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1

Ion exchange technology assessment report  

SciTech Connect

In the execution of its charter, the SRS Ion Exchange Technology Assessment Team has determined that ion exchange (IX) technology has evolved to the point where it should now be considered as a viable alternative to the SRS reference ITP/LW/PH process. The ion exchange media available today offer the ability to design ion exchange processing systems tailored to the unique physical and chemical properties of SRS soluble HLW's. The technical assessment of IX technology and its applicability to the processing of SRS soluble HLW has demonstrated that IX is unquestionably a viable technology. A task team was chartered to evaluate the technology of ion exchange and its potential for replacing the present In-Tank Precipitation and proposed Late Wash processes to remove Cs, Sr, and Pu from soluble salt solutions at the Savannah River Site. This report documents the ion exchange technology assessment and conclusions of the task team.

Duhn, E.F.

1992-01-01T23:59:59.000Z

2

Ion exchange technology assessment report  

SciTech Connect

In the execution of its charter, the SRS Ion Exchange Technology Assessment Team has determined that ion exchange (IX) technology has evolved to the point where it should now be considered as a viable alternative to the SRS reference ITP/LW/PH process. The ion exchange media available today offer the ability to design ion exchange processing systems tailored to the unique physical and chemical properties of SRS soluble HLW`s. The technical assessment of IX technology and its applicability to the processing of SRS soluble HLW has demonstrated that IX is unquestionably a viable technology. A task team was chartered to evaluate the technology of ion exchange and its potential for replacing the present In-Tank Precipitation and proposed Late Wash processes to remove Cs, Sr, and Pu from soluble salt solutions at the Savannah River Site. This report documents the ion exchange technology assessment and conclusions of the task team.

Duhn, E.F.

1992-12-31T23:59:59.000Z

3

Small Column Ion Exchange at Savannah River Site Technology Readiness Assessment Report  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Small Column Ion Exchange Technology at Small Column Ion Exchange Technology at Savannah River Site U.S. Department of Energy Office of Environmental Management Office of Technology Innovation and Development Technology Readiness Assessment Report November 2011 U.S. DOE-EM Office of Technology Innovation and Development November 11, 2011 Small Column Ion Exchange Program Technology Readiness Assessment Page 2 of 112 This page intentionally left blank November 11, 2011 U.S. DOE-EM Office of Technology Innovation and Development Small Column Ion Exchange Program Technology Readiness Assessment Page 3 of 112 APPROVALS ________________________ _ Harry D. Harmon Date

4

Small Column Ion Exchange Technology at Savannah River Site | Department of  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Small Column Ion Exchange Technology at Savannah River Site Small Column Ion Exchange Technology at Savannah River Site Small Column Ion Exchange Technology at Savannah River Site The Small Column Ion Exchange (SCIX) system being developed for deployment at the Savannah River Site (SRS) is a supplementary salt waste processing technology that, if implemented, will augment the baseline Salt Waste Processing Facility (SWPF) capability. An opportunity exists to shorten the SRS radioactive waste system lifecycle by 6 years, and significantly reduce life cycle costs, by accelerating salt processing to earlier completion, simultaneous with sludge vitrification. As described in the Enhanced Tank Waste Strategy, which is part of the Department of Energy (DOE) Office of Environmental Management (EM) Roadmap - EM Journey to Excellence,

5

LITERATURE REVIEWS TO SUPPORT ION EXCHANGE TECHNOLOGY SELECTION FOR MODULAR SALT PROCESSING  

SciTech Connect

This report summarizes the results of literature reviews conducted to support the selection of a cesium removal technology for application in a small column ion exchange (SCIX) unit supported within a high level waste tank. SCIX is being considered as a technology for the treatment of radioactive salt solutions in order to accelerate closure of waste tanks at the Savannah River Site (SRS) as part of the Modular Salt Processing (MSP) technology development program. Two ion exchange materials, spherical Resorcinol-Formaldehyde (RF) and engineered Crystalline Silicotitanate (CST), are being considered for use within the SCIX unit. Both ion exchange materials have been studied extensively and are known to have high affinities for cesium ions in caustic tank waste supernates. RF is an elutable organic resin and CST is a non-elutable inorganic material. Waste treatment processes developed for the two technologies will differ with regard to solutions processed, secondary waste streams generated, optimum column size, and waste throughput. Pertinent references, anticipated processing sequences for utilization in waste treatment, gaps in the available data, and technical comparisons will be provided for the two ion exchange materials to assist in technology selection for SCIX. The engineered, granular form of CST (UOP IE-911) was the baseline ion exchange material used for the initial development and design of the SRS SCIX process (McCabe, 2005). To date, in-tank SCIX has not been implemented for treatment of radioactive waste solutions at SRS. Since initial development and consideration of SCIX for SRS waste treatment an alternative technology has been developed as part of the River Protection Project Waste Treatment Plant (RPP-WTP) Research and Technology program (Thorson, 2006). Spherical RF resin is the baseline media for cesium removal in the RPP-WTP, which was designed for the treatment of radioactive waste supernates and is currently under construction in Hanford, WA. Application of RF for cesium removal in the Hanford WTP does not involve in-riser columns but does utilize the resin in large scale column configurations in a waste treatment facility. The basic conceptual design for SCIX involves the dissolution of saltcake in SRS Tanks 1-3 to give approximately 6 M sodium solutions and the treatment of these solutions for cesium removal using one or two columns supported within a high level waste tank. Prior to ion exchange treatment, the solutions will be filtered for removal of entrained solids. In addition to Tanks 1-3, solutions in two other tanks (37 and 41) will require treatment for cesium removal in the SCIX unit. The previous SCIX design (McCabe, 2005) utilized CST for cesium removal with downflow supernate processing and included a CST grinder following cesium loading. Grinding of CST was necessary to make the cesium-loaded material suitable for vitrification in the SRS Defense Waste Processing Facility (DWPF). Because RF resin is elutable (and reusable) and processing requires conversion between sodium and hydrogen forms using caustic and acidic solutions more liquid processing steps are involved. The WTP baseline process involves a series of caustic and acidic solutions (downflow processing) with water washes between pH transitions across neutral. In addition, due to resin swelling during conversion from hydrogen to sodium form an upflow caustic regeneration step is required. Presumably, one of these basic processes (or some variation) will be utilized for MSP for the appropriate ion exchange technology selected. CST processing involves two primary waste products: loaded CST and decontaminated salt solution (DSS). RF processing involves three primary waste products: spent RF resin, DSS, and acidic cesium eluate, although the resin is reusable and typically does not require replacement until completion of multiple treatment cycles. CST processing requires grinding of the ion exchange media, handling of solids with high cesium loading, and handling of liquid wash and conditioning solutions. RF processing requires h

King, W

2007-11-30T23:59:59.000Z

6

Summary - Small Column Ion Exchange (SCIX)Technology at the SRS  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

ETR ETR R Un Baseline The Sm being The SC operat which Sr, and waste critical the SC deploy Specif exchan [CST]) CST, a (mono and so (RMF) maturi readin design moving The pu techni projec Site: S roject: S E Report Date: F ited States Sma Why DOE e SCIX System Pr mall Column Io developed at S CIX system is tions (ion excha function to rem d actinides) fro and prepare th l technology ele CIX system tha yment and thes fically the critica nge on a selec ) housed in an actinide and Sr osodium titanat olids/liquid sepa ). The objectiv ty of the SCIX ess of the proc n, and to provid g towards deta To view the full E http://www.em.doe. urpose of an Externa ical risk associated w ct decisions. Technic Savannah Rive Small Column Exchange/SCIX Feb. 2011 Departmen ll Colum E-EM Did This rocess Diagram on Exchange (S

7

Ion exchange technology in the remediation of uranium contaminated groundwater at Fernald  

SciTech Connect

Using pump and treat methodology, uranium contaminated groundwater is being removed from the Great Miami Aquifer at the Fernald Environmental Management Project (FEMP) per the FEMP Record of Decision (ROD) that defines groundwater cleanup. Standard extraction wells pump about 3900 gallons-per-minute (gpm) from the aquifer through five ion exchange treatment systems. The largest treatment system k the Advanced Wastewater Treatment (AWWT) Expansion System with a capacity of 1800 gpm, which consists of three trains of two vessels. The trains operate in parallel treating 600 gpm each, The two vessels in each train operate in series, one in lead and one in lag. Treated groundwater is either reinfected back into the aquifer to speed up the aquifer cleanup processor discharged to the Great Miami River. The uranium regulatory ROD limit for discharge to the river is 20 parts per billion (ppb), and the FEMP uranium administrative action level for reinfection is 10 ppb. Spent (i.e., a resin that no longer adsorbs uranium) ion exchange resins must either be replaced or regenerated. The regeneration of spent ion exchange resins is considerably more cost effective than their replacement. Therefore, a project was undertaken to learn how best to regenerate the resins in the groundwater vessels. At the outset of this project, considerable uncertainty existed as to whether a spent resin could be regenerated successfully enough so that it performed as well as new resin relative to achieving very low uranium concentrations in the effluent. A second major uncertain y was whether the operational lifetime of a regenerated resin would be similar to that of a new resin with respect to uranium loading capacity and effluent concentration behavior. The project was successful in that a method for regenerating resins has been developed that is operationally efficient, that results in regenerated resins yielding uranium concentrations much lower than regulatory limits, and that results in regenerated resins with operational lifetimes comparable to new resins.

Chris Sutton; Cathy Glassmeyer; Steve Bozich

2000-09-29T23:59:59.000Z

8

Technology Performance Exchange  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Technology Performance Exchange Technology Performance Exchange TDM - Jason Koman (BTO) TDM - Dave Catarious (FEMP) William Livingood National Renewable Energy Laboratory William.Livingood@nrel.gov 303-384-7490 April 2, 2013 2 | Building Technologies Office eere.energy.gov Purpose & Objectives Problem: Perceived fiscal risk associated with the installation of unfamiliar technologies impedes adoption rates for cost-effective, energy-saving products. Impact of Project: Enable end users to quickly and

9

Technology Performance Exchange (Fact Sheet)  

SciTech Connect

This fact sheet, 'The Technology Performance Exchange' will be presented at the ET Summit, held at the Pasadena Convention Center on October 15-17, 2012. The Technology Performance Exchange will be a centralized, Web-based portal for finding and sharing energy performance data for commercial building technologies.

Not Available

2012-10-01T23:59:59.000Z

10

Grafted methylenediphosphonate ion exchange resins  

DOE Patents (OSTI)

An ion exchange resin is disclosed that is comprised of an insoluble copolymer onto which are grafted pendent groups that provide 1.0 to about 10 mmol/g dry weight phosphorous. The pendent groups have the formula ##STR1## wherein R is hydrogen, a cation or mixtures thereof; and R.sup.1 is hydrogen or an C.sub.1 -C.sub.2 alkyl group. The resin also contains zero to about 5 mmol/g dry weight of pendent aromatic sulfonate groups. Processes for making and using an ion exchange resin are also disclosed.

Trochimcznk, Andrzej W. (Knoxbille, TN); Gatrone, Ralph C. (Plymouth, PA); Alexandratos, Spiro (Knoxville, TN); Horwitz, E. Philip (Naperville, IL)

1997-01-01T23:59:59.000Z

11

Grafted methylenediphosphonate ion exchange resins  

DOE Patents (OSTI)

An ion exchange resin is disclosed that is comprised of an insoluble copolymer onto which are grafted pendent groups that provide 1.0 to about 10 mmol/g dry weight phosphorous. The pendent groups have the formula ##STR1## wherein R is hydrogen, a cation or mixtures thereof; and R.sup.1 is hydrogen or an C.sub.1 -C.sub.2 alkyl group. The resin also contains zero to about 5 mmol/g dry weight of pendent aromatic sulfonate groups. Processes for making and using an ion exchange-resin are also disclosed.

Trochimcznk, Andrzej W. (Knoxville, TN); Gatrone, Ralph C. (Plymouth, PA); Alexandratos, Spiro (Knoxville, TN); Horwitz, E. Philip (Naperville, IL)

1998-01-27T23:59:59.000Z

12

Morphology of Ion Exchange Membranes  

Science Journals Connector (OSTI)

......the HjO,- treatment of the ion exchange...and rinsed with water. After drying...Determined in sea water at 25 C by electrodialysis. Fig. 2. Neosepta...with deionized water, treated with...prepared by the treatment of the cation......

Yoshikazu HORI; Toru NAKATANI; Yukio MIZUTANI

1986-10-01T23:59:59.000Z

13

Ion exchange purification of scandium  

DOE Patents (OSTI)

An improvement in purification of scandium through ion exchange chromatography is disclosed in which the oxidation potential of the eluting solution is altered by the addition of potassium chlorate or ammonium chloride so that removal of contaminants is encouraged. The temperature, pH and concentration of the eluent HEDTA are controlled in order to maintain the scandium in the column while minimizing dilution of the scandium band. Recovery of scandium is improved by pumping dilute scandium over the column prior to stripping the scandium and precipitation. This eliminates the HEDTA ion and other monovalent cations contaminating the scandium band. This method maximizes recovery of scandium while maintaining purity. 2 figs.

Herchenroeder, L.A.; Burkholder, H.R.

1990-10-23T23:59:59.000Z

14

Technology Performance Exchange | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Performance Exchange Performance Exchange Technology Performance Exchange A collaboration between the U.S. Department of Energy's (DOE's) Federal Energy Management Program Office and the Building Technologies Office, the Technology Performance Exchange will establish a Web-based portal and accompanying database that allows technology suppliers to submit product performance data that private and public sector end users can use to make fact-based procurement decisions. Suppliers will populate the database with technologies that affect building activities, including construction, commissioning, maintenance, monitoring, equipment, and verification. This project will help the U.S. energy efficiency technology market by providing objective product performance data to building engineers and

15

The many faces of ion-exchange resins  

SciTech Connect

Ion-exchange resins have been used commercially for over 60 years. Softening and demineralization of water for boiler feed and process use were then, and continue to be, the most familiar and widespread applications of ion-exchange resins throughout the chemical process industries (CPI). Several types of membrane-based technologies, such as electrodialysis, reverse osmosis and, more recently, electrodeionization are recognized as alternative methods for water treatment. Yet, modern versions of ion-exchange resins remain a major player in water treatment. In addition, these versatile materials can be found performing a wide range of tasks in both aqueous and nonaqueous environments. Some of these diverse applications include: acid or base catalysis; manufacture of high-purity solvents and reagent chemicals; separation of by-products of fermentation processes; deacidification of organic solvents; high-purity water production for semiconductor manufacture; recovery of valuable waste from dilute process effluents; controlled release of pharmaceutical products; and chromatography, both on the analytical and the industrial scale. The key to understanding the potential of ion-exchange resins is to look beyond their exchange and adsorptive characteristics, and to see their fundamental nature. In other words, it`s necessary to first consider them as spherical, particulate reactive polymers that perform chemical reactions.

McNutty, J.T. [Rohm and Haas Co., Philadelphia, PA (United States)

1997-06-01T23:59:59.000Z

16

Porous solid ion exchange wafer for immobilizing biomolecules  

DOE Patents (OSTI)

A porous solid ion exchange wafer having a combination of a biomolecule capture-resin and an ion-exchange resin forming a charged capture resin within said wafer. Also disclosed is a porous solid ion exchange wafer having a combination of a biomolecule capture-resin and an ion-exchange resin forming a charged capture resin within said wafer containing a biomolecule with a tag. A separate bioreactor is also disclosed incorporating the wafer described above.

Arora, Michelle B. (Woodridge, IL); Hestekin, Jamie A. (Morton Grove, IL); Lin, YuPo J. (Naperville, IL); St. Martin, Edward J. (Libertyville, IL); Snyder, Seth W. (Lincolnwood, IL)

2007-12-11T23:59:59.000Z

17

Technology Performance Exchange - 2014 BTO Peer Review | Department...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Technology Performance Exchange - 2014 BTO Peer Review Technology Performance Exchange - 2014 BTO Peer Review Project Objective This project's overall goal is to ensure that...

18

Novel silica-based ion exchange resin  

SciTech Connect

Eichrom`s highly successful Diphonixo resin resembles a conventional ion exchange resin in its use of sulfonic acid ligands on a styrene- divinylbenzene matrix. Diphonix resin exhibits rapid exchange kinetics that allow economical operation of ion exchange systems. Unlike conventional resins, Diphonix resin contains chelating ligands that are diphosphonic acid groups that recognize and remove the targeted metals and reject the more common elements such as sodium, calcium and magnesium. This latter property makes Diphonix ideal for many industrial scale applications, including those involving waste treatment. For treatment of low-level, transuranic (TRU) and high- level radioactive wastes, Diphonix`s polystyrene backbone hinders its application due to radiolytic stability of the carbon-hydrogen bonds and lack of compatibility with expected vitrification schemes. Polystyrene-based Diphonix is approximately 60% carbon- hydrogen. In response to an identified need within the Department of Energy for a resin with the positive attributes of Diphonix that also exhibits greater radiolytic stability and final waste form compatibility, Eichrom has successfully developed a new, silica-based resin version of Diphonix. Target application for this new resin is for use in environmental restoration and waste management situations involving the processing of low-level, transuranic and high-level radioactive wastes. The resin can also be used for processing liquid mixed waste (waste that contains low level radioactivity and hazardous constituents) including mixed wastes contaminated with organic compounds. Silica-based Diphonix is only 10% carbon-hydrogen, with the bulk of the matrix silica.

NONE

1997-11-01T23:59:59.000Z

19

Intermediate-Scale Ion Exchange Removal of Cesium and Technetium from Hanford Tank 241-AN-102  

SciTech Connect

Ion exchange tests have been completed at the Savannah River Technology Center for British Nuclear Fuels Limited, Inc. as part of the Hanford River Protection Project. Radioactive cesium and technetium (pertechnetate form only) were removed by ion exchange from a sample of Envelope C salt solution from Hanford Tank 241-AN-102 (sample volume: approximately 17 L at 4.8 M Na plus). The original sample was diluted and subjected to strontium/transuranics (Sr/TRU) precipitation and filtration processes before ion exchange processing was performed. Batch contact and column tests for the ion exchange removal of cesium and technetium were then completed on the Sr/TRU-decontaminated product. Previous ion exchange tests were conducted on a smaller portion (0.5 L) of the Tank 241-AN-102 supernate sample, which had been similarly pretreated, and the results were reported in a separate document.

King, W.D.

2001-02-15T23:59:59.000Z

20

Intermediate-Scale Ion Exchange Removal of Cesium and Technetium from Hanford Tank 241-AN-102  

SciTech Connect

Ion exchange tests have been completed at the Savannah River Technology Center for British Nuclear Fuels Limited, Inc. as part of the Hanford River Protection Project. Radioactive cesium and technetium (pertechnetate form only) were removed by ion exchange from a sample of Envelope C salt solution from Hanford Tank 241-AN-102 (sample volume: approximately 18 L at 4.8 M Na plus). The original sample was diluted and subjected to strontium/transuranics (Sr/TRU) precipitation and filtration processes before ion exchange processing was performed. Batch contact and column tests for the ion exchange removal of cesium and technetium were then completed on the Sr/TRU-decontaminated product. Previous ion exchange tests were conducted on a smaller portion (0.5 L) of the Tank 241-AN-102 supernate sample, which had been similarly pretreated, and the results were reported in a separate document.

King, W.D.

2001-09-10T23:59:59.000Z

Note: This page contains sample records for the topic "ion exchange technology" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Energy Technology Data Exchange | Open Energy Information  

Open Energy Info (EERE)

Exchange Exchange Jump to: navigation, search Logo: Energy Technology Data Exchange Name Energy Technology Data Exchange Address P.O. Box 62 Place Oak Ridge, Tennessee Zip 37831 Year founded 1987 Phone number 865 576 1272 Coordinates 36.0103°, -84.2698° Loading map... {"minzoom":false,"mappingservice":"googlemaps3","type":"ROADMAP","zoom":14,"types":["ROADMAP","SATELLITE","HYBRID","TERRAIN"],"geoservice":"google","maxzoom":false,"width":"600px","height":"350px","centre":false,"title":"","label":"","icon":"","visitedicon":"","lines":[],"polygons":[],"circles":[],"rectangles":[],"copycoords":false,"static":false,"wmsoverlay":"","layers":[],"controls":["pan","zoom","type","scale","streetview"],"zoomstyle":"DEFAULT","typestyle":"DEFAULT","autoinfowindows":false,"kml":[],"gkml":[],"fusiontables":[],"resizable":false,"tilt":0,"kmlrezoom":false,"poi":true,"imageoverlays":[],"markercluster":false,"searchmarkers":"","locations":[{"text":"","title":"","link":null,"lat":36.0103,"lon":-84.2698,"alt":0,"address":"","icon":"","group":"","inlineLabel":"","visitedicon":""}]}

22

Solidification of ion exchange resin wastes  

SciTech Connect

Solidification media investigated included portland type I, portland type III and high alumina cements, a proprietary gypsum-based polymer modified cement, and a vinyl ester-styrene thermosetting plastic. Samples formulated with hydraulic cement were analyzed to investigate the effects of resin type, resin loading, waste-to-cement ratio, and water-to-cement ratio. The solidification of cation resin wastes with portland cement was characterized by excessive swelling and cracking of waste forms, both after curing and during immersion testing. Mixed bed resin waste formulations were limited by their cation component. Additives to improve the mechanical properties of portland cement-ion exchange resin waste forms were evaluated. High alumina cement formulations dislayed a resistance to deterioration of mechanical integrity during immersion testing, thus providing a significant advantage over portland cements for the solidification of resin wastes. Properties of cement-ion exchange resin waste forms were examined. An experiment was conducted to study the leachability of /sup 137/Cs, /sup 85/Sr, and /sup 60/Co from resins modified in portland type III and high alumina cements. The cumulative /sup 137/Cs fraction release was at least an order of magnitude greater than that of either /sup 85/Sr or /sup 60/Co. Release rates of /sup 137/Cs in high alumina cement were greater than those in portland III cement by a factor of two.Compressive strength and leach testing were conducted for resin wastes solidified with polymer-modified gypsum based cement. /sup 137/Cs, /sup 85/Sr, and /sup 60/Co fraction releases were about one, two and three orders of magnitude higher, respectively, than in equivalent portland type III cement formulations. As much as 28.6 wt % dry ion exchange resin was successfully solidified using vinyl ester-styrene compared with a maximum of 25 wt % in both portland and gypsum-based cement.

Not Available

1982-08-01T23:59:59.000Z

23

Organosilicon ion-exchange and complexing adsorbents  

Science Journals Connector (OSTI)

Data on the ion-exchange and complexing organosilicon adsorbents published during the last 1012 years, including the results of systematic research of the authors, are summarized and analyzed. The following types of substances are considered: silicas with covalently grafted modifiers, silicas and aluminosilicates with non-covalently grafted modifiers and carbofunctional polyorganylsilsesquioxanes prepared by polycondensation of appropriate organosilicon monomers. Adsorbents of these types find extensive practical use, in particular, as analytical reagents for determination of metals in natural and artificial specimens, agents for isolation of valuable elements from industrial wastes and agents for removal of especially hazardous components from wastes and effluents. The bibliography includes 109 references.

N N Vlasova; E N Oborina; O Yu Grigoryeva; Mikhail G Voronkov

2013-01-01T23:59:59.000Z

24

Modeling Multi-Metal Ion Exchange in Biosorption  

E-Print Network (OSTI)

, may serve as a means for purifying industrial wastewaters that contain toxic heavy metal ions heavy metals often through ion exchange. This biosorption can be used for purification of metalModeling Multi-Metal Ion Exchange in Biosorption S I L K E S C H I E W E R A N D B O H U M I L V O

Volesky, Bohumil

25

Building Technologies Office: HVAC Optimized Heat Exchangers Research  

NLE Websites -- All DOE Office Websites (Extended Search)

Optimized Heat Optimized Heat Exchangers Research Project to someone by E-mail Share Building Technologies Office: HVAC Optimized Heat Exchangers Research Project on Facebook Tweet about Building Technologies Office: HVAC Optimized Heat Exchangers Research Project on Twitter Bookmark Building Technologies Office: HVAC Optimized Heat Exchangers Research Project on Google Bookmark Building Technologies Office: HVAC Optimized Heat Exchangers Research Project on Delicious Rank Building Technologies Office: HVAC Optimized Heat Exchangers Research Project on Digg Find More places to share Building Technologies Office: HVAC Optimized Heat Exchangers Research Project on AddThis.com... About Take Action to Save Energy Partner with DOE Activities Appliances Research Building Envelope Research

26

Building Technologies Office: Building Energy Data Exchange Specification  

NLE Websites -- All DOE Office Websites (Extended Search)

Building Energy Data Building Energy Data Exchange Specification to someone by E-mail Share Building Technologies Office: Building Energy Data Exchange Specification on Facebook Tweet about Building Technologies Office: Building Energy Data Exchange Specification on Twitter Bookmark Building Technologies Office: Building Energy Data Exchange Specification on Google Bookmark Building Technologies Office: Building Energy Data Exchange Specification on Delicious Rank Building Technologies Office: Building Energy Data Exchange Specification on Digg Find More places to share Building Technologies Office: Building Energy Data Exchange Specification on AddThis.com... About Take Action to Save Energy Activities 179d Tax Calculator Advanced Energy Design Guides Advanced Energy Retrofit Guides

27

Heavy metals removal from oil sludge using ion exchange textiles.  

E-Print Network (OSTI)

??In this research, ion exchange textiles were used for the first time for the removal of heavy metals from oil sludge. The target metals which (more)

Muslat, Ziyad

2005-01-01T23:59:59.000Z

28

Effects of ionizing radiation on modern ion exchange materials  

SciTech Connect

We review published studies of the effects of ionizing radiation on ion exchange materials, emphasizing those published in recent years. A brief overview is followed by a more detailed examination of recent developments. Our review includes styrene/divinylbenzene copolymers with cation-exchange or anion-exchange functional groups, polyvinylpyridine anion exchangers, chelating resins, multifunctional resins, and inorganic exchangers. In general, strong-acid cation exchange resins are more resistant to radiation than are strong-base anion exchange resins, and polyvinylpyridine resins are more resistant than polystyrene resins. Cross-linkage, salt form, moisture content, and the surrounding medium all affect the radiation stability of a specific exchanger. Inorganic exchangers usually, but not always, exhibit high radiation resistance. Liquid ion exchangers, which have been used so extensively in nuclear processing applications, also are included.

Marsh, S.F.; Pillay, K.K.S.

1993-10-01T23:59:59.000Z

29

TECHNICAL COMPARISON OF CANDIDATE ION EXCHANGE MEDIA FOR SMALL COLUMN ION EXCHANGE (SCIX) APPLICATIONS IN SUPPORT OF SUPPLEMENTAL LAW PRETREATMENT  

SciTech Connect

At-tank supplemental pretreatment including both filtration and small column ion exchange is currently under evaluation to facilitate salt waste retrieval and processing in the Hanford tank farms. Spherical resorcinol formaldehyde (sRF) resin is the baseline ion exchange resin for use in the Waste Treatment and Immobilization Plant (WTP). This document provides background and technical rationale to assist in determining whether spherical resorcinol formaldehyde (sRF) is also the appropriate ion exchange resin for supplemental LAW pretreatment processes and compares sRF with crystalline silicotitanate (CST) as potential supplemental pretreatment ion exchange media.

RAMSEY AA; THORSON MR

2010-12-28T23:59:59.000Z

30

NEI Corporation Technology Promotes Efficiency in Heat Exchangers...  

Office of Science (SC) Website

More Information January 2013 NEI Corporation Technology Promotes Efficiency in Heat Exchangers NEI's SuperCondenser(tm) technology increases the energy efficiency of a...

31

E-Print Network 3.0 - acidic ion exchange Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

Gina M. Canfield,a Summary: and other zeolites tend to exchange hydronium ions from hydro- lyzed water or from acidic hydrated metal... Sodalite ion exchange in polyethylene...

32

Interpenetrating polymer network ion exchange membranes and method for preparing same  

DOE Patents (OSTI)

Interpenetrating polymer network ion exchange membranes include a microporous polymeric support film interpenetrated by an ion exchange polymer and are produced by absorbing and polymerizing monomers within the support film. The ion exchange polymer provides ion exchange ligands at the surface of and throughout the support film which have sufficient ligand mobility to extract and transport ions across the membrane.

Alexandratos, Spiro D. (Knoxville, TN); Danesi, Pier R. (Vienna, AT); Horwitz, E. Philip (Naperville, IL)

1989-01-01T23:59:59.000Z

33

Assessment of commercially available ion exchange materials for cesium removal from highly alkaline wastes  

SciTech Connect

Approximately 61 million gallons of nuclear waste generated in plutonium production, radionuclide removal campaigns, and research and development activities is stored on the Department of Energy`s Hanford Site, near Richland, Washington. Although the pretreatment process and disposal requirements are still being defined, most pretreatment scenarios include removal of cesium from the aqueous streams. In many cases, after cesium is removed, the dissolved salt cakes and supernates can be disposed of as LLW. Ion exchange has been a leading candidate for this separation. Ion exchange systems have the advantage of simplicity of equipment and operation and provide many theoretical stages in a small space. The organic ion exchange material Duolite{trademark} CS-100 has been selected as the baseline exchanger for conceptual design of the Initial Pretreatment Module (IPM). Use of CS-100 was chosen because it is considered a conservative, technologically feasible approach. During FY 96, final resin down-selection will occur for IPM Title 1 design. Alternate ion exchange materials for cesium exchange will be considered at that time. The purpose of this report is to conduct a search for commercially available ion exchange materials which could potentially replace CS-100. This report will provide where possible a comparison of these resin in their ability to remove low concentrations of cesium from highly alkaline solutions. Materials which show promise can be studied further, while less encouraging resins can be eliminated from consideration.

Brooks, K.P.; Kim, A.Y.; Kurath, D.E.

1996-04-01T23:59:59.000Z

34

Tc-99 Ion Exchange Resin Testing  

SciTech Connect

Pacific Northwest National Laboratory was contracted by CHPRC to evaluate the release of 99Tc from spent resin used to treat water from well 299-W15-765 and stored for several years. The key questions to be answered are: 1) does 99Tc readily release from the spent ion exchange resin after being in storage for several years; 2) if hot water stripping is used to remove the co-contaminant carbon tetrachloride, will 99Tc that has been sequestered by the resin be released; and 3) can spent resin be encapsulated into a cementitious waste form; if so, how much 99Tc would be released from the weathering of the monolith waste form? The results from the long term stability leach test results confirm that the resin is not releasing a significant amount of the sequestered 99Tc, evident by the less than 0.02% of the total 99Tc loaded being identified in the solution. Furthermore, it is possible that the measured 99Tc concentration is the result of 99Tc contained in the pore spaces of the resin. In addition to these results, analyses conducted to examine the impact of hot water on the release of 99Tc suggest that only a small percentage of the total is being released. This suggest that hot water stripping to remove carbon tetrachloride will not have a significant affect on the resins ability to hold-on to sequestered 99Tc. Finally, encapsulation of spent resin in a cementitious material may be a viable disposal option, but additional tests are needed to examine the extent of physical degradation caused by moisture loss and the effect this degradation process can have on the release of 99Tc.

Valenta, Michelle M.; Parker, Kent E.; Pierce, Eric M.

2010-08-01T23:59:59.000Z

35

IEA Energy Technology Data Exchange | Open Energy Information  

Open Energy Info (EERE)

IEA Energy Technology Data Exchange IEA Energy Technology Data Exchange Jump to: navigation, search Tool Summary Name: IEA Energy Technology Data Exchange Agency/Company /Organization: International Energy Agency Sector: Energy Topics: Technology characterizations Resource Type: Dataset Website: www.etde.org/ References: IEA Energy Technology Data Exchange[1] Mission "ETDE's mission is: "To provide governments, industry and the research community in the member countries with access to the widest range of information on energy research, science and technology and to increase dissemination of this information to developing countries."" References ↑ "IEA Energy Technology Data Exchange" Retrieved from "http://en.openei.org/w/index.php?title=IEA_Energy_Technology_Data_Exchange&oldid=32878

36

Building Technologies Office: HVAC Radial Air Bearing Heat Exchanger  

NLE Websites -- All DOE Office Websites (Extended Search)

Radial Air Bearing Radial Air Bearing Heat Exchanger Research Project to someone by E-mail Share Building Technologies Office: HVAC Radial Air Bearing Heat Exchanger Research Project on Facebook Tweet about Building Technologies Office: HVAC Radial Air Bearing Heat Exchanger Research Project on Twitter Bookmark Building Technologies Office: HVAC Radial Air Bearing Heat Exchanger Research Project on Google Bookmark Building Technologies Office: HVAC Radial Air Bearing Heat Exchanger Research Project on Delicious Rank Building Technologies Office: HVAC Radial Air Bearing Heat Exchanger Research Project on Digg Find More places to share Building Technologies Office: HVAC Radial Air Bearing Heat Exchanger Research Project on AddThis.com... About Take Action to Save Energy Partner with DOE

37

Inorganic ion exchange evaluation and design: Silicotitanate ion exchange waste conversion  

SciTech Connect

Ion exchange materials are being evaluated for removing Cs, SR from tank waste. Thermal conversion of a variety of compositions within the Cs{sub 2}O-TiO{sub 2}-SiO{sub 2} phase diagram yielded both glass and crystalline materials, some of which show low leach rates and negligible Cs losses during heat treatment. A new material, CsTiSi{sub 2}0{sub 6}, with a structure isomorphous to pollucite (CsAlSi{sub 2}0{sub 6}) has been identified. This material represents a new class of crystalline zeolite materials which contain large amounts of titanium. Direct conversion of Cs loaded silicotitanate ion exchangers to CsTiSi{sub 2}O{sub 6} is an excellent alternative to dissolving the Cs-loaded or Cs-eluted exchangers in borosilicate glass because: CsTiSi{sub 2}O{sub 6} is formed using a simple, one step heat treatment. The unique crystalline pollucite-like structure of CsTiSi{sub 2}O{sub 6} traps Cs, and exhibits extremely low Cs leach rates. CsTiSi{sub 2}O{sub 6} is converted to solid waste at a low processing temperature of 700 to 800 C (nominal melter operating temperatures are 1150 C). CsTiSi{sub 2}0{sub 6} concentrates the waste, thus generating lower volumes of expensive HLW. Cs losses due to volatilization during processing of CsTiSi{sub 2}O{sub 6} are extremely low.

Balmer, M.L.; Bunker, B.C.

1995-03-01T23:59:59.000Z

38

Desalination of brackish waters using ion-exchange media  

SciTech Connect

An environmentally friendly method and materials study for desalinating inland brackish waters (i.e., coal bed methane produced waters) using a set of ion-exchange materials is presented. This desalination process effectively removes anions and cations in separate steps with minimal caustic waste generation. The anion-exchange material, hydrotalcite (HTC), exhibits an ion-exchange capacity (IEC) of around 3 mequiv g{sup -1}. The cation-exchange material, an amorphous aluminosilicate permutite-like material, (Na{sub x}+2yAl{sub x}Si{sub 1}-xO{sub 2+y}), has an IEC of around to 2.5 mequiv g{sup -1}. These ion-exchange materials were studied and optimized because of their specific ion-exchange capacity for the ions of interest and their ability to function in the temperature and pH regions necessary for cost and energy effectiveness. Room temperature, minimum pressure column studies (once-pass through) on simulant brackish water (total dissolved solids (TDS) = 2222 ppm) resulted in water containing TDS = 25 ppm. A second once-pass through column study on actual produced water (TDS = similar to 11 000) with a high carbonate concentration used an additional lime softening step and resulted in a decreased TDS of 600 ppm.

Pless, J.D.; Philips, M.L.F.; Voigt, J.A.; Moore, D.; Axness, M.; Krumhansl, J.L.; Nenoff, T.M. [Sandia National Labs., Albuquerque, NM (United States)

2006-06-21T23:59:59.000Z

39

Desalination of brackish waters using ion exchange media.  

SciTech Connect

An environmentally friendly method and materials study for desalinating inland brackish waters (i.e., coal bed methane produced waters) using a set of ion-exchange materials is presented. This desalination process effectively removes anions and cations in separate steps with minimal caustic waste generation. The anion-exchange material, hydrotalcite (HTC), exhibits an ion-exchange capacity (IEC) of {approx} 3 mequiv g{sup -1}. The cation-exchange material, an amorphous aluminosilicate permutite-like material, (Na{sub x+2y}Al{sub x}Si{sub 1-x}O{sub 2+y}), has an IEC of {approx}2.5 mequiv g{sup -1}. These ion-exchange materials were studied and optimized because of their specific ion-exchange capacity for the ions of interest and their ability to function in the temperature and pH regions necessary for cost and energy effectiveness. Room temperature, minimum pressure column studies (once-pass through) on simulant brackish water (total dissolved solids (TDS) = 2222 ppm) resulted in water containing TDS = 25 ppm. A second once-pass through column study on actual produced water (TDS = {approx}11,000) with a high carbonate concentration used an additional lime softening step and resulted in a decreased TDS of 600 ppm.

Pless, Jason D.; Krumhansl, James Lee; Nenoff, Tina Maria; Voigt, James A.; Phillips, Mark L. F.; Axness, Marlene; Moore, Diana Lynn

2005-01-01T23:59:59.000Z

40

Ion exchange phase transitions in "doped" water--filled channels  

E-Print Network (OSTI)

Ion transport through narrow water--filled channels is impeded by a high electrostatic barrier. The latter originates from the large ratio of the dielectric constants of the water and a surrounding media. We show that ``doping'', i.e. immobile charges attached to the walls of the channel, substantially reduces the barrier. This explains why most of the biological ion channels are ``doped''. We show that at rather generic conditions the channels may undergo ion exchange phase transitions (typically of the first order). Upon such a transition a finite latent concentration of ions may either enter or leave the channel, or be exchanged between the ions of different valences. We discuss possible implications of these transitions for the Ca-vs.-Na selectivity of biological Ca channels. We also show that transport of divalent Ca ions is assisted by their fractionalization into two separate excitations.

J. Zhang; A. Kamenev; B. I. Shklovskii

2005-10-12T23:59:59.000Z

Note: This page contains sample records for the topic "ion exchange technology" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Radiation effects on a zeolite ion exchanger and a pollucite  

SciTech Connect

Cation exchange capacity and selective Cs and Sr ion sorption measurements were found to be too insensitive to detect radiation effects on irradiated Ionsiv-IE-95 zeolite. However, leaching the zeolite while under ..gamma..-irradiation caused a modest increase in the desorption of exchangeable ions. Gamma-irradiation and subsequent leaching of a natural pollucite also slightly enhanced the leachability of this material. The increased desorption of ions from the zeolite and the enhanced leachability of the pollucite are apparently caused by a decrease in pH due to the generation of acidic species during irradiation.

Komarneni, S.; Palau, G.L.; Pillay, K.K.S.

1983-01-01T23:59:59.000Z

42

ION EXCHANGE PERFORMANCE OF TITANOSILICATES, GERMANATES AND CARBON NANOTUBES  

SciTech Connect

This report presents a summary of testing the affinity of titanosilicates (TSP), germanium-substituted titanosilicates (Ge-TSP) and multiwall carbon nanotubes (MWCNT) for lanthanide ions in dilute nitric acid solution. The K-TSP ion exchanger exhibited the highest affinity for lanthanides in dilute nitric acid solutions. The Ge-TSP ion exchanger shows promise as a material with high affinity, but additional tests are needed to confirm the preliminary results. The MWCNT exhibited much lower affinities than the K-TSP in dilute nitric acid solutions. However, the MWCNT are much more chemically stable to concentrated nitric acid solutions and, therefore, may candidates for ion exchange in more concentrated nitric acid solutions. This technical report serves as the deliverable documenting completion of the FY13 research milestone, M4FT-13SR0303061 measure actinide and lanthanide distribution values in nitric acid solutions with sodium and potassium titanosilicate materials.

Alsobrook, A.; Hobbs, D.

2013-04-24T23:59:59.000Z

43

RESORCINOL-FORMALDEHYDE ION EXCHANGE RESIN CHEMISTRY FOR HIGH LEVEL WASTE TREATMENT  

SciTech Connect

A principal goal at the Savannah River Site is to safely dispose of the large volume of liquid nuclear waste held in many storage tanks. In-tank ion exchange technology is being considered for cesium removal using a polymer resin made of resorcinol formaldehyde that has been engineered into microspheres. The waste under study is generally lower in potassium and organic components than Hanford waste; therefore, the resin performance was evaluated with actual dissolved salt waste. The ion exchange performance and resin chemistry results are discussed.

Nash, C.; Duignan, M.

2010-01-14T23:59:59.000Z

44

Ion sources for ion implantation technology (invited)  

SciTech Connect

Ion sources for ion implantation are introduced. The technique is applied not only to large scale integration (LSI) devices but also to flat panel display. For LSI fabrication, ion source scheduled maintenance cycle is most important. For CMOS image sensor devices, metal contamination at implanted wafer is most important. On the other hand, to fabricate miniaturized devices, cluster ion implantation has been proposed to make shallow PN junction. While for power devices such as silicon carbide, aluminum ion is required. For doping processes of LCD fabrication, a large ion source is required. The extraction area is about 150 cm 10 cm, and the beam uniformity is important as well as the total target beam current.

Sakai, Shigeki, E-mail: sakai-shigeki@nissin.co.jp; Hamamoto, Nariaki; Inouchi, Yutaka; Umisedo, Sei; Miyamoto, Naoki [Nissin Ion Equipment co., ltd, 575 Kuze-Tonoshiro-cho Minami-ku, Kyoto 601-8205 (Japan)] [Nissin Ion Equipment co., ltd, 575 Kuze-Tonoshiro-cho Minami-ku, Kyoto 601-8205 (Japan)

2014-02-15T23:59:59.000Z

45

Small-Scale Ion Exchange Removal of Cesium and Technetium from Hanford Tank 241-AN-103  

SciTech Connect

The pretreatment process for BNFL, Inc.'s Hanford River Protection Project is to provide decontaminated low activity waste and concentrated eluate streams for vitrification into low activity and high level waste glass, respectively. The pretreatment includes sludge washing, filtration, precipitation, and ion exchange processes to remove entrained solids, cesium, transuranics, technetium, and strontium. The ion exchange removal of cesium (Cs) and technetium (Tc) ions is accomplished by using SuperLig 644, and 639 resins from IBC Advanced Technologies, American Fork, Utah. The resins were shown to selectively remove cesium and technetium (as pertechnetate), from alkaline salt solutions. The efficiency of ion exchange column loading and elution is a complex function involving feed compositions, equilibrium and kinetic behavior of ion exchange resins, diffusion, and the ionic strength and pH of the aqueous solution. A previous experimental program completed at the Savannah River Technology Center demonstrated the conceptualized flow sheet parameters with a similar Hanford tank sample (241-AW-101). Those experiments included determination of Cs and Tc batch distribution coefficients by SuperLig 644 and 639 resins and demonstration of small-scale column breakthrough and elution. The experimental findings were used in support of preliminary design bases and pretreatment flow sheet development by BNFL, Inc.

Hassan, N.M.

2000-07-27T23:59:59.000Z

46

Ion exchange performance of commercial crystalline silicotitanates for cesium removal  

SciTech Connect

A new class of inorganic ion exchangers called crystalline silicotitanates (CST), invented by researchers at Sandia National Laboratories and Texas A&M University, has been commercialized in a joint Sandia-UOP effort. The original developmental materials exhibited high selectivity for the ion exchange of cesium, strontium, and several other radionuclides from highly alkaline solutions containing molar concentrations of Na{sup +}. The materials also showed excellent chemical and radiation stability. Together, the high selectivity and stability of the CSTs made them excellent candidates for treatment of solutions such as the Hanford tank supernates and other DOE radwastes. Sandia National Laboratories and UOP have teamed under a Cooperative Research and Development Agreement (CRADA) to develop CSTs in the powdered form and in an engineered form suitable for column ion exchange use. A continuous-flow, column ion exchange process is expected to be used to remove Cs and other radionuclides from the Hanford supernatant. The powder material invented by the Sandia and Texas A&M team consists of submicron-size particles. It is not designed for column ion exchange but may be used in other applications.

Braun, R.; Dangieri, T.J.; Fennelly, D.J. [and others

1996-03-01T23:59:59.000Z

47

Ion exchange polymers for anion separations  

DOE Patents (OSTI)

Anion exchange resins including at least two positively charged sites and a well-defined spacing between the positive sites are provided together with a process of removing anions or anionic metal complexes from aqueous solutions by use of such resins. The resins can be substituted poly(vinylpyridine) and substituted polystyrene.

Jarvinen, G.D.; Marsh, S.F.; Bartsch, R.A.

1997-09-23T23:59:59.000Z

48

Ion exchange polymers for anion separations  

DOE Patents (OSTI)

Anion exchange resins including at least two positively charged sites and a ell-defined spacing between the positive sites are provided together with a process of removing anions or anionic metal complexes from aqueous solutions by use of such resins. The resins can be substituted poly(vinylpyridine) and substituted polystyrene.

Jarvinen, Gordon D. (Los Alamos, NM); Marsh, S. Fredric (Los Alamos, NM); Bartsch, Richard A. (Lubbock, TX)

1997-01-01T23:59:59.000Z

49

Microsoft Word - Nano-sized Ion Exchange Particles.docx  

NLE Websites -- All DOE Office Websites (Extended Search)

Reducing Ion Exchange Particles to Nano-Size Shows Big Potential Reducing Ion Exchange Particles to Nano-Size Shows Big Potential AIKEN, S.C. (January 30, 2012) - Sometimes bigger isn't better. Researchers at the U.S. Department of Energy's Savannah River National Laboratory have successfully shown that they can replace useful little particles of monosodium titanate (MST) with even tinier nano-sized particles, making them even more useful for a variety of applications. MST is an ion exchange material used to decontaminate radioactive and industrial wastewater solutions, and has been shown to be an effective way to deliver metals into living cells for some types of medical treatment. Typically, MST, and a modified form known as mMST developed by SRNL and Sandia National Laboratories, are in the form of fine powders, spherically-shaped particles about 1 to 10 microns in diameter

50

Method and solvent composition for regenerating an ion exchange resin  

DOE Patents (OSTI)

A method and composition for removing perchlorate from a highly selective ion exchange resin is disclosed. The disclosed approach comprises treating the resin in a solution of super critical or liquid carbon dioxide and one or more quaternary ammonium chloride surfactant compounds.

Even, William R. (Livermore, CA); Irvin, David J. (Livermore, CA); Irvin, Jennifer A. (Livermore, CA); Tarver, Edward E. (Livermore, CA); Brown, Gilbert M. (Knoxville, TN); Wang, James C. F. (Livermore, CA)

2002-01-01T23:59:59.000Z

51

CO adsorption on ion-exchanged Ru zeolite catalysts  

SciTech Connect

CO adsorption on ion-exchanged Ru zeolite catalysts, studied by IR spectroscopy, revealed the existence of three types of ruthenium which adsorbed the carbon monoxide into three different states. The ruthenium types were atomically or highly dispersed ruthenium, ruthenium clusters which formed ruthenium carbonyl, and larger (> 1 nm) particles, probably on the outer zeolite surfaces.

Goodwin, J.G. (Univ. of Pittsburgh); Naccache, G.

1980-08-01T23:59:59.000Z

52

Copper Removal from A-01 Outfall by Ion Exchange  

SciTech Connect

Chelex100, a commercially available ion exchange resin, has been identified in this study as having a significant affinity for copper and zinc in the A-01 outfall water. Removal of copper and zinc from A-01 outfall water will ensure that the outfall meets the state of South Carolina's limit on these heavy metals.

Oji, L.N.

1999-02-17T23:59:59.000Z

53

Ion Exchange Membrane Cathodes for Scalable Microbial Fuel Cells  

Science Journals Connector (OSTI)

Ion Exchange Membrane Cathodes for Scalable Microbial Fuel Cells ... The optimum amount of graphite fibers needed for these brush electrodes has not yet been optimized, and the cathode remains the greatest challenge for MFC designs. ... Different catalyst locations (inside versus outside) and loadings, specific surface areas, and solution chemistry (solution conductivity) were examined to optimize performance. ...

Yi Zuo; Shaoan Cheng; Bruce E. Logan

2008-08-13T23:59:59.000Z

54

REMOVING RADIUM-226 ION EXCHANGE RESINS  

E-Print Network (OSTI)

. M. R. Collins Department of Civil Engineering - University of New Hampshire Funded by: United States for Radionuclides · 1962 US Public Health Services DWS ­ 3 pCi/L Radium 226 · 1977 USEPA National Interim Prim. DWS Environmental Protection Agency (USEPA) New England Water Treatment Technology Assistance Center (WTTAC

55

Investigating the Use of Ion Exchange Resins for Processing Biodiesel Feedstocks  

E-Print Network (OSTI)

Ion exchange resins, commonly used in water treatment, demonstrate promise for the production of biodiesel from biomass feedstocks. The goal of this presented PhD research is to investigate novel uses of ion exchange resins for processing biodiesel...

Jamal, Yousuf 1973-

2012-11-27T23:59:59.000Z

56

Small-Scale Ion Exchange Removal of Cesium and Technetium from Hanford Tank 241-AN-102  

SciTech Connect

The pretreatment process for BNFL, Inc.'s Hanford River Protection Project is to provide decontaminated low activity waste and concentrated eluate streams for vitrification into low and high activity waste glass, respectively. The pretreatment includes sludge washing, filtration, precipitation, and ion exchange processes to remove entrained solids, cesium, transuranics, technetium, and strontium. The cesium (Cs-137) and technetium (Tc-99) ion exchange removal is accomplished by using SuperLig 644, and 639 resins from IBC Advanced Technologies, American Fork, Utah. The resins were shown to selectively remove cesium and technetium (as anionic pertechnetate ) from alkaline salt solutions. The efficiency of ion exchange column loading and elution is a complex function involving feed compositions, equilibrium and kinetic behavior of ion exchange resins, diffusion, and the ionic strength and pH of the aqueous solution. A previous experimental program completed at the Savannah River Tech nology Center2 demonstrated the conceptualized flow sheet parameters with an Envelope C sample from Hanford Tank 241-AN-107. Those experiments also included determination of Cs and Tc batch distribution coefficients by SuperLig 644 and 639 resins and demonstration of small-scale column breakthrough and elution. The experimental findings were used in support of preliminary design bases and pretreatment flow sheet development by BNFL, Inc.

Hassan, N.M.

2000-07-27T23:59:59.000Z

57

Electrodeposition of microparticles on polarized ion exchange membranes  

SciTech Connect

The use of ion exchange membranes to extract microparticles from an aqueous solution is considered. The efficiency of removing negatively charged aerosil particles depends substantially on the nature of the membrane located at the anode. It has been established that besides an increase in the electric field intensity the principal factor ensuring an increase in the efficiency of purifying a solution by electrodeposition of microparticles on a membrane surface is a reduction in the flowrate relative to the membrane surface.

Verbich, S.V.; Ponomarev, M.I.; Grebenyuk, V.D.; Dukhin, S.S.

1986-11-01T23:59:59.000Z

58

Ion-Exchange Membranes in the Chemical Process Industry  

Science Journals Connector (OSTI)

Other applications of ion-exchange membranes are still in an early state of their development, such as the redox flow battery. ... (40) More recently, interest in electrodialysis as a flow battery has increased and will be briefly discussed in the following. ... One is based on a reversal of regular electrodialysis and is referred to as concentration flow battery,(40) and the other is based on reversal of electrodialysis with bipolar membranes and is referred to as neutralization flow battery. ...

Heiner Strathmann; Andrej Grabowski; Gerhart Eigenberger

2013-03-13T23:59:59.000Z

59

Development and properties of crystalline silicotitanate (CST) ion exchangers for radioactive waste applications  

SciTech Connect

Crystalline silicotitanates (CSTs) are a new class of ion exchangers that were jointly invented by researchers at Sandia National Laboratories and Texas A&M University. One particular CST, known as TAM-5, is remarkable for its ability to separate parts-per-million concentrations of cesium from highly alkaline solutions (pH> 14) containing high sodium concentrations (>5M). It is also highly effective for removing cesium from neutral and acidic solutions, and for removing strontium from basic and neutral solutions. Cesium isotopes are fission products that account for a large portion of the radioactivity in waste streams generated during weapons material production. Tests performed at numerous locations with early lab-scale TAM-5 samples established the material as a leading candidate for treating radioactive waste volumes such as those found at the Hanford site in Washington. Thus Sandia developed a Cooperative Research and Development Agreement (CRADA) partnership with UOP, a world leader in developing, commercializing, and supplying adsorbents and associated process technology to commercialize and further develop the material. CSTs are now commercially available from UOP in a powder (UOP IONSIV{reg_sign} IE-910 ion exchanger) and granular form suitable for column ion exchange operations (UOP IONSIV{reg_sign} IE-911 ion exchanger). These materials exhibit a high capacity for cesium in a wide variety of solutions of interest to the Department of Energy, and they are chemically, thermally, and radiation stable. They have performed well in tests at numerous sites with actual radioactive waste solutions, and are being demonstrated in the 100,000 liter Cesium Removal Demonstration taking place at Oak Ridge National Laboratory with Melton Valley Storage Tank waste. It has been estimated that applying CSTs to the Hanford cleanup alone will result in a savings of more than $300 million over baseline technologies.

Miller, J.E.; Brown, N.E.

1997-04-01T23:59:59.000Z

60

Ion Exchange Testing with SRF Resin FY2012  

SciTech Connect

Ion exchange using spherical resorcinol-formaldehyde (SRF) resin has been selected by the U.S. Department of Energys Office of River Protection (DOE-ORP) for use in the Pretreatment Facility (PTF) of the Hanford Tank Waste Treatment and Immobilization Plant (WTP) and for potential application in at-tank deployment. Numerous studies have shown SRF resin to be effective for removing 137Cs from a wide variety of actual and simulated tank waste supernatants (Adamson et al. 2006; Blanchard et al. 2008; Burgeson et al. 2004; Duignan and Nash 2009; Fiskum et al. 2006a; Fiskum et al. 2006b; Fiskum et al. 2006c; Fiskum et al. 2007; Hassan and Adu-Wusu 2003; King et al. 2004; Nash et al. 2006). Prior work at the Pacific Northwest National Laboratory (PNNL) has focused primarily on the loading behavior for 4 to 6 M Na solutions at 25 to 45C. Recent proposed changes to the WTP ion exchange process baseline indicate that loading may include a broader range of sodium molarities (0.1 to 8 M) and higher temperatures (50C) to alleviate post-filtration precipitation issues. This report discusses ion exchange loading kinetics testing activities performed in accordance with Test Plan TP-WTPSP-002, Rev. 3.0 , which was prepared and approved in response to the Test Specification 24590 PTF-TSP-RT-09-002, Rev. 0 (Lehrman 2010) and Test Exception 24590 PTF TEF RT-11-00003, Rev. 0 (Meehan 2011). This testing focused on column tests evaluating the impact of elevated temperature on resin degradation over an extended period of time and batch contacts evaluating the impact on Cs loading over a broad range of sodium concentrations (0.1 to 5 M). These changes may be required to alleviate post-filtration precipitation issues and broaden the data range of SRF resin loading under the conditions expected with the new equipment and process changes.

Russell, Renee L.; Rinehart, Donald E.; Peterson, Reid A.

2013-06-11T23:59:59.000Z

Note: This page contains sample records for the topic "ion exchange technology" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Ion Exchange Testing with SRF Resin FY 2012  

SciTech Connect

Ion exchange using spherical resorcinol-formaldehyde (SRF) resin has been selected by the U.S. Department of Energys Office of River Protection (DOE-ORP) for use in the Pretreatment Facility (PTF) of the Hanford Tank Waste Treatment and Immobilization Plant (WTP) and for potential application in at-tank deployment. Numerous studies have shown SRF resin to be effective for removing 137Cs from a wide variety of actual and simulated tank waste supernatants (Adamson et al. 2006; Blanchard et al. 2008; Burgeson et al. 2004; Duignan and Nash 2009; Fiskum et al. 2006a; Fiskum et al. 2006b; Fiskum et al. 2006c; Fiskum et al. 2007; Hassan and Adu-Wusu 2003; King et al. 2004; Nash et al. 2006). Prior work at the Pacific Northwest National Laboratory (PNNL) has focused primarily on the loading behavior for 4 to 6 M Na solutions at 25 to 45C. Recent proposed changes to the WTP ion exchange process baseline indicate that loading may include a broader range of sodium molarities (0.1 to 8 M) and higher temperatures (50C) to alleviate post-filtration precipitation issues. This report discusses ion exchange loading kinetics testing activities performed in accordance with Test Plan TP-WTPSP-002, Rev. 3.01, which was prepared and approved in response to the Test Specification 24590-PTF-TSP-RT-09-002, Rev. 0 (Lehrman 2010) and Test Exception 24590-PTF-TEF-RT-11-00003, Rev. 0 (Meehan 2011). This testing focused on column tests evaluating the impact of elevated temperature on resin degradation over an extended period of time and batch contacts evaluating the impact on Cs loading over a broad range of sodium concentrations (0.1 to 5 M). These changes may be required to alleviate post-filtration precipitation issues and broaden the data range of SRF resin loading under the conditions expected with the new equipment and process changes.

Russell, Renee L.; Rinehart, Donald E.; Peterson, Reid A.

2014-07-02T23:59:59.000Z

62

Electrically switched cesium ion exchange. FY 1996 annual report  

SciTech Connect

An electrochemical method for metal ion separations, called Electrically Switched Ion Exchange, is described. Direct oxidation and reduction of an electroactive film attached to an electrode surface is used to load and unload the film with alkali metal cations. The electroactive films under investigation are Ni hexacyanoferrates, which are deposited on the surface by applying an anodic potential to a Ni electrode in a solution containing the ferricyanide anion. Reported film preparation procedures were modified to produce films with improved capacity and stability. Electrochemical behavior of the derivatized electrodes were investigated using cyclic voltammetry and chronocoulometry. The films show selectivity for Cs in concentrated sodium solutions. Raman spectroscopy was used to monitor changes in oxidation state of the film and imaging experiments have demonstrated that the redox reactions are spatially homogenous across the film. Requirements for a bench scale unit were identified.

Lilga, M.A.; Orth, R.J.; Sukamto, J.P.H. [Pacific Northwest National Lab., Richland, WA (United States); Schwartz, D.T.; Haight, S.M. [Washington Univ., Seattle, WA (United States); Genders, D. [Electrosynthesis Co., Inc., Cheektowaga, NY (United States)

1996-12-01T23:59:59.000Z

63

Water softening by single-bowl ion exchange filter efficiency estimate and improvement  

E-Print Network (OSTI)

The article presents results of experimental investigations of the water softener in a laboratory installation of uninterruptible countercurrent ion exchange filter, which has a movable layer of ion exchange material. The installation provides for two simultaneous processes: counter ion sorption and regeneration of the sorbent with the processing capability of the sorbent in the regeneration zone by ultrasonic radiation.

Kostygin, V A; Kochetov, G M; Tugay, A M; Vashchenko, V N

2014-01-01T23:59:59.000Z

64

Ion exchange resins. (Latest citations from the US Patent bibliographic file with exemplary claims). Published Search  

SciTech Connect

The bibliography contains citations concerning preparation, regeneration, and applications of ion exchange resins. Applications include water and waste treatment; food processing; chemical recovery, separation, purification, and catalysis; desalination; and ore treatment and recovery. Methods are included for the processing of spent ion exchange resins and for protecting ion exchange resins from oxidation and chemical degradation. (Contains 250 citations and includes a subject term index and title list.)

Not Available

1994-04-01T23:59:59.000Z

65

Plasma ion sources and ion beam technology inmicrofabrications  

SciTech Connect

For over decades, focused ion beam (FIB) has been playing a very important role in microscale technology and research, among which, semiconductor microfabrication is one of its biggest application area. As the dimensions of IC devices are scaled down, it has shown the need for new ion beam tools and new approaches to the fabrication of small-scale devices. In the meanwhile, nanotechnology has also deeply involved in material science research and bioresearch in recent years. The conventional FIB systems which utilize liquid gallium ion sources to achieve nanometer scale resolution can no longer meet the various requirements raised from such a wide application area such as low contamination, high throughput and so on. The drive towards controlling materials properties at nanometer length scales relies on the availability of efficient tools. In this thesis, three novel ion beam tools have been developed and investigated as the alternatives for the conventional FIB systems in some particular applications. An integrated focused ion beam (FIB) and scanning electron microscope (SEM) system has been developed for direct doping or surface modification. This new instrument employs a mini-RF driven plasma source to generate focused ion beam with various ion species, a FEI two-lens electron (2LE) column for SEM imaging, and a five-axis manipulator system for sample positioning. An all-electrostatic two-lens column has been designed to focus the ion beam extracted from the source. Based on the Munro ion optics simulation, beam spot sizes as small as 100 nm can be achieved at beam energies between 5 to 35 keV if a 5 {micro}m-diameter extraction aperture is used. Smaller beam spot sizes can be obtained with smaller apertures at sacrifice of some beam current. The FEI 2LE column, which utilizes Schottky emission, electrostatic focusing optics, and stacked-disk column construction, can provide high-resolution (as small as 20 nm) imaging capability, with fairly long working distance (25 mm) at 25 keV beam voltage. Such an integrated FIB/SEM dual-beam system will not only improve the accuracy and reproducibility when performing ion beam sculpting and direct implantation processes, but will also enable researchers to perform cross-sectioning, imaging, and analysis with the same tool. A major advantage of this approach is the ability to produce a wide variety of ion species tailored to the application.

Ji, Lili

2007-09-01T23:59:59.000Z

66

Sodalite ion exchange in polyethylene oxide oligomer solvents Gina M. Canfield,a  

E-Print Network (OSTI)

Sodalite ion exchange in polyethylene oxide oligomer solvents Gina M. Canfield,a Michael Bizimisb and rare earth ions. Ethylene oxide-based oligomers (polyethylene glycol, polyethylene glycol methyl ether

Latturner, Susan

67

Electrodialysis-ion exchange for the separation of dissolved salts  

SciTech Connect

The Department of Energy generates and stores a significant quantity of low level, high level, and mixed wastes. As some of the DOE facilities are decontaminated and decommissioned, additional and possibly different forms of wastes will be generated. A significant portion of these wastes are aqueous streams containing acids, bases, and salts, or are wet solids containing inorganic salts. Some of these wastes are quite dilute solutions, whereas others contain large quantities of nitrates either in the form of dissolved salts or acids. Many of the wastes are also contaminated with heavy metals, radioactive products, or organics. Some of these wastes are in storage because a satisfactory treatment and disposal processes have not been developed. This report describes the process of electrodialysis-ion exchange (EDIX) for treating aqueous wastes streams consisting of nitrates, sodium, organics, heavy metals, and radioactive species.

Baroch, C.J.; Grant, P.J.

1995-12-31T23:59:59.000Z

68

Development of an spFRET method to measure structure changes in ion exchange proteins  

E-Print Network (OSTI)

transporter, major facilitator superfamily, membrane transport, membrane transporter, OxlT, single molecule, spFRET, transport protein. Tightly coupled ion exchangers, such as the AE anion exchange systems only take place at an appreciable rate if a suitable substrate ion is bound to the transport site

Novotny, Lukas

69

Ion exchange resins. (Latest citations from the EI Compendex*plus database). Published Search  

SciTech Connect

The bibliography contains citations concerning preparation, properties, and applications of ion exchange resins. Applications include water and waste treatment, chemical recovery, separation, purification, catalysis, desalination, and ore treatment. Regeneration and disposal of ion exchange resins are also covered. (Contains 250 citations and includes a subject term index and title list.)

NONE

1995-01-01T23:59:59.000Z

70

Ion exchange resins. (Latest citations from the EI Compendex*plus database). Published Search  

SciTech Connect

The bibliography contains citations concerning preparation, properties, and applications of ion exchange resins. Applications include water and waste treatment, chemical recovery, separation, purification, catalysis, desalination, and ore treatment. Regeneration and disposal of ion exchange resins are also covered. (Contains 50-250 citations and includes a subject term index and title list.) (Copyright NERAC, Inc. 1995)

NONE

1996-01-01T23:59:59.000Z

71

Ion exchange resins. (Latest citations from the EI Compendex*plus database). Published Search  

SciTech Connect

The bibliography contains citations concerning preparation, properties, and applications of ion exchange resins. Applications include water and waste treatment, chemical recovery, separation, purification, catalysis, desalination, and ore treatment. Regeneration and disposal of ion exchange resins are also covered. (Contains 250 citations and includes a subject term index and title list.)

Not Available

1993-12-01T23:59:59.000Z

72

Ion Exchange Media for Reduction of Liquid Radwaste in Commercial Power Plants  

SciTech Connect

Ion exchange resins currently make up as much as one-half of all radioactive waste generated by commercial nuclear power plants. A major challenge is reduction of the quantity of ion exchange media requiring disposal. Although the amount of spent ion exchange resins disposed has decreased year after year, a new urgency has arisen with the pending closure of a major disposal site in 2008. This paper explores whether ion exchange resins also can be used to potentially reduce radioactive liquid waste volumes and / or limit them to Class A wastes only. Source term reduction and minimization of manpower exposure to radioactivity are other important goals. Specialty ion exchange products may help to achieve source term reduction of certain radionuclides. Some established operations, data, and process concepts are presented to address these critical issues encountered in liquid radwaste management. (authors)

Yarnell, P.A. [Graver Technologies, LLC, Glasgow, DE (United Kingdom); Tavares, A. [Graver Technologies, LLC, Newark, NJ (United States)

2008-07-01T23:59:59.000Z

73

Revised Thermal Analysis of LANL Ion Exchange Column  

SciTech Connect

This document updates a previous calculation of the temperature distributions in a Los Alamos National Laboratory (LANL) ion exchange column.1 LANL operates two laboratory-scale anion exchange columns, in series, to extract Pu-238 from nitric acid solutions. The Defense Nuclear Facilities Safety Board has requested an updated analysis to calculate maximum temperatures for higher resin loading capacities obtained with a new formulation of the Reillex HPQ anion exchange resin. The increased resin loading capacity will not exceed 118 g plutonium per L of resin bed. Calculations were requested for normal operation of the resin bed at the minimum allowable solution feed rate of 30 mL/min and after an interruption of flow at the end of the feed stage, when one of the columns is fully loaded. The object of the analysis is to demonstrate that the decay heat from the Pu-238 will not cause resin bed temperatures to increase to a level where the resin significantly degrades. At low temperatures, resin bed temperatures increase primarily due to decay heat. At {approx}70 C a Low Temperature Exotherm (LTE) resulting from the reaction between 8-12 M HNO{sub 3} and the resin has been observed. The LTE has been attributed to an irreversible oxidation of pendant ethyl benzene groups at the termini of the resin polymer chains by nitric acid. The ethyl benzene groups are converted to benzoic acid moities. The resin can be treated to permanently remove the LTE by heating a resin suspension in 8M HNO{sub 3} for 30-45 minutes. No degradation of the resin performance is observed after the LTE removal treatment. In fact, heating the resin in boiling ({approx}115-120 C) 12 M HNO{sub 3} for 3 hr displays thermal stability analogous to resin that has been treated to remove the LTE. The analysis is based on a previous study of the SRS Frames Waste Recovery (FWR) column, performed in support of the Pu-238 production campaign for NASA's Cassini mission. In that study, temperature transients following an interruption of flow to the column were calculated. The transient calculations were terminated after the maximum resin bed temperature reached the Technical Standard of 60 C, which was set to prevent significant resin degradation. The LANL column differs from the FWR column in that it has a significantly smaller radius, 3.73 cm nominal versus approximately 28 cm. It follows that natural convection removes heat much more effectively from the LANL column, so that the column may reach thermal equilibrium. Consequently, the calculations for a flow interruption were extended until an approach to thermal equilibrium was observed. The LANL ion exchange process also uses a different resin than was used in the FWR column. The LANL column uses Reillex HPQ{trademark} resin, which is more resistant to attack by nitric acid than the Ionac 641{trademark} resin used in the FWR column. Heat generation from the resin oxidation reaction with nitric acid is neglected in this analysis since LANL will be treating the resin to remove the LTE prior to loading the resin in the columns. Calculations were performed using a finite difference computer code, which incorporates models for absorption and elution of plutonium and for forced and natural convection within the resin bed. Calculations for normal column operation during loading were performed using an initial temperature and a feed temperature equal to the ambient air temperature. The model for the normal flow calculations did not include natural convection within the resin bed. The no flow calculations were started with the temperature and concentration profiles at the end of the loading stage, when there would be a maximum amount of plutonium either adsorbed on the resin or in the feed solution in the column.

Laurinat, J

2006-04-11T23:59:59.000Z

74

THERMAL MODELING OF ION EXCHANGE COLUMNS WITH SPHERICAL RF RESIN  

SciTech Connect

Models have been developed to simulate the thermal performance of RF columns fully loaded with radioactive cesium. Temperature distributions and maximum temperatures across the column were calculated during Small Column Ion Exchange (SCIX) process upset conditions with a focus on implementation at Hanford. A two-dimensional computational modeling approach was taken to include conservative, bounding estimates for key parameters such that the results will provide the maximum centerline temperatures achievable under the design configurations using a feed composition known to promote high cesium loading on RF. The current full-scale design for the SCIX system includes a central cooling tube, and one objective of these calculations was to examine its elimination to simplify the design. Results confirmed that a column design without a central cooling tube is feasible for RF, allowing for the possibility of significant design simplifications if it can be assumed that the columns are always filled with liquid. With active cooling through the four outer tubes, the maximum column diameter expected to maintain the temperature below the assumed media and safety limits is 26 inches, which is comparable to the current design diameter. Additional analysis was conducted to predict the maximum column temperatures for the previously unevaluated accident scenario involving inadvertent drainage of liquid from a cesium-saturated column, with retention of the ion exchange media and cesium in the column. As expected, much higher maximum temperatures are observed in this case due to the poor heat transfer properties of air versus liquid. For this hypothetical accident scenario involving inadvertent and complete drainage of liquid from a cesium-saturated column, the modeling results indicate that the maximum temperature within a 28 inch diameter RF column with external cooling is expected to exceed 250 C within 2 days, while the maximum temperature of a 12 inch column is maintained below 100 C. In addition, the calculation results demonstrate that the cooling tube system external to an air-filled column is not highly effective at reducing the maximum temperature, but the baseline design using a central cooling tube inside the column provides sufficient cooling to maintain the maximum temperature near the assumed safety limit.

Lee, S.; King, W.

2009-12-30T23:59:59.000Z

75

DEVELOPMENT OF PROTOTYPE TITANATE ION EXCHANGE LOADED MEMBRANES FOR STRONTIUM, CESIUM AND ACTINIDE DECONTAMINATION FROM AQUEOUS MEDIA  

SciTech Connect

We have successfully incorporated high surface area particles of titanate ion exchange materials (monosodium titanate and crystalline silicotitanate) with acceptable particle size distribution into porous and inert support membrane fibrils consisting of polytetrafluoroethylene (Teflon{reg_sign}), polyethylene and cellulose materials. The resulting membrane sheets, under laboratory conditions, were used to evaluate the removal of surrogate radioactive materials for cesium-137 and strontium-90 from high caustic nuclear waste simulants. These membrane supports met the nominal requirement for nonchemical interaction with the embedded ion exchange materials and were porous enough to allow sufficient liquid flow. Some of this 47-mm size stamped out prototype titanium impregnated ion exchange membrane discs was found to remove more than 96% of dissolved cesium-133 and strontium-88 from a caustic nuclear waste salt simulants. Since in traditional ion exchange based column technology monosodium titanate (MST) is known to have great affinity for the sorbing of other actinides like plutonium, neptunium and even uranium, we expect that the MST-based membranes developed here, although not directly evaluated for uptake of these three actinides because of costs associated with working with actinides which do not have 'true' experimental surrogates, would also show significant affinity for these actinides in aqueous media. It was also observed that crystalline silicotitanate impregnated polytetrafluoroethylene or polyethylene membranes became less selective and sorbed both cesium and strontium from the caustic aqueous salt simulants.

Oji, L; Keisha Martin, K; David Hobbs, D

2008-05-30T23:59:59.000Z

76

Determination of Method Detection Limits for Trace 232-Thorium and 238-Uranium in Copper using Ion Exchange and ICPMS  

SciTech Connect

Determination of Method Detection Limits for Trace 232-Thorium and 238-Uranium in Copper using Ion Exchange and ICPMS

Hoppe, Eric W.; LaFerriere, Brian D.; Maiti, Tapas C.; Soin, Aleksandr

2014-04-15T23:59:59.000Z

77

Enabling Detailed Energy Analyses via the Technology Performance Exchange: Preprint  

SciTech Connect

One of the key tenets to increasing adoption of energy efficiency solutions in the built environment is improving confidence in energy performance. Current industry practices make extensive use of predictive modeling, often via the use of sophisticated hourly or sub-hourly energy simulation programs, to account for site-specific parameters (e.g., climate zone, hours of operation, and space type) and arrive at a performance estimate. While such methods are highly precise, they invariably provide less than ideal accuracy due to a lack of high-quality, foundational energy performance input data. The Technology Performance Exchange was constructed to allow the transparent sharing of foundational, product-specific energy performance data, and leverages significant, external engineering efforts and a modular architecture to efficiently identify and codify the minimum information necessary to accurately predict product energy performance. This strongly-typed database resource represents a novel solution to a difficult and established problem. One of the most exciting benefits is the way in which the Technology Performance Exchange's application programming interface has been leveraged to integrate contributed foundational data into the Building Component Library. Via a series of scripts, data is automatically translated and parsed into the Building Component Library in a format that is immediately usable to the energy modeling community. This paper (1) presents a high-level overview of the project drivers and the structure of the Technology Performance Exchange; (2) offers a detailed examination of how technologies are incorporated and translated into powerful energy modeling code snippets; and (3) examines several benefits of this robust workflow.

Studer, D.; Fleming, K.; Lee, E.; Livingood, W.

2014-08-01T23:59:59.000Z

78

Journal of Membrane Science 239 (2004) 1726 Highly conductive ordered heterogeneous ion-exchange membranes  

E-Print Network (OSTI)

in the matrix required for reasonable ion transport through the membrane is 50­70 wt.% [2Journal of Membrane Science 239 (2004) 17­26 Highly conductive ordered heterogeneous ion-exchange membranes are used in electrodialysis (ED) as ion-selective membranes and in power sources (such as fuel

Freger, Viatcheslav "Slava"

79

Engineering embedded metal nanoparticles with ion beam technology  

Science Journals Connector (OSTI)

In this paper, we summarize our recent results of study on how to engineer the embedded metal nanoparticles in silica by ion implantation and ion irradiation technologies, including controlling the size,...

Feng Ren; Xiang Heng Xiao; Guang Xu Cai; Jian Bo Wang

2009-08-01T23:59:59.000Z

80

Liquid Salt Heat Exchanger Technology for VHTR Based Applications  

SciTech Connect

The objective of this research is to evaluate performance of liquid salt fluids for use as a heat carrier for transferring high-temperature process heat from the very high-temperature reactor (VHTR) to chemical process plants. Currently, helium is being considered as the heat transfer fluid; however, the tube size requirements and the power associated with pumping helium may not be economical. Recent work on liquid salts has shown tremendous potential to transport high-temperature heat efficiently at low pressures over long distances. This project has two broad objectives: To investigate the compatibility of Incoloy 617 and coated and uncoated SiC ceramic composite with MgCl2-KCl molten salt to determine component lifetimes and aid in the design of heat exchangers and piping; and, To conduct the necessary research on the development of metallic and ceramic heat exchangers, which are needed for both the helium-to-salt side and salt-to-process side, with the goal of making these heat exchangers technologically viable. The research will consist of three separate tasks. The first task deals with material compatibility issues with liquid salt and the development of techniques for on-line measurement of corrosion products, which can be used to measure material loss in heat exchangers. Researchers will examine static corrosion of candidate materials in specific high-temperature heat transfer salt systems and develop an in situ electrochemical probe to measure metallic species concentrations dissolved in the liquid salt. The second task deals with the design of both the intermediate and process side heat exchanger systems. Researchers will optimize heat exchanger design and study issues related to corrosion, fabrication, and thermal stresses using commercial and in-house codes. The third task focuses integral testing of flowing liquid salts in a heat transfer/materials loop to determine potential issues of using the salts and to capture realistic behavior of the salts in a small scale prototype system. This includes investigations of plugging issues, heat transfer, pressure drop, and the corrosion and erosion of materials in the flowing system.

Mark Anderson; Kumar Sridhara; Todd Allen; Per Peterson

2012-10-11T23:59:59.000Z

Note: This page contains sample records for the topic "ion exchange technology" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Experimental Findings On Minor Actinide And Lanthanide Separations Using Ion Exchange  

SciTech Connect

This project seeks to determine if inorganic or hybrid inorganic ion-exchange materials can be exploited to provide effective americium and curium separations. Specifically, we seek to understand the fundamental structural and chemical factors responsible for the selectivity of the tested ion-exchange materials for actinide and lanthanide ions. During FY13, experimental work focused in the following areas: (1) investigating methods to oxidize americium in dilute nitric acid with subsequent ion-exchange performance measurements of ion exchangers with the oxidized americium and (2) synthesis, characterization and testing of ion-exchange materials. Ion-exchange materials tested included alkali titanates, alkali titanosilicates, carbon nanotubes and group(IV) metal phosphonates. Americium oxidation testing sought to determine the influence that other redox active components may have on the oxidation of Am(III). Experimental findings indicated that Pu(IV) is oxidized to Pu(VI) by peroxydisulfate, but there are no indications that the presence of plutonium affects the rate or extent of americium oxidation at the concentrations of peroxydisulfate being used. Tests also explored the influence of nitrite on the oxidation of Am(III). Given the formation of Am(V) and Am(VI) in the presence of nitrite, it appears that nitrite is not a strong deterrent to the oxidation of Am(III), but may be limiting Am(VI) by quickly reducing Am(VI) to Am(V). Interestingly, additional absorbance peaks were observed in the UV-Vis spectra at 524 and 544 nm in both nitric acid and perchloric acid solutions when the peroxydisulfate was added as a solution. These peaks have not been previously observed and do not correspond to the expected peak locations for oxidized americium in solution. Additional studies are in progress to identify these unknown peaks. Three titanosilicate ion exchangers were synthesized using a microwave-accelerated reaction system (MARS?) and determined to have high affinities for lanthanide ions in dilute nitric acid. The K-TSP ion exchanger exhibited the highest affinity for lanthanides in dilute nitric acid solutions. The Ge-TSP ion exchanger shows promise as a material with high affinity, but additional tests are needed to confirm the preliminary results. On the other hand, carbon nanotubes and nitrogen-doped carbon nanotubes exhibited low, but measureable affinities for lanthanide ions in dilute nitric acid solutions (pH 3 and 6). The MWCNT exhibited much lower affinities than the K-TSP in dilute nitric acid solutions. However, the MWCNT are much more chemically stable in concentrated nitric acid solutions and, therefore, may be candidates for ion exchange in more concentrated nitric acid solutions.

Hobbs, D. T.; Shehee, T. C.; Clearfield, A.

2013-09-17T23:59:59.000Z

82

MODELING AN ION EXCHANGE PROCESS FOR CESIUM REMOVAL FROM ALKALINE RADIOACTIVE WASTE SOLUTIONS  

SciTech Connect

The performance of spherical Resorcinol-Formaldehyde ion-exchange resin for the removal of cesium from alkaline radioactive waste solutions has been investigated through computer modeling. Cesium adsorption isotherms were obtained by fitting experimental data using a thermodynamic framework. Results show that ion-exchange is an efficient method for cesium removal from highly alkaline radioactive waste solutions. On average, two 1300 liter columns operating in series are able to treat 690,000 liters of waste with an initial cesium concentration of 0.09 mM in 11 days achieving a decontamination factor of over 50,000. The study also tested the sensitivity of ion-exchange column performance to variations in flow rate, temperature and column dimensions. Modeling results can be used to optimize design of the ion exchange system.

Smith, F; Luther Hamm, L; Sebastian Aleman, S; Johnston Michael, J

2008-08-26T23:59:59.000Z

83

Ion exchange kinetics of cesium for various reaction designs using crystalline silicotitanate, UOP IONSIV IE-911  

E-Print Network (OSTI)

, the major component of CST, slowly dissolved at hydrogen peroxide concentrations greater than 1 M. A simple and novel experimental apparatus for a single-layer ion exchange column was developed to generate experimental data for estimation...

Kim, Sung Hyun

2004-09-30T23:59:59.000Z

84

Radiochemical analysis of the polar agrochemicals validamycin and the metabolite melamine by ion-exchange chromatography  

Science Journals Connector (OSTI)

Suitable analytical methods to determine the radiochemical purity of validamycin and melamine are not described in the literature. High performance ion-exchange chromatography for the detection of underivatize...

A. Fredenhagen

2004-08-01T23:59:59.000Z

85

High Level Waste System Impacts from Small Column Ion Exchange Implementation  

SciTech Connect

The objective of this task is to identify potential waste streams that could be treated with the Small Column Ion Exchange (SCIX) and perform an initial assessment of the impact of doing so on the High-Level Waste (HLW) system. Design of the SCIX system has been performed as a backup technology for decontamination of High-Level Waste (HLW) at the Savannah River Site (SRS). The SCIX consists of three modules which can be placed in risers inside underground HLW storage tanks. The pump and filter module and the ion exchange module are used to filter and decontaminate the aqueous tank wastes for disposition in Saltstone. The ion exchange module contains Crystalline Silicotitanate (CST in its engineered granular form is referred to as IONSIV{reg_sign} IE-911), and is selective for removal of cesium ions. After the IE-911 is loaded with Cs-137, it is removed and the column is refilled with a fresh batch. The grinder module is used to size-reduce the cesium-loaded IE-911 to make it compatible with the sludge vitrification system in the Defense Waste Processing Facility (DWPF). If installed at the SRS, this SCIX would need to operate within the current constraints of the larger HLW storage, retrieval, treatment, and disposal system. Although the equipment has been physically designed to comply with system requirements, there is also a need to identify which waste streams could be treated, how it could be implemented in the tank farms, and when this system could be incorporated into the HLW flowsheet and planning. This document summarizes a preliminary examination of the tentative HLW retrieval plans, facility schedules, decontamination factor targets, and vitrified waste form compatibility, with recommendations for a more detailed study later. The examination was based upon four batches of salt solution from the currently planned disposition pathway to treatment in the SCIX. Because of differences in capabilities between the SRS baseline and SCIX, these four batches were combined into three batches for a total of about 3.2 million gallons of liquid waste. The chemical and radiological composition of these batches was estimated from the SpaceMan Plus{trademark} model using the same data set and assumptions as the baseline plans.

McCabe, D. J.; Hamm, L. L.; Aleman, S. E.; Peeler, D. K.; Herman, C. C.; Edwards, T. B.

2005-08-18T23:59:59.000Z

86

Nanoparticle-crosslinked hydrogels as a class of efficient materials for separation and ion exchange  

E-Print Network (OSTI)

dye from a mixture of cationic and anionic dyes. These ion-exchange properties are driven the gel matrix. A comparison of the nanostructured gel with a typical cation-exchange resin (polystyrene the shrinking property of NIPA gels when heated. Additionally, we demonstrate the disassembly of Laponite

Raghavan, Srinivasa

87

Equilibrium Model for Ion Exchange Between Multivalent Cations and Zeolite-A in a Molten Salt  

SciTech Connect

A two-site equilibrium model that previously only accommodated monovalent cations has been extended to include divalent and trivalent cations for ion exchange between zeolite-A and molten chloride salts, a process being considered for concentrating nuclear fission products into high level waste forms. Equilibrium constants were determined by fitting the model to equilibrium data sets for ion exchange between zeolite-A and Cs ternary salt (CsCl-LiCl-KCl), Rb ternary salt (RbCl-LiCl-KCl), Na ternary salt (NaCl-LiCl-KCl), Sr ternary salt (SrCl2-LiCl-KCl), and U ternary salt (UCl3-LiCl-KCl). The results reveal a good fit between the experimental data sets and the model. The two ion exchange sites, framework sites and occluded sites, demonstrate different relative selectivities for the cations. It was found that Sr2_ is the preferred cation in the ion exchange site, and Cs_ is the preferred cation in the occlusion site. Meanwhile, Li_ has the highest combined selectivity when both ion exchange and occlusion sites are considered. Interestingly, divalent and trivalent species are more preferred in the ion exchange site than the monovalent species with the exception of Li_.

Supathorn Phongikaroon; Michael Simpson

2005-10-01T23:59:59.000Z

88

Ion-exchange material and method of storing radioactive wastes  

DOE Patents (OSTI)

A new cation exchanger is a modified tobermorite containing aluminum isomorphously substituted for silicon and containing sodium or potassium. The exchanger is selective for lead, rubidium, cobalt, and cadmium and is selective for cesium over calcium or sodium. The tobermorites are compatible with cement and are useful for the long-term fixation and storage of radioactive nuclear wastes.

Komarneni, S.; Roy, D.M.

1983-10-31T23:59:59.000Z

89

Quantifying exchange coupling in f-ion pairs using the diamagnetic substitution method  

SciTech Connect

One of the challenges in the chemistry of actinide and lanthanide (f-ion) is quantifying exchange coupling between f-ions. While qualitative information about exchange coupling may be readily obtained using the diamagnetic substitution approach, obtaining quantitative information is much more difficult. This article describes how exchange coupling may be quantified using the susceptibility of a magnetically isolated analog, as in the diamagnetic substitution approach, along with the anisotropy of the ground state as determined by EPR spectroscopy. Several examples are used to illustrate and test this approach.

Lukens, Wayne W.; Walter, Marc D.

2010-04-01T23:59:59.000Z

90

Advanced Heat/Mass Exchanger Technology for Geothermal and solar Renewable Energy Systems  

Energy.gov (U.S. Department of Energy (DOE))

Advanced Heat/Mass Exchanger Technology for Geothermal and solar Renewable Energy Systems presentation at the April 2013 peer review meeting held in Denver, Colorado.

91

Cement waste-form development for ion-exchange resins at the Rocky Flats Plant  

SciTech Connect

This report describes the development of a cement waste form to stabilize ion-exchange resins at Rocky Flats Environmental Technology Site (RFETS). These resins have an elevated potential for ignition due to inadequate wetness and contact with nitrates. The work focused on the preparation and performance evaluation of several Portland cement/resin formulations. The performance standards were chosen to address Waste Isolation Pilot Plant and Environmental Protection Agency Resource Conservation and Recovery Act requirements, compatibility with Rocky Flats equipment, and throughput efficiency. The work was performed with surrogate gel-type Dowex cation- and anion-exchange resins chosen to be representative of the resin inventory at RFETS. Work was initiated with nonactinide resins to establish formulation ranges that would meet performance standards. Results were then verified and refined with actinide-containing resins. The final recommended formulation that passed all performance standards was determined to be a cement/water/resin (C/W/R) wt % ratio of 63/27/10 at a pH of 9 to 12. The recommendations include the acceptable compositional ranges for each component of the C/W/R ratio. Also included in this report are a recommended procedure, an equipment list, and observations/suggestions for implementation at RFETS. In addition, information is included that explains why denitration of the resin is unnecessary for stabilizing its ignitability potential.

Veazey, G.W. [Los Alamos National Labs., NM (United States); Ames, R.L. [Rocky Flats Environmental Technology Site, Golden, CO (United States)

1997-03-01T23:59:59.000Z

92

Ion exchange phase transitions in water-filled channels with charged walls  

Science Journals Connector (OSTI)

Ion transport through narrow water-filled channels is impeded by a high electrostatic barrier. The latter originates from the large ratio of the dielectric constants of the water and the surrounding media. We show that doping, i.e., immobile charges attached to the walls of the channel, substantially reduces the barrier. This explains why most of the biological ion channels are doped. We show that at rather generic conditions the channels may undergo ion exchange phase transitions (typically of the first order). Upon such a transition a finite latent concentration of ions may either enter or leave the channel, or be exchanged between the ions of different valences. We discuss possible implications of these transitions for the Ca-vs-Na selectivity of biological Ca channels. We also show that transport of divalent Ca ions is assisted by their fractionalization into two separate excitations.

J. Zhang; A. Kamenev; B. I. Shklovskii

2006-05-19T23:59:59.000Z

93

Injection Solvent Effect on Peak Height in Ion Exchange HPLC  

Science Journals Connector (OSTI)

......2. To further evaluate the effect of the injection volume only...injection volume were varied. Effect of weak injection solvent There...same eluent ion strength. The effect of eluent ion strength. Figure...nitrate in the mobile phase. 418 ship of the peak height of phenylacetate......

Hyunjoo Kim Lee; Norman E. Hoffman

1992-10-01T23:59:59.000Z

94

Radiolytic effects on ion exchangers during the storage of radioactive wastes  

SciTech Connect

Radiolytic effects on ion exchangers are being recognized as a significant problem in the processing and storage of high-specific-activity radioactive waste forms. Two major literature surveys and a series of scoping experiments conducted during this investigation indicate that radiation decomposition of ion exchange materials has the potential for a variety of undesirable consequences. These include the ready dispersion of adsorbed radionuclides to the environment, corrosion and pressurization of waste canisters, and generation of flammable and explosive gases, as well as agglomeration of ion exchangers to a rigid monolith with the partitioning of a liquid phase. Some of the highlights of the literature surveys and the major findings of the experimental studies are reported here.

Pillay, K.K.S.; Palau, G.L.

1982-01-01T23:59:59.000Z

95

A kinetic model for ion exchange between cesium and sodium using silico-titanates  

E-Print Network (OSTI)

over this entire range of pH. This unique characteristic makes the TAMS material desirable. Two other available organic ion exchangers (carboxylic acid based resin and resorcinol formaldehyde resin) show some capability for cesium removal; however... et al. (1947) used this method successfully to predict their data with the phenol-formaldehyde resinous exchanger, Amberlite IR-1. Similarly, Nachod and Wood (1944) and Turse and Rieman (1961) found their data fitted quite well on both zeolites...

Nguyen, Luan Thanh

1994-01-01T23:59:59.000Z

96

Denitration of Rocky Flats Ion-Exchange Resins: Recommendation of Denitration Processes, October 19, 1995  

SciTech Connect

Resin denitration via anion-exchange is an implementable process that can effectively mitigate the hazards associated with stored resins in which the bulk of the nitrate consists of an "exchangeable nitrate" ionically bound to the cationic sites of the anion-exchange resins. Salicylate has been selected as the exchange anion of choice because of its superior selectivity for the Rocky Flats resins and its unique potential for comprehensive recovery and recycle. This report outlines a single recommended resin denigration procedure that is reasonably independent of the resin composition and the current stored form. This procedure is not optimized but rather seeks to `over-treat' the resins so that a single procedure works for the variety of stored resins. The recommended treatment with sodium salicylate reduces resins by 95-99+% the measured exothermic behavior of the ion-exchange.

Jacob Espinoza; Mary Barr; Wayne Smith

1998-12-01T23:59:59.000Z

97

Nuclear quantum effects in water exchange around lithium and fluoride ions  

E-Print Network (OSTI)

We employ classical and ring polymer molecular dynamics simulations to study the effect of nuclear quantum fluctuations on the structure and the water exchange dynamics of aqueous solutions of lithium and fluoride ions. While we obtain reasonably good agreement with experimental data for solutions of lithium by augmenting the Coulombic interactions between the ion and the water molecules with a standard Lennard-Jones ion-oxygen potential, the same is not true for solutions of fluoride, for which we find that a potential with a softer repulsive wall gives much better agreement. A small degree of destabilization of the first hydration shell is found in quantum simulations of both ions when compared with classical simulations, with the shell becoming less sharply defined and the mean residence time of the water molecules in the shell decreasing. In line with these modest differences, we find that the mechanisms of the exchange processes are unaffected by quantization, so a classical description of these reaction...

Wilkins, David M; Dang, Liem X

2015-01-01T23:59:59.000Z

98

Evaluation of Selective Ion Exchange Resins for Removal of Mercury from the H-Area Water Treatment Unit  

SciTech Connect

This study investigated the ability of seven ion exchange (IX) resins, some of which were mercury specific, to remove mercury in H-Area WTU waters from three sources (Reverse Osmosis (RO) Feed, RO Permeate from Train A, and a mercury ''hot spot'' extraction well HEX 18). Seven ion exchange resins, including ResinTech CG8 and Dowex 21K (the cation and anion exchange resins currently used at the H-Area WTU) were screened against five alternative ion exchange materials plus an experimental blank. Mercury decontamination factors (DFs), mercury breakthrough, and post-test contaminant concentrations of IX resins were determined for each IX material tested.

Serkiz, S.M.

2000-09-05T23:59:59.000Z

99

Removing Radium-226 Contamination From Ion Exchange Resins Used in Drinking Water Treatment  

E-Print Network (OSTI)

Removing Radium-226 Contamination From Ion Exchange Resins Used in Drinking Water Treatment P r o b of groundwater containing high levels of radium-226 activity (Objective 1) were regenerated with prescribed brine that the concentration of salt in the brine cleaning solution was the most influential factor in the resin regeneration

100

Patterned ion exchange membranes for improved power production in microbial reverse-electrodialysis cells  

E-Print Network (OSTI)

Patterned ion exchange membranes for improved power production in microbial reverse-electrodialysis August 2014 Keywords: Microbial reverse electrodialysis cell Patterned membranes Integrated spacer Internal resistance a b s t r a c t Power production in microbial reverse-electrodialysis cells (MRCs) can

Note: This page contains sample records for the topic "ion exchange technology" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

HIGH ASPECT RATIO ION EXCHANGE RESIN BED - HYDRAULIC RESULTS FOR SPERICAL RESIN BEADS  

SciTech Connect

A principal role of the DOE Savannah River Site is to safely dispose of a large volume of liquid nuclear waste held in many storage tanks. An in-tank ion exchange unit is being considered for cesium removal to accelerate waste processing. This unit is planned to have a relatively high bed height to diameter ratio (10:1). Complicating the design is the need to cool the ion exchange media; therefore, the ion exchange column will have a central cooling core making the flow path annular. To separate cesium from waste the media being considered is made of resorcinol formaldehyde resin deposited on spherical plastic beads and is a substitute for a previously tested resin made of crystalline silicotitanate. This spherical media not only has an advantage of being mechanically robust, but, unlike its predecessor, it is also reusable, that is, loaded cesium can be removed through elution and regeneration. Resin regeneration leads to more efficient operation and less spent resin waste, but its hydraulic performance in the planned ion exchange column was unknown. Moreover, the recycling process of this spherical resorcinol formaldehyde causes its volume to significantly shrink and swell. To determine the spherical media's hydraulic demand a linearly scaled column was designed and tested. The waste simulant used was prototypic of the wastes' viscosity and density. This paper discusses the hydraulic performance of the media that will be used to assist in the design of a full-scale unit.

Duignan, M; Charles Nash, C; Timothy Punch, T

2007-09-27T23:59:59.000Z

102

A new class of non-zeolitic sorbents for air separations: Lithium ion exchanged pillared clays  

SciTech Connect

Zeolites are the only known sorbents that adsorb N{sub 2} selectively over O{sub 2}, and are used for industrial air separation. Pillared clays (PILCs) have a high Broensted acidity (k.e., high proton density). It is found in this study that when the protons are exchanged by alkali metal ions, in particular Li{sup +}, the ion exchanged pillared clays can exhibit a high N{sub 2}/O{sub 2} adsorption selectivity that rivals that of the zeolites. The first result shows a pure-component adsorption ratio of N{sub 2}/O{sub 2} = 3.2 (at 25 C and 1 atm) for Li{sup +}-exchanged PILC. The N{sub 2} capacity, however, is only 20% that of the zeolite, and remains to be improved. A systematic investigation is conducted on the effects of three factors on the N{sub 2}/O{sub 2} selectivity: (1) starting clays (tetrahedral vs octahedral isomorphous substitution and clays with different charge densities), (2) different metal oxides as pillars, and (3) different ion exchange alkali metal cations (Li{sup +}, Na{sup +}, K{sup +}, Rb{sup +}, and Cs{sup +}). The highest N{sub 2}/O{sub 2} selectivities are achieved by using clays with the highest charge densities, metal oxides forming pillars with the narrowest gallery spaces, and ion exchange cations with the smallest ionic radii. Effects by all three factors are qualitatively understood. The high N{sub 2}/O{sub 2} selectivity on the Li{sup +} exchanged PILC is the result of the small ionic radius (and hence high polarizing power) of Li{sup +} and the strong quadrupole moment of the N{sub 2} molecule. Moreover, a technique is developed with which the amount of the exchanged cations can exceed that allowed by the original cation exchange capacity of the clay by using a high pH value in the ion exchange solution.

Cheng, L.S.; Yang, R.T. [State Univ. of New York, Buffalo, NY (United States). Dept. of Chemical Engineering

1995-06-01T23:59:59.000Z

103

Influence of energy exchange of electrons and ions on the long-wavelength thermal instability in magnetized astrophysical objects  

Science Journals Connector (OSTI)

......research-article Papers Influence of energy exchange of electrons and ions...are different and include the energy exchange in thermal equations...Vazquez-Semadeni Gazol 2002; Audit Hennebelle 2005; Stiele, Lesch...does not take into account an energy exchange between species in......

Anatoly K. Nekrasov

2012-01-01T23:59:59.000Z

104

"INTERNATIONAL ENVIRONMENTAL TECHNOLOGY IDENTIFICATION, DEVELOPMENT, DEMONSTRATION, DEPLOYMENT AND EXCHANGE"  

E-Print Network (OSTI)

Energy Technology Laboratory (NETL) in Morgantown, West Virginia. NETL provided both technical and fiscal

Hazen, Terry

105

Nanocomposite reverse electrodialysis (RED) ion-exchange membranes for salinity gradient power generation  

Science Journals Connector (OSTI)

Abstract Despite the important role of ion-exchange membranes (IEMs) in reverse electrodialysis (RED) systems, the current absence of proper ion-exchange membranes delays the sustainable development of the RED process for salinity gradient power generation. This research presents the preparation of a new type of organicinorganic nanocomposite cation exchange membrane and its performance characteristics. The combination of functionalized iron (III) oxide ( Fe 2 O 3 - SO 4 2 ? ) as an inorganic filler with the sulfonated poly (2,6-dimethyl-1,4-phenylene oxide) (sPPO) polymer matrix proved to have great potential for power generation by RED. The results showed that an optimal amount of Fe 2 O 3 - SO 4 2 ? (0.50.7wt%) enhanced the key electrochemical properties of the ion-exchange membranes including a permselectivity up to 87.65% and an area resistance of 0.87?cm2. The nanocomposite membrane containing 0.7wt% ( Fe 2 O 3 - SO 4 2 ? ) achieved a maximum power density (amount of power per unit membrane area) of 1.3Wm?2, which is relatively higher than that of the commercially available CSO (SelemionTM, Japan) membranes. The goal of the present work is to maximize the salinity gradient power generation by developing RED-specific nanocomposite IEMs. The results show the potential of the new design of the nanocomposite \\{IEMs\\} for viable energy generation by RED.

Jin Gi Hong; Yongsheng Chen

2014-01-01T23:59:59.000Z

106

Modelling Mixed Bed Ion Exchange Kinetics for Removal of Trace Levels of Divalent Cations in Ultrapure Water  

SciTech Connect

Ion exchanger resin fluid film mass transfer coefficients and the ionic diffusivities from which they are derived are often measured by use of ion exchange resin columns. Such tests, usually run dynamically using short resin beds, are often performed using relatively high (ppm) concentrations of ions to accurately measure output concentrations as a function of flow rate. The testing described herein was performed to determine fluid film ionic diffusivities for cationic concentrations typical of ultrapure water ({le}ppb levels) containing ppm levels of ammonia. Effective ionic diffusivities at these low ionic concentrations and high pHs were needed to complete a computer model (SIMIX) to be used in ion exchange simulations. SIMIX is a generalized multicomponent ion exchange model designed to simulate the removal of divalent cations from ultrapure water.

B. Widman

2003-01-01T23:59:59.000Z

107

Vehicle Technologies Office Merit Review 2014: Daikin Advanced Lithium Ion Battery Technology High Voltage Electrolyte  

Energy.gov (U.S. Department of Energy (DOE))

Presentation given by Daikin America at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about Daikin advanced lithium ion...

108

Charge-exchange recombination spectroscopy of the plasma ion temperature at the T-10 tokamak  

SciTech Connect

Charge-exchange recombination spectroscopy (CXRS) based on a diagnostic neutral beam has been developed at the T-10 tokamak. The diagnostics allows one to measure the ion temperature profile in the cross section of the plasma column. In T-10 experiments, the measurement technique was adjusted and the elements of the CXRS diagnostics for ITER were tested. The used spectroscopic equipment makes it possible to reliably determine the ion temperature from the Doppler broadening of impurity lines (helium, carbon), as well as of the spectral lines of the working gas. The profiles of the plasma ion temperature in deuterium and helium discharges were measured at different plasma currents and densities, including with the use of active Doppler measurements of lines of different elements. The validity and reliability of ion temperature measurements performed by means of the developed CXRS diagnostics are analyzed.

Krupin, V. A., E-mail: vkrupin@nfi.kiae.ru [National Research Centre Kurchatov Institute (Russian Federation); Tugarinov, S. N. [Project Center ITER (Russian Federation)] [Project Center ITER (Russian Federation); Barsukov, A. G.; Dnestrovskij, A. Yu.; Klyuchnikov, L. A.; Korobov, K. V.; Krasnyanskii, S. A. [National Research Centre Kurchatov Institute (Russian Federation)] [National Research Centre Kurchatov Institute (Russian Federation); Naumenko, N. N. [National Academy of Sciences of Belarus, Stepanov Institute of Physics (Belarus)] [National Academy of Sciences of Belarus, Stepanov Institute of Physics (Belarus); Nemets, A. R.; Sushkov, A. V.; Tilinin, G. N. [National Research Centre Kurchatov Institute (Russian Federation)] [National Research Centre Kurchatov Institute (Russian Federation)

2013-08-15T23:59:59.000Z

109

Disease-associated changes in the expression of ion channels, ion receptors, ion exchangers and Ca{sup 2+}-handling proteins in heart hypertrophy  

SciTech Connect

The molecular pathology of cardiac hypertrophy is multifactorial with transcript regulation of ion channels, ion exchangers and Ca{sup 2+}-handling proteins being speculative. We therefore investigated disease-associated changes in gene expression of various ion channels and their receptors as well as ion exchangers, cytoskeletal proteins and Ca{sup 2+}-handling proteins in normotensive and spontaneously hypertensive (SHR) rats. We also compared experimental findings with results from hypertrophic human hearts, previously published (Borlak, J., and Thum, T., 2003. Hallmarks of ion channel gene expression in end-stage heart failure. FASEB J. 17, 1592-1608). We observed significant (P < 0.05) induction in transcript level of ATP-driven ion exchangers (Atp1A1, NCX-1, SERCA2a), ion channels (L-type Ca{sup 2+}-channel, K{sub ir}3.4, Na{sub v}1.5) and RyR-2 in hypertrophic hearts, while gene expression was repressed in diseased human hearts. Further, the genes coding for calreticulin and calmodulin, PMCA 1 and 4 as well as {alpha}-skeletal actin were significantly (P < 0.05) changed in hypertrophic human heart, but were unchanged in hypertrophic left ventricles of the rat heart. Notably, transcript level of {alpha}- and {beta}-MHC, calsequestrin, K{sub ir}6.1 (in the right ventricle only), phospholamban as well as troponin T were repressed in both diseased human and rat hearts. Our study enabled an identification of disease-associated candidate genes. Their regulation is likely to be the result of an imbalance between pressure load/stretch force and vascular tonus and the observed changes may provide a rational for the rhythm disturbances observed in patients with cardiac hypertrophy.

Zwadlo, Carolin [Fraunhofer Institute of Toxicology and Experimental Medicine, Center for Drug Research and Medical Biotechnology, Hannover (Germany); Borlak, Juergen [Fraunhofer Institute of Toxicology and Experimental Medicine, Center for Drug Research and Medical Biotechnology, Hannover (Germany)]. E-mail: borlak@item.fraunhofer.de

2005-09-15T23:59:59.000Z

110

A photodiode-based neutral particle bolometer for characterizing charge-exchanged fast-ion behavior  

SciTech Connect

A neutral particle bolometer (NPB) has been designed and implemented on Tri Alpha Energy's C-2 device in order to spatially and temporally resolve the charge-exchange losses of fast-ion populations originating from neutral beam injection into field-reversed configuration plasmas. This instrument employs a silicon photodiode as the detection device with an integrated tungsten filter coating to reduce sensitivity to light radiation. Here we discuss the technical aspects and calibration of the NPB, and report typical NPB measurement results of wall recycling effects on fast-ion losses.

Clary, R.; Smirnov, A.; Dettrick, S.; Knapp, K.; Korepanov, S.; Ruskov, E. [Tri Alpha Energy, Inc., Rancho Santa Margarita, California 92688 (United States); Heidbrink, W. W.; Zhu, Y. [University of California-Irvine, Irvine, California 92697 (United States)

2012-10-15T23:59:59.000Z

111

Radioactive wastewater treatment using a mixture of TANNIX sorbent and VARION mixed bed ion exchange resin  

Science Journals Connector (OSTI)

A wastewater treatment system has been developed by using a mixture of ammonium-insoluble tannin (TANNIX, this is the trademark of an adsorbent made by Mitsubishi Nuclear Fuel Co. Ltd) and mixed (strong acid cation exchanger and strong base anion exchanger) ion exchange resin (MIX) for the selective separation of transuranium isotopes, including Pu, Am, Cm, and U, as well as fission and radioactive corrosion products from boric acid solution (pH ? 4.1). The equilibrium and fixed bed sorption experiments resulted in Kd values of 104??105 ml/g, and decontamination factors of 1,000, with a breakthrough point between 1500 BV and 5000 BV of accumulated volume.

G. Patzay; P. Tilky; J. Schunk; T. Pinter; F. Feil; K. Hamaguchi; L. Weiser

2006-01-01T23:59:59.000Z

112

Membrane permeation process for dehydration of organic liquid mixtures using sulfonated ion-exchange polyalkene membranes  

DOE Patents (OSTI)

A membrane permeation process for dehydrating a mixture of organic liquids, such as alcohols or close boiling, heat sensitive mixtures. The process comprises causing a component of the mixture to selectively sorb into one side of sulfonated ion-exchange polyalkene (e.g., polyethylene) membranes and selectively diffuse or flow therethrough, and then desorbing the component into a gas or liquid phase on the other side of the membranes.

Cabasso, Israel (131 Buckingham Ave., Syracuse, NY 13210); Korngold, Emmanuel (P.O. Box 1025, Beer-Sheva 84110, IL)

1988-01-01T23:59:59.000Z

113

Modification of Malonamide Ion-Exchange/Chelating Resins Using the FieldsKabatschnik Reaction and Their Application to Metal Ion Removal from Aqueous Solutions  

Science Journals Connector (OSTI)

A resin containing 2-aminoethyl-substituted amides of malonic acid was modified in the FieldsKabatschnik reaction using diethyl phosphite. The resultant ion-exchange/chelating resins have aminomethylphosphona...

Andrzej W. Trochimczuk; Julia Jezierska

2000-06-01T23:59:59.000Z

114

The effects of amine additives and flow rate on the performance of mixed-bed ion exchange at ultralow concentrations  

Science Journals Connector (OSTI)

Experimental data were obtained to evaluate the effects of amine additives for pH control of solution and the ... performance of mixed-bed ion exchange for the removal of ionic impurities in solution. The experim...

Byeong Il Noh; Gang Choon Lee; Tae Kyung Yoon

2005-05-01T23:59:59.000Z

115

Metal nanoparticles in catalytic polymer membranes and ion-exchange systems for advanced purification of water from molecular oxygen  

Science Journals Connector (OSTI)

Methods of synthesis of metal nanoparticles and metal/polymer nanocomposites including ion-exchange materials are considered. The effect of the composition and size of nanoparticles on their catalytic activity is analyzed. Attention is focused on the composites used in catalytic processes, namely, catalytic membranes and ion-exchange systems. The problems associated with the removal of dissolved oxygen from water by means of such composites are discussed. The bibliography includes 225 references.

V V Volkov; T A Kravchenko; Vyacheslav I Roldughin

2013-01-01T23:59:59.000Z

116

Investigation of the ion exchange equilibrium between NA+, Ca++, Mg++, and a sulfonated polystyrene resin at various concentrations  

E-Print Network (OSTI)

INVESTIGATiON OF THE ION EXCHANGE EQUILIBRIUM BETWEEN Na , Ca++, Mg++, AND A SULFONATED POLYSTYRENE RESIN AT VARIOUS CONCENTRATIONS A THESIS BY WILLIAM FRANKLIN McILHENNY Submitted to the Graduate School of the Agricultural and Mechanical... College of Texas in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE January 1958 MaJor Subject: Chemical Engineering INVESTIGATION OF THE ION EXCHANGE EQUILIBRIUM BFTWEEN Na+, Ca++ Mg++ AND A SULFONATED POLYSTYRENE RESIN...

McIlhenny, William Franklin

1958-01-01T23:59:59.000Z

117

Measurement of charge exchange cross sections for highly charged xenon and thorium ions with molecular hydrogen in a Penning Ion Trap  

SciTech Connect

Highly charged xenon (35+ to 46+) and thorium (72+ to 79+) ions were produced in an Electron Beam Ion Trap (EBIT). The ions were extracted from EBIT in a short pulse. Ions of one charge state were selected using an electromagnet. The ions were recaptured at low energy in a cryogenic Penning trap (RETRAP). As the ions captured electrons from molecular hydrogen, populations of the various charge states were obtained by measuring the image currents induced by the ions on the electrodes of the trap. Data on the number of ions in each charge state vs. time were compared to theoretical rate equations in order to determine the average charge exchange rates. These rates were compared to charge exchange rates of an ion with a known charge exchange cross section (Ar{sup 11+}) measured in a similar manner in order to determine the average charge exchange cross sections for the highly charged ions. The energy of interaction between the highly charged ions and hydrogen was estimated to be 4 eV in the center of mass frame. The mean charge exchange cross sections were 9 {times} 10{sup {minus}14} cm{sup 2} for Xe{sup 43+} to Xe{sup 46+} and 2 {times} 10{sup {minus}13} cm{sup 2} for Th{sup 73+} to Th{sup 79+}. Double capture was approximately 20--25% of the total for both xenon and thorium. A fit indicated that the cross sections were approximately proportional to q. This is consistent with a linear dependence of cross section on q within the measurement uncertainties.

Weinberg, G.M.

1995-12-01T23:59:59.000Z

118

Perchlorate Degradation Using Partially Oxidized Titanium Ions and Ion Exchange Membrane Hybrid System  

E-Print Network (OSTI)

. To enhance the overall rate of reaction, high concentrations of acid and Ti(III) are needed, but transport of hydrogen ions through the anion permeable membrane was observed and would be greater at higher acid concentrations. The proposed mathematical model...

Park, Sung Hyuk

2011-08-08T23:59:59.000Z

119

Tennessee, Pennsylvania: Porous Power Technologies Improves Lithium Ion Battery, Wins R&D 100 Award  

Office of Energy Efficiency and Renewable Energy (EERE)

Porous Power Technologies, partnered with Oak Ridge National Laboratory (ORNL), developed SYMMETRIX HPX-F, a nanocomposite separator for improved lithium-ion battery technology.

120

ION LASER TECHNOLOGY I L T 5 0 0 0  

E-Print Network (OSTI)

ION LASER TECHNOLOGY I L T 5 0 0 0 OPERATIONS MANUAL REVISION B 45-052 #12;C A U T I O N The use Description 3 mrriAL SET-UP AND OPERATION 6 LASER HEAD CONTROLS EKphnatkm ofFeatiirea ^ 8 POWER SUPPLY mustFatkm 9 I L T 5 0 0 0 Labels 10 SUGGESTIONS TO EXTEND LASER LIFE 11 LASER MIRROR ADJUSTMENT 12 LOCATION

Kleinfeld, David

Note: This page contains sample records for the topic "ion exchange technology" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Modeling Ion-Exchange Processing With Spherical Resins For Cesium Removal  

SciTech Connect

The spherical Resorcinol-Formaldehyde and hypothetical spherical SuperLig(r) 644 ion-exchange resins are evaluated for cesium removal from radioactive waste solutions. Modeling results show that spherical SuperLig(r) 644 reduces column cycling by 50% for high-potassium solutions. Spherical Resorcinol Formaldehyde performs equally well for the lowest-potassium wastes. Less cycling reduces nitric acid usage during resin elution and sodium addition during resin regeneration, therefore, significantly decreasing life-cycle operational costs. A model assessment of the mechanism behind ''cesium bleed'' is also conducted. When a resin bed is eluted, a relatively small amount of cesium remains within resin particles. Cesium can bleed into otherwise decontaminated product in the next loading cycle. The bleed mechanism is shown to be fully isotherm-controlled vs. mass transfer controlled. Knowledge of residual post-elution cesium level and resin isotherm can be utilized to predict rate of cesium bleed in a mostly non-loaded column. Overall, this work demonstrates the versatility of the ion-exchange modeling to study the effects of resin characteristics on processing cycles, rates, and cold chemical consumption. This evaluation justifies further development of a spherical form of the SL644 resin.

Hang, T.; Nash, C. A.; Aleman, S. E.

2012-09-19T23:59:59.000Z

122

Literature Review of Spherical Resorcinol-Formaldehyde for Cesium Ion Exchange  

SciTech Connect

The current report summarizes work performed throughout the scientific community and DOE complex as reported in the open literature and DOE-sponsored reports to evaluate the Cs+ ion exchange (CIX) characteristics of SRF resin. King (2007) completed a similar literature review in support of material selection for the Small Column Ion Exchange (SCIX) project. Josephson et al. (2010) and Sams et al. (2009) provided a similar brief review of SRF CIX for the near-tank Cs+ removal (NTCR) project. Thorson (2008a) documented the basis for recommending SRF over SuperLigTM 644 as the primary CIX resin in the WTP. The current review expands on previous work, summarizes additional work completed to date, and provides a broad view of the literature without focusing on a specific column system. Although the focus of the current review is the SRF resin, many cited references include multiple materials such as the non-spherical GGRF and SuperLigTM 644 organic resins and crystalline silicotitanate (CST) IONSIVTM IE-911, a non-elutable inorganic material. This report summarizes relevant information provided in the literature.

Brown, Garrett N.

2014-09-30T23:59:59.000Z

123

THERMAL ANALYSIS FOR IN-TANK ION-EXCHANGE COLUMN PROCESS  

SciTech Connect

High Level Waste (HLW) at the Savannah River Site (SRS) is stored in three forms: sludge, saltcake, and supernate. A small column ion-exchange (SCIX) process is being designed to treat dissolved saltcake waste before feeding it to the saltstone facility to be made into grout. The waste is caustic with high concentrations of various sodium salts and lower concentrations of radionuclides. Two cation exchange media being considered are a granular form of crystalline silicotitanate (CST) and a spherical form of resorcinol-formaldehyde (RF) resin. CST is an inorganic material highly selective for cesium that is not elutable. Through this process, radioactive cesium from the salt solution is absorbed into ion exchange media (either CST or RF) which is packed within a flow-through column. A packed column loaded with radioactive cesium generates significant heat from radiolytic decay. If engineering designs cannot handle this thermal load, hot spots may develop locally which could degrade the performance of the ion-exchange media. Performance degradation with regard to cesium removal has been observed between 50 and 80 C for CST [1] and at 65 C for RF resin [2]. In addition, the waste supernate solution will boil around 130 C. If the columns boiled dry, the sorbent material could plug the column and lead to replacement of the entire column module. Alternatively, for organic resins such as RF there is risk of fire at elevated temperatures. The objective of the work is to compute temperature distributions across CST- and RF-packed columns immersed in waste supernate under accident scenarios involving loss of salt solution flow through the beds and, in some cases, loss of coolant system flow. For some cases, temperature distributions are determined as a function of time after the initiation of a given accident scenario and in other cases only the final steady-state temperature distributions are calculated. In general, calculations are conducted to ensure conservative and bounding results for the maximum temperatures achievable using the current baseline column design. This information will assist in SCIX design and facility maintenance.

Lee, S; Frank02 Smith, F

2009-01-05T23:59:59.000Z

124

Actinide Separation Science and Technology  

Science Journals Connector (OSTI)

Both the science and technology of the actinides as we know them today owe much to separation science. Conversely, the field of metal ion separations, solvent extraction, and ion exchange in particular, would ...

Kenneth L. Nash; Charles Madic

2011-01-01T23:59:59.000Z

125

Actinide Separation Science and Technology  

Science Journals Connector (OSTI)

Both the science and technology of the actinides as we know them today owe much to separation science. Conversely, the field of metal ion separations, solvent extraction, and ion exchange in particular, would ...

Kenneth L. Nash; Charles Madic

2006-01-01T23:59:59.000Z

126

In situ ion exchange preparation of Pt/carbon nanotubes electrode: Effect of two-step oxidation of carbon nanotubes  

SciTech Connect

Multi-walled carbon nanotubes (MWNTs) supported Pt electrode is prepared by in-situ ion exchange method. X-ray photoelectron spectroscopy (XPS) confirms that compared with the only electrochemical oxidation or chemical oxidation treatment, more carboxylic acid groups are produced on the surface of MWNTs treated by dual-oxidation, which involves both electrochemical oxidation and chemical oxidation. Transmission electron microscopy (TEM) shows that Pt nanoparticles deposited via in-situ ion exchange are highly dispersed on the MWNTs surface. Electrochemical measurements show that the resultant Pt/MWNTs electrode treated by dual-oxidation exhibits the largest electrochemical surface area and the highest activity for oxygen reduction reaction (ORR) among the investigated electrodes. This can be attributed to the fact that dual-oxidation treatment produces more carboxylic acid groups at the electroactive sites on MWNTs surface, which results in loading more Pt nanoparticles in the following ion exchange process.

Zhang, Sheng; Shao, Yuyan; Gao, Yunzhi; Chen, Guangyu; Lin, Yuehe; Yin, Geping

2011-12-01T23:59:59.000Z

127

Influence of earth gravity on reaction engineering of tubular reactor for high concentration tungsten ion-exchange  

Science Journals Connector (OSTI)

The influence of gravity on the reaction engineering of tubular reactor is studied by analyzing the residence time distribution curves. The results show that upflow-feeding mode is more beneficial compared with downflow-feeding mode, since the flow pattern of the fluid in the reactor is closer to plug flow. The result of dynamic experiment conducted in ion-exchange of tungsten metallurgy is as good as that in reaction engineering of ion-exchange column. Whether downflow-feeding or upflow-feeding mode is adopted, breakthrough time decreases when solution concentration increases. Upflow-feeding mode has longer breakthrough time and greater improvement in adsorption capacity especially with high WO3 concentration in ion-exchange.

Zhong-wei ZHAO; Lu-ping XIAO; Chi-hao GUO; Xing-yu CHEN; Ai-liang CHEN; Guang-sheng HUO; Hong-gui LI

2010-01-01T23:59:59.000Z

128

THREE-DIMENSIONAL THERMAL MODELING ANALYSIS OF CST MEDIA FOR THE SMALL ION EXCHANGE PROJECT  

SciTech Connect

The Small Column Ion Exchange (SCIX) project is designed to accelerate closure of High Level Waste (HLW) tanks at the Savannah River Site (SRS). The SRS tanks store HLW in three forms: sludge, saltcake, and supernate. An in-tank ion exchange process is being designed to treat supernate and dissolved saltcake waste. Through this process, radioactive cesium from the salt solution is adsorbed into Crystalline Silicotitanate (CST) ion exchange media packed within a flow-through column. A packed column loaded with radioactive cesium generates significant heat from radiolytic decay. The waste supernate solution within the ion exchange bed will boil around 120 C. Solution superheating above the boiling point within the column could lead to violent hazardous energy releases. System heating from loaded CST is also of concern in other process modules, such as the waste tank. Due to tank structural integrity concerns, the wall temperature limit for the SRS waste tanks is 100 C. The transfer of cesium-loaded CST to the tank could result in localized hot spots on the tank floor and walls which may exceed this limit. As a result, thermal modeling calculations have been conducted to predict the maximum temperatures achievable both in the column and in the waste tank. As specified in the associated Technical Task Plan, one objective of the present work was to compute temperature distributions within the ion exchange column module under accident scenarios including loss of salt solution flow through the bed and loss of coolant system flow. The column modeling domain and the scope of the calculations in this case were broadened relative to previous two-dimensional calculations to include vertical temperature distributions within the packed bed of ion exchange media as well as the upper column plenum region containing only fluid. The baseline design conditions and in-column modeling domain for the ion-exchange column module are shown in Figure 1. These evaluations assumed the maximum bounding cesium loading considered possible based on current knowledge regarding CST media and the anticipated feed compositions. Since this cesium loading was considerably higher than the nominal loading conditions in SRS waste, cases with lower loading were also evaluated. Modeling parameters were the same as those used previously unless otherwise indicated. The current model does not capture multi-phase cooling mechanisms operative when solution boiling occurs. This feature is conservative in the sense that it does not account for the large cooling effects associated with phase transfer. However, the potential transfer of heat to the plenum region associated with vertical bubble ascension through the column during boiling is also neglected. Thermal modeling calculations were also performed for the entire waste storage tank for the case where loaded and ground CST was transferred to the tank. The modeling domain used for the in-tank calculations is provided in Figure 2. The in-tank domain is based on SRS Tank 41, which is a Type-IIIA tank. Temperature distributions were evaluated for cylindrical, ground CST mounds located on the tank floor. Media grinding is required prior to vitrification processing of the CST in the SRS Defense Waste Processing Facility (DWPF). The location of the heat source region on the tank floor due to the accumulation of CST material was assumed to be just under the grinder. The shape of the CST mound was assumed to be cylindrical. This shape is believed to be most representative of the actual mound shape formed in the tank, given that submersible mixing pumps will be available for media dispersion. Alternative configurations involving other geometrical shapes for the CST mound were evaluated in the previous work. Sensitivity analysis for the in-tank region was performed for different amounts of CST media. As was the case for the in-column model, the in-tank model does not include multi-phase cooling mechanisms operative when solution boiling occurs. The in-column and the in-tank evaluations incorporated recently updated maximum cesi

Lee, S.; King, W.

2011-09-12T23:59:59.000Z

129

Li-Ion and Other Advanced Battery Technologies  

NLE Websites -- All DOE Office Websites (Extended Search)

scientist viewing computer screen scientist viewing computer screen Li-Ion and Other Advanced Battery Technologies The research aims to overcome the fundamental chemical and mechanical instabilities that have impeded the development of batteries for vehicles with acceptable range, acceleration, costs, lifetime, and safety. Its aim is to identify and better understand cell performance and lifetime limitations. These batteries have many other applications, in mobile electronic devices, for example. The work addresses synthesis of components into battery cells with determination of failure modes, materials synthesis and evaluation, advanced diagnostics, and improved electrochemical model development. This research involves: Battery development and analysis; Mathematical modeling; Sophisticated diagnostics;

130

Engineering embedded metal nanoparticles with ion beam technology  

E-Print Network (OSTI)

2002) Engineering embedded metal nanoparticles with ion beam3 Engineering embedded metal nanoparticles with ion beamcompara- Engineering embedded metal nanoparticles with ion

Ren, Feng; Xiao, Xiang Heng; Cai, Guang Xu; Wang, Jian Bo; Jiang, Chang Zhong

2009-01-01T23:59:59.000Z

131

REMOVAL OF CESIUM FROM SAVANNAH RIVER SITE WASTE WITH SPHERICAL RESORCINOL FORMALDEHYDE ION EXCHANGE RESIN EXPERIMENTAL TESTS  

SciTech Connect

A principal goal at the Savannah River Site (SRS) is to safely dispose of the large volume of liquid nuclear waste held in many storage tanks. In-tank ion exchange (IX) columns are being considered for cesium removal. The spherical form of resorcinol formaldehyde ion exchange resin (sRF) is being evaluated for decontamination of dissolved saltcake waste at SRS, which is generally lower in potassium and organic components than Hanford waste. The sRF performance with SRS waste was evaluated in two phases: resin batch contacts and IX column testing with both simulated and actual dissolved salt waste. The tests, equipment, and results are discussed.

Duignan, M.; Nash, C.

2010-03-31T23:59:59.000Z

132

Electrodialysis-ion exchange for the separation of dissolved salts. Final report  

SciTech Connect

The program described in this report studies the suitability of electrodialysis-ion exchange (EDIX) to treat aqueous streams containing heavy metals and radioactive cations in a solution containing sodium and nitrates. The goal of the program was to produce a cation stream containing sodium, heavy metals, and radioactive cations; an anion stream of nitric acid free of heavy metals and radioactive cations; and a product stream that meets discharge criteria. The experimental results, described in detail, indicated that EDIX was not a suitable process for treating wastes containing metals that formed insoluble hydroxides in a basic solution; the metals precipitate in the catholyte and feed compartments, and in the cathode membrane. The test program was therefore terminated prior to completion of all planned activities. 2 refs., 22 figs., 8 tabs.

Harrison, J.L.; Baroch, C.J.; Litz, J.

1996-07-19T23:59:59.000Z

133

Nucleon exchange mechanism in heavy-ion collisions at near-barrier energies  

SciTech Connect

Nucleon drift and diffusion mechanisms in central collisions of asymmetric heavy ions at near-barrier energies are investigated in the framework of a stochastic mean-field approach. Expressions for diffusion and drift coefficients for nucleon transfer deduced from the stochastic mean-field approach in the semiclassical approximation have similar forms familiar from the phenomenological nucleon exchange model. The variance of fragment mass distribution agrees with the empirical formula {sigma}{sub AA}{sup 2}(t)=N{sub exc}(t). The comparison with the time-dependent Hartree-Fock calculations shows that below barrier energies, the drift coefficient in the semiclassical approximation underestimates the mean number of nucleon transfer obtained in the quantal framework. Motion of the window in the dinuclear system has a significant effect on the nucleon transfer in asymmetric collisions.

Yilmaz, B. [Physics Department, Ankara University, Tandogan 06100, Ankara (Turkey); Ayik, S. [Physics Department, Tennessee Technological University, Cookeville, Tennessee 38505 (United States); Lacroix, D. [Grand Accelerateur National d'Ions Lourds (GANIL), CEA/DSM-CNRS/IN2P3, BP 55027, F-14076 Caen Cedex 5 (France); Washiyama, K. [PNTPM, CP 229, Universite Libre de Bruxelles, B-1050 Brussels (Belgium)

2011-06-15T23:59:59.000Z

134

Synthesis and Characterization of the Microporosity of Ion-Exchanged Al2O3-Pillared Clays  

Science Journals Connector (OSTI)

Although most PILC studies have focused on their use for catalytic application, there has also been other work in which PILCs have been studied as potential sorbents for gas separation applications. ... We have chosen Al2O3-pillared clay for this study because of the small pore size and interlayer spacing of this material compared with other types of pillared clays (e.g., TiO2-PILC, SiO2-PILC).1 ... The samples and analytical results are identified by the following convention:? the sample Li+?PILC represents Al2O3-pillared clay which has undergone postsynthesis ion exchange with the Li+ cation (in a solution of LiCl as described earlier). ...

Nick D. Hutson; Donald J. Gualdoni; Ralph T. Yang

1998-10-31T23:59:59.000Z

135

Standard practice for The separation of americium from plutonium by ion exchange  

E-Print Network (OSTI)

1.1 This practice describes the use of an ion exchange technique to separate plutonium from solutions containing low concentrations of americium prior to measurement of the 241Am by gamma counting. 1.2 This practice covers the removal of plutonium, but not all the other radioactive isotopes that may interfere in the determination of 241Am. 1.3 This practice can be used when 241Am is to be determined in samples in which the plutonium is in the form of metal, oxide, or other solid provided that the solid is appropriately sampled and dissolved (See Test Methods C758, C759, and C1168). 1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

American Society for Testing and Materials. Philadelphia

2001-01-01T23:59:59.000Z

136

Using Process Knowledge to Manage Disposal Classification of Ion-Exchange Resin - 13566  

SciTech Connect

It has been previously shown by EPRI [1] that Class B and C resins represent a small portion by volume of the overall generation of radioactively contaminated resins. In fact, if all of the resins were taken together the overall classification would meet Class A disposal requirements. Lowering the classification of the ion exchange resins as they are presented for disposal provides a path for minimizing the amount of waste stored. Currently there are commercial options for blending wastes from various generators for Class A disposal in development. The NRC may have by this time introduced changes and clarifications to the Branch Technical Position (BTP) on Concentration Averaging and Encapsulation [2] that may ultimately add more flexibility to what can be done at the plant level. The BTP has always maintained that mixtures of resins that are combined for ALARA purposes or operational efficiency can be classified on the basis of the mixture. This is a point often misinterpreted and misapplied. This paper will address options that can be exercised by the generator that can limit B and C waste generation by more rigorous tracking of generation and taking advantage of the normal mix of wastes. This can be achieved through the monitoring of reactor coolant chemistry data and coupled with our knowledge of radionuclide production mechanisms. This knowledge can be used to determine the overall accumulation of activity in ion-exchange resins and provides a 'real-time' waste classification determination of the resin and thereby provide a mechanism to reduce the production of waste that exceeds class A limits. It should be noted that this alternative approach, although rarely used in a nuclear power plant setting, is acknowledged in the original BTP on classification [3] as a viable option for determining radionuclide inventories for classification of waste. Also included is a discussion of an examination performed at the Byron plant to estimate radionuclide content in the final waste stream from upstream sampling of reactor coolant and fuel pool water. (authors)

Bohnsack, Jonathan N.; James, David W. [DW James Consulting, LLC 855 Village Center Drive No. 330 North Oaks, MN 55127 (United States)] [DW James Consulting, LLC 855 Village Center Drive No. 330 North Oaks, MN 55127 (United States)

2013-07-01T23:59:59.000Z

137

Modelling Zn (II) sorption onto clayey sediments using a multi-site ion-exchange model Tertre E.1,2  

E-Print Network (OSTI)

Modelling Zn (II) sorption onto clayey sediments using a multi-site ion-exchange model Tertre E.1.tertre@univ-poitiers.fr Keywords: ion exchange theory, zinc, clayey sediments, geochemical modelling, sorption and desorption the behaviour of these contaminants and, in particular, the sorption reactions on mineral surfaces. In this way

Paris-Sud XI, Université de

138

Small-Scale Ion Exchange Removal of Cesium and Technetium from Envelope B Hanford Tank 241-AZ-102  

SciTech Connect

The pretreatment process for the Hanford River Protection Project Waste Treatment Plant is to provide decontaminated Low-Activity Waste and concentrated elute streams for vitrification into low- and high-activity waste glass, respectively. The pretreatment includes sludge washing, filtration, precipitation, and ion exchange processes to remove entrained solids, strontium, transuranics, cesium, and technetium.

King, W.D.

2001-02-15T23:59:59.000Z

139

DOI: 10.1002/chem.201002135 High Gas Sorption and Metal-Ion Exchange of Microporous MetalOrganic  

E-Print Network (OSTI)

DOI: 10.1002/chem.201002135 High Gas Sorption and Metal-Ion Exchange of Microporous Metal nanoparticles in the MOF.[1,2f,3] Gas sorption properties also depend on pore volume and ligand structures] but sorption properties for other gases have been less well explored.[6] In addition, the tetracarboxylate

Paik Suh, Myunghyun

140

Cesium removal from liquid acidic wastes with the primary focus on ammonium molybdophosphate as an ion exchanger: A literature review  

SciTech Connect

Many articles have been written concerning the selective removal of cesium from both acidic and alkaline defense wastes. The majority of the work performed for cesium removal from defense wastes involves alkaline feed solutions. Several different techniques for cesium removal from acidic solutions have been evaluated such as precipitation, solvent extraction, and ion exchange. The purpose of this paper is to briefly review various techniques for cesium removal from acidic solutions. The main focus of the review will be on ion exchange techniques, particularly those involving ammonium molybdophosphate as the exchanger. The pertinent literature sources are condensed into a single document for quick reference. The information contained in this document was used as an aid in determining techniques to evaluate cesium removal from the acidic Idaho Chemical Processing Plant waste matrices. 47 refs., 2 tabs.

Miller, C.J.

1995-03-01T23:59:59.000Z

Note: This page contains sample records for the topic "ion exchange technology" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Permeation of ethylene and ethane through sulfonated polysulfones and sulfonated poly(phenylene oxide) ion exchange membranes  

SciTech Connect

Permeation of ethylene and ethane is sulfonated poly(phenylene oxide), sulfonated bisphenol A polyarylethersulfone and sulfonated hexafluorobisphenol A polyarylethersulfone (6F-SPS) exchanged with Ag{sup +} ions were measured as a function of degree of sulfonation, temperature and trans membrane differential pressure. The data were compared with the permeation results for these membranes in acid form and alkaline metal salt form. Membranes exchanged with Ag{sup +} ions displayed enhanced etylene permeability and ethylene-ethane separation factors. The enhancement in transport of ethylene in ion exchange membranes is apparently related to an increase in ethylene solubility affected by complexation of ethylene with immobilized Ag{sup +} ions. A substantial increase in ethylene permeation rate and separation factor was observed when the feed gas was saturated with water vapors. Enhanced permeation/separation were attributed to an increase in the mobility of silver ions in water plasticized membranes. Membranes plasticized with glycerol exhibited high ethylene permeation rate and ethylene/ethane separation factors in dry feed gas streams that were comparable with permeation rates in water plasticized membranes.

Yurkovetsky, A.; Watterson, A. [Univ. of Massachusetts, Lowell, MA (United States); Bikson, B. [Innovative Membrane Systems, Inc., Norwood, MA (United States); Kharas, G.B. [DePaul Univ., Chicago, IL (United States)

1993-12-31T23:59:59.000Z

142

Process for carbonaceous material conversion and recovery of alkali metal catalyst constituents held by ion exchange sites in conversion residue  

DOE Patents (OSTI)

In a coal gasification operation or similar conversion process carried out in the presence of an alkali metal-containing catalyst wherein solid particles containing alkali metal residues are produced, alkali metal constituents are recovered for the particles by contacting or washing them with an aqueous solution containing calcium or magnesium ions in an alkali metal recovery zone at a low temperature, preferably below about 249.degree. F. During the washing or leaching process, the calcium or magnesium ions displace alkali metal ions held by ion exchange sites in the particles thereby liberating the ions and producing an aqueous effluent containing alkali metal constituents. The aqueous effluent from the alkali metal recovery zone is then recycled to the conversion process where the alkali metal constituents serve as at least a portion of the alkali metal constituents which comprise the alkali metal-containing catalyst.

Sharp, David W. (Seabrook, TX)

1980-01-01T23:59:59.000Z

143

Ion Exchange Studies for Removal of Sulfate from Hanford Tank Waste Envelope C (241-AN-107) Using SuperLig 655 Resin  

SciTech Connect

BNFL Inc. is evaluating various pretreatment technologies to mitigate the impacts of sulfate on the LAW vitrification system. One pretreatment technology for separating sulfate from LAW solutions involves the use of SuperLig{reg_sign} 655 (SL-655), a proprietary ion exchange material developed and supplied by IBC Advanced Technologies, Inc., American Fork, UT. This report describes testing of SL-655 with diluted ([Na] {approximately} 5 M) waste from Hanford Tank 241-AN-107 at Battelle, Pacific Northwest Division. Batch contact studies were conducted from 4 to 96 hours to determine the sulfate distribution coefficient and reaction kinetics. A small-scale ion exchange column test was conducted to evaluate sulfate removal, loading, breakthrough, and elution from the SL-655. In all of these tests, an archived 241-AN-107 tank waste sample (pretreated to remove Cs, Sr, and transuranics elements) was used. The experimental details and results are described in this report. Under the test conditions, SL-655 was found to have no significant ion exchange affinity for sulfate in this matrix. The batch contact study resulted in no measurable difference in the aqueous sulfate concentration following resin contact (K{sub d} {approximately} 0). The column test also demonstrated SL-655 had no practical affinity for sulfate in the tested matrix. Within experimental error, the sulfate concentration in the column effluent was equal to the concentration in the feed after passing 3 bed volumes of sample through the columns. Furthermore, some, if not all, of the decreased sulfate concentration in these first three column volumes of effluent can be ascribed to mixing and dilution of the 241-AN-107 feed with the interstitial liquid present in the column at the start of the loading cycle. Finally, ICP-AES measurements on the eluate solutions showed the presence of barium as soon as contact with the feed solution is completed. Barium is a metal not detected in the feed solution. Should the loss of barium be correlated with the resin's ability to selectively complex sulfate, then maintaining even the current limited resin characteristics for sulfate complexation over multiple cycles becomes questionable.

DE Kurath; JR Bontha; DL Blanchard; SK Fiskum; BM Rapko

2000-08-23T23:59:59.000Z

144

E-Print Network 3.0 - adjustment ion exchange Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

- Institut fr Experimentalphysik, Universitt Innsbruck Collection: Physics 14 ION CYCLOTRON HEATING IN A TOROIDAL OC TUPOLE J. D. Barter and J. C. Sprott Summary: ion...

145

New ion exchangers and solvent extractants for pre-analysis separation of actinides. Annual report, June 1982-May 1983  

SciTech Connect

Prior to radiochemical determination of actinide elements such as uranium, neptunium and plutonium, an ion exchange or solvent extraction method is often employed to separate these from themselves and other interfering elements. In order to improve the separation efficiency and reduce time, cost, and liquid waste of analytical separation methods, new and better ion exchangers and solvent extractants are under evaluation. New microreticular and macroreticular anion exchange resins and bifunctional organophosphorus solvent extractants have been evaluated for uranium, neptunium and plutonium separations. Previous work comparing numerous anion exchange resins has shown the macroreticular Amberlite IRA-938 resin as having the highest actinide capacity and best elution kinetics. Recent studies have confirmed the resin has advantages over others for Pu-U separations. Work at Rocky Flats on bifunctional organophosphorus solvent extractants for the recovery and purification of actinides has led to the identification of several new separation systems applicable for radiochemical analysis. Dihexyl-N,N-diethylcarbamoylmethylphosphonate (DHDECMP), its dibutyl analog DBDECMP, and DHDECMP-tributylphosphate (TBP) using liquid-liquid or extraction chromatography techniques are applicable for plutonium-americium and plutonium separations. Both DHDECMP and DBDECMP extract actinides strongly, extract lanthanides, iron, gallium, molybdenum, titanium, vanadium, zirconium partially, and do not extract most other elements from 5 to 7M nitric acid. With the DHDECMP-TBP and DBDECMP-TBP systems, synergistic effects have been observed for both plutonium and americium. The chemistry and application for pre-analysis separations of these solvent extraction systems are described. 11 references, 9 figures, 7 tables.

Navratil, J.D.

1983-06-01T23:59:59.000Z

146

RHEOLOGY OF SETTLED SOLIDS IN THE SMALL COLUMN ION EXCHANGE PROCESS  

SciTech Connect

The Small Column Ion Exchange (SCIX) process is being developed to remove cesium, strontium, and actinides from Savannah River Site (SRS) Liquid Waste using an existing waste tank as process housing. This method includes the addition of monosodium titanate (MST) to a waste tank containing salt solution and entrained sludge solids, followed by tank mixing and filtration. The filtrate is then processed through in-tank ion exchange columns containing crystalline silicotitanate (CST) media. While the process is operating, it is known that solid particles begin to settle in the tank and temperatures may reach beyond 45 C. Previous testing has shown that sludge-MST slurries that sit for extended periods at elevated temperatures can develop large shear strengths, making them difficult to resuspend and remove from the tank. The authors conducted rheological testing of mixtures containing various concentrations of sludge simulant, MST, and CST (three preparations) that were aged at different times (i.e., 0 to 13 weeks) and isothermally maintained to 30, 45, or 60 C. Two types of grinding methodologies were employed to prepare CST for this testing, herein called Savannah River National Laboratory (SRNL) and Vitreous State Laboratory (VSL) ground materials. Unground CST particles were also tested. A small number of samples were irradiated prior to 4 week settling and 60 C temperature treatment, with exposures ranging from 0 to 100 MRad. Additional tests are also being conducted that will allow the solid particles to settle at 45 C for 6, 12, and 24 months. The objectives of this task are to determine the impact of feed composition, settling time, and temperature on the shear strength, yield stress, and consistency of the slurries and to determine the impact of radiation on slurry rheology. The testing will determine the relative impact of these parameters rather than predict the shear strength, yield stress, and consistency as a function of feed and operating conditions. This document describes the rheology of slurries containing MST, CST, and simulated sludge that sat at indicated temperatures for up to 13 weeks. A previous SRNL report described preliminary rheology data of slurries containing MST and sludge. Preliminary results of the irradiation tests are also presented in this report, though additional data are still being collected. Rheology of the long term settling samples (6, 12, and 24 months) and additional irradiation test results will be reported at a later date. Conclusions from this analysis are as follows: (1) Slurries containing MST and unground CST have the largest shear strength. Due to the high shear strengths measured in slurries containing unground CST, evaluations of specific tank contents and mixing capability should be performed prior to any addition of this material into a waste tank. Experimentally determined shear strengths indicate mixing could be problematic in mixtures containing unground CST. (2) Increasing the ground CST fraction in the slurry increases the slurry shear strength, yield stress, and consistency. (3) Increasing the sludge fraction in the slurry decreases the slurry shear strength, yield stress, and consistency. (4) Slurries containing VSL ground CST have larger shear strength, yield stress, and consistency than slurries containing SRNL ground CST. (5) The effects of settling time and temperature on slurry shear strength are slurry dependent. (6) No effects of settling time and temperature on slurry yield stress or consistency were observed. (7) Radiation up to 100 MRad does not appear to affect properties of shear strength, yield stress, or consistency of process feeds.

Ferguson, C.; Prior, M.; Koopman, D.; Edwards, T.

2011-06-20T23:59:59.000Z

147

REAL WASTE TESTING OF SPHERICAL RESORCINOL-FORMALDEHYDE ION EXCHANGE RESIN  

SciTech Connect

This report presents data on batch contact and column testing tasks for spherical resorcinol-formaldehyde (sRF) resin. The testing used a non-radioactive simulant of SRS Tank 2F dissolved salt, as well as an actual radioactive waste sample of similar composition, which are both notably high in sodium (6 M). The resin was Microbeads batch 5E-370/641 which had been made on the hundred gallon scale. Equilibrium batch contact work focused on cesium at a temperature of 25 C due to the lack of such data to better benchmark existing isotherm models. Two campaigns were performed with small-scale ion exchange columns, first with Tank 2F simulant, then with actual dissolved salt in the Shielded Cells. An extrapolation of the batch contact results with radioactive waste over-predicted the cesium loaded onto the IX sRF resin bed by approximately 11%. This difference is not unexpected considering uncertainties from measurement and extrapolation and because the ion exchange that occurs when waste flows through a resin bed probably cannot reach the same level of equilibrium as when waste and resin are joined in a long term batch contact. Resin was also characterized to better understand basic chemistry issues such as holdup of trace transition metals present in the waste feed streams. The column tests involved using two beds of sRF resin in series, with the first bed referred to as the Lead column and the second bed as the Lag column. The test matrix included two complete IX cycles for both the simulant and actual waste phases. A cycle involves cesium adsorption, until the resin in the Lead column reaches saturation, and then regenerating the sRF resin, which includes eluting the cesium. Both the simulated and the actual wastes were treated with two cycles of operation, and the resin beds that were used in the Lead and Lag columns of simulant test phase were regenerated and reused in the actual waste test phase. This task is the first to demonstrate the treatment of SRS waste with sRF resin and the tests clearly demonstrated cesium decontamination for actual waste. The results of the column tests were similar for both the simulated and the actual waste and demonstrated Cs removal with sRF from both wastes. For a flowrate of 1.4 bed volumes (BV)/hour at 25 C those results with sRF resin were: (1) Simulant and actual waste results are equivalent; (2) Cs breakthrough began between 200 and 250 BV; (3) Cs breakthrough reached 100% at around 400 BV; (4) Cs breakthrough curve from 5% to 100% is approximately linear; (5) Cs elution with 0.5 M HNO3 starts at 2 BV and ends at 6BV; (6) Most, if not all, of Cs adsorbed during treatment is released during elution; (7) At 100% breakthrough of Cs the resin bed adsorbs approximately 85% of full capacity before detection in the effluent; the remaining 15% is adsorbed at saturation; (8) Approximately 90% of resin bed changes (color and volume) are complete by 6 BV; and (9) During elution the resin shrinks to about 80% of its fully working (sodium form) BV.

Nash, C.; Duignan, M.

2009-10-30T23:59:59.000Z

148

SCALING SOLID RESUSPENSION AND SORPTION FOR THE SMALL COLUMN ION EXCHANGE PROCESSING TANK  

SciTech Connect

The Small Column Ion Exchange (SCIX) process is being developed to remove cesium, strontium, and actinides from Savannah River Site (SRS) Liquid Waste using an existing 1.3 million gallon waste tank (i.e., Tank 41H) to house the process. Savannah River National Laboratory (SRNL) is conducting pilot-scale mixing tests to determine the pump requirements for suspending and resuspending Monosodium Titanate (MST), Crystalline Silicotitanate (CST), and simulated sludge. In addition, SRNL will also be conducting pilot-scale tests to determine the mixing requirements for the strontium and actinide sorption. As part of this task, the results from the pilot-scale tests must be scaled up to a full-scale waste tank. This document describes the scaling approach. The pilot-scale tank is a 1/10.85 linear scale model of Tank 41H. The tank diameter, tank liquid level, pump nozzle diameter, pump elevation, and cooling coil diameter are all 1/10.85 of their dimensions in Tank 41H. The pump locations correspond to the proposed locations in Tank 41H by the SCIX Program (Risers B5 and B2 for two pump configurations and Risers B5, B3, and B1 for three pump configurations). MST additions are through Riser E1, the proposed MST addition riser in Tank 41H. To determine the approach to scaling the results from the pilot-scale tank to Tank 41H, the authors took the following approach. They reviewed the technical literature for methods to scale mixing with jets and suspension of solid particles with jets, and the technical literature on mass transfer from a liquid to a solid particle to develop approaches to scaling the test data. SRNL assembled a team of internal experts to review the scaling approach and to identify alternative approaches that should be considered.

Poirier, M.; Qureshi, Z.

2010-12-14T23:59:59.000Z

149

Flue gas carbon dioxide sequestration during water softening with ion-exchange fibers  

SciTech Connect

This study examines the use of ion-exchange fibers (IX fibers) to permanently sequester carbon dioxide present in flue gas into an aqueous phase as calcium or magnesium alkalinity while concurrently softening hard water. The only process inputs besides carbon dioxide (or flue gas) are snowmelt (or rainwater); no other chemicals are required for the regeneration of the IX fibers. Importantly, the process is not energy intensive and carbon dioxide does not need to be compressed to excessive pressures (>150 psi) for efficient use. Sources of carbon dioxide do not require concentration and, therefore, the use of raw flue gas (similar to 17% CO{sub 2}) is feasible with the rate of sequestration governed only by the partial pressure of carbon dioxide. While valid for flue gas obtained from any combustion process (e.g., coal, oil, natural gas, etc.), emissions from oil or gas combustion may be more appropriate for use in the described process due to the absence of mercury and particulates. It should also be noted that the presence of sulfur dioxide in flue gas would not adversely affect the process and may even enhance regeneration efficiency. The only product of the proposed process is an environmentally benign regenerant stream containing calcium and/or magnesium alkalinity. The unique property of IX fibers that makes the proposed process both environmentally sustainable and economically feasible is amenability to efficient regeneration with carbon dioxide and harvested snowmelt. Low intraparticle diffusional resistance is the underlying reason why IX fibers are amenable to efficient regeneration using snowmelt sparged with carbon dioxide; 95% calcium recovery was attained at a CO{sub 2} partial pressure of 6.8 atm. The energy balance for a typical electric utility shows that up to 1% of carbon dioxide emitted during combustion would be sequestered in the softening process.

Greenleaf, J.E.; SenGupta, A.K. [Lafayette College, Easton, PA (United States). Dept. of Civil & Environmental Engineering

2009-06-15T23:59:59.000Z

150

The synthesis and characterization of Zirconium p-Phenylbis(phosphonate) Phosphate and other Zirconium Arylbis(phosphonates) for the application of ion exchange  

E-Print Network (OSTI)

. These materials showed promise for many uses, of greatest interest were of catalysis and ion exchange. Zirconium p-Phenylbis(phosphonate) Phosphate was synthesized by several routes to investigate the inherent structural characteristics as they applied...

Bellinghausen, Paul Christian

2012-06-07T23:59:59.000Z

151

Exchange-bias instability in a bilayer with an ion-beam imprinted stripe pattern of ferromagnetic/antiferromagnetic interfaces  

SciTech Connect

We have investigated the magnetization arrangement in an in-plane stripe pattern with alternating exchange-bias domains. The stripe pattern was produced by ion bombardment induced magnetic patterning, which changed locally the exchange-bias direction at the ferromagnet/antiferromagnet interface, but not the magnetic or antiferromagnetic properties of the Co{sub 70}Fe{sub 30} and Mn{sub 83}Ir{sub 17} layers, respectively. For the analysis of the magnetic domain structure evolution along the hysteresis loop we used a combination of experimental techniques: magneto-optical Kerr effect, Kerr microscopy, polarized neutron reflectometry, and off-specular scattering of polarized neutrons with polarization analysis. Instead of a perfect antiparallel alignment we found that the magnetization in neighboring stripes is periodically canted with respect to the stripe axis so that the net magnetization of the ferromagnetic film turns almost perpendicular to the stripes. At the same time the projection of the magnetization vector onto the stripe axis has a periodically alternating sign. The experimental observations are explained and quantitatively described within the frame of a phenomenological model, taking into account interfacial exchange bias, intralayer exchange energy, and uniaxial anisotropy. The model defines conditions which can be used for tailoring nano- and micro-patterned exchange-bias systems with different types of magnetic order.

Theis-Broehl, Katharina; Wolff, Maximilian; Westphalen, Andreas; Zabel, Hartmut; McCord, Jeffrey; Hoeink, Volker; Schmalhorst, Jan; Reiss, Guenther; Weis, Tanja; Engel, Dieter; Ehresmann, Arno; Ruecker, Ulrich; Toperverg, Boris P. [Department of Physics, Ruhr-University Bochum, D-44780 Bochum (Germany); Leibniz Institute for Solid State and Materials Research Dresden, Institute for Metallic Materials, Helmholtzstrasse 20, D-01169 Dresden (Germany); Department of Physics, University Bielefeld, Universitaetsstrasse 25, D-33615 Bielefeld (Germany); Institute of Physics and Centre for Interdisciplinary Nanostructure Science and Technology (CINSaT), University of Kassel, Heinrich-Plett-Strasse 40, D-34132 Kassel (Germany); Institut fuer Festkoerperforschung, Forschungszentrum Juelich GmbH, D-52425 Juelich (Germany); Department of Physics, Ruhr-University Bochum, D-44780 Bochum, Germany, Institut Laue Langevin, Boite Postale 156, Grenoble 38000, France, and Petersburg Nuclear Physics Institute, Gatchina, 188300 St. Petersburg (Russian Federation)

2006-05-01T23:59:59.000Z

152

Enhancement of exchange bias and training effect in ion-beam sputtered Fe{sub 46}Mn{sub 54}/Ni{sub 81}Fe{sub 19} bilayers  

SciTech Connect

We present a remarkable enhancement by 300% of the exchange-bias field at room temperature, without affecting the coercivity value, via optimum magnetic annealing (250?C/3 kOe) in ion-beam sputtered FeMn(30?nm)/NiFe(10?nm) bilayers. This specific behavior has been attributed to a higher degree of ?-FeMn(111) orientation that offers more interfacial FeMn moments to get pinned with the moments of the adjacent NiFe layer. Unlike the absence of training effect at room temperature, a pronounced training effect and an accompanying magnetization reversal asymmetry are evidenced upon field cooling below 50?K due to the presence of biaxial exchange induced anisotropy across the interdiffused FeMn/NiFe interface. The present findings not only have technological significance but also are of relevance to the understanding of interfacial spin disorder and frustration in these exchange-biased systems.

Fulara, Himanshu; Chaudhary, Sujeet, E-mail: sujeetc@physics.iitd.ac.in; Kashyap, Subhash C. [Thin Film Laboratory, Department of Physics, Indian Institute of Technology Delhi, New Delhi 110016 (India); Granville, Simon [Callaghan Innovation, PO Box 31310, Lower Hutt 5040 (New Zealand); The MacDiarmid Institute for Advanced Materials and Nanotechnology, Lower Hutt (New Zealand)

2014-01-28T23:59:59.000Z

153

PILOT SCALE TESTING OF MONOSODIUM TITANATE MIXING FOR THE SRS SMALL COLUMN ION EXCHANGE PROCESS - 11224  

SciTech Connect

The Small Column Ion Exchange (SCIX) process is being developed to remove cesium, strontium, and select actinides from Savannah River Site (SRS) Liquid Waste using an existing waste tank (i.e., Tank 41H) to house the process. Savannah River National Laboratory (SRNL) is conducting pilot-scale mixing tests to determine the pump requirements for suspending monosodium titanate (MST), crystalline silicotitanate (CST), and simulated sludge. The purpose of this pilot scale testing is to determine the requirements for the pumps to suspend the MST particles so that they can contact the strontium and actinides in the liquid and be removed from the tank. The pilot-scale tank is a 1/10.85 linear scaled model of SRS Tank 41H. The tank diameter, tank liquid level, pump nozzle diameter, pump elevation, and cooling coil diameter are all 1/10.85 of their dimensions in Tank 41H. The pump locations correspond to the proposed locations in Tank 41H by the SCIX program (Risers B5 and B2 for two pump configurations and Risers B5, B3, and B1 for three pump configurations). The conclusions from this work follow: (i) Neither two standard slurry pumps nor two quad volute slurry pumps will provide sufficient power to initially suspend MST in an SRS waste tank. (ii) Two Submersible Mixer Pumps (SMPs) will provide sufficient power to initially suspend MST in an SRS waste tank. However, the testing shows the required pump discharge velocity is close to the maximum discharge velocity of the pump (within 12%). (iii) Three SMPs will provide sufficient power to initially suspend MST in an SRS waste tank. The testing shows the required pump discharge velocity is 66% of the maximum discharge velocity of the pump. (iv) Three SMPs are needed to resuspend MST that has settled in a waste tank at nominal 45 C for four weeks. The testing shows the required pump discharge velocity is 77% of the maximum discharge velocity of the pump. Two SMPs are not sufficient to resuspend MST that settled under these conditions.

Poirier, M.; Restivo, M.; Williams, M.; Herman, D.; Steeper, T.

2011-01-25T23:59:59.000Z

154

RHEOLOGY OF SETTLED SOLIDS IN THE SMALL COLUMN ION EXCHANGE PROCESS  

SciTech Connect

The Small Column Ion Exchange (SCIX) process is being developed to remove cesium, strontium, and actinides from Savannah River Site (SRS) Liquid Waste using an existing waste tank (i.e., Tank 41H) to house the process. This process adds monosodium titanate (MST) to a waste tank containing salt solution (and entrained sludge solids). While the process is operating, the solid particles will begin to settle at temperatures up to 45 C. Previous testing has shown that sludge-MST slurries that sit for extended periods (i.e., 1-61 days) at elevated temperatures (i.e., 23-80 C) can develop large shear strengths which could make them difficult to resuspend and remove from the tank. The authors are conducting rheological testing of mixtures containing various concentrations of sludge, MST, and crystalline silicotitanate (CST, ground and unground) that have been aged at different times (i.e., 0 to 13 weeks) and isothermally heated to 30, 45, or 60 C. Additional tests are being conducted that will allow the solid particles to settle at 45 C for 6, 12, and 24 months. The objectives of this task are to determine the impact of settling time and temperature on the shear strength, yield stress, and consistency of the slurries and to determine the impact of radiation on slurry rheology. The testing will determine the relative impact of these parameters rather than predict the shear strength, yield stress, and consistency as a function of feed and operating conditions. This document describes the rheology of slurries containing MST and simulated sludge that sat at elevated temperatures (i.e., up to 60 C) for up to 13 weeks. Rheology of CST-containing slurries, as well as results of the long term settling (6, 12, and 24 months) and irradiation tests (10 and 100 MRad), will be reported later. The conclusions from this analysis follow: (1) MST only slurries that sat at elevated temperatures had larger shear strength, yield stress, and consistency than MST plus sludge slurries that settled at elevated temperatures. (2) The addition of sludge to an MST slurry reduces the shear strength, yield stress, and consistency. (3) The impact of settling time and temperature on slurry rheology is inconclusive at this time. The authors are collecting additional data to attempt to determine the impact of settling time and temperature on slurry shear strength, yield stress, and consistency.

Poirier, M.; Ferguson, C.; Koopman, D.

2011-01-27T23:59:59.000Z

155

Time-dependence ion charge state distributions of vacuum arcs: An interpretation involving atoms and charge exchange collisions  

SciTech Connect

Experimentally observed charge state distributions are known to be higher at the beginning of each arc discharge. Up to know, this has been attributed to cathode surface effects in terms of changes of temperature, chemical composition and spot mode. Here it is shown that the initial decay of charge states of cathodic arc plasmas may at least in part due to charge exchange collisions of ions with neutrals that gradually fill the discharge volume. Sources of neutrals may include evaporated atoms from macroparticles and still-hot craters of previously active arc spots. More importantly, atoms are also produced by energetic condensation of the cathodic arc plasma. Self-sputtering is significant when ions impact with near-normal angle of incidence, and ions have low sticking probability when impacting at oblique angle of incidence. Estimates show that the characteristic time for filling the near-cathode discharge volume agrees well with the charge state decay time, and the likelihood of charge exchange is reasonably large to be taken into account.

Anders, Andre

2004-08-27T23:59:59.000Z

156

Variations in K{sup +}-Na{sup +} ion exchange depth in commercial and experimental float glass compositions  

SciTech Connect

The authors report the results of ion-exchange experiments conducted on 17 commercial soda-lime-silicate (SLS) float glass and 8 experimental SLS glass compositions. A significant variation in the depth of K{sup +} penetration with relatively small changes in composition was observed. The data were fit to a multiple regression model in which the major oxides are the independent variables and depth of K{sup +} is the dependent variable. The model indicates that increased depth of exchange (increased interdiffusion coefficient) correlates predominantly with increased K{sub 2}O and/or Na{sub 2}O content of the glass, with a decreased total alkaline earth content and with the ratio of CaO/MgO.

Sinton, C.W.; LaCourse, W.C.; O'Connell, M.J.

1999-12-01T23:59:59.000Z

157

Continuous alpha-amylase production using Bacillus amyloliquefaciens adsorbed on an ion exchange resin  

Science Journals Connector (OSTI)

A method for the continuous production of extracellular alpha amylase by surface immobilized cells of Bacillus amyloliquefaciens...NRC 2147 has been developed. A large-pore, macroreticular anionic exchange resin ...

Carl A. Groom; Andrew J. Daugulis

1988-03-01T23:59:59.000Z

158

Final purification of synthetic olive oil mill wastewater treated by chemical oxidation using ion exchange: Study of operating parameters  

Science Journals Connector (OSTI)

Abstract In this research work, ion exchange (IE) is presented as a suitable option for purification of olive oil mill wastewater (OMW) previously treated by means of a secondary treatment (OMWST). This pretreatment consisted in Fenton-like oxidation process, followed by coagulationflocculation and filtration through olive stones. The parametric requirements for drinking water production or at least for public waterways discharge were achieved using a combination of two IE columns working in series at bench scale. The IE resins used in this study were Dowex Marathon C and Amberlite IRA-67. The effect of contact time, operating temperature and flow rate on simultaneous removal of sodium, total iron, chloride and phenols (the major pollutant species in OMWST) were investigated. Removal percentages of sodium, chloride and total iron increased with incrementing the contact time. Equilibrium was obtained in about 30min for all ions and ion concentrations values determined were lower than the maximum levels for drinking water standards. On the other hand, adsorption efficiencies of sodium, total iron and chloride ions were found to be not considerably affected by the operating temperature. The highest phenols removal percentage (around 100%) was obtained in the first minutes for 298K and 10L/h.

M.D. Vctor-Ortega; J.M. Ochando-Pulido; G. Hodaifa; A. Martinez-Ferez

2014-01-01T23:59:59.000Z

159

PILOT-SCALE HYDRAULIC TESTING OF RESORCINOL FORMALDEHYDE ION EXCHANGE RESIN  

SciTech Connect

Savannah River National Laboratory (SRNL) performed pilot-scale hydraulic/chemical testing of spherical resorcinol formaldehyde (RF) ion exchange (IX) resin for the River Protection Project Hanford Tank Waste Treatment & Immobilization Plant (WTP) Project. The RF resin cycle testing was conducted in two pilot-scale IX columns, 1/4 and 1/2 scale. A total of twenty-three hydraulic/chemical cycles were successfully completed on the spherical RF resin. Seven of the cycles were completed in the 12-inch IX Column and sixteen cycles were completed in the 24-inch IX Column. Hydraulic testing showed that the permeability of the RF resin remained essentially constant, with no observed trend in the reduction of the permeability as the number of cycles increased. The permeability during the pilot-scale testing was 2 1/2 times better than the design requirements of the WTP full-scale system. The permeability of the resin bed was uniform with respect to changes in bed depth. Upflow Regeneration and Simulant Introduction in the IX columns revealed another RF resin benefit; negligible radial pressures to the column walls from the swelling of resin beads. In downflow of the Regeneration and Simulant Introduction steps, the resin bed particles pack tightly together and produce higher hydraulic pressures than that found in upflow. Also, upflow Simulant Introduction produced an ideal level bed for the twenty cycles completed using upflow Simulant Introduction. Conversely, the three cycles conducted using downflow Simulant Introduction produced an uneven bed surface with erosion around the thermowells. The RF resin bed in both columns showed no tendency to form fissures or pack more densely as the number of cycles increased. Particle size measurements of the RF resin showed no indication of particle size change (for a given chemical) with cycles and essentially no fines formation. Micrographs comparing representative bead samples before and after testing indicated no change in bead morphology. The skeletal density of the RF resin in the 24-inch IX Column increased slightly with cycling (in both hydrogen and sodium form). The chemical solutions used in the pilot-scale testing remained clear throughout testing, indicating very little chemical breakdown of the RF resin beads. The RF resin particles did not break down and produce fines, which would have resulted in higher pressure drops across the resin bed. Three cesium (Cs) loading tests were conducted on the RF resin in pilot-scale IX columns. Laboratory analyses concluded the Cs in the effluent never exceeded the detection limit. Therefore, there was no measurable degradation in cesium removal performance. Using the pilot-scale systems to add the RF resin to the columns and removing the resin from the columns was found to work well. The resin was added and removed from the columns three times with no operational concerns. Whether the resin was in sodium or hydrogen form, the resin flowed well and resulted in an ideal resin bed formation during each Resin Addition. During Resin Removal, 99+ % of the resin was easily sluiced out of the IX column. The hydraulic performance of the spherical RF resin during cycle testing was found to be superior to all other tested IX resins, and SRNL testing indicates that the resin should hold up to many cycles in actual radioactive Cs separation. The RF resin was found to be durable in the long term cycle testing and should result in a cost saving in actual operations when compared to other IX resins.

Adamson, D

2007-01-09T23:59:59.000Z

160

PILOT-SCALE HYDRAULIC TESTING OF RESORCINOL FORMALDEHYDE ION EXCHANGE RESIN  

SciTech Connect

Savannah River National Laboratory (SRNL) performed pilot-scale hydraulic/chemical testing of spherical resorcinol formaldehyde (RF) ion exchange (IX) resin for the River Protection Project-Hanford Tank Waste Treatment & Immobilization Plant (WTP) Project. The RF resin cycle testing was conducted in two pilot-scale IX columns, 1/4 and 1/2 scale. A total of twenty-three hydraulic/chemical cycles were successfully completed on the spherical RF resin. Seven of the cycles were completed in the 12 inch IX Column and sixteen cycles were completed in the 24 inch IX Column. Hydraulic testing showed that the permeability of the RF resin remained essentially constant, with no observed trend in the reduction of the permeability as the number of cycles increased. The permeability during the pilot-scale testing was 2 1/2 times better than the design requirements of the WTP full-scale system. The permeability of the resin bed was uniform with respect to changes in bed depth. Upflow Regeneration and Simulant Introduction in the IX columns revealed another RF resin benefit; negligible radial pressures to the column walls from the swelling of resin beads. In downflow of the Regeneration and Simulant Introduction steps, the resin bed particles pack tightly together and produce higher hydraulic pressures than that found in upflow. Also, upflow Simulant Introduction produced an ideal level bed for the twenty cycles completed using upflow Simulant Introduction. Conversely, the three cycles conducted using downflow Simulant Introduction produced an uneven bed surface with erosion around the thermowells. The RF resin bed in both columns showed no tendency to form fissures or pack more densely as the number of cycles increased. Particle size measurements of the RF resin showed no indication of particle size change (for a given chemical) with cycles and essentially no fines formation. Micrographs comparing representative bead samples before and after testing indicated no change in bead morphology. The skeletal density of the RF resin in the 24 inch IX Column increased slightly with cycling (in both hydrogen and sodium form). The chemical solutions used in the pilot-scale testing remained clear throughout testing, indicating very little chemical breakdown of the RF resin beads. The RF resin particles did not break down and produce fines, which would have resulted in higher pressure drops across the resin bed. Three cesium (Cs) loading tests were conducted on the RF resin in pilot-scale IX columns. Laboratory analyses concluded the Cs in the effluent never exceeded the detection limit. Therefore, there was no measurable degradation in cesium removal performance. Using the pilot-scale systems to add the RF resin to the columns and removing the resin from the columns was found to work well. The resin was added and removed from the columns three times with no operational concerns. Whether the resin was in sodium or hydrogen form, the resin flowed well and resulted in an ideal resin bed formation during each Resin Addition. During Resin Removal, 99+ % of the resin was easily sluiced out of the IX column. The hydraulic performance of the spherical RF resin during cycle testing was found to be superior to all other tested IX resins, and SRNL testing indicates that the resin should hold up to many cycles in actual radioactive Cs separation. The RF resin was found to be durable in the long term cycle testing and should result in a cost saving in actual operations when compared to other IX resins.

Adamson, D

2006-11-08T23:59:59.000Z

Note: This page contains sample records for the topic "ion exchange technology" from the National Library of EnergyBeta (NLEBeta).
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161

IMPACTS OF SMALL COLUMN ION EXCHANGE STREAMS ON DWPF GLASS FORMULATION KT07-SERIES GLASS COMPOSITIONS  

SciTech Connect

This report is the third in a series of studies of the impacts of the addition of Crystalline Silicotitanate (CST) and Monosodium Titanate (MST) from the Small Column Ion Exchange (SCIX) process on the Defense Waste Processing Facility (DWPF) glass waste form and the applicability of the DWPF process control models. MST from the Salt Waste Processing Facility is also considered in the study. The KT07-series glasses were selected to evaluate any potential impacts of noble metals on their properties and performance. The glasses characterized thus far for the SCIX study have not included noble metals since they are not typically tracked in sludge batch composition projections. However, noble metals can act as nucleation sites in glass melts, leading to enhanced crystallization. This crystallization can potentially influence the properties and performance of the glass, such as chemical durability, viscosity, and liquidus temperature. The noble metals Ag, Pd, Rh, and Ru were added to the KT07-series glasses in concentrations based on recent measurements of Sludge Batch 6, which was considered to contain a high concentration of noble metals. The KT04-series glasses were used as the baseline compositions. After fabrication, the glasses were characterized to determine their homogeneity, chemical composition, durability, and viscosity. Liquidus temperature measurements are also underway but were not complete at the time of this report. The liquidus temperature results for the KT07-series glasses, along with several of the earlier glasses in the SCIX study, will be documented separately. All of the KT07-series glasses, both quenched and slowly cooled, were found to be amorphous by X-ray diffraction. Chemical composition measurements showed that all of the glasses met their targeted compositions. The Product Consistency Test (PCT) results showed that all of the glasses had chemical durabilities that were far better than that of the Environmental Assessment benchmark glass. The measured PCT responses were well predicted by the current DWPF Product Composition Control System (PCCS) durability models. The measured viscosity values for each KT07-series glass were acceptable for DWPF processing and were well predicted by the current PCCS model. Overall, the results show that the inclusion of relatively high concentrations of noble metals (in terms of expected values for a DWPF sludge batch) had no significant impact on the properties and performance of these glass compositions. There were no significant differences in the measured properties when compared to those of the KT04-series glasses, which did not contain noble metals. Liquidus temperature measurements are still underway and there may be an impact of the noble metals on those measurements. However, no adverse effects were noted in terms of crystallization after slow cooling. At the completion of these studies, all of the data generated will be reviewed with regard to the applicability of the DWPF PCCS models and recommendations will be made as to whether the validation ranges of the current models can be extended, or whether some or all of the models need to be refit to allow for the incorporation of the SCIX streams. As changes are made to the projected sludge compositions and the volume of the SCIX material, additional evaluations should be performed.

Fox, K.; Edwards, T.

2011-01-12T23:59:59.000Z

162

IMPACT OF SMALL COLUMN ION EXCHANGE STREAMS ON DWPF GLASS FORMULATION MELT RATE STUDIES  

SciTech Connect

This study was undertaken to evaluate the potential impacts of the Small Column Ion Exchange (SCIX) streams - particularly the addition of Monosodium Titanate (MST) and Crystalline Silicotitanate (CST) - on the melt rate of simulated feed for the Defense Waste Processing Facility (DWPF). Additional MST was added to account for contributions from the Salt Waste Processing Facility (SWPF). The Savannah River National Laboratory (SRNL) Melt Rate Furnace (MRF) was used to evaluate four melter feed compositions: two with simulated SCIX and SWPF material and two without. The Slurry-fed Melt Rate Furnace (SMRF) was then used to compare two different feeds: one with and one without bounding concentrations of simulated SCIX and SWPF material. Analyses of the melter feed materials confirmed that they met their targeted compositions. Four feeds were tested in triplicate in the MRF. The linear melt rates were determined by using X-ray computed tomography to measure the height of the glass formed along the bottom of the beakers. The addition of the SCIX and SWPF material reduced the average measured melt rate by about 10% in MRF testing, although there was significant scatter in the data. Two feeds were tested in the SMRF. It was noted that the ground CST alone (ground CST with liquid in a bucket) was extremely difficult to resuspend during preparation of the feed with material from SCIX and SWPF. This feed was also more difficult to pump than the material without MST and CST due to settling occurring in the melter feed line, although the yield stress of both feeds was high relative to the DWPF design basis. Steady state feeding conditions were maintained for about five hours for each feed. There was a reduction in the feed and pour rates of approximately 15% when CST and MST were added to the feed, although there was significant scatter in the data. Analysis of samples collected from the SMRF pour stream showed that the composition of the glass changed as expected when MST and CST were added to the feed. These reductions in melt rate are consistent with previous studies that showed a negative impact of increased TiO{sub 2} concentrations on the rate of melting. The impact of agitating the melt pool via bubbling was not studied as part of this work, but may be of interest for further testing. It is recommended that additional melt rate testing be performed should a potential reduction in melt rate of 10-15% be considered an issue of concern, or should the anticipated composition of the glass with the addition of material from salt waste processing be modified significantly from the current projections, either due to changes in sludge batch preparation or changes in the composition or volume of SCIX and SWPF material.

Fox, K.; Miller, D.; Koopman, D.

2011-04-26T23:59:59.000Z

163

An ion trap built with photonic crystal fibre technology  

E-Print Network (OSTI)

We demonstrate a surface-electrode ion trap fabricated using techniques transferred from the manufacture of photonic-crystal fibres. This provides a relatively straightforward route for realizing traps with an electrode structure on the 100 micron scale with high optical access. We demonstrate the basic functionality of the trap by cooling a single ion to the quantum ground state, allowing us to measure a heating rate from the ground state of 787(24) quanta/s. Variation of the fabrication procedure used here may provide access to traps in this geometry with trap scales between 100 um and 10 um.

Lindenfelser, F; Kienzler, D; Bykov, D; Uebel, P; Schmidt, M A; Russell, P St J; Home, J P

2015-01-01T23:59:59.000Z

164

Method of uranium reclamation from aqueous systems by reactive ion exchange. [US DOE patent application; anion exchange resin of copolymerized divinyl-benzene and styrene having quarternary ammonium groups and bicarbonate ligands  

DOE Patents (OSTI)

A reactive ion exchange method for separation and recovery of values of uranium, neptunium, plutonium, or americium from substantially neutral aqueous systems of said metals comprises contacting said system with an effective amount of a basic anion exchange resin of copolymerized divinyl-benzene and styrene having quarternary ammonium groups and bicarbonate ligands to achieve nearly 100% sorption of said actinyl ion onto said resin and an aqueous system practically free of said actinyl ions. The method is operational over an extensive range of concentrations from about 10/sup -6/ M to 1.0 M actinyl ion and a pH range of about 4 to 7. The method has particulr application to treatment of waste streams from Purex-type nuclear fuel reprocessing facilities and hydrometallurgical processes involving U, Np, P, or Am.

Maya, L.

1981-11-05T23:59:59.000Z

165

Salt-Zeolite Ion Exchange Equilibrium Studies for Complete Set of Fission Products in Molten LiCl-KCl  

SciTech Connect

This paper presents results on LiCl-KCl based molten salts/zeolite-A contact experiments and the associated equilibrium ion exchange model. Experiments examine the contact behaviors of various ternary salts (LiCl-KCl-YCl3, LiCl-KCl-LaCl3, and LiCl-KCl-PrCl3) and quaternary salts (LiCl-KCl-CsCl-NdCl3 and LiCl-KCl-CsCl-SrCl2) with the zeolite-A. The developed equilibrium model assumes that there are ion exchange and occlusion sites, both of which are in equilibrium with the molten salt phase. A systematic approach in estimating total occlusion capacity of the zeolite-A is developed. The parameters of the model, including the total occlusion capacity of the zeolite-A, were determined from fitting experimental data collected via multiple independent studies including the ones reported in this paper. Experiments involving ternary salts were used for estimating the parameters of the model, while those involving quaternary salts were used to validate the model.

Tae-Sic Yoo; Steven M. Frank; Michael F. Simpson; Paula A. Hahn; Terry J. Battisti; Supathorn Phongikaroon

2010-09-01T23:59:59.000Z

166

Sequential separation of actinide elements from highly radioactive Hanford waste by ion exchange methods  

SciTech Connect

A simple, rapid method has been developed for the sequential separation of actinide elements from samples with high salt content such as these resulting from efforts to characterize Hanford storage tank waste. Actinide elements in 9M HC1 solution are introduced into an anion exchange column. U(VI), Np(IV) and Pu(IV) are retained on the column while Am(III) passes through. Plutonium is eluted first, reductively; after which neptunium and then uranium are eluted with mixtures of HC1 and HF. The Am(III) is purified by cation exchange in a nitric acid system. 14 refs., 2 tabs.

Maiti, T.C.; Kaye, J.H.; Kozelisky, A.E.

1991-04-01T23:59:59.000Z

167

PhD position in trapped ion quantum technology and nanoscience at the University of Sussex, Brighton, UK  

E-Print Network (OSTI)

PhD position in trapped ion quantum technology and nanoscience at the University of Sussex a quantum computer with trapped ions. Research in the group focuses on the borderland of nanoscience

Hensinger, Winfried

168

Eco-friendly preparation of 5-hydroxymethylfurfural from sucrose using ion-exchange resins  

Science Journals Connector (OSTI)

Abstract An efficient preparation of 5-hydroxymethylfurfural from sucrose, a renewable resource, is reported herein, following a sequence of four steps catalyzed by reusable cation- and anion-exchange resins: hydrolysis, dehydration, glucose/fructose isomerisation and dehydration. The title compound, a key building block in current industrial chemistry, was isolated in its pure form without chromatographic purification in an overall yield of 50%.

Javier Prez-Maqueda; Irene Arenas-Ligioiz; scar Lpez; Jos G. Fernndez-Bolaos

2014-01-01T23:59:59.000Z

169

Ultra-fast charge exchange spectroscopy for turbulent ion temperature fluctuation measurements on the DIII-D tokamak (invited)  

SciTech Connect

A novel two-channel, high throughput, high efficiency spectrometer system has been developed to measure impurity ion temperature and toroidal velocity fluctuations associated with long-wavelength turbulence and other plasma instabilities. The spectrometer observes the emission of the n= 8-7 hydrogenic transition of C{sup +5} ions ({lambda}{sub air}= 529.06 nm) resulting from charge exchange reactions between deuterium heating beams and intrinsic carbon. Novel features include a large, prism-coupled high-dispersion, volume-phase-holographic transmission grating and high-quantum efficiency, high-gain, low-noise avalanche photodiode detectors that sample emission at 1 MHz. This new diagnostic offers an order-of-magnitude increase in sensitivity compared to earlier ion thermal turbulence measurements. Increased sensitivity is crucial for obtaining enough photon statistics from plasmas with much less impurity content. The irreducible noise floor set by photon statistics sets the ultimate sensitivity to plasma fluctuations. Based on the measured photon flux levels for the entire spectral line, photon noise levels for T(tilde sign){sub i}/T{sub i} and V(tilde sign){sub i}/V{sub i} of {approx}1% are expected, while statistical averaging over long data records enables reduction in the detectable plasma fluctuation levels to values less than that. Broadband ion temperature fluctuations are observed to near 200 kHz in an L-mode discharge. Cross-correlation with the local beam emission spectroscopy measurements demonstrates a strong coupling of the density and temperature fields, and enables the cross-phase measurements between density and ion temperature fluctuations.

Uzun-Kaymak, I. U.; Fonck, R. J.; McKee, G. R. [Department of Engineering Physics, University of Wisconsin, Madison, Wisconsin 53706 (United States)

2012-10-15T23:59:59.000Z

170

Building America Technology Solutions for New and Existing Homes: Foundation Heat Exchanger, Oak Ridge, Tennessee  

Energy.gov (U.S. Department of Energy (DOE))

This case study introduces the foundation heat exchanger that can significantly reduce the cost of the ground source heat pump (GHSP).

171

Investigation of the effect of intra-molecular interactions on the gas-phase conformation of peptides as probed by ion mobility-mass spectrometry, gas-phase hydrogen/deuterium exchange, and molecular mechanics  

E-Print Network (OSTI)

-phase H/D ion molecule reactions that alkali adducted species exchange slower and to a lesser extent than protonated species in the tyrosine- and arginine-containing peptides. Experimental and computational results are discussed in terms of peptide ion...

Sawyer, Holly Ann

2006-04-12T23:59:59.000Z

172

Small Column Ion Exchange Testing of Superlig 644 for Removal of 137Cs from Hanford Tank Waste Envelope C (Tank 241-AN-107)  

SciTech Connect

The current BNFL Inc. flowsheet for the pretreatment of the Hanford high-level tank wastes includes the use of Superlig{reg_sign} materials for removing {sup 137}Cs from the aqueous fraction of the waste. The Superlig materials applicable to cesium removal include the cesium-selective Superlig 632and Superlig 644. These materials have been developed and supplied by IBC Advanced Technologies, Inc., American Fork, Utah. This report describes the testing of the Superlig 644 ion exchange material in a small dual-column system. The bed volume of the lead column was 18.6 mL (L/D = 7), and the bed volume of the lag column was 15.9 mL (L/D = 6) during the loading phase. The sample processed was approximately 1.6 L of diluted waste ([Na{sup +}] = 4.84 M) from Tank 241-AN-107 (Envelope C). This sample had been previously treated for removal of Sr/transuranic (TRU) values and clarified in a single tube cross-flow filtration unit. All ion exchange process steps were tested, including resin-bed preparation, loading, feed displacement, water rinse, elution, eluant rinse, and resin regeneration. A summary of performance measures for both columns is shown in Table S1. The Cs {lambda} values represent a measure of the effective capacity of the SL-644 resin. The Cs {lambda} of 20 for the lead column is much lower than the estimated 150 obtained by the Savannah River Technology Center during Phase 1A testing. Equilibrium data obtained with batch contacts using the AN-107 Cs IX feed predicts a Cs {lambda} of 183. A Cs {lambda} for the lag column could not be determined due to insufficient breakthrough, but it appeared to work well and removed nearly all of the cesium not removed by the lead column. The low value for the lead column indicates that it did not perform as expected. This may have been due to air or gas in the bed that caused fluid channeling or blinding of the resin. The maximum decontamination factor (DF) for {sup 137}Cs listed in Table S1 is based on {sup 137}Cs concentration in the first samples collected from each column and the {sup 137}Cs concentration in the feed. The composite DF for {sup 137}Cs was 1,760, which provided an effluent with a {sup 137}Cs concentration of 8.7E-02 Ci/m{sup 3}. The {sup 137}Cs concentration is below the basis of design limit and is 7.2% of the contract limit for {sup 137}Cs.

DE Kurath; DL Blanchard; JR Bontha

2000-06-28T23:59:59.000Z

173

Fractionation of NaCl, MgCl2, and CaCl2 brines with a polyfunctional ion exchange resin  

E-Print Network (OSTI)

softening, demineralizat1on, or sim1lar processes in which the objective is to remove undesirable 1ons. Ion exchange as a separation technique, that 1s, the recovery of two or more 1ons, has become 1ncreas1ngly important. Mayer and Tompk1ns (12.... Phys. 20, 1657 (1952). 11. McIlhenny, W. F. , M. S. Thesis, Texas A. and M. College (1958). 12 . Mayer, S. W. , Tompkins, E. R. , J. Am. Chem. Soc . 69, 2866 ( 1947) 1$. Nachod, F. C. , Schubert, J. , Ion Exchange Technolo Academic Press, N ew York...

Baker, Albert Byre

1959-01-01T23:59:59.000Z

174

The dehydration of fructose to 5-hydroxymethylfurfural efficiently catalyzed by acidic ion-exchange resin in ionic liquid  

Science Journals Connector (OSTI)

The efficient dehydration of fructose to 5-hydroxymethylfurfural (HMF) was developed in ionic liquids (ILs) with acidic ion-exchange resins as catalyst. By screening different resins and \\{ILs\\} respectively, it was found that the structure of resins and \\{ILs\\} had a prominent effect on the dehydration of fructose. In 1-butyl-3-methylimidazolium chloride ([Bmim]Cl), D001-cc resin showed a high activity. And then the effects of reaction temperatures, dosages of D001-cc, and different initial fructose loadings on the dehydration of fructose were studied in detail. The system of D001-cc resin and [Bmim]Cl exhibited a constant activity at 75C for 20min and a 86.2% yield of HMF was obtained after seven recycles. At 75C for 20min, a 93.0% yield of HMF from the dehydration of fructose was obtained.

Yuan Li; Hui Liu; Changhua Song; Xiaomin Gu; Huaming Li; Wenshuai Zhu; Sheng Yin; Changri Han

2013-01-01T23:59:59.000Z

175

Advances in ion transport membrane technology for Syngas production  

Science Journals Connector (OSTI)

Abstract Ceramic, ion transport membranes for the production of Syngas (ITM Syngas) produce high pressure synthesis gas in a single unit operation from low pressure air and pre-reformed natural gas. Oxygen transport through ITM Syngas membranes occurs through a series of processes, including solid phase oxygen anion diffusion through the dense membrane and surface reactions on the air and reducing sides of the membrane. This paper focuses on the effect of adding porous layers to the syngas side or both sides of the membrane to increase the available surface area for the surface reactions. The highest fluxes are achieved by increasing the surface area on both sides of the membrane, indicating that both surface reactions are a significant resistance to oxygen transport.

C.F. Miller; Jack Chen; M.F. Carolan; E.P. Foster

2014-01-01T23:59:59.000Z

176

Exchange interaction in binuclear complexes with rare-earth and copper ions: A many-body model study  

Science Journals Connector (OSTI)

We have used a many-body model Hamiltonian to study the nature of the magnetic ground state of heterobinuclear complexes involving rare-earth and copper ions. We have taken into account all diagonal repulsions involving the rare-earth 4f and 5d orbitals and the copper 3d orbital. In addition, we have included direct exchange interaction, crystal field splitting of the rare-earth atomic levels and spin-orbit interaction in the 4f orbitals. We have identified the interorbital 4f repulsion Uff and crystal field parameter ?f as the key parameters involved in controlling the type of exchange interaction between the rare earth 4f and copper 3d spins. We have explored the nature of the ground state in the parameter space of Uff, ?f, spin-orbit interaction strength ?, and the 4f filling nf. We find that these systems show low-spin or high-spin ground state depending on the filling of the 4f levels of the rare-earth ion and ground state spin is critically dependent on Uff and ?f. In case of half filling [Gd(III)] we find a reentrant low-spin state as Uff is increased, for small values of ?f, which explains the recently reported apparent anomalous antiferromagnetic behavior of Gd(III)-radical complexes. By varying Uff we also observe a switch over in the ground state spin for other fillings. We have introduced a spin-orbit coupling scheme which goes beyond the L-S or j-j coupling scheme and we find that spin-orbit coupling does not significantly alter the basic picture.

Indranil Rudra; C. Raghu; S. Ramasesha

2002-05-28T23:59:59.000Z

177

Haemocompatibility and ion exchange capability of nanocellulose polypyrrole membranes intended for blood purification  

Science Journals Connector (OSTI)

...highly purified water. The increasing...haemodialysis membranes and dialysis technology that...following groups: small water-soluble compounds...difficult to remove by dialysis. The failure to...during dialysis treatments [1]. However...extraction [11] and electric energy storage...

2012-01-01T23:59:59.000Z

178

Summary - Small Column Ion Exchange (SCIX)Technology at the SRS  

Office of Environmental Management (EM)

in an actinide and Sr osodium titanat olidsliquid sepa ). The objectiv ty of the SCIX ess of the proc n, and to provid g towards deta To view the full E http:www.em.doe....

179

Selective Conversion of D-Fructose to 5-Hydroxymethylfurfural by Ion-Exchange Resin in Acetone/Dimethyl sulfoxide Solvent Mixtures  

Science Journals Connector (OSTI)

Selective Conversion of D-Fructose to 5-Hydroxymethylfurfural by Ion-Exchange Resin in Acetone/Dimethyl sulfoxide Solvent Mixtures ... Catalytic dehydration of D-fructose to 5-Hydroxymethylfurfural (5-HMF) in acetone/dimethyl sulfoxide solvent mixtures was studied in the presence of a strong acidic cation-exchange resin catalyst (DOWEX 50WX8?100) by microwave heating. ... For example, 5-hydroxymethylfurfural (5-HMF), which is used in plastics, pharmaceuticals, and fine chemicals, is presently derived from petrochemicals but could be substituted by its biomass-derived counterpart. ...

Xinhua Qi; Masaru Watanabe; Taku M. Aida; Richard Lee Smith, Jr.

2008-10-31T23:59:59.000Z

180

STRONTIUM AND ACTINIDE SORPTION BY MST AND MMST UNDER CONDITIONS REVELANT TO THE SMALL COLUMN ION-EXCHANGE PROCESS  

SciTech Connect

A series of tests were performed to examine the kinetics of Sr and actinide removal by monosodium titanate (MST) and modified monosodium titanate (mMST) under mixing conditions similar to what will be provided in the Small Column Ion Exchange (SCIX) Program. Similar removal kinetics were seen for two different mixing energies, indicating that under these conditions bulk solution transport is not the rate limiting step for Sr and actinide removal. Sr removal was found to be rapid for both MST and mMST, reaching steady-state conditions within six hours. In contrast, at least six weeks is necessary to reach steady-state conditions for Pu with MST. For mMST, steady-state conditions for Pu were achieved within two weeks. The actual contact time required for the SCIX process will depend on starting sorbate concentrations as well as the requirements for the decontaminated salt solution. During testing leaks occurred in both the MST and mMST tests and evidence of potential desorption was observed. The desorption likely occurred as a result of the change in solids to liquid phase ratio that occurred due to the loss of solution. Based on these results, Savannah River National Laboratory (SRNL) recommended additional testing to further study the effect of changing phase ratios on desorption. This testing is currently in progress and results will be documented in a separate report.

Taylor-Pashow, K.; Hobbs, D.; Poirier, M.

2011-05-06T23:59:59.000Z

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181

Optimization of Cesium Removal from Hanford Envelope A Simulant with SuperLig 639 Ion Exchange Resin  

SciTech Connect

Hanford RadioactiveWaste materials have been categorized into four envelopes labeled A through D as specified in the Tank Waste Remediation Contract between BNFL and DOE. 1 Envelopes A, B and C contain only solubilized species and are specified as Low-Activity Waste (LAW). Each envelope is defined based on compositional maximums of chemical and radioactive constituents. Envelopes A and B contain low concentrations of organic species and the primary form of technetium is pertechnetate (TcO4-). Envelope C contains higher levels of organic species and technetium which is primarily in the nonpertechnetate form (presumably complexed TcO2). Envelope D is sludge which has been separated from the supernate and is referred to as High Activity Waste. The current plant design utilizes SuperLig ion exchange resins to remove cesium and technetium (the primary radioactive constituents) from the Hanford LAW. The process is designed to produce a decontaminated waste stream and a concentrated eluate waste stream for vitrification into low and high activity glasses, respectively.

King, W.D.

2000-07-27T23:59:59.000Z

182

Preliminary Ion Exchange Modeling for Removal of Cesium from Hanford Waste Using SuperLig 644 Resin  

SciTech Connect

A proposed facility is being designed for the immobilization of Hanford high-level radioactive waste. One unit process in the facility is designed to remove radioactive cesium by ion-exchange from the strongly alkaline aqueous phase. A resin specifically designed with high selectivity of cesium under alkaline conditions is being investigated. The resin also is elutable under more acidic conditions. The proposed design of the facility consists of two sets of two packed columns placed in series (i.e., a lead column followed by a lag (guard) column configuration). During operation, upon reaching a specified cesium concentration criterion at the exit of the lag column, operation is switched to the second set of lead and lag columns. The cesium-loaded lead column is processed (i.e., washed and eluted) and switched to the lag position. the previous lag column is then placed in the lead position (without eluting) and the system is ready for use in the next cycle. For a well designed process, the loading and elution processes result in significant volume reductions in aqueous high-level waste.

Hamm, L.L.

2000-08-23T23:59:59.000Z

183

Intermediate-Scale Ion Exchange Removal of Technetium from Savannah River Site Tank 44 F Supernate Solution  

SciTech Connect

As part of the Hanford River Protection Project waste Treatment facility design contracted to BNFL, Inc., a sample of Savannah River Site (SRS) Tank 4 F waste solution was treated for the removal of technetium (as pertechnetate ion). Interest in treating the SRS sample for Tc removal resulted from the similarity between the Tank 44 F supernate composition and Hanford Envelope A supernate solutions. The Tank 44 F sample was available as a by-product of tests already conducted at the Savannah River Technology Center (SRTC) as part of the Alternative Salt Disposition Program for treatment of SRS wastes. Testing of the SRS sample resulted in considerable cost-savings since it was not necessary to ship a sample of Hanford supernate to SRS.

King, W.D.

2000-08-23T23:59:59.000Z

184

Ion-pairing dynamics of Li{sup +} and SCN{sup -} in dimethylformamide solution: Chemical exchange two-dimensional infrared spectroscopy  

SciTech Connect

Ultrafast two-dimensional infrared (2DIR) spectroscopy has been proven to be an exceptionally useful method to study chemical exchange processes between different vibrational chromophores under thermal equilibria. Here, we present experimental results on the thermal equilibrium ion pairing dynamics of Li{sup +} and SCN{sup -} ions in N,N-dimethylformamide. Li{sup +} and SCN{sup -} ions can form a contact ion pair (CIP). Varying the relative concentration of Li{sup +} in solution, we could control the equilibrium CIP and free SCN{sup -} concentrations. Since the CN stretch frequency of Li-SCN CIP is blue-shifted by about 16 cm{sup -1} from that of free SCN{sup -} ion, the CN stretch IR spectrum is a doublet. The temperature-dependent IR absorption spectra reveal that the CIP formation is an endothermic (0.57 kJ/mol) process and the CIP state has larger entropy by 3.12 J/(K mol) than the free ion states. Since the two ionic configurations are spectrally distinguishable, this salt solution is ideally suited for nonlinear IR spectroscopic investigations to study ion pair association and dissociation dynamics. Using polarization-controlled IR pump-probe methods, we first measured the lifetimes and orientational relaxation times of these two forms of ionic configurations. The vibrational population relaxation times of both the free ion and CIP are about 32 ps. However, the orientational relaxation time of the CIP, which is {approx}47 ps, is significantly longer than that of the free SCN{sup -}, which is {approx}7.7 ps. This clearly indicates that the effective moment of inertia of the CIP is much larger than that of the free SCN{sup -}. Then, using chemical exchange 2DIR spectroscopy and analyzing the diagonal peak and cross-peak amplitude changes with increasing the waiting time, we determined the contact ion pair association and dissociation time constants that are found to be 165 and 190 ps, respectively. The results presented and discussed in this paper are believed to be important, not only because the ion-pairing dynamics is one of the most fundamental physical chemistry problems but also because such molecular ion-ion interactions are of critical importance in understanding Hofmeister effects on protein stability.

Lee, Kyung-Koo; Park, Kwang-Hee; Kwon, Donghyun; Choi, Jun-Ho; Son, Hyewon [Department of Chemistry, Research Institute for Natural Sciences, Korea University, Seoul 136-701 (Korea, Republic of); Park, Sungnam; Cho, Minhaeng [Department of Chemistry, Research Institute for Natural Sciences, Korea University, Seoul 136-701 (Korea, Republic of); Multidimensional Spectroscopy Laboratory, Korea Basic Science Institute, Seoul 136-713 (Korea, Republic of)

2011-02-14T23:59:59.000Z

185

U.S.-MEXICO TECHNOLOGY TRANSFER; BILATERAL TECHNICAL EXCHANGES FOR SUSTAINABLE ECONOMIC GROWTH IN THE BORDER REGION  

SciTech Connect

The U.S. Department of Energy (DOE) maintains a strong commitment to transfer the results of its science and technology programs to the private sector. The intent is to apply innovative and sometimes advanced technologies to address needs while simultaneously stimulating new commercial business opportunities. Such focused technology transfer was evident in the late 1990s as the results of DOE investments in environmental management technology development led to new tools for characterizing and remediating contaminated sites as well as handling and minimizing the generation of hazardous wastes. The Departments Office of Environmental Management was attempting to reduce the cost, accelerate the schedule, and improve the efficacy of clean-up efforts in the nuclear weapons complex. It recognized that resulting technologies had broader world market applications and that their commercialization would further reduce costs and facilitate deployment of improved technology at DOE sites. DOEs Albuquerque Operations Office (now part of the National Nuclear Security Administration) began in 1995 to build the foundation for a technology exchange program with Mexico. Initial sponsorship for this work was provided by the Departments Office of Environmental Management. As part of this effort, Applied Sciences Laboratory, Inc. (ASL) was contracted by the DOE Albuquerque office to identify Mexicos priority environmental management needs, identify and evaluate DOE-sponsored technologies as potential solutions for those needs, and coordinate these opportunities with decision makers from Mexicos federal government. That work led to an improved understanding of many key environmental challenges that Mexico faces and the many opportunities to apply DOEs technologies to help resolve them. The above results constituted, in large part, the foundation for an initial DOE-funded program to apply the Departments technology base to help address some of Mexicos challenging environmental issues. The results also brought focus to the potential contributions that DOEs science and technology could make for solving the many difficult, multi-generational problems faced by hundreds of bi-national communities along the 2,000-mile shared border of the United States and Mexico. Efforts to address these U.S.-Mexico border issues were initially sponsored by the DOEs Albuquerque and Carlsbad offices. In subsequent years, the U.S. Congress directed appropriations to DOEs Carlsbad office to address public health, safety and security issues prevalent within U.S.-Mexico border communities. With ASLs assistance, DOEs Albuquerque office developed contacts and formed partnerships with interested U.S and Mexican government, academic, and commercial organizations. Border industries, industrial effluents, and public health conditions were evaluated and documented. Relevant technologies were then matched to environmental problem sets along the border. Several technologies that were identified and subsequently supported by this effort are now operational in a number of U.S.-Mexico border communities, several communities within Mexicos interior states, and in other parts of Latin America. As a result, some serious public health threats within these communities caused by exposure to toxic airborne pollutants have been reduced. During this time, DOEs Carlsbad office hosted a bilateral conference to establish a cross-border consensus on what should be done on the basis of these earlier investigative efforts. Participating border region stakeholders set an agenda for technical collaborations. This agenda was supported by several Members of Congress who provided appropriations and directed DOEs Carlsbad office to initiate technology demonstration projects. During the following two years, more than 12 private-sector and DOE-sponsored technologies were demonstrated in partnership with numerous border community stakeholders. All technologies were well received and their effectiveness at addressing health, safety and security issues w

Jimenez, Richard, D., Dr.

2007-10-01T23:59:59.000Z

186

Efficiencies and Optimization of Weak Base Anion Ion-Exchange Resin for Groundwater Hexavalent Chromium Removal at Hanford  

SciTech Connect

The U.S. Department of Energys (DOEs) contractor, CH2M HILL Plateau Remediation Company, has successfully converted a series of groundwater treatment facilities to use a new treatment resin that is delivering more than $3 million in annual cost savings and efficiency in treating groundwater contamination at the DOE Hanford Site in southeastern Washington State. During the production era, the nuclear reactors at the Hanford Site required a continuous supply of high-quality cooling water during operations. Cooling water consumption ranged from about 151,417 to 378,541 L/min (40,000 to 100,000 gal/min) per reactor, depending on specific operating conditions. Water from the Columbia River was filtered and treated chemically prior to use as cooling water, including the addition of sodium dichromate as a corrosion inhibitor. Hexavalent chromium was the primary component of the sodium dichromate and was introduced into the groundwater at the Hanford Site as a result of planned and unplanned discharges from the reactors starting in 1944. Groundwater contamination by hexavalent chromium and other contaminants related to nuclear reactor operations resulted in the need for groundwater remedial actions within the Hanford Site reactor areas. Beginning in 1995, groundwater treatment methods were evaluated, leading to the use of pump-and-treat facilities with ion exchange using Dowex 21K, a regenerable, strong-base anion exchange resin. This required regeneration of the resin, which was performed offsite. In 2008, DOE recognized that regulatory agreements would require significant expansion for the groundwater chromium treatment capacity. As a result, CH2M HILL performed testing at the Hanford Site in 2009 and 2010 to demonstrate resin performance in the specific groundwater chemistry at different waste sites. The testing demonstrated that a weak-base anion, single-use resin, specifically ResinTech SIR-700 , was effective at removing chromium, had a significantly higher capacity, could be disposed of efficiently onsite, and would eliminate the complexities and programmatic risks from sampling, packaging, transportation, and return of resin for regeneration.

Nesham, Dean O. [CH2M HILL Plateau Remediation Company, Richland, WA (United States); Ivarson, Kristine A. [CH2M HILL Plateau Remediation Company, Richland, WA (United States); Hanson, James P. [CH2M HILL Plateau Remediation Company, Richland, WA (United States); Miller, Charles W. [CH2M HILL Plateau Remediation Company, Richland, WA (United States); Meyers, P. [USDOE, Richland Operations Office, WA (United States); Jaschke, Naomi M. [USDOE, Richland Operations Office, WA (United States)

2014-02-03T23:59:59.000Z

187

Vehicle Technologies Office Merit Review 2014: Advanced High Energy Li-Ion Cell for PHEV and EV Applications  

Energy.gov (U.S. Department of Energy (DOE))

Presentation given by 3M at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about advanced high energy Li-ion cell for PHEV...

188

IEEE TRANSACTIONS ON NANOBIOSCIENCE, VOL. 4, NO. 1, MARCH 2005 121 Microchip Technology in Ion-Channel Research  

E-Print Network (OSTI)

IEEE TRANSACTIONS ON NANOBIOSCIENCE, VOL. 4, NO. 1, MARCH 2005 121 Microchip Technology in Ion drugs have been taken off the market, or their use curtailed, because they have caused sudden death due

Sigworth, Fred

189

Development and implementation of a FT-ICR mass spectrometer for the investigation of ion conformations of peptide sequence isomers containing basic amino acid residues by gas-phase hydrogen/deuterium exchange  

E-Print Network (OSTI)

The gas-phase hydrogen/deuterium (H/D) exchange of protonated di- and tripeptides containing a basic amino acid residue has been studied with a Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometer. Bimolecular reactions...

Marini, Joseph Thomas

2004-09-30T23:59:59.000Z

190

DEVELOPMENT OF A UHT WATER PASTEURIZATION SYSTEM USING MICROCHANNEL HEAT EXCHANGER TECHNOLOGY  

E-Print Network (OSTI)

stages of proposal development for DaVita, leveraging the OSU Venture Fund money for a small-scale system+ that a small-scale system is feasible with microchannel technology. These past activities, as footnoted below, significant interest exists in a stand-alone water purification system in the 1000 ml

Escher, Christine

191

Proceedings of the workshop for exchange of technology for CWC inspections  

SciTech Connect

With the signing of the Chemical Weapons Convention (CWC), the work of the Preparatory Commission in defining the modalities of on-site verification inspections will begin early in 1993. One of the methods for increasing the effectiveness of inspections is the collection of samples for chemical analysis. The CWC allows for this analysis to be performed either at the site of the inspection or in a dedicated off-site laboratory. The decision as to where samples are to be analyzed in any specific instance may involve a consideration of the threat, real or perceived, to the compromise of legitimate sensitive host-party information. The ability to perform efficient chemical analysis at the inspection site, where samples remain in joint (host-inspector) custody and the analytical procedures can be observed by the host, can alleviate much of the concern over possible loss of confidential information in both government and industry. This workshop was designed to encourage the exchange of information among participants with experience in the use of analytical equipment for on-site sample collection and analysis. Individual projects are processed separately for the databases.

McGuire, R.R.

1993-04-01T23:59:59.000Z

192

SELECTIVE REMOVAL OF STRONTIUM AND CESIUM FROM SIMULATED WASTE SOLUTION WITH TITANATE ION EXCHANGERS IN A FILTER CARTRIDGE CONFIGURATION  

SciTech Connect

This report describes experimental results for the selective removal of strontium and cesium from simulated waste solutions using monosodium titanate (MST) and crystalline silicotitanate (CST)-laden filter cartridges. Four types of ion exchange cartridge media (CST and MST designed by both 3M and POROX{reg_sign}) were evaluated. In these proof-of-principle tests effective uptake of both Sr-85 and Cs-137 was observed. However, the experiments were not performed long enough to determine the saturation levels or breakthrough curve for each filter cartridge. POREX{reg_sign} MST cartridges, which by design were based on co-sintering of the active titanates with polyethylene particles, seem to perform as well as the 3M-designed MST cartridges (impregnated filter membrane design) in the uptake of strontium. At low salt simulant conditions (0.29 M Na{sup +}), the instantaneous decontamination factor (D{sub F}) for Sr-85 with the 3M-design MST cartridge measured 26, representing the removal of 96% of the Sr-85. On the other hand, the Sr-85 instantaneous D{sub F} with the POREX{reg_sign} design MST cartridge measured 40 or 98% removal of the Sr-85. Strontium removal with the 3M-design MST and CST cartridges placed in series filter arrangement produced an instantaneous decontamination factor of 41 or 97.6% removal compared to an instantaneous decontamination factor of 368 or 99.7% removal of the strontium with the POREX{reg_sign} MST and CST cartridge design placed in series. At high salt simulant conditions (5.6 M Na{sup +}), strontium removal with 3M-designed MST cartridge only and with 3M-designed MST and CST cartridges operated in a series configuration were identical. The instantaneous decontamination factor and the strontium removal efficiency, under the above configuration, averaged 8.6 and 88%, respectively. There were no POREX{reg_sign} cartridge experiments using the higher ionic strength simulant solution. At low salt simulant conditions, the uptake of Cs-137 with POREX{reg_sign} CST cartridge out performed the 3M-designed CST cartridges. The POREX{reg_sign} CST cartridge, with a Cs-137 instantaneous decontamination factor of 55 and a Cs-137 removal efficiency of 98% does meet the Cs-137 decontamination goals in the low salt simulant liquor. The Cs-137 removal with 3M-designed CST cartridge produced a decontamination factor of 2 or 49% removal efficiency. The Cs-137 performance graph for the 3M-designed CST cartridge showed an early cessation in the uptake of cesium-137. This behavior was not observed with the POREX{reg_sign} CST cartridges. No Cs-137 uptake tests were performed with the POREX{reg_sign} CST cartridges at high salt simulant conditions. The 3M-designed CST cartridges, with an instantaneous Cs-137 decontamination factor of less than 3 and a Cs-137 removal efficiency of less than 50% failed to meet the Cs-137 decontamination goals in both the low and high salt simulant liquors. This poor performance in the uptake of Cs-137 by the 3M CST cartridges may be attributed to fabrication flaws for the 3M-designed CST cartridges. The reduced number of CST membrane wraps per cartridge during the cartridge design phase, from 3-whole wraps to about 1.5, may have contributed to Cs-137 laden simulant channeling/by-pass which led to the poor performance in terms of Cs-137 sorption characteristics for the 3M designed CST cartridges. The grinding of CST ion exchange materials, to reduce the particle size distribution and thus enhance their easy incorporation into the filter membranes and the co-sintering of MST with polyethylene particles, did not adversely affect the sorption kinetics of both CST and MST in the uptake of Cs-137 and Sr-85, respectively. In general, the POREX{reg_sign} based cartridges showed more resistance to simulant flow through the filter cartridges as evidenced by higher pressure differences across the cartridges. Based on these findings they conclude that incorporating MST and CST sorbents into filter membranes represent a promising method for the semi-continuous removal of radioisotopes of strontium a

Oji, L.; Martin, K.; Hobbs, D.

2011-05-26T23:59:59.000Z

193

Technology development for corrosion-resistant condensing heat exchangers. Final report, September 1984-October 1985  

SciTech Connect

The report presents the results of a study to develop technology to support gas-appliance manufacturers in the selection of corrosion-resistant materials for high-efficiency, gas-fired residential space-heating equipment. Condensate sampling during the 1984-85 heating season has indicated that condensate chloride levels from indoor-air combustion normally vary by 200 or 300% from week-to-week due to normal homeowner activities. Several homes, however, had chloride levels greater than the benchmark level (26 ppm) nearly every week. These results support the hypothesis that high indoor chloride levels are more likely caused by on-going homeowner activities than by a rare chloride-producing event. The mean chloride level found in outdoor-air condensate samples was five to eight times lower than the mean of the indoor data. The chloride level corresponding to the 99.5 percentile for the outdoor samples could not be estimated because of the limited amount of outdoor data.

Stickford, G.H.; Hindin, B.; Talbert, S.G.; Agrawal, A.K.; Murphy, M.J.

1985-10-01T23:59:59.000Z

194

Investigation of dynamic driving cycle effect on the degradation of proton exchange membrane fuel cell by segmented cell technology  

Science Journals Connector (OSTI)

Abstract Durability is one of the most important limiting factors for the commercialization of proton exchange membrane fuel cell (PEMFC). Fuel cells are more vulnerable to degradation under operating conditions as dynamic load cycle or start up/shut down. The purpose of this study is to evaluate influences of driving cycles on the durability of fuel cells through analyzing the degradation mechanism of a segmented cell in real time. This study demonstrates that the performance of the fuel cell significantly decreases after 200 cycles. The segmented cell technology is used to measure the local current density distribution, which shows that the current density at the exit region and the inlet region declines much faster than the other parts. Meanwhile, electro-chemical impedance spectroscopy (EIS) reveals that after 200 cycles the ohmic resistance of fuel cell increases, especially at the cathode, and electro-chemical surface area (ESA) decreases from 392 to 307cm2mg?1. Furthermore, scanning electron microscopy (SEM) images of the membraneelectrode assembly (MEA) in cross-section demonstrate crackle flaw on the surface of the catalyst layer and the delamination of the electrodes from the membrane. Transmission electron microscope (TEM) results also show that the Pt particle size increases distinctly after driving cycles.

R. Lin; F. Xiong; W.C. Tang; L. Tcher; J.M. Zhang; J.X. Ma

2014-01-01T23:59:59.000Z

195

Ion exchange separation of plutonium and gallium (1) resource and inventory requirements, (2) waste, emissions, and effluent, and (3) facility size  

SciTech Connect

The following report summarizes an effort intended to estimate within an order-of-magnitude the (1) resource and inventory requirements, (2) waste, emissions, and effluent amounts, and (3) facility size, for ion exchange (IX) separation of plutonium and gallium. This analysis is based upon processing 3.5 MT-Pu/yr. The technical basis for this summary is detailed in a separate document, {open_quotes}Preconceptual Design for Separation of Plutonium and Gallium by Ion Exchange{close_quotes}. The material balances of this separate document are based strictly on stoichiometric amounts rather than details of actual operating experience, in order to avoid classification as Unclassified Controlled Nuclear Information. This approximation neglets the thermodynamics and kinetics which can significantly impact the amount of reagents required. Consequently, the material resource requirements and waste amounts presented here would normally be considered minimums for processing 3.5 MT-Pu/yr; however, the author has compared the inventory estimates presented with that of an actual operating facility and found them similar. Additionally, the facility floor space presented here is based upon actual plutonium processing systems and can be considered a nominal estimate.

DeMuth, S.

1997-09-30T23:59:59.000Z

196

CdS and CdS/CdSe sensitized ZnO nanorod array solar cells prepared by a solution ions exchange process  

SciTech Connect

Graphical abstract: - Highlights: CdS and CdS/CdSe quantum dots are assembled on ZnO nanorods by ion exchange process. The CdS/CdSe sensitization of ZnO effectively extends the absorption spectrum. The performance of ZnO/CdS/CdSe cell is improved by extending absorption spectrum. - Abstract: In this paper, cadmium sulfide (CdS) and cadmium sulfide/cadmium selenide (CdS/CdSe) quantum dots (QDs) are assembled onto ZnO nanorod arrays by a solution ion exchange process for QD-sensitized solar cell application. The morphology, composition and absorption properties of different photoanodes were characterized with scanning electron microscope, transmission electron microscope, energy-dispersive X-ray spectrum and Raman spectrum in detail. It is shown that conformal and uniform CdS and CdS/CdSe shells can grow on ZnO nanorod cores. Quantum dot sensitized solar cells based on ZnO/CdS and ZnO/CdS/CdSe nanocable arrays were assembled with gold counter electrode and polysulfide electrolyte solution. The CdS/CdSe sensitization of ZnO can effectively extend the absorption spectrum up to 650 nm, which has a remarkable impact on the performance of a photovoltaic device by extending the absorption spectrum. Preliminary results show one fourth improvement in solar cell efficiency.

Chen, Ling; Gong, Haibo; Zheng, Xiaopeng; Zhu, Min; Zhang, Jun [Key Laboratory of Inorganic Functional Materials in Universities of Shandong, School of Materials Science and Engineering, University of Jinan, Jinan 250022, Shandong (China); Yang, Shikuan [Department of Engineering Science and Mechanics, The Pennsylvania State University, University Park, PA 16802-6812 (United States); Cao, Bingqiang, E-mail: mse_caobq@ujn.edu.cn [Key Laboratory of Inorganic Functional Materials in Universities of Shandong, School of Materials Science and Engineering, University of Jinan, Jinan 250022, Shandong (China)

2013-10-15T23:59:59.000Z

197

Calcite dissolution and Ca/Na ion-exchange reactions in columns with different flow rates through high ESR soil  

E-Print Network (OSTI)

The leaching of a Na?-affected calcareous soil with water results in two concurrent recesses: (i) CaCO? dissolution, and (ii) replacement of Na? on the cation-exchange complex by Ca?. In the current study, Woodward soil (coarse-silty, mixed...

Navarre, Audrey

2012-06-07T23:59:59.000Z

198

PAPER STUDY EVALUATIONS OF THE INTRODUCTION OF SMALL COLUMN ION EXCHANGE WASTE STREAMS TO THE DEFENSE WASTE PROCESSING FACILITY  

SciTech Connect

The objective of this paper study is to provide guidance on the impact of Monosodium Titanate (MST) and Crystalline Silicotitanate (CST) streams from the Small Column Ion Exchange (SCIX) process on the Defense Waste Processing Facility (DWPF) flowsheet and glass waste form. A series of waste processing scenarios was evaluated, including projected compositions of Sludge Batches 8 through 17 (SB8 through SB17), MST additions, CST additions to Tank 40 or to a sludge batch preparation tank (Tank 42 or Tank 51, referred to generically as Tank 51 in this report), streams from the Salt Waste Processing Facility (SWPF), and two canister production rates. A wide array of potential glass frit compositions was used to support this assessment. The sludge and frit combinations were evaluated using the predictive models in the current DWPF Product Composition Control System (PCCS). The results were evaluated based on the number of frit compositions available for a particular sludge composition scenario. A large number of candidate frit compositions (e.g., several dozen to several hundred) is typically a good indicator of a sludge composition for which there is flexibility in forming an acceptable waste glass and meeting canister production rate commitments. The MST and CST streams will significantly increase the concentrations of certain components in glass, such as Nb{sub 2}O{sub 5}, TiO{sub 2}, and ZrO{sub 2}, to levels much higher than have been previously processed at DWPF. Therefore, several important assumptions, described in detail in the report, had to be made in performing the evaluations. The results of the paper studies, which must be applied carefully given the assumptions made concerning the impact of higher Ti, Zr, and Nb concentrations on model validity, provided several observations: (1) There was difficulty in identifying a reasonable number of candidate frits (and in some cases an inability to identify any candidate frits) when a waste loading of 40% is targeted for Sludge Batches 8, 16, and 17, regardless of the addition of SCIX or SWPF streams. This indicates that the blending strategy for these sludge batches should be reevaluated by Savannah River Remediation (SRR). (2) In general, candidate frits were available to accommodate CST additions to either Tank 40 or Tank 51. A larger number of candidate frits were typically available for the sludge batches when CST is added to Tank 51 rather than Tank 40, meaning that more compositional flexibility would be available for frit selection and DWPF operation. Note however that for SB8 and SB17, no candidate frits were available to accommodate CST going to Tank 40 with and without SWPF streams. The addition of SWPF streams generally improves the number of candidate frits available for processing of a given sludge batch. (3) The change in production rate from 40 Sludge Receipt and Adjustment Tank (SRAT) batches per year (i.e., the current production rate) to 75 SRAT batches per year, without SWPF streams included, had varied results in terms of the number of candidate frits available for processing of a given sludge batch. Therefore, this variable is not of much concern in terms of incorporating the SCIX streams. Note that the evaluation at 75 SRAT batches per year (approximately equivalent to 325 canisters per year) is more conservative in terms of the impact of SCIX streams as compared to a production rate of 400 canisters per year. Overall, the outcome of this paper study shows no major issues with the ability to identify an acceptable glass processing window when CST from the SCIX process is transferred to either Tank 40 or Tank 51. The assumptions used and the model limitations identified in this report must be addressed through further experimental studies, which are currently being performed. As changes occur to the planned additions of MST and CST, or to the sludge batch preparation strategy, additional evaluations will be performed to determine the potential impacts. As stated above, the issues with Sludge Batches 8, 16, and 17 should be further evaluated by SRR. A

Fox, K.; Edwards, T.; Stone, M.; Koopman, D.

2010-06-29T23:59:59.000Z

199

Selective metal ion extraction for multiple ion liquid-liquid exchange reactions. Progress report, DE-AS02-79ER 10406. A001  

SciTech Connect

The first phase of selecting a model binary system to study was completed. The system selected is Cu(II), Fe(III) acid sulfate solutions extracted by ..beta..-alkenyl 8-hydroxy quinoline (Kelex 100) in xylene. Maximum copper extraction occurs in less than 5 minutes at 30 to 50/sup 0/C. Thermodynamic chemical equilibrium studies with the Fe(III) ion indicate that the ionic charge of the extracted ion is +3 over a limited pH and concentration range. A simplified equilibrium model did not fit the experimental data. A chemical equilibrium model for the aqueous phase was developed. Kinetic studies on the liquid jet recycle reactor are underway. The model proposed to analyze simultaneous extraction of Cu(II) and Fe(III) in a stirred tank extractor was reduced to a set of two nonlinear algebraic equations for idealized kinetic expressions.

Tavlarides, L.L.

1980-01-01T23:59:59.000Z

200

Study by in situ FTIR of the SCR of NO by propene on Cu2+ ion-exchanged Ti-PILC  

Science Journals Connector (OSTI)

Adsorption on Cu ion-exchanged titanium pillared clay (Cu-Ti-PILC) was investigated by in situ infrared spectroscopy to provide insight into the reaction intermediates present in the selective catalytic reduction (SCR) of NO by propene in the presence of oxygen. The NO/O2 adsorption produced different nitrate species due to the presence of terminal and bridged Cu2+OH groups. These nitrates evolved into N2 and N2O in small amounts once the NO catalytic cycle was finished. It can be concluded that the Cu2+OH groups reacted with the nitro group, thus forming nitrates. C3H6 adsorption was higher and stronger than NO adsorption on the active sites of the catalyst. C3H6 reacted in the active site producing hydrocarbon intermediates (an organic nitro compound and acetate), which were responsible for the NO reduction.

J.L. Valverde; A. de Lucas; F. Dorado; A. Romero; P.B. Garca

2005-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "ion exchange technology" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Experimental data and analysis to support the design of an ion-exchange process for the treatment of Hanford tank waste supernatant liquids  

SciTech Connect

Hanford`s 177 underground storage tanks contain a mixture of sludge, salt cake, and alkaline supernatant liquids. Disposal options for these wastes are high-level waste (HLW) glass for disposal in a repository or low-level waste (LLW) glass for onsite disposal. Systems-engineering studies show that economic and environmental considerations preclude disposal of these wastes without further treatment. Difficulties inherent in transportation and disposal of relatively large volumes of HLW make it impossible to vitrify all of the tank waste as HLW. Potential environmental impacts make direct disposal of all of the tank waste as LLW glass unacceptable. Although the pretreatment and disposal requirements are still being defined, most pretreatment scenarios include retrieval of the aqueous liquids, dissolution of the salt cakes, and washing of the sludges to remove soluble components. Most of the cesium is expected to be in the aqueous liquids, which are the focus of this report on cesium removal by ion exchange. The main objectives of the ion-exchange process are removing cesium from the bulk of the tank waste (i.e., decontamination) and concentrating the separated cesium for vitrification. Because exact requirements for removal of {sup 137}Cs have not yet been defined, a range of removal requirements will be considered. This study addresses requirements to achieve {sup 137}Cs levels in LLW glass between (1) the Nuclear Regulatory Commission (NRC) Class C (10 CFR 61) limit of 4600 Ci/m{sup 3} and (2) 1/10th of the NRC Class A limit of 1 Ci/m{sup 3} i.e., 0.1/m{sup 3}. The required degrees of separation of cesium from other waste components is a complex function involving interactions between the design of the vitrification process, waste form considerations, and other HLW stream components that are to be vitrified.

Kurath, D.E.; Bray, L.A.; Brooks, K.P.; Brown, G.N.; Bryan, S.A.; Carlson, C.D.; Carson, K.J.; DesChane, J.R.; Elovich, R.J.; Kim, A.Y.

1994-12-01T23:59:59.000Z

202

Integrated Module Heat Exchanger | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Module Heat Exchanger Integrated Module Heat Exchanger 2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting...

203

Calendar Life Studies of Advanced Technology Development Program Gen 1 Lithium Ion Batteries  

SciTech Connect

This report presents the test results of a special calendar-life test conducted on 18650-size, prototype, lithium-ion battery cells developed to establish a baseline chemistry and performance for the Advanced Technology Development Program. As part of electrical performance testing, a new calendar-life test protocol was used. The test consisted of a once-per-day discharge and charge pulse designed to have minimal impact on the cell yet establish the performance of the cell over a period of time such that the calendar life of the cell could be determined. The calendar life test matrix included two states of charge (i.e., 60 and 80%) and four temperatures (40, 50, 60, and 70C). Discharge and regen resistances were calculated from the test data. Results indicate that both discharge and regen resistance increased nonlinearly as a function of the test time. The magnitude of the discharge and regen resistance depended on the temperature and state of charge at which the test was conducted. The calculated discharge and regen resistances were then used to develop empirical models that may be useful to predict the calendar life or the cells.

Wright, Randy Ben; Motloch, Chester George

2001-03-01T23:59:59.000Z

204

Cycle Life Studies of Advanced Technology Development Program Gen 1 Lithium Ion Batteries  

SciTech Connect

This report presents the test results of a special calendar-life test conducted on 18650-size, prototype, lithium-ion battery cells developed to establish a baseline chemistry and performance for the Advanced Technology Development Program. As part of electrical performance testing, a new calendar-life test protocol was used. The test consisted of a once-per-day discharge and charge pulse designed to have minimal impact on the cell yet establish the performance of the cell over a period of time such that the calendar life of the cell could be determined. The calendar life test matrix included two states of charge (i.e., 60 and 80%) and four temperatures (40, 50, 60, and 70C). Discharge and regen resistances were calculated from the test data. Results indicate that both discharge and regen resistance increased nonlinearly as a function of the test time. The magnitude of the discharge and regen resistance depended on the temperature and state of charge at which the test was conducted. The calculated discharge and regen resistances were then used to develop empirical models that may be useful to predict the calendar life or the cells.

Wright, Randy Ben; Motloch, Chester George

2001-03-01T23:59:59.000Z

205

Combining reverse osmosis and ion-exchange allows beet distillery condensates to be recycled as fermentable dilution water  

Science Journals Connector (OSTI)

Abstract Combinations of physical purification processes, i.e. anion-exchange, adsorption, and reverse osmosis were evaluated and compared with single ones for their ability to remove target inhibitory compounds from distillery condensates with the purpose of reusing condensates as fermentation water. Performances of the treatments were evaluated through analyses of residual target compounds and batch and continuous fermentation experiments. Reverse osmosis on BW30 membrane (Dow Chemical) at 25bar transmembrane pressure and volume reduction ratio (VRR)=8 followed by anion-exchange (weak Amberlite FPA 51 resin, Dow) was the most efficient process to decrease all inhibitory target compounds (formic, acetic, propanoic, butanoic acids and 2-phenethyl alcohol) present in a distillery condensate below their detection or quantification limit. Water recovery was 87.5%. Such treated condensate proved convenient for reuse as fermentation water. Fermentation tests run in a multistage device exhibited yeast viability and ethanol production performances (concentration and global productivity) equivalent to the blank for a final ethanol concentration of 80gL?1 close to practical value encountered in distilleries.

Marie-Laure Lameloise; Marjorie Gavach; Marielle Bouix; Claire Fargues

2014-01-01T23:59:59.000Z

206

Nonlinear ion concentration polarization : fundamentals and applications  

E-Print Network (OSTI)

Ion exchange membrane (IEM) is a functional material that has a permselectivity of ions. Two types of IEMs - anion exchange membrane (AEM) and cation exchange membrane (CEM) - are used in a variety of electrochemical ...

Kwak, Rhokyun

2013-01-01T23:59:59.000Z

207

A review of focused ion beam technology and its applications in transmission electron microscopy  

Science Journals Connector (OSTI)

......fabrication technologies. Damage issues...twodimensional,cell-basedtopographysimulations...of polymer solar cells deposited on...progress of FIB technology and its applications...observation technology of binder...of polymer solar cells deposited on......

Masaaki Sugiyama; Genichi Sigesato

2004-10-01T23:59:59.000Z

208

Ion exchange characteristics of enhanced oil recovery systems (miscibility studies). Sesquiannual report, April 1, 1979-September 30, 1980  

SciTech Connect

In the period of this report, studies of the hydrotropic properties of organic alkylbenzenesulfonates and particularly of alkylbenzenecarboxylates were extended; the effects of several different alcohols on miscibility between aqueous protosurfactant solutions and aliphatic and aromatic alkanes were investigated; hydrotropic properties of an alicylic carboxylate were determined; the equivalent weight of the organic salts studied was extended into the surfactant range; solubilities of protosurfactants and surfactants in salt solution were measured; and investigations of the adsorption of protosurfactants on minerals as a function of salinity were started. Pseudo three-component representations of hydrocarbon/alcohol/aqueous protosurfactant solutions (constant ratio of organic salt to water) have now been studied extensively, particularly in the case of toluene/1-butanol/aqueous sodium 2,5-diisopropylbenzenesulfonate. Measurements include establishment of the phase behavior in the limiting three-component systems, the effect of protosurfactant concentration in the four-component systems, and determination of the compositions in a limited number of cases of the coexisting phases. In extension of the equivalent weight of organic salts into the recognized surfactant regime, some were found to give miscibiity patterns which appeared to be reasonable extrapolations of the protosurfactants systems and some were quite different. Solubilities of surfactants restrict investigation to compositions having asymmetric boundaries. In these, it appears that protosurfactants are more effective in promoting miscibility than surfactants. Solubilities of organic salts in NaCl solutions, both of protosurfactants and surfactants, decline much more sharply with NaCl concentration than a constant product of the sodium ion concentration times the organic ion concentration would predict.

Ho, P.C.; Kraus, K.A.; Bender, T.M.; Ogden, S.B.

1981-07-01T23:59:59.000Z

209

Vehicle Technologies Office Merit Review 2014: Optimization of Ion Transport in High Energy Composite Cathodes  

Energy.gov (U.S. Department of Energy (DOE))

Presentation given by University of California San Diego at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about...

210

Stabilized Lithium Metal Powder, Enabling Material and Revolutionary Technology for High Energy Li-ion Batteries  

Energy.gov (U.S. Department of Energy (DOE))

2010 DOE Vehicle Technologies and Hydrogen Programs Annual Merit Review and Peer Evaluation Meeting, June 7-11, 2010 -- Washington D.C.

211

Vehicle Technologies Office Merit Review 2014: Fluorinated Electrolyte for 5-V Li-Ion Chemistry  

Energy.gov (U.S. Department of Energy (DOE))

Presentation given by Argonne National Laboratory at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about fluorinated...

212

A review of focused ion beam technology and its applications in transmission electron microscopy  

Science Journals Connector (OSTI)

......Observation of the configuration of binder latex in coating layer -Direct observation technology of binder. In: Proc. Japan TAPPI Annual Meeting, pp. 679-685....................

Masaaki Sugiyama; Genichi Sigesato

2004-10-01T23:59:59.000Z

213

Anion exchange membrane  

DOE Patents (OSTI)

An anion exchange membrane and fuel cell incorporating the anion exchange membrane are detailed in which proazaphosphatrane and azaphosphatrane cations are covalently bonded to a sulfonated fluoropolymer support along with anionic counterions. A positive charge is dispersed in the aforementioned cations which are buried in the support to reduce the cation-anion interactions and increase the mobility of hydroxide ions, for example, across the membrane. The anion exchange membrane has the ability to operate at high temperatures and in highly alkaline environments with high conductivity and low resistance.

Verkade, John G; Wadhwa, Kuldeep; Kong, Xueqian; Schmidt-Rohr, Klaus

2013-05-07T23:59:59.000Z

214

Charge-Exchange Collisions Between Hydrogen Ions and Cesium Vapor in the Energy Range 0.5-20 keV  

Science Journals Connector (OSTI)

Charge-exchange collisions have been studied when H+ ions and ground state H0 atoms are incident on Cs vapor. Measurements of the positive, neutral, and negative beam components after passage through the target were made as a function of the Cs target thickness at several energies between 0.5 and 20 keV. All three beam components were found to approach charge equilibrium monotonically. The maximum H- equilibrium yield is (21 4)%, which occurs at an H+ energy of 0.75 keV. The H- yield decreases with increasing energy, and is 0.4% at 20 keV. At energies below 4 keV the H+ equilibrium yield is very small compared with the yield of H0 and H-. For energies greater than 10 kev the H- equilibrium yield is very small compared with the yield of H0 and H+. The cross sections ?+0, ?+-, ?0+, and ?0- were measured. The subscripts + and - refer to the H+ and H- ions, 0 as an initial subscript refers to a ground-state H0 atom, and 0 as a final subscript refers to an H0 atom in the particular states produced. The cross section ?+0 decreases with increasing energy, and ranges from (9.4 2.0) 10-15 cm2 at 1 keV to (7.5 1.1) 10-16 cm2 at 15 keV. The cross section ?+- decreases with increasing energy in the range 2-15 keV, and has the value (2.1 0.6) 10-17 cm2 at 5 keV. The cross section ?0+ increases with increasing energy, having the value (1.2 0.2) 10-17 cm2 at 2 keV, and (1.74 0.26) 10-16 cm2 at 15 keV. The cross section ?0- decreases with increasing energy, having the value (1.5 0.3) 10-16 cm2 at 2 keV and (1.4 0.2) 10-17 cm2 at 15 keV.

A. S. Schlachter; P. J. Bjorkholm; D. H. Loyd; L. W. Anderson; W. Haeberli

1969-01-05T23:59:59.000Z

215

SELECTIVE REMOVAL OF STRONTIUM AND CESIUM FROM SIMULATED WASTE SOLUTION WITH TITANATE ION-EXCHANGERS IN A FILTER CARTRIDGE CONFIGURATIONS-12092  

SciTech Connect

Experimental results for the selective removal of strontium and cesium from simulated waste solutions with monosodium titanate and crystalline silicotitanate laden filter cartridges are presented. In these proof-of-principle tests, effective uptake of both strontium-85 and cesium-137 were observed using ion-exchangers in this filter cartridge configuration. At low salt simulant conditions, the instantaneous decontamination factor for strontium-85 with monosodium titanate impregnated filter membrane cartridges measured 26, representing 96% strontium-85 removal efficiency. On the other hand, the strontium-85 instantaneous decontamination factor with co-sintered active monosodium titanate cartridges measured 40 or 98% Sr-85 removal efficiency. Strontium-85 removal with the monosodium titanate impregnated membrane cartridges and crystalline silicotitanate impregnated membrane cartridges, placed in series arrangement, produced an instantaneous decontamination factor of 41 compared to an instantaneous decontamination factor of 368 for strontium-85 with co-sintered active monosodium titanate cartridges and co-sintered active crystalline silicotitanate cartridges placed in series. Overall, polyethylene co-sintered active titanates cartridges performed as well as titanate impregnated filter membrane cartridges in the uptake of strontium. At low ionic strength conditions, there was a significant uptake of cesium-137 with co-sintered crystalline silicotitanate cartridges. Tests results with crystalline silicotitanate impregnated membrane cartridges for cesium-137 decontamination are currently being re-evaluated. Based on these preliminary findings we conclude that incorporating monosodium titanate and crystalline silicotitanate sorbents into membranes represent a promising method for the semicontinuous removal of radioisotopes of strontium and cesium from nuclear waste solutions.

Oji, L.; Martin, K.; Hobbs, D.

2012-01-03T23:59:59.000Z

216

SELECTIVE REMOVAL OF STRONTIUM AND CESIUM FROM SIMULATED WASTE SOLUTION WITH TITANATE ION-EXCHANGERS IN A FILTER CARTRIDGE CONFIGURATIONS-12092  

SciTech Connect

Experimental results for the selective removal of strontium and cesium from simulated waste solutions with monosodium titanate (MST) and crystalline silicotitanate (CST) laden filter cartridges are presented. In these proof-of-principle tests, effective uptake of both Sr-85 and Cs-137 were observed using ion-exchangers in this filter cartridge configuration. At low salt simulant conditions, the instantaneous decontamination factor (D{sub F}) for Sr-85 with MST impregnated filter membrane cartridges measured 26, representing 96% Sr-85 removal efficiency. On the other hand, the Sr-85 instantaneous D{sub F} with co-sintered active MST cartridges measured 40 or 98% Sr-85 removal efficiency. Strontium-85 removal with the MST impregnated membrane cartridges and CST impregnated membrane cartridges, placed in series arrangement, produced an instantaneous decontamination factor of 41 compared to an instantaneous decontamination factor of 368 for strontium-85 with co-sintered active MST cartridges and co-sintered active CST cartridges placed in series. Overall, polyethylene co-sintered active titanates cartridges performed as well as titanate impregnated filter membrane cartridges in the uptake of strontium. At low ionic strength conditions, there was a significant uptake of Cs-137 with co-sintered CST cartridges. Tests results with CST impregnated membrane cartridges for Cs-137 decontamination are currently being re-evaluated. Based on these preliminary findings we conclude that incorporating MST and CST sorbents into membranes represent a promising method for the semi-continuous removal of radioisotopes of strontium and cesium from nuclear waste solutions.

Oji, L.; Martin, K.; Hobbs, D.

2011-11-10T23:59:59.000Z

217

Vehicle Technologies Office Merit Review 2014: Metal-Based High Capacity Li-Ion Anodes  

Energy.gov (U.S. Department of Energy (DOE))

Presentation given by Binghamton University-SUNY at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about metal-based high...

218

Vehicle Technologies Office Merit Review 2014: Development of Electrolytes for Lithium-ion Batteries  

Energy.gov (U.S. Department of Energy (DOE))

Presentation given by University of Rhode Island at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about the development of...

219

HCCI Cycle-by-Cycle Combustion Phase Control Based on Ion Current Technology in GDI Engine  

Science Journals Connector (OSTI)

Homogenous charge compression ignition gains attention increasingly because of its high efficiency and low emissions. The combustion phase control has been one of the key technological issues which affect its ind...

Zhiyong Zhang; Liguang Li; Robert Dibble

2013-01-01T23:59:59.000Z

220

Office of Waste Processing Technical Exchange  

NLE Websites -- All DOE Office Websites (Extended Search)

Event Media Links Event Media Links Session 1: Technical Exchange Opening Topic Speaker PDF Podcast S01-01 Welcome T. Michalske, SRNL N/A Podcast S01-03 Introductions G. Flowers, SRNS N/A Podcast S01-04 Opening Remarks I. Triay, DOE-EM Presentation PDF Podcast S01-05 Status of Waste Processing Technology Development S. Schneider, DOE-EM Presentation PDF Podcast S01-06 Hanford/SRS Tank Waste Path Forward K. Subramanian/ T. Sams, SRR/WRPS Presentation PDF Podcast S01-07 Fluidized Bed Steam Reformer Overview B. Mason, TTT Presentation PDF Podcast S01-08 Next Generation Cesium Solvent B.Moyer/S. Fink/M. Geeting, ORNL/SRNL/SRR Presentation PDF Podcast S01-09 Rotary Microfilter Development/Small Column Ion Exchange D. Herman/ R. Edwards, SRNL/SRR Presentation PDF Podcast Session 2: Increased Waste Loading - Improved Current Processing

Note: This page contains sample records for the topic "ion exchange technology" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

DIVALENT ION EXCHANGE WITH ALKALI  

E-Print Network (OSTI)

Enhanced Oil and Gas Recovery and Improved Drilling Hethods,on Enhanced Oil and Gas Recovery and Im- proved Drilling

Bunge, A.L.

2011-01-01T23:59:59.000Z

222

Argonne Transportation Technology R&D Center - About Us - DOE, Lithium-ion  

NLE Websites -- All DOE Office Websites (Extended Search)

About Us About Us Transportation Research Focuses on DOE's Energy Resources Goals Open the Door The U.S. Department of Energy's (DOE's) goals call for increasing the efficiency and productivity of energy use, while limiting the environmental impacts. In support of these goals, Argonne's Transportation Technology Research and Development Center (TTRDC) brings together scientists and engineers from many disciplines to find cost-effective solutions to the problems of foreign oil dependency and greenhouse gas emissions. As one of the DOE's lead laboratories for research in hybrid powertrains, batteries, and fuel efficient technologies, Argonne's transportation program is critical to advancing the development of next-generation vehicles. The TTRDC's overall goal is to work with DOE, other federal agencies, and industrial partners to put new transportation technologies on the road that improve the way we live and contribute to a better, cleaner future for all.

223

PROJECT W-551 INTERIM PRETREATMENT SYSTEM TECHNOLOGY SELECTION SUMMARY DECISION REPORT AND RECOMMENDATION  

SciTech Connect

This report provides the conclusions of the tank farm interim pretreatment technology decision process. It documents the methodology, data, and results of the selection of cross-flow filtration and ion exchange technologies for implementation in project W-551, Interim Pretreatment System. This selection resulted from the evaluation of specific scope criteria using quantitative and qualitative analyses, group workshops, and technical expert personnel.

CONRAD EA

2008-08-12T23:59:59.000Z

224

492 J. Opt. Soc. Am. B/Vol. 5,No. 2/February 1988 Nonlinear-optical effects in ion-exchanged  

E-Print Network (OSTI)

nonlinearity together with a fast response time.'-7 SDG consists of nano- crystallites of CdS-exchanged semiconductor-doped glass waveguides C. N. Ironside, T. J.Cullen, B.S. Bhumbra, and J.Bell Department-exchanged channel waveguides fabricated in semiconductor- doped glass. The nonlinearity is manifested as optically

225

Coupling of porous filtration and ion-exchange membranes in an electrodialysis stack and impact on cation selectivity: A novel approach for sea water demineralization and the production of physiological water  

Science Journals Connector (OSTI)

Conventional electrodialysis (ED) and electrodialysis with ultrafiltration (EDUF) or nanofiltration (EDNF) membrane treatments were carried-out for partial desalination of sea water and to evaluate their potential for the production of physiological water. A demineralization rate of 10.6% was obtained with the EDNF and of 40.25% with EDUF and conventional ED processes. The nanofiltration membrane, due to its high electrical resistance, slowed down the migrations of ions. Moreover, the use of an ultrafiltration membrane had no significant effect on the demineralization rate of sea water and the electrodialytic parameters in comparison with the use of conventional ED membranes. A demineralization rate between 20.5 and 30.1% was obtained for each cation analyzed following EDNF treatments and between 43.3 and 64.4% when conventional ED or EDUF was used. Moreover, the decrease in the concentration of monovalent ions was slightly larger than for divalent ions in the case of ED and EDUF while for EDNF, the higher decrease was observed for calcium ion. This means that the replacement of a cation-exchange membrane by an ultrafiltration membrane would not change the selectivity of the process for ion separation but with a nanofiltration membrane a cation-selectivity appears.

Laurent Bazinet; Marianne Moalic

2011-01-01T23:59:59.000Z

226

Argonne Transportation Technology R&D Center - Lithium-ion Batteries,  

NLE Websites -- All DOE Office Websites (Extended Search)

Alternative Fuels Autonomie Batteries Downloadable Dynamometer Database Engines Green Racing GREET Hybrid Electric Vehicles Hydrogen & Fuel Cells Materials Modeling, Simulation & Software Plug-In Hybrid Electric Vehicles PSAT Smart Grid Student Competitions Technology Analysis Transportation Research and Analysis Computing Center Working With Argonne Contact TTRDC Photo of battery developers that links to story Press Coverage What's New Multimedia Logo of the Wharton School of Business Dec. 13. Knowledge@Wharton. Green SPorts and Transportation: The Elephant in the Room Logo of Crain's Chicago Business Dec. 10. Crain's Chicago Business. Argonne chemist Pete Chupas named one of Crain's 2013 "40 under 40" Logo of the Sioux City Journal Dec. 2. Sioux City Journal. Ethanol Supporters Say the Numbers Support Their Industry

227

E-Print Network 3.0 - anion-exchange resin technique Sample Search...  

NLE Websites -- All DOE Office Websites (Extended Search)

at Urbana-Champaign Collection: Chemistry 39 9 Treatment of Metal-Bearing Effluents: Removal and Summary: anions are called anion exchangers. The ion exchange function of a...

228

Ammonium Bicarbonate Transport in Anion Exchange Membranes for Salinity Gradient Energy  

Science Journals Connector (OSTI)

Ammonium Bicarbonate Transport in Anion Exchange Membranes for Salinity Gradient Energy ... Current status of ion exchange membranes for power generation from salinity gradients ...

Geoffrey M. Geise; Michael A. Hickner; Bruce E. Logan

2013-08-22T23:59:59.000Z

229

Technolog  

NLE Websites -- All DOE Office Websites (Extended Search)

Research in Research in Science and Technolog y Sandia pushes frontiers of knowledge to meet the nation's needs, today and tomorrow Sandia National Laboratories' fundamental science and technology research leads to greater understanding of how and why things work and is intrinsic to technological advances. Basic research that challenges scientific assumptions enables the nation to push scientific boundaries. Innovations and breakthroughs produced at Sandia allow it to tackle critical issues, from maintaining the safety, security and effectiveness of the nation's nuclear weapons and preventing domestic and interna- tional terrorism to finding innovative clean energy solutions, develop- ing cutting-edge nanotechnology and moving the latest advances to the marketplace. Sandia's expertise includes:

230

Cryogenic ion implantation near amorphization threshold dose for halo/extension junction improvement in sub-30 nm device technologies  

SciTech Connect

We report on junction advantages of cryogenic ion implantation with medium current implanters. We propose a methodical approach on maximizing cryogenic effects on junction characteristics near the amorphization threshold doses that are typically used for halo implants for sub-30 nm technologies. BF{sub 2}{sup +} implant at a dose of 8 Multiplication-Sign 10{sup 13}cm{sup -2} does not amorphize silicon at room temperature. When implanted at -100 Degree-Sign C, it forms a 30 - 35 nm thick amorphous layer. The cryogenic BF{sub 2}{sup +} implant significantly reduces the depth of the boron distribution, both as-implanted and after anneals, which improves short channel rolloff characteristics. It also creates a shallower n{sup +}-p junction by steepening profiles of arsenic that is subsequently implanted in the surface region. We demonstrate effects of implant sequences, germanium preamorphization, indium and carbon co-implants for extension/halo process integration. When applied to sequences such as Ge+As+C+In+BF{sub 2}{sup +}, the cryogenic implants at -100 Degree-Sign C enable removal of Ge preamorphization, and form more active n{sup +}-p junctions and steeper B and In halo profiles than sequences at room temperature.

Park, Hugh; Todorov, Stan; Colombeau, Benjamin; Rodier, Dennis; Kouzminov, Dimitry; Zou Wei; Guo Baonian; Khasgiwale, Niranjan; Decker-Lucke, Kurt [Applied Materials, Varian Semiconductor Equipment, 35 Dory Road, Gloucester, Massachusetts 01930 (United States)

2012-11-06T23:59:59.000Z

231

Energy Technology Data Exchange (ETDE)  

NLE Websites -- All DOE Office Websites (Extended Search)

World Energy Congress IEA Hydrogen Implementing Agreement Brazil Canada Denmark Finland Germany Korea, Rep. of The Netherlands Norway Mexico Switzerland Sweden United...

232

REMOVAL OF TECHNETIUM 99 FROM THE EFFLUENT TREATMENT FACILITY (ETF) BASIN 44 USING PUROLITE A-530E & REILLEX HPQ & SYBRON IONAC SR-7 ION EXCHANGE RESINS  

SciTech Connect

This report documents the laboratory testing and analyses as directed under the test plan, RPP-20407. The overall goal of this task was to evaluate and compare candidate anion exchange resins for their capacity to remove Technetium-99 from Basin 44 Reverse Osmosis reject stream. The candidate resins evaluated were Purolite A-530E, Reillex HPQ, and Sybron IONAC SR-7.

DUNCAN JB

2004-10-29T23:59:59.000Z

233

Simultaneous removal of organic matter and salt ions from saline wastewater in bioelectrochemical systems  

E-Print Network (OSTI)

in physical and chemical separation processes such as ion-exchange, electrodialysis, or reverse osmosis [1

234

Technology Transfer: Available Technologies  

NLE Websites -- All DOE Office Websites (Extended Search)

Ion Sources and Beam Technologies Ion Sources and Beam Technologies GENERATORS AND DETECTORS Compact, Safe and Energy Efficient Neutron Generator Fast Pulsed Neutron Generator High Energy Gamma Generator Lithium-Drifted Silicon Detector with Segmented Contacts Low Power, High Energy Gamma Ray Detector Calibration Device Nested Type Coaxial Neutron Generator Neutron and Proton Generators: Cylindrical Neutron Generator with Nested Option, IB-1764 Neutron-based System for Nondestructive Imaging, IB-1794 Mini Neutron Tube, IB-1793a Ultra-short Ion and Neutron Pulse Production, IB-1707 Mini Neutron Generator, IB-1793b Compact Spherical Neutron Generator, IB-1675 Plasma-Driven Neutron/Gamma Generators Portable, Low-cost Gamma Source for Active Interrogation ION SOURCES WITH ANTENNAS External Antenna for Ion Sources

235

IMPACTS OF SMALL COLUMN ION EXCHANGE STREAMS ON DWPF GLASS FORMULATION: KT08, KT09, AND KT10-SERIES GLASS COMPOSITIONS  

SciTech Connect

This report is the fourth in a series of studies of the impacts of the addition of Crystalline Silicotitanate (CST) and Monosodium Titanate (MST) from the Small Column Ion Exchange (SCIX) process on the Defense Waste Processing Facility (DWPF) glass waste form and the applicability of the DWPF process control models. MST from the Salt Waste Processing Facility (SWPF) is also considered in the study. The KT08-series of glasses was designed to evaluate any impacts of the inclusion of uranium and thorium in glasses containing the SCIX components. The KT09-series of glasses was designed to study the effect of increasing Al{sub 2}O{sub 3} and K{sub 2}O concentrations on the propensity for crystallization of titanium containing phases in high TiO{sub 2} concentration glasses. Earlier work on the KT05-series glasses recommended that the impact of these two components be studied further. Increased Al{sub 2}O{sub 3} concentrations have been shown to improve the properties and performance of high waste loading glasses, and K{sub 2}O has been reported to improve the retention of TiO{sub 2} in silicate glasses. The KT10-series of compositions was designed to evaluate any impacts of the SCIX components at concentrations 50% higher than currently projected.a The glasses were fabricated in the laboratory and characterized to identify crystallization, to verify chemical compositions, to measure viscosity, and to measure durability. Liquidus temperature measurements for the KT10-series glasses are underway and will be reported separately. All but one of the KT08-series glasses were found to be amorphous by X-ray diffraction (XRD). One of the slowly cooled glasses contained a small amount of trevorite, which had no practical impact on the durability of the glass and is typically found in DWPF-type glasses. The measured Product Consistency Test (PCT) responses for the KT08-series glasses are well predicted by the DWPF models. The viscosities of the KT08-series glasses were generally well predicted by the DWPF model. No unexpected issues were encountered when uranium and thorium were added to the glasses with SCIX components. Increased Al{sub 2}O{sub 3} concentrations were not successful in preventing the formation of iron titanate crystals in the KT09-series glasses. Increased K{sub 2}O concentrations were successful in hindering the formation of iron titanates in some of the glasses after the canister centerline cooled (CCC) heat treatment. However, this result did not apply to all of the CCC versions of the glasses, indicating a compositional dependence of this effect. In addition, high concentrations of K{sub 2}O have been shown to hinder the ability of the DWPF durability and viscosity models to predict the performance of these glasses. The usefulness of increased K{sub 2}O concentrations in preventing the formation of iron titanates may therefore be limited. Further characterization was not performed for the KT09-series glasses since the type of crystallization formed was the characteristic of interest for these compositions. All of the KT10-series glasses were XRD amorphous, regardless of heat treatment. Chemical composition measurements showed that the glasses met the targeted concentrations for each oxide. In general, the measured PCT responses of the KT10-series glasses were well predicted by the DWPF models. The measured, normalized release values for silicon for some of the glasses fell above the 95% confidence interval for the predicted values; however, the PCT responses for these glasses remain considerably lower than that of the benchmark Environmental Assessment (EA) glass. The viscosities of the KT10-series glasses were generally well predicted by the DWPF model. The next step in this study will be to compile all of the data developed and further compare the measured properties and performance with those predicted by the current DWPF Product Composition Control System (PCCS) models. Recommendations will then be made as to which models, if any, may need to be modified in order to accommodate the material from SCIX into DWPF

Fox, K.; Edwards, T.

2011-04-26T23:59:59.000Z

236

ESTABLISHING SUSTAINABLE US HEV/PHEV MANUFACTURING BASE: STABILIZED LITHIUM METAL POWDER, ENABLING MATERIAL AND REVOLUTIONARY TECHNOLOGY FOR HIGH ENERGY LI-ION BATTERIES  

SciTech Connect

FMC Lithium Division has successfully completed the project Establishing Sustainable US PHEV/EV Manufacturing Base: Stabilized Lithium Metal Powder, Enabling Material and Revolutionary Technology for High Energy Li-ion Batteries. The project included design, acquisition and process development for the production scale units to 1) produce stabilized lithium dispersions in oil medium, 2) to produce dry stabilized lithium metal powders, 3) to evaluate, design and acquire pilot-scale unit for alternative production technology to further decrease the cost, and 4) to demonstrate concepts for integrating SLMP technology into the Li- ion batteries to increase energy density. It is very difficult to satisfy safety, cost and performance requirements for the PHEV and EV applications. As the initial step in SLMP Technology introduction, industry can use commercially available LiMn2O4 or LiFePO4, for example, that are the only proven safer and cheaper lithium providing cathodes available on the market. Unfortunately, these cathodes alone are inferior to the energy density of the conventional LiCoO2 cathode and, even when paired with the advanced anode materials, such as silicon composite material, the resulting cell will still not meet the energy density requirements. We have demonstrated, however, if SLMP Technology is used to compensate for the irreversible capacity in the anode, the efficiency of the cathode utilization will be improved and the cost of the cell, based on the materials, will decrease.

Yakovleva, Marina

2012-12-31T23:59:59.000Z

237

Ion-exchanged pillared clays: A new class of catalysts for selective catalytic reduction of NO by hydrocarbons and by ammonia  

SciTech Connect

Selective catalytic reduction (SCR) of NO by NH{sub 3} is presently performed with vanadia-based catalysts for flue gas applications. Hydrocarbons would be the preferred reducing agents over NH{sub 3} because of the practical problems associated with the use of NH{sub 3} (i.e., handling and slippage through the reactor). SCR of NO by hydrocarbons can also find important applications for lean-burn (i.e., O{sub 2}-rich) gasoline and diesel engines where the noble-metal three-way catalysts are not effective in the presence of excess oxygen. Pillared interlayered clays (PILCs) have been studied extensively for a number of catalyzed reactions. We have found high activities of PILCs for SCR of NO by NH{sub 3} (26.28). Pillared clays have considerable Bronsted acidity (27, 28), and the protons can be exchanged with metal cations. The Bronsted acidity of TiO{sub 2}-PILC, in particular, remains high after heat treatment at temperatures as high as 400{degrees}C (27-29). In this note, we report first results on the activities of cation-exchanged pillared clays for SCR of NO by both hydrocarbon and NH{sub 3}. 37 refs., 3 figs.

NONE

1995-09-01T23:59:59.000Z

238

r- and p-space electron densities and related kinetic and exchange energies in terms of s states alone for the leading term in the 1/Z expansion for nonrelativistic closed-shell atomic ions  

Science Journals Connector (OSTI)

As a step towards constructing nonlocal energy density functionals, the leading term in the so-called 1/Z expansion for closed-shell atomic ions is the focus here. This term is characterized by the properties of the bare Coulomb potential (-Ze2/r), and for an arbitrary number of closed shells it is known that ??(r)/?r=-(2Z/a0)?s(r), where ?(r) is the ground-state electron density while ?s(r) is the s-state (l=0) contribution to ?(r). Here, the kinetic-energy density t(r) is also derived as a double integral in terms of ?s(r) and Z. Although the exchange energy density ?x(r) is more complex than t(r), a proof is given that, in the Coulomb limit system, ?x is indeed also determined by s-state properties alone. The same is shown to be true for the momentum density n(p), which here is obtained explicitly for an arbitrary number of closed shells. Finally, numerical results are presented that include (a) ten-electron atomic ions (K+L shells), (b) the limit as the number of closed shells tends to infinity, where an appeal is made to the analytical r-space study of Heilmann and Lieb [Phys. Rev. A 52, 3628 (1995)], and (c) momentum density and Compton line shape for an arbitrary number of closed shells.

I. A. Howard; N. H. March; V. E. Van Doren

2001-05-04T23:59:59.000Z

239

SingleSep Disposable Capsules A Separation Technology Based on Microporous Membranes  

E-Print Network (OSTI)

Sartobind SingleSep Disposable Capsules A Separation Technology Based on Microporous Membranes into a conventional housing for easy and quick handling, making ion exchange purification nearly as easy as filtration procedures. For upscaling to production and downstream pro- cessing, Sartorius offers Sartobind Multi

Lebendiker, Mario

240

Information technology equipment cooling system  

SciTech Connect

According to one embodiment, a system for removing heat from a rack of information technology equipment may include a sidecar indoor air to liquid heat exchanger that cools warm air generated by the rack of information technology equipment. The system may also include a liquid to liquid heat exchanger and an outdoor heat exchanger. The system may further include configurable pathways to connect and control fluid flow through the sidecar heat exchanger, the liquid to liquid heat exchanger, the rack of information technology equipment, and the outdoor heat exchanger based upon ambient temperature and/or ambient humidity to remove heat from the rack of information technology equipment.

Schultz, Mark D.

2014-06-10T23:59:59.000Z

Note: This page contains sample records for the topic "ion exchange technology" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Discovery and Early Development of Non-Suppressed Ion Chromatography  

Science Journals Connector (OSTI)

......contained resins that were...significantly lower exchange capacity than the older ion exchangers...tional resins of that time...needed. In addition, the extent...was a vivid demonstration of the value...Although the XAD resins were neutral...derivatized to form ion exchangers...of varying exchange capacity......

James S. Fritz; Douglas T. Gjerde

2010-08-01T23:59:59.000Z

242

STATEMENT OF CONSIDERA l"IONS REQUEST BY INEOS USA LLC, OPERATING AS INEOS TECHNOLOGIES, (lNEOS) FOR AN  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

CONSIDERA l"IONS CONSIDERA l"IONS REQUEST BY INEOS USA LLC, OPERATING AS INEOS TECHNOLOGIES, (lNEOS) FOR AN ADVANCE WAIVER OF DOMESTIC AND FOREIGN PATENT RIGHTS UNDER A PROPOSED SUB-AWARD OF GRANT NO. DE-FG36-04G014315 BETWEEN BIOENGINEERING RESOURCES, INC. (BRI) AND DOE; W(A)2008-028 The Petitioner, INEOS. has requested a waiver of domestic and foreign patent rights for all subject inventions arising from its participation under the above referenced award entitled "Thermochemical Conversion of Com Stover." Petitioner is in the process of acquiring Bioengineering Resources, Inc. (BRI), the original small business grantee. In anticipation of its pending acquisition, Petitioner has proposed to become a sub-awardee under BRI by means of a sub-award agreement (sub-award).

243

Vehicle Technologies Office Merit Review 2014: Utilization of UV or EB Curing Technology to Significantly Reduce Costs and VOCs in the Manufacture of Lithium-Ion Battery Electrodes  

Energy.gov (U.S. Department of Energy (DOE))

Presentation given by Miltec UV International at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about the utilization of UV...

244

Vehicle Technologies Office Merit Review 2014: Characterization of Voltage Fade in Lithium-ion Cells with Layered Oxides  

Energy.gov (U.S. Department of Energy (DOE))

Presentation given by Argonne National Laboratory at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about characterization...

245

Vehicle Technologies Office Merit Review 2014: Overcoming Processing Cost Barriers of High-Performance Lithium-Ion Battery Electrodes  

Energy.gov (U.S. Department of Energy (DOE))

Presentation given by Oak Ridge National Laboratory at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about overcoming...

246

Vehicle Technologies Office Merit Review 2014: Innovative Manufacturing and Materials for Low-Cost Lithium-Ion Batteries  

Energy.gov (U.S. Department of Energy (DOE))

Presentation given by Optodot Corporation at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about innovative manufacturing...

247

Vehicle Technologies Office Merit Review 2014: Wiring Up Silicon Nanostructures for High Energy Lithium-Ion Battery Anodes  

Energy.gov (U.S. Department of Energy (DOE))

Presentation given by Stanford University at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about wiring up silicon...

248

Vehicle Technologies Office Merit Review 2014: Manufacturability Study and Scale-Up for Large Format Lithium Ion Batteries  

Energy.gov (U.S. Department of Energy (DOE))

Presentation given by Oak Ridge National Laboratory at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about...

249

Vehicle Technologies Office Merit Review 2014: Nanoscale Heterostructures and Thermoplastic Resin Binders: Novel Li-ion Anode Systems  

Energy.gov (U.S. Department of Energy (DOE))

Presentation given by University of Pittsburgh at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about nanoscale...

250

Technology Readiness Assessments | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Waste Management » Tank Waste and Waste Processing » Waste Management » Tank Waste and Waste Processing » Technology Readiness Assessments Technology Readiness Assessments Documents Available for Download January 1, 2012 Compilation of TRA Summaries A compilation of all TRA Summaries November 1, 2011 Small Column Ion Exchange at Savannah River Site Technology Readiness Assessment Report February 7, 2011 Preliminary Technology Readiness Assessment (TRA) for the Calcine Disposition Project Volume 2 (CDP) Full Document and Summary Versions are available for download February 7, 2011 Preliminary Technology Readiness Assessment (TRA) for the Calcine Disposition Project Volume 1 (CDP) Full Document and Summary Versions are available for download November 1, 2009 K Basins Sludge Treatment Project Phase 1 Full Document and Summary Versions are available for download

251

Arsenic Removal Technologies and the Effect of Source Water Quality on Performance  

SciTech Connect

Arsenic removal technologies that are effective at the tens of ppb level include coagulation, followed by settling/microfiltration, ion exchange by mineral surfaces,and pressure-driven membrane processes (reverse osmosis, nanofiltration and ultrafiltration). This report describes the fundamental mechanisms of operation of the arsenic removal systems and addresses the critical issues of arsenic speciation, source water quality on the performance of the arsenic removal systems and costs associated with the different treatment technology categories.

KHANDAKER, NADIM R.; BRADY, PATRICK V.

2002-07-01T23:59:59.000Z

252

Separation scheme for selective and quantitative isolation of cobalt from neutron-irradiated biological materials by ion exchange and extraction chromatography  

SciTech Connect

Highly reliable radiochemical separation scheme for selective and quantitative isolation of trace amounts of cobalt from neutron-irradiated biological materials was elaborated. The method consists in wet-ashing of the sample with HNO{sub 3} + HClO{sub 4} (1:1) mixture plus vanadium salt (oxidation catalyst), removal of silica by evaporation with HF and separation of cobalt from accompanying ions successively on 3 columns with Dowex 1-X8[Cl{sup -}] from 0.5 M HCl, Dowex 1-X8[Cl{sup -}] from 8 M HCl + 2 M MgCl{sub 2} and tri-n-octylphosphine oxide (TOPO) supported on styrene-divinylbenzene copolymer, from 7 M HCl solution, respectively. Cobalt of very high radiochemical purity is finally recovered in 1.2 M HCl solution with practically 100% yield. The separation scheme is universally applicable, to biological samples of both animal and plant origin and was devised to become an integral part of the very accurate ({open_quotes}definitive{close_quotes}) method of cobalt determination by neutron activation analysis (NAA). Preliminary results on Co determination by NAA in some certified reference materials confirmed high reliability of the devised separation scheme.

Dybczynski, R.; Danko, B.; Maleszewska, H. [Institute of Nuclear Chemistry and Technology, Warsaw (Poland)

1994-01-01T23:59:59.000Z

253

Optical pumping of ions  

Science Journals Connector (OSTI)

Radiofrequency spectroscopy has been extended to positive ions with S ground states by means of optical pumping. The ions are stored in buffer gases or ion traps and are polarized directly by optical pumping or indirectly by spin exchange, change exchange, or Penning ionization with optically pumped atoms. The applied methods are described. The experiments can be divided into two categories: Collisional interactions of the polarized ions are investigated, like the exchange processes mentioned above, spin exchange with free electrons, spin depolarization and hyperfine density shifts in rare gases. For the two latter effects drastic differences are observed between atomic and ionic 2S12 states the explanations of which reveal the influence of the ionic charge on the interactions. The comparison of equivalent processes involving isoelectronic 2S or 2P configurations of atoms and ions provides a test of current collision theories. Precision rf spectroscopy of ionic ground states yields the 2S12 hyperfine structure splittings of 3He+ and group II ions with relative accuracies of up to 10?9, with further improvement possible. Direct and indirect optical pumping of 1S0 ions is used to determine nuclear magnetic moments, diamagnetic shielding coefficients, and chemical shifts. Applications and further developments of the present methods are discussed.

E.W. Weber

1977-01-01T23:59:59.000Z

254

Vehicle Technologies Office Merit Review 2014: Development of Large Format Lithium Ion Cells with Higher Energy Density  

Energy.gov (U.S. Department of Energy (DOE))

Presentation given by XALT Energy LLC at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about development of large format...

255

Vehicle Technologies Office Merit Review 2014: Studies on High Capacity Cathodes for Advanced Lithium-ion Systems  

Energy.gov (U.S. Department of Energy (DOE))

Presentation given by Oak Ridge National Laboratory at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about studies on high...

256

Vehicle Technologies Office Merit Review 2014: Post-Test Analysis of Lithium-Ion Battery Materials at Argonne National Laboratory  

Energy.gov (U.S. Department of Energy (DOE))

Presentation given by Argonne National Laboratory at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about post-test...

257

Vehicle Technologies Office Merit Review 2014: High Energy, Long Cycle Life Lithium-ion Batteries for EV Applications  

Energy.gov (U.S. Department of Energy (DOE))

Presentation given by The Pennsylvania State University at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about high energy...

258

Vehicle Technologies Office Merit Review 2014: Real-time Metrology for Li-ion Battery R&D and Manufacturing  

Energy.gov (U.S. Department of Energy (DOE))

Presentation given by Applied Spectra, Inc at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about real-time metrology for...

259

Vehicle Technologies Office Merit Review 2014: Efficient Safety and Degradation Modeling of Automotive Li-ion Cells and Pack  

Energy.gov (U.S. Department of Energy (DOE))

Presentation given by EC Power at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about efficient safety and degradation...

260

Design and Development of a Plastic Film Heat Exchanger  

E-Print Network (OSTI)

of the PFHX technology in olving heat. exchange at any pressure other than'atmo pheric pressure. Atmospheric applications could ope ate with a simple remote level control basin. There are also many other potential appl ca tions of the PFHX technology...DESIGN AND DEVELOPMENT OF A PLASTIC FILM HEAT EXCHANGER Eric C. Guyer, Sc.D., David L. Brownell, and Martin K. Gollin Dynatech RID Company Cambridge, Massachusetts ABSTRACT A plastic film heat exchang.er (PFHX) utilizes the low cost...

Guyer, E. C.; Gollin, M. K.; Brownell, D. L.

Note: This page contains sample records for the topic "ion exchange technology" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Heat exchanger  

DOE Patents (OSTI)

A heat exchanger comparising a shell attached at its open end to one side of a tube sheet and a detachable head connected to the other side of said tube sheet. The head is divided into a first and second chamber in fluid communication with a nozzle inlet and nozzle outlet, respectively, formed in said tube sheet. A tube bundle is mounted within said shell and is provided with inlets and outlets formed in said tube sheet in communication with said first and second chambers, respectively.

Brackenbury, Phillip J. (Richland, WA)

1986-01-01T23:59:59.000Z

262

Heat exchanger  

DOE Patents (OSTI)

A heat exchanger comparising a shell attached at its open end to one side of a tube sheet and a detachable head connected to the other side of said tube sheet. The head is divided into a first and second chamber in fluid communication with a nozzle inlet and nozzle outlet, respectively, formed in said tube sheet. A tube bundle is mounted within said shell and is provided with inlets and outlets formed in said tube sheet in communication with said first and second chambers, respectively.

Brackenbury, P.J.

1983-12-08T23:59:59.000Z

263

Building Technologies Office: About Emerging Technologies  

NLE Websites -- All DOE Office Websites (Extended Search)

Emerging Technologies Emerging Technologies The Emerging Technologies team funds the research and development of cost-effective, energy-efficient building technologies within five years of commercialization. Learn more about the: Key Technologies Benefits Results Key Technologies Specific technologies pursued within the Emerging Technologies team include: Lighting: advanced solid-state lighting systems, including core technology research and development, manufacturing R&D, and market development Heating, ventilation, and air conditioning (HVAC): heat pumps, heat exchangers, and working fluids Building Envelope: highly insulating and dynamic windows, cool roofs, building thermal insulation, façades, daylighting, and fenestration Water Heating: heat pump water heaters and solar water heaters

264

Segmented heat exchanger  

DOE Patents (OSTI)

A segmented heat exchanger system for transferring heat energy from an exhaust fluid to a working fluid. The heat exchanger system may include a first heat exchanger for receiving incoming working fluid and the exhaust fluid. The working fluid and exhaust fluid may travel through at least a portion of the first heat exchanger in a parallel flow configuration. In addition, the heat exchanger system may include a second heat exchanger for receiving working fluid from the first heat exchanger and exhaust fluid from a third heat exchanger. The working fluid and exhaust fluid may travel through at least a portion of the second heat exchanger in a counter flow configuration. Furthermore, the heat exchanger system may include a third heat exchanger for receiving working fluid from the second heat exchanger and exhaust fluid from the first heat exchanger. The working fluid and exhaust fluid may travel through at least a portion of the third heat exchanger in a parallel flow configuration.

Baldwin, Darryl Dean (Lafayette, IN); Willi, Martin Leo (Dunlap, IL); Fiveland, Scott Byron (Metamara, IL); Timmons, Kristine Ann (Chillicothe, IL)

2010-12-14T23:59:59.000Z

265

Radioactive ion detector  

DOE Patents (OSTI)

Apparatus for detecting the presence, in aqueous media, of substances which emit alpha and/or beta radiation and determining the oxidation state of these radioactive substances, that is, whether they are in cationic or anionic form. In one embodiment, a sensor assembly has two elements, one comprised of an ion-exchange material which binds cations and the other comprised of an ion-exchange material which binds anions. Each ion-exchange element is further comprised of a scintillation plastic and a photocurrent generator. When a radioactive substance to which the sensor is exposed binds to either element and emits alpha or beta particles, photons produced in the scintillation plastic illuminate the photocurrent generator of that element. Sensing apparatus senses generator output and thereby indicates whether cationic species or anionic species or both are present and also provides an indication of species quantity. 2 figs.

Bower, K.E.; Weeks, D.R.

1997-08-12T23:59:59.000Z

266

Radioactive ion detector  

DOE Patents (OSTI)

Apparatus for detecting the presence, in aqueous media, of substances which emit alpha and/or beta radiation and determining the oxidation state of these radioactive substances, that is, whether they are in cationic or anionic form. In one embodiment, a sensor assembly has two elements, one comprised of an ion-exchange material which binds cations and the other comprised of an ion-exchange material which binds anions. Each ion-exchange element is further comprised of a scintillation plastic and a photocurrent generator. When a radioactive substance to which the sensor is exposed binds to either element and emits alpha or beta particles, photons produced in the scintillation plastic illuminate the photocurrent generator of that element. Sensing apparatus senses generator output and thereby indicates whether cationic species or anionic species or both are present and also provides an indication of species quantity.

Bower, Kenneth E. (Los Alamos, NM); Weeks, Donald R. (Saratoga, CA)

1997-01-01T23:59:59.000Z

267

The Surface Texturing of Monocrystalline Silicon with NH4OH and Ion Implantation for Applications in Solar Cells Compatible with CMOS Technology  

Science Journals Connector (OSTI)

Abstract This work presents the development of photovoltaic cells based on p+/n junction in Si substrates, aimed at compatibility with fabrication processes with CMOS technology. The compatible processes, which are developed in this study, are the techniques: i) Si surface texturing, with the textured surface reflection of 15% obtained by the formation of micro-pyramids (heights between 3 and 7?m) using NH4OH (ammonium hydroxide) alkaline solution, which is free of undesirable contamination by Na+ and K+ ions, when NaOH and KOH traditional solutions are used, respectively, and ii) of the ECR-CVD (Electron Cyclotron Resonance - Chemical Vapor Deposition) deposition of SiNx (silicon nitride) anti-reflective coating (ARC), which is carried out at room temperature and can be performed after the end of cell fabrication without damage on metallic tracks and without variation of p+/n junction depth. The ARC coating characterization presented that the silicon nitride has a refractive index of 1.92 and a minimum reflectance of 1.03%, which is an excellent result for application in solar (or photovoltaic) cells. For the formation of the pn junction was used ion implantation process with 11B+, E=20KeV, dose of 1x1015cm2 and four rotations of 90 to get uniformity on texturized surfaces.

A.R. Silva; J. Miyoshi; J.A. Diniz; I. Doi; J. Godoy

2014-01-01T23:59:59.000Z

268

Microfabricated Ion Traps  

E-Print Network (OSTI)

Ion traps offer the opportunity to study fundamental quantum systems with high level of accuracy highly decoupled from the environment. Individual atomic ions can be controlled and manipulated with electric fields, cooled to the ground state of motion with laser cooling and coherently manipulated using optical and microwave radiation. Microfabricated ion traps hold the advantage of allowing for smaller trap dimensions and better scalability towards large ion trap arrays also making them a vital ingredient for next generation quantum technologies. Here we provide an introduction into the principles and operation of microfabricated ion traps. We show an overview of material and electrical considerations which are vital for the design of such trap structures. We provide guidance in how to choose the appropriate fabrication design, consider different methods for the fabrication of microfabricated ion traps and discuss previously realized structures. We also discuss the phenomenon of anomalous heating of ions within ion traps, which becomes an important factor in the miniaturization of ion traps.

Marcus D. Hughes; Bjoern Lekitsch; Jiddu A. Broersma; Winfried K. Hensinger

2011-06-28T23:59:59.000Z

269

Electron Beam Ion Sources  

E-Print Network (OSTI)

Electron beam ion sources (EBISs) are ion sources that work based on the principle of electron impact ionization, allowing the production of very highly charged ions. The ions produced can be extracted as a DC ion beam as well as ion pulses of different time structures. In comparison to most of the other known ion sources, EBISs feature ion beams with very good beam emittances and a low energy spread. Furthermore, EBISs are excellent sources of photons (X-rays, ultraviolet, extreme ultraviolet, visible light) from highly charged ions. This chapter gives an overview of EBIS physics, the principle of operation, and the known technical solutions. Using examples, the performance of EBISs as well as their applications in various fields of basic research, technology and medicine are discussed.

Zschornacka, G; Thorn, A

2013-01-01T23:59:59.000Z

270

Ion Exchange Kinetics Testing with SRF Resin  

SciTech Connect

The U.S. Department of Energy (DOE) Hanford Site contains more than 53 million gallons of legacy waste generated as a byproduct of plutonium production and reprocessing operations. The wastes are a complex mixture composed mostly of NaNO3, NaNO2, NaOH, NaAlO2, Na3PO4, and Na2SO4, with a number of minor and trace metals, organics, and radionuclides stored in underground waste tanks. The DOE Office of River Protection (ORP) has contracted Bechtel National Incorporated (BNI) to build a pretreatment facility, the River Protection Project-Waste Treatment Plant (RPP-WTP), that will separate long-lived transuranics (TRU) and highly radioactive components (specifically 137Cs and, in selected cases, 90Sr) from the bulk (non-radioactive) constituents and immobilize the wastes by vitrification. The plant is designed to produce two waste streams: a high-volume low-activity waste (LAW) and a low-volume high-activity waste (HLW).

Russell, Renee L.; Rinehart, Donald E.; Brown, Garrett N.; Schonewill, Philip P.; Peterson, Reid A.

2012-04-01T23:59:59.000Z

271

Ion exchange as a tertiary treatment  

E-Print Network (OSTI)

that these treatment methods are capable of removing an appreciable amount of objection? able dissolved organic and inorganic materi aJ s from the final effluent. Color and turbidity were greatly reduced and an appreciable amount of the suspended solids were... Demand Re Resin A General Anion mg. /1. MLVSS psi gpm Milligrams per I. iter Mixed Liquor Volatile Suspended Solids Pounds per Square Inch Gallons per Minute. mm Mi llimeters kgr meq ml Kilogram Milliequilavent Millimeter S. S. BV...

Westervelt, Ronald David

1968-01-01T23:59:59.000Z

272

Psychology on Exchange InternationalExchangeProgram  

E-Print Network (OSTI)

Psychology on Exchange InternationalExchangeProgram Psychology majors are welcome to apply Honours, you need to take into account the advice from the Department of Psychology (http://sydney.edu.au/ current_students/student_exchange/forms_downloads.shtml). Timing To meet Australian Psychology

Viglas, Anastasios

273

Scaling the Ion Trap Quantum Processor  

Science Journals Connector (OSTI)

...atomic ion species to act as "refrigerator" ions to quench the...scale beyond the QCCD in a modular architecture, one can link separate...trapped ion technology. (A) Modular distributed...A major challenge in both modular quantum computer...

C. Monroe; J. Kim

2013-03-08T23:59:59.000Z

274

A New Hybrid Proton-Exchange-Membrane Fuel Cells-Battery Power System with Efficiencies Considered  

Science Journals Connector (OSTI)

Hybrid systems, based on lead-acid or lithium-ion batteries and proton-exchange-membrane fuel cells (PEMFCs), give the possibility of ... results show that the combination of lead-acid batteries or lithium-ion batteries

Chung-Hsing Chao; Jenn-Jong Shieh

2013-01-01T23:59:59.000Z

275

Vehicle Technologies Office Merit Review 2014: Characterization...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Characterization of Voltage Fade in Lithium-ion Cells with Layered Oxides Vehicle Technologies Office Merit Review 2014: Characterization of Voltage Fade in Lithium-ion Cells with...

276

Woven heat exchanger  

DOE Patents (OSTI)

This invention relates to a heat exchanger for waste heat recovery from high temperature industrial exhaust streams. In a woven ceramic heat exchanger using the basic tube-in-shell design, each heat exchanger consisting of tube sheets and tube, is woven separately. Individual heat exchangers are assembled in cross-flow configuration. Each heat exchanger is woven from high temperature ceramic fiber, the warp is continuous from tube to tube sheet providing a smooth transition and unitized construction.

Piscitella, R.R.

1984-07-16T23:59:59.000Z

277

Manufacturing Science and Technology: Technologies  

NLE Websites -- All DOE Office Websites (Extended Search)

Ion Beam Manufacture Ion Beam Manufacture PDF format (113 kb) Example sine wave FIB sputtered into initially planar Si substrate Example sine wave FIB sputtered into initially planar Si substrate Sandia Manufacturing Science & Technology's Focused Ion Beam (FIB) laboratory provides an opportunity for research, development and prototyping. Currently, our scientists are developing methods for ion beam sculpting microscale tools, components and devices. This includes shaping of specialty tools such as end-mills, turning tools and indenters. Many of these have been used in ultra-precision machining DOE applications. Additionally, staff are developing the capability to ion mill geometrically-complex features and substrates. This includes the ability to sputter predetermined curved shapes of various symmetries and

278

Optimized Anion Exchange Membranes for Vanadium Redox Flow Batteries  

Science Journals Connector (OSTI)

vanadium redox flow battery; anion exchange membrane; ion exchange capacity; cycling performance; power density ... All electrochemical measurements were conducted using a fully automated redox flow battery testing system (Scribner 857 Redox Flow Cell System). ... Characteristics of a new all-vanadium redox flow battery ...

Dongyang Chen; Michael A. Hickner; Ertan Agar; E. Caglan Kumbur

2013-06-25T23:59:59.000Z

279

Office of Waste Processing Technical Exchange  

NLE Websites -- All DOE Office Websites (Extended Search)

Agenda Hotel Register Contacts Event Media Speaker Information Home Agenda Hotel Register Contacts Event Media Speaker Information Home Environmental Management Waste Processing Technical Exchange 2010 in Atlanta, GA, November 16 - 18. Over the past eight years, personnel from the three sites, Savannah River/Hanford/Idaho along with others receiving funding from the Environmental Management Office of Waste Processing have met to exchange recent results of on-going field operations and technology development. The purpose of this exchange is to provide a forum for discussion of each Site's efforts to accelerate cleanup operations. Keys to success and lessons learned are openly exchanged in a manner to allow for open discussion between operations, engineering and scientists to accelerate transition of technologies from concepts to field implementation.

280

Two-dimensional spectroscopy for the study of ion Coulomb crystals  

E-Print Network (OSTI)

Ion Coulomb crystals are currently establishing themselves as a highly controllable test-bed for mesoscopic systems of statistical mechanics. The detailed experimental interrogation of the dynamics of these crystals however remains an experimental challenge. In this work, we show how to extend the concepts of multi-dimensional nonlinear spectroscopy to the study of the dynamics of ion Coulomb crystals. The scheme we present can be realized with state-of-the-art technology and gives direct access to the dynamics, revealing nonlinear couplings even in systems with many ions and in the presence of thermal excitations. We illustrate the advantages of our proposal showing how two-dimensional spectroscopy can be used to detect signatures of a structural phase transition of the ion crystal, as well as resonant energy exchange between modes. Furthermore, we demonstrate in these examples how different decoherence mechanisms can be identified.

A. Lemmer; C. Cormick; C. T. Schmiegelow; F. Schmidt-Kaler; M. B. Plenio

2014-07-03T23:59:59.000Z

Note: This page contains sample records for the topic "ion exchange technology" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Korea Power Exchange (KPX) | Open Energy Information  

Open Energy Info (EERE)

Exchange (KPX) Exchange (KPX) Jump to: navigation, search Logo: Korea Power Exchange (KPX) Name Korea Power Exchange (KPX) Agency/Company /Organization Argonne National Laboratory Sector Energy Focus Area Energy Efficiency Topics Background analysis Website http://www.dis.anl.gov/news/Ko Country South Korea Eastern Asia References http://www.dis.anl.gov/news/KoreaKpxIit.html Abstract In an agreement signed on March 26, 2007, Argonne National Laboratory and the Illinois Institute of Technology are joining with the Korea Power Exchange to establish a joint training program combining training and research at Argonne with formal academic education at IIT. Argonne-IIT Joint Graduate Program in Electricity Markets: In an agreement signed on March 26, 2007, Argonne National Laboratory and the Illinois

282

Multicomponent Adsorption Study of Metal Ions onto Bagasse Fly Ash Using Taguchi's Design of Experimental Methodology  

Science Journals Connector (OSTI)

Department of Chemical Engineering, Indian Institute of Technology?Roorkee, Roorkee 247667, India ... Adsorption technologies for metals wastes include activated carbon and ion exchange treatment. ... The concentration of Cd(II), Ni(II), and Zn(II) in the aqueous samples was determined using a flame atomic absorption spectrophotometer (GBC Avanta, Australia) with the detection limit of 0.009, 0.040, and 0.008 mg/L at wavelengths of 228.8, 232, and 213.9 nm, for Cd(II), Ni(II), and Zn(II), respectively, using an air?acetylene flame. ...

Vimal C. Srivastava; Indra D. Mall; Indra M. Mishra

2007-07-14T23:59:59.000Z

283

Intracellular Sequestration of Sodium by a Novel Na /H Exchanger in Yeast Is Enhanced by Mutations in the  

E-Print Network (OSTI)

membrane Na /K -ATPase, a P-type ion pump, that drives Na ions out of the cell in exchange for K ions (1). The resultant Na gradient serves as the primary energy source for the transport of other ions and metabolites threat to agricultural production worldwide (4, 5). Because of a basic similarity in ion transport

Rao, Rajini

284

Cesium and Strontium Specific Exchangers for Nuclear Waste Effluent Remediation  

SciTech Connect

During the past 50 years, nuclear defense activities have produced large quantities of nuclear waste that now require safe and permanent disposal. The general procedure to be implemented involves the removal of cesium and strontium from the waste solutions for disposal in permanently vitrified media. This requires highly selective sorbents or ion exchangers. Further, at the high radiation doses present in the solution, organic exchangers or sequestrants are likely to decompose over time. Inorganic ion exchangers are resistant to radiation damage and can exhibit remarkably high selectivities. We have synthesized three families of tunnel-type ion exchangers. The crystal structures of these compounds as well as their protonated phases, coupled with ion exchange titrations, were determined and this information was used to develop an understanding of their ion exchange behavior. The ion exchange selectivities of these phases could be regulated by isomorphous replacement of the framework metals by larger or smaller radius metals. In the realm of layered compounds, we prepared alumina, silica, and zirconia pillared clays and sodium micas. The pillared clays yielded very high Kd values for Cs+ and were very effective in removing Cs+ from groundwaters. The sodium micas also had a high affinity for Cs+ but an even greater attraction for S42+. They also possess the property of trapping these ions permanently as the layers slowly decrease their interlayer distance as loading occurs. Sodium nonatitanate exhibited extremely high Kd values for Sr2+ in alkaline tank wastes and should be considered for removal of Sr2+ in such cases. For tank wastes containing complexing agents, we have found that adding Ca2+ to the solution releases the complexed Sr2+ which may then be removed with the CST exchanger.

A. Clearfield; A. I. Bortun; L. A. Bortun; E. A. Bhlume; P. Sylvester; G. M. Graziano

2000-09-01T23:59:59.000Z

285

Potassium-Calcium Exchange in a Multireactive Soil System: II. Thermodynamics1 P. M. JARDINE ANDD. L. SPARKS2  

E-Print Network (OSTI)

ions and sup- ports the hypothesis of the multireactive natureof the soil. Although K was selectively energy of ex- change, enthalpy of exchange, entropy of exchange. Jardine, P.M., and D.L. Sparks. 1984

Sparks, Donald L.

286

Transport of copper ammines through a cation-exchange membrane during electrodialysis  

SciTech Connect

Extraction of copper ammine complexes from waste waters in electroplating technology and in production of cuprammonium fibers is an important problem and electrodialysis with ion-exchange membranes is the most promising method of solving it. The authors aim was to study transport of copper(II) ammines through a commercial cation-exchange membrane of the MK-40 type. The electrodialyzer consisted of five Plexiglas compartments separated in alternating order by MK-40 cation-exchange and MA-40 anion-exchange membranes. The authors studied the dependence of the transport of copper(II) ammine complexes on the current density at copper concentration 0.025 M in the desalination compartment and 0.15 M ammonia concentration. The experiments lead to the conclusion that electrodialysis of copper(II) ammine complexes is possible only at current densities below the limiting values and that the transport is accompanied by decrease of the formation function of the complexes both in the membrane and in the solution of the concentrate receiving compartment.

Kireeva, L.D.; Shaposhnik, V.A.; Sorokina, V.I.

1987-09-10T23:59:59.000Z

287

Heat Exchanger Technologies for Distillation Columns  

E-Print Network (OSTI)

Conference, Houston, TX, April 16-19, 2002 Downcomer Ii IMass Transfer Ales I Hem Transrer Surf':lce I I I i i i i IDo-.>m" I Vapour Flow Figure 5. Alternative Inlegral Condenser Design Engineers unfamiliar with the thermodynamics of distillation...

Polley, G. T.

288

Li-Ion Battery Cell Manufacturing | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Li-Ion Battery Cell Manufacturing Li-Ion Battery Cell Manufacturing 2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer...

289

Building America Technology Solutions for New and Existing Homes...  

Energy Savers (EERE)

America Technology Solutions for New and Existing Homes: Foundation Heat Exchanger, Oak Ridge, Tennessee Building America Technology Solutions for New and Existing Homes:...

290

Handbook of Zeolite Science and Technology Edited by Scott M. Auerbach (University of Massachusetts, Amherst), Kathleen A. Carrado (Argonne National Laboratory), Prabir K. Dutta (The Ohio State University). Marcel Dekker, Inc.:? New York, Basel. 2003. xii + 1184 pp. $235.00. ISBN 0-8247-4020-3.  

Science Journals Connector (OSTI)

Handbook of Zeolite Science and Technology Edited by Scott M. Auerbach (University of Massachusetts, Amherst), Kathleen A. Carrado (Argonne National Laboratory), Prabir K. Dutta (The Ohio State University). ... Parts IV and V cover traditional applications such as catalysis, ion exchange, and gas separations, but also include surveys of zeolite applications in photonics, organic photochemistry, electrochemistry, nuclear waste management, and medical applications. ...

Kendall T. Thomson

2004-06-17T23:59:59.000Z

291

VOLUME 76, NUMBER 1 P H Y S I C A L R E V I E W L E T T E R S 1 JANUARY 1996 First Study of Heavy-Ion Mirror Charge Exchange  

E-Print Network (OSTI)

are nuclear reaction studies with mirror nuclear pairs, since only one member of a mirror pair can be stable accessible excitation energy range. Charge-exchange p, n reactions at energies above 100 MeV have long been, since they involve the detection of rather low-energy neutrons. Furthermore, experiments in the b1

Bertulani, Carlos A. - Department of Physics and Astronomy, Texas A&M University

292

Highly Polarized Ion Sources for Electron Ion Colliders (EIC)  

SciTech Connect

The operation of the RHIC facility at BNL and the Electron Ion Colliders (EIC) under development at Jefferson Laboratory and BNL need high brightness ion beams with the highest polarization. Charge exchange injection into a storage ring or synchrotron and Siberian snakes have the potential to handle the needed polarized beam currents, but first the ion sources must create beams with the highest possible polarization to maximize collider productivity, which is proportional to a high power of the polarization. We are developing one universal H-/D- ion source design which will synthesize the most advanced developments in the field of polarized ion sources to provide high current, high brightness, ion beams with greater than 90% polarization, good lifetime, high reliability, and good power efficiency. The new source will be an advanced version of an atomic beam polarized ion source (ABPIS) with resonant charge exchange ionization by negative ions. An integrated ABPIS design will be prepared based on new materials and an optimized magnetic focusing system. Polarized atomic and ion beam formation, extraction, and transport for the new source will be computer simulated.

V.G. Dudnikov, R.P. Johnson, Y.S. Derbenev, Y. Zhang

2010-03-01T23:59:59.000Z

293

Ion Beam Materials Lab  

NLE Websites -- All DOE Office Websites (Extended Search)

Facilities » Facilities » Ion Beam Materials Lab Ion Beam Materials Lab A new research frontier awaits! Our door is open and we thrive on mutually beneficial partnerships, collaborations that drive innovations and new technologies. April 12, 2012 Ion Beam Danfysik Implanter High Voltage Terminal. Contact Yongqiang Wang (505) 665-1596 Email Devoted to the characterization and modification of surfaces through the use of ion beams The Ion Beam Materials Laboratory (IBML) is a Los Alamos National Laboratory resource devoted to the characterization and modification of surfaces through the use of ion beams. The IBML provides and operates the core facilities, while supporting the design and implementation of specific apparati needed for experiments requested by users of the facility. The result is a facility with

294

Utilization of UV or EB Curing Technology to Significantly Reduce Costs and VOCs in the Manufacture of Lithium-Ion Battery Electrodes  

Energy.gov (U.S. Department of Energy (DOE))

2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

295

Utilization of UV or EB Curing Technology to Significantly Reduce Costs and VOCs in the Manufacture of Lithium-Ion Battery Electrodes  

Energy.gov (U.S. Department of Energy (DOE))

2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

296

Discovery and Early Development of Non-Suppressed Ion Chromatography  

Science Journals Connector (OSTI)

......charge on cation-exchange materials caused a mixture of the resins...Then the chloromethylated materials were converted into ion exchangers...few months later that year, Bill Rich, the Vice President of...stress corrosion cracking of turbine blades. Ion chromatography......

James S. Fritz; Douglas T. Gjerde

2010-08-01T23:59:59.000Z

297

Ion source  

DOE Patents (OSTI)

A magnetic filter for an ion source reduces the production of undesired ion species and improves the ion beam quality. High-energy ionizing electrons are confined by the magnetic filter to an ion source region, where the high-energy electrons ionize gas molecules. One embodiment of the magnetic filter uses permanent magnets oriented to establish a magnetic field transverse to the direction of travel of ions from the ion source region to the ion extraction region. In another embodiment, low energy 16 eV electrons are injected into the ion source to dissociate gas molecules and undesired ion species into desired ion species.

Leung, Ka-Ngo (Hercules, CA); Ehlers, Kenneth W. (Alamo, CA)

1984-01-01T23:59:59.000Z

298

High-resolution studies of charge exchange in supernova remnants with Magellan, XMM-Newton, and Micro-X  

E-Print Network (OSTI)

Charge exchange, the semi-resonant transfer of an electron from a neutral atom to an excited state in an energetic ion, can occur in plasmas where energetic ions are incident on a cold, at least partially neutral gas. ...

Heine, Sarah Nicole Trowbridge

2014-01-01T23:59:59.000Z

299

HVAC Radial Air Bearing Heat Exchangers Research Project | Department of  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Radial Air Bearing Heat Exchangers Radial Air Bearing Heat Exchangers Research Project HVAC Radial Air Bearing Heat Exchangers Research Project The U.S. Department of Energy is currently conducting research into heating, ventilation, and air conditioning (HVAC) radial air bearing heat exchangers. Rotary air bearing heat exchanger technology simultaneously solves four long standing problems of conventional "fan-plus-finned-heat-sink" heat exchangers. Project Description This project seeks to design, fabricate, and test successive generations of prototype radial air bearing heat exchanger devices based on lessons learned and further insights into device optimization, computational fluid dynamic studies for parametric optimization and determination of scaling laws, and laboratory measurement of flow field and heat transfer

300

Technology Analysis  

NLE Websites -- All DOE Office Websites (Extended Search)

* Heavy Vehicle Technologies * Heavy Vehicle Technologies * Multi-Path Transportation Futures * Idling Studies * EDrive Vehicle Monthly Sales Transportation Research and Analysis Computing Center Working With Argonne Contact TTRDC Technology Analysis truck Heavy vehicle techologies are one subject of study. Research Reducing Greenhouse Gas Emissions from U.S. Transportation Heavy Vehicle Technologies Multi-Path Transportation Futures Study Idling Studies Light Duty Electric Drive Vehicles Monthly Sales Updates Lithium-Ion Battery Recycling and Life Cycle Analysis Reports Propane Vehicles: Status, Challenges, and Opportunities (pdf; 525 kB) Natural Gas Vehicles: Status, Barriers, and Opportunities (pdf; 696 kB) Regulatory Influences That Will Likely Affect Success of Plug-in Hybrid and Battery Electric Vehicles (pdf; 1.02 MB)

Note: This page contains sample records for the topic "ion exchange technology" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Engineering of microorganisms towards recovery of rare metal ions  

Science Journals Connector (OSTI)

The bioadsorption of metal ions using microorganisms is an attractive technology for the recovery of rare metal ions as well as removal of toxic heavy metal ions from aqueous solution. In initial attempts, microo...

Kouichi Kuroda; Mitsuyoshi Ueda

2010-06-01T23:59:59.000Z

302

A model for improvement of water heating heat exchanger designs for residential heat pump water heaters.  

E-Print Network (OSTI)

??Heat pump water heaters are a promising technology to reduce energy use and greenhouse gas emissions. A key component is the water heating heat exchanger. (more)

Weerawoot, Arunwattana

2010-01-01T23:59:59.000Z

303

Vehicle Technologies Office Merit Review 2014: Modular Process Equipment for Low Cost Manufacturing of High Capacity Prismatic Li-Ion Cell Alloy Anodes  

Energy.gov (U.S. Department of Energy (DOE))

Presentation given by Applied Materials at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about modular process equipment...

304

Lithium Ion Accomplishments  

NLE Websites -- All DOE Office Websites (Extended Search)

Lithium ion Battery Commercialization Lithium ion Battery Commercialization Johnson Controls-Saft Advanced Power Solutions, of Milwaukee, Wisconsin: Johnson Controls-Saft (JCS) will supply lithium-ion batteries to Mercedes for their S Class Hybrid to be introduced in October 2009. Technology developed with DOE support (the VL6P cell) will be used in the S Class battery. In May 2006, the Johnson Controls-Saft Joint Venture was awarded a 24 month $14.4 million contract by the DOE/USABC to develop a 40kW Li ion HEV battery system offering improved safety, low temperature performance, and cost. JCS has reported a 40% cost reduction of the 40kW system being developed in their DOE/USABC contract while maintaining performance. Lithium Ion Battery Material Commercialization Argonne National Laboratory has licensed cathode materials and associated processing

305

Architecture on Exchange InternationalExchangeProgram  

E-Print Network (OSTI)

. Previous students have attended: · McMaster University, Canada · Malmö University, Sweden · University of Leeds, United Kingdom · Northeastern University, USA · Purdue University, USA · University of California on page 2 5 International Office Study Abroad and Exchange Program Level 4, Jane Foss Russell Building (G

Viglas, Anastasios

306

Agriculture on Exchange InternationalExchangeProgram  

E-Print Network (OSTI)

-wide exchange destinations for Agriculture majors include: Canada....................McGill University, Faculty of Arts (AgEc only) (www.umanitoba.ca) United Kingdom.....University of Leeds, School of Earth and Environment (www.leeds.ac.uk) .................................University of Nottingham, School of Biosciences

Viglas, Anastasios

307

Uniform insulation applied-B ion diode  

DOE Patents (OSTI)

An applied-B field extraction ion diode has uniform insulation over an anode surface for increased efficiency. When the uniform insulation is accomplished with anode coils, and a charge-exchange foil is properly placed, the ions may be focused at a point on the z axis.

Seidel, David B. (Albuquerque, NM); Slutz, Stephen A. (Albuquerque, NM)

1988-01-01T23:59:59.000Z

308

Vehicle Technologies Office Merit Review 2014: Development of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Development of Electrolytes for Lithium-ion Batteries Vehicle Technologies Office Merit Review 2014: Development of Electrolytes for Lithium-ion Batteries Presentation given by...

309

Vehicle Technologies Office Merit Review 2014: Studies on High...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Studies on High Capacity Cathodes for Advanced Lithium-ion Systems Vehicle Technologies Office Merit Review 2014: Studies on High Capacity Cathodes for Advanced Lithium-ion Systems...

310

Vehicle Technologies Office Merit Review 2014: Fluorinated Electrolyte...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Fluorinated Electrolyte for 5-V Li-Ion Chemistry Vehicle Technologies Office Merit Review 2014: Fluorinated Electrolyte for 5-V Li-Ion Chemistry Presentation given by Argonne...

311

Sandia National Laboratories: ion beam assisted deposition  

NLE Websites -- All DOE Office Websites (Extended Search)

ion beam assisted deposition Sandia, Los Alamos, Superconducting Technologies Inc., & Superpower: Solution Deposition Planarization On March 20, 2013, in CINT, Facilities, Grid...

312

About Emerging Technologies | Department of Energy  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Emerging Technologies » About Emerging Technologies Emerging Technologies » About Emerging Technologies About Emerging Technologies The Emerging Technologies team funds the research and development of cost-effective, energy-efficient building technologies within five years of commercialization. Learn more about the: Key Technologies Benefits Results Key Technologies Specific technologies pursued within the Emerging Technologies team include: Lighting: advanced solid-state lighting systems, including core technology research and development, manufacturing R&D, and market development Heating, ventilation, and air conditioning (HVAC): heat pumps, heat exchangers, and working fluids Building Envelope: highly insulating and dynamic windows, cool roofs, building thermal insulation, façades, daylighting, and fenestration

313

Charge exchange recombination spectroscopy on fusion devices  

SciTech Connect

For fusion, obtaining reliable measurements of basic plasma parameters like ion and electron densities and temperatures is a primary goal. For theory, measurements are needed as a function of time and space to understand plasma transport and confinement with the ultimate goal of achieving economic nuclear fusion power. Electron profile measurements and plasma spectroscopy for the plasma ions are introduced. With the advent of Neutral Beam auxiliary plasma heating, Charge Exchange Recombination Spectroscopy provides accurate and time resolved measurements of the ions in large volume fusion devices. In acknowledgement of Nicol Peacock's role in the development of these techniques, still at the forefront of plasma fusion research, this paper describes the evolution of this diagnostic method.

Duval, B. P. [Centre de Recherches en Physique des Plasmas, EPFL, Lausanne (Switzerland)

2012-05-25T23:59:59.000Z

314

IonBeamMicroFab  

NLE Websites -- All DOE Office Websites (Extended Search)

Ion Beam Manufacture of Microscale Ion Beam Manufacture of Microscale Tools and Components Manufacturing Technologies Sandia Manufacturing Science &Technology's Focused Ion Beam (FIB) laboratory provides an opportunity for research, development and prototyping. Currently, our scientists are devel- oping methods for ion beam sculpting microscale tools, components and devices. This includes shaping of specialty tools such as end-mills, turning tools and indenters. Many of these have been used in ultra-precision machining DOE applications. Additionally, staff are developing the capability to ion mill geo- metrically-complex features and substrates. This includes the ability to sputter predeter- mined curved shapes of various symmetries and periodicities. Capabilities and Expertise * Two custom-built focused ion beam sys-

315

Wound tube heat exchanger  

DOE Patents (OSTI)

What is disclosed is a wound tube heat exchanger in which a plurality of tubes having flattened areas are held contiguous adjacent flattened areas of tubes by a plurality of windings to give a double walled heat exchanger. The plurality of windings serve as a plurality of effective force vectors holding the conduits contiguous heat conducting walls of another conduit and result in highly efficient heat transfer. The resulting heat exchange bundle is economical and can be coiled into the desired shape. Also disclosed are specific embodiments such as the one in which the tubes are expanded against their windings after being coiled to insure highly efficient heat transfer.

Ecker, Amir L. (Duncanville, TX)

1983-01-01T23:59:59.000Z

316

Vehicle Technologies Office Merit Review 2014: High Energy Density Li-ion Cells for EVs Based on Novel, High Voltage Cathode Material Systems  

Energy.gov (U.S. Department of Energy (DOE))

Presentation given by Farasis Energy, Inc. at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about high energy density Li...

317

Vehicle Technologies Office Merit Review 2014: Development of Cell/Pack Level Models for Automotive Li-Ion Batteries with Experimental Validation  

Energy.gov (U.S. Department of Energy (DOE))

Presentation given by EC Power at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about evelopment of cell/pack level models...

318

Green Exchange | Open Energy Information  

Open Energy Info (EERE)

Exchange Place: New York, New York Zip: NY 10282 Product: String representation "The Green Excha ... es marketplace." is too long. References: Green Exchange1 This article is a...

319

E-Print Network 3.0 - aluminium ions Sample Search Results  

NLE Websites -- All DOE Office Websites (Extended Search)

Otty, Mass and heat transfer in ion-exchange membranes (1996) 7. Belinda Flem, Peltier... heats in cryolite melts with alumina (1996) 8. Ellen Marie Hansen, Modelling of...

320

Active microchannel heat exchanger  

DOE Patents (OSTI)

The present invention is an active microchannel heat exchanger with an active heat source and with microchannel architecture. The microchannel heat exchanger has (a) an exothermic reaction chamber; (b) an exhaust chamber; and (c) a heat exchanger chamber in thermal contact with the exhaust chamber, wherein (d) heat from the exothermic reaction chamber is convected by an exothermic reaction exhaust through the exhaust chamber and by conduction through a containment wall to the working fluid in the heat exchanger chamber thereby raising a temperature of the working fluid. The invention is particularly useful as a liquid fuel vaporizer and/or a steam generator for fuel cell power systems, and as a heat source for sustaining endothermic chemical reactions and initiating exothermic reactions.

Tonkovich, Anna Lee Y. (Pasco, WA) [Pasco, WA; Roberts, Gary L. (West Richland, WA) [West Richland, WA; Call, Charles J. (Pasco, WA) [Pasco, WA; Wegeng, Robert S. (Richland, WA) [Richland, WA; Wang, Yong (Richland, WA) [Richland, WA

2001-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "ion exchange technology" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

On a cryogenic noble gas ion catcher  

E-Print Network (OSTI)

In-situ purification of the gas used as stopping medium in a noble gas ion catcher by operating the device at low temperatures of 60 to 150 K was investigated. Alpha-decay recoil ions from a 223Ra source served as energetic probes. The combined ion survival and transport efficiencies for 219Rn ions saturated below about 90 K, reaching 28.7(17) % in helium, 22.1(13) % in neon, and 17.0(10) % in argon. These values may well reflect the charge exchange and stripping cross sections during the slowing down of the ions, and thus represent a fundamental upper limit for the efficiency of noble gas ion catcher devices. We suggest the cryogenic noble gas ion catcher as a technically simpler alternative to the ultra-high purity noble gas ion catcher operating at room temperature.

P. Dendooven; S. Purushothaman; K. Gloos

2005-10-20T23:59:59.000Z

322

Metrics for the cost of proprietary information exchange languages in intelligent systems  

Science Journals Connector (OSTI)

The increasing number of intelligent software components is accompanied by an increasing number of proprietary information exchange languages between components. One of the challenges for the smart technology worker is to achieve intelligent system component ... Keywords: information, information exchange languages, information exchange standards, intelligent system components, intelligent systems, interoperability, interoperability cost metrics, interoperability costs, interoperability metrics, interoperability risk metrics, metrics, proprietary exchange languages, return on investment, standard languages, standards

John Horst; Nathan Hartman; George Wong

2010-09-01T23:59:59.000Z

323

(Environmental technology)  

SciTech Connect

The traveler participated in a conference on environmental technology in Paris, sponsored by the US Embassy-Paris, US Environmental Protection Agency (EPA), the French Environmental Ministry, and others. The traveler sat on a panel for environmental aspects of energy technology and made a presentation on the potential contributions of Oak Ridge National Laboratory (ORNL) to a planned French-American Environmental Technologies Institute in Chattanooga, Tennessee, and Evry, France. This institute would provide opportunities for international cooperation on environmental issues and technology transfer related to environmental protection, monitoring, and restoration at US Department of Energy (DOE) facilities. The traveler also attended the Fourth International Conference on Environmental Contamination in Barcelona. Conference topics included environmental chemistry, land disposal of wastes, treatment of toxic wastes, micropollutants, trace organics, artificial radionuclides in the environment, and the use biomonitoring and biosystems for environmental assessment. The traveler presented a paper on The Fate of Radionuclides in Sewage Sludge Applied to Land.'' Those findings corresponded well with results from studies addressing the fate of fallout radionuclides from the Chernobyl nuclear accident. There was an exchange of new information on a number of topics of interest to DOE waste management and environmental restoration needs.

Boston, H.L.

1990-10-12T23:59:59.000Z

324

Ion collection by a conducting sphere in a magnetized or drifting collisional plasma  

E-Print Network (OSTI)

Ion collection by dust grains and probes in plasmas with a neutral background is of interest in the study of both space and terrestrial plasmas, where charge-exchange collisions can play an important role in ion collection. ...

Haakonsen, Christian Bernt, 1985-

2011-01-01T23:59:59.000Z

325

LANL: Ion Beam Materials Laboratory  

NLE Websites -- All DOE Office Websites (Extended Search)

Ion Beam Materials Laboratory (IBML) is a Los Ion Beam Materials Laboratory (IBML) is a Los Alamos National Laboratory resource devoted to materi- als research through the use of ion beams. Current major research areas include surface characterization through ion beam analysis techniques, surface modification and materials synthesis through ion implantation technology, and radiation damage stud- ies in gases, liquids, and solids. The laboratory's core is a 3.2 MV tandem ion accelerator and a 200 kV ion implanter together with several beam lines. Attached to each beam line is a series of experimental stations that support various research programs. The operation of IBML and its interactions with users are organized around core facilities and experimental stations. The IBML provides and operates the core facilities as well as supports

326

Material properties of cation exchange membranes for chloralkali electrolysis, water electrolysis and fuel cells  

Science Journals Connector (OSTI)

Owing to the development of perfluorinated ion-exchange membranes, the application of the membranes in electrochemical cells has advanced greatly, especially in chloralkali electrolysis. Material properties of pe...

T. Asawa

1989-07-01T23:59:59.000Z

327

Vehicle Technologies Office Merit Review 2014: Utilization of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

or EB Curing Technology to Significantly Reduce Costs and VOCs in the Manufacture of Lithium-Ion Battery Electrodes Vehicle Technologies Office Merit Review 2014: Utilization of...

328

Utilization of UV or EB Curing Technology to Significantly Reduce...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

or EB Curing Technology to Significantly Reduce Costs and VOCs in the Manufacture of Lithium-Ion Battery Electrodes Utilization of UV or EB Curing Technology to Significantly...

329

Silane discharge ion chemistry  

SciTech Connect

Silane dc, rf, and dc proximity discharges have been studied using mass spectroscopic measurements of the positive ions as a detailed diagnostic for the type of discharge used to produce hydrogenated amorphous silicon solar photovoltaic cells. The properties and quality of these films depends in a very complex way upon the interactions of the many reactive neutral and ion species in the discharge. Qualitative models of the ion chemical processes in these discharges have been developed from experimental measurements. Knowledge of the ion-molecule and electron-molecule collision cross sections is important to any attempt at understanding silane discharge chemistry. Consequently, the electron impact ionization cross sections for silane and disilane have been measured and for comparison purposes also for methane and ethane. In addition, the rate coefficients for charge exchange reactions of He , Ne , and Ar with silane, disilane, methane, and ethane have been measured as these are important to understanding discharges in inert gas-silane mixtures. A detailed quantitative model of the cathode sheath region of a silane dc discharge has been developed by extending the best recent calculation of the electron motion in the sheath to a self-consistent form which includes the ion motion. This model is used with comparison of silane dc discharge data to diagnose the ion chemistry occurring in the sheath region of silane dc discharge. The understanding of the discharge ion chemical processes that have been gained in this study represent an important step toward understanding the chemical and physical processes leading to film growth.

Chatham, R.H. III

1984-01-01T23:59:59.000Z

330

Accelerator development for heavy ion fusion  

SciTech Connect

Accelerator technology development is presented for heavy ion drivers used in inertial confinement fusion. The program includes construction of low-velocity ''test bed'' accelerator facilities, development of analytical and experimental techniques to characterize ion beam behavior, and the study of ion beam energy deposition.

Talbert, W.L. Jr.; Sawyer, G.A.

1980-01-01T23:59:59.000Z

331

Significant Cost Improvement of Li-Ion Cells Through Non-NMP...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Significant Cost Improvement of Li-Ion Cells Through Non-NMP Electrode Coating, Direct Separator Coating, and Fast Formation Technologies Significant Cost Improvement of Li-Ion...

332

Thermal Analysis of Lithium-Ion Battery Packs and Thermal Management Solutions.  

E-Print Network (OSTI)

??Lithium ion (Li-ion) batteries have been gaining recognition as the primary technology for energy storage in motive applications due to their improved specific energy densities, (more)

Bhatia, Padampat Chander

2013-01-01T23:59:59.000Z

333

Deep-Sea Research I 53 (2006) 684688 Experimental evaluation of the isotopic exchange equilibrium  

E-Print Network (OSTI)

on the ion-exchange separation of boron isotopes. Bulletin of Chemical Society of Japan 50, 158­163]. Since strengths. r 2006 Elsevier Ltd. All rights reserved. Keywords: Boron isotopes; Boron isotopic exchange. Introduction The boron isotopic composition of marine carbonates constitutes a promising tracer of the paleo

Kaufman, Alan Jay

334

Oligoacetic Acid Characterization by Isocratic and Linear Salt Gradient Anion-Exchange Chromatography  

Science Journals Connector (OSTI)

......ion-exchange Gibbs free energy (Gexchange) was calcu...constant increment in the energy of exchange for the addition...as the increment per car- boxylic acid group...oligomers provided an alternative and convenient method...calculation of the Gibbs free energy of adsorption for biomolecules......

Hong Li; Costas S. Patrickios

2001-03-01T23:59:59.000Z

335

Charge-exchange collisions in interpenetrating laser-produced magnesium plasmas  

E-Print Network (OSTI)

Charge-exchange collisions in interpenetrating laser-produced magnesium plasmas S.S. HARILAL,1 C charge-exchange collisions between highly charged Mg ions in colliding laser-produced magnesium plasmas magnesium plasmas. 1. INTRODUCTION Several applications of laser-produced plasmas involve an experimental

Harilal, S. S.

336

Manufacturing Science and Technology: Technologies  

NLE Websites -- All DOE Office Websites (Extended Search)

Thin Films Thin Films PDF format (189 kb) Multi Layer Thin Films Multi Layer Thin Films Planetary Sputtering SystemsPlanetary Sputtering Systems Planetary Sputtering Systems The Thin Film laboratory within Manufacturing Science & Technology provides a variety of vapor deposition processes and facilities for cooperative research and development. Available capabilities include electron beam evaporation, sputter deposition, reactive deposition processes, atomic layer deposition (ALD) and specialized techniques such as focused ion beam induced chemical vapor deposition. Equipment can be reconfigured for prototyping or it can be dedicated to long-term research, development and manufacturing. Most sputter and evaporative deposition systems are capable of depositing multiple materials.

337

Diffusion-Welded Microchannel Heat Exchanger for Industrial Processes  

SciTech Connect

The goal of next generation reactors is to increase energy ef?ciency in the production of electricity and provide high-temperature heat for industrial processes. The ef?cient transfer of energy for industrial applications depends on the ability to incorporate effective heat exchangers between the nuclear heat transport system and the industrial process. The need for ef?ciency, compactness, and safety challenge the boundaries of existing heat exchanger technology. Various studies have been performed in attempts to update the secondary heat exchanger that is downstream of the primary heat exchanger, mostly because its performance is strongly tied to the ability to employ more ef?cient industrial processes. Modern compact heat exchangers can provide high compactness, a measure of the ratio of surface area-to-volume of a heat exchange. The microchannel heat exchanger studied here is a plate-type, robust heat exchanger that combines compactness, low pressure drop, high effectiveness, and the ability to operate with a very large pressure differential between hot and cold sides. The plates are etched and thereafter joined by diffusion welding, resulting in extremely strong all-metal heat exchanger cores. After bonding, any number of core blocks can be welded together to provide the required ?ow capacity. This study explores the microchannel heat exchanger and draws conclusions about diffusion welding/bonding for joining heat exchanger plates, with both experimental and computational modeling, along with existing challenges and gaps. Also, presented is a thermal design method for determining overall design speci?cations for a microchannel printed circuit heat exchanger for both supercritical (24 MPa) and subcritical (17 MPa) Rankine power cycles.

Piyush Sabharwall; Denis E. Clark; Michael V. Glazoff; Michael G. McKellar; Ronald E. Mizia

2013-03-01T23:59:59.000Z

338

Ion Colliders  

E-Print Network (OSTI)

High-energy ion colliders are large research tools in nuclear physics to study the Quark-Gluon-Plasma (QGP). The range of collision energy and high luminosity are important design and operational considerations. The experiments also expect flexibility with frequent changes in the collision energy, detector fields, and ion species. Ion species range from protons, including polarized protons in RHIC, to heavy nuclei like gold, lead and uranium. Asymmetric collision combinations (e.g. protons against heavy ions) are also essential. For the creation, acceleration, and storage of bright intense ion beams, limits are set by space charge, charge change, and intrabeam scattering effects, as well as beam losses due to a variety of other phenomena. Currently, there are two operating ion colliders, the Relativistic Heavy Ion Collider (RHIC) at BNL, and the Large Hadron Collider (LHC) at CERN.

Fischer, W

2015-01-01T23:59:59.000Z

339

Chemical exchange program analysis.  

SciTech Connect

As part of its EMS, Sandia performs an annual environmental aspects/impacts analysis. The purpose of this analysis is to identify the environmental aspects associated with Sandia's activities, products, and services and the potential environmental impacts associated with those aspects. Division and environmental programs established objectives and targets based on the environmental aspects associated with their operations. In 2007 the most significant aspect identified was Hazardous Materials (Use and Storage). The objective for Hazardous Materials (Use and Storage) was to improve chemical handling, storage, and on-site movement of hazardous materials. One of the targets supporting this objective was to develop an effective chemical exchange program, making a business case for it in FY07, and fully implementing a comprehensive chemical exchange program in FY08. A Chemical Exchange Program (CEP) team was formed to implement this target. The team consists of representatives from the Chemical Information System (CIS), Pollution Prevention (P2), the HWMF, Procurement and the Environmental Management System (EMS). The CEP Team performed benchmarking and conducted a life-cycle analysis of the current management of chemicals at SNL/NM and compared it to Chemical Exchange alternatives. Those alternatives are as follows: (1) Revive the 'Virtual' Chemical Exchange Program; (2) Re-implement a 'Physical' Chemical Exchange Program using a Chemical Information System; and (3) Transition to a Chemical Management Services System. The analysis and benchmarking study shows that the present management of chemicals at SNL/NM is significantly disjointed and a life-cycle or 'Cradle-to-Grave' approach to chemical management is needed. This approach must consider the purchasing and maintenance costs as well as the cost of ultimate disposal of the chemicals and materials. A chemical exchange is needed as a mechanism to re-apply chemicals on site. This will not only reduce the quantity of unneeded chemicals and the amount spent on new purchases, but will also avoid disposal costs. If SNL/NM were to realize a 5 percent reduction in chemical inventory and a 10 percent reduction in disposal of unused chemicals the total savings would be $189, 200 per year.

Waffelaert, Pascale

2007-09-01T23:59:59.000Z

340

Ion-sensitive phase transitions driven by Debye-Hckel non-ideality  

E-Print Network (OSTI)

We find that the Debye-H\\"uckel nonideality of dilute aqueous electrolytes is sufficient to drive volume phase transitions and criticality, even in the absence of a self-attracting or elastic network. Our result follows from a Landau mean-field theory for a system of confined ions in an external solution of mixed-valence counterions, where the ratio of squared monovalent to divalent ion concentration provides a temperature-like variable for the phase transition. Our analysis was motivated by long-studied volume phase transitions via ion exchange in ionic gels, but our findings agree with existing theory for volume-temperature phase transitions in charged hard-sphere models and other systems by Fisher and Levin, and McGahay and Tomozawa. Our mean-field model predicts a continuous line of gas-liquid-type critical points connecting a purely monovalent, divalent-sensitive critical point at one extreme with a divalent, monovalent-sensitive critical point at the other; an alternative representation of the Landau functional handles this second limit. It follows that critical sensitivity to ion valence is tunable to any desired valence ratio. The critical or discontinuous dependent variable can be the confinement volume; alternatively the internal electrical potential may be more convenient in applications. Our simplified conditions for ionic phase transitions to occur, together with our relatively simple theory to describe them, may facilitate exploration of tunable critical sensitivity in areas such as ion detection technology, biological switches and osmotic control.

Kyle J. Welch; Fred Gittes

2011-09-12T23:59:59.000Z

Note: This page contains sample records for the topic "ion exchange technology" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Separation and Detection of Sulfur-Containing Anions Using Single-Column Ion Chromatography  

Science Journals Connector (OSTI)

......derivatized. With the resin-based column...states or complex ions. Sulfide is...Systems with resin-based anion exchange (RBAX) columns...for which ion-exchange H...detectors. In addition to electrical...since its early demonstration. It has been......

Richard E. Poulson; Harry M. Borg

1987-09-01T23:59:59.000Z

342

Physics and technology in the ion-cyclotron range of frequency on Tore Supra and TITAN test facility: implication for ITER  

SciTech Connect

To support the design of an ITER ion-cyclotron range of frequency heating (ICRH) system and to mitigate risks of operation in ITER, CEA has initiated an ambitious Research & Development program accompanied by experiments on Tore Supra or test-bed facility together with a significant modelling effort. The paper summarizes the recent results in the following areas: Comprehensive characterization (experiments and modelling) of a new Faraday screen concept tested on the Tore Supra antenna. A new model is developed for calculating the ICRH sheath rectification at the antenna vicinity. The model is applied to calculate the local heat flux on Tore Supra and ITER ICRH antennas. Full-wave modelling of ITER ICRH heating and current drive scenarios with the EVE code. With 20 MW of power, a current of 400 kA could be driven on axis in the DT scenario. Comparison between DT and DT(3He) scenario is given for heating and current drive efficiencies. First operation of CW test-bed facility, TITAN, designed for ITER ICRH components testing and could host up to a quarter of an ITER antenna. R&D of high permittivity materials to improve load of test facilities to better simulate ITER plasma antenna loading conditions.

Litaudon, X [CEA, France; Bernard, J. M. [CEA, IRFM, France; Colas, L. [CEA, France; Dumont, R. J. [CEA Cadarache, St. Paul lex Durance, France; Argouarch, A. [CEA Cadarache, St. Paul lex Durance, France; Bottollier-Curtet, H. [CEA, IRFM, France; Bremond, S. [CEA, IRFM, France; Champeaux, S. [CEA, IRFM, France; Corre, Y. [CEA Cadarache, St. Paul lex Durance, France; Dumortier, P. [ERM-KMS, Association EURATOM-Belgian State, Brussels, Belgium; Firdaouss, M. [CEA, IRFM, France; Guilhem, D. [CEA, IRFM, France; Gunn, J. P. [CEA, IRFM, France; Gouard, Ph. [CEA, DAM, DIF, Arpajon cedex, France; Hoang, G T [CEA, IRFM, France; Jacquot, Jonathan [CEA, IRFM, France; Klepper, C Christopher [ORNL; Kubic, M. [CEA, IRFM, France; Kyrytsya, V. [ERM-KMS, Association EURATOM-Belgian State, Brussels, Belgium; Lombard, G. [CEA, IRFM, France; Milanesio, D. [Politecnico di Torino; Messiaen, A. [ERM-KMS, Association EURATOM-Belgian State, Brussels, Belgium; Mollard, P. [CEA, IRFM, France; Meyer, O. [CEA Cadarache, St. Paul lex Durance, France; Zarzoso, D. [CEA, IRFM, France

2013-01-01T23:59:59.000Z

343

Water uptake, ionic conductivity and swelling properties of anion-exchange membrane  

E-Print Network (OSTI)

occurs with negative excess volume of mixing. Percolative nature of the ion transport has been is reduced at the cathode to produce OH? , which transports through the anion-exchange membrane (AEM membrane, AEM can conduct ions only in the presence of water. In addition, water is one of the reactants

344

Building Energy Data Exchange Specification Scoping Report |...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Building Energy Data Exchange Specification Scoping Report Building Energy Data Exchange Specification Scoping Report The Building Energy Data Exchange Specification (BEDES),...

345

Structure of the Alkali-metal-atom-Strontium molecular ions: towards photoassociation and formation of cold molecular ions  

E-Print Network (OSTI)

The potential energy curves, permanent and transition dipole moments, and the static dipolar polarizability, of molecular ions composed of one alkali-metal atom and a Strontium ion are determined with a quantum chemistry approach. The molecular ions are treated as effective two-electron systems and are treated using effective core potentials including core polarization, large gaussian basis sets, and full configuration interaction. In the perspective of upcoming experiments aiming at merging cold atom and cold ion traps, possible paths for radiative charge exchange, photoassociation of a cold Lithium or Rubidium atom and a Strontium ion are discussed, as well as the formation of stable molecular ions.

Mireille Aymar; Romain Gurout; Olivier Dulieu

2011-02-24T23:59:59.000Z

346

Structure of the alkali-metal-atom + strontium molecular ions: Towards photoassociation and formation of cold molecular ions  

SciTech Connect

The potential energy curves, permanent and transition dipole moments, and the static dipolar polarizability, of molecular ions composed of one alkali-metal atom and a strontium ion are determined with a quantum chemistry approach. The molecular ions are treated as effective two-electron systems and are treated using effective core potentials including core polarization, large gaussian basis sets, and full configuration interaction. In the perspective of upcoming experiments aiming at merging cold atom and cold ion traps, possible paths for radiative charge exchange, photoassociation of a cold lithium or rubidium atom and a strontium ion are discussed, as well as the formation of stable molecular ions.

Aymar, M.; Dulieu, O. [Laboratoire Aime Cotton, CNRS, UPR3321, Ba circumflex t. 505, Univ Paris-Sud, 91405 Orsay Cedex (France); Guerout, R. [Laboratoire Kastler-Brossel, CNRS, ENS, Univ Pierre et Marie Curie case 74, Campus Jussieu, F-75252 Paris Cedex 05 (France)

2011-08-14T23:59:59.000Z

347

Structure of the Alkali-metal-atom-Strontium molecular ions: towards photoassociation and formation of cold molecular ions  

E-Print Network (OSTI)

The potential energy curves, permanent and transition dipole moments, and the static dipolar polarizability, of molecular ions composed of one alkali-metal atom and a Strontium ion are determined with a quantum chemistry approach. The molecular ions are treated as effective two-electron systems and are treated using effective core potentials including core polarization, large gaussian basis sets, and full configuration interaction. In the perspective of upcoming experiments aiming at merging cold atom and cold ion traps, possible paths for radiative charge exchange, photoassociation of a cold Lithium or Rubidium atom and a Strontium ion are discussed, as well as the formation of stable molecular ions.

Aymar, Mireille; Dulieu, Olivier

2011-01-01T23:59:59.000Z

348

A New Generation of Parabolic Trough Technology  

Office of Environmental Management (EM)

Trough Technology Innovat ive t echnology solut ions f or su st a in a b ilit y ABENGOA SOLAR Parabolic Trough Collector Technology Abengoa Solar Cont ent 2 Solana Solar Power...

349

Thermoelectric heat exchange element  

DOE Patents (OSTI)

A thermoelectric heat exchange module includes a first substrate including a heat receptive side and a heat donative side and a series of undulatory pleats. The module may also include a thermoelectric material layer having a ZT value of 1.0 or more disposed on at least one of the heat receptive side and the heat donative side, and an electrical contact may be in electrical communication with the thermoelectric material layer.

Callas, James J. (Peoria, IL); Taher, Mahmoud A. (Peoria, IL)

2007-08-14T23:59:59.000Z

350

Anodic polymerization of vinyl ethylene carbonate in Li-Ion battery electrolyte  

E-Print Network (OSTI)

Ethylene Carbonate in Li-Ion Battery Electrolyte Guoyingof a commercial Li-ion battery electrolyte containing 2 %are an important part of Li-ion battery technology yet their

Chen, Guoying; Zhuang, Guorong V.; Richardson, Thomas J.; Gao, Liu; Ross Jr., Philip N.

2005-01-01T23:59:59.000Z

351

High Voltage Electrolytes for Li-ion Batteries | Department of...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Electrolytes for Li-ion Batteries High Voltage Electrolytes for Li-ion Batteries 2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and...

352

Lithium Source For High Performance Li-ion Cells  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

New cathode and anode electrodes are required to improve the energy density of Li-ion cells for transportation technologies. The cost of Li-ion systems for transportation...

353

High Voltage Electrolytes for Li-ion Batteries | Department of...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

in Support of 5 V Li-ion Chemistries Vehicle Technologies Office Merit Review 2014: Fluorinated Electrolyte for 5-V Li-Ion Chemistry High Voltage Electrolyte for Lithium Batteries...

354

Lithium Source For High Performance Li-ion Cells | Department...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Li-ion Cells Lithium Source For High Performance Li-ion Cells 2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer...

355

Dealing with Uncertainties During Heat Exchanger Design  

E-Print Network (OSTI)

Technology Conference, Houston, TX, May 1-4, 2001 E2 Area = 100 m 2 cp= 35 kW/K El Area = 300 m 2 Figure 1. Simple Heat Exchanger Network CP = 30 kW/K CP= 55 kWIK Assume that exchangers EI (of heat transfer area 100 m 2 ) and E2 (of 300 m 2... .) are perfectly sized. Consequently, the cold stream leaving E I has a temperature of 277?C and that leaving E2 a temperature of 212?C. If a ten percent design margin had been added to each of these units (i.e. El now has 110 m 2 and E2 has 330 m 2...

Polley, G. T.; Pugh, S. J.

356

Multi-scale Characterization Studies of Aged Li-ion Battery Materials for Improved Performance.  

E-Print Network (OSTI)

?? Among various electrical energy storage devices the recent advances in Li-ion battery technology has made this technology very promising. Li-ion batteries can be used (more)

Nagpure, Shrikant C.

2012-01-01T23:59:59.000Z

357

Enhanced life ion source for germanium and carbon ion implantation  

SciTech Connect

Germanium and carbon ions represent a significant portion of total ion implantation steps in the process flow. Very often ion source materials that used to produce ions are chemically aggressive, especially at higher temperatures, and result in fast ion source performance degradation and a very limited lifetime [B.S. Freer, et. al., 2002 14th Intl. Conf. on Ion Implantation Technology Proc, IEEE Conf. Proc., p. 420 (2003)]. GeF{sub 4} and CO{sub 2} are commonly used to generate germanium and carbon beams. In the case of GeF{sub 4} controlling the tungsten deposition due to the de-composition of WF{sub 6} (halogen cycle) is critical to ion source life. With CO{sub 2}, the materials oxidation and carbon deposition must be controlled as both will affect cathode thermionic emission and anti-cathode (repeller) efficiencies due to the formation of volatile metal oxides. The improved ion source design Extended Life Source 3 (Eterna ELS3) together with its proprietary co-gas material implementation has demonstrated >300 hours of stable continuous operation when using carbon and germanium ion beams. Optimizing cogas chemistries retard the cathode erosion rate for germanium and carbon minimizes the adverse effects of oxygen when reducing gas is introduced for carbon. The proprietary combination of hardware and co-gas has improved source stability and the results of the hardware and co-gas development are discussed.

Hsieh, Tseh-Jen; Colvin, Neil; Kondratenko, Serguei [Axcelis Technologies, Inc. 108 Cherry Hill Drive, Beverly, MA 01915 (United States)

2012-11-06T23:59:59.000Z

358

MEASUREMENT OF ION BEAM FROM LASER ION SOURCE FOR RHIC Takeshi Kanesue, Kyushu University, Fukuoka 819-0395, Japan  

E-Print Network (OSTI)

, Fukuoka 819-0395, Japan Jun Tamura, Tokyo Institute of Technology, Meguro-ku, Tokyo 152-8550, Japan Radiation Laboratory [1]. The low charge state, low emittance and high ion yield laser ion source (LIS

359

ENGINEERING TECHNOLOGY Engineering Technology  

E-Print Network (OSTI)

, Mechatronics Technology, and Renewable Energy Technology. Career Opportunities Graduates of four: business administration, wind farm management, aircraft maintenance, tooling production, quality and safety or selected program track focus. Transfer students must talk to their advisor about transferring their courses

360

ENGINEERING TECHNOLOGY Engineering Technology  

E-Print Network (OSTI)

: business administration, energy management, wind farm management, automation and controls, aircraft, Mechatronics Technology, and Renewable Energy Technology. Career Opportunities Graduates of four students must talk to their advisor about transferring their courses over for WSU credit. Laboratory

Note: This page contains sample records for the topic "ion exchange technology" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Building Technologies Office: Emerging Technologies  

NLE Websites -- All DOE Office Websites (Extended Search)

Emerging Technologies Emerging Technologies Printable Version Share this resource Send a link to Building Technologies Office: Emerging Technologies to someone by E-mail Share Building Technologies Office: Emerging Technologies on Facebook Tweet about Building Technologies Office: Emerging Technologies on Twitter Bookmark Building Technologies Office: Emerging Technologies on Google Bookmark Building Technologies Office: Emerging Technologies on Delicious Rank Building Technologies Office: Emerging Technologies on Digg Find More places to share Building Technologies Office: Emerging Technologies on AddThis.com... About Take Action to Save Energy Partner with DOE Activities Technology Research, Standards, & Codes Popular Links Success Stories Previous Next Lighten Energy Loads with System Design.

362

Particle diagnostics of ion cyclotron resonance plasma heating in the Globus-M tokamak  

SciTech Connect

Basic experimental results on cyclotron heating of the ion plasma component in the Globus-M spherical tokamak obtained by means of the ACORD-12 charge-exchange ion analyzer are presented. A procedure for determining the maximum energy of fast ions confined in the plasma is described. The procedure was applied to estimate the limiting energy of hydrogen minority ions accelerated during ion cyclotron heating in the Globus-M tokamak. The experimental evaluation of the maximum hydrogen ion energy is confirmed by simulations of ion orbits. Recommendations for optimizing experiments on ion cyclotron heating in the Globus-M tokamak are formulated.

Chernyshev, F. V.; Ayushin, B. B.; Gusev, V. K.; D'yachenko, V. V.; Minaev, V. B.; Mironov, M. I.; Petrov, M. P.; Petrov, Yu. V.; Sakharov, N. V.; Khitrov, S. A.; Shcherbinin, O. N. [Russian Academy of Sciences, Ioffe Physicotechnical Institute (Russian Federation)

2009-11-15T23:59:59.000Z

363

Sources of polarized ions and atoms  

SciTech Connect

In this presentation we discuss methods of producing large quantities of polarized atoms and ions (Stern-Gerlach separation, optical pumping, and spin-exchange) as well as experimental methods of measuring the degree of polarization of atomic systems. The usefulness of polarized atoms in probing the microscopic magnetic surface properties of materials will also be discussed. 39 refs., 5 figs., 2 tabs.

Cornelius, W.D.

1988-01-01T23:59:59.000Z

364

Sandia National Laboratories: lithium-ion-based solid electrolyte...  

NLE Websites -- All DOE Office Websites (Extended Search)

lithium-ion-based solid electrolyte battery Sandia Labs, Front Edge Technology, Inc., Pacific Northwest National Lab, Univ. of California-Los Angeles: Micro Power Source On March...

365

Overview of Capabilities Conversion System Technology  

E-Print Network (OSTI)

cycles Heat exchanger design and optimization TES Material Integration & Optimization: Solar power plantOverview of Capabilities Conversion System Technology - Power System Demonstrations - Systems Conceptual Design/Trade Space Exploration - Simulation Modeling for Manufacturing - Hybrid Energy Systems

Lee, Dongwon

366

Large Scale Geothermal Exchange System for Residential, Office and Retail  

Open Energy Info (EERE)

Geothermal Exchange System for Residential, Office and Retail Geothermal Exchange System for Residential, Office and Retail Development Geothermal Project Jump to: navigation, search Last modified on July 22, 2011. Project Title Large Scale Geothermal Exchange System for Residential, Office and Retail Development Project Type / Topic 1 Recovery Act - Geothermal Technologies Program: Ground Source Heat Pumps Project Type / Topic 2 Topic Area 1: Technology Demonstration Projects Project Description RiverHeath will be a new neighborhood, with residences, shops, restaurants, and offices. The design incorporates walking trails, community gardens, green roofs, and innovative stormwater controls. A major component of the project is our reliance on renewable energy. One legacy of the land's industrial past is an onsite hydro-electric facility which formerly powered the paper factories. The onsite hydro is being refurbished and will furnish 100% of the project's electricity demand.

367

Ion temperatures in Ormak from Doppler broadening  

Science Journals Connector (OSTI)

Rapid-scanning spectrometric techniques have permitted the determination of ion temperatures in ORMAK as a function of time during the discharge pulse for ORMAK plasma currents up to 180 kA. Emission spectra of hydrogen atoms are Doppler-broadened in the line wings, characteristic of the initial proton motions prior to charge exchange, and give ion "temperatures" generally less than kT+ ~ 300 eV. Impurity spectra of C III and O V, as well as the spectra of He II in helium discharges, lead to somewhat higher ion temperatures ranging up to a maximum of kT+ ~ 700 eV.

J. Rand McNally Jr.; R.V. Neidigh

1973-01-01T23:59:59.000Z

368

Heat exchanger-accumulator  

DOE Patents (OSTI)

What is disclosed is a heat exchanger-accumulator for vaporizing a refrigerant or the like, characterized by an upright pressure vessel having a top, bottom and side walls; an inlet conduit eccentrically and sealingly penetrating through the top; a tubular overflow chamber disposed within the vessel and sealingly connected with the bottom so as to define an annular outer volumetric chamber for receiving refrigerant; a heat transfer coil disposed in the outer volumetric chamber for vaporizing the liquid refrigerant that accumulates there; the heat transfer coil defining a passageway for circulating an externally supplied heat exchange fluid; transferring heat efficiently from the fluid; and freely allowing vaporized refrigerant to escape upwardly from the liquid refrigerant; and a refrigerant discharge conduit penetrating sealingly through the top and traversing substantially the length of the pressurized vessel downwardly and upwardly such that its inlet is near the top of the pressurized vessel so as to provide a means for transporting refrigerant vapor from the vessel. The refrigerant discharge conduit has metering orifices, or passageways, penetrating laterally through its walls near the bottom, communicating respectively interiorly and exteriorly of the overflow chamber for controllably carrying small amounts of liquid refrigerant and oil to the effluent stream of refrigerant gas.

Ecker, Amir L. (Dallas, TX)

1980-01-01T23:59:59.000Z

369

Towards an XML-based Data Exchange Mechanism for the Portuguese SMEs  

E-Print Network (OSTI)

business messages effectively. However, EDI technology still remains to be introduced in SMEs and (if1 Towards an XML-based Data Exchange Mechanism for the Portuguese SMEs Miguel Mira da Silva IST to be used by SMEs to exchange business messages. Although it seems a simple task, EDI has faced many

da Silva, Alberto Rodrigues

370

Comparative studies on authentication and key exchange methods for 802.11 wireless LAN  

Science Journals Connector (OSTI)

IEEE 802.11 wireless LAN has become one of the hot topics on the design and development of network access technologies. In particular, its authentication and key exchange (AKE) aspects, which form a vital building block for modern security mechanisms, ... Keywords: Authentication, Confidentiality, Key exchange, Security, WLAN

Jun Lei, Xiaoming Fu, Dieter Hogrefe, Jianrong Tan

2007-08-01T23:59:59.000Z

371

Ion Cyclotron-Resonance Heating in a Toroidal Octupole  

Science Journals Connector (OSTI)

rf power near the ion cyclotron-resonance frequency has been used to produce a hundredfold increase (from ? 1 to ? 100 eV) in the ion temperature in a toroidal octupole device. The heating produces no noticeable instabilities or other deleterious effects except for a high reflux of neutrals from the walls. The heating rate is consistent with theory and the limiting ion temperature is determined by charge-exchange losses.

J. D. Barter and J. C. Sprott

1975-06-30T23:59:59.000Z

372

Sodium-bearing Waste Treatment Technology Evaluation Report  

SciTech Connect

Sodium-bearing waste (SBW) disposition is one of the U.S. Department of Energy (DOE) Idaho Operation Offices (NE-ID) and State of Idahos top priorities at the Idaho National Engineering and Environmental Laboratory (INEEL). The INEEL has been working over the past several years to identify a treatment technology that meets NE-ID and regulatory treatment requirements, including consideration of stakeholder input. Many studies, including the High-Level Waste and Facilities Disposition Environmental Impact Statement (EIS), have resulted in the identification of five treatment alternatives that form a short list of perhaps the most appropriate technologies for the DOE to select from. The alternatives are (a) calcination with maximum achievable control technology (MACT) upgrade, (b) steam reforming, (c) cesium ion exchange (CsIX) with immobilization, (d) direct evaporation, and (e) vitrification. Each alternative has undergone some degree of applied technical development and preliminary process design over the past four years. This report presents a summary of the applied technology and process design activities performed through February 2004. The SBW issue and the five alternatives are described in Sections 2 and 3, respectively. Details of preliminary process design activities for three of the alternatives (steam reforming, CsIX, and direct evaporation) are presented in three appendices. A recent feasibility study provides the details for calcination. There have been no recent activities performed with regard to vitrification; that section summarizes and references previous work.

Charles M. Barnes; Arlin L. Olson; Dean D. Taylor

2004-05-01T23:59:59.000Z

373

Modeling Uranium-Proton Ion Exchange in Biosorption  

E-Print Network (OSTI)

threatening heavy metals because of its high toxicity and some radioactivity. Excessive amounts of uranium seaweed biomass was used to remove the heavy metal uranium from the aqueous solution. Uranium biosorption the heavy metal uptake performance of different biosorbents.LangmuirandFreundlichmodelsoftengenerally fit

Volesky, Bohumil

374

Non-aqueous liquid compositions comprising ion exchange polymers  

DOE Patents (OSTI)

Compositions, and methods of making thereof, comprising from about 1% to about 5% of a perfluorinated sulfonic acid ionomer or a hydrocarbon-based ionomer; and from about 95% to about 99% of a solvent, said solvent consisting essentially of a polyol; wherein said composition is substantially free of water and wherein said ionomer is uniformly dispersed in said solvent.

Kim, Yu Seung (Los Alamos, NM); Lee, Kwan-Soo (Blacksburg, VA); Rockward, Tommy Q. T. (Rio Rancho, NM)

2011-07-19T23:59:59.000Z

375

Ion Exchange for the Recycling of Wastewater Constituents  

Science Journals Connector (OSTI)

Recycling or the constituents of wastewater requires efficient and cheap separation methods. Pollutants ... removed in a concentrated form to facilitate their recycling. Similarly, the raw water must be ... has a...

Brian Bolto; Lucjan Pawlowski

1985-01-01T23:59:59.000Z

376

Parametric Ion-Exchange Processes (Parametric Pumping and Allied Techniques)  

Science Journals Connector (OSTI)

The term parametric pumping implies the idea of pumping, that is of transport of material (in our case, ionic species) up along some potential scale (in our case, chemical potential), at the cost of degradat...

D. Tondeur; G. Grevillot

1986-01-01T23:59:59.000Z

377

Sorption of heavy metals by modified chelating ion exchangers  

Science Journals Connector (OSTI)

Satisfactory sorption capacity towards heavy metals of several physically modified chelating resins at low pH is reported. It was found that the linear sorption isotherms are the most appropriate for describing the sorption of Ni and Pb. The data obtained revealed that the chelating resins studied are able to remove selectively copper from a complex synthetic solution containing Fe, Mn and Pb. The regeneration of Lewatit TP 208 by 10% H2SO4 in batch conditions proved to be effective through three consecutive runs of loading-regeneration.

Valentin Nenov; Bogdan Bonev

2010-01-01T23:59:59.000Z

378

The Dynamics of Platinum Precipitation in an Ion Exchange Membrane  

E-Print Network (OSTI)

Microscopy of polymer electrolyte membranes that have undergone operation under fuel cell conditions, have revealed a well defined band of platinum in the membrane. Here, we propose a physics based model that captures the mechanism of platinum precipitation in the polymer electrolyte membrane. While platinum is observed throughout the membrane, the preferential growth of platinum at the band of platinum is dependent on the electrochemical potential distribution in the membrane. In this paper, the location of the platinum band is calculated as a function of the gas concentration at the cathode and anode, gas diffusion coefficients and solubility constants of the gases in the membrane, which are functions of relative humidity. Under H2/N2 conditions the platinum band is located near the cathode-membrane interface, as the oxygen concentration in the cathode gas stream increases and/or the hydrogen concentration in the anode gas stream decreases, the band moves towards the anode. The model developed in this paper...

Burlatsky, S F; Atrazhev, V V; Dmitriev, D V; Kuzminyh, N Y; Erikhman, N S

2013-01-01T23:59:59.000Z

379

Charge Transport through a Novel Zeolite Y Membrane by a Self-Exchange Process Hyunjung Lee and Prabir K. Dutta*  

E-Print Network (OSTI)

Charge Transport through a Novel Zeolite Y Membrane by a Self-Exchange Process Hyunjung Lee-photoresist-coated membranes were found. Accessibility of the intrazeolitic volume was examined by ion exchange and for optimally illuminated membranes was comparable to uncoated membranes. Charge transport through the membrane

Dutta, Prabir K.

380

Office of Waste Processing Technical Exchange  

NLE Websites -- All DOE Office Websites (Extended Search)

EM Waste Processing Technical Exchange 2010 Agenda EM Waste Processing Technical Exchange 2010 Agenda (Sponsored by EM Office of Waste Processing) November 16 - 18, 2010; Loews Hotel, Atlanta, GA 11/2/2010 Monday, November 15, 2010 5:00 - 7:00 pm Early Registration and Speaker Check-in *Light Refreshments Tuesday Morning, November 16, 2010 Session 1: Technical Exchange Opening (Chair: W. Wilmarth); Salon D Live Webcast Click the video icon to view Session 1 Live Webcast Submit Question Click the Question icon to submit a question. Time Topic Speaker 7:00 am Registration and Check-in 8:00 am S01-01 Welcome T. Michalske, SRNL 8:05 am S01-02 Opening Comments Y. Collazo, DOE-EM 8:15 am S01-03 Introductions G. Flowers, SRNS 8:20 am S01-04 Opening Remarks I. Triay, DOE-EM 8:45 am S01-05 Status of Waste Processing Technology Development

Note: This page contains sample records for the topic "ion exchange technology" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

basic exchange telecommunications radio service  

Science Journals Connector (OSTI)

A service that extends telecommunications service to rural, outlying, and remote...Common abbreviation BETRS. Note: In the basic exchange telecommunications radio service (BETRS), the (a)....

2001-01-01T23:59:59.000Z

382

Plasma ion sources and ion beam technology in microfabrications  

E-Print Network (OSTI)

Ka-Ngo Leung Nuclear Engineering Department University ofin Engineering-Nuclear Engineering in the GRADUATE DIVISIONJi Doctor of Philosophy in Nuclear Engineering University of

Ji, Lili

2007-01-01T23:59:59.000Z

383

Cryogenic silicon surface ion trap  

E-Print Network (OSTI)

Trapped ions are pre-eminent candidates for building quantum information processors and quantum simulators. They have been used to demonstrate quantum gates and algorithms, quantum error correction, and basic quantum simulations. However, to realise the full potential of such systems and make scalable trapped-ion quantum computing a reality, there exist a number of practical problems which must be solved. These include tackling the observed high ion-heating rates and creating scalable trap structures which can be simply and reliably produced. Here, we report on cryogenically operated silicon ion traps which can be rapidly and easily fabricated using standard semiconductor technologies. Single $^{40}$Ca$^+$ ions have been trapped and used to characterize the trap operation. Long ion lifetimes were observed with the traps exhibiting heating rates as low as $\\dot{\\bar{n}}=$ 0.33 phonons/s at an ion-electrode distance of 230 $\\mu$m. These results open many new avenues to arrays of micro-fabricated ion traps.

Michael Niedermayr; Kirill Lakhmanskiy; Muir Kumph; Stefan Partel; Johannes Edlinger; Michael Brownnutt; Rainer Blatt

2014-03-20T23:59:59.000Z

384

Na K -pump ligands modulate gating of palytoxin-induced ion channels  

E-Print Network (OSTI)

proteins that mediate transport of ions across cell membranes, they traditionally have been viewed as very to the extracellular surface. The 3Na 2K -exchange transport cycle is completed when two extracellular K ions bind ensure the vectorial nature of net transport. The occluded-ion conformations, with binding sites

Gadsby, David

385

RESEARCH PAPER The face value of ion fluxes: the challenge of determining  

E-Print Network (OSTI)

is the membrane-transport parameter of greatest interest to most researchers in the field of plant ion transport physiology. Key words: Barley, cellular ion exchange, efflux, high-affinity transport, influx, low-affinity transport, potassium. Introduction The unidirectional influx of nutrient ions into the plant cell

Britto, Dev T.

386

ION CYCLOTRON HEATING IN A TOROIDAL OC TUPOLE J. D. Barter and J. C. Sprott  

E-Print Network (OSTI)

ION CYCLOTRON HEATING IN A TOROIDAL OC TUPOLE J. D. Barter and J. C. Sprott February 1975;ION CYCLOTRON HEAT ING IN A TOROIDAL OCTUPOLE J. ,D. Barter and J. C. Sprott University of Wisconsin ion temperature is determined by charge exchange losses. #12;· 19n cyclotron resonance heating has

Sprott, Julien Clinton

387

Technological assessment and evaluation of high power batteries and their commercial values  

E-Print Network (OSTI)

Lithium Ion (Li-ion) battery technology has the potential to compete with the more matured Nickel Metal Hydride (NiMH) battery technology in the Hybrid Electric Vehicle (HEV) energy storage market as it has higher specific ...

Teo, Seh Kiat

2006-01-01T23:59:59.000Z

388

Neutron-Proton Exchange Demonstrated  

Science Journals Connector (OSTI)

Neutron-Proton Exchange Demonstrated ... EVIDENCE of the exchange of charge between protons and neutrons has recently been obtained from studies in the high power cyclotron, according to Ernest O. Lawrence, professor of physics at the University of California a* Berkeley. ...

1947-11-03T23:59:59.000Z

389

Gas Exchange, Partial Pressure Gradients,  

E-Print Network (OSTI)

Gas Exchange, Partial Pressure Gradients, and the Oxygen Window Johnny E. Brian, Jr., M of circulatory and gas transport physiology, and the best place to start is with normobaric physiology. LIFE affect the precise gas exchange occurring in individual areas of the lungs and body tissues. To make

Riba Sagarra, Jaume

390

Technology Transfer: Site Map  

NLE Websites -- All DOE Office Websites (Extended Search)

Site Map Site Map About Us About Technology Transfer Contact Us Available Technologies Advanced Materials Biofuels Biotechnology and Medicine Developing World Energy Environmental Technologies Imaging and Lasers Ion Sources and Beam Technologies Nanotechnology and Microtechnology Software and Information Technology For Industry Licensing Overview Frequently Asked Questions Partnering with Berkeley Lab Licensing Interest Form Receive New Tech Alerts For Researchers What You Need to Know and Do The Tech Transfer Process Forms Record of Invention (Word doc -- please do not use earlier PDF version of the form) Software Disclosure and Abstract (PDF, use Adobe Acrobat or Adobe Reader 9 and up ONLY to complete the form) Policies Conflict of Interest Outside Empolyment Export Control FAQs for Researchers

391

Heat exchanger design considerations for high temperature gas-cooled reactor (HTGR) plants  

SciTech Connect

Various aspects of the high-temperature heat exchanger conceptual designs for the gas turbine (HTGR-GT) and process heat (HTGR-PH) plants are discussed. Topics include technology background, heat exchanger types, surface geometry, thermal sizing, performance, material selection, mechanical design, fabrication, and the systems-related impact of installation and integration of the units in the prestressed concrete reactor vessel. The impact of future technology developments, such as the utilization of nonmetallic materials and advanced heat exchanger surface geometries and methods of construction, is also discussed.

McDonald, C.F.; Vrable, D.L.; Van Hagan, T.H.; King, J.H.; Spring, A.H.

1980-02-01T23:59:59.000Z

392

Vehicle Technologies Office Merit Review 2014: Post-Test Analysis...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Post-Test Analysis of Lithium-Ion Battery Materials at Argonne National Laboratory Vehicle Technologies Office Merit Review 2014: Post-Test Analysis of Lithium-Ion Battery...

393

Ion Sources for High Energy Ion Implantation at BNL | U.S. DOE Office of  

Office of Science (SC) Website

Ion Sources for High Energy Ion Ion Sources for High Energy Ion Implantation at BNL Nuclear Physics (NP) NP Home About Research Facilities Science Highlights Benefits of NP Spinoff Applications Spinoff Archives SBIR/STTR Applications of Nuclear Science and Technology Funding Opportunities Nuclear Science Advisory Committee (NSAC) News & Resources Contact Information Nuclear Physics U.S. Department of Energy SC-26/Germantown Building 1000 Independence Ave., SW Washington, DC 20585 P: (301) 903-3613 F: (301) 903-3833 E: sc.np@science.doe.gov More Information » Spinoff Archives Ion Sources for High Energy Ion Implantation at BNL Print Text Size: A A A RSS Feeds FeedbackShare Page Application/instrumentation: Ion Sources for High Energy Ion Implantation Developed at: Brookhaven National Laboratory, New York; High Current Electronic

394

FAST ION STUDIES OF ION CYCLOTRON HEATING  

E-Print Network (OSTI)

FAST ION STUDIES OF ION CYCLOTRON HEATING IN THE PLT TOKAMAK Gregory Wayne Hammett;@1986 Gregory Wayne Hammett ALL RIGHTS RESERVED #12;Abstract Fast Ion Studies of Ion Cyclotron Heating about the physics of wave heating. Previous experiments have demonstrated that ion cyclotron heating

Hammett, Greg

395

Modular heat exchanger  

DOE Patents (OSTI)

A shell and tube heat exchanger having a plurality of individually removable tube bundle modules. A lattice of structural steel forming rectangular openings therein is placed at each end of a cylindrical shell. Longitudinal structural members are placed in the shell between corners of the rectangular openings situated on opposite ends of the shell. Intermediate support members interconnect the longitudinal supports so as to increase the longitudinal supports rigidity. Rectangular parallelpiped tube bundle moldules occupy the space defined by the longitudinal supports and end supports and each include a rectangular tube sheet situated on each end of a plurality of tubes extending therethrough, a plurality of rectangular tube supports located between the tube sheets, and a tube bundle module stiffening structure disposed about the bundle's periphery and being attached to the tube sheets and tube supports. The corners of each tube bundle module have longitudinal framework members which are mateable with and supported by the longitudinal support members. Intermediate support members constitute several lattice, each of which is situate d in a plane between the end support members. The intermediate support members constituting the several lattice extend horizontally and vertically between longitudinal supports of adjacent tube module voids. An alternative embodiment for intermediate support members constitute a series of structural plates situated at the corners of the module voids and having recesses therein for receiving the respective longitudinal support members adjacent thereto, protrusions separating the recesses, and a plurality of struts situated between protrusions of adjacent structural plates.

Giardina, Angelo R. [Marple Township, Delaware County, PA

1981-03-03T23:59:59.000Z

396

Technology Transfer: Available Technologies  

NLE Websites -- All DOE Office Websites (Extended Search)

test test Please refer to the list of technologies below for licensing and research collaboration availability. If you can't find the technology you're interested in, please contact us at TTD@lbl.gov. Energy ENERGY EFFICIENT TECHNOLOGIES Aerosol Sealing Aerosol Remote Sealing System Clog-free Atomizing and Spray Drying Nozzle Air-stable Nanomaterials for Efficient OLEDs Solvent Processed Nanotube Composites OLEDS with Air-stable Structured Electrodes APIs for Online Energy Saving Tools: Home Energy Saver and EnergyIQ Carbon Dioxide Capture at a Reduced Cost Dynamic Solar Glare Blocking System Electrochromic Device Controlled by Sunlight Electrochromic Windows with Multiple-Cavity Optical Bandpass Filter Electrochromic Window Technology Portfolio Universal Electrochromic Smart Window Coating

397

Ion Rings for Magnetic Fusion  

SciTech Connect

This Final Technical Report presents the results of the program, Ion Rings for Magnetic Fusion, which was carried out under Department of Energy funding during the period August, 1993 to January, 2005. The central objective of the program was to study the properties of field-reversed configurations formed by ion rings. In order to reach this objective, our experimental program, called the Field-reversed Ion Ring Experiment, FIREX, undertook to develop an efficient, economical technology for the production of field-reversed ion rings. A field-reversed configuration (FRC) in which the azimuthal (field-reversing) current is carried by ions with gyro-radius comparable to the magnetic separatrix radius is called a field-reversed ion ring. A background plasma is required for charge neutralization of the ring, and this plasma will be confined within the ring's closed magnetic flux. Ion rings have long been of interest as the basis of compact magnetic fusion reactors, as the basis for a high-power accelerator for an inertial fusion driver, and for other applications of high power ion beams or plasmas of high energy density. Specifically, the FIREX program was intended to address the longstanding question of the contribution of large-orbit ions to the observed stability of experimental FRCs to the MHD tilt mode. Typical experimental FRCs with s {approx} 2-4, where s is the ratio of separatrix radius to ion gyro-radius, have been stable to tilting, but desired values for a fusion reactor, s > 20, should be unstable. The FIREX ring would consist of a plasma with large s for the background ions, but with s {approx} 1 for the ring ions. By varying the proportions of these two populations, the minimum proportion of large-orbit ions necessary for stability could be determined. The incorporation of large-orbit ions, perhaps by neutral-beam injection, into an FRC has been advanced for the purpose of stabilizing, heating, controlling angular momentum, and aiding the formation of a reactor-scale FRC, and the FIREX program was intended to test the ideas behind this approach. We will describe in this report the technological development path and advances in physics understanding that allowed FIREX to reach a regime in which ion rings were reproducibly created with up to about half the current necessary to produce field reversal. Unfortunately, the experiments were limited to this level by a fundamental, unanticipated aspect of the physics of strong ion rings in plasma. The FIREX ring is a strongly anisotropic, current-carrying population of ions moving faster than the Alfven speed in the background plasma. The rapidly changing ring current excites very large-amplitude Alfven waves in the plasma, and these waves strongly affect the ring, causing rapid energy loss in a way that is not compatible with the success of the ring trapping scenario around which FIREX was designed. The result was that FIREX rings were always very short-lived. We will discuss the implication of these results for possible future use of large-orbit ions in FRCs. In short, it appears that a certain range of the parameters characterizing the ring Alfven mach number and distribution function must be avoided to allow the existence of a long-lived energetic ion component in an FRC. This report will explain why FIREX experimental results cannot be directly scaled to quantitatively predict this range for a particular FRC configuration. This will require accurate, three-dimensional simulations. FIREX results do constitute a very good dataset for validating such a code, and simulations already carried out during this program provide a guide to the important physics involved.

Greenly, John, B.

2005-07-31T23:59:59.000Z

398

secondary ion detection | EMSL  

NLE Websites -- All DOE Office Websites (Extended Search)

ion detection secondary ion detection Leads No leads are available at this time. Magnesium behavior and structural defects in Mg+ ion implanted silicon carbide. Abstract: As a...

399

Technology Transfer: Available Technologies  

NLE Websites -- All DOE Office Websites (Extended Search)

Advanced Materials Advanced Materials Adjustably Inducing Biaxial Strain in Thin Films Bone Replacement and Dental Materials Flexibone: Osteo-mimetic Composites Graded Bioactive Glass and Glass/Ceramic Coatings for Metal Bone Implants Injectable Hydrogel-Based Biodegradable Bone Replacement Materials Mineralization of Biocompatible Scaffolds Peptides for the Controllable Promotion or Inhibition of Bone Growth Remineralization and Repair of Calcified Tissues Using Biomimetic Polymer Boron Nitride Converted Carbon Fibers Catalysts for Reduction of SO2 to Elemental Sulfur Catalyst Exchanges Deuterium or Tritium into Organic and Organometallic Compounds Direct Thin Film Path to Low Cost, Large Area III-V Photovoltaics Easily Assembled Porous Thin Films Full Spectrum Semiconducting Material for Affordable, Highly

400

Worldwide 'Power exchanges' | OpenEI Community  

Open Energy Info (EERE)

Indian government is attempting to set-up power exchang, where one can buysell electrical power (just like stock exchange). Please let me know: If power exchange exists in...

Note: This page contains sample records for the topic "ion exchange technology" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Recycling used engine coolant using high-volume stationary, multiple technology equipment  

SciTech Connect

Recycling used engine coolant has become increasingly desirable due to two significant factors. First, engine coolant frequently merits designation as a hazardous waste under the Federal Clean Water Act. Federal and some state environmental protection agencies have instituted strict regulation of the disposal of used engine coolant. In some cases, the disposal of engine coolant requires imposition of waste disposal fees and surcharges. Secondly, ethylene glycol, the principal cost component of engine coolant, has experienced dramatic price fluctuations and occasional shortages in supply. Therefore, there are both environmental and economic pressures to recycle engine coolant and recover the ethylene glycol component in an efficient and cost-effective manner. This paper discusses a multistage apparatus and a process for recycling used engine coolant that employs a combination of filtration, centrifugation (hydrocyclone separation), dissolved air flotation, nanofiltration, reverse osmosis, continuous deionization, and ion exchange processes for separating ethylene glycol and water from used engine coolant. The engine coolant is prefiltered through a series of filters. The filters remove particulate contaminates. This filtered fluid is then subjected to dissolved air flotation and centrifugation to remove petroleum. Then it is heated and pressurized prior to being passed over a series of two different sets of semipermeable membranes. The membrane technologies separate the feed stream into a permeate solution of ethylene glycol and water and a concentrate waste solution. The concentrate solution is returned to a concentrate tank for continuous circulation through the apparatus. The permeate solution is subjected to final refining by continuous deionization followed by a cation and anion ion exchange polishing process. The continuous deionization reduces ionic contaminants, and the ion exchange system eliminates any ionic contaminants left by the previous purification methods. A mechanical blender is used to mix the purified recovered fluid with fresh ethylene glycol (to adjust freeze point) and performance enhancing chemicals.

Haddock, M.E. [Recycled Engine Coolants, Inc., Austin, TX (United States); Eaton, E.R. [Penray Companies, Inc., Elk Grove Village, IL (United States)

1999-08-01T23:59:59.000Z

402

Heat exchanger with ceramic elements  

DOE Patents (OSTI)

An annular heat exchanger assembly includes a plurality of low thermal growth ceramic heat exchange members with inlet and exit flow ports on distinct faces. A mounting member locates each ceramic member in a near-annular array and seals the flow ports on the distinct faces into the separate flow paths of the heat exchanger. The mounting member adjusts for the temperature gradient in the assembly and the different coefficients of thermal expansion of the members of the assembly during all operating temperatures.

Corey, John A. (North Troy, NY)

1986-01-01T23:59:59.000Z

403

Role of Cation-Water Disorder during Cation Exchange in Small-Pore Zeolite  

NLE Websites -- All DOE Office Websites (Extended Search)

Role of Cation-Water Disorder during Cation Exchange in Small-Pore Zeolite Role of Cation-Water Disorder during Cation Exchange in Small-Pore Zeolite Sodium Natrolite Thursday, October 31, 2013 Structural changes leading to disordering of the cation-water arrangement within the pores of zeolite natrolite while exchanging sodium (Na+) with potassium (K+) have been investigated using x-ray diffraction (XRD) and oxygen K-edge x-ray absorption spectroscopy (XAS). cation in zeolite sodium natrolite fig1 Figure 1) Artistic representation of the natrolite channel, which opens progressively as a function of the exchanging cation's size. The small golf ball represents ordered sodium cations in a closed elliptical channel, whereas the large baseball represents a disordered cesium cation in an open circular channel. The most fundamental chemical property of zeolites is ion exchange. A

404

Influence of the electron-exchange and quantum shielding on the bremsstrahlung spectrum in degenerate quantum plasmas  

SciTech Connect

The influence of the electron-exchange and quantum shielding on the bremsstrahlung spectrum is investigated in degenerate quantum plasmas. The impact-parameter analysis with the Shukla-Eliasson potential is applied to obtain the electron-ion bremsstrahlung radiation cross section as a function of the impact parameter, photon energy, projectile energy, electron-exchange parameter, Fermi energy, and plasmon energy. The result shows that the electron-exchange effect strongly enhances the bremsstrahlung radiation spectrum in degenerate quantum plasmas. It is also shown that the influence of the electron-exchange broadens the photon emission range in the electron-ion bremsstrahlung process. It is found that the electron-exchange effect focuses the bremsstrahlung photon energy in the soft photon domain. In addition, it is found that the bremsstrahlung radiation cross section increases with an increase of the Fermi energy and, however, decreases with increasing plasmon energy.

Jung, Young-Dae [Department of Electrical and Computer Engineering, MC 0407, University of California, San Diego, 9500 Gilman Drive, La Jolla, California 92093-0407, USA and Department of Applied Physics, Hanyang University, Ansan, Kyunggi-Do 426-791 (Korea, Republic of)] [Department of Electrical and Computer Engineering, MC 0407, University of California, San Diego, 9500 Gilman Drive, La Jolla, California 92093-0407, USA and Department of Applied Physics, Hanyang University, Ansan, Kyunggi-Do 426-791 (Korea, Republic of)

2013-10-15T23:59:59.000Z

405

Energy Efficiency Exchange 2015 | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Energy Efficiency Exchange 2015 Energy Efficiency Exchange 2015 As the nation's largest energy consumer, the federal government has a tremendous opportunity and clear...

406

Materials - Micro heat exchangers ... | ornl.gov  

NLE Websites -- All DOE Office Websites (Extended Search)

Materials - Micro heat exchangers ... Heat exchanger components fabricated with 3-D printing and analyzed with neutron imaging create a world of opportunities for electronic...

407

Better Buildings Residential Network Orientation Peer Exchange...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Better Buildings Residential Network Orientation Peer Exchange Webinar Better Buildings Residential Network Orientation Peer Exchange Webinar September 11, 2014 7:00PM to 8:3...

408

Building Technologies Office: Performance Metrics Tiers  

NLE Websites -- All DOE Office Websites (Extended Search)

Performance Metrics Performance Metrics Tiers to someone by E-mail Share Building Technologies Office: Performance Metrics Tiers on Facebook Tweet about Building Technologies Office: Performance Metrics Tiers on Twitter Bookmark Building Technologies Office: Performance Metrics Tiers on Google Bookmark Building Technologies Office: Performance Metrics Tiers on Delicious Rank Building Technologies Office: Performance Metrics Tiers on Digg Find More places to share Building Technologies Office: Performance Metrics Tiers on AddThis.com... About Take Action to Save Energy Activities 179d Tax Calculator Advanced Energy Design Guides Advanced Energy Retrofit Guides Building Energy Data Exchange Specification Buildings Performance Database Data Centers Energy Asset Score Energy Modeling Software

409

Building Technologies Office: Commercial Reference Buildings  

NLE Websites -- All DOE Office Websites (Extended Search)

Commercial Reference Commercial Reference Buildings to someone by E-mail Share Building Technologies Office: Commercial Reference Buildings on Facebook Tweet about Building Technologies Office: Commercial Reference Buildings on Twitter Bookmark Building Technologies Office: Commercial Reference Buildings on Google Bookmark Building Technologies Office: Commercial Reference Buildings on Delicious Rank Building Technologies Office: Commercial Reference Buildings on Digg Find More places to share Building Technologies Office: Commercial Reference Buildings on AddThis.com... About Take Action to Save Energy Activities 179d Tax Calculator Advanced Energy Design Guides Advanced Energy Retrofit Guides Building Energy Data Exchange Specification Buildings Performance Database Data Centers Energy Asset Score

410

Building Technologies Office: Advanced Energy Retrofit Guides  

NLE Websites -- All DOE Office Websites (Extended Search)

Energy Energy Retrofit Guides to someone by E-mail Share Building Technologies Office: Advanced Energy Retrofit Guides on Facebook Tweet about Building Technologies Office: Advanced Energy Retrofit Guides on Twitter Bookmark Building Technologies Office: Advanced Energy Retrofit Guides on Google Bookmark Building Technologies Office: Advanced Energy Retrofit Guides on Delicious Rank Building Technologies Office: Advanced Energy Retrofit Guides on Digg Find More places to share Building Technologies Office: Advanced Energy Retrofit Guides on AddThis.com... About Take Action to Save Energy Activities 179d Tax Calculator Advanced Energy Design Guides Advanced Energy Retrofit Guides Building Energy Data Exchange Specification Buildings Performance Database Data Centers Energy Asset Score

411

Negative Ion Based Heating and Diagnostic Neutral Beams for ITER  

SciTech Connect

To meet the requirements of the four operating and one start-up scenarios foreseen in the International Tokamak Experimental Reactor (ITER) a flexible heating mix will be required, which has to include a reliable contribution from neutral beams. The current baseline of ITER foresees 2 Heating Neutral Beam (HNB) systems based on negative ion technology, each operating at 1 MeV 40 A D{sup -} ions, and each capable of delivering up to 16.7 MW of D deg. to the ITER plasma. A 3rd HNB injector is foreseen as an upgrade option. In addition a dedicated Diagnostic Neutral Beam (DNB) injecting 100 keV 60 A of negative hydrogen ions will be available for charge exchange resonant spectroscopy (CXRS). The significant R and D effort necessary to meet the design requirements will be provided in the Neutral Beam Test Facility (NBTF), which is to be constructed in Padua, Italy. This paper gives an overview of the current status of the neutral beam (NB) systems and the chosen configuration. The ongoing integration effort into the ITER plant is highlighted and open interface issues are identified. It is shown how installation and maintenance logistics has influenced the design. ITER operating scenarios are briefly discussed, including start-up and commissioning. For example it is now envisaged to have a low current hydrogen phase of ITER operations, essentially for commissioning of the many auxiliary systems used on ITER. The low current limits the achievable plasma density, and hence the NB energy due to shine through limitations. Therefore a possible reconfiguration of the auxiliary heating systems is now being discussed. Other NB related issues identified by the ongoing design review process are emphasized and possible impact on the implementations of the HNB and DNB systems is indicated.

Schunke, B.; Bora, D.; Cordier, J.-J.; Hemsworth, R.; Tanga, A. [ITER Organization, Cadarache, 13108 St.-Paul-lez-Durance (France); Antoni, V. [Consorzio RFX, EURATOM-ENEA Association, Corso Stati Uniti 4, I-35127 (Italy); Bonicelli, T. [IPR, Bhat, Gandhinagar, Gujarat, 382428 (India); Chakraborty, A. [EFDA CSU, Boltzmannstrasse 2, D-85748, Garching (Germany); Inoue, T.; Watanabe, K. [JAEA, 801-1 Mukouyama, Naka-machi, Naka-gun, Ibaraki-ken 311-0193 (Japan)

2008-04-07T23:59:59.000Z

412

Analysis of a high-temperature heat exchanger for an externally-fired micro gas turbine  

Science Journals Connector (OSTI)

Abstract The externally-fired gas turbine (EFGT) can convert fuels such as coal, biomass, biomass gasification gas and solar energy into electricity and heat. The combination of this technology with biomass gasification gas represents an interesting option for gasification, for which it has been difficult to find a conversion technology. In this system, the heat exchanger deals with the contaminants of biomass derived gas instead of the turbine itself. However, these contaminants can build a deposit layer in the heat exchanger that can affect its performance. The heat exchanger is important in externally fired gas turbines since the turbine inlet temperature is directly dependent on its performance. Several studies on heat exchangers for externally fired gas turbines have been carried out. However, very few detailed studies were found comparing the performance of heat exchangers for externally fired gas turbines considering the effect of deposit materials on the surfaces. In this regard, this work compares the performance of a corrugated plate heat exchanger and a two-tube-passes shell and tube heat exchanger considering the effect of thickness of deposit material with different thermal conductivities on pressure drop and effectiveness. The results show that the effectiveness of the corrugated plate heat exchanger is more influenced at larger thicknesses of deposit materials than the two-tube-passes shell and tube heat exchanger. There is an exponential increase in the pressure drop of the plate heat exchanger while a monotonic increase of pressure drop is seen for the shell and tube heat exchanger. The increase in the thickness of the deposit material has two effects. On one hand, it increases the resistance to heat transfer and on the other hand, it reduces the through flow area increasing the velocity and hence the heat transfer coefficient. Additionally, the effectiveness of the heat exchangers had a stronger influence on the power output than the pressure drop.

Fabiola Baina; Anders Malmquist; Lucio Alejo; Bjrn Palm; Torsten H. Fransson

2015-01-01T23:59:59.000Z

413

Hydrothermal Exploration Best Practices and Geothermal Knowledge Exchange  

Open Energy Info (EERE)

Hydrothermal Exploration Best Practices and Geothermal Knowledge Exchange Hydrothermal Exploration Best Practices and Geothermal Knowledge Exchange on Openei Jump to: navigation, search OpenEI Reference LibraryAdd to library Conference Paper: Hydrothermal Exploration Best Practices and Geothermal Knowledge Exchange on Openei Abstract Though exploring for hydrothermal resources is not new, advances in exploration technologies and the pursuit of less visible resources have created a need to outline exploration best practices. This multi-year study outlines 21 geothermal exploration regions in the Western United States. These regions were developed based on the U.S. Geological Survey (USGS) physiographic regions, then adjusted to fit geothermal parameters such as differences in geologic regime, structure, heat source, surface effects

414

Technical Exchange and Cooperation Agreement between the Department of  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Technical Exchange and Cooperation Agreement between the Department Technical Exchange and Cooperation Agreement between the Department of Energy and the European Atomic Energy Community Technical Exchange and Cooperation Agreement between the Department of Energy and the European Atomic Energy Community The objective of this technical arrangement is to establish a framework for co-operation between the Parties in the field of nuclear-related technology research and development based upon mutual benefit. The co-operation is intended to occur in specific areas where the programs of the Parties complement one another as well as those in which comparability exists. 4.5.1.1.3.3_eu_agreement.pdf More Documents & Publications International_Agreements_January_2001_December_2004.pdf International Agreements Comments EM International Strategic Plan 2010-2015

415

Technical Exchange and Cooperation Agreement between the Department of  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Technical Exchange and Cooperation Agreement between the Department Technical Exchange and Cooperation Agreement between the Department of Energy and the European Atomic Energy Community Technical Exchange and Cooperation Agreement between the Department of Energy and the European Atomic Energy Community The objective of this technical arrangement is to establish a framework for co-operation between the Parties in the field of nuclear-related technology research and development based upon mutual benefit. The co-operation is intended to occur in specific areas where the programs of the Parties complement one another as well as those in which comparability exists. 4.5.1.1.3.3_eu_agreement.pdf More Documents & Publications International_Agreements_January_2001_December_2004.pdf International Agreements Comments Scanned_Agreement.pdf

416

Ion-Molecular Reactions in Plasma Containment Devices  

Science Journals Connector (OSTI)

We investigate ion-molecule charge exchange followed by dissociative electron recombination with molecular ions due to the presence of common impurities in a plasma-containment device. For a He+ plasma with N2 impurity, the ionic constituency of plasmas is changed from He+ to nitrogen ions with a time constant ?* given by ?*P(N2)?24 msec ? Torr. However, those ion-molecular recombination processes are not responsible for the enhanced plasma loss in the Princeton spherator at the best vacuum condition.

B. H. Ripin; M. Okabayashi; J. Schmidt; V. Voitsenja; V. Yoshikawa

1972-01-17T23:59:59.000Z

417

Technology Transfer: Available Technologies  

NLE Websites -- All DOE Office Websites (Extended Search)

Please refer to the list of technologies below for licensing and research Please refer to the list of technologies below for licensing and research collaboration availability. If you can't find the technology you're interested in, please contact us at TTD@lbl.gov. Biotechnology and Medicine DIAGNOSTICS AND THERAPEUTICS CANCER CANCER PROGNOSTICS 14-3-3 Sigma as a Biomarker of Basal Breast Cancer ANXA9: A Therapeutic Target and Predictive Marker for Early Detection of Aggressive Breast Cancer Biomarkers for Predicting Breast Cancer Patient Response to PARP Inhibitors Breast Cancer Recurrence Risk Analysis Using Selected Gene Expression Comprehensive Prognostic Markers and Therapeutic Targets for Drug-Resistant Breast Cancers Diagnostic Test to Personalize Therapy Using Platinum-based Anticancer Drugs Early Detection of Metastatic Cancer Progenitor Cells

418

Buildings-to-Grid Technical Opportunities: From the Information and Communications Technology Perspective  

Energy.gov (U.S. Department of Energy (DOE))

Information and communications technology (ICT) has enabled the integration of computer and audio-visual networks, leading to unprecedented exchange of data between various users and entities.

419

Vehicle Technologies Office Merit Review 2014: Innovative Manufacturin...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Innovative Manufacturing and Materials for Low-Cost Lithium-Ion Batteries Vehicle Technologies Office Merit Review 2014: Innovative Manufacturing and Materials for Low-Cost...

420

Vehicle Technologies Office Merit Review 2014: Overcoming Processing...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Office Merit Review 2014: Overcoming Processing Cost Barriers of High-Performance Lithium-Ion Battery Electrodes Vehicle Technologies Office Merit Review 2014: Overcoming...

Note: This page contains sample records for the topic "ion exchange technology" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Technology Transfer: Available Technologies  

NLE Websites -- All DOE Office Websites (Extended Search)

Software and Information Technologies Software and Information Technologies Algorithm for Correcting Detector Nonlinearites Chatelet: More Accurate Modeling for Oil, Gas or Geothermal Well Production Collective Memory Transfers for Multi-Core Processors Energy Efficiency Software EnergyPlus:Energy Simulation Software for Buildings Tools, Guides and Software to Support the Design and Operation of Energy Efficient Buildings Flexible Bandwidth Reservations for Data Transfer Genomic and Proteomic Software LABELIT - Software for Macromolecular Diffraction Data Processing PHENIX - Software for Computational Crystallography Vista/AVID: Visualization and Allignment Software for Comparative Genomics Geophysical Software Accurate Identification, Imaging, and Monitoring of Fluid Saturated Underground Reservoirs

422

Shell and Tube Heat Exchangers  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

Unconventional Resources Technology Unconventional Resources Technology Advisory Committee Comments and Recommendations 2007 Unconventional Gas Research and Development Annual Plan July, 2007 Unconventional Resources Technology Advisory Committee Report TABLE OF CONTENTS 1.0 INTRODUCTION............................................................................................................... 3 2.0 EXECUTIVE SUMMARY AND RECOMMENDATIONS ................................................... 4 3.0 SUB GROUP REPORTS .................................................................................................. 6 3.1 TECHNOLOGY TRANSFER ................................................................................. 7 3.2 REGULATION .......................................................................................................

423

Conduction in Multiphase ParticulateFibrous Networks Simulations and Experiments on Li-ion Anodes  

E-Print Network (OSTI)

promising Li-ion battery technologies incorporate nanoarchitectured carbon networks, typically in the form electronically February 7, 2003. Several promising Li-ion battery technologies incorporate nanoarchitecturedConduction in Multiphase Particulate?Fibrous Networks Simulations and Experiments on Li-ion Anodes

Sastry, Ann Marie

424

Chapter 2 - Water Electrolysis Technologies  

Science Journals Connector (OSTI)

Abstract The purpose of this chapter is to provide an overview of the different water electrolysis technologies. In the introduction section, the general characteristics of water electrolysis (thermodynamics, kinetics, efficiency) are described. Main electrolysis technologies used to produce hydrogen and oxygen of electrolytic grade are then described in the following sections. Alkaline water electrolysis is described in Section 2.2, proton-exchange membrane water electrolysis in Section 2.3 and high-temperature water electrolysis in Section 2.4. For each technology, state-of-the-art performances are analyzed, limitations are identified and some perspectives are discussed.

Pierre Millet; Sergey Grigoriev

2013-01-01T23:59:59.000Z

425

Advanced Heat/Mass Exchanger Technology for Geothermal and solar...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

& Publications Guide to Developing Air-Cooled Lithium Bromide (LiBr) Absorption for CHP Applications, April 2005 CX-003216: Categorical Exclusion Determination Air-Cooled...

426

Technology Performance Exchange - 2013 BTO Peer Review | Department...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Building Energy Modeling Library Whole Building Performance-Based Procurement Training Small- and Medium-Size Building Automation and Control System Needs: Scoping Study...

427

East-West Exchanges of Technology Increase Rapidly  

Science Journals Connector (OSTI)

...overall So-viet imports rose by no less...dramatic increase in imports of Western tech-niqVes...equipment for petroleum refining, and...decide to permit export of such computers...de-cision to defer exports of computers...and machinery, China is now beginning...supply of Soviet petroleum, for which a...

Victor K. McElheny

1966-07-08T23:59:59.000Z

428

Secondary Heat Exchanger Design and Comparison for Advanced High Temperature Reactor  

SciTech Connect

The goals of next generation nuclear reactors, such as the high temperature gas-cooled reactor and advance high temperature reactor (AHTR), are to increase energy efficiency in the production of electricity and provide high temperature heat for industrial processes. The efficient transfer of energy for industrial applications depends on the ability to incorporate effective heat exchangers between the nuclear heat transport system and the industrial process heat transport system. The need for efficiency, compactness, and safety challenge the boundaries of existing heat exchanger technology, giving rise to the following study. Various studies have been performed in attempts to update the secondary heat exchanger that is downstream of the primary heat exchanger, mostly because its performance is strongly tied to the ability to employ more efficient conversion cycles, such as the Rankine super critical and subcritical cycles. This study considers two different types of heat exchangershelical coiled heat exchanger and printed circuit heat exchangeras possible options for the AHTR secondary heat exchangers with the following three different options: (1) A single heat exchanger transfers all the heat (3,400 MW(t)) from the intermediate heat transfer loop to the power conversion system or process plants; (2) Two heat exchangers share heat to transfer total heat of 3,400 MW(t) from the intermediate heat transfer loop to the power conversion system or process plants, each exchanger transfers 1,700 MW(t) with a parallel configuration; and (3) Three heat exchangers share heat to transfer total heat of 3,400 MW(t) from the intermediate heat transfer loop to the power conversion system or process plants. Each heat exchanger transfers 1,130 MW(t) with a parallel configuration. A preliminary cost comparison will be provided for all different cases along with challenges and recommendations.

Piyush Sabharwall; Ali Siahpush; Michael McKellar; Michael Patterson; Eung Soo Kim

2012-06-01T23:59:59.000Z

429

Calorimetry exchange program quarterly data report, fourth quarter CY92  

SciTech Connect

The goals of the Calorimetry Sample Exchange Program are: (1) discuss measurement differences (2) review and improve analytical measurements and methods (3) discuss new measurement capabilities (4) provide data to DOE on measurement capabilities to evaluate shipper- receiver differences (5) provide characterized or standard materials as necessary for exchange participants (6) provide a measurement control program for plutonium analysis A sample Of PUO2 powder is available at each participating site for NDA measurement, including either or both calorimetry and high-resolution gamma-ray spectroscopy, the elements which are typically combined to provide a calorimetric assay of plutonium. The facilities measure the sample as frequently and to the level of precision which they desire, and then submit the data to the Exchange for analysis. The data report includes summary tables for each measurement and charts showing the performance of each laboratory. Comparisons are made to the accepted values for the exchange sample and to data previously reported by that laboratory. This information is presented, in the form of quarterly reports as this document provides and as annual reports, intended for use by Exchange participants in measurement control programs, or to indicate when bias corrections may be appropriate. No attempt, however, has been made to standardize methods or frequency of data collection, calibration, or operating procedures. Direct comparisons between laboratories may, therefore, be misleading since data have not been collected to the same precision or for the same time periods. A meeting of the participants of the Calorimetry Exchange is held annually at EG&G Mound Applied Technologies. The purposes of this meeting are to discuss measurement differences, problems, and new measurement capabilities, and to determine the additional activities needed to fulfill the goals of the Exchange.

Barnett, T.M.

1992-12-31T23:59:59.000Z

430

ANSI Summary of US-China Exchange on EV Standardization  

NLE Websites -- All DOE Office Websites (Extended Search)

ANSI Summary of US-China Exchange on EV ANSI Summary of US-China Exchange on EV Standardization Presented by: Jim McCabe Senior Director, Standards Facilitation American National Standards Institute US.-China Electric Vehicles and Battery Technology Workshop August 23, 2012 ANSI EVSP Roadmap | US-China EV and Battery Technology Workshop Background - Why the Need for a U.S. Standardization Roadmap for EVs?  Many U.S. based standards developing organizations (SDOs) produce globally relevant standards following an open, consensus-based process (SAE, UL, NFPA, IEEE, and others)  A standardization roadmap would . . . Maximize coordination among SDOs and provide guidance on standards participation and progress  Enable the U.S. to speak more coherently with international partners

431

Batteries for Plug-in Hybrid Electric Vehicles (PHEVs): Goals and the State of Technology circa 2008  

E-Print Network (OSTI)

safety and cost. Third, Li-Ion battery designs are betterattributes of one type of Li-Ion battery cannot necessarilycapabilities. In any case, Li-Ion battery technologies hold

Axsen, Jonn; Burke, Andy; Kurani, Kenneth S

2008-01-01T23:59:59.000Z

432

Emerging Technologies  

Energy.gov (U.S. Department of Energy (DOE))

The Emerging Technologies (ET) Program of the Building Technologies Office (BTO) supports applied research and development (R&D) for technologies, systems, and models that contribute to building energy consumption.

433

Exploring knowledge diffusion among nations: a study of core technologies in fuel cells  

Science Journals Connector (OSTI)

Technological trajectory is a representation of the development of technology. Based on the analysis of the trajectories of prominent technologies, we can explore the phenomena of technology evolution and knowledge diffusion. In this study, we focus ... Keywords: Knowledge diffusion, Membrane electrode assembly (MEA), Patent citation network, Proton exchange membrane fuel cells (PEMFCs), Technological trajectory

Mei Hsiu-Ching Ho; Vincent H. Lin; John S. Liu

2014-07-01T23:59:59.000Z

434

Technology Transfer  

NLE Websites -- All DOE Office Websites (Extended Search)

Technology Transfer Since 1974, the Federal Laboratory Consortium (FLC) Award for Excellence in Technology Transfer has recognized scientists and engineers at federal government...

435

Tools & Technologies  

Energy.gov (U.S. Department of Energy (DOE))

Weprovide leadership for transforming workforce development through the power of technology. It develops corporate educational technology policy and enables the use of learning tools and...

436

Vacancy association energy in scandium doped ceria: 45Sc MAS NMR and 2D exchange spectroscopy study  

Science Journals Connector (OSTI)

Abstract Oxygen vacancy exchange between Sc ions in 0.5% Sc-doped ceria Sc0.005Ce0.995O0.9975 is investigated by means of 2D exchange spectroscopy (EXSY). 45Sc NMR spectrum of Sc-doped ceria contains two peaksone corresponding to Sc ions coupled with an oxygen vacancy (Sc-7), and the other corresponding to Sc ions in a regular lattice site surrounded by eight oxygen ions (Sc-8). The vacancy exchange between these two Sc sites generates the cross-peaks in the EXSY spectrum. Relative amplitudes of the cross-peaks provide direct values of the exchange frequency at a given temperature. Arrhenius analysis of the exchange frequency gives the activation energy Ea=1.18eV for the vacancy hopping between Sc sites. Most of this energy barrier is due to association energy which binds the vacancy to Sc3+. Large dopantvacancy association energy in Sc doped ceria is demonstrated by 45Sc NMR spectrum of La/Sc doubly doped sample, ScxLaxCe1?2xO2?x, x=0.005, where the only line of Sc-7 site shows that all vacancies are bound by Sc3+ ions.

Reio Pder; Juhan Subbi; Helgi Kooskora; Ivo Heinmaa

2014-01-01T23:59:59.000Z

437

Defluoridation of drinking water using metal embedded biocarbon technology  

Science Journals Connector (OSTI)

The water that circulates in contact with fluorinated ores is particularly rich in fluoride. The beneficial and the harmful effects of fluoride consumption are well documented. The dental and skeletal fluorosis is the widespread harmful effects of a long consumption of fluoride. WHO recommended level of fluoride in drinking water is 1.5 mg/L. Different methods have been tested for defluoridation of waters such as coagulation, adsorption, precipitation, ion exchange, reverse osmosis, and electrodialysis. The metal embedded biocarbon sorption method is promising in defluoridation of drinking water. The optimal operating conditions such as effect of contact time, effect of pH and effect of adsorbent dose for fluoride removal from aqueous solution using metal embedded biocarbon technology have been determined on synthetic wastewater. The temperature for the continuous mode of experiments was 27 2C. The result indicates that maximum removal (98%) of fluoride ion was achieved in 180 minutes. The amount of biocarbon dose is 2.0 g. The present results highlight the use of indigenous medicinal plants for the removal of fluoride in ground water. It is economically feasible option because of its bioavailability and its efficiency.

Malairajan Singanan

2013-01-01T23:59:59.000Z

438

Multi-block sulfonated poly(phenylene) copolymer proton exchange membranes  

DOE Patents (OSTI)

Improved multi-block sulfonated poly(phenylene) copolymer compositions, methods of making the same, and their use as proton exchange membranes (PEM) in hydrogen fuel cells, direct methanol fuel cells, in electrode casting solutions and electrodes. The multi-block architecture has defined, controllable hydrophobic and hydrophilic segments. These improved membranes have better ion transport (proton conductivity) and water swelling properties.

Fujimoto, Cy H. (Albuquerque, NM); Hibbs, Michael (Albuquerque, NM); Ambrosini, Andrea (Albuquerque, NM)

2012-02-07T23:59:59.000Z

439

Synthesis, Structural Characterization, and Catalytic Properties of Tungsten-Exchanged Weiping Ding, George D. Meitzner, David O. Marler,| and Enrique Iglesia*  

E-Print Network (OSTI)

exchanged W/H-ZSM5. 1. Introduction Transition metal ions (e.g., Mo, W, V, Fe, Cr) loaded onto several between oxides or carbides of Mo and W. The synthesis of exchanged WOx precursors and their subsequent. They detected carbidic carbon on Mo/H-ZSM5 and showed that MoOx species reduce almost to Mo0 during reaction.10

Iglesia, Enrique

440

Fast time resolution charge-exchange measurements during the fishbone instability in the poloidal divertor experiment  

SciTech Connect

Measurements of fast ion losses due to the fishbone instability during high ..beta../sub T/q neutral beam heated discharges in the Poloidal Divertor Experiment have been made using two new vertical-viewing charge-exchange analyzers. The measurements show that the instability has an n=1 toroidal mode number, and that it ejects beam ions in a toroidally rotating beacon directed outward along a major radius. Observations of ejected ions with energies up to twice the beam injection energy at R approx. = R/sub 0/ + a indicate the presence of a non-..mu..-conserving acceleration mechanism.

Beiersdorfer, P.; Kaita, R.; Goldston, R.J.

1984-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "ion exchange technology" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

C60 Secondary Ion Fourier Transform Ion Cyclotron Resonance Mass...  

NLE Websites -- All DOE Office Websites (Extended Search)

C60 Secondary Ion Fourier Transform Ion Cyclotron Resonance Mass Spectrometry. C60 Secondary Ion Fourier Transform Ion Cyclotron Resonance Mass Spectrometry. Abstract: Secondary...

442

Anion-exchange resin-based desulfurization process. Final report  

SciTech Connect

The following investigations were performed: (1) batch mode screening of eleven(11) commercially available resins and selection of three candidate resins for further evaluation in a fixed-bed setup. (2) Process variables study using three candidate resins in the fixed-bed setup and selection of the ``best`` resin for process economics development. (3) Exhaustion efficiency and solution concentration were found to be inversely related necessitating a trade-off between the resin cost versus the cost of evaporation/concentration of ensuing effluents. (4) Higher concentration of the HCO{sub 3}{sup {minus}} form of active sites over less active CO{sub 3}{sup 2{minus}} form of sites in the resin was believed to be the main reason for the observed increase in the equilibrium capacity of the resin at an elevated static CO{sub 2}-pressure. This Increase in capacity was found to level off around 80--120 psig range. The increase in CO{sub 2}-pressure, however, did not appear to affect the overall ion-exchange kinetics. (5) In the fixed-bed mode, the solution concentration was found to affect the equilibrium capacity of candidate resins. Their relationship was well satisfied by the Langmuir type non-linear equilibrium isotherm. Alternatively, the effect of solution concentration on overall ion-exchange kinetics varied from resin to resin. (6) Product inhibition effect on the resin was observed as an initial increase followed by a significant decrease in the resin`s equilibrium capacity for SO{sub 4}{sup 2{minus}} as the HCO{sub 3}{sup {minus}}/SO{sub 4}{sup 2{minus}} molar ratio in the solution was increased from 0 to 1.0. This ratio, however, did not affect the overall ion-exchange kinetics.

Sheth, A C; Dharmapurikar, R; Strevel, S D

1994-01-01T23:59:59.000Z

443

Exploration Technologies Technology Needs Assessment  

Energy.gov (U.S. Department of Energy (DOE))

The Exploration Technologies Needs Assessment is a critical component of ongoing technology roadmapping efforts, and will be used to guide the program's research and development.

444

Softhard exchange-coupled layered structures with modulated exchange coupling  

E-Print Network (OSTI)

, Tuscaloosa, Alabama 35487-0209 Received 8 April 2003; accepted 28 June 2003 Magnetically soft/hard exchange-coupled for high performance permanent magnets in the past decades and much progress has been made in improving permanent mag- netic properties. A figure of merit of permanent magnetic materials is the maximum magnetic

Garmestani, Hamid

445

Ion beam induced surface and interface engineering  

Science Journals Connector (OSTI)

The injection of material into a target specimen in the form of an accelerated ion beam offers a most valuable tool for altering its physical, chemical, structural, surface and interface properties in a controlled manner and tailoring new materials for basic and applied research for science and technology. The present review describes experimental, theoretical and recent aspects of ion beam modifications at various solids, thin films, and multilayered systems covering wider energy ranges including the older basic concepts which are now of interest. These results reveal that the ionsolid interaction physics provides a unique way for controlling the produced defects of the desired type at a desired location. These interests have been stimulated by the possibilities of synthesizing novel materials with potential applications in the field of thin films, surfaces and interface science. Many applications of ion induced engineering are being developed for various sciences of high technological interest for future aspects.

I.P. Jain; Garima Agarwal

2011-01-01T23:59:59.000Z

446

Energy Technologies  

Energy.gov (U.S. Department of Energy (DOE))

Best practices, project resources, and other tools on energy efficiency and renewable energy technologies.

447

Test results of a Stirling engine utilizing heat exchanger modules with an integral heat pipe  

SciTech Connect

The Heat Pipe Stirling Engine (HP-1000), a free-piston Stirling engine incorporating three heat exchanger modules, each having a sodium filled heat pipe, has been tested at the NASA-Lewis Research Center as part of the Civil Space Technology Initiative (CSTI). The heat exchanger modules were designed to reduce the number of potential flow leak paths in the heat exchanger assembly and incorporate a heat pipe as the link between the heat source and the engine. An existing RE-1000 free-piston Stirling engine was modified to operate using the heat exchanger modules. This paper describes heat exchanger module and engine performance during baseline testing. Condenser temperature profiles, brake power, and efficiency are presented and discussed.

Skupinski, R.C.; Tower, L.K.; Madi, F.J.; Brusk, K.D.

1993-04-01T23:59:59.000Z

448

Heat Pump Cycle with Solution Circuit and Internal Heat Exchange  

E-Print Network (OSTI)

-stage cycle, the heat transfer area required on the refrigerant side will increase by 10~ compared to the ammonia cycl e. CONCLUSIONS The hea t p1llllp cycl e employ ing one sol ut ion circuit and absorber/de sorber heat exchange has a more sophisticated... when a two-stage version fed into the same compressor. While ammonia of this cycl e is used. In this paper. another evaporate s out of an ammonia-water sol ution on C version of such cycles will be discussed which the composition. X. of this solution...

Radermacher, R.

449

SWNT?MWNT Hybrid Architecture for Proton Exchange Membrane Fuel Cell Cathodes  

Science Journals Connector (OSTI)

SWNT?MWNT Hybrid Architecture for Proton Exchange Membrane Fuel Cell Cathodes ... A thin film of single-wall carbon nanotubes (SWNTs) and SWNT?multiwall carbon nanotube (MWNT) hybrids loaded with Pt have been evaluated as the cathode catalyst layer in proton exchange membrane fuel cells. ... Hydrogen, Fuel Cells & Infrastructure Technologies Program: Multi-Year Research, Development and Demonstration Plan: Planned Program Activities for 2003?2010; U.S. Department of Energy: Energy Efficiency and Renewable Energy: January 21, 2005. ...

Palanisamy Ramesh; Mikhail E. Itkis; Jason M. Tang; Robert C. Haddon

2008-05-28T23:59:59.000Z

450

Method and apparatus for removing ions from soil  

DOE Patents (OSTI)

A method and apparatus are presented for selectively removing species of ions from an area of soil. Permeable membranes 14 and 18 impregnated with an ion exchange resin that is specific to one or more species of chemical ions are inserted into ground 12 in close proximity to, and on opposing sides of, a soil area of interest 22. An electric potential is applied across electrodes 26 and 28 to cause the migration of ions out of soil area 22 toward the membranes 14 and 18. Preferably, the resin exchanges ions of sodium or hydrogen for ions of mercury that it captures from soil area 22. Once membranes 14 and 18 become substantially saturated with mercury ions, the potential applied across electrodes 26 and 28 is discontinued and membranes 14 and 18 are preferably removed from soil 12 for storage or recovery of the ions. The membranes are also preferably impregnated with a buffer to inhibit the effect of the hydrolysis of water by current from the electrodes.

Bibler, J.P.

1993-03-02T23:59:59.000Z

451

Method and apparatus for removing ions from soil  

DOE Patents (OSTI)

A method and apparatus for selectively removing species of ions from an area of soil. Permeable membranes 14 and 18 impregnated with an ion exchange resin that is specific to one or more species of chemical ions are inserted into ground 12 in close proximity to, and on opposing sides of, a soil area of interest 22. An electric potential is applied across electrodes 26 and 28 to cause the migration of ions out of soil area 22 toward the membranes 14 and 18. Preferably, the resin exchanges ions of sodium or hydrogen for ions of mercury that it captures from soil area 22. Once membranes 14 and 18 become substantially saturated with mercury ions, the potential applied across electrodes 26 and 28 is discontinued and membranes 14 and 18 are preferably removed from soil 12 for storage or recovery of the ions. The membranes are also preferably impregnated with a buffer to inhibit the effect of the hydrolysis of water by current from the electrodes.

Bibler, Jane P. (813 E. Rollingwood Rd., Aiken, SC 29801)

1993-01-01T23:59:59.000Z

452

Ion Monitoring  

DOE Patents (OSTI)

The apparatus and method provide a technique for significantly reducing capacitance effects in detector electrodes arising due to movement of the instrument relative to the item/location being monitored in ion detection based techniques. The capacitance variations are rendered less significant by placing an electrically conducting element between the detector electrodes and the monitored location/item. Improved sensitivity and reduced noise signals arise as a result. The technique also provides apparatus and method suitable for monitoring elongate items which are unsuited to complete enclosure in one go within a chamber. The items are monitored part by part as the pass through the instrument, so increasing the range of items or locations which can be successfully monitored.

Orr, Christopher Henry (Calderbridge, GB); Luff, Craig Janson (Calderbridge, GB); Dockray, Thomas (Calderbridge, GB); Macarthur, Duncan Whittemore (Los Alamos, NM)

2003-11-18T23:59:59.000Z

453

Primer on nuclear exchange models  

SciTech Connect

Basic physics is applied to nuclear force exchange models between two nations. Ultimately, this scenario approach can be used to try and answer the age old question of 'how much is enough?' This work is based on Chapter 2 of Physics of Societal Issues: Calculations on National Security, Environment and Energy (Springer, 2007 and 2014)

Hafemeister, David [Physics Department, Cal Poly University, San Luis Obispo, California (United States)

2014-05-09T23:59:59.000Z

454

Ion-mobility Spectrometry Based NOx Sensor - Nuclear Engineering Division  

NLE Websites -- All DOE Office Websites (Extended Search)

NPNS > Sensors and NPNS > Sensors and Instrumentation and NDE > Energy System Application > DOE Office of Transportation Technologies > Ion-mobility Spectrometry Based NOx Sensor Capabilities Sensors and Instrumentation and Nondestructive Evaluation Overview Energy System Applications Overview DOE Office of Fossil Energy DOE Office of Transportation Technologies Ion-mobility Spectrometry Based NOx Sensor DOE Office of Power Technology Work for Others Safety-Related Applications Homeland Security Applications Biomedical Applications Millimiter Wave Group Papers Other NPNS Capabilities Work with Argonne Contact us For Employees Site Map Help Join us on Facebook Follow us on Twitter NE on Flickr Sensors and Instrumentation and Nondestructive Evaluation Ion-mobility Spectrometry Based NOx Sensor

455

Multiple pollutant removal using the condensing heat exchanger. Task 3, Long term testing at the ECTC  

SciTech Connect

The objective of this task is to demonstrate long term operation of a condensing heat exchanger for coal-fired conditions. A small condensing heat exchanger will be installed at the Environmental Control Technology Center in Barker, New York. It will be installed downstream of the flue gas particulate removal system. The test will determine the amount of wear, if any, on the Teflon{trademark} covered internals of the heat exchanger. Visual inspection and measurements will be obtained for the Teflon{trademark} covered tubes during the test. The material wear study will conducted over a one year calendar period, and the CHX equipment will be operated to the fullest extent allowable.

Schulze, K.H.

1996-01-01T23:59:59.000Z

456

Improved Electrode Materials in Lithium-Ion (Li-ion) Batteries: Innovation  

NLE Websites -- All DOE Office Websites (Extended Search)

Improved Electrode Materials in Lithium-Ion (Li-ion) Batteries: Innovation Improved Electrode Materials in Lithium-Ion (Li-ion) Batteries: Innovation and Optimization Speaker(s): Jordi Cabana-Jimenez Date: January 14, 2008 - 12:00pm Location: 90-3122 Seminar Host/Point of Contact: Venkat Srinivasan The advent of Li-ion batteries has played a central role in the impressive development of portable digital and wireless technology. Such success has triggered further efforts to utilize them as key components in other applications with an even larger impact on society, which include electric vehicles and energy backup for renewable energy sources. However, several challenges need to be met before these expectations can be realized, as Li-ion batteries currently do not meet the power and energy density requirements of these devices. New and better materials for the electrodes

457

ion microprobe | EMSL  

NLE Websites -- All DOE Office Websites (Extended Search)

microprobe ion microprobe Leads No leads are available at this time. Magnesium behavior and structural defects in Mg+ ion implanted silicon carbide. Abstract: As a candidate...

458

EMSL - secondary ion detection  

NLE Websites -- All DOE Office Websites (Extended Search)

secondary-ion-detection en Magnesium behavior and structural defects in Mg+ ion implanted silicon carbide. http:www.emsl.pnl.govemslwebpublicationsmagnesium-behavior-and-struc...

459

(K4Li4)Al8Ge8O328H2O: an Li+-exchanged potassium aluminogermanate with the zeolite gismondine (GIS) topology  

Science Journals Connector (OSTI)

The title microporous material, (K,Li)-(Al,Ge)-GIS, namely lithium potassium dialuminium digermanium octaoxide dihydrate, is the result of a 50% Li+ exchange into the K-(Al,Ge)-GIS structure. A structural change occurs due to disordering of K+ ions with Li+ ions along [001] and ordering of water molecules along [101].

Celestian, A.J.

2003-07-12T23:59:59.000Z

460

Significant Cost Improvement of Li-Ion Cells Through Non-NMP...  

Energy.gov (U.S. Department of Energy (DOE)) Indexed Site

2 DOE Program Review: Significant Cost Improvement of Li- Ion Cells Through Non-NMP Electrode Coating, Direct Separator Coating, and Fast Formation Technologies PI: YK Son...

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461

Innovative Manufacturing and Materials for Low-Cost Lithium-Ion...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Manufacturing and Materials for Low-Cost Lithium-Ion Batteries 2012 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer...

462

Heat Exchanger Fouling- Prediction, Measurement and Mitigation  

E-Print Network (OSTI)

The U. S. Department of Energy (DOE), Office of Industrial Programs (OIP) sponsors the development of innovative heat exchange systems. Fouling is a major and persistent cost associated with most industrial heat exchangers and nationally wastes...

Peterson, G. R.

463

Building Technologies Office: Partner with DOE and Emerging Technologies  

NLE Websites -- All DOE Office Websites (Extended Search)

with DOE and Emerging Technologies with DOE and Emerging Technologies The U.S. Department of Energy (DOE) seeks partnerships to research and develop energy efficient building technologies, including advanced lighting, heating, ventilating and air conditioning (HVAC), building envelope (walls and roof), windows, water heating, appliances, and sensors and controls. Some partnership opportunities are described below. Industries Manufacturers and other developers of building energy efficient technologies are encouraged to apply to one of our funding solicitations, called funding opportunity announcements (FOAs), which are posted on the EERE Funding Opportunity Exchange. Interested industries may also consider partnering with one of the DOE-supported national laboratories (Oak Ridge National Laboratory, Lawrence Berkeley National Laboratory, National Renewable Energy Laboratory, Pacific Northwest National Laboratory, etc.) to jointly develop market-ready