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Note: This page contains sample records for the topic "ion exchange ix" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
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1

Ion exchange technology assessment report  

SciTech Connect (OSTI)

In the execution of its charter, the SRS Ion Exchange Technology Assessment Team has determined that ion exchange (IX) technology has evolved to the point where it should now be considered as a viable alternative to the SRS reference ITP/LW/PH process. The ion exchange media available today offer the ability to design ion exchange processing systems tailored to the unique physical and chemical properties of SRS soluble HLW's. The technical assessment of IX technology and its applicability to the processing of SRS soluble HLW has demonstrated that IX is unquestionably a viable technology. A task team was chartered to evaluate the technology of ion exchange and its potential for replacing the present In-Tank Precipitation and proposed Late Wash processes to remove Cs, Sr, and Pu from soluble salt solutions at the Savannah River Site. This report documents the ion exchange technology assessment and conclusions of the task team.

Duhn, E.F.

1992-01-01T23:59:59.000Z

2

Ion exchange technology assessment report  

SciTech Connect (OSTI)

In the execution of its charter, the SRS Ion Exchange Technology Assessment Team has determined that ion exchange (IX) technology has evolved to the point where it should now be considered as a viable alternative to the SRS reference ITP/LW/PH process. The ion exchange media available today offer the ability to design ion exchange processing systems tailored to the unique physical and chemical properties of SRS soluble HLW`s. The technical assessment of IX technology and its applicability to the processing of SRS soluble HLW has demonstrated that IX is unquestionably a viable technology. A task team was chartered to evaluate the technology of ion exchange and its potential for replacing the present In-Tank Precipitation and proposed Late Wash processes to remove Cs, Sr, and Pu from soluble salt solutions at the Savannah River Site. This report documents the ion exchange technology assessment and conclusions of the task team.

Duhn, E.F.

1992-12-31T23:59:59.000Z

3

Ion exchange phenomena  

SciTech Connect (OSTI)

Ion exchange phenomena involve the population of readily exchangeable ions, the subset of adsorbed solutes that balance the intrinsic surface charge and can be readily replaced by major background electrolyte ions (Sposito, 2008). These phenomena have occupied a central place in soil chemistry research since Way (1850) first showed that potassium uptake by soils resulted in the release of an equal quantity of moles of charge of calcium and magnesium. Ion exchange phenomena are now routinely modeled in studies of soil formation (White et al., 2005), soil reclamation (Kopittke et al., 2006), soil fertilitization (Agbenin and Yakubu, 2006), colloidal dispersion/flocculation (Charlet and Tournassat, 2005), the mechanics of argillaceous media (Gajo and Loret, 2007), aquitard pore water chemistry (Tournassat et al., 2008), and groundwater (Timms and Hendry, 2007; McNab et al., 2009) and contaminant hydrology (Chatterjee et al., 2008; van Oploo et al., 2008; Serrano et al., 2009).

Bourg, I.C.; Sposito, G.

2011-05-01T23:59:59.000Z

4

Vitrification of ion exchange resins  

DOE Patents [OSTI]

The present invention relates to vitrification of ion exchange resins that have become loaded with hazardous or radioactive wastes, in a way that produces a homogenous and durable waste form and reduces the disposal volume of the resin. The methods of the present invention involve directly adding borosilicate glass formers and an oxidizer to the ion exchange resin and heating the mixture at sufficient temperature to produce homogeneous glass.

Cicero-Herman, Connie A. (Aiken, SC); Workman, Rhonda Jackson (North Augusta, SC)

2001-01-01T23:59:59.000Z

5

MODELING RESULTS FROM CESIUM ION EXCHANGE PROCESSING WITH SPHERICAL RESINS  

SciTech Connect (OSTI)

Ion exchange modeling was conducted at the Savannah River National Laboratory to compare the performance of two organic resins in support of Small Column Ion Exchange (SCIX). In-tank ion exchange (IX) columns are being considered for cesium removal at Hanford and the Savannah River Site (SRS). The spherical forms of resorcinol formaldehyde ion exchange resin (sRF) as well as a hypothetical spherical SuperLig{reg_sign} 644 (SL644) are evaluated for decontamination of dissolved saltcake wastes (supernates). Both SuperLig{reg_sign} and resorcinol formaldehyde resin beds can exhibit hydraulic problems in their granular (nonspherical) forms. SRS waste is generally lower in potassium and organic components than Hanford waste. Using VERSE-LC Version 7.8 along with the cesium Freundlich/Langmuir isotherms to simulate the waste decontamination in ion exchange columns, spherical SL644 was found to reduce column cycling by 50% for high-potassium supernates, but sRF performed equally well for the lowest-potassium feeds. Reduced cycling results in reduction of nitric acid (resin elution) and sodium addition (resin regeneration), therefore, significantly reducing life-cycle operational costs. These findings motivate the development of a spherical form of SL644. This work demonstrates the versatility of the ion exchange modeling to study the effects of resin characteristics on processing cycles, rates, and cold chemical consumption. The value of a resin with increased selectivity for cesium over potassium can be assessed for further development.

Nash, C.; Hang, T.; Aleman, S.

2011-01-03T23:59:59.000Z

6

Phosphonic acid based ion exchange resins  

DOE Patents [OSTI]

An ion exchange resin is described for extracting metal ions from a liquid waste stream. An ion exchange resin is prepared by copolymerizing a vinylidene diphosphonic acid with styrene, acrylonitrile and divinylbenzene. 9 figures.

Horwitz, E.P.; Alexandratos, S.D.; Gatrone, R.C.; Chiarizia, R.

1994-01-25T23:59:59.000Z

7

Grafted methylenediphosphonate ion exchange resins  

DOE Patents [OSTI]

An ion exchange resin is disclosed that is comprised of an insoluble copolymer onto which are grafted pendent groups that provide 1.0 to about 10 mmol/g dry weight phosphorous. The pendent groups have the formula ##STR1## wherein R is hydrogen, a cation or mixtures thereof; and R.sup.1 is hydrogen or an C.sub.1 -C.sub.2 alkyl group. The resin also contains zero to about 5 mmol/g dry weight of pendent aromatic sulfonate groups. Processes for making and using an ion exchange resin are also disclosed.

Trochimcznk, Andrzej W. (Knoxbille, TN); Gatrone, Ralph C. (Plymouth, PA); Alexandratos, Spiro (Knoxville, TN); Horwitz, E. Philip (Naperville, IL)

1997-01-01T23:59:59.000Z

8

Grafted methylenediphosphonate ion exchange resins  

DOE Patents [OSTI]

An ion exchange resin is disclosed that is comprised of an insoluble copolymer onto which are grafted pendent groups that provide 1.0 to about 10 mmol/g dry weight phosphorous. The pendent groups have the formula ##STR1## wherein R is hydrogen, a cation or mixtures thereof; and R.sup.1 is hydrogen or an C.sub.1 -C.sub.2 alkyl group. The resin also contains zero to about 5 mmol/g dry weight of pendent aromatic sulfonate groups. Processes for making and using an ion exchange-resin are also disclosed.

Trochimcznk, Andrzej W. (Knoxville, TN); Gatrone, Ralph C. (Plymouth, PA); Alexandratos, Spiro (Knoxville, TN); Horwitz, E. Philip (Naperville, IL)

1998-01-27T23:59:59.000Z

9

Grafted methylenediphosphonate ion exchange resins  

DOE Patents [OSTI]

An ion exchange resin is disclosed that is comprised of an insoluble copolymer onto which are grafted pendent groups that provide 1.0 to about 10 mmol/g dry weight phosphorus. The pendent groups have the formula as shown in the patent wherein R is hydrogen, a cation or mixtures thereof; and R{sup 1} is hydrogen or an C{sub 1}-C{sub 2} alkyl group. The resin also contains zero to about 5 mmol/g dry weight of pendent aromatic sulfonate groups. Processes for making and using an ion exchange resin are also disclosed.

Trochimcznk, A.W.; Gatrone, R.C.; Alexandratos, S.; Horwitz, E.P.

1997-04-08T23:59:59.000Z

10

Ion exchange purification of scandium  

DOE Patents [OSTI]

An improvement in purification of scandium through ion exchange chromatography is disclosed in which the oxidation potential of the eluting solution is altered by the addition of potassium chlorate or ammonium chloride so that removal of contaminants is encouraged. The temperature, pH and concentration of the eluent HEDTA are controlled in order to maintain the scandium in the column while minimizing dilution of the scandium band. Recovery of scandium is improved by pumping dilute scandium over the column prior to stripping the scandium and precipitation. This eliminates the HEDTA ion and other monovalent cations contaminating the scandium band. This method maximizes recovery of scandium while maintaining purity. 2 figs.

Herchenroeder, L.A.; Burkholder, H.R.

1990-10-23T23:59:59.000Z

11

REMOVAL OF CESIUM FROM SAVANNAH RIVER SITE WASTE WITH SPHERICAL RESORCINOL FORMALDEHYDE ION EXCHANGE RESIN EXPERIMENTAL TESTS  

SciTech Connect (OSTI)

A principal goal at the Savannah River Site (SRS) is to safely dispose of the large volume of liquid nuclear waste held in many storage tanks. In-tank ion exchange (IX) columns are being considered for cesium removal. The spherical form of resorcinol formaldehyde ion exchange resin (sRF) is being evaluated for decontamination of dissolved saltcake waste at SRS, which is generally lower in potassium and organic components than Hanford waste. The sRF performance with SRS waste was evaluated in two phases: resin batch contacts and IX column testing with both simulated and actual dissolved salt waste. The tests, equipment, and results are discussed.

Duignan, M.; Nash, C.

2010-03-31T23:59:59.000Z

12

DIVALENT ION EXCHANGE WITH ALKALI  

E-Print Network [OSTI]

Injection for Enhanced Oil Recovery - A Status Report," SPEDOE Symposium on Enhanced Oil Recovery, Tulsa, OK, Apri120-ions is important enhanced oil recovery with chemical addi-

Bunge, A.L.

2011-01-01T23:59:59.000Z

13

PILOT-SCALE HYDRAULIC TESTING OF RESORCINOL FORMALDEHYDE ION EXCHANGE RESIN  

SciTech Connect (OSTI)

Savannah River National Laboratory (SRNL) performed pilot-scale hydraulic/chemical testing of spherical resorcinol formaldehyde (RF) ion exchange (IX) resin for the River Protection Project-Hanford Tank Waste Treatment & Immobilization Plant (WTP) Project. The RF resin hydraulic cycle testing was conducted in two pilot-scale IX columns, 1/4 and 1/2 scale. A total of twenty-three hydraulic/chemical cycles were successfully completed on the spherical RF resin. Sixteen of these cycles were completed in the 24-inch IX Column (1/2 scale column). Hydraulic testing showed that the permeability of the RF resin remained essentially constant, with no observed trend in the reduction of the permeability as the number of cycles increased. The permeability during the pilot-scale testing was 3 times better than the design requirements of the WTP full-scale IX system. The RF resin bed showed no tendency to form fissures or pack more densely as the number of cycles increased. Particle size measurements of the RF resin showed no indication of particle size change (for a given chemical) with cycles and essentially no fines formation. The permeability of the resin bed was uniform with respect to changes in bed depth. Upflow Regeneration and Simulant Introduction in the IX columns revealed another RF resin benefit; negligible radial pressures to the column walls from the swelling of resin beads. The hydraulic and chemical performance of the spherical RF resin during cycle testing was found to be superior to all other tested IX resins. The pilot-scale testing indicates that the RF resin is durable and should hold up to many hydraulic cycles in actual radioactive Cesium (Cs) separation.

Adamson, D.

2009-05-28T23:59:59.000Z

14

Ion exchange selectivity of a perfluorosulfonate ionomer  

E-Print Network [OSTI]

of Advisory Committee: Dr. C. R. Martin The ion exchange selectivity of Nafion was evaluated. Two separate series of homologous cations were separated. A series of viologens, methyl, benzyl, and heptyl, were sepa- rated by utilizing tetramethyl ammonium... which demonstrated X m the ionic exchange characteristic of the system. Comparison of the elution volumes of methyl viologen on ODS (1. 80 ml) and on Nafion coated ODS (9. 50 ml) also indicates the ionic characteristic of the Nafion column...

Wilkerson, James Edward

1983-01-01T23:59:59.000Z

15

Thermal Analysis of LANL Ion Exchange Column  

SciTech Connect (OSTI)

This document reports results from an ion exchange column heat transfer analysis requested by Los Alamos National Laboratory (LANL). The object of the analysis is to demonstrate that the decay heat from the Pu-238 will not cause resin bed temperatures to increase to a level where the resin significantly degrades.

Laurinat, J.E.

1999-06-16T23:59:59.000Z

16

Porous solid ion exchange wafer for immobilizing biomolecules  

DOE Patents [OSTI]

A porous solid ion exchange wafer having a combination of a biomolecule capture-resin and an ion-exchange resin forming a charged capture resin within said wafer. Also disclosed is a porous solid ion exchange wafer having a combination of a biomolecule capture-resin and an ion-exchange resin forming a charged capture resin within said wafer containing a biomolecule with a tag. A separate bioreactor is also disclosed incorporating the wafer described above.

Arora, Michelle B. (Woodridge, IL); Hestekin, Jamie A. (Morton Grove, IL); Lin, YuPo J. (Naperville, IL); St. Martin, Edward J. (Libertyville, IL); Snyder, Seth W. (Lincolnwood, IL)

2007-12-11T23:59:59.000Z

17

Novel silica-based ion exchange resin  

SciTech Connect (OSTI)

Eichrom`s highly successful Diphonixo resin resembles a conventional ion exchange resin in its use of sulfonic acid ligands on a styrene- divinylbenzene matrix. Diphonix resin exhibits rapid exchange kinetics that allow economical operation of ion exchange systems. Unlike conventional resins, Diphonix resin contains chelating ligands that are diphosphonic acid groups that recognize and remove the targeted metals and reject the more common elements such as sodium, calcium and magnesium. This latter property makes Diphonix ideal for many industrial scale applications, including those involving waste treatment. For treatment of low-level, transuranic (TRU) and high- level radioactive wastes, Diphonix`s polystyrene backbone hinders its application due to radiolytic stability of the carbon-hydrogen bonds and lack of compatibility with expected vitrification schemes. Polystyrene-based Diphonix is approximately 60% carbon- hydrogen. In response to an identified need within the Department of Energy for a resin with the positive attributes of Diphonix that also exhibits greater radiolytic stability and final waste form compatibility, Eichrom has successfully developed a new, silica-based resin version of Diphonix. Target application for this new resin is for use in environmental restoration and waste management situations involving the processing of low-level, transuranic and high-level radioactive wastes. The resin can also be used for processing liquid mixed waste (waste that contains low level radioactivity and hazardous constituents) including mixed wastes contaminated with organic compounds. Silica-based Diphonix is only 10% carbon-hydrogen, with the bulk of the matrix silica.

NONE

1997-11-01T23:59:59.000Z

18

PILOT-SCALE HYDRAULIC TESTING OF RESORCINOL FORMALDEHYDE ION EXCHANGE RESIN  

SciTech Connect (OSTI)

Savannah River National Laboratory (SRNL) performed pilot-scale hydraulic/chemical testing of spherical resorcinol formaldehyde (RF) ion exchange (IX) resin for the River Protection Project Hanford Tank Waste Treatment & Immobilization Plant (WTP) Project. The RF resin cycle testing was conducted in two pilot-scale IX columns, 1/4 and 1/2 scale. A total of twenty-three hydraulic/chemical cycles were successfully completed on the spherical RF resin. Seven of the cycles were completed in the 12-inch IX Column and sixteen cycles were completed in the 24-inch IX Column. Hydraulic testing showed that the permeability of the RF resin remained essentially constant, with no observed trend in the reduction of the permeability as the number of cycles increased. The permeability during the pilot-scale testing was 2 1/2 times better than the design requirements of the WTP full-scale system. The permeability of the resin bed was uniform with respect to changes in bed depth. Upflow Regeneration and Simulant Introduction in the IX columns revealed another RF resin benefit; negligible radial pressures to the column walls from the swelling of resin beads. In downflow of the Regeneration and Simulant Introduction steps, the resin bed particles pack tightly together and produce higher hydraulic pressures than that found in upflow. Also, upflow Simulant Introduction produced an ideal level bed for the twenty cycles completed using upflow Simulant Introduction. Conversely, the three cycles conducted using downflow Simulant Introduction produced an uneven bed surface with erosion around the thermowells. The RF resin bed in both columns showed no tendency to form fissures or pack more densely as the number of cycles increased. Particle size measurements of the RF resin showed no indication of particle size change (for a given chemical) with cycles and essentially no fines formation. Micrographs comparing representative bead samples before and after testing indicated no change in bead morphology. The skeletal density of the RF resin in the 24-inch IX Column increased slightly with cycling (in both hydrogen and sodium form). The chemical solutions used in the pilot-scale testing remained clear throughout testing, indicating very little chemical breakdown of the RF resin beads. The RF resin particles did not break down and produce fines, which would have resulted in higher pressure drops across the resin bed. Three cesium (Cs) loading tests were conducted on the RF resin in pilot-scale IX columns. Laboratory analyses concluded the Cs in the effluent never exceeded the detection limit. Therefore, there was no measurable degradation in cesium removal performance. Using the pilot-scale systems to add the RF resin to the columns and removing the resin from the columns was found to work well. The resin was added and removed from the columns three times with no operational concerns. Whether the resin was in sodium or hydrogen form, the resin flowed well and resulted in an ideal resin bed formation during each Resin Addition. During Resin Removal, 99+ % of the resin was easily sluiced out of the IX column. The hydraulic performance of the spherical RF resin during cycle testing was found to be superior to all other tested IX resins, and SRNL testing indicates that the resin should hold up to many cycles in actual radioactive Cs separation. The RF resin was found to be durable in the long term cycle testing and should result in a cost saving in actual operations when compared to other IX resins.

Adamson, D

2007-01-09T23:59:59.000Z

19

PILOT-SCALE HYDRAULIC TESTING OF RESORCINOL FORMALDEHYDE ION EXCHANGE RESIN  

SciTech Connect (OSTI)

Savannah River National Laboratory (SRNL) performed pilot-scale hydraulic/chemical testing of spherical resorcinol formaldehyde (RF) ion exchange (IX) resin for the River Protection Project-Hanford Tank Waste Treatment & Immobilization Plant (WTP) Project. The RF resin cycle testing was conducted in two pilot-scale IX columns, 1/4 and 1/2 scale. A total of twenty-three hydraulic/chemical cycles were successfully completed on the spherical RF resin. Seven of the cycles were completed in the 12 inch IX Column and sixteen cycles were completed in the 24 inch IX Column. Hydraulic testing showed that the permeability of the RF resin remained essentially constant, with no observed trend in the reduction of the permeability as the number of cycles increased. The permeability during the pilot-scale testing was 2 1/2 times better than the design requirements of the WTP full-scale system. The permeability of the resin bed was uniform with respect to changes in bed depth. Upflow Regeneration and Simulant Introduction in the IX columns revealed another RF resin benefit; negligible radial pressures to the column walls from the swelling of resin beads. In downflow of the Regeneration and Simulant Introduction steps, the resin bed particles pack tightly together and produce higher hydraulic pressures than that found in upflow. Also, upflow Simulant Introduction produced an ideal level bed for the twenty cycles completed using upflow Simulant Introduction. Conversely, the three cycles conducted using downflow Simulant Introduction produced an uneven bed surface with erosion around the thermowells. The RF resin bed in both columns showed no tendency to form fissures or pack more densely as the number of cycles increased. Particle size measurements of the RF resin showed no indication of particle size change (for a given chemical) with cycles and essentially no fines formation. Micrographs comparing representative bead samples before and after testing indicated no change in bead morphology. The skeletal density of the RF resin in the 24 inch IX Column increased slightly with cycling (in both hydrogen and sodium form). The chemical solutions used in the pilot-scale testing remained clear throughout testing, indicating very little chemical breakdown of the RF resin beads. The RF resin particles did not break down and produce fines, which would have resulted in higher pressure drops across the resin bed. Three cesium (Cs) loading tests were conducted on the RF resin in pilot-scale IX columns. Laboratory analyses concluded the Cs in the effluent never exceeded the detection limit. Therefore, there was no measurable degradation in cesium removal performance. Using the pilot-scale systems to add the RF resin to the columns and removing the resin from the columns was found to work well. The resin was added and removed from the columns three times with no operational concerns. Whether the resin was in sodium or hydrogen form, the resin flowed well and resulted in an ideal resin bed formation during each Resin Addition. During Resin Removal, 99+ % of the resin was easily sluiced out of the IX column. The hydraulic performance of the spherical RF resin during cycle testing was found to be superior to all other tested IX resins, and SRNL testing indicates that the resin should hold up to many cycles in actual radioactive Cs separation. The RF resin was found to be durable in the long term cycle testing and should result in a cost saving in actual operations when compared to other IX resins.

Adamson, D

2006-11-08T23:59:59.000Z

20

Solidification of ion exchange resin wastes  

SciTech Connect (OSTI)

Solidification media investigated included portland type I, portland type III and high alumina cements, a proprietary gypsum-based polymer modified cement, and a vinyl ester-styrene thermosetting plastic. Samples formulated with hydraulic cement were analyzed to investigate the effects of resin type, resin loading, waste-to-cement ratio, and water-to-cement ratio. The solidification of cation resin wastes with portland cement was characterized by excessive swelling and cracking of waste forms, both after curing and during immersion testing. Mixed bed resin waste formulations were limited by their cation component. Additives to improve the mechanical properties of portland cement-ion exchange resin waste forms were evaluated. High alumina cement formulations dislayed a resistance to deterioration of mechanical integrity during immersion testing, thus providing a significant advantage over portland cements for the solidification of resin wastes. Properties of cement-ion exchange resin waste forms were examined. An experiment was conducted to study the leachability of /sup 137/Cs, /sup 85/Sr, and /sup 60/Co from resins modified in portland type III and high alumina cements. The cumulative /sup 137/Cs fraction release was at least an order of magnitude greater than that of either /sup 85/Sr or /sup 60/Co. Release rates of /sup 137/Cs in high alumina cement were greater than those in portland III cement by a factor of two.Compressive strength and leach testing were conducted for resin wastes solidified with polymer-modified gypsum based cement. /sup 137/Cs, /sup 85/Sr, and /sup 60/Co fraction releases were about one, two and three orders of magnitude higher, respectively, than in equivalent portland type III cement formulations. As much as 28.6 wt % dry ion exchange resin was successfully solidified using vinyl ester-styrene compared with a maximum of 25 wt % in both portland and gypsum-based cement.

Not Available

1982-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "ion exchange ix" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Modeling Multi-Metal Ion Exchange in Biosorption  

E-Print Network [OSTI]

, may serve as a means for purifying industrial wastewaters that contain toxic heavy metal ions heavy metals often through ion exchange. This biosorption can be used for purification of metalModeling Multi-Metal Ion Exchange in Biosorption S I L K E S C H I E W E R A N D B O H U M I L V O

Volesky, Bohumil

22

adjustment ion exchange: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of intra-molecular interactions on the gas-phase conformation of peptides as probed by ion mobility-mass spectrometry, gas-phase hydrogendeuterium exchange, and molecular...

23

Effects of ionizing radiation on modern ion exchange materials  

SciTech Connect (OSTI)

We review published studies of the effects of ionizing radiation on ion exchange materials, emphasizing those published in recent years. A brief overview is followed by a more detailed examination of recent developments. Our review includes styrene/divinylbenzene copolymers with cation-exchange or anion-exchange functional groups, polyvinylpyridine anion exchangers, chelating resins, multifunctional resins, and inorganic exchangers. In general, strong-acid cation exchange resins are more resistant to radiation than are strong-base anion exchange resins, and polyvinylpyridine resins are more resistant than polystyrene resins. Cross-linkage, salt form, moisture content, and the surrounding medium all affect the radiation stability of a specific exchanger. Inorganic exchangers usually, but not always, exhibit high radiation resistance. Liquid ion exchangers, which have been used so extensively in nuclear processing applications, also are included.

Marsh, S.F.; Pillay, K.K.S.

1993-10-01T23:59:59.000Z

24

TECHNICAL COMPARISON OF CANDIDATE ION EXCHANGE MEDIA FOR SMALL COLUMN ION EXCHANGE (SCIX) APPLICATIONS IN SUPPORT OF SUPPLEMENTAL LAW PRETREATMENT  

SciTech Connect (OSTI)

At-tank supplemental pretreatment including both filtration and small column ion exchange is currently under evaluation to facilitate salt waste retrieval and processing in the Hanford tank farms. Spherical resorcinol formaldehyde (sRF) resin is the baseline ion exchange resin for use in the Waste Treatment and Immobilization Plant (WTP). This document provides background and technical rationale to assist in determining whether spherical resorcinol formaldehyde (sRF) is also the appropriate ion exchange resin for supplemental LAW pretreatment processes and compares sRF with crystalline silicotitanate (CST) as potential supplemental pretreatment ion exchange media.

RAMSEY AA; THORSON MR

2010-12-28T23:59:59.000Z

25

E-Print Network 3.0 - acidic ion exchange Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Gina M. Canfield,a Summary: and other zeolites tend to exchange hydronium ions from hydro- lyzed water or from acidic hydrated metal... Sodalite ion exchange in polyethylene...

26

CHARACTERIZATION OF CYCLED SPHERICAL RESORCINOL-FORMALDEHYDE ION EXCHANGE RESIN  

SciTech Connect (OSTI)

This report presents characterization data for two spherical resorcinol-formaldehyde (sRF) resin beds that had processed cesium in non-radioactive and radioactive cycles. All column cycle operations for the resin beds including loading, displacements, elution, regeneration, breakthroughs, and solution analyses are reported in Nash and Duignan, 2009a. That report covered four ion exchange (IX) campaigns using the two {approx}11 mL beds in columns in a lead-lag arrangement. The first two campaigns used Savannah River Site (SRS) Tank 2F nonradioactive simulant while the latter two were fed with actual dissolved salt in the Savannah River National Laboratory (SRNL) Shielded Cells. Both radioactive cycles ran to cesium breakthrough of the lead column. The resin beds saw in excess of 400 bed volumes of feed in each cycle. Resin disposal plans in tank farm processing depend on characterizations of resin used with actual tank feed. Following a final 30 bed volume (BV) elution with nitric acid, the resin beds were found to contain detectable chromium, barium, boron, aluminum, iron, sodium, sulfur, plutonium, cesium, and mercury. Resin affinity for plutonium is important in criticality safety considerations. Cesium-137 was found to be less than 10E+7 dpm/g of resin, similar to past work with sRF resin. Sulfur levels are reasonably consistent with other work and are expected to represent sulfur chemistry used in the resin manufacture. There were low but detectable levels of technetium, americium, and curium. Toxicity Characteristic Leaching Procedure (TCLP) work on the used (eluted) resin samples showed significant contents of mercury, barium, and chromium. One resin sample exceeded the TCLP level for mercury while the other metals were below TCLP levels. TCLP organics measurements indicated measurable benzene in one case, though the source was unknown. Results of this work were compared with other work on similar sRF resin characterizations in this report. This is the first work to quantify mercury on sRF resin. Resin mercury content is important in plans for the disposition of used sRF resin. Mercury speciation in high level waste (HLW) is unknown. It may be partly organic, one example being methyl mercury cation. Further study of the resin's affinity for mercury is recommended.

Nash, C.; Duignan, M.

2010-02-23T23:59:59.000Z

27

Interpenetrating polymer network ion exchange membranes and method for preparing same  

DOE Patents [OSTI]

Interpenetrating polymer network ion exchange membranes include a microporous polymeric support film interpenetrated by an ion exchange polymer and are produced by absorbing and polymerizing monomers within the support film. The ion exchange polymer provides ion exchange ligands at the surface of and throughout the support film which have sufficient ligand mobility to extract and transport ions across the membrane.

Alexandratos, Spiro D. (Knoxville, TN); Danesi, Pier R. (Vienna, AT); Horwitz, E. Philip (Naperville, IL)

1989-01-01T23:59:59.000Z

28

Radiation effects on a zeolite ion exchanger and a pollucite  

SciTech Connect (OSTI)

Cation exchange capacity and selective Cs and Sr ion sorption measurements were found to be too insensitive to detect radiation effects on irradiated Ionsiv-IE-95 zeolite. However, leaching the zeolite while under ..gamma..-irradiation caused a modest increase in the desorption of exchangeable ions. Gamma-irradiation and subsequent leaching of a natural pollucite also slightly enhanced the leachability of this material. The increased desorption of ions from the zeolite and the enhanced leachability of the pollucite are apparently caused by a decrease in pH due to the generation of acidic species during irradiation.

Komarneni, S.; Palau, G.L.; Pillay, K.K.S.

1983-01-01T23:59:59.000Z

29

MINOR ACTINIDE SEPARATIONS USING ION EXCHANGERS OR IONIC LIQUIDS  

SciTech Connect (OSTI)

This project seeks to determine if (1) inorganic-based ion exchange materials or (2) electrochemical methods in ionic liquids can be exploited to provide effective Am and Cm separations. Specifically, we seek to understand the fundamental structural and chemical factors responsible for the selectivity of inorganic-based ion-exchange materials for actinide and lanthanide ions. Furthermore, we seek to determine whether ionic liquids can serve as the electrolyte that would enable formation of higher oxidation states of Am and other actinides. Experiments indicated that pH, presence of complexants and Am oxidation state exhibit significant influence on the uptake of actinides and lanthanides by layered sodium titanate and hybrid zirconium and tin phosphonate ion exchangers. The affinity of the ion exchangers increased with increasing pH. Greater selectivity among Ln(III) ions with sodium titanate materials occurs at a pH close to the isoelectric potential of the ion exchanger. The addition of DTPA decreased uptake of Am and Ln, whereas the addition of TPEN generally increases uptake of Am and Ln ions by sodium titanate. Testing confirmed two different methods for producing Am(IV) by oxidation of Am(III) in ionic liquids (ILs). Experimental results suggest that the unique coordination environment of ionic liquids inhibits the direct electrochemical oxidation of Am(III). The non-coordinating environment increases the oxidation potential to a higher value, while making it difficult to remove the inner coordination of water. Both confirmed cases of Am(IV) were from the in-situ formation of strong chemical oxidizers.

Hobbs, D.; Visser, A.; Bridges, N.

2011-09-20T23:59:59.000Z

30

Ion exchange polymers for anion separations  

DOE Patents [OSTI]

Anion exchange resins including at least two positively charged sites and a well-defined spacing between the positive sites are provided together with a process of removing anions or anionic metal complexes from aqueous solutions by use of such resins. The resins can be substituted poly(vinylpyridine) and substituted polystyrene.

Jarvinen, G.D.; Marsh, S.F.; Bartsch, R.A.

1997-09-23T23:59:59.000Z

31

Ion exchange polymers for anion separations  

DOE Patents [OSTI]

Anion exchange resins including at least two positively charged sites and a ell-defined spacing between the positive sites are provided together with a process of removing anions or anionic metal complexes from aqueous solutions by use of such resins. The resins can be substituted poly(vinylpyridine) and substituted polystyrene.

Jarvinen, Gordon D. (Los Alamos, NM); Marsh, S. Fredric (Los Alamos, NM); Bartsch, Richard A. (Lubbock, TX)

1997-01-01T23:59:59.000Z

32

Rupture loop annex ion exchange RLAIX vault deactivation  

SciTech Connect (OSTI)

This engineering report documents the deactivation, stabilization and final conditions of the Rupture Loop Annex Ion Exchange (RLAIX) Vault located northwest of the 309 Building`s Plutonium Recycle Test Reactor (PRTR). Twelve ion exchange columns, piping debris, and column liquid were removed from the vault, packaged and shipped for disposal. The vault walls and floor were decontaminated, and portions of the vault were painted to fix loose contamination. Process piping and drains were plugged, and the cover blocks and rain cover were installed. Upon closure,the vault was empty, stabilized, isolated.

Ham, J.E.; Harris, D.L., Westinghouse Hanford

1996-08-01T23:59:59.000Z

33

Sandia National Laboratories: molecularly engineered ion exchanger  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the1developmentturbine bladelifetime ismobile test system Solarmolecularly engineered ion

34

Thermal Analysis for Ion-Exchange Column System  

SciTech Connect (OSTI)

Models have been developed to simulate the thermal characteristics of crystalline silicotitanate ion exchange media fully loaded with radioactive cesium either in a column configuration or distributed within a waste storage tank. This work was conducted to support the design and operation of a waste treatment process focused on treating dissolved, high-sodium salt waste solutions for the removal of specific radionuclides. The ion exchange column will be installed inside a high level waste storage tank at the Savannah River Site. After cesium loading, the ion exchange media may be transferred to the waste tank floor for interim storage. Models were used to predict temperature profiles in these areas of the system where the cesium-loaded media is expected to lead to localized regions of elevated temperature due to radiolytic decay. Normal operating conditions and accident scenarios (including loss of solution flow, inadvertent drainage, and loss of active cooling) were evaluated for the ion exchange column using bounding conditions to establish the design safety basis. The modeling results demonstrate that the baseline design using one central and four outer cooling tubes provides a highly efficient cooling mechanism for reducing the maximum column temperature. In-tank modeling results revealed that an idealized hemispherical mound shape leads to the highest tank floor temperatures. In contrast, even large volumes of CST distributed in a flat layer with a cylindrical shape do not result in significant floor heating.

Lee, Si Y.; King, William D.

2012-12-20T23:59:59.000Z

35

CO adsorption on ion-exchanged Ru zeolite catalysts  

SciTech Connect (OSTI)

CO adsorption on ion-exchanged Ru zeolite catalysts, studied by IR spectroscopy, revealed the existence of three types of ruthenium which adsorbed the carbon monoxide into three different states. The ruthenium types were atomically or highly dispersed ruthenium, ruthenium clusters which formed ruthenium carbonyl, and larger (> 1 nm) particles, probably on the outer zeolite surfaces.

Goodwin, J.G. (Univ. of Pittsburgh); Naccache, G.

1980-08-01T23:59:59.000Z

36

Method and solvent composition for regenerating an ion exchange resin  

DOE Patents [OSTI]

A method and composition for removing perchlorate from a highly selective ion exchange resin is disclosed. The disclosed approach comprises treating the resin in a solution of super critical or liquid carbon dioxide and one or more quaternary ammonium chloride surfactant compounds.

Even, William R. (Livermore, CA); Irvin, David J. (Livermore, CA); Irvin, Jennifer A. (Livermore, CA); Tarver, Edward E. (Livermore, CA); Brown, Gilbert M. (Knoxville, TN); Wang, James C. F. (Livermore, CA)

2002-01-01T23:59:59.000Z

37

Investigating the Use of Ion Exchange Resins for Processing Biodiesel Feedstocks  

E-Print Network [OSTI]

Ion exchange resins, commonly used in water treatment, demonstrate promise for the production of biodiesel from biomass feedstocks. The goal of this presented PhD research is to investigate novel uses of ion exchange resins for processing biodiesel...

Jamal, Yousuf 1973-

2012-11-27T23:59:59.000Z

38

Water Exchange Rates and Molecular Mechanism around Aqueous Halide Ions  

SciTech Connect (OSTI)

Molecular dynamics simulations were performed to systematically study the water-exchange mechanism around aqueous chloride, bromide, and iodide ions. Transition state theory, Grote-Hynes theory, and the reactive flux method were employed to compute water exchange rates. We computed the pressure dependence of rate constants and the corresponding activation volumes to investigate the mechanism of the solvent exchange event. The activation volumes obtained using the transition state theory rate constants are negative for all the three anions, thus indicating an associative mechanism. Contrary to the transition state theory results, activation volumes obtained using rate constants from Grote-Hynes theory and the reactive flux method are positive, thus indicating a dissociative mechanism. The Division of Chemical Sciences, Geosciences, and Biosciences, Office of Basic Energy Sciences (BES), of the U.S. Department of Energy (DOE) funded this work. Battelle operates Pacific Northwest National Laboratory for DOE. The calculations were carried out using computer resources provided by BES.

Annapureddy, Harsha V.; Dang, Liem X.

2014-07-17T23:59:59.000Z

39

Ion Exchange Testing with SRF Resin FY2012  

SciTech Connect (OSTI)

Ion exchange using spherical resorcinol-formaldehyde (SRF) resin has been selected by the U.S. Department of Energy’s Office of River Protection (DOE-ORP) for use in the Pretreatment Facility (PTF) of the Hanford Tank Waste Treatment and Immobilization Plant (WTP) and for potential application in at-tank deployment. Numerous studies have shown SRF resin to be effective for removing 137Cs from a wide variety of actual and simulated tank waste supernatants (Adamson et al. 2006; Blanchard et al. 2008; Burgeson et al. 2004; Duignan and Nash 2009; Fiskum et al. 2006a; Fiskum et al. 2006b; Fiskum et al. 2006c; Fiskum et al. 2007; Hassan and Adu-Wusu 2003; King et al. 2004; Nash et al. 2006). Prior work at the Pacific Northwest National Laboratory (PNNL) has focused primarily on the loading behavior for 4 to 6 M Na solutions at 25 to 45°C. Recent proposed changes to the WTP ion exchange process baseline indicate that loading may include a broader range of sodium molarities (0.1 to 8 M) and higher temperatures (50°C) to alleviate post-filtration precipitation issues. This report discusses ion exchange loading kinetics testing activities performed in accordance with Test Plan TP-WTPSP-002, Rev. 3.0 , which was prepared and approved in response to the Test Specification 24590 PTF-TSP-RT-09-002, Rev. 0 (Lehrman 2010) and Test Exception 24590 PTF TEF RT-11-00003, Rev. 0 (Meehan 2011). This testing focused on column tests evaluating the impact of elevated temperature on resin degradation over an extended period of time and batch contacts evaluating the impact on Cs loading over a broad range of sodium concentrations (0.1 to 5 M). These changes may be required to alleviate post-filtration precipitation issues and broaden the data range of SRF resin loading under the conditions expected with the new equipment and process changes.

Russell, Renee L.; Rinehart, Donald E.; Peterson, Reid A.

2013-06-11T23:59:59.000Z

40

Ion Exchange Testing with SRF Resin FY 2012  

SciTech Connect (OSTI)

Ion exchange using spherical resorcinol-formaldehyde (SRF) resin has been selected by the U.S. Department of Energy’s Office of River Protection (DOE-ORP) for use in the Pretreatment Facility (PTF) of the Hanford Tank Waste Treatment and Immobilization Plant (WTP) and for potential application in at-tank deployment. Numerous studies have shown SRF resin to be effective for removing 137Cs from a wide variety of actual and simulated tank waste supernatants (Adamson et al. 2006; Blanchard et al. 2008; Burgeson et al. 2004; Duignan and Nash 2009; Fiskum et al. 2006a; Fiskum et al. 2006b; Fiskum et al. 2006c; Fiskum et al. 2007; Hassan and Adu-Wusu 2003; King et al. 2004; Nash et al. 2006). Prior work at the Pacific Northwest National Laboratory (PNNL) has focused primarily on the loading behavior for 4 to 6 M Na solutions at 25 to 45°C. Recent proposed changes to the WTP ion exchange process baseline indicate that loading may include a broader range of sodium molarities (0.1 to 8 M) and higher temperatures (50°C) to alleviate post-filtration precipitation issues. This report discusses ion exchange loading kinetics testing activities performed in accordance with Test Plan TP-WTPSP-002, Rev. 3.01, which was prepared and approved in response to the Test Specification 24590-PTF-TSP-RT-09-002, Rev. 0 (Lehrman 2010) and Test Exception 24590-PTF-TEF-RT-11-00003, Rev. 0 (Meehan 2011). This testing focused on column tests evaluating the impact of elevated temperature on resin degradation over an extended period of time and batch contacts evaluating the impact on Cs loading over a broad range of sodium concentrations (0.1 to 5 M). These changes may be required to alleviate post-filtration precipitation issues and broaden the data range of SRF resin loading under the conditions expected with the new equipment and process changes.

Russell, Renee L.; Rinehart, Donald E.; Peterson, Reid A.

2014-07-02T23:59:59.000Z

Note: This page contains sample records for the topic "ion exchange ix" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

HEAT TRANSFER ANALYSIS FOR ION-EXCHANGE COLUMN SYSTEM  

SciTech Connect (OSTI)

Models have been developed to simulate the thermal characteristics of Crystalline Silicotitanate (CST) ion exchange media fully loaded with radioactive cesium in a column configuration and distributed within a waste storage tank. This work was conducted to support the Small Column Ion Exchange (SCIX) program which is focused on processing dissolved, high-sodium salt waste for the removal of specific radionuclides (including Cs-137, Sr-90, and actinides) within a High Level Waste (HLW) storage tank at the Savannah River Site. The SCIX design includes CST columns inserted and supported in the tank top risers for cesium removal. Temperature distributions and maximum temperatures across the column were calculated with a focus on process upset conditions. A two-dimensional computational modeling approach for the in-column ion-exchange domain was taken to include conservative, bounding estimates for key parameters such that the results would provide the maximum centerline temperatures achievable under the design configurations using a feed composition known to promote high cesium loading on CST. The current full-scale design for the CST column includes one central cooling pipe and four outer cooling tubes. Most calculations assumed that the fluid within the column was stagnant (i.e. no buoyancy-induced flow) for a conservative estimate. A primary objective of these calculations was to estimate temperature distributions across packed CST beds immersed in waste supernate or filled with dry air under various accident scenarios. Accident scenarios evaluated included loss of salt solution flow through the bed, inadvertent column drainage, and loss of active cooling in the column. The modeling results demonstrate that the baseline design using one central and four outer cooling tubes provides a highly efficient cooling mechanism for reducing the maximum column temperature.

Lee, S.; King, W.

2011-05-23T23:59:59.000Z

42

Electrically switched cesium ion exchange. FY 1996 annual report  

SciTech Connect (OSTI)

An electrochemical method for metal ion separations, called Electrically Switched Ion Exchange, is described. Direct oxidation and reduction of an electroactive film attached to an electrode surface is used to load and unload the film with alkali metal cations. The electroactive films under investigation are Ni hexacyanoferrates, which are deposited on the surface by applying an anodic potential to a Ni electrode in a solution containing the ferricyanide anion. Reported film preparation procedures were modified to produce films with improved capacity and stability. Electrochemical behavior of the derivatized electrodes were investigated using cyclic voltammetry and chronocoulometry. The films show selectivity for Cs in concentrated sodium solutions. Raman spectroscopy was used to monitor changes in oxidation state of the film and imaging experiments have demonstrated that the redox reactions are spatially homogenous across the film. Requirements for a bench scale unit were identified.

Lilga, M.A.; Orth, R.J.; Sukamto, J.P.H. [Pacific Northwest National Lab., Richland, WA (United States); Schwartz, D.T.; Haight, S.M. [Washington Univ., Seattle, WA (United States); Genders, D. [Electrosynthesis Co., Inc., Cheektowaga, NY (United States)

1996-12-01T23:59:59.000Z

43

Evaluation of Ion Exchange Materials in K Basin Floor Sludge and Potential Solvents for PCB Extraction from Ion Exchange Materials  

SciTech Connect (OSTI)

Approximately 73 m{sup 3} of heterogeneous solid material, ''sludge,'' (upper bound estimate, Packer 1997) have accumulated at the bottom of the K Basins in the 100 K Area of the Hanford Site. This sludge is a mixture of spent fuel element corrosion products, ion exchange materials (organic and inorganic), graphite-based gasket materials, iron and aluminum metal corrosion products, sand, and debris (Makenas et al. 1996, 1997). In addition, small amounts of polychlorinated biphenyls (PCBs) have been found. These small amounts are significant from a regulatory standpoint. Ultimately, it is planned to transfer the K Basins sludge to the Hanford double shell tanks (DSTs). Chemical pretreatment is required to address criticality issues and the destruction or removal of PCBs before the K Basin sludge can be transferred to the DSTs. Eleven technologies have been evaluated (Papp 1997) as potential pretreatment methods. Based on the evaluations and engineering studies and limited testing, Fluor Daniel Hanford recommended solvent washing of the K Basin sludge, followed by nitric acid dissolution and, potentially, peroxide addition (FDH 1997). The solvent washing (extraction) and peroxide addition would be used to facilitate PCB removal and destruction. Following solvent extraction, the PCBs could be distilled and concentrated for disposal as a low-level waste. The purpose of the work reported here was to continue investigating solvent extraction, first by better identifying the ion exchange materials in the actual sludge samples and then evaluating various solvents for removing the PCBs or possibly dissolving the resins. This report documents some of the process knowledge on ion exchange materials used and spilled in the K Basins and describes the materials identified from wet sieving KE Basin floor and canister sludge and the results of other analyses. Several photographs are included to compare materials and illustrate material behavior. A summary of previous tests on solvent extraction of PCB surrogates from simulant K Basin sludge is also given.

Schmidt, A.J.; Klinger, G.S.; Bredt, P.R.

1999-04-10T23:59:59.000Z

44

REAL WASTE TESTING OF SPHERICAL RESORCINOL-FORMALDEHYDE ION EXCHANGE RESIN  

SciTech Connect (OSTI)

This report presents data on batch contact and column testing tasks for spherical resorcinol-formaldehyde (sRF) resin. The testing used a non-radioactive simulant of SRS Tank 2F dissolved salt, as well as an actual radioactive waste sample of similar composition, which are both notably high in sodium (6 M). The resin was Microbeads batch 5E-370/641 which had been made on the hundred gallon scale. Equilibrium batch contact work focused on cesium at a temperature of 25 C due to the lack of such data to better benchmark existing isotherm models. Two campaigns were performed with small-scale ion exchange columns, first with Tank 2F simulant, then with actual dissolved salt in the Shielded Cells. An extrapolation of the batch contact results with radioactive waste over-predicted the cesium loaded onto the IX sRF resin bed by approximately 11%. This difference is not unexpected considering uncertainties from measurement and extrapolation and because the ion exchange that occurs when waste flows through a resin bed probably cannot reach the same level of equilibrium as when waste and resin are joined in a long term batch contact. Resin was also characterized to better understand basic chemistry issues such as holdup of trace transition metals present in the waste feed streams. The column tests involved using two beds of sRF resin in series, with the first bed referred to as the Lead column and the second bed as the Lag column. The test matrix included two complete IX cycles for both the simulant and actual waste phases. A cycle involves cesium adsorption, until the resin in the Lead column reaches saturation, and then regenerating the sRF resin, which includes eluting the cesium. Both the simulated and the actual wastes were treated with two cycles of operation, and the resin beds that were used in the Lead and Lag columns of simulant test phase were regenerated and reused in the actual waste test phase. This task is the first to demonstrate the treatment of SRS waste with sRF resin and the tests clearly demonstrated cesium decontamination for actual waste. The results of the column tests were similar for both the simulated and the actual waste and demonstrated Cs removal with sRF from both wastes. For a flowrate of 1.4 bed volumes (BV)/hour at 25 C those results with sRF resin were: (1) Simulant and actual waste results are equivalent; (2) Cs breakthrough began between 200 and 250 BV; (3) Cs breakthrough reached 100% at around 400 BV; (4) Cs breakthrough curve from 5% to 100% is approximately linear; (5) Cs elution with 0.5 M HNO3 starts at 2 BV and ends at 6BV; (6) Most, if not all, of Cs adsorbed during treatment is released during elution; (7) At 100% breakthrough of Cs the resin bed adsorbs approximately 85% of full capacity before detection in the effluent; the remaining 15% is adsorbed at saturation; (8) Approximately 90% of resin bed changes (color and volume) are complete by 6 BV; and (9) During elution the resin shrinks to about 80% of its fully working (sodium form) BV.

Nash, C.; Duignan, M.

2009-10-30T23:59:59.000Z

45

Sodalite ion exchange in polyethylene oxide oligomer solvents Gina M. Canfield,a  

E-Print Network [OSTI]

Sodalite ion exchange in polyethylene oxide oligomer solvents Gina M. Canfield,a Michael Bizimisb and rare earth ions. Ethylene oxide-based oligomers (polyethylene glycol, polyethylene glycol methyl ether

Latturner, Susan

46

Small Column Ion Exchange Design and Safety Strategy  

SciTech Connect (OSTI)

Small Column Ion Exchange (SCIX) is a transformational technology originally developed by the Department of Energy (DOE) Environmental Management (EM-30) office and is now being deployed at the Savannah River Site (SRS) to significantly increase overall salt processing capacity and accelerate the Liquid Waste System life-cycle. The process combines strontium and actinide removal using Monosodium Titanate (MST), Rotary Microfiltration, and cesium removal using Crystalline Silicotitanate (CST, specifically UOP IONSIV{reg_sign}IE-911 ion exchanger) to create a low level waste stream to be disposed in grout and a high level waste stream to be vitrified. The process also includes preparation of the streams for disposal, e.g., grinding of the loaded CST material. These waste processing components are technically mature and flowsheet integration studies are being performed including glass formulations studies, application specific thermal modeling, and mixing studies. The deployment program includes design and fabrication of the Rotary Microfilter (RMF) assembly, ion-exchange columns (IXCs), and grinder module, utilizing an integrated system safety design approach. The design concept is to install the process inside an existing waste tank, Tank 41H. The process consists of a feed pump with a set of four RMFs, two IXCs, a media grinder, three Submersible Mixer Pumps (SMPs), and all supporting infrastructure including media receipt and preparation facilities. The design addresses MST mixing to achieve the required strontium and actinide removal and to prevent future retrieval problems. CST achieves very high cesium loadings (up to 1,100 curies per gallon (Ci/gal) bed volume). The design addresses the hazards associated with this material including heat management (in column and in-tank), as detailed in the thermal modeling. The CST must be size reduced for compatibility with downstream processes. The design addresses material transport into and out of the grinder and includes provisions for equipment maintenance including remote handling. The design includes a robust set of nuclear safety controls compliant with DOE Standard (STD)-1189, Integration of Safety into the Design Process. The controls cover explosions, spills, boiling, aerosolization, and criticality. Natural Phenomena Hazards (NPH) including seismic event, tornado/high wind, and wildland fire are considered. In addition, the SCIX process equipment was evaluated for impact to existing facility safety equipment including the waste tank itself. SCIX is an innovative program which leverages DOE's technology development capabilities to provide a basis for a successful field deployment.

Huff, T.; Rios-Armstrong, M.; Edwards, R.; Herman, D.

2011-02-07T23:59:59.000Z

47

Development of an spFRET method to measure structure changes in ion exchange proteins  

E-Print Network [OSTI]

transporter, major facilitator superfamily, membrane transport, membrane transporter, OxlT, single molecule, spFRET, transport protein. Tightly coupled ion exchangers, such as the AE anion exchange systems only take place at an appreciable rate if a suitable substrate ion is bound to the transport site

Novotny, Lukas

48

Ion-exchange selectivities of periderm and cuticular membranes toward alkali cations  

SciTech Connect (OSTI)

The ion-exchange selectivities of lithium, sodium, potassium, and cesium on isolated potato periderm (Solanum tuberosum) and pear fruit cuticular membranes were investigated; the general order of preference both for cation selectivities and ion-exchange capacities was lithium > sodium > potassium > cesium. The potato periderm and pear fruit cuticular membranes exhibited a behavior typical of ion-exchange resins of the weak acid type. At constant pH 7, the ion-exchange capacities of periderm and cuticular membranes increased with hydrated ionic radius, and also with increasing pH and neutral salt concentration, and decreased with crystal ionic radius. Counterion selectivities also exhibited the same behavior. The ion-exchange properties are discussed in terms of the structure and function of potato periderm and pear fruit cuticular membranes.

Ersoz, M. [Univ. of Selcuk, Konya (Turkey); Duncan, H.J. [Univ. of Glasgow, Scotland (United Kingdom)

1994-08-01T23:59:59.000Z

49

Revised Thermal Analysis of LANL Ion Exchange Column  

SciTech Connect (OSTI)

This document updates a previous calculation of the temperature distributions in a Los Alamos National Laboratory (LANL) ion exchange column.1 LANL operates two laboratory-scale anion exchange columns, in series, to extract Pu-238 from nitric acid solutions. The Defense Nuclear Facilities Safety Board has requested an updated analysis to calculate maximum temperatures for higher resin loading capacities obtained with a new formulation of the Reillex HPQ anion exchange resin. The increased resin loading capacity will not exceed 118 g plutonium per L of resin bed. Calculations were requested for normal operation of the resin bed at the minimum allowable solution feed rate of 30 mL/min and after an interruption of flow at the end of the feed stage, when one of the columns is fully loaded. The object of the analysis is to demonstrate that the decay heat from the Pu-238 will not cause resin bed temperatures to increase to a level where the resin significantly degrades. At low temperatures, resin bed temperatures increase primarily due to decay heat. At {approx}70 C a Low Temperature Exotherm (LTE) resulting from the reaction between 8-12 M HNO{sub 3} and the resin has been observed. The LTE has been attributed to an irreversible oxidation of pendant ethyl benzene groups at the termini of the resin polymer chains by nitric acid. The ethyl benzene groups are converted to benzoic acid moities. The resin can be treated to permanently remove the LTE by heating a resin suspension in 8M HNO{sub 3} for 30-45 minutes. No degradation of the resin performance is observed after the LTE removal treatment. In fact, heating the resin in boiling ({approx}115-120 C) 12 M HNO{sub 3} for 3 hr displays thermal stability analogous to resin that has been treated to remove the LTE. The analysis is based on a previous study of the SRS Frames Waste Recovery (FWR) column, performed in support of the Pu-238 production campaign for NASA's Cassini mission. In that study, temperature transients following an interruption of flow to the column were calculated. The transient calculations were terminated after the maximum resin bed temperature reached the Technical Standard of 60 C, which was set to prevent significant resin degradation. The LANL column differs from the FWR column in that it has a significantly smaller radius, 3.73 cm nominal versus approximately 28 cm. It follows that natural convection removes heat much more effectively from the LANL column, so that the column may reach thermal equilibrium. Consequently, the calculations for a flow interruption were extended until an approach to thermal equilibrium was observed. The LANL ion exchange process also uses a different resin than was used in the FWR column. The LANL column uses Reillex HPQ{trademark} resin, which is more resistant to attack by nitric acid than the Ionac 641{trademark} resin used in the FWR column. Heat generation from the resin oxidation reaction with nitric acid is neglected in this analysis since LANL will be treating the resin to remove the LTE prior to loading the resin in the columns. Calculations were performed using a finite difference computer code, which incorporates models for absorption and elution of plutonium and for forced and natural convection within the resin bed. Calculations for normal column operation during loading were performed using an initial temperature and a feed temperature equal to the ambient air temperature. The model for the normal flow calculations did not include natural convection within the resin bed. The no flow calculations were started with the temperature and concentration profiles at the end of the loading stage, when there would be a maximum amount of plutonium either adsorbed on the resin or in the feed solution in the column.

Laurinat, J

2006-04-11T23:59:59.000Z

50

THERMAL MODELING OF ION EXCHANGE COLUMNS WITH SPHERICAL RF RESIN  

SciTech Connect (OSTI)

Models have been developed to simulate the thermal performance of RF columns fully loaded with radioactive cesium. Temperature distributions and maximum temperatures across the column were calculated during Small Column Ion Exchange (SCIX) process upset conditions with a focus on implementation at Hanford. A two-dimensional computational modeling approach was taken to include conservative, bounding estimates for key parameters such that the results will provide the maximum centerline temperatures achievable under the design configurations using a feed composition known to promote high cesium loading on RF. The current full-scale design for the SCIX system includes a central cooling tube, and one objective of these calculations was to examine its elimination to simplify the design. Results confirmed that a column design without a central cooling tube is feasible for RF, allowing for the possibility of significant design simplifications if it can be assumed that the columns are always filled with liquid. With active cooling through the four outer tubes, the maximum column diameter expected to maintain the temperature below the assumed media and safety limits is 26 inches, which is comparable to the current design diameter. Additional analysis was conducted to predict the maximum column temperatures for the previously unevaluated accident scenario involving inadvertent drainage of liquid from a cesium-saturated column, with retention of the ion exchange media and cesium in the column. As expected, much higher maximum temperatures are observed in this case due to the poor heat transfer properties of air versus liquid. For this hypothetical accident scenario involving inadvertent and complete drainage of liquid from a cesium-saturated column, the modeling results indicate that the maximum temperature within a 28 inch diameter RF column with external cooling is expected to exceed 250 C within 2 days, while the maximum temperature of a 12 inch column is maintained below 100 C. In addition, the calculation results demonstrate that the cooling tube system external to an air-filled column is not highly effective at reducing the maximum temperature, but the baseline design using a central cooling tube inside the column provides sufficient cooling to maintain the maximum temperature near the assumed safety limit.

Lee, S.; King, W.

2009-12-30T23:59:59.000Z

51

Determination of Method Detection Limits for Trace 232-Thorium and 238-Uranium in Copper using Ion Exchange and ICPMS  

SciTech Connect (OSTI)

Determination of Method Detection Limits for Trace 232-Thorium and 238-Uranium in Copper using Ion Exchange and ICPMS

Hoppe, Eric W.; LaFerriere, Brian D.; Maiti, Tapas C.; Soin, Aleksandr

2014-04-15T23:59:59.000Z

52

Journal of Membrane Science 239 (2004) 1726 Highly conductive ordered heterogeneous ion-exchange membranes  

E-Print Network [OSTI]

in the matrix required for reasonable ion transport through the membrane is 50­70 wt.% [2Journal of Membrane Science 239 (2004) 17­26 Highly conductive ordered heterogeneous ion-exchange membranes are used in electrodialysis (ED) as ion-selective membranes and in power sources (such as fuel

Freger, Viatcheslav "Slava"

53

anionic ion exchangers: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

ions and water flow under the influence of gradients in hydrostatic pressure, ion chemical potential, and electrical potential (voltage), leading to solvent flow, ionic fluxes...

54

Experimental Findings On Minor Actinide And Lanthanide Separations Using Ion Exchange  

SciTech Connect (OSTI)

This project seeks to determine if inorganic or hybrid inorganic ion-exchange materials can be exploited to provide effective americium and curium separations. Specifically, we seek to understand the fundamental structural and chemical factors responsible for the selectivity of the tested ion-exchange materials for actinide and lanthanide ions. During FY13, experimental work focused in the following areas: (1) investigating methods to oxidize americium in dilute nitric acid with subsequent ion-exchange performance measurements of ion exchangers with the oxidized americium and (2) synthesis, characterization and testing of ion-exchange materials. Ion-exchange materials tested included alkali titanates, alkali titanosilicates, carbon nanotubes and group(IV) metal phosphonates. Americium oxidation testing sought to determine the influence that other redox active components may have on the oxidation of Am(III). Experimental findings indicated that Pu(IV) is oxidized to Pu(VI) by peroxydisulfate, but there are no indications that the presence of plutonium affects the rate or extent of americium oxidation at the concentrations of peroxydisulfate being used. Tests also explored the influence of nitrite on the oxidation of Am(III). Given the formation of Am(V) and Am(VI) in the presence of nitrite, it appears that nitrite is not a strong deterrent to the oxidation of Am(III), but may be limiting Am(VI) by quickly reducing Am(VI) to Am(V). Interestingly, additional absorbance peaks were observed in the UV-Vis spectra at 524 and 544 nm in both nitric acid and perchloric acid solutions when the peroxydisulfate was added as a solution. These peaks have not been previously observed and do not correspond to the expected peak locations for oxidized americium in solution. Additional studies are in progress to identify these unknown peaks. Three titanosilicate ion exchangers were synthesized using a microwave-accelerated reaction system (MARS?) and determined to have high affinities for lanthanide ions in dilute nitric acid. The K-TSP ion exchanger exhibited the highest affinity for lanthanides in dilute nitric acid solutions. The Ge-TSP ion exchanger shows promise as a material with high affinity, but additional tests are needed to confirm the preliminary results. On the other hand, carbon nanotubes and nitrogen-doped carbon nanotubes exhibited low, but measureable affinities for lanthanide ions in dilute nitric acid solutions (pH 3 and 6). The MWCNT exhibited much lower affinities than the K-TSP in dilute nitric acid solutions. However, the MWCNT are much more chemically stable in concentrated nitric acid solutions and, therefore, may be candidates for ion exchange in more concentrated nitric acid solutions.

Hobbs, D. T.; Shehee, T. C.; Clearfield, A.

2013-09-17T23:59:59.000Z

55

MODELING AN ION EXCHANGE PROCESS FOR CESIUM REMOVAL FROM ALKALINE RADIOACTIVE WASTE SOLUTIONS  

SciTech Connect (OSTI)

The performance of spherical Resorcinol-Formaldehyde ion-exchange resin for the removal of cesium from alkaline radioactive waste solutions has been investigated through computer modeling. Cesium adsorption isotherms were obtained by fitting experimental data using a thermodynamic framework. Results show that ion-exchange is an efficient method for cesium removal from highly alkaline radioactive waste solutions. On average, two 1300 liter columns operating in series are able to treat 690,000 liters of waste with an initial cesium concentration of 0.09 mM in 11 days achieving a decontamination factor of over 50,000. The study also tested the sensitivity of ion-exchange column performance to variations in flow rate, temperature and column dimensions. Modeling results can be used to optimize design of the ion exchange system.

Smith, F; Luther Hamm, L; Sebastian Aleman, S; Johnston Michael, J

2008-08-26T23:59:59.000Z

56

Ion exchange kinetics of cesium for various reaction designs using crystalline silicotitanate, UOP IONSIV IE-911  

E-Print Network [OSTI]

, the major component of CST, slowly dissolved at hydrogen peroxide concentrations greater than 1 M. A simple and novel experimental apparatus for a single-layer ion exchange column was developed to generate experimental data for estimation...

Kim, Sung Hyun

2004-09-30T23:59:59.000Z

57

E-Print Network 3.0 - alkali ion exchange Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Search Sample search results for: alkali ion exchange Page: << < 1 2 3 4 5 > >> 1 Corrosion mechanisms of low level vitrified radioactive waste in a loamy soil M.I. Ojovan1...

58

Experimental Ion Exchange Column With SuperLig 639 And Simulant Formulation  

SciTech Connect (OSTI)

SuperLig®639 ion exchange resin was tested as a retrieval mechanism for pertechnetate, through decontamination of a perrhenate spiked 5M Simple Average Na{sup +} Mass Based Simulant. Testing included batch contacts and a three-column ion exchange campaign. A decontamination of perrhenate exceeding 99% from the liquid feed was demonstrated. Analysis of the first formulation of a SBS/WESP simulant found unexpectedly low concentrations of soluble aluminum. Follow-on work will complete the formulation.

Morse, Megan; Nash, C.

2013-08-26T23:59:59.000Z

59

Assessment of commercially available ion exchange materials for cesium removal from highly alkaline wastes  

SciTech Connect (OSTI)

Approximately 61 million gallons of nuclear waste generated in plutonium production, radionuclide removal campaigns, and research and development activities is stored on the Department of Energy`s Hanford Site, near Richland, Washington. Although the pretreatment process and disposal requirements are still being defined, most pretreatment scenarios include removal of cesium from the aqueous streams. In many cases, after cesium is removed, the dissolved salt cakes and supernates can be disposed of as LLW. Ion exchange has been a leading candidate for this separation. Ion exchange systems have the advantage of simplicity of equipment and operation and provide many theoretical stages in a small space. The organic ion exchange material Duolite{trademark} CS-100 has been selected as the baseline exchanger for conceptual design of the Initial Pretreatment Module (IPM). Use of CS-100 was chosen because it is considered a conservative, technologically feasible approach. During FY 96, final resin down-selection will occur for IPM Title 1 design. Alternate ion exchange materials for cesium exchange will be considered at that time. The purpose of this report is to conduct a search for commercially available ion exchange materials which could potentially replace CS-100. This report will provide where possible a comparison of these resin in their ability to remove low concentrations of cesium from highly alkaline solutions. Materials which show promise can be studied further, while less encouraging resins can be eliminated from consideration.

Brooks, K.P.; Kim, A.Y.; Kurath, D.E.

1996-04-01T23:59:59.000Z

60

Effects of Ion-Exchange Treatment on Bromate Formation and Oxidation Efficiency during Ozonation  

E-Print Network [OSTI]

water treatment. In this study, we applied several different ion exchangers (i.e., anion exchange resins technologies in advanced drinking water treatment processes along with activated carbon treatment. Ozonation), chlorine-resistant pathogenic organisms, and various micropollutants in drinking water treatment. In Japan

Takada, Shoji

Note: This page contains sample records for the topic "ion exchange ix" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Ion-exchange material and method of storing radioactive wastes  

DOE Patents [OSTI]

A new cation exchanger is a modified tobermorite containing aluminum isomorphously substituted for silicon and containing sodium or potassium. The exchanger is selective for lead, rubidium, cobalt, and cadmium and is selective for cesium over calcium or sodium. The tobermorites are compatible with cement and are useful for the long-term fixation and storage of radioactive nuclear wastes.

Komarneni, S.; Roy, D.M.

1983-10-31T23:59:59.000Z

62

Quantifying exchange coupling in f-ion pairs using the diamagnetic substitution method  

SciTech Connect (OSTI)

One of the challenges in the chemistry of actinide and lanthanide (f-ion) is quantifying exchange coupling between f-ions. While qualitative information about exchange coupling may be readily obtained using the diamagnetic substitution approach, obtaining quantitative information is much more difficult. This article describes how exchange coupling may be quantified using the susceptibility of a magnetically isolated analog, as in the diamagnetic substitution approach, along with the anisotropy of the ground state as determined by EPR spectroscopy. Several examples are used to illustrate and test this approach.

Lukens, Wayne W.; Walter, Marc D.

2010-04-01T23:59:59.000Z

63

Decontamination of water using nitrate selective ion exchange resin  

DOE Patents [OSTI]

A method for nitrate decontamination of water which involves passing the water through a bed of alkyl phosphonium anion exchange resin which has pendant alkyl groups of C[sub 3] or larger.

Lockridge, J.E.; Fritz, J.S.

1990-07-31T23:59:59.000Z

64

Radiolytic effects on ion exchangers during the storage of radioactive wastes  

SciTech Connect (OSTI)

Radiolytic effects on ion exchangers are being recognized as a significant problem in the processing and storage of high-specific-activity radioactive waste forms. Two major literature surveys and a series of scoping experiments conducted during this investigation indicate that radiation decomposition of ion exchange materials has the potential for a variety of undesirable consequences. These include the ready dispersion of adsorbed radionuclides to the environment, corrosion and pressurization of waste canisters, and generation of flammable and explosive gases, as well as agglomeration of ion exchangers to a rigid monolith with the partitioning of a liquid phase. Some of the highlights of the literature surveys and the major findings of the experimental studies are reported here.

Pillay, K.K.S.; Palau, G.L.

1982-01-01T23:59:59.000Z

65

A kinetic model for ion exchange between cesium and sodium using silico-titanates  

E-Print Network [OSTI]

over this entire range of pH. This unique characteristic makes the TAMS material desirable. Two other available organic ion exchangers (carboxylic acid based resin and resorcinol formaldehyde resin) show some capability for cesium removal; however... et al. (1947) used this method successfully to predict their data with the phenol-formaldehyde resinous exchanger, Amberlite IR-1. Similarly, Nachod and Wood (1944) and Turse and Rieman (1961) found their data fitted quite well on both zeolites...

Nguyen, Luan Thanh

1994-01-01T23:59:59.000Z

66

Ligand-exchange chromatography of aromatic amines on resin-bound cobalt ion  

SciTech Connect (OSTI)

The use of cobalt metal for the selective separation of aromatic amines is completed with a chemically bonded diamine and glyoxime functional groups onto Lycopodium clavatum. Oximes and amines are excellent complexing agents for transition metal ions. Cobalt(II) metal ions can easily be immobilized on bis-diaminoethyl-glyoximated sporopollenin (bDAEG-sporopollenin). The ligand-exchange behavior of modified Lycopodium clavatum with respect to aromatic amines was investigated. This will permit the evaluation of bDAEG-sporopollenin ligand exchangers for their utilization as sorbents in the recovery, pollution control, and elimination of amines from wastewater.

Pehlivan, E.; Vural, U.S.; Ayar, A.; Yildiz, S. [Selcuk Univ., Konya (Turkey)

1996-06-01T23:59:59.000Z

67

RESORCINOL-FORMALDEHYDE ION EXCHANGE RESIN CHEMISTRY FOR HIGH LEVEL WASTE TREATMENT  

SciTech Connect (OSTI)

A principal goal at the Savannah River Site is to safely dispose of the large volume of liquid nuclear waste held in many storage tanks. In-tank ion exchange technology is being considered for cesium removal using a polymer resin made of resorcinol formaldehyde that has been engineered into microspheres. The waste under study is generally lower in potassium and organic components than Hanford waste; therefore, the resin performance was evaluated with actual dissolved salt waste. The ion exchange performance and resin chemistry results are discussed.

Nash, C.; Duignan, M.

2010-01-14T23:59:59.000Z

68

Nuclear quantum effects in water exchange around lithium and fluoride ions  

E-Print Network [OSTI]

We employ classical and ring polymer molecular dynamics simulations to study the effect of nuclear quantum fluctuations on the structure and the water exchange dynamics of aqueous solutions of lithium and fluoride ions. While we obtain reasonably good agreement with experimental data for solutions of lithium by augmenting the Coulombic interactions between the ion and the water molecules with a standard Lennard-Jones ion-oxygen potential, the same is not true for solutions of fluoride, for which we find that a potential with a softer repulsive wall gives much better agreement. A small degree of destabilization of the first hydration shell is found in quantum simulations of both ions when compared with classical simulations, with the shell becoming less sharply defined and the mean residence time of the water molecules in the shell decreasing. In line with these modest differences, we find that the mechanisms of the exchange processes are unaffected by quantization, so a classical description of these reaction...

Wilkins, David M; Dang, Liem X

2015-01-01T23:59:59.000Z

69

Patterned ion exchange membranes for improved power production in microbial reverse-electrodialysis cells  

E-Print Network [OSTI]

Patterned ion exchange membranes for improved power production in microbial reverse-electrodialysis August 2014 Keywords: Microbial reverse electrodialysis cell Patterned membranes Integrated spacer Internal resistance a b s t r a c t Power production in microbial reverse-electrodialysis cells (MRCs) can

70

Removing Radium-226 Contamination From Ion Exchange Resins Used in Drinking Water Treatment  

E-Print Network [OSTI]

Removing Radium-226 Contamination From Ion Exchange Resins Used in Drinking Water Treatment P r o b of groundwater containing high levels of radium-226 activity (Objective 1) were regenerated with prescribed brine that the concentration of salt in the brine cleaning solution was the most influential factor in the resin regeneration

71

HIGH ASPECT RATIO ION EXCHANGE RESIN BED - HYDRAULIC RESULTS FOR SPERICAL RESIN BEADS  

SciTech Connect (OSTI)

A principal role of the DOE Savannah River Site is to safely dispose of a large volume of liquid nuclear waste held in many storage tanks. An in-tank ion exchange unit is being considered for cesium removal to accelerate waste processing. This unit is planned to have a relatively high bed height to diameter ratio (10:1). Complicating the design is the need to cool the ion exchange media; therefore, the ion exchange column will have a central cooling core making the flow path annular. To separate cesium from waste the media being considered is made of resorcinol formaldehyde resin deposited on spherical plastic beads and is a substitute for a previously tested resin made of crystalline silicotitanate. This spherical media not only has an advantage of being mechanically robust, but, unlike its predecessor, it is also reusable, that is, loaded cesium can be removed through elution and regeneration. Resin regeneration leads to more efficient operation and less spent resin waste, but its hydraulic performance in the planned ion exchange column was unknown. Moreover, the recycling process of this spherical resorcinol formaldehyde causes its volume to significantly shrink and swell. To determine the spherical media's hydraulic demand a linearly scaled column was designed and tested. The waste simulant used was prototypic of the wastes' viscosity and density. This paper discusses the hydraulic performance of the media that will be used to assist in the design of a full-scale unit.

Duignan, M; Charles Nash, C; Timothy Punch, T

2007-09-27T23:59:59.000Z

72

A new class of non-zeolitic sorbents for air separations: Lithium ion exchanged pillared clays  

SciTech Connect (OSTI)

Zeolites are the only known sorbents that adsorb N{sub 2} selectively over O{sub 2}, and are used for industrial air separation. Pillared clays (PILCs) have a high Broensted acidity (k.e., high proton density). It is found in this study that when the protons are exchanged by alkali metal ions, in particular Li{sup +}, the ion exchanged pillared clays can exhibit a high N{sub 2}/O{sub 2} adsorption selectivity that rivals that of the zeolites. The first result shows a pure-component adsorption ratio of N{sub 2}/O{sub 2} = 3.2 (at 25 C and 1 atm) for Li{sup +}-exchanged PILC. The N{sub 2} capacity, however, is only 20% that of the zeolite, and remains to be improved. A systematic investigation is conducted on the effects of three factors on the N{sub 2}/O{sub 2} selectivity: (1) starting clays (tetrahedral vs octahedral isomorphous substitution and clays with different charge densities), (2) different metal oxides as pillars, and (3) different ion exchange alkali metal cations (Li{sup +}, Na{sup +}, K{sup +}, Rb{sup +}, and Cs{sup +}). The highest N{sub 2}/O{sub 2} selectivities are achieved by using clays with the highest charge densities, metal oxides forming pillars with the narrowest gallery spaces, and ion exchange cations with the smallest ionic radii. Effects by all three factors are qualitatively understood. The high N{sub 2}/O{sub 2} selectivity on the Li{sup +} exchanged PILC is the result of the small ionic radius (and hence high polarizing power) of Li{sup +} and the strong quadrupole moment of the N{sub 2} molecule. Moreover, a technique is developed with which the amount of the exchanged cations can exceed that allowed by the original cation exchange capacity of the clay by using a high pH value in the ion exchange solution.

Cheng, L.S.; Yang, R.T. [State Univ. of New York, Buffalo, NY (United States). Dept. of Chemical Engineering

1995-06-01T23:59:59.000Z

73

Chaotic behavior of ion exchange phenomena in polymer gel electrolytes through irradiated polymeric membrane  

E-Print Network [OSTI]

A desktop experiment has been done to show the nonlinearity in the I-V characteristics of an ion conducting electrochemical micro-system. Its chaotic dynamics is being reported for the first time which has been captured by an electronic circuit. Polyvinylidene fluoride-co-hexafluoropropene (PVdF-HFP) gel electrolyte comprising of a combination of plasticizers (ethylene carbonate and propylene carbonate) and salts have been prepared to study the exchange of ions through porous poly ethylene terephthalate (PET) membranes. The nonlinearity of this system is due to the ion exchange of the polymer gel electrolytes (PGEs) through a porous membrane. The different regimes of spiking and non-spiking chaotic motions are being presented. The possible applications are highlighted.

Sangeeta Rawat; Barnamala Saha; Awadhesh Prasad; Amita Chandra

2012-04-18T23:59:59.000Z

74

SPACE RESOURCES ROUNDTABLE IX  

E-Print Network [OSTI]

SPACE RESOURCES ROUNDTABLE IX Colorado School of Mines October 25-27, 2007 http://www.ISRUinfo.com Sponsored by: Colorado School of Mines Lunar and Planetary Institute Space Resources Roundtable, Inc. First Space Michael B. Duke, Colorado School of Mines Leslie Gertsch, University of Missouri-Rolla Alex

Rathbun, Julie A.

75

Modelling Mixed Bed Ion Exchange Kinetics for Removal of Trace Levels of Divalent Cations in Ultrapure Water  

SciTech Connect (OSTI)

Ion exchanger resin fluid film mass transfer coefficients and the ionic diffusivities from which they are derived are often measured by use of ion exchange resin columns. Such tests, usually run dynamically using short resin beds, are often performed using relatively high (ppm) concentrations of ions to accurately measure output concentrations as a function of flow rate. The testing described herein was performed to determine fluid film ionic diffusivities for cationic concentrations typical of ultrapure water ({le}ppb levels) containing ppm levels of ammonia. Effective ionic diffusivities at these low ionic concentrations and high pHs were needed to complete a computer model (SIMIX) to be used in ion exchange simulations. SIMIX is a generalized multicomponent ion exchange model designed to simulate the removal of divalent cations from ultrapure water.

B. Widman

2003-01-01T23:59:59.000Z

76

LITERATURE REVIEWS TO SUPPORT ION EXCHANGE TECHNOLOGY SELECTION FOR MODULAR SALT PROCESSING  

SciTech Connect (OSTI)

This report summarizes the results of literature reviews conducted to support the selection of a cesium removal technology for application in a small column ion exchange (SCIX) unit supported within a high level waste tank. SCIX is being considered as a technology for the treatment of radioactive salt solutions in order to accelerate closure of waste tanks at the Savannah River Site (SRS) as part of the Modular Salt Processing (MSP) technology development program. Two ion exchange materials, spherical Resorcinol-Formaldehyde (RF) and engineered Crystalline Silicotitanate (CST), are being considered for use within the SCIX unit. Both ion exchange materials have been studied extensively and are known to have high affinities for cesium ions in caustic tank waste supernates. RF is an elutable organic resin and CST is a non-elutable inorganic material. Waste treatment processes developed for the two technologies will differ with regard to solutions processed, secondary waste streams generated, optimum column size, and waste throughput. Pertinent references, anticipated processing sequences for utilization in waste treatment, gaps in the available data, and technical comparisons will be provided for the two ion exchange materials to assist in technology selection for SCIX. The engineered, granular form of CST (UOP IE-911) was the baseline ion exchange material used for the initial development and design of the SRS SCIX process (McCabe, 2005). To date, in-tank SCIX has not been implemented for treatment of radioactive waste solutions at SRS. Since initial development and consideration of SCIX for SRS waste treatment an alternative technology has been developed as part of the River Protection Project Waste Treatment Plant (RPP-WTP) Research and Technology program (Thorson, 2006). Spherical RF resin is the baseline media for cesium removal in the RPP-WTP, which was designed for the treatment of radioactive waste supernates and is currently under construction in Hanford, WA. Application of RF for cesium removal in the Hanford WTP does not involve in-riser columns but does utilize the resin in large scale column configurations in a waste treatment facility. The basic conceptual design for SCIX involves the dissolution of saltcake in SRS Tanks 1-3 to give approximately 6 M sodium solutions and the treatment of these solutions for cesium removal using one or two columns supported within a high level waste tank. Prior to ion exchange treatment, the solutions will be filtered for removal of entrained solids. In addition to Tanks 1-3, solutions in two other tanks (37 and 41) will require treatment for cesium removal in the SCIX unit. The previous SCIX design (McCabe, 2005) utilized CST for cesium removal with downflow supernate processing and included a CST grinder following cesium loading. Grinding of CST was necessary to make the cesium-loaded material suitable for vitrification in the SRS Defense Waste Processing Facility (DWPF). Because RF resin is elutable (and reusable) and processing requires conversion between sodium and hydrogen forms using caustic and acidic solutions more liquid processing steps are involved. The WTP baseline process involves a series of caustic and acidic solutions (downflow processing) with water washes between pH transitions across neutral. In addition, due to resin swelling during conversion from hydrogen to sodium form an upflow caustic regeneration step is required. Presumably, one of these basic processes (or some variation) will be utilized for MSP for the appropriate ion exchange technology selected. CST processing involves two primary waste products: loaded CST and decontaminated salt solution (DSS). RF processing involves three primary waste products: spent RF resin, DSS, and acidic cesium eluate, although the resin is reusable and typically does not require replacement until completion of multiple treatment cycles. CST processing requires grinding of the ion exchange media, handling of solids with high cesium loading, and handling of liquid wash and conditioning solutions. RF processing requires h

King, W

2007-11-30T23:59:59.000Z

77

Charge-exchange recombination spectroscopy of the plasma ion temperature at the T-10 tokamak  

SciTech Connect (OSTI)

Charge-exchange recombination spectroscopy (CXRS) based on a diagnostic neutral beam has been developed at the T-10 tokamak. The diagnostics allows one to measure the ion temperature profile in the cross section of the plasma column. In T-10 experiments, the measurement technique was adjusted and the elements of the CXRS diagnostics for ITER were tested. The used spectroscopic equipment makes it possible to reliably determine the ion temperature from the Doppler broadening of impurity lines (helium, carbon), as well as of the spectral lines of the working gas. The profiles of the plasma ion temperature in deuterium and helium discharges were measured at different plasma currents and densities, including with the use of active Doppler measurements of lines of different elements. The validity and reliability of ion temperature measurements performed by means of the developed CXRS diagnostics are analyzed.

Krupin, V. A., E-mail: vkrupin@nfi.kiae.ru [National Research Centre Kurchatov Institute (Russian Federation); Tugarinov, S. N. [Project Center ITER (Russian Federation)] [Project Center ITER (Russian Federation); Barsukov, A. G.; Dnestrovskij, A. Yu.; Klyuchnikov, L. A.; Korobov, K. V.; Krasnyanskii, S. A. [National Research Centre Kurchatov Institute (Russian Federation)] [National Research Centre Kurchatov Institute (Russian Federation); Naumenko, N. N. [National Academy of Sciences of Belarus, Stepanov Institute of Physics (Belarus)] [National Academy of Sciences of Belarus, Stepanov Institute of Physics (Belarus); Nemets, A. R.; Sushkov, A. V.; Tilinin, G. N. [National Research Centre Kurchatov Institute (Russian Federation)] [National Research Centre Kurchatov Institute (Russian Federation)

2013-08-15T23:59:59.000Z

78

Disease-associated changes in the expression of ion channels, ion receptors, ion exchangers and Ca{sup 2+}-handling proteins in heart hypertrophy  

SciTech Connect (OSTI)

The molecular pathology of cardiac hypertrophy is multifactorial with transcript regulation of ion channels, ion exchangers and Ca{sup 2+}-handling proteins being speculative. We therefore investigated disease-associated changes in gene expression of various ion channels and their receptors as well as ion exchangers, cytoskeletal proteins and Ca{sup 2+}-handling proteins in normotensive and spontaneously hypertensive (SHR) rats. We also compared experimental findings with results from hypertrophic human hearts, previously published (Borlak, J., and Thum, T., 2003. Hallmarks of ion channel gene expression in end-stage heart failure. FASEB J. 17, 1592-1608). We observed significant (P < 0.05) induction in transcript level of ATP-driven ion exchangers (Atp1A1, NCX-1, SERCA2a), ion channels (L-type Ca{sup 2+}-channel, K{sub ir}3.4, Na{sub v}1.5) and RyR-2 in hypertrophic hearts, while gene expression was repressed in diseased human hearts. Further, the genes coding for calreticulin and calmodulin, PMCA 1 and 4 as well as {alpha}-skeletal actin were significantly (P < 0.05) changed in hypertrophic human heart, but were unchanged in hypertrophic left ventricles of the rat heart. Notably, transcript level of {alpha}- and {beta}-MHC, calsequestrin, K{sub ir}6.1 (in the right ventricle only), phospholamban as well as troponin T were repressed in both diseased human and rat hearts. Our study enabled an identification of disease-associated candidate genes. Their regulation is likely to be the result of an imbalance between pressure load/stretch force and vascular tonus and the observed changes may provide a rational for the rhythm disturbances observed in patients with cardiac hypertrophy.

Zwadlo, Carolin [Fraunhofer Institute of Toxicology and Experimental Medicine, Center for Drug Research and Medical Biotechnology, Hannover (Germany); Borlak, Juergen [Fraunhofer Institute of Toxicology and Experimental Medicine, Center for Drug Research and Medical Biotechnology, Hannover (Germany)]. E-mail: borlak@item.fraunhofer.de

2005-09-15T23:59:59.000Z

79

Determination of plasma ion velocity distribution via charge-exchange recombination spectroscopy  

SciTech Connect (OSTI)

Spectroscopy of line radiation from plasma impurity ions excited by charge-exchange recombination reactions with energetic neutral beam atoms is rapidly becoming recognized as a powerful technique for measuring ion temperature, bulk plasma motion, impurity transport, and more exotic phenomena such as fast alpha particle distributions. In particular, this diagnostic offers the capability of obtaining space- and time-resolved ion temperature and toroidal plasma rotation profiles with relatively simple optical systems. Cascade-corrected excitation rate coefficients for use in both fully stripped impurity density studies and ion temperature measurements have been calculated to the principal ..delta..n = 1 transitions of He+, C/sup 5 +/, and O/sup 7 +/ with neutral beam energies of 5 to 100 keV/amu. A fiber optically coupled spectrometer system has been used on PDX to measure visible He/sup +/ radiation excited by charge exchange. Central ion temperatures up to 2.4 keV and toroidal rotation speeds up to 1.5 x 10/sup 7/ cm/s were observed in diverted discharges with P/sub INJ/ less than or equal to 3.0 MW.

Fonck, R.J.; Darrow, D.S.; Jaehnig, K.P.

1983-12-01T23:59:59.000Z

80

A photodiode-based neutral particle bolometer for characterizing charge-exchanged fast-ion behavior  

SciTech Connect (OSTI)

A neutral particle bolometer (NPB) has been designed and implemented on Tri Alpha Energy's C-2 device in order to spatially and temporally resolve the charge-exchange losses of fast-ion populations originating from neutral beam injection into field-reversed configuration plasmas. This instrument employs a silicon photodiode as the detection device with an integrated tungsten filter coating to reduce sensitivity to light radiation. Here we discuss the technical aspects and calibration of the NPB, and report typical NPB measurement results of wall recycling effects on fast-ion losses.

Clary, R.; Smirnov, A.; Dettrick, S.; Knapp, K.; Korepanov, S.; Ruskov, E. [Tri Alpha Energy, Inc., Rancho Santa Margarita, California 92688 (United States); Heidbrink, W. W.; Zhu, Y. [University of California-Irvine, Irvine, California 92697 (United States)

2012-10-15T23:59:59.000Z

Note: This page contains sample records for the topic "ion exchange ix" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Counterdiffusion of liquid hydrocarbon pairs in ion-exchanged forms of zeolite X  

SciTech Connect (OSTI)

Adsorptive counterdiffusion rates of liquid benzene, ethyl benzene, 1,3,5-trimethyl benzene, and 1-methyl naphthalene into Na/sup +/, K/sup +/, Cs/sup +/, and Ca/sup 2 +/ ion exchanged forms of zeolite X saturated with cyclohexane were measured. The diffusivity of the adsorbing hydrocarbon decreases as the effective pore size of the zeolite is decreased by ion exchange. The effective pore size in CaX and CsX was so small as not to allow the adsorptive counterdiffusion of 1,3,5-trimethyl benzene and 1-methyl naphthalene. Diffusion took place only after the cations in the pore mouths were displaced to other cation sites in the structure under the influence of the adsorbing hydrocarbon molecules, and thus the rate of counterdiffusion appeared to increase with time.

Culfaz, A.; Erguen, G.

1986-01-01T23:59:59.000Z

82

The characteristic assessment of spent ion exchange resin from PUSPATI TRIGA REACTOR (RTP) for immobilization process  

SciTech Connect (OSTI)

In this paper, spent ion exchange resin generated from PUSPATI TRIGA reactor (RTP) in Malaysian Nuclear Agency were characterized based on the water content, radionuclide content and radionuclide leachability. The result revealed that the water content in the spent resin is 48%. Gamma spectrometry analysis indicated the presence of {sup 134}Cs, {sup 137}Cs, {sup 152}Eu, {sup 54}Mn, {sup 58}Co, {sup 60}Co and {sup 65}Zn. The leachability test shows a small concentrations (<1 Bq/l) of {sup 152}Eu and {sup 134}Cs were leached out from the spent resin while {sup 60}Co activity concentrations slightly exceeded the limit generally used for industrial wastewater i.e. 1 Bq/l. Characterization of spent ion exchange resin sampled from RTP show that this characterization is important as a basis to immobilize this radioactive waste using geopolymer technology.

Wahida, Nurul [School of Applied Physics, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor, Malaysia and Malaysian Nuclear Agency, Bangi 43000 Kajang, Selangor (Malaysia); Yasir, Muhamad Samudi; Majid, Amran Ab; Irwan, M. N. [School of Applied Physics, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor (Malaysia); Wahab, Mohd Abd; Marzukee, Nik; Paulus, Wilfred; Phillip, Esther; Thanaletchumy [Malaysian Nuclear Agency, Bangi 43000 Kajang, Selangor (Malaysia)

2014-09-03T23:59:59.000Z

83

Membrane permeation process for dehydration of organic liquid mixtures using sulfonated ion-exchange polyalkene membranes  

DOE Patents [OSTI]

A membrane permeation process for dehydrating a mixture of organic liquids, such as alcohols or close boiling, heat sensitive mixtures. The process comprises causing a component of the mixture to selectively sorb into one side of sulfonated ion-exchange polyalkene (e.g., polyethylene) membranes and selectively diffuse or flow therethrough, and then desorbing the component into a gas or liquid phase on the other side of the membranes.

Cabasso, Israel (131 Buckingham Ave., Syracuse, NY 13210); Korngold, Emmanuel (P.O. Box 1025, Beer-Sheva 84110, IL)

1988-01-01T23:59:59.000Z

84

Development and properties of crystalline silicotitanate (CST) ion exchangers for radioactive waste applications  

SciTech Connect (OSTI)

Crystalline silicotitanates (CSTs) are a new class of ion exchangers that were jointly invented by researchers at Sandia National Laboratories and Texas A&M University. One particular CST, known as TAM-5, is remarkable for its ability to separate parts-per-million concentrations of cesium from highly alkaline solutions (pH> 14) containing high sodium concentrations (>5M). It is also highly effective for removing cesium from neutral and acidic solutions, and for removing strontium from basic and neutral solutions. Cesium isotopes are fission products that account for a large portion of the radioactivity in waste streams generated during weapons material production. Tests performed at numerous locations with early lab-scale TAM-5 samples established the material as a leading candidate for treating radioactive waste volumes such as those found at the Hanford site in Washington. Thus Sandia developed a Cooperative Research and Development Agreement (CRADA) partnership with UOP, a world leader in developing, commercializing, and supplying adsorbents and associated process technology to commercialize and further develop the material. CSTs are now commercially available from UOP in a powder (UOP IONSIV{reg_sign} IE-910 ion exchanger) and granular form suitable for column ion exchange operations (UOP IONSIV{reg_sign} IE-911 ion exchanger). These materials exhibit a high capacity for cesium in a wide variety of solutions of interest to the Department of Energy, and they are chemically, thermally, and radiation stable. They have performed well in tests at numerous sites with actual radioactive waste solutions, and are being demonstrated in the 100,000 liter Cesium Removal Demonstration taking place at Oak Ridge National Laboratory with Melton Valley Storage Tank waste. It has been estimated that applying CSTs to the Hanford cleanup alone will result in a savings of more than $300 million over baseline technologies.

Miller, J.E.; Brown, N.E.

1997-04-01T23:59:59.000Z

85

Decontamination and dismantlement of the building 594 waste ion exchange facility at Argonne National Laboratory-East project final report.  

SciTech Connect (OSTI)

The Building 594 D&D Project was directed toward the following goals: Removal of any radioactive and hazardous materials associated with the Waste Ion Exchange Facility; Decontamination of the Waste Ion Exchange Facility to unrestricted use levels; Demolition of Building 594; and Documentation of all project activities affecting quality (i.e., waste packaging, instrument calibration, audit results, and personnel exposure) These goals had been set in order to eliminate the radiological and hazardous safety concerns inherent in the Waste Ion Exchange Facility and to allow, upon completion of the project, unescorted and unmonitored access to the area. The ion exchange system and the resin contained in the system were the primary areas of concern, while the condition of the building which housed the system was of secondary concern. ANL-E health physics technicians characterized the Building 594 Waste Ion Exchange Facility in September 1996. The characterization identified a total of three radionuclides present in the Waste Ion Exchange Facility with a total activity of less than 5 {micro}Ci (175 kBq). The radionuclides of concern were Co{sup 60}, Cs{sup 137}, and Am{sup 241}. The highest dose rates observed during the project were associated with the resin in the exchange vessels. DOE Order 5480.2A establishes the maximum whole body exposure for occupational workers at 5 rem (50 mSv)/yr; the administrative limit at ANL-E is 1 rem/yr (10 mSv/yr).

Wiese, E. C.

1998-11-23T23:59:59.000Z

86

IMPACT OF THE SMALL COLUMN ION EXCHANGE PROCESS ON THE DEFENSE WASTE PROCESSING FACILITY - 12112  

SciTech Connect (OSTI)

The Savannah River Site (SRS) is investigating the deployment of a parallel technology to the Salt Waste Processing Facility (SWPF, presently under construction) to accelerate high activity salt waste processing. The proposed technology combines large waste tank strikes of monosodium titanate (MST) to sorb strontium and actinides with two ion exchange columns packed with crystalline silicotitanate (CST) resin to sorb cesium. The new process was designated Small Column Ion Exchange (SCIX), since the ion exchange columns were sized to fit within a waste storage tank riser. Loaded resins are to be combined with high activity sludge waste and fed to the Defense Waste Processing Facility (DWPF) for incorporation into the current glass waste form. Decontaminated salt solution produced by SCIX will be fed to the SRS Saltstone Facility for on-site immobilization as a grout waste form. Determining the potential impact of SCIX resins on DWPF processing was the basis for this study. Accelerated salt waste treatment is projected to produce a significant savings in the overall life cycle cost of waste treatment at SRS.

Koopman, D.; Lambert, D.; Fox, K.; Stone, M.

2011-11-07T23:59:59.000Z

87

A Critical Evaluation on the Use of Kinetics for DeterminingThermodynamicsof Ion Exchange in Soils1  

E-Print Network [OSTI]

Words: dynamicsof ion exchange, kineticmeth- ods, physical chemistry of K, film diffusion. Ogwada, R are they often applicable to field conditions. Agricultural soils are nearly always in a state of nonequilibrium

Sparks, Donald L.

88

Ion exchange columns for selective removal of cesium from aqueous radioactive waste using hydrous crystalline silico-titanates  

E-Print Network [OSTI]

conscious society. In Hanford, WA, hundreds of underground storage tanks hold tens of millions of gallons of aqueous radioactive waste. This liquid waste, which has a very high sodium content, contains trace amounts of radioactive cesium 137. Since... the material for batch ion exchange of the nuclear waste solution. More research was needed to investigate the material's effectiveness in a column operation. An ion exchange column system was developed to study column performance. The column design...

Ricci, David Michael

1995-01-01T23:59:59.000Z

89

Investigation of the ion exchange equilibrium between NA+, Ca++, Mg++, and a sulfonated polystyrene resin at various concentrations  

E-Print Network [OSTI]

INVESTIGATiON OF THE ION EXCHANGE EQUILIBRIUM BETWEEN Na , Ca++, Mg++, AND A SULFONATED POLYSTYRENE RESIN AT VARIOUS CONCENTRATIONS A THESIS BY WILLIAM FRANKLIN McILHENNY Submitted to the Graduate School of the Agricultural and Mechanical... College of Texas in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE January 1958 MaJor Subject: Chemical Engineering INVESTIGATION OF THE ION EXCHANGE EQUILIBRIUM BFTWEEN Na+, Ca++ Mg++ AND A SULFONATED POLYSTYRENE RESIN...

McIlhenny, William Franklin

1958-01-01T23:59:59.000Z

90

Perchlorate Degradation Using Partially Oxidized Titanium Ions and Ion Exchange Membrane Hybrid System  

E-Print Network [OSTI]

. To enhance the overall rate of reaction, high concentrations of acid and Ti(III) are needed, but transport of hydrogen ions through the anion permeable membrane was observed and would be greater at higher acid concentrations. The proposed mathematical model...

Park, Sung Hyuk

2011-08-08T23:59:59.000Z

91

Ix-,,"  

Office of Legacy Management (LM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarlyEnergyDepartment ofDepartment ofof EnergyYou$ EGcG ENERGYELIkNATIONHEALXH: l ._I *r' (Ix-,,"

92

Small Column Ion Exchange at Savannah River Site Technology Readiness Assessment Report  

Energy Savers [EERE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of Inspector GeneralDepartment of Energyof the Americas |DOE FormerEnergySaveP RSmall Column Ion Exchange

93

Modulated active charge exchange fast ion diagnostic for the C-2 field-reversed configuration experiment  

SciTech Connect (OSTI)

A diagnostic technique for measuring the fast-ion energy distribution in a field-reversed configuration plasma was developed and tested on the C-2 experiment. A deuterium neutral beam modulated at 22 kHz is injected into the plasma, producing a localized charge-exchange target for the confined fast protons. The escaping fast neutrals are detected by a neutral particle analyzer. The target beam transverse size ({approx}15 cm) defines the spatial resolution of the method. The equivalent current density of the target beam is {<=}0.15 A/cm{sup 2}, which corresponds to a neutral density ({approx}6 Multiplication-Sign 10{sup 9} cm{sup -3}) that highly exceeds the background neutral density in the core of C-2. The deuterium fast-ions due to the target beam (E{approx}27 keV), are not confined in C-2 and thus make a negligible contribution to the measured signals.

Korepanov, S.; Smirnov, A.; Clary, R.; Dettrick, S. [Tri Alpha Energy, Inc., Rancho Santa Margarita, California 92688 (United States); Deichuli, P.; Kondakov, A.; Murakhtin, S. [Budker Institute of Nuclear Physics, Novosibirsk (Russian Federation)

2012-10-15T23:59:59.000Z

94

Exchange bias in polycrystalline magnetite films made by ion-beam assisted deposition  

SciTech Connect (OSTI)

Iron oxide films were produced using ion-beam-assisted deposition, and Raman spectroscopy and x-ray diffraction indicate single-phase magnetite. However, incorporation of significant fractions of argon in the films from ion bombardment is evident from chemical analysis, and Fe/O ratios are lower than expected from pure magnetite, suggesting greater than normal disorder. Low temperature magnetometry and first-order reversal curve measurements show strong exchange bias, which likely arises from defects at grain boundaries, possibly amorphous, creating frustrated spins. Since these samples contain grains ?6?nm, a large fraction of the material consists of grain boundaries, where spins are highly disordered and reverse independently with external field.

Kaur, Maninder; Qiang, You [Department of Physics, University of Idaho, Moscow, Idaho 83844 (United States); Jiang, Weilin [Pacific Northwest National Laboratory, Richland, Washington 99352 (United States); Burks, Edward C.; Liu, Kai [Department of Physics, University of California, Davis, California 95616 (United States); Namavar, Fereydoon [University of Nebraska Medical Center, Omaha, Nebraska 68198 (United States); McCloy, John S. [Pacific Northwest National Laboratory, Richland, Washington 99352 (United States); School of Mechanical and Materials Engineering, Washington State University, Pullman, Washington 98163 (United States)

2014-11-07T23:59:59.000Z

95

Small Column Ion Exchange Testing of Superlig 644 for Removal of 137Cs from Hanford Tank Waste Envelope C (Tank 241-AN-107)  

SciTech Connect (OSTI)

The current BNFL Inc. flowsheet for the pretreatment of the Hanford high-level tank wastes includes the use of Superlig{reg_sign} materials for removing {sup 137}Cs from the aqueous fraction of the waste. The Superlig materials applicable to cesium removal include the cesium-selective Superlig 632and Superlig 644. These materials have been developed and supplied by IBC Advanced Technologies, Inc., American Fork, Utah. This report describes the testing of the Superlig 644 ion exchange material in a small dual-column system. The bed volume of the lead column was 18.6 mL (L/D = 7), and the bed volume of the lag column was 15.9 mL (L/D = 6) during the loading phase. The sample processed was approximately 1.6 L of diluted waste ([Na{sup +}] = 4.84 M) from Tank 241-AN-107 (Envelope C). This sample had been previously treated for removal of Sr/transuranic (TRU) values and clarified in a single tube cross-flow filtration unit. All ion exchange process steps were tested, including resin-bed preparation, loading, feed displacement, water rinse, elution, eluant rinse, and resin regeneration. A summary of performance measures for both columns is shown in Table S1. The Cs {lambda} values represent a measure of the effective capacity of the SL-644 resin. The Cs {lambda} of 20 for the lead column is much lower than the estimated 150 obtained by the Savannah River Technology Center during Phase 1A testing. Equilibrium data obtained with batch contacts using the AN-107 Cs IX feed predicts a Cs {lambda} of 183. A Cs {lambda} for the lag column could not be determined due to insufficient breakthrough, but it appeared to work well and removed nearly all of the cesium not removed by the lead column. The low value for the lead column indicates that it did not perform as expected. This may have been due to air or gas in the bed that caused fluid channeling or blinding of the resin. The maximum decontamination factor (DF) for {sup 137}Cs listed in Table S1 is based on {sup 137}Cs concentration in the first samples collected from each column and the {sup 137}Cs concentration in the feed. The composite DF for {sup 137}Cs was 1,760, which provided an effluent with a {sup 137}Cs concentration of 8.7E-02 Ci/m{sup 3}. The {sup 137}Cs concentration is below the basis of design limit and is 7.2% of the contract limit for {sup 137}Cs.

DE Kurath; DL Blanchard; JR Bontha

2000-06-28T23:59:59.000Z

96

Use of Novel Highly Selective Ion Exchange Media for Minimizing the Waste Arising from Different NPP and Other Liquids  

SciTech Connect (OSTI)

Highly selective inorganic ion exchangers give new possibilities to implement and operate new innovative treatment systems for radioactive liquids. Because of high selectivity these ion exchangers can be used even in liquids of high salt concentrations. Only selected target nuclides will be separated and inactive salts are left in the liquid, which can be released or recategorized. Thus, it is possible to reduce the volume of radioactive waste dramatically. On the other hand, only a small volume of highly selective material is required in applications, which makes it possible to design totally new types of compact treatment systems. The major benefit of selective ion exchange media comes from the very large volume reduction of radioactive waste in final disposal. It is also possible to save in investment costs, because small ion exchanger volumes can be used and handled in a very small facility. This paper describes different applications of these highly selective ion exchangers, both commercial fullscale applications and laboratory tests, to give the idea of their efficiency for different liquids.

Tusa, Esko; Harjula, Risto; Lehto, Jukka

2003-02-25T23:59:59.000Z

97

Literature Review of Spherical Resorcinol-Formaldehyde for Cesium Ion Exchange  

SciTech Connect (OSTI)

The current report summarizes work performed throughout the scientific community and DOE complex as reported in the open literature and DOE-sponsored reports to evaluate the Cs+ ion exchange (CIX) characteristics of SRF resin. King (2007) completed a similar literature review in support of material selection for the Small Column Ion Exchange (SCIX) project. Josephson et al. (2010) and Sams et al. (2009) provided a similar brief review of SRF CIX for the near-tank Cs+ removal (NTCR) project. Thorson (2008a) documented the basis for recommending SRF over SuperLigTM 644 as the primary CIX resin in the WTP. The current review expands on previous work, summarizes additional work completed to date, and provides a broad view of the literature without focusing on a specific column system. Although the focus of the current review is the SRF resin, many cited references include multiple materials such as the non-spherical GGRF and SuperLigTM 644 organic resins and crystalline silicotitanate (CST) IONSIVTM IE-911, a non-elutable inorganic material. This report summarizes relevant information provided in the literature.

Brown, Garrett N.

2014-09-30T23:59:59.000Z

98

Modeling Ion-Exchange Processing With Spherical Resins For Cesium Removal  

SciTech Connect (OSTI)

The spherical Resorcinol-Formaldehyde and hypothetical spherical SuperLig(r) 644 ion-exchange resins are evaluated for cesium removal from radioactive waste solutions. Modeling results show that spherical SuperLig(r) 644 reduces column cycling by 50% for high-potassium solutions. Spherical Resorcinol Formaldehyde performs equally well for the lowest-potassium wastes. Less cycling reduces nitric acid usage during resin elution and sodium addition during resin regeneration, therefore, significantly decreasing life-cycle operational costs. A model assessment of the mechanism behind ''cesium bleed'' is also conducted. When a resin bed is eluted, a relatively small amount of cesium remains within resin particles. Cesium can bleed into otherwise decontaminated product in the next loading cycle. The bleed mechanism is shown to be fully isotherm-controlled vs. mass transfer controlled. Knowledge of residual post-elution cesium level and resin isotherm can be utilized to predict rate of cesium bleed in a mostly non-loaded column. Overall, this work demonstrates the versatility of the ion-exchange modeling to study the effects of resin characteristics on processing cycles, rates, and cold chemical consumption. This evaluation justifies further development of a spherical form of the SL644 resin.

Hang, T.; Nash, C. A.; Aleman, S. E.

2012-09-19T23:59:59.000Z

99

Heterogeneous models of tubular reactors packed with ion-exchange resins: Simulation of the MTBE synthesis  

SciTech Connect (OSTI)

The study of behavior of fixed-bed reactors using ion-exchange resins as catalysts was carried out by making use of a complete bidimensional heterogeneous model for the reactor, which included the resistances inside the ion-exchange resin particles, considered with a macroreticular structure. The active sites were located inside the gel phase of the resin, represented by microspheres, and on the macropores walls. The overall efficiency of such heterogeneous catalyst particles was defined by the macroeffectiveness and microeffectiveness factors accounting for the process behavior on the macropores and inside the microspheres. The synthesis of methyl tert-butyl ether, MTBE, a liquid-phase reversible exothermic reaction between methanol and isobutene, was considered as a reference case. This system was studied in the temperature range of 313--338 K, and the effect of the thermodynamic equilibrium conditions was examined. The results predicted by the complete heterogeneous model were compared with those obtained with the simple pseudohomogeneous model, which revealed higher hot spots. Moreover, a comparison between bidimensional and unidimensional models was also performed. The orthogonal collocation method was used for the discretization of the differential equations inside the catalyst particles, which were reduced from three (corresponding to the three mass balances for the three compounds, isobutene, methanol, and MTBE) to only one differential equation, by using the concept of the generalized variable.

Quinta Ferreira, R.M.; Almeida-Costa, C.A. [Univ. of Coimbra (Portugal). Dept. of Chemical Engineering; Rodrigues, A.E. [Univ. of Porto (Portugal). Dept. of Chemical Engineering

1996-11-01T23:59:59.000Z

100

MODELING CST ION EXCHANGE FOR CESIUM REMOVAL FROM SCIX BATCHES 1 - 4  

SciTech Connect (OSTI)

The objective of this work is, through modeling, to predict the performance of Crystalline Silicotitinate (CST) for the removal of cesium from Small Column Ion Exchange (SCIX) Batches 1-4 (as proposed in Revision 16 of the Liquid Waste System Plan). The scope of this task is specified in Technical Task Request (TTR) 'SCIX Feed Modeling', HLE-TTR-2011-003, which specified using the Zheng, Anthony, Miller (ZAM) code to predict CST isotherms for six given SCIX feed compositions and the VErsatile Reaction and SEparation simulator for Liquid Chromatography (VERSE-LC) code to predict ion-exchange column behavior. The six SCIX feed compositions provided in the TTR represent SCIX Batches 1-4 and Batches 1 and 2 without caustic addition. The study also investigated the sensitivity in column performance to: (1) Flow rates of 5, 10, and 20 gpm with 10 gpm as the nominal flow; and (2) Temperatures of 25, 35, and 45 C with 35 C as the nominal temperature. The isotherms and column predictions presented in this report reflect the expected performance of engineered CST IE-911. This form of CST was used in experiments conducted at the Savannah River National Laboratory (SRNL) that formed the basis for estimating model parameters (Hamm et al., 2002). As has been done previously, the engineered resin capacity is estimated to be 68% of the capacity of particulate CST without binder.

Smith, F.

2011-04-25T23:59:59.000Z

Note: This page contains sample records for the topic "ion exchange ix" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

THERMAL ANALYSIS FOR IN-TANK ION-EXCHANGE COLUMN PROCESS  

SciTech Connect (OSTI)

High Level Waste (HLW) at the Savannah River Site (SRS) is stored in three forms: sludge, saltcake, and supernate. A small column ion-exchange (SCIX) process is being designed to treat dissolved saltcake waste before feeding it to the saltstone facility to be made into grout. The waste is caustic with high concentrations of various sodium salts and lower concentrations of radionuclides. Two cation exchange media being considered are a granular form of crystalline silicotitanate (CST) and a spherical form of resorcinol-formaldehyde (RF) resin. CST is an inorganic material highly selective for cesium that is not elutable. Through this process, radioactive cesium from the salt solution is absorbed into ion exchange media (either CST or RF) which is packed within a flow-through column. A packed column loaded with radioactive cesium generates significant heat from radiolytic decay. If engineering designs cannot handle this thermal load, hot spots may develop locally which could degrade the performance of the ion-exchange media. Performance degradation with regard to cesium removal has been observed between 50 and 80 C for CST [1] and at 65 C for RF resin [2]. In addition, the waste supernate solution will boil around 130 C. If the columns boiled dry, the sorbent material could plug the column and lead to replacement of the entire column module. Alternatively, for organic resins such as RF there is risk of fire at elevated temperatures. The objective of the work is to compute temperature distributions across CST- and RF-packed columns immersed in waste supernate under accident scenarios involving loss of salt solution flow through the beds and, in some cases, loss of coolant system flow. For some cases, temperature distributions are determined as a function of time after the initiation of a given accident scenario and in other cases only the final steady-state temperature distributions are calculated. In general, calculations are conducted to ensure conservative and bounding results for the maximum temperatures achievable using the current baseline column design. This information will assist in SCIX design and facility maintenance.

Lee, S; Frank02 Smith, F

2009-01-05T23:59:59.000Z

102

THERMAL PERFORMANCE ANALYSIS FOR SMALL ION-EXCHANGE CESIUM REMOVAL PROCESS  

SciTech Connect (OSTI)

The In-Riser Ion Exchange program focuses on the development of in-tank systems to decontaminate high level waste (HLW) salt solutions at the Savannah River Site (SRS) and the Hanford Site. Small Column Ion Exchange (SCIX) treatment for cesium removal is a primary in-riser technology for decontamination prior to final waste immobilization in Saltstone. Through this process, radioactive cesium from the salt solution is adsorbed onto the ion exchange media which is packed within a flow-through column. Spherical Resorcinol-Formaldehyde (RF) is being considered as the ion exchange media for the application of this technology at both sites. A packed column loaded with media containing radioactive cesium generates significant heat from radiolytic decay. Under normal operating conditions, process fluid flow through the column can provide adequate heat removal from the columns. However, in the unexpected event of loss of fluid flow or fluid drainage from the column, the design must be adequate to handle the thermal load to avoid unacceptable temperature excursions. Otherwise, hot spots may develop locally which could degrade the performance of the ion-exchange media or the temperature could rise above column safety limits. Data exists which indicates that performance degradation with regard to cesium removal occurs with RF at 65C. In addition, the waste supernate solution will boil around 130C. As a result, two temperature limits have been assumed for this analysis. An additional upset scenario was considered involving the loss of the supernate solution due to inadvertent fluid drainage through the column boundary. In this case, the column containing the loaded media could be completely dry. This event is expected to result in high temperatures that could damage the column or cause the RF sorbent material to undergo undesired physical changes. One objective of these calculations is to determine the range of temperatures that should be evaluated during testing with the RF media. Although, the safety temperature limit is based on the salt solution boiling point which does not apply in the air-filled case (because there is no liquid), this same limit (130C) is used as a measure for the evaluation of this condition as well. The primary objective of the present work is to develop models to simulate the thermal performance of the RF column design when the media is fully loaded with radioactive cesium and the central cooling tube is excluded. Previous analysis led to the consideration of this design simplification for RF, since the baseline column design with center cooling was developed assuming that CST media would be used for cesium removal which has a higher volumetric heat load. Temperature distributions and maximum temperatures across the column during SCIX process operations and upset conditions were conducted with a focus on SCIX implementation at Hanford. However, a feed composition and cesium loading were assumed which were known to be considerably higher than would typically be observed at Hanford. In order to evaluate the impact of this potentially highly conservative assumption, fractionally-reduced loading cases were also considered. A computational modeling approach was taken to include conservative, bounding estimates for key parameters so that the results would provide the maximum temperatures achievable under the design configurations.

Lee, S.; King, W.

2009-12-29T23:59:59.000Z

103

THREE-DIMENSIONAL THERMAL MODELING ANALYSIS OF CST MEDIA FOR THE SMALL ION EXCHANGE PROJECT  

SciTech Connect (OSTI)

The Small Column Ion Exchange (SCIX) project is designed to accelerate closure of High Level Waste (HLW) tanks at the Savannah River Site (SRS). The SRS tanks store HLW in three forms: sludge, saltcake, and supernate. An in-tank ion exchange process is being designed to treat supernate and dissolved saltcake waste. Through this process, radioactive cesium from the salt solution is adsorbed into Crystalline Silicotitanate (CST) ion exchange media packed within a flow-through column. A packed column loaded with radioactive cesium generates significant heat from radiolytic decay. The waste supernate solution within the ion exchange bed will boil around 120 C. Solution superheating above the boiling point within the column could lead to violent hazardous energy releases. System heating from loaded CST is also of concern in other process modules, such as the waste tank. Due to tank structural integrity concerns, the wall temperature limit for the SRS waste tanks is 100 C. The transfer of cesium-loaded CST to the tank could result in localized hot spots on the tank floor and walls which may exceed this limit. As a result, thermal modeling calculations have been conducted to predict the maximum temperatures achievable both in the column and in the waste tank. As specified in the associated Technical Task Plan, one objective of the present work was to compute temperature distributions within the ion exchange column module under accident scenarios including loss of salt solution flow through the bed and loss of coolant system flow. The column modeling domain and the scope of the calculations in this case were broadened relative to previous two-dimensional calculations to include vertical temperature distributions within the packed bed of ion exchange media as well as the upper column plenum region containing only fluid. The baseline design conditions and in-column modeling domain for the ion-exchange column module are shown in Figure 1. These evaluations assumed the maximum bounding cesium loading considered possible based on current knowledge regarding CST media and the anticipated feed compositions. Since this cesium loading was considerably higher than the nominal loading conditions in SRS waste, cases with lower loading were also evaluated. Modeling parameters were the same as those used previously unless otherwise indicated. The current model does not capture multi-phase cooling mechanisms operative when solution boiling occurs. This feature is conservative in the sense that it does not account for the large cooling effects associated with phase transfer. However, the potential transfer of heat to the plenum region associated with vertical bubble ascension through the column during boiling is also neglected. Thermal modeling calculations were also performed for the entire waste storage tank for the case where loaded and ground CST was transferred to the tank. The modeling domain used for the in-tank calculations is provided in Figure 2. The in-tank domain is based on SRS Tank 41, which is a Type-IIIA tank. Temperature distributions were evaluated for cylindrical, ground CST mounds located on the tank floor. Media grinding is required prior to vitrification processing of the CST in the SRS Defense Waste Processing Facility (DWPF). The location of the heat source region on the tank floor due to the accumulation of CST material was assumed to be just under the grinder. The shape of the CST mound was assumed to be cylindrical. This shape is believed to be most representative of the actual mound shape formed in the tank, given that submersible mixing pumps will be available for media dispersion. Alternative configurations involving other geometrical shapes for the CST mound were evaluated in the previous work. Sensitivity analysis for the in-tank region was performed for different amounts of CST media. As was the case for the in-column model, the in-tank model does not include multi-phase cooling mechanisms operative when solution boiling occurs. The in-column and the in-tank evaluations incorporated recently updated maximum cesi

Lee, S.; King, W.

2011-09-12T23:59:59.000Z

104

Preliminary flowsheet: Ion exchange for separation of cesium from Hanford tank waste using resorcinol-formaldehyde resin  

SciTech Connect (OSTI)

This preliminary flowsheet document describes an ion exchange process which uses resorcinol-formaldehyde (R-F) resin to remove cesium from Hanford tank waste. The flowsheet describes one possible equipment configuration, and contains mass balances based on that configuration with feeds of Neutralized Current Acid Waste, and Double Shell Slurry Feed. The flowsheet also discusses process alternatives, unresolved issues, and development needs associated with the ion exchange process. It is expected that this flowsheet will evolve as open issues are resolved and progress is made on development needs. This is part of the Tank Waste Remediation Program at Hanford. 26 refs, 6 figs, 25 tabs.

Penwell, D.L.

1994-12-28T23:59:59.000Z

105

THERMAL MODELING ANALYSIS OF CST MEDIA IN THE SMALL COLUMN ION EXCHANGE PROJECT  

SciTech Connect (OSTI)

Models have been developed to simulate the thermal characteristics of Crystalline Silicotitanate (CST) ion exchange media fully loaded with radioactive cesium in a column configuration and distributed within a waste storage tank. This work was conducted to support the Small Column Ion Exchange (SCIX) program which is focused on processing dissolved, high-sodium salt waste for the removal of specific radionuclides (including Cs-137, Sr-90, and actinides) within a High Level Waste (HLW) storage tank at the Savannah River Site. The SCIX design includes CST columns inserted and supported in the tank top risers for cesium removal. Temperature distributions and maximum temperatures across the column were calculated with a focus on process upset conditions. A two-dimensional computational modeling approach for the in-column ion-exchange domain was taken to include conservative, bounding estimates for key parameters such that the results would provide the maximum centerline temperatures achievable under the design configurations using a feed composition known to promote high cesium loading on CST. One salt processing scenario includes the transport of the loaded (and possibly ground) CST media to the treatment tank floor. Therefore, additional thermal modeling calculations were conducted using a three-dimensional approach to evaluate temperature distributions for the entire in-tank domain including distribution of the spent CST media either as a mound or a flat layer on the tank floor. These calculations included mixtures of CST with HLW sludge or loaded Monosodium Titanate (MST) media used for strontium/actinide sorption. The current full-scale design for the CST column includes one central cooling pipe and four outer cooling tubes. Most calculations assumed that the fluid within the column was stagnant (i.e. no buoyancy-induced flow) for a conservative estimate. A primary objective of these calculations was to estimate temperature distributions across packed CST beds immersed in waste supernate or filled with dry air under various accident scenarios. Accident scenarios evaluated included loss of salt solution flow through the bed (a primary heat transfer mechanism), inadvertent column drainage, and loss of active cooling in the column. The calculation results showed that for a wet CST column with active cooling through one central and four outer tubes and 35 C ambient external air, the peak temperature for the fully-loaded column is about 63 C under the loss of fluid flow accident, which is well below the supernate boiling point. The peak temperature for the naturally-cooled (no active, engineered cooling) wet column is 156 C under fully-loaded conditions, exceeding the 130 C boiling point. Under these conditions, supernate boiling would maintain the column temperature near 130 C until all supernate was vaporized. Without active engineered cooling and assuming a dry column suspended in unventilated air at 35 C, the fully-loaded column is expected to rise to a maximum of about 258 C due to the combined loss-of coolant and column drainage accidents. The modeling results demonstrate that the baseline design using one central and four outer cooling tubes provides a highly efficient cooling mechanism for reducing the maximum column temperature. Results for the in-tank modeling calculations clearly indicate that when realistic heat transfer boundary conditions are imposed on the bottom surface of the tank wall, as much as 450 gallons of ground CST (a volume equivalent to two ion exchange processing cycles) in an ideal hemispherical shape (the most conservative geometry) can be placed in the tank without exceeding the 100 C wall temperature limit. Furthermore, in the case of an evenly-distributed flat layer, the tank wall reaches the temperature limit after the ground CST material reaches a height of approximately 8 inches.

Lee, S.

2010-11-01T23:59:59.000Z

106

Standard practice for The separation of americium from plutonium by ion exchange  

E-Print Network [OSTI]

1.1 This practice describes the use of an ion exchange technique to separate plutonium from solutions containing low concentrations of americium prior to measurement of the 241Am by gamma counting. 1.2 This practice covers the removal of plutonium, but not all the other radioactive isotopes that may interfere in the determination of 241Am. 1.3 This practice can be used when 241Am is to be determined in samples in which the plutonium is in the form of metal, oxide, or other solid provided that the solid is appropriately sampled and dissolved (See Test Methods C758, C759, and C1168). 1.4 This standard does not purport to address all of the safety concerns, if any, associated with its use. It is the responsibility of the user of this standard to establish appropriate safety and health practices and determine the applicability of regulatory limitations prior to use.

American Society for Testing and Materials. Philadelphia

2001-01-01T23:59:59.000Z

107

Small-Column Cesium Ion Exchange Elution Testing of Spherical Resorcinol-Formaldehyde  

SciTech Connect (OSTI)

This report summarizes the work performed to evaluate multiple, cesium loading, and elution cycles for small columns containing SRF resin using a simple, high-level waste (HLW) simulant. Cesium ion exchange loading and elution curves were generated for a nominal 5 M Na, 2.4E-05 M Cs, 0.115 M Al loading solution traced with 134Cs followed by elution with variable HNO3 (0.02, 0.07, 0.15, 0.23, and 0.28 M) containing variable CsNO3 (5.0E-09, 5.0E-08, and 5.0E-07 M) and traced with 137Cs. The ion exchange system consisted of a pump, tubing, process solutions, and a single, small ({approx}15.7 mL) bed of SRF resin with a water-jacketed column for temperature-control. The columns were loaded with approximately 250 bed volumes (BVs) of feed solution at 45 C and at 1.5 to 12 BV per hour (0.15 to 1.2 cm/min). The columns were then eluted with 29+ BVs of HNO3 processed at 25 C and at 1.4 BV/h. The two independent tracers allowed analysis of the on-column cesium interaction between the loading and elution solutions. The objective of these tests was to improve the correlation between the spent resin cesium content and cesium leached out of the resin in subsequent loading cycles (cesium leakage) to help establish acid strength and purity requirements.

Brown, Garrett N.; Russell, Renee L.; Peterson, Reid A.

2011-10-21T23:59:59.000Z

108

Using Process Knowledge to Manage Disposal Classification of Ion-Exchange Resin - 13566  

SciTech Connect (OSTI)

It has been previously shown by EPRI [1] that Class B and C resins represent a small portion by volume of the overall generation of radioactively contaminated resins. In fact, if all of the resins were taken together the overall classification would meet Class A disposal requirements. Lowering the classification of the ion exchange resins as they are presented for disposal provides a path for minimizing the amount of waste stored. Currently there are commercial options for blending wastes from various generators for Class A disposal in development. The NRC may have by this time introduced changes and clarifications to the Branch Technical Position (BTP) on Concentration Averaging and Encapsulation [2] that may ultimately add more flexibility to what can be done at the plant level. The BTP has always maintained that mixtures of resins that are combined for ALARA purposes or operational efficiency can be classified on the basis of the mixture. This is a point often misinterpreted and misapplied. This paper will address options that can be exercised by the generator that can limit B and C waste generation by more rigorous tracking of generation and taking advantage of the normal mix of wastes. This can be achieved through the monitoring of reactor coolant chemistry data and coupled with our knowledge of radionuclide production mechanisms. This knowledge can be used to determine the overall accumulation of activity in ion-exchange resins and provides a 'real-time' waste classification determination of the resin and thereby provide a mechanism to reduce the production of waste that exceeds class A limits. It should be noted that this alternative approach, although rarely used in a nuclear power plant setting, is acknowledged in the original BTP on classification [3] as a viable option for determining radionuclide inventories for classification of waste. Also included is a discussion of an examination performed at the Byron plant to estimate radionuclide content in the final waste stream from upstream sampling of reactor coolant and fuel pool water. (authors)

Bohnsack, Jonathan N.; James, David W. [DW James Consulting, LLC 855 Village Center Drive No. 330 North Oaks, MN 55127 (United States)] [DW James Consulting, LLC 855 Village Center Drive No. 330 North Oaks, MN 55127 (United States)

2013-07-01T23:59:59.000Z

109

DATA QUALITY OBJECTIVE SUMMARY REPORT FOR THE 105 K EAST ION EXCHANGE COLUMN MONOLITH  

SciTech Connect (OSTI)

The 105-K East (KE) Basin Ion Exchange Column (IXC) cells, lead caves, and the surrounding vault are to be removed as necessary components in implementing ''Hanford Federal Facility Agreement and Consent Order'' (Ecology et al. 2003) milestone M-034-32 (Complete Removal of the K East Basin Structure). The IXCs consist of six units located in the KE Basin, three in operating positions in cells and three stored in a lead cave. Methods to remove the IXCs from the KE Basin were evaluated in KBC-28343, ''Disposal of K East Basin Ion Exchange Column Evaluation''. The method selected for removal was grouting the six IXCs into a single monolith for disposal at the Environmental Restoration Disposal Facility (ERDF). Grout will be added to the IXC cells, IXC lead caves containing spent IXCs, and in the spaces between the lead cave walls and metal skin, to immobilize the contaminants, provide self-shielding, minimize void space, and provide a structurally stable waste form. The waste to be offered for disposal is the encapsulated monolith defined by the exterior surfaces of the vault and the lower surface of the underlying slab. This document presents summary of the data quality objective (DQO) process establishing the decisions and data required to support decision-making activities for the disposition of the IXC monolith. The DQO process is completed in accordance with the seven-step planning process described in EPA QA/G-4, ''Guidance for the Data Quality Objectives Process'', which is used to clarify and study objectives; define the appropriate type, quantity, and quality of data; and support defensible decision-making. The DQO process involves the following steps: (1) state the problem; (2) identify the decision; (3) identify the inputs to the decision; (4) define the boundaries of the study; (5) develop a decision rule (DR); (6) specify tolerable limits on decision errors; and (7) optimize the design for obtaining data.

JOCHEN, R.M.

2007-08-02T23:59:59.000Z

110

DATA QUALITY OBJECTIVES SUMMARY REPORT FOR THE 105K EAST BASIN ION EXCHANGE COLUMN MONOLITH  

SciTech Connect (OSTI)

The 105-K East (KE) Basin Ion Exchange Column (IXC) cells, lead caves, and the surrounding vault are to be removed as necessary components in implementing ''Hanford Federal Facility Agreement and Consert Order'' (Ecology et al. 2003) milestone M-034-32 (Complete Removal of the K East Basin Structure). The IXCs consist of six units located in the KE Basin, three in operating positions in cells and three stored in a lead cave. Methods to remove the IXCs from the KE Basin were evaluated in KBC-28343, ''Disposal of K East Basin Ion Exchange Column Evaluation''. The method selected for removal was grouting of the six IXCs into a single monolith for disposal at the Environmental Restoration Disposal Facility (ERDF). Grout will be added to the IXC cells, IXC lead caves containing spent IXCs, and in the spaces between to immobilize the contaminants, provide self-shielding, minimize void space, and provide a structurally stable waste form. The waste to be offered for disposal is the encapsulated monolith defined by the exterior surfaces of the vault and the lower surface of the underlying slab. This document presents a summary of the data quality objective (DQO) process establishing the decisions and data required to support decision-making activities for disposition of the IXC monolith. The DQO process is completed in accordance with the seven-step planning process described in EPA QA/G-4, ''Guidance for the Data Quality Objectives Process'', which is used to clarify and study objectives; define the appropriate type, quantity, and quality of data; and support defensible decision-making. The DQO process involves the following steps: (1) state the problem; (2) identify the decision; (3) identify the inputs to the decision; (4) define the boundaries of the study; (5) develop a decision rule (DR); (6) specify tolerable limits on decision errors; and (7) optimize the design for obtaining data.

JOCHEN, R.M.

2007-02-07T23:59:59.000Z

111

Formation and structural characterization of potassium titanates and the potassium ion exchange property  

SciTech Connect (OSTI)

In the present work, K{sub 2}Ti{sub 2}O{sub 5}, K{sub 2}Ti{sub 4}O{sub 9} and K{sub 2}Ti{sub 6}O{sub 13} are synthesized by solid state method. Their structures and morphologies are characterized by X-ray diffraction, Raman spectra and scanning electron microscopy. The binding energies of K, Ti and O in potassium titanates were then evaluated by X-ray photoelectron spectroscopy and compared with those in K/TiO{sub 2}. Finally the corresponding K ion exchange properties are investigated by synthesizing NO oxidation catalysts with Co(NO{sub 3}){sub 2} precursor. It is found that the binding energy of K in K{sub 2}Ti{sub 2}O{sub 5} is much higher than those in K{sub 2}Ti{sub 4}O{sub 9} and K{sub 2}Ti{sub 6}O{sub 13}, and because of which, it shows quite different catalytic performances. Compared with other potassium titanates, the K in K{sub 2}Ti{sub 2}O{sub 5} is much easier to be exchanged out.

Wang Qiang, E-mail: wulihe@postech.ac.kr [Department of Catalysis Science and Engineering, School of Chemical Engineering and Technology, Harbin Institute of Technology, Harbin, Heilongjiang, 150001 (China); School of Environmental Science and Engineering, POSTECH, San 31, Hyoja-Dong, Nam-gu, Pohang 790-784 (Korea, Republic of); Guo Zhanhu [Integrated Composites Laboratory (ICL), Dan F. Smith Department of Chemical Engineering, Lamar University, Beaumont, TX 77710 (United States); Chung, Jong Shik [School of Environmental Science and Engineering, POSTECH, San 31, Hyoja-Dong, Nam-gu, Pohang 790-784 (Korea, Republic of); Department of Chemical Engineering, POSTECH, San 31, Hyoja-Dong, Nam-gu, Pohang 790-784 (Korea, Republic of)

2009-10-15T23:59:59.000Z

112

Anionic Gallium-Based Metal;#8722;Organic Framework and Its Sorption and Ion-Exchange Properties  

SciTech Connect (OSTI)

A gallium-based metal-organic framework Ga{sub 6}(C{sub 9}H{sub 3}O{sub 6}){sub 8} {center_dot} (C{sub 2}H{sub 8}N){sub 6}(C{sub 3}H{sub 7}NO){sub 3}(H{sub 2}O){sub 26} [1, Ga{sub 6}(1,3,5-BTC){sub 8} {center_dot} 6DMA {center_dot} 3DMF {center_dot} 26H{sub 2}O], GaMOF-1; BTC = benzenetricarboxylate/trimesic acid and DMA = dimethylamine, with space group I{bar 4}3d, a = 19.611(1) {angstrom}, and V = 7953.4(6) {angstrom}{sup 3}, was synthesized using solvothermal techniques and characterized by synchrotron-based X-ray microcrystal diffraction. Compound 1 contains isolated gallium tetrahedra connected by the organic linker (BTC) forming a 3,4-connected anionic porous network. Disordered positively charged ions and solvent molecules are present in the pore, compensating for the negative charge of the framework. These positively charged molecules could be exchanged with alkali-metal ions, as is evident by an ICP-MS study. The H{sub 2} storage capacity of the parent framework is moderate with a H{sub 2} storage capacity of {approx}0.5 wt % at 77 K and 1 atm.

Banerjee, Debasis; Kim, Sun Jin; Wu, Haohan; Xu, Wenqian; Borkowski, Lauren A.; Li, Jing; Parise, John B. (Kwangju); (Rutgers); (SBU)

2012-04-30T23:59:59.000Z

113

808 OPTICS LETTERS / Vol. 18, No. 10 / May 15, 1993 Photowritten gratings in ion-exchanged glass waveguides  

E-Print Network [OSTI]

gratings line by line. Gratings have been optically written in photo- sensitive fibers. Line808 OPTICS LETTERS / Vol. 18, No. 10 / May 15, 1993 Photowritten gratings in ion-exchanged glass defectcentered at 330 am,which was created by y-ray irradiation of the glass. The bleaching was accomplished

Winick, Kim

114

Novel Hybrid Materials with High Stability for Electrically Switched Ion Exchange: Carbon Nanotubes/Polyaniline/Nickel Hexacyanoferrate Nanocomposites  

SciTech Connect (OSTI)

A novel and stable carbon nanotubes /polyaniline /nickel hexacyanoferrates composite film has been synthesized with electrodeposition method, and the possibility for removing cesium through an electrically switched ion exchange has been evaluated in a mixture containing NaNO3 and CsNO3.

Lin, Yuehe; Cui, Xiaoli

2005-04-21T23:59:59.000Z

115

The TFTR E Parallel B Spectrometer for Mass and Energy Resolved Multi-Ion Charge Exchange Diagnostics  

SciTech Connect (OSTI)

The Charge Exchange Neutral Analyzer diagnostic for the Tokamak Fusion Test Reactor was designed to measure the energy distributions of both the thermal ions and the supra thermal populations arising from neutral-beam injection and ion cyclotron radio-frequency heating. These measurements yield the plasma ion temperature, as well as several other plasma parameters necessary to provide an understanding of the plasma condition and the performance of the auxiliary heating methods. For this application, a novel charge-exchange spectrometer using a dee-shaped region of parallel electric and magnetic fields was developed at the Princeton Plasma Physics Laboratory. The design and performance of this spectrometer is described in detail, including the effects of exposure of the microchannel plate detector to magnetic fields, neutrons, and tritium.

A.L. Roquemore; S.S. Medley

1998-01-01T23:59:59.000Z

116

Synthesis and Evaluation of Cu-SAPO-34 Catalysts for Ammonia Selective Catalytic Reduction. 1. Aqueous Solution Ion Exchange  

SciTech Connect (OSTI)

SAPO-34 molecular sieves are synthesized using various structure directing agents (SDAs). Cu-SAPO-34 catalysts are prepared via aqueous solution ion exchange. Catalysts are characterized with surface area/pore volume measurements, temperature programmed reduction (TPR), electron paramagnetic resonance (EPR) and nuclear magnetic resonance (NMR) spectroscopies. Catalytic properties are examined using standard ammonia selective catalytic reduction (NH3-SCR) and ammonia oxidation reactions. During solution ion exchange, different SAPO-34 samples undergo different extent of structural damage via irreversible hydrolysis. Si content within the samples (i.e., Al-O-Si bond density) and framework stress are key factors that affect irreversible hydrolysis. Even using very dilute Cu acetate solutions, it is not possible to generate Cu-SAPO-34 samples with only isolated Cu2+ ions. Small amounts of CuOx species always coexist with isolated Cu2+ ions. Highly active and selective Cu-SAPO-34 catalysts for NH3-SCR are readily generated using this synthesis protocol, even for SAPO-34 samples that degrade substantially during solution ion exchange. High-temperature aging is found to improve the catalytic performance. This is likely due to reduction of intracrystalline mass-transfer limitations via formation of additional porosity in the highly defective SAPO-34 particles formed after ion exchange. The authors gratefully acknowledge the US Department of Energy (DOE), Office of Energy Efficiency and Renewable Energy, Office of Vehicle Technologies for the support of this work. The research described in this paper was performed at the Environmental Molecular Sciences Laboratory (EMSL), a national scientific user facility sponsored by the DOE’s Office of Biological and Environmental Research and located at Pacific Northwest National Laboratory (PNNL). PNNL is operated for the US DOE by Battelle Memorial Institute under contract number DE-AC05-76RL01830.

Gao, Feng; Walter, Eric D.; Washton, Nancy M.; Szanyi, Janos; Peden, Charles HF

2013-09-06T23:59:59.000Z

117

Increase of ionic conductivity in the microporous lithosilicate RUB-29 by Na-ion exchange processes  

SciTech Connect (OSTI)

The ionic conductivity in the zeolite-like lithosilicate RUB-29 (Cs{sub 14}Li{sub 24}[Li{sub 18}Si{sub 72}O{sub 172}].14H{sub 2}O [S.-H. Park, J.B. Parise, H. Gies, H. Liu, C.P. Grey, B.H. Toby, J. Am. Chem. Soc. 122 (2000) 11023-11024]) increases via simple ion-exchange processes, in particular when Na cations replace a part of Cs{sup +} and Li{sup +} of the material. The resulting ionic conductivity value of 3.2x10{sup -3} S cm{sup -1} at 885 K is about two orders higher than that for the original material [S.-H. Park, J.B. Parise, M.E. Franke, T. Seydel, C. Paulmann, Micropor. Mesopor. Mater., in print ( (doi:10.1016/j.micromeso.2007.03.040) available online since April 19, 2007)]. The structural basis of a Na{sup +}-exchanged RUB-29 sample (Na-RUB-29) at 673 K could be elucidated by means of neutron powder diffraction. Rietveld refinements confirmed the replacement of Na{sup +} for both parts of Cs and Li cations, agreeing with idealized cell content, Na{sub 8}Cs{sub 8}Li{sub 40}Si{sub 72}O{sub 172}. As a result of the incorporation of Na{sup +} in large pores, the number of Li{sup +} vacancies in dense Li{sub 2}O-layers of the structure could increase. This can be one of the main reasons for the improved conductivity in Na-RUB-29. In addition, mobile Na cations may also contribute to the conductivity in Na-RUB-29 as continuous scattering length densities were found around the sites for Na in difference Fourier map. - Graphical abstract: Li{sub 2}O-layers formed by edge- and corner-sharing LiO{sub 4}- and LiO{sub 3}-moieties in the zeolite-like lithosilicate RUB-29 provide optimal pathways for conducting Li{sup +}. The number of empty Li sites in this layer-like configuration could increase via 'simple' Na{sup +}-exchange processes, promoting fast Li motions.

Park, S.-H. [Section Crystallography, Earth and Environmental Sciences, Ludwig-Maximilians-Universitaet Muenchen, Theresienstr. 41, 80333 Munich (Germany)], E-mail: sohyun.park@lmu.de; Senyshyn, A. [Material- and Earth Sciences, Technische Universitaet Darmstadt, Petersenstr. 23, 64287 Darmstadt (Germany); Forschungsneutronenquelle Heinz Maier-Leibnitz (FRM II), Lichtenbergstr. 1, 85747 Garching (Germany); Paulmann, C. [Mineralogisch-Petrographisches Institut, Universitaet Hamburg, Grindelallee 48, 20146 Hamburg (Germany); HASYLAB, DESY, Notkestr. 85, 22603 Hamburg (Germany)

2007-12-15T23:59:59.000Z

118

TESTING OF NOVEL INORGANIC ION EXCHANGERS FOR THE REMOVAL OF RADIOCOBALT FROM NPP WASTE EFFLUENTS  

SciTech Connect (OSTI)

New antimonysilicate (SbSi) ion exchanger is being developed for industrial use. Tentative screening tests using simulated waste liquids have indicated that this material can remove most key radionuclides such as {sup 60}Co, {sup 90}Sr and {sup 137}Cs in much broader pH-range than existing commercial materials. As a part of the development program, the material is being tested for the removal of {sup 60}Co from real nuclear power plant waste waters. In this context, test with small-scale laboratory columns (bed volume 0.5 mL) have been carried out using a Floor Drain water samples from Ginna NPP and Diablo Canyon NPP, USA. More than 90% of {sup 60}Co in these liquids was removable by mechanical filtration (0.45 {micro}m). SbSi columns removed more than 90% of the soluble {sup 60}Co that was left in the solutions after filtration. The tests were discontinued when about 2000 bed volumes were treated due to depletion of test liquids with no sign of column exhaustion.

Harjula, R.; Paajanen, A.; Mueller, T.; Lehto, J.

2002-02-25T23:59:59.000Z

119

Inflation for Bianchi IX model  

E-Print Network [OSTI]

The influence of Inflation on initial (i.e. at Planck's epoch) large anisotropy of the Universe is studied, considering a more general metric than the isotropic one: the locally rotationally symmetric (L.R.S.) Bianchi IX metric. We find, then, a large set of initial conditions of intrinsic curvature and shear allowing an inflationary epoch that make the anisotropy negligible. These are not trivial because of the non-linearity of the Einstein's equations.

R. Bergamini; P. Sedici; P. Verrocchio

1996-11-29T23:59:59.000Z

120

PILOT SCALE TESTING OF MONOSODIUM TITANATE MIXING FOR THE SRS SMALL COLUMN ION EXCHANGE PROCESS - 11224  

SciTech Connect (OSTI)

The Small Column Ion Exchange (SCIX) process is being developed to remove cesium, strontium, and select actinides from Savannah River Site (SRS) Liquid Waste using an existing waste tank (i.e., Tank 41H) to house the process. Savannah River National Laboratory (SRNL) is conducting pilot-scale mixing tests to determine the pump requirements for suspending monosodium titanate (MST), crystalline silicotitanate (CST), and simulated sludge. The purpose of this pilot scale testing is to determine the requirements for the pumps to suspend the MST particles so that they can contact the strontium and actinides in the liquid and be removed from the tank. The pilot-scale tank is a 1/10.85 linear scaled model of SRS Tank 41H. The tank diameter, tank liquid level, pump nozzle diameter, pump elevation, and cooling coil diameter are all 1/10.85 of their dimensions in Tank 41H. The pump locations correspond to the proposed locations in Tank 41H by the SCIX program (Risers B5 and B2 for two pump configurations and Risers B5, B3, and B1 for three pump configurations). The conclusions from this work follow: (i) Neither two standard slurry pumps nor two quad volute slurry pumps will provide sufficient power to initially suspend MST in an SRS waste tank. (ii) Two Submersible Mixer Pumps (SMPs) will provide sufficient power to initially suspend MST in an SRS waste tank. However, the testing shows the required pump discharge velocity is close to the maximum discharge velocity of the pump (within 12%). (iii) Three SMPs will provide sufficient power to initially suspend MST in an SRS waste tank. The testing shows the required pump discharge velocity is 66% of the maximum discharge velocity of the pump. (iv) Three SMPs are needed to resuspend MST that has settled in a waste tank at nominal 45 C for four weeks. The testing shows the required pump discharge velocity is 77% of the maximum discharge velocity of the pump. Two SMPs are not sufficient to resuspend MST that settled under these conditions.

Poirier, M.; Restivo, M.; Williams, M.; Herman, D.; Steeper, T.

2011-01-25T23:59:59.000Z

Note: This page contains sample records for the topic "ion exchange ix" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
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121

Variations in K{sup +}-Na{sup +} ion exchange depth in commercial and experimental float glass compositions  

SciTech Connect (OSTI)

The authors report the results of ion-exchange experiments conducted on 17 commercial soda-lime-silicate (SLS) float glass and 8 experimental SLS glass compositions. A significant variation in the depth of K{sup +} penetration with relatively small changes in composition was observed. The data were fit to a multiple regression model in which the major oxides are the independent variables and depth of K{sup +} is the dependent variable. The model indicates that increased depth of exchange (increased interdiffusion coefficient) correlates predominantly with increased K{sub 2}O and/or Na{sub 2}O content of the glass, with a decreased total alkaline earth content and with the ratio of CaO/MgO.

Sinton, C.W.; LaCourse, W.C.; O'Connell, M.J.

1999-12-01T23:59:59.000Z

122

Title IX | Department of Energy  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas ConchasPassiveSubmittedStatusButler Tina Butler Tina-Butler.jpgLightingWindows Tips:StudyIX

123

IMPACT OF SMALL COLUMN ION EXCHANGE STREAMS ON DWPF GLASS FORMULATION MELT RATE STUDIES  

SciTech Connect (OSTI)

This study was undertaken to evaluate the potential impacts of the Small Column Ion Exchange (SCIX) streams - particularly the addition of Monosodium Titanate (MST) and Crystalline Silicotitanate (CST) - on the melt rate of simulated feed for the Defense Waste Processing Facility (DWPF). Additional MST was added to account for contributions from the Salt Waste Processing Facility (SWPF). The Savannah River National Laboratory (SRNL) Melt Rate Furnace (MRF) was used to evaluate four melter feed compositions: two with simulated SCIX and SWPF material and two without. The Slurry-fed Melt Rate Furnace (SMRF) was then used to compare two different feeds: one with and one without bounding concentrations of simulated SCIX and SWPF material. Analyses of the melter feed materials confirmed that they met their targeted compositions. Four feeds were tested in triplicate in the MRF. The linear melt rates were determined by using X-ray computed tomography to measure the height of the glass formed along the bottom of the beakers. The addition of the SCIX and SWPF material reduced the average measured melt rate by about 10% in MRF testing, although there was significant scatter in the data. Two feeds were tested in the SMRF. It was noted that the ground CST alone (ground CST with liquid in a bucket) was extremely difficult to resuspend during preparation of the feed with material from SCIX and SWPF. This feed was also more difficult to pump than the material without MST and CST due to settling occurring in the melter feed line, although the yield stress of both feeds was high relative to the DWPF design basis. Steady state feeding conditions were maintained for about five hours for each feed. There was a reduction in the feed and pour rates of approximately 15% when CST and MST were added to the feed, although there was significant scatter in the data. Analysis of samples collected from the SMRF pour stream showed that the composition of the glass changed as expected when MST and CST were added to the feed. These reductions in melt rate are consistent with previous studies that showed a negative impact of increased TiO{sub 2} concentrations on the rate of melting. The impact of agitating the melt pool via bubbling was not studied as part of this work, but may be of interest for further testing. It is recommended that additional melt rate testing be performed should a potential reduction in melt rate of 10-15% be considered an issue of concern, or should the anticipated composition of the glass with the addition of material from salt waste processing be modified significantly from the current projections, either due to changes in sludge batch preparation or changes in the composition or volume of SCIX and SWPF material.

Fox, K.; Miller, D.; Koopman, D.

2011-04-26T23:59:59.000Z

124

Method of uranium reclamation from aqueous systems by reactive ion exchange. [US DOE patent application; anion exchange resin of copolymerized divinyl-benzene and styrene having quarternary ammonium groups and bicarbonate ligands  

DOE Patents [OSTI]

A reactive ion exchange method for separation and recovery of values of uranium, neptunium, plutonium, or americium from substantially neutral aqueous systems of said metals comprises contacting said system with an effective amount of a basic anion exchange resin of copolymerized divinyl-benzene and styrene having quarternary ammonium groups and bicarbonate ligands to achieve nearly 100% sorption of said actinyl ion onto said resin and an aqueous system practically free of said actinyl ions. The method is operational over an extensive range of concentrations from about 10/sup -6/ M to 1.0 M actinyl ion and a pH range of about 4 to 7. The method has particulr application to treatment of waste streams from Purex-type nuclear fuel reprocessing facilities and hydrometallurgical processes involving U, Np, P, or Am.

Maya, L.

1981-11-05T23:59:59.000Z

125

Radioactive Spent Ion-Exchange Resins Conditioning by the Hot Supercompaction Process at Tihange NPP - Early Experience - 12200  

SciTech Connect (OSTI)

Spent ion-exchange resins are considered to be problematic waste that, in many cases, requires special approaches and precautions during their conditioning to meet the acceptance criteria for disposal. In Belgium, for economical reasons, the Volume Reduction Factor is a key criterion. After Tractebel Engineering performed a technical and economical comparison of the industrially available systems, Tihange NPP decided to install a spent ion-exchange resins hot supercompaction unit with Tractebel Engineering in the role of architect-engineer. The treatment and conditioning unit processes the spent ion-exchange resins through the following steps: dewatering of the resins, drying the resins under deep vacuum, discharging the dried resins into compactable drums, super-compacting the drums to generate pellets, grouting the pellets into standard 400 litres waste drums (overpacks) licensed for final disposal in the near-surface repository in Belgium. Several developments were required to adapt the reference process and equipment to PWR spent ion-exchange bead resins and Belgian radioactive waste acceptance criteria. In order to avoid cracks on the compacted drum, and external surface contamination from resin leaks, some improvements were achieved to minimize spring-back as well as the risk of cracking the drum wall. Placing the compactable drum inside a second, slightly larger drum, guarantees clean and reproducible pellets. Currently the commissioning phase is on-going. Numerous process validation tests have been completed. An acceptance file was transmitted to the Belgian Waste Management Authority recently. This will be followed by demonstration tests necessary to obtain their final acceptance of the installation. More than 3 800 drums of mixed powdered and bead resins have been processed by the reference Hot Compaction process, achieving a Volume Reduction Factor (VRF) of 2.5. The equipment has been proven to be a reliable technology with low operation and maintenance costs. Tractebel Engineering has managed the construction of a new application of this process in Belgium at Tihange NPP. Several developments were required to adapt the reference process and equipment to PWR spent ion-exchange bead resins and Belgian radioactive waste acceptance criteria. The chosen method of conditioning (draining, drying and compaction of the spent resins followed by grouting of the pellets in a 400 litres drum) immobilizes the spent resins under the form of a solid, compact, stable, and non dispersible block free of interstitial water. The various series of inactive tests which were conducted at Tihange NPP, helped among others to determine the best design of the compactable drum and lid and to set the value of critical parameters such as vapour temperature at the end of drying, speed, force and duration of compaction. In an environment of very limited space for interim storage and in the absence of an operational final repository site, or in the case of high final disposal costs, the process exhibits the following key advantages: - Achieving a Volume Reduction Factor (VRF) close to 1 (overpack included) for the interim storage instead of increased volumes observed with other currently available processes; - Achieving a water free end product; - Creating a flexible waste product for interim storage (pellet), which can be retrieved and routed into alternative types of package later, if not initially grouted; - Using well proven standard technologies like drying and compaction; - Flexible use of the system components for the supercompaction of other operational solid waste streams when not conducting resins conditioning campaigns. (authors)

Braet, Johan; Charpentier, David; Centner, Baudouin; Vanderperre, Serge [Nuclear Department, Tractebel Engineering (GDF-SUEZ), Avenue Ariane 7, B-1200 Brussels (Belgium)

2012-07-01T23:59:59.000Z

126

Nonlinear inverse problem for a model of ion-exchange filter: numerical recovery of parameters  

E-Print Network [OSTI]

]. Power-generating units of TPP operate under severe corrosive conditions: high temperature (515 - 530°C-exchange filters results in highly mineralized, acidic and alkaline waste water [9]. With the continuous) and pressure (15 MPa) of hot steam [2]. Some units are made of cheap corrosion and heat-resistant steel which

127

Ultra-fast charge exchange spectroscopy for turbulent ion temperature fluctuation measurements on the DIII-D tokamak (invited)  

SciTech Connect (OSTI)

A novel two-channel, high throughput, high efficiency spectrometer system has been developed to measure impurity ion temperature and toroidal velocity fluctuations associated with long-wavelength turbulence and other plasma instabilities. The spectrometer observes the emission of the n= 8-7 hydrogenic transition of C{sup +5} ions ({lambda}{sub air}= 529.06 nm) resulting from charge exchange reactions between deuterium heating beams and intrinsic carbon. Novel features include a large, prism-coupled high-dispersion, volume-phase-holographic transmission grating and high-quantum efficiency, high-gain, low-noise avalanche photodiode detectors that sample emission at 1 MHz. This new diagnostic offers an order-of-magnitude increase in sensitivity compared to earlier ion thermal turbulence measurements. Increased sensitivity is crucial for obtaining enough photon statistics from plasmas with much less impurity content. The irreducible noise floor set by photon statistics sets the ultimate sensitivity to plasma fluctuations. Based on the measured photon flux levels for the entire spectral line, photon noise levels for T(tilde sign){sub i}/T{sub i} and V(tilde sign){sub i}/V{sub i} of {approx}1% are expected, while statistical averaging over long data records enables reduction in the detectable plasma fluctuation levels to values less than that. Broadband ion temperature fluctuations are observed to near 200 kHz in an L-mode discharge. Cross-correlation with the local beam emission spectroscopy measurements demonstrates a strong coupling of the density and temperature fields, and enables the cross-phase measurements between density and ion temperature fluctuations.

Uzun-Kaymak, I. U.; Fonck, R. J.; McKee, G. R. [Department of Engineering Physics, University of Wisconsin, Madison, Wisconsin 53706 (United States)

2012-10-15T23:59:59.000Z

128

Core-ion temperature measurement of the ADITYA tokamak using passive charge exchange neutral particle energy analyzer  

SciTech Connect (OSTI)

Core-ion temperature measurements have been carried out by the energy analysis of passive charge exchange (CX) neutrals escaping out of the ADITYA tokamak plasma (minor radius, a= 25 cm and major radius, R= 75 cm) using a 45 Degree-Sign parallel plate electrostatic energy analyzer. The neutral particle analyzer (NPA) uses a gas cell configuration for re-ionizing the CX-neutrals and channel electron multipliers (CEMs) as detectors. Energy calibration of the NPA has been carried out using ion-source and {Delta}E/E of high-energy channel has been found to be {approx}10%. Low signal to noise ratio (SNR) due to VUV reflections on the CEMs was identified during the operation of the NPA with ADITYA plasma discharges. This problem was rectified by upgrading the system by incorporating the additional components and arrangements to suppress VUV radiations and improve its VUV rejection capabilities. The noise rejection capability of the NPA was experimentally confirmed using a standard UV-source and also during the plasma discharges to get an adequate SNR (>30) at the energy channels. Core-ion temperature T{sub i}(0) during flattop of the plasma current has been measured to be up to 150 eV during ohmically heated plasma discharges which is nearly 40% of the average core-electron temperature (typically T{sub e}(0) {approx} 400 eV). The present paper describes the principle of tokamak ion temperature measurement, NPA's design, development, and calibration along with the modifications carried out for minimizing the interference of plasma radiations in the CX-spectrum. Performance of the NPA during plasma discharges and experimental results on the measurement of ion-temperature have also been reported here.

Pandya, Santosh P.; Ajay, Kumar; Mishra, Priyanka; Dhingra, Rajani D.; Govindarajan, J. [Institute for Plasma Research, Bhat, Gandhinagar 382 428, Gujarat (India)

2013-02-15T23:59:59.000Z

129

Investigation of the effect of intra-molecular interactions on the gas-phase conformation of peptides as probed by ion mobility-mass spectrometry, gas-phase hydrogen/deuterium exchange, and molecular mechanics  

E-Print Network [OSTI]

-phase H/D ion molecule reactions that alkali adducted species exchange slower and to a lesser extent than protonated species in the tyrosine- and arginine-containing peptides. Experimental and computational results are discussed in terms of peptide ion...

Sawyer, Holly Ann

2006-04-12T23:59:59.000Z

130

Phase transition upon K{sup +} ion exchange into Na-low silica X: Combined NMR and synchrotron X-ray powder diffraction study  

SciTech Connect (OSTI)

The mechanism by which K{sup +} ions exchange into zeolite Na-low silica X (LSX) (Na{sub 96}Al{sub 96}Si{sub 96}O{sub 384}{center_dot}nH{sub 2}O) has ben determined by studying structures of the Na-LSX and K-LSX end members in the Na-K LSX solid solution series as well as samples exchanged at the 20%, 42% and 80% K{sup +} levels. A preliminary investigation using {sup 29}Si MAS NMR spectroscopy revealed a two-phase region in the solid solution near 80% K{sup +} exchange. Rietveld analysis of the powder diffraction data collected from hydrated samples showed that, up to 42% of K{sup +} exchange, K{sup +} ions were located preferentially at site I{prime}, just outside the double 6-ring (D6R) in the sodalite age, and at site II, above the single 6-ring (S6R) in the supercage. Introduction of K{sup +} ions into site I{prime} repositioned Na{sup +} ions into site I, at the center of the D6R. An abrupt change in the cubic lattice parameter from 25.0389(5) to 25.2086(5) {angstrom} marked the formation of a second phase at the 80% K{sup +}-exchange level as K{sup +} ions began to occupy site I. No coexistence of phases was observed for the fully K{sup +}-exchanged sample (a = 25.2486(2) {angstrom}), where sites I and II were fully occupied by K{sup +} ions.

Lee, Y.; Parise, J.B. [State Univ. of New York, Stony Brook, NY (United States)] [State Univ. of New York, Stony Brook, NY (United States); Carr, S.W. [ANSTO, Menai (Australia)] [ANSTO, Menai (Australia)

1998-09-01T23:59:59.000Z

131

Fractionation of NaCl, MgCl2, and CaCl2 brines with a polyfunctional ion exchange resin  

E-Print Network [OSTI]

softening, demineralizat1on, or sim1lar processes in which the objective is to remove undesirable 1ons. Ion exchange as a separation technique, that 1s, the recovery of two or more 1ons, has become 1ncreas1ngly important. Mayer and Tompk1ns (12.... Phys. 20, 1657 (1952). 11. McIlhenny, W. F. , M. S. Thesis, Texas A. and M. College (1958). 12 . Mayer, S. W. , Tompkins, E. R. , J. Am. Chem. Soc . 69, 2866 ( 1947) 1$. Nachod, F. C. , Schubert, J. , Ion Exchange Technolo Academic Press, N ew York...

Baker, Albert Byre

1959-01-01T23:59:59.000Z

132

Ion exchange behavior among metal trisilicates: probing selectivity, structures, and mechanism  

E-Print Network [OSTI]

of the octahedral metal. The substitution of Ge for Si can also increase the pore size. A variety of cations have been exchanged into the trisilicates including alkali and alkaline earths, lanthanides, and actinides. The reason for the selectivity rests... the complexities of inorganic synthesis and gained the confidence to know that I can synthesize anything. I would like to acknowledge Dr. Sharath Kirumakki. He has been a valuable colleague and advisor throughout my endeavors at A&M. Above all...

Fewox, Christopher Sean

2008-10-10T23:59:59.000Z

133

Method for digesting spent ion exchange resins and recovering actinides therefrom using microwave radiation  

DOE Patents [OSTI]

The present invention relates to methods for digesting diphosphonic acid substituted cation exchange resins that have become loaded with actinides, rare earth metals, or heavy metals, in a way that allows for downstream chromatographic analysis of the adsorbed species without damage to or inadequate elution from the downstream chromatographic resins. The methods of the present invention involve contacting the loaded diphosphonic acid resin with concentrated oxidizing acid in a closed vessel, and irradiating this mixture with microwave radiation. This efficiently increases the temperature of the mixture to a level suitable for digestion of the resin without the use of dehydrating acids that can damage downstream analytical resins. In order to ensure more complete digestion, the irradiated mixture can be mixed with hydrogen peroxide or other oxidant, and reirradiated with microwave radiation.

Maxwell, III, Sherrod L. (Aiken, SC); Nichols, Sheldon T. (Augusta, GA)

1999-01-01T23:59:59.000Z

134

Preliminary Ion Exchange Modeling for Removal of Cesium from Hanford Waste Using SuperLig 644 Resin  

SciTech Connect (OSTI)

A proposed facility is being designed for the immobilization of Hanford high-level radioactive waste. One unit process in the facility is designed to remove radioactive cesium by ion-exchange from the strongly alkaline aqueous phase. A resin specifically designed with high selectivity of cesium under alkaline conditions is being investigated. The resin also is elutable under more acidic conditions. The proposed design of the facility consists of two sets of two packed columns placed in series (i.e., a lead column followed by a lag (guard) column configuration). During operation, upon reaching a specified cesium concentration criterion at the exit of the lag column, operation is switched to the second set of lead and lag columns. The cesium-loaded lead column is processed (i.e., washed and eluted) and switched to the lag position. the previous lag column is then placed in the lead position (without eluting) and the system is ready for use in the next cycle. For a well designed process, the loading and elution processes result in significant volume reductions in aqueous high-level waste.

Hamm, L.L.

2000-08-23T23:59:59.000Z

135

Ion-pairing dynamics of Li{sup +} and SCN{sup -} in dimethylformamide solution: Chemical exchange two-dimensional infrared spectroscopy  

SciTech Connect (OSTI)

Ultrafast two-dimensional infrared (2DIR) spectroscopy has been proven to be an exceptionally useful method to study chemical exchange processes between different vibrational chromophores under thermal equilibria. Here, we present experimental results on the thermal equilibrium ion pairing dynamics of Li{sup +} and SCN{sup -} ions in N,N-dimethylformamide. Li{sup +} and SCN{sup -} ions can form a contact ion pair (CIP). Varying the relative concentration of Li{sup +} in solution, we could control the equilibrium CIP and free SCN{sup -} concentrations. Since the CN stretch frequency of Li-SCN CIP is blue-shifted by about 16 cm{sup -1} from that of free SCN{sup -} ion, the CN stretch IR spectrum is a doublet. The temperature-dependent IR absorption spectra reveal that the CIP formation is an endothermic (0.57 kJ/mol) process and the CIP state has larger entropy by 3.12 J/(K mol) than the free ion states. Since the two ionic configurations are spectrally distinguishable, this salt solution is ideally suited for nonlinear IR spectroscopic investigations to study ion pair association and dissociation dynamics. Using polarization-controlled IR pump-probe methods, we first measured the lifetimes and orientational relaxation times of these two forms of ionic configurations. The vibrational population relaxation times of both the free ion and CIP are about 32 ps. However, the orientational relaxation time of the CIP, which is {approx}47 ps, is significantly longer than that of the free SCN{sup -}, which is {approx}7.7 ps. This clearly indicates that the effective moment of inertia of the CIP is much larger than that of the free SCN{sup -}. Then, using chemical exchange 2DIR spectroscopy and analyzing the diagonal peak and cross-peak amplitude changes with increasing the waiting time, we determined the contact ion pair association and dissociation time constants that are found to be 165 and 190 ps, respectively. The results presented and discussed in this paper are believed to be important, not only because the ion-pairing dynamics is one of the most fundamental physical chemistry problems but also because such molecular ion-ion interactions are of critical importance in understanding Hofmeister effects on protein stability.

Lee, Kyung-Koo; Park, Kwang-Hee; Kwon, Donghyun; Choi, Jun-Ho; Son, Hyewon [Department of Chemistry, Research Institute for Natural Sciences, Korea University, Seoul 136-701 (Korea, Republic of); Park, Sungnam; Cho, Minhaeng [Department of Chemistry, Research Institute for Natural Sciences, Korea University, Seoul 136-701 (Korea, Republic of); Multidimensional Spectroscopy Laboratory, Korea Basic Science Institute, Seoul 136-713 (Korea, Republic of)

2011-02-14T23:59:59.000Z

136

Preliminary flowsheet: Ion exchange process for the separation of cesium from Hanford tank waste using Duolite{trademark} CS-100 resin  

SciTech Connect (OSTI)

This preliminary flowsheet document describes an ion exchange process which uses Duolite{trademark} CS-100 resin to remove cesium from Hanford Tank waste. The flowsheet describes one possible equipment configuration, and contains mass balances based on that configuration with feeds of Neutralized Current Acid Waste, and Double Shell Slurry Feed. Process alternatives, unresolved issues, and development needs are discussed which relate to the process.

Eager, K.M.; Penwell, D.L.; Knutson, B.J.

1994-12-01T23:59:59.000Z

137

Efficiencies and Optimization of Weak Base Anion Ion-Exchange Resin for Groundwater Hexavalent Chromium Removal at Hanford  

SciTech Connect (OSTI)

The U.S. Department of Energy’s (DOE’s) contractor, CH2M HILL Plateau Remediation Company, has successfully converted a series of groundwater treatment facilities to use a new treatment resin that is delivering more than $3 million in annual cost savings and efficiency in treating groundwater contamination at the DOE Hanford Site in southeastern Washington State. During the production era, the nuclear reactors at the Hanford Site required a continuous supply of high-quality cooling water during operations. Cooling water consumption ranged from about 151,417 to 378,541 L/min (40,000 to 100,000 gal/min) per reactor, depending on specific operating conditions. Water from the Columbia River was filtered and treated chemically prior to use as cooling water, including the addition of sodium dichromate as a corrosion inhibitor. Hexavalent chromium was the primary component of the sodium dichromate and was introduced into the groundwater at the Hanford Site as a result of planned and unplanned discharges from the reactors starting in 1944. Groundwater contamination by hexavalent chromium and other contaminants related to nuclear reactor operations resulted in the need for groundwater remedial actions within the Hanford Site reactor areas. Beginning in 1995, groundwater treatment methods were evaluated, leading to the use of pump-and-treat facilities with ion exchange using Dowex™ 21K, a regenerable, strong-base anion exchange resin. This required regeneration of the resin, which was performed offsite. In 2008, DOE recognized that regulatory agreements would require significant expansion for the groundwater chromium treatment capacity. As a result, CH2M HILL performed testing at the Hanford Site in 2009 and 2010 to demonstrate resin performance in the specific groundwater chemistry at different waste sites. The testing demonstrated that a weak-base anion, single-use resin, specifically ResinTech SIR-700 ®, was effective at removing chromium, had a significantly higher capacity, could be disposed of efficiently onsite, and would eliminate the complexities and programmatic risks from sampling, packaging, transportation, and return of resin for regeneration.

Nesham, Dean O. [CH2M HILL Plateau Remediation Company, Richland, WA (United States); Ivarson, Kristine A. [CH2M HILL Plateau Remediation Company, Richland, WA (United States); Hanson, James P. [CH2M HILL Plateau Remediation Company, Richland, WA (United States); Miller, Charles W. [CH2M HILL Plateau Remediation Company, Richland, WA (United States); Meyers, P. [USDOE, Richland Operations Office, WA (United States); Jaschke, Naomi M. [USDOE, Richland Operations Office, WA (United States)

2014-02-03T23:59:59.000Z

138

Development and implementation of a FT-ICR mass spectrometer for the investigation of ion conformations of peptide sequence isomers containing basic amino acid residues by gas-phase hydrogen/deuterium exchange  

E-Print Network [OSTI]

The gas-phase hydrogen/deuterium (H/D) exchange of protonated di- and tripeptides containing a basic amino acid residue has been studied with a Fourier transform ion cyclotron resonance (FT-ICR) mass spectrometer. Bimolecular reactions...

Marini, Joseph Thomas

2004-09-30T23:59:59.000Z

139

Transition Path Sampling of Water Exchange Rates and Mechanisms...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Path Sampling of Water Exchange Rates and Mechanisms around Aqueous Ions . Transition Path Sampling of Water Exchange Rates and Mechanisms around Aqueous Ions . Abstract: The rates...

140

Fiscal year 1997 final report for task plan SR-16WT-31 task B, vitrification of ion exchange material  

SciTech Connect (OSTI)

In Fiscal Year 1997, the Department of Energy Tanks Focus Area (TFA) funded the Savannah River Technology Center (SRTC) to develop and demonstrate the vitrification of a CST ion exchange material loaded with radioactive cesium from one of the Melton Valley Storage Tanks at the Oak Ridge National Laboratory (ORNL). SRTC developed a patent-pending glass formulation that can be used to vitrify CST sorbent producing a quality borosilicate glass waste form. SRTC demonstrated this formulation by vitrifying the radioactive CST in the SRTC shielded cells melter.In addition to the formulation developed for vitrification of the `CST-only` glass waste form, SRTC also developed formulations for vitrification of CST coupled with High-Level Waste (HLW) sludges. A Defense Waste Processing Facility (DWPF) coupled feed formulation has been developed with up to 10 weight percent CST and 28 weight percent DWPF sludge oxides. A coupled Hanford formulation has also been developed for producing quality glass waste forms with up to 10 weight percent CST and 45 weight percent Hanford sludge oxides. The significant accomplishments of this project were then development of CST-only glass formulations incorporating up to 65 weight-percent CST, development of techniques for delivering a slurry or dry feed to a joule-heated melter, demonstration of a CST-only glass formulation in a continuous melter operation, demonstration of compliance with the Nevada Test Site (NTS) Waste Acceptance Criteria (WAC), development of CST-sludge glass formulations incorporating up to 10 weight percent CST and 28 weight percent DWPF sludges oxides, demonstration of CST-sludge glass formulations using radioactive sludge and radioactive CST, development of CST-sludge glass formulations incorporating up to 10 weight percent CST and 45 weight percent. All commitments made to the TFA have been met as indicated by the associated milestones. Milestones and the month in which they were completed: Initiate Immobilization of CST in Glass (completed 8/97); Demonstrate that Sludge-CST Glass Satisfied PC Specs in WAPS (completed 9/97); Determine Process Parameters of Sludge-CST Glass (completed 8/97); Demonstrate that CST-Only Glass Satisfied PC Specs in WAPS (completed 9/97); Determine Process Parameters of CST-Only Glass (completed 9/97). The results for Task B of Task Plan SR-16WT-31 have been documented in reports that have been included as attachments. The following is a summary of the attachments from the CST vitrification project.

Ferrara, D.; Andrews, M.K.; Harbour, J.R.; Fellinger, T.L.; Herman, D.T.; Marshall, K.M.; Workman, P.J.

1997-09-30T23:59:59.000Z

Note: This page contains sample records for the topic "ion exchange ix" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

CsIX/TRU Grout Feasibility Study  

SciTech Connect (OSTI)

A settlement agreement between the Department of Energy (DOE) and the State of Idaho mandates that liquid waste now stored at the Idaho Nuclear Technology Engineering Center (INTEC - formerly the Idaho Chemical Processing Plant, ICPP) will be calcined by the end of year 2012. This study investigates an alternative treatment of the liquid waste that removes undissolved solids (UDS) by filtration and removes cesium by ion exchange followed by cement-based grouting of the remaining liquid into 55-gal drums. Operations are assumed to be from January 2008 through December 2012. The grouted waste will be contact-handled and will be shipped to the Waste Isolation Pilot Plant (WIPP) in New Mexico for disposal. The small volume of secondary wastes such as the filtered solids and cesium sorbent (resin) would remain in storage at the Idaho National Engineering and Environmental Laboratory for treatment and disposal under another project, with an option to dispose of the filtered solids as a r emote-handled waste at WIPP.

S. J. Losinski; C. M. Barnes; B. K. Grover

1998-11-01T23:59:59.000Z

142

PROJECTS FROM FEDERAL REGION IX DEPARTMENT OF ENERGY APPROPRIATE ENERGY TECHNOLOGY PROGRAM PART II  

E-Print Network [OSTI]

Appropriate Energy Technology Resource Center .IX DOE Appropriate Energy Technology Pilot Program - PartIX DOE Appropriate Energy Technology Pilot Program - Part I;

Case, C.W.

2012-01-01T23:59:59.000Z

143

CdS and CdS/CdSe sensitized ZnO nanorod array solar cells prepared by a solution ions exchange process  

SciTech Connect (OSTI)

Graphical abstract: - Highlights: • CdS and CdS/CdSe quantum dots are assembled on ZnO nanorods by ion exchange process. • The CdS/CdSe sensitization of ZnO effectively extends the absorption spectrum. • The performance of ZnO/CdS/CdSe cell is improved by extending absorption spectrum. - Abstract: In this paper, cadmium sulfide (CdS) and cadmium sulfide/cadmium selenide (CdS/CdSe) quantum dots (QDs) are assembled onto ZnO nanorod arrays by a solution ion exchange process for QD-sensitized solar cell application. The morphology, composition and absorption properties of different photoanodes were characterized with scanning electron microscope, transmission electron microscope, energy-dispersive X-ray spectrum and Raman spectrum in detail. It is shown that conformal and uniform CdS and CdS/CdSe shells can grow on ZnO nanorod cores. Quantum dot sensitized solar cells based on ZnO/CdS and ZnO/CdS/CdSe nanocable arrays were assembled with gold counter electrode and polysulfide electrolyte solution. The CdS/CdSe sensitization of ZnO can effectively extend the absorption spectrum up to 650 nm, which has a remarkable impact on the performance of a photovoltaic device by extending the absorption spectrum. Preliminary results show one fourth improvement in solar cell efficiency.

Chen, Ling; Gong, Haibo; Zheng, Xiaopeng; Zhu, Min; Zhang, Jun [Key Laboratory of Inorganic Functional Materials in Universities of Shandong, School of Materials Science and Engineering, University of Jinan, Jinan 250022, Shandong (China); Yang, Shikuan [Department of Engineering Science and Mechanics, The Pennsylvania State University, University Park, PA 16802-6812 (United States); Cao, Bingqiang, E-mail: mse_caobq@ujn.edu.cn [Key Laboratory of Inorganic Functional Materials in Universities of Shandong, School of Materials Science and Engineering, University of Jinan, Jinan 250022, Shandong (China)

2013-10-15T23:59:59.000Z

144

Calcite dissolution and Ca/Na ion-exchange reactions in columns with different flow rates through high ESR soil  

E-Print Network [OSTI]

min?¹ under conditions of saturated flow. Column eluate was monitored for pH, carbonate alkalinity, and Na, Ca and Cl concentrations to evaluate the elution of SAR 10 solution, dissolution of CaCO? and exchange of Na by Ca on the cation...

Navarre, Audrey

1999-01-01T23:59:59.000Z

145

Ares I-X 30 Day ReportAres I-X 30 Day Report Bob Ess, Mission Manager  

E-Print Network [OSTI]

Ares I-X 30 Day ReportAres I-X 30 Day Report Bob Ess, Mission Manager Marshall Smith, SE&I Chief Bob Ess, Mission Manager Marshall Smith, SE&I Chief December 3, 2009December 3, 2009 www.nasa.gov #12

Waliser, Duane E.

146

Determination of platinum and palladium in geologic samples by ion exchange chromatography with inductively coupled plasma atomic emission spectrometric detection  

SciTech Connect (OSTI)

An alternative procedure to the classical fire assay method for determining Pt and Pd in sulfide ores, concentrates, and furnace mattes is presented. A suitable amount of sample is digested with aqua regla and filtered and any remaining gangue is digested with a mixture of HF and HClO/sub 4/. The solution is filtered and the residue fused with sodium peroxide granules. The fused salts are dissolved in a dilute HCl acid solution and all three solutions combined. The resultant solution is passed through a Bio-Rad AG 50W-X8 cation exchange resin in the H/sup +/ form. The chlorocomplex anions of Pt and Pd are not retained by the cation exchange resin while the base metal cations are efficiently removed from the eluent. Pt and Pd concentrations are subsequently determined with an inductively coupled plasma (ICP). Preliminary experiments showing the method's potential expandability to Au are included.

Brown, R.J.; Biggs, W.R.

1984-04-01T23:59:59.000Z

147

Ion Exchange Studies for Removal of Sulfate from Hanford Tank Waste Envelope C (241-AN-107) Using SuperLig 655 Resin  

SciTech Connect (OSTI)

BNFL Inc. is evaluating various pretreatment technologies to mitigate the impacts of sulfate on the LAW vitrification system. One pretreatment technology for separating sulfate from LAW solutions involves the use of SuperLig{reg_sign} 655 (SL-655), a proprietary ion exchange material developed and supplied by IBC Advanced Technologies, Inc., American Fork, UT. This report describes testing of SL-655 with diluted ([Na] {approximately} 5 M) waste from Hanford Tank 241-AN-107 at Battelle, Pacific Northwest Division. Batch contact studies were conducted from 4 to 96 hours to determine the sulfate distribution coefficient and reaction kinetics. A small-scale ion exchange column test was conducted to evaluate sulfate removal, loading, breakthrough, and elution from the SL-655. In all of these tests, an archived 241-AN-107 tank waste sample (pretreated to remove Cs, Sr, and transuranics elements) was used. The experimental details and results are described in this report. Under the test conditions, SL-655 was found to have no significant ion exchange affinity for sulfate in this matrix. The batch contact study resulted in no measurable difference in the aqueous sulfate concentration following resin contact (K{sub d} {approximately} 0). The column test also demonstrated SL-655 had no practical affinity for sulfate in the tested matrix. Within experimental error, the sulfate concentration in the column effluent was equal to the concentration in the feed after passing 3 bed volumes of sample through the columns. Furthermore, some, if not all, of the decreased sulfate concentration in these first three column volumes of effluent can be ascribed to mixing and dilution of the 241-AN-107 feed with the interstitial liquid present in the column at the start of the loading cycle. Finally, ICP-AES measurements on the eluate solutions showed the presence of barium as soon as contact with the feed solution is completed. Barium is a metal not detected in the feed solution. Should the loss of barium be correlated with the resin's ability to selectively complex sulfate, then maintaining even the current limited resin characteristics for sulfate complexation over multiple cycles becomes questionable.

DE Kurath; JR Bontha; DL Blanchard; SK Fiskum; BM Rapko

2000-08-23T23:59:59.000Z

148

Experimental data and analysis to support the design of an ion-exchange process for the treatment of Hanford tank waste supernatant liquids  

SciTech Connect (OSTI)

Hanford`s 177 underground storage tanks contain a mixture of sludge, salt cake, and alkaline supernatant liquids. Disposal options for these wastes are high-level waste (HLW) glass for disposal in a repository or low-level waste (LLW) glass for onsite disposal. Systems-engineering studies show that economic and environmental considerations preclude disposal of these wastes without further treatment. Difficulties inherent in transportation and disposal of relatively large volumes of HLW make it impossible to vitrify all of the tank waste as HLW. Potential environmental impacts make direct disposal of all of the tank waste as LLW glass unacceptable. Although the pretreatment and disposal requirements are still being defined, most pretreatment scenarios include retrieval of the aqueous liquids, dissolution of the salt cakes, and washing of the sludges to remove soluble components. Most of the cesium is expected to be in the aqueous liquids, which are the focus of this report on cesium removal by ion exchange. The main objectives of the ion-exchange process are removing cesium from the bulk of the tank waste (i.e., decontamination) and concentrating the separated cesium for vitrification. Because exact requirements for removal of {sup 137}Cs have not yet been defined, a range of removal requirements will be considered. This study addresses requirements to achieve {sup 137}Cs levels in LLW glass between (1) the Nuclear Regulatory Commission (NRC) Class C (10 CFR 61) limit of 4600 Ci/m{sup 3} and (2) 1/10th of the NRC Class A limit of 1 Ci/m{sup 3} i.e., 0.1/m{sup 3}. The required degrees of separation of cesium from other waste components is a complex function involving interactions between the design of the vitrification process, waste form considerations, and other HLW stream components that are to be vitrified.

Kurath, D.E.; Bray, L.A.; Brooks, K.P.; Brown, G.N.; Bryan, S.A.; Carlson, C.D.; Carson, K.J.; DesChane, J.R.; Elovich, R.J.; Kim, A.Y.

1994-12-01T23:59:59.000Z

149

Nonlinear ion concentration polarization : fundamentals and applications  

E-Print Network [OSTI]

Ion exchange membrane (IEM) is a functional material that has a permselectivity of ions. Two types of IEMs - anion exchange membrane (AEM) and cation exchange membrane (CEM) - are used in a variety of electrochemical ...

Kwak, Rhokyun

2013-01-01T23:59:59.000Z

150

Anisotropic Bianchi types VIII and IX locally rotationally symmetric cosmologies  

SciTech Connect (OSTI)

We present a class of exact cosmological solutions of Einstein-Maxwell equations, which are anisotropic and spatially homogeneous of Bianchi types VIII and IX, and class IIIb in the Stewart-Ellis classification of locally rotationally symmetric models. If we take the electromagnetic field equal to zero, a class of Bianchi types VIII/IX spatially homogeneous anisotropic cosmological solutions with perfect fluid is obtained.

Assad, M.J.D.; Soares, I.D.

1983-10-15T23:59:59.000Z

151

Synthesis and Evaluation of Cu/SAPO-34 Catalysts for NH3-SCR 2: Solid-state Ion Exchange and One-pot Synthesis  

SciTech Connect (OSTI)

Cu-SAPO-34 catalysts are synthesized using two methods: solid-state ion exchange (SSIE) and one-pot synthesis. SSIE is conducted by calcining SAPO-34/CuO mixtures at elevated temperatures. For the one-pot synthesis method, Cu-containing chemicals (CuO and CuSO4) are added during gel preparation. A high-temperature calcination step is also needed for this method. Catalysts are characterized with surface area/pore volume measurements, temperature programmed reduction (TPR), electron paramagnetic resonance (EPR) and nuclear magnetic resonance (NMR) spectroscopies, and scanning electron microscopy (SEM). Catalytic properties are examined using standard ammonia selective catalytic reduction (NH3-SCR) and ammonia oxidation reactions. In Cu-SAPO-34 samples formed using SSIE, Cu presents both as isolated Cu2+ ions and unreacted CuO. The former is highly active and selective in NH3-SCR, while the latter catalyzes a side reaction; notably, the non-selective oxidation of NH3 above 350 ºC. Using the one-pot method followed by a high-temperature aging treatment, it is possible to form Cu SAPO-34 samples with predominately isolated Cu2+ ions at low Cu loadings. However at much higher Cu loadings, isolated Cu2+ ions that bind weakly with the CHA framework and CuO clusters also form. These Cu moieties are very active in catalyzing non-selective NH3 oxidation above 350 ºC. Low-temperature reaction kinetics indicate that Cu-SAPO-34 samples formed using SSIE have core-shell structures where Cu is enriched in the shell layers; while Cu is more evenly distributed within the one-pot samples. Reaction kinetics also suggest that at low temperatures, the local environment next to Cu2+ ion centers plays little role on the overall catalytic properties. The authors gratefully acknowledge the US Department of Energy (DOE), Energy Efficiency and Renewable Energy, Vehicle Technologies Office for the support of this work. The research described in this paper was performed at the Environmental Molecular Sciences Laboratory (EMSL), a national scientific user facility sponsored by the DOE’s Office of Biological and Environmental Research and located at Pacific Northwest National Laboratory (PNNL). PNNL is operated for the US DOE by Battelle under contract number DE-AC05-76RL01830. The authors also thank Shari Li (PNNL) for surface area/pore volume measurements, and Bruce W. Arey (PNNL) for SEM measurements. Discussions with Drs. A. Yezerets, K. Kamasamudram, J.H. Li, N. Currier and J.Y. Luo from Cummins, Inc. and H.Y. Chen and H. Hess from Johnson-Matthey are greatly appreciated.

Gao, Feng; Walter, Eric D.; Washton, Nancy M.; Szanyi, Janos; Peden, Charles HF

2015-01-01T23:59:59.000Z

152

Enhancement of exchange bias and training effect in ion-beam sputtered Fe{sub 46}Mn{sub 54}/Ni{sub 81}Fe{sub 19} bilayers  

SciTech Connect (OSTI)

We present a remarkable enhancement by 300% of the exchange-bias field at room temperature, without affecting the coercivity value, via optimum magnetic annealing (250?°C/3 kOe) in ion-beam sputtered FeMn(30?nm)/NiFe(10?nm) bilayers. This specific behavior has been attributed to a higher degree of ?-FeMn(111) orientation that offers more interfacial FeMn moments to get pinned with the moments of the adjacent NiFe layer. Unlike the absence of training effect at room temperature, a pronounced training effect and an accompanying magnetization reversal asymmetry are evidenced upon field cooling below 50?K due to the presence of biaxial exchange induced anisotropy across the interdiffused FeMn/NiFe interface. The present findings not only have technological significance but also are of relevance to the understanding of interfacial spin disorder and frustration in these exchange-biased systems.

Fulara, Himanshu; Chaudhary, Sujeet, E-mail: sujeetc@physics.iitd.ac.in; Kashyap, Subhash C. [Thin Film Laboratory, Department of Physics, Indian Institute of Technology Delhi, New Delhi 110016 (India); Granville, Simon [Callaghan Innovation, PO Box 31310, Lower Hutt 5040 (New Zealand); The MacDiarmid Institute for Advanced Materials and Nanotechnology, Lower Hutt (New Zealand)

2014-01-28T23:59:59.000Z

153

Anion exchange membrane  

DOE Patents [OSTI]

An anion exchange membrane and fuel cell incorporating the anion exchange membrane are detailed in which proazaphosphatrane and azaphosphatrane cations are covalently bonded to a sulfonated fluoropolymer support along with anionic counterions. A positive charge is dispersed in the aforementioned cations which are buried in the support to reduce the cation-anion interactions and increase the mobility of hydroxide ions, for example, across the membrane. The anion exchange membrane has the ability to operate at high temperatures and in highly alkaline environments with high conductivity and low resistance.

Verkade, John G; Wadhwa, Kuldeep; Kong, Xueqian; Schmidt-Rohr, Klaus

2013-05-07T23:59:59.000Z

154

A simplified methodology for sizing ground coupled heat pump heat exchangers in cooling dominated climates  

E-Print Network [OSTI]

between GSIM and two commercially available heat exchanger sizing methods, the National Water Well Association (NWWA) and the International Ground Source Heat Pump Association (IGSHPA) methods, was performed. GSIM heat exchanger lengths for Dallas were... Pump Capacity and Cooling Load. . . . . Oversizing and Undersizing the Heat Pump. . . . . . . . . . . . . . Summary. . 72 74 76 78 80 82 85 87 90 92 IX COMPARISON OF HEAT EXCHANGER SIZING METHODS . . 93 International Ground Source Heat...

Gonzalez, Jose Antonio

1993-01-01T23:59:59.000Z

155

SELECTIVE REMOVAL OF STRONTIUM AND CESIUM FROM SIMULATED WASTE SOLUTION WITH TITANATE ION-EXCHANGERS IN A FILTER CARTRIDGE CONFIGURATIONS-12092  

SciTech Connect (OSTI)

Experimental results for the selective removal of strontium and cesium from simulated waste solutions with monosodium titanate (MST) and crystalline silicotitanate (CST) laden filter cartridges are presented. In these proof-of-principle tests, effective uptake of both Sr-85 and Cs-137 were observed using ion-exchangers in this filter cartridge configuration. At low salt simulant conditions, the instantaneous decontamination factor (D{sub F}) for Sr-85 with MST impregnated filter membrane cartridges measured 26, representing 96% Sr-85 removal efficiency. On the other hand, the Sr-85 instantaneous D{sub F} with co-sintered active MST cartridges measured 40 or 98% Sr-85 removal efficiency. Strontium-85 removal with the MST impregnated membrane cartridges and CST impregnated membrane cartridges, placed in series arrangement, produced an instantaneous decontamination factor of 41 compared to an instantaneous decontamination factor of 368 for strontium-85 with co-sintered active MST cartridges and co-sintered active CST cartridges placed in series. Overall, polyethylene co-sintered active titanates cartridges performed as well as titanate impregnated filter membrane cartridges in the uptake of strontium. At low ionic strength conditions, there was a significant uptake of Cs-137 with co-sintered CST cartridges. Tests results with CST impregnated membrane cartridges for Cs-137 decontamination are currently being re-evaluated. Based on these preliminary findings we conclude that incorporating MST and CST sorbents into membranes represent a promising method for the semi-continuous removal of radioisotopes of strontium and cesium from nuclear waste solutions.

Oji, L.; Martin, K.; Hobbs, D.

2011-11-10T23:59:59.000Z

156

SELECTIVE REMOVAL OF STRONTIUM AND CESIUM FROM SIMULATED WASTE SOLUTION WITH TITANATE ION-EXCHANGERS IN A FILTER CARTRIDGE CONFIGURATIONS-12092  

SciTech Connect (OSTI)

Experimental results for the selective removal of strontium and cesium from simulated waste solutions with monosodium titanate and crystalline silicotitanate laden filter cartridges are presented. In these proof-of-principle tests, effective uptake of both strontium-85 and cesium-137 were observed using ion-exchangers in this filter cartridge configuration. At low salt simulant conditions, the instantaneous decontamination factor for strontium-85 with monosodium titanate impregnated filter membrane cartridges measured 26, representing 96% strontium-85 removal efficiency. On the other hand, the strontium-85 instantaneous decontamination factor with co-sintered active monosodium titanate cartridges measured 40 or 98% Sr-85 removal efficiency. Strontium-85 removal with the monosodium titanate impregnated membrane cartridges and crystalline silicotitanate impregnated membrane cartridges, placed in series arrangement, produced an instantaneous decontamination factor of 41 compared to an instantaneous decontamination factor of 368 for strontium-85 with co-sintered active monosodium titanate cartridges and co-sintered active crystalline silicotitanate cartridges placed in series. Overall, polyethylene co-sintered active titanates cartridges performed as well as titanate impregnated filter membrane cartridges in the uptake of strontium. At low ionic strength conditions, there was a significant uptake of cesium-137 with co-sintered crystalline silicotitanate cartridges. Tests results with crystalline silicotitanate impregnated membrane cartridges for cesium-137 decontamination are currently being re-evaluated. Based on these preliminary findings we conclude that incorporating monosodium titanate and crystalline silicotitanate sorbents into membranes represent a promising method for the semicontinuous removal of radioisotopes of strontium and cesium from nuclear waste solutions.

Oji, L.; Martin, K.; Hobbs, D.

2012-01-03T23:59:59.000Z

157

IX. Standards for Student Organizations Standards of all Student Organizations  

E-Print Network [OSTI]

1 of 8 IX. Standards for Student Organizations Standards of all Student Organizations As stated to the same standards of conduct to which students are held on an individual basis. Standards for Fraternities on February 25, 1976 - the University has developed the following standards for fraternity/sorority life

Marsh, David

158

Visual Information Systems Chapter IX: Introduction to Virtual Reality 1  

E-Print Network [OSTI]

­ Semiology ­ Substitution of sensations Human Perception · Filtering · Air vibration (sounds, etc.) · Speed by humans becomes perceptible in the virtual physical world #12;Visual Information Systems Chapter IX Worlds · Representation of a virtual world ­ Choice of representation ­ Human perception ­ Likelihood

Laurini, Robert

159

E-Print Network 3.0 - americas ix final Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

IX & STEM: Promising Practices for science,technoLogy, engineering Source: NASA Ames Research Center, Vision Science and Technology Group Collection: Engineering 8 The Burke...

160

E-Print Network 3.0 - anhydrase ix correlates Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

ix correlates Page: << < 1 2 3 4 5 > >> 1 Prokaryotic carbonic anhydrases Kerry S. Smith *, James G. Ferry Summary: Prokaryotic carbonic anhydrases Kerry S. Smith *, James G....

Note: This page contains sample records for the topic "ion exchange ix" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

E-Print Network 3.0 - anhydrase ix biochemical Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

ix biochemical Page: << < 1 2 3 4 5 > >> 1 Prokaryotic carbonic anhydrases Kerry S. Smith *, James G. Ferry Summary: Prokaryotic carbonic anhydrases Kerry S. Smith *, James G....

162

RESIDENTIAL EXCHANGE  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

establishes the right of Pacific Northwest electric utilities to participate in the Residential Exchange Program that provides wholesale power cost benefits for residential and...

163

REMOVAL OF TECHNETIUM 99 FROM THE EFFLUENT TREATMENT FACILITY (ETF) BASIN 44 USING PUROLITE A-530E & REILLEX HPQ & SYBRON IONAC SR-7 ION EXCHANGE RESINS  

SciTech Connect (OSTI)

This report documents the laboratory testing and analyses as directed under the test plan, RPP-20407. The overall goal of this task was to evaluate and compare candidate anion exchange resins for their capacity to remove Technetium-99 from Basin 44 Reverse Osmosis reject stream. The candidate resins evaluated were Purolite A-530E, Reillex HPQ, and Sybron IONAC SR-7.

DUNCAN JB

2004-10-29T23:59:59.000Z

164

Simultaneous removal of organic matter and salt ions from saline wastewater in bioelectrochemical systems  

E-Print Network [OSTI]

in physical and chemical separation processes such as ion-exchange, electrodialysis, or reverse osmosis [1

165

ATTACHMENT IX Review of Air Products Fischer-Tropsch Synthesis Work  

E-Print Network [OSTI]

IX.1-Draft ATTACHMENT IX Review of Air Products Fischer-Tropsch Synthesis Work During the 1980s, Air Products & Chemicals worked on several aspects of the Fischer-Tropsch synthesis. These included, exhibited similar activity and product selectivity, showing that the preparative method was reproducible

Kentucky, University of

166

IMPACTS OF SMALL COLUMN ION EXCHANGE STREAMS ON DWPF GLASS FORMULATION: KT08, KT09, AND KT10-SERIES GLASS COMPOSITIONS  

SciTech Connect (OSTI)

This report is the fourth in a series of studies of the impacts of the addition of Crystalline Silicotitanate (CST) and Monosodium Titanate (MST) from the Small Column Ion Exchange (SCIX) process on the Defense Waste Processing Facility (DWPF) glass waste form and the applicability of the DWPF process control models. MST from the Salt Waste Processing Facility (SWPF) is also considered in the study. The KT08-series of glasses was designed to evaluate any impacts of the inclusion of uranium and thorium in glasses containing the SCIX components. The KT09-series of glasses was designed to study the effect of increasing Al{sub 2}O{sub 3} and K{sub 2}O concentrations on the propensity for crystallization of titanium containing phases in high TiO{sub 2} concentration glasses. Earlier work on the KT05-series glasses recommended that the impact of these two components be studied further. Increased Al{sub 2}O{sub 3} concentrations have been shown to improve the properties and performance of high waste loading glasses, and K{sub 2}O has been reported to improve the retention of TiO{sub 2} in silicate glasses. The KT10-series of compositions was designed to evaluate any impacts of the SCIX components at concentrations 50% higher than currently projected.a The glasses were fabricated in the laboratory and characterized to identify crystallization, to verify chemical compositions, to measure viscosity, and to measure durability. Liquidus temperature measurements for the KT10-series glasses are underway and will be reported separately. All but one of the KT08-series glasses were found to be amorphous by X-ray diffraction (XRD). One of the slowly cooled glasses contained a small amount of trevorite, which had no practical impact on the durability of the glass and is typically found in DWPF-type glasses. The measured Product Consistency Test (PCT) responses for the KT08-series glasses are well predicted by the DWPF models. The viscosities of the KT08-series glasses were generally well predicted by the DWPF model. No unexpected issues were encountered when uranium and thorium were added to the glasses with SCIX components. Increased Al{sub 2}O{sub 3} concentrations were not successful in preventing the formation of iron titanate crystals in the KT09-series glasses. Increased K{sub 2}O concentrations were successful in hindering the formation of iron titanates in some of the glasses after the canister centerline cooled (CCC) heat treatment. However, this result did not apply to all of the CCC versions of the glasses, indicating a compositional dependence of this effect. In addition, high concentrations of K{sub 2}O have been shown to hinder the ability of the DWPF durability and viscosity models to predict the performance of these glasses. The usefulness of increased K{sub 2}O concentrations in preventing the formation of iron titanates may therefore be limited. Further characterization was not performed for the KT09-series glasses since the type of crystallization formed was the characteristic of interest for these compositions. All of the KT10-series glasses were XRD amorphous, regardless of heat treatment. Chemical composition measurements showed that the glasses met the targeted concentrations for each oxide. In general, the measured PCT responses of the KT10-series glasses were well predicted by the DWPF models. The measured, normalized release values for silicon for some of the glasses fell above the 95% confidence interval for the predicted values; however, the PCT responses for these glasses remain considerably lower than that of the benchmark Environmental Assessment (EA) glass. The viscosities of the KT10-series glasses were generally well predicted by the DWPF model. The next step in this study will be to compile all of the data developed and further compare the measured properties and performance with those predicted by the current DWPF Product Composition Control System (PCCS) models. Recommendations will then be made as to which models, if any, may need to be modified in order to accommodate the material from SCIX into DWPF

Fox, K.; Edwards, T.

2011-04-26T23:59:59.000Z

167

Ion-exchanged pillared clays: A new class of catalysts for selective catalytic reduction of NO by hydrocarbons and by ammonia  

SciTech Connect (OSTI)

Selective catalytic reduction (SCR) of NO by NH{sub 3} is presently performed with vanadia-based catalysts for flue gas applications. Hydrocarbons would be the preferred reducing agents over NH{sub 3} because of the practical problems associated with the use of NH{sub 3} (i.e., handling and slippage through the reactor). SCR of NO by hydrocarbons can also find important applications for lean-burn (i.e., O{sub 2}-rich) gasoline and diesel engines where the noble-metal three-way catalysts are not effective in the presence of excess oxygen. Pillared interlayered clays (PILCs) have been studied extensively for a number of catalyzed reactions. We have found high activities of PILCs for SCR of NO by NH{sub 3} (26.28). Pillared clays have considerable Bronsted acidity (27, 28), and the protons can be exchanged with metal cations. The Bronsted acidity of TiO{sub 2}-PILC, in particular, remains high after heat treatment at temperatures as high as 400{degrees}C (27-29). In this note, we report first results on the activities of cation-exchanged pillared clays for SCR of NO by both hydrocarbon and NH{sub 3}. 37 refs., 3 figs.

NONE

1995-09-01T23:59:59.000Z

168

Cogniie, Creier, Comportament / Cognition, Brain, Behavior Vol. IX(3), 239-272, 2005  

E-Print Network [OSTI]

Cogniie, Creier, Comportament / Cognition, Brain, Behavior Vol. IX(3), 239-272, 2005 ©Romanian), 193-210, 2005 ©Romanian Association of Cognitive Sciences Iunie 2005 · Cogniie, Creier, Comportament

Oztop, Erhan

169

E-Print Network 3.0 - axisymmetric bianchi-ix cosmological Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of Wellington Collection: Mathematics 29 ccsd-00102606,version1-2Oct2006 Integrable geodesic flows and Summary: -axial Bianchi IX metric. 12;1 Introduction The study of the...

170

E-Print Network 3.0 - anhydrase ix ca Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

anhydrase ix ca Page: << < 1 2 3 4 5 > >> 1 Prokaryotic carbonic anhydrases Kerry S. Smith *, James G. Ferry Summary: during purica- tion 22 conrmed an earlier report of a...

171

E-Print Network 3.0 - anhydrase ix expression Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

ix expression Page: << < 1 2 3 4 5 > >> 1 Prokaryotic carbonic anhydrases Kerry S. Smith *, James G. Ferry Summary: , growth inhibition by cyanate of a cynS deletion strain...

172

Exchange effects in magnetized quantum plasmas  

E-Print Network [OSTI]

We apply the many-particle quantum hydrodynamics including the Coulomb exchange interaction to magnetized quantum plasmas. We consider a number of wave phenomenon under influence of the Coulomb exchange interaction. Since the Coulomb exchange interaction affects longitudinal and transverse-longitudinal waves we focus our attention to the Langmuir waves, Trivelpiece-Gould waves, ion-acoustic waves in non-isothermal magnetized plasmas, the dispersion of the longitudinal low-frequency ion-acoustic waves and low-frequencies electromagnetic waves at $T_{e}\\gg T_{i}$ . We obtained the numerical simulation of the dispersion properties of different types of waves.

Trukhanova, Mariya Iv

2015-01-01T23:59:59.000Z

173

U.S. Department of Energy Categorical Exclusion ...  

Broader source: Energy.gov (indexed) [DOE]

Addition of Pump, Piping, and Ion Exchange Column in Effluent Treatment Project Savannah River Site AikenAikenSouth Carolina Addition of Pump, Piping and Ion Exchange (IX) Column...

174

Heat exchanger  

DOE Patents [OSTI]

A heat exchanger comparising a shell attached at its open end to one side of a tube sheet and a detachable head connected to the other side of said tube sheet. The head is divided into a first and second chamber in fluid communication with a nozzle inlet and nozzle outlet, respectively, formed in said tube sheet. A tube bundle is mounted within said shell and is provided with inlets and outlets formed in said tube sheet in communication with said first and second chambers, respectively.

Brackenbury, P.J.

1983-12-08T23:59:59.000Z

175

Heat exchanger  

DOE Patents [OSTI]

A heat exchanger comparising a shell attached at its open end to one side of a tube sheet and a detachable head connected to the other side of said tube sheet. The head is divided into a first and second chamber in fluid communication with a nozzle inlet and nozzle outlet, respectively, formed in said tube sheet. A tube bundle is mounted within said shell and is provided with inlets and outlets formed in said tube sheet in communication with said first and second chambers, respectively.

Brackenbury, Phillip J. (Richland, WA)

1986-01-01T23:59:59.000Z

176

Agriculture on Exchange InternationalExchangeProgram  

E-Print Network [OSTI]

Agriculture on Exchange InternationalExchangeProgram Students enrolled in courses offered through the Faculty of Agriculture and Environment are welcome to apply for exchange. However, to ensure that you Academic Adviser before submitting an exchange application. Undergraduate Agriculture students normally go

Viglas, Anastasios

177

Optimizing Synthesis of Na2Ti2SiO7 - 2H2O (Na-CST) and Ion Exchange Pathways for Cs0.4H1.6Ti2SiO7 - H2O (Cs-CST) Determined from in situ Synchrotron X-ray Powder Diffraction  

SciTech Connect (OSTI)

Observation of wide angle diffraction data collected in situ during previous synthesis of Na-CST (Na{sub 2}Ti{sub 2}SiO{sub 7}-2H{sub 2}O) showed initial crystallization of a precursor phase (SNT) at 30 C followed by conversion to CST after 1 h at 220 C. In situ studies of Cs{sup +} ion exchange into the H{sup +} form of CST showed a site-by-site ion exchange pathway accompanied by a simultaneous structural transition from P4{sub 2}/mbc (cell parameters a = 11.0690(6) Angstroms, c = 11.8842(6) Angstroms) to P4{sub 2}/mcm (cell parameters a = 7.847(2) Angstroms, c = 11.9100(6) Angstroms). After approximately 18% Cs{sup +} exchange into site designated Cs2 in space group P4{sub 2}/mcm, a site designated Cs1 in space group P4{sub 2}/mcm began to fill at the center of the 8MR windows until a maximum of approximately 22% exchange was achieved for Cs1. Bond valence sums of site Cs1 to framework O{sup 2-} are 1.00 v.u., while bond valence sums of site Cs2 to framework O{sup 2-} are 0.712 v.u. suggesting Cs1 to have a more stable bonding environment.

Celestian,A.; Medvedev, D.; Tripathi, A.; Parise, J.; Clearfield, A.

2005-01-01T23:59:59.000Z

178

Segmented heat exchanger  

DOE Patents [OSTI]

A segmented heat exchanger system for transferring heat energy from an exhaust fluid to a working fluid. The heat exchanger system may include a first heat exchanger for receiving incoming working fluid and the exhaust fluid. The working fluid and exhaust fluid may travel through at least a portion of the first heat exchanger in a parallel flow configuration. In addition, the heat exchanger system may include a second heat exchanger for receiving working fluid from the first heat exchanger and exhaust fluid from a third heat exchanger. The working fluid and exhaust fluid may travel through at least a portion of the second heat exchanger in a counter flow configuration. Furthermore, the heat exchanger system may include a third heat exchanger for receiving working fluid from the second heat exchanger and exhaust fluid from the first heat exchanger. The working fluid and exhaust fluid may travel through at least a portion of the third heat exchanger in a parallel flow configuration.

Baldwin, Darryl Dean (Lafayette, IN); Willi, Martin Leo (Dunlap, IL); Fiveland, Scott Byron (Metamara, IL); Timmons, Kristine Ann (Chillicothe, IL)

2010-12-14T23:59:59.000Z

179

Radioactive ion detector  

DOE Patents [OSTI]

Apparatus for detecting the presence, in aqueous media, of substances which emit alpha and/or beta radiation and determining the oxidation state of these radioactive substances, that is, whether they are in cationic or anionic form. In one embodiment, a sensor assembly has two elements, one comprised of an ion-exchange material which binds cations and the other comprised of an ion-exchange material which binds anions. Each ion-exchange element is further comprised of a scintillation plastic and a photocurrent generator. When a radioactive substance to which the sensor is exposed binds to either element and emits alpha or beta particles, photons produced in the scintillation plastic illuminate the photocurrent generator of that element. Sensing apparatus senses generator output and thereby indicates whether cationic species or anionic species or both are present and also provides an indication of species quantity. 2 figs.

Bower, K.E.; Weeks, D.R.

1997-08-12T23:59:59.000Z

180

Radioactive ion detector  

DOE Patents [OSTI]

Apparatus for detecting the presence, in aqueous media, of substances which emit alpha and/or beta radiation and determining the oxidation state of these radioactive substances, that is, whether they are in cationic or anionic form. In one embodiment, a sensor assembly has two elements, one comprised of an ion-exchange material which binds cations and the other comprised of an ion-exchange material which binds anions. Each ion-exchange element is further comprised of a scintillation plastic and a photocurrent generator. When a radioactive substance to which the sensor is exposed binds to either element and emits alpha or beta particles, photons produced in the scintillation plastic illuminate the photocurrent generator of that element. Sensing apparatus senses generator output and thereby indicates whether cationic species or anionic species or both are present and also provides an indication of species quantity.

Bower, Kenneth E. (Los Alamos, NM); Weeks, Donald R. (Saratoga, CA)

1997-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "ion exchange ix" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

New EUV Fe IX emission line identifications from Hinode/EIS  

E-Print Network [OSTI]

Four Fe IX transitions in the wavelength range 188--198 A are identified for the first time in spectra from the EUV Imaging Spectrometer on board the Hinode satellite. In particular the emission line at 197.86 A is unblended and close to the peak of the EIS sensitivity curve, making it a valuable diagnostic of plasma at around 800,000 K - a critical temperature for studying the interface between the corona and transition region. Theoretical ratios amongst the four lines predicted from the CHIANTI database reveal weak sensitivity to density and temperature with observed values consistent with theory. The ratio of 197.86 relative to the 171.07 resonance line of Fe IX is found to be an excellent temperature diagnostic, independent of density, and the derived temperature in the analysed data set is log T=5.95, close to the predicted temperature of maximum ionization of Fe IX.

P. R. Young

2008-10-28T23:59:59.000Z

182

E-Print Network 3.0 - automated anion-exchange purification Sample...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

www.merck-lsp.de Summary: .merck-lsp.de 1.10316 Fractogel EMD TMAE Hicap (M) Ion Exchange chromatography using strong anion exchangers... capacity) Properties of the high...

183

Ion Exchange Kinetics Testing with SRF Resin  

SciTech Connect (OSTI)

The U.S. Department of Energy (DOE) Hanford Site contains more than 53 million gallons of legacy waste generated as a byproduct of plutonium production and reprocessing operations. The wastes are a complex mixture composed mostly of NaNO3, NaNO2, NaOH, NaAlO2, Na3PO4, and Na2SO4, with a number of minor and trace metals, organics, and radionuclides stored in underground waste tanks. The DOE Office of River Protection (ORP) has contracted Bechtel National Incorporated (BNI) to build a pretreatment facility, the River Protection Project-Waste Treatment Plant (RPP-WTP), that will separate long-lived transuranics (TRU) and highly radioactive components (specifically 137Cs and, in selected cases, 90Sr) from the bulk (non-radioactive) constituents and immobilize the wastes by vitrification. The plant is designed to produce two waste streams: a high-volume low-activity waste (LAW) and a low-volume high-activity waste (HLW).

Russell, Renee L.; Rinehart, Donald E.; Brown, Garrett N.; Schonewill, Philip P.; Peterson, Reid A.

2012-04-01T23:59:59.000Z

184

Ion exchange as a tertiary treatment  

E-Print Network [OSTI]

that these treatment methods are capable of removing an appreciable amount of objection? able dissolved organic and inorganic materi aJ s from the final effluent. Color and turbidity were greatly reduced and an appreciable amount of the suspended solids were... Demand Re Resin A General Anion mg. /1. MLVSS psi gpm Milligrams per I. iter Mixed Liquor Volatile Suspended Solids Pounds per Square Inch Gallons per Minute. mm Mi llimeters kgr meq ml Kilogram Milliequilavent Millimeter S. S. BV...

Westervelt, Ronald David

1968-01-01T23:59:59.000Z

185

REMOVING RADIUM-226 ION EXCHANGE RESINS  

E-Print Network [OSTI]

. M. R. Collins Department of Civil Engineering - University of New Hampshire Funded by: United States for Radionuclides · 1962 US Public Health Services DWS ­ 3 pCi/L Radium 226 · 1977 USEPA National Interim Prim. DWS Environmental Protection Agency (USEPA) New England Water Treatment Technology Assistance Center (WTTAC

186

Acidic Ion Exchange Membrane - Energy Innovation Portal  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth (AOD)ProductssondeadjustsondeadjustAbout the Building Technologies OfficeAccounting forFacilities

187

Corrosive resistant heat exchanger  

DOE Patents [OSTI]

A corrosive and errosive resistant heat exchanger which recovers heat from a contaminated heat stream. The heat exchanger utilizes a boundary layer of innocuous gas, which is continuously replenished, to protect the heat exchanger surface from the hot contaminated gas. The innocuous gas is conveyed through ducts or perforations in the heat exchanger wall. Heat from the heat stream is transferred by radiation to the heat exchanger wall. Heat is removed from the outer heat exchanger wall by a heat recovery medium.

Richlen, Scott L. (Annandale, VA)

1989-01-01T23:59:59.000Z

188

Universit Paris IX Dauphine Ecole Doctorale de Gestion Comptabilit Finance (EDOGEST)  

E-Print Network [OSTI]

1 Université Paris IX Dauphine Ecole Doctorale de Gestion Comptabilité Finance (EDOGEST) Centre de Recherche Européen en Finance et Gestion (CREFIGE) CONTRIBUTION A L'ANALYSE DES DETERMINANTS DE L'OFFRE D'INFORMATION SUR LE CAPITAL INTELLECTUEL THESE pour l'obtention du titre de DOCTEUR EN SCIENCES DE GESTION (arrêté

Boyer, Edmond

189

1. WELDING SHALL BE PERFORMED IN ACCORDANCE WITH ASME SECTION IX. NO CODE STAMP REQUIRED.  

E-Print Network [OSTI]

NOTES 1. WELDING SHALL BE PERFORMED IN ACCORDANCE WITH ASME SECTION IX. NO CODE STAMP REQUIRED. 2. ALL WELDS SHALL BE DYE PENETRANT INSPECTED. NO RADIOGRAPHY REQUIRED. 3. MATERIAL CERTIFICATIONS HOSE W/TUBING ENDS, 13.5 FACE-TO-FACE N/A 3 1 swagelok 1.0 pipe weld connector SS - 316L SWAGELOK PIPE

McDonald, Kirk

190

Alunos do TADS apresentam trabalhos no IX Workshop de Viso Computacional no Rio de Janeiro  

E-Print Network [OSTI]

Alunos do TADS apresentam trabalhos no IX Workshop de Visão Computacional no Rio de Janeiro Nos Superior em Tecnologia em Análise e Desenvolvimento de Sistemas (TADS), do Setor de Educação Profissional TADS, orientados pelo Prof. Neves, com a participação do Prof. Dr. Gilson Giraldi, do LNCC (Laboratório

Paraná, Universidade Federal do

191

Princeton University Nondiscrimination Statement In compliance with Title IX of the Education Amendments of 1972, Section  

E-Print Network [OSTI]

programs, or other aspects of its educational programs or activities. The vice provost for institutionalPrinceton University Nondiscrimination Statement In compliance with Title IX of the Education action programs should be directed to the Office of the Vice Provost for Institutional Equity

192

Volumetric Global Illumination and Reconstruction via Energy Backprojection Frank Dachille IX, Klaus Mueller, and Arie Kaufman  

E-Print Network [OSTI]

Volumetric Global Illumination and Reconstruction via Energy Backprojection Frank Dachille IX State University of New York at Stony Brook Stony Brook, NY 11794-4400 Abstract Volumetric energy volu- metric backprojection. CR Categories: I.3.1 [Computer Graphics]: Hardware Archi- tecture; I.3

Mueller, Klaus

193

Woven heat exchanger  

DOE Patents [OSTI]

This invention relates to a heat exchanger for waste heat recovery from high temperature industrial exhaust streams. In a woven ceramic heat exchanger using the basic tube-in-shell design, each heat exchanger consisting of tube sheets and tube, is woven separately. Individual heat exchangers are assembled in cross-flow configuration. Each heat exchanger is woven from high temperature ceramic fiber, the warp is continuous from tube to tube sheet providing a smooth transition and unitized construction.

Piscitella, R.R.

1984-07-16T23:59:59.000Z

194

Intracellular Sequestration of Sodium by a Novel Na /H Exchanger in Yeast Is Enhanced by Mutations in the  

E-Print Network [OSTI]

membrane Na /K -ATPase, a P-type ion pump, that drives Na ions out of the cell in exchange for K ions (1). The resultant Na gradient serves as the primary energy source for the transport of other ions and metabolites threat to agricultural production worldwide (4, 5). Because of a basic similarity in ion transport

Rao, Rajini

195

Cesium and Strontium Specific Exchangers for Nuclear Waste Effluent Remediation  

SciTech Connect (OSTI)

During the past 50 years, nuclear defense activities have produced large quantities of nuclear waste that now require safe and permanent disposal. The general procedure to be implemented involves the removal of cesium and strontium from the waste solutions for disposal in permanently vitrified media. This requires highly selective sorbents or ion exchangers. Further, at the high radiation doses present in the solution, organic exchangers or sequestrants are likely to decompose over time. Inorganic ion exchangers are resistant to radiation damage and can exhibit remarkably high selectivities. We have synthesized three families of tunnel-type ion exchangers. The crystal structures of these compounds as well as their protonated phases, coupled with ion exchange titrations, were determined and this information was used to develop an understanding of their ion exchange behavior. The ion exchange selectivities of these phases could be regulated by isomorphous replacement of the framework metals by larger or smaller radius metals. In the realm of layered compounds, we prepared alumina, silica, and zirconia pillared clays and sodium micas. The pillared clays yielded very high Kd values for Cs+ and were very effective in removing Cs+ from groundwaters. The sodium micas also had a high affinity for Cs+ but an even greater attraction for S42+. They also possess the property of trapping these ions permanently as the layers slowly decrease their interlayer distance as loading occurs. Sodium nonatitanate exhibited extremely high Kd values for Sr2+ in alkaline tank wastes and should be considered for removal of Sr2+ in such cases. For tank wastes containing complexing agents, we have found that adding Ca2+ to the solution releases the complexed Sr2+ which may then be removed with the CST exchanger.

A. Clearfield; A. I. Bortun; L. A. Bortun; E. A. Bhlume; P. Sylvester; G. M. Graziano

2000-09-01T23:59:59.000Z

196

Potassium-Calcium Exchange in a Multireactive Soil System: II. Thermodynamics1 P. M. JARDINE ANDD. L. SPARKS2  

E-Print Network [OSTI]

ions and sup- ports the hypothesis of the multireactive natureof the soil. Although K was selectively energy of ex- change, enthalpy of exchange, entropy of exchange. Jardine, P.M., and D.L. Sparks. 1984

Sparks, Donald L.

197

Anion exchange polymer electrolytes  

DOE Patents [OSTI]

Solid anion exchange polymer electrolytes include chemical compounds comprising a polymer backbone with side chains that include guanidinium cations.

Kim, Yu Seung; Kim, Dae Sik

2013-09-10T23:59:59.000Z

198

VOLUME 76, NUMBER 1 P H Y S I C A L R E V I E W L E T T E R S 1 JANUARY 1996 First Study of Heavy-Ion Mirror Charge Exchange  

E-Print Network [OSTI]

are nuclear reaction studies with mirror nuclear pairs, since only one member of a mirror pair can be stable accessible excitation energy range. Charge-exchange p, n reactions at energies above 100 MeV have long been, since they involve the detection of rather low-energy neutrons. Furthermore, experiments in the b1

Bertulani, Carlos A. - Department of Physics and Astronomy, Texas A&M University

199

High-resolution studies of charge exchange in supernova remnants with Magellan, XMM-Newton, and Micro-X  

E-Print Network [OSTI]

Charge exchange, the semi-resonant transfer of an electron from a neutral atom to an excited state in an energetic ion, can occur in plasmas where energetic ions are incident on a cold, at least partially neutral gas. ...

Heine, Sarah Nicole Trowbridge

2014-01-01T23:59:59.000Z

200

Chicago Climate Exchange, Inc. 2010 Chicago Climate Exchange 1 The Role of Exchanges and Standardization  

E-Print Network [OSTI]

Chicago Climate Exchange®, Inc.© 2010 Chicago Climate Exchange 1 The Role of Exchanges and Standardization in Reducing Emissions at Scale Michael J. Walsh, Ph.D. Executive Vice President Chicago Climate Exchange, Inc. #12;Chicago Climate Exchange®, Inc.© 2010 Chicago Climate Exchange Pacala-Socolow GHG

Note: This page contains sample records for the topic "ion exchange ix" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Uniform insulation applied-B ion diode  

DOE Patents [OSTI]

An applied-B field extraction ion diode has uniform insulation over an anode surface for increased efficiency. When the uniform insulation is accomplished with anode coils, and a charge-exchange foil is properly placed, the ions may be focused at a point on the z axis.

Seidel, David B. (Albuquerque, NM); Slutz, Stephen A. (Albuquerque, NM)

1988-01-01T23:59:59.000Z

202

Homoclinic chaos in axisymmetric Bianchi-IX cosmological models with an ad hoc quantum potential  

SciTech Connect (OSTI)

In this work we study the dynamics of the axisymmetric Bianchi-IX cosmological model with a term of quantum potential added. As it is well known, this class of Bianchi-IX models is homogeneous and anisotropic with two scale factors, A(t) and B(t), derived from the solution of Einstein's equation for general relativity. The model we use in this work has a cosmological constant and the matter content is dust. To this model we add a quantum-inspired potential that is intended to represent short-range effects due to the general relativistic behavior of matter in small scales and play the role of a repulsive force near the singularity. We find that this potential restricts the dynamics of the model to positive values of A(t) and B(t) and alters some qualitative and quantitative characteristics of the dynamics studied previously by several authors. We make a complete analysis of the phase space of the model finding critical points, periodic orbits, stable/unstable manifolds using numerical techniques such as Poincare section, numerical continuation of orbits, and numerical globalization of invariant manifolds. We compare the classical and the quantum models. Our main result is the existence of homoclinic crossings of the stable and unstable manifolds in the physically meaningful region of the phase space [where both A(t) and B(t) are positive], indicating chaotic escape to inflation and bouncing near the singularity.

Correa, G. C.; Stuchi, T. J.; Joras, S. E. [Instituto de Fisica, Universidade Federal do Rio de Janeiro, Caixa Postal 68528, Rio de Janeiro, RJ 21941-972 (Brazil)

2010-04-15T23:59:59.000Z

203

Direct fired heat exchanger  

SciTech Connect (OSTI)

A gas-to-liquid heat exchanger system which transfers heat from a gas, generally the combustion gas of a direct-fired generator of an absorption machine, to a liquid, generally an absorbent solution. The heat exchanger system is in a counterflow fluid arrangement which creates a more efficient heat transfer.

Reimann, Robert C. (Lafayette, NY); Root, Richard A. (Spokane, WA)

1986-01-01T23:59:59.000Z

204

Ion exchange-induced dissolution of calcite in Na-montmorillonite/CaCO?b3?s systems: its effect on hydraulic conductivity, CaCO?b3?s dissolution kinetics, and CaCO?b3?s equilibrium relations  

E-Print Network [OSTI]

ION EXCHAiVGE-INDUCED DISSOLUTION OF CALCITE IV Na- lVIONTMORILLONITE/CaCO3 SYSTEMS: ITS EFFECT ON HYDRAULIC CONDUCTIVITY, CaCOp DISSOLUTION KINETICS, AND CaCO3 EQUILIBRIUM RELATIONS A Thesis by JOSE BRUNO DEL RIO DURAND Submitted... in the laboratory under conditions of saturated flow. Experiments with Na/Ca-montmorillonite/calcite/sand mixtures showed that the deleterious effect of sodicity on hydraulic conductivity (HC) and clay flocculation was minimized substantially when calcite...

Del Rio Durand, Jose Bruno

1990-01-01T23:59:59.000Z

205

Charge exchange recombination spectroscopy on fusion devices  

SciTech Connect (OSTI)

For fusion, obtaining reliable measurements of basic plasma parameters like ion and electron densities and temperatures is a primary goal. For theory, measurements are needed as a function of time and space to understand plasma transport and confinement with the ultimate goal of achieving economic nuclear fusion power. Electron profile measurements and plasma spectroscopy for the plasma ions are introduced. With the advent of Neutral Beam auxiliary plasma heating, Charge Exchange Recombination Spectroscopy provides accurate and time resolved measurements of the ions in large volume fusion devices. In acknowledgement of Nicol Peacock's role in the development of these techniques, still at the forefront of plasma fusion research, this paper describes the evolution of this diagnostic method.

Duval, B. P. [Centre de Recherches en Physique des Plasmas, EPFL, Lausanne (Switzerland)

2012-05-25T23:59:59.000Z

206

Synthesis and crystal structure of Mg{sub 0.5}NbO{sub 2}: An ion-exchange reaction with Mg{sup 2+} between trigonal [NbO{sub 2}]{sup -} layers  

SciTech Connect (OSTI)

A new layered niobate, Mg{sub 0.5}NbO{sub 2}, was synthesized from LiNbO{sub 2} through a cation-exchange reaction with Mg{sup 2+} at 450-550 Degree-Sign C. This is the first example of a topotactic reaction with an aliovalent cation between trigonal [NbO{sub 2}]{sup -} layers. It is proposed to be isostructural with LiNbO{sub 2} (space group; P6{sub 3}/mmc) with lattice parameters of a=2.9052(6) A, c=10.625(15) A. The lattice parameters and formation energy of Mg{sub 0.5}NbO{sub 2} crystallized in LiNbO{sub 2} form and other layered CaNb{sub 2}O{sub 4} one were calculated by density functional theory. - Graphical abstract: A new layered niobate, Mg{sub 0.5}NbO{sub 2}, was synthesized from LiNbO{sub 2} through a cation-exchange reaction with Mg{sup 2+} at 450-550 Degree-Sign C. It is isostructural with LiNbO{sub 2} with lattice parameters of a=2.9052(6) A, c=10.625(15) A. Mg{sup 2+} are described in spheres located between [NbO{sub 2}]{sup -} trigonal layers and its occupancy is 0.5. Highlights: Black-Right-Pointing-Pointer A new layered niobate, Mg{sub 0.5}NbO{sub 2}, was synthesized from LiNbO{sub 2}. Black-Right-Pointing-Pointer Cation-exchange reaction converted two monovalent Li{sup +} into one divalent Mg{sup 2+} at 450-550 Degree-Sign C. Black-Right-Pointing-Pointer Mg{sub 0.5}NbO{sub 2} was isostructural with LiNbO{sub 2} (space group; P6{sub 3}/mmc). Black-Right-Pointing-Pointer Its lattice parameters were a=2.9052(6) A and c=10.625(15) A. Black-Right-Pointing-Pointer Synthesized Mg{sub 0.5}NbO{sub 2} was calculated to be thermodynamically more favorable.

Miura, Akira, E-mail: amiura@yamanashi.ac.jp [Center for Crystal Science and Technology, University of Yamanashi (Japan); Takei, Takahiro; Kumada, Nobuhiro [Center for Crystal Science and Technology, University of Yamanashi (Japan)

2013-01-15T23:59:59.000Z

207

IX. IMPACT OF AEROSOLS FROM THE ERUPTION OF EL CHICHN ON BEAM RADIATION IN THE PACIFIC NORTHWEST  

E-Print Network [OSTI]

measured on clear days the effects of normal climatic differences are avoided. Solar radiation data taken of following this procedure for the clear day solar noon global radiation is shown in Fig. 21. The data shown27 IX. IMPACT OF AEROSOLS FROM THE ERUPTION OF EL CHICHÃ?N ON BEAM RADIATION IN THE PACIFIC

Oregon, University of

208

Heat and mass exchanger  

DOE Patents [OSTI]

A mass and heat exchanger includes at least one first substrate with a surface for supporting a continuous flow of a liquid thereon that either absorbs, desorbs, evaporates or condenses one or more gaseous species from or to a surrounding gas; and at least one second substrate operatively associated with the first substrate. The second substrate includes a surface for supporting the continuous flow of the liquid thereon and is adapted to carry a heat exchange fluid therethrough, wherein heat transfer occurs between the liquid and the heat exchange fluid.

Lowenstein, Andrew (Princeton, NJ); Sibilia, Marc J. (Princeton, NJ); Miller, Jeffrey A. (Hopewell, NJ); Tonon, Thomas (Princeton, NJ)

2007-09-18T23:59:59.000Z

209

Heat and mass exchanger  

DOE Patents [OSTI]

A mass and heat exchanger includes at least one first substrate with a surface for supporting a continuous flow of a liquid thereon that either absorbs, desorbs, evaporates or condenses one or more gaseous species from or to a surrounding gas; and at least one second substrate operatively associated with the first substrate. The second substrate includes a surface for supporting the continuous flow of the liquid thereon and is adapted to carry a heat exchange fluid therethrough, wherein heat transfer occurs between the liquid and the heat exchange fluid.

Lowenstein, Andrew (Princeton, NJ); Sibilia, Marc J. (Princeton, NJ); Miller, Jeffrey A. (Hopewell, NJ); Tonon, Thomas (Princeton, NJ)

2011-06-28T23:59:59.000Z

210

Active microchannel heat exchanger  

DOE Patents [OSTI]

The present invention is an active microchannel heat exchanger with an active heat source and with microchannel architecture. The microchannel heat exchanger has (a) an exothermic reaction chamber; (b) an exhaust chamber; and (c) a heat exchanger chamber in thermal contact with the exhaust chamber, wherein (d) heat from the exothermic reaction chamber is convected by an exothermic reaction exhaust through the exhaust chamber and by conduction through a containment wall to the working fluid in the heat exchanger chamber thereby raising a temperature of the working fluid. The invention is particularly useful as a liquid fuel vaporizer and/or a steam generator for fuel cell power systems, and as a heat source for sustaining endothermic chemical reactions and initiating exothermic reactions.

Tonkovich, Anna Lee Y. (Pasco, WA) [Pasco, WA; Roberts, Gary L. (West Richland, WA) [West Richland, WA; Call, Charles J. (Pasco, WA) [Pasco, WA; Wegeng, Robert S. (Richland, WA) [Richland, WA; Wang, Yong (Richland, WA) [Richland, WA

2001-01-01T23:59:59.000Z

211

Radial flow heat exchanger  

DOE Patents [OSTI]

A radial flow heat exchanger (20) having a plurality of first passages (24) for transporting a first fluid (25) and a plurality of second passages (26) for transporting a second fluid (27). The first and second passages are arranged in stacked, alternating relationship, are separated from one another by relatively thin plates (30) and (32), and surround a central axis (22). The thickness of the first and second passages are selected so that the first and second fluids, respectively, are transported with laminar flow through the passages. To enhance thermal energy transfer between first and second passages, the latter are arranged so each first passage is in thermal communication with an associated second passage along substantially its entire length, and vice versa with respect to the second passages. The heat exchangers may be stacked to achieve a modular heat exchange assembly (300). Certain heat exchangers in the assembly may be designed slightly differently than other heat exchangers to address changes in fluid properties during transport through the heat exchanger, so as to enhance overall thermal effectiveness of the assembly.

Valenzuela, Javier (Hanover, NH)

2001-01-01T23:59:59.000Z

212

Ion collection by a conducting sphere in a magnetized or drifting collisional plasma  

E-Print Network [OSTI]

Ion collection by dust grains and probes in plasmas with a neutral background is of interest in the study of both space and terrestrial plasmas, where charge-exchange collisions can play an important role in ion collection. ...

Haakonsen, Christian Bernt, 1985-

2011-01-01T23:59:59.000Z

213

Charge-exchange collisions in interpenetrating laser-produced magnesium plasmas  

E-Print Network [OSTI]

Charge-exchange collisions in interpenetrating laser-produced magnesium plasmas S.S. HARILAL,1 C charge-exchange collisions between highly charged Mg ions in colliding laser-produced magnesium plasmas magnesium plasmas. 1. INTRODUCTION Several applications of laser-produced plasmas involve an experimental

Harilal, S. S.

214

Synthesis of Li{sub (x)}Na{sub (2-x)}Mn{sub 2}S{sub 3} and LiNaMnS{sub 2} through redox-induced ion exchange reactions  

SciTech Connect (OSTI)

Na{sub 2}Mn{sub 2}S{sub 3} was oxidatively deintercalated using iodine in acetonitrile to yield Na{sub 1.3}Mn{sub 2}S{sub 3}, with lattice constants nearly identical to that of the reactant. Lithium was then reductively intercalated into the oxidized product to yield Li{sub 0.7}Na{sub 1.3}Mn{sub 2}S{sub 3}. When heated, this metastable compound decomposed to form a new crystalline compound, LiNaMnS{sub 2}, along with MnS and residual Na{sub 2}Mn{sub 2}S{sub 3}. Single crystal X-ray diffraction structural analysis of LiNaMnS{sub 2} revealed that this compound crystallizes in P-3m1 with cell parameters a=4.0479(6) A, c=6.7759(14) A, V=96.15(3) A{sup 3} (Z=1, wR2=0.0367) in the NaLiCdS{sub 2} structure-type. - Graphical abstract: Structure of LiNaMnS{sub 2}. Li and Mn are statistically distributed in edge-shared tetrahedral environments linked into infinite planes. Sodium ions occupy interlayer sites.

Luthy, Joshua A.; Goodman, Phillip L. [Department of Chemistry and Biochemistry, Texas State University-San Marcos, 601 University Drive, San Marcos, TX 78666 (United States); Martin, Benjamin R. [Department of Chemistry and Biochemistry, Texas State University-San Marcos, 601 University Drive, San Marcos, TX 78666 (United States)], E-mail: bmartin@txstate.edu

2009-03-15T23:59:59.000Z

215

Ion Colliders  

E-Print Network [OSTI]

High-energy ion colliders are large research tools in nuclear physics to study the Quark-Gluon-Plasma (QGP). The range of collision energy and high luminosity are important design and operational considerations. The experiments also expect flexibility with frequent changes in the collision energy, detector fields, and ion species. Ion species range from protons, including polarized protons in RHIC, to heavy nuclei like gold, lead and uranium. Asymmetric collision combinations (e.g. protons against heavy ions) are also essential. For the creation, acceleration, and storage of bright intense ion beams, limits are set by space charge, charge change, and intrabeam scattering effects, as well as beam losses due to a variety of other phenomena. Currently, there are two operating ion colliders, the Relativistic Heavy Ion Collider (RHIC) at BNL, and the Large Hadron Collider (LHC) at CERN.

Fischer, W

2015-01-01T23:59:59.000Z

216

A corrosive resistant heat exchanger  

DOE Patents [OSTI]

A corrosive and erosive resistant heat exchanger which recovers heat from a contaminated heat stream. The heat exchanger utilizes a boundary layer of innocuous gas, which is continuously replenished, to protect the heat exchanger surface from the hot contaminated gas. The innocuous gas is pumped through ducts or perforations in the heat exchanger wall. Heat from the heat stream is transferred by radiation to the heat exchanger wall. Heat is removed from the outer heat exchanger wall by a heat recovery medium. 3 figs., 3 tabs.

Richlen, S.L.

1987-08-10T23:59:59.000Z

217

Chemical exchange program analysis.  

SciTech Connect (OSTI)

As part of its EMS, Sandia performs an annual environmental aspects/impacts analysis. The purpose of this analysis is to identify the environmental aspects associated with Sandia's activities, products, and services and the potential environmental impacts associated with those aspects. Division and environmental programs established objectives and targets based on the environmental aspects associated with their operations. In 2007 the most significant aspect identified was Hazardous Materials (Use and Storage). The objective for Hazardous Materials (Use and Storage) was to improve chemical handling, storage, and on-site movement of hazardous materials. One of the targets supporting this objective was to develop an effective chemical exchange program, making a business case for it in FY07, and fully implementing a comprehensive chemical exchange program in FY08. A Chemical Exchange Program (CEP) team was formed to implement this target. The team consists of representatives from the Chemical Information System (CIS), Pollution Prevention (P2), the HWMF, Procurement and the Environmental Management System (EMS). The CEP Team performed benchmarking and conducted a life-cycle analysis of the current management of chemicals at SNL/NM and compared it to Chemical Exchange alternatives. Those alternatives are as follows: (1) Revive the 'Virtual' Chemical Exchange Program; (2) Re-implement a 'Physical' Chemical Exchange Program using a Chemical Information System; and (3) Transition to a Chemical Management Services System. The analysis and benchmarking study shows that the present management of chemicals at SNL/NM is significantly disjointed and a life-cycle or 'Cradle-to-Grave' approach to chemical management is needed. This approach must consider the purchasing and maintenance costs as well as the cost of ultimate disposal of the chemicals and materials. A chemical exchange is needed as a mechanism to re-apply chemicals on site. This will not only reduce the quantity of unneeded chemicals and the amount spent on new purchases, but will also avoid disposal costs. If SNL/NM were to realize a 5 percent reduction in chemical inventory and a 10 percent reduction in disposal of unused chemicals the total savings would be $189, 200 per year.

Waffelaert, Pascale

2007-09-01T23:59:59.000Z

218

E-Print Network 3.0 - advantageous metal ion Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Ion Exchange in Biosorption S I L K E S C H I E W E R A N D B O H U M I L V O... heavy metals often through ion exchange. This biosorption can be used for purification of...

219

Water uptake, ionic conductivity and swelling properties of anion-exchange membrane  

E-Print Network [OSTI]

occurs with negative excess volume of mixing. Percolative nature of the ion transport has been is reduced at the cathode to produce OHÃ? , which transports through the anion-exchange membrane (AEM membrane, AEM can conduct ions only in the presence of water. In addition, water is one of the reactants

220

Structure of the Alkali-metal-atom-Strontium molecular ions: towards photoassociation and formation of cold molecular ions  

E-Print Network [OSTI]

The potential energy curves, permanent and transition dipole moments, and the static dipolar polarizability, of molecular ions composed of one alkali-metal atom and a Strontium ion are determined with a quantum chemistry approach. The molecular ions are treated as effective two-electron systems and are treated using effective core potentials including core polarization, large gaussian basis sets, and full configuration interaction. In the perspective of upcoming experiments aiming at merging cold atom and cold ion traps, possible paths for radiative charge exchange, photoassociation of a cold Lithium or Rubidium atom and a Strontium ion are discussed, as well as the formation of stable molecular ions.

Mireille Aymar; Romain Guérout; Olivier Dulieu

2011-02-24T23:59:59.000Z

Note: This page contains sample records for the topic "ion exchange ix" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Structure of the alkali-metal-atom + strontium molecular ions: Towards photoassociation and formation of cold molecular ions  

SciTech Connect (OSTI)

The potential energy curves, permanent and transition dipole moments, and the static dipolar polarizability, of molecular ions composed of one alkali-metal atom and a strontium ion are determined with a quantum chemistry approach. The molecular ions are treated as effective two-electron systems and are treated using effective core potentials including core polarization, large gaussian basis sets, and full configuration interaction. In the perspective of upcoming experiments aiming at merging cold atom and cold ion traps, possible paths for radiative charge exchange, photoassociation of a cold lithium or rubidium atom and a strontium ion are discussed, as well as the formation of stable molecular ions.

Aymar, M.; Dulieu, O. [Laboratoire Aime Cotton, CNRS, UPR3321, Ba circumflex t. 505, Univ Paris-Sud, 91405 Orsay Cedex (France); Guerout, R. [Laboratoire Kastler-Brossel, CNRS, ENS, Univ Pierre et Marie Curie case 74, Campus Jussieu, F-75252 Paris Cedex 05 (France)

2011-08-14T23:59:59.000Z

222

Structure of the Alkali-metal-atom-Strontium molecular ions: towards photoassociation and formation of cold molecular ions  

E-Print Network [OSTI]

The potential energy curves, permanent and transition dipole moments, and the static dipolar polarizability, of molecular ions composed of one alkali-metal atom and a Strontium ion are determined with a quantum chemistry approach. The molecular ions are treated as effective two-electron systems and are treated using effective core potentials including core polarization, large gaussian basis sets, and full configuration interaction. In the perspective of upcoming experiments aiming at merging cold atom and cold ion traps, possible paths for radiative charge exchange, photoassociation of a cold Lithium or Rubidium atom and a Strontium ion are discussed, as well as the formation of stable molecular ions.

Aymar, Mireille; Dulieu, Olivier

2011-01-01T23:59:59.000Z

223

Building Energy Data Exchange Specification Scoping Report |...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Building Energy Data Exchange Specification Scoping Report Building Energy Data Exchange Specification Scoping Report The Building Energy Data Exchange Specification (BEDES),...

224

EMSL - ions  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

ions en Reorientation of the ‘free OH’ group in the top-most layer of airwater interface of sodium fluoride aqueous http:www.emsl.pnl.govemslwebpublications...

225

Thermoelectric heat exchange element  

DOE Patents [OSTI]

A thermoelectric heat exchange module includes a first substrate including a heat receptive side and a heat donative side and a series of undulatory pleats. The module may also include a thermoelectric material layer having a ZT value of 1.0 or more disposed on at least one of the heat receptive side and the heat donative side, and an electrical contact may be in electrical communication with the thermoelectric material layer.

Callas, James J. (Peoria, IL); Taher, Mahmoud A. (Peoria, IL)

2007-08-14T23:59:59.000Z

226

Proceedings: Heat exchanger workshop  

SciTech Connect (OSTI)

Heat transfer processes are of controlling importance in the operation of a thermal power plant. Heat exchangers are major cost items and are an important source of problems causing poor power plant availability and performance. A workshop to examine the improvements that can be made to heat exchangers was sponsored by the Electric Power Research Institute (EPRI) on June 10-11, 1986, in Palo Alto, California. This workshop was attended by 25 engineers and scientists representing EPRI-member utilities and EPRI consultants. A forum was provided for discussions related to the design, operation and maintenance of utility heat transfer equipment. The specific objectives were to identify research directions that could significantly improve heat exchanger performance, reliability and life cycle economics. Since there is a great diversity of utility heat transfer equipment in use, this workshop addressed two equipment categories: Boiler Feedwater Heaters (FWH) and Heat Recovery Steam Generators (HRSG). The workshop was divided into the following panel sessions: functional design, mechanical design, operation, suggested research topics, and prioritization. Each panel session began with short presentations by experts on the subject and followed by discussions by the attendees. This report documents the proceedings of the workshop and contains recommendations of potentially valuable areas of research and development. 4 figs.

Not Available

1987-07-01T23:59:59.000Z

227

Sandia National Laboratories: Heat Exchanger Development  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

LabHeat Exchanger Development Heat Exchanger Development Planned Heat Exchanger Test Loop Capabilities Heat Exchanger 1 500 kW Heaters (Elec.) 500 kW Gas Cooler Unbalanced flows...

228

Sources of polarized ions and atoms  

SciTech Connect (OSTI)

In this presentation we discuss methods of producing large quantities of polarized atoms and ions (Stern-Gerlach separation, optical pumping, and spin-exchange) as well as experimental methods of measuring the degree of polarization of atomic systems. The usefulness of polarized atoms in probing the microscopic magnetic surface properties of materials will also be discussed. 39 refs., 5 figs., 2 tabs.

Cornelius, W.D.

1988-01-01T23:59:59.000Z

229

Fast Neutral Generation by Charge Exchange Reaction and Its Effect on Neutron Production Rate in Inertial Electrostatic Confinement Fusion Systems  

SciTech Connect (OSTI)

Fast neutral generation by charge exchange reaction in inertial electrostatic confinement plasmas is studied by solving the Poisson equation and the Boltzmann equation for fast neutrals. Fusion reactions carried by the charge exchange fast neutrals become appreciable compared with ion-background fusion reaction. It is shown that the fusion reaction between fast neutral and background gas is sensitively affected by experimental parameters (grid voltage, background gas pressure) and ion distribution function.

Yoshinaga, S.; Matsuura, H.; Nakao, Y.; Kudo, K. [Kyushu University (Japan)

2005-05-15T23:59:59.000Z

230

Hydrocarbon cracking with yttrium exchanged zeolite y catalyst  

SciTech Connect (OSTI)

A process is described for cracking a gas oil boiling range hydrocarbon feedstock comprising the step of contacting the feedstock in a catalytic cracking zone under catalytic cracking conditions to produce convulsion products comprising gasoline with a catalyst composition. The process comprises: a Y crystalline aluminosilicate zeolite, having the structure of faujasite and having uniform pore diameters and a silica to alumina mole ratio of at least about 5; an inorganic oxide matrix; and the zeolite having been ion exchanged with a mixture of rare earths prior to compositing with the matrix; and the zeolite having been subsequently further ion exchanged with yttrium following compositing with the matrix, whereby the catalyst composition contains 0.30 to 3.0 wt% yttrium.

Lochow, C.F.; Kovacs, D.B.

1987-05-12T23:59:59.000Z

231

Charge Transport through a Novel Zeolite Y Membrane by a Self-Exchange Process Hyunjung Lee and Prabir K. Dutta*  

E-Print Network [OSTI]

Charge Transport through a Novel Zeolite Y Membrane by a Self-Exchange Process Hyunjung Lee-photoresist-coated membranes were found. Accessibility of the intrazeolitic volume was examined by ion exchange and for optimally illuminated membranes was comparable to uncoated membranes. Charge transport through the membrane

Dutta, Prabir K.

232

Optimization of Heat Exchanger Cleaning  

E-Print Network [OSTI]

decrease models of the heat recovery decay. A mathematical comparison of mechanical and chemical cleaning of heat exchangers has identified the most significant parameters which affect the choice between the two methods. INTRODUCTION In most... can be somewhat mitigated by periodic chemical or mechanical cleaning of the exchanger surface, and by the addition of antifoul ants. The typical decay in heat recovery capabil ity due to fou 1i ng and restoration afte r heat exchanger cleaning...

Siegell, J. H.

233

Non-aqueous liquid compositions comprising ion exchange polymers  

DOE Patents [OSTI]

Compositions, and methods of making thereof, comprising from about 1% to about 5% of a perfluorinated sulfonic acid ionomer or a hydrocarbon-based ionomer; and from about 95% to about 99% of a solvent, said solvent consisting essentially of a polyol; wherein said composition is substantially free of water and wherein said ionomer is uniformly dispersed in said solvent.

Kim, Yu Seung (Los Alamos, NM); Lee, Kwan-Soo (Blacksburg, VA); Rockward, Tommy Q. T. (Rio Rancho, NM)

2011-07-19T23:59:59.000Z

234

Non-aqueous liquid compositions comprising ion exchange polymers  

DOE Patents [OSTI]

Compositions, and methods of making thereof, comprising from about 1% to about 5% of a perfluorinated sulfonic acid ionomer or a hydrocarbon-based ionomer; and from about 95% to about 99% of a solvent, said solvent consisting essentially of a polyol; wherein said composition is substantially free of water and wherein said ionomer is uniformly dispersed in said solvent.

Kim, Yu Seung; Lee, Kwan-Soo; Rockward, Tommy Q. T.

2013-03-12T23:59:59.000Z

235

Modeling Uranium-Proton Ion Exchange in Biosorption  

E-Print Network [OSTI]

threatening heavy metals because of its high toxicity and some radioactivity. Excessive amounts of uranium seaweed biomass was used to remove the heavy metal uranium from the aqueous solution. Uranium biosorption the heavy metal uptake performance of different biosorbents.LangmuirandFreundlichmodelsoftengenerally fit

Volesky, Bohumil

236

External Technical Review Report for Small Column Ion Exchange Technology  

Office of Environmental Management (EM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) " ,"ClickPipelinesProvedDecember 2005DepartmentDecember U.S. Department of9ofDepartment ofat Savannah River

237

Exploration of Ion-Exchanged Glass for Seals Applications  

E-Print Network [OSTI]

the current cost of the least expensive, deployed system or device, the readiness level must be five or greater, and the security level must be six or greater. NASA defines technology readiness levels as “a systematic metric/measurement system...

Ghanbari, Roushan

2012-10-19T23:59:59.000Z

238

Small Column Ion Exchange at Savannah River Site Technology Readiness  

Broader source: Energy.gov (indexed) [DOE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "ofEarly Career Scientists' Research |RegulationRenewable Energy (EERE) |SeniorIt seemsReportP RDOEEarlier

239

The Dynamics of Platinum Precipitation in an Ion Exchange Membrane  

E-Print Network [OSTI]

Microscopy of polymer electrolyte membranes that have undergone operation under fuel cell conditions, have revealed a well defined band of platinum in the membrane. Here, we propose a physics based model that captures the mechanism of platinum precipitation in the polymer electrolyte membrane. While platinum is observed throughout the membrane, the preferential growth of platinum at the band of platinum is dependent on the electrochemical potential distribution in the membrane. In this paper, the location of the platinum band is calculated as a function of the gas concentration at the cathode and anode, gas diffusion coefficients and solubility constants of the gases in the membrane, which are functions of relative humidity. Under H2/N2 conditions the platinum band is located near the cathode-membrane interface, as the oxygen concentration in the cathode gas stream increases and/or the hydrogen concentration in the anode gas stream decreases, the band moves towards the anode. The model developed in this paper...

Burlatsky, S F; Atrazhev, V V; Dmitriev, D V; Kuzminyh, N Y; Erikhman, N S

2013-01-01T23:59:59.000Z

240

Na K -pump ligands modulate gating of palytoxin-induced ion channels  

E-Print Network [OSTI]

proteins that mediate transport of ions across cell membranes, they traditionally have been viewed as very to the extracellular surface. The 3Na 2K -exchange transport cycle is completed when two extracellular K ions bind ensure the vectorial nature of net transport. The occluded-ion conformations, with binding sites

Gadsby, David

Note: This page contains sample records for the topic "ion exchange ix" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

RESEARCH PAPER The face value of ion fluxes: the challenge of determining  

E-Print Network [OSTI]

is the membrane-transport parameter of greatest interest to most researchers in the field of plant ion transport physiology. Key words: Barley, cellular ion exchange, efflux, high-affinity transport, influx, low-affinity transport, potassium. Introduction The unidirectional influx of nutrient ions into the plant cell

Britto, Dev T.

242

Quality Assurance Exchange, January 2007  

Broader source: Energy.gov (indexed) [DOE]

third article of this series (Quality Assurance Exchange June, volume 2, Issue 2), the bulk of the comments derived from the factual accuracy review should be editorial. When...

243

A Binghamton Exchange Program UNIVERSITY COLLEGE UTRECHT EXCHANGE PROGRAM  

E-Print Network [OSTI]

A Binghamton Exchange Program UNIVERSITY COLLEGE UTRECHT EXCHANGE PROGRAM THE BINGHAMTON PROGRAM AT UNIVERSITY COLLEGE UTRECHT Utrecht University ranks first among Dutch universi- ties and is one of the finest universities in Europe. Students take courses in the University College Utrecht (UCU), Utrecht University

Suzuki, Masatsugu

244

A Binghamton Exchange Program UTRECHT SCHOOL OF ECONOMICS EXCHANGE PROGRAM  

E-Print Network [OSTI]

A Binghamton Exchange Program UTRECHT SCHOOL OF ECONOMICS EXCHANGE PROGRAM THE BINGHAMTON PROGRAM AT UTRECHT SCHOOL OF ECONOMICS Utrecht University ranks first among Dutch universi- ties and is one of the finest universities in Europe. Students take courses in the Utrecht School of Eco- nomics (USE

Suzuki, Masatsugu

245

SWIFT ULTRAVIOLET/OPTICAL TELESCOPE IMAGING OF STAR-FORMING REGIONS IN M81 AND HOLMBERG IX  

SciTech Connect (OSTI)

We present Swift UV/Optical Telescope (UVOT) imaging of the galaxies M81 and Holmberg IX. We combine UVOT imaging in three near-ultraviolet (NUV) filters (uvw2: 1928 A; uvm2: 2246 A; uvw1: 2600 A) with ground-based optical imaging from the Sloan Digital Sky Survey to constrain the stellar populations of both galaxies. Our analysis consists of three different methods. First, we use the NUV imaging to identify UV star-forming knots and then perform spectral energy distribution (SED) modeling on the UV/optical photometry of these sources. Second, we measure surface brightness profiles of the disk of M81 in the NUV and optical. Lastly, we use SED fitting of individual pixels to map the properties of the two galaxies. In agreement with earlier studies, we find evidence for a burst in star formation in both galaxies starting {approx}200 Myr ago coincident with the suggested time of an M81-M82 interaction. In line with theories of its origin as a tidal dwarf, we find that the luminosity-weighted age of Holmberg IX is a few hundred million years. Both galaxies are best fit by a Milky Way dust extinction law with a prominent 2175 A bump. In addition, we describe a stacked median filter technique for modeling the diffuse background light within a galaxy and a Markov chain method for cleaning segment maps generated by SExtractor.

Hoversten, E. A.; Gronwall, C.; Siegel, M. H. [Department of Astronomy and Astrophysics, Pennsylvania State University, 525 Davey Laboratory, University Park, PA 16802 (United States); Vanden Berk, D. E. [Physics Department, St. Vincent College, Latrobe, PA 15650 (United States); Basu-Zych, A. R. [NASA/Goddard Space Flight Center, Greenbelt, MD 20771 (United States); Breeveld, A. A.; Kuin, N. P. M.; Page, M. J. [Mullard Space Science Laboratory/UCL, Holbury St. Mary, Dorking, Surrey RH5 6NT (United Kingdom); Brown, P. J. [Department of Physics and Astronomy, University of Utah, Salt Lake City, UT 84112 (United States); Roming, P. W. A. [Space Science and Engineering Division, Southwest Research Institute, 6220 Culebra Road, San Antonio, TX 78238 (United States)

2011-06-15T23:59:59.000Z

246

Technology Performance Exchange (Fact Sheet)  

SciTech Connect (OSTI)

This fact sheet, 'The Technology Performance Exchange' will be presented at the ET Summit, held at the Pasadena Convention Center on October 15-17, 2012. The Technology Performance Exchange will be a centralized, Web-based portal for finding and sharing energy performance data for commercial building technologies.

Not Available

2012-10-01T23:59:59.000Z

247

Gas Exchange, Partial Pressure Gradients,  

E-Print Network [OSTI]

Gas Exchange, Partial Pressure Gradients, and the Oxygen Window Johnny E. Brian, Jr., M of circulatory and gas transport physiology, and the best place to start is with normobaric physiology. LIFE affect the precise gas exchange occurring in individual areas of the lungs and body tissues. To make

Riba Sagarra, Jaume

248

High Temperature Heat Exchanger Project  

SciTech Connect (OSTI)

The UNLV Research Foundation assembled a research consortium for high temperature heat exchanger design and materials compatibility and performance comprised of university and private industry partners under the auspices of the US DOE-NE Nuclear Hydrogen Initiative in October 2003. The objectives of the consortium were to conduct investigations of candidate materials for high temperature heat exchanger componets in hydrogen production processes and design and perform prototypical testing of heat exchangers. The initial research of the consortium focused on the intermediate heat exchanger (located between the nuclear reactor and hydrogen production plan) and the components for the hydrogen iodine decomposition process and sulfuric acid decomposition process. These heat exchanger components were deemed the most challenging from a materials performance and compatibility perspective

Anthony E. Hechanova, Ph.D.

2008-09-30T23:59:59.000Z

249

Characterization of Ion Dynamics in Structures for Lossless Ion...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Ion Dynamics in Structures for Lossless Ion Manipulations. Characterization of Ion Dynamics in Structures for Lossless Ion Manipulations. Abstract: Structures for Lossless Ion...

250

secondary ion detection | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

ion detection secondary ion detection Leads No leads are available at this time. Magnesium behavior and structural defects in Mg+ ion implanted silicon carbide. Abstract: As a...

251

Investigating Iron Ions | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Investigating Iron Ions Investigating Iron Ions Computer code provides detailed predictions of highly charged ions in water Using resources at EMSL, scientists obtained...

252

Modular heat exchanger  

DOE Patents [OSTI]

A shell and tube heat exchanger having a plurality of individually removable tube bundle modules. A lattice of structural steel forming rectangular openings therein is placed at each end of a cylindrical shell. Longitudinal structural members are placed in the shell between corners of the rectangular openings situated on opposite ends of the shell. Intermediate support members interconnect the longitudinal supports so as to increase the longitudinal supports rigidity. Rectangular parallelpiped tube bundle moldules occupy the space defined by the longitudinal supports and end supports and each include a rectangular tube sheet situated on each end of a plurality of tubes extending therethrough, a plurality of rectangular tube supports located between the tube sheets, and a tube bundle module stiffening structure disposed about the bundle's periphery and being attached to the tube sheets and tube supports. The corners of each tube bundle module have longitudinal framework members which are mateable with and supported by the longitudinal support members. Intermediate support members constitute several lattice, each of which is situate d in a plane between the end support members. The intermediate support members constituting the several lattice extend horizontally and vertically between longitudinal supports of adjacent tube module voids. An alternative embodiment for intermediate support members constitute a series of structural plates situated at the corners of the module voids and having recesses therein for receiving the respective longitudinal support members adjacent thereto, protrusions separating the recesses, and a plurality of struts situated between protrusions of adjacent structural plates.

Giardina, Angelo R. [Marple Township, Delaware County, PA

1981-03-03T23:59:59.000Z

253

Energy-Exchange Project  

SciTech Connect (OSTI)

The purpose of the study was to determine what energy savings can be achieved by coordinating the resources and requirements of two facilities, the 26th Ward Water Pollution Control Plant (WPCP) and a housing development named Starrett City with its own total energy system. It was determined that three energy exchange options were economically and technically feasible. These include: the transfer of digester gas produced at the 26th Ward to the boilers at the Starrett City's total energy plant (TEP); the transfer of hot water heated at the TEP to the 26th Ward for space and process heating; and the transfer of coal effluent waste water from the 26th Ward to the condenser cooling systems at the TEP. Technical information is presented to support the findings. The report addresses those tasks of the statement of work dedicated to data acquisition, analysis, and energy conservation strategies internal to the Starrett City TEP and the community it supplies as well as to the 26th Ward WPCP. (MCW)

Not Available

1982-04-01T23:59:59.000Z

254

2013 IREP Symposium-Bulk Power System Dynamics and Control -IX (IREP), August 25-30, 2013, Rethymnon, Greece Active network management: planning under  

E-Print Network [OSTI]

]. Such incentives have resulted in the on-going installation of wind and solar power generation resources2013 IREP Symposium-Bulk Power System Dynamics and Control -IX (IREP), August 25-30, 2013 In Europe, concern about the environmental impact of the electricity industry is currently driving

Ernst, Damien

255

Modeling of Casting, Welding and Advanced Solidification Processes IX Edited by Peter R. Sahm, Preben N. Hansen and James G. Conley  

E-Print Network [OSTI]

Modeling of Casting, Welding and Advanced Solidification Processes IX Edited by Peter R. Sahm to the Modelling of Welding Phenomena G. A. Taylor, M. Hughes and K. Pericleous Centre for Numerical Modelling of welding phenomena is presented. The framework includes models from both the fields of Computational Fluid

Taylor, Gary

256

2011 Macmillan Publishers Ltd. 1350-23IX Journal of Brand Management Vol. 18, 7, 457472 www.palgrave-journals.com/bm/  

E-Print Network [OSTI]

Keywords: brand loyalty; escapism; conformity; self-image congruence; social motivation #12;Labrecque et al© 2011 Macmillan Publishers Ltd. 1350-23IX Journal of Brand Management Vol. 18, 7, 457­472 www, DeKalb, IL 60115-2897, USA Original Article Exploring social motivations for brand loyalty

Ahmad, Sajjad

257

Heat exchanger using graphite foam  

DOE Patents [OSTI]

A heat exchanger is disclosed. The heat exchanger may have an inlet configured to receive a first fluid and an outlet configured to discharge the first fluid. The heat exchanger may further have at least one passageway configured to conduct the first fluid from the inlet to the outlet. The at least one passageway may be composed of a graphite foam and a layer of graphite material on the exterior of the graphite foam. The layer of graphite material may form at least a partial barrier between the first fluid and a second fluid external to the at least one passageway.

Campagna, Michael Joseph; Callas, James John

2012-09-25T23:59:59.000Z

258

Heat exchanger with ceramic elements  

DOE Patents [OSTI]

An annular heat exchanger assembly includes a plurality of low thermal growth ceramic heat exchange members with inlet and exit flow ports on distinct faces. A mounting member locates each ceramic member in a near-annular array and seals the flow ports on the distinct faces into the separate flow paths of the heat exchanger. The mounting member adjusts for the temperature gradient in the assembly and the different coefficients of thermal expansion of the members of the assembly during all operating temperatures.

Corey, John A. (North Troy, NY)

1986-01-01T23:59:59.000Z

259

Energy Efficiency Exchange 2015 | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Energy Efficiency Exchange 2015 Energy Efficiency Exchange 2015 As the nation's largest energy consumer, the federal government has a tremendous opportunity and clear...

260

Advanced Materials for Proton Exchange Membranes | Department...  

Broader source: Energy.gov (indexed) [DOE]

Advanced Materials for Proton Exchange Membranes Advanced Materials for Proton Exchange Membranes A presentation to the High Temperature Membranes Working Group meeting, May 19,...

Note: This page contains sample records for the topic "ion exchange ix" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Better Buildings Residential Network Orientation Peer Exchange...  

Broader source: Energy.gov (indexed) [DOE]

Better Buildings Residential Network Orientation Peer Exchange Webinar Better Buildings Residential Network Orientation Peer Exchange Webinar September 11, 2014 7:00PM to 8:3...

262

Hear Exchange Assembly  

DOE Patents [OSTI]

A heat exchange assembly comprises a plurality of plates disposed in a spaced-apart arrangement, each of the plurality of plates includes a plurality of passages extending internally from a first end to a second end for directing flow of a heat transfer fluid in a first plane, a plurality of first end-piece members equaling the number of plates and a plurality of second end-piece members also equaling the number of plates, each of the first and second end-piece members including a recessed region adapted to fluidly connect and couple with the first and second ends of the plate, respectively, and further adapted to be affixed to respective adjacent first and second end-piece members in a stacked formation, and each of the first and second end-piece members further including at least one cavity for enabling entry of the heat transfer fluid into the plate, exit of the heat transfer fluid from the plate, or 180.degree. turning of the fluid within the plate to create a serpentine-like fluid flow path between points of entry and exit of the fluid, and at least two fluid conduits extending through the stacked plurality of first and second end-piece members for providing first fluid connections between the parallel fluid entry points of adjacent plates and a fluid supply inlet, and second fluid connections between the parallel fluid exit points of adjacent plates and a fluid discharge outlet so that the heat transfer fluid travels in parallel paths through each respective plate.

Lowenstein, Andrew (Princeton, NJ); Sibilia, Marc (Princeton, NJ); Miller, Jeffrey (Rocky Hill, NJ); Tonon, Thomas S. (Princeton, NJ)

2003-05-27T23:59:59.000Z

263

Quantization of the Bianchi type-IX model in N=1 Supergravity in the Presence of Supermatter  

E-Print Network [OSTI]

The general theory of N=1 supergravity with supermatter is applied to a Bianchi type IX diagonal model. The supermatter is constituted by a complex scalar field and its spin-$1\\over 2$ fermionic partners. The K\\"ahler geometry is chosen to be a two-dimensional flat one. The Lorentz invariant Ansatz for the wave function of the universe is taken to be as simple as possible in order to obtain {\\it new} solutions. The set of differential equations derived from the quantum constraints are analysed in two different cases: if the supermatter terms include an analytical potential or not. In the latter the wave function is found to have a simple form.

P. V. Moniz

1995-05-29T23:59:59.000Z

264

Heat pipe array heat exchanger  

DOE Patents [OSTI]

A heat pipe arrangement for exchanging heat between two different temperature fluids. The heat pipe arrangement is in a ounterflow relationship to increase the efficiency of the coupling of the heat from a heat source to a heat sink.

Reimann, Robert C. (Lafayette, NY)

1987-08-25T23:59:59.000Z

265

Anion exchange polymer electrolytes  

DOE Patents [OSTI]

Solid anion exchange polymer electrolytes and compositions comprising chemical compounds comprising a polymeric core, a spacer A, and a guanidine base, wherein said chemical compound is uniformly dispersed in a suitable solvent and has the structure: ##STR00001## wherein: i) A is a spacer having the structure O, S, SO.sub.2, --NH--, --N(CH.sub.2).sub.n, wherein n=1-10, --(CH.sub.2).sub.n--CH.sub.3--, wherein n=1-10, SO.sub.2-Ph, CO-Ph, ##STR00002## wherein R.sub.5, R.sub.6, R.sub.7 and R.sub.8 each are independently --H, --NH.sub.2, F, Cl, Br, CN, or a C.sub.1-C.sub.6 alkyl group, or any combination of thereof; ii) R.sub.9, R.sub.10, R.sub.11, R.sub.12, or R.sub.13 each independently are --H, --CH.sub.3, --NH.sub.2, --NO, --CH.sub.nCH.sub.3 where n=1-6, HC.dbd.O--, NH.sub.2C.dbd.O--, --CH.sub.nCOOH where n=1-6, --(CH.sub.2).sub.n--C(NH.sub.2)--COOH where n=1-6, --CH--(COOH)--CH.sub.2--COOH, --CH.sub.2--CH(O--CH.sub.2CH.sub.3).sub.2, --(C.dbd.S)--NH.sub.2, --(C.dbd.NH)--N--(CH.sub.2).sub.nCH.sub.3, where n=0-6, --NH--(C.dbd.S)--SH, --CH.sub.2--(C.dbd.O)--O--C(CH.sub.3).sub.3, --O--(CH.sub.2).sub.n--CH--(NH.sub.2)--COOH, where n=1-6, --(CH.sub.2).sub.n--CH.dbd.CH wherein n=1-6, --(CH.sub.2).sub.n--CH--CN wherein n=1-6, an aromatic group such as a phenyl, benzyl, phenoxy, methylbenzyl, nitrogen-substituted benzyl or phenyl groups, a halide, or halide-substituted methyl groups; and iii) wherein the composition is suitable for use in a membrane electrode assembly.

Kim, Yu Seung; Kim, Dae Sik; Lee, Kwan-Soo

2013-07-23T23:59:59.000Z

266

Multi-block sulfonated poly(phenylene) copolymer proton exchange membranes  

DOE Patents [OSTI]

Improved multi-block sulfonated poly(phenylene) copolymer compositions, methods of making the same, and their use as proton exchange membranes (PEM) in hydrogen fuel cells, direct methanol fuel cells, in electrode casting solutions and electrodes. The multi-block architecture has defined, controllable hydrophobic and hydrophilic segments. These improved membranes have better ion transport (proton conductivity) and water swelling properties.

Fujimoto, Cy H. (Albuquerque, NM); Hibbs, Michael (Albuquerque, NM); Ambrosini, Andrea (Albuquerque, NM)

2012-02-07T23:59:59.000Z

267

Synthesis, Structural Characterization, and Catalytic Properties of Tungsten-Exchanged Weiping Ding, George D. Meitzner, David O. Marler,| and Enrique Iglesia*  

E-Print Network [OSTI]

exchanged W/H-ZSM5. 1. Introduction Transition metal ions (e.g., Mo, W, V, Fe, Cr) loaded onto several between oxides or carbides of Mo and W. The synthesis of exchanged WOx precursors and their subsequent. They detected carbidic carbon on Mo/H-ZSM5 and showed that MoOx species reduce almost to Mo0 during reaction.10

Iglesia, Enrique

268

Fast time resolution charge-exchange measurements during the fishbone instability in the poloidal divertor experiment  

SciTech Connect (OSTI)

Measurements of fast ion losses due to the fishbone instability during high ..beta../sub T/q neutral beam heated discharges in the Poloidal Divertor Experiment have been made using two new vertical-viewing charge-exchange analyzers. The measurements show that the instability has an n=1 toroidal mode number, and that it ejects beam ions in a toroidally rotating beacon directed outward along a major radius. Observations of ejected ions with energies up to twice the beam injection energy at R approx. = R/sub 0/ + a indicate the presence of a non-..mu..-conserving acceleration mechanism.

Beiersdorfer, P.; Kaita, R.; Goldston, R.J.

1984-01-01T23:59:59.000Z

269

C60 Secondary Ion Fourier Transform Ion Cyclotron Resonance Mass...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

C60 Secondary Ion Fourier Transform Ion Cyclotron Resonance Mass Spectrometry. C60 Secondary Ion Fourier Transform Ion Cyclotron Resonance Mass Spectrometry. Abstract: Secondary...

270

Anion-exchange resin-based desulfurization process. Final report  

SciTech Connect (OSTI)

The following investigations were performed: (1) batch mode screening of eleven(11) commercially available resins and selection of three candidate resins for further evaluation in a fixed-bed setup. (2) Process variables study using three candidate resins in the fixed-bed setup and selection of the ``best`` resin for process economics development. (3) Exhaustion efficiency and solution concentration were found to be inversely related necessitating a trade-off between the resin cost versus the cost of evaporation/concentration of ensuing effluents. (4) Higher concentration of the HCO{sub 3}{sup {minus}} form of active sites over less active CO{sub 3}{sup 2{minus}} form of sites in the resin was believed to be the main reason for the observed increase in the equilibrium capacity of the resin at an elevated static CO{sub 2}-pressure. This Increase in capacity was found to level off around 80--120 psig range. The increase in CO{sub 2}-pressure, however, did not appear to affect the overall ion-exchange kinetics. (5) In the fixed-bed mode, the solution concentration was found to affect the equilibrium capacity of candidate resins. Their relationship was well satisfied by the Langmuir type non-linear equilibrium isotherm. Alternatively, the effect of solution concentration on overall ion-exchange kinetics varied from resin to resin. (6) Product inhibition effect on the resin was observed as an initial increase followed by a significant decrease in the resin`s equilibrium capacity for SO{sub 4}{sup 2{minus}} as the HCO{sub 3}{sup {minus}}/SO{sub 4}{sup 2{minus}} molar ratio in the solution was increased from 0 to 1.0. This ratio, however, did not affect the overall ion-exchange kinetics.

Sheth, A C; Dharmapurikar, R; Strevel, S D

1994-01-01T23:59:59.000Z

271

Softhard exchange-coupled layered structures with modulated exchange coupling  

E-Print Network [OSTI]

, Tuscaloosa, Alabama 35487-0209 Received 8 April 2003; accepted 28 June 2003 Magnetically soft/hard exchange-coupled for high performance permanent magnets in the past decades and much progress has been made in improving permanent mag- netic properties. A figure of merit of permanent magnetic materials is the maximum magnetic

Garmestani, Hamid

272

In pursuit of clean air: a data book of problems and strategies at the state level. Volume 5. Federal Regions VIII, IX, and X  

SciTech Connect (OSTI)

The following material is provided for each state in Federal Regions VIII, IX, and X: state title page (lists nonattainment areas for each pollutant, the number of monitors with valid readings for a particular averaging time for a pollutant, and the number of monitors that recorded a violation of the standard); revised State Implementation Plan (SIP) outline (covers sources of the problems, the proposed strategies for achieving attainment, and new state review procedures); maps of nonattainment areas, as designated; SAROAD (Storage and Retrieval of Aerometric Data) data; SAROAD data maps; power plant data; power plant maps; and county maps. States in Federal Region VIII are Colorado, Montana, North Dakota, South Dakota, Utah, and Wyoming. Federal Region IX includes Arizona, California, and Nevada. Federal Region X includes Idaho, Oregon, and Washington. (JGB)

Garvey, D.B.; Streets, D.G.

1980-02-01T23:59:59.000Z

273

Heat Pump Cycle with Solution Circuit and Internal Heat Exchange  

E-Print Network [OSTI]

-stage cycle, the heat transfer area required on the refrigerant side will increase by 10~ compared to the ammonia cycl e. CONCLUSIONS The hea t p1llllp cycl e employ ing one sol ut ion circuit and absorber/de sorber heat exchange has a more sophisticated... when a two-stage version fed into the same compressor. While ammonia of this cycl e is used. In this paper. another evaporate s out of an ammonia-water sol ution on C version of such cycles will be discussed which the composition. X. of this solution...

Radermacher, R.

274

Information Exchange for theInformation Exchange for the Development of SustainableDevelopment of Sustainable  

E-Print Network [OSTI]

Information Exchange for theInformation Exchange for the Development of SustainableDevelopment influenced the development ofthe development of sustainable wood process industrysustainable wood process industry substantiallysubstantially .. Information Exchange for the development of Sustainable Wood Process

275

Method and apparatus for removing ions from soil  

DOE Patents [OSTI]

A method and apparatus are presented for selectively removing species of ions from an area of soil. Permeable membranes 14 and 18 impregnated with an ion exchange resin that is specific to one or more species of chemical ions are inserted into ground 12 in close proximity to, and on opposing sides of, a soil area of interest 22. An electric potential is applied across electrodes 26 and 28 to cause the migration of ions out of soil area 22 toward the membranes 14 and 18. Preferably, the resin exchanges ions of sodium or hydrogen for ions of mercury that it captures from soil area 22. Once membranes 14 and 18 become substantially saturated with mercury ions, the potential applied across electrodes 26 and 28 is discontinued and membranes 14 and 18 are preferably removed from soil 12 for storage or recovery of the ions. The membranes are also preferably impregnated with a buffer to inhibit the effect of the hydrolysis of water by current from the electrodes.

Bibler, J.P.

1993-03-02T23:59:59.000Z

276

Method and apparatus for removing ions from soil  

DOE Patents [OSTI]

A method and apparatus for selectively removing species of ions from an area of soil. Permeable membranes 14 and 18 impregnated with an ion exchange resin that is specific to one or more species of chemical ions are inserted into ground 12 in close proximity to, and on opposing sides of, a soil area of interest 22. An electric potential is applied across electrodes 26 and 28 to cause the migration of ions out of soil area 22 toward the membranes 14 and 18. Preferably, the resin exchanges ions of sodium or hydrogen for ions of mercury that it captures from soil area 22. Once membranes 14 and 18 become substantially saturated with mercury ions, the potential applied across electrodes 26 and 28 is discontinued and membranes 14 and 18 are preferably removed from soil 12 for storage or recovery of the ions. The membranes are also preferably impregnated with a buffer to inhibit the effect of the hydrolysis of water by current from the electrodes.

Bibler, Jane P. (813 E. Rollingwood Rd., Aiken, SC 29801)

1993-01-01T23:59:59.000Z

277

Ion Monitoring  

DOE Patents [OSTI]

The apparatus and method provide a technique for significantly reducing capacitance effects in detector electrodes arising due to movement of the instrument relative to the item/location being monitored in ion detection based techniques. The capacitance variations are rendered less significant by placing an electrically conducting element between the detector electrodes and the monitored location/item. Improved sensitivity and reduced noise signals arise as a result. The technique also provides apparatus and method suitable for monitoring elongate items which are unsuited to complete enclosure in one go within a chamber. The items are monitored part by part as the pass through the instrument, so increasing the range of items or locations which can be successfully monitored.

Orr, Christopher Henry (Calderbridge, GB); Luff, Craig Janson (Calderbridge, GB); Dockray, Thomas (Calderbridge, GB); Macarthur, Duncan Whittemore (Los Alamos, NM)

2003-11-18T23:59:59.000Z

278

Primer on nuclear exchange models  

SciTech Connect (OSTI)

Basic physics is applied to nuclear force exchange models between two nations. Ultimately, this scenario approach can be used to try and answer the age old question of 'how much is enough?' This work is based on Chapter 2 of Physics of Societal Issues: Calculations on National Security, Environment and Energy (Springer, 2007 and 2014)

Hafemeister, David [Physics Department, Cal Poly University, San Luis Obispo, California (United States)

2014-05-09T23:59:59.000Z

279

Chemistry in Disks. IX. Observations and modeling of HCO+ and DCO+ in DM Tau  

E-Print Network [OSTI]

We present resolved Plateau de Bure Array observations of DM Tau in lines of HCO+ (3-2), (1-0) and DCO+ (3-2). A power-law fitting approach allowed a derivation of column densities of these two molecules. A chemical inner hole of ~50 AU was found in both HCO+ and DCO+ with DCO+ emission extending to only 450 AU. An isotopic ratio of R_D = N(DCO+) / N(HCO+) was found to range from 0.1 at 50 AU and 0.2 at 450 AU. Chemical modeling allowed an exploration of the sensitivity of these molecular abundances to physical parameters out with temperature, finding that X-rays were the domination ionization source in the HCO+ molecular region and that R_D also is sensitive to the CO depletion. The ionization fraction, assuming a steady state system, was found to be x(e-) ~ 10$^{-7}$. Modeling suggests that HCO+ is the dominant charged molecule in the disk but its contribution to ionization fraction is dwarfed by atmoic ions such as C+, S+ and H+.

Teague, Richard; Guilloteau, Stephane; Henning, Thomas; Dutrey, Anne; Wakelam, Valentine; Chapillon, Edwige; Pietu, Vincent

2015-01-01T23:59:59.000Z

280

Ion funnel ion trap and process  

DOE Patents [OSTI]

An ion funnel trap is described that includes a inlet portion, a trapping portion, and a outlet portion that couples, in normal operation, with an ion funnel. The ion trap operates efficiently at a pressure of .about.1 Torr and provides for: 1) removal of low mass-to-charge (m/z) ion species, 2) ion accumulation efficiency of up to 80%, 3) charge capacity of .about.10,000,000 elementary charges, 4) ion ejection time of 40 to 200 .mu.s, and 5) optimized variable ion accumulation times. Ion accumulation with low concentration peptide mixtures has shown an increase in analyte signal-to-noise ratios (SNR) of a factor of 30, and a greater than 10-fold improvement in SNR for multiply charged analytes.

Belov, Mikhail E [Richland, WA; Ibrahim, Yehia M [Richland, WA; Clowers, Biran H [West Richland, WA; Prior, David C [Hermiston, OR; Smith, Richard D [Richland, WA

2011-02-15T23:59:59.000Z

Note: This page contains sample records for the topic "ion exchange ix" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Heavy Ion Event Displays  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

simulated collisions of lead ions in the LHC experiments. Additional photos, video and information are available at these links: Lead-ion collision images from the ALICE...

282

ion microprobe | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

microprobe ion microprobe Leads No leads are available at this time. Magnesium behavior and structural defects in Mg+ ion implanted silicon carbide. Abstract: As a candidate...

283

EMSL - secondary ion detection  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

secondary-ion-detection en Magnesium behavior and structural defects in Mg+ ion implanted silicon carbide. http:www.emsl.pnl.govemslwebpublicationsmagnesium-behavior-and-struc...

284

Polymer-Supported Reagents: The Role of Bifunctionality in the Design of Ion-Selective Complexants  

SciTech Connect (OSTI)

The importance of multi-functionality in the preparation of ion-selective polymers is evident from the structure of enzymes where specific metal ions are bound through cooperative interactions among different amino acids. In synthetic polymers, ionic selectivity is enhanced when a chemical reaction is superimposed on an ion-exchange process. The concept of reactive ion exchange has been extended through the synthesis of crosslinked polymers whose metal ion selectivity is a function of reduction, coordination or precipitation reactions as determined by various covalently bound ligands. Development of three classes of dual mechanism bifunctional polymers, a new series of bifunctional diphosphonate polymers, and novel bifunctional ion-selective polymers with enhanced ionic accessibility has been accomplished.

Alexandratos, S. D.

2001-06-01T23:59:59.000Z

285

Second Law Optimization of Heat Exchangers  

E-Print Network [OSTI]

A new method for optimizing heat exchangers is developed in this paper. It is based on second law efficiency relationships rather than on the traditional heat exchanger effectiveness concept. The cost of energy is based on its availability level...

Witte, L. C.

286

Condensing Heat Exchangers Optimize Steam Boilers  

E-Print Network [OSTI]

for Industrial Boilers" R. E. Thompson - R. J. Goldstick KVB, Inc., 18806 Skypark Blvd., Irvine, California 92714, pg. 12-4. (3) "Condensing Heat Exchangers Using Tenon R Covered Tubes", Ronald Hessen, Condensing Heat Exchanger Corp., Latham, New York...

Sullivan, B.; Sullivan, P. A.

1983-01-01T23:59:59.000Z

287

Synergistic diffuser/heat-exchanger design  

E-Print Network [OSTI]

The theoretical and numerical evaluation of synergistic diffusing heat-exchanger design is presented. Motivation for this development is based on current diffuser and heat-exchange technologies in cogeneration plants, which ...

Lazzara, David S. (David Sergio), 1980-

2004-01-01T23:59:59.000Z

288

Efficiency Exchange Conference Highlights Energy Efficiency Innovation...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Energy Efficiency Alliance (NEEA), Bonneville Power Administration and electric utilities throughout the Northwest, are hosting the second annual Efficiency Exchange...

289

The Mechanism Responsible for Extraordinary Cs-ion Selectivity in Crystalline Silicotitanate  

SciTech Connect (OSTI)

Combining information from time-resolved X-ray and neutron scattering with theoretical calculations has revealed the elegant mechanism whereby hydrogen crystalline silicotitanate (H-CST; H2Ti2SiO7{center_dot}1.5H2O) achieves its remarkable ion-exchange selectivity for cesium. Rather than a simple ion-for-ion displacement reaction into favorable sites, which has been suggested by static structural studies of ion-exchanged variants of CST, Cs+ exchange proceeds via a two-step process mediated by conformational changes in the framework. Similar to the case of ion channels in proteins, occupancy of the most favorable site does not occur until the first lever, cooperative repulsive interactions between water and the initial Cs-exchange site, repels a hydrogen lever on the silicotitanate framework. Here we show that these interactions induce a subtle conformational rearrangement in CST that unlocks the preferred Cs site and increases the overall capacity and selectivity for ion exchange.

Celestian,A.; Kubicki, J.; Hanson, J.; Clearfield, A.; Parise, J.

2008-01-01T23:59:59.000Z

290

Science Policy Exchange September 21, 2009 Columbia River Estuary Science-Policy Exchange  

E-Print Network [OSTI]

Science Policy Exchange September 21, 2009 Summary 1 Columbia River Estuary Science-Policy Exchange and Conservation Council hosted a science-policy exchange in Astoria, Oregon. The Council supports strategies Science Advisory Board (ISAB) and the Independent Scientific Review Panel (ISRP) attended the exchange

291

Numerical study of the characteristics of the ion and fast atom beams in an end-Hall ion source  

SciTech Connect (OSTI)

An end-Hall ion source is a cylindrical magnetized device of few centimeters in length able to generate an ion beam with a current of typically 1 A and ion energies in the range of 100 eV. This ion source does not use acceleration grids, has a relatively large ion beam divergence, and is well suited for ion assisted deposition processes. In this paper, a self-consistent two-dimensional quasi-neutral model of an end-Hall ion source is used to understand the parameters controlling the characteristics of the extracted. The model results underline the role of charge exchange collisions on beam properties. The calculated energy distribution functions reveal the existence of groups of slow ions and fast neutrals. Ion mean energy corresponds to roughly 60% of the discharge voltage, while the root mean square deviation from the mean energy corresponds to about 33% of the discharge voltage, as in experiments. The influence of the position of the electron emitting source on the ion angular distribution is also shown.

Oudini, N. [Universite de Toulouse, UPS, INPT, LAPLACE (Laboratoire Plasma et Conversion d'Energie), 118 route de Narbonne, F-31062 Toulouse Cedex 9 (France); Garrigues, L.; Hagelaar, G. J. M.; Boeuf, J. P. [Universite de Toulouse, UPS, INPT, LAPLACE (Laboratoire Plasma et Conversion d'Energie), 118 route de Narbonne, F-31062 Toulouse Cedex 9 (France); CNRS, LAPLACE, F-31062 Toulouse (France)

2012-10-15T23:59:59.000Z

292

Microfabricated ion frequency standard  

DOE Patents [OSTI]

A microfabricated ion frequency standard (i.e. an ion clock) is disclosed with a permanently-sealed vacuum package containing a source of ytterbium (Yb) ions and an octupole ion trap. The source of Yb ions is a micro-hotplate which generates Yb atoms which are then ionized by a ultraviolet light-emitting diode or a field-emission electron source. The octupole ion trap, which confines the Yb ions, is formed from suspended electrodes on a number of stacked-up substrates. A microwave source excites a ground-state transition frequency of the Yb ions, with a frequency-doubled vertical-external-cavity laser (VECSEL) then exciting the Yb ions up to an excited state to produce fluorescent light which is used to tune the microwave source to the ground-state transition frequency, with the microwave source providing a precise frequency output for the ion clock.

Schwindt, Peter (Albuquerque, NM); Biedermann, Grant (Albuquerque, NM); Blain, Matthew G. (Albuquerque, NM); Stick, Daniel L. (Albuquerque, NM); Serkland, Darwin K. (Albuquerque, NM); Olsson, III, Roy H. (Albuquerque, NM)

2010-12-28T23:59:59.000Z

293

OXYGEN 18 EXCHANGE REACTIONS OF ALDEHYDES AND KETONES  

E-Print Network [OSTI]

OXYGEN 18 EXCHANGE REACTIONS OF ALDEHYDES AND KETONES TWO-eng-48 OXYGEN 18 EXCHANGE REACTIONS OF ALDEHYDES AND KETONES

Byrn, Marianne; Calvin, Melvin

1965-01-01T23:59:59.000Z

294

Ion sources for ion implantation technology (invited)  

SciTech Connect (OSTI)

Ion sources for ion implantation are introduced. The technique is applied not only to large scale integration (LSI) devices but also to flat panel display. For LSI fabrication, ion source scheduled maintenance cycle is most important. For CMOS image sensor devices, metal contamination at implanted wafer is most important. On the other hand, to fabricate miniaturized devices, cluster ion implantation has been proposed to make shallow PN junction. While for power devices such as silicon carbide, aluminum ion is required. For doping processes of LCD fabrication, a large ion source is required. The extraction area is about 150 cm × 10 cm, and the beam uniformity is important as well as the total target beam current.

Sakai, Shigeki, E-mail: sakai-shigeki@nissin.co.jp; Hamamoto, Nariaki; Inouchi, Yutaka; Umisedo, Sei; Miyamoto, Naoki [Nissin Ion Equipment co., ltd, 575 Kuze-Tonoshiro-cho Minami-ku, Kyoto 601-8205 (Japan)] [Nissin Ion Equipment co., ltd, 575 Kuze-Tonoshiro-cho Minami-ku, Kyoto 601-8205 (Japan)

2014-02-15T23:59:59.000Z

295

Diffusion and selective transport of alkali cations on cation-exchange membrane  

SciTech Connect (OSTI)

The diffusion coefficients and selective transport for alkali metal cations through a charged polysulfonated ICE-450 ion-exchange membrane were measured as a function of pH at 25{degrees}C. The permeability and diffusion coefficients were found to increase in the sequence Cs{sup +} {ge} K{sup +} {ge} Na{sup +} {ge} Li{sup +}. The relationship between the permeability and the diffusion coefficients, and the hydrated radii of cations in the membrane were shown. This sequence was also explained by considering the hydration of ions in the membrane. The selectivity transport of K-Na and K-Li binary systems at various pH gradients through the membrane were also investigated under various conditions. In the selective transport of metal ions, the selectivity depended on both the hydrated ionic size and the interaction between the fixed groups in the membrane and the metal ions.

Ersoez, M. [Selcuk Univ., Konya (Turkey)

1995-11-01T23:59:59.000Z

296

Microfabricated Ion Traps  

E-Print Network [OSTI]

Ion traps offer the opportunity to study fundamental quantum systems with high level of accuracy highly decoupled from the environment. Individual atomic ions can be controlled and manipulated with electric fields, cooled to the ground state of motion with laser cooling and coherently manipulated using optical and microwave radiation. Microfabricated ion traps hold the advantage of allowing for smaller trap dimensions and better scalability towards large ion trap arrays also making them a vital ingredient for next generation quantum technologies. Here we provide an introduction into the principles and operation of microfabricated ion traps. We show an overview of material and electrical considerations which are vital for the design of such trap structures. We provide guidance in how to choose the appropriate fabrication design, consider different methods for the fabrication of microfabricated ion traps and discuss previously realized structures. We also discuss the phenomenon of anomalous heating of ions within ion traps, which becomes an important factor in the miniaturization of ion traps.

Marcus D. Hughes; Bjoern Lekitsch; Jiddu A. Broersma; Winfried K. Hensinger

2011-06-28T23:59:59.000Z

297

Ion Distribution And Electronic Stopping Power For Au ions In...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Distribution And Electronic Stopping Power For Au ions In Silicon Carbide. Ion Distribution And Electronic Stopping Power For Au ions In Silicon Carbide. Abstract: Accurate...

298

Nuclear proliferation and civilian nuclear power. Report of the Nonproliferation Alternative Systems Assessment Program. Volume IX. Reactor and fuel cycle description  

SciTech Connect (OSTI)

The Nonproliferation Alterntive Systems Assessment Program (NASAP) has characterized and assessed various reactor/fuel-cycle systems. Volume IX provides, in summary form, the technical descriptions of the reactor/fuel-cycle systems studied. This includes the status of the system technology, as well as a discussion of the safety, environmental, and licensing needs from a technical perspective. This information was then used in developing the research, development, and demonstration (RD and D) program, including its cost and time frame, to advance the existing technology to the level needed for commercial use. Wherever possible, the cost data are given as ranges to reflect the uncertainties in the estimates.

Not Available

1980-06-01T23:59:59.000Z

299

Broad beam ion implanter  

DOE Patents [OSTI]

An ion implantation device for creating a large diameter, homogeneous, ion beam is described, as well as a method for creating same, wherein the device is characterized by extraction of a diverging ion beam and its conversion by ion beam optics to an essentially parallel ion beam. The device comprises a plasma or ion source, an anode and exit aperture, an extraction electrode, a divergence-limiting electrode and an acceleration electrode, as well as the means for connecting a voltage supply to the electrodes.

Leung, Ka-Ngo (Hercules, CA)

1996-01-01T23:59:59.000Z

300

Mathematical Modeling of Cation Contamination in a Proton-exchange Membrane  

SciTech Connect (OSTI)

Transport phenomena in an ion-exchange membrane containing both H+ and K+ are described using multicomponent diffusion equations (Stefan-Maxwell). A model is developed for transport through a Nafion 112 membrane in a hydrogen-pump setup. The model results are analyzed to quantify the impact of cation contamination on cell potential. It is shown that limiting current densities can result due to a decrease in proton concentration caused by the build-up of contaminant ions. An average cation concentration of 30 to 40 percent is required for appreciable effects to be noticed under typical steady-state operating conditions.

Weber, Adam; Delacourt, Charles

2008-09-11T23:59:59.000Z

Note: This page contains sample records for the topic "ion exchange ix" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Exchange Fluctuation Theorem for correlated quantum systems  

E-Print Network [OSTI]

We extend the Exchange Fluctuation Theorem for energy exchange between thermal quantum systems beyond the assumption of molecular chaos, and describe the non-equilibrium exchange dynamics of correlated quantum states. The relation quantifies how the tendency for systems to equilibrate is modified in high-correlation environments. Our results elucidate the role of measurement disturbance for such scenarios. We show a simple application by finding a semi-classical maximum work theorem in the presence of correlations.

Sania Jevtic; David Jennings; Terry Rudolph; Yuji Hirono; Shojun Nakayama; Mio Murao

2014-12-04T23:59:59.000Z

302

Superconducting microfabricated ion traps  

E-Print Network [OSTI]

We fabricate superconducting ion traps with niobium and niobium nitride and trap single [superscript 88]Sr ions at cryogenic temperatures. The superconducting transition is verified and characterized by measuring the ...

Wang, Shannon Xuanyue

303

Low-Cost Microchannel Heat Exchanger  

Broader source: Energy.gov (indexed) [DOE]

Produce prototype heat exchangers for electronics cooling and high pressure waste heat recovery power system applications Test integrity and confirm high performance of...

304

NETL's Energy Data eXchange  

ScienceCinema (OSTI)

A brief tour around NETL's Energy Data Exchange site, where researchers can upload data or look at data from another researcher.

None

2014-07-22T23:59:59.000Z

305

NETL's Energy Data eXchange  

SciTech Connect (OSTI)

A brief tour around NETL's Energy Data Exchange site, where researchers can upload data or look at data from another researcher.

None

2014-07-16T23:59:59.000Z

306

THERMOSIPHON WATER HEATERS WITH HEAT EXCHANGERS  

E-Print Network [OSTI]

The Performance of Solar Water Heater With Natural Ci rcul2-6, 1980 THERMOSIPHON WATER HEATERS WITH HEAT EXCHANGERSJune 1980 THERMOSIPHON WATER HEATERS WITH HEAT EXCHANGERS*

Mertol, Atila

2012-01-01T23:59:59.000Z

307

Manufacturing serendipity: Chicago Innovation Exchange enhancing...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Social Media Photos Videos Fact Sheets, Brochures and Reports Summer Science Writing Internship John Flavin, Executive Director of the Chicago Innovation Exchange, started a small...

308

Single Ion Implantation  

SciTech Connect (OSTI)

On the equipment needed to implant ions in silicon and other materials. More information: http://newscenter.lbl.gov/f...

Thomas Schenkel

2008-10-21T23:59:59.000Z

309

Single Ion Implantation  

ScienceCinema (OSTI)

On the equipment needed to implant ions in silicon and other materials. More information: http://newscenter.lbl.gov/f...

Thomas Schenkel

2010-01-08T23:59:59.000Z

310

Helium-like ions as powerful X-ray plasma diagnostics  

E-Print Network [OSTI]

We revisited the calculations of the ratios of the Helium-like ion ``triplet'' (resonance, intercombination, and forbidden lines) for Z=6 to 14 (C V, N VI, O VII, Ne IX, Mg XI, Si XIII) in order to provide temperature, density and ionization diagnostics for the new high-resolution spectroscopic data of Chandra and XMM-Newton. Comparing to earlier computations, collisional rates are updated and the best experimental values for radiative transition probabilities are used. The influence of an external radiation field (photo-excitation) and the contribution from unresolved dielectronic satellite lines to the line ratios are discussed. Collision-dominated plasmas (e.g. stellar coronae), photo-ionized plasmas (e.g. AGNs) or transient plasmas (e.g. SNRs) are considered.

D. Porquet; R. Mewe; A. J. J Raassen; J. S. Kaastra; J. Dubau

2000-12-12T23:59:59.000Z

311

Lithium Ion Production NDE  

E-Print Network [OSTI]

Lithium Ion Electrode Production NDE and QC Considerations David Wood, Debasish Mohanty, Jianlin Li, and Claus Daniel 12/9/13 EERE Quality Control Workshop #12;2 Presentation name Lithium Ion Electrode to be meaningful and provide electrode and cell QC. #12;3 Presentation name New Directions in Lithium Ion Electrode

312

Lithium ion sources  

E-Print Network [OSTI]

HIFAN 1866 Lithium ion sources by Prabir K. Roy, Wayne G.No. DE-AC02-05CH11231. Lithium ion sources Prabir K. RoyUSA Abstract A 10.9 cm diameter lithium alumino-silicate ion

Roy, Prabir K.

2014-01-01T23:59:59.000Z

313

NEW Fe IX LINE IDENTIFICATIONS USING SOLAR AND HELIOSPHERIC OBSERVATORY/SOLAR ULTRAVIOLET MEASUREMENT OF EMITTED RADIATION AND HINODE/EIS JOINT OBSERVATIONS OF THE QUIET SUN  

SciTech Connect (OSTI)

In this work, we study joint observations of Hinode/EUV Imaging Spectrometer (EIS) and Solar and Heliospheric Observatory/Solar Ultraviolet Measurement of Emitted Radiation of Fe IX lines emitted by the same level of the high energy configuration 3s {sup 2}3p {sup 5}4p. The intensity ratios of these lines are dependent on atomic physics parameters only and not on the physical parameters of the emitting plasma, so that they are excellent tools to verify the relative intensity calibration of high-resolution spectrometers that work in the 170-200 A and 700-850 A wavelength ranges. We carry out extensive atomic physics calculations to improve the accuracy of the predicted intensity ratio, and compare the results with simultaneous EIS-SUMER observations of an off-disk quiet Sun region. We were able to identify two ultraviolet lines in the SUMER spectrum that are emitted by the same level that emits one bright line in the EIS wavelength range. Comparison between predicted and measured intensity ratios, wavelengths and energy separation of Fe IX levels confirms the identifications we make. Blending and calibration uncertainties are discussed. The results of this work are important for cross-calibrating EIS and SUMER, as well as future instrumentation.

Landi, E.; Young, P. R. [Naval Research Laboratory, Space Science Division, Washington, DC 20375 (United States)

2009-12-20T23:59:59.000Z

314

Energy spectrum of argon ions emitted from Filippov type Sahand plasma focus  

SciTech Connect (OSTI)

The energy and flux of the argon ions produced in Sahand plasma focus have been measured by employing a well-designed Faraday cup. The secondary electron emission effects on the ion signals are simulated and the dimensions of Faraday cup are optimized to minimize these effects. The measured ion energy spectrum is corrected for the ion energy loss and charge exchange in the background gas. The effects of the capacitor bank voltage and working gas pressure on the ion energy spectrum are also investigated. It has been shown that the emitted ion number per energy increases as the capacitor bank voltage increases. Decreasing the working gas pressure leads to the increase in the number of emitted ion per energy.

Mohammadnejad, M.; Pestehe, S. J.; Mohammadi, M. A. [Department of Atomic and Molecular Physics, Faculty of Physics, University of Tabriz, Postal Code 5166614766, Tabriz (Iran, Islamic Republic of) [Department of Atomic and Molecular Physics, Faculty of Physics, University of Tabriz, Postal Code 5166614766, Tabriz (Iran, Islamic Republic of); Research Institute for Applied Physics and Astronomy, University of Tabriz, Tabriz (Iran, Islamic Republic of)

2013-07-15T23:59:59.000Z

315

Superconducting microfabricated ion traps  

E-Print Network [OSTI]

We fabricate superconducting ion traps with niobium and niobium nitride and trap single 88Sr ions at cryogenic temperatures. The superconducting transition is verified and characterized by measuring the resistance and critical current using a 4-wire measurement on the trap structure, and observing change in the rf reflection. The lowest observed heating rate is 2.1(3) quanta/sec at 800 kHz at 6 K and shows no significant change across the superconducting transition, suggesting that anomalous heating is primarily caused by noise sources on the surface. This demonstration of superconducting ion traps opens up possibilities for integrating trapped ions and molecular ions with superconducting devices.

Shannon X. Wang; Yufei Ge; Jaroslaw Labaziewicz; Eric Dauler; Karl Berggren; Isaac L. Chuang

2010-12-14T23:59:59.000Z

316

Combustion of calcium-exchanged coal. First quarterly report  

SciTech Connect (OSTI)

The work performed during this first period includes equipment modification, development of analytical methods, oxidative pretreatment runs and combustion runs. The coal feeding section of an existing furnace was modified for uninterrupted feeding and better control of residence time. Analytical methods for sulfur and calcium in the coal and ash and for gaseous SO/sub 2/ were standardized. Oxidative pretreatment experiments were conducted in a fluidized bed at temperatures about 200/sup 0/C to evaluate the potential of this method for increasing the ion exchange capacity of coals and determine the accompanying loss of heating value. Combustion experiments were carried out at very high particle temperatures (2000/sup 0/K) at which a large fraction of the calcium additive was vaporized while 50 to 80% of the sulfur evolved as sulfur oxide. Continuing combustion experiments will be conducted at lower particle temperatures.

Gavalas, G.R.; Flagan, R.C.

1984-02-10T23:59:59.000Z

317

Microfabricated ion trap array  

DOE Patents [OSTI]

A microfabricated ion trap array, comprising a plurality of ion traps having an inner radius of order one micron, can be fabricated using surface micromachining techniques and materials known to the integrated circuits manufacturing and microelectromechanical systems industries. Micromachining methods enable batch fabrication, reduced manufacturing costs, dimensional and positional precision, and monolithic integration of massive arrays of ion traps with microscale ion generation and detection devices. Massive arraying enables the microscale ion traps to retain the resolution, sensitivity, and mass range advantages necessary for high chemical selectivity. The reduced electrode voltage enables integration of the microfabricated ion trap array with on-chip circuit-based rf operation and detection electronics (i.e., cell phone electronics). Therefore, the full performance advantages of the microfabricated ion trap array can be realized in truly field portable, handheld microanalysis systems.

Blain, Matthew G. (Albuquerque, NM); Fleming, James G. (Albuquerque, NM)

2006-12-26T23:59:59.000Z

318

K+ production in baryon-baryon and heavy-ion collisions  

E-Print Network [OSTI]

Kaon production cross sections in nucleon-nucleon, nucleon-Delta, and Delta-Delta interactions are studied in a boson exchange model. For the latter two interactions, the exchanged pion can be on-mass shell...only contributions due to a virtual pion an included via the Peierls method by taking into account the finite Delta width. With these cross sections and also those for pion-baryon interactions, subthreshold kaon production from heavy-ion collisions...

Li, GQ; Ko, Che Ming; Chung, WS.

1998-01-01T23:59:59.000Z

319

WAGES, FLEXIBLE EXCHANGE RATES, AND MACROECONOMIC POLICY*  

E-Print Network [OSTI]

WAGES, FLEXIBLE EXCHANGE RATES, AND MACROECONOMIC POLICY* JEFFREY SACHS In an open economy with a floaLing exchange rate, the efficacy of fiscal and monetary policy depends fundamentally on the wage rate depreciation, while fiscal expansion has no output effect. These results hold only when real wages

320

Thermodynamic Efficiency of Heat Exchange Devices  

E-Print Network [OSTI]

is defined for heat exchange devices. The efficiency can be simply written in terms of the mean absolute temperature levels of the two fluids exchanging heat, and an appropriate environment temperature. It is also shown that for a given ratio of hot to cold...

Witte, L. C.; Shamsundar, N.

1982-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "ion exchange ix" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Most spin-1/2 transition-metal ions do have single ion anisotropy  

SciTech Connect (OSTI)

The cause for the preferred spin orientation in magnetic systems containing spin-1/2 transition-metal ions was explored by studying the origin of the easy-plane anisotropy of the spin-1/2 Cu{sup 2+} ions in CuCl{sub 2}·2H{sub 2}O, LiCuVO{sub 4}, CuCl{sub 2}, and CuBr{sub 2} on the basis of density functional theory and magnetic dipole-dipole energy calculations as well as a perturbation theory treatment of the spin-orbit coupling. We find that the spin orientation observed for these spin-1/2 ions is not caused by their anisotropic spin exchange interactions, nor by their magnetic dipole-dipole interactions, but by the spin-orbit coupling associated with their crystal-field split d-states. Our study also predicts in-plane anisotropy for the Cu{sup 2+} ions of Bi{sub 2}CuO{sub 4} and Li{sub 2}CuO{sub 2}. The results of our investigations dispel the mistaken belief that magnetic systems with spin-1/2 ions have no magnetic anisotropy induced by spin-orbit coupling.

Liu, Jia; Whangbo, Myung-Hwan, E-mail: hxiang@fudan.edu.cn, E-mail: mike-whangbo@ncsu.edu [Department of Chemistry, North Carolina State University, Raleigh, North Carolina 27695 (United States); Koo, Hyun-Joo [Department of Chemistry and Research Institute for Basic Sciences, Kyung Hee University, Seoul 130-701 (Korea, Republic of); Xiang, Hongjun, E-mail: hxiang@fudan.edu.cn, E-mail: mike-whangbo@ncsu.edu [Key Laboratory of Computational Physical Sciences (Ministry of Education), State Key Laboratory of Surface Physics, and Department of Physics, Fudan University, Shanghai 200433 (China); Kremer, Reinhard K. [Max-Planck-Institut für Festkörperforschung, Heisenbergstrasse 1, D-70569 Stuttgart (Germany)

2014-09-28T23:59:59.000Z

322

FAST ION STUDIES OF ION CYCLOTRON HEATING  

E-Print Network [OSTI]

responsible for the design, construction, and cali bration of the charge exchange neutral analyzer. Bob this "resonance local ization" by imparting perpendicular energy to particles, and by imparting more energy-resolving, neutral particle analyzer, al though the assumed RF power deposition profile needed to match the data

Hammett, Greg

323

2013 IREP Symposium-Bulk Power System Dynamics and Control IX (IREP), August 25-30, 2013, Rethymnon, Greece A Production Simulation Tool for Systems with an Integrated Concentrated Solar  

E-Print Network [OSTI]

, Rethymnon, Greece A Production Simulation Tool for Systems with an Integrated Concentrated Solar Plant2013 IREP Symposium-Bulk Power System Dynamics and Control ­IX (IREP), August 25-30, 2013 with Thermal Energy Storage Ti Xu George Gross University of Illinois at Urbana-Champaign University

Gross, George

324

Built-in biaxial strain dependence of I'-X transport in GaAs/ln,Al, -,AsJGaAs pseudomorphic heterojunction barriers (x=0, 0.03, and 0.06)  

E-Print Network [OSTI]

of thermionic emission and tunneling currents for the case of IT-X transport are signifi- cantly smaller thanBuilt-in biaxial strain dependence of I'-X transport in GaAs/ln,Al, -,AsJGaAs pseudomorphic 5800, Albuquerque, New Mexico 8718.5-1370 (Received 12 May 1994; accepted for publication 26 August

Yang, Kyounghoon

325

Kr II and Xe II axial velocity distribution functions in a cross-field ion source  

SciTech Connect (OSTI)

Laser induced fluorescence measurements were carried out in a cross-field ion source to examine the behaviour of the axial ion velocity distribution functions (VDFs) in the expanding plasma. In the present paper, we focus on the axial VDFs of Kr II and Xe II ions. We examine the contourplots in a 1D-phase space (x,v{sub x}) representation in front of the exhaust channel and along the centerline of the ion source. The main ion beam, whose momentum corresponds to the ions that are accelerated through the whole potential drop, is observed. A secondary structure reveals the ions coming from the opposite side of the channel. We show that the formation of the neutralized ion flow is governed by the annular geometry. The assumption of a collisionless shock or a double layer due to supersonic beam interaction is not necessary. A non-negligible fraction of slow ions originates in local ionization or charge-exchange collision events between ions of the expanding plasma and atoms of the background residual gas. Slow ions that are produced near the centerline in the vicinity of the exit plane are accelerated toward the source body with a negative velocity leading to a high sputtering of front face. On the contrary, the ions that are produced in the vicinity of the channel exit plane are partially accelerated by the extended electric field.

Lejeune, A.; Bourgeois, G.; Mazouffre, S. [ICARE, CNRS, 1C Avenue de la Recherche Scientifique, 45071 Orlans Cedex 2 (France)

2012-07-15T23:59:59.000Z

326

Sorption of heavy metal ions on new metal-ligand complexes chemically derived from Lycopodium clavatum  

SciTech Connect (OSTI)

Sorption of heavy metal ions from aqueous solution has been investigated as a function of pH using a novel exchanger system whereby Lycopodium clavatum is functionalized with carboxylate and glyoxime metal-ligand complexes. The new ligand exchangers were prepared using a reaction of diaminosporopollenin with various metal-ligand complexes of glyoxime and monocarboxylic acid. The sorptive behavior of these metal-ligand exchangers and the possibilities to remove and to recover selectively heavy metal cations using these systems are discussed on the basis of their chemical natures and their complexing properties.

Pehlivan, E.; Ersoz, M.; Yildiz, S. [Univ. of Selcuk, Konya (Turkey); Duncan, H.J. [Univ. of Glasgow, Scotland (United Kingdom)

1994-08-01T23:59:59.000Z

327

Ion photon emission microscope  

DOE Patents [OSTI]

An ion beam analysis system that creates microscopic multidimensional image maps of the effects of high energy ions from an unfocussed source upon a sample by correlating the exact entry point of an ion into a sample by projection imaging of the ion-induced photons emitted at that point with a signal from a detector that measures the interaction of that ion within the sample. The emitted photons are collected in the lens system of a conventional optical microscope, and projected on the image plane of a high resolution single photon position sensitive detector. Position signals from this photon detector are then correlated in time with electrical effects, including the malfunction of digital circuits, detected within the sample that were caused by the individual ion that created these photons initially.

Doyle, Barney L. (Albuquerque, NM)

2003-04-22T23:59:59.000Z

328

Collection of ions  

DOE Patents [OSTI]

The apparatus and method provide an improved technique for detecting ions as the area from which ions are attracted to a detector is increased, consequently increasing the number of ions detected. This is achieved by providing the outer electrodes of the detector connected to the electrical potential, together with alternate intermediate electrodes. The other intermediate electrodes and preferably the housing are grounded. The technique renders such detection techniques more sensitive and gives them a lower threshold at which they can function.

Orr, Christopher Henry (Calderbridge, GB); Luff, Craig Janson (Calderbridge, GB); Dockray, Thomas (Calderbridge, GB); Macarthur, Duncan Whittemore (Los Alamos, NM); Bounds, John Alan (Los Alamos, NM); Koster, James E. (Los Alamos, NM)

2001-01-01T23:59:59.000Z

329

Skew chicane based betatron eigenmode exchange module  

DOE Patents [OSTI]

A skewed chicane eigenmode exchange module (SCEEM) that combines in a single beamline segment the separate functionalities of a skew quad eigenmode exchange module and a magnetic chicane. This module allows the exchange of independent betatron eigenmodes, alters electron beam orbit geometry, and provides longitudinal parameter control with dispersion management in a single beamline segment with stable betatron behavior. It thus reduces the spatial requirements for multiple beam dynamic functions, reduces required component counts and thus reduces costs, and allows the use of more compact accelerator configurations than prior art design methods.

Douglas, David (Yorktown, VA)

2010-12-28T23:59:59.000Z

330

EMSL - ion microprobe  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

microprobe en Magnesium behavior and structural defects in Mg+ ion implanted silicon carbide. http:www.emsl.pnl.govemslwebpublicationsmagnesium-behavior-and-structural-defects...

331

Correlation ion mobility spectroscopy  

DOE Patents [OSTI]

Correlation ion mobility spectrometry (CIMS) uses gating modulation and correlation signal processing to improve IMS instrument performance. Closely spaced ion peaks can be resolved by adding discriminating codes to the gate and matched filtering for the received ion current signal, thereby improving sensitivity and resolution of an ion mobility spectrometer. CIMS can be used to improve the signal-to-noise ratio even for transient chemical samples. CIMS is especially advantageous for small geometry IMS drift tubes that can otherwise have poor resolution due to their small size.

Pfeifer, Kent B. (Los Lunas, NM); Rohde, Steven B. (Corrales, NM)

2008-08-26T23:59:59.000Z

332

Kitchen Appliance Upgrades Improve Water Efficiency at DOD Exchange...  

Broader source: Energy.gov (indexed) [DOE]

Kitchen Appliance Upgrades Improve Water Efficiency at DOD Exchange Facilities Case study details the U.S. Department of Defense (DOD) Exchange (formerly the Army and Air Force...

333

Electrically Controlled Anion Exchange Based on Polypyrrole and...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Controlled Anion Exchange Based on Polypyrrole and Carbon Nanotubes Nanocomposite for Perchlorate Removal . Electrically Controlled Anion Exchange Based on Polypyrrole and Carbon...

334

Light weight and economical exhaust heat exchanger for waste...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

exhaust heat exchanger for waste heat recovery using mixed radiant and convective heat transfer Light weight and economical exhaust heat exchanger for waste heat recovery...

335

Exploration Best Practices and the OpenEI Knowledge Exchange...  

Energy Savers [EERE]

Exchange Webinar Exploration Best Practices and the OpenEI Knowledge Exchange Webinar slide presentation by Katherine Young, Timothy Reber and Kermit Witherbee on April 11, 2012....

336

Proton Exchange Membrane Fuel Cells for Electrical Power Generation...  

Broader source: Energy.gov (indexed) [DOE]

Proton Exchange Membrane Fuel Cells for Electrical Power Generation On-Board Commercial Airplanes Proton Exchange Membrane Fuel Cells for Electrical Power Generation On-Board...

337

Lessons Learned: Peer Exchange Calls Fall 2014 | Department of...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Calls Fall 2014 Lessons Learned: Peer Exchange Calls Fall 2014 Better Buildings Residential Network, Lessons Learned: Peer Exchange Calls Fall 2014. Lessons Learned: Peer...

338

Better Buildings Residential Network: Lessons Learned: Peer Exchange...  

Energy Savers [EERE]

Better Buildings Residential Network: Lessons Learned: Peer Exchange Calls Better Buildings Residential Network: Lessons Learned: Peer Exchange Calls Better Buildings Residential...

339

2012 National Trainers' Exchange for Department of Energy Safety...  

Office of Environmental Management (EM)

TN. Over 100 participants attended the Trainers' Exchange to share and exchange best practices and techniques on how to create more effective and empowering training. The...

340

Antiferromagnetic domain size and exchange bias  

E-Print Network [OSTI]

Using neutron diffraction, we measured the sizes of antiferromagnetic domains in three ferromagnet/antiferromagnet bilayer samples as a function of the magnitude and sign of exchange bias, temperature, and antiferromagnet composition. Neutron...

Fitzsimmons, M. R.; Lederman, D.; Cheon, M.; Shi, H.; Olamit, J.; Roshchin, Igor V.; Schuller, Ivan K.

2008-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "ion exchange ix" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Adaptive systems for foreign exchange trading  

E-Print Network [OSTI]

, Cambridge, and Dr Mark Austin and Dr Stacy Williams, both of HSBC Global Markets, outline the results- niques in foreign exchange markets for a number of years. Over 18 months a joint project with HSBC Global

Fernandez, Thomas

342

Configuring Entourage 2008 w/ Exchange Web Services. Note: These instruction assume that the Exchange Web Services (EWS) Update  

E-Print Network [OSTI]

Configuring Entourage 2008 w/ Exchange Web Services. Note: These instruction assume that the Exchange Web Services (EWS) Update , also known as Entourage 13.0, has already been

Blackwell, Keith

343

Integrated Approach to Revamping Heat Exchangers Networks  

E-Print Network [OSTI]

geometry configurations for a given set of process conditions. Develop simulation model (in Aspen Plus) incorporating rigorous heat exchanger (Aspen Hetran) models for the 1) Validate existing preheat train performance & evaluate the existing and de...-bottlenecked cases de-bottlenecked performance Initiate pinch analysis (using Aspen Pinch) directly 2) Determine feasible energy saving from (Aspen Plus) simulation results Heat exchanger network pinch analysis (using Aspen Pinch) incorporating rigorous (Aspen...

Glass, K. E.; Dhole, V.; Wang, Y.

344

Heat Exchanger Technologies for Distillation Columns  

E-Print Network [OSTI]

each type of exchanger in turn. Heat exchanger size is minimised if the temperature driving force is maximised. The design should therefore seek to minimise the temperature changes during phase change. So, streams that are being condensed are kept... Reboiler not always possible (e.g. one part of a unit may be running at reduced load). Result: installed steam driven unit required to ensure integrity or heat recovery not used. Low temperature driving force Operation at low temperature driving force...

Polley, G. T.

345

Exchange Visitors Program | Department of Energy  

Energy Savers [EERE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious RankCombustion |Energy UsageAUDITVehicles »Exchange Visitors Program Exchange Visitors Program The

346

Heat exchanger for power generation equipment  

DOE Patents [OSTI]

A heat exchanger for a turbine is provided wherein the heat exchanger comprises a heat transfer cell comprising a sheet of material having two opposed ends and two opposed sides. In addition, a plurality of concavities are disposed on a surface portion of the sheet of material so as to cause hydrodynamic interactions and affect a heat transfer rate of the turbine between a fluid and the concavities when the fluid is disposed over the concavities.

Nirmalan, Nirm Velumylm; Bowman, Michael John

2005-06-14T23:59:59.000Z

347

Selective ion source  

DOE Patents [OSTI]

A ion source is described wherein selected ions maybe extracted to the exclusion of unwanted ion species of higher ionization potential. Also described is a method of producing selected ions from a compound, such as P{sup +} from PH{sub 3}. The invention comprises a plasma chamber, an electron source, a means for introducing a gas to be ionized by electrons from the electron source, means for limiting electron energy from the electron source to a value between the ionization energy of the selected ion species and the greater ionization energy of an unwanted ion specie, and means for extracting the target ion specie from the plasma chamber. In one embodiment, the electrons are generated in a plasma cathode chamber immediately adjacent to the plasma chamber. A small extractor draws the electrons from the plasma cathode chamber into the relatively positive plasma chamber. The energy of the electrons extracted in this manner is easily controlled. The invention is particularly useful for doping silicon with P{sup +}, As{sup +}, and B{sup +} without the problematic presence of hydrogen, helium, water, or carbon oxide ions. Doped silicon is important for manufacture of semiconductors and semiconductor devices. 6 figs.

Leung, K.N.

1996-05-14T23:59:59.000Z

348

Selective ion source  

DOE Patents [OSTI]

A ion source is described wherein selected ions maybe extracted to the exclusion of unwanted ion species of higher ionization potential. Also described is a method of producing selected ions from a compound, such as P.sup.+ from PH.sub.3. The invention comprises a plasma chamber, an electron source, a means for introducing a gas to be ionized by electrons from the electron source, means for limiting electron energy from the electron source to a value between the ionization energy of the selected ion species and the greater ionization energy of an unwanted ion specie, and means for extracting the target ion specie from the plasma chamber. In one embodiment, the electrons are generated in a plasma cathode chamber immediately adjacent to the plasma chamber. A small extractor draws the electrons from the plasma cathode chamber into the relatively positive plasma chamber. The energy of the electrons extracted in this manner is easily controlled. The invention is particularly useful for doping silicon with P.sup.+, AS.sup.+, and B.sup.+ without the problematic presence of hydrogen, helium, water, or carbon oxide ions. Doped silicon is important for manufacture of semiconductors and semiconductor devices.

Leung, Ka-Ngo (Hercules, CA)

1996-01-01T23:59:59.000Z

349

Ion-beam technologies  

SciTech Connect (OSTI)

This compilation of figures and diagrams reviews processes for depositing diamond/diamond-like carbon films. Processes addressed are chemical vapor deposition (HFCVD, PACVD, etc.), plasma vapor deposition (plasma sputtering, ion beam sputtering, evaporation, etc.), low-energy ion implantation, and hybrid processes (biased sputtering, IBAD, biased HFCVD, etc.). The tribological performance of coatings produced by different means is discussed.

Fenske, G.R. [Argonne National Lab., IL (United States)

1993-01-01T23:59:59.000Z

350

Microfabricated cylindrical ion trap  

SciTech Connect (OSTI)

A microscale cylindrical ion trap, having an inner radius of order one micron, can be fabricated using surface micromachining techniques and materials known to the integrated circuits manufacturing and microelectromechanical systems industries. Micromachining methods enable batch fabrication, reduced manufacturing costs, dimensional and positional precision, and monolithic integration of massive arrays of ion traps with microscale ion generation and detection devices. Massive arraying enables the microscale cylindrical ion trap to retain the resolution, sensitivity, and mass range advantages necessary for high chemical selectivity. The microscale CIT has a reduced ion mean free path, allowing operation at higher pressures with less expensive and less bulky vacuum pumping system, and with lower battery power than conventional- and miniature-sized ion traps. The reduced electrode voltage enables integration of the microscale cylindrical ion trap with on-chip integrated circuit-based rf operation and detection electronics (i.e., cell phone electronics). Therefore, the full performance advantages of microscale cylindrical ion traps can be realized in truly field portable, handheld microanalysis systems.

Blain, Matthew G.

2005-03-22T23:59:59.000Z

351

Ion mobility sensor system  

DOE Patents [OSTI]

An ion mobility sensor system including an ion mobility spectrometer and a differential mobility spectrometer coupled to the ion mobility spectrometer. The ion mobility spectrometer has a first chamber having first end and a second end extending along a first direction, and a first electrode system that generates a constant electric field parallel to the first direction. The differential mobility spectrometer includes a second chamber having a third end and a fourth end configured such that a fluid may flow in a second direction from the third end to the fourth end, and a second electrode system that generates an asymmetric electric field within an interior of the second chamber. Additionally, the ion mobility spectrometer and the differential mobility spectrometer form an interface region. Also, the first end and the third end are positioned facing one another so that the constant electric field enters the third end and overlaps the fluid flowing in the second direction.

Xu, Jun; Watson, David B.; Whitten, William B.

2013-01-22T23:59:59.000Z

352

Experimental and theoretical treatment of elementary ligand exchange reactions in aluminum complexes  

SciTech Connect (OSTI)

Substitution of a hydroxide or fluoride ion for a water molecule in the inner-coordination sphere of Al(OH{sub 2}){sub 6}{sup 3+} considerably weakens bonds from aluminum to other water molecules that are also in the inner-coordination sphere. The labilizing effect of these substitutions on the rate of dissociation of Al-O bonds is a model for ligand-promoted dissolution of aluminum (hydr)oxide minerals. Here measured activation parameters for ligand exchange are compared with ab initio calculations of the energetics for comparable reactions. Because solvent exchange is an elementary reaction, it is particularly well-suited for such comparisons. The calculations indicate that substitution of hydroxide or fluoride ion into the inner-coordination sphere greatly reduces the energy requires to remove a water molecule. The calculated and measured activation energies, however, differ significantly. A reasonable interpretation is that interactions between hydration waters and second-sphere water molecules, which are usually partly or fully excluded from the calculations, contribute to the exchange mechanism.

Phillips, B.L.; Casey, W.H. [Univ. of California, Davis, CA (United States)] [Univ. of California, Davis, CA (United States); Tossell, J.A. [Univ. of Maryland, College Park, MD (United States). Dept. of Chemistry] [Univ. of Maryland, College Park, MD (United States). Dept. of Chemistry

1998-10-01T23:59:59.000Z

353

A gas ion source for continuous-flow AMS R.J. Schneider a,*, S.-W. Kim a,c  

E-Print Network [OSTI]

A and negative ion currents up to 80 lA. Recently, the compact, permanent-magnet microwave plasma ion source and magnesium vapor charge-exchange canal were coupled to the recombinator injector of the 2.5 MV Tandetron magnet. Small samples containing several micromoles of CO2 could be entrained in a stream of argon used

Sessions, Alex L.

354

Potentiometric Sensor for Real-Time Monitoring of Multivalent Ion Concentrations in Molten Salt  

SciTech Connect (OSTI)

Electrorefining of spent metallic nuclear fuel in high temperature molten salt systems is a core technology in pyroprocessing, which in turn plays a critical role in the development of advanced fuel cycle technologies. In electrorefining, spent nuclear fuel is treated electrochemically in order to effect separations between uranium, noble metals, and active metals, which include the transuranics. The accumulation of active metals in a lithium chloride-potassium chloride (LiCl-KCl) eutectic molten salt electrolyte occurs at the expense of the UCl3-oxidant concentration in the electrolyte, which must be periodically replenished. Our interests lie with the accumulation of active metals in the molten salt electrolyte. The real-time monitoring of actinide concentrations in the molten salt electrolyte is highly desirable for controlling electrochemical operations and assuring materials control and accountancy. However, real-time monitoring is not possible with current methods for sampling and chemical analysis. A new solid-state electrochemical sensor is being developed for real-time monitoring of actinide ion concentrations in a molten salt electrorefiner. The ultimate function of the sensor is to monitor plutonium concentrations during electrorefining operations, but in this work gadolinium was employed as a surrogate material for plutonium. In a parametric study, polycrystalline sodium beta double-prime alumina (Na-ß?-alumina) discs and tubes were subject to vapor-phase exchange with gadolinium ions (Gd3+) using a gadolinium chloride salt (GdCl3) as a precursor to produce gadolinium beta double-prime alumina (Gd-ß?-alumina) samples. Electrochemical impedance spectroscopy and microstructural analysis were performed on the ion-exchanged discs to determine the relationship between ion exchange and Gd3+ ion conductivity. The ion-exchanged tubes were configured as potentiometric sensors in order to monitor real-time Gd3+ ion concentrations in mixtures of gadolinium chloride (GdCl3) in LiCl-KCl eutectic molten salts through measurement of the potential difference between a reference and working electrode.

Peter A. Zink; Jan-Fong Jue; Brenda E. Serrano; Guy L. Fredrickson; Ben F. Cowan; Steven D. Herrmann; Shelly X. Li

2010-07-01T23:59:59.000Z

355

Simulation of ion heating in the topside auroral ionosphere  

SciTech Connect (OSTI)

Energization of ions to low energies (less than or equal to10 eV) in the topside ionosphere (300--2000 km altitude) has been observed for a decade. These ionospheric ions have been invoked as the source population of keV ions energized in the auroral magnetosphere (greater than or equal to1 R/sub E/ altitude). If so, the importance of the topside ionosphere as a source of magnetospheric plasma must be assessed quantitatively. To determine the efficiencies of this topside auroral ionospheric source of magnetospheric plasma, Monte Carlo simulations of wave-particle ion heating under realistic topside conditions have been carried out. It is shown that the source efficiency is greatly affected by (1) copious charge exchange interactions between the ions and thermospheric neutrals at an early stage of heating and (2) the observed existence of downward parallel electric potential drops. The composition of warm ions escaping the topside is predicted to be drastically different from the cold ionospheric composition. This study also predicts the existence of a hot (<10 eV) population of thermospheric neutrals in the high latitude topside ionosphere. copyright American Geophysical Union 1988

Chiu, Y.T.; Cladis, J.B.; Francis, W.E.

1988-12-01T23:59:59.000Z

356

Charge exchange and chemical reactions with trapped Th{sup 3+}  

SciTech Connect (OSTI)

We have measured the reaction rates of trapped, buffer gas cooled Th{sup 3+} and various gases and have analyzed the reaction products using trapped ion mass spectrometry techniques. Ion trap lifetimes are usually limited by reactions with background molecules, and the high electron affinity of multiply charged ions such as Th{sup 3+} make them more prone to loss. Our results show that reactions of Th{sup 3+} with carbon dioxide, methane, and oxygen all occur near the classical Langevin rate, while reaction rates with argon, hydrogen, and nitrogen are orders of magnitude lower. Reactions of Th{sup 3+} with oxygen and methane proceed primarily via charge exchange, while simultaneous charge exchange and chemical reaction occurs between Th{sup 3+} and carbon dioxide. Loss rates of Th{sup 3+} in helium are consistent with reaction with impurities in the gas. Reaction rates of Th{sup 3+} with nitrogen and argon depend on the internal electronic configuration of the Th{sup 3+}.

Churchill, L. R.; DePalatis, M. V.; Chapman, M. S. [School of Physics, Georgia Institute of Technology, Atlanta, Georgia 30332-0430 (United States)

2011-01-15T23:59:59.000Z

357

Long-term corrosion measurements in condensing heat exchangers. Topical report, September 1989-January 1993  

SciTech Connect (OSTI)

Corrosion of metals used in condensing heat exchangers for gas appliances has been correlated most strongly with the chloride content of the condensate. This study presents results of an experimental examination of the long-term corrosion in metals used in condensing heat exchangers. The objective of this work is to develop a rationale for predicting the performance and expected service life of metals in condensing heat exchangers. Long-term exposure tests were conducted using finned-tube condensing heat exchangers containing tubes of 304L, 3161L, 3171L, Sea-Cure, and 29-4C steel, and aluminum. The natural gas was spiked with R-11 to generate chloride ion levels in the condensate of 3 ppm, 26 ppm, and 225 ppm. The aluminum tubes experienced through-the-wall pitting after 1.5 months at 225 ppm chloride, and after 6 months at 26 ppm chloride. At 3 ppm, most of the tubes exhibited no corrosion. At 225 ppm and 26 ppm, the 300-series stainless steels experienced through-the-wall corrosion within 3 months, but at 3 ppm virtually no corrosion was found. Sea-Cure and 29-4C exhibited the best corrosion resistance with some pitting at 225 ppm but none at 26 ppm and 3 ppm.

Stickford, G.H.; Hindin, B.

1993-01-31T23:59:59.000Z

358

Conceptual design of a fast-ion D-alpha diagnostic on experimental advanced superconducting tokamak  

SciTech Connect (OSTI)

To investigate the fast ion behavior, a fast ion D-alpha (FIDA) diagnostic system has been planned and is presently under development on Experimental Advanced Superconducting Tokamak. The greatest challenges for the design of a FIDA diagnostic are its extremely low intensity levels, which are usually significantly below the continuum radiation level and several orders of magnitude below the bulk-ion thermal charge-exchange feature. Moreover, an overlaying Motional Stark Effect (MSE) feature in exactly the same wavelength range can interfere. The simulation of spectra code is used here to guide the design and evaluate the diagnostic performance. The details for the parameters of design and hardware are presented.

Huang, J., E-mail: juan.huang@ipp.ac.cn; Wan, B.; Hu, L.; Hu, C. [Institute of Plasma Physics, Chinese Academy of Sciences, P.O. 1126, 230031 Hefei, Anhui (China); Heidbrink, W. W.; Zhu, Y. [Department of Physics and Astronomy, University of California, Irvine, California 92697 (United States); Hellermann, M. G. von [FOM Institute DIFFER, P.O. BOX 1207, Nieuwegein 3430 BE (Netherlands); Gao, W.; Wu, C.; Li, Y.; Fu, J.; Lyu, B.; Yu, Y.; Ye, M. [School of Nuclear Science and Technology, University of Science and Technology of China, Hefei, Anhui 230026 (China); Shi, Y. [School of Nuclear Science and Technology, University of Science and Technology of China, Hefei, Anhui 230026 (China); WCI for Fusion Theory, National Fusion Research Institute, 52 Eoeun-Dong, Yusung-Gu, Daejeon 305-333 (Korea, Republic of)

2014-11-15T23:59:59.000Z

359

Relating to ion detection  

DOE Patents [OSTI]

The apparatus and method provide a technique for improving detection of alpha and/or beta emitting sources on items or in locations using indirect means. The emission forms generate ions in a medium surrounding the item or location and the medium is then moved to a detecting location where the ions are discharged to give a measure of the emission levels. To increase the level of ions generated and render the system particularly applicable for narrow pipes and other forms of conduits, the medium pressure is increased above atmospheric pressure. STATEMENT REGARDING FEDERALLY SPONSORED RESEARCH OR DEVELOPMENT

Orr, Christopher Henry (Calderbridge, GB); Luff, Craig Janson (Calderbridge, GB); Dockray, Thomas (Calderbridge, GB); Macarthur, Duncan Whittemore (Los Alamos, NM)

2001-01-01T23:59:59.000Z

360

Initial Assessment of Electron and X-Ray Production and Charge Exchange in the NDCX-II Accelerator  

SciTech Connect (OSTI)

The purpose of this note is to provide initial assessments of some atomic physics effects for the accelerator section of NDCX-II. There are several effects we address: the production of electrons associated with loss of beam ions to the walls, the production of electrons associated with ionization of background gas, the possibly resultant production of X-rays when these electrons hit bounding surfaces, and charge exchange of beam ions on background gas. The results presented here are based on a number of caveats that will be stated below, which we will attempt to remove in the near future.

COHEN, R.H.

2010-02-18T23:59:59.000Z

Note: This page contains sample records for the topic "ion exchange ix" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Imaging ion outflow in the high-latitude magnetosphere using low-energy neutral atoms  

SciTech Connect (OSTI)

The measurement of neutral atom fluxes generated by charge exchange with the Earth's geocorona has recently been shown to provide the capability to image the magnetosphere. The authors investigate neutral oxygen fluxes produced by charge exchange from the cusp/cleft ion fountain population. Using an empirical cusp/cleft ion fountain model, an empirical variation of the geocoronal neutral hydrogen density with distance, and typical values for charge-exchange cross sections, line-of-sight integrations are performed to calculate the neutral oxygen flux at arbitrary locations in space. The resulting images are evaluated for a set of orbital positions of the proposed HI-LITE small explorer spacecraft. The resulting neutral oxygen fluxes are high enough for imaging with a low-energy neutral atom imaging instrument (ILENA) onboard the spacecraft.

Hesse, M.; Smith, M.F.; Herrero, F. (NASA, Greenbelt, MD (United States). Goddard Space Flight Center); Ghielmetti, A.G.; Shelley, E.G. (Lockheed Palo Alto Research Lab., CA (United States)); Wurz, P.; Bochsler, P. (Univ. of Bern (Switzerland)); Gallagher, D.L.; Moore, T.E. (NASA, Huntsville, AL (United States). Marshall Space Flight Center); Stephen, T.S. (Univ. of Denver, CO (United States))

1993-12-01T23:59:59.000Z

362

Dr. Ing. /PhD / Dr.techn. Students supervised by Signe Kjelstrup 1. Torleif Holt, Transport and equilibrium properties of a cation exchange membrane (1983)  

E-Print Network [OSTI]

, (1996) 6. Magnar Ottøy, Mass and heat transfer in ion-exchange membranes (1996) 7. Belinda Flem, Peltier in the Polymer Electrolyte Membrane Fuel Cell (2007) 17. Isabella Inzoli, Coupled transports of heat and massDr. Ing. /PhD / Dr.techn. Students supervised by Signe Kjelstrup 1. Torleif Holt, Transport

Kjelstrup, Signe

363

Ion sensing method  

DOE Patents [OSTI]

The present invention allows the determination of trace levels of ionic substances in a sample solution (ions, metal ions, and other electrically charged molecules) by coupling a separation method, such as liquid chromatography, with ion selective electrodes (ISE) prepared so as to allow detection at activities below 10.sup.-6 M. The separation method distributes constituent molecules into fractions due to unique chemical and physical properties, such as charge, hydrophobicity, specific binding interactions, or movement in an electrical field. The separated fractions are detected by means of the ISE(s). These ISEs can be used singly or in an array. Accordingly, modifications in the ISEs are used to permit detection of low activities, specifically, below 10.sup.-6 M, by using low activities of the primary analyte (the molecular species which is specifically detected) in the inner filling solution of the ISE. Arrays constructed in various ways allow flow-through sensing for multiple ions.

Smith, Richard Harding; Martin, Glenn Brian

2004-05-18T23:59:59.000Z

364

Ion manipulation device  

DOE Patents [OSTI]

An ion manipulation method and device is disclosed. The device includes a pair of substantially parallel surfaces. An array of inner electrodes is contained within, and extends substantially along the length of, each parallel surface. The device includes a first outer array of electrodes and a second outer array of electrodes. Each outer array of electrodes is positioned on either side of the inner electrodes, and is contained within and extends substantially along the length of each parallel surface. A DC voltage is applied to the first and second outer array of electrodes. A RF voltage, with a superimposed electric field, is applied to the inner electrodes by applying the DC voltages to each electrode. Ions either move between the parallel surfaces within an ion confinement area or along paths in the direction of the electric field, or can be trapped in the ion confinement area.

Anderson, Gordon A; Smith, Richard D; Ibrahim, Yehia M; Baker, Erin M

2014-09-16T23:59:59.000Z

365

Pulsed ion beam source  

DOE Patents [OSTI]

An improved pulsed ion beam source having a new biasing circuit for the fast magnetic field. This circuit provides for an initial negative bias for the field created by the fast coils in the ion beam source which pre-ionize the gas in the source, ionize the gas and deliver the gas to the proper position in the accelerating gap between the anode and cathode assemblies in the ion beam source. The initial negative bias improves the interaction between the location of the nulls in the composite magnetic field in the ion beam source and the position of the gas for pre-ionization and ionization into the plasma as well as final positioning of the plasma in the accelerating gap. Improvements to the construction of the flux excluders in the anode assembly are also accomplished by fabricating them as layered structures with a high melting point, low conductivity material on the outsides with a high conductivity material in the center.

Greenly, John B. (Lansing, NY)

1997-01-01T23:59:59.000Z

366

Secondary ion collection and transport system for ion microprobe  

DOE Patents [OSTI]

A secondary ion collection and transport system, for use with an ion microprobe, which is very compact and occupies only a small working distance, thereby enabling the primary ion beam to have a short focal length and high resolution. Ions sputtered from the target surface by the primary beam's impact are collected between two arcuate members having radii of curvature and applied voltages that cause only ions within a specified energy band to be collected. The collected ions are accelerated and focused in a transport section consisting of a plurality of spaced conductive members which are coaxial with and distributed along the desired ion path. Relatively high voltages are applied to alternate transport sections to produce accelerating electric fields sufficient to transport the ions through the section to an ion mass analyzer, while lower voltages are applied to the other transport sections to focus the ions and bring their velocity to a level compatible with the analyzing apparatus.

Ward, James W. (Canoga Park, CA); Schlanger, Herbert (Simi Valley, CA); McNulty, Jr., Hugh (Santa Monica, CA); Parker, Norman W. (Camarillo, CA)

1985-01-01T23:59:59.000Z

367

Heat exchanger for coal gasification process  

DOE Patents [OSTI]

This invention provides a heat exchanger, particularly useful for systems requiring cooling of hot particulate solids, such as the separated fines from the product gas of a carbonaceous material gasification system. The invention allows effective cooling of a hot particulate in a particle stream (made up of hot particulate and a gas), using gravity as the motive source of the hot particulate. In a preferred form, the invention substitutes a tube structure for the single wall tube of a heat exchanger. The tube structure comprises a tube with a core disposed within, forming a cavity between the tube and the core, and vanes in the cavity which form a flow path through which the hot particulate falls. The outside of the tube is in contact with the cooling fluid of the heat exchanger.

Blasiole, George A. (Greensburg, PA)

1984-06-19T23:59:59.000Z

368

Modeling particle deposition on HVAC heat exchangers  

SciTech Connect (OSTI)

Fouling of fin-and-tube heat exchangers by particle deposition leads to diminished effectiveness in supplying ventilation and air conditioning. This paper explores mechanisms that cause particle deposition on heat exchanger surfaces. We present a model that accounts for impaction, diffusion, gravitational settling, and turbulence. Simulation results suggest that some submicron particles deposit in the heat exchanger core, but do not cause significant performance impacts. Particles between 1 and 10 {micro}m deposit with probabilities ranging from 1-20% with fin edge impaction representing the dominant mechanism. Particles larger than 10 {micro}m deposit by impaction on refrigerant tubes, gravitational settling on fin corrugations, and mechanisms associated with turbulent airflow. The model results agree reasonably well with experimental data, but the deposition of larger particles at high velocities is underpredicted. Geometric factors, such as discontinuities in the fins, are hypothesized to be responsible for the discrepancy.

Siegel, J.A.; Nazaroff, W.W.

2002-01-01T23:59:59.000Z

369

Ion electric propulsion unit  

DOE Patents [OSTI]

An electron cyclotron resonance (ECR) thruster is disclosed having a plasma chamber which is electrically biased with a positive voltage. The chamber bias serves to efficiently accelerate and expel the positive ions from the chamber. Electrons follow the exiting ions, serving to provide an electrically neutral exhaust plume. In a further embodiment, a downstream shaping magnetic field serves to further accelerate and/or shape the exhaust plume.

Light, Max E; Colestock, Patrick L

2014-01-28T23:59:59.000Z

370

Ion-beam-driven electrostatic ion cyclotron instabilities  

SciTech Connect (OSTI)

We present results of numerical simulations on the electrostatic ion cyclotron instabilities driven by the ion beam parallel to the magnetic field. For the beam speed exceeding the thermal speed of background ions and the beam temperature much lower than the background ion temperature, it is found that the instability results in strong perpendicular heating and slowing down of parallel drift of the beam ions, leading to the saturation of the instability. Applications to plasma heating and space plasma physics are discussed.

Miura, A.; Okuda, H.; Ashour-Abdalla, M.

1982-10-01T23:59:59.000Z

371

Gas exchange measurements in natural systems  

SciTech Connect (OSTI)

Direct knowledge of the rates of gas exchange in lakes and the ocean is based almost entirely on measurements of the isotopes /sup 14/C, /sup 222/Rn and /sup 3/He. The distribution of natural radiocarbon has yielded the average rate of CO/sub 2/ exchange for the ocean and for several closed basin lakes. That of bomb produced radiocarbon has been used in the same systems. The /sup 222/Rn to /sup 226/Ra ratio in open ocean surface water has been used to give local short term gas exchange rates. The radon method generally cannot be used in lakes, rivers, estuaries or shelf areas because of the input of radon from sediments. A few attempts have been made to use the excess /sup 3/He produced by decay of bomb produced tritium in lakes to give gas transfer rates. The uncertainty in the molecular diffusivity of helium and in the diffusivity dependence of the rate of gas transfer holds back the application of this method. A few attempts have been made to enrich the surface waters of small lakes with /sup 226/Ra and /sup 3/H in order to allow the use of the /sup 222/Rn and /sup 3/He methods. While these studies give broadly concordant results, many questions remain unanswered. The wind velocity dependence of gas exchange rate has yet to be established in field studies. The dependence of gas exchange rate on molecular diffusivity also remains in limbo. Finally, the degree of enhancement of CO/sub 2/ exchange through chemical reactions has been only partially explored. 49 references, 2 figures, 2 tables.

Broecker, W.S.; Peng, T.H.

1983-01-01T23:59:59.000Z

372

Heat Exchanger With Internal Pin Elements  

DOE Patents [OSTI]

A heat exchanger/heater comprising a tubular member having a fluid inlet end, a fluid outlet end and plurality of pins secured to the interior wall of the tube. Various embodiments additionally comprise a blocking member disposed concentrically inside the pins, such as a core plug or a baffle array. Also disclosed is a vapor generator employing an internally pinned tube, and a fluid-heater/heat-exchanger utilizing an outer jacket tube and fluid-side baffle elements, as well as methods for heating a fluid using an internally pinned tube.

Gerstmann, Joseph (Framingham, MA); Hannon, Charles L. (Arlington, MA)

2004-01-13T23:59:59.000Z

373

Confronting Dilaton-exchange gravity with experiments  

E-Print Network [OSTI]

We study the experimental constraints on theories, where the equivalence principle is violated by dilaton-exchange contributions to the usual graviton-exchange gravity. We point out that in this case it is not possible to have any CPT violation and hence there is no constraint from the CPT violating measurements in the $K-$system. The most stringent bound is obtained from the $K_L - K_S$ mass difference. In contrast, neither neutrino oscillation experiments nor neutrinoless double beta decay imply significant constraints.

H. V. Klapdor-Kleingrothaus; H. Päs; U. Sarkar

2000-08-16T23:59:59.000Z

374

Correlating Humidity-Dependent Ionically Conductive Surface Area with Transport Phenomena in Proton-Exchange Membranes  

SciTech Connect (OSTI)

The objective of this effort was to correlate the local surface ionic conductance of a Nafion? 212 proton-exchange membrane with its bulk and interfacial transport properties as a function of water content. Both macroscopic and microscopic proton conductivities were investigated at different relative humidity levels, using electrochemical impedance spectroscopy and current-sensing atomic force microscopy (CSAFM). We were able to identify small ion-conducting domains that grew with humidity at the surface of the membrane. Numerical analysis of the surface ionic conductance images recorded at various relative humidity levels helped determine the fractional area of ion-conducting active sites. A simple square-root relationship between the fractional conducting area and observed interfacial mass-transport resistance was established. Furthermore, the relationship between the bulk ionic conductivity and surface ionic conductance pattern of the Nafion? membrane was examined.

He, Qinggang; Kusoglu, Ahmet; Lucas, Ivan T.; Clark, Kyle; Weber, Adam Z.; Kostecki, Robert

2011-08-01T23:59:59.000Z

375

Bifunctional anion-exchange resins with improved selectivity and exchange kinetics  

DOE Patents [OSTI]

Disclosed herein are a class of anion exchange resins containing two different exchange sites with improved selectivity and sorptive capability for chemical species in solution, such as heptavalent technetium (as pertechnetate anion, TcO.sub.4.sup.-). The resins are prepared by first reacting haloalkylated crosslinked copolymer beads with a large tertiary amine in a solvent in which the resin beads can swell, followed by reaction with a second, smaller, tertiary amine to more fully complete the functionalization of the resin. The resins have enhanced selectivity, capacity, and exchange kinetics.

Alexandratos, Spiro D. (Knoxville, TN); Brown, Gilbert M. (Knoxville, TN); Bonnesen, Peter V. (Knoxville, TN); Moyer, Bruce A. (Oak Ridge, TN)

2000-01-01T23:59:59.000Z

376

Ion temperature gradient driven turbulence with strong trapped ion resonance  

SciTech Connect (OSTI)

A theory to describe basic characterization of ion temperature gradient driven turbulence with strong trapped ion resonance is presented. The role of trapped ion granulations, clusters of trapped ions correlated by precession resonance, is the focus. Microscopically, the presence of trapped ion granulations leads to a sharp (logarithmic) divergence of two point phase space density correlation at small scales. Macroscopically, trapped ion granulations excite potential fluctuations that do not satisfy dispersion relation and so broaden frequency spectrum. The line width from emission due only to trapped ion granulations is calculated. The result shows that the line width depends on ion free energy and electron dissipation, which implies that non-adiabatic electrons are essential to recover non-trivial dynamics of trapped ion granulations. Relevant testable predictions are summarized.

Kosuga, Y., E-mail: kosuga@riam.kyushu-u.ac.jp [Institute for Advanced Study, Kyushu University, Fukuoka (Japan); Research Institute for Applied Mechanics, Kyushu University, Fukuoka (Japan); Itoh, S.-I. [Research Center for Plasma Turbulence, Kyushu University, Fukuoka (Japan); Research Institute for Applied Mechanics, Kyushu University, Fukuoka (Japan); Diamond, P. H. [CASS and CMTFO, University of California at San Diego, La Jolla, California 92093 (United States); WCI Center for Fusion Theory, National Fusion Research Institute, Daejeon (Korea, Republic of); Itoh, K. [National Institute for Fusion Science, Gifu (Japan); Research Center for Plasma Turbulence, Kyushu University, Fukuoka (Japan); Lesur, M. [Research Institute for Applied Mechanics, Kyushu University, Fukuoka (Japan)

2014-10-15T23:59:59.000Z

377

Electronuclear ion fusion in an ion cyclotron resonance reactor  

SciTech Connect (OSTI)

A method and apparatus for generating nuclear fusion by ion cyclotron resonance in an ion trap reactor. The reactor includes a cylindrical housing having an axial axis, an internal surface, and first and second ends. First and second end plates that are charged are respectively located at the first and second ends of the cylindrical housing. A gas layer is adsorbed on the internal surface of the cylindrical housing. Ions are desorbed from the gas layer, forming a plasma layer adjacent to the cylindrical housing that includes first ions that have a same charge sign as the first and second end plates. A uniform magnetic field is oriented along the axial axis of the cylindrical housing. Second ions, that are unlike the first ions, but have the same charge sign, are injected into the cylindrical housing along the axial axis of the cylindrical housing. A radio frequency field resonantly accelerates the injected second ions at the cyclotron resonance frequency of the second ions. The second ions circulate in increasing helical orbits and react with the first ions, at the optimum energy for nuclear fusion. The amplitude of the radio frequency field is adjusted to accelerate the second ions at a rate equal to the rate of tangential energy loss of the second ions by nuclear scattering in the first ions, causing the ions to continually interact until fusion occurs.

Cowgill, Donald F.

1996-12-01T23:59:59.000Z

378

COMMODITY PRICE VOLATILITY ACROSS EXCHANGE RATE REGIMES  

E-Print Network [OSTI]

1 COMMODITY PRICE VOLATILITY ACROSS EXCHANGE RATE REGIMES John T. Cuddington* and Hong Liang** March 10, 2003 ABSTRACT This paper documents a new "stylized fact" regarding the relative price 1880 to 1996, this key relative price among two categories of tradable goods is shown to exhibit

379

8 Ecosystem Exchange 8.3 Introduction  

E-Print Network [OSTI]

of momentum, sensible heat, H, latent heat, E, and carbon dioxide, Fc, and the energy budget. 8.4 Storage and carbon dioxide are described. Patterns of these exchanges are explained in relation to appropriate variables and controlling factors. The storage of mass and energy is presented first, followed by the fluxes

380

DYNAMIC MODELING PROTON EXCHANGE MEMBRANE FUEL CELL  

E-Print Network [OSTI]

DYNAMIC MODELING PROTON EXCHANGE MEMBRANE FUEL CELL OVERVIEW Current/Completed Plug Power reformer from GE · Use of GenCore to investigate effects of fuel quality and dynamic changes in fuel to garner SCAQMD funding for fuel cell testing GenCore system is sensitive to diluents · As built design

Mease, Kenneth D.

Note: This page contains sample records for the topic "ion exchange ix" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

MODELING PARTICLE DEPOSITION ON HVAC HEAT EXCHANGERS  

E-Print Network [OSTI]

LBNL-49339 MODELING PARTICLE DEPOSITION ON HVAC HEAT EXCHANGERS J.A. Siegel1,3 * and W.W. Nazaroff2 Department of Energy under contract DE-AC03-76SF00098. #12;MODELING PARTICLE DEPOSITION ON HVAC HEAT, such as discontinuities in the fins, are hypothesized to be responsible for the discrepancy. INDEX TERMS HVAC, Fouling

382

Heat exchanger with transpired, highly porous fins  

DOE Patents [OSTI]

The heat exchanger includes a fin and tube assembly with increased heat transfer surface area positioned within a hollow chamber of a housing to provide effective heat transfer between a gas flowing within the hollow chamber and a fluid flowing in the fin and tube assembly. A fan is included to force a gas, such as air, to flow through the hollow chamber and through the fin and tube assembly. The fin and tube assembly comprises fluid conduits to direct the fluid through the heat exchanger, to prevent mixing with the gas, and to provide a heat transfer surface or pathway between the fluid and the gas. A heat transfer element is provided in the fin and tube assembly to provide extended heat transfer surfaces for the fluid conduits. The heat transfer element is corrugated to form fins between alternating ridges and grooves that define flow channels for directing the gas flow. The fins are fabricated from a thin, heat conductive material containing numerous orifices or pores for transpiring the gas out of the flow channel. The grooves are closed or only partially open so that all or substantially all of the gas is transpired through the fins so that heat is exchanged on the front and back surfaces of the fins and also within the interior of the orifices, thereby significantly increasing the available the heat transfer surface of the heat exchanger. The transpired fins also increase heat transfer effectiveness of the heat exchanger by increasing the heat transfer coefficient by disrupting boundary layer development on the fins and by establishing other beneficial gas flow patterns, all at desirable pressure drops.

Kutscher, Charles F. (Golden, CO); Gawlik, Keith (Boulder, CO)

2002-01-01T23:59:59.000Z

383

Oxygen ion conducting materials  

DOE Patents [OSTI]

An oxygen ion conducting ceramic oxide that has applications in industry including fuel cells, oxygen pumps, oxygen sensors, and separation membranes. The material is based on the idea that substituting a dopant into the host perovskite lattice of (La,Sr)MnO.sub.3 that prefers a coordination number lower than 6 will induce oxygen ion vacancies to form in the lattice. Because the oxygen ion conductivity of (La,Sr)MnO.sub.3 is low over a very large temperature range, the material exhibits a high overpotential when used. The inclusion of oxygen vacancies into the lattice by doping the material has been found to maintain the desirable properties of (La,Sr)MnO.sub.3, while significantly decreasing the experimentally observed overpotential.

Vaughey, John; Krumpelt, Michael; Wang, Xiaoping; Carter, J. David

2005-07-12T23:59:59.000Z

384

Oxygen ion conducting materials  

DOE Patents [OSTI]

An oxygen ion conducting ceramic oxide that has applications in industry including fuel cells, oxygen pumps, oxygen sensors, and separation membranes. The material is based on the idea that substituting a dopant into the host perovskite lattice of (La,Sr)MnO.sub.3 that prefers a coordination number lower than 6 will induce oxygen ion vacancies to form in the lattice. Because the oxygen ion conductivity of (La,Sr)MnO.sub.3 is low over a very large temperature range, the material exhibits a high overpotential when used. The inclusion of oxygen vacancies into the lattice by doping the material has been found to maintain the desirable properties of (La,Sr)MnO.sub.3, while significantly decreasing the experimentally observed overpotential.

Carter, J. David; Wang, Xiaoping; Vaughey, John; Krumpelt, Michael

2004-11-23T23:59:59.000Z

385

Oxygen ion conducting materials  

DOE Patents [OSTI]

An oxygen ion conducting ceramic oxide that has applications in industry including fuel cells, oxygen pumps, oxygen sensors, and separation membranes. The material is based on the idea that substituting a dopant into the host perovskite lattice of (La,Sr)MnO.sub.3 that prefers a coordination number lower than 6 will induce oxygen ion vacancies to form in the lattice. Because the oxygen ion conductivity of (La,Sr)MnO.sub.3 is low over a very large temperature range, the material exhibits a high overpotential when used. The inclusion of oxygen vacancies into the lattice by doping the material has been found to maintain the desirable properties of (La,Sr)MnO.sub.3, while significantly decreasing the experimentally observed overpotential.

Vaughey, John (Elmhurst, IL); Krumpelt, Michael (Naperville, IL); Wang, Xiaoping (Downers Grove, IL); Carter, J. David (Bolingbrook, IL)

2003-01-01T23:59:59.000Z

386

Asymmetric ion trap  

DOE Patents [OSTI]

An ion trap having two end cap electrodes disposed asymmetrically about a center of a ring electrode is disclosed. The inner surface of the end cap electrodes are conformed to an asymmetric pair of equipotential lines of the harmonic formed by the application of voltages to the electrodes. The asymmetry of the end cap electrodes allows ejection of charged species through the closer of the two electrodes which in turn allows for simultaneously detecting anions and cations expelled from the ion trap through the use of two detectors charged with opposite polarity. 4 figs.

Barlow, S.E.; Alexander, M.L.; Follansbee, J.C.

1997-12-02T23:59:59.000Z

387

Asymmetric ion trap  

DOE Patents [OSTI]

An ion trap having two end cap electrodes disposed asymmetrically about a center of a ring electrode. The inner surface of the end cap electrodes are conformed to an asymmetric pair of equipotential lines of the harmonic formed by the application of voltages to the electrodes. The asymmetry of the end cap electrodes allows ejection of charged species through the closer of the two electrodes which in turn allows for simultaneously detecting anions and cations expelled from the ion trap through the use of two detectors charged with opposite polarity.

Barlow, Stephan E. (Richland, WA); Alexander, Michael L. (Richland, WA); Follansbee, James C. (Pasco, WA)

1997-01-01T23:59:59.000Z

388

Essays on Real Exchange Rates and Theoretical Monetary Aggregation  

E-Print Network [OSTI]

This dissertation is a collection of three essays focused on real exchange rates and theoretical monetary aggregation. The first essay focused on the convergence of real exchange rates' idiosyncratic effects after isolating ...

Zheng, Mingming

2014-05-31T23:59:59.000Z

389

Energy Efficiency Exchange 2015 Schedule | Department of Energy  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Schedule Energy Efficiency Exchange 2015 Schedule The schedule for Energy Efficiency Exchange 2015 is available below. Monday, August 10, 2015 12 p.m.-5:30 p.m. Registration...

390

Fouling of HVAC fin and tube heat exchangers  

E-Print Network [OSTI]

air ? air ? part ? part FPI HVAC REFERENCES Anonymous, 1987,LBNL-47668 Fouling of HVAC Fin and Tube Heat ExchangersCIEE SPONSOR. FOULING OF HVAC FIN AND TUBE HEAT EXCHANGERS

Siegel, Jeffrey; Carey, Van P.

2001-01-01T23:59:59.000Z

391

Kitchen Appliance Upgrades Improve Water Efficiency at DOD Exchange Facilities  

Broader source: Energy.gov [DOE]

Case study details the Exchange (formerly the Army and Air Force Exchange Service), which took a leadership role in kitchen appliance upgrades to improve water efficiency by integrating water efficiency concepts into the organization's overall sustainability plan and objectives.

392

Using Plate Heat Exchangers to Increase Energy Efficiency  

E-Print Network [OSTI]

"In recent years, there has been an increasing awareness of Plate Heat Exchangers (PHE's) in industrial processes around the world. While PHE's have historically been classified as compact heat exchangers, compactness is often a secondary advantage...

Bailey, K.

393

affect gas exchange: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

were Ho, David 15 AIR-WATER GAS EXCHANGE: MECHANISMS GOVERNING THE COMBINED EFFECTS OF WIND AND RAIN ON THE GAS TRANSFER Geosciences Websites Summary: AIR-WATER GAS EXCHANGE:...

394

affects gas exchange: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

were Ho, David 15 AIR-WATER GAS EXCHANGE: MECHANISMS GOVERNING THE COMBINED EFFECTS OF WIND AND RAIN ON THE GAS TRANSFER Geosciences Websites Summary: AIR-WATER GAS EXCHANGE:...

395

Networking Call for Residential Network Members Peer Exchange...  

Office of Environmental Management (EM)

Networking Call for Residential Network Members Peer Exchange Call Networking Call for Residential Network Members Peer Exchange Call March 12, 2015 12:30PM to 2:00PM EDT...

396

Using Mobile Applications to Generate Customer Demand Peer Exchange...  

Energy Savers [EERE]

Using Mobile Applications to Generate Customer Demand Peer Exchange Call Using Mobile Applications to Generate Customer Demand Peer Exchange Call March 12, 2015 3:00PM to 4:3...

397

Advances in lithium-ion batteries  

E-Print Network [OSTI]

Advances in Lithium-Ion Batteries Edited by Walter A. vanpuzzling mysteries of lithium ion batteries. The book beginssuch importance to lithium ion batteries one is amazed that

Kerr, John B.

2003-01-01T23:59:59.000Z

398

Heat exchanger containing a component capable of discontinuous movement  

DOE Patents [OSTI]

Regenerative heat exchangers are described for transferring heat between hot and cold fluids. The heat exchangers have seal-leakage rates significantly less than those of conventional regenerative heat exchangers because the matrix is discontinuously moved and is releasably sealed while in a stationary position. Both rotary and modular heat exchangers are described. Also described are methods for transferring heat between a hot and cold fluid using the discontinuous movement of matrices.

Wilson, David Gordon (Winchester, MA)

2002-01-01T23:59:59.000Z

399

Safe Exchange Planner Tuomas Sandholm and Vincent Ferrandon  

E-Print Network [OSTI]

, the technique may also facilitate illegal trades of drugs, arms, porn, etc., where enforcement of the exchange

Gordon, Geoffrey J.

400

Heat exchanger containing a component capable of discontinuous movement  

DOE Patents [OSTI]

Regenerative heat exchangers are described for transferring heat between hot and cold fluids. The heat exchangers have seal-leakage rates significantly less than those of conventional regenerative heat exchangers because the matrix is discontinuously moved and is releasably sealed while in a stationary position. Both rotary and modular heat exchangers are described. Also described are methods for transferring heat between a hot and cold fluid using the discontinuous movement of matrices.

Wilson, David Gordon

2001-04-17T23:59:59.000Z

Note: This page contains sample records for the topic "ion exchange ix" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Design and Development of a Plastic Film Heat Exchanger  

E-Print Network [OSTI]

of the PFHX technology in olving heat. exchange at any pressure other than'atmo pheric pressure. Atmospheric applications could ope ate with a simple remote level control basin. There are also many other potential appl ca tions of the PFHX technology...DESIGN AND DEVELOPMENT OF A PLASTIC FILM HEAT EXCHANGER Eric C. Guyer, Sc.D., David L. Brownell, and Martin K. Gollin Dynatech RID Company Cambridge, Massachusetts ABSTRACT A plastic film heat exchang.er (PFHX) utilizes the low cost...

Guyer, E. C.; Gollin, M. K.; Brownell, D. L.

402

Heat exchanger containing a component capable of discontinuous movement  

DOE Patents [OSTI]

Regenerative heat exchangers are described for transferring heat between hot and cold fluids. The heat exchangers have seal-leakage rates significantly less than those of conventional regenerative heat exchangers because the matrix is discontinuously moved and is releasably sealed while in a stationary position. Both rotary and modular heat exchangers are described. Also described are methods for transferring heat between a hot and cold fluid using the discontinuous movement of matrices. 11 figures.

Wilson, D.G.

1993-11-09T23:59:59.000Z

403

Quality Assurance Exchange Setpebmer 2007, Volume 3 Issue 3  

Broader source: Energy.gov [DOE]

Quality Assurance Exchange Setpebmer 2007, Volume 3 Issue 3 U.S. Department of Energy Office of Corporate Safety Analysis

404

Quality Assurance Exchange August 2007, Volume 3 Issue 2  

Broader source: Energy.gov [DOE]

Quality Assurance Exchange August 2007, Volume 3 Issue 2 U.S. Department of Energy Office of Corporate Safety Analysis

405

Quality Assurance Exchange January 2007, Volume 3 Issue 1  

Broader source: Energy.gov [DOE]

Quality Assurance Exchange January 2007, Volume 3 Issue 1 U.S. Department of Energy Office of Corporate Safety Analysis

406

QUALITY ASSURANCE EXCHANGE July 2005 Volume 1 Issue 1  

Broader source: Energy.gov [DOE]

QUALITY ASSURANCE EXCHANGE July 2005 Volume 1 Issue 1 US Department of Energy, Office of Quality Assurance Programs (EH-31)

407

Metal cation/anion adsorption on calcium carbonate: Implications to metal ion concentrations in groundwater  

SciTech Connect (OSTI)

This chapter evaluates the sorption behavior of metallic ions on specimen calcite as a basis for determining the importance of calcite relative to other subsurface sorbents, such as layer silicates and oxides, in controlling metal ion concentration in calcareous groundwaters. A review of the literature shows the sorption of both metallic cations and anions on calcite over ranges in pH and CO{sub 2} partial pressure to be consistent with a surface-exchange process where cations exchange with surface Ca and anions exchange with surface CO{sub 3}. A general surface-exchange model was developed to account for the effects of Ca and CO{sub 3} concentrations, pH, and calcite surface area on cation and anion sorption onto calcite. The model was applied to recently developed experimental sorption data of Zn and SeO{sub 3} on specimen calcite in equilibrium CaCO{sub 3}(aq) suspensions. The surface-exchange model was able to describe the effects of pH on both cation and anion sorption, and provided good predictions of the effects of variable CO{sub 2}(g) pressure on Zn sorption and of PO{sub 4} on SeO{sub 3} sorption. The surface-exchange model, combined with sorption constants for other phases, was used to calculate Cd sorption to a hypothetical aquifer material containing a mixture of sorbents. The sorbent concentrations were fixed to those expected in groundwater zones. The multi-sorbent calculation documented the importance of calcite as a sorbent for metallic ions in groundwater.93 refs., 18 figs., 5 tabs.

Zachara, J.M.; Cowan, C.E.; Resch, C.T.

1990-05-01T23:59:59.000Z

408

Investigation of Transient Phenomena of Proton Exchange Membrane Fuel Cells  

E-Print Network [OSTI]

Investigation of Transient Phenomena of Proton Exchange Membrane Fuel Cells by Roongrojana of Proton Exchange Membrane Fuel Cells by Roongrojana Songprakorp BSc, Prince of Songkhla University to the modeling and under- standing of the dynamic behavior of proton exchange membrane fuel cells (PEMFCs

Victoria, University of

409

FOCUS: HYDROGEN EXCHANGE AND COVALENT MODIFICATION ACCOUNT AND PERSPECTIVE  

E-Print Network [OSTI]

hydrogen exchange behavior, understand the underlying chemistry and structural physics of hydrogen exchange-protected by their H-bonding interactions, they engage in continual ex- change with the hydrogens of solvent water of the underlying chemistry and structural phys- ics of protein HX processes. The study of protein hydrogen exchange

Englander, S. Walter

410

Heat exchanger support apparatus in a fluidized bed  

DOE Patents [OSTI]

A heat exchanger is mounted in the upper portion of a fluidized combusting bed for the control of the temperature of the bed. A support, made up of tubes, is extended from the perforated plate of the fluidized bed up to the heat exchanger. The tubular support framework for the heat exchanger has liquid circulated therethrough to prevent deterioration of the support.

Lawton, Carl W. (West Hartford, CT)

1982-01-01T23:59:59.000Z

411

IntroductiontoProcessEngineering(PTG) 4. Heat exchangers;  

E-Print Network [OSTI]

ProcessEngineering(PTG) VST rz13 8/72 Heat exchangers: energy balance Picture: SEHB06 Heat exchanger schematic with open/72 Overall heat transfer coefficient · The heat transfer process* may be described by a simple model expression Q = U·A·T for temperature diffence T (°C), heat exchange area A (m2) and overall heat transfer

Zevenhoven, Ron

412

Pulsed ion beam source  

DOE Patents [OSTI]

An improved pulsed ion beam source is disclosed having a new biasing circuit for the fast magnetic field. This circuit provides for an initial negative bias for the field created by the fast coils in the ion beam source which pre-ionize the gas in the source, ionize the gas and deliver the gas to the proper position in the accelerating gap between the anode and cathode assemblies in the ion beam source. The initial negative bias improves the interaction between the location of the nulls in the composite magnetic field in the ion beam source and the position of the gas for pre-ionization and ionization into the plasma as well as final positioning of the plasma in the accelerating gap. Improvements to the construction of the flux excluders in the anode assembly are also accomplished by fabricating them as layered structures with a high melting point, low conductivity material on the outsides with a high conductivity material in the center. 12 figs.

Greenly, J.B.

1997-08-12T23:59:59.000Z

413

Lithium ion conducting electrolytes  

DOE Patents [OSTI]

The present invention relates generally to highly conductive alkali-metal ion non-crystalline electrolyte systems, and more particularly to novel and unique molten (liquid), rubbery, and solid electrolyte systems which are especially well suited for use with high current density electrolytic cells such as primary and secondary batteries.

Angell, Charles Austen (Mesa, AZ); Liu, Changle (Midland, MI); Xu, Kang (Montgomery Village, MD); Skotheim, Terje A. (Tucson, AZ)

1999-01-01T23:59:59.000Z

414

High spatial and temporal resolution charge exchange recombination spectroscopy on the HL-2A tokamak  

SciTech Connect (OSTI)

A 32/64-channel charge exchange recombination spectroscopy (CXRS) diagnostic system is developed on the HL-2A tokamak (R = 1.65 m, a = 0.4 m), monitoring plasma ion temperature and toroidal rotation velocity simultaneously. A high throughput spectrometer (F/2.8) and a pitch-controlled fiber bundle enable the temporal resolution of the system up to 400 Hz. The observation geometry and an optimized optic system enable the highest radial resolution up to ?1 cm at the plasma edge. The CXRS system monitors the carbon line emission (C VI, n = 8–7, 529.06 nm) whose Doppler broadening and Doppler shift provide ion temperature and plasma rotation velocity during the neutral beam injection. The composite CX spectral data are analyzed by the atomic data and analysis structure charge exchange spectroscopy fitting (ADAS CXSFIT) code. First experimental results are shown for the case of HL-2A plasmas with sawtooth oscillations, electron cyclotron resonance heating, and edge transport barrier during the high-confinement mode (H-mode)

Wei, Y. L.; Yu, D. L., E-mail: yudl@swip.ac.cn; Liu, L.; Cao, J. Y.; Sun, A. P.; Ma, Q.; Chen, W. J.; Liu, Yi; Yan, L. W.; Yang, Q. W.; Duan, X. R.; Liu, Yong [Southwestern Institute of Physics, Chengdu 610041 (China); Ida, K. [National Institute for Fusion Science, Toki 509-5292 (Japan); Hellermann, M. von [ITER Diagnostic Team, IO, Route de Vinon sur Verdon, 13115 St Paul lez Durance (France); FOM-Institute for Plasma physics “Rijnhuizen,” Association EURATOM, Trilateral Euregio Cluster, 3430 BE Nieuwegein (Netherlands)

2014-10-15T23:59:59.000Z

415

The effect of various cropping systems upon organic matter, total nitrogen, cation exchange capacity, exchangeable cations, conductivity and reaction  

E-Print Network [OSTI]

&IBRARY A 4 N COLLEGE OF TEXAS THE EFFECT OF VARIOUS CROPPING SYSTEMS UPON ORGANIC MATTER, TOTAL NITROGEN, CATION EXCHANGE CAPACITY, EXCHANGEABLE CATIONS, CONDUCTIVITY AND REACTION. A Thesis By MOHAMMAD ABDUL MANNAN Submitted...

Mannan, Mohammad Abdul

1958-01-01T23:59:59.000Z

416

Multidimensional numerical modeling of heat exchangers. [LMFBR  

SciTech Connect (OSTI)

A comprehensive, multidimensional, thermal-hydraulic model is developed for the analysis of shell-and-tube heat exchangers for liquid-metal services. For the shellside fluid, the conservation equations of mass, momentum, and energy for continuum fluids are modified using the concept of porosity, surface permeability and distributed resistance to account for the blockage effects due to the presence of heat-transfer tubes, flow baffles/shrouds, the support plates, etc. On the tubeside, the heat-transfer tubes are connected in parallel between the inlet and outlet plenums, and tubeside flow distribution is calculated based on the plenum-to-plenum pressure difference being equal for all tubes. It is assumed that the fluid remains single-phase on the shell side and may undergo phase-change on the tube side, thereby simulating the conditions of Liquid Metal Fast Breeder Reactor (LMFBR) intermediate heat exchangers (IHX) and steam generators (SG).

Sha, W.T.; Yang, C.I.; Kao, T.T.; Cho, S.M.

1982-01-01T23:59:59.000Z

417

Carbon nanotube heat-exchange systems  

DOE Patents [OSTI]

A carbon nanotube heat-exchange system (10) and method for producing the same. One embodiment of the carbon nanotube heat-exchange system (10) comprises a microchannel structure (24) having an inlet end (30) and an outlet end (32), the inlet end (30) providing a cooling fluid into the microchannel structure (24) and the outlet end (32) discharging the cooling fluid from the microchannel structure (24). At least one flow path (28) is defined in the microchannel structure (24), fluidically connecting the inlet end (30) to the outlet end (32) of the microchannel structure (24). A carbon nanotube structure (26) is provided in thermal contact with the microchannel structure (24), the carbon nanotube structure (26) receiving heat from the cooling fluid in the microchannel structure (24) and dissipating the heat into an external medium (19).

Hendricks, Terry Joseph (Arvada, CO); Heben, Michael J. (Denver, CO)

2008-11-11T23:59:59.000Z

418

Dealing with Uncertainties During Heat Exchanger Design  

E-Print Network [OSTI]

Technology Conference, Houston, TX, May 1-4, 2001 E2 Area = 100 m 2 cp= 35 kW/K El Area = 300 m 2 Figure 1. Simple Heat Exchanger Network CP = 30 kW/K CP= 55 kWIK Assume that exchangers EI (of heat transfer area 100 m 2 ) and E2 (of 300 m 2... .) are perfectly sized. Consequently, the cold stream leaving E I has a temperature of 277?C and that leaving E2 a temperature of 212?C. If a ten percent design margin had been added to each of these units (i.e. El now has 110 m 2 and E2 has 330 m 2...

Polley, G. T.; Pugh, S. J.

419

Non-aqueous liquid compositions comprising ion exchange polymers reference to related application  

DOE Patents [OSTI]

Compositions, and methods of making thereof, comprising from about 1% to about 5% of a perfluorinated sulfonic acid ionomer or a hydrocarbon-based ionomer; and from about 95% to about 99% of a solvent, said solvent consisting essentially of a polyol; wherein said composition is substantially free of water and wherein said ionomer is uniformly dispersed in said solvent.

Kim; Yu Seung (Los Alamos, NM), Lee; Kwan-Soo (Los Alamos, NM), Rockward; Tommy Q. T. (Rio Rancho, NM)

2012-08-07T23:59:59.000Z

420

Sorption of micropollutant estrone to a water treatment ion exchange resin   

E-Print Network [OSTI]

Micropollutants occur in natural waters from a range of sources. Estrogenic compounds are naturally excreted by humans and hence stem predominantly from wastewater effluents. Due to the small size and concentration of ...

Neale, Peta A.; Mastrup, Maibritt; Borgmann, Thomas; Schäfer, Andrea

2010-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "ion exchange ix" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Design, optimization, and selectivity of inorganic ion-exchangers for radioactive waste remediation  

E-Print Network [OSTI]

The processes of development of nuclear weapons resulted in accumulation of thousands of curies of high-level radioactive waste. Liquid waste produced in the US has been stored in carbon steel tanks in highly alkaline (1-3 M NaOH, 6 M sodium salts...

Medvedev, Dmitry Gennadievich

2005-11-01T23:59:59.000Z

422

Extensive separations (CLEAN) processing strategy compared to TRUEX strategy and sludge wash ion exchange  

SciTech Connect (OSTI)

Numerous pretreatment flowsheets have been proposed for processing the radioactive wastes in Hanford`s 177 underground storage tanks. The CLEAN Option is examined along with two other flowsheet alternatives to quantify the trade-off of greater capital equipment and operating costs for aggressive separations with the reduced waste disposal costs and decreased environmental/health risks. The effect on the volume of HLW glass product and radiotoxicity of the LLW glass or grout product is predicted with current assumptions about waste characteristics and separations processes using a mass balance model. The prediction is made on three principal processing options: washing of tank wastes with removal of cesium and technetium from the supernatant, with washed solids routed directly to the glass (referred to as the Sludge Wash C processing strategy); the previous steps plus dissolution of the solids and removal of transuranic (TRU) elements, uranium, and strontium using solvent extraction processes (referred to as the Transuranic Extraction Option C (TRUEX-C) processing strategy); and an aggressive yet feasible processing strategy for separating the waste components to meet several main goals or objectives (referred to as the CLEAN Option processing strategy), such as the LLW is required to meet the US Nuclear Regulatory Commission Class A limits; concentrations of technetium, iodine, and uranium are reduced as low as reasonably achievable; and HLW will be contained within 1,000 borosilicate glass canisters that meet current Hanford Waste Vitrification Plant glass specifications.

Knutson, B.J.; Jansen, G.; Zimmerman, B.D.; Seeman, S.E. [Westinghouse Hanford Co., Richland, WA (United States); Lauerhass, L.; Hoza, M. [Pacific Northwest Lab., Richland, WA (United States)

1994-08-01T23:59:59.000Z

423

-Supporting Information-2 Patterned ion exchange membranes for improved power production in4  

E-Print Network [OSTI]

production in4 microbial reverse-electrodialysis cells5 6 Jia Liua , Geoffrey M. Geisea, b , Xi Luoc

424

Engineered Treatment of As-laden Regeneration Brine from Ion Exchange Processes .  

E-Print Network [OSTI]

??Arsenic (As) contamination of drinking water sources has been one of the most challenging global environmental issues. In the United States, the newly revised maximum… (more)

STEINWINDER, THOMAS

2006-01-01T23:59:59.000Z

425

Summary - Small Column Ion Exchange (SCIX)Technology at the SRS  

Office of Environmental Management (EM)

in an actinide and Sr osodium titanat olidsliquid sepa ). The objectiv ty of the SCIX ess of the proc n, and to provid g towards deta To view the full E http:www.em.doe....

426

Immobilization, Trapping, and Anion Exchange of Perrhenate Ion Using Copper-Based Tripodal Complexes  

E-Print Network [OSTI]

We describe a multidentate tripodal ligand in which three pendant arms carrying di(2-picolyl)amine units are linked to the ortho positions of a tris(o-xylyl) scaffold, providing N(CH[subscript 2]-o-C[subscript 6]H[subscript ...

Cao, Rui

427

SEPARATION OF PROTEINS BY ION EXCHANGE AND MEMBRANE CHROMATOGRAPHY: BUFFER COMPOSITION, INTERFERING IMPURITIES AND FOULING CONSIDERATIONS  

E-Print Network [OSTI]

on identifying major impurity and optimization of solution properties for target protein purification. The second approach consisted of designing an adsorbent that interacted specifically with the target molecule. The first study included modification of protein...

Imam, Tahmina

2010-01-16T23:59:59.000Z

428

E-Print Network 3.0 - argentine ion exchange Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Serveur Web : www.gate.cnrs.fr 12;1 Brsil-Argentine : effets... liberalisation, revealed comparative advantage. Rsum L'intgration commerciale de...

429

An Ion Exchange Study of Possible Hydridized 5f Bonding in the Actinides  

E-Print Network [OSTI]

e n t son auericiwn and promethium i n hydrochloric a c i dlanthanides lutetium, promethium, and cerium gradually movedAlso, although lutetium, promethium, and ceriwn kept t h e

Diamond, R.M.; Street, Jr., K.; Seaborg, G.T.

1951-01-01T23:59:59.000Z

430

Applications of Highly Cross Linked Mixed Bed Ion Exchange Resins in Biodiesel Processing  

E-Print Network [OSTI]

Biofuels are a promising solution to society's quest for sustainable energy. In the transportation sector, biodiesel is the leading alternative diesel fuel currently in use today. However, the current global and domestic production of biodiesel...

Jamal, Yousuf

2010-10-12T23:59:59.000Z

431

Detailed Investigation of Ion Exchange in Ball Milled LiH+MgB2 System using  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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432

Direct Observation of Ion Exchange in Mechanically Activated LiH+MgB2  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation Proposed Newcatalyst phasesDataTranslocation of Shewanella Oneidensisthe Size Distribution

433

Exchange bias in polycrystalline magnetite films made by ion-beam assisted  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsing ZirconiaPolicy and Assistance100 tonusingdeposition. | EMSL polycrystalline

434

External Technical Review Report for Small Column Ion Exchange Technology at Savannah River Site  

Office of Environmental Management (EM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "of Energy Power SystemsResources DOEElectricalonJusticeEnergy7249 Federaland Review of Infrastructure

435

Small Column Ion Exchange Technology at Savannah River Site | Department of  

Energy Savers [EERE]

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of Inspector GeneralDepartment of Energyof the Americas |DOE FormerEnergySaveP R

436

Summary - Small Column Ion Exchange (SCIX)Technology at the SRS  

Office of Environmental Management (EM)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May Jun Jul(Summary) "of Energy Power.pdf11-161-LNGInternational EnergyCommittee onGASRainey STAR Center | ETR-19Calcine

437

Iodine Adsorption on Ion-Exchange Resins and Activated Carbons– Batch Testing  

SciTech Connect (OSTI)

Iodine sorption onto seven resins and six carbon materials was evaluated using water from well 299-W19-36 on the Hanford Site. These materials were tested using a range of solution-to-solid ratios. The test results are as follows: • The efficacy of the resin and granular activated carbon materials was less than predicted based on manufacturers’ performance data. It is hypothesized that this is due to the differences in speciation previously determined for Hanford groundwater. • The sorption of iodine is affected by the iodine species in the source water. Iodine loading on resins using source water ranged from 1.47 to 1.70 µg/g with the corresponding Kd values from 189.9 to 227.0 mL/g. The sorption values when the iodine is converted to iodide ranged from 2.75 to 5.90 µg/g with the corresponding Kd values from 536.3 to 2979.6 mL/g. It is recommended that methods to convert iodine to iodide be investigated in fiscal year (FY) 2015. • The chemicals used to convert iodine to iodate adversely affected the sorption of iodine onto the carbon materials. Using as-received source water, loading and Kd values ranged from 1.47 to 1.70 µg/g and 189.8 to 226.3 mL/g respectively. After treatment, loading and Kd values could not be calculated because there was little change between the initial and final iodine concentration. It is recommended the cause of the decrease in iodine sorption be investigated in FY15. • In direct support of CH2M HILL Plateau Remediation Company, Pacific Northwest National Laboratory has evaluated samples from within the 200W pump and treat bioreactors. As part of this analysis, pictures taken within the bioreactor reveal a precipitate that, based on physical properties and known aqueous chemistry, is hypothesized to be iron pyrite or chalcopyrite, which could affect iodine adsorption. It is recommended these materials be tested at different solution-to-solid ratios in FY15 to determine their effect on iodine sorption.

Parker, Kent E.; Golovich, Elizabeth C.; Wellman, Dawn M.

2014-09-30T23:59:59.000Z

438

Chicago Climate Exchange CCX | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Office of InspectorConcentrating SolarElectricEnergyCTBarreisVolcanic National Park | OpenChevron Energy33.Exchange CCX

439

The effect of fluoride and aluminum on the anion exchange of plutonium from nitric acid  

SciTech Connect (OSTI)

Anion exchange in nitric acid is a prominent aqueous process used to recover and purify plutonium from impure nuclear materials. This process is sensitive to fluoride ion, which complexes plutonium in competition with the anionic nitrato complex that is strongly sorbed on the anion exchange column. Fluoride interference traditionally has been counteracted by adding a masking agent, such as aluminum, that forms competing complexes with fluoride. The interfering effect of fluoride is known to be a function not only of the fluoride-to-aluminum ratio but also of the fluoride-to-plutonium ratio. This report summarizes a Los Alamos study of the effect of 25 fluoride-aluminum-plutonium conmbinations on the anion exchange sorption of plutonium. Five aluminum-to-plutonium ratios ranging from 0.10 to 10 were each evaluated at five fluoride-to-aluminum ratios that ranged from 0 to 6. The fluoride-to-plutonium ratio has a greater influence on plutonium sorption than does the fluoride-to-aluminum ratio. Aluminum was less effective as a masking agent than had been assumed, because measurable fluoride interference occurred at all levels of added aluminum.

Marsh, S.F.

1987-07-01T23:59:59.000Z

440

Direct exchange interaction of localized spins associated with unpaired sp electrons in Be-doped low-temperature-grown GaAs layers  

SciTech Connect (OSTI)

Beryllium-doped GaAs layers grown at low temperatures by molecular-beam epitaxy contain localized spins associated with unpaired sp electrons of As{sub Ga}{sup +} ions. Interactions of these localized spins are investigated by measuring the magnetization with a superconducting quantum interference device and the peak-to-peak width of electron paramagnetic resonance (EPR) spectra for samples with different spin concentrations ranging from 3 x 10{sup 18} to 2.0 x 10{sup 19} cm{sup -3}. The results show that localized spins in this material antiferromagnetically interact on each other via direct exchange. From the analysis of the temperature dependence and field dependence of the magnetization on the basis of the Curie-Weiss law and the molecular-field approximation, exchange energy of each sample was derived. The dependence of the exchange energy on the concentration of localized spins is reasonably explained by a model of direct exchange, which results from the overlapping of wave functions of unpaired electrons at As{sub Ga}{sup +} ions. The peak-to-peak width of EPR spectra increases with an increase in the spin concentration at low temperatures, whereas it decreases with an increase in the temperature for samples with high spin concentrations. These EPR results also show that significant exchange interactions indeed occur between localized spins in this material. These effects of direct exchange interactions between localized spins can clearly be observed at their average distances of around 4 nm, which implies a considerably large spatial extension of the wave function of an unpaired sp electron around an As{sub Ga}{sup +} ion.

Bae, K. W.; Mohamed, Mohd Ambri; Jung, D. W.; Otsuka, N. [School of Materials Science Japan Advanced Institute of Science and Technology Asahidai 1-1, Nomishi, Ishikawa 923-1292 (Japan)

2011-04-01T23:59:59.000Z

Note: This page contains sample records for the topic "ion exchange ix" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Batch sorption of divalent metal ions onto brown coal  

SciTech Connect (OSTI)

Brown coal, a relatively abundant and inexpensive material is currently being investigated as an adsorbent to remove some contaminants from aqueous solution. The adsorption of some heavy metals from aqueous solutions on the brown coals was studied as a function of pH, contact time, adsorbent dosage and concentration of metal solutions. A carboxyl, phenolic hydroxyl, and metoxyl functional group present on the coal surface was the adsorption site to remove metal ions from solution by means of ion exchange and hydrogen bonding. Effective removal of heavy metals was achieved at pH values of 4.0-5.0. The experimental data have been analyzed using the Langmuir isotherm models. Under optimized conditions, the percentage of metal removal by brown coal adsorption was over 80%.

Pehlivan, E.; Gode, F. [University of Selcuk, Konya (Turkey). Faculty of Engineering & Architecture

2006-12-15T23:59:59.000Z

442

Photoabsorption by Ions and Atoms  

SciTech Connect (OSTI)

Recent progress in theoretical and experimental investigations of photoabsorption by atoms and ions is presented. Specifically, examples of near-chaotic behavior in photoionization of positive ions, low-energy manifestations of nondipole effects, high-energy breakdown of the single particle picture and new phenomenology uncovered in the inner-shell photoabsorption by negative ions are discussed.

Manson, Steven T. [Department of Physics and Astronomy, Georgia State University, Atlanta, Georgia 30303 (United States)

2004-12-01T23:59:59.000Z

443

Fuel ion rotation measurement and its implications on H-mode theories  

SciTech Connect (OSTI)

Poloidal and toroidal rotation of the fuel ions (He{sup 2+}) and the impurity ions (C{sup 6+} and B{sup 5+}) in H-mode helium plasmas have been investigated in the DIII-D tokamak by means of charge exchange recombination spectroscopy, resulting in the discovery that the fuel ion poloidal rotation is in the ion diamagnetic drift direction while the impurity ion rotation is in the electron diamagnetic drift direction. The radial electric field obtained from radial force balance analysis of the measured pressure gradients and rotation velocities is shown to be the same regardless of which ion species is used and therefore is a more fundamental parameter than the rotation flows in studying H-mode phenomena. It is shown that the three contributions to the radial electric field (diamagnetic, poloidal rotation, and toroidal rotation terms) are comparable and consequently the poloidal flow does not solely represent the E {times} B flow. In the high-shear edge region, the density scale length is comparable to the ion poloidal gyroradius, and thus neoclassical theory is not valid there. In view of this new discovery that the fuel and impurity ions rotate in opposite sense, L-H transition theories based on the poloidal rotation may require improvement.

Kim, J.; Burrell, K.H.; Gohil, P.; Groebner, R.J.; Hinton, F.L.; Kim, Y.B.; Seraydarian, R. [General Atomics, San Diego, CA (United States); Mandl, W. [Max-Planck-Institut fuer Plasmaphysik, Garching (Germany). Oberflaechenphysik; Wade, M.R. [Oak Ridge National Lab., TN (United States)

1993-10-01T23:59:59.000Z

444

Spherical ion oscillations in a positive polarity gridded inertial-electrostatic confinement device  

SciTech Connect (OSTI)

A pulsed, positive polarity gridded inertial electrostatic confinement device has been investigated experimentally, using a differential emissive probe and potential traces as primary diagnostics. Large amplitude oscillations in the plasma current and plasma potential were observed within a microsecond of the discharge onset, which are indicative of coherent ion oscillations about a temporarily confined excess of recirculating electron space charge. The magnitude of the depth of the potential well in the established virtual cathode was determined using a differential emissive Langmuir probe, which correlated well to the potential well inferred from the ion oscillation frequency for both hydrogen and argon experiments. It was found that the timescale for ion oscillation dispersion is strongly dependent on the neutral gas density, and weakly dependent on the peak anode voltage. The cessation of the oscillations was found to be due to charge exchange processes converting ions to high velocity neutrals, causing the abrupt de-coherence of the oscillations through an avalanche dispersion in phase space.

Bandara, R.; Khachan, J. [Plasma Physics, School of Physics, University of Sydney, Camperdown, New South Wales 2006 (Australia)] [Plasma Physics, School of Physics, University of Sydney, Camperdown, New South Wales 2006 (Australia)

2013-07-15T23:59:59.000Z

445

Ion Chromatograph | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

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446

Minutes of the 28th Annual Plutonium Sample Exchange Meeting. Part II: metal sample exchange  

SciTech Connect (OSTI)

Contents of this publication include the following list of participating laboratories; agenda; attendees; minutes of October 25 and 26 meeting; and handout materials supplied by speakers. The handout materials cover the following: statistics and reporting; plutonium - chemical assay 100% minus impurities; americium neptunium, uranium, carbon and iron data; emission spectroscopy data; plutonium metal sample exchange; the calorimetry sample exchange; chlorine determination in plutonium metal using phyrohydrolysis; spectrophotometric determination of 238-plutonium in oxide; plutonium measurement capabilities at the Savannah River Plant; and robotics in radiochemical laboratory.

Not Available

1984-01-01T23:59:59.000Z

447

Electron string ion sources for carbon ion cancer therapy accelerators  

E-Print Network [OSTI]

The Electron String type of Ion Sources (ESIS) was developed, constructed and tested first in the Joint Institute for Nuclear Research. These ion sources can be the appropriate sources for production of pulsed C4+ and C6+ ion beams which can be used for cancer therapy accelerators. In fact the test ESIS Krion-6T already now at the solenoid magnetic field only 4.6 T provides more than 10^10 C4+ ions per pulse and about 5*10^9 C6+ ions per pulse. Such ion sources could be suitable for application at synchrotrons. It was also found, that Krion-6T can provide more than 10^11 C6+ ions per second at 100 Hz repetition rate, and the repetition rate can be increased at the same or larger ion output per second. This makes ESIS applicable at cyclotrons as well. As for production of 11C radioactive ion beams ESIS can be the most economic kind of ion source. To proof that the special cryogenic cell for pulse injection of gaseous species into electron string was successfully tested using the ESIS Krion-2M.

Boytsov, A Yu; Donets, E D; Donets, E E; Katagiri, K; Noda, K; Ponkin, D O; Ramzdorf, A Yu; Salnikov, V V; Shutov, V B

2015-01-01T23:59:59.000Z

448

Scientific Exchange Application | Photosynthetic Antenna Research Center  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administrationcontroller systemsBi (2) Sr (2)Science HighlightAlanExchange Program / Scientific

449

Scientific Exchange Program deadline | Photosynthetic Antenna Research  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administrationcontroller systemsBi (2) Sr (2)Science HighlightAlanExchange Program /

450

Energy Technology Data Exchange | Open Energy Information  

Open Energy Info (EERE)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home5b9fcbce19 NoPublic Utilities Address:011-DNA Jump37. It isInformation Contracts (ESPC) Webinar Jump to:S AData Exchange

451

A novel planar ion funnel design for miniature ion optics  

SciTech Connect (OSTI)

The novel planar ion funnel (PIF) design presented in this article emphasizes simple fabrication, assembly, and operation, making it amenable to extreme miniaturization. Simulations performed in SIMION 8.0 indicate that ion focusing can be achieved by using a gradient of electrostatic potentials on concentric metal rings in a plane. A prototype was fabricated on a 35 × 35 mm custom-designed printed circuit board (PCB) with a center hole for ions to pass through and a series of concentric circular metal rings of increasing diameter on the front side of the PCB. Metal vias on the PCB electrically connected each metal ring to a resistive potential divider that was soldered on the back of the PCB. The PIF was tested at 5.5 × 10{sup ?6} Torr in a vacuum test setup that was equipped with a broad-beam ion source on the front and a micro channel plate (MCP) ion detector on the back of the PIF. The ion current recorded on the MCP anode during testing indicated a 23× increase in the ion transmission through the PIF when electric potentials were applied to the rings. These preliminary results demonstrate the functionality of a 2D ion funnel design with a much smaller footprint and simpler driving electronics than conventional 3D ion funnels. Future directions to improve the design and a possible micromachining approach to fabrication are discussed in the conclusions.

Chaudhary, A.; Amerom, Friso H. W. van; Short, R. T. [Space and Marine Technology Laboratory, SRI International, 450 8th Ave SE, St. Petersburg, Florida 33701 (United States)

2014-10-15T23:59:59.000Z

452

EPR Line Shifts and Line Shape Changes Due to Spin Exchange of Nitroxide Free Radicals in Liquids 2. Extension to High Spin Exchange Frequencies and Inhomogeneously  

E-Print Network [OSTI]

EPR Line Shifts and Line Shape Changes Due to Spin Exchange of Nitroxide Free Radicals in Liquids 2 for the EPR spectrum of a nitroxide free radical undergoing spin exchange in the slow exchange limit following

Bales, Barney

453

Compact ion accelerator source  

DOE Patents [OSTI]

An ion source includes a conductive substrate, the substrate including a plurality of conductive nanostructures with free-standing tips formed on the substrate. A conductive catalytic coating is formed on the nanostructures and substrate for dissociation of a molecular species into an atomic species, the molecular species being brought in contact with the catalytic coating. A target electrode placed apart from the substrate, the target electrode being biased relative to the substrate with a first bias voltage to ionize the atomic species in proximity to the free-standing tips and attract the ionized atomic species from the substrate in the direction of the target electrode.

Schenkel, Thomas; Persaud, Arun; Kapadia, Rehan; Javey, Ali

2014-04-29T23:59:59.000Z

454

Helium Ion Microscope | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-SeriesFlickr FlickrGuidedCH2M HILL SecretaryHazmat workFAQsHelium Ion Microscope

455

Diffusion-Welded Microchannel Heat Exchanger for Industrial Processes  

SciTech Connect (OSTI)

The goal of next generation reactors is to increase energy ef?ciency in the production of electricity and provide high-temperature heat for industrial processes. The ef?cient transfer of energy for industrial applications depends on the ability to incorporate effective heat exchangers between the nuclear heat transport system and the industrial process. The need for ef?ciency, compactness, and safety challenge the boundaries of existing heat exchanger technology. Various studies have been performed in attempts to update the secondary heat exchanger that is downstream of the primary heat exchanger, mostly because its performance is strongly tied to the ability to employ more ef?cient industrial processes. Modern compact heat exchangers can provide high compactness, a measure of the ratio of surface area-to-volume of a heat exchange. The microchannel heat exchanger studied here is a plate-type, robust heat exchanger that combines compactness, low pressure drop, high effectiveness, and the ability to operate with a very large pressure differential between hot and cold sides. The plates are etched and thereafter joined by diffusion welding, resulting in extremely strong all-metal heat exchanger cores. After bonding, any number of core blocks can be welded together to provide the required ?ow capacity. This study explores the microchannel heat exchanger and draws conclusions about diffusion welding/bonding for joining heat exchanger plates, with both experimental and computational modeling, along with existing challenges and gaps. Also, presented is a thermal design method for determining overall design speci?cations for a microchannel printed circuit heat exchanger for both supercritical (24 MPa) and subcritical (17 MPa) Rankine power cycles.

Piyush Sabharwall; Denis E. Clark; Michael V. Glazoff; Michael G. McKellar; Ronald E. Mizia

2013-03-01T23:59:59.000Z

456

Automatic Tube Cleaning Systems for Condensers and Heat Exchangers  

E-Print Network [OSTI]

AUTOMATIC TUBE CLEANING SYSTEMS FOR CONDENSERS AND HEAT EXCHANGERS Kaveh Someah/V.P. Sales & Mktg. WSA Engineered Systems, Milwaukee, WI (414) 354-6470 ABSTRACT The on-line Automatic Tube Cleaning Systems (ATCS) for condensers and heat... exchangers provide a positive means for automatic cleaning on a continuous basis, while the exchanger or condenser remains "on stream" and at its full operating potential. Condenser tube fouling contributes up to 50% of the total condenser tube heat...

Someah, K.

457

Demonstration and Performance Monitoring of Foundation Heat Exchangers...  

Energy Savers [EERE]

for New and Existing Homes: Foundation Heat Exchanger, Oak Ridge, Tennessee Performance Analysis of Air-Source Variable Speed Heat Pumps and Various Electric Water Heating Options...

458

High-Performance Refrigerator Using Novel Rotating Heat Exchanger...  

Broader source: Energy.gov (indexed) [DOE]

pumps have the potentially to reduce energy costs and refrigerant charge in a compact space. Rotating heat exchangers installed in appliances and heat pumps have the potentially...

459

Quality Assurance Exchange August 2009, Volume 5 Issue 2  

Broader source: Energy.gov [DOE]

Quality Assurance Exchange August 2009, Volume 5 Issue 2 U.S. Department of Energy Office of Quality Assurance Policy and Assistance

460

anion exchange centrifugation: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of a Centrifuged Double Y-Shape Microfluidic Platform for Simple Continuous Cell Environment Exchange CiteSeer Summary: Abstract: We have demonstrated the efficacy of a...

Note: This page contains sample records for the topic "ion exchange ix" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

affecting proton exchange: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

stress applied to the electrode area of a Proton Exchange Membrane (PEM) fuel cell is known to significantly affect power output. In practice, electrode stress arises...

462

annealed proton exchanged: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

characterized and integrated in Membrane-Electrodes Assembly to be tested in fuel cell operating conditions, mobile or stationary), Proton Exchange Membrane Fuel Cells...

463

alloy heat exchanger: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Heat Exchangers, Heat Transfer, Energy, Phase Change and multiphase process, Renewable energy (Solan, Tidal), Energy Storage, Conversion Cessi, Paola 53 Dealing with...

464

Computational modeling and optimization of proton exchange membrane fuel cells.  

E-Print Network [OSTI]

??Improvements in performance, reliability and durability as well as reductions in production costs, remain critical prerequisites for the commercialization of proton exchange membrane fuel cells.… (more)

Secanell Gallart, Marc

2007-01-01T23:59:59.000Z

465

Exchange Market Equilibria with Leontief's Utility: Freedom of ...  

E-Print Network [OSTI]

Aug 5, 2006 ... ... for the first time, solving this class of Leontief exchange economies is ...... Department of Management Science and Engineering, Stanford ...

2006-08-09T23:59:59.000Z

466

States Biomass/Clean Cities Information Exchange: Food and Fuel...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Clean Cities Information Exchange: Food and Fuel At the August 7, 2008 joint quarterly Web conference of DOE's Biomass and Clean Cities programs, Roya Stanley (Iowa Office of...

467

Design and Test of Tube & Shell Heat Exchangers for Potential  

E-Print Network [OSTI]

exchangerLow-temperature side Chiller > Calorimeter body Storage tank Storage tank Calorimeter monitor Calorimeter body High-temperature side Chiller > Experimental apparatus for seawater heat

468

Kitchen Appliance Upgrades Improve Water Efficiency at DOD Exchange...  

Broader source: Energy.gov (indexed) [DOE]

Kitchen Appliance Upgrades Improve Water Efficiency at DOD Exchange Facilities: Best Management Practice Case Study 11: Commercial Kitchen Equipment (Brochure), Federal Energy...

469

anion exchange membrane: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

(PEMFC) are amongst the most studied fuel Boyer, Edmond 13 Computational modeling and optimization of proton exchange membrane fuel cells. Open Access Theses and Dissertations...

470

anion exchange membranes: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

(PEMFC) are amongst the most studied fuel Boyer, Edmond 13 Computational modeling and optimization of proton exchange membrane fuel cells. Open Access Theses and Dissertations...

471

QUALITY ASSURANCE EXCHANGE December 2005 Volume 1 Issue 3  

Broader source: Energy.gov [DOE]

QUALITY ASSURANCE EXCHANGE December 2005 Volume 1 Issue 3 U.S. Department of Energy, Office of Corporate Performance Assessment Office of Quality Assurance Programs (EH-31)

472

Quality Assurance Exchange Winter 2010 Volume 6 Issue 1  

Broader source: Energy.gov [DOE]

Quality Assurance Exchange Winter 2010 Volume 6 Issue 1 U.S. Department of Energy Office of Quality Assurance Policy and Assistance

473

Quality Assurance Exchange October 2008 Volume 4 Issue 2  

Broader source: Energy.gov [DOE]

Quality Assurance Exchange October 2008 Volume 4 Issue 2 U.S. Department of Energy Office of Quality Assurance Policy and Assistance

474

Quality Assurance Exchange March 2006, Volume 2 Issue 1  

Broader source: Energy.gov [DOE]

Quality Assurance Exchange March 2006, Volume 2 Issue 1 U.S. Department of Energy, Office of Corporate Performance Assessment Office of Quality Assurance Programs (EH-31)

475

Controlling mercury spills in laboratories with a thermometer exchange program  

E-Print Network [OSTI]

and Verification of Thermometers. ©American Society forliquid-in-glass thermometers - general purpose laboratoryin Laboratories with A Thermometer Exchange Program Lawrence

McLouth, Lawrence D.

2002-01-01T23:59:59.000Z

476

Utilization of Methacrylates and Polymer Matrices for the Synthesis of Ion Specific Resins  

SciTech Connect (OSTI)

Disposal, storage, and/or transmutation of actinides such as americium (Am) will require the development of specific separation schemes. Existing efforts focus on solvent extraction systems for achieving suitable separation of actinide from lanthanides. However, previous work has shown the feasibility of ion-imprinting polymer-based resins for use in ion-exchange-type separations with metal ion recognition. Phenolic-based resins have been shown to function well for Am-Eu separations, but these resins exhibited slow kinetics and difficulties in the imprinting process. This project addresses the need for new and innovative methods for the selective separation of actinides through novel ion-imprinted resins. The project team will explore incorporation of metals into extended frameworks, including the possibility of 3D polymerized matrices that can serve as a solid-state template for specific resin preparation. For example, an anhydrous trivalent f-element chain can be formed directly from a metal carbonate, and methacrylic acid from water. From these simple coordination complexes, molecules of discrete size or shape can be formed via the utilization of coordinating ligands or by use of an anionic multi-ligand system incorporating methacrylate. Additionally, alkyl methyl methacrylates have been used successfully to create template nanospaces, which underscores their potential utility as 3D polymerized matrices. This evidence provides a unique route for the preparation of a specific metal ion template for the basis of ion-exchange separations. Such separations may prove to be excellent discriminators of metal ions, even between f-elements.

Czerwinski, Kenneth

2013-10-29T23:59:59.000Z

477

Microchannel Heat Exchangers with Carbon Dioxide  

SciTech Connect (OSTI)

The objective of the present study was to determine the performance of CO{sub 2} microchannel evaporators and gas coolers in operational conditions representing those of residential heat pumps. A set of breadboard prototype microchannel evaporators and gas coolers was developed and tested. The refrigerant in the heat exchangers followed a counter cross-flow path with respect to the airflow direction. The test conditions corresponded to the typical operating conditions of residential heat pumps. In addition, a second set of commercial microchannel evaporators and gas coolers was tested for a less comprehensive range of operating conditions. The test results were reduced and a comprehensive data analysis, including comparison with the previous studies in this field, was performed. Capacity and pressure drop of the evaporator and gas cooler for the range of parameters studied were analyzed and are documented in this report. A gas cooler performance prediction model based on non-dimensional parameters was also developed and results are discussed as well. In addition, in the present study, experiments were conducted to evaluate capacities and pressure drops for sub-critical CO{sub 2} flow boiling and transcritical CO{sub 2} gas cooling in microchannel heat exchangers. An extensive review of the literature failed to indicate any previous systematic study in this area, suggesting a lack of fundamental understanding of the phenomena and a lack of comprehensive data that would quantify the performance potential of CO{sub 2} microchannel heat exchangers for the application at hand. All experimental tests were successfully conducted with an energy balance within {+-}3%. The only exceptions to this were experiments at very low saturation temperatures (-23 C), where energy balances were as high as 10%. In the case of evaporators, it was found that a lower saturation temperature (especially when moisture condensation occurs) improves the overall heat transfer coefficient significantly. However, under such conditions, air side pressure drop also increases when moisture condensation occurs. An increase in airflow rate also increases the overall heat transfer coefficient. Air side pressure drop mainly depends on airflow rate. For the gas cooler, a significant portion of the heat transfer occurred in the first heat exchanger module on the refrigerant inlet side. The temperature and pressure of CO{sub 2} significantly affect the heat transfer and fluid flow characteristics due to some important properties (such as specific heat, density, and viscosity). In the transcritical region, performance of CO{sub 2} strongly depends on the operating temperature and pressure. Semi-empirical models were developed for predictions of CO{sub 2} evaporator and gas cooler system capacities. The evaporator model introduced two new factors to account for the effects of air-side moisture condensate and refrigerant outlet superheat. The model agreed with the experimental results within {+-}13%. The gas cooler model, based on non-dimensional parameters, successfully predicted the experimental results within {+-}20%. Recommendations for future work on this project include redesigning headers and/or introducing flow mixers to avoid flow mal-distribution problems, devising new defrosting techniques, and improving numerical models. These recommendations are described in more detail at the end of this report.

Zhao, Y.; Ohadi, M.M.; Radermacher, R.

2001-09-15T23:59:59.000Z

478

Electron exchange-correlation in quantum mechanics  

SciTech Connect (OSTI)

It is shown that Fermi-Dirac statistics is guaranteed by the Dirac current, from which spin-dependent quantum velocity fields and spin-dependent quantum trajectories can be inferred. Pauli's exclusion principle is demonstrated using the spin-dependent quantum trajectories. The Dirac current, unlike the Schroedinger current, is nonzero for stationary bound states due to the permanent magnetic moment of the electron. It is of order c{sup 0} in agreement with observation that Fermi-Dirac statistics is independent of electronic velocity. In summary the physical basis for exchange-correlation is found in Dirac's equation, although Schroedinger's equation may be used to evaluate the Dirac current in the nonrelativistic regime of electronic velocity.

Ritchie, B

2009-01-30T23:59:59.000Z

479

Systems Engineering Handbook Foreword ................................ ................................ ................................ ............................ ix  

E-Print Network [OSTI]

NASA Systems Engineering Handbook SP-610S June 1995 #12;Contents Foreword ................................ ................................ ................................ .... 1 Fundamentals of System Engineering ................................ ............................ 3 Definition of Systems Engineering

Rhoads, James

480

Series Foreword vii Acknowledgments ix  

E-Print Network [OSTI]

Ethics and Animal Research 19 Bernard E. Rollin 3 The Evolutionary Basis for Animal Research 31 Stephen P Empty Cages: Animal Rights and Vivisection 107 Tom Regan 8 Virtue, Vice, and Vivisection 125 Garret of Hypocrisy 267 Tom Regan 16 We're All Animals: A Feminist Treatment of the Moral Limits of Nonhuman Animal

Note: This page contains sample records for the topic "ion exchange ix" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

Characterization of Electrode Materials for Lithium Ion and Sodium Ion Batteries using Synchrotron Radiation Techniques  

E-Print Network [OSTI]

Relationships in the Li-Ion Battery Electrode Material LiNiAl foil may be used for Li ion battery cathode materials andElectrode materials, Li ion battery, Na ion battery, X-ray

Doeff, Marca M.

2013-01-01T23:59:59.000Z

482

Apparatus and method of dissociating ions in a multipole ion guide  

DOE Patents [OSTI]

A method of dissociating ions in a multipole ion guide is disclosed. A stream of charged ions is supplied to the ion guide. A main RF field is applied to the ion guide to confine the ions through the ion guide. An excitation RF field is applied to one pair of rods of the ion guide. The ions undergo dissociation when the applied excitation RF field is resonant with a secular frequency of the ions. The multipole ion guide is, but not limited to, a quadrupole, a hexapole, and an octopole.

Webb, Ian K.; Tang, Keqi; Smith, Richard D.; Ibrahim, Yehia M.; Anderson, Gordon A.

2014-07-08T23:59:59.000Z