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Sample records for ion trap mass

  1. Mini ion trap mass spectrometer

    DOE Patents [OSTI]

    Dietrich, D.D.; Keville, R.F.

    1995-09-19

    An ion trap is described which operates in the regime between research ion traps which can detect ions with a mass resolution of better than 1:10{sup 9} and commercial mass spectrometers requiring 10{sup 4} ions with resolutions of a few hundred. The power consumption is kept to a minimum by the use of permanent magnets and a novel electron gun design. By Fourier analyzing the ion cyclotron resonance signals induced in the trap electrodes, a complete mass spectra in a single combined structure can be detected. An attribute of the ion trap mass spectrometer is that overall system size is drastically reduced due to combining a unique electron source and mass analyzer/detector in a single device. This enables portable low power mass spectrometers for the detection of environmental pollutants or illicit substances, as well as sensors for on board diagnostics to monitor engine performance or for active feedback in any process involving exhausting waste products. 10 figs.

  2. Mini ion trap mass spectrometer

    DOE Patents [OSTI]

    Dietrich, Daniel D.; Keville, Robert F.

    1995-01-01

    An ion trap which operates in the regime between research ion traps which can detect ions with a mass resolution of better than 1:10.sup.9 and commercial mass spectrometers requiring 10.sup.4 ions with resolutions of a few hundred. The power consumption is kept to a minimum by the use of permanent magnets and a novel electron gun design. By Fourier analyzing the ion cyclotron resonance signals induced in the trap electrodes, a complete mass spectra in a single combined structure can be detected. An attribute of the ion trap mass spectrometer is that overall system size is drastically reduced due to combining a unique electron source and mass analyzer/detector in a single device. This enables portable low power mass spectrometers for the detection of environmental pollutants or illicit substances, as well as sensors for on board diagnostics to monitor engine performance or for active feedback in any process involving exhausting waste products.

  3. Microscale ion trap mass spectrometer

    DOE Patents [OSTI]

    Ramsey, J. Michael (Knoxville, TN); Witten, William B. (Lancing, TN); Kornienko, Oleg (Lansdale, PA)

    2002-01-01

    An ion trap for mass spectrometric chemical analysis of ions is delineated. The ion trap includes a central electrode having an aperture; a pair of insulators, each having an aperture; a pair of end cap electrodes, each having an aperture; a first electronic signal source coupled to the central electrode; a second electronic signal source coupled to the end cap electrodes. The central electrode, insulators, and end cap electrodes are united in a sandwich construction where their respective apertures are coaxially aligned and symmetric about an axis to form a partially enclosed cavity having an effective radius r.sub.0 and an effective length 2z.sub.0, wherein r.sub.0 and/or z.sub.0 are less than 1.0 mm, and a ratio z.sub.0 /r.sub.0 is greater than 0.83.

  4. Universal collisional activation ion trap mass spectrometry

    DOE Patents [OSTI]

    McLuckey, S.A.; Goeringer, D.E.; Glish, G.L.

    1993-04-27

    A universal collisional activation ion trap comprises an ion trapping means containing a bath gas and having connected thereto a noise signal generator. A method of operating a universal collisional activation ion trap comprises the steps of: providing an ion trapping means; introducing into the ion trapping means a bath gas; and, generating a noise signal within the ion trapping means; introducing into the ion trapping means a substance that, when acted upon by the noise signal, undergoes collisional activation to form product ions.

  5. Universal collisional activation ion trap mass spectrometry

    DOE Patents [OSTI]

    McLuckey, Scott A. (Oak Ridge, TN); Goeringer, Douglas E. (Oak Ridge, TN); Glish, Gary L. (Oak Ridge, TN)

    1993-01-01

    A universal collisional activation ion trap comprises an ion trapping means containing a bath gas and having connected thereto a noise signal generator. A method of operating a universal collisional activation ion trap comprises the steps of: providing an ion trapping means; introducing into the ion trapping means a bath gas; and, generating a noise signal within the ion trapping means; introducing into the ion trapping means a substance that, when acted upon by the noise signal, undergoes collisional activation to form product ions.

  6. Electron source for a mini ion trap mass spectrometer

    DOE Patents [OSTI]

    Dietrich, Daniel D.; Keville, Robert F.

    1995-01-01

    An ion trap which operates in the regime between research ion traps which can detect ions with a mass resolution of better than 1:10.sup.9 and commercial mass spectrometers requiring 10.sup.4 ions with resolutions of a few hundred. The power consumption is kept to a minimum by the use of permanent magnets and a novel electron gun design. By Fourier analyzing the ion cyclotron resonance signals induced in the trap electrodes, a complete mass spectra in a single combined structure can be detected. An attribute of the ion trap mass spectrometer is that overall system size is drastically reduced due to combining a unique electron source and mass analyzer/detector in a single device. This enables portable low power mass spectrometers for the detection of environmental pollutants or illicit substances, as well as sensors for on board diagnostics to monitor engine performance or for active feedback in any process involving exhausting waste products.

  7. Electron source for a mini ion trap mass spectrometer

    DOE Patents [OSTI]

    Dietrich, D.D.; Keville, R.F.

    1995-12-19

    An ion trap is described which operates in the regime between research ion traps which can detect ions with a mass resolution of better than 1:10{sup 9} and commercial mass spectrometers requiring 10{sup 4} ions with resolutions of a few hundred. The power consumption is kept to a minimum by the use of permanent magnets and a novel electron gun design. By Fourier analyzing the ion cyclotron resonance signals induced in the trap electrodes, a complete mass spectra in a single combined structure can be detected. An attribute of the ion trap mass spectrometer is that overall system size is drastically reduced due to combining a unique electron source and mass analyzer/detector in a single device. This enables portable low power mass spectrometers for the detection of environmental pollutants or illicit substances, as well as sensors for on board diagnostics to monitor engine performance or for active feedback in any process involving exhausting waste products. 10 figs.

  8. Differentially pumped dual linear quadrupole ion trap mass spectrometer

    DOE Patents [OSTI]

    Owen, Benjamin C.; Kenttamaa, Hilkka I.

    2015-10-20

    The present disclosure provides a new tandem mass spectrometer and methods of using the same for analyzing charged particles. The differentially pumped dual linear quadrupole ion trap mass spectrometer of the present disclose includes a combination of two linear quadrupole (LQIT) mass spectrometers with differentially pumped vacuum chambers.

  9. Dipole Excitation With A Paul Ion Trap Mass Spectrometer

    SciTech Connect (OSTI)

    MacAskill, J. A.; Madzunkov, S. M.; Chutjian, A.

    2011-06-01

    Preliminary results are presented for the use of an auxiliary radiofrequency (rf) excitation voltage in combination with a high purity, high voltage rf generator to perform dipole excitation within a high precision Paul ion trap. These results show the effects of the excitation frequency over a continuous frequency range on the resultant mass spectra from the Paul trap with particular emphasis on ion ejection times, ion signal intensity, and peak shapes. Ion ejection times are found to decrease continuously with variations in dipole frequency about several resonant values and show remarkable symmetries. Signal intensities vary in a complex fashion with numerous resonant features and are driven to zero at specific frequency values. Observed intensity variations depict dipole excitations that target ions of all masses as well as individual masses. Substantial increases in mass resolution are obtained with resolving powers for nitrogen increasing from 114 to 325.

  10. Electron Flood Charge Compensation Device for Ion Trap Secondary Ion Mass Spectrometry

    SciTech Connect (OSTI)

    Appelhans, Anthony David; Ward, Michael Blair; Olson, John Eric

    2002-11-01

    During secondary ion mass spectrometry (SIMS) analyses of organophosphorous compounds adsorbed onto soils, the measured anion signals were lower than expected and it was hypothesized that the low signals could be due to sample charging. An electron flood gun was designed, constructed and used to investigate sample charging of these and other sample types. The flood gun was integrated into one end cap of an ion trap secondary ion mass spectrometer and the design maintained the geometry of the self-stabilizing extraction optics used in this instrument. The SIMION ion optics program was used to design the flood gun, and experimental results agreed with the predicted performance. Results showed the low anion signals from the soils were not due to sample charging. Other insulating and conducting samples were tested using both a ReO4- and a Cs+ primary ion beam. The proximity of the sample and electron source to the ion trap aperture resulted in generation of background ions in the ion trap via electron impact (EI) ionization during the period the electron gun was flooding the sample region. When using the electron gun with the ReO4- primary beam, the required electron current was low enough that the EI background was negligible; however, the high electron flood current required with the Cs+ beam produced background EI ions that degraded the quality of the mass spectra. The consequences of the EI produced cations will have to be evaluated on a sample-by-sample basis when using electron flood. It was shown that the electron flood gun could be intentionally operated to produce EI spectra in this instrument. This offers the opportunity to measure, nearly simultaneously, species evaporating from a sample, via EI, and species bound to the surface, via SIMS.

  11. Microfabricated ion trap array

    DOE Patents [OSTI]

    Blain, Matthew G. (Albuquerque, NM); Fleming, James G. (Albuquerque, NM)

    2006-12-26

    A microfabricated ion trap array, comprising a plurality of ion traps having an inner radius of order one micron, can be fabricated using surface micromachining techniques and materials known to the integrated circuits manufacturing and microelectromechanical systems industries. Micromachining methods enable batch fabrication, reduced manufacturing costs, dimensional and positional precision, and monolithic integration of massive arrays of ion traps with microscale ion generation and detection devices. Massive arraying enables the microscale ion traps to retain the resolution, sensitivity, and mass range advantages necessary for high chemical selectivity. The reduced electrode voltage enables integration of the microfabricated ion trap array with on-chip circuit-based rf operation and detection electronics (i.e., cell phone electronics). Therefore, the full performance advantages of the microfabricated ion trap array can be realized in truly field portable, handheld microanalysis systems.

  12. Microfabricated cylindrical ion trap

    DOE Patents [OSTI]

    Blain, Matthew G.

    2005-03-22

    A microscale cylindrical ion trap, having an inner radius of order one micron, can be fabricated using surface micromachining techniques and materials known to the integrated circuits manufacturing and microelectromechanical systems industries. Micromachining methods enable batch fabrication, reduced manufacturing costs, dimensional and positional precision, and monolithic integration of massive arrays of ion traps with microscale ion generation and detection devices. Massive arraying enables the microscale cylindrical ion trap to retain the resolution, sensitivity, and mass range advantages necessary for high chemical selectivity. The microscale CIT has a reduced ion mean free path, allowing operation at higher pressures with less expensive and less bulky vacuum pumping system, and with lower battery power than conventional- and miniature-sized ion traps. The reduced electrode voltage enables integration of the microscale cylindrical ion trap with on-chip integrated circuit-based rf operation and detection electronics (i.e., cell phone electronics). Therefore, the full performance advantages of microscale cylindrical ion traps can be realized in truly field portable, handheld microanalysis systems.

  13. Microfabricated linear Paul-Straubel ion trap

    DOE Patents [OSTI]

    Mangan, Michael A. (Albuquerque, NM); Blain, Matthew G. (Albuquerque, NM); Tigges, Chris P. (Albuquerque, NM); Linker, Kevin L. (Albuquerque, NM)

    2011-04-19

    An array of microfabricated linear Paul-Straubel ion traps can be used for mass spectrometric applications. Each ion trap comprises two parallel inner RF electrodes and two parallel outer DC control electrodes symmetric about a central trap axis and suspended over an opening in a substrate. Neighboring ion traps in the array can share a common outer DC control electrode. The ions confined transversely by an RF quadrupole electric field potential well on the ion trap axis. The array can trap a wide array of ions.

  14. Ion funnel ion trap and process

    DOE Patents [OSTI]

    Belov, Mikhail E [Richland, WA; Ibrahim, Yehia M [Richland, WA; Clowers, Biran H [West Richland, WA; Prior, David C [Hermiston, OR; Smith, Richard D [Richland, WA

    2011-02-15

    An ion funnel trap is described that includes a inlet portion, a trapping portion, and a outlet portion that couples, in normal operation, with an ion funnel. The ion trap operates efficiently at a pressure of .about.1 Torr and provides for: 1) removal of low mass-to-charge (m/z) ion species, 2) ion accumulation efficiency of up to 80%, 3) charge capacity of .about.10,000,000 elementary charges, 4) ion ejection time of 40 to 200 .mu.s, and 5) optimized variable ion accumulation times. Ion accumulation with low concentration peptide mixtures has shown an increase in analyte signal-to-noise ratios (SNR) of a factor of 30, and a greater than 10-fold improvement in SNR for multiply charged analytes.

  15. Detection of Chemical/Biological Agents and Stimulants using Quadrupole Ion Trap Mass Spectrometry

    SciTech Connect (OSTI)

    Harmon, S.H.; Hart, K.J.; Vass, A.A.; Wise, M.B.; Wolf, D.A.

    1999-06-14

    Detection of Chemical/Biological Agents and Simulants A new detector for chemical and biological agents is being developed for the U. S. Army under the Chemical and Biological Mass Spectrometer Block II program. The CBMS Block II is designed to optimize detection of both chemical and biological agents through the use of direct sampling inlets [I], a multi- ported sampling valve and a turbo- based vacuum system to support chemical ionization. Unit mass resolution using air as the buffer gas [2] has been obtained using this design. Software to control the instrument and to analyze the data generated from the instrument has also been newly developed. Detection of chemical agents can be accomplished. using the CBMS Block II design via one of two inlets - a l/ I 6'' stainless steel sample line -Chemical Warfare Air (CW Air) or a ground probe with enclosed capillary currently in use by the US Army - CW Ground. The Block II design is capable of both electron ionization and chemical ionization. Ethanol is being used as the Cl reagent based on a study indicating best performance for the Biological Warfare (BW) detection task (31). Data showing good signal to noise for 500 pg of methyl salicylate injected into the CW Air inlet, 50 ng of dimethylmethylphosphonate exposed to the CW Ground probe and 5 ng of methyl stearate analyzed using the pyrolyzer inlet were presented. Biological agents are sampled using a ''bio-concentrator'' unit that is designed to concentrate particles in the low micron range. Particles are collected in the bottom of a quartz pyrolyzer tube. An automated injector is being developed to deliver approximately 2 pL of a methylating reagent, tetramethylamonium- hydroxide to 'the collected particles. Pyrolysis occurs by rapid heating to ca. 55OOC. Biological agents are then characterized by their fatty acid methyl ester profiles and by other biomarkers. A library of ETOH- Cl/ pyrolysis MS data of microorganisms used for a recently published study [3] has been expanded with additional bacteria and fungi. These spectra were acquired on a Finnigan Magnum ion trap using helium buffer gas. A new database of Cl spectra of microorganisms is planned using the CBMS Block II instrument and air as the buffer gas. Using the current database, the fatty acid composition of the organisms was compared using the percentage of the ion current attributable to fatty acids. The data presented suggest promising rules for discrimination of these organisms. Strain, growth media and vegetative state do contribute to some of the distributions observed in the data. However, the data distributions observed in the current study only reflect our experience to date and do not fully represent the variability that might be expected in practice: Acquisition of MS/ MS spectra has begun (using He and air buffer gas) of the protonated molecular ion of a variety of fatty acids and for a number of ions nominally assigned as fatty acids from microorganisms. These spectra will be used to help verify fatty acid .

  16. Asymmetric ion trap

    DOE Patents [OSTI]

    Barlow, S.E.; Alexander, M.L.; Follansbee, J.C.

    1997-12-02

    An ion trap having two end cap electrodes disposed asymmetrically about a center of a ring electrode is disclosed. The inner surface of the end cap electrodes are conformed to an asymmetric pair of equipotential lines of the harmonic formed by the application of voltages to the electrodes. The asymmetry of the end cap electrodes allows ejection of charged species through the closer of the two electrodes which in turn allows for simultaneously detecting anions and cations expelled from the ion trap through the use of two detectors charged with opposite polarity. 4 figs.

  17. Asymmetric ion trap

    DOE Patents [OSTI]

    Barlow, Stephan E. (Richland, WA); Alexander, Michael L. (Richland, WA); Follansbee, James C. (Pasco, WA)

    1997-01-01

    An ion trap having two end cap electrodes disposed asymmetrically about a center of a ring electrode. The inner surface of the end cap electrodes are conformed to an asymmetric pair of equipotential lines of the harmonic formed by the application of voltages to the electrodes. The asymmetry of the end cap electrodes allows ejection of charged species through the closer of the two electrodes which in turn allows for simultaneously detecting anions and cations expelled from the ion trap through the use of two detectors charged with opposite polarity.

  18. Fundamental Electroweak Studies using Trapped Ions & Atoms

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    collaboration performs fundamental electroweak studies on trapped ions & atoms. We use neutral atom and ion trapping techniques at radioactive ion beam facilities here and...

  19. Action spectroscopy of SrCl{sup +} using an integrated ion trap time-of-flight mass spectrometer

    SciTech Connect (OSTI)

    Puri, Prateek Schowalter, Steven J.; Hudson, Eric R.; Kotochigova, Svetlana; Petrov, Alexander

    2014-07-07

    The photodissociation cross-section of SrCl{sup +} is measured in the spectral range of 36?00046?000 cm{sup ?1} using a modular time-of-flight mass spectrometer (TOF-MS). By irradiating a sample of trapped SrCl{sup +} molecular ions with a pulsed dye laser, X{sup 1}?{sup +} state molecular ions are electronically excited to the repulsive wall of the A{sup 1}? state, resulting in dissociation. Using the TOF-MS, the product fragments are detected and the photodissociation cross-section is determined for a broad range of photon energies. Detailed ab initio calculations of the SrCl{sup +} molecular potentials and spectroscopic constants are also performed and are found to be in good agreement with experiment. The spectroscopic constants for SrCl{sup +} are also compared to those of another alkaline earth halogen, BaCl{sup +}, in order to highlight structural differences between the two molecular ions. This work represents the first spectroscopy and ab initio calculations of SrCl{sup +}.

  20. Ion temperature gradient driven turbulence with strong trapped ion

    Office of Scientific and Technical Information (OSTI)

    resonance (Journal Article) | SciTech Connect Ion temperature gradient driven turbulence with strong trapped ion resonance Citation Details In-Document Search Title: Ion temperature gradient driven turbulence with strong trapped ion resonance A theory to describe basic characterization of ion temperature gradient driven turbulence with strong trapped ion resonance is presented. The role of trapped ion granulations, clusters of trapped ions correlated by precession resonance, is the focus.

  1. Highly charged ion secondary ion mass spectroscopy

    DOE Patents [OSTI]

    Hamza, Alex V.; Schenkel, Thomas; Barnes, Alan V.; Schneider, Dieter H.

    2001-01-01

    A secondary ion mass spectrometer using slow, highly charged ions produced in an electron beam ion trap permits ultra-sensitive surface analysis and high spatial resolution simultaneously. The spectrometer comprises an ion source producing a primary ion beam of highly charged ions that are directed at a target surface, a mass analyzer, and a microchannel plate detector of secondary ions that are sputtered from the target surface after interaction with the primary beam. The unusually high secondary ion yield permits the use of coincidence counting, in which the secondary ion stops are detected in coincidence with a particular secondary ion. The association of specific molecular species can be correlated. The unique multiple secondary nature of the highly charged ion interaction enables this new analytical technique.

  2. Quantum chaos of an ion trapped in a linear ion trap (Journal Article) |

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect Quantum chaos of an ion trapped in a linear ion trap Citation Details In-Document Search Title: Quantum chaos of an ion trapped in a linear ion trap We describe the transition to quantum chaos of an ion trapped in a linear ion trap and interacting with two laser fields. Under the conditions of adiabatic illumination of the upper level of the ion, and when the frequencies of the two laser beams are slightly different, the system is reduced to a quantum linear oscillator

  3. Ion traps fabricated in a CMOS foundry

    SciTech Connect (OSTI)

    Mehta, K. K.; Ram, R. J.; Eltony, A. M.; Chuang, I. L.; Bruzewicz, C. D.; Sage, J. M. Chiaverini, J.

    2014-07-28

    We demonstrate trapping in a surface-electrode ion trap fabricated in a 90-nm CMOS (complementary metal-oxide-semiconductor) foundry process utilizing the top metal layer of the process for the trap electrodes. The process includes doped active regions and metal interconnect layers, allowing for co-fabrication of standard CMOS circuitry as well as devices for optical control and measurement. With one of the interconnect layers defining a ground plane between the trap electrode layer and the p-type doped silicon substrate, ion loading is robust and trapping is stable. We measure a motional heating rate comparable to those seen in surface-electrode traps of similar size. This demonstration of scalable quantum computing hardware utilizing a commercial CMOS process opens the door to integration and co-fabrication of electronics and photonics for large-scale quantum processing in trapped-ion arrays.

  4. Ion Trap Array-Based Systems And Methods For Chemical Analysis

    DOE Patents [OSTI]

    Whitten, William B [Oak Ridge, TN; Ramsey, J Michael [Knoxville, TN

    2005-08-23

    An ion trap-based system for chemical analysis includes an ion trap array. The ion trap array includes a plurality of ion traps arranged in a 2-dimensional array for initially confining ions. Each of the ion traps comprise a central electrode having an aperture, a first and second insulator each having an aperture sandwiching the central electrode, and first and second end cap electrodes each having an aperture sandwiching the first and second insulator. A structure for simultaneously directing a plurality of different species of ions out from the ion traps is provided. A spectrometer including a detector receives and identifies the ions. The trap array can be used with spectrometers including time-of-flight mass spectrometers and ion mobility spectrometers.

  5. Subcellular-level resolution MALDI-MS imaging of maize leaf metabolites by MALDI-linear ion trap-Orbitrap mass spectrometer

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Korte, Andrew R.; Yandeau-Nelson, Marna D.; Nikolau, Basil J.; Lee, Young Jin

    2015-01-25

    A significant limiting factor in achieving high spatial resolution for matrix-assisted laser desorption ionization-mass spectrometry (MALDI-MS) imaging is the size of the laser spot at the sample surface. We present modifications to the beam-delivery optics of a commercial MALDI-linear ion trap-Orbitrap instrument, incorporating an external Nd:YAG laser, beam-shaping optics, and an aspheric focusing lens, to reduce the minimum laser spot size from ~50 μm for the commercial configuration down to ~9 μm for the modified configuration. This improved system was applied for MALDI-MS imaging of cross sections of juvenile maize leaves at 5-μm spatial resolution using an oversampling method. Theremore » are a variety of different metabolites including amino acids, glycerolipids, and defense-related compounds were imaged at a spatial resolution well below the size of a single cell. Such images provide unprecedented insights into the metabolism associated with the different tissue types of the maize leaf, which is known to asymmetrically distribute the reactions of C4 photosynthesis among the mesophyll and bundle sheath cell types. The metabolite ion images correlate with the optical images that reveal the structures of the different tissues, and previously known and newly revealed asymmetric metabolic features are observed.« less

  6. Subcellular-level resolution MALDI-MS imaging of maize leaf metabolites by MALDI-linear ion trap-Orbitrap mass spectrometer

    SciTech Connect (OSTI)

    Korte, Andrew R.; Yandeau-Nelson, Marna D.; Nikolau, Basil J.; Lee, Young Jin

    2015-01-25

    A significant limiting factor in achieving high spatial resolution for matrix-assisted laser desorption ionization-mass spectrometry (MALDI-MS) imaging is the size of the laser spot at the sample surface. We present modifications to the beam-delivery optics of a commercial MALDI-linear ion trap-Orbitrap instrument, incorporating an external Nd:YAG laser, beam-shaping optics, and an aspheric focusing lens, to reduce the minimum laser spot size from ~50 ?m for the commercial configuration down to ~9 ?m for the modified configuration. This improved system was applied for MALDI-MS imaging of cross sections of juvenile maize leaves at 5-?m spatial resolution using an oversampling method. There are a variety of different metabolites including amino acids, glycerolipids, and defense-related compounds were imaged at a spatial resolution well below the size of a single cell. Such images provide unprecedented insights into the metabolism associated with the different tissue types of the maize leaf, which is known to asymmetrically distribute the reactions of C4 photosynthesis among the mesophyll and bundle sheath cell types. The metabolite ion images correlate with the optical images that reveal the structures of the different tissues, and previously known and newly revealed asymmetric metabolic features are observed.

  7. Study of Ion Cooling and Ejection from Two Stage Linear Quadrupole Ion Trap consisted of RFQ ion guides

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ion Cooling and Ejection from Two Stage Linear Quadrupole Ion Trap consisted of RFQ ion guides Kozlovskiy V.I., Filatov V. V., Shchepunov (UNIRIB, O.R.A.U. Oak Ridge, TN, USA) V. A., Brusov V. S., Pikhtelev A. R., Zelenov V. V. Introduction The primary objective of this work concerns linear quadrupole ion traps, which are commonly used to interface a continuous ion beam from an external source with a mass analyzer, requiring bunched or pulsed beams. We assume that the ions prepared for mass

  8. Ion temperature gradient driven turbulence with strong trapped...

    Office of Scientific and Technical Information (OSTI)

    Ion temperature gradient driven turbulence with strong trapped ion resonance Citation Details In-Document Search Title: Ion temperature gradient driven turbulence with strong ...

  9. Electron beam ion source and electron beam ion trap (invited)

    SciTech Connect (OSTI)

    Becker, Reinard [Scientific Software Service, Kapellenweg 2a, D-63571 Gelnhausen (Germany); Kester, Oliver [National Superconducting Cyclotron Laboratory, Michigan State University, East Lansing, Michigan 48824 (United States)

    2010-02-15

    The electron beam ion source (EBIS) and its trap variant [electron beam ion trap (EBIT)] celebrated their 40th and 20th anniversary, respectively, at the EBIS/T Symposium 2007 in Heidelberg. These technologically challenging sources of highly charged ions have seen a broad development in many countries over the last decades. In contrast to most other ion sources the recipe of improvement was not ''sorcery'' but a clear understanding of the physical laws and obeying the technological constraints. This review will report important achievements of the past as well as promising developments in the future.

  10. Ball-grid array architecture for microfabricated ion traps

    SciTech Connect (OSTI)

    Guise, Nicholas D. Fallek, Spencer D.; Stevens, Kelly E.; Brown, K. R.; Volin, Curtis; Harter, Alexa W.; Amini, Jason M.; Higashi, Robert E.; Lu, Son Thai; Chanhvongsak, Helen M.; Nguyen, Thi A.; Marcus, Matthew S.; Ohnstein, Thomas R.; Youngner, Daniel W.

    2015-05-07

    State-of-the-art microfabricated ion traps for quantum information research are approaching nearly one hundred control electrodes. We report here on the development and testing of a new architecture for microfabricated ion traps, built around ball-grid array (BGA) connections, that is suitable for increasingly complex trap designs. In the BGA trap, through-substrate vias bring electrical signals from the back side of the trap die to the surface trap structure on the top side. Gold-ball bump bonds connect the back side of the trap die to an interposer for signal routing from the carrier. Trench capacitors fabricated into the trap die replace area-intensive surface or edge capacitors. Wirebonds in the BGA architecture are moved to the interposer. These last two features allow the trap die to be reduced to only the area required to produce trapping fields. The smaller trap dimensions allow tight focusing of an addressing laser beam for fast single-qubit rotations. Performance of the BGA trap as characterized with {sup 40}Ca{sup +} ions is comparable to previous surface-electrode traps in terms of ion heating rate, mode frequency stability, and storage lifetime. We demonstrate two-qubit entanglement operations with {sup 171}Yb{sup +} ions in a second BGA trap.

  11. Off-resonance energy absorption in a linear Paul trap due to mass selective resonant quenching

    SciTech Connect (OSTI)

    Sivarajah, I.; Goodman, D. S.; Wells, J. E.; Smith, W. W.; Narducci, F. A.

    2013-11-15

    Linear Paul traps (LPT) are used in many experimental studies such as mass spectrometry, atom-ion collisions, and ion-molecule reactions. Mass selective resonant quenching (MSRQ) is implemented in LPT either to identify a charged particle's mass or to remove unwanted ions from a controlled experimental environment. In the latter case, MSRQ can introduce undesired heating to co-trapped ions of different mass, whose secular motion is off resonance with the quenching ac field, which we call off-resonance energy absorption (OREA). We present simulations and experimental evidence that show that the OREA increases exponentially with the number of ions loaded into the trap and with the amplitude of the off-resonance external ac field.

  12. Quantum chaos of an ion trapped in a linear ion trap

    SciTech Connect (OSTI)

    Berman, Gennady P. [Theoretical Division T-13, and CNLS, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States)] [Theoretical Division T-13, and CNLS, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); James, Daniel F. V. [Theoretical Division T-4, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States)] [Theoretical Division T-4, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Kamenev, Dimitri I. [Theoretical Division T-13, and CNLS, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States) [Theoretical Division T-13, and CNLS, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Nizhny Novgorod State University, Nizhny Novgorod, 603600, Russia (Russian Federation)

    2000-06-01

    We describe the transition to quantum chaos of an ion trapped in a linear ion trap and interacting with two laser fields. Under the conditions of adiabatic illumination of the upper level of the ion, and when the frequencies of the two laser beams are slightly different, the system is reduced to a quantum linear oscillator interacting with a monochromatic wave. The property of localization over the quantum resonance cells is proposed to exploit in order to facilitate the process of measurement of the probability distribution of an ion on the vibrational levels. In the regime of strong chaos the time-averaged values of the energy and dispersion of energy are computed and compared with the corresponding classical quantities for different values of the perturbation amplitude. In the exact resonance case, the classical analog of the system possesses an infinite inhomogeneous stochastic web. We analyze the quantum dynamics inside the inhomogeneous web. It is shown that the quantum system mimics on average the dynamics of the corresponding classical system. Formation of the quantum resonance cells is illustrated in the case of a finite detuning from the exact resonance, and under increasing of the wave amplitude. The parameters of the model and the initial conditions are close to the real physical situation which can be realized in the system of cold trapped ion perturbed by two lasers fields with close frequencies. (c) 2000 American Institute of Physics.

  13. Ball-grid array architecture for microfabricated ion traps (Journal...

    Office of Scientific and Technical Information (OSTI)

    Gold-ball bump bonds connect the back side of the trap die to an interposer for signal ... IONS; CAPACITORS; COMPARATIVE EVALUATIONS; GOLD; HEATING RATE; LASER RADIATION; QUANTUM ...

  14. Electrostatic particle trap for ion beam sputter deposition

    DOE Patents [OSTI]

    Vernon, Stephen P. (Pleasanton, CA); Burkhart, Scott C. (Livermore, CA)

    2002-01-01

    A method and apparatus for the interception and trapping of or reflection of charged particulate matter generated in ion beam sputter deposition. The apparatus involves an electrostatic particle trap which generates electrostatic fields in the vicinity of the substrate on which target material is being deposited. The electrostatic particle trap consists of an array of electrode surfaces, each maintained at an electrostatic potential, and with their surfaces parallel or perpendicular to the surface of the substrate. The method involves interception and trapping of or reflection of charged particles achieved by generating electrostatic fields in the vicinity of the substrate, and configuring the fields to force the charged particulate material away from the substrate. The electrostatic charged particle trap enables prevention of charged particles from being deposited on the substrate thereby enabling the deposition of extremely low defect density films, such as required for reflective masks of an extreme ultraviolet lithography (EUVL) system.

  15. Ion Trapping, Storage, and Ejection in Structures for Lossless Ion Manipulations

    SciTech Connect (OSTI)

    Zhang, Xinyu; Garimella, Venkata BS; Prost, Spencer A.; Webb, Ian K.; Chen, Tsung-Chi; Tang, Keqi; Tolmachev, Aleksey V.; Norheim, Randolph V.; Baker, Erin Shammel; Anderson, Gordon A.; Ibrahim, Yehia M.; Smith, Richard D.

    2015-06-16

    A structure for lossless ion manipulation (SLIM) module was constructed with electrode arrays patterned on a pair of parallel printed circuit boards (PCB) separated by 5 mm and utilized to investigate capabilities for ion trapping at 4 Torr. Positive ions were confined by application of RF having alternating phases on a series of inner rung electrodes and by positive DC potentials on surrounding guard electrodes on each PCB. An axial DC field was also introduced by stepwise varying the DC potential of the inner rung electrodes so as to control the ion transport and accumulation inside the ion trap. We show that ions could be trapped and accumulated with 100% efficiency, stored for at least 5 hours with no losses, and could be rapidly ejected from the SLIM trap.

  16. The uses of electron beam ion traps in the study of highly charged ions

    SciTech Connect (OSTI)

    Knapp, D.

    1994-11-02

    The Electron Beam Ion Trap (EBIT) is a relatively new tool for the study of highly charged ions. Its development has led to a variety of new experimental opportunities; measurements have been performed with EBITs using techniques impossible with conventional ion sources or storage rings. In this paper, I will highlight the various experimental techniques we have developed and the results we have obtained using the EBIT and higher-energy Super-EBIT built at the Lawrence Livermore National Laboratory. The EBIT employs a high-current-density electron beam to trap, ionize, and excite a population of ions. The ions can be studied in situ or extracted from the trap for external experiments. The trapped ions form an ionization-state equilibrium determined by the relative ionization and recombination rates. Ions of several different elements may simultaneously be present in the trap. The ions are nearly at rest, and, for most systems, all in their ground-state configurations. The electron-ion interaction energy has a narrow distribution and can be varied over a wide range. We have used the EBIT devices for the measurement of electron-ion interactions, ion structure, ion-surface interactions, and the behavior of low-density plasmas.

  17. First Use of High Charge States for Mass Measurements of Short-Lived Nuclides in a Penning Trap

    SciTech Connect (OSTI)

    Ettenauer, S.; Gallant, A. T.; Dilling, J.; Simon, M. C.; Chaudhuri, A.; Mane, E.; Delheij, P.; Pearson, M. R.; Brunner, T.; Chowdhury, U.; Simon, V. V.; Brodeur, M.; Andreoiu, C.; Audi, G.; Lopez-Urrutia, J. R. Crespo; Ullrich, J.; Gwinner, G.; Lapierre, A.; Lunney, D.; Ringle, R.

    2011-12-30

    Penning trap mass measurements of short-lived nuclides have been performed for the first time with highly charged ions, using the TITAN facility at TRIUMF. Compared to singly charged ions, this provides an improvement in experimental precision that scales with the charge state q. Neutron-deficient Rb isotopes have been charge bred in an electron beam ion trap to q=8-12+ prior to injection into the Penning trap. In combination with the Ramsey excitation scheme, this unique setup creating low energy, highly charged ions at a radioactive beam facility opens the door to unrivaled precision with gains of 1-2 orders of magnitude. The method is particularly suited for short-lived nuclides such as the superallowed {beta} emitter {sup 74}Rb (T{sub 1/2}=65 ms). The determination of its atomic mass and an improved Q{sub EC} value are presented.

  18. Advanced quadrupole ion trap instrumentation for low level vehicle emissions measurements. CRADA final report for number ORNL93-0238

    SciTech Connect (OSTI)

    McLuckey, S.A.; Buchanan, M.V.; Asano, K.G.; Hart, K.J.; Goeringer, D.E.; Dearth, M.A.

    1997-09-01

    Quadrupole ion trap mass spectrometry has been evaluated for its potential use in vehicle emissions measurements in vehicle test facilities as an analyzer for the top 15 compounds contributing to smog generation. A variety of ionization methods were explored including ion trap in situ chemical ionization, atmospheric sampling glow discharge ionization, and nitric oxide chemical ionization in a glow discharge ionization source coupled with anion trap mass spectrometer. Emphasis was placed on the determination of hydrocarbons and oxygenated hydrocarbons at parts per million to parts per billion levels. Ion trap in situ water chemical ionization and atmospheric sampling glow discharge ionization were both shown to be amenable to the analysis of arenes, alcohols, aldehydes and, to some degree, alkenes. Atmospheric sampling glow discharge also generated molecular ions of methyl-t-butyl ether (MTBE). Neither of these ionization methods, however, were found to generate diagnostic ions for the alkanes. Nitric oxide chemical ionization, on the other hand, was found to yield diagnostic ions for alkanes, alkenes, arenes, alcohols, aldehydes, and MTBE. The ability to measure a variety of hydrocarbons present at roughly 15 parts per billion at measurement rates of 3 Hz was demonstrated. These results have demonstrated that the ion trap has an excellent combination of sensitivity, specificity, speed, and flexibility with respect to the technical requirements of the top 15 analyzer.

  19. Ionization of polarized 3He+ ions in EBIS trap with slanted electrostatic mirror.

    SciTech Connect (OSTI)

    Pikin,A.; Zelenski, A.; Kponou, A.; Alessi, J.; Beebe, E.; Prelee, K.; Raparia, D.

    2007-09-10

    Methods of producing the nuclear polarized {sup 3}He{sup +} ions and their ionization to {sup 3}H{sup ++} in ion trap of the electron Beam Ion Source (EBIS) are discussed. Computer simulations show that injection and accumulation of {sup 3}He{sup +} ions in the EBIS trap with slanted electrostatic mirror can be very effective for injection times longer than the ion traversal time through the trap.

  20. DYNAMICAL STABILITY AND QUANTUM CHAOS OF IONS IN A LINEAR TRAP (1999002ER).

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (Technical Report) | SciTech Connect Technical Report: DYNAMICAL STABILITY AND QUANTUM CHAOS OF IONS IN A LINEAR TRAP (1999002ER). Citation Details In-Document Search Title: DYNAMICAL STABILITY AND QUANTUM CHAOS OF IONS IN A LINEAR TRAP (1999002ER). The realization of a paradigm chaotic system, namely the harmonically driven oscillator, in the quantum domain using cold trapped ions driven by lasers is theoretically investigated. The simplest characteristics of regular and chaotic dynamics

  1. Scalable, High-Speed Measurement-Based Quantum Computer Using Trapped Ions

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect Scalable, High-Speed Measurement-Based Quantum Computer Using Trapped Ions Citation Details In-Document Search Title: Scalable, High-Speed Measurement-Based Quantum Computer Using Trapped Ions We describe a scalable, high-speed, and robust architecture for measurement-based quantum computing with trapped ions. Measurement-based architectures offer a way to speed up operation of a quantum computer significantly by parallelizing the slow entangling

  2. Collision Processes of Highly Charged Ions with Electrons Studied with an Electron Beam Ion Trap

    SciTech Connect (OSTI)

    Nakamura, Nobuyuki; Watanabe, Tsutomu; Ohtani, Shunsuke; Kavanagh, Anthony P.; Currell, Fred J.; Watanabe, Hirofumi; Sakaue, Hiroyuki A.; Kato, Daiji; Li Yueming; Tong Xiaoming

    2009-09-10

    The electron beam ion trap in Tokyo (Tokyo-EBIT)is suitable for studying relativistic effects in the collisions of highly charged heavy ions with electrons because it can produce and trap very highly charged heavy ions which interact with a mono-energetic and unidirectional relativistic electron beam with an energy of up to 200 keV. Recently, we have been studying resonant processes in ionization and recombination by measuring the charge abundance inside the EBIT at the equilibrium. The abundance ratio between adjacent charge states varies slowly with the electron energy when there is no resonant process. However, when the electron energy coincides with the resonant energy at which ionization or recombination is enhanced, the abundance ratio can drastically change. Thus, the resonant processes can be studied by measuring the abundance ratio between adjacent ions as a function of electron beam energy. In this talk, recent progress for heavy ions with very high charge states up to He-like Bi{sup 81+}, is presented. For such ions, relativistic effects significantly affect the resonant processes. For example, the generalized Breit interaction (GBI) effect, which treats the retardation in the exchange of single virtual photon between the free and orbital electrons, has been clearly observed in the DR resonant strength in Li-like Bi{sup 80+}. Recently we have also found that the GBI effect plays an important role in the interference between non-resonant and resonant recombinations. Experimental results are presented in comparison with theoretical calculations.

  3. Extending Penning trap mass measurements with SHIPTRAP to the heaviest elements

    SciTech Connect (OSTI)

    Block, M.; Ackermann, D.; Herfurth, F.; Hofmann, S.; Blaum, K.; Droese, C.; Marx, G.; Schweikhard, L.; Duellmann, Ch. E.; Eibach, M.; Eliseev, S.; Haettner, E.; Plass, W. R.; Scheidenberger, C.; Hessberger, F. P.; Ramirez, E. Minaya; Nesterenko, D.; and others

    2013-03-19

    Penning-trap mass spectrometry of radionuclides provides accurate mass values and absolute binding energies. Such mass measurements are sensitive indicators of the nuclear structure evolution far away from stability. Recently, direct mass measurements have been extended to the heavy elements nobelium (Z=102) and lawrencium (Z=103) with the Penning-trap mass spectrometer SHIPTRAP. The results probe nuclear shell effects at N=152. New developments will pave the way to access even heavier nuclides.

  4. Gated charged-particle trap

    DOE Patents [OSTI]

    Benner, W. Henry (Danville, CA)

    1999-01-01

    The design and operation of a new type of charged-particle trap provides simultaneous measurements of mass, charge, and velocity of large electrospray ions. The trap consists of a detector tube mounted between two sets of center-bored trapping plates. Voltages applied to the trapping plates define symmetrically-opposing potential valleys which guide axially-injected ions to cycle back and forth through the charge-detection tube. A low noise charge-sensitive amplifier, connected to the tube, reproduces the image charge of individual ions as they pass through the detector tube. Ion mass is calculated from measurement of ion charge and velocity following each passage through the detector.

  5. Radial transport of energetic ions in the presence of trapped electron mode turbulence

    SciTech Connect (OSTI)

    Chowdhury, J.; Wang, W.; Ethier, S.; Manickam, J. [Princeton Plasma Physics Laboratory, Princeton, New Jersey 08543 (United States); Ganesh, R. [Institute for Plasma Research, Bhat, Gandhinagar 382428 (India)

    2011-11-15

    The nature of transport of hot ions is studied in the presence of microturbulence generated by the trapped electron mode in a Tokamak using massively parallel, first principle based global nonlinear gyrokinetic simulation, and with the help of a passive tracer method. Passing and trapped hot ions are observed to exhibit inverse and inverse square scaling with energy, while those with isotropic pitch distribution are found to exhibit inverse dependence on energy. For all types of hot ions, namely, isotropic, passing, and trapped, the radial transport appears to be subdiffusive for the parameters considered.

  6. Assembling a ring-shaped crystal in a microfabricated surface ion trap

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Stick, Daniel Lynn; Univ. of New Mexico, Albuquerque, NM; Tabakov, Boyan; Univ. of New Mexico, Albuquerque, NM; Benito, Francisco; Blain, Matthew; Clark, Craig R.; Clark, Susan; Haltli, Raymond A.; Maunz, Peter; et al

    2015-09-01

    We report on experiments with a microfabricated surface trap designed for confining a chain of ions in a ring. Uniform ion separation over most of the ring is achieved with a rotationally symmetric design and by measuring and suppressing undesired electric fields. After reducing stray fields, the ions are confined primarily by a radio-frequency pseudopotential and their mutual Coulomb repulsion. As a result, approximately 400 40Ca+ ions with an average separation of 9 μm comprise the ion crystal.

  7. Coupling of ion temperature gradient and trapped electron modes in the presence of impurities in tokamak plasmas

    SciTech Connect (OSTI)

    Du, Huarong; Wang, Zheng-Xiong, E-mail: zxwang@dlut.edu.cn [MOE Key Laboratory of Materials Modification by Beams, School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116024 (China)] [MOE Key Laboratory of Materials Modification by Beams, School of Physics and Optoelectronic Technology, Dalian University of Technology, Dalian 116024 (China); Dong, J. Q. [Institute for Fusion Theory and Simulation, Zhejiang University, Hangzhou 310027 (China) [Institute for Fusion Theory and Simulation, Zhejiang University, Hangzhou 310027 (China); Southwestern Institute of Physics, Chengdu 610041 (China); Liu, S. F. [School of Physics, Nankai University, Tianjin 300071 (China)] [School of Physics, Nankai University, Tianjin 300071 (China)

    2014-05-15

    The coupling of ion temperature gradient (ITG or ?{sub i}) mode and trapped electron mode (TEM) in the presence of impurity ions is numerically investigated in toroidal collisionless plasmas, using the gyrokinetic integral eigenmode equation. A framework for excitations of the ITG modes and TEMs with respect to their driving sources is formulated first, and then the roles of impurity ions played in are analyzed comprehensively. In particular, the characteristics of the ITG and TEM instabilities in the presence of impurity ions are emphasized for both strong and weak coupling (hybrid and coexistent) cases. It is found that the impurity ions with inwardly (outwardly) peaked density profiles have stabilizing (destabilizing) effects on the hybrid (namely the TE-ITG) modes in consistence with previous works. A new finding of this work is that the impurity ions have stabilizing effects on TEMs in small ?{sub i} (?{sub i}?1) regime regardless of peaking directions of their density profiles whereas the impurity ions with density gradient L{sub ez}=L{sub ne}/L{sub nz}>1 (L{sub ez}<1) destabilize (stabilize) the TEMs in large ?{sub i} (?{sub i}?1) regime. In addition, the dependences of the growth rate, real frequency, eigenmode structure, and wave spectrum on charge concentration, charge number, and mass of impurity ions are analyzed in detail. The necessity for taking impurity ion effects on the features of turbulence into account in future transport experimental data analyses is also discussed.

  8. Assembling a ring-shaped crystal in a microfabricated surface ion trap

    SciTech Connect (OSTI)

    Stick, Daniel Lynn; Tabakov, Boyan; Benito, Francisco; Blain, Matthew; Clark, Craig R.; Clark, Susan; Haltli, Raymond A.; Maunz, Peter; Sterk, Jonathan D.; Tigges, Chris

    2015-09-01

    We report on experiments with a microfabricated surface trap designed for confining a chain of ions in a ring. Uniform ion separation over most of the ring is achieved with a rotationally symmetric design and by measuring and suppressing undesired electric fields. After reducing stray fields, the ions are confined primarily by a radio-frequency pseudopotential and their mutual Coulomb repulsion. As a result, approximately 400 40Ca+ ions with an average separation of 9 ?m comprise the ion crystal.

  9. Rare-earth neutral metal injection into an electron beam ion trap plasma

    SciTech Connect (OSTI)

    Magee, E. W., E-mail: magee1@llnl.gov; Beiersdorfer, P.; Brown, G. V. [Lawrence Livermore National Laboratory, Livermore, California 94550 (United States); Hell, N. [Lawrence Livermore National Laboratory, Livermore, California 94550 (United States); Dr. Remeis-Sternwarte and ECAP, Universitt Erlangen-Nrnberg, 96049 Bamberg (Germany)

    2014-11-15

    We have designed and implemented a neutral metal vapor injector on the SuperEBIT high-energy electron beam ion trap at the Lawrence Livermore National Laboratory. A horizontally directed vapor of a europium metal is created using a thermal evaporation technique. The metal vapor is then spatially collimated prior to injection into the trap. The source's form and quantity constraints are significantly reduced making plasmas out of metal with vapor pressures ?10{sup ?7} Torr at ?1000?C more obtainable. A long pulsed or constant feed metal vapor injection method adds new flexibility by varying the timing of injection and rate of material being introduced into the trap.

  10. High-precision Penning trap mass measurements for tests of the Standard Model

    SciTech Connect (OSTI)

    Blaum, Klaus; Eliseev, Sergey; Nagy, Szilard

    2010-08-04

    With the nowadays achievable accuracy in Penning trap mass spectrometry on short-lived exotic nuclides as well as stable atoms, precision fundamental tests can be performed, among them a test of the Standard Model, in particular with regard to the weak interaction, the CPT symmetry conservation, and the unitarity of the Cabibbo-Kobayashi-Maskawa quark mixing matrix. In addition, accurate mass values of specific nuclides are important for neutrino physics. The presently best tests of the Standard Model with high-precision Penning trap mass spectrometry will be reviewed.

  11. DYNAMICAL STABILITY AND QUANTUM CHAOS OF IONS IN A LINEAR TRAP (1999002ER).

    Office of Scientific and Technical Information (OSTI)

    (Technical Report) | SciTech Connect Technical Report: DYNAMICAL STABILITY AND QUANTUM CHAOS OF IONS IN A LINEAR TRAP (1999002ER). Citation Details In-Document Search Title: DYNAMICAL STABILITY AND QUANTUM CHAOS OF IONS IN A LINEAR TRAP (1999002ER). × You are accessing a document from the Department of Energy's (DOE) SciTech Connect. This site is a product of DOE's Office of Scientific and Technical Information (OSTI) and is provided as a public service. Visit OSTI to utilize additional

  12. Noise reduction in negative-ion quadrupole mass spectrometry

    DOE Patents [OSTI]

    Chastagner, P.

    1993-04-20

    A quadrupole mass spectrometer (QMS) system is described having an ion source, quadrupole mass filter, and ion collector/recorder system. A weak, transverse magnetic field and an electron collector are disposed between the quadrupole and ion collector. When operated in negative ion mode, the ion source produces a beam of primarily negatively-charged particles from a sample, including electrons as well as ions. The beam passes through the quadrupole and enters the magnetic field, where the electrons are deflected away from the beam path to the electron collector. The negative ions pass undeflected to the ion collector where they are detected and recorded as a mass spectrum.

  13. Dynamical stability and quantum chaos of ions in a linear trap

    SciTech Connect (OSTI)

    Berman, G. P. [Group T-13 and CNLS, University of California, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States)] [Group T-13 and CNLS, University of California, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); James, D. F. V. [Group T-4, University of California, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States)] [Group T-4, University of California, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Hughes, R. J. [Group P-23, University of California, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States)] [Group P-23, University of California, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Gulley, M. S. [Group P-25, University of California, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States)] [Group P-25, University of California, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Holzscheiter, M. H. [Group P-23, University of California, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States)] [Group P-23, University of California, Los Alamos National Laboratory, Los Alamos, New Mexico 87545 (United States); Lopez, G. V. [Departamento de Fisica, Universidad de Guadalajara, Corregidora 500, S.R. 44420, Guadalajara, Jalisco, (Mexico)] [Departamento de Fisica, Universidad de Guadalajara, Corregidora 500, S.R. 44420, Guadalajara, Jalisco, (Mexico)

    2000-02-01

    The realization of a paradigm chaotic system, namely, the harmonically driven oscillator, in the quantum domain using cold trapped ions driven by lasers is theoretically investigated. The simplest characteristics of regular and chaotic dynamics are calculated. The possibilities of experimental realization are discussed. (c) 2000 The American Physical Society.

  14. Compact mass spectrometer for plasma discharge ion analysis

    DOE Patents [OSTI]

    Tuszewski, M.G.

    1997-07-22

    A mass spectrometer and methods are disclosed for mass spectrometry which are useful in characterizing a plasma. This mass spectrometer for determining type and quantity of ions present in a plasma is simple, compact, and inexpensive. It accomplishes mass analysis in a single step, rather than the usual two-step process comprised of ion extraction followed by mass filtering. Ions are captured by a measuring element placed in a plasma and accelerated by a known applied voltage. Captured ions are bent into near-circular orbits by a magnetic field such that they strike a collector, producing an electric current. Ion orbits vary with applied voltage and proton mass ratio of the ions, so that ion species may be identified. Current flow provides an indication of quantity of ions striking the collector. 7 figs.

  15. Compact mass spectrometer for plasma discharge ion analysis

    DOE Patents [OSTI]

    Tuszewski, Michel G. (Los Alamos, NM)

    1997-01-01

    A mass spectrometer and methods for mass spectrometry which are useful in characterizing a plasma. This mass spectrometer for determining type and quantity of ions present in a plasma is simple, compact, and inexpensive. It accomplishes mass analysis in a single step, rather than the usual two-step process comprised of ion extraction followed by mass filtering. Ions are captured by a measuring element placed in a plasma and accelerated by a known applied voltage. Captured ions are bent into near-circular orbits by a magnetic field such that they strike a collector, producing an electric current. Ion orbits vary with applied voltage and proton mass ratio of the ions, so that ion species may be identified. Current flow provides an indication of quantity of ions striking the collector.

  16. Mass spectrometer and methods of increasing dispersion between ion beams

    DOE Patents [OSTI]

    Appelhans, Anthony D.; Olson, John E.; Delmore, James E.

    2006-01-10

    A mass spectrometer includes a magnetic sector configured to separate a plurality of ion beams, and an electrostatic sector configured to receive the plurality of ion beams from the magnetic sector and increase separation between the ion beams, the electrostatic sector being used as a dispersive element following magnetic separation of the plurality of ion beams. Other apparatus and methods are provided.

  17. Gated charged-particle trap

    DOE Patents [OSTI]

    Benner, W.H.

    1999-03-09

    The design and operation of a new type of charged-particle trap provides simultaneous measurements of mass, charge, and velocity of large electrospray ions. The trap consists of a detector tube mounted between two sets of center-bored trapping plates. Voltages applied to the trapping plates define symmetrically-opposing potential valleys which guide axially-injected ions to cycle back and forth through the charge-detection tube. A low noise charge-sensitive amplifier, connected to the tube, reproduces the image charge of individual ions as they pass through the detector tube. Ion mass is calculated from measurement of ion charge and velocity following each passage through the detector. 5 figs.

  18. Electron impact action spectroscopy of mass/charge selected macromolecular ions: Inner-shell excitation of ubiquitin protein

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Rankovic, Milos Lj.; Giuliani, Alexandre; Milosavljevic, Aleksandar R.

    2016-02-11

    In this study, we have performed inner-shell electron impact action spectroscopy of mass and charge selected macromolecular ions. For this purpose, we have coupled a focusing electron gun with a linear quadrupole ion trap mass spectrometer. This experiment represents a proof of principle that an energy-tunable electron beam can be used in combination with radio frequency traps as an activation method in tandem mass spectrometry (MS2) and allows performing action spectroscopy. Electron impact MS2 spectra of multiply protonated ubiquitin protein ion have been recorded at incident electron energies around the carbon 1s excitation. Both MS2 and single ionization energy dependencemore » spectra are compared with literature data obtained using the soft X-ray activation conditions.« less

  19. Ion source for high-precision mass spectrometry

    DOE Patents [OSTI]

    Todd, P.J.; McKown, H.S.; Smith, D.H.

    1982-04-26

    The invention is directed to a method for increasing the precision of positive-ion relative abundance measurements conducted in a sector mass spectrometer having an ion source for directing a beam of positive ions onto a collimating slit. The method comprises incorporating in the source an electrostatic lens assembly for providing a positive-ion beam of circular cross section for collimation by the slit. 2 figures, 3 tables.

  20. Stress influenced trapping processes in Si based multi-quantum well structures and heavy ions implanted Si

    SciTech Connect (OSTI)

    Ciurea, Magdalena Lidia Lazanu, Sorina

    2014-10-06

    Multi-quantum well structures and Si wafers implanted with heavy iodine and bismuth ions are studied in order to evaluate the influence of stress on the parameters of trapping centers. The experimental method of thermostimullatedcurrents without applied bias is used, and the trapping centers are filled by illumination. By modeling the discharge curves, we found in multilayered structures the parameters of both 'normal' traps and 'stress-induced' ones, the last having a Gaussian-shaped temperature dependence of the cross section. The stress field due to the presence of stopped heavy ions implanted into Si was modeled by a permanent electric field. The increase of the strain from the neighborhood of I ions to the neighborhood of Bi ions produces the broadening of some energy levels and also a temperature dependence of the cross sections for all levels.

  1. Linear electronic field time-of-flight ion mass spectrometers

    DOE Patents [OSTI]

    Funsten, Herbert O. (Los Alamos, NM)

    2010-08-24

    Time-of-flight mass spectrometer comprising a first drift region and a second drift region enclosed within an evacuation chamber; a means of introducing an analyte of interest into the first drift region; a pulsed ionization source which produces molecular ions from said analyte of interest; a first foil positioned between the first drift region and the second drift region, which dissociates said molecular ions into constituent atomic ions and emits secondary electrons; an electrode which produces secondary electrons upon contact with a constituent atomic ion in second drift region; a stop detector comprising a first ion detection region and a second ion detection region; and a timing means connected to the pulsed ionization source, to the first ion detection region, and to the second ion detection region.

  2. Orthogonal Injection Ion Funnel Interface Providing Enhanced Performance for Selected Reaction Monitoring-Triple Quadruple Mass Spectrometry

    SciTech Connect (OSTI)

    Chen, Tsung-Chi; Fillmore, Thomas L.; Prost, Spencer A.; Moore, Ronald J.; Ibrahim, Yehia M.; Smith, Richard D.

    2015-07-21

    The electrodynamic ion funnel facilitates efficient focusing and transfer of charged particles in the higher pressure regions (e.g. ion source interfaces) of mass spectrometers, and thus providing increased sensitivity. An “off-axis” ion funnel design has been developed to reduce the source contamination and interferences from, e.g. ESI droplet residue and other poorly focused neutral or charged particles with very high mass-to charge ratios. In this study a dual ion funnel interface consisting of an orthogonal higher pressure electrodynamic ion funnel (HPIF) and an ion funnel trap combined with a triple quadruple mass spectrometer was developed and characterized. An orthogonal ion injection inlet and a repeller plate electrode was used to direct ions to an ion funnel HPIF at 9-10 Torr pressure. Several critical factors for the HPIF were characterized, including the effects of RF amplitude, DC gradient and operating pressure. Compared to the triple quadrupole standard interface more than 4-fold improvement in the limit of detection for the direct quantitative MS analysis of low abundance peptides was observed. The sensitivity enhancement in liquid chromatography selected reaction monitoring (SRM) analyses of low abundance peptides spiked into a highly complex mixture was also compared with that obtained using a both commercial s-lens interface and a in-line dual ion funnel interface.

  3. Generation of high charge state metal ion beams by electron cyclotron resonance heating of vacuum arc plasma in cusp trap

    SciTech Connect (OSTI)

    Nikolaev, A. G.; Savkin, K. P.; Oks, E. M.; Vizir, A. V.; Yushkov, G. Yu.; Vodopyanov, A. V.; Izotov, I. V.; Mansfeld, D. A.

    2012-02-15

    A method for generating high charge state heavy metal ion beams based on high power microwave heating of vacuum arc plasma confined in a magnetic trap under electron cyclotron resonance conditions has been developed. A feature of the work described here is the use of a cusp magnetic field with inherent ''minimum-B'' structure as the confinement geometry, as opposed to a simple mirror device as we have reported on previously. The cusp configuration has been successfully used for microwave heating of gas discharge plasma and extraction from the plasma of highly charged, high current, gaseous ion beams. Now we use the trap for heavy metal ion beam generation. Two different approaches were used for injecting the vacuum arc metal plasma into the trap - axial injection from a miniature arc source located on-axis near the microwave window, and radial injection from sources mounted radially at the midplane of the trap. Here, we describe preliminary results of heating vacuum arc plasma in a cusp magnetic trap by pulsed (400 {mu}s) high power (up to 100 kW) microwave radiation at 37.5 GHz for the generation of highly charged heavy metal ion beams.

  4. Electron and recoil ion momentum imaging with a magneto-optically trapped target

    SciTech Connect (OSTI)

    Hubele, R.; Schuricke, M.; Goullon, J.; Lindenblatt, H.; Ferreira, N.; Laforge, A.; Brhl, E.; Globig, D.; Misra, D.; Sell, M.; Song, Z.; Wang, X.; Zhang, S.; Jesus, V. L. B. de; Kelkar, A.; Schneider, K.; Schulz, M.; Fischer, D.

    2015-03-15

    A reaction microscope (ReMi) has been combined with a magneto-optical trap (MOT) for the kinematically complete investigation of atomic break-up processes. With the novel MOTReMi apparatus, the momentum vectors of the fragments of laser-cooled and state-prepared lithium atoms are measured in coincidence and over the full solid angle. The first successful implementation of a MOTReMi could be realized due to an optimized design of the present setup, a nonstandard operation of the MOT, and by employing a switching cycle with alternating measuring and trapping periods. The very low target temperature in the MOT (?2 mK) allows for an excellent momentum resolution. Optical preparation of the target atoms in the excited Li 2{sup 2}P{sub 3/2} state was demonstrated providing an atomic polarization of close to 100%. While first experimental results were reported earlier, in this work, we focus on the technical description of the setup and its performance in commissioning experiments involving target ionization in 266 nm laser pulses and in collisions with projectile ions.

  5. Method for increasing the dynamic range of mass spectrometers

    DOE Patents [OSTI]

    Belov, Mikhail; Smith, Richard D.; Udseth, Harold R.

    2004-09-07

    A method for enhancing the dynamic range of a mass spectrometer by first passing a sample of ions through the mass spectrometer having a quadrupole ion filter, whereupon the intensities of the mass spectrum of the sample are measured. From the mass spectrum, ions within this sample are then identified for subsequent ejection. As further sampling introduces more ions into the mass spectrometer, the appropriate rf voltages are applied to a quadrupole ion filter, thereby selectively ejecting the undesired ions previously identified. In this manner, the desired ions may be collected for longer periods of time in an ion trap, thus allowing better collection and subsequent analysis of the desired ions. The ion trap used for accumulation may be the same ion trap used for mass analysis, in which case the mass analysis is performed directly, or it may be an intermediate trap. In the case where collection is an intermediate trap, the desired ions are accumulated in the intermediate trap, and then transferred to a separate mass analyzer. The present invention finds particular utility where the mass analysis is performed in an ion trap mass spectrometer or a Fourier transform ion cyclotron resonance mass spectrometer.

  6. Optical Ramsey spectroscopy of a single trapped {sup 88}Sr{sup +} ion

    SciTech Connect (OSTI)

    Letchumanan, V. [National Physical Laboratory, Teddington, Middlesex TW11 0LW (United Kingdom); Department of Physics, Imperial College London, South Kensington Campus, London SW7 2BW (United Kingdom); Gill, P.; Sinclair, A.G. [National Physical Laboratory, Teddington, Middlesex TW11 0LW (United Kingdom); Riis, E. [Department of Physics, University of Strathclyde, Glasgow G4 0NG (United Kingdom)

    2004-09-01

    Coherent optical spectroscopy has been performed on the narrow 5s {sup 2}S{sub 1/2}-4d {sup 2}D{sub 5/2} quadrupole transition in a single Doppler-cooled and trapped {sup 88}Sr{sup +} ion. High-contrast optical Ramsey spectra have been observed with fringe visibilities up to {approx}90%. The visibility decreased as the free precession period was increased, and was limited by the interrogation laser's coherence. The effect of varying the relative phase of the second Ramsey pulse was investigated. By measuring the difference in excitation probability on reversing a 90 deg. relative phase shift between the two Ramsey pulses, we have demonstrated Ramsey's anti-symmetric line shape in the optical domain. A significant advantage of this line shape is the zero crossing at line center and the independence of this center frequency on drifts in signal amplitude. This optical Ramsey line shape is suitable for stabilizing a local oscillator to an atomic reference transition in an optical frequency standard. All observed optical Ramsey signals are well described by a model using the optical Bloch equations.

  7. Linear electric field time-of-flight ion mass spectrometer

    DOE Patents [OSTI]

    Funsten, Herbert O. (Los Alamos, NM); Feldman, William C. (Los Alamos, NM)

    2008-06-10

    A linear electric field ion mass spectrometer having an evacuated enclosure with means for generating a linear electric field located in the evacuated enclosure and means for injecting a sample material into the linear electric field. A source of pulsed ionizing radiation injects ionizing radiation into the linear electric field to ionize atoms or molecules of the sample material, and timing means determine the time elapsed between ionization of atoms or molecules and arrival of an ion out of the ionized atoms or molecules at a predetermined position.

  8. Simulation of lean NOx trap performance with microkinetic chemistry and without mass transfer.

    SciTech Connect (OSTI)

    Larson, Rich; Daw, C. Stuart; Pihl, Josh A.; Chakravarthy, V. Kalyana

    2011-08-01

    A microkinetic chemical reaction mechanism capable of describing both the storage and regeneration processes in a fully formulated lean NO{sub x} trap (LNT) is presented. The mechanism includes steps occurring on the precious metal, barium oxide (NO{sub x} storage), and cerium oxide (oxygen storage) sites of the catalyst. The complete reaction set is used in conjunction with a transient plug flow reactor code to simulate not only conventional storage/regeneration cycles with a CO/H{sub 2} reductant, but also steady flow temperature sweep experiments that were previously analyzed with just a precious metal mechanism and a steady state code. The results show that NO{sub x} storage is not negligible during some of the temperature ramps, necessitating a re-evaluation of the precious metal kinetic parameters. The parameters for the entire mechanism are inferred by finding the best overall fit to the complete set of experiments. Rigorous thermodynamic consistency is enforced for parallel reaction pathways and with respect to known data for all of the gas phase species involved. It is found that, with a few minor exceptions, all of the basic experimental observations can be reproduced with these purely kinetic simulations, i.e., without including mass-transfer limitations. In addition to accounting for normal cycling behavior, the final mechanism should provide a starting point for the description of further LNT phenomena such as desulfation and the role of alternative reductants.

  9. Thermoelectrically cooled water trap

    DOE Patents [OSTI]

    Micheels, Ronald H.

    2006-02-21

    A water trap system based on a thermoelectric cooling device is employed to remove a major fraction of the water from air samples, prior to analysis of these samples for chemical composition, by a variety of analytical techniques where water vapor interferes with the measurement process. These analytical techniques include infrared spectroscopy, mass spectrometry, ion mobility spectrometry and gas chromatography. The thermoelectric system for trapping water present in air samples can substantially improve detection sensitivity in these analytical techniques when it is necessary to measure trace analytes with concentrations in the ppm (parts per million) or ppb (parts per billion) partial pressure range. The thermoelectric trap design is compact and amenable to use in a portable gas monitoring instrumentation.

  10. Continuous time-of-flight ion mass spectrometer

    DOE Patents [OSTI]

    Funsten, Herbert O.; Feldman, William C.

    2004-10-19

    A continuous time-of-flight mass spectrometer having an evacuated enclosure with means for generating an electric field located in the evacuated enclosure and means for injecting a sample material into the electric field. A source of continuous ionizing radiation injects ionizing radiation into the electric field to ionize atoms or molecules of the sample material, and timing means determine the time elapsed between arrival of a secondary electron out of said ionized atoms or molecules at a first predetermined location and arrival of a sample ion out of said ionized atoms or molecules at a second predetermined location.

  11. Ion cyclotron resonance cell

    DOE Patents [OSTI]

    Weller, Robert R. (Aiken, SC)

    1995-01-01

    An ion cyclotron resonance cell having two adjacent sections separated by a center trapping plate. The first section is defined by the center trapping plate, a first end trapping plate, and excitation and detector electrodes. The second section includes a second end trapping plate spaced apart from the center plate, a mirror, and an analyzer. The analyzer includes a wavelength-selective light detector, such as a detector incorporating an acousto-optical device (AOD) and a photodetector. One or more ion guides, grounded plates with holes for the ion beam, are positioned within the vacuum chamber of the mass spectrometer between the ion source and the cell. After ions are trapped and analyzed by ion cyclotron resonance techniques in the first section, the ions of interest are selected according to their mass and passed into the second section for optical spectroscopic studies. The trapped ions are excited by light from a laser and caused thereby to fluoresce. The fluorescent light emitted by the excited ions is reflected by the mirror and directed onto the detector. The AOD is scanned, and the photodetector output is recorded and analyzed. The ions remain in the second section for an extended period, enabling multiple studies to be carried out on the same ensemble of ions.

  12. Ion cyclotron resonance cell

    DOE Patents [OSTI]

    Weller, R.R.

    1995-02-14

    An ion cyclotron resonance cell is disclosed having two adjacent sections separated by a center trapping plate. The first section is defined by the center trapping plate, a first end trapping plate, and excitation and detector electrodes. The second section includes a second end trapping plate spaced apart from the center plate, a mirror, and an analyzer. The analyzer includes a wavelength-selective light detector, such as a detector incorporating an acousto-optical device (AOD) and a photodetector. One or more ion guides, grounded plates with holes for the ion beam, are positioned within the vacuum chamber of the mass spectrometer between the ion source and the cell. After ions are trapped and analyzed by ion cyclotron resonance techniques in the first section, the ions of interest are selected according to their mass and passed into the second section for optical spectroscopic studies. The trapped ions are excited by light from a laser and caused thereby to fluoresce. The fluorescent light emitted by the excited ions is reflected by the mirror and directed onto the detector. The AOD is scanned, and the photodetector output is recorded and analyzed. The ions remain in the second section for an extended period, enabling multiple studies to be carried out on the same ensemble of ions. 5 figs.

  13. Target normal sheath acceleration of foil ions by laser-trapped hot electrons from a long subcritical-density preplasma

    SciTech Connect (OSTI)

    Luan, S. X.; Yu, Wei; Shen, B. F.; Xu, Z. Z.; Yu, M. Y.; Zhuo, H. B.; Xu, Han; Wong, A. Y.; Wang, J. W.

    2014-12-15

    In a long subcritical density plasma, an ultrashort ultraintense laser pulse can self-organize into a fast but sub-relativistic propagating structure consisting of the modulated laser light and a large number of trapped electrons from the plasma. Upon impact of the structure with a solid foil target placed in the latter, the remaining laser light is reflected, but the dense and hot trapped electrons pass through the foil, together with the impact-generated target-frontsurface electrons to form a dense hot electron cloud at the back of the target suitable for enhancing target normal sheath acceleration of the target-backsurface ions. The accelerated ions are well collimated and of high charge and energy densities, with peak energies a full order of magnitude higher than that from target normal sheath acceleration without the subcritical density plasma. In the latter case, the space-charge field accelerating the ions is limited since they are formed only by the target-frontsurface electrons during the very short instant of laser reflection.

  14. Method for studying a sample of material using a heavy ion induced mass spectrometer source

    DOE Patents [OSTI]

    Fries, D.P.; Browning, J.F.

    1999-02-16

    A heavy ion generator is used with a plasma desorption mass spectrometer to provide an appropriate neutron flux in the direction of a fissionable material in order to desorb and ionize large molecules from the material for mass analysis. The heavy ion generator comprises a fissionable material having a high n,f reaction cross section. The heavy ion generator also comprises a pulsed neutron generator that is used to bombard the fissionable material with pulses of neutrons, thereby causing heavy ions to be emitted from the fissionable material. These heavy ions impinge on a material, thereby causing ions to desorb off that material. The ions desorbed off the material pass through a time-of-flight mass analyzer, wherein ions can be measured with masses greater than 25,000 amu. 3 figs.

  15. System for studying a sample of material using a heavy ion induced mass spectrometer source

    DOE Patents [OSTI]

    Fries, David P. (St. Petersburg, FL); Browning, James F. (Palm Harbour, FL)

    1998-01-01

    A heavy ion generator is used with a plasma desorption mass spectrometer to provide an appropriate neutron flux in the direction of a fissionable material in order to desorb and ionize large molecules from the material for mass analysis. The heavy ion generator comprises a fissionable material having a high n,f reaction cross section. The heavy ion generator also comprises a pulsed neutron generator that is used to bombard the fissionable material with pulses of neutrons, thereby causing heavy ions to be emitted from the fissionable material. These heavy ions impinge on a material, thereby causing ions to desorb off that material. The ions desorbed off the material pass through a time-of-flight mass analyzer, wherein ions can be measured with masses greater than 25,000 amu.

  16. Method for studying a sample of material using a heavy ion induced mass spectrometer source

    DOE Patents [OSTI]

    Fries, David P. (St. Petersburg, FL); Browning, James F. (Palm Harbour, FL)

    1999-01-01

    A heavy ion generator is used with a plasma desorption mass spectrometer to provide an appropriate neutron flux in the direction of a fissionable material in order to desorb and ionize large molecules from the material for mass analysis. The heavy ion generator comprises a fissionable material having a high n,f reaction cross section. The heavy ion generator also comprises a pulsed neutron generator that is used to bombard the fissionable material with pulses of neutrons, thereby causing heavy ions to be emitted from the fissionable material. These heavy ions impinge on a material, thereby causing ions to desorb off that material. The ions desorbed off the material pass through a time-of-flight mass analyzer, wherein ions can be measured with masses greater than 25,000 amu.

  17. System for studying a sample of material using a heavy ion induced mass spectrometer source

    DOE Patents [OSTI]

    Fries, D.P.; Browning, J.F.

    1998-07-21

    A heavy ion generator is used with a plasma desorption mass spectrometer to provide an appropriate neutron flux in the direction of a fissionable material in order to desorb and ionize large molecules from the material for mass analysis. The heavy ion generator comprises a fissionable material having a high (n,f) reaction cross section. The heavy ion generator also comprises a pulsed neutron generator that is used to bombard the fissionable material with pulses of neutrons, thereby causing heavy ions to be emitted from the fissionable material. These heavy ions impinge on a material, thereby causing ions to desorb off that material. The ions desorbed off the material pass through a time-of-flight mass analyzer, wherein ions can be measured with masses greater than 25,000 amu. 3 figs.

  18. A high-current electron gun for the electron beam ion trap at the National Superconducting Cyclotron Laboratory

    SciTech Connect (OSTI)

    Schwarz, S. Baumann, T. M.; Kittimanapun, K.; Lapierre, A.; Snyder, A.

    2014-02-15

    The Electron Beam Ion Trap (EBIT) in NSCL’s reaccelerator ReA uses continuous ion injection and accumulation. In order to maximize capture efficiency and minimize breeding time into high charge states, the EBIT requires a high-current/high current-density electron beam. A new electron gun insert based on a concave Ba-dispenser cathode has been designed and built to increase the current transmitted through the EBIT’s superconducting magnet. With the new insert, stable EBIT operating conditions with 0.8 A of electron beam have been established. The design of the electron gun is presented together with calculated and measured perveance data. In order to assess the experimental compression of the electron beam, a pinhole CCD camera has been set up to measure the electron beam radius. The camera observes X-rays emitted from highly charged ions, excited by the electron beam. Initial tests with this camera setup will be presented. They indicate that a current density of 640 A/cm{sup 2} has been reached when the EBIT magnet was operated at 4 T.

  19. Apparatus and methods for continuous beam fourier transform mass spectrometry

    DOE Patents [OSTI]

    McLuckey, Scott A.; Goeringer, Douglas E.

    2002-01-01

    A continuous beam Fourier transform mass spectrometer in which a sample of ions to be analyzed is trapped in a trapping field, and the ions in the range of the mass-to-charge ratios to be analyzed are excited at their characteristic frequencies of motion by a continuous excitation signal. The excited ions in resonant motions generate real or image currents continuously which can be detected and processed to provide a mass spectrum.

  20. A new detector for mass spectrometry: Direct detection of low energy ions

    Office of Scientific and Technical Information (OSTI)

    using a multi-pixel photon counter (Journal Article) | SciTech Connect A new detector for mass spectrometry: Direct detection of low energy ions using a multi-pixel photon counter Citation Details In-Document Search Title: A new detector for mass spectrometry: Direct detection of low energy ions using a multi-pixel photon counter A new type of ion detector for mass spectrometry and general detection of low energy ions is presented. The detector consists of a scintillator optically coupled to

  1. A Brief History in Time of Ion Traps and their Achievements in Science

    DOE R&D Accomplishments [OSTI]

    Holzscheiter, M. H.

    1994-01-01

    A short history of the development of the ion storage technique for precision experiments is given. This is by no means meant to be a complete review of the field, but the intend is to use a few specific examples to describe how the persistence, ingenuity, and experimental skill of a few people has generated the core of a field which is now growing at an ever faster pace, spreading into new areas, developing sub fields, and allowing a view at nature, using very modest experimental equipment, which by far rivals even the most ambitious dreams of high energy physics.

  2. Determination of the ReA Electron Beam Ion Trap electron beam radius and current density with an X-ray pinhole camera

    SciTech Connect (OSTI)

    Baumann, Thomas M. Lapierre, Alain Kittimanapun, Kritsada; Schwarz, Stefan; Leitner, Daniela; Bollen, Georg

    2014-07-15

    The Electron Beam Ion Trap (EBIT) of the National Superconducting Cyclotron Laboratory at Michigan State University is used as a charge booster and injector for the currently commissioned rare isotope re-accelerator facility ReA. This EBIT charge breeder is equipped with a unique superconducting magnet configuration, a combination of a solenoid and a pair of Helmholtz coils, allowing for a direct observation of the ion cloud while maintaining the advantages of a long ion trapping region. The current density of its electron beam is a key factor for efficient capture and fast charge breeding of continuously injected, short-lived isotope beams. It depends on the radius of the magnetically compressed electron beam. This radius is measured by imaging the highly charged ion cloud trapped within the electron beam with a pinhole camera, which is sensitive to X-rays emitted by the ions with photon energies between 2 keV and 10 keV. The 80%-radius of a cylindrical 800 mA electron beam with an energy of 15 keV is determined to be r{sub 80%}=(21219)?m in a 4 T magnetic field. From this, a current density of j = (454 83)A/cm{sup 2} is derived. These results are in good agreement with electron beam trajectory simulations performed with TriComp and serve as a test for future electron gun design developments.

  3. Spectroscopy at the high-energy electron beam ion trap (Super EBIT)

    SciTech Connect (OSTI)

    Widmann, K.; Beiersdorfer, P.; Crespo Lopez-Urrutia, J.R.

    1996-07-10

    The following progress report presents some of the x-ray measurements performed during the last year on the Livermore SuperEBIT facility. The measurements include: direct observation of the spontaneous emission of the hyperfine transition in ground state hydrogenlike holmium, {sup 165}Ho{sup 66{plus}}; measurements of the n {equals} 2 {r_arrow} 2 transition energies in neonlike thorium, Th{sup 80{plus}}, through lithiumlike thorium, Th{sup 87{plus}}, testing the predictions of quantum electrodynamical contributions in high-Z ions up to the 0.4{percent} level; measurements of the isotope shift of the n= 2 {r_arrow} 2 transition energies between lithiumlike through carbonize uranium, {sup 233}U{sup 89{plus}...86{plus}} and {sup 238}U{sup 89{plus}...86{plus}}, inferring the variation of the mean- square nuclear charge radius; and high-resolution measurements of the K{alpha} radiation of heliumlike xenon, Xe{sup 52 {plus}}, using a transmission-type crystal spectrometer, resolving for the first time the ls2p{sup 3}P{sub 1} {r_arrow} 1S{sup 2} {sup 1}S{sub 0} and ls2s{sup 3}S{sub 1} {r_arrow} 1S{sup 2} {sup 1}S{sub 0} transitions individually. 41 refs., 9 figs., 1 tab.

  4. Development of a New Ion Mobility Time-of-Flight Mass Spectrometer

    SciTech Connect (OSTI)

    Ibrahim, Yehia M.; Baker, Erin Shammel; Danielson, William F.; Norheim, Randolph V.; Prior, David C.; Anderson, Gordon A.; Belov, Mikhail E.; Smith, Richard D.

    2015-02-01

    A new ion mobility spectrometer (IMS) platform was developed to improve upon the sensitivity and reproducibility of our previous platforms, and further enhance IMS-MS utility for broad pan-omics measurements. The new platform incorporated an improved electrospray ionization source and interface for enhanced sensitivity, and providing the basis for further benefits based upon implementation of multiplexed IMS. The ion optics included electrodynamic ion funnels at both the entrance and exit of the IMS, an ion funnel trap for ion injection, and a design in which nearly all ion optics (e.g. drift rings, ion funnels) were fabricated using printed circuit board technology. The IMS resolving power achieved was ~73 for singly-charged ions, very close to the predicted diffusion-limited resolving power (~75). The platforms performance evaluation (e.g. for proteomics measurements) include LC-IMS-TOF MS datasets for 30 technical replicates for a trypsin digested human serum, and included platform performance in each dimension (LC, IMS and MS) separately.

  5. Effect of trapped electron on the dust ion acoustic waves in dusty plasma using time fractional modified Korteweg-de Vries equation

    SciTech Connect (OSTI)

    Nazari-Golshan, A.; Nourazar, S. S.; Department of Mechanical Engineering, Amirkabir University of Technology, Tehran

    2013-10-15

    The time fractional modified Korteweg-de Vries (TFMKdV) equation is solved to study the nonlinear propagation of small but finite amplitude dust ion-acoustic (DIA) solitary waves in un-magnetized dusty plasma with trapped electrons. The plasma is composed of a cold ion fluid, stationary dust grains, and hot electrons obeying a trapped electron distribution. The TFMKdV equation is derived by using the semi-inverse and Agrawal's methods and then solved by the Laplace Adomian decomposition method. Our results show that the amplitude of the DIA solitary waves increases with the increase of time fractional order ?, the wave velocity v{sub 0}, and the population of the background free electrons ?. However, it is vice-versa for the deviation from isothermality parameter b, which is in agreement with the result obtained previously.

  6. Apparatus for reduction of selected ion intensities in confined ion beams

    DOE Patents [OSTI]

    Eiden, Gregory C. (Richland, WA); Barinaga, Charles J. (Richland, WA); Koppenaal, David W. (Richland, WA)

    2001-01-01

    An apparatus for producing an ion beam having an increased proportion of analyte ions compared to carrier gas ions is disclosed. Specifically, the apparatus has an ion trap or a collision cell containing a reagent gas wherein the reagent gas accepts charge from the analyte ions thereby selectively neutralizing the carrier gas ions. Also disclosed is the collision cell as employed in various locations within analytical instruments including an inductively coupled plasma mass spectrometer.

  7. Covalent Immobilization of Peptides on Self-Assembled Monolayer Surfaces Using Soft-Landing of Mass-Selected Ions

    SciTech Connect (OSTI)

    Wang, Peng; Hadjar, Omar; Laskin, Julia

    2007-06-23

    Covalent immobilization of peptides on solid supports plays an important role in biochemistry with applications ranging from characterization of molecular recognition events at the amino acid level and identification of biologically active motifs in proteins to development of novel biosensors and substrates for improved cell adhesion. Self-assembled monolayer surfaces (SAMs) provide a simple and convenient platform for tailoring chemical properties of a variety of substrates. Existing techniques for linking peptides to SAMs are based on solution-phase synthetic strategies and require relatively large quantities of purified material. Here, we report a novel approach for highly selective covalent binding of peptides to SAMs using soft-landing (SL) of mass-selected ions. SL is defined as intact deposition of ions onto suitable substrates at hyperthermal (<100 eV) energies.Recent studies have demonstrated that SAMs are excellent deposition targets for SL due to their ability to dissipate kinetic energies of the projectiles and their efficiency in trapping captured species. It has been proposed that SL could be utilized for controlled preparation of protein arrays.

  8. LOW-TEMPERATURE ION TRAP STUDIES OF N{sup +}({sup 3} P{sub ja} ) + H{sub 2}(j) {yields} NH{sup +} + H

    SciTech Connect (OSTI)

    Zymak, I.; Hejduk, M.; Mulin, D.; Plasil, R.; Glosik, J.; Gerlich, D.

    2013-05-01

    Using a low-temperature 22-pole ion trap apparatus, detailed measurements for the title reaction have been performed between 10 K and 100 K in order to get some state specific information about this fundamental hydrogen abstraction process. The relative population of the two lowest H{sub 2} rotational states, j = 0 and 1, has been varied systematically. NH{sup +} formation is nearly thermo-neutral; however, to date, the energetics are not known with the accuracy required for low-temperature astrochemistry. Additional complications arise from the fact that, so far, there is no reliable theoretical or experimental information on how the reactivity of the N{sup +} ion depends on its fine-structure (FS) state {sup 3} P{sub ja} . Since in the present trapping experiment, thermalization of the initially hot FS population competes with hydrogen abstraction, the evaluation of the decay of N{sup +} ions over long storage times and at various He and H{sub 2} gas densities provides information on these processes. First assuming strict adiabatic behavior, a set of state specific rate coefficients is derived from the measured thermal rate coefficients. In addition, by recording the disappearance of the N{sup +} ions over several orders of magnitude, information on nonadiabatic transitions is extracted including FS-changing collisions.

  9. Charge Retention by Gold Clusters on Surfaces Prepared Using Soft Landing of Mass Selected Ions

    SciTech Connect (OSTI)

    Johnson, Grant E.; Priest, Thomas A.; Laskin, Julia

    2012-01-24

    Monodisperse gold clusters have been prepared on surfaces in different charge states through soft landing of mass-selected ions. Ligand-stabilized gold clusters were prepared in methanol solution by reduction of chloro(triphenylphosphine)gold(I) with borane tert-butylamine complex in the presence of 1,3-bis(diphenylphosphino)propane. Electrospray ionization was used to introduce the clusters into the gas-phase and mass-selection was employed to isolate a single ionic cluster species (Au11L53+, L = 1,3-bis(diphenylphosphino)propane) which was delivered to surfaces at well controlled kinetic energies. Using in-situ time of flight secondary ion mass spectrometry (TOF-SIMS) it is demonstrated that the Au11L53+ cluster retains its 3+ charge state when soft landed onto the surface of a 1H,1H,2H,2H-

  10. Ultra High Mass Range Mass Spectrometer System

    DOE Patents [OSTI]

    Reilly, Peter T. A. [Knoxville, TN

    2005-12-06

    Applicant's present invention comprises mass spectrometer systems that operate in a mass range from 1 to 10.sup.16 DA. The mass spectrometer system comprising an inlet system comprising an aerodynamic lens system, a reverse jet being a gas flux generated in an annulus moving in a reverse direction and a multipole ion guide; a digital ion trap; and a thermal vaporization/ionization detector system. Applicant's present invention further comprises a quadrupole mass spectrometer system comprising an inlet system having a quadrupole mass filter and a thermal vaporization/ionization detector system. Applicant's present invention further comprises an inlet system for use with a mass spectrometer system, a method for slowing energetic particles using an inlet system. Applicant's present invention also comprises a detector device and a method for detecting high mass charged particles.

  11. High explosives vapor detection by atmospheric sampling glow discharge ionization/tandem mass spectrometry

    SciTech Connect (OSTI)

    McLuckey, S.A.; Goeringer, D.E.; Asano, K.G.

    1996-02-01

    The combination of atmospheric sampling glow discharge ionization with tandem mass spectrometry for the detection of traces of high explosives is described. Particular emphasis is placed on use of the quadrupole ion trap as the type of tandem mass spectrometer. Atmospheric sampling glow discharge provides a simple, rugged, and efficient means for anion formation while the quadrupole ion trap provides for efficient tandem mass spectrometry. Mass selective ion accumulation and non-specific ion activation methods can be used to overcome deleterious effects arising from ion/ion interactions. Such interactions constitute the major potential technical barrier to the use of the ion trap for real-time monitoring of targeted compounds in uncontrolled and highly variable matrices. Tailored waveforms can be used to effect both mass selective ion accumulation and ion activation. Concatenated tailored waveforms allow for both functions in a single experiment thereby providing the capability for monitoring several targeted species simultaneously. The combination of atmospheric sampling glow discharge ionization with a state-of-the-art analytical quadrupole ion trap is a highly sensitive and specific detector for traces of high explosives. The combination is also small and inexpensive relative to virtually any other form of tandem mass spectrometry. The science and technology underlying the glow discharge/ion trap combination is sufficiently mature to form the basis for an engineering effort to make the detector portable. 85 refs.

  12. Modeling the ion density distribution in collisional cooling RF multipole ion guides

    SciTech Connect (OSTI)

    Tolmachev, Aleksey V.; Udseth, Harold R.; Smith, Richard D.

    2003-01-01

    Collisional cooling radio frequency (RF) multipoles are widely used in mass spectrometry, as ion guides and two-dimensional (2D) ion traps. Understanding the behavior of ions in these devices is important in choosing a multipole configuration. We have developed a computer model based on ion trajectory calculations in the RF multipole electric field, taking into account ion-ion and ion-neutral interactions. The two-dimensional model for idealized infinite RF multipoles gives accurate description of the ion density distribution. We consider first a basic case of a single m/z ion cloud in the 2D RF quadrupole after equilibrium is reached. Approximate theoretical relationships for the ion cloud configuration in the 2D ion trap are tested based on simulations results. Next we proceed with a case of an ion cloud consisting of several different m/z ion species. The ion relaxation dynamics and the process of establishing the stratified ion density distribution are followed. Simulations reveal a different relaxation dynamics for the axial and radial ion kinetic energy components. The kinetic energy relaxation rate is dependent on ion population and bath gas pressure. The equilibrium distribution agrees well with the ion stratification theory, as demonstrated by simulations for RF quadrupole and octupole 2D ion traps.

  13. Detecting and Removing Data Artifacts in Hadamard Transform Ion Mobility-Mass Spectrometry Measurements

    SciTech Connect (OSTI)

    Prost, Spencer A.; Crowell, Kevin L.; Baker, Erin Shammel; Ibrahim, Yehia M.; Clowers, Brian H.; Monroe, Matthew E.; Anderson, Gordon A.; Smith, Richard D.; Payne, Samuel H.

    2014-12-01

    Applying Hadamard transform multiplexing to ion mobility separations (IMS) can significantly improve the signal-to-noise ratio and throughput for IMS coupled mass spectrometry (MS) measurements by increasing the ion utilization efficiency. However, it has been determined that both fluctuations in ion intensity as well as spatial shifts in the multiplexed data lower the signal-to-noise ratios and appear as noise in downstream processing of the data. To address this problem, we have developed a novel algorithm that discovers and eliminates data artifacts. The algorithm uses knowledge of the true signal peaks derived from the encoded data and allows for both artifacts and noise to be removed with high confidence, decreasing the likelihood of false identifications in subsequent data processing. The result is that IMS-MS can be applied to increase measurement sensitivity while avoiding artifacts that have previously limited its utility.

  14. Reduction of plyatomic ion interferences in indictively coupled plasma mass spectrometry with cryogenic desolvation

    SciTech Connect (OSTI)

    Alves, L.C.

    1993-09-01

    A desolvation scheme for introducing aqueous and organic samples into an argon inductively coupled plasma is described; the aerosol generated by nebulizer is heated (+140 C) and cooled ({minus}80 C) repeatedly, and the dried aerosol is then injected into the mass spectrometer. Polyatomic ions are greatly suppressed. This scheme was validated with analysis of seawater and urine reference samples. Finally, the removal of organic solvents by cryogenic desolvation was studied.

  15. Preparation and in situ Characterization of Surfaces Using Soft-Landing in a Fourier Transform Ion Cyclotron Resonance Mass Spectrometer

    SciTech Connect (OSTI)

    Alvarez, Jormarie; Cooks, Robert G.; Barlow, Stephan E.; Gaspar, Dan J.; Futrell, Jean H.; Laskin, Julia

    2005-06-01

    Mass-selected peptide ions produced by electrospray ionization were deposited onto fluorinated self-assembled monolayer surfaces (FSAM) surfaces by soft-landing using a Fourier transform ion cyclotron resonance mass spectrometer (FT-ICR MS) specially designed for studying interactions of large ions with surfaces. Analysis of the modified surface was performed in situ by combining 2 keV Cs+ secondary ion mass spectrometry with FT-ICR detection of the sputtered ions (FT-ICR-SIMS). Regardless of the initial charge state of the precursor ion, the SIMS mass spectra included singly-protonated peptide fragment ions and peaks characteristic of the surfaces in all cases. In some experiments multiply-protonated peptide ions and [M+Au]+ ions were also observed upon SIMS analysis of modified surfaces. For comparison with the in situ analysis of the modified surfaces, ex situ analysis of some of the modified surfaces was performed by 25 kV Ga+ time of flight ? secondary ion mass spectrometry (ToF-SIMS). The ex situ analysis demonstrated that a significant number of soft-landed peptide ions remain charged on the surface even when exposed to air for several hours after deposition. Charge retention of soft-landed ions dramatically increases the ion yields obtained during SIMS analysis very sensitive detection of deposited material at less than 1% of monolayer coverage. Accumulation of charged species on the surface undergoes saturation due to Coulomb repulsion between charges at close to 30% coverage. We estimated that close to 1 ng of peptide could be deposited on the spot area of 4 mm2 of the FSAM surface without reaching saturation.

  16. Kinetic electron and ion instability of the lunar wake simulated at physical mass ratio

    SciTech Connect (OSTI)

    Haakonsen, Christian Bernt Hutchinson, Ian H. Zhou, Chuteng

    2015-03-15

    The solar wind wake behind the moon is studied with 1D electrostatic particle-in-cell (PIC) simulations using a physical ion to electron mass ratio (unlike prior investigations); the simulations also apply more generally to supersonic flow of dense magnetized plasma past non-magnetic objects. A hybrid electrostatic Boltzmann electron treatment is first used to investigate the ion stability in the absence of kinetic electron effects, showing that the ions are two-stream unstable for downstream wake distances (in lunar radii) greater than about three times the solar wind Mach number. Simulations with PIC electrons are then used to show that kinetic electron effects can lead to disruption of the ion beams at least three times closer to the moon than in the hybrid simulations. This disruption occurs as the result of a novel wake phenomenon: the non-linear growth of electron holes spawned from a narrow dimple in the electron velocity distribution. Most of the holes arising from the dimple are small and quickly leave the wake, approximately following the unperturbed electron phase-space trajectories, but some holes originating near the center of the wake remain and grow large enough to trigger disruption of the ion beams. Non-linear kinetic-electron effects are therefore essential to a comprehensive understanding of the 1D electrostatic stability of such wakes, and possible observational signatures in ARTEMIS data from the lunar wake are discussed.

  17. (Competitive ion kinetics in director mass spectrometric organic speciation). Progress report

    SciTech Connect (OSTI)

    Sieck, L.W.

    1986-01-01

    Essentially all of the completed/in progress studies during the last reporting period have involved the NBS pulsed electron beam high pressure mass spectrometer. Three distinct areas of research are recognizable; (1) determinations of binding energies and entropies for association and cluster ions, which is accomplished by measuring the temperature dependence of the equilibrium A/sup +/ or A/sup -/ + B in equilibrium A/sup +/.B or A/sup -/.B, (2) measurement of unimolecular rate constants for the thermal decomposition (pyrolysis of protonated organic molecules, and (3) evaluation of proton affinities and gas phase acidities via measurement of variable-temperature equilibria of the type AH/sup +/ + B in equilibrium BH/sup +/ + A and A/sup -/ + BH in equilibrium AH + B/sup -/. The various systems and classes of molecules chosen for study were those deemed most likely to provide fundamental new information on ion kinetics, ionic stabilities and ionic reaction mechanisms.

  18. Method for selective detection of explosives in mass spectrometer or ion mobility spectrometer at parts-per-quadrillion level

    DOE Patents [OSTI]

    Ewing, Robert G.; Atkinson, David A.; Clowers, Brian H.

    2015-09-01

    A method for selective detection of volatile and non-volatile explosives in a mass spectrometer or ion mobility spectrometer at a parts-per-quadrillion level without preconcentration is disclosed. The method comprises the steps of ionizing a carrier gas with an ionization source to form reactant ions or reactant adduct ions comprising nitrate ions (NO.sub.3.sup.-); selectively reacting the reactant ions or reactant adduct ions with at least one volatile or non-volatile explosive analyte at a carrier gas pressure of at least about 100 Ton in a reaction region disposed between the ionization source and an ion detector, the reaction region having a length which provides a residence time (tr) for reactant ions therein of at least about 0.10 seconds, wherein the selective reaction yields product ions comprising reactant ions or reactant adduct ions that are selectively bound to the at least one explosive analyte when present therein; and detecting product ions with the ion detector to determine presence or absence of the at least one explosive analyte.

  19. MS/MS Automated Selected Ion Chromatograms

    Energy Science and Technology Software Center (OSTI)

    2005-12-12

    This program can be used to read a LC-MS/MS data file from either a Finnigan ion trap mass spectrometer (.Raw file) or an Agilent Ion Trap mass spectrometer (.MGF and .CDF files) and create a selected ion chromatogram (SIC) for each of the parent ion masses chosen for fragmentation. The largest peak in each SIC is also identified, with reported statistics including peak elution time, height, area, and signal to noise ratio. It creates severalmore » output files, including a base peak intensity (BPI) chromatogram for the survey scan, a BPI for the fragmentation scans, an XML file containing the SIC data for each parent ion, and a "flat file" (ready for import into a database) containing summaries of the SIC data statistics.« less

  20. Method for calibrating a Fourier transform ion cyclotron resonance mass spectrometer

    DOE Patents [OSTI]

    Smith, Richard D.; Masselon, Christophe D.; Tolmachev, Aleksey

    2003-08-19

    A method for improving the calibration of a Fourier transform ion cyclotron resonance mass spectrometer wherein the frequency spectrum of a sample has been measured and the frequency (f) and intensity (I) of at least three species having known mass to charge (m/z) ratios and one specie having an unknown (m/z) ratio have been identified. The method uses the known (m/z) ratios, frequencies, and intensities at least three species to calculate coefficients A, B, and C, wherein the mass to charge ratio of a least one of the three species (m/z).sub.i is equal to ##EQU1## wherein f.sub.i is the detected frequency of the specie, G(I.sub.i) is a predetermined function of the intensity of the species, and Q is a predetermined exponent. Using the calculated values for A, B, and C, the mass to charge ratio of the unknown specie (m/z).sub.ii is calculated as the sum of ##EQU2## wherein f.sub.ii is the measured frequency of the unknown specie, and (I.sub.ii) is the measured intensity of the unknown specie.

  1. Enhancing Biological Analyses with Three Dimensional Field Asymmetric Ion Mobility, Low Field Drift Time Ion Mobility and Mass Spectrometry (FAIMS/IMS-MS) Separations

    SciTech Connect (OSTI)

    Zhang, Xing; Ibrahim, Yehia M.; Chen, Tsung-Chi; Kyle, Jennifer E.; Norheim, Randolph V.; Monroe, Matthew E.; Smith, Richard D.; Baker, Erin Shammel

    2015-06-30

    We report the first evaluation of a platform coupling a high speed field asymmetric ion mobility spectrometry microchip (FAIMS) with drift tube ion mobility and mass spectrometry (IMS-MS). The FAIMS/IMS-MS platform was used to analyze biological samples and simultaneously acquire multidimensional information of detected features from the measured FAIMS compensation fields and IMS drift times, while also obtaining accurate ion masses. These separations thereby increase the overall separation power, resulting increased information content, and provide more complete characterization of more complex samples. The separation conditions were optimized for sensitivity and resolving power by the selection of gas compositions and pressures in the FAIMS and IMS separation stages. The resulting performance provided three dimensional separations, benefitting both broad complex mixture studies and targeted analyses by e.g. improving isomeric separations and allowing detection of species obscured by chemical noise and other interfering peaks.

  2. Competitive ion kinetics in direct mass spectrometric organic speciation: (Progress report, FY87-89)

    SciTech Connect (OSTI)

    Sieck, L.W.

    1987-01-01

    The following were studied: Stabilities of S...H/sup +/...X bonds, thermal decomposition of ions, stabilities of nitro anion association ions, stabilities of SF/sub 6//sup -/ association ions, proton affinities and cationic stabilization of tetraalkylhydrazines, adduct ion diagnostics in MS/MS, and anionic association ions incorporating RO/sup -/ or RCO/sub 2//sup -/.

  3. Campaign 1.7 Pu Aging. Development of Time of Flight Secondary Ion Mass Spectroscopy

    SciTech Connect (OSTI)

    Venhaus, Thomas J.

    2015-09-09

    The first application of Time-of-Flight Secondary Ion Mass Spectroscopy (ToF-SIMS) to an aged plutonium surface has resulted in a rich set of surface chemistry data, as well as some unexpected results. FY15 was highlighted by not only the first mapping of hydrogen-containing features within the metal, but also a prove-in series of experiments using the systems Sieverts Reaction Cell. These experiments involved successfully heating the sample to ~450 oC for nearly 24 hours while the sample was dosed several times with hydrogen, followed by an in situ ToF-SIMS analysis. During this year, the data allowed for better and more consistent identification of the myriad peaks that result from the SIMS sputter process. In collaboration with the AWE (U.K), the system was also fully aligned for sputter depth profiling for future experiments.

  4. Soft Landing of Mass-Selected Gold Clusters: Influence of Ion and Ligand on Charge Retention and Reactivity

    SciTech Connect (OSTI)

    Johnson, Grant E.; Laskin, Julia

    2015-02-01

    Herein, we employ a combination of reduction synthesis in solution, soft landing of mass-selected precursor and product ions, and in situ time-of-flight secondary ion mass spectrometry (TOF-SIMS) to examine the influence of ion and the length of diphosphine ligands on the charge retention and reactivity of ligated gold clusters deposited onto self-assembled monolayer surfaces (SAMs). Product ions (Au10L42+, (10,4)2+, L = 1,3-bis(diphenyl-phosphino)propane, DPPP) were prepared through in-source collision induced dissociation (CID) and precursor ions [(8,4)2+, L = 1,6-bis(diphenylphosphino)hexane, DPPH] were synthesized in solution for comparison to (11,5)3+ precursor ions ligated with DPPP investigated previously (ACS Nano 2012, 6, 573 and J. Phys. Chem. C. 2012, 116, 24977). Similar to (11,5)3+ precursor ions, the (10,4)2+ product ions are shown to retain charge on 1H,1H,2H,2H-perfluorodecanethiol monolayers (FSAMs). Additional abundant peaks at higher m/z indicative of reactivity are observed in the TOF-SIMS spectrum of (10,4)2+ product ions that are not seen for (11,5)3+ precursor ions. The abundance of (10,4)2+ on 16-mercaptohexadecanoic acid (COOH-SAMs) is demonstrated to be lower than on FSAMs, consistent with partial reduction of charge. The (10,4)2+ product ion on 1-dodecanethiol (HSAMs) exhibits peaks similar to those seen on the COOH-SAM. On the HSAM, higher m/z peaks indicative of reactivity are observed similar to those on the FSAM. The (8,4)2+ DPPH precursor ions are shown to retain charge on FSAMs similar to (11,5)3+ precursor ions prepared with DPPP. An additional peak corresponding to attachment of one gold atom to (8,4)2+ is observed at higher m/z for DPPH-ligated clusters. On the COOH-SAM, (8,4)2+ is less abundant than on the FSAM consistent with partial neutralization. The results indicate that although retention of charge by product ions generated by CID is similar to precursor ions their reactivity during analysis with SIMS is different resulting in the formation of peaks corresponding to reaction products. The length of the ligand exerts only a minor influence on the charge retention and reactivity of gold clusters. Based on the observed reactivity of (10,4)2+ it is anticipated that in-source CID will be increasingly applied for the preparation of a distribution of product ions, including undercoordinated and reactive species, for soft landing onto surfaces.

  5. In Situ SIMS and IR Spectroscopy of Well-Defined Surfaces Prepared by Soft Landing of Mass-Selected Ions

    SciTech Connect (OSTI)

    Johnson, Grant E.; Gunaratne, Kalupathirannehelage Don D.; Laskin, Julia

    2014-06-16

    Soft landing of mass-selected ions onto surfaces is a powerful approach for the highly-controlled preparation of materials that are inaccessible using conventional synthesis techniques. Coupling soft landing with in situ characterization using secondary ion mass spectrometry (SIMS) and infrared reflection absorption spectroscopy (IRRAS) enables analysis of well-defined surfaces under clean vacuum conditions. The capabilities of three soft-landing instruments constructed in our laboratory are illustrated for the representative system of surface-bound organometallics prepared by soft landing of mass-selected ruthenium tris(bipyridine) dications, [Ru(bpy)3]2+, onto carboxylic acid terminated self-assembled monolayer surfaces on gold (COOH-SAMs). In situ time-of-flight (TOF)-SIMS provides insight into the reactivity of the soft-landed ions. In addition, the kinetics of charge reduction, neutralization and desorption occurring on the COOH-SAM both during and after ion soft landing are studied using in situ Fourier transform ion cyclotron resonance (FT-ICR)-SIMS measurements. In situ IRRAS experiments provide insight into how the structure of organic ligands surrounding metal centers is perturbed through immobilization of organometallic ions on COOH-SAM surfaces by soft landing. Collectively, the three instruments provide complementary information about the chemical composition, reactivity and structure of well-defined species supported on surfaces.

  6. Investigations into the origins of polyatomic ions in inductively coupled plasma-mass spectrometry

    SciTech Connect (OSTI)

    McIntyre, Sally M.

    2010-05-16

    An inductively coupled plasma-mass spectrometer (ICP-MS) is an elemental analytical instrument capable of determining nearly all elements in the periodic table at limits of detection in the parts per quadrillion and with a linear analytical range over 8-10 orders of magnitude. Three concentric quartz tubes make up the plasma torch. Argon gas is spiraled through the outer tube and generates the plasma powered by a looped load coil operating at 27.1 or 40.6 MHz. The argon flow of the middle channel is used to keep the plasma above the innermost tube through which solid or aqueous sample is carried in a third argon stream. A sample is progressively desolvated, atomized and ionized. The torch is operated at atmospheric pressure. To reach the reduced pressures of mass spectrometers, ions are extracted through a series of two, approximately one millimeter wide, circular apertures set in water cooled metal cones. The space between the cones is evacuated to approximately one torr. The space behind the second cone is pumped down to, or near to, the pressure needed for the mass spectrometer (MS). The first cone, called the sampler, is placed directly in the plasma plume and its position is adjusted to the point where atomic ions are most abundant. The hot plasma gas expands through the sampler orifice and in this expansion is placed the second cone, called the skimmer. After the skimmer traditional MS designs are employed, i.e. quadrupoles, magnetic sectors, time-of-flight. ICP-MS is the leading trace element analysis technique. One of its weaknesses are polyatomic ions. This dissertation has added to the fundamental understanding of some of these polyatomic ions, their origins and behavior. Although mainly continuing the work of others, certain novel approaches have been introduced here. Chapter 2 includes the first reported efforts to include high temperature corrections to the partition functions of the polyatomic ions in ICP-MS. This and other objections to preceeding papers in this area were addressed. Errors in the measured T{sub gas} values were found for given errors in the experimental and spectroscopic values. The ionization energy of the neutral polyatomic ion was included in calculations to prove the validity of ignoring more complicated equilibria. Work was begun on the question of agreement between kinetics of the plasma and interface and the increase and depletion seen in certain polyatomic ions. This dissertation was also the first to report day to day ranges for T{sub gas} values and to use a statistical test to compare different operating conditions. This will help guide comparisons of previous and future work. Chapter 4 was the first attempt to include the excited electronic state 2 in the partition function of ArO{sup +} as well as the first to address the different dissociation products of the ground and first electronic levels of ArO{sup +}. Chapter 5 reports an interesting source of memory in ICP-MS that could affect mathematical corrections for polyatomic ions. For future work on these topics I suggest the following experiments and investigations. Clearly not an extensive list, they are instead the first topics curiosity brings to mind. (1) Measurement of T{sub gas} values when using the flow injection technique of Appendix B. It was believed that there was a fundamental difference in the plasma when the auto-sampler was used versus a continuous injection. Is this reflected in T{sub gas} values? (2) The work of Chapter 3 can be expanded and supplemented with more trials, new cone materials (i.e. copper, stainless steel) and more cone geometries. Some of this equipment is already present in the laboratory, others could be purchased or made. (3) T{sub gas} values from Chapter 3 could be correlated with instrument pressures during the experiment. Pressures after the skimmer cone were recorded for many days but have yet to be collated with the measured T{sub gas} values. (4) The work in Chapter 5 could be expanded to include more metals. Does the curious correlation between measured T{sub gas} and element boili

  7. Validating mass spectrometry measurements of nuclear materials via a non-contact volume analysis method of ion sputter craters

    SciTech Connect (OSTI)

    Willingham, David G.; Naes, Benjamin E.; Fahey, Albert J.

    2015-01-01

    A combination of secondary ion mass spectrometry, optical profilometry and a statistically-driven algorithm was used to develop a non-contact volume analysis method to validate the useful yields of nuclear materials. The volume analysis methodology was applied to ion sputter craters created in silicon and uranium substrates sputtered by 18.5 keV O- and 6.0 keV Ar+ ions. Sputter yield measurements were determined from the volume calculations and were shown to be comparable to Monte Carlo calculations and previously reported experimental observations. Additionally, the volume calculations were used to determine the useful yields of Si+, SiO+ and SiO2+ ions from the silicon substrate and U+, UO+ and UO2+ ions from the uranium substrate under 18.5 keV O- and 6.0 keV Ar+ ion bombardment. This work represents the first steps toward validating the interlaboratory and cross-platform performance of mass spectrometry for the analysis of nuclear materials.

  8. Characterization of Interlayer Cs+ in Clay Samples Using Secondary Ion Mass Spectrometry with Laser Sample Modification

    SciTech Connect (OSTI)

    G. S. Groenewold; R. Avci; C. Karahan; K. Lefebre; R. V. Fox; M. M. Cortez; A. K. Gianotto; J. Sunner; W. L. Manner

    2004-04-01

    Ultraviolet laser irradiation was used to greatly enhance the secondary ion mass spectrometry (SIMS) detection of Cs+ adsorbed to soil consisting of clay and quartz. Imaging SIMS showed that the enhancement of the Cs+ signal was spatially heterogeneous: the intensity of the Cs+ peak was increased by factors up to 100 for some particles but not at all for others. Analysis of standard clay samples exposed to Cs+ showed a variable response to laser irradiation depending on the type of clay analyzed. The Cs+ abundance was significantly enhanced when Cs+-exposed montmorillonite was irradiated and then analyzed using SIMS, which contrasted with the behavior of Cs+-exposed kaolinite, which displayed no Cs+ enhancement. Exposed illitic clays displayed modest enhancement of Cs+ upon laser irradiation, intermediate between that of kaolinite and montmorillonite. The results for Cs+ were rationalized in terms of adsorption to interlayer sites within the montmorillonite, which is an expandable phyllosilicate. In these locations, Cs+ was not initially detectable using SIMS. Upon irradiation, Cs+ was thermally redistributed, which enabled detection using SIMS. Since neither the illite nor the kaolinite is an expandable clay, adsorption to inner-layer sites does not occur, and either modest or no laser enhancement of the Cs+ signal is observed. Laser irradiation also produced unexpected enhancement of Ti+ from illite and kaolinite clays that contained small quantities of Ti, which indicates the presence of microscopic titanium oxide phases in the clay materials.

  9. Ion funnel with extended mass range and reduced conductance limit aperture

    DOE Patents [OSTI]

    Tolmachev, Aleksey V. (Richland, WA); Smith, Richard D. (Richland, WA)

    2008-04-01

    An improved ion funnel design is disclosed that decreases the axial RF (parasite) fields at the ion funnel exit. This is achieved by addition of one or more compensation electrodes after the conductance limit electrode. Various RF voltage profiles may be applied to the various electrodes minimizing the parasite axial potential wells. The smallest RF aperture that serves as the conductance limiting electrode is further reduced over standard designs. Overall, the ion funnel improves transmission ranges of both low m/z and high m/z ions, reducing RF activation of ions and decreasing the gas load to subsequent differential pumping stages.

  10. Extended ion energetics data base for mass spectrometric characterization of energy related pollutants. Final report

    SciTech Connect (OSTI)

    Parr, A.C.

    1983-01-01

    This project funded research at NBS from September, 1982 until November, 1983 and represented a continuation of an effort in precision ion thermochemistry measurements and calculations. The effort was divided into two main areas: laboratory effort using threshold photoelectron-photoion coincidence spectroscopy and a theoretical effort in ion energetics estimation schemes.

  11. Total cyanide mass measurement with micro-ion selective electrode for determination of specific activity of carbon-11 cyanide

    SciTech Connect (OSTI)

    Shea, Colleen; Alexoff, David L.; Kim, Dohyun; Hoque, Ruma; Schueller, Michael J.; Fowler, Joanna S.; Qu, Wenchao

    2015-04-25

    In this study, we aim to directly measure the specific activity (SA) of the carbon-11 cyanide ([11C]CN¯) produced by our in-house built automated [11C]HCN production system and to identify the major sources of 12C-cyanide (12CN¯). The [11C]CN¯ is produced from [11C]CO2, which is generated by the 14N(p,α)11C nuclear reaction using a cyclotron. Direct measurement of cyanide concentrations was accomplished using a relatively inexpensive, and easy to use ion selective electrode (ISE) which offered an appropriate range of sensitivity for detecting mass. Multiple components of the [11C]HCN production system were isolated in order to determine their relative contributions to 12CN¯ mass. It was determined that the system gases were responsible for approximately 30% of the mass, and that the molecular sieve/nickel furnace unit contributed approximately 70% of the mass. Beam on target (33 µA for 1 and 10 min) did not contribute significantly to the mass. Additionally, we compared the SA of our [11C]HCN precursor determined using the ISE to the SA of our current [11C]CN¯ derived radiotracers determined by HPLC to assure there was no significant difference between the two methods. These results are the first reported use of an ion selective electrode to determine the SA of no-carrier-added cyanide ion, and clearly show that it is a valuable, inexpensive and readily available tool suitable for this purpose.

  12. Total cyanide mass measurement with micro-ion selective electrode for determination of specific activity of carbon-11 cyanide

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Shea, Colleen; Alexoff, David L.; Kim, Dohyun; Hoque, Ruma; Schueller, Michael J.; Fowler, Joanna S.; Qu, Wenchao

    2015-04-25

    In this study, we aim to directly measure the specific activity (SA) of the carbon-11 cyanide ([11C]CN¯) produced by our in-house built automated [11C]HCN production system and to identify the major sources of 12C-cyanide (12CN¯). The [11C]CN¯ is produced from [11C]CO2, which is generated by the 14N(p,α)11C nuclear reaction using a cyclotron. Direct measurement of cyanide concentrations was accomplished using a relatively inexpensive, and easy to use ion selective electrode (ISE) which offered an appropriate range of sensitivity for detecting mass. Multiple components of the [11C]HCN production system were isolated in order to determine their relative contributions to 12CN¯ mass.more » It was determined that the system gases were responsible for approximately 30% of the mass, and that the molecular sieve/nickel furnace unit contributed approximately 70% of the mass. Beam on target (33 µA for 1 and 10 min) did not contribute significantly to the mass. Additionally, we compared the SA of our [11C]HCN precursor determined using the ISE to the SA of our current [11C]CN¯ derived radiotracers determined by HPLC to assure there was no significant difference between the two methods. These results are the first reported use of an ion selective electrode to determine the SA of no-carrier-added cyanide ion, and clearly show that it is a valuable, inexpensive and readily available tool suitable for this purpose.« less

  13. In-situ Mass Spectrometric Determination of Molecular Structural Evolution at the Solid Electrolyte Interphase in Lithium-Ion Batteries

    SciTech Connect (OSTI)

    Zhu, Zihua; Zhou, Yufan; Yan, Pengfei; Vemuri, Venkata Rama Ses; Xu, Wu; Zhao, Rui; Wang, Xuelin; Thevuthasan, Suntharampillai; Baer, Donald R.; Wang, Chong M.

    2015-08-19

    Dynamic molecular evolution at solid/liquid electrolyte interface is always a mystery for a rechargeable battery due to the challenge to directly probe/observe the solid/liquid interface under reaction conditions, which in essence appears to be similarly true for all the fields involving solid/liquid phases, such as electrocatalysis, electrodeposition, biofuel conversion, biofilm, and biomineralization, We use in-situ liquid secondary ion mass spectroscopy (SIMS) for the first time to directly observe the molecular structural evolution at the solid electrode/liquid electrolyte interface for a lithium (Li)-ion battery under dynamic operating conditions. We have discovered that the deposition of Li metal on copper electrode leads to the condensation of solvent molecules around the electrode. Chemically, this layer of solvent condensate tends to deplete the salt anion and with low concentration of Li+ ions, which essentially leads to the formation of a lean electrolyte layer adjacent to the electrode and therefore contributes to the overpotential of the cell. This unprecedented molecular level dynamic observation at the solid electrode/liquid electrolyte interface provides vital chemical information that is needed for designing of better battery chemistry for enhanced performance, and ultimately opens new avenues for using liquid SIMS to probe molecular evolution at solid/liquid interface in general.

  14. The Radial Loss of Ions Trapped in the Thermal Barrier Potential and the Design of Divertor Magnetic Field in GAMMA10

    SciTech Connect (OSTI)

    Katanuma, I. [Plasma Research Center, University of Tsukuba (Japan); Ito, T. [Plasma Research Center, University of Tsukuba (Japan); Saimaru, H. [Plasma Research Center, University of Tsukuba (Japan); Sasagawa, Y. [Plasma Research Center, University of Tsukuba (Japan); Pastukhov, V.P. [I.V.Kuruchatov Atomic Energy Institute (Russian Federation); Ishii, K. [Plasma Research Center, University of Tsukuba (Japan); Tatematsu, Y. [Plasma Research Center, University of Tsukuba (Japan); Saito, T. [Plasma Research Center, University of Tsukuba (Japan); Islam, Md.K. [Plasma Research Center, University of Tsukuba (Japan); Nakashima, Y. [Plasma Research Center, University of Tsukuba (Japan); Cho, T. [Plasma Research Center, University of Tsukuba (Japan)

    2005-01-15

    The ion radial loss exists in the presence of a non-axisymmetric electrostatic potential in the end-mirror cells of GAMMA10, which leads to a formation of the thermal barrier potential. The non-axisymmetric electrostatic potential can also exist in the central cell. A design for divertor magnetic field of GAMMA10 is performed, the purpose of which is first to reduce an ion radial transport in the central cell by making electrostatic potential circular and second to assure the macroscopic plasma stability of GAMMA10 without help of non-axisymmetric anchor cells which enhances a neoclassical radial transport.

  15. Ion mass spectrometry investigations of the discharge during reactive high power pulsed and direct current magnetron sputtering of carbon in Ar and Ar/N{sub 2}

    SciTech Connect (OSTI)

    Schmidt, S.; Greczynski, G.; Jensen, J.; Hultman, L.; Czigany, Zs.

    2012-07-01

    Ion mass spectrometry was used to investigate discharges formed during high power impulse magnetron sputtering (HiPIMS) and direct current magnetron sputtering (DCMS) of a graphite target in Ar and Ar/N{sub 2} ambient. Ion energy distribution functions (IEDFs) were recorded in time-averaged and time-resolved mode for Ar{sup +}, C{sup +}, N{sub 2}{sup +}, N{sup +}, and C{sub x}N{sub y}{sup +} ions. An increase of N{sub 2} in the sputter gas (keeping the deposition pressure, pulse width, pulse frequency, and pulse energy constant) results for the HiPIMS discharge in a significant increase in C{sup +}, N{sup +}, and CN{sup +} ion energies. Ar{sup +}, N{sub 2}{sup +}, and C{sub 2}N{sup +} ion energies, in turn, did not considerably vary with the changes in working gas composition. The HiPIMS process showed higher ion energies and fluxes, particularly for C{sup +} ions, compared to DCMS. The time evolution of the plasma species was analyzed for HiPIMS and revealed the sequential arrival of working gas ions, ions ejected from the target, and later during the pulse-on time molecular ions, in particular CN{sup +} and C{sub 2}N{sup +}. The formation of fullerene-like structured CN{sub x} thin films for both modes of magnetron sputtering is explained by ion mass-spectrometry results and demonstrated by transmission electron microscopy as well as diffraction.

  16. A frequency and amplitude scanned quadrupole mass filter for the analysis of high m/z ions

    SciTech Connect (OSTI)

    Shinholt, Deven L.; Anthony, Staci N.; Alexander, Andrew W.; Draper, Benjamin E.; Jarrold, Martin F.

    2014-11-15

    Quadrupole mass filters (QMFs) are usually not used to analyze high m/z ions, due to the low frequency resonant circuit that is required to drive them. Here we describe a new approach to generating waveforms for QMFs. Instead of scanning the amplitude of a sine wave to measure the m/z spectrum, the frequency of a trapezoidal wave is digitally scanned. A synchronous, narrow-range (<0.2%) amplitude scan overlays the frequency scan to improve the sampling resolution. Because the frequency is the primary quantity that is scanned, there is, in principle, no upper m/z limit. The frequency signal is constructed from a stabilized base clock using a field programmable gate array. This signal drives integrating amplifiers which generate the trapezoidal waves. For a trapezoidal wave the harmonics can be minimized by selecting the appropriate rise and fall times. To achieve a high resolving power, the digital signal has low jitter, and the trapezoidal waveform is generated with high fidelity. The QMF was characterized with cesium iodide clusters. Singly and multiply charged clusters with z up to +5 were observed. A resolving power of ∼1200 (FWHM) was demonstrated over a broad m/z range. Resolution was lost above 20 000 Th, partly because of congestion due to overlapping multiply charged clusters. Ions were observed for m/z values well in excess of 150 000 Th.

  17. Light Trapping, Absorption and ...

    Office of Scientific and Technical Information (OSTI)

    ... Trapping and Solar Energy Harvesting" IEEE Symposium on Photonic Crystals, City ... France, July 1-4, 2012 14. " Solar light trapping in 3D photonic crystal thin-films", IEEE ...

  18. Coverage Dependent Charge Reduction of Cationic Gold Clusters on Surfaces Prepared Using Soft Landing of Mass-selected Ions

    SciTech Connect (OSTI)

    Johnson, Grant E.; Priest, Thomas A.; Laskin, Julia

    2012-11-29

    The ionic charge state of monodisperse cationic gold clusters on surfaces may be controlled by selecting the coverage of mass-selected ions soft landed onto a substrate. Polydisperse diphosphine-capped gold clusters were synthesized in solution by reduction of chloro(triphenylphosphine)gold(I) with borane tert-butylamine in the presence of 1,3-bis(diphenylphosphino)propane. The polydisperse gold clusters were introduced into the gas phase by electrospray ionization and mass selection was employed to select a multiply charged cationic cluster species (Au11L53+, m/z = 1409, L = 1,3-bis(diphenylphosphino)propane) which was delivered to the surfaces of four different self-assembled monolayers on gold (SAMs) at coverages of 1011 and 1012 clusters/mm2. Employing the spatial profiling capabilities of in-situ time-of-flight secondary ion mass spectrometry (TOF-SIMS) it is shown that, in addition to the chemical functionality of the monolayer (as demonstrated previously: ACS Nano, 2012, 6, 573) the coverage of cationic gold clusters on the surface may be used to control the distribution of ionic charge states of the soft-landed multiply charged clusters. In the case of a 1H,1H,2H,2H-perfluorodecanethiol SAM (FSAM) almost complete retention of charge by the deposited Au11L53+ clusters was observed at a lower coverage of 1011 clusters/mm2. In contrast, at a higher coverage of 1012 clusters/mm2, pronounced reduction of charge to Au11L52+ and Au11L5+ was observed on the FSAM. When soft landed onto 16- and 11-mercaptohexadecanoic acid surfaces on gold (16,11-COOH-SAMs), the mass-selected Au11L53+ clusters exhibited partial reduction of charge to Au11L52+ at lower coverage and additional reduction of charge to both Au11L52+ and Au11L5+ at higher coverage. The reduction of charge was found to be more pronounced on the surface of the shorter (thinner) C11 than the longer (thicker) C16-COOH-SAM. On the surface of the 1-dodecanethiol (HSAM) monolayer, the most abundant charge state was found to be Au11L52+ at lower coverage and Au11L5+ at higher coverage, respectively. A coverage-dependent electron tunneling mechanism is proposed to account for the observed reduction of charge of mass-selected multiply charged gold clusters soft landed on SAMs. The results demonstrate that one of the critical parameters that influence the chemical and physical properties of supported metal clusters, ionic charge state, may be controlled by selecting the coverage of charged species soft landed onto surfaces.

  19. Microfabricated ion frequency standard

    DOE Patents [OSTI]

    Schwindt, Peter (Albuquerque, NM); Biedermann, Grant (Albuquerque, NM); Blain, Matthew G. (Albuquerque, NM); Stick, Daniel L. (Albuquerque, NM); Serkland, Darwin K. (Albuquerque, NM); Olsson, III, Roy H. (Albuquerque, NM)

    2010-12-28

    A microfabricated ion frequency standard (i.e. an ion clock) is disclosed with a permanently-sealed vacuum package containing a source of ytterbium (Yb) ions and an octupole ion trap. The source of Yb ions is a micro-hotplate which generates Yb atoms which are then ionized by a ultraviolet light-emitting diode or a field-emission electron source. The octupole ion trap, which confines the Yb ions, is formed from suspended electrodes on a number of stacked-up substrates. A microwave source excites a ground-state transition frequency of the Yb ions, with a frequency-doubled vertical-external-cavity laser (VECSEL) then exciting the Yb ions up to an excited state to produce fluorescent light which is used to tune the microwave source to the ground-state transition frequency, with the microwave source providing a precise frequency output for the ion clock.

  20. Experimental Evaluation and Optimization of Structures for Lossless Ion Manipulations for Ion Mobility Spectrometry with Time-of-Flight Mass Spectrometry

    SciTech Connect (OSTI)

    Webb, Ian K.; Garimella, Venkata BS; Tolmachev, Aleksey V.; Chen, Tsung-Chi; Zhang, Xinyu; Norheim, Randolph V.; Prost, Spencer A.; Lamarche, Brian L.; Anderson, Gordon A.; Ibrahim, Yehia M.; Smith, Richard D.

    2014-09-05

    We report on the performance of Structures for Lossless Ion Manipulation (SLIM) devices as a means for transmitting ions and performing ion mobility separations (IMS). Ions were successfully transferred from an electrospray ionization (ESI) source to the TOF MS analyzer by means of a linear SLIM device and an alternative arrangement including a 90 turn. First, the linear geometry was optimized for radial confinement by tuning RF on the central rung electrodes and potentials on the DC-only guard electrodes. Selecting an appropriate DC guard bias (2-6 V) and RF amplitude (?160 Vp-p at 750 kHz) resulted in the greatest ion intensities. Close to ideal IMS resolving power was maintained over a range of applied voltages. Second, the 90 turn was optimized for radial confinement by tuning the RF on the rung electrodes and DC on the guard electrodes; however, both resolving power and ion transmission showed a dependence on these voltages and the best conditions for both were > 300 Vp-p RF (685 kHz) and 7-11 V guard DC bias. Both geometries provide IMS resolving powers at the theoretical limit (R~58), showing that the negative racetrack effect from turning around a corner can be successfully avoided, as well as the capability for essentially lossless ion transmission.

  1. Extending the frontiers of mass spectrometric instrumentation and methods

    SciTech Connect (OSTI)

    Schieffer, Gregg

    2010-12-15

    The focus of this dissertation is two-fold: developing novel analysis methods using mass spectrometry and the implementation and characterization of a novel ion mobility mass spectrometry instrumentation. The novel mass spectrometry combines ion trap for ion/ion reactions coupled to an ion mobility cell. The long term goal of this instrumentation is to use ion/ion reactions to probe the structure of gas phase biomolecule ions. The three ion source - ion trap - ion mobility - qTOF mass spectrometer (IT - IM - TOF MS) instrument is described. The analysis of the degradation products in coal (Chapter 2) and the imaging plant metabolites (Appendix III) fall under the methods development category. These projects use existing commercial instrumentation (JEOL AccuTOF MS and Thermo Finnigan LCQ IT, respectively) for the mass analysis of the degraded coal products and the plant metabolites, respectively. The coal degradation paper discusses the use of the DART ion source for fast and easy sample analysis. The sample preparation consisted of a simple 50 fold dilution of the soluble coal products in water and placing the liquid in front of the heated gas stream. This is the first time the DART ion source has been used for analysis of coal. Steven Raders under the guidance of John Verkade came up with the coal degradation projects. Raders performed the coal degradation reactions, worked up the products, and sent them to me. Gregg Schieffer developed the method and wrote the paper demonstrating the use of the DART ion source for the fast and easy sample analysis. The plant metabolite imaging project extends the use of colloidal graphite as a sample coating for atmospheric pressure LDI. DC Perdian and I closely worked together to make this project work. Perdian focused on building the LDI setup whereas Schieffer focused on the MSn analysis of the metabolites. Both Perdian and I took the data featured in the paper. Perdian was the primary writer of the paper and used it as a chapter in his dissertation. Perdian and Schieffer worked together to address the revisions and publish it in Rapid Communications in Mass Spectrometry Journal.

  2. Simplifying steam trap selection

    SciTech Connect (OSTI)

    Debat, R.J. )

    1994-01-01

    In the current economic world order, there is an obligation to eliminate waste and conserve economic and natural resources. One trap blowing 100-lb of steam through a 1/4-in. orifice can cost more than $12,000 a year in wasted energy. Richard J. Debat of Armstrong International, Inc. explains the operating principles of the four basic types of steam traps as the first step in simplifying the selection process so the right trap can be specified for a given application.

  3. Steam trap monitor

    DOE Patents [OSTI]

    Ryan, M.J.

    1987-05-04

    A steam trap monitor positioned downstream of a steam trap in a closed steam system includes a first sensor (a hot finger) for measuring the energy of condensate and a second sensor (a cold finger) for measuring the total energy of condensate and steam in the line. The hot finger includes one or more thermocouples for detecting condensate level and energy, while the cold finger contains a liquid with a lower boiling temperature than that of water. Vapor pressure from the liquid is used to do work such as displacing a piston or bellow in providing an indication of total energy (steam + condensate) of the system. Processing means coupled to and responsive to outputs from the hot and cold fingers subtracts the former from the latter to provide an indication of the presence of steam downstream from the trap indicating that the steam trap is malfunctioning. 2 figs.

  4. A Thomson-type mass and energy spectrometer for characterizing ion energy distributions in a coaxial plasma gun operating in a gas-puff mode

    SciTech Connect (OSTI)

    Rieker, G. B.; Poehlmann, F. R.; Cappelli, M. A.

    2013-07-15

    Measurements of ion energy distribution are performed in the accelerated plasma of a coaxial electromagnetic plasma gun operating in a gas-puff mode at relatively low discharge energy (900 J) and discharge potential (4 kV). The measurements are made using a Thomson-type mass and energy spectrometer with a gated microchannel plate and phosphor screen as the ion sensor. The parabolic ion trajectories are captured from the sensor screen with an intensified charge-coupled detector camera. The spectrometer was designed and calibrated using the Geant4 toolkit, accounting for the effects on the ion trajectories of spatial non-uniformities in the spectrometer magnetic and electric fields. Results for hydrogen gas puffs indicate the existence of a class of accelerated protons with energies well above the coaxial discharge potential (up to 24 keV). The Thomson analyzer confirms the presence of impurities of copper and iron, also of relatively high energies, which are likely erosion or sputter products from plasma-electrode interactions.

  5. Laser ablation-inductively coupled plasma-mass spectrometry: Examinations of the origins of polyatomic ions and advances in the sampling of particulates

    SciTech Connect (OSTI)

    Witte, Travis

    2011-11-30

    This dissertation provides a general introduction to Inductively coupled plasma-mass spectrometry (ICP-MS) and laser ablation (LA) sampling, with an examination of analytical challenges in the employment of this technique. It discusses the origin of metal oxide ions (MO+) in LA-ICP-MS, as well as the effect of introducing helium and nitrogen to the aerosol gas flow on the formation of these polyatomic interferences. It extends the study of polyatomic ions in LA-ICP-MS to metal argide (MAr+) species, an additional source of possible significant interferences in the spectrum. It describes the application of fs-LA-ICP-MS to the determination of uranium isotope ratios in particulate samples.

  6. Method and apparatus for confinement of ions in the presence of a neutral gas

    DOE Patents [OSTI]

    Peurrung, A.J.; Barlow, S.E.

    1999-08-03

    The present invention is an apparatus and method for combining ions with a neutral gas and flowing the mixture with a radial flow component through a magnetic field so that the weakly ionized gas is confined by the neutral gas. When the weakly ionized gas is present in sufficient density, a weakly ionized non-neutral plasma is formed that may be trapped in accordance with the present invention. Applications for a weakly ionized non-neutral plasma exploit the trap`s ability to store and manipulate ionic species in the presence of neutral gas. The trap may be connected to a mass spectrometer thereby permitting species identification after a fixed period of time. Delicate and/or heavy particles such as clusters may be held and studied in a ``gentle`` environment. In addition, the trap can provide a relatively intense, low-energy source of a particular ion species for surface implantation or molecular chemistry. Finally, a long trap may permit spectroscopy of unprecedented accuracy to be performed on ionic species. 4 figs.

  7. Ionization-Induced Electron Trapping inUltrarelativistic Plasma Wakes

    SciTech Connect (OSTI)

    Oz, E.; Deng, S.; Katsouleas, T.; Muggli, P.; Barnes, C.D.; Blumenfeld, I.; Decker, F.J.; Emma, P.; Hogan, M.J.; Ischebeck, R.; Iverson, R.H.; Kirby, N.; Krejcik, P.; O'Connell, C.; Siemann, R.H.; Walz, D.; Auerbach, D.; Clayton, C.E.; Huang, C.; Johnson, D.K.; Joshi, C.; /UCLA

    2007-04-06

    The onset of trapping of electrons born inside a highly relativistic, 3D beam-driven plasma wake is investigated. Trapping occurs in the transition regions of a Li plasma confined by He gas. Li plasma electrons support the wake, and higher ionization potential He atoms are ionized as the beam is focused by Li ions and can be trapped. As the wake amplitude is increased, the onset of trapping is observed. Some electrons gain up to 7.6 GeV in a 30.5 cm plasma. The experimentally inferred trapping threshold is at a wake amplitude of 36 GV/m, in good agreement with an analytical model and PIC simulations.

  8. WATER-TRAPPED WORLDS

    SciTech Connect (OSTI)

    Menou, Kristen [Department of Astronomy, Columbia University, 550 West 120th Street, New York, NY 10027 (United States)

    2013-09-01

    Although tidally locked habitable planets orbiting nearby M-dwarf stars are among the best astronomical targets to search for extrasolar life, they may also be deficient in volatiles and water. Climate models for this class of planets show atmospheric transport of water from the dayside to the nightside, where it is precipitated as snow and trapped as ice. Since ice only slowly flows back to the dayside upon accumulation, the resulting hydrological cycle can trap a large amount of water in the form of nightside ice. Using ice sheet dynamical and thermodynamical constraints, I illustrate how planets with less than about a quarter the Earth's oceans could trap most of their surface water on the nightside. This would leave their dayside, where habitable conditions are met, potentially dry. The amount and distribution of residual liquid water on the dayside depend on a variety of geophysical factors, including the efficiency of rock weathering at regulating atmospheric CO{sub 2} as dayside ocean basins dry up. Water-trapped worlds with dry daysides may offer similar advantages as land planets for habitability, by contrast with worlds where more abundant water freely flows around the globe.

  9. Steam trap monitor

    DOE Patents [OSTI]

    Ryan, Michael J. (Plainfield, IL)

    1988-01-01

    A steam trap monitor positioned downstream of a steam trap in a closed steam system includes a first sensor (the combination of a hot finger and thermocouple well) for measuring the energy of condensate and a second sensor (a cold finger) for measuring the total energy of condensate and steam in the line. The hot finger includes one or more thermocouples for detecting condensate level and energy, while the cold finger contains a liquid with a lower boiling temperature than that of water. Vapor pressure from the liquid is used to do work such as displacing a piston or bellows in providing an indication of total energy (steam+condensate) of the system. Processing means coupled to and responsive to outputs from the thermocouple well hot and cold fingers subtracts the condensate energy as measured by the hot finger and thermocouple well from the total energy as measured by the cold finger to provide an indication of the presence of steam downstream from the trap indicating that the steam trap is malfunctioning.

  10. SIEMENS ADVANCED QUANTRA FTICR MASS SPECTROMETER FOR ULTRA HIGH RESOLUTION AT LOW MASS

    SciTech Connect (OSTI)

    Spencer, W; Laura Tovo, L

    2008-07-08

    The Siemens Advanced Quantra Fourier Transform Ion Cyclotron Resonance (FTICR) mass spectrometer was evaluated as an alternative instrument to large double focusing mass spectrometers for gas analysis. High resolution mass spectrometers capable of resolving the common mass isomers of the hydrogen isotopes are used to provide data for accurate loading of reservoirs and to monitor separation of tritium, deuterium, and helium. Conventional double focusing magnetic sector instruments have a resolution that is limited to about 5000. The Siemens FTICR instrument achieves resolution beyond 400,000 and could possibly resolve the tritium ion from the helium-3 ion, which differ by the weight of an electron, 0.00549 amu. Working with Y-12 and LANL, SRNL requested Siemens to modify their commercial Quantra system for low mass analysis. To achieve the required performance, Siemens had to increase the available waveform operating frequency from 5 MHz to 40 MHz and completely redesign the control electronics and software. However, they were able to use the previous ion trap, magnet, passive pump, and piezo-electric pulsed inlet valve design. NNSA invested $1M in this project and acquired four systems, two for Y-12 and one each for SRNL and LANL. Siemens claimed a $10M investment in the Quantra systems. The new Siemens Advanced Quantra demonstrated phenomenal resolution in the low mass range. Resolution greater than 400,000 was achieved for mass 2. The new spectrometer had a useful working mass range to 500 Daltons. However, experiments found that a continuous single scan from low mass to high was not possible. Two useful working ranges were established covering masses 1 to 6 and masses 12 to 500 for our studies. A compromise performance condition enabled masses 1 to 45 to be surveyed. The instrument was found to have a dynamic range of about three orders of magnitude and quantitative analysis is expected to be limited to around 5 percent without using complex fitting algorithms. Analysis of low concentration ions, at the ppm level, required a separate analysis using ion ejection techniques. Chemical ionization due to the formation of the MH{sup +} ion or MD{sup +} increased the complexity of the spectra compared to magnetic sector mass spectra and formation of the protonated or deuterated complex was a dynamic function of the trap ion concentration. This made quantitative measurement more of a challenge. However, the resolution of the instrument was far superior to any other mass spectrometry technique that has been applied to the analysis of the hydrogen isotopes. The piezo-electric picoliter injection device offers a new way of submitting small quantities of atmospheric pressure sample gas for analysis. The new software had many improvements over the previous version but significant flaws in the beta codes remain that make the prototype units less than ideal. The instrument is a promising new technology that experience will likely improve. Unfortunately, Siemens has concluded that the technology will not be a commercial success and has decided to stop producing this product.

  11. Dynamical Dipole Mode in Heavy-Ion Fusion-Evaporation and Fission Reactions in the {sup 192}Pb Mass Region

    SciTech Connect (OSTI)

    Silvestri, R.; Inglima, G.; La Commara, M.; Martin, B.; Sandoli, M.; Pierroutsakou, D.; Parascandolo, C.; Boiano, A.; Romoli, M.; Agodi, C.; Alba, R.; Colonna, M.; Coniglione, R.; Del Zoppo, A.; Maiolino, C.; Santonocito, D.; Baran, V.; De Filippo, E.; Di Toro, M.; Rizzo, C.

    2011-10-28

    The prompt {gamma}-ray emission related with the dynamical dipole mode decay was investigated in the {sup 192}Pb mass region by means of the {sup 40}Ca+{sup 152}Sm and {sup 48}Ca+{sup 144}Sm fusion-evaporation and fission reactions at E{sub lab} = 11 and 10.1 MeV/nucleon, respectively. The two reactions populate, through entrance channel having different charge asymmetries, the {sup 192}Pb compound nucleus at an excitation energy of 236 MeV with identical spin distribution. Preliminary results of this experiment show that the dynamical dipole mode survives in collisions involving heavier mass reaction partners than those studied previously. As a fast cooling mechanism on the fusion path, the prompt dipole {gamma} radiation could be of interest for the synthesis of super-heavy elements through ''hot'' fusion reactions.

  12. Radial cold trap

    DOE Patents [OSTI]

    Grundy, Brian R. (Greensburg, PA)

    1981-01-01

    The radial cold trap comprises a housing having a plurality of mesh bands disposed therein. The mesh bands comprise concentrically arranged bands of mesh with the mesh specific surface area of each band increasing from the outermost mesh band to the innermost mesh band. An inlet nozzle is attached to the outside section of the housing while an outlet nozzle is attached to the inner portion of the housing so as to be concentrically connected to the innermost mesh band. An inlet baffle having orifices therein may be disposed around the outermost mesh band and within the housing for directing the flow of the fluid from the inlet nozzle to the outermost mesh band in a uniform manner. The flow of fluid passes through each consecutive mesh band and into the outlet nozzle. The circular pattern of the symmetrically arranged mesh packing allows for better utilization of the entire cold trap volume.

  13. Radial cold trap

    DOE Patents [OSTI]

    Grundy, B.R.

    1981-09-29

    The radial cold trap comprises a housing having a plurality of mesh bands disposed therein. The mesh bands comprise concentrically arranged bands of mesh with the mesh specific surface area of each band increasing from the outermost mesh band to the innermost mesh band. An inlet nozzle is attached to the outside section of the housing while an outlet nozzle is attached to the inner portion of the housing so as to be concentrically connected to the innermost mesh band. An inlet baffle having orifices therein may be disposed around the outermost mesh band and within the housing for directing the flow of the fluid from the inlet nozzle to the outermost mesh band in a uniform manner. The flow of fluid passes through each consecutive mesh band and into the outlet nozzle. The circular pattern of the symmetrically arranged mesh packing allows for better utilization of the entire cold trap volume. 2 figs.

  14. Method and apparatus for confinement of ions in the presence of a neutral gas

    DOE Patents [OSTI]

    Peurrung, Anthony J.; Barlow, Stephan E.

    1999-01-01

    The present invention is an apparatus and method for combining ions with a neutral gas and flowing the mixture with a radial flow component through a magnetic field so that the weakly ionized gas is confined by the neutral gas. When the weakly ionized gas is present in sufficient density, a weakly ionized non-neutral plasma is formed that may be trapped in accordance with the present invention. Applications for a weakly ionized non-neutral plasma exploit the trap's ability to store and manipulate ionic species in the presence of neutral gas. The trap may be connected to a mass spectrometer thereby permitting species identification after a fixed period of time. Delicate and/or heavy particles such as clusters may be held and studied in a "gentle" environment. In addition, the trap can provide a relatively intense, low-energy source of a particular ion species for surface implantation or molecular chemistry. Finally, a long trap may permit spectroscopy of unprecedented accuracy to be performed on ionic species.

  15. Microchip and wedge ion funnels and planar ion beam analyzers using same

    DOE Patents [OSTI]

    Shvartsburg, Alexandre A; Anderson, Gordon A; Smith, Richard D

    2012-10-30

    Electrodynamic ion funnels confine, guide, or focus ions in gases using the Dehmelt potential of oscillatory electric field. New funnel designs operating at or close to atmospheric gas pressure are described. Effective ion focusing at such pressures is enabled by fields of extreme amplitude and frequency, allowed in microscopic gaps that have much higher electrical breakdown thresholds in any gas than the macroscopic gaps of present funnels. The new microscopic-gap funnels are useful for interfacing atmospheric-pressure ionization sources to mass spectrometry (MS) and ion mobility separation (IMS) stages including differential IMS or FAIMS, as well as IMS and MS stages in various configurations. In particular, "wedge" funnels comprising two planar surfaces positioned at an angle and wedge funnel traps derived therefrom can compress ion beams in one dimension, producing narrow belt-shaped beams and laterally elongated cuboid packets. This beam profile reduces the ion density and thus space-charge effects, mitigating the adverse impact thereof on the resolving power, measurement accuracy, and dynamic range of MS and IMS analyzers, while a greater overlap with coplanar light or particle beams can benefit spectroscopic methods.

  16. Structural phase transitions and topological defects in ion Coulomb crystals

    SciTech Connect (OSTI)

    Partner, Heather L.; Nigmatullin, Ramil; Burgermeister, Tobias; Keller, Jonas; Pyka, Karsten; Plenio, Martin B.; Retzker, Alex; Zurek, Wojciech Hubert; del Campo, Adolfo; Mehlstaubler, Tanja E.

    2014-11-19

    We use laser-cooled ion Coulomb crystals in the well-controlled environment of a harmonic radiofrequency ion trap to investigate phase transitions and defect formation. Topological defects in ion Coulomb crystals (kinks) have been recently proposed for studies of nonlinear physics with solitons and as carriers of quantum information. Defects form when a symmetry breaking phase transition is crossed non-adiabatically. For a second order phase transition, the Kibble-Zurek mechanism predicts that the formation of these defects follows a power law scaling in the rate of the transition. We demonstrate a scaling of defect density and describe kink dynamics and stability. We further discuss the implementation of mass defects and electric fields as first steps toward controlled kink preparation and manipulation.

  17. Final Technical Report for DE-FG02-06ER15835: Chemical Imaging with 100nm Spatial Resolution: Combining High Resolution Flurosecence Microscopy and Ion Mobility Mass Spectrometry

    SciTech Connect (OSTI)

    Buratto, Steven K.

    2013-09-03

    We have combined, in a single instrument, high spatial resolution optical microscopy with the chemical specificity and conformational selectivity of ion mobility mass spectrometry. We discuss the design and construction of this apparatus as well as our efforts in applying this technique to thin films of molecular semiconductor materials.

  18. Electron Trapping by Molecular Vibration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electron Trapping by Molecular Vibration Print In photoelectron spectroscopy experiments performed at the ALS, a group of researchers has found that electronic transitions normally...

  19. Greenpower Trap Mufflerl System

    Energy Savers [EERE]

    Water GREENPOWER TRAP-MUFFLER(tm) System (US Patent #6892531, 5085049, PCT, others pending) www.dieselnet.com/dr.rim Catalyst/DPF EGR Accumulator Air Intake Filter Turbo Charger Engine Intercooler EGR+water vapor Clean Exhaust PM 93% NOx 50% ECU E-Igniter FBC/OBC Water Lubrication Fuel + FBC Emissions Test Results Verified by Japan Automotive Research Inst., Tokyo, Japan 0 1 2 3 4 5 6 Before After NOx 2.676 5.51 g/kwH 51.4% 0 0.05 0.1 0.15 0.2 0.25 0.3 Before After PM g/kwH 0.278 0.03 89.2% NOx

  20. Adiabatic electron response and solitary wave generation by trapped particle nonlinearity in a hydrogen plasma

    SciTech Connect (OSTI)

    Mandal, Debraj; Sharma, Devendra [Institute for Plasma Research, Bhat, Gandhinagar 382428 (India)

    2014-10-15

    The finite amplitude ion acoustic waves that trap electrons modify the structure of the evolving nonlinear soliton solutions. In the numerical simulations, self-consistently generated solitary waves are studied that emerge as a result of a current driven microinstability growing the ion acoustic mode in a collisionless Vlasov plasma. The growth saturates as a result of nonlinear effects governed by a combination of nonlinearities originating from the hydrodynamic model and kinetic particle trapping effects. The resulting solitary waves also coexist with a finite current and an electron plasma wave capable of perturbing the trapping potential. The results of multiscale simulation are analyzed and characterized following the kinetic prescription of undamped trapped particle mode in the form of phase space vortex solutions that are generalized form of Sagdeev's solitons and obey the solutions of a modified Korteweg-de Vries equation, accounting for a stronger nonlinearity originating from the electron trapping.

  1. Mass measurements near the Z = N line with JYFLTRAP

    SciTech Connect (OSTI)

    Kankainen, Anu; Collaboration: JYFLTRAP Collaboration

    2011-11-30

    Masses of nuclides involved in astrophysical rp and {nu}p processes have to be known precisely in order to model these processes reliably. Mass excesses for 90 ground state and 8 isomeric states of neutron-deficient nuclides have been determined with a precision of better than 10 keV with the JYFLTRAP double Penning trap mass spectrometer at the Ion-Guide Isotope Separator On-Line facility in Jyvaeskylae. Highlights of the measurements related to nuclear astrophysics are given. Some of the measured isomers, such as {sup 53}Co{sup m}, {sup 90}Tc{sup m}, and {sup 95}Pd{sup m}, and implications for the excitation energy of the 21{sup +} isomer in {sup 94}Ag are briefly discussed.

  2. Thermostatic steam trap

    SciTech Connect (OSTI)

    Anderson, A.H.; Mac Nicol, A.E.

    1987-03-03

    A thermostatic trap is described for a heating system having a feed pipe connected to a source of steam and a discharge pipe for discharge of condensate and comprising: housing means defining a volume and comprising a bowl shaped body, a removable cover therefor, a housing inlet pipe portion projecting from a side wall portion of the body and adapted for connection to the discharge pipe. A housing outlet pipe portion projects from a bottom wall portion of the body, and an outlet orifice defined by the bottom wall portion and extends between the volume and the outlet pipe portion; a valve body means retained within the volume and comprising an end wall, a side wall and a retaining ring portion that together define a valve chamber. The end wall defines a valve inlet opening communicating with the chamber and an annular valve seat within the chamber and encircling the valve inlet opening. The valve body means comprises a valve outlet pipe that defines a valve outlet opening axially aligned with the valve inlet opening and communicating with the chamber, the outlet pipe being fixed in the outlet orifice; a resilient, annular seal means disposed within the valve chamber and encircling the valve inlet opening; and a bi-metallic disc disposed within the valve chamber between the annular seal means and the outlet opening and having an outer peripheral portion retained by the retaining ring portion of the valve body means.

  3. Protection #2: Trap and Remove Sediment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Trap and Remove Sediment Protection 2: Trap and Remove Sediment The 3 Protections Defense in Depth August 1, 2013 Sediment behind LA Canyon weir is sampled and excavated...

  4. Ruthenium trisbipyridine as a candidate for gas-phase spectroscopic studies in a Fourier transform mass spectrometer

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Scott, Jill R.; Ham, Jason E.; Durham, Bill; Tremblay, Paul L.

    2004-01-01

    Metal polypyridines are excellent candidates for gas-phase optical experiments where their intrinsic properties can be studied without complications due to the presence of solvent. The fluorescence lifetimes of [Ru(bpy) 3 ] 1+ trapped in an optical detection cell within a Fourier transform mass spectrometer were obtained using matrix-assisted laser desorption/ionization to generate the ions with either 2,5-dihydroxybenzoic acid (DHB) or sinapinic acid (SA) as matrix. All transients acquired, whether using DHB or SA for ion generation, were best described as approximately exponential decays. The rate constant for transients derived using DHB as matrix was 4×10 7 s −1 ,more » while the rate constant using SA was 1×10 7 s −1 . Some suggestions of multiple exponential decay were evident although limited by the quality of the signals. Photodissociation experiments revealed that [Ru(bpy) 3 ] 1+ generated using DHB can decompose to [Ru(bpy) 2 ] 1+ , whereas ions generated using SA showed no decomposition. Comparison of the mass spectra with the fluorescence lifetimes illustrates the promise of incorporating optical detection with trapped ion mass spectrometry techniques.« less

  5. Inspect and Repair Steam Traps

    SciTech Connect (OSTI)

    Not Available

    2006-01-01

    This revised ITP tip sheet on inspecting and repairing steam traps provide how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  6. Hydrodynamic enhanced dielectrophoretic particle trapping

    DOE Patents [OSTI]

    Miles, Robin R.

    2003-12-09

    Hydrodynamic enhanced dielectrophoretic particle trapping carried out by introducing a side stream into the main stream to squeeze the fluid containing particles close to the electrodes producing the dielelectrophoretic forces. The region of most effective or the strongest forces in the manipulating fields of the electrodes producing the dielectrophoretic forces is close to the electrodes, within 100 .mu.m from the electrodes. The particle trapping arrangement uses a series of electrodes with an AC field placed between pairs of electrodes, which causes trapping of particles along the edges of the electrodes. By forcing an incoming flow stream containing cells and DNA, for example, close to the electrodes using another flow stream improves the efficiency of the DNA trapping.

  7. Electron Trapping by Molecular Vibration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electron Trapping by Molecular Vibration Print In photoelectron spectroscopy experiments performed at the ALS, a group of researchers has found that electronic transitions normally thought to be forbidden can in fact be excited in conjunction with certain types of molecular vibrations. Specifically, they found that when the symmetry of a linear triatomic molecule is broken by asymmetric vibrational modes, photoelectrons can become temporarily trapped by the molecule before ultimately escaping,

  8. Electron Trapping by Molecular Vibration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electron Trapping by Molecular Vibration Print In photoelectron spectroscopy experiments performed at the ALS, a group of researchers has found that electronic transitions normally thought to be forbidden can in fact be excited in conjunction with certain types of molecular vibrations. Specifically, they found that when the symmetry of a linear triatomic molecule is broken by asymmetric vibrational modes, photoelectrons can become temporarily trapped by the molecule before ultimately escaping,

  9. Electron Trapping by Molecular Vibration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electron Trapping by Molecular Vibration Print In photoelectron spectroscopy experiments performed at the ALS, a group of researchers has found that electronic transitions normally thought to be forbidden can in fact be excited in conjunction with certain types of molecular vibrations. Specifically, they found that when the symmetry of a linear triatomic molecule is broken by asymmetric vibrational modes, photoelectrons can become temporarily trapped by the molecule before ultimately escaping,

  10. Electron Trapping by Molecular Vibration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electron Trapping by Molecular Vibration Print In photoelectron spectroscopy experiments performed at the ALS, a group of researchers has found that electronic transitions normally thought to be forbidden can in fact be excited in conjunction with certain types of molecular vibrations. Specifically, they found that when the symmetry of a linear triatomic molecule is broken by asymmetric vibrational modes, photoelectrons can become temporarily trapped by the molecule before ultimately escaping,

  11. Electron Trapping by Molecular Vibration

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electron Trapping by Molecular Vibration Electron Trapping by Molecular Vibration Print Wednesday, 27 April 2005 00:00 In photoelectron spectroscopy experiments performed at the ALS, a group of researchers has found that electronic transitions normally thought to be forbidden can in fact be excited in conjunction with certain types of molecular vibrations. Specifically, they found that when the symmetry of a linear triatomic molecule is broken by asymmetric vibrational modes, photoelectrons can

  12. Imaging mass spectrometer with mass tags

    DOE Patents [OSTI]

    Felton, James S.; Wu, Kuang Jen; Knize, Mark G.; Kulp, Kristen S.; Gray, Joe W.

    2010-06-01

    A method of analyzing biological material by exposing the biological material to a recognition element, that is coupled to a mass tag element, directing an ion beam of a mass spectrometer to the biological material, interrogating at least one region of interest area from the biological material and producing data, and distributing the data in plots.

  13. Imaging mass spectrometer with mass tags

    DOE Patents [OSTI]

    Felton, James S.; Wu, Kuang Jen J.; Knize, Mark G.; Kulp, Kristen S.; Gray, Joe W.

    2013-01-29

    A method of analyzing biological material by exposing the biological material to a recognition element, that is coupled to a mass tag element, directing an ion beam of a mass spectrometer to the biological material, interrogating at least one region of interest area from the biological material and producing data, and distributing the data in plots.

  14. Computer analysis of sodium cold trap design and performance. [LMFBR

    SciTech Connect (OSTI)

    McPheeters, C.C.; Raue, D.J.

    1983-11-01

    Normal steam-side corrosion of steam-generator tubes in Liquid Metal Fast Breeder Reactors (LMFBRs) results in liberation of hydrogen, and most of this hydrogen diffuses through the tubes into the heat-transfer sodium and must be removed by the purification system. Cold traps are normally used to purify sodium, and they operate by cooling the sodium to temperatures near the melting point, where soluble impurities including hydrogen and oxygen precipitate as NaH and Na/sub 2/O, respectively. A computer model was developed to simulate the processes that occur in sodium cold traps. The Model for Analyzing Sodium Cold Traps (MASCOT) simulates any desired configuration of mesh arrangements and dimensions and calculates pressure drops and flow distributions, temperature profiles, impurity concentration profiles, and impurity mass distributions.

  15. Single event mass spectrometry

    DOE Patents [OSTI]

    Conzemius, Robert J. (Ames, IA)

    1990-01-16

    A means and method for single event time of flight mass spectrometry for analysis of specimen materials. The method of the invention includes pulsing an ion source imposing at least one pulsed ion onto the specimen to produce a corresponding emission of at least one electrically charged particle. The emitted particle is then dissociated into a charged ion component and an uncharged neutral component. The ion and neutral components are then detected. The time of flight of the components are recorded and can be used to analyze the predecessor of the components, and therefore the specimen material. When more than one ion particle is emitted from the specimen per single ion impact, the single event time of flight mass spectrometer described here furnis This invention was made with Government support under Contract No. W-7405-ENG82 awarded by the Department of Energy. The Government has certain rights in the invention.

  16. Electrospray Ionization Mass Spectrometry

    SciTech Connect (OSTI)

    Kelly, Ryan T.; Marginean, Ioan; Tang, Keqi

    2014-06-13

    Electrospray Ionization (ESI) is a process whereby gas phase ions are created from molecules in solution. As a solution exits a narrow tube in the presence of a strong electric field, an aerosol of charged droplets are is formed that produces gas phase ions as they it desolvates. ESI-MS comprises the creation of ions by ESI and the determination of their mass to charge ratio (m/z) by MS.

  17. Method for calibrating mass spectrometers

    DOE Patents [OSTI]

    Anderson, Gordon A [Benton City, WA; Brands, Michael D [Richland, WA; Bruce, James E [Schwenksville, PA; Pasa-Tolic, Ljiljana [Richland, WA; Smith, Richard D [Richland, WA

    2002-12-24

    A method whereby a mass spectra generated by a mass spectrometer is calibrated by shifting the parameters used by the spectrometer to assign masses to the spectra in a manner which reconciles the signal of ions within the spectra having equal mass but differing charge states, or by reconciling ions having known differences in mass to relative values consistent with those known differences. In this manner, the mass spectrometer is calibrated without the need for standards while allowing the generation of a highly accurate mass spectra by the instrument.

  18. Ion manipulation device

    DOE Patents [OSTI]

    Anderson, Gordon A; Smith, Richard D; Ibrahim, Yehia M; Baker, Erin M

    2014-09-16

    An ion manipulation method and device is disclosed. The device includes a pair of substantially parallel surfaces. An array of inner electrodes is contained within, and extends substantially along the length of, each parallel surface. The device includes a first outer array of electrodes and a second outer array of electrodes. Each outer array of electrodes is positioned on either side of the inner electrodes, and is contained within and extends substantially along the length of each parallel surface. A DC voltage is applied to the first and second outer array of electrodes. A RF voltage, with a superimposed electric field, is applied to the inner electrodes by applying the DC voltages to each electrode. Ions either move between the parallel surfaces within an ion confinement area or along paths in the direction of the electric field, or can be trapped in the ion confinement area.

  19. Note: High density pulsed molecular beam for cold ion chemistry

    SciTech Connect (OSTI)

    Kokish, M. G.; Rajagopal, V.; Marler, J. P.; Odom, B. C.

    2014-08-15

    A recent expansion of cold and ultracold molecule applications has led to renewed focus on molecular species preparation under ultrahigh vacuum conditions. Meanwhile, molecular beams have been used to study gas phase chemical reactions for decades. In this paper, we describe an apparatus that uses pulsed molecular beam technology to achieve high local gas densities, leading to faster reaction rates with cold trapped ions. We characterize the beam's spatial profile using the trapped ions themselves. This apparatus could be used for preparation of molecular species by reactions requiring excitation of trapped ion precursors to states with short lifetimes or for obtaining a high reaction rate with minimal increase of background chamber pressure.

  20. Guide to Orifice Plate Steam Traps

    SciTech Connect (OSTI)

    Oland, C.B.

    2001-01-11

    This guide was prepared to serve as a foundation for making informed decisions about when orifice plate steam traps should be considered for use in new or existing steam systems. It presents background information about different types of steam traps and defines their unique functional and operational characteristics. The advantages and disadvantages associated with using orifice plate steam traps are provided to highlight their capabilities and limitations. Finally, recommendations for using orifice plate steam traps are presented, and possible applications are identified.

  1. Significant in-medium {eta}{sup '} mass reduction in {radical}(s{sub NN}) = 200 GeV Au+Au collisions at the BNL Relativistic Heavy Ion Collider

    SciTech Connect (OSTI)

    Vertesi, R.; Sziklai, J.; Csoergo, T.

    2011-05-15

    In high-energy heavy ion collisions a hot and dense medium is formed, where the U{sub A}(1) or chiral symmetry may temporarily be restored. As a consequence, the mass of the {eta}{sup '}(958) mesons may be reduced to its quark model value, and the abundance of {eta}{sup '} mesons at low p{sub T} may be enhanced by more than a factor of 10. The intercept parameter {lambda}{sub *} of the charged pion Bose Einstein correlations provides a sensitive observable of the possibly enhanced {eta}{sup '} abundance. We have analyzed {lambda}{sub *}(m{sub T}) data from {radical}(s{sub N{sub N}})=200 GeV central Au+Au reactions measured at the BNL Relativistic Heavy Ion Collider (RHIC), using extensive Monte Carlo simulations based on six popular models for hadronic multiplicities. Based on the combined STAR and PHENIX data set, and on various systematic investigations of resonance multiplicities and model parameters, we conclude that in {radical}(s{sub N{sub N}})=200 GeV central Au+Au reactions the mass of the {eta}{sup '} meson is reduced by {Delta}m{sub {eta}}{sup '*}>200 MeV, at the 99.9% confidence level in the considered model class. Such a significant {eta}{sup '} mass modification may indicate the restoration of the U{sub A}(1) symmetry in a hot and dense hadronic matter and the return of the ninth ''prodigal'' Goldstone boson. A similar analysis of NA44 S+Pb data at top CERN Super Proton Synchroton (SPS) energies showed no significant in-medium {eta}{sup '} mass modification.

  2. An Adaptable Multiple Power Source for Mass Spectrometry and other Scientific Instruments

    SciTech Connect (OSTI)

    Lin, Tzu-Yung; Anderson, Gordon A.; Norheim, Randolph V.; Prost, Spencer A.; Lamarche, Brian L.; Leach, Franklin E.; Auberry, Kenneth J.; Smith, Richard D.; Koppenaal, David W.; Robinson, Errol W.; Pasa-Tolic, Ljiljana

    2015-09-18

    Power supplies are commonly used in the operation of many types of scientific equipment, including mass spectrometers and ancillary instrumentation. A generic modern mass spectrometer comprises an ionization source, such as electrospray ionization (ESI), ion transfer devices such as ion funnels and multipole ion guides, and ion signal detection apparatus. Very often such platforms include, or are interfaced with ancillary elements in order to manipulate samples before or after ionization. In order to operate such scientific instruments, numerous direct current (DC) channels and radio frequency (RF) signals are required, along with other controls such as temperature regulation. In particular, DC voltages in the range of 400 V, along with MHz range RF signals with peak-to-peak amplitudes in the hundreds of volts range are commonly used to transfer ionized samples under vacuum. Additionally, an ESI source requires a high voltage (HV) DC source capable of producing several thousand volts and heaters capable of generating temperatures up to 300C. All of these signals must be properly synchronized and managed in order to carry out ion trapping, accumulation and detection.

  3. A new detector for mass spectrometry: Direct detection of low...

    Office of Scientific and Technical Information (OSTI)

    A new detector for mass spectrometry: Direct detection of low energy ions using a ... Subject: 46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND TECHNOLOGY; CRYSTALS; ION ...

  4. Inspect and Repair Steam Traps, Energy Tips: STEAM, Steam Tip...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    leaking traps should account for less than 5% of the trap population. If your steam distribution system includes more than 500 traps, a steam trap survey will probably reveal...

  5. Heavy Ions - 88-Inch Cyclotron

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Heavy Ions Heavy ions used at the BASE Facility are accelerated in the form of "cocktails," named because of the fact that several heavy ions with the same mass-to-charge ratio are sent into the Cyclotron, which accelerates the ions while acting as a precision mass separator. The Control Room Operator then uses Cyclotron frequency to select only the desired ion, a process that takes about 2 minutes. We provide four standard cocktails: 4.5, 10, 16, and 30 MeV/nucleon. Depending on the

  6. Secondary ion collection and transport system for ion microprobe

    DOE Patents [OSTI]

    Ward, James W. (Canoga Park, CA); Schlanger, Herbert (Simi Valley, CA); McNulty, Jr., Hugh (Santa Monica, CA); Parker, Norman W. (Camarillo, CA)

    1985-01-01

    A secondary ion collection and transport system, for use with an ion microprobe, which is very compact and occupies only a small working distance, thereby enabling the primary ion beam to have a short focal length and high resolution. Ions sputtered from the target surface by the primary beam's impact are collected between two arcuate members having radii of curvature and applied voltages that cause only ions within a specified energy band to be collected. The collected ions are accelerated and focused in a transport section consisting of a plurality of spaced conductive members which are coaxial with and distributed along the desired ion path. Relatively high voltages are applied to alternate transport sections to produce accelerating electric fields sufficient to transport the ions through the section to an ion mass analyzer, while lower voltages are applied to the other transport sections to focus the ions and bring their velocity to a level compatible with the analyzing apparatus.

  7. Higher order QED in high-mass e{sup +}e{sup -} pair production at energies available at the BNL Relativistic Heavy Ion Collider (RHIC)

    SciTech Connect (OSTI)

    Baltz, Anthony J.; Nystrand, Joakim

    2010-08-15

    Lowest order and higher order QED calculations have been carried out for the RHIC high mass e{sup +}e{sup -} pairs observed by PHENIX with single zero-degree-calorimeter triggers. The lowest order QED results for the experimental acceptance are about two standard deviations larger than the PHENIX data. Corresponding higher order QED calculations are within one standard deviation of the data.

  8. Method and apparatuses for ion cyclotron spectrometry

    DOE Patents [OSTI]

    Dahl, David A. (Idaho Falls, ID); Scott, Jill R. (Idaho Falls, ID); McJunkin, Timothy R. (Idaho Falls, ID)

    2012-03-06

    An ion cyclotron spectrometer may include a vacuum chamber that extends at least along a z-axis and means for producing a magnetic field within the vacuum chamber so that a magnetic field vector is generally parallel to the z-axis. The ion cyclotron spectrometer may also include means for producing a trapping electric field within the vacuum chamber. The trapping electric field may comprise a field potential that, when taken in cross-section along the z-axis, includes at least one section that is concave down and at least one section that is concave up so that ions traversing the field potential experience a net magnetron effect on a cyclotron frequency of the ions that is substantially equal to zero. Other apparatuses and a method for performing ion cyclotron spectrometry are also disclosed herein.

  9. Linear electric field mass spectrometry

    DOE Patents [OSTI]

    McComas, David J. (Los Alamos, NM); Nordholt, Jane E. (Los Alamos, NM)

    1992-01-01

    A mass spectrometer and methods for mass spectrometry. The apparatus is compact and of low weight and has a low power requirement, making it suitable for use on a space satellite and as a portable detector for the presence of substances. High mass resolution measurements are made by timing ions moving through a gridless cylindrically symmetric linear electric field.

  10. Linear electric field mass spectrometry

    DOE Patents [OSTI]

    McComas, D.J.; Nordholt, J.E.

    1992-12-01

    A mass spectrometer and methods for mass spectrometry are described. The apparatus is compact and of low weight and has a low power requirement, making it suitable for use on a space satellite and as a portable detector for the presence of substances. High mass resolution measurements are made by timing ions moving through a gridless cylindrically symmetric linear electric field. 8 figs.

  11. Real-Time Particulate Mass Measurements Pre and Post Diesel Particulat...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Real-Time Particulate Mass Measurements Pre and Post Diesel Particulate Filters for ... Filter Loading and Regeneration Real-Time Measurement of Diesel Trap Efficiency ...

  12. Ion source

    DOE Patents [OSTI]

    Leung, Ka-Ngo (Hercules, CA); Ehlers, Kenneth W. (Alamo, CA)

    1984-01-01

    A magnetic filter for an ion source reduces the production of undesired ion species and improves the ion beam quality. High-energy ionizing electrons are confined by the magnetic filter to an ion source region, where the high-energy electrons ionize gas molecules. One embodiment of the magnetic filter uses permanent magnets oriented to establish a magnetic field transverse to the direction of travel of ions from the ion source region to the ion extraction region. In another embodiment, low energy 16 eV electrons are injected into the ion source to dissociate gas molecules and undesired ion species into desired ion species.

  13. Fluorohydrogenate Cluster Ions in the Gas Phase: Electrospray Ionization Mass Spectrometry of the [1-Ethyl-3-methylimidazolium+][F(HF)2.3] Ionic Liquid

    SciTech Connect (OSTI)

    Gary S. Groenewold; James E. Delmore; Michael T. Benson; Tetsuya Tsuda; Rika Hagiwara

    2013-12-01

    Electrospray ionization of the fluorohydrogenate ionic liquid [1-ethyl-3-methylimidazolium][F(HF)2.3] ionic liquid was conducted to understand the nature of the anionic species as they exist in the gas phase. Abundant fluorohydrogenate clusters were produced; however, the dominant anion in the clusters was [FHF-], and not the fluoride-bound HF dimers or trimers that are seen in solution. Density functional theory (DFT) calculations suggest that HF molecules are bound to the clusters by about 30 kcal/mol. The DFT-calculated structures of the [FHF-]-bearing clusters show that the favored interactions of the anions are with the methynic and acetylenic hydrogen atoms on the imidazolium cation, forming planar structures similar to those observed in the solid state. A second series of abundant negative ions was also formed that contained [SiF5-] together with the imidazolium cation and the fluorohydrogenate anions that originate from reaction of the spray solution with silicate surfaces.

  14. Cavity sideband cooling of trapped molecules

    SciTech Connect (OSTI)

    Kowalewski, Markus; Vivie-Riedle, Regina de [Department of Chemistry, Ludwig-Maximilian-Universitaet, D-81377 Munich (Germany); Morigi, Giovanna [Departament de Fisica, Universitat Autonoma de Barcelona, E-08193 Bellaterra (Spain); Theoretische Physik, Universitaet des Saarlandes, D-66041 Saarbruecken (Germany); Pinkse, Pepijn W. H. [MESA Institute for Nanotechnology, University of Twente, P.O. Box 217, 7500AE Enschede (Netherlands)

    2011-09-15

    The efficiency of cavity sideband cooling of trapped molecules is theoretically investigated for the case in which the infrared transition between two rovibrational states is used as a cycling transition. The molecules are assumed to be trapped either by a radiofrequency or optical trapping potential, depending on whether they are charged or neutral, and confined inside a high-finesse optical resonator that enhances radiative emission into the cavity mode. Using realistic experimental parameters and COS as a representative molecular example, we show that in this setup, cooling to the trap ground state is feasible.

  15. Porous materials with pre-designed single-molecule traps for CO2 selective adsorption

    SciTech Connect (OSTI)

    Li, JR; Yu, JM; Lu, WG; Sun, LB; Sculley, J; Balbuena, PB; Zhou, HC

    2013-02-26

    Despite tremendous efforts, precise control in the synthesis of porous materials with pre-designed pore properties for desired applications remains challenging. Newly emerged porous metal-organic materials, such as metal-organic polyhedra and metal-organic frameworks, are amenable to design and property tuning, enabling precise control of functionality by accurate design of structures at the molecular level. Here we propose and validate, both experimentally and computationally, a precisely designed cavity, termed a 'single-molecule trap', with the desired size and properties suitable for trapping target CO2 molecules. Such a single-molecule trap can strengthen CO2-host interactions without evoking chemical bonding, thus showing potential for CO2 capture. Molecular single-molecule traps in the form of metal-organic polyhedra are designed, synthesised and tested for selective adsorption of CO2 over N-2 and CH4, demonstrating the trapping effect. Building these pre-designed single-molecule traps into extended frameworks yields metal-organic frameworks with efficient mass transfer, whereas the CO2 selective adsorption nature of single-molecule traps is preserved.

  16. Measurements of PM Traps | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Measurements of PM Traps Measurements of PM Traps 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentantion: West Virginia University PDF icon 2004_deer_clark.pdf More Documents & Publications Investigation of the Effects of Fuels and Aftertreatment Devices on the Emission Profiles of Trucks and Buses DOE-HDBK-1132-99 DOE-HDBK-1132-99

  17. Ion/Surface Reactions and Ion Soft-Landing

    SciTech Connect (OSTI)

    Gologan, Bogdan; Green, Jason R.; Alvarez, Jormarie; Laskin, Julia; Cooks, Robert G.

    2005-02-08

    Ion/surface collision phenomena in the hyperthermal collision energy regime (1-100 eV) are reviewed, with emphasis on chemical processes associated with the impact of small organic and biological ions at functionalized self-assembled monolayer surfaces. Inelastic collisions can lead to excitation the projectile ion and can result in fragmentation, a process known as surface-induced dissociation which is useful in chemical analysis using tandem mass spectrometry.. Changes in charge can accompany ion/surface collisions and those associated with a change in polarity (positive to negative ions or vice-versa) are an attractive method for ion structural characterization and isomer differentiation. The energetics, thermochemistry and dynamics of surface-induced charge inversion of nitrobenzene and other substituted aromatics is discussed. Reactive collisions also occur between gaseous ions and surfaces and the reactions depend on the chemical nature of the collision partners. These reactions can be used for selected chemical modifications of surfaces as well as for surface analysis. Particular emphasis is given here to one ion/surface interaction, ion soft-landing, a process in which the projectile ion is landed intact at the surface, either as the corresponding neutral molecule or, interestingly but less commonly, in the form of the ion itself. The ion soft-landing experiment allows preparative mass spectrometry, for example the preparation of pure biological compounds by using the mass spectrometer as a separation device. After separation, the mass-selected ions are collected by soft-landing, at different spatial points in an array. If the experiment is done using a suitable liquid medium, at least some proteins retain their biological activity.

  18. Method for reduction of selected ion intensities in confined ion beams

    DOE Patents [OSTI]

    Eiden, G.C.; Barinaga, C.J.; Koppenaal, D.W.

    1998-06-16

    A method for producing an ion beam having an increased proportion of analyte ions compared to carrier gas ions is disclosed. Specifically, the method has the step of addition of a charge transfer gas to the carrier analyte combination that accepts charge from the carrier gas ions yet minimally accepts charge from the analyte ions thereby selectively neutralizing the carrier gas ions. Also disclosed is the method as employed in various analytical instruments including an inductively coupled plasma mass spectrometer. 7 figs.

  19. Method for reduction of selected ion intensities in confined ion beams

    DOE Patents [OSTI]

    Eiden, Gregory C. (Richland, WA); Barinaga, Charles J. (Richland, WA); Koppenaal, David W. (Richland, WA)

    1998-01-01

    A method for producing an ion beam having an increased proportion of analyte ions compared to carrier gas ions is disclosed. Specifically, the method has the step of addition of a charge transfer gas to the carrier analyte combination that accepts charge from the carrier gas ions yet minimally accepts charge from the analyte ions thereby selectively neutralizing the carrier gas ions. Also disclosed is the method as employed in various analytical instruments including an inductively coupled plasma mass spectrometer.

  20. Mass spectroscopic apparatus and method

    DOE Patents [OSTI]

    Bomse, David S. (Santa Fe, NM); Silver, Joel A. (Santa Fe, NM); Stanton, Alan C. (Santa Fe, NM)

    1991-01-01

    The disclosure is directed to a method and apparatus for ionization modulated mass spectrometric analysis. Analog or digital data acquisition and processing can be used. Ions from a time variant source are detected and quantified. The quantified ion output is analyzed using a computer to provide a two-dimensional representation of at least one component present within an analyte.

  1. The Paul Trap Simulator Experiment (PTSX) | Princeton Plasma...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    The Paul Trap Simulator Experiment (PTSX) The Paul Trap Simulator Experiment (PTSX) at the U.S. Department of Energy's Princeton Plasma Physics Laboratory doesn't trap people named...

  2. Detection method for dissociation of multiple-charged ions

    DOE Patents [OSTI]

    Smith, Richard D. (Richland, WA); Udseth, Harold R. (Richland, WA); Rockwood, Alan L. (Richland, WA)

    1991-01-01

    Dissociations of multiple-charged ions are detected and analyzed by charge-separation tandem mass spectrometry. Analyte molecules are ionized to form multiple-charged parent ions. A particular charge parent ion state is selected in a first-stage mass spectrometer and its mass-to-charge ratio (M/Z) is detected to determine its mass and charge. The selected parent ions are then dissociated, each into a plurality of fragments including a set of daughter ions each having a mass of at least one molecular weight and a charge of at least one. Sets of daughter ions resulting from the dissociation of one parent ion (sibling ions) vary in number but typically include two to four ions, one or more multiply-charged. A second stage mass spectrometer detects mass-to-charge ratio (m/z) of the daughter ions and a temporal or temporo-spatial relationship among them. This relationship is used to correlate the daughter ions to determine which (m/z) ratios belong to a set of sibling ions. Values of mass and charge of each of the sibling ions are determined simultaneously from their respective (m/z) ratios such that the sibling ion charges are integers and sum to the parent ion charge.

  3. Bear Trap Hot Spring Pool & Spa Low Temperature Geothermal Facility...

    Open Energy Info (EERE)

    Trap Hot Spring Pool & Spa Low Temperature Geothermal Facility Jump to: navigation, search Name Bear Trap Hot Spring Pool & Spa Low Temperature Geothermal Facility Facility Bear...

  4. Emittance and Current of Electrons Trapped in a Plasma Wakefield...

    Office of Scientific and Technical Information (OSTI)

    Emittance and Current of Electrons Trapped in a Plasma Wakefield Accelerator Citation Details In-Document Search Title: Emittance and Current of Electrons Trapped in a Plasma...

  5. Requirements-Driven Diesel Catalyzed Particulate Trap Design...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Requirements-Driven Diesel Catalyzed Particulate Trap Design and Optimization Requirements-Driven Diesel Catalyzed Particulate Trap Design and Optimization 2005 Diesel Engine...

  6. H2-Assisted NOx Traps: Test Cell Results Vehicle Installations...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    -Assisted NOx Traps: Test Cell Results Vehicle Installations H2-Assisted NOx Traps: Test Cell Results Vehicle Installations 2003 DEER Conference Presentation: ArvinMeritor PDF icon...

  7. Lean NOx Traps - Microstructural Studies of Real World and Model...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Traps - Microstructural Studies of Real World and Model Catalysts Lean NOx Traps - Microstructural Studies of Real World and Model Catalysts 2005 Diesel Engine Emissions Reduction...

  8. Dynamic trapping near a quantum critical point (Journal Article...

    Office of Scientific and Technical Information (OSTI)

    Dynamic trapping near a quantum critical point Citation Details In-Document Search Title: Dynamic trapping near a quantum critical point Authors: Kolodrubetz, Michael ; Katz, ...

  9. NAC 503 - Hunting, Fishing and Trapping | Open Energy Information

    Open Energy Info (EERE)

    Fishing and TrappingLegal Abstract These code sections outline the protective measures and restrictions on hunting, fishing, and trapping in the state of Nevada. Published...

  10. Mass measurements of rare isotopes with SHIPTRAP

    SciTech Connect (OSTI)

    Dworschak, M.

    2010-06-01

    The Penning-trap mass spectrometer SHIPTRAP was set up with the aim to perform high-precision mass measurements. Since autumn 2005, the masses of 63 neutron-deficient nuclides in the mass range from A = 80 to A = 254 have been determined with relative uncertainties of down to 10{sup -8}. Nuclides with half-lives down to 580 ms and production rates of less than one atom per minute were investigated. The results are valuable for nuclear structure investigations and nuclear astrophysics. The most remarkable successes were the first direct mass measurements beyond the proton drip line and in the region above Z = 100.

  11. November 18, 2010: Antimatter Trapped and Stored

    Broader source: Energy.gov [DOE]

    November 18, 2010The Department’s Lawrence Berkeley National Laboratory (LBNL) announces that atoms of antimatter have been trapped and stored for the first time in a magnetic bottle-like device by...

  12. Protection #2: Trap and Remove Sediment

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Trap and Remove Sediment Protection #2: Trap and Remove Sediment The 3 Protections = Defense in Depth August 1, 2013 Sediment behind LA Canyon weir is sampled and excavated regularly. As of 2012, no sediment required disposal as hazardous or radioactive waste. Sediment behind LA Canyon weir is sampled and excavated regularly. As of 2012, no sediment required disposal as hazardous or radioactive waste. The 3 Protections Protection #1: Remove the source of contamination Protection #2: Stabilize,

  13. Analysis of electron dynamics in non-ideal Penning traps

    SciTech Connect (OSTI)

    Coppa, G.; Mulas, R.; D'Angola, A.

    2012-06-15

    Penning traps that are used for particular applications, such as in ion pump technology, Larmor, bouncing, and diocotron frequencies, can be of the same order of magnitude. The paper deals with the dynamics of electrons confined in such devices starting from the study of the properties of the trajectories. In cases of interest, in which electron-neutral collision frequency is much smaller with respect to the characteristic frequencies of the motion, suitable time averages of the trajectories are introduced in order to simplify the analysis of the problem. In the work, time averages have been calculated in a simple way by using an approximate r-z decoupling of the effective potential. Results obtained with the method are presented and discussed in both linear and nonlinear regimes.

  14. Antihydrogen Trapped in the ALPHA Experiment

    ScienceCinema (OSTI)

    None

    2011-04-25

    In 2010 the ALPHA collaboration succeeded in trapping antihydrogen atoms for the first time.[i]  Stored antihydrogen promises to be a unique tool for making high precision measurements of the structure of this first anti-atom. Achieving this milestone presented several substantial experimental challenges and this talk will describe how they were overcome.   The unique design features of the ALPHA apparatus will be explained.[ii]  These allow a high intensity positron source and an antiproton imaging detector similar to the one used in the ATHENA[iii] experiment to be combined with an innovative magnet design of the anti-atom trap. This seeks to minimise the perturbations to trapped charged particles which may cause particle loss and heating[iv].   The diagnostic techniques used to measure the diameter, number, density, and temperatures of both plasmas will be presented as will the methods developed to actively compress and cool of both plasma species to sizes and temperatures [v],[vi], [vii] where trapping attempts with a reasonable chance of success can be tried.   The results of the successful trapping experiments will be outlined as well as some subsequent experiments to improve the trapping rate and storage time. [i] 'Trapped antihydrogen' G.B. Andresen et al., Nature 468, 673 (2010) [ii]'A Magnetic Trap for Antihydrogen Confinement' W. Bertsche et al., Nucl. Instr. Meth. Phys. Res. A566, 746 (2006) [iii] Production and detection of cold antihydrogen atoms M.Amoretti et al., Nature 419, 456 (2002). [iv]' Antihydrogen formation dynamics in a multipolar neutral anti-atom trap' G.B. Andresen et al., Phys. Lett. B 685, 141 (2010) [v]' Evaporative Cooling of Antiprotons to Cryogenic Temperatures',                                   G.B. Andresen et al. Phys. Rev. Lett 105, 013003 (2010) [vi]'Compression of Antiproton Clouds for Antihydrogen Trapping' G. B. Andresen et al. Phys. Rev. Lett 100, 203401 (2008) [vii]  'Autoresonant Excitation of Antiproton Plasmas' G.B. Andresen et al., Phys. Rev. Lett. 106, 025002 (2011) Organizer: Ferdinand Hahn PH/DT Detector Seminar webpage  

  15. High resolution mass spectrometry method and system for analysis of whole proteins and other large molecules

    DOE Patents [OSTI]

    Reilly, Peter T. A. (Knoxville, TN) [Knoxville, TN; Harris, William A. (Naperville, IL) [Naperville, IL

    2010-03-02

    A matrix assisted laser desorption/ionization (MALDI) method and related system for analyzing high molecular weight analytes includes the steps of providing at least one matrix-containing particle inside an ion trap, wherein at least one high molecular weight analyte molecule is provided within the matrix-containing particle, and MALDI on the high molecular weight particle while within the ion trap. A laser power used for ionization is sufficient to completely vaporize the particle and form at least one high molecular weight analyte ion, but is low enough to avoid fragmenting the high molecular weight analyte ion. The high molecular weight analyte ion is extracted out from the ion trap, and is then analyzed using a detector. The detector is preferably a pyrolyzing and ionizing detector.

  16. Characterization of trapped gas saturation and heterogeneity in core sampling using miscible-displacement experiments

    SciTech Connect (OSTI)

    Smith, D.H.; Jikich, S.A.

    1994-12-31

    Trapped gas saturation and permeability heterogeneity were evaluated in Berea cores at reservoir conditions, using standard miscible displacement experiments, with and without surfactants. Pressure and production history were influenced by core heterogeneity and foam lamellae formation when aqueous surfactant was present in the core. The objective of the dispersion-capacitance model was to estimate trapped gas saturations; however longitudinal dispersion and mass transfer also were examined. The results show that the dispersion-capacitance model accurately fits trapped gas saturation controlled by rock heterogeneities and foam lamellae for lamella generating mechanisms that allow a continuous gas phase (leave-behind lamellae). The practical applications resulting from this study can aid in core sample selection and scaling short laboratory corefloods to field dimensions for applications to foam stimulation and underground storage of natural gas.

  17. Rare-earth neutral metal injection into an electron beam ion...

    Office of Scientific and Technical Information (OSTI)

    injection into an electron beam ion trap plasma Authors: Magee, E W ; Beiersdorfer, P ; Brown, G V ; Hell, N Publication Date: 2014-05-28 OSTI Identifier: 1169881 Report Number(s):...

  18. Signal enhancement using a switchable magnetic trap

    DOE Patents [OSTI]

    Beer, Neil Reginald (Pleasanton, CA)

    2012-05-29

    A system for analyzing a sample including providing a microchannel flow channel; associating the sample with magnetic nanoparticles or magnetic polystyrene-coated beads; moving the sample with said magnetic nanoparticles or magnetic polystyrene-coated beads in the microchannel flow channel; holding the sample with the magnetic nanoparticles or magnetic polystyrene-coated beads in a magnetic trap in the microchannel flow channel; and analyzing the sample obtaining an enhanced analysis signal. An apparatus for analysis of a sample includes magnetic particles connected to the sample, a microchip, a flow channel in the microchip, a source of carrier fluid connected to the flow channel for moving the sample in the flow channel, an electromagnet trap connected to the flow line for selectively magnetically trapping the sample and the magnetic particles, and an analyzer for analyzing the sample.

  19. Thermal electric vapor trap arrangement and method

    DOE Patents [OSTI]

    Alger, Terry (Tracy, CA)

    1988-01-01

    A technique for trapping vapor within a section of a tube is disclosed herein. This technique utilizes a conventional, readily providable thermal electric device having a hot side and a cold side and means for powering the device to accomplish this. The cold side of this device is positioned sufficiently close to a predetermined section of the tube and is made sufficiently cold so that any condensable vapor passing through the predetermined tube section is condensed and trapped, preferably within the predetermined tube section itself.

  20. Thermal electric vapor trap arrangement and method

    DOE Patents [OSTI]

    Alger, T.

    1988-03-15

    A technique for trapping vapor within a section of a tube is disclosed herein. This technique utilizes a conventional, readily providable thermal electric device having a hot side and a cold side and means for powering the device to accomplish this. The cold side of this device is positioned sufficiently close to a predetermined section of the tube and is made sufficiently cold so that any condensable vapor passing through the predetermined tube section is condensed and trapped, preferably within the predetermined tube section itself. 4 figs.

  1. Geochemical Speciation Mass Transfer

    Energy Science and Technology Software Center (OSTI)

    1985-12-01

    PHREEQC is designed to model geochemical reactions. Based on an ion association aqueous model, PHREEQC can calculate pH, redox potential, and mass transfer as a function of reaction progress. It can be used to describe geochemical processes for both far-field and near-field performance assessment and to evaluate data acquisition needs and test data. It can also calculate the composition of solutions in equilibrium with multiple phases. The data base, including elements, aqueous species, and mineralmore » phases, is independent of the program and is completely user-definable. PHREEQC requires thermodynamic data for each solid, gaseous, or dissolved chemical species being modeled. The two data bases, PREPHR and DEQPAK7, supplied with PHREEQC are for testing purposes only and should not be applied to real problems without first being carefully examined. The conceptual model embodied in PHREEQC is the ion-association model of Pearson and Noronha. In this model a set of mass action equations are established for each ion pair (and controlling solid phases when making mass transfer calculations) along with a set of mass balance equations for each element considered. These sets of equations are coupled using activity coefficient values for each aqueous species and solved using a continued fraction approach for the mass balances combined with a modified Newton-Raphson technique for all other equations. The activity coefficient expressions in PHREEQC include the extended Debye-Huckel, WATEQ Debye-Huckel, and Davies equations from the original United States Geological Survey version of the program. The auxiliary preprocessor program PHTL, which is derived from EQTL, converts EQ3/6 thermodynamic data to PHREEQC format so that the two programs can be compared. PHREEQC can be used to determine solubility limits on the radionuclides present in the waste form. These solubility constraints may be input to the WAPPA leach model.« less

  2. Method and apparatus for ion cyclotron spectrometry

    DOE Patents [OSTI]

    Dahl, David A. (Idaho Falls, ID) [Idaho Falls, ID; Scott, Jill R. (Idaho Falls, ID) [Idaho Falls, ID; McJunkin, Timothy R. (Idaho Falls, ID) [Idaho Falls, ID

    2010-08-17

    An ion cyclotron spectrometer may include a vacuum chamber that extends at least along a z-axis and means for producing a magnetic field within the vacuum chamber so that a magnetic field vector is generally parallel to the z-axis. The ion cyclotron spectrometer may also include means for producing a trapping electric field within the vacuum chamber that includes at least a first section that induces a first magnetron effect that increases a cyclotron frequency of an ion and at least a second section that induces a second magnetron effect that decreases the cyclotron frequency of an ion. The cyclotron frequency changes induced by the first and second magnetron effects substantially cancel one another so that an ion traversing the at least first and second sections will experience no net change in cyclotron frequency.

  3. Bucket-type steam traps removed in $82K retrofit

    SciTech Connect (OSTI)

    Poplett, J.

    1985-08-19

    A retrofit of 481 mostly failed steam traps at Martin Marietta's Aerospace Division should reduce steam costs by $70,000 and require little or no maintenance. Payback should occur within 14 months. The new traps include orifice, bellow-type thermostatic, and float-type traps that have few or no moving parts. Lack of maintenance was responsible for the poor performance of the bucket traps that were replaced, although manufacturers of the bucket traps disagree that replacement of certain parts is necessary every six months. The author describes the design and operation of each type of trap.

  4. Magnetic Centrifugal Mass Filter Abraham J. Fetterman and Nathaniel J.

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Fisch | Princeton Plasma Physics Lab Magnetic Centrifugal Mass Filter Abraham J. Fetterman and Nathaniel J. Fisch This invention is of a magnetic centrifugal mass filter that can separate ions of different mass or ions of different energies into separate streams. The filter, which uses both the centrifugal and magnetic confinement of ions, can be used to separate radioactive fission products from nuclear waste or from spent nuclear fuel in a nonproliferative manner. No.: M-818

  5. Review of Orifice Plate Steam Traps | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Review of Orifice Plate Steam Traps Review of Orifice Plate Steam Traps This guide was prepared to serve as a foundation for making informed decisions about when orifice plate...

  6. Thermal Deactivation Mechanisms of Fully-Formed Lean NOx Trap...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Lean NOx Trap Catalysts Aged by LeanRich Cycling Catalysts in fully formulated lean NOx traps are aged and evaluated in a bench-flow reactor using simulated diesel...

  7. RYPOS Trap Field Demonstrations Part 1 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1 RYPOS Trap Field Demonstrations Part 1 2002 DEER Conference Presentation: RYPOS Inc. PDF icon 2002_deer_depetrillo1.pdf More Documents & Publications RYPOS Trap Field Demonstrations Part 2

  8. RYPOS Trap Field Demonstrations Part 2 | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2 RYPOS Trap Field Demonstrations Part 2 2002 DEER Conference Presentation: RYPOS Inc. PDF icon 2002_deer_depetrillo2.pdf More Documents & Publications RYPOS Trap Field Demonstrations Part 1

  9. Inspect and Repair Steam Traps | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Inspect and Repair Steam Traps Inspect and Repair Steam Traps This tip sheet on inspecting and repairing steam traps provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies. STEAM TIP SHEET #1 PDF icon Inspect and Repair Steam Traps (January 2012) More Documents & Publications Flash High-Pressure Condensate to Regenerate Low-Pressure Steam Use Steam Jet Ejectors or Thermocompressors to Reduce Venting of Low-Pressure Steam Recover Heat

  10. Emittance and Current of Electrons Trapped in a Plasma Wakefield

    Office of Scientific and Technical Information (OSTI)

    Accelerator (Conference) | SciTech Connect Emittance and Current of Electrons Trapped in a Plasma Wakefield Accelerator Citation Details In-Document Search Title: Emittance and Current of Electrons Trapped in a Plasma Wakefield Accelerator In recent experiments plasma electrons became trapped in a plasma wakefield accelerator (PWFA). The transverse size of these trapped electrons on a downstream diagnostic yields an upper limit measurement of transverse normalized emittance divided by peak

  11. High voltage gas insulated transmission line with continuous particle trapping

    DOE Patents [OSTI]

    Cookson, Alan H. (Pittsburgh, PA); Dale, Steinar J. (Monroeville, PA)

    1983-01-01

    This invention provides a novel high voltage gas insulated transmission line utilizing insulating supports spaced at intervals with snap-in means for supporting a continuous trapping apparatus and said trapping apparatus having perforations and cutouts to facilitate trapping of contaminating particles and system flexibility.

  12. Ion Rings for Magnetic Fusion

    SciTech Connect (OSTI)

    Greenly, John, B.

    2005-07-31

    This Final Technical Report presents the results of the program, Ion Rings for Magnetic Fusion, which was carried out under Department of Energy funding during the period August, 1993 to January, 2005. The central objective of the program was to study the properties of field-reversed configurations formed by ion rings. In order to reach this objective, our experimental program, called the Field-reversed Ion Ring Experiment, FIREX, undertook to develop an efficient, economical technology for the production of field-reversed ion rings. A field-reversed configuration (FRC) in which the azimuthal (field-reversing) current is carried by ions with gyro-radius comparable to the magnetic separatrix radius is called a field-reversed ion ring. A background plasma is required for charge neutralization of the ring, and this plasma will be confined within the ring's closed magnetic flux. Ion rings have long been of interest as the basis of compact magnetic fusion reactors, as the basis for a high-power accelerator for an inertial fusion driver, and for other applications of high power ion beams or plasmas of high energy density. Specifically, the FIREX program was intended to address the longstanding question of the contribution of large-orbit ions to the observed stability of experimental FRCs to the MHD tilt mode. Typical experimental FRCs with s {approx} 2-4, where s is the ratio of separatrix radius to ion gyro-radius, have been stable to tilting, but desired values for a fusion reactor, s > 20, should be unstable. The FIREX ring would consist of a plasma with large s for the background ions, but with s {approx} 1 for the ring ions. By varying the proportions of these two populations, the minimum proportion of large-orbit ions necessary for stability could be determined. The incorporation of large-orbit ions, perhaps by neutral-beam injection, into an FRC has been advanced for the purpose of stabilizing, heating, controlling angular momentum, and aiding the formation of a reactor-scale FRC, and the FIREX program was intended to test the ideas behind this approach. We will describe in this report the technological development path and advances in physics understanding that allowed FIREX to reach a regime in which ion rings were reproducibly created with up to about half the current necessary to produce field reversal. Unfortunately, the experiments were limited to this level by a fundamental, unanticipated aspect of the physics of strong ion rings in plasma. The FIREX ring is a strongly anisotropic, current-carrying population of ions moving faster than the Alfven speed in the background plasma. The rapidly changing ring current excites very large-amplitude Alfven waves in the plasma, and these waves strongly affect the ring, causing rapid energy loss in a way that is not compatible with the success of the ring trapping scenario around which FIREX was designed. The result was that FIREX rings were always very short-lived. We will discuss the implication of these results for possible future use of large-orbit ions in FRCs. In short, it appears that a certain range of the parameters characterizing the ring Alfven mach number and distribution function must be avoided to allow the existence of a long-lived energetic ion component in an FRC. This report will explain why FIREX experimental results cannot be directly scaled to quantitatively predict this range for a particular FRC configuration. This will require accurate, three-dimensional simulations. FIREX results do constitute a very good dataset for validating such a code, and simulations already carried out during this program provide a guide to the important physics involved.

  13. Shale gas is natural gas trapped inside

    Energy Savers [EERE]

    Shale gas is natural gas trapped inside formations of shale - fine grained sedimentary rocks that can be rich sources of petroleum and natural gas. Just a few years ago, much of this resource was considered uneconomical to produce. But Office of Fossil Energy (FE) research helped refine cost-effective horizontal drilling and hydraulic fracturing technologies, protective environmental practices and data development, making hundreds of trillions of cubic feet of gas technically recoverable where

  14. Highly charged ion based time of flight emission microscope

    DOE Patents [OSTI]

    Barnes, Alan V. (Livermore, CA); Schenkel, Thomas (San Francisco, CA); Hamza, Alex V. (Livermore, CA); Schneider, Dieter H. (Livermore, CA); Doyle, Barney (Albuquerque, NM)

    2001-01-01

    A highly charged ion based time-of-flight emission microscope has been designed, which improves the surface sensitivity of static SIMS measurements because of the higher ionization probability of highly charged ions. Slow, highly charged ions are produced in an electron beam ion trap and are directed to the sample surface. The sputtered secondary ions and electrons pass through a specially designed objective lens to a microchannel plate detector. This new instrument permits high surface sensitivity (10.sup.10 atoms/cm.sup.2), high spatial resolution (100 nm), and chemical structural information due to the high molecular ion yields. The high secondary ion yield permits coincidence counting, which can be used to enhance determination of chemical and topological structure and to correlate specific molecular species.

  15. Non-vanishing ponderomotive AC electrophoretic effect for particle trapping

    SciTech Connect (OSTI)

    Guan, Weihau; Park, Jae Hyun nmn; Krstic, Predrag S; Reed, Mark A

    2011-01-01

    We present here a study on overlooked aspects of alternating current (AC) electrokinetics AC electrophoretic (ACEP) phenomena. The dynamics of a particle with both polarizability and net charges in a non-uniform AC electric trapping field is investigated. It is found that either electrophoretic (EP) or dielectrophoretic (DEP) effects can dominate the trapping dynamics, depending on experimental conditions. A dimensionless parameter gamma is developed to predict the relative strength of EP and DEP effects in a quadrupole AC field. An ACEP trap is feasible for charged particles in salt-free or low salt concentration solutions. In contrast to DEP traps, an ACEP trap favors the downscaling of the particle size.

  16. Ion focusing

    DOE Patents [OSTI]

    Cooks, Robert Graham; Baird, Zane; Peng, Wen-Ping

    2015-11-10

    The invention generally relates to apparatuses for focusing ions at or above ambient pressure and methods of use thereof. In certain embodiments, the invention provides an apparatus for focusing ions that includes an electrode having a cavity, at least one inlet within the electrode configured to operatively couple with an ionization source, such that discharge generated by the ionization source is injected into the cavity of the electrode, and an outlet. The cavity in the electrode is shaped such that upon application of voltage to the electrode, ions within the cavity are focused and directed to the outlet, which is positioned such that a proximal end of the outlet receives the focused ions and a distal end of the outlet is open to ambient pressure.

  17. Time of flight mass spectrometer

    DOE Patents [OSTI]

    Ulbricht, Jr., William H. (Arvada, CO)

    1984-01-01

    A time-of-flight mass spectrometer is described in which ions are desorbed from a sample by nuclear fission fragments, such that desorption occurs at the surface of the sample impinged upon by the fission fragments. This configuration allows for the sample to be of any thickness, and eliminates the need for complicated sample preparation.

  18. Zinc-oxide charge trapping memory cell with ultra-thin chromium-oxide trapping layer

    SciTech Connect (OSTI)

    El-Atab, Nazek; Rizk, Ayman; Nayfeh, Ammar; Okyay, Ali K.; UNAM-National Nanotechnology Research Center and Institute of Materials Science and Nanotechnology, Bilkent University, 06800 Ankara

    2013-11-15

    A functional zinc-oxide based SONOS memory cell with ultra-thin chromium oxide trapping layer was fabricated. A 5 nm CrO{sub 2} layer is deposited between Atomic Layer Deposition (ALD) steps. A threshold voltage (V{sub t}) shift of 2.6V was achieved with a 10V programming voltage. Also for a 2V V{sub t} shift, the memory with CrO{sub 2} layer has a low programming voltage of 7.2V. Moreover, the deep trapping levels in CrO{sub 2} layer allows for additional scaling of the tunnel oxide due to an increase in the retention time. In addition, the structure was simulated using Physics Based TCAD. The results of the simulation fit very well with the experimental results providing an understanding of the charge trapping and tunneling physics.

  19. Hole Trapping at Surfaces of m?ZrO2 and m?HfO2 Nanocrystals

    SciTech Connect (OSTI)

    Wolf, Matthew J.; Mckenna, Keith P.; Shlyuger, Alexander L.

    2012-12-03

    We investigate hole trapping at the most prevalent facets of monoclinic zirconia (m-ZrO2) and hafnia (m-HfO2) nanocrystals using first-principles methods. The localization of holes at surface oxygen ions is more favorable than in the bulk crystal by up to ?1 eV. This is caused mainly by the reduction of the absolute value of the electrostatic potential at the surface ions with respect to the bulk and by the significant surface distortion caused by the hole localization. The mobility of holes at surfaces is much lower than that found in the bulk and is fairly isotropic. Unlike in cubic oxides, such as MgO and CaO, we do not find a significant driving force for preferential trapping of holes at steps on the m-ZrO2 surface. These fundamental results are relevant to mechanisms of water oxidation, photocatalysis, contact charging, and photodesorption.

  20. Ultra-high-mass mass spectrometry with charge discrimination using cryogenic detectors

    DOE Patents [OSTI]

    Frank, Matthias (Berkeley, CA); Mears, Carl A. (Oakland, CA); Labov, Simon E. (Berkeley, CA); Benner, W. Henry (Danville, CA)

    1999-01-01

    An ultra-high-mass time-of-flight mass spectrometer using a cryogenic particle detector as an ion detector with charge discriminating capabilities. Cryogenic detectors have the potential for significantly improving the performance and sensitivity of time-of-flight mass spectrometers, and compared to ion multipliers they exhibit superior sensitivity for high-mass, slow-moving macromolecular ions and can be used as "stop" detectors in time-of-flight applications. In addition, their energy resolving capability can be used to measure the charge state of the ions. Charge discrimination is very valuable in all time-of-flight mass spectrometers. Using a cryogenically-cooled Nb-Al.sub.2 O.sub.3 -Nb superconductor-insulator-superconductor (SIS) tunnel junction (STJ) detector operating at 1.3 K as an ion detector in a time-of-flight mass spectrometer for large biomolecules it was found that the STJ detector has charge discrimination capabilities. Since the cryogenic STJ detector responds to ion energy and does not rely on secondary electron production, as in the conventionally used microchannel plate (MCP) detectors, the cryogenic detector therefore detects large molecular ions with a velocity-independent efficiency approaching 100%.

  1. Sales lag sparks steam trap diversity

    SciTech Connect (OSTI)

    Crawford, E.

    1980-03-03

    Competing manufacturers have broadened their product range and customer services in an effort to survive a tightened market and the introduction of unconventional devices. Users and vendors agree that rising energy costs now give inspection and maintenance of steam traps top priority. New products on the market are described. Competition has led to some questionable advertising and legal action. Fixed orifice and temperature-actuated valves are among the alternative products offered. Models of the major manufacturers are compared by type, pressure and condensate load range, primary use, and price.

  2. Gas turbine engines with particle traps

    DOE Patents [OSTI]

    Boyd, Gary L. (Tempe, AZ); Sumner, D. Warren (Phoenix, AZ); Sheoran, Yogendra (Scottsdale, AZ); Judd, Z. Daniel (Phoenix, AZ)

    1992-01-01

    A gas turbine engine (10) incorporates a particle trap (46) that forms an entrapment region (73) in a plenum (24) which extends from within the combustor (18) to the inlet (32) of a radial-inflow turbine (52, 54). The engine (10) is thereby adapted to entrap particles that originate downstream from the compressor (14) and are otherwise propelled by combustion gas (22) into the turbine (52, 54). Carbonaceous particles that are dislodged from the inner wall (50) of the combustor (18) are incinerated within the entrapment region (73) during operation of the engine (10).

  3. Isotopic abundance in atom trap trace analysis

    DOE Patents [OSTI]

    Lu, Zheng-Tian; Hu, Shiu-Ming; Jiang, Wei; Mueller, Peter

    2014-03-18

    A method and system for detecting ratios and amounts of isotopes of noble gases. The method and system is constructed to be able to measure noble gas isotopes in water and ice, which helps reveal the geological age of the samples and understand their movements. The method and system uses a combination of a cooled discharge source, a beam collimator, a beam slower and magneto-optic trap with a laser to apply resonance frequency energy to the noble gas to be quenched and detected.

  4. High-energy accelerator for beams of heavy ions

    DOE Patents [OSTI]

    Martin, Ronald L. (La Grange, IL); Arnold, Richard C. (Chicago, IL)

    1978-01-01

    An apparatus for accelerating heavy ions to high energies and directing the accelerated ions at a target comprises a source of singly ionized heavy ions of an element or compound of greater than 100 atomic mass units, means for accelerating the heavy ions, a storage ring for accumulating the accelerated heavy ions and switching means for switching the heavy ions from the storage ring to strike a target substantially simultaneously from a plurality of directions. In a particular embodiment the heavy ion that is accelerated is singly ionized hydrogen iodide. After acceleration, if the beam is of molecular ions, the ions are dissociated to leave an accelerated singly ionized atomic ion in a beam. Extraction of the beam may be accomplished by stripping all the electrons from the atomic ion to switch the beam from the storage ring by bending it in magnetic field of the storage ring.

  5. Mesoscopic supersolid of dipoles in a trap

    SciTech Connect (OSTI)

    Golomedov, A. E.; Astrakharchik, G. E.; Lozovik, Yu. E.

    2011-09-15

    A mesoscopic system of dipolar bosons trapped by a harmonic potential is considered. The system has a number of physical realizations including dipole excitons, atoms with large dipolar moment, polar molecules, and Rydberg atoms in inhomogeneous electric field. We carry out a diffusion Monte Carlo simulation to define the quantum properties of a two-dimensional system of trapped dipoles at zero temperature. In dimensionless units the system is described by two control parameters, namely, the number of particles and the strength of the interparticle interaction. We have shown that when the interparticle interaction is strong enough a mesoscopic crystal is formed. As the strength of interactions is decreased a multistage melting takes place. Off-diagonal order in the system is tested using natural-orbitals analysis. We have found that the system might be Bose condensed even in the case of strong interparticle interactions. There is a set of parameters for which a spatially ordered structure is formed while simultaneously the fraction of Bose-condensed particles is nonzero. This might be considered as a realization of a mesoscopic supersolid.

  6. Fluctuation characteristics and transport properties of collisionless trapped electron mode turbulence

    SciTech Connect (OSTI)

    Xiao Yong; Holod, Ihor; Zhang Wenlu; Lin Zhihong [Department of Physics and Astronomy, University of California, Irvine, California 92697 (United States); Klasky, Scott [Oak Ridge National Laboratory, Oak Ridge, Tennessee 37831 (United States)

    2010-02-15

    The collisionless trapped electron mode turbulence is investigated by global gyrokinetic particle simulation. The zonal flow dominated by low frequency and short wavelength acts as a very important saturation mechanism. The turbulent eddies are mostly microscopic, but with a significant portion in the mesoscale. The ion heat transport is found to be diffusive and follows the local radial profile of the turbulence intensity. However, the electron heat transport demonstrates some nondiffusive features and only follows the global profile of the turbulence intensity. The nondiffusive features of the electron heat transport is further confirmed by nonlognormal statistics of the flux-surface-averaged electron heat flux. The radial and time correlation functions are calculated to obtain the radial correlation length and autocorrelation time. Characteristic time scale analysis shows that the zonal flow shearing time and eddy turnover time are very close to the effective decorrelation time, which suggests that the trapped electrons move with the fluid eddies. The fluidlike behaviors of the trapped electrons and the persistence of the mesoscale eddies contribute to the transition of the electron turbulent transport from gyro-Bohm scaling to Bohm scaling when the device size decreases.

  7. Gas insulated transmission line having tapered particle trapping ring

    DOE Patents [OSTI]

    Cookson, Alan H. (Pittsburgh, PA)

    1982-01-01

    A gas-insulated transmission line includes an outer sheath, an inner conductor, insulating supports and an insulating gas. A particle-trapping ring is secured to each insulating support, and it is comprised of a central portion and two tapered end portions. The ends of the particle trapping ring have a smaller diameter than the central portion of the ring, so as to enable the use of the particle trapping ring in a curved transmission line.

  8. Steam trap maintenance management saves $180,000 annually

    SciTech Connect (OSTI)

    Franks, F.C.; Wickersham, C.

    1985-12-01

    The Reichhold Chemical plant is located in Elizabeth, NJ. At this location, the cost of steam had skyrocketed to $5.30 per million Btu. The plant has 600 steam traps manufactured by ten different companies. Some 17 different models of traps are used with 33 piping configurations. There are five different operating pressures throughout the plant ranging from 15-175 psig, including 30, 65, and 120 psig. Five different applications of steam usage can be broken down as follows: steam tracing (56%); drip (21%); comfort heating (18%); tank coil (4%); and process (1%). In the fall of 1983, the annual yearly inspection of steam traps was supplanted with an independent trap survey service, specializing in detecting the malfunctioning of various types of steam traps. The basic program included location and tagging of all steam traps; survey and inspection of steam trap population; development of a trap map; and full computer analysis of collected data. It was determined that approximately 3919 lb/hr of steam could be saved by repairing the failed open traps and implementing the report's recommendations. There were also benefits from fixing the failed closed traps which were out of service at the time of the survey. These traps do not allow the flow of steam or condensate to pass through the orifice. This condition causes condensate to back up and reduce efficiency. The maintenance management has been pleased with the results and recommendations of the program. It has provided them with a complete inventory and status report of the 600 traps plantwide. It saved $180,000 over the previous year in energy expenditures. This was the most important contribution in lowering the plant energy costs.

  9. Thermostatic/orifice trap reduces fuel, repair costs

    SciTech Connect (OSTI)

    Not Available

    1982-11-01

    This article is an evaluation of a steam trap that combines the continuous drain oriface with a thermostatically controlled trap oriface to efficiently remove condensate from virtually any steam system within its operating limits. This trap effectively reduces fuel and repair costs and has a capacity of 6000 il/hr, handles various pressures up to 600 psig, and operates against back pressures up to 90% of inlet pressure.

  10. Light Trapping, Absorption and Solar Energy Harvesting by Artificial

    Office of Scientific and Technical Information (OSTI)

    Materials (Technical Report) | SciTech Connect Technical Report: Light Trapping, Absorption and Solar Energy Harvesting by Artificial Materials Citation Details In-Document Search Title: Light Trapping, Absorption and Solar Energy Harvesting by Artificial Materials We provide designs of thin-film solar cells utilizing optimized photonic-crystal light-trapping and numerical simulations of their solar-to-electrical power conversion efficiencies. Authors: John, Sajeev [1] + Show Author

  11. A Sub-Millimeter Solenoid Device for Trapping Paramagnetic Microbeads

    Office of Scientific and Technical Information (OSTI)

    (Conference) | SciTech Connect A Sub-Millimeter Solenoid Device for Trapping Paramagnetic Microbeads Citation Details In-Document Search Title: A Sub-Millimeter Solenoid Device for Trapping Paramagnetic Microbeads We present the design and preliminary evaluation of a paramagnetic microsphere trapping and separation device consisting of a copper solenoid wrapped around a 1.3 mm diameter glass capillary. The magnetization and subsequent dipole-dipole interaction of paramagnetic spheres under

  12. Requirements-Driven Diesel Catalyzed Particulate Trap Design and

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Optimization | Department of Energy Requirements-Driven Diesel Catalyzed Particulate Trap Design and Optimization Requirements-Driven Diesel Catalyzed Particulate Trap Design and Optimization 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters PDF icon 2005_deer_harris.pdf More Documents & Publications Diesel Emission Control Technology Review Investigation of Aging Mechanisms in Lean NOx Traps Diesel Particulate Filters: Market Introducution

  13. Benchmark Reaction Mechanisms and Kinetics for Lean NOx Traps | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Benchmark Reaction Mechanisms and Kinetics for Lean NOx Traps Benchmark Reaction Mechanisms and Kinetics for Lean NOx Traps 2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. PDF icon acep_01_larson.pdf More Documents & Publications Development of Chemical Kinetic Models for Lean NOx Traps Development of Optimal Catalyst Designs and Operating Strategies for Lean NOx Reduction in Coupled

  14. 'Data Deluge' Pushes Mass Spec Imaging to New Heights

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    'Data Deluge' Pushes Mass Spec Imaging to New Heights 'Data Deluge' Pushes Mass Spec Imaging to New Heights MANTISSA Team Takes Novel Approach to Improve Experimental Data Analysis July 15, 2015 Contact: Kathy Kincade, +1 510 495 2124, kkincade@lbl.gov MANTISSA Ion-intensity visualization of the 20 most important ions in a mouse brain segment selected by the CX/CUR algorithm. Of the 20 ions, little redundancy is present, pointing to the effectiveness of the CX approach for information

  15. Decoherence and dephasing errors caused by the dc Stark effect in rapid ion

    Office of Scientific and Technical Information (OSTI)

    transport (Journal Article) | SciTech Connect Decoherence and dephasing errors caused by the dc Stark effect in rapid ion transport Citation Details In-Document Search Title: Decoherence and dephasing errors caused by the dc Stark effect in rapid ion transport We investigate the error due to the dc Stark effect for quantum information processing for trapped ion quantum computers using the scalable architecture proposed in D. Wineland et al. [J. Res. Natl. Inst. Stand. Technol. 103, 259

  16. Light Trapping, Absorption and Solar Energy Harvesting by Artificial...

    Office of Scientific and Technical Information (OSTI)

    Title: Light Trapping, Absorption and Solar Energy Harvesting by Artificial Materials We provide designs of thin-film solar cells utilizing optimized photonic-crystal ...

  17. A Sub-Millimeter Solenoid Device for Trapping Paramagnetic Microbeads...

    Office of Scientific and Technical Information (OSTI)

    We present the design and preliminary evaluation of a paramagnetic microsphere trapping ... The chaining of paramagnetic spheres is important to the design of magnetic-based ...

  18. Wolf Trap, Virginia: Energy Resources | Open Energy Information

    Open Energy Info (EERE)

    Bureau 2005 Place to 2006 CBSA Retrieved from "http:en.openei.orgwindex.php?titleWolfTrap,Virginia&oldid253815" Feedback Contact needs updating Image needs updating...

  19. PowerTrap: Ultrafine PM Control without Performance Penalties...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    PowerTrap: Ultrafine PM Control without Performance Penalties 2003 DEER Conference Presentation: Per-Tec Ltd, University of Manchester PDF icon 2003deerkukla.pdf More Documents & ...

  20. Quark Masses

    SciTech Connect (OSTI)

    Gasser, Juerg

    2005-10-26

    In my talk, I reviewed some basic aspects of quark masses: what do they mean, how can they be determined, what is our present knowledge on them. The talk was addressed to non specialists in the field, and so is this write up.

  1. Dynamic multiplexed analysis method using ion mobility spectrometer

    DOE Patents [OSTI]

    Belov, Mikhail E [Richland, WA

    2010-05-18

    A method for multiplexed analysis using ion mobility spectrometer in which the effectiveness and efficiency of the multiplexed method is optimized by automatically adjusting rates of passage of analyte materials through an IMS drift tube during operation of the system. This automatic adjustment is performed by the IMS instrument itself after determining the appropriate levels of adjustment according to the method of the present invention. In one example, the adjustment of the rates of passage for these materials is determined by quantifying the total number of analyte molecules delivered to the ion trap in a preselected period of time, comparing this number to the charge capacity of the ion trap, selecting a gate opening sequence; and implementing the selected gate opening sequence to obtain a preselected rate of analytes within said IMS drift tube.

  2. Eolian paleotopographic highs as stratigraphic traps: origin and distinction

    SciTech Connect (OSTI)

    Eschner, T.B.; Kocurek, G.A.

    1985-02-01

    Significant hydrocarbon accumulations occur where eolian paleotopographic highs are preserved beneath transgressive marine deposits. Paleotopographic highs can represent erosional remnants of an unconformity, or partly preserved eolian dunes, or combinations of both. Paleotopography reflects the extent of modification undergone by eolian units prior to or during transgression. Modification varies between extremes of (1) destruction - where eolian deposits are deeply eroded and the former dunal profile is lost, and (2) preservation - where dunes and interdune areas are preserved nearly intact. The extent of modification that occurs during transgression is controlled primarily by (1) the energy of the transgressing sea, (2) the speed of transgression, and (3) the abundance of sand-stabilizing early cements or plants. High-energy seas destroy dunes through persistent erosion by tides and waves and by initiating dune collapse and mass flowage of dune sands. Preservation occurs where quiescent seas flood interdune areas and create shallow to periodically emergent marine environments, such as interdune sabkhas or tidal flats. Gradual filling of interdune areas with shallow marine sediments can fortify and preserve adjacent dunes. These varied processes that interact between marine and eolian environments to create different types of topography are exemplified in ancient eolian-marine sequences of the Western Interior of North America, and preserved Holocene dunes of coastal Australia. Different types of eolian highs can be recognized by analysis of bounding surfaces in outcrop or core. An understanding of eolian-marine processes and environments that create topography allows for prediction of areas of potential stratigraphic traps.

  3. Ion acoustic solitons/double layers in two-ion plasma revisited

    SciTech Connect (OSTI)

    Lakhina, G. S. Singh, S. V. Kakad, A. P.

    2014-06-15

    Ion acoustic solitons and double layers are studied in a collisionless plasma consisting of cold heavier ion species, a warm lighter ion species, and hot electrons having Boltzmann distributions by Sagdeev pseudo-potential technique. In contrast to the previous results, no double layers and super-solitons are found when both the heavy and lighter ion species are treated as cold. Only the positive potential solitons are found in this case. When the thermal effects of the lighter ion species are included, in addition to the usual ion-acoustic solitons occurring at M?>?1 (where the Mach number, M, is defined as the ratio of the speed of the solitary wave and the ion-acoustic speed considering temperature of hot electrons and mass of the heavier ion species), slow ion-acoustic solitons/double layers are found to occur at low Mach number (M?ion-acoustic mode is actually a new ion-ion hybrid acoustic mode which disappears when the normalized number density of lighter ion species tends to 1 (i.e., no heavier species). An interesting property of the new slow ion-acoustic mode is that at low number density of the lighter ion species, only negative potential solitons/double layers are found whereas for increasing densities there is a transition first to positive solitons/double layers, and then only positive solitons. The model can be easily applicable to the dusty plasmas having positively charged dust grains by replacing the heavier ion species by the dust mass and doing a simple normalization to take account of the dust charge.

  4. The ion-ion hybrid Alfvn resonator in a fusion environment

    SciTech Connect (OSTI)

    Farmer, W. A.; Morales, G. J.

    2014-06-01

    An investigation is made of a shear Alfvn wave resonator for burning plasma conditions expected in the ITER device. For small perpendicular scale-lengths the shear mode, which propagates predominantly along the magnetic field direction, experiences a parallel reflection where the wave frequency matches the local ion-ion hybrid frequency. In a tokamak device operating with a deuteriumtritium fuel, this effect can form a natural resonator because of the variation in local field strength along a field line. The relevant kinetic dispersion relation is examined to determine the relative importance of Landau and cyclotron damping over the possible resonator parameter space. A WKB model based on the kinetic dispersion relation is used to determine the eigenfrequencies and the quality factors of modes trapped in the resonator. The lowest frequency found has a value slightly larger than the ion-ion hybrid frequency at the outboard side of a given flux surface. The possibility that the resonator modes can be driven unstable by energetic alpha particles is considered. It is found that within a bandwidth of roughly 600 kHz above the ion-ion hybrid frequency on the outboard side of the flux surface, the shear modes can experience significant spatial amplification. An assessment is made of the form of an approximate global eigenmode that possesses the features of a resonator. It is identified that magnetic field shear combined with large ion temperature can cause coupling to an ion-Bernstein wave, which can limit the instability.

  5. Fundamental and methodological investigations for the improvement of elemental analysis by inductively coupled plasma mass soectrometry

    SciTech Connect (OSTI)

    Ebert, Christopher Hysjulien

    2012-07-27

    This dissertation describes a variety of studies meant to improve the analytical performance of inductively coupled plasma mass spectrometry (ICP-MS) and laser ablation (LA) ICP-MS. The emission behavior of individual droplets and LA generated particles in an ICP is studied using a high-speed, high frame rate digital camera. Phenomena are observed during the ablation of silicate glass that would cause elemental fractionation during analysis by ICP-MS. Preliminary work for ICP torch developments specifically tailored for the improvement of LA sample introduction are presented. An abnormal scarcity of metal-argon polyatomic ions (MAr{sup +}) is observed during ICP-MS analysis. Evidence shows that MAr{sup +} ions are dissociated by collisions with background gas in a shockwave near the tip of the skimmer cone. Method development towards the improvement of LA-ICP-MS for environmental monitoring is described. A method is developed to trap small particles in a collodion matrix and analyze each particle individually by LA-ICP-MS.

  6. The Brookhaven National Laboratory electron beam ion source for RHIC

    SciTech Connect (OSTI)

    Alessi, J.G.; Barton, D.; Beebe, E.; Bellavia, S.; Gould, O.; Kponou, A.; Lambiase, R.; Lockey, R.; McNerney, A.; Mapes, M.; Marneris, I.; Okamura, M.; Phillips, D.; Pikin, A.I.; Raparia, D.; Ritter, J.; Snydstrup, L.; Theisen, C.; Wilinski, M.

    2010-02-22

    As part of a new heavy ion preinjector that will supply beams for the Relativistic Heavy Ion Collider and the National Aeronautics and Space Administration Space Radiation Laboratory, construction of a new electron beam ion source (EBIS) is now being completed. This source, based on the successful prototype Brookhaven National Laboratory Test EBIS, is designed to produce milliampere level currents of all ion species, with q/m = (1/6)-(1/2). Among the major components of this source are a 5 T, 2-m-long, 204 mm diameter warm bore superconducting solenoid, an electron gun designed to operate at a nominal current of 10 A, and an electron collector designed to dissipate {approx} 300 kW of peak power. Careful attention has been paid to the design of the vacuum system, since a pressure of 10{sup -10} Torr is required in the trap region. The source includes several differential pumping stages, the trap can be baked to 400 C, and there are non-evaporable getter strips in the trap region. Power supplies include a 15 A, 15 kV electron collector power supply, and fast switchable power supplies for most of the 16 electrodes used for varying the trap potential distribution for ion injection, confinement, and extraction. The EBIS source and all EBIS power supplies sit on an isolated platform, which is pulsed up to a maximum of 100 kV during ion extraction. The EBIS is now fully assembled, and operation will be beginning following final vacuum and power supply tests. Details of the EBIS components are presented.

  7. Improved negative ion source

    DOE Patents [OSTI]

    Delmore, J.E.

    1984-05-01

    A method and apparatus for providing a negative ion source accelerates electrons away from a hot filament electron emitter into a region of crossed electric and magnetic fields arranged in a magnetron configuration. During a portion of the resulting cycloidal path, the electron velocity is reduced below its initial value. The electron accelerates as it leaves the surface at a rate of only slightly less than if there were no magnetic field, thereby preventing a charge buildup at the surface of the emitter. As the electron traverses the cycloid, it is decelerated during the second, third, and fourth quadrants, then reaccelerated as it approaches the end of the fourth quadrant to regain its original velocity. The minimum velocity occurs during the fourth quadrant, and corresponds to an electron temperature of 200 to 500/sup 0/C for the electric and magnetic fields commonly encountered in the ion sources of magnetic sector mass spectrometers. An ion source using the above-described thermalized electrons is also disclosed.

  8. Negative ion source

    DOE Patents [OSTI]

    Delmore, James E. (Idaho Falls, ID)

    1987-01-01

    A method and apparatus for providing a negative ion source accelerates electrons away from a hot filament electron emitter into a region of crossed electric and magnetic fields arranged in a magnetron configuration. During a portion of the resulting cycloidal path, the electron velocity is reduced below its initial value. The electron accelerates as it leaves the surface at a rate of only slightly less than if there were no magnetic field, thereby preventing a charge buildup at the surface of the emitter. As the electron traverses the cycloid, it is decelerated during the second, third, and fourth quadrants, then reeccelerated as it approaches the end of the fourth quadrant to regain its original velocity. The minimum velocity occurs during the fourth quadrant, and corresponds to an electron temperature of 200.degree. to 500.degree. for the electric and magnetic fields commonly encountered in the ion sources of magnetic sector mass spectrometers. An ion source using the above-described thermalized electrons is also disclosed.

  9. Debris trap in a turbine cooling system

    DOE Patents [OSTI]

    Wilson, Ian David (Clifton Park, NY)

    2002-01-01

    In a turbine having a rotor and a plurality of stages, each stage comprising a row of buckets mounted on the rotor for rotation therewith; and wherein the buckets of at least one of the stages are cooled by steam, the improvement comprising at least one axially extending cooling steam supply conduit communicating with an at least partially annular steam supply manifold; one or more axially extending cooling steam feed tubes connected to the manifold at a location radially outwardly of the cooling steam supply conduit, the feed tubes arranged to supply cooling steam to the buckets of at least one of the plurality of stages; the manifold extending radially beyond the feed tubes to thereby create a debris trap region for collecting debris under centrifugal loading caused by rotation of the rotor.

  10. Contaminant trap for gas-insulated apparatus

    DOE Patents [OSTI]

    Adcock, James L. (Knoxville, TN); Pace, Marshall O. (Knoxville, TN); Christophorou, Loucas G. (Oak Ridge, TN)

    1984-01-01

    A contaminant trap for a gas-insulated electrical conductor is provided. A resinous dielectric body such as Kel-F wax, grease or other sticky polymeric or oligomeric compound is disposed on the inside wall of the outer housing for the conductor. The resinous body is sufficiently sticky at ambient temperatures to immobilize contaminant particles in the insulating gas on the exposed surfaces thereof. An electric resistance heating element is disposed in the resinous body to selectively raise the temperature of the resinous body to a molten state so that the contaminant particles collected on the surface of the body sink into the body so that the surface of the resinous body is renewed to a particle-less condition and, when cooled, returns to a sticky collecting surface.

  11. A hollow cathode ion source for production of primary ions for the BNL electron beam ion source

    SciTech Connect (OSTI)

    Alessi, James Beebe, Edward; Carlson, Charles; McCafferty, Daniel; Pikin, Alexander; Ritter, John

    2014-02-15

    A hollow cathode ion source, based on one developed at Saclay, has been modified significantly and used for several years to produce all primary 1+ ions injected into the Relativistic Heavy Ion Collider Electron Beam Ion Source (EBIS) at Brookhaven. Currents of tens to hundreds of microamperes have been produced for 1+ ions of He, C, O, Ne, Si, Ar, Ti, Fe, Cu, Kr, Xe, Ta, Au, and U. The source is very simple, relying on a glow discharge using a noble gas, between anode and a solid cathode containing the desired species. Ions of both the working gas and ionized sputtered cathode material are extracted, and then the desired species is selected using an ExB filter before being transported into the EBIS trap for charge breeding. The source operates pulsed with long life and excellent stability for most species. Reliable ignition of the discharge at low gas pressure is facilitated by the use of capacitive coupling from a simple toy plasma globe. The source design, and operating experience for the various species, is presented.

  12. Plasma Mass Filters For Nuclear Waste Reprocessing

    SciTech Connect (OSTI)

    Abraham J. Fetterman and Nathaniel J. Fisch

    2011-05-26

    Practical disposal of nuclear waste requires high-throughput separation techniques. The most dangerous part of nuclear waste is the fission product, which contains the most active and mobile radioisotopes and produces most of the heat. We suggest that the fission products could be separated as a group from nuclear waste using plasma mass filters. Plasmabased processes are well suited to separating nuclear waste, because mass rather than chemical properties are used for separation. A single plasma stage can replace several stages of chemical separation, producing separate streams of bulk elements, fission products, and actinoids. The plasma mass filters may have lower cost and produce less auxiliary waste than chemical processing plants. Three rotating plasma configurations are considered that act as mass filters: the plasma centrifuge, the Ohkawa filter, and the asymmetric centrifugal trap.

  13. Plasma Mass Filters For Nuclear Waste Reprocessing

    SciTech Connect (OSTI)

    Abraham J. Fetterman and Nathaniel J. Fisch

    2011-05-25

    Practical disposal of nuclear waste requires high-throughput separation techniques. The most dangerous part of nuclear waste is the fission product, which contains the most active and mobile radioisotopes and produces most of the heat. We suggest that the fission products could be separated as a group from nuclear waste using plasma mass filters. Plasmabased processes are well suited to separating nuclear waste, because mass rather than chemical properties are used for separation. A single plasma stage can replace several stages of chemical separation, producing separate streams of bulk elements, fission products, and actinoids. The plasma mass filters may have lower cost and produce less auxiliary waste than chemical processing plants. Three rotating plasma configurations are considered that act as mass filters: the plasma centrifuge, the Ohkawa filter, and the asymmetric centrifugal trap.

  14. PowerTrap: Ultrafine PM Control without Performance Penalties | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy PowerTrap: Ultrafine PM Control without Performance Penalties PowerTrap: Ultrafine PM Control without Performance Penalties 2003 DEER Conference Presentation: Per-Tec Ltd, University of Manchester PDF icon 2003_deer_kukla.pdf More Documents & Publications Plasmatron Fuel Reformer Development and Internal Combustion Engine Vehicle Applications Review of Diesel Emission Control Technology Active Soot Filter Regeneration

  15. Charge Trapping in High Efficiency Alternating Copolymers: Implications in

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Organic Photovoltaic Device Efficiency | ANSER Center | Argonne-Northwestern National Laboratory Charge Trapping in High Efficiency Alternating Copolymers: Implications in Organic Photovoltaic Device Efficiency Home > Research > ANSER Research Highlights > Charge Trapping in High Efficiency Alternating Copolymers: Implications in Organic Photovoltaic Device Efficiency

  16. Optical trapping apparatus, methods and applications using photonic crystal resonators

    DOE Patents [OSTI]

    Erickson, David; Chen, Yih-Fan

    2015-06-16

    A plurality of photonic crystal resonator optical trapping apparatuses and a plurality optical trapping methods using the plurality of photonic crystal resonator optical trapping apparatuses include located and formed over a substrate a photonic waveguide that is coupled (i.e., either separately coupled or integrally coupled) with a photonic crystal resonator. In a particular embodiment, the photonic waveguide and the photonic crystal resonator comprise a monocrystalline silicon (or other) photonic material absent any chemical functionalization. In another particular embodiment, the photonic waveguide and the photonic crystal resonator comprise a silicon nitride material which when actuating the photonic crystal resonator optical trapping apparatus with a 1064 nanometer resonant photonic radiation wavelength (or other resonant photonic radiation wavelength in a range from about 700 to about 1200 nanometers) provides no appreciable heating of an aqueous sample fluid that is analyzed by the photonic crystal resonator optical trapping apparatus.

  17. A Pneumatic Actuated Microfluidic Beads-Trapping Device

    SciTech Connect (OSTI)

    Shao, Guocheng; Cai, Ziliang; Wang, Jun; Wang, Wanjun; Lin, Yuehe

    2011-08-20

    The development of a polydimethylsiloxane (PDMS) microfluidic microbeads trapping device is reported in this paper. Besides fluid channels, the proposed device includes a pneumatic control chamber and a beads-trapping chamber with a filter array structure. The pneumatic flow control chamber and the beads-trapping chamber are vertically stacked and separated by a thin membrane. By adjusting the pressure in the pneumatic control chamber, the membrane can either be pushed against the filter array to set the device in trapping mode or be released to set the device in releasing mode. In this paper, a computational fluid dynamics simulation was conducted to optimize the geometry design of the filter array structure; the device fabrication was also carried out. The prototype device was tested and the preliminary experimental results showed that it can be used as a beads-trapping unit for various biochemistry and analytical chemistry applications, especially for flow injection analysis systems.

  18. Characterization of trapped gas saturation and heterogeneity in core samples using miscible-displacement experiments

    SciTech Connect (OSTI)

    Smith, D.H.; Jikich, S.A.

    1994-12-31

    Trapped gas saturation and permeability heterogeneity were evaluated in Berea cores at reservoir conditions, using standard miscible displacement experiments, with and without surfactants. Pressure and production history were influenced by core heterogeneity and foam lamellae formation when aqueous surfactant was present in the core. A simple dispersion model and a three-coefficient dispersion-capacitance model (Coates-Smith) were fit to the experimental data. The dispersion-capacitance model successfully matched the experiments in which foam lamella formed, while the simple dispersion model was used only for determining initial core flow heterogeneity. The objective of the dispersion-capacitance model was to estimate trapped gas saturations; however longitudinal dispersion and mass transfer also were examined. The results show that the dispersion-capacitance model accurately fits trapped gas saturation controlled by rock heterogeneities and foam lamellae for lamella generating mechanisms that allow a continuous gas phase (leave-behind lamellae). The practical applications resulting from this study can aid in core sample selection and scaling short laboratory corefloods to field dimensions for applications to foam stimulation and underground storage of natural gas.

  19. Sample inlet tube for ion source

    DOE Patents [OSTI]

    Prior, David [Hermiston, OR; Price, John [Richland, WA; Bruce, Jim [Oceanside, CA

    2002-09-24

    An improved inlet tube is positioned within an aperture through the device to allow the passage of ions from the ion source, through the improved inlet tube, and into the interior of the device. The inlet tube is designed with a larger end and a smaller end wherein the larger end has a larger interior diameter than the interior diameter of the smaller end. The inlet tube is positioned within the aperture such that the larger end is pointed towards the ion source, to receive ions therefrom, and the smaller end is directed towards the interior of the device, to deliver the ions thereto. Preferably, the ion source utilized in the operation of the present invention is a standard electrospray ionization source. Similarly, the present invention finds particular utility in conjunction with analytical devices such as mass spectrometers.

  20. Low pressure electrospray ionization system and process for effective transmission of ions

    DOE Patents [OSTI]

    Tang, Keqi (Richland, WA); Page, Jason S (Kennewick, WA); Kelly, Ryan T (West Richland, WA); Smith, Richard D (Richland, WA)

    2012-05-08

    Systems and methods that provide up to complete transmission of ions between coupled stages with low effective ion losses. An "interfaceless" electrospray ionization system is further described that operates an electrospray at a reduced pressure such that standard electrospray sample solutions can be directly sprayed into an electrodynamic ion funnel which provides ion focusing and transmission of ions into a mass analyzer. Furthermore, chambers maintained at different pressures can allow for more optimal operating conditions for an electrospray emitter and an ion guide.

  1. Ion Stancu

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the Search for Neutrino Oscillations with MiniBooNE Ion Stancu University of Alabama Frontiers in Neutrino Physics APC, Paris, October 6th, 2011 06.10.2011
FNP
 2
 Ion
Stancu
-
University
of
Alabama
 Introduction Review of the MiniBooNE oscillation results: * Motivation for MiniBooNE: testing the LSND signal * MiniBooNE design strategy and assumptions * Neutrino oscillation results: PRL 98, 231801 (2007) & PRL 102, 101802 (2009) * Antineutrino oscillation results: PRL 103,

  2. Improved ion source

    DOE Patents [OSTI]

    Leung, K.N.; Ehlers, K.W.

    1982-05-04

    A magnetic filter for an ion source reduces the production of undesired ion species and improves the ion beam quality. High-energy ionizing electrons are confined by the magnetic filter to an ion source region, where the high-energy electrons ionize gas molecules. One embodiment of the magnetic filter uses permanent magnets oriented to establish a magnetic field transverse to the direction of travel of ions from the ion source region to the ion extraction region. In another embodiment, low energy 16 eV electrons are injected into the ion source to dissociate gas molecules and undesired ion species into desired ion species,

  3. Cast-to-shape electrokinetic trapping medium

    DOE Patents [OSTI]

    Shepodd, Timothy J.; Franklin, Elizabeth; Prickett, Zane T.; Artau, Alexander

    2004-08-03

    A three-dimensional microporous polymer network material, or monolith, cast-to-shape in a microchannel. The polymer monolith, produced by a phase separation process, is capable of trapping and retaining charged protein species from a mixture of charged and uncharged species under the influence of an applied electric field. The retained charged protein species are released from the porous polymer monolith by a pressure driven flow in the substantial absence of the electric field. The pressure driven flow is independent of direction and thus neither means to reverse fluid flow nor a multi-directional flow field is required, a single flow through the porous polymer monolith can be employed, in contrast to prior art systems. The monolithic polymer material produced by the invention can function as a chromatographic medium. Moreover, by virtue of its ability to retain charged protein species and quantitatively release the retained species the porous polymer monolith can serve as a means for concentrating charged protein species from, for example, a dilute solution.

  4. Cast-to-shape electrokinetic trapping medium

    DOE Patents [OSTI]

    Shepodd, Timothy J. (Livermore, CA); Franklin, Elizabeth (Rolla, MO); Prickett, Zane T. (Golden, CO); Artau, Alexander (Pleasanton, CA)

    2006-05-30

    A three-dimensional microporous polymer network material, or monolith, cast-to-shape in a microchannel. The polymer monolith, produced by a phase separation process, is capable of trapping and retaining charged protein species from a mixture of charged and uncharged species under the influence of an applied electric field. The retained charged protein species are released from the porous polymer monolith by a pressure driven flow in the substantial absence of the electric field. The pressure driven flow is independent of direction and thus neither means to reverse fluid flow nor a multi-directional flow field is required, a single flow through the porous polymer monolith can be employed, in contrast to prior art systems. The monolithic polymer material produced by the invention can function as a chromatographic medium. Moreover, by virtue of its ability to retain charged protein species and quantitatively release the retained species the porous polymer monolith can serve as a means for concentrating charged protein species from, for example, a dilute solution.

  5. Hydrogen isotope trapping in Al-Cu binary alloys

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Chao, Paul; Karnesky, Richard A.

    2016-02-03

    In this study, the trapping mechanisms for hydrogen isotopes in Al–X Cu (0.0 at. % < X < 3.5 at. %) alloys were investigated using thermal desorption spectroscopy (TDS), electrical conductivity, and differential scanning calorimetry. Constant heating rate TDS was used to determine microstructural trap energies and occupancies. In addition to the trapping states in pure Al reported in the literature (interstitial lattice sites, dislocations, and vacancies), a trap site due to Al–Cu intermetallic precipitates is observed. The binding energy of this precipitate trap is (18 ± 3) kJ•mol–1 (0.19 ± 0.03 eV). Typical occupancy of this trap is high;more » for Al–2.6 at. % Cu (a Cu composition comparable to that in AA2219) charged at 200 °C with 130 MPa D2 for 68 days, there is ca. there is 3.15×10–7 mol D bound to the precipitate trap per mol of Al, accounting for a third of the D in the charged sample.« less

  6. Ion source based on the cathodic arc

    DOE Patents [OSTI]

    Sanders, D.M.; Falabella, S.

    1994-02-01

    A cylindrically symmetric arc source to produce a ring of ions which leave the surface of the arc target radially and are reflected by electrostatic fields present in the source to a point of use, such as a part to be coated, is described. An array of electrically isolated rings positioned in the source serves the dual purpose of minimizing bouncing of macroparticles and providing electrical insulation to maximize the electric field gradients within the source. The source also includes a series of baffles which function as a filtering or trapping mechanism for any macroparticles. 3 figures.

  7. Ion source based on the cathodic arc

    DOE Patents [OSTI]

    Sanders, David M. (Livermore, CA); Falabella, Steven (Livermore, CA)

    1994-01-01

    A cylindrically symmetric arc source to produce a ring of ions which leave the surface of the arc target radially and are reflected by electrostatic fields present in the source to a point of use, such as a part to be coated. An array of electrically isolated rings positioned in the source serves the dual purpose of minimizing bouncing of macroparticles and providing electrical insulation to maximize the electric field gradients within the source. The source also includes a series of baffles which function as a filtering or trapping mechanism for any macroparticles.

  8. A high-performance electron beam ion source

    SciTech Connect (OSTI)

    Alessi,J.; Beebe, E.; Bellavia, S.; Gould, O.; Kponou, A.; Lambiase, R.; Lockey, R.; McCafferty, D.; Okamura, M.; Pikin, A. I.; Raparia, D.; Ritter, J.; Syndstrup, L.

    2009-06-08

    At Brookhaven National Laboratory, a high current Electron Beam Ion Source (EBIS) has been developed as part of a new preinjector that is under construction to replace the Tandem Van de Graaffs as the heavy ion preinjector for the RHIC and NASA experimental programs. This preinjector will produce milliampere-level currents of essentially any ion species, with q/A {ge} 1/6, in short pulses, for injection into the Booster synchrotron. In order to produce the required intensities, this EBIS uses a 10A electron gun, and an electron collector designed to handle 300 kW of pulsed electron beam power. The EBIS trap region is 1.5 m long, inside a 5T, 2m long, 8-inch bore superconducting solenoid. The source is designed to switch ion species on a pulse-to-pulse basis, at a 5 Hz repetition rate. Singly-charged ions of the appropriate species, produced external to the EBIS, are injected into the trap and confined until the desired charge state is reached via stepwise ionization by the electron beam. Ions are then extracted and matched into an RFQ, followed by a short IH Linac, for acceleration to 2 MeV/A, prior to injection into the Booster synchrotron. An overview of the preinjector is presented, along with experimental results from the prototype EBIS, where all essential requirements have already been demonstrated. Design features and status of construction of the final high intensity EBIS is also be presented.

  9. Using malaise traps to sample ground beetles (Coleoptera: Carabidae).

    SciTech Connect (OSTI)

    Ulyshen, Michael D., James L. Hanula, and Scott Horn

    2005-01-01

    Pitfall traps provide an easy and inexpensive way to sample ground-dwelling arthropods (Spence and Niemela 1994; Spence et al. 1997; Abildsnes and Tommeras 2000) and have been used exclusively in many studies of the abundance and diversity of ground beetles (Coleoptera: Carabidae). Despite the popularity of this trapping technique, pitfall traps have many disadvantages. For example, they often fail to collect both small (Spence and Niemela 1994) and ? ????trap-shy?¢??? species (Benest 1989), eventually deplete the local carabid population (Digweed et al. 1995), require a species to be ground-dwelling in order to be captured (Liebherr and Mahar 1979), and produce different results depending on trap diameter and material, type of preservative used, and trap placement (Greenslade 1964; Luff 1975; Work et al. 2002). Further complications arise from seasonal patterns of movement among the beetles themselves (Maelfait and Desender 1990), as well as numerous climatic factors, differences in plant cover, and variable surface conditions (Adis 1979). Because of these limitations, pitfall trap data give an incomplete picture of the carabid community and should be interpreted carefully. Additional methods, such as use of Berlese funnels and litter washing (Spence and Niemela 1994), collection from lights (Usis and MacLean 1998), and deployment of flight intercept devices (Liebherr and Mahar 1979; Paarmann and Stork 1987), should be incorporated in surveys to better ascertain the species composition and relative numbers of ground beetles. Flight intercept devices, like pitfall traps, have the advantage of being easy to use and replicate, but their value to carabid surveys is largely unknown. Here we demonstrate the effectiveness of Malaise traps for sampling ground beetles in a bottomland hardwood forest.

  10. Using malaise traps to sample ground beetles (Coleoptera: Carabidae).

    SciTech Connect (OSTI)

    Ulyshen, Michael D., James L. Hanula, and Scott Horn

    2005-01-01

    Pitfall traps provide an easy and inexpensive way to sample ground-dwelling arthropods (Spence and Niemela 1994; Spence et al. 1997; Abildsnes and Tommeras 2000) and have been used exclusively in many studies of the abundance and diversity of ground beetles (Coleoptera: Carabidae). Despite the popularity of this trapping technique, pitfall traps have many disadvantages. For example, they often fail to collect both small (Spence and Niemela 1994) and ?¢????trap-shy?¢??? species (Benest 1989), eventually deplete the local carabid population (Digweed et al. 1995), require a species to be ground-dwelling in order to be captured (Liebherr and Mahar 1979), and produce different results depending on trap diameter and material, type of preservative used, and trap placement (Greenslade 1964; Luff 1975; Work et al. 2002). Further complications arise from seasonal patterns of movement among the beetles themselves (Maelfait and Desender 1990), as well as numerous climatic factors, differences in plant cover, and variable surface conditions (Adis 1979). Because of these limitations, pitfall trap data give an incomplete picture of the carabid community and should be interpreted carefully. Additional methods, such as use of Berlese funnels and litter washing (Spence and Niemela 1994), collection from lights (Usis and MacLean 1998), and deployment of flight intercept devices (Liebherr and Mahar 1979; Paarmann and Stork 1987), should be incorporated in surveys to better ascertain the species composition and relative numbers of ground beetles. Flight intercept devices, like pitfall traps, have the advantage of being easy to use and replicate, but their value to carabid surveys is largely unknown. Here we demonstrate the effectiveness of Malaise traps for sampling ground beetles in a bottomland hardwood forest.

  11. High Performance Ion Mobility Spectrometry Using Hourglass Electrodynamic Funnel And Internal Ion Funnel

    DOE Patents [OSTI]

    Smith, Richard D. (Richland, WA); Tang, Keqi (Richland, WA); Shvartsburg, Alexandre A. (Richland, WA)

    2005-11-22

    A method and apparatus enabling increased sensitivity in ion mobility spectrometry/mass spectrometry instruments which substantially reduces or eliminates the loss of ions in ion mobility spectrometer drift tubes utilizing a device for transmitting ions from an ion source which allows the transmission of ions without significant delay to an hourglass electrodynamic ion funnel at the entrance to the drift tube and/or an internal ion funnel at the exit of the drift tube. An hourglass electrodynamic funnel is formed of at least an entry element, a center element, and an exit element, wherein the aperture of the center element is smaller than the aperture of the entry element and the aperture of the exit elements. Ions generated in a relatively high pressure region by an ion source at the exterior of the hourglass electrodynamic funnel are transmitted to a relatively low pressure region at the entrance of the hourglass funnel through a conductance limiting orifice. Alternating and direct electrical potentials are applied to the elements of the hourglass electrodynamic funnel thereby drawing ions into and through the hourglass electrodynamic funnel thereby introducing relatively large quantities of ions into the drift tube while maintaining the gas pressure and composition at the interior of the drift tube as distinct from those at the entrance of the electrodynamic funnel and allowing a positive gas pressure to be maintained within the drift tube, if desired. An internal ion funnel is provided within the drift tube and is positioned at the exit of said drift tube. The advantage of the internal ion funnel is that ions that are dispersed away from the exit aperture within the drift tube, such as those that are typically lost in conventional drift tubes to any subsequent analysis or measurement, are instead directed through the exit of the drift tube, vastly increasing the amount of ions exiting the drift tube.

  12. Molecular Characterization of S- and N-containing Organic Constituents in Ambient Aerosols by negative ion mode High-Resolution Nanospray Desorption Electrospray Ionization Mass Spectrometry: CalNex 2010 field study

    SciTech Connect (OSTI)

    O'Brien, Rachel E.; Laskin, Alexander; Laskin, Julia; Rubitschun, Caitlin L.; Surratt, Jason D.; Goldstein, Allen H.

    2014-11-27

    Samples of ambient aerosols from the 2010 California Research at the Nexus of Air Quality and Climate Change (CalNex) field study were analyzed using Nanospray Desorption Electrospray Ionization High Resolution Mass Spectrometry (nano-DESI/MS). Four samples per day were collected in Bakersfield, CA on June 20-24 with a collection time of 6 hours per sample. Four characteristic groups of organic constituents were identified in the samples: compounds containing carbon, hydrogen, and oxygen only (CHO), sulfur- (CHOS), nitrogen-(CHON), and both nitrogen- and sulfur-containing organics (CHONS). Within the groups, organonitrates, organosulfates, and nitroxy organosulfates were assigned based on accurate mass measurements and elemental ratio comparisons. Changes in the chemical composition of the aerosol samples were observed throughout the day. The number of observed CHO compounds increased in the afternoon samples, suggesting regional photochemical processing as a source. The average number of CHOS compounds had the smallest changes throughout the day, consistent with a more broadly distributed source. Both of the nitrogen-containing groups (CHON and CHONS) had greater numbers of compounds in the night and morning samples, indicating that nitrate radical chemistry was likely a source for those compounds. Most of the compounds were found in submicron particles. The size distribution of CHON compounds was bimodal. We conclude that the majority of the compounds observed were secondary in nature with both biogenic and anthropogenic sources.

  13. Movement of particles using sequentially activated dielectrophoretic particle trapping

    DOE Patents [OSTI]

    Miles, Robin R.

    2004-02-03

    Manipulation of DNA and cells/spores using dielectrophoretic (DEP) forces to perform sample preparation protocols for polymerized chain reaction (PCR) based assays for various applications. This is accomplished by movement of particles using sequentially activated dielectrophoretic particle trapping. DEP forces induce a dipole in particles, and these particles can be trapped in non-uniform fields. The particles can be trapped in the high field strength region of one set of electrodes. By switching off this field and switching on an adjacent electrodes, particles can be moved down a channel with little or no flow.

  14. Trap seal for open circuit liquid cooled turbines

    DOE Patents [OSTI]

    Grondahl, Clayton M. (Clifton Park, NY); Germain, Malcolm R. (Ballston Lake, NY)

    1980-01-01

    An improved trap seal for open circuit liquid cooled turbines is disclosed. The trap seal of the present invention includes an annular recess formed in the supply conduit of cooling channels formed in the airfoil of the turbine buckets. A cylindrical insert is located in the annular recesses and has a plurality of axial grooves formed along the outer periphery thereof and a central recess formed in one end thereof. The axial grooves and central recess formed in the cylindrical insert cooperate with the annular recess to define a plurality of S-shaped trap seals which permit the passage of liquid coolant but prohibit passage of gaseous coolant.

  15. Modeling the Regeneration Chemistry of Lean NOx Traps | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy the Regeneration Chemistry of Lean NOx Traps Modeling the Regeneration Chemistry of Lean NOx Traps Presentation given at DEER 2006, August 20-24, 2006, Detroit, Michigan. Sponsored by the U.S. DOE's EERE FreedomCar and Fuel Partnership and 21st Century Truck Programs. PDF icon 2006_deer_larson.pdf More Documents & Publications Kinetic and Performance Studies of the Regeneration Phase of Model Pt/Rh/Ba NOx Traps for Design and Optimization Production, Storage, and FC Analysis

  16. Nitrogen Oxides as a Chemistry Trap in Detonating Oxygen-Rich...

    Office of Scientific and Technical Information (OSTI)

    Conference: Nitrogen Oxides as a Chemistry Trap in Detonating Oxygen-Rich Materials Citation Details In-Document Search Title: Nitrogen Oxides as a Chemistry Trap in Detonating...

  17. Nitrogen Oxides as a Chemistry Trap in Detonating Oxygen-Rich...

    Office of Scientific and Technical Information (OSTI)

    Conference: Nitrogen Oxides as a Chemistry Trap in Detonating Oxygen-Rich Materials Citation Details In-Document Search Title: Nitrogen Oxides as a Chemistry Trap in Detonating ...

  18. Small system for tritium accelerator mass spectrometry

    DOE Patents [OSTI]

    Roberts, M.L.; Davis, J.C.

    1993-02-23

    Apparatus for ionizing and accelerating a sample containing isotopes of hydrogen and detecting the ratios of hydrogen isotopes contained in the sample is disclosed. An ion source generates a substantially linear ion beam including ions of tritium from the sample. A radio-frequency quadrupole accelerator is directly coupled to and axially aligned with the source at an angle of substantially zero degrees. The accelerator accelerates species of the sample having different mass to different energy levels along the same axis as the ion beam. A spectrometer is used to detect the concentration of tritium ions in the sample. In one form of the invention, an energy loss spectrometer is used which includes a foil to block the passage of hydrogen, deuterium and [sup 3]He ions, and a surface barrier or scintillation detector to detect the concentration of tritium ions. In another form of the invention, a combined momentum/energy loss spectrometer is used which includes a magnet to separate the ion beams, with Faraday cups to measure the hydrogen and deuterium and a surface barrier or scintillation detector for the tritium ions.

  19. Ion Monitoring

    DOE Patents [OSTI]

    Orr, Christopher Henry (Calderbridge, GB); Luff, Craig Janson (Calderbridge, GB); Dockray, Thomas (Calderbridge, GB); Macarthur, Duncan Whittemore (Los Alamos, NM)

    2003-11-18

    The apparatus and method provide a technique for significantly reducing capacitance effects in detector electrodes arising due to movement of the instrument relative to the item/location being monitored in ion detection based techniques. The capacitance variations are rendered less significant by placing an electrically conducting element between the detector electrodes and the monitored location/item. Improved sensitivity and reduced noise signals arise as a result. The technique also provides apparatus and method suitable for monitoring elongate items which are unsuited to complete enclosure in one go within a chamber. The items are monitored part by part as the pass through the instrument, so increasing the range of items or locations which can be successfully monitored.

  20. Ion mobility sensor

    DOE Patents [OSTI]

    Koo, Jackson C.; Yu, Conrad M.

    2005-08-23

    An ion mobility sensor which can detect both ion and molecules simultaneously. Thus, one can measure the relative arrival times between various ions and molecules. Different ions have different mobility in air, and the ion sensor enables measurement of ion mobility, from which one can identify the various ions and molecules. The ion mobility sensor which utilizes a pair of glow discharge devices may be designed for coupling with an existing gas chromatograph, where various gas molecules are already separated, but numbers of each kind of molecules are relatively small, and in such cases a conventional ion mobility sensor cannot be utilized.

  1. Vacuum chamber for ion manipulation device

    DOE Patents [OSTI]

    Chen, Tsung-Chi; Tang, Keqi; Ibrahim, Yehia M; Smith, Richard D; Anderson, Gordon A; Baker, Erin M

    2014-12-09

    An ion manipulation method and device is disclosed. The device includes a pair of substantially parallel surfaces. An array of inner electrodes is contained within, and extends substantially along the length of, each parallel surface. The device includes a first outer array of electrodes and a second outer array of electrodes. Each outer array of electrodes is positioned on either side of the inner electrodes, and is contained within and extends substantially along the length of each parallel surface. A DC voltage is applied to the first and second outer array of electrodes. A RF voltage, with a superimposed electric field, is applied to the inner electrodes by applying the DC voltages to each electrode. Ions either move between the parallel surfaces within an ion confinement area or along paths in the direction of the electric field, or can be trapped in the ion confinement area. A predetermined number of pairs of surfaces are disposed in one or more chambers, forming a multiple-layer ion mobility cyclotron device.

  2. Method and apparatus for selective filtering of ions

    DOE Patents [OSTI]

    Page, Jason S. (Kennewick, WA); Tang, Keqi (Richland, WA); Smith, Richard D. (Richland, WA)

    2009-04-07

    An adjustable, low mass-to-charge (m/z) filter is disclosed employing electrospray ionization to block ions associated with unwanted low m/z species from entering the mass spectrometer and contributing their space charge to down-stream ion accumulation steps. The low-mass filter is made by using an adjustable potential energy barrier from the conductance limiting terminal electrode of an electrodynamic ion funnel, which prohibits species with higher ion mobilities from being transmitted. The filter provides a linear voltage adjustment of low-mass filtering from m/z values from about 50 to about 500. Mass filtering above m/z 500 can also be performed; however, higher m/z species are attenuated. The mass filter was evaluated with a liquid chromatography-mass spectrometry analysis of an albumin tryptic digest and resulted in the ability to block low-mass, "background" ions which account for 40-70% of the total ion current from the ESI source during peak elution.

  3. Combined distance-of-flight and time-of-flight mass spectrometer

    DOE Patents [OSTI]

    Enke, Christie G; Ray, Steven J; Graham, Alexander W; Hieftje, Gary M; Barinaga, Charles J; Koppenaal, David W

    2014-02-11

    A combined distance-of-flight mass spectrometry (DOFMS) and time-of-flight mass spectrometry (TOFMS) instrument includes an ion source configured to produce ions having varying mass-to-charge ratios, a first detector configured to determine when each of the ions travels a predetermined distance, a second detector configured to determine how far each of the ions travels in a predetermined time, and a detector extraction region operable to direct portions of the ions either to the first detector or to the second detector.

  4. Lean NOx Trap Regeneration Selectivity Towards N2O -- Similarities...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Towards N2O -- Similarities and Differences Between H2, CO and C3H6 Reductants Lean NOx Trap Regeneration Selectivity Towards N2O -- Similarities and Differences Between H2,...

  5. Inspect and Repair Steam Traps - Steam Tip Sheet #1

    SciTech Connect (OSTI)

    2012-01-31

    This revised AMO tip sheet on inspecting and repairing steam traps provides how-to advice for improving industrial steam systems using low-cost, proven practices and technologies.

  6. Laser-driven Sisyphus cooling in an optical dipole trap

    SciTech Connect (OSTI)

    Ivanov, Vladyslav V.; Gupta, Subhadeep

    2011-12-15

    We propose a laser-driven Sisyphus-cooling scheme for atoms confined in a far-off resonance optical dipole trap. Utilizing the differential trap-induced ac Stark shift, two electronic levels of the atom are resonantly coupled by a cooling laser preferentially near the trap bottom. After absorption of a cooling photon, the atom loses energy by climbing the steeper potential, and then spontaneously decays preferentially away from the trap bottom. The proposed method is particularly suited to cooling alkaline-earth-metal-like atoms where two-level systems with narrow electronic transitions are present. Numerical simulations for the cases of {sup 88}Sr and {sup 174}Yb demonstrate the expected recoil and Doppler temperature limits. The method requires a relatively small number of scattered photons and can potentially lead to phase-space densities approaching quantum degeneracy in subsecond time scales.

  7. Stable Metal-Organic Frameworks Containing Single-Molecule Traps...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Stable Metal-Organic Frameworks Containing Single-Molecule Traps for Enzyme Encapsulation Previous Next List Dawei Feng, Tian-Fu Liu, Jie Su, Mathieu Bosch, Zhangwen Wei, Wei Wan,...

  8. Stories of Discovery & Innovation: Trapping the Light Fantastic...

    Office of Science (SC) Website

    Trapping the Light Fantastic Energy Frontier Research Centers (EFRCs) EFRCs Home Centers ... Print Text Size: A A A Subscribe FeedbackShare Page New solar cell design uses advanced ...

  9. Observation of Ti{sup 4+} ions in a high power impulse magnetron sputtering plasma

    SciTech Connect (OSTI)

    Andersson, Joakim; Anders, Andre; Ehiasarian, Arutiun P.

    2008-08-18

    Multiply charged titanium ions including Ti{sup 4+} were observed in high power impulse magnetron sputtering discharges. Mass/charge spectrometry was used to identify metal ion species. Quadruply charged titanium ions were identified by isotope-induced broadening at mass/charge 12. Due to their high potential energy, Ti{sup 4+} ions give a high yield of secondary electrons, which in turn are likely to be responsible for the generation of multiply charged states.

  10. Negative ion beam injection apparatus with magnetic shield and electron removal means

    DOE Patents [OSTI]

    Anderson, Oscar A. (Berkeley, CA); Chan, Chun F. (Hayward, CA); Leung, Ka-Ngo (Hercules, CA)

    1994-01-01

    A negative ion source is constructed to produce H.sup.- ions without using Cesium. A high percentage of secondary electrons that typically accompany the extracted H.sup.- are trapped and eliminated from the beam by permanent magnets in the initial stage of acceleration. Penetration of the magnetic field from the permanent magnets into the ion source is minimized. This reduces the destructive effect the magnetic field could have on negative ion production and extraction from the source. A beam expansion section in the extractor results in a strongly converged final beam.

  11. Generic equilibration dynamics of planar defects in trapped atomic

    Office of Scientific and Technical Information (OSTI)

    superfluids (Journal Article) | DOE PAGES Generic equilibration dynamics of planar defects in trapped atomic superfluids « Prev Next » Title: Generic equilibration dynamics of planar defects in trapped atomic superfluids Authors: Scherpelz, Peter ; Padavić, Karmela ; Murray, Andy ; Glatz, Andreas ; Aranson, Igor S. ; Levin, K. Publication Date: 2015-03-18 OSTI Identifier: 1179955 Type: Publisher's Accepted Manuscript Journal Name: Physical Review A Additional Journal Information: Journal

  12. Effects of magnetization on fusion product trapping and secondary neutron

    Office of Scientific and Technical Information (OSTI)

    spectra (Journal Article) | DOE PAGES Effects of magnetization on fusion product trapping and secondary neutron spectra This content will become publicly available on May 14, 2016 « Prev Next » Title: Effects of magnetization on fusion product trapping and secondary neutron spectra In magnetizing the fusion fuel in inertial confinement fusion (ICF) systems, we found that the required stagnation pressure and density can be relaxed dramatically. This happens because the magnetic field

  13. Generic equilibration dynamics of planar defects in trapped atomic

    Office of Scientific and Technical Information (OSTI)

    superfluids (Journal Article) | SciTech Connect SciTech Connect Search Results Journal Article: Generic equilibration dynamics of planar defects in trapped atomic superfluids Citation Details In-Document Search Title: Generic equilibration dynamics of planar defects in trapped atomic superfluids Authors: Scherpelz, Peter ; Padavić, Karmela ; Murray, Andy ; Glatz, Andreas ; Aranson, Igor S. ; Levin, K. Publication Date: 2015-03-18 OSTI Identifier: 1179955 Type: Publisher's Accepted

  14. A Sub-Millimeter Solenoid Device for Trapping Paramagnetic Microbeads

    Office of Scientific and Technical Information (OSTI)

    (Conference) | SciTech Connect A Sub-Millimeter Solenoid Device for Trapping Paramagnetic Microbeads Citation Details In-Document Search Title: A Sub-Millimeter Solenoid Device for Trapping Paramagnetic Microbeads × You are accessing a document from the Department of Energy's (DOE) SciTech Connect. This site is a product of DOE's Office of Scientific and Technical Information (OSTI) and is provided as a public service. Visit OSTI to utilize additional information resources in energy science

  15. Advanced Gasification Mercury/Trace Metal Control with Monolith Traps

    Office of Scientific and Technical Information (OSTI)

    (Technical Report) | SciTech Connect Advanced Gasification Mercury/Trace Metal Control with Monolith Traps Citation Details In-Document Search Title: Advanced Gasification Mercury/Trace Metal Control with Monolith Traps × You are accessing a document from the Department of Energy's (DOE) SciTech Connect. This site is a product of DOE's Office of Scientific and Technical Information (OSTI) and is provided as a public service. Visit OSTI to utilize additional information resources in energy

  16. Correlation measurements in nuclear {beta}-decay using traps and polarized low energy beams

    SciTech Connect (OSTI)

    Naviliat-Cuncic, Oscar

    2013-05-06

    Precision measurements in nuclear {beta}-decay provide sensitive means to test discrete symmetries in the weak interaction and to determine some of the fundamental constants in semi-leptonic decays, like the coupling of the lightest quarks to charged weak bosons. The main motivation of such measurements is to find deviations from Standard Model predictions as possible indications of new physics. In this contribution I will focus on two topics related to precision measurements in nuclear {beta}-decay: i) the determination of the V{sub ud} element of the Cabibbo-Kobayashi-Maskawa quark mixing matrix from nuclear mirror transitions and ii) the search for exotic scalar or tensor contributions from {beta}{nu} angular correlations. The purpose is to underline the role being played by experimental techniques based on the confinement of radioactive species with atom and ion traps as well as the plans to use low energy polarized beams.

  17. Theory of Fine-scale Zonal Flow Generation From Trapped Electron Mode Turbulence

    SciTech Connect (OSTI)

    Lu Wang and T.S. Hahm

    2009-06-11

    Most existing zonal flow generation theory has been developed with a usual assumption of qr?? << 1 (qr is the radial wave number of zonal flow, and ?? is the ion poloidal gyrora- dius). However, recent nonlinear gyrokinetic simulations of trapped electron mode (TEM) turbulence exhibit a relatively short radial scale of the zonal flows with qr?? ~ 1 [Z. Lin et al., IAEA-CN/TH/P2-8 (2006); D. Ernst et al., Phys. Plasmas 16, 055906 (2009)]. This work reports an extension of zonal flow growth calculation to this short wavelength regime via the wave kinetics approach. A generalized expression for the polarization shielding for arbitrary radial wavelength [Lu Wang and T.S. Hahm, to appear in Phys. Plasmas (2009)] which extends the Rosenbluth-Hinton formula in the long wavelength limit is applied.

  18. Investigation of Aging Mechanisms in Lean NOx Traps

    SciTech Connect (OSTI)

    Mark Crocker

    2010-03-31

    Lean NO{sub x} traps (LNTs) represent a promising technology for the abatement of NO{sub x} under lean conditions. Although LNTs are starting to find commercial application, the issue of catalyst durability remains problematic. LNT susceptibility to sulfur poisoning is the single most important factor determining effective catalyst lifetime. The NO{sub x} storage element of the catalyst has a greater affinity for SO{sub 3} than it does for NO{sub 2}, and the resulting sulfate is more stable than the stored nitrate. Although this sulfate can be removed from the catalyst by means of high temperature treatment under rich conditions, the required conditions give rise to deactivation mechanisms such as precious metal sintering, total surface area loss, and solid state reactions between the various oxides present. The principle objective of this project was to improve understanding of the mechanisms of lean NO{sub x} trap aging, and to understand the effect of washcoat composition on catalyst aging characteristics. The approach utilized involved detailed characterization of model catalysts prior to and after aging, in tandem with measurement of catalyst performance in NO{sub x} storage and reduction. In this manner, NO{sub x} storage and reduction characteristics were correlated with the evolution of catalyst physico-chemical properties upon aging. Rather than using poorly characterized proprietary catalysts, or simple model catalysts of the Pt/BaO/Al{sub 2}O{sub 3} type (representing the first generation of LNTs), Pt/Rh/BaO/Al{sub 2}O{sub 3} catalysts were employed which also incorporated CeO{sub 2} or CeO{sub 2}-ZrO{sub 2}, representing a model system which more accurately reflects current LNT formulations. Catalysts were prepared in which the concentration of each of the main components was systematically varied: Pt (50, 75 or 100 g/ft{sup 3}), Rh (10 or 20 g/ft{sup 3}), BaO (15, 30 or 45 g/L), and either CeO{sub 2} (0, 50 or 100 g/L) or CeO{sub 2}-ZrO{sub 2} (0, 50 or 100 g/L). A high surface area La-stabilized alumina was used to support the BaO phase. Catalysts were obtained by washcoating onto standard cordierite substrates, the total washcoat loading being set at 260 g/L. La-stabilized alumina was used as the balance. Subsequent to de-greening, the NO{sub x} storage and reduction characteristics of the catalysts were evaluated on a bench reactor, after which the catalysts were aged on a bench reactor to the equivalent of ca. 75,000 miles of road aging using a published accelerated aging protocol. The aged catalysts were then subjected to the same evaluation proecdure used for the de-greened catalysts. In addition to the use of standard physico-chemical analytical techniques for studying the fresh and aged model catalysts, use was made of advanced analytical tools for characterizing their NO{sub x} storage/reduction and sulfation/desulfation characteristics, such as Spatially resolved capillary-inlet Mass Spectrometry (SpaciMS) and in situ Diffuse Reflectance Infrared Fourier Transform Spectroscopy (DRIFTS).

  19. Subcellular analysis by laser ablation electrospray ionization mass spectrometry

    DOE Patents [OSTI]

    Vertes, Akos; Stolee, Jessica A; Shrestha, Bindesh

    2014-12-02

    In various embodiments, a method of laser ablation electrospray ionization mass spectrometry (LAESI-MS) may generally comprise micro-dissecting a cell comprising at least one of a cell wall and a cell membrane to expose at least one subcellular component therein, ablating the at least one subcellular component by an infrared laser pulse to form an ablation plume, intercepting the ablation plume by an electrospray plume to form ions, and detecting the ions by mass spectrometry.

  20. Characterization of Traveling Wave Ion Mobility Separations in Structures for Lossless Ion Manipulations

    SciTech Connect (OSTI)

    Hamid, Ahmed M.; Ibrahim, Yehia M.; Garimella, Venkata BS; Webb, Ian K.; Deng, Liulin; Chen, Tsung-Chi; Anderson, Gordon A.; Prost, Spencer A.; Norheim, Randolph V.; Tolmachev, Aleksey V.; Smith, Richard D.

    2015-10-28

    We report on the development and characterization of a new traveling wave-based Structure for Lossless Ion Manipulations (TW-SLIM) for ion mobility separations (IMS). The TW-SLIM module uses a parallel array of RF electrodes for ion confinement, spaced by an array of short DC electrodes to which a TW can be applied to drive ion motion. The ability of the TW-SLIM for efficient ion confinement, lossless ion transport, and ion mobility separations at different RF and TW parameters is reported. The TW-SLIM module is shown to allow transfers a wide mass range of ions (200-2500 Da) utilizing a confining RF waveform (1 MHz and 300 Vp-p), and low TW amplitudes (<20 V). Also, the short module achieved an ion mobility peak capacity of 24 and a peak generation rate of 1014 s-1 for TW speeds of <210 m/s. TW-SLIM performance was characterized over a wide range of RF and DC voltage parameters, and demonstrated robust performance. The combined attributes of flexible design and low voltage requirements for traveling wave IMS, provide a basis for SLIM devices incorporating extended series of ion manipulations.

  1. Characterization of Plasma Membrane Proteins from Ovarian Cancer Cells Using Mass Spectrometry

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Springer, David L.; Auberry, Deanna L.; Ahram, Mamoun; Adkins, Joshua N.; Feldhaus, Jane M.; Wahl, Jon H.; Wunschel, David S.; Rodland, Karin D.

    2004-01-01

    To determine how the repertoire of plasma membrane proteins change with disease state, specifically related to cancer, several methods for preparation of plasma membrane proteins were evaluated. Cultured cells derived from stage IV ovarian tumors were grown to 90% confluence and harvested in buffer containing CHAPS detergent. This preparation was centrifuged at low speed to remove insoluble cellular debris resulting in a crude homogenate. Glycosylated proteins in the crude homogenate were selectively enriched using lectin affinity chromatography. The crude homogenate and the lectin purified sample were prepared for mass spectrometric evaluation. The general procedure for protein identification began with trypsinmore » digestion of protein fractions followed by separation by reversed phase liquid chromatography that was coupled directly to a conventional tandem mass spectrometer (i.e. LCQ ion trap). Mass and fragmentation data for the peptides were searched against a human proteome data base using the informatics program SEQUEST. Using this procedure 398 proteins were identified with high confidence, including receptors, membrane-associated ligands, proteases, phosphatases, as well as structural and adhesion proteins. Results indicate that lectin chromatography provides a select subset of proteins and that the number and quality of the identifications improve as does the confidence of the protein identifications for this subset. These results represent the first step in development of methods to separate and successfully identify plasma membrane proteins from advanced ovarian cancer cells. Further characterization of plasma membrane proteins will contribute to our understanding of the mechanisms underlying progression of this deadly disease and may lead to new targeted interventions as well as new biomarkers for diagnosis.« less

  2. Characterization of Plasma Membrane Proteins from Ovarian Cancer Cells Using Mass Spectrometry

    SciTech Connect (OSTI)

    Springer, David L.; Auberry, Deanna L.; Ahram, Mamoun; Adkins, Joshua N.; Feldhaus, Jane M.; Wahl, Jon H.; Wunsch, David M.; Rodland, Karin D.

    2003-01-01

    To determine how the repertoire of plasma membrane proteins change with disease state, specifically related to cancer, several methods for preparation of plasma membrane proteins were evaluated. Cultured cells derived from stage IV ovarian tumors were grown to 90% confluence and harvested in buffer containing CHAPS detergent. This preparation was centrifuged at low speed to remove insoluble cellular debris resulting in a crude homogenate. Glycosylated proteins in the crude homogenate were selectively enriched using lectin affinity chromatography. The crude homogenate and the lectin purified sample were prepared for mass spectrometric evaluation. The general procedure for protein identification began with trypsin digestion of protein fractions followed by separation by reversed phase liquid chromatography that was coupled directly to a conventional tandem mass spectrometer (i.e. LCQ ion trap). Mass and fragmentation data for the peptides were searched against a human proteome data base using the informatics program SEQUEST. Using this procedure 398 proteins were identified with high confidence, including receptors, membrane-associated ligands, proteases, phosphatases, as well as structural and adhesion proteins. Results indicate that lectin chromatography provides a select subset of proteins and that the number and quality of the identifications improve as does the confidence of the protein identifications for this subset. These results represent the first step in development of methods to separate and successfully identify plasma membrane proteins from advanced ovarian cancer cells. Further characterization of plasma membrane proteins will contribute to our understanding of the mechanisms underlying progression of this deadly disease and may lead to new targeted interventions as well as new biomarkers for diagnosis.

  3. Low pressure electrospray ionization system and process for effective transmission of ions

    DOE Patents [OSTI]

    Tang, Keqi (Richland, WA); Page, Jason S. (Kennewick, WA); Kelly, Ryan T. (Wet Richland, WA); Smith, Richard D. (Richland, WA)

    2010-03-02

    A system and method are disclosed that provide up to complete transmission of ions between coupled stages with low effective ion losses. A novel "interfaceless" electrospray ionization system is further described that operates the electrospray at a reduced pressure such that standard electrospray sample solutions can be directly sprayed into an electrodynamic ion funnel which provides ion focusing and transmission of ions into a mass analyzer.

  4. System and method for trapping and measuring a charged particle in a liquid

    DOE Patents [OSTI]

    Reed, Mark A; Krstic, Predrag S; Guan, Weihua; Zhao, Xiongce

    2013-07-23

    A system and method for trapping a charged particle is disclosed. A time-varying periodic multipole electric potential is generated in a trapping volume. A charged particle under the influence of the multipole electric field is confined to the trapping volume. A three electrode configuration giving rise to a 3D Paul trap and a four planar electrode configuration giving rise to a 2D Paul trap are disclosed.

  5. System and method for trapping and measuring a charged particle in a liquid

    DOE Patents [OSTI]

    Reed, Mark A; Krstic, Predrag S; Guan, Weihua; Zhao, Xiongce

    2012-10-23

    A system and method for trapping a charged particle is disclosed. A time-varying periodic multipole electric potential is generated in a trapping volume. A charged particle under the influence of the multipole electric field is confined to the trapping volume. A three electrode configuration giving rise to a 3D Paul trap and a four planar electrode configuration giving rise to a 2D Paul trap are disclosed.

  6. Ion manipulation device with electrical breakdown protection

    DOE Patents [OSTI]

    Chen, Tsung-Chi; Tang, Keqi; Ibrahim, Yehia M; Smith, Richard D; Anderson, Gordon A; Baker, Erin M

    2014-12-02

    An ion manipulation method and device is disclosed. The device includes a pair of substantially parallel surfaces. An array of inner electrodes is contained within, and extends substantially along the length of, each parallel surface. The device includes a first outer array of electrodes and a second outer array of electrodes. Each outer array of electrodes is positioned on either side of the inner electrodes, and is contained within and extends substantially along the length of each parallel surface. A DC voltage is applied to the first and second outer array of electrodes. A RF voltage, with a superimposed electric field, is applied to the inner electrodes by applying the DC voltages to each electrode. Ions either move between the parallel surfaces within an ion confinement area or along paths in the direction of the electric field, or can be trapped in the ion confinement area. The surfaces are housed in a chamber, and at least one electrically insulative shield is coupled to an inner surface of the chamber for increasing a mean-free-path between two adjacent electrodes in the chamber.

  7. A multi-technique analysis of deuterium trapping and near-surface precipitate growth in plasma-exposed tungsten

    SciTech Connect (OSTI)

    Kolasinski, Robert; Shimada, Masashi; Oya, Yasuhisa; Buchenauer, Dean A.; Chikada, Takumi; Cowgill, Donald F.; Donovan, David; Friddle, Raymond William; Michibayashi, Katsu; Sato, Misaki

    2015-08-17

    We examine how deuterium becomes trapped in plasma-exposed tungsten and forms near-surface platelet-shaped precipitates. How these bubbles nucleate and grow, as well as the amount of deuterium trapped within, is crucial for interpreting the experimental database. Here, we use a combined experimental/theoretical approach to provide further insight into the underlying physics. With the Tritium Plasma Experiment, we exposed a series of ITER-gradetungsten samples to high flux D plasmas (up to 1.5 1022 m-2 s-1) at temperatures ranging between 103 and 554 C. Retention of deuterium trapped in the bulk, assessed through thermal desorption spectrometry, reached a maximum at 230 C and diminished rapidly thereafter for T > 300 C. Post-mortem examination of the surfaces revealed non-uniform growth of bubbles ranging in diameter between 1 and 10 ?m over the surface with a clear correlation with grain boundaries. Electron back-scattering diffraction maps over a large area of the surface confirmed this dependence; grains containing bubbles were aligned with a preferred slip vector along the <111> directions. Focused ion beam profiles suggest that these bubbles nucleated as platelets at depths of 200 nm1 ?m beneath the surface and grew as a result of expansion of sub-surface cracks. Furthermore, to estimate the amount of deuterium trapped in these defects relative to other sites within the material, we applied a continuum-scale treatment of hydrogen isotope precipitation. Additionally, we propose a straightforward model of near-surface platelet expansion that reproduces bubble sizes consistent with our measurements. For the tungsten microstructure considered here, we find that bubbles would only weakly affect migration of D into the material, perhaps explaining why deep trapping was observed in prior studies with plasma-exposed neutron-irradiated specimens. We foresee no insurmountable issues that would prevent the theoretical framework developed here from being extended to a broader range of systems where precipitation of insoluble gases in ion beam or plasma-exposed metals is of interest.

  8. A multi-technique analysis of deuterium trapping and near-surface precipitate growth in plasma-exposed tungsten

    SciTech Connect (OSTI)

    Kolasinski, Robert; Shimada, Masashi; Oya, Yasuhisa; Buchenauer, Dean A.; Chikada, Takumi; Cowgill, Donald F.; Donovan, David; Friddle, Raymond William; Michibayashi, Katsu; Sato, Misaki

    2015-08-17

    We examine how deuterium becomes trapped in plasma-exposed tungsten and forms near-surface platelet-shaped precipitates. How these bubbles nucleate and grow, as well as the amount of deuterium trapped within, is crucial for interpreting the experimental database. Here, we use a combined experimental/theoretical approach to provide further insight into the underlying physics. With the Tritium Plasma Experiment, we exposed a series of ITER-gradetungsten samples to high flux D plasmas (up to 1.5 × 1022 m-2 s-1) at temperatures ranging between 103 and 554 °C. Retention of deuterium trapped in the bulk, assessed through thermal desorption spectrometry, reached a maximum at 230 °C and diminished rapidly thereafter for T > 300 °C. Post-mortem examination of the surfaces revealed non-uniform growth of bubbles ranging in diameter between 1 and 10 μm over the surface with a clear correlation with grain boundaries. Electron back-scattering diffraction maps over a large area of the surface confirmed this dependence; grains containing bubbles were aligned with a preferred slip vector along the <111> directions. Focused ion beam profiles suggest that these bubbles nucleated as platelets at depths of 200 nm–1 μm beneath the surface and grew as a result of expansion of sub-surface cracks. Furthermore, to estimate the amount of deuterium trapped in these defects relative to other sites within the material, we applied a continuum-scale treatment of hydrogen isotope precipitation. Additionally, we propose a straightforward model of near-surface platelet expansion that reproduces bubble sizes consistent with our measurements. For the tungsten microstructure considered here, we find that bubbles would only weakly affect migration of D into the material, perhaps explaining why deep trapping was observed in prior studies with plasma-exposed neutron-irradiated specimens. We foresee no insurmountable issues that would prevent the theoretical framework developed here from being extended to a broader range of systems where precipitation of insoluble gases in ion beam or plasma-exposed metals is of interest.

  9. A multi-technique analysis of deuterium trapping and near-surface precipitate growth in plasma-exposed tungsten

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kolasinski, Robert; Shimada, Masashi; Oya, Yasuhisa; Buchenauer, Dean A.; Chikada, Takumi; Cowgill, Donald F.; Donovan, David; Friddle, Raymond William; Michibayashi, Katsu; Sato, Misaki

    2015-08-17

    We examine how deuterium becomes trapped in plasma-exposed tungsten and forms near-surface platelet-shaped precipitates. How these bubbles nucleate and grow, as well as the amount of deuterium trapped within, is crucial for interpreting the experimental database. Here, we use a combined experimental/theoretical approach to provide further insight into the underlying physics. With the Tritium Plasma Experiment, we exposed a series of ITER-gradetungsten samples to high flux D plasmas (up to 1.5 × 1022 m-2 s-1) at temperatures ranging between 103 and 554 °C. Retention of deuterium trapped in the bulk, assessed through thermal desorption spectrometry, reached a maximum at 230more » °C and diminished rapidly thereafter for T > 300 °C. Post-mortem examination of the surfaces revealed non-uniform growth of bubbles ranging in diameter between 1 and 10 μm over the surface with a clear correlation with grain boundaries. Electron back-scattering diffraction maps over a large area of the surface confirmed this dependence; grains containing bubbles were aligned with a preferred slip vector along the <111> directions. Focused ion beam profiles suggest that these bubbles nucleated as platelets at depths of 200 nm–1 μm beneath the surface and grew as a result of expansion of sub-surface cracks. Furthermore, to estimate the amount of deuterium trapped in these defects relative to other sites within the material, we applied a continuum-scale treatment of hydrogen isotope precipitation. Additionally, we propose a straightforward model of near-surface platelet expansion that reproduces bubble sizes consistent with our measurements. For the tungsten microstructure considered here, we find that bubbles would only weakly affect migration of D into the material, perhaps explaining why deep trapping was observed in prior studies with plasma-exposed neutron-irradiated specimens. We foresee no insurmountable issues that would prevent the theoretical framework developed here from being extended to a broader range of systems where precipitation of insoluble gases in ion beam or plasma-exposed metals is of interest.« less

  10. High-Performance Ion Mobility Spectrometry Using Hourglass Electrodynamic Funnel And Internal Ion Funnel

    DOE Patents [OSTI]

    Smith, Richard D. (Richland, WA); Tang, Keqi (Richland, WA); Shvartsburg, Alexandre A. (Richland, WA)

    2004-11-16

    A method and apparatus enabling increased sensitivity in ion mobility spectrometry/mass spectrometry instruments which substantially reduces or eliminates the loss of ions in ion mobility spectrometer drift tubes utilizing an hourglass electrodynamic ion funnel at the entrance to the drift tube and/or an internal ion funnel at the exit of the drift tube. An hourglass electrodynamic funnel is formed of at least an entry element, a center element, and an exit element, wherein the aperture of the center element is smaller than the aperture of the entry element and the aperture of the exit elements. Ions generated in a relatively high pressure region by an ion source at the exterior of the hourglass electrodynamic funnel are transmitted to a relatively low pressure region at the entrance of the hourglass funnel through a conductance limiting orifice. Alternating and direct electrical potentials are applied to the elements of the hourglass electrodynamic funnel thereby drawing ions into and through the hourglass electrodynamic funnel thereby introducing relatively large quantities of ions into the drift tube while maintaining the gas pressure and composition at the interior of the drift tube as distinct from those at the entrance of the electrodynamic funnel and allowing a positive gas pressure to be maintained within the drift tube, if desired. An internal ion funnel is provided within the drift tube and is positioned at the exit of said drift tube. The advantage of the internal ion funnel is that ions that are dispersed away from the exit aperture within the drift tube, such as those that are typically lost in conventional drift tubes to any subsequent analysis or measurement, are instead directed through the exit of the drift tube, vastly increasing the amount of ions exiting the drift tube.

  11. Ion sources for ion implantation technology (invited)

    SciTech Connect (OSTI)

    Sakai, Shigeki Hamamoto, Nariaki; Inouchi, Yutaka; Umisedo, Sei; Miyamoto, Naoki

    2014-02-15

    Ion sources for ion implantation are introduced. The technique is applied not only to large scale integration (LSI) devices but also to flat panel display. For LSI fabrication, ion source scheduled maintenance cycle is most important. For CMOS image sensor devices, metal contamination at implanted wafer is most important. On the other hand, to fabricate miniaturized devices, cluster ion implantation has been proposed to make shallow PN junction. While for power devices such as silicon carbide, aluminum ion is required. For doping processes of LCD fabrication, a large ion source is required. The extraction area is about 150 cm 10 cm, and the beam uniformity is important as well as the total target beam current.

  12. Recent progress in tailoring trap-based positron beams

    SciTech Connect (OSTI)

    Natisin, M. R.; Hurst, N. C.; Danielson, J. R.; Surko, C. M. [Physics Department, University of California, San Diego La Jolla CA 92093-0319 (United States)

    2013-03-19

    Recent progress is described to implement two approaches to specially tailor trap-based positron beams. Experiments and simulations are presented to understand the limits on the energy spread and pulse duration of positron beams extracted from a Penning-Malmberg (PM) trap after the particles have been buffer-gas cooled (or heated) in the range of temperatures 1000 {>=} T {>=} 300 K. These simulations are also used to predict beam performance for cryogenically cooled positrons. Experiments and simulations are also presented to understand the properties of beams formed when plasmas are tailored in a PM trap in a 5 tesla magnetic field, then non-adiabatically extracted from the field using a specially designed high-permeability grid to create a new class of electrostatically guided beams.

  13. Cocktails and Ions - 88-Inch Cyclotron

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Cocktails and Ions BASE Ion List Download as a .pdf

  14. Global strings in extra dimensions: The full map of solutions, matter trapping, and the hierarchy problem

    SciTech Connect (OSTI)

    Bronnikov, K. A.; Meierovich, B. E.

    2008-02-15

    We consider (d{sub 0} + 2)-dimensional configurations with global strings in two extra dimensions and a flat metric in d{sub 0} dimensions, endowed with a warp factor e{sup 2{gamma}} depending on the distance l from the string center. All possible regular solutions of the field equations are classified by the behavior of the warp factor and the extradimensional circular radius r(l). Solutions with r {yields} {infinity} and r {yields} const > 0 as l {yields} {infinity} are interpreted in terms of thick brane-world models. Solutions with r {yields} 0 as l {yields} l{sub c} > 0, i.e., those with a second center, are interpreted as either multibrane systems (which are appropriate for large enough distances l{sub c} between the centers) or as Kaluza-Klein-type configurations with extra dimensions invisible due to their smallness. In the case of the Mexican-hat symmetry-breaking potential, we build the full map of regular solutions on the ({epsilon}, {Gamma}) parameter plane, where {epsilon} acts as an effective cosmological constant and {Gamma} characterizes the gravitational field strength. The trapping properties of candidate brane worlds for test scalar fields are discussed. Good trapping properties for massive fields are found for models with increasing warp factors. Kaluza-Klein-type models are shown to have nontrivial warp factor behaviors, leading to matter particle mass spectra that seem promising from the standpoint of hierarchy problems.

  15. Global strings in extra dimensions: The full map of solutions, matter trapping, and the hierarchy problem

    SciTech Connect (OSTI)

    Bronnikov, K. A.; Meierovich, B. E.

    2008-02-15

    We consider (d{sub 0} + 2)-dimensional configurations with global strings in two extra dimensions and a flat metric in d{sub 0} dimensions, endowed with a warp factor e{sup 2{gamma}} depending on the distance l from the string center. All possible regular solutions of the field equations are classified by the behavior of the warp factor and the extradimensional circular radius r(l). Solutions with r {sup {yields}} {infinity} and r {sup {yields}} const > 0 as l {sup {yields}} {infinity} are interpreted in terms of thick brane-world models. Solutions with r {sup {yields}} 0 as l {sup {yields}} l{sub c} > 0, i.e., those with a second center, are interpreted as either multibrane systems (which are appropriate for large enough distances l{sub c} between the centers) or as Kaluza-Klein-type configurations with extra dimensions invisible due to their smallness. In the case of the Mexican-hat symmetry-breaking potential, we build the full map of regular solutions on the ({epsilon}, {gamma}) parameter plane, where {epsilon} acts as an effective cosmological constant and {gamma} characterizes the gravitational field strength. The trapping properties of candidate brane worlds for test scalar fields are discussed. Good trapping properties for massive fields are found for models with increasing warp factors. Kaluza-Klein-type models are shown to have nontrivial warp factor behaviors, leading to matter particle mass spectra that seem promising from the standpoint of hierarchy problems.

  16. Three dimensional separation trap based on dielectrophoresis and use thereof

    DOE Patents [OSTI]

    Mariella, Jr., Raymond P.

    2004-05-04

    An apparatus is adapted to separate target materials from other materials in a flow containing the target materials and other materials. A dielectrophoretic trap is adapted to receive the target materials and the other materials. At least one electrode system is provided in the trap. The electrode system has a three-dimensional configuration. The electrode system includes a first electrode and a second electrode that are shaped and positioned relative to each such that application of an electrical voltage to the first electrode and the second electrode creates a dielectrophoretic force and said dielectrophoretic force does not reach zero between the first electrode and the second electrode.

  17. Advanced Gasification Mercury/Trace Metal Control with Monolith Traps

    Office of Scientific and Technical Information (OSTI)

    (Technical Report) | SciTech Connect Advanced Gasification Mercury/Trace Metal Control with Monolith Traps Citation Details In-Document Search Title: Advanced Gasification Mercury/Trace Metal Control with Monolith Traps Two Corning monoliths and a non-carbon-based material have been identified as potential additives for mercury capture in syngas at temperatures above 400°F and pressure of 600 psig. A new Corning monolith formulation, GR-F1-2189, described as an active sample appeared to be

  18. Gallium hole traps in irradiated KTiOPO{sub 4}:Ga crystals

    SciTech Connect (OSTI)

    Grachev, V.; Meyer, M.; Malovichko, G.; Hunt, A. W.

    2014-12-07

    Nominally pure and gallium doped single crystals of potassium titanyl phosphate (KTiOPO{sub 4}) have been studied by Electron Paramagnetic Resonance at low temperatures before and after irradiation. Irradiation with 20?MeV electrons performed at room temperature and liquid nitrogen temperature caused an appearance of electrons and holes. Gallium impurities act as hole traps in KTiOPO{sub 4} creating Ga{sup 4+} centers. Two different Ga{sup 4+} centers were observed, Ga1 and Ga2. The Ga1 centers are dominant in Ga-doped samples. For the Ga1 center, a superhyperfine structure with one nucleus with nuclear spin was registered and attributed to the interaction of gallium electrons with a phosphorus nucleus or proton in its surrounding. In both Ga1 and Ga2 centers, Ga{sup 4+} ions substitute for Ti{sup 4+} ions, but with a preference to one of two electrically distinct crystallographic positions (site selective substitution). The Ga doping eliminates one of the shortcomings of KTP crystalsionic conductivity of bulk crystals. However, this does not improve significantly the resistance of the crystals to electron and ?-radiation.

  19. Reliable operation of the Brookhaven EBIS for highly charged ion production for RHIC and NSRL

    SciTech Connect (OSTI)

    Beebe, E. Alessi, J. Binello, S. Kanesue, T. McCafferty, D. Morris, J. Okamura, M. Pikin, A. Ritter, J. Schoepfer, R.

    2015-01-09

    An Electron Beam Ion Source for the Relativistic Heavy Ion Collider (RHIC EBIS) was commissioned at Brookhaven in September 2010 and since then it routinely supplies ions for RHIC and NASA Space Radiation Laboratory (NSRL) as the main source of highly charged ions from Helium to Uranium. Using three external primary ion sources for 1+ injection into the EBIS and an electrostatic injection beam line, ion species at the EBIS exit can be switched in 0.2 s. A total of 16 different ion species have been produced to date. The length and the capacity of the ion trap have been increased by 20% by extending the trap by two more drift tubes, compared with the original design. The fraction of Au{sup 32+} in the EBIS Au spectrum is approximately 12% for 70-80% electron beam neutralization and 8 pulses operation in a 5 Hertz train and 4-5 s super cycle. For single pulse per super cycle operation and 25% electron beam neutralization, the EBIS achieves the theoretical Au{sup 32+} fractional output of 18%. Long term stability has been very good with availability of the beam from RHIC EBIS during 2012 and 2014 RHIC runs approximately 99.8%.

  20. Apparatus and method for hydrogen and oxygen mass spectrometry of the terrestrial magnetosphere

    DOE Patents [OSTI]

    Funsten, Herbert O. (Los Alamos, NM); Dors, Eric E. (Los Alamos, NM); Harper, Ronnie W. (Los Alamos, NM); Reisenfeld, Daniel B. (Stevensville, MT)

    2007-05-15

    A detector element for mass spectrometry of a flux of heavy and light ions, that includes: a first detector to detect light ions that transit through a foil operatively placed in front of the first detector, and a second detector that detects the flux of heavy and light ions.

  1. Broad beam ion implanter

    DOE Patents [OSTI]

    Leung, Ka-Ngo (Hercules, CA)

    1996-01-01

    An ion implantation device for creating a large diameter, homogeneous, ion beam is described, as well as a method for creating same, wherein the device is characterized by extraction of a diverging ion beam and its conversion by ion beam optics to an essentially parallel ion beam. The device comprises a plasma or ion source, an anode and exit aperture, an extraction electrode, a divergence-limiting electrode and an acceleration electrode, as well as the means for connecting a voltage supply to the electrodes.

  2. Practical considerations in realizing a magnetic centrifugal mass filter

    SciTech Connect (OSTI)

    Gueroult, Renaud; Fisch, Nathaniel J.

    2012-12-15

    The magnetic centrifugal mass filter concept represents a variation on the plasma centrifuge, with applications that are particularly promising for high-throughput separation of ions with large mass differences. A number of considerations, however, constrain the parameter space in which this device operates best. The rotation speed, magnetic field intensity, and ion temperature are constrained by the ion confinement requirements. Collisions must also be large enough to eject ions, but small enough not to eject them too quickly. The existence of favorable regimes meeting these constraints is demonstrated by a single-particle orbit code. As an example of interest, it is shown that separation factors of about 2.3 are achievable in a single pass when separating Aluminum from Strontium ions.

  3. Practical Considerations in Realizing a Magnetic C entrifugal Mass Filter

    SciTech Connect (OSTI)

    Renaud Gueroult and Nathaniel J. Fisch

    2012-06-18

    The Magnetic Centrifugal Mass Filter concept represents a variation on the plasma centrifuge, with applications that are particularly promising for high-throughput separation of ions with large mass differences. A number of considerations, however, constrain the parameter space in which this device operates best. The rotation speed, magnetic field intensity and ion temperature are constrained by the ion confinement requirements. Collisions must also be large enough to eject ions, but small enough not to eject them too quickly. The existence of favorable regimes meeting these constraints is demonstrated by a single-particle orbit code. As an example of interest, it is shown that separation factors of about 2:3 are achievable in a single pass when separating Aluminum from Strontium ions

  4. An extension of the multiple-trapping model

    SciTech Connect (OSTI)

    Shkilev, V. P.

    2012-07-15

    The hopping charge transport in disordered semiconductors is considered. Using the concept of the transport energy level, macroscopic equations are derived that extend a multiple-trapping model to the case of semiconductors with both energy and spatial disorders. It is shown that, although both types of disorder can cause dispersive transport, the frequency dependence of conductivity is determined exclusively by the spatial disorder.

  5. Single particle density of trapped interacting quantum gases

    SciTech Connect (OSTI)

    Bala, Renu; Bosse, J.; Pathak, K. N.

    2015-05-15

    An expression for single particle density for trapped interacting gases has been obtained in first order of interaction using Greens function method. Results are easily simplified for homogeneous quantum gases and are found to agree with famous results obtained by Huang-Yang-Luttinger and Lee-Yang.

  6. ION Engineering | Open Energy Information

    Open Energy Info (EERE)

    ION Engineering Jump to: navigation, search Name: ION Engineering Place: Boulder, Colorado Zip: 80301 Sector: Carbon Product: ION is the first clean-tech company to successfully...

  7. Possible Diamond-Like Nanoscale Structures Induced by Slow Highly-Charged Ions on Graphite (HOPG)

    SciTech Connect (OSTI)

    Sideras-Haddad, E.; Schenkel, T.; Shrivastava, S.; Makgato, T.; Batra, A.; Weis, C. D.; Persaud, A.; Erasmus, R.; Mwakikunga, B.

    2009-01-06

    The interaction between slow highly-charged ions (SHCI) of different charge states from an electron-beam ion trap and highly oriented pyrolytic graphite (HOPG) surfaces is studied in terms of modification of electronic states at single-ion impact nanosizeareas. Results are presented from AFM/STM analysis of the induced-surface topological features combined with Raman spectroscopy. I-V characteristics for a number of different impact regions were measured with STM and the results argue for possible formation of diamond-like nanoscale structures at the impact sites.

  8. Manipulation of transport hysteresis on graphene field effect transistors with Ga ion irradiation

    SciTech Connect (OSTI)

    Wang, Quan, E-mail: wangq@mail.ujs.edu.cn [School of Mechanical Engineering, Jiangsu University, Zhenjiang 212013 (China); State Key Laboratory of Transducer Technology, Chinese Academy of Sciences, Shanghai 200050 (China); Liu, Shuai; Ren, Naifei [School of Mechanical Engineering, Jiangsu University, Zhenjiang 212013 (China)

    2014-09-29

    We have studied the effect of Ga ion irradiation on the controllable hysteretic behavior of graphene field effect transistors fabricated on Si/SO{sub 2} substrates. The various densities of defects in graphene were monitored by Raman spectrum. It was found that the Dirac point shifted to the positive gate voltage constantly, while the hysteretic behavior was enhanced first and then weakened, with the dose of ion irradiation increasing. By contrasting the trap charges density induced by dopant and the total density of effective trap charges, it demonstrated that adsorbate doping was not the decisive factor that induced the hysteretic behavior. The tunneling between the defect sites induced by ion irradiation was also an important cause for the hysteresis.

  9. Applications of decelerated ions

    SciTech Connect (OSTI)

    Johnson, B.M.

    1985-03-01

    Many facilities whose sole purpose had been to accelerate ion beams are now becoming decelerators as well. The development and current status of accel-decel operations is reviewed here. Applications of decelerated ions in atomic physics experiments are discussed.

  10. Ion Beam Materials Lab

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the individual researchers' needs. The core of the laboratory consists of a 3 MV NEC tandem accelerator, a 200 kV Varian ion implanter, and a 200 kV Danfysik ion implanter...

  11. Single Ion Implantation

    ScienceCinema (OSTI)

    Thomas Schenkel

    2010-01-08

    On the equipment needed to implant ions in silicon and other materials. More information: http://newscenter.lbl.gov/f...

  12. Negative ion generator

    DOE Patents [OSTI]

    Stinnett, R.W.

    1984-05-08

    A negative ion generator is formed from a magnetically insulated transmission line having a coating of graphite on the cathode for producing negative ions and a plurality of apertures on the opposed anode for the release of negative ions. Magnetic insulation keeps electrons from flowing from the cathode to the anode. A transverse magnetic field removes electrons which do escape through the apertures from the trajectory of the negative ions. 8 figs.

  13. Negative ion generator

    DOE Patents [OSTI]

    Stinnett, Regan W. (Albuquerque, NM)

    1984-01-01

    A negative ion generator is formed from a magnetically insulated transmission line having a coating of graphite on the cathode for producing negative ions and a plurality of apertures on the opposed anode for the release of negative ions. Magnetic insulation keeps electrons from flowing from the cathode to the anode. A transverse magnetic field removes electrons which do escape through the apertures from the trajectory of the negative ions.

  14. X-ray radiography with highly charged ions

    DOE Patents [OSTI]

    Marrs, Roscoe E. (Livermore, CA)

    2000-01-01

    An extremely small (1-250 micron FWHM) beam of slow highly charged ions deexciting on an x-ray production target generates x-ray monochromatic radiation that is passed through a specimen and detected for imaging. The resolution of the x-ray radiograms is improved and such detection is achieved with relatively low dosages of radiation passing through the specimen. An apparatus containing an electron beam ion trap (and modifications thereof) equipped with a focusing column serves as a source of ions that generate radiation projected onto an image detector. Electronic and other detectors are able to detect an increased amount of radiation per pixel than achieved by previous methods and apparati.

  15. Production of Endohedral Fullerenes by Ion Implantation

    SciTech Connect (OSTI)

    Diener, M.D.; Alford, J. M.; Mirzadeh, S.

    2007-05-31

    The empty interior cavity of fullerenes has long been touted for containment of radionuclides during in vivo transport, during radioimmunotherapy (RIT) and radioimaging for example. As the chemistry required to open a hole in fullerene is complex and exceedingly unlikely to occur in vivo, and conformational stability of the fullerene cage is absolute, atoms trapped within fullerenes can only be released during extremely energetic events. Encapsulating radionuclides in fullerenes could therefore potentially eliminate undesired toxicity resulting from leakage and catabolism of radionuclides administered with other techniques. At the start of this project however, methods for production of transition metal and p-electron metal endohedral fullerenes were completely unknown, and only one method for production of endohedral radiofullerenes was known. They therefore investigated three different methods for the production of therapeutically useful endohedral metallofullerenes: (1) implantation of ions using the high intensity ion beam at the Oak Ridge National Laboratory (ORNL) Surface Modification and Characterization Research Center (SMAC) and fullerenes as the target; (2) implantation of ions using the recoil energy following alpha decay; and (3) implantation of ions using the recoil energy following neutron capture, using ORNL's High Flux Isotope Reactor (HFIR) as a thermal neutron source. While they were unable to obtain evidence of successful implantation using the ion beam at SMAC, recoil following alpha decay and neutron capture were both found to be economically viable methods for the production of therapeutically useful radiofullerenes. In this report, the procedures for preparing fullerenes containing the isotopes {sup 212}Pb, {sup 212}Bi, {sup 213}Bi, and {sup 177}Lu are described. None of these endohedral fullerenes had ever previously been prepared, and all of these radioisotopes are actively under investigation for RIT. Additionally, the chemistry for derivatizing the radiofullerenes for water-solubility and a method for removing exohedral radionuclides are reported. The methods and chemistry developed during this CRADA are the crucial first steps for the development of fullerenes as a method superior to existing technologies for in vivo transport of radionuclides.

  16. Analysis of fission gas release kinetics by on-line mass spectrometry

    SciTech Connect (OSTI)

    Zerega, Y.; Reynard-Carette, C.; Parrat, D.; Carette, M.; Brkic, B.; Lyoussi, A.; Bignan, G.; Janulyte, A.; Andre, J.; Pontillon, Y.; Ducros, G.; Taylor, S.

    2011-07-01

    The release of fission gas (Xe and Kr) and helium out of nuclear fuel materials in normal operation of a nuclear power reactor can constitute a strong limitation of the fuel lifetime. Moreover, radioactive isotopes of Xe and Kr contribute significantly to the global radiological source term released in the primary coolant circuit in case of accidental situations accompanied by fuel rod loss of integrity. As a consequence, fission gas release investigation is of prime importance for the nuclear fuel cycle economy, and is the driven force of numerous R and D programs. In this domain, for solving current fuel behavior understanding issues, preparing the development of new fuels (e.g. for Gen IV power systems) and for improving the modeling prediction capability, there is a marked need for innovations in the instrumentation field, mainly for: . Quantification of very low fission gas concentrations, released from fuel sample and routed in sweeping lines. Monitoring of quick gas release variations by quantification of elementary release during a short period of time. Detection of a large range of atomic masses (e.g. H{sub 2}, HT, He, CO, CO{sub 2}, Ne, Ar, Kr, Xe), together with a performing separation of isotopes for Xe and Kr elements. Coupling measurement of stable and radioactive gas isotopes, by using in parallel mass spectrometry and gamma spectrometry techniques. To fulfill these challenging needs, a common strategy for analysis equipment implementation has been set up thanks to a recently launched collaboration between the CEA and the Univ. of Provence, with the technological support of the Liverpool Univ.. It aims at developing a chronological series of mass spectrometer devices based upon mass filter and 2D/3D ion traps with Fourier transform operating mode and having increasing levels of performances to match the previous challenges for out-of pile and in-pile experiments. The final objective is to install a high performance online mass spectrometer coupled to a gamma spectrometer in the fission product laboratory of the future Jules Horowitz Material Test Reactor. An intermediate step will consist of testing first equipment on an existing experimental facility in the LECA-STAR Hot Cell Laboratory of the CEA Cadarache. This paper presents the scientific and operational stakes linked to fission gas issues, resumes the current state of art for analyzing them in nuclear facilities, then presents the skills gathered through this collaboration to overcome technological bottlenecks. Finally it describes the implementation strategy in nuclear research facilities of the CEA Cadarache. (authors)

  17. Vertically Integrated Mass Production of Automotive Class Lithium Ion Batteries

    Broader source: Energy.gov [DOE]

    2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  18. Vertically Integrated Mass Production of Automotive Class Lithium Ion

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Batteries | Department of Energy 1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon arravt018_es_alvarez

  19. Vertically Integrated Mass Production of Automotive Class Lithium Ion

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Batteries | Department of Energy 0 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C. PDF icon esarravt018_pinho

  20. Vertically Integrated Mass Production of Automotive Class Lithium Ion

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Batteries | Department of Energy 2 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting PDF icon arravt018_es_alvarez_2012

  1. High current multicharged metal ion source using high power gyrotron heating of vacuum arc plasma

    SciTech Connect (OSTI)

    Vodopyanov, A. V.; Golubev, S. V.; Khizhnyak, V. I.; Mansfeld, D. A.; Nikolaev, A. G.; Oks, E. M.; Savkin, K. P.; Vizir, A. V.; Yushkov, G. Yu.

    2008-02-15

    A high current, multi charged, metal ion source using electron heating of vacuum arc plasma by high power gyrotron radiation has been developed. The plasma is confined in a simple mirror trap with peak magnetic field in the plug up to 2.5 T, mirror ratio of 3-5, and length variable from 15 to 20 cm. Plasma formed by a cathodic vacuum arc is injected into the trap either (i) axially using a compact vacuum arc plasma gun located on axis outside the mirror trap region or (ii) radially using four plasma guns surrounding the trap at midplane. Microwave heating of the mirror-confined, vacuum arc plasma is accomplished by gyrotron microwave radiation of frequency 75 GHz, power up to 200 kW, and pulse duration up to 150 {mu}s, leading to additional stripping of metal ions by electron impact. Pulsed beams of platinum ions with charge state up to 10+, a mean charge state over 6+, and total (all charge states) beam current of a few hundred milliamperes have been formed.

  2. Mass spectrometric immunoassay

    DOE Patents [OSTI]

    Nelson, Randall W; Williams, Peter; Krone, Jennifer Reeve

    2013-07-16

    Rapid mass spectrometric immunoassay methods for detecting and/or quantifying antibody and antigen analytes utilizing affinity capture to isolate the analytes and internal reference species (for quantification) followed by mass spectrometric analysis of the isolated analyte/internal reference species. Quantification is obtained by normalizing and calibrating obtained mass spectrum against the mass spectrum obtained for an antibody/antigen of known concentration.

  3. Mass spectrometric immunoassay

    DOE Patents [OSTI]

    Nelson, Randall W (Phoenix, AZ); Williams, Peter (Phoenix, AZ); Krone, Jennifer Reeve (Granbury, TX)

    2007-12-04

    Rapid mass spectrometric immunoassay methods for detecting and/or quantifying antibody and antigen analytes utilizing affinity capture to isolate the analytes and internal reference species (for quantification) followed by mass spectrometric analysis of the isolated analyte/internal reference species. Quantification is obtained by normalizing and calibrating obtained mass spectrum against the mass spectrum obtained for an antibody/antigen of known concentration.

  4. Mass spectrometric immunoassay

    DOE Patents [OSTI]

    Nelson, Randall W.; Williams, Peter; Krone, Jennifer Reeve

    2005-12-13

    Rapid mass spectrometric immunoassay methods for detecting and/or quantifying antibody and antigen analytes utilizing affinity capture to isolate the analytes and internal reference species (for quantification) followed by mass spectrometric analysis of the isolated analyte/internal reference species. Quantification is obtained by normalizing and calibrating obtained mass spectrum against the mass spectrum obtained for an antibody/antigen of known concentration.

  5. Charge Retention by Peptide Ions Soft-Landed onto Self-Assembled Monolayer Surfaces

    SciTech Connect (OSTI)

    Laskin, Julia; Wang, Peng; Hadjar, Omar; Futrell, Jean H.; Alvarez, Jormarie; Cooks, Robert G.

    2007-08-01

    Soft-landing of singly and doubly protonated peptide ions onto three self-assembled monolayer surfaces (SAMs) was performed using a novel ion deposition instrument constructed in our laboratory and a Fourier transform ion cyclotron resonance mass spectrometer (FT-ICR MS) specially designed for studying collisions of large ions with surfaces.. Modified surfaces were analyzed using in situ 2 keV Cs+ secondary ion mass spectrometry or ex situ 15 keV Ga+ time-of-flight secondary ion mass spectrometry (ToF-SIMS). The results demonstrate that a fraction of multiply protonated peptide ions retain more than one proton following soft-landing on the FSAM surface. [M+2H]2+ ions observed in FT-ICR SIMS spectra are produced by desorption of multiply charged ions from the surface, while re-ionization of singly protonated ions or neutral peptides is a source of [M+2H]2+ ions in Tof-SIMS spectra. Differences in neutralization efficiency of soft-landed ions following exposure of surfaces to laboratory air has a measurable effect on the results of ex situ ToF-SIMS analysis of soft-landed ions on SAM surfaces.

  6. Energy spread and time structure of ion beams extracted from the ReA-EBIT rare isotope charge breeder

    SciTech Connect (OSTI)

    Baumann, Thomas M.; Lapierre, Alain; Schwarz, Stefan; Kittimanapun, Kritsada; Bollen, Georg

    2015-01-09

    The ReA re-accelerator of the National Superconducting Cyclotron Laboratory at Michigan State University utilizes an Electron Beam Ion Trap (EBIT) for charge breeding thermalized rare isotope beams. Recent commissioning measurements have been performed to characterize the performance of this EBIT. The energy spread of extracted highly charged ion beams was measured to be about 0.3% of the total beam energy. From this, the temperature of the ion ensemble in the trap is calculated to be kT{sub q}/q?=?31eV for O{sup 7+}, while it is kT{sub q}/q?=?25eV for K{sup 15+}. In addition initial results are presented for two extraction schemes developed to spread highly charged ion pulses in time.

  7. Intra-catalyst Reductant Chemistry in Lean NOx Traps: A Study...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Intra-catalyst Reductant Chemistry in Lean NOx Traps: A Study on Sulfur Effects Intra-catalyst Reductant Chemistry in Lean NOx Traps: A Study on Sulfur Effects Presentation given ...

  8. Combining Low-Temperature Combustion with Lean-NOx Trap Yields...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Low-Temperature Combustion with Lean-NOx Trap Yields Progress Toward Targets of Efficient ... Intra-catalyst Reductant Chemistry in Lean NOx Traps: A Study on Sulfur Effects Reductant ...

  9. Compact hydrogen/helium isotope mass spectrometer

    DOE Patents [OSTI]

    Funsten, Herbert O. (Los Alamos, NM); McComas, David J. (Los Alamos, NM); Scime, Earl E. (Morgantown, WV)

    1996-01-01

    The compact hydrogen and helium isotope mass spectrometer of the present invention combines low mass-resolution ion mass spectrometry and beam-foil interaction technology to unambiguously detect and quantify deuterium (D), tritium (T), hydrogen molecule (H.sub.2, HD, D.sub.2, HT, DT, and T.sub.2), .sup.3 He, and .sup.4 He concentrations and concentration variations. The spectrometer provides real-time, high sensitivity, and high accuracy measurements. Currently, no fieldable D or molecular speciation detectors exist. Furthermore, the present spectrometer has a significant advantage over traditional T detectors: no confusion of the measurements by other beta-emitters, and complete separation of atomic and molecular species of equivalent atomic mass (e.g., HD and .sup.3 He).

  10. Development of a low energy ion source for ROSINA ion mode calibration

    SciTech Connect (OSTI)

    Rubin, Martin; Altwegg, Kathrin; Jaeckel, Annette; Balsiger, Hans

    2006-10-15

    The European Rosetta mission on its way to comet 67P/Churyumov-Gerasimenko will remain for more than a year in the close vicinity (1 km) of the comet. The two ROSINA mass spectrometers on board Rosetta are designed to analyze the neutral and ionized volatile components of the cometary coma. However, the relative velocity between the comet and the spacecraft will be minimal and also the velocity of the outgassing particles is below 1 km/s. This combination leads to very low ion energies in the surrounding plasma of the comet, typically below 20 eV. Additionally, the spacecraft may charge up to a few volts in this environment. In order to simulate such plasma and to calibrate the mass spectrometers, a source for ions with very low energies had to be developed for the use in the laboratory together with the different gases expected at the comet. In this paper we present the design of this ion source and we discuss the physical parameters of the ion beam like sensitivity, energy distribution, and beam shape. Finally, we show the first ion measurements that have been performed together with one of the two mass spectrometers.

  11. Characterization of compounds by time-of-flight measurement utilizing random fast ions

    DOE Patents [OSTI]

    Conzemius, R.J.

    1989-04-04

    An apparatus is described for characterizing the mass of sample and daughter particles, comprising a source for providing sample ions; a fragmentation region wherein a fraction of the sample ions may fragment to produce daughter ion particles; an electrostatic field region held at a voltage level sufficient to effect ion-neutral separation and ion-ion separation of fragments from the same sample ion and to separate ions of different kinetic energy; a detector system for measuring the relative arrival times of particles; and processing means operatively connected to the detector system to receive and store the relative arrival times and operable to compare the arrival times with times detected at the detector when the electrostatic field region is held at a different voltage level and to thereafter characterize the particles. Sample and daughter particles are characterized with respect to mass and other characteristics by detecting at a particle detector the relative time of arrival for fragments of a sample ion at two different electrostatic voltage levels. The two sets of particle arrival times are used in conjunction with the known altered voltage levels to mathematically characterize the sample and daughter fragments. In an alternative embodiment the present invention may be used as a detector for a conventional mass spectrometer. In this embodiment, conventional mass spectrometry analysis is enhanced due to further mass resolving of the detected ions. 8 figs.

  12. Characterization of compounds by time-of-flight measurement utilizing random fast ions

    DOE Patents [OSTI]

    Conzemius, Robert J.

    1989-01-01

    An apparatus for characterizing the mass of sample and daughter particles, comprising a source for providing sample ions; a fragmentation region wherein a fraction of the sample ions may fragment to produce daughter ion particles; an electrostatic field region held at a voltage level sufficient to effect ion-neutral separation and ion-ion separation of fragments from the same sample ion and to separate ions of different kinetic energy; a detector system for measuring the relative arrival times of particles; and processing means operatively connected to the detector system to receive and store the relative arrival times and operable to compare the arrival times with times detected at the detector when the electrostatic field region is held at a different voltage level and to thereafter characterize the particles. Sample and daughter particles are characterized with respect to mass and other characteristics by detecting at a particle detector the relative time of arrival for fragments of a sample ion at two different electrostatic voltage levels. The two sets of particle arrival times are used in conjunction with the known altered voltage levels to mathematically characterize the sample and daughter fragments. In an alternative embodiment the present invention may be used as a detector for a conventional mass spectrometer. In this embodiment, conventional mass spectrometry analysis is enhanced due to further mass resolving of the detected ions.

  13. Trapping of dust and dust acoustic waves in laboratory plasmas

    SciTech Connect (OSTI)

    Prabhakara, H.R.; Tanna, V.L. [Institute for Plasma Research, Bhat, Gandhinagar 382 424 (India)] [Institute for Plasma Research, Bhat, Gandhinagar 382 424 (India)

    1996-08-01

    Trapping of negatively charged dust particles is observed in a hot cathode plasma discharge when a layer of dust is exposed to the plasma. The particles are visible in the scattered He{endash}Ne laser light. The trajectories of individual particles have been photographed. The dust particles are excluded from the sheath region of any object in the plasma. The intensity of scattered light as well as the potential on a floating Langmuir probe show coherent fluctuations in the frequency range 1{endash}15 Hz. After several hours of exposure to the plasma, the dust layer develops striations similar to those on sand dunes. Trapping of dust particles by the plasma and the possible identification of the observed low-frequency fluctuations with dust acoustic waves are discussed. {copyright} {ital 1996 American Institute of Physics.}

  14. Real-time calibration of a feedback trap

    SciTech Connect (OSTI)

    Gavrilov, Momčilo; Jun, Yonggun; Bechhoefer, John

    2014-09-15

    Feedback traps use closed-loop control to trap or manipulate small particles and molecules in solution. They have been applied to the measurement of physical and chemical properties of particles and to explore fundamental questions in the non-equilibrium statistical mechanics of small systems. These applications have been hampered by drifts in the electric forces used to manipulate the particles. Although the drifts are small for measurements on the order of seconds, they dominate on time scales of minutes or slower. Here, we show that a recursive maximum likelihood (RML) algorithm can allow real-time measurement and control of electric and stochastic forces over time scales of hours. Simulations show that the RML algorithm recovers known parameters accurately. Experimental estimates of diffusion coefficients are also consistent with expected physical properties.

  15. Bose gas in a single-beam optical dipole trap

    SciTech Connect (OSTI)

    Simon, Lena; Strunz, Walter T.

    2010-06-15

    We study an ultracold Bose gas in an optical dipole trap consisting of one single focused laser beam. An analytical expression for the corresponding density of states beyond the usual harmonic approximation is obtained. We are thus able to discuss the existence of a critical temperature for Bose-Einstein condensation and find that the phase transition must be enabled by a cutoff near the threshold. Moreover, we study the dynamics of evaporative cooling and observe significant deviations from the findings for the well-established harmonic approximation. Furthermore, we investigate Bose-Einstein condensates in such a trap in Thomas-Fermi approximation and determine analytical expressions for chemical potential, internal energy, and Thomas-Fermi radii beyond the usual harmonic approximation.

  16. Ionization source utilizing a jet disturber in combination with an ion funnel and method of operation

    DOE Patents [OSTI]

    Smith, Richard D. (Richland, WA); Kim, Taeman (Richland, WA); Tang, Keqi (Richland, WA); Udseth, Harold R. (Richland, WA)

    2003-06-24

    A jet disturber used in combination with an ion funnel to focus ions and other charged particles generated at or near atmospheric pressure into a relatively low pressure region, which allows increased conductance of the ions and other charged particles. The jet disturber is positioned within an ion funnel and may be interfaced with a multi-capillary inlet juxtaposed between an ion source and the interior of an instrument maintained at near atmospheric pressure. The invention finds particular advantages when deployed to improve the ion transmission between an electrospray ionization source and the first vacuum stage of a mass spectrometer.

  17. Steven Chu: Laser Cooling and Trapping of Atoms

    Office of Scientific and Technical Information (OSTI)

    Steven Chu Laser Cooling and Trapping of Atoms Resources with Additional Information * Interviews, Speeches, and Presentations * Patents Steven Chu Photo Credit: Lawrence Berkeley National Laboratory Roy Kaltschmidt, Photographer Steven Chu was appointed by President Barack Obama to be the 12th Secretary of Energy and served in this capacity until April 22, 2013. He was previously Director of Lawrence Berkeley National Laboratory (LBNL), Professor in the Physics Department at the University of

  18. Qualitative analysis of trapped Dirac fermions in graphene

    SciTech Connect (OSTI)

    Jakubsk, Vt Krej?i?k, David

    2014-10-15

    We study the confinement of Dirac fermions in graphene and in carbon nanotubes by an external magnetic field, mechanical deformations or inhomogeneities in the substrate. By applying variational principles to the square of the Dirac operator, we obtain sufficient and necessary conditions for confinement of the quasi-particles. The rigorous theoretical results are illustrated on the realistic examples of the three classes of traps.

  19. Real-Time Particulate Mass Measurements Pre and Post Diesel Particulate

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Filters for LIght-Duty Diesel Vehicles | Department of Energy Particulate Mass Measurements Pre and Post Diesel Particulate Filters for LIght-Duty Diesel Vehicles Real-Time Particulate Mass Measurements Pre and Post Diesel Particulate Filters for LIght-Duty Diesel Vehicles PDF icon 2005_deer_anderson.pdf More Documents & Publications Advanced Radio Frequency-Based Sensors for Monitoring Diesel Particulate Filter Loading and Regeneration Real-Time Measurement of Diesel Trap Efficiency

  20. Observation of cold Rb{sub 2} molecules trapped in an optical dipole trap using a laser-pulse-train technique

    SciTech Connect (OSTI)

    Menegatti, Carlos R.; Marangoni, Bruno S.; Marcassa, Luis G.

    2011-11-15

    In this work, we have developed and characterized a laser-pulse-train technique to observe cold Rb{sub 2} molecules trapped in an optical dipole trap. The molecules are produced in a magneto-optical trap, and then loaded into a crossed optical dipole trap. The time evolution of the molecular population is obtained by applying a laser pulse train, which photoionizes the ground-state molecules through intermediate molecular bands. Our results show that this technique allows us to obtain a faster data acquisition rate of the time evolution of the molecule population than other techniques.

  1. WATER TRAPPING ON TIDALLY LOCKED TERRESTRIAL PLANETS REQUIRES SPECIAL CONDITIONS

    SciTech Connect (OSTI)

    Yang, Jun; Abbot, Dorian S.; Liu, Yonggang; Hu, Yongyun

    2014-12-01

    Surface liquid water is essential for standard planetary habitability. Calculations of atmospheric circulation on tidally locked planets around M stars suggest that this peculiar orbital configuration lends itself to the trapping of large amounts of water in kilometers-thick ice on the night side, potentially removing all liquid water from the day side where photosynthesis is possible. We study this problem using a global climate model including coupled atmosphere, ocean, land, and sea ice components as well as a continental ice sheet model driven by the climate model output. For a waterworld, we find that surface winds transport sea ice toward the day side and the ocean carries heat toward the night side. As a result, nightside sea ice remains O(10m) thick and nightside water trapping is insignificant. If a planet has large continents on its night side, they can grow ice sheets O(1000m) thick if the geothermal heat flux is similar to Earth's or smaller. Planets with a water complement similar to Earth's would therefore experience a large decrease in sea level when plate tectonics drives their continents onto the night side, but would not experience complete dayside dessiccation. Only planets with a geothermal heat flux lower than Earth's, much of their surface covered by continents, and a surface water reservoir O(10%) of Earth's would be susceptible to complete water trapping.

  2. Single microbe trap and release in sub-microfluidics

    SciTech Connect (OSTI)

    Vasdekis, Andreas E.

    2013-05-08

    Lab-on-a-chip systems have substantially impacted the way life-sciences are explored; life on earth, however, comprises mostly of microbes, which due to their sub-micron dimensions and high mobility are more challenging to dynamically manipulate on-a-chip. To address this challenge, we developed a high resolution microfluidic system (submicrofluidics) fabricated by direct electron beam lithography that is capable of trapping single microbes and releasing them upon demand. The fabrication method enabled the integration of sub-micron indentations (400 nm) with millimetre-scale fluidic channels rapidly in a single processing step. The larger channels deliver the cell suspension and reagents, while the sub-micron indentations immobilize the cells by locally increasing the hydrodynamic resistance. By volume exclusion, single cell trapping was possible in this system without any surface treatment. By increasing the flow rate, the microbes overcome the trap barrier and pass through the narrow indentation without undergoing lysis with kinetics that depend on their size. The fabrication method and its performance are described, along with microbial characterisations using E. coli.

  3. Charge exchange molecular ion source

    DOE Patents [OSTI]

    Vella, Michael C.

    2003-06-03

    Ions, particularly molecular ions with multiple dopant nucleons per ion, are produced by charge exchange. An ion source contains a minimum of two regions separated by a physical barrier and utilizes charge exchange to enhance production of a desired ion species. The essential elements are a plasma chamber for production of ions of a first species, a physical separator, and a charge transfer chamber where ions of the first species from the plasma chamber undergo charge exchange or transfer with the reactant atom or molecules to produce ions of a second species. Molecular ions may be produced which are useful for ion implantation.

  4. Multicomponent liquid ion exchange with chabazite zeolites

    SciTech Connect (OSTI)

    Robinson, S.M.; Arnold, W.D. Jr.; Byers, C.W.

    1993-10-01

    In spite of the increasing commercial use of zeolites for binary and multicomponent sorption, the understanding of the basic mass-transfer processes associated with multicomponent zeolite ion-exchange systems is quite limited. This study was undertaken to evaluate Na-Ca-Mg-Cs-Sr ion exchange from an aqueous solution using a chabazite zeolite. Mass-transfer coefficients and equilibrium equations were determined from experimental batch-reactor data for single and multicomponent systems. The Langmuir isotherm was used to represent the equilibrium relationship for binary systems, and a modified Dubinin-Polyani model was used for the multicomponent systems. The experimental data indicate that diffusion through the microporous zeolite crystals is the primary diffusional resistance. Macropore diffusion also significantly contributes to the mass-transfer resistance. Various mass-transfer models were compared to the experimental data to determine mass-transfer coefficients. Effective diffusivities were obtained which accurately predicted experimental data using a variety of models. Only the model which accounts for micropore and macropore diffusion occurring in series accurately predicted multicomponent data using single-component diffusivities. Liquid and surface diffusion both contribute to macropore diffusion. Surface and micropore diffusivities were determined to be concentration dependent.

  5. Ion photon emission microscope

    DOE Patents [OSTI]

    Doyle, Barney L. (Albuquerque, NM)

    2003-04-22

    An ion beam analysis system that creates microscopic multidimensional image maps of the effects of high energy ions from an unfocussed source upon a sample by correlating the exact entry point of an ion into a sample by projection imaging of the ion-induced photons emitted at that point with a signal from a detector that measures the interaction of that ion within the sample. The emitted photons are collected in the lens system of a conventional optical microscope, and projected on the image plane of a high resolution single photon position sensitive detector. Position signals from this photon detector are then correlated in time with electrical effects, including the malfunction of digital circuits, detected within the sample that were caused by the individual ion that created these photons initially.

  6. Collection of ions

    DOE Patents [OSTI]

    Orr, Christopher Henry (Calderbridge, GB); Luff, Craig Janson (Calderbridge, GB); Dockray, Thomas (Calderbridge, GB); Macarthur, Duncan Whittemore (Los Alamos, NM); Bounds, John Alan (Los Alamos, NM); Koster, James E. (Los Alamos, NM)

    2001-01-01

    The apparatus and method provide an improved technique for detecting ions as the area from which ions are attracted to a detector is increased, consequently increasing the number of ions detected. This is achieved by providing the outer electrodes of the detector connected to the electrical potential, together with alternate intermediate electrodes. The other intermediate electrodes and preferably the housing are grounded. The technique renders such detection techniques more sensitive and gives them a lower threshold at which they can function.

  7. Ion beam generating apparatus

    DOE Patents [OSTI]

    Brown, I.G.; Galvin, J.

    1987-12-22

    An ion generating apparatus utilizing a vacuum chamber, a cathode and an anode in the chamber. A source of electrical power produces an arc or discharge between the cathode and anode. The arc is sufficient to vaporize a portion of the cathode to form a plasma. The plasma is directed to an extractor which separates the electrons from the plasma, and accelerates the ions to produce an ion beam. 10 figs.

  8. Ion beam generating apparatus

    DOE Patents [OSTI]

    Brown, Ian G. (1088 Woodside Rd., Berkeley, CA 94708); Galvin, James (2 Commodore #276, Emeryville, CA 94608)

    1987-01-01

    An ion generating apparatus utilizing a vacuum chamber, a cathode and an anode in the chamber. A source of electrical power produces an arc or discharge between the cathode and anode. The arc is sufficient to vaporize a portion of the cathode to form a plasma. The plasma is directed to an extractor which separates the electrons from the plasma, and accelerates the ions to produce an ion beam.

  9. Cesium trapping characteristics on fly ash filter according to different carrier gases

    SciTech Connect (OSTI)

    Shin, Jin-Myeong; Park, Jang-Jin; Song, Kee-Chan

    2007-07-01

    Fly ash, which is a kind of waste from a coal fired power plant, has been used as a trapping material because it contains silica and alumina suitable for forming pollucite (CsAlSi{sub 2}O{sub 6}). Fly ash is sintered in order to fabricate it into a self-standing filter. The effect of a carrier gas on a cesium trapping quantity is investigated to analyze the cesium trapping characteristics by the fly ash filter in a lab-scale experimental apparatus. The chemical form of the cesium trapped on the filter after trapping cesium is identified to be a pollucite phase regardless of the type of carrier gas. The trapping efficiency of cesium by the fly ash filter under the air and NO{sub x}/air conditions is up to 99.0 %. However, the trapping efficiency of the cesium under the SO{sub x} condition was decreased to 80.0 %. (authors)

  10. BERNAS ION SOURCE DISCHARGE SIMULATION

    SciTech Connect (OSTI)

    RUDSKOY,I.; KULEVOY, T.V.; PETRENKO, S.V.; KUIBEDA, R.P.; SELEZNEV, D.N.; PERSHIN, V.I.; HERSHCOVITCH, A.; JOHNSON, B.M.; GUSHENETS, V.I.; OKS, E.M.; POOLE, H.J.

    2007-08-26

    The joint research and development program is continued to develop steady-state ion source of decaborane beam for ion implantation industry. Bemas ion source is the wide used ion source for ion implantation industry. The new simulation code was developed for the Bemas ion source discharge simulation. We present first results of the simulation for several materials interested in semiconductors. As well the comparison of results obtained with experimental data obtained at the ITEP ion source test-bench is presented.

  11. Correlation ion mobility spectroscopy

    DOE Patents [OSTI]

    Pfeifer, Kent B. (Los Lunas, NM); Rohde, Steven B. (Corrales, NM)

    2008-08-26

    Correlation ion mobility spectrometry (CIMS) uses gating modulation and correlation signal processing to improve IMS instrument performance. Closely spaced ion peaks can be resolved by adding discriminating codes to the gate and matched filtering for the received ion current signal, thereby improving sensitivity and resolution of an ion mobility spectrometer. CIMS can be used to improve the signal-to-noise ratio even for transient chemical samples. CIMS is especially advantageous for small geometry IMS drift tubes that can otherwise have poor resolution due to their small size.

  12. Elbow mass flow meter

    DOE Patents [OSTI]

    McFarland, Andrew R. (College Station, TX); Rodgers, John C. (Santa Fe, NM); Ortiz, Carlos A. (Bryan, TX); Nelson, David C. (Santa Fe, NM)

    1994-01-01

    Elbow mass flow meter. The present invention includes a combination of an elbow pressure drop generator and a shunt-type mass flow sensor for providing an output which gives the mass flow rate of a gas that is nearly independent of the density of the gas. For air, the output is also approximately independent of humidity.

  13. Simulation and optimization of a 10 A electron gun with electrostatic compression for the electron beam ion source

    SciTech Connect (OSTI)

    Pikin, A.; Beebe, E. N.; Raparia, D.

    2013-03-15

    Increasing the current density of the electron beam in the ion trap of the Electron Beam Ion Source (EBIS) in BNL's Relativistic Heavy Ion Collider facility would confer several essential benefits. They include increasing the ions' charge states, and therefore, the ions' energy out of the Booster for NASA applications, reducing the influx of residual ions in the ion trap, lowering the average power load on the electron collector, and possibly also reducing the emittance of the extracted ion beam. Here, we discuss our findings from a computer simulation of an electron gun with electrostatic compression for electron current up to 10 A that can deliver a high-current-density electron beam for EBIS. The magnetic field in the cathode-anode gap is formed with a magnetic shield surrounding the gun electrodes and the residual magnetic field on the cathode is (5 Division-Sign 6) Gs. It was demonstrated that for optimized gun geometry within the electron beam current range of (0.5 Division-Sign 10) A the amplitude of radial beam oscillations can be maintained close to 4% of the beam radius by adjusting the injection magnetic field generated by a separate magnetic coil. Simulating the performance of the gun by varying geometrical parameters indicated that the original gun model is close to optimum and the requirements to the precision of positioning the gun elements can be easily met with conventional technology.

  14. The Mission and Technology of a Gas Dynamic Trap Neutron Source for Fusion Material and Component Testing and Qualification

    SciTech Connect (OSTI)

    Ivanov, A; Kulcinski, J; Molvik, A; Ryutov, D; Santarius, J; Simonen, T; Wirth, B D; Ying, A

    2009-11-23

    The successful operation (with {beta} {le} 60%, classical ions and electrons with Te = 250 eV) of the Gas Dynamic Trap (GDT) device at the Budker Institute of Nuclear Physics (BINP) in Novosibirsk, Russia, extrapolates to a 2 MW/m{sup 2} Dynamic Trap Neutron Source (DTNS), which burns only {approx}100 g of tritium per full power year. The DTNS has no serious physics, engineering, or technology obstacles; the extension of neutral beam lines to steady state can use demonstrated engineering; and it supports near-term tokamaks and volume neutron sources. The DTNS provides a neutron spectrum similar to that of ITER and satisfies the missions specified by the materials community to test fusion materials (listed as one of the top grand challenges for engineering in the 21st century by the U.S. National Academy of Engineering) and subcomponents (including tritium-breeding blankets) needed to construct DEMO. The DTNS could serve as the first Fusion Nuclear Science Facility (FNSF), called for by ReNeW, and could provide the data necessary for licensing subsequent FSNFs.

  15. Influence of local capillary trapping on containment system effectiveness

    SciTech Connect (OSTI)

    Bryant, Steven

    2014-03-31

    Immobilization of CO2 injected into deep subsurface storage reservoirs is a critical component of risk assessment for geologic CO2 storage (GCS). Local capillary trapping (LCT) is a recently established mode of immobilization that arises when CO2 migrates due to buoyancy through heterogeneous storage reservoirs. This project sought to assess the amount and extent of LCT expected in storage formations under a range of injection conditions, and to confirm the persistence of LCT if the seal overlying the reservoir were to lose its integrity. Numerical simulation using commercial reservoir simulation software was conducted to assess the influence of injection. Laboratory experiments, modeling and numerical simulation were conducted to assess the effect of compromised seal integrity. Bench-scale (0.6 m by 0.6 m by 0.03 m) experiments with surrogate fluids provided the first empirical confirmation of the key concepts underlying LCT: accumulation of buoyant nonwetting phase at above residual saturations beneath capillary barriers in a variety of structures, which remains immobile under normal capillary pressure gradients. Immobilization of above-residual saturations is a critical distinction between LCT and the more familiar residual saturation trapping. To estimate the possible extent of LCT in a storage reservoir an algorithm was developed to identify all potential local traps, given the spatial distribution of capillary entry pressure in the reservoir. The algorithm assumes that the driving force for CO2 migration can be represented as a single value of critical capillary entry pressure Pc,entrycrit, such that cells with capillary entry pressure greater/less than Pc,entrycrit act as barriers/potential traps during CO2 migration. At intermediate values of Pc,entrycrit, the barrier regions become more laterally extensive in the reservoir, approaching a percolation threshold while non-barrier regions remain numerous. The maximum possible extent of LCT thus occurs at Pc,entrycrit near this threshold. Testing predictions of this simple algorithm against full-physics simulations of buoyancy-driven CO2 migration support the concept of critical capillary entry pressure. However, further research is needed to determine whether a single value of critical capillary entry pressure always applies and how that value can be determined a priori. Simulations of injection into high-resolution (cells 0.3 m on a side) 2D and 3D heterogeneous domains show two characteristic behaviors. At small gravity numbers (vertical flow velocity much less than horizontal flow velocity) the CO2 fills local traps as well as regions that would act as local barriers if CO2 were moving only due to buoyancy. When injection ceases, the CO2 migrates vertically to establish large saturations within local traps and residual saturation elsewhere. At large gravity numbers, the CO2 invades a smaller portion of the perforated interval. Within this smaller swept zone the local barriers are not invaded, but local traps are filled to large saturation during injection and remain during post-injection gravity-driven migration. The small gravity number behavior is expected in the region within 100 m of a vertical injection well at anticipated rates of injection for commercial GCS. Simulations of leakage scenarios (through-going region of large permeability imposed in overlying seal) indicate that LCT persists (i.e. CO2 remains held in a large fraction of the local iv traps) and the persistence is independent of injection rate during storage. Simulations of leakage for the limiting case of CO2 migrating vertically from an areally extensive emplacement in the lower portion of a reservoir showed similar strong persistence of LCT. This research has two broad implications for GCS. The first is that LCT can retain a significant fraction of the CO2 stored in a reservoir above and beyond the residual saturation -- if the overlying seal were to fail. Thus frameworks for risk assessment should be extended to account for LCT. The second implication is that compared to pressure driven flow in reservoirs, CO2 migration and trapping behave in a qualitatively different manner in heterogeneous reservoirs when buoyancy is the dominant driving force for flow. Thus simulations of GCS that neglect capillary heterogeneity will fail to capture important features of the CO2 plume. While commercial reservoir simulation software can account for fine scale capillary heterogeneity, it has not been designed to work efficiently with such domains, and no simulators can handle fine-scale resolution throughout the reservoir. A possible way to upscale the migration and trapping is to apply an effective residual saturation to coarse-scale grids. While the extent of overall immobilization can be correlated in this way, all coarser grids failed to capture the distance traveled by the migrating CO2 for large gravity number. Thus it remains unclear how best to account for LCT in the routine simulation work-flow that will be needed for large-scale GCS. Alternatives meriting investigation include streamline methods, reduced-physics proxies (e.g. particle tracking), and biased invasion percolation algorithms, which are based on precisely the capillary heterogeneity essential for LCT.

  16. Portable gas chromatograph-mass spectrometer

    DOE Patents [OSTI]

    Andresen, B.D.; Eckels, J.D.; Kimmons, J.F.; Myers, D.W.

    1996-06-11

    A gas chromatograph-mass spectrometer (GC-MS) is described for use as a field portable organic chemical analysis instrument. The GC-MS is designed to be contained in a standard size suitcase, weighs less than 70 pounds, and requires less than 600 watts of electrical power at peak power (all systems on). The GC-MS includes: a conduction heated, forced air cooled small bore capillary gas chromatograph, a small injector assembly, a self-contained ion/sorption pump vacuum system, a hydrogen supply, a dual computer system used to control the hardware and acquire spectrum data, and operational software used to control the pumping system and the gas chromatograph. This instrument incorporates a modified commercial quadrupole mass spectrometer to achieve the instrument sensitivity and mass resolution characteristic of laboratory bench top units. 4 figs.

  17. Portable gas chromatograph-mass spectrometer

    DOE Patents [OSTI]

    Andresen, Brian D. (Livermore, CA); Eckels, Joel D. (Livermore, CA); Kimmons, James F. (Manteca, CA); Myers, David W. (Livermore, CA)

    1996-01-01

    A gas chromatograph-mass spectrometer (GC-MS) for use as a field portable organic chemical analysis instrument. The GC-MS is designed to be contained in a standard size suitcase, weighs less than 70 pounds, and requires less than 600 watts of electrical power at peak power (all systems on). The GC-MS includes: a conduction heated, forced air cooled small bore capillary gas chromatograph, a small injector assembly, a self-contained ion/sorption pump vacuum system, a hydrogen supply, a dual computer system used to control the hardware and acquire spectrum data, and operational software used to control the pumping system and the gas chromatograph. This instrument incorporates a modified commercial quadrupole mass spectrometer to achieve the instrument sensitivity and mass resolution characteristic of laboratory bench top units.

  18. Plume collimation for laser ablation electrospray ionization mass spectrometry

    DOE Patents [OSTI]

    Vertes, Akos; Stolee, Jessica A.

    2014-09-09

    In various embodiments, a device may generally comprise a capillary having a first end and a second end; a laser to emit energy at a sample in the capillary to ablate the sample and generate an ablation plume in the capillary; an electrospray apparatus to generate an electrospray plume to intercept the ablation plume to produce ions; and a mass spectrometer having an ion transfer inlet to capture the ions. The ablation plume may comprise a collimated ablation plume. The device may comprise a flow cytometer. Methods of making and using the same are also described.

  19. Selective ion source

    DOE Patents [OSTI]

    Leung, K.N.

    1996-05-14

    A ion source is described wherein selected ions maybe extracted to the exclusion of unwanted ion species of higher ionization potential. Also described is a method of producing selected ions from a compound, such as P{sup +} from PH{sub 3}. The invention comprises a plasma chamber, an electron source, a means for introducing a gas to be ionized by electrons from the electron source, means for limiting electron energy from the electron source to a value between the ionization energy of the selected ion species and the greater ionization energy of an unwanted ion specie, and means for extracting the target ion specie from the plasma chamber. In one embodiment, the electrons are generated in a plasma cathode chamber immediately adjacent to the plasma chamber. A small extractor draws the electrons from the plasma cathode chamber into the relatively positive plasma chamber. The energy of the electrons extracted in this manner is easily controlled. The invention is particularly useful for doping silicon with P{sup +}, As{sup +}, and B{sup +} without the problematic presence of hydrogen, helium, water, or carbon oxide ions. Doped silicon is important for manufacture of semiconductors and semiconductor devices. 6 figs.

  20. Selective ion source

    DOE Patents [OSTI]

    Leung, Ka-Ngo (Hercules, CA)

    1996-01-01

    A ion source is described wherein selected ions maybe extracted to the exclusion of unwanted ion species of higher ionization potential. Also described is a method of producing selected ions from a compound, such as P.sup.+ from PH.sub.3. The invention comprises a plasma chamber, an electron source, a means for introducing a gas to be ionized by electrons from the electron source, means for limiting electron energy from the electron source to a value between the ionization energy of the selected ion species and the greater ionization energy of an unwanted ion specie, and means for extracting the target ion specie from the plasma chamber. In one embodiment, the electrons are generated in a plasma cathode chamber immediately adjacent to the plasma chamber. A small extractor draws the electrons from the plasma cathode chamber into the relatively positive plasma chamber. The energy of the electrons extracted in this manner is easily controlled. The invention is particularly useful for doping silicon with P.sup.+, AS.sup.+, and B.sup.+ without the problematic presence of hydrogen, helium, water, or carbon oxide ions. Doped silicon is important for manufacture of semiconductors and semiconductor devices.

  1. Development of ion sources for ion projection lithography

    SciTech Connect (OSTI)

    Lee, Y.; Gough, R.A.; Kunkel, W.B.; Leung, K.N.; Perkins, L.T.

    1996-05-01

    Multicusp ion sources are capable of generating ion beams with low axial energy spread as required by the Ion Projection Lithography (IPL). Longitudinal ion energy spread has been studied in two different types of plasma discharge: the filament discharge ion source characterized by its low axial energy spread, and the RF-driven ion source characterized by its long source lifetime. For He{sup +} ions, longitudinal ion energy spreads of 1-2 eV were measured for a filament discharge multicusp ion source which is within the IPL device requirements. Ion beams with larger axial energy spread were observed in the RF-driven source. A double-chamber ion source has been designed which combines the advantages of low axial energy spread of the filament discharge ion source with the long lifetime of the RF-driven source. The energy spread of the double chamber source is lower than that of the RF-driven source.

  2. Ion mobility sensor system

    DOE Patents [OSTI]

    Xu, Jun; Watson, David B.; Whitten, William B.

    2013-01-22

    An ion mobility sensor system including an ion mobility spectrometer and a differential mobility spectrometer coupled to the ion mobility spectrometer. The ion mobility spectrometer has a first chamber having first end and a second end extending along a first direction, and a first electrode system that generates a constant electric field parallel to the first direction. The differential mobility spectrometer includes a second chamber having a third end and a fourth end configured such that a fluid may flow in a second direction from the third end to the fourth end, and a second electrode system that generates an asymmetric electric field within an interior of the second chamber. Additionally, the ion mobility spectrometer and the differential mobility spectrometer form an interface region. Also, the first end and the third end are positioned facing one another so that the constant electric field enters the third end and overlaps the fluid flowing in the second direction.

  3. Charge Transfer Fluorescence and 34 nm Exciton Diffusion Length in Polymers with Electron Acceptor End Traps

    SciTech Connect (OSTI)

    Zaikowski, L.; Mauro, G.; Bird, M.; Karten, B.; Asaoka, S.; Wu, Q.; Cook, A. R.; Miller, J.

    2014-12-22

    Photoexcitation of conjugated poly-2,7-(9,9-dihexylfluorene) polyfluorenes with naphthylimide (NI) and anthraquinone (AQ) electron-acceptor end traps produces excitons that form charge transfer states at the end traps. Intramolecular singlet exciton transport to end traps was examined by steady state fluorescence for polyfluorenes of 17 to 127 repeat units in chloroform, dimethylformamide (DMF), tetrahydrofuran (THF), and p-xylene. End traps capture excitons and form charge transfer (CT) states at all polymer lengths and in all solvents. The CT nature of the end-trapped states is confirmed by their fluorescence spectra, solvent and trap group dependence and DFT descriptions. Quantum yields of CT fluorescence are as large as 46%. This strong CT emission is understood in terms of intensity borrowing. Energies of the CT states from onsets of the fluorescence spectra give the depths of the traps which vary with solvent polarity. For NI end traps the trap depths are 0.06 (p-xylene), 0.13 (THF) and 0.19 eV (CHCl3). For AQ, CT fluorescence could be observed only in p-xylene where the trap depth is 0.27 eV. Quantum yields, emission energies, charge transfer energies, solvent reorganization and vibrational energies were calculated. Fluorescence measurements on chains >100 repeat units indicate that end traps capture ~50% of the excitons, and that the exciton diffusion length LD =34 nm, which is much larger than diffusion lengths reported in polymer films or than previously known for diffusion along isolated chains. The efficiency of exciton capture depends on chain length, but not on trap depth, solvent polarity or which trap group is present.

  4. Charge transfer fluorescence and 34 nm exciton diffusion length in polymers with electron acceptor end traps

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zaikowski, Lori; Mauro, Gina; Bird, Matthew; Karten, Brianne; Asaoka, Sadayuki; Wu, Qin; Cook, Andrew R.; Miller, John R.

    2014-12-22

    Photoexcitation of conjugated poly-2,7-(9,9-dihexylfluorene) polyfluorenes with naphthylimide (NI) and anthraquinone (AQ) electron-acceptor end traps produces excitons that form charge transfer states at the end traps. Intramolecular singlet exciton transport to end traps was examined by steady state fluorescence for polyfluorenes of 17 to 127 repeat units in chloroform, dimethylformamide (DMF), tetrahydrofuran (THF), and p-xylene. End traps capture excitons and form charge transfer (CT) states at all polymer lengths and in all solvents. The CT nature of the end-trapped states is confirmed by their fluorescence spectra, solvent and trap group dependence and DFT descriptions. Quantum yields of CT fluorescence are asmore » large as 46%. This strong CT emission is understood in terms of intensity borrowing. Energies of the CT states from onsets of the fluorescence spectra give the depths of the traps which vary with solvent polarity. For NI end traps the trap depths are 0.06 (p-xylene), 0.13 (THF) and 0.19 eV (CHCl3). For AQ, CT fluorescence could be observed only in p-xylene where the trap depth is 0.27 eV. Quantum yields, emission energies, charge transfer energies, solvent reorganization and vibrational energies were calculated. Fluorescence measurements on chains >100 repeat units indicate that end traps capture ~50% of the excitons, and that the exciton diffusion length LD =34 nm, which is much larger than diffusion lengths reported in polymer films or than previously known for diffusion along isolated chains. As a result, the efficiency of exciton capture depends on chain length, but not on trap depth, solvent polarity or which trap group is present.« less

  5. Photovoltaic cell with light trapping for enhanced efficiency

    DOE Patents [OSTI]

    Brener, Igal; Fofang, Nche Tumasang; Luk, Ting S.

    2015-11-19

    The efficiency of a photovoltaic cell is enhanced by light trapping using Mie-scattering nanostructures. In one embodiment, an array of nanocylinders is formed on the front surface of a silicon film to enhance forward scattering into the film, and an array of nanocylinders is formed on the back surface to enhance backscattering so that more light is absorbed within the silicon film. In an alternate embodiment, a mirror layer is formed on the back surface of the silicon film to reflect light within the film back toward the front-surface nanocylinder array.

  6. DOE - NNSA/NFO -- News & Views Accident Trap

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Accident Traps Four Workers 1,800 Feet below Ground Photo - rescue from 1,800 feet below Over the past 42 years the Nevada Test Site has earned an excellent safety record. Thousands of workers have completed millions of accident-free hours at this heavy industry site. Since 1957 (no accurate records exist for 1951-56) there have been 46 fatalities on the Test Site, and six fatalities at other Test-Site-related locations. Being safety conscious and prepared minimizes the impact of the occasional

  7. The isobaric multiplet mass equation for A?71 revisited

    SciTech Connect (OSTI)

    Lam, Yi Hua; Blank, Bertram; Smirnova, Nadezda A.; Bueb, Jean Bernard; Antony, Maria Susai

    2013-11-15

    Accurate mass determination of short-lived nuclides by Penning-trap spectrometers and progress in the spectroscopy of proton-rich nuclei have triggered renewed interest in the isobaric multiplet mass equation (IMME). The energy levels of the members of T=1/2,1,3/2, and 2 multiplets and the coefficients of the IMME are tabulated for A?71. The new compilation is based on the most recent mass evaluation (AME2011) and it includes the experimental results on energies of the states evaluated up to end of 2011. Taking into account the error bars, a significant deviation from the quadratic form of the IMME for the A=9,35 quartets and the A=32 quintet is observed.

  8. Method of multiplexed analysis using ion mobility spectrometer

    DOE Patents [OSTI]

    Belov, Mikhail E. (Richland, WA); Smith, Richard D. (Richland, WA)

    2009-06-02

    A method for analyzing analytes from a sample introduced into a Spectrometer by generating a pseudo random sequence of a modulation bins, organizing each modulation bin as a series of submodulation bins, thereby forming an extended pseudo random sequence of submodulation bins, releasing the analytes in a series of analyte packets into a Spectrometer, thereby generating an unknown original ion signal vector, detecting the analytes at a detector, and characterizing the sample using the plurality of analyte signal subvectors. The method is advantageously applied to an Ion Mobility Spectrometer, and an Ion Mobility Spectrometer interfaced with a Time of Flight Mass Spectrometer.

  9. Ion optics of RHIC electron beam ion source

    SciTech Connect (OSTI)

    Pikin, A.; Alessi, J.; Beebe, E.; Kponou, A.; Okamura, M.; Raparia, D.; Ritter, J.; Tan, Y.; Kuznetsov, G.

    2012-02-15

    RHIC electron beam ion source has been commissioned to operate as a versatile ion source on RHIC injection facility supplying ion species from He to Au for Booster. Except for light gaseous elements RHIC EBIS employs ion injection from several external primary ion sources. With electrostatic optics fast switching from one ion species to another can be done on a pulse to pulse mode. The design of an ion optical structure and the results of simulations for different ion species are presented. In the choice of optical elements special attention was paid to spherical aberrations for high-current space charge dominated ion beams. The combination of a gridded lens and a magnet lens in LEBT provides flexibility of optical control for a wide range of ion species to satisfy acceptance parameters of RFQ. The results of ion transmission measurements are presented.

  10. Trapping ultracold gases near cryogenic materials with rapid reconfigurability

    SciTech Connect (OSTI)

    Naides, Matthew A.; Turner, Richard W.; Lai, Ruby A.; DiSciacca, Jack M.; Lev, Benjamin L.

    2013-12-16

    We demonstrate an atom chip trapping system that allows the placement and high-resolution imaging of ultracold atoms within microns from any ?100??m-thin, UHV-compatible material, while also allowing sample exchange with minimal experimental downtime. The sample is not connected to the atom chip, allowing rapid exchange without perturbing the atom chip or laser cooling apparatus. Exchange of the sample and retrapping of atoms has been performed within a week turnaround, limited only by chamber baking. Moreover, the decoupling of sample and atom chip provides the ability to independently tune the sample temperature and its position with respect to the trapped ultracold gas, which itself may remain in the focus of a high-resolution imaging system. As a first demonstration of this system, we have confined a 700-nK cloud of 8??10{sup 4} {sup 87}Rb atoms within 100??m of a gold-mirrored 100-?m-thick silicon substrate. The substrate was cooled to 35?K without use of a heat shield, while the atom chip, 120??m away, remained at room temperature. Atoms may be imaged and retrapped every 16?s, allowing rapid data collection.

  11. Have the best available trap on the job, check design, installation, and maintenance

    SciTech Connect (OSTI)

    Spires, F.; Toy, D.A.

    1986-12-01

    Industrial and commercial installations can have much more efficient steam systems with properly designed, installed, and maintained steam traps. Thirty years ago, steam trap maintenance did not have near the significance it does today; fuel costs have risen from about $0.30 per 1000 lb of steam to over 25 times that a few years ago to about 15 times that cost today. Worn or otherwise malfunctioning steam traps can take quite a toll on the energy bill, especially since most traps are designed to fail in the open position. Failure of just one steam trap with a 1/2'' diameter orifice in the open position can cost $45,090 a year. This article gives guidelines for the prevention of steam trap failures.

  12. Elemental and isotopic analysis of inorganic salts by laser desorption ionization mass spectrometry

    SciTech Connect (OSTI)

    Jayasekharan, T.; Sahoo, N. K.

    2013-02-05

    Laser desorption ionization mass spectrometry is applied for the analysis of elements as well as their isotopic composition in different inorganic salts. At very low laser energies the inorganic ions are desorbed and ionized from the thin layer of the sample surface. The naturally occurring isotopes of alkali and silver ions are resolved using time of flight mass spectrometer. Further increase in laser energy shows the appearance of Al, Cr, and Fe ions in the mass spectra. This indicates the penetration laser beam beyond the sample surface leading to the ablation of sample target at higher energies. The simultaneous appearance of atomic ions from the sample target at relatively higher laser energies hampers the unambiguous identification of amino acid residues from the biomolecular ions in MALDI-MS.

  13. Relating to ion detection

    DOE Patents [OSTI]

    Orr, Christopher Henry (Calderbridge, GB); Luff, Craig Janson (Calderbridge, GB); Dockray, Thomas (Calderbridge, GB); Macarthur, Duncan Whittemore (Los Alamos, NM)

    2001-01-01

    The apparatus and method provide a technique for improving detection of alpha and/or beta emitting sources on items or in locations using indirect means. The emission forms generate ions in a medium surrounding the item or location and the medium is then moved to a detecting location where the ions are discharged to give a measure of the emission levels. To increase the level of ions generated and render the system particularly applicable for narrow pipes and other forms of conduits, the medium pressure is increased above atmospheric pressure. STATEMENT REGARDING FEDERALLY SPONSORED RESEARCH OR DEVELOPMENT

  14. Investigation of Aging Mechanisms in Lean NOx Traps | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Aging Mechanisms in Lean NOx Traps Investigation of Aging Mechanisms in Lean NOx Traps 2009 DOE Hydrogen Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting, May 18-22, 2009 -- Washington D.C. PDF icon ace_26_crocker.pdf More Documents & Publications Pt-free, Perovskite-based Lean NOx Trap Catalysts CLEERS Coordination & Development of Catalyst Process Kinetic Data Lean NOx Reduction with Dual Layer LNT/SCR Catalysts

  15. Lean NOx Traps - Microstructural Studies of Real World and Model Catalysts

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    | Department of Energy Traps - Microstructural Studies of Real World and Model Catalysts Lean NOx Traps - Microstructural Studies of Real World and Model Catalysts 2005 Diesel Engine Emissions Reduction (DEER) Conference Presentations and Posters PDF icon 2005_deer_narula.pdf More Documents & Publications Low Temperature Emission Control Pre-Competitive Catalysis Research: Fundamental Sulfation/Desulfation Studies of Lean NOx Traps Investigation of Aging Mechanisms in Lean

  16. Particle trapping: A key requisite of structure formation and stability of

    Office of Scientific and Technical Information (OSTI)

    Vlasov-Poisson plasmas (Journal Article) | SciTech Connect Particle trapping: A key requisite of structure formation and stability of Vlasov-Poisson plasmas Citation Details In-Document Search Title: Particle trapping: A key requisite of structure formation and stability of Vlasov-Poisson plasmas Particle trapping is shown to control the existence of undamped coherent structures in Vlasov-Poisson plasmas and thereby affects the onset of plasma instability beyond the realm of linear Landau

  17. Using impedance measurements for detecting pathogens trapped in an electric field

    DOE Patents [OSTI]

    Miles, Robin R.

    2004-07-20

    Impedance measurements between the electrodes in an electric field is utilized to detect the presence of pathogens trapped in the electric field. Since particles trapped in a field using the dielectiphoretic force changes the impedance between the electrodes by changing the dielectric material between the electrodes, the degree of particle trapping can be determined by measuring the impedance. This measurement is used to determine if sufficient pathogen have been collected to analyze further or potentially to identify the pathogen.

  18. Polarization-dependent atomic dipole traps behind a circular aperture for neutral-atom quantum computing

    SciTech Connect (OSTI)

    Gillen-Christandl, Katharina; Copsey, Bert D.

    2011-02-15

    The neutral-atom quantum computing community has successfully implemented almost all necessary steps for constructing a neutral-atom quantum computer. We present computational results of a study aimed at solving the remaining problem of creating a quantum memory with individually addressable sites for quantum computing. The basis of this quantum memory is the diffraction pattern formed by laser light incident on a circular aperture. Very close to the aperture, the diffraction pattern has localized bright and dark spots that can serve as red-detuned or blue-detuned atomic dipole traps. These traps are suitable for quantum computing even for moderate laser powers. In particular, for moderate laser intensities ({approx}100 W/cm{sup 2}) and comparatively small detunings ({approx}1000-10 000 linewidths), trap depths of {approx}1 mK and trap frequencies of several to tens of kilohertz are achieved. Our results indicate that these dipole traps can be moved by tilting the incident laser beams without significantly changing the trap properties. We also explored the polarization dependence of these dipole traps. We developed a code that calculates the trapping potential energy for any magnetic substate of any hyperfine ground state of any alkali-metal atom for any laser detuning much smaller than the fine-structure splitting for any given electric field distribution. We describe details of our calculations and include a summary of different notations and conventions for the reduced matrix element and how to convert it to SI units. We applied this code to these traps and found a method for bringing two traps together and apart controllably without expelling the atoms from the trap and without significant tunneling probability between the traps. This approach can be scaled up to a two-dimensional array of many pinholes, forming a quantum memory with single-site addressability, in which pairs of atoms can be brought together and apart for two-qubit gates for quantum computing.

  19. GreenPower Trap Water-Muffler System | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    GreenPower Trap Water-Muffler System GreenPower Trap Water-Muffler System This hydrated EGR system reduces NOx and enhances fuel efficiency, and the DPF is catalyzed by the fuel-borne catalyst generated by the oil-borne catalyst system PDF icon deer09_rim.pdf More Documents & Publications DPF -"Hydrated EGR" Fuel Saver System GreenPowerTM Trap-Muffler

  20. Mass spectrometer with electron source for reducing space charge effects in sample beam

    DOE Patents [OSTI]

    Houk, Robert S.; Praphairaksit, Narong

    2003-10-14

    A mass spectrometer includes an ion source which generates a beam including positive ions, a sampling interface which extracts a portion of the beam from the ion source to form a sample beam that travels along a path and has an excess of positive ions over at least part of the path, thereby causing space charge effects to occur in the sample beam due to the excess of positive ions in the sample beam, an electron source which adds electrons to the sample beam to reduce space charge repulsion between the positive ions in the sample beam, thereby reducing the space charge effects in the sample beam and producing a sample beam having reduced space charge effects, and a mass analyzer which analyzes the sample beam having reduced space charge effects.

  1. Atom Trap Trace Analysis at ANL | U.S. DOE Office of Science...

    Office of Science (SC) Website

    Atom Trap Trace Analysis at ANL Nuclear Physics (NP) NP Home About Research Facilities Science Highlights Benefits of NP Applications of Nuclear Science Applications of Nuclear ...

  2. Pre-Designed Single-Molecule Traps for CO2 Capture | Center for Gas

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    SeparationsRelevant to Clean Energy Technologies | Blandine Jerome Pre-Designed Single-Molecule Traps for CO2 Capture

  3. Lean NOx Trap Formulation Effect on Performance with In-Cylinder...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Formulation Effect on Performance with In-Cylinder Regeneration Strategies Lean NOx Trap Formulation Effect on Performance with In-Cylinder Regeneration Strategies Poster ...

  4. Synergies of High-Efficiency Clean Combustion and Lean NOx Trap...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Trap Catalysts investigation of potential synergies of low emission advanced combustion techniques and advanced lean exhaust catalytic aftertreatment. PDF icon deer08parks.pdf...

  5. Charge trapping and de-trapping in isolated CdSe/ZnS nanocrystals under an external electric field: Indirect evidence for a permanent dipole moment

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Zang, Huidong; Cristea, Mihail; Shen, Xuan; Liu, Mingzhao; Camino, Fernando; Cotlet, Mircea

    2015-08-05

    Single nanoparticle studies of charge trapping and de-trapping in core/shell CdSe/ZnS nanocrystals incorporated into an insulating matrix and subjected to an external electric field demonstrate the ability to reversibly modulate the exciton dynamics and photoluminescence blinking while providing indirect evidence for the existence of a permanent ground state dipole moment in such nanocrystals. A model assuming the presence of energetically deep charge traps physically aligned along the direction of the permanent dipole is proposed in order to explain the dynamics of nanocrystal blinking in the presence of a permanent dipole moment.

  6. Ion sensing method

    DOE Patents [OSTI]

    Smith, Richard Harding; Martin, Glenn Brian

    2004-05-18

    The present invention allows the determination of trace levels of ionic substances in a sample solution (ions, metal ions, and other electrically charged molecules) by coupling a separation method, such as liquid chromatography, with ion selective electrodes (ISE) prepared so as to allow detection at activities below 10.sup.-6 M. The separation method distributes constituent molecules into fractions due to unique chemical and physical properties, such as charge, hydrophobicity, specific binding interactions, or movement in an electrical field. The separated fractions are detected by means of the ISE(s). These ISEs can be used singly or in an array. Accordingly, modifications in the ISEs are used to permit detection of low activities, specifically, below 10.sup.-6 M, by using low activities of the primary analyte (the molecular species which is specifically detected) in the inner filling solution of the ISE. Arrays constructed in various ways allow flow-through sensing for multiple ions.

  7. Focused ion beam system

    DOE Patents [OSTI]

    Leung, Ka-Ngo (Hercules, CA); Gough, Richard A. (Kensington, CA); Ji, Qing (Berkeley, CA); Lee, Yung-Hee Yvette (Berkeley, CA)

    1999-01-01

    A focused ion beam (FIB) system produces a final beam spot size down to 0.1 .mu.m or less and an ion beam output current on the order of microamps. The FIB system increases ion source brightness by properly configuring the first (plasma) and second (extraction) electrodes. The first electrode is configured to have a high aperture diameter to electrode thickness aspect ratio. Additional accelerator and focusing electrodes are used to produce the final beam. As few as five electrodes can be used, providing a very compact FIB system with a length down to only 20 mm. Multibeamlet arrangements with a single ion source can be produced to increase throughput. The FIB system can be used for nanolithography and doping applications for fabrication of semiconductor devices with minimum feature sizes of 0.1 .mu.m or less.

  8. Focused ion beam system

    DOE Patents [OSTI]

    Leung, K.; Gough, R.A.; Ji, Q.; Lee, Y.Y.

    1999-08-31

    A focused ion beam (FIB) system produces a final beam spot size down to 0.1 {mu}m or less and an ion beam output current on the order of microamps. The FIB system increases ion source brightness by properly configuring the first (plasma) and second (extraction) electrodes. The first electrode is configured to have a high aperture diameter to electrode thickness aspect ratio. Additional accelerator and focusing electrodes are used to produce the final beam. As few as five electrodes can be used, providing a very compact FIB system with a length down to only 20 mm. Multibeamlet arrangements with a single ion source can be produced to increase throughput. The FIB system can be used for nanolithography and doping applications for fabrication of semiconductor devices with minimum feature sizes of 0.1 m or less. 13 figs.

  9. The Origins of Mass

    ScienceCinema (OSTI)

    Lincoln, Don

    2014-08-07

    The Higgs boson was discovered in July of 2012 and is generally understood to be the origin of mass. While those statements are true, they are incomplete. It turns out that the Higgs boson is responsible for only about 2% of the mass of ordinary matter. In this dramatic new video, Dr. Don Lincoln of Fermilab tells us the rest of the story.

  10. The Origins of Mass

    SciTech Connect (OSTI)

    Lincoln, Don

    2014-07-30

    The Higgs boson was discovered in July of 2012 and is generally understood to be the origin of mass. While those statements are true, they are incomplete. It turns out that the Higgs boson is responsible for only about 2% of the mass of ordinary matter. In this dramatic new video, Dr. Don Lincoln of Fermilab tells us the rest of the story.

  11. Elbow mass flow meter

    DOE Patents [OSTI]

    McFarland, A.R.; Rodgers, J.C.; Ortiz, C.A.; Nelson, D.C.

    1994-08-16

    The present invention includes a combination of an elbow pressure drop generator and a shunt-type mass flow sensor for providing an output which gives the mass flow rate of a gas that is nearly independent of the density of the gas. For air, the output is also approximately independent of humidity. 3 figs.

  12. Sandia Energy - Photoionization Mass Spectroscopy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Photoionization Mass Spectroscopy Home Transportation Energy Predictive Simulation of Engines Diagnostics Gas-Phase Diagnostics Photoionization Mass Spectroscopy Photoionization...

  13. Development of high-spatial and high-mass resolution mass spectrometric imaging (MSI) and its application to the study of small metabolites and endogenous molecules of plants

    SciTech Connect (OSTI)

    Jun, Ji Hyun

    2011-11-30

    High-spatial and high-mass resolution laser desorption ionization (LDI) mass spectrometric (MS) imaging technology was developed for the attainment of MS images of higher quality containing more information on the relevant cellular and molecular biology in unprecedented depth. The distribution of plant metabolites is asymmetric throughout the cells and tissues, and therefore the increase in the spatial resolution was pursued to reveal the localization of plant metabolites at the cellular level by MS imaging. For achieving high-spatial resolution, the laser beam size was reduced by utilizing an optical fiber with small core diameter (25 ?m) in a vacuum matrix-assisted laser desorption ionization-linear ion trap (vMALDI-LTQ) mass spectrometer. Matrix application was greatly improved using oscillating capillary nebulizer. As a result, single cell level spatial resolution of ~ 12 ?m was achieved. MS imaging at this high spatial resolution was directly applied to a whole Arabidopsis flower and the substructures of an anther and single pollen grains at the stigma and anther were successfully visualized. MS imaging of high spatial resolution was also demonstrated to the secondary roots of Arabidopsis thaliana and a high degree of localization of detected metabolites was successfully unveiled. This was the first MS imaging on the root for molecular species. MS imaging with high mass resolution was also achieved by utilizing the LTQ-Orbitrap mass spectrometer for the direct identification of the surface metabolites on the Arabidopsis stem and root and differentiation of isobaric ions having the same nominal mass with no need of tandem mass spectrometry (MS/MS). MS imaging at high-spatial and high-mass resolution was also applied to cer1 mutant of the model system Arabidopsis thaliana to demonstrate its usefulness in biological studies and reveal associated metabolite changes in terms of spatial distribution and/or abundances compared to those of wild-type. The spatial distribution of targeted metabolites, mainly waxes and flavonoids, was systematically explored on various organs, including flowers, leaves, stems, and roots at high spatial resolution of ~ 12-50 ?m and the changes in the abundance level of these metabolites were monitored on the cer1 mutant with respect to the wild-type. This study revealed the metabolic biology of CER1 gene on each individual organ level with very detailed high spatial resolution. The separate MS images of isobaric metabolites, i.e. C29 alkane vs. C28 aldehyde could be constructed on both genotypes from MS imaging at high mass resolution. This allows tracking of abundance changes for those compounds along with the genetic mutation, which is not achievable with low mass resolution mass spectrometry. This study supported previous hypothesis of molecular function of CER1 gene as aldehyde decarbonylase, especially by displaying hyper accumulation of aldehydes and C30 fatty acid and decrease in abundance of alkanes and ketones in several plant organs of cer1 mutant. The scope of analytes was further directed toward internal cell metabolites from the surface metabolites of the plant. MS profiling and imaging of internal cell metabolites were performed on the vibratome section of Arabidopsis leaf. Vibratome sectioning of the leaf was first conducted to remove the surface cuticle layer and it was followed by enzymatic treatment of the section to induce the digestion of primary cell walls, middle lamella, and expose the internal cells underneath to the surface for detection with the laser by LDI-MS. The subsequent MS imaging onto the enzymatically treated vibratome section allowed us to map the distribution of the metabolites in the internal cell layers, linolenic acid (C18:3 FA) and linoleic acid (C18:2 FA). The development of an assay for relative quantification of analytes at the single subcellular/organelle level by LDI-MS imaging was attempted and both plausibility and significant obstacles were seen. As a test system, native plant organelle, chloroplasts isolated from the spinach leaves were used

  14. Ion electric propulsion unit

    DOE Patents [OSTI]

    Light, Max E; Colestock, Patrick L

    2014-01-28

    An electron cyclotron resonance (ECR) thruster is disclosed having a plasma chamber which is electrically biased with a positive voltage. The chamber bias serves to efficiently accelerate and expel the positive ions from the chamber. Electrons follow the exiting ions, serving to provide an electrically neutral exhaust plume. In a further embodiment, a downstream shaping magnetic field serves to further accelerate and/or shape the exhaust plume.

  15. High current ion source

    DOE Patents [OSTI]

    Brown, Ian G. (1088 Woodside Rd., Berkeley, CA 94708); MacGill, Robert A. (645 Kern St., Richmond, CA 94805); Galvin, James E. (2 Commodore Dr. #276, Emeryville, CA 94608)

    1990-01-01

    An ion source utilizing a cathode and anode for producing an electric arc therebetween. The arc is sufficient to vaporize a portion of the cathode to form a plasma. The plasma leaves the generation region and expands through another regon. The density profile of the plasma may be flattened using a magnetic field formed within a vacuum chamber. Ions are extracted from the plasma to produce a high current broad on beam.

  16. Mass and charge overlaps in beamline implantation into compound semiconductor materials

    SciTech Connect (OSTI)

    Current, M. I.; Eddy, R.; Hudak, C.; Serfass, J.; Mount, G.

    2012-11-06

    Mass overlaps occurring as a result of extraction of ions from an arc discharge and gas collisions, producing molecular break up and charge exchange in the accelerator beamline, are examined for ion implantation into compound semiconductors. The effects of the choice of plasma gas elements for Be{sup +} implants are examined as an example.

  17. EA-1690: A123 Systems, Inc., Automotive-Class Lithium-Ion Battery...

    Broader source: Energy.gov (indexed) [DOE]

    to A123 Systems, Inc., for Vertically Integrated Mass Production of Automotive-Class Lithium-Ion Batteries April 20, 2010 EA-1690: Finding of No Significant Impact A123 Systems,...

  18. In the OSTI Collections: Lithium-ion Batteries | OSTI, US Dept...

    Office of Scientific and Technical Information (OSTI)

    Lithium-ion batteries have high energy per unit of volume and mass, and other chemical reactions that compete with their current-generating reactions are minimal, so they don't ...

  19. Design and operational characteristics of a cast steel mass spectrometer

    SciTech Connect (OSTI)

    Blantocas, Gene Q.; Ramos, Henry J.; Wada, Motoi

    2004-09-01

    A cast steel magnetic sector mass analyzer is developed for studies of hydrogen and helium ion beams generated by a gas discharge compact ion source. The optimum induced magnetic flux density of 3500 G made it possible to scan the whole spectrum of hydrogen and helium ion species. Analysis of beam characteristics shows that the mass spectrometer sensitivity, and resolving power are approximately inversely proportional. The resolution is enhanced at higher pressures and lower current discharges. In contrast, the instrument sensitivity increased at higher current discharges and decreased at higher pressures. Calculations of the ultimate resolving power with reference to analyzer dimensions yield a numerical value of 30. System anomaly in the form of spherical aberrations was also analyzed using the paraxial beam envelope equation. Beam divergence is most significant at high discharge conditions where angular spread reaches an upper limit of 8.6 deg.

  20. Method and apparatus for multispray emitter for mass spectrometry

    DOE Patents [OSTI]

    Smith, Richard D.; Tang, Keqi; Lin, Yuehe

    2004-12-14

    A method and apparatus that utilizes two or more emitters simultaneously to form an electrospray of a sample that is then directed into a mass spectrometer, thereby increasing the total ion current introduced into an electrospray ionization mass spectrometer, given a liquid flow rate of a sample. The method and apparatus are most conveniently constructed as an array of spray emitters fabricated on a single chip, however, the present invention encompasses any apparatus wherein two or more emitters are simultaneously utilized to form an electrospray of a sample that is then directed into a mass spectrometer.

  1. Lean Gasoline Engine Reductant Chemistry During Lean NOx Trap Regeneration

    SciTech Connect (OSTI)

    Choi, Jae-Soon; Prikhodko, Vitaly Y; Partridge Jr, William P; Parks, II, James E; Norman, Kevin M; Huff, Shean P; Chambon, Paul H; Thomas, John F

    2010-01-01

    Lean NOx Trap (LNT) catalysts can effectively reduce NOx from lean engine exhaust. Significant research for LNTs in diesel engine applications has been performed and has led to commercialization of the technology. For lean gasoline engine applications, advanced direct injection engines have led to a renewed interest in the potential for lean gasoline vehicles and, thereby, a renewed demand for lean NOx control. To understand the gasoline-based reductant chemistry during regeneration, a BMW lean gasoline vehicle has been studied on a chassis dynamometer. Exhaust samples were collected and analyzed for key reductant species such as H2, CO, NH3, and hydrocarbons during transient drive cycles. The relation of the reductant species to LNT performance will be discussed. Furthermore, the challenges of NOx storage in the lean gasoline application are reviewed.

  2. Trapping and aerogelation of nanoparticles in negative gravity hydrocarbon flames

    SciTech Connect (OSTI)

    Chakrabarty, Rajan K.; Novosselov, Igor V.; Beres, Nicholas D.; Moosmller, Hans; Sorensen, Christopher M.; Stipe, Christopher B.

    2014-06-16

    We report the experimental realization of continuous carbon aerogel production using a flame aerosol reactor by operating it in negative gravity (?g; up-side-down configuration). Buoyancy opposes the fuel and air flow forces in ?g, which eliminates convectional outflow of nanoparticles from the flame and traps them in a distinctive non-tipping, flicker-free, cylindrical flame body, where they grow to millimeter-size aerogel particles and gravitationally fall out. Computational fluid dynamics simulations show that a closed-loop recirculation zone is set up in ?g flames, which reduces the time to gel for nanoparticles by ?10{sup 6}?s, compared to positive gravity (upward rising) flames. Our results open up new possibilities of one-step gas-phase synthesis of a wide variety of aerogels on an industrial scale.

  3. Lean NOx Trap Catalysis for Lean Natural Gas Engine Applications

    SciTech Connect (OSTI)

    Parks, II, James E; Storey, John Morse; Theiss, Timothy J; Ponnusamy, Senthil; Ferguson, Harley Douglas; Williams, Aaron M; Tassitano, James B

    2007-09-01

    Distributed energy is an approach for meeting energy needs that has several advantages. Distributed energy improves energy security during natural disasters or terrorist actions, improves transmission grid reliability by reducing grid load, and enhances power quality through voltage support and reactive power. In addition, distributed energy can be efficient since transmission losses are minimized. One prime mover for distributed energy is the natural gas reciprocating engine generator set. Natural gas reciprocating engines are flexible and scalable solutions for many distributed energy needs. The engines can be run continuously or occasionally as peak demand requires, and their operation and maintenance is straightforward. Furthermore, system efficiencies can be maximized when natural gas reciprocating engines are combined with thermal energy recovery for cooling, heating, and power applications. Expansion of natural gas reciprocating engines for distributed energy is dependent on several factors, but two prominent factors are efficiency and emissions. Efficiencies must be high enough to enable low operating costs, and emissions must be low enough to permit significant operation hours, especially in non-attainment areas where emissions are stringently regulated. To address these issues the U.S. Department of Energy and the California Energy Commission launched research and development programs called Advanced Reciprocating Engine Systems (ARES) and Advanced Reciprocating Internal Combustion Engines (ARICE), respectively. Fuel efficiency and low emissions are two primary goals of these programs. The work presented here was funded by the ARES program and, thus, addresses the ARES 2010 goals of 50% thermal efficiency (fuel efficiency) and <0.1 g/bhp-hr emissions of oxides of nitrogen (NOx). A summary of the goals for the ARES program is given in Table 1-1. ARICE 2007 goals are 45% thermal efficiency and <0.015 g/bhp-hr NOx. Several approaches for improving the efficiency and emissions of natural gas reciprocating engines are being pursued. Approaches include: stoichiometric engine operation with exhaust gas recirculation and three-way catalysis, advanced combustion modes such as homogeneous charge compression ignition, and extension of the lean combustion limit with advanced ignition concepts and/or hydrogen mixing. The research presented here addresses the technical approach of combining efficient lean spark-ignited natural gas combustion with low emissions obtained from a lean NOx trap catalyst aftertreatment system. This approach can be applied to current lean engine technology or advanced lean engines that may result from related efforts in lean limit extension. Furthermore, the lean NOx trap technology has synergy with hydrogen-assisted lean limit extension since hydrogen is produced from natural gas during the lean NOx trap catalyst system process. The approach is also applicable to other lean engines such as diesel engines, natural gas turbines, and lean gasoline engines; other research activities have focused on those applications. Some commercialization of the technology has occurred for automotive applications (both diesel and lean gasoline engine vehicles) and natural gas turbines for stationary power. The research here specifically addresses barriers to commercialization of the technology for large lean natural gas reciprocating engines for stationary power. The report presented here is a comprehensive collection of research conducted by Oak Ridge National Laboratory (ORNL) on lean NOx trap catalysis for lean natural gas reciprocating engines. The research was performed in the Department of Energy's ARES program from 2003 to 2007 and covers several aspects of the technology. All studies were conducted at ORNL on a Cummins C8.3G+ natural gas engine chosen based on industry input to simulate large lean natural gas engines. Specific technical areas addressed by the research include: NOx reduction efficiency, partial oxidation and reforming chemistry, and the effects of sulfur poisons on the partial oxidation

  4. Gas turbine engine combustor can with trapped vortex cavity

    DOE Patents [OSTI]

    Burrus, David Louis; Joshi, Narendra Digamber; Haynes, Joel Meier; Feitelberg, Alan S.

    2005-10-04

    A gas turbine engine combustor can downstream of a pre-mixer has a pre-mixer flowpath therein and circumferentially spaced apart swirling vanes disposed across the pre-mixer flowpath. A primary fuel injector is positioned for injecting fuel into the pre-mixer flowpath. A combustion chamber surrounded by an annular combustor liner disposed in supply flow communication with the pre-mixer. An annular trapped dual vortex cavity located at an upstream end of the combustor liner is defined between an annular aft wall, an annular forward wall, and a circular radially outer wall formed therebetween. A cavity opening at a radially inner end of the cavity is spaced apart from the radially outer wall. Air injection first holes are disposed through the forward wall and air injection second holes are disposed through the aft wall. Fuel injection holes are disposed through at least one of the forward and aft walls.

  5. Inertial confinement fusion based on the ion-bubble trigger

    SciTech Connect (OSTI)

    Jafari, S. Nilkar, M.; Ghasemizad, A.; Mehdian, H.

    2014-10-15

    Triggering the ion-bubble in an inertial confinement fusion, we have developed a novel scheme for the fast ignition. This scheme relies on the plasma cavitation by the wake of an intense laser pulse to generate an ion-bubble. The bubble acts both as an intense electron accelerator and as an electron wiggler. Consequently, the accelerated electrons trapped in the bubble can emit an intense tunable laser light. This light can be absorbed by an ablation layer on the outside surface of the ignition capsule, which subsequently drills it and thereby produces a guide channel in the pellet. Finally, the relativistic electron beam created in the bubble is guided through the channel to the high density core igniting the fusion fuel. The normalized beam intensity and beam energy required for triggering the ignition have been calculated when core is heated by the e-beam. In addition, through solving the momentum transfer, continuity and wave equations, a dispersion relation for the electromagnetic and space-charge waves has been analytically derived. The variations of growth rate with the ion-bubble density and electron beam energy have been illustrated. It is found that the growth rates of instability are significantly controlled by the ions concentration and the e-beam energy in the bubble.

  6. Ion optics of RHIC EBIS

    SciTech Connect (OSTI)

    Pikin, A.; Alessi, J.; Beebe, E.; Kponou, A.; Okamura, M.; Raparia, D.; Ritter, J.; Tan, Y.; Kuznetsov, G.

    2011-09-10

    RHIC EBIS has been commissioned to operate as a versatile ion source on RHIC injection facility supplying ion species from He to Au for Booster. Except for light gaseous elements RHIC EBIS employs ion injection from several external primary ion sources. With electrostatic optics fast switching from one ion species to another can be done on a pulse to pulse mode. The design of an ion optical structure and the results of simulations for different ion species are presented. In the choice of optical elements special attention was paid to spherical aberrations for high-current space charge dominated ion beams. The combination of a gridded lens and a magnet lens in LEBT provides flexibility of optical control for a wide range of ion species to satisfy acceptance parameters of RFQ. The results of ion transmission measurements are presented.

  7. Sampling probe for microarray read out using electrospray mass spectrometry

    DOE Patents [OSTI]

    Van Berkel, Gary J.

    2004-10-12

    An automated electrospray based sampling system and method for analysis obtains samples from surface array spots having analytes. The system includes at least one probe, the probe including an inlet for flowing at least one eluting solvent to respective ones of a plurality of spots and an outlet for directing the analyte away from the spots. An automatic positioning system is provided for translating the probe relative to the spots to permit sampling of any spot. An electrospray ion source having an input fluidicly connected to the probe receives the analyte and generates ions from the analyte. The ion source provides the generated ions to a structure for analysis to identify the analyte, preferably being a mass spectrometer. The probe can be a surface contact probe, where the probe forms an enclosing seal along the periphery of the array spot surface.

  8. Impact of Sulfur Dioxide on Lean NOx Trap Catalysts | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Sulfur Dioxide on Lean NOx Trap Catalysts Impact of Sulfur Dioxide on Lean NOx Trap Catalysts 2004 Diesel Engine Emissions Reduction (DEER) Conference Presentation: University of New Mexico PDF icon 2004_deer_hammache.pdf More Documents & Publications CLEERS Aftertreatment Modeling and Analysis CLEERS Aftertreatment Modeling and Analysis An Improvement of Diesel PM and NOx Reduction System

  9. Characterization of a state-insensitive dipole trap for cesium atoms

    SciTech Connect (OSTI)

    Phoonthong, P.; Douglas, P.; Wickenbrock, A.; Renzoni, F.

    2010-07-15

    In this work we characterize a state-insensitive dipole trap for cold cesium atoms, as realized by tightly focusing a single running laser beam at the magic wavelength. The use of trapping light at the magic wavelength of 935.6 nm resulted in the same ac Stark shift for the {sup 6}S{sub 1/2} ground state and the {sup 6}P{sub 3/2} excited state. A complete characterization of the trap is given, which includes the dependence of the lifetime on the trap depth, an analysis of the important role played by a depumper beam, and a comparison with dipole trapping at different (nonmagic) wavelengths. In particular, we measured the differential light shift of the relevant optical transition as a function of the trapping light wavelength, and showed that it becomes zero at the magic wavelength. Our results are compared to previous realizations of state-insensitive dipole traps for cesium atoms. We also discuss the possible role of the state-insensitive trap, its limitations, and possible developments for the study of ground-state quantum coherence phenomena and related applications.

  10. Development of Chemical Kinetic Models for Lean NOx Traps | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy 1 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation PDF icon ace035_larson_2011_o.pdf More Documents & Publications Development of Chemical Kinetic Models for Lean NOx Traps Benchmark Reaction Mechanisms and Kinetics for Lean NOx Traps CLEERS Coordination & Development of Catalyst Process Kinetic Data

  11. IonCCD for direct position-sensitive charged-particle detection: from electrons and keV ions to hyperthermal biomolecular ions

    SciTech Connect (OSTI)

    Hadjar, Omar; Johnson, Grant E.; Laskin, Julia; Kibelka, Gottfried; Shill, Scott M.; Kuhn, Ken; Cameron, Chad; Kassan, Scott

    2011-04-01

    A novel charged-particle sensitive, pixel based detector array is described and its usage is demonstrated for a variety of applications, from detection of elemental particles (electrons) to hyper-thermal large biomolecular positive and negative ions including keV light atomic and molecular ions. The array detector is a modified light-sensitive charged coupled device (CCD). The IonCCDTM was engineered for direct charged particle detection by replacing the semi-conductor part of the CCD pixel by a conductor1. In contrast with the CCD, where the semi-conductive pixel is responsible for electron-hole pair formation upon photon bombardment, the IonCCD uses a capacitor coupled to the conductive electrode for direct charge integration. The detector can be operated from atmospheric pressure to high vacuum since no high voltages are needed. The IonCCD, presented in this work is an array of 2126 active pixels with 21 um pixel width and 3 um pixel gap. The detection area is 1.5x51mm2 where 1.5 mm and 51 mm are pixel and detector array length, respectively. The result is a one-dimensional position-sensitive detector with 24 um spatial resolution and 88 % pixel area ratio (PAR). In this work we demonstrate the capabilities and the performance of the detector. For the first time we show the direct detection of 250 eV electrons providing linearity response and detection efficiency of the IonCCD as function of electron beam current. Using positive ions from and electron impact source (E-I), we demonstrate that the detection efficiency of the IonCCD is virtually independent of particle energy [250 eV, 1250 eV], particle impact angle [45o, 90o] and particle flux. By combining the IonCCD with a double focusing sector field of Mattauch-Herzog geometry (M-H), we demonstrate fast acquisition of mass spectra in direct air sniffing mode. A first step towards fast in vivo breath analysis is presented. Detection of hyper-thermal biomolecular ions produced using an electrospray ionization source (ESI) is presented. The IonCCD was used as beam profiler to characterize the beam shape and intensity of 15 eV protonated and deprotonated biomolecular ions at the exit of an RF only collisional quadrupole. We present simultaneous detection of 140 eV doubly protonated biomolecular ions when the IonCCD is combined with the M-H analyzer. The latter, demonstrates the possibility of simultaneous separation and micro-array deposition of biological material using a miniature sector field.

  12. Solids mass flow determination

    DOE Patents [OSTI]

    Macko, Joseph E. (Hempfield Township, Westmoreland County, PA)

    1981-01-01

    Method and apparatus for determining the mass flow rate of solids mixed with a transport fluid to form a flowing mixture. A temperature differential is established between the solids and fluid. The temperature of the transport fluid prior to mixing, the temperature of the solids prior to mixing, and the equilibrium temperature of the mixture are monitored and correlated in a heat balance with the heat capacities of the solids and fluid to determine the solids mass flow rate.

  13. Apparatus for preparing a sample for mass spectrometry

    DOE Patents [OSTI]

    Villa-Aleman, Eliel (Aiken, SC)

    1994-01-01

    An apparatus for preparing a sample for analysis by a mass spectrometer system. The apparatus has an entry chamber and an ionization chamber separated by a skimmer. A capacitor having two space-apart electrodes followed by one or more ion-imaging lenses is disposed in the ionization chamber. The chamber is evacuated and the capacitor is charged. A valve injects a sample gas in the form of sample pulses into the entry chamber. The pulse is collimated by the skimmer and enters the ionization chamber. When the sample pulse passes through the gap between the electrodes, it discharges the capacitor and is thereby ionized. The ions are focused by the imaging lenses and enter the mass analyzer, where their mass and charge are analyzed.

  14. Apparatus for preparing a sample for mass spectrometry

    DOE Patents [OSTI]

    Villa-Aleman, E.

    1994-05-10

    An apparatus is described for preparing a sample for analysis by a mass spectrometer system. The apparatus has an entry chamber and an ionization chamber separated by a skimmer. A capacitor having two space-apart electrodes followed by one or more ion-imaging lenses is disposed in the ionization chamber. The chamber is evacuated and the capacitor is charged. A valve injects a sample gas in the form of sample pulses into the entry chamber. The pulse is collimated by the skimmer and enters the ionization chamber. When the sample pulse passes through the gap between the electrodes, it discharges the capacitor and is thereby ionized. The ions are focused by the imaging lenses and enter the mass analyzer, where their mass and charge are analyzed. 1 figures.

  15. Hybrid particle traps and conditioning procedure for gas insulated transmission lines

    DOE Patents [OSTI]

    Dale, Steinar J. (Monroeville, PA); Cookson, Alan H. (Churchill, PA)

    1982-01-01

    A gas insulated transmission line includes an outer sheath, an inner condor within the outer sheath, insulating supports supporting the inner conductor within the outer sheath, and an insulating gas electrically insulating the inner conductor from the outer sheath. An apertured particle trapping ring is disposed within the outer sheath, and the trapping ring has a pair of dielectric members secured at each longitudinal end thereof, with the dielectric members extending outwardly from the trapping ring along an arc. A support sheet having an adhesive coating thereon is secured to the trapping ring and disposed on the outer sheath within the low field region formed between the trapping ring and the outer sheath. A conditioning method used to condition the transmission line prior to activation in service comprises applying an AC voltage to the inner conductor in a plurality of voltage-time steps, with the voltage-time steps increasing in voltage magnitude while decreasing in time duration.

  16. Hydride vapor phase GaN films with reduced density of residual electrons and deep traps

    SciTech Connect (OSTI)

    Polyakov, A. Y.; Smirnov, N. B.; Govorkov, A. V.; Yugova, T. G.; Cox, H.; Helava, H.; Makarov, Yu.; Usikov, A. S.

    2014-05-14

    Electrical properties and deep electron and hole traps spectra are compared for undoped n-GaN films grown by hydride vapor phase epitaxy (HVPE) in the regular process (standard HVPE samples) and in HVPE process optimized for decreasing the concentration of residual donor impurities (improved HVPE samples). It is shown that the residual donor density can be reduced by optimization from ?10{sup 17}?cm{sup ?3} to (25)??10{sup 14}?cm{sup ?3}. The density of deep hole traps and deep electron traps decreases with decreased donor density, so that the concentration of deep hole traps in the improved samples is reduced to ?5??10{sup 13}?cm{sup ?3} versus 2.9??10{sup 16}?cm{sup ?3} in the standard samples, with a similar decrease in the electron traps concentration.

  17. Simultaneous magneto-optical trapping of bosonic and fermionic chromium atoms

    SciTech Connect (OSTI)

    Chicireanu, R.; Pouderous, A.; Barbe, R.; Laburthe-Tolra, B.; Marechal, E.; Vernac, L.; Keller, J.-C.; Gorceix, O.

    2006-05-15

    We report on magneto-optical trapping of fermionic {sup 53}Cr atoms. A Zeeman-slowed atomic beam provides loading rates up to 3x10{sup 6} s{sup -1}. We present systematic characterization of the magneto-optical trap (MOT). We obtain up to 5x10{sup 5} atoms in the steady-state MOT. The atoms radiatively decay from the excited P state into metastable D states, and, due to the large dipolar magnetic moment of chromium atoms in these states, they can remain magnetically trapped in the quadrupole field gradient of the MOT. We study the accumulation of metastable {sup 53}Cr atoms in this magnetic trap. We also report on the simultaneous magneto-optical trapping of bosonic {sup 52}Cr and fermionic {sup 53}Cr atoms. Finally, we characterize the light-assisted collision losses in this Bose-Fermi cold mixture.

  18. Scattering of a tightly focused beam by an optically trapped particle

    SciTech Connect (OSTI)

    Lock, James A.; Wrbanek, Susan Y.; Weiland, Kenneth E

    2006-05-20

    Near-forward scattering of an optically trapped 5-{mu}m-radius polystyrene latex sphere by the trapping beam was examined both theoretically and experimentally. Since the trapping beam is tightly focused, the beam fields superpose and interfere with the scattered fields in the forward hemisphere. The observed light intensity consists of a series of concentric bright and dark fringes centered about the forward-scattering direction. Both the number of fringes and their contrast depend on the position of the trapping beam focal waist with respect to the sphere. The fringes are caused by diffraction that is due to the truncation of the tail of the trapping beam as the beam is transmitted through the sphere.

  19. Negative ion source

    DOE Patents [OSTI]

    Leung, K.N.; Ehlers, K.W.

    1984-12-04

    An ionization vessel is divided into an ionizing zone and an extraction zone by a magnetic filter. The magnetic filter prevents high-energy electrons from crossing from the ionizing zone to the extraction zone. A small positive voltage impressed on a plasma grid, located adjacent an extraction grid, positively biases the plasma in the extraction zone to thereby prevent positive ions from migrating from the ionizing zone to the extraction zone. Low-energy electrons, which would ordinarily be dragged by the positive ions into the extraction zone, are thereby prevented from being present in the extraction zone and being extracted along with negative ions by the extraction grid. Additional electrons are suppressed from the output flux using ExB drift provided by permanent magnets and the extractor grid electrical field. 14 figs.

  20. Actinide-ion sensor

    DOE Patents [OSTI]

    Li, Shelly X; Jue, Jan-fong; Herbst, Ronald Scott; Herrmann, Steven Douglas

    2015-01-13

    An apparatus for the real-time, in-situ monitoring of actinide-ion concentrations. A working electrolyte is positioned within the interior of a container. The working electrolyte is separated from a reference electrolyte by a separator. A working electrode is at least partially in contact with the working electrolyte. A reference electrode is at least partially in contact with the reference electrolyte. A voltmeter is electrically connected to the working electrode and the reference electrode. The working electrolyte comprises an actinide-ion of interest. The separator is ionically conductive to the actinide-ion of interest. The separator comprises an actinide, Zr, and Nb. Preferably, the actinide of the separator is Am or Np, more preferably Pu. In one embodiment, the actinide of the separator is the actinide of interest. In another embodiment, the separator further comprises P and O.

  1. Oxygen ion conducting materials

    DOE Patents [OSTI]

    Vaughey, John; Krumpelt, Michael; Wang, Xiaoping; Carter, J. David

    2005-07-12

    An oxygen ion conducting ceramic oxide that has applications in industry including fuel cells, oxygen pumps, oxygen sensors, and separation membranes. The material is based on the idea that substituting a dopant into the host perovskite lattice of (La,Sr)MnO.sub.3 that prefers a coordination number lower than 6 will induce oxygen ion vacancies to form in the lattice. Because the oxygen ion conductivity of (La,Sr)MnO.sub.3 is low over a very large temperature range, the material exhibits a high overpotential when used. The inclusion of oxygen vacancies into the lattice by doping the material has been found to maintain the desirable properties of (La,Sr)MnO.sub.3, while significantly decreasing the experimentally observed overpotential.

  2. Oxygen ion conducting materials

    DOE Patents [OSTI]

    Carter, J. David; Wang, Xiaoping; Vaughey, John; Krumpelt, Michael

    2004-11-23

    An oxygen ion conducting ceramic oxide that has applications in industry including fuel cells, oxygen pumps, oxygen sensors, and separation membranes. The material is based on the idea that substituting a dopant into the host perovskite lattice of (La,Sr)MnO.sub.3 that prefers a coordination number lower than 6 will induce oxygen ion vacancies to form in the lattice. Because the oxygen ion conductivity of (La,Sr)MnO.sub.3 is low over a very large temperature range, the material exhibits a high overpotential when used. The inclusion of oxygen vacancies into the lattice by doping the material has been found to maintain the desirable properties of (La,Sr)MnO.sub.3, while significantly decreasing the experimentally observed overpotential.

  3. Oxygen ion conducting materials

    DOE Patents [OSTI]

    Vaughey, John (Elmhurst, IL); Krumpelt, Michael (Naperville, IL); Wang, Xiaoping (Downers Grove, IL); Carter, J. David (Bolingbrook, IL)

    2003-01-01

    An oxygen ion conducting ceramic oxide that has applications in industry including fuel cells, oxygen pumps, oxygen sensors, and separation membranes. The material is based on the idea that substituting a dopant into the host perovskite lattice of (La,Sr)MnO.sub.3 that prefers a coordination number lower than 6 will induce oxygen ion vacancies to form in the lattice. Because the oxygen ion conductivity of (La,Sr)MnO.sub.3 is low over a very large temperature range, the material exhibits a high overpotential when used. The inclusion of oxygen vacancies into the lattice by doping the material has been found to maintain the desirable properties of (La,Sr)MnO.sub.3, while significantly decreasing the experimentally observed overpotential.

  4. Microwave ion source

    DOE Patents [OSTI]

    Leung, Ka-Ngo; Reijonen, Jani; Thomae, Rainer W.

    2005-07-26

    A compact microwave ion source has a permanent magnet dipole field, a microwave launcher, and an extractor parallel to the source axis. The dipole field is in the form of a ring. The microwaves are launched from the middle of the dipole ring using a coaxial waveguide. Electrons are heated using ECR in the magnetic field. The ions are extracted from the side of the source from the middle of the dipole perpendicular to the source axis. The plasma density can be increased by boosting the microwave ion source by the addition of an RF antenna. Higher charge states can be achieved by increasing the microwave frequency. A xenon source with a magnetic pinch can be used to produce intense EUV radiation.

  5. Radioactive ion detector

    DOE Patents [OSTI]

    Bower, K.E.; Weeks, D.R.

    1997-08-12

    Apparatus for detecting the presence, in aqueous media, of substances which emit alpha and/or beta radiation and determining the oxidation state of these radioactive substances, that is, whether they are in cationic or anionic form. In one embodiment, a sensor assembly has two elements, one comprised of an ion-exchange material which binds cations and the other comprised of an ion-exchange material which binds anions. Each ion-exchange element is further comprised of a scintillation plastic and a photocurrent generator. When a radioactive substance to which the sensor is exposed binds to either element and emits alpha or beta particles, photons produced in the scintillation plastic illuminate the photocurrent generator of that element. Sensing apparatus senses generator output and thereby indicates whether cationic species or anionic species or both are present and also provides an indication of species quantity. 2 figs.

  6. Radioactive ion detector

    DOE Patents [OSTI]

    Bower, Kenneth E. (Los Alamos, NM); Weeks, Donald R. (Saratoga, CA)

    1997-01-01

    Apparatus for detecting the presence, in aqueous media, of substances which emit alpha and/or beta radiation and determining the oxidation state of these radioactive substances, that is, whether they are in cationic or anionic form. In one embodiment, a sensor assembly has two elements, one comprised of an ion-exchange material which binds cations and the other comprised of an ion-exchange material which binds anions. Each ion-exchange element is further comprised of a scintillation plastic and a photocurrent generator. When a radioactive substance to which the sensor is exposed binds to either element and emits alpha or beta particles, photons produced in the scintillation plastic illuminate the photocurrent generator of that element. Sensing apparatus senses generator output and thereby indicates whether cationic species or anionic species or both are present and also provides an indication of species quantity.

  7. Negative ion source

    DOE Patents [OSTI]

    Leung, K.N.; Ehlers, K.W.

    1982-08-06

    An ionization vessel is divided into an ionizing zone and an extraction zone by a magnetic filter. The magnetic filter prevents high-energy electrons from crossing from the ionizing zone to the extraction zone. A small positive voltage impressed on a plasma grid, located adjacent an extraction grid, positively biases the plasma in the extraction zone to thereby prevent positive ions from migrating from the ionizing zone to the extraction zone. Low-energy electrons, which would ordinarily be dragged by the positive ions into the extraction zone, are thereby prevented from being present in the extraction zone and being extracted along with negative ions by the extraction grid. Additional electrons are suppressed from the output flux using ExB drift provided by permanent magnets and the extractor grid electrical field.

  8. Negative ion source

    DOE Patents [OSTI]

    Leung, Ka-Ngo (Hercules, CA); Ehlers, Kenneth W. (Alamo, CA)

    1984-01-01

    An ionization vessel is divided into an ionizing zone and an extraction zone by a magnetic filter. The magnetic filter prevents high-energy electrons from crossing from the ionizing zone to the extraction zone. A small positive voltage impressed on a plasma grid, located adjacent an extraction grid, positively biases the plasma in the extraction zone to thereby prevent positive ions from migrating from the ionizing zone to the extraction zone. Low-energy electrons, which would ordinarily be dragged by the positive ions into the extraction zone, are thereby prevented from being present in the extraction zone and being extracted along with negative ions by the extraction grid. Additional electrons are suppressed from the output flux using ExB drift provided by permanent magnets and the extractor grid electrical field.

  9. Hydrogen ion microlithography

    DOE Patents [OSTI]

    Tsuo, Y.S.; Deb, S.K.

    1990-10-02

    Disclosed is a hydrogen ion microlithography process for use in microelectronic fabrication and semiconductor device processing. The process comprises the steps of providing a single layer of either an amorphous silicon or hydrogenated amorphous silicon material. A pattern is recorded in a selected layer of amorphous silicon or hydrogenated amorphous silicon materials by preferentially implanting hydrogen ions therein so as to permit the selected layer to serve as a mask-resist wafer suitable for subsequent development and device fabrication. The layer is developed to provide a surface pattern therein adaptable for subsequent use in microelectronic fabrication and semiconductor device processing. 6 figs.

  10. Hydrogen ion microlithography

    DOE Patents [OSTI]

    Tsuo, Y. Simon (Lakewood, CO); Deb, Satyen K. (Boulder, CO)

    1990-01-01

    Disclosed is a hydrogen ion microlithography process for use in microelectronic fabrication and semiconductor device processing. The process comprises the steps of providing a single layer of either an amorphous silicon or hydrogenated amorphous silicon material. A pattern is recorded in a selected layer of amorphous silicon or hydrogenated amorphous silicon materials by preferentially implanting hydrogen ions therein so as to permit the selected layer to serve as a mask-resist wafer suitable for subsequent development and device fabrication. The layer is developed to provide a surface pattern therein adaptable for subsequent use in microelectronic fabrication and semiconductor device processing.

  11. The discrepancies in multistep damage evolution of yttria-stabilized zirconia irradiated with different ions

    SciTech Connect (OSTI)

    Yang, Tengfei; Taylor, Caitlin A.; Kong, Shuyan; Wang, Chenxu; Zhang, Yanwen; Huang, Xuejun; Xue, Jianming; Yan, Sha; Wang, Yugang

    2013-01-01

    This paper reports a comprehensive investigation of structural damage in yttria-stabilized zirconia irradiated with different ions over a wide fluence range. A similar multistep damage accumulation exists for the irradiations of different ions, but the critical doses for occurrence of second damage step, characterized by a faster increase in damage fraction, and the maximum elastic strain at the first damage step are varied and depend on ion mass. For irradiations of heavier ions, the second damage step occurs at a higher dose with a lower critical elastic strain. Furthermore, larger extended defects were observed in the irradiations of heavy ions at the second damage step. Associated with other experiment results and multistep damage accumulation model, the distinct discrepancies in the damage buildup under irradiations of different ions were interpreted by the effects of electronic excitation, energy of primary knock-on atom and chemistry contributions of deposited ions.

  12. Time-of-flight SIMS/MSRI reflectron mass analyzer and method

    DOE Patents [OSTI]

    Smentkowski, Vincent S. (Clifton Park, NY); Gruen, Dieter M. (Downers Grove, IL); Krauss, Alan R. (Naperville, IL); Schultz, J. Albert (Houston, TX); Holecek, John C. (Colorado Springs, CO)

    1999-12-28

    A method and apparatus for analyzing the surface characteristics of a sample by Secondary Ion Mass Spectroscopy (SIMS) and Mass Spectroscopy of Recoiled Ions (MSRI) is provided. The method includes detecting back scattered primary ions, low energy ejected species, and high energy ejected species by ion beam surface analysis techniques comprising positioning a ToF SIMS/MSRI mass analyzer at a predetermined angle .theta., where .theta. is the angle between the horizontal axis of the mass analyzer and the undeflected primary ion beam line, and applying a specific voltage to the back ring of the analyzer. Preferably, .theta. is less than or equal to about 120.degree. and, more preferably, equal to 74.degree.. For positive ion analysis, the extractor, lens, and front ring of the reflectron are set at negative high voltages (-HV). The back ring of the reflectron is set at greater than about +700V for MSRI measurements and between the range of about +15 V and about +50V for SIMS measurements. The method further comprises inverting the polarity of the potentials applied to the extractor, lens, front ring, and back ring to obtain negative ion SIMS and/or MSRI data.

  13. Determination of atmospheric carbonyl sulfide by isotope dilution gas chromatography/mass spectrometry

    SciTech Connect (OSTI)

    Lewin, E.E.; Taggart, R.L.; Lalevic, M.; Bandy, A.R.

    1987-05-01

    A gas chromatography/mass spectrometry (GB/MS) method for determining atmospheric carbonyl sulfide (OCS) with a precision better than 2% is reported. High precision and insensitivity to sample loss and changes in detector response were achieved by using isotopically labeled OCS as an internal standard. Tenax, Molecular Sieve 5A, Carbosieve B, and Carbosieve S were evaluated for collecting atmospheric OCS. Molecular Sieve 5A provided the best trapping and recovery efficiencies.

  14. Ion velocities in direct current arc plasma generated from compound cathodes

    SciTech Connect (OSTI)

    Zhirkov, I.; Rosen, J.; Eriksson, A. O.; Oerlikon Balzers Coating AG, Iramali 18, 9496 Balzers

    2013-12-07

    Arc plasma from Ti-C, Ti-Al, and Ti-Si cathodes was characterized with respect to charge-state-resolved ion energy. The evaluated peak velocities of different ion species in plasma generated from a compound cathode were found to be equal and independent on ion mass. Therefore, measured difference in kinetic energies can be inferred from the difference in ion mass, with no dependence on ion charge state. The latter is consistent with previous work. These findings can be explained by plasma quasineutrality, ion acceleration by pressure gradients, and electron-ion coupling. Increasing the C concentration in Ti-C cathodes resulted in increasing average and peak ion energies for all ion species. This effect can be explained by the cohesive energy rule, where material and phases of higher cohesive energy generally result in increasing energies (velocities). This is also consistent with the here obtained peak velocities around 1.37, 1.42, and 1.55 (10{sup 4} m/s) for ions from Ti{sub 0.84}Al{sub 0.16}, Ti{sub 0.90}Si{sub 0.10}, and Ti{sub 0.90}C{sub 0.10} cathodes, respectively.

  15. Distance-dependent plasma composition and ion energy in high power impulse magnetron sputtering

    SciTech Connect (OSTI)

    Ehiasarian, Arutiun P; Andersson, Joakim; Anders, Andr

    2010-04-18

    The plasma composition of high power impulse magnetron sputtering (HIPIMS) has been studied for titanium and chromium targets using a combined energy analyser and quadrupole mass spectrometer. Measurements were done at distances from 50 to 300 mm from the sputtering target. Ti and Cr are similar in atomic mass but have significantly different sputter yields, which gives interesting clues on the effect of the target on plasma generation and transport of atoms. The Ti and Cr HIPIMS plasmas operated at a peak target current density of ~;;0.5 A cm-2. The measurements of the argon and metal ion content as well as the ion energy distribution functions showed that (1) singly and doubly charged ions were found for argon as well as for the target metal, (2) the majority of ions were singly charged argon for both metals at all distances investigated, (3) the Cr ion density was maintained to distances further from the target than Ti. Gas rarefaction was identified as a main factor promoting transport of metal ions, with the stronger effect observed for Cr, the material with higher sputter yield. Cr ions were found to displace a significant portion of the gas ions, whereas this was less evident in the Ti case. The observations indicate that the presence of metal vapour promotes charge exchange and reduces the electron temperature and thereby practically prevents the production of Ar2+ ions near the target. The content of higher charge states of metal ions depends on the probability of charge exchange with argon.

  16. Proceedings of the workshop on opportunities for atomic physics using slow, highly-charged ions

    SciTech Connect (OSTI)

    Not Available

    1987-01-01

    The study of atomic physics with highly-charged ions is an area of intense activity at the present time because of a convergence of theoretical interest and advances in experimental techniques. The purpose of the Argonne ''Workshop on Opportunities for Atomic Physics Using Slow, Highly-Charged Ions'' was to bring together atomic, nuclear, and accelerator physicists in order to identify what new facilities would be most useful for the atomic physics community. The program included discussion of existing once-through machines, advanced ion sources, recoil ion techniques, ion traps, and cooler rings. One of the topics of the Workshop was to discuss possible improvement to the ANL Tandem-Linac facility (ATLAS) to enhance the capability for slowing down ions after they are stripped to a high-charge state (the Accel/Decel technique). Another topic was the opportunity for atomic physics provided by the ECR ion source which is being built for the Uranium Upgrade of ATLAS. 18 analytics were prepared for the individual papers in this volume.

  17. Laser driven ion accelerator

    DOE Patents [OSTI]

    Tajima, Toshiki

    2006-04-18

    A system and method of accelerating ions in an accelerator to optimize the energy produced by a light source. Several parameters may be controlled in constructing a target used in the accelerator system to adjust performance of the accelerator system. These parameters include the material, thickness, geometry and surface of the target.

  18. Laser driven ion accelerator

    DOE Patents [OSTI]

    Tajima, Toshiki

    2005-06-14

    A system and method of accelerating ions in an accelerator to optimize the energy produced by a light source. Several parameters may be controlled in constructing a target used in the accelerator system to adjust performance of the accelerator system. These parameters include the material, thickness, geometry and surface of the target.

  19. Pulsed ion beam source

    DOE Patents [OSTI]

    Greenly, J.B.

    1997-08-12

    An improved pulsed ion beam source is disclosed having a new biasing circuit for the fast magnetic field. This circuit provides for an initial negative bias for the field created by the fast coils in the ion beam source which pre-ionize the gas in the source, ionize the gas and deliver the gas to the proper position in the accelerating gap between the anode and cathode assemblies in the ion beam source. The initial negative bias improves the interaction between the location of the nulls in the composite magnetic field in the ion beam source and the position of the gas for pre-ionization and ionization into the plasma as well as final positioning of the plasma in the accelerating gap. Improvements to the construction of the flux excluders in the anode assembly are also accomplished by fabricating them as layered structures with a high melting point, low conductivity material on the outsides with a high conductivity material in the center. 12 figs.

  20. Lithium ion conducting electrolytes

    DOE Patents [OSTI]

    Angell, Charles Austen (Mesa, AZ); Liu, Changle (Midland, MI); Xu, Kang (Montgomery Village, MD); Skotheim, Terje A. (Tucson, AZ)

    1999-01-01

    The present invention relates generally to highly conductive alkali-metal ion non-crystalline electrolyte systems, and more particularly to novel and unique molten (liquid), rubbery, and solid electrolyte systems which are especially well suited for use with high current density electrolytic cells such as primary and secondary batteries.

  1. Photo ion spectrometer

    DOE Patents [OSTI]

    Gruen, Dieter M. (Downers Grove, IL); Young, Charles E. (Westmont, IL); Pellin, Michael J. (Naperville, IL)

    1989-01-01

    A method and apparatus for extracting for quantitative analysis ions of selected atomic components of a sample. A lens system is configured to provide a slowly diminishing field region for a volume containing the selected atomic components, enabling accurate energy analysis of ions generated in the slowly diminishing field region. The lens system also enables focusing on a sample of a charged particle beam, such as an ion beam, along a path length perpendicular to the sample and extraction of the charged particles along a path length also perpendicular to the sample. Improvement of signal to noise ratio is achieved by laser excitation of ions to selected autoionization states before carrying out quantitative analysis. Accurate energy analysis of energetic charged particles is assured by using a preselected resistive thick film configuration disposed on an insulator substrate for generating predetermined electric field boundary conditions to achieve for analysis the required electric field potential. The spectrometer also is applicable in the fields of SIMS, ISS and electron spectroscopy.

  2. Photo ion spectrometer

    DOE Patents [OSTI]

    Gruen, D.M.; Young, C.E.; Pellin, M.J.

    1989-08-08

    A method and apparatus are described for extracting for quantitative analysis ions of selected atomic components of a sample. A lens system is configured to provide a slowly diminishing field region for a volume containing the selected atomic components, enabling accurate energy analysis of ions generated in the slowly diminishing field region. The lens system also enables focusing on a sample of a charged particle beam, such as an ion beam, along a path length perpendicular to the sample and extraction of the charged particles along a path length also perpendicular to the sample. Improvement of signal to noise ratio is achieved by laser excitation of ions to selected auto-ionization states before carrying out quantitative analysis. Accurate energy analysis of energetic charged particles is assured by using a preselected resistive thick film configuration disposed on an insulator substrate for generating predetermined electric field boundary conditions to achieve for analysis the required electric field potential. The spectrometer also is applicable in the fields of SIMS, ISS and electron spectroscopy. 8 figs.

  3. Flowing afterglow measurements of the density dependence of gas-phase ion-ion mutual neutralization reactions

    SciTech Connect (OSTI)

    Shuman, Nicholas S.; Viggiano, Albert A.; Johnsen, Rainer

    2013-05-28

    We have studied the dependence of several ion-ion mutual neutralization (MN) reactions on helium density in the range from 1.6 Multiplication-Sign 10{sup 16} to 1.5 Multiplication-Sign 10{sup 17} cm{sup -3} at 300 K, using the Variable Electron and Neutral Density Attachment Mass Spectrometry method. The rate coefficients of the reactions Ar{sup +}+ Br{sub 2}{sup -}, Ar{sup +}+ SF{sub 6}{sup -}, and Ar{sup +}+ C{sub 7}F{sub 14}{sup -} were found to be independent of gas density over the range studied, in disagreement with earlier observations that similar MN reactions are strongly enhanced at the same gas densities. The cause of the previous enhancement with density is traced to the use of 'orbital-motion-limit' theory to infer ion densities from the currents collected by ion-attracting Langmuir probes in a region where it is not applicable.

  4. Electron Ionization Mass Spectrum of Tellurium Hexafluoride

    SciTech Connect (OSTI)

    Clark, Richard A.; McNamara, Bruce K.; Barinaga, Charles J.; Peterson, James M.; Govind, Niranjan; Andersen, Amity; Abrecht, David G.; Schwantes, Jon M.; Ballou, Nathan E.

    2015-05-18

    The first electron ionization mass spectrum of tellurium hexafluoride (TeF6) is reported. The starting material was produced by direct fluorination of Te metal or TeO2 with nitrogen trifluoride. Formation of TeF6 was confirmed through cryogenic capture of the tellurium fluorination product and analysis through Raman spectroscopy. The eight natural abundance isotopes were observed for each of the set of fragment ions: TeF5+, TeF4+ TeF3+, TeF2+, TeF1+, and Te+, Te2+. A trend in increasing abundance was observed for the even fluoride bearing ions: TeF1+ < TeF3+ < TeF5+, and a decreasing abundance was observed for the even fragment series: Te(0)+ > TeF2+ > TeF4+ > TeF6+, with the molecular ion TeF6+ not observed at all. Density functional theory based electronic structure calculations were used to calculate optimized ground state geometries of these gas phase species and their relative stabilities explain the trends in the data and the lack of observed signal for TeF6+.

  5. Ion polarization in the MEIC figure-8 ion collider ring

    SciTech Connect (OSTI)

    V.S. Morozov, Ya.S. Derbenev, Y. Zhang, P. Chevtsov, A.M. Kondratenko, M.A. Kondratenko, Yu.N. Filatov

    2012-07-01

    The nuclear physics program envisaged at the Medium-energy Electron-Ion Collider (MEIC) currently being developed at the Jefferson Lab calls for collisions of 3-11 GeV/c longitudinally polarized electrons and 20-100 GeV/c, in equivalent proton momentum, longitudinally/ transversely polarized protons/ deuterons/ light ions. We present a scheme that provides the required ion polarization arrangement in the MEIC's ion collider ring.

  6. Ion velocities in a micro-cathode arc thruster

    SciTech Connect (OSTI)

    Zhuang Taisen; Shashurin, Alexey; Keidar, Michael; Beilis, Isak

    2012-06-15

    Ion velocities in the plasma jet generated by the micro-cathode arc thruster are studied by means of time-of-flight method using enhanced ion detection system (EIDS). The EIDS triggers perturbations (spikes) on arc current waveform, and the larger current in the spike generates denser plasma bunches propagating along with the mainstream plasma. The EIDS utilizes double electrostatic probes rather than single probes. The average Ti ion velocity is measured to be around 2 Multiplication-Sign 10{sup 4} m/s without a magnetic field. It was found that the application of a magnetic field does not change ion velocities in the interelectrode region while leads to ion acceleration in the free expanding plasma plume by a factor of about 2. Ion velocities of about 3.5 Multiplication-Sign 10{sup 4} m/s were detected for the magnetic field of about 300 mT at distance of about 100-200 mm from the cathode. It is proposed that plasma is accelerated due to Lorentz force. The average thrust is calculated using the ion velocity measurements and the cathode mass consumption rate, and its increase with the magnetic field is demonstrated.

  7. Particle trap for compressed gas insulated transmission systems

    DOE Patents [OSTI]

    Cookson, Alan H. (Pittsburgh, PA)

    1985-01-01

    A particle trap is provided for gas insulated transmission lines having a central high voltage conductor supported within an outer coaxial conductive sheath by a dielectric support member. A cavity between the inner conductor and outer sheath is filled with a dielectric insulating gas. A cone-like particle deflector, mounted to the inner conductor, deflects moving particles away from the support member, to radially outer portions of the cavity. A conductive shield is disposed adjacent the outer sheath to form a field-free region in radially outer portions of the cavity, between the shield and the sheath. Particles traveling along the cavity are deflected by the cone-like deflector into the field-free region where they are held immobile. In a vertical embodiment, particles enter the field-free region through an upper end of a gap formed between shield and sheath members. In a horizontal embodiment, the deflector cone has a base which is terminated radially internally of the shield. Apertures in the shield located adjacent the deflector allow passage of deflected particles into the field-free region. The dielectric support member is thereby protected from contaminating particles that may otherwise come to rest thereon.

  8. Particle trap for compressed gas insulated transmission systems

    DOE Patents [OSTI]

    Cookson, A.H.

    1984-04-26

    A particle trap is provided for gas insulated transmission lines having a central high voltage conductor supported within an outer coaxial conductive sheath by a dielectric support member. A cavity between the inner conductor and outer sheath is filled with a dielectric insulating gas. A cone-like particle deflector, mounted to the inner conductor, deflects moving particles away from the support member, to radially outer portions of the cavity. A conductive shield is disposed adjacent the outer sheath to form a field-free region in radially outer portions of the cavity, between the shield and the sheath. Particles traveling along the cavity are deflected by the cone-like deflector into the field-free region where they are held immobile. In a vertical embodiment, particles enter the field-free region through an upper end of a gap formed between shield and sheath members. In a horizontal embodiment, the deflector cone has a base which is terminated radially internally of the shield. Apertures in the shield located adjacent the deflector allow passage of deflected particles into the field-free region. The dielectric support member is thereby protected from contaminating particles that may otherwise come to rest thereon.

  9. Three-dimensional light trap for reflective particles

    DOE Patents [OSTI]

    Neal, Daniel R. (Tijeras, NM)

    1999-01-01

    A system for containing either a reflective particle or a particle having an index of refraction lower than that of the surrounding media in a three-dimensional light cage. A light beam from a single source illuminates an optics system and generates a set of at least three discrete focussed beams that emanate from a single exit aperture and focus on to a focal plane located close to the particle. The set of focal spots defines a ring that surrounds the particle. The set of focussed beams creates a "light cage" and circumscribes a zone of no light within which the particle lies. The surrounding beams apply constraining forces (created by radiation pressure) to the particle, thereby containing it in a three-dimensional force field trap. A diffractive element, such as an aperture multiplexed lens, or either a Dammann grating or phase element in combination with a focusing lens, may be used to generate the beams. A zoom lens may be used to adjust the size of the light cage, permitting particles of various sizes to be captured and contained.

  10. Three-dimensional light trap for reflective particles

    DOE Patents [OSTI]

    Neal, D.R.

    1999-08-17

    A system is disclosed for containing either a reflective particle or a particle having an index of refraction lower than that of the surrounding media in a three-dimensional light cage. A light beam from a single source illuminates an optics system and generates a set of at least three discrete focused beams that emanate from a single exit aperture and focus on to a focal plane located close to the particle. The set of focal spots defines a ring that surrounds the particle. The set of focused beams creates a ``light cage`` and circumscribes a zone of no light within which the particle lies. The surrounding beams apply constraining forces (created by radiation pressure) to the particle, thereby containing it in a three-dimensional force field trap. A diffractive element, such as an aperture multiplexed lens, or either a Dammann grating or phase element in combination with a focusing lens, may be used to generate the beams. A zoom lens may be used to adjust the size of the light cage, permitting particles of various sizes to be captured and contained. 10 figs.

  11. Certification Framework Based on Effective Trapping for Geologic Carbon Sequestration

    SciTech Connect (OSTI)

    Oldenburg, Curtis M.; Bryant, Steven L.; Nicot, Jean-Philippe

    2009-01-15

    We have developed a certification framework (CF) for certifying the safety and effectiveness of geologic carbon sequestration (GCS) sites. Safety and effectiveness are achieved if CO{sub 2} and displaced brine have no significant impact on humans, other living things, resources, or the environment. In the CF, we relate effective trapping to CO{sub 2} leakage risk which takes into account both the impact and probability of leakage. We achieve simplicity in the CF by using (1) wells and faults as the potential leakage pathways, (2) compartments to represent environmental resources that may be impacted by leakage, (3) CO{sub 2} fluxes and concentrations in the compartments as proxies for impact to vulnerable entities, (4) broad ranges of storage formation properties to generate a catalog of simulated plume movements, and (5) probabilities of intersection of the CO{sub 2} plume with the conduits and compartments. We demonstrate the approach on a hypothetical GCS site in a Texas Gulf Coast saline formation. Through its generality and flexibility, the CF can contribute to the assessment of risk of CO{sub 2} and brine leakage as part of the certification process for licensing and permitting of GCS sites around the world regardless of the specific regulations in place in any given country.

  12. Unconformity related traps and production, Lower Cretaceous through Mississippian Strata, central and northern Rocky Mountains

    SciTech Connect (OSTI)

    Dolson, J. )

    1990-05-01

    Unconformities provide a useful means of equating stratigraphic traps between basins. Systematic mapping can define new concepts through analogy, often from geographically separate areas. Lower Cretaceous through Mississippian surfaces in the central and northern Rockies provide examples. Late Mississippian and Early Pennsylvanian surfaces formed at least four paleodrainage basins separated by the Transcontinental arch. Tyler Formation valley fills (Montana, North Dakota) have produced more than 100 million BOE. Analogous targets in Utah remain untested, but the Mid-Continent Morrow trend continues to yield new reserves. Permian and Triassic paleodrainages filled primarily with seals and form regional traps. A breached Madison trap (Mississippian, Colorado), more than 350 million BOE (Permian Minnelusa, Wyoming), more than 8 billion BOE (from the White Rim Sandstone tar deposits Permian Utah), and eastern Williston basin (Mississippian) are examples. Minor basal valley fill trapping also occurs. Transgressive carbonate facies changes have trapped more than 40 million BOE (Permian Phosphoria Formation, Wyoming). Additional deep gas potential exists. Jurassic unconformities control seal distribution over Nugget Sandstone (Jurassic) reservoirs and partially control Mississippian porosity on the Sweetgrass arch (Montana). Minor paleohill trapping also occurs. Lower Cretaceous surfaces have trapped nearly 2 billion BOE hydrocarbons in 10 paleodrainage networks. Undrilled paleodrainage basins remain deep gas targets. The systematic examination of Rocky Mountain unconformities has been understudied. New exploration concepts and reserve additions await the creative interpreter.

  13. SECTION II: HEAVY ION REACTIONS

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    II: HEAVY ION REACTIONS Experimental Determination of the Symmetry Energy of a Low Density Nuclear Gas ...II-1 S....

  14. Ion Removal - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Advanced Materials Advanced Materials Find More Like This Return to Search Ion Removal Idaho National Laboratory Contact INL About This Technology Technology Marketing Summary INL's ion removal technology leverages the ability of phosphazene polymers discriminate between water and metal ions, which allows water to pass through the membrane while retaining the ions. Description The inherent chemical and thermal stability of the phosphazene polymers are an added strengths for separating and

  15. Light Trapping for Thin Silicon Solar Cells by Femtosecond Laser Texturing: Preprint

    SciTech Connect (OSTI)

    Lee, B. G.; Lin, Y. T.; Sher, M. J.; Mazur, E.; Branz, H. M.

    2012-06-01

    Femtosecond laser texturing is used to create nano- to micron-scale surface roughness that strongly enhances light-trapping in thin crystalline silicon solar cells. Light trapping is crucial for thin solar cells where a single light-pass through the absorber is insufficient to capture the weakly absorbed red and near-infrared photons, especially with an indirect-gap semiconductor absorber layer such as crystalline Si which is less than 20 um thick. We achieve enhancement of the optical absorption from light-trapping that approaches the Yablonovitch limit.

  16. Optical trapping and rotation of airborne absorbing particles with a single focused laser beam

    SciTech Connect (OSTI)

    Lin, Jinda; Li, Yong-qing, E-mail: liy@ecu.edu [Department of Physics, East Carolina University, Greenville, North Carolina 27858-4353 (United States)] [Department of Physics, East Carolina University, Greenville, North Carolina 27858-4353 (United States)

    2014-03-10

    We measure the periodic circular motion of single absorbing aerosol particles that are optically trapped with a single focused Gaussian beam and rotate around the laser propagation direction. The scattered light from the trapped particle is observed to be directional and change periodically at 0.420?kHz. The instantaneous positions of the moving particle within a rotation period are measured by a high-speed imaging technique using a charge coupled device camera and a repetitively pulsed light-emitting diode illumination. The centripetal acceleration of the trapped particle as high as ?20 times the gravitational acceleration is observed and is attributed to the photophoretic forces.

  17. Generation and decay of entanglement in exciton/polariton trapped systems

    SciTech Connect (OSTI)

    Quiroga, L.; Tejedor, C.

    2011-12-23

    The entanglement evolution of interacting trapped solid-state bosons, i.e. excitons or polaritons, is theoretically studied. From an initially separable state the quasi-particle interactions generate boson entanglement which is degraded as dissipation takes place. Based on exact solutions of a Markovian Master equation at T = 0 K, we discuss how dissipation affects the quantum entanglement dynamics of coupled solid-state boson systems. The single trap Wigner function is also calculated and its relationship to the trapped boson entanglement is discussed.

  18. GreenPowerTM Trap-Muffler System | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    GreenPowerTM Trap-Muffler System GreenPowerTM Trap-Muffler System Poster presentation at the 2007 Diesel Engine-Efficiency & Emissions Research Conference (DEER 2007). 13-16 August, 2007, Detroit, Michigan. Sponsored by the U.S. Department of Energy's (DOE) Office of FreedomCAR and Vehicle Technologies (OFCVT). PDF icon deer07_rim.pdf More Documents & Publications GreenPower Trap Water-Muffler System DPF -"Hydrated EGR" Fuel Saver

  19. Thermal Deactivation Mechanisms of Fully-Formed Lean NOx Trap Catalysts

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Aged by Lean/Rich Cycling | Department of Energy Deactivation Mechanisms of Fully-Formed Lean NOx Trap Catalysts Aged by Lean/Rich Cycling Thermal Deactivation Mechanisms of Fully-Formed Lean NOx Trap Catalysts Aged by Lean/Rich Cycling Catalysts in fully formulated lean NOx traps are aged and evaluated in a bench-flow reactor using simulated diesel engine exhaust. PDF icon deer08_toops.pdf More Documents & Publications APBF-DEC Heavy Duty NOx Adsorber/DPF Project: Heavy Duty Linehaul

  20. Space charge compensation in the Linac4 low energy beam transport line with negative hydrogen ions

    SciTech Connect (OSTI)

    Valerio-Lizarraga, Cristhian A.; Lallement, Jean-Baptiste; Lettry, Jacques; Scrivens, Richard; Leon-Monzon, Ildefonso; Midttun, ystein; University of Oslo, Oslo

    2014-02-15

    The space charge effect of low energy, unbunched ion beams can be compensated by the trapping of ions or electrons into the beam potential. This has been studied for the 45 keV negative hydrogen ion beam in the CERN Linac4 Low Energy Beam Transport using the package IBSimu [T. Kalvas et al., Rev. Sci. Instrum. 81, 02B703 (2010)], which allows the space charge calculation of the particle trajectories. The results of the beam simulations will be compared to emittance measurements of an H{sup ?} beam at the CERN Linac4 3 MeV test stand, where the injection of hydrogen gas directly into the beam transport region has been used to modify the space charge compensation degree.

  1. Engineering rock mass classifications

    SciTech Connect (OSTI)

    Bieniawski, Z.T.

    1989-01-01

    This book is a reference on rock mass classification, consolidating into one handy source information widely scattered through the literature. Includes new, unpublished material and case histories. Presents the fundamental concepts of classification schemes and critically appraises their practical application in industrial projects such as tunneling and mining.

  2. Characterization of an RF plasma ion source for ion implantation

    SciTech Connect (OSTI)

    Kopalidis, Peter M.; Wan Zhimin

    2012-11-06

    A novel inductively coupled RF plasma ion source has been developed for use in a beamline ion implanter. Ion density data have been taken with an array of four Langmuir probes spaced equally at the source extraction arc slit. These provide ion density uniformity information as a function of source pressure, RF power and gas mixture composition. In addition, total extracted ion beam current data are presented for the same conditions. The comparative advantages of the RF source in terms of higher beam current, reduced maintenance and overall productivity improvement compared to a hot cathode source are discussed.

  3. Method of precisely modifying predetermined surface layers of a workpiece by cluster ion impact therewith

    DOE Patents [OSTI]

    Friedman, Lewis (Patchogue, NY); Buehler, Robert J. (Patchogue, NY); Matthew, Michael W. (East Patchogue, NY); Ledbetter, Myron (Belle Terre, NY)

    1985-01-01

    A method of precisely modifying a selected area of a workpiece by producing a beam of charged cluster ions that is narrowly mass selected to a predetermined mean size of cluster ions within a range of 25 to 10.sup.6 atoms per cluster ion, and accelerated in a beam to a critical velocity. The accelerated beam is used to impact a selected area of an outer surface of the workpiece at a preselected rate of impacts of cluster ions/cm.sup.2 /sec. in order to effect a precise modification in that selected area of the workpiece.

  4. Method of precisely modifying predetermined surface layers of a workpiece by cluster ion impact therewith

    DOE Patents [OSTI]

    Friedman, L.; Beuhler, R.J.; Matthew, M.W.; Ledbetter, M.

    1984-06-25

    A method of precisely modifying a selected area of a workpiece by producing a beam of charged cluster ions that is narrowly mass selected to a predetermined mean size of cluster ions within a range of 25 to 10/sup 6/ atoms per cluster ion, and accelerated in a beam to a critical velocity. The accelerated beam is used to impact a selected area of an outer surface of the workpiece at a preselected rate of impacts of cluster ions/cm/sup 2//sec in order to effect a precise modification in that selected area of the workpiece.

  5. Origins of ion irradiation-induced Ga nanoparticle motion on GaAs surfaces

    SciTech Connect (OSTI)

    Kang, M.; Wu, J. H.; Chen, H. Y.; Thornton, K.; Goldman, R. S. [Department of Materials Science and Engineering, University of Michigan, Ann Arbor, Michigan 48109-2136 (United States)] [Department of Materials Science and Engineering, University of Michigan, Ann Arbor, Michigan 48109-2136 (United States); Sofferman, D. L. [Department of Materials Science and Engineering, University of Michigan, Ann Arbor, Michigan 48109-2136 (United States) [Department of Materials Science and Engineering, University of Michigan, Ann Arbor, Michigan 48109-2136 (United States); Department of Physics, Adelphi University, Garden City, New York 11530-0701 (United States); Beskin, I. [Department of Physics, University of Michigan, Ann Arbor, Michigan 48109-1040 (United States)] [Department of Physics, University of Michigan, Ann Arbor, Michigan 48109-1040 (United States)

    2013-08-12

    We have examined the origins of ion irradiation-induced nanoparticle (NP) motion. Focused-ion-beam irradiation of GaAs surfaces induces random walks of Ga NPs, which are biased in the direction opposite to that of ion beam scanning. Although the instantaneous NP velocities are constant, the NP drift velocities are dependent on the off-normal irradiation angle, likely due to a difference in surface non-stoichiometry induced by the irradiation angle dependence of the sputtering yield. It is hypothesized that the random walks are initiated by ion irradiation-induced thermal fluctuations, with biasing driven by anisotropic mass transport.

  6. Effect of electromagnetic pulse transverse inhomogeneity on ion acceleration by radiation pressure

    SciTech Connect (OSTI)

    Lezhnin, K. V.; Kamenets, F. F.; Beskin, V. S.; Kando, M.; Esirkepov, T. Zh.; Bulanov, S. V.

    2015-03-15

    During ion acceleration by radiation pressure, a transverse inhomogeneity of an electromagnetic pulse leads to an off-axis displacement of the irradiated target, limiting the achievable ion energy. This effect is analytically described within the framework of a thin foil target model and with particle-in-cell simulations showing that the maximum energy of the accelerated ions decreases as the displacement from the axis of the target's initial position increases. The results obtained can be applied to the optimization of ion acceleration by the laser radiation pressure with mass-limited targets.

  7. Laser driven compact ion accelerator

    DOE Patents [OSTI]

    Tajima, Toshiki

    2005-03-15

    A laser driven compact ion source including a light source that produces an energy pulse, a light source guide that guides the energy pulse to a target and produces an ion beam. The ion beam is transported to a desired destination.

  8. Air mass flow estimation in turbocharged diesel engines from in-cylinder pressure measurement

    SciTech Connect (OSTI)

    Desantes, J.M.; Galindo, J.; Guardiola, C.; Dolz, V.

    2010-01-15

    Air mass flow determination is needed for the control of current internal combustion engines. Current methods are based on specific sensors (as hot wire anemometers) or indirect estimation through manifold pressure. With the availability of cylinder pressure sensors for engine control, methods based on them can be used for replacing or complementing standard methods. Present paper uses in cylinder pressure increase during the intake stroke for inferring the trapped air mass. The method is validated on two different turbocharged diesel engines and compared with the standard methods. (author)

  9. Sulfate Storage and Stability on Common Lean NOx Trap Components

    SciTech Connect (OSTI)

    Ottinger, Nathan A; Toops, Todd J; Pihl, Josh A; Roop, Justin T; Choi, Jae-Soon; Partridge Jr, William P

    2012-01-01

    Components found in a commercial lean NO{sub x} trap have been studied in order to determine their impact on sulfate storage and release. A micro-reactor and a diffuse reflectance infrared Fourier transform spectrometer (DRIFTS) were used to compare components MgAl{sub 2}O{sub 4}, Pt/MgAl{sub 2}O{sub 4}, Pt/Al{sub 2}O{sub 3}, Pt/Ba/Al{sub 2}O{sub 3}, Pt/CeO{sub 2}-ZrO{sub 2}, and Pt/Ba/CeO{sub 2}-ZrO{sub 2}, as well as physical mixtures of Pt/Al{sub 2}O{sub 3} + MgAl{sub 2}O{sub 4} and Pt/Ba/CeO{sub 2}-ZrO{sub 2} + MgAl{sub 2}O{sub 4}. Desulfation temperature profiles as well as DRIFTS NO{sub x} and SO{sub x} storage spectra are presented for all components. This systematic approach highlighted the ability of the underlying support to impact sulfate stability, in particular when Ba was supported on ceria-zirconia rather than alumina the desulfation temperature decreased by 60-120 C. A conceptual model of sulfation progression on the ceria-zirconia support is proposed that explains the high uptake of sulfur and low temperature release when it is employed. It was also determined that the close proximity of platinum is not necessary for much of the sulfation and desulfation chemistry that occurs, as physical mixtures with platinum dispersed on only one phase displayed similar behavior to samples with platinum dispersed on both phases.

  10. Ion aggregation in high salt solutions: Ion network versus ion cluster

    SciTech Connect (OSTI)

    Kim, Seongheun; Kim, Heejae; Choi, Jun-Ho; Cho, Minhaeng

    2014-09-28

    The critical aggregation phenomena are ubiquitous in many self-assembling systems. Ions in high salt solutions could also spontaneously form larger ion aggregates, but their effects on hydrogen-bond structures in water have long been controversial. Here, carrying out molecular dynamics (MD) simulation studies of high salt solutions and comparing the MD simulation results with infrared absorption and pump-probe spectroscopy of OD stretch mode of HDO in highly concentrated salt solutions and {sup 13}C-NMR chemical shift of S{sup 13}CN{sup ?} in KSCN solutions, we find evidence on the onset of ion aggregate and large-scale ion-ion network formation that concomitantly breaks water hydrogen-bond structure in certain salt solutions. Despite that these experimental results cannot provide direct evidence on the three-dimensional morphological structures of ion aggregates, they serve as reference data for verifying MD simulation methods. The MD results suggest that disrupted water hydrogen-bond network is intricately intertwined with ion-ion network. This further shows morphological variation of ion aggregate structures from ion cluster to ion network in high salt solutions that are interrelated to the onset of macroscopic aggregate formation and the water hydrogen-bond structure making and breaking processes induced by Hofmeister ions.

  11. Time-of-flight heavy ion backscattering spectrometry

    SciTech Connect (OSTI)

    Knapp, J.A.; Banks, J.C.; Doyle, B.L.

    1993-08-01

    A new time-of-flight (TOF) ion detection system for Heavy Ion Backscattering Spectrometry (HIBS) is described. Examples are also given of the use of the system for measuring low-level contamination on Si wafers. Currently, the TOF-HBIS system has a sensitivity of 1 {times} 10{sup 9}/cm{sup 2} for the heaviest of surface impurity atoms and a mass resolution capable of separating Fe from Cu. The sensitivity is expected to improve by an additional order of magnitude on a industrial TOF-HIBS system being constructed for SEMATECH.

  12. Vertically aligned gas-insulated transmission line having particle traps at the inner conductor

    DOE Patents [OSTI]

    Dale, Steinar J. (Monroeville, PA)

    1984-01-01

    Gas insulated electrical apparatus having first and second conductors separated by an insulating support within an insulating gas environment, and particle traps disposed along the surface of the high potential conductor for trapping and inactivating foreign particles which may be present within the insulating gas medium. Several embodiments of the invention were developed which are particularly suited for vertically aligned gas insulated transmission lines. The particle traps are grooves or cavities formed into the walls of the tubular inner conductor, without extending into the hollow portion of the conductor. In other embodiments, the traps are appendages or insert flanges extending from the inner conductor, with the insulator supports contacting the appendages instead of the inner conductor.

  13. High Contrast Ramsey Fringes with Coherent-Population-Trapping Pulses in a Double Lambda Atomic System

    SciTech Connect (OSTI)

    Zanon, T.; Guerandel, S.; Clercq, E. de; Holleville, D.; Dimarcq, N.; Clairon, A. [SYRTE, Observatoire de Paris, 61 Avenue de l'Observatoire, 75014 Paris (France)

    2005-05-20

    We report the observation of Raman-Ramsey fringes using a double lambda scheme creating coherent population trapping in an atomic ensemble combined with pulsed optical radiations. The observation was made in a Cs vapor mixed with N{sub 2} buffer gas in a closed cell. The double lambda scheme is created with lin perpendicular lin polarized laser beams leading to higher contrast than the usual simple lambda scheme. The pulsed trapping technique leads to narrow fringe widths scaling as 1/(2T) with high contrasts which are no longer limited by the saturation effect. This technique operates in a different way from the classical Ramsey sequence: the signal is done by applying a long trapping pulse to prepare the atomic state superposition, and fringe detection is accomplished by optical transmission during a short second trapping pulse without any perturbation of the dark state.

  14. Study of electron trapping by a transversely ellipsoidal bubble in the laser wake-field acceleration

    SciTech Connect (OSTI)

    Cho, Myung-Hoon; Kim, Young-Kuk; Hur, Min Sup

    2013-09-15

    We present electron trapping in an ellipsoidal bubble which is not well explained by the spherical bubble model by [Kostyukov et al., Phys. Rev. Lett. 103, 175003 (2009)]. The formation of an ellipsoidal bubble, which is elongated transversely, frequently occurs when the spot size of the laser pulse is large compared to the plasma wavelength. First, we introduce the relation between the bubble size and the field slope inside the bubble in longitudinal and transverse directions. Then, we provide an ellipsoidal model of the bubble potential and investigate the electron trapping condition by numerical integration of the equations of motion. We found that the ellipsoidal model gives a significantly less restrictive trapping condition than that of the spherical bubble model. The trapping condition is compared with three-dimensional particle-in-cell simulations and the electron trajectory in test potential simulations.

  15. Subtask 4.27 - Evaluation of the Multielement Sorbent Trap (MEST...

    Office of Scientific and Technical Information (OSTI)

    an Illinois Coal-Fired Plant Citation Details In-Document Search Title: Subtask 4.27 - Evaluation of the Multielement Sorbent Trap (MEST) Method at an Illinois Coal-Fired Plant ...

  16. Light trapping in thin film solar cells using textured photonic crystal

    DOE Patents [OSTI]

    Yi, Yasha (Somerville, MA); Kimerling, Lionel C. (Concord, MA); Duan, Xiaoman (Amesbury, MA); Zeng, Lirong (Cambridge, MA)

    2009-01-27

    A solar cell includes a photoactive region that receives light. A photonic crystal is coupled to the photoactive region, wherein the photonic crystal comprises a distributed Bragg reflector (DBR) for trapping the light.

  17. Design and Performance of a High-Flux Electrospray Ionization Source for Ion Soft-Landing

    SciTech Connect (OSTI)

    Gunaratne, Kalupathirannehelage Don D.; Prabhakaran, Venkateshkumar; Ibrahim, Yehia M.; Norheim, Randolph V.; Johnson, Grant E.; Laskin, Julia

    2015-01-01

    We report the design and evaluation of a new high-intensity electrospray ionization source for ion soft-landing experiments. The source incorporates a dual ion funnel, which enables operation with a higher gas load through an expanded heated inlet into the additional first region of differential pumping. This capability allowed us to examine the effect of the inner diameter (ID) of the heated stainless steel inlet on the total ion current transmitted through the dual funnel interface and, more importantly, the mass-selected ion current delivered to the deposition target. The ion transmission of the dual funnel is similar to the transmission of the single funnel used in our previous soft landing studies. However, substantially higher ion currents were obtained using larger ID heated inlets and an orthogonal inlet geometry, in which the heated inlet is positioned perpendicular to the direction of ion propagation through the instrument. The highest ion currents were obtained using the orthogonal geometry and a 1.4 mm ID heated inlet. The corresponding stable deposition rate of ~1 μg of mass-selected ions per day will facilitate future studies focused on the controlled deposition of biological molecules on substrates and preparation of materials for studies in catalysis, energy storage, and self-assembly

  18. Twisted mass finite volume effects

    SciTech Connect (OSTI)

    Colangelo, Gilberto; Wenger, Urs; Wu, Jackson M. S.

    2010-08-01

    We calculate finite-volume effects on the pion masses and decay constant in twisted mass lattice QCD at finite lattice spacing. We show that the lighter neutral pion in twisted mass lattice QCD gives rise to finite-volume effects that are exponentially enhanced when compared to those arising from the heavier charged pions. We demonstrate that the recent two flavor twisted mass lattice data can be better fitted when twisted mass effects in finite-volume corrections are taken into account.

  19. Direct probing of electron and hole trapping into nano-floating-gate in organic field-effect transistor nonvolatile memories

    SciTech Connect (OSTI)

    Cui, Ze-Qun; Wang, Shun; Chen, Jian-Mei; Gao, Xu; Dong, Bin E-mail: chilf@suda.edu.cn Chi, Li-Feng E-mail: chilf@suda.edu.cn Wang, Sui-Dong E-mail: chilf@suda.edu.cn

    2015-03-23

    Electron and hole trapping into the nano-floating-gate of a pentacene-based organic field-effect transistor nonvolatile memory is directly probed by Kelvin probe force microscopy. The probing is straightforward and non-destructive. The measured surface potential change can quantitatively profile the charge trapping, and the surface characterization results are in good accord with the corresponding device behavior. Both electrons and holes can be trapped into the nano-floating-gate, with a preference of electron trapping than hole trapping. The trapped charge quantity has an approximately linear relation with the programming/erasing gate bias, indicating that the charge trapping in the device is a field-controlled process.

  20. Nanoscale mass conveyors

    DOE Patents [OSTI]

    Regan, Brian C. (Oakland, CA); Aloni, Shaul (Albany, CA); Zettl, Alexander K. (Kensington, CA)

    2008-03-11

    A mass transport method and device for individually delivering chargeable atoms or molecules from source particles is disclosed. It comprises a channel; at least one source particle of chargeable material fixed to the surface of the channel at a position along its length; a means of heating the channel; and a means for applying an controllable electric field along the channel, whereby the device transports the atoms or molecules along the channel in response to applied electric field. In a preferred embodiment, the mass transport device will comprise a multiwalled carbon nanotube (MWNT), although other one dimensional structures may also be used. The MWNT or other structure acts as a channel for individual or small collections of atoms due to the atomic smoothness of the material. Also preferred is a source particle of a metal such as indium. The particles move by dissociation into small units, in some cases, individual atoms. The particles are preferably less than 100 nm in size.