National Library of Energy BETA

Sample records for ion exchange technology

  1. Ion exchange technology assessment report

    SciTech Connect (OSTI)

    Duhn, E.F.

    1992-01-01

    In the execution of its charter, the SRS Ion Exchange Technology Assessment Team has determined that ion exchange (IX) technology has evolved to the point where it should now be considered as a viable alternative to the SRS reference ITP/LW/PH process. The ion exchange media available today offer the ability to design ion exchange processing systems tailored to the unique physical and chemical properties of SRS soluble HLW's. The technical assessment of IX technology and its applicability to the processing of SRS soluble HLW has demonstrated that IX is unquestionably a viable technology. A task team was chartered to evaluate the technology of ion exchange and its potential for replacing the present In-Tank Precipitation and proposed Late Wash processes to remove Cs, Sr, and Pu from soluble salt solutions at the Savannah River Site. This report documents the ion exchange technology assessment and conclusions of the task team.

  2. Ion exchange technology assessment report

    SciTech Connect (OSTI)

    Duhn, E.F.

    1992-12-31

    In the execution of its charter, the SRS Ion Exchange Technology Assessment Team has determined that ion exchange (IX) technology has evolved to the point where it should now be considered as a viable alternative to the SRS reference ITP/LW/PH process. The ion exchange media available today offer the ability to design ion exchange processing systems tailored to the unique physical and chemical properties of SRS soluble HLW`s. The technical assessment of IX technology and its applicability to the processing of SRS soluble HLW has demonstrated that IX is unquestionably a viable technology. A task team was chartered to evaluate the technology of ion exchange and its potential for replacing the present In-Tank Precipitation and proposed Late Wash processes to remove Cs, Sr, and Pu from soluble salt solutions at the Savannah River Site. This report documents the ion exchange technology assessment and conclusions of the task team.

  3. Vitrification of ion exchange materials. Innovative technology summary report

    SciTech Connect (OSTI)

    Not Available

    1999-07-01

    Ion exchange is a process that safely and efficiently removes radionuclides from tank waste. Cesium and strontium account for a large portion of the radioactivity in waste streams from US Department of Energy (DOE) weapons production. Crystalline silicotitanate (CST) is an inorganic sorbent that strongly binds cesium, strontium, and several other radionuclides. Developed jointly by Sandia National Laboratory and Texas A and M University, CST was commercialized through a cooperative research and development agreement with an industrial partner. Both an engineered (mesh pellets) and powdered forms are commercially available. Cesium removal is a baseline in HLW treatment processing. CST is very effective at removing cesium from HLW streams and is being considered for adoption at several sites. However, CST is nonregenerable, and it presents a significant secondary waste problem. Treatment options include vitrification of the CST, vitrification of the CST coupled with HLW, direct disposal, and low-temperature processes such as grouting. The work presented in this report demonstrates that it is effective to immobilize CST using a baseline technology such as vitrification. Vitrification produces a durable waste form. CST vitrification was not demonstrated before 1996. In FY97, acceptable glass formulations were developed using cesium-loaded CST obtained from treating supernatants from Oak Ridge Reservation (ORR) tanks, and the CST was vitrified in a research melter at the Savannah River Technology Center (SRTC). In FY98, SRS decided to reevaluate the use of in-tank precipitation using tetraphenylborate to remove cesium from tank supernatant and to consider other options for cesium removal, including CST. Hanford and Idaho National Engineering and Environmental Laboratory also require radionuclide removal in their baseline flowsheets.

  4. LITERATURE REVIEWS TO SUPPORT ION EXCHANGE TECHNOLOGY SELECTION FOR MODULAR SALT PROCESSING

    SciTech Connect (OSTI)

    King, W

    2007-11-30

    This report summarizes the results of literature reviews conducted to support the selection of a cesium removal technology for application in a small column ion exchange (SCIX) unit supported within a high level waste tank. SCIX is being considered as a technology for the treatment of radioactive salt solutions in order to accelerate closure of waste tanks at the Savannah River Site (SRS) as part of the Modular Salt Processing (MSP) technology development program. Two ion exchange materials, spherical Resorcinol-Formaldehyde (RF) and engineered Crystalline Silicotitanate (CST), are being considered for use within the SCIX unit. Both ion exchange materials have been studied extensively and are known to have high affinities for cesium ions in caustic tank waste supernates. RF is an elutable organic resin and CST is a non-elutable inorganic material. Waste treatment processes developed for the two technologies will differ with regard to solutions processed, secondary waste streams generated, optimum column size, and waste throughput. Pertinent references, anticipated processing sequences for utilization in waste treatment, gaps in the available data, and technical comparisons will be provided for the two ion exchange materials to assist in technology selection for SCIX. The engineered, granular form of CST (UOP IE-911) was the baseline ion exchange material used for the initial development and design of the SRS SCIX process (McCabe, 2005). To date, in-tank SCIX has not been implemented for treatment of radioactive waste solutions at SRS. Since initial development and consideration of SCIX for SRS waste treatment an alternative technology has been developed as part of the River Protection Project Waste Treatment Plant (RPP-WTP) Research and Technology program (Thorson, 2006). Spherical RF resin is the baseline media for cesium removal in the RPP-WTP, which was designed for the treatment of radioactive waste supernates and is currently under construction in Hanford, WA. Application of RF for cesium removal in the Hanford WTP does not involve in-riser columns but does utilize the resin in large scale column configurations in a waste treatment facility. The basic conceptual design for SCIX involves the dissolution of saltcake in SRS Tanks 1-3 to give approximately 6 M sodium solutions and the treatment of these solutions for cesium removal using one or two columns supported within a high level waste tank. Prior to ion exchange treatment, the solutions will be filtered for removal of entrained solids. In addition to Tanks 1-3, solutions in two other tanks (37 and 41) will require treatment for cesium removal in the SCIX unit. The previous SCIX design (McCabe, 2005) utilized CST for cesium removal with downflow supernate processing and included a CST grinder following cesium loading. Grinding of CST was necessary to make the cesium-loaded material suitable for vitrification in the SRS Defense Waste Processing Facility (DWPF). Because RF resin is elutable (and reusable) and processing requires conversion between sodium and hydrogen forms using caustic and acidic solutions more liquid processing steps are involved. The WTP baseline process involves a series of caustic and acidic solutions (downflow processing) with water washes between pH transitions across neutral. In addition, due to resin swelling during conversion from hydrogen to sodium form an upflow caustic regeneration step is required. Presumably, one of these basic processes (or some variation) will be utilized for MSP for the appropriate ion exchange technology selected. CST processing involves two primary waste products: loaded CST and decontaminated salt solution (DSS). RF processing involves three primary waste products: spent RF resin, DSS, and acidic cesium eluate, although the resin is reusable and typically does not require replacement until completion of multiple treatment cycles. CST processing requires grinding of the ion exchange media, handling of solids with high cesium loading, and handling of liquid wash and conditioning solutions. RF processing requires h

  5. Vehicle Technologies Office Merit Review 2015: Ion-Exchanged Derived Cathodes (IE-LL_NCM) for High Energy Density LIBs

    Broader source: Energy.gov [DOE]

    Presentation given by Argonne National Laboratory at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about ion-exchanged...

  6. Radiation Studies with Argentine Ion Exchange Material

    SciTech Connect (OSTI)

    Crawford, C.L.

    2002-06-28

    A recent technology exchange between Argentina Nuclear Energy Commission (CNEA) and the US Department of Energy involved vitrification studies of ion exchange resins. Details of the spent ion exchange resins currently stored at two Argentine nuclear power plants, Atucha I and Embalse, have been presented in earlier reports. The present study examines irradiation of simulant samples of ion exchange resins.

  7. Small Column Ion Exchange Technology at Savannah River Site | Department of

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LIST OF APPLICABLE DIRECTIVES PursuantEnergy Small Column Ion Exchange Technology

  8. Electrically Switched Cesium Ion Exchange

    SciTech Connect (OSTI)

    JPH Sukamto; ML Lilga; RK Orth

    1998-10-23

    This report discusses the results of work to develop Electrically Switched Ion Exchange (ESIX) for separations of ions from waste streams relevant to DOE site clean-up. ESIX combines ion exchange and electrochemistry to provide a selective, reversible method for radionuclide separation that lowers costs and minimizes secondary waste generation typically associated with conventional ion exchange. In the ESIX process, an electroactive ion exchange film is deposited onto. a high surface area electrode, and ion uptake and elution are controlled directly by modulating the potential of the film. As a result, the production of secondary waste is minimized, since the large volumes of solution associated with elution, wash, and regeneration cycles typical of standard ion exchange are not needed for the ESIX process. The document is presented in two parts: Part I, the Summary Report, discusses the objectives of the project, describes the ESIX concept and the approach taken, and summarizes the major results; Part II, the Technology Description, provides a technical description of the experimental procedures and in-depth discussions on modeling, case studies, and cost comparisons between ESIX and currently used technologies.

  9. Ion exchange phenomena

    SciTech Connect (OSTI)

    Bourg, I.C.; Sposito, G.

    2011-05-01

    Ion exchange phenomena involve the population of readily exchangeable ions, the subset of adsorbed solutes that balance the intrinsic surface charge and can be readily replaced by major background electrolyte ions (Sposito, 2008). These phenomena have occupied a central place in soil chemistry research since Way (1850) first showed that potassium uptake by soils resulted in the release of an equal quantity of moles of charge of calcium and magnesium. Ion exchange phenomena are now routinely modeled in studies of soil formation (White et al., 2005), soil reclamation (Kopittke et al., 2006), soil fertilitization (Agbenin and Yakubu, 2006), colloidal dispersion/flocculation (Charlet and Tournassat, 2005), the mechanics of argillaceous media (Gajo and Loret, 2007), aquitard pore water chemistry (Tournassat et al., 2008), and groundwater (Timms and Hendry, 2007; McNab et al., 2009) and contaminant hydrology (Chatterjee et al., 2008; van Oploo et al., 2008; Serrano et al., 2009).

  10. Small Column Ion Exchange at Savannah River Site Technology Readiness Assessment Report

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LIST OF APPLICABLE DIRECTIVES PursuantEnergy Small Column Ion Exchange

  11. Technology Performance Exchange

    SciTech Connect (OSTI)

    2015-09-01

    To address the need for accessible, high-quality data, the Department of Energy has developed the Technology Performance Exchange (TPEx). TPEx enables technology suppliers, third-party testing laboratories, and other entities to share product performance data. These data are automatically transformed into a format that technology evaluators can easily use in their energy modeling assessments to inform procurement decisions.

  12. Continuous Bed Ion Exchange Column

    E-Print Network [OSTI]

    Lebendiker, Mario

    UNOTM Q&S Continuous Bed Ion Exchange Column Instruction Manual Catalog Numbers 720-0001, 720 with 5 column volumes of water. Elevated backpressures may occur when wash- ing with deionized water. Do

  13. Vitrification of ion exchange resins

    DOE Patents [OSTI]

    Cicero-Herman, Connie A. (Aiken, SC); Workman, Rhonda Jackson (North Augusta, SC)

    2001-01-01

    The present invention relates to vitrification of ion exchange resins that have become loaded with hazardous or radioactive wastes, in a way that produces a homogenous and durable waste form and reduces the disposal volume of the resin. The methods of the present invention involve directly adding borosilicate glass formers and an oxidizer to the ion exchange resin and heating the mixture at sufficient temperature to produce homogeneous glass.

  14. Phosphonic acid based ion exchange resins

    DOE Patents [OSTI]

    Horwitz, E. Philip (Naperville, IL); Alexandratos, Spiro D. (Knoxville, TN); Gatrone, Ralph C. (Naperville, IL); Chiarizia, Ronato (Oak Park, IL)

    1994-01-01

    An ion exchange resin for extracting metal ions from a liquid waste stream. An ion exchange resin is prepared by copolymerizing a vinylidene disphosphonic acid with styrene, acrylonitrile and divinylbenzene.

  15. Phosphonic acid based ion exchange resins

    DOE Patents [OSTI]

    Horwitz, E.P.; Alexandratos, S.D.; Gatrone, R.C.; Chiarizia, R.

    1996-07-23

    An ion exchange resin is described for extracting metal ions from a liquid waste stream. An ion exchange resin is prepared by copolymerizing a vinylidene diphosphonic acid with styrene, acrylonitrile and divinylbenzene. 10 figs.

  16. Phosphonic acid based ion exchange resins

    DOE Patents [OSTI]

    Horwitz, E. Philip (Naperville, IL); Alexandratos, Spiro D. (Knoxville, TN); Gatrone, Ralph C. (Naperville, IL); Chiarizia, Ronato (Oak Park, IL)

    1996-01-01

    An ion exchange resin for extracting metal ions from a liquid waste stream. An ion exchange resin is prepared by copolymerizing a vinylidene diphosphonic acid with styrene, acrylonitrile and divinylbenzene.

  17. Phosphonic acid based ion exchange resins

    DOE Patents [OSTI]

    Horwitz, E.P.; Alexandratos, S.D.; Gatrone, R.C.; Chiarizia, R.

    1994-01-25

    An ion exchange resin is described for extracting metal ions from a liquid waste stream. An ion exchange resin is prepared by copolymerizing a vinylidene diphosphonic acid with styrene, acrylonitrile and divinylbenzene. 9 figures.

  18. Summary - Small Column Ion Exchange (SCIX)Technology at the SRS

    Office of Environmental Management (EM)

    technologies t cess for comple de the program ailed design. TR reports, please v govPagesExternal al Technical Review with projects and de cal risk reduction inc bases,...

  19. Separation Report No. 100 Ion Exchange

    E-Print Network [OSTI]

    Lebendiker, Mario

    ). Historically, the challenge for chromatographic resin manufactures has been to introduce a relatively thick ion-exchangeSeparation Report No. 100 TSK-GEL BioAssist® Series Ion Exchange Columns Table of Contents 1. Introduction 2 2. Basic Properties 2 2-1 Ion-Exchange Capacity and Pore Characteristics 2 2-2 Separation

  20. Ion exchange purification of scandium

    DOE Patents [OSTI]

    Herchenroeder, Laurie A. (Noblesville, IN); Burkholder, Harvey R. (Ames, IA)

    1990-10-23

    An improvement in purification of scandium through ion exchange chromatography is disclosed in which the oxidation potential of the eluting solution is altered by the addition of potassium chlorate or ammonium chloride so that removal of contaminants is encouraged. The temperature, pH and concentration of the eluent HEDTA are controlled in order to maintain the scandium in the column while minimizing dilution of the scandium band. Recovery of scandium is improved by pumping dilute scandium over the column prior to stripping the scandium and precipitation. This eliminates the HEDTA ion and other monovalent cations contaminating the scandium band. This method maximizes recovery of scandium while maintaining purity.

  1. Technology Performance Exchange (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2012-10-01

    This fact sheet, 'The Technology Performance Exchange' will be presented at the ET Summit, held at the Pasadena Convention Center on October 15-17, 2012. The Technology Performance Exchange will be a centralized, Web-based portal for finding and sharing energy performance data for commercial building technologies.

  2. Technology Performance Exchange

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Q3 Deliverable: Develop Site Workflows and Design Website Layout Q3 GoNo-Go DOE Decision Point: Passed Q1 Milestone: Develop Data Entry Forms Q2 Milestone: Release Technology...

  3. Modeling of Crystalline Silicotitanate Ion Exchange Columns

    SciTech Connect (OSTI)

    Walker, D.D.

    1999-03-09

    Non-elutable ion exchange is being considered as a potential replacement for the In-Tank Precipitation process for removing cesium from Savannah River Site (SRS) radioactive waste. Crystalline silicotitanate (CST) particles are the reference ion exchange medium for the process. A major factor in the construction cost of this process is the size of the ion exchange column required to meet product specifications for decontaminated waste. To validate SRS column sizing calculations, SRS subcontracted two reknowned experts in this field to perform similar calculations: Professor R. G. Anthony, Department of Chemical Engineering, Texas A&038;M University, and Professor S. W. Wang, Department of Chemical Engineering, Purdue University. The appendices of this document contain reports from the two subcontractors. Definition of the design problem came through several meetings and conference calls between the participants and SRS personnel over the past few months. This document summarizes the problem definition and results from the two reports.

  4. Cesium-specific phenolic ion exchange resin

    DOE Patents [OSTI]

    Bibler, Jane P. (Aiken, SC); Wallace, Richard M. (Aiken, SC)

    1995-01-01

    A phenolic, cesium-specific, cation exchange resin is prepared by neutralizing resorcinol with potassium hydroxide, condensing/polymerizing the resulting intermediate with formaldehyde, heat-curing the resulting polymer to effect cross-linking and grinding it to desired particle size for use. This resin will selectively and efficiently adsorb cesium ions in the presence of a high concentration of sodium ions with a low carbon to cesium ratio.

  5. Cesium-specific phenolic ion exchange resin

    DOE Patents [OSTI]

    Bibler, J.P.; Wallace, R.M.

    1995-08-15

    A phenolic, cesium-specific, cation exchange resin is prepared by neutralizing resorcinol with potassium hydroxide, condensing/polymerizing the resulting intermediate with formaldehyde, heat-curing the resulting polymer to effect cross-linking and grinding it to desired particle size for use. This resin will selectively and efficiently adsorb cesium ions in the presence of a high concentration of sodium ions with a low carbon to cesium ratio. 2 figs.

  6. Magnetic ion exchange: Is there potential for international development? 

    E-Print Network [OSTI]

    Neale, Peta A.; Schäfer, Andrea

    2009-01-01

    Magnetic ion exchange (MIEX®) is an ion exchange resin developed as an additive to existing water treatment plants where additional organic matter is to be removed. The smaller size, magnetic properties and simple ...

  7. PRTR ion exchange vault water removal

    SciTech Connect (OSTI)

    Ham, J.E.

    1995-11-01

    This report documents the removal of radiologically contaminated water from the Plutonium Recycle Test Reactor (PRTR) ion exchange vault. Approximately 57,000 liters (15,000 gallons) of water had accumulated in the vault due to the absence of a rain cover. The water was removed and the vault inspected for signs of leakage. No evidence of leakage was found. The removal and disposal of the radiologically contaminated water decreased the risk of environmental contamination.

  8. Ion-Exchangeable, Electronically Conducting Layered Perovskite Oxyfluorides

    E-Print Network [OSTI]

    Ion-Exchangeable, Electronically Conducting Layered Perovskite Oxyfluorides Yoji Kobayashi@chem.psu.edu Abstract: Cation-exchangeable d0 layered perovskites are amenable to intercalation, exfoliation of mixed-valent perovskites. Conversely, electronically and magnetically interesting layered perovskites

  9. Advanced Heat/Mass Exchanger Technology for Geothermal and solar...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    HeatMass Exchanger Technology for Geothermal and solar Renewable Energy Systems Advanced HeatMass Exchanger Technology for Geothermal and solar Renewable Energy Systems Advanced...

  10. TECHNICAL COMPARISON OF CANDIDATE ION EXCHANGE MEDIA FOR SMALL COLUMN ION EXCHANGE (SCIX) APPLICATIONS IN SUPPORT OF SUPPLEMENTAL LAW PRETREATMENT

    SciTech Connect (OSTI)

    RAMSEY AA; THORSON MR

    2010-12-28

    At-tank supplemental pretreatment including both filtration and small column ion exchange is currently under evaluation to facilitate salt waste retrieval and processing in the Hanford tank farms. Spherical resorcinol formaldehyde (sRF) resin is the baseline ion exchange resin for use in the Waste Treatment and Immobilization Plant (WTP). This document provides background and technical rationale to assist in determining whether spherical resorcinol formaldehyde (sRF) is also the appropriate ion exchange resin for supplemental LAW pretreatment processes and compares sRF with crystalline silicotitanate (CST) as potential supplemental pretreatment ion exchange media.

  11. Assessment of commercially available ion exchange materials for cesium removal from highly alkaline wastes

    SciTech Connect (OSTI)

    Brooks, K.P.; Kim, A.Y.; Kurath, D.E.

    1996-04-01

    Approximately 61 million gallons of nuclear waste generated in plutonium production, radionuclide removal campaigns, and research and development activities is stored on the Department of Energy`s Hanford Site, near Richland, Washington. Although the pretreatment process and disposal requirements are still being defined, most pretreatment scenarios include removal of cesium from the aqueous streams. In many cases, after cesium is removed, the dissolved salt cakes and supernates can be disposed of as LLW. Ion exchange has been a leading candidate for this separation. Ion exchange systems have the advantage of simplicity of equipment and operation and provide many theoretical stages in a small space. The organic ion exchange material Duolite{trademark} CS-100 has been selected as the baseline exchanger for conceptual design of the Initial Pretreatment Module (IPM). Use of CS-100 was chosen because it is considered a conservative, technologically feasible approach. During FY 96, final resin down-selection will occur for IPM Title 1 design. Alternate ion exchange materials for cesium exchange will be considered at that time. The purpose of this report is to conduct a search for commercially available ion exchange materials which could potentially replace CS-100. This report will provide where possible a comparison of these resin in their ability to remove low concentrations of cesium from highly alkaline solutions. Materials which show promise can be studied further, while less encouraging resins can be eliminated from consideration.

  12. MODELING RESULTS FROM CESIUM ION EXCHANGE PROCESSING WITH SPHERICAL RESINS

    SciTech Connect (OSTI)

    Nash, C.; Hang, T.; Aleman, S.

    2011-01-03

    Ion exchange modeling was conducted at the Savannah River National Laboratory to compare the performance of two organic resins in support of Small Column Ion Exchange (SCIX). In-tank ion exchange (IX) columns are being considered for cesium removal at Hanford and the Savannah River Site (SRS). The spherical forms of resorcinol formaldehyde ion exchange resin (sRF) as well as a hypothetical spherical SuperLig{reg_sign} 644 (SL644) are evaluated for decontamination of dissolved saltcake wastes (supernates). Both SuperLig{reg_sign} and resorcinol formaldehyde resin beds can exhibit hydraulic problems in their granular (nonspherical) forms. SRS waste is generally lower in potassium and organic components than Hanford waste. Using VERSE-LC Version 7.8 along with the cesium Freundlich/Langmuir isotherms to simulate the waste decontamination in ion exchange columns, spherical SL644 was found to reduce column cycling by 50% for high-potassium supernates, but sRF performed equally well for the lowest-potassium feeds. Reduced cycling results in reduction of nitric acid (resin elution) and sodium addition (resin regeneration), therefore, significantly reducing life-cycle operational costs. These findings motivate the development of a spherical form of SL644. This work demonstrates the versatility of the ion exchange modeling to study the effects of resin characteristics on processing cycles, rates, and cold chemical consumption. The value of a resin with increased selectivity for cesium over potassium can be assessed for further development.

  13. Standard practice for the ion exchange separation of uranium and plutonium prior to isotopic analysis

    E-Print Network [OSTI]

    American Society for Testing and Materials. Philadelphia

    2008-01-01

    Standard practice for the ion exchange separation of uranium and plutonium prior to isotopic analysis

  14. ION EXCHANGE PERFORMANCE OF TITANOSILICATES, GERMANATES AND CARBON NANOTUBES

    SciTech Connect (OSTI)

    Alsobrook, A.; Hobbs, D.

    2013-04-24

    This report presents a summary of testing the affinity of titanosilicates (TSP), germanium-substituted titanosilicates (Ge-TSP) and multiwall carbon nanotubes (MWCNT) for lanthanide ions in dilute nitric acid solution. The K-TSP ion exchanger exhibited the highest affinity for lanthanides in dilute nitric acid solutions. The Ge-TSP ion exchanger shows promise as a material with high affinity, but additional tests are needed to confirm the preliminary results. The MWCNT exhibited much lower affinities than the K-TSP in dilute nitric acid solutions. However, the MWCNT are much more chemically stable to concentrated nitric acid solutions and, therefore, may candidates for ion exchange in more concentrated nitric acid solutions. This technical report serves as the deliverable documenting completion of the FY13 research milestone, M4FT-13SR0303061 – measure actinide and lanthanide distribution values in nitric acid solutions with sodium and potassium titanosilicate materials.

  15. Waste treatment by ion-exchange. (Latest citations from Pollution abstracts). Published Search

    SciTech Connect (OSTI)

    NONE

    1995-09-01

    The bibliography contains citations concerning wastewater treatment by ion-exchange techniques. Methods for removing metals, nitrates, phosphates, fluorides, and organic pollutants are described. Applications of this technology to the electroplating, metal finishing, pulp, paper, and other industries are included. The citations examine the commercial feasibility of using ion-exchange methods for pollutant reduction when the process is used alone or in combination with various pretreatment techniques. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  16. Waste treatment by ion-exchange. (Latest citations from Pollution abstracts). Published Search

    SciTech Connect (OSTI)

    NONE

    1996-10-01

    The bibliography contains citations concerning wastewater treatment by ion-exchange techniques. Methods for removing metals, nitrates, phosphates, fluorides, and organic pollutants are described. Applications of this technology to the electroplating, metal finishing, pulp, paper, and other industries are included. The citations examine the commercial feasibility of using ion-exchange methods for pollutant reduction when the process is used alone or in combination with various pretreatment techniques. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

  17. Summary of Testing of SuperLig 639 at the TFL Ion Exchange Facility

    SciTech Connect (OSTI)

    Steimke, J.L.

    2000-12-19

    A pilot scale facility was designed and built in the Thermal Fluids Laboratory at the Savannah River Technology Center to test ion exchange resins for removing technetium and cesium from simulated Hanford Low Activity Waste (LAW). The facility supports the design of the Hanford River Protection Project for BNFL, Inc. The pilot scale system mimics the full-length of the columns and the operational scenario of the planned ion exchange system. Purposes of the testing include confirmation of the design, evaluation of methods for process optimization and developing methods for waste volume minimization. This report documents the performance of the technetium removal resin.

  18. RESORCINOL-FORMALDEHYDE ION EXCHANGE RESIN CHEMISTRY FOR HIGH LEVEL WASTE TREATMENT

    SciTech Connect (OSTI)

    Nash, C.; Duignan, M.

    2010-01-14

    A principal goal at the Savannah River Site is to safely dispose of the large volume of liquid nuclear waste held in many storage tanks. In-tank ion exchange technology is being considered for cesium removal using a polymer resin made of resorcinol formaldehyde that has been engineered into microspheres. The waste under study is generally lower in potassium and organic components than Hanford waste; therefore, the resin performance was evaluated with actual dissolved salt waste. The ion exchange performance and resin chemistry results are discussed.

  19. Perchlorate Degradation Using Partially Oxidized Titanium Ions and Ion Exchange Membrane Hybrid System 

    E-Print Network [OSTI]

    Park, Sung Hyuk

    2011-08-08

    + and Ti3+) in solutions and as part of an ion exchange membrane reactor system. Aqueous titanium ions (Ti2+ and Ti3+) were applied to remove perchlorate ions and its destructive mechanism, reaction kinetics, and the effect of environmental factors were...

  20. Ion extraction and charge exchange in laser isotope separation

    SciTech Connect (OSTI)

    Hostein, D.; Doneddu, F.

    1996-02-01

    In the atomic vapor laser isotope separation (AVLIS) process, a vapor is ionized by pulsed laser beams, and the ions are extracted by negatively biased collectors. The authors compute the unsteady dynamics of the photoplasma using a two-dimensional (2-D) particle-in-cell (PIC) code. Collisions between ions and neutral species are simulated by a Monte Carlo technique. The plasma dynamics is visualized by snapshots of particle positions showing the directions of their velocities. The three kinds of particles (electrons, photo-ions, and ions created by charge exchange) are marked by different colors. The graphic outputs illustrate the motion of the electrons toward the anodes, the vertical drift of the plasma, its erosion by the transient ion sheath, and nonselective ionization by charge exchange.

  1. Cementation of residue ion exchange resins at Rocky Flats

    SciTech Connect (OSTI)

    Dustin, D.F.; Beckman, T.D.; Madore, C.M.

    1998-03-03

    Ion exchange resins have been used to purify nitric acid solutions of plutonium at Rocky Flats since the 1950s. Spent ion exchange resins were retained for eventual recovery of residual plutonium, typically by incineration followed by the aqueous extraction of plutonium from the resultant ash. The elimination of incineration as a recovery process in the late 1980s and the absence of a suitable alternative process for plutonium recovery from resins led to a situation where spent ion exchange resins were simply placed into temporary storage. This report describes the method that Rocky Flats is currently using to stabilize residue ion exchange resins. The objective of the resin stabilization program is: (1) to ensure their safety during interim storage at the site, and (2) to prepare them for ultimate shipment to the Waste Isolation Pilot Plant (WIPP) in New Mexico. Included in the discussion is a description of the safety concerns associated with ion exchange resins, alternatives considered for their stabilization, the selection of the preferred treatment method, the means of implementing the preferred option, and the progress to date.

  2. Ion exchange polymers for anion separations

    DOE Patents [OSTI]

    Jarvinen, G.D.; Marsh, S.F.; Bartsch, R.A.

    1997-09-23

    Anion exchange resins including at least two positively charged sites and a well-defined spacing between the positive sites are provided together with a process of removing anions or anionic metal complexes from aqueous solutions by use of such resins. The resins can be substituted poly(vinylpyridine) and substituted polystyrene.

  3. Ion exchange polymers for anion separations

    DOE Patents [OSTI]

    Jarvinen, Gordon D. (Los Alamos, NM); Marsh, S. Fredric (Los Alamos, NM); Bartsch, Richard A. (Lubbock, TX)

    1997-01-01

    Anion exchange resins including at least two positively charged sites and a ell-defined spacing between the positive sites are provided together with a process of removing anions or anionic metal complexes from aqueous solutions by use of such resins. The resins can be substituted poly(vinylpyridine) and substituted polystyrene.

  4. Catalysis using hydrous metal oxide ion exchangers

    DOE Patents [OSTI]

    Dosch, R.G.; Stephens, H.P.; Stohl, F.V.

    1983-07-21

    In a process which is catalyzed by a catalyst comprising an active metal on a carrier, said metal being active as a catalyst for the process, an improvement is provided wherein the catalyst is a hydrous, alkali metal or alkaline earth metal titanate, zirconate, niobate or tantalate wherein alkali or alkaline earth metal cations have been exchanged with a catalytically effective amount of cations of said metal.

  5. Modeling Uranium-Proton Ion Exchange in Biosorption

    E-Print Network [OSTI]

    Volesky, Bohumil

    Modeling Uranium-Proton Ion Exchange in Biosorption J I N B A I Y A N G A N D B O H U M I L V O L E, Quebec, Canada H3A 2B2 Biosorption of uranium metal ions by a nonliving protonated Sargassum fluitans seaweed biomass was used to remove the heavy metal uranium from the aqueous solution. Uranium biosorption

  6. Information systems to enhance technology exchange

    SciTech Connect (OSTI)

    Hunter, T.; Harrington, M.; Harlan, C.; Drozhko, E.

    1994-03-01

    A fundamental part of international technology exchange is the compilation and dissemination of information. Worldwide environmental problems and technology development activities form the basis for important opportunities across the world and especially for those in the former Soviet Union. Recently, important agreements have been reached among Russian institutes engaged in environmental work and the US Department of Energy (DOE) and its national laboratories. These agreements will allow a systematic compilation of information on environmental contamination problems in Russia that can be included in DOE`s environmental information systems. A computer hardware and software system has been loaned to Russian scientists by the DOE for the sharing of environmental software and data, while establishing standards for future information networks.

  7. Thermal Analysis for Ion-Exchange Column System

    SciTech Connect (OSTI)

    Lee, Si Y.; King, William D.

    2012-12-20

    Models have been developed to simulate the thermal characteristics of crystalline silicotitanate ion exchange media fully loaded with radioactive cesium either in a column configuration or distributed within a waste storage tank. This work was conducted to support the design and operation of a waste treatment process focused on treating dissolved, high-sodium salt waste solutions for the removal of specific radionuclides. The ion exchange column will be installed inside a high level waste storage tank at the Savannah River Site. After cesium loading, the ion exchange media may be transferred to the waste tank floor for interim storage. Models were used to predict temperature profiles in these areas of the system where the cesium-loaded media is expected to lead to localized regions of elevated temperature due to radiolytic decay. Normal operating conditions and accident scenarios (including loss of solution flow, inadvertent drainage, and loss of active cooling) were evaluated for the ion exchange column using bounding conditions to establish the design safety basis. The modeling results demonstrate that the baseline design using one central and four outer cooling tubes provides a highly efficient cooling mechanism for reducing the maximum column temperature. In-tank modeling results revealed that an idealized hemispherical mound shape leads to the highest tank floor temperatures. In contrast, even large volumes of CST distributed in a flat layer with a cylindrical shape do not result in significant floor heating.

  8. 1.17972 Fractoprep Ion Exchange chromatography (IEX)

    E-Print Network [OSTI]

    Lebendiker, Mario

    1.17972 Fractoprep® SO3 - Ion Exchange chromatography (IEX) Fractoprep® is a hydrophilic synthetic Sulfogroup (SO3)- Protein binding capacity ~ 100 mg lysozyme/ml of gel pH stability range pH 2 up to pH 14

  9. New PerfSONAR Updates Showcased at 2015 Technology Exchange

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    New PerfSONAR Updates Showcased at 2015 Technology Exchange News & Publications ESnet News Media & Press Publications and Presentations Galleries ESnet Awards and Honors Contact Us...

  10. Negative Joule Heating in Ion-Exchange Membranes

    E-Print Network [OSTI]

    P. M. Biesheuvel; D. Brogioli; H. V. M. Hamelers

    2014-02-06

    In ion-exchange membrane processes, ions and water flow under the influence of gradients in hydrostatic pressure, ion chemical potential, and electrical potential (voltage), leading to solvent flow, ionic fluxes and ionic current. At the outer surfaces of the membranes, electrical double layers (EDLs) are formed (Donnan layers). When a current flows through the membrane, we argue that besides the positive Joule heating in the bulk of the membrane and in the electrolyte outside the membrane, there is also negative Joule heating in one of the EDLs. We define Joule heating as the inner product of the two vectors current and field strength. Also when fluid flows through a charged membrane, at one side of the membrane there is pressure-related cooling, due to the osmotic and hydrostatic pressure differences across the EDLs.

  11. Negative Joule Heating in Ion-Exchange Membranes

    E-Print Network [OSTI]

    Biesheuvel, P M; Hamelers, H V M

    2014-01-01

    In ion-exchange membrane processes, ions and water flow under the influence of gradients in hydrostatic pressure, ion chemical potential, and electrical potential (voltage), leading to solvent flow, ionic fluxes and ionic current. At the outer surfaces of the membranes, electrical double layers (EDLs) are formed (Donnan layers). When a current flows through the membrane, we argue that besides the positive Joule heating in the bulk of the membrane and in the electrolyte outside the membrane, there is also negative Joule heating in one of the EDLs. We define Joule heating as the inner product of the two vectors current and field strength. Also when fluid flows through a charged membrane, at one side of the membrane there is pressure-related cooling, due to the osmotic and hydrostatic pressure differences across the EDLs.

  12. IMPACT OF THE SMALL COLUMN ION EXCHANGE PROCESS ON THE DEFENSE WASTE PROCESSING FACILITY - 12112

    SciTech Connect (OSTI)

    Koopman, D.; Lambert, D.; Fox, K.; Stone, M.

    2011-11-07

    The Savannah River Site (SRS) is investigating the deployment of a parallel technology to the Salt Waste Processing Facility (SWPF, presently under construction) to accelerate high activity salt waste processing. The proposed technology combines large waste tank strikes of monosodium titanate (MST) to sorb strontium and actinides with two ion exchange columns packed with crystalline silicotitanate (CST) resin to sorb cesium. The new process was designated Small Column Ion Exchange (SCIX), since the ion exchange columns were sized to fit within a waste storage tank riser. Loaded resins are to be combined with high activity sludge waste and fed to the Defense Waste Processing Facility (DWPF) for incorporation into the current glass waste form. Decontaminated salt solution produced by SCIX will be fed to the SRS Saltstone Facility for on-site immobilization as a grout waste form. Determining the potential impact of SCIX resins on DWPF processing was the basis for this study. Accelerated salt waste treatment is projected to produce a significant savings in the overall life cycle cost of waste treatment at SRS.

  13. Metal-ion recycle technology for metal electroplating waste waters

    SciTech Connect (OSTI)

    Sauer, N.N.; Smith, B.F.

    1993-06-01

    As a result of a collaboration with Boeing Aerospace, the authors have begun a program to identify suitable treatments or to develop new treatments for electroplating baths. The target baths are mixed-metal or alloy baths that are being integrated into the Boeing electroplating complex. These baths, which are designed to replace highly toxic chromium and cadmium baths, contain mixtures of two metals, either nickel-tungsten, nickel-zinc, or zinc-tin. This report reviews the literature and details currently available on emerging technologies that could affect recovery of metals from electroplating baths under development by Boeing Aerospace. This literature survey summarizes technologies relevant to the recovery of metals from electroplating processes. The authors expanded the scope to investigate single metal ion recovery technologies that could be applied to metal ion recovery from alloy baths. This review clearly showed that the electroplating industry has traditionally relied on precipitation and more recently on electrowinning as its waste treatment methods. Despite the almost ubiquitous use of precipitation to remove contaminant metal ions from waste electroplating baths and rinse waters, this technology is clearly no longer feasible for the electroplating industry for several reasons. First, disposal of unstabilized sludge is no longer allowed by law. Second, these methods are no longer adequate as metal-removal techniques because they cannot meet stringent new metal discharge limits. Third, precious resources are being wasted or discarded because these methods do not readily permit recovery of the target metal ions. As a result, emerging technologies for metal recovery are beginning to see application to electroplating waste recycle. This report summarizes current research in these areas. Included are descriptions of various membrane technologies, such as reverse osmosis and ultrafiltration, ion exchange and chelating polymer technology, and electrodialysis.

  14. Nonlinear inverse problem for a model of ion-exchange filter: numerical recovery of parameters

    E-Print Network [OSTI]

    methods of ion exchange is based on passing of source water or partially treated water through a filter-exchange filters results in highly mineralized, acidic and alkaline waste water [9]. With the continuous1 Nonlinear inverse problem for a model of ion-exchange filter: numerical recovery of parameters

  15. Ion Exchange Testing with SRF Resin FY2012

    SciTech Connect (OSTI)

    Russell, Renee L.; Rinehart, Donald E.; Peterson, Reid A.

    2013-06-11

    Ion exchange using spherical resorcinol-formaldehyde (SRF) resin has been selected by the U.S. Department of Energy’s Office of River Protection (DOE-ORP) for use in the Pretreatment Facility (PTF) of the Hanford Tank Waste Treatment and Immobilization Plant (WTP) and for potential application in at-tank deployment. Numerous studies have shown SRF resin to be effective for removing 137Cs from a wide variety of actual and simulated tank waste supernatants (Adamson et al. 2006; Blanchard et al. 2008; Burgeson et al. 2004; Duignan and Nash 2009; Fiskum et al. 2006a; Fiskum et al. 2006b; Fiskum et al. 2006c; Fiskum et al. 2007; Hassan and Adu-Wusu 2003; King et al. 2004; Nash et al. 2006). Prior work at the Pacific Northwest National Laboratory (PNNL) has focused primarily on the loading behavior for 4 to 6 M Na solutions at 25 to 45°C. Recent proposed changes to the WTP ion exchange process baseline indicate that loading may include a broader range of sodium molarities (0.1 to 8 M) and higher temperatures (50°C) to alleviate post-filtration precipitation issues. This report discusses ion exchange loading kinetics testing activities performed in accordance with Test Plan TP-WTPSP-002, Rev. 3.0 , which was prepared and approved in response to the Test Specification 24590 PTF-TSP-RT-09-002, Rev. 0 (Lehrman 2010) and Test Exception 24590 PTF TEF RT-11-00003, Rev. 0 (Meehan 2011). This testing focused on column tests evaluating the impact of elevated temperature on resin degradation over an extended period of time and batch contacts evaluating the impact on Cs loading over a broad range of sodium concentrations (0.1 to 5 M). These changes may be required to alleviate post-filtration precipitation issues and broaden the data range of SRF resin loading under the conditions expected with the new equipment and process changes.

  16. Ion Exchange Testing with SRF Resin FY 2012

    SciTech Connect (OSTI)

    Russell, Renee L.; Rinehart, Donald E.; Peterson, Reid A.

    2014-07-02

    Ion exchange using spherical resorcinol-formaldehyde (SRF) resin has been selected by the U.S. Department of Energy’s Office of River Protection (DOE-ORP) for use in the Pretreatment Facility (PTF) of the Hanford Tank Waste Treatment and Immobilization Plant (WTP) and for potential application in at-tank deployment. Numerous studies have shown SRF resin to be effective for removing 137Cs from a wide variety of actual and simulated tank waste supernatants (Adamson et al. 2006; Blanchard et al. 2008; Burgeson et al. 2004; Duignan and Nash 2009; Fiskum et al. 2006a; Fiskum et al. 2006b; Fiskum et al. 2006c; Fiskum et al. 2007; Hassan and Adu-Wusu 2003; King et al. 2004; Nash et al. 2006). Prior work at the Pacific Northwest National Laboratory (PNNL) has focused primarily on the loading behavior for 4 to 6 M Na solutions at 25 to 45°C. Recent proposed changes to the WTP ion exchange process baseline indicate that loading may include a broader range of sodium molarities (0.1 to 8 M) and higher temperatures (50°C) to alleviate post-filtration precipitation issues. This report discusses ion exchange loading kinetics testing activities performed in accordance with Test Plan TP-WTPSP-002, Rev. 3.01, which was prepared and approved in response to the Test Specification 24590-PTF-TSP-RT-09-002, Rev. 0 (Lehrman 2010) and Test Exception 24590-PTF-TEF-RT-11-00003, Rev. 0 (Meehan 2011). This testing focused on column tests evaluating the impact of elevated temperature on resin degradation over an extended period of time and batch contacts evaluating the impact on Cs loading over a broad range of sodium concentrations (0.1 to 5 M). These changes may be required to alleviate post-filtration precipitation issues and broaden the data range of SRF resin loading under the conditions expected with the new equipment and process changes.

  17. Water softening by single-bowl ion exchange filter efficiency estimate and improvement

    E-Print Network [OSTI]

    Kostygin, V A; Kochetov, G M; Tugay, A M; Vashchenko, V N

    2014-01-01

    The article presents results of experimental investigations of the water softener in a laboratory installation of uninterruptible countercurrent ion exchange filter, which has a movable layer of ion exchange material. The installation provides for two simultaneous processes: counter ion sorption and regeneration of the sorbent with the processing capability of the sorbent in the regeneration zone by ultrasonic radiation.

  18. Data quality objectives for Ion Exchange Module (IXM) disposition

    SciTech Connect (OSTI)

    Choi, I.

    1995-01-31

    This Data Quality Objective (DQO) document presents the data needs and accuracy requirements for sampling ion exchange modules at the K Basins, 100 K Area, to determine if there is a hydrogen gas buildup within the modules. This document was produced by PNL, with the assistance of Neptune and Associates, and was partly funded (for facilitator) by DOE-HQ as a demonstration DQO for EM activities. PNL involved a number of PNL, WHC and support contract staff (including external technical consultants) in meetings to define the data needed, along with the necessary accuracy, to resolve issues associated with hydrogen accumulation in Ion Exchange Modules (IXMS) that were generated prior to July 1994 and only have one nuc-fil vent. IXMs generated after July 1994 have multiple nuc-fil vents and do not require sampling. PNL transmitted this DQO to WHC on January 31, 1995. This Supporting Document is to assure that the document is captured into the document retrieval system. WHC review focused on the acceptability of the technical conclusions such that the data collected will meet minimum operational, safety and environmental needs.

  19. Studies of Ion Exchange Resin Integrity under Flowsheet Extremes: Part II

    SciTech Connect (OSTI)

    Nash, C.A.

    2002-12-19

    This task addressed four items related to SuperLig(R) 644 ion exchange resin stability under nominal to extreme conditions.

  20. Recent advances in lithium ion technology

    SciTech Connect (OSTI)

    Levy, S.C.

    1995-01-01

    Lithium ion technology is based on the use of lithium intercalating electrodes. Carbon is the most commonly used anode material, while the cathode materials of choice have been layered lithium metal chalcogenides (LiMX{sub 2}) and lithium spinel-type compounds. Electrolytes may be either organic liquids or polymers. Although the first practical use of graphite intercalation compounds as battery anodes was reported in 1981 for molten salt cells (1) and in 1983 for ambient temperature systems (2) it was not until Sony Energytech announced a new lithium ion rechargeable cell containing a lithium ion intercalating carbon anode in 1990, that interest peaked. The reason for this heightened interest is that these cells have the high energy density, high voltage and fight weight of metallic lithium systems plus a very long cycle life, but without the disadvantages of dendrite formation on charge and the safety considerations associated with metallic lithium.

  1. Determination of Method Detection Limits for Trace 232-Thorium and 238-Uranium in Copper using Ion Exchange and ICPMS

    SciTech Connect (OSTI)

    Hoppe, Eric W.; LaFerriere, Brian D.; Maiti, Tapas C.; Soin, Aleksandr

    2014-04-15

    Determination of Method Detection Limits for Trace 232-Thorium and 238-Uranium in Copper using Ion Exchange and ICPMS

  2. Technology transfer personnel exchange at the Boeing Company

    SciTech Connect (OSTI)

    Antoniak, Z.I.

    1993-03-01

    The objective of the exchange was to transfer Pacific Northwest Laboratory (PNL) technology and expertise in advanced ceramic fabric composites (ACFC) to the Boeing Defense Space Group (Boeing Aerospace). Boeing Aerospace was especially interested in applying PNL-developed ACFC technology to its current and future spacecraft and space missions. Boeing has on-going independent research and development (R D) programs on advanced radiators and heat pipes, therefore, PNL research in ceramic fabric heat pipes was of particular interest to Boeing. Thus, this exchange assisted in the transfer of PNL's ACFC heat pipe technology and other, related research capabilities to private industrial application. The project was proposed as an initial step in building a long-term collaborative relationship between Boeing and PNL that may result in future Cooperative Research and Development Agreements (CRADAs) and/or other types of collaborative efforts.

  3. Technology transfer personnel exchange at the Boeing Company

    SciTech Connect (OSTI)

    Antoniak, Z.I.

    1993-03-01

    The objective of the exchange was to transfer Pacific Northwest Laboratory (PNL) technology and expertise in advanced ceramic fabric composites (ACFC) to the Boeing Defense & Space Group (Boeing Aerospace). Boeing Aerospace was especially interested in applying PNL-developed ACFC technology to its current and future spacecraft and space missions. Boeing has on-going independent research and development (R&D) programs on advanced radiators and heat pipes, therefore, PNL research in ceramic fabric heat pipes was of particular interest to Boeing. Thus, this exchange assisted in the transfer of PNL`s ACFC heat pipe technology and other, related research capabilities to private industrial application. The project was proposed as an initial step in building a long-term collaborative relationship between Boeing and PNL that may result in future Cooperative Research and Development Agreements (CRADAs) and/or other types of collaborative efforts.

  4. Ion Exchange and Solvent Extraction: Supramolecular Aspects of Solvent Exchange Volume 21

    SciTech Connect (OSTI)

    Gloe, Karsten [Technischen Universität Dresden] [Technischen Universität Dresden; Tasker, Peter A [ORNL] [ORNL; Oshima, Tatsuya [University of Miyazaki] [University of Miyazaki; Watarai, Hitoshi [Institute for NanoScience Design at Osaka University] [Institute for NanoScience Design at Osaka University; Nilsson, Mikael [University of California, Irvine] [University of California, Irvine

    2013-01-01

    Preface The theme of supramolecular chemistry (SC), entailing the organization of multiple species through noncovalent interactions, has permeated virtually all aspects of chemical endeavor over the past several decades. Given that the observed behavior of discrete molecular species depends upon their weak interactions with one another and with matrix components, one would have to conclude that SC must indeed form part of the fabric of chemistry itself. A vast literature now serves to categorize SC phenomena within a body of consistent terminology. The word supramolecular itself appears in the titles of dozens of books, several journals, and a dedicated encyclopedia. Not surprisingly, the theme of SC also permeates the field of solvent extraction (SX), inspiring the framework for this volume of Ion Exchange and Solvent Extraction. It is attempted in the six chapters of this volume to identify both how supramolecular behavior occurs and is studied in the context of SX and how SC is influencing the current direction of SX. Researchers and practitioners have long dealt with supramolecular interactions in SX. Indeed, the use of polar extractant molecules in nonpolar media virtually assures that aggregative interactions will dominate the solution behavior of SX. Analytical chemists working in the 1930s to the 1950s with simple mono- and bidentate chelating ligands as extractants noted that extraction of metal ions obeyed complicated mass-action equilibria involving complex stoichiometries. As chemists and engineers developed processes for nuclear and hydrometallurgical applications in the 1950s and 1960s, the preference for aliphatic diluents only enhanced the complexity and supramolecular nature of extraction chemistry. Use of physical techniques such as light scattering and vapor-pressure measurements together with various spectroscopic methods revealed organic-phase aggregates from well-defined dimers to small aggregates containing a few extractant molecules to large inverse micelles swollen with water molecules. Extraction systems involving long-chain cations such as alkylammonium species or long-chain anions such as sulfonates or carboxylates proved especially prone to extensive aggregate formation. The related phenomenon of third-phase formation in SX systems, long misunderstood, is now yielding to spectroscopic and scattering techniques showing extensive long-range organization. Over the last 50 years, tools for studying the structure and thermodynamics of aggregation have grown increasingly sophisticated, leading to a rich and detailed understanding of what we can now recognize as SC phenomena in SX. In the 1970s and 1980s, the rapid growth of SC elicited a paradigm shift in SX. The influence of SC principles had two major effects on the course of SX research. First, it provided a framework for understanding the supramolecular behavior that was already well appreciated in the field of SX, though earlier without the SC terminology. Second, it provided the conceptual tools to control supramolecular behavior in SX, direct it for intended functionality, and to simplify it. Extraction by designed reagents has been steadily progressing ever since, with commercial applications emerging to successfully validate this approach. With the discovery of crown ethers in the late 1960s, the advancement of extractant design has fruitfully employed the concept of inclusion. While considerable initial progress occurred with such molecules, especially because of their affinity and selectivity for alkali and alkaline earth metals, other molecular platforms such as calixarenes have proven more versatile. Multidentate receptors for partial to full inclusion of cations, anions, ion pairs, as well as neutral species, have now become commonplace for selective extraction. This volume of Ion Exchange and Solvent Extraction examines how the principles of SC are being employed both in advancing the design of new highly selective SX systems and in understanding aggregation phenomena in SX systems. Chapter 1 discusses the nature and definition of SC

  5. Synthesis and Evaluation of Cu-SAPO-34 Catalysts for Ammonia Selective Catalytic Reduction. 1. Aqueous Solution Ion Exchange

    SciTech Connect (OSTI)

    Gao, Feng; Walter, Eric D.; Washton, Nancy M.; Szanyi, Janos; Peden, Charles HF

    2013-09-06

    SAPO-34 molecular sieves are synthesized using various structure directing agents (SDAs). Cu-SAPO-34 catalysts are prepared via aqueous solution ion exchange. Catalysts are characterized with surface area/pore volume measurements, temperature programmed reduction (TPR), electron paramagnetic resonance (EPR) and nuclear magnetic resonance (NMR) spectroscopies. Catalytic properties are examined using standard ammonia selective catalytic reduction (NH3-SCR) and ammonia oxidation reactions. During solution ion exchange, different SAPO-34 samples undergo different extent of structural damage via irreversible hydrolysis. Si content within the samples (i.e., Al-O-Si bond density) and framework stress are key factors that affect irreversible hydrolysis. Even using very dilute Cu acetate solutions, it is not possible to generate Cu-SAPO-34 samples with only isolated Cu2+ ions. Small amounts of CuOx species always coexist with isolated Cu2+ ions. Highly active and selective Cu-SAPO-34 catalysts for NH3-SCR are readily generated using this synthesis protocol, even for SAPO-34 samples that degrade substantially during solution ion exchange. High-temperature aging is found to improve the catalytic performance. This is likely due to reduction of intracrystalline mass-transfer limitations via formation of additional porosity in the highly defective SAPO-34 particles formed after ion exchange. The authors gratefully acknowledge the US Department of Energy (DOE), Office of Energy Efficiency and Renewable Energy, Office of Vehicle Technologies for the support of this work. The research described in this paper was performed at the Environmental Molecular Sciences Laboratory (EMSL), a national scientific user facility sponsored by the DOE’s Office of Biological and Environmental Research and located at Pacific Northwest National Laboratory (PNNL). PNNL is operated for the US DOE by Battelle Memorial Institute under contract number DE-AC05-76RL01830.

  6. Investigating the Use of Ion Exchange Resins for Processing Biodiesel Feedstocks 

    E-Print Network [OSTI]

    Jamal, Yousuf 1973-

    2012-11-27

    at a larger market share within the existing US economy. Alternative feedstocks must also be examined for their ability to produce biodiesel and additional recoverable organics. Use of ion exchange resins under low temperature and pressure...

  7. Experimental Ion Exchange Column With SuperLig 639 And Simulant Formulation

    SciTech Connect (OSTI)

    Morse, Megan; Nash, C.

    2013-08-26

    SuperLig®639 ion exchange resin was tested as a retrieval mechanism for pertechnetate, through decontamination of a perrhenate spiked 5M Simple Average Na{sup +} Mass Based Simulant. Testing included batch contacts and a three-column ion exchange campaign. A decontamination of perrhenate exceeding 99% from the liquid feed was demonstrated. Analysis of the first formulation of a SBS/WESP simulant found unexpectedly low concentrations of soluble aluminum. Follow-on work will complete the formulation.

  8. High Level Waste System Impacts from Small Column Ion Exchange Implementation

    SciTech Connect (OSTI)

    McCabe, D. J.; Hamm, L. L.; Aleman, S. E.; Peeler, D. K.; Herman, C. C.; Edwards, T. B.

    2005-08-18

    The objective of this task is to identify potential waste streams that could be treated with the Small Column Ion Exchange (SCIX) and perform an initial assessment of the impact of doing so on the High-Level Waste (HLW) system. Design of the SCIX system has been performed as a backup technology for decontamination of High-Level Waste (HLW) at the Savannah River Site (SRS). The SCIX consists of three modules which can be placed in risers inside underground HLW storage tanks. The pump and filter module and the ion exchange module are used to filter and decontaminate the aqueous tank wastes for disposition in Saltstone. The ion exchange module contains Crystalline Silicotitanate (CST in its engineered granular form is referred to as IONSIV{reg_sign} IE-911), and is selective for removal of cesium ions. After the IE-911 is loaded with Cs-137, it is removed and the column is refilled with a fresh batch. The grinder module is used to size-reduce the cesium-loaded IE-911 to make it compatible with the sludge vitrification system in the Defense Waste Processing Facility (DWPF). If installed at the SRS, this SCIX would need to operate within the current constraints of the larger HLW storage, retrieval, treatment, and disposal system. Although the equipment has been physically designed to comply with system requirements, there is also a need to identify which waste streams could be treated, how it could be implemented in the tank farms, and when this system could be incorporated into the HLW flowsheet and planning. This document summarizes a preliminary examination of the tentative HLW retrieval plans, facility schedules, decontamination factor targets, and vitrified waste form compatibility, with recommendations for a more detailed study later. The examination was based upon four batches of salt solution from the currently planned disposition pathway to treatment in the SCIX. Because of differences in capabilities between the SRS baseline and SCIX, these four batches were combined into three batches for a total of about 3.2 million gallons of liquid waste. The chemical and radiological composition of these batches was estimated from the SpaceMan Plus{trademark} model using the same data set and assumptions as the baseline plans.

  9. Ion-exchange material and method of storing radioactive wastes

    DOE Patents [OSTI]

    Komarneni, S.; Roy, D.M.

    1983-10-31

    A new cation exchanger is a modified tobermorite containing aluminum isomorphously substituted for silicon and containing sodium or potassium. The exchanger is selective for lead, rubidium, cobalt, and cadmium and is selective for cesium over calcium or sodium. The tobermorites are compatible with cement and are useful for the long-term fixation and storage of radioactive nuclear wastes.

  10. ROTARY FILTER FINES TESTING FOR SMALL COLUMN ION EXCHANGE

    SciTech Connect (OSTI)

    Herman, D.

    2011-08-03

    SRNL was requested to quantify the amount of 'fines passage' through the 0.5 micron membranes currently used for the rotary microfilter (RMF). Testing was also completed to determine if there is any additional benefit to utilizing a 0.1 micron filter to reduce the amount of fines that could pass through the filter. Quantifying of the amount of fines that passed through the two sets of membranes that were tested was accomplished by analyzing the filtrate by Inductively Coupled Plasma Atomic Emission Spectrometry (ICP-AES) for titanium. Even with preparations to isolate the titanium, all samples returned results of less than the instrument's detection limit of 0.184 mg/L. Test results show that the 0.5 micron filters produced a significantly higher flux while showing a negligible difference in filtrate clarity measured by turbidity. The first targeted deployment of the RMF is with the Small Column Ion Exchange (SCIX) at the Savannah River Site (SRS). SCIX uses crystalline silicotitanate (CST) to sorb cesium to decontaminate a clarified salt solution. The passage of fine particles through the filter membranes in sufficient quantities has the potential to impact the downstream facilities. To determine the amount of fines passage, a contract was established with SpinTek Filtration to operate a 3-disk pilot scale unit with prototypic filter disk and various feeds and two different filter disk membranes. SpinTek evaluated a set of the baseline 0.5 micron filter disks as well as a set of 0.1 micron filter disks to determine the amount of fine particles that would pass the membrane and to determine the flux each set produced. The membrane on both disk sets is manufactured by the Pall Corporation (PMM 050). Each set of disks was run with three feed combinations: prototypically ground CST, CST plus monosodium titanate (MST), and CST, MST, plus Sludge Batch 6 (SB6) simulant. Throughout the testing, samples of the filtrate were collected, measured for turbidity, and sent back to SRNL for analysis to quantify the amount of fines that passed through the membrane. It should be noted that even though ground CST was tested, it will be transferred to the Defense Waste Processing Facility (DWPF) feed tank and is not expected to require filtration.

  11. CHARACTERIZATION OF CYCLED SPHERICAL RESORCINOL-FORMALDEHYDE ION EXCHANGE RESIN

    SciTech Connect (OSTI)

    Nash, C.; Duignan, M.

    2010-02-23

    This report presents characterization data for two spherical resorcinol-formaldehyde (sRF) resin beds that had processed cesium in non-radioactive and radioactive cycles. All column cycle operations for the resin beds including loading, displacements, elution, regeneration, breakthroughs, and solution analyses are reported in Nash and Duignan, 2009a. That report covered four ion exchange (IX) campaigns using the two {approx}11 mL beds in columns in a lead-lag arrangement. The first two campaigns used Savannah River Site (SRS) Tank 2F nonradioactive simulant while the latter two were fed with actual dissolved salt in the Savannah River National Laboratory (SRNL) Shielded Cells. Both radioactive cycles ran to cesium breakthrough of the lead column. The resin beds saw in excess of 400 bed volumes of feed in each cycle. Resin disposal plans in tank farm processing depend on characterizations of resin used with actual tank feed. Following a final 30 bed volume (BV) elution with nitric acid, the resin beds were found to contain detectable chromium, barium, boron, aluminum, iron, sodium, sulfur, plutonium, cesium, and mercury. Resin affinity for plutonium is important in criticality safety considerations. Cesium-137 was found to be less than 10E+7 dpm/g of resin, similar to past work with sRF resin. Sulfur levels are reasonably consistent with other work and are expected to represent sulfur chemistry used in the resin manufacture. There were low but detectable levels of technetium, americium, and curium. Toxicity Characteristic Leaching Procedure (TCLP) work on the used (eluted) resin samples showed significant contents of mercury, barium, and chromium. One resin sample exceeded the TCLP level for mercury while the other metals were below TCLP levels. TCLP organics measurements indicated measurable benzene in one case, though the source was unknown. Results of this work were compared with other work on similar sRF resin characterizations in this report. This is the first work to quantify mercury on sRF resin. Resin mercury content is important in plans for the disposition of used sRF resin. Mercury speciation in high level waste (HLW) is unknown. It may be partly organic, one example being methyl mercury cation. Further study of the resin's affinity for mercury is recommended.

  12. Cement waste-form development for ion-exchange resins at the Rocky Flats Plant

    SciTech Connect (OSTI)

    Veazey, G.W.; Ames, R.L.

    1997-03-01

    This report describes the development of a cement waste form to stabilize ion-exchange resins at Rocky Flats Environmental Technology Site (RFETS). These resins have an elevated potential for ignition due to inadequate wetness and contact with nitrates. The work focused on the preparation and performance evaluation of several Portland cement/resin formulations. The performance standards were chosen to address Waste Isolation Pilot Plant and Environmental Protection Agency Resource Conservation and Recovery Act requirements, compatibility with Rocky Flats equipment, and throughput efficiency. The work was performed with surrogate gel-type Dowex cation- and anion-exchange resins chosen to be representative of the resin inventory at RFETS. Work was initiated with nonactinide resins to establish formulation ranges that would meet performance standards. Results were then verified and refined with actinide-containing resins. The final recommended formulation that passed all performance standards was determined to be a cement/water/resin (C/W/R) wt % ratio of 63/27/10 at a pH of 9 to 12. The recommendations include the acceptable compositional ranges for each component of the C/W/R ratio. Also included in this report are a recommended procedure, an equipment list, and observations/suggestions for implementation at RFETS. In addition, information is included that explains why denitration of the resin is unnecessary for stabilizing its ignitability potential.

  13. Enabling Detailed Energy Analyses via the Technology Performance Exchange: Preprint

    SciTech Connect (OSTI)

    Studer, D.; Fleming, K.; Lee, E.; Livingood, W.

    2014-08-01

    One of the key tenets to increasing adoption of energy efficiency solutions in the built environment is improving confidence in energy performance. Current industry practices make extensive use of predictive modeling, often via the use of sophisticated hourly or sub-hourly energy simulation programs, to account for site-specific parameters (e.g., climate zone, hours of operation, and space type) and arrive at a performance estimate. While such methods are highly precise, they invariably provide less than ideal accuracy due to a lack of high-quality, foundational energy performance input data. The Technology Performance Exchange was constructed to allow the transparent sharing of foundational, product-specific energy performance data, and leverages significant, external engineering efforts and a modular architecture to efficiently identify and codify the minimum information necessary to accurately predict product energy performance. This strongly-typed database resource represents a novel solution to a difficult and established problem. One of the most exciting benefits is the way in which the Technology Performance Exchange's application programming interface has been leveraged to integrate contributed foundational data into the Building Component Library. Via a series of scripts, data is automatically translated and parsed into the Building Component Library in a format that is immediately usable to the energy modeling community. This paper (1) presents a high-level overview of the project drivers and the structure of the Technology Performance Exchange; (2) offers a detailed examination of how technologies are incorporated and translated into powerful energy modeling code snippets; and (3) examines several benefits of this robust workflow.

  14. Decontamination of water using nitrate selective ion exchange resin

    DOE Patents [OSTI]

    Lockridge, J.E.; Fritz, J.S.

    1990-07-31

    A method for nitrate decontamination of water which involves passing the water through a bed of alkyl phosphonium anion exchange resin which has pendant alkyl groups of C[sub 3] or larger.

  15. The Ion-Exchange Separation of Zirconium and Hafnium

    E-Print Network [OSTI]

    Street, Kenneth Jr.; Seaborg, Glenn T.

    2008-01-01

    EXCHANGE SE~ARATION OF ZIRCONIUM AND HAFNIUM Kenneth street,containing "'0.1 percent zirconium oxide by weight. Thefective method of separating zirconium from hafnimu. In view

  16. Pressurized fluidized-bed combustion technology exchange workshop

    SciTech Connect (OSTI)

    ,

    1980-04-01

    The pressurized fluidized-bed combustion technology exchange workshop was held June 5 and 6, 1979, at The Meadowlands Hilton Hotel, Secaucus, New Jersey. Eleven papers have been entered individually into EDB and ERA. The papers include reviews of the US DOE and EPRI programs in this area and papers by Swedish, West German, British and American organizations. The British papers concern the joint program of the USA, UK and FRG at Leatherhead. The key factor in several papers is the use of fluidized bed combustors, gas turbines, and steam turbines in combined-cycle power plants. One paper examines several combined-cycle alternatives. (LTN)

  17. Liquid Salt Heat Exchanger Technology for VHTR Based Applications

    SciTech Connect (OSTI)

    Anderson, Mark; Sridhara, Kumar; Allen, Todd; Peterson, Per

    2012-10-11

    The objective of this research is to evaluate performance of liquid salt fluids for use as a heat carrier for transferring high-temperature process heat from the very high-temperature reactor (VHTR) to chemical process plants. Currently, helium is being considered as the heat transfer fluid; however, the tube size requirements and the power associated with pumping helium may not be economical. Recent work on liquid salts has shown tremendous potential to transport high-temperature heat efficiently at low pressures over long distances. This project has two broad objectives: To investigate the compatibility of Incoloy 617 and coated and uncoated SiC ceramic composite with MgCl2-KCl molten salt to determine component lifetimes and aid in the design of heat exchangers and piping; and, To conduct the necessary research on the development of metallic and ceramic heat exchangers, which are needed for both the helium-to-salt side and salt-to-process side, with the goal of making these heat exchangers technologically viable. The research will consist of three separate tasks. The first task deals with material compatibility issues with liquid salt and the development of techniques for on-line measurement of corrosion products, which can be used to measure material loss in heat exchangers. Researchers will examine static corrosion of candidate materials in specific high-temperature heat transfer salt systems and develop an in situ electrochemical probe to measure metallic species concentrations dissolved in the liquid salt. The second task deals with the design of both the intermediate and process side heat exchanger systems. Researchers will optimize heat exchanger design and study issues related to corrosion, fabrication, and thermal stresses using commercial and in-house codes. The third task focuses integral testing of flowing liquid salts in a heat transfer/materials loop to determine potential issues of using the salts and to capture realistic behavior of the salts in a small scale prototype system. This includes investigations of plugging issues, heat transfer, pressure drop, and the corrosion and erosion of materials in the flowing system.

  18. Improved hydrous oxide ion-exchange compound catalysts

    DOE Patents [OSTI]

    Dosch, R.G.; Stephens, H.P.

    1986-04-09

    Disclosed is a catalytic material of improved activity which comprises a hydrous, alkali metal or alkaline earth metal or quaternary ammonium titanate, zirconate, niobate, or tantalate, in which the metal or ammonium cations have been exchanged with a catalytically effective quantity of a catalyst metal, and which has been subsequently treated with a solution of a Bronsted acid.

  19. Preparation of catalysts via ion-exchangeable coatings on supports

    DOE Patents [OSTI]

    Dosch, R.G.; Stephens, H.P.

    1986-04-09

    Disclosed are: new catalytic compositions which comprise an inert support coated with a hydrous alkali metal, alkaline earth metal, or quaternary ammonium titanate, niobate, zirconate, or tantalate, in which the alkali or alkaline earth metal or quaternary ammonium cations have been exchanged for a catalytically effective quantity of a catalytically effective metal.

  20. State of technology of direct contact heat exchanging

    SciTech Connect (OSTI)

    Vallario, R.W.; DeBellis, D.E.

    1984-05-01

    Specific objectives of this study were to assess the state of technology development and to identify and evaluate the constraints to wider use of direct contact heat exchanger (DCHE) technology in the U.S. The scope of this study is relatively broad; it includes many types of generic systems and end-use applications, both current and future. Domestic and foreign experience with DCHE technology are compared, although the primary focus is on domestic experience. Twenty-two distinct applications of DCHE technology were identified in this study and are examined in this report. The general format is to describe each system, explore its potential applications, discuss current and past research activities and identify major implementation barriers. Finally, as a result of discussions with principal users of DCHE systems and with other knowledgeable sources, generic and specific R and D needs to overcome specific implementation barriers have been identified. The following list of DCHE systems/concepts has been classified into four major end-uses; there is also a category for specialized (other) applications.

  1. Nuclear quantum effects in water exchange around lithium and fluoride ions

    E-Print Network [OSTI]

    Wilkins, David M; Dang, Liem X

    2015-01-01

    We employ classical and ring polymer molecular dynamics simulations to study the effect of nuclear quantum fluctuations on the structure and the water exchange dynamics of aqueous solutions of lithium and fluoride ions. While we obtain reasonably good agreement with experimental data for solutions of lithium by augmenting the Coulombic interactions between the ion and the water molecules with a standard Lennard-Jones ion-oxygen potential, the same is not true for solutions of fluoride, for which we find that a potential with a softer repulsive wall gives much better agreement. A small degree of destabilization of the first hydration shell is found in quantum simulations of both ions when compared with classical simulations, with the shell becoming less sharply defined and the mean residence time of the water molecules in the shell decreasing. In line with these modest differences, we find that the mechanisms of the exchange processes are unaffected by quantization, so a classical description of these reaction...

  2. Denitration of Rocky Flats Ion-Exchange Resins: Recommendation of Denitration Processes, October 19, 1995

    SciTech Connect (OSTI)

    Jacob Espinoza; Mary Barr; Wayne Smith

    1998-12-01

    Resin denitration via anion-exchange is an implementable process that can effectively mitigate the hazards associated with stored resins in which the bulk of the nitrate consists of an "exchangeable nitrate" ionically bound to the cationic sites of the anion-exchange resins. Salicylate has been selected as the exchange anion of choice because of its superior selectivity for the Rocky Flats resins and its unique potential for comprehensive recovery and recycle. This report outlines a single recommended resin denigration procedure that is reasonably independent of the resin composition and the current stored form. This procedure is not optimized but rather seeks to `over-treat' the resins so that a single procedure works for the variety of stored resins. The recommended treatment with sodium salicylate reduces resins by 95-99+% the measured exothermic behavior of the ion-exchange.

  3. INTERNATIONAL ENVIRONMENTAL TECHNOLOGY IDENTIFICATION, DEVELOPMENT, DEMONSTRATION, DEPLOYMENT AND EXCHANGE

    SciTech Connect (OSTI)

    Roy C. Herndon

    2001-02-28

    Cooperative Agreement (DE-FC21-95EW55101) between the U.S. Department of Energy (DOE) and the Florida State University's Institute for International Cooperative Environmental Research (IICER) was designed to facilitate a number of joint programmatic goals of both the DOE and the IICER related to international technology identification, development, demonstration and deployment using a variety of mechanisms to accomplish these goals. These mechanisms included: laboratory and field research; technology demonstrations; international training and technical exchanges; data collection, synthesis and evaluation; the conduct of conferences, symposia and high-level meetings; and other appropriate and effective approaches. The DOE utilized the expertise and facilities of the IICER at Florida State University to accomplish its goals related to this cooperative agreement. The IICER has unique and demonstrated capabilities that have been utilized to conduct the tasks for this cooperative agreement. The IICER conducted activities related to technology identification, development, evaluation, demonstration and deployment through its joint centers which link the capabilities at Florida State University with collaborating academic and leading research institutions in the major countries of Central and Eastern Europe (e.g., Czech Republic, Hungary, Poland) and Russia. The activities and accomplishments for this five-year cooperative agreement are summarized in this Final Technical Report.

  4. Exploration of Ion-Exchanged Glass for Seals Applications 

    E-Print Network [OSTI]

    Ghanbari, Roushan

    2012-10-19

    As the nuclear industry grows around the globe, it brings with it a need for more safeguards and proliferation resistant technologies. The International Atomic Energy Agency (IAEA) depends on effective containment and ...

  5. Ion Exchange Membrane Cathodes for Scalable Microbial Fuel Cells

    E-Print Network [OSTI]

    applications. Introduction A microbial fuel cell (MFC) is a new technology for bioenergy production because separator to reduce oxygen diffusion to the anode can increase volumetric power density to 627 W/

  6. HIGH ASPECT RATIO ION EXCHANGE RESIN BED - HYDRAULIC RESULTS FOR SPERICAL RESIN BEADS

    SciTech Connect (OSTI)

    Duignan, M; Charles Nash, C; Timothy Punch, T

    2007-09-27

    A principal role of the DOE Savannah River Site is to safely dispose of a large volume of liquid nuclear waste held in many storage tanks. An in-tank ion exchange unit is being considered for cesium removal to accelerate waste processing. This unit is planned to have a relatively high bed height to diameter ratio (10:1). Complicating the design is the need to cool the ion exchange media; therefore, the ion exchange column will have a central cooling core making the flow path annular. To separate cesium from waste the media being considered is made of resorcinol formaldehyde resin deposited on spherical plastic beads and is a substitute for a previously tested resin made of crystalline silicotitanate. This spherical media not only has an advantage of being mechanically robust, but, unlike its predecessor, it is also reusable, that is, loaded cesium can be removed through elution and regeneration. Resin regeneration leads to more efficient operation and less spent resin waste, but its hydraulic performance in the planned ion exchange column was unknown. Moreover, the recycling process of this spherical resorcinol formaldehyde causes its volume to significantly shrink and swell. To determine the spherical media's hydraulic demand a linearly scaled column was designed and tested. The waste simulant used was prototypic of the wastes' viscosity and density. This paper discusses the hydraulic performance of the media that will be used to assist in the design of a full-scale unit.

  7. High-resolution determination of {sup 147}Pm in urine using dynamic ion-exchange chromatography

    SciTech Connect (OSTI)

    Elchuk, S.; Lucy, C.A.; Burns, K.I. [Chalk River Labs., Ontario (Canada)

    1992-10-15

    Ion exchange preconcentration followed by HPLC purification prior to scintillation counting was used to measure the concentration of {sup 147}Pm in urine. the detection limit for this method was found to be 0.1 Bq (3 fg) of {sup 147}Pm in 500 ml of urine.

  8. Immobilization of the Radionuclides from Spent Ion-Exchange Resins Using Vitrification

    SciTech Connect (OSTI)

    Hutson, N. D.; Crawford, C. L.; Russo, D. O.; Sterba, M. E.

    2002-02-25

    Approximately 60 g of an iron-enriched borosilicate glass was made in the radiochemical labs of the Savannah River Technology Center (SRTC). The glass was made to demonstrate the immobilization of the radioisotopes contained on representative Argentine ion exchange resins (similar to those used at the Embalse plant). The product was approximately 90% amorphous and was quite durable as measured by the release rates from the Product Consistency Test (PCT). The release rates were considerably better than those of the U. S. High Level Waste (HLW) benchmark DWPF EA glass. The release rate of the Cs-137 was predictably similar to that of Na and Li. No Co-60 or Sr-90 was measured in the PCT leachate. The mass balances for the inactive additives were quite good. Of the radioisotopes, approximately 71% of Cs-137 was accounted for in the glass product. This was similar to the Na mass balance. Approximately 89% of the Co-60 was accounted for in the glass product.

  9. Chaotic behavior of ion exchange phenomena in polymer gel electrolytes through irradiated polymeric membrane

    E-Print Network [OSTI]

    Sangeeta Rawat; Barnamala Saha; Awadhesh Prasad; Amita Chandra

    2012-04-18

    A desktop experiment has been done to show the nonlinearity in the I-V characteristics of an ion conducting electrochemical micro-system. Its chaotic dynamics is being reported for the first time which has been captured by an electronic circuit. Polyvinylidene fluoride-co-hexafluoropropene (PVdF-HFP) gel electrolyte comprising of a combination of plasticizers (ethylene carbonate and propylene carbonate) and salts have been prepared to study the exchange of ions through porous poly ethylene terephthalate (PET) membranes. The nonlinearity of this system is due to the ion exchange of the polymer gel electrolytes (PGEs) through a porous membrane. The different regimes of spiking and non-spiking chaotic motions are being presented. The possible applications are highlighted.

  10. Fifteen years of operation with inorganic highly selective ion exchange materials

    SciTech Connect (OSTI)

    Tusa, E. [Fortum Nuclear Services Ltd (Finland); Harjula, R. [Helsinki Univ., Radiochemical laboratory (Finland); Yarnell, P. [Graver Technologies, LLC, Glasgow, DE (United States)

    2007-07-01

    During latest fifteen years three highly selective inorganic ion exchange materials, CsTreat{sup R}, SrTreat{sup R}, and CoTreat, have been in full scale commercial use. All these materials have high capacity, and they give high decontamination factor (DF) and remarkably good volume reduction factor for storage and final disposal. A new material for antimony removal is currently coming for demonstration phase. Since 1991 only 160 liters (5.7 cu.ft) of cesium specific material, CsTreat{sup R}, has been used to purify over 1,100 m{sup 3} (over 290,000 gal) of high salt evaporator concentrates in Fortum's Loviisa NPP in Finland (1-3). In Olkiluoto NPP about 240 m{sup 3} (63,400 gal) of pool water was purified by a single 12 liter (0.4 cu.ft) column. First US application at Callaway NPP purified cesium from about 3,000 m{sup 3} (800,000 gallons) with about 250 liters (9 cu.ft) of CsTreat in their de-min system. A demonstration project at SRS site showed possibilities to remove cesium and strontium from pool water by recirculation. In Japan, reprocessing liquid was efficiently treated at JAERI site in Tokai-mura. Original cesium and strontium concentrations of about 7,4 GBq/liter (200 mCi/liter) were reduced by factors of well over 1,000. In UK, UKAEA has used CsTreat in their effluent treatment system to remove cesium from sodium coolant of their prototype fast reactor (PFR). 950 tons of sodium resulting in the generation of approximately 9000 tons of liquid effluent was treated. Cesium levels were reduced to below detection limit for release. Because of slow kinetics of inorganic materials the use of these materials in powder form was developed. Powder form CoTreat was successfully tested for use as pre-coat to existing Funda filters in THOPR feed pond plant (Sellafield, UK). Based on the same chemistry, Graver Technologies developed CsFloc and CoFloc materials for US market. CoFloc material has also demonstrated a secondary specificity for antimony removal, but this is still under testing. Well over 200 different cases were tested by customers for these ion exchange materials. Many of those tests have led to real applications and there are still many cases to come. Best benefit for users come from high volume reduction of waste volume and from high decontamination of purified liquid. (authors)

  11. Small Column Ion Exchange at Savannah River Site Technology Readiness

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:Financing Tool FitsProjectDataSecretaryDepartment of Energy Changes Help Long Island

  12. External Technical Review Report for Small Column Ion Exchange Technology

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum12, 2015Executive Order 13514 Federal LeadershipDepartmentSeptemebr

  13. Hydrogen production in the K-Basin ion exchange columns, modules and cartridge filters

    SciTech Connect (OSTI)

    Not Available

    1994-12-21

    K-Basin uses ion exchange modules and ion exchange (IX) columns for removing radionuclides from the basin water. When the columns and modules are loaded, they are removed from service, drained and stored. After a few IX columns accumulate in storage, they are moved to a burial box. One of the burial box contains 33 columns and the other, six. The radionuclides act on the liquid left within and adhering to the beads to produce hydrogen. This report describes the generation rate, accumulation rate and significance of that accumulation. This summary also highlights those major areas of concern to the external (to Westinghouse Hanford Company [WHC]) reviewers. Appendix H presents the comments made by the external reviewers and, on a separate sheet, the responses to those comments. The concerns regarding the details of the analytical approach, are addressed in Appendix H and in the appropriate section.

  14. Safety Evaluation for Packaging for onsite Transfer of plutonium recycle test reactor ion exchange columns

    SciTech Connect (OSTI)

    Smith, R.J.

    1995-09-11

    The purpose of this Safety Evaluation for Packaging (SEP) is to authorize the use of three U.S. Department of Transportation (DOT) 7A, Type A metal boxes (Capital Industries Part No. S 0600-0600-1080- 0104) to package 12 Plutonium Recycle Test Reactor (PRTR) ion exchange columns as low-level waste (LLW). The packages will be transferred from the 309 Building in the 300 Area to low level waste burial in the 200 West Area. Revision 1 of WHC-SD-TP-SEP-035 (per ECN No. 621467) documents that the boxes containing ion exchange columns and grout will maintain the payload under normal conditions of transport if transferred without the box lids

  15. Solar Wind Charge Exchange Studies of Highly Charged Ions on Atomic Hydrogen

    SciTech Connect (OSTI)

    Draganic, Ilija N [ORNL; Seely, D. G. [Albion College; McCammon, D [University of Wisconsin, Madison; Havener, Charles C [ORNL

    2011-01-01

    Accurate studies of low energy charge exchange (CX) are critical to understanding underlying soft X ray radiation processes in the interaction of highly charged ions from the solar wind with the neutral atoms and molecules in the heliosphere, cometary comas, planetary atmospheres, interstellar winds, etc.. Particularly important are the CX cross sections for bare, H like, and He like ions of C, N, O and Ne, which are the dominant charge states for these heavier elements in the solar wind. Absolute total cross sections for single electron capture by H like ions of C, N, O and fully stripped O ions from atomic hydrogen have been measured in an expanded range of relative collision energies (5 eV u 20 keV u) and compared to previous H oven measurements. The present measurements are performed using a merged beams technique with intense highly charged ion beams extracted from a 14.5 GHz ECR ion source installed on a high voltage platform at the Oak Ridge National Laboratory. For the collision energy range of 0.3 keV u 3.3 keV u, which corresponds to typical ion velocities in the solar wind, the new measurements are in good agreement with previous H oven measurements. The experimental results are discussed in detail and compared with theoretical calculations where available.

  16. Solar Wind Charge Exchange Studies Of Highly Charged Ions On Atomic Hydrogen

    SciTech Connect (OSTI)

    Draganic, I. N.; Havener, C. C. [Physics Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831 (United States); Seely, D. G. [Department of Physics, Albion College, Albion, MI 49224 (United States); McCammon, D. [Department of Physics, University of Wisconsin, Madison, WI 53706 (United States)

    2011-06-01

    Accurate studies of low-energy charge exchange (CX) are critical to understanding underlying soft X-ray radiation processes in the interaction of highly charged ions from the solar wind with the neutral atoms and molecules in the heliosphere, cometary comas, planetary atmospheres, interstellar winds, etc.. Particularly important are the CX cross sections for bare, H-like, and He-like ions of C, N, O and Ne, which are the dominant charge states for these heavier elements in the solar wind. Absolute total cross sections for single electron capture by H-like ions of C, N, O and fully-stripped O ions from atomic hydrogen have been measured in an expanded range of relative collision energies (5 eV/u-20 keV/u) and compared to previous H-oven measurements. The present measurements are performed using a merged-beams technique with intense highly charged ion beams extracted from a 14.5 GHz ECR ion source installed on a high voltage platform at the Oak Ridge National Laboratory. For the collision energy range of 0.3 keV/u-3.3 keV/u, which corresponds to typical ion velocities in the solar wind, the new measurements are in good agreement with previous H-oven measurements. The experimental results are discussed in detail and compared with theoretical calculations where available.

  17. Membrane permeation process for dehydration of organic liquid mixtures using sulfonated ion-exchange polyalkene membranes

    DOE Patents [OSTI]

    Cabasso, Israel (131 Buckingham Ave., Syracuse, NY 13210); Korngold, Emmanuel (P.O. Box 1025, Beer-Sheva 84110, IL)

    1988-01-01

    A membrane permeation process for dehydrating a mixture of organic liquids, such as alcohols or close boiling, heat sensitive mixtures. The process comprises causing a component of the mixture to selectively sorb into one side of sulfonated ion-exchange polyalkene (e.g., polyethylene) membranes and selectively diffuse or flow therethrough, and then desorbing the component into a gas or liquid phase on the other side of the membranes.

  18. Staff exchange with Spokane Intercollegiate Research and Technology Institute (SIRTI), final project report

    SciTech Connect (OSTI)

    Alexander, G.M.

    1994-12-01

    Staff exchanges, such as the one described in this report, are intended to facilitate communication and collaboration among scientists and engineers at Department of Energy (DOE) laboratories, in U.S. industry, and academia. Funding support for these exchanges is provided by the DOE, Office of Energy Research, Laboratory Technology Transfer Program. Funding levels for each exchange typically range from $20,000 to $40,000. The exchanges offer the opportunity for the laboratories to transfer technology and expertise to industry, gain a perspective on industry`s problems, and develop the basis for further cooperative efforts through Cooperative Research and Development Agreements (CRADAS) or other mechanisms.

  19. Technology Solutions Case Study: Foundation Heat Exchanger, Oak Ridge, Tennessee

    SciTech Connect (OSTI)

    2014-03-01

    The foundation heat exchanger, developed by Oak Ridge National Laboratory, is a new concept for a cost-effective horizontal ground heat exchanger that can be connected to water-to-water or water-to-air heat pump systems for space conditioning as well as domestic water heating.

  20. A Critical Evaluation on the Use of Kinetics for DeterminingThermodynamicsof Ion Exchange in Soils1

    E-Print Network [OSTI]

    Sparks, Donald L.

    not assist one in understanding the mechanisms and rates of K exchange in clay min- erals and soils, norA Critical Evaluation on the Use of Kinetics for DeterminingThermodynamicsof Ion Exchange in Soils1 (£,,) in the two soils ranged from 7.42 kJ mol~' using the miscible displacement tech- nique to 32.96 kJ mol

  1. Synthesis of Single-Crystalline Niobate Nanorods via Ion-Exchange Based on Molten-Salt Reaction

    E-Print Network [OSTI]

    Wang, Zhong L.

    Synthesis of Single-Crystalline Niobate Nanorods via Ion-Exchange Based on Molten-Salt Reaction by employing hydrothermal reaction2 or templates,3 molten-salt syn- thesis,4 and composite- exchange approach for the synthesis of single-crystal sodium and calcium niobates nanorods based on molten-salt

  2. Vehicle Technologies Office Merit Review 2014: Daikin Advanced Lithium Ion Battery Technology – High Voltage Electrolyte

    Office of Energy Efficiency and Renewable Energy (EERE)

    Presentation given by Daikin America at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about Daikin advanced lithium ion...

  3. Emerging Heat Exchanger Technologies for the Mitigation of Fouling in Crude Oil Pre-Heat Trains 

    E-Print Network [OSTI]

    Polley, G. T.; Pugh, S. J.; King, D. C.

    2002-01-01

    -heat train exchangers foul is controlled by fluid velocity and by wall temperature. Technologies which promote the heat transfer on the crude oil side of an exchanger are therefore favoured. (Note: promotion of the heat transfer on the hot side of the unit...

  4. Kinetics of Ion Exchange on Clay Minerals and Soil: I. Evaluation of Methods1 R. A. OGWADA AND D. L. SPARKS2

    E-Print Network [OSTI]

    Sparks, Donald L.

    Kinetics of Ion Exchange on Clay Minerals and Soil: I. Evaluation of Methods1 R. A. OGWADA AND D. L,vermiculite. Ogwada, R.A., and D.L. Sparks. 1986. Kinetics of ion exchangeon clay minerals and soil: I. Evaluation displacement or flow techniques to investigate kinetics of ion exchange on soils and clay minerals (Sparks

  5. Exchange bias in polycrystalline magnetite films made by ion-beam assisted deposition

    SciTech Connect (OSTI)

    Kaur, Maninder; Qiang, You [Department of Physics, University of Idaho, Moscow, Idaho 83844 (United States); Jiang, Weilin [Pacific Northwest National Laboratory, Richland, Washington 99352 (United States); Burks, Edward C.; Liu, Kai [Department of Physics, University of California, Davis, California 95616 (United States); Namavar, Fereydoon [University of Nebraska Medical Center, Omaha, Nebraska 68198 (United States); McCloy, John S. [Pacific Northwest National Laboratory, Richland, Washington 99352 (United States); School of Mechanical and Materials Engineering, Washington State University, Pullman, Washington 98163 (United States)

    2014-11-07

    Iron oxide films were produced using ion-beam-assisted deposition, and Raman spectroscopy and x-ray diffraction indicate single-phase magnetite. However, incorporation of significant fractions of argon in the films from ion bombardment is evident from chemical analysis, and Fe/O ratios are lower than expected from pure magnetite, suggesting greater than normal disorder. Low temperature magnetometry and first-order reversal curve measurements show strong exchange bias, which likely arises from defects at grain boundaries, possibly amorphous, creating frustrated spins. Since these samples contain grains ?6?nm, a large fraction of the material consists of grain boundaries, where spins are highly disordered and reverse independently with external field.

  6. The removal of uranium from acidic media using ion exchange and/or extraction chromatography

    SciTech Connect (OSTI)

    FitzPatrick, J.R.; Schake, B.S.; Murphy, J.; Holmes, K; West, M.H.

    1996-06-01

    The separation and purification of uranium from either nitric acid or hydrochloric acid media can be accomplished by using either solvent extraction or ion-exchange. Over the past two years at Los Alamos, emerging programs are focused on recapturing the expertise required to do limited, small-quantity processing of enriched uranium. During this period of time, we have been investigating ion-addition, waste stream polishing is associated with this effort in order to achieve more complete removal of uranium prior to recycle of the acid. Extraction chromatography has been demonstrated to further polish the uranium from both nitric and hydrochloric acid media thus allowing for a more complete recovery of the actinide material and creation of less waste during the processing steps.

  7. Use of Novel Highly Selective Ion Exchange Media for Minimizing the Waste Arising from Different NPP and Other Liquids

    SciTech Connect (OSTI)

    Tusa, Esko; Harjula, Risto; Lehto, Jukka

    2003-02-25

    Highly selective inorganic ion exchangers give new possibilities to implement and operate new innovative treatment systems for radioactive liquids. Because of high selectivity these ion exchangers can be used even in liquids of high salt concentrations. Only selected target nuclides will be separated and inactive salts are left in the liquid, which can be released or recategorized. Thus, it is possible to reduce the volume of radioactive waste dramatically. On the other hand, only a small volume of highly selective material is required in applications, which makes it possible to design totally new types of compact treatment systems. The major benefit of selective ion exchange media comes from the very large volume reduction of radioactive waste in final disposal. It is also possible to save in investment costs, because small ion exchanger volumes can be used and handled in a very small facility. This paper describes different applications of these highly selective ion exchangers, both commercial fullscale applications and laboratory tests, to give the idea of their efficiency for different liquids.

  8. Literature Review of Spherical Resorcinol-Formaldehyde for Cesium Ion Exchange

    SciTech Connect (OSTI)

    Brown, Garrett N.

    2014-09-30

    The current report summarizes work performed throughout the scientific community and DOE complex as reported in the open literature and DOE-sponsored reports to evaluate the Cs+ ion exchange (CIX) characteristics of SRF resin. King (2007) completed a similar literature review in support of material selection for the Small Column Ion Exchange (SCIX) project. Josephson et al. (2010) and Sams et al. (2009) provided a similar brief review of SRF CIX for the near-tank Cs+ removal (NTCR) project. Thorson (2008a) documented the basis for recommending SRF over SuperLigTM 644 as the primary CIX resin in the WTP. The current review expands on previous work, summarizes additional work completed to date, and provides a broad view of the literature without focusing on a specific column system. Although the focus of the current review is the SRF resin, many cited references include multiple materials such as the non-spherical GGRF and SuperLigTM 644 organic resins and crystalline silicotitanate (CST) IONSIVTM IE-911, a non-elutable inorganic material. This report summarizes relevant information provided in the literature.

  9. Modeling Ion-Exchange Processing With Spherical Resins For Cesium Removal

    SciTech Connect (OSTI)

    Hang, T.; Nash, C. A.; Aleman, S. E.

    2012-09-19

    The spherical Resorcinol-Formaldehyde and hypothetical spherical SuperLig(r) 644 ion-exchange resins are evaluated for cesium removal from radioactive waste solutions. Modeling results show that spherical SuperLig(r) 644 reduces column cycling by 50% for high-potassium solutions. Spherical Resorcinol Formaldehyde performs equally well for the lowest-potassium wastes. Less cycling reduces nitric acid usage during resin elution and sodium addition during resin regeneration, therefore, significantly decreasing life-cycle operational costs. A model assessment of the mechanism behind ''cesium bleed'' is also conducted. When a resin bed is eluted, a relatively small amount of cesium remains within resin particles. Cesium can bleed into otherwise decontaminated product in the next loading cycle. The bleed mechanism is shown to be fully isotherm-controlled vs. mass transfer controlled. Knowledge of residual post-elution cesium level and resin isotherm can be utilized to predict rate of cesium bleed in a mostly non-loaded column. Overall, this work demonstrates the versatility of the ion-exchange modeling to study the effects of resin characteristics on processing cycles, rates, and cold chemical consumption. This evaluation justifies further development of a spherical form of the SL644 resin.

  10. Ion exchange columns for selective removal of cesium from aqueous radioactive waste using hydrous crystalline silico-titanates 

    E-Print Network [OSTI]

    Ricci, David Michael

    1995-01-01

    conscious society. In Hanford, WA, hundreds of underground storage tanks hold tens of millions of gallons of aqueous radioactive waste. This liquid waste, which has a very high sodium content, contains trace amounts of radioactive cesium 137. Since.... The radioactive waste would be concentrated in the exchanger so that it can be stored in solid form, which requires less storage space. The remaining liquid would no longer be radioactive and could be disposed of at a much lower cost. Ion exchange has...

  11. THREE-DIMENSIONAL THERMAL MODELING ANALYSIS OF CST MEDIA FOR THE SMALL ION EXCHANGE PROJECT

    SciTech Connect (OSTI)

    Lee, S.; King, W.

    2011-09-12

    The Small Column Ion Exchange (SCIX) project is designed to accelerate closure of High Level Waste (HLW) tanks at the Savannah River Site (SRS). The SRS tanks store HLW in three forms: sludge, saltcake, and supernate. An in-tank ion exchange process is being designed to treat supernate and dissolved saltcake waste. Through this process, radioactive cesium from the salt solution is adsorbed into Crystalline Silicotitanate (CST) ion exchange media packed within a flow-through column. A packed column loaded with radioactive cesium generates significant heat from radiolytic decay. The waste supernate solution within the ion exchange bed will boil around 120 C. Solution superheating above the boiling point within the column could lead to violent hazardous energy releases. System heating from loaded CST is also of concern in other process modules, such as the waste tank. Due to tank structural integrity concerns, the wall temperature limit for the SRS waste tanks is 100 C. The transfer of cesium-loaded CST to the tank could result in localized hot spots on the tank floor and walls which may exceed this limit. As a result, thermal modeling calculations have been conducted to predict the maximum temperatures achievable both in the column and in the waste tank. As specified in the associated Technical Task Plan, one objective of the present work was to compute temperature distributions within the ion exchange column module under accident scenarios including loss of salt solution flow through the bed and loss of coolant system flow. The column modeling domain and the scope of the calculations in this case were broadened relative to previous two-dimensional calculations to include vertical temperature distributions within the packed bed of ion exchange media as well as the upper column plenum region containing only fluid. The baseline design conditions and in-column modeling domain for the ion-exchange column module are shown in Figure 1. These evaluations assumed the maximum bounding cesium loading considered possible based on current knowledge regarding CST media and the anticipated feed compositions. Since this cesium loading was considerably higher than the nominal loading conditions in SRS waste, cases with lower loading were also evaluated. Modeling parameters were the same as those used previously unless otherwise indicated. The current model does not capture multi-phase cooling mechanisms operative when solution boiling occurs. This feature is conservative in the sense that it does not account for the large cooling effects associated with phase transfer. However, the potential transfer of heat to the plenum region associated with vertical bubble ascension through the column during boiling is also neglected. Thermal modeling calculations were also performed for the entire waste storage tank for the case where loaded and ground CST was transferred to the tank. The modeling domain used for the in-tank calculations is provided in Figure 2. The in-tank domain is based on SRS Tank 41, which is a Type-IIIA tank. Temperature distributions were evaluated for cylindrical, ground CST mounds located on the tank floor. Media grinding is required prior to vitrification processing of the CST in the SRS Defense Waste Processing Facility (DWPF). The location of the heat source region on the tank floor due to the accumulation of CST material was assumed to be just under the grinder. The shape of the CST mound was assumed to be cylindrical. This shape is believed to be most representative of the actual mound shape formed in the tank, given that submersible mixing pumps will be available for media dispersion. Alternative configurations involving other geometrical shapes for the CST mound were evaluated in the previous work. Sensitivity analysis for the in-tank region was performed for different amounts of CST media. As was the case for the in-column model, the in-tank model does not include multi-phase cooling mechanisms operative when solution boiling occurs. The in-column and the in-tank evaluations incorporated recently updated maximum cesi

  12. Preliminary flowsheet: Ion exchange for separation of cesium from Hanford tank waste using resorcinol-formaldehyde resin

    SciTech Connect (OSTI)

    Penwell, D.L.

    1994-12-28

    This preliminary flowsheet document describes an ion exchange process which uses resorcinol-formaldehyde (R-F) resin to remove cesium from Hanford tank waste. The flowsheet describes one possible equipment configuration, and contains mass balances based on that configuration with feeds of Neutralized Current Acid Waste, and Double Shell Slurry Feed. The flowsheet also discusses process alternatives, unresolved issues, and development needs associated with the ion exchange process. It is expected that this flowsheet will evolve as open issues are resolved and progress is made on development needs. This is part of the Tank Waste Remediation Program at Hanford. 26 refs, 6 figs, 25 tabs.

  13. REMOVAL OF CESIUM FROM SAVANNAH RIVER SITE WASTE WITH SPHERICAL RESORCINOL FORMALDEHYDE ION EXCHANGE RESIN EXPERIMENTAL TESTS

    SciTech Connect (OSTI)

    Duignan, M.; Nash, C.

    2010-03-31

    A principal goal at the Savannah River Site (SRS) is to safely dispose of the large volume of liquid nuclear waste held in many storage tanks. In-tank ion exchange (IX) columns are being considered for cesium removal. The spherical form of resorcinol formaldehyde ion exchange resin (sRF) is being evaluated for decontamination of dissolved saltcake waste at SRS, which is generally lower in potassium and organic components than Hanford waste. The sRF performance with SRS waste was evaluated in two phases: resin batch contacts and IX column testing with both simulated and actual dissolved salt waste. The tests, equipment, and results are discussed.

  14. THERMAL MODELING ANALYSIS OF CST MEDIA IN THE SMALL COLUMN ION EXCHANGE PROJECT

    SciTech Connect (OSTI)

    Lee, S.

    2010-11-01

    Models have been developed to simulate the thermal characteristics of Crystalline Silicotitanate (CST) ion exchange media fully loaded with radioactive cesium in a column configuration and distributed within a waste storage tank. This work was conducted to support the Small Column Ion Exchange (SCIX) program which is focused on processing dissolved, high-sodium salt waste for the removal of specific radionuclides (including Cs-137, Sr-90, and actinides) within a High Level Waste (HLW) storage tank at the Savannah River Site. The SCIX design includes CST columns inserted and supported in the tank top risers for cesium removal. Temperature distributions and maximum temperatures across the column were calculated with a focus on process upset conditions. A two-dimensional computational modeling approach for the in-column ion-exchange domain was taken to include conservative, bounding estimates for key parameters such that the results would provide the maximum centerline temperatures achievable under the design configurations using a feed composition known to promote high cesium loading on CST. One salt processing scenario includes the transport of the loaded (and possibly ground) CST media to the treatment tank floor. Therefore, additional thermal modeling calculations were conducted using a three-dimensional approach to evaluate temperature distributions for the entire in-tank domain including distribution of the spent CST media either as a mound or a flat layer on the tank floor. These calculations included mixtures of CST with HLW sludge or loaded Monosodium Titanate (MST) media used for strontium/actinide sorption. The current full-scale design for the CST column includes one central cooling pipe and four outer cooling tubes. Most calculations assumed that the fluid within the column was stagnant (i.e. no buoyancy-induced flow) for a conservative estimate. A primary objective of these calculations was to estimate temperature distributions across packed CST beds immersed in waste supernate or filled with dry air under various accident scenarios. Accident scenarios evaluated included loss of salt solution flow through the bed (a primary heat transfer mechanism), inadvertent column drainage, and loss of active cooling in the column. The calculation results showed that for a wet CST column with active cooling through one central and four outer tubes and 35 C ambient external air, the peak temperature for the fully-loaded column is about 63 C under the loss of fluid flow accident, which is well below the supernate boiling point. The peak temperature for the naturally-cooled (no active, engineered cooling) wet column is 156 C under fully-loaded conditions, exceeding the 130 C boiling point. Under these conditions, supernate boiling would maintain the column temperature near 130 C until all supernate was vaporized. Without active engineered cooling and assuming a dry column suspended in unventilated air at 35 C, the fully-loaded column is expected to rise to a maximum of about 258 C due to the combined loss-of coolant and column drainage accidents. The modeling results demonstrate that the baseline design using one central and four outer cooling tubes provides a highly efficient cooling mechanism for reducing the maximum column temperature. Results for the in-tank modeling calculations clearly indicate that when realistic heat transfer boundary conditions are imposed on the bottom surface of the tank wall, as much as 450 gallons of ground CST (a volume equivalent to two ion exchange processing cycles) in an ideal hemispherical shape (the most conservative geometry) can be placed in the tank without exceeding the 100 C wall temperature limit. Furthermore, in the case of an evenly-distributed flat layer, the tank wall reaches the temperature limit after the ground CST material reaches a height of approximately 8 inches.

  15. Standard practice for The separation of americium from plutonium by ion exchange

    E-Print Network [OSTI]

    American Society for Testing and Materials. Philadelphia

    2001-01-01

    1.1 This practice describes the use of an ion exchange technique to separate plutonium from solutions containing low concentrations of americium prior to measurement of the 241Am by gamma counting. 1.2 This practice covers the removal of plutonium, but not all the other radioactive isotopes that may interfere in the determination of 241Am. 1.3 This practice can be used when 241Am is to be determined in samples in which the plutonium is in the form of metal, oxide, or other solid provided that the solid is appropriately sampled and dissolved (See Test Methods C758, C759, and C1168). 1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

  16. Effects of pyrolysis conditions and ion-exchangeable cations on the thermal decomposition of a Victorian low-rank coal

    SciTech Connect (OSTI)

    Sathe, C.; Pang, Y.; Li, C.Z. [Monash Univ., Clayton, Victoria (Australia)

    1998-12-31

    A Loy Yang brown coal sample was acid-washed and ion-exchanged with Na and Ca to prepare the H-form, Na-form and Ca-form coal samples. These coal samples were pyrolyzed in a wire-mesh reactor where the extraparticle secondary reactions of the evolved volatiles were minimized. The ion-exchanged coal samples were found to give very different tar yields from those of the raw coal samples. The tar yields from the pyrolysis of the raw and H-form coal samples were observed to be very sensitive to changes in heating rate and the tar yields at 600 C were found to increase much more than the corresponding increases in the total volatile yields as the heating rate was increased from 1 to 1,000 K/s. In contrast, the tar yields from the Ca-form and Na-form coal samples showed little heating rate sensitivity. The heating rate sensitivity of pyrolysis yields is believed to be at least partly related to the presence of carboxyl/carboxylate groups and other bulky substitution groups in the coal as well as the rapid pressure buildup within the particles. Re-exchanging Na in the Na-form coal sample and Ca in the Ca-form coal sample with H confirmed the effects of Na and Ca, but also suggested that the irreversible structural changes taking place during ion-exchange should also be considered to evaluate the effects of ion-exchangeable cations during pyrolysis. The major roles of ion-exchangeable cations during pyrolysis are thought to be associated with the transformation of the alkali and alkaline earth metallic species. Some Ca was volatilized during pyrolysis, even at temperatures as low as 600 C.

  17. Using Process Knowledge to Manage Disposal Classification of Ion-Exchange Resin - 13566

    SciTech Connect (OSTI)

    Bohnsack, Jonathan N.; James, David W.

    2013-07-01

    It has been previously shown by EPRI [1] that Class B and C resins represent a small portion by volume of the overall generation of radioactively contaminated resins. In fact, if all of the resins were taken together the overall classification would meet Class A disposal requirements. Lowering the classification of the ion exchange resins as they are presented for disposal provides a path for minimizing the amount of waste stored. Currently there are commercial options for blending wastes from various generators for Class A disposal in development. The NRC may have by this time introduced changes and clarifications to the Branch Technical Position (BTP) on Concentration Averaging and Encapsulation [2] that may ultimately add more flexibility to what can be done at the plant level. The BTP has always maintained that mixtures of resins that are combined for ALARA purposes or operational efficiency can be classified on the basis of the mixture. This is a point often misinterpreted and misapplied. This paper will address options that can be exercised by the generator that can limit B and C waste generation by more rigorous tracking of generation and taking advantage of the normal mix of wastes. This can be achieved through the monitoring of reactor coolant chemistry data and coupled with our knowledge of radionuclide production mechanisms. This knowledge can be used to determine the overall accumulation of activity in ion-exchange resins and provides a 'real-time' waste classification determination of the resin and thereby provide a mechanism to reduce the production of waste that exceeds class A limits. It should be noted that this alternative approach, although rarely used in a nuclear power plant setting, is acknowledged in the original BTP on classification [3] as a viable option for determining radionuclide inventories for classification of waste. Also included is a discussion of an examination performed at the Byron plant to estimate radionuclide content in the final waste stream from upstream sampling of reactor coolant and fuel pool water. (authors)

  18. Small-Column Cesium Ion Exchange Elution Testing of Spherical Resorcinol-Formaldehyde

    SciTech Connect (OSTI)

    Brown, Garrett N.; Russell, Renee L.; Peterson, Reid A.

    2011-10-21

    This report summarizes the work performed to evaluate multiple, cesium loading, and elution cycles for small columns containing SRF resin using a simple, high-level waste (HLW) simulant. Cesium ion exchange loading and elution curves were generated for a nominal 5 M Na, 2.4E-05 M Cs, 0.115 M Al loading solution traced with 134Cs followed by elution with variable HNO3 (0.02, 0.07, 0.15, 0.23, and 0.28 M) containing variable CsNO3 (5.0E-09, 5.0E-08, and 5.0E-07 M) and traced with 137Cs. The ion exchange system consisted of a pump, tubing, process solutions, and a single, small ({approx}15.7 mL) bed of SRF resin with a water-jacketed column for temperature-control. The columns were loaded with approximately 250 bed volumes (BVs) of feed solution at 45 C and at 1.5 to 12 BV per hour (0.15 to 1.2 cm/min). The columns were then eluted with 29+ BVs of HNO3 processed at 25 C and at 1.4 BV/h. The two independent tracers allowed analysis of the on-column cesium interaction between the loading and elution solutions. The objective of these tests was to improve the correlation between the spent resin cesium content and cesium leached out of the resin in subsequent loading cycles (cesium leakage) to help establish acid strength and purity requirements.

  19. DATA QUALITY OBJECTIVE SUMMARY REPORT FOR THE 105 K EAST ION EXCHANGE COLUMN MONOLITH

    SciTech Connect (OSTI)

    JOCHEN, R.M.

    2007-08-02

    The 105-K East (KE) Basin Ion Exchange Column (IXC) cells, lead caves, and the surrounding vault are to be removed as necessary components in implementing ''Hanford Federal Facility Agreement and Consent Order'' (Ecology et al. 2003) milestone M-034-32 (Complete Removal of the K East Basin Structure). The IXCs consist of six units located in the KE Basin, three in operating positions in cells and three stored in a lead cave. Methods to remove the IXCs from the KE Basin were evaluated in KBC-28343, ''Disposal of K East Basin Ion Exchange Column Evaluation''. The method selected for removal was grouting the six IXCs into a single monolith for disposal at the Environmental Restoration Disposal Facility (ERDF). Grout will be added to the IXC cells, IXC lead caves containing spent IXCs, and in the spaces between the lead cave walls and metal skin, to immobilize the contaminants, provide self-shielding, minimize void space, and provide a structurally stable waste form. The waste to be offered for disposal is the encapsulated monolith defined by the exterior surfaces of the vault and the lower surface of the underlying slab. This document presents summary of the data quality objective (DQO) process establishing the decisions and data required to support decision-making activities for the disposition of the IXC monolith. The DQO process is completed in accordance with the seven-step planning process described in EPA QA/G-4, ''Guidance for the Data Quality Objectives Process'', which is used to clarify and study objectives; define the appropriate type, quantity, and quality of data; and support defensible decision-making. The DQO process involves the following steps: (1) state the problem; (2) identify the decision; (3) identify the inputs to the decision; (4) define the boundaries of the study; (5) develop a decision rule (DR); (6) specify tolerable limits on decision errors; and (7) optimize the design for obtaining data.

  20. Proton and light ion induced charge exchange reactions in nuclei This article has been downloaded from IOPscience. Please scroll down to see the full text article.

    E-Print Network [OSTI]

    Fernández de Córdoba, Pedro

    Proton and light ion induced charge exchange reactions in nuclei This article has been downloaded Scripta. Vol. 48, 101-104, 1993 Proton and Light Ion Induced Charge Exchange Reactions in Nuclei E. Oset of strength from the proton to the deu- teron targets and an even more remarkable shift of the strength

  1. Light-assisted ion-neutral reactive processes in the cold regime: radiative molecule formation vs. charge exchange

    E-Print Network [OSTI]

    Hall, Felix H J; Bouloufa, Nadia; Dulieu, Olivier; Willitsch, Stefan

    2011-01-01

    We present a combined experimental and theoretical study of cold reactive collisions between laser-cooled Ca+ ions and Rb atoms in an ion-atom hybrid trap. We observe rich chemical dynamics consisting of a complex interplay between non-adiabatic and radiative charge exchange as well as radiative molecule formation which are interpreted using high-level electronic structure calculations. We study the role of light-assisted processes and show that the efficiency of the dominant chemical pathways is considerably enhanced in excited reaction channels. Our results point to a general framework of radiative and non-radiative processes dominating the cold chemistry in ion-atom hybrid traps.

  2. Novel Hybrid Materials with High Stability for Electrically Switched Ion Exchange: Carbon Nanotubes/Polyaniline/Nickel Hexacyanoferrate Nanocomposites

    SciTech Connect (OSTI)

    Lin, Yuehe; Cui, Xiaoli

    2005-04-21

    A novel and stable carbon nanotubes /polyaniline /nickel hexacyanoferrates composite film has been synthesized with electrodeposition method, and the possibility for removing cesium through an electrically switched ion exchange has been evaluated in a mixture containing NaNO3 and CsNO3.

  3. Technology Performance Exchange - 2014 BTO Peer Review | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:Financing ToolInternational Affairs, BeforeActivities TechnicalOffice -Key toEnergy Technology

  4. STUDIES OF X-RAY PRODUCTION FOLLOWING CHARGE EXCHANGE RECOMBINATION BETWEEN HIGHLY CHARGED IONS AND NEUTRAL ATOMS AND MOLECULES

    SciTech Connect (OSTI)

    Brown, G V; Beiersdorfer, P; Chen, H; Clementson, J; Frankel, M; Gu, M F; Kelley, R L; Kilbourne, C A; Porter, F S; Thorn, D B; Wargelin, B J

    2008-08-28

    We have used microcalorimeters built by the NASA/Goddard Space Flight Center and the Lawrence Livermore National Laboratory Electron Beam Ion Trap to measure X-ray emission produced by charge exchange reactions between highly charged ions colliding with neutral helium, hydrogen, and nitrogen gas. Our measurements show the spectral dependence on neutral species and also show the distinct differences between spectra produced by charge exchange reactions and those produced by direct impact excitation. These results are part of an ongoing experimental investigation at the LLNL EBIT facility of charge exchange spectral signatures and can be used to interpret X-ray spectra produced by a variety of laboratory and celestial sources including cometary and planetary atmospheres, the Earth's magnetosheath, the heliosphere, and tokamaks.

  5. Process for carbonaceous material conversion and recovery of alkali metal catalyst constituents held by ion exchange sites in conversion residue

    DOE Patents [OSTI]

    Sharp, David W. (Seabrook, TX)

    1980-01-01

    In a coal gasification operation or similar conversion process carried out in the presence of an alkali metal-containing catalyst wherein solid particles containing alkali metal residues are produced, alkali metal constituents are recovered for the particles by contacting or washing them with an aqueous solution containing calcium or magnesium ions in an alkali metal recovery zone at a low temperature, preferably below about 249.degree. F. During the washing or leaching process, the calcium or magnesium ions displace alkali metal ions held by ion exchange sites in the particles thereby liberating the ions and producing an aqueous effluent containing alkali metal constituents. The aqueous effluent from the alkali metal recovery zone is then recycled to the conversion process where the alkali metal constituents serve as at least a portion of the alkali metal constituents which comprise the alkali metal-containing catalyst.

  6. The TFTR E Parallel B Spectrometer for Mass and Energy Resolved Multi-Ion Charge Exchange Diagnostics

    SciTech Connect (OSTI)

    A.L. Roquemore; S.S. Medley

    1998-01-01

    The Charge Exchange Neutral Analyzer diagnostic for the Tokamak Fusion Test Reactor was designed to measure the energy distributions of both the thermal ions and the supra thermal populations arising from neutral-beam injection and ion cyclotron radio-frequency heating. These measurements yield the plasma ion temperature, as well as several other plasma parameters necessary to provide an understanding of the plasma condition and the performance of the auxiliary heating methods. For this application, a novel charge-exchange spectrometer using a dee-shaped region of parallel electric and magnetic fields was developed at the Princeton Plasma Physics Laboratory. The design and performance of this spectrometer is described in detail, including the effects of exposure of the microchannel plate detector to magnetic fields, neutrons, and tritium.

  7. Processes for washing a spent ion exchange bed and for treating biomass-derived pyrolysis oil, and apparatuses for treating biomass-derived pyrolysis oil

    DOE Patents [OSTI]

    Baird, Lance Awender; Brandvold, Timothy A.

    2015-11-24

    Processes and apparatuses for washing a spent ion exchange bed and for treating biomass-derived pyrolysis oil are provided herein. An exemplary process for washing a spent ion exchange bed employed in purification of biomass-derived pyrolysis oil includes the step of providing a ion-depleted pyrolysis oil stream having an original oxygen content. The ion-depleted pyrolysis oil stream is partially hydrotreated to reduce the oxygen content thereof, thereby producing a partially hydrotreated pyrolysis oil stream having a residual oxygen content that is less than the original oxygen content. At least a portion of the partially hydrotreated pyrolysis oil stream is passed through the spent ion exchange bed. Water is passed through the spent ion exchange bed after passing at least the portion of the partially hydrotreated pyrolysis oil stream therethrough.

  8. Radium-thorium disequilibrium and zeolite-water ion exchange in a Yellowstone hydrothermal environment

    SciTech Connect (OSTI)

    Sturchio, N.C.; Bohlke, J.K. (Argonne National Laboratory, IL (USA)); Binz, C.M. (Loras College, Dubuque, IA (USA))

    1989-05-01

    Whole rock samples of hydrothermally altered Biscuit Basin rhyolite from Yellowstone drill cores Y-7 and Y-8 were analyzed for {sup 226}Ra and {sup 230}Th to determine the extent of radioactive disequilibrium and its relation to the rates and mechanisms of element transport in the shallow portion of an active hydrothermal system. The ({sup 226}Ra/{sup 230}Th) activity ratios range from 0.73 to 1.46 and are generally correlated with Th-normalized Ba concentrations (Ba{sub N}). Compositions of clinoptilolite and mordenite in these samples are consistent with ion exchange equilibrium between zeolites and coexisting thermal waters. Average K{sup Ba}{sub d mineral-water} values are 1.0 {center dot} 10{sup 5} mL/g for clinoptilolite and 1.4 {center dot} 10{sup 4} mL/g for mordenite. Apparent diffusivities through matrix porosity estimated for R and Ba range from {approximately}10{sup {minus}12} to {approximately}10{sup {minus}10} cm{sup 2} s{sup {minus}1} in thoroughly zeolitic rhyolite; these rates of diffusion are too low to account for the observed distance scale of ({sup 226}Ra/{sup 230}Th) disequilibrium. The correlated values of ({sup 226}Ra/{sup 230}Th) disequilibrium and Ba{sub N} represent zeolite-water ion exchange equilibrium that is caused by porous flow of water through the rock matrix and by the relatively rapid diffusion of cations within the zeolite lattices. A water flux of at least {approximately}2.5 (cm{sup 3}{sub water}/cm{sup 3}{sub rock}) yr{sup {minus}1} is required to produce measurable ({sup 226}Ra/{sup 230}Th) disequilibrium, whereas at least {approximately}23 (cm{sup 3}{sub water}/cm{sup 3}{sub rock}) yr{sup {minus}1} is required for the sample exhibiting the most extreme ({sup 226}Ra/{sup 230}Th) disequilibrium; these fluxes are much higher than those that can be inferred from net mass transfers of stable species.

  9. Preliminary study of iron removal from hydrochloric pickling liquor by ion exchange

    SciTech Connect (OSTI)

    Maranon, E.; Suarez, F.; Alonso, F.; Fernandez, Y.; Sastre, H. [Univ. of Oviedo, Asturias (Spain). Dept. of Chemical and Environmental Engineering] [Univ. of Oviedo, Asturias (Spain). Dept. of Chemical and Environmental Engineering

    1999-07-01

    Hydrochloric acid from exhausted pickling baths is a residue that has to be managed adequately because of its high pollutant potential. In this work, an ion exchange treatment for removing iron from the spent acid was studied in an attempt to make the re-utilization of said acid viable for industry while reducing the amount of waste generated. Several cationic, anionic, and chelating resins were tested. Cationic and chelating resins are able to remove Fe(II) that is present as a cation in the acid, whereas anionic resins are able to remove Fe(III) that forms anionic complexes with the chloride anion. The capacity of the cationic and chelating resins, although not high, does improve as the iron concentration in the hydrochloric acid increases and when the acid concentration decreases, because there is less competition between the ferrous cation and the protons. The anionic resins showed higher capacity for removing iron, especially the Lewatit MP-500, and this capacity also increased with iron concentration.

  10. The effect of pore-regulating agents on the ion-exchange properties of ferrocyanide-aluminosilicate sorbents

    SciTech Connect (OSTI)

    Panasyugin, A.S.; Trofimenko, N.E.; Komarov, V.S.; Rat`ko, A.I.; Masherova, N.P. [Institute of General and Inorganic Chemistry, Minsk (Belarus)

    1994-08-01

    Among the methods of controlling the adsorptive and structural properties of porous materials is the use of pore-regulating agents, which are introduced at different synthesis stages and subsequently removed by washing or calcination to produce a porous structure characterized by either a peaked or bimodal pore-size distribution. The open porous structure thus produced is accessible to reactant molecules, improves diffusion characteristics, and contributes to an increase in both the intensity and rate of saturation of absorbents. Earlier, the authors studied the ion-exchange properties and the mechanism of formation of ferrocyanide-aluminosilicate sorbents prepared by modifying the surface of clinoptilolite with ferrocyanides of heavy metals. The application of ferrocyanides (FCs) onto the aluminosilicate surface renders diffusion much easier than in the case of pure ferrocyanides and enhances the sorbent selectivity for cesium ions. The purpose of this work is to study the effect of pore-regulation agents that are introduced during preparation of composite sorbents on the ion-exchange properties of these sorbents with respect to alkali ions (Cs{sup +}, Na{sup +}, and Li{sup +}). Analysis of the kinetic curves demonstrates that modification by ferrocyanides in the presence of boric acid causes a decrease in the internal diffusion rates during the exchange of H{sup +} for Li{sup +}, Na{sup +}, and Cs{sup +} by 2.6, 2.1, and 0.2 times respectively. The introduction of pore-regulating agents was found to increase the selectivity of the modified samples for {sup 137}Cs by 1.8-6.7 and 1.5-2.2 times in comparison with the starting clinoptilolite and sorbents prepared without pore-regulating agents. This allow the use of ferrocyanide-aluminosilicate materials as selective sorbents for the {sup 137}Cs ion in the presence of considerable amounts of other ions.

  11. -Supporting Information-2 Patterned ion exchange membranes for improved power production in4

    E-Print Network [OSTI]

    ) 451-8628701723 24 25 26 *Corresponding Author27 28 29 #12;2 PTFE Plate Polymersolution PTFE Plate Membrane Smooth cation exchange membrane Smooth anion exchange membrane (A) (B) 30 31

  12. Aspects of the physics, chemistry, and technology of high intensity heavy ion sources

    SciTech Connect (OSTI)

    Alton, G.D.

    1980-01-01

    Particular emphasis is placed on the technology of plasma discharge ion sources which utilize solid elemental or molecular compounds to produce vapor for the ionization process. A brief discussion is made of the elementary concepts underlying the formation and extraction of ion beams from plasma discharge sources. A limited review of low charge state positive ion sources suitable for accelerator use is also given.

  13. Technology Development Roadmap for the Advanced High Temperature Reactor Secondary Heat Exchanger

    SciTech Connect (OSTI)

    P. Sabharwall; M. McCllar; A. Siahpush; D. Clark; M. Patterson; J. Collins

    2012-09-01

    This Technology Development Roadmap (TDRM) presents the path forward for deploying large-scale molten salt secondary heat exchangers (MS-SHX) and recognizing the benefits of using molten salt as the heat transport medium for advanced high temperature reactors (AHTR). This TDRM will aid in the development and selection of the required heat exchanger for: power production (the first anticipated process heat application), hydrogen production, steam methane reforming, methanol to gasoline production, or ammonia production. This TDRM (a) establishes the current state of molten salt SHX technology readiness, (b) defines a path forward that systematically and effectively tests this technology to overcome areas of uncertainty, (c) demonstrates the achievement of an appropriate level of maturity prior to construction and plant operation, and (d) identifies issues and prioritizes future work for maturing the state of SHX technology. This study discusses the results of a preliminary design analysis of the SHX and explains the evaluation and selection methodology. An important engineering challenge will be to prevent the molten salt from freezing during normal and off-normal operations because of its high melting temperature (390°C for KF ZrF4). The efficient transfer of energy for industrial applications depends on the ability to incorporate cost-effective heat exchangers between the nuclear heat transport system and industrial process heat transport system. The need for efficiency, compactness, and safety challenge the capabilities of existing heat exchanger technology. The description of potential heat exchanger configurations or designs (such as printed circuit, spiral or helical coiled, ceramic, plate and fin, and plate type) were covered in an earlier report (Sabharwall et al. 2011). Significant future work, much of which is suggested in this report, is needed before the benefits and full potential of the AHTR can be realized. The execution of this TDRM will focuses research efforts on the near-term qualification, selection, or maturation strategy as detailed in this report. Development of the integration methodology feasibility study, along with research and development (R&D) needs, are ongoing tasks that will be covered in the future reports as work progresses. Section 2 briefly presents the integration of AHTR technology with conventional chemical industrial processes., See Idaho National Laboratory (INL) TEV-1160 (2011) for further details

  14. Investigation of the effect of intra-molecular interactions on the gas-phase conformation of peptides as probed by ion mobility-mass spectrometry, gas-phase hydrogen/deuterium exchange, and molecular mechanics 

    E-Print Network [OSTI]

    Sawyer, Holly Ann

    2006-04-12

    Ion mobility-mass spectrometry (IM-MS), gas-phase hydrogen/deuterium (H/D) exchange ion molecule reactions and molecular modeling provide complimentary information and are used here for the characterization of peptide ion structure, including fine...

  15. RHEOLOGY OF SETTLED SOLIDS IN THE SMALL COLUMN ION EXCHANGE PROCESS

    SciTech Connect (OSTI)

    Ferguson, C.; Prior, M.; Koopman, D.; Edwards, T.

    2011-06-20

    The Small Column Ion Exchange (SCIX) process is being developed to remove cesium, strontium, and actinides from Savannah River Site (SRS) Liquid Waste using an existing waste tank as process housing. This method includes the addition of monosodium titanate (MST) to a waste tank containing salt solution and entrained sludge solids, followed by tank mixing and filtration. The filtrate is then processed through in-tank ion exchange columns containing crystalline silicotitanate (CST) media. While the process is operating, it is known that solid particles begin to settle in the tank and temperatures may reach beyond 45 C. Previous testing has shown that sludge-MST slurries that sit for extended periods at elevated temperatures can develop large shear strengths, making them difficult to resuspend and remove from the tank. The authors conducted rheological testing of mixtures containing various concentrations of sludge simulant, MST, and CST (three preparations) that were aged at different times (i.e., 0 to 13 weeks) and isothermally maintained to 30, 45, or 60 C. Two types of grinding methodologies were employed to prepare CST for this testing, herein called Savannah River National Laboratory (SRNL) and Vitreous State Laboratory (VSL) ground materials. Unground CST particles were also tested. A small number of samples were irradiated prior to 4 week settling and 60 C temperature treatment, with exposures ranging from 0 to 100 MRad. Additional tests are also being conducted that will allow the solid particles to settle at 45 C for 6, 12, and 24 months. The objectives of this task are to determine the impact of feed composition, settling time, and temperature on the shear strength, yield stress, and consistency of the slurries and to determine the impact of radiation on slurry rheology. The testing will determine the relative impact of these parameters rather than predict the shear strength, yield stress, and consistency as a function of feed and operating conditions. This document describes the rheology of slurries containing MST, CST, and simulated sludge that sat at indicated temperatures for up to 13 weeks. A previous SRNL report described preliminary rheology data of slurries containing MST and sludge. Preliminary results of the irradiation tests are also presented in this report, though additional data are still being collected. Rheology of the long term settling samples (6, 12, and 24 months) and additional irradiation test results will be reported at a later date. Conclusions from this analysis are as follows: (1) Slurries containing MST and unground CST have the largest shear strength. Due to the high shear strengths measured in slurries containing unground CST, evaluations of specific tank contents and mixing capability should be performed prior to any addition of this material into a waste tank. Experimentally determined shear strengths indicate mixing could be problematic in mixtures containing unground CST. (2) Increasing the ground CST fraction in the slurry increases the slurry shear strength, yield stress, and consistency. (3) Increasing the sludge fraction in the slurry decreases the slurry shear strength, yield stress, and consistency. (4) Slurries containing VSL ground CST have larger shear strength, yield stress, and consistency than slurries containing SRNL ground CST. (5) The effects of settling time and temperature on slurry shear strength are slurry dependent. (6) No effects of settling time and temperature on slurry yield stress or consistency were observed. (7) Radiation up to 100 MRad does not appear to affect properties of shear strength, yield stress, or consistency of process feeds.

  16. REAL WASTE TESTING OF SPHERICAL RESORCINOL-FORMALDEHYDE ION EXCHANGE RESIN

    SciTech Connect (OSTI)

    Nash, C.; Duignan, M.

    2009-10-30

    This report presents data on batch contact and column testing tasks for spherical resorcinol-formaldehyde (sRF) resin. The testing used a non-radioactive simulant of SRS Tank 2F dissolved salt, as well as an actual radioactive waste sample of similar composition, which are both notably high in sodium (6 M). The resin was Microbeads batch 5E-370/641 which had been made on the hundred gallon scale. Equilibrium batch contact work focused on cesium at a temperature of 25 C due to the lack of such data to better benchmark existing isotherm models. Two campaigns were performed with small-scale ion exchange columns, first with Tank 2F simulant, then with actual dissolved salt in the Shielded Cells. An extrapolation of the batch contact results with radioactive waste over-predicted the cesium loaded onto the IX sRF resin bed by approximately 11%. This difference is not unexpected considering uncertainties from measurement and extrapolation and because the ion exchange that occurs when waste flows through a resin bed probably cannot reach the same level of equilibrium as when waste and resin are joined in a long term batch contact. Resin was also characterized to better understand basic chemistry issues such as holdup of trace transition metals present in the waste feed streams. The column tests involved using two beds of sRF resin in series, with the first bed referred to as the Lead column and the second bed as the Lag column. The test matrix included two complete IX cycles for both the simulant and actual waste phases. A cycle involves cesium adsorption, until the resin in the Lead column reaches saturation, and then regenerating the sRF resin, which includes eluting the cesium. Both the simulated and the actual wastes were treated with two cycles of operation, and the resin beds that were used in the Lead and Lag columns of simulant test phase were regenerated and reused in the actual waste test phase. This task is the first to demonstrate the treatment of SRS waste with sRF resin and the tests clearly demonstrated cesium decontamination for actual waste. The results of the column tests were similar for both the simulated and the actual waste and demonstrated Cs removal with sRF from both wastes. For a flowrate of 1.4 bed volumes (BV)/hour at 25 C those results with sRF resin were: (1) Simulant and actual waste results are equivalent; (2) Cs breakthrough began between 200 and 250 BV; (3) Cs breakthrough reached 100% at around 400 BV; (4) Cs breakthrough curve from 5% to 100% is approximately linear; (5) Cs elution with 0.5 M HNO3 starts at 2 BV and ends at 6BV; (6) Most, if not all, of Cs adsorbed during treatment is released during elution; (7) At 100% breakthrough of Cs the resin bed adsorbs approximately 85% of full capacity before detection in the effluent; the remaining 15% is adsorbed at saturation; (8) Approximately 90% of resin bed changes (color and volume) are complete by 6 BV; and (9) During elution the resin shrinks to about 80% of its fully working (sodium form) BV.

  17. The synthesis and characterization of Zirconium p-Phenylbis(phosphonate) Phosphate and other Zirconium Arylbis(phosphonates) for the application of ion exchange 

    E-Print Network [OSTI]

    Bellinghausen, Paul Christian

    1995-01-01

    . These materials showed promise for many uses, of greatest interest were of catalysis and ion exchange. Zirconium p-Phenylbis(phosphonate) Phosphate was synthesized by several routes to investigate the inherent structural characteristics as they applied...

  18. SCALING SOLID RESUSPENSION AND SORPTION FOR THE SMALL COLUMN ION EXCHANGE PROCESSING TANK

    SciTech Connect (OSTI)

    Poirier, M.; Qureshi, Z.

    2010-12-14

    The Small Column Ion Exchange (SCIX) process is being developed to remove cesium, strontium, and actinides from Savannah River Site (SRS) Liquid Waste using an existing 1.3 million gallon waste tank (i.e., Tank 41H) to house the process. Savannah River National Laboratory (SRNL) is conducting pilot-scale mixing tests to determine the pump requirements for suspending and resuspending Monosodium Titanate (MST), Crystalline Silicotitanate (CST), and simulated sludge. In addition, SRNL will also be conducting pilot-scale tests to determine the mixing requirements for the strontium and actinide sorption. As part of this task, the results from the pilot-scale tests must be scaled up to a full-scale waste tank. This document describes the scaling approach. The pilot-scale tank is a 1/10.85 linear scale model of Tank 41H. The tank diameter, tank liquid level, pump nozzle diameter, pump elevation, and cooling coil diameter are all 1/10.85 of their dimensions in Tank 41H. The pump locations correspond to the proposed locations in Tank 41H by the SCIX Program (Risers B5 and B2 for two pump configurations and Risers B5, B3, and B1 for three pump configurations). MST additions are through Riser E1, the proposed MST addition riser in Tank 41H. To determine the approach to scaling the results from the pilot-scale tank to Tank 41H, the authors took the following approach. They reviewed the technical literature for methods to scale mixing with jets and suspension of solid particles with jets, and the technical literature on mass transfer from a liquid to a solid particle to develop approaches to scaling the test data. SRNL assembled a team of internal experts to review the scaling approach and to identify alternative approaches that should be considered.

  19. Selective catalytic reduction of NOx with NH3 over a Cu-SSZ-13 catalyst prepared by a solid state ion exchange method

    SciTech Connect (OSTI)

    Wang, Di; Gao, Feng; Peden, Charles HF; Li, Junhui; Kamasamudram, Krishna; Epling, William S.

    2014-06-01

    A novel solid state method was developed to synthesize Cu-SSZ-13 catalysts with excellent NH3-SCR performance and durable hydrothermal stability. After the solid state ion exchange (SSIE) process, the SSZ framework structure and surface area was maintained. In-situ DRIFTS and NH3-TPD experiments provide evidence that isolated Cu ions were successfully exchanged into the pores, which are the active centers for the NH3-SCR reaction.

  20. International technology exchange in support of the Defense Waste Processing Facility wasteform production

    SciTech Connect (OSTI)

    Kitchen, B.G.

    1989-08-23

    The nearly completed Defense Waste Processing Facility (DWPF) is a Department of Energy (DOE) facility at the Savannah River Site that is designed to immobilize defense high level radioactive waste (HLW) by vitrification in borosilicate glass and containment in stainless steel canisters suitable for storage in the future DOE HLW repository. The DWPF is expected to start cold operation later this year (1990), and will be the first full scale vitrification facility operating in the United States, and the largest in the world. The DOE has been coordinating technology transfer and exchange on issues relating to HLW treatment and disposal through bi-lateral agreements with several nations. For the nearly fifteen years of the vitrification program at Savannah River Laboratory, over two hundred exchanges have been conducted with a dozen international agencies involving about five-hundred foreign national specialists. These international exchanges have been beneficial to the DOE`s waste management efforts through confirmation of the choice of the waste form, enhanced understanding of melter operating phenomena, support for paths forward in political/regulatory arenas, confirmation of costs for waste form compliance programs, and establishing the need for enhancements of melter facility designs. This paper will compare designs and schedules of the international vitrification programs, and will discuss technical areas where the exchanges have provided data that have confirmed and aided US research and development efforts, impacted the design of the DWPF and guided the planning for regulatory interaction and product acceptance.

  1. International technology exchange in support of the Defense Waste Processing Facility wasteform production

    SciTech Connect (OSTI)

    Kitchen, B.G.

    1989-08-23

    The nearly completed Defense Waste Processing Facility (DWPF) is a Department of Energy (DOE) facility at the Savannah River Site that is designed to immobilize defense high level radioactive waste (HLW) by vitrification in borosilicate glass and containment in stainless steel canisters suitable for storage in the future DOE HLW repository. The DWPF is expected to start cold operation later this year (1990), and will be the first full scale vitrification facility operating in the United States, and the largest in the world. The DOE has been coordinating technology transfer and exchange on issues relating to HLW treatment and disposal through bi-lateral agreements with several nations. For the nearly fifteen years of the vitrification program at Savannah River Laboratory, over two hundred exchanges have been conducted with a dozen international agencies involving about five-hundred foreign national specialists. These international exchanges have been beneficial to the DOE's waste management efforts through confirmation of the choice of the waste form, enhanced understanding of melter operating phenomena, support for paths forward in political/regulatory arenas, confirmation of costs for waste form compliance programs, and establishing the need for enhancements of melter facility designs. This paper will compare designs and schedules of the international vitrification programs, and will discuss technical areas where the exchanges have provided data that have confirmed and aided US research and development efforts, impacted the design of the DWPF and guided the planning for regulatory interaction and product acceptance.

  2. Enhancement of exchange bias and training effect in ion-beam sputtered Fe{sub 46}Mn{sub 54}/Ni{sub 81}Fe{sub 19} bilayers

    SciTech Connect (OSTI)

    Fulara, Himanshu; Chaudhary, Sujeet, E-mail: sujeetc@physics.iitd.ac.in; Kashyap, Subhash C. [Thin Film Laboratory, Department of Physics, Indian Institute of Technology Delhi, New Delhi 110016 (India); Granville, Simon [Callaghan Innovation, PO Box 31310, Lower Hutt 5040 (New Zealand); The MacDiarmid Institute for Advanced Materials and Nanotechnology, Lower Hutt (New Zealand)

    2014-01-28

    We present a remarkable enhancement by 300% of the exchange-bias field at room temperature, without affecting the coercivity value, via optimum magnetic annealing (250?°C/3 kOe) in ion-beam sputtered FeMn(30?nm)/NiFe(10?nm) bilayers. This specific behavior has been attributed to a higher degree of ?-FeMn(111) orientation that offers more interfacial FeMn moments to get pinned with the moments of the adjacent NiFe layer. Unlike the absence of training effect at room temperature, a pronounced training effect and an accompanying magnetization reversal asymmetry are evidenced upon field cooling below 50?K due to the presence of biaxial exchange induced anisotropy across the interdiffused FeMn/NiFe interface. The present findings not only have technological significance but also are of relevance to the understanding of interfacial spin disorder and frustration in these exchange-biased systems.

  3. PILOT SCALE TESTING OF MONOSODIUM TITANATE MIXING FOR THE SRS SMALL COLUMN ION EXCHANGE PROCESS - 11224

    SciTech Connect (OSTI)

    Poirier, M.; Restivo, M.; Williams, M.; Herman, D.; Steeper, T.

    2011-01-25

    The Small Column Ion Exchange (SCIX) process is being developed to remove cesium, strontium, and select actinides from Savannah River Site (SRS) Liquid Waste using an existing waste tank (i.e., Tank 41H) to house the process. Savannah River National Laboratory (SRNL) is conducting pilot-scale mixing tests to determine the pump requirements for suspending monosodium titanate (MST), crystalline silicotitanate (CST), and simulated sludge. The purpose of this pilot scale testing is to determine the requirements for the pumps to suspend the MST particles so that they can contact the strontium and actinides in the liquid and be removed from the tank. The pilot-scale tank is a 1/10.85 linear scaled model of SRS Tank 41H. The tank diameter, tank liquid level, pump nozzle diameter, pump elevation, and cooling coil diameter are all 1/10.85 of their dimensions in Tank 41H. The pump locations correspond to the proposed locations in Tank 41H by the SCIX program (Risers B5 and B2 for two pump configurations and Risers B5, B3, and B1 for three pump configurations). The conclusions from this work follow: (i) Neither two standard slurry pumps nor two quad volute slurry pumps will provide sufficient power to initially suspend MST in an SRS waste tank. (ii) Two Submersible Mixer Pumps (SMPs) will provide sufficient power to initially suspend MST in an SRS waste tank. However, the testing shows the required pump discharge velocity is close to the maximum discharge velocity of the pump (within 12%). (iii) Three SMPs will provide sufficient power to initially suspend MST in an SRS waste tank. The testing shows the required pump discharge velocity is 66% of the maximum discharge velocity of the pump. (iv) Three SMPs are needed to resuspend MST that has settled in a waste tank at nominal 45 C for four weeks. The testing shows the required pump discharge velocity is 77% of the maximum discharge velocity of the pump. Two SMPs are not sufficient to resuspend MST that settled under these conditions.

  4. Vehicle Technologies Office Merit Review 2015: Lithium-Ion Battery Production and Recycling Materials Issues

    Broader source: Energy.gov [DOE]

    Presentation given by Argonne National Laboratory at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about lithium-ion...

  5. Vehicle Technologies Office Merit Review 2015: Optimization of Ion Transport in High-Energy Composite Cathodes

    Broader source: Energy.gov [DOE]

    Presentation given by UC San Diego at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about optimization of ion transport in...

  6. UV and EB Curable Binder Technology for Lithium Ion Batteries and UltraCapacitors

    SciTech Connect (OSTI)

    Voelker, Gary

    2012-04-30

    the basic feasibility of using UV curing technology to produce Lithium ion battery electrodes at speeds over 200 feet per minute has been shown. A unique set of UV curable chemicals were discovered that were proven to be compatible with a Lithium ion battery environment with the adhesion qualities of PVDF.

  7. Method of uranium reclamation from aqueous systems by reactive ion exchange. [US DOE patent application; anion exchange resin of copolymerized divinyl-benzene and styrene having quarternary ammonium groups and bicarbonate ligands

    DOE Patents [OSTI]

    Maya, L.

    1981-11-05

    A reactive ion exchange method for separation and recovery of values of uranium, neptunium, plutonium, or americium from substantially neutral aqueous systems of said metals comprises contacting said system with an effective amount of a basic anion exchange resin of copolymerized divinyl-benzene and styrene having quarternary ammonium groups and bicarbonate ligands to achieve nearly 100% sorption of said actinyl ion onto said resin and an aqueous system practically free of said actinyl ions. The method is operational over an extensive range of concentrations from about 10/sup -6/ M to 1.0 M actinyl ion and a pH range of about 4 to 7. The method has particulr application to treatment of waste streams from Purex-type nuclear fuel reprocessing facilities and hydrometallurgical processes involving U, Np, P, or Am.

  8. Phosphonic acid based exchange resins

    DOE Patents [OSTI]

    Horwitz, E.P.; Alexandratos, S.D.; Gatrone, R.C.; Chiarizia, R.

    1995-09-12

    An ion exchange resin is described for extracting metal ions from a liquid waste stream. An ion exchange resin is prepared by copolymerizing a vinylidene diphosphonic acid with styrene, acrylonitrile and divinylbenzene. 10 figs.

  9. Phosphonic acid based exchange resins

    DOE Patents [OSTI]

    Horwitz, E. Philip (Naperville, IL); Alexandratos, Spiro D. (Knoxville, TN); Gatrone, Ralph C. (Naperville, IL); Chiarizia, Ronato (Oak Park, IL)

    1995-01-01

    An ion exchange resin for extracting metal ions from a liquid waste stream. An ion exchange resin is prepared by copolymerizing a vinylidene diphosphonic acid with styrene, acrylonitrile and divinylbenzene.

  10. Exchange and polarization effects on elastic electron-atom/ion scattering

    E-Print Network [OSTI]

    Kaganovich, Igor

    ~V d IonsElectrons Secondary emission electrons E 11 equation for species coupled with 1 for electric approaches Needed for modeling and simulations : · accurate atomic and molecular data (, d/d, , rates

  11. Ion exchange behavior among metal trisilicates: probing selectivity, structures, and mechanism 

    E-Print Network [OSTI]

    Fewox, Christopher Sean

    2008-10-10

    with divalent cations.18 Exhaustive exchange of K2TiSi3O9•H2O with various cations at neutral pH gave the selectivity series Mn2+, Ca2+, > Sr2+ >Cs+. The crystal structures derived from powder data showed great disorder in the cation sites of all... site was more selective than the exchange site in the larger tunnel. It was also demonstrated that changing the size of the unit cell through isomorphous substitution of the octahedral M4+ metal altered the selectivity of the material. Those...

  12. Core-ion temperature measurement of the ADITYA tokamak using passive charge exchange neutral particle energy analyzer

    SciTech Connect (OSTI)

    Pandya, Santosh P.; Ajay, Kumar; Mishra, Priyanka; Dhingra, Rajani D.; Govindarajan, J. [Institute for Plasma Research, Bhat, Gandhinagar 382 428, Gujarat (India)

    2013-02-15

    Core-ion temperature measurements have been carried out by the energy analysis of passive charge exchange (CX) neutrals escaping out of the ADITYA tokamak plasma (minor radius, a= 25 cm and major radius, R= 75 cm) using a 45 Degree-Sign parallel plate electrostatic energy analyzer. The neutral particle analyzer (NPA) uses a gas cell configuration for re-ionizing the CX-neutrals and channel electron multipliers (CEMs) as detectors. Energy calibration of the NPA has been carried out using ion-source and {Delta}E/E of high-energy channel has been found to be {approx}10%. Low signal to noise ratio (SNR) due to VUV reflections on the CEMs was identified during the operation of the NPA with ADITYA plasma discharges. This problem was rectified by upgrading the system by incorporating the additional components and arrangements to suppress VUV radiations and improve its VUV rejection capabilities. The noise rejection capability of the NPA was experimentally confirmed using a standard UV-source and also during the plasma discharges to get an adequate SNR (>30) at the energy channels. Core-ion temperature T{sub i}(0) during flattop of the plasma current has been measured to be up to 150 eV during ohmically heated plasma discharges which is nearly 40% of the average core-electron temperature (typically T{sub e}(0) {approx} 400 eV). The present paper describes the principle of tokamak ion temperature measurement, NPA's design, development, and calibration along with the modifications carried out for minimizing the interference of plasma radiations in the CX-spectrum. Performance of the NPA during plasma discharges and experimental results on the measurement of ion-temperature have also been reported here.

  13. Synthesis and Evaluation of Cu/SAPO-34 Catalysts for NH3-SCR 2: Solid-state Ion Exchange and One-pot Synthesis

    SciTech Connect (OSTI)

    Gao, Feng; Walter, Eric D.; Washton, Nancy M.; Szanyi, Janos; Peden, Charles HF

    2015-01-01

    Cu-SAPO-34 catalysts are synthesized using two methods: solid-state ion exchange (SSIE) and one-pot synthesis. SSIE is conducted by calcining SAPO-34/CuO mixtures at elevated temperatures. For the one-pot synthesis method, Cu-containing chemicals (CuO and CuSO4) are added during gel preparation. A high-temperature calcination step is also needed for this method. Catalysts are characterized with surface area/pore volume measurements, temperature programmed reduction (TPR), electron paramagnetic resonance (EPR) and nuclear magnetic resonance (NMR) spectroscopies, and scanning electron microscopy (SEM). Catalytic properties are examined using standard ammonia selective catalytic reduction (NH3-SCR) and ammonia oxidation reactions. In Cu-SAPO-34 samples formed using SSIE, Cu presents both as isolated Cu2+ ions and unreacted CuO. The former is highly active and selective in NH3-SCR, while the latter catalyzes a side reaction; notably, the non-selective oxidation of NH3 above 350 ºC. Using the one-pot method followed by a high-temperature aging treatment, it is possible to form Cu SAPO-34 samples with predominately isolated Cu2+ ions at low Cu loadings. However at much higher Cu loadings, isolated Cu2+ ions that bind weakly with the CHA framework and CuO clusters also form. These Cu moieties are very active in catalyzing non-selective NH3 oxidation above 350 ºC. Low-temperature reaction kinetics indicate that Cu-SAPO-34 samples formed using SSIE have core-shell structures where Cu is enriched in the shell layers; while Cu is more evenly distributed within the one-pot samples. Reaction kinetics also suggest that at low temperatures, the local environment next to Cu2+ ion centers plays little role on the overall catalytic properties. The authors gratefully acknowledge the US Department of Energy (DOE), Energy Efficiency and Renewable Energy, Vehicle Technologies Office for the support of this work. The research described in this paper was performed at the Environmental Molecular Sciences Laboratory (EMSL), a national scientific user facility sponsored by the DOE’s Office of Biological and Environmental Research and located at Pacific Northwest National Laboratory (PNNL). PNNL is operated for the US DOE by Battelle under contract number DE-AC05-76RL01830. The authors also thank Shari Li (PNNL) for surface area/pore volume measurements, and Bruce W. Arey (PNNL) for SEM measurements. Discussions with Drs. A. Yezerets, K. Kamasamudram, J.H. Li, N. Currier and J.Y. Luo from Cummins, Inc. and H.Y. Chen and H. Hess from Johnson-Matthey are greatly appreciated.

  14. Developments in lithium-ion battery technology in the Peoples Republic of China.

    SciTech Connect (OSTI)

    Patil, P. G.; Energy Systems

    2008-02-28

    Argonne National Laboratory prepared this report, under the sponsorship of the Office of Vehicle Technologies (OVT) of the U.S. Department of Energy's (DOE's) Office of Energy Efficiency and Renewable Energy, for the Vehicles Technologies Team. The information in the report is based on the author's visit to Beijing; Tianjin; and Shanghai, China, to meet with representatives from several organizations (listed in Appendix A) developing and manufacturing lithium-ion battery technology for cell phones and electronics, electric bikes, and electric and hybrid vehicle applications. The purpose of the visit was to assess the status of lithium-ion battery technology in China and to determine if lithium-ion batteries produced in China are available for benchmarking in the United States. With benchmarking, DOE and the U.S. battery development industry would be able to understand the status of the battery technology, which would enable the industry to formulate a long-term research and development program. This report also describes the state of lithium-ion battery technology in the United States, provides information on joint ventures, and includes information on government incentives and policies in the Peoples Republic of China (PRC).

  15. Synthesis, characterization, and ion exchange properties of a sodium nonatitanate, Na4Ti9O20.xH2O 

    E-Print Network [OSTI]

    Graziano, Gina Marie

    1998-01-01

    of these problems, the waste needs to be removed from these tanks and given permanent, safe storage. The purpose of this research is to produce a more efficient ion exchanger to separate the highly radioactive isotopes (9oSr, 137 Cs and transuranics) from the large...

  16. Adsorption of Hydrofluorocarbons HFC-134 and HFC-134A on X and Y Zeolites: Effect of Ion-Exchange on Selectivity and Heat of Adsorption

    E-Print Network [OSTI]

    Siperstein, Flor R.

    Adsorption of Hydrofluorocarbons HFC-134 and HFC-134A on X and Y Zeolites: Effect of Ion-Exchange on Selectivity and Heat of Adsorption Scott Savitz, Flor R. Siperstein, Robert Huber, Stephen M. Tieri, Raymond J Adsorption isotherms and heats of adsorption were measured for HFC-134 (1,1,2,2-tetrafluoroethane) and HFC

  17. X-RAY SIGNATURE OF CHARGE EXCHANGE IN L-SHELL SULFUR IONS

    SciTech Connect (OSTI)

    Frankel, M.; Beiersdorfer, P.; Brown, G. V.; Gu, M. F. [Lawrence Livermore National Laboratory, CA, 94550 (United States); Kelley, R. L.; Kilbourne, C. A.; Porter, F. S. [NASA/Goddard Space Flight Center, Greenbelt, MD, 20771 (United States)], E-mail: frankel4@llnl.gov, E-mail: beiersdorfer1@llnl.gov

    2009-09-01

    The X-ray signature of L-shell charge exchange in sulfur was studied in the laboratory. A comparison of the charge exchange (CX) spectra with those obtained under electron-impact excitation showed marked differences. In the CX spectra, an enhancement was observed in the transitions from levels with high principal quantum numbers, n = 4, 5, 6 {yields} n = 2 in comparison with the n = 3 {yields} n = 2 transitions that dominate the direct excitation spectra. An even greater enhancement was recorded in the transitions from the levels of electron capture to the ground states: n = 7, 8, 9 {yields} n = 2. The spectra mainly consist of emission from S XIV, but lower charge states such as S XIII, S XII, and S XI also contribute. The results have been compared with observations made by the Chandra and XMM-Newton X-ray Observatories of Jupiter's polar regions. The enhancement we noticed in transitions from the high-n levels is not seen in the Chandra spectra.

  18. Short-time hydrothermal synthesis and delamination of ion exchangeable Mg/Ga layered double hydroxides

    SciTech Connect (OSTI)

    Unal, Ugur [Department of Nano Science and Technology, Faculty of Engineering, Kumamoto University, Kurokami 2-39-1, Kumamoto 860-8555 (Japan)], E-mail: ugurunal@chem.kumamoto-u.ac.jp

    2007-09-15

    The hydrothermal synthesis of magnesium-gallium layered double hydroxides (Mg/Ga LDHs) was studied under static and agitated conditions. Not only well-crystallized and large-sized Mg/Ga LDHs having hexagonal morphology were obtained but also the reaction time was comparatively decreased from 24 to 2 h by means of agitation during hydrothermal synthesis. In static conditions, mainly GaOOH and magnesite phases were formed. The elemental analysis results show that the final Mg/Ga ratio is significantly different from the initial ratio. The reason was attributed to the difference in the hydrolytic behavior of Mg{sup 2+} and Ga{sup 3+}. Furthermore, the anion exchange studies with glycine, dodecyl sulfate, ferrocyanide and ferricyanide were performed to investigate the intercalation behavior of the anions into Mg/Ga LDHs. In addition, delamination of Mg/Ga LDHs was performed in formamide for the glycine exchanged forms. Large size of nanosheets thus obtained can be utilized in the fabrication of functional thin films. - Graphical abstract: Hydrothermal synthesis under agitation resulted in highly crystalline Mg/Ga LDHs slabs in a short time. The LDHs slabs were delaminated into two-dimensional nanosize sheets.

  19. Structure/function studies of resorcinol-formaldehyde (R-F) and phenol-formaldehyde (P-F) copolymer ion-exchange resins

    SciTech Connect (OSTI)

    Hubler, T.L.; Franz, J.A.; Shaw, W.J.; Hogan, M.O.; Hallen, R.T.; Brown, G.N.; Linehan, J.C.

    1996-09-01

    he U.S. Department of Energy`s (DOE) Hanford Site was established to produce plutonium for the U.S. defense mission. Over the course of decades, hazardous, toxic, and radioactive chemical wastes were generated and disposed of in a variety of ways including storage in underground tanks. An estimated 180 million tons of high-level radioactive wastes are stored in 177 underground storage tanks. During production of fissile plutonium, large quantities of 90Sr and 137CS were produced. The high abundance and intermediate length half- lives of these fission products are the reason that effort is directed toward selective removal of these radionuclides from the bulk waste stream before final tank waste disposal is effected. Economically, it is desirable to remove the highly radioactive fraction of the tank waste for vitrification. Ion-exchange technology is being evaluated for removing cesium from Hanford Site waste tanks. This report summarizes data and analysis performed by Pacific Northwest National Laboratory (PNNL)for both resorcinol-formaldehyde (R-F) and phenol-formaldehyde (P-F) resins and relates their observed differences in performance and chemical stability to their structure. The experimental approach used to characterize the resins was conducted using primarily two types of data: batch distribution coefficients (Kds) and solid-state 13C NMR. Comparison of these data for a particular resin allowed correlation of resin performance to resin structure. Additional characterization techniques included solid-state 19F NMR, and elemental analyses.

  20. Method for digesting spent ion exchange resins and recovering actinides therefrom using microwave radiation

    DOE Patents [OSTI]

    Maxwell, III, Sherrod L. (Aiken, SC); Nichols, Sheldon T. (Augusta, GA)

    1999-01-01

    The present invention relates to methods for digesting diphosphonic acid substituted cation exchange resins that have become loaded with actinides, rare earth metals, or heavy metals, in a way that allows for downstream chromatographic analysis of the adsorbed species without damage to or inadequate elution from the downstream chromatographic resins. The methods of the present invention involve contacting the loaded diphosphonic acid resin with concentrated oxidizing acid in a closed vessel, and irradiating this mixture with microwave radiation. This efficiently increases the temperature of the mixture to a level suitable for digestion of the resin without the use of dehydrating acids that can damage downstream analytical resins. In order to ensure more complete digestion, the irradiated mixture can be mixed with hydrogen peroxide or other oxidant, and reirradiated with microwave radiation.

  1. Patterned ion exchange membranes for improved power production in microbial reverse-electrodialysis cells

    E-Print Network [OSTI]

    membrane). The COD removal rate, coulombic efficiency, and energy efficiency of the MRC also increased China e State Key Laboratory of Urban Water Resource and Environment, Harbin Institute of Technology, No surface on one membrane side. Internal resistance was reduced, increasing power in the MRC. Energy

  2. Transport of ions in a segmented linear Paul trap in printed-circuit-board technology

    E-Print Network [OSTI]

    G. Huber; T. Deuschle; W. Schnitzler; R. Reichle; K. Singer; F. Schmidt-Kaler

    2007-11-19

    We describe the construction and operation of a segmented linear Paul trap, fabricated in printed-circuit-board technology with an electrode segment width of 500 microns. We prove the applicability of this technology to reliable ion trapping and report the observation of Doppler cooled ion crystals of Ca-40 with this kind of traps. Measured trap frequencies agree with numerical simulations at the level of a few percent from which we infer a high fabrication accuracy of the segmented trap. To demonstrate its usefulness and versatility for trapped ion experiments we study the fast transport of a single ion. Our experimental results show a success rate of 99.0(1)% for a transport distance of 2x2mm in a round-trip time of T=20us, which corresponds to 4 axial oscillations only. We theoretically and experimentally investigate the excitation of oscillations caused by fast ion transports with error-function voltage ramps: For a slightly slower transport (a round-trip shuttle within T=30us) we observe non-adiabatic motional excitation of 0.89(15)meV.

  3. Preliminary Ion Exchange Modeling for Removal of Cesium from Hanford Waste Using SuperLig 644 Resin

    SciTech Connect (OSTI)

    Hamm, L.L.

    2000-08-23

    A proposed facility is being designed for the immobilization of Hanford high-level radioactive waste. One unit process in the facility is designed to remove radioactive cesium by ion-exchange from the strongly alkaline aqueous phase. A resin specifically designed with high selectivity of cesium under alkaline conditions is being investigated. The resin also is elutable under more acidic conditions. The proposed design of the facility consists of two sets of two packed columns placed in series (i.e., a lead column followed by a lag (guard) column configuration). During operation, upon reaching a specified cesium concentration criterion at the exit of the lag column, operation is switched to the second set of lead and lag columns. The cesium-loaded lead column is processed (i.e., washed and eluted) and switched to the lag position. the previous lag column is then placed in the lead position (without eluting) and the system is ready for use in the next cycle. For a well designed process, the loading and elution processes result in significant volume reductions in aqueous high-level waste.

  4. Preliminary flowsheet: Ion exchange process for the separation of cesium from Hanford tank waste using Duolite{trademark} CS-100 resin

    SciTech Connect (OSTI)

    Eager, K.M.; Penwell, D.L.; Knutson, B.J.

    1994-12-01

    This preliminary flowsheet document describes an ion exchange process which uses Duolite{trademark} CS-100 resin to remove cesium from Hanford Tank waste. The flowsheet describes one possible equipment configuration, and contains mass balances based on that configuration with feeds of Neutralized Current Acid Waste, and Double Shell Slurry Feed. Process alternatives, unresolved issues, and development needs are discussed which relate to the process.

  5. Development and implementation of a FT-ICR mass spectrometer for the investigation of ion conformations of peptide sequence isomers containing basic amino acid residues by gas-phase hydrogen/deuterium exchange 

    E-Print Network [OSTI]

    Marini, Joseph Thomas

    2004-09-30

    The gas-phase hydrogen/deuterium (H/D) exchange of protonated di- and tripeptides containing a basic amino acid residue has been studied with a Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometer. Bimolecular reactions...

  6. Moving fiction : novelists, technology designers, and the art of the exchange

    E-Print Network [OSTI]

    Epstein, Michael, 1969-

    2004-01-01

    How can concepts from literature and technology design combine to create new forms of storytelling on mobile devices? This paper examines the theory and practice of bringing literary techniques into mobile technology design. ...

  7. Vehicle Technologies Office Merit Review 2014: Advanced High Energy Li-Ion Cell for PHEV and EV Applications

    Broader source: Energy.gov [DOE]

    Presentation given by 3M at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about advanced high energy Li-ion cell for PHEV...

  8. DISSOCIATIVE CHARGE EXCHANGE AND IONIZATION OF O2 BY FAST H+ ENERGETIC ION INTERACTIONS IN EUROPA'S OXYGEN

    E-Print Network [OSTI]

    Johnson, Robert E.

    ABSTRACT Measurements of electron capture and ionization of O2 molecules in collisions with H+ and O+ ions to Oþ 2 product formation are shown to be dominant for both the H+ and the O+ projectiles in the capture, and sulfur ions (Cooper et al. 2001; Paranicas et al. 2002). Collisions with these ions can lead

  9. Plasma-based ion implantation and deposition: A review of physics,technology, and applications

    SciTech Connect (OSTI)

    Pelletier, Jacques; Anders, Andre

    2005-05-16

    After pioneering work in the 1980s, plasma-based ion implantation (PBII) and plasma-based ion implantation and deposition (PBIID) can now be considered mature technologies for surface modification and thin film deposition. This review starts by looking at the historical development and recalling the basic ideas of PBII. Advantages and disadvantages are compared to conventional ion beam implantation and physical vapor deposition for PBII and PBIID, respectively, followed by a summary of the physics of sheath dynamics, plasma and pulse specifications, plasma diagnostics, and process modeling. The review moves on to technology considerations for plasma sources and process reactors. PBII surface modification and PBIID coatings are applied in a wide range of situations. They include the by-now traditional tribological applications of reducing wear and corrosion through the formation of hard, tough, smooth, low-friction and chemically inert phases and coatings, e.g. for engine components. PBII has become viable for the formation of shallow junctions and other applications in microelectronics. More recently, the rapidly growing field of biomaterial synthesis makes used of PBII&D to produce surgical implants, bio- and blood-compatible surfaces and coatings, etc. With limitations, also non-conducting materials such as plastic sheets can be treated. The major interest in PBII processing originates from its flexibility in ion energy (from a few eV up to about 100 keV), and the capability to efficiently treat, or deposit on, large areas, and (within limits) to process non-flat, three-dimensional workpieces, including forming and modifying metastable phases and nanostructures. We use the acronym PBII&D when referring to both implantation and deposition, while PBIID implies that deposition is part of the process.

  10. Sabdia's Radial Flow Air Bearing Heat Exchanger

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Sandia's Radial Flow ir Bearing Heat Exchanger 2014 Building Technologies Office Peer Review Sandia's TRL 5 Air Bearing Heat exchanger technology (a. k. a. The Sandia Cooler)...

  11. U.S.-MEXICO TECHNOLOGY TRANSFER; BILATERAL TECHNICAL EXCHANGES FOR SUSTAINABLE ECONOMIC GROWTH IN THE BORDER REGION

    SciTech Connect (OSTI)

    Jimenez, Richard, D., Dr.

    2007-10-01

    The U.S. Department of Energy (DOE) maintains a strong commitment to transfer the results of its science and technology programs to the private sector. The intent is to apply innovative and sometimes advanced technologies to address needs while simultaneously stimulating new commercial business opportunities. Such focused “technology transfer” was evident in the late 1990s as the results of DOE investments in environmental management technology development led to new tools for characterizing and remediating contaminated sites as well as handling and minimizing the generation of hazardous wastes. The Department’s Office of Environmental Management was attempting to reduce the cost, accelerate the schedule, and improve the efficacy of clean-up efforts in the nuclear weapons complex. It recognized that resulting technologies had broader world market applications and that their commercialization would further reduce costs and facilitate deployment of improved technology at DOE sites. DOE’s Albuquerque Operations Office (now part of the National Nuclear Security Administration) began in 1995 to build the foundation for a technology exchange program with Mexico. Initial sponsorship for this work was provided by the Department’s Office of Environmental Management. As part of this effort, Applied Sciences Laboratory, Inc. (ASL) was contracted by the DOE Albuquerque office to identify Mexico’s priority environmental management needs, identify and evaluate DOE-sponsored technologies as potential solutions for those needs, and coordinate these opportunities with decision makers from Mexico’s federal government. That work led to an improved understanding of many key environmental challenges that Mexico faces and the many opportunities to apply DOE’s technologies to help resolve them. The above results constituted, in large part, the foundation for an initial DOE-funded program to apply the Department’s technology base to help address some of Mexico’s challenging environmental issues. The results also brought focus to the potential contributions that DOE’s science and technology could make for solving the many difficult, multi-generational problems faced by hundreds of bi-national communities along the 2,000-mile shared border of the United States and Mexico. Efforts to address these U.S.-Mexico border issues were initially sponsored by the DOE’s Albuquerque and Carlsbad offices. In subsequent years, the U.S. Congress directed appropriations to DOE’s Carlsbad office to address public health, safety and security issues prevalent within U.S.-Mexico border communities. With ASL’s assistance, DOE’s Albuquerque office developed contacts and formed partnerships with interested U.S and Mexican government, academic, and commercial organizations. Border industries, industrial effluents, and public health conditions were evaluated and documented. Relevant technologies were then matched to environmental problem sets along the border. Several technologies that were identified and subsequently supported by this effort are now operational in a number of U.S.-Mexico border communities, several communities within Mexico’s interior states, and in other parts of Latin America. As a result, some serious public health threats within these communities caused by exposure to toxic airborne pollutants have been reduced. During this time, DOE’s Carlsbad office hosted a bilateral conference to establish a cross-border consensus on what should be done on the basis of these earlier investigative efforts. Participating border region stakeholders set an agenda for technical collaborations. This agenda was supported by several Members of Congress who provided appropriations and directed DOE’s Carlsbad office to initiate technology demonstration projects. During the following two years, more than 12 private-sector and DOE-sponsored technologies were demonstrated in partnership with numerous border community stakeholders. All technologies were well received and their effectiveness at addressing health, safety and security issues w

  12. Chemical and radiation stability of SuperLig{reg_sign}644, resorcinol-formaldehyde, and CS-100 cesium ion exchange materials

    SciTech Connect (OSTI)

    Brown, G.N.; Adami, S.R.; Bray, L.A.

    1995-09-01

    At the request of the Initial Pretreatment Module Project within Westinghouse Hanford Company, Pacific Northwest Laboratory (PNL) conducted this study for the Efficient Separations and Processing Crosscutting Program (ESP) under the task ``Develop and Test Sorbents.`` The purpose of the study was to assess and compare the chemical and radiolytic stability of several cesium-selective ion exchange materials in simulated alkaline Hanford tank waste matrices. Pretreatment of nuclear process wastes to remove of cesium and other radionuclides by ion exchange was proposed previously as one method of minimizing the amount of high-level radioactive waste at Hanford. In this study, PNL evaluated three cesium-selective materials SuperLig{reg_sign}644, resorcinol-formaldehyde (R-F), and CS-100 for chemical and radiation stability in 1 M NaOH and a simulated neutralized current acid waste (NCAW). The objective of the study is to investigate the stability of the newly produced SuperLig{reg_sign}644 under a variety of conditions in an attempt to simulate and predict the degradation process. The following specific conclusions and recommendations resulted from the study.

  13. Calcite dissolution and Ca/Na ion-exchange reactions in columns with different flow rates through high ESR soil 

    E-Print Network [OSTI]

    Navarre, Audrey

    1999-01-01

    min?¹ under conditions of saturated flow. Column eluate was monitored for pH, carbonate alkalinity, and Na, Ca and Cl concentrations to evaluate the elution of SAR 10 solution, dissolution of CaCO? and exchange of Na by Ca on the cation...

  14. Proton exchange membrane materials for the advancement of direct methanol fuel-cell technology

    DOE Patents [OSTI]

    Cornelius, Christopher J. (Albuquerque, NM)

    2006-04-04

    A new class of hybrid organic-inorganic materials, and methods of synthesis, that can be used as a proton exchange membrane in a direct methanol fuel cell. In contrast with Nafion.RTM. PEM materials, which have random sulfonation, the new class of materials have ordered sulfonation achieved through self-assembly of alternating polyimide segments of different molecular weights comprising, for example, highly sulfonated hydrophilic PDA-DASA polyimide segment alternating with an unsulfonated hydrophobic 6FDA-DAS polyimide segment. An inorganic phase, e.g., 0.5 5 wt % TEOS, can be incorporated in the sulfonated polyimide copolymer to further improve its properties. The new materials exhibit reduced swelling when exposed to water, increased thermal stability, and decreased O.sub.2 and H.sub.2 gas permeability, while retaining proton conductivities similar to Nafion.RTM.. These improved properties may allow direct methanol fuel cells to operate at higher temperatures and with higher efficiencies due to reduced methanol crossover.

  15. PAPER STUDY EVALUATIONS OF THE INTRODUCTION OF SMALL COLUMN ION EXCHANGE WASTE STREAMS TO THE DEFENSE WASTE PROCESSING FACILITY

    SciTech Connect (OSTI)

    Fox, K.; Edwards, T.; Stone, M.; Koopman, D.

    2010-06-29

    The objective of this paper study is to provide guidance on the impact of Monosodium Titanate (MST) and Crystalline Silicotitanate (CST) streams from the Small Column Ion Exchange (SCIX) process on the Defense Waste Processing Facility (DWPF) flowsheet and glass waste form. A series of waste processing scenarios was evaluated, including projected compositions of Sludge Batches 8 through 17 (SB8 through SB17), MST additions, CST additions to Tank 40 or to a sludge batch preparation tank (Tank 42 or Tank 51, referred to generically as Tank 51 in this report), streams from the Salt Waste Processing Facility (SWPF), and two canister production rates. A wide array of potential glass frit compositions was used to support this assessment. The sludge and frit combinations were evaluated using the predictive models in the current DWPF Product Composition Control System (PCCS). The results were evaluated based on the number of frit compositions available for a particular sludge composition scenario. A large number of candidate frit compositions (e.g., several dozen to several hundred) is typically a good indicator of a sludge composition for which there is flexibility in forming an acceptable waste glass and meeting canister production rate commitments. The MST and CST streams will significantly increase the concentrations of certain components in glass, such as Nb{sub 2}O{sub 5}, TiO{sub 2}, and ZrO{sub 2}, to levels much higher than have been previously processed at DWPF. Therefore, several important assumptions, described in detail in the report, had to be made in performing the evaluations. The results of the paper studies, which must be applied carefully given the assumptions made concerning the impact of higher Ti, Zr, and Nb concentrations on model validity, provided several observations: (1) There was difficulty in identifying a reasonable number of candidate frits (and in some cases an inability to identify any candidate frits) when a waste loading of 40% is targeted for Sludge Batches 8, 16, and 17, regardless of the addition of SCIX or SWPF streams. This indicates that the blending strategy for these sludge batches should be reevaluated by Savannah River Remediation (SRR). (2) In general, candidate frits were available to accommodate CST additions to either Tank 40 or Tank 51. A larger number of candidate frits were typically available for the sludge batches when CST is added to Tank 51 rather than Tank 40, meaning that more compositional flexibility would be available for frit selection and DWPF operation. Note however that for SB8 and SB17, no candidate frits were available to accommodate CST going to Tank 40 with and without SWPF streams. The addition of SWPF streams generally improves the number of candidate frits available for processing of a given sludge batch. (3) The change in production rate from 40 Sludge Receipt and Adjustment Tank (SRAT) batches per year (i.e., the current production rate) to 75 SRAT batches per year, without SWPF streams included, had varied results in terms of the number of candidate frits available for processing of a given sludge batch. Therefore, this variable is not of much concern in terms of incorporating the SCIX streams. Note that the evaluation at 75 SRAT batches per year (approximately equivalent to 325 canisters per year) is more conservative in terms of the impact of SCIX streams as compared to a production rate of 400 canisters per year. Overall, the outcome of this paper study shows no major issues with the ability to identify an acceptable glass processing window when CST from the SCIX process is transferred to either Tank 40 or Tank 51. The assumptions used and the model limitations identified in this report must be addressed through further experimental studies, which are currently being performed. As changes occur to the planned additions of MST and CST, or to the sludge batch preparation strategy, additional evaluations will be performed to determine the potential impacts. As stated above, the issues with Sludge Batches 8, 16, and 17 should be further evaluated by SRR. A

  16. Heavy-ion double charge exchange reactions: a tool towards 0v\\b{eta}\\b{eta} nuclear matrix elements

    E-Print Network [OSTI]

    Cappuzzello, F; Agodi, C; Bond`?, M; Carbone, D; Cunsolo, A; Foti, A

    2015-01-01

    The knowledge of the nuclear matrix elements for the neutrinoless double beta decay is fundamental for neutrino physics. In this paper, an innovative technique to extract information on the nuclear matrix elements by measuring the cross section of a double charge exchange nuclear reaction is proposed. The basic point is that the initial and final state wave functions in the two processes are the same and the transition operators are similar. The double charge exchange cross sections can be factorized in a nuclear structure term containing the matrix elements and a nuclear reaction factor. First pioneering experimental results for the 40Ca(18O,18Ne)40Ar reaction at 270 MeV incident energy show that such cross section factorization reasonably holds for the crucial 0+ --> 0+ transition to 40Args, at least at very forward angles.

  17. Heavy-ion double charge exchange reactions: a tool towards 0v\\b{eta}\\b{eta} nuclear matrix elements

    E-Print Network [OSTI]

    F. Cappuzzello; M. Cavallaro; C. Agodi; M. Bond`?; D. Carbone; A. Cunsolo; A. Foti

    2015-11-12

    The knowledge of the nuclear matrix elements for the neutrinoless double beta decay is fundamental for neutrino physics. In this paper, an innovative technique to extract information on the nuclear matrix elements by measuring the cross section of a double charge exchange nuclear reaction is proposed. The basic point is that the initial and final state wave functions in the two processes are the same and the transition operators are similar. The double charge exchange cross sections can be factorized in a nuclear structure term containing the matrix elements and a nuclear reaction factor. First pioneering experimental results for the 40Ca(18O,18Ne)40Ar reaction at 270 MeV incident energy show that such cross section factorization reasonably holds for the crucial 0+ --> 0+ transition to 40Args, at least at very forward angles.

  18. Nonlinear ion concentration polarization : fundamentals and applications

    E-Print Network [OSTI]

    Kwak, Rhokyun

    2013-01-01

    Ion exchange membrane (IEM) is a functional material that has a permselectivity of ions. Two types of IEMs - anion exchange membrane (AEM) and cation exchange membrane (CEM) - are used in a variety of electrochemical ...

  19. Experimental data and analysis to support the design of an ion-exchange process for the treatment of Hanford tank waste supernatant liquids

    SciTech Connect (OSTI)

    Kurath, D.E.; Bray, L.A.; Brooks, K.P.; Brown, G.N.; Bryan, S.A.; Carlson, C.D.; Carson, K.J.; DesChane, J.R.; Elovich, R.J.; Kim, A.Y.

    1994-12-01

    Hanford`s 177 underground storage tanks contain a mixture of sludge, salt cake, and alkaline supernatant liquids. Disposal options for these wastes are high-level waste (HLW) glass for disposal in a repository or low-level waste (LLW) glass for onsite disposal. Systems-engineering studies show that economic and environmental considerations preclude disposal of these wastes without further treatment. Difficulties inherent in transportation and disposal of relatively large volumes of HLW make it impossible to vitrify all of the tank waste as HLW. Potential environmental impacts make direct disposal of all of the tank waste as LLW glass unacceptable. Although the pretreatment and disposal requirements are still being defined, most pretreatment scenarios include retrieval of the aqueous liquids, dissolution of the salt cakes, and washing of the sludges to remove soluble components. Most of the cesium is expected to be in the aqueous liquids, which are the focus of this report on cesium removal by ion exchange. The main objectives of the ion-exchange process are removing cesium from the bulk of the tank waste (i.e., decontamination) and concentrating the separated cesium for vitrification. Because exact requirements for removal of {sup 137}Cs have not yet been defined, a range of removal requirements will be considered. This study addresses requirements to achieve {sup 137}Cs levels in LLW glass between (1) the Nuclear Regulatory Commission (NRC) Class C (10 CFR 61) limit of 4600 Ci/m{sup 3} and (2) 1/10th of the NRC Class A limit of 1 Ci/m{sup 3} i.e., 0.1/m{sup 3}. The required degrees of separation of cesium from other waste components is a complex function involving interactions between the design of the vitrification process, waste form considerations, and other HLW stream components that are to be vitrified.

  20. Interplay between water uptake, ion interactions, and conductivity in an e-beam grafted poly(ethylene-co-tetrafluoroethylene) anion exchange membrane

    SciTech Connect (OSTI)

    Pandey, Tara P.; Maes, Ashley M.; Sarode, Himanshu N.; Peters, Bethanne D.; Lavina, Sandra; Vezzù, Keti; Yang, Yuan; Poynton, Simon D.; Varcoe, John R.; Seifert, Soenke; Liberatore, Matthew W.; Di Noto, Vito; Herring, Andrew M.

    2014-12-23

    We demonstrate that the true hydroxide conductivity in an e-beam grafted poly(ethylene-co-tetrafluoroethylene) [ETFE] anion exchange membrane (AEM) is as high as 132 mS cm-1 at 80 °C and 95% RH, comparable to a proton exchange membrane, but with very much less water present in the film. To understand this behaviour we studied ion transport of hydroxide, carbonate, bicarbonate and chloride, as well as water uptake and distribution. Water uptake of the AEM in water vapor is an order of magnitude lower than when submerged in liquid water. In addition 19F pulse field gradient spin echo NMR indicates that there is little tortuosity in the ionic pathways through the film. A complete analysis of the IR spectrum of the AEM and the analyses of water absorption using FT-IR led to conclusion that the fluorinated backbone chains do not interact with water and that two types of water domains exist within the membrane. The reduction in conductivity was measured during exposure of the OH- form of the AEM to air at 95% RH and was seen to be much slower than the reaction of CO2 with OH- as the amount of water in the film determines its ionic conductivity and at relative wet RHs its re-organization is slow.

  1. Interplay between water uptake, ion interactions, and conductivity in an e-beam grafted poly(ethylene-co-tetrafluoroethylene) anion exchange membrane

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Pandey, Tara P.; Maes, Ashley M.; Sarode, Himanshu N.; Peters, Bethanne D.; Lavina, Sandra; Vezzù, Keti; Yang, Yuan; Poynton, Simon D.; Varcoe, John R.; Seifert, Soenke; et al

    2014-12-23

    We demonstrate that the true hydroxide conductivity in an e-beam grafted poly(ethylene-co-tetrafluoroethylene) [ETFE] anion exchange membrane (AEM) is as high as 132 mS cm-1 at 80 °C and 95% RH, comparable to a proton exchange membrane, but with very much less water present in the film. To understand this behaviour we studied ion transport of hydroxide, carbonate, bicarbonate and chloride, as well as water uptake and distribution. Water uptake of the AEM in water vapor is an order of magnitude lower than when submerged in liquid water. In addition 19F pulse field gradient spin echo NMR indicates that there ismore »little tortuosity in the ionic pathways through the film. A complete analysis of the IR spectrum of the AEM and the analyses of water absorption using FT-IR led to conclusion that the fluorinated backbone chains do not interact with water and that two types of water domains exist within the membrane. The reduction in conductivity was measured during exposure of the OH- form of the AEM to air at 95% RH and was seen to be much slower than the reaction of CO2 with OH- as the amount of water in the film determines its ionic conductivity and at relative wet RHs its re-organization is slow.« less

  2. Advanced Technology Development Program for Lithium-Ion Batteries: Gen 2 Performance Evaluation Final Report

    SciTech Connect (OSTI)

    Jon P. Christophersen; Ira Bloom; Edward V. Thomas; Kevin L. Gering; Gary L. Henriksen; Vincent S. Battaglia; David Howell

    2006-07-01

    The Advanced Technology Development Program has completed performance testing of the second generation of lithium-ion cells (i.e., Gen 2 cells). The 18650-size Gen 2 cells, with a baseline and variant chemistry, were distributed over a matrix consisting of three states-of-charge (SOCs) (60, 80, and 100% SOC), four temperatures (25, 35, 45, and 55°C), and three life tests (calendar-, cycle-, and accelerated-life). The calendar- and accelerated-life cells were clamped at an open-circuit voltage corresponding to the designated SOC and were subjected to a once-per-day pulse profile. The cycle-life cells were continuously pulsed using a profile that was centered around 60% SOC. Life testing was interrupted every four weeks for reference performance tests (RPTs), which were used to quantify changes in cell degradation as a function of aging. The RPTs generally consisted of C1/1 and C1/25 static capacity tests, a low-current hybrid pulse power characterization test, and electrochemical impedance spectroscopy. The rate of cell degradation generally increased with increasing test temperature, and SOC. It was also usually slowest for the calendar-life cells and fastest for the accelerated-life cells. Detailed capacity-, power-, and impedance-based performance results are reported.

  3. DOE Technology Performance Exchange

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirleyEnergy A plug-in electricLaboratory | Department ofPotawatomi Community |Barrels3

  4. Evaluation and comparison of SuperLig{reg_sign} 644, resorcinol-formaldehyde and CS-100 ion exchange materials for the removal of cesium from simulated alkaline supernate

    SciTech Connect (OSTI)

    Brown, G.N.; Bray, L.A.; Eloviche, R.J.; Bruening, R.L.; Decker, R.M.; Kafka, T.M.; White, L.R.

    1995-03-01

    PNL evaluated three polymeric materials for Cs removal efficiency from a simulated Hanford Neutralized Current Acid Waste (NCAW) supernatant liquid using 200 mL ion exchange columns. Cs loadings (mmole Cs/g resin) were 0.20, 0.18, and 0.039 for Super Lig 644, R-F, and CS-100 (0.045, 0.070, 0.011 mmole Cs/mL resin). Elution of each resin material with 0.5 M HNO{sub 3} required 3.5, 7.0, and 3.2 cv to reach 0.1 C/C{sub 0} for the respective materials, resulting in volume compressions of 27, 20, and 6.9. Peak Cs concentrations during elution was 185, 38.5, and 27.8 C/C{sub 0}. SuperLig 644 had the highest Cs loading per gram in NCAW and the greatest volume compression on aci elution. Because of high density and poor elution, R-F had the highest Cs loading per unit volume and lower volume compression. CS-100, the baseline material for Cs removal at Hanford, was inferior to both SuperLig 644 and R-F in terms of Cs loading and selectivity over sodium.

  5. Porous polymer monolithic columns with gold nanoparticles as an intermediate ligand for the separation of proteins in reverse phase-ion exchange mixed mode

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Terborg, Lydia; Masini, Jorge C.; Lin, Michelle; Lipponen, Katriina; Riekolla, Marja -Liisa; Svec, Frantisek

    2014-11-04

    A new approach has been developed for the preparation of mixed-mode stationary phases to separate proteins. The pore surface of monolithic poly(glycidyl methacrylate-co-ethylene dimethacrylate) capillary columns was functionalized with thiols and coated with gold nanoparticles. The final mixed mode surface chemistry was formed by attaching, in a single step, alkanethiols, mercaptoalkanoic acids, and their mixtures on the free surface of attached gold nanoparticles. Use of these mixtures allowed fine tuning of the hydrophobic/hydrophilic balance. The amount of attached gold nanoparticles according to thermal gravimetric analysis was 44.8 wt.%. This value together with results of frontal elution enabled calculation of surfacemore »coverage with the alkanethiol and mercaptoalkanoic acid ligands. Interestingly, alkanethiols coverage in a range of 4.46–4.51 molecules/nm2 significantly exceeded that of mercaptoalkanoic acids with 2.39–2.45 molecules/nm2. The mixed mode character of these monolithic stationary phases was for the first time demonstrated in the separations of proteins that could be achieved in the same column using gradient elution conditions typical of reverse phase (using gradient of acetonitrile in water) and ion exchange chromatographic modes (applying gradient of salt in water), respectively.« less

  6. Vehicle Technologies Office Merit Review 2015: High Energy Density Li-ion Cells for EV’s Based on Novel, High Voltage Cathode Material Systems

    Broader source: Energy.gov [DOE]

    Presentation given by Farasis at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about high energy density Li-ion cells for...

  7. SELECTIVE REMOVAL OF STRONTIUM AND CESIUM FROM SIMULATED WASTE SOLUTION WITH TITANATE ION-EXCHANGERS IN A FILTER CARTRIDGE CONFIGURATIONS-12092

    SciTech Connect (OSTI)

    Oji, L.; Martin, K.; Hobbs, D.

    2012-01-03

    Experimental results for the selective removal of strontium and cesium from simulated waste solutions with monosodium titanate and crystalline silicotitanate laden filter cartridges are presented. In these proof-of-principle tests, effective uptake of both strontium-85 and cesium-137 were observed using ion-exchangers in this filter cartridge configuration. At low salt simulant conditions, the instantaneous decontamination factor for strontium-85 with monosodium titanate impregnated filter membrane cartridges measured 26, representing 96% strontium-85 removal efficiency. On the other hand, the strontium-85 instantaneous decontamination factor with co-sintered active monosodium titanate cartridges measured 40 or 98% Sr-85 removal efficiency. Strontium-85 removal with the monosodium titanate impregnated membrane cartridges and crystalline silicotitanate impregnated membrane cartridges, placed in series arrangement, produced an instantaneous decontamination factor of 41 compared to an instantaneous decontamination factor of 368 for strontium-85 with co-sintered active monosodium titanate cartridges and co-sintered active crystalline silicotitanate cartridges placed in series. Overall, polyethylene co-sintered active titanates cartridges performed as well as titanate impregnated filter membrane cartridges in the uptake of strontium. At low ionic strength conditions, there was a significant uptake of cesium-137 with co-sintered crystalline silicotitanate cartridges. Tests results with crystalline silicotitanate impregnated membrane cartridges for cesium-137 decontamination are currently being re-evaluated. Based on these preliminary findings we conclude that incorporating monosodium titanate and crystalline silicotitanate sorbents into membranes represent a promising method for the semicontinuous removal of radioisotopes of strontium and cesium from nuclear waste solutions.

  8. SELECTIVE REMOVAL OF STRONTIUM AND CESIUM FROM SIMULATED WASTE SOLUTION WITH TITANATE ION-EXCHANGERS IN A FILTER CARTRIDGE CONFIGURATIONS-12092

    SciTech Connect (OSTI)

    Oji, L.; Martin, K.; Hobbs, D.

    2011-11-10

    Experimental results for the selective removal of strontium and cesium from simulated waste solutions with monosodium titanate (MST) and crystalline silicotitanate (CST) laden filter cartridges are presented. In these proof-of-principle tests, effective uptake of both Sr-85 and Cs-137 were observed using ion-exchangers in this filter cartridge configuration. At low salt simulant conditions, the instantaneous decontamination factor (D{sub F}) for Sr-85 with MST impregnated filter membrane cartridges measured 26, representing 96% Sr-85 removal efficiency. On the other hand, the Sr-85 instantaneous D{sub F} with co-sintered active MST cartridges measured 40 or 98% Sr-85 removal efficiency. Strontium-85 removal with the MST impregnated membrane cartridges and CST impregnated membrane cartridges, placed in series arrangement, produced an instantaneous decontamination factor of 41 compared to an instantaneous decontamination factor of 368 for strontium-85 with co-sintered active MST cartridges and co-sintered active CST cartridges placed in series. Overall, polyethylene co-sintered active titanates cartridges performed as well as titanate impregnated filter membrane cartridges in the uptake of strontium. At low ionic strength conditions, there was a significant uptake of Cs-137 with co-sintered CST cartridges. Tests results with CST impregnated membrane cartridges for Cs-137 decontamination are currently being re-evaluated. Based on these preliminary findings we conclude that incorporating MST and CST sorbents into membranes represent a promising method for the semi-continuous removal of radioisotopes of strontium and cesium from nuclear waste solutions.

  9. Anion exchange membrane

    DOE Patents [OSTI]

    Verkade, John G; Wadhwa, Kuldeep; Kong, Xueqian; Schmidt-Rohr, Klaus

    2013-05-07

    An anion exchange membrane and fuel cell incorporating the anion exchange membrane are detailed in which proazaphosphatrane and azaphosphatrane cations are covalently bonded to a sulfonated fluoropolymer support along with anionic counterions. A positive charge is dispersed in the aforementioned cations which are buried in the support to reduce the cation-anion interactions and increase the mobility of hydroxide ions, for example, across the membrane. The anion exchange membrane has the ability to operate at high temperatures and in highly alkaline environments with high conductivity and low resistance.

  10. DIVALENT ION EXCHANGE WITH ALKALI

    E-Print Network [OSTI]

    Bunge, A.L.

    2011-01-01

    and Imporved Drilling Methods, Tulsa, OK, Aug. 22-24, 1979.on Enhanced Oil Recovery, Tulsa, OK, Apri120-23, 1980.on Improved Oil Recovery, Tulsa, OK, March 22-24, Radke, C.

  11. Vehicle Technologies Office Merit Review 2014: Fluorinated Electrolyte for 5-V Li-Ion Chemistry

    Broader source: Energy.gov [DOE]

    Presentation given by Argonne National Laboratory at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about fluorinated...

  12. Vehicle Technologies Office Merit Review 2015: Fluorinated Electrolyte for 5-V Li-Ion Chemistry

    Broader source: Energy.gov [DOE]

    Presentation given by Argonne National Laboratory at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about fluorinated...

  13. Vehicle Technologies Office Merit Review 2014: Optimization of Ion Transport in High Energy Composite Cathodes

    Broader source: Energy.gov [DOE]

    Presentation given by University of California San Diego at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about...

  14. Rapid gasification of nascent char in steam atmosphere during the pyrolysis of Na- and Ca-ion-exchanged brown coals in a drop-tube reactor

    SciTech Connect (OSTI)

    Ondej Maek; Sou Hosokai; Koyo Norinaga; Chun-Zhu Li; Jun-ichiro Hayashi [Hokkaido University, Kita-ku (Japan). Center for Advanced Research of Energy Conversion Materials

    2009-09-15

    Several recent studies on in situ steam gasification of coal suggest a possibility of extremely fast steam gasification of char from rapid pyrolysis of pulverized brown coal. The unprecedented rate of char steam gasification can be achieved by exposing nascent char, that is, after tar evolution (temperature range >600{sup o}C), but before devolatilization (<900{sup o}C), to steam in the presence of Na and/or Ca dispersed in/on the char. In this study, we conducted rapid pyrolysis experiments using ion-exchanged Loy Yang brown coal samples, that is, H-form coal with Na/Ca contents <0.001 wt %, Na-form coal with Na content = 2.8 wt % and Ca-form coal with Ca content = 3.2 wt %. These samples were pyrolyzed in an atmospheric drop-tube reactor at a temperature of 900{sup o}C, inlet steam concentration of 50 vol. %, and a particle residence times of 2.8 s. The char yields from the pyrolysis of Na-form and Ca-form coals were as low as 12 and 33% on the respective coal carbon bases, and accounted for only 18 and 53% of the char yields from the full devolatilization of the respective coals at 900{sup o}C. In addition, the pyrolysis also consumed as much as 0.7-1.1 mol of H{sub 2}O per mol of coal C. On the other hand, the nascent char from the H-form coal allowed carbon deposition from the nascent tar, resulting in a char yield as high as 115% of that from the full devolatilization. The chars from the Na-form and Ca-form coals also acted as catalysts for steam reforming of tar, which was evidenced by significant negative synergistic effects of blending of H-form coal with Na-form coal or Ca-form coal on the tar and soot yields. 57 refs., 6 figs.

  15. Vehicle Technologies Office Merit Review 2015: High Energy Anode Material Development for Li-ion Batteries

    Broader source: Energy.gov [DOE]

    Presentation given by Sinode Systems at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about high energy anode material...

  16. Vehicle Technologies Office Merit Review 2014: Metal-Based High Capacity Li-Ion Anodes

    Broader source: Energy.gov [DOE]

    Presentation given by Binghamton University-SUNY at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about metal-based high...

  17. International fuel cycle and waste management technology exchange activities sponsored by the United States Department of Energy: FY 1982 evaluation report

    SciTech Connect (OSTI)

    Lakey, L.T.; Harmon, K.M.

    1983-02-01

    In FY 1982, DOE and DOE contractor personnel attended 40 international symposia and conferences on fuel reprocessing and waste management subjects. The treatment of high-level waste was the topic most often covered in the visits, with geologic disposal and general waste management also being covered in numerous visits. Topics discussed less frequently inlcude TRU/LLW treatment, airborne waste treatment, D and D, spent fuel handling, and transportation. The benefits accuring to the US from technology exchange activities with other countries are both tangible, e.g., design of equipment, and intangible, e.g., improved foreign relations. New concepts initiated in other countries, particularly those with sizable nuclear programs, are beginning to appear in US efforts in growing numbers. The spent fuel dry storage concept originating in the FRG is being considered at numerous sites. Similarly, the German handling and draining concepts for the joule-heated ceramic melter used to vitrify wastes are being incorporated in US designs. Other foreigh technologies applicable in the US include the slagging incinerator (Belgium), the SYNROC waste form (Australia), the decontamination experience gained in decommissioning the Eurochemic reprocessing plant (Belgium), the engineered surface storage of low- and intermediate-level waste (Belgium, FRG, France), the air-cooled storage of vitrified high-level waste (France, UK), waste packaging (Canada, FRG, Sweden), disposal in salt (FRG), disposal in granite (Canada, Sweden), and sea dumping (UK, Belgium, The Netherlands, Switzerland). These technologies did not necessarily originated or have been tried in the US but for various reasons are now being applied and extended in other countries. This growing nuclear technological base in other countires reduces the number of technology avenues the US need follow to develop a solid nuclear power program.

  18. PROJECT W-551 INTERIM PRETREATMENT SYSTEM TECHNOLOGY SELECTION SUMMARY DECISION REPORT AND RECOMMENDATION

    SciTech Connect (OSTI)

    CONRAD EA

    2008-08-12

    This report provides the conclusions of the tank farm interim pretreatment technology decision process. It documents the methodology, data, and results of the selection of cross-flow filtration and ion exchange technologies for implementation in project W-551, Interim Pretreatment System. This selection resulted from the evaluation of specific scope criteria using quantitative and qualitative analyses, group workshops, and technical expert personnel.

  19. LANL: Ion Beam Materials Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    and materials synthesis through ion implantation technology, and radiation damage stud- ies in gases, liquids, and solids. The laboratory's core is a 3.2 MV tandem ion...

  20. Synergistic diffuser/heat-exchanger design

    E-Print Network [OSTI]

    Lazzara, David S. (David Sergio), 1980-

    2004-01-01

    The theoretical and numerical evaluation of synergistic diffusing heat-exchanger design is presented. Motivation for this development is based on current diffuser and heat-exchange technologies in cogeneration plants, which ...

  1. IMPACTS OF SMALL COLUMN ION EXCHANGE STREAMS ON DWPF GLASS FORMULATION: KT08, KT09, AND KT10-SERIES GLASS COMPOSITIONS

    SciTech Connect (OSTI)

    Fox, K.; Edwards, T.

    2011-04-26

    This report is the fourth in a series of studies of the impacts of the addition of Crystalline Silicotitanate (CST) and Monosodium Titanate (MST) from the Small Column Ion Exchange (SCIX) process on the Defense Waste Processing Facility (DWPF) glass waste form and the applicability of the DWPF process control models. MST from the Salt Waste Processing Facility (SWPF) is also considered in the study. The KT08-series of glasses was designed to evaluate any impacts of the inclusion of uranium and thorium in glasses containing the SCIX components. The KT09-series of glasses was designed to study the effect of increasing Al{sub 2}O{sub 3} and K{sub 2}O concentrations on the propensity for crystallization of titanium containing phases in high TiO{sub 2} concentration glasses. Earlier work on the KT05-series glasses recommended that the impact of these two components be studied further. Increased Al{sub 2}O{sub 3} concentrations have been shown to improve the properties and performance of high waste loading glasses, and K{sub 2}O has been reported to improve the retention of TiO{sub 2} in silicate glasses. The KT10-series of compositions was designed to evaluate any impacts of the SCIX components at concentrations 50% higher than currently projected.a The glasses were fabricated in the laboratory and characterized to identify crystallization, to verify chemical compositions, to measure viscosity, and to measure durability. Liquidus temperature measurements for the KT10-series glasses are underway and will be reported separately. All but one of the KT08-series glasses were found to be amorphous by X-ray diffraction (XRD). One of the slowly cooled glasses contained a small amount of trevorite, which had no practical impact on the durability of the glass and is typically found in DWPF-type glasses. The measured Product Consistency Test (PCT) responses for the KT08-series glasses are well predicted by the DWPF models. The viscosities of the KT08-series glasses were generally well predicted by the DWPF model. No unexpected issues were encountered when uranium and thorium were added to the glasses with SCIX components. Increased Al{sub 2}O{sub 3} concentrations were not successful in preventing the formation of iron titanate crystals in the KT09-series glasses. Increased K{sub 2}O concentrations were successful in hindering the formation of iron titanates in some of the glasses after the canister centerline cooled (CCC) heat treatment. However, this result did not apply to all of the CCC versions of the glasses, indicating a compositional dependence of this effect. In addition, high concentrations of K{sub 2}O have been shown to hinder the ability of the DWPF durability and viscosity models to predict the performance of these glasses. The usefulness of increased K{sub 2}O concentrations in preventing the formation of iron titanates may therefore be limited. Further characterization was not performed for the KT09-series glasses since the type of crystallization formed was the characteristic of interest for these compositions. All of the KT10-series glasses were XRD amorphous, regardless of heat treatment. Chemical composition measurements showed that the glasses met the targeted concentrations for each oxide. In general, the measured PCT responses of the KT10-series glasses were well predicted by the DWPF models. The measured, normalized release values for silicon for some of the glasses fell above the 95% confidence interval for the predicted values; however, the PCT responses for these glasses remain considerably lower than that of the benchmark Environmental Assessment (EA) glass. The viscosities of the KT10-series glasses were generally well predicted by the DWPF model. The next step in this study will be to compile all of the data developed and further compare the measured properties and performance with those predicted by the current DWPF Product Composition Control System (PCCS) models. Recommendations will then be made as to which models, if any, may need to be modified in order to accommodate the material from SCIX into DWPF

  2. ESTABLISHING SUSTAINABLE US HEV/PHEV MANUFACTURING BASE: STABILIZED LITHIUM METAL POWDER, ENABLING MATERIAL AND REVOLUTIONARY TECHNOLOGY FOR HIGH ENERGY LI-ION BATTERIES

    SciTech Connect (OSTI)

    Yakovleva, Marina

    2012-12-31

    FMC Lithium Division has successfully completed the project “Establishing Sustainable US PHEV/EV Manufacturing Base: Stabilized Lithium Metal Powder, Enabling Material and Revolutionary Technology for High Energy Li-ion Batteries”. The project included design, acquisition and process development for the production scale units to 1) produce stabilized lithium dispersions in oil medium, 2) to produce dry stabilized lithium metal powders, 3) to evaluate, design and acquire pilot-scale unit for alternative production technology to further decrease the cost, and 4) to demonstrate concepts for integrating SLMP technology into the Li- ion batteries to increase energy density. It is very difficult to satisfy safety, cost and performance requirements for the PHEV and EV applications. As the initial step in SLMP Technology introduction, industry can use commercially available LiMn2O4 or LiFePO4, for example, that are the only proven safer and cheaper lithium providing cathodes available on the market. Unfortunately, these cathodes alone are inferior to the energy density of the conventional LiCoO2 cathode and, even when paired with the advanced anode materials, such as silicon composite material, the resulting cell will still not meet the energy density requirements. We have demonstrated, however, if SLMP Technology is used to compensate for the irreversible capacity in the anode, the efficiency of the cathode utilization will be improved and the cost of the cell, based on the materials, will decrease.

  3. Energy Technology Data Exchange (ETDE)

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Signatories: Partners: IAEA International Nuclear Information System (INIS) IEA Clean Coal Centre WorldWideScience.org World Energy Congress IEA Hydrogen Implementing...

  4. NREL - DOE Technology Performance Exchange

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCED MANUFACTURING OFFICESpecialAPPENDIX FOrigin ofAllen LichvarAREVA NOPRDepartmentof4 October- DOE

  5. Technolog

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    focuses on multi-scale, multiphysics approaches to understanding natural systems, "engineering the earth" with sensing and drilling technologies and characterizing geomaterials...

  6. Vehicle Technologies Office Merit Review 2015: Giga Life Cycle: Manufacture of Cells from Recycled EV Li-ion Batteries

    Broader source: Energy.gov [DOE]

    Presentation given by OnTo Technology at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about Giga Life Cycle: manufacture...

  7. Vehicle Technologies Office Merit Review 2014: Significant Cost Improvement of Li-ion Cells Through Non-NMP Electrode Coating, Direct Separator Coating, and Fast Formation Technologies

    Broader source: Energy.gov [DOE]

    Presentation given by Johnson Controls at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about significant cost improvement...

  8. Vehicle Technologies Office Merit Review 2015: Significant Cost Improvement of Li-Ion Cells Through Non-NMP Electrode Coating, Direct Separator Coating, and Fast Formation Technologies

    Broader source: Energy.gov [DOE]

    Presentation given by Johnson Controls at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about significant cost improvement...

  9. Radioactive ion detector

    DOE Patents [OSTI]

    Bower, Kenneth E. (Los Alamos, NM); Weeks, Donald R. (Saratoga, CA)

    1997-01-01

    Apparatus for detecting the presence, in aqueous media, of substances which emit alpha and/or beta radiation and determining the oxidation state of these radioactive substances, that is, whether they are in cationic or anionic form. In one embodiment, a sensor assembly has two elements, one comprised of an ion-exchange material which binds cations and the other comprised of an ion-exchange material which binds anions. Each ion-exchange element is further comprised of a scintillation plastic and a photocurrent generator. When a radioactive substance to which the sensor is exposed binds to either element and emits alpha or beta particles, photons produced in the scintillation plastic illuminate the photocurrent generator of that element. Sensing apparatus senses generator output and thereby indicates whether cationic species or anionic species or both are present and also provides an indication of species quantity.

  10. Radioactive ion detector

    DOE Patents [OSTI]

    Bower, K.E.; Weeks, D.R.

    1997-08-12

    Apparatus for detecting the presence, in aqueous media, of substances which emit alpha and/or beta radiation and determining the oxidation state of these radioactive substances, that is, whether they are in cationic or anionic form. In one embodiment, a sensor assembly has two elements, one comprised of an ion-exchange material which binds cations and the other comprised of an ion-exchange material which binds anions. Each ion-exchange element is further comprised of a scintillation plastic and a photocurrent generator. When a radioactive substance to which the sensor is exposed binds to either element and emits alpha or beta particles, photons produced in the scintillation plastic illuminate the photocurrent generator of that element. Sensing apparatus senses generator output and thereby indicates whether cationic species or anionic species or both are present and also provides an indication of species quantity. 2 figs.

  11. FERRIC ION-SPECIFIC SEQUESTERING AGENTS. 7. SYNTHESIS, IRON EXCHANGE KINETICS, AND STABILITY CONSTANTS OF N-SUBSTITUTED, SULFONATED CATECHOYLAMIDE ANALOGUES OF ENTEROBACTIN.

    SciTech Connect (OSTI)

    Pecoraro, Vincent L.; Weitl, Frederick L.; Raymond, Kenneth N.

    1980-10-01

    For treatment of chronic iron overload (as occurs in Cooley's anemia), ferric ion sequestering agents with specific properties are necessary. Two analogues of enterobactin [a microbial chelating agent with the greatest stability constant known for an Fe(III) complex] are reported which exhibit: i) hydrolytic stability; ii) water solubility; iii) N-substitution to block peptidase hydrolysis. The first compound, N,N',N"- trimethyl-N,N',N"-tris(2,3-dihydroxysulfobenzoyl)1,3,5-triaminomethyl- benzene, [Me{sub 3}MECAMS, 6] was prepared from the amide of trimesloyl chloride (1) and MeNH{sub 2}. The resulting amide was reduced to the triamine (3) and converted in three steps to the final product 6 in 6% overall yield. The proton-dependent formation constant (log K*) for the reaction: Fe{sup 3+} + H{sub 3}L{sup 6-} = FeL{sup 6-} + 3H{sup +} is 4.87, which gives an equilibrium concentration of [Fe{sup 3+}] at pH 7.4 of 2 x 10{sup -27} M for 10{sup -5} M L (6) and 10{sup -6} M total Fe{sup 3+}. The estimated formation constant (log {beta}{sub 110}) is 40. At low pH the FeL{sup 6-} complex undergoes a series of three, one-proton reactions which probably gives a tris-salicylate complex formed by the carbonyl and ortho-catechol oxygen of the 2,3~dihydroxybenzoyl units (the same reaction that occurs with ferric enterobactin). After six hours in the presence of 6 mM ascorbate, Me{sub 3}MECAMS (6.0 mM) removed 3.7% of the ferric ion initially sequestered by the iron storage protein, ferritin. The human iron transport protein transferrin goves up iron to Me{sub 3}MECAMS with a pseudo first-order rate constant of 1.9 x 10{sup -3}min{sup -1} (ligand concentration 2 X 10{sup -4} M). This rate is comparable to that of enterobactin and other catechoyl amide sequestering agents. and greatly exceeds that of desferrioxamine B (Desferal{reg-sign}). the current drug of choice in treating iron overload. Two related compounds have been prepared in which the catechol ring is attached to the amide nitrogen through a methylene group, with amide formation with an acetyl group. In N,N',N"-triacetyl-N,N' ,N"-tris(2,3- dihydroxysulfobenzoyl) -N,N',N"-triaminomethylbenzene [NAcMECAMS, 111... and its unsulfonated precursor, the amide linkage of the catechoyl amides such as Me{sub 3}MECAMS (6) has been shifted from an endo position relative to the benzene and catechol rings to an exo position in which the amide carbonyl is not conjugated with the catechol ring and cannot form a stable chelate ring in conjunction with a catechol oxygen. The preparation of 11 and 10 proceeded from the previously described precursor of TRIMCAM, 7. borane reduction to the tri.amine 8, and amide formation with acetyl chloride to 9, followed by deprotection of the catechol oxygens with BBr{sub 3}/CH{sub 2}Cl{sub 2} to give 10. Sulfonation of 10 to NAcMECAMS, 11, is carried out in fuming sulfuric acid. In comparison with Me{sub 3}MECAMS, the protonation of NAcMECAMS (11) proceeds by an initial two-proton step in contrast to the one-proton reactions typical of the catechoyl amides, which can form a salicylate mode of coordination involving the amide carbonyl group. Also as a result of the removal of the carbonyl group from conjugation with the catechol ring, the acidity of NAcMECAMS (11) is less than Me{sub 3}MECAMS (6). While the estimated log {beta{sub 110} is approximately the same as for Me{sub 3}MECAMS (40). the effective formation constant (log K*) and pM.(- log [Fe{sub aq}{sup 3+}] ) values are lower (4.0 and 25.0, respectively).

  12. Evaluation of Hydrogen Isotope Exchange Methodology on Adsorbents for Tritium Removal

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Morgan, Gregg A.; Xiao, S. Xin

    2015-03-06

    The Savannah River National Laboratory has demonstrated a potential process that can be used to remove tritium from tritiated water using Pt-catalyzed molecular sieves. The process is an elemental isotope exchange process in which H2 (when flowed through the molecular sieves) will exchange with the adsorbed water, D2O, leaving H2O adsorbed on the molecular sieves. Various formulations of catalyzed molecular sieve material were prepared using two different techniques, Pt-implantation and Pt-ion exchange. This technology has been demonstrated for a protium (H) and deuterium (D) system, but can also be used for the removal of tritium from contaminated water (T2O, HTO,more »and DTO) using D2 (or H2)« less

  13. Vehicle Technologies Office Merit Review 2014: Overcoming Processing Cost Barriers of High-Performance Lithium-Ion Battery Electrodes

    Office of Energy Efficiency and Renewable Energy (EERE)

    Presentation given by Oak Ridge National Laboratory at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about overcoming...

  14. Vehicle Technologies Office Merit Review 2015: Innovative Manufacturing and Materials for Low-Cost Lithium-Ion Batteries

    Office of Energy Efficiency and Renewable Energy (EERE)

    Presentation given by Optodot Corporation at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about innovative manufacturing...

  15. Vehicle Technologies Office Merit Review 2014: Innovative Manufacturing and Materials for Low-Cost Lithium-Ion Batteries

    Office of Energy Efficiency and Renewable Energy (EERE)

    Presentation given by Optodot Corporation at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about innovative manufacturing...

  16. Vehicle Technologies Office Merit Review 2014: Wiring Up Silicon Nanostructures for High Energy Lithium-Ion Battery Anodes

    Broader source: Energy.gov [DOE]

    Presentation given by Stanford University at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about wiring up silicon...

  17. Vehicle Technologies Office Merit Review 2014: Manufacturability Study and Scale-Up for Large Format Lithium Ion Batteries

    Broader source: Energy.gov [DOE]

    Presentation given by Oak Ridge National Laboratory at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about...

  18. Vehicle Technologies Office Merit Review 2014: Characterization of Voltage Fade in Lithium-ion Cells with Layered Oxides

    Broader source: Energy.gov [DOE]

    Presentation given by Argonne National Laboratory at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about characterization...

  19. Vehicle Technologies Office Merit Review 2014: Nanoscale Heterostructures and Thermoplastic Resin Binders: Novel Li-ion Anode Systems

    Broader source: Energy.gov [DOE]

    Presentation given by University of Pittsburgh at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about nanoscale...

  20. SMALL PARTICLE HEAT EXCHANGERS

    E-Print Network [OSTI]

    Hunt, A.J.

    2011-01-01

    The Small Particle Heat Exchange Receiver (SPHER) for Solarof the small particle heat exchange receiver (or SPHER), asabsorption process, the heat exchange to the gas, the choice

  1. Vehicle Technologies Office Merit Review 2015: Utilization of UV or EB Curing Technology to Significantly Reduce Costs and VOCs in the Manufacture of Lithium-Ion Battery Electrodes

    Broader source: Energy.gov [DOE]

    Presentation given by Miltec UV International at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about utilization of UV or...

  2. Vehicle Technologies Office Merit Review 2014: Utilization of UV or EB Curing Technology to Significantly Reduce Costs and VOCs in the Manufacture of Lithium-Ion Battery Electrodes

    Broader source: Energy.gov [DOE]

    Presentation given by Miltec UV International at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about the utilization of UV...

  3. Microfabricated Ion Traps

    E-Print Network [OSTI]

    Marcus D. Hughes; Bjoern Lekitsch; Jiddu A. Broersma; Winfried K. Hensinger

    2011-06-28

    Ion traps offer the opportunity to study fundamental quantum systems with high level of accuracy highly decoupled from the environment. Individual atomic ions can be controlled and manipulated with electric fields, cooled to the ground state of motion with laser cooling and coherently manipulated using optical and microwave radiation. Microfabricated ion traps hold the advantage of allowing for smaller trap dimensions and better scalability towards large ion trap arrays also making them a vital ingredient for next generation quantum technologies. Here we provide an introduction into the principles and operation of microfabricated ion traps. We show an overview of material and electrical considerations which are vital for the design of such trap structures. We provide guidance in how to choose the appropriate fabrication design, consider different methods for the fabrication of microfabricated ion traps and discuss previously realized structures. We also discuss the phenomenon of anomalous heating of ions within ion traps, which becomes an important factor in the miniaturization of ion traps.

  4. Technologies

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home RoomPreservationBio-Inspired Solar Fuel ProductionRecoverable15/2008Technologies Technologies

  5. Technology

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home RoomPreservationBio-Inspired Solar FuelTechnology /newsroom/_assets/images/s-icon.png Technology

  6. SMALL PARTICLE HEAT EXCHANGERS

    E-Print Network [OSTI]

    Hunt, A.J.

    2011-01-01

    heat exchangers. These types of heat exchangers have limitedheat exchanger to solar collection systems that utilize linear trough- typenon-solar heat exchangers. These may be of the type used to

  7. Vehicle Technologies Office Merit Review 2014: Real-time Metrology for Li-ion Battery R&D and Manufacturing

    Broader source: Energy.gov [DOE]

    Presentation given by Applied Spectra, Inc at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about real-time metrology for...

  8. Vehicle Technologies Office Merit Review 2014: High Energy, Long Cycle Life Lithium-ion Batteries for EV Applications

    Broader source: Energy.gov [DOE]

    Presentation given by The Pennsylvania State University at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about high energy...

  9. Vehicle Technologies Office Merit Review 2015: High Energy, Long Cycle Life Lithium-ion Batteries for EV Applications

    Broader source: Energy.gov [DOE]

    Presentation given by Penn State at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about high energy, long cycle life...

  10. Vehicle Technologies Office Merit Review 2015: Thick Low-Cost, High-Power Lithium-Ion Electrodes via Aqueous Processing

    Office of Energy Efficiency and Renewable Energy (EERE)

    Presentation given by Oak Ridge National Laboratory at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about thick low-cost,...

  11. Vehicle Technologies Office Merit Review 2015: Studies on High Capacity Cathodes for Advanced Lithium-ion Systems

    Office of Energy Efficiency and Renewable Energy (EERE)

    Presentation given by Oak Ridge National Laboratory at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about studies on high...

  12. Vehicle Technologies Office Merit Review 2014: Post-Test Analysis of Lithium-Ion Battery Materials at Argonne National Laboratory

    Broader source: Energy.gov [DOE]

    Presentation given by Argonne National Laboratory at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about post-test...

  13. Vehicle Technologies Office Merit Review 2015: Low?Cost, High?Capacity Lithium Ion Batteries through Modified Surface and Microstructure

    Broader source: Energy.gov [DOE]

    Presentation given by Navitas Systems at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about low?cost, high?capacity...

  14. Vehicle Technologies Office Merit Review 2014: Development of Large Format Lithium Ion Cells with Higher Energy Density

    Broader source: Energy.gov [DOE]

    Presentation given by XALT Energy LLC at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about development of large format...

  15. Vehicle Technologies Office Merit Review 2014: Studies on High Capacity Cathodes for Advanced Lithium-ion Systems

    Broader source: Energy.gov [DOE]

    Presentation given by Oak Ridge National Laboratory at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about studies on high...

  16. Vehicle Technologies Office Merit Review 2015: Post-Test Analysis of Lithium-Ion Battery Materials at Argonne National Laboratory

    Broader source: Energy.gov [DOE]

    Presentation given by Argonne National Laboratory at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about post-test...

  17. Vehicle Technologies Office Merit Review 2015: Real-time Metrology for Li-ion Battery R&D and Manufacturing

    Broader source: Energy.gov [DOE]

    Presentation given by Applied Spectra at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about real-time metrology for Li...

  18. Vehicle Technologies Office Merit Review 2015: Low-cost, High Energy Si/Graphene Anodes for Li-ion Batteries

    Broader source: Energy.gov [DOE]

    Presentation given by XG Sciences at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about low-cost, high energy Si/graphene...

  19. Vehicle Technologies Office Merit Review 2015: Efficient Safety and Degradation Modeling of Automotive Li-ion Cells and Pack

    Broader source: Energy.gov [DOE]

    Presentation given by EC-Power at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about efficient safety and degradation...

  20. Vehicle Technologies Office Merit Review 2014: Efficient Safety and Degradation Modeling of Automotive Li-ion Cells and Pack

    Broader source: Energy.gov [DOE]

    Presentation given by EC Power at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about efficient safety and degradation...

  1. Drift orbit topology of fast ions in tokamaks Plasma Science and Fusion Centre, Massachusetts Institute of Technology,

    E-Print Network [OSTI]

    Egedal, Jan

    , Massachusetts Institute of Technology, Cambridge, Massachusetts, United States of America Abstract. Graphical the presence of special orbit types (co-pinch orbits) causes first orbit loss of fusion products. 1

  2. Drift orbit topology of fast ions in tokamaks Plasma Science and Fusion Centre, Massachusetts Institute of Technology,

    E-Print Network [OSTI]

    Egedal, Jan

    , Massachusetts Institute of Technology, Cambridge, Massachusetts, United States of America Abstract. Graphical the presence of special orbit types (co­pinch orbits) causes first orbit loss of fusion products. 1

  3. Technologies

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power AdministrationRobust,Field-effectWorking With U.S. CoalMexico IndependentMatter and Technologies R&D

  4. Ion Exchange Kinetics Testing with SRF Resin

    SciTech Connect (OSTI)

    Russell, Renee L.; Rinehart, Donald E.; Brown, Garrett N.; Schonewill, Philip P.; Peterson, Reid A.

    2012-04-01

    The U.S. Department of Energy (DOE) Hanford Site contains more than 53 million gallons of legacy waste generated as a byproduct of plutonium production and reprocessing operations. The wastes are a complex mixture composed mostly of NaNO3, NaNO2, NaOH, NaAlO2, Na3PO4, and Na2SO4, with a number of minor and trace metals, organics, and radionuclides stored in underground waste tanks. The DOE Office of River Protection (ORP) has contracted Bechtel National Incorporated (BNI) to build a pretreatment facility, the River Protection Project-Waste Treatment Plant (RPP-WTP), that will separate long-lived transuranics (TRU) and highly radioactive components (specifically 137Cs and, in selected cases, 90Sr) from the bulk (non-radioactive) constituents and immobilize the wastes by vitrification. The plant is designed to produce two waste streams: a high-volume low-activity waste (LAW) and a low-volume high-activity waste (HLW).

  5. Acidic Ion Exchange Membrane - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 OutreachProductswsicloudwsicloudden DocumentationAccommodations Accommodations LosUnderground Find More Like

  6. High-Performance Refrigerator Using Novel Rotating Heat Exchanger...

    Energy Savers [EERE]

    Cooler relative to current heat exchanger technology are additional refrigerated space, noise reduction, and fouling reduction. Additional refrigerated volume realized by the more...

  7. Growth of oxide exchange bias layers

    DOE Patents [OSTI]

    Chaiken, Alison (Fremont, CA); Michel, Richard P. (Bloomington, MN)

    1998-01-01

    An oxide (NiO, CoO, NiCoO) antiferromagnetic exchange bias layer produced by ion beam sputtering of an oxide target in pure argon (Ar) sputtering gas, with no oxygen gas introduced into the system. Antiferromagnetic oxide layers are used, for example, in magnetoresistive readback heads to shift the hysteresis loops of ferromagnetic films away from the zero field axis. For example, NiO exchange bia layers have been fabricated using ion beam sputtering of an NiO target using Ar ions, with the substrate temperature at 200.degree. C., the ion beam voltage at 1000V and the beam current at 20 mA, with a deposition rate of about 0.2 .ANG./sec. The resulting NiO film was amorphous.

  8. Growth of oxide exchange bias layers

    DOE Patents [OSTI]

    Chaiken, A.; Michel, R.P.

    1998-07-21

    An oxide (NiO, CoO, NiCoO) antiferromagnetic exchange bias layer produced by ion beam sputtering of an oxide target in pure argon (Ar) sputtering gas, with no oxygen gas introduced into the system. Antiferromagnetic oxide layers are used, for example, in magnetoresistive readback heads to shift the hysteresis loops of ferromagnetic films away from the zero field axis. For example, NiO exchange bias layers have been fabricated using ion beam sputtering of an NiO target using Ar ions, with the substrate temperature at 200 C, the ion beam voltage at 1000V and the beam current at 20 mA, with a deposition rate of about 0.2 {angstrom}/sec. The resulting NiO film was amorphous. 4 figs.

  9. Microfabricated Ion Traps

    E-Print Network [OSTI]

    Hughes, Marcus D; Broersma, Jiddu A; Hensinger, Winfried K

    2011-01-01

    Ion traps offer the opportunity to study fundamental quantum systems with high level of accuracy highly decoupled from the environment. Individual atomic ions can be controlled and manipulated with electric fields, cooled to the ground state of motion with laser cooling and coherently manipulated using optical and microwave radiation. Microfabricated ion traps hold the advantage of allowing for smaller trap dimensions and better scalability towards large ion trap arrays also making them a vital ingredient for next generation quantum technologies. Here we provide an introduction into the principles and operation of microfabricated ion traps. We show an overview of material and electrical considerations which are vital for the design of such trap structures. We provide guidance in how to choose the appropriate fabrication design, consider different methods for the fabrication of microfabricated ion traps and discuss previously realized structures. We also discuss the phenomenon of anomalous heating of ions with...

  10. STUDIES ON TWO CLASSES OF POSITIVE ELECTRODE MATERIALS FOR LITHIUM-ION BATTERIES

    E-Print Network [OSTI]

    Wilcox, James D.

    2010-01-01

    as cathode materials for lithium ion battery. ElectrochimicaCapacity, High Rate Lithium-Ion Battery Electrodes Utilizinghours. 1.4 Lithium Ion Batteries Lithium battery technology

  11. Corrosive resistant heat exchanger

    DOE Patents [OSTI]

    Richlen, Scott L. (Annandale, VA)

    1989-01-01

    A corrosive and errosive resistant heat exchanger which recovers heat from a contaminated heat stream. The heat exchanger utilizes a boundary layer of innocuous gas, which is continuously replenished, to protect the heat exchanger surface from the hot contaminated gas. The innocuous gas is conveyed through ducts or perforations in the heat exchanger wall. Heat from the heat stream is transferred by radiation to the heat exchanger wall. Heat is removed from the outer heat exchanger wall by a heat recovery medium.

  12. PROCESS SPECIFICATION LANGUAGE FOR PROJECT SCHEDULING INFORMATION EXCHANGE

    E-Print Network [OSTI]

    Stanford University

    of Standards and Technology (NIST) and is emerging as a standard exchange language for process information in the manufacturing industry. This paper explores how PSL can be used for exchanging project scheduling informationPROCESS SPECIFICATION LANGUAGE FOR PROJECT SCHEDULING INFORMATION EXCHANGE Jinxing Cheng1 , Michael

  13. RESIDENTIAL EXCHANGE

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMassR&D100 Winners * Impacts on Global TechnologyProceeding Sign In About22 -8A

  14. Intercalation Kinetics and Ion Mobility in Electrode Materials...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Intercalation Kinetics and Ion Mobility in Electrode Materials for Advanced Lithium Ion Batteries 2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program...

  15. Fast-ion D measurements of the fast-ion distribution ,,invited...a... W. W. Heidbrinkb

    E-Print Network [OSTI]

    Heidbrink, William W.

    Fast-ion D measurements of the fast-ion distribution ,,invited...a... W. W. Heidbrinkb University; published online 25 October 2010 The fast-ion D FIDA diagnostic is an application of charge-exchange recombination spectroscopy. Fast ions that neutralize in an injected neutral beam emit Balmer- light

  16. 1614 IEEE TRANSACTIONS ON VEHICULAR TECHNOLOGY, VOL. 63, NO. 4, MAY 2014 The State of Charge Estimation of Lithium-Ion

    E-Print Network [OSTI]

    Mi, Chunting "Chris"

    Estimation of Lithium-Ion Batteries Based on a Proportional-Integral Observer Jun Xu, Student Member, IEEE--With the development of electric drive vehicles (EDVs), the state-of-charge (SOC) estimation for lithium-ion (Li of lithium-ion batteries in EDVs. The structure of the proposed PI observer is analyzed, and the con

  17. 1020 IEEE TRANSACTIONS ON VEHICULAR TECHNOLOGY, VOL. 62, NO. 3, MARCH 2013 State of Charge Estimation of Lithium-Ion Batteries

    E-Print Network [OSTI]

    Mi, Chunting "Chris"

    Estimation of Lithium-Ion Batteries in Electric Drive Vehicles Using Extended Kalman Filtering Zheng Chen. Index Terms--Extended Kalman filter (EKF), hardware-in- the-loop, lithium-ion battery, nonlinear battery], a modeling approach for the scale-up of a lithium- ion polymer battery (LIPB) is reported. A comparison

  18. Woven heat exchanger

    DOE Patents [OSTI]

    Piscitella, Roger R. (Idaho Falls, ID)

    1987-01-01

    In a woven ceramic heat exchanger using the basic tube-in-shell design, each heat exchanger consisting of tube sheets and tube, is woven separately. Individual heat exchangers are assembled in cross-flow configuration. Each heat exchanger is woven from high temperature ceramic fiber, the warp is continuous from tube to tube sheet providing a smooth transition and unitized construction.

  19. Ion source

    DOE Patents [OSTI]

    Leung, Ka-Ngo (Hercules, CA); Ehlers, Kenneth W. (Alamo, CA)

    1984-01-01

    A magnetic filter for an ion source reduces the production of undesired ion species and improves the ion beam quality. High-energy ionizing electrons are confined by the magnetic filter to an ion source region, where the high-energy electrons ionize gas molecules. One embodiment of the magnetic filter uses permanent magnets oriented to establish a magnetic field transverse to the direction of travel of ions from the ion source region to the ion extraction region. In another embodiment, low energy 16 eV electrons are injected into the ion source to dissociate gas molecules and undesired ion species into desired ion species.

  20. Woven heat exchanger

    DOE Patents [OSTI]

    Piscitella, R.R.

    1984-07-16

    This invention relates to a heat exchanger for waste heat recovery from high temperature industrial exhaust streams. In a woven ceramic heat exchanger using the basic tube-in-shell design, each heat exchanger consisting of tube sheets and tube, is woven separately. Individual heat exchangers are assembled in cross-flow configuration. Each heat exchanger is woven from high temperature ceramic fiber, the warp is continuous from tube to tube sheet providing a smooth transition and unitized construction.

  1. Electron beam ion source and electron beam ion trap (invited)

    SciTech Connect (OSTI)

    Becker, Reinard [Scientific Software Service, Kapellenweg 2a, D-63571 Gelnhausen (Germany); Kester, Oliver [National Superconducting Cyclotron Laboratory, Michigan State University, East Lansing, Michigan 48824 (United States)

    2010-02-15

    The electron beam ion source (EBIS) and its trap variant [electron beam ion trap (EBIT)] celebrated their 40th and 20th anniversary, respectively, at the EBIS/T Symposium 2007 in Heidelberg. These technologically challenging sources of highly charged ions have seen a broad development in many countries over the last decades. In contrast to most other ion sources the recipe of improvement was not ''sorcery'' but a clear understanding of the physical laws and obeying the technological constraints. This review will report important achievements of the past as well as promising developments in the future.

  2. U.S. Department of Energy Vehicle Technologies, EE-2G

    E-Print Network [OSTI]

    Pennycook, Steve

    are available to DOE employees, DOE contractors, Energy Technology Data Exchange (ETDE) representatives

  3. FinalReport for completed IPP-0110 and 0110A Projects:"High Energy Ion Technology of Interfacial Thin Film Coatings for Electronic, Optical and Industrial Applications"

    SciTech Connect (OSTI)

    Brown, Ian

    2009-09-01

    The DOE-supported IPP (Initiatives for Proliferation Prevention) Project, IPP-0110, and its accompanying 'add-on project' IPP-0110A, entitled 'High Energy Ion Technology of Interfacial Thin Film Coatings for Electronic, Optical and Industrial Applications' was a collaborative project involving the Lawrence Berkeley National Laboratory (LBNL) as the U.S. DOE lab; the US surface modification company, Phygen, Inc., as the US private company involved; and the High Current Electronics Institute (HCEI) of the Russian Academy of Sciences, Tomsk, Siberia, Russia, as the NIS Institute involved. Regular scientific research progress meetings were held to which personnel came from all participating partners. The meetings were held mostly at the Phygen facilities in Minneapolis, Minnesota (with Phygen as host) with meetings also held at Tomsk, Russia (HCEI as host), and at Berkeley, California (LBNL as host) In this way, good exposure of all researchers to the various different laboratories involved was attained. This report contains the Final Reports (final deliverables) from the Russian Institute, HCEI. The first part is that for IPP-0110A (the 'main part' of the overall project) and the second part is that for the add-on project IPP-0110A. These reports are detailed, and contain all aspects of all the research carried out. The project was successful in that all deliverables as specified in the proposals were successfully developed, tested, and delivered to Phygen. All of the plasma hardware was designed, made and tested at HCEI, and the performance was excellent. Some of the machine and performance parameters were certainly of 'world class'. The goals and requirements of the IPP Project were well satisfied. I would like to express my gratitude to the DOE IPP program for support of this project throughout its entire duration, and for the unparalleled opportunity thereby provided for all of the diverse participants in the project to join in this collaborative research. The benefits are superb, as measured in quite a number of different ways.

  4. Information technology equipment cooling method

    DOE Patents [OSTI]

    Schultz, Mark D.

    2015-10-20

    According to one embodiment, a system for removing heat from a rack of information technology equipment may include a sidecar indoor air to liquid heat exchanger that cools air utilized by the rack of information technology equipment to cool the rack of information technology equipment. The system may also include a liquid to liquid heat exchanger and an outdoor heat exchanger. The system may further include configurable pathways to connect and control fluid flow through the sidecar heat exchanger, the liquid to liquid heat exchanger, the rack of information technology equipment, and the outdoor heat exchanger based upon ambient temperature and/or ambient humidity to remove heat generated by the rack of information technology equipment.

  5. Energy Exchange Registration Desk

    Broader source: Energy.gov [DOE]

    Sunday through Thursday, staff will be available at the Energy Exchange registration desk at the Phoenix Convention Center to answer any questions, distribute attendee badges, and register those seeking to attend the Energy Exchange.

  6. Energy Exchange News

    Broader source: Energy.gov [DOE]

    Please join FEMP Director Tim Unruh and Julia Kelley with Oak Ridge National Laboratory (ORNL) for a presentation on the Energy Exchange. The Energy Exchange is a new 2 1/2 day training opportunity...

  7. High-resolution studies of charge exchange in supernova remnants with Magellan, XMM-Newton, and Micro-X

    E-Print Network [OSTI]

    Heine, Sarah Nicole Trowbridge

    2014-01-01

    Charge exchange, the semi-resonant transfer of an electron from a neutral atom to an excited state in an energetic ion, can occur in plasmas where energetic ions are incident on a cold, at least partially neutral gas. ...

  8. Anion exchange polymer electrolytes

    DOE Patents [OSTI]

    Kim, Yu Seung; Kim, Dae Sik

    2013-09-10

    Solid anion exchange polymer electrolytes include chemical compounds comprising a polymer backbone with side chains that include guanidinium cations.

  9. Capture and isolation of highly-charged ions in a unitary Penning trap

    E-Print Network [OSTI]

    Brewer, Samuel M; Tan, Joseph N

    2013-01-01

    We recently used a compact Penning trap to capture and isolate highly-charged ions extracted from an electron beam ion trap (EBIT) at the National Institute of Standards and Technology (NIST). Isolated charge states of highly-stripped argon and neon ions with total charge $Q \\geq 10$, extracted at energies of up to $4\\times 10^3\\,Q$ eV, are captured in a trap with well depths of $\\,\\approx (4\\, {\\rm to}\\, 12)\\,Q$ eV. Here we discuss in detail the process to optimize velocity-tuning, capture, and storage of highly-charged ions in a unitary Penning trap designed to provide easy radial access for atomic or laser beams in charge exchange or spectroscopic experiments, such as those of interest for proposed studies of one-electron ions in Rydberg states or optical transitions of metastable states in multiply-charged ions. Under near-optimal conditions, ions captured and isolated in such rare-earth Penning traps can be characterized by an initial energy distribution that is $\\approx$ 60 times narrower than typically...

  10. ERASMUS EXCHANGE LEARNING AGREEMENT

    E-Print Network [OSTI]

    Pfeifer, Holger

    ERASMUS ­ EXCHANGE LEARNING AGREEMENT --FINAL THESIS / PROJECT -- Name of Applicant Exchange to conclude Bachelor Master PhD Other: Course No. Course Title Duration (Months) ECTS (5 ECTS / Month) N is approved. Date and Stamp: Coordinator Signature: #12;ERASMUS ­ EXCHANGE | LEARNING AGREEMENT --FINAL THESIS

  11. Charge exchange system

    DOE Patents [OSTI]

    Anderson, Oscar A. (Berkeley, CA)

    1978-01-01

    An improved charge exchange system for substantially reducing pumping requirements of excess gas in a controlled thermonuclear reactor high energy neutral beam injector. The charge exchange system utilizes a jet-type blanket which acts simultaneously as the charge exchange medium and as a shield for reflecting excess gas.

  12. Two-dimensional spectroscopy for the study of ion Coulomb crystals

    E-Print Network [OSTI]

    A. Lemmer; C. Cormick; C. T. Schmiegelow; F. Schmidt-Kaler; M. B. Plenio

    2015-05-04

    Ion Coulomb crystals are currently establishing themselves as a highly controllable test-bed for mesoscopic systems of statistical mechanics. The detailed experimental interrogation of the dynamics of these crystals however remains an experimental challenge. In this work, we show how to extend the concepts of multi-dimensional nonlinear spectroscopy to the study of the dynamics of ion Coulomb crystals. The scheme we present can be realized with state-of-the-art technology and gives direct access to the dynamics, revealing nonlinear couplings even in the presence of thermal excitations. We illustrate the advantages of our proposal showing how two-dimensional spectroscopy can be used to detect signatures of a structural phase transition of the ion crystal, as well as resonant energy exchange between modes. Furthermore, we demonstrate in these examples how different decoherence mechanisms can be identified.

  13. Internet Exchanges: Enabling Local Online Communities

    E-Print Network [OSTI]

    Mitchell, Keith

    Interconnect Principles Internet Exchange History Internet Exchange Models Internet Exchange Security Setting, Foundry #12;Internet Exchanges History #12;A decade+ of Internet Exchanges The London Internet ExchangeInternet Exchanges: Enabling Local Online Communities Keith Mitchell Chair, United Kingdom Network

  14. Tennessee, Pennsylvania: Porous Power Technologies Improves Lithium...

    Broader source: Energy.gov (indexed) [DOE]

    Laboratory (ORNL), developed SYMMETRIX HPX-F, a nanocomposite separator for improved lithium-ion battery technology. This breakthrough membrane technology addresses market...

  15. Ion exchange-induced dissolution of calcite in Na-montmorillonite/CaCO?b3?s systems: its effect on hydraulic conductivity, CaCO?b3?s dissolution kinetics, and CaCO?b3?s equilibrium relations 

    E-Print Network [OSTI]

    Del Rio Durand, Jose Bruno

    1990-01-01

    Minerals Repository, Clay Minerals Society, University of Missouri, Columbia, MQ) was treated with pH 5. 5 Na-acetate in order to remove traces of CaCO3; complete Na-saturation of the sample was achieved by successive washings with 1 M NaC1... was present. The DD reaction resulted in pH values of approximately 10, a decrease of the exchangeable sodium percemage (ESP), and in a substantial enhancement of calcite dissolution. The rate of calcite dissolution in these systems, as well as in batch...

  16. Heat Exchanger Technologies for Distillation Columns 

    E-Print Network [OSTI]

    Polley, G. T.

    2002-01-01

    '" Surface " i i i i I Vapour Flow I IDowncomcr , ICoolanlFCtXl I ('oolAnl Rcll1nJ I Figure 3. Integral Intermediate Condenser The mass flow of liquid coming down the column will generally be similar to that of the vapour flowing up the column...

  17. NREL: Technology Transfer - African Delegation Exchanges Knowledge...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Experts May 18, 2015 Tapping into 14,000 megawatts of geothermal potential in eastern Africa is the focus one new collaboration at NREL. Six visitors from Djibouti, Ethiopia, and...

  18. Knowledge Exchange and Technology Extension SFM Network

    E-Print Network [OSTI]

    . · Tradable carbon credits related to timber production and forestry operations are calculated by identifying trading initiatives, carbon sequestration is becoming a potential revenue source and an objective ), methane (CH4 ) and nitrous oxide (N2 O). Assessing the carbon balance for Canada's managed forests

  19. Energy Technology Data Exchange | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTIONRobertsdale, AlabamaETEC GmbH JumpEllenville, NewLtd EILEnergy DatadataCentreCo LtdEnergyLimitedData

  20. Technology Performance Exchange | Department of Energy

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX E LIST OF APPLICABLEStatutory Authority J-I- 1May 20062012Department of

  1. Nanofabrication using focused ion beam

    E-Print Network [OSTI]

    Latif, Adnan

    Focused ion beam (FIB) technique uses a focused beam of ions to scan the surface of a specimen, analogous to the way scanning electron microscope (SEM) utilizes electrons. Recent developments in the FIB technology have led to beam spot size below...

  2. Utilization of UV or EB Curing Technology to Significantly Reduce Costs and VOCs in the Manufacture of Lithium-Ion Battery Electrodes

    Broader source: Energy.gov [DOE]

    2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  3. Significant Cost Improvement of Li-Ion Cells Through Non-NMP Electrode Coating, Direct Separator Coating, and Fast Formation Technologies

    Broader source: Energy.gov [DOE]

    2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  4. Microsoft Exchange Servers Archives - Nercenergy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of NaturalDukeWakefieldSulfateSciTechtail.Theory ofDid you notHeatMaRIEdioxide capture | CenterTechnologies | BlandineExchange

  5. Energy Exchange Presentations

    Broader source: Energy.gov [DOE]

    Presentations from Energy Exchange, a two-and-a-half day training scheduled for August 11-13, 2015, at the Phoenix Convention Center in Phoenix, Arizona.

  6. Energy Exchange Speaker Biographies

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Speaker Biographies U.S. Department of Energy Energy Exchange, August 2015 Chris Abbuehl (Constellation Energy) Christopher Abbuehl is responsible for leading the development of...

  7. The Future is Here - Smart Home Technology | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The Future is Here - Smart Home Technology The Future is Here - Smart Home Technology Better Buildings Residential Network Peer Exchange Call Series: The Future is Here - Smart...

  8. Building America Technology Solutions for New and Existing Homes...

    Energy Savers [EERE]

    Building America Technology Solutions for New and Existing Homes: Foundation Heat Exchanger, Oak Ridge, Tennessee Building America Technology Solutions for New and Existing Homes:...

  9. Nanoheterostructure Cation Exchange: Anionic Framework Conservation

    SciTech Connect (OSTI)

    Jain, Prashant K.; Amirav, Lilac; Aloni, Shaul; Alivisatos, A. Paul

    2010-05-11

    In ionic nanocrystals the cationic sub-lattice can be replaced with a different metal ion via a fast, simple, and reversible place-exchange, allowing post-synthetic modification of the composition of the nanocrystal, while preserving its size and shape. Here, we demonstrate for the first time that during such an exchange, the anionic framework of the crystal is preserved. When applied to nanoheterostructures, this phenomenon ensures that compositional interfaces within the heterostructure are conserved throughout the transformation. For instance, a morphology composed of a CdSe nanocrystal embedded in a CdS rod (CdSe/CdS) was exchanged to a PbSe/PbS nanorod via a Cu2Se/Cu2S structure. During every exchange cycle, the seed size and position within the nanorod were preserved, as evident by excitonic features, Z-contrast imaging, and elemental line-scans. Anionic framework conservation extends the domain of cation exchange to the design of more complex and unique nanostructures.

  10. Optimization of Heat Exchangers

    SciTech Connect (OSTI)

    Ivan Catton

    2010-10-01

    The objective of this research is to develop tools to design and optimize heat exchangers (HE) and compact heat exchangers (CHE) for intermediate loop heat transport systems found in the very high temperature reator (VHTR) and other Generation IV designs by addressing heat transfer surface augmentation and conjugate modeling. To optimize heat exchanger, a fast running model must be created that will allow for multiple designs to be compared quickly. To model a heat exchanger, volume averaging theory, VAT, is used. VAT allows for the conservation of mass, momentum and energy to be solved for point by point in a 3 dimensional computer model of a heat exchanger. The end product of this project is a computer code that can predict an optimal configuration for a heat exchanger given only a few constraints (input fluids, size, cost, etc.). As VAT computer code can be used to model characteristics )pumping power, temperatures, and cost) of heat exchangers more quickly than traditional CFD or experiment, optimization of every geometric parameter simultaneously can be made. Using design of experiment, DOE and genetric algorithms, GE, to optimize the results of the computer code will improve heat exchanger disign.

  11. Direct fired heat exchanger

    DOE Patents [OSTI]

    Reimann, Robert C. (Lafayette, NY); Root, Richard A. (Spokane, WA)

    1986-01-01

    A gas-to-liquid heat exchanger system which transfers heat from a gas, generally the combustion gas of a direct-fired generator of an absorption machine, to a liquid, generally an absorbent solution. The heat exchanger system is in a counterflow fluid arrangement which creates a more efficient heat transfer.

  12. Vehicle Technologies Office Merit Review 2015: Enabling High-Energy/Voltage Lithium-Ion Cells for Transportation Applications: Part 3 Electrochemistry

    Broader source: Energy.gov [DOE]

    Presentation given by Argonne National Laboratory at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about enabling high...

  13. Vehicle Technologies Office Merit Review 2015: Enabling High-Energy/Voltage Lithium-Ion Cells for Transportation Applications: Part 2 Materials

    Broader source: Energy.gov [DOE]

    Presentation given by Argonne National Laboratory at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about enabling high...

  14. Vehicle Technologies Office Merit Review 2014: Modular Process Equipment for Low Cost Manufacturing of High Capacity Prismatic Li-Ion Cell Alloy Anodes

    Broader source: Energy.gov [DOE]

    Presentation given by Applied Materials at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about modular process equipment...

  15. Vehicle Technologies Office Merit Review 2015: Enabling High-Energy/Voltage Lithium-Ion Cells for Transportation Applications: Part 1 Baseline Protocols and Analysis

    Broader source: Energy.gov [DOE]

    Presentation given by Argonne National Laboratory at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about enabling high...

  16. Vehicle Technologies Office Merit Review 2015: Electrode Coating Defect Analysis and Processing NDE for High-Energy Lithium-Ion Batteries

    Broader source: Energy.gov [DOE]

    Presentation given by Oak Ridge National Laboratory at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about electrode...

  17. Aberration Corrected Emittance Exchange

    E-Print Network [OSTI]

    Nanni, Emilio A

    2015-01-01

    Full exploitation of emittance exchange (EEX) requires aberration-free performance of a complex imaging system including active radio-frequency (RF) elements which can add temporal distortions. We investigate the performance of an EEX line where the exchange occurs between two dimensions with normalized emittances which differ by orders of magnitude. The transverse emittance is exchanged into the longitudinal dimension using a double dog-leg emittance exchange setup with a 5 cell RF deflector cavity. Aberration correction is performed on the four most dominant aberrations. These include temporal aberrations that are corrected with higher order magnetic optical elements located where longitudinal and transverse emittance are coupled. We demonstrate aberration-free performance of emittances differing by 4 orders of magnitude, i.e. an initial transverse emittance of $\\epsilon_x=1$ pm-rad is exchanged with a longitudinal emittance of $\\epsilon_z=10$ nm-rad.

  18. Efficient evaluation of beam ion confinement in spherical tokamaks Massachusetts Institute of Technology, Plasma Science and Fusion Center, Cambridge, Massachusetts 02139

    E-Print Network [OSTI]

    Egedal, Jan

    of the beam confinement. Losses due to nonadiabatic changes in the magnetic moment are also evaluated. Due: 10.1063/1.1569490# I. INTRODUCTION One of the important methods for heating magnetically confinedEfficient evaluation of beam ion confinement in spherical tokamaks J. Egedal Massachusetts

  19. Efficient evaluation of beam ion confinement in spherical tokamaks Massachusetts Institute of Technology, Plasma Science and Fusion Center, Cambridge, Massachusetts 02139

    E-Print Network [OSTI]

    Egedal, Jan

    of the beam confinement. Losses due to nonadiabatic changes in the magnetic moment are also evaluated. Due: 10.1063/1.1569490 I. INTRODUCTION One of the important methods for heating magnetically confinedEfficient evaluation of beam ion confinement in spherical tokamaks J. Egedal Massachusetts

  20. Innovative Manufacturing and Materials for Low-Cost Lithium-Ion...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Lithium-Ion Batteries Innovative Manufacturing and Materials for Low-Cost Lithium-Ion Batteries 2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual...

  1. Significant Cost Improvement of Li-Ion Cells Through Non-NMP...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Significant Cost Improvement of Li-Ion Cells Through Non-NMP Electrode Coating, Direct Separator Coating, and Fast Formation Technologies Significant Cost Improvement of Li-Ion...

  2. Secondary Waste Considerations for Vitrification of Sodium-Bearing Waste at the Idaho Nuclear Technology and Engineering Center FY-2001 Status Report

    SciTech Connect (OSTI)

    Herbst, A.K.; Kirkham, R.J.; Losinski, S.J.

    2002-09-26

    The Idaho Nuclear Technology and Engineering Center (INTEC) is considering vitrification to process liquid sodium-bearing waste. Preliminary studies were completed to evaluate the potential secondary wastes from the melter off-gas clean up systems. Projected secondary wastes comprise acidic and caustic scrubber solutions, HEPA filters, activated carbon, and ion exchange media. Possible treatment methods, waste forms, and disposal sites are evaluated from radiological and mercury contamination estimates.

  3. Vehicle Technologies Office Merit Review 2015: Dramatically Improve the Safety Performance of Li Ion Battery Separators and Reduce the Manufacturing Cost using Ultraviolet Curing and High Precision Coating Technologies

    Office of Energy Efficiency and Renewable Energy (EERE)

    Presentation given by Miltec UV International at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about dramatically improve...

  4. Information Technology Tools for Multifamily Building Programs...

    Broader source: Energy.gov (indexed) [DOE]

    Program Multifamily Low-Income Peer Exchange Call: Information Technology Tools for Multifamily Building Programs, Call Slides and Discussion Summary, March 15, 2012. Call Slides...

  5. Wound tube heat exchanger

    DOE Patents [OSTI]

    Ecker, Amir L. (Duncanville, TX)

    1983-01-01

    What is disclosed is a wound tube heat exchanger in which a plurality of tubes having flattened areas are held contiguous adjacent flattened areas of tubes by a plurality of windings to give a double walled heat exchanger. The plurality of windings serve as a plurality of effective force vectors holding the conduits contiguous heat conducting walls of another conduit and result in highly efficient heat transfer. The resulting heat exchange bundle is economical and can be coiled into the desired shape. Also disclosed are specific embodiments such as the one in which the tubes are expanded against their windings after being coiled to insure highly efficient heat transfer.

  6. Heat and mass exchanger

    DOE Patents [OSTI]

    Lowenstein, Andrew (Princeton, NJ); Sibilia, Marc J. (Princeton, NJ); Miller, Jeffrey A. (Hopewell, NJ); Tonon, Thomas (Princeton, NJ)

    2011-06-28

    A mass and heat exchanger includes at least one first substrate with a surface for supporting a continuous flow of a liquid thereon that either absorbs, desorbs, evaporates or condenses one or more gaseous species from or to a surrounding gas; and at least one second substrate operatively associated with the first substrate. The second substrate includes a surface for supporting the continuous flow of the liquid thereon and is adapted to carry a heat exchange fluid therethrough, wherein heat transfer occurs between the liquid and the heat exchange fluid.

  7. Heat and mass exchanger

    DOE Patents [OSTI]

    Lowenstein, Andrew (Princeton, NJ); Sibilia, Marc J. (Princeton, NJ); Miller, Jeffrey A. (Hopewell, NJ); Tonon, Thomas (Princeton, NJ)

    2007-09-18

    A mass and heat exchanger includes at least one first substrate with a surface for supporting a continuous flow of a liquid thereon that either absorbs, desorbs, evaporates or condenses one or more gaseous species from or to a surrounding gas; and at least one second substrate operatively associated with the first substrate. The second substrate includes a surface for supporting the continuous flow of the liquid thereon and is adapted to carry a heat exchange fluid therethrough, wherein heat transfer occurs between the liquid and the heat exchange fluid.

  8. A Semi-Empirical Model for Porous Media Heat Exchanger Design Richard A. Wirtz1

    E-Print Network [OSTI]

    Wirtz, Richard A.

    A Semi-Empirical Model for Porous Media Heat Exchanger Design Richard A. Wirtz1 Mechanical-dimensional temperature Introduction Compact heat exchangers invariably incorporate heat transfer augmentation technology matrix at the fluid-solid interface of a compact heat exchanger will also enhance performance

  9. Vehicle Technologies Office Merit Review 2014: Development of Cell/Pack Level Models for Automotive Li-Ion Batteries with Experimental Validation

    Broader source: Energy.gov [DOE]

    Presentation given by EC Power at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about evelopment of cell/pack level models...

  10. Vehicle Technologies Office Merit Review 2014: High Energy Density Li-ion Cells for EV’s Based on Novel, High Voltage Cathode Material Systems

    Broader source: Energy.gov [DOE]

    Presentation given by Farasis Energy, Inc. at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about high energy density Li...

  11. Vehicle Technologies Office Merit Review 2015: IR Thermography as a Non-Destructive Evaluation (NDE) Tool for Lithium-Ion Battery Manufacturing

    Broader source: Energy.gov [DOE]

    Presentation given by Oak Ridge National Laboratory at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about IR thermography...

  12. Active microchannel heat exchanger

    DOE Patents [OSTI]

    Tonkovich, Anna Lee Y. (Pasco, WA) [Pasco, WA; Roberts, Gary L. (West Richland, WA) [West Richland, WA; Call, Charles J. (Pasco, WA) [Pasco, WA; Wegeng, Robert S. (Richland, WA) [Richland, WA; Wang, Yong (Richland, WA) [Richland, WA

    2001-01-01

    The present invention is an active microchannel heat exchanger with an active heat source and with microchannel architecture. The microchannel heat exchanger has (a) an exothermic reaction chamber; (b) an exhaust chamber; and (c) a heat exchanger chamber in thermal contact with the exhaust chamber, wherein (d) heat from the exothermic reaction chamber is convected by an exothermic reaction exhaust through the exhaust chamber and by conduction through a containment wall to the working fluid in the heat exchanger chamber thereby raising a temperature of the working fluid. The invention is particularly useful as a liquid fuel vaporizer and/or a steam generator for fuel cell power systems, and as a heat source for sustaining endothermic chemical reactions and initiating exothermic reactions.

  13. Energy Exchange Schedule

    Broader source: Energy.gov [DOE]

    The schedule for Energy Exchange is now available. Attendees will have the option of attending a variety of training sessions offered within 10 tracks during the times listed below. Session details...

  14. Greywater heat exchanger

    SciTech Connect (OSTI)

    Holmberg, D.

    1983-11-21

    A kilowatt meter and water meter were installed to monitor pregreywater usage. The design considerations, the heat exchanger construction and installation, and the monitoring of usage levels are described.

  15. Isothermal Ice-Crystallization Kinetics in the Gas-Diffusion Layer of a Proton-Exchange-Membrane Fuel Cell

    E-Print Network [OSTI]

    Dursch, Thomas J.

    2013-01-01

    Renewable Energy, Office of Fuel Cell Technologies, of theProton-Exchange- Membrane Fuel Cell T. J. Dursch, 1,2 M. A.proton-exchange membrane fuel cell (PEMFC) are investigated

  16. Radial flow heat exchanger

    DOE Patents [OSTI]

    Valenzuela, Javier (Hanover, NH)

    2001-01-01

    A radial flow heat exchanger (20) having a plurality of first passages (24) for transporting a first fluid (25) and a plurality of second passages (26) for transporting a second fluid (27). The first and second passages are arranged in stacked, alternating relationship, are separated from one another by relatively thin plates (30) and (32), and surround a central axis (22). The thickness of the first and second passages are selected so that the first and second fluids, respectively, are transported with laminar flow through the passages. To enhance thermal energy transfer between first and second passages, the latter are arranged so each first passage is in thermal communication with an associated second passage along substantially its entire length, and vice versa with respect to the second passages. The heat exchangers may be stacked to achieve a modular heat exchange assembly (300). Certain heat exchangers in the assembly may be designed slightly differently than other heat exchangers to address changes in fluid properties during transport through the heat exchanger, so as to enhance overall thermal effectiveness of the assembly.

  17. Transport of multiply and highly charged ions through nanoscale apertures in silicon nitride membranes

    E-Print Network [OSTI]

    . PACS: 34.50.Dy Keywords: Slow highly charged ions; Capillary transmission; Charge exchange 1-the-barrier model (COB) [4­7]. The model can be used to estimate the critical distance for charge transfer dc exchange of multiply and highly charged ions for transmission of aper- tures in silicon nitride targets

  18. The evolution of ion charge states in cathodic vacuum arc plasmas: a review

    SciTech Connect (OSTI)

    Anders, Andre

    2011-12-18

    Cathodic vacuum arc plasmas are known to contain multiply charged ions. 20 years after “Pressure Ionization: its role in metal vapour vacuum arc plasmas and ion sources” appeared in vol. 1 of Plasma Sources Science and Technology, it is a great opportunity to re-visit the issue of pressure ionization, a non-ideal plasma effect, and put it in perspective to the many other factors that influence observable charge state distributions, such as the role of the cathode material, the path in the density-temperature phase diagram, the “noise” in vacuum arc plasma as described by a fractal model approach, the effects of external magnetic fields and charge exchange collisions with neutrals. A much more complex image of the vacuum arc plasma emerges putting decades of experimentation and modeling in perspective.

  19. Synthesis of Anion Exchange Polystyrene Membranes for the Electrolysis of

    E-Print Network [OSTI]

    Singh, Jayant K.

    - moval of chloride ions. The composite membrane is homogeneously modified by gas phase nitration separation technique, in which electrically charged membranes are used and electrical poten- tial differenceSynthesis of Anion Exchange Polystyrene Membranes for the Electrolysis of Sodium Chloride Sonny

  20. Cationanion versus cationframework interactions in sodalites: First-principles study of model Cu-exchanged sodalites

    E-Print Network [OSTI]

    Selloni, Annabella

    as catalysts for the reduction of NOx compounds.6­8 In this respect, Cu- exchanged sodalites may represent for silver-exchanged sodalites. The reduction of the lattice parameter is accompanied by the formation of Cu ions per cage, resulting in a simultaneous reduction of Cu­framework distances. For fully

  1. Performance Characteristics of Lithium-ion Batteries of Various Chemistries for Plug-in Hybrid Vehicles

    E-Print Network [OSTI]

    Burke, Andrew; Miller, Marshall

    2009-01-01

    for vehicle applications. 2 Lithium-ion battery chemistriesThe lithium-ion battery technology used for consumerfrom EIG Figure 4: Lithium-ion battery modules for testing

  2. Heavy ion medical accelerator options

    SciTech Connect (OSTI)

    Gough, R.A.; Alonso, J.R.

    1985-01-01

    This paper briefly explores the accelerator technology available for heavy ion medical accelerators in the mass range of 1 to 40 (protons through argon). Machines that are designed to produce the required intensities of a particular design ion, such as silicon (mass 28), can satisfy the intensity requirements for all lighter ions, and can produce beams with higher mass, such as argon, at somewhat reduced, but still useful intensity levels. They can also provide beams of radioactive ions, such as carbon-11 and neon-19, which are useful in diagnostic imaging and for directly verifiable treatments. These accelerators are all based on proven technology, and can be built at predictable costs. It is the conclusion of several design studies that they can be operated reliably in a hospital-based environment. 8 refs., 22 figs.

  3. Towards a cryogenic planar ion trap for Sr-88

    E-Print Network [OSTI]

    Bakr, Waseem (Waseem S.)

    2006-01-01

    This thesis describes experiments with ion traps constructed with electrodes in a single two-dimensional plane, and ion traps operated in a cryogenic environment at 77K and 4K temperatures. These two technologies address ...

  4. Thermoacoustic imaging using heavy ion beams

    SciTech Connect (OSTI)

    Claytor, T.N.; Tesmer, J.R.; Deemer, B.C.; Murphy, J.C.

    1995-10-01

    Ion beams have been used for surface modification, semiconductor device fabrication and for material analysis, which makes ion-material interactions of significant importance. Ion implantation will produce new compositions near the surface by ion mixing or directly by implanting desired ions. Ions exchange their energy to the host material as they travel into the material by several different processes. High energy ions ionize the host atoms before atomic collisions transfer the remaining momentum and stop the incident ion. As they penetrate the surface, the low energy ions ionize the host atoms, but also have a significantly large momentum transfer mechanism near the surface of the material. This leads to atoms, groups of atoms and electrons being ejected from the surface, which is the momentum transfer process of sputtering. This talk addresses the acoustic waves generated during ion implantation using modulated heavy ion beams. The mechanisms for elastic wave generation during ion implantation, in the regimes where sputtering is significant and where implantation is dominant and sputtering is negligible, has been studied. The role of momentum transfer and thermal energy production during ion implantation was compared to laser generated elastic waves in an opaque solid as a reference, since laser generated ultrasound has been extensively studied and is fairly well understood. The thermoelastic response dominated in both high and low ion energy regimes since, apparently, more energy is lost to thermal heat producing mechanisms than momentum transfer processes. The signal magnitude was found to vary almost linearly with incident energy as in the laser thermoelastic regime. The time delays for longitudinal and shear waves-were characteristic of those expected for a purely thermal heating source. The ion beams are intrinsically less sensitive to the albedo of the surface.

  5. Utilization of UV or EB Curing Technology to Significantly Reduce...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Curing Technology to Significantly Reduce Costs and VOCs in the Manufacture of Lithium-Ion Battery Electrodes Utilization of UV or EB Curing Technology to Significantly Reduce...

  6. Ankara, Turkey Exchange Program

    E-Print Network [OSTI]

    Fernandez, Eduardo

    Ankara, Turkey Exchange Program Bilkent University Bilkent University (BU) was founded in 1984 as Turkey's first private, non-profit institution of higher education. BU is recognized and ranked internationally as the premier institution of higher education in Turkey. Its lively campus with its cultural

  7. Brazil, Florianpolis Exchange Program

    E-Print Network [OSTI]

    Fernandez, Eduardo

    Brazil, Florianópolis Exchange Program Universidade do Sul de Santa Catarina (UNISUL) Brazil, one Culture through Music and Cinema (Beg./Int. level), (Alternative Media and Social Movements in Brazil (int Economics in the Age of Globalization: focus in Brazil Consumer Behavior Ethnicity and Society

  8. A corrosive resistant heat exchanger

    DOE Patents [OSTI]

    Richlen, S.L.

    1987-08-10

    A corrosive and erosive resistant heat exchanger which recovers heat from a contaminated heat stream. The heat exchanger utilizes a boundary layer of innocuous gas, which is continuously replenished, to protect the heat exchanger surface from the hot contaminated gas. The innocuous gas is pumped through ducts or perforations in the heat exchanger wall. Heat from the heat stream is transferred by radiation to the heat exchanger wall. Heat is removed from the outer heat exchanger wall by a heat recovery medium. 3 figs., 3 tabs.

  9. Electrode Materials for Rechargeable Lithium-Ion Batteries: A...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electrode Materials for Rechargeable Lithium-Ion Batteries: A New Synthetic Approach Technology available for licensing: New high-energy cathode materials for use in rechargeable...

  10. Novel Redox Shuttles for Overcharge Protection of Lithium-Ion...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Redox Shuttles for Overcharge Protection of Lithium-Ion Batteries Technology available for licensing: Electrolytes containing novel redox shuttles (electron transporters) for...

  11. A Better Anode Design to Improve Lithium-Ion Batteries

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    electronics, and the newest electric cars. Good as these batteries are, the need for energy storage in batteries is surpassing current technologies. In a lithium-ion battery,...

  12. Lithium Ion Electrode Production NDE and QC Considerations |...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Lithium Secondary Batteries Vehicle Technologies Office Merit Review 2015: Electrode Coating Defect Analysis and Processing NDE for High-Energy Lithium-Ion Batteries Roll-to-Roll...

  13. Setup Exchange 2010 on an Android Device Exchange 2010

    E-Print Network [OSTI]

    Calgary, University of

    Setup Exchange 2010 on an Android Device Exchange 2010 The following instructions are for setting up an Exchange 2010 account on an Android device such as a Samsung Galaxy III or tablet. These instructions are designed for devices using the 4.1 or better Android operating system. You will need to use

  14. Optimal electrode geometries for 2-dimensional ion arrays with bi-layer ion traps

    E-Print Network [OSTI]

    F. N. Krauth; J. Alonso; J. P. Home

    2014-11-04

    We investigate electrode geometries required to produce periodic 2-dimensional ion-trap arrays with the ions placed between two planes of electrodes. We present a generalization of previous methods for traps containing a single electrode plane to this new geometry, and show that for a given ion-electrode distance and applied voltages, the inter-ion distance can be reduced by a factor of up to 3 relative to single-plane traps. This represents an increase by a factor of 9 in the trap density and a factor of 27 in the exchange coupling between the oscillatory motion of neighboring ions. The resulting traps are also considerably deeper for bi-layer structures than for single-plane traps. These results could offer a useful path towards 2-dimensional ion arrays for quantum simulation. We also discuss issues with the fabrication of such traps.

  15. Building Energy Data Exchange Specification Scoping Report |...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Building Energy Data Exchange Specification Scoping Report Building Energy Data Exchange Specification Scoping Report The Building Energy Data Exchange Specification (BEDES),...

  16. Information Exchange Among Collaborating Enterprises

    E-Print Network [OSTI]

    Hsu, Cheng

    Information Exchange Among Collaborating Enterprises David Levermore1 , Gilbert Babin2 , and Cheng enterprises. Otherwise, the exchange tends to be limited at the level of file transfers. To overcome a new information exchange model to extend previous global query results and cover independent databases

  17. The allowance exchange - ALEX

    SciTech Connect (OSTI)

    Mangis, J.K.; Miller, C.; Nicholas, J.

    1997-12-31

    The success of market approaches to pollution control in reducing the cost of compliance with environmental regulation, has insured the inclusion of emissions trading programs in current and future regulatory programs. As these environmental trading programs multiply, (SO{sub 2}, NO{sub x}, Ozone Precursors, Wetlands, CO{sub 2} and others), utility companies will need a central location to buy, sell, and trade these allowances to meet regulatory needs. In response, SAIC has designed and prototyped an electronic trading system that can provide a common forum for the location and exchange of environmental allowances, marketable permits, and other market based instruments for environmental management. SAIC intends to open and operate the Allowance Exchange (ALEX) for the trading of all environmental allowances, associated with the operation of electric utilities, as a service to the nation, the industry, and the environmental community.

  18. Energy Exchange Attendee Guide

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Education Units (CEUs) 1 Session Speaker Biographies & Presentations 1 Emerging Technology Pavilion 1 Plenary Speakers 2 Agenda at Glance 4 Track Overview 5 Session...

  19. Heat exchange apparatus

    DOE Patents [OSTI]

    Degtiarenko, Pavel V.

    2003-08-12

    A heat exchange apparatus comprising a coolant conduit or heat sink having attached to its surface a first radial array of spaced-apart parallel plate fins or needles and a second radial array of spaced-apart parallel plate fins or needles thermally coupled to a body to be cooled and meshed with, but not contacting the first radial array of spaced-apart parallel plate fins or needles.

  20. Thermoelectric heat exchange element

    DOE Patents [OSTI]

    Callas, James J. (Peoria, IL); Taher, Mahmoud A. (Peoria, IL)

    2007-08-14

    A thermoelectric heat exchange module includes a first substrate including a heat receptive side and a heat donative side and a series of undulatory pleats. The module may also include a thermoelectric material layer having a ZT value of 1.0 or more disposed on at least one of the heat receptive side and the heat donative side, and an electrical contact may be in electrical communication with the thermoelectric material layer.

  1. DOE Energy Exchange

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:FinancingPetroleum Based| Department ofRefrigerators | Department DOE Energy Exchange Ms. Amanda

  2. Performance of an inverted ion source

    SciTech Connect (OSTI)

    Salvadori, M. C.; Teixeira, F. S.; Sgubin, L. G.; Araujo, W. W. R.; Spirin, R. E.; Oks, E. M.; Brown, I. G.

    2013-02-15

    Whereas energetic ion beams are conventionally produced by extracting ions (say, positive ions) from a plasma that is held at high (positive) potential, with ion energy determined by the potential drop through which the ions fall in the beam formation electrode system, in the device described here the plasma and its electronics are held at ground potential and the ion beam is formed and injected energetically into a space maintained at high (negative) potential. We refer to this configuration as an 'inverted ion source.' This approach allows considerable savings both technologically and economically, rendering feasible some ion beam applications, in particular small-scale ion implantation, that might otherwise not be possible for many researchers and laboratories. We have developed a device of this kind utilizing a metal vapor vacuum arc plasma source, and explored its operation and beam characteristics over a range of parameter variation. The downstream beam current has been measured as a function of extraction voltage (5-35 kV), arc current (50-230 A), metal ion species (Ti, Nb, Au), and extractor grid spacing and beamlet aperture size (3, 4, and 5 mm). The downstream ion beam current as measured by a magnetically-suppressed Faraday cup was up to as high as 600 mA, and with parametric variation quite similar to that found for the more conventional metal vapor vacuum arc ion source.

  3. Non-aqueous liquid compositions comprising ion exchange polymers

    DOE Patents [OSTI]

    Kim, Yu Seung; Lee, Kwan-Soo; Rockward, Tommy Q. T.

    2013-03-12

    Compositions, and methods of making thereof, comprising from about 1% to about 5% of a perfluorinated sulfonic acid ionomer or a hydrocarbon-based ionomer; and from about 95% to about 99% of a solvent, said solvent consisting essentially of a polyol; wherein said composition is substantially free of water and wherein said ionomer is uniformly dispersed in said solvent.

  4. Non-aqueous liquid compositions comprising ion exchange polymers

    DOE Patents [OSTI]

    Kim, Yu Seung (Los Alamos, NM); Lee, Kwan-Soo (Blacksburg, VA); Rockward, Tommy Q. T. (Rio Rancho, NM)

    2011-07-19

    Compositions, and methods of making thereof, comprising from about 1% to about 5% of a perfluorinated sulfonic acid ionomer or a hydrocarbon-based ionomer; and from about 95% to about 99% of a solvent, said solvent consisting essentially of a polyol; wherein said composition is substantially free of water and wherein said ionomer is uniformly dispersed in said solvent.

  5. The Ion-Exchange Separation of Zirconium and Hafnium

    E-Print Network [OSTI]

    Street, Kenneth Jr.; Seaborg, Glenn T.

    2008-01-01

    Special Weapons Projeot Atomic Energy Commission, Washingtonauspices of the Atomic Energy Commission at the Radiation

  6. The Dynamics of Platinum Precipitation in an Ion Exchange Membrane

    E-Print Network [OSTI]

    Burlatsky, S F; Atrazhev, V V; Dmitriev, D V; Kuzminyh, N Y; Erikhman, N S

    2013-01-01

    Microscopy of polymer electrolyte membranes that have undergone operation under fuel cell conditions, have revealed a well defined band of platinum in the membrane. Here, we propose a physics based model that captures the mechanism of platinum precipitation in the polymer electrolyte membrane. While platinum is observed throughout the membrane, the preferential growth of platinum at the band of platinum is dependent on the electrochemical potential distribution in the membrane. In this paper, the location of the platinum band is calculated as a function of the gas concentration at the cathode and anode, gas diffusion coefficients and solubility constants of the gases in the membrane, which are functions of relative humidity. Under H2/N2 conditions the platinum band is located near the cathode-membrane interface, as the oxygen concentration in the cathode gas stream increases and/or the hydrogen concentration in the anode gas stream decreases, the band moves towards the anode. The model developed in this paper...

  7. Uranium Adsorption on Ion-Exchange Resins - Batch Testing

    SciTech Connect (OSTI)

    Mattigod, Shas V.; Golovich, Elizabeth C.; Wellman, Dawn M.; Cordova, Elsa A.; Smith, Ronald M.

    2010-12-01

    The uranium adsorption performance of five resins (Dowex 1, Dowex 21K 16-30 [fresh], Dowex 21K 16-30 [regenerated], Purofine PFA600/4740, and ResinTech SIR-1200) were tested using unspiked, nitrate-spiked, and nitrate-spiked/pH adjusted source water from well 299-W19-36. These batch tests were conducted in support of a resin selection process in which the best resin to use for uranium treatment in the 200-West Area groundwater pump-and-treat system will be identified. The results from these tests are as follows: • The data from the high-nitrate (1331 mg/L) tests indicated that Dowex 1, Dowex 21K 16-30 (fresh), Purofine PFA600/4740, and ResinTech SIR-1200 all adsorbed uranium similarly well with Kd values ranging from ~15,000 to 95,000 ml/g. All four resins would be considered suitable for use in the treatment system based on uranium adsorption characteristics. • Lowering the pH of the high nitrate test conditions from 8.2 to 7.5 did not significantly change the uranium adsorption isotherms for the four tested resins. The Kd values for these four resins under high nitrate (1338 mg/L), lower pH (7.5) ranged from ~15,000 to 80,000 ml/g. • Higher nitrate concentrations greatly reduced the uranium adsorption on all four resins. Tests conducted with unspiked (no amendments; nitrate at 337 mg/L and pH at 8.2) source water yielded Kd values for Dowex 1, Dowex 21K 16-30 (fresh), Purofine PFA600/4740, and ResinTech SIR-1200 resins ranging from ~800,000 to >3,000,000 ml/g. These values are about two orders of magnitude higher than the Kd values noted from tests conducted using amended source water. • Compared to the fresh resin, the regenerated Dowex 21K 16-30 resin exhibited significantly lower uranium-adsorption performance under all test conditions. The calculated Kd values for the regenerated resin were typically an order of magnitude lower than the values calculated for the fresh resin. • Additional testing using laboratory columns is recommended to better resolve differences between the adsorption abilities of the resins and to develop estimates of uranium loading on the resins. By determining the quantity of uranium that each resin can adsorb and the time required to reach various levels of loading, resin lifetime in the treatment system can be estimated.

  8. Ion Rings for Magnetic Fusion

    SciTech Connect (OSTI)

    Greenly, John, B.

    2005-07-31

    This Final Technical Report presents the results of the program, Ion Rings for Magnetic Fusion, which was carried out under Department of Energy funding during the period August, 1993 to January, 2005. The central objective of the program was to study the properties of field-reversed configurations formed by ion rings. In order to reach this objective, our experimental program, called the Field-reversed Ion Ring Experiment, FIREX, undertook to develop an efficient, economical technology for the production of field-reversed ion rings. A field-reversed configuration (FRC) in which the azimuthal (field-reversing) current is carried by ions with gyro-radius comparable to the magnetic separatrix radius is called a field-reversed ion ring. A background plasma is required for charge neutralization of the ring, and this plasma will be confined within the ring's closed magnetic flux. Ion rings have long been of interest as the basis of compact magnetic fusion reactors, as the basis for a high-power accelerator for an inertial fusion driver, and for other applications of high power ion beams or plasmas of high energy density. Specifically, the FIREX program was intended to address the longstanding question of the contribution of large-orbit ions to the observed stability of experimental FRCs to the MHD tilt mode. Typical experimental FRCs with s {approx} 2-4, where s is the ratio of separatrix radius to ion gyro-radius, have been stable to tilting, but desired values for a fusion reactor, s > 20, should be unstable. The FIREX ring would consist of a plasma with large s for the background ions, but with s {approx} 1 for the ring ions. By varying the proportions of these two populations, the minimum proportion of large-orbit ions necessary for stability could be determined. The incorporation of large-orbit ions, perhaps by neutral-beam injection, into an FRC has been advanced for the purpose of stabilizing, heating, controlling angular momentum, and aiding the formation of a reactor-scale FRC, and the FIREX program was intended to test the ideas behind this approach. We will describe in this report the technological development path and advances in physics understanding that allowed FIREX to reach a regime in which ion rings were reproducibly created with up to about half the current necessary to produce field reversal. Unfortunately, the experiments were limited to this level by a fundamental, unanticipated aspect of the physics of strong ion rings in plasma. The FIREX ring is a strongly anisotropic, current-carrying population of ions moving faster than the Alfven speed in the background plasma. The rapidly changing ring current excites very large-amplitude Alfven waves in the plasma, and these waves strongly affect the ring, causing rapid energy loss in a way that is not compatible with the success of the ring trapping scenario around which FIREX was designed. The result was that FIREX rings were always very short-lived. We will discuss the implication of these results for possible future use of large-orbit ions in FRCs. In short, it appears that a certain range of the parameters characterizing the ring Alfven mach number and distribution function must be avoided to allow the existence of a long-lived energetic ion component in an FRC. This report will explain why FIREX experimental results cannot be directly scaled to quantitatively predict this range for a particular FRC configuration. This will require accurate, three-dimensional simulations. FIREX results do constitute a very good dataset for validating such a code, and simulations already carried out during this program provide a guide to the important physics involved.

  9. Better Buildings Neighborhood Program Workforce Peer Exchange...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Neighborhood Program Workforce Peer Exchange Call: Contractor Pricing Better Buildings Neighborhood Program Workforce Peer Exchange Call: Contractor Pricing Better Buildings...

  10. Ion Temperature Evolution in an Ultracold Neutral Plasma

    E-Print Network [OSTI]

    McQuillen, P; Langin, T; Killian, T C

    2015-01-01

    We study the long-time evolution of the ion temperature in an expanding ultracold neutral plasma using spatially resolved, laser-induced-fluorescence spectroscopy. Adiabatic cooling reduces the ion temperature by an order of magnitude during the plasma expansion, to temperatures as low as 0.2 K. Cooling is limited by heat exchange between ions and the much hotter electrons. We also present evidence for an additional heating mechanism and discuss possible sources. Data are described by a model of the plasma evolution, including the effects of ion-electron heat exchange. We show that for appropriate initial conditions, the degree of Coulomb coupling of ions in the plasma increases during expansion.

  11. Microstructural Modeling and Design of Rechargeable Lithium-Ion Batteries

    E-Print Network [OSTI]

    García, R. Edwin

    Microstructural Modeling and Design of Rechargeable Lithium-Ion Batteries R. Edwin Garci´a,a, *,z microstructure. Experi- mental measurements are reproduced. Early models for lithium-ion batteries were developed Institute of Technology, Cambridge, Massachusetts 01239-4307, USA The properties of rechargeable lithium-ion

  12. Microsoft Exchange Archives - Nercenergy

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformationJesse BergkampCentermillionStockpileEqual EmploymentElectricity &Exchange

  13. Priority Firm Exchange .

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home RoomPreservation of Fe(II) by Carbon-Rich Matrices inPrincipalFirm Exchange . . . . . . . . . . . .

  14. NGNP Process Heat Utilization: Liquid Metal Phase Change Heat Exchanger

    SciTech Connect (OSTI)

    Piyush Sabharwall; Mike Patterson; Vivek Utgikar; Fred Gunnerson

    2008-09-01

    One key long-standing issue that must be overcome to fully realize the successful growth of nuclear power is to determine other benefits of nuclear energy apart from meeting the electricity demands. The Next Generation Nuclear Plant (NGNP) will most likely be producing electricity and heat for the production of hydrogen and/or oil retrieval from oil sands and oil shale to help in our national pursuit of energy independence. For nuclear process heat to be utilized, intermediate heat exchange is required to transfer heat from the NGNP to the hydrogen plant or oil recovery field in the most efficient way possible. Development of nuclear reactor - process heat technology has intensified the interest in liquid metals as heat transfer media because of their ideal transport properties. Liquid metal heat exchangers are not new in practical applications. An important rational for considering liquid metals is the potential convective heat transfer is among the highest known. Thus explains the interest in liquid metals as coolant for intermediate heat exchange from NGNP. For process heat it is desired that, intermediate heat exchangers (IHX) transfer heat from the NGNP in the most efficient way possible. The production of electric power at higher efficiency via the Brayton Cycle, and hydrogen production, requires both heat at higher temperatures and high effectiveness compact heat exchangers to transfer heat to either the power or process cycle. Compact heat exchangers maximize the heat transfer surface area per volume of heat exchanger; this has the benefit of reducing heat exchanger size and heat losses. High temperature IHX design requirements are governed in part by the allowable temperature drop between the outlet and inlet of the NGNP. In order to improve the characteristics of heat transfer, liquid metal phase change heat exchangers may be more effective and efficient. This paper explores the overall heat transfer characteristics and pressure drop of the phase change heat exchanger with Na as the heat exchanger coolant. In order to design a very efficient and effective heat exchanger one must optimize the design such that we have a high heat transfer and a lower pressure drop, but there is always a trade-off between them. Based on NGNP operational parameters, a heat exchanger analysis with the sodium phase change will be presented to show that the heat exchanger has the potential for highly effective heat transfer, within a small volume at reasonable cost.

  15. Heat exchanger-accumulator

    DOE Patents [OSTI]

    Ecker, Amir L. (Dallas, TX)

    1980-01-01

    What is disclosed is a heat exchanger-accumulator for vaporizing a refrigerant or the like, characterized by an upright pressure vessel having a top, bottom and side walls; an inlet conduit eccentrically and sealingly penetrating through the top; a tubular overflow chamber disposed within the vessel and sealingly connected with the bottom so as to define an annular outer volumetric chamber for receiving refrigerant; a heat transfer coil disposed in the outer volumetric chamber for vaporizing the liquid refrigerant that accumulates there; the heat transfer coil defining a passageway for circulating an externally supplied heat exchange fluid; transferring heat efficiently from the fluid; and freely allowing vaporized refrigerant to escape upwardly from the liquid refrigerant; and a refrigerant discharge conduit penetrating sealingly through the top and traversing substantially the length of the pressurized vessel downwardly and upwardly such that its inlet is near the top of the pressurized vessel so as to provide a means for transporting refrigerant vapor from the vessel. The refrigerant discharge conduit has metering orifices, or passageways, penetrating laterally through its walls near the bottom, communicating respectively interiorly and exteriorly of the overflow chamber for controllably carrying small amounts of liquid refrigerant and oil to the effluent stream of refrigerant gas.

  16. Design issues of a thermoacoustic refrigerator and its heat exchangers

    SciTech Connect (OSTI)

    Wetzel, M.; Herman, C.

    1996-12-31

    Thermoacoustic refrigeration is a fast advancing new refrigeration technology. Performance calculations indicate remarkable values for the thermoacoustic core of a thermoacoustic refrigerator. The thermoacoustic core is responsible for pumping heat from a cold to a hot temperature reservoir. However, the systems necessary to support the thermoacoustic core, such as heat exchangers and acoustic drivers are the weak points of this refrigeration technology. Particularly, heat exchangers were designed so far without any optimization. A reason for this is the lack of knowledge of the flow structures and heat transfer phenomena at the interface between the thermoacoustic core and the heat exchangers. For the purpose of gaining better insight, the authors built a thermoacoustic refrigerator model and applied visualization techniques, such as smoke injection and holographic interferometry, to visualize the flow and temperature fields at the interface.

  17. Neutralization principles for the Extraction and Transport of Ion Beams

    E-Print Network [OSTI]

    Riege, H

    2000-01-01

    The strict application of conventional extraction techniques of ion beams from a plasma source is characterized by a natural intensity limit determined by space charge.The extracted current may be enhanced far beyond this limit by neutralizing the space charge of the extracted ions in the first extraction gap of the source with electrons injected from the opposite side. The transverse and longitudinal emittances of a neutralized ion beam, hence its brightness, are preserved. Results of beam compensation experiments, which have been carried out with a laser ion source, are resumed for proposing a general scheme of neutralizing ion sources and their adjacent low-energy beam transport channels with electron beams. Many technical applications of high-mass ion beam neutralization technology may be identified: the enhancement of ion source output for injection into high-intensity, low-and high-energy accelerators, or ion thrusters in space technology, for the neutral beams needed for plasma heating of magnetic conf...

  18. Optimization of Heat Exchanger Cleaning 

    E-Print Network [OSTI]

    Siegell, J. H.

    1986-01-01

    EXCHANGER CLEANING Jeffrey H. Siegell Exxon Research and Engineering Company Florham Park, New Jersey ABSTRACT The performance of heat integration systems is quantified in terms of the amount of heat that is recovered. This decreases with time due... to increased fouling of the heat exchange surface. Using the "Total Fouling Related Expenses (TFRE)" approach, economic incentives for heat exchanger cleaning are evaluated using linear, exponential, and exponential finite decrease models of the heat...

  19. An Inventor's GuIde to InnovAtIons

    E-Print Network [OSTI]

    An Inventor's GuIde to InnovAtIons CommerCIAlIzAtIon At old domInIon unIversIty #12;ContACt us odu.edu/facultystaff/ research/innovations- commercialization 757-683-4027 the Inventor's GuIde to InnovAtIons Commer of Michigan Tech Transfer's "An Inventor's Guide to Technology Transfer." We would like to thank

  20. Improved ion source

    DOE Patents [OSTI]

    Leung, K.N.; Ehlers, K.W.

    1982-05-04

    A magnetic filter for an ion source reduces the production of undesired ion species and improves the ion beam quality. High-energy ionizing electrons are confined by the magnetic filter to an ion source region, where the high-energy electrons ionize gas molecules. One embodiment of the magnetic filter uses permanent magnets oriented to establish a magnetic field transverse to the direction of travel of ions from the ion source region to the ion extraction region. In another embodiment, low energy 16 eV electrons are injected into the ion source to dissociate gas molecules and undesired ion species into desired ion species,

  1. Computerising gentlemen: the automation of the London Stock Exchange, c. 1945-1995 

    E-Print Network [OSTI]

    Pardo-Guerra, Juan Pablo

    2011-01-01

    This dissertation concerns the development of market information technologies in the London Stock Exchange, c. 1945-1992. Based on archival research in London, Cambridge and Edinburgh, and 20 semistructured interviews ...

  2. Ion transport across individual sub-continuum graphene nanopores : phenomenology, theory, and implications for industrial separations

    E-Print Network [OSTI]

    Jain, Tarun (Tarun Kumar)

    2015-01-01

    Atomically thin materials, and in particular graphene, provide a new class of solid-state nanopores - apertures that allow for the exchange of matter across thin membranes - with the smallest possible volumes of any ion ...

  3. Gas Exchange, Partial Pressure Gradients,

    E-Print Network [OSTI]

    Riba Sagarra, Jaume

    Gas Exchange, Partial Pressure Gradients, and the Oxygen Window Johnny E. Brian, Jr., M. Inherent unsaturation. Partial pressure vacancy. Most divers with an interest in decompression diving have affect the precise gas exchange occurring in individual areas of the lungs and body tissues. To make

  4. 4, 125164, 2007 Methanol exchange

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    BGD 4, 125­164, 2007 Methanol exchange between grassland and the atmosphere A. Brunner et al. Title Discussions Biogeosciences Discussions is the access reviewed discussion forum of Biogeosciences Methanol (albrecht.neftel@art.admin.ch) 125 #12;BGD 4, 125­164, 2007 Methanol exchange between grassland

  5. ERASMUS EXCHANGE HOUSING APPLICATION FORM

    E-Print Network [OSTI]

    Pfeifer, Holger

    ERASMUS ­ EXCHANGE HOUSING APPLICATION FORM PERSONAL DATA Family Name / Last Name Type your names Permanent Address Street, House Number Postal Code, City Country Phone Number eMail Address MOBILITY August 31. See: www.uni-ulm.de/io/exchange/housing.html Beginning of rental period: End of rental period

  6. Energy Technology Partnership (ETP) Energy Industry Doctorates

    E-Print Network [OSTI]

    Painter, Kevin

    Energy Technology Partnership (ETP) Energy Industry Doctorates in Low Carbon Energy Technologies for Guidance 1. Introduction The Energy Technology Partnership (ETP) has established an Energy Industry for `industry-ready', post-doctoral researchers to enhance energy industry innovation and knowledge exchange

  7. Technology Assessment TECHNOLOGY ASSESSMENT

    E-Print Network [OSTI]

    Rock, Chris

    Technology Assessment 10/14/2004 1 TECHNOLOGY ASSESSMENT STRATEGIC PLAN MISSION STATEMENT Support the Mission of Texas Tech University and the TTU Information Technology Division by providing timely and relevant information and assistance in current and emerging technologies and their practical applications

  8. Bioscience Technology Bioscience Technology

    E-Print Network [OSTI]

    Vertes, Akos

    Bioscience Technology Bioscience Technology Advantage Business Media 100 Enterprise Drive Rockaway, co-director of George Washington University's Institute for Proteomics Technology and Applications-by-point. Manufacturers have stampeded to offer the new technology. Applied Biosystems got out in front in 2004 when

  9. Technological assessment and evaluation of high power batteries and their commercial values

    E-Print Network [OSTI]

    Teo, Seh Kiat

    2006-01-01

    Lithium Ion (Li-ion) battery technology has the potential to compete with the more matured Nickel Metal Hydride (NiMH) battery technology in the Hybrid Electric Vehicle (HEV) energy storage market as it has higher specific ...

  10. Sodium-bearing Waste Treatment Technology Evaluation Report

    SciTech Connect (OSTI)

    Charles M. Barnes; Arlin L. Olson; Dean D. Taylor

    2004-05-01

    Sodium-bearing waste (SBW) disposition is one of the U.S. Department of Energy (DOE) Idaho Operation Office’s (NE-ID) and State of Idaho’s top priorities at the Idaho National Engineering and Environmental Laboratory (INEEL). The INEEL has been working over the past several years to identify a treatment technology that meets NE-ID and regulatory treatment requirements, including consideration of stakeholder input. Many studies, including the High-Level Waste and Facilities Disposition Environmental Impact Statement (EIS), have resulted in the identification of five treatment alternatives that form a short list of perhaps the most appropriate technologies for the DOE to select from. The alternatives are (a) calcination with maximum achievable control technology (MACT) upgrade, (b) steam reforming, (c) cesium ion exchange (CsIX) with immobilization, (d) direct evaporation, and (e) vitrification. Each alternative has undergone some degree of applied technical development and preliminary process design over the past four years. This report presents a summary of the applied technology and process design activities performed through February 2004. The SBW issue and the five alternatives are described in Sections 2 and 3, respectively. Details of preliminary process design activities for three of the alternatives (steam reforming, CsIX, and direct evaporation) are presented in three appendices. A recent feasibility study provides the details for calcination. There have been no recent activities performed with regard to vitrification; that section summarizes and references previous work.

  11. Staff exchange with Chemical Waste Management. Final project report

    SciTech Connect (OSTI)

    Harrer, B.J.; Barak, D.W.

    1993-12-01

    Original objective was transfer of PNL technology and expertise in computational chemistry and waste flow/treatment modeling to CWM. Identification and characterization of a broader portfolio of PNL`s environmental remediation technologies with high potential for rapid application became the focus of the exchange, which included E-mail exchanges. Of the 14 technologies discussed, the following were identified as being of high interest to CWM: six phase soil heating (in-situ heating), high energy electrical corona, RAAS/ReOpt{trademark} (remedial, expert system), TEES{trademark} (catalytic production of methane from biological wastes), PST (process for treating petroleum sludge). CWM`s reorganization and downsizing reduced the potential benefits to industry, but a proposal for transfer and application of PST to Wheelabrator was made.

  12. Modular heat exchanger

    DOE Patents [OSTI]

    Giardina, A.R.

    1981-03-03

    A shell and tube heat exchanger is described having a plurality of individually removable tube bundle modules. A lattice of structural steel forming rectangular openings therein is placed at each end of a cylindrical shell. Longitudinal structural members are placed in the shell between corners of the rectangular openings situated on opposite ends of the shell. Intermediate support members interconnect the longitudinal supports so as to increase the longitudinal supports rigidity. Rectangular parallelepiped tube bundle modules occupy the space defined by the longitudinal supports and end supports and each include a rectangular tube sheet situated on each end of a plurality of tubes extending there through, a plurality of rectangular tube supports located between the tube sheets, and a tube bundle module stiffening structure disposed about the bundle's periphery and being attached to the tube sheets and tube supports. The corners of each tube bundle module have longitudinal framework members which are mateable with and supported by the longitudinal support members. Intermediate support members constitute several lattices, each of which is situated in a plane between the end support members. The intermediate support members constituting the several lattices extend horizontally and vertically between longitudinal supports of adjacent tube module voids. An alternative embodiment for intermediate support members constitute a series of structural plates situated at the corners of the module voids and having recesses therein for receiving the respective longitudinal support members adjacent thereto, protrusions separating the recesses, and a plurality of struts situated between protrusions of adjacent structural plates. 12 figs.

  13. Modular heat exchanger

    DOE Patents [OSTI]

    Giardina, Angelo R. [Marple Township, Delaware County, PA

    1981-03-03

    A shell and tube heat exchanger having a plurality of individually removable tube bundle modules. A lattice of structural steel forming rectangular openings therein is placed at each end of a cylindrical shell. Longitudinal structural members are placed in the shell between corners of the rectangular openings situated on opposite ends of the shell. Intermediate support members interconnect the longitudinal supports so as to increase the longitudinal supports rigidity. Rectangular parallelpiped tube bundle moldules occupy the space defined by the longitudinal supports and end supports and each include a rectangular tube sheet situated on each end of a plurality of tubes extending therethrough, a plurality of rectangular tube supports located between the tube sheets, and a tube bundle module stiffening structure disposed about the bundle's periphery and being attached to the tube sheets and tube supports. The corners of each tube bundle module have longitudinal framework members which are mateable with and supported by the longitudinal support members. Intermediate support members constitute several lattice, each of which is situate d in a plane between the end support members. The intermediate support members constituting the several lattice extend horizontally and vertically between longitudinal supports of adjacent tube module voids. An alternative embodiment for intermediate support members constitute a series of structural plates situated at the corners of the module voids and having recesses therein for receiving the respective longitudinal support members adjacent thereto, protrusions separating the recesses, and a plurality of struts situated between protrusions of adjacent structural plates.

  14. Ion Monitoring

    DOE Patents [OSTI]

    Orr, Christopher Henry (Calderbridge, GB); Luff, Craig Janson (Calderbridge, GB); Dockray, Thomas (Calderbridge, GB); Macarthur, Duncan Whittemore (Los Alamos, NM)

    2003-11-18

    The apparatus and method provide a technique for significantly reducing capacitance effects in detector electrodes arising due to movement of the instrument relative to the item/location being monitored in ion detection based techniques. The capacitance variations are rendered less significant by placing an electrically conducting element between the detector electrodes and the monitored location/item. Improved sensitivity and reduced noise signals arise as a result. The technique also provides apparatus and method suitable for monitoring elongate items which are unsuited to complete enclosure in one go within a chamber. The items are monitored part by part as the pass through the instrument, so increasing the range of items or locations which can be successfully monitored.

  15. A fundamentally new approach to air-cooled heat exchangers.

    SciTech Connect (OSTI)

    Koplow, Jeffrey P.

    2010-01-01

    We describe breakthrough results obtained in a feasibility study of a fundamentally new architecture for air-cooled heat exchangers. A longstanding but largely unrealized opportunity in energy efficiency concerns the performance of air-cooled heat exchangers used in air conditioners, heat pumps, and refrigeration equipment. In the case of residential air conditioners, for example, the typical performance of the air cooled heat exchangers used for condensers and evaporators is at best marginal from the standpoint the of achieving maximum the possible coefficient of performance (COP). If by some means it were possible to reduce the thermal resistance of these heat exchangers to a negligible level, a typical energy savings of order 30% could be immediately realized. It has long been known that a several-fold increase in heat exchanger size, in conjunction with the use of much higher volumetric flow rates, provides a straight-forward path to this goal but is not practical from the standpoint of real world applications. The tension in the market place between the need for energy efficiency and logistical considerations such as equipment size, cost and operating noise has resulted in a compromise that is far from ideal. This is the reason that a typical residential air conditioner exhibits significant sensitivity to reductions in fan speed and/or fouling of the heat exchanger surface. The prevailing wisdom is that little can be done to improve this situation; the 'fan-plus-finned-heat-sink' heat exchanger architecture used throughout the energy sector represents an extremely mature technology for which there is little opportunity for further optimization. But the fact remains that conventional fan-plus-finned-heat-sink technology simply doesn't work that well. Their primary physical limitation to performance (i.e. low thermal resistance) is the boundary layer of motionless air that adheres to and envelops all surfaces of the heat exchanger. Within this boundary layer region, diffusive transport is the dominant mechanism for heat transfer. The resulting thermal bottleneck largely determines the thermal resistance of the heat exchanger. No one has yet devised a practical solution to the boundary layer problem. Another longstanding problem is inevitable fouling of the heat exchanger surface over time by particulate matter and other airborne contaminants. This problem is especially important in residential air conditioner systems where often little or no preventative maintenance is practiced. The heat sink fouling problem also remains unsolved. The third major problem (alluded to earlier) concerns inadequate airflow to heat exchanger resulting from restrictions on fan noise. The air-cooled heat exchanger described here solves all of the above three problems simultaneously. The 'Air Bearing Heat Exchanger' provides a several-fold reduction in boundary layer thickness, intrinsic immunity to heat sink fouling, and drastic reductions in noise. It is also very practical from the standpoint of cost, complexity, ruggedness, etc. Successful development of this technology is also expected to have far reaching impact in the IT sector from the standpointpoint of solving the 'Thermal Brick Wall' problem (which currently limits CPU clocks speeds to {approx}3 GHz), and increasing concern about the the electrical power consumption of our nation's information technology infrastructure.

  16. Lithium ion sources

    E-Print Network [OSTI]

    Roy, Prabir K.

    2014-01-01

    HIFAN 1866 Lithium ion sources by Prabir K. Roy, Wayne G.No. DE-AC02-05CH11231. Lithium ion sources Prabir K. Roya source of ?100 mA lithium ion current for the Neutralized

  17. Method and apparatus for removing ions from soil

    DOE Patents [OSTI]

    Bibler, Jane P. (813 E. Rollingwood Rd., Aiken, SC 29801)

    1993-01-01

    A method and apparatus for selectively removing species of ions from an area of soil. Permeable membranes 14 and 18 impregnated with an ion exchange resin that is specific to one or more species of chemical ions are inserted into ground 12 in close proximity to, and on opposing sides of, a soil area of interest 22. An electric potential is applied across electrodes 26 and 28 to cause the migration of ions out of soil area 22 toward the membranes 14 and 18. Preferably, the resin exchanges ions of sodium or hydrogen for ions of mercury that it captures from soil area 22. Once membranes 14 and 18 become substantially saturated with mercury ions, the potential applied across electrodes 26 and 28 is discontinued and membranes 14 and 18 are preferably removed from soil 12 for storage or recovery of the ions. The membranes are also preferably impregnated with a buffer to inhibit the effect of the hydrolysis of water by current from the electrodes.

  18. Method and apparatus for removing ions from soil

    DOE Patents [OSTI]

    Bibler, J.P.

    1993-03-02

    A method and apparatus are presented for selectively removing species of ions from an area of soil. Permeable membranes 14 and 18 impregnated with an ion exchange resin that is specific to one or more species of chemical ions are inserted into ground 12 in close proximity to, and on opposing sides of, a soil area of interest 22. An electric potential is applied across electrodes 26 and 28 to cause the migration of ions out of soil area 22 toward the membranes 14 and 18. Preferably, the resin exchanges ions of sodium or hydrogen for ions of mercury that it captures from soil area 22. Once membranes 14 and 18 become substantially saturated with mercury ions, the potential applied across electrodes 26 and 28 is discontinued and membranes 14 and 18 are preferably removed from soil 12 for storage or recovery of the ions. The membranes are also preferably impregnated with a buffer to inhibit the effect of the hydrolysis of water by current from the electrodes.

  19. Heat exchanger with ceramic elements

    DOE Patents [OSTI]

    Corey, John A. (North Troy, NY)

    1986-01-01

    An annular heat exchanger assembly includes a plurality of low thermal growth ceramic heat exchange members with inlet and exit flow ports on distinct faces. A mounting member locates each ceramic member in a near-annular array and seals the flow ports on the distinct faces into the separate flow paths of the heat exchanger. The mounting member adjusts for the temperature gradient in the assembly and the different coefficients of thermal expansion of the members of the assembly during all operating temperatures.

  20. Heat exchanger using graphite foam

    DOE Patents [OSTI]

    Campagna, Michael Joseph; Callas, James John

    2012-09-25

    A heat exchanger is disclosed. The heat exchanger may have an inlet configured to receive a first fluid and an outlet configured to discharge the first fluid. The heat exchanger may further have at least one passageway configured to conduct the first fluid from the inlet to the outlet. The at least one passageway may be composed of a graphite foam and a layer of graphite material on the exterior of the graphite foam. The layer of graphite material may form at least a partial barrier between the first fluid and a second fluid external to the at least one passageway.

  1. Entanglement Exchange and Bohmian Mechanics

    E-Print Network [OSTI]

    Nick Huggett; Tiziana Vistarini

    2009-05-25

    This paper analyses the phenomenon of entanglement exchange in Bohm's pilot wave interpretation of quantum mechanics. The interesting feature of the phenomenon is that systems become entangled without causal interaction; hence it is a useful situation for investigating the unique nature of interaction in Bohmian mechanics. The first two sections introduce, respectively, entanglement exchange in the standard interpretation of quantum mechanics, and the basic principles of Bohmian mechanics. The next section shows that the Bohmian interpretation makes the same experimental predictions about entanglement exchange as the standard one. The final section draws some conclusions about interactions and entanglement in Bohmian mechanics.

  2. Modeling and Simulation of Lithium-Ion Batteries from a Systems Engineering Perspective

    E-Print Network [OSTI]

    Braatz, Richard D.

    The lithium-ion battery is an ideal candidate for a wide variety of applications due to its high energy/power density and operating voltage. Some limitations of existing lithium-ion battery technology include underutilization, ...

  3. Computational study of the transport mechanisms of molecules and ions in solid materials 

    E-Print Network [OSTI]

    Zhang, Yingchun

    2009-06-02

    Transport of ions and molecules in solids is a very important process in many technological applications, for example, in drug delivery, separation processes, and in power sources such as ion diffusion in electrodes or in ...

  4. Modeling temperature distribution in cylindrical lithium ion batteries for use in electric vehicle cooling system design

    E-Print Network [OSTI]

    Jasinski, Samuel Anthony

    2008-01-01

    Recent advancements in lithium ion battery technology have made BEV's a more feasible alternative. However, some safety concerns still exist. While the energy density of lithium ion batteries has all but made them the ...

  5. Ion funnel ion trap and process

    DOE Patents [OSTI]

    Belov, Mikhail E [Richland, WA; Ibrahim, Yehia M [Richland, WA; Clowers, Biran H [West Richland, WA; Prior, David C [Hermiston, OR; Smith, Richard D [Richland, WA

    2011-02-15

    An ion funnel trap is described that includes a inlet portion, a trapping portion, and a outlet portion that couples, in normal operation, with an ion funnel. The ion trap operates efficiently at a pressure of .about.1 Torr and provides for: 1) removal of low mass-to-charge (m/z) ion species, 2) ion accumulation efficiency of up to 80%, 3) charge capacity of .about.10,000,000 elementary charges, 4) ion ejection time of 40 to 200 .mu.s, and 5) optimized variable ion accumulation times. Ion accumulation with low concentration peptide mixtures has shown an increase in analyte signal-to-noise ratios (SNR) of a factor of 30, and a greater than 10-fold improvement in SNR for multiply charged analytes.

  6. Nonlocal exchange correlation in screened-exchange densityfunctional methods

    SciTech Connect (OSTI)

    Lee, Byounghak; Wang, Lin-Wang; Spataru, Catalin D.; Louie,Steven G.

    2007-04-22

    We present a systematic study on the exchange-correlationeffects in screened-exchange local density functional method. Toinvestigate the effects of the screened-exchange potential in the bandgap correction, we have compared the exchange-correlation potential termin the sX-LDA formalism with the self-energy term in the GWapproximation. It is found that the band gap correction of the sX-LDAmethod primarily comes from the downshift of valence band states,resulting from the enhancement of bonding and the increase of ionizationenergy. The band gap correction in the GW method, on the contrary, comesin large part from the increase of theconduction band energies. We alsostudied the effects of the screened-exchange potential in the totalenergy by investigating the exchange-correlation hole in comparison withquantum Monte Carlo calculations. When the Thomas-Fermi screening isused, the sX-LDA method overestimates (underestimates) theexchange-correlation hole in short (long) range. From theexchange-correlation energy analysis we found that the LDA method yieldsbetter absolute total energy than sX-LDA method.

  7. Sandia Energy - Heat-Exchanger Development

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Heat-Exchanger Development Home Stationary Power Nuclear Fuel Cycle Advanced Nuclear Energy Nuclear Energy Systems Laboratory (NESL) Brayton Lab Heat-Exchanger Development...

  8. Heat exchange assembly

    DOE Patents [OSTI]

    Lowenstein, Andrew; Sibilia, Marc; Miller, Jeffrey; Tonon, Thomas S.

    2004-06-08

    A heat exchange assembly comprises a plurality of plates disposed in a spaced-apart arrangement, each of the plurality of plates includes a plurality of passages extending internally from a first end to a second end for directing flow of a heat transfer fluid in a first plane, a plurality of first end-piece members equaling the number of plates and a plurality of second end-piece members also equaling the number of plates, each of the first and second end-piece members including a recessed region adapted to fluidly connect and couple with the first and second ends of the plate, respectively, and further adapted to be affixed to respective adjacent first and second end-piece members in a stacked formation, and each of the first and second end-piece members further including at least one cavity for enabling entry of the heat transfer fluid into the plate, exit of the heat transfer fluid from the plate, or 180.degree. turning of the fluid within the plate to create a serpentine-like fluid flow path between points of entry and exit of the fluid, and at least two fluid conduits extending through the stacked plurality of first and second end-piece members for providing first fluid connections between the parallel fluid entry points of adjacent plates and a fluid supply inlet, and second fluid connections between the parallel fluid exit points of adjacent plates and a fluid discharge outlet so that the heat transfer fluid travels in parallel paths through each respective plate.

  9. Hear Exchange Assembly

    DOE Patents [OSTI]

    Lowenstein, Andrew (Princeton, NJ); Sibilia, Marc (Princeton, NJ); Miller, Jeffrey (Rocky Hill, NJ); Tonon, Thomas S. (Princeton, NJ)

    2003-05-27

    A heat exchange assembly comprises a plurality of plates disposed in a spaced-apart arrangement, each of the plurality of plates includes a plurality of passages extending internally from a first end to a second end for directing flow of a heat transfer fluid in a first plane, a plurality of first end-piece members equaling the number of plates and a plurality of second end-piece members also equaling the number of plates, each of the first and second end-piece members including a recessed region adapted to fluidly connect and couple with the first and second ends of the plate, respectively, and further adapted to be affixed to respective adjacent first and second end-piece members in a stacked formation, and each of the first and second end-piece members further including at least one cavity for enabling entry of the heat transfer fluid into the plate, exit of the heat transfer fluid from the plate, or 180.degree. turning of the fluid within the plate to create a serpentine-like fluid flow path between points of entry and exit of the fluid, and at least two fluid conduits extending through the stacked plurality of first and second end-piece members for providing first fluid connections between the parallel fluid entry points of adjacent plates and a fluid supply inlet, and second fluid connections between the parallel fluid exit points of adjacent plates and a fluid discharge outlet so that the heat transfer fluid travels in parallel paths through each respective plate.

  10. Heat pipe array heat exchanger

    DOE Patents [OSTI]

    Reimann, Robert C. (Lafayette, NY)

    1987-08-25

    A heat pipe arrangement for exchanging heat between two different temperature fluids. The heat pipe arrangement is in a ounterflow relationship to increase the efficiency of the coupling of the heat from a heat source to a heat sink.

  11. Mass Exchange Processes with Input

    E-Print Network [OSTI]

    P. L. Krapivsky

    2015-03-07

    We investigate a system of interacting clusters evolving through mass exchange and supplemented by input of small clusters. Three possibilities depending on the rate of exchange generically occur when input is homogeneous: continuous growth, gelation, and instantaneous gelation. We mostly study the growth regime using scaling methods. An exchange process with reaction rates equal to the product of reactant masses admits an exact solution which allows us to justify the validity of scaling approaches in this special case. We also investigate exchange processes with a localized input. We show that if the diffusion coefficients are mass-independent, the cluster mass distribution becomes stationary and develops an algebraic tail far away from the source.

  12. Asset Prices and Exchange Rates

    E-Print Network [OSTI]

    Pavlova, Anna

    2003-08-01

    This paper develops a simple two-country, two-good model, in which the real exchange rate, stock and bond prices are jointly determined. The model predicts that ...

  13. Asset Prices and Exchange Rates

    E-Print Network [OSTI]

    Pavlova, Anna

    2004-11-30

    This paper develops a simple two-country, two-good model, in which the real exchange rate, stock and bond prices are jointly determined. The model predicts that stock market prices are correlated ...

  14. Anion exchange polymer electrolytes

    DOE Patents [OSTI]

    Kim, Yu Seung; Kim, Dae Sik; Lee, Kwan-Soo

    2013-07-23

    Solid anion exchange polymer electrolytes and compositions comprising chemical compounds comprising a polymeric core, a spacer A, and a guanidine base, wherein said chemical compound is uniformly dispersed in a suitable solvent and has the structure: ##STR00001## wherein: i) A is a spacer having the structure O, S, SO.sub.2, --NH--, --N(CH.sub.2).sub.n, wherein n=1-10, --(CH.sub.2).sub.n--CH.sub.3--, wherein n=1-10, SO.sub.2-Ph, CO-Ph, ##STR00002## wherein R.sub.5, R.sub.6, R.sub.7 and R.sub.8 each are independently --H, --NH.sub.2, F, Cl, Br, CN, or a C.sub.1-C.sub.6 alkyl group, or any combination of thereof; ii) R.sub.9, R.sub.10, R.sub.11, R.sub.12, or R.sub.13 each independently are --H, --CH.sub.3, --NH.sub.2, --NO, --CH.sub.nCH.sub.3 where n=1-6, HC.dbd.O--, NH.sub.2C.dbd.O--, --CH.sub.nCOOH where n=1-6, --(CH.sub.2).sub.n--C(NH.sub.2)--COOH where n=1-6, --CH--(COOH)--CH.sub.2--COOH, --CH.sub.2--CH(O--CH.sub.2CH.sub.3).sub.2, --(C.dbd.S)--NH.sub.2, --(C.dbd.NH)--N--(CH.sub.2).sub.nCH.sub.3, where n=0-6, --NH--(C.dbd.S)--SH, --CH.sub.2--(C.dbd.O)--O--C(CH.sub.3).sub.3, --O--(CH.sub.2).sub.n--CH--(NH.sub.2)--COOH, where n=1-6, --(CH.sub.2).sub.n--CH.dbd.CH wherein n=1-6, --(CH.sub.2).sub.n--CH--CN wherein n=1-6, an aromatic group such as a phenyl, benzyl, phenoxy, methylbenzyl, nitrogen-substituted benzyl or phenyl groups, a halide, or halide-substituted methyl groups; and iii) wherein the composition is suitable for use in a membrane electrode assembly.

  15. Multi-block sulfonated poly(phenylene) copolymer proton exchange membranes

    DOE Patents [OSTI]

    Fujimoto, Cy H. (Albuquerque, NM); Hibbs, Michael (Albuquerque, NM); Ambrosini, Andrea (Albuquerque, NM)

    2012-02-07

    Improved multi-block sulfonated poly(phenylene) copolymer compositions, methods of making the same, and their use as proton exchange membranes (PEM) in hydrogen fuel cells, direct methanol fuel cells, in electrode casting solutions and electrodes. The multi-block architecture has defined, controllable hydrophobic and hydrophilic segments. These improved membranes have better ion transport (proton conductivity) and water swelling properties.

  16. Vehicle Technologies Office Merit Review 2015: A Commercially...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Office Merit Review 2015: High Energy, Long Cycle Life Lithium-ion Batteries for EV Applications Silicon Nanostructure-based Technology for Next Generation Energy Storage...

  17. Temporal Development of Ion Beam Mean Charge State in PulsedVacuum Arc Ion Sources

    SciTech Connect (OSTI)

    Oks, Efim M.; Yushkov, Georgy Yu.; Anders, Andre

    2007-06-21

    Vacuum arc ion sources, commonly also known as "Mevva" ionsources, are used to generate intense pulsed metal ion beams. It is knownthat the mean charge state of the ion beam lies between 1 and 4,depending on cathode material, arc current, arc pulse duration, presenceor absence of magnetic field at the cathode, as well background gaspressure. A characteristic of the vacuum arc ion beam is a significantdecrease in ion charge state throughout the pulse. This decrease can beobserved up to a few milliseconds, until a "noisy" steady-state value isestablished. Since the extraction voltage is constant, a decrease in theion charge state has a proportional impact on the average ion beamenergy. This paper presents results of detailed investigations of theinfluence of arc parameters on the temporal development of the ion beammean charge state for a wide range of cathode materials. It is shown thatfor fixed pulse duration, the charge state decrease can be reduced bylower arc current, higher pulse repetition rate, and reduction of thedistance between cathode and extraction region. The latter effect may beassociated with charge exchange processes in the dischargeplasma.

  18. Secondary Heat Exchanger Design and Comparison for Advanced High Temperature Reactor

    SciTech Connect (OSTI)

    Piyush Sabharwall; Ali Siahpush; Michael McKellar; Michael Patterson; Eung Soo Kim

    2012-06-01

    The goals of next generation nuclear reactors, such as the high temperature gas-cooled reactor and advance high temperature reactor (AHTR), are to increase energy efficiency in the production of electricity and provide high temperature heat for industrial processes. The efficient transfer of energy for industrial applications depends on the ability to incorporate effective heat exchangers between the nuclear heat transport system and the industrial process heat transport system. The need for efficiency, compactness, and safety challenge the boundaries of existing heat exchanger technology, giving rise to the following study. Various studies have been performed in attempts to update the secondary heat exchanger that is downstream of the primary heat exchanger, mostly because its performance is strongly tied to the ability to employ more efficient conversion cycles, such as the Rankine super critical and subcritical cycles. This study considers two different types of heat exchangers—helical coiled heat exchanger and printed circuit heat exchanger—as possible options for the AHTR secondary heat exchangers with the following three different options: (1) A single heat exchanger transfers all the heat (3,400 MW(t)) from the intermediate heat transfer loop to the power conversion system or process plants; (2) Two heat exchangers share heat to transfer total heat of 3,400 MW(t) from the intermediate heat transfer loop to the power conversion system or process plants, each exchanger transfers 1,700 MW(t) with a parallel configuration; and (3) Three heat exchangers share heat to transfer total heat of 3,400 MW(t) from the intermediate heat transfer loop to the power conversion system or process plants. Each heat exchanger transfers 1,130 MW(t) with a parallel configuration. A preliminary cost comparison will be provided for all different cases along with challenges and recommendations.

  19. Engineering vertically aligned InAs/GaAs quantum dot structures via anion exchange

    E-Print Network [OSTI]

    Wang, Zhong L.

    of Technology, Atlanta, GA 30332-0245, USA b School of Electrical and Computer Engineering, Georgia Institute of Technology, Atlanta, GA 30332, USA Received 17 March 2002; accepted 16 April 2002 by D. Van Dyck Abstract P exchange; D. Stranski­Krastanov (S­K) growth Self-assemble by exploiting the Stranski­Krastanov (S

  20. Microfabricated ion frequency standard

    DOE Patents [OSTI]

    Schwindt, Peter (Albuquerque, NM); Biedermann, Grant (Albuquerque, NM); Blain, Matthew G. (Albuquerque, NM); Stick, Daniel L. (Albuquerque, NM); Serkland, Darwin K. (Albuquerque, NM); Olsson, III, Roy H. (Albuquerque, NM)

    2010-12-28

    A microfabricated ion frequency standard (i.e. an ion clock) is disclosed with a permanently-sealed vacuum package containing a source of ytterbium (Yb) ions and an octupole ion trap. The source of Yb ions is a micro-hotplate which generates Yb atoms which are then ionized by a ultraviolet light-emitting diode or a field-emission electron source. The octupole ion trap, which confines the Yb ions, is formed from suspended electrodes on a number of stacked-up substrates. A microwave source excites a ground-state transition frequency of the Yb ions, with a frequency-doubled vertical-external-cavity laser (VECSEL) then exciting the Yb ions up to an excited state to produce fluorescent light which is used to tune the microwave source to the ground-state transition frequency, with the microwave source providing a precise frequency output for the ion clock.

  1. United States-Russia exchange visits

    SciTech Connect (OSTI)

    Desmond, W.J.; Czajkowski, A.F. [USDOE, Washington, DC (United States). Office of Nonproliferation and National Security; Zack, N.R. [Los Alamos National Lab., NM (United States); Martin, H.R. [USDOE New Brunswick Lab., Argonne, IL (United States); Gardner, B. [Sandia National Labs., Albuquerque, NM (United States); Schlegel, S. [Pacific Northwest Lab., Richland, WA (United States); Von Hippel, F. [US Office of Science and Technology Policy, Washington, DC (United States)

    1995-09-01

    The Department of Energy, under a government-to-government program, hosted the first visit with the Russian Federation to exchange information and technologies for special nuclear material control, accounting, and physical protection at a plutonium storage facility. The Russian specialists toured a storage facility at the Hanford Site near Richland, Washington, and were shown the physical protection and materials control systems that DOE employs to protect excess nuclear materials. Technical discussions included topics associated with protective forces and their operation, perimeter and interior intrusion detection and assessment equipment/systems, vulnerability assessment demonstrations, and the vault monitoring and materials control systems. In October, the Russian Federation hosted a reciprocal visit to the Mayak Enterprise civil plutonium storage facility, previously known as Chelyabinsk-65. The US specialists participated in technical discussions on the protection and control of plutonium and supported an evaluation of safeguards and security at the Mayak storage facility.

  2. New Oxygen-Production Technology Proving Successful

    Broader source: Energy.gov [DOE]

    The Office of Fossil Energy's National Energy Technology Laboratory has partnered with Air Products and Chemicals Inc. of Allentown, Penn. to develop the Ion Transport Membrane (ITM) Oxygen, a revolutionary new oxygen-production technology that requires less energy and offers lower capital costs than conventional technologies.

  3. Development of models for exchange of electronic documents

    SciTech Connect (OSTI)

    Glavev, Victor

    2014-11-18

    The report presents a model for exchange of electronic documents between different government administrations. It defines electronic messages that are transmitted between them and the way that messages should be processed by software systems. The proposed approach is sufficiently general and allows use of the best applicable information technologies such as data presentation structures and communication protocols. Within the study, a simple implementation of the model is implemented and deployed in various government administrations in Republic of Bulgaria.

  4. The Phoenician Trade Network: Tracing a Mediterranean Exchange System 

    E-Print Network [OSTI]

    Puckett, Neil 1983-

    2012-11-15

    evidence exists that Phoenicians used warships such as the Pentecontor for colonization, this chapter concentrates on the merchant ship as the primary vessel for exchange.44 Lastly, the chapter addresses navigation, both with regard to technologies... that the 43 For instance, a 200-ton ships has been purported as part of the Ugarit fleet (Aubet 1994, 172- 5). 44 CPG, 5-10 1 8 Phoenicians had the potential to develop in order to successfully navigate during their voyages are discussed...

  5. Selective compositional mixing in GaAs/AIGaAs superlattice induced by low dose Si focused ion beam implantation

    E-Print Network [OSTI]

    Cincinnati, University of

    of the mixing process was observed at 100 keV implantation energy, with a "pinch-off" (more heavily mixed ion beam (FIB) implantation technology has been especially attractive in this application, since/or transfer technology, the lateral profiles of the ion beam (and of the ions implanted in the solid

  6. Maskless, resistless ion beam lithography

    SciTech Connect (OSTI)

    Ji, Qing

    2003-03-10

    As the dimensions of semiconductor devices are scaled down, in order to achieve higher levels of integration, optical lithography will no longer be sufficient for the needs of the semiconductor industry. Alternative next-generation lithography (NGL) approaches, such as extreme ultra-violet (EUV), X-ray, electron-beam, and ion projection lithography face some challenging issues with complicated mask technology and low throughput. Among the four major alternative NGL approaches, ion beam lithography is the only one that can provide both maskless and resistless patterning. As such, it can potentially make nano-fabrication much simpler. This thesis investigates a focused ion beam system for maskless, resistless patterning that can be made practical for high-volume production. In order to achieve maskless, resistless patterning, the ion source must be able to produce a variety of ion species. The compact FIB system being developed uses a multicusp plasma ion source, which can generate ion beams of various elements, such as O{sub 2}{sup +}, BF{sub 2}{sup +}, P{sup +} etc., for surface modification and doping applications. With optimized source condition, around 85% of BF{sub 2}{sup +}, over 90% of O{sub 2}{sup +} and P{sup +} have been achieved. The brightness of the multicusp-plasma ion source is a key issue for its application to maskless ion beam lithography. It can be substantially improved by optimizing the source configuration and extractor geometry. Measured brightness of 2 keV He{sup +} beam is as high as 440 A/cm{sup 2} {center_dot} Sr, which represents a 30x improvement over prior work. Direct patterning of Si thin film using a focused O{sub 2}{sup +} ion beam has been investigated. A thin surface oxide film can be selectively formed using 3 keV O{sub 2}{sup +} ions with the dose of 10{sup 15} cm{sup -2}. The oxide can then serve as a hard mask for patterning of the Si film. The process flow and the experimental results for directly patterned poly-Si features are presented. The formation of shallow pn-junctions in bulk silicon wafers by scanning focused P{sup +} beam implantation at 5 keV is also presented. With implantation dose of around 10{sup 16} cm{sup -2}, the electron concentration is about 2.5 x 10{sup 18} cm{sup -3} and electron mobility is around 200 cm{sup 2}/V{center_dot}s. To demonstrate the suitability of scanning FIB lithography for the manufacture of integrated circuit devices, SOI MOSFET fabrication using the maskless, resistless ion beam lithography is demonstrated. An array of microcolumns can be built by stacking multi-aperture electrode and insulator layers. Because the multicusp plasma source can achieve uniform ion density over a large area, it can be used in conjunction with the array of microcolumns, for massively parallel FIB processing to achieve reasonable exposure throughput.

  7. Savannah River Technology Center. Monthly report

    SciTech Connect (OSTI)

    Not Available

    1994-02-01

    This document contains information about the research programs being conducted at the Savannah River Plant. Topics of discussion include: thermal cycling absorption process, development of new alloys, ion exchange, oxalate precipitation, calcination, environmental research, remedial action, ecological risk assessments, chemical analysis of salt cakes, natural phenomena hazards assessment, and sampling of soils and groundwater.

  8. A Better Anode Design to Improve Lithium-Ion Batteries

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    are, the need for energy storage in batteries is surpassing current technologies. In a lithium-ion battery, charge moves from the cathode to the anode, a critical component for...

  9. A Better Anode Design to Improve Lithium-Ion Batteries

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    need for energy storage in batteries is surpassing current technologies. In a lithium-ion battery, charge moves from the cathode to the anode, a critical component for storing...

  10. Analytic model of the ion angular distribution in a collisional sheath

    SciTech Connect (OSTI)

    Vahedi, V.; Stewart, R.A.; Lieberman, M.A. (Department of Electrical Engineering and Computer Science and the Electronics Research Laboratory, University of California, Berkeley, Berkeley, California 94720 (United States))

    1993-07-01

    An analytic model is developed for the ion angular distribution in a collisional sheath. In a previous study, the one-dimensional (normal to the sheath) ion velocity distribution was obtained under the assumption that charge exchange is the dominant ion-neutral collision mechanism. In the present model, we assume [lambda][sub scat][ge][lambda][sub cx], where [lambda][sub scat] and [lambda][sub cx] are the mean free paths for ion-neutral elastic scattering and charge-exchange collisions, respectively. With this assumption, the angular distribution mainly arises from ions that strike the electrode after undergoing only one scattering collision following the last charge-exchange collision. Comparison of the analytic model with results obtained from a particle-in-cell simulation gives excellent agreement. Both the average angle of ions striking the electrode and the ratio of parallel to perpendicular ion flux at the electrode are shown to scale with the ratio of scattering to charge-exchange cross sections [sigma][sub scat]/[sigma][sub cx].

  11. Building Efficiency Technologies by Tomorrow’s Engineers and Researchers (BETTER) Capstone

    Office of Energy Efficiency and Renewable Energy (EERE)

    Lead Performer: Georgia Institute of Technology – Atlanta, GAPartners:  -   Alphabet Energy – Hayward, CA  -   Alabama Heat Exchangers, AL  -   Advanced Renewable Energy  -   Emrgy Hydro – Atlanta,...

  12. Buildings-to-Grid Technical Opportunities: From the Information and Communications Technology Perspective

    SciTech Connect (OSTI)

    Kuruganti, Teja; Brabmley, Michael

    2014-03-28

    Information and communications technology (ICT) has enabled the integration of computer and audio-visual networks, leading to unprecedented exchange of data between various users and entities.

  13. Faience Technology

    E-Print Network [OSTI]

    Nicholson, Paul

    2009-01-01

    by Joanne Hodges. Faience Technology, Nicholson, UEE 2009Egyptian materials and technology, ed. Paul T. Nicholson,Nicholson, 2009, Faience Technology. UEE. Full Citation:

  14. Test results of a Stirling engine utilizing heat exchanger modules with an integral heat pipe

    SciTech Connect (OSTI)

    Skupinski, R.C.; Tower, L.K.; Madi, F.J.; Brusk, K.D.

    1993-04-01

    The Heat Pipe Stirling Engine (HP-1000), a free-piston Stirling engine incorporating three heat exchanger modules, each having a sodium filled heat pipe, has been tested at the NASA-Lewis Research Center as part of the Civil Space Technology Initiative (CSTI). The heat exchanger modules were designed to reduce the number of potential flow leak paths in the heat exchanger assembly and incorporate a heat pipe as the link between the heat source and the engine. An existing RE-1000 free-piston Stirling engine was modified to operate using the heat exchanger modules. This paper describes heat exchanger module and engine performance during baseline testing. Condenser temperature profiles, brake power, and efficiency are presented and discussed.

  15. DVZ_Remediation_Technology_Tables_Info_Exchange.xlsx

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration would like submit theCovalent Bonding Low-Cost2 DOE HQSiteo n n eDPFJ.D.DRIVINGServices

  16. IEA Energy Technology Data Exchange | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QAsource History View NewTexas: Energy Resources JumpNewTexas:Hydrothermally DepositedInformation 6|

  17. Microsoft Word - DVZ Technologies Public Information Exchange Summary.doc

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantityBonneville Power Administration wouldMass map shines light on77 PAGE OF PAGESpersonal March 3,ORP-2003-14, Rev.June 22, 2010

  18. Technology Performance Exchange - 2013 BTO Peer Review | Department of

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankADVANCEDInstallers/ContractorsPhotovoltaics »Tankless WaterEnergyJanuary28-982 DOE

  19. NREL: DOE Technology Performance Exchange - 2015 Peer Review | Department

    Broader source: Energy.gov (indexed) [DOE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity of Natural GasAdjustmentsShirley Ann JacksonDepartment ofOffice| DepartmentGJPPGPracticesDraft.doc|2002 |of Energy Daniel

  20. New PerfSONAR Updates Showcased at 2015 Technology Exchange

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Homesum_a_epg0_fpd_mmcf_m.xls" ,"Available from WebQuantity ofkandz-cm11 Outreach Home Room NewsInformationJessework usesofPublications64 2.251 2.211 2.196Energy National LabsNew

  1. Understanding Nucleic AcidIon Interactions

    E-Print Network [OSTI]

    Herschlag, Dan

    of Technology, 2628 CJ Delft, Netherlands; email: Jan.Lipfert@lmu.de 2 Department of Physics and Center for Nano Keywords ions, RNA/DNA, electrostatics, Poisson­Boltzmann, Manning condensation, Hill equation, free energy;Contents INTRODUCTION. . . . . . . . . . . . . . . . . 814 THE BASICS

  2. UCI Equipment Management Peter's Exchange

    E-Print Network [OSTI]

    Wood, Marcelo A.

    the Asset Retirement Global document available in KFS under KFS Capital Asset Management (as the EIMR formUCI Equipment Management Peter's Exchange (UCI Surplus Sales) SURPLUS PICK-UP REQUEST Department) Phone: (949) 824-6111, 6447, 6519, 6100 Fax this form to (949) 824-4115, or e-mail Equipment-Management

  3. Primer on nuclear exchange models

    SciTech Connect (OSTI)

    Hafemeister, David [Physics Department, Cal Poly University, San Luis Obispo, California (United States)

    2014-05-09

    Basic physics is applied to nuclear force exchange models between two nations. Ultimately, this scenario approach can be used to try and answer the age old question of 'how much is enough?' This work is based on Chapter 2 of Physics of Societal Issues: Calculations on National Security, Environment and Energy (Springer, 2007 and 2014)

  4. BRAZIL, Belo Horizonte Exchange Program

    E-Print Network [OSTI]

    Fernandez, Eduardo

    BRAZIL, Belo Horizonte Exchange Program Universidade Federal de Minas Gerais (UFMG) Brazil, one and Carnival. Belo Horizonte is the 1st planned city in Brazil and is the capital of Minas Gerais. It has transportation, and spending money. These fees are paid in Brazil and are estimated at R$1,800 Real per month

  5. Superconducting microfabricated ion traps

    E-Print Network [OSTI]

    Wang, Shannon Xuanyue

    We fabricate superconducting ion traps with niobium and niobium nitride and trap single [superscript 88]Sr ions at cryogenic temperatures. The superconducting transition is verified and characterized by measuring the ...

  6. Applications of decelerated ions

    SciTech Connect (OSTI)

    Johnson, B.M.

    1985-03-01

    Many facilities whose sole purpose had been to accelerate ion beams are now becoming decelerators as well. The development and current status of accel-decel operations is reviewed here. Applications of decelerated ions in atomic physics experiments are discussed.

  7. Electron-less negative ion extraction from ion-ion plasmas (Journal...

    Office of Scientific and Technical Information (OSTI)

    results showing that continuous negative ion extraction, without co-extracted electrons, is possible from highly electronegative SFsub 6 ion-ion plasma at low gas...

  8. Single Ion Implantation

    ScienceCinema (OSTI)

    Thomas Schenkel

    2010-01-08

    On the equipment needed to implant ions in silicon and other materials. More information: http://newscenter.lbl.gov/f...

  9. Negative ion generator

    DOE Patents [OSTI]

    Stinnett, R.W.

    1984-05-08

    A negative ion generator is formed from a magnetically insulated transmission line having a coating of graphite on the cathode for producing negative ions and a plurality of apertures on the opposed anode for the release of negative ions. Magnetic insulation keeps electrons from flowing from the cathode to the anode. A transverse magnetic field removes electrons which do escape through the apertures from the trajectory of the negative ions. 8 figs.

  10. Diagnostic Characterization of High-Power Lithium-Ion Batteries For Use in Hybrid Electric Vehicles

    E-Print Network [OSTI]

    Diagnostic Characterization of High-Power Lithium-Ion Batteries For Use in Hybrid Electric Vehicles Lithium-ion batteries are a fast-growing technology that is attractive for use in portable electronics of lithium-ion batteries for hybrid electric vehicle (HEV) applications. The ATD Program is a joint effort

  11. Toward Real-Time Simulation of Physics Based Lithium-Ion Battery Models

    E-Print Network [OSTI]

    Subramanian, Venkat

    Toward Real-Time Simulation of Physics Based Lithium-Ion Battery Models Venkat R. Subramanian Technological University, Cookeville, Tennessee 38505, USA Recent interest in lithium-ion batteries for electric on the computational efficiency of lithium-ion battery models. This paper presents an effective approach to simulate

  12. Stochastic Simulation Model for the 3D Morphology of Composite Materials in Li-Ion Batteries

    E-Print Network [OSTI]

    Schmidt, Volker

    Stochastic Simulation Model for the 3D Morphology of Composite Materials in Li-Ion Batteries Ralf August 30, 2010 Abstract Battery technology plays an important role in energy storage. In particular, lithium­ ion (Li-ion) batteries are of great interest, because of their high capacity, long cycle life

  13. Adsorption and Diffusion of Lithium on Layered Silicon for Li-Ion Georgios A. Tritsaris,,

    E-Print Network [OSTI]

    -dimensional silicon in the form of silicene layers for Li-ion storage. KEYWORDS: Lithium-ion battery, energy storage batteries constitute a promising energy storage technology suitable for portable and grid applicationsAdsorption and Diffusion of Lithium on Layered Silicon for Li-Ion Storage Georgios A. Tritsaris

  14. Silicon nanopillar anodes for lithium-ion batteries using nanoimprint lithography with flexible molds

    E-Print Network [OSTI]

    Arnold, Craig B.

    ) The lithium ion battery, a preferred energy storage technology, is limited by its volumetric and gravimetric. INTRODUCTION The lithium ion battery has become the energy storage me- dium of choice for almost allSilicon nanopillar anodes for lithium-ion batteries using nanoimprint lithography with flexible

  15. Lithium ion sources

    E-Print Network [OSTI]

    Roy, Prabir K.

    2014-01-01

    HIFAN 1866 Lithium ion sources by Prabir K. Roy, Wayne G.No. DE-AC02-05CH11231. Lithium ion sources Prabir K. RoyUSA Abstract A 10.9 cm diameter lithium alumino-silicate ion

  16. Integrated Approach to Revamping Heat Exchangers Networks 

    E-Print Network [OSTI]

    Glass, K. E.; Dhole, V.; Wang, Y.

    2002-01-01

    A heat exchanger network constitutes the core of the plant energy systems interlinking the core process operation and the utility systems. This paper will illustrate an integrated approach for the revamp of a heat exchanger network by bringing...

  17. Second Law Optimization of Heat Exchangers 

    E-Print Network [OSTI]

    Witte, L. C.

    1985-01-01

    A new method for optimizing heat exchangers is developed in this paper. It is based on second law efficiency relationships rather than on the traditional heat exchanger effectiveness concept. The cost of energy is based on its availability level...

  18. Thermodynamic Efficiency of Heat Exchange Devices 

    E-Print Network [OSTI]

    Witte, L. C.; Shamsundar, N.

    1982-01-01

    inlet temperatures, the efficiency and effectiveness for particular heat exchange configurations are related. Conclusions regarding the effect of stream temperatures on the efficiency of various types of exchangers are made. The concept is applied...

  19. Ab initio investigation of the exchange interactions in Bi$_2$Fe$_4$O$_9$: The Cairo pentagonal lattice compound

    E-Print Network [OSTI]

    Z. V. Pchelkina; S. V. Streltsov

    2013-08-05

    We present the \\emph{ab initio} calculation of the electronic structure and magnetic properties of Bi$_2$Fe$_4$O$_9$. This compound crystallizes in the orthorhombic crystal structure with the Fe$^{3+}$ ions forming the Cairo pentagonal lattice implying strong geometric frustration. The neutron diffraction measurements reveal nearly orthogonal magnetic configuration, which at first sight is rather unexpected since it does not minimize the total energy of the pair of magnetic ions coupled by the Heisenberg exchange interaction. Here we calculate the electronic structure and exchange integrals of Bi2Fe4O9 within the LSDA+U method. We obtain three different in-plane (J3=36 K, J4=73 K, J5=23 K) and two interplane (J1=10 K, J2=12 K) exchange parameters. The derived set of exchange integrals shows that the realistic description of Bi2Fe4O9 needs a more complicated model than the ideal Cairo pentagonal lattice with only two exchange parameters in the plane. However, if one takes into account only two largest exchange integrals, then according to the ratio x\\equiv J3/J4=0.49<\\sqrt{2} (a critical parameter for the ideal Cairo pentagonal lattice, see. Ref.~1) the ground state should be the orthogonal magnetic configuration in agreement with experiment. The microscopic origin of different exchange interactions is also discussed.

  20. Distance-dependent plasma composition and ion energy in high power impulse magnetron sputtering

    SciTech Connect (OSTI)

    Ehiasarian, Arutiun P; Andersson, Joakim; Anders, André

    2010-04-18

    The plasma composition of high power impulse magnetron sputtering (HIPIMS) has been studied for titanium and chromium targets using a combined energy analyser and quadrupole mass spectrometer. Measurements were done at distances from 50 to 300 mm from the sputtering target. Ti and Cr are similar in atomic mass but have significantly different sputter yields, which gives interesting clues on the effect of the target on plasma generation and transport of atoms. The Ti and Cr HIPIMS plasmas operated at a peak target current density of ~;;0.5 A cm-2. The measurements of the argon and metal ion content as well as the ion energy distribution functions showed that (1) singly and doubly charged ions were found for argon as well as for the target metal, (2) the majority of ions were singly charged argon for both metals at all distances investigated, (3) the Cr ion density was maintained to distances further from the target than Ti. Gas rarefaction was identified as a main factor promoting transport of metal ions, with the stronger effect observed for Cr, the material with higher sputter yield. Cr ions were found to displace a significant portion of the gas ions, whereas this was less evident in the Ti case. The observations indicate that the presence of metal vapour promotes charge exchange and reduces the electron temperature and thereby practically prevents the production of Ar2+ ions near the target. The content of higher charge states of metal ions depends on the probability of charge exchange with argon.

  1. Superconducting microfabricated ion traps

    E-Print Network [OSTI]

    Shannon X. Wang; Yufei Ge; Jaroslaw Labaziewicz; Eric Dauler; Karl Berggren; Isaac L. Chuang

    2010-12-14

    We fabricate superconducting ion traps with niobium and niobium nitride and trap single 88Sr ions at cryogenic temperatures. The superconducting transition is verified and characterized by measuring the resistance and critical current using a 4-wire measurement on the trap structure, and observing change in the rf reflection. The lowest observed heating rate is 2.1(3) quanta/sec at 800 kHz at 6 K and shows no significant change across the superconducting transition, suggesting that anomalous heating is primarily caused by noise sources on the surface. This demonstration of superconducting ion traps opens up possibilities for integrating trapped ions and molecular ions with superconducting devices.

  2. Hadronic physics in peripheral heavy ion collisions

    E-Print Network [OSTI]

    A. A. Natale

    2002-01-22

    We discuss the production of hadronic resonances in very peripheral heavy ion collisions, where the ions collide with impact parameter larger than twice the nuclear radius and remain intact after the collision. We compare the resonance production through two-photon and double Pomeron exchange, showing that when we impose the condition for a peripheral interaction the $\\gamma \\gamma$ process dominates over the Pomeron interaction, due to the short range propagation of this last one. We also discuss the observation of light resonances through the subprocess $\\gamma \\gamma \\to R \\to \\gamma \\gamma $, which is a clean signal for glueball candidates as well as one way to check the existence of a possible scalar $\\sigma$ meson.

  3. Nuclear Reactors and Technology

    SciTech Connect (OSTI)

    Cason, D.L.; Hicks, S.C. [eds.

    1992-01-01

    This publication Nuclear Reactors and Technology (NRT) announces on a monthly basis the current worldwide information available from the open literature on nuclear reactors and technology, including all aspects of power reactors, components and accessories, fuel elements, control systems, and materials. This publication contains the abstracts of DOE reports, journal articles, conference papers, patents, theses, and monographs added to the Energy Science and Technology Database during the past month. Also included are US information obtained through acquisition programs or interagency agreements and international information obtained through the International Energy Agency`s Energy Technology Data Exchange or government-to-government agreements. The digests in NRT and other citations to information on nuclear reactors back to 1948 are available for online searching and retrieval on the Energy Science and Technology Database and Nuclear Science Abstracts (NSA) database. Current information, added daily to the Energy Science and Technology Database, is available to DOE and its contractors through the DOE Integrated Technical Information System. Customized profiles can be developed to provide current information to meet each user`s needs.

  4. Helically coiled tube heat exchanger

    SciTech Connect (OSTI)

    Harris, A.M.

    1981-08-18

    In a heat exchanger such as a steam generator for a nuclear reactor, two or more bundles of helically coiled tubes are arranged in series with the tubes in each bundle integrally continuing through the tube bundles arranged in series therewith. Pitch values for the tubing in any pair of tube bundles, taken transverse to the path of the reactor coolant flow about the tubes, are selected as a ratio of two unequal integers to permit efficient operation of each tube bundle while maintaining the various tube bundles of the heat exchanger within a compact envelope. Preferably, the helix angle and tube pitch parallel to the path of coolant flow are constant for all tubes in a single bundle so that the tubes are of approximately the same length within each bundle.

  5. Heat exchanger and related methods

    DOE Patents [OSTI]

    Turner, Terry D.; McKellar, Michael G.

    2015-12-22

    Heat exchangers include a housing having an inlet and an outlet and forming a portion of a transition chamber. A heating member may form another portion of the transition chamber. The heating member includes a first end having a first opening and a second end having a second opening larger than the first opening. Methods of conveying a fluid include supplying a first fluid into a transition chamber of a heat exchanger, supplying a second fluid into the transition chamber, and altering a state of a portion of the first fluid with the second fluid. Methods of sublimating solid particles include conveying a first fluid comprising a material in a solid state into a transition chamber, heating the material to a gaseous state by directing a second fluid through a heating member and mixing the first fluid and the second fluid.

  6. Energy spectrum of argon ions emitted from Filippov type Sahand plasma focus

    SciTech Connect (OSTI)

    Mohammadnejad, M.; Pestehe, S. J.; Mohammadi, M. A.; Research Institute for Applied Physics and Astronomy, University of Tabriz, Tabriz

    2013-07-15

    The energy and flux of the argon ions produced in Sahand plasma focus have been measured by employing a well-designed Faraday cup. The secondary electron emission effects on the ion signals are simulated and the dimensions of Faraday cup are optimized to minimize these effects. The measured ion energy spectrum is corrected for the ion energy loss and charge exchange in the background gas. The effects of the capacitor bank voltage and working gas pressure on the ion energy spectrum are also investigated. It has been shown that the emitted ion number per energy increases as the capacitor bank voltage increases. Decreasing the working gas pressure leads to the increase in the number of emitted ion per energy.

  7. EXCHANGE FUNCTIONS Exchange Functions is a speci cation mechanism for designing and a model for

    E-Print Network [OSTI]

    Filman, Robert E.

    to monitor and control a manufacturing process is an embedded system. 74 #12;exchange functions 75 exampleCHAPTER SEVEN EXCHANGE FUNCTIONS Exchange Functions is a speci cation mechanism for designing and a model for describing distributed and embedded systems.* Exchange Functions assumes ex- plicit processes

  8. Optimised multi-ion cavity coupling

    E-Print Network [OSTI]

    Stephen Begley; Markus Vogt; Gurpreet Kaur Gulati; Hiroki Takahashi; Matthias Keller

    2015-12-31

    Recent technological advances in cavity quantum electrodynamics (CQED) are paving the way to utilise multiple quantum emitters confined in a single optical cavity. In such systems it is crucially important to control the quantum mechanical coupling of individual emitters to the cavity mode. In this regard, combining ion trap technologies with CQED provides a particularly promising approach due to the well-established motional control over trapped ions. Here we experimentally demonstrate coupling of up to five trapped ions in a string to a high-finesse optical cavity. By changing the axial position and spacing of the ions in a fully deterministic manner, we systematically characterise their coupling to the cavity mode through visibility measurements of the cavity emission. In good agreement with the theoretical model, the results demonstrate that the geometrical configuration of multiple trapped ions can be manipulated to obtain optimal cavity coupling. Our system presents a new ground to explore CQED with multiple quantum emitters, enabled by the highly controllable collective light-matter interaction.

  9. Microfabricated ion trap array

    DOE Patents [OSTI]

    Blain, Matthew G. (Albuquerque, NM); Fleming, James G. (Albuquerque, NM)

    2006-12-26

    A microfabricated ion trap array, comprising a plurality of ion traps having an inner radius of order one micron, can be fabricated using surface micromachining techniques and materials known to the integrated circuits manufacturing and microelectromechanical systems industries. Micromachining methods enable batch fabrication, reduced manufacturing costs, dimensional and positional precision, and monolithic integration of massive arrays of ion traps with microscale ion generation and detection devices. Massive arraying enables the microscale ion traps to retain the resolution, sensitivity, and mass range advantages necessary for high chemical selectivity. The reduced electrode voltage enables integration of the microfabricated ion trap array with on-chip circuit-based rf operation and detection electronics (i.e., cell phone electronics). Therefore, the full performance advantages of the microfabricated ion trap array can be realized in truly field portable, handheld microanalysis systems.

  10. Polymer filtration: An emerging technology for selective metals recovery

    SciTech Connect (OSTI)

    Smith, B.F.; Robison, T.W.; Cournoyer, M.E.

    1995-12-31

    A new technology is under development to selectively recover regulated metal ions from electroplating rinse waters. The electroplating metal ions are recovered in a concentrated form with the appropriate counter ions ready for return to the original electroplating bath. The technology is based on the use of specially designed water-soluble polymers that selectively bind with the metal ions in the rinse bath. The polymers have such a large molecular weight that they can be physically separated using available ultrafiltration technology. The advantages of this technology are high metal selectivity with no sludge formation, rapid processing, low energy, low capital costs, and small size. We have tested and demonstrated the recovery of zinc and nickel (a new alloy electroplating bath designed to replace cadmium) from rinse waters. The metal-ion concentrate was returned to the original electroplating bath. Applications of this technology include waste treatment for textile, paint and dye production, chemical manufacturing, and nuclear reactor and reprocessing operations.

  11. Renaissance in Flow-Cell Technologies Recent Advancements and Future Opportunities

    E-Print Network [OSTI]

    Electrodes Thick = High Energy Thin = High Power 4 #12;uper or s y UTC Proprietary Flow Batteries cells Flow Battery SystemFlow Battery System Electrolyte flow Ion exchange membrane Cell stack (power System Architectures Proton Exchange Membrane Flow Batteries: Energy stored in solutions

  12. Heat Exchangers for Solar Water Heating Systems | Department...

    Energy Savers [EERE]

    Heat Exchangers for Solar Water Heating Systems Heat Exchangers for Solar Water Heating Systems Image of a heat exchanger. | Photo from iStockphoto.com Image of a heat exchanger. |...

  13. Better Buildings Workforce Peer Exchange Quality Assurance Strategies...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Quality Assurance Strategies Better Buildings Workforce Peer Exchange Quality Assurance Strategies Better Buildings Workforce Peer Exchange Quality Assurance Strategies, call...

  14. Measurement of spin diffusion length in sputtered Ni films using a special exchange-biased spin valve geometry

    E-Print Network [OSTI]

    Birge, Norman

    valve geometry Charles E. Moreaua Department of Physics, Albion College, Albion, Michigan 49224 Ion C exchange-biased spin valve geometry that inserts a Ni "spoiler" layer into a Py/Cu/Py spin valve. Fits In the context of ferromagnetic/nonmagnetic F/N multilayers or spin valves, the size of the giant

  15. Approach to the surface characteristics of the H and H -LaT forms of cation-exchange resins by measurement of the heat of immersion

    SciTech Connect (OSTI)

    Suzuki, T.; Uematsu, T.

    1985-11-07

    Surface characteristics of H and its multivalent cation-exchanged resins, which have been used as catalysts, were probed by measurement of the heats of immersion in 1-nitropropane, n-hexane, and water. It was found that the electrostatic field strengths (F) calculated from the heats of immersion in 1-nitropropane and n-hexane increased with increasing ratios of the exchanged multivalent cation (LaT ) in the univalent form (H ) cation-exchange resin. This tendency was also observed in the differences in F between the LaT exchanged resins and H form of the resin by using the calorimetric data obtained from the heats of immersion in water. These results suggest that the exchanged LaT ion does not homogeneously interact with three univalent anionic sites (SO3 ) of the cation-exchange resin, but interacts with only two SO3 ions, that is, the LaT ion is localized on the surface of the resin. The difference in F obtained from the heats of immersion into water was found to be useful as a simple and rapid criterion of the surface characteristics of the cation-exchange resins. 18 references, 4 figures, 1 table.

  16. Microelectromechanical system assembled ion optics: An advance to miniaturization and assembly of electron and ion optics

    SciTech Connect (OSTI)

    Fox, J.; Verbeck, G. [University of North Texas, Denton, Texas 76203 (United States); Saini, R.; Tsui, K. [Zyvex, Richardson, Texas 75081 (United States)

    2009-09-15

    Deep-reactive ion etching of n-doped silicon-on-insulator is utilized to make ion optical components to aid in the miniaturization of mass analyzers. The microelectromechanical system components are bound to aluminum nitride substrates and employed three-dimensional assembly. The assembly methods are tested for breakdown (V{sub b}), durability, and alignment. Demonstration of ion manipulation is shown with a 1 mm Bradbury-Nielsen gate, 500 {mu}m Einzel lens, 500 {mu}m coaxial ring ion trap, and reflectron optics. Data are presented showing the resolution, attenuation, and performance of each of these devices. We demonstrate advantages and disadvantages of this technology and its applications to mass analysis.

  17. BERNAS ION SOURCE DISCHARGE SIMULATION

    SciTech Connect (OSTI)

    RUDSKOY,I.; KULEVOY, T.V.; PETRENKO, S.V.; KUIBEDA, R.P.; SELEZNEV, D.N.; PERSHIN, V.I.; HERSHCOVITCH, A.; JOHNSON, B.M.; GUSHENETS, V.I.; OKS, E.M.; POOLE, H.J.

    2007-08-26

    The joint research and development program is continued to develop steady-state ion source of decaborane beam for ion implantation industry. Bemas ion source is the wide used ion source for ion implantation industry. The new simulation code was developed for the Bemas ion source discharge simulation. We present first results of the simulation for several materials interested in semiconductors. As well the comparison of results obtained with experimental data obtained at the ITEP ion source test-bench is presented.

  18. The newest achievements of studies on the reutilization, treatment, and disposal technology of hazardous wastes

    SciTech Connect (OSTI)

    Liu Peizhe [Chinese Research Academy of Environmental Sciences, Beijing (China)

    1996-12-31

    From 1991 to 1996, key studies on the reutilization, treatment, and disposal technology of hazardous wastes have been incorporated into the national plan for environmental protection science and technology. At present, the research achievements have been accomplished, have passed national approval, and have been accepted. The author of this paper, as leader of the national group for this research work, expounds the newest achievements of the studies involving four parts: (1) the reutilization technology of electroplating sludge, including the ion-exchange process for recovering the sludge and waste liquor for producing chromium tanning agent and extracting chromium and colloidal protein from tanning waste residue; on the recovery of heavy metals from the electroplating waste liquor with microbic purification; on the demonstration project of producing modified plastics from the sludge and the waste plastics; and on the demonstration of the recovery of heavy metals from waste electroplating sludge by using the ammonia-leaching process; (2) the demonstrative research of reutilization technology of chromium waste residues, including production of self-melting ore and smelting of chromium-containing pig iron, and of pyrolytic detoxification of the residue with cyclone furnace; (3) the incineration technology of hazardous wastes with successful results of the industrial incinerator system for polychlorinated biphenyls; and (4) the safety landfill technology for disposal of hazardous wastes, with a complete set of technology for pretreatment, selection of the site, development of the antipercolating materials, and design and construction of the landfill. Only a part of the achievements is introduced in this paper, most of which has been built and is being operated for demonstration to further spreading application and accumulate experience. 6 refs., 7 figs., 6 tabs.

  19. Ion photon emission microscope

    DOE Patents [OSTI]

    Doyle, Barney L. (Albuquerque, NM)

    2003-04-22

    An ion beam analysis system that creates microscopic multidimensional image maps of the effects of high energy ions from an unfocussed source upon a sample by correlating the exact entry point of an ion into a sample by projection imaging of the ion-induced photons emitted at that point with a signal from a detector that measures the interaction of that ion within the sample. The emitted photons are collected in the lens system of a conventional optical microscope, and projected on the image plane of a high resolution single photon position sensitive detector. Position signals from this photon detector are then correlated in time with electrical effects, including the malfunction of digital circuits, detected within the sample that were caused by the individual ion that created these photons initially.

  20. Ion beam generating apparatus

    DOE Patents [OSTI]

    Brown, Ian G. (1088 Woodside Rd., Berkeley, CA 94708); Galvin, James (2 Commodore #276, Emeryville, CA 94608)

    1987-01-01

    An ion generating apparatus utilizing a vacuum chamber, a cathode and an anode in the chamber. A source of electrical power produces an arc or discharge between the cathode and anode. The arc is sufficient to vaporize a portion of the cathode to form a plasma. The plasma is directed to an extractor which separates the electrons from the plasma, and accelerates the ions to produce an ion beam.

  1. Ion beam generating apparatus

    DOE Patents [OSTI]

    Brown, I.G.; Galvin, J.

    1987-12-22

    An ion generating apparatus utilizing a vacuum chamber, a cathode and an anode in the chamber. A source of electrical power produces an arc or discharge between the cathode and anode. The arc is sufficient to vaporize a portion of the cathode to form a plasma. The plasma is directed to an extractor which separates the electrons from the plasma, and accelerates the ions to produce an ion beam. 10 figs.

  2. Collection of ions

    DOE Patents [OSTI]

    Orr, Christopher Henry (Calderbridge, GB); Luff, Craig Janson (Calderbridge, GB); Dockray, Thomas (Calderbridge, GB); Macarthur, Duncan Whittemore (Los Alamos, NM); Bounds, John Alan (Los Alamos, NM); Koster, James E. (Los Alamos, NM)

    2001-01-01

    The apparatus and method provide an improved technique for detecting ions as the area from which ions are attracted to a detector is increased, consequently increasing the number of ions detected. This is achieved by providing the outer electrodes of the detector connected to the electrical potential, together with alternate intermediate electrodes. The other intermediate electrodes and preferably the housing are grounded. The technique renders such detection techniques more sensitive and gives them a lower threshold at which they can function.

  3. Information transmission without energy exchange

    E-Print Network [OSTI]

    Robert H. Jonsson; Eduardo Martin-Martinez; Achim Kempf

    2015-02-24

    We show that it is possible to use a massless field in the vacuum to communicate in such a way that the signal travels arbitrarily slower than the speed of light and such that no energy is transmitted from the sender to the receiver. Instead, the receiver has to supply a signal-dependent amount of work to switch his detector on and off. Because of that, this kind of communication without energy exchange may be called "Quantum Collect Calling". This type of communication is related to Casimir-like interactions and it is made possible by dimension ---and curvature--- dependent subtleties of Huygens' principle.

  4. Green Exchange | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIXsource History View New Pages RecentPlantMagmaIncentives JumpElectronics CouncilExchange

  5. Energy conservation potential of surface modification technologies

    SciTech Connect (OSTI)

    Le, H.K.; Horne, D.M.; Silberglitt, R.S.

    1985-09-01

    This report assesses the energy conservation impact of surface modification technologies on the metalworking industries. The energy conservation impact of surface modification technologies on the metalworking industries is assessed by estimating their friction and wear tribological sinks and the subsequent reduction in these sinks when surface modified tools are used. Ion implantation, coatings, and laser and electron beam surface modifications are considered.

  6. Correlation ion mobility spectroscopy

    DOE Patents [OSTI]

    Pfeifer, Kent B. (Los Lunas, NM); Rohde, Steven B. (Corrales, NM)

    2008-08-26

    Correlation ion mobility spectrometry (CIMS) uses gating modulation and correlation signal processing to improve IMS instrument performance. Closely spaced ion peaks can be resolved by adding discriminating codes to the gate and matched filtering for the received ion current signal, thereby improving sensitivity and resolution of an ion mobility spectrometer. CIMS can be used to improve the signal-to-noise ratio even for transient chemical samples. CIMS is especially advantageous for small geometry IMS drift tubes that can otherwise have poor resolution due to their small size.

  7. Demand response enabling technology development

    E-Print Network [OSTI]

    2006-01-01

    data of California power exchange wholesale electrical powerFigure 1: California power exchange wholesale electrical

  8. Graphene-oxide-coated LiNi0.5Mn1.5O4 as high voltage cathode for lithium ion batteries with high energy

    E-Print Network [OSTI]

    Zhou, Chongwu

    Graphene-oxide-coated LiNi0.5Mn1.5O4 as high voltage cathode for lithium ion batteries with high Since Sony rst commercialized lithium ion batteries in the early 1990s, the market for lithium ion of the great success of lithium ion battery technology developed for portable electronic devices, higher

  9. Energy Exchange 2015 Speaker Biographies

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Community that brings together a diverse set of expertise across DOE to help spur energy technology innovation through prizes and challenges, and she also co-leads the Wave Energy...

  10. Anion Exchange Membranes: Current Status and Moving Forward

    SciTech Connect (OSTI)

    Hickner, MA; Herring, AM; Coughlin, EB

    2013-10-29

    This short review is meant to provide the reader with highlights in anion exchange membrane research, describe current needs in the field, and point out promising directions for future work. Anion exchange membranes (AEMs) provide one possible route to low platinum or platinum-free fuel cells with the potential for facile oxidation of complex fuels beyond hydrogen and methanol. AEMs and related stable cationic polymers also have applications in energy storage and other electrochemical technologies such as water electrolyzers and redox flow batteries. While anion exchange membranes have been known for a long time in water treatment applications, materials for electrochemical technology with robust mechanical properties in thin film format have only recently become more widely available. High hydroxide and bicarbonate anion conductivity have been demonstrated in a range of AEM formats, but intrinsic stability of the polymers and demonstration of long device lifetime remain major roadblocks. Novel approaches to stable materials have focused on new types of cations that employ delocalization and steric shielding of the positive center to mitigate nucleophilic attack by hydroxide. A number of promising polymer backbones and membrane architectures have been identified, but limited device testing and a lack of understanding of the degradation mechanisms in operating devices is slowing progress on engineered systems with alkaline fuel cell technology. Our objective is to spur more research in this area to develop fuel cell systems that approach the costs of inexpensive batteries for large-scale applications. (c) 2013 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2013, 51, 1727-1735, 2013

  11. Exploration Technologies - Technology Needs Assessment

    SciTech Connect (OSTI)

    Greene, Amanda I.; Thorsteinsson, Hildigunnur; Reinhardt, Tim; Solomon, Samantha; James, Mallory

    2011-06-01

    This assessment is a critical component of ongoing technology roadmapping efforts, and will be used to guide the Geothermal Technology Program's research and development.

  12. Permeation Barrier Coatings for the Helical Heat Exchanger

    SciTech Connect (OSTI)

    Korinko, P.S.

    1999-05-26

    A permeation barrier coating was specified for the Helical Heat Exchanger (HHE) to minimize contamination through emissions and/or permeation into the nitrogen system for ALARA reasons. Due to the geometry of the HHE, a special coating practice was needed since the conventional method of high temperature pack aluminization was intractable. A survey of many coating companies was undertaken; their coating capabilities and technologies were assessed and compared to WSRC needs. The processes and limitations to coating the HHE are described. Slurry coating appears to be the most technically sound approach for coating the HHE.

  13. Shanghai Environment and Energy Exchange | Open Energy Information

    Open Energy Info (EERE)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on QA:QA J-E-1 SECTION J APPENDIX ECoop Inc JumpHeter Battery Technology Co Ltd Jump to: navigation,ChuanjiEnergy Exchange

  14. Cathodes - Technological review

    SciTech Connect (OSTI)

    Cherkouk, Charaf; Nestler, Tina

    2014-06-16

    Lithium cobalt oxide (LiCoO{sub 2}) was already used in the first commercialized Li-ion battery by SONY in 1990. Still, it is the most frequently used cathode material nowadays. However, LiCoO{sub 2} is intrinsically unstable in the charged state, especially at elevated temperatures and in the overcharged state causing volume changes and transport limitation for high power batteries. In this paper, some technological aspects with large impact on cell performance from the cathode material point of view will be reviewed. At first it will be focused on the degradation processes and life-time mechanisms of the cathode material LiCoO{sub 2}. Electrochemical and structural results on commercial Li-ion batteries recorded during the cycling will be discussed. Thereafter, advanced nanomaterials for new cathode materials will be presented.

  15. Research for Advanced Heat Exchangers- The U.S. DOE Program 

    E-Print Network [OSTI]

    Richlen, S. L.

    1986-01-01

    technical problem areas have been identified (see Figure 2). From these problem areas the technology deficiencies or R&D categories tend to group into three major areas: o Configurations o Materials o Support Technologies Industry's Heat Exchanger R... of Sciences, and outside reviewers to be sure that they fit within the DOE guidelines and meet industry's needs. The Office of Industrial Programs has considerable interaction with various technical societies, trade associations, industry working groups...

  16. Development of ion sources for ion projection lithography

    SciTech Connect (OSTI)

    Lee, Y.; Gough, R.A.; Kunkel, W.B.; Leung, K.N.; Perkins, L.T.

    1996-05-01

    Multicusp ion sources are capable of generating ion beams with low axial energy spread as required by the Ion Projection Lithography (IPL). Longitudinal ion energy spread has been studied in two different types of plasma discharge: the filament discharge ion source characterized by its low axial energy spread, and the RF-driven ion source characterized by its long source lifetime. For He{sup +} ions, longitudinal ion energy spreads of 1-2 eV were measured for a filament discharge multicusp ion source which is within the IPL device requirements. Ion beams with larger axial energy spread were observed in the RF-driven source. A double-chamber ion source has been designed which combines the advantages of low axial energy spread of the filament discharge ion source with the long lifetime of the RF-driven source. The energy spread of the double chamber source is lower than that of the RF-driven source.

  17. Thermally Activated Technologies Technology Roadmap, May 2003...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Thermally Activated Technologies Technology Roadmap, May 2003 Thermally Activated Technologies Technology Roadmap, May 2003 The purpose of this Technology Roadmap is to outline a...

  18. Selective ion source

    DOE Patents [OSTI]

    Leung, Ka-Ngo (Hercules, CA)

    1996-01-01

    A ion source is described wherein selected ions maybe extracted to the exclusion of unwanted ion species of higher ionization potential. Also described is a method of producing selected ions from a compound, such as P.sup.+ from PH.sub.3. The invention comprises a plasma chamber, an electron source, a means for introducing a gas to be ionized by electrons from the electron source, means for limiting electron energy from the electron source to a value between the ionization energy of the selected ion species and the greater ionization energy of an unwanted ion specie, and means for extracting the target ion specie from the plasma chamber. In one embodiment, the electrons are generated in a plasma cathode chamber immediately adjacent to the plasma chamber. A small extractor draws the electrons from the plasma cathode chamber into the relatively positive plasma chamber. The energy of the electrons extracted in this manner is easily controlled. The invention is particularly useful for doping silicon with P.sup.+, AS.sup.+, and B.sup.+ without the problematic presence of hydrogen, helium, water, or carbon oxide ions. Doped silicon is important for manufacture of semiconductors and semiconductor devices.

  19. Selective ion source

    DOE Patents [OSTI]

    Leung, K.N.

    1996-05-14

    A ion source is described wherein selected ions maybe extracted to the exclusion of unwanted ion species of higher ionization potential. Also described is a method of producing selected ions from a compound, such as P{sup +} from PH{sub 3}. The invention comprises a plasma chamber, an electron source, a means for introducing a gas to be ionized by electrons from the electron source, means for limiting electron energy from the electron source to a value between the ionization energy of the selected ion species and the greater ionization energy of an unwanted ion specie, and means for extracting the target ion specie from the plasma chamber. In one embodiment, the electrons are generated in a plasma cathode chamber immediately adjacent to the plasma chamber. A small extractor draws the electrons from the plasma cathode chamber into the relatively positive plasma chamber. The energy of the electrons extracted in this manner is easily controlled. The invention is particularly useful for doping silicon with P{sup +}, As{sup +}, and B{sup +} without the problematic presence of hydrogen, helium, water, or carbon oxide ions. Doped silicon is important for manufacture of semiconductors and semiconductor devices. 6 figs.

  20. Microfabricated cylindrical ion trap

    DOE Patents [OSTI]

    Blain, Matthew G.

    2005-03-22

    A microscale cylindrical ion trap, having an inner radius of order one micron, can be fabricated using surface micromachining techniques and materials known to the integrated circuits manufacturing and microelectromechanical systems industries. Micromachining methods enable batch fabrication, reduced manufacturing costs, dimensional and positional precision, and monolithic integration of massive arrays of ion traps with microscale ion generation and detection devices. Massive arraying enables the microscale cylindrical ion trap to retain the resolution, sensitivity, and mass range advantages necessary for high chemical selectivity. The microscale CIT has a reduced ion mean free path, allowing operation at higher pressures with less expensive and less bulky vacuum pumping system, and with lower battery power than conventional- and miniature-sized ion traps. The reduced electrode voltage enables integration of the microscale cylindrical ion trap with on-chip integrated circuit-based rf operation and detection electronics (i.e., cell phone electronics). Therefore, the full performance advantages of microscale cylindrical ion traps can be realized in truly field portable, handheld microanalysis systems.

  1. Better Buildings Neighborhood Program Workforce Peer Exchange...

    Energy Savers [EERE]

    Peer Exchange Call: Engaging and Growing Small Contractor Businesses Agenda * Call Logistics and Attendance * Discussion: Do programs have any lessons learned, success...

  2. Energy Exchange Payment Information and Cancellation Policy ...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Payment Information and Cancellation Policy Energy Exchange Payment Information and Cancellation Policy Payment Information An invoice will be sent to you with payment options....

  3. Heat transfer and heat exchangers reference handbook

    SciTech Connect (OSTI)

    Not Available

    1991-01-15

    The purpose of this handbook is to provide Rocky Flats personnel with an understanding of the basic concepts of heat transfer and the operation of heat exchangers.

  4. NETL's Energy Data eXchange

    ScienceCinema (OSTI)

    None

    2014-07-22

    A brief tour around NETL's Energy Data Exchange site, where researchers can upload data or look at data from another researcher.

  5. Miniaturized Air-to-Refrigerant Heat Exchangers

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    kW air-to-water and air-to- refrigerant heat exchangers Investigate conventional and additive manufacturing techniques Analyze system level performance of novel heat...

  6. Better Buildings Neighborhood Program Financing Peer Exchange...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1, 2011 Better Buildings Neighborhood Program Financing Peer Exchange Call: "What is the Right Rate?" Call Slides and Discussion Summary Agenda * Call Logistics and Attendance ...

  7. Better Buildings Neighborhood Program Sustainability Peer Exchange...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    1, 2012 Better Buildings Neighborhood Program Sustainability Peer Exchange Call: Revenue from Contractor Fees Agenda and Discussion * Welcome and Call Purpose This call was the...

  8. Better Buildings Neighborhood Program Workforce Peer Exchange...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Better Buildings Neighborhood Program Workforce Peer Exchange Call: Working with the Real Estate Sector Call Slides and Discussion Summary Agenda * Call Logistics and Attendance...

  9. Efficiency Exchange Conference Highlights Energy Efficiency Innovation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Efficiency Exchange Conference Highlights Energy Efficiency Innovations and Trends Northwest electric power industry connects on the latest energy efficiency programs and...

  10. Efficiency Exchange highlights energy efficiency innovations...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Efficiency Exchange highlights energy efficiency innovations and trends Northwest electric power industry connects on the latest energy efficiency programs and strategies Portland,...

  11. NETL's Energy Data eXchange

    SciTech Connect (OSTI)

    2014-07-16

    A brief tour around NETL's Energy Data Exchange site, where researchers can upload data or look at data from another researcher.

  12. Industrial Plate Exchangers Heat Recovery and Fouling 

    E-Print Network [OSTI]

    Cross, P. H.

    1981-01-01

    Plate and Frame Heat Exchangers have special characteristics for both fouling and heat recovery. These are discussed in general then related to two industrial examples....

  13. Ion mobility sensor system

    SciTech Connect (OSTI)

    Xu, Jun; Watson, David B.; Whitten, William B.

    2013-01-22

    An ion mobility sensor system including an ion mobility spectrometer and a differential mobility spectrometer coupled to the ion mobility spectrometer. The ion mobility spectrometer has a first chamber having first end and a second end extending along a first direction, and a first electrode system that generates a constant electric field parallel to the first direction. The differential mobility spectrometer includes a second chamber having a third end and a fourth end configured such that a fluid may flow in a second direction from the third end to the fourth end, and a second electrode system that generates an asymmetric electric field within an interior of the second chamber. Additionally, the ion mobility spectrometer and the differential mobility spectrometer form an interface region. Also, the first end and the third end are positioned facing one another so that the constant electric field enters the third end and overlaps the fluid flowing in the second direction.

  14. From transistor to trapped-ion computers for quantum chemistry

    E-Print Network [OSTI]

    M. -H. Yung; J. Casanova; A. Mezzacapo; J. McClean; L. Lamata; A. Aspuru-Guzik; E. Solano

    2013-07-16

    Over the last few decades, quantum chemistry has progressed through the development of computational methods based on modern digital computers. However, these methods can hardly fulfill the exponentially-growing resource requirements when applied to large quantum systems. As pointed out by Feynman, this restriction is intrinsic to all computational models based on classical physics. Recently, the rapid advancement of trapped-ion technologies has opened new possibilities for quantum control and quantum simulations. Here, we present an efficient toolkit that exploits both the internal and motional degrees of freedom of trapped ions for solving problems in quantum chemistry, including molecular electronic structure, molecular dynamics, and vibronic coupling. We focus on applications that go beyond the capacity of classical computers, but may be realizable on state-of-the-art trapped-ion systems. These results allow us to envision a new paradigm of quantum chemistry that shifts from the current transistor to a near-future trapped-ion-based technology.

  15. APEC experts` group on clean coal technology

    SciTech Connect (OSTI)

    NONE

    1994-12-31

    The proceedings of the Asia-Pacific Economic Cooperation (APEC) Expert`s Group on Clean Coal Technology`s Technical Seminar held in Jakarta, Indonesia, from October 10-13, 1994 are presented. A total of 28 papers were presented at the seminar. These papers addressed issues of relevance to APEC member economies associated with the application of clean coal technologies (CCTs) and created a forum where information and ideas about CCTs and their application in the Asia-Pacific Region could be exchanged. A separate abstract was prepared for each paper for inclusion in the Energy Science and Technology Database.

  16. Nuclear Reactors and Technology; (USA)

    SciTech Connect (OSTI)

    Cason, D.L.; Hicks, S.C.

    1991-01-01

    Nuclear Reactors and Technology (NRT) announces on a monthly basis the current worldwide information available from the open literature on nuclear reactors and technology, including all aspects of power reactors, components and accessories, fuel elements, control systems, and materials. This publication contains the abstracts of DOE reports, journal articles, conference papers, patents, theses, and monographs added to the Energy Science and Technology Database (EDB) during the past month. Also included are US information obtained through acquisition programs or interagency agreements and international information obtained through the International Energy Agency's Energy Technology Data Exchange or government-to-government agreements. The digests in NRT and other citations to information on nuclear reactors back to 1948 are available for online searching and retrieval on EDB and Nuclear Science Abstracts (NSA) database. Current information, added daily to EDB, is available to DOE and its contractors through the DOE integrated Technical Information System. Customized profiles can be developed to provide current information to meet each user's needs.

  17. A Simplified Electrochemical and Thermal Aging Model of LiFePO4-Graphite Li-ion Batteries

    E-Print Network [OSTI]

    1 A Simplified Electrochemical and Thermal Aging Model of LiFePO4-Graphite Li-ion Batteries: Power of a commercial LiFePO4-graphite Li-ion battery. Compared to the isothermal reference, the mechanism of porosity;2 Due to their high power and energy densities, Li-ion technologies are the leading battery systems

  18. Metal-Ion-Mediated Reactions

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Metal-Ion-Mediated Reactions Metal-Ion-Mediated Reactions Print Monday, 19 December 2011 18:29 While mononuclear, polynuclear, and polymeric metal complexes are most often...

  19. Nuclear electric propulsion for planetary science missions: NASA technology program planning

    SciTech Connect (OSTI)

    Doherty, M.P. (NASA Lewis Research Center, 21000 Brookpark Rd., Cleveland, Ohio 44135 (United States))

    1993-01-10

    This paper presents the status of technology program planning to achieve readiness of Nuclear Electric Propulsion technologies needed to meet the advanced propulsion system requirements for planetary science missions in the next century. The technology program planning is based upon technologies of significant maturity: ion electric propulsion and the SP-100 space nulcear power technologies. Detailed plans are presented herein for the required ion electric propulsion technology development and demonstration. Closer coordination between space nuclear power and space electric propulsion technology programs is a necessity as technology plans are being further refined in light of NEP concept definition and possible early NEP flight activities.

  20. Nuclear electric propulsion for planetary science missions: NASA technology program planning

    SciTech Connect (OSTI)

    Doherty, M.P.

    1993-05-01

    This paper presents the status of technology program planning to develop those Nuclear Electric Propulsion technologies needed to meet the advanced propulsion system requirements for planetary science missions in the next century. The technology program planning is based upon technologies with significant development heritage: ion electric propulsion and the SP-100 space nuclear power technologies. Detailed plans are presented for the required ion electric propulsion technology development and demonstration. Closer coordination between space nuclear power and space electric propulsion technology programs is a necessity as technology plans are being further refined in light of NEP concept definition and possible early NEP flight activities.