the insulation potential for a multilayer insulation system from first principles. The heat transfer regimes included are: radiation, conduction by free molecule gas conduction, and conduction through continuum gas conduction. Heat transfer in the transition region between the two gas conduction regimes is also included.

  16. Method and apparatus for connecting high voltage leads to a high temperature super-conducting transformer

    DOE Patents [OSTI]

    Golner, Thomas M.; Mehta, Shirish P.

    2005-07-26

    A method and apparatus for connecting high voltage leads to a super-conducting transformer is provided that includes a first super-conducting coil set, a second super-conducting coil set, and a third super-conducting coil set. The first, second and third super-conducting coil sets are connected via an insulated interconnect system that includes insulated conductors and insulated connectors that are utilized to connect the first, second, and third super-conducting coil sets to the high voltage leads.

  17. Carlsbad Field Office (CBFO) Audit A-04-05, conducted at Los...

    Energy Savers [EERE]

    04-05, conducted at Los Alamos National Laboratory (LANL), April 26-30, 2004 Carlsbad Field Office (CBFO) Audit A-04-05, conducted at Los Alamos National Laboratory (LANL), April ...

  18. Carlsbad Field Office (CBFO) Audit A-13-23, conducted at Los...

    Energy Savers [EERE]

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