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Note: This page contains sample records for the topic "ion batteries elucidated" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

Advances in lithium-ion batteries  

E-Print Network [OSTI]

Advances in Lithium-Ion Batteries Edited by Walter A. vanpuzzling mysteries of lithium ion batteries. The book beginssuch importance to lithium ion batteries one is amazed that

Kerr, John B.

2003-01-01T23:59:59.000Z

2

EV Everywhere Batteries Workshop - Next Generation Lithium Ion...  

Energy Savers [EERE]

Next Generation Lithium Ion Batteries Breakout Session Report EV Everywhere Batteries Workshop - Next Generation Lithium Ion Batteries Breakout Session Report Breakout session...

3

Novel Electrolytes for Lithium Ion Batteries  

SciTech Connect (OSTI)

We have been investigating three primary areas related to lithium ion battery electrolytes. First, we have been investigating the thermal stability of novel electrolytes for lithium ion batteries, in particular borate based salts. Second, we have been investigating novel additives to improve the calendar life of lithium ion batteries. Third, we have been investigating the thermal decomposition reactions of electrolytes for lithium-oxygen batteries.

Lucht, Brett L

2014-12-12T23:59:59.000Z

4

Electrolytes for lithium ion batteries  

DOE Patents [OSTI]

A family of electrolytes for use in a lithium ion battery. The genus of electrolytes includes ketone-based solvents, such as, 2,4-dimethyl-3-pentanone; 3,3-dimethyl 2-butanone(pinacolone) and 2-butanone. These solvents can be used in combination with non-Lewis Acid salts, such as Li.sub.2[B.sub.12F.sub.12] and LiBOB.

Vaughey, John; Jansen, Andrew N.; Dees, Dennis W.

2014-08-05T23:59:59.000Z

5

Improved Positive Electrode Materials for Li-ion Batteries  

E-Print Network [OSTI]

of the assembled Li-ion battery, such as the operating1-4: Schematic of a Li-ion battery. Li + ions are shuttledprocessing of active Li-ion battery materials. Various

Conry, Thomas Edward

2012-01-01T23:59:59.000Z

6

Characterization of Electrode Materials for Lithium Ion and Sodium Ion Batteries using Synchrotron Radiation Techniques  

E-Print Network [OSTI]

Relationships in the Li-Ion Battery Electrode Material LiNiAl foil may be used for Li ion battery cathode materials andElectrode materials, Li ion battery, Na ion battery, X-ray

Doeff, Marca M.

2013-01-01T23:59:59.000Z

7

Coated Silicon Nanowires as Anodes in Lithium Ion Batteries  

E-Print Network [OSTI]

for rechargeable lithium batteries. J. Power Sources 139,for advanced lithium-ion batteries. J. Power Sources 174,nano-anodes for lithium rechargeable batteries. Angew. Chem.

Watts, David James

2014-01-01T23:59:59.000Z

8

A Better Anode Design to Improve Lithium-Ion Batteries  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

A Better Anode Design to Improve Lithium-Ion Batteries A Better Anode Design to Improve Lithium-Ion Batteries Print Friday, 23 March 2012 13:53 Lithium-ion batteries are in smart...

9

Model Reformulation and Design of Lithium-ion Batteries  

E-Print Network [OSTI]

987 94 Model Reformulation and Design of Lithium-ion Batteries V.R. Subramanian1,*, V. Boovaragavan Prediction......................................997 Optimal Design of Lithium-ion Batteries Lithium-ion batteries, product design, Bayesian estimation, Markov Chain Monte Carlo simulation

Subramanian, Venkat

10

Secretary Chu Celebrates Expansion of Lithium-Ion Battery Production...  

Office of Environmental Management (EM)

Celebrates Expansion of Lithium-Ion Battery Production in North Carolina Secretary Chu Celebrates Expansion of Lithium-Ion Battery Production in North Carolina July 26, 2011 -...

11

Lithium Ion Battery Performance of Silicon Nanowires With Carbon...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Ion Battery Performance of Silicon Nanowires With Carbon Skin . Lithium Ion Battery Performance of Silicon Nanowires With Carbon Skin . Abstract: Silicon (Si) nanomaterials have...

12

Linking Ion Solvation and Lithium Battery Electrolyte Properties...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Linking Ion Solvation and Lithium Battery Electrolyte Properties Linking Ion Solvation and Lithium Battery Electrolyte Properties 2010 DOE Vehicle Technologies and Hydrogen...

13

Characterization of Materials for Li-ion Batteries: Success Stories...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Materials for Li-ion Batteries: Success Stories from the High Temperature Materials Laboratory (HTML) User Program Characterization of Materials for Li-ion Batteries: Success...

14

Characterization of Li-ion Batteries using Neutron Diffraction...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Li-ion Batteries using Neutron Diffraction and Infrared Imaging Techniques Characterization of Li-ion Batteries using Neutron Diffraction and Infrared Imaging Techniques 2011 DOE...

15

Fact Sheet: Lithium-Ion Batteries for Stationary Energy Storage...  

Energy Savers [EERE]

Fact Sheet: Lithium-Ion Batteries for Stationary Energy Storage (October 2012) Fact Sheet: Lithium-Ion Batteries for Stationary Energy Storage (October 2012) DOE's Energy Storage...

16

Predictive Models of Li-ion Battery Lifetime (Presentation)  

SciTech Connect (OSTI)

Predictive models of Li-ion battery reliability must consider a multiplicity of electrochemical, thermal and mechanical degradation modes experienced by batteries in application environments. Complicating matters, Li-ion batteries can experience several path dependent degradation trajectories dependent on storage and cycling history of the application environment. Rates of degradation are controlled by factors such as temperature history, electrochemical operating window, and charge/discharge rate. Lacking accurate models and tests, lifetime uncertainty must be absorbed by overdesign and warranty costs. Degradation models are needed that predict lifetime more accurately and with less test data. Models should also provide engineering feedback for next generation battery designs. This presentation reviews both multi-dimensional physical models and simpler, lumped surrogate models of battery electrochemical and mechanical degradation. Models are compared with cell- and pack-level aging data from commercial Li-ion chemistries. The analysis elucidates the relative importance of electrochemical and mechanical stress-induced degradation mechanisms in real-world operating environments. Opportunities for extending the lifetime of commercial battery systems are explored.

Smith, K.; Wood, E.; Santhanagopalan, S.; Kim, G.; Shi, Y.; Pesaran, A.

2014-09-01T23:59:59.000Z

17

Intercalation dynamics in lithium-ion batteries  

E-Print Network [OSTI]

A new continuum model has been proposed by Singh, Ceder, and Bazant for the ion intercalation dynamics in a single crystal of rechargeable-battery electrode materials. It is based on the Cahn-Hilliard equation coupled to ...

Burch, Damian

2009-01-01T23:59:59.000Z

18

LITHIUM-ION BATTERY CHARGING REPORT G. MICHAEL BARRAMEDA  

E-Print Network [OSTI]

to handle the Powerizer Li-Ion rechargeable Battery Packs. It will bring reveal battery specificationsLITHIUM-ION BATTERY CHARGING REPORT G. MICHAEL BARRAMEDA 1. Abstract This report introduces how the amount of "de-Rating" the batteries have experienced. 2. Safety Guidelines · Must put battery

Ruina, Andy L.

19

Negative Electrodes for Li-Ion Batteries  

SciTech Connect (OSTI)

Graphitized carbons have played a key role in the successful commercialization of Li-ion batteries. The physicochemical properties of carbon cover a wide range; therefore identifying the optimum active electrode material can be time consuming. The significant physical properties of negative electrodes for Li-ion batteries are summarized, and the relationship of these properties to their electrochemical performance in nonaqueous electrolytes, are discussed in this paper.

Kinoshita, Kim; Zaghib, Karim

2001-10-01T23:59:59.000Z

20

An Analytical Model for Predicting the Remaining Battery Capacity of Lithium-Ion Batteries  

E-Print Network [OSTI]

An Analytical Model for Predicting the Remaining Battery Capacity of Lithium-Ion Batteries Peng cycle-life tends to shrink significantly. The capacities of commercial lithium-ion batteries fade by 10 prediction model to estimate the remaining capacity of a Lithium-Ion battery. The proposed analytical model

Pedram, Massoud

Note: This page contains sample records for the topic "ion batteries elucidated" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Characterization of Electrode Materials for Lithium Ion and Sodium Ion Batteries using Synchrotron Radiation Techniques  

E-Print Network [OSTI]

Alternatives to Current Lithium-Ion Batteries. Adv. EnergyMaterials for Lithium Ion Batteries. Materials Matters. 7 4.to the Study of Lithium Ion Batteries. J. Solid State

Doeff, Marca M.

2013-01-01T23:59:59.000Z

22

Six-Membered-Ring Malonatoborate-Based Lithium Salts as Electrolytes for Lithium Ion Batteries  

E-Print Network [OSTI]

References 1. Lithium Ion Batteries: Fundamentals andProgram for Lithium Ion Batteries, U.S. Department ofas Electrolytes for Lithium Ion Batteries Li Yang a , Hanjun

Yang, Li

2014-01-01T23:59:59.000Z

23

STUDIES ON TWO CLASSES OF POSITIVE ELECTRODE MATERIALS FOR LITHIUM-ION BATTERIES  

E-Print Network [OSTI]

facing rechargeable lithium batteries. Nature, 2001. 414(of rechargeable lithium batteries, I. Lithium manganeseof rechargeable lithium batteries, II. Lithium ion

Wilcox, James D.

2010-01-01T23:59:59.000Z

24

Beyond Conventional Cathode Materials for Li-ion Batteries and Na-ion Batteries Nickel fluoride conversion materials and P2 type Na-ion intercalation cathodes /  

E-Print Network [OSTI]

active material for Li-ion battery, Fe2OF4. ElectrochemistryIron Fluoride, in a Li Ion Battery: A Solid-State NMR, X-raymaterials for Li-ion battery……………………………133 8.2. P2 type

Lee, Dae Hoe

2013-01-01T23:59:59.000Z

25

Lithium ion battery with improved safety  

DOE Patents [OSTI]

A lithium battery with improved safety that utilizes one or more additives in the battery electrolyte solution wherein a lithium salt is dissolved in an organic solvent, which may contain propylene, carbonate. For example, a blend of 2 wt % triphenyl phosphate (TPP), 1 wt % diphenyl monobutyl phosphate (DMP) and 2 wt % vinyl ethylene carbonate additives has been found to significantly enhance the safety and performance of Li-ion batteries using a LiPF6 salt in EC/DEC electrolyte solvent. The invention relates to both the use of individual additives and to blends of additives such as that shown in the above example at concentrations of 1 to 4-wt % in the lithium battery electrolyte. This invention relates to additives that suppress gas evolution in the cell, passivate graphite electrode and protect it from exfoliating in the presence of propylene carbonate solvents in the electrolyte, and retard flames in the lithium batteries.

Chen, Chun-hua; Hyung, Yoo Eup; Vissers, Donald R.; Amine, Khalil

2006-04-11T23:59:59.000Z

26

High-discharge-rate lithium ion battery  

SciTech Connect (OSTI)

The present invention provides for a lithium ion battery and process for creating such, comprising higher binder to carbon conductor ratios than presently used in the industry. The battery is characterized by much lower interfacial resistances at the anode and cathode as a result of initially mixing a carbon conductor with a binder, then with the active material. Further improvements in cycleability can also be realized by first mixing the carbon conductor with the active material first and then adding the binder.

Liu, Gao; Battaglia, Vincent S; Zheng, Honghe

2014-04-22T23:59:59.000Z

27

Finding Room for Improvement in Transition Metal Oxides Cathodes for Lithium-ion Batteries  

E-Print Network [OSTI]

Oxides Cathodes for Lithium-ion Batteries Kinson C. Kam andusing rechargeable lithium-ion batteries has become an

Kam, Kinson

2012-01-01T23:59:59.000Z

28

Mechanical Properties of Lithium-Ion Battery Separator Materials  

E-Print Network [OSTI]

Mechanical Properties of Lithium-Ion Battery Separator Materials Patrick Sinko B.S. Materials Science and Engineering 2013, Virginia Tech John Cannarella PhD. Candidate Mechanical and Aerospace and motivation ­ Why study lithium-ion batteries? ­ Lithium-ion battery fundamentals ­ Why study the mechanical

Petta, Jason

29

Improved layered mixed transition metal oxides for Li-ion batteries  

E-Print Network [OSTI]

for rechargeable lithium batteries," Science 311(5763), 977-^ for Advanced Lithium-Ion Batteries," J. Electrochem. Soc.02 for lithium-ion batteries," Chem. Lett. , [3] Yabuuchi,

Doeff, Marca M.

2010-01-01T23:59:59.000Z

30

Performance Characteristics of Lithium-ion Batteries of Various Chemistries for Plug-in Hybrid Vehicles  

E-Print Network [OSTI]

the manufacture of lithium batteries (References 2 and 3).Characteristics of Lithium-ion Batteries of VariousAdvisor utilizing lithium-ion batteries of the different

Burke, Andrew; Miller, Marshall

2009-01-01T23:59:59.000Z

31

Surface reconstruction and chemical evolution of stoichiometric layered cathode materials for lithium-ion batteries  

E-Print Network [OSTI]

Layered Oxides for Lithium Batteries. Nano Lett. 13, 3857–O 2 Cathode Material in Lithium Ion Batteries. Adv. Energydecomposition in lithium ion batteries: first-principles

Lin, Feng

2014-01-01T23:59:59.000Z

32

EV Everywhere Batteries Workshop - Beyond Lithium Ion Breakout...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Beyond Lithium Ion Breakout Session Report EV Everywhere Batteries Workshop - Beyond Lithium Ion Breakout Session Report Breakout session presentation for the EV Everywhere Grand...

33

Anode materials for lithium-ion batteries  

DOE Patents [OSTI]

An anode material for lithium-ion batteries is provided that comprises an elongated core structure capable of forming an alloy with lithium; and a plurality of nanostructures placed on a surface of the core structure, with each nanostructure being capable of forming an alloy with lithium and spaced at a predetermined distance from adjacent nanostructures.

Sunkara, Mahendra Kumar; Meduri, Praveen; Sumanasekera, Gamini

2014-12-30T23:59:59.000Z

34

Towards a lithium-ion fiber battery  

E-Print Network [OSTI]

One of the key objectives in the realm of flexible electronics and flexible power sources is to achieve large-area, low-cost, scalable production of flexible systems. In this thesis we propose a new Li-ion battery architecture ...

Grena, Benjamin (Benjamin Jean-Baptiste)

2013-01-01T23:59:59.000Z

35

Three-Dimensional Lithium-Ion Battery Model (Presentation)  

SciTech Connect (OSTI)

Nonuniform battery physics can cause unexpected performance and life degradations in lithium-ion batteries; a three-dimensional cell performance model was developed by integrating an electrode-scale submodel using a multiscale modeling scheme.

Kim, G. H.; Smith, K.

2008-05-01T23:59:59.000Z

36

Transport and Failure in Li-ion Batteries | Stanford Synchrotron...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Li-ion Batteries Monday, February 13, 2012 - 1:30pm SSRL Conference Room 137-322 Stephen J. Harris, General Motors R&D While battery performance is well predicted by the...

37

Lithium-ion battery modeling using non-equilibrium thermodynamics  

E-Print Network [OSTI]

The focus of this thesis work is the application of non-equilibrium thermodynamics in lithium-ion battery modeling. As the demand for higher power and longer lasting batteries increases, the search for materials suitable ...

Ferguson, Todd R. (Todd Richard)

2014-01-01T23:59:59.000Z

38

Structural Integration of Silicon Solar Cells and Lithium-ion Batteries Using Printed Electronics  

E-Print Network [OSTI]

state lithium-ion (Li-ion) battery were adhesively joinedfilm solid state Li-ion battery was not able to withstand5.8 The performance of the Li-ion battery under tensile

Kang, Jin Sung

2012-01-01T23:59:59.000Z

39

Side Reactions in Lithium-Ion Batteries  

E-Print Network [OSTI]

for rechargeable lithium batteries. Advanced Materials 10,Protection of Secondary Lithium Batteries. Journal of thein Rechargeable Lithium Batteries for Overcharge Protection.

Tang, Maureen Han-Mei

2012-01-01T23:59:59.000Z

40

Design Principles for the Use of Electroactive Polymers for Overcharge Protection of Lithium-Ion Batteries  

E-Print Network [OSTI]

Modeling of Lithium Batteries. Kluwer Academic Publishers,of interest for lithium batteries. Therefore, we can use y =and J. Newman, Advances in Lithium-Ion Batteries, ch.

Thomas-Alyea, Karen E.; Newman, John; Chen, Guoying; Richardson, Thomas J.

2005-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "ion batteries elucidated" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Improved layered mixed transition metal oxides for Li-ion batteries  

E-Print Network [OSTI]

for rechargeable lithium batteries," Science 311 (5763),for rechargeable lithium batteries," Science 311(5763), 977-M n , ^ for Advanced Lithium-Ion Batteries," J. Electrochem.

Doeff, Marca M.

2010-01-01T23:59:59.000Z

42

Advanced Cathode Material Development for PHEV Lithium Ion Batteries...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

More Documents & Publications Advanced Cathode Material Development for PHEV Lithium Ion Batteries High Energy Novel Cathode Alloy Automotive Cell Develop & evaluate...

43

Electrode Materials for Rechargeable Lithium-Ion Batteries: A...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Electrode Materials for Rechargeable Lithium-Ion Batteries: A New Synthetic Approach Technology available for licensing: New high-energy cathode materials for use in rechargeable...

44

Correlation of Lithium-Ion Battery Performance with Structural...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Correlation of Lithium-Ion Battery Performance with Structural and Chemical Transformations Wednesday, April 30, 2014 Chemical evolution and structural transformations in a...

45

Advanced Cathode Material Development for PHEV Lithium Ion Batteries...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

More Documents & Publications Advanced Cathode Material Development for PHEV Lithium Ion Batteries Vehicle Technologies Office Merit Review 2014: High Energy Novel...

46

Lower Cost Lithium Ion Batteries From Aluminum Substituted Cathode...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Lower Cost Lithium Ion Batteries From Aluminum Substituted Cathode Materials Lawrence Berkeley National Laboratory Contact LBL About This Technology Technology Marketing...

47

High Voltage Electrolytes for Li-ion Batteries  

Broader source: Energy.gov (indexed) [DOE]

or otherwise restricted information High Voltage Electrolytes for Li-ion Batteries Vehicle Technologies Program 2 Overview * Start: Sep 2008 * End: Sep 2011 * 20 %...

48

Characterization of Materials for Li-ion Batteries: Success Stories...  

Broader source: Energy.gov (indexed) [DOE]

Materials for Li-ion Batteries: Success Stories from the High Temperature Materials Laboratory (HTML) User Program DOE 2010 Vehicle Technologies Annual Merit Review and Peer...

49

Alloys as Anode Materials in Magnesium Ion Batteries.  

E-Print Network [OSTI]

?? This thesis is a feasibility study of the possible application of magnesium alloys forfuture magnesium-ion batteries. It investigates dierent alloys and characterizesthem with respect… (more)

Syvertsen, Alf Petter

2012-01-01T23:59:59.000Z

50

Characterization of Li-ion Batteries using Neutron Diffraction...  

Broader source: Energy.gov (indexed) [DOE]

Li-ion batteries Using Neutron Diffraction and Infrared Imaging Techniques: Success Stories from the High Temperature Materials Laboratory (HTML) User Program DOE 2011 Vehicle...

51

Investigation of critical parameters in Li-ion battery electrodes...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

of critical parameters in Li-ion battery electrodes 2011 DOE Hydrogen and Fuel Cells Program, and Vehicle Technologies Program Annual Merit Review and Peer Evaluation...

52

Development of Electrolytes for Lithium-ion Batteries  

Broader source: Energy.gov (indexed) [DOE]

Battaglia & J. Kerr (LBNL) * M. Payne (Novolyte) * F. Puglia & B. Ravdel (Yardney) * G. Smith & O. Borodin (U. Utah) 3 3 Develop novel electrolytes for lithium ion batteries that...

53

Beyond Conventional Cathode Materials for Li-ion Batteries and Na-ion Batteries Nickel fluoride conversion materials and P2 type Na-ion intercalation cathodes /  

E-Print Network [OSTI]

in a Li Ion Battery: A Solid-State NMR, X-ray Diffraction,in a Li Ion Battery: A Solid-State NMR, X-ray Diffraction,

Lee, Dae Hoe

2013-01-01T23:59:59.000Z

54

Defective graphene as promising anode material for Na-ion battery and Ca-ion battery  

E-Print Network [OSTI]

We have investigated adsorption of Na and Ca on graphene with divacancy (DV) and Stone-Wales (SW) defect. Our results show that adsorption is not possible on pristine graphene. However, their adsorption on defective sheet is energetically favorable. The enhanced adsorption can be attributed to the increased charge transfer between adatoms and underlying defective sheet. With the increase in defect density until certain possible limit, maximum percentage of adsorption also increases giving higher battery capacity. For maximum possible DV defect, we can achieve maximum capacity of 1459 mAh/g for Na-ion batteries (NIBs) and 2900 mAh/g for Ca-ion batteries (CIBs). For graphene full of SW defect, we find the maximum capacity of NIBs and CIBs is around 1071 mAh/g and 2142 mAh/g respectively. Our results will help create better anode materials with much higher capacity and better cycling performance for NIBs and CIBs.

Datta, Dibakar; Shenoy, Vivek B

2013-01-01T23:59:59.000Z

55

Failure modes in high-power lithium-ion batteries for use in hybrid electric vehicles  

E-Print Network [OSTI]

MODES IN HIGH-POWER LITHIUM-ION BATTERIES FOR USE IN HYBRIDof high-power lithium-ion batteries for hybrid electricthe development of lithium-ion batteries for hybrid electric

2001-01-01T23:59:59.000Z

56

Develop high energy high power Li-ion battery cathode materials : a first principles computational study  

E-Print Network [OSTI]

as cathode materials for Li-ion battery. Physica B-CondensedHigh Energy High Power Li-ion Battery Cathode Materials AHigh Energy High Power Li-ion Battery Cathode Materials A

Xu, Bo; Xu, Bo

2012-01-01T23:59:59.000Z

57

Anodic polymerization of vinyl ethylene carbonate in Li-Ion battery electrolyte  

E-Print Network [OSTI]

Ethylene Carbonate in Li-Ion Battery Electrolyte Guoyingof a commercial Li-ion battery electrolyte containing 2 %are an important part of Li-ion battery technology yet their

Chen, Guoying; Zhuang, Guorong V.; Richardson, Thomas J.; Gao, Liu; Ross Jr., Philip N.

2005-01-01T23:59:59.000Z

58

Lithium-ion batteries having conformal solid electrolyte layers  

DOE Patents [OSTI]

Hybrid solid-liquid electrolyte lithium-ion battery devices are disclosed. Certain devices comprise anodes and cathodes conformally coated with an electron insulating and lithium ion conductive solid electrolyte layer.

Kim, Gi-Heon; Jung, Yoon Seok

2014-05-27T23:59:59.000Z

59

Dispelling a Misconception About Mg-Ion Batteries  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

One promising alternative would be a battery based on a multivalent ion, such as magnesium (Mg). Whereas a Li-ion with a charge of +1 provides only a single electron for an...

60

Ion implantation of highly corrosive electrolyte battery components  

DOE Patents [OSTI]

A method of producing corrosion resistant electrodes and other surfaces in corrosive batteries using ion implantation is described. Solid electrically conductive material is used as the ion implantation source. Battery electrode grids, especially anode grids, can be produced with greatly increased corrosion resistance for use in lead acid, molten salt, end sodium sulfur.

Muller, Rolf H. (Berkeley, CA); Zhang, Shengtao (Berkeley, CA)

1997-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "ion batteries elucidated" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Ion implantation of highly corrosive electrolyte battery components  

DOE Patents [OSTI]

A method of producing corrosion resistant electrodes and other surfaces in corrosive batteries using ion implantation is described. Solid electrically conductive material is used as the ion implantation source. Battery electrode grids, especially anode grids, can be produced with greatly increased corrosion resistance for use in lead acid, molten salt, and sodium sulfur. 6 figs.

Muller, R.H.; Zhang, S.

1997-01-14T23:59:59.000Z

62

Microstructural Modeling and Design of Rechargeable Lithium-Ion Batteries  

E-Print Network [OSTI]

Microstructural Modeling and Design of Rechargeable Lithium-Ion Batteries R. Edwin Garci´a,a, *,z microstructure. Experi- mental measurements are reproduced. Early models for lithium-ion batteries were developed Institute of Technology, Cambridge, Massachusetts 01239-4307, USA The properties of rechargeable lithium

García, R. Edwin

63

Mechanics of Electrodes in Lithium-ion Batteries A dissertation presented  

E-Print Network [OSTI]

investigates the mechanical behavior of electrodes in Li-ion batteries. Each electrode in a Li-ion battery of electrodes in Li-ion batteries. We model an inelastic host of Li by considering diffusion, elastic reaction promotes plastic deformation by lowering the stress needed to flow. Li-ion battery is an emerging

64

Fail Safe Design for Large Capacity Lithium-ion Batteries  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Fail Safe Design for Large Capacity Lithium-ion Batteries NREL Commercialization & Tech Transfer Webinar March 27, 2011 Gi-Heon Kim gi-heon.kim@nrel.gov John Ireland, Kyu-Jin Lee,...

65

Thermo-mechanical Behavior of Lithium-ion Battery Electrodes  

E-Print Network [OSTI]

Developing electric vehicles is widely considered as a direct approach to resolve the energy and environmental challenges faced by the human race. As one of the most promising power solutions to electric cars, the lithium ion battery is expected...

An, Kai

2013-11-25T23:59:59.000Z

66

Development of High Energy Cathode for Li-ion Batteries  

Broader source: Energy.gov (indexed) [DOE]

for Li-ion Batteries Ji-Guang Zhang and Jun Liu Pacific Northwest National Laboratory 2010 DOE Vehicle Technologies Program Review June 7-11, 2010 Project ID: ES056 This...

67

Understanding Why Silicon Anodes of Lithium-Ion Batteries Are...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Understanding Why Silicon Anodes of Lithium-Ion Batteries Are Fast to Discharge but Slow to Charge December 02, 2014 Measured and calculated rate-performance of a Si thin-film (70...

68

2010 DOE, Li-Ion Battery Cell Manufacturing  

Broader source: Energy.gov (indexed) [DOE]

otherwise restricted information" 2010 DOE, Li-Ion Battery Cell Manufacturing Kee Eun LG Chem Ltd.Compact Power Inc. Jun 8 th 2010 Project ID ARRAVT001 "This presentation does...

69

Sodium Ion Insertion in Hollow Carbon Nanowires for Battery Applicatio...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

B Schwenzer, J Xiao, Z Nie, LV Saraf, Z Yang, and J Liu.2012."Sodium Ion Insertion in Hollow Carbon Nanowires for Battery Applications."Nano Letters 12(7):37833787....

70

Development of High Capacity Anode for Li-ion Batteries  

Broader source: Energy.gov (indexed) [DOE]

stability of Si-based anode. 4 Milestones * Synthesize and characterize TiO 2 Graphene and SnO 2 Graphene nano-composite as anode for Li-ion batteries. - on going *...

71

Construction of a Li Ion Battery (LIB) Cathode Production Plant...  

Broader source: Energy.gov (indexed) [DOE]

Construction of a Li Ion Battery (LIB) Cathode Production Plant in Elyria, Ohio Project ID ARRAVT008 Joe DiCarlo BASF Corporation May 11, 2011 "This presentation does not contain...

72

Prediction of Retained Capacity and EODV of Li-ion Batteries in LEO Spacecraft Batteries  

E-Print Network [OSTI]

In resent years ANN is widely reported for modeling in different areas of science including electro chemistry. This includes modeling of different technological batteries such as lead acid battery, Nickel cadmium batteries etc. Lithium ion batteries are advance battery technology which satisfy most of the space mission requirements. Low earth orbit (LEO)space craft batteries undergo large number of charge discharge cycles (about 25000 cycles)compared to other ground level or space applications. This study is indented to develop ANN model for about 25000 cycles, cycled under various temperature, Depth Of Discharge (DOD) settings with constant charge voltage limit to predict the retained capacity and End of Discharge Voltage (EODV). To extract firm conclusion and distinguish the capability of ANN method, the predicted values are compared with experimental result by statistical method and Bland Altman plot.

Ramakrishnan, S; Jeyakumar, A Ebenezer

2010-01-01T23:59:59.000Z

73

A Model Reduction Framework for Efficient Simulation of Li-Ion Batteries  

E-Print Network [OSTI]

of degradation processes in lithium-ion batteries, the modelling of cell dynamics at the mircometer scale lithium-ion batteries is the deposition of metallic lithium at the negative battery electrode (LiA Model Reduction Framework for Efficient Simulation of Li-Ion Batteries Mario Ohlberger Stephan

74

The development of low cost LiFePO4-based high power lithium-ion batteries  

E-Print Network [OSTI]

study of rechargeable lithium batteries for application inin consumer-size lithium batteries, such as the synthetic4 -BASED HIGH POWER LITHIUM-ION BATTERIES Joongpyo Shim,

Shim, Joongpyo; Sierra, Azucena; Striebel, Kathryn A.

2003-01-01T23:59:59.000Z

75

Virus constructed iron phosphate lithium ion batteries in unmanned aircraft systems  

E-Print Network [OSTI]

FePO? lithium ion batteries that have cathodes constructed by viruses are scaled up in size to examine potential for use as an auxiliary battery in the Raven to power the payload equipment. These batteries are assembled ...

Kolesnikov-Lindsey, Rachel

76

NANOMATERIALS FOR HIGH CAPACITY LI-ION BATTERIES Taylor Grieve, Iowa State University, SURF 2009 Fellow  

E-Print Network [OSTI]

NANOMATERIALS FOR HIGH CAPACITY LI-ION BATTERIES Taylor Grieve, Iowa State University, SURF 2009 energy storage devices continues to grow. Lithium-ion (Li-ion) secondary, or renewable, batteries are of interest due to their high energy and power characteristics. Performance enhancements of Li- ion batteries

Li, Mo

77

Thermal Stability of LiPF6 Salt and Li-ion Battery Electrolytes Containing LiPF6  

E-Print Network [OSTI]

of LiPF 6 Salt and Li-ion Battery Electrolytes ContainingLiPF 6 in prototypical Li-ion battery solvents was studied6 and the prototypical Li- ion battery solvents EC, PC, DMC

Yang, Hui; Zhuang, Guorong V.; Ross Jr., Philip N.

2006-01-01T23:59:59.000Z

78

Electrolytes for Use in High Energy Lithium-Ion Batteries with...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

for Use in High Energy Lithium-Ion Batteries with Wide Operating Temperature Range Electrolytes for Use in High Energy Lithium-Ion Batteries with Wide Operating Temperature Range...

79

Implications of Rapid Charging and Chemo-Mechanical Degradation in Lithium-Ion Battery Electrodes  

E-Print Network [OSTI]

Li-ion batteries, owing to their unique characteristics with high power and energy density, are broadly considered a leading candidate for vehicle electrification. A pivotal performance drawback of the Li-ion batteries manifests in the lengthy...

Hasan, Mohammed Fouad

2014-04-23T23:59:59.000Z

80

Post-Test Analysis of Lithium-Ion Battery Materials at Argonne...  

Broader source: Energy.gov (indexed) [DOE]

Test Analysis of Lithium-Ion Battery Materials at Argonne National Laboratory Post-Test Analysis of Lithium-Ion Battery Materials at Argonne National Laboratory 2013 DOE Hydrogen...

Note: This page contains sample records for the topic "ion batteries elucidated" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Low-Cost Graphite and Olivine-Based Materials for Li-Ion Batteries...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Low-Cost Graphite and Olivine-Based Materials for Li-Ion Batteries Low-Cost Graphite and Olivine-Based Materials for Li-Ion Batteries Presentation from the U.S. DOE Office of...

82

Development of Cell/Pack Level Models for Automotive Li-Ion Batteries...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

CellPack Level Models for Automotive Li-Ion Batteries with Experimental Validation Development of CellPack Level Models for Automotive Li-Ion Batteries with Experimental...

83

Modeling and Simulation of Lithium-Ion Batteries from a Systems Engineering Perspective  

E-Print Network [OSTI]

The lithium-ion battery is an ideal candidate for a wide variety of applications due to its high energy/power density and operating voltage. Some limitations of existing lithium-ion battery technology include underutilization, ...

Braatz, Richard D.

84

Modeling temperature distribution in cylindrical lithium ion batteries for use in electric vehicle cooling system design  

E-Print Network [OSTI]

Recent advancements in lithium ion battery technology have made BEV's a more feasible alternative. However, some safety concerns still exist. While the energy density of lithium ion batteries has all but made them the ...

Jasinski, Samuel Anthony

2008-01-01T23:59:59.000Z

85

Advanced Li-Ion Polymer Battery Cell Manufacturing Plant in USA...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Li-Ion Polymer Battery Cell Manufacturing Plant in USA Advanced Li-Ion Polymer Battery Cell Manufacturing Plant in USA 2012 DOE Hydrogen and Fuel Cells Program and Vehicle...

86

A Yolk-Shell Design for Stabilized and Scalable Li-Ion Battery...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Yolk-Shell Design for Stabilized and Scalable Li-Ion Battery Alloy Anodes. A Yolk-Shell Design for Stabilized and Scalable Li-Ion Battery Alloy Anodes. Abstract: Silicon is...

87

Nanoscale LiFePO4 and Li4Ti5O12 for High Rate Li-ion Batteries  

E-Print Network [OSTI]

12 for High Rate Li-ion Batteries A. Jaiswal 1 , C. R. Hornenext generation of Li-ion batteries for consumer electronics

Jaiswal, A.

2010-01-01T23:59:59.000Z

88

Improvement of Thermal Stability of Li-Ion Batteries by Polymer Coating of LiMn2O4  

E-Print Network [OSTI]

thermal stability of the Li-ion battery. CONCLUSIONS CoatingPDDA. EC- AFM studies on Li-ion battery electrodes offered

Stroeve, Pieter; Vidu, Ruxandra

2004-01-01T23:59:59.000Z

89

Advanced Electrolyte Additives for PHEV/EV Lithium-ion Battery...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

More Documents & Publications Advanced Electrolyte Additives for PHEVEV Lithium-ion Battery Development of Advanced Electrolytes and Electrolyte Additives...

90

E-Print Network 3.0 - aqueous lithium-ion battery Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: -board identification and diagnostics for Lithium Ion batteries. The electrochemical, electrical, and transport... and cost Target, Current technology status...

91

Design of a Lithium-ion Battery Pack for PHEV Using a Hybrid Optimization Method  

E-Print Network [OSTI]

Design of a Lithium-ion Battery Pack for PHEV Using a Hybrid Optimization Method Nansi Xue1 Abstract This paper outlines a method for optimizing the design of a lithium-ion battery pack for hy- brid, volume or material cost. Keywords: Lithium-ion, Optimization, Hybrid vehicle, Battery pack design

Papalambros, Panos

92

Electrolyte Stability Determines Scaling Limits for Solid-State 3D Li Ion Batteries  

E-Print Network [OSTI]

Electrolyte Stability Determines Scaling Limits for Solid-State 3D Li Ion Batteries Dmitry Ruzmetov, all-solid-state Li ion batteries (LIBs) with high specific capacity and small footprint are highly to their high-energy density, Li ion batteries (LIBs) are attractive for these applications, and all-solid-state

Rubloff, Gary W.

93

Stochastic reconstruction and electrical transport studies of porous cathode of Li-ion batteries  

E-Print Network [OSTI]

of the Li-ion batteries through developing electrode materials [1e5], reducing size [6] and optimizing shape,13], as one of the main factors limiting Li-ion battery performance, has not been resolved. Fundamental the ulti- mate performance and stability. Theoretical work of Li-ion batteries has focused on macroscopic

Liu, Fuqiang

94

Porous Doped Silicon Nanowires for Lithium Ion Battery Anode with Long Cycle Life  

E-Print Network [OSTI]

in energy storage has stimulated significant interest in lithium ion battery research. The lithium ion battery is one of the most promising systems which is efficient in delivering energy, light in weightPorous Doped Silicon Nanowires for Lithium Ion Battery Anode with Long Cycle Life Mingyuan Ge

Zhou, Chongwu

95

Cycle Life Modeling of Lithium-Ion Batteries Gang Ning* and Branko N. Popov**,z  

E-Print Network [OSTI]

Cycle Life Modeling of Lithium-Ion Batteries Gang Ning* and Branko N. Popov**,z Department and Newman4 made a first attempt to model the parasitic reactions in lithium-ion batteries by incorporating a solvent oxidation into a lithium-ion battery model. Spotnitz5 developed polynomial expressions

Popov, Branko N.

96

Performance Characteristics of Cathode Materials for Lithium-Ion Batteries: A Monte Carlo Strategy  

E-Print Network [OSTI]

Performance Characteristics of Cathode Materials for Lithium-Ion Batteries: A Monte Carlo Strategy to study the performance of cathode materials in lithium-ion batteries. The methodology takes into account. Published September 26, 2008. Lithium-ion batteries are state-of-the-art power sources1 for por- table

Subramanian, Venkat

97

AN OPEN-CIRCUIT-VOLTAGE MODEL OF LITHIUM-ION BATTERIES FOR EFFECTIVE INCREMENTAL CAPACITY ANALYSIS  

E-Print Network [OSTI]

AN OPEN-CIRCUIT-VOLTAGE MODEL OF LITHIUM-ION BATTERIES FOR EFFECTIVE INCREMENTAL CAPACITY ANALYSIS electrochemical properties and aging status. INTRODUCTION With the widespread use of lithium-ion batteries the com- plex battery physical behavior during the lithium-ion intercalac- tion/deintercalation process

Peng, Huei

98

Abstract--This paper describes experimental results aiming at analyzing lithium-ion batteries performances  

E-Print Network [OSTI]

Abstract--This paper describes experimental results aiming at analyzing lithium-ion batteries (SOH) of cells. Index Terms--Lithium-ion batteries, Aging, EIS, State Of Charge, State Of Health, Fuzzy Logic System. I. INTRODUCTION Lithium ion secondary batteries are now being used in wide applications

Boyer, Edmond

99

Stress generation during lithiation of high-capacity electrode particles in lithium ion batteries  

E-Print Network [OSTI]

Stress generation during lithiation of high-capacity electrode particles in lithium ion batteries S in controlling stress generation in high-capacity electrodes for lithium ion batteries. Ã? 2013 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved. Keywords: Lithium ion battery; Lithiation

Zhu, Ting

100

Arrays of Sealed Silicon Nanotubes As Anodes for Lithium Ion Batteries  

E-Print Network [OSTI]

Arrays of Sealed Silicon Nanotubes As Anodes for Lithium Ion Batteries Taeseup Song, Jianliang Xia ABSTRACT Silicon is a promising candidate for electrodes in lithium ion batteries due to its large reversible capacity and long-term cycle stability. KEYWORDS Lithium ion battery, silicon, nanotubes

Rogers, John A.

Note: This page contains sample records for the topic "ion batteries elucidated" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Kinetics of Initial Lithiation of Crystalline Silicon Electrodes of Lithium-Ion Batteries  

E-Print Network [OSTI]

Kinetics of Initial Lithiation of Crystalline Silicon Electrodes of Lithium-Ion Batteries Matt phase. KEYWORDS: Lithium-ion batteries, silicon, kinetics, plasticity Lithium-ion batteries already at the electrolyte/lithiated silicon interface, diffusion of lithium through the lithiated phase, and the chemical

102

Large Plastic Deformation in High-Capacity Lithium-Ion Batteries Caused by Charge and Discharge  

E-Print Network [OSTI]

Large Plastic Deformation in High-Capacity Lithium-Ion Batteries Caused by Charge and Discharge, Massachusetts 02138 Evidence has accumulated recently that a high-capacity elec- trode of a lithium-ion battery in the particle is high, possibly leading to fracture and cavitation. I. Introduction LITHIUM-ION batteries

Suo, Zhigang

103

Parameter Estimation and Capacity Fade Analysis of Lithium-Ion Batteries Using Reformulated Models  

E-Print Network [OSTI]

Parameter Estimation and Capacity Fade Analysis of Lithium-Ion Batteries Using Reformulated Models and characterize capacity fade in lithium-ion batteries. As a comple- ment to approaches to mathematically model been made in developing lithium-ion battery models that incor- porate transport phenomena

Subramanian, Venkat

104

Carbonophosphates: A New Family of Cathode Materials for Li-Ion Batteries Identified Computationally  

E-Print Network [OSTI]

Carbonophosphates: A New Family of Cathode Materials for Li-Ion Batteries Identified ABSTRACT: The tremendous growth of Li-ion batteries into a wide variety of applications is setting new applications from portable electronics to electric vehicles. A critical element of a Li-ion battery is the Li

Ceder, Gerbrand

105

Electrochimica Acta 51 (2006) 20122022 A generalized cycle life model of rechargeable Li-ion batteries  

E-Print Network [OSTI]

­discharge model to simulate the cycle life behavior of rechargeable Li-ion batteries has been developed. The model and Newman [4] made a first attempt to model the parasitic reaction in Li-ion batteries by assuming a solvent and reversible capacity loss due to the growth and dissolution of SEI film in Li-ion batteries. Ramadass et al

Popov, Branko N.

106

Efficient Reformulation of Solid-Phase Diffusion in Physics-Based Lithium-Ion Battery Models  

E-Print Network [OSTI]

in the solid phase. Introduction Physics based Li-ion battery models use porous electrode theory. One and their drawbacks Porous electrode models of Li-ion batteries often use approximations to eliminate the time and disadvantages when used in Li-ion battery models. For instance, the Duhamel's superposition method is the robust

Subramanian, Venkat

107

Real-time observation of lithium fibers growth inside a nanoscale lithium-ion battery  

E-Print Network [OSTI]

to observe the real-time nucleation and growth of the lithium fibers inside a nanoscale Li-ion battery. Our needed for safe and high power Li-ion batteries. VC 2011 American Institute of Physics. [doi:10Real-time observation of lithium fibers growth inside a nanoscale lithium-ion battery Hessam

Endres. William J.

108

Short communication Enhanced autonomic shutdown of Li-ion batteries by polydopamine  

E-Print Network [OSTI]

Short communication Enhanced autonomic shutdown of Li-ion batteries by polydopamine coated Accepted 9 July 2014 Available online 17 July 2014 Keywords: Li-ion batteries Thermal shutdown Polyethylene binder, applied onto a battery anode surface, dried, and incorporated into Li-ion coin cells. FTIR

Sottos, Nancy R.

109

Non-aqueous electrolyte for lithium-ion battery  

DOE Patents [OSTI]

The present technology relates to stabilizing additives and electrolytes containing the same for use in electrochemical devices such as lithium ion batteries and capacitors. The stabilizing additives include triazinane triones and bicyclic compounds comprising succinic anhydride, such as compounds of Formulas I and II described herein.

Zhang, Lu; Zhang, Zhengcheng; Amine, Khalil

2014-04-15T23:59:59.000Z

110

Abstract--A novel, accurate, compact, and power efficient Lith-ium-Ion (Li-Ion) battery charger designed to yield maximum  

E-Print Network [OSTI]

1 Abstract-- A novel, accurate, compact, and power efficient Lith- ium-Ion (Li-Ion) battery charger battery, linear charger, switching charger. I. INTRODUCTION ITHIUM-ION (Li-Ion) batteries are widely used of Li-Ion batteries to over-charged voltages im- poses stringent charge requirements on the design

Rincon-Mora, Gabriel A.

111

Multi-layered, chemically bonded lithium-ion and lithium/air batteries  

SciTech Connect (OSTI)

Disclosed are multilayer, porous, thin-layered lithium-ion batteries that include an inorganic separator as a thin layer that is chemically bonded to surfaces of positive and negative electrode layers. Thus, in such disclosed lithium-ion batteries, the electrodes and separator are made to form non-discrete (i.e., integral) thin layers. Also disclosed are methods of fabricating integrally connected, thin, multilayer lithium batteries including lithium-ion and lithium/air batteries.

Narula, Chaitanya Kumar; Nanda, Jagjit; Bischoff, Brian L; Bhave, Ramesh R

2014-05-13T23:59:59.000Z

112

Redox shuttles for lithium ion batteries  

SciTech Connect (OSTI)

Compounds may have general Formula IVA or IVB. ##STR00001## where, R.sup.8, R.sup.9, R.sup.10, and R.sup.11 are each independently selected from H, F, Cl, Br, CN, NO.sub.2, alkyl, haloalkyl, and alkoxy groups; X and Y are each independently O, S, N, or P; and Z' is a linkage between X and Y. Such compounds may be used as redox shuttles in electrolytes for use in electrochemical cells, batteries and electronic devices.

Weng, Wei; Zhang, Zhengcheng; Amine, Khalil

2014-11-04T23:59:59.000Z

113

Sandia National Laboratories: lithium-ion battery  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the1developmentturbine blade manufacturinglife-cycleion battery Electric Car

114

Electronically conductive polymer binder for lithium-ion battery electrode  

DOE Patents [OSTI]

A family of carboxylic acid group containing fluorene/fluorenon copolymers is disclosed as binders of silicon particles in the fabrication of negative electrodes for use with lithium ion batteries. These binders enable the use of silicon as an electrode material as they significantly improve the cycle-ability of silicon by preventing electrode degradation over time. In particular, these polymers, which become conductive on first charge, bind to the silicon particles of the electrode, are flexible so as to better accommodate the expansion and contraction of the electrode during charge/discharge, and being conductive promote the flow battery current.

Liu, Gao; Xun, Shidi; Battaglia, Vincent S; Zheng, Honghe

2014-10-07T23:59:59.000Z

115

Towards the development of calcium ion batteries  

E-Print Network [OSTI]

A novel system for the study of calcium-ion electroactive materials has been developed, characterized, and utilized to screen a number of candidate calcium intercalation compounds. The system is comprised of a dried, ...

Rogosic, John

2014-01-01T23:59:59.000Z

116

Optimum Charging Profile for Lithium-ion Batteries to Maximize Energy Storage and Utilization  

E-Print Network [OSTI]

Optimum Charging Profile for Lithium-ion Batteries to Maximize Energy Storage and Utilization Ravi applications, the ability to recharge quickly and efficiently is a critical requirement for a storage battery The optimal profile of charging current for a lithium-ion battery is estimated using dynamic optimization

Subramanian, Venkat

117

Comparison of Reduced Order Lithium-Ion Battery Models for Control Applications  

E-Print Network [OSTI]

@umich.edu. automotive field, lithium-ion batteries are the core of energy source and storage. In most cases the lithium-ion battery performances play an important role for the energy efficiency of these vehicles, suffering often - 50 C over a short period of about 10 s - 20 s [9]. In order to efficiently manage the battery systems

Stefanopoulou, Anna

118

Electrochemical Lithium Harvesting from Waste Li-ion Batteries Byron M. Wolfe III1  

E-Print Network [OSTI]

Electrochemical Lithium Harvesting from Waste Li-ion Batteries Byron M. Wolfe III1 , Wen Chao Lee1 This study demonstrates the feasibility of using water and the contents of waste Li-ion batteries for the electrodes in a Li-liquid battery system. Li metal was collected electrochemically from a waste Li

Zhou, Yaoqi

119

Phosphazene Based Additives for Improvement of Safety and Battery Lifetimes in Lithium-Ion Batteries  

SciTech Connect (OSTI)

There need to be significant improvements made in lithium-ion battery technology, principally in the areas of safety and useful lifetimes to truly enable widespread adoption of large format batteries for the electrification of the light transportation fleet. In order to effect the transition to lithium ion technology in a timely fashion, one promising next step is through improvements to the electrolyte in the form of novel additives that simultaneously improve safety and useful lifetimes without impairing performance characteristics over wide temperature and cycle duty ranges. Recent efforts in our laboratory have been focused on the development of such additives with all the requisite properties enumerated above. We present the results of the study of novel phosphazene based electrolytes additives.

Mason K Harrup; Kevin L Gering; Harry W Rollins; Sergiy V Sazhin; Michael T Benson; David K Jamison; Christopher J Michelbacher

2011-10-01T23:59:59.000Z

120

Nanostructured materials for lithium-ion batteries: Surface conductivity vs. bulk  

E-Print Network [OSTI]

Nanostructured materials for lithium-ion batteries: Surface conductivity vs. bulk ion cathode materials for high capacity lithium-ion batteries. Owing to their inherently low electronic-ion batteries. Lithium transition metal phosphates such as LiFePO4,1 LiMnPO4,2 Li3V2(PO4)3 3 and LiVPO4F4 have

Ryan, Dominic

Note: This page contains sample records for the topic "ion batteries elucidated" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Lithium ion batteries with titania/graphene anodes  

DOE Patents [OSTI]

Lithium ion batteries having an anode comprising at least one graphene layer in electrical communication with titania to form a nanocomposite material, a cathode comprising a lithium olivine structure, and an electrolyte. The graphene layer has a carbon to oxygen ratio of between 15 to 1 and 500 to 1 and a surface area of between 400 and 2630 m.sup.2/g. The nanocomposite material has a specific capacity at least twice that of a titania material without graphene material at a charge/discharge rate greater than about 10 C. The olivine structure of the cathode of the lithium ion battery of the present invention is LiMPO.sub.4 where M is selected from the group consisting of Fe, Mn, Co, Ni and combinations thereof.

Liu, Jun; Choi, Daiwon; Yang, Zhenguo; Wang, Donghai; Graff, Gordon L; Nie, Zimin; Viswanathan, Vilayanur V; Zhang, Jason; Xu, Wu; Kim, Jin Yong

2013-05-28T23:59:59.000Z

122

Highly - conductive cathode for lithium-ion battery using M13 phage - SWCNT complex  

E-Print Network [OSTI]

Lithium-ion batteries are commonly used in portable electronics, and the rapid growth of mobile technology calls for an improvement in battery capabilities. Reducing the particle size of electrode materials in synthesis ...

Adams, Melanie Chantal

2013-01-01T23:59:59.000Z

123

Design of a testing device for quasi-confined compression of lithium-ion battery cells  

E-Print Network [OSTI]

The Impact and Crashworthiness Laboratory at MIT has formed a battery consortium to promote research concerning the crash characteristics of new lithium-ion battery technologies as used in automotive applications. Within ...

Roselli, Eric (Eric J.)

2011-01-01T23:59:59.000Z

124

Characterization of Electrode Materials for Lithium Ion and Sodium Ion Batteries using Synchrotron Radiation Techniques  

SciTech Connect (OSTI)

We describe the use of synchrotron X-ray absorption spectroscopy (XAS) and X-ray diffraction (XRD) techniques to probe details of intercalation/deintercalation processes in electrode materials for Li ion and Na ion batteries. Both in situ and ex situ experiments are used to understand structural behavior relevant to the operation of devices.

Mehta, Apurva; Stanford Synchrotron Radiation Lightsource; Doeff, Marca M.; Chen, Guoying; Cabana, Jordi; Richardson, Thomas J.; Mehta, Apurva; Shirpour, Mona; Duncan, Hugues; Kim, Chunjoong; Kam, Kinson C.; Conry, Thomas

2013-04-30T23:59:59.000Z

125

Ethylmethylcarbonate, a promising solvent for Li-ion rechargeable batteries  

SciTech Connect (OSTI)

Ethylmethylcarbonate (EMC) has been found to be a promising solvent for rechargeable Li-ion batteries. Graphite electrodes, which are usually sensitive to the composition of the electrolyte solution, can be successfully cycled at high reversible capacities in several Li salt solutions in this solvent (LiAsF{sub 6}, LiPF{sub 6}, etc.). These results are interesting because lithium ions cannot intercalate into graphite in diethyl carbonate solutions and cycle poorly in dimethyl carbonate solutions. To understand the high compatibility of EMC for Li-ion battery systems as compared with the other two open-chain alkyl carbonates mentioned above, the surface chemistry developed in both Li and carbon electrodes in EMC solution was studied and compared with that developed on these electrodes in other alkyl carbonate solutions. Basically, the major surface species formed on both electrodes in EMC include ROLi, ROCO{sub 2}Li, and Li{sub 2}CO{sub 3} species. The uniqueness of EMC as a battery solvent is discussed in light of these studies.

Ein-Eli, Y.; Thomas, S.R.; Koch, V. [Covalent Associates Inc., Woburn, MA (United States); Aurbach, D.; Markovsky, B.; Schechter, A. [Bar-Ilan Univ., Ramat Gan (Israel). Dept. of Chemistry

1996-12-01T23:59:59.000Z

126

Synthesis, Characterization and Performance of Cathodes for Lithium Ion Batteries  

E-Print Network [OSTI]

0 lithium batteries. J. Electrochem. Soc.for rechargeable lithium batteries. Advanced Materials 1998,for rechargeable lithium batteries. J. Electrochem. Soc.

Zhu, Jianxin

2014-01-01T23:59:59.000Z

127

Experimental Validation of a Lithium-Ion Battery State of Charge Estimation with an Extended Kalman Filter  

E-Print Network [OSTI]

], is identified and validated through experimental data by a 10 Ah li-ion battery pack, during charge 37 V at 10 Ah Li-ion battery.. Keywords: Battery model, parameter identification, Kalman filter, SOCExperimental Validation of a Lithium-Ion Battery State of Charge Estimation with an Extended Kalman

Stefanopoulou, Anna

128

Robustness analysis of State-of-Charge estimation methods for two types of Li-ion batteries  

E-Print Network [OSTI]

Robustness analysis of State-of-Charge estimation methods for two types of Li-ion batteries estimation Li-ion battery Robustness analysis a b s t r a c t Battery State of Charge (SOC) estimation. This paper analyzes the robustness of SOC estimation algorithms for two types of Li-ion batteries under

Peng, Huei

129

Identity of Passive Film Formed on Aluminum in Li-ion Battery Electrolytes with LiPF6  

E-Print Network [OSTI]

Film on Aluminum in Li-ion Battery Electrolytes with LiPFFormed on Aluminum in Li-ion Battery Electrolytes with LiPFbattery charging. From the prospective of maintaining a functioning cathode in Li-ion

Zhang, Xueyuan; Devine, T.M.

2008-01-01T23:59:59.000Z

130

Chemical Shuttle Additives in Lithium Ion Batteries  

SciTech Connect (OSTI)

The goals of this program were to discover and implement a redox shuttle that is compatible with large format lithium ion cells utilizing LiNi{sub 1/3}Mn{sub 1/3}Co{sub 1/3}O{sub 2} (NMC) cathode material and to understand the mechanism of redox shuttle action. Many redox shuttles, both commercially available and experimental, were tested and much fundamental information regarding the mechanism of redox shuttle action was discovered. In particular, studies surrounding the mechanism of the reduction of the oxidized redox shuttle at the carbon anode surface were particularly revealing. The initial redox shuttle candidate, namely 2-(pentafluorophenyl)-tetrafluoro-1,3,2-benzodioxaborole (BDB) supplied by Argonne National Laboratory (ANL, Lemont, Illinois), did not effectively protect cells containing NMC cathodes from overcharge. The ANL-RS2 redox shuttle molecule, namely 1,4-bis(2-methoxyethoxy)-2,5-di-tert-butyl-benzene, which is a derivative of the commercially successful redox shuttle 2,5-di-tert-butyl-1,4-dimethoxybenzene (DDB, 3M, St. Paul, Minnesota), is an effective redox shuttle for cells employing LiFePO{sub 4} (LFP) cathode material. The main advantage of ANL-RS2 over DDB is its larger solubility in electrolyte; however, ANL-RS2 is not as stable as DDB. This shuttle also may be effectively used to rebalance cells in strings that utilize LFP cathodes. The shuttle is compatible with both LTO and graphite anode materials although the cell with graphite degrades faster than the cell with LTO, possibly because of a reaction with the SEI layer. The degradation products of redox shuttle ANL-RS2 were positively identified. Commercially available redox shuttles Li{sub 2}B{sub 12}F{sub 12} (Air Products, Allentown, Pennsylvania and Showa Denko, Japan) and DDB were evaluated and were found to be stable and effective redox shuttles at low C-rates. The Li{sub 2}B{sub 12}F{sub 12} is suitable for lithium ion cells utilizing a high voltage cathode (potential that is higher than NMC) and the DDB is useful for lithium ion cells with LFP cathodes (potential that is lower than NMC). A 4.5 V class redox shuttle provided by Argonne National Laboratory was evaluated which provides a few cycles of overcharge protection for lithium ion cells containing NMC cathodes but it is not stable enough for consideration. Thus, a redox shuttle with an appropriate redox potential and sufficient chemical and electrochemical stability for commercial use in larger format lithium ion cells with NMC cathodes was not found. Molecular imprinting of the redox shuttle molecule during solid electrolyte interphase (SEI) layer formation likely contributes to the successful reduction of oxidized redox shuttle species at carbon anodes. This helps to understand how a carbon anode covered with an SEI layer, that is supposed to be electrically insulating, can reduce the oxidized form of a redox shuttle.

Patterson, Mary

2013-03-31T23:59:59.000Z

131

Edge-Enriched Graphitic Anodes by KOH Activation for Higher Rate Capability Lithium Ion Batteries  

E-Print Network [OSTI]

Lithium Ion Batteries D. Zakhidov,1,2 R. Sugamata,3 T. Yasue,3 T. Hayashi,3 Y. A. Kim,3 and M. Endo4 1 successful anode for lithium ion batteries due to its low cost, safety, and ease of fabrication, but higher are expected to surpass conventional graphite anodes due to larger number of edges for lithium ion

132

Studies on Capacity Fade of Spinel based Li-Ion Batteries  

E-Print Network [OSTI]

Studies on Capacity Fade of Spinel based Li-Ion Batteries by P. Ramadass , A. Durairajan, Bala S To characterize the capacity fade phenomena of Li- ion batteries. To decrease the capacity fade on both positive the change in capacity of commercially available spinel based Li-ion Cells (Cellbatt cells). Study

Popov, Branko N.

133

NREL's PHEV/EV Li-Ion Battery Secondary-Use Project  

SciTech Connect (OSTI)

Accelerated development and market penetration of plug-in hybrid electric vehicles (PHEVs) and electric vehicles (EVs) is restricted at present by the high cost of lithium-ion (Li-ion) batteries. One way to address this problem is to recover a fraction of the Li-ion battery's cost via reuse in other applications after it is retired from service in the vehicle, when the battery may still have sufficient performance to meet the requirements of other energy storage applications.

Newbauer, J.; Pesaran, A.

2010-06-01T23:59:59.000Z

134

Batteries: Overview of Battery Cathodes  

E-Print Network [OSTI]

insertion reactions. For Li-ion battery materials, it refersis widespread throughout the Li-ion battery literature, thisthe chemistry of the Li-ion battery is not fixed, unlike the

Doeff, Marca M

2011-01-01T23:59:59.000Z

135

Lithium Ion Battery Performance of Silicon Nanowires With Carbon Skin  

SciTech Connect (OSTI)

Silicon (Si) nanomaterials have emerged as a leading candidate for next generation lithium-ion battery anodes. However, the low electrical conductivity of Si requires the use of conductive additives in the anode film. Here we report a solution-based synthesis of Si nanowires with a conductive carbon skin. Without any conductive additive, the Si nanowire electrodes exhibited capacities of over 2000 mA h g-1 for 100 cycles when cycled at C/10 and over 1200 mA h g-1 when cycled more rapidly at 1C against Li metal.. In situ transmission electron microscopy (TEM) observation reveals that the carbon skin performs dual roles: it speeds lithiation of the Si nanowires significantly, while also constraining the final volume expansion. The present work sheds light on ways to optimize lithium battery performance by smartly tailoring the nanostructure of composition of materials based on silicon and carbon.

Bogart, Timothy D.; Oka, Daichi; Lu, Xiaotang; Gu, Meng; Wang, Chong M.; Korgel, Brian A.

2013-12-06T23:59:59.000Z

136

Lithium-ion batteries with intrinsic pulse overcharge protection  

DOE Patents [OSTI]

The present invention relates in general to the field of lithium rechargeable batteries, and more particularly relates to the positive electrode design of lithium-ion batteries with improved high-rate pulse overcharge protection. Thus the present invention provides electrochemical devices containing a cathode comprising at least one primary positive material and at least one secondary positive material; an anode; and a non-aqueous electrolyte comprising a redox shuttle additive; wherein the redox potential of the redox shuttle additive is greater than the redox potential of the primary positive material; the redox potential of the redox shuttle additive is lower than the redox potential of the secondary positive material; and the redox shuttle additive is stable at least up to the redox potential of the secondary positive material.

Chen, Zonghai; Amine, Khalil

2013-02-05T23:59:59.000Z

137

Modeling of Nonuniform Degradation in Large-Format Li-ion Batteries (Poster)  

SciTech Connect (OSTI)

Shows results of an empirical model capturing effects of both storage and cycling and developed the lithium ion nickel cobalt aluminum advanced battery chemistry.

Smith, K.; Kim, G. H.; Pesaran, A.

2009-06-01T23:59:59.000Z

138

Silicon sponge improves lithium-ion battery performance | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsrucLas ConchasPassiveSubmitted forHighlightsSeminarsSilicon sponge improves lithium-ion battery

139

Nanostructured ion beam-modified Ge films for high capacity Li ion battery anodes  

SciTech Connect (OSTI)

Nanostructured ion beam-modified Ge electrodes fabricated directly on Ni current collector substrates were found to exhibit excellent specific capacities during electrochemical cycling in half-cell configuration with Li metal for a wide range of cycling rates. Structural characterization revealed that the nanostructured electrodes lose porosity during cycling but maintain excellent electrical contact with the metallic current collector substrate. These results suggest that nanostructured Ge electrodes have great promise for use as high performance Li ion battery anodes.

Rudawski, N. G.; Darby, B. L.; Yates, B. R.; Jones, K. S. [Department of Materials Science and Engineering, University of Florida, Gainesville, Florida 32611-6400 (United States); Elliman, R. G. [Department of Electronic Materials Engineering, Research School of Physics and Engineering, Australian National University, Canberra, Australian Capital Territory 0200 (Australia); Volinsky, A. A. [Department of Mechanical Engineering, University of South Florida, Tampa Florida 33620 (United States)

2012-02-20T23:59:59.000Z

140

Overview of Computer-Aided Engineering of Batteries and Introduction to Multi-Scale, Multi-Dimensional Modeling of Li-Ion Batteries (Presentation)  

SciTech Connect (OSTI)

This 2012 Annual Merit Review presentation gives an overview of the Computer-Aided Engineering of Batteries (CAEBAT) project and introduces the Multi-Scale, Multi-Dimensional model for modeling lithium-ion batteries for electric vehicles.

Pesaran, A.; Kim, G. H.; Smith, K.; Santhanagopalan, S.; Lee, K. J.

2012-05-01T23:59:59.000Z

Note: This page contains sample records for the topic "ion batteries elucidated" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

An ultra-compact and efficient Li-ion battery charger circuit for biomedical applications  

E-Print Network [OSTI]

This paper describes an ultra-compact analog lithium-ion (Li-ion) battery charger for wirelessly powered implantable medical devices. The charger presented here takes advantage of the tanh output current profile of an ...

Do Valle, Bruno Guimaraes

142

Beyond Conventional Cathode Materials for Li-ion Batteries and Na-ion Batteries Nickel fluoride conversion materials and P2 type Na-ion intercalation cathodes /  

E-Print Network [OSTI]

spinel structures for lithium batteries. ElectrochemistryMaterials for Rechargeable Lithium Batteries. Journal of thefor Rechargeable Lithium Batteries. Electrochemical and

Lee, Dae Hoe

2013-01-01T23:59:59.000Z

143

Study of polypyrrole graphite composite as anode material for secondary lithium-ion batteries  

E-Print Network [OSTI]

Study of polypyrrole graphite composite as anode material for secondary lithium-ion batteries of the composite. The composite material has been studied for specific discharge capacity, coulombic efficiency for the Li-ion battery. Of various carbon materials that have been tried, graphite is favored because it (i

Popov, Branko N.

144

Paper-Based Lithium-Ion Battery Nojan Aliahmad, Mangilal Agarwal, Sudhir Shrestha, and Kody Varahramyan  

E-Print Network [OSTI]

Paper-Based Lithium-Ion Battery Nojan Aliahmad, Mangilal Agarwal, Sudhir Shrestha, and Kody Indianapolis (IUPUI), Indianapolis, IN 46202 Lithium-ion batteries have a wide range of applications including devices. Lithium titanium oxide (Li4Ti5O12), lithium magnesium oxide (LiMn2O4) and lithium cobalt oxide

Zhou, Yaoqi

145

Efficient Reformulation of Solid-Phase Diffusion in Physics-Based Lithium-Ion Battery Models  

E-Print Network [OSTI]

Efficient Reformulation of Solid-Phase Diffusion in Physics-Based Lithium-Ion Battery Models or approximation for the solid phase. One of the major difficulties in simulating Li-ion battery models is the need typically solve electrolyte con- centration, electrolyte potential, solid-state potential, and solid-state

Subramanian, Venkat

146

Mathematical Model Reformulation for Lithium-Ion Battery Simulations: Galvanostatic Boundary Conditions  

E-Print Network [OSTI]

-ion battery which has been converted to a one-dimensional 1D model using approxi- mations for solid-state listed elsewhere Electrochem. Solid-State Lett., 10, A225 2007 can be carried out to expedite of charge, state of health, and other parameters of lithium-ion batteries in millisec- onds. Rigorous

Subramanian, Venkat

147

Impedance Analysis of Silicon Nanowire Lithium Ion Battery Anodes Riccardo Ruffo,  

E-Print Network [OSTI]

resistance and solid state diffusion through the bulk of the nanowires. The surface process is dominatedImpedance Analysis of Silicon Nanowire Lithium Ion Battery Anodes Riccardo Ruffo, Seung Sae Hong as a high-capacity anode in a lithium ion battery. The ac response was measured by using impedance

Cui, Yi

148

Diagnostic Characterization of High-Power Lithium-Ion Batteries For Use in Hybrid Electric Vehicles  

E-Print Network [OSTI]

Diagnostic Characterization of High-Power Lithium-Ion Batteries For Use in Hybrid Electric Vehicles and electric vehicles due to their relatively high specific energy and specific power. The Advanced Technology of lithium-ion batteries for hybrid electric vehicle (HEV) applications. The ATD Program is a joint effort

149

Crumpled Graphene-Encapsulated Si Nanoparticles for Lithium Ion Battery Anodes  

E-Print Network [OSTI]

efficiency. SECTION: Energy Conversion and Storage; Energy and Charge Transport Silicon is a promising highCrumpled Graphene-Encapsulated Si Nanoparticles for Lithium Ion Battery Anodes Jiayan Luo, Xin Zhao improved performance as Li ion battery anodes in terms of capacity, cycling stability, and Coulombic

Huang, Jiaxing

150

Synthesis and Electrochemical Performance of a Lithium Titanium Phosphate Anode for Aqueous Lithium-Ion Batteries  

E-Print Network [OSTI]

on larger scales. Im- provement of the safety of lithium-ion batteries must occur if they are to be utilized in aqueous cells. However, the choice of a suitable anode material for an aqueous lithium-ion battery is moreSynthesis and Electrochemical Performance of a Lithium Titanium Phosphate Anode for Aqueous Lithium

Cui, Yi

151

Fracture and debonding in lithium-ion batteries with electrodes of hollow coreeshell nanostructures  

E-Print Network [OSTI]

. In particular, silicon anodes of such coreeshell nano- structures have been cycled thousands of times failure modes in a coated-hollow electrode particle. -ion batteries Fracture Debonding Silicon a b s t r a c t In a novel design of lithium-ion batteries, hollow

Suo, Zhigang

152

UV and EB Curable Binder Technology for Lithium Ion Batteries and UltraCapacitors  

SciTech Connect (OSTI)

the basic feasibility of using UV curing technology to produce Lithium ion battery electrodes at speeds over 200 feet per minute has been shown. A unique set of UV curable chemicals were discovered that were proven to be compatible with a Lithium ion battery environment with the adhesion qualities of PVDF.

Voelker, Gary

2012-04-30T23:59:59.000Z

153

Stochastic Simulation Model for the 3D Morphology of Composite Materials in Li-Ion Batteries  

E-Print Network [OSTI]

Stochastic Simulation Model for the 3D Morphology of Composite Materials in Li-Ion Batteries Ralf of composite materials used in Li-ion batteries. In this paper, we develop a stochastic simulation model in 3D, Stochastic Simulation Model, Structural Analysis, Marked Point Process, Germ-Grain Model, Model Fitting

Schmidt, Volker

154

Implementations of electric vehicle system based on solar energy in Singapore assessment of lithium ion batteries for automobiles  

E-Print Network [OSTI]

In this thesis report, both quantitative and qualitative approaches are used to provide a comprehensive analysis of lithium ion (Li-ion) batteries for plug-in hybrid electric vehicle (PHEV) and battery electric vehicle ...

Fu, Haitao

2009-01-01T23:59:59.000Z

155

Addressing the Impact of Temperature Extremes on Large Format Li-Ion Batteries for Vehicle Applications (Presentation)  

SciTech Connect (OSTI)

This presentation discusses the effects of temperature on large format lithium-ion batteries in electric drive vehicles.

Pesaran, A.; Santhanagopalan, S.; Kim, G. H.

2013-05-01T23:59:59.000Z

156

Prediction of Multi-Physics Behaviors of Large Lithium-Ion Batteries During Internal and External Short Circuit (Presentation)  

SciTech Connect (OSTI)

This presentation describes the multi-physics behaviors of internal and external short circuits in large lithium-ion batteries.

Kim, G. H.; Lee, K. J.; Chaney, L.; Smith, K.; Darcy, E.; Pesaran, A.; Darcy, E.

2010-11-01T23:59:59.000Z

157

A robust state-of-charge estimator for multiple types of lithium-ion batteries using adaptive extended Kalman filter  

E-Print Network [OSTI]

A robust state-of-charge estimator for multiple types of lithium-ion batteries using adaptive a SOC estimator for suitable for multiple lithium ion battery chemistries. Proved the system robustness of charge (SoC) of multiple types of lithium ion battery (LiB) cells with adaptive extended Kalman filter

Mi, Chunting "Chris"

158

Kinetic Monte Carlo Simulation of Surface Heterogeneity in Graphite Anodes for Lithium-Ion Batteries: Passive Layer  

E-Print Network [OSTI]

, but was lower at later cycles. The temperature that optimizes the active surface in a lithium-ion battery. Published February 14, 2011. Rechargeable lithium-ion batteries have been extensively used in mobile-discharge rate. The lithium-ion battery is also promising for electric (plug-in and hybrid) vehicles

Subramanian, Venkat

159

Capacity fade study of lithium-ion batteries cycled at high discharge rates Gang Ning, Bala Haran, Branko N. Popov*  

E-Print Network [OSTI]

Capacity fade study of lithium-ion batteries cycled at high discharge rates Gang Ning, Bala Haran at high discharge rates. # 2003 Elsevier Science B.V. All rights reserved. Keywords: Lithium-ion batteries collectors can affect up to different degrees the capacity fade of lithium-ion batteries [1­5]. Quantifying

Popov, Branko N.

160

Cycle-Life Characterization of Automotive Lithium-Ion Batteries with LiNiO2 Cathode  

E-Print Network [OSTI]

Cycle-Life Characterization of Automotive Lithium-Ion Batteries with LiNiO2 Cathode Yancheng Zhang of lithium- ion batteries for electric vehicles EVs and hybrid EVs HEVs . Substantial research has been- face, which is critical to the cycle life and calendar life of lithium- ion batteries.1,2 Unfortunately

Note: This page contains sample records for the topic "ion batteries elucidated" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Parameter Estimation and Capacity Fade Analysis of Lithium-Ion Batteries Using First-Principles-Based Efficient Reformulated Models  

E-Print Network [OSTI]

Parameter Estimation and Capacity Fade Analysis of Lithium-Ion Batteries Using First parameters of lithium-ion batteries are estimated using a first-principles electrochemical engineering model and understanding of lithium-ion batteries using physics-based first-principles models. These models are based

Subramanian, Venkat

162

Model-based simultaneous optimization of multiple design parameters for lithium-ion batteries for maximization of energy density  

E-Print Network [OSTI]

Model-based simultaneous optimization of multiple design parameters for lithium-ion batteries Keywords: Lithium-ion batteries Model-based design Optimization Physics based reformulated model a b s t r for porous electrodes that are commonly used in advanced batteries such as lithium-ion systems. The approach

Subramanian, Venkat

163

Cyclic plasticity and shakedown in high-capacity electrodes of lithium-ion batteries Laurence Brassart, Kejie Zhao, Zhigang Suo  

E-Print Network [OSTI]

Cyclic plasticity and shakedown in high-capacity electrodes of lithium-ion batteries Laurence for lithium-ion batteries. Upon absorbing a large amount of lithium, the electrode swells greatly rights reserved. 1. Introduction Rechargeable lithium-ion batteries are energy-storage systems of choice

Suo, Zhigang

164

Nonequilibrium Phase Transformation and Particle Shape Effect in LiFePO4 Materials for Li-Ion Batteries  

E-Print Network [OSTI]

-induced nonequilibrium phenomenon in Li-ion batteries. A theoretical anal- ysis is presented to show for Li-ion batteries as power sources in transporta- tion and future energy landscape requires transformaiton in Li ion batteries, especially on meta- stable miscibility gap distortion and discharge behaviors

Liu, Fuqiang

165

A Yolk-Shell Design for Stabilized and Scalable Li-Ion Battery Alloy Matthew T. McDowell,  

E-Print Network [OSTI]

A Yolk-Shell Design for Stabilized and Scalable Li-Ion Battery Alloy Anodes Nian Liu,, Hui Wu nanoparticle, Li-ion battery, anode, yolk-shell, solid-electrolyte interphase, in situ TEM Electrochemical anode that is currently used in Li-ion batteries.2 Among all the alloy anodes, silicon has the highest

Cui, Yi

166

A Simplified Electrochemical and Thermal Aging Model of LiFePO4-Graphite Li-ion Batteries  

E-Print Network [OSTI]

1 A Simplified Electrochemical and Thermal Aging Model of LiFePO4-Graphite Li-ion Batteries: Power of a commercial LiFePO4-graphite Li-ion battery. Compared to the isothermal reference, the mechanism of porosity;2 Due to their high power and energy densities, Li-ion technologies are the leading battery systems

167

Figure 1. Schematic drawing showing the components of a Li-ion battery cell and the information that can be  

E-Print Network [OSTI]

Figure 1. Schematic drawing showing the components of a Li-ion battery cell and the information Proposals In Situ Electron Microscopy and Spectroscopy Studies of Interfaces in Advanced Li-ion Batteries) such as Li-ion batteries are complex multi- component systems that incorporate widely dissimilar phases

168

Microstructure Reconstruction and Direct Evaluation of Li-Ion Battery Cathodes Fuqiang Liu* and N A Siddique  

E-Print Network [OSTI]

Microstructure Reconstruction and Direct Evaluation of Li-Ion Battery Cathodes Fuqiang Liu* and N of Texas at Arlington, Arlington, Texas 76019, USA High-capacity Li-ion batteries are among the best of the major challenges in Li-ion batteries is to improve mass transport across multiple phase interfaces

Liu, Fuqiang

169

Simplified Electrochemical and Thermal Model of LiFePO4-Graphite Li-Ion Batteries for Fast Charge Applications  

E-Print Network [OSTI]

Simplified Electrochemical and Thermal Model of LiFePO4- Graphite Li-Ion Batteries for Fast Charge, a simplified electrochemical and thermal model of LiFePO4-graphite based Li-ion batteries is developed : 10.1149/2.064209jes #12;Over the past 15 years, Li-ion batteries have received much attention

Paris-Sud XI, Université de

170

Adaptation of an Electrochemistry-based Li-Ion Battery Model to Account for Deterioration Observed Under Randomized Use  

E-Print Network [OSTI]

Adaptation of an Electrochemistry-based Li-Ion Battery Model to Account for Deterioration Observed). In this paper, we use an electrochemistry-based lithium ion (Li-ion) battery model developed in (Daigle, Moffett Field, CA 94035 matthew.j.daigle@nasa.gov ABSTRACT Tracking the variation in battery dynamics

Daigle, Matthew

171

The Effect of Single Walled Carbon Nanotubes on Lithium-Ion Batteries and Electric Double Layer Capacitors  

E-Print Network [OSTI]

into the anode of the Li-ion battery and the electrodes of the EDLC to observe the effects it would have and resistance of the EDLC. If the use of SWNT also improves these devices, it would be evidence that Li-ion batteries and EDLCs are excellent options for more efficient commercial energy storage. Li-ion batteries

Mellor-Crummey, John

172

Integrated Lithium-Ion Battery Model Encompassing Multi-Physics in Varied Scales: An Integrated Computer Simulation Tool for Design and Development of EDV Batteries (Presentation)  

SciTech Connect (OSTI)

This presentation discusses the physics of lithium-ion battery systems in different length scales, from atomic scale to system scale.

Kim, G. H.; Smith, K.; Lee, K. J.; Santhanagopalan, S.; Pesaran, A.

2011-01-01T23:59:59.000Z

173

Models for Battery Reliability and Lifetime  

SciTech Connect (OSTI)

Models describing battery degradation physics are needed to more accurately understand how battery usage and next-generation battery designs can be optimized for performance and lifetime. Such lifetime models may also reduce the cost of battery aging experiments and shorten the time required to validate battery lifetime. Models for chemical degradation and mechanical stress are reviewed. Experimental analysis of aging data from a commercial iron-phosphate lithium-ion (Li-ion) cell elucidates the relative importance of several mechanical stress-induced degradation mechanisms.

Smith, K.; Wood, E.; Santhanagopalan, S.; Kim, G. H.; Neubauer, J.; Pesaran, A.

2014-03-01T23:59:59.000Z

174

Graphite Foams for Lithium-Ion Battery Current Collectors  

SciTech Connect (OSTI)

Graphite open-cell foams, with their very high electronic and thermal conductivities, may serve as high surface area and corrosion resistant current collectors for lithium-ion batteries. As a proof of principle, cathodes were prepared by sintering carbon-coated LiFePO4 particles into the porous graphite foams. Cycling these cathodes in a liquid electrolyte cell showed promising performance even for materials and coatings that have not been optimized. The specific capacity is not limited by the foam structure, but by the cycling performance of the coated LiFePO4 particles. Upon extended cycling for more than 100 deep cycles, no loss of capacity is observed for rates of C/2 or less. The uncoated graphite foams will slowly intercalate lithium reversibly at potentials less than 0.2 volts versus lithium.

Dudney, Nancy J [ORNL; Tiegs, Terry N [ORNL; Kiggans, Jim [ORNL; Jang, Young-Il [ORNL; Klett, James William [ORNL

2007-01-01T23:59:59.000Z

175

Improving the Performance of Lithium Ion Batteries at Low Temperature  

SciTech Connect (OSTI)

The ability for Li-ion batteries to operate at low temperatures is extremely critical for the development of energy storage for electric and hybrid electric vehicle technologies. Currently, Li-ion cells have limited success in operating at temperature below –10 deg C. Electrolyte conductivity at low temperature is not the main cause of the poor performance of Li-ion cells. Rather the formation of a tight interfacial film between the electrolyte and the electrodes has often been an issue that resulted in a progressive capacity fading and limited discharge rate capability. The objective of our Phase I work is to develop novel electrolytes that can form low interfacial resistance solid electrolyte interface (SEI) films on carbon anodes and metal oxide cathodes. From the results of our Phase I work, we found that the interfacial impedance of Fluoro Ethylene Carbonate (FEC) electrolyte at the low temperature of –20degC is astonishingly low, compared to the baseline 1.2M LiPFEMC:EC:PC:DMC (10:20:10:60) electrolyte. We found that electrolyte formulations with fluorinated carbonate co-solvent have excellent film forming properties and better de-solvation characteristics to decrease the interfacial SEI film resistance and facilitate the Li-ion diffusion across the SEI film. The very overwhelming low interfacial impedance for FEC electrolytes will translate into Li-ion cells with much higher power for cold cranking and high Regen/charge at the low temperature. Further, since the SEI film resistance is low, Li interaction kinetics into the electrode will remain very fast and thus Li plating during Regen/charge period be will less likely to happen.

Trung H. Nguyen; Peter Marren; Kevin Gering

2007-04-20T23:59:59.000Z

176

SISGR: Linking Ion Solvation and Lithium Battery Electrolyte Properties  

SciTech Connect (OSTI)

The solvation and phase behavior of the model battery electrolyte salt lithium trifluoromethanesulfonate (LiCF3SO3) in commonly used organic solvents; ethylene carbonate (EC), gamma-butyrolactone (GBL), and propylene carbonate (PC) was explored. Data from differential scanning calorimetry (DSC), Raman spectroscopy, and X-ray diffraction were correlated to provide insight into the solvation states present within a sample mixture. Data from DSC analyses allowed the construction of phase diagrams for each solvent system. Raman spectroscopy enabled the determination of specific solvation states present within a solvent-Ã?Â?Ã?Â?salt mixture, and X-ray diffraction data provided exact information concerning the structure of a solvates that could be isolated Thermal analysis of the various solvent-salt mixtures revealed the phase behavior of the model electrolytes was strongly dependent on solvent symmetry. The point groups of the solvents were (in order from high to low symmetry): C2V for EC, CS for GBL, and C1 for PC(R). The low symmetry solvents exhibited a crystallinity gap that increased as solvent symmetry decreased; no gap was observed for EC-LiTf, while a crystallinity gap was observed spanning 0.15 to 0.3 mole fraction for GBL-LiTf, and 0.1 to 0.33 mole fraction for PC(R)-LiTf mixtures. Raman analysis demonstrated the dominance of aggregated species in almost all solvent compositions. The AGG and CIP solvates represent the majority of the species in solutions for the more concentrated mixtures, and only in very dilute compositions does the SSIP solvate exist in significant amounts. Thus, the poor charge transport characteristics of CIP and AGG account for the low conductivity and transport properties of LiTf and explain why is a poor choice as a source of Li+ ions in a Li-ion battery.

Trulove, Paul C; Foley, Matthew P

2013-03-14T23:59:59.000Z

177

Elastic modulus mapping of atomically thin film based Lithium Ion Battery electrodes Lithium Ion Batteries (LIB) are one of the most promising class of next generation energy storage devices,  

E-Print Network [OSTI]

Batteries (LIB) are one of the most promising class of next generation energy storage devices, which canElastic modulus mapping of atomically thin film based Lithium Ion Battery electrodes Lithium Ion the charging/discharging which otherwise lead to in efficient battery operation. The cyclically charging

178

batteries | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

batteries batteries Leads No leads are available at this time. Magnesium behavior and structural defects in Mg+ ion implanted silicon carbide. Abstract: As a candidate material for...

179

Control oriented 1D electrochemical model of lithium ion battery Kandler A. Smith a  

E-Print Network [OSTI]

dynamics (i.e. state of charge). � 2007 Elsevier Ltd. All rights reserved. Keywords: Lithium ion battery electrochemical system dynamics [3,4]. Empirical battery models are often favored for their low order (2­5 states and Wang show that a hybrid electric vehicle (HEV) cell may become solid state diffusion limited in sec

180

Lithium-Ion battery State of Charge estimation with a Kalman Filter based on a electrochemical model  

E-Print Network [OSTI]

Lithium-Ion battery State of Charge estimation with a Kalman Filter based on a electrochemical state of charge (SOC). In this paper an averaged electrochemical Lithium-ion battery model suitable-Volmer current and the solid concentration at the interface with the electrolyte and (ii) the battery current

Stefanopoulou, Anna

Note: This page contains sample records for the topic "ion batteries elucidated" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

High-Capacity Micrometer-Sized Li2S Particles as Cathode Materials for Advanced Rechargeable Lithium-Ion Batteries  

E-Print Network [OSTI]

Lithium-Ion Batteries Yuan Yang, Guangyuan Zheng, Sumohan Misra,§ Johanna Nelson,§ Michael F. Toney for lithium metal-free rechargeable batteries. It has a theoretical capacity of 1166 mAh/g, which is nearly 1 as the cathode material for rechargeable lithium-ion batteries with high specific energy. INTRODUCTION

Cui, Yi

182

Applied Surface Science 266 (2013) 516 Interphase chemistry of Si electrodes used as anodes in Li-ion batteries  

E-Print Network [OSTI]

in Li-ion batteries Catarina Pereira-Nabaisa,b , Jolanta S´wiatowskaa, , Alexandre Chagnesb, , Franc made to increase the energy density of lithium-ion batteries (LiB), namely for electric vehicle applications. One way to improve the energy density of a battery is to use high specific capacity materials, e

Boyer, Edmond

183

EA-1690: A123 Systems, Inc., Automotive-Class Lithium-Ion Battery...  

Broader source: Energy.gov (indexed) [DOE]

to A123 Systems, Inc., for Vertically Integrated Mass Production of Automotive-Class Lithium-Ion Batteries April 20, 2010 EA-1690: Finding of No Significant Impact A123 Systems,...

184

NREL Enhances the Performance of a Lithium-Ion Battery Cathode (Fact Sheet)  

SciTech Connect (OSTI)

Scientists from NREL and the University of Toledo have combined theoretical and experimental studies to demonstrate a promising approach to significantly enhance the performance of lithium iron phosphate (LiFePO4) cathodes for lithium-ion batteries.

Not Available

2012-10-01T23:59:59.000Z

185

Development of a representative volume element of lithium-ion batteries for thermo-mechanical integrity  

E-Print Network [OSTI]

The importance of Lithium-ion batteries continues to grow with the introduction of more electronic devices, electric cars, and energy storage. Yet the optimization approach taken by the manufacturers and system designers ...

Hill, Richard Lee, Sr

2011-01-01T23:59:59.000Z

186

A layered sodium titanate as promising anode material for sodium ion batteries  

E-Print Network [OSTI]

Sodium ion batteries have recently received great attention for large-scale energy applications because of the abundance and low cost of sodium source. Although some cathode materials with desirable electrochemical properties ...

Wu, Di, S.M. Massachusetts Institute of Technology

2014-01-01T23:59:59.000Z

187

Second-Use Li-Ion Batteries to Aid Automotive and Utility Industries (Fact Sheet)  

SciTech Connect (OSTI)

Repurposing Li-ion batteries at the end of useful life in electric drive vehicles could eliminate owners' disposal concerns and offer low-cost energy storage for certain applications.

Not Available

2014-01-01T23:59:59.000Z

188

Ab initio screening of lithium diffusion rates in transition metal oxide cathodes for lithium ion batteries  

E-Print Network [OSTI]

A screening metric for diffusion limitations in lithium ion battery cathodes is derived using transition state theory and common materials properties. The metric relies on net activation barrier for lithium diffusion. ...

Moore, Charles J. (Charles Jacob)

2012-01-01T23:59:59.000Z

189

Amorphous Metallic Glass as New High Power and Energy Density Anodes For Lithium Ion Rechargeable Batteries  

E-Print Network [OSTI]

We have investigated the use of aluminum based amorphous metallic glass as the anode in lithium ion rechargeable batteries. Amorphous metallic glasses have no long-range ordered microstructure; the atoms are less closely ...

Meng, Shirley Y.

190

Parameter Estimation and Capacity Fade Analysis of Lithium-Ion Batteries Using Reformulated Models  

E-Print Network [OSTI]

Many researchers have worked to develop methods to analyze and characterize capacity fade in lithium-ion batteries. As a complement to approaches to mathematically model capacity fade that require detailed understanding ...

Braatz, Richard D.

191

Microstructural effects on capacity-rate performance of vanadium oxide cathodes in lithium-ion batteries  

E-Print Network [OSTI]

Vanadium oxide thin film cathodes were analyzed to determine whether smaller average grain size and/or a narrower average grain size distribution affects the capacity-rate performance in lithium-ion batteries. Vanadium ...

Davis, Robin M. (Robin Manes)

2005-01-01T23:59:59.000Z

192

Investigation on Aluminum-Based Amorphous Metallic Glass as New Anode Material in Lithium Ion Batteries  

E-Print Network [OSTI]

Aluminum based amorphous metallic glass powders were produced and tested as the anode materials for the lithium ion rechargeable batteries. Ground Al??Ni₁?La₁? was found to have a ...

Meng, Shirley Y.

193

Material characterization of high-voltage lithium-ion battery models for crashworthiness analysis  

E-Print Network [OSTI]

A three-phased study of the material properties and post-impact behavior of prismatic pouch lithium-ion battery cells was conducted to refine computational finite element models and explore the mechanisms of thermal runaway ...

Meier, Joseph D. (Joseph David)

2013-01-01T23:59:59.000Z

194

Development of a constitutive model predicting the point of short-circuit within lithium-ion battery cells  

E-Print Network [OSTI]

The use of Lithium Ion batteries continues to grow in electronic devices, the automotive industry in hybrid and electric vehicles, as well as marine applications. Such batteries are the current best for these applications ...

Campbell, John Earl, Jr

2012-01-01T23:59:59.000Z

195

1020 IEEE TRANSACTIONS ON VEHICULAR TECHNOLOGY, VOL. 62, NO. 3, MARCH 2013 State of Charge Estimation of Lithium-Ion Batteries  

E-Print Network [OSTI]

Estimation of Lithium-Ion Batteries in Electric Drive Vehicles Using Extended Kalman Filtering Zheng Chen. Index Terms--Extended Kalman filter (EKF), hardware-in- the-loop, lithium-ion battery, nonlinear battery], a modeling approach for the scale-up of a lithium- ion polymer battery (LIPB) is reported. A comparison

Mi, Chunting "Chris"

196

Quadruple Adaptive Observer of the Core Temperature in Cylindrical Li-ion Batteries and their Health Monitoring  

E-Print Network [OSTI]

Quadruple Adaptive Observer of the Core Temperature in Cylindrical Li-ion Batteries to an effective thermal management system and to maintain safety, performance, and longevity of these Li-Ion. Dyche Anderson Abstract-- Temperature monitoring is a critical issue for lithium ion batteries. Since

Stefanopoulou, Anna

197

Thermal characteristics of air flow cooling in the lithium ion batteries experimental chamber  

SciTech Connect (OSTI)

A battery pack prototype has been designed and built to evaluate various air cooling concepts for the thermal management of Li-ion batteries. The heat generation from the Li-Ion batteries was simulated with electrical heat generation devices with the same dimensions as the Li-Ion battery (200 mm x 150 mm x 12 mm). Each battery simulator generates up to 15W of heat. There are 20 temperature probes placed uniformly on the surface of the battery simulator, which can measure temperatures in the range from -40 C to +120 C. The prototype for the pack has up to 100 battery simulators and temperature probes are recorder using a PC based DAQ system. We can measure the average surface temperature of the simulator, temperature distribution on each surface and temperature distributions in the pack. The pack which holds the battery simulators is built as a crate, with adjustable gap (varies from 2mm to 5mm) between the simulators for air flow channel studies. The total system flow rate and the inlet flow temperature are controlled during the test. The cooling channel with various heat transfer enhancing devices can be installed between the simulators to investigate the cooling performance. The prototype was designed to configure the number of cooling channels from one to hundred Li-ion battery simulators. The pack is thermally isolated which prevents heat transfer from the pack to the surroundings. The flow device can provide the air flow rate in the gap of up to 5m/s velocity and air temperature in the range from -30 C to +50 C. Test results are compared with computational modeling of the test configurations. The present test set up will be used for future tests for developing and validating new cooling concepts such as surface conditions or heat pipes.

Lukhanin A.; Rohatgi U.; Belyaev, A.; Fedorchenko, D.; Khazhmuradov, M.; Lukhanin, O; Rudychev, I.

2012-07-08T23:59:59.000Z

198

Developments in lithium-ion battery technology in the Peoples Republic of China.  

SciTech Connect (OSTI)

Argonne National Laboratory prepared this report, under the sponsorship of the Office of Vehicle Technologies (OVT) of the U.S. Department of Energy's (DOE's) Office of Energy Efficiency and Renewable Energy, for the Vehicles Technologies Team. The information in the report is based on the author's visit to Beijing; Tianjin; and Shanghai, China, to meet with representatives from several organizations (listed in Appendix A) developing and manufacturing lithium-ion battery technology for cell phones and electronics, electric bikes, and electric and hybrid vehicle applications. The purpose of the visit was to assess the status of lithium-ion battery technology in China and to determine if lithium-ion batteries produced in China are available for benchmarking in the United States. With benchmarking, DOE and the U.S. battery development industry would be able to understand the status of the battery technology, which would enable the industry to formulate a long-term research and development program. This report also describes the state of lithium-ion battery technology in the United States, provides information on joint ventures, and includes information on government incentives and policies in the Peoples Republic of China (PRC).

Patil, P. G.; Energy Systems

2008-02-28T23:59:59.000Z

199

Computer-Aided Engineering of Batteries for Designing Better Li-Ion Batteries (Presentation)  

SciTech Connect (OSTI)

This presentation describes the current status of the DOE's Energy Storage R and D program, including modeling and design tools and the Computer-Aided Engineering for Automotive Batteries (CAEBAT) program.

Pesaran, A.; Kim, G. H.; Smith, K.; Lee, K. J.; Santhanagopalan, S.

2012-02-01T23:59:59.000Z

200

Lithium-ion battery diagnostic and prognostic techniques  

DOE Patents [OSTI]

Embodiments provide a method and a system for determining cell imbalance condition of a multi-cell battery including a plurality of cell strings. To determine a cell imbalance condition, a charge current is applied to the battery and is monitored during charging. The charging time for each cell string is determined based on the monitor of the charge current. A charge time difference of any two cell strings in the battery is used to determine the cell imbalance condition by comparing with a predetermined acceptable charge time difference for the cell strings.

Singh, Harmohan N.

2009-11-03T23:59:59.000Z

Note: This page contains sample records for the topic "ion batteries elucidated" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Block copolymer with simultaneous electric and ionic conduction for use in lithium ion batteries  

DOE Patents [OSTI]

Redox reactions that occur at the electrodes of batteries require transport of both ions and electrons to the active centers. Reported is the synthesis of a block copolymer that exhibits simultaneous electronic and ionic conduction. A combination of Grignard metathesis polymerization and click reaction was used successively to synthesize the block copolymer containing regioregular poly(3-hexylthiophene) (P3HT) and poly(ethylene oxide) (PEO) segments. The P3HT-PEO/LiTFSI mixture was then used to make a lithium battery cathode with LiFePO.sub.4 as the only other component. All-solid lithium batteries of the cathode described above, a solid electrolyte and a lithium foil as the anode showed capacities within experimental error of the theoretical capacity of the battery. The ability of P3HT-PEO to serve all of the transport and binding functions required in a lithium battery electrode is thus demonstrated.

2013-10-08T23:59:59.000Z

202

Analysis of Impedance Response in Lithium-ion Battery Electrodes  

E-Print Network [OSTI]

A major amount of degradation in battery life is in the form of chemical degradation due to the formation of Solid Electrolyte Interface (SEI) which is a passive film resulting from chemical reaction. Mechanical degradation in the form of fracture...

Cho, Seongkoo

2013-12-04T23:59:59.000Z

203

The lithium-ion battery industry for electric vehicles  

E-Print Network [OSTI]

Electric vehicles have reemerged as a viable alternative means of transportation, driven by energy security concerns, pressures to mitigate climate change, and soaring energy demand. The battery component will play a key ...

Kassatly, Sherif (Sherif Nabil)

2010-01-01T23:59:59.000Z

204

Graphene-oxide-coated LiNi0.5Mn1.5O4 as high voltage cathode for lithium ion batteries with high energy  

E-Print Network [OSTI]

Graphene-oxide-coated LiNi0.5Mn1.5O4 as high voltage cathode for lithium ion batteries with high Since Sony rst commercialized lithium ion batteries in the early 1990s, the market for lithium ion of the great success of lithium ion battery technology developed for portable electronic devices, higher

Zhou, Chongwu

205

In-situ Investigation of Vanadium Ion Transport in Redox Flow Battery  

SciTech Connect (OSTI)

We will show a new method to differentiate the vanadium transport from concentration gradient and that from electric field. Flow batteries with vanadium and iron redox couples as the electro-active species were employed to investigate the transport behavior of vanadium ions in the presence of electric field. It was shown that electric field accelerated the positive-to-negative and reduced the negative-to-positive vanadium ions transport in charge process and affected the vanadium ions transport in an opposite way in discharge process. In addition, a method was designed to differentiate the concentration gradient-driven vanadium ions diffusion and electric field-driven vanadium ions migration. Simplified mathematical model was established to simulate the vanadium ions transport in real charge-discharge operation of flow battery. The concentration gradient diffusion coefficients and electric-migration coefficients of V2+, V3+, VO2+, and VO2+ across Nafion membrane were obtained by fitting the experimental data.

Luo, Qingtao; Li, Liyu; Nie, Zimin; Wang, Wei; Wei, Xiaoliang; Li, Bin; Chen, Baowei; Yang, Zhenguo

2012-06-27T23:59:59.000Z

206

Probing the Failure Mechanism of SnO2 Nanowires for Sodium-ion Batteries  

SciTech Connect (OSTI)

Non-lithium metals such as sodium have attracted wide attention as a potential charge carrying ion for rechargeable batteries, performing the same role as lithium in lithium- ion batteries. As sodium and lithium have the same +1 charge, it is assumed that what has been learnt about the operation of lithium ion batteries can be transferred directly to sodium batteries. Using in-situ TEM, in combination with DFT calculations, we probed the structural and chemical evolution of SnO2 nanowire anodes in Na-ion batteries and compared them quantitatively with results from Li-ion batteries [Science 330 (2010) 1515]. Upon Na insertion into SnO2, a displacement reaction occurs, leading to the formation of amorphous NaxSn nanoparticles covered by crystalline Na2O shell. With further Na insertion, the NaxSn core crystallized into Na15Sn4 (x=3.75). Upon extraction of Na (desodiation), the NaxSn core transforms to Sn nanoparticles. Associated with a volume shrinkage, nanopores appear and metallic Sn particles are confined in hollow shells of Na2O, mimicking a peapod structure. These pores greatly increase electrical impedance, therefore naturally accounting for the poor cyclability of SnO2. DFT calculations indicate that Na+ diffuses 30 times slower than Li+ in SnO2, in agreement with in-situ TEM measurement. Insertion of Na can chemo-mechanically soften the reaction product to greater extent than in lithiation. Therefore, in contrast to the lithiation of SnO2, no dislocation plasticity was seen ahead of the sodiation front. This direct comparison of the results from Na and Li highlights the critical role of ionic size and electronic structure of different ionic species on the charge/discharge rate and failure mechanisms in these batteries.

Gu, Meng; Kushima, Akihiro; Shao, Yuyan; Zhang, Jiguang; Liu, Jun; Browning, Nigel D.; Li, Ju; Wang, Chong M.

2013-09-30T23:59:59.000Z

207

Effect of flame-retarding additives on surface chemistry in Li-ion batteries  

SciTech Connect (OSTI)

This study examined the properties of 1 wt.% vinylene carbonate (VC), vinyl ethylene carbonate (VEC), and diphenyl octyl phosphate (DPOF) additive electrolytes as a promising way of beneficially improving the surface and cell resistance of Li-ion batteries. Surface film formation on the negative and positive electrodes was analyzed by electrochemical impedance spectroscopy (EIS), Fourier transform infrared (FT-IR) spectroscopy, and scanning electron microscopy (SEM). In conclusion, EIS, FT-IR spectroscopy and SEM results confirmed that DPOF is an excellent additive to the electrolyte in the Li-ion batteries due to the improved co-intercalation of the solvent molecules.

Nam, N.D.; Park, I.J. [Department of Advanced Materials Science and Engineering, Sungkyunkwan University, 300 Chunchun-Dong, Jangan-Gu, Suwon 440-746 (Korea, Republic of)] [Department of Advanced Materials Science and Engineering, Sungkyunkwan University, 300 Chunchun-Dong, Jangan-Gu, Suwon 440-746 (Korea, Republic of); Kim, J.G., E-mail: kimjg@skku.ac.kr [Department of Advanced Materials Science and Engineering, Sungkyunkwan University, 300 Chunchun-Dong, Jangan-Gu, Suwon 440-746 (Korea, Republic of); Kim, H.S. [Battery Research Group, Korea Electrotechnology Research Institute, Changwon 641-120 (Korea, Republic of)] [Battery Research Group, Korea Electrotechnology Research Institute, Changwon 641-120 (Korea, Republic of)

2012-10-15T23:59:59.000Z

208

A techno-economic analysis and optimization of Li-ion batteries for light-duty passenger vehicle electrification  

E-Print Network [OSTI]

A techno-economic analysis and optimization of Li-ion batteries for light-duty passenger vehicle thickness a b s t r a c t We conduct a techno-economic analysis of Li-ion NMC-G prismatic pouch battery

McGaughey, Alan

209

In-situ raman microscopy of individual LiNi0.8Co0.15Al0.05O2 particles in the Li-ion battery composite cathode  

E-Print Network [OSTI]

2 Particles in the Li-ion Battery Composite Cathode Jingleidegradation of various Li-ion battery systems has been the

Lei, Jinglei; McLarnon, Frank; Kostecki, Robert

2004-01-01T23:59:59.000Z

210

Inelastic hosts as electrodes for high-capacity lithium-ion batteries Kejie Zhao, Matt Pharr, Joost J. Vlassak, and Zhigang Suoa  

E-Print Network [OSTI]

Inelastic hosts as electrodes for high-capacity lithium-ion batteries Kejie Zhao, Matt Pharr, Joost for high-capacity lithium-ion batteries. Upon absorbing lithium, silicon swells several times its volume strength. © 2011 American Institute of Physics. doi:10.1063/1.3525990 Lithium-ion batteries

211

Cahn-Hilliard Reaction Model for Isotropic Li-ion Battery Particles Yi Zeng1, Martin Z. Bazant1,2  

E-Print Network [OSTI]

Cahn-Hilliard Reaction Model for Isotropic Li-ion Battery Particles Yi Zeng1, Martin Z. Bazant1,2 1 particle. This general approach extends previous Li-ion battery models, which either neglect phase theory for Li-ion batteries [13, 18] with Butler-Volmer kinetics and concentration depen- dent

Bazant, Martin Z.

212

Block Copolymer Solid Battery Electrolyte with High Li-Ion Transference Number  

E-Print Network [OSTI]

Block Copolymer Solid Battery Electrolyte with High Li-Ion Transference Number Ayan Ghosh number TLi+ value of 0.9 at room temperature 21­23°C . The solid-state flexible, translucent polymer of withstanding such high voltage conditions. Unlike traditional liquid electrolytes, solid-state polymer electro

Rubloff, Gary W.

213

Silicon-tin oxynitride glassy composition and use as anode for lithium-ion battery  

DOE Patents [OSTI]

Disclosed are silicon-tin oxynitride glassy compositions which are especially useful in the construction of anode material for thin-film electrochemical devices including rechargeable lithium-ion batteries, electrochromic mirrors, electrochromic windows, and actuators. Additional applications of silicon-tin oxynitride glassy compositions include optical fibers and optical waveguides.

Neudecker, Bernd J. (Knoxville, TN); Bates, John B. (Oak Ridge, TN)

2001-01-01T23:59:59.000Z

214

Diagnostic Characterization of High Power Lithium-Ion Batteries for Use in Hybrid Electric Vehicles  

E-Print Network [OSTI]

Diagnostic Characterization of High Power Lithium-Ion Batteries for Use in Hybrid Electric Vehicles are a fast-growing technology that is attrac- tive for use in portable electronics and electric vehicles due electric vehicle HEV applications.c A baseline cell chemistry was identified as a carbon anode negative

215

Phase transformations and microstructural design of lithiated metal anodes for lithium-ion rechargeable batteries  

E-Print Network [OSTI]

There has been great recent interest in lithium storage at the anode of Li-ion rechargeable battery by alloying with metals such as Al, Sn, and Sb, or metalloids such as Si, as an alternative to the intercalation of graphite. ...

Limthongkul, Pimpa, 1975-

2002-01-01T23:59:59.000Z

216

Room-temperature stationary sodium-ion batteries for large-scale electric energy storage  

E-Print Network [OSTI]

energy and utility applications, such as pump hydro, compressed air, y-wheel and electrochemicalRoom-temperature stationary sodium-ion batteries for large-scale electric energy storage Huilin Pan attention particularly in large- scale electric energy storage applications for renewable energy and smart

Wang, Wei Hua

217

Doped LiFePO? cathodes for high power density lithium ion batteries  

E-Print Network [OSTI]

Olivine LiFePO4 has received much attention recently as a promising storage compound for cathodes in lithium ion batteries. It has an energy density similar to that of LiCoO 2, the current industry standard for cathode ...

Bloking, Jason T. (Jason Thompson), 1979-

2003-01-01T23:59:59.000Z

218

Graphene-enhanced hybrid phase change materials for thermal management of Li-ion batteries  

E-Print Network [OSTI]

with graphene. Incorporation of graphene increases thermal conductivity of phase change materials. Graphene that common PCMs are characterized by very low thermal conductivity, K, with typical values in the range of 0Graphene-enhanced hybrid phase change materials for thermal management of Li-ion batteries

219

Surface Modification Agents for Lithium-Ion Batteries | Argonne National  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security AdministrationcontrollerNanocrystalline GalliumSuppression of conductivity inBatteries -

220

Forming gas treatment of lithium ion battery anode graphite powders  

DOE Patents [OSTI]

The invention provides a method of making a battery anode in which a quantity of graphite powder is provided. The temperature of the graphite powder is raised from a starting temperature to a first temperature between 1000 and 2000.degree. C. during a first heating period. The graphite powder is then cooled to a final temperature during a cool down period. The graphite powder is contacted with a forming gas during at least one of the first heating period and the cool down period. The forming gas includes H.sub.2 and an inert gas.

Contescu, Cristian Ion; Gallego, Nidia C; Howe, Jane Y; Meyer, III, Harry M; Payzant, Edward Andrew; Wood, III, David L; Yoon, Sang Young

2014-09-16T23:59:59.000Z

Note: This page contains sample records for the topic "ion batteries elucidated" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Sandia National Laboratories: lithium-ion-based solid electrolyte battery  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the1developmentturbine blade manufacturinglife-cycleion battery Electric Carion-based

222

Nanoscale Imaging of Lithium Ion Distribution During In Situ Operation of Battery Electrode and Electrolyte  

E-Print Network [OSTI]

A major challenge in the development of new battery materials is understanding their fundamental mechanisms of operation and degradation. Their microscopically inhomogeneous nature calls for characterization tools that provide operando and localized information from individual grains and particles. Here we describe an approach that images the nanoscale distribution of ions during electrochemical charging of a battery in a transmission electron microscope liquid flow cell. We use valence energy-loss spectroscopy to track both solvated and intercalated ions, with electronic structure fingerprints of the solvated ions identified using an ab initio non-linear response theory. Equipped with the new electrochemical cell holder, nanoscale spectroscopy and theory, we have been able to determine the lithiation state of a LiFePO4 electrode and surrounding aqueous electrolyte in real time with nanoscale resolution during electrochemical charge and discharge. We follow lithium transfer between electrode and electrolyte a...

Holtz, Megan E; Gunceler, Deniz; Gao, Jie; Sundararaman, Ravishankar; Schwarz, Kathleen A; Arias, Tomás A; Abruña, Héctor D; Muller, David A

2013-01-01T23:59:59.000Z

223

Platform Li-Ion Battery Risk Assessment Tool: Cooperative Research and Development Final Report, CRADA Number CRD-01-406  

SciTech Connect (OSTI)

The pressure within a lithium-ion cell changes due to various chemical reactions. When a battery undergoes an unintended short circuit, the pressure changes are drastic - and often lead to uncontrolled failure of the cells. As part of work for others with Oceanit Laboratories Inc. for the NAVY STTR, NREL built Computational Fluid Dynamic (CFD) simulations that can identify potential weak spots in the battery during such events, as well as propose designs to control violent failure of batteries.

Santhanagopalan, S.

2012-07-01T23:59:59.000Z

224

Six Thousand Electrochemical Cycles of Double-Walled Silicon Nanotube Anodes for Lithium Ion Batteries  

SciTech Connect (OSTI)

Despite remarkable progress, lithium ion batteries still need higher energy density and better cycle life for consumer electronics, electric drive vehicles and large-scale renewable energy storage applications. Silicon has recently been explored as a promising anode material for high energy batteries; however, attaining long cycle life remains a significant challenge due to materials pulverization during cycling and an unstable solid-electrolyte interphase. Here, we report double-walled silicon nanotube electrodes that can cycle over 6000 times while retaining more than 85% of the initial capacity. This excellent performance is due to the unique double-walled structure in which the outer silicon oxide wall confines the inner silicon wall to expand only inward during lithiation, resulting in a stable solid-electrolyte interphase. This structural concept is general and could be extended to other battery materials that undergo large volume changes.

Wu, H

2011-08-18T23:59:59.000Z

225

Journal of Power Sources 160 (2006) 662673 Power and thermal characterization of a lithium-ion battery  

E-Print Network [OSTI]

-ion battery; Electrochemical modeling; Hybrid-electric vehicles; Transient; Solid-state diffusion; Heat, indicating solid-state diffusion is the limiting mechanism. The 3.9 V cell-1 maximum limit, meant to protect where batteries are used as a transient pulse power source, cycled about a relatively fixed state

226

On-board state of health monitoring of lithium-ion batteries using incremental capacity analysis with support vector regressionq  

E-Print Network [OSTI]

On-board state of health monitoring of lithium-ion batteries using incremental capacity analysis-board battery state-of-health (SOH) monitoring framework is proposed. 2013 Accepted 5 February 2013 Available online 11 February 2013 Keywords: Electric vehicles Lithium

Peng, Huei

227

Maximum Li storage in Si nanowires for the high capacity three-dimensional Li-ion battery  

E-Print Network [OSTI]

, such as fuel cells and secondary batteries. Here we report a coin-type Si nanowire NW half-cell Li-ion battery is the central research subject in various energy conversion systems, such as solar cells, fuel cells must be optimally coordinated.7 In this respect, Si nanowire NW arrays can serve as the high capacity

Jo, Moon-Ho

228

The Effect of Single Walled Carbon Nanotubes on Lithium-Ion Batteries and Electric Double Layer Capacitors  

E-Print Network [OSTI]

on the overall performance of Li-ion batteries and EDLCs. SWNTs were incorporated into the anode of the Lithium carbon in the EDLC to act as conductors. An EDLC containing no SWNT was the control. Activated carbon secondary batteries ·High voltage (3.6 V) ·No memory effect ·lightweight EDLCs ·High power density ·High

229

Layered cathode materials for lithium ion rechargeable batteries  

DOE Patents [OSTI]

A number of materials with the composition Li.sub.1+xNi.sub..alpha.Mn.sub..beta.Co.sub..gamma.M'.sub..delta.O.sub.2-- zF.sub.z (M'=Mg,Zn,Al,Ga,B,Zr,Ti) for use with rechargeable batteries, wherein x is between about 0 and 0.3, .alpha. is between about 0.2 and 0.6, .beta. is between about 0.2 and 0.6, .gamma. is between about 0 and 0.3, .delta. is between about 0 and 0.15, and z is between about 0 and 0.2. Adding the above metal and fluorine dopants affects capacity, impedance, and stability of the layered oxide structure during electrochemical cycling.

Kang, Sun-Ho (Naperville, IL); Amine, Khalil (Downers Grove, IL)

2007-04-17T23:59:59.000Z

230

Synthesis of Na1.25V3O8 Nanobelts with Excellent Long-Term Stability for Rechargeable Lithium-Ion Batteries  

E-Print Network [OSTI]

by the calcination temperatures. As cathode materials for lithium ion batteries, the Na1.25V3O8 nanobelts synthesized.25V3O8 nanobelts are promising cathode materials for secondary lithium batteries. KEYWORDS: sodium vanadium oxide, nanobelts, sol-gel, lithium-ion batteries, long-term stability 1. INTRODUCTION Because

Cao, Guozhong

231

A Unified Open-Circuit-Voltage Model of Lithium-ion Batteries for State-of-Charge Estimation and State-of-Health Monitoring $  

E-Print Network [OSTI]

A Unified Open-Circuit-Voltage Model of Lithium-ion Batteries for State-of-Charge Estimation. Keywords: Electric vehicles, Lithium-ion batteries, Open-Circuit-Voltage, State-of-Charge, State is widely used for characterizing battery properties under different conditions. It contains important

Peng, Huei

232

The Application of Synchrotron Techniques to the Study of Lithium-ion Batteries  

SciTech Connect (OSTI)

This paper gives a brief review of the application of synchrotron X-ray techniques to the study of lithium-ion battery materials. The two main techniques are X-ray absorption spectroscopy (XAS) and high-resolution X-ray diffraction (XRD). Examples are given for in situ XAS and XRD studies of lithium-ion battery cathodes during cycling. This includes time-resolved methods. The paper also discusses the application of soft X-ray XAS to do ex situ studies on battery cathodes. By applying two signal detection methods, it is possible to probe the surface and the bulk of cathode materials simultaneously. Another example is the use of time-resolved XRD studies of the decomposition of reactions of charged cathodes at elevated temperatures. Measurements were done both in the dry state and in the presence of electrolyte. Brief reports are also given on two new synchrotron techniques. One is inelastic X-ray scattering, and the other is synchrotron X-ray reflectometry studies of the surface electrode interface (SEI) on highly oriented single crystal lithium battery cathode surfaces.

McBreen, J.

2009-07-01T23:59:59.000Z

233

Novel Energy Sources -Material Architecture and Charge Transport in Solid State Ionic Materials for Rechargeable Li ion Batteries  

SciTech Connect (OSTI)

Since its introduction in the consumer market at the beginning of 1990s by Sony Corporation ‘Li-ion rechargeable battery’ and ‘LiCoO2 cathode’ is an inseparable couple for highly reliable practical applications. However, a separation is inevitable as Li-ion rechargeable battery industry demand more and more from this well serving cathode. Spinel-type lithium manganate (e.g., LiMn2O4), lithium-based layered oxide materials (e.g., LiNiO2) and lithium-based olivine-type compounds (e.g., LiFePO4) are nowadays being extensively studied for application as alternate cathode materials in Li-ion rechargeable batteries. Primary goal of this project was the advancement of Li-ion rechargeable battery to meet the future demands of the energy sector. Major part of the research emphasized on the investigation of electrodes and solid electrolyte materials for improving the charge transport properties in Li-ion rechargeable batteries. Theoretical computational methods were used to select electrodes and electrolyte material with enhanced structural and physical properties. The effect of nano-particles on enhancing the battery performance was also examined. Satisfactory progress has been made in the bulk form and our efforts on realizing micro-battery based on thin films is close to give dividend and work is progressing well in this direction.

Katiyar, Ram S; Gómez, M; Majumder, S B; Morell, G; Tomar, M S; Smotkin, E; Bhattacharya, P; Ishikawa, Y

2009-01-19T23:59:59.000Z

234

On the electrochemical reactivity and design of NiP2 negative electrodes for secondary Li-ion batteries  

E-Print Network [OSTI]

commercialisation, rechargeable Li-ion batteries are widely accepted, and are becoming the main power source1 On the electrochemical reactivity and design of NiP2 negative electrodes for secondary Li-ion study of cubic and monoclinic NiP2 polymorphs towards Li, as candidate for anodic applications for Li-ion

Boyer, Edmond

235

Evaluation of Tavorite-Structured Cathode Materials for Lithium-Ion Batteries Using High-Throughput Computing  

E-Print Network [OSTI]

Cathode materials with structure similar to the mineral tavorite have shown promise for use in lithium-ion batteries, but this class of materials is relatively unexplored. We use high-throughput density-functional-theory ...

Mueller, Tim

236

Three-Dimensional Thermal-Electrochemical Coupled Model for Spirally Wound Large-Format Lithium-Ion Batteries (Presentation)  

SciTech Connect (OSTI)

This presentation discusses the behavior of spirally wound large-format Li-ion batteries with respect to their design. The objectives of the study include developing thermal and electrochemical models resolving 3-dimensional spirally wound structures of cylindrical cells, understanding the mechanisms and interactions between local electrochemical reactions and macroscopic heat and electron transfers, and developing a tool and methodology to support macroscopic designs of cylindrical Li-ion battery cells.

Lee, K. J.; Smith K.; Kim, G. H.

2011-04-01T23:59:59.000Z

237

Highly Reversible Open Framework Nanoscale Electrodes for Divalent Ion Batteries  

E-Print Network [OSTI]

Blue family of open framework materials, such as nickel hexacyanoferrate, allow for the reversible of protons and lithium ions into solid materials has led to the success of nickel metal hydride and lithium materials have been studied extensively.15,16,18,20-23 Electrodeposited PB thin films have demonstrated

Cui, Yi

238

Synthesis, Characterization and Testing of Novel Anode and Cathode Materials for Li-Ion Batteries  

SciTech Connect (OSTI)

During this program we have synthesized and characterized several novel cathode and anode materials for application in Li-ion batteries. Novel synthesis routes like chemical doping, electroless deposition and sol-gel method have been used and techniques like impedance, cyclic voltammetry and charge-discharge cycling have been used to characterize these materials. Mathematical models have also been developed to fit the experimental result, thus helping in understanding the mechanisms of these materials.

White, Ralph E.; Popov, Branko N.

2002-10-31T23:59:59.000Z

239

EMSL - batteries  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

batteries en Magnesium behavior and structural defects in Mg+ ion implanted silicon carbide. http:www.emsl.pnl.govemslwebpublicationsmagnesium-behavior-and-structural-defects-...

240

Modeling the performance and cost of lithium-ion batteries for electric-drive vehicles.  

SciTech Connect (OSTI)

This report details the Battery Performance and Cost model (BatPaC) developed at Argonne National Laboratory for lithium-ion battery packs used in automotive transportation. The model designs the battery for a specified power, energy, and type of vehicle battery. The cost of the designed battery is then calculated by accounting for every step in the lithium-ion battery manufacturing process. The assumed annual production level directly affects each process step. The total cost to the original equipment manufacturer calculated by the model includes the materials, manufacturing, and warranty costs for a battery produced in the year 2020 (in 2010 US$). At the time this report is written, this calculation is the only publically available model that performs a bottom-up lithium-ion battery design and cost calculation. Both the model and the report have been publically peer-reviewed by battery experts assembled by the U.S. Environmental Protection Agency. This report and accompanying model include changes made in response to the comments received during the peer-review. The purpose of the report is to document the equations and assumptions from which the model has been created. A user of the model will be able to recreate the calculations and perhaps more importantly, understand the driving forces for the results. Instructions for use and an illustration of model results are also presented. Almost every variable in the calculation may be changed by the user to represent a system different from the default values pre-entered into the program. The distinct advantage of using a bottom-up cost and design model is that the entire power-to-energy space may be traversed to examine the correlation between performance and cost. The BatPaC model accounts for the physical limitations of the electrochemical processes within the battery. Thus, unrealistic designs are penalized in energy density and cost, unlike cost models based on linear extrapolations. Additionally, the consequences on cost and energy density from changes in cell capacity, parallel cell groups, and manufacturing capabilities are easily assessed with the model. New proposed materials may also be examined to translate bench-scale values to the design of full-scale battery packs providing realistic energy densities and prices to the original equipment manufacturer. The model will be openly distributed to the public in the year 2011. Currently, the calculations are based in a Microsoft{reg_sign} Office Excel spreadsheet. Instructions are provided for use; however, the format is admittedly not user-friendly. A parallel development effort has created an alternate version based on a graphical user-interface that will be more intuitive to some users. The version that is more user-friendly should allow for wider adoption of the model.

Nelson, P. A.

2011-10-20T23:59:59.000Z

Note: This page contains sample records for the topic "ion batteries elucidated" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

EV Everywhere Batteries Workshop - Materials Processing and Manufactur...  

Energy Savers [EERE]

More Documents & Publications EV Everywhere Batteries Workshop - Next Generation Lithium Ion Batteries Breakout Session Report EV Everywhere Batteries Workshop - Beyond...

242

Structural Integration of Silicon Solar Cells and Lithium-ion Batteries Using Printed Electronics  

E-Print Network [OSTI]

solid state battery ..of the thin-film solid state battery is shown in Fig. 13.the thin-film solid state battery. CHAPTER FIVE Performance

Kang, Jin Sung

2012-01-01T23:59:59.000Z

243

Studies of ionic liquids in lithium-ion battery test systems  

E-Print Network [OSTI]

are not useful for lithium batteries. We are therefore nowapplications using lithium batteries, we must be sure thattemperature range. For lithium batteries in hybrid vehicles,

Salminen, Justin; Prausnitz, John M.; Newman, John

2006-01-01T23:59:59.000Z

244

Develop high energy high power Li-ion battery cathode materials : a first principles computational study  

E-Print Network [OSTI]

of cathode materials for lithium batteries guided by first-facing rechargeable lithium batteries. Nature, 2001. 414(M.S. Whittingham, Lithium batteries and cathode materials.

Xu, Bo; Xu, Bo

2012-01-01T23:59:59.000Z

245

Lithium Ion Battery Performance of Silicon Nanowires With Carbon Skin . |  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: VegetationEquipment Surfaces and Interfaces Sample6, 2011Liisa O'NeillFuels MarketLisaLithiumEMSL Ion

246

Sodium Ion Insertion in Hollow Carbon Nanowires for Battery Applications. |  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administrationcontroller systemsBiSite CulturalDepartment ofat Home |EMSL Sodium Ion Insertion

247

Probing the Failure Mechanism of SnO{sub 2} Nanowires for Sodium-Ion Batteries  

SciTech Connect (OSTI)

Nonlithium metals such as sodium have attracted wide attention as a potential charge carrying ion for rechargeable batteries. Using in situ transmission electron microscopy in combination with density functional theory calculations, we probed the structural and chemical evolution of SnO{sub 2} nanowire anodes in Na-ion batteries and compared them quantitatively with results from Li-ion batteries (Huang, J. Y.; et al. Science 2010, 330, 1515-1520). Upon Na insertion into SnO{sub 2}, a displacement reaction occurs, leading to the formation of amorphous Na{sub x}Sn nanoparticles dispersed in Na{sub 2}O matrix. With further Na insertion, the Na{sub x}Sn crystallized into Na{sub 15}Sn{sub 4} (x = 3.75). Upon extraction of Na (desodiation), the Na{sub x}Sn transforms to Sn nanoparticles. Associated with the dealloying, pores are found to form, leading to a structure of Sn particles confined in a hollow matrix of Na{sub 2}O. These pores greatly increase electrical impedance, therefore accounting for the poor cyclability of SnO{sub 2}. DFT calculations indicate that Na{sup +} diffuses 30 times slower than Li{sup +} in SnO{sub 2}, in agreement with in situ TEM measurement. Insertion of Na can chemomechanically soften the reaction product to a greater extent than in lithiation. Therefore, in contrast to the lithiation of SnO{sub 2} significantly less dislocation plasticity was seen ahead of the sodiation front. This direct comparison of the results from Na and Li highlights the critical role of ionic size and electronic structure of different ionic species on the charge/discharge rate and failure mechanisms in these batteries.

Gu, Meng; Kushima, Akihiro; Shao, Yuyan; Zhang, Ji-Guang; Liu, Jun; Browning, Nigel D; Li, Ju; Wang, Chongmin

2013-09-30T23:59:59.000Z

248

Nanowire Lithium-Ion Battery P R O J E C T L E A D E R : Alec Talin (NIST)  

E-Print Network [OSTI]

To fabricate a single nanowire Li-ion battery and observe it charging and discharging. K E Y A C C O M P L I S H M E N T S Designed, fabricated, and tested complete Li-ion nanowire batteries measuring Nanowire Lithium-Ion Battery P R O J E C T L E A D E R : Alec Talin (NIST) C O L L A B O R A T O R

249

Corrosion of lithium-ion battery current collectors  

SciTech Connect (OSTI)

The primary current-collector materials being used in lithium-ion cells are susceptible to environmental degradation: aluminum to pitting corrosion and copper to environmentally assisted cracking. Localized corrosion occurred on bare aluminum electrodes during simulated ambient-temperature cycling in an excess of electrolyte. The highly oxidizing potential associated with the positive-electrode charge condition was the primary factor. The corrosion mechanism differed from the pitting typically observed in aqueous electrolytes because each site was filled with a mixed metal/metal-oxide product, forming surface mounds or nodules. Electrochemical impedance spectroscopy was shown to be an effective analytical tool for characterizing the corrosion behavior of aluminum under these conditions. Based on X-ray photoelectron spectroscopy analyses, little difference existed in the composition of the surface film on aluminum and copper after immersion or cycling in LiPF{sub 6} electrolytes made with two different solvent formulations. Although Li and P were the predominant adsorbed surface species, the corrosion resistance of aluminum may simply be due to its native oxide. Finally, copper was shown to be susceptible to environmental cracking at or near the lithium potential when specific metallurgical conditions existed (work hardening and large grain size).

Braithwaite, J.W.; Gonzales, A.; Nagasubramanian, G.; Lucero, S.J.; Peebles, D.E.; Ohlhausen, J.A.; Cieslak, W.R. [Sandia National Labs., Albuquerque, NM (United States)] [Sandia National Labs., Albuquerque, NM (United States)

1999-02-01T23:59:59.000Z

250

A hyperbolic problem with non-local constraint describing ion-rearrangement in a model for ion-lithium batteries  

E-Print Network [OSTI]

In this paper we study the Fokker-Plank equation arising in a model which describes the charge and discharge process of ion-lithium batteries. In particular we focus our attention on slow reaction regimes with non-negligible entropic effects, which triggers the mass-splitting transition. At first we prove that the problem is globally well-posed. After that we prove a stability result under some hypothesis of improved regularity and a uniqueness result for the stability under some additional condition of

Stefano Scrobogna; Juan J. L. Velázquez

2015-02-20T23:59:59.000Z

251

Observation of State of Charge Distributions in Lithium-ion Battery Electrodes  

SciTech Connect (OSTI)

Current lithium-ion battery technology is gearing towards meeting the robust demand of power and energy requirements for all-electric transportation without compromising on the safety, performance, and cycle life. The state-of-charge (SOC) of a Li-ion cell can be a macroscopic indicator of the state-of-health of the battery. The microscopic origin of the SOC relates to the local lithium content in individual electrode particles and the effective ability of Li-ions to transport or shuttle between the redox couples through the cell geometric boundaries. Herein, micrometer-resolved Raman mapping of a transition-metal-based oxide positive electrode, Li{sub 1-x}(Ni{sub y}Co{sub z}Al{sub 1-y-z})O{sub 2}, maintained at different SOCs, is shown. An attempt has been made to link the underlying changes to the composition and structural integrity at the individual particle level. Furthermore, an SOC distribution at macroscopic length scale of the electrodes is presented.

Remillard, Jeffrey [Ford Research and Advanced Engineering, Ford Motor Company; O'Neil, Ann E [Ford Research and Advanced Engineering, Ford Motor Company; Bernardi, Dawn [Ford Research and Advanced Engineering, Ford Motor Company; Ro, Tina J [Massachusetts Institute of Technology (MIT); Miller, Ted [Ford Motor Company; Neitering, Ken [Ford Research and Advanced Engineering, Ford Motor Company; Go, Joo-Young [SB Limotive, Korea; Nanda, Jagjit [ORNL

2011-01-01T23:59:59.000Z

252

Advanced Surface and Microstructural Characterization of Natural Graphite Anodes for Lithium Ion Batteries  

SciTech Connect (OSTI)

Natural graphite powders were subjected to a series of thermal treatments in order to improve the anode irreversible capacity loss (ICL) and capacity retention during long-term cycling of lithium ion batteries. A baseline thermal treatment in inert Ar or N2 atmosphere was compared to cases with a proprietary additive to the furnace gas environment. This additive substantially altered the surface chemistry of the natural graphite powders and resulted in significantly improved long-term cycling performance of the lithium ion batteries over the commercial natural graphite baseline. Different heat-treatment temperatures were investigated ranging from 950-2900 C with the intent of achieving the desired long-term cycling performance with as low of a maximum temperature and thermal budget as possible. A detailed summary of the characterization data is also presented, which includes X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), Raman spectroscopy, and temperature-programed desorption mass spectroscopy (TPD-MS). This characterization data was correlated to the observed capacity fade improvements over the course of long-term cycling at high charge-discharge rates in full lithium-ion coin cells. It is believed that the long-term performance improvements are a result of forming a more stable solid electrolyte interface (SEI) layer on the anode graphite surfaces, which is directly related to the surface chemistry modifications imparted by the proprietary gas environment during thermal treatment.

Gallego, Nidia C [ORNL] [ORNL; Contescu, Cristian I [ORNL] [ORNL; Meyer III, Harry M [ORNL] [ORNL; Howe, Jane Y [ORNL] [ORNL; Meisner, Roberta Ann [ORNL] [ORNL; Payzant, E Andrew [ORNL] [ORNL; Lance, Michael J [ORNL] [ORNL; Yoon, Steve [A123 Systems, Inc.] [A123 Systems, Inc.; Denlinger, Matthew [A123 Systems, Inc.] [A123 Systems, Inc.; Wood III, David L [ORNL] [ORNL

2014-01-01T23:59:59.000Z

253

Graphene-based Electrochemical Energy Conversion and Storage: Fuel cells, Supercapacitors and Lithium Ion Batteries  

SciTech Connect (OSTI)

Graphene has attracted extensive research interest due to its strictly 2-dimensional (2D) structure, which results in its unique electronic, thermal, mechanical, and chemical properties and potential technical applications. These remarkable characteristics of graphene, along with the inherent benefits of a carbon material, make it a promising candidate for application in electrochemical energy devices. This article reviews the methods of graphene preparation, introduces the unique electrochemical behavior of graphene, and summarizes the recent research and development on graphene-based fuel cells, supercapacitors and lithium ion batteries. In addition, promising areas are identified for the future development of graphene-based materials in electrochemical energy conversion and storage systems.

Hou, Junbo; Shao, Yuyan; Ellis, Michael A.; Moore, Robert; Yi, Baolian

2011-09-14T23:59:59.000Z

254

Chemical overcharge protection of lithium and lithium-ion secondary batteries  

DOE Patents [OSTI]

This invention features the use of redox reagents, dissolved in non-aqueous electrolytes, to provide overcharge protection for cells having lithium metal or lithium-ion negative electrodes (anodes). In particular, the invention features the use of a class of compounds consisting of thianthrene and its derivatives as redox shuttle reagents to provide overcharge protection. Specific examples of this invention are thianthrene and 2,7-diacetyl thianthrene. One example of a rechargeable battery in which 2,7-diacetyl thianthrene is used has carbon negative electrode (anode) and spinet LiMn{sub 2}O{sub 4} positive electrode (cathode). 8 figs.

Abraham, K.M.; Rohan, J.F.; Foo, C.C.; Pasquariello, D.M.

1999-01-12T23:59:59.000Z

255

Chemical overcharge protection of lithium and lithium-ion secondary batteries  

DOE Patents [OSTI]

This invention features the use of redox reagents, dissolved in non-aqueous electrolytes, to provide overcharge protection for cells having lithium metal or lithium-ion negative electrodes (anodes). In particular, the invention features the use of a class of compounds consisting of thianthrene and its derivatives as redox shuttle reagents to provide overcharge protection. Specific examples of this invention are thianthrene and 2,7-diacetyl thianthrene. One example of a rechargeable battery in which 2,7-diacetyl thianthrene is used has carbon negative electrode (anode) and spinet LiMn.sub.2 O.sub.4 positive electrode (cathode).

Abraham, Kuzhikalail M. (Needham, MA); Rohan, James F. (Cork City, IE); Foo, Conrad C. (Dedham, MA); Pasquariello, David M. (Pawtucket, RI)

1999-01-01T23:59:59.000Z

256

Flexographically Printed Rechargeable Zinc-based Battery for Grid Energy Storage  

E-Print Network [OSTI]

the rechargeable battery industry. Li-ion batteries rapidlyLi-ion chemistry. For grid storage applications, several other rechargeable batteryLi-ion batteries, because cadmium is highly toxic. In 1991, lithium-ion battery

Wang, Zuoqian

2013-01-01T23:59:59.000Z

257

Some comments on the Butler-Volmer equation for modeling Lithium-ion batteries  

E-Print Network [OSTI]

In this article the Butler-Volmer equation used in describing Lithium-ion (Li-ion) batteries is discussed. First, a complete mathematical model based on a macro-homogeneous approach developed by Neuman is presented. Two common mistakes found in the literature regarding a sign in a boundary conditions and the use of the transfer coefficient are mentioned. The paper focuses on the form of the Butler-Volmer equation in the model. It is shown how practical problems can be avoided by taking care in the form used, particularly to avoid difficulties when the solid particle in the electrodes approaches a fully charged or discharged state or the electrolyte gets depleted. This shows that the open circuit voltage and the exchange current density must depend on the lithium concentration in both the solid and the electrolyte in a particular way at the extremes of the concentration ranges.

Ramos, A M

2015-01-01T23:59:59.000Z

258

Modeling Electrochemical Decomposition of Fluoroethylene Carbonate on Silicon Anode Surfaces in Lithium Ion Batteries  

E-Print Network [OSTI]

Fluoroethylene carbonate (FEC) shows promise as an electrolyte additive for improving passivating solid-electrolyte interphase (SEI) films on silicon anodes used in lithium ion batteries (LIB). We apply density functional theory (DFT), ab initio molecular dynamics (AIMD), and quantum chemistry techniques to examine excess-electron-induced FEC molecular decomposition mechanisms that lead to FEC-modified SEI. We consider one- and two-electron reactions using cluster models and explicit interfaces between liquid electrolyte and model Li(x)Si(y) surfaces, respectively. FEC is found to exhibit more varied reaction pathways than unsubstituted ethylene carbonate. The initial bond-breaking events and products of one- and two-electron reactions are qualitatively similar, with a fluoride ion detached in both cases. However, most one-electron products are charge-neutral, not anionic, and may not coalesce to form effective Li+-conducting SEI unless they are further reduced or take part in other reactions. The implication...

Leung, Kevin; Foster, Michael E; Ma, Yuguang; del la Hoz, Julibeth M Martinez; Sai, Na; Balbuena, Perla B

2014-01-01T23:59:59.000Z

259

STUDIES ON TWO CLASSES OF POSITIVE ELECTRODE MATERIALS FOR LITHIUM-ION BATTERIES  

E-Print Network [OSTI]

4) Lithium Battery Cathode. Electrochemical and Solid-StateBattery Electrodes Utilizing Fibrous Conductive Additives. Electrochemical and Solid-Statesolid state, these effects can become limiting in some systems. 1.3 Battery

Wilcox, James D.

2010-01-01T23:59:59.000Z

260

STUDIES ON TWO CLASSES OF POSITIVE ELECTRODE MATERIALS FOR LITHIUM-ION BATTERIES  

E-Print Network [OSTI]

Linden, D. , Handbook of Batteries. 2nd ed. 1995, New York:rechargeable lithium batteries. Nature, 2001. 414(6861): p.of rechargeable lithium batteries, I. Lithium manganese

Wilcox, James D.

2010-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "ion batteries elucidated" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Nb-doped TiO2 Nanofibers for Lithium Ion Batteries M. Fehse,, S. Cavaliere, P. E. Lippens, I. Savych, A. Iodacela, L.  

E-Print Network [OSTI]

Nb-doped TiO2 Nanofibers for Lithium Ion Batteries M. Fehse,, S. Cavaliere, P. E. Lippens, I, lithium ion batteries (LIB) have come a long way.1 Originally intended to serve only for small portable properties due to necessary solid elec- trolyte interphase (SEI) formation and the risk of lithium plating

Paris-Sud XI, Université de

262

TiSnSb a new efficient negative electrode for Li-ion batteries: mechanism investigations by operando-XRD and Mossbauer techniques  

E-Print Network [OSTI]

TiSnSb a new efficient negative electrode for Li-ion batteries: mechanism investigations We report the electrochemical study of TiSnSb towards Li, as a negative electrode for Li-ion batteries. TiSnSb can reversibly take up more than 5 lithiums per formula unit leading to reversible

Boyer, Edmond

263

Modeling of Nonuniform Degradation in Large-Format Li-ion Batteries (Presentation)  

SciTech Connect (OSTI)

Study of impacts of large-format cell design features on battery useful life to improve battery engineering models, including both realistic geometry and physics.

Smith, K.; Kim, G. H.; Pesaran, A.

2009-05-01T23:59:59.000Z

264

Elucidating the Higher Stability of Vanadium (V) Cations in Mixed...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Elucidating the Higher Stability of Vanadium (V) Cations in Mixed Acid Based Redox Flow Battery Electrolytes. Abstract: The Vanadium (V) cation structures in mixed acid based...

265

Enhanced rate capability of LiMn0.9Mg0.1PO4 nanoplates by reduced graphene oxide/carbon double coating for Li-ion batteries  

E-Print Network [OSTI]

coating for Li-ion batteries Sungun Wi a , Jaewon Kim a , Seunghoon Nam a , Joonhyeon Kang a , Sangheon March 2014 Available online 12 March 2014 Keywords: Li-ion battery LiMnPO4 Reduced graphene oxide Charge) nanoplates are intro- duced as a cathode material for Li-ion batteries with excellent rate capability

Park, Byungwoo

266

Internal Short Circuit Device Helps Improve Lithium-Ion Battery Design (Fact Sheet)  

SciTech Connect (OSTI)

NREL's emulation tool helps manufacturers ensure the safety and reliability of electric vehicle batteries.

Not Available

2012-04-01T23:59:59.000Z

267

Block copolymer electrolytes for lithium batteries  

E-Print Network [OSTI]

interface in the Li-ion battery. Electrochimica Acta 50,K. The role of Li-ion battery electrolyte reactivity inK. The role of Li-ion battery electrolyte reactivity in

Hudson, William Rodgers

2011-01-01T23:59:59.000Z

268

Electrochemical Properties of Nanostructured Al1-xCux Alloys as Anode Materials for Rechargeable Lithium-Ion Batteries  

E-Print Network [OSTI]

controlling these two properties is the mag- nitude of interaction between the active and the inactiveElectrochemical Properties of Nanostructured Al1-xCux Alloys as Anode Materials for Rechargeable Lithium-Ion Batteries C. Y. Wang,a, * Y. S. Meng,b, * G. Ceder,c, *,z and Y. Lia,d,z a Advanced Materials

Ceder, Gerbrand

269

Thermal stability of LiPF6EC:EMC electrolyte for lithium ion batteries Gerardine G. Bottea  

E-Print Network [OSTI]

Thermal stability of LiPF6±EC:EMC electrolyte for lithium ion batteries Gerardine G. Bottea , Ralph study of the LiPF6±EC:EMC electrolyte. The effect of different variables on its thermal stability was evaluated: salt (LiPF6) concentration effect, solvents, EC:EMC ratios, and heating rates. Hermetically

270

Electronic transport in Lithium Nickel Manganese Oxide, a high-voltage cathode material for Lithium-Ion batteries  

E-Print Network [OSTI]

Potential routes by which the energy densities of lithium-ion batteries may be improved abound. However, the introduction of Lithium Nickel Manganese Oxide (LixNi1i/2Mn3/2O4, or LNMO) as a positive electrode material appears ...

Ransil, Alan Patrick Adams

2013-01-01T23:59:59.000Z

271

Improved layered mixed transition metal oxides for Li-ion batteries  

SciTech Connect (OSTI)

Recent work in our laboratory has been directed towards development of mixed layered transition metal oxides with general composition Li[Ni, Co, M, Mn]O2 (M=Al, Ti) for Li ion battery cathodes. Compounds such as Li[Ni1/3Co1/3Mn1/3]O2 (often called NMCs) are currently being commercialized for use in consumer electronic batteries, but the high cobalt content makes them too expensive for vehicular applications such as electric vehicles (EV), plug-in hybrid electric vehicles (PHEVs), or hybrid electric vehicles (HEVs). To reduce materials costs, we have explored partial or full substitution of Co with Al, Ti, and Fe. Fe substitution generally decreases capacity and results in poorer rate and cycling behavior. Interestingly, low levels of substitution with Al or Ti improve aspects of performance with minimal impact on energy densities, for some formulations. High levels of Al substitution compromise specific capacity, however, so further improvements require that the Ni and Mn content be increased and Co correspondingly decreased. Low levels of Al or Ti substitution can then be used offset negative effects induced by the higher Ni content. The structural and electrochemical characterization of substituted NMCs is presented in this paper.

Doeff, Marca M.; Conry, Thomas; Wilcox, James

2010-03-05T23:59:59.000Z

272

Material and energy flows in the materials production, assembly, and end-of-life stages of the automotive lithium-ion battery life cycle  

SciTech Connect (OSTI)

This document contains material and energy flows for lithium-ion batteries with an active cathode material of lithium manganese oxide (LiMn{sub 2}O{sub 4}). These data are incorporated into Argonne National Laboratory's Greenhouse gases, Regulated Emissions, and Energy use in Transportation (GREET) model, replacing previous data for lithium-ion batteries that are based on a nickel/cobalt/manganese (Ni/Co/Mn) cathode chemistry. To identify and determine the mass of lithium-ion battery components, we modeled batteries with LiMn{sub 2}O{sub 4} as the cathode material using Argonne's Battery Performance and Cost (BatPaC) model for hybrid electric vehicles, plug-in hybrid electric vehicles, and electric vehicles. As input for GREET, we developed new or updated data for the cathode material and the following materials that are included in its supply chain: soda ash, lime, petroleum-derived ethanol, lithium brine, and lithium carbonate. Also as input to GREET, we calculated new emission factors for equipment (kilns, dryers, and calciners) that were not previously included in the model and developed new material and energy flows for the battery electrolyte, binder, and binder solvent. Finally, we revised the data included in GREET for graphite (the anode active material), battery electronics, and battery assembly. For the first time, we incorporated energy and material flows for battery recycling into GREET, considering four battery recycling processes: pyrometallurgical, hydrometallurgical, intermediate physical, and direct physical. Opportunities for future research include considering alternative battery chemistries and battery packaging. As battery assembly and recycling technologies develop, staying up to date with them will be critical to understanding the energy, materials, and emissions burdens associated with batteries.

Dunn, J.B.; Gaines, L.; Barnes, M.; Wang, M.; Sullivan, J. (Energy Systems)

2012-06-21T23:59:59.000Z

273

Mesoporous carbon -Cr2O3 composite as an anode material for lithium ion batteries  

SciTech Connect (OSTI)

Mesoporous carbon-Cr2O3 (M-C-Cr2O3) composite was prepared by co-assembly of in-situ formed phenolic resin, chromium precursor, and Pluronic block copolymer under acidic conditions, followed by carbonization at 750oC under Argon. The TEM results confirmed that the Cr2O3 nanoparticles, ranging from 10 to 20 nm, were well dispersed in the matrix of mesoporous carbon. The composite exhibited an initial reversible capacity of 710 mAh g-1 and good cycling stability, which is mainly due to the synergic effects of carbons within the composites, i.e. confining the crystal growth of Cr2O3 during the high temperature treatment step and buffering the volume change of Cr2O3 during the cycling step. This composite material is a promising anode material for lithium ion batteries.

Guo, Bingkun [ORNL; Chi, Miaofang [ORNL; Sun, Xiao-Guang [ORNL; Dai, Sheng [ORNL

2012-01-01T23:59:59.000Z

274

Nanostructured lithium-aluminum alloy electrodes for lithium-ion batteries.  

SciTech Connect (OSTI)

Electrodeposited aluminum films and template-synthesized aluminum nanorods are examined as negative electrodes for lithium-ion batteries. The lithium-aluminum alloying reaction is observed electrochemically with cyclic voltammetry and galvanostatic cycling in lithium half-cells. The electrodeposition reaction is shown to have high faradaic efficiency, and electrodeposited aluminum films reach theoretical capacity for the formation of LiAl (1 Ah/g). The performance of electrodeposited aluminum films is dependent on film thickness, with thicker films exhibiting better cycling behavior. The same trend is shown for electron-beam deposited aluminum films, suggesting that aluminum film thickness is the major determinant in electrochemical performance regardless of deposition technique. Synthesis of aluminum nanorod arrays on stainless steel substrates is demonstrated using electrodeposition into anodic aluminum oxide templates followed by template dissolution. Unlike nanostructures of other lithium-alloying materials, the electrochemical performance of these aluminum nanorod arrays is worse than that of bulk aluminum.

Hudak, Nicholas S.; Huber, Dale L.

2010-12-01T23:59:59.000Z

275

A Combustion Chemistry Analysis of Carbonate Solvents in Li-Ion Batteries  

SciTech Connect (OSTI)

Under abusive conditions Li-ion batteries can rupture, ejecting electrolyte and other flammable gases. In this paper we consider some of the thermochemical properties of these gases that will determine whether they ignite and how energetically they burn. We show that flames of carbonate solvents are fundamentally less energetic than those of conventional hydrocarbons. An example of this difference is given using a recently developed mechanism for dimethyl carbonate (DMC) combustion, where we show that a diffusion flame burning DMC has only half the peak energy release rate of an analogous propane flame. We find a significant variation among the carbonate solvents in the factors that are important to determining flammability, such as combustion enthalpy and vaporization enthalpy. This result suggests that thermochemical and kinetic factors might well be considered when choosing solvent mixtures.

Harris, S J; Timmons, A; Pitz, W J

2008-11-13T23:59:59.000Z

276

Layer cathode methods of manufacturing and materials for Li-ion rechargeable batteries  

DOE Patents [OSTI]

A positive electrode active material for lithium-ion rechargeable batteries of general formula Li.sub.1+xNi.sub..alpha.Mn.sub..beta.A.sub..gamma.O.sub.2 and further wherein A is Mg, Zn, Al, Co, Ga, B, Zr, or Ti and 0

Kang, Sun-Ho (Naperville, IL); Amine, Khalil (Downers Grove, IL)

2008-01-01T23:59:59.000Z

277

Efficient Simulation and Reformulation of Lithium-Ion Battery Models for Enabling Electric Transportation  

E-Print Network [OSTI]

Improving the efficiency and utilization of battery systems can increase the viability and cost-effectiveness of existing technologies for electric vehicles (EVs). Developing smarter battery management systems and advanced ...

Northrop, Paul W. C.

278

Develop high energy high power Li-ion battery cathode materials : a first principles computational study  

E-Print Network [OSTI]

lithium battery cathode. Electrochemical and Solid Statebattery performance of LiMn2O4 cathode. Solid State Ionics,

Xu, Bo; Xu, Bo

2012-01-01T23:59:59.000Z

279

Electrochemical characteristics of plasma-etched black silicon as anodes for Li-ion batteries  

SciTech Connect (OSTI)

Nanostructured silicon as an anode material for Li-ion batteries is produced for the first time by inductively coupled plasma–plasma etching of Si wafers in the black silicon regime. The microscopic structure strongly resembles other types of nanostructured silicon, with a well-arranged nanostructure possessing a sufficient porosity for accommodating large volume expansion. Despite these features, however, a high first-cycle irreversible capacity loss and a poor cycle life are observed. The main reason for these poor features is the formation of a thick solid-electrolyte interphase (SEI) layer related to the surface condition of the pristine nanostructured black silicon (b-Si) electrode. Therefore, the cycle life of the b-Si electrode is heavily influenced by the constant reformation of the SEI layer depending upon the surface composition in spite of the presence of nanostructured Si. In the fast lithiation experiments, the nanostructure region of the b-Si electrode is detached from the Si substrate owing to the kinetics difference between the lithium ion diffusion and the electron injection and phase transformation in the nanostructured Si region. This means that more Si substrate is involved in lithiation at high current rates. It is therefore important to maintain balance in the chemical kinetics during the lithiation of nanostructured Si electrodes with a Si substrate.

Lee, Gibaek; Wehrspohn, Ralf B., E-mail: ralf.b.wehrspohn@iwmh.fraunhofer.de [Fraunhofer Institute for Mechanics of Materials IWM, Halle (Saale) 06120, Germany and Department of Physics, Martin-Luther University, Halle (Saale) 06099 (Germany); Schweizer, Stefan L. [Department of Physics, Martin-Luther University, Halle (Saale) 06099 (Germany)

2014-11-01T23:59:59.000Z

280

Modeling Electrochemical Decomposition of Fluoroethylene Carbonate on Silicon Anode Surfaces in Lithium Ion Batteries  

E-Print Network [OSTI]

Fluoroethylene carbonate (FEC) shows promise as an electrolyte additive for improving passivating solid-electrolyte interphase (SEI) films on silicon anodes used in lithium ion batteries (LIB). We apply density functional theory (DFT), ab initio molecular dynamics (AIMD), and quantum chemistry techniques to examine excess-electron-induced FEC molecular decomposition mechanisms that lead to FEC-modified SEI. We consider one- and two-electron reactions using cluster models and explicit interfaces between liquid electrolyte and model Li(x)Si(y) surfaces, respectively. FEC is found to exhibit more varied reaction pathways than unsubstituted ethylene carbonate. The initial bond-breaking events and products of one- and two-electron reactions are qualitatively similar, with a fluoride ion detached in both cases. However, most one-electron products are charge-neutral, not anionic, and may not coalesce to form effective Li+-conducting SEI unless they are further reduced or take part in other reactions. The implications of these reactions to silicon-anode based LIB are discussed.

Kevin Leung; Susan B. Rempe; Michael E. Foster; Yuguang Ma; Julibeth M. Martinez del la Hoz; Na Sai; Perla B. Balbuena

2014-01-17T23:59:59.000Z

Note: This page contains sample records for the topic "ion batteries elucidated" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Organic salts as super-high rate capability materials for lithium-ion batteries Y. Y. Zhang, Y. Y. Sun, S. X. Du, H.-J. Gao, and S. B. Zhang  

E-Print Network [OSTI]

Organic salts as super-high rate capability materials for lithium-ion batteries Y. Y. Zhang, Y. Y of transition metal doped Li2S as cathode materials in lithium batteries J. Renewable Sustainable Energy 4 of electrode nanomaterials in lithium-ion battery: The effects of surface stress J. Appl. Phys. 112, 103507

Gao, Hongjun

282

Probing the Degradation Mechanisms in Electrolyte Solutions for Li-ion Batteries by In-Situ Transmission Electron Microscopy  

SciTech Connect (OSTI)

One of the goals in the development of new battery technologies is to find new electrolytes with increased electrochemical stability. In-situ (scanning) transmission electron microscopy ((S)TEM) using an electrochemical fluid cell provides the ability to rapidly and directly characterize electrode/electrolyte interfacial reactions under battery relevant electrochemical conditions. Furthermore, as the electron beam itself causes a localized electrochemical reaction when it interacts with the electrolyte, the breakdown products that occur during the first stages of battery operation can potentially be simulated and characterized using a straightforward in-situ liquid stage (without electrochemical biasing capabilities). In this paper, we have studied the breakdown of a range of inorganic/salt complexes that are used in state-of-the-art Li-ion battery systems. The results of the in-situ (S)TEM experiments matches with previous stability tests performed during battery operation and the breakdown products and mechanisms are also consistent with known mechanisms. This analysis indicates that in-situ liquid stage (S)TEM observations can be used to directly test new electrolyte designs and provide structural insights into the origin of the solid electrolyte interphase (SEI) formation mechanism.

Abellan Baeza, Patricia; Mehdi, Beata L.; Parent, Lucas R.; Gu, Meng; Park, Chiwoo; Xu, Wu; Zhang, Yaohui; Arslan, Ilke; Zhang, Jiguang; Wang, Chong M.; Evans, James E.; Browning, Nigel D.

2014-02-21T23:59:59.000Z

283

Electrochemical-thermal modeling and microscale phase change for passive internal thermal management of lithium ion batteries.  

SciTech Connect (OSTI)

A fully coupled electrochemical and thermal model for lithium-ion batteries is developed to investigate the impact of different thermal management strategies on battery performance. In contrast to previous modeling efforts focused either exclusively on particle electrochemistry on the one hand or overall vehicle simulations on the other, the present work predicts local electrochemical reaction rates using temperature-dependent data on commercially available batteries designed for high rates (C/LiFePO{sub 4}) in a computationally efficient manner. Simulation results show that conventional external cooling systems for these batteries, which have a low composite thermal conductivity ({approx}1 W/m-K), cause either large temperature rises or internal temperature gradients. Thus, a novel, passive internal cooling system that uses heat removal through liquid-vapor phase change is developed. Although there have been prior investigations of phase change at the microscales, fluid flow at the conditions expected here is not well understood. A first-principles based cooling system performance model is developed and validated experimentally, and is integrated into the coupled electrochemical-thermal model for assessment of performance improvement relative to conventional thermal management strategies. The proposed cooling system passively removes heat almost isothermally with negligible thermal resistances between the heat source and cooling fluid. Thus, the minimization of peak temperatures and gradients within batteries allow increased power and energy densities unencumbered by thermal limitations.

Fuller, Thomas F. (Georgia Institute of Technology, Atlanta, GA); Bandhauer, Todd (Georgia Institute of Technology, Atlanta, GA); Garimella, Srinivas (Georgia Institute of Technology, Atlanta, GA)

2012-01-01T23:59:59.000Z

284

Studies on Capacity Fade of Spinel-Based Li-Ion Batteries Ramadass Premanand, Anand Durairajan,* Bala Haran,** Ralph White,*** and  

E-Print Network [OSTI]

Studies on Capacity Fade of Spinel-Based Li-Ion Batteries Ramadass Premanand, Anand Durairajan of South Carolina, Columbia, South Carolina 29208, USA The performance of Cell-Batt® Li-ion cells using in Mn content with cycling. These studies indicate that capacity fade of spinel-based Li-ion cells can

285

Elucidating the event-by-event flow fluctuations in heavy-ion collisions via the event shape selection technique  

E-Print Network [OSTI]

The presence of large event-by-event flow fluctuations in heavy ion collisions at RHIC and the LHC provides an opportunity to study a broad class of flow observables. This paper explores the correlations among harmonic flow coefficients $v_n$ and their phases $\\Phi_n$, and the rapidity fluctuation of $v_n$. The study is carried out usin Pb+Pb events generated by the AMPT model with fixed impact parameter. The overall ellipticity/triangularity of events is varied by selecting on the eccentricities $\\epsilon_n$ or the magnitudes of the flow vector $q_n$ for n=2 and 3, respectively. The responses of the $v_n$, the event-plane correlations, and the rapidity fluctuations, to the change in $\\epsilon_n$ and $q_n$ are then systematized. Strong positive correlations are observed among all even harmonics $v_2, v_4$, and $v_6$ (all increase with $q_2$), between $v_2$ and $v_5$ (both increase with $q_2$) and between $v_3$ and $v_5$ (both increase with $q_3$), consistent with the effects of nonlinear collective response. In contrast, an anti-correlation is observed between $v_2$ and $v_3$ similar to that seen between $\\epsilon_2$ and $\\epsilon_3$. These correlation patterns are found to be independent of whether selecting on $q_n$ or $\\epsilon_n$, validating the ability of $q_n$ in selecting the initial geometry. A forward/backward asymmetry of $v_n(\\eta)$ is observed for events selected on $q_n$ but not on $\\epsilon_n$, reflecting dynamical fluctuations exposed by the $q_n$ selection. Many event-plane correlators show good agreement between $q_n$ and $\\epsilon_n$ selections, suggesting that their variations with $q_n$ are controlled by the change of $\\epsilon_n$ in the initial geometry. Hence these correlators may serve as promising observables for disentangling the fluctuations generated in various stages of the evolution of the matter created in heavy ion collisions.

Peng Huo; Jiangyong Jia; Soumya Mohapatra

2014-09-11T23:59:59.000Z

286

Cr, N-Codoped TiO2 Mesoporous Microspheres for Li-ion Rechargeable Batteries with Enhanced Electrochemical Performance  

SciTech Connect (OSTI)

Cr,N-codoped TiO2 mesoporous microspheres synthesized using hydrothermal and subsequent nitridation treatment, exhibited higher solubility of nitrogen, and improved electrical conductivity than N-doped TiO2, as anode for Lithium-ion rechargeable batteries, which led to improving charge-discharge capacity at 0.1 C and twice higher rate capability compared to that of nitrogen-doped TiO2 mesoporous microsphere at 10 C

Bi, Zhonghe [ORNL] [ORNL; Paranthaman, Mariappan Parans [ORNL] [ORNL; Guo, Bingkun [ORNL] [ORNL; Unocic, Raymond R [ORNL] [ORNL; Meyer III, Harry M [ORNL] [ORNL; Bridges, Craig A [ORNL] [ORNL; Sun, Xiao-Guang [ORNL] [ORNL; Dai, Sheng [ORNL] [ORNL

2014-01-01T23:59:59.000Z

287

Mapping Particle Charges in Battery Electrodes  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

of batteries masks their chemical complexity. A typical lithium-ion battery in a cell phone consists of trillions of particles. When a lithium-ion battery is charged or...

288

A Yolk-Shell Design for Stabilized and Scalable Li-Ion Battery Alloy Anodes  

SciTech Connect (OSTI)

Silicon is regarded as one of the most promising anode materials for next generation lithium-ion batteries. For use in practical applications, a Si electrode must have high capacity, long cycle life, high efficiency, and the fabrication must be industrially scalable. Here, we design and fabricate a yolk-shell structure to meet all these needs. The fabrication is carried out without special equipment and mostly at room temperature. Commercially available Si nanoparticles are completely sealed inside conformal, thin, self-supporting carbon shells, with rationally designed void space in between the particles and the shell. The well-defined void space allows the Si particles to expand freely without breaking the outer carbon shell, therefore stabilizing the solid-electrolyte interphase on the shell surface. High capacity (?2800 mAh/g at C/10), long cycle life (1000 cycles with 74% capacity retention), and high Coulombic efficiency (99.84%) have been realized in this yolk-shell structured Si electrode.

Liu, Nian; Wu, Hui; Mcdowell, Matthew T.; Yao, Yan; Wang, Chong M.; Cui, Yi

2012-05-02T23:59:59.000Z

289

Interface Modifications by Anion Acceptors for High Energy Lithium Ion Batteries  

SciTech Connect (OSTI)

Li-rich, Mn-rich (LMR) layered composite, for example, Li[Li0.2Ni0.2Mn0.6]O2, has attracted extensive interests because of its highest energy density among all cathode candidates for lithium ion batteries (LIB). However, capacity degradation and voltage fading are the major challenges associated with this series of layered composite, which plagues its practical application. Herein, we demonstrate that anion receptor, tris(pentafluorophenyl)borane ((C6F5)3B, TPFPB), substantially enhances the cycling stability and alleviates the voltage degradation of LMR. In the presence of 0.2 M TPFPB, Li[Li0.2Ni0.2Mn0.6]O2 shows capacity retention of 81% after 300 cycles. It is proposed that TPFPB effectively confines the highly active oxygen species released from structural lattice through its strong coordination ability and high oxygen solubility. The electrolyte decomposition caused by the oxygen species attack is therefore largely mitigated, forming reduced amount of byproducts on the cathode surface. Additionally, other salts such as insulating LiF derived from electrolyte decomposition are also soluble in the presence of TPFPB. The collective effects of TPFPB mitigate the accumulation of parasitic reaction products and stabilize the interfacial resistances between cathode and electrolyte during extended cycling, thus significantly improving the cycling performance of Li[Li0.2Ni0.2Mn0.6]O2.

Zheng, Jianming; Xiao, Jie; Gu, Meng; Zuo, Pengjian; Wang, Chong M.; Zhang, Jiguang

2014-03-15T23:59:59.000Z

290

Fused ring and linking groups effect on overcharge protection for lithium-ion batteries.  

SciTech Connect (OSTI)

The derivatives of 1,3-benzodioxan (DBBD1) and 1,4-benzodioxan (DBBD2) bearing two tert-butyl groups have been synthesized as new redox shuttle additives for overcharge protection of lithium-ion batteries. Both compounds exhibit a reversible redox wave over 4 V vs Li/Li{sup +} with better solubility in a commercial electrolyte (1.2 M LiPF{sub 6}) dissolved in ethylene carbonate/ethyl methyl carbonate (EC/EMC 3/7) than the di-tert-butyl-substituted 1,4-dimethoxybenzene (DDB). The electrochemical stability of DBBD1 and DBBD2 was tested under charge/discharge cycles with 100% overcharge at each cycle in MCMB/LiFePO{sub 4} and Li{sub 4}Ti{sub 5}O{sub 12}/LiFePO{sub 4} cells. DBBD2 shows significantly better performance than DBBD1 for both cell chemistries. The structural difference and reaction energies for decomposition have been studied by density functional calculations.

Weng, W.; Zhang, Z.; Redfern, P. C.; Curtiss, L. A.; Amine, K.

2011-02-01T23:59:59.000Z

291

E-Print Network 3.0 - advanced lithium-ion batteries Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Materials Reliability Division Collection: Materials Science 38 1 of 5 Copyright 2007 Tesla Motors Updated: December 19, 2007 The Tesla Roadster Battery System Summary: This...

292

Performance Characteristics of Lithium-ion Batteries of Various Chemistries for Plug-in Hybrid Vehicles  

E-Print Network [OSTI]

initial and life cycle costs of the battery. This paper hasbattery chemistries have the potential for longer cycle life which on a life cycle cost

Burke, Andrew; Miller, Marshall

2009-01-01T23:59:59.000Z

293

Hierarchically Structured Materials for Lithium Batteries  

SciTech Connect (OSTI)

Lithium-ion battery (LIB) is one of the most promising power sources to be deployed in electric vehicles (EV), including solely battery powered vehicles, plug-in hybrid electric vehicles, and hybrid electrical vehicles. With the increasing demand on devices of high energy densities (>500 Wh/kg) , new energy storage systems, such as lithium-oxygen (Li-O2) batteries and other emerging systems beyond the conventional LIB also attracted worldwide interest for both transportation and grid energy storage applications in recent years. It is well known that the electrochemical performances of these energy storage systems depend not only on the composition of the materials, but also on the structure of electrode materials used in the batteries. Although the desired performances characteristics of batteries often have conflict requirements on the micro/nano-structure of electrodes, hierarchically designed electrodes can be tailored to satisfy these conflict requirements. This work will review hierarchically structured materials that have been successfully used in LIB and Li-O2 batteries. Our goal is to elucidate 1) how to realize the full potential of energy materials through the manipulation of morphologies, and 2) how the hierarchical structure benefits the charge transport, promotes the interfacial properties, prolongs the electrode stability and battery lifetime.

Xiao, Jie; Zheng, Jianming; Li, Xiaolin; Shao, Yuyan; Zhang, Jiguang

2013-09-25T23:59:59.000Z

294

Flexographically Printed Rechargeable Zinc-based Battery for Grid Energy Storage  

E-Print Network [OSTI]

Performance for Lithium Batteries,” J. Electrochem. Soc. ,developments in lithium ion batteries,” Materials Sciencefor advanced lithium-ion batteries,” Journal of Power

Wang, Zuoqian

2013-01-01T23:59:59.000Z

295

Recovery of lithium and cobalt from waste lithium ion batteries of mobile phone  

SciTech Connect (OSTI)

Graphical abstract: Recovery of valuable metals from scrap batteries of mobile phone. - Highlights: • Recovery of Co and Li from spent LIBs was performed by hydrometallurgical route. • Under the optimum condition, 99.1% of lithium and 70.0% of cobalt were leached. • The mechanism of the dissolution of lithium and cobalt was studied. • Activation energy for lithium and cobalt were found to be 32.4 kJ/mol and 59.81 kJ/mol, respectively. • After metal recovery, residue was washed before disposal to the environment. - Abstract: In view of the stringent environmental regulations, availability of limited natural resources and ever increasing need of alternative energy critical elements, an environmental eco-friendly leaching process is reported for the recovery of lithium and cobalt from the cathode active materials of spent lithium-ion batteries of mobile phones. The experiments were carried out to optimize the process parameters for the recovery of lithium and cobalt by varying the concentration of leachant, pulp density, reductant volume and temperature. Leaching with 2 M sulfuric acid with the addition of 5% H{sub 2}O{sub 2} (v/v) at a pulp density of 100 g/L and 75 °C resulted in the recovery of 99.1% lithium and 70.0% cobalt in 60 min. H{sub 2}O{sub 2} in sulfuric acid solution acts as an effective reducing agent, which enhance the percentage leaching of metals. Leaching kinetics of lithium in sulfuric acid fitted well to the chemical controlled reaction model i.e. 1 ? (1 ? X){sup 1/3} = k{sub c}t. Leaching kinetics of cobalt fitted well to the model ‘ash diffusion control dense constant sizes spherical particles’ i.e. 1 ? 3(1 ? X){sup 2/3} + 2(1 ? X) = k{sub c}t. Metals could subsequently be separated selectively from the leach liquor by solvent extraction process to produce their salts by crystallization process from the purified solution.

Jha, Manis Kumar, E-mail: mkjha@nmlindia.org; Kumari, Anjan; Jha, Amrita Kumari; Kumar, Vinay; Hait, Jhumki; Pandey, Banshi Dhar

2013-09-15T23:59:59.000Z

296

Mechanical characterization of lithium-ion battery micro components for development of homogenized and multilayer material models  

E-Print Network [OSTI]

The overall battery research of the Impact and Crashworthiness Laboratory (ICL) at MIT has been focused on understanding the battery's mechanical properties so that individual battery cells and battery packs can be ...

Miller, Kyle M. (Kyle Mark)

2014-01-01T23:59:59.000Z

297

Recovery Act - Demonstration of Sodium Ion Battery for Grid Level Applications  

SciTech Connect (OSTI)

Aquion Energy received a $5.179 million cooperative research agreement under the Department of Energyâ??s Smart Grid Demonstration Program â?? Demonstration of Promising Energy Storage Technologies (Program Area 2.5) of FOA DE-FOE-0000036. The main objective of this project was to demonstrate Aquionâ??s low cost, grid-scale, ambient temperature sodium ion energy storage device. The centerpiece of the technology is a novel hybrid energy storage chemistry that has been proven in a laboratory environment. The objective was to translate these groundbreaking results from the small-batch, small-cell test environment to the pilot scale to enable significant numbers of multiple ampere-hour cells to be manufactured and assembled into test batteries. Aquion developed a proof of concept demonstration unit that showed similar performance and major cost improvement over existing technologies. Beyond minimizing cell and system cost, Aquion built a technology that is safe, environmentally benign and durable over many thousands of cycles as used in a variety of grid support roles. As outlined in the Program documents, the original goals of the project were to demonstrate a unit that: 1. Has a projected capital cost of less than $250/kWh at the pack level 2. A deep discharge cycle life of > 10,000 cycles 3. A volumetric energy density of >20 kWh/m3 4. Projected calendar life of over 10 years 5. A device that contains no hazardous materials and retains best in class safety characteristics. Through the course of this project Aquion developed its aqueous electrolyte electrochemical energy storage device to the point where large demonstration units (> 10 kWh) were able to function in grid-supporting functions detailed by their collaborators. Aquionâ??s final deliverable was an ~15 kWh system that has the ability to perform medium to long duration (> 2 hours) charge and discharge functions approaching 95% DC-DC efficiency. The system has functioned, and continues to function as predicted with no indication that it will not tolerate well beyond 10 calendar years and 10,000 cycles. It has been in continuous operation for more than 1 year with 1,000 cycles (of varying depth of discharge, including 100% depth of discharge) and no identifiable degradation to the system. The final thick electrode cell structure has shown an energy density of 25 kWh/m3 at a five hour (or greater) discharge time. The primary chemistry has remained non-toxic, containing no acids or other corrosive chemicals, and the battery units have passed numerous safety tests, including flame resistance testing. These tests have verified the claim that the device is safe to use and contains no hazardous materials. Current projections show costs at the pack level to offer best in class value and are competitive with lead-acid batteries, factoring in LCOE.

Wiley, Ted; Whitacre, Jay; Eshoo, Michael; Noland, James; Campbell, Williams; Spears, Christopher

2012-08-31T23:59:59.000Z

298

Fluorinated Phosphazene Co-solvents for Improved Thermal and Safety Performance in Lithium-Ion Battery Electrolytes  

SciTech Connect (OSTI)

The safety of lithium-ion batteries is coming under increased scrutiny as they are being adopted for large format applications especially in the vehicle transportation industry and for grid-scale energy storage. The primary short-comings of lithium-ion batteries are the flammability of the liquid electrolyte and sensitivity to high voltage and elevated temperatures. We have synthesized a series of non-flammable fluorinated phosphazene liquids and blended them with conventional carbonate solvents. While the use of these phosphazenes as standalone electrolytes is highly desirable, they simply do not satisfy all of the many requirements that must be met such as high LiPF6 solubility and low viscosity, thus we have used them as additives and co-solvents in blends with typical carbonates. The physical and electrochemical properties of the electrolyte blends were characterized, and then the blends were used to build 2032-type coin cells which were evaluated at constant current cycling rates from C/10 to C/1. We have evaluated the performance of the electrolytes by determining the conductivity, viscosity, flash point, vapor pressure, thermal stability, electrochemical window, cell cycling data, and the ability to form solid electrolyte interphase (SEI) films. This paper presents our results on a series of chemically similar fluorinated cyclic phosphazene trimers, the FM series, which has exhibited numerous beneficial effects on battery performance, lifetimes, and safety aspects.

Harry W. Rollins; Mason K. Harrup; Eric J. Dufek; David K. Jamison; Sergiy V. Sazhin; Kevin L. Gering; Dayna L. Daubaras

2014-10-01T23:59:59.000Z

299

PSM: Lithium-Ion Battery State of Charge (SOC) and Critical Surface Charge (CSC) Estimation using an Electrochemical Model-driven  

E-Print Network [OSTI]

PSM: Lithium-Ion Battery State of Charge (SOC) and Critical Surface Charge (CSC) Estimation using Abstract-- This paper presents a numerical calculation of the evolution of the spatially-resolved solid concentration in the two electrodes of a lithium-ion cell. The microscopic solid con- centration is driven

Stefanopoulou, Anna

300

Missouri Lithium-Ion Battery Company Hosts Tour With U.S. Deputy...  

Energy Savers [EERE]

Kokam's in Missouri are helping American workers to compete in the fast-growing advanced battery and energy storage industry," said Deputy Secretary of Energy Poneman. "We at the...

Note: This page contains sample records for the topic "ion batteries elucidated" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Unique battery with an active membrane separator having uniform physico-chemically functionalized ion channels and a method making the same  

DOE Patents [OSTI]

The invention relates to a unique battery having an active, porous membrane and method of making the same. More specifically the invention relates to a sealed battery system having a porous, metal oxide membrane with uniform, physicochemically functionalized ion channels capable of adjustable ionic interaction. The physicochemically-active porous membrane purports dual functions: an electronic insulator (separator) and a unidirectional ion-transporter (electrolyte). The electrochemical cell membrane is activated for the transport of ions by contiguous ion coordination sites on the interior two-dimensional surfaces of the trans-membrane unidirectional pores. The membrane material is designed to have physicochemical interaction with ions. Control of the extent of the interactions between the ions and the interior pore walls of the membrane and other materials, chemicals, or structures contained within the pores provides adjustability of the ionic conductivity of the membrane.

Gerald, II, Rex E. (Brookfield, IL); Ruscic, Katarina J. (Chicago, IL); Sears, Devin N. (Spruce Grove, CA); Smith, Luis J. (Natick, MA); Klingler, Robert J. (Glenview, IL); Rathke, Jerome W. (Homer Glen, IL)

2012-02-21T23:59:59.000Z

302

Development of High Energy Lithium Batteries for Electric Vehicles...  

Broader source: Energy.gov (indexed) [DOE]

Kasei * Focused on High Capacity Manganese Rich (HCMR TM ) cathodes & Silicon-Carbon composite anodes for Lithium ion batteries * Envia's high energy Li-ion battery materials...

303

Special Feature: Reducing Energy Costs with Better Batteries  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Scientific Computing Center (NERSC) are working to achieve this goal. New Anode Boots Capacity of Lithium-Ion Batteries Lithium-ion batteries are everywhere- in smart...

304

Final Progress Report for Linking Ion Solvation and Lithium Battery Electrolyte Properties  

SciTech Connect (OSTI)

The research objective of this proposal was to provide a detailed analysis of how solvent and anion structure govern the solvation state of Li+ cations in solvent-LiX mixtures and how this, in turn, dictates the electrolyte physicochemical and electrochemical properties which govern (in part) battery performance. Lithium battery electrolytes remain a poorly understood and hardly studied topic relative to the research devoted to battery electrodes. This is due to the fact that it is the electrodes which determine the energy (capacity) of the battery. The electrolyte, however, plays a crucial role in the practical energy density, power, low and/or high temperature performance, lifetime, safety, etc. which is achievable. The development within this project of a "looking glass" into the molecular interactions (i.e., solution structure) in bulk electrolytes through a synergistic experimental approach involving three research thrusts complements work by other researchers to optimize multi-solvent electrolytes and efforts to understand/control the electrode-electrolyte interfaces, thereby enabling the rational design of electrolytes for a wide variety of battery chemistries and applications (electrolytes-on-demand). The three research thrusts pursued include: (1) conduction of an in-depth analysis of the thermal phase behavior of diverse solvent-LiX mixtures, (2) exploration of the ionic association/solvate formation behavior of select LiX salts with a wide variety of solvents, and (3) linking structure to properties?determination of electrolyte physicochemical and electrochemical properties for comparison with the ionic association and phase behavior.

Henderson, Wesley

2014-08-29T23:59:59.000Z

305

Recycle Batteries CSM recycles a variety of battery types including automotive, sealed lead acid, nickel  

E-Print Network [OSTI]

metal hydride and lithium ion batteries. The use of these batteries is increasing as a green, nickel metal hydride and lithium ion batteries. Please contact EHS if you need an accumulation containerRecycle Batteries CSM recycles a variety of battery types including automotive, sealed lead acid

306

Kinetic investigation of catalytic disproportionation of superoxide ions in the non-aqueous electrolyte used in Li-air batteries  

DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

Superoxide reacts with carbonate solvents in Li–air batteries. Tris(pentafluorophenyl)borane is found to catalyze a more rapid superoxide (O2–) disproportionation reaction than the reaction between superoxide and propylene carbonate (PC). With this catalysis, the negative impact of the reaction between the electrolyte and O2– produced by the O2 reduction can be minimized. A simple kinetic study using ESR spectroscopy was reported to determine reaction orders and rate constants for the reaction between PC and superoxide, and the disproportionation of superoxide catalyzed by Tris(pentafluorophenyl)borane and Li ions. The reactions are found to be first order and the rate constants are 0.033 s–1 M–1, 0.020 s–1 M–1 and 0.67 s–1 M–1 for reactions with PC, Li ion and Tris(pentafluorophenyl)borane, respectively.

Wang, Qiang [Univ. of Massachusetts at Boston, Boston, MA (United States); Yang, Xiao -Qing [Brookhaven National Laboratory (BNL), Upton, NY (United States); Zheng, Doug [Univ. of Massachusetts at Boston, Boston, MA (United States); McKinnon, Meaghan E. [Univ. of Massachusetts at Boston, Boston, MA (United States); Qu, Deyang [Univ. of Massachusetts at Boston, Boston, MA (United States)

2015-01-01T23:59:59.000Z

307

Tailored Recovery of Carbons from Waste Tires for Enhanced Performance as Anodes in Lithium-ion Batteries  

SciTech Connect (OSTI)

Morphologically tailored pyrolysis-recovered carbon black is utilized in lithium-ion batteries as a potential solution for adding value to waste tire-rubber-derived materials. Micronized tire rubber was digested in a hot oleum bath to yield a sulfonated rubber slurry that was then filtered, washed, and compressed into a solid cake. Carbon was recovered from the modified rubber cake by pyrolysis in a nitrogen atmosphere. The chemical pretreatment of rubber produced a carbon monolith with higher yield than that from the control (a fluffy tire-rubber-derived carbon black). The carbon monolith showed a very small volume fraction of pores of widths 3 4 nm, reduced specific surface area, and an ordered assembly of graphitic domains. Electrochemical studies on the recovered-carbon-based anode revealed an improved Li-ion battery performance with higher reversible capacity than that of commercial carbon materials. Anodes made with a sulfonated tire-rubber-derived carbon and a control tire-rubber-derived carbon, respectively, exhibited an initial coulombic efficiency of 80% and 45%, respectively. The reversible capacity of the cell with the sulfonated carbon as anode was 400 mAh/g after 100 cycles, with nearly 100% coulombic efficiency. Our success in producing higher performance carbon material from waste tire rubber for potential use in energy storage applications adds a new avenue to tire rubber recycling.

Naskar, Amit K [ORNL; Bi, [ORNL; Saha, Dipendu [ORNL; Chi, Miaofang [ORNL; Bridges, Craig A [ORNL; Paranthaman, Mariappan Parans [ORNL

2014-01-01T23:59:59.000Z

308

Thermal Stability of LiPF6 Salt and Li-ion Battery ElectrolytesContaining LiPF6  

SciTech Connect (OSTI)

The thermal stability of the neat LiPF6 salt and of 1 molal solutions of LiPF6 in prototypical Li-ion battery solvents was studied with thermogravimetric analysis (TGA) and on-line FTIR. Pure LiPF6 salt is thermally stable up to 380 K in a dry inert atmosphere, and its decomposition path is a simple dissociation producing LiF as solid and PF5 as gaseous products. In the presence of water (300 ppm) in the carrier gas, its decomposition onset temperature is lowered as a result of direct thermal reaction between LiPF6 and water vapor to form POF3 and HF. No new products were observed in 1 molal solutions of LiPF6 in EC, DMC and EMC by on-line TGA-FTIR analysis. The storage of the same solutions in sealed containers at 358 K for 300 420 hrs. did not produce any significant quantity of new products as well. In particular, noalkylflurophosphates were found in the solutions after storage at elevated temperature. In the absence of either an impurity like alcohol or cathode active material that may (or may not) act as a catalyst, there is no evidence of thermally induced reaction between LiPF6 and the prototypical Li-ion battery solvents EC, PC, DMC or EMC.

Yang, Hui; Zhuang, Guorong V.; Ross Jr., Philip N.

2006-03-08T23:59:59.000Z

309

Three-dimensional graphene/LiFePO{sub 4} nanostructures as cathode materials for flexible lithium-ion batteries  

SciTech Connect (OSTI)

Graphical abstract: Graphene/LiFePO{sub 4} composites as a high-performance cathode material for flexible lithium-ion batteries have been prepared by using a co-precipitation method to synthesize graphene/LiFePO4 powders as precursors and then followed by a solvent evaporation process. - Highlights: • Flexible LiFePO{sub 4}/graphene films were prepared first time by a solvent evaporation process. • The flexible electrode exhibited a high discharge capacity without conductive additives. • Graphene network offers the electrode adequate strength to withstand repeated flexing. - Abstract: Three-dimensional graphene/LiFePO{sub 4} nanostructures for flexible lithium-ion batteries were successfully prepared by solvent evaporation method. Structural characteristics of flexible electrodes were investigated by X-ray diffraction (XRD), atomic force microscopy (AFM) and scanning electron microscopy (SEM). Electrochemical performance of graphene/LiFePO{sub 4} was examined by a variety of electrochemical testing techniques. The graphene/LiFePO{sub 4} nanostructures showed high electrochemical properties and significant flexibility. The composites with low graphene content exhibited a high capacity of 163.7 mAh g{sup ?1} at 0.1 C and 114 mAh g{sup ?1} at 5 C without further incorporation of conductive agents.

Ding, Y.H., E-mail: yhding@xtu.edu.cn [College of Chemical Engineering, Xiangtan University, Hunan 411105 (China); Institute of Rheology Mechanics, Xiangtan University, Hunan 411105 (China); Ren, H.M. [Institute of Rheology Mechanics, Xiangtan University, Hunan 411105 (China); Huang, Y.Y. [BTR New Energy Materials Inc., Shenzhen 518000 (China); Chang, F.H.; Zhang, P. [Institute of Rheology Mechanics, Xiangtan University, Hunan 411105 (China)

2013-10-15T23:59:59.000Z

310

Structural micro-porous carbon anode for rechargeable lithium-ion batteries  

DOE Patents [OSTI]

A secondary battery having a rechargeable lithium-containing anode, a cathode and a separator positioned between the cathode and anode with an organic electrolyte solution absorbed therein is provided. The anode comprises three-dimensional microporous carbon structures synthesized from polymeric high internal phase emulsions or materials derived from this emulsion source, i.e., granules, powders, etc.

Delnick, Frank M. (Albuquerque, NM); Even, Jr., William R. (Livermore, CA); Sylwester, Alan P. (Washington, DC); Wang, James C. F. (Livermore, CA); Zifer, Thomas (Manteca, CA)

1995-01-01T23:59:59.000Z

311

Structural micro-porous carbon anode for rechargeable lithium-ion batteries  

DOE Patents [OSTI]

A secondary battery having a rechargeable lithium-containing anode, a cathode and a separator positioned between the cathode and anode with an organic electrolyte solution absorbed therein is provided. The anode comprises three-dimensional microporous carbon structures synthesized from polymeric high internal phase emulsions or materials derived from this emulsion source, i.e., granules, powders, etc. 6 figs.

Delnick, F.M.; Even, W.R. Jr.; Sylwester, A.P.; Wang, J.C.F.; Zifer, T.

1995-06-20T23:59:59.000Z

312

STUDIES ON TWO CLASSES OF POSITIVE ELECTRODE MATERIALS FOR LITHIUM-ION BATTERIES  

SciTech Connect (OSTI)

The development of advanced lithium-ion batteries is key to the success of many technologies, and in particular, hybrid electric vehicles. In addition to finding materials with higher energy and power densities, improvements in other factors such as cost, toxicity, lifetime, and safety are also required. Lithium transition metal oxide and LiFePO{sub 4}/C composite materials offer several distinct advantages in achieving many of these goals and are the focus of this report. Two series of layered lithium transition metal oxides, namely LiNi{sub 1/3}Co{sub 1/3-y}M{sub y}Mn{sub 1/3}O{sub 2} (M=Al, Co, Fe, Ti) and LiNi{sub 0.4}Co{sub 0.2-y}M{sub y}Mn{sub 0.4}O{sub 2} (M = Al, Co, Fe), have been synthesized. The effect of substitution on the crystal structure is related to shifts in transport properties and ultimately to the electrochemical performance. Partial aluminum substitution creates a high-rate positive electrode material capable of delivering twice the discharge capacity of unsubstituted materials. Iron substituted materials suffer from limited electrochemical performance and poor cycling stability due to the degradation of the layered structure. Titanium substitution creates a very high rate positive electrode material due to a decrease in the anti-site defect concentration. LiFePO{sub 4} is a very promising electrode material but suffers from poor electronic and ionic conductivity. To overcome this, two new techniques have been developed to synthesize high performance LiFePO{sub 4}/C composite materials. The use of graphitization catalysts in conjunction with pyromellitic acid leads to a highly graphitic carbon coating on the surface of LiFePO{sub 4} particles. Under the proper conditions, the room temperature electronic conductivity can be improved by nearly five orders of magnitude over untreated materials. Using Raman spectroscopy, the improvement in conductivity and rate performance of such materials has been related to the underlying structure of the carbon films. The combustion synthesis of LiFePO4 materials allows for the formation of nanoscale active material particles with high-quality carbon coatings in a quick and inexpensive fashion. The carbon coating is formed during the initial combustion process at temperatures that exceed the thermal stability limit of LiFePO{sub 4}. The olivine structure is then formed after a brief calcination at lower temperatures in a controlled environment. The carbon coating produced in this manner has an improved graphitic character and results in superior electrochemical performance. The potential co-synthesis of conductive carbon entities, such as carbon nanotubes and fibers, is also briefly discussed.

Wilcox, James D.

2008-12-18T23:59:59.000Z

313

Fracture of electrodes in lithium-ion batteries caused by fast charging Kejie Zhao, Matt Pharr, Joost J. Vlassak, and Zhigang Suoa  

E-Print Network [OSTI]

Fracture of electrodes in lithium-ion batteries caused by fast charging Kejie Zhao, Matt Pharr distribution of lithium results in stresses that may cause the particle to fracture. The distributions of the particle, below which fracture is averted. © 2010 American Institute of Physics. doi:10.1063/1.3492617 I

314

Received 21 Dec 2012 | Accepted 26 Apr 2013 | Published 4 Jun 2013 Stable Li-ion battery anodes by in-situ  

E-Print Network [OSTI]

Stanford Institute for Materials and Energy Sciences, SLAC National Accelerator Laboratory, 2575 Sand Hill processes, mostly through nanos- tructured material design. Here we report incorporation of a conducting-ion batteries with high- energy density and long cycle life is of critical importance to address the ever

Cui, Yi

315

Preparation of novel carbon microfiber/carbon nanofiber-dispersed polyvinyl alcohol-based nanocomposite material for lithium-ion electrolyte battery separator  

E-Print Network [OSTI]

December 2012 Keywords: Li-ion battery separator Polyvinyl alcohol Carbon micro-nanofibers Suspension acetate to produce polyvinyl alcohol gel, ball-milling of the surfactant dispersed carbon micro of the polyvinyl alcohol gel formation, and the mixing of hydro- phobic reagents along with polyethylene glycol

Singh, Jayant K.

316

Composition-tailored synthesis of gradient transition metal precursor particles for lithium-ion battery cathode materials.  

SciTech Connect (OSTI)

We report the tailored synthesis of particles with internal gradients in transition metal composition aided by the use of a general process model. Tailored synthesis of transition metal particles was achieved using a coprecipitation reaction with tunable control over the process conditions. Gradients in the internal composition of the particles was monitored and confirmed experimentally by analysis of particles collected during regularly timed intervals. Particles collected from the reactor at the end of the process were used as the precursor material for the solid-state synthesis of Li{sub 1.2}(Mn{sub 0.62}Ni{sub 0.38}){sub 0.8}O{sub 2}, which was electrochemically evaluated as the active cathode material in a lithium battery. The Li{sub 1.2}(Mn{sub 0.62}Ni{sub 0.38}){sub 0.8}O{sub 2} material was the first example of a structurally integrated multiphase material with a tailored internal gradient in relative transition metal composition as the active cathode material in a lithium-ion battery. We believe our general synthesis strategy may be applied to produce a variety of new cathode materials with tunable interior, surface, and overall relative transition metal compositions.

Koenig, G. M.; Belharouak, I.; Deng, H.; Amine, K.; Sun, Y. K. (Chemical Sciences and Engineering Division)

2011-04-12T23:59:59.000Z

317

Density Functional Theory Simulations Predict New Materials for Magnesium-Ion Batteries (Fact Sheet), NREL Highlights, Science  

SciTech Connect (OSTI)

Multivalence is identified in the light element, B, through structure morphology. Boron sheets exhibit highly versatile valence, and the layered boron materials may hold the promise of a high-energy-density magnesium-ion battery. Practically, boron is superior to previously known multivalence materials, especially transition metal compounds, which are heavy, expensive, and often not benign. Based on density functional theory simulations, researchers at the National Renewable Energy Laboratory (NREL) have predicted a series of stable magnesium borides, MgB{sub x}, with a broad range of stoichiometries, 2 < x < 16, by removing magnesium atoms from MgB{sub 2}. The layered boron structures are preserved through an in-plane topological transformation between the hexagonal lattice domains and the triangular domains. The process can be reversibly switched as the charge transfer changes with Mg insertion/extraction. The mechanism of such a charge-driven transformation originates from the versatile valence state of boron in its planar form. The discovery of these new physical phenomena suggests the design of a high-capacity magnesium-boron battery with theoretical energy density 876 mAh/g and 1550 Wh/L.

Not Available

2011-10-01T23:59:59.000Z

318

Synthesis and Characterization of Lithium Bis(fluoromalonato)borate (LiBFMB) for Lithium Ion Battery Applications  

SciTech Connect (OSTI)

A new orthochelated salt, lithium bis(monofluoromalonato)borate (LiBFMB), has been synthesized and purified for the first time for application in lithium ion batteries. The presence of fluorine in the borate anion of LiBFMB increases its oxidation potential and also facilitates ion dissociation, as reflected by the ratio of ionic conductivity measured by electrochemical impedance spectroscopy ( exp) and that by ion diffusivity coefficients obtained using pulsed field gradient nuclear magnetic resonance (PFG-NMR) technique ( NMR). Half-cell tests using 5.0 V lithium nickel manganese oxide (LiNi0.5Mn1.5O4) as a cathode and EC/DMC/DEC as a solvent reveals that the impedance of the LiBFMB cell is much larger than those of LiPF6 and LiBOB based cells, which results in lower capacity and poor cycling performance of the former. XPS spectra of the cycled cathode electrode suggest that because of the stability of the LiBFMB salt, the solid electrolyte interphase (SEI) formed on the cathode surface is significantly different from those of LiPF6 and LiBOB based electrolytes, resulting in more solvent decomposition and thicker SEI layer. Initial results also indicate that using high dielectric constant solvent PC alters the surface chemistry, reduces the interfacial impedance, and enhances the performance of LiBFMB based 5.0V cell.

Liao, Chen [ORNL] [ORNL; Han, Kee Sung [ORNL] [ORNL; Baggetto, Loic [ORNL] [ORNL; Hillesheim, Daniel A [ORNL] [ORNL; Custelcean, Radu [ORNL] [ORNL; Lee, Dr. Eun-Sung [University of Texas at Austin] [University of Texas at Austin; Guo, Bingkun [ORNL] [ORNL; Bi, Zhonghe [ORNL] [ORNL; Jiang, Deen [ORNL] [ORNL; Veith, Gabriel M [ORNL] [ORNL; Hagaman, Edward {Ed} W [ORNL; Brown, Gilbert M [ORNL] [ORNL; Bridges, Craig A [ORNL] [ORNL; Paranthaman, Mariappan Parans [ORNL] [ORNL; Manthiram, Arumugam [University of Texas at Austin] [University of Texas at Austin; Dai, Sheng [ORNL] [ORNL; Sun, Xiao-Guang [ORNL] [ORNL

2014-01-01T23:59:59.000Z

319

Hydrothermal synthesis of flowerlike SnO{sub 2} nanorod bundles and their application for lithium ion battery  

SciTech Connect (OSTI)

SnO{sub 2} nanorod bundles were synthesized by hydrothermal method. Field-emission scanning electron microscopy and transmission electron microscopy images showed that the as-prepared flowerlike SnO{sub 2} nanorod bundles consist of tetragonal nanorods with size readily tunable. Their electrochemical properties and application as anode for lithium-ion battery were evaluated by galvanostatic discharge–charge testing and cycle voltammetry. SnO{sub 2} nanorod flowers possess improved discharge capacity of 694 mA h g{sup ?1} up to 40th cycle at 0.1 C. - Highlights: ? The flowerlike SnO{sub 2} nanorod bundles were synthesized by hydrothermal method. ? SnO{sub 2} nanorod bundles with tunable size by controlling concentration of SnCl{sub 4}. ? A probable formation mechanism of SnO{sub 2} nanorod bundles has been proposed.

Wen, Zhigang, E-mail: xh168688@126.com [School of Materials Science and Engineering, Central South University, Changsha 410083 (China); State Key Laboratory of Powder Metallurgy, Central South University, Changsha 410083 (China); Department of Chemistry and Chemical Engineering, Qiannan Normal College for Nationalities, Duyun 558000 (China); Zheng, Feng, E-mail: fzheng@mail.csu.edu.cn [School of Materials Science and Engineering, Central South University, Changsha 410083 (China); State Key Laboratory of Powder Metallurgy, Central South University, Changsha 410083 (China); Yu, Hongchun; Jiang, Ziran [School of Materials Science and Engineering, Central South University, Changsha 410083 (China); Liu, Kanglian [Department of Chemistry and Chemical Engineering, Qiannan Normal College for Nationalities, Duyun 558000 (China)

2013-02-15T23:59:59.000Z

320

Three-phase model for the reversible lithiation/delithiation of SnO anodes in Li-ion batteries  

E-Print Network [OSTI]

Using first-principles calculations, we propose a microscopic model to explain the reversible lithiation/delithiation of tin-oxide anodes in lithium-ion batteries. When the irreversible regime ends, the anode grains consist of layers of Li-oxide separated by Sn bilayers. During the following reversible lithiation, the Li-oxide undergoes two phase transformations that give rise to a Li-enrichment of the oxide and the formation of a SnLi composite. The anode grain structure stays layered and ordered with an effective theoretical reversible capacity of 4.5 Li per Sn atom. The predicted anode volume expansion and voltage profile agree well with experiments, contrary to existing models.

Pedersen, Andreas; Luisier, Mathieu

2015-01-01T23:59:59.000Z

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321

Bis(fluoromalonato)borate (BFMB) Anion Based Ionic Liquid As an Additive for Lithium-Ion Battery Electrolytes  

SciTech Connect (OSTI)

Propylene carbonate (PC) is a good solvent for lithium ion battery applications due to its low melting point and high dielectric constant. However, PC is easily intercalated into graphite causing it to exfoliate, killing its electrochemical performance. Here we report on the synthesis of a new ionic liquid electrolyte based on partially fluorinated borate anion, 1-butyl-1,2-dimethylimidazolium bis(fluoromalonato)borate (BDMIm.BFMB), which can be used as an additive in 1 M LiPF6/PC electrolyte to suppress graphite exfoliation and improve cycling performance. In addition, both PC and BDMIm.BFMB can be used synergistically as additive to 1.0M LiPF6/methyl isopropyl sulfone (MIPS) to dramatically improve its cycling performance. It is also found that the chemistry nature of the ionic liquids has dramatic effect on their role as additive in PC based electrolyte.

Sun, Xiao-Guang [ORNL] [ORNL; Liao, Chen [ORNL] [ORNL; Baggetto, Loic [ORNL] [ORNL; Guo, Bingkun [ORNL] [ORNL; Unocic, Raymond R [ORNL] [ORNL; Veith, Gabriel M [ORNL] [ORNL; Dai, Sheng [ORNL] [ORNL

2014-01-01T23:59:59.000Z

322

Binder-free Ge-three dimensional graphene electrodes for high-rate capacity Li-ion batteries  

SciTech Connect (OSTI)

A binder-free, high-rate Ge-three dimensional (3D) graphene composite was synthesized by directly depositing Ge film atop 3D graphene grown by microwave plasma chemical vapor deposition on Ni substrate. The Ge-3D graphene structure demonstrates excellent electrochemical performance as a lithium ion battery (LIB) anode with a reversible capacity of 1140 mAh g{sup ?1} at 1/3C over 100 cycles and 835 mAh g{sup ?1} at 8C after 60 cycles, and significantly a discharge capacity of 186 mAh g{sup ?1} was still achieved at 32C. The high capacity and outstanding stability of the Ge-3D graphene composite propose it as a promising electrode in high-performance thin film LIBs.

Wang, C. D.; Chui, Y. S.; Chen, X. F., E-mail: xianfeng.chen@cityu.edu.hk, E-mail: apwjzh@cityu.edu.hk; Zhang, W. J., E-mail: xianfeng.chen@cityu.edu.hk, E-mail: apwjzh@cityu.edu.hk [Center of Super-Diamond and Advanced Films (COSDAF) and Department of Physics and Materials Science, City University of Hong Kong, Hong Kong (China); Li, Y. [Center of Super-Diamond and Advanced Films (COSDAF) and Department of Physics and Materials Science, City University of Hong Kong, Hong Kong (China) [Center of Super-Diamond and Advanced Films (COSDAF) and Department of Physics and Materials Science, City University of Hong Kong, Hong Kong (China); Department of Polymer Science and Engineering, Soochow University, Suzhou 215123 (China)

2013-12-16T23:59:59.000Z

323

Batteries: Overview of Battery Cathodes  

SciTech Connect (OSTI)

The very high theoretical capacity of lithium (3829 mAh/g) provided a compelling rationale from the 1970's onward for development of rechargeable batteries employing the elemental metal as an anode. The realization that some transition metal compounds undergo reductive lithium intercalation reactions reversibly allowed use of these materials as cathodes in these devices, most notably, TiS{sub 2}. Another intercalation compound, LiCoO{sub 2}, was described shortly thereafter but, because it was produced in the discharged state, was not considered to be of interest by battery companies at the time. Due to difficulties with the rechargeability of lithium and related safety concerns, however, alternative anodes were sought. The graphite intercalation compound (GIC) LiC{sub 6} was considered an attractive candidate but the high reactivity with commonly used electrolytic solutions containing organic solvents was recognized as a significant impediment to its use. The development of electrolytes that allowed the formation of a solid electrolyte interface (SEI) on surfaces of the carbon particles was a breakthrough that enabled commercialization of Li-ion batteries. In 1990, Sony announced the first commercial batteries based on a dual Li ion intercalation system. These devices are assembled in the discharged state, so that it is convenient to employ a prelithiated cathode such as LiCoO{sub 2} with the commonly used graphite anode. After charging, the batteries are ready to power devices. The practical realization of high energy density Li-ion batteries revolutionized the portable electronics industry, as evidenced by the widespread market penetration of mobile phones, laptop computers, digital music players, and other lightweight devices since the early 1990s. In 2009, worldwide sales of Li-ion batteries for these applications alone were US$ 7 billion. Furthermore, their performance characteristics (Figure 1) make them attractive for traction applications such as hybrid electric vehicles (HEVs), plug-in hybrid electric vehicles (PHEVs), and electric vehicles (EVs); a market predicted to be potentially ten times greater than that of consumer electronics. In fact, only Liion batteries can meet the requirements for PHEVs as set by the U.S. Advanced Battery Consortium (USABC), although they still fall slightly short of EV goals. In the case of Li-ion batteries, the trade-off between power and energy shown in Figure 1 is a function both of device design and the electrode materials that are used. Thus, a high power battery (e.g., one intended for an HEV) will not necessarily contain the same electrode materials as one designed for high energy (i.e., for an EV). As is shown in Figure 1, power translates into acceleration, and energy into range, or miles traveled, for vehicular uses. Furthermore, performance, cost, and abuse-tolerance requirements for traction batteries differ considerably from those for consumer electronics batteries. Vehicular applications are particularly sensitive to cost; currently, Li-ion batteries are priced at about $1000/kWh, whereas the USABC goal is $150/kWh. The three most expensive components of a Li-ion battery, no matter what the configuration, are the cathode, the separator, and the electrolyte. Reduction of cost has been one of the primary driving forces for the investigation of new cathode materials to replace expensive LiCoO{sub 2}, particularly for vehicular applications. Another extremely important factor is safety under abuse conditions such as overcharge. This is particularly relevant for the large battery packs intended for vehicular uses, which are designed with multiple cells wired in series arrays. Premature failure of one cell in a string may cause others to go into overcharge during passage of current. These considerations have led to the development of several different types of cathode materials, as will be covered in the next section. Because there is not yet one ideal material that can meet requirements for all applications, research into cathodes for Li-ion batteries is, as of this writ

Doeff, Marca M

2010-07-12T23:59:59.000Z

324

STUDIES ON TWO CLASSES OF POSITIVE ELECTRODE MATERIALS FOR LITHIUM-ION BATTERIES  

E-Print Network [OSTI]

the lithium- transition metal electrostatic interaction. Thecation electrostatic interactions. 1 Lithium ions occupy theinteractions or by inhibiting the complete removal of lithium

Wilcox, James D.

2010-01-01T23:59:59.000Z

325

Li-Ion Battery with LiFePO4 Cathode and Li4Ti5O12 Anode for Stationary Energy Storage  

SciTech Connect (OSTI)

i-ion batteries based on commercially available LiFePO4 cathode and Li4Ti5O12 anode were investigated for potential stationary energy storage applications. The full cell that operated at flat 1.85V demonstrated stable cycling for 200 cycles followed by a rapid fade. A significant improvement in cycling stability was achieved via Ketjen black coating of the cathode. A Li-ion full cell with Ketjen black modified LiFePO4 cathode and an unmodified Li4Ti5O12 anode exhibited negligible fade after more than 1200 cycles with a capacity of ~130mAh/g. The improved stability, along with its cost-effectiveness, environmentally benignity and safety, make the LiFePO4/ Li4Ti5O12 Li-ion battery a promising option of storing renewable energy.

Wang, Wei; Choi, Daiwon; Yang, Zhenguo

2013-01-01T23:59:59.000Z

326

Battery Charger Efficiency  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

of batteries. * The battery charger could be used to charge a single battery, single battery bank, multiple batteries or multiple battery banks * The dominant batteries in...

327

Battery utilizing ceramic membranes  

DOE Patents [OSTI]

A thin film battery is disclosed based on the use of ceramic membrane technology. The battery includes a pair of conductive collectors on which the materials for the anode and the cathode may be spin coated. The separator is formed of a porous metal oxide ceramic membrane impregnated with electrolyte so that electrical separation is maintained while ion mobility is also maintained. The entire battery can be made less than 10 microns thick while generating a potential in the 1 volt range.

Yahnke, Mark S. (Berkeley, CA); Shlomo, Golan (Haifa, IL); Anderson, Marc A. (Madison, WI)

1994-01-01T23:59:59.000Z

328

Vehicle Technologies Office Merit Review 2014: Daikin Advanced Lithium Ion Battery Technology – High Voltage Electrolyte  

Broader source: Energy.gov [DOE]

Presentation given by Daikin America at 2014 DOE Hydrogen and Fuel Cells Program and Vehicle Technologies Office Annual Merit Review and Peer Evaluation Meeting about Daikin advanced lithium ion...

329

Advanced Electrolyte Additives for PHEV/EV Lithium-ion Battery  

Broader source: Energy.gov (indexed) [DOE]

Li-ion Cell Performance: For conventional electrolyte (for example 1.2M LiPF 6 ECEMC 37), the SEI additive is the performance improver. Artificial SEI forms prior the...

330

Cahn-Hilliard Reaction Model for Isotropic Li-ion Battery Particles  

E-Print Network [OSTI]

Using the recently developed Cahn-Hilliard reaction (CHR) theory, we present a simple mathematical model of the transition from solid-solution radial diffusion to two-phase shrinking-core dynamics during ion intercalation ...

Zeng, Yi

331

Surface-Modified Membrane as A Separator for Lithium-Ion Polymer Battery  

E-Print Network [OSTI]

This paper describes the fabrication of novel modified polyethylene (PE) membranes using plasma technology to create high-performance and cost-effective separator membranes for practical applications in lithium-ion polymer ...

Kim, Jun Young

332

New electrolytes and electrolyte additives to improve the low temperature performance of lithium-ion batteries  

SciTech Connect (OSTI)

In this program, two different approaches were undertaken to improve the role of electrolyte at low temperature performance - through the improvement in (i) ionic conductivity and (ii) interfacial behavior. Several different types of electrolytes were prepared to examine the feasibil.ity of using these new electrolytes in rechargeable lithium-ion cells in the temperature range of +40°C to -40°C. The feasibility studies include (a) conductivity measurements of the electrolytes, (b) impedance measurements of lithium-ion cells using the screened electrolytes with di.fferent electrochemical history such as [(i) fresh cells prior to formation cycles, (ii) after first charge, and (iii) after first discharge], (c) electrical performance of the cells at room temperatures, and (d) charge discharge behavior at various low temperatures. Among the different types of electrolytes investigated in Phase I and Phase II of this SBIR project, carbonate-based LiPF6 electrolytes with the proposed additives and the low viscous ester as a third component to the carbonate-based LiPF6 electrolytes show promising results at low temperatures. The latter electrolytes deliver over 80% of room temperature capacity at -20{degrees}C when the lithium-ion cells containing these electrolytes were charged at -20 °C. Also, there was no lithium plating when the lithium­-ion cells using C-C composite anode and LiPF{sub 6} in EC/EMC/MP electrolyte were charged at -20{degrees}C at C/5 rate. The studies of ionic conductivity and AC impedance of these new electrolytes, as well as the charge discharge characteristics of lithium-ion cells using these new electrolytes at various low temperatures provide new findings: The reduced capacity and power capability, as well as the problem of lithium plating at low temperatures charging of lithium-ion cells are primarily due to slow the lithium-ion intercalation/de-intercalation kinetics in the carbon structure.

Yang, Xiao-Qing

2008-08-31T23:59:59.000Z

333

The predicted crystal structure of Li4C6O6, an organic cathode material for Li-ion batteries, from first-principles multi-level computational methods  

E-Print Network [OSTI]

The predicted crystal structure of Li4C6O6, an organic cathode material for Li-ion batteries, from details for the electrochemical properties of these organic electrodes (chemical potential for Li ion the optimum positions of Li ions intercalated within each C6O6 framework. 3. We then optimized each

Goddard III, William A.

334

A Computational Investigation of Li(subscript 9)M(subscript 3)(P(subscript 2)O(subscript 7))(subscript 3)(PO(subscript 4))(subscript 2) (M = V, Mo) as Cathodes for Li Ion Batteries  

E-Print Network [OSTI]

Cathodes with high energy density and safety are sought to improve the performance of Li ion batteries for electric vehicle and consumer electronics applications. In this study, we examine the properties of the potential ...

Jain, Anubhav

335

ALS Technique Gives Novel View of Lithium Battery Dendrite Growth  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

ALS Technique Gives Novel View of Lithium Battery Dendrite Growth Print Lithium-ion batteries, popular in today's electronic devices and electric vehicles, could gain significant...

336

BROADBAND IDENTIFICATION OF BATTERY ELECTRICAL IMPEDANCE FOR HEV  

E-Print Network [OSTI]

­ CEA LETI/LITEN; P. Granjon ­ GIPSA-Lab; Abstract -- In recent years, Li-ion batteries have been for the broadband monitoring of a battery. Keywords-- battery impedance, spectroscopy, broadband signals, Li-ion system of EV and HEV. Li-ion battery technology is believed to be the most attractive

Paris-Sud XI, Université de

337

Layered Li1+x(Ni0.425Mn0.425Co0.15)1xO2 Positive Electrode Materials for Lithium-Ion Batteries  

E-Print Network [OSTI]

Layered Li1+x(Ni0.425Mn0.425Co0.15)1­xO2 Positive Electrode Materials for Lithium-Ion Batteries range decreased with overlithiation Keywords : Although LiCoO2 is suitable for the lithium-ion battery electrochemical performances. Recently lithium-rich manganese-based materials such as Li[NixLi(1/3­2x/3)Mn(2/3­x/3

Boyer, Edmond

338

Studies of ionic liquids in lithium-ion battery test systems  

SciTech Connect (OSTI)

In this work, thermal and electrochemical properties of neat and mixed ionic liquid - lithium salt systems have been studied. The presence of a lithium salt causes both thermal and phase-behavior changes. Differential scanning calorimeter DSC and thermal gravimetric analysis TGA were used for thermal analysis for several imidazolium bis(trifluoromethylsulfonyl)imide, trifluoromethansulfonate, BF{sub 4}, and PF{sub 6} systems. Conductivities and diffusion coefficient have been measured for some selected systems. Chemical reactions in electrode - ionic liquid electrolyte interfaces were studied by interfacial impedance measurements. Lithium-lithium and lithium-carbon cells were studied at open circuit and a charged system. The ionic liquids studied include various imidazolium systems that are already known to be electrochemically unstable in the presence of lithium metal. In this work the development of interfacial resistance is shown in a Li|BMIMBF{sub 4} + LiBF{sub 4}|Li cell as well as results from some cycling experiments. As the ionic liquid reacts with the lithium electrode the interfacial resistance increases. The results show the magnitude of reactivity due to reduction of the ionic liquid electrolyte that eventually has a detrimental effect on battery performance.

Salminen, Justin; Prausnitz, John M.; Newman, John

2006-06-01T23:59:59.000Z

339

One-pot synthesis of a metal–organic framework as an anode for Li-ion batteries with improved capacity and cycling stability  

SciTech Connect (OSTI)

Metal–organic framework is a kind of novel electrode materials for lithium ion batteries. Here, a 3D metal–organic framework Co{sub 2}(OH){sub 2}BDC (BDC=1,4-benzenedicarboxylate) was synthesized for the first time by the reaction of Co{sup 2+} with a bio-inspired renewable organic ligand 1,4-benzenedicarboxylic acid through a solvothermal method. As an anode material for lithium ion batteries, this material exhibited an excellent cyclic stability as well as a large reversible capacity of ca. 650 mA h g{sup ?1} at a current density of 50 mA g{sup ?1} after 100 cycles within the voltage range of 0.02–3.0 V, higher than that of other BDC based anode. - Graphical abstract: The PXRD pattern and the cycleability curves (inset) of Co{sub 2}(OH){sub 2}BDC. Display Omitted - Highlights: • Co{sub 2}(OH){sub 2}BDC was synthesized through a one pot solvothermal process. • The solvent had a great effect on the purity of this material. • This material was used as anode material for lithium ion batteries for the first time. • Co{sub 2}(OH){sub 2}BDC showed improved capacity and cycling stability.

Gou, Lei, E-mail: Leigou@chd.edu.cn; Hao, Li-Min; Shi, Yong-Xin; Ma, Shou-Long; Fan, Xiao-Yong; Xu, Lei; Li, Dong-Lin, E-mail: dlli@chd.edu.cn; Wang, Kang

2014-02-15T23:59:59.000Z

340

Hierarchical mesoporous/microporous carbon with graphitized frameworks for high-performance lithium-ion batteries  

SciTech Connect (OSTI)

A hierarchical meso-/micro-porous graphitized carbon with uniform mesopores and ordered micropores, graphitized frameworks, and extra-high surface area of ?2200 m{sup 2}/g, was successfully synthesized through a simple one-step chemical vapor deposition process. The commercial mesoporous zeolite Y was utilized as a meso-/ micro-porous template, and the small-molecule methane was employed as a carbon precursor. The as-prepared hierarchical meso-/micro-porous carbons have homogeneously distributed mesopores as a host for electrolyte, which facilitate Li{sup +} ions transport to the large-area micropores, resulting a high reversible lithium ion storage of 1000 mA h/g and a high columbic efficiency of 65% at the first cycle.

Lv, Yingying; Fang, Yin; Qian, Xufang; Tu, Bo [Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Laboratory of Advanced Materials, Fudan University, Shanghai 200433 (China); Wu, Zhangxiong [Department of Chemical Engineering, Monash University, Clayton, VIC 3800 (Australia); Asiri, Abdullah M. [Chemistry Department and The Center of Excellence for Advanced Materials Research, King Abdulaziz University, P.O. Box 80203, Jeddah 21589 (Saudi Arabia); Zhao, Dongyuan, E-mail: dyzhao@fudan.edu.cn [Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Laboratory of Advanced Materials, Fudan University, Shanghai 200433 (China); Department of Chemical Engineering, Monash University, Clayton, VIC 3800 (Australia)

2014-11-01T23:59:59.000Z

Note: This page contains sample records for the topic "ion batteries elucidated" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

In-Situ Transmission Electron Microscopy Probing of Native Oxide and Artificial Layers on Silicon Nanoparticles for Lithium Ion Batteries  

SciTech Connect (OSTI)

Surface modification of silicon nanoparticle via molecular layer deposition (MLD) has been recently proved to be an effective way for dramatically enhancing the cyclic performance in lithium ion batteries. However, the fundamental mechanism as how this thin layer of coating function is not known, which is even complicated by the inevitable presence of native oxide of several nanometers on the silicon nanoparticle. Using in-situ TEM, we probed in detail the structural and chemical evolution of both uncoated and coated silicon particles upon cyclic lithiation/delithation. We discovered that upon initial lithiation, the native oxide layer converts to crystalline Li2O islands, which essentially increases the impedance on the particle, resulting in ineffective lithiation/delithiation, and therefore low coulombic efficiency. In contrast, the alucone MLD coated particles show extremely fast, thorough and highly reversible lithiation behaviors, which are clarified to be associated with the mechanical flexibility and fast Li+/e- conductivity of the alucone coating. Surprisingly, the alucone MLD coating process chemically changes the silicon surface, essentially removing the native oxide layer and therefore mitigates side reaction and detrimental effects of the native oxide. This study provides a vivid picture of how the MLD coating works to enhance the coulombic efficiency and preserve capacity and clarifies the role of the native oxide on silicon nanoparticles during cyclic lithiation and delithiation. More broadly, this work also demonstrated that the effect of the subtle chemical modification of the surface during the coating process may be of equal importance as the coating layer itself.

He, Yang; Piper, Daniela M.; Gu, Meng; Travis, Jonathan J.; George, Steven M.; Lee, Se-Hee; Genc, Arda; Pullan, Lee; Liu, Jun; Mao, Scott X.; Zhang, Jiguang; Ban, Chunmei; Wang, Chong M.

2014-10-27T23:59:59.000Z

342

Towards First Principles prediction of Voltage Dependences of Electrolyte/Electrolyte Interfacial Processes in Lithium Ion Batteries  

E-Print Network [OSTI]

In lithium ion batteries, Li+ intercalation and processes associated with passivation of electrodes are governed by applied voltages, which are in turn associated with free energy changes of Li+ transfer (Delta G_t) between the solid and liquid phases. Using ab initio molecular dynamics (AIMD) and thermodynamic integration techniques, we compute Delta G_t for the virtual transfer of a Li+ from a LiC(6) anode slab, with pristine basal planes exposed, to liquid ethylene carbonate confined in a nanogap. The onset of delithiation, at Delta G_t=0, is found to occur on LiC(6) anodes with negatively charged basal surfaces. These negative surface charges are evidently needed to retain Li+ inside the electrode, and should affect passivation ("SEI") film formation processes. Fast electrolyte decomposition is observed at even larger electron surface densities. By assigning the experimentally known voltage (0.1 V vs. Li+/Li metal) to the predicted delithiation onset, an absolute potential scale is obtained. This enables ...

Leung, Kevin

2013-01-01T23:59:59.000Z

343

Batteries, mobile phones & small electrical devices  

E-Print Network [OSTI]

, mobile phones and data collection equipment. Lithium Ion batteries are used in mobile phones, laptopsBatteries, mobile phones & small electrical devices IN-BUILDING RECYCLING STATIONS. A full list of acceptable items: Sealed batteries ­excludes vented NiCad and Lead acid batteries Cameras Laser printer

344

High power rechargeable batteries Paul V. Braun  

E-Print Network [OSTI]

High power rechargeable batteries Paul V. Braun , Jiung Cho, James H. Pikul, William P. King storage Secondary batteries High energy density High power density Lithium ion battery 3D battery electrodes a b s t r a c t Energy and power density are the key figures of merit for most electrochemical

Braun, Paul

345

Platform Li-Ion Battery Risk Assessment Tool: Cooperative Research and Development Final Report, CRADA Number CRD-10-407  

SciTech Connect (OSTI)

Creare was awarded a Phase 1 STTR contract from the US Office of Naval Research, with a seven month period of performance from 6/28/2010 to 1/28/2011. The objectives of the STTR were to determine the feasibility of developing a software package for estimating reliability of battery packs, and develop a user interface to allow the designer to assess the overall impact on battery packs and host platforms for cell-level faults. NREL served as sub-tier partner to Creare, providing battery modeling and battery thermal safety expertise.

Smith, K.

2012-01-01T23:59:59.000Z

346

Cation-substituted spinel oxide and oxyfluoride cathodes for lithium ion batteries  

DOE Patents [OSTI]

The present invention includes compositions and methods of making cation-substituted and fluorine-substituted spinel cathode compositions by firing a LiMn.sub.2-y-zLi.sub.yM.sub.zO.sub.4 oxide with NH.sub.4HF.sub.2 at low temperatures of between about 300 and 700.degree. C. for 2 to 8 hours and a .eta. of more than 0 and less than about 0.50, mixed two-phase compositions consisting of a spinel cathode and a layered oxide cathode, and coupling them with unmodified or surface modified graphite anodes in lithium ion cells.

Manthiram, Arumugam; Choi, Wongchang

2014-05-13T23:59:59.000Z

347

High-Power Electrodes for Lithium-Ion Batteries | U.S. DOE Office of  

Office of Science (SC) Website

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched5 IndustrialIsadoreConnecticut Regions National11-12, 2005 HighMayHeavy-Ions|Science

348

Are Batteries Ready for Plug-in Hybrid Buyers?  

E-Print Network [OSTI]

237–253. Burke, A. , 2007. Batteries and ultracapacitors forresults with lithium-ion batteries. In: Proceedings (CD)locate/tranpol Are batteries ready for plug-in hybrid

Axsen, Jonn; Burke, Andy; Kurani, Kenneth S

2010-01-01T23:59:59.000Z

349

Cation-substituted spinel oxide and oxyfluoride cathodes for lithium ion batteries  

DOE Patents [OSTI]

The present invention includes compositions and methods of making cation-substituted and fluorine-substituted spinel cathode compositions by firing a LiMn2-y-zLiyMzO4 oxide with NH4HF2 at low temperatures of between about 300 and 700.degree. C. for 2 to 8 hours and a .eta. of more than 0 and less than about 0.50, mixed two-phase compositions consisting of a spinel cathode and a layered oxide cathode, and coupling them with unmodified or surface modified graphite anodes in lithium ion cells.

Manthiram, Arumugam; Choi, Wonchang

2010-05-18T23:59:59.000Z

350

Batteries for Plug-in Hybrid Electric Vehicles (PHEVs): Goals and the State of Technology circa 2008  

E-Print Network [OSTI]

safety and cost. Third, Li-Ion battery designs are betterattributes of one type of Li-Ion battery cannot necessarilycapabilities. In any case, Li-Ion battery technologies hold

Axsen, Jonn; Burke, Andy; Kurani, Kenneth S

2008-01-01T23:59:59.000Z

351

Self-Organized Amorphous TiO2 Nanotube Arrays on Porous Ti Foam for Rechargeable Lithium and Sodium Ion Batteries  

SciTech Connect (OSTI)

Self-organized amorphous TiO2 nanotube arrays (NTAs) were successfully fabricated on both Ti foil and porous Ti foam through electrochemical anodization techniques. The starting Ti foams were fabricated using ARCAM s Electron Beam Melting (EBM) technology. The TiO2 NTAs on Ti foam were used as anodes in lithium ion batteries; they exhibited high capacities of 103 Ahcm-2 at 10 Acm-2 and 83 Ahcm-2 at 500 Acm-2, which are two to three times higher than those achieved on the standard Ti foil, which is around 40 Ahcm-2 at 10 Acm-2 and 24 Ahcm-2 at 500 Acm-2, respectively. This improvement is mainly attributed to higher surface area of the Ti foam and higher porosity of the nanotube arrays layer grown on the Ti foam. In addition, a Na-ion half-cell composed of these NTAs anodes and Na metal showed a self-improving specific capacity upon cycling at 10 Acm-2. These results indicate that TiO2 NTAs grown on Ti porous foam are promising electrodes for Li-ion or Na-ion rechargeable batteries.

Bi, Zhonghe [ORNL; Paranthaman, Mariappan Parans [ORNL; Menchhofer, Paul A [ORNL; Dehoff, Ryan R [ORNL; Bridges, Craig A [ORNL; Chi, Miaofang [ORNL; Guo, Bingkun [ORNL; Sun, Xiao-Guang [ORNL; Dai, Sheng [ORNL

2013-01-01T23:59:59.000Z

352

Reinvestigation on the state-of-the-art nonaqueous carbonate electrolytes for 5 V Li-ion battery applications  

SciTech Connect (OSTI)

The charging voltage limits of mixed carbonate solvents for Li-ion batteries have been systematically investigated from 4.9 to 5.3 V in half cells using Cr-doped spinel cathode material LiNi0.45Cr0.05Mn1.5O4. We found that the stability of conventional carbonate electrolytes is strongly related to the stability and properties of the cathode materials at both lithiated and de-lithiated states. It is the first time to report that the conventional electrolytes based on mixtures of ethylene carbonate (EC) and linear carbonate (dimethyl carbonate - DMC, ethyl methyl carbonate - EMC, and diethyl carbonate - DEC) have shown very similar long-term cycling performance when cycled up to 5.2 V on LiNi0.45Cr0.05Mn1.5O4. The discharge capacity increases with the charge cutoff voltage and reaches the highest discharge capacity at 5.2 V. The capacity retention is about 87% after 500 cycles at 1C rate for all three carbonate mixtures when cycled between 3.0 V and 5.2V. The first-cycle efficiency has a maximum value at 5.1 V, with an average from 83% to 85% at C/10 rate. When cycled to 5.3 V, EC-DMC still shows good cycling performance but EC-EMC and EC-DEC show faster capacity fading. EC-DMC and EC-EMC have much better rate capability than EC-DEC. In addition, the first-cycle irreversible capacity loss increases with the cutoff voltage and the 'inactive' conductive carbon has also been found to be partly associated with the low first-cycle Coulombic efficiency at high voltages due to electrolyte decomposition and probably the PF6- anion irreversible intercalation.

Xu, Wu; Chen, Xilin; Ding, Fei; Xiao, Jie; Wang, Deyu; Pan, Anqiang; Zheng, Jianming; Li, Xiaohong S.; Padmaperuma, Asanga B.; Zhang, Jiguang

2012-09-01T23:59:59.000Z

353

Battery system  

DOE Patents [OSTI]

A battery module includes a plurality of battery cells and a system configured for passing a fluid past at least a portion of the plurality of battery cells in a parallel manner.

Dougherty, Thomas J; Wood, Steven J; Trester, Dale B; Andrew, Michael G

2013-08-27T23:59:59.000Z

354

Khalil Amine on Lithium-air Batteries  

ScienceCinema (OSTI)

Khalil Amine, materials scientist at Argonne National Laboratory, speaks on the new technology Lithium-air batteries, which could potentially increase energy density by 5-10 times over lithium-ion batteries.

Khalil Amine

2010-01-08T23:59:59.000Z

355

Michael Thackery on Lithium-air Batteries  

ScienceCinema (OSTI)

Michael Thackery, Distinguished Fellow at Argonne National Laboratory, speaks on the new technology Lithium-air batteries, which could potentially increase energy density by 5-10 times over lithium-ion batteries.

Michael Thackery

2010-01-08T23:59:59.000Z

356

Design and Simulation of Lithium Rechargeable Batteries  

E-Print Network [OSTI]

A New Rechargeable Plastic Li-Ion Battery," Lithium Batteryion battery developed at Bellcore in Red Bank, NJ.1-6 The experimental prototYpe cell has the configuration: Li

Doyle, C.M.

2010-01-01T23:59:59.000Z

357

Batteries: Overview of Battery Cathodes  

E-Print Network [OSTI]

M=Mn, Ni, Co) in Lithium Batteries at 50°C. Electrochem.Spinel Electrodes for Lithium Batteries. J. Am. Ceram. Soc.for Rechargeable Lithium Batteries. J. Power Sources 54:

Doeff, Marca M

2011-01-01T23:59:59.000Z

358

PHEV/EV Li-Ion Battery Second-Use Project, NREL (National Renewable Energy Laboratory) (Poster)  

SciTech Connect (OSTI)

Plug-in hybrid electric vehicles (PHEVs) and full electric vehicles (Evs) have great potential to reduce U.S. dependence on foreign oil and emissions. Battery costs need to be reduced by ~50% to make PHEVs cost competitive with conventional vehicles. One option to reduce initial costs is to reuse the battery in a second application following its retirement from automotive service and offer a cost credit for its residual value.

Newbauer, J.; Pesaran, A.

2010-05-01T23:59:59.000Z

359

LiMn{sub 2}O{sub 4} nanoparticles anchored on graphene nanosheets as high-performance cathode material for lithium-ion batteries  

SciTech Connect (OSTI)

Nanocrystalline LiMn{sub 2}O{sub 4}/graphene nanosheets nanocomposite has been successfully synthesized by a one-step hydrothermal method without post-heat treatment. In the nanocomposite, LiMn{sub 2}O{sub 4} nanoparticles of 10–30 nm in size are well crystallized and homogeneously anchored on the graphene nanosheets. The graphene nanosheets not only provide a highly conductive matrix for LiMn{sub 2}O{sub 4} nanoparticles but also effectively reduce the agglomeration of LiMn{sub 2}O{sub 4} nanoparticles. The nanocrystalline LiMn{sub 2}O{sub 4}/graphene nanosheets nanocomposite exhibited greatly improved electrochemical performance in terms of specific capacity, cycle performance, and rate capability compared with the bare LiMn{sub 2}O{sub 4} nanoparticles. The superior electrochemical performance of the nanocrystalline LiMn{sub 2}O{sub 4}/graphene nanosheets nanocomposite makes it promising as cathode material for high-performance lithium-ion batteries. - Graphical abstract: Nanocrystalline LiMn{sub 2}O{sub 4}/graphene nanosheets (GNS) nanocomposite exhibit superior cathode performance for lithium-ion batteries compared to the bare LiMn{sub 2}O{sub 4} nanoparticles. Display Omitted - Highlights: • LiMn{sub 2}O{sub 4}/graphene nanocomposite is synthesized by a one-step hydrothermal method. • LiMn{sub 2}O{sub 4} nanoparticles are uniformly anchored on the graphene nanosheets. • The nanocomposite exhibits excellent cathode performance for lithium-ion batteries.

Lin, Binghui; Yin, Qing; Hu, Hengrun; Lu, Fujia [School of Materials Science and Engineering, Nanjing University of Science and Technology, Xiaolingwei 200, Nanjing, Jiangsu 210094 (China); Xia, Hui, E-mail: xiahui@njust.edu.cn [School of Materials Science and Engineering, Nanjing University of Science and Technology, Xiaolingwei 200, Nanjing, Jiangsu 210094 (China); Herbert Gleiter Institute of Nanoscience, Nanjing University of Science and Technology, Nanjing 210094 (China)

2014-01-15T23:59:59.000Z

360

Amorphous Zn?GeO? Nanoparticles as Anodes with High Reversible Capacity and Long Cycling Life for Li-ion Batteries  

SciTech Connect (OSTI)

Amorphous and crystalline Zn?GeO? nanoparticles were prepared and characterized as anode materials for Li-ion batteries. A higher reversible specific capacity of 1250 mAh/g after 500 cycles and excellent rate capability were obtained for amorphous Zn?GeO? nanoparticles, compared to that of crystalline Zn?GeO? nanoparticles. Small particle size, amorphous phase and incorporation of zinc and oxygen contribute synergetically to the improved performance by effectively mitigating the huge volume variations during lithiation and delithiation process.

Yi, Ran; Feng, Jinkui; Lv, Dongping; Gordin, Mikhail; Chen, Shuru; Choi, Daiwon; Wang, Donghai

2013-07-30T23:59:59.000Z

Note: This page contains sample records for the topic "ion batteries elucidated" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

A New Charging Method for Li-ion Batteries: Dependence of the charging time on the Direction of an Additional Oscillating Field  

E-Print Network [OSTI]

We have recently proposed a new method for charging Li-ion batteries based on large-scale molecular dynamics studies (I. Abou Hamad et al, Phys. Chem. Chem. Phys., 12, 2740 (2010)). Applying an additional oscillating electric field in the direction perpendicular to the graphite sheets of the anode showed an exponential decrease in charging time with increasing amplitude of the applied oscillating field. Here we present new results exploring the effect on the charging time of changing the orientation of the oscillating field. Results for oscillating fields in three orthogonal directions are compared.

Hamad, I Abou; Wipf, D O; Rikvold, P A

2010-01-01T23:59:59.000Z

362

Battery utilizing ceramic membranes  

DOE Patents [OSTI]

A thin film battery is disclosed based on the use of ceramic membrane technology. The battery includes a pair of conductive collectors on which the materials for the anode and the cathode may be spin coated. The separator is formed of a porous metal oxide ceramic membrane impregnated with electrolyte so that electrical separation is maintained while ion mobility is also maintained. The entire battery can be made less than 10 microns thick while generating a potential in the 1 volt range. 2 figs.

Yahnke, M.S.; Shlomo, G.; Anderson, M.A.

1994-08-30T23:59:59.000Z

363

Are batteries ready for plug-in hybrid buyers?  

E-Print Network [OSTI]

Of the battery chemistries discussed, only Li-ion shows the2008) battery researchers continue to develop Li-ionbattery chemistries: nickel-metal hydride (NiMH) and lithium-ion (Li-

Axsen, Jonn; Kurani, Kenneth S.; Burke, Andrew

2008-01-01T23:59:59.000Z

364

Are Batteries Ready for Plug-in Hybrid Buyers?  

E-Print Network [OSTI]

Of the battery chemistries discussed, only Li-ion shows the2008) battery researchers continue to develop Li-ionbattery chemistries: nickel- metal hydride (NiMH) and lithium-ion (Li-

Axsen, Jonn; Burke, Andy; Kurani, Kenneth S

2010-01-01T23:59:59.000Z

365

Are Batteries Ready for Plug-in Hybrid Buyers?  

E-Print Network [OSTI]

Of the battery chemistries discussed, only Li-ion shows the2008) battery researchers continue to develop Li-ionbattery chemistries: nickel-metal hydride (NiMH) and lithium-ion (Li-

Axsen, Jonn; Kurani, Kenneth S; Burke, Andy

2009-01-01T23:59:59.000Z

366

Microwave Plasma Chemical Vapor Deposition of Nano-Structured Sn/C Composite Thin-Film Anodes for Li-ion Batteries  

E-Print Network [OSTI]

Meeting on Lithium Batteries, Biarritz, France, June 18–23,Sn/C anodes for lithium batteries. Thin layers of graphiticKeywords: Sn/C; Lithium Batteries; Anode; Plasma; Microwave

Marcinek, M.

2008-01-01T23:59:59.000Z

367

ESTABLISHING SUSTAINABLE US HEV/PHEV MANUFACTURING BASE: STABILIZED LITHIUM METAL POWDER, ENABLING MATERIAL AND REVOLUTIONARY TECHNOLOGY FOR HIGH ENERGY LI-ION BATTERIES  

SciTech Connect (OSTI)

FMC Lithium Division has successfully completed the project “Establishing Sustainable US PHEV/EV Manufacturing Base: Stabilized Lithium Metal Powder, Enabling Material and Revolutionary Technology for High Energy Li-ion Batteries”. The project included design, acquisition and process development for the production scale units to 1) produce stabilized lithium dispersions in oil medium, 2) to produce dry stabilized lithium metal powders, 3) to evaluate, design and acquire pilot-scale unit for alternative production technology to further decrease the cost, and 4) to demonstrate concepts for integrating SLMP technology into the Li- ion batteries to increase energy density. It is very difficult to satisfy safety, cost and performance requirements for the PHEV and EV applications. As the initial step in SLMP Technology introduction, industry can use commercially available LiMn2O4 or LiFePO4, for example, that are the only proven safer and cheaper lithium providing cathodes available on the market. Unfortunately, these cathodes alone are inferior to the energy density of the conventional LiCoO2 cathode and, even when paired with the advanced anode materials, such as silicon composite material, the resulting cell will still not meet the energy density requirements. We have demonstrated, however, if SLMP Technology is used to compensate for the irreversible capacity in the anode, the efficiency of the cathode utilization will be improved and the cost of the cell, based on the materials, will decrease.

Yakovleva, Marina

2012-12-31T23:59:59.000Z

368

Optimal Energy Management Strategy including Battery Health through Thermal  

E-Print Network [OSTI]

: Energy management strategy, Plug-in hybrid electric vehicles, Li-ion battery aging, thermal management process of Li-ion batteries is very intricate and is currently the subject of many studies, Gyan et al interested in a thorough analysis on Li-ion battery aging can refer to Vetter et al. (2005), Broussely et al

Paris-Sud XI, Université de

369

High performance batteries with carbon nanomaterials and ionic liquids  

DOE Patents [OSTI]

The present invention is directed to lithium-ion batteries in general and more particularly to lithium-ion batteries based on aligned graphene ribbon anodes, V.sub.2O.sub.5 graphene ribbon composite cathodes, and ionic liquid electrolytes. The lithium-ion batteries have excellent performance metrics of cell voltages, energy densities, and power densities.

Lu, Wen (Littleton, CO)

2012-08-07T23:59:59.000Z

370

Highly Reversible Li-Ion Intercalating MoP2 Nanoparticle Cluster Anode for Lithium Rechargeable Batteries  

E-Print Network [OSTI]

Highly Reversible Li-Ion Intercalating MoP2 Nanoparticle Cluster Anode for Lithium Rechargeable, metal phosphides MPn, M = transition metal ions as attractive Li-ion anode materials have received lithium reactions, i MPn LixMPn simple Li-ion interca- lation and ii MPn M LixM + LixP alloying followed

Cho, Jaephil

371

A High-Performance PHEV Battery Pack  

Broader source: Energy.gov (indexed) [DOE]

LCD Glass OLED Materials Color Filter Lithium-Ion Batteries for - Mobile Phone, Laptop, Power Tool - Hybrid & Electric Vehicles - ESS Energy Solution(10%) Petro-...

372

Electrochemical and microstructural studies of AlPO?-nanoparticle coated LiCoO? for lithium-ion batteries  

E-Print Network [OSTI]

AlPO?-nanoparticle coated LiCoO? is studied as a positive electrode for lithium rechargeable batteries for a high-voltage charge limit of 4.7V. To understand the role of the coating in transport phenomena and in deintercalation ...

Appapillai, Anjuli T. (Anjuli Tara)

2006-01-01T23:59:59.000Z

373

Jeff Chamberlain on Lithium-air batteries  

ScienceCinema (OSTI)

Jeff Chamberlain, technology transfer expert at Argonne National Laboratory, speaks on the new technology Lithium-air batteries, which could potentially increase energy density by 5-10 times over lithium-ion batteries. More information at http://www.anl.gov/Media_Center/News/2009/batteries090915.html

Chamberlain, Jeff

2013-04-19T23:59:59.000Z

374

Jeff Chamberlain on Lithium-air batteries  

SciTech Connect (OSTI)

Jeff Chamberlain, technology transfer expert at Argonne National Laboratory, speaks on the new technology Lithium-air batteries, which could potentially increase energy density by 5-10 times over lithium-ion batteries. More information at http://www.anl.gov/Media_Center/News/2009/batteries090915.html

Chamberlain, Jeff

2009-01-01T23:59:59.000Z

375

Michael Thackeray on Lithium-air Batteries  

ScienceCinema (OSTI)

Michael Thackeray, Distinguished Fellow at Argonne National Laboratory, speaks on the new technology Lithium-air batteries, which could potentially increase energy density by 5-10 times over lithium-ion batteries. More information at http://www.anl.gov/Media_Center/News/2009/batteries090915.html

Thackeray, Michael

2013-04-19T23:59:59.000Z

376

Dual Phase Li4 Ti5O12–TiO2 Nanowire Arrays As Integrated Anodes For High-rate Lithium-ion Batteries  

SciTech Connect (OSTI)

Lithium titanate (Li4Ti5O12) is well known as a zero strain material inherently, which provides excellent long cycle stability as a negative electrode for lithium ion batteries. However, the low specific capacity (175 mA h g?1) limits it to power batteries although the low electrical conductivity is another intrinsic issue need to be solved. In this work, we developed a facile hydrothermal and ion-exchange route to synthesize the self-supported dual-phase Li4Ti5O12–TiO2 nanowire arrays to further improve its capacity as well as rate capability. The ratio of Li4Ti5O12 to TiO2 in the dual phase Li4Ti5O12–TiO2 nanowire is around 2:1. The introduction of TiO2 into Li4Ti5O12 increases the specific capacity. More importantly, by interface design, it creates a dual-phase nanostructure with high grain boundary density that facilitates both electron and Li ion transport. Compared with phase-pure nanowire Li4Ti5O12 and TiO2 nanaowire arrays, the dual-phase nanowire electrode yielded superior rate capability (135.5 at 5 C, 129.4 at 10 C, 120.2 at 20 C and 115.5 mA h g?1 at 30 C). In-situ transmission electron microscope clearly shows the near zero deformation of the dual phase structure, which explains its excellent cycle stability.

Liao, Jin; Chabot, Victor; Gu, Meng; Wang, Chong M.; Xiao, Xingcheng; Chen, Zhongwei

2014-08-19T23:59:59.000Z

377

E-Print Network 3.0 - aluminum air batteries Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

aluminum- ion battery that will be a significant contribution to 21st century energy storage... . Because an aluminum battery is trivalent, it has a ... Source:...

378

Designing Silicon Nanostructures for High Energy Lithium Ion...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Designing Silicon Nanostructures for High Energy Lithium Ion Battery Anodes Designing Silicon Nanostructures for High Energy Lithium Ion Battery Anodes 2012 DOE Hydrogen and Fuel...

379

Highly Reversible Mg Insertion in Nanostructured Bi for Mg Ion...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Reversible Mg Insertion in Nanostructured Bi for Mg Ion Batteries. Highly Reversible Mg Insertion in Nanostructured Bi for Mg Ion Batteries. Abstract: Rechargeable magnesium...

380

Microwave Plasma Chemical Vapor Deposition of Carbon Coatings on LiNi1/3Co1/3Mn1/3O2 for Li-Ion Battery Composite Cathodes  

E-Print Network [OSTI]

O 2 for Li-ion Battery Composite Cathodes Marek L. MarcinekRaman spectroscopy. The composite LiNi 1/3 Co 1/3 Mn 1/3 O 2electronic contact within the composite cathode and does not

Doeff, M.M.

2012-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "ion batteries elucidated" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Synthesis and electrochemical performances of amorphous carbon-coated Sn-Sb particles as anode material for lithium-ion batteries  

SciTech Connect (OSTI)

The amorphous carbon coating on the Sn-Sb particles was prepared from aqueous glucose solutions using a hydrothermal method. Because the outer layer carbon of composite materials is loose cotton-like and porous-like, it can accommodate the expansion and contraction of active materials to maintain the stability of the structure, and hinder effectively the aggregation of nano-sized alloy particles. The as-prepared composite materials show much improved electrochemical performances as anode materials for lithium-ion batteries compared with Sn-Sb alloy and carbon alone. This amorphous carbon-coated Sn-Sb particle is extremely promising anode materials for lithium secondary batteries and has a high potentiality in the future use. - Graphical abstract: The amorphous carbon coating on the Sn-Sb particles was prepared from aqueous glucose solutions using a hydrothermal method. Because the outer layer carbon of composite materials is loose cotton-like and porous-like, it can accommodate the expansion and contraction of active materials to maintain the stability of the structure, and hinder effectively the aggregation of nano-sized alloy particles.

Wang Zhong [State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871 (China); General Research Institute for Nonferrous Metal, Beijing 100088 (China); Tian Wenhuai [Department of Materials Physics and Chemistry, University of Science and Technology Beijing, Beijing 100083 (China); Liu Xiaohe [Department of Inorganic Materials, Central South University, Changsha, Hunan 410083 (China); Yang Rong [State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871 (China); Li Xingguo [State Key Laboratory of Rare Earth Materials Chemistry and Applications, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871 (China)], E-mail: xgli@pku.edu.cn

2007-12-15T23:59:59.000Z

382

Solid electrolytes for battery applications a theoretical perspective a  

E-Print Network [OSTI]

solid state batteries at the present time. · Several companies are involved in all solids state batterySolid electrolytes for battery applications ­ a theoretical perspective a Natalie Holzwarth ion batteries Solid electrolytes Advantages 1. Excellent chemical and physical stability. 2. Perform

Holzwarth, Natalie

383

A Facile synthesis of flower-like Co{sub 3}O{sub 4} porous spheres for the lithium-ion battery electrode  

SciTech Connect (OSTI)

The porous hierarchical spherical Co{sub 3}O{sub 4} assembled by nanosheets have been successfully fabricated. The porosity and the particle size of the product can be controlled by simply altering calcination temperature. SEM, TEM and SAED were performed to confirm that mesoporous Co{sub 3}O{sub 4} nanostructures are built-up by numerous nanoparticles with random attachment. The BET specific surface area and pore size of the product calcined at 280 deg. C are 72.5 m{sup 2} g{sup -1} and 4.6 nm, respectively. Our experiments further demonstrated that electrochemical performances of the synthesized products working as an anode material of lithium-ion battery are strongly dependent on the porosity. - Graphical abstract: The flower-like Co{sub 3}O{sub 4} porous spheres with hierarchical structure have been successfully prepared via a simple calcination process using cobalt hydroxide as precursor.

Zheng Jun; Liu Jing; Lv Dongping; Kuang Qin [State Key Laboratory for Physical Chemistry of Solid Surfaces and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China); Jiang Zhiyuan, E-mail: zyjiang@xmu.edu.c [State Key Laboratory for Physical Chemistry of Solid Surfaces and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China); Xie Zhaoxiong; Huang Rongbin; Zheng Lansun [State Key Laboratory for Physical Chemistry of Solid Surfaces and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005 (China)

2010-03-15T23:59:59.000Z

384

Direct Access to Mesoporous Crystalline TiO2/Carbon Composites with Large and Uniform Pores for Use as Anode Materials in Lithium Ion Batteries  

SciTech Connect (OSTI)

Mesoporous and highly crystalline TiO{sub 2} (anatase)/carbon composites with large (>5?nm) and uniform pores were synthesized using PI-b-PEO block copolymers as structure directing agents. Pore sizes could be tuned by utilizing block copolymers with different molecular weights. The resulting mesoporous TiO{sub 2}/carbon was successfully used as an anode material for Li ion batteries. Without addition of conducting aid (Super P), the electrode showed high capacity during the first insertion/desertion cycle due to carbon wiring inside the walls of mesoporous TiO{sub 2}/carbon. The electrode further showed stable cycle performance up to 50 cycles and the specific charge capacity at 30?C was 38?mA h (g of TiO{sub 2}){sup ?1}, which indicates CCM-TiO{sub 2}/carbon can be used as a material for high rate use.

Lee, Jinwoo; Jung, Yoon S.; Warren, Scott C.; Kamperman, Marleen; Oh, Seung M.; DiSalvo, Francis J.; Wiesner, Ulrich

2011-01-01T23:59:59.000Z

385

Capacity fade analysis of a battery/super capacitor hybrid and a battery under pulse loads full cell studies  

E-Print Network [OSTI]

. Introduction Hybrid energy storage devices are more efficient than a battery in supplying the total powerCapacity fade analysis of a battery/super capacitor hybrid and a battery under pulse loads ­ full words: capacity fade, interfacial impedance, lithium ion battery/supercapacitor hybrid, pulse discharge

Popov, Branko N.

386

Fabrication of carbon microcapsules containing silicon nanoparticles-carbon nanotubes nanocomposite by sol-gel method for anode in lithium ion battery  

SciTech Connect (OSTI)

Carbon microcapsules containing silicon nanoparticles (Si NPs)-carbon nanotubes (CNTs) nanocomposite (Si-CNT-C) have been fabricated by a surfactant mediated sol-gel method followed by a carbonization process. Silicon nanoparticles-carbon nanotubes (Si-CNT) nanohybrids were produced by a wet-type beadsmill method. To obtain Si-CNT nanocomposites with spherical morphologies, a silica precursor (tetraethylorthosilicate, TEOS) and polymer (PMMA) mixture was employed as a structure-directing medium. Thus the Si-CNT/Silica-Polymer microspheres were prepared by an acid catalyzed sol-gel method. Then a carbon precursor such as polypyrrole (PPy) was incorporated onto the surfaces of pre-existing Si-CNT/silica-polymer to generate Si-CNT/Silica-Polymer-PPy microspheres. Subsequent thermal treatment of the precursor followed by wet etching of silica produced Si-CNT-C microcapsules. The intermediate silica/polymer must disappear during the carbonization and etching process resulting in the formation of an internal free space. The carbon precursor polymer should transform to carbon shell to encapsulate remaining Si-CNT nanocomposites. Therefore, hollow carbon microcapsules containing Si-CNT nanocomposites could be obtained (Si-CNT-C). The successful fabrication was confirmed by scanning electron microscopy (SEM) and X-ray diffraction (XRD). These final materials were employed for anode performance improvement in lithium ion battery. The cyclic performances of these Si-CNT-C microcapsules were measured with a lithium battery half cell tests. - Graphical Abstract: Carbon microcapsules containing silicon nanoparticles (Si NPs)-carbon nanotubes (CNTs) nanocomposite (Si-CNT-C) have been fabricated by a surfactant mediated sol-gel method. Highlights: > Polymeric microcapsules containing Si-CNT transformed to carbon microcapsules. > Accommodate volume changes of Si NPs during Li ion charge/discharge. > Sizes of microcapsules were controlled by experimental parameters. > Lithium storage capacity and coulombic efficiency were demonstrated. > Use of sol-gel procedure as intermediate reaction.

Bae, Joonwon, E-mail: joonwonbae@gmail.com [Samsung Advanced Institute of Technology, Yong-In City 446-712, Gyeong-Gi Province (Korea, Republic of)

2011-07-15T23:59:59.000Z

387

One-pot synthesis of SnO{sub 2}/reduced graphene oxide nanocomposite in ionic liquid-based solution and its application for lithium ion batteries  

SciTech Connect (OSTI)

Graphical abstract: - Highlights: • A facile and low-temperature method is developed for SnO{sub 2}/graphene composite. • Synthesis performed in a choline chloride-based ionic liquid. • The composite shows an enhanced cycling stability as anode for Li-ion batteries. • 4 nm SnO{sub 2} nanoparticles mono-dispersed on the surface of reduced graphene oxide. - Abstract: A facile and low-temperature method is developed for SnO{sub 2}/graphene composite which involves an ultrasonic-assistant oxidation–reduction reaction between Sn{sup 2+} and graphene oxide in a choline chloride–ethylene glycol based ionic liquid under ambient conditions. The reaction solution is non-corrosive and environmental-friendly. Moreover, the proposed technique does not require complicated infrastructures and heat treatment. The SnO{sub 2}/graphene composite consists of about 4 nm sized SnO{sub 2} nanoparticles with cassiterite structure mono-dispersed on the surface of reduced graphene oxide. As anode for lithium-ion batteries, the SnO{sub 2}/graphene composite shows a satisfying cycling stability (535 mAh g{sup ?1} after 50 cycles @100 mA g{sup ?1}), which is significantly prior to the bare 4 nm sized SnO{sub 2} nanocrsytals. The graphene sheets in the hybrid nanostructure could provide a segmentation effect to alleviate the volume expansion of the SnO{sub 2} and restrain the small and active Sn-based particles aggregating into larger and inactive clusters during cycling.

Gu, Changdong, E-mail: cdgu@zju.edu.cn; Zhang, Heng; Wang, Xiuli; Tu, Jiangping

2013-10-15T23:59:59.000Z

388

Overcharge Protection for 4 V Lithium Batteries at High Rates and Low Temperature  

E-Print Network [OSTI]

Protection for 4 V Lithium Batteries at High Rates and LowRechargeable lithium batteries are known for their highBecause lithium ion batteries are especially susceptible to

Chen, Guoying

2010-01-01T23:59:59.000Z

389

Challenges for Na-ion Negative Electrodes  

E-Print Network [OSTI]

Na-ion batteries have been proposed as candidates for replacing Li-ion batteries. In this paper we examine the viability of Na-ion negative electrode materials based on Na alloys or hard carbons in terms of volumetric ...

Chevrier, V. L.

390

Combustion synthesized nanocrystalline Li{sub 3}V{sub 2}(PO{sub 4}){sub 3}/C cathode for lithium-ion batteries  

SciTech Connect (OSTI)

Graphical abstract: Nanocrystalline Li{sub 3}V{sub 2}(PO{sub 4}){sub 3}/C compound has been synthesized using a novel corn assisted combustion (CAC) method, wherein the composite prepared at 850 °C is found to exhibit superior physical and electrochemical properties than the one synthesized at 800 °C (Fig. 1). Despite the charge disproportionation of V{sup 4+} and a possible solid solution behavior of Li{sub 3}V{sub 2}(PO{sub 4}){sub 3} cathode upon insertion and de-insertion of Li{sup +} ions, the structural stability of the same is appreciable, even with the extraction of third lithium at 4.6 V (Fig. 2). An appreciable specific capacity of 174 mAh g{sup ?1} with an excellent columbic efficiency (99%) and better capacity retention upon high rate applications have been exhibited by Li{sub 3}V{sub 2}(PO{sub 4}){sub 3}/C cathode, thus demonstrating the feasibility of CAC method in preparing the title compound to best suit with the needs of lithium battery applications. Display Omitted Highlights: ? Novel corn assisted combustion method has been used to synthesize Li{sub 3}V{sub 2}(PO{sub 4}){sub 3}/C. ? Corn is a cheap and eco benign combustible fuel to facilitate CAC synthesis. ? Li{sub 3}V{sub 2}(PO{sub 4}){sub 3}/C exhibits an appreciable specific capacity of 174 mAh g{sup ?1} (C/10 rate). ? Currently observed columbic efficiency of 99% is better than the reported behavior. ? Suitability of Li{sub 3}V{sub 2}(PO{sub 4}){sub 3}/C cathode up to 10C rate is demonstrated. -- Abstract: Nanocrystalline Li{sub 3}V{sub 2}(PO{sub 4}){sub 3}/C composite synthesized using a novel corn assisted combustion method at 850 °C exhibits superior physical and electrochemical properties than the one synthesized at 800 °C. Despite the charge disproportionation of V{sup 4+} and a possible solid solution behavior of Li{sub 3}V{sub 2}(PO{sub 4}){sub 3} cathode upon insertion and extraction of Li{sup +} ions, the structural stability of the same is appreciable, even with the extraction of third lithium at 4.6 V. An appreciable specific capacity of 174 mAh g{sup ?1} and better capacity retention upon high rate applications have been exhibited by Li{sub 3}V{sub 2}(PO{sub 4}){sub 3}/C cathode, thus demonstrating the suitability of the same for lithium-ion battery applications.

Nathiya, K.; Bhuvaneswari, D.; Gangulibabu [Central Electrochemical Research Institute, Karaikudi 630006 (India)] [Central Electrochemical Research Institute, Karaikudi 630006 (India); Kalaiselvi, N., E-mail: kalaiselvicecri@gmail.com [Central Electrochemical Research Institute, Karaikudi 630006 (India)

2012-12-15T23:59:59.000Z

391

Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications  

E-Print Network [OSTI]

Battery safety has been a very important research area over the past decade. Commercially available lithium ion batteries employ low flash point (<80 °C), flammable, and volatile organic electrolytes. These organic based ...

Hu, Qichao

392

Overview of Computer-Aided Engineering of Batteries (CAEBAT)...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Computer-Aided Engineering of Batteries (CAEBAT) and Introduction to Multi-Scale, Multi-Dimensional (MSMD) Modeling of Lithium-Ion Batteries Overview of Computer-Aided Engineering...

393

Microfabricated thin-film batteries : technology and potential applications  

E-Print Network [OSTI]

High-energy-density lithium ion batteries have enabled a myriad of small consumer-electronics applications. Batteries for these applications most often employ a liquid electrolyte system. However, liquid electrolytes do ...

Greiner, Julia

2006-01-01T23:59:59.000Z

394

Novel Cell Design for Combined In Situ Acoustic Emission and X-ray Diffraction of Cycling Lithium Ion Batteries  

SciTech Connect (OSTI)

An in situ acoustic emission (AE) and X-ray diffraction (XRD) cell for use in the study of battery electrode materials has been devised and tested. This cell uses commercially available coin cell hardware retrofitted with a metalized polyethylene terephthalate (PET) disk which acts as both an X-ray window and a current collector. In this manner the use of beryllium and its associated cost and hazard is avoided. An AE sensor may be affixed to the cell face opposite the PET window in order to monitor degradation effects, such as particle fracture, during cell cycling. Silicon particles which were previously studied by the AE technique were tested in this cell as a model material. The performance of these cells compared well with unmodified coin cells while providing information about structural changes in the active material as the cell is repeatedly charged and discharged.

Rhodes, Kevin J [ORNL; Kirkham, Melanie J [ORNL; Meisner, Roberta Ann [ORNL; Parish, Chad M [ORNL; Dudney, Nancy J [ORNL; Daniel, Claus [ORNL

2011-01-01T23:59:59.000Z

395

Development of Production-Intent Plug-In Hybrid Vehicle Using Advanced Lithium-Ion Battery Packs with Deployment to a Demonstration Fleet  

SciTech Connect (OSTI)

The primary goal of this project was to speed the development of one of the first commercially available, OEM-produced plug-in hybrid electric vehicles (PHEV). The performance of the PHEV was expected to double the fuel economy of the conventional hybrid version. This vehicle program incorporated a number of advanced technologies, including advanced lithium-ion battery packs and an E85-capable flex-fuel engine. The project developed, fully integrated, and validated plug-in specific systems and controls by using GM’s Global Vehicle Development Process (GVDP) for production vehicles. Engineering Development related activities included the build of mule vehicles and integration vehicles for Phases I & II of the project. Performance data for these vehicles was shared with the U.S. Department of Energy (DOE). The deployment of many of these vehicles was restricted to internal use at GM sites or restricted to assigned GM drivers. Phase III of the project captured the first half or Alpha phase of the Engineering tasks for the development of a new thermal management design for a second generation battery module. The project spanned five years. It included six on-site technical reviews with representatives from the DOE. One unique aspect of the GM/DOE collaborative project was the involvement of the DOE throughout the OEM vehicle development process. The DOE gained an understanding of how an OEM develops vehicle efficiency and FE performance, while balancing many other vehicle performance attributes to provide customers well balanced and fuel efficient vehicles that are exciting to drive. Many vehicle content and performance trade-offs were encountered throughout the vehicle development process to achieve product cost and performance targets for both the OEM and end customer. The project team completed two sets of PHEV development vehicles with fully integrated PHEV systems. Over 50 development vehicles were built and operated for over 180,000 development miles. The team also completed four GM engineering development Buy-Off rides/milestones. The project included numerous engineering vehicle and systems development trips including extreme hot, cold and altitude exposure. The final fuel economy performance demonstrated met the objectives of the PHEV collaborative GM/DOE project. Charge depletion fuel economy of twice that of the non-PHEV model was demonstrated. The project team also designed, developed and tested a high voltage battery module concept that appears to be feasible from a manufacturability, cost and performance standpoint. The project provided important product development and knowledge as well as technological learnings and advancements that include multiple U.S. patent applications.

No, author

2013-09-29T23:59:59.000Z

396

KAir Battery  

Broader source: Energy.gov [DOE]

KAir Battery, from Ohio State University, is commercializing highly energy efficient cost-effective potassium air batteries for use in the electrical stationary storage systems market (ESSS). Beyond, the ESSS market potential applications range from temporary power stations and electric vehicle.

397

Particle-Level Modeling of the Charge-Discharge Behavior of Nanoparticulate Phase-Separating Li-Ion Battery Electrodes  

E-Print Network [OSTI]

In nanoparticulate phase-separating electrodes, phase separation inside the particles can be hindered during their charge/discharge cycles even when a thermodynamic driving force for phase separation exists. In such cases, particles may (de)lithiate discretely in a process referred to as mosaic instability. This instability could be the key to elucidating the complex charge/discharge dynamics in nanoparticulate phase-separating electrodes. In this paper, the dynamics of the mosaic instability is studied using Smoothed Boundary Method simulations at the particle level, where the concentration and electrostatic potential fields are spatially resolved around individual particles. Two sets of configurations consisting of spherical particles with an identical radius are employed to study the instability in detail. The effect of an activity-dependent exchange current density on the mosaic instability, which leads to asymmetric charge/discharge, is also studied. While we show that our model reproduces the results of...

Orvananos, Bernardo; Yu, Hui-Chia; Bazant, Martin Z; Thornton, Katsuyo

2013-01-01T23:59:59.000Z

398

Voltage, Stability and Diffusion Barrier Differences between Sodium-ion and Lithium-ion Intercalation Materials  

E-Print Network [OSTI]

To evaluate the potential of Na-ion batteries, we contrast in this work the difference between Na-ion and Li-ion based intercalation chemistries in terms of three key battery properties—voltage, phase stability and diffusion ...

Ong, Shyue Ping

399

Solid polymer electrolyte lithium batteries  

DOE Patents [OSTI]

This invention pertains to Lithium batteries using Li ion (Li[sup +]) conductive solid polymer electrolytes composed of solvates of Li salts immobilized in a solid organic polymer matrix. In particular, this invention relates to Li batteries using solid polymer electrolytes derived by immobilizing solvates formed between a Li salt and an aprotic organic solvent (or mixture of such solvents) in poly(vinyl chloride). 3 figures.

Alamgir, M.; Abraham, K.M.

1993-10-12T23:59:59.000Z

400

Solid polymer electrolyte lithium batteries  

DOE Patents [OSTI]

This invention pertains to Lithium batteries using Li ion (Li.sup.+) conductive solid polymer electrolytes composed of solvates of Li salts immobilized in a solid organic polymer matrix. In particular, this invention relates to Li batteries using solid polymer electrolytes derived by immobilizing solvates formed between a Li salt and an aprotic organic solvent (or mixture of such solvents) in poly(vinyl chloride).

Alamgir, Mohamed (Dedham, MA); Abraham, Kuzhikalail M. (Needham, MA)

1993-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "ion batteries elucidated" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Innovative Manufacturing and Materials for Low-Cost Lithium-Ion...  

Broader source: Energy.gov (indexed) [DOE]

Merit Review 2014: Innovative Manufacturing and Materials for Low-Cost Lithium-Ion Batteries Innovative Manufacturing and Materials for Low-Cost Lithium-Ion Batteries...

402

Technological assessment and evaluation of high power batteries and their commercial values  

E-Print Network [OSTI]

Lithium Ion (Li-ion) battery technology has the potential to compete with the more matured Nickel Metal Hydride (NiMH) battery technology in the Hybrid Electric Vehicle (HEV) energy storage market as it has higher specific ...

Teo, Seh Kiat

2006-01-01T23:59:59.000Z

403

First-Principles Study of Novel Conversion Reactions for High-Capacity Li-Ion Battery Anodes in the Li-Mg-B-N-H System  

SciTech Connect (OSTI)

Anodes for Li-ion batteries are primarily carbon-based due to their low cost and long cycle life. However, improvements to the Li capacity of carbon anodes, LiC{sub 6} in particular, are necessary to obtain a larger energy density. State-of-the-art light-metal hydrides for hydrogen storage applications often contain Li and involve reactions requiring Li transport, and light-metal ionic hydrides are candidates for novel conversion materials. Given a set of known solid-state and gas-phase reactants, we have determined the phase diagram in the Li-Mg-B-N-H system in the grand canonical ensemble, as a function of lithium chemical potential. We present computational results for several new conversion reactions with capacities between 2400 and 4000 mAh g{sup -1} that are thermodynamically favorable and that do not involve gas evolution. We provide experimental evidence for the reaction pathway on delithiation for the compound Li{sub 4}BN{sub 3}H{sub 10}. While the predicted reactions involve multiple steps, the maximum volume increase for these materials on lithium insertion is significantly smaller than that for Si.

Mason, T.H.; Graetz, J.; Liu, X.; Hong, J.; Majzoub, E.H.

2011-07-28T23:59:59.000Z

404

Simulations of Plug-in Hybrid Vehicles Using Advanced Lithium Batteries and Ultracapacitors on Various Driving Cycles  

E-Print Network [OSTI]

7: Simulation results for the batteries alone kW kW Batteryor even lithium-ion batteries. This is another advantagewith the air-electrode batteries. Table 6: Simulation

Burke, Andy; Zhao, Hengbing

2010-01-01T23:59:59.000Z

405

Crab Shells as Sustainable Templates from Nature for Nanostructured Battery Electrodes  

E-Print Network [OSTI]

then be used to encapsulate sulfur and silicon to form cathodes and anodes for Li-ion batteries. The resulting, silicon High capacity Li-ion battery electrode materials such as Si, Sn, SnO2, S, and O2 have attracted great attention due their potential to increase Li-ion battery energy density. For example, silicon

Cui, Yi

406

Solid-state lithium battery  

DOE Patents [OSTI]

The present invention is directed to a higher power, thin film lithium-ion electrolyte on a metallic substrate, enabling mass-produced solid-state lithium batteries. High-temperature thermodynamic equilibrium processing enables co-firing of oxides and base metals, providing a means to integrate the crystalline, lithium-stable, fast lithium-ion conductor lanthanum lithium tantalate (La.sub.1/3-xLi.sub.3xTaO.sub.3) directly with a thin metal foil current collector appropriate for a lithium-free solid-state battery.

Ihlefeld, Jon; Clem, Paul G; Edney, Cynthia; Ingersoll, David; Nagasubramanian, Ganesan; Fenton, Kyle Ross

2014-11-04T23:59:59.000Z

407

Saft America Advanced Batteries Plant Celebrates Grand Opening...  

Energy Savers [EERE]

Florida, factory, which will produce advanced lithium-ion batteries to power electric vehicles and other applications. Saft America estimates it will create nearly 280...

408

advanced battery technologies: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Websites Summary: diesel engine, an electric motor, a Lithium-Ion battery, and an Eaton automated manual transmission. The electric motor, clutch, transmission, inverter,...

409

advanced battery technology: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Websites Summary: diesel engine, an electric motor, a Lithium-Ion battery, and an Eaton automated manual transmission. The electric motor, clutch, transmission, inverter,...

410

Electric Vehicle Battery Thermal Issues and Thermal Management Techniques (Presentation)  

SciTech Connect (OSTI)

This presentation examines the issues concerning thermal management in electric drive vehicles and management techniques for improving the life of a Li-ion battery in an EDV.

Rugh, J. P.; Pesaran, A.; Smith, K.

2013-07-01T23:59:59.000Z

411

Metal-Air Electric Vehicle Battery: Sustainable, High-Energy Density, Low-Cost Electrochemical Energy Storage – Metal-Air Ionic Liquid (MAIL) Batteries  

SciTech Connect (OSTI)

Broad Funding Opportunity Announcement Project: ASU is developing a new class of metal-air batteries. Metal-air batteries are promising for future generations of EVs because they use oxygen from the air as one of the battery’s main reactants, reducing the weight of the battery and freeing up more space to devote to energy storage than Li-Ion batteries. ASU technology uses Zinc as the active metal in the battery because it is more abundant and affordable than imported lithium. Metal-air batteries have long been considered impractical for EV applications because the water-based electrolytes inside would decompose the battery interior after just a few uses. Overcoming this traditional limitation, ASU’s new battery system could be both cheaper and safer than today’s Li-Ion batteries, store from 4-5 times more energy, and be recharged over 2,500 times.

None

2009-12-21T23:59:59.000Z

412

Stability of aluminum in low-temperature lithium-ion battery electrolytes. Progress report, October 1997--September 1998  

SciTech Connect (OSTI)

The authors investigated the stability of aluminum at the high positive potentials encountered during the charging of lithium-ion cells. The electrolyte in these cells consists of solutions of lithium hexafluorophosphate and lithium methide in binary- and ternary-solvent mixtures of ethylene carbonate, dimethyl carbonate, and ethyl methyl carbonate. They performed the investigations with the controlled potential coulometry technique. They found that a protective surface film was formed on aluminum electrodes in these solutions and that this film protected the electrodes from further corrosion. The protective surface film was found to break down in lithium methide solutions at 4.25 V versus a lithium reference electrode, and this resulted in increased corrosion of the aluminum electrodes at higher potentials. In contrast to lithium methide solutions, the protective surface film formed on aluminum electrodes in lithium hexafluorophosphate solutions was found to be quite stable and did not break down at potentials up to [approximately]5 V.

Behl, W.K.; Plichta, E.J.

1999-03-01T23:59:59.000Z

413

Lithium transition metal fluorophosphates (Li{sub 2}CoPO{sub 4}F and Li{sub 2}NiPO{sub 4}F) as cathode materials for lithium ion battery from atomistic simulation  

SciTech Connect (OSTI)

Lithium transition metal fluorophosphates (Li{sub 2}MPO{sub 4}F, M: Co and Ni) have been investigated from atomistic simulation. In order to predict the characteristics of these materials as cathode materials for lithium ion batteries, structural property, defect chemistry, and Li{sup +} ion transportation property are characterized. The core–shell model with empirical force fields is employed to reproduce the unit-cell parameters of crystal structure, which are in good agreement with the experimental data. In addition, the formation energies of intrinsic defects (Frenkel and antisite) are determined by energetics calculation. From migration energy calculations, it is found that these flurophosphates have a 3D Li{sup +} ion diffusion network forecasting good Li{sup +} ion conducting performances. Accordingly, we expect that this study provides an atomic scale insight as cathode materials for lithium ion batteries. - Graphical abstract: Lithium transition metal fluorophosphates (Li{sub 2}CoPO{sub 4}F and Li{sub 2}NiPO{sub 4}F). Display Omitted - Highlights: • Lithium transition metal fluorophosphates (Li{sub 2}MPO{sub 4}F, M: Co and Ni) are investigated from classical atomistic simulation. • The unit-cell parameters from experimental studies are reproduced by the core–shell model. • Li{sup +} ion conducting Li{sub 2}MPO{sub 4}F has a 3D Li{sup +} ion diffusion network. • It is predicted that Li/Co or Li/Ni antisite defects are well-formed at a substantial concentration level.

Lee, Sanghun, E-mail: sh0129.lee@samsung.com; Park, Sung Soo, E-mail: sung.s.park@samsung.com

2013-08-15T23:59:59.000Z

414

California Lithium Battery, Inc. | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

Systems and CALiB Power. US production of this advanced Very Large Format (400Ah+) si-graphene LI-ion battery is scheduled to start in California in 2014. Plans are to produce the...

415

Modification of carbon nanotubes by CuO-doped NiO nanocomposite for use as an anode material for lithium-ion batteries  

SciTech Connect (OSTI)

CuO-doped NiO (CuNiO) with porous hexagonal morphology is fabricated via a modified in-situ co-precipitation method and its nanocomposite is prepared with carbon nanotubes (CNTs). The electrochemical properties of CuNiO/CNT nanocomposite are investigated by cyclic voltammetry (CV), galvanostatic charge–discharge tests and electrochemical impedance spectroscopy (EIS). Since Cu can both act as conductor and a catalyst, the CuNiO/CNT nanocomposite exhibits higher initial coulombic efficiency (82.7% of the 2nd cycle) and better capacity retention (78.6% on 50th cycle) than bare CuNiO (78.9% of the 2nd cycle), CuO/CNT (76.8% of the 2nd cycle) and NiO/CNT (77.7% of the 2nd cycle) at the current density of 100 mA /g. This high capacity and good cycling ability is attributed to the partial substitution of Cu{sup +2} for Ni{sup +2}, resulting in an increase of holes concentration, and therefore improved p-type conductivity along with an intimate interaction with CNTs providing large surface area, excellent conduction, mechanical strength and chemical stability. - Graphical abstract: The porous CuNiO/CNT nanocomposite synthesized via a modified co-precipitation method in combination with subsequent calcination was applied in the negative electrode materials for lithium-ion batteries and exhibited high electrochemical performance. - Highlights: • CuO doped NiO/CNTs nano composite is achieved via a simple co-precipitation method. • Monodispersity, shape and sizes of sample particles is specifically controlled. • Good quality adhesion between CNTs and CuNiO is visible from TEM image. • High electrochemical performance is achieved. • Discharge capacity of 686 mA h/g after 50 cycles with coulombic efficiency (82.5%)

Mustansar Abbas, Syed, E-mail: qau_abbas@yahoo.com [Nanoscience and Catalysis Division, National Centre for Physics, Islamabad 45320 (Pakistan); Department of Chemistry, Quaid-e-Azam University, Islamabad (Pakistan); Tajammul Hussain, Syed [Nanoscience and Catalysis Division, National Centre for Physics, Islamabad 45320 (Pakistan); Ali, Saqib [Department of Chemistry, Quaid-e-Azam University, Islamabad (Pakistan); Ahmad, Nisar [Department of Chemistry, Hazara University, Mansehra (Pakistan); Ali, Nisar [Department of Physics, University of Punjab, Lahore (Pakistan); Abbas, Saghir [Department of Chemistry, Quaid-e-Azam University, Islamabad (Pakistan); Ali, Zulfiqar [Nanoscience and Catalysis Division, National Centre for Physics, Islamabad 45320 (Pakistan); College of Earth and Environmental Sciences, University of Punjab, Lahore (Pakistan)

2013-06-15T23:59:59.000Z

416

A Desalination Battery Mauro Pasta,  

E-Print Network [OSTI]

is promising when compared to reverse osmosis ( 0.2 Wh l-1 ), the most efficient technique presently available. KEYWORDS: Seawater desalination, mixing entropy battery, reverse osmosis, ion selectivity Increasing of desalination technologies have been developed over the years.2,4-10 Reverse osmosis requires a large electrical

Cui, Yi

417

Surface-Driven Sodium Ion Energy Storage in Nanocellular Carbon...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Surface-Driven Sodium Ion Energy Storage in Nanocellular Carbon Foams. Surface-Driven Sodium Ion Energy Storage in Nanocellular Carbon Foams. Abstract: Sodium ion (Na+) batteries...

418

Metal-Air Batteries  

SciTech Connect (OSTI)

Metal-air batteries have much higher specific energies than most currently available primary and rechargeable batteries. Recent advances in electrode materials and electrolytes, as well as new designs on metal-air batteries, have attracted intensive effort in recent years, especially in the development of lithium-air batteries. The general principle in metal-air batteries will be reviewed in this chapter. The materials, preparation methods, and performances of metal-air batteries will be discussed. Two main metal-air batteries, Zn-air and Li-air batteries will be discussed in detail. Other type of metal-air batteries will also be described.

Zhang, Jiguang; Bruce, Peter G.; Zhang, Gregory

2011-08-01T23:59:59.000Z

419

Biologically enhanced cathode design for improved capacity and cycle life for lithium-oxygen batteries  

E-Print Network [OSTI]

Lithium-oxygen batteries have a great potential to enhance the gravimetric energy density of fully packaged batteries by two to three times that of lithium ion cells. Recent studies have focused on finding stable electrolytes ...

Oh, Dahyun

420

Ab initio prediction of thermodynamics in alkali metal-air batteries  

E-Print Network [OSTI]

Electric vehicles ("EVs") require high-energy-density batteries with reliable cyclability and rate capability. However, the current state-of-the-art Li-ion batteries only exhibit energy densities near ~150 Wh/kg, limiting ...

Kang, ShinYoung

2014-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "ion batteries elucidated" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Theory of SEI Formation in Rechargeable Batteries: Capacity Fade, Accelerated Aging and Lifetime Prediction  

E-Print Network [OSTI]

Cycle life is critically important in applications of rechargeable batteries, but lifetime prediction is mostly based on empirical trends, rather than mathematical models. In practical lithium-ion batteries, capacity fade ...

Pinson, Matthew Bede

422

Vehicle Battery Safety Roadmap Guidance  

SciTech Connect (OSTI)

The safety of electrified vehicles with high capacity energy storage devices creates challenges that must be met to assure commercial acceptance of EVs and HEVs. High performance vehicular traction energy storage systems must be intrinsically tolerant of abusive conditions: overcharge, short circuit, crush, fire exposure, overdischarge, and mechanical shock and vibration. Fail-safe responses to these conditions must be designed into the system, at the materials and the system level, through selection of materials and safety devices that will further reduce the probability of single cell failure and preclude propagation of failure to adjacent cells. One of the most important objectives of DOE's Office of Vehicle Technologies is to support the development of lithium ion batteries that are safe and abuse tolerant in electric drive vehicles. This Roadmap analyzes battery safety and failure modes of state-of-the-art cells and batteries and makes recommendations on future investments that would further DOE's mission.

Doughty, D. H.

2012-10-01T23:59:59.000Z

423

battery materials | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

battery materials battery materials Leads No leads are available at this time. Modeling Interfacial Glass-Water Reactions: Recent Advances and Current Limitations. Abstract: The...

424

Battery cell feedthrough apparatus  

DOE Patents [OSTI]

A compact, hermetic feedthrough apparatus comprising interfitting sleeve portions constructed of chemically-stable materials to permit unique battery designs and increase battery life and performance.

Kaun, Thomas D. (New Lenox, IL)

1995-01-01T23:59:59.000Z

425

Battery Safety Testing  

Broader source: Energy.gov (indexed) [DOE]

mechanical modeling battery crash worthiness for USCAR Abuse tolerance evaluation of cells, batteries, and systems Milestones Demonstrate improved abuse tolerant cells and...

426

Rechargeable thin film battery and method for making the same  

DOE Patents [OSTI]

A rechargeable, stackable, thin film, solid-state lithium electrochemical cell, thin film lithium battery and method for making the same is disclosed. The cell and battery provide for a variety configurations, voltage and current capacities. An innovative low temperature ion beam assisted deposition method for fabricating thin film, solid-state anodes, cathodes and electrolytes is disclosed wherein a source of energetic ions and evaporants combine to form thin film cell components having preferred crystallinity, structure and orientation. The disclosed batteries are particularly useful as power sources for portable electronic devices and electric vehicle applications where high energy density, high reversible charge capacity, high discharge current and long battery lifetimes are required.

Goldner, Ronald B.; Liu, Te-Yang; Goldner, Mark A.; Gerouki, Alexandra; Haas, Terry E.

2006-01-03T23:59:59.000Z

427

Optical state-of-charge monitor for batteries  

DOE Patents [OSTI]

A method and apparatus for determining the instantaneous state-of-charge of a battery in which change in composition with discharge manifests itself as a change in optical absorption. In a lead-acid battery, the sensor comprises a fiber optic system with an absorption cell or, alternatively, an optical fiber woven into an absorbed-glass-mat battery. In a lithium-ion battery, the sensor comprises fiber optics for introducing light into the anode to monitor absorption when lithium ions are introduced.

Weiss, Jonathan D. (Albuquerque, NM)

1999-01-01T23:59:59.000Z

428

Celgard US Manufacturing Facilities Initiative for Lithium-ion...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Initiative for Lithium-ion Battery Separator Celgard US Manufacturing Facilities Initiative for Lithium-ion Battery Separator FY 2012 Annual Progress Report for Energy Storage R&D...

429

Lithium Metal Anodes for Rechargeable Batteries  

SciTech Connect (OSTI)

Rechargeable lithium metal batteries have much higher energy density than those of lithium ion batteries using graphite anode. Unfortunately, uncontrollable dendritic lithium growth inherent in these batteries (upon repeated charge/discharge cycling) and limited Coulombic efficiency during lithium deposition/striping has prevented their practical application over the past 40 years. With the emerging of post Li-ion batteries, safe and efficient operation of lithium metal anode has become an enabling technology which may determine the fate of several promising candidates for the next generation of energy storage systems, including rechargeable Li-air battery, Li-S battery, and Li metal battery which utilize lithium intercalation compounds as cathode. In this work, various factors which affect the morphology and Coulombic efficiency of lithium anode will be analyzed. Technologies used to characterize the morphology of lithium deposition and the results obtained by modeling of lithium dendrite growth will also be reviewed. At last, recent development in this filed and urgent need in this field will also be discussed.

Xu, Wu; Wang, Jiulin; Ding, Fei; Chen, Xilin; Nasybulin, Eduard N.; Zhang, Yaohui; Zhang, Jiguang

2014-02-28T23:59:59.000Z

430

Thin, Flexible Secondary Li-Ion Paper Liangbing Hu,  

E-Print Network [OSTI]

Thin, Flexible Secondary Li-Ion Paper Batteries Liangbing Hu, Hui Wu, Fabio La Mantia, Yuan Yang, secondary Li-ion batteries are key components in por- table electronics due to their high power and energy integrated all of the components of a Li-ion battery into a single sheet of paper with a simple lamination

Cui, Yi

431

NREL: Energy Storage - Battery Ownership  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

publications. Updating United States Advanced Battery Consortium and Department of Energy Battery Technology Targets for Battery Electric Vehicles Sensitivity of Plug-In Hybrid...

432

Survey of mercury, cadmium and lead content of household batteries  

SciTech Connect (OSTI)

Highlights: • A well selected sample of 146 batteries was analysed for its heavy metals content. • A comparison was made between heavy metals contents in batteries in 2006 and 2011. • No significant change after implementation of the new EU Batteries Directive. • Severe differences in heavy metal contents were found in different battery-types. - Abstract: The objective of this work was to provide updated information on the development of the potential impact of heavy metal containing batteries on municipal waste and battery recycling processes following transposition of the new EU Batteries Directive 2006/66/EC. A representative sample of 146 different types of commercially available dry and button cells as well as lithium-ion accumulators for mobile phones were analysed for their mercury (Hg)-, cadmium (Cd)- and lead (Pb)-contents. The methods used for preparing the cells and analysing the heavy metals Hg, Cd, and Pb were either developed during a former study or newly developed. Several batteries contained higher mass fractions of mercury or cadmium than the EU limits. Only half of the batteries with mercury and/or lead fractions above the marking thresholds were labelled. Alkaline–manganese mono-cells and Li-ion accumulators, on average, contained the lowest heavy metal concentrations, while zinc–carbon batteries, on average, contained the highest levels.

Recknagel, Sebastian, E-mail: sebastian.recknagel@bam.de [BAM Federal Institute for Materials Research and Testing, Department of Analytical Chemistry, Reference Materials, Richard-Willstätter-Straße 11, D-12489 Berlin (Germany); Radant, Hendrik [BAM Federal Institute for Materials Research and Testing, Department of Analytical Chemistry, Reference Materials, Richard-Willstätter-Straße 11, D-12489 Berlin (Germany); Kohlmeyer, Regina [German Federal Environment Agency (UBA), Section III 1.6 Extended Producer Responsibility, Wörlitzer Platz 1, D-06844 Dessau-Roßlau (Germany)

2014-01-15T23:59:59.000Z

433

A High-Efficiency Grid-Tie Battery Energy Storage System.  

E-Print Network [OSTI]

??Lithium-ion based battery energy storage system has become one of the most popular forms of energy storage system for its high charge and discharge efficiency… (more)

Qian, Hao

2011-01-01T23:59:59.000Z

434

Celgard US Manufacturing Facilities Initiative for Lithium-ion...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

More Documents & Publications Celgard US Manufacturing Facilities Initiative for Lithium-ion Battery Separator Celgard US Manufacturing Facilities Initiative for Lithium-ion...

435

Quick charge battery  

SciTech Connect (OSTI)

Electric and hybrid electric vehicles (EVs and HEVs) will become a significant reality in the near future of the automotive industry. Both types of vehicles will need a means to store energy on board. For the present, the method of choice would be lead-acid batteries, with the HEV having auxiliary power supplied by a small internal combustion engine. One of the main drawbacks to lead-acid batteries is internal heat generation as a natural consequence of the charging process as well as resistance losses. This limits the re-charging rate to the battery pack for an EV which has a range of about 80 miles. A quick turnaround on recharge is needed but not yet possible. One of the limiting factors is the heat buildup. For the HEV the auxiliary power unit provides a continuous charge to the battery pack. Therefore heat generation in the lead-acid battery is a constant problem that must be addressed. Presented here is a battery that is capable of quick charging, the Quick Charge Battery with Thermal Management. This is an electrochemical battery, typically a lead-acid battery, without the inherent thermal management problems that have been present in the past. The battery can be used in an all-electric vehicle, a hybrid-electric vehicle or an internal combustion engine vehicle, as well as in other applications that utilize secondary batteries. This is not restricted to only lead-acid batteries. The concept and technology are flexible enough to use in any secondary battery application where thermal management of the battery must be addressed, especially during charging. Any battery with temperature constraints can benefit from this advancement in the state of the art of battery manufacturing. This can also include nickel-cadmium, metal-air, nickel hydroxide, zinc-chloride or any other type of battery whose performance is affected by the temperature control of the interior as well as the exterior of the battery.

Parise, R.J.

1998-07-01T23:59:59.000Z

436

10 Questions for a Batteries Expert: Daniel Abraham  

Broader source: Energy.gov [DOE]

Lithium-ion batteries are in almost every cell phone, as well as cameras, camcorders, and computers. Dr. Abraham explains, "Our goal is to get the batteries into our cars –- into the next generation of plug-in hybrid and electric vehicles." Learn more.

437

Using Transient Electrical Measurements for Real-Time Monitoring of Battery State-of-Charge  

E-Print Network [OSTI]

system. I. INTRODUCTION Future energy-storage systems are likely to use lithium- ion batteries because regulate efficiency and power availability in battery-based systems, it is important to have a robust realUsing Transient Electrical Measurements for Real-Time Monitoring of Battery State

Nasipuri, Asis

438

A Fuel-Cell-Battery Hybrid for Portable Embedded Kyungsoo Lee, Naehyuck Chang  

E-Print Network [OSTI]

that of a Li-ion battery. The FC cannot respond to sudden changes in the load, and so a system powered solelyA Fuel-Cell-Battery Hybrid for Portable Embedded Systems Kyungsoo Lee, Naehyuck Chang Dept. of EECS on the development of a fuel cell (FC) and battery hybrid (FC- Bh) system for use in portable microelectronic systems

Kambhampati, Subbarao

439

Degradation of Li/S Battery Electrodes Studied Using X-ray Phase Contrast Tomography  

E-Print Network [OSTI]

the Li-ion battery market. This can be explained by their high energy density, high operating voltage1 Degradation of Li/S Battery Electrodes Studied Using X-ray Phase Contrast Tomography L. Zielkea. Zengerlea,f and S. Thielea,g Lithium/sulphur batteries are promising candidates for future energy storage

Schmidt, Volker

440

BATTERY AWARE TASK SCHEDULING FOR A SYSTEM-ON-A-CHIP USING VOLTAGE/CLOCK SCALING  

E-Print Network [OSTI]

is closest to the [12]; however we use Li-Ion based battery model of [13] to guide the schedul- ing processBATTERY AWARE TASK SCHEDULING FOR A SYSTEM-ON-A-CHIP USING VOLTAGE/CLOCK SCALING Princey Chowdhury Engineering Tempe AZ 85287 ABSTRACT Battery lifetime is a critical parameter in the operation of mobile

Kambhampati, Subbarao

Note: This page contains sample records for the topic "ion batteries elucidated" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

The Seventh Cell of a Six-Cell Battery Delyan Raychev, Youhuizi Li and Weisong Shi  

E-Print Network [OSTI]

propose an alternate method, called autonomous battery clusters (ABC), of building batteries and new ways to maximize the energy utilization of any devices that could be powered by Lithium Ion batteries. Experimental source. Index Terms--Energy Efficiency; Energy Management; Bat- tery Discharging I. INTRODUCTION Mankind

Shi, Weisong

442

Rechargeable Magnesium Batteries: Low-Cost Rechargeable Magnesium Batteries with High Energy Density  

SciTech Connect (OSTI)

BEEST Project: Pellion Technologies is developing rechargeable magnesium batteries that would enable an EV to travel 3 times farther than it could using Li-ion batteries. Prototype magnesium batteries demonstrate excellent electrochemical behavior; delivering thousands of charge cycles with very little fade. Nevertheless, these prototypes have always stored too little energy to be commercially viable. Pellion Technologies is working to overcome this challenge by rapidly screening potential storage materials using proprietary, high-throughput computer models. To date, 12,000 materials have been identified and analyzed. The resulting best materials have been electrochemically tested, yielding several very promising candidates.

None

2010-10-01T23:59:59.000Z

443

Development of First Principles Capacity Fade Model for Li-Ion Cells  

E-Print Network [OSTI]

developed to simulate the capacity fade of Li-ion batteries. Incorporation of a continuous occurrence a first principles capacity fade model for Li-ion batteries. Darling and Newman1 made a first attempt into a lithium-ion battery model. The model explains the self-discharge process occurring in Li-ion cells

Popov, Branko N.

444

Battery cell feedthrough apparatus  

DOE Patents [OSTI]

A compact, hermetic feedthrough apparatus is described comprising interfitting sleeve portions constructed of chemically-stable materials to permit unique battery designs and increase battery life and performance. 8 figs.

Kaun, T.D.

1995-03-14T23:59:59.000Z

445

High-energy metal air batteries  

DOE Patents [OSTI]

Disclosed herein are embodiments of lithium/air batteries and methods of making and using the same. Certain embodiments are pouch-cell batteries encased within an oxygen-permeable membrane packaging material that is less than 2% of the total battery weight. Some embodiments include a hybrid air electrode comprising carbon and an ion insertion material, wherein the mass ratio of ion insertion material to carbon is 0.2 to 0.8. The air electrode may include hydrophobic, porous fibers. In particular embodiments, the air electrode is soaked with an electrolyte comprising one or more solvents including dimethyl ether, and the dimethyl ether subsequently is evacuated from the soaked electrode. In other embodiments, the electrolyte comprises 10-20% crown ether by weight.

Zhang, Ji-Guang; Xiao, Jie; Xu, Wu; Wang, Deyu; Williford, Ralph E.; Liu, Jun

2014-07-01T23:59:59.000Z

446

High-energy metal air batteries  

DOE Patents [OSTI]

Disclosed herein are embodiments of lithium/air batteries and methods of making and using the same. Certain embodiments are pouch-cell batteries encased within an oxygen-permeable membrane packaging material that is less than 2% of the total battery weight. Some embodiments include a hybrid air electrode comprising carbon and an ion insertion material, wherein the mass ratio of ion insertion material to carbon is 0.2 to 0.8. The air electrode may include hydrophobic, porous fibers. In particular embodiments, the air electrode is soaked with an electrolyte comprising one or more solvents including dimethyl ether, and the dimethyl ether subsequently is evacuated from the soaked electrode. In other embodiments, the electrolyte comprises 10-20% crown ether by weight.

Zhang, Ji-Guang; Xiao, Jie; Xu, Wu; Wang, Deyu; Williford, Ralph E.; Liu, Jun

2013-07-09T23:59:59.000Z

447

Final Report - Recovery Act - Development and application of processing and process control for nano-composite materials for lithium ion batteries  

SciTech Connect (OSTI)

Oak Ridge National Laboratory and A123 Systems, Inc. collaborated on this project to develop a better understanding, quality control procedures, and safety testing for A123 System s nanocomposite separator (NCS) technology which is a cell based patented technology and separator. NCS demonstrated excellent performance. x3450 prismatic cells were shown to survive >8000 cycles (1C/2C rate) at room temperature with greater than 80% capacity retention with only NCS present as an alternative to conventional polyolefin. However, for a successful commercialization, the coating conditions required to provide consistent and reliable product had not been optimized and QC techniques for being able to remove defective material before incorporation into a cell had not been developed. The work outlined in this report addresses these latter two points. First, experiments were conducted to understand temperature profiles during the different drying stages of the NCS coating when applied to both anode and cathode. One of the more interesting discoveries of this study was the observation of the large temperature decrease experienced by the wet coating between the end of the infrared (IR) drying stage and the beginning of the exposure to the convection drying oven. This is not a desirable situation as the temperature gradient could have a deleterious effect on coating quality. Based on this and other experimental data a radiative transfer model was developed for IR heating that also included a mass transfer module for drying. This will prove invaluable for battery coating optimization especially where IR drying is being employed. A stress model was also developed that predicts that under certain drying conditions tensile stresses are formed in the coating which could lead to cracking that is sometimes observed after drying is complete. Prediction of under what conditions these stresses form is vital to improving coating quality. In addition to understanding the drying process other parameters such as slurry quality and equipment optimization were examined. Removal of particles and gels by filtering, control of viscosity by %solids and mixing adjustments, removal of trapped gas in the slurry and modification of coater speed and slot die gap were all found to be important for producing uniform and flaw-free coatings. Second, an in-line Hi-Pot testing method has been developed specifically for NCS that will enable detection of coating flaws that could lead to soft or hard electrical shorts within the cell. In this way flawed material can be rejected before incorporation into the cell thus greatly reducing the amount of scrap that is generated. Improved battery safety is an extremely important benefit of NCS. Evaluation of battery safety is usually accomplished by conducting a variety of tests including nail penetration, hot box, over charge, etc. For these tests entire batteries must be built but the resultant temperature and voltage responses reveal little about the breakdown mechanism. In this report is described a pinch test which is used to evaluate NCS quality at various stages including coated anode and cathode as well as assembled cell. Coupled with post-microscopic examination of the damaged pinch point test data can assist in the coating optimization from an improved end-use standpoint. As a result of this work two invention disclosures, one for optimizing drying methodology and the other for an in-line system for flaw detection, have been filed. In addition, 2 papers are being written for submission to peer-reviewed journals.

Daniel, Claus [ORNL; Armstrong, Beth L [ORNL; Maxey, L Curt [ORNL; Sabau, Adrian S [ORNL; Wang, Hsin [ORNL; Hagans, Patrick [A123 Systems, Inc.; Babinec, Sue [A123 Systems, Inc.

2013-08-01T23:59:59.000Z

448

CRADA Final Report for NFE-08-01826: Development and application of processing and processcontrol for nano-composite materials for lithium ion batteries  

SciTech Connect (OSTI)

Oak Ridge National Laboratory and A123 Systems, Inc. collaborated on this project to develop a better understanding, quality control procedures, and safety testing for A123 System’s nanocomposite separator (NCS) technology which is a cell based patented technology and separator. NCS demonstrated excellent performance. x3450 prismatic cells were shown to survive >8000 cycles (1C/2C rate) at room temperature with greater than 80% capacity retention with only NCS present as an alternative to conventional polyolefin. However, for a successful commercialization, the coating conditions required to provide consistent and reliable product had not been optimized and QC techniques for being able to remove defective material before incorporation into a cell had not been developed. The work outlined in this report addresses these latter two points. First, experiments were conducted to understand temperature profiles during the different drying stages of the NCS coating when applied to both anode and cathode. One of the more interesting discoveries of this study was the observation of the large temperature decrease experienced by the wet coating between the end of the infrared (IR) drying stage and the beginning of the exposure to the convection drying oven. This is not a desirable situation as the temperature gradient could have a deleterious effect on coating quality. Based on this and other experimental data a radiative transfer model was developed for IR heating that also included a mass transfer module for drying. This will prove invaluable for battery coating optimization especially where IR drying is being employed. A stress model was also developed that predicts that under certain drying conditions tensile stresses are formed in the coating which could lead to cracking that is sometimes observed after drying is complete. Prediction of under what conditions these stresses form is vital to improving coating quality. In addition to understanding the drying process other parameters such as slurry quality and equipment optimization were examined. Removal of particles and gels by filtering, control of viscosity by %solids and mixing adjustments, removal of trapped gas in the slurry and modification of coater speed and slot die gap were all found to be important for producing uniform and flaw-free coatings. Second, an in-line Hi-Pot testing method has been developed specifically for NCS that will enable detection of coating flaws that could lead to soft or hard electrical shorts within the cell. In this way flawed material can be rejected before incorporation into the cell thus greatly reducing the amount of scrap that is generated. Improved battery safety is an extremely important benefit of NCS. Evaluation of battery safety is usually accomplished by conducting a variety of tests including nail penetration, hot box, over charge, etc. For these tests entire batteries must be built but the resultant temperature and voltage responses reveal little about the breakdown mechanism. In this report is described a pinch test which is used to evaluate NCS quality at various stages including coated anode and cathode as well as assembled cell. Coupled with post-microscopic examination of the damaged ‘pinch point’ test data can assist in the coating optimization from an improved end-use standpoint. As a result of this work two invention disclosures, one for optimizing drying methodology and the other for an in-line system for flaw detection, have been filed. In addition, 2 papers are being written for submission to peer-reviewed journals.

Daniel, C.; Armstrong, B.; Maxey, C.; Sabau, A.; Wang, H.; Hagans, P. (A123 Systems, Inc.); and Babinec, S. (A123 Systems, Inc.)

2012-12-15T23:59:59.000Z

449

The Science of Battery Degradation.  

SciTech Connect (OSTI)

This report documents work that was performed under the Laboratory Directed Research and Development project, Science of Battery Degradation. The focus of this work was on the creation of new experimental and theoretical approaches to understand atomistic mechanisms of degradation in battery electrodes that result in loss of electrical energy storage capacity. Several unique approaches were developed during the course of the project, including the invention of a technique based on ultramicrotoming to cross-section commercial scale battery electrodes, the demonstration of scanning transmission x-ray microscopy (STXM) to probe lithium transport mechanisms within Li-ion battery electrodes, the creation of in-situ liquid cells to observe electrochemical reactions in real-time using both transmission electron microscopy (TEM) and STXM, the creation of an in-situ optical cell utilizing Raman spectroscopy and the application of the cell for analyzing redox flow batteries, the invention of an approach for performing ab initio simulation of electrochemical reactions under potential control and its application for the study of electrolyte degradation, and the development of an electrochemical entropy technique combined with x-ray based structural measurements for understanding origins of battery degradation. These approaches led to a number of scientific discoveries. Using STXM we learned that lithium iron phosphate battery cathodes display unexpected behavior during lithiation wherein lithium transport is controlled by nucleation of a lithiated phase, leading to high heterogeneity in lithium content at each particle and a surprising invariance of local current density with the overall electrode charging current. We discovered using in-situ transmission electron microscopy that there is a size limit to lithiation of silicon anode particles above which particle fracture controls electrode degradation. From electrochemical entropy measurements, we discovered that entropy changes little with degradation but the origin of degradation in cathodes is kinetic in nature, i.e. lower rate cycling recovers lost capacity. Finally, our modeling of electrode-electrolyte interfaces revealed that electrolyte degradation may occur by either a single or double electron transfer process depending on thickness of the solid-electrolyte- interphase layer, and this cross-over can be modeled and predicted.

Sullivan, John P; Fenton, Kyle R [Sandia National Laboratories, Albuquerque, NM; El Gabaly Marquez, Farid; Harris, Charles Thomas [Sandia National Laboratories, Albuquerque, NM; Hayden, Carl C.; Hudak, Nicholas [Sandia National Laboratories, Albuquerque, NM; Jungjohann, Katherine Leigh [Sandia National Laboratories, Albuquerque, NM; Kliewer, Christopher Jesse; Leung, Kevin [Sandia National Laboratories, Albuquerque, NM; McDaniel, Anthony H.; Nagasubramanian, Ganesan [Sandia National Laboratories, Albuquerque, NM; Sugar, Joshua Daniel; Talin, Albert Alec; Tenney, Craig M [Sandia National Laboratories, Albuquerque, NM; Zavadil, Kevin R. [Sandia National Laboratories, Albuquerque, NM

2015-01-01T23:59:59.000Z

450

High Performance Batteries Based on Hybrid Magnesium and Lithium Chemistry  

SciTech Connect (OSTI)

Magnesium and lithium (Mg/Li) hybrid batteries that combine Mg and Li electrochemistry, consisting of a Mg anode, a lithium-intercalation cathode and a dual-salt electrolyte with both Mg2+ and Li+ ions, were constructed and examined in this work. Our results show that hybrid (Mg/Li) batteries were able to combine the advantages of Li-ion and Mg batteries, and delivered outstanding rate performance (83% for capacities at 15C and 0.1C) and superior cyclic stability (~5% fade after 3000 cycles).

Cheng, Yingwen; Shao, Yuyan; Zhang, Jiguang; Sprenkle, Vincent L.; Liu, Jun; Li, Guosheng

2014-01-01T23:59:59.000Z

451

Rechargeable Lithium-Air Batteries: Development of Ultra High Specific Energy Rechargeable Lithium-Air Batteries Based on Protected Lithium Metal Electrodes  

SciTech Connect (OSTI)

BEEST Project: PolyPlus is developing the world’s first commercially available rechargeable lithium-air (Li-Air) battery. Li-Air batteries are better than the Li-Ion batteries used in most EVs today because they breathe in air from the atmosphere for use as an active material in the battery, which greatly decreases its weight. Li-Air batteries also store nearly 700% as much energy as traditional Li-Ion batteries. A lighter battery would improve the range of EVs dramatically. Polyplus is on track to making a critical breakthrough: the first manufacturable protective membrane between its lithium–based negative electrode and the reaction chamber where it reacts with oxygen from the air. This gives the battery the unique ability to recharge by moving lithium in and out of the battery’s reaction chamber for storage until the battery needs to discharge once again. Until now, engineers had been unable to create the complex packaging and air-breathing components required to turn Li-Air batteries into rechargeable systems.

None

2010-07-01T23:59:59.000Z

452

Sandia National Laboratories: Batteries & Energy Storage Publications  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

StorageBatteries & Energy Storage Publications Batteries & Energy Storage Publications Batteries & Energy Storage Fact Sheets Achieving Higher Energy Density in Flow Batteries at...

453

accumulateurs lithium-ion au: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

in Lithium Ion Battery Electrodes Texas A&M University - TxSpace Summary: Lithium ion battery systems are promising solutions to current energy storage needs due to their high...

454

Anti-Idling Battery for Truck Applications  

SciTech Connect (OSTI)

In accordance to the Assistance Agreement DE-EE0001036, the objective of this project was to develop an advanced high voltage lithium-ion battery for use in an all-electric HVAC system for Class-7-8 heavy duty trucks. This system will help heavy duty truck drivers meet the tough new anti-idling laws being implemented by over 23 states. Quallion will be partnering with a major OEM supplier of HVAC systems to develop this system. The major OEM supplier will provide Quallion the necessary interface requirements and HVAC hardware to ensure successful testing of the all-electric system. At the end of the program, Quallion will deliver test data on three (3) batteries as well as test data for the prototype HVAC system. The objectives of the program are: (1) Battery Development - Objective 1 - Define battery and electronics specifications in preparation for building the prototype module. (Completed - summary included in report) and Objective 2 - Establish a functional prototype battery and characterize three batteries in-house. (Completed - photos and data included in report); (2) HVAC Development - Objective 1 - Collaborate with manufacturers to define HVAC components, layout, and electronics in preparation for establishing the prototype system. (Completed - photos and data included in report) and Objective 2 - Acquire components for three functional prototypes for use by Quallion. (Completed - photos and data included in report).

Keith Kelly

2011-09-30T23:59:59.000Z

455

Effect of fuel rate and annealing process of LiFePO{sub 4} cathode material for Li-ion batteries synthesized by flame spray pyrolysis method  

SciTech Connect (OSTI)

In this study the effect of fuel rate and annealing on particle formation of LiFePO{sub 4} as battery cathode using flame spray pyrolysis method was investigated numerically and experimentally. Numerical study was done using ANSYS FLUENT program. In experimentally, LiFePO{sub 4} was synthesized from inorganic aqueous solution followed by annealing. LPG was used as fuel and air was used as oxidizer and carrier gas. Annealing process attempted in inert atmosphere at 700°C for 240 min. Numerical result showed that the increase of fuel rate caused the increase of flame temperature. Microscopic observation using Scanning Electron Microscopy (SEM) revealed that all particles have sphere and polydisperse. Increasing fuel rate caused decreasing particle size and increasing particles crystallinity. This phenomenon attributed to the flame temperature. However, all produced particles still have more amorphous phase. Therefore, annealing needed to increase particles crystallinity. Fourier Transform Infrared (FTIR) analysis showed that all particles have PO4 function group. Increasing fuel rate led to the increase of infrared spectrum absorption corresponding to the increase of particles crystallinity. This result indicated that phosphate group vibrated easily in crystalline phase. From Electrochemical Impedance Spectroscopy (EIS) analysis, annealing can cause the increase of Li{sup +} diffusivity. The diffusivity coefficient of without and with annealing particles were 6.84399×10{sup ?10} and 8.59888×10{sup ?10} cm{sup 2} s{sup ?1}, respectively.

Halim, Abdul; Setyawan, Heru; Machmudah, Siti; Nurtono, Tantular; Winardi, Sugeng [Chemical Engineering, Sepuluh Nopember Institute of Technology, Kampus Sukolilo Surabaya Indonesia 60111 (Indonesia)

2014-02-24T23:59:59.000Z

456

The Lithium-Ion Cell: Model, State Of Charge Estimation  

E-Print Network [OSTI]

The Lithium-Ion Cell: Model, State Of Charge Estimation and Battery Management System Tutor degradation mechanisms of a Li-ion cell based on LiCoO2", Journal of Power Sources #12;Lithium ions and e and Y. Fuentes. Computer simulations of a lithium-ion polymer battery and implications for higher

Schenato, Luca

457

Selecting a PV battery  

SciTech Connect (OSTI)

The primary goal for all photovoltaic systems must be to provide value. Since the total life cycle cost of a system will depend on the type of battery installed, the impact of proper battery selection is considerable. For the designer, selecting an ideal battery can be confusing because he seldom has a reliable frame of reference with which to compare options. This article is an attempt to provide that frame of reference by describing a specific battery design which, for many photovoltaic applications, will represent the best value option. Other battery types can then simply be contrasted to this ''reference battery'' to see if they provide better or worse overall value in any particular application.

Jones, W.

1983-01-01T23:59:59.000Z

458

Engineering Recently, we created the first Li-ion electrochemical cell  

E-Print Network [OSTI]

characterization of Li-ion battery materials. In this presentation, I'll first review our latest progress of using for understanding important processes in Li-ion batteries. For example, liquid cells are required in order impact on the design of Li-ion batteries. Finally I will discuss outstanding challenging issues

459

Lithium battery management system  

DOE Patents [OSTI]

Provided is a system for managing a lithium battery system having a plurality of cells. The battery system comprises a variable-resistance element electrically connected to a cell and located proximate a portion of the cell; and a device for determining, utilizing the variable-resistance element, whether the temperature of the cell has exceeded a predetermined threshold. A method of managing the temperature of a lithium battery system is also included.

Dougherty, Thomas J. (Waukesha, WI)

2012-05-08T23:59:59.000Z

460

Flash report: Automotive batteries  

SciTech Connect (OSTI)

Battery inventories soared early in the years after sales plunged 15% due to the mild winter. But in the last 90 days, admist a hot summer, industry leader Exide announced a 5% price hike to assess the current market, OTR interviewed 14 professionals from the battery industry - Contacts include four battery manufacturers, one industry specialists, seven retail chains plus two wholesalers. The nine sales groups supply about 10,000 stores an automotive shops nationwide.

Gates, J.H.

1995-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "ion batteries elucidated" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

Battery Lifetime Analysis and Simulation Tool (BLAST) Documentation  

SciTech Connect (OSTI)

The deployment and use of lithium-ion batteries in automotive and stationary energy storage applications must be optimized to justify their high up-front costs. Given that batteries degrade with use and storage, such optimizations must evaluate many years of operation. As the degradation mechanisms are sensitive to temperature, state-of-charge histories, current levels, and cycle depth and frequency, it is important to model both the battery and the application to a high level of detail to ensure battery response is accurately predicted. To address these issues, the National Renewable Energy Laboratory has developed the Battery Lifetime Analysis and Simulation Tool (BLAST) suite of tools. This suite of tools pairs NREL's high-fidelity battery degradation model with a battery electrical and thermal performance model, application-specific electrical and thermal performance models of the larger system (e.g., an electric vehicle), application-specific system use data (e.g., vehicle travel patterns and driving data), and historic climate data from cities across the United States. This provides highly realistic, long-term predictions of battery response and thereby enables quantitative comparisons of varied battery use strategies.

Neubauer, J.

2014-12-01T23:59:59.000Z

462

battery2.indd  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

High Power Battery Systems Company 5 Silkin Street, Apt. 40 Sarov, Nizhny Novgorod Russia, 607190 Alexander A. Potanin 7-(83130)-43701 (phonefax), potanin@hpbs.ru General...

463

Solid Electrolyte Batteries  

Broader source: Energy.gov (indexed) [DOE]

Kim Texas Materials Institute The University of Texas at Austin Solid Electrolyte Batteries This presentation does not contain any proprietary or confidential information. DOE...

464

EMSL - battery materials  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

battery-materials en Modeling Interfacial Glass-Water Reactions: Recent Advances and Current Limitations. http:www.emsl.pnl.govemslwebpublicationsmodeling-interfacial-glass-wa...

465

On the Accuracy and Simplifications of Battery Models using In Situ Measurements of Lithium Concentration in Operational Cells  

E-Print Network [OSTI]

. INTRODUCTION Accurate estimates of Lithium Ion Battery State of Charge (SOC) are critical for constraining and solid phase lithium distributions across the electrode may better utilize the battery's stored energyOn the Accuracy and Simplifications of Battery Models using In Situ Measurements of Lithium

Stefanopoulou, Anna

466

Design of Electric Drive Vehicle Batteries for Long Life and Low Cost: Robustness to Geographic and Consumer-Usage Variation (Presentation)  

SciTech Connect (OSTI)

This presentation describes a battery optimization and trade-off analysis for Li-ion batteries used in EVs and PHEVs to extend their life and/or reduce cost.

Smith, K.; Markel, T.; Kim, G. H.; Pesaran, A.

2010-10-01T23:59:59.000Z

467

Lithium metal oxide electrodes for lithium cells and batteries  

DOE Patents [OSTI]

A lithium metal oxide positive electrode for a non-aqueous lithium cell is disclosed. The cell is prepared in its initial discharged state and has a general formula xLiMO.sub.2.(1-x)Li.sub.2 M'O.sub.3 in which 0ion with at least one ion being Mn or Ni, and where M' is one or more tetravalent ion. Complete cells or batteries are disclosed with anode, cathode and electrolyte as are batteries of several cells connected in parallel or series or both.

Thackeray, Michael M. (Naperville, IL); Johnson, Christopher S. (Naperville, IL); Amine, Khalil (Downers Grove, IL); Kim, Jaekook (Naperville, IL)

2004-01-13T23:59:59.000Z

468

Intrinsic Surface Stability in LiMn2-xNix04-s (x = 0.45, 0.5) High Voltage Spinel Materials for Lithium Ion Batteries  

SciTech Connect (OSTI)

This work reports the surface stability of the high vollage Li ion cathode LiMn2_,Ni,Ooh\\ (x = 0.5, 0.45) by comparing thin fi lm and powder composite electrodes after cycling using X-ray photoelectron spectroscopy. The thin film electrodes offer the abili ty to probe the surface of the material without the need of a conductive agent and polymer binder typically used in composite electrodes. The resulls suggest that neither oxidation of PP6 to POF3 nor the decomposition of ethylene carbonate or dimethylene carbonate occurs on the surface of the spinel material. These resulls confirm the enhanced cycling stability and rate capability associated with the high vollage spinel material and suggests that the SE!IIayer fonns due to the reaction of electrochemically inactive components in composite electrodes with the electrolyte.

Carroll, Kyler J [University of California, San Diego; Yang, Ming-Che [University of Florida, Gainesville; Veith, Gabriel M [ORNL; Dudney, Nancy J [ORNL; Meng, Ying Shirley [University of California, San Diego

2012-01-01T23:59:59.000Z

469

Optical State-of-Change Monitor for Lead-Acid Batteries  

SciTech Connect (OSTI)

A method and apparatus for determining the instantaneous state-of-charge of a battery in which change in composition with discharge manifests itself as a change in optical absorption. In a lead-acid battery, the sensor comprises a fiber optic system with an absorption cdl or, alternatively, an optical fiber woven into an absorbed-glass-mat battery. In a lithium-ion battery, the sensor comprises fiber optics for introducing light into the anode to monitor absorption when lithium ions are introduced.

Weiss, Jonathan D.

1998-07-24T23:59:59.000Z

470

Servant dictionary battery, map  

E-Print Network [OSTI]

Attic *** book teachest Servant dictionary scarf [11] Winery demijohn battery, map AuntLair X Cupboard1 wireless Potting gloves aunt[3] Storage dumbwaiter wrench OldFurn parcel, med whistle Over] EastAnnex battery[4] Cupboard2 [2] mask DeadEnd rucksack AlisonWriting [16] TinyBalcony [17] gold key

Rosenthal, Jeffrey S.

471

battery, map parcel, med  

E-Print Network [OSTI]

Attic *** book teachest Servant dictionary scarf [11] Winery demijohn battery, map AuntLair X Cupboard1 wireless Potting gloves aunt[3] Storage dumbwaiter wrench OldFurn parcel, med whistle Over] EastAnnex battery[4] Cupboard2 [2] mask DeadEnd rucksack AlisonWriting [16] TinyBalcony [17] gold key

Rosenthal, Jeffrey S.

472

EV Everywhere Batteries Workshop - Next Generation Lithium Ion Batteries  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:Year in Review: TopEnergyIDIQ Contract ESPC IDIQ Contract DocumentBreakout Session Report |

473

Batteries - Next-generation Li-ion batteries Breakout session  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels Data Center Home Page on Delicious Rank EERE:YearRound-Up fromDepartmentTie Ltd: Scope ChangeL-01-06Hot-Humid-Basic Energy20585

474

Semi-Solid Flowable Battery Electrodes: Semi-Solid Flow Cells for Automotive and Grid-Level Energy Storage  

SciTech Connect (OSTI)

BEEST Project: Scientists at 24M are crossing a Li-Ion battery with a fuel cell to develop a semi-solid flow battery. This system relies on some of the same basic chemistry as a standard Li-Ion battery, but in a flow battery the energy storage material is held in external tanks, so storage capacity is not limited by the size of the battery itself. The design makes it easier to add storage capacity by simply increasing the size of the tanks and adding more paste. In addition, 24M's design also is able to extract more energy from the semi-solid paste than conventional Li-Ion batteries. This creates a cost-effective, energy-dense battery that can improve the driving range of EVs or be used to store energy on the electric grid.

2010-09-01T23:59:59.000Z

475

Nanostructured material for advanced energy storage : magnesium battery cathode development.  

SciTech Connect (OSTI)

Magnesium batteries are alternatives to the use of lithium ion and nickel metal hydride secondary batteries due to magnesium's abundance, safety of operation, and lower toxicity of disposal. The divalency of the magnesium ion and its chemistry poses some difficulties for its general and industrial use. This work developed a continuous and fibrous nanoscale network of the cathode material through the use of electrospinning with the goal of enhancing performance and reactivity of the battery. The system was characterized and preliminary tests were performed on the constructed battery cells. We were successful in building and testing a series of electrochemical systems that demonstrated good cyclability maintaining 60-70% of discharge capacity after more than 50 charge-discharge cycles.

Sigmund, Wolfgang M. (University of Florida, Gainesville, FL); Woan, Karran V. (University of Florida, Gainesville, FL); Bell, Nelson Simmons

2010-11-01T23:59:59.000Z

476

Battery Wear from Disparate Duty-Cycles: Opportunities for Electric-Drive Vehicle Battery Health Management; Preprint  

SciTech Connect (OSTI)

Electric-drive vehicles utilizing lithium-ion batteries experience wholly different degradation patterns than do conventional vehicles, depending on geographic ambient conditions and consumer driving and charging patterns. A semi-empirical life-predictive model for the lithium-ion graphite/nickel-cobalt-aluminum chemistry is presented that accounts for physically justified calendar and cycling fade mechanisms. An analysis of battery life for plug-in hybrid electric vehicles considers 782 duty-cycles from travel survey data superimposed with climate data from multiple geographic locations around the United States. Based on predicted wear distributions, opportunities for extending battery life including modification of battery operating limits, thermal and charge control are discussed.

Smith, K.; Earleywine, M.; Wood, E.; Pesaran, A.

2012-10-01T23:59:59.000Z

477

A review of battery life-cycle analysis : state of knowledge and critical needs.  

SciTech Connect (OSTI)

A literature review and evaluation has been conducted on cradle-to-gate life-cycle inventory studies of lead-acid, nickel-cadmium, nickel-metal hydride, sodium-sulfur, and lithium-ion battery technologies. Data were sought that represent the production of battery constituent materials and battery manufacture and assembly. Life-cycle production data for many battery materials are available and usable, though some need updating. For the remaining battery materials, lifecycle data either are nonexistent or, in some cases, in need of updating. Although battery manufacturing processes have occasionally been well described, detailed quantitative information on energy and material flows is missing. For all but the lithium-ion batteries, enough constituent material production energy data are available to approximate material production energies for the batteries, though improved input data for some materials are needed. Due to the potential benefit of battery recycling and a scarcity of associated data, there is a critical need for life-cycle data on battery material recycling. Either on a per kilogram or per watt-hour capacity basis, lead-acid batteries have the lowest production energy, carbon dioxide emissions, and criteria pollutant emissions. Some process-related emissions are also reviewed in this report.

Sullivan, J. L.; Gaines, L.; Energy Systems

2010-12-22T23:59:59.000Z

478

Secondary Use of PHEV and EV Batteries: Opportunities & Challenges (Presentation)  

SciTech Connect (OSTI)

NREL and partners will investigate the reuse of retired lithium ion batteries for plug-in hybrid, hybrid, and electric vehicles in order to reduce vehicle costs and emissions and curb our dependence on foreign oil. A workshop to solicit industry feedback on the process is planned. Analyses will be conducted, and aged batteries will be tested in two or three suitable second-use applications. The project is considering whether retired PHEV/EV batteries have value for other applications; if so, what are the barriers and how can they be overcome?

Neubauer, J.; Pesaran, A.; Howell, D.

2010-05-01T23:59:59.000Z

479

Secondary battery material and synthesis method  

DOE Patents [OSTI]

A composite Li.sub.1+xMn.sub.2-x-yM.sub.yO.sub.4 cathode material stabilized by treatment with a second transition metal oxide phase that is highly suitable for use in high power and energy density Li-ion cells and batteries. A method for treating a Li.sub.1+xMn.sub.2-x-yM.sub.yO.sub.4 cathode material utilizing a dry mixing and firing process.

Liu, Hongjian; Kepler, Keith Douglas; Wang, Yu

2013-10-22T23:59:59.000Z

480

BEEST: Electric Vehicle Batteries  

SciTech Connect (OSTI)

BEEST Project: The U.S. spends nearly a $1 billion per day to import petroleum, but we need dramatically better batteries for electric and plug-in hybrid vehicles (EV/PHEV) to truly compete with gasoline-powered cars. The 10 projects in ARPA-E’s BEEST Project, short for “Batteries for Electrical Energy Storage in Transportation,” could make that happen by developing a variety of rechargeable battery technologies that would enable EV/PHEVs to meet or beat the price and performance of gasoline-powered cars, and enable mass production of electric vehicles that people will be excited to drive.

None

2010-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "ion batteries elucidated" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


481

SOLAR BATTERY CHARGERS FOR NIMH BATTERIES1 Abstract -This paper proposes new solar battery  

E-Print Network [OSTI]

SOLAR BATTERY CHARGERS FOR NIMH BATTERIES1 Abstract - This paper proposes new solar battery chargers for NiMH batteries. Used with portable solar panels, existing charge control methods are shown of consumer portable solar arrays. These new arrays are lightweight, durable, and flexible and have been

Lehman, Brad

482

Colorado: Isothermal Battery Calorimeter Quantifies Heat Flow...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

Isothermal Battery Calorimeter Quantifies Heat Flow, Helps Make Safer, Longer-lasting Batteries Colorado: Isothermal Battery Calorimeter Quantifies Heat Flow, Helps Make Safer,...

483

Design and Simulation of Lithium Rechargeable Batteries  

E-Print Network [OSTI]

Gabano, Ed. , Lithium Batteries, Academic Press, New York,K. V. Kordesch, "Primary Batteries 1951-1976," J. Elec- n ~.Rechargeable Lithium Batteries," J. Electrochem. Soc. , [20

Doyle, C.M.

2010-01-01T23:59:59.000Z

484

Design and Simulation of Lithium Rechargeable Batteries  

E-Print Network [OSTI]

J. -P. Gabano, Ed. , Lithium Batteries, Academic Press, Newfor Rechargeable Lithium Batteries," J. Electrochem.for Rechargeable Lithium Batteries," J. Electroclzern.

Doyle, C.M.

2010-01-01T23:59:59.000Z

485

Ionic liquids for rechargeable lithium batteries  

E-Print Network [OSTI]

for rechargeable lithium batteries (Preliminary report,applications using lithium batteries, we must be sure thattemperature range. For lithium batteries in hybrid vehicles,

Salminen, Justin; Papaiconomou, Nicolas; Kerr, John; Prausnitz, John; Newman, John

2008-01-01T23:59:59.000Z

486

Block copolymer electrolytes for lithium batteries  

E-Print Network [OSTI]

polymer electrolytes for lithium batteries. Nature 394, 456-facing rechargeable lithium batteries. Nature 414, 359-367 (vanadium oxides for lithium batteries. Journal of Materials

Hudson, William Rodgers

2011-01-01T23:59:59.000Z

487

Single Nanorod Devices for Battery Diagnostics: A Case Study on LiMn2O4  

E-Print Network [OSTI]

correlate well with the better cycling performance of Al-doped LiMn2O4 in our Li-ion battery tests: LiAl0Single Nanorod Devices for Battery Diagnostics: A Case Study on LiMn2O4 Yuan Yang, Chong Xie nanostructure devices as a powerful new diagnostic tool for batteries with LiMn2O4 nanorod materials

Cui, Yi

488

Parallel flow diffusion battery  

DOE Patents [OSTI]

A parallel flow diffusion battery for determining the mass distribution of an aerosol has a plurality of diffusion cells mounted in parallel to an aerosol stream, each diffusion cell including a stack of mesh wire screens of different density.

Yeh, H.C.; Cheng, Y.S.

1984-01-01T23:59:59.000Z

489

Side terminal battery  

SciTech Connect (OSTI)

A side terminal battery and method of making same is shown and described. In particular, the terminal includes an electrically conductive plug disposed within an externally extending boss. The plug does not extend into the battery. Rather, a riser is welded to the plug through an aperture disposed at the base of the boss. The terminal is mechanically crimped to further ensure the leak-resistant soundness of the joint between the plug and riser.

Clingenpeel, W.R.

1981-12-08T23:59:59.000Z

490

Novel Redox Shuttles for Overcharge Protection of Lithium-Ion...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Redox Shuttles for Overcharge Protection of Lithium-Ion Batteries Technology available for licensing: Electrolytes containing novel redox shuttles (electron transporters) for...

491

JCESR: Moving Beyond Lithium-Ion | Argonne National Laboratory  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

JCESR: Moving Beyond Lithium-Ion Share Topic Energy Energy usage Energy storage Batteries Browse By - Any - Energy -Energy efficiency --Vehicles ---Alternative fuels ---Automotive...

492

Comparison of Battery Life Across Real-World Automotive Drive-Cycles (Presentation)  

SciTech Connect (OSTI)

Laboratories run around-the-clock aging tests to try to understand as quickly as possible how long new Li-ion battery designs will last under certain duty cycles. These tests may include factors such as duty cycles, climate, battery power profiles, and battery stress statistics. Such tests are generally accelerated and do not consider possible dwell time at high temperatures and states-of-charge. Battery life-predictive models provide guidance as to how long Li-ion batteries may last under real-world electric-drive vehicle applications. Worst-case aging scenarios are extracted from hundreds of real-world duty cycles developed from vehicle travel surveys. Vehicles examined included PHEV10 and PHEV40 EDVs under fixed (28 degrees C), limited cooling (forced ambient temperature), and aggressive cooling (20 degrees C chilled liquid) scenarios using either nightly charging or opportunity charging. The results show that battery life expectancy is 7.8 - 13.2 years for the PHEV10 using a nightly charge in Phoenix, AZ (hot climate), and that the 'aggressive' cooling scenario can extend battery life by 1-3 years, while the 'limited' cooling scenario shortens battery life by 1-2 years. Frequent (opportunity) charging can reduce battery life by 1 year for the PHEV10, while frequent charging can extend battery life by one-half year.

Smith, K.; Earleywine, M.; Wood, E.; Pesaran, A.

2011-11-01T23:59:59.000Z

493

Molecular Architecture for Polyphosphazene Electrolytes for Seawater Batteries  

SciTech Connect (OSTI)

In this work, a series of polyphosphazenes were designed to function as water resistant, yet ionically conductive membranes for application to lithium/seawater batteries. In membranes of this nature, various molecular architectures are possible and representatives from each possible type were chosen. These polymers were synthesized and their performance as solid polymer electrolytes was evaluated in terms of both lithium ion conductivity and water permeability. The impact that this molecular architecture has on total performance of the membranes for seawater batteries is discussed. Further implications of this molecular architecture on the mechanisms of lithium ion transport through polyphosphazenes are also discussed.

Mason K. Harrup; Mason K. Harrup; Thomas A. Luther; Christopher J. Orme; Eric S. Peterson

2005-08-01T23:59:59.000Z

494

PARAMETERIZATION AND VALIDATION OF AN INTEGRATED ELECTRO-THERMAL CYLINDRICAL LFP BATTERY MODEL  

E-Print Network [OSTI]

with a two-state thermal model to form an electro-thermal model for cylindrical lithium ion batteries- eters. A two-state thermal model is used to approximate the core and surface temperatures of the battery to lithium diffusion in the solid phase and in the electrolyte [13]. These circuit elements depend on state

Stefanopoulou, Anna

495

New Nanostructured Li2S/Silicon Rechargeable Battery with High Specific Energy  

E-Print Network [OSTI]

an average voltage of 2.2 V vs Li/Li+ (about 60% of the voltage of conventional Li-ion batteries nanowires R echargeable batteries are critical power sources for mobile applications such as portable-11 the relatively low charge capacity of cathodes remains the limiting factor preventing higher energy density

Cui, Yi

496

New sealed rechargeable batteries and supercapacitors  

SciTech Connect (OSTI)

This conference was divided into the following sections: supercapacitors; nickel-metal hydride batteries; lithium polymer batteries; lithium/carbon batteries; cathode materials; and lithium batteries. Separate abstracts were prepared for the 46 papers of this conference.

Barnett, B.M. (ed.) (Arthur D. Little, Inc., Cambridge, MA (United States)); Dowgiallo, E. (ed.) (Dept. of Energy, Washington, DC (United States)); Halpert, G. (ed.) (Jet Propulsion Lab., Pasadena, CA (United States)); Matsuda, Y. (ed.) (Yamagushi Univ., Ube (Japan)); Takehara, Z.I. (ed.) (Kyoto Univ. (Japan))

1993-01-01T23:59:59.000Z

497

Nickel coated aluminum battery cell tabs  

DOE Patents [OSTI]

A battery cell tab is described. The battery cell tab is anodized on one end and has a metal coating on the other end. Battery cells and methods of making battery cell tabs are also described.

Bucchi, Robert S.; Casoli, Daniel J.; Campbell, Kathleen M.; Nicotina, Joseph

2014-07-29T23:59:59.000Z

498

Testimonials- Partnerships in Battery Technologies- CalBattery  

Broader source: Energy.gov [DOE]

Phil Roberts, CEO and Founder of California Lithium Battery (CalBattery), describes the new growth and development that was possible through partnering with the U.S. Department of Energy.

499

Advanced battery technology for electric two-wheelers in the people's Republic of China.  

SciTech Connect (OSTI)

This report focuses on lithium-ion (Li-ion) battery technology applications for two- and possibly three-wheeled vehicles. The author of this report visited the People's Republic of China (PRC or China) to assess the status of Li-ion battery technology there and to analyze Chinese policies, regulations, and incentives for using this technology and for using two- and three-wheeled vehicles. Another objective was to determine if the Li-ion batteries produced in China were available for benchmarking in the United States. The United States continues to lead the world in Li-ion technology research and development (R&D). Its strong R&D program is funded by the U.S. Department of Energy and other federal agencies, such as the National Institute of Standards and Technology and the U.S. Department of Defense. In Asia, too, developed countries like China, Korea, and Japan are commercializing and producing this technology. In China, more than 120 companies are involved in producing Li-ion batteries. There are more than 139 manufacturers of electric bicycles (also referred to as E-bicycles, electric bikes or E-bikes, and electric two-wheelers or ETWs in this report) and several hundred suppliers. Most E-bikes use lead acid batteries, but there is a push toward using Li-ion battery technology for two- and three-wheeled applications. Highlights and conclusions from this visit are provided in this report and summarized.

Patil, P. G.; Energy Systems

2009-07-22T23:59:59.000Z

500

Novel electrolyte chemistries for Mg-Ni rechargeable batteries.  

SciTech Connect (OSTI)

Commercial hybrid electric vehicles (HEV) and battery electric vehicles (BEV) serve as means to reduce the nation's dependence on oil. Current electric vehicles use relatively heavy nickel metal hydride (Ni-MH) rechargeable batteries. Li-ion rechargeable batteries have been developed extensively as the replacement; however, the high cost and safety concerns are still issues to be resolved before large-scale production. In this study, we propose a new highly conductive solid polymer electrolyte for Mg-Ni high electrochemical capacity batteries. The traditional corrosive alkaline aqueous electrolyte (KOH) is replaced with a dry polymer with conductivity on the order of 10{sup -2} S/cm, as measured by impedance spectroscopy. Several potential novel polymer and polymer composite candidates are presented with the best-performing electrolyte results for full cell testing and cycling.

Garcia-Diaz, Brenda (Savannah River National Laboratory); Kane, Marie; Au, Ming (Savannah River National Laboratory)

2010-10-01T23:59:59.000Z