Sample records for ion exchange resins

  1. Vitrification of ion exchange resins

    DOE Patents [OSTI]

    Cicero-Herman, Connie A. (Aiken, SC); Workman, Rhonda Jackson (North Augusta, SC)

    2001-01-01T23:59:59.000Z

    The present invention relates to vitrification of ion exchange resins that have become loaded with hazardous or radioactive wastes, in a way that produces a homogenous and durable waste form and reduces the disposal volume of the resin. The methods of the present invention involve directly adding borosilicate glass formers and an oxidizer to the ion exchange resin and heating the mixture at sufficient temperature to produce homogeneous glass.

  2. Grafted methylenediphosphonate ion exchange resins

    DOE Patents [OSTI]

    Trochimcznk, A.W.; Gatrone, R.C.; Alexandratos, S.; Horwitz, E.P.

    1997-04-08T23:59:59.000Z

    An ion exchange resin is disclosed that is comprised of an insoluble copolymer onto which are grafted pendent groups that provide 1.0 to about 10 mmol/g dry weight phosphorus. The pendent groups have the formula as shown in the patent wherein R is hydrogen, a cation or mixtures thereof; and R{sup 1} is hydrogen or an C{sub 1}-C{sub 2} alkyl group. The resin also contains zero to about 5 mmol/g dry weight of pendent aromatic sulfonate groups. Processes for making and using an ion exchange resin are also disclosed.

  3. Phosphonic acid based ion exchange resins

    DOE Patents [OSTI]

    Horwitz, E.P.; Alexandratos, S.D.; Gatrone, R.C.; Chiarizia, R.

    1994-01-25T23:59:59.000Z

    An ion exchange resin is described for extracting metal ions from a liquid waste stream. An ion exchange resin is prepared by copolymerizing a vinylidene diphosphonic acid with styrene, acrylonitrile and divinylbenzene. 9 figures.

  4. Phosphonic acid based ion exchange resins

    DOE Patents [OSTI]

    Horwitz, E.P.; Alexandratos, S.D.; Gatrone, R.C.; Chiarizia, R.

    1996-07-23T23:59:59.000Z

    An ion exchange resin is described for extracting metal ions from a liquid waste stream. An ion exchange resin is prepared by copolymerizing a vinylidene diphosphonic acid with styrene, acrylonitrile and divinylbenzene. 10 figs.

  5. MODELING RESULTS FROM CESIUM ION EXCHANGE PROCESSING WITH SPHERICAL RESINS

    SciTech Connect (OSTI)

    Nash, C.; Hang, T.; Aleman, S.

    2011-01-03T23:59:59.000Z

    Ion exchange modeling was conducted at the Savannah River National Laboratory to compare the performance of two organic resins in support of Small Column Ion Exchange (SCIX). In-tank ion exchange (IX) columns are being considered for cesium removal at Hanford and the Savannah River Site (SRS). The spherical forms of resorcinol formaldehyde ion exchange resin (sRF) as well as a hypothetical spherical SuperLig{reg_sign} 644 (SL644) are evaluated for decontamination of dissolved saltcake wastes (supernates). Both SuperLig{reg_sign} and resorcinol formaldehyde resin beds can exhibit hydraulic problems in their granular (nonspherical) forms. SRS waste is generally lower in potassium and organic components than Hanford waste. Using VERSE-LC Version 7.8 along with the cesium Freundlich/Langmuir isotherms to simulate the waste decontamination in ion exchange columns, spherical SL644 was found to reduce column cycling by 50% for high-potassium supernates, but sRF performed equally well for the lowest-potassium feeds. Reduced cycling results in reduction of nitric acid (resin elution) and sodium addition (resin regeneration), therefore, significantly reducing life-cycle operational costs. These findings motivate the development of a spherical form of SL644. This work demonstrates the versatility of the ion exchange modeling to study the effects of resin characteristics on processing cycles, rates, and cold chemical consumption. The value of a resin with increased selectivity for cesium over potassium can be assessed for further development.

  6. Method and solvent composition for regenerating an ion exchange resin

    DOE Patents [OSTI]

    Even, William R. (Livermore, CA); Irvin, David J. (Livermore, CA); Irvin, Jennifer A. (Livermore, CA); Tarver, Edward E. (Livermore, CA); Brown, Gilbert M. (Knoxville, TN); Wang, James C. F. (Livermore, CA)

    2002-01-01T23:59:59.000Z

    A method and composition for removing perchlorate from a highly selective ion exchange resin is disclosed. The disclosed approach comprises treating the resin in a solution of super critical or liquid carbon dioxide and one or more quaternary ammonium chloride surfactant compounds.

  7. Investigating the Use of Ion Exchange Resins for Processing Biodiesel Feedstocks 

    E-Print Network [OSTI]

    Jamal, Yousuf 1973-

    2012-11-27T23:59:59.000Z

    Ion exchange resins, commonly used in water treatment, demonstrate promise for the production of biodiesel from biomass feedstocks. The goal of this presented PhD research is to investigate novel uses of ion exchange resins for processing biodiesel...

  8. Investigating the Use of Ion Exchange Resins for Processing Biodiesel Feedstocks

    E-Print Network [OSTI]

    Jamal, Yousuf 1973-

    2012-11-27T23:59:59.000Z

    Ion exchange resins, commonly used in water treatment, demonstrate promise for the production of biodiesel from biomass feedstocks. The goal of this presented PhD research is to investigate novel uses of ion exchange resins for processing biodiesel...

  9. CHARACTERIZATION OF CYCLED SPHERICAL RESORCINOL-FORMALDEHYDE ION EXCHANGE RESIN

    SciTech Connect (OSTI)

    Nash, C.; Duignan, M.

    2010-02-23T23:59:59.000Z

    This report presents characterization data for two spherical resorcinol-formaldehyde (sRF) resin beds that had processed cesium in non-radioactive and radioactive cycles. All column cycle operations for the resin beds including loading, displacements, elution, regeneration, breakthroughs, and solution analyses are reported in Nash and Duignan, 2009a. That report covered four ion exchange (IX) campaigns using the two {approx}11 mL beds in columns in a lead-lag arrangement. The first two campaigns used Savannah River Site (SRS) Tank 2F nonradioactive simulant while the latter two were fed with actual dissolved salt in the Savannah River National Laboratory (SRNL) Shielded Cells. Both radioactive cycles ran to cesium breakthrough of the lead column. The resin beds saw in excess of 400 bed volumes of feed in each cycle. Resin disposal plans in tank farm processing depend on characterizations of resin used with actual tank feed. Following a final 30 bed volume (BV) elution with nitric acid, the resin beds were found to contain detectable chromium, barium, boron, aluminum, iron, sodium, sulfur, plutonium, cesium, and mercury. Resin affinity for plutonium is important in criticality safety considerations. Cesium-137 was found to be less than 10E+7 dpm/g of resin, similar to past work with sRF resin. Sulfur levels are reasonably consistent with other work and are expected to represent sulfur chemistry used in the resin manufacture. There were low but detectable levels of technetium, americium, and curium. Toxicity Characteristic Leaching Procedure (TCLP) work on the used (eluted) resin samples showed significant contents of mercury, barium, and chromium. One resin sample exceeded the TCLP level for mercury while the other metals were below TCLP levels. TCLP organics measurements indicated measurable benzene in one case, though the source was unknown. Results of this work were compared with other work on similar sRF resin characterizations in this report. This is the first work to quantify mercury on sRF resin. Resin mercury content is important in plans for the disposition of used sRF resin. Mercury speciation in high level waste (HLW) is unknown. It may be partly organic, one example being methyl mercury cation. Further study of the resin's affinity for mercury is recommended.

  10. Experience with NuResin, a mobile ion exchange resin reprocessing system

    SciTech Connect (OSTI)

    Palazzi, K.R.; Bell, M.J.; Concklin, J.R. [B& W Nuclear Technologies, Lynchburg, VA (United States)

    1995-12-31T23:59:59.000Z

    Ion exchange resin used in condensate polishing, steam generator blowdown, and radwaste systems is a major contributor to the volume of low-level waste (LLW) at operating nuclear plants. Plant regeneration systems for resins use large quantities of demineralized water for cleaning, separating, and regenerating resins. These systems generate a tremendous volume of LLW from boiling water reactors (BWRs) and those pressurized water reactors (PWRs) that have experienced steam generator tube leaks. At essentially all BWRs and those PWRs that replace rather than regenerate condensate polishing resin, the LLW volume contribution from the resin alone is significant. This report describes a process for the treatment of resins with the objective of returning the resin to service.

  11. Vitrification of cesium-contaminated organic ion exchange resin

    SciTech Connect (OSTI)

    Sargent, T.N. Jr. [Clemson Univ., SC (United States)

    1994-08-01T23:59:59.000Z

    Vitrification has been declared by the Environmental Protection Agency (USEPA) as the Best Demonstrated Available Technology (BDAT) for the permanent disposal of high-level radioactive waste. Savannah River Site currently uses a sodium tetraphenylborate (NaTPB) precipitation process to remove Cs-137 from a wastewater solution created from the processing of nuclear fuel. This process has several disadvantages such as the formation of a benzene waste stream. It has been proposed to replace the precipitation process with an ion exchange process using a new resorcinol-formaldehyde resin developed by Savannah River Technical Center (SRTC). Preliminary tests, however, showed that problems such as crust formation and a reduced final glass wasteform exist when the resin is placed in the melter environment. The newly developed stirred melter could be capable of overcoming these problems. This research explored the operational feasibility of using the stirred tank melter to vitrify an organic ion exchange resin. Preliminary tests included crucible studies to determine the reducing potential of the resin and the extent of oxygen consuming reactions and oxygen transfer tests to approximate the extent of oxygen transfer into the molten glass using an impeller and a combination of the impeller and an external oxygen transfer system. These preliminary studies were used as a basis for the final test which was using the stirred tank melter to vitrify nonradioactive cesium loaded organic ion exchange resin. Results from this test included a cesium mass balance, a characterization of the semi-volatile organic compounds present in the off gas as products of incomplete combustion (PIC), a qualitative analysis of other volatile metals, and observations relating to the effect the resin had on the final redox state of the glass.

  12. Ion Exchange Testing with SRF Resin FY 2012

    SciTech Connect (OSTI)

    Russell, Renee L.; Rinehart, Donald E.; Peterson, Reid A.

    2014-07-02T23:59:59.000Z

    Ion exchange using spherical resorcinol-formaldehyde (SRF) resin has been selected by the U.S. Department of Energy’s Office of River Protection (DOE-ORP) for use in the Pretreatment Facility (PTF) of the Hanford Tank Waste Treatment and Immobilization Plant (WTP) and for potential application in at-tank deployment. Numerous studies have shown SRF resin to be effective for removing 137Cs from a wide variety of actual and simulated tank waste supernatants (Adamson et al. 2006; Blanchard et al. 2008; Burgeson et al. 2004; Duignan and Nash 2009; Fiskum et al. 2006a; Fiskum et al. 2006b; Fiskum et al. 2006c; Fiskum et al. 2007; Hassan and Adu-Wusu 2003; King et al. 2004; Nash et al. 2006). Prior work at the Pacific Northwest National Laboratory (PNNL) has focused primarily on the loading behavior for 4 to 6 M Na solutions at 25 to 45°C. Recent proposed changes to the WTP ion exchange process baseline indicate that loading may include a broader range of sodium molarities (0.1 to 8 M) and higher temperatures (50°C) to alleviate post-filtration precipitation issues. This report discusses ion exchange loading kinetics testing activities performed in accordance with Test Plan TP-WTPSP-002, Rev. 3.01, which was prepared and approved in response to the Test Specification 24590-PTF-TSP-RT-09-002, Rev. 0 (Lehrman 2010) and Test Exception 24590-PTF-TEF-RT-11-00003, Rev. 0 (Meehan 2011). This testing focused on column tests evaluating the impact of elevated temperature on resin degradation over an extended period of time and batch contacts evaluating the impact on Cs loading over a broad range of sodium concentrations (0.1 to 5 M). These changes may be required to alleviate post-filtration precipitation issues and broaden the data range of SRF resin loading under the conditions expected with the new equipment and process changes.

  13. Decontamination of water using nitrate selective ion exchange resin

    DOE Patents [OSTI]

    Lockridge, J.E.; Fritz, J.S.

    1990-07-31T23:59:59.000Z

    A method for nitrate decontamination of water which involves passing the water through a bed of alkyl phosphonium anion exchange resin which has pendant alkyl groups of C[sub 3] or larger.

  14. Decontamination of water using nitrate selective ion exchange resin

    DOE Patents [OSTI]

    Lockridge, James E. (Ames, IA); Fritz, James S. (Ames, IA)

    1990-07-31T23:59:59.000Z

    A method for nitrate decontamination of water which involves passing the water through a bed of alkyl phosphonium anion exchange resin which has pendant alkyl groups of C.sub.3 or larger.

  15. Toyopearl Ion Exchange Resins. IEC is the most com-mon liquid chromatographic method used in manu-

    E-Print Network [OSTI]

    Lebendiker, Mario

    Toyopearl Ion Exchange Resins. IEC is the most com- mon liquid chromatographic method used in manu- facturing of biological therapeutics. Toyopearl IEC resins have the advantages of the HW-65 or HW-55 base exchanger -O-CH2-CH2-N+-(C2H5)3HW- 55 strong anion exchanger Structure of Toyopearl IEC resins + Size

  16. Waste minimization pretreatment via pyrolysis and oxidative pyrolysis of organic ion exchange resin

    SciTech Connect (OSTI)

    Chun, U.K.; Choi, K.; Yang, K.H.; Park, J.K.; Song, M.J. [Korea Electric Power Research Inst., Taejon (Korea, Republic of). Nuclear Power Generation Lab.] [Korea Electric Power Research Inst., Taejon (Korea, Republic of). Nuclear Power Generation Lab.

    1998-12-31T23:59:59.000Z

    Pyrolysis and/or oxidative pyrolysis of organic ion exchange resins and other combustible waste may be effective pretreatment processes before vitrification. Three different methods were examined with the TGA to pretreat the resins: pyrolysis; oxidative pyrolysis; and oxidative pyrolyses of ash remaining after the pyrolysis of resin. The latter two methods were found to provide better volume reduction than the pyrolysis-only process. Between the two types of resins, cationic and anionic, the cationic exchange resin was less volatile. Pyrolysis and oxidative pyrolysis of mixed resin (50% cation and 50% anion by wt.) showed volatilization at the temperatures where volatilization was observed for each of the separate resins. Because of certain limitations of the commercial TGA, tube furnace experiments were performed, generally, to examine the pyrolysis of larger quantities of cationic, anionic, and mixed resin, and to examine off-gas characteristics. The cationic resin-only and anionic resin-only gravimetric results showed good agreement with the smaller-scale TGA results. SEM pictures of the different variants of the resin (cationic, anionic, and mixed) show a different morphology for each. Off-gas data showed the presence of H{sub 2}S, SO{sub 2}, CO, and NO during the pyrolysis of cationic resin. CO was observed during the pyrolysis of anionic resin. The mixed resin trials showed the presence of the gases approximately at the temperatures where the gases would evolve if the results of the two different resins (cationic and anionic) were superimposed. However, the amount of hydrogen sulfide relative to the sulfur dioxide was found to increase significantly compared to the results of the cationic resin-only trials.

  17. The characteristic assessment of spent ion exchange resin from PUSPATI TRIGA REACTOR (RTP) for immobilization process

    SciTech Connect (OSTI)

    Wahida, Nurul [School of Applied Physics, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor, Malaysia and Malaysian Nuclear Agency, Bangi 43000 Kajang, Selangor (Malaysia); Yasir, Muhamad Samudi; Majid, Amran Ab; Irwan, M. N. [School of Applied Physics, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor (Malaysia); Wahab, Mohd Abd; Marzukee, Nik; Paulus, Wilfred; Phillip, Esther; Thanaletchumy [Malaysian Nuclear Agency, Bangi 43000 Kajang, Selangor (Malaysia)

    2014-09-03T23:59:59.000Z

    In this paper, spent ion exchange resin generated from PUSPATI TRIGA reactor (RTP) in Malaysian Nuclear Agency were characterized based on the water content, radionuclide content and radionuclide leachability. The result revealed that the water content in the spent resin is 48%. Gamma spectrometry analysis indicated the presence of {sup 134}Cs, {sup 137}Cs, {sup 152}Eu, {sup 54}Mn, {sup 58}Co, {sup 60}Co and {sup 65}Zn. The leachability test shows a small concentrations (<1 Bq/l) of {sup 152}Eu and {sup 134}Cs were leached out from the spent resin while {sup 60}Co activity concentrations slightly exceeded the limit generally used for industrial wastewater i.e. 1 Bq/l. Characterization of spent ion exchange resin sampled from RTP show that this characterization is important as a basis to immobilize this radioactive waste using geopolymer technology.

  18. THERMAL MODELING OF ION EXCHANGE COLUMNS WITH SPHERICAL RF RESIN

    SciTech Connect (OSTI)

    Lee, S.; King, W.

    2009-12-30T23:59:59.000Z

    Models have been developed to simulate the thermal performance of RF columns fully loaded with radioactive cesium. Temperature distributions and maximum temperatures across the column were calculated during Small Column Ion Exchange (SCIX) process upset conditions with a focus on implementation at Hanford. A two-dimensional computational modeling approach was taken to include conservative, bounding estimates for key parameters such that the results will provide the maximum centerline temperatures achievable under the design configurations using a feed composition known to promote high cesium loading on RF. The current full-scale design for the SCIX system includes a central cooling tube, and one objective of these calculations was to examine its elimination to simplify the design. Results confirmed that a column design without a central cooling tube is feasible for RF, allowing for the possibility of significant design simplifications if it can be assumed that the columns are always filled with liquid. With active cooling through the four outer tubes, the maximum column diameter expected to maintain the temperature below the assumed media and safety limits is 26 inches, which is comparable to the current design diameter. Additional analysis was conducted to predict the maximum column temperatures for the previously unevaluated accident scenario involving inadvertent drainage of liquid from a cesium-saturated column, with retention of the ion exchange media and cesium in the column. As expected, much higher maximum temperatures are observed in this case due to the poor heat transfer properties of air versus liquid. For this hypothetical accident scenario involving inadvertent and complete drainage of liquid from a cesium-saturated column, the modeling results indicate that the maximum temperature within a 28 inch diameter RF column with external cooling is expected to exceed 250 C within 2 days, while the maximum temperature of a 12 inch column is maintained below 100 C. In addition, the calculation results demonstrate that the cooling tube system external to an air-filled column is not highly effective at reducing the maximum temperature, but the baseline design using a central cooling tube inside the column provides sufficient cooling to maintain the maximum temperature near the assumed safety limit.

  19. Using Process Knowledge to Manage Disposal Classification of Ion-Exchange Resin - 13566

    SciTech Connect (OSTI)

    Bohnsack, Jonathan N.; James, David W. [DW James Consulting, LLC 855 Village Center Drive No. 330 North Oaks, MN 55127 (United States)] [DW James Consulting, LLC 855 Village Center Drive No. 330 North Oaks, MN 55127 (United States)

    2013-07-01T23:59:59.000Z

    It has been previously shown by EPRI [1] that Class B and C resins represent a small portion by volume of the overall generation of radioactively contaminated resins. In fact, if all of the resins were taken together the overall classification would meet Class A disposal requirements. Lowering the classification of the ion exchange resins as they are presented for disposal provides a path for minimizing the amount of waste stored. Currently there are commercial options for blending wastes from various generators for Class A disposal in development. The NRC may have by this time introduced changes and clarifications to the Branch Technical Position (BTP) on Concentration Averaging and Encapsulation [2] that may ultimately add more flexibility to what can be done at the plant level. The BTP has always maintained that mixtures of resins that are combined for ALARA purposes or operational efficiency can be classified on the basis of the mixture. This is a point often misinterpreted and misapplied. This paper will address options that can be exercised by the generator that can limit B and C waste generation by more rigorous tracking of generation and taking advantage of the normal mix of wastes. This can be achieved through the monitoring of reactor coolant chemistry data and coupled with our knowledge of radionuclide production mechanisms. This knowledge can be used to determine the overall accumulation of activity in ion-exchange resins and provides a 'real-time' waste classification determination of the resin and thereby provide a mechanism to reduce the production of waste that exceeds class A limits. It should be noted that this alternative approach, although rarely used in a nuclear power plant setting, is acknowledged in the original BTP on classification [3] as a viable option for determining radionuclide inventories for classification of waste. Also included is a discussion of an examination performed at the Byron plant to estimate radionuclide content in the final waste stream from upstream sampling of reactor coolant and fuel pool water. (authors)

  20. REAL WASTE TESTING OF SPHERICAL RESORCINOL-FORMALDEHYDE ION EXCHANGE RESIN

    SciTech Connect (OSTI)

    Nash, C.; Duignan, M.

    2009-10-30T23:59:59.000Z

    This report presents data on batch contact and column testing tasks for spherical resorcinol-formaldehyde (sRF) resin. The testing used a non-radioactive simulant of SRS Tank 2F dissolved salt, as well as an actual radioactive waste sample of similar composition, which are both notably high in sodium (6 M). The resin was Microbeads batch 5E-370/641 which had been made on the hundred gallon scale. Equilibrium batch contact work focused on cesium at a temperature of 25 C due to the lack of such data to better benchmark existing isotherm models. Two campaigns were performed with small-scale ion exchange columns, first with Tank 2F simulant, then with actual dissolved salt in the Shielded Cells. An extrapolation of the batch contact results with radioactive waste over-predicted the cesium loaded onto the IX sRF resin bed by approximately 11%. This difference is not unexpected considering uncertainties from measurement and extrapolation and because the ion exchange that occurs when waste flows through a resin bed probably cannot reach the same level of equilibrium as when waste and resin are joined in a long term batch contact. Resin was also characterized to better understand basic chemistry issues such as holdup of trace transition metals present in the waste feed streams. The column tests involved using two beds of sRF resin in series, with the first bed referred to as the Lead column and the second bed as the Lag column. The test matrix included two complete IX cycles for both the simulant and actual waste phases. A cycle involves cesium adsorption, until the resin in the Lead column reaches saturation, and then regenerating the sRF resin, which includes eluting the cesium. Both the simulated and the actual wastes were treated with two cycles of operation, and the resin beds that were used in the Lead and Lag columns of simulant test phase were regenerated and reused in the actual waste test phase. This task is the first to demonstrate the treatment of SRS waste with sRF resin and the tests clearly demonstrated cesium decontamination for actual waste. The results of the column tests were similar for both the simulated and the actual waste and demonstrated Cs removal with sRF from both wastes. For a flowrate of 1.4 bed volumes (BV)/hour at 25 C those results with sRF resin were: (1) Simulant and actual waste results are equivalent; (2) Cs breakthrough began between 200 and 250 BV; (3) Cs breakthrough reached 100% at around 400 BV; (4) Cs breakthrough curve from 5% to 100% is approximately linear; (5) Cs elution with 0.5 M HNO3 starts at 2 BV and ends at 6BV; (6) Most, if not all, of Cs adsorbed during treatment is released during elution; (7) At 100% breakthrough of Cs the resin bed adsorbs approximately 85% of full capacity before detection in the effluent; the remaining 15% is adsorbed at saturation; (8) Approximately 90% of resin bed changes (color and volume) are complete by 6 BV; and (9) During elution the resin shrinks to about 80% of its fully working (sodium form) BV.

  1. DEVELOPMENT OF WET-OXIDATION TREATMENT SYSTEM FOR FILTER BACKWASH SLUDGE AND ION EXCHANGE RESINS

    SciTech Connect (OSTI)

    Miyamoto, T.; Motoyama, M.; Shibuya, M.; Wada, H.; Yamazaki, K.

    2003-02-27T23:59:59.000Z

    Decomposition of organic compounds contained in filter backwash sludge and spent ion exchange resins is considered effective in reducing the waste volume. A system using the wet-oxidation process has been studied for the treatment of the sludge and resins stored at Tsuruga Power Station Unit 1, 357MWe BWR, owned by The Japan Atomic Power Company. Compared with various processes for treating sludge and resin, the wet-oxidation system is rather simple and the process conditions are mild. Waste samples collected from storage tanks were processed by wet-oxidation and appropriate decomposition of the organic compounds was verified. After the decomposition the residue can be solidified with cement or bitumen for final disposal. When compared with direct solidification without decomposition, the number of waste packages can be reduced by a factor of a few dozens for the sludge and three for the resin. Additional measures for conditioning secondary waste products have also been studied, and their applicability to the Tsuruga Power Station was verified. Some of the conditions studied were specific to the Tsuruga Power Station, but it is expected that the system will provide an effective solution for sludge and resin treatment at other NPPs.

  2. Heterogeneous models of tubular reactors packed with ion-exchange resins: Simulation of the MTBE synthesis

    SciTech Connect (OSTI)

    Quinta Ferreira, R.M.; Almeida-Costa, C.A. [Univ. of Coimbra (Portugal). Dept. of Chemical Engineering; Rodrigues, A.E. [Univ. of Porto (Portugal). Dept. of Chemical Engineering

    1996-11-01T23:59:59.000Z

    The study of behavior of fixed-bed reactors using ion-exchange resins as catalysts was carried out by making use of a complete bidimensional heterogeneous model for the reactor, which included the resistances inside the ion-exchange resin particles, considered with a macroreticular structure. The active sites were located inside the gel phase of the resin, represented by microspheres, and on the macropores walls. The overall efficiency of such heterogeneous catalyst particles was defined by the macroeffectiveness and microeffectiveness factors accounting for the process behavior on the macropores and inside the microspheres. The synthesis of methyl tert-butyl ether, MTBE, a liquid-phase reversible exothermic reaction between methanol and isobutene, was considered as a reference case. This system was studied in the temperature range of 313--338 K, and the effect of the thermodynamic equilibrium conditions was examined. The results predicted by the complete heterogeneous model were compared with those obtained with the simple pseudohomogeneous model, which revealed higher hot spots. Moreover, a comparison between bidimensional and unidimensional models was also performed. The orthogonal collocation method was used for the discretization of the differential equations inside the catalyst particles, which were reduced from three (corresponding to the three mass balances for the three compounds, isobutene, methanol, and MTBE) to only one differential equation, by using the concept of the generalized variable.

  3. Vitrification of ion-exchange (IEX) resins: Advantages and technical challenges

    SciTech Connect (OSTI)

    Jantzen, C.M.; Peeler, D.K.; Cicero, C.A.

    1995-12-31T23:59:59.000Z

    Technologies are being developed by the US Department of Energy`s (DOE) Savannah River Site (SRS) in conjunction with the Electric Power Research Institute (EPRI) and the commercial sector to convert low-level radioactive ion exchange (IEX) resin wastes from the nuclear utilities to solid stabilized waste forms for permanent disposal. One of the alternative waste stabilization technologies is vitrification of the resin into glass. Wastes can be vitrified at elevated temperatures by thermal treatment. One alternative thermal treatment is conventional Joule heated melting. Vitrification of wastes into glass is an attractive option because it atomistically bonds both hazardous and radioactive species in the glass structure, and volume reduces the wastes by 70-80%. The large volume reductions allow for large associated savings in disposal and/or long term storage costs.

  4. Synthesis and Characterization of Templated Ion Exchange Resins for the Selective Complexation of Actinide Ions

    SciTech Connect (OSTI)

    Murray, George M.; Uy, O. Manual murragm1@aplcomm.jhuapl.edu; uyom1@aplmsg.jhuapl.edu

    2001-03-01T23:59:59.000Z

    The purpose of this research is to develop a polymeric extractant for the selective complexation of uranyl ions (and subsequently other actinyl and actinide ions) from aqueous solutions (lakes, streams, waste tanks and even body fluids). Chemical insights into what makes a good complexation site will be used to synthesize reagents tailor-made for the complexation of uranyl and other actinide ions. These insights, derived from studies of molecular recognition include ion coordination number and geometry, ionic size and ionic shape, as well as ion to ligand thermodynamic affinity. Selectivity for a specific actinide ion will be obtained by providing the polymers with cavities lined with complexing ligands so arranged as to match the charge, coordination number, coordination geometry, and size of the actinide metal ion. These cavity-containing polymers will be produced by using a specific ion (or surrogate) as a template around which monomeric complexing ligands will be polymerized. The complexing ligands will be ones containing functional groups known to form stable complexes with a specific ion and less stable complexes with other cations. Prior investigator's approaches for making templated resins for metal ions have had marginal success. We have extended and amended these methodologies in our work with Pb(II) and uranyl ion, by changing the order of the steps, by the inclusion of sonication, by using higher complex loading, and the selection of functional groups with better complexation constants. This has resulted in significant improvements to selectivity. The unusual shape of the uranyl ion suggests that this approach will result in even greater selectivities than already observed for Pb(II). Preliminary data obtained for uranyl templated polymers shows unprecedented selectivity and has resulted in the first ion selective electrode for uranyl ion.

  5. Investigation of the ion exchange equilibrium between NA+, Ca++, Mg++, and a sulfonated polystyrene resin at various concentrations

    E-Print Network [OSTI]

    McIlhenny, William Franklin

    1958-01-01T23:59:59.000Z

    Cl and saturated Na01 with a sulfonated polystyrene cation exchanger. Anderson and Peebles report the Ca ? Na equilibrium with a l ++ + sulfonated polystyrene resin to 0. 62 N. 24 Juda, Kasper and Potter reported on the 1on exchange softening of seawater... average K calculated, at least seven values were averaged. 21 DISCUSSION OF RESULTS The measured equ1valent fractions of Mg , Ca , and Na ++ ++ ions in solution, and the calculated equivalent fractions on the resin are given in Table II. From...

  6. Method for digesting spent ion exchange resins and recovering actinides therefrom using microwave radiation

    DOE Patents [OSTI]

    Maxwell, III, Sherrod L. (Aiken, SC); Nichols, Sheldon T. (Augusta, GA)

    1999-01-01T23:59:59.000Z

    The present invention relates to methods for digesting diphosphonic acid substituted cation exchange resins that have become loaded with actinides, rare earth metals, or heavy metals, in a way that allows for downstream chromatographic analysis of the adsorbed species without damage to or inadequate elution from the downstream chromatographic resins. The methods of the present invention involve contacting the loaded diphosphonic acid resin with concentrated oxidizing acid in a closed vessel, and irradiating this mixture with microwave radiation. This efficiently increases the temperature of the mixture to a level suitable for digestion of the resin without the use of dehydrating acids that can damage downstream analytical resins. In order to ensure more complete digestion, the irradiated mixture can be mixed with hydrogen peroxide or other oxidant, and reirradiated with microwave radiation.

  7. Radioactive Spent Ion-Exchange Resins Conditioning by the Hot Supercompaction Process at Tihange NPP - Early Experience - 12200

    SciTech Connect (OSTI)

    Braet, Johan; Charpentier, David; Centner, Baudouin; Vanderperre, Serge [Nuclear Department, Tractebel Engineering (GDF-SUEZ), Avenue Ariane 7, B-1200 Brussels (Belgium)

    2012-07-01T23:59:59.000Z

    Spent ion-exchange resins are considered to be problematic waste that, in many cases, requires special approaches and precautions during their conditioning to meet the acceptance criteria for disposal. In Belgium, for economical reasons, the Volume Reduction Factor is a key criterion. After Tractebel Engineering performed a technical and economical comparison of the industrially available systems, Tihange NPP decided to install a spent ion-exchange resins hot supercompaction unit with Tractebel Engineering in the role of architect-engineer. The treatment and conditioning unit processes the spent ion-exchange resins through the following steps: dewatering of the resins, drying the resins under deep vacuum, discharging the dried resins into compactable drums, super-compacting the drums to generate pellets, grouting the pellets into standard 400 litres waste drums (overpacks) licensed for final disposal in the near-surface repository in Belgium. Several developments were required to adapt the reference process and equipment to PWR spent ion-exchange bead resins and Belgian radioactive waste acceptance criteria. In order to avoid cracks on the compacted drum, and external surface contamination from resin leaks, some improvements were achieved to minimize spring-back as well as the risk of cracking the drum wall. Placing the compactable drum inside a second, slightly larger drum, guarantees clean and reproducible pellets. Currently the commissioning phase is on-going. Numerous process validation tests have been completed. An acceptance file was transmitted to the Belgian Waste Management Authority recently. This will be followed by demonstration tests necessary to obtain their final acceptance of the installation. More than 3 800 drums of mixed powdered and bead resins have been processed by the reference Hot Compaction process, achieving a Volume Reduction Factor (VRF) of 2.5. The equipment has been proven to be a reliable technology with low operation and maintenance costs. Tractebel Engineering has managed the construction of a new application of this process in Belgium at Tihange NPP. Several developments were required to adapt the reference process and equipment to PWR spent ion-exchange bead resins and Belgian radioactive waste acceptance criteria. The chosen method of conditioning (draining, drying and compaction of the spent resins followed by grouting of the pellets in a 400 litres drum) immobilizes the spent resins under the form of a solid, compact, stable, and non dispersible block free of interstitial water. The various series of inactive tests which were conducted at Tihange NPP, helped among others to determine the best design of the compactable drum and lid and to set the value of critical parameters such as vapour temperature at the end of drying, speed, force and duration of compaction. In an environment of very limited space for interim storage and in the absence of an operational final repository site, or in the case of high final disposal costs, the process exhibits the following key advantages: - Achieving a Volume Reduction Factor (VRF) close to 1 (overpack included) for the interim storage instead of increased volumes observed with other currently available processes; - Achieving a water free end product; - Creating a flexible waste product for interim storage (pellet), which can be retrieved and routed into alternative types of package later, if not initially grouted; - Using well proven standard technologies like drying and compaction; - Flexible use of the system components for the supercompaction of other operational solid waste streams when not conducting resins conditioning campaigns. (authors)

  8. Preliminary flowsheet: Ion exchange for separation of cesium from Hanford tank waste using resorcinol-formaldehyde resin

    SciTech Connect (OSTI)

    Penwell, D.L.

    1994-12-28T23:59:59.000Z

    This preliminary flowsheet document describes an ion exchange process which uses resorcinol-formaldehyde (R-F) resin to remove cesium from Hanford tank waste. The flowsheet describes one possible equipment configuration, and contains mass balances based on that configuration with feeds of Neutralized Current Acid Waste, and Double Shell Slurry Feed. The flowsheet also discusses process alternatives, unresolved issues, and development needs associated with the ion exchange process. It is expected that this flowsheet will evolve as open issues are resolved and progress is made on development needs. This is part of the Tank Waste Remediation Program at Hanford. 26 refs, 6 figs, 25 tabs.

  9. Efficiencies and Optimization of Weak Base Anion Ion-Exchange Resin for Groundwater Hexavalent Chromium Removal at Hanford

    SciTech Connect (OSTI)

    Nesham, Dean O. [CH2M HILL Plateau Remediation Company, Richland, WA (United States); Ivarson, Kristine A. [CH2M HILL Plateau Remediation Company, Richland, WA (United States); Hanson, James P. [CH2M HILL Plateau Remediation Company, Richland, WA (United States); Miller, Charles W. [CH2M HILL Plateau Remediation Company, Richland, WA (United States); Meyers, P. [USDOE, Richland Operations Office, WA (United States); Jaschke, Naomi M. [USDOE, Richland Operations Office, WA (United States)

    2014-02-03T23:59:59.000Z

    The U.S. Department of Energy’s (DOE’s) contractor, CH2M HILL Plateau Remediation Company, has successfully converted a series of groundwater treatment facilities to use a new treatment resin that is delivering more than $3 million in annual cost savings and efficiency in treating groundwater contamination at the DOE Hanford Site in southeastern Washington State. During the production era, the nuclear reactors at the Hanford Site required a continuous supply of high-quality cooling water during operations. Cooling water consumption ranged from about 151,417 to 378,541 L/min (40,000 to 100,000 gal/min) per reactor, depending on specific operating conditions. Water from the Columbia River was filtered and treated chemically prior to use as cooling water, including the addition of sodium dichromate as a corrosion inhibitor. Hexavalent chromium was the primary component of the sodium dichromate and was introduced into the groundwater at the Hanford Site as a result of planned and unplanned discharges from the reactors starting in 1944. Groundwater contamination by hexavalent chromium and other contaminants related to nuclear reactor operations resulted in the need for groundwater remedial actions within the Hanford Site reactor areas. Beginning in 1995, groundwater treatment methods were evaluated, leading to the use of pump-and-treat facilities with ion exchange using Dowex™ 21K, a regenerable, strong-base anion exchange resin. This required regeneration of the resin, which was performed offsite. In 2008, DOE recognized that regulatory agreements would require significant expansion for the groundwater chromium treatment capacity. As a result, CH2M HILL performed testing at the Hanford Site in 2009 and 2010 to demonstrate resin performance in the specific groundwater chemistry at different waste sites. The testing demonstrated that a weak-base anion, single-use resin, specifically ResinTech SIR-700 ®, was effective at removing chromium, had a significantly higher capacity, could be disposed of efficiently onsite, and would eliminate the complexities and programmatic risks from sampling, packaging, transportation, and return of resin for regeneration.

  10. Porous solid ion exchange wafer for immobilizing biomolecules

    DOE Patents [OSTI]

    Arora, Michelle B. (Woodridge, IL); Hestekin, Jamie A. (Morton Grove, IL); Lin, YuPo J. (Naperville, IL); St. Martin, Edward J. (Libertyville, IL); Snyder, Seth W. (Lincolnwood, IL)

    2007-12-11T23:59:59.000Z

    A porous solid ion exchange wafer having a combination of a biomolecule capture-resin and an ion-exchange resin forming a charged capture resin within said wafer. Also disclosed is a porous solid ion exchange wafer having a combination of a biomolecule capture-resin and an ion-exchange resin forming a charged capture resin within said wafer containing a biomolecule with a tag. A separate bioreactor is also disclosed incorporating the wafer described above.

  11. Summary of pilot-scale activities with resorcinol ion exchange resin

    SciTech Connect (OSTI)

    Cicero, C.A. [Westinghouse Savannah River Company, AIKEN, SC (United States); Bickford, D.F.; Sargent, T.N.; Andrews, M.K.; Bibler, J.P.; Bibler, N.E.; Jantzen, C.M.

    1995-10-02T23:59:59.000Z

    The Mixed Waste Focus Area (MWFA) of the Department of Energy (DOE) is currently investigating vitrification technology for treatment of low level mixed wastes (LLMW). They have chartered the Savannah River Technology Center (SRTC) to study vitrification of the wastes through an Office of Technology Development (OTD) Technical Task Plan (TTP). SRTC`s efforts have included crucible-scale studies and pilot scale testing on simulated LLMW sludges, resins, soils, and other solid wastes. Results from the crucible-scale studies have been used as the basis for the pilot-scale demonstrations. As part of the fiscal year (FY) 1995 activities, SRTC performed crucible-scale studies with organic resins. This waste stream was selected because of the large number of DOE sites, as well as commercial industries, that use resins for treatment of liquid wastes. Pilot-scale studies were to be completed in FY 1995, but could not be due to a reduction in funding. Instead, a compilation of pilot-scale tests with organic resins performed under the guidance of SRTC was provided in this report. The studies which will be discussed used a resorcinol- formaldehyde resin loaded with non-radioactive cesium, which was fed with simulated wastewater treatment sludge feed. The first study was performed at the SRTC in the mini-melter, 1/100th scale of the Defense Waste Processing Facility (DWPF) melter, and also involved limited crucible-scale studies to determine the resin loading obtainable. The other study was performed at the DOE/Industrial Center for Vitrification Research (Center) and involved both crucible and pilot-scale testing in the Stir-Melter stirred-melter. Both studies were successful in vitrifying the resin in simulated radioactive sludge and glass additive feeds.

  12. Technical note Use of mixed ion exchange resin and the denitrifier method to determine isotopic

    E-Print Network [OSTI]

    Templer, Pamela

    as water passes over them (e.g., Van Dam et al.,1991; Fenn et al., 2002; Simkin et al., 2004.g., Simkin et al., 2004) and therefore resin collectors can remain in the field for a longer period of time

  13. Ion exchange as a tertiary treatment

    E-Print Network [OSTI]

    Westervelt, Ronald David

    1968-01-01T23:59:59.000Z

    , produced the first synthetic ion exchange resins by reacting phenol with formaldehyde (2). These resins were insoluble and infusible. They found that the cation exchange properties could be greatly in- creased by substituting phenolsulfonic acid... by hydrogen ions. They could also b&. operated on the sodium cycle to exchange sodium iona for cations in solution. Adams and Holmes also produced the first anion exchange resins by reacting amines such as m-phenylene- diamine with formaldehyde...

  14. Preliminary flowsheet: Ion exchange process for the separation of cesium from Hanford tank waste using Duolite{trademark} CS-100 resin

    SciTech Connect (OSTI)

    Eager, K.M.; Penwell, D.L.; Knutson, B.J.

    1994-12-01T23:59:59.000Z

    This preliminary flowsheet document describes an ion exchange process which uses Duolite{trademark} CS-100 resin to remove cesium from Hanford Tank waste. The flowsheet describes one possible equipment configuration, and contains mass balances based on that configuration with feeds of Neutralized Current Acid Waste, and Double Shell Slurry Feed. Process alternatives, unresolved issues, and development needs are discussed which relate to the process.

  15. Iodine Adsorption on Ion-Exchange Resins and Activated Carbons– Batch Testing

    SciTech Connect (OSTI)

    Parker, Kent E.; Golovich, Elizabeth C.; Wellman, Dawn M.

    2014-09-30T23:59:59.000Z

    Iodine sorption onto seven resins and six carbon materials was evaluated using water from well 299-W19-36 on the Hanford Site. These materials were tested using a range of solution-to-solid ratios. The test results are as follows: • The efficacy of the resin and granular activated carbon materials was less than predicted based on manufacturers’ performance data. It is hypothesized that this is due to the differences in speciation previously determined for Hanford groundwater. • The sorption of iodine is affected by the iodine species in the source water. Iodine loading on resins using source water ranged from 1.47 to 1.70 µg/g with the corresponding Kd values from 189.9 to 227.0 mL/g. The sorption values when the iodine is converted to iodide ranged from 2.75 to 5.90 µg/g with the corresponding Kd values from 536.3 to 2979.6 mL/g. It is recommended that methods to convert iodine to iodide be investigated in fiscal year (FY) 2015. • The chemicals used to convert iodine to iodate adversely affected the sorption of iodine onto the carbon materials. Using as-received source water, loading and Kd values ranged from 1.47 to 1.70 µg/g and 189.8 to 226.3 mL/g respectively. After treatment, loading and Kd values could not be calculated because there was little change between the initial and final iodine concentration. It is recommended the cause of the decrease in iodine sorption be investigated in FY15. • In direct support of CH2M HILL Plateau Remediation Company, Pacific Northwest National Laboratory has evaluated samples from within the 200W pump and treat bioreactors. As part of this analysis, pictures taken within the bioreactor reveal a precipitate that, based on physical properties and known aqueous chemistry, is hypothesized to be iron pyrite or chalcopyrite, which could affect iodine adsorption. It is recommended these materials be tested at different solution-to-solid ratios in FY15 to determine their effect on iodine sorption.

  16. Method of uranium reclamation from aqueous systems by reactive ion exchange. [US DOE patent application; anion exchange resin of copolymerized divinyl-benzene and styrene having quarternary ammonium groups and bicarbonate ligands

    DOE Patents [OSTI]

    Maya, L.

    1981-11-05T23:59:59.000Z

    A reactive ion exchange method for separation and recovery of values of uranium, neptunium, plutonium, or americium from substantially neutral aqueous systems of said metals comprises contacting said system with an effective amount of a basic anion exchange resin of copolymerized divinyl-benzene and styrene having quarternary ammonium groups and bicarbonate ligands to achieve nearly 100% sorption of said actinyl ion onto said resin and an aqueous system practically free of said actinyl ions. The method is operational over an extensive range of concentrations from about 10/sup -6/ M to 1.0 M actinyl ion and a pH range of about 4 to 7. The method has particulr application to treatment of waste streams from Purex-type nuclear fuel reprocessing facilities and hydrometallurgical processes involving U, Np, P, or Am.

  17. Anion-exchange resin-based desulfurization process. Final report

    SciTech Connect (OSTI)

    Sheth, A C; Dharmapurikar, R; Strevel, S D

    1994-01-01T23:59:59.000Z

    The following investigations were performed: (1) batch mode screening of eleven(11) commercially available resins and selection of three candidate resins for further evaluation in a fixed-bed setup. (2) Process variables study using three candidate resins in the fixed-bed setup and selection of the ``best`` resin for process economics development. (3) Exhaustion efficiency and solution concentration were found to be inversely related necessitating a trade-off between the resin cost versus the cost of evaporation/concentration of ensuing effluents. (4) Higher concentration of the HCO{sub 3}{sup {minus}} form of active sites over less active CO{sub 3}{sup 2{minus}} form of sites in the resin was believed to be the main reason for the observed increase in the equilibrium capacity of the resin at an elevated static CO{sub 2}-pressure. This Increase in capacity was found to level off around 80--120 psig range. The increase in CO{sub 2}-pressure, however, did not appear to affect the overall ion-exchange kinetics. (5) In the fixed-bed mode, the solution concentration was found to affect the equilibrium capacity of candidate resins. Their relationship was well satisfied by the Langmuir type non-linear equilibrium isotherm. Alternatively, the effect of solution concentration on overall ion-exchange kinetics varied from resin to resin. (6) Product inhibition effect on the resin was observed as an initial increase followed by a significant decrease in the resin`s equilibrium capacity for SO{sub 4}{sup 2{minus}} as the HCO{sub 3}{sup {minus}}/SO{sub 4}{sup 2{minus}} molar ratio in the solution was increased from 0 to 1.0. This ratio, however, did not affect the overall ion-exchange kinetics.

  18. Ion Exchange Studies for Removal of Sulfate from Hanford Tank Waste Envelope C (241-AN-107) Using SuperLig 655 Resin

    SciTech Connect (OSTI)

    DE Kurath; JR Bontha; DL Blanchard; SK Fiskum; BM Rapko

    2000-08-23T23:59:59.000Z

    BNFL Inc. is evaluating various pretreatment technologies to mitigate the impacts of sulfate on the LAW vitrification system. One pretreatment technology for separating sulfate from LAW solutions involves the use of SuperLig{reg_sign} 655 (SL-655), a proprietary ion exchange material developed and supplied by IBC Advanced Technologies, Inc., American Fork, UT. This report describes testing of SL-655 with diluted ([Na] {approximately} 5 M) waste from Hanford Tank 241-AN-107 at Battelle, Pacific Northwest Division. Batch contact studies were conducted from 4 to 96 hours to determine the sulfate distribution coefficient and reaction kinetics. A small-scale ion exchange column test was conducted to evaluate sulfate removal, loading, breakthrough, and elution from the SL-655. In all of these tests, an archived 241-AN-107 tank waste sample (pretreated to remove Cs, Sr, and transuranics elements) was used. The experimental details and results are described in this report. Under the test conditions, SL-655 was found to have no significant ion exchange affinity for sulfate in this matrix. The batch contact study resulted in no measurable difference in the aqueous sulfate concentration following resin contact (K{sub d} {approximately} 0). The column test also demonstrated SL-655 had no practical affinity for sulfate in the tested matrix. Within experimental error, the sulfate concentration in the column effluent was equal to the concentration in the feed after passing 3 bed volumes of sample through the columns. Furthermore, some, if not all, of the decreased sulfate concentration in these first three column volumes of effluent can be ascribed to mixing and dilution of the 241-AN-107 feed with the interstitial liquid present in the column at the start of the loading cycle. Finally, ICP-AES measurements on the eluate solutions showed the presence of barium as soon as contact with the feed solution is completed. Barium is a metal not detected in the feed solution. Should the loss of barium be correlated with the resin's ability to selectively complex sulfate, then maintaining even the current limited resin characteristics for sulfate complexation over multiple cycles becomes questionable.

  19. Thermal Analysis of LANL Ion Exchange Column

    SciTech Connect (OSTI)

    Laurinat, J.E.

    1999-06-16T23:59:59.000Z

    This document reports results from an ion exchange column heat transfer analysis requested by Los Alamos National Laboratory (LANL). The object of the analysis is to demonstrate that the decay heat from the Pu-238 will not cause resin bed temperatures to increase to a level where the resin significantly degrades.

  20. K Basin Sludge Conditioning Process Testing Project Results from Test 4, ''Acid Digestion of Mixed-Bed Ion Exchange Resin''

    SciTech Connect (OSTI)

    Pool, K.H.; Delegard, C.H.; Schmidt, A.J.; Thornton, B.M.; Silvers, K.L.

    1999-04-02T23:59:59.000Z

    Approximately 73 m{sup 3} of heterogeneous solid material, ''sludge,'' (upper bound estimate, Packer 1997) have accumulated at the bottom of the K Basins in the 100 K Area of the Hanford Site. This sludge is a mixture of spent fuel element corrosion products, ion exchange materials (organic and inorganic), graphite-based gasket materials, iron and aluminum metal corrosion products, sand, and debris (Makenas et al. 1996, 1997). In addition, small amounts of polychlorinated biphenyls (PCBs) have been found. Ultimately, it is planned to transfer the K Basins sludge to the Hanford double shell tanks (DSTs). The Hanford Spent Nuclear Fuel (HSNF) project has conducted a number of evaluations to examine technology and processing alternatives to pretreat K Basin sludge to meet storage and disposal requirements. From these evaluations, chemical pretreatment has been selected to address criticality issues, reactivity, and the destruction or removal of PCBs before the K Basin sludge can be transferred to the DSTs. Chemical pretreatment, referred to as the K Basin sludge conditioning process, includes nitric acid dissolution of the sludge (with removal of acid insoluble solids), neutrons absorber addition, neutralization, and reprecipitation. Laboratory testing is being conducted by the Pacific Northwest National Laboratory (PNNL) to provide data necessary to develop the sludge conditioning process.

  1. TECHNICAL COMPARISON OF CANDIDATE ION EXCHANGE MEDIA FOR SMALL COLUMN ION EXCHANGE (SCIX) APPLICATIONS IN SUPPORT OF SUPPLEMENTAL LAW PRETREATMENT

    SciTech Connect (OSTI)

    RAMSEY AA; THORSON MR

    2010-12-28T23:59:59.000Z

    At-tank supplemental pretreatment including both filtration and small column ion exchange is currently under evaluation to facilitate salt waste retrieval and processing in the Hanford tank farms. Spherical resorcinol formaldehyde (sRF) resin is the baseline ion exchange resin for use in the Waste Treatment and Immobilization Plant (WTP). This document provides background and technical rationale to assist in determining whether spherical resorcinol formaldehyde (sRF) is also the appropriate ion exchange resin for supplemental LAW pretreatment processes and compares sRF with crystalline silicotitanate (CST) as potential supplemental pretreatment ion exchange media.

  2. ESTIMATION OF RADIOLYTIC GAS GENERATION RATE FOR CYLINDRICAL RADIOACTIVE WASTE PACKAGES - APPLICATION TO SPENT ION EXCHANGE RESIN CONTAINERS

    SciTech Connect (OSTI)

    Husain, A.; Lewis, Brent J.

    2003-02-27T23:59:59.000Z

    Radioactive waste packages containing water and/or organic substances have the potential to radiolytically generate hydrogen and other combustible gases. Typically, the radiolytic gas generation rate is estimated from the energy deposition rate and the radiolytic gas yield. Estimation of the energy deposition rate must take into account the contributions from all radionuclides. While the contributions from non-gamma emitting radionuclides are relatively easy to estimate, an average geometry factor must be computed to determine the contribution from gamma emitters. Hitherto, no satisfactory method existed for estimating the geometry factors for a cylindrical package. In the present study, a formulation was developed taking into account the effect of photon buildup. A prototype code, called PC-CAGE, was developed to numerically solve the integrals involved. Based on the selected dimensions for a cylinder, the specified waste material, the photon energy of interest and a value for either the absorption or attenuation coefficient, the code outputs values for point and average geometry factors. These can then be used to estimate the internal dose rate to the material in the cylinder and hence to calculate the radiolytic gas generation rate. Besides the ability to estimate the rates of radiolytic gas generation, PC-CAGE can also estimate the dose received by the container material. This is based on values for the point geometry factors at the surface of the cylinder. PC-CAGE was used to calculate geometry factors for a number of cylindrical geometries. Estimates for the absorbed dose rate in container material were also obtained. The results for Ontario Power Generation's 3 m3 resin containers indicate that about 80% of the source gamma energy is deposited internally. In general, the fraction of gamma energy deposited internally depends on the dimensions of the cylinder, the material within it and the photon energy; the fraction deposited increases with increasing dimensions of the cylinder and decreases with increasing photon energy.

  3. Liquid membrane coated ion-exchange column solids

    DOE Patents [OSTI]

    Barkey, Dale P. (Berkeley, CA)

    1989-01-01T23:59:59.000Z

    This invention relates to a method for improving the performance of liquid embrane separations by coating a liquid membrane onto solid ion-exchange resin beads in a fixed bed. Ion-exchange beads fabricated from an ion-exchange resin are swelled with water and are coated with a liquid membrane material that forms a film over the beads. The beads constitute a fixed bed ion-exchange column. Fluid being treated that contains the desired ion to be trapped by the ion-exchange particle is passed through the column. A carrier molecule, contained in the liquid membrane ion-exchange material, is selected for the desired ion in the fluid. The carrier molecule forms a complex with the desired ion, transporting it through the membrane and thus separating it from the other ions. The solution is fed continuously until breakthrough occurs at which time the ion is recovered, and the bed is regenerated.

  4. Liquid membrane coated ion-exchange column solids

    DOE Patents [OSTI]

    Barkey, Dale P. (Berkeley, CA)

    1988-01-01T23:59:59.000Z

    This invention relates to a method for improving the performance of liquid membrane separations by coating a liquid membrane onto solid ion-exchange resin beads in a fixed bed. Ion-exchange beads fabricated from an ion-exchange resin are swelled with water and are coated with a liquid membrane material that forms a film over the beads. The beads constitute a fixed bed ion-exchange column. Fluid being treated that contains the desired ion to be trapped by the ion-exchange particle is passed through the column. A carrier molecule, contained in the liquid membrane ion-exchange material, is selective for the desired ion in the fluid. The carrier molecule forms a complex with the desired ion, transporting it through the membrane and thus separating it from the other ions. The solution is fed continuously until breakthrough occurs at which time the ion is recovered, and the bed is regenerated.

  5. Ion exchange phenomena

    SciTech Connect (OSTI)

    Bourg, I.C.; Sposito, G.

    2011-05-01T23:59:59.000Z

    Ion exchange phenomena involve the population of readily exchangeable ions, the subset of adsorbed solutes that balance the intrinsic surface charge and can be readily replaced by major background electrolyte ions (Sposito, 2008). These phenomena have occupied a central place in soil chemistry research since Way (1850) first showed that potassium uptake by soils resulted in the release of an equal quantity of moles of charge of calcium and magnesium. Ion exchange phenomena are now routinely modeled in studies of soil formation (White et al., 2005), soil reclamation (Kopittke et al., 2006), soil fertilitization (Agbenin and Yakubu, 2006), colloidal dispersion/flocculation (Charlet and Tournassat, 2005), the mechanics of argillaceous media (Gajo and Loret, 2007), aquitard pore water chemistry (Tournassat et al., 2008), and groundwater (Timms and Hendry, 2007; McNab et al., 2009) and contaminant hydrology (Chatterjee et al., 2008; van Oploo et al., 2008; Serrano et al., 2009).

  6. Anion-exchange resin-based desulfurization process

    SciTech Connect (OSTI)

    Sheth, A.C.; Strevel, S.D.

    1991-01-01T23:59:59.000Z

    The University of Tennessee Space Institute (UTSI) has been directed to further develop an anion-exchange, resin-based desulfurization concept. It is necessary that the soluble sulfates of alkali metal sorbents be desulfurized (regenerated) and recycled to make regenerative flue gas desulfurization options more attractive. In order to achieve this, a low-temperature, low-cost desulfurization process to reactivate spent alkali metal sorbents is necessary. UTSI's anion-exchange, resin-based concept is believed to satisfy this requirement. Investigators will perform the following investigations: screening of commercially available resins; process variables study and improving resin performance; optimization of resin-regeneration; evaluation of performance enhancers; development of Best-Process Schematic and related economics; and planing for proof-of-concept (POC) scale testing. 2 refs., 3 figs., 3 tabs.

  7. Charge exchange molecular ion source

    DOE Patents [OSTI]

    Vella, Michael C.

    2003-06-03T23:59:59.000Z

    Ions, particularly molecular ions with multiple dopant nucleons per ion, are produced by charge exchange. An ion source contains a minimum of two regions separated by a physical barrier and utilizes charge exchange to enhance production of a desired ion species. The essential elements are a plasma chamber for production of ions of a first species, a physical separator, and a charge transfer chamber where ions of the first species from the plasma chamber undergo charge exchange or transfer with the reactant atom or molecules to produce ions of a second species. Molecular ions may be produced which are useful for ion implantation.

  8. Anion-exchange resin-based desulfurization process

    SciTech Connect (OSTI)

    Sheth, A.C.; Strevel, S.D.; Dharmapurikar, R.

    1992-01-01T23:59:59.000Z

    Under DOE Grant No. FG22-90PC90309, the University of Tennessee Space Institute (UTSI) is contracted to further develop its anion-exchange, resin-based desulfurization concept to desulfurize alkali metal sulfates. From environmental as well as economic viewpoints, it is necessary to remove soluble sulfates from the wastes created by flue gas desulfurization systems. In order to do this economically, a low-cost desulfurization process for spent sorbents is necessary. UTSI's anion-exchange resin-based desulfurization concept is believed to satisfy these requirements.

  9. Revised Thermal Analysis of LANL Ion Exchange Column

    SciTech Connect (OSTI)

    Laurinat, J

    2006-04-11T23:59:59.000Z

    This document updates a previous calculation of the temperature distributions in a Los Alamos National Laboratory (LANL) ion exchange column.1 LANL operates two laboratory-scale anion exchange columns, in series, to extract Pu-238 from nitric acid solutions. The Defense Nuclear Facilities Safety Board has requested an updated analysis to calculate maximum temperatures for higher resin loading capacities obtained with a new formulation of the Reillex HPQ anion exchange resin. The increased resin loading capacity will not exceed 118 g plutonium per L of resin bed. Calculations were requested for normal operation of the resin bed at the minimum allowable solution feed rate of 30 mL/min and after an interruption of flow at the end of the feed stage, when one of the columns is fully loaded. The object of the analysis is to demonstrate that the decay heat from the Pu-238 will not cause resin bed temperatures to increase to a level where the resin significantly degrades. At low temperatures, resin bed temperatures increase primarily due to decay heat. At {approx}70 C a Low Temperature Exotherm (LTE) resulting from the reaction between 8-12 M HNO{sub 3} and the resin has been observed. The LTE has been attributed to an irreversible oxidation of pendant ethyl benzene groups at the termini of the resin polymer chains by nitric acid. The ethyl benzene groups are converted to benzoic acid moities. The resin can be treated to permanently remove the LTE by heating a resin suspension in 8M HNO{sub 3} for 30-45 minutes. No degradation of the resin performance is observed after the LTE removal treatment. In fact, heating the resin in boiling ({approx}115-120 C) 12 M HNO{sub 3} for 3 hr displays thermal stability analogous to resin that has been treated to remove the LTE. The analysis is based on a previous study of the SRS Frames Waste Recovery (FWR) column, performed in support of the Pu-238 production campaign for NASA's Cassini mission. In that study, temperature transients following an interruption of flow to the column were calculated. The transient calculations were terminated after the maximum resin bed temperature reached the Technical Standard of 60 C, which was set to prevent significant resin degradation. The LANL column differs from the FWR column in that it has a significantly smaller radius, 3.73 cm nominal versus approximately 28 cm. It follows that natural convection removes heat much more effectively from the LANL column, so that the column may reach thermal equilibrium. Consequently, the calculations for a flow interruption were extended until an approach to thermal equilibrium was observed. The LANL ion exchange process also uses a different resin than was used in the FWR column. The LANL column uses Reillex HPQ{trademark} resin, which is more resistant to attack by nitric acid than the Ionac 641{trademark} resin used in the FWR column. Heat generation from the resin oxidation reaction with nitric acid is neglected in this analysis since LANL will be treating the resin to remove the LTE prior to loading the resin in the columns. Calculations were performed using a finite difference computer code, which incorporates models for absorption and elution of plutonium and for forced and natural convection within the resin bed. Calculations for normal column operation during loading were performed using an initial temperature and a feed temperature equal to the ambient air temperature. The model for the normal flow calculations did not include natural convection within the resin bed. The no flow calculations were started with the temperature and concentration profiles at the end of the loading stage, when there would be a maximum amount of plutonium either adsorbed on the resin or in the feed solution in the column.

  10. Ion exchange technology assessment report

    SciTech Connect (OSTI)

    Duhn, E.F.

    1992-01-01T23:59:59.000Z

    In the execution of its charter, the SRS Ion Exchange Technology Assessment Team has determined that ion exchange (IX) technology has evolved to the point where it should now be considered as a viable alternative to the SRS reference ITP/LW/PH process. The ion exchange media available today offer the ability to design ion exchange processing systems tailored to the unique physical and chemical properties of SRS soluble HLW's. The technical assessment of IX technology and its applicability to the processing of SRS soluble HLW has demonstrated that IX is unquestionably a viable technology. A task team was chartered to evaluate the technology of ion exchange and its potential for replacing the present In-Tank Precipitation and proposed Late Wash processes to remove Cs, Sr, and Pu from soluble salt solutions at the Savannah River Site. This report documents the ion exchange technology assessment and conclusions of the task team.

  11. Ion exchange technology assessment report

    SciTech Connect (OSTI)

    Duhn, E.F.

    1992-12-31T23:59:59.000Z

    In the execution of its charter, the SRS Ion Exchange Technology Assessment Team has determined that ion exchange (IX) technology has evolved to the point where it should now be considered as a viable alternative to the SRS reference ITP/LW/PH process. The ion exchange media available today offer the ability to design ion exchange processing systems tailored to the unique physical and chemical properties of SRS soluble HLW`s. The technical assessment of IX technology and its applicability to the processing of SRS soluble HLW has demonstrated that IX is unquestionably a viable technology. A task team was chartered to evaluate the technology of ion exchange and its potential for replacing the present In-Tank Precipitation and proposed Late Wash processes to remove Cs, Sr, and Pu from soluble salt solutions at the Savannah River Site. This report documents the ion exchange technology assessment and conclusions of the task team.

  12. Anion-exchange resin-based desulfurization process

    SciTech Connect (OSTI)

    Sheth, A.C.; Strevel, S.D.

    1991-01-01T23:59:59.000Z

    Under the current grant (FG22-90PC90309), the University of Tennessee Space Institute (UTSI) will carry out the necessary bench scale experiments to further develop it anion-exchange, resin-based desulfurization concept to desulfurize alkali metal sulfates. In particular, it is planned to screen commercially available resins and then carry out process optimization work with three selected resins. Further optimization of the resin regeneration step as well as evaluation of the effect of various performance enhancers will then be carried out with one selected resin. A process schematic, to be developed based on the bench scale results, will be used to estimate the related economics. Some limited scope testing will also be carried out using the spent-seed and sorbent materials obtained from both the coal-fired magnetohydrodynamics (MHD) and the in-duct sorbent injection pilot scale facilities. During this reporting period, 90% of the planned batch mode screening experiments for the eleven samples of candidate resins were completed. Preliminary evaluation of the resulting data is continuing in order to select a smaller number (3--4) of samples for screening in the fixed-bed setup. The installation of the semi-automated fixed-bed setup is about 70% complete and shakedown experiments will be started in 3--4 weeks. Progress made in relation to these activities is presented below. 2 figs., 3 tabs.

  13. Regeneration of anion exchange resins by catalyzed electrochemical reduction

    DOE Patents [OSTI]

    Gu, Baohua (Oak Ridge, TN); Brown, Gilbert M. (Knoxville, TN)

    2002-01-01T23:59:59.000Z

    Anion exchange resins sorbed with perchlorate may be regenerated by a combination of chemical reduction of perchlorate to chloride using a reducing agent and an electrochemical reduction of the oxidized reducing agent. Transitional metals including Ti, Re, and V are preferred chemical reagents for the reduction of perchlorate to chloride. Complexing agents such as oxalate are used to prevent the precipitation of the oxidized Ti(IV) species, and ethyl alcohol may be added to accelerate the reduction kinetics of perchlorate. The regeneration may be performed by continuously recycling the regenerating solution through the resin bed and an electrochemical cell so that the secondary waste generation is minimized.

  14. Ion exchange polymers for anion separations

    DOE Patents [OSTI]

    Jarvinen, G.D.; Marsh, S.F.; Bartsch, R.A.

    1997-09-23T23:59:59.000Z

    Anion exchange resins including at least two positively charged sites and a well-defined spacing between the positive sites are provided together with a process of removing anions or anionic metal complexes from aqueous solutions by use of such resins. The resins can be substituted poly(vinylpyridine) and substituted polystyrene.

  15. Ion exchange polymers for anion separations

    DOE Patents [OSTI]

    Jarvinen, Gordon D. (Los Alamos, NM); Marsh, S. Fredric (Los Alamos, NM); Bartsch, Richard A. (Lubbock, TX)

    1997-01-01T23:59:59.000Z

    Anion exchange resins including at least two positively charged sites and a ell-defined spacing between the positive sites are provided together with a process of removing anions or anionic metal complexes from aqueous solutions by use of such resins. The resins can be substituted poly(vinylpyridine) and substituted polystyrene.

  16. Regeneration of strong-base anion-exchange resins by sequential chemical displacement

    DOE Patents [OSTI]

    Brown, Gilbert M. (Knoxville, TN); Gu, Baohua (Oak Ridge, TN); Moyer, Bruce A. (Oak Ridge, TN); Bonnesen, Peter V. (Knoxville, TN)

    2002-01-01T23:59:59.000Z

    A method for regenerating strong-base anion exchange resins utilizing a sequential chemical displacement technique with new regenerant formulation. The new first regenerant solution is composed of a mixture of ferric chloride, a water-miscible organic solvent, hydrochloric acid, and water in which tetrachloroferrate anion is formed and used to displace the target anions on the resin. The second regenerant is composed of a dilute hydrochloric acid and is used to decompose tetrachloroferrate and elute ferric ions, thereby regenerating the resin. Alternative chemical displacement methods include: (1) displacement of target anions with fluoroborate followed by nitrate or salicylate and (2) displacement of target anions with salicylate followed by dilute hydrochloric acid. The methodology offers an improved regeneration efficiency, recovery, and waste minimization over the conventional displacement technique using sodium chloride (or a brine) or alkali metal hydroxide.

  17. Ion Exchange Kinetics Testing with SRF Resin

    SciTech Connect (OSTI)

    Russell, Renee L.; Rinehart, Donald E.; Brown, Garrett N.; Schonewill, Philip P.; Peterson, Reid A.

    2012-04-01T23:59:59.000Z

    The U.S. Department of Energy (DOE) Hanford Site contains more than 53 million gallons of legacy waste generated as a byproduct of plutonium production and reprocessing operations. The wastes are a complex mixture composed mostly of NaNO3, NaNO2, NaOH, NaAlO2, Na3PO4, and Na2SO4, with a number of minor and trace metals, organics, and radionuclides stored in underground waste tanks. The DOE Office of River Protection (ORP) has contracted Bechtel National Incorporated (BNI) to build a pretreatment facility, the River Protection Project-Waste Treatment Plant (RPP-WTP), that will separate long-lived transuranics (TRU) and highly radioactive components (specifically 137Cs and, in selected cases, 90Sr) from the bulk (non-radioactive) constituents and immobilize the wastes by vitrification. The plant is designed to produce two waste streams: a high-volume low-activity waste (LAW) and a low-volume high-activity waste (HLW).

  18. Ion exchange purification of scandium

    DOE Patents [OSTI]

    Herchenroeder, L.A.; Burkholder, H.R.

    1990-10-23T23:59:59.000Z

    An improvement in purification of scandium through ion exchange chromatography is disclosed in which the oxidation potential of the eluting solution is altered by the addition of potassium chlorate or ammonium chloride so that removal of contaminants is encouraged. The temperature, pH and concentration of the eluent HEDTA are controlled in order to maintain the scandium in the column while minimizing dilution of the scandium band. Recovery of scandium is improved by pumping dilute scandium over the column prior to stripping the scandium and precipitation. This eliminates the HEDTA ion and other monovalent cations contaminating the scandium band. This method maximizes recovery of scandium while maintaining purity. 2 figs.

  19. PRTR ion exchange vault column sampling

    SciTech Connect (OSTI)

    Cornwell, B.C.

    1995-03-14T23:59:59.000Z

    This report documents ion exchange column sampling and Non Destructive Assay (NDA) results from activities in 1994, for the Plutonium Recycle Test Reactor (PRTR) ion exchange vault. The objective was to obtain sufficient information to prepare disposal documentation for the ion exchange columns found in the PRTR Ion exchange vault. This activity also allowed for the monitoring of the liquid level in the lower vault. The sampling activity contained five separate activities: (1) Sampling an ion exchange column and analyzing the ion exchange media for purpose of waste disposal; (2) Gamma and neutron NDA testing on ion exchange columns located in the upper vault; (3) Lower vault liquid level measurement; (4) Radiological survey of the upper vault; and (5) Secure the vault pending waste disposal.

  20. Inorganic Chemistry, "01. 13,No. 7, 1974 exchange resin using acetonitrile as eluent. The acetonitrile was

    E-Print Network [OSTI]

    Bodner, George M.

    Inorganic Chemistry, "01. 13,No. 7, 1974 exchange resin using acetonitrile as eluent. The acetonitrile was removed in vacuo and the residue sublimed at 40-45" to obtain 0.764 g (4.3 5% yield, mp 145

  1. Summary of Testing of SuperLig 639 at the TFL Ion Exchange Facility

    SciTech Connect (OSTI)

    Steimke, J.L.

    2000-12-19T23:59:59.000Z

    A pilot scale facility was designed and built in the Thermal Fluids Laboratory at the Savannah River Technology Center to test ion exchange resins for removing technetium and cesium from simulated Hanford Low Activity Waste (LAW). The facility supports the design of the Hanford River Protection Project for BNFL, Inc. The pilot scale system mimics the full-length of the columns and the operational scenario of the planned ion exchange system. Purposes of the testing include confirmation of the design, evaluation of methods for process optimization and developing methods for waste volume minimization. This report documents the performance of the technetium removal resin.

  2. Experimental Ion Exchange Column With SuperLig 639 And Simulant Formulation

    SciTech Connect (OSTI)

    Morse, Megan; Nash, C.

    2013-08-26T23:59:59.000Z

    SuperLig®639 ion exchange resin was tested as a retrieval mechanism for pertechnetate, through decontamination of a perrhenate spiked 5M Simple Average Na{sup +} Mass Based Simulant. Testing included batch contacts and a three-column ion exchange campaign. A decontamination of perrhenate exceeding 99% from the liquid feed was demonstrated. Analysis of the first formulation of a SBS/WESP simulant found unexpectedly low concentrations of soluble aluminum. Follow-on work will complete the formulation.

  3. Sandia National Laboratories: molecularly engineered ion exchanger

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ion exchanger ECIS and UOP (a Honewell Company): CSTs Clean Radioactive Waste in Fukushima and Worldwide On February 14, 2013, in Energy, Materials Science, Nuclear Energy,...

  4. Small-Scale Ion Exchange Removal of Cesium and Technetium from Hanford Tank 241-AN-103

    SciTech Connect (OSTI)

    Hassan, N.M.

    2000-07-27T23:59:59.000Z

    The pretreatment process for BNFL, Inc.'s Hanford River Protection Project is to provide decontaminated low activity waste and concentrated eluate streams for vitrification into low activity and high level waste glass, respectively. The pretreatment includes sludge washing, filtration, precipitation, and ion exchange processes to remove entrained solids, cesium, transuranics, technetium, and strontium. The ion exchange removal of cesium (Cs) and technetium (Tc) ions is accomplished by using SuperLig 644, and 639 resins from IBC Advanced Technologies, American Fork, Utah. The resins were shown to selectively remove cesium and technetium (as pertechnetate), from alkaline salt solutions. The efficiency of ion exchange column loading and elution is a complex function involving feed compositions, equilibrium and kinetic behavior of ion exchange resins, diffusion, and the ionic strength and pH of the aqueous solution. A previous experimental program completed at the Savannah River Technology Center demonstrated the conceptualized flow sheet parameters with a similar Hanford tank sample (241-AW-101). Those experiments included determination of Cs and Tc batch distribution coefficients by SuperLig 644 and 639 resins and demonstration of small-scale column breakthrough and elution. The experimental findings were used in support of preliminary design bases and pretreatment flow sheet development by BNFL, Inc.

  5. Cesium Ion Exchange Using Tank 241-AN-104 Supernate

    SciTech Connect (OSTI)

    Adu-Wusu, K.

    2003-12-22T23:59:59.000Z

    The River Protection Project is to design and build a high level nuclear waste treatment facility. The waste treatment plant is to process millions of gallons of radioactive waste stored in tanks at the Hanford Site. The high level nuclear waste treatment process includes various unit operations, such as ultrafiltration, precipitation, evaporation, ion exchange, and vitrification. Ion exchange is identified as the optimal treatment method for removal of cesium-137 and Tc-99 from the waste. Extensive ion exchange testing was performed using small-scale columns with actual waste samples. The objectives of this study were to: demonstrate SuperLig 644 ion exchange performance and process steps for the removal of cesium from actual AN-104 tank waste; pretreat actual AN-104 tank waste to reduce the concentration of cesium-137 in the waste below LAW vitrification limit; produce and characterize cesium eluate solutions for use in eluate evaporation tests. The experiments consisted of batch contact and small-scale column tests. The batch contact tests measured sorption partition coefficients Kds. The Kds were used to predict the effective resin capacity. The small-scale column tests, which closely mimic plant conditions, generated loading and elution profile data used to determine whether removal targets and design requirements were met.

  6. Phenolic cation-exchange resin material for recovery of cesium and strontium. [Patent application

    DOE Patents [OSTI]

    Ebra, M.A.; Wallace, R.M.

    1982-05-05T23:59:59.000Z

    A phenolic cation exchange resin with a chelating group has been prepared by reacting resorcinol with iminodiacetic acid in the presence of formaldehyde at a molar ratio of about 1:1:6. The material is highly selective for the simultaneous recovery of both cesium and strontium from aqueous alkaline solutions, such as, aqueous alkaline nuclear wate solutions. The organic resins are condensation polymers of resorcinol and formaldehyde with attached chelating groups. The column performance of the resins compares favorably with that of commercially available resins for either cesium or strontium removal. By combining Cs/sup +/ and Sr/sup 2 +/ removal in the same bed, the resins allow significant reduction of the size and complexity of facilities for processing nuclear waste.

  7. Dynamic Asphaltene-Resin Exchange at the Oil/Water Interface: Time-Dependent W/O Emulsion Stability for Asphaltene/Resin

    E-Print Network [OSTI]

    Kilpatrick, Peter K.

    Dynamic Asphaltene-Resin Exchange at the Oil/Water Interface: Time-Dependent W/O Emulsion Stability for Asphaltene/Resin Model Oils Xiaoli Yang, Vincent J. Verruto, and Peter K. Kilpatrick* Department of Chemical was used to determine the time-dependent stability of water-in- oil emulsions in which asphaltenes

  8. MODELING AN ION EXCHANGE PROCESS FOR CESIUM REMOVAL FROM ALKALINE RADIOACTIVE WASTE SOLUTIONS

    SciTech Connect (OSTI)

    Smith, F; Luther Hamm, L; Sebastian Aleman, S; Johnston Michael, J

    2008-08-26T23:59:59.000Z

    The performance of spherical Resorcinol-Formaldehyde ion-exchange resin for the removal of cesium from alkaline radioactive waste solutions has been investigated through computer modeling. Cesium adsorption isotherms were obtained by fitting experimental data using a thermodynamic framework. Results show that ion-exchange is an efficient method for cesium removal from highly alkaline radioactive waste solutions. On average, two 1300 liter columns operating in series are able to treat 690,000 liters of waste with an initial cesium concentration of 0.09 mM in 11 days achieving a decontamination factor of over 50,000. The study also tested the sensitivity of ion-exchange column performance to variations in flow rate, temperature and column dimensions. Modeling results can be used to optimize design of the ion exchange system.

  9. DIVALENT ION EXCHANGE WITH ALKALI

    E-Print Network [OSTI]

    Bunge, A.L.

    2011-01-01T23:59:59.000Z

    Injection for Enhanced Oil Recovery - A Status Report," SPEDOE Symposium on Enhanced Oil Recovery, Tulsa, OK, Apri120-ions is important enhanced oil recovery with chemical addi-

  10. Method for regenerating magnetic polyamine-epichlorohydrin resin

    DOE Patents [OSTI]

    Kochen, Robert L. (Boulder, CO); Navratil, James D. (Simi Valley, CA)

    1997-07-29T23:59:59.000Z

    Magnetic polymer resins capable of efficient removal of actinides and heavy metals from contaminated water are disclosed together with methods for making, using, and regenerating them. The resins comprise polyamine-epichlorohydrin resin beads with ferrites attached to the surfaces of the beads. Markedly improved water decontamination is demonstrated using these magnetic polymer resins of the invention in the presence of a magnetic field, as compared with water decontamination methods employing ordinary ion exchange resins or ferrites taken separately.

  11. Method for regenerating magnetic polyamine-epichlorohydrin resin

    DOE Patents [OSTI]

    Kochen, R.L.; Navratil, J.D.

    1997-07-29T23:59:59.000Z

    Magnetic polymer resins capable of efficient removal of actinides and heavy metals from contaminated water are disclosed together with methods for making, using, and regenerating them. The resins comprise polyamine-epichlorohydrin resin beads with ferrites attached to the surfaces of the beads. Markedly improved water decontamination is demonstrated using these magnetic polymer resins of the invention in the presence of a magnetic field, as compared with water decontamination methods employing ordinary ion exchange resins or ferrites taken separately. 9 figs.

  12. IMPACT OF THE SMALL COLUMN ION EXCHANGE PROCESS ON THE DEFENSE WASTE PROCESSING FACILITY - 12112

    SciTech Connect (OSTI)

    Koopman, D.; Lambert, D.; Fox, K.; Stone, M.

    2011-11-07T23:59:59.000Z

    The Savannah River Site (SRS) is investigating the deployment of a parallel technology to the Salt Waste Processing Facility (SWPF, presently under construction) to accelerate high activity salt waste processing. The proposed technology combines large waste tank strikes of monosodium titanate (MST) to sorb strontium and actinides with two ion exchange columns packed with crystalline silicotitanate (CST) resin to sorb cesium. The new process was designated Small Column Ion Exchange (SCIX), since the ion exchange columns were sized to fit within a waste storage tank riser. Loaded resins are to be combined with high activity sludge waste and fed to the Defense Waste Processing Facility (DWPF) for incorporation into the current glass waste form. Decontaminated salt solution produced by SCIX will be fed to the SRS Saltstone Facility for on-site immobilization as a grout waste form. Determining the potential impact of SCIX resins on DWPF processing was the basis for this study. Accelerated salt waste treatment is projected to produce a significant savings in the overall life cycle cost of waste treatment at SRS.

  13. Decontamination and dismantlement of the building 594 waste ion exchange facility at Argonne National Laboratory-East project final report.

    SciTech Connect (OSTI)

    Wiese, E. C.

    1998-11-23T23:59:59.000Z

    The Building 594 D&D Project was directed toward the following goals: Removal of any radioactive and hazardous materials associated with the Waste Ion Exchange Facility; Decontamination of the Waste Ion Exchange Facility to unrestricted use levels; Demolition of Building 594; and Documentation of all project activities affecting quality (i.e., waste packaging, instrument calibration, audit results, and personnel exposure) These goals had been set in order to eliminate the radiological and hazardous safety concerns inherent in the Waste Ion Exchange Facility and to allow, upon completion of the project, unescorted and unmonitored access to the area. The ion exchange system and the resin contained in the system were the primary areas of concern, while the condition of the building which housed the system was of secondary concern. ANL-E health physics technicians characterized the Building 594 Waste Ion Exchange Facility in September 1996. The characterization identified a total of three radionuclides present in the Waste Ion Exchange Facility with a total activity of less than 5 {micro}Ci (175 kBq). The radionuclides of concern were Co{sup 60}, Cs{sup 137}, and Am{sup 241}. The highest dose rates observed during the project were associated with the resin in the exchange vessels. DOE Order 5480.2A establishes the maximum whole body exposure for occupational workers at 5 rem (50 mSv)/yr; the administrative limit at ANL-E is 1 rem/yr (10 mSv/yr).

  14. Evaluation of Ion Exchange Materials in K Basin Floor Sludge and Potential Solvents for PCB Extraction from Ion Exchange Materials

    SciTech Connect (OSTI)

    Schmidt, A.J.; Klinger, G.S.; Bredt, P.R.

    1999-04-10T23:59:59.000Z

    Approximately 73 m{sup 3} of heterogeneous solid material, ''sludge,'' (upper bound estimate, Packer 1997) have accumulated at the bottom of the K Basins in the 100 K Area of the Hanford Site. This sludge is a mixture of spent fuel element corrosion products, ion exchange materials (organic and inorganic), graphite-based gasket materials, iron and aluminum metal corrosion products, sand, and debris (Makenas et al. 1996, 1997). In addition, small amounts of polychlorinated biphenyls (PCBs) have been found. These small amounts are significant from a regulatory standpoint. Ultimately, it is planned to transfer the K Basins sludge to the Hanford double shell tanks (DSTs). Chemical pretreatment is required to address criticality issues and the destruction or removal of PCBs before the K Basin sludge can be transferred to the DSTs. Eleven technologies have been evaluated (Papp 1997) as potential pretreatment methods. Based on the evaluations and engineering studies and limited testing, Fluor Daniel Hanford recommended solvent washing of the K Basin sludge, followed by nitric acid dissolution and, potentially, peroxide addition (FDH 1997). The solvent washing (extraction) and peroxide addition would be used to facilitate PCB removal and destruction. Following solvent extraction, the PCBs could be distilled and concentrated for disposal as a low-level waste. The purpose of the work reported here was to continue investigating solvent extraction, first by better identifying the ion exchange materials in the actual sludge samples and then evaluating various solvents for removing the PCBs or possibly dissolving the resins. This report documents some of the process knowledge on ion exchange materials used and spilled in the K Basins and describes the materials identified from wet sieving KE Basin floor and canister sludge and the results of other analyses. Several photographs are included to compare materials and illustrate material behavior. A summary of previous tests on solvent extraction of PCB surrogates from simulant K Basin sludge is also given.

  15. Literature Review of Spherical Resorcinol-Formaldehyde for Cesium Ion Exchange

    SciTech Connect (OSTI)

    Brown, Garrett N.

    2014-09-30T23:59:59.000Z

    The current report summarizes work performed throughout the scientific community and DOE complex as reported in the open literature and DOE-sponsored reports to evaluate the Cs+ ion exchange (CIX) characteristics of SRF resin. King (2007) completed a similar literature review in support of material selection for the Small Column Ion Exchange (SCIX) project. Josephson et al. (2010) and Sams et al. (2009) provided a similar brief review of SRF CIX for the near-tank Cs+ removal (NTCR) project. Thorson (2008a) documented the basis for recommending SRF over SuperLigTM 644 as the primary CIX resin in the WTP. The current review expands on previous work, summarizes additional work completed to date, and provides a broad view of the literature without focusing on a specific column system. Although the focus of the current review is the SRF resin, many cited references include multiple materials such as the non-spherical GGRF and SuperLigTM 644 organic resins and crystalline silicotitanate (CST) IONSIVTM IE-911, a non-elutable inorganic material. This report summarizes relevant information provided in the literature.

  16. PRTR ion exchange vault water removal

    SciTech Connect (OSTI)

    Ham, J.E.

    1995-11-01T23:59:59.000Z

    This report documents the removal of radiologically contaminated water from the Plutonium Recycle Test Reactor (PRTR) ion exchange vault. Approximately 57,000 liters (15,000 gallons) of water had accumulated in the vault due to the absence of a rain cover. The water was removed and the vault inspected for signs of leakage. No evidence of leakage was found. The removal and disposal of the radiologically contaminated water decreased the risk of environmental contamination.

  17. Recent advances in UTSI`s anion-exchange resin-based seed regeneration process

    SciTech Connect (OSTI)

    Sheth, A.C.; Holt, J.K.; Strevel, S.D.; Parthasarathy, S. [Univ. of Tennessee Space Institute, Tullahoma, TN (United States)] [and others

    1993-12-31T23:59:59.000Z

    In a Magnetohydrodynamic (MHD) system the combustion gases are seeded with easily ionized potassium carbonate to provide about 1% by weight of potassium in the resulting plasma. The potassium carbonate seed serves the dual purpose of increasing the electrical conductivity of the plasma and of removing the sulfur-containing gaseous products derived from combustion of the fossil fuel. To improve the economics of the MHD technology, a high percentage of the potassium is recovered and recycled in the form of sulfur-free potassium salts such as potassium carbonate. The process of sulfur removal from the spent seed, K{sub 2}SO{sub 4}-rich material, is termed seed regeneration. A seed regeneration concept has been developed and tested at the University of Tennessee Space Institute (UTSI), wherein a commercially available weak-base, anion-exchange resin is used at ambient conditions to remove sulfur from the alkali metal sulfates. Currently, under grants from the University Coal Research (UCR) program sponsored by the U.S. Department of Energy`s Pittsburgh Energy Technology Center, and from the Small Business Innovative Research (SBIR) program administered by the U.S. DOE Headquarters, UTSI is developing an anion-exchange resin-based seed regeneration concept. In this paper, the major results from these two concurrent studies are discussed, and the recommendations for the appropriate future efforts are provided.

  18. Anion-exchange resin-based desulfurization process. Quarterly technical progress report, Januray 1, 1992--March 31, 1992

    SciTech Connect (OSTI)

    Sheth, A.C.; Strevel, S.D.; Dharmapurikar, R.

    1992-07-01T23:59:59.000Z

    Under DOE Grant No. FG22-90PC90309, the University of Tennessee Space Institute (UTSI) is contracted to further develop its anion-exchange, resin-based desulfurization concept to desulfurize alkali metal sulfates. From environmental as well as economic viewpoints, it is necessary to remove soluble sulfates from the wastes created by flue gas desulfurization systems. In order to do this economically, a low-cost desulfurization process for spent sorbents is necessary. UTSI`s anion-exchange resin-based desulfurization concept is believed to satisfy these requirements.

  19. Removal of radioactive materials and heavy metals from water using magnetic resin

    DOE Patents [OSTI]

    Kochen, Robert L. (Boulder, CO); Navratil, James D. (Simi Valley, CA)

    1997-01-21T23:59:59.000Z

    Magnetic polymer resins capable of efficient removal of actinides and heavy metals from contaminated water are disclosed together with methods for making, using, and regenerating them. The resins comprise polyamine-epichlorohydrin resin beads with ferrites attached to the surfaces of the beads. Markedly improved water decontamination is demonstrated using these magnetic polymer resins of the invention in the presence of a magnetic field, as compared with water decontamination methods employing ordinary ion exchange resins or ferrites taken separately.

  20. Removal of radioactive materials and heavy metals from water using magnetic resin

    DOE Patents [OSTI]

    Kochen, R.L.; Navratil, J.D.

    1997-01-21T23:59:59.000Z

    Magnetic polymer resins capable of efficient removal of actinides and heavy metals from contaminated water are disclosed together with methods for making, using, and regenerating them. The resins comprise polyamine-epichlorohydrin resin beads with ferrites attached to the surfaces of the beads. Markedly improved water decontamination is demonstrated using these magnetic polymer resins of the invention in the presence of a magnetic field, as compared with water decontamination methods employing ordinary ion exchange resins or ferrites taken separately. 9 figs.

  1. alkali ion exchange: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    many biological processes. In ion channels3 Guidoni, Leonardo 2 Spin-Exchange Optical Pumping with Alkali-Metal Vapors Physics Websites Summary: Spin-Exchange Optical Pumping with...

  2. adjustment ion exchange: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of intra-molecular interactions on the gas-phase conformation of peptides as probed by ion mobility-mass spectrometry, gas-phase hydrogendeuterium exchange, and molecular...

  3. argentine ion exchange: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of intra-molecular interactions on the gas-phase conformation of peptides as probed by ion mobility-mass spectrometry, gas-phase hydrogendeuterium exchange, and molecular...

  4. acidic ion exchange: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of the chlorine ion in freezing salt on the corrosion behavior of automobile IF steel in boric acid buffer solution with different chloride ions Volinsky, Alex A. 157 GAS EXCHANGE...

  5. The adsorption and desorption of picloram, trifluralin, and paraquat by ionic and nonionic exchange resins

    E-Print Network [OSTI]

    McCall, Homer Gene

    1970-01-01T23:59:59.000Z

    !nc of soi ution and vc ry s!n&11 anount o( a&isorbe?t us?&i in !! nst of. 1:he =, t urlies r&v i ?wed. Th? srna1 1 vol u!nes us& d in ti!is sLuriy . I I!niLcd the lr vel s of. herhi cidal co!. cent rations. I CHg CI-Ig c . J 2' 2CI C N-IC ? C-(. )2...THE ADSORPTION AND DESORPTIOV OF PICLORAM, TRIi LURALIN, AND PARAQUAT BY IONIC AND NON-IOiVIC EXCHANGE RESINS A Thesi. s HO~!1L'R GEiVE MCCAJ I. Silhmfti c~1 1 o the Cr icli! ite C& I lece of ieicc! s Arc M Ull 1 i '1". s1. I v i. il part Ial...

  6. Small-Column Cesium Ion Exchange Elution Testing of Spherical Resorcinol-Formaldehyde

    SciTech Connect (OSTI)

    Brown, Garrett N.; Russell, Renee L.; Peterson, Reid A.

    2011-10-21T23:59:59.000Z

    This report summarizes the work performed to evaluate multiple, cesium loading, and elution cycles for small columns containing SRF resin using a simple, high-level waste (HLW) simulant. Cesium ion exchange loading and elution curves were generated for a nominal 5 M Na, 2.4E-05 M Cs, 0.115 M Al loading solution traced with 134Cs followed by elution with variable HNO3 (0.02, 0.07, 0.15, 0.23, and 0.28 M) containing variable CsNO3 (5.0E-09, 5.0E-08, and 5.0E-07 M) and traced with 137Cs. The ion exchange system consisted of a pump, tubing, process solutions, and a single, small ({approx}15.7 mL) bed of SRF resin with a water-jacketed column for temperature-control. The columns were loaded with approximately 250 bed volumes (BVs) of feed solution at 45 C and at 1.5 to 12 BV per hour (0.15 to 1.2 cm/min). The columns were then eluted with 29+ BVs of HNO3 processed at 25 C and at 1.4 BV/h. The two independent tracers allowed analysis of the on-column cesium interaction between the loading and elution solutions. The objective of these tests was to improve the correlation between the spent resin cesium content and cesium leached out of the resin in subsequent loading cycles (cesium leakage) to help establish acid strength and purity requirements.

  7. anion-exchange resin technique: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Mohd Meraj Jafri; Dr. D. K. Singh; Dr. P. K. Kamani 13 Monitoring the resin infusion manufacturing process under industrial environment using distributed sensors CERN...

  8. Inorganic ion exchange evaluation and design: Silicotitanate ion exchange waste conversion

    SciTech Connect (OSTI)

    Balmer, M.L.; Bunker, B.C.

    1995-03-01T23:59:59.000Z

    Ion exchange materials are being evaluated for removing Cs, SR from tank waste. Thermal conversion of a variety of compositions within the Cs{sub 2}O-TiO{sub 2}-SiO{sub 2} phase diagram yielded both glass and crystalline materials, some of which show low leach rates and negligible Cs losses during heat treatment. A new material, CsTiSi{sub 2}0{sub 6}, with a structure isomorphous to pollucite (CsAlSi{sub 2}0{sub 6}) has been identified. This material represents a new class of crystalline zeolite materials which contain large amounts of titanium. Direct conversion of Cs loaded silicotitanate ion exchangers to CsTiSi{sub 2}O{sub 6} is an excellent alternative to dissolving the Cs-loaded or Cs-eluted exchangers in borosilicate glass because: CsTiSi{sub 2}O{sub 6} is formed using a simple, one step heat treatment. The unique crystalline pollucite-like structure of CsTiSi{sub 2}O{sub 6} traps Cs, and exhibits extremely low Cs leach rates. CsTiSi{sub 2}O{sub 6} is converted to solid waste at a low processing temperature of 700 to 800 C (nominal melter operating temperatures are 1150 C). CsTiSi{sub 2}0{sub 6} concentrates the waste, thus generating lower volumes of expensive HLW. Cs losses due to volatilization during processing of CsTiSi{sub 2}O{sub 6} are extremely low.

  9. Standard practice for the ion exchange separation of uranium and plutonium prior to isotopic analysis

    E-Print Network [OSTI]

    American Society for Testing and Materials. Philadelphia

    2008-01-01T23:59:59.000Z

    Standard practice for the ion exchange separation of uranium and plutonium prior to isotopic analysis

  10. ION EXCHANGE PERFORMANCE OF TITANOSILICATES, GERMANATES AND CARBON NANOTUBES

    SciTech Connect (OSTI)

    Alsobrook, A.; Hobbs, D.

    2013-04-24T23:59:59.000Z

    This report presents a summary of testing the affinity of titanosilicates (TSP), germanium-substituted titanosilicates (Ge-TSP) and multiwall carbon nanotubes (MWCNT) for lanthanide ions in dilute nitric acid solution. The K-TSP ion exchanger exhibited the highest affinity for lanthanides in dilute nitric acid solutions. The Ge-TSP ion exchanger shows promise as a material with high affinity, but additional tests are needed to confirm the preliminary results. The MWCNT exhibited much lower affinities than the K-TSP in dilute nitric acid solutions. However, the MWCNT are much more chemically stable to concentrated nitric acid solutions and, therefore, may candidates for ion exchange in more concentrated nitric acid solutions. This technical report serves as the deliverable documenting completion of the FY13 research milestone, M4FT-13SR0303061 – measure actinide and lanthanide distribution values in nitric acid solutions with sodium and potassium titanosilicate materials.

  11. Nanoscale Heterostructures and Thermoplastic Resin Binders: Novel...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Nanoscale Heterostructures and Thermoplastic Resin Binders: Novel Lithium-Ion Anodes Nanoscale Heterostructures and Thermoplastic Resin Binders: Novel Lithium-Ion Anodes 2012 DOE...

  12. Rupture loop annex ion exchange RLAIX vault deactivation

    SciTech Connect (OSTI)

    Ham, J.E.; Harris, D.L., Westinghouse Hanford

    1996-08-01T23:59:59.000Z

    This engineering report documents the deactivation, stabilization and final conditions of the Rupture Loop Annex Ion Exchange (RLAIX) Vault located northwest of the 309 Building`s Plutonium Recycle Test Reactor (PRTR). Twelve ion exchange columns, piping debris, and column liquid were removed from the vault, packaged and shipped for disposal. The vault walls and floor were decontaminated, and portions of the vault were painted to fix loose contamination. Process piping and drains were plugged, and the cover blocks and rain cover were installed. Upon closure,the vault was empty, stabilized, isolated.

  13. Catalysis using hydrous metal oxide ion exchangers

    DOE Patents [OSTI]

    Dosch, R.G.; Stephens, H.P.; Stohl, F.V.

    1983-07-21T23:59:59.000Z

    In a process which is catalyzed by a catalyst comprising an active metal on a carrier, said metal being active as a catalyst for the process, an improvement is provided wherein the catalyst is a hydrous, alkali metal or alkaline earth metal titanate, zirconate, niobate or tantalate wherein alkali or alkaline earth metal cations have been exchanged with a catalytically effective amount of cations of said metal.

  14. Modeling Uranium-Proton Ion Exchange in Biosorption

    E-Print Network [OSTI]

    Volesky, Bohumil

    seaweed biomass was used to remove the heavy metal uranium from the aqueous solution. Uranium biosorptionModeling Uranium-Proton Ion Exchange in Biosorption J I N B A I Y A N G A N D B O H U M I L V O L E, Quebec, Canada H3A 2B2 Biosorption of uranium metal ions by a nonliving protonated Sargassum fluitans

  15. Thermal Analysis for Ion-Exchange Column System

    SciTech Connect (OSTI)

    Lee, Si Y.; King, William D.

    2012-12-20T23:59:59.000Z

    Models have been developed to simulate the thermal characteristics of crystalline silicotitanate ion exchange media fully loaded with radioactive cesium either in a column configuration or distributed within a waste storage tank. This work was conducted to support the design and operation of a waste treatment process focused on treating dissolved, high-sodium salt waste solutions for the removal of specific radionuclides. The ion exchange column will be installed inside a high level waste storage tank at the Savannah River Site. After cesium loading, the ion exchange media may be transferred to the waste tank floor for interim storage. Models were used to predict temperature profiles in these areas of the system where the cesium-loaded media is expected to lead to localized regions of elevated temperature due to radiolytic decay. Normal operating conditions and accident scenarios (including loss of solution flow, inadvertent drainage, and loss of active cooling) were evaluated for the ion exchange column using bounding conditions to establish the design safety basis. The modeling results demonstrate that the baseline design using one central and four outer cooling tubes provides a highly efficient cooling mechanism for reducing the maximum column temperature. In-tank modeling results revealed that an idealized hemispherical mound shape leads to the highest tank floor temperatures. In contrast, even large volumes of CST distributed in a flat layer with a cylindrical shape do not result in significant floor heating.

  16. MODELING CST ION EXCHANGE FOR CESIUM REMOVAL FROM SCIX BATCHES 1 - 4

    SciTech Connect (OSTI)

    Smith, F.

    2011-04-25T23:59:59.000Z

    The objective of this work is, through modeling, to predict the performance of Crystalline Silicotitinate (CST) for the removal of cesium from Small Column Ion Exchange (SCIX) Batches 1-4 (as proposed in Revision 16 of the Liquid Waste System Plan). The scope of this task is specified in Technical Task Request (TTR) 'SCIX Feed Modeling', HLE-TTR-2011-003, which specified using the Zheng, Anthony, Miller (ZAM) code to predict CST isotherms for six given SCIX feed compositions and the VErsatile Reaction and SEparation simulator for Liquid Chromatography (VERSE-LC) code to predict ion-exchange column behavior. The six SCIX feed compositions provided in the TTR represent SCIX Batches 1-4 and Batches 1 and 2 without caustic addition. The study also investigated the sensitivity in column performance to: (1) Flow rates of 5, 10, and 20 gpm with 10 gpm as the nominal flow; and (2) Temperatures of 25, 35, and 45 C with 35 C as the nominal temperature. The isotherms and column predictions presented in this report reflect the expected performance of engineered CST IE-911. This form of CST was used in experiments conducted at the Savannah River National Laboratory (SRNL) that formed the basis for estimating model parameters (Hamm et al., 2002). As has been done previously, the engineered resin capacity is estimated to be 68% of the capacity of particulate CST without binder.

  17. Water Exchange Rates and Molecular Mechanism around Aqueous Halide Ions

    SciTech Connect (OSTI)

    Annapureddy, Harsha V.; Dang, Liem X.

    2014-07-17T23:59:59.000Z

    Molecular dynamics simulations were performed to systematically study the water-exchange mechanism around aqueous chloride, bromide, and iodide ions. Transition state theory, Grote-Hynes theory, and the reactive flux method were employed to compute water exchange rates. We computed the pressure dependence of rate constants and the corresponding activation volumes to investigate the mechanism of the solvent exchange event. The activation volumes obtained using the transition state theory rate constants are negative for all the three anions, thus indicating an associative mechanism. Contrary to the transition state theory results, activation volumes obtained using rate constants from Grote-Hynes theory and the reactive flux method are positive, thus indicating a dissociative mechanism. The Division of Chemical Sciences, Geosciences, and Biosciences, Office of Basic Energy Sciences (BES), of the U.S. Department of Energy (DOE) funded this work. Battelle operates Pacific Northwest National Laboratory for DOE. The calculations were carried out using computer resources provided by BES.

  18. Westinghouse Modular Grinding Process - Enhancement of Volume Reduction for Hot Resin Supercompaction - 13491

    SciTech Connect (OSTI)

    Fehrmann, Henning [Westinghouse Electric Germany GmbH, Dudenstr. 44, D-68167 Mannheim (Germany)] [Westinghouse Electric Germany GmbH, Dudenstr. 44, D-68167 Mannheim (Germany); Aign, Joerg [Westinghouse Electric Germany GmbH, Global D and D and Waste Management, Tarpenring 6, D-22419 Hamburg (Germany)] [Westinghouse Electric Germany GmbH, Global D and D and Waste Management, Tarpenring 6, D-22419 Hamburg (Germany)

    2013-07-01T23:59:59.000Z

    In nuclear power plants (NPP) ion exchange (IX) resins are used in several systems for water treatment. Spent resins can contain a significant amount of contaminates which makes treatment for disposal of spent resins mandatory. Several treatment processes are available such as direct immobilization with technologies like cementation, bitumisation, polymer solidification or usage of a high integrity container (HIC). These technologies usually come with a significant increase in final waste volume. The Hot Resin Supercompaction (HRSC) is a thermal treatment process which reduces the resin waste volume significantly. For a mixture of powdered and bead resins the HRSC process has demonstrated a volume reduction of up to 75 % [1]. For bead resins only the HRSC process is challenging because the bead resins compaction properties are unfavorable. The bead resin material does not form a solid block after compaction and shows a high spring back effect. The volume reduction of bead resins is not as good as for the mixture described in [1]. The compaction properties of bead resin waste can be significantly improved by grinding the beads to powder. The grinding also eliminates the need for a powder additive.Westinghouse has developed a modular grinding process to grind the bead resin to powder. The developed process requires no circulation of resins and enables a selective adjustment of particle size and distribution to achieve optimal results in the HRSC or in any other following process. A special grinding tool setup is use to minimize maintenance and radiation exposure to personnel. (authors)

  19. HEAT TRANSFER ANALYSIS FOR ION-EXCHANGE COLUMN SYSTEM

    SciTech Connect (OSTI)

    Lee, S.; King, W.

    2011-05-23T23:59:59.000Z

    Models have been developed to simulate the thermal characteristics of Crystalline Silicotitanate (CST) ion exchange media fully loaded with radioactive cesium in a column configuration and distributed within a waste storage tank. This work was conducted to support the Small Column Ion Exchange (SCIX) program which is focused on processing dissolved, high-sodium salt waste for the removal of specific radionuclides (including Cs-137, Sr-90, and actinides) within a High Level Waste (HLW) storage tank at the Savannah River Site. The SCIX design includes CST columns inserted and supported in the tank top risers for cesium removal. Temperature distributions and maximum temperatures across the column were calculated with a focus on process upset conditions. A two-dimensional computational modeling approach for the in-column ion-exchange domain was taken to include conservative, bounding estimates for key parameters such that the results would provide the maximum centerline temperatures achievable under the design configurations using a feed composition known to promote high cesium loading on CST. The current full-scale design for the CST column includes one central cooling pipe and four outer cooling tubes. Most calculations assumed that the fluid within the column was stagnant (i.e. no buoyancy-induced flow) for a conservative estimate. A primary objective of these calculations was to estimate temperature distributions across packed CST beds immersed in waste supernate or filled with dry air under various accident scenarios. Accident scenarios evaluated included loss of salt solution flow through the bed, inadvertent column drainage, and loss of active cooling in the column. The modeling results demonstrate that the baseline design using one central and four outer cooling tubes provides a highly efficient cooling mechanism for reducing the maximum column temperature.

  20. Small Column Ion Exchange Design and Safety Strategy

    SciTech Connect (OSTI)

    Huff, T.; Rios-Armstrong, M.; Edwards, R.; Herman, D.

    2011-02-07T23:59:59.000Z

    Small Column Ion Exchange (SCIX) is a transformational technology originally developed by the Department of Energy (DOE) Environmental Management (EM-30) office and is now being deployed at the Savannah River Site (SRS) to significantly increase overall salt processing capacity and accelerate the Liquid Waste System life-cycle. The process combines strontium and actinide removal using Monosodium Titanate (MST), Rotary Microfiltration, and cesium removal using Crystalline Silicotitanate (CST, specifically UOP IONSIV{reg_sign}IE-911 ion exchanger) to create a low level waste stream to be disposed in grout and a high level waste stream to be vitrified. The process also includes preparation of the streams for disposal, e.g., grinding of the loaded CST material. These waste processing components are technically mature and flowsheet integration studies are being performed including glass formulations studies, application specific thermal modeling, and mixing studies. The deployment program includes design and fabrication of the Rotary Microfilter (RMF) assembly, ion-exchange columns (IXCs), and grinder module, utilizing an integrated system safety design approach. The design concept is to install the process inside an existing waste tank, Tank 41H. The process consists of a feed pump with a set of four RMFs, two IXCs, a media grinder, three Submersible Mixer Pumps (SMPs), and all supporting infrastructure including media receipt and preparation facilities. The design addresses MST mixing to achieve the required strontium and actinide removal and to prevent future retrieval problems. CST achieves very high cesium loadings (up to 1,100 curies per gallon (Ci/gal) bed volume). The design addresses the hazards associated with this material including heat management (in column and in-tank), as detailed in the thermal modeling. The CST must be size reduced for compatibility with downstream processes. The design addresses material transport into and out of the grinder and includes provisions for equipment maintenance including remote handling. The design includes a robust set of nuclear safety controls compliant with DOE Standard (STD)-1189, Integration of Safety into the Design Process. The controls cover explosions, spills, boiling, aerosolization, and criticality. Natural Phenomena Hazards (NPH) including seismic event, tornado/high wind, and wildland fire are considered. In addition, the SCIX process equipment was evaluated for impact to existing facility safety equipment including the waste tank itself. SCIX is an innovative program which leverages DOE's technology development capabilities to provide a basis for a successful field deployment.

  1. Used powdex resin for liquid waste processing

    SciTech Connect (OSTI)

    Pearson, C.J.; Bramblett, J.W.

    1995-05-01T23:59:59.000Z

    Powdex resin has traditionally been used on the Secondary side for condensate polishing. The resins on these polishers are backwashed periodically based on chemical breakthrough or high differential pressure. Upon the backwash, the ion exchange capacity on the powdex resin is not completely exhausted. In the past, this partially used powdex resin was sluiced to a liner and treated as waste for disposal. In an effort to reduce radioactivity being released from segregated, high chemical concentration wastes, the idea of trying used powdex resin was initiated. In 1992, Duke Power Company began processing problem liquid waste streams with used Secondary powdex and subsequent decanting of the waste water for release. the results have shown significant reductions in the activity of this water. This paper will detail the history, method, and the results of using Secondary powdex for liquid radwaste processing. It will also describe the benefits, such as: (1) Processing waste streams not suitable for bead resin demineralizers. (2) Ability to process large volumes of waste water in a short period of time. (3) Recycling media thought to be useless. (4) > 80% Reduction in activity of water processed. (5) Overall curies reduction. (6) Improved bead demineralizer performance.

  2. Determination of Method Detection Limits for Trace 232-Thorium and 238-Uranium in Copper using Ion Exchange and ICPMS

    SciTech Connect (OSTI)

    Hoppe, Eric W.; LaFerriere, Brian D.; Maiti, Tapas C.; Soin, Aleksandr

    2014-04-15T23:59:59.000Z

    Determination of Method Detection Limits for Trace 232-Thorium and 238-Uranium in Copper using Ion Exchange and ICPMS

  3. Fast ion charge exchange spectroscopy adapted for tangential viewing geometry in LHD

    SciTech Connect (OSTI)

    Ito, T.; Osakabe, M.; Ida, K.; Yoshinuma, M.; Kobayashi, M.; Goto, M.; Isobe, M.; Toi, K.; Takeiri, Y.; Okamura, S. [National Institute for Fusion Science, Toki 509-5292 (Japan); Murakami, S.; Kobayashi, S. [Department of Nuclear Engineering, Kyoto University, Kyoto 606-8501 (Japan); Ogawa, K. [Department of Energy Engineering and Science, Nagoya University, Nagoya 464-8601 (Japan)

    2010-10-15T23:59:59.000Z

    A tangential Fast Ion Charge eXchange Spectroscopy is newly applied on a Large Helical Device (LHD) for co/countercirculating fast ions, which are produced by high energy tangential negative-ion based neutral beam injection. With this new observation geometry, both the tangential-neutral beam (NB) and a low-energy radial-NB based on positive ions can be utilized as probe beams of the measurement. We have successfully observed Doppler-shifted H-alpha lights due to the charge exchange process between the probing NB and circulating hydrogen ions of around 100 keV in LHD plasmas.

  4. TOSOH BIOSCIENCE TOYOPEARL Resins for IEC

    E-Print Network [OSTI]

    Lebendiker, Mario

    TOSOH BIOSCIENCE TOYOPEARL Resins for IEC Anion Exchange TOYOPEARL DEAE-650 TOYOPEARL SuperQ-650-550EC TSK-GEL-5PW Bulk Resins for IEC Anion Exchange TSK-GEL SuperQ-5PW TSK-GEL DEAE-5PW Cation Chromatographic Resin IEC is probably the most widely used liquid chromatographic method for the separation

  5. Ion exchange equilibrium - a key to condensate polisher performance

    SciTech Connect (OSTI)

    Darji, J.D.; McGilbra, A.F.

    1980-01-01T23:59:59.000Z

    To successfully deal with the present stringent requirements for boiler feedwater, it was necessary to look at the history of condensate polishing. The feedwater quality requirements have become more stringent. To meet these quality requirements, it was essential to discuss the effect of condensate chemistry on resin performance and to realize that equipment damage may be traced to poor polisher performance. 4 refs.

  6. anionic ion exchangers: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    ions and water flow under the influence of gradients in hydrostatic pressure, ion chemical potential, and electrical potential (voltage), leading to solvent flow, ionic fluxes...

  7. Ion Exchange and Solvent Extraction: Supramolecular Aspects of Solvent Exchange Volume 21

    SciTech Connect (OSTI)

    Gloe, Karsten [Technischen Universität Dresden] [Technischen Universität Dresden; Tasker, Peter A [ORNL] [ORNL; Oshima, Tatsuya [University of Miyazaki] [University of Miyazaki; Watarai, Hitoshi [Institute for NanoScience Design at Osaka University] [Institute for NanoScience Design at Osaka University; Nilsson, Mikael [University of California, Irvine] [University of California, Irvine

    2013-01-01T23:59:59.000Z

    Preface The theme of supramolecular chemistry (SC), entailing the organization of multiple species through noncovalent interactions, has permeated virtually all aspects of chemical endeavor over the past several decades. Given that the observed behavior of discrete molecular species depends upon their weak interactions with one another and with matrix components, one would have to conclude that SC must indeed form part of the fabric of chemistry itself. A vast literature now serves to categorize SC phenomena within a body of consistent terminology. The word supramolecular itself appears in the titles of dozens of books, several journals, and a dedicated encyclopedia. Not surprisingly, the theme of SC also permeates the field of solvent extraction (SX), inspiring the framework for this volume of Ion Exchange and Solvent Extraction. It is attempted in the six chapters of this volume to identify both how supramolecular behavior occurs and is studied in the context of SX and how SC is influencing the current direction of SX. Researchers and practitioners have long dealt with supramolecular interactions in SX. Indeed, the use of polar extractant molecules in nonpolar media virtually assures that aggregative interactions will dominate the solution behavior of SX. Analytical chemists working in the 1930s to the 1950s with simple mono- and bidentate chelating ligands as extractants noted that extraction of metal ions obeyed complicated mass-action equilibria involving complex stoichiometries. As chemists and engineers developed processes for nuclear and hydrometallurgical applications in the 1950s and 1960s, the preference for aliphatic diluents only enhanced the complexity and supramolecular nature of extraction chemistry. Use of physical techniques such as light scattering and vapor-pressure measurements together with various spectroscopic methods revealed organic-phase aggregates from well-defined dimers to small aggregates containing a few extractant molecules to large inverse micelles swollen with water molecules. Extraction systems involving long-chain cations such as alkylammonium species or long-chain anions such as sulfonates or carboxylates proved especially prone to extensive aggregate formation. The related phenomenon of third-phase formation in SX systems, long misunderstood, is now yielding to spectroscopic and scattering techniques showing extensive long-range organization. Over the last 50 years, tools for studying the structure and thermodynamics of aggregation have grown increasingly sophisticated, leading to a rich and detailed understanding of what we can now recognize as SC phenomena in SX. In the 1970s and 1980s, the rapid growth of SC elicited a paradigm shift in SX. The influence of SC principles had two major effects on the course of SX research. First, it provided a framework for understanding the supramolecular behavior that was already well appreciated in the field of SX, though earlier without the SC terminology. Second, it provided the conceptual tools to control supramolecular behavior in SX, direct it for intended functionality, and to simplify it. Extraction by designed reagents has been steadily progressing ever since, with commercial applications emerging to successfully validate this approach. With the discovery of crown ethers in the late 1960s, the advancement of extractant design has fruitfully employed the concept of inclusion. While considerable initial progress occurred with such molecules, especially because of their affinity and selectivity for alkali and alkaline earth metals, other molecular platforms such as calixarenes have proven more versatile. Multidentate receptors for partial to full inclusion of cations, anions, ion pairs, as well as neutral species, have now become commonplace for selective extraction. This volume of Ion Exchange and Solvent Extraction examines how the principles of SC are being employed both in advancing the design of new highly selective SX systems and in understanding aggregation phenomena in SX systems. Chapter 1 discusses the nature and definition of SC

  8. Sorption of micropollutant estrone to a water treatment ion exchange resin 

    E-Print Network [OSTI]

    Neale, Peta A.; Mastrup, Maibritt; Borgmann, Thomas; Schäfer, Andrea

    2010-01-01T23:59:59.000Z

    Micropollutants occur in natural waters from a range of sources. Estrogenic compounds are naturally excreted by humans and hence stem predominantly from wastewater effluents. Due to the small size and concentration of ...

  9. Applications of Highly Cross Linked Mixed Bed Ion Exchange Resins in Biodiesel Processing

    E-Print Network [OSTI]

    Jamal, Yousuf

    2010-10-12T23:59:59.000Z

    Biofuels are a promising solution to society's quest for sustainable energy. In the transportation sector, biodiesel is the leading alternative diesel fuel currently in use today. However, the current global and domestic production of biodiesel...

  10. Ion exchange behavior among metal trisilicates: probing selectivity, structures, and mechanism

    E-Print Network [OSTI]

    Fewox, Christopher Sean

    2008-10-10T23:59:59.000Z

    in the clean up process. By separating high activity isotopes and other actinides waste can be segregated and processed according to contamination threat, isotope half-life, and activity. Cesium-137 and Strontium-90 are found in fission products and pose... and other actinides but is inefficient for the separation of strontium. 1.2. Previously studied inorganic ion exchange materials One of the first inorganic ion exchange materials extensively studied for waste remediation was sodium nonatitanate (SNT...

  11. Ion-exchange material and method of storing radioactive wastes

    DOE Patents [OSTI]

    Komarneni, S.; Roy, D.M.

    1983-10-31T23:59:59.000Z

    A new cation exchanger is a modified tobermorite containing aluminum isomorphously substituted for silicon and containing sodium or potassium. The exchanger is selective for lead, rubidium, cobalt, and cadmium and is selective for cesium over calcium or sodium. The tobermorites are compatible with cement and are useful for the long-term fixation and storage of radioactive nuclear wastes.

  12. ROTARY FILTER FINES TESTING FOR SMALL COLUMN ION EXCHANGE

    SciTech Connect (OSTI)

    Herman, D.

    2011-08-03T23:59:59.000Z

    SRNL was requested to quantify the amount of 'fines passage' through the 0.5 micron membranes currently used for the rotary microfilter (RMF). Testing was also completed to determine if there is any additional benefit to utilizing a 0.1 micron filter to reduce the amount of fines that could pass through the filter. Quantifying of the amount of fines that passed through the two sets of membranes that were tested was accomplished by analyzing the filtrate by Inductively Coupled Plasma Atomic Emission Spectrometry (ICP-AES) for titanium. Even with preparations to isolate the titanium, all samples returned results of less than the instrument's detection limit of 0.184 mg/L. Test results show that the 0.5 micron filters produced a significantly higher flux while showing a negligible difference in filtrate clarity measured by turbidity. The first targeted deployment of the RMF is with the Small Column Ion Exchange (SCIX) at the Savannah River Site (SRS). SCIX uses crystalline silicotitanate (CST) to sorb cesium to decontaminate a clarified salt solution. The passage of fine particles through the filter membranes in sufficient quantities has the potential to impact the downstream facilities. To determine the amount of fines passage, a contract was established with SpinTek Filtration to operate a 3-disk pilot scale unit with prototypic filter disk and various feeds and two different filter disk membranes. SpinTek evaluated a set of the baseline 0.5 micron filter disks as well as a set of 0.1 micron filter disks to determine the amount of fine particles that would pass the membrane and to determine the flux each set produced. The membrane on both disk sets is manufactured by the Pall Corporation (PMM 050). Each set of disks was run with three feed combinations: prototypically ground CST, CST plus monosodium titanate (MST), and CST, MST, plus Sludge Batch 6 (SB6) simulant. Throughout the testing, samples of the filtrate were collected, measured for turbidity, and sent back to SRNL for analysis to quantify the amount of fines that passed through the membrane. It should be noted that even though ground CST was tested, it will be transferred to the Defense Waste Processing Facility (DWPF) feed tank and is not expected to require filtration.

  13. Magnetic properties of cobalt-ferrite nanoparticles embedded in polystyrene resin

    E-Print Network [OSTI]

    Boolchand, Punit

    Magnetic properties of cobalt-ferrite nanoparticles embedded in polystyrene resin P. P. Vaishnava online 20 April 2006 Samples of maghemite and cobalt-ferrite nanoparticles sizes, 3­10 nm were prepared.6­8 How- ever, the ion-exchange method can also produce nanopar- ticles of ferrites and other

  14. Fire Safety Tests for Spherical Resorcinol Formaldehyde Resin: Data Summary Report

    SciTech Connect (OSTI)

    Kim, Dong-Sang; Peterson, Reid A.; Schweiger, Michael J.

    2012-07-30T23:59:59.000Z

    A draft safety evaluation of the scenario for spherical resorcinol-formaldehyde (SRF) resin fire inside the ion exchange column was performed by the Hanford Tank Waste Treatment and Immobilization Plant (WTP) Fire Safety organization. The result of this draft evaluation suggested a potential change of the fire safety classification for the Cesium Ion Exchange Process System (CXP) emergency elution vessels, equipment, and piping, which may be overly bounding based on the fire performance data from the manufacturer of the ion exchange resin selected for use at the WTP. To resolve this question, the fire properties of the SRF resin were measured by Southwest Research Institute (SwRI), following the American Society for Testing and Materials (ASTM) standard procedures, through a subcontract managed by Pacific Northwest National Laboratory (PNNL). For some tests, the ASTM standard procedures were not entirely appropriate or practical for the SRF resin material, so the procedures were modified and deviations from the ASTM standard procedures were noted. This report summarizes the results of fire safety tests performed and reported by SwRI. The efforts by PNNL were limited to summarizing the test results provided by SwRI into one consolidated data report. All as-received SwRI reports are attached to this report in the Appendix. Where applicable, the precision and bias of each test method, as given by each ASTM standard procedure, are included and compared with the SwRI test results of the SRF resin.

  15. Preparation of catalysts via ion-exchangeable coatings on supports

    DOE Patents [OSTI]

    Dosch, R.G.; Stephens, H.P.

    1986-04-09T23:59:59.000Z

    Disclosed are: new catalytic compositions which comprise an inert support coated with a hydrous alkali metal, alkaline earth metal, or quaternary ammonium titanate, niobate, zirconate, or tantalate, in which the alkali or alkaline earth metal or quaternary ammonium cations have been exchanged for a catalytically effective quantity of a catalytically effective metal.

  16. Improved hydrous oxide ion-exchange compound catalysts

    DOE Patents [OSTI]

    Dosch, R.G.; Stephens, H.P.

    1986-04-09T23:59:59.000Z

    Disclosed is a catalytic material of improved activity which comprises a hydrous, alkali metal or alkaline earth metal or quaternary ammonium titanate, zirconate, niobate, or tantalate, in which the metal or ammonium cations have been exchanged with a catalytically effective quantity of a catalyst metal, and which has been subsequently treated with a solution of a Bronsted acid.

  17. Nuclear quantum effects in water exchange around lithium and fluoride ions

    E-Print Network [OSTI]

    Wilkins, David M; Dang, Liem X

    2015-01-01T23:59:59.000Z

    We employ classical and ring polymer molecular dynamics simulations to study the effect of nuclear quantum fluctuations on the structure and the water exchange dynamics of aqueous solutions of lithium and fluoride ions. While we obtain reasonably good agreement with experimental data for solutions of lithium by augmenting the Coulombic interactions between the ion and the water molecules with a standard Lennard-Jones ion-oxygen potential, the same is not true for solutions of fluoride, for which we find that a potential with a softer repulsive wall gives much better agreement. A small degree of destabilization of the first hydration shell is found in quantum simulations of both ions when compared with classical simulations, with the shell becoming less sharply defined and the mean residence time of the water molecules in the shell decreasing. In line with these modest differences, we find that the mechanisms of the exchange processes are unaffected by quantization, so a classical description of these reaction...

  18. High-resolution determination of {sup 147}Pm in urine using dynamic ion-exchange chromatography

    SciTech Connect (OSTI)

    Elchuk, S.; Lucy, C.A.; Burns, K.I. [Chalk River Labs., Ontario (Canada)

    1992-10-15T23:59:59.000Z

    Ion exchange preconcentration followed by HPLC purification prior to scintillation counting was used to measure the concentration of {sup 147}Pm in urine. the detection limit for this method was found to be 0.1 Bq (3 fg) of {sup 147}Pm in 500 ml of urine.

  19. Nonlinear inverse problem for a model of ion-exchange filter: numerical recovery of parameters

    E-Print Network [OSTI]

    ) and pressure (15 MPa) of hot steam [2]. Some units are made of cheap corrosion and heat-resistant steel which1 Nonlinear inverse problem for a model of ion-exchange filter: numerical recovery of parameters]. Power-generating units of TPP operate under severe corrosive conditions: high temperature (515 - 530°C

  20. A new class of non-zeolitic sorbents for air separations: Lithium ion exchanged pillared clays

    SciTech Connect (OSTI)

    Cheng, L.S.; Yang, R.T. [State Univ. of New York, Buffalo, NY (United States). Dept. of Chemical Engineering

    1995-06-01T23:59:59.000Z

    Zeolites are the only known sorbents that adsorb N{sub 2} selectively over O{sub 2}, and are used for industrial air separation. Pillared clays (PILCs) have a high Broensted acidity (k.e., high proton density). It is found in this study that when the protons are exchanged by alkali metal ions, in particular Li{sup +}, the ion exchanged pillared clays can exhibit a high N{sub 2}/O{sub 2} adsorption selectivity that rivals that of the zeolites. The first result shows a pure-component adsorption ratio of N{sub 2}/O{sub 2} = 3.2 (at 25 C and 1 atm) for Li{sup +}-exchanged PILC. The N{sub 2} capacity, however, is only 20% that of the zeolite, and remains to be improved. A systematic investigation is conducted on the effects of three factors on the N{sub 2}/O{sub 2} selectivity: (1) starting clays (tetrahedral vs octahedral isomorphous substitution and clays with different charge densities), (2) different metal oxides as pillars, and (3) different ion exchange alkali metal cations (Li{sup +}, Na{sup +}, K{sup +}, Rb{sup +}, and Cs{sup +}). The highest N{sub 2}/O{sub 2} selectivities are achieved by using clays with the highest charge densities, metal oxides forming pillars with the narrowest gallery spaces, and ion exchange cations with the smallest ionic radii. Effects by all three factors are qualitatively understood. The high N{sub 2}/O{sub 2} selectivity on the Li{sup +} exchanged PILC is the result of the small ionic radius (and hence high polarizing power) of Li{sup +} and the strong quadrupole moment of the N{sub 2} molecule. Moreover, a technique is developed with which the amount of the exchanged cations can exceed that allowed by the original cation exchange capacity of the clay by using a high pH value in the ion exchange solution.

  1. Determination of platinum and palladium in geologic samples by ion exchange chromatography with inductively coupled plasma atomic emission spectrometric detection

    SciTech Connect (OSTI)

    Brown, R.J.; Biggs, W.R.

    1984-04-01T23:59:59.000Z

    An alternative procedure to the classical fire assay method for determining Pt and Pd in sulfide ores, concentrates, and furnace mattes is presented. A suitable amount of sample is digested with aqua regla and filtered and any remaining gangue is digested with a mixture of HF and HClO/sub 4/. The solution is filtered and the residue fused with sodium peroxide granules. The fused salts are dissolved in a dilute HCl acid solution and all three solutions combined. The resultant solution is passed through a Bio-Rad AG 50W-X8 cation exchange resin in the H/sup +/ form. The chlorocomplex anions of Pt and Pd are not retained by the cation exchange resin while the base metal cations are efficiently removed from the eluent. Pt and Pd concentrations are subsequently determined with an inductively coupled plasma (ICP). Preliminary experiments showing the method's potential expandability to Au are included.

  2. A photodiode-based neutral particle bolometer for characterizing charge-exchanged fast-ion behavior

    SciTech Connect (OSTI)

    Clary, R.; Smirnov, A.; Dettrick, S.; Knapp, K.; Korepanov, S.; Ruskov, E. [Tri Alpha Energy, Inc., Rancho Santa Margarita, California 92688 (United States); Heidbrink, W. W.; Zhu, Y. [University of California-Irvine, Irvine, California 92697 (United States)

    2012-10-15T23:59:59.000Z

    A neutral particle bolometer (NPB) has been designed and implemented on Tri Alpha Energy's C-2 device in order to spatially and temporally resolve the charge-exchange losses of fast-ion populations originating from neutral beam injection into field-reversed configuration plasmas. This instrument employs a silicon photodiode as the detection device with an integrated tungsten filter coating to reduce sensitivity to light radiation. Here we discuss the technical aspects and calibration of the NPB, and report typical NPB measurement results of wall recycling effects on fast-ion losses.

  3. Safety Evaluation for Packaging for onsite Transfer of plutonium recycle test reactor ion exchange columns

    SciTech Connect (OSTI)

    Smith, R.J.

    1995-09-11T23:59:59.000Z

    The purpose of this Safety Evaluation for Packaging (SEP) is to authorize the use of three U.S. Department of Transportation (DOT) 7A, Type A metal boxes (Capital Industries Part No. S 0600-0600-1080- 0104) to package 12 Plutonium Recycle Test Reactor (PRTR) ion exchange columns as low-level waste (LLW). The packages will be transferred from the 309 Building in the 300 Area to low level waste burial in the 200 West Area. Revision 1 of WHC-SD-TP-SEP-035 (per ECN No. 621467) documents that the boxes containing ion exchange columns and grout will maintain the payload under normal conditions of transport if transferred without the box lids

  4. Solar Wind Charge Exchange Studies of Highly Charged Ions on Atomic Hydrogen

    SciTech Connect (OSTI)

    Draganic, Ilija N [ORNL; Seely, D. G. [Albion College; McCammon, D [University of Wisconsin, Madison; Havener, Charles C [ORNL

    2011-01-01T23:59:59.000Z

    Accurate studies of low energy charge exchange (CX) are critical to understanding underlying soft X ray radiation processes in the interaction of highly charged ions from the solar wind with the neutral atoms and molecules in the heliosphere, cometary comas, planetary atmospheres, interstellar winds, etc.. Particularly important are the CX cross sections for bare, H like, and He like ions of C, N, O and Ne, which are the dominant charge states for these heavier elements in the solar wind. Absolute total cross sections for single electron capture by H like ions of C, N, O and fully stripped O ions from atomic hydrogen have been measured in an expanded range of relative collision energies (5 eV u 20 keV u) and compared to previous H oven measurements. The present measurements are performed using a merged beams technique with intense highly charged ion beams extracted from a 14.5 GHz ECR ion source installed on a high voltage platform at the Oak Ridge National Laboratory. For the collision energy range of 0.3 keV u 3.3 keV u, which corresponds to typical ion velocities in the solar wind, the new measurements are in good agreement with previous H oven measurements. The experimental results are discussed in detail and compared with theoretical calculations where available.

  5. Solar Wind Charge Exchange Studies Of Highly Charged Ions On Atomic Hydrogen

    SciTech Connect (OSTI)

    Draganic, I. N.; Havener, C. C. [Physics Division, Oak Ridge National Laboratory, Oak Ridge, TN 37831 (United States); Seely, D. G. [Department of Physics, Albion College, Albion, MI 49224 (United States); McCammon, D. [Department of Physics, University of Wisconsin, Madison, WI 53706 (United States)

    2011-06-01T23:59:59.000Z

    Accurate studies of low-energy charge exchange (CX) are critical to understanding underlying soft X-ray radiation processes in the interaction of highly charged ions from the solar wind with the neutral atoms and molecules in the heliosphere, cometary comas, planetary atmospheres, interstellar winds, etc.. Particularly important are the CX cross sections for bare, H-like, and He-like ions of C, N, O and Ne, which are the dominant charge states for these heavier elements in the solar wind. Absolute total cross sections for single electron capture by H-like ions of C, N, O and fully-stripped O ions from atomic hydrogen have been measured in an expanded range of relative collision energies (5 eV/u-20 keV/u) and compared to previous H-oven measurements. The present measurements are performed using a merged-beams technique with intense highly charged ion beams extracted from a 14.5 GHz ECR ion source installed on a high voltage platform at the Oak Ridge National Laboratory. For the collision energy range of 0.3 keV/u-3.3 keV/u, which corresponds to typical ion velocities in the solar wind, the new measurements are in good agreement with previous H-oven measurements. The experimental results are discussed in detail and compared with theoretical calculations where available.

  6. Perchlorate Degradation Using Partially Oxidized Titanium Ions and Ion Exchange Membrane Hybrid System

    E-Print Network [OSTI]

    Park, Sung Hyuk

    2011-08-08T23:59:59.000Z

    Perchlorate has entered human and environmental food chains and has received a great deal of attention because of its toxicity to humans. In this study, chemical degradation of perchlorate was investigated using partially oxidized titanium ions (Ti2...

  7. Fire Safety Tests for Cesium-Loaded Spherical Resorcinol Formaldehyde Resin: Data Summary Report

    SciTech Connect (OSTI)

    Kim, Dong-Sang; Schweiger, Michael J.; Peterson, Reid A.

    2012-09-01T23:59:59.000Z

    A draft safety evaluation of the scenario for spherical resorcinol formaldehyde (SRF) resin fire inside the ion exchange column was performed by the Hanford Tank Waste Treatment and Immobilization Plant (WTP) Fire Safety organization. The result of this draft evaluation suggested a potential change of the fire safety classification for the Cesium Ion Exchange Process System (CXP) emergency elution vessels, equipment, and piping. To resolve this question, the fire properties of the SRF resin were measured by Southwest Research Institute (SwRI) through a subcontract managed by Pacific Northwest National Laboratory (PNNL). The results of initial fire safety tests on the SRF resin were documented in a previous report (WTP-RPT-218). The present report summarizes the results of additional tests performed by SwRI on the cesium-loaded SRF resin. The efforts by PNNL were limited to summarizing the test results provided by SwRI into one consolidated data report. The as-received SwRI report is attached to this report in the Appendix A. Where applicable, the precision and bias of each test method, as given by each American Society for Testing and Materials (ASTM) standard procedure, are included and compared with the SwRI test results of the cesium-loaded SRF resin.

  8. Vehicle Technologies Office Merit Review 2015: Ion-Exchanged Derived Cathodes (IE-LL_NCM) for High Energy Density LIBs

    Broader source: Energy.gov [DOE]

    Presentation given by Argonne National Laboratory at 2015 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about ion-exchanged...

  9. Ion exchange columns for selective removal of cesium from aqueous radioactive waste using hydrous crystalline silico-titanates

    E-Print Network [OSTI]

    Ricci, David Michael

    1995-01-01T23:59:59.000Z

    conscious society. In Hanford, WA, hundreds of underground storage tanks hold tens of millions of gallons of aqueous radioactive waste. This liquid waste, which has a very high sodium content, contains trace amounts of radioactive cesium 137. Since... the material for batch ion exchange of the nuclear waste solution. More research was needed to investigate the material's effectiveness in a column operation. An ion exchange column system was developed to study column performance. The column design...

  10. Modulated active charge exchange fast ion diagnostic for the C-2 field-reversed configuration experiment

    SciTech Connect (OSTI)

    Korepanov, S.; Smirnov, A.; Clary, R.; Dettrick, S. [Tri Alpha Energy, Inc., Rancho Santa Margarita, California 92688 (United States); Deichuli, P.; Kondakov, A.; Murakhtin, S. [Budker Institute of Nuclear Physics, Novosibirsk (Russian Federation)

    2012-10-15T23:59:59.000Z

    A diagnostic technique for measuring the fast-ion energy distribution in a field-reversed configuration plasma was developed and tested on the C-2 experiment. A deuterium neutral beam modulated at 22 kHz is injected into the plasma, producing a localized charge-exchange target for the confined fast protons. The escaping fast neutrals are detected by a neutral particle analyzer. The target beam transverse size ({approx}15 cm) defines the spatial resolution of the method. The equivalent current density of the target beam is {<=}0.15 A/cm{sup 2}, which corresponds to a neutral density ({approx}6 Multiplication-Sign 10{sup 9} cm{sup -3}) that highly exceeds the background neutral density in the core of C-2. The deuterium fast-ions due to the target beam (E{approx}27 keV), are not confined in C-2 and thus make a negligible contribution to the measured signals.

  11. Exchange bias in polycrystalline magnetite films made by ion-beam assisted deposition

    SciTech Connect (OSTI)

    Kaur, Maninder; Qiang, You [Department of Physics, University of Idaho, Moscow, Idaho 83844 (United States); Jiang, Weilin [Pacific Northwest National Laboratory, Richland, Washington 99352 (United States); Burks, Edward C.; Liu, Kai [Department of Physics, University of California, Davis, California 95616 (United States); Namavar, Fereydoon [University of Nebraska Medical Center, Omaha, Nebraska 68198 (United States); McCloy, John S. [Pacific Northwest National Laboratory, Richland, Washington 99352 (United States); School of Mechanical and Materials Engineering, Washington State University, Pullman, Washington 98163 (United States)

    2014-11-07T23:59:59.000Z

    Iron oxide films were produced using ion-beam-assisted deposition, and Raman spectroscopy and x-ray diffraction indicate single-phase magnetite. However, incorporation of significant fractions of argon in the films from ion bombardment is evident from chemical analysis, and Fe/O ratios are lower than expected from pure magnetite, suggesting greater than normal disorder. Low temperature magnetometry and first-order reversal curve measurements show strong exchange bias, which likely arises from defects at grain boundaries, possibly amorphous, creating frustrated spins. Since these samples contain grains ?6?nm, a large fraction of the material consists of grain boundaries, where spins are highly disordered and reverse independently with external field.

  12. The removal of uranium from acidic media using ion exchange and/or extraction chromatography

    SciTech Connect (OSTI)

    FitzPatrick, J.R.; Schake, B.S.; Murphy, J.; Holmes, K; West, M.H.

    1996-06-01T23:59:59.000Z

    The separation and purification of uranium from either nitric acid or hydrochloric acid media can be accomplished by using either solvent extraction or ion-exchange. Over the past two years at Los Alamos, emerging programs are focused on recapturing the expertise required to do limited, small-quantity processing of enriched uranium. During this period of time, we have been investigating ion-addition, waste stream polishing is associated with this effort in order to achieve more complete removal of uranium prior to recycle of the acid. Extraction chromatography has been demonstrated to further polish the uranium from both nitric and hydrochloric acid media thus allowing for a more complete recovery of the actinide material and creation of less waste during the processing steps.

  13. Use of Novel Highly Selective Ion Exchange Media for Minimizing the Waste Arising from Different NPP and Other Liquids

    SciTech Connect (OSTI)

    Tusa, Esko; Harjula, Risto; Lehto, Jukka

    2003-02-25T23:59:59.000Z

    Highly selective inorganic ion exchangers give new possibilities to implement and operate new innovative treatment systems for radioactive liquids. Because of high selectivity these ion exchangers can be used even in liquids of high salt concentrations. Only selected target nuclides will be separated and inactive salts are left in the liquid, which can be released or recategorized. Thus, it is possible to reduce the volume of radioactive waste dramatically. On the other hand, only a small volume of highly selective material is required in applications, which makes it possible to design totally new types of compact treatment systems. The major benefit of selective ion exchange media comes from the very large volume reduction of radioactive waste in final disposal. It is also possible to save in investment costs, because small ion exchanger volumes can be used and handled in a very small facility. This paper describes different applications of these highly selective ion exchangers, both commercial fullscale applications and laboratory tests, to give the idea of their efficiency for different liquids.

  14. Alternate Methods for Eluting Cesium from Spherical Resorcinol-Formaldehyde Resin

    SciTech Connect (OSTI)

    Taylor, Paul Allen [ORNL; Johnson, Heather Lauren [University of Tennessee, Knoxville (UTK)

    2009-02-01T23:59:59.000Z

    A small-column ion exchange (SCIX) system has been proposed for removing cesium from the supernate and dissolved salt solutions in the high-level-waste tanks at the Savannah River Site (SRS). The SCIX system could use either crystalline silicotitanate (CST), an inorganic, non-regenerable sorbent, or spherical resorcinol-formaldehyde (RF), a new regenerable resin, to remove cesium from the waste solutions. The baseline method for eluting the cesium from the RF resin uses 15 bed volumes (BV) of 0.5 M nitric acid (HNO{sub 3}). The nitric acid eluate, containing the radioactive cesium, would be combined with the sludge from the waste tanks and would be converted into glass at the Defense Waste Processing Facility (DWPF) at SRS. The amount of nitric acid that would be used to elute the RF resin, using the current elution protocol, exceeds the capacity of DWPF to destroy the nitrate ions and maintain the required chemical reducing environment in the glass melt. Installing a denitration evaporator at SRS is technically feasible but would add considerable cost to the project. Alternate methods for eluting the resin have been tested, including using lower concentrations of nitric acid, other acids, and changing the flow regimes. About 4 BV of 0.5 M HNO{sub 3} are required to remove the sodium (titrate the resin) and most of the cesium from the resin, so the bulk of the acid used for the baseline elution method removes a very small quantity of cesium from the resin. A summary of the elution methods that have been tested are listed.

  15. THERMAL MODELING ANALYSIS OF CST MEDIA IN THE SMALL COLUMN ION EXCHANGE PROJECT

    SciTech Connect (OSTI)

    Lee, S.

    2010-11-01T23:59:59.000Z

    Models have been developed to simulate the thermal characteristics of Crystalline Silicotitanate (CST) ion exchange media fully loaded with radioactive cesium in a column configuration and distributed within a waste storage tank. This work was conducted to support the Small Column Ion Exchange (SCIX) program which is focused on processing dissolved, high-sodium salt waste for the removal of specific radionuclides (including Cs-137, Sr-90, and actinides) within a High Level Waste (HLW) storage tank at the Savannah River Site. The SCIX design includes CST columns inserted and supported in the tank top risers for cesium removal. Temperature distributions and maximum temperatures across the column were calculated with a focus on process upset conditions. A two-dimensional computational modeling approach for the in-column ion-exchange domain was taken to include conservative, bounding estimates for key parameters such that the results would provide the maximum centerline temperatures achievable under the design configurations using a feed composition known to promote high cesium loading on CST. One salt processing scenario includes the transport of the loaded (and possibly ground) CST media to the treatment tank floor. Therefore, additional thermal modeling calculations were conducted using a three-dimensional approach to evaluate temperature distributions for the entire in-tank domain including distribution of the spent CST media either as a mound or a flat layer on the tank floor. These calculations included mixtures of CST with HLW sludge or loaded Monosodium Titanate (MST) media used for strontium/actinide sorption. The current full-scale design for the CST column includes one central cooling pipe and four outer cooling tubes. Most calculations assumed that the fluid within the column was stagnant (i.e. no buoyancy-induced flow) for a conservative estimate. A primary objective of these calculations was to estimate temperature distributions across packed CST beds immersed in waste supernate or filled with dry air under various accident scenarios. Accident scenarios evaluated included loss of salt solution flow through the bed (a primary heat transfer mechanism), inadvertent column drainage, and loss of active cooling in the column. The calculation results showed that for a wet CST column with active cooling through one central and four outer tubes and 35 C ambient external air, the peak temperature for the fully-loaded column is about 63 C under the loss of fluid flow accident, which is well below the supernate boiling point. The peak temperature for the naturally-cooled (no active, engineered cooling) wet column is 156 C under fully-loaded conditions, exceeding the 130 C boiling point. Under these conditions, supernate boiling would maintain the column temperature near 130 C until all supernate was vaporized. Without active engineered cooling and assuming a dry column suspended in unventilated air at 35 C, the fully-loaded column is expected to rise to a maximum of about 258 C due to the combined loss-of coolant and column drainage accidents. The modeling results demonstrate that the baseline design using one central and four outer cooling tubes provides a highly efficient cooling mechanism for reducing the maximum column temperature. Results for the in-tank modeling calculations clearly indicate that when realistic heat transfer boundary conditions are imposed on the bottom surface of the tank wall, as much as 450 gallons of ground CST (a volume equivalent to two ion exchange processing cycles) in an ideal hemispherical shape (the most conservative geometry) can be placed in the tank without exceeding the 100 C wall temperature limit. Furthermore, in the case of an evenly-distributed flat layer, the tank wall reaches the temperature limit after the ground CST material reaches a height of approximately 8 inches.

  16. Standard practice for The separation of americium from plutonium by ion exchange

    E-Print Network [OSTI]

    American Society for Testing and Materials. Philadelphia

    2001-01-01T23:59:59.000Z

    1.1 This practice describes the use of an ion exchange technique to separate plutonium from solutions containing low concentrations of americium prior to measurement of the 241Am by gamma counting. 1.2 This practice covers the removal of plutonium, but not all the other radioactive isotopes that may interfere in the determination of 241Am. 1.3 This practice can be used when 241Am is to be determined in samples in which the plutonium is in the form of metal, oxide, or other solid provided that the solid is appropriately sampled and dissolved (See Test Methods C758, C759, and C1168). 1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

  17. DATA QUALITY OBJECTIVE SUMMARY REPORT FOR THE 105 K EAST ION EXCHANGE COLUMN MONOLITH

    SciTech Connect (OSTI)

    JOCHEN, R.M.

    2007-08-02T23:59:59.000Z

    The 105-K East (KE) Basin Ion Exchange Column (IXC) cells, lead caves, and the surrounding vault are to be removed as necessary components in implementing ''Hanford Federal Facility Agreement and Consent Order'' (Ecology et al. 2003) milestone M-034-32 (Complete Removal of the K East Basin Structure). The IXCs consist of six units located in the KE Basin, three in operating positions in cells and three stored in a lead cave. Methods to remove the IXCs from the KE Basin were evaluated in KBC-28343, ''Disposal of K East Basin Ion Exchange Column Evaluation''. The method selected for removal was grouting the six IXCs into a single monolith for disposal at the Environmental Restoration Disposal Facility (ERDF). Grout will be added to the IXC cells, IXC lead caves containing spent IXCs, and in the spaces between the lead cave walls and metal skin, to immobilize the contaminants, provide self-shielding, minimize void space, and provide a structurally stable waste form. The waste to be offered for disposal is the encapsulated monolith defined by the exterior surfaces of the vault and the lower surface of the underlying slab. This document presents summary of the data quality objective (DQO) process establishing the decisions and data required to support decision-making activities for the disposition of the IXC monolith. The DQO process is completed in accordance with the seven-step planning process described in EPA QA/G-4, ''Guidance for the Data Quality Objectives Process'', which is used to clarify and study objectives; define the appropriate type, quantity, and quality of data; and support defensible decision-making. The DQO process involves the following steps: (1) state the problem; (2) identify the decision; (3) identify the inputs to the decision; (4) define the boundaries of the study; (5) develop a decision rule (DR); (6) specify tolerable limits on decision errors; and (7) optimize the design for obtaining data.

  18. DATA QUALITY OBJECTIVES SUMMARY REPORT FOR THE 105K EAST BASIN ION EXCHANGE COLUMN MONOLITH

    SciTech Connect (OSTI)

    JOCHEN, R.M.

    2007-02-07T23:59:59.000Z

    The 105-K East (KE) Basin Ion Exchange Column (IXC) cells, lead caves, and the surrounding vault are to be removed as necessary components in implementing ''Hanford Federal Facility Agreement and Consert Order'' (Ecology et al. 2003) milestone M-034-32 (Complete Removal of the K East Basin Structure). The IXCs consist of six units located in the KE Basin, three in operating positions in cells and three stored in a lead cave. Methods to remove the IXCs from the KE Basin were evaluated in KBC-28343, ''Disposal of K East Basin Ion Exchange Column Evaluation''. The method selected for removal was grouting of the six IXCs into a single monolith for disposal at the Environmental Restoration Disposal Facility (ERDF). Grout will be added to the IXC cells, IXC lead caves containing spent IXCs, and in the spaces between to immobilize the contaminants, provide self-shielding, minimize void space, and provide a structurally stable waste form. The waste to be offered for disposal is the encapsulated monolith defined by the exterior surfaces of the vault and the lower surface of the underlying slab. This document presents a summary of the data quality objective (DQO) process establishing the decisions and data required to support decision-making activities for disposition of the IXC monolith. The DQO process is completed in accordance with the seven-step planning process described in EPA QA/G-4, ''Guidance for the Data Quality Objectives Process'', which is used to clarify and study objectives; define the appropriate type, quantity, and quality of data; and support defensible decision-making. The DQO process involves the following steps: (1) state the problem; (2) identify the decision; (3) identify the inputs to the decision; (4) define the boundaries of the study; (5) develop a decision rule (DR); (6) specify tolerable limits on decision errors; and (7) optimize the design for obtaining data.

  19. Formation and structural characterization of potassium titanates and the potassium ion exchange property

    SciTech Connect (OSTI)

    Wang Qiang, E-mail: wulihe@postech.ac.kr [Department of Catalysis Science and Engineering, School of Chemical Engineering and Technology, Harbin Institute of Technology, Harbin, Heilongjiang, 150001 (China); School of Environmental Science and Engineering, POSTECH, San 31, Hyoja-Dong, Nam-gu, Pohang 790-784 (Korea, Republic of); Guo Zhanhu [Integrated Composites Laboratory (ICL), Dan F. Smith Department of Chemical Engineering, Lamar University, Beaumont, TX 77710 (United States); Chung, Jong Shik [School of Environmental Science and Engineering, POSTECH, San 31, Hyoja-Dong, Nam-gu, Pohang 790-784 (Korea, Republic of); Department of Chemical Engineering, POSTECH, San 31, Hyoja-Dong, Nam-gu, Pohang 790-784 (Korea, Republic of)

    2009-10-15T23:59:59.000Z

    In the present work, K{sub 2}Ti{sub 2}O{sub 5}, K{sub 2}Ti{sub 4}O{sub 9} and K{sub 2}Ti{sub 6}O{sub 13} are synthesized by solid state method. Their structures and morphologies are characterized by X-ray diffraction, Raman spectra and scanning electron microscopy. The binding energies of K, Ti and O in potassium titanates were then evaluated by X-ray photoelectron spectroscopy and compared with those in K/TiO{sub 2}. Finally the corresponding K ion exchange properties are investigated by synthesizing NO oxidation catalysts with Co(NO{sub 3}){sub 2} precursor. It is found that the binding energy of K in K{sub 2}Ti{sub 2}O{sub 5} is much higher than those in K{sub 2}Ti{sub 4}O{sub 9} and K{sub 2}Ti{sub 6}O{sub 13}, and because of which, it shows quite different catalytic performances. Compared with other potassium titanates, the K in K{sub 2}Ti{sub 2}O{sub 5} is much easier to be exchanged out.

  20. Kinetics of Ion Exchange on Clay Minerals and Soil: II. Elucidation of Rate-limiting Steps1 R. A. OGWADA ANDD. L. SPARKS2

    E-Print Network [OSTI]

    Sparks, Donald L.

    Kinetics of Ion Exchange on Clay Minerals and Soil: II. Elucidation of Rate-limiting Steps1 R. A of this study was to elucidate the rate- limiting steps for K+ adsorption on the clay minerals and soil. We.L. Sparks. 1986. Kinetics of ion exchange on clay minerals and soil: II. Elucidation of rate-limiting steps

  1. Proton and light ion induced charge exchange reactions in nuclei This article has been downloaded from IOPscience. Please scroll down to see the full text article.

    E-Print Network [OSTI]

    Fernández de Córdoba, Pedro

    Proton and light ion induced charge exchange reactions in nuclei This article has been downloaded Scripta. Vol. 48, 101-104, 1993 Proton and Light Ion Induced Charge Exchange Reactions in Nuclei E. Oset of strength from the proton to the deu- teron targets and an even more remarkable shift of the strength

  2. Novel Hybrid Materials with High Stability for Electrically Switched Ion Exchange: Carbon Nanotubes/Polyaniline/Nickel Hexacyanoferrate Nanocomposites

    SciTech Connect (OSTI)

    Lin, Yuehe; Cui, Xiaoli

    2005-04-21T23:59:59.000Z

    A novel and stable carbon nanotubes /polyaniline /nickel hexacyanoferrates composite film has been synthesized with electrodeposition method, and the possibility for removing cesium through an electrically switched ion exchange has been evaluated in a mixture containing NaNO3 and CsNO3.

  3. Light-assisted ion-neutral reactive processes in the cold regime: radiative molecule formation vs. charge exchange

    E-Print Network [OSTI]

    Hall, Felix H J; Bouloufa, Nadia; Dulieu, Olivier; Willitsch, Stefan

    2011-01-01T23:59:59.000Z

    We present a combined experimental and theoretical study of cold reactive collisions between laser-cooled Ca+ ions and Rb atoms in an ion-atom hybrid trap. We observe rich chemical dynamics consisting of a complex interplay between non-adiabatic and radiative charge exchange as well as radiative molecule formation which are interpreted using high-level electronic structure calculations. We study the role of light-assisted processes and show that the efficiency of the dominant chemical pathways is considerably enhanced in excited reaction channels. Our results point to a general framework of radiative and non-radiative processes dominating the cold chemistry in ion-atom hybrid traps.

  4. Anionic Gallium-Based Metal;#8722;Organic Framework and Its Sorption and Ion-Exchange Properties

    SciTech Connect (OSTI)

    Banerjee, Debasis; Kim, Sun Jin; Wu, Haohan; Xu, Wenqian; Borkowski, Lauren A.; Li, Jing; Parise, John B. (Kwangju); (Rutgers); (SBU)

    2012-04-30T23:59:59.000Z

    A gallium-based metal-organic framework Ga{sub 6}(C{sub 9}H{sub 3}O{sub 6}){sub 8} {center_dot} (C{sub 2}H{sub 8}N){sub 6}(C{sub 3}H{sub 7}NO){sub 3}(H{sub 2}O){sub 26} [1, Ga{sub 6}(1,3,5-BTC){sub 8} {center_dot} 6DMA {center_dot} 3DMF {center_dot} 26H{sub 2}O], GaMOF-1; BTC = benzenetricarboxylate/trimesic acid and DMA = dimethylamine, with space group I{bar 4}3d, a = 19.611(1) {angstrom}, and V = 7953.4(6) {angstrom}{sup 3}, was synthesized using solvothermal techniques and characterized by synchrotron-based X-ray microcrystal diffraction. Compound 1 contains isolated gallium tetrahedra connected by the organic linker (BTC) forming a 3,4-connected anionic porous network. Disordered positively charged ions and solvent molecules are present in the pore, compensating for the negative charge of the framework. These positively charged molecules could be exchanged with alkali-metal ions, as is evident by an ICP-MS study. The H{sub 2} storage capacity of the parent framework is moderate with a H{sub 2} storage capacity of {approx}0.5 wt % at 77 K and 1 atm.

  5. STUDIES OF X-RAY PRODUCTION FOLLOWING CHARGE EXCHANGE RECOMBINATION BETWEEN HIGHLY CHARGED IONS AND NEUTRAL ATOMS AND MOLECULES

    SciTech Connect (OSTI)

    Brown, G V; Beiersdorfer, P; Chen, H; Clementson, J; Frankel, M; Gu, M F; Kelley, R L; Kilbourne, C A; Porter, F S; Thorn, D B; Wargelin, B J

    2008-08-28T23:59:59.000Z

    We have used microcalorimeters built by the NASA/Goddard Space Flight Center and the Lawrence Livermore National Laboratory Electron Beam Ion Trap to measure X-ray emission produced by charge exchange reactions between highly charged ions colliding with neutral helium, hydrogen, and nitrogen gas. Our measurements show the spectral dependence on neutral species and also show the distinct differences between spectra produced by charge exchange reactions and those produced by direct impact excitation. These results are part of an ongoing experimental investigation at the LLNL EBIT facility of charge exchange spectral signatures and can be used to interpret X-ray spectra produced by a variety of laboratory and celestial sources including cometary and planetary atmospheres, the Earth's magnetosheath, the heliosphere, and tokamaks.

  6. Process for carbonaceous material conversion and recovery of alkali metal catalyst constituents held by ion exchange sites in conversion residue

    DOE Patents [OSTI]

    Sharp, David W. (Seabrook, TX)

    1980-01-01T23:59:59.000Z

    In a coal gasification operation or similar conversion process carried out in the presence of an alkali metal-containing catalyst wherein solid particles containing alkali metal residues are produced, alkali metal constituents are recovered for the particles by contacting or washing them with an aqueous solution containing calcium or magnesium ions in an alkali metal recovery zone at a low temperature, preferably below about 249.degree. F. During the washing or leaching process, the calcium or magnesium ions displace alkali metal ions held by ion exchange sites in the particles thereby liberating the ions and producing an aqueous effluent containing alkali metal constituents. The aqueous effluent from the alkali metal recovery zone is then recycled to the conversion process where the alkali metal constituents serve as at least a portion of the alkali metal constituents which comprise the alkali metal-containing catalyst.

  7. Synthesis and Evaluation of Cu-SAPO-34 Catalysts for Ammonia Selective Catalytic Reduction. 1. Aqueous Solution Ion Exchange

    SciTech Connect (OSTI)

    Gao, Feng; Walter, Eric D.; Washton, Nancy M.; Szanyi, Janos; Peden, Charles HF

    2013-09-06T23:59:59.000Z

    SAPO-34 molecular sieves are synthesized using various structure directing agents (SDAs). Cu-SAPO-34 catalysts are prepared via aqueous solution ion exchange. Catalysts are characterized with surface area/pore volume measurements, temperature programmed reduction (TPR), electron paramagnetic resonance (EPR) and nuclear magnetic resonance (NMR) spectroscopies. Catalytic properties are examined using standard ammonia selective catalytic reduction (NH3-SCR) and ammonia oxidation reactions. During solution ion exchange, different SAPO-34 samples undergo different extent of structural damage via irreversible hydrolysis. Si content within the samples (i.e., Al-O-Si bond density) and framework stress are key factors that affect irreversible hydrolysis. Even using very dilute Cu acetate solutions, it is not possible to generate Cu-SAPO-34 samples with only isolated Cu2+ ions. Small amounts of CuOx species always coexist with isolated Cu2+ ions. Highly active and selective Cu-SAPO-34 catalysts for NH3-SCR are readily generated using this synthesis protocol, even for SAPO-34 samples that degrade substantially during solution ion exchange. High-temperature aging is found to improve the catalytic performance. This is likely due to reduction of intracrystalline mass-transfer limitations via formation of additional porosity in the highly defective SAPO-34 particles formed after ion exchange. The authors gratefully acknowledge the US Department of Energy (DOE), Office of Energy Efficiency and Renewable Energy, Office of Vehicle Technologies for the support of this work. The research described in this paper was performed at the Environmental Molecular Sciences Laboratory (EMSL), a national scientific user facility sponsored by the DOE’s Office of Biological and Environmental Research and located at Pacific Northwest National Laboratory (PNNL). PNNL is operated for the US DOE by Battelle Memorial Institute under contract number DE-AC05-76RL01830.

  8. Increase of ionic conductivity in the microporous lithosilicate RUB-29 by Na-ion exchange processes

    SciTech Connect (OSTI)

    Park, S.-H. [Section Crystallography, Earth and Environmental Sciences, Ludwig-Maximilians-Universitaet Muenchen, Theresienstr. 41, 80333 Munich (Germany)], E-mail: sohyun.park@lmu.de; Senyshyn, A. [Material- and Earth Sciences, Technische Universitaet Darmstadt, Petersenstr. 23, 64287 Darmstadt (Germany); Forschungsneutronenquelle Heinz Maier-Leibnitz (FRM II), Lichtenbergstr. 1, 85747 Garching (Germany); Paulmann, C. [Mineralogisch-Petrographisches Institut, Universitaet Hamburg, Grindelallee 48, 20146 Hamburg (Germany); HASYLAB, DESY, Notkestr. 85, 22603 Hamburg (Germany)

    2007-12-15T23:59:59.000Z

    The ionic conductivity in the zeolite-like lithosilicate RUB-29 (Cs{sub 14}Li{sub 24}[Li{sub 18}Si{sub 72}O{sub 172}].14H{sub 2}O [S.-H. Park, J.B. Parise, H. Gies, H. Liu, C.P. Grey, B.H. Toby, J. Am. Chem. Soc. 122 (2000) 11023-11024]) increases via simple ion-exchange processes, in particular when Na cations replace a part of Cs{sup +} and Li{sup +} of the material. The resulting ionic conductivity value of 3.2x10{sup -3} S cm{sup -1} at 885 K is about two orders higher than that for the original material [S.-H. Park, J.B. Parise, M.E. Franke, T. Seydel, C. Paulmann, Micropor. Mesopor. Mater., in print ( (doi:10.1016/j.micromeso.2007.03.040) available online since April 19, 2007)]. The structural basis of a Na{sup +}-exchanged RUB-29 sample (Na-RUB-29) at 673 K could be elucidated by means of neutron powder diffraction. Rietveld refinements confirmed the replacement of Na{sup +} for both parts of Cs and Li cations, agreeing with idealized cell content, Na{sub 8}Cs{sub 8}Li{sub 40}Si{sub 72}O{sub 172}. As a result of the incorporation of Na{sup +} in large pores, the number of Li{sup +} vacancies in dense Li{sub 2}O-layers of the structure could increase. This can be one of the main reasons for the improved conductivity in Na-RUB-29. In addition, mobile Na cations may also contribute to the conductivity in Na-RUB-29 as continuous scattering length densities were found around the sites for Na in difference Fourier map. - Graphical abstract: Li{sub 2}O-layers formed by edge- and corner-sharing LiO{sub 4}- and LiO{sub 3}-moieties in the zeolite-like lithosilicate RUB-29 provide optimal pathways for conducting Li{sup +}. The number of empty Li sites in this layer-like configuration could increase via 'simple' Na{sup +}-exchange processes, promoting fast Li motions.

  9. EVALUATION OF POTENTIAL ELUANTS FOR NON-ACID ELUTION OF CESIUM FROM RESORCINOL-FORMALDEHYDE RESIN

    SciTech Connect (OSTI)

    Adu-Wusu, K.; Pennebaker, F.

    2010-12-22T23:59:59.000Z

    Small-column ion exchange (SCIX) units installed in high-level waste tanks to remove Cs-137 from highly alkaline salt solutions are among the waste treatment plans in the DOE-complex. Spherical Resorcinol-Formaldehyde (sRF) is the ion exchange resin selected for use in the Hanford Waste Treatment and Immobilization Plant (WTP). It is also the primary ion exchange material under consideration for SCIX at the Hanford site. The elution step of the multi-step ion exchange process is typically done with 0.5 M nitric acid. An acid eluant is a potential hazard in the event of a spill, leak, etc. because the high-level waste tanks are made of carbon steel. Corrosion and associated structural damage may ensue. A study has been conducted to explore non-acid elution as an alternative. Batch contact sorption equilibrium screening tests have been conducted with 36 potential non-acid eluants. The sorption tests involve equilibrating each cesium-containing eluant solution with the sRF resin for 48 hours at 25 C in a shaker oven. In the sorption tests, an eluant is deemed to have a high cesium elution potential if it minimizes cesium sorption onto the sRF resin. The top candidates (based on lowest cesium sorption distribution coefficients) include ammonium carbonate, ammonium carbonate/ammonium hydroxide, ammonium bicarbonate, rubidium carbonate, ammonium acetate, ammonium acetate/ammonium hydroxide, ammonium bicarbonate/ammonium hydroxide, calcium chloride, and magnesium chloride. A select few of the top candidate eluants from the screening tests were subjected to actual sorption (loading) and elution tests to confirm their elution ability. The actual sorption (loading) and elution tests mimicked the typical sRF-cesium ion exchange process (i.e., sorption or loading, caustic wash, water rinse, and elution) via batch contact sorption and quasi column caustic wash/water rinse/elution. The eluants tested included ammonium carbonate, ammonium acetate, calcium acetate, magnesium acetate, and nitric acid. Calcium acetate and magnesium acetate were substitutes for calcium chloride and magnesium chloride respectively due to corrosion concerns. Nitric acid was selected for benchmarking since it is the baseline cesium eluant for sRF resin. The cesium elution performance of ammonium carbonate and ammonium acetate was approximately the same as the benchmark eluant, nitric acid. Ninety-seven (97), 94, and 100% percent of the cesium sorbed or loaded were eluted by ammonium carbonate, ammonium acetate, and nitric acid was respectively. The performance of calcium acetate and magnesium acetate, on the other hand, was mediocre. Percent elution was 16 and 8 respectively.

  10. TESTING OF NOVEL INORGANIC ION EXCHANGERS FOR THE REMOVAL OF RADIOCOBALT FROM NPP WASTE EFFLUENTS

    SciTech Connect (OSTI)

    Harjula, R.; Paajanen, A.; Mueller, T.; Lehto, J.

    2002-02-25T23:59:59.000Z

    New antimonysilicate (SbSi) ion exchanger is being developed for industrial use. Tentative screening tests using simulated waste liquids have indicated that this material can remove most key radionuclides such as {sup 60}Co, {sup 90}Sr and {sup 137}Cs in much broader pH-range than existing commercial materials. As a part of the development program, the material is being tested for the removal of {sup 60}Co from real nuclear power plant waste waters. In this context, test with small-scale laboratory columns (bed volume 0.5 mL) have been carried out using a Floor Drain water samples from Ginna NPP and Diablo Canyon NPP, USA. More than 90% of {sup 60}Co in these liquids was removable by mechanical filtration (0.45 {micro}m). SbSi columns removed more than 90% of the soluble {sup 60}Co that was left in the solutions after filtration. The tests were discontinued when about 2000 bed volumes were treated due to depletion of test liquids with no sign of column exhaustion.

  11. Investigation of the effect of intra-molecular interactions on the gas-phase conformation of peptides as probed by ion mobility-mass spectrometry, gas-phase hydrogen/deuterium exchange, and molecular mechanics 

    E-Print Network [OSTI]

    Sawyer, Holly Ann

    2006-04-12T23:59:59.000Z

    Ion mobility-mass spectrometry (IM-MS), gas-phase hydrogen/deuterium (H/D) exchange ion molecule reactions and molecular modeling provide complimentary information and are used here for the characterization of peptide ion structure, including fine...

  12. Investigation of the effect of intra-molecular interactions on the gas-phase conformation of peptides as probed by ion mobility-mass spectrometry, gas-phase hydrogen/deuterium exchange, and molecular mechanics

    E-Print Network [OSTI]

    Sawyer, Holly Ann

    2006-04-12T23:59:59.000Z

    Ion mobility-mass spectrometry (IM-MS), gas-phase hydrogen/deuterium (H/D) exchange ion molecule reactions and molecular modeling provide complimentary information and are used here for the characterization of peptide ion structure, including fine...

  13. RHEOLOGY OF SETTLED SOLIDS IN THE SMALL COLUMN ION EXCHANGE PROCESS

    SciTech Connect (OSTI)

    Ferguson, C.; Prior, M.; Koopman, D.; Edwards, T.

    2011-06-20T23:59:59.000Z

    The Small Column Ion Exchange (SCIX) process is being developed to remove cesium, strontium, and actinides from Savannah River Site (SRS) Liquid Waste using an existing waste tank as process housing. This method includes the addition of monosodium titanate (MST) to a waste tank containing salt solution and entrained sludge solids, followed by tank mixing and filtration. The filtrate is then processed through in-tank ion exchange columns containing crystalline silicotitanate (CST) media. While the process is operating, it is known that solid particles begin to settle in the tank and temperatures may reach beyond 45 C. Previous testing has shown that sludge-MST slurries that sit for extended periods at elevated temperatures can develop large shear strengths, making them difficult to resuspend and remove from the tank. The authors conducted rheological testing of mixtures containing various concentrations of sludge simulant, MST, and CST (three preparations) that were aged at different times (i.e., 0 to 13 weeks) and isothermally maintained to 30, 45, or 60 C. Two types of grinding methodologies were employed to prepare CST for this testing, herein called Savannah River National Laboratory (SRNL) and Vitreous State Laboratory (VSL) ground materials. Unground CST particles were also tested. A small number of samples were irradiated prior to 4 week settling and 60 C temperature treatment, with exposures ranging from 0 to 100 MRad. Additional tests are also being conducted that will allow the solid particles to settle at 45 C for 6, 12, and 24 months. The objectives of this task are to determine the impact of feed composition, settling time, and temperature on the shear strength, yield stress, and consistency of the slurries and to determine the impact of radiation on slurry rheology. The testing will determine the relative impact of these parameters rather than predict the shear strength, yield stress, and consistency as a function of feed and operating conditions. This document describes the rheology of slurries containing MST, CST, and simulated sludge that sat at indicated temperatures for up to 13 weeks. A previous SRNL report described preliminary rheology data of slurries containing MST and sludge. Preliminary results of the irradiation tests are also presented in this report, though additional data are still being collected. Rheology of the long term settling samples (6, 12, and 24 months) and additional irradiation test results will be reported at a later date. Conclusions from this analysis are as follows: (1) Slurries containing MST and unground CST have the largest shear strength. Due to the high shear strengths measured in slurries containing unground CST, evaluations of specific tank contents and mixing capability should be performed prior to any addition of this material into a waste tank. Experimentally determined shear strengths indicate mixing could be problematic in mixtures containing unground CST. (2) Increasing the ground CST fraction in the slurry increases the slurry shear strength, yield stress, and consistency. (3) Increasing the sludge fraction in the slurry decreases the slurry shear strength, yield stress, and consistency. (4) Slurries containing VSL ground CST have larger shear strength, yield stress, and consistency than slurries containing SRNL ground CST. (5) The effects of settling time and temperature on slurry shear strength are slurry dependent. (6) No effects of settling time and temperature on slurry yield stress or consistency were observed. (7) Radiation up to 100 MRad does not appear to affect properties of shear strength, yield stress, or consistency of process feeds.

  14. Preconceptual design for separation of plutonium and gallium by ion exchange

    SciTech Connect (OSTI)

    DeMuth, S.F.

    1997-09-30T23:59:59.000Z

    The disposition of plutonium from decommissioned nuclear weapons, by incorporation into commercial UO{sub 2}-based nuclear reactor fuel, is a viable means to reduce the potential for theft of excess plutonium. This fuel, which would be a combination of plutonium oxide and uranium oxide, is referred to as a mixed oxide (MOX). Following power generation in commercial reactors with this fuel, the remaining plutonium would become mixed with highly radioactive fission products in a spent fuel assembly. The radioactivity, complex chemical composition, and large size of this spent fuel assembly, would make theft difficult with elaborate chemical processing required for plutonium recovery. In fabricating the MOX fuel, it is important to maintain current commercial fuel purity specifications. While impurities from the weapons plutonium may or may not have a detrimental affect on the fuel fabrication or fuel/cladding performance, certifying the effect as insignificant could be more costly than purification. Two primary concerns have been raised with regard to the gallium impurity: (1) gallium vaporization during fuel sintering may adversely affect the MOX fuel fabrication process, and (2) gallium vaporization during reactor operation may adversely affect the fuel cladding performance. Consequently, processes for the separation of plutonium from gallium are currently being developed and/or designed. In particular, two separation processes are being considered: (1) a developmental, potentially lower cost and lower waste, thermal vaporization process following PuO{sub 2} powder preparation, and (2) an off-the-shelf, potentially higher cost and higher waste, aqueous-based ion exchange (IX) process. While it is planned to use the thermal vaporization process should its development prove successful, IX has been recommended as a backup process. This report presents a preconceptual design with material balances for separation of plutonium from gallium by IX.

  15. SCALING SOLID RESUSPENSION AND SORPTION FOR THE SMALL COLUMN ION EXCHANGE PROCESSING TANK

    SciTech Connect (OSTI)

    Poirier, M.; Qureshi, Z.

    2010-12-14T23:59:59.000Z

    The Small Column Ion Exchange (SCIX) process is being developed to remove cesium, strontium, and actinides from Savannah River Site (SRS) Liquid Waste using an existing 1.3 million gallon waste tank (i.e., Tank 41H) to house the process. Savannah River National Laboratory (SRNL) is conducting pilot-scale mixing tests to determine the pump requirements for suspending and resuspending Monosodium Titanate (MST), Crystalline Silicotitanate (CST), and simulated sludge. In addition, SRNL will also be conducting pilot-scale tests to determine the mixing requirements for the strontium and actinide sorption. As part of this task, the results from the pilot-scale tests must be scaled up to a full-scale waste tank. This document describes the scaling approach. The pilot-scale tank is a 1/10.85 linear scale model of Tank 41H. The tank diameter, tank liquid level, pump nozzle diameter, pump elevation, and cooling coil diameter are all 1/10.85 of their dimensions in Tank 41H. The pump locations correspond to the proposed locations in Tank 41H by the SCIX Program (Risers B5 and B2 for two pump configurations and Risers B5, B3, and B1 for three pump configurations). MST additions are through Riser E1, the proposed MST addition riser in Tank 41H. To determine the approach to scaling the results from the pilot-scale tank to Tank 41H, the authors took the following approach. They reviewed the technical literature for methods to scale mixing with jets and suspension of solid particles with jets, and the technical literature on mass transfer from a liquid to a solid particle to develop approaches to scaling the test data. SRNL assembled a team of internal experts to review the scaling approach and to identify alternative approaches that should be considered.

  16. PILOT SCALE TESTING OF MONOSODIUM TITANATE MIXING FOR THE SRS SMALL COLUMN ION EXCHANGE PROCESS - 11224

    SciTech Connect (OSTI)

    Poirier, M.; Restivo, M.; Williams, M.; Herman, D.; Steeper, T.

    2011-01-25T23:59:59.000Z

    The Small Column Ion Exchange (SCIX) process is being developed to remove cesium, strontium, and select actinides from Savannah River Site (SRS) Liquid Waste using an existing waste tank (i.e., Tank 41H) to house the process. Savannah River National Laboratory (SRNL) is conducting pilot-scale mixing tests to determine the pump requirements for suspending monosodium titanate (MST), crystalline silicotitanate (CST), and simulated sludge. The purpose of this pilot scale testing is to determine the requirements for the pumps to suspend the MST particles so that they can contact the strontium and actinides in the liquid and be removed from the tank. The pilot-scale tank is a 1/10.85 linear scaled model of SRS Tank 41H. The tank diameter, tank liquid level, pump nozzle diameter, pump elevation, and cooling coil diameter are all 1/10.85 of their dimensions in Tank 41H. The pump locations correspond to the proposed locations in Tank 41H by the SCIX program (Risers B5 and B2 for two pump configurations and Risers B5, B3, and B1 for three pump configurations). The conclusions from this work follow: (i) Neither two standard slurry pumps nor two quad volute slurry pumps will provide sufficient power to initially suspend MST in an SRS waste tank. (ii) Two Submersible Mixer Pumps (SMPs) will provide sufficient power to initially suspend MST in an SRS waste tank. However, the testing shows the required pump discharge velocity is close to the maximum discharge velocity of the pump (within 12%). (iii) Three SMPs will provide sufficient power to initially suspend MST in an SRS waste tank. The testing shows the required pump discharge velocity is 66% of the maximum discharge velocity of the pump. (iv) Three SMPs are needed to resuspend MST that has settled in a waste tank at nominal 45 C for four weeks. The testing shows the required pump discharge velocity is 77% of the maximum discharge velocity of the pump. Two SMPs are not sufficient to resuspend MST that settled under these conditions.

  17. IMPACT OF SMALL COLUMN ION EXCHANGE STREAMS ON DWPF GLASS FORMULATION MELT RATE STUDIES

    SciTech Connect (OSTI)

    Fox, K.; Miller, D.; Koopman, D.

    2011-04-26T23:59:59.000Z

    This study was undertaken to evaluate the potential impacts of the Small Column Ion Exchange (SCIX) streams - particularly the addition of Monosodium Titanate (MST) and Crystalline Silicotitanate (CST) - on the melt rate of simulated feed for the Defense Waste Processing Facility (DWPF). Additional MST was added to account for contributions from the Salt Waste Processing Facility (SWPF). The Savannah River National Laboratory (SRNL) Melt Rate Furnace (MRF) was used to evaluate four melter feed compositions: two with simulated SCIX and SWPF material and two without. The Slurry-fed Melt Rate Furnace (SMRF) was then used to compare two different feeds: one with and one without bounding concentrations of simulated SCIX and SWPF material. Analyses of the melter feed materials confirmed that they met their targeted compositions. Four feeds were tested in triplicate in the MRF. The linear melt rates were determined by using X-ray computed tomography to measure the height of the glass formed along the bottom of the beakers. The addition of the SCIX and SWPF material reduced the average measured melt rate by about 10% in MRF testing, although there was significant scatter in the data. Two feeds were tested in the SMRF. It was noted that the ground CST alone (ground CST with liquid in a bucket) was extremely difficult to resuspend during preparation of the feed with material from SCIX and SWPF. This feed was also more difficult to pump than the material without MST and CST due to settling occurring in the melter feed line, although the yield stress of both feeds was high relative to the DWPF design basis. Steady state feeding conditions were maintained for about five hours for each feed. There was a reduction in the feed and pour rates of approximately 15% when CST and MST were added to the feed, although there was significant scatter in the data. Analysis of samples collected from the SMRF pour stream showed that the composition of the glass changed as expected when MST and CST were added to the feed. These reductions in melt rate are consistent with previous studies that showed a negative impact of increased TiO{sub 2} concentrations on the rate of melting. The impact of agitating the melt pool via bubbling was not studied as part of this work, but may be of interest for further testing. It is recommended that additional melt rate testing be performed should a potential reduction in melt rate of 10-15% be considered an issue of concern, or should the anticipated composition of the glass with the addition of material from salt waste processing be modified significantly from the current projections, either due to changes in sludge batch preparation or changes in the composition or volume of SCIX and SWPF material.

  18. A Comprehensive Study of the Solubility, Thermochemistry, Ion Exchange, and Precipitation Kinetics of NO3 Cancrinite and NO3 Sodalite

    SciTech Connect (OSTI)

    Colon, Carlos F. Joyce; Navrotsky, Alexandra; Krumhansl, James L.; Nyman, May

    2003-06-01T23:59:59.000Z

    NO3 cancrinite and NO3 sodalite haves been found as a common sodium alumino-silicate forming in strongly caustic alkaline aqueous solutions associated with radioactive High Level Waste (HLW) stored in many underground tanks and also in nuclear waste treatment facilities such as the Savannah River Site (SRS). The precipitation of alumino-silicate phases from caustic nuclear wastes has proven to be problematic in a number of processes in waste treatment facilities including radionuclide separations (cementation of columns by aluminosilicate phases), tank emptying (aluminosilicate tank heels), and condensation of wastes in evaporators (aluminosilicate precipitates in the evaporators, providing nucleation sites for growth of critical masses of radioactive actinide salts). Therefore, in order to prevent their formation an assessment of the relative stability, formation kinetics, and the ion-exchange characteristics of these two phases in HLW solutions needs to be investigated. The goals of this project are to: (1) Develop a robust equilibrium thermodynamic framework to accurately describe and predict the formation of NO3 cancrinite and NO3 sodalite. (2) Provide a comprehensive characterization of the solid precipitation rates and mechanisms using novel spectroscopic (e.g., NMR) and thermochemical techniques in conditions encountered in HLW waste solutions. (3) Characterize the precipitation kinetics of the aluminosilicates and study the effects of temperature and fluid composition. (4) Investigate the ion exchange capacity of these zeolitic phases with respect to radionuclides and RCRA metal species.

  19. A Comprehensive Study of the Solubility, Thermochemistry, Ion Exchange, and Precipitation Kinetics of NO3 Cancrinite and NO3 Sodalite

    SciTech Connect (OSTI)

    Colon, Carlos F. Jove; Navrotsky, Alexandra; Krumhansl, James L.; Nyman, May

    2002-06-01T23:59:59.000Z

    NO3 cancrinite and NO3 sodalite haves been found as a common sodium alumino-silicate forming in strongly caustic alkaline aqueous solutions associated with radioactive High Level Waste (HLW) stored in many underground tanks and also in nuclear waste treatment facilities such as the Savannah River Site (SRS). The appearance of these phases have created very expensive problems in waste treatment plants by fouling process evaporators in the SRS waste processing facility. Therefore, in order to prevent their formation an assessment of the relative stability, formation kinetics, and the ion-exchange characteristics of these two phases in HLW solutions needs to be investigated. The goals of this project are to: (1) Develop a robust equilibrium thermodynamic framework to accurately describe and predict the formation of NO3 cancrinite and NO3 sodalite. (2) Provide a comprehensive characterization of the solid precipitation rates and mechanisms using novel spectroscopic (e.g., NMR) and thermochemical techniques in conditions encountered in HLW waste solutions. (3) Investigate the ion exchange capacity of these zeolitic phases with respect to radionuclides and RCRA metal species.

  20. Core-ion temperature measurement of the ADITYA tokamak using passive charge exchange neutral particle energy analyzer

    SciTech Connect (OSTI)

    Pandya, Santosh P.; Ajay, Kumar; Mishra, Priyanka; Dhingra, Rajani D.; Govindarajan, J. [Institute for Plasma Research, Bhat, Gandhinagar 382 428, Gujarat (India)

    2013-02-15T23:59:59.000Z

    Core-ion temperature measurements have been carried out by the energy analysis of passive charge exchange (CX) neutrals escaping out of the ADITYA tokamak plasma (minor radius, a= 25 cm and major radius, R= 75 cm) using a 45 Degree-Sign parallel plate electrostatic energy analyzer. The neutral particle analyzer (NPA) uses a gas cell configuration for re-ionizing the CX-neutrals and channel electron multipliers (CEMs) as detectors. Energy calibration of the NPA has been carried out using ion-source and {Delta}E/E of high-energy channel has been found to be {approx}10%. Low signal to noise ratio (SNR) due to VUV reflections on the CEMs was identified during the operation of the NPA with ADITYA plasma discharges. This problem was rectified by upgrading the system by incorporating the additional components and arrangements to suppress VUV radiations and improve its VUV rejection capabilities. The noise rejection capability of the NPA was experimentally confirmed using a standard UV-source and also during the plasma discharges to get an adequate SNR (>30) at the energy channels. Core-ion temperature T{sub i}(0) during flattop of the plasma current has been measured to be up to 150 eV during ohmically heated plasma discharges which is nearly 40% of the average core-electron temperature (typically T{sub e}(0) {approx} 400 eV). The present paper describes the principle of tokamak ion temperature measurement, NPA's design, development, and calibration along with the modifications carried out for minimizing the interference of plasma radiations in the CX-spectrum. Performance of the NPA during plasma discharges and experimental results on the measurement of ion-temperature have also been reported here.

  1. Phase transition upon K{sup +} ion exchange into Na-low silica X: Combined NMR and synchrotron X-ray powder diffraction study

    SciTech Connect (OSTI)

    Lee, Y.; Parise, J.B. [State Univ. of New York, Stony Brook, NY (United States)] [State Univ. of New York, Stony Brook, NY (United States); Carr, S.W. [ANSTO, Menai (Australia)] [ANSTO, Menai (Australia)

    1998-09-01T23:59:59.000Z

    The mechanism by which K{sup +} ions exchange into zeolite Na-low silica X (LSX) (Na{sub 96}Al{sub 96}Si{sub 96}O{sub 384}{center_dot}nH{sub 2}O) has ben determined by studying structures of the Na-LSX and K-LSX end members in the Na-K LSX solid solution series as well as samples exchanged at the 20%, 42% and 80% K{sup +} levels. A preliminary investigation using {sup 29}Si MAS NMR spectroscopy revealed a two-phase region in the solid solution near 80% K{sup +} exchange. Rietveld analysis of the powder diffraction data collected from hydrated samples showed that, up to 42% of K{sup +} exchange, K{sup +} ions were located preferentially at site I{prime}, just outside the double 6-ring (D6R) in the sodalite age, and at site II, above the single 6-ring (S6R) in the supercage. Introduction of K{sup +} ions into site I{prime} repositioned Na{sup +} ions into site I, at the center of the D6R. An abrupt change in the cubic lattice parameter from 25.0389(5) to 25.2086(5) {angstrom} marked the formation of a second phase at the 80% K{sup +}-exchange level as K{sup +} ions began to occupy site I. No coexistence of phases was observed for the fully K{sup +}-exchanged sample (a = 25.2486(2) {angstrom}), where sites I and II were fully occupied by K{sup +} ions.

  2. Method and apparatus for removing ions from soil

    DOE Patents [OSTI]

    Bibler, Jane P. (813 E. Rollingwood Rd., Aiken, SC 29801)

    1993-01-01T23:59:59.000Z

    A method and apparatus for selectively removing species of ions from an area of soil. Permeable membranes 14 and 18 impregnated with an ion exchange resin that is specific to one or more species of chemical ions are inserted into ground 12 in close proximity to, and on opposing sides of, a soil area of interest 22. An electric potential is applied across electrodes 26 and 28 to cause the migration of ions out of soil area 22 toward the membranes 14 and 18. Preferably, the resin exchanges ions of sodium or hydrogen for ions of mercury that it captures from soil area 22. Once membranes 14 and 18 become substantially saturated with mercury ions, the potential applied across electrodes 26 and 28 is discontinued and membranes 14 and 18 are preferably removed from soil 12 for storage or recovery of the ions. The membranes are also preferably impregnated with a buffer to inhibit the effect of the hydrolysis of water by current from the electrodes.

  3. Method and apparatus for removing ions from soil

    DOE Patents [OSTI]

    Bibler, J.P.

    1993-03-02T23:59:59.000Z

    A method and apparatus are presented for selectively removing species of ions from an area of soil. Permeable membranes 14 and 18 impregnated with an ion exchange resin that is specific to one or more species of chemical ions are inserted into ground 12 in close proximity to, and on opposing sides of, a soil area of interest 22. An electric potential is applied across electrodes 26 and 28 to cause the migration of ions out of soil area 22 toward the membranes 14 and 18. Preferably, the resin exchanges ions of sodium or hydrogen for ions of mercury that it captures from soil area 22. Once membranes 14 and 18 become substantially saturated with mercury ions, the potential applied across electrodes 26 and 28 is discontinued and membranes 14 and 18 are preferably removed from soil 12 for storage or recovery of the ions. The membranes are also preferably impregnated with a buffer to inhibit the effect of the hydrolysis of water by current from the electrodes.

  4. Delayed cure bismaleimide resins

    DOE Patents [OSTI]

    Not Available

    1982-08-12T23:59:59.000Z

    Prior art polybismaleimides begin to polymerize at or just above the melting point of the monomer. This patent describes new bismaleimide resins which have an increased pot life and provide longer time periods in which the monomer remains fluid. The resins can be polymerized into molded articles with a high uniformity of properties. (DLC)

  5. PRELIMINARY REPORT ON EVALUATION OF POTENTIAL ELUANTS FOR NON-ACID ELUTION OF CESIUM FROM RESORCINOL-FORMALDEHYDE RESIN

    SciTech Connect (OSTI)

    Adu-Wusu, K.; Pennebaker, F.

    2010-09-01T23:59:59.000Z

    Small-column ion exchange (SCIX) units installed in high-level waste tanks to remove Cs-137 from highly alkaline salt solutions are among the waste treatment plans in the DOE-complex. Spherical Resorcinol-Formaldehyde (sRF) is the ion exchange resin selected for use in the Hanford Waste Treatment and Immobilization Plant (WTP). It is also the primary ion exchange material under consideration for SCIX at the Hanford site. The elution step of the multi-step ion exchange process is typically done with 0.5 M nitric acid. An acid eluant is a potential hazard in the event of a spill, leak, etc. because the high-level waste tanks are made of carbon steel. Corrosion and associated structural damage may ensue. Studies are ongoing to explore non-acid elution as an alternative. Batch contact sorption equilibrium screening tests have been conducted with 36 potential non-acid eluants. The sorption tests involve equilibrating each cesium-containing eluant solution with the sRF resin for 48 hours at 25 C in a shaker oven. In the sorption tests, an eluant is deemed to have a high cesium elution potential if it minimizes cesium sorption onto the sRF resin. The top candidates (based on lowest cesium sorption distribution coefficients) include ammonium carbonate, ammonium carbonate/ammonium hydroxide, ammonium bicarbonate, rubidium carbonate, ammonium acetate, ammonium acetate/ammonium hydroxide, ammonium bicarbonate/ammonium hydroxide, calcium chloride, and magnesium chloride. The next phase of testing for this work will focus on the following down selected eluants: Ammonium carbonate, ammonium acetate, calcium acetate, magnesium acetate, nitric acid, and ammonium hydroxide. The next testing phase is a confirmation of the elution ability of the selected eluants. It will mimic a typical sRF cesium ion exchange process i.e., sorption or loading, caustic wash, water rinse, and elution via batch contact sorption and quasi column caustic wash/water rinse/elution. Due to corrosion concerns, calcium acetate and magnesium acetate will be tested instead of calcium chloride and magnesium chloride respectively. Nitric acid is for benchmarking since it is the baseline sRF eluant. The information at hand indicates ammonium hydroxide, while a weak base, may hold promise as an effective eluant. Hence, its inclusion among the eluants to be studied despite the fact that it was not tested as a stand-alone eluant earlier.

  6. Development of Pillared M(IV) Phosphate Phosphonate Inorganic Organic Hybrid Ion Exchange Materials for Applications in Separations found in the Nuclear Fuel Cycle 

    E-Print Network [OSTI]

    Burns, Jonathan

    2012-10-02T23:59:59.000Z

    ..................................................................................................... 105 5.5.1 Basic sorption .............................................................................. 105 5.5.2 Plutonium redox .......................................................................... 107 5.5.3 Americium oxidation....1. ................................ 104 xiii FIGURE Page 32 Schematic of the ion exchange equilibrium for the M(IV) hybrids. ............................................................................................. 106 33 Latimer diagram for plutonium in 1 M perchloric...

  7. X-RAY SIGNATURE OF CHARGE EXCHANGE IN L-SHELL SULFUR IONS

    SciTech Connect (OSTI)

    Frankel, M.; Beiersdorfer, P.; Brown, G. V.; Gu, M. F. [Lawrence Livermore National Laboratory, CA, 94550 (United States); Kelley, R. L.; Kilbourne, C. A.; Porter, F. S. [NASA/Goddard Space Flight Center, Greenbelt, MD, 20771 (United States)], E-mail: frankel4@llnl.gov, E-mail: beiersdorfer1@llnl.gov

    2009-09-01T23:59:59.000Z

    The X-ray signature of L-shell charge exchange in sulfur was studied in the laboratory. A comparison of the charge exchange (CX) spectra with those obtained under electron-impact excitation showed marked differences. In the CX spectra, an enhancement was observed in the transitions from levels with high principal quantum numbers, n = 4, 5, 6 {yields} n = 2 in comparison with the n = 3 {yields} n = 2 transitions that dominate the direct excitation spectra. An even greater enhancement was recorded in the transitions from the levels of electron capture to the ground states: n = 7, 8, 9 {yields} n = 2. The spectra mainly consist of emission from S XIV, but lower charge states such as S XIII, S XII, and S XI also contribute. The results have been compared with observations made by the Chandra and XMM-Newton X-ray Observatories of Jupiter's polar regions. The enhancement we noticed in transitions from the high-n levels is not seen in the Chandra spectra.

  8. Small Column Ion Exchange at Savannah River Site Technology Readiness Assessment Report

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directedAnnual Site EnvironmentalEnergySafely Delivering DOE'sEnergy SmallAwardsSmall Column Ion

  9. A Comprehensive Study of the Solubility, Thermochemistry, Ion Exchange, and Precipitation Kinetics of NO3 Cancrinite and NO3 Sodalite (Project No.: 81959)

    SciTech Connect (OSTI)

    Colon, Carlos F. Jove; Navrotsky, Alexandra; Krumhansl, James L.; Nyman, May; Liu, Qingyuan

    2004-06-01T23:59:59.000Z

    NO3 cancrinite and NO3 sodalite haves been found as a common sodium alumino-silicate forming in strongly caustic and alkaline aqueous solutions associated with radioactive High Level Waste (HLW) stored in many underground tanks and also in nuclear waste treatment facilities such as the Savannah River Site (SRS). The appearance of these phases have created very expensive problems in waste treatment plants by fouling process evaporators in the SRS waste processing facility. Therefore, in order to prevent their formation an assessment of the relative stability, formation kinetics, and the ion-exchange characteristics of these two phases in HLW solutions needs to be investigated. The goals of this project are to: (1) Develop a robust equilibrium thermodynamic framework to accurately describe the formation of NO3 cancrinite and NO3 sodalite. (2) Provide quantification and characterization of the solid precipitation rates through long-term batch kinetic experiments and novel analytical techniques. (3) Investigate the partitioning and ion exchange properties of these zeolitic phases with respect to radionuclides and RCRA metal species. This also includes compositional and structural characterization of ion exchanged solids elucidate the exchange properties of these phases.

  10. Fractionation of NaCl, MgCl2, and CaCl2 brines with a polyfunctional ion exchange resin

    E-Print Network [OSTI]

    Baker, Albert Byre

    1959-01-01T23:59:59.000Z

    ml. of 2 N. HC1 and 150 ml. of distilled water. The filtrate and wash solut1ons were analyzed for Ca++, Mg~, and Cl iona. Calcium and magnesium were deter- mined by a complexometric titration with a 0. 01 molar solution of the disodium salt... for various FIGURE 4 VARIATION OF SELECTIVITY COEFFICIENTS WITH FEED SOLUTION RATIO 30. 0 Ca Na 10. 0 3. 0 1. 0 Mg Na Ca 8 0. 3 0. 1 0. 01 0. 03 0. 10 0. 3 1. 0 3. 0 10. 0 Ratio of ? , ? , or ~ in Feed Ca Ca Na' Mg' Na total solution...

  11. EFFECT OF GYPSUM ON AVAILABLE PHOSPHORUS EVALUATED BY MEHLICH-1, ION EXCHANGE RESIN, AND Pi-PAPER IN A BRAZILIAN TROPICAL OXISOL

    E-Print Network [OSTI]

    Silva, Rodrigo Coqui da; Chien, Sen Hsuing; Prochnow, Luís Ignácio

    2009-01-01T23:59:59.000Z

    Pure gypsum Source average Phosphate Rock (100 mg kg -1 P)Pure gypsum Source average Phosphate Rock (100 mg kg -1 P) bPure gypsum Source average Phosphate Rock (100 mg kg -1 P)

  12. {sup 1}H and {sup 23}Na MAS NMR spectroscopy of cationic species in CO{sub 2} selective alkaline earth metal porous silicoaluminophosphates prepared via liquid and solid state ion exchange

    SciTech Connect (OSTI)

    Arevalo-Hidalgo, Ana G. [Department of Chemical Engineering, University of Puerto Rico-Mayagueez Campus, Mayagueez, PR 00681-9000 (Puerto Rico); Dugar, Sneha; Fu, Riqiang [National High Magnetic Field Laboratory, Florida State University, Tallahassee, FL 32310 (United States); Hernandez-Maldonado, Arturo J., E-mail: arturoj.hernandez@upr.edu [Department of Chemical Engineering, University of Puerto Rico-Mayagueez Campus, Mayagueez, PR 00681-9000 (Puerto Rico)

    2012-07-15T23:59:59.000Z

    The location of extraframework cations in Sr{sup 2+} and Ba{sup 2+} ion-exchanged SAPO-34 was estimated by means of {sup 1}H and {sup 23}Na MAS NMR spectroscopy and spectral deconvolution. Incorporation of the alkaline earth metal cations onto the SAPO framework was achieved via liquid state ion exchange, coupled partial detemplation/solid-state ion exchange, and combination of both techniques. MAS NMR revealed that the level of ion exchange was limited by the presence of protons and sodium cations near hexagonal prisms (site SI), which are relatively difficult to exchange with the alkaline earth metal due to steric and charge repulsion criteria. In addition, the presence of ammonium cations in the supercages facilitated the exchange of otherwise tenacious hydrogen as corroborated by unit cell compositional data as well as enhanced CO{sub 2} adsorption at low partial pressures. The extraframework ammonium species were produced from partial detemplation of the structure-directing agent employed for the SAPO-34 synthesis, tetraethylammonium. - Graphical abstract: MAS NMR was used to elucidate the position the cationic species in alkaline earth metal exchanged silicoaluminophosphates. These species played a significant role during the ion exchange process and, therefore, the materials ultimate CO{sub 2} adsorption performance. Highlights: Black-Right-Pointing-Pointer Location of extraframework Sr{sup 2+} or Ba{sup 2+} cations was estimated by means of {sup 1}H and {sup 23}Na MAS NMR. Black-Right-Pointing-Pointer Level of Sr{sup 2+} or Ba{sup 2+} ion exchange was limited by the presence of protons and sodium cations. Black-Right-Pointing-Pointer Presence of ammonium cations in the supercages facilitated the exchange. Black-Right-Pointing-Pointer Sr{sup 2+} and Ba{sup 2+} ion exchanged SAPOs are outstanding CO{sub 2} adsorbents.

  13. Method for removing contaminants from plastic resin

    DOE Patents [OSTI]

    Bohnert, George W. (Harrisonville, MO); Hand, Thomas E. (Lee's Summit, MO); DeLaurentiis, Gary M. (Jamestown, CA)

    2008-12-09T23:59:59.000Z

    A resin recycling method that produces essentially contaminant-free synthetic resin material in an environmentally safe and economical manner. The method includes receiving the resin in container form. The containers are then ground into resin particles. The particles are exposed to a solvent, the solvent contacting the resin particles and substantially removing contaminants on the resin particles. After separating the particles and the resin, a solvent removing agent is used to remove any residual solvent remaining on the resin particles after separation.

  14. Development and implementation of a FT-ICR mass spectrometer for the investigation of ion conformations of peptide sequence isomers containing basic amino acid residues by gas-phase hydrogen/deuterium exchange 

    E-Print Network [OSTI]

    Marini, Joseph Thomas

    2004-09-30T23:59:59.000Z

    The gas-phase hydrogen/deuterium (H/D) exchange of protonated di- and tripeptides containing a basic amino acid residue has been studied with a Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometer. Bimolecular reactions...

  15. Development and implementation of a FT-ICR mass spectrometer for the investigation of ion conformations of peptide sequence isomers containing basic amino acid residues by gas-phase hydrogen/deuterium exchange

    E-Print Network [OSTI]

    Marini, Joseph Thomas

    2004-09-30T23:59:59.000Z

    The gas-phase hydrogen/deuterium (H/D) exchange of protonated di- and tripeptides containing a basic amino acid residue has been studied with a Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometer. Bimolecular reactions...

  16. Glycoprotein Enrichment Resin User Manual

    E-Print Network [OSTI]

    Lebendiker, Mario

    Glycoprotein Enrichment Resin User Manual Cat. No. 635647 PT4050-1 (PR912675) Published 14 January Laboratories, Inc. Version No. PR912675 ATakara Bio Company 2 Glycoprotein Enrichment Resin User Manual I.................................................................................................4 IV. Glycoprotein Enrichment

  17. Transition Path Sampling of Water Exchange Rates and Mechanisms...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Path Sampling of Water Exchange Rates and Mechanisms around Aqueous Ions . Transition Path Sampling of Water Exchange Rates and Mechanisms around Aqueous Ions . Abstract: The rates...

  18. Fiscal year 1997 final report for task plan SR-16WT-31 task B, vitrification of ion exchange material

    SciTech Connect (OSTI)

    Ferrara, D.; Andrews, M.K.; Harbour, J.R.; Fellinger, T.L.; Herman, D.T.; Marshall, K.M.; Workman, P.J.

    1997-09-30T23:59:59.000Z

    In Fiscal Year 1997, the Department of Energy Tanks Focus Area (TFA) funded the Savannah River Technology Center (SRTC) to develop and demonstrate the vitrification of a CST ion exchange material loaded with radioactive cesium from one of the Melton Valley Storage Tanks at the Oak Ridge National Laboratory (ORNL). SRTC developed a patent-pending glass formulation that can be used to vitrify CST sorbent producing a quality borosilicate glass waste form. SRTC demonstrated this formulation by vitrifying the radioactive CST in the SRTC shielded cells melter.In addition to the formulation developed for vitrification of the `CST-only` glass waste form, SRTC also developed formulations for vitrification of CST coupled with High-Level Waste (HLW) sludges. A Defense Waste Processing Facility (DWPF) coupled feed formulation has been developed with up to 10 weight percent CST and 28 weight percent DWPF sludge oxides. A coupled Hanford formulation has also been developed for producing quality glass waste forms with up to 10 weight percent CST and 45 weight percent Hanford sludge oxides. The significant accomplishments of this project were then development of CST-only glass formulations incorporating up to 65 weight-percent CST, development of techniques for delivering a slurry or dry feed to a joule-heated melter, demonstration of a CST-only glass formulation in a continuous melter operation, demonstration of compliance with the Nevada Test Site (NTS) Waste Acceptance Criteria (WAC), development of CST-sludge glass formulations incorporating up to 10 weight percent CST and 28 weight percent DWPF sludges oxides, demonstration of CST-sludge glass formulations using radioactive sludge and radioactive CST, development of CST-sludge glass formulations incorporating up to 10 weight percent CST and 45 weight percent. All commitments made to the TFA have been met as indicated by the associated milestones. Milestones and the month in which they were completed: Initiate Immobilization of CST in Glass (completed 8/97); Demonstrate that Sludge-CST Glass Satisfied PC Specs in WAPS (completed 9/97); Determine Process Parameters of Sludge-CST Glass (completed 8/97); Demonstrate that CST-Only Glass Satisfied PC Specs in WAPS (completed 9/97); Determine Process Parameters of CST-Only Glass (completed 9/97). The results for Task B of Task Plan SR-16WT-31 have been documented in reports that have been included as attachments. The following is a summary of the attachments from the CST vitrification project.

  19. SELECTIVE REMOVAL OF STRONTIUM AND CESIUM FROM SIMULATED WASTE SOLUTION WITH TITANATE ION EXCHANGERS IN A FILTER CARTRIDGE CONFIGURATION

    SciTech Connect (OSTI)

    Oji, L.; Martin, K.; Hobbs, D.

    2011-05-26T23:59:59.000Z

    This report describes experimental results for the selective removal of strontium and cesium from simulated waste solutions using monosodium titanate (MST) and crystalline silicotitanate (CST)-laden filter cartridges. Four types of ion exchange cartridge media (CST and MST designed by both 3M and POROX{reg_sign}) were evaluated. In these proof-of-principle tests effective uptake of both Sr-85 and Cs-137 was observed. However, the experiments were not performed long enough to determine the saturation levels or breakthrough curve for each filter cartridge. POREX{reg_sign} MST cartridges, which by design were based on co-sintering of the active titanates with polyethylene particles, seem to perform as well as the 3M-designed MST cartridges (impregnated filter membrane design) in the uptake of strontium. At low salt simulant conditions (0.29 M Na{sup +}), the instantaneous decontamination factor (D{sub F}) for Sr-85 with the 3M-design MST cartridge measured 26, representing the removal of 96% of the Sr-85. On the other hand, the Sr-85 instantaneous D{sub F} with the POREX{reg_sign} design MST cartridge measured 40 or 98% removal of the Sr-85. Strontium removal with the 3M-design MST and CST cartridges placed in series filter arrangement produced an instantaneous decontamination factor of 41 or 97.6% removal compared to an instantaneous decontamination factor of 368 or 99.7% removal of the strontium with the POREX{reg_sign} MST and CST cartridge design placed in series. At high salt simulant conditions (5.6 M Na{sup +}), strontium removal with 3M-designed MST cartridge only and with 3M-designed MST and CST cartridges operated in a series configuration were identical. The instantaneous decontamination factor and the strontium removal efficiency, under the above configuration, averaged 8.6 and 88%, respectively. There were no POREX{reg_sign} cartridge experiments using the higher ionic strength simulant solution. At low salt simulant conditions, the uptake of Cs-137 with POREX{reg_sign} CST cartridge out performed the 3M-designed CST cartridges. The POREX{reg_sign} CST cartridge, with a Cs-137 instantaneous decontamination factor of 55 and a Cs-137 removal efficiency of 98% does meet the Cs-137 decontamination goals in the low salt simulant liquor. The Cs-137 removal with 3M-designed CST cartridge produced a decontamination factor of 2 or 49% removal efficiency. The Cs-137 performance graph for the 3M-designed CST cartridge showed an early cessation in the uptake of cesium-137. This behavior was not observed with the POREX{reg_sign} CST cartridges. No Cs-137 uptake tests were performed with the POREX{reg_sign} CST cartridges at high salt simulant conditions. The 3M-designed CST cartridges, with an instantaneous Cs-137 decontamination factor of less than 3 and a Cs-137 removal efficiency of less than 50% failed to meet the Cs-137 decontamination goals in both the low and high salt simulant liquors. This poor performance in the uptake of Cs-137 by the 3M CST cartridges may be attributed to fabrication flaws for the 3M-designed CST cartridges. The reduced number of CST membrane wraps per cartridge during the cartridge design phase, from 3-whole wraps to about 1.5, may have contributed to Cs-137 laden simulant channeling/by-pass which led to the poor performance in terms of Cs-137 sorption characteristics for the 3M designed CST cartridges. The grinding of CST ion exchange materials, to reduce the particle size distribution and thus enhance their easy incorporation into the filter membranes and the co-sintering of MST with polyethylene particles, did not adversely affect the sorption kinetics of both CST and MST in the uptake of Cs-137 and Sr-85, respectively. In general, the POREX{reg_sign} based cartridges showed more resistance to simulant flow through the filter cartridges as evidenced by higher pressure differences across the cartridges. Based on these findings they conclude that incorporating MST and CST sorbents into filter membranes represent a promising method for the semi-continuous removal of radioisotopes of strontium a

  20. System for removing contaminants from plastic resin

    DOE Patents [OSTI]

    Bohnert, George W. (Harrisonville, MO); Hand, Thomas E. (Lee's Summit, MO); DeLaurentiis, Gary M. (Jamestown, CA)

    2010-11-23T23:59:59.000Z

    A resin recycling system that produces essentially contaminant-free synthetic resin material in an environmentally safe and economical manner. The system includes receiving the resin in container form. A grinder grinds the containers into resin particles. The particles are exposed to a solvent in one or more solvent wash vessels, the solvent contacting the resin particles and substantially removing contaminants on the resin particles. A separator is used to separate the resin particles and the solvent. The resin particles are then placed in solvent removing element where they are exposed to a solvent removing agent which removes any residual solvent remaining on the resin particles after separation.

  1. Calcite dissolution and Ca/Na ion-exchange reactions in columns with different flow rates through high ESR soil

    E-Print Network [OSTI]

    Navarre, Audrey

    1999-01-01T23:59:59.000Z

    The leaching of a Na?-affected calcareous soil with water results in two concurrent recesses: (i) CaCO? dissolution, and (ii) replacement of Na? on the cation-exchange complex by Ca²?. In the current study, Woodward soil (coarse-silty, mixed...

  2. Calcite dissolution and Ca/Na ion-exchange reactions in columns with different flow rates through high ESR soil 

    E-Print Network [OSTI]

    Navarre, Audrey

    1999-01-01T23:59:59.000Z

    The leaching of a Na?-affected calcareous soil with water results in two concurrent recesses: (i) CaCO? dissolution, and (ii) replacement of Na? on the cation-exchange complex by Ca²?. In the current study, Woodward soil (coarse-silty, mixed...

  3. Recovery of uranium from seawater; 15: Development of amidoxime resins with high sedimentation velocity for passively driver fluidized bed adsorbers

    SciTech Connect (OSTI)

    Egawa, Hiroaki; Kabay, N.; Jyo, A.; Hirono, Masaki; Shuto, Taketomi (Kumamoto Univ. (Japan). Dept. of Applied Chemistry)

    1994-03-01T23:59:59.000Z

    In order to design the amidoxime resins (RNH) suitable for circulating fluidized bed adsorbers, RNH were prepared from precursory acrylonitrile-divinylbenzene copolymer beads of different particle sizes, and chemical and physical properties of the resulting RNH were evaluated. Specific surface areas, pore structures, swelling ratios, and anion and cation-exchange capacities of RNH are little affected by the particle size, while their sedimentation velocities in water increase with an increase in particle size as expected from fluid dynamics. Although the uptake of uncomplexed uranyl ion from a uranyl nitrate solution (0.01 M) was not influenced by the particle size, the uranium uptake from seawater decreases with an increase in the particle size, indicating that the particle diffusion of the bulky complexed species UO[sub 2](CO[sub 3])[sub 3][sup 4[minus

  4. EVALUATION OF POTENTIAL ELUANTS FOR NON-ACID ELUTION OF CESIUM FROM SPHERICAL RESORCINOL-FORMALDEHYDE RESIN

    SciTech Connect (OSTI)

    Adu-Wusu, K.; Nash, C.; Pennebaker, F.

    2011-10-23T23:59:59.000Z

    Ion Exchange column loading and elution of cesium from spherical resorcinol-formaldehyde resin have been conducted for two potential non-acid eluants -(NH{sub 4}){sub 2}CO{sub 3} and CH{sub 3}COONH{sub 4}. The results revealed encouraging cesium elution performance. 100% elution was achieved in at most 22 hours ({approx}28 bed volumes) of elution. Elution performance was fairly high at 6 hours ({approx}8 bed volumes) of elution for some of the eluants and also practically comparable to the benchmark acid eluant (HNO{sub 3}). Hence, it is quite possible 100% percent elution will be closer to the 6th hour than the 22nd hour. Elution is generally enhanced by increasing the concentration and pH of the eluants, and combining the eluants.

  5. Chromatography resin support

    DOE Patents [OSTI]

    Dobos, James G. (North Augusta, SC)

    2002-01-01T23:59:59.000Z

    An apparatus and method of using an improved chromatography resin support is disclosed. The chromatography support platform is provided by a stainless steel hollow cylinder adapted for being inserted into a chromatography column. An exterior wall of the stainless steel cylinder defines a groove for carrying therein an "O"-ring. The upper surface of the stainless steel column is covered by a fine stainless steel mesh welded to the edges of the stainless steel cylinder. When placed upon a receiving ledge defined within a chromatography column, the "O"-ring provides a fluid tight seal with the inner edge wall of the chromatography cylinder. The stainless steel mesh supports the chromatography matrix and provides a back flushable support which is economical and simple to construct.

  6. Synthesis and Evaluation of Cu/SAPO-34 Catalysts for NH3-SCR 2: Solid-state Ion Exchange and One-pot Synthesis

    SciTech Connect (OSTI)

    Gao, Feng; Walter, Eric D.; Washton, Nancy M.; Szanyi, Janos; Peden, Charles HF

    2015-01-01T23:59:59.000Z

    Cu-SAPO-34 catalysts are synthesized using two methods: solid-state ion exchange (SSIE) and one-pot synthesis. SSIE is conducted by calcining SAPO-34/CuO mixtures at elevated temperatures. For the one-pot synthesis method, Cu-containing chemicals (CuO and CuSO4) are added during gel preparation. A high-temperature calcination step is also needed for this method. Catalysts are characterized with surface area/pore volume measurements, temperature programmed reduction (TPR), electron paramagnetic resonance (EPR) and nuclear magnetic resonance (NMR) spectroscopies, and scanning electron microscopy (SEM). Catalytic properties are examined using standard ammonia selective catalytic reduction (NH3-SCR) and ammonia oxidation reactions. In Cu-SAPO-34 samples formed using SSIE, Cu presents both as isolated Cu2+ ions and unreacted CuO. The former is highly active and selective in NH3-SCR, while the latter catalyzes a side reaction; notably, the non-selective oxidation of NH3 above 350 ºC. Using the one-pot method followed by a high-temperature aging treatment, it is possible to form Cu SAPO-34 samples with predominately isolated Cu2+ ions at low Cu loadings. However at much higher Cu loadings, isolated Cu2+ ions that bind weakly with the CHA framework and CuO clusters also form. These Cu moieties are very active in catalyzing non-selective NH3 oxidation above 350 ºC. Low-temperature reaction kinetics indicate that Cu-SAPO-34 samples formed using SSIE have core-shell structures where Cu is enriched in the shell layers; while Cu is more evenly distributed within the one-pot samples. Reaction kinetics also suggest that at low temperatures, the local environment next to Cu2+ ion centers plays little role on the overall catalytic properties. The authors gratefully acknowledge the US Department of Energy (DOE), Energy Efficiency and Renewable Energy, Vehicle Technologies Office for the support of this work. The research described in this paper was performed at the Environmental Molecular Sciences Laboratory (EMSL), a national scientific user facility sponsored by the DOE’s Office of Biological and Environmental Research and located at Pacific Northwest National Laboratory (PNNL). PNNL is operated for the US DOE by Battelle under contract number DE-AC05-76RL01830. The authors also thank Shari Li (PNNL) for surface area/pore volume measurements, and Bruce W. Arey (PNNL) for SEM measurements. Discussions with Drs. A. Yezerets, K. Kamasamudram, J.H. Li, N. Currier and J.Y. Luo from Cummins, Inc. and H.Y. Chen and H. Hess from Johnson-Matthey are greatly appreciated.

  7. Retrofit for Plastic Resin Driers

    E-Print Network [OSTI]

    Joseph, B.; Thuro, G.

    RETROFIT FOR PLASTIC RESIN DRIERS BABU JOSEPH PH.D. Supervising Engineer Southern California Edison Company, Irwindale, California GEORGE THURO Thuro, & Associates, Costa Mesa, California Plastic resins used in injection molding have... installation of dew point meters and a programmable controller to tailor the regeneration cycle to the required dew point temperature. Background It was estimated that there are about 450 plastic processors in the Southern California Edison service...

  8. Liquid monobenzoxazine based resin system

    DOE Patents [OSTI]

    Tietze, Roger; Nguyen, Yen-Loan; Bryant, Mark

    2014-10-07T23:59:59.000Z

    The present invention provides a liquid resin system including a liquid monobenzoxazine monomer and a non-glycidyl epoxy compound, wherein the weight ratio of the monobenzoxazine monomer to the non-glycidyl epoxy compound is in a range of about 25:75 to about 60:40. The liquid resin system exhibits a low viscosity and exceptional stability over an extended period of time making its use in a variety of composite manufacturing methods highly advantageous.

  9. Dissolution of mega-voids in resin transfer molding

    E-Print Network [OSTI]

    Clark, Paul Nordstrom

    2007-01-01T23:59:59.000Z

    of Gas Bubbles in an Epoxy Resin: Evaluating the Inputof Gas Bubbles in an Epoxy Resin: Evaluating the Inputin panel mold Item: Epoxy resin and hardener Manufacturer:

  10. IMPACTS OF SMALL COLUMN ION EXCHANGE STREAMS ON DWPF GLASS FORMULATION: KT01, KT02, KT03, AND KT04-SERIES GLASS COMPOSITIONS

    SciTech Connect (OSTI)

    Fox, K.; Edwards, T.

    2010-11-01T23:59:59.000Z

    Four series of glass compositions were selected, fabricated, and characterized as part of a study to determine the impacts of the addition of Crystalline Silicotitanate (CST) and Monosodium Titanate (MST) from the Small Column Ion Exchange (SCIX) process on the Defense Waste Processing Facility (DWPF) glass waste form and the applicability of the DWPF process control models. The KT01 and KT02-series of glasses were chosen to allow for the identification of the influence of the concentrations of major components of the glass on the retention of TiO{sub 2}. The KT03 series of glasses was chosen to allow for the identification of these influences when higher Nb{sub 2}O{sub 5} and ZrO{sub 2} concentrations are included along with TiO2. The KT04 series of glasses was chosen to investigate the properties and performance of glasses based on the best available projections of actual compositions to be processed at the DWPF (i.e., future sludge batches including the SCIX streams).

  11. Electronically and ionically conductive porous material and method for manufacture of resin wafers therefrom

    DOE Patents [OSTI]

    Lin, YuPo J. (Naperville, IL); Henry, Michael P. (Batavia, IL); Snyder, Seth W. (Lincolnwood, IL)

    2008-11-18T23:59:59.000Z

    An electrically and ionically conductive porous material including a thermoplastic binder and one or more of anion exchange moieties or cation exchange moieties or mixtures thereof and/or one or more of a protein capture resin and an electrically conductive material. The thermoplastic binder immobilizes the moieties with respect to each other but does not substantially coat the moieties and forms the electrically conductive porous material. A wafer of the material and a method of making the material and wafer are disclosed.

  12. Electronically and ionically conductive porous material and method for manufacture of resin wafers therefrom

    DOE Patents [OSTI]

    Lin, YuPo J. (Naperville, IL); Henry, Michael P. (Batavia, IL); Snyder, Seth W. (Lincolnwood, IL)

    2011-07-12T23:59:59.000Z

    An electrically and ionically conductive porous material including a thermoplastic binder and one or more of anion exchange moieties or cation exchange moieties or mixtures thereof and/or one or more of a protein capture resin and an electrically conductive material. The thermoplastic binder immobilizes the moieties with respect to each other but does not substantially coat the moieties and forms the electrically conductive porous material. A wafer of the material and a method of making the material and wafer are disclosed.

  13. Method of removing contaminants from plastic resins

    DOE Patents [OSTI]

    Bohnert, George W. (Harrisonville, MO); Hand, Thomas E. (Lee's Summit, MO); DeLaurentiis, Gary M. (Jamestown, CA)

    2008-11-18T23:59:59.000Z

    A method for removing contaminants from synthetic resin material containers using a first organic solvent system and a second carbon dioxide system. The organic solvent is utilized for removing the contaminants from the synthetic resin material and the carbon dioxide is used to separate any residual organic solvent from the synthetic resin material.

  14. Method for removing contaminants from plastic resin

    DOE Patents [OSTI]

    Bohnert, George W. (Harrisonville, MO); Hand, Thomas E. (Lee's Summit, MO); DeLaurentiis, Gary M. (Jamestown, CA)

    2008-12-30T23:59:59.000Z

    A method for removing contaminants from synthetic resin material containers using a first organic solvent system and a second carbon dioxide system. The organic solvent is utilized for removing the contaminants from the synthetic resin material and the carbon dioxide is used to separate any residual organic solvent from the synthetic resin material.

  15. Method of removing contaminants from plastic resins

    DOE Patents [OSTI]

    Bohnert,George W. (Harrisonville, MO); Hand,Thomas E. (Lee's Summit, MO); Delaurentiis,Gary M. (Jamestown, CA)

    2007-08-07T23:59:59.000Z

    A method for removing contaminants from synthetic resin material containers using a first organic solvent system and a second carbon dioxide system. The organic solvent is utilized for removing the contaminants from the synthetic resin material and the carbon dioxide is used to separate any residual organic solvent from the synthetic resin material.

  16. Enhancement of exchange bias and training effect in ion-beam sputtered Fe{sub 46}Mn{sub 54}/Ni{sub 81}Fe{sub 19} bilayers

    SciTech Connect (OSTI)

    Fulara, Himanshu; Chaudhary, Sujeet, E-mail: sujeetc@physics.iitd.ac.in; Kashyap, Subhash C. [Thin Film Laboratory, Department of Physics, Indian Institute of Technology Delhi, New Delhi 110016 (India); Granville, Simon [Callaghan Innovation, PO Box 31310, Lower Hutt 5040 (New Zealand); The MacDiarmid Institute for Advanced Materials and Nanotechnology, Lower Hutt (New Zealand)

    2014-01-28T23:59:59.000Z

    We present a remarkable enhancement by 300% of the exchange-bias field at room temperature, without affecting the coercivity value, via optimum magnetic annealing (250?°C/3 kOe) in ion-beam sputtered FeMn(30?nm)/NiFe(10?nm) bilayers. This specific behavior has been attributed to a higher degree of ?-FeMn(111) orientation that offers more interfacial FeMn moments to get pinned with the moments of the adjacent NiFe layer. Unlike the absence of training effect at room temperature, a pronounced training effect and an accompanying magnetization reversal asymmetry are evidenced upon field cooling below 50?K due to the presence of biaxial exchange induced anisotropy across the interdiffused FeMn/NiFe interface. The present findings not only have technological significance but also are of relevance to the understanding of interfacial spin disorder and frustration in these exchange-biased systems.

  17. Anion exchange membrane

    DOE Patents [OSTI]

    Verkade, John G; Wadhwa, Kuldeep; Kong, Xueqian; Schmidt-Rohr, Klaus

    2013-05-07T23:59:59.000Z

    An anion exchange membrane and fuel cell incorporating the anion exchange membrane are detailed in which proazaphosphatrane and azaphosphatrane cations are covalently bonded to a sulfonated fluoropolymer support along with anionic counterions. A positive charge is dispersed in the aforementioned cations which are buried in the support to reduce the cation-anion interactions and increase the mobility of hydroxide ions, for example, across the membrane. The anion exchange membrane has the ability to operate at high temperatures and in highly alkaline environments with high conductivity and low resistance.

  18. SELECTIVE REMOVAL OF STRONTIUM AND CESIUM FROM SIMULATED WASTE SOLUTION WITH TITANATE ION-EXCHANGERS IN A FILTER CARTRIDGE CONFIGURATIONS-12092

    SciTech Connect (OSTI)

    Oji, L.; Martin, K.; Hobbs, D.

    2011-11-10T23:59:59.000Z

    Experimental results for the selective removal of strontium and cesium from simulated waste solutions with monosodium titanate (MST) and crystalline silicotitanate (CST) laden filter cartridges are presented. In these proof-of-principle tests, effective uptake of both Sr-85 and Cs-137 were observed using ion-exchangers in this filter cartridge configuration. At low salt simulant conditions, the instantaneous decontamination factor (D{sub F}) for Sr-85 with MST impregnated filter membrane cartridges measured 26, representing 96% Sr-85 removal efficiency. On the other hand, the Sr-85 instantaneous D{sub F} with co-sintered active MST cartridges measured 40 or 98% Sr-85 removal efficiency. Strontium-85 removal with the MST impregnated membrane cartridges and CST impregnated membrane cartridges, placed in series arrangement, produced an instantaneous decontamination factor of 41 compared to an instantaneous decontamination factor of 368 for strontium-85 with co-sintered active MST cartridges and co-sintered active CST cartridges placed in series. Overall, polyethylene co-sintered active titanates cartridges performed as well as titanate impregnated filter membrane cartridges in the uptake of strontium. At low ionic strength conditions, there was a significant uptake of Cs-137 with co-sintered CST cartridges. Tests results with CST impregnated membrane cartridges for Cs-137 decontamination are currently being re-evaluated. Based on these preliminary findings we conclude that incorporating MST and CST sorbents into membranes represent a promising method for the semi-continuous removal of radioisotopes of strontium and cesium from nuclear waste solutions.

  19. SELECTIVE REMOVAL OF STRONTIUM AND CESIUM FROM SIMULATED WASTE SOLUTION WITH TITANATE ION-EXCHANGERS IN A FILTER CARTRIDGE CONFIGURATIONS-12092

    SciTech Connect (OSTI)

    Oji, L.; Martin, K.; Hobbs, D.

    2012-01-03T23:59:59.000Z

    Experimental results for the selective removal of strontium and cesium from simulated waste solutions with monosodium titanate and crystalline silicotitanate laden filter cartridges are presented. In these proof-of-principle tests, effective uptake of both strontium-85 and cesium-137 were observed using ion-exchangers in this filter cartridge configuration. At low salt simulant conditions, the instantaneous decontamination factor for strontium-85 with monosodium titanate impregnated filter membrane cartridges measured 26, representing 96% strontium-85 removal efficiency. On the other hand, the strontium-85 instantaneous decontamination factor with co-sintered active monosodium titanate cartridges measured 40 or 98% Sr-85 removal efficiency. Strontium-85 removal with the monosodium titanate impregnated membrane cartridges and crystalline silicotitanate impregnated membrane cartridges, placed in series arrangement, produced an instantaneous decontamination factor of 41 compared to an instantaneous decontamination factor of 368 for strontium-85 with co-sintered active monosodium titanate cartridges and co-sintered active crystalline silicotitanate cartridges placed in series. Overall, polyethylene co-sintered active titanates cartridges performed as well as titanate impregnated filter membrane cartridges in the uptake of strontium. At low ionic strength conditions, there was a significant uptake of cesium-137 with co-sintered crystalline silicotitanate cartridges. Tests results with crystalline silicotitanate impregnated membrane cartridges for cesium-137 decontamination are currently being re-evaluated. Based on these preliminary findings we conclude that incorporating monosodium titanate and crystalline silicotitanate sorbents into membranes represent a promising method for the semicontinuous removal of radioisotopes of strontium and cesium from nuclear waste solutions.

  20. anion exchange resins: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    interfacial area, of an aging asphalteneresin model oil droplet, displacing the asphaltenes and reducing the stability and the dilatational elasticity. 1. Introduction Water...

  1. anion exchange resin: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    interfacial area, of an aging asphalteneresin model oil droplet, displacing the asphaltenes and reducing the stability and the dilatational elasticity. 1. Introduction Water...

  2. acid exchange resins: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    interfacial area, of an aging asphalteneresin model oil droplet, displacing the asphaltenes and reducing the stability and the dilatational elasticity. 1. Introduction Water...

  3. DIVALENT ION EXCHANGE WITH ALKALI

    E-Print Network [OSTI]

    Bunge, A.L.

    2011-01-01T23:59:59.000Z

    and Imporved Drilling Methods, Tulsa, OK, Aug. 22-24, 1979.on Enhanced Oil Recovery, Tulsa, OK, Apri120-23, 1980.on Improved Oil Recovery, Tulsa, OK, March 22-24, Radke, C.

  4. Rapid gasification of nascent char in steam atmosphere during the pyrolysis of Na- and Ca-ion-exchanged brown coals in a drop-tube reactor

    SciTech Connect (OSTI)

    Ondej Maek; Sou Hosokai; Koyo Norinaga; Chun-Zhu Li; Jun-ichiro Hayashi [Hokkaido University, Kita-ku (Japan). Center for Advanced Research of Energy Conversion Materials

    2009-09-15T23:59:59.000Z

    Several recent studies on in situ steam gasification of coal suggest a possibility of extremely fast steam gasification of char from rapid pyrolysis of pulverized brown coal. The unprecedented rate of char steam gasification can be achieved by exposing nascent char, that is, after tar evolution (temperature range >600{sup o}C), but before devolatilization (<900{sup o}C), to steam in the presence of Na and/or Ca dispersed in/on the char. In this study, we conducted rapid pyrolysis experiments using ion-exchanged Loy Yang brown coal samples, that is, H-form coal with Na/Ca contents <0.001 wt %, Na-form coal with Na content = 2.8 wt % and Ca-form coal with Ca content = 3.2 wt %. These samples were pyrolyzed in an atmospheric drop-tube reactor at a temperature of 900{sup o}C, inlet steam concentration of 50 vol. %, and a particle residence times of 2.8 s. The char yields from the pyrolysis of Na-form and Ca-form coals were as low as 12 and 33% on the respective coal carbon bases, and accounted for only 18 and 53% of the char yields from the full devolatilization of the respective coals at 900{sup o}C. In addition, the pyrolysis also consumed as much as 0.7-1.1 mol of H{sub 2}O per mol of coal C. On the other hand, the nascent char from the H-form coal allowed carbon deposition from the nascent tar, resulting in a char yield as high as 115% of that from the full devolatilization. The chars from the Na-form and Ca-form coals also acted as catalysts for steam reforming of tar, which was evidenced by significant negative synergistic effects of blending of H-form coal with Na-form coal or Ca-form coal on the tar and soot yields. 57 refs., 6 figs.

  5. Ortho-ortho aramatic bis maleimide-diamine resin

    DOE Patents [OSTI]

    Zupancic, J.J.; Swedo, R.J.; Jamieson, D.R.; Schumacher, E.F.; Buehler, A.J.

    1991-06-18T23:59:59.000Z

    APO-BMI is a chain-extended with certain diamines to provide thermosetting resins retaining the improved properties of APO-BMI resins, but having increased toughness in the cured resins.

  6. NON-ISOTHERMAL INJECTION MOULDING WITH RESIN CURE AND PREFORM DEFORMABILITY

    E-Print Network [OSTI]

    Preziosi, Luigi

    Transfer Molding), SRIM (Structural Resin Injection Molding), SCRIMP (Seeman Com- posite Resin Infusion

  7. Guayule resin separation and purification

    E-Print Network [OSTI]

    Bajwa, Mohinder P.S.

    1992-01-01T23:59:59.000Z

    " capillary column and Hewlett-Packard "Ultra 1" capillary column. The detector fitted on our GC is the FID. The temperature program used is 60'C for the first minute, temperature rise at the rate of 15 C/min, and then 278'C for 12 minutes. The full details... on a Hewlett-Packard "Ultra I" capillary column, using an FID 20 22 24 25 27 34 35 36 37 39 16. GC of fraction "a" obtained in repeated polar-non-polar fractionation of the Firestone resins, analyzed on a "Supelcowax 10" capillary column...

  8. acrylic resin denture: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    39 ANALYSIS OF CYANATE ESTER RESINS AND GRAPHITE FABRIC FOR USE IN RESIN FILM INFUSION PROCESSING CiteSeer Summary: The objective of this investigation was to characterize...

  9. Treatment Resin Reduces Costs, Materials in Hanford Groundwater...

    Office of Environmental Management (EM)

    Treatment Resin Reduces Costs, Materials in Hanford Groundwater Cleanup - Efficiency delivered more than 6 million in cost savings, 3 million in annual savings Treatment Resin...

  10. Fluorinated diamond bonded in fluorocarbon resin

    DOE Patents [OSTI]

    Taylor, Gene W. (Los Alamos, NM)

    1982-01-01T23:59:59.000Z

    By fluorinating diamond grit, the grit may be readily bonded into a fluorocarbon resin matrix. The matrix is formed by simple hot pressing techniques. Diamond grinding wheels may advantageously be manufactured using such a matrix. Teflon fluorocarbon resins are particularly well suited for using in forming the matrix.

  11. Modified resins for solid-phase extraction

    DOE Patents [OSTI]

    Fritz, James S. (Ames, IA); Sun, Jeffrey J. (Ames, IA)

    1993-07-27T23:59:59.000Z

    A process of treating aqueous solutions to remove organic solute contaminants by contacting an aqueous solution containing polar organic solute contaminants with a functionalized polystyrene-divinyl benzene adsorbent resin, with the functionalization of said resin being accomplished by organic hydrophilic groups such as hydroxymethyl, acetyl and cyanomethyl.

  12. Modified resins for solid-phase extraction

    DOE Patents [OSTI]

    Fritz, James S. (Ames, IA); Sun, Jeffrey J. (Ames, IA)

    1991-12-10T23:59:59.000Z

    A process of treating aqueous solutions to remove organic solute contaminants by contacting an aqueous solution containing polar organic solute contaminants with a functionalized polystyrene-divinyl benzene adsorbent resin, with the functionalization of said resin being accomplished by organic hydrophilic groups such as hydroxymethyl, acetyl and cyanomethyl.

  13. IMPACTS OF SMALL COLUMN ION EXCHANGE STREAMS ON DWPF GLASS FORMULATION: KT08, KT09, AND KT10-SERIES GLASS COMPOSITIONS

    SciTech Connect (OSTI)

    Fox, K.; Edwards, T.

    2011-04-26T23:59:59.000Z

    This report is the fourth in a series of studies of the impacts of the addition of Crystalline Silicotitanate (CST) and Monosodium Titanate (MST) from the Small Column Ion Exchange (SCIX) process on the Defense Waste Processing Facility (DWPF) glass waste form and the applicability of the DWPF process control models. MST from the Salt Waste Processing Facility (SWPF) is also considered in the study. The KT08-series of glasses was designed to evaluate any impacts of the inclusion of uranium and thorium in glasses containing the SCIX components. The KT09-series of glasses was designed to study the effect of increasing Al{sub 2}O{sub 3} and K{sub 2}O concentrations on the propensity for crystallization of titanium containing phases in high TiO{sub 2} concentration glasses. Earlier work on the KT05-series glasses recommended that the impact of these two components be studied further. Increased Al{sub 2}O{sub 3} concentrations have been shown to improve the properties and performance of high waste loading glasses, and K{sub 2}O has been reported to improve the retention of TiO{sub 2} in silicate glasses. The KT10-series of compositions was designed to evaluate any impacts of the SCIX components at concentrations 50% higher than currently projected.a The glasses were fabricated in the laboratory and characterized to identify crystallization, to verify chemical compositions, to measure viscosity, and to measure durability. Liquidus temperature measurements for the KT10-series glasses are underway and will be reported separately. All but one of the KT08-series glasses were found to be amorphous by X-ray diffraction (XRD). One of the slowly cooled glasses contained a small amount of trevorite, which had no practical impact on the durability of the glass and is typically found in DWPF-type glasses. The measured Product Consistency Test (PCT) responses for the KT08-series glasses are well predicted by the DWPF models. The viscosities of the KT08-series glasses were generally well predicted by the DWPF model. No unexpected issues were encountered when uranium and thorium were added to the glasses with SCIX components. Increased Al{sub 2}O{sub 3} concentrations were not successful in preventing the formation of iron titanate crystals in the KT09-series glasses. Increased K{sub 2}O concentrations were successful in hindering the formation of iron titanates in some of the glasses after the canister centerline cooled (CCC) heat treatment. However, this result did not apply to all of the CCC versions of the glasses, indicating a compositional dependence of this effect. In addition, high concentrations of K{sub 2}O have been shown to hinder the ability of the DWPF durability and viscosity models to predict the performance of these glasses. The usefulness of increased K{sub 2}O concentrations in preventing the formation of iron titanates may therefore be limited. Further characterization was not performed for the KT09-series glasses since the type of crystallization formed was the characteristic of interest for these compositions. All of the KT10-series glasses were XRD amorphous, regardless of heat treatment. Chemical composition measurements showed that the glasses met the targeted concentrations for each oxide. In general, the measured PCT responses of the KT10-series glasses were well predicted by the DWPF models. The measured, normalized release values for silicon for some of the glasses fell above the 95% confidence interval for the predicted values; however, the PCT responses for these glasses remain considerably lower than that of the benchmark Environmental Assessment (EA) glass. The viscosities of the KT10-series glasses were generally well predicted by the DWPF model. The next step in this study will be to compile all of the data developed and further compare the measured properties and performance with those predicted by the current DWPF Product Composition Control System (PCCS) models. Recommendations will then be made as to which models, if any, may need to be modified in order to accommodate the material from SCIX into DWPF

  14. Charm and bottom production in inclusive double Pomeron exchange in heavy-ion collisions at energies available at the CERN Large Hadron Collider

    SciTech Connect (OSTI)

    Gay Ducati, M. B.; Machado, M. M.; Machado, M. V. T. [High Energy Physics Phenomenology Group, GFPAE, IF-UFRGS Caixa Postal 15051, CEP 91501-970, Porto Alegre, RS (Brazil)

    2011-01-15T23:59:59.000Z

    The inclusive double Pomeron exchange cross section for heavy-quark pair production is calculated for nucleus-nucleus collisions at the Large Hadron Collider. The present estimate is based on hard diffractive factorization, corrected by absorptive corrections and nuclear effects. The theoretical uncertainties for nuclear collisions are investigated and a comparison to other approaches is presented. The production channels giving a similar final state configuration are discussed as well.

  15. Complexation of the uranyl ion with the aminomethylenediphosphonates MAMDP and AMDP

    SciTech Connect (OSTI)

    Bollinger, J.E.; Roundhill, D.M. [Tulane Univ., New Orleans, LA (United States)

    1994-12-21T23:59:59.000Z

    The use of uranium as a nuclear energy source has made it a valuable mineral resource over the past forty years. Processing uranium generally involves leaching the metal as the uranyl ion (UO{sub 2}){sup 2+} from ore, followed by solvent extraction, precipitation or batch adsorption onto ion exchange-type resins. Uranium reserves exist also in the form of UO{sub 2}(CO{sub 3}){sub 3}{sup 4{minus}} dissolved in seawater, and although these concentrations are very low they represent globally some 4.9 x 10{sup 9} tons. In the interest of tapping this resource efforts toward developing more efficient and selective means of UO{sub 2}{sup 2+} ion sequestering have been underway for some time. The authors have measured the stability and protonation constants of the different complexes formed in aqueous solution between the UO{sub 2}{sup 2+} ion and the compounds N,N{prime}-dimethylaminomethylenebis(phosphonic acid) (MAMDP) and aminomethylenebis(phosphonic acid) (AMDP). From these data one can evaluate the potential for compounds of this type to be useful as uranyl ion sequestering agents.

  16. Ion-exchanged pillared clays: A new class of catalysts for selective catalytic reduction of NO by hydrocarbons and by ammonia

    SciTech Connect (OSTI)

    NONE

    1995-09-01T23:59:59.000Z

    Selective catalytic reduction (SCR) of NO by NH{sub 3} is presently performed with vanadia-based catalysts for flue gas applications. Hydrocarbons would be the preferred reducing agents over NH{sub 3} because of the practical problems associated with the use of NH{sub 3} (i.e., handling and slippage through the reactor). SCR of NO by hydrocarbons can also find important applications for lean-burn (i.e., O{sub 2}-rich) gasoline and diesel engines where the noble-metal three-way catalysts are not effective in the presence of excess oxygen. Pillared interlayered clays (PILCs) have been studied extensively for a number of catalyzed reactions. We have found high activities of PILCs for SCR of NO by NH{sub 3} (26.28). Pillared clays have considerable Bronsted acidity (27, 28), and the protons can be exchanged with metal cations. The Bronsted acidity of TiO{sub 2}-PILC, in particular, remains high after heat treatment at temperatures as high as 400{degrees}C (27-29). In this note, we report first results on the activities of cation-exchanged pillared clays for SCR of NO by both hydrocarbon and NH{sub 3}. 37 refs., 3 figs.

  17. Production of sodium-22 from proton irradiated aluminum

    DOE Patents [OSTI]

    Taylor, Wayne A. (Los Alamos, NM); Heaton, Richard C. (Los Alamos, NM); Jamriska, David J. (Los Alamos, NM)

    1996-01-01T23:59:59.000Z

    A process for selective separation of sodium-22 from a proton irradiated minum target including dissolving a proton irradiated aluminum target in hydrochloric acid to form a first solution including aluminum ions and sodium ions, separating a portion of the aluminum ions from the first solution by crystallization of an aluminum salt, contacting the remaining first solution with an anion exchange resin whereby ions selected from the group consisting of iron and copper are selectively absorbed by the anion exchange resin while aluminum ions and sodium ions remain in solution, contacting the solution with an cation exchange resin whereby aluminum ions and sodium ions are adsorbed by the cation exchange resin, and, contacting the cation exchange resin with an acid solution capable of selectively separating the adsorbed sodium ions from the cation exchange resin while aluminum ions remain adsorbed on the cation exchange resin is disclosed.

  18. Resin-assisted enrichment of thios as a general strategy for proteomic profiling of cysteine-based reversible modifications

    SciTech Connect (OSTI)

    Guo, Jia; Gaffrey, Matthew J.; Su, Dian; Liu, Tao; Camp, David G.; Smith, Richard D.; Qian, Weijun

    2014-01-01T23:59:59.000Z

    Reversible modifications on cysteine thiols play a significant role in redox signaling and regulation. A number of reversible redox modifications, including disulfide formation, S-nitrosylation, and S-glutathionylation, have been recognized for their significance in various physiological and pathological processes. Here we describe in detail a resin-assisted thiol-affinity enrichment protocol for both biochemical and proteomics applications. This protocol serves as a general approach for specific isolation of thiol-containing proteins or peptides derived from reversible redox-modified proteins. This approach utilizes thiol-affinity resins to directly capture thiol-containing proteins or peptides through a disulfide exchange reaction followed by on-resin protein digestion and on-resin multiplexed isobaric labeling to facilitate LC?MS/MS based quantitative site-specific analysis of redox modifications. The overall approach requires a much simpler workflow with increased specificity compared to the commonly used biotin switch technique. By coupling different selective reduction strategies, the resin-assisted approach provides the researcher with a useful tool capable of enriching different types of reversible modifications on protein thiols. Procedures for selective enrichment and analyses of S-nitrosylation and total reversible cysteine oxidation are presented to demonstrate the utility of this general strategy.

  19. Viscoelastic Properties of an Epoxy Resin during Cure

    E-Print Network [OSTI]

    Mather, Patrick T.

    Viscoelastic Properties of an Epoxy Resin during Cure DANIEL J. O'BRIEN1 Department of Mechanical: The cure dependent relaxation modulus of an epoxy resin was investigated over the entire range of cure as well as thermal asymmetry can result in uneven curing of the part. Second, epoxy resins can shrink

  20. Exchange effects in magnetized quantum plasmas

    E-Print Network [OSTI]

    Trukhanova, Mariya Iv

    2015-01-01T23:59:59.000Z

    We apply the many-particle quantum hydrodynamics including the Coulomb exchange interaction to magnetized quantum plasmas. We consider a number of wave phenomenon under influence of the Coulomb exchange interaction. Since the Coulomb exchange interaction affects longitudinal and transverse-longitudinal waves we focus our attention to the Langmuir waves, Trivelpiece-Gould waves, ion-acoustic waves in non-isothermal magnetized plasmas, the dispersion of the longitudinal low-frequency ion-acoustic waves and low-frequencies electromagnetic waves at $T_{e}\\gg T_{i}$ . We obtained the numerical simulation of the dispersion properties of different types of waves.

  1. Characterization of Group V Dubnium Homologs on DGA Extraction Chromatography Resin from Nitric and Hydrofluoric Acid Matrices

    SciTech Connect (OSTI)

    Despotopulos, J D; Sudowe, R

    2012-02-21T23:59:59.000Z

    Studies of the chemical properties of superheavy elements (SHE) pose interesting challenges due to their short half-lives and low production rates. Chemical systems must have extremely fast kinetics, fast enough kinetics to be able to examine the chemical properties of interest before the SHE decays to another nuclide. To achieve chemistry on such time scales, the chemical system must also be easily automated. Most importantly however, a chemical system must be developed which provides suitable separation and kinetics before an on-line study of a SHE can be performed. Relativistic effects make studying the chemical properties of SHEs interesting due to the impact these effects could have on the SHEs chemical properties. Relativistic effects arise when the velocity of the s orbital electrons approach the speed of light. As this velocity increases, the Bohr radius of the inner electron orbitals decreases and there is an increase in the particles mass. This contraction results in a destabilization of the energy of the outer d and f electron orbitals (5f and 6d in the case of SHE), which can cause these to expand due to their increased shielding from the nuclear charge. Another relativistic effect is the spin-orbit splitting for p, d, and f orbitals into j = 1 {+-} 1/2 states. This can lead most interestingly to a possible increased stability of element 114, which due to large spin-orbit splitting of the 7p orbital and the relativistically stabilized 7p{sub 1/2} and 7s orbital gives rise to a closed shell ground state of 7s{sup 2}7p{sub 1/2}{sup 2}. The homologs of element 105, dubnium (Db), Ta and Nb and the pseudo-homolog Pa, are well known to hydrolyze and form both neutral and non-neutral monoatomic and polyatomic species that may cause issues with extraction from a given chemical system. Early ion-exchange and solvent-extraction studies show mixed results for the behavior of Db. Some studies show Db behaving most similar to Ta, while others show it behaving somewhere between Nb and Pa. Much more recent studies have examined the properties of Db from HNO{sub 3}/HF matrices, and suggest Db forms complexes similar to those of Pa. Very little experimental work into the behavior of element 114 has been performed. Thermochromatography experiments of three atoms of element 114 indicate that the element 114 is at least as volatile as Hg, At, and element 112. Lead was shown to deposit on gold at temperatures about 1000 C higher than the atoms of element 114. Results indicate a substantially increased stability of element 114. No liquid phase studies of element 114 or its homologs (Pb, Sn, Ge) or pseudo-homologs (Hg, Cd) have been performed. Theoretical predictions indicate that element 114 is should have a much more stable +2 oxidation state and neutral state than Pb, which would result in element 114 being less reactive and less metallic than Pb. The relativistic effects on the 7p{sub 1/2} electrons are predicted to cause a diagonal relationship to be introduced into the periodic table. Therefore, 114{sup 2+} is expected to behave as if it were somewhere between Hg{sup 2+}, Cd{sup 2+}, and Pb{sup 2+}. In this work two commercially available extraction chromatography resins are evaluated, one for the separation of Db homologs and pseudo?homologs from each other as well as from potential interfering elements such as Group IV Rf homologs and actinides, and the other for separation of element 114 homologs. One resin, Eichrom's DGA resin, contains a N,N,N',N'-tetra-n-octyldiglycolamide extractant, which separates analytes based on both size and charge characteristics of the solvated metal species, coated on an inert support. The DGA resin was examined for Db chemical systems, and shows a high degree of selectivity for tri-, tetra-, and hexavalent metal ions in multiple acid matrices with fast kinetics. The other resin, Eichrom's Pb resin, contains a di-t-butylcyclohexano 18-crown-6 extractant with isodecanol solvent, which separates analytes based on steric interactions between the cavity of the crown ether and electrostatic interac

  2. Method for detecting resin leakage in LWR coolant

    SciTech Connect (OSTI)

    Girard, J.E.

    1988-05-01T23:59:59.000Z

    Resin leakage from condensate polishing units can result in steam generator corrosion. This report describes the development of a resin leakage detection method based in analyzing the organic breakdown products released from resin on heating. The breakdown products are analyzed using high performance liquid chromatography (HPLC) with fluorescence detection. Some of the organic products formed have been identified. A design for a resin monitoring unit, suitable for incorporation into the IONTRAC system, is presented. Theoretically, detection of ppB levels of resin by processing about one liter of water, is possible.

  3. Electrically conductive resinous bond and method of manufacture

    DOE Patents [OSTI]

    Snowden, Jr., Thomas M. (P.O. Box 4231, Clearwater, FL 33518); Wells, Barbara J. (865 N. Village Dr., Apt. 101B, St. Petersburg, FL 33702)

    1987-01-01T23:59:59.000Z

    A method of bonding elements together with a bond of high strength and good electrical conductivity which comprises: applying an unfilled polyimide resin between surfaces of the elements to be bonded, heat treating said unfilled polyimide resin in stages between a temperature range of about 40.degree. to 365.degree. C. to form a strong adhesive bond between said elements, applying a metal-filled polyimide resin overcoat between said elements so as to provide electrical connection therebetween, and heat treating said metal-filled polyimide resin with substantially the same temperature profile as the unfilled polyimide resin. The present invention is also concerned with an adhesive, resilient, substantially void free bonding combination for providing a high strength, electrically conductive adhesive attachment between electrically conductive elements which comprises a major amount of an unfilled polyimide resin and a minor amount of a metal-filled polyimide resin.

  4. Electrically conductive resinous bond and method of manufacture

    DOE Patents [OSTI]

    Snowden, T.M. Jr.; Wells, B.J.

    1985-01-01T23:59:59.000Z

    A method of bonding elements together with a bond of high strength and good electrical conductivity which comprises: applying an unfilled polyimide resin between surfaces of the elements to be bonded, heat treating said unfilled polyimide resin in stages between a temperature range of about 40 to 365/sup 0/C to form a strong adhesive bond between said elements, applying a metal-filled polyimide resin overcoat between said elements so as to provide electrical connection therebetween, and heat treating said metal-filled polyimide resin with substantially the same temperature profile as the unfilled polyimide resin. The present invention is also concerned with an adhesive, resilient, substantially void free bonding combination for providing a high strength, electrically conductive adhesive attachment between electrically conductive elements which comprises a major amount of an unfilled polyimide resin and a minor amount of a metal-filled polyimide resin.

  5. Exchange effects in a cold plasma

    E-Print Network [OSTI]

    Ekman, Robin; Brodin, Gert

    2015-01-01T23:59:59.000Z

    We have studied the exchange corrections to linear electrostatic wave propagation in a plasma using a quantum kinetic formalism. Specifically we have considered the zero temperature limit. In order to simplify the calculations we have focused on the long wavelength limit, i.e. wavelengths much longer than the de Broglie wavelength. For the case of ion-acoustic waves we have calculated the exchange correction both to the damping rate and the real part of the frequency. For Langmuir waves the frequency shift due to exchange effects is found. Our results are compared with the frequency shifts deduced from commonly used exchange potentials which are computed from density functional theory.

  6. Radioactive ion detector

    DOE Patents [OSTI]

    Bower, K.E.; Weeks, D.R.

    1997-08-12T23:59:59.000Z

    Apparatus for detecting the presence, in aqueous media, of substances which emit alpha and/or beta radiation and determining the oxidation state of these radioactive substances, that is, whether they are in cationic or anionic form. In one embodiment, a sensor assembly has two elements, one comprised of an ion-exchange material which binds cations and the other comprised of an ion-exchange material which binds anions. Each ion-exchange element is further comprised of a scintillation plastic and a photocurrent generator. When a radioactive substance to which the sensor is exposed binds to either element and emits alpha or beta particles, photons produced in the scintillation plastic illuminate the photocurrent generator of that element. Sensing apparatus senses generator output and thereby indicates whether cationic species or anionic species or both are present and also provides an indication of species quantity. 2 figs.

  7. Simulation of the vacuum assisted resin transfer molding (VARTM) process and the development of light-weight composite bridging

    E-Print Network [OSTI]

    Robinson, Marc J.

    2008-01-01T23:59:59.000Z

    versus time constitutive model for epoxy resin at fixedconstitutive model for epoxy resin at fixed temperature.dependence, the viscosity of epoxy resin is also dependent

  8. Glutathione Resins I. List of Components

    E-Print Network [OSTI]

    Lebendiker, Mario

    , dilute 4 ml of 10X Extraction/Loading Buffer with 36 ml of deionized water. If necessary, warm is prepacked with 1-ml Glutathione-Uniflow Resin. · 5 x 100 mg of Glutathione (reduced) · 10X Extraction/Loading Buffer (1.4 mM NaCl; 100 mM Na2 HPO4 ; 18 mM KH2 PO4 , pH 7.5): To prepare the extraction/loading buffer

  9. Optimizing Synthesis of Na2Ti2SiO7 - 2H2O (Na-CST) and Ion Exchange Pathways for Cs0.4H1.6Ti2SiO7 - H2O (Cs-CST) Determined from in situ Synchrotron X-ray Powder Diffraction

    SciTech Connect (OSTI)

    Celestian,A.; Medvedev, D.; Tripathi, A.; Parise, J.; Clearfield, A.

    2005-01-01T23:59:59.000Z

    Observation of wide angle diffraction data collected in situ during previous synthesis of Na-CST (Na{sub 2}Ti{sub 2}SiO{sub 7}-2H{sub 2}O) showed initial crystallization of a precursor phase (SNT) at 30 C followed by conversion to CST after 1 h at 220 C. In situ studies of Cs{sup +} ion exchange into the H{sup +} form of CST showed a site-by-site ion exchange pathway accompanied by a simultaneous structural transition from P4{sub 2}/mbc (cell parameters a = 11.0690(6) Angstroms, c = 11.8842(6) Angstroms) to P4{sub 2}/mcm (cell parameters a = 7.847(2) Angstroms, c = 11.9100(6) Angstroms). After approximately 18% Cs{sup +} exchange into site designated Cs2 in space group P4{sub 2}/mcm, a site designated Cs1 in space group P4{sub 2}/mcm began to fill at the center of the 8MR windows until a maximum of approximately 22% exchange was achieved for Cs1. Bond valence sums of site Cs1 to framework O{sup 2-} are 1.00 v.u., while bond valence sums of site Cs2 to framework O{sup 2-} are 0.712 v.u. suggesting Cs1 to have a more stable bonding environment.

  10. Machine for applying a two component resin to a roadway surface

    DOE Patents [OSTI]

    Huszagh, D.W.

    1984-01-01T23:59:59.000Z

    A portable machine for spraying two component resins onto a roadway, the machine having a pneumatic control system, including means for purging the machine of mixed resin with air and then removing remaining resin with solvent. Interlocks prevent contamination of solvent and resin, and mixed resin can be purged in the event of a power failure.

  11. Agriculture on Exchange InternationalExchangeProgram

    E-Print Network [OSTI]

    Viglas, Anastasios

    Agriculture on Exchange InternationalExchangeProgram Students enrolled in courses offered through the Faculty of Agriculture and Environment are welcome to apply for exchange. However, to ensure that you Academic Adviser before submitting an exchange application. Undergraduate Agriculture students normally go

  12. Segmented heat exchanger

    DOE Patents [OSTI]

    Baldwin, Darryl Dean (Lafayette, IN); Willi, Martin Leo (Dunlap, IL); Fiveland, Scott Byron (Metamara, IL); Timmons, Kristine Ann (Chillicothe, IL)

    2010-12-14T23:59:59.000Z

    A segmented heat exchanger system for transferring heat energy from an exhaust fluid to a working fluid. The heat exchanger system may include a first heat exchanger for receiving incoming working fluid and the exhaust fluid. The working fluid and exhaust fluid may travel through at least a portion of the first heat exchanger in a parallel flow configuration. In addition, the heat exchanger system may include a second heat exchanger for receiving working fluid from the first heat exchanger and exhaust fluid from a third heat exchanger. The working fluid and exhaust fluid may travel through at least a portion of the second heat exchanger in a counter flow configuration. Furthermore, the heat exchanger system may include a third heat exchanger for receiving working fluid from the second heat exchanger and exhaust fluid from the first heat exchanger. The working fluid and exhaust fluid may travel through at least a portion of the third heat exchanger in a parallel flow configuration.

  13. acrylic resins part: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    (being developed for the full scale DEAP-3600 detector). , 2012-01-01 6 Liquid Resin Infusion process monitoring with superimposed Fibre Bragg Grating sensor Physics Websites...

  14. acrylic resin oral: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    the present ones contain up to 80% silica North Texas, University of 89 Measuring Asphaltenes and Resins, and Dipole Moment in Petroleum Fluids Engineering Websites Summary: and...

  15. amberlite irc-718 resins: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Myslinski 1997-01-01 16 Team 1: Design of Carbon Fiber Resin Composites for Improved Materials Science Websites Summary: composite material with optimum fatigue performance. This...

  16. amberlite xad-4 resin: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Myslinski 1997-01-01 18 Team 1: Design of Carbon Fiber Resin Composites for Improved Materials Science Websites Summary: composite material with optimum fatigue performance. This...

  17. acp resin composites: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1972- 2003-01-01 2 Team 1: Design of Carbon Fiber Resin Composites for Improved Materials Science Websites Summary: composite material with optimum fatigue performance. This...

  18. adhesive composite resin: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1972- 2003-01-01 4 Team 1: Design of Carbon Fiber Resin Composites for Improved Materials Science Websites Summary: composite material with optimum fatigue performance. This...

  19. amberlite xad-16 resin: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Myslinski 1997-01-01 16 Team 1: Design of Carbon Fiber Resin Composites for Improved Materials Science Websites Summary: composite material with optimum fatigue performance. This...

  20. alkyd resins: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    German, Donovan P. 17 Team 1: Design of Carbon Fiber Resin Composites for Improved Materials Science Websites Summary: composite material with optimum fatigue performance. This...

  1. amberlite xad-7 resin: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Myslinski 1997-01-01 16 Team 1: Design of Carbon Fiber Resin Composites for Improved Materials Science Websites Summary: composite material with optimum fatigue performance. This...

  2. aged composite resin: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    1972- 2003-01-01 2 Team 1: Design of Carbon Fiber Resin Composites for Improved Materials Science Websites Summary: composite material with optimum fatigue performance. This...

  3. Numerical and experimental analyses of resin infusion manufacturing processes of composite materials

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Numerical and experimental analyses of resin infusion manufacturing processes of composite SAS, 38630 Les Avenières, France Abstract: Liquid Resin Infusion (LRI) processes are promising between the deformations of the porous medium and the resin flow during infusion [1

  4. Ion exchange selectivity of a perfluorosulfonate ionomer

    E-Print Network [OSTI]

    Wilkerson, James Edward

    1983-01-01T23:59:59.000Z

    (TMA-Cl) as Eluent 6 Elution of Viologens with Tetraethyl Ammonium Br {TEA-Br) as Eluent 7 Effect of Concentration of KC1 on Retention Volume of Methyl Viologen on Column N-1 8 Effect. of Organic Modifier on V r 9 Effect of Organic Modifier...-4 with TMA-Br as Eluent 2 39 14 Effect of Nafion Volume on Retention Volume of Pyridinium Bromides. 41 vii LIST OF FIGURES Failure 1 Calibration Curve of Ru(bpy) 3 in Methanol. 2+ 2 Effect of Ionic Strength on Elution of Methyl Viologen 3...

  5. Acidic Ion Exchange Membrane - Energy Innovation Portal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041cloth DocumentationProducts (VAP) VAP7-0973 1 Introduction InNational Laboratories Find More

  6. Growth of oxide exchange bias layers

    DOE Patents [OSTI]

    Chaiken, A.; Michel, R.P.

    1998-07-21T23:59:59.000Z

    An oxide (NiO, CoO, NiCoO) antiferromagnetic exchange bias layer produced by ion beam sputtering of an oxide target in pure argon (Ar) sputtering gas, with no oxygen gas introduced into the system. Antiferromagnetic oxide layers are used, for example, in magnetoresistive readback heads to shift the hysteresis loops of ferromagnetic films away from the zero field axis. For example, NiO exchange bias layers have been fabricated using ion beam sputtering of an NiO target using Ar ions, with the substrate temperature at 200 C, the ion beam voltage at 1000V and the beam current at 20 mA, with a deposition rate of about 0.2 {angstrom}/sec. The resulting NiO film was amorphous. 4 figs.

  7. MODELING WITH STRUCTURE OF RESINS IN ELECTRONIC , Tadahiro SHIBUTANI*

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    MODELING WITH STRUCTURE OF RESINS IN ELECTRONIC COMPONENTS Qiang YU* , Tadahiro SHIBUTANI* , Masaki model of the interfacial structure of resin in electronic components was proposed. Bimaterial model, interfacial fracture becomes one of the most important problems in the assessment of reliability

  8. Corrosive resistant heat exchanger

    DOE Patents [OSTI]

    Richlen, Scott L. (Annandale, VA)

    1989-01-01T23:59:59.000Z

    A corrosive and errosive resistant heat exchanger which recovers heat from a contaminated heat stream. The heat exchanger utilizes a boundary layer of innocuous gas, which is continuously replenished, to protect the heat exchanger surface from the hot contaminated gas. The innocuous gas is conveyed through ducts or perforations in the heat exchanger wall. Heat from the heat stream is transferred by radiation to the heat exchanger wall. Heat is removed from the outer heat exchanger wall by a heat recovery medium.

  9. PLUTONIUM LOADING CAPACITY OF REILLEX HPQ ANION EXCHANGE COLUMN - AFS-2 PLUTONIUM FLOWSHEET FOR MOX

    SciTech Connect (OSTI)

    Kyser, E.; King, W.; O'Rourke, P.

    2012-07-26T23:59:59.000Z

    Radioactive plutonium (Pu) anion exchange column experiments using scaled HB-Line designs were performed to investigate the dependence of column loading performance on the feed composition in the H-Canyon dissolution process for plutonium oxide (PuO{sub 2}) product shipped to the Mixed Oxide (MOX) Fuel Fabrication Facility (MFFF). These loading experiments show that a representative feed solution containing {approx}5 g Pu/L can be loaded onto Reillex{trademark} HPQ resin from solutions containing 8 M total nitrate and 0.1 M KF provided that the F is complexed with Al to an [Al]/[F] molar ratio range of 1.5-2.0. Lower concentrations of total nitrate and [Al]/[F] molar ratios may still have acceptable performance but were not tested in this study. Loading and washing Pu losses should be relatively low (<1%) for resin loading of up to 60 g Pu/L. Loading above 60 g Pu/L resin is possible, but Pu wash losses will increase such that 10-20% of the additional Pu fed may not be retained by the resin as the resin loading approaches 80 g Pu/L resin.

  10. Recovery of uranium from seawater. 13. Long-term stability tests for high-performance chelating resins containing amidoxime groups and evaluation of elution process

    SciTech Connect (OSTI)

    Egawa, Hiroaki; Kabay, Nalan; Shuto, Taketomi; Jyo, Akinori (Kumamoto Univ. (Japan))

    1993-03-01T23:59:59.000Z

    Large-scale adsorption/elution cycles were performed to investigate the long-term stability of the chelating resins employed. The adsorbed metal ions were rapidly and quantitatively eluted from the resins with acid eluants. The shrinkage of the resins with successive adsorption/elution cycles influenced the adsorption capacity. The uranium recovery was maintained at a nearly constant value by the employment of bicarbonate eluants. In particular, 2 mol dm[sup [minus]3] NH[sub 4]HCO[sub 3] yielded an efficient stripping for uranium. However, it was clarified that the elution with 0.25 mol dm[sup [minus]3] H[sub 2]SO[sub 4], which gave a high efficiency, was better than the bicarbonate eluants.

  11. Methane production using resin-wafer electrodeionization

    DOE Patents [OSTI]

    Snyder, Seth W; Lin, YuPo; Urgun-Demirtas, Meltem

    2014-03-25T23:59:59.000Z

    The present invention provides an efficient method for creating natural gas including the anaerobic digestion of biomass to form biogas, and the electrodeionization of biogas to form natural gas and carbon dioxide using a resin-wafer deionization (RW-EDI) system. The method may be further modified to include a wastewater treatment system and can include a chemical conditioning/dewatering system after the anaerobic digestion system. The RW-EDI system, which includes a cathode and an anode, can either comprise at least one pair of wafers, each a basic and acidic wafer, or at least one wafer comprising of a basic portion and an acidic portion. A final embodiment of the RW-EDI system can include only one basic wafer for creating natural gas.

  12. Dynamic response of phenolic resin and its carbon-nanotube composites to shock wave loading

    E-Print Network [OSTI]

    Goddard III, William A.

    Dynamic response of phenolic resin and its carbon-nanotube composites to shock wave loading B of phenolic resin and its carbon-nanotube CNT composites to shock wave compression. For phenolic resin, our strain hardening. Shock loading of the CNT-resin composites is applied parallel or perpendicular

  13. Monitoring the resin infusion manufacturing process under industrial environment using distributed sensors

    E-Print Network [OSTI]

    Boyer, Edmond

    1 Monitoring the resin infusion manufacturing process under industrial environment using the Liquid Resin Infusion process under industrial environment is proposed. To detect the resin front; Liquid Resin Infusion. #12;2 1. Introduction Recently, Liquid Composite Molding (LCM) processes have been

  14. Woven heat exchanger

    DOE Patents [OSTI]

    Piscitella, R.R.

    1984-07-16T23:59:59.000Z

    This invention relates to a heat exchanger for waste heat recovery from high temperature industrial exhaust streams. In a woven ceramic heat exchanger using the basic tube-in-shell design, each heat exchanger consisting of tube sheets and tube, is woven separately. Individual heat exchangers are assembled in cross-flow configuration. Each heat exchanger is woven from high temperature ceramic fiber, the warp is continuous from tube to tube sheet providing a smooth transition and unitized construction.

  15. Cesium and Strontium Specific Exchangers for Nuclear Waste Effluent Remediation

    SciTech Connect (OSTI)

    A. Clearfield; A. I. Bortun; L. A. Bortun; E. A. Bhlume; P. Sylvester; G. M. Graziano

    2000-09-01T23:59:59.000Z

    During the past 50 years, nuclear defense activities have produced large quantities of nuclear waste that now require safe and permanent disposal. The general procedure to be implemented involves the removal of cesium and strontium from the waste solutions for disposal in permanently vitrified media. This requires highly selective sorbents or ion exchangers. Further, at the high radiation doses present in the solution, organic exchangers or sequestrants are likely to decompose over time. Inorganic ion exchangers are resistant to radiation damage and can exhibit remarkably high selectivities. We have synthesized three families of tunnel-type ion exchangers. The crystal structures of these compounds as well as their protonated phases, coupled with ion exchange titrations, were determined and this information was used to develop an understanding of their ion exchange behavior. The ion exchange selectivities of these phases could be regulated by isomorphous replacement of the framework metals by larger or smaller radius metals. In the realm of layered compounds, we prepared alumina, silica, and zirconia pillared clays and sodium micas. The pillared clays yielded very high Kd values for Cs+ and were very effective in removing Cs+ from groundwaters. The sodium micas also had a high affinity for Cs+ but an even greater attraction for S42+. They also possess the property of trapping these ions permanently as the layers slowly decrease their interlayer distance as loading occurs. Sodium nonatitanate exhibited extremely high Kd values for Sr2+ in alkaline tank wastes and should be considered for removal of Sr2+ in such cases. For tank wastes containing complexing agents, we have found that adding Ca2+ to the solution releases the complexed Sr2+ which may then be removed with the CST exchanger.

  16. assisted resin transfer: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    13 14 15 16 17 18 19 20 21 22 23 24 25 Next Page Last Page Topic Index 81 Measuring Asphaltenes and Resins, and Dipole Moment in Petroleum Fluids Engineering Websites Summary: and...

  17. acid chelating resin: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    unsaturated polyester resin and provides a (more) Kayatin, Matthew J. 2012-01-01 108 Boric acid reversibly inhibits the second step of pre-mRNA splicing Noam Shomron, Gil Ast...

  18. Fluorinated diamond particles bonded in a filled fluorocarbon resin matrix

    DOE Patents [OSTI]

    Taylor, G.W.; Roybal, H.E.

    1983-11-14T23:59:59.000Z

    A method of producing fluorinated diamond particles bonded in a filled fluorocarbon resin matrix. Simple hot pressing techniques permit the formation of such matrices from which diamond impregnated grinding tools and other articles of manufacture can be produced. Teflon fluorocarbon resins filled with Al/sub 2/O/sub 3/ yield grinding tools with substantially improved work-to-wear ratios over grinding wheels known in the art.

  19. Fluorinated diamond particles bonded in a filled fluorocarbon resin matrix

    DOE Patents [OSTI]

    Taylor, Gene W. (Los Alamos, NM); Roybal, Herman E. (Santa Fe, NM)

    1985-01-01T23:59:59.000Z

    A method of producing fluorinated diamond particles bonded in a filled fluorocarbon resin matrix. Simple hot pressing techniques permit the formation of such matrices from which diamond impregnated grinding tools and other articles of manufacture can be produced. Teflon fluorocarbon resins filled with Al.sub.2 O.sub.3 yield grinding tools with substantially improved work-to-wear ratios over grinding wheels known in the art.

  20. Evaluating guayule resin fractions for mutagenicity and toxicity

    E-Print Network [OSTI]

    Avirett, Donald Baker

    1992-01-01T23:59:59.000Z

    EVALUATING GUAYULE RESIN FRACTIONS FOR NUTAGENICITY AND TOXICITY A Thesis by DONALD BAKER AVIRETT Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements for the degree of MASTER... OF SCIENCE December 1992 Major Subject: Industrial Hygiene EVALUATING GUAYULE RESIN FRACTIONS FOR MUTAGENICITY AND TOXICITY A Thesis by DONALD BAKER AVIRETT Submitted to Texas A&M University in partial fulfillment of the requirements for the degree...

  1. Homogenization of the Poisson-Nernst-Planck Equations for Ion Transport in Charged Porous Media

    E-Print Network [OSTI]

    Markus Schmuck; Martin Z. Bazant

    2014-07-14T23:59:59.000Z

    Effective Poisson-Nernst-Planck (PNP) equations are derived for macroscopic ion transport in charged porous media under periodic fluid flow by an asymptotic multi-scale expansion with drift. The microscopic setting is a two-component periodic composite consisting of a dilute electrolyte continuum (described by standard PNP equations) and a continuous dielectric matrix, which is impermeable to the ions and carries a given surface charge. Four new features arise in the upscaled equations: (i) the effective ionic diffusivities and mobilities become tensors, related to the microstructure; (ii) the effective permittivity is also a tensor, depending on the electrolyte/matrix permittivity ratio and the ratio of the Debye screening length to the macroscopic length of the porous medium; (iii) the microscopic fluidic convection is replaced by a diffusion-dispersion correction in the effective diffusion tensor; and (iv) the surface charge per volume appears as a continuous "background charge density", as in classical membrane models. The coefficient tensors in the upscaled PNP equations can be calculated from periodic reference cell problems. For an insulating solid matrix, all gradients are corrected by the same tensor, and the Einstein relation holds at the macroscopic scale, which is not generally the case for a polarizable matrix, unless the permittivity and electric field are suitably defined. In the limit of thin double layers, Poisson's equation is replaced by macroscopic electroneutrality (balancing ionic and surface charges). The general form of the macroscopic PNP equations may also hold for concentrated solution theories, based on the local-density and mean-field approximations. These results have broad applicability to ion transport in porous electrodes, separators, membranes, ion-exchange resins, soils, porous rocks, and biological tissues.

  2. Energy Exchange News

    Broader source: Energy.gov [DOE]

    Please join FEMP Director Tim Unruh and Julia Kelley with Oak Ridge National Laboratory (ORNL) for a presentation on the Energy Exchange. The Energy Exchange is a new 2 1/2 day training opportunity...

  3. Apparatus and method for removing solvent from carbon dioxide in resin recycling system

    DOE Patents [OSTI]

    Bohnert, George W. (Harrisonville, MO); Hand, Thomas E. (Lee's Summit, MO); DeLaurentiis, Gary M. (Jamestown, CA)

    2009-01-06T23:59:59.000Z

    A two-step resin recycling system and method solvent that produces essentially contaminant-free synthetic resin material. The system and method includes one or more solvent wash vessels to expose resin particles to a solvent, the solvent contacting the resin particles in the one or more solvent wash vessels to substantially remove contaminants on the resin particles. A separator is provided to separate the solvent from the resin particles after removal from the one or more solvent wash vessels. The resin particles are next exposed to carbon dioxide in a closed loop carbon dioxide system. The closed loop system includes a carbon dioxide vessel where the carbon dioxide is exposed to the resin, substantially removing any residual solvent remaining on the resin particles after separation. A separation vessel is also provided to separate the solvent from the solvent laden carbon dioxide. Both the carbon dioxide and the solvent are reused after separation in the separation vessel.

  4. Anion exchange polymer electrolytes

    DOE Patents [OSTI]

    Kim, Yu Seung; Kim, Dae Sik

    2013-09-10T23:59:59.000Z

    Solid anion exchange polymer electrolytes include chemical compounds comprising a polymer backbone with side chains that include guanidinium cations.

  5. Purification Or Organic Acids Using Anion Exchange Chromatography.

    DOE Patents [OSTI]

    Ponnampalam; Elankovan (Okemos, MI)

    2001-09-04T23:59:59.000Z

    Disclosed is a cost-effective method for purifying and acidifying carboxylic acids, including organic acids and amino acids. The method involves removing impurities by allowing the anionic form of the carboxylic acid to bind to an anion exchange column and washing the column. The carboxylic anion is displaced as carboxylic acid by washing the resin with a strong inorganic anion. This method is effective in removing organic carboxylic acids and amino acids from a variety of industrial sources, including fermentation broths, hydrolysates, and waste streams.

  6. High-resolution studies of charge exchange in supernova remnants with Magellan, XMM-Newton, and Micro-X

    E-Print Network [OSTI]

    Heine, Sarah Nicole Trowbridge

    2014-01-01T23:59:59.000Z

    Charge exchange, the semi-resonant transfer of an electron from a neutral atom to an excited state in an energetic ion, can occur in plasmas where energetic ions are incident on a cold, at least partially neutral gas. ...

  7. anion-exchange resin-based desulfurization: Topics by E-print...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Flue Gas Desulfurization GT Gas Turbine HHV Higher Heating Values HCN Hydrogen Cyanide HRSG Heat Recovery Steam Generation... ? Nuclear Power Plants ? Solar Power Plants ? Wind...

  8. anion-exchange resins omega-3: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    finding a popular magazine or newspaper that has not contained an article on farmed fish lately. The articles all have a similar slant, namely that fish farming is bad for the...

  9. acidic cation-exchange resin: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    stable thermodynamically and hydration free energies obtained Yu, Fangqun 232 ANTIBODY PURIFICATION USING CAPRYLIC ACID In mildly acidic conditions, the addition of short-chain...

  10. Energy Exchange | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Exchange Energy Exchange Energy Exchange August 11-13, 2015, Phoenix Convention Center The 2015 Energy Exchange in Phoenix, Arizona, is being launched to provide two-and-a-half...

  11. Uranium from seawater research : final progress report, FY 1982

    E-Print Network [OSTI]

    Borzekowski, J.

    1982-01-01T23:59:59.000Z

    During the FY '82 campaign 14 new ion exchange resin formulations, prepared by the Rohm & Haas Company, were tested by MIT at the Woods Hole Oceanographic Institution. The best of these chelating resins was again of the ...

  12. Uniform insulation applied-B ion diode

    DOE Patents [OSTI]

    Seidel, David B. (Albuquerque, NM); Slutz, Stephen A. (Albuquerque, NM)

    1988-01-01T23:59:59.000Z

    An applied-B field extraction ion diode has uniform insulation over an anode surface for increased efficiency. When the uniform insulation is accomplished with anode coils, and a charge-exchange foil is properly placed, the ions may be focused at a point on the z axis.

  13. Process for preparing phenolic formaldehyde resole resin products derived from fractionated fast-pyrolysis oils

    DOE Patents [OSTI]

    Chum, Helena L. (Arvada, CO); Kreibich, Roland E. (Auburn, WA)

    1992-01-01T23:59:59.000Z

    A process for preparing phenol-formaldehyde resole resins and adhesive compositions in which portions of the phenol normally contained in said resins are replaced by a phenol/neutral fractions extract obtained from fractionating fast-pyrolysis oils.

  14. Chicago Climate Exchange, Inc. 2010 Chicago Climate Exchange 1 The Role of Exchanges and Standardization

    E-Print Network [OSTI]

    Chicago Climate Exchange®, Inc.© 2010 Chicago Climate Exchange 1 The Role of Exchanges and Standardization in Reducing Emissions at Scale Michael J. Walsh, Ph.D. Executive Vice President Chicago Climate Exchange, Inc. #12;Chicago Climate Exchange®, Inc.© 2010 Chicago Climate Exchange Pacala-Socolow GHG

  15. alkyd-amino resins based: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Websites Summary: EVALUATION OF HAND LAY-UP AND RESIN TRANSFER MOLDING IN COMPOSITE WIND TURBINE BLADE MANUFACTURING......

  16. FLUID FLOW MODELING OF RESIN TRANSFER MOLDING FOR COMPOSITE MATERIAL WIND TURBINE BLADE STRUCTURES

    E-Print Network [OSTI]

    FLUID FLOW MODELING OF RESIN TRANSFER MOLDING FOR COMPOSITE MATERIAL WIND TURBINE BLADE STRUCTURES.............................................................................................................7 Composite Materials...................................................................................................7 Material Properties

  17. COMPUTATIONAL MODELING OF THE VACUUM ASSISTED RESIN TRANSFER MOLDING (VARTM) PROCESS

    E-Print Network [OSTI]

    Grujicic, Mica

    process to ensure void-free parts; (b) non-isothermal resin infusion to shorten manufacturing cycle time

  18. Toughened epoxy resin system and a method thereof

    DOE Patents [OSTI]

    Janke, C.J.; Dorsey, G.F.; Havens, S.J.; Lopata, V.J.

    1998-03-10T23:59:59.000Z

    Mixtures of epoxy resins with cationic initiators are curable under high energy ionizing radiation such as electron beam radiation, X-ray radiation, and gamma radiation. The composition of this process consists of an epoxy resin, a cationic initiator such as a diaryliodonium or triarylsulfonium salt of specific anions, and a toughening agent such as a thermoplastic, hydroxy-containing thermoplastic oligomer, epoxy-containing thermoplastic oligomer, reactive flexibilizer, rubber, elastomer, or mixture thereof. Cured compositions have high glass transition temperatures, good mechanical properties, and good toughness. These properties are comparable to those of similar thermally cured epoxies.

  19. Toughened epoxy resin system and a method thereof

    DOE Patents [OSTI]

    Janke, Christopher J. (Oliver Springs, TN); Dorsey, George F. (Farragut, TN); Havens, Stephen J. (Knoxville, TN); Lopata, Vincent J. (Manitoba, CA)

    1998-01-01T23:59:59.000Z

    Mixtures of epoxy resins with cationic initiators are curable under high energy ionizing radiation such as electron beam radiation, X-ray radiation, and gamma radiation. The composition of this process consists of an epoxy resin, a cationic initiator such as a diaryliodonium or triarylsulfonium salt of specific anions, and a toughening agent such as a thermoplastic, hydroxy-containing thermoplastic oligomer, epoxy-containing thermoplastic oligomer, reactive flexibilizer, rubber, elastomer, or mixture thereof. Cured compositions have high glass transition temperatures, good mechanical properties, and good toughness. These properties are comparable to those of similar thermally cured epoxies.

  20. MODELING AND SIMULATION OF SOLID FLUIDIZATION IN A RESIN COLUMN

    SciTech Connect (OSTI)

    Lee, S.

    2014-06-24T23:59:59.000Z

    The objective of the present work is to model the resin particles within the column during fluidization and sedimentation processes using computation fluid dynamics (CFD) approach. The calculated results will help interpret experimental results, and they will assist in providing guidance on specific details of testing design and establishing a basic understanding of particle’s hydraulic characteristics within the column. The model is benchmarked against the literature data and the test data (2003) conducted at Savannah River Site (SRS). The paper presents the benchmarking results and the modeling predictions of the SRS resin column using the improved literature correlations applicable for liquid-solid granular flow.

  1. Creep of an epoxy resin under transient temperatures

    E-Print Network [OSTI]

    Watkins, Larry Alan

    1973-01-01T23:59:59.000Z

    CREEP OF AN EPOXY RESIN UNDER TRANSIENT TEMPERATURES A Thesis by LARRY ALAN WATKINS Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement for the degree of MASTER OF SCIENCE August 1973 Major... Subject: Civil Engineering CREEP OF AN EPOXY RESIN UNDER TRANSIENT TEMPERATURES A Thesis by LARRY ALAN MATKINS Approved as to style and content by: R. A. Schapery (Ch ai rman o f Commi t tee ) C. H. amson, (Head of Department) R. E. Martin...

  2. Curing and post-curing luminescence in an epoxy resin O. Gallot-lavalle 1

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Curing and post-curing luminescence in an epoxy resin O. Gallot-lavallée 1 *, G. Teyssedre 1 , C of Applied Polymer Science Keywords: Epoxy resin, Luminescence, Thermo-stimulation, Chemiluminescence, Post epoxy resin samples are heated in air. This phenomenon is very sensitive to the nature of the atmosphere

  3. Non-isothermal preform infiltration during the vacuum-assisted resin transfer molding (VARTM) process

    E-Print Network [OSTI]

    Grujicic, Mica

    the infiltration of a rectangular carbon fiber based preform with the NBV-800 epoxy resin and to optimize the VARTMNon-isothermal preform infiltration during the vacuum-assisted resin transfer molding (VARTM-element model is developed to analyze the infiltration of a fiber preform with resin under non- isothermal

  4. Space charge behaviour in an epoxy resin: the influence of fillers, temperature and electrode material

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Space charge behaviour in an epoxy resin: the influence of fillers, temperature and electrode material Short title: Space charge in an epoxy resin O. Gallot-lavallée 1 *, G. Teyssedre 1 , C. Laurent 1 the possibility of performing space charge measurement on filled epoxy resin despite the piezoelectricity

  5. Liquid Resin Infusion process monitoring with superimposed Fibre Bragg Grating sensor

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Liquid Resin Infusion process monitoring with superimposed Fibre Bragg Grating sensor Emmanuel Resin Infusion (LRI) , with the FBG/LPG sensor embedded in a composite part. Dielectric analysis the material and the structure. Among the various composite manufacturing processes, Liquid Resin Infusion (LRI

  6. Effect of Resins and DBSA on Asphaltene Precipitation from Petroleum Fluids

    E-Print Network [OSTI]

    Firoozabadi, Abbas

    Effect of Resins and DBSA on Asphaltene Precipitation from Petroleum Fluids Lamia Goual and Abbas different petroleum fluids. Various resins are added to three different petroleum fluids to measure of precipitation. However, addition of resins to a petroleum fluid increases the amount of precipitated asphaltenes

  7. Ion exchange-induced dissolution of calcite in Na-montmorillonite/CaCO?b3?s systems: its effect on hydraulic conductivity, CaCO?b3?s dissolution kinetics, and CaCO?b3?s equilibrium relations 

    E-Print Network [OSTI]

    Del Rio Durand, Jose Bruno

    1990-01-01T23:59:59.000Z

    Minerals Repository, Clay Minerals Society, University of Missouri, Columbia, MQ) was treated with pH 5. 5 Na-acetate in order to remove traces of CaCO3; complete Na-saturation of the sample was achieved by successive washings with 1 M NaC1... was present. The DD reaction resulted in pH values of approximately 10, a decrease of the exchangeable sodium percemage (ESP), and in a substantial enhancement of calcite dissolution. The rate of calcite dissolution in these systems, as well as in batch...

  8. Nanoscale Heterostructures and Thermoplastic Resin Binders: Novel

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn'tOrigin of Contamination in Many Devils Wash,EnergyNanophosphate technology forLithium-Ion

  9. Surface chemistry control for selective fossil resin flotation

    DOE Patents [OSTI]

    Miller, Jan D. (1886 Atkin Ave., Salt Lake City, UT 84106); Yi, Ye (2875 E. Wander Way, Salt Lake City, UT 84117); Yu, Qiang (224 University Village, Salt Lake City, UT 84108)

    1994-01-01T23:59:59.000Z

    A froth flotation method is disclosed for separating fine particles of fossil resin from by use of frothing reagents which include an aliphatic organic compound having a polar group and containing not more than four carbon atoms. Butanol is an effective frothing reagent in this method.

  10. Energy Conservation Opportunities in Hydrocarbon Resin Manufacturing Facilities

    E-Print Network [OSTI]

    Ganji, A. R.; Hackett, B.; Chow, S.; Lonergan, R.; Wimer, J.

    "The results of a plant-wide assessment of the manufacturing facilities of Neville Chemical Company, a manufacturer of hydrocarbon resins will be presented in this paper. The project was co-funded by US Department of Energy under its Plant...

  11. Surface chemistry control for selective fossil resin flotation

    DOE Patents [OSTI]

    Miller, J.D.; Yi, Y.; Yu, Q.

    1994-06-07T23:59:59.000Z

    A froth flotation method is disclosed for separating fine particles of fossil resin by use of frothing reagents which include an aliphatic organic compound having a polar group and containing not more than four carbon atoms. Butanol is an effective frothing reagent in this method. 12 figs.

  12. Measuring Asphaltenes and Resins, and Dipole Moment in Petroleum Fluids

    E-Print Network [OSTI]

    Firoozabadi, Abbas

    , and oils. Asphaltenes and resins are polar, while the rest of the so-called oils are either nonpolar-Messaoud field in Algeria 44 API gravity with an asphaltene content of 0.1 wt % that precipitates a considerable from Boscan in Venezuela 10 API gravity con- taining approximately 17 wt % asphaltenes does not en

  13. Optimization of Heat Exchangers

    SciTech Connect (OSTI)

    Ivan Catton

    2010-10-01T23:59:59.000Z

    The objective of this research is to develop tools to design and optimize heat exchangers (HE) and compact heat exchangers (CHE) for intermediate loop heat transport systems found in the very high temperature reator (VHTR) and other Generation IV designs by addressing heat transfer surface augmentation and conjugate modeling. To optimize heat exchanger, a fast running model must be created that will allow for multiple designs to be compared quickly. To model a heat exchanger, volume averaging theory, VAT, is used. VAT allows for the conservation of mass, momentum and energy to be solved for point by point in a 3 dimensional computer model of a heat exchanger. The end product of this project is a computer code that can predict an optimal configuration for a heat exchanger given only a few constraints (input fluids, size, cost, etc.). As VAT computer code can be used to model characteristics )pumping power, temperatures, and cost) of heat exchangers more quickly than traditional CFD or experiment, optimization of every geometric parameter simultaneously can be made. Using design of experiment, DOE and genetric algorithms, GE, to optimize the results of the computer code will improve heat exchanger disign.

  14. Nanoheterostructure Cation Exchange: Anionic Framework Conservation

    SciTech Connect (OSTI)

    Jain, Prashant K.; Amirav, Lilac; Aloni, Shaul; Alivisatos, A. Paul

    2010-05-11T23:59:59.000Z

    In ionic nanocrystals the cationic sub-lattice can be replaced with a different metal ion via a fast, simple, and reversible place-exchange, allowing post-synthetic modification of the composition of the nanocrystal, while preserving its size and shape. Here, we demonstrate for the first time that during such an exchange, the anionic framework of the crystal is preserved. When applied to nanoheterostructures, this phenomenon ensures that compositional interfaces within the heterostructure are conserved throughout the transformation. For instance, a morphology composed of a CdSe nanocrystal embedded in a CdS rod (CdSe/CdS) was exchanged to a PbSe/PbS nanorod via a Cu2Se/Cu2S structure. During every exchange cycle, the seed size and position within the nanorod were preserved, as evident by excitonic features, Z-contrast imaging, and elemental line-scans. Anionic framework conservation extends the domain of cation exchange to the design of more complex and unique nanostructures.

  15. Charge exchange recombination spectroscopy on fusion devices

    SciTech Connect (OSTI)

    Duval, B. P. [Centre de Recherches en Physique des Plasmas, EPFL, Lausanne (Switzerland)

    2012-05-25T23:59:59.000Z

    For fusion, obtaining reliable measurements of basic plasma parameters like ion and electron densities and temperatures is a primary goal. For theory, measurements are needed as a function of time and space to understand plasma transport and confinement with the ultimate goal of achieving economic nuclear fusion power. Electron profile measurements and plasma spectroscopy for the plasma ions are introduced. With the advent of Neutral Beam auxiliary plasma heating, Charge Exchange Recombination Spectroscopy provides accurate and time resolved measurements of the ions in large volume fusion devices. In acknowledgement of Nicol Peacock's role in the development of these techniques, still at the forefront of plasma fusion research, this paper describes the evolution of this diagnostic method.

  16. Synthesis and crystal structure of Mg{sub 0.5}NbO{sub 2}: An ion-exchange reaction with Mg{sup 2+} between trigonal [NbO{sub 2}]{sup -} layers

    SciTech Connect (OSTI)

    Miura, Akira, E-mail: amiura@yamanashi.ac.jp [Center for Crystal Science and Technology, University of Yamanashi (Japan); Takei, Takahiro; Kumada, Nobuhiro [Center for Crystal Science and Technology, University of Yamanashi (Japan)

    2013-01-15T23:59:59.000Z

    A new layered niobate, Mg{sub 0.5}NbO{sub 2}, was synthesized from LiNbO{sub 2} through a cation-exchange reaction with Mg{sup 2+} at 450-550 Degree-Sign C. This is the first example of a topotactic reaction with an aliovalent cation between trigonal [NbO{sub 2}]{sup -} layers. It is proposed to be isostructural with LiNbO{sub 2} (space group; P6{sub 3}/mmc) with lattice parameters of a=2.9052(6) A, c=10.625(15) A. The lattice parameters and formation energy of Mg{sub 0.5}NbO{sub 2} crystallized in LiNbO{sub 2} form and other layered CaNb{sub 2}O{sub 4} one were calculated by density functional theory. - Graphical abstract: A new layered niobate, Mg{sub 0.5}NbO{sub 2}, was synthesized from LiNbO{sub 2} through a cation-exchange reaction with Mg{sup 2+} at 450-550 Degree-Sign C. It is isostructural with LiNbO{sub 2} with lattice parameters of a=2.9052(6) A, c=10.625(15) A. Mg{sup 2+} are described in spheres located between [NbO{sub 2}]{sup -} trigonal layers and its occupancy is 0.5. Highlights: Black-Right-Pointing-Pointer A new layered niobate, Mg{sub 0.5}NbO{sub 2}, was synthesized from LiNbO{sub 2}. Black-Right-Pointing-Pointer Cation-exchange reaction converted two monovalent Li{sup +} into one divalent Mg{sup 2+} at 450-550 Degree-Sign C. Black-Right-Pointing-Pointer Mg{sub 0.5}NbO{sub 2} was isostructural with LiNbO{sub 2} (space group; P6{sub 3}/mmc). Black-Right-Pointing-Pointer Its lattice parameters were a=2.9052(6) A and c=10.625(15) A. Black-Right-Pointing-Pointer Synthesized Mg{sub 0.5}NbO{sub 2} was calculated to be thermodynamically more favorable.

  17. Heat and mass exchanger

    DOE Patents [OSTI]

    Lowenstein, Andrew (Princeton, NJ); Sibilia, Marc J. (Princeton, NJ); Miller, Jeffrey A. (Hopewell, NJ); Tonon, Thomas (Princeton, NJ)

    2007-09-18T23:59:59.000Z

    A mass and heat exchanger includes at least one first substrate with a surface for supporting a continuous flow of a liquid thereon that either absorbs, desorbs, evaporates or condenses one or more gaseous species from or to a surrounding gas; and at least one second substrate operatively associated with the first substrate. The second substrate includes a surface for supporting the continuous flow of the liquid thereon and is adapted to carry a heat exchange fluid therethrough, wherein heat transfer occurs between the liquid and the heat exchange fluid.

  18. Heat and mass exchanger

    DOE Patents [OSTI]

    Lowenstein, Andrew (Princeton, NJ); Sibilia, Marc J. (Princeton, NJ); Miller, Jeffrey A. (Hopewell, NJ); Tonon, Thomas (Princeton, NJ)

    2011-06-28T23:59:59.000Z

    A mass and heat exchanger includes at least one first substrate with a surface for supporting a continuous flow of a liquid thereon that either absorbs, desorbs, evaporates or condenses one or more gaseous species from or to a surrounding gas; and at least one second substrate operatively associated with the first substrate. The second substrate includes a surface for supporting the continuous flow of the liquid thereon and is adapted to carry a heat exchange fluid therethrough, wherein heat transfer occurs between the liquid and the heat exchange fluid.

  19. SILICON CARBIDE CERAMICS FOR COMPACT HEAT EXCHANGERS

    SciTech Connect (OSTI)

    DR. DENNIS NAGLE; DR. DAJIE ZHANG

    2009-03-26T23:59:59.000Z

    Silicon carbide (SiC) materials are prime candidates for high temperature heat exchangers for next generation nuclear reactors due to their refractory nature and high thermal conductivity at elevated temperatures. This research has focused on demonstrating the potential of liquid silicon infiltration (LSI) for making SiC to achieve this goal. The major advantage of this method over other ceramic processing techniques is the enhanced capability of making high dense, high purity SiC materials in complex net shapes. For successful formation of net shape SiC using LSI techniques, the carbon preform reactivity and pore structure must be controlled to allow the complete infiltration of the porous carbon structure which allows complete conversion of the carbon to SiC. We have established a procedure for achieving desirable carbon properties by using carbon precursors consisting of two readily available high purity organic materials, crystalline cellulose and phenolic resin. Phenolic resin yields a glassy carbon with low chemical reactivity and porosity while the cellulose carbon is highly reactive and porous. By adjusting the ratio of these two materials in the precursor mixtures, the properties of the carbons produced can be controlled. We have identified the most favorable carbon precursor composition to be a cellulose resin mass ratio of 6:4 for LSI formation of SiC. The optimum reaction conditions are a temperature of 1800 C, a pressure of 0.5 Torr of argon, and a time of 120 minutes. The fully dense net shape SiC material produced has a density of 2.96 g cm{sup -3} (about 92% of pure SiC) and a SiC volume fraction of over 0.82. Kinetics of the LSI SiC formation process was studied by optical microscopy and quantitative digital image analysis. This study identified six reaction stages and provided important understanding of the process. Although the thermal conductivity of pure SiC at elevated temperatures is very high, thermal conductivities of most commercial SiC materials are much lower due to phonon scattering by impurities (e.g., sintering aids located at the grain boundaries of these materials). The thermal conductivity of our SiC was determined using the laser flash method and it is 214 W/mK at 373 K and 64 W/mK at 1273 K. These values are very close to those of pure SiC and are much higher than those of SiC materials made by industrial processes. This SiC made by our LSI process meets the thermal properties required for use in high temperature heat exchanger. Cellulose and phenolic resin carbons lack the well-defined atomic structures associated with common carbon allotropes. Atomic-scale structure was studied using high resolution transmission electron microscopy (HRTEM), nitrogen gas adsorption and helium gas pycnometry. These studies revealed that cellulose carbon exhibits a very high degree of atomic disorder and angstrom-scale porosity. It has a density of only 93% of that of pure graphite, with primarily sp2 bonding character and a low concentration of graphene clusters. Phenolic resin carbon shows more structural order and substantially less angstrom-scale porosity. Its density is 98% of that of pure graphite, and Fourier transform analysis of its TEM micrographs has revealed high concentrations of sp3 diamond and sp2 graphene nano-clusters. This is the first time that diamond nano-clusters have been observed in carbons produced from phenolic resin. AC and DC electrical measurements were made to follow the thermal conversion of microcrystalline cellulose to carbon. This study identifies five regions of electrical conductivity that can be directly correlated to the chemical decomposition and microstructural evolution during carbonization. In Region I, a decrease in overall AC conductivity occurs due to the initial loss of the polar groups from cellulose molecules. In Region II, the AC conductivity starts to increase with heat treatment temperature due to the formation and growth of conducting carbon clusters. In Region III, a further increase of AC conductivity with increasing heat treatment temperature is obs

  20. Active microchannel heat exchanger

    DOE Patents [OSTI]

    Tonkovich, Anna Lee Y. (Pasco, WA) [Pasco, WA; Roberts, Gary L. (West Richland, WA) [West Richland, WA; Call, Charles J. (Pasco, WA) [Pasco, WA; Wegeng, Robert S. (Richland, WA) [Richland, WA; Wang, Yong (Richland, WA) [Richland, WA

    2001-01-01T23:59:59.000Z

    The present invention is an active microchannel heat exchanger with an active heat source and with microchannel architecture. The microchannel heat exchanger has (a) an exothermic reaction chamber; (b) an exhaust chamber; and (c) a heat exchanger chamber in thermal contact with the exhaust chamber, wherein (d) heat from the exothermic reaction chamber is convected by an exothermic reaction exhaust through the exhaust chamber and by conduction through a containment wall to the working fluid in the heat exchanger chamber thereby raising a temperature of the working fluid. The invention is particularly useful as a liquid fuel vaporizer and/or a steam generator for fuel cell power systems, and as a heat source for sustaining endothermic chemical reactions and initiating exothermic reactions.

  1. Energy Exchange Schedule

    Broader source: Energy.gov [DOE]

    The schedule for Energy Exchange is now available. Attendees will have the option of attending a variety of training sessions offered within 10 tracks during the times listed below. Session details...

  2. Radial flow heat exchanger

    DOE Patents [OSTI]

    Valenzuela, Javier (Hanover, NH)

    2001-01-01T23:59:59.000Z

    A radial flow heat exchanger (20) having a plurality of first passages (24) for transporting a first fluid (25) and a plurality of second passages (26) for transporting a second fluid (27). The first and second passages are arranged in stacked, alternating relationship, are separated from one another by relatively thin plates (30) and (32), and surround a central axis (22). The thickness of the first and second passages are selected so that the first and second fluids, respectively, are transported with laminar flow through the passages. To enhance thermal energy transfer between first and second passages, the latter are arranged so each first passage is in thermal communication with an associated second passage along substantially its entire length, and vice versa with respect to the second passages. The heat exchangers may be stacked to achieve a modular heat exchange assembly (300). Certain heat exchangers in the assembly may be designed slightly differently than other heat exchangers to address changes in fluid properties during transport through the heat exchanger, so as to enhance overall thermal effectiveness of the assembly.

  3. Rheology Analysis of Thermosetting Resin Candidates for Use in Fuel Compacting

    SciTech Connect (OSTI)

    Trammell, Michael P. [ORNL

    2012-06-01T23:59:59.000Z

    The AGR-1 and AGR-2 overcoating and compacting method utilized a wet mixing process where liquid resin (Hexion Durite SC-1008) was blended with natural and synthetic graphite to produce a graphite/resin matrix for overcoating. The matrix production method specified in the scale-up plan is a co-grinding jet mill process where powdered resin and graphite are fed at the same time into a jet mill. Because of the change in matrix production style, SC-1008 cannot be used in the jet milling process because it is a liquid. Also, attempts to dry out matrix made with SC-1008 for use in the overcoating process at B&W had mixed results. The SC-1008 resin became tacky when dried which caused the matrix to build up inside the overcoater. The scale- up jet milling/mixing and overcoating processes required that a suite of solid or powdered resins be identified. Suitable resins candidates were down selected to two resins, specifically Plenco 14838 and Hexion SD-1708. These resins are referred to as novolac or “two-stage” resins because they require the addition of a curing agent such as hexamethylenetetramine (Hexa) to promote an increased level of cross linking. The overcoating matrix is made of 3 components; natural graphite, synthetic graphite, and resin. The most influential component of the compacting process is the resin component and how it behaves with regards to time, temperature, and pressure. The selected scale-up resins are considered fast curing which means that the increase in molecular weight (curing) occurs over a relatively short period of time, ranging from a few seconds to several minutes depending on the temperature. To find the optimal compacting conditions it is useful to quantify this behavior. In this report, rheology is used to investigate viscosity as a function of time at specific temperatures for the previously mentioned resins.

  4. Method of recovering hazardous waste from phenolic resin filters

    DOE Patents [OSTI]

    Meikrantz, David H. (Idaho Falls, ID); Bourne, Gary L. (Idaho Falls, ID); McFee, John N. (Albuquerque, NM); Burdge, Bradley G. (Idaho Falls, ID); McConnell, Jr., John W. (Idaho Falls, ID)

    1991-01-01T23:59:59.000Z

    The invention is a process for the recovery of hazardous wastes such as heavy metals and radioactive elements from phenolic resin filter by a circulating a solution of 8 to 16 molar nitric acid at a temperature of 110 to 190 degrees F. through the filter. The hot solution dissolves the filter material and releases the hazardous material so that it can be recovered or treated for long term storage in an environmentally safe manner.

  5. Experimental studies of the transfer phenomena of tritium in an isotope exchange column for recovery tritium

    E-Print Network [OSTI]

    Experimental studies of the transfer phenomena of tritium in an isotope exchange column for recovery tritium Anisia Bornea, Ion Cristescu, Marius Zamfirache, Carmen Varlam National Institute of R processes for tritium separation, is the catalyst isotope exchange water-hydrogen. The main problem

  6. Synthesis of Li{sub (x)}Na{sub (2-x)}Mn{sub 2}S{sub 3} and LiNaMnS{sub 2} through redox-induced ion exchange reactions

    SciTech Connect (OSTI)

    Luthy, Joshua A.; Goodman, Phillip L. [Department of Chemistry and Biochemistry, Texas State University-San Marcos, 601 University Drive, San Marcos, TX 78666 (United States); Martin, Benjamin R. [Department of Chemistry and Biochemistry, Texas State University-San Marcos, 601 University Drive, San Marcos, TX 78666 (United States)], E-mail: bmartin@txstate.edu

    2009-03-15T23:59:59.000Z

    Na{sub 2}Mn{sub 2}S{sub 3} was oxidatively deintercalated using iodine in acetonitrile to yield Na{sub 1.3}Mn{sub 2}S{sub 3}, with lattice constants nearly identical to that of the reactant. Lithium was then reductively intercalated into the oxidized product to yield Li{sub 0.7}Na{sub 1.3}Mn{sub 2}S{sub 3}. When heated, this metastable compound decomposed to form a new crystalline compound, LiNaMnS{sub 2}, along with MnS and residual Na{sub 2}Mn{sub 2}S{sub 3}. Single crystal X-ray diffraction structural analysis of LiNaMnS{sub 2} revealed that this compound crystallizes in P-3m1 with cell parameters a=4.0479(6) A, c=6.7759(14) A, V=96.15(3) A{sup 3} (Z=1, wR2=0.0367) in the NaLiCdS{sub 2} structure-type. - Graphical abstract: Structure of LiNaMnS{sub 2}. Li and Mn are statistically distributed in edge-shared tetrahedral environments linked into infinite planes. Sodium ions occupy interlayer sites.

  7. Injection repair of carbon fiber/bismaleimide composite panels with bisphenol E cyanate ester resin

    SciTech Connect (OSTI)

    Thunga, Mahendra [Ames Laboratory; Bauer, Amy [Iowa State University; Obusek, Kristine [Fleet Readiness Center East; Meilunas, Ray [Naval Air Warfare Center Aircraft Division; Akinc, Mufit [Ames Laboratory; Kessler, Michael R [Ames Laboratory

    2014-08-01T23:59:59.000Z

    Resin injection of bisphenol E cyanate ester, a low viscosity resin that cures into a high temperature thermoset polymer, is investigated as a reliable repair method to restore strength and stiffness in delaminated carbon fiber/bismaleimide composites used in aircraft panels. The influence of temperature on the viscosity of the uncured resin was measured to optimize the injection conditions for high resin infiltration into the delaminations. The repair efficiency of the resin was evaluated by varying the panel thickness and the method by which the delamination damage was created in the composite specimens. Ultrasonic scanning (C-scan), flash thermography images, and cross-section analysis of repaired panels revealed excellent resin infiltration into the damaged region. Evaluation of mechanical repair efficiency using both bending stiffness and in-plain compressive strength of the composite panels as the repair metrics showed values exceeding 100%.

  8. Ion colliders

    SciTech Connect (OSTI)

    Fischer, W.

    2011-12-01T23:59:59.000Z

    Ion colliders are research tools for high-energy nuclear physics, and are used to test the theory of Quantum Chromo Dynamics (QCD). The collisions of fully stripped high-energy ions create matter of a temperature and density that existed only microseconds after the Big Bang. Ion colliders can reach higher densities and temperatures than fixed target experiments although at a much lower luminosity. The first ion collider was the CERN Intersecting Storage Ring (ISR), which collided light ions [77Asb1, 81Bou1]. The BNL Relativistic Heavy Ion Collider (RHIC) is in operation since 2000 and has collided a number of species at numerous energies. The CERN Large Hadron Collider (LHC) started the heavy ion program in 2010. Table 1 shows all previous and the currently planned running modes for ISR, RHIC, and LHC. All three machines also collide protons, which are spin-polarized in RHIC. Ion colliders differ from proton or antiproton colliders in a number of ways: the preparation of the ions in the source and the pre-injector chain is limited by other effects than for protons; frequent changes in the collision energy and particle species, including asymmetric species, are typical; and the interaction of ions with each other and accelerator components is different from protons, which has implications for collision products, collimation, the beam dump, and intercepting instrumentation devices such a profile monitors. In the preparation for the collider use the charge state Z of the ions is successively increased to minimize the effects of space charge, intrabeam scattering (IBS), charge change effects (electron capture and stripping), and ion-impact desorption after beam loss. Low charge states reduce space charge, intrabeam scattering, and electron capture effects. High charge states reduce electron stripping, and make bending and acceleration more effective. Electron stripping at higher energies is generally more efficient. Table 2 shows the charge states and energies in the RHIC and LHC injector chains for the heaviest ion species used to date. The RHIC pulsed sputter source (PSC) and Tandem electrostatic accelerator are being replaced by an Electron Beam Ion Source (EBIS), Radio Frequency Quadrupole (RFQ) and short linac [08Ale1]. With EBIS beams of any element can be prepared for RHIC including uranium and spin-polarized 3He. At CERN an ECR ion source is used, followed by an RFQ and Linac. The ions are then accumulated, electron cooled, and accelerated in LEIR. After transfer to and acceleration in the PS, ion beams are injected into the SPS.

  9. Resin-assisted Enrichment of N-terminal Peptides for Characterizing...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Enrichment of N-terminal Peptides for Characterizing Proteolytic Processing. Resin-assisted Enrichment of N-terminal Peptides for Characterizing Proteolytic Processing. Abstract:...

  10. Monitoring the resin infusion manufacturing process under industrial environment using distributed sensors

    E-Print Network [OSTI]

    Wang, Peng; Drapier, Sylvain; Vautrin, Alain; Minni, Jean-Christophe; 10.1177/0021998311410479

    2012-01-01T23:59:59.000Z

    A novel direct approach to detect the resin flow front during the Liquid Resin Infusion process under industrial environment is proposed. To detect the resin front accurately and verify the results, which are deduced from indirect micro-thermocouples measurements, optical fiber sensors based on Fresnel reflection are utilized. It is expected that the results derived from both techniques will lead to an improvement of our understanding of the resin flow and in particular prove that micro-thermocouples can be used as sensors as routine technique under our experimental conditions. Moreover, comparisons with numerical simulations are carried out and experimental and simulated mold filling times are successfully compared.

  11. EFFECTS OF TOUGHENED MATRIX RESINS ON COMPOSITE MATERIALS FOR WIND TURBINE BLADES

    E-Print Network [OSTI]

    EFFECTS OF TOUGHENED MATRIX RESINS ON COMPOSITE MATERIALS FOR WIND TURBINE BLADES by Ricardo Orozco turbine energy project. #12;v TABLE OF CONTENTS LIST OF TABLES

  12. EVALUATION OF HAND LAY-UP AND RESIN TRANSFER MOLDING IN COMPOSITE WIND TURBINE BLADE MANUFACTURING

    E-Print Network [OSTI]

    EVALUATION OF HAND LAY-UP AND RESIN TRANSFER MOLDING IN COMPOSITE WIND TURBINE BLADE MANUFACTURING..........................................................................................................1 Hand Lay-up in Turbine Blade Fabrication

  13. Resin-assisted enrichment of thios as a general strategy for...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    enrichment of thios as a general strategy for proteomic profiling of cysteine-based reversible modifications. Resin-assisted enrichment of thios as a general strategy for proteomic...

  14. Laser Assisted Emittance Exchange

    SciTech Connect (OSTI)

    Xiang, Dao; /SLAC

    2012-06-11T23:59:59.000Z

    We describe here the laser assisted emittance exchange (LAEE) technique. A laser operating in the transverse mode (TEM10 or TEM01) is used to interact with the electron beam in a dispersive region and to initiate the transverse-to-longitudinal emittance exchange. It is shown that with the LAEE one can generate an electron beam with ultralow transverse emittance, which allows one to significantly bring down the size of an X-ray free electron laser (FEL) and greatly extend the availability of these light sources. The technique can also be used to enhance the performances of X-ray FELs in storage rings. The timing and energy jitter problems for the standard emittance exchange and LAEE techniques are also discussed.

  15. A corrosive resistant heat exchanger

    DOE Patents [OSTI]

    Richlen, S.L.

    1987-08-10T23:59:59.000Z

    A corrosive and erosive resistant heat exchanger which recovers heat from a contaminated heat stream. The heat exchanger utilizes a boundary layer of innocuous gas, which is continuously replenished, to protect the heat exchanger surface from the hot contaminated gas. The innocuous gas is pumped through ducts or perforations in the heat exchanger wall. Heat from the heat stream is transferred by radiation to the heat exchanger wall. Heat is removed from the outer heat exchanger wall by a heat recovery medium. 3 figs., 3 tabs.

  16. Munich, Germany Exchange Program

    E-Print Network [OSTI]

    Fernandez, Eduardo

    Munich, Germany Exchange Program Ludwig-Maximilians-Universitat Founded in 1472, Ludwig talented scholars and students from all over the world. As one of Germany's most dynamic universities, LMU administration, and geosciences to name a few. Most courses are offered in Germany, but many departments offer

  17. Evaluation of ultrafiltration membranes in the purification of guayule resin

    E-Print Network [OSTI]

    Jeyaseelan, Ranjit S.

    1991-01-01T23:59:59.000Z

    : Methanol at 370 ml/nun 150 MWCO Membrane Feed: Water at 20 psi 150 MWCO Membrane Feed: Water at 50 psi 200 MWCO Membrane Feed: AVater at 370 ml/min 200 MWCO Membrane Feed: Methanol at 370 ml/min 20 27 30 31 200 MWCO Membrane Feed: Guayule Resin... at 370 ml/min . . . 33 350 MWCO Membrane Feed: AVater at 86. 8 ml/min 10 12 13 14 350 MWCO Membrane Feed: Water at 20 psi 350 MWCO Membrane Feed: Water at 40 psi 350 MWCO Membrane Iced: Methanol at 86. 8 ml/min 350 MWCO Membrane Feed: Methanol...

  18. Evaluating guayule resin fractions for mutagenicity and toxicity 

    E-Print Network [OSTI]

    Avirett, Donald Baker

    1992-01-01T23:59:59.000Z

    microorganism, Il. The system measures the inhibitory effects of test substances upon the normal light producing ability of the bacteria. The purpose of this investigation was to assess several fractions of guayule resin for mutagenicity using the Ames ~a... Salm~ test is a short ? term microbial test using a mutant form of ~(IB~ EEI1~~g bacteria for assaying mutagenic activity of chemicals. It is termed an in-vitro test versus an in-vivo test (using laboratory animals), which is more expensive and time...

  19. Curing Properties of Epoxy Resins for Use to Abandon Wells Destroyed by Hurricanes in the Gulf of Mexico

    E-Print Network [OSTI]

    Gao, Suining

    2012-02-14T23:59:59.000Z

    completely destroyed and toppled. This project tested the curing properties of several epoxy resin systems in different environments. A bisphenol-F/epichlorohydrin (BPF) resin cured by curing agent MBOEA system was successfully tested in the laboratory as a...

  20. Nanoscale Heterostructures and Thermoplastic Resin Binders: Novel Lithium-Ion Anodes

    Broader source: Energy.gov [DOE]

    2013 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Program Annual Merit Review and Peer Evaluation Meeting

  1. Building Energy Data Exchange Specification Scoping Report |...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Building Energy Data Exchange Specification Scoping Report Building Energy Data Exchange Specification Scoping Report The Building Energy Data Exchange Specification (BEDES),...

  2. Ecosystem Restoration through Interdisciplinary Exchange

    E-Print Network [OSTI]

    Sachs, Frederick

    Ecosystem Restoration through Interdisciplinary Exchange David M. Blersch dblersch Shade of Blue and You 21 September 2010 #12;National Science Foundation Ecosystem Restoration through;National Science Foundation Ecosystem Restoration through Interdisciplinary Exchange UB's ERIE Program www

  3. Deliverable for F?ST project: Ln Resin based PLE

    SciTech Connect (OSTI)

    Peterson, Dominic S. [Los Alamos National Laboratory; Armenta, Claudine E. [Los Alamos National Laboratory; Rim, Jung H. [Los Alamos National Laboratory

    2012-05-03T23:59:59.000Z

    This memo describes the fabrication of a polymer ligand extractant based on Eichrom's LN-1 resin. This work has been in support of the Fast Alpha Spectrometry Tool (F{alpha}ST) project. The first part of LANL's role in this project is to evaluate new extractants for use in polymer ligand extractants (PLEs). The first new extractant evaluated is Di(2-ethyl hexyl) phosphoric acid (HDEHP), which is an effective metal extractant. It has very efficient chelating properties for a wide variety of metal ions. HDEHP is an amphiphillic molecule with two long hydrocarbon chains and a polar end with a phosphoryl oxygen (P=O) and an acidic -OH group as shown in Figure 1. HDEHP has shown effectiveness in extracting lanthanides, selective actinides, and other trivalent elements. Several authors have reported that lanthanides and elements with +3 oxidation state have similar extraction behavior in nitric acid. The distribution ratio for lanthanides rapidly decreases at lower nitric concentration then start to increase at higher concentration as shown in. The trivalent americium, curium, and yttrium exhibit similar trend as trivalent lanthanides. This extraction trend can be also observed from hydrogen chloride solution. This work describes the use of this ligand in a PLE to extract plutonium from solution. Polymer ligand films were prepared by dissolving HDEHP ligands and polystyrene beads in THF. The solution was directly deposited onto a 40 mm diameter stainless steel substrate using an automated pipette. HDEHP based PLEs with direct stippling method are shown in Figure 2. The solution was air dried at room temperature overnight to ensure complete evaporation of THF. The plutonium tracer solution was prepared in 0.01, 0.1, 1, and 8M nitric solutions to study the effect of nitric concentration in plutonium extraction. 0.1667 Bq {sup 239}Pu tracer solution was directly stippled on each PLE and was allowed to equilibrate for 3 hours before removing the solution. The plutonium activity of each sample was measured by direct alpha counting to quantify the plutonium recovery by HDEHP PLE. The alpha spectra from alpha spectroscopy are shown in Figure 3. 1:5, 1:10, and 1:20 PLEs had sharp peak with low tailing. 1:2 had an extremely long tail, which is a possible indication that a large amount of ligands caused the film to not form a smooth surface. Also, it can be noted that 1:2 ratio PLE surface was not as rigid as the other ratio PLEs and it was prone to scratching during sample handing. The resolution of alpha spectra was quantified by measuring Full Width at Half of the Maximum (FWHM) using Bortels equation. The tailing component of the peak was also measured along with FWHM. The peak resolutions and tailing measurements for 0.1M nitric solution samples are given in Table 1. The best resolution was achieved with 1:5 PLE and worst was given by 1:2 PLE. The plutonium recovery by HDEHP PLE was dependent on both nitric concentration and ligand to polymer ratio. 1:2 PLE consistently had the highest recovery followed by 1:5 as shown in Figure 4. It should be noted that 1:2 ratio PLEs consistently had long tailing and the ROI of the spectrum had to be increased to encompass total counts from the tracer. 1:10 and 1:20 PLEs had close to zero percent recovery in all nitric concentration except for 0.01M. The highest plutonium recovery was observed for 0.1M nitric acid. 1:5 PLE gave the best combination of alpha spectroscopy resolution and plutonium recovery. Radiography image of samples were generated to study the plutonium distribution on the PLE surface. Samples were placed on an imaging plate (Fujifilm BAS-TR 2025) for 24 hours and the plate was scanned using GE Typhoon FLA 7000 system. The radiography image in Figure 5 shows uneven distribution with hot spots along the edge and in the center of the samples. These hot spots may be the result of highly localized concentration of ligands or surface defects that were observed in SEM. This unevenness in distribution may cause inaccurate activity measurement by alpha spectroscopy due to a bias in the

  4. High energy electron beam curing of epoxy resin systems incorporating cationic photoinitiators

    DOE Patents [OSTI]

    Janke, Christopher J. (Powell, TN); Lopata, Vincent J. (Manitoba, CA); Havens, Stephen J. (Knoxville, TN); Dorsey, George F. (Farragut, TN); Moulton, Richard J. (Lafayette, CA)

    1999-01-01T23:59:59.000Z

    A mixture of epoxy resins such as a semi-solid triglycidyl ether of tris (hydroxyphenyl) methane and a low viscosity bisphenol A glycidyl ether and a cationic photoinitiator such as a diaryliodonium salt is cured by irradiating with a dosage of electron beams from about 50 to about 150 kGy, forming a cross-linked epoxy resin polymer.

  5. Terebinth resin in antiquity: possible uses in the Late Bronze Age Aegean region

    E-Print Network [OSTI]

    Peachey, Claire Patricia

    1995-01-01T23:59:59.000Z

    --resin, fruits, leaves, bark, wood and galls. Some possible uses of terebinth resin in the Late Bronze Aegean region are then explored, as this area is likely to have been one of the intended destinations of the Uluburun ship. A discussion of the accepted...

  6. FLUORINATED HYDROXYTELECHELIC POLYBUTADIENE AS ADDITIVE IN CATIONIC PHOTOPOLYMERIZATION OF AN EPOXY RESIN

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    OF AN EPOXY RESIN B. Ameduri 1 , R. Bongiovanni2 , M. Sangermano2 , A. Priola2 1 Ingénierie et Architectures in original formulations to enable the UV cationic polymerization of a telechelic diepoxy cycloaliphatic resin) values showing a surface modification of the epoxy based system. Indeed, great modifications were noted

  7. Cure Kinetics of Aqueous PhenolFormaldehyde Resins Used for Oriented Strandboard Manufacturing: Analytical

    E-Print Network [OSTI]

    Cure Kinetics of Aqueous Phenol­Formaldehyde Resins Used for Oriented Strandboard Manufacturing their manufacture.2 Differential scanning calorimetry (DSC) is a well-established technique to study the polymer. To evaluate the effect of lignin addition on the curing of phenolic resin, Barry et al.16 obtained

  8. EFFECTS OF RESIN AND WAX ON THE WATER UPTAKE BEHAVIOR OF WOOD STRANDS

    E-Print Network [OSTI]

    Wang, Siqun

    EFFECTS OF RESIN AND WAX ON THE WATER UPTAKE BEHAVIOR OF WOOD STRANDS Yang2hang1 Post and wax are essential additives in the manufactureof composite panels such as OSB. Resin binds wood elements together while wax acts as a water repellent. The objective of this study was to investigate

  9. Acceleration of rate of cure in boron trifluoride amine catalyzed cure of epoxy resins

    SciTech Connect (OSTI)

    Goel, A.B.

    1987-11-10T23:59:59.000Z

    This patent describes the process for the acceleration of the cure rate of an epoxy resin comprising forming a mixture of an epoxy resin with a boron trifluoride-amine complex and an isocyanate compound and curing the mixture at a temperature in the range of from about ambient to about 130/sup 0/C.

  10. High energy electron beam curing of epoxy resin systems incorporating cationic photoinitiators

    DOE Patents [OSTI]

    Janke, C.J.; Lopata, V.J.; Havens, S.J.; Dorsey, G.F.; Moulton, R.J.

    1999-03-02T23:59:59.000Z

    A mixture of epoxy resins such as a semi-solid triglycidyl ether of tris (hydroxyphenyl) methane and a low viscosity bisphenol A glycidyl ether and a cationic photoinitiator such as a diaryliodonium salt is cured by irradiating with a dosage of electron beams from about 50 to about 150 kGy, forming a cross-linked epoxy resin polymer.

  11. Hydro-Mechanical Loading and Compressibility of Fibrous Media for Resin Infusion Processes

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Hydro-Mechanical Loading and Compressibility of Fibrous Media for Resin Infusion Processes P investigating the compressibility behaviour of composite preform with a view of modelling resin infusion Infusion The need for manufacturing large composite parts in the aeronautic industry is ever increasing

  12. PLASTIC RESINS INDUSTRY HIT HARD BY GLOBAL ECONOMIC RECESSION IN 2008

    E-Print Network [OSTI]

    Laughlin, Robert B.

    , but buying only 4.5 billion pounds per month. Although the demand for plastics is ultimately tied to overallPLASTIC RESINS INDUSTRY HIT HARD BY GLOBAL ECONOMIC RECESSION IN 2008 The US plastic resins in the second half of the year. According to the American Chemistry Council (ACC) Plastics Industry Producers

  13. Abstract--Resins are used in nuclear power plants for water ultrapurification. Two approaches are considered in this work

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Abstract--Resins are used in nuclear power plants for water ultrapurification. Two approaches in manufacturing ultrapure water for nuclear power plants. Resins allow the removal of ionic impurities to subparts-per-million. Thereby in nuclear power plants, resins contribute to guarantee personnel safety, to control feed system

  14. Bending properties of epoxy resin matrix composites filled with NiMnGa ferromagnetic shape memory alloy powders

    E-Print Network [OSTI]

    Zheng, Yufeng

    Bending properties of epoxy resin matrix composites filled with Ni­Mn­Ga ferromagnetic shape memory­Mn­Ga Composite materials Mechanical properties Microstructure Two types of epoxy resin matrix composites filled­Mn­Ga epoxy resin composites were reported, yet the bending property of Ni­Mn­Ga-polymer smart composites has

  15. Rheological and thermal study of the curing process of a cycloaliphatic epoxy resin: application to the optimization of the

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    1 Rheological and thermal study of the curing process of a cycloaliphatic epoxy resin: application-4-67-14-37-80; Fax: 33-4-67-14-40-28 ABSTRACT The curing process of a cycloaliphatic epoxy resin was defined using of structure-properties relationships. Keywords: curing kinetics, epoxy resin, dynamic mechanical properties

  16. Comptes Rendus des JNC 16 Toulouse 2009 Suivi du procd de la fabrication Liquid Resin Infusion (LRI) sur

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    Comptes Rendus des JNC 16 Toulouse 2009 Suivi du procédé de la fabrication Liquid Resin Infusion (LRI) sur simulateur industriel par capteurs distribués Monitoring the Liquid Resin Infusion (LRI.HENRAT@hexcel.com Résumé Les procédés par infusion de résine LRI (Liquid Resin Infusion) sont des procédés de fabrication

  17. Mathematical model of cavitation during resin lm infusion process I. Sevostianov a,*, V.E. Verijenko b

    E-Print Network [OSTI]

    Sevostianov, Igor

    Mathematical model of cavitation during resin ®lm infusion process I. Sevostianov a,*, V ®lm infusion (RFI) process. An analytical model is developed to describe the cavitation conditions formation; Resin ®lm infusion 1. Introduction The resin ®lm infusion (RFI) method of producing composite

  18. Thermoelectric heat exchange element

    DOE Patents [OSTI]

    Callas, James J. (Peoria, IL); Taher, Mahmoud A. (Peoria, IL)

    2007-08-14T23:59:59.000Z

    A thermoelectric heat exchange module includes a first substrate including a heat receptive side and a heat donative side and a series of undulatory pleats. The module may also include a thermoelectric material layer having a ZT value of 1.0 or more disposed on at least one of the heat receptive side and the heat donative side, and an electrical contact may be in electrical communication with the thermoelectric material layer.

  19. Proceedings: Heat exchanger workshop

    SciTech Connect (OSTI)

    Not Available

    1987-07-01T23:59:59.000Z

    Heat transfer processes are of controlling importance in the operation of a thermal power plant. Heat exchangers are major cost items and are an important source of problems causing poor power plant availability and performance. A workshop to examine the improvements that can be made to heat exchangers was sponsored by the Electric Power Research Institute (EPRI) on June 10-11, 1986, in Palo Alto, California. This workshop was attended by 25 engineers and scientists representing EPRI-member utilities and EPRI consultants. A forum was provided for discussions related to the design, operation and maintenance of utility heat transfer equipment. The specific objectives were to identify research directions that could significantly improve heat exchanger performance, reliability and life cycle economics. Since there is a great diversity of utility heat transfer equipment in use, this workshop addressed two equipment categories: Boiler Feedwater Heaters (FWH) and Heat Recovery Steam Generators (HRSG). The workshop was divided into the following panel sessions: functional design, mechanical design, operation, suggested research topics, and prioritization. Each panel session began with short presentations by experts on the subject and followed by discussions by the attendees. This report documents the proceedings of the workshop and contains recommendations of potentially valuable areas of research and development. 4 figs.

  20. Fast Neutral Generation by Charge Exchange Reaction and Its Effect on Neutron Production Rate in Inertial Electrostatic Confinement Fusion Systems

    SciTech Connect (OSTI)

    Yoshinaga, S.; Matsuura, H.; Nakao, Y.; Kudo, K. [Kyushu University (Japan)

    2005-05-15T23:59:59.000Z

    Fast neutral generation by charge exchange reaction in inertial electrostatic confinement plasmas is studied by solving the Poisson equation and the Boltzmann equation for fast neutrals. Fusion reactions carried by the charge exchange fast neutrals become appreciable compared with ion-background fusion reaction. It is shown that the fusion reaction between fast neutral and background gas is sensitively affected by experimental parameters (grid voltage, background gas pressure) and ion distribution function.

  1. Hydrocarbon cracking with yttrium exchanged zeolite y catalyst

    SciTech Connect (OSTI)

    Lochow, C.F.; Kovacs, D.B.

    1987-05-12T23:59:59.000Z

    A process is described for cracking a gas oil boiling range hydrocarbon feedstock comprising the step of contacting the feedstock in a catalytic cracking zone under catalytic cracking conditions to produce convulsion products comprising gasoline with a catalyst composition. The process comprises: a Y crystalline aluminosilicate zeolite, having the structure of faujasite and having uniform pore diameters and a silica to alumina mole ratio of at least about 5; an inorganic oxide matrix; and the zeolite having been ion exchanged with a mixture of rare earths prior to compositing with the matrix; and the zeolite having been subsequently further ion exchanged with yttrium following compositing with the matrix, whereby the catalyst composition contains 0.30 to 3.0 wt% yttrium.

  2. Priority Firm Exchange .

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Science (SC)IntegratedSpeedingTechnical News, informationPriority Firm Exchange . . . . . . . . .

  3. Method for recovering and using lignin in adhesive resins

    DOE Patents [OSTI]

    Schroeder, Herbert A. (Ft. Collins, CO)

    1993-01-01T23:59:59.000Z

    Lignin, or a lignin derived material, which has been significantly demethylated (e.g., the demethylated lignin found in the raffinate produced as a by-product of dimethyl sulfide production which can be carried out using the spent liquor from wood pulping operations) can be isolated by a process wherein an organic solvent is added to a lignin-containing aqueous solution. The organic solvent is typically a polar, and at least a partially water-immiscible substance such as, for example, ethyl acetate. The resulting lignin-containing aqueous solution/organic solvent mixture is acidified to produce a water layer which is discarded and an organic solvent layer which contains the demethylated lignin. Upon its recovery, the demethylated lignin is dissolved in an alkaline solution to which an aldehyde source is added to produce a resol-type resin. The aldehyde source may be formaldehyde in solution, paraformaldehyde, hexamethylenetetramine, or other aldehydes including acetaldehyde, furfural, and their derivatives.

  4. Exploration of Ion-Exchanged Glass for Seals Applications 

    E-Print Network [OSTI]

    Ghanbari, Roushan

    2012-10-19T23:59:59.000Z

    to the same point load, the fracture patterns produced can be compared and used as a verification measure. This technology has the potential to be used in passive seal applications. Each image was categorized depending on its fracture as a "3 leaf" or "4 leaf...

  5. Ion Exchange Membrane Cathodes for Scalable Microbial Fuel Cells

    E-Print Network [OSTI]

    -7), complex wastes and wastewaters, such as agricultural waste (8) and domestic wastewater (9, 10), and other electrodes)andthusrepresentmoreusefulmaterialsforreducing the costs of MFCs for wastewater treatment in various wastes and wastewaters (1-3). Diverse organic substrates have been used as electron donors

  6. Exploration of Ion-Exchanged Glass for Seals Applications

    E-Print Network [OSTI]

    Ghanbari, Roushan

    2012-10-19T23:59:59.000Z

    ........................................................................................................ 34 Figure 15. Semitransparent overlay of two images created using the MATLAB ........... 35 Figure 16. Binary, composite image of samples 5 and 7 ............................................... 37 Figure 17. Histogram of „3 leaf? composite images... with normal fit overlay .................. 41 Figure 18. Probability plot of „3 leaf? composite images with normal fit ...................... 42 Figure 19. Histogram of „4 leaf? composite images with normal fit overlay .................. 43 x Page Figure...

  7. Stabilization of Intrazeolitic Cadmium Telluride Nanoclusters by Ion Exchange

    E-Print Network [OSTI]

    and the potential of unique applications in solar energy conversion and photocatalysis,3-5 electronics,6 of semiconduc- tors change markedly in the nanometer size regime, because the ratio of surface-to-bulk atoms increases with decreasing size. The high surface free energy of these nanoclusters is manifested in unusual

  8. Non-aqueous liquid compositions comprising ion exchange polymers

    DOE Patents [OSTI]

    Kim, Yu Seung; Lee, Kwan-Soo; Rockward, Tommy Q. T.

    2013-03-12T23:59:59.000Z

    Compositions, and methods of making thereof, comprising from about 1% to about 5% of a perfluorinated sulfonic acid ionomer or a hydrocarbon-based ionomer; and from about 95% to about 99% of a solvent, said solvent consisting essentially of a polyol; wherein said composition is substantially free of water and wherein said ionomer is uniformly dispersed in said solvent.

  9. Non-aqueous liquid compositions comprising ion exchange polymers

    DOE Patents [OSTI]

    Kim, Yu Seung (Los Alamos, NM); Lee, Kwan-Soo (Blacksburg, VA); Rockward, Tommy Q. T. (Rio Rancho, NM)

    2011-07-19T23:59:59.000Z

    Compositions, and methods of making thereof, comprising from about 1% to about 5% of a perfluorinated sulfonic acid ionomer or a hydrocarbon-based ionomer; and from about 95% to about 99% of a solvent, said solvent consisting essentially of a polyol; wherein said composition is substantially free of water and wherein said ionomer is uniformly dispersed in said solvent.

  10. Small Column Ion Exchange at Savannah River Site Technology Readiness

    Energy Savers [EERE]

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page onYou are now leaving Energy.gov You are now leaving Energy.gov You are being directed offOCHCO Overview OCHCO OverviewRepositoryManagement | DepartmentImpact of TeamingAssessment Report

  11. External Technical Review Report for Small Column Ion Exchange Technology

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122Commercial602 1,39732 DOEDepartment of EnergyEric J.ExploringExternal

  12. Investigating Iron Ions | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Investigating Iron Ions Investigating Iron Ions Computer code provides detailed predictions of highly charged ions in water Using resources at EMSL, scientists obtained...

  13. Helium Ion Microscope | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Helium Ion Microscope Helium Ion Microscope The Helium Ion Microscope promises to advance biological, geochemical, biogeochemical, and surfaceinterface studies using its combined...

  14. Helium Ion Microscope | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Helium Ion Microscope Helium Ion Microscope Bruce Arey discusses the capabilities of EMSL's new helium ion microscope housed in EMSL's Quiet Wing....

  15. A Binghamton Exchange Program UNIVERSITY COLLEGE UTRECHT EXCHANGE PROGRAM

    E-Print Network [OSTI]

    Suzuki, Masatsugu

    A Binghamton Exchange Program UNIVERSITY COLLEGE UTRECHT EXCHANGE PROGRAM THE BINGHAMTON PROGRAM AT UNIVERSITY COLLEGE UTRECHT Utrecht University ranks first among Dutch universi- ties and is one of the finest universities in Europe. Students take courses in the University College Utrecht (UCU), Utrecht University

  16. A Binghamton Exchange Program UTRECHT SCHOOL OF ECONOMICS EXCHANGE PROGRAM

    E-Print Network [OSTI]

    Suzuki, Masatsugu

    A Binghamton Exchange Program UTRECHT SCHOOL OF ECONOMICS EXCHANGE PROGRAM THE BINGHAMTON PROGRAM AT UTRECHT SCHOOL OF ECONOMICS Utrecht University ranks first among Dutch universi- ties and is one of the finest universities in Europe. Students take courses in the Utrecht School of Eco- nomics (USE

  17. Photothermal determination of thermal diffusivity and polymerization depth profiles of polymerized dental resins

    E-Print Network [OSTI]

    Mandelis, Andreas

    emitted diode LED . Due to the highly light dispersive nature of dental resins, the polymerization process a frequency scan. Prior to each frequency scan, photopolymerization was induced using a high power blue light

  18. Numerical and experimental analyses of resin infusion manufacturing processes of composite materials

    E-Print Network [OSTI]

    Wang, Peng; Molimard, Jérôme; Vautrin, Alain; Minni, Jean-Christophe; 10.1177/0021998311421990

    2012-01-01T23:59:59.000Z

    Liquid resin infusion (LRI) processes are promising manufacturing routes to produce large, thick, or complex structural parts. They are based on the resin flow induced, across its thickness, by a pressure applied onto a preform/resin stacking. However, both thickness and fiber volume fraction of the final piece are not well controlled since they result from complex mechanisms which drive the transient mechanical equilibrium leading to the final geometrical configuration. In order to optimize both design and manufacturing parameters, but also to monitor the LRI process, an isothermal numerical model has been developed which describes the mechanical interaction between the deformations of the porous medium and the resin flow during infusion.1, 2 With this numerical model, it is possible to investigate the LRI process of classical industrial part shapes. To validate the numerical model, first in 2D, and to improve the knowledge of the LRI process, this study details a comparison between numerical simulations and...

  19. Activated Resins TB263 11/99 Novagen 1United States & Canada 800-207-0144

    E-Print Network [OSTI]

    Lebendiker, Mario

    ..........................................................................3 Monitoring reaction progress.............................................................................6 Recommended storage conditions by incubation with the ligand in an appropriate buffer. The resin is supplied as a dry powder. PreACT Fractogel

  20. Measurement and modeling of uranium and strategic element sorption by amidoxime resins in natural seawater

    E-Print Network [OSTI]

    Pina-Jordan, Jose Gregorio

    1985-01-01T23:59:59.000Z

    'ulfillment of the requirements for the degree of MASTER OP SCIENCE December i985 Major Subject: Nuclear Engineering MEASUREMENT AND MODELING OF URANIUM AND STRATEGIC ELEMENT SORPTION BY AMIDOXIME RESINS IN NATURAL SEANATER A thesis by JOSE GREGORIO PINA...MEASUREMENT AND MODELING OF URANIUM AND STRATEGIC ELEMENT SORPTION BY AMIDOXIME RESINS IN NATURAL SEAMATER A Thesis by JOSE GREGORIO PINA-JORDAN Submitted to the Graduate College oi' Texas A&M University in partial I...

  1. Destructive-condensation transformations of resinous crude oil by the action of light

    SciTech Connect (OSTI)

    Melikadze, L.D.; Kuprashvili, B.G.; Barabadze, S.S.; Bakhturidze, G.S.; Shatakishvili, T.N.

    1987-08-01T23:59:59.000Z

    The effect of radiation from a mercury-quartz lamp PRK-2 upon native resin-asphaltene substances of Norian, Samgore and Supsin crude oils is examined. Irradiated resin substances from crude oil undergo marked changes - photochemical breakdown to form gaseous hydrocarbons (methane, ethane and propane) and photochemical condensation. During the condensation step molar mass increases and three-dimensional structures are formed, these have a high softening point (above 400/sup 0/C) and do not dissolve in organic solvents.

  2. Effect of external stress on moisture diffusion in an epoxy resin and its composite material

    E-Print Network [OSTI]

    Henson, Michael Chamberlain

    1986-01-01T23:59:59.000Z

    EFFECT OF EXTERNAL STRESS ON MOISTURE DIFFUSION IN AN EPOXY RESIN AND ITS C(MPOSITE MATERIAL A Thesis by MICHAEL CHAMBERLAIN HENSON Submitted to the Graduate College of Texas A&M University in partial fulfillment of the requirement... for the degree of MASTER OF SCIENCE May 1986 Major Subject: Civil Engineering EFFECT OF EXTERNAL STRESS ON MOISTURE DIFFUSION IN AN EPOXY RESIN AND ITS CCNPOSITE MATERIAL A Thesis by MICHAEL CHAMBERLAIN HENSON Approved as to style and content by: (Y...

  3. Effect of resin toughness on fracture behavior of graphite/epoxy composites 

    E-Print Network [OSTI]

    Cohen, Ronald Nelson

    1982-01-01T23:59:59.000Z

    EFFECT OF RESIN TOUGHNESS ON FRACTURE BEHAVIOR OF GRAPHITE/EPOXY COMPOSITES A Thesis Dy RONALD NELSON COHEN Submitted to the Graduate College of Texas ASM University in partial fulfillment of the requirement for the degree of MASTER... OF SCIENCE December 1982 Mlajor Subject: Interdisciplinary Enqi neeri ng EFFECT OF RESIN TOUGHNESS ON FRACTURE BEHAVIOR OF GRAPHITE/EPOXY COMPOSITES A Thesis by RONALD NELSON COHEN Approved as to style and content by: (N. L. Bradley, Cha man) (R. A...

  4. Resin injected bolted connections: A step towards achieving slip-resistant joints in FRP

    E-Print Network [OSTI]

    Mottram, Toby

    of resin ­ slip not more than 0 150.15 mm. 2. Static creep test · Test for determination of design bearing resistance of the resin ­ creep should be less than 0.3 mm during lifetime. 3. Fatigue test B i i t f t t i d t t bli h 4 · Bearing resistance from creep test is used to establish bearing stress ranges. · If total

  5. Technology Performance Exchange (Fact Sheet)

    SciTech Connect (OSTI)

    Not Available

    2012-10-01T23:59:59.000Z

    This fact sheet, 'The Technology Performance Exchange' will be presented at the ET Summit, held at the Pasadena Convention Center on October 15-17, 2012. The Technology Performance Exchange will be a centralized, Web-based portal for finding and sharing energy performance data for commercial building technologies.

  6. Gas Exchange, Partial Pressure Gradients,

    E-Print Network [OSTI]

    Riba Sagarra, Jaume

    Gas Exchange, Partial Pressure Gradients, and the Oxygen Window Johnny E. Brian, Jr., M of circulatory and gas transport physiology, and the best place to start is with normobaric physiology. LIFE affect the precise gas exchange occurring in individual areas of the lungs and body tissues. To make

  7. 4, 125164, 2007 Methanol exchange

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    BGD 4, 125­164, 2007 Methanol exchange between grassland and the atmosphere A. Brunner et al. Title Discussions Biogeosciences Discussions is the access reviewed discussion forum of Biogeosciences Methanol (albrecht.neftel@art.admin.ch) 125 #12;BGD 4, 125­164, 2007 Methanol exchange between grassland

  8. High Temperature Heat Exchanger Project

    SciTech Connect (OSTI)

    Anthony E. Hechanova, Ph.D.

    2008-09-30T23:59:59.000Z

    The UNLV Research Foundation assembled a research consortium for high temperature heat exchanger design and materials compatibility and performance comprised of university and private industry partners under the auspices of the US DOE-NE Nuclear Hydrogen Initiative in October 2003. The objectives of the consortium were to conduct investigations of candidate materials for high temperature heat exchanger componets in hydrogen production processes and design and perform prototypical testing of heat exchangers. The initial research of the consortium focused on the intermediate heat exchanger (located between the nuclear reactor and hydrogen production plan) and the components for the hydrogen iodine decomposition process and sulfuric acid decomposition process. These heat exchanger components were deemed the most challenging from a materials performance and compatibility perspective

  9. Process for separation of zirconium-88, rubidium-83 and yttrium-88

    DOE Patents [OSTI]

    Heaton, Richard C. (Los Alamos, NM); Jamriska, Sr., David J. (Los Alamos, NM); Taylor, Wayne A. (Los Alamos, NM)

    1994-01-01T23:59:59.000Z

    A process for selective separation of strontium-82 and strontium-85 from proton irradiated molybdenum targets is provided and includes dissolving the molybdenum target in a hydrogen peroxide solution to form a first ion-containing solution, passing the first ion-containing solution through a first cationic resin whereby ions selected from the group consisting of molybdenum, niobium, technetium, selenium, vanadium, arsenic, germanium, zirconium and rubidium remain in the first ion-containing solution while ions selected from the group consisting of rubidium, zinc, beryllium, cobalt, iron, manganese, chromium, strontium, yttrium and zirconium are selectively adsorbed by the first resin, contacting the first resin with an acid solution capable of stripping adsorbed ions from the first cationic exchange resin whereby the adsorbed ions are removed from the first resin to form a second ion-containing solution, evaporating the second ion-containing solution for time sufficient to remove substantially all of the acid and water from the second ion-containing solution whereby a residue remains, dissolving the residue from the evaporated second-ion containing solution in a dilute acid to form a third ion-containing solution, said third ion-containing solution having an acid molarity adapted to permit said ions to be adsorbed by a cationic exchange resin, passing the third ion-containing solution through a second cationic resin whereby the ions are adsorbed by the second resin, contacting the second resin with a dilute sulfuric acid solution whereby the adsorbed ions selected from the group consisting of rubidium, zinc, beryllium, cobalt, iron, manganese, chromium, and zirconium are selectively removed from the second resin, and contacting the second resin with a dilute acid solution whereby the adsorbed strontium ions are selectively removed. Zirconium, rubidium, and yttrium radioisotopes can also be recovered with additional steps.

  10. The effects of phosphorous ligands on the gas phase ligand exchange reactions of dichromium ionic cluster fragments

    E-Print Network [OSTI]

    Nguyen, Hanh Duc

    1991-01-01T23:59:59.000Z

    ligands have been investigated by Fourier transform ion cyclotron resonance mass spectrometer (FT-ICR). This work demonstrates that the rates for disappearance of Cr, (CO)?' (y = 5-6) by ligand exchange reactions with phosphorus ligands depend... cyclotron resonance mass spectrometer (FT-ICR). FT-ICR is a particularly valuable technique for studying ion-molecule reaction chemistry because the experimental sequences are separated in time, not in space. Mass selective isolation of ions can...

  11. Energy-Exchange Project

    SciTech Connect (OSTI)

    Not Available

    1982-04-01T23:59:59.000Z

    The purpose of the study was to determine what energy savings can be achieved by coordinating the resources and requirements of two facilities, the 26th Ward Water Pollution Control Plant (WPCP) and a housing development named Starrett City with its own total energy system. It was determined that three energy exchange options were economically and technically feasible. These include: the transfer of digester gas produced at the 26th Ward to the boilers at the Starrett City's total energy plant (TEP); the transfer of hot water heated at the TEP to the 26th Ward for space and process heating; and the transfer of coal effluent waste water from the 26th Ward to the condenser cooling systems at the TEP. Technical information is presented to support the findings. The report addresses those tasks of the statement of work dedicated to data acquisition, analysis, and energy conservation strategies internal to the Starrett City TEP and the community it supplies as well as to the 26th Ward WPCP. (MCW)

  12. Heat exchanger using graphite foam

    DOE Patents [OSTI]

    Campagna, Michael Joseph; Callas, James John

    2012-09-25T23:59:59.000Z

    A heat exchanger is disclosed. The heat exchanger may have an inlet configured to receive a first fluid and an outlet configured to discharge the first fluid. The heat exchanger may further have at least one passageway configured to conduct the first fluid from the inlet to the outlet. The at least one passageway may be composed of a graphite foam and a layer of graphite material on the exterior of the graphite foam. The layer of graphite material may form at least a partial barrier between the first fluid and a second fluid external to the at least one passageway.

  13. Heat exchanger with ceramic elements

    DOE Patents [OSTI]

    Corey, John A. (North Troy, NY)

    1986-01-01T23:59:59.000Z

    An annular heat exchanger assembly includes a plurality of low thermal growth ceramic heat exchange members with inlet and exit flow ports on distinct faces. A mounting member locates each ceramic member in a near-annular array and seals the flow ports on the distinct faces into the separate flow paths of the heat exchanger. The mounting member adjusts for the temperature gradient in the assembly and the different coefficients of thermal expansion of the members of the assembly during all operating temperatures.

  14. Jute fiber composites from coal, super clean coal, and petroleum vacuum residue-modified phenolic resin

    SciTech Connect (OSTI)

    Ahmaruzzaman, M.; Sharma, D.K. [Indian Institute of Technology, New Delhi (India). Center of Energy Studies

    2005-07-01T23:59:59.000Z

    Jute fiber composites were prepared with novolac and coal, phenolated-oxidized super clean coal (POS), petroleum vacuum residue (XVR)-modified phenol-formaldehyde (novolac) resin. Five different type of resins, i.e., coal, POS, and XVR-modified resins were used by replacing (10% to 50%) with coal, POS, and XVR. The composites thus prepared have been characterized by tensile strength, hardness, thermogravimetric analysis (TGA), Fourier-transfer infrared (FT-IR), water absorption, steam absorption, and thickness swelling studies. Twenty percent POS-modified novolac composites showed almost the same tensile strength as that of pure novolac composites. After 30% POS incorporation, the tensile strength decreased to 25.84MPa from 33.96MPa in the case of pure novolac resin composites. However, after 50% POS incorporation, the percent retention of tensile strength was appreciable, i.e., 50.80% retention of tensile strength to that of pure novolac jute composites. The tensile strength of coal and XVR-rnodified composites showed a trend similar to that shown by POS-modified novolac resin composites. However, composites prepared from coal and XVR-modified resin with 50% phenol replacement showed 25.4% and 42% tensile strength retention, respectively, compared to that of pure novolac jute composites. It was found that the hardness of the modified composites slightly decreased with an increase in coal, POS, and XVR incorporation in the resin. The XVR-modified composites showed comparatively lower steam absorption than did coal or POS-modified composites. The thermal stability of the POS-modified composites was the highest among the composites studied. The detailed results obtained are being reported.

  15. Understanding microbe-mineral electron exchange | EMSL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    insight into how bacteria, such as S. oneidensis (above), exchange electrons with minerals in their surroundings as part of cellular respiration-a series of electron exchanges...

  16. Advanced Materials for Proton Exchange Membranes | Department...

    Broader source: Energy.gov (indexed) [DOE]

    Advanced Materials for Proton Exchange Membranes Advanced Materials for Proton Exchange Membranes A presentation to the High Temperature Membranes Working Group meeting, May 19,...

  17. Competing effects of magnetocrystalline anisotropy and exchange...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    effects of magnetocrystalline anisotropy and exchange bias in epitaxial FeIrMn bilayers. Competing effects of magnetocrystalline anisotropy and exchange bias in epitaxial FeIrMn...

  18. Residential Exchange History Fact Sheet - June 2007

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    history of BPA's Residential Exchange Program June 2007 F rom its start, the Residential Exchange Program (REP) has been a source of nearly continuous controversy. Its roots go...

  19. Ion detector

    DOE Patents [OSTI]

    Tullis, Andrew M. (Livermore, CA)

    1987-01-01T23:59:59.000Z

    An improved ion detector device of the ionization detection device chamber ype comprises an ionization chamber having a central electrode therein surrounded by a cylindrical electrode member within the chamber with a collar frictionally fitted around at least one of the electrodes. The collar has electrical contact means carried in an annular groove in an inner bore of the collar to contact the outer surface of the electrode to provide electrical contact between an external terminal and the electrode without the need to solder leads to the electrode.

  20. Heat exchange assembly

    DOE Patents [OSTI]

    Lowenstein, Andrew; Sibilia, Marc; Miller, Jeffrey; Tonon, Thomas S.

    2004-06-08T23:59:59.000Z

    A heat exchange assembly comprises a plurality of plates disposed in a spaced-apart arrangement, each of the plurality of plates includes a plurality of passages extending internally from a first end to a second end for directing flow of a heat transfer fluid in a first plane, a plurality of first end-piece members equaling the number of plates and a plurality of second end-piece members also equaling the number of plates, each of the first and second end-piece members including a recessed region adapted to fluidly connect and couple with the first and second ends of the plate, respectively, and further adapted to be affixed to respective adjacent first and second end-piece members in a stacked formation, and each of the first and second end-piece members further including at least one cavity for enabling entry of the heat transfer fluid into the plate, exit of the heat transfer fluid from the plate, or 180.degree. turning of the fluid within the plate to create a serpentine-like fluid flow path between points of entry and exit of the fluid, and at least two fluid conduits extending through the stacked plurality of first and second end-piece members for providing first fluid connections between the parallel fluid entry points of adjacent plates and a fluid supply inlet, and second fluid connections between the parallel fluid exit points of adjacent plates and a fluid discharge outlet so that the heat transfer fluid travels in parallel paths through each respective plate.

  1. Hear Exchange Assembly

    SciTech Connect (OSTI)

    Lowenstein, Andrew (Princeton, NJ); Sibilia, Marc (Princeton, NJ); Miller, Jeffrey (Rocky Hill, NJ); Tonon, Thomas S. (Princeton, NJ)

    2003-05-27T23:59:59.000Z

    A heat exchange assembly comprises a plurality of plates disposed in a spaced-apart arrangement, each of the plurality of plates includes a plurality of passages extending internally from a first end to a second end for directing flow of a heat transfer fluid in a first plane, a plurality of first end-piece members equaling the number of plates and a plurality of second end-piece members also equaling the number of plates, each of the first and second end-piece members including a recessed region adapted to fluidly connect and couple with the first and second ends of the plate, respectively, and further adapted to be affixed to respective adjacent first and second end-piece members in a stacked formation, and each of the first and second end-piece members further including at least one cavity for enabling entry of the heat transfer fluid into the plate, exit of the heat transfer fluid from the plate, or 180.degree. turning of the fluid within the plate to create a serpentine-like fluid flow path between points of entry and exit of the fluid, and at least two fluid conduits extending through the stacked plurality of first and second end-piece members for providing first fluid connections between the parallel fluid entry points of adjacent plates and a fluid supply inlet, and second fluid connections between the parallel fluid exit points of adjacent plates and a fluid discharge outlet so that the heat transfer fluid travels in parallel paths through each respective plate.

  2. C60 Secondary Ion Fourier Transform Ion Cyclotron Resonance Mass...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    C60 Secondary Ion Fourier Transform Ion Cyclotron Resonance Mass Spectrometry. C60 Secondary Ion Fourier Transform Ion Cyclotron Resonance Mass Spectrometry. Abstract: Secondary...

  3. Krypton charge exchange cross sections for Hall effect thruster models

    SciTech Connect (OSTI)

    Hause, Michael L. [Institute for Scientific Research, Boston College, Chestnut Hill, Massachusetts 02159 (United States); Prince, Benjamin D.; Bemish, Raymond J. [Air Force Research Laboratory, Space Vehicles Directorate, Kirtland AFB, New Mexico 87117 (United States)

    2013-04-28T23:59:59.000Z

    Following discharge from a Hall effect thruster, charge exchange occurs between ions and un-ionized propellant atoms. The low-energy cations produced can disturb operation of onboard instrumentation or the thruster itself. Charge-exchange cross sections for both singly and doubly charged propellant atoms are required to model these interactions. While xenon is the most common propellant currently used in Hall effect thrusters, other propellants are being considered, in particular, krypton. We present here guided-ion beam measurements and comparisons to semiclassical calculations for Kr{sup +} + Kr and Kr{sup 2+} + Kr cross sections. The measurements of symmetric Kr{sup +} + Kr charge exchange are in good agreement with both the calculations including spin-orbit effects and previous measurements. For the symmetric Kr{sup 2+} + Kr reaction, we present cross section measurements for center-of-mass energies between 1 eV and 300 eV, which spans energies not previously examined experimentally. These cross section measurements compare well with a simple one-electron transfer model. Finally, cross sections for the asymmetric Kr{sup 2+} + Kr {yields} Kr{sup +} + Kr{sup +} reaction show an onset near 12 eV, reaching cross sections near constant value of 1.6 A{sup 2} with an exception near 70-80 eV.

  4. Asset Prices and Exchange Rates

    E-Print Network [OSTI]

    Pavlova, Anna

    2003-08-01T23:59:59.000Z

    This paper develops a simple two-country, two-good model, in which the real exchange rate, stock and bond prices are jointly determined. The model predicts that ...

  5. Asset Prices and Exchange Rates

    E-Print Network [OSTI]

    Pavlova, Anna

    2004-11-30T23:59:59.000Z

    This paper develops a simple two-country, two-good model, in which the real exchange rate, stock and bond prices are jointly determined. The model predicts that stock market prices are correlated ...

  6. Energy Efficiency Exchange 2015 Schedule

    Broader source: Energy.gov [DOE]

    The schedule for Energy Efficiency Exchange 2015 is now available. Attendees will have the option of attending a variety of training sessions offered within 10 tracks during the times listed below....

  7. Optimization of Heat Exchanger Cleaning 

    E-Print Network [OSTI]

    Siegell, J. H.

    1986-01-01T23:59:59.000Z

    The performance of heat integration systems is quantified in terms of the amount of heat that is recovered. This decreases with time due to increased fouling of the heat exchange surface. Using the "Total Fouling Related Expenses (TFRE)" approach...

  8. Designing Flexible Heat Exchanger Networks

    E-Print Network [OSTI]

    Gautam, R.; Chen, H. S.; Wareck, J. S.

    Procedures and methods used for designing flexible heat exchanger networks are described. The general approach consists of defining the flexibility problem as a set of cases. Pinch Technology is then used to develop an initial network design...

  9. Dynamic response of phenolic resin and its carbon-nanotube composites to shock wave loading

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Arman, B. [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States) and Texas A and M Univ., College Station, TX (United States); An, Q. [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States) and California Institute of Technology, Pasedena, CA (United States); Luo, S. N. [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Desai, T. G. [Advanced Cooling Technologies, Inc., Lancaster, PA (United States); Tonks, D. L. [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Cagin, T. [Texas A and M Univ., College Station, TX (United States); Goddard III, W. A. [California Institute of Technology, Pasedena, CA (United States)

    2011-01-01T23:59:59.000Z

    We investigate with nonreactive molecular dynamics simulations the dynamic response of phenolic resin and its carbon-nanotube (CNT) composites to shock wave compression. For phenolic resin, our simulations yield shock states in agreement with experiments on similar polymers except the “phase change” observed in experiments, indicating that such phase change is chemical in nature. The elastic–plastic transition is characterized by shear stress relaxation and atomic-level slip, and phenolic resin shows strong strain hardening. Shock loading of the CNT-resin composites is applied parallel or perpendicular to the CNT axis, and the composites demonstrate anisotropy in wave propagation, yield and CNT deformation. The CNTs induce stress concentrations in the composites and may increase the yield strength. Our simulations suggest that the bulk shock response of the composites depends on the volume fraction, length ratio, impact cross-section, and geometry of the CNT components; the short CNTs in current simulations have insignificant effect on the bulk response of resin polymer.

  10. Dynamic response of phenolic resin and its carbon-nanotube composites to shock wave loading

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Arman, B.; An, Q.; Luo, S. N.; Desai, T. G.; Tonks, D. L.; Cagin, T.; Goddard III, W. A.

    2011-01-01T23:59:59.000Z

    We investigate with nonreactive molecular dynamics simulations the dynamic response of phenolic resin and its carbon-nanotube (CNT) composites to shock wave compression. For phenolic resin, our simulations yield shock states in agreement with experiments on similar polymers except the “phase change” observed in experiments, indicating that such phase change is chemical in nature. The elastic–plastic transition is characterized by shear stress relaxation and atomic-level slip, and phenolic resin shows strong strain hardening. Shock loading of the CNT-resin composites is applied parallel or perpendicular to the CNT axis, and the composites demonstrate anisotropy in wave propagation, yield and CNT deformation. Themore »CNTs induce stress concentrations in the composites and may increase the yield strength. Our simulations suggest that the bulk shock response of the composites depends on the volume fraction, length ratio, impact cross-section, and geometry of the CNT components; the short CNTs in current simulations have insignificant effect on the bulk response of resin polymer.« less

  11. Anion exchange polymer electrolytes

    DOE Patents [OSTI]

    Kim, Yu Seung; Kim, Dae Sik; Lee, Kwan-Soo

    2013-07-23T23:59:59.000Z

    Solid anion exchange polymer electrolytes and compositions comprising chemical compounds comprising a polymeric core, a spacer A, and a guanidine base, wherein said chemical compound is uniformly dispersed in a suitable solvent and has the structure: ##STR00001## wherein: i) A is a spacer having the structure O, S, SO.sub.2, --NH--, --N(CH.sub.2).sub.n, wherein n=1-10, --(CH.sub.2).sub.n--CH.sub.3--, wherein n=1-10, SO.sub.2-Ph, CO-Ph, ##STR00002## wherein R.sub.5, R.sub.6, R.sub.7 and R.sub.8 each are independently --H, --NH.sub.2, F, Cl, Br, CN, or a C.sub.1-C.sub.6 alkyl group, or any combination of thereof; ii) R.sub.9, R.sub.10, R.sub.11, R.sub.12, or R.sub.13 each independently are --H, --CH.sub.3, --NH.sub.2, --NO, --CH.sub.nCH.sub.3 where n=1-6, HC.dbd.O--, NH.sub.2C.dbd.O--, --CH.sub.nCOOH where n=1-6, --(CH.sub.2).sub.n--C(NH.sub.2)--COOH where n=1-6, --CH--(COOH)--CH.sub.2--COOH, --CH.sub.2--CH(O--CH.sub.2CH.sub.3).sub.2, --(C.dbd.S)--NH.sub.2, --(C.dbd.NH)--N--(CH.sub.2).sub.nCH.sub.3, where n=0-6, --NH--(C.dbd.S)--SH, --CH.sub.2--(C.dbd.O)--O--C(CH.sub.3).sub.3, --O--(CH.sub.2).sub.n--CH--(NH.sub.2)--COOH, where n=1-6, --(CH.sub.2).sub.n--CH.dbd.CH wherein n=1-6, --(CH.sub.2).sub.n--CH--CN wherein n=1-6, an aromatic group such as a phenyl, benzyl, phenoxy, methylbenzyl, nitrogen-substituted benzyl or phenyl groups, a halide, or halide-substituted methyl groups; and iii) wherein the composition is suitable for use in a membrane electrode assembly.

  12. High Current Ion Source Development for Heavy Ion Fusion

    SciTech Connect (OSTI)

    Westenskow, G A; Grote, D P; Kwan, J W

    2003-09-04T23:59:59.000Z

    We are developing high-current-density high-brightness sources for Heavy Ion Fusion applications. Heavy ion driven inertial fusion requires beams of high brightness in order to achieve high power density at the target for high target gain. At present, there are no existing ion source types that can readily meet all the driver HIF requirements, though sources exist which are adequate for present experiments and which with further development may achieve driver requirements. Our two major efforts have been on alumino-silicate sources and RF plasma sources. Experiments being performed on a 10-cm alumino-silicate source are described. To obtain a compact system for a HIF driver we are studying RF plasma sources where low current beamlets are combined to produce a high current beam. A 80-kV 20-{micro}s source has produced up to 5 mA of Ar{sup +} in a single beamlet. The extraction current density was 100 mA/cm{sup 2}. We present measurements of the extracted current density as a function of RF power and gas pressure, current density uniformity, emittance, and energy dispersion (due to charge exchange).

  13. Self-regenerating column chromatography

    DOE Patents [OSTI]

    Park, W.K.

    1995-05-30T23:59:59.000Z

    The present invention provides a process for treating both cations and anions by using a self-regenerating, multi-ionic exchange resin column system which requires no separate regeneration steps. The process involves alternating ion-exchange chromatography for cations and anions in a multi-ionic exchange column packed with a mixture of cation and anion exchange resins. The multi-ionic mixed-charge resin column works as a multi-function column, capable of independently processing either cationic or anionic exchange, or simultaneously processing both cationic and anionic exchanges. The major advantage offered by the alternating multi-function ion exchange process is the self-regeneration of the resins.

  14. Multi-block sulfonated poly(phenylene) copolymer proton exchange membranes

    DOE Patents [OSTI]

    Fujimoto, Cy H. (Albuquerque, NM); Hibbs, Michael (Albuquerque, NM); Ambrosini, Andrea (Albuquerque, NM)

    2012-02-07T23:59:59.000Z

    Improved multi-block sulfonated poly(phenylene) copolymer compositions, methods of making the same, and their use as proton exchange membranes (PEM) in hydrogen fuel cells, direct methanol fuel cells, in electrode casting solutions and electrodes. The multi-block architecture has defined, controllable hydrophobic and hydrophilic segments. These improved membranes have better ion transport (proton conductivity) and water swelling properties.

  15. Ion Monitoring

    DOE Patents [OSTI]

    Orr, Christopher Henry (Calderbridge, GB); Luff, Craig Janson (Calderbridge, GB); Dockray, Thomas (Calderbridge, GB); Macarthur, Duncan Whittemore (Los Alamos, NM)

    2003-11-18T23:59:59.000Z

    The apparatus and method provide a technique for significantly reducing capacitance effects in detector electrodes arising due to movement of the instrument relative to the item/location being monitored in ion detection based techniques. The capacitance variations are rendered less significant by placing an electrically conducting element between the detector electrodes and the monitored location/item. Improved sensitivity and reduced noise signals arise as a result. The technique also provides apparatus and method suitable for monitoring elongate items which are unsuited to complete enclosure in one go within a chamber. The items are monitored part by part as the pass through the instrument, so increasing the range of items or locations which can be successfully monitored.

  16. Effects of electron exchange-correlation potential on electrostatic oscillations in single-walled carbon nanotubes

    SciTech Connect (OSTI)

    Khan, S. A., E-mail: sakhan@ncp.edu.pk; Hassan, Sunia [National Centre for Physics, Quaid-i-Azam University Campus, Islamabad 45320 (Pakistan)

    2014-05-28T23:59:59.000Z

    Using macroscopic quantum hydrodynamic formulation, we study the dispersion properties of electrostatic electron plasma oscillations in single-walled carbon nanotubes. The electrons and ions are considered uniformly distributed over the cylindrical surface of a nanotube thus forming a two-component (electron-ion) quantum plasma system. Electron degeneracy via Fermi-Dirac statistics as well as electron exchange and correlation effects is taken into account. It is found that the quantum (Bohm) potential arising due to fermionic nature of electrons and exchange-correlations effects has significant impact on the wave. The frequency of wave is influenced by variation in azimuthal index and radius of the nanotube. The results are analyzed numerically for typical systems for relatively longer wavelength waves and possible consequences are discussed. The results can be important in general understanding of the role of exchange-correlation potential in quantum hydrodynamic treatment of charge-carriers in nanotubes.

  17. Ion funnel ion trap and process

    DOE Patents [OSTI]

    Belov, Mikhail E [Richland, WA; Ibrahim, Yehia M [Richland, WA; Clowers, Biran H [West Richland, WA; Prior, David C [Hermiston, OR; Smith, Richard D [Richland, WA

    2011-02-15T23:59:59.000Z

    An ion funnel trap is described that includes a inlet portion, a trapping portion, and a outlet portion that couples, in normal operation, with an ion funnel. The ion trap operates efficiently at a pressure of .about.1 Torr and provides for: 1) removal of low mass-to-charge (m/z) ion species, 2) ion accumulation efficiency of up to 80%, 3) charge capacity of .about.10,000,000 elementary charges, 4) ion ejection time of 40 to 200 .mu.s, and 5) optimized variable ion accumulation times. Ion accumulation with low concentration peptide mixtures has shown an increase in analyte signal-to-noise ratios (SNR) of a factor of 30, and a greater than 10-fold improvement in SNR for multiply charged analytes.

  18. Resole resin products derived from fractionated organic and aqueous condensates made by fast-pyrolysis of biomass materials

    DOE Patents [OSTI]

    Chum, Helena L. (8448 Allison Ct., Arvada, CO 80005); Black, Stuart K. (4976 Raleigh St., Denver, CO 80212); Diebold, James P. (57 N. Yank Way, Lakewood, CO 80228); Kreibich, Roland E. (4201 S. 344th, Auburn, WA 98001)

    1993-01-01T23:59:59.000Z

    A process for preparing phenol-formaldehyde resole resins by fractionating organic and aqueous condensates made by fast-pyrolysis of biomass materials while using a carrier gas to move feed into a reactor to produce phenolic-containing/neutrals in which portions of the phenol normally contained in said resins are replaced by a phenolic/neutral fractions extract obtained by fractionation.

  19. Epoxy Resin-Photopolymer Composites for Volume Timothy J. Trentler, Joel E. Boyd, and Vicki L. Colvin*

    E-Print Network [OSTI]

    Epoxy Resin-Photopolymer Composites for Volume Holography Timothy J. Trentler, Joel E. Boyd by mixing photopo- lymerizable vinyl monomers with a liquid epoxy resin and an amine hardener. A solid matrix is formed in situ as the epoxy cures at room temperature. The unreacted vinyl monomers

  20. Characterization of the pentacene thin-film transistors with an epoxy resin-based polymeric gate insulator

    E-Print Network [OSTI]

    Boyer, Edmond

    Characterization of the pentacene thin-film transistors with an epoxy resin-based polymeric gate seeking desirable semi- conductor/insulator combinations [3]. In this study, we adopted an epoxy resin fabricated and characterized. SU-8, a reliable epoxy-based pho- toresist, is tested as a potential highly

  1. Processing and property investigation of single-walled carbon nanotube (SWNT) buckypaper/epoxy resin matrix nanocomposites

    E-Print Network [OSTI]

    Das, Suman

    buckypaper was realized by infiltrating acetone diluted epoxy resin (Epon 862/EPI Cure W system) alongProcessing and property investigation of single-walled carbon nanotube (SWNT) buckypaper/epoxy resin matrix nanocomposites Zhi Wanga , Zhiyong Lianga , Ben Wanga,*, Chuck Zhanga , Leslie Kramerb

  2. Resole resin products derived from fractionated organic and aqueous condensates made by fast-pyrolysis of biomass materials

    DOE Patents [OSTI]

    Chum, H.L.; Black, S.K.; Diebold, J.P.; Kreibich, R.E.

    1993-08-10T23:59:59.000Z

    A process for preparing phenol-formaldehyde resole resins by fractionating organic and aqueous condensates made by fast-pyrolysis of biomass materials while using a carrier gas to move feed into a reactor to produce phenolic-containing/neutrals in which portions of the phenol normally contained in said resins are replaced by a phenolic/neutral fractions extract obtained by fractionation.

  3. Resin {sup 90}Y microsphere activity measurements for liver brachytherapy

    SciTech Connect (OSTI)

    Dezarn, William A.; Kennedy, Andrew S. [Wake Radiology Oncology, Cary, North Carolina 27518 (United States)

    2007-06-15T23:59:59.000Z

    The measurement of the radioactivity administered to the patient is one of the major components of {sup 90}Y microsphere liver brachytherapy. The activity of {sup 90}Y microspheres in a glass delivery vial was measured in a dose calibrator. The calibration value to use for {sup 90}Y in the dose calibrator was verified using an activity calibration standard provided by the microsphere manufacturer. This method allowed for the determination of a consistent, reproducible local activity standard. Additional measurements were made to determine some of the factors that could affect activity measurement. The axial response of the dose calibrator was determined by the ratio of activity measurements at the bottom and center of the dose calibrator. The axial response was 0.964 for a glass shipping vial, 1.001 for a glass V-vial, and 0.988 for a polycarbonate V-vial. Comparisons between activity measurements in the dose calibrator and those using a radiation survey meter were found to agree within 10%. It was determined that the dose calibrator method was superior to the survey meter method because the former allowed better defined measurement geometry and traceability of the activity standard back to the manufacturer. Part of the preparation of resin {sup 90}Y microspheres for patient delivery is to draw out a predetermined activity from a shipping vial and place it into a V-vial for delivery to the patient. If the drawn activity was placed in a glass V-vial, the activity measured in the dose calibrator with a glass V-vial was 4% higher than the drawn activity from the shipping vial standard. If the drawn activity was placed in a polycarbonate V-vial, the activity measured in the dose calibrator with a polycarbonate V-vial activity was 20% higher than the drawn activity from the shipping vial standard. Careful characterization of the local activity measurement standard is recommended instead of simply accepting the calibration value of the dose calibrator manufacturer.

  4. Heavy Ion Event Displays

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    simulated collisions of lead ions in the LHC experiments. Additional photos, video and information are available at these links: Lead-ion collision images from the ALICE...

  5. A Fully Biobased Epoxy Resin from Vegetable Oils: From the Synthesis of the Precursors by Thiol-ene Reaction to the Study of the Final Material

    E-Print Network [OSTI]

    Boyer, Edmond

    A Fully Biobased Epoxy Resin from Vegetable Oils: From the Synthesis of the Precursors by Thiol agent for bio-based epoxy resin. The thermal crosslinking reaction between AGSO and epoxi- dized linseed and thermal behav- iors. But, the substitution of bis-phenol A based epoxy resins by materials coming from

  6. The nature and fate of natural resins in the geosphere - VIII - NMR and Py-GC-MS characterization of soluble labdanoid polymers isolated from holocene class I resins.

    SciTech Connect (OSTI)

    Clifford, D. J.; Hatcher, P. G.; Botto, R. E.; Muntean, J. V.; Michaels, B.; Anderson, K. B.; Chemistry; Pennsylvania State Univ.; Amoco Oil Co.

    1997-01-01T23:59:59.000Z

    Soluble polylabdanoids isolated by sequential solvent extraction have been characterized by liquid-state {sup 13}C- and {sup 1}H NMR and {sup 13}C-{sup 1}H HMQC (heteronuclear correlation) NMR spectroscopy in addition to solid-state NMR and Py-GC-MS techniques. Two Holocene resins originating from Santander, Colombia and Mombasa, Kenya were analyzed. Soluble polymers were isolated by extraction with a 1:1 (v/v) methylene chloride-methanol mixture following sequential extractions with methylene chloride and methanol. The molecular weight of polymer extracts was shown by GPC analyses to exceed that of non-polymeric occluded terpenoids. Py-GC-MS, solid-state {sup 13}C CP/MAS and {sup 13}C cross-polarization/depolarization NMR spectroscopy results indicated that chemical compositions of soluble polymers isolated from immature resins are highly representative of the structure of corresponding insoluble polymers, i.e. polylabdatrienes. These data provide evidence for cross-linking or cyclization of side-chain olefinic carbons during or shortly after polymerization. Generally, the characterization of soluble resin polymers by liquid-state NMR spectroscopy has proven to be an excellent means for investigating the maturation mechanism of polylabdanoid resinites, and has potential for furthering the application of Class I resinites as geothermal indicators.

  7. Information Exchange for theInformation Exchange for the Development of SustainableDevelopment of Sustainable

    E-Print Network [OSTI]

    Information Exchange for theInformation Exchange for the Development of SustainableDevelopment influenced the development ofthe development of sustainable wood process industrysustainable wood process industry substantiallysubstantially .. Information Exchange for the development of Sustainable Wood Process

  8. The Mechanism Responsible for Extraordinary Cs-ion Selectivity in Crystalline Silicotitanate

    SciTech Connect (OSTI)

    Celestian,A.; Kubicki, J.; Hanson, J.; Clearfield, A.; Parise, J.

    2008-01-01T23:59:59.000Z

    Combining information from time-resolved X-ray and neutron scattering with theoretical calculations has revealed the elegant mechanism whereby hydrogen crystalline silicotitanate (H-CST; H2Ti2SiO7{center_dot}1.5H2O) achieves its remarkable ion-exchange selectivity for cesium. Rather than a simple ion-for-ion displacement reaction into favorable sites, which has been suggested by static structural studies of ion-exchanged variants of CST, Cs+ exchange proceeds via a two-step process mediated by conformational changes in the framework. Similar to the case of ion channels in proteins, occupancy of the most favorable site does not occur until the first lever, cooperative repulsive interactions between water and the initial Cs-exchange site, repels a hydrogen lever on the silicotitanate framework. Here we show that these interactions induce a subtle conformational rearrangement in CST that unlocks the preferred Cs site and increases the overall capacity and selectivity for ion exchange.

  9. Delayed neutron assay to test sorbers for uranium-from-seawater applications

    E-Print Network [OSTI]

    Nitta, Cynthia K.

    1982-01-01T23:59:59.000Z

    Delayed Fission Neutron (DFN) assay has been applied to the measurement of uranium content in sorbers exposed to natural seawater for the purpose of evaluating advanced ion exchange resins. DFN assay was found to be ...

  10. Bismuth generator method

    DOE Patents [OSTI]

    Bray, Lane Allan (Richland, WA); DesChane, Jaquetta R. (Pasco, WA)

    1998-01-01T23:59:59.000Z

    A method for separating .sup.213 Bi from a solution of radionuclides wherein the solution contains a concentration of the chloride ions and hydrogen ions adjusted to allow the formation of a chloride complex. The solution is then brought into contact with an anion exchange resin, whereupon .sup.213 Bi is absorbed from the solution and adhered onto the anion exchange resin in the chloride complex. Other non-absorbing radionuclides such as .sup.225 Ra, .sup.225 Ac, and .sup.221 Fr, along with HCl are removed from the anion exchange resin with a scrub solution. The .sup.213 Bi is removed from the anion exchange resin by washing the anion exchange resin with a stripping solution free of chloride ions and with a reduced hydrogen ion concentration which breaks the chloride anionic complex, releasing the .sup.213 Bi as a cation. In a preferred embodiment of the present invention, the anion exchange resin is provided as a thin membrane, allowing for extremely rapid adherence and stripping of the .sup.213 Bi. A preferred stripping solution for purification of .sup.213 Bi for use in medical applications includes sodium acetate, pH 5.5. A protein conjugated with bifunctional chelating agents in vivo with the NaOAc, to receive the .sup.213 Bi as it is being released from the anion exchange resin.

  11. Numerical study of the characteristics of the ion and fast atom beams in an end-Hall ion source

    SciTech Connect (OSTI)

    Oudini, N. [Universite de Toulouse, UPS, INPT, LAPLACE (Laboratoire Plasma et Conversion d'Energie), 118 route de Narbonne, F-31062 Toulouse Cedex 9 (France); Garrigues, L.; Hagelaar, G. J. M.; Boeuf, J. P. [Universite de Toulouse, UPS, INPT, LAPLACE (Laboratoire Plasma et Conversion d'Energie), 118 route de Narbonne, F-31062 Toulouse Cedex 9 (France); CNRS, LAPLACE, F-31062 Toulouse (France)

    2012-10-15T23:59:59.000Z

    An end-Hall ion source is a cylindrical magnetized device of few centimeters in length able to generate an ion beam with a current of typically 1 A and ion energies in the range of 100 eV. This ion source does not use acceleration grids, has a relatively large ion beam divergence, and is well suited for ion assisted deposition processes. In this paper, a self-consistent two-dimensional quasi-neutral model of an end-Hall ion source is used to understand the parameters controlling the characteristics of the extracted. The model results underline the role of charge exchange collisions on beam properties. The calculated energy distribution functions reveal the existence of groups of slow ions and fast neutrals. Ion mean energy corresponds to roughly 60% of the discharge voltage, while the root mean square deviation from the mean energy corresponds to about 33% of the discharge voltage, as in experiments. The influence of the position of the electron emitting source on the ion angular distribution is also shown.

  12. Cure Kinetics of Aqueous Phenol-Formaldehyde Resins Used for Oriented Strandboard Manufacturing

    E-Print Network [OSTI]

    Cure Kinetics of Aqueous Phenol-Formaldehyde Resins Used for Oriented Strandboard Manufacturing the onset cure temperature, and caused separation of the addition and condensation reac- tions involved in curing of CR. Compared with neat CR, the addition reaction of CR/wood mixture also followed an nth

  13. Fabrication and characterization of iron oxide nanoparticles reinforced vinyl-ester resin nanocomposites

    E-Print Network [OSTI]

    Guo, John Zhanhu

    reinforced with iron oxide (Fe2O3) nanoparticles were fabricated. The particle func- tionalization with a bi-functional-stability in the functionalized nanoparticles filled vinyl ester resin nanocomposites as compared to the unmodified nanoparticle acid or base. Furthermore, the functional groups of the polymer surrounding the nano- particles enable

  14. Effects of Glass Fabric and Laminate Construction on the Fatigue of Resin Infused Blade Materials

    E-Print Network [OSTI]

    Effects of Glass Fabric and Laminate Construction on the Fatigue of Resin Infused Blade Materials. Introduction Wind turbine blades experience very high numbers of fatigue cycles varying between tension and wind conditions. The fatigue of composite laminates appropriate for wind turbine blades has been

  15. Effects of petroleum resins on asphaltene aggregation and water-in-oil emulsion formation

    E-Print Network [OSTI]

    Kilpatrick, Peter K.

    Effects of petroleum resins on asphaltene aggregation and water-in-oil emulsion formation P; accepted 30 December 2002 Abstract Asphaltenes from four crude oils were fractionated by precipitation) indicated the onset of asphaltene precipitation occurred at lower toluene volume fractions (0.1Á/0.2) than

  16. Self-assembly of resins and asphaltenes facilitates asphaltene dissolution by an organic acid

    E-Print Network [OSTI]

    Firoozabadi, Abbas

    Self-assembly of resins and asphaltenes facilitates asphaltene dissolution by an organic acid Sara Accepted 28 November 2012 Available online 28 December 2012 Keywords: Asphaltenes Self-assembly Colloidal stability Non-polar electrostatics a b s t r a c t Asphaltene precipitation occurs in petroleum fluids under

  17. Solvent cleaning system and method for removing contaminants from solvent used in resin recycling

    DOE Patents [OSTI]

    Bohnert, George W. (Harrisonville, MO); Hand, Thomas E. (Lee's Summit, MO); DeLaurentiis, Gary M. (Jamestown, CA)

    2009-01-06T23:59:59.000Z

    A two step solvent and carbon dioxide based system that produces essentially contaminant-free synthetic resin material and which further includes a solvent cleaning system for periodically removing the contaminants from the solvent so that the solvent can be reused and the contaminants can be collected and safely discarded in an environmentally safe manner.

  18. Microfabricated ion frequency standard

    SciTech Connect (OSTI)

    Schwindt, Peter (Albuquerque, NM); Biedermann, Grant (Albuquerque, NM); Blain, Matthew G. (Albuquerque, NM); Stick, Daniel L. (Albuquerque, NM); Serkland, Darwin K. (Albuquerque, NM); Olsson, III, Roy H. (Albuquerque, NM)

    2010-12-28T23:59:59.000Z

    A microfabricated ion frequency standard (i.e. an ion clock) is disclosed with a permanently-sealed vacuum package containing a source of ytterbium (Yb) ions and an octupole ion trap. The source of Yb ions is a micro-hotplate which generates Yb atoms which are then ionized by a ultraviolet light-emitting diode or a field-emission electron source. The octupole ion trap, which confines the Yb ions, is formed from suspended electrodes on a number of stacked-up substrates. A microwave source excites a ground-state transition frequency of the Yb ions, with a frequency-doubled vertical-external-cavity laser (VECSEL) then exciting the Yb ions up to an excited state to produce fluorescent light which is used to tune the microwave source to the ground-state transition frequency, with the microwave source providing a precise frequency output for the ion clock.

  19. Primer on nuclear exchange models

    SciTech Connect (OSTI)

    Hafemeister, David [Physics Department, Cal Poly University, San Luis Obispo, California (United States)

    2014-05-09T23:59:59.000Z

    Basic physics is applied to nuclear force exchange models between two nations. Ultimately, this scenario approach can be used to try and answer the age old question of 'how much is enough?' This work is based on Chapter 2 of Physics of Societal Issues: Calculations on National Security, Environment and Energy (Springer, 2007 and 2014)

  20. Ion Coulomb Crystals

    E-Print Network [OSTI]

    Richard C. Thompson

    2014-11-18T23:59:59.000Z

    Ion Coulomb crystals (ICC), formed by atomic ions at low temperatures in radiofrequency and Penning ion traps, are structures that have remarkable properties and many applications. Images of Coulomb crystals are striking and reveal the crystal structure, which arises from a balance between the trapping forces acting on the ions and their mutual Coulomb repulsion. Applications of these structures range from frequency standards and quantum simulation through to measurement of the cross sections of chemical reactions of ions.

  1. Analytic model of the ion angular distribution in a collisional sheath

    SciTech Connect (OSTI)

    Vahedi, V.; Stewart, R.A.; Lieberman, M.A. (Department of Electrical Engineering and Computer Science and the Electronics Research Laboratory, University of California, Berkeley, Berkeley, California 94720 (United States))

    1993-07-01T23:59:59.000Z

    An analytic model is developed for the ion angular distribution in a collisional sheath. In a previous study, the one-dimensional (normal to the sheath) ion velocity distribution was obtained under the assumption that charge exchange is the dominant ion-neutral collision mechanism. In the present model, we assume [lambda][sub scat][ge][lambda][sub cx], where [lambda][sub scat] and [lambda][sub cx] are the mean free paths for ion-neutral elastic scattering and charge-exchange collisions, respectively. With this assumption, the angular distribution mainly arises from ions that strike the electrode after undergoing only one scattering collision following the last charge-exchange collision. Comparison of the analytic model with results obtained from a particle-in-cell simulation gives excellent agreement. Both the average angle of ions striking the electrode and the ratio of parallel to perpendicular ion flux at the electrode are shown to scale with the ratio of scattering to charge-exchange cross sections [sigma][sub scat]/[sigma][sub cx].

  2. Tailoring coercivity of unbiased exchange-coupled ferromagnet/antiferromagnet bilayers

    SciTech Connect (OSTI)

    Sossmeier, K. D.; Schafer, D.; Bastos, A. P. O.; Schmidt, J. E.; Geshev, J. [Instituto de Fisica, Universidade Federal do Rio Grande do Sul (UFRGS), Porto Alegre, 91501-970 Rio Grande do Sul (Brazil)

    2012-07-01T23:59:59.000Z

    This paper reports experimental results obtained on unconventional exchange-coupled ferromagnet/antiferromagnet (FM/AF) system showing zero net bias. The Curie temperature of the FM (NiCu) is lower than the blocking temperature of the AF (IrMn). Samples were either annealed or irradiated with He, Ar, or Ge ions at 40 keV. Due to the exchange coupling at the FM/AF interface, the coercivity (H{sub C}) of the as-deposited FM/AF bilayer is rather higher than that of the corresponding FM single layer. We found that by choosing a proper ion fluence or annealing temperature, it is possible to controllably vary H{sub C}. Ion irradiation of the FM single layer has lead to only a decrease of H{sub C} and annealing or He ion irradiation has not caused important changes at the FM/AF interface; nevertheless, a twofold increase of H{sub C} was obtained after these treatments. Even more significant enhancement of H{sub C} was attained after Ge ion irradiation and attributed to ion-implantation-induced modification of only the FM layer; damages of the FM/AF interface, on the other hand, decrease the coercivity.

  3. Finance Peer Exchange Kickoff Call | Department of Energy

    Energy Savers [EERE]

    Finance Peer Exchange Kickoff Call Finance Peer Exchange Kickoff Call BetterBuildings Financing Peer Exchange Kickoff Call, Call Slides and Discussion Summary, April 28, 2011. Call...

  4. Better Buildings Workforce Peer Exchange Quality Assurance Strategies...

    Energy Savers [EERE]

    Better Buildings Workforce Peer Exchange Quality Assurance Strategies Better Buildings Workforce Peer Exchange Quality Assurance Strategies Better Buildings Workforce Peer Exchange...

  5. Synergistic diffuser/heat-exchanger design

    E-Print Network [OSTI]

    Lazzara, David S. (David Sergio), 1980-

    2004-01-01T23:59:59.000Z

    The theoretical and numerical evaluation of synergistic diffusing heat-exchanger design is presented. Motivation for this development is based on current diffuser and heat-exchange technologies in cogeneration plants, which ...

  6. Heat Exchanger Fouling- Prediction, Measurement and Mitigation 

    E-Print Network [OSTI]

    Peterson, G. R.

    1989-01-01T23:59:59.000Z

    The U. S. Department of Energy (DOE), Office of Industrial Programs (OIP) sponsors the development of innovative heat exchange systems. Fouling is a major and persistent cost associated with most industrial heat exchangers and nationally wastes...

  7. Planning study, resin and debris removal system. Three Mile Island nuclear station unit 2 make-up and purification demineralizers

    SciTech Connect (OSTI)

    Renkey, E.J.; Jenkins, W.W.

    1983-06-01T23:59:59.000Z

    Various methods were evaluated to remove the resin and debris from the makeup and purification demineralizers. There are two preferred concepts. The existing waste disposal system should be utilized if some contamination of currently clean lines is acceptable. A skid mounted, temporary, upflow/downflow system should be utilized if the demineralizers and associated piping are to be cleaned to the maximum extent practicable with minimum contamination of the existing system. Both methods provide for removal of complex organic compounds from the effluent and elution of cesium from the resin. The resin and debris will be diluted with concrete to be disposed of in accordance with 10CFR61 burial limits.

  8. Ab initio investigation of the exchange interactions in Bi$_2$Fe$_4$O$_9$: The Cairo pentagonal lattice compound

    E-Print Network [OSTI]

    Z. V. Pchelkina; S. V. Streltsov

    2013-08-05T23:59:59.000Z

    We present the \\emph{ab initio} calculation of the electronic structure and magnetic properties of Bi$_2$Fe$_4$O$_9$. This compound crystallizes in the orthorhombic crystal structure with the Fe$^{3+}$ ions forming the Cairo pentagonal lattice implying strong geometric frustration. The neutron diffraction measurements reveal nearly orthogonal magnetic configuration, which at first sight is rather unexpected since it does not minimize the total energy of the pair of magnetic ions coupled by the Heisenberg exchange interaction. Here we calculate the electronic structure and exchange integrals of Bi2Fe4O9 within the LSDA+U method. We obtain three different in-plane (J3=36 K, J4=73 K, J5=23 K) and two interplane (J1=10 K, J2=12 K) exchange parameters. The derived set of exchange integrals shows that the realistic description of Bi2Fe4O9 needs a more complicated model than the ideal Cairo pentagonal lattice with only two exchange parameters in the plane. However, if one takes into account only two largest exchange integrals, then according to the ratio x\\equiv J3/J4=0.49<\\sqrt{2} (a critical parameter for the ideal Cairo pentagonal lattice, see. Ref.~1) the ground state should be the orthogonal magnetic configuration in agreement with experiment. The microscopic origin of different exchange interactions is also discussed.

  9. Science Policy Exchange September 21, 2009 Columbia River Estuary Science-Policy Exchange

    E-Print Network [OSTI]

    Science Policy Exchange September 21, 2009 Summary 1 Columbia River Estuary Science-Policy Exchange and Conservation Council hosted a science-policy exchange in Astoria, Oregon. The Council supports strategies Science Advisory Board (ISAB) and the Independent Scientific Review Panel (ISRP) attended the exchange

  10. Broad beam ion implanter

    DOE Patents [OSTI]

    Leung, Ka-Ngo (Hercules, CA)

    1996-01-01T23:59:59.000Z

    An ion implantation device for creating a large diameter, homogeneous, ion beam is described, as well as a method for creating same, wherein the device is characterized by extraction of a diverging ion beam and its conversion by ion beam optics to an essentially parallel ion beam. The device comprises a plasma or ion source, an anode and exit aperture, an extraction electrode, a divergence-limiting electrode and an acceleration electrode, as well as the means for connecting a voltage supply to the electrodes.

  11. On Multiple Gluon Exchange Webs

    E-Print Network [OSTI]

    Mark Harley

    2015-05-21T23:59:59.000Z

    I present an overview of the study of infrared singularities through the eikonal approximation and the concept of webs. Our work reveals the interesting structure of an infinite subclass of webs, Multiple Gluon Exchange Webs. We find that they can be expressed as sums of products of functions depending upon only a single cusp angle, spanned by a simple basis of functions, and conjecture that this structure will hold to all orders.

  12. Predicting the adsorption of second generation biofuels by polymeric resins with applications for in situ product recovery (ISPR)

    E-Print Network [OSTI]

    Nielsen, David R.

    The application of hydrophobic polymeric resins as solid-phase adsorbent materials for the recovery and purification of prospective second generation biofuel compounds, including ethanol, iso-propanol, n-propanol, iso-butanol, ...

  13. Superconducting microfabricated ion traps

    E-Print Network [OSTI]

    Wang, Shannon Xuanyue

    We fabricate superconducting ion traps with niobium and niobium nitride and trap single [superscript 88]Sr ions at cryogenic temperatures. The superconducting transition is verified and characterized by measuring the ...

  14. Vehicle Technologies Office Merit Review 2014: Nanoscale Heterostructures and Thermoplastic Resin Binders: Novel Li-ion Anode Systems

    Broader source: Energy.gov [DOE]

    Presentation given by University of Pittsburgh at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about nanoscale...

  15. OXYGEN 18 EXCHANGE REACTIONS OF ALDEHYDES AND KETONES

    E-Print Network [OSTI]

    Byrn, Marianne; Calvin, Melvin

    1965-01-01T23:59:59.000Z

    OXYGEN 18 EXCHANGE REACTIONS OF ALDEHYDES AND KETONES TWO-eng-48 OXYGEN 18 EXCHANGE REACTIONS OF ALDEHYDES AND KETONES

  16. Single Ion Implantation

    ScienceCinema (OSTI)

    Thomas Schenkel

    2010-01-08T23:59:59.000Z

    On the equipment needed to implant ions in silicon and other materials. More information: http://newscenter.lbl.gov/f...

  17. Single Ion Implantation

    SciTech Connect (OSTI)

    Thomas Schenkel

    2008-10-21T23:59:59.000Z

    On the equipment needed to implant ions in silicon and other materials. More information: http://newscenter.lbl.gov/f...

  18. Lithium Ion Production NDE

    E-Print Network [OSTI]

    Lithium Ion Electrode Production NDE and QC Considerations David Wood, Debasish Mohanty, Jianlin Li, and Claus Daniel 12/9/13 EERE Quality Control Workshop #12;2 Presentation name Lithium Ion Electrode to be meaningful and provide electrode and cell QC. #12;3 Presentation name New Directions in Lithium Ion Electrode

  19. Lithium ion sources

    E-Print Network [OSTI]

    Roy, Prabir K.

    2014-01-01T23:59:59.000Z

    HIFAN 1866 Lithium ion sources by Prabir K. Roy, Wayne G.No. DE-AC02-05CH11231. Lithium ion sources Prabir K. RoyUSA Abstract A 10.9 cm diameter lithium alumino-silicate ion

  20. Evaluation of bisphenol E cyanate ester for the resin-injection repair of advanced composites

    SciTech Connect (OSTI)

    Wilber Yaote Lio

    2009-12-19T23:59:59.000Z

    This thesis is a compilation of a general introduction and literature review that ties together the subsequent chapters which consist of two journal articles that have yet to be submitted for publication. The overall topic relates to the evaluation and application of a new class of cyanate ester resin with unique properties that lend it applicable to use as a resin for injection repair of high glass transition temperature polymer matrix composites. The first article (Chapter 2) details the evaluation and optimization of adhesive properties of this cyanate ester and alumina nanocomposites under different conditions. The second article (Chapter 3) describes the development and evaluation of an injection repair system for repairing delaminations in polymer matrix composites.

  1. Resin-assisted Enrichment of N-terminal Peptides for Characterizing Proteolytic Processing

    SciTech Connect (OSTI)

    Kim, Jong Seo; Dai, Ziyu; Aryal, Uma K.; Moore, Ronald J.; Camp, David G.; Baker, Scott E.; Smith, Richard D.; Qian, Weijun

    2013-06-17T23:59:59.000Z

    Proteolytic processing is a ubiquitous, irreversible posttranslational modification that plays an important role in cellular regulation in all living organisms. Herein we report a resin-assisted positive selection method for specifically enriching protein N-terminal peptides to facilitate the characterization of proteolytic processing events by liquid chromatography-tandem mass spectrometry. In this approach, proteins are initially reduced and alkylated and their lysine residues are converted to homoarginines. Then, protein N-termini are selectively converted to reactive thiol groups. We demonstrate that these sequential reactions were achieved with nearly quantitative efficiencies. Thiol-containing N-terminal peptides are then captured (>98% efficiency) by a thiol-affinity resin, a significant improvement over the traditional avidin/biotin enrichment. Application to cell lysates of Aspergillus niger, a filamentous fungus of interest for biomass degradation, enabled the identification of 1672 unique protein N-termini and proteolytic cleavage sites from 690 unique proteins.

  2. Investigation of gamma induced degradation of Amberlite 200 cation resin by mass spectrometer and liquid chromatograph

    E-Print Network [OSTI]

    Freitag, Albert Antonio

    1977-01-01T23:59:59.000Z

    of the requirement for the degree of MASTER OF SCIENCE December 1977 Major Subject: Nuclear Engineering INVESTIGATION OI' GAMMA INDUCED DEGRADATION OF AMBERLITE 200 CATION RESIN BY MASS SPECTROMETER AND LIQUID CHROMATOGRAPH A Thesis by ALBERT ANTONIO FREITAG... and to Dr. Robert G. Cochran, Head of the Nuclear Engineering Department, for providing the financial support necessary for completion of this work. DEDICATION I dedicate this work to my wife, Diann, for her tolerance and support. Vi TADLE OF CONTL...

  3. The effect of molecular architecture on the mechanical properties of epoxy resin systems

    E-Print Network [OSTI]

    Holmes, Gale Antrus

    1992-01-01T23:59:59.000Z

    -modified epoxy arose from an , increase in energy-dissipating deformations occurring in the material near the crack tip. He proposed that the primary deformation processes resulted from (1) localized cavitation 23 in the rubber or at the particle and matrix... and capable of yielding before the rubbery particles can cavitate then bridging of the crack face by these particles may result. If this "salami" morphology is indeed similar to HIPS and contains embedded tight crosslinked resin this may explain...

  4. Measurement of spin diffusion length in sputtered Ni films using a special exchange-biased spin valve geometry

    E-Print Network [OSTI]

    Birge, Norman

    valve geometry Charles E. Moreaua Department of Physics, Albion College, Albion, Michigan 49224 Ion C exchange-biased spin valve geometry that inserts a Ni "spoiler" layer into a Py/Cu/Py spin valve. Fits In the context of ferromagnetic/nonmagnetic F/N multilayers or spin valves, the size of the giant

  5. J. CHEM. SOC. FARADAY TRANS., 1991, 87(15), 2501-2506 2501 Ca-K-H Exchange on Silt-, Clay-and Silt +Clay-size Soil Separates

    E-Print Network [OSTI]

    Sparks, Donald L.

    J. CHEM. SOC. FARADAY TRANS., 1991, 87(15), 2501-2506 2501 Ca-K-H Exchange on Silt-, Clay- and Silt +Clay-size Soil Separates Steven A. Grant*t and Donald L. Sparks Department of Plant and Soil Sciences and kaolinite clays. To predict accurately chemical equilibria of a natural ion- exchanger, one is forced

  6. Testing and analysis of immersed heat exchangers

    SciTech Connect (OSTI)

    Farrington, R.B.; Bingham, C.E.

    1986-08-01T23:59:59.000Z

    The objectives were to determine the performance of four immersed, ''supply-side'' heat exchangers used in solar domestic-hot-water systems; to examine the effects of flow rate, temperature difference, and coil configuration on performance; and to develop a simple model to predict the performance of immersed heat exchangers. We tested four immersed heat exchangers: a smooth coil, a finned spiral, a single-wall bayonet, and a double-wall bayonet. We developed two analyticl models and a simple finite difference model. We experimentally verified that the performance of these heat exchangers depends on the flow rate through them; we also showed that the temperature difference between the heat exchanger's inlet and the storage tank can strongly affect a heat exchanger's performance. We also compared the effects of the heat exchanger's configuration and correlated Nusselt and Rayleigh numbers for each heat exchanger tested. The smooth coil had a higher effectiveness than the others, while the double-wall bayonet had a very low effectiveness. We still do not know the long-term effectiveness of heat exchangers regarding scale accumulation, nor do we know the effects of very low flow rates on a heat exchanger's performance.

  7. Superconducting microfabricated ion traps

    E-Print Network [OSTI]

    Shannon X. Wang; Yufei Ge; Jaroslaw Labaziewicz; Eric Dauler; Karl Berggren; Isaac L. Chuang

    2010-12-14T23:59:59.000Z

    We fabricate superconducting ion traps with niobium and niobium nitride and trap single 88Sr ions at cryogenic temperatures. The superconducting transition is verified and characterized by measuring the resistance and critical current using a 4-wire measurement on the trap structure, and observing change in the rf reflection. The lowest observed heating rate is 2.1(3) quanta/sec at 800 kHz at 6 K and shows no significant change across the superconducting transition, suggesting that anomalous heating is primarily caused by noise sources on the surface. This demonstration of superconducting ion traps opens up possibilities for integrating trapped ions and molecular ions with superconducting devices.

  8. Sandia Energy - Heat Exchanger Development

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of Scienceand RequirementsCoatingsUltra-High-Voltage SiliconEnergyFailureGlobalHeat Exchanger

  9. Ion cyclotron resonance cell

    DOE Patents [OSTI]

    Weller, R.R.

    1995-02-14T23:59:59.000Z

    An ion cyclotron resonance cell is disclosed having two adjacent sections separated by a center trapping plate. The first section is defined by the center trapping plate, a first end trapping plate, and excitation and detector electrodes. The second section includes a second end trapping plate spaced apart from the center plate, a mirror, and an analyzer. The analyzer includes a wavelength-selective light detector, such as a detector incorporating an acousto-optical device (AOD) and a photodetector. One or more ion guides, grounded plates with holes for the ion beam, are positioned within the vacuum chamber of the mass spectrometer between the ion source and the cell. After ions are trapped and analyzed by ion cyclotron resonance techniques in the first section, the ions of interest are selected according to their mass and passed into the second section for optical spectroscopic studies. The trapped ions are excited by light from a laser and caused thereby to fluoresce. The fluorescent light emitted by the excited ions is reflected by the mirror and directed onto the detector. The AOD is scanned, and the photodetector output is recorded and analyzed. The ions remain in the second section for an extended period, enabling multiple studies to be carried out on the same ensemble of ions. 5 figs.

  10. Ion cyclotron resonance cell

    DOE Patents [OSTI]

    Weller, Robert R. (Aiken, SC)

    1995-01-01T23:59:59.000Z

    An ion cyclotron resonance cell having two adjacent sections separated by a center trapping plate. The first section is defined by the center trapping plate, a first end trapping plate, and excitation and detector electrodes. The second section includes a second end trapping plate spaced apart from the center plate, a mirror, and an analyzer. The analyzer includes a wavelength-selective light detector, such as a detector incorporating an acousto-optical device (AOD) and a photodetector. One or more ion guides, grounded plates with holes for the ion beam, are positioned within the vacuum chamber of the mass spectrometer between the ion source and the cell. After ions are trapped and analyzed by ion cyclotron resonance techniques in the first section, the ions of interest are selected according to their mass and passed into the second section for optical spectroscopic studies. The trapped ions are excited by light from a laser and caused thereby to fluoresce. The fluorescent light emitted by the excited ions is reflected by the mirror and directed onto the detector. The AOD is scanned, and the photodetector output is recorded and analyzed. The ions remain in the second section for an extended period, enabling multiple studies to be carried out on the same ensemble of ions.

  11. Microfabricated ion trap array

    DOE Patents [OSTI]

    Blain, Matthew G. (Albuquerque, NM); Fleming, James G. (Albuquerque, NM)

    2006-12-26T23:59:59.000Z

    A microfabricated ion trap array, comprising a plurality of ion traps having an inner radius of order one micron, can be fabricated using surface micromachining techniques and materials known to the integrated circuits manufacturing and microelectromechanical systems industries. Micromachining methods enable batch fabrication, reduced manufacturing costs, dimensional and positional precision, and monolithic integration of massive arrays of ion traps with microscale ion generation and detection devices. Massive arraying enables the microscale ion traps to retain the resolution, sensitivity, and mass range advantages necessary for high chemical selectivity. The reduced electrode voltage enables integration of the microfabricated ion trap array with on-chip circuit-based rf operation and detection electronics (i.e., cell phone electronics). Therefore, the full performance advantages of the microfabricated ion trap array can be realized in truly field portable, handheld microanalysis systems.

  12. ION-BY-ION COOLING EFFICIENCIES

    SciTech Connect (OSTI)

    Gnat, Orly [Theoretical Astrophysics, California Institute of Technology, MC 350-17, Pasadena, CA 91125 (United States) and Racah Institute of Physics, Hebrew University, 91904 Jerusalem (Israel); Ferland, Gary J., E-mail: orlyg@tapir.caltech.edu [Department of Physics and Astronomy, University of Kentucky, Lexington, KY 40506 (United States)

    2012-03-01T23:59:59.000Z

    We present ion-by-ion cooling efficiencies for low-density gas. We use Cloudy (version 10.00) to estimate the cooling efficiencies for each ion of the first 30 elements (H-Zn) individually. We present results for gas temperatures between 10{sup 4} and 10{sup 8} K, assuming low densities and optically thin conditions. When nonequilibrium ionization plays a significant role the ionization states deviate from those that obtain in collisional ionization equilibrium (CIE), and the local cooling efficiency at any given temperature depends on specific nonequilibrium ion fractions. The results presented here allow for an efficient estimate of the total cooling efficiency for any ionic composition. We also list the elemental cooling efficiencies assuming CIE conditions. These can be used to construct CIE cooling efficiencies for non-solar abundance ratios or to estimate the cooling due to elements not included in any nonequilibrium computation. All the computational results are listed in convenient online tables.

  13. Most spin-1/2 transition-metal ions do have single ion anisotropy

    SciTech Connect (OSTI)

    Liu, Jia; Whangbo, Myung-Hwan, E-mail: hxiang@fudan.edu.cn, E-mail: mike-whangbo@ncsu.edu [Department of Chemistry, North Carolina State University, Raleigh, North Carolina 27695 (United States); Koo, Hyun-Joo [Department of Chemistry and Research Institute for Basic Sciences, Kyung Hee University, Seoul 130-701 (Korea, Republic of); Xiang, Hongjun, E-mail: hxiang@fudan.edu.cn, E-mail: mike-whangbo@ncsu.edu [Key Laboratory of Computational Physical Sciences (Ministry of Education), State Key Laboratory of Surface Physics, and Department of Physics, Fudan University, Shanghai 200433 (China); Kremer, Reinhard K. [Max-Planck-Institut für Festkörperforschung, Heisenbergstrasse 1, D-70569 Stuttgart (Germany)

    2014-09-28T23:59:59.000Z

    The cause for the preferred spin orientation in magnetic systems containing spin-1/2 transition-metal ions was explored by studying the origin of the easy-plane anisotropy of the spin-1/2 Cu{sup 2+} ions in CuCl{sub 2}·2H{sub 2}O, LiCuVO{sub 4}, CuCl{sub 2}, and CuBr{sub 2} on the basis of density functional theory and magnetic dipole-dipole energy calculations as well as a perturbation theory treatment of the spin-orbit coupling. We find that the spin orientation observed for these spin-1/2 ions is not caused by their anisotropic spin exchange interactions, nor by their magnetic dipole-dipole interactions, but by the spin-orbit coupling associated with their crystal-field split d-states. Our study also predicts in-plane anisotropy for the Cu{sup 2+} ions of Bi{sub 2}CuO{sub 4} and Li{sub 2}CuO{sub 2}. The results of our investigations dispel the mistaken belief that magnetic systems with spin-1/2 ions have no magnetic anisotropy induced by spin-orbit coupling.

  14. DHE (downhole heat exchangers). [Downhole Heat Exchangers (DHE)

    SciTech Connect (OSTI)

    Culver, G.

    1990-11-01T23:59:59.000Z

    The use of downhole heat exchangers (DHE) for residential or commercial space and domestic water heating and other applications has several desirable features. Systems are nearly or completely passive -- that is, no or very little geothermal water or steam is produced from the well either reducing or completely eliminating surface environmental concerns and the need for disposal systems or injection wells. Initial cost of pumps and installation are eliminated or reduced along with pumping power costs and maintenance costs associated with pumping often corrosive geothermal fluids. Many residential and small commercial systems do not require circulating pumps because the density difference in the incoming and outgoing sides of the loop are sufficient to overcome circulating friction losses in the entire system. The major disadvantage of DHEs is their dependence on natural heat flow. In areas where geological conditions provide high permeability and a natural hydraulic gradient, DHEs can provide a substantial quantity of heat. A single 500-ft (152 m) well in Klamath Falls, Oregon, supplies over one megawatt thermal and output is apparently limited by the surface area of pipe that can be installed in the well bore. In contrast, DHEs used in conjunction with heat pumps may supply less than 8 KW from a well of similar depth. Here output is limited by conductive heat flow with perhaps a small contribution from convection near the well bore. The highest capacity DHE reported to date, in Turkey, supplies 6 MW thermal from an 820-ft (250 m) well. There were two main goals for this project. The first was to gather, disseminate and exchange internationally information on DHES. The second was to perform experiments that would provide insight into well bore/aquifer interaction and thereby provide more information on which to base DHE designs. 27 refs., 31 figs., 3 tabs.

  15. THERMOSIPHON WATER HEATERS WITH HEAT EXCHANGERS

    E-Print Network [OSTI]

    Mertol, Atila

    2012-01-01T23:59:59.000Z

    The Performance of Solar Water Heater With Natural Ci rcul2-6, 1980 THERMOSIPHON WATER HEATERS WITH HEAT EXCHANGERSJune 1980 THERMOSIPHON WATER HEATERS WITH HEAT EXCHANGERS*

  16. Manufacturing serendipity: Chicago Innovation Exchange enhancing...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Social Media Photos Videos Fact Sheets, Brochures and Reports Summer Science Writing Internship John Flavin, Executive Director of the Chicago Innovation Exchange, started a small...

  17. Sandia National Laboratories: information exchange on performance...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    exchange on performance indicators Sandia Contributes to International Electrotechnical Commission IEC 61400-26 Availability Standard On June 12, 2014, in Analysis, Distribution...

  18. NETL's Energy Data eXchange

    SciTech Connect (OSTI)

    None

    2014-07-16T23:59:59.000Z

    A brief tour around NETL's Energy Data Exchange site, where researchers can upload data or look at data from another researcher.

  19. NETL's Energy Data eXchange

    ScienceCinema (OSTI)

    None

    2014-07-22T23:59:59.000Z

    A brief tour around NETL's Energy Data Exchange site, where researchers can upload data or look at data from another researcher.

  20. Efficiency Exchange Conference Highlights Energy Efficiency Innovation...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Efficiency Exchange Conference Highlights Energy Efficiency Innovations and Trends Northwest electric power industry connects on the latest energy efficiency programs and...

  1. Energy Efficiency Exchange 2015 | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Energy Efficiency Exchange 2015 August 11-13, 2015, Phoenix Convention Center As the nation's largest energy consumer, the federal government has a tremendous opportunity and clear...

  2. Low-Cost Microchannel Heat Exchanger

    Energy Savers [EERE]

    process Produce prototype heat exchangers for electronics cooling and high pressure waste heat recovery power system applications Test integrity and confirm high...

  3. Efficiency Exchange highlights energy efficiency innovations...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Efficiency Exchange highlights energy efficiency innovations and trends Northwest electric power industry connects on the latest energy efficiency programs and strategies Portland,...

  4. A Lightweight Material for Heat Exchange Applications

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    exchangers have been manufactured from metal because metals are effective in conducting thermal energy. Plastics, although cheaper, lighter, and less energy intensive to make...

  5. Damage Profile and Ion Distribution of Slow Heavy Ions in Compounds...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Profile and Ion Distribution of Slow Heavy Ions in Compounds. Damage Profile and Ion Distribution of Slow Heavy Ions in Compounds. Abstract: Slow heavy ions inevitably produce a...

  6. Combustion of calcium-exchanged coal. First quarterly report

    SciTech Connect (OSTI)

    Gavalas, G.R.; Flagan, R.C.

    1984-02-10T23:59:59.000Z

    The work performed during this first period includes equipment modification, development of analytical methods, oxidative pretreatment runs and combustion runs. The coal feeding section of an existing furnace was modified for uninterrupted feeding and better control of residence time. Analytical methods for sulfur and calcium in the coal and ash and for gaseous SO/sub 2/ were standardized. Oxidative pretreatment experiments were conducted in a fluidized bed at temperatures about 200/sup 0/C to evaluate the potential of this method for increasing the ion exchange capacity of coals and determine the accompanying loss of heating value. Combustion experiments were carried out at very high particle temperatures (2000/sup 0/K) at which a large fraction of the calcium additive was vaporized while 50 to 80% of the sulfur evolved as sulfur oxide. Continuing combustion experiments will be conducted at lower particle temperatures.

  7. Multiphase transport model for heavy ion collisions at RHIC

    E-Print Network [OSTI]

    Zi-wei Lin; Subrata Pal; C. M. Ko; Bao-An Li; Bin Zhang

    2001-05-18T23:59:59.000Z

    Using a multiphase transport model (AMPT) with both partonic and hadronic interactions, we study the multiplicity and transverse momentum distributions of charged particles such as pions, kaons and protons in central Au+Au collisions at RHIC energies. Effects due to nuclear shadowing and jet quenching on these observables are also studied. We further show preliminary results on the production of multistrange baryons from the strangeness-exchange reactions during the hadronic stage of heavy ion collisions.

  8. Ion beam generating apparatus

    DOE Patents [OSTI]

    Brown, Ian G. (1088 Woodside Rd., Berkeley, CA 94708); Galvin, James (2 Commodore #276, Emeryville, CA 94608)

    1987-01-01T23:59:59.000Z

    An ion generating apparatus utilizing a vacuum chamber, a cathode and an anode in the chamber. A source of electrical power produces an arc or discharge between the cathode and anode. The arc is sufficient to vaporize a portion of the cathode to form a plasma. The plasma is directed to an extractor which separates the electrons from the plasma, and accelerates the ions to produce an ion beam.

  9. Ion beam generating apparatus

    DOE Patents [OSTI]

    Brown, I.G.; Galvin, J.

    1987-12-22T23:59:59.000Z

    An ion generating apparatus utilizing a vacuum chamber, a cathode and an anode in the chamber. A source of electrical power produces an arc or discharge between the cathode and anode. The arc is sufficient to vaporize a portion of the cathode to form a plasma. The plasma is directed to an extractor which separates the electrons from the plasma, and accelerates the ions to produce an ion beam. 10 figs.

  10. Collection of ions

    DOE Patents [OSTI]

    Orr, Christopher Henry (Calderbridge, GB); Luff, Craig Janson (Calderbridge, GB); Dockray, Thomas (Calderbridge, GB); Macarthur, Duncan Whittemore (Los Alamos, NM); Bounds, John Alan (Los Alamos, NM); Koster, James E. (Los Alamos, NM)

    2001-01-01T23:59:59.000Z

    The apparatus and method provide an improved technique for detecting ions as the area from which ions are attracted to a detector is increased, consequently increasing the number of ions detected. This is achieved by providing the outer electrodes of the detector connected to the electrical potential, together with alternate intermediate electrodes. The other intermediate electrodes and preferably the housing are grounded. The technique renders such detection techniques more sensitive and gives them a lower threshold at which they can function.

  11. Correlation ion mobility spectroscopy

    DOE Patents [OSTI]

    Pfeifer, Kent B. (Los Lunas, NM); Rohde, Steven B. (Corrales, NM)

    2008-08-26T23:59:59.000Z

    Correlation ion mobility spectrometry (CIMS) uses gating modulation and correlation signal processing to improve IMS instrument performance. Closely spaced ion peaks can be resolved by adding discriminating codes to the gate and matched filtering for the received ion current signal, thereby improving sensitivity and resolution of an ion mobility spectrometer. CIMS can be used to improve the signal-to-noise ratio even for transient chemical samples. CIMS is especially advantageous for small geometry IMS drift tubes that can otherwise have poor resolution due to their small size.

  12. Controlled catalytic and thermal sequential pyrolysis and hydrolysis of phenolic resin containing waste streams to sequentially recover monomers and chemicals

    DOE Patents [OSTI]

    Chum, Helena L. (Arvada, CO); Evans, Robert J. (Lakewood, CO)

    1992-01-01T23:59:59.000Z

    A process of using fast pyrolysis in a carrier gas to convert a waste phenolic resin containing feedstreams in a manner such that pyrolysis of said resins and a given high value monomeric constituent occurs prior to pyrolyses of the resins in other monomeric components therein comprising: selecting a first temperature program range to cause pyrolysis of said resin and a given high value monomeric constituent prior to a temperature range that causes pyrolysis of other monomeric components; selecting, if desired, a catalyst and a support and treating said feedstreams with said catalyst to effect acid or basic catalyzed reaction pathways to maximize yield or enhance separation of said high value monomeric constituent in said first temperature program range to utilize reactive gases such as oxygen and steam in the pyrolysis process to drive the production of specific products; differentially heating said feedstreams at a heat rate within the first temperature program range to provide differential pyrolysis for selective recovery of optimum quantity of said high value monomeric constituent prior to pyrolysis of other monomeric components therein; separating said high value monomeric constituent; selecting a second higher temperature program range to cause pyrolysis of a different high value monomeric constituent of said phenolic resins waste and differentially heating said feedstreams at said higher temperature program range to cause pyrolysis of said different high value monomeric constituent; and separating said different high value monomeric constituent.

  13. Controlled catalytic and thermal sequential pyrolysis and hydrolysis of phenolic resin containing waste streams to sequentially recover monomers and chemicals

    DOE Patents [OSTI]

    Chum, H.L.; Evans, R.J.

    1992-08-04T23:59:59.000Z

    A process is described for using fast pyrolysis in a carrier gas to convert a waste phenolic resin containing feedstreams in a manner such that pyrolysis of said resins and a given high value monomeric constituent occurs prior to pyrolyses of the resins in other monomeric components therein comprising: selecting a first temperature program range to cause pyrolysis of said resin and a given high value monomeric constituent prior to a temperature range that causes pyrolysis of other monomeric components; selecting, if desired, a catalyst and a support and treating said feedstreams with said catalyst to effect acid or basic catalyzed reaction pathways to maximize yield or enhance separation of said high value monomeric constituent in said first temperature program range to utilize reactive gases such as oxygen and steam in the pyrolysis process to drive the production of specific products; differentially heating said feedstreams at a heat rate within the first temperature program range to provide differential pyrolysis for selective recovery of optimum quantity of said high value monomeric constituent prior to pyrolysis of other monomeric components therein; separating said high value monomeric constituent; selecting a second higher temperature program range to cause pyrolysis of a different high value monomeric constituent of said phenolic resins waste and differentially heating said feedstreams at said higher temperature program range to cause pyrolysis of said different high value monomeric constituent; and separating said different high value monomeric constituent. 11 figs.

  14. WAGES, FLEXIBLE EXCHANGE RATES, AND MACROECONOMIC POLICY*

    E-Print Network [OSTI]

    WAGES, FLEXIBLE EXCHANGE RATES, AND MACROECONOMIC POLICY* JEFFREY SACHS In an open economy with a floaLing exchange rate, the efficacy of fiscal and monetary policy depends fundamentally on the wage rate depreciation, while fiscal expansion has no output effect. These results hold only when real wages

  15. Configure Outlook 2010 with Exchange Server

    E-Print Network [OSTI]

    Qiu, Weigang

    Configure Outlook 2010 with Exchange Server #12;1. Navigate to the Windows Start Menu (or press. #12;14. E-mail server settings will now auto configure. 15. Once the Auto Account Setup is configured server settings or additional server types. 3. Click the Next > button. #12;4. Select Microsoft Exchange

  16. Business Time in the Foreign Exchange Markets

    E-Print Network [OSTI]

    Edinburgh, University of

    Business Time in the Foreign Exchange Markets Mark J L Orr Centre for Cognitive Science Edinburgh University June 1997 #12; Business Time in the Foreign Exchange Markets Mark J L Orr y Centre for Cognitive; Contents 1 Introduction 4 2 The Price Change Scaling Law 5 3 Business Time 7 4 The BZW Data 11 5 Volatility

  17. Plasma ion sources and ion beam technology in microfabrications

    E-Print Network [OSTI]

    Ji, Lili

    2007-01-01T23:59:59.000Z

    in the right chamber (ion chamber) are confined in their ownwatts and that on the ion chamber is 50 watts. A permanent-column and the ion source chamber. The simulation is

  18. New technology in condensate polishing

    SciTech Connect (OSTI)

    Kunin, R.; Salem, E.; Libutti, B. (Graver Co., Union, NJ (United States). Water Div.)

    1992-08-01T23:59:59.000Z

    Sulfonic acid ion exchange resins. when carried into a boiler or steam generator, thermally decompose releasing large amounts of corrosive, sulfates. Replacement of the sulfonic acid resin with a carboxylic acid resin would eliminate this source of contamination. The sulfonic acid resin is a strong acid: the carboxylic acid resin is a weak acid. The carboxylic acid resin alone is not capable of splitting salts which limits its use to mixed resin beds or to its use in single or individual beds with feeds of high alkalinity or high pH values. Laboratory, pilot plant and full scale plant tests compared the two resins in precoat filters. When the resins in mixed beds were in the acid form, the weakly acid resin was almost as effective in removing sodium ion as the strongly acid resin. In the ammonium form. the weakly acid resin was generally more effective in removing sodium than the strongly acid resin. Condensate polishing reduced the sodium ion to a few parts per billion (ppB). Complete resin separation before regeneration is more important for the weakly acid resin than for the strongly acid resin. Another development found that the hydrazine reaction with oxygen could be catalyzed by powdered activated carbon combined with microfibers on a Powdex substrate. The carbon should be thoroughly washed to reduce its residual sodium content. In plant tests, the carbon reduced the oxygen concentration in condensate about 50% during startup. In preliminary tests believed to be typical, carbon lowered the oxygen concentration below 10 ppB in about 6 hours compared to 18 hours without the carbon. Oxygen is also reduced during normal operation.

  19. Process for strontium-82 separation

    DOE Patents [OSTI]

    Heaton, R.C.; Jamriska, D.J. Sr.; Taylor, W.A.

    1992-12-01T23:59:59.000Z

    A process for selective separation of strontium-82 and strontium-85 from proton irradiated molybdenum targets comprises dissolving the molybdenum target in a hydrogen peroxide solution to form a first solution containing ions selected from a group consisting of molybdenum, niobium, technetium, selenium, vanadium, arsenic, germanium, zirconium, rubidium, zinc, beryllium, cobalt, iron, manganese, chromium, strontium, and yttrium; passing the solution through a first cationic resin whereby ions selected from a group consisting of zinc, beryllium, cobalt, iron, manganese, chromium, strontium, yttrium a portion of zirconium and a portion of rubidium are selectively absorbed by the first resin; contacting the first resin with an acid solution to strip and remove the absorbed ions from the first cationic exchange resin to form a second solution; evaporating the second solution for a time sufficient to remove substantially all of the acid and water from the solution whereby a residue remains; dissolving the residue in a dilute acid to form a third solution; passing the third solution through a second cationic resin whereby the ions are absorbed by the second resin; contacting the second resin with a dilute sulfuric acid solution whereby the absorbed ions selected from the group consisting of rubidium, zinc, beryllium, cobalt, iron, manganese, chromium and zirconium are selectively removed from the second resin; and contacting the second resin with a dilute acid solution whereby the absorbed strontium ions are selectively removed. 1 fig.

  20. Process for strontium-82 separation

    DOE Patents [OSTI]

    Heaton, Richard C. (Los Alamos, NM); Jamriska, Sr., David J. (Los Alamos, NM); Taylor, Wayne A. (Los Alamos, NM)

    1992-01-01T23:59:59.000Z

    A process for selective separation of strontium-82 and strontium-85 from proton irradiated molybdenum targets comprises dissolving the molybdenum target in a hydrogen peroxide solution to form a first solution containing ions selected from a group consisting of molybdenum, niobium, technetium, selenium, vanadium, arsenic, germanium, zirconium, rubidium, zinc, beryllium, cobalt, iron, manganese, chromium, strontium, and yttrium; passing the solution through a first cationic resin whereby ions selected from a group consisting of zinc, beryllium, cobalt, iron, manganese, chromium, strontium, yttrium a portion of zirconium and a portion of rubidium are selectively absorbed by the first resin; contacting the first resin with an acid solution to strip and remove the absorbed ions from the first cationic exchange resin to form a second solution; evaporating the second solution for a time sufficient to remove substantially all of the acid and water from the solution whereby a residue remains; dissolving the residue in a dilute acid to form a third solution; passing the third solution through a second cationic resin whereby the ions are absorbed by the second resin; contacting the second resin with a dilute sulfuric acid solution whereby the absorbed ions selected from the group consisting of rubidium, zinc, beryllium, cobalt, iron, manganese, chromium and zirconium are selectively removed from the second resin; and contacting the second resin with a dilute acid solution whereby the absorbed strontium ions are selectively removed.

  1. Standard Test Method for Resin Flow of Carbon Fiber-Epoxy Prepreg

    E-Print Network [OSTI]

    American Society for Testing and Materials. Philadelphia

    1999-01-01T23:59:59.000Z

    1.1 This test method covers the determination of the amount of resin flow that will take place from prepreg tape or sheet under given conditions of temperature and pressure. 1.2 The values stated in SI units are to be regarded as standard. The values in parentheses are for reference only. 1.3 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

  2. Oxidation reactions of solid carbonaceous and resinous substances in supercritical water

    SciTech Connect (OSTI)

    Koda, S. [Sophia University, Tokyo (Japan). Dept. of Material and Life Science

    2009-01-15T23:59:59.000Z

    Recent kinetic studies, particularly those by means of shadowgraphy and X-ray radiography, for supercritical water oxidation of solid carbonaceous and resinous substances have revealed the importance of the O{sub 2} mass transfer process over the intrinsic surface reaction at higher temperatures. The mass transfer processes, internal and external one, should be incorporated in designing SCWO processes for solid substances and related processes such as catalytic SCWO. Some model calculation efforts of late are briefly described. Finally, fundamental information required for future development is itemed.

  3. Microfabricated cylindrical ion trap

    DOE Patents [OSTI]

    Blain, Matthew G.

    2005-03-22T23:59:59.000Z

    A microscale cylindrical ion trap, having an inner radius of order one micron, can be fabricated using surface micromachining techniques and materials known to the integrated circuits manufacturing and microelectromechanical systems industries. Micromachining methods enable batch fabrication, reduced manufacturing costs, dimensional and positional precision, and monolithic integration of massive arrays of ion traps with microscale ion generation and detection devices. Massive arraying enables the microscale cylindrical ion trap to retain the resolution, sensitivity, and mass range advantages necessary for high chemical selectivity. The microscale CIT has a reduced ion mean free path, allowing operation at higher pressures with less expensive and less bulky vacuum pumping system, and with lower battery power than conventional- and miniature-sized ion traps. The reduced electrode voltage enables integration of the microscale cylindrical ion trap with on-chip integrated circuit-based rf operation and detection electronics (i.e., cell phone electronics). Therefore, the full performance advantages of microscale cylindrical ion traps can be realized in truly field portable, handheld microanalysis systems.

  4. Selective ion source

    DOE Patents [OSTI]

    Leung, K.N.

    1996-05-14T23:59:59.000Z

    A ion source is described wherein selected ions maybe extracted to the exclusion of unwanted ion species of higher ionization potential. Also described is a method of producing selected ions from a compound, such as P{sup +} from PH{sub 3}. The invention comprises a plasma chamber, an electron source, a means for introducing a gas to be ionized by electrons from the electron source, means for limiting electron energy from the electron source to a value between the ionization energy of the selected ion species and the greater ionization energy of an unwanted ion specie, and means for extracting the target ion specie from the plasma chamber. In one embodiment, the electrons are generated in a plasma cathode chamber immediately adjacent to the plasma chamber. A small extractor draws the electrons from the plasma cathode chamber into the relatively positive plasma chamber. The energy of the electrons extracted in this manner is easily controlled. The invention is particularly useful for doping silicon with P{sup +}, As{sup +}, and B{sup +} without the problematic presence of hydrogen, helium, water, or carbon oxide ions. Doped silicon is important for manufacture of semiconductors and semiconductor devices. 6 figs.

  5. Selective ion source

    DOE Patents [OSTI]

    Leung, Ka-Ngo (Hercules, CA)

    1996-01-01T23:59:59.000Z

    A ion source is described wherein selected ions maybe extracted to the exclusion of unwanted ion species of higher ionization potential. Also described is a method of producing selected ions from a compound, such as P.sup.+ from PH.sub.3. The invention comprises a plasma chamber, an electron source, a means for introducing a gas to be ionized by electrons from the electron source, means for limiting electron energy from the electron source to a value between the ionization energy of the selected ion species and the greater ionization energy of an unwanted ion specie, and means for extracting the target ion specie from the plasma chamber. In one embodiment, the electrons are generated in a plasma cathode chamber immediately adjacent to the plasma chamber. A small extractor draws the electrons from the plasma cathode chamber into the relatively positive plasma chamber. The energy of the electrons extracted in this manner is easily controlled. The invention is particularly useful for doping silicon with P.sup.+, AS.sup.+, and B.sup.+ without the problematic presence of hydrogen, helium, water, or carbon oxide ions. Doped silicon is important for manufacture of semiconductors and semiconductor devices.

  6. Relativistic heavy ion research

    SciTech Connect (OSTI)

    Nagamiya, Shoji.

    1992-01-01T23:59:59.000Z

    This report discusses the following topics: antiproton production; Bose-Einstein correlations; high-transverse momentum spectra; strangeness enhancement in heavy ion collisions; search for rare negative secondaries of antiprotons and antinuclei produced in heavy ion collisions; quark matter; and time-of-flight systems test at Brookhaven AGS. (LSP).

  7. Ion-beam technologies

    SciTech Connect (OSTI)

    Fenske, G.R. [Argonne National Lab., IL (United States)

    1993-01-01T23:59:59.000Z

    This compilation of figures and diagrams reviews processes for depositing diamond/diamond-like carbon films. Processes addressed are chemical vapor deposition (HFCVD, PACVD, etc.), plasma vapor deposition (plasma sputtering, ion beam sputtering, evaporation, etc.), low-energy ion implantation, and hybrid processes (biased sputtering, IBAD, biased HFCVD, etc.). The tribological performance of coatings produced by different means is discussed.

  8. Tailored benzoxazines as novel resin systems for printed circuit boards in high temperature e-mobility applications

    SciTech Connect (OSTI)

    Troeger, K., E-mail: altstaedt@uni-bayreuth.de; Darka, R. Khanpour, E-mail: altstaedt@uni-bayreuth.de; Neumeyer, T., E-mail: altstaedt@uni-bayreuth.de; Altstaedt, V., E-mail: altstaedt@uni-bayreuth.de [Polymer Engineering, University of Bayreuth, Germany and Polymer Engineering, Universitaetsstrasse 30, 95447 Bayreuth (Germany)

    2014-05-15T23:59:59.000Z

    This study focuses on the development of Bisphenol-F-benzoxazine resins blended with different ratios of a trifunctional epoxy resin suitable as matrix for substrates for high temperature printed circuit board (HT-PCB) applications. With the benzoxazine blends glass transition temperatures of more than 190 °C could be achieved in combination with a coefficient of thermal expansion in thickness direction (z-CTE) of less than 60 ppm/K without adding any fillers. This shows the high potential of the benzoxazine-epoxy blend systems as substrate materials for HT-PCBs. To understand the thermal behavior of the different formulations, the apparent crosslink density was calculated based on data from Dynamic Mechanical Analysis. Laminates in laboratory scale were prepared and characterized to demonstrate the transformation of the neat resin properties into real electronic substrate properties. The produced laminates exhibit a z-CTE below 40 ppm/K.

  9. HEAVY-ION RADIOGRAPHY AND HEAVY-ION COMPUTED TOMOGRAPHY

    E-Print Network [OSTI]

    Fabrikant, J.I.

    2010-01-01T23:59:59.000Z

    RADIOGRAPHY AND HEAVY-ION COMPUTED TOMOGRAPHY 1,2 Jacob I .RADIOGRAPHY AND HEAVY-ION COMPUTED TOMOGRAPHY J I Fabrikant,

  10. Ion mobility sensor system

    DOE Patents [OSTI]

    Xu, Jun; Watson, David B.; Whitten, William B.

    2013-01-22T23:59:59.000Z

    An ion mobility sensor system including an ion mobility spectrometer and a differential mobility spectrometer coupled to the ion mobility spectrometer. The ion mobility spectrometer has a first chamber having first end and a second end extending along a first direction, and a first electrode system that generates a constant electric field parallel to the first direction. The differential mobility spectrometer includes a second chamber having a third end and a fourth end configured such that a fluid may flow in a second direction from the third end to the fourth end, and a second electrode system that generates an asymmetric electric field within an interior of the second chamber. Additionally, the ion mobility spectrometer and the differential mobility spectrometer form an interface region. Also, the first end and the third end are positioned facing one another so that the constant electric field enters the third end and overlaps the fluid flowing in the second direction.

  11. Mathematical model of stress formation during vacuum resin infusion I.B. Sevostianov, V.E. Verijenko*, C.J. von Klemperer, B. Chevallereau1

    E-Print Network [OSTI]

    Sevostianov, Igor

    Mathematical model of stress formation during vacuum resin infusion process I.B. Sevostianov, V manufacturing technology based on vacuum infusion which is also known as resin film infusion technology to be infused by the vacuum to completely wet-out the reinforcements and eliminate air voids in the laminate

  12. Use of 2,5-dimethyl-2,5-hexane diamine as a curing agent for epoxy resins

    DOE Patents [OSTI]

    Rinde, James A. [Livermore, CA; Newey, Herbert A. [Lafayette, CA

    1981-02-24T23:59:59.000Z

    Primary diamines of the formula ##STR1## wherein R is a straight chain saturated hydrocarbon of 2 to 4 carbons, a disubstituted benzene ring, or disubstituted dibenzo methane for use as a curing agent for epoxy resins. These curing agents can be used to form epoxy resin mixtures useful in filament winding and pre-impregnated fiber molding and in formulating film adhesives, powder coatings and molding powders. The epoxy mixtures form for such uses as room temperature non-reacting, intermediate stable state which has a latent cross-linking capability.

  13. Use of 2,5-dimethyl-2,5-hexane diamine as a curing agent for epoxy resins

    DOE Patents [OSTI]

    Rinde, J.A.; Newey, H.A.

    1981-02-24T23:59:59.000Z

    Primary diamines are disclosed of the formula shown in a diagram wherein R is a straight chain saturated hydrocarbon of 2 to 4 carbons, a disubstituted benzene ring, or disubstituted dibenzomethane for use as a curing agent for epoxy resins. These curing agents can be used to form epoxy resin mixtures useful in filament winding and pre-impregnated fiber molding and in formulating film adhesives, powder coatings and molding powders. The epoxy mixtures form for such uses as room temperature non-reacting, intermediate stable state which has a latent cross-linking capability.

  14. CRYOGENIC LIFETIME TESTS ON A COMMERCIAL EPOXY RESIN HIGH VOLTAGE BUSHING

    SciTech Connect (OSTI)

    Schwenterly, S W [ORNL; Pleva, Ed [Waukesha Electric Systems, Waukesha, WI; Ha, Tam T [ORNL

    2012-01-01T23:59:59.000Z

    High-temperature superconducting (HTS) power devices operating in liquid nitrogen frequently require high-voltage bushings to carry the current leads from the superconducting windings to the room temperature grid connections. Oak Ridge National Laboratory is collaborating with Waukesha Electric Systems, SuperPower, and Southern California Edison to develop and demonstrate an HTS utility power transformer. Previous dielectric high voltage tests in support of this program have been carried out in test cryostats with commercial epoxy resin bushings from Electro Composites Inc. (ECI). Though the bushings performed well in these short-term tests, their long-term operation at high voltage in liquid nitrogen needs to be verified for use on the utility grid. Long-term tests are being carried out on a sample 28-kV-class ECI bushing. The bushing has a monolithic cast, cycloaliphatic resin body and is fire- and shatter-resistant. The test cryostat is located in an interlocked cage and is energized at 25 kVac around the clock. Liquid nitrogen (LN) is automatically refilled every 9.5 hours. Partial discharge, capacitance, and leakage resistance tests are periodically performed to check for deviations from factory values. At present, over 2400 hours have been accumulated with no changes in these parameters. The tests are scheduled to run for four to six months.

  15. Skew chicane based betatron eigenmode exchange module

    DOE Patents [OSTI]

    Douglas, David (Yorktown, VA)

    2010-12-28T23:59:59.000Z

    A skewed chicane eigenmode exchange module (SCEEM) that combines in a single beamline segment the separate functionalities of a skew quad eigenmode exchange module and a magnetic chicane. This module allows the exchange of independent betatron eigenmodes, alters electron beam orbit geometry, and provides longitudinal parameter control with dispersion management in a single beamline segment with stable betatron behavior. It thus reduces the spatial requirements for multiple beam dynamic functions, reduces required component counts and thus reduces costs, and allows the use of more compact accelerator configurations than prior art design methods.

  16. Heat Exchanger Support Bracket Design Calculations

    SciTech Connect (OSTI)

    Rucinski, Russ; /Fermilab

    1995-01-12T23:59:59.000Z

    This engineering note documents the design of the heat exchanger support brackets. The heat exchanger is roughly 40 feet long, 22 inches in diameter and weighs 6750 pounds. It will be mounted on two identical support brackets that are anchored to a concrete wall. The design calculations were done for one bracket supporting the full weight of the heat exchanger, rounded up to 6800 pounds. The design follows the American Institute of Steel Construction (AISC) Manual of steel construction, Eighth edition. All calculated stresses and loads on welds were below allowables.

  17. Better Buildings Workforce Peer Exchange Call: Kick-off | Department...

    Energy Savers [EERE]

    Documents & Publications Better Buildings Working with Utilities Peer Exchange Call: Kick-off Administering Nonprofit Energy Efficiency Programs Finance Peer Exchange Kickoff Call...

  18. Better Buildings Working with Utilities Peer Exchange Call: Kick...

    Broader source: Energy.gov (indexed) [DOE]

    April 21, 2011 Call Slides and Discussion Summary More Documents & Publications Finance Peer Exchange Kickoff Call Better Buildings Workforce Peer Exchange Call: Kick-off...

  19. Amine-Amine Exchange in Aminium-Methanesulfonate Aerosols. |...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Amine-Amine Exchange in Aminium-Methanesulfonate Aerosols. Amine-Amine Exchange in Aminium-Methanesulfonate Aerosols. Abstract: Aerosol particles are ubiquitous in the atmosphere...

  20. Gate-tunable exchange coupling between cobalt clusters on graphene...

    Office of Scientific and Technical Information (OSTI)

    Accepted Manuscript: Gate-tunable exchange coupling between cobalt clusters on graphene Citation Details Title: Gate-tunable exchange coupling between cobalt clusters on...