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Note: This page contains sample records for the topic "iodine phos phorus" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

PhosPhorus, Agriculture &  

E-Print Network [OSTI]

Phosphorus lost from agricultural soils can increase the fertility status of natural waters (eutrophication that controls eutrophication of fresh waters.The USEPA has recommended a limit for controlling eutrophication have not been established. Numerous water quality problems have been associated with eutrophication

Liskiewicz, Maciej

2

Phos-toolsTM Phos-tagTM 540 Phosphoprotein Blot Stain  

E-Print Network [OSTI]

maintenance, gene expression, cell division, signal transduction, and apoptosis. PerkinElmer's proprietary procedure is simple, reliable and robust, requiring as little as 2-3 hours to complete. Phos maxima of 300 and 460 nm, with a broad emission maximum centered at approximately 630 nm. Thus, the two

Lebendiker, Mario

3

Test of an LED Monitoring System for the PHOS Spectrometer  

E-Print Network [OSTI]

Preprint submitted to Elsevier Print on 26th January 2000A prototype monitoring system for the Photon Spectrometer (PHOS) of the ALICE experiment at LHC is described in detail. The prototype consists of Control and Master modules. The first one is 8x8 matrix of Light Emitting Diodes coupled with stable generators of current pulses. The system provides an individual control for each of the 64 channels of PHOS prototype based on lead-tungstate crystals. A long term stability of order of 10-3 has been achieved in integral beam tests of the monitoring system and PHOS prototypes.

Blick, A M; Erin, S V; Kharlov, Yu V; Lobanov, M O; Mikhailov, Yu V; Minaev, N G; Petrov, V A; Sadovsky, S A; Samoylenko, V D; Suzdalev, V I; Senko, V A; Tikhonov, V V

1999-01-01T23:59:59.000Z

4

E-Print Network 3.0 - alice phos calorimeter Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Summary: The ALICE experiment at LHC will detect and identify prompt photons and light neutral-mesons with the PHOS... photons in ALICE with the high resolution pho- ton...

5

PerkinElmer Life and Analytical Sciences Phos-toolsTM  

E-Print Network [OSTI]

a critical role in the regulation of cell signaling, metabolic maintenance, gene expression, cell divi- sion. The staining procedure is simple, reliable and robust, re- quiring as little as 3-4 hours to complete. Phos excitation maxima of 300 and 460 nm, with a broad emission maximum centered at approximately 630 nm. Thus

Lebendiker, Mario

6

Iodine transport analysis in the ESBWR.  

SciTech Connect (OSTI)

A simplified ESBWR MELCOR model was developed to track the transport of iodine released from damaged reactor fuel in a hypothesized core damage accident. To account for the effects of iodine pool chemistry, radiolysis of air and cable insulation, and surface coatings (i.e., paint) the iodine pool model in MELCOR was activated. Modifications were made to MELCOR to add sodium pentaborate as a buffer in the iodine pool chemistry model. An issue of specific interest was whether iodine vapor removed from the drywell vapor space by the PCCS heat exchangers would be sequestered in water pools or if it would be rereleased as vapor back into the drywell. As iodine vapor is not included in the deposition models for diffusiophoresis or thermophoresis in current version of MELCOR, a parametric study was conducted to evaluate the impact of a range of iodine removal coefficients in the PCCS heat exchangers. The study found that higher removal coefficients resulted in a lower mass of iodine vapor in the drywell vapor space.

Kalinich, Donald A.; Gauntt, Randall O.; Young, Michael Francis; Longmire, Pamela

2009-03-01T23:59:59.000Z

7

Subnanosecond photodissociation atomic iodine laser  

SciTech Connect (OSTI)

The Q factor of an iodine photodissociation laser was switched periodically by a quarter-wave Pockels cell. The voltage applied to the cell was produced by discharging a cable line and it represented a sequence of damped trapezoidal pulses with steep edges. The repetition period of the transmission maxima of the switch was equal to the round-trip time of the resonator. The gas mixture consisted of C/sub 3/F/sub 7/I (7--15 Torr) and Ar; the total pressure was 1 atm. A train of subnanosecond laser pulses consisting of 3--4 pulses was obtained. The total energy of the train was 10--20 mJ and the minimum duration of a single pulse was 0.4 nsec.

Acnenkov, V.I.; Belotserkovets, A.V.; Grigorovich, S.V.

1981-09-01T23:59:59.000Z

8

Bid Ceil (1996) 87, 143-147 0 Elsevier. Paris  

E-Print Network [OSTI]

stained in a non-Feulgen procedure with osmium annnine-B and imaged at several electron energy the distribution of nucleic acid phos- phorus. osmium ammine-B / energy filtered TEM / RNA / phosphorus mapping- proteins;hnRNP, heterogeneous nuclear RNP. (BR) granules [12, 14, 151. The advantage of employing ES1

Olins, Ada L.

1996-01-01T23:59:59.000Z

9

The influence of phosphorus nutrition and water stress on the osmotic adjustment and growth of loblolly pine  

E-Print Network [OSTI]

LITERATURE REVIEW Water Stress Osmotic Adjustment Phosphorus MATERIALS AND METHODS Experimental Design Sowing Preparation Sowing and Seedling Cultivation Treatments . . . . . . . ~ Measurements . . . . . . - ~ ~ ~ Statistical Analysis RESULTS... three days. Fertilizer was applied every other time the seedlings received water. Treatments were initiated to provide three levels of phos- phorus nutrition (10, 100, 200 ppm) and three levels of water stress. Water stress was imposed...

Wilson, Alan Byron

1985-01-01T23:59:59.000Z

10

Mixed-layered bismuth-oxygen-iodine materials for capture and waste disposal of radioactive iodine  

DOE Patents [OSTI]

Materials and methods of synthesizing mixed-layered bismuth oxy-iodine materials, which can be synthesized in the presence of aqueous radioactive iodine species found in caustic solutions (e.g. NaOH or KOH). This technology provides a one-step process for both iodine sequestration and storage from nuclear fuel cycles. It results in materials that will be durable for repository conditions much like those found in Waste Isolation Pilot Plant (WIPP) and estimated for Yucca Mountain (YMP). By controlled reactant concentrations, optimized compositions of these mixed-layered bismuth oxy-iodine inorganic materials are produced that have both a high iodine weight percentage and a low solubility in groundwater environments.

Krumhansl, James L; Nenoff, Tina M

2013-02-26T23:59:59.000Z

11

The Behaviour ofIodine in the Terrestrial Environment.  

E-Print Network [OSTI]

The Behaviour ofIodine in the Terrestrial Environment. An Investigation of the Possible Roskilde, Denmark Febtuary 1990 #12;1 Risř-M-2851 THE BEHAVIOUR OF IODINE IN THE TERRESTRIAL ENVIRONMENT influence the migration behaviour of iodine in the terrestrial environment. It is stated that the organic

12

Speciation and transport of anthropogenic 129Iodine and natural 127Iodine in surface and subsurface environments  

E-Print Network [OSTI]

, the majority of iodine appears to be in proteins (Hou et al., 2000). In humic acids, the majority of iodine appears to be in methoxy-phenols (Warner et al., 2000). In experiments where natural organic matter in river water is exposed to inorganic I- for ~ 2... for the degree of DOCTOR OF PHILOSOPHY Approved as to style and content by: Peter H. Santschi (Chair of Committee) Luis A. Cifuentes (Member) Gary A. Gill (Member) Ethan Grossman (Member) Laodong Guo (Member) Wilford D...

Schwehr, Kathleen Ann

2005-02-17T23:59:59.000Z

13

Method for gettering organic, inorganic and elemental iodine in aqueous solutions  

DOE Patents [OSTI]

A process for the removal of iodine from aqueous solutions, particularly the trapping of radioactive iodine to mitigate damage resulting from accidents or spills associated with nuclear reactors, by exposing the solution to well dispersed silver carbonate which reacts with the iodine and iodides, thereby gettering iodine and iodine compounds from solution. The iodine is not only removed from solution but also from the contiguous vapor.

Beahm, Edward C. (Oak Ridge, TN); Shockley, William E. (Oak Ridge, TN)

1990-01-01T23:59:59.000Z

14

Iodine Sorbent Performance in FY 2012 Deep Bed Tests  

SciTech Connect (OSTI)

Nuclear fission results in the production of fission products and activation products, some of which tend to be volatile during used fuel reprocessing and evolve in gaseous species into the reprocessing facility off-gas systems. Analyses have shown that I-129, due to its radioactivity, high potential mobility in the environment, and high longevity (half life of 15.7 million years), can require control efficiencies of up to 1,000x or higher to meet regulatory emission limits. Iodine capture is an important aspect of the Separations and Waste Forms Campaign Off-gas Sigma Team (Jubin 2011, Pantano 2011). Deep-bed iodine sorption tests for both silver-functionalized Aerogel and silver zeolite sorbents were performed during Fiscal Year 2012. These tests showed that: • Decontamination factors were achieved that exceed reasonably conservative estimates for DFs needed for used fuel reprocessing facilities in the U.S. to meet regulatory requirements for I-129 capture. • Silver utilizations approached or exceeded 100% for high inlet gas iodine concentrations, but test durations were not long enough to approach 100% silver utilization for lower iodine concentrations. • The depth of the mass transfer zone was determined for both low iodine concentrations (under 10 ppmv) and for higher iodine concentrations (between 10-50 ppmv); the depth increases over time as iodine is sorbed. • These sorbents capture iodine by chemisorption, where the sorbed iodine reacts with the silver to form very non-volatile AgI. Any sorbed iodine that is physisorbed but not chemically reacted with silver to form AgI might not be tightly held by the sorbent. The portion of sorbed iodine that tends to desorb because it is not chemisorbed (reacted to form AgI) is small, under 1%, for the AgZ tests, and even smaller, under 0.01%, for the silver-functionalized Aerogel.

Nick Soelberg; Tony Watson

2012-08-01T23:59:59.000Z

15

Determination of iodine to compliment mass spectrometric measurements  

SciTech Connect (OSTI)

The dose of iodine-129 to facility personnel and the general public as a result of past, present, and future activities at DOE sites is of continuing interest, WINCO received about 160 samples annually in a variety of natural matrices, including snow, milk, thyroid tissue, and sagebrush, in which iodine-129 is determined in order to evaluate this dose, Currently, total iodine and the isotopic ratio of iodine-127 to iodine-129 are determined by mass spectrometry. These two measurements determine the concentration of iodine-129 in each sample, These measurements require at least 16 h of mass spectrometer operator time for each sample. A variety of methods are available which concentrate and determine small quantities of iodine. Although useful, these approaches would increase both time and cost. The objective of this effort was to determine total iodine by an alternative method in order to decrease the load on mass spectrometry by 25 to 50%. The preparation of each sample for mass spectrometric analysis involves a common step--collection of iodide on an ion exchange bed. This was the focal point of the effort since the results would be applicable to all samples.

Hohorst, F.A.

1994-11-01T23:59:59.000Z

16

Detection of iodine monoxide in the tropical free troposphere  

E-Print Network [OSTI]

19, 2012) Atmospheric iodine monoxide (IO) is a radical that catalytically destroys heat trapping in the remote tropical marine boundary layer (MBL) (2­4). IO further affects the oxidative capacity iodine species over the remote ocean remain poorly understood (11, 14) but are currently thought

17

Gain and continuous-wave laser power enhancement with a secondary discharge to predissociate molecular iodine  

E-Print Network [OSTI]

with this chemical singlet oxygen generator motivated many investi- gations into an electrically driven oxygen molecular iodine in an electric oxygen-iodine laser G. F. Benavides,1 J. W. Zimmerman,2 B. S. Woodard,2 D. L the addition of a secondary discharge to predissociate the molecular iodine in an electric oxygen-iodine laser

Carroll, David L.

18

Aging and iodine loading of silver-functionalized aerogels  

SciTech Connect (OSTI)

Engineered silver-functionalized silica aerogels are being investigated for their potential application in off-gas treatment at a used nuclear fuel reprocessing facility. Reprocessing will release several key volatile radionuclides, including iodine-129. To achieve regulatory compliance, iodine-129 must be removed from any off-gas stream prior to environmental discharge. Ag{sup 0}-functionalized aerogels have been demonstrated to have high iodine-capture capacity, high porosity, and potential for conversion into a waste form. Capture materials used in off-gas treatment may be exposed to a heated, high-humidity, acidic gas stream for months. Extended exposure to this stream could affect sorbent performance. It was the aim of this study to evaluate what impacts might be observed when Ag{sup 0}-functionalized aerogels prepared at Pacific Northwest National Laboratory were contacted with a dry air stream for up to 6 months and then used to adsorb iodine from a synthetic off-gas stream. Results demonstrate that there is some loss of iodine-capture capacity caused by aging, but that this loss is not as marked as for aging of more traditional iodine sorbents, such as silver-impregnated mordenite. Specifically, aging silver-functionalized aerogel under a dry air stream for up to 6 months can decrease its iodine capacity from 41 wt% to 32 wt%. (authors)

Bruffey, S.H.; Jubin, R.T.; Anderson, K.K.; Walker, J.F. [Oak Ridge National Laboratory, P.O. Box 2008, MS-6223, Oak Ridge, TN 37831 (United States)

2013-07-01T23:59:59.000Z

19

AGING AND IODINE LOADING OF SILVER-FUNCTIONALIZED AEROGELS  

SciTech Connect (OSTI)

Engineered silver-functionalized silica aerogels are being investigated for their application in off-gas treatment at a used nuclear fuel reprocessing facility. Reprocessing will release several key volatile radionuclides, including iodine-129. To achieve regulatory compliance, iodine-129 must be removed from any off-gas stream prior to environmental discharge. Silver-functionalized aerogels have been demonstrated to have high iodine capture capacity, high porosity and potential for conversion into a waste form. Capture materials used in off-gas treatment may be exposed to a heated, high humidity, acidic gas stream for months. Extended exposure to this stream could affect sorbent performance. It was the aim of this study to evaluate what impacts might be observed when Ag0-functionalized aerogels prepared at Pacific Northwest National Laboratory were contacted with a dry air stream for up to 6 months and then used to adsorb iodine from a synthetic off-gas stream. Results demonstrate that there is some loss of iodine capture capacity caused by aging, but that this loss is not as marked as for aging of more traditional iodine sorbents, such as silver-impregnated mordenite. Specifically, aging silver-functionalized aerogel under a dry air stream for up to 6 months can decrease its iodine capacity from 41wt% to 32wt%.

Bruffey, Stephanie H [ORNL; Jubin, Robert Thomas [ORNL; Anderson, Kaara K [ORNL; Walker Jr, Joseph Franklin [ORNL

2013-01-01T23:59:59.000Z

20

Iodine-coordinated sulfide leads to an exceptionally stable ceramic...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

LPS and LiI. This new formulation takes advantage of the chemical stability of LiI to render an electrolyte with excellent compatability with Li anode. Additionally, the iodine...

Note: This page contains sample records for the topic "iodine phos phorus" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Origin of electronic transport of lithium phthalocyanine iodine crystal  

SciTech Connect (OSTI)

The electronic structures of Lithium Phthalocyanine Iodine are investigated using density functional theory. Comparing the band structures of several model crystals, the metallic conductivity of highly doped LiPcI{sub x} can be explained by the band of doped iodine. These results reveal that there is a new mechanism for electronic transport of doped organic semiconductors that the dopant band plays the main role.

Koike, Noritake; Oda, Masato; Shinozuka, Yuzo [Department of Materials Science and Chemistry, Wakayama University, 930 Sakaedani, Wakayama (Japan)

2013-12-04T23:59:59.000Z

22

Iodine in Drinking Waters, Vegetables, Cottonseed Meal, and Roughages.  

E-Print Network [OSTI]

LIBRARY, A & M COLLEGE, G. S. FRAPS and J. F. FUDGE Division of Chemistry TEXAS AGRICULTURAL EXPERIMENT STATION A. B. CONNER, DIRECTOR, College Station, Texas BULLETIN NO. 595 NOVEMBER 1940 -- IODINE IN DRINKING WATERS, VEGETABLES..., COTTONSEED MEAL, AND ROUGEIAGES ! .I rq?,\\?Y - AGRICULTURAL AND MECHANICAL COLLEGE OF TEXAS T. 0. WALTON, President A96-1140-7M-LJ.80 5 [Blank Page in Original Bulletin] Iodine was determined in nearly 500 samples of city and rural drinking waters...

Fudge, J. F. (Joseph Franklin); Fraps, G. S. (George Stronach)

1940-01-01T23:59:59.000Z

23

Deep Bed Iodine Sorbent Testing FY 2011 Report  

SciTech Connect (OSTI)

Nuclear fission results in the production of fission products (FPs) and activation products that increasingly interfere with the fission process as their concentrations increase. Some of these fission and activation products tend to evolve in gaseous species during used nuclear fuel reprocessing. Analyses have shown that I129, due to its radioactivity, high potential mobility in the environment, and high longevity (half life of 15.7 million years), can require control efficiencies of up to 1,000x or higher to meet regulatory emission limits. Deep-bed iodine sorption testing has been done to evaluate the performance of solid sorbents for capturing iodine in off-gas streams from nuclear fuel reprocessing plants. The objectives of the FY 2011 deep bed iodine sorbent testing are: (1) Evaluate sorbents for iodine capture under various conditions of gas compositions and operating temperature (determine sorption efficiencies, capacities, and mass transfer zone depths); and (2) Generate data for dynamic iodine sorption modeling. Three tests performed this fiscal year on silver zeolite light phase (AgZ-LP) sorbent are reported here. Additional tests are still in progress and can be reported in a revision of this report or a future report. Testing was somewhat delayed and limited this year due to initial activities to address some questions of prior testing, and due to a period of maintenance for the on-line GC. Each test consisted of (a) flowing a synthetic blend of gases designed to be similar to an aqueous dissolver off-gas stream over the sorbent contained in three separate bed segments in series, (b) measuring each bed inlet and outlet gas concentrations of iodine and methyl iodide (the two surrogates of iodine gas species considered most representative of iodine species expected in dissolver off-gas), (c) operating for a long enough time to achieve breakthrough of the iodine species from at least one (preferably the first two) bed segments, and (d) post-test purging with pure N2 to drive loosely or physisorbed iodine species off of the sorbent. Post-test calculations determine the control efficiencies for each bed, iodine loadings on the sorbent, and mass transfer zone depths. Portions of the iodine-laden sorbent from the first bed of two of the tests have been shipped to SNL for waste form studies. Over the past three years, we have explored a full range of inlet iodine and methyl iodide concentrations ranging from {approx}100 ppb to {approx}100 ppm levels, and shown adequate control efficiencies within a bed depth as shallow as 2 inches for lower concentrations and 4 inches for higher concentrations, for the AgZ-type sorbents. We are now performing a limited number of tests in the NC-77 sorbent from SNL. Then we plan to continue to (a) fill in data gaps needed for isotherms and dynamic sorbent modeling, and (b) test the performance of additional sorbents under development.

Nick Soelberg; Tony Watson

2011-08-01T23:59:59.000Z

24

Summary of FY 2010 Iodine Capture Studies at the INL  

SciTech Connect (OSTI)

Three breakthrough runs using silver mordenite sorbents were conducted and a dynamic sorption capacity estimated based on MeI analysis from a 2" bed. However, it is now believed the data for the first 2 runs is incomplete because the contributions from elemental iodine were not included. Although the only source of iodine was MeI, elemental iodine was generated within the sorbent bed, presumably from a recombination reaction likely catalyzed by silver mordenite. On-line effluent analysis with a GC was only capable of analyzing MeI, not I2. Scrub samples drawn during Run #3, which are specific for I2, show significant levels of I2 being emitted from a partially spent Ag-mordenite bed. By combining MeI and I2 analyses, a well defined total iodine breakthrough curve can be generated for Run #3. At the conclusion of Run #3 (IONEX Ag-900 was the sorbent) the effluent level from Bed 2 was approaching 70% of the feed concentration. The leading bed (Bed 1) had an estimated average loading of 66 mg I/g sorbent, Bed 2's was 52 mg I/g. The corresponding silver utilizations (assuming formation of AgI) were about 59% and 46%, respectively. The spent sorbents are being sent to Sandia National Laboratories for confirmatory analysis of iodine and silver utilization as well as source material for waste form development.

Daryl R. Haefner; Tony L. Watson; Michael G. Jones

2010-08-01T23:59:59.000Z

25

Low sintering temperature glass waste forms for sequestering radioactive iodine  

DOE Patents [OSTI]

Materials and methods of making low-sintering-temperature glass waste forms that sequester radioactive iodine in a strong and durable structure. First, the iodine is captured by an adsorbant, which forms an iodine-loaded material, e.g., AgI, AgI-zeolite, AgI-mordenite, Ag-silica aerogel, ZnI.sub.2, CuI, or Bi.sub.5O.sub.7I. Next, particles of the iodine-loaded material are mixed with powdered frits of low-sintering-temperature glasses (comprising various oxides of Si, B, Bi, Pb, and Zn), and then sintered at a relatively low temperature, ranging from 425.degree. C. to 550.degree. C. The sintering converts the mixed powders into a solid block of a glassy waste form, having low iodine leaching rates. The vitrified glassy waste form can contain as much as 60 wt % AgI. A preferred glass, having a sintering temperature of 500.degree. C. (below the silver iodide sublimation temperature of 500.degree. C.) was identified that contains oxides of boron, bismuth, and zinc, while containing essentially no lead or silicon.

Nenoff, Tina M.; Krumhansl, James L.; Garino, Terry J.; Ockwig, Nathan W.

2012-09-11T23:59:59.000Z

26

E-Print Network 3.0 - atomic iodine laser Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

iodine laser Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic iodine laser Page: << < 1 2 3 4 5 > >> 1 JOURNALDE PHYSIQUEIV ColloqueC7,...

27

E-Print Network 3.0 - acex project iodine Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

eggs. Sunlight was used as the control. Adults in the quartz-iodine... the rare earth lamp was used as a substitute. Egg hatch for the quartz-iodine lamp and sunlight ... Source:...

28

Light-Induced Passivation of Si by Iodine Ethanol Solution: Preprint  

SciTech Connect (OSTI)

We report on our observations of light-activated passivation of silicon surfaces by iodine-ethanol solution.

Sopori, B.; Rupnowski, P.; Appel, J.; Guhaabiswas, D.; Anderson-Jackson, L.

2009-02-01T23:59:59.000Z

29

Discovery of palladium, antimony, tellurium, iodine, and xenon isotopes  

SciTech Connect (OSTI)

Currently, thirty-eight palladium, thirty-eight antimony, thirty-nine tellurium, thirty-eight iodine, and forty xenon isotopes have been observed and the discovery of these isotopes is described here. For each isotope a brief synopsis of the first refereed publication, including the production and identification method, is presented.

Kathawa, J.; Fry, C.; Thoennessen, M., E-mail: thoennessen@nscl.msu.edu

2013-01-15T23:59:59.000Z

30

Aging of Iodine-Loaded Silver Mordenite in NO2  

SciTech Connect (OSTI)

Used nuclear fuel facilities need to control and minimize radioactive emissions. Off-gas systems are designed to remove radioactive contaminants, such as 85Kr, 14C, 3H, and 129I. In an off-gas system, any capture material will be exposed to a gas stream for months at a time. This gas stream may be at elevated temperature and could contain water, NOx gas, or a variety of other constituents comprising the dissolver off-gas stream in a nuclear fuel reprocessing plant. For this reason, it is important to evaluate the effects of long-term exposure, or aging, on proposed capture materials. One material under consideration is reduced silver mordenite (Ag0Z), which is recognized for its efficient iodine capture properties. Iodine is immobilized on Ag0Z as AgI, a solid with low volatility (m.p. ? 500°C). The aim of this study was to determine whether extended aging at elevated temperature in a nominally 2% NO2 environment would result in a loss of immobilized iodine from this material due to either physical or chemical changes that might occur during aging. Charges of iodine-loaded reduced silver mordenite (I2-Ag0Z) were exposed to a 2% NO2 environment for 1, 2, 3, and 4 months at 150°C, then analyzed for iodine losses The aging study was completed successfully. The material did not visibly change color or form. The results demonstrate that no significant iodine loss was observed over the course of 4 months of 2% NO2 aging of I2-Ag0Z at elevated temperature within the margin of error and the variability (~10%) in the loading along the beds. This provides assurance that iodine will remain immobilized on Ag0Z during extended online use in an off-gas capture treatment system. Future tests should expose I2-Ag0Z to progressively more complex feed gases in an effort to accurately replicate the conditions expected in a reprocessing facility.

Bruffey, Stephanie H. [ORNL; Jubin, Robert Thomas [ORNL; Patton, Kaara K. [ORNL; Walker Jr, Joseph Franklin [ORNL

2014-04-01T23:59:59.000Z

31

Iodine-129 and Iodine-127 speciation in groundwater at the Hanford Site, U.S.: iodate incorporation into calcite  

SciTech Connect (OSTI)

The Hanford Site, the most contaminated nuclear site in the United States, has large radioactive waste plumes containing high 129I levels. The geochemical transport and fate of radioiodine depends largely on its chemical speciation that is greatly affected by environmental factors. This study reports, for the first time, the speciation of stable and radioactive iodine in the groundwater from the Hanford Site. Iodate was the dominant species and accounts for up to 84%, followed by organo-iodine and minimal levels of iodide. The relatively high pH and oxidizing environment may have prevented iodate reduction. Our results identified that calcite precipitation caused by degassing of CO2 during deep groundwater sampling incorporated between 7 to 40% of dissolved iodine (including 127I and 129I) that was originally in the groundwater, transforming dissolved to particulate iodate during sampling. In order to understand the mechanisms underlying iodine incorporation by calcite, laboratory experiments were carried out to replicate this iodine sequestering processes. Two methods were utilized in this study, 1) addition of sodium carbonate; 2) addition of calcium chloride followed by sodium carbonate where the pH was well controlled at ~8.2, which is close to the average pH of Hanford Site groundwater. It was demonstrated that iodate was the main species incorporated into calcite and this incorporation process could be impeded by elevated pH and decreasing ionic strength in groundwater. This study provides critical information for predicting the long-term fate and transport of 129I at the Hanford Site and reveals a potential means for improved remediation strategies of 129I.

Zhang, Saijin [Texas A and M Univ. at Galveston, TX (United States). Dept. of Marine Science; Xu, Chen [Texas A and M Univ. at Galveston, TX (United States). Dept. of Marine Science; Creeley, Danielle [Texas A and M Univ. at Galveston, TX (United States). Dept. of Marine Science; Ho, Yi-Fang [Texas A and M Univ. at Galveston, TX (United States). Dept. of Marine Science; Li, Hsiu-Ping [Texas A and M Univ. at Galveston, TX (United States). Dept. of Marine Science; Grandbois, Russell [Texas A and M Univ. at Galveston, TX (United States). Dept. of Marine Science; Schwehr, Kathy [Texas A and M Univ. at Galveston, TX (United States). Dept. of Marine Science; Kaplan, Daniel I. [Savannah River National Laboratory, Aiken, SC (United States); Yeager, Chris [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Wellman, Dawn M. [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Santschi, Peter H. [Texas A and M Univ. at Galveston, TX (United States). Dept. of Marine Science

2013-07-25T23:59:59.000Z

32

Response to Comment on “Iodine-129 and Iodine-127 Speciation in Groundwater at Hanford Site, U.S.: Iodate Incorporation into Calcite”  

SciTech Connect (OSTI)

In his comment on our paper “Iodine-129 and Iodine-127 Speciation in Groundwater at Hanford Site, U.S.: Iodate Incorporation into Calcite”, Lu specified three concerns for Zhang et al’s study,1 including (1) precipitation mechanism (degassing vs freezing), (2) analytical methods, and (3) mass balance control. In response, comparative and comprehensive discussions on the precipitation mechanisms and iodine incorporation can be found in the paper, as well as below. This includes additional experiments of iodine distribution and speciation in calcite precipitates. In addition, the measurements of total iodine in soils/sediment were clarified below as well. The calculations on mass balance in this comment were clarified by using correct data sets. Lu proposed that freezing samples

Zhang, Saijin; Xu, Chen; Creeley, Danielle; Ho, Yi-Fang; Li, Hsiu-Ping; Grandbois, Russell; Schwehr, Kathy; Kaplan, D. I.; Yeager, Chris; Wellman, Dawn M.; Santschi, Peter H.

2013-11-04T23:59:59.000Z

33

Iodine Loading of NO Aged Silver Exchanged Mordenite  

SciTech Connect (OSTI)

In an off-gas treatment system for used nuclear fuel processing, a solid sorbent will typically be exposed to a gas stream for months at a time. This gas stream may be at elevated temperature and could contain water vapor, gaseous nitrogen oxides (NO{sub x}), nitric acid vapors, and a variety of other constituents. For this reason, it is important to evaluate the effects of long-term exposure, or aging, on proposed sorbents. Silver exchanged mordenite (AgZ) is being studied at Oak Ridge National Laboratory (ORNL) to determine its iodine sorption capacity after long term exposure to increasingly more complex chemical environments. Studies previously conducted at ORNL investigated the effects of aging reduced silver exchanged mordenite (Ag{sup 0}Z) in dry air, moist air, and NO2. This study investigated the effects of extended exposure to nitric oxide (NO) gas on the iodine capture performance of Ag{sup 0}Z. A deep bed of Ag{sup 0}Z was aged in a 1% nitric oxide (NO) air stream, and portions of the bed were removed at pre-determined intervals. After being removed from the NO stream, each sample was loaded with iodine in a thin bed configuration. These samples were analyzed by neutron activation analysis (NAA) to quantify the iodine content in the sample. Samples were removed at one week and one month. A 78% decrease in sample capacity was seen after one week of exposure, with no further decrease observed after 1 month of aging. The observed loss in capacity is larger in magnitude than previous studies exposing Ag{sup 0}Z to dry air, moist air, or NO2 gas. The aging study was terminated after one month and repeated; this successfully demonstrated the reproducibility of the results.

Patton, K. K. [ORNL; Bruffey, S. H. [ORNL; Jubin, J. T. [ORNL; Walker, Jr., J. F. [ORNL

2014-09-30T23:59:59.000Z

34

Radioactive Iodine and Krypton Control for Nuclear Fuel Reprocessing Facilities  

SciTech Connect (OSTI)

The removal of volatile radionuclides generated during used nuclear fuel reprocessing in the US is almost certain to be necessary for the licensing of a reprocessing facility in the US. Various control technologies have been developed, tested, or used over the past 50 years for control of volatile radionuclide emissions from used fuel reprocessing plants. The US DOE has sponsored, since 2009, an Off-gas Sigma Team to perform research and development focused on the most pressing volatile radionuclide control and immobilization problems. In this paper, we focus on the control requirements and methodologies for 85Kr and 129I. Numerous candidate technologies have been studied and developed at laboratory and pilot-plant scales in an effort to meet the need for high iodine control efficiency and to advance alternatives to cryogenic separations for krypton control. Several of these show promising results. Iodine decontamination factors as high as 105, iodine loading capacities, and other adsorption parameters including adsorption rates have been demonstrated under some conditions for both silver zeolite (AgZ) and Ag-functionalized aerogel. Sorbents, including an engineered form of AgZ and selected metal organic framework materials (MOFs), have been successfully demonstrated to capture Kr and Xe without the need for separations at cryogenic temperatures.

N. R. Soelberg; J. D. Law; T. G. Garn; M. Greenhalgh; R. T. Jubin; P. Thallapally; D. M. Strachan

2013-08-01T23:59:59.000Z

35

Transition of Iodine Analysis to Accelerator Mass Spectrometry  

SciTech Connect (OSTI)

This NA 22 funded research project investigated the transition of iodine isotopic analyses from thermal ionization mass spectrometry (TIMS) to an accelerator mass spectrometry (AMS) system. Previous work (Fiscal Year 2010) had demonstrated comparable data from TIMS and AMS. With AMS providing comparable data with improved background levels and vastly superior sample throughput, improvement in the sample extraction from environmental sample matrices was needed to bring sample preparation throughput closer to the operation level of the instrument. Previous research used an extraction chemistry that was not optimized for yield or refined for reduced labor to prove the principle. This research was done to find an extraction with better yield using less labor per sample to produce a sample ready for the AMS instrument. An extraction method using tetramethyl ammonium hydroxide (TMAH) was developed for removal of iodine species from high volume air filters. The TMAH with gentle heating was superior to the following three extraction methods: ammonium hydroxide aided by sonication, acidic and basic extraction aided by microwave, and ethanol mixed with sodium hydroxide. Taking the iodine from the extraction solvent to being ready for AMS analysis was accomplished by a direct precipitation, as well as, using silver wool to harvest the iodine from the TMAH. Portions of the same filters processed in FY 2010 were processed again with the improved extraction scheme followed by successful analysis by AMS at the Swiss Federal Institute of Technology. The data favorably matched the data obtained in 2010. The time required for analysis has been reduced over the aqueous extraction/AMS approach developed in FY 2010. For a hypothetical batch of 30 samples, the AMS methodology is about 10 times faster than the traditional gas phase chemistry and TIMS analysis. As an additional benefit, background levels for the AMS method are about 1000 times lower than TIMS. This results from the fundamental mechanisms of ionization in the AMS system and which produces a beneficial cleanup of molecular interferences. Continued clean operation of the extraction process was demonstrated through blank analysis included with all sample sets analyzed. INL work showed improvement on the first year’s demonstration of AMS vs. TIMS. An improved extraction of high volume air filters followed by isotopic analysis by AMS, can be used successfully to make iodine measurements with results comparable to those obtained by filter combustion and TIMS analysis. More progress on the conversion from an extract solution to an AMS sample ready for analysis is still needed. Although the preparation scheme through AMS is already at a higher performing thoughput than TIMS, the chemical preparation cannot match the instrument capability for number of samples per day without further development.

M. L. Adamic; J. E. Olson; D. D. Jenson; J. G. Eisenmenger; M. G. Watrous

2012-09-01T23:59:59.000Z

36

Investigation of silver electrodeposition on polycrystalline platinum by iodine chemisorption  

E-Print Network [OSTI]

Qb)ja'A (12) Silver electrodeposition onto the I-pretreated polycrystalline Pt electrode was done using 2 mM AgC104 in 1 M H2SO4. Under these conditions, Ag deposition consists of two underpotential deposition peaks at 0. 65 and 0. 50 V (peaks 1...INVESTIGATION OF SILVER ELECIRODEPOSITION ON POLYCRYSTALLINE PLATINUM BY IODINE CHEMISORPTION A Thesis by JOHN EUGENE HARRIS Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements...

Harris, John Eugene

1988-01-01T23:59:59.000Z

37

Experimental Effects of Atomic Oxygen on the Development of an Electric Discharge Oxygen Iodine Laser  

E-Print Network [OSTI]

state I. Conventionally, a two-phase (gas-liquid) chemistry singlet oxygen generator (SOG) producesExperimental Effects of Atomic Oxygen on the Development of an Electric Discharge Oxygen Iodine of the electric discharge iodine laser continues, the role of oxygen atoms downstream of the discharge region

Carroll, David L.

38

Iodine stabilization of a diode laser in the optical communication band  

E-Print Network [OSTI]

Iodine stabilization of a diode laser in the optical communication band Hsiang-Chen Chui and Sen September 23, 2004 The iodine molecule has frequently been used as a frequency reference from the green provides a simple, compact, and high-performance frequency reference in the optical communication band

Shy,Jow-Tsong

39

Roles of Naturally Occurring Bacteria in Controlling Iodine-129 Mobility in Subsurface Soils  

E-Print Network [OSTI]

Stable iodine 129I Radioactive iodine-129 238U Uranium-238 ABTS 2, 2’-azino-bis-3-ethylbenzothiazoline-6-sulphonic acid ATP Adenosine-5'-triphosphate Br- Bromide Cl- Chloride CoA Coenzyme A DOE Department of Energy DOE-EM Department... 5.5 Discussion ................................................................................ 95 VI SUMMARY ......................................................................................... 100 6.1 Accumulation of I...

Li, Hsiu-Ping

2012-10-19T23:59:59.000Z

40

Soil Iodine Determination in Deccan Syneclise, India: Implications for Near Surface Geochemical Hydrocarbon Prospecting  

SciTech Connect (OSTI)

The association of iodine with organic matter in sedimentary basins is well documented. High iodine concentration in soils overlying oil and gas fields and areas with hydrocarbon microseepage has been observed and used as a geochemical exploratory tool for hydrocarbons in a few studies. In this study, we measure iodine concentration in soil samples collected from parts of Deccan Syneclise in the west central India to investigate its potential application as a geochemical indicator for hydrocarbons. The Deccan Syneclise consists of rifted depositional sites with Gondwana-Mesozoic sediments up to 3.5 km concealed under the Deccan Traps and is considered prospective for hydrocarbons. The concentration of iodine in soil samples is determined using ICP-MS and the values range between 1.1 and 19.3 ppm. High iodine values are characteristic of the northern part of the sampled region. The total organic carbon (TOC) content of the soil samples range between 0.1 and 1.3%. The TOC correlates poorly with the soil iodine (r{sup 2} < 1), indicating a lack of association of iodine with the surficial organic matter and the possibility of interaction between the seeping hydrocarbons and soil iodine. Further, the distribution pattern of iodine compares well with two surface geochemical indicators: the adsorbed light gaseous hydrocarbons (methane through butane) and the propane-oxidizing bacterial populations in the soil. The integration of geochemical observations show the occurrence of elevated values in the northern part of the study area, which is also coincident with the presence of exposed dyke swarms that probably serve as conduits for hydrocarbon microseepage. The corroboration of iodine with existing geological, geophysical, and geochemical data suggests its efficacy as one of the potential tool in surface geochemical exploration of hydrocarbons. Our study supports Deccan Syneclise to be promising in terms of its hydrocarbon prospects.

Mani, Devleena, E-mail: devleenatiwari@ngri.res.in [National Geophysical Research Institute (Council of Scientific and Industrial Research) (India); Kumar, T. Satish [Oil India Limited (India); Rasheed, M. A.; Patil, D. J.; Dayal, A. M.; Rao, T. Gnaneshwar; Balaram, V. [National Geophysical Research Institute (Council of Scientific and Industrial Research) (India)

2011-03-15T23:59:59.000Z

Note: This page contains sample records for the topic "iodine phos phorus" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Determination of Iodine-129 in Low Level Radioactive Wastes - 13334  

SciTech Connect (OSTI)

For the radioactivity determination of {sup 129}I in the radioactive wastes, alkali fusion and anion-exchange resin separation methods, which are sample pretreatment methods, have been investigated in this study. To separate and quantify the {sup 129}I radionuclide in an evaporator bottom and spent resin, the radionuclide was chemically leached from the wastes and adsorbed on an anion exchange resin at pH 4, 7, 9. In the case of dry active waste and another solid type, the alkali fusion method was applied. KNO{sub 3} was added as a KOH and oxidizer to the wastes. It was then fused at 450 deg. C for 1 hour. The radioactivity of the separated iodine was measured with a low energy gamma spectrometer after the sample pretreatment. Finally, it was confirmed that the recovery rate of the iodine for the alkali fusion method was 83.6±3.8%, and 86.4±1.6% for the anionic exchange separation method. (authors)

Choi, K.C.; Ahn, J.H.; Park, Y.J.; Song, K.S. [Nuclear Chemistry Research Division, Korea Atomic Energy Research Institute, Daejeon, 305-600 (Korea, Republic of)] [Nuclear Chemistry Research Division, Korea Atomic Energy Research Institute, Daejeon, 305-600 (Korea, Republic of)

2013-07-01T23:59:59.000Z

42

Iodine Adsorption on Ion-Exchange Resins and Activated Carbons– Batch Testing  

SciTech Connect (OSTI)

Iodine sorption onto seven resins and six carbon materials was evaluated using water from well 299-W19-36 on the Hanford Site. These materials were tested using a range of solution-to-solid ratios. The test results are as follows: • The efficacy of the resin and granular activated carbon materials was less than predicted based on manufacturers’ performance data. It is hypothesized that this is due to the differences in speciation previously determined for Hanford groundwater. • The sorption of iodine is affected by the iodine species in the source water. Iodine loading on resins using source water ranged from 1.47 to 1.70 µg/g with the corresponding Kd values from 189.9 to 227.0 mL/g. The sorption values when the iodine is converted to iodide ranged from 2.75 to 5.90 µg/g with the corresponding Kd values from 536.3 to 2979.6 mL/g. It is recommended that methods to convert iodine to iodide be investigated in fiscal year (FY) 2015. • The chemicals used to convert iodine to iodate adversely affected the sorption of iodine onto the carbon materials. Using as-received source water, loading and Kd values ranged from 1.47 to 1.70 µg/g and 189.8 to 226.3 mL/g respectively. After treatment, loading and Kd values could not be calculated because there was little change between the initial and final iodine concentration. It is recommended the cause of the decrease in iodine sorption be investigated in FY15. • In direct support of CH2M HILL Plateau Remediation Company, Pacific Northwest National Laboratory has evaluated samples from within the 200W pump and treat bioreactors. As part of this analysis, pictures taken within the bioreactor reveal a precipitate that, based on physical properties and known aqueous chemistry, is hypothesized to be iron pyrite or chalcopyrite, which could affect iodine adsorption. It is recommended these materials be tested at different solution-to-solid ratios in FY15 to determine their effect on iodine sorption.

Parker, Kent E.; Golovich, Elizabeth C.; Wellman, Dawn M.

2014-09-30T23:59:59.000Z

43

Systematic study of iodine nuclei in A?125 mass region  

SciTech Connect (OSTI)

Excited states of {sup 127}I were populated via {sup 124}Sn({sup 7}Li,{sup 4}n?){sup 127}I fusion-evaporation reaction at beam energy of 33 MeV. Multipolarities of several transitions were determined and spins of corresponding states have been confirmed. The band-head spin and parity of an already reported band at 2901.2 keV has been confirmed. Based on the observed characteristic features and by comparing with the systematics of odd mass iodine nuclei, a ?g{sub 7/2}??h{sub 11/2}{sup 2} configuration has been proposed for this band. The experimental B(M1)/B(E2) values for ?g{sub 7/2} band were compared with the theoretical results of semi classical model of Frauendorf and Donau and found in well agreement.

Sharma, H. P.; Chakraborty, S.; Kumar, A. [Department of Physics, Banaras Hindu University, Varanasi-221005 (India); Banerjee, P. [Division of Nuclear Physics, Saha Institute of Nuclear Physics, Kolkata-700064 (India); Ganguly, S. [Department of Physics, Chandernagore College, Chandannagar-721136 (India); Muralithar, S.; Singh, R. P. [Inter University Accelerator Center, New Delhi-110067 (India); Kumar, A.; Kaur, N. [Department of Physics, Punjab University, Chandigarh-160014 (India); Kumar, S. [Department of Physics and Astrophysics, University of Delhi, New Delhi-110067 (India); Chaturvedi, L. [Department of Pure and Applied Physics, Guru Ghasidas Vishwavidyalaya, Bilaspur-495009 (India); Jain, A. K. [Department of Physics, Indian Institute of Technology, Roorkee-247667 (India); Laxminarayan, S. [Department of Physics, Andhra University, Visakhapatnam-530003 (India)

2014-08-14T23:59:59.000Z

44

ALTERNATIVE FLOWSHEETS FOR THE SULFUR-IODINE THERMOCHEMICAL HYDROGEN CYCLE  

SciTech Connect (OSTI)

OAK-B135 A hydrogen economy will need significant new sources of hydrogen. Unless large-scale carbon sequestration can be economically implemented, use of hydrogen reduces greenhouse gases only if the hydrogen is produced with non-fossil energy sources. Nuclear energy is one of the limited options available. One of the promising approaches to produce large quantities of hydrogen from nuclear energy efficiently is the Sulfur-Iodine (S-I) thermochemical water-splitting cycle, driven by high temperature heat from a helium Gas-Cooled Reactor. They have completed a study of nuclear-driven thermochemical water-splitting processes. The final task of this study was the development of a flowsheet for a prototype S-I production plant. An important element of this effort was the evaluation of alternative flowsheets and selection of the reference design.

BROWN,LC; LENTSCH,RD; BESENBRUCH,GE; SCHULTZ,KR; FUNK,JE

2003-02-01T23:59:59.000Z

45

Sulfur-Iodine Integrated Lab Scale Experiment Development  

SciTech Connect (OSTI)

The sulfur-iodine (SI) cycle was deermined to be the best cycle for coupling to a high temperature reactor (HTR) because of its high efficiency and potential for further improvement. The Japanese Atomic Energy Agency (JAEA) has also selected the SI process for further development and has successfully completed bench-scale demonstrations of the SI process at atmospheric pressure. JEA also plans to proceed with pilot-scale demonstrations of the SI process and eventually plans to couple an SI demonstration plant to its High Temperature Test Reactor (HHTR). As part of an international NERI project, GA, SNL, and the Frech Commissariat L'Energie Atomique performed laboratory-scale demonstrations of the SI process at prototypical temperatures and pressures. This demonstration was performed at GA in San Diego, CA and concluded in April 2009.

Russ, Ben

2011-05-27T23:59:59.000Z

46

Doping efficiency of single and randomly stacked bilayer graphene by iodine adsorption  

SciTech Connect (OSTI)

We report on the efficiency and thermal stability of p-doping by iodine on single and randomly stacked, weakly coupled bilayer polycrystalline graphene, as directly measured by photoelectron emission microscopy. The doping results in work function value increase of 0.4–0.5?eV, with a higher degree of iodine uptake by the bilayer (2%) as compared to the single layer (1%) suggesting iodine intercalation in the bilayer. The chemistry of iodine is identified accordingly as I{sub 3}{sup ?} and I{sub 5}{sup ?} poly iodide anionic complexes with slightly higher concentration of I{sub 5}{sup ?} in bilayer than monolayer graphene, likely attributed to differences in doping mechanisms. Temperature dependent in-situ annealing of the doped films demonstrated that the doping remains efficient up to 200?°C.

Kim, HoKwon; Renault, Olivier; Rouchon, Denis; Mariolle, Denis; Chevalier, Nicolas [Univ. Grenoble Alpes, F-38000 Grenoble, France and CEA, LETI, MINATEC Campus, F-38054 Grenoble (France); Tyurnina, Anastasia; Simonato, Jean-Pierre; Dijon, Jean [Univ. Grenoble Alpes, F-38000 Grenoble, France and CEA, LITEN, Minatec Campus, F-38054 Grenoble (France)

2014-07-07T23:59:59.000Z

47

Contrast-Medium-Enhanced Digital Mammography: Contrast vs. Iodine Concentration Phantom Calibration  

SciTech Connect (OSTI)

This work deals with the application of the contrast-medium-enhanced digital subtraction mammography technique in order to calibrate the contrast level in subtracted phantom images as function of iodine concentration to perform dynamic studies of the contrast-medium uptake in the breast. Previously optimized dual-energy temporal subtraction modalities were used (a) to determine radiological parameters for a dynamic clinical study composed of 1 mask+3 post-contrast images limiting the total mean glandular dose to 2.5 mGy, and (b) to perform a contrast vs iodine concentration calibration using a custom-made phantom. Calculated exposure values were applied using a commercial full-field digital mammography unit. Contrast in subtracted phantom images (one mask and one post-CM) is linear as function of iodine concentration, although the sensitivity (contrast per iodine concentration) decreases beyond 8 mg/mL. This calibration seems to apply only to thin and normal thickness breasts.

Rosado-Mendez, I.; Brandan, M. E. [Instituto de Fisica, Universidad Nacional Autonoma de Mexico, 04510 DF (Mexico); Villasenor, Y. [Instituto Nacional de Cancerologia (INCan), Av. San Fernando 22, Tlalpan 14080 DF (Mexico); Benitez-Bribiesca, L. [Centro Medico Nacional Siglo XXI, Av. Cuauhtemoc 330, Col. Doctores 06725 DF (Mexico)

2008-08-11T23:59:59.000Z

48

Sorption and transport of iodine species in sediments from the Savannah River and Hanford Sites  

E-Print Network [OSTI]

Sorption and transport of iodine species in sediments from the Savannah River and Hanford Sites-iodoaniline) in sediments collected at the Savannah River and Hanford Sites, where anthropogenic 129 I from

Hu, Qinhong "Max"

49

Development of Efficient Flowsheet and Transient Modeling for Nuclear Heat Coupled Sulfur Iodine Cyclefor Hydrogen Production  

SciTech Connect (OSTI)

The realization of the hydrogen as an energy carrier for future power sources relies on a practical method of producing hydrogen in large scale with no emission of green house gases. Hydrogen is an energy carrier which can be produced by a thermochemical water splitting process. The Sulfur-Iodine (SI) process is an example of a water splitting method using iodine and sulfur as recycling agents.

Shripad T. Revankar; Nicholas R. Brown; Cheikhou Kane; Seungmin Oh

2010-05-01T23:59:59.000Z

50

NO2 Aging and Iodine Loading of Silver-Functionalized Aerogels  

SciTech Connect (OSTI)

Off-gas treatment systems in used fuel reprocessing which use fixed-bed adsorbers are typically designed to operate for an extended period of time before replacement or regeneration of the adsorbent. During this time, the sorbent material will be exposed to the off-gas stream. Exposure could last for months, depending on the replacement cycle time. The gas stream will be at elevated temperature and will possibly contain a mixture of water vapor, NOx, nitric acid vapors, and a variety of other constituents in addition to the radionuclides of capture interest. A series of studies were undertaken to evaluate the effects of long-term exposure, or aging, on proposed iodine sorbent materials under increasingly harsh off-gas conditions. Previous studies have evaluated the effects of up to 6 months of aging under dry air and under humid air conditions on the iodine loading behavior of Ag0-functionalized aerogels. This study examines the effects of extended exposure (up to 6 months) to NO2 on the iodine loading capacity of Ag0- functionalized aerogels. Material aged for 1 and 2 months appeared to have a similar total loading capacity to fresh material. Over an aging period of 4 months, a loss of approximately 15% of the total iodine capacity was seen. The iodine capacity loss on silver-functionalized aerogels due to NO2 was smaller than the iodine capacity loss due to humid or dry air aging.

Patton, K K [ORNL; Bruffey, S H [ORNL; Walker, J F [ORNL; Jubin, R T [ORNL

2014-07-31T23:59:59.000Z

51

Nuclear Hydrogen Initiative, Results of the Phase II Testing of Sulfur-Iodine Integrated Lab Scale Experiments  

SciTech Connect (OSTI)

International collaborative effort to construct a laboratory-scale Sulfur-Iodine process capable of producing 100-200 L/hr of hydrogen.

Benjamin Russ; G. Naranjo; R. Moore; W. Sweet; M. Hele; N. Pons

2009-10-30T23:59:59.000Z

52

Iodine-129 separation and determination by neutron activation analysis  

SciTech Connect (OSTI)

A method is described for analysis of /sup 129/I in fission product mixtures originating from fuel reprocessing studies and low-level wastes. The method utilizes conventional iodine valence adjustment and solvent extraction techniques to chemically separate /sup 129/I from most fission products. The /sup 129/I is determined by neutron irradiation and measurement of the 12.4 h /sup 130/I produced by the neutron capture reaction. Special techniques were devised for neutron irradiation of /sup 129/I samples in the pneumatic tube irradiation facilities at the High Flux Isotope (HFIR) and Oak Ridge Research (ORR) Reactors. Chemically separated /sup 129/I is adsorbed on an anion exchange resin column made from an irradiation container. The loaded resin is then irradiated in either of the pneumatic facilities to produce /sup 130/I. Sensitivity of the analysis with the HFIR facility (flux: 5 x 10/sup 14/ n/cm/sup 2//sec) and a 100-second irradiation time is approximately 0.03 nanograms. Samples up to 250 ml in volume can be easily processed.

Bate, L.C.; Stokely, J.R.

1981-01-01T23:59:59.000Z

53

FUNCTIONALIZED SILICA AEROGELS: ADVANCED MATERIALS TO CAPTURE AND IMMOBILIZE RADIOACTIVE IODINE  

SciTech Connect (OSTI)

To support the future expansion of nuclear energy, an effective method is needed to capture and safely store radiological iodine-129 released during reprocessing of spent nuclear fuel. Various materials have been investigated to capture and immobilize iodine. In most cases, however, the materials that are effective for capturing iodine cannot subsequently be sintered/densified to create a stable composite that could be a viable waste form. We have developed chemically modified, highly porous, silica aerogels that show sorption capacities higher than 440 mg of I2 per gram at 150 C. An iodine uptake test in dry air containing 4.2 ppm of iodine demonstrated no breakthrough after 3.5 h and indicated a decontamination factor in excess of 310. Preliminary densification tests showed that the I2-loaded aerogels retained more than 92 wt% of I2 after thermal sintering with pressure assistance at 1200 C for 30 min. These high capture and retention efficiencies for I2 can be further improved by optimizing the functionalization process and the chemistry as well as the sintering conditions.

Matyas, Josef; Fryxell, Glen E.; Busche, Brad J.; Wallace, Krys; Fifield, Leonard S.

2011-11-16T23:59:59.000Z

54

Purex Plant gaseous iodine-129 control capability and process development requirements  

SciTech Connect (OSTI)

This report describes the ability of the Purex Plant to effectively control iodine-129 emissions. Based on historical evidence, the current Purex Plant iodine control system appears capable of meeting the goal of limiting gaseous iodine-129 emissions at the point of discharge to levels stipulated by the Department of Energy (DOE) for an uncontrolled area. Expected decontamination factors (DF`s) with the current system will average about 100 and will be above the calculated DF`s of 2.2 and 87 required to meet DOE yearly average concentration limits for controlled and uncontrolled areas respectively, but below the calculated DF of 352 required for meeting the proposed Environmental Protection Agency (EPA) mass emission limit. Chemical costs for maintaining compliance with the DOE limits will be approximately $166 per metric ton of fuel processed (based on a silver nitrate price of $12.38/oz). Costs will increase in proportion to increases in silver prices.

Evoniuk, C.J.

1981-01-01T23:59:59.000Z

55

Comparative EPMA and -XRF methods for mapping micro-scale distribution of iodine in biocarbonates of the CallovianOxfordian  

E-Print Network [OSTI]

Comparative EPMA and -XRF methods for mapping micro-scale distribution of iodine in biocarbonates spectrometry (IR), electron microprobe (EPMA), spatially resolved synchrotron-based X-ray fluorescence (-XRF recrystallized into diagenetic calcite and celestite. EPMA and -XRF data show bioaccumulation of iodine

Paris-Sud XI, Université de

56

Project EARTH-11-RR2: Co-evolution of iodine antioxidant mechanism in marine algae and Earth-surface  

E-Print Network [OSTI]

Project EARTH-11-RR2: Co-evolution of iodine antioxidant mechanism in marine algae and Earth algae (yet they are lacking in green algae) ­ but the phylogenetic distribution of iodine accumulation haloperoxidases. The first appearance and important divergence of brown algae occurred within the last 200 myr

Henderson, Gideon

57

Wafer Preparation and Iodine-Ethanol-Ethanol Passivation Procedure for Reproducible Minority-Carrier Lifetime Measurement: Preprint  

SciTech Connect (OSTI)

This paper describes reasons that lifetime measurments may be irreproducible using iodine-in-ethanol (I-E) passivation. Possible factors include the strength of the iodine in ethanol solution, wafer cleaning procedures, influence of wafer container during lifetime measurement, and stability of I-E.

Sopori, B.; Rupnowski, P.; Appel, J.; Mehta, V.; Li, C.; Johnston, S.

2008-05-01T23:59:59.000Z

58

Extraction and Quantitative Analysis of Iodine in Solid and Solution Matrixes  

SciTech Connect (OSTI)

129I is a contaminant of interest in the vadose zone and groundwater at numerous federal and privately-owned facilities. Several techniques have been utilized to extract iodine from solid matrices; however, all of them rely on two fundamental approaches: liquid extraction or chemical/heat facilitated volatilization. While these methods are typically chosen for their ease of implementation, they do not totally dissolve the solid. Because some of the iodine partitions onto the soil, extraction methods that do not result in total sample dissolution could underestimate the total iodine content of solid samples. We defined a method that produces complete solid dissolution and conducted laboratory tests to assess its efficacy to completely extract iodine from solid matrices. Testing consisted of potassium nitrate/potassium hydroxide fusion of the sample, followed by sample dissolution in a mixture of sulfuric acid and sodium bisulfite. Direct analysis of the dissolved sample was performed via inductively coupled plasma mass spectrometry (Perkin Elmer Elan DRC II) using a tertiary amine (Spectrasol CFA-C) carrier solution. The fusion extraction method resulted in complete sample dissolution of all solid matrices tested: sediment, glass samples containing low-levels of iodine, as well as tank waste material collected from the Hanford Site. Quantitative analysis of iodine (127I and 129I) showed better than ? 10% accuracy for certified reference standards, with the linear operating range extending more than three orders of magnitude (0.005 to 5 ug/L). Extraction and analysis of four replicates of standard reference material (San Joaquin Soil) from the National Institute of Standards and Technology, Gaithersburg, MD, resulted in an average recovery of 98% with a relative percent deviation of 6%. This simple and cost-effective technique can be applied to solid samples of varying matrices with little or no adaptation.

Brown, Christopher F.; Geiszler, Keith N.; Vickerman, Tanya S.

2005-11-01T23:59:59.000Z

59

An evaluation of radio-iodinated human serum albumin in the dog  

E-Print Network [OSTI]

iodinated (131I) human serum albumin. I. Animal studies. Circulation. 4: 552-556, 1951. 19. McFarlane, W. S. Efficient trace-labeling of proteins with iodine. Nature, 182: 53, 1958. 20. Prinzmetal, M. , E. Corday, R. J. Spritzler, and W. Flieg.... Nature. 190: 1211-1212, 1961. Seely, R. D. , W. E. Nerlich, and D. E. Gregg. A comparison of cardiac output determined by the Fick procedure and a direct method using the rotameter? Circulation. 1: 1261-1266, 1950. 25. Shipley, R. A. , R. E. Clark, D...

Hood, David Martin

1973-01-01T23:59:59.000Z

60

Technetium and Iodine Getters to Improve Cast Stone Performance  

SciTech Connect (OSTI)

To determine the effectiveness of the various getter materials prior to their solidification in Cast Stone, a series of batch sorption experiments was performed at Pacific Northwest National Laboratory. To quantify the effectiveness of the removal of Tc(VII) and I(I) from solution by getters, the distribution coefficient, Kd (mL/g), was calculated. Testing involved placing getter material in contact with spiked waste solutions at a 1:100 solid-to-solution ratio for periods up to 45 days with periodic solution sampling. One Tc getter was also tested at a 1:10 solid-to-solution ratio. Two different solution media, 18.2 M? deionized water (DI H2O) and a 7.8 M Na LAW simulant, were used in the batch sorption tests. Each test was conducted at room temperature in an anoxic chamber containing N2 with a small amount of H2 (0.7%) to maintain anoxic conditions. Each getter-solution combination was run in duplicate. Three Tc- and I-doping concentrations were used separately in aliquots of both the 18.2 M? DI H2O and a 7.8 M Na LAW waste simulant. The 1× concentration was developed based on Hanford Tank Waste Operations Simulator (HTWOS) model runs to support the River Protection Project System Plan Revision 6. The other two concentrations were 5× and 10× of the HTWOS values. The Tc and I tests were run separately (i.e., the solutions did not contain both solutes). Sampling of the solid-solution mixtures occurred nominally after 0.2, 1, 3, 6, 9, 12, 15 days and ~35 to 45 days. Seven getter materials were tested for Tc and five materials were tested for I. The seven Tc getters were blast furnace slag 1 (BFS1) (northwest source), BFS2 (southeast source), Sn(II)-treated apatite, Sn(II) chloride, nano tin phosphate, KMS (a potassium-metal-sulfide), and tin hydroxapatite. The five iodine getters were layered bismuth hydroxide (LBH), argentite mineral, synthetic argentite, silver-treated carbon, and silver-treated zeolite. The Tc Kd values measured from experiments conducted using the 7.8 M Na LAW simulant (the simulant selected to represent LAW) for the first 15 days for four Tc getters (BFS1, BFS2, Sn(II)-treated apatite, and Sn(II) chloride) show no, to a very small, capacity to remove Tc from the LAW simulant. For the Tc-getter experiments in the 7.8 M LAW simulant, the majority of the effluent samples show very small drops in Tc concentrations for the 35-day compared to the 15-day samplings. However, the Tc concentration in the simulant blanks also dropped slightly during this period, so the effect of the getter contacting LAW simulant at 35 days compared to 15 days is minimal; except that the BFS1 1:10 test shows a slow but steady decrease in Tc concentration in the LAW simulant supernatant from the beginning to the 35 day contact at which point about 20% of the original Tc has been removed from solution. Lastly, the KMS getter gives the highest Kd value for Tc at 35 days where Kd values have increased to 104 mL/g. When considering the different I getters reacting with the 7.8 M LAW simulant, two getters are much more effective than the others: Ag zeolite and Syn Arg. The other getters have calculated iodide distribution coefficients that show very limited effectiveness in the caustic conditions created by the LAW simulant. These are preliminary results that will need more detailed analyses including both pre- and post-batch sorption getter solid-phase characterization using state-of-the-art instrumentation such as synchrotron X ray absorption spectroscopy, which can delineate the oxidation state of the Tc and likely iodine species as well as some of the getters key major components, sulfur and iron in the BFS, and tin and sulfur in the tin-bearing and sulfur-bearing getters. This report also describes future experimental studies to be performed to better elucidate the mechanisms controlling the Tc and I sequestration processes in the various getters and leach tests of getter-bearing Cast Stone monoliths.

Qafoku, Nikolla; Neeway, James J.; Lawter, Amanda R.; Levitskaia, Tatiana G.; Serne, R. Jeffrey; Westsik, Joseph H.; Snyder, Michelle MV

2014-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "iodine phos phorus" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Demonstration of an iodine laser pumped by an air-helium electric discharge  

E-Print Network [OSTI]

issues with this chemical singlet oxygen generator (SOG) motivated many investigations-He-NO gas mixture. Active oxygen and nitrogen species were observed downstream of the discharge regionW in a supersonic flow cavity. Keywords: electric oxygen iodine laser, electric discharge, singlet oxygen, active

Carroll, David L.

62

Deficiencies of sodium and iodine in grazing sheep in northern China  

E-Print Network [OSTI]

Deficiencies of sodium and iodine in grazing sheep in northern China DG Masters JR Lindsay SX Yu DX of Traditional Veterinary Medicine, Chinese Academy of Agricultural Science, Xiaoxihu, Lanzhou, Gansu, China An examination of the mineral status of grazing sheep at 3 sites in northern China has provided evidence

Paris-Sud XI, Université de

63

Singlet oxygen generation using iodinated squaraine and squaraine-rotaxane dyesw  

E-Print Network [OSTI]

Singlet oxygen generation using iodinated squaraine and squaraine-rotaxane dyesw Easwaran Arunkumar-rotaxanes to generate singlet oxygen for potential application in photodynamic therapy (PDT). Specifically, we compare-to-face orientations in the solid state. Singlet oxygen generation efficiency was measured by trapping with 1

Smith, Bradley D.

64

8 March 2010 Role of dietary iodine and cruciferous vegetables in thyroid cancer  

E-Print Network [OSTI]

8 March 2010 1 Role of dietary iodine and cruciferous vegetables in thyroid cancer: A countrywide Rougier, MD4 Pascal Guénel, MD, PhD1,2 Author affiliations 1 Environmental Epidemiology of Cancer, CESP: Pascal Guénel, MD, PhD Environmental Epidemiology of Cancer UMRS 1018, Inserm CESP 16 avenue Paul

Paris-Sud XI, Université de

65

Deciphering the measured ratios of Iodine-131 to Cesium-137 at the Fukushima reactors  

E-Print Network [OSTI]

We calculate the relative abundance of the radioactive isotopes Iodine-131 and Cesium-137 produced by nuclear fission in reactors and compare it with data taken at the troubled Fukushima Dai-ichi nuclear power plant. The ratio of radioactivities of these two isotopes can be used to obtain information about when the nuclear reactions terminated.

T. Matsui

2011-12-13T23:59:59.000Z

66

Features of adsorbed radioactive chemical elements and their isotopes distribution in iodine air filters AU-1500 at nuclear power plants  

E-Print Network [OSTI]

The main aim of research is to investigate the physical features of spatial distribution of the adsorbed radioactive chemical elements and their isotopes in the granular filtering medium in the iodine air filters of the type of AU1500 in the forced exhaust ventilation systems at the nuclear power plant. The gamma activation analysis method is applied to accurately characterize the distribution of the adsorbed radioactive chemical elements and their isotopes in the granular filtering medium in the AU1500 iodine air filter after its long term operation at the nuclear power plant. The typical spectrum of the detected chemical elements and their isotopes in the AU1500 iodine air filter, which was exposed to the bremsstrahlung gamma quantum irradiation, produced by the accelerating electrons in the tantalum target, are obtained. The spatial distributions of the detected chemical element 127I and some other chemical elements and their isotopes in the layer of absorber, which was made of the cylindrical coal granules of the type of SKT3, in the AU1500 iodine air filter are also researched. The possible influences by the standing acoustic wave of air pressure in the iodine air filter on the spatial distribution of the chemical elements and their isotopes in the iodine air filter are discussed. The comprehensive analysis of obtained research results on the distribution of the adsorbed chemical elements and their isotopes in the absorber of iodine air filter is performed.

I. M. Neklyudov; A. N. Dovbnya; N. P. Dikiy; O. P. Ledenyov; Yu. V. Lyashko

2013-06-21T23:59:59.000Z

67

Determination of iodine in organic compounds using low-temperature ammoniacal plasma of high-frequency discharge  

SciTech Connect (OSTI)

This paper presents a method for the determination of iodine in organic compounds, based on the use of a low-temperature ammonial plasma of an electrodeless high frequency discharge. The method was tested on a large number of compounds, and is distinguished by simplicity of operation, rapidity, accuracy and applicability for simultaneous determination of iodine and palladium. The results of the simultaneous determination of iodine and palladium in organic compounds are shown. The relative standard deviation does not exceed 0.011. The duration of each determination is 15-20 min.

Volodina, M.A.; Kutseva, N.K.

1986-09-01T23:59:59.000Z

68

The development of autocatalytic structural materials for use in the sulfur-iodine process for the production of hydrogen  

E-Print Network [OSTI]

The Sulfur-Iodine Cycle for the thermochemical production of hydrogen offers many benefits to traditional methods of hydrogen production. As opposed to steam methane reforming - the most prevalent method of hydrogen ...

Miu, Kevin (Kevin K.)

2006-01-01T23:59:59.000Z

69

Expanded Analysis of Hot Isostatic Pressed Iodine-Loaded Silver-Exchanged Mordenite  

SciTech Connect (OSTI)

Reduced silver-exchanged mordenite (Ag0Z) is being evaluated as a potential material to control the release of radioactive iodine that is released during the reprocessing of used nuclear fuel into the plant off-gas streams. The purpose of this study was to determine if hot pressing could directly convert this iodine loaded sorbent into a waste form suitable for long-term disposition. The minimal pretreatment required for production of pressed pellets makes hot pressing a technically and economically desirable process. Initial scoping studies utilized hot uniaxial pressing (HUPing) to prepare samples of non-iodine-loaded reduced silver exchanged mordenite (Ag0Z). The resulting samples were very fragile due to the low pressure (~ 28 MPa) used. It was recommended that hot isostatic pressing (HIPing), performed at higher temperatures and pressures, be investigated. HIPing was carried out in two phases, with a third and final phase currently underway. Phase I evaluated the effects of pressure and temperature conditions on the manufacture of a pressed sample. The base material was an engineered form of silver zeolite. Six samples of Ag0Z and two samples of I-Ag0Z were pressed. It was found that HIPing produced a pressed pellet of high density. Analysis of each pressed pellet by scanning electron microscopy-energy dispersive spectrophotometry (SEM-EDS) and X-ray diffraction (XRD) demonstrated that under the conditions used for pressing, the majority of the material transforms into an amorphous structure. The only crystalline phase observed in the pressed Ag0Z material was SiO2. For the samples loaded with iodine (I-Ag0Z) iodine was present as AgI clusters at low temperatures, and transformed into AgIO4 at high temperatures. Surface mapping and EDS demonstrate segregation between silver iodide phases and silicon dioxide phases. Based on the results of the Phase I study, an expanded test matrix was developed to examine the effects of multiple source materials, compositional variations, and an expanded temperature range. Each sample was analyzed with the approach used in Phase I. In all cases, there is nothing in the SEM or XRD analyses that indicates creation of any AgI-containing silicon phase, with the samples being found to be largely amorphous. Phase III of this study has been initiated and is the final phase of scoping tests. It will expand upon the test matrix completed in Phase II and will examine the durability of the pressed pellets through product consistency testing (PCT) studies. Transformation of the component material into a well-characterized iodine-containing mineral phase would be desirable. This would limit the additional experimental testing and modeling required to determine the long-term stability of the pressed pellet, as much of that information has already been learned for several common iodine-containing minerals. However, this is not an absolute requirement, especially if pellets produced by hot isostatic pressing can be demonstrated through initial PCT studies to retain iodine well despite their amorphous composition.

Jubin, R. T. [ORNL; Bruffey, S. H. [ORNL; Patton, K. K. [ORNL

2014-09-30T23:59:59.000Z

70

Laboratory studies on the evolution of iodine-129 during Purex-uranium metal dissolution  

SciTech Connect (OSTI)

The path of iodine from the Purex dissolver was determined during fuel dissolution using /sup 125/I tracer. Laboratory-scale equipment qualification studies were completed using sections of nonirradiated uranium N-reactor fuel elements. A proof-of-principle dissolution study was completed at the end of FY 1979 in the PNL hot cells using wafers of irradiated N-reactor fuel. The findings include the following: the laboratory-scale dissolver/downdraft condenser was designed at a factor of 5 x 10/sup -5/ of the Purex flowsheet; with no refluxing, 5.6 moles of HNO/sub 3/ were required per mole of dissolved uranium. With NO/sub x/ recovery in the reflux stream, an average of 3.6 moles of HNO/sub 3/ was required. These results formed the basis for adequate modeling of the laboratory Purex downdraft dissolver; approximately 8% of the iodine was found in the final dissolver solution when the /sup 125/I tracer was added to the initial dissolver solution prior to the first cut, 6-h dissolution; when the /sup 125/I was added continuously during the 6-h dissolution without any refluxing of the condenser acid back to the dissolver, approximately 16% of the iodine was found in the dissolver solution; when irradiated N-reactor fuel was dissolved while /sup 125/I tracer was continuously added to the dissolver during the 6-h test, 11% of the /sup 125/I tracer was found in the dissolver solution. After 2 h of refluxing with air sparging, 6% of the /sup 125/I tracer was found in the dissolver solution; and analysis of the fission product /sup 129/I in the fuel duplicated the tracer study results with 8% and 7% of the iodine remaining in the dissolver solution after 6 and 8 h, respectively.

Bray, L.A.

1980-03-01T23:59:59.000Z

71

Sulfur Iodine Process Summary for the Hydrogen Technology Down-Selection  

SciTech Connect (OSTI)

This report summarizes the sulfur-iodine (SI) thermochemical water splitting process for the purpose of supporting the process for evaluating and recommending a hydrogen production technology to deploy with the Next Generation Nuclear Plant (NGNP). This package provides the baseline process description as well as a comparison with the process as it was implemented in the Integrated Lab Scale (ILS) experiment conducted at General Atomics from 2006-2009.

Benjamin Russ

2009-05-01T23:59:59.000Z

72

Atmospheric dispersion and deposition of iodine-131 released from the Hanford Site  

SciTech Connect (OSTI)

Approximately 2.6x10{sup 4} TBq (700,000 curies) of iodine-131 were released to the air from reactor fuel processing plants on the Hanford Site in southcentral Washington State from December 1944 through December 1949. The Hanford Environmental Dose Reconstruction (HEDR) Project developed a suite of codes to estimate the doses that might have resulted from these releases. The Regional Atmospheric Transport Code for Hanford Emission Tracking (RATCHET) computer code is part of this suite. The RATCHET code implements a Lagrangian-trajectory, Gaussian-puff dispersion model that uses hourly meteorological and release rate data to estimate daily time-integrated air concentrations and surface contamination for use in dose estimates. In this model, iodine is treated as a mixture of three species (nominally, inorganic gases, organic gases, and particles). Model deposition parameters are functions of the mixture and meteorological conditions. A resistance model is used to calculate dry deposition velocities. Equilibrium between concentrations in the precipitation and the air near the ground is assumed in calculating wet deposition of gases, and irreversible washout of the particles is assumed. RATCHET explicitly treats the uncertainties in model parameters and meteorological conditions. Uncertainties in iodine-131 release rates and partitioning among the nominal species are treated by varying model input. The results of 100 model runs for December 1944 through December 1949 indicate that monthly average air concentrations and deposition have uncertainties ranging from a factor of two near the center of the time-integrated plume to more than an order of magnitude near the edge. These results indicate that -10% of the iodine-131 released to the atmosphere decayed during transit in the study area, -56% was deposited within the study area, and the remaining 34% was transported out of the study area while still in the air.

Ramsdell, J.V.; Simonen, C.A.; Burk, K.W.; Stage, S.A.

1994-06-01T23:59:59.000Z

73

Physical features of accumulation and distribution processes of small disperse coal dust precipitations and absorbed radioactive chemical elements in iodine air filter at nuclear power plant  

E-Print Network [OSTI]

The physical features of absorption process of radioactive chemical elements and their isotopes in the iodine air filters of the type of AU-1500 at the nuclear power plants are researched. It is shown that the non-homogenous spatial distribution of absorbed radioactive chemical elements and their isotopes in the iodine air filter, probed by the gamma-activation analysis method, is well correlated with the spatial distribution of small disperse coal dust precipitations in the iodine air filter. This circumstance points out to an important role by the small disperse coal dust fractions of absorber in the absorption process of radioactive chemical elements and their isotopes in the iodine air filter. The physical origins of characteristic interaction between the radioactive chemical elements and the accumulated small disperse coal dust precipitations in an iodine air filter are considered. The analysis of influence by the researched physical processes on the technical characteristics and functionality of iodine ...

Ledenyov, Oleg P; Poltinin, P Ya; Fedorova, L I

2012-01-01T23:59:59.000Z

74

Determine Minimum Silver Flake Addition to GCM for Iodine Loaded AgZ  

SciTech Connect (OSTI)

The minimum amount of silver flake required to prevent loss of I{sub 2} during sintering in air for a SNL Glass Composite Material (GCM) Waste Form containing AgI-MOR (ORNL, 8.7 wt%) was determined to be 1.1 wt% Ag. The final GCM composition prior to sintering was 20 wt% AgI-MOR, 1.1 wt% Ag, and 80 wt% Bi-Si oxide glass. The amount of silver flake needed to suppress iodine loss was determined using thermo gravimetric analysis with mass spectroscopic off-gas analysis. These studies found that the ratio of silver to AgI-MOR required is lower in the presence of the glass than without it. Therefore an additional benefit of the GCM is that it serves to inhibit some iodine loss during processing. Alternatively, heating the AgI-MOR in inert atmosphere instead of air allowed for densified GCM formation without I{sub 2} loss, and no necessity for the addition of Ag. The cause of this behavior is found to be related to the oxidation of the metallic Ag to Ag{sup +} when heated to above ~300{degrees}C in air. Heating rate, iodine loading levels and atmosphere are the important variables that determine AgI migration and results suggest that AgI may be completely incorporated into the mordenite structure by the 550{degrees}C sintering temperature.

Terry J. Garino; Tina M. Nenoff; Mark A. Rodriguez

2014-04-01T23:59:59.000Z

75

Dissolved iodine in rainfall,cloud,stream and groundwater in the Plynlimon area of mid-Wales Hydrol. Earth Syst. Sci., 11(1), 283293, 2007  

E-Print Network [OSTI]

). Further, there are issues of radioactive iodine contamination from nuclear weapon testing, nuclear, much higher concentrations can occur in brines associated with oil fields where concentrations can

Paris-Sud XI, Université de

76

Effect of iodination on human growth hormone and prolactin: characterized by bioassay, radioimmunoassay, radioreceptor assay, and electrophoresis  

SciTech Connect (OSTI)

Human GH (hGH) and PRL (hPRL) were iodinated using lactoperoxidase. The iodinated hormones were characterized by RIA, radioreceptor assay (RRA), and bioassay (BA) using the Nb2 Node lymphoma cell line. The proportion of tracer that could bind to rat liver membranes or rabbit antibodies was determined, and the distribution of iodinated hormones was examined using polyacrylamide gel electrophoresis. Excess antibody was capable of precipitating 87.9% of the radioactivity associated with the hGH tracer and 86.0% of the hPRL tracer. The maximal specific binding to a liver membrane preparation averaged 67.3% of the (/sup 125/I)iodo-hGH radioactivity and 48.8% of the (/sup 125/I)iodo-hPRL radioactivity. The respective BA and RRA activity estimates for (/sup 125/I)iodo-hGH averaged 90% and 114% of the activity measured by the RIA. For (/sup 125/I)iodo-hPRL, the values were 75% by BA and 68% by RRA. The bioactivity profiles of iodinated hGH and hPRL shifted anodally on polyacrylamide gel electrophoresis in comparison to the bioactivity distribution of the respective uniodinated hormones. Iodine incorporation rather than oxidation appeared to be responsible for the shift. After electrophoresis, all eluates which contained significant radioactivity were active in the BA and RIA. Furthermore, specific activities calculated from the bioactive hormone and radioactivity in each electrophoretic segment agreed well with the average specific activity estimated from the amount of iodine incorporated into the protein peak upon gel filtration. These data suggest that hGH and hPRL to a major degree retain biological integrity after iodination.

Hughes, J.P.; Tanaka, T.; Gout, P.W.; Beer, C.T.; Noble, R.L.; Friesen, H.G.

1982-09-01T23:59:59.000Z

77

Effect of iodination on human growth hormone and prolactin: characterized by bioassay, radioimmunoassay, radioreceptor assay, and electrophoresis  

SciTech Connect (OSTI)

Human GH (hGH) and PRL (hPRL) were iodinated using lactoperoxidase. The iodinated hormones were characterized by RIA, radioreceptor assay (RRA), and bioassay (BA) using the Nb2 Node lymphoma cell line. The proportion of tracer that could bind to rat liver membranes or rabbit antibodies was determined, and the distribution of iodinated hormones was examined using polyacrylamide gel electrophoresis. Excess antibody was capable of precipitating 87.9% of the radioactivity associated with the hGH tracer and 86.0% of the hPRL tracer. The maximal specific binding to a liver membrane preparation averaged 67.3% of the (/sup 125/I)iodo-hGH radioactivity and 48.8% of the (/sup 125/I)iodo-hPRL radioactivity. The respective BA and RRA activity estimates for (/sup 125/)iodo-hGH averaged 90% and 114% of the activity measured by the RIA. For (/sup 125/I)iodo-hPRL, the values were 75% by BA and 68% by RRA. The bioactivity profiles of iodinated hGH and hPRL shifted anodally on polyacrylamide gel electrophoresis in comparison to the bioactivity distribution of the respective uniodinated hormones. Iodine incorporation rather than oxidation appeared to be responsible for the shift. After electrophoresis, all eluates which contained significant radioactivity were active in the BA and RIA. Furthermore, specific activities calculated from the bioactive hormone and radioactivity in each electrophoretic segment agreed well with the average specific activity estimated from the amount of iodine incorporated into the protein peak upon gel filtration. These data suggest that hGH and hPRL to a major degree retain biological integrity after iodination.

Hughes, J.P. (Univ. of Manitoba, Winnipeg, Canada); Tanaka, T.; Gout, P.W.; Beer, C.T.; Noble, R.L.; Friesen, H.G.

1982-09-01T23:59:59.000Z

78

Dynamics of production of iodine atoms by dissociation of iodides in a pulsed self-sustained discharge  

SciTech Connect (OSTI)

Absorption at the laser transition has been used for the first time to assess the evolution of concentration of iodine atoms in a pulsed self-sustained discharge in mixtures of iodides with a buffer gas such as molecular nitrogen and helium. Dynamics of the iodine atom production is studied by the method of absorption spectroscopy. The dissociation of C{sub n}F{sub 2n+1}I and CnH{sub 2n+1}I (n = 1, 2) iodides is investigated. The energy required to produce atomic iodine is evaluated. The experimental data obtained for CF{sub 3}I are compared with the results of numerical simulations, their reasonable agreement being demonstrated. (active media)

Vagin, Nikolai P; Kochetov, Igor' V; Napartovich, A P; Yuryshev, Nikolai N

2013-07-31T23:59:59.000Z

79

Features of adsorbed radioactive chemical elements and their isotopes distribution in iodine air filters AU-1500 at nuclear power plants  

E-Print Network [OSTI]

The main aim of research is to investigate the physical features of spatial distribution of the adsorbed radioactive chemical elements and their isotopes in the granular filtering medium in the iodine air filters of the type of AU1500 in the forced exhaust ventilation systems at the nuclear power plant. The gamma activation analysis method is applied to accurately characterize the distribution of the adsorbed radioactive chemical elements and their isotopes in the granular filtering medium in the AU1500 iodine air filter after its long term operation at the nuclear power plant. The typical spectrum of the detected chemical elements and their isotopes in the AU1500 iodine air filter, which was exposed to the bremsstrahlung gamma quantum irradiation, produced by the accelerating electrons in the tantalum target, are obtained. The spatial distributions of the detected chemical element 127I and some other chemical elements and their isotopes in the layer of absorber, which was made of the cylindrical coal granule...

Neklyudov, I M; Dikiy, N P; Ledenyov, O P; Lyashko, Yu V

2013-01-01T23:59:59.000Z

80

LITERATURE SURVEY FOR GROUNDWATER TREATMENT OPTIONS FOR NITRATE IODINE-129 AND URANIUM 200-ZP-1 OPERABLE UNIT HANFORD SITE  

SciTech Connect (OSTI)

This literature review presents treatment options for nitrate, iodine-129, and uranium, which are present in groundwater at the 200-ZP-I Groundwater Operable Unit (OU) within the 200 West Area of the Hanford Site. The objective of this review is to determine available methods to treat or sequester these contaminants in place (i.e., in situ) or to pump-and-treat the groundwater aboveground (i.e., ex situ). This review has been conducted with emphasis on commercially available or field-tested technologies, but theoretical studies have, in some cases, been considered when no published field data exist. The initial scope of this literature review included only nitrate and iodine-I 29, but it was later expanded to include uranium. The focus of the literature review was weighted toward researching methods for treatment of nitrate and iodine-129 over uranium because of the relatively greater impact of those compounds identified at the 200-ZP-I OU.

BYRNES ME

2008-06-05T23:59:59.000Z

Note: This page contains sample records for the topic "iodine phos phorus" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Methods of Gas Phase Capture of Iodine from Fuel Reprocessing Off-Gas: A Literature Survey  

SciTech Connect (OSTI)

A literature survey was conducted to collect information and summarize the methods available to capture iodine from fuel reprocessing off-gases. Techniques were categorized as either wet scrubbing or solid adsorbent methods, and each method was generally described as it might be used under reprocessing conditions. Decontamination factors are quoted only to give a rough indication of the effectiveness of the method. No attempt is made to identify a preferred capture method at this time, although activities are proposed that would provide a consistent baseline that would aid in evaluating technologies.

Daryl Haefner

2007-02-01T23:59:59.000Z

82

Sulfur Iodine Process Summary for the Hydrogen Technology Down-Selection: Process Performance Package  

SciTech Connect (OSTI)

This document describes the details of implementing a Sulfur-Iodine (S-I) hydrogen production plant to deploy with the Next General Nuclear Power Plant (NGNP). Technical requirements and specifications are included, and a conceptual plant design is presented. The following areas of interest are outlined in particular as a baseline for the various technology comparisons: (1) Performance Criteria - (a) Quantity of hydrogen produced, (b) Purity of hydrogen produced, (c) Flexibility to serve various applications, (d) Waste management; (2) Economic Considerations - (a) Cost of hydrogen, (b) Development costs; and (3) Risk - (a) Technical maturity of the S-I process, (b) Development risk, (c) Scale up options.

Benjamin Russ

2009-06-01T23:59:59.000Z

83

Use of iodine surface geochemical surveys in the Lodgepole and Minnelusa plays, U.S. northern Rockies  

SciTech Connect (OSTI)

The use of surface geochemistry is becoming more prevalent in oil exploration, especially for focusing specific target areas for 2D and 3D seismic surveys. Presented here are two surface geochemical surveys utilizing the iodine method in delineating Upper Minnelusa sands of Permian age in the Powder River basin and Lodgepole Waulsortian-like mounds of Mississippian age in the Williston basin. Iodine is an indirect indicator of a petroleum accumulation at depth. Increases in iodine anomalies are caused by the presence of petroleum seepage in the upper part of the soil section. In the very shallow surface, less than 10 ft, a reaction occurs between hydrocarbons and iodine under sunlight forming inorganic compounds. The source of the iodine is either from minerals in the soil and/or from the atmosphere with ultraviolet light as the initiator of the reaction. Any iodine in the subsurface could not migrate far in the presence of hydrocarbons and due to its large molecular size. The compounds that form in the soil remain solid and are relatively difficult to remove. Any surface geochemical anomaly needs to be followed by seismic in order to provide a specific drilling target. If a surface geochemical survey is properly designed and implemented, when no anomaly is present, then to date regardless of the type of method used the results have been dry holes. If a surface geochemical anomaly is present, the intensity, areal extent, and quality of the anomaly cannot determine the economic viability of the accumulation of depth, but there is a significant increase in the success rate. The best utilization of these methods is to determine areas where there is no possibility of finding petroleum and focusing on areas that do. In the case of the Lodgepole and Minnelusa plays, surface geochemistry allows a low cost approach and helps focus and minimize 2D and 3D survey costs.

Tedesco, S.A.; Bretz, S. [Atoka Geochemical Services Corp., Englewood, CO (United States)

1995-06-05T23:59:59.000Z

84

A study of the reactions related to the catalytic decomposition of hydrogen peroxide by the iodate-iodine couple  

E-Print Network [OSTI]

of the requirement f' or the degree of' I'lASTER OF SCIENCE December 1970 Najor Subject: Chemistry 7 Fl 0 0 III A STUDY OF THE REACTIDNS RELATED TO 'THE CATALYTIC DECONPOSITION GF HYDROGEN PEROXIDE BY THE IODATE-IODINE COUPLE A Thesis by RADNILO S Ii...'ii C Approved as to style and content by: ~Chairz~n f Committee~ / [H d Oep tr ~t A1ember December 1970 ABSTRACT A Study of he Reactions Related to the Catalytic Deconposition of Hydrogen Peroxide by the Iodate-Iodine Couple. (December 1970...

Simic, Radmilo

1970-01-01T23:59:59.000Z

85

Generation of concentration density maxima of small dispersive coal dust particles in horizontal iodine air filter at air-dust aerosol blow  

E-Print Network [OSTI]

The spatial distributions of the small dispersive coal dust particles with the nano and micro sizes in the granular filtering medium with the cylindrical coal granules in the absorber in the horizontal iodine air filter during its long term operation at the nuclear power plant are researched. It is shown that the concentration density maxima of the small dispersive coal dust particles appear in the granular filtering medium with the cylindrical coal absorbent granules in the horizontal iodine air filter at an action by the air dust aerosol blow. The comparison of the measured aerodynamic resistances of the horizontal and vertical iodine air filters is conducted. The main conclusion is that the magnitude of the aerodynamic resistance of the horizontal iodine air filters is much smaller in comparison with the magnitude of the aerodynamic resistance of the vertical iodine air filters at the same loads of the air dust aerosol volumes. It is explained that the direction of the air dust aerosol blow and the direction of the gravitation force in the horizontal iodine air filter are orthogonal, hence the effective accumulation of the small dispersive coal dust particles takes place at the bottom of absorber in the horizontal iodine air filter. It is found that the air dust aerosol stream flow in the horizontal iodine air filter is not limited by the appearing structures, made of the precipitated small dispersive coal dust particles, in distinction from the vertical iodine air filter, in the process of long term operation of the iodine air filters at the nuclear power plant.

I. M. Neklyudov; O. P. Ledenyov; L. I. Fedorova; P. Ya. Poltinin

2013-06-11T23:59:59.000Z

86

Measurement of positive gain on the 1315 nm transition of atomic iodine pumped by O2,,a1  

E-Print Network [OSTI]

state I 2 P3/2 . Conventionally, the O2 1 is produced by a liquid chemistry singlet oxygen generator of gain. © 2004 American Institute of Physics. [DOI: 10.1063/1.1784519] The classic chemical oxygen the metastable excited singlet oxygen molecule, O2 a1 [de- noted O2 1 hereafter], and the iodine atom ground

Carroll, David L.

87

Oxygen Discharge and Post-Discharge Kinetics Experiments and Modeling for the Electric Oxygen-Iodine Laser System  

E-Print Network [OSTI]

Oxygen Discharge and Post-Discharge Kinetics Experiments and Modeling for the Electric Oxygen a low-pressure oxygen/helium/nitric oxide discharge. In the electric discharge oxygen-iodine laser (ElectricOIL) the discharge production of atomic oxygen, ozone, and other excited species adds levels

Carroll, David L.

88

Diffusion of Iodine and Rhenium in Category 3 Waste Encasement Concrete and Soil Fill Material  

SciTech Connect (OSTI)

Assessing long-term performance of Category 3 waste cement grouts for radionuclide encasement requires knowledge of the radionuclide-cement interactions and mechanisms of retention (i.e. sorption or precipitation). This understanding will enable accurate prediction of radionuclide fate when the waste forms come in contact with groundwater. A set of diffusion experiments using carbonated and non-carbonated concrete-soil half cells was conducted under unsaturated conditions (4% and 7% by wt moisture content). Spiked concrete half-cell specimens were prepared with and without colloidal metallic iron addition and were carbonated using supercritical carbon dioxide. Spikes of I and Re were added to achieve measurable diffusion profile in the soil part of the half-cell. In addition, properties of concrete materials likely to influence radionuclide migration such as carbonation were evaluated in an effort to correlate these properties with the release of iodine and rhenium.

Wellman, Dawn M.; Mattigod, Shas V.; Whyatt, Greg A.; Powers, Laura; Parker, Kent E.; Wood, Marcus I.

2006-12-15T23:59:59.000Z

89

Stable N-CuInSe.sub.2 /iodide-iodine photoelectrochemical cell  

DOE Patents [OSTI]

In a photoelectrochemical solar cell, stable output and solar efficiency in excess of 10% are achieved with a photoanode of n-CuInSe.sub.2 electrode material and an iodine/iodide redox couple used in a liquid electrolyte. The photoanode is prepared by treating the electrode material by chemical etching, for example in Br.sub.2 /MeOH; heating the etched electrode material in air or oxygen; depositing a surface film coating of indium on the electrode material after the initial heating; and thereafter again heating the electrode material in air or oxygen to oxidize the indium. The electrolyte is treated by the addition of Cu.sup.+ or Cu.sup.2+ salts and In.sup.3+ salts.

Cahen, David (Rehovot, IL); Chen, Yih W. (Lakewood, CO)

1985-01-01T23:59:59.000Z

90

The Sulfur-Iodine Cycle: Process Analysis and Design Using Comprehensive Phase Equilibrium Measurements and Modeling  

SciTech Connect (OSTI)

Of the 100+ thermochemical hydrogen cycles that have been proposed, the Sulfur-Iodine (S-I) Cycle is a primary target of international interest for the centralized production of hydrogen from nuclear power. However, the cycle involves complex and highly nonideal phase behavior at extreme conditions that is only beginning to be understood and modeled for process simulation. The consequence is that current designs and efficiency projections have large uncertainties, as they are based on incomplete data that must be extrapolated from property models. This situation prevents reliable assessment of the potential viability of the system and, even more, a basis for efficient process design. The goal of this NERI award (05-006) was to generate phase-equilibrium data, property models, and comprehensive process simulations so that an accurate evaluation of the S-I Cycle could be made. Our focus was on Section III of the Cycle, where the hydrogen is produced by decomposition of hydroiodic acid (HI) in the presence of water and iodine (I2) in a reactive distillation (RD) column. The results of this project were to be transferred to the nuclear hydrogen community in the form of reliable flowsheet models for the S-I process. Many of the project objectives were achieved. At Clemson University, a unique, tantalum-based, phase-equilibrium apparatus incorporating a view cell was designed and constructed for measuring fluid-phase equilibria for mixtures of iodine, HI, and water (known as HIx) at temperatures to 350 °C and pressures to 100 bar. Such measurements were of particular interest for developing a working understanding of the expected operation of the RD column in Section III. The view cell allowed for the IR observation and discernment of vapor-liquid (VL), liquid-liquid, and liquid-liquid-vapor (LLVE) equilibria for HIx systems. For the I2-H2O system, liquid-liquid equilibrium (LLE) was discovered to exist at temperatures up to 310-315 °C, in contrast to the models and predictions of earlier workers. For the I2-HI-H2O ternary, LLE and LLVE were all observed for the first time at temperatures of 160 and 200 °C. Three LLE tie-lines were measured at 160 °C, and preliminary indications are that the underlying phase behavior could result in further improvements in the performance of the S-I Cycle. Unfortunately, these new results were obtained too late in the project to be incorporated into the modeling and simulation work described below. At the University of Virginia, a uniquely complete and reliable model was developed for the thermodynamic properties of HIx, covering the range of conditions expected for the separation of product hydrogen and recycled iodine in the RD column located in Section III. The model was validated with all available property spectroscopy data. The results provide major advances over prior understanding of the chemical speciation involved. The model was implemented in process simulation studies of the S-I Cycle, which showed improvement in energy efficiency to 42%, as well as significantly smaller capital requirements due to lower pressure operation and much smaller equipment sizes. The result is that the S-I Cycle may be much more economically feasible than was previously thought. If both the experimental and modeling work described above were to be continued to ultimate process optimization, both the American public and the global community would benefit from this alternative energy source that does not produce carbon emissions.

Thies, Mark C.; O'Connell, J. P.; Gorensek, Maximilian B.

2010-01-10T23:59:59.000Z

91

Ab initio studies of ultrafast x-ray scattering of the photodissociation of iodine  

SciTech Connect (OSTI)

We computationally examine various aspects of the reaction dynamics of the photodissociation and recombination of molecular iodine. We use our recently proposed formalism to calculate time-dependent x-ray scattering signal changes from first principles. Different aspects of the dynamics of this prototypical reaction are studied, such as coherent and noncoherent processes, features of structural relaxation that are periodic in time versus nonperiodic dissociative processes, as well as small electron density changes caused by electronic excitation, all with respect to x-ray scattering. We can demonstrate that wide-angle x-ray scattering offers a possibility to study the changes in electron densities in nonperiodic systems, which render it a suitable technique for the investigation of chemical reactions from a structural dynamics point of view.

Debnarova, Andrea; Techert, Simone [Max Planck Institute for Biophysical Chemistry, 37077 Goettingen, Am Fassberg 11 (Germany); Schmatz, Stefan [Institut fuer Physikalische Chemie, Universitaet Goettingen, 37077 Goettingen, Tammannstr. 6 (Germany)

2010-09-28T23:59:59.000Z

92

A Sensitive Determination of Iodine Species, Including Organoiodine, for Freshwater and Seawater Samples Using High Performance Liquid Chromatography and Spectrophotometric Detection  

E-Print Network [OSTI]

, with minimal sample preparation, compared to existing methods. The method has been successfully applied to determine iodide, iodate as the difference of total inorganic iodide and iodide after reduction of the sample, and organic iodine as the difference...

Schwehr, K. A.; Santschi, P. H.

93

Influence by small dispersive coal dust particles of different fractional consistence on characteristics of iodine air filter at nuclear power plant  

E-Print Network [OSTI]

The main purpose of research is to determine the influence by the small dispersive coal dust particles of the different fractional consistence on the technical characteristics of the vertical iodine air filter at nuclear power plant. The research on the transport properties of the small dispersive coal dust particles in the granular filtering medium of absorber in the vertical iodine air filter is completed in the case, when the modeled aerodynamic conditions are similar to the real aerodynamic conditions. It is shown that the appearance of the different fractional consistence of small dispersive coal dust particles with the decreasing dimensions down to the micro and nano sizes at the action of the air dust aerosol stream normally results in a significant change of distribution of the small dispersive coal dust particles masses in the granular filtering medium of an absorber in the vertical iodine air filter, changing the vertical iodine air filter aerodynamic characteristics. The precise characterization of...

Neklyudov, I M; Fedorova, L I; Poltinin, P Ya

2013-01-01T23:59:59.000Z

94

Influence by small dispersive coal dust particles of different fractional consistence on characteristics of iodine air filter at nuclear power plant  

E-Print Network [OSTI]

The main purpose of research is to determine the influence by the small dispersive coal dust particles of the different fractional consistence on the technical characteristics of the vertical iodine air filter at nuclear power plant. The research on the transport properties of the small dispersive coal dust particles in the granular filtering medium of absorber in the vertical iodine air filter is completed in the case, when the modeled aerodynamic conditions are similar to the real aerodynamic conditions. It is shown that the appearance of the different fractional consistence of small dispersive coal dust particles with the decreasing dimensions down to the micro and nano sizes at the action of the air dust aerosol stream normally results in a significant change of distribution of the small dispersive coal dust particles masses in the granular filtering medium of an absorber in the vertical iodine air filter, changing the vertical iodine air filter aerodynamic characteristics. The precise characterization of the aerodynamic resistance of a model of the vertical iodine air filter is completed. The comparative analysis of the technical characteristics of the vertical and horizontal iodine air filters is also made.

I. M. Neklyudov; O. P. Ledenyov; L. I. Fedorova; P. Ya. Poltinin

2013-02-18T23:59:59.000Z

95

Iodine-131 releases from the Hanford Site, 1944--1947. Volume 1, Text: Hanford Environmental Dose Reconstruction Project  

SciTech Connect (OSTI)

Releases of fission product iodine-131 from separation plants at the Hanford reservation are calculated for the 1944 through 1947 period. Releases to the atmosphere were from the ventilation stacks of T and B separation plants. A reconstruction of daily separation plant operations forms the basis of the releases. The reconstruction traces the iodine-131 content of each fuel discharge from the B, D, and F Reactors to the dissolving step in the separation plants. Statistical computer modeling techniques are used to estimate hourly release histories based on sampling mathematical distribution functions that express the uncertainties in the source data and timing. The reported daily, monthly, and yearly estimates are averages and uncertainty ranges are based on 100 independent Monte Carlo ``realizations`` of the hourly release histories.

Heeb, C.M.

1992-10-01T23:59:59.000Z

96

Adsorbate-induced corrosion: anodic dissolution of palladium induced by chemisorbed iodine in halide-free acid solutions  

E-Print Network [OSTI]

as to style and content by: M. P. ria (Chair Co ittee) G. Vigh (Member) R. G. Anthony (Member) M. B. Hall (Head of Department) December 1991 ABSTRACT Adsorbate-Induced Corrosion: Anodic Dissolution of Palladium Induced by Chemisorbed Iodine... not anodically dissolve to an appreciable extent. Approach This investigation employed polycrystalline palladium foils, wires, and rods. Experimental measurements utilized a combination of conventional electrochemical techniques including voltammetry and...

Schimpf, Janemarie A

1991-01-01T23:59:59.000Z

97

Continuous-wave laser oscillation on the 1315 nm transition of atomic iodine pumped by O2,,a1  

E-Print Network [OSTI]

oxygen generator. There are many system issues having to do with weight, safety, and the ability.1063/1.1883317 The classic chemical oxygen-iodine laser COIL system1 operates on the I 2 P1/2 I 2 P3/2 electronic transi transfer between the metastable excited singlet oxygen molecule, O2 a1 de- noted as O2 1 hereafter

Carroll, David L.

98

Conversion and correction factors for historical measurements of Iodine-131 in Hanford-area vegetation, 1945--1947: Draft  

SciTech Connect (OSTI)

This report is a result of the Hanford Environmental Dose Reconstruction (HEDR) Project whose goal is to estimate the radiation dose that individuals could have received from emissions since 1944 at the US Department of Energy's (DOE) Hanford Site near Richland, Washington. The report describes in detail the reconstructed conversion and correction factors for historical measurements of iodine-131 in Hanford-area vegetation which was collected from the beginning of October 1945 through the end of December 1947.

Mart, E.I.; Denham, D.H.; Thiede, M.E.

1993-05-01T23:59:59.000Z

99

Abatement of Xenon and Iodine Emissions from Medical Isotope Production Facilities  

SciTech Connect (OSTI)

The capability of the International Monitoring System (IMS) to detect xenon from underground nuclear explosions is dependent on the radioactive xenon background. Adding to the background, medical isotope production (MIP) by fission releases several important xenon isotopes including xenon-133 and iodine-133 that decays to xenon-133. The amount of xenon released from these facilities may be equivalent to or exceed that released from an underground nuclear explosion. Thus the release of gaseous fission products within days of irradiation makes it difficult to distinguish MIP emissions from a nuclear explosion. In addition, recent shortages in molybdenum-99 have created interest and investment opportunities to design and build new MIP facilities in the United States and throughout the world. Due to the potential increase in the number of MIP facilities, a discussion of abatement technologies provides insight into how the problem of emission control from MIP facilities can be tackled. A review of practices is provided to delineate methods useful for abatement of medical isotopes.

Doll, Charles G. [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Sorensen, Christina M. [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Bowyer, Ted W. [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Friese, Judah I. [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Hayes, James C. [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Hoffman, Emma L. [Australian Nuclear Science and Technology Organisation, Menai (Australia); Kephart, Rosara F. [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

2014-04-01T23:59:59.000Z

100

Chalcogen-based aerogels as a multifunctional platform for remediation of radioactive iodine  

SciTech Connect (OSTI)

Aerogels employing chalcogen-based (i.e., S, Se, and/or Te) structural units and interlinking metals are termed chalcogels and have many emerging applications. Here, chalcogels are discussed in the context of nuclear fuel reprocessing and radioactive waste remediation. Motivated by previous work on removal of heavy metals in aqueous solution, we explored the application of germanium sulfide chalcogels as a sorbent for gas-phase I2 based on Pearson's Hard/Soft Acid-Base (HSAB) principle. This work was driven by a significant need for high-efficiency sorbents for I-129, a long-lived isotope evolved during irradiated UO2 nuclear fuel reprocessing. These chalcogel compositions are shown to possess an affinity for iodine gas, I2(g), at various concentrations in air and the affinity is attributed to a strong chemical attraction between the chalcogen and I2(g), according to the HSAB principle. The high sorption efficiency is facilitated by the high porosity as well as the exceptionally large surface area of the chalcogels.

Riley, Brian J.; Chun, Jaehun; Ryan, Joseph V.; Matyas, Josef; Li, Xiaohong S.; Matson, Dean W.; Sundaram, S. K.; Strachan, Denis M.; Vienna, John D.

2011-12-22T23:59:59.000Z

Note: This page contains sample records for the topic "iodine phos phorus" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


101

Preoperative irradiation, lymphadenectomy, and 125iodine implantation for patients with localized carcinoma of the prostate  

SciTech Connect (OSTI)

Fifty-four patients with clinically and surgically localized prostatic carcinoma were treated with low-dose preoperative irradiation (1050 cGy), pelvic lymphadenectomy, and interstitial /sup 125/Iodine implantation. The follow-up range is 2 to 9 years with a median follow-up of 5 years. Overall local tumor control is 92%. Actuarial 5-year survival is 86% and the actuarial disease-free survival at 5 years is 73%. Patients with poorly differentiated tumors have a significantly worse actuarial survival (62%) at 5 years than patients with well (95%) or moderately well differentiated tumors (93%), p = 0.04. Disease-free survival at 5 years was influenced by grade: well (100%), moderate (60%), and poor (48%), p = 0.03. Multivariate regression analysis indicates that only the degree of differentiation (p = 0.05) significantly impacts on survival. Both degree of differentiation (p = 0.04) and nodal status (p = 0.03) significantly influence disease-free survival. Potency has been maintained in 71% of patients potent at the time of implantation. Late reactions have been acceptable to date: bladder outlet obstruction (13%), mild proctitis (13%), cystourethritis (6%), incontinence (2%), and prostatic calculi (2%).

DeLaney, T.F.; Shipley, W.U.; O'Leary, M.P.; Biggs, P.J.; Prout, G.R. Jr.

1986-10-01T23:59:59.000Z

102

Detection of Gravitational Redshift on the Solar Disk by Using Iodine-Cell Technique  

E-Print Network [OSTI]

With an aim to examine whether the predicted solar gravitational redshift can be observationally confirmed under the influence of the convective Doppler shift due to granular motions, we attempted measuring the absolute spectral line-shifts on a large number of points over the solar disk based on an extensive set of 5188-5212A region spectra taken through an iodine-cell with the Solar Domeless Telescope at Hida Observatory. The resulting heliocentric line shifts at the meridian line (where no rotational shift exists), which were derived by finding the best-fit parameterized model spectrum with the observed spectrum and corrected for the earth's motion, turned out to be weakly position-dependent as ~ +400 m/s near the disk center and increasing toward the limb up to ~ +600 m/s (both with a standard deviation of sigma ~ 100 m/s). Interestingly, this trend tends to disappear when the convectiveshift due to granular motions (~-300 m/s at the disk center and increasing toward the limb; simulated based on the two-c...

Takeda, Yoichi

2012-01-01T23:59:59.000Z

103

LABORATORY REPORT ON IODINE ({sup 129}I AND {sup 127}I) SPECIATION, TRANSFORMATION AND MOBILITY IN HANFORD GROUNDWATER, SUSPENDED PARTICLES AND SEDIMENTS  

SciTech Connect (OSTI)

The Hanford Site in eastern Washington produced plutonium for several decades and in the process generated billions of gallons of radioactive waste. Included in this complex mixture of waste was 50 Ci of iodine-129 ({sup 129}I). Iodine-129’s high abundance, due to its high fission yield, and extreme toxicity result in iodine-129 becoming a key risk driver at many Department of Energy (DOE) sites. The mobility of radioiodine in arid environments, such as the Hanford Site, depends largely on its chemical speciation and is also greatly affected by many other environmental factors, especially natural sediment organic matter (SOM). Groundwater radioiodine speciation has not been measured in arid regions with major plumes or large disposed {sup 129}I inventories, including the Hanford Site, Idaho National Laboratory, and Nevada Test Site. In this study, stable iodine-127 and radioiodine-129 speciation, pH, and dissolved organic carbon (DOC) of groundwater samples collected from seven wells located in the 200-West Area of the Hanford site were investigated. The most striking finding was that iodate (IO{sub 3}{sup -}) was the most abundant species. Unexpectedly, iodide (I{sup -}), which was likely the form of iodine in the source materials and the expected dominant groundwater species based on thermodynamic considerations, only accounted for 1-2% of the total iodine concentration. It is likely that the relatively high pH and the low abundance of sedimentary organic matter (SOM) that is present at the site slowed down or even inhibited the reduction of iodate, as SOM abiotically reduce iodate into iodide. Moreover, a study on the kinetics of iodide and iodate uptake and aqueous speciation transformation by three representative subsurface Hanford sediments was performed over a period of about one month. This study was carried out by using iodide-125 or iodate-125 at the ambient iodine-127concentration found at the site. Iodate K{sub d} values were on average 89% greater than iodide K{sub d} values, and the K{sub d} values for both species tended to increase with the amount of organic carbon (OC) present in the sediment. It is especially noteworthy that this trend existed at the very low OC concentrations that naturally exist in the Hanford sediments. Iodine and OC can form essentially irreversible covalent bonds, thereby providing a yet unstudied {sup 129}I retardation reaction at the Hanford Site. In addition to the transformation of iodine species, the sediment collected from the vadose zone also released stable iodide into the aqueous phase. It was found that the three sediments all took up the ambient iodate from the groundwater and slowly transformed it into iodide under the laboratory conditions, likely dependent on the abundance of reducing agents such as organic matter and Fe{sup 2+}. Therefore two competitive iodine processes were identified, the tendency for the sediment to reduce iodate to iodide, and the groundwater chemistry to maintain the iodine as iodate, presumably it is largely the result of natural pH and dissolved O{sub 2}/Eh levels. Suspended carbonate (and silica) particles collected from Hanford groundwater contained elevated amounts of iodine (142 ± 8 ?g/g iodine), consisting mainly of iodate (>99%). Iodate was likely incorporated into the carbonate structure during calcite precipitation upon degasing of CO{sub 2} as the groundwater samples were removed from the subsurface. This concentration of groundwater iodate in precipitated carbonate has implication to long-term fate and transport of 129I and on active in-situ {sup 129}I groundwater remediation. This study provides some of the first groundwater radioiodine speciation studies conducted in arid environments and provides much needed mechanistic descriptions to permit making informed decisions about low-cost/high intellectual input remediation options, such as monitored natural attenuation, or long-term stewardship of nuclear waste disposal sites.

Kaplan, D.; Santschi, P.; Xu, C.; Zhang, S.; Ho, Y.; Li, H.; Schwehr, K.

2012-09-30T23:59:59.000Z

104

Generation of concentration density maxima of small dispersive coal dust particles in horizontal iodine air filter at air-dust aerosol blow  

E-Print Network [OSTI]

The spatial distributions of the small dispersive coal dust particles with the nano and micro sizes in the granular filtering medium with the cylindrical coal granules in the absorber in the horizontal iodine air filter during its long term operation at the nuclear power plant are researched. It is shown that the concentration density maxima of the small dispersive coal dust particles appear in the granular filtering medium with the cylindrical coal absorbent granules in the horizontal iodine air filter at an action by the air dust aerosol blow. The comparison of the measured aerodynamic resistances of the horizontal and vertical iodine air filters is conducted. The main conclusion is that the magnitude of the aerodynamic resistance of the horizontal iodine air filters is much smaller in comparison with the magnitude of the aerodynamic resistance of the vertical iodine air filters at the same loads of the air dust aerosol volumes. It is explained that the direction of the air dust aerosol blow and the directi...

Neklyudov, I M; Fedorova, L I; Poltinin, P Ya

2013-01-01T23:59:59.000Z

105

Separation, Concentration, and Immobilization of Technetium and Iodine from Alkaline Supernate Waste  

SciTech Connect (OSTI)

Development of remediation technologies for the characterization, retrieval, treatment, concentration, and final disposal of radioactive and chemical tank waste stored within the Department of Energy (DOE) complex represents an enormous scientific and technological challenge. A combined total of over 90 million gallons of high-level waste (HLW) and low-level waste (LLW) are stored in 335 underground storage tanks at four different DOE sites. Roughly 98% of this waste is highly alkaline in nature and contains high concentrations of nitrate and nitrite salts along with lesser concentrations of other salts. The primary waste forms are sludge, saltcake, and liquid supernatant with the bulk of the radioactivity contained in the sludge, making it the largest source of HLW. The saltcake (liquid waste with most of the water removed) and liquid supernatant consist mainly of sodium nitrate and sodium hydroxide salts. The main radioactive constituent in the alkaline supernatant is cesium-137, but strontium-90, technetium-99, and transuranic nuclides are also present in varying concentrations. Reduction of the radioactivity below Nuclear Regulatory Commission (NRC) limits would allow the bulk of the waste to be disposed of as LLW. Because of the long half-life of technetium-99 (2.1 x 10 5 y) and the mobility of the pertechnetate ion (TcO 4 - ) in the environment, it is expected that technetium will have to be removed from the Hanford wastes prior to disposal as LLW. Also, for some of the wastes, some level of technetium removal will be required to meet LLW criteria for radioactive content. Therefore, DOE has identified a need to develop technologies for the separation and concentration of technetium-99 from LLW streams. Eichrom has responded to this DOE-identified need by demonstrating a complete flowsheet for the separation, concentration, and immobilization of technetium (and iodine) from alkaline supernatant waste.

James Harvey; Michael Gula

1998-12-07T23:59:59.000Z

106

High pressure sulfuric acid decomposition experiments for the sulfur-iodine thermochemical cycle.  

SciTech Connect (OSTI)

A series of three pressurized sulfuric acid decomposition tests were performed to (1) obtain data on the fraction of sulfuric acid catalytically converted to sulfur dioxide, oxygen, and water as a function of temperature and pressure, (2) demonstrate real-time measurements of acid conversion for use as process control, (3) obtain multiple measurements of conversion as a function of temperature within a single experiment, and (4) assess rapid quenching to minimize corrosion of metallic components by undecomposed acid. All four of these objectives were successfully accomplished. This report documents the completion of the NHI milestone on high pressure H{sub 2}SO{sub 4} decomposition tests for the Sulfur-Iodine (SI) thermochemical cycle project. All heated sections of the apparatus, (i.e. the boiler, decomposer, and condenser) were fabricated from Hastelloy C276. A ceramic acid injection tube and a ceramic-sheathed thermocouple were used to minimize corrosion of hot liquid acid on the boiler surfaces. Negligible fracturing of the platinum on zirconia catalyst was observed in the high temperature decomposer. Temperature measurements at the exit of the decomposer and at the entry of the condenser indicated that the hot acid vapors were rapidly quenched from about 400 C to less than 20 C within a 14 cm length of the flow path. Real-time gas flow rate measurements of the decomposition products provided a direct measurement of acid conversion. Pressure in the apparatus was preset by a pressure-relief valve that worked well at controlling the system pressure. However, these valves sometimes underwent abrupt transitions that resulted in rapidly varying gas flow rates with concomitant variations in the acid conversion fraction.

Velasquez, Carlos E; Reay, Andrew R.; Andazola, James C.; Naranjo, Gerald E.; Gelbard, Fred

2005-09-01T23:59:59.000Z

107

The influence of iodinated casein and high fat diets on the performance and incidence of fatty livers in laying hens  

E-Print Network [OSTI]

THE INl'LUENCE OF IODINATED CASEIN AND HIGH FAT DIETS ON THE PEBFORMANC' AND INCIDENCE OF FATTY LIVERS IN LAYING H"NS A Thesis Loui" Lee Young Submitted to the Graduate College of the Texas A&II Univer -ity in partial fulfillment... of the requirement for the degree of MASTER OF SCIENCE January 1967 Major Subject oultry Science THE INPLUENCE OP IODINA'I "D CAS IN AND HIGH FAT DIETS ON THE P, HFOHMAI'JCE AND INCIDENCE OP PATTY LIVENS IN LAYING HENS A Thesis Louis Lee Young Approved...

Young, Louis Lee

1967-01-01T23:59:59.000Z

108

Proceedings of the International Conference on Lasers `95, eds. V.J. Corcoran and T.A. Goldman, STS Press, McLean VA, 1996, pp. 225-231. OPTIMIZING HIGH PRESSURE CHEMICAL OXYGEN-IODINE LASERS  

E-Print Network [OSTI]

Press, McLean VA, 1996, pp. 225-231. OPTIMIZING HIGH PRESSURE CHEMICAL OXYGEN-IODINE LASERS David L laser model was baselined to existing oxygen-iodine research assessment and device improvement chemical(1) generator. It may be possible to improve high pressure RADICL performance by increasing the number of large

Carroll, David L.

109

Gain and continuous-wave laser oscillation on the 1315 nm atomic iodine transition pumped by an air-helium electric discharge  

E-Print Network [OSTI]

peroxide and Cl2 gas. Logistic issues with this chemical sin- glet oxygen generator motivated many by a radio-frequency-excited electric discharge sustained in a dry air-He­NO gas mixture. Active oxygen American Institute of Physics. DOI: 10.1063/1.2957678 The classical chemical oxygen iodine laser COIL re

Carroll, David L.

110

Conversion and correction factors for historical measurements of Iodine-131 in Hanford-area vegetation, 1945--1947: Draft. Hanford Environmental Dose Reconstruction Project  

SciTech Connect (OSTI)

This report is a result of the Hanford Environmental Dose Reconstruction (HEDR) Project whose goal is to estimate the radiation dose that individuals could have received from emissions since 1944 at the US Department of Energy`s (DOE) Hanford Site near Richland, Washington. The report describes in detail the reconstructed conversion and correction factors for historical measurements of iodine-131 in Hanford-area vegetation which was collected from the beginning of October 1945 through the end of December 1947.

Mart, E.I.; Denham, D.H.; Thiede, M.E.

1993-05-01T23:59:59.000Z

111

The application of iodine and magnetic susceptibility surface geochemical surveys in the Lodgepole Play, Eastern Williston Basin, North Dakota  

SciTech Connect (OSTI)

The use of surface geochemistry as a first pass exploration tool is becoming more prevalent in petroleum exploration. This is especially true due to the high cost of 2-D and 3-D surveys in defining small targets such as the Waulsortian mounds of the Lodgepole Formation. Surface geochemical surveys are very effective in pinpointing specific target areas for seismic surveying and thus reducing costs. Presented are examples of surface geochemical surveys utilizing magnetic susceptibility and iodine methods in delineating reservoirs in the Lodgepole, Mission Canyon and Red River formations. The types of surveys presented vary from reconnaissance to detail and examples of how to define a grid will be discussed. Surface geochemical surveys can be very effective when the areal extent of the target(s) and the purpose of the survey are clearly defined prior to implementation. By determining which areas have microseepage and which areas do not, surface geochemistry can be a very effective tool in focusing exploration efforts and maximizing exploration dollars.

Tedesco, S.A. [Atoka Geochemical Services Corp., Englewood, CO (United States)

1996-06-01T23:59:59.000Z

112

JOURNAL DE PHYSIQUE ColZoque C9, suppZe'ment au nO1l, Tome 41, novembre 1980, page C9-449 A POTENTIAL ATOMIC IODINE LASER PUMPED BY ELECTRICALLY GENERATED 'A OXYGEN  

E-Print Network [OSTI]

-449 A POTENTIAL ATOMIC IODINE LASER PUMPED BY ELECTRICALLY GENERATED 'A OXYGEN G. Fournier, J. Bonnet and D ation. This paper shows that an electron generator of 1~ oxygen [21 . A condition beam controlled discharge could be an for lasing is a concentration ratio ['A] / efficient oxygen generator to lase with C3z

Paris-Sud XI, Université de

113

Distribution of small dispersive coal dust particles and absorbed radioactive chemical elements in conditions of forced acoustic resonance in iodine air filter at nuclear power plant  

E-Print Network [OSTI]

The physical features of distribution of the small dispersive coal dust particles and the adsorbed radioactive chemical elements and their isotopes in the absorber with the granular filtering medium with the cylindrical coal granules were researched in the case of the intensive air dust aerosol stream flow through the iodine air filter (IAF). It was shown that, at the certain aerodynamic conditions in the IAF, the generation of the acoustic oscillations is possible. It was found that the acoustic oscillations generation results in an appearance of the standing acoustic waves of the air pressure (density) in the IAF. In the case of the intensive blow of the air dust aerosol, it was demonstrated that the standing acoustic waves have some strong influences on both: 1) the dynamics of small dispersive coal dust particles movement and their accumulation in the IAF; 2) the oversaturation of the cylindrical coal granules by the adsorbed radioactive chemical elements and their isotopes in the regions, where the antin...

Ledenyov, Oleg P

2013-01-01T23:59:59.000Z

114

The development and deployment of a ground-based, laser-induced fluorescence instrument for the in situ detection of iodine monoxide radicals  

SciTech Connect (OSTI)

High abundances of iodine monoxide (IO) are known to exist and to participate in local photochemistry of the marine boundary layer. Of particular interest are the roles IO plays in the formation of new particles in coastal marine environments and in depletion episodes of ozone and mercury in the Arctic polar spring. This paper describes a ground-based instrument that measures IO at mixing ratios less than one part in 10{sup 12}. The IO radical is measured by detecting laser-induced fluorescence at wavelengths longer that 500 nm. Tunable visible light is used to pump the A{sup 2}?{sub 3/2} (v{sup ?} = 2) ? X{sup 2}?{sub 3/2} (v{sup ?} = 0) transition of IO near 445 nm. The laser light is produced by a solid-state, Nd:YAG-pumped Ti:Sapphire laser at 5 kHz repetition rate. The laser-induced fluorescence instrument performs reliably with very high signal-to-noise ratios (>10) achieved in short integration times (<1 min). The observations from a validation deployment to the Shoals Marine Lab on Appledore Island, ME are presented and are broadly consistent with in situ observations from European Coastal Sites. Mixing ratios ranged from the instrumental detection limit (<1 pptv) to 10 pptv. These data represent the first in situ point measurements of IO in North America.

Thurlow, M. E., E-mail: thurlow@huarp.harvard.edu; Hannun, R. A.; Lapson, L. B.; Anderson, J. G. [Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138 (United States)] [Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138 (United States); Co, D. T. [Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138 (United States) [Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138 (United States); Argonne-Northwestern Solar Energy Research Center and Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208-3113 (United States); O'Brien, A. S. [Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138 (United States) [Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138 (United States); Department of Civil and Environmental Engineering, Princeton University, Princeton, New Jersey 08544 (United States); Hanisco, T. F. [Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138 (United States) [Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138 (United States); NASA Goddard Space Flight Center, Code 614, Greenbelt, Maryland 20771 (United States)

2014-04-15T23:59:59.000Z

115

Distribution of small dispersive coal dust particles and absorbed radioactive chemical elements in conditions of forced acoustic resonance in iodine air filter at nuclear power plant  

E-Print Network [OSTI]

The physical features of distribution of the small dispersive coal dust particles and the adsorbed radioactive chemical elements and their isotopes in the absorber with the granular filtering medium with the cylindrical coal granules were researched in the case of the intensive air dust aerosol stream flow through the iodine air filter (IAF). It was shown that, at the certain aerodynamic conditions in the IAF, the generation of the acoustic oscillations is possible. It was found that the acoustic oscillations generation results in an appearance of the standing acoustic waves of the air pressure (density) in the IAF. In the case of the intensive blow of the air dust aerosol, it was demonstrated that the standing acoustic waves have some strong influences on both: 1) the dynamics of small dispersive coal dust particles movement and their accumulation in the IAF; 2) the oversaturation of the cylindrical coal granules by the adsorbed radioactive chemical elements and their isotopes in the regions, where the antinodes of the acoustic waves are positioned. Finally, we completed the comparative analysis of the theoretical calculations with the experimental results, obtained for the cases of: 1) the experimental aerodynamic modeling of physical processes of the absorbed radioactive chemical elements and their isotopes distribution in the IAF; and 2) the gamma-activation spectroscopy analysis of the absorbed radioactive chemical elements and their isotopes distribution in the IAF. We made the innovative propositions on the necessary technical modifications with the purpose to improve the IAF technical characteristics and increase its operational time at the nuclear power plant (NPP), going from the completed precise characterization of the IAF parameters at the long term operation.

Oleg P. Ledenyov; Ivan M. Neklyudov

2013-06-14T23:59:59.000Z

116

Iodine-131 Releases from Radioactive Lanthanum Processing at the X-10 Site in Oak Ridge, Tennessee (1944-1956)- An Assessment of Quantities released, Off-Site Radiation Doses, and Potential Excess Risks of Thyroid Cancer, Volume 1  

SciTech Connect (OSTI)

In the early 1990s, concern about the Oak Ridge Reservation's past releases of contaminants to the environment prompted Tennessee's public health officials to pursue an in-depth study of potential off-site health effects at Oak Ridge. This study, the Oak Ridge dose reconstruction, was supported by an agreement between the U.S. Department of Energy (DOE) and the State of Tennessee, and was overseen by a 12-member panel appointed by Tennessee's Commissioner of Health. One of the major contaminants studied in the dose reconstruction was radioactive iodine, which was released to the air by X-10 (now called Oak Ridge National Laboratory) as it processed spent nuclear reactor fuel from 1944 through 1956. The process recovered radioactive lanthanum for use in weapons development. Iodine concentrates in the thyroid gland so health concerns include various diseases of the thyroid, such as thyroid cancer. The large report, ''Iodine-131 Releases from Radioactive Lanthanum Processing at the X-10 Site in Oak Ridge, Tennessee (1944-1956) - An Assessment of Quantities Released, Off-site Radiation Doses, and Potential Excess Risks of Thyroid Cancer,'' is in two volumes. Volume 1 is the main body of the report, and Volume 1A, which has the same title, consists of 22 supporting appendices. Together, these reports serve the following purposes: (1) describe the methodologies used to estimate the amount of iodine-131 (I-131) released; (2) evaluate I-131's pathway from air to vegetation to food to humans; (3) estimate doses received by human thyroids; (4) estimate excess risk of acquiring a thyroid cancer during ones lifetime; and (5) provide equations, examples of historical documents used, and tables of calculated values. Results indicate that females born in 1952 who consumed milk from a goat pastured a few miles east of X-10 received the highest doses from I-131 and would have had the highest risks of contracting thyroid cancer. Doses from cow's milk are considerably less . Detailed dose and risk estimates, and associated uncertainties, for other contaminants studied for the Oak Ridge dose reconstruction are presented in several other technical reports. One way to easily locate them in OSTI's Information Bridge is by searching the ''report number field'' for the number DOE/OR/21981*. Be sure to place the asterisk after the base number so your search can list the complete series of reports related to Oak Ridge Dose Reconstruction.

Apostoaei, A.I.; Burns, R.E.; Hoffman, F.O.; Ijaz, T.; Lewis, C.J.; Nair, S.K.; Widner, T.E.

1999-07-01T23:59:59.000Z

117

Equilibria in aqueous iodine solutions  

E-Print Network [OSTI]

for the determination of pH and. 1odide concentration. This instrument, reads pH to 0. 001 pH units and millivolts to F 1 mv. An Orion Specific Ion Electrode, Iodide Model 94-53, was used in the iodide determination. A Corning Triple Purpose pH glass elect- rode... with such electrodes fully confirms this statement. The optimum concentration of Solution I was found to be between 5 x 10 and 10 H iodide. Error in ZIIF Although short-term reproducibility to within 0. 001 26 pH unit can in principle be achieved. with the glass...

Burger, Joanne Denise

1970-01-01T23:59:59.000Z

118

The {sup 2}P{sub 1/2} {yields} {sup 2}P{sub 3/2} laser transition in atomic iodine and the problem of search for signals from extraterrestrial intelligence  

SciTech Connect (OSTI)

It is proposed to search for signals from extraterrestrial intelligence (ETI) at a wavelength of 1.315 {mu}m of the laser {sup 2}P{sub 1/2} {yields} {sup 2}P{sub 3/2} transition in the atomic iodine, which can be used for this purpose as the natural frequency reference. The search at this wavelength is promising because active quantum filters (AQFs) with the quantum sensitivity limit have been developed for this wavelength, which are capable of receiving laser signals, consisting of only a few photons, against the background of emission from a star under study. In addition, high-power iodine lasers emitting diffraction-limited radiation at 1.315 {mu}m have been created, which highly developed ETI also can have. If a ETI sends in our direction a diffraction-limited 10-ns, 1-kJ laser pulse with the beam diameter of 10 m, a receiver with an AQF mounted on a ten-meter extra-atmospheric optical telescope can detect this signal at a distance of up to 300 light years, irrespective of the ETI position on the celestial sphere. The realisation of the projects for manufacturing optical telescopes of diameter 30 m will increase the research range up to 2700 light years. A weak absorption of the 1.315-{mu}m radiation in the Earth atmosphere (the signal is attenuated by less than 20%) allows the search for ETI signals by using ground telescopes equipped with adaptive optical systems. (laser applications and other topics in quantum electronics)

Kutaev, Yu F; Mankevich, S K ['Astrofizika' Research and Production Association (Russian Federation); Nosach, O Yu; Orlov, E P [P.N. Lebedev Physics Institute, Russian Academy of Sciences, Moscow (Russian Federation)

2007-07-31T23:59:59.000Z

119

Oak Ridge Reservation Volume 3. Records relating to RaLa, iodine-131, and cesium-137 at the Oak Ridge National Laboratory and the Oak Ridge Operations Office: A guide to record series of the Department of Energy and its contractors  

SciTech Connect (OSTI)

The purpose of this guide is to describe each of the documents and record series pertaining to the production, release, and disposal of radioactive barium-lanthanum (RaLa), iodine-131, and cesium-137 at the Department of Energy`s (DOE) Oak Ridge National Laboratory (ORNL) in Oak Ridge, Tennessee. History Associates Incorporated (HAI) prepared this guide as part of DOE`s Epidemiologic Records Inventory Project, which seeks to verify and conduct inventories of epidemiologic and health-related records at various DOE and DOE contractor sites. This introduction briefly describes the Epidemiologic Records Inventory Project and HAI`s role. It provides information on the history of the DOE-Oak Ridge Reservation (ORR), particularly ORNL. Specific attention is given to the production of RaLa and the fission products iodine-131 and cesium-137. This introduction also describes the methodologies HAI used in the selection and inventorying of documents and record series pertaining to RaLa, iodine-131, and cesium-137, and in the production of this guide. Concluding paragraphs describe the arrangement of the record series, explain the information contained in the record series descriptions, and indicate restrictions on access to the records.

NONE

1995-03-21T23:59:59.000Z

120

Iodine-131 Releases from Radioactive Lanthanum Processing at the X-10 Site in Oak Ridge, Tennessee (1944-1956)- An Assessment of Quantities released, Off-Site Radiation Doses, and Potential Excess Risks of Thyroid Cancer- APPENDICES Appendices-Volume 1A  

SciTech Connect (OSTI)

This report consists of all the appendices for the report described below: In the early 1990s, concern about the Oak Ridge Reservation's past releases of contaminants to the environment prompted Tennessee's public health officials to pursue an in-depth study of potential off-site health effects at Oak Ridge. This study, the Oak Ridge dose reconstruction, was supported by an agreement between the U.S. Department of Energy (DOE) and the State of Tennessee, and was overseen by a 12-member panel appointed by Tennessee's Commissioner of Health. One of the major contaminants studied in the dose reconstruction was radioactive iodine, which was released to the air by X-10 (now called Oak Ridge National Laboratory) as it processed spent nuclear reactor fuel from 1944 through 1956. The process recovered radioactive lanthanum for use in weapons development. Iodine concentrates in the thyroid gland so health concerns include various diseases of the thyroid, such as thyroid cancer. The large report, ''Iodine-131 Releases from Radioactive Lanthanum Processing at the X-10 Site in Oak Ridge, Tennessee (1944-1956) - An Assessment of Quantities Released, Off-site Radiation Doses, and Potential Excess Risks of Thyroid Cancer,'' is in two volumes. Volume 1 is the main body of the report, and Volume 1A, which has the same title, consists of 22 supporting appendices. Together, these reports serve the following purposes: (1) describe the methodologies used to estimate the amount of iodine-131 (I-131) released; (2) evaluate I-131's pathway from air to vegetation to food to humans; (3) estimate doses received by human thyroids; (4) estimate excess risk of acquiring a thyroid cancer during ones lifetime; and (5) provide equations, examples of historical documents used, and tables of calculated values as appendices. Results indicate that females born in 1952 who consumed milk from a goat pastured a few miles east of X-10 received the highest doses from I-131 and would have had the highest risks of contracting thyroid cancer. Doses from cow's milk are considerably less. Detailed dose and risk estimates, and associated uncertainties, for other contaminants studied in the Oak Ridge dose reconstruction are presented in several other technical reports. One way to easily locate them in OSTI's Information Bridge is by searching the ''report number field'' for the number DOE/OR/21981*. Be sure to place the asterisk after the base number so your search can list the complete series of reports related to Oak Ridge Dose Reconstruction.

Apostoaei, A.I.; Burns, R.E.; Hoffman, F.O.; Ijaz, T.; Lewis, C.J.; Nair, S.K.; Widner, T.E.

1999-07-01T23:59:59.000Z

Note: This page contains sample records for the topic "iodine phos phorus" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Dry deposition of gaseous elemental iodine on water  

E-Print Network [OSTI]

to receptor is essential in hazard evaluation. These processes include diffusion in the atmosphere and deposition on the earth's surface, followed by translocation through bioenvironmental pathways. All nuclear power plants sre constructed near a large... body of water used for cooling, and, at the present time, all nuclear plants release gaseous radioiodine. As a result, deposition of I2 on surface water is sn additional exposure pathway which must be considered when evaluating the hazard...

Allen, Michael Dana

1974-01-01T23:59:59.000Z

122

Technetium and Iodine Separations in the UREX Process.  

SciTech Connect (OSTI)

The Accelerator Transmutation of Waste (ATW) program is being developed to determine the feasibility of separatin and transmutating the transactinides (Pu-Cm) and long-lived fission product (99Tc and 'I) from spent light water reactor (LWR) fuel. This approach would help with the disposal of spent commercial fuel. In addition, since the residual waste after ATW treatment will have much lower levels of long-lived species, this process may improve the performance and acceptability of long-term geologic disposal of nuclear waste. A roadmap for the Accelerator Transmutation of Waste (ATW) was submitted to Congress in 1999.' This document gave an overall view of the ATW concept and program. A subsequent document prepared by the Technical Working Group for ATW Separations Technologies and Waste Forms issued a second roadmap that dealt more specifically with the radionuclide separations and waste disposal needs for the ATW program.' This latter document discusses the UREX (Uranium Extraction) process. The latest iteration of the UREX flowsheet is shown in Figure le3T his flowsheet anticipates the co-extraction of technetium with uranium from dissolved LWR fuel by tributylphosphate (TBP) and their subsequent sequential bwk-extraction from the TBP stream.

Schroeder, N. C. (Norman C.); Attrep, Moses; Marrero, T. (Thomas)

2001-01-01T23:59:59.000Z

123

The crystal structure of the triphenylphosphine sulfide - iodine addition complex  

E-Print Network [OSTI]

. . 7274 92 ~ 8810 35*3628 33. 6805 16. 7589 25 3752 16 5130 22. 7232 55 ' 4284' 48. 4644 53. 8980 113. 6853 39 0346 ? ? ? -25. 3724 0 0 0 0 0 5 5 5 -5 6 8 8 0 34 2100 17 8600 7 4900 '11 4300 19 5600 36 1436 16 3137 14 ' 1642...

Schweikert, William Walter

1966-01-01T23:59:59.000Z

124

Measurement of the resistivity versus temperature in iodine single crystals  

E-Print Network [OSTI]

Me:. . of: the' aygnreti'up. O'M:~e =', ? brana, rod, - C' ln the- oopper blond, ", E . e-, the-. heater. &&re; . . : ';;;!, :; and 8' 9:e ?tIie danplj mounted Xn the ogIindH. oa1, ~11 of' '. ' the pgaQB 8lfclei 1 , -. 9y p1ac&! the. button...&ge ;kanp1e Pre@erat;ao'n', md. "EgM jument -i'=q=, =';~=' . ' IX~, . ". '. :Keasurcdent . of 'Hes5stk~4y as a Pm'@Mon o5 ';" . -'2sinjsrshure. an/ BeitiiICs; ~. ' j -, ', '-'. v ~ . '- . ? t XTjfe. . . '?Df sonation. of Resnlt'8 ~ ~ ~ ' s ~ ', e...

Somoano, Robert Bonner

2012-06-07T23:59:59.000Z

125

ace iodine project: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Miu, Kevin (Kevin K.) 2006-01-01 210 Ainsi, grace au th eor eme 47, est satisfaisable ssi l'ensemble des abrres a branchement au plus d reconnus par Computer Technologies and...

126

CORRELATION OF FAILURE TIRES FOR IODINE SCC OF ZIRCALOY  

E-Print Network [OSTI]

D. Cllbiocciotti, & Jones, "EPRI - NASA Cooperative P:rojon Corrosion Cracking", EPRI NP-717 (1978). Cubiocciotti,R.L. Jones and Zircaloy", EPRI NP-1329 (19SO). C. Syrett, "

Shann, S.

2013-01-01T23:59:59.000Z

127

Radioactive Iodine and Krypton Control for Nuclear Fuel Reprocessing Facilities  

SciTech Connect (OSTI)

Nuclear fission results in the production of fission products and activation products, some of which tend to be volatile during used fuel reprocessing. These can evolve in volatile species in the reprocessing facility off-gas streams, depending on the separations and reprocessing technologies that are used. Radionuclides that have been identified as “volatile radionuclides” are noble gases (most notably isotopes of Kr and Xe); 3H; 14C; and 129I. Radionuclides that tend to form volatile species that evolve into reprocessing facility off-gas systems are more challenging to efficiently control compared to radionuclides that tend to stay in solid or liquid phases. Future used fuel reprocessing facilities in the United States can require efficient capture of some volatile radionuclides in their off-gas streams to meet regulatory emission requirements. In aqueous reprocessing, these radionuclides are most commonly expected to evolve into off-gas streams in tritiated water [3H2O (T2O) and 3HHO (THO)], radioactive CO2, noble gases, and gaseous HI, I2, or volatile organic iodides. The fate and speciation of these radionuclides from a non-aqueous fuel reprocessing facility is less well known at this time, but active investigations are in progress. An Off-Gas Sigma Team was formed in late FY 2009 to integrate and coordinate the Fuel Cycle Research and Development (FCR&D) activities directed towards the capture and sequestration of the these volatile radionuclides (Jubin 2012a). The Sigma Team concept was envisioned to bring together multidisciplinary teams from across the DOE complex that would work collaboratively to solve the technical challenges and to develop the scientific basis for the capture and immobilization technologies such that the sum of the efforts was greater than the individual parts. The Laboratories currently participating in this effort are Argonne National Laboratory (ANL), Idaho National Laboratory (INL), Oak Ridge National Laboratory (ORNL), Pacific Northwest National Laboratory (PNNL), and Sandia National Laboratories (SNL). This article focuses on control of volatile radionuclides that evolve during aqueous reprocessing of UNF. In particular, most of the work by the Off-gas Sigma Team has focused on the capture and sequestration of 129I and 85Kr, mainly because, as discussed below, control of 129I can require high efficiencies to meet regulatory requirements, and control of 85Kr using cryogenic processing, which has been the technology demonstrated and used commercially to date, can add considerable cost to a reprocessing facility.

Soelberg, Nicolas R. [Idaho National Laboratory, Idaho Falls, ID (United States); Garn, Troy [Idaho National Laboratory, Idaho Falls, ID (United States); Greenhalgh, Mitchell [Idaho National Laboratory, Idaho Falls, ID (United States); Law, Jack [Idaho National Laboratory, Idaho Falls, ID (United States); Jubin, Robert T. [Oak Ridge National Laboratory, Oak Ridge, TN (United States); Strachan, Denis M. [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Thallapally, Praveen K. [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

2013-07-22T23:59:59.000Z

128

The contribution of oceanic methyl iodide to stratospheric iodine  

E-Print Network [OSTI]

horizontal wind speed and vertical transport efficiency (speed Horizontal wind speed and vertical transport CH 3 Ivertical transport. Note that for these two days high www.atmos-chem-phys.net/13/11869/2013/ horizontal wind speeds

2013-01-01T23:59:59.000Z

129

Photoelectron spectroscopy of higher bromine and iodine oxide anions:  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administration the1 - September 2006 TheStevenAdministration AlbumCoulomb repulsion andElectron

130

Iodine-coordinated sulfide leads to an exceptionally stable ceramic  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmospheric Optical Depth7-1D: Vegetation ProposedUsingFunInfrared LandResponses toInvestigatingAdaptedInvestor Flows

131

Method for the simultaneous preparation of radon-211, xenon-125, xenon-123, astatine-211, iodine-125 and iodine-123  

DOE Patents [OSTI]

The invention relates to a practical method for commercially producing radiopharmaceutical activities and, more particularly, relates to a method for the preparation of about equal amount of Radon-211 (/sup 211/Rn) and Xenon-125 (/sup 125/Xe) including a one-step chemical procedure following an irradiation procedure in which a selected target of Thorium (/sup 232/Th) or Uranium (/sup 238/U) is irradiated. The disclosed method is also effective for the preparation in a one-step chemical procedure of substantially equal amounts of high purity /sup 123/I and /sup 211/At. In one preferred arrangement of the invention almost equal quantities of /sup 211/Rn and /sup 125/Xe are prepared using a onestep chemical procedure in which a suitably irradiated fertile target material, such as thorium-232 or uranium-238, is treated to extract those radionuclides from it. In the same one-step chemical procedure about equal quantities of /sup 211/At and /sup 123/I are prepared and stored for subsequent use. In a modified arrangement of the method of the invention, it is practiced to separate and store about equal amounts of only /sup 211/Rn and /sup 125/Xe, while preventing the extraction or storage of the radionuclides /sup 211/At and /sup 123/I.

Mirzadeh, S.; Lambrecht, R.M.

1985-07-01T23:59:59.000Z

132

E-Print Network 3.0 - a2 peroxidase expression Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

., Cereghino, G.P.L. & Gold, M.H. (1999) Homologous expression of recombinant lignin peroxidase... of bee venom phos- pholipase A2. Biochemistry 24, ... Source: Youngs,...

133

Synthesis and study of ligands for Pd-catalyzed C-O and C-N coupling  

E-Print Network [OSTI]

A new ligand, AdBrettPhos, was synthesized and its use, along with tBuBrettPhos, in C-O coupling reactions at low temperatures was investigated. Using Pd catalysts containing these ligands, electron-neutral aryl bromides ...

Davis, Nicole R. (Nicole Rose)

2009-01-01T23:59:59.000Z

134

Characterization of an iodine-based ionic liquid ion source and studies on ion fragmentation  

E-Print Network [OSTI]

Electrosprays are a well studied source of charged droplets and ions. A specific subclass is the ionic liquid ion source (ILIS), which produce ion beams from the electrostatically stressed meniscus of ionic liquids. ILIS ...

Fedkiw, Timothy Peter

2010-01-01T23:59:59.000Z

135

Resistivity of low percentage perylene to iodine complexes and their excess noise spectra  

E-Print Network [OSTI]

that pressed prlycrystalline samples and single crystals should yield the same activation energy. & However others have ~btained activation energies nf 1 to 1 . 5 ev i'nr single crystal s. 9 & 3 L511er reports a rapid droop in activation energy from 0. 7... 0. 60 0. 34 0. 13 0. 35 0. 24 Extrinsic 0, 034 0. 034 0. 056 0, 059 (oZ) 240 250 288 Int. 10 3 10 4 0. 2 50 0. 2 106 10 104 10 Table 1. Information Cbtained from Figures e through P, 16 decreasing the gap between them...

Caruthers, Jerald Wayne

1966-01-01T23:59:59.000Z

136

On the mobility and potential retention of iodine in the Callovovian-Oxfordian formation  

E-Print Network [OSTI]

manuscript, published in "Physics and Chemistry of the Earth Parts A/B/C 32 (2007) 539-551" DOI : 10.1016/j.pce organic matter of the sediment before and during deposition, and early diagenesis. At variance with total diffusion on similar rock materials have already shown that iodide does not behave like chloride

Paris-Sud XI, Université de

137

IODINE IN THE ENVIRONMENT REVISITED. AN EVALUATION OF THE CHEMICAL-AND PHYSICO CHEMICAL  

E-Print Network [OSTI]

107 years) has received considerable attention as a byproduct of nuclear energy production. 129 I released to the environment, e.g. by nuclear accidents may be accumulated in the thyroid gland

138

Volatility literature of chlorine, iodine, cesium, strontium, technetium, and rhenium; technetium and rhenium volatility testing  

SciTech Connect (OSTI)

A literature review pertaining to the volatilization of Sr, Cs, Tc (and its surrogate Re), Cl, I and other related species during the vitrification of Hanford Low Level Waste (LLW) streams has been performed and the relevant information summarized. For many of these species, the chemistry which occurs in solution prior to the waste stream entering the melter is important in dictating their loss at higher temperatures. In addition, the interactive effects between the species being lost was found to be important. A review of the chemistries of Tc and Re was also performed. It was suggested that Re would indeed act as an excellent surrogate for Tc in non-radioactive materials testing. Experimental results on Tc and Re loss from sodium aluminoborosilicate melts of temperatures ranging from 900--1350{degrees}C performed at PNL are reported and confirm that Re behaves in a nearly identical manner to that of technetium.

Langowski, M.H.; Darab, J.G.; Smith, P.A.

1996-03-01T23:59:59.000Z

139

Performance of a Multistream Injection Chemical OxygenIodine Laser with Starlet Ejectors  

E-Print Network [OSTI]

and has the potential for higher pressure recovery. Pressures in the singlet-oxygen generator were technology development to date has focused on the singlet-oxygen generator (SOG). The liquid SOG technology- oxygen generation and transport efficiency. The idea of the starlet nozzle concept stems originally from

Carroll, David L.

140

A Model of Radioiodine Transfer to Goat Milk Incorporating the Influence of Stable Iodine  

E-Print Network [OSTI]

nuclear accidents such as those at Windscale (1957) and Chernobyl (1986). An important route by which

Crout, Neil

Note: This page contains sample records for the topic "iodine phos phorus" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

Hyperfine predissociation in the B state of iodine investigated through lifetime measurements of individual hyperfine sublevels  

E-Print Network [OSTI]

. - The dynamics of molecular excited states is an important chapter of present-day molecular physics from the level under investigation following a pulsed excitation of this level. Our laser-excited

Boyer, Edmond

142

Relationship of the serum protein-bound iodine to rates of gain in beef cattle  

E-Print Network [OSTI]

to03 Go ?H -P CO HOI PQ Hto01 oto H O to rH O CD... tOO to02to o o Oi01to ?00101 ?01 to H rH 05 O 01 01 to rH tO rH O ? 00toe'? en 00 01*0001to 001 01 ao 05 01 !>?> tOa> 01lO #oto!> IDtoo 01* 00to rH 01 COo ? ID H oo> 0> 05 c?to GO Hto...

Stokes, David Kershaw

1956-01-01T23:59:59.000Z

143

Earth Planets Space, 54, 265273, 2002 Iodine isotope ratios and halide concentrations in fluids  

E-Print Network [OSTI]

is best preserved in the high-temperature fumaroles collected in 1998 and has a 129 I/I ratio of 756 ± 47 recent meteoric water from the fumarolic system after 1993. The acid hot springs on the flanks by mixing with old meteoric water and seawater. Fumarolic gases and hot spring waters were also analyzed

Fehn, Udo

144

Space-charge-limited current measurements in iodine crystals by pulse techniques  

E-Print Network [OSTI]

to x = d. using the con- ditions: ae E(0 ~ t) 0 Q t-0 pd b. ) E dx = V = constant 0 c. Q~(x, t) = 0 &x one obtains 2 ](d. t) = a~ E (d. t) 'Sw d Now at x = d, before the leading front of the carriers arrives, p(d. t) = 0 , t&ti so that Jc... = 0 at x = d for t ti (the transit time of the carriers). This implies that dE = 0 o t&ti 'bxx=d Therefore we see from E&Ls. (3) and (0) that hE(d, t) = 8E (d. , t) ~ t&ti st 2d (5) A solution to Eq. (5) is E=V 1 d ~oct with ~= 1 and. t = d...

Robinette, William Clayton

2012-06-07T23:59:59.000Z

145

Carrier envelope phase stabilization of a femtosecond laser and iodine spectroscopy  

E-Print Network [OSTI]

. In this context, the CW stability of the Ti:sapphire laser is discussed to provide a procedure for the femtosecond laser adjustments. In addition, the pulse trains emitted by the femtosecond laser are described analytically to provide a theoretical basis...

Zhu, Feng

2006-10-30T23:59:59.000Z

146

Interfacing the tandem mirror reactor to the sulfur-iodine process for hydrogen production  

SciTech Connect (OSTI)

The blanket is linked to the H/sub 2/SO/sub 4/ vaporization units and SO/sub 3/ decomposition reactor with either sodium or helium. The engineering and safety problems associated with these choices are discussed. This H/sub 2/SO/sub 4/ step uses about 90% of the TMR heat and is best close-coupled to the nuclear island. The rest of the process we propose to be driven by steam and does not require close-coupling. The sodium loop coupling seems to be preferable at this time. We can operate with a blanket around 1200 K and the SO/sub 3/ decomposer around 1050 K. This configuration offers double-barrier protection between Li-Na and the SO/sub 3/ process gases. Heat pipes offer an attractive alternate to provide an additional barrier, added modularity for increased reliability, and tritium concentration and isolation operations with very little thermal penalty.

Galloway, T.R.

1980-06-02T23:59:59.000Z

147

Capture of Solar and Higher-Energy Neutrinos by Iodine 127  

E-Print Network [OSTI]

We discuss and improve a recent treatment of the absorption of solar neutrinos by ${}^{127}$I, in connection with a proposed solar neutrino detector. With standard-solar-model fluxes and an in-medium value of -1.0 for the axial-vector coupling constant $g_A$, we obtain a ${}^8$B-neutrino cross section of 3.3$\\times 10^{-42}$, about 50\\% larger than in our previous work, and a ${}^7$Be cross section that is less certain but nevertheless also larger than before. We then apply the improved techniques to higher incoming energies that obtain at the LAMPF beam dump, where an experiment is underway to finalize a calibration of the ${}^{127}$I with electron neutrinos from muon decay. We find that forbidden operators, which play no role in solar-neutrino absorption, contribute nonnegligibly to the LAMPF cross section, and that the preliminary LAMPF mean value is significantly larger than our prediction.

J. Engel; S. Pittel; P. Vogel

1994-02-17T23:59:59.000Z

148

Impact of Foliar Fertilizer Containing Iodine on “Golden Delicious” Apple Trees  

E-Print Network [OSTI]

on marketable Golden Delicious/M.9 apple production. At thecontaining fertilizer on apple fruits firmness and theirold “Golden Delicious/M.9” apple trees Trees were spaced at

Szwonek, Eugeniusz

2009-01-01T23:59:59.000Z

149

Iodine in groundwater of the North China Plain: Spatial patterns and hydrogeochemical processes of enrichment  

E-Print Network [OSTI]

of enrichment Eryong Zhang a,b, , Yanyan Wang c , Yong Qian d , Teng Ma c , Dongxiao Zhang a , Hongbin Zhan e

Zhan, Hongbin

150

Resistivity measurements of iodine single crystals by an A.C. technique  

E-Print Network [OSTI]

are organic semi- conductors. Inokuchi and Akamatu and Garrett have investigated the electrical properties of several of these semiconductors and have also summarized the re- suits of much of the work that has been done on these materials up to 1961. Be... as the resistance increases, the accuracy is better than 10% in the resistance range of 10 ohms with a capacitance of 10 pF across the sample. If the capacitance is decreased by trimming the bridge before electrodes are con- nected to the sample to rule out all...

Intararithi, Thanom

1965-01-01T23:59:59.000Z

151

SciTech Connect: Assessment of Methods to Consolidate Iodine-Loaded  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administrationcontroller systems controllerAdditive ManufacturingSilver-Functionalized Silica

152

SciTech Connect: Efforts to Consolidate Chalcogels with Adsorbed Iodine  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear Security Administrationcontroller systems controllerAdditiveBetatronAerogelDistancesCaptureiron

153

Zeolite Salt Occlusion: A Potential Route for the Immobilisation of Iodine-129? Neil C. Hyatt,1*  

E-Print Network [OSTI]

in air, at 500o C, with the sodium forms of the zeolites leads to the formation of occlusion products, Sheffield, S1 3JD. UK. 2 School of Chemical Sciences, The University of Birmingham, Birmingham, B15 2TT. UK have been used to monitor the occlusion reaction at 400o C, and show that the occlusion product

Sheffield, University of

154

Iodine solubility in a low-activity waste borosilicate glass at 1000°C  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-SeriesFlickrinformation for and ApplicationNuclearLeaoInvestingsolubility in a

155

Iodine valence and local environments in borosilicate waste glasses using X-ray absorption spectroscopy  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr May JunDatastreamsmmcrcalgovInstrumentsruc DocumentationP-SeriesFlickrinformation for and ApplicationNuclearLeaoInvestingsolubility in

156

Tritium And Iodine Plumes on the U.S. Department of Energy Hanford Site  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched Ferromagnetism in Layered NbS2TopoPortalBRDF Effects in Satellite Retrieval ofMay

157

Tritium And Iodine Plumes on the U.S. Department of Energy Hanford Site  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE:1 First Use of Energy for All Purposes (Fuel and Nonfuel),Feet) Year Jan Feb Mar Apr MayAtmosphericNuclear SecurityTensile Strain Switched Ferromagnetism in Layered NbS2TopoPortalBRDF Effects in Satellite Retrieval

158

Direct vapor/solid synthesis of mercuric iodide using compounds of mercury and iodine  

SciTech Connect (OSTI)

A process is disclosed for producing high purity mercuric iodide by passing a gaseous source of a mercuric compound through a particulate bed of a low vapor pressure iodide compound which is maintained at an elevated temperature which is the lower of either: (a) just below the melting or volatilization temperature of the iodide compound (which ever is lower); or (b) just below the volatilization point of the other reaction product formed during the reaction; to cause the mercuric compound to react with the iodide compound to form mercuric iodide which then passes as a vapor out of the bed into a cooler condensation region.

Skinner, Nathan L. (Carpinteria, CA)

1990-01-01T23:59:59.000Z

159

BIOCHEMICAL AND BIOPHYSICAL RESEARCH COMMUNICATIONS 243, 664668 (1998) ARTICLE NO. RC988151  

E-Print Network [OSTI]

) particles from potato tuber. N-terminal se-between F1 and Fo and regulate energy coupling in quences characterised protein phos- Mitochondria were isolated and purified from potato tubers (Sola- phorylation

Allen, John F.

160

J. Sep. Sci. 2005, 28, 155162 www.jss-journal.de i 2005 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim OriginalPaper  

E-Print Network [OSTI]

[bis(pyridin-2-ylmethyl)amino]propan-2-olato dizinc(II) complex (Phos-tag), which is linked to a highly cross of pro- teins, such as phosphorylation, glycosylation, methyla- tion, and acetylation, dramatically

Lebendiker, Mario

Note: This page contains sample records for the topic "iodine phos phorus" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Novel 125 I production and recovery system  

E-Print Network [OSTI]

This research suggests ways of reducing contamination of iodine-126 in iodine-125 and lays out a simpler iodine-125 production technique to increase the yield. By using aluminum irradiation vessels the yield of iodine-125 produced by neutron...

Kar, Adwitiya

2009-05-15T23:59:59.000Z

162

Iodine Pathways and Off-Gas Stream Characteristics for Aqueous Reprocessing Plants – A Literature Survey and Assessment  

SciTech Connect (OSTI)

Used nuclear fuel is currently being reprocessed in only a few countries, notably France, England, Japan, and Russia. The need to control emissions of the gaseous radionuclides to the air during nuclear fuel reprocessing has already been reported for the entire plant. But since the gaseous radionuclides can partition to various different reprocessing off-gas streams, for example, from the head end, dissolver, vessel, cell, and melter, an understanding of each of these streams is critical. These off-gas streams have different flow rates and compositions and could have different gaseous radionuclide control requirements, depending on how the gaseous radionuclides partition. This report reviews the available literature to summarize specific engineering data on the flow rates, forms of the volatile radionuclides in off-gas streams, distributions of these radionuclides in these streams, and temperatures of these streams. This document contains an extensive bibliography of the information contained in the open literature.

R. T. Jubin; D. M. Strachan; N. R. Soelberg

2013-09-01T23:59:59.000Z

163

Urinary Metabolomic Analysis to Detect Changes After Intravenous, Non-ionic, Low Osmolar Iodinated Radiocontrast for Computerized Tomographic Imaging  

E-Print Network [OSTI]

Acad Radiol. after percutaneous coronary intervention and adialysis after percutaneous coronary intervention and theafter percutaneous coronary intervention: development and

Diercks, Deborah B; Owen, Kelly P; Tolstikov, Vladimir; Sutter, Mark E; Kline, Jeffrey A

2014-01-01T23:59:59.000Z

164

129 Iodine: A New Hydrologic Tracer for Aquifer Recharge Conditions Influenced by River Flow Rate and Evapotranspiration  

E-Print Network [OSTI]

analogy to chloride ? Long term database Chloride: Analogy for Iodide y = 5.27x -0.32 R 2 = 0.53 R = 0.73 0 1 2 3 4 5 6 0 20 40 60 80 100 120 SARPD Monthly Flow m 3 s -1 S ARP D [ C l - ] m e q / L Monthly values INSET: Annual median values.... GW y = 0.46x + 1.27 R 2 = 0.96 -2 -1 0 1 2 -3 -2 -1 0 log [Cl - GW ] or log [Cl - SARPD ] meq/L lo g [ C l - PP T ] m e q/ L ...

Schwehr, K. A.; Santschi, P. H.; Moran, J. E.

2003-01-01T23:59:59.000Z

165

The level of serum protein-bound iodine, its repeatability and relationship to rate of gain in immature beef cattle  

E-Print Network [OSTI]

H? sxdJx0 to increase .in. humans ?=xowx,fww et alG O 1948) and baboons (van Zyla 1957) o Ne differences were observed in the thyroid activity of pregnant and non-pregnant ewes ?Klwdlx and Turner 3 1946; Kenneman xt f'i w 1955). Wux results lm... ;ugsol'l$okf' 'xJx'si bfs Hx,f0 hl f ;dlhxow bohu fw x'xkhdl;uldxhok x y o ' o h g so,o'fd hl hufh lm hux k?3? fw0 $'lH*'ow mdfkholws ow u*,fw sxdf) 4uxw $dxfhxd 'xJx's bxdx f00x0i hux 'fHx'x0 hugdlyowx bfs Hl*w0 hl f sxklw0 mdfkholw bohu fw x...

Green, George G.

1958-01-01T23:59:59.000Z

166

Iodine-125-labeled lipoprotein lipase as a tool to detect and study spontaneous lipolysis in bovine milk  

SciTech Connect (OSTI)

The distribution of lipoprotein lipase among cream, casein, and milk serum can be evaluated by addition of a trace amount of /sup 125/I-labeled lipoprotein lipase to milk. Radioactive lipase was distributed in parallel to endogenous lipase under several conditions. In some milk samples, binding of lipase to cream increased when the milk was cooled. Correlation was good between bound labeled lipase and degree of cold-induced lipolysis in corresponding milk samples. Binding of lipase to cream or to casein was not saturable by addition of two-to threefold more lipase than is normally present in milk. In milk with a relatively high fraction of lipase bound to cream, a correspondingly lower fraction was associated with casein, whereas the fraction of lipase in milk serum was similar in all milk samples. Cold-induced binding of lipoprotein lipase to cream was not fully reversed when the milk was warmed again. Heparin released lipase from casein and increased the amount of lipase bound to cream after cooling.

Sundheim, G.; Bengtsson-Olivecrona, G.

1986-07-01T23:59:59.000Z

167

Absolute frequency measurement of the iodine-stabilized Ar+ at 514.6 nm using a femtosecond optical frequency comb.  

E-Print Network [OSTI]

Hz higher than the value of 582490603.38(15) MHz, adopted by the CIPM in 2003 [T.J. Quinn, Metrologia 40

Boyer, Edmond

168

Mesostructures DOI: 10.1002/anie.201310748  

E-Print Network [OSTI]

functionalized with organic groups that can form tight bonding to inorganic species. Such polymers were able analogues (AlPO4 and other related metal phos- phates with open frameworks), titanium dioxide (TiO2. The incorporation of mesoporosity into these materials has been an important issue for resolving the diffusion

Ihee, Hyotcherl

169

17. J. Haywood, The Penguin Historical Atlas of the Vi-kings (Penguin Books, London, 1995).  

E-Print Network [OSTI]

adenine dinucleotide phos- phate. Low micromolar concentrations of carbon monoxide inhibited the DNA binding activity of holo-NPAS2 but not that of apo-NPAS2. Upon exposure to carbon monoxide, inactive BMAL1 heme binding during the purification of NPAS2, a mammali- an bHLH (basic helix-loop-helix)­PAS tran

Rutter, Jared

170

Eos, Vol. 93, No. 41, 9 October 2012 2012. American Geophysical Union. All Rights Reserved.  

E-Print Network [OSTI]

Phos 2012, a conference dedicated to cutting-edge research on phosphorus, was held in the Centro Stefano was sponsored by Cen- tro Stefano Franscini, Swiss National Foun- dation, the U.S. National Science Founda- tion Tracers for a Better Understanding of the Phosphorus Cycle; Monte Verità, Switzerland, 24­29 June 2012 #12;

Paytan, Adina

171

REGULAR PAPER Modulation of the fluorescence yield in heliobacterial cells  

E-Print Network [OSTI]

. They are thought to use a light-driven cyclic electron transport pathway to pump protons, and thereby phos brief flashes is inversely correlated to the variable fluorescence. Using pump-probe spectros- copy), or conversion to heat. When photosynthetic systems are operating efficiently, photochemistry dominates

172

Cholesterol lowering by soya lecithins in the rat in vivo: stimulation of the hepa-  

E-Print Network [OSTI]

of HDL-cholesterol and increase of bile lipid secretion. E Poli-E Poli- chetti N Diaconescu L Malli I You) Gastroenterology 94, A621 ]. The implication of HDL-PC in the bile lipid secretion was also previously shown) containing only 25% pure phos- phatidylcholine (PC). Lecithin stimulates bile secretion [Rioux et al (1988

Paris-Sud XI, Université de

173

Occupancy and site distribution of europium in barium magnesium aluminate Eu Mossbauer spectroscopy  

E-Print Network [OSTI]

as a blue emitting phosphor in various lighting applications. The 4f6 5d4f7 transition of Eu2 Therefore improving the stability of BAM is one of the im- portant concerns for the lighting industries.2 for fluorescent lamps with a high color rendering index. In comparison to the red and green emitting phos- phors

Boolchand, Punit

174

A Lipid-modified Phosphoinositide-specific Phospholipase C (TcPI-PLC) Is Involved in Differentiation of Trypomastigotes to  

E-Print Network [OSTI]

A Lipid-modified Phosphoinositide-specific Phospholipase C (TcPI-PLC) Is Involved C (PI- PLC) is an important component of the inositol phos- phate/diacylglycerol signaling pathway. A newly discov- ered Trypanosoma cruzi PI-PLC (TcPI-PLC) is lipid modified in its N terminus, targeted

Singer, Randall

175

1150 IEEE JOURNAL OF QUANTUM ELECTRONICS, VOL. 39, NO. 9, SEPTEMBER 2003 Modeling of the ElectriCOIL System  

E-Print Network [OSTI]

) Traditionally, this pumping reaction is fed by a liquid chem- istry singlet oxygen generator (SOG). However discharge oxygen-iodine laser (ElectriCOIL) system. Results of those studies along with more recent Terms--Chemical oxygen-iodine laser, chemical oxygen- iodine laser (COIL), discharge oxygen-iodine laser

Carroll, David L.

176

DOE/RL-2010-89 Review Copy October 1, 2010  

E-Print Network [OSTI]

such as chromium, nitrate, carbon tetrachloride, tritium, iodine-129, and technetium-99 at concentrations above

Hubbard, Susan

177

Effects of Iodine Content in the Electrolyte on the Charge Transfer and Power Conversion Efficiency of Dye-Sensitized Solar Cells under  

E-Print Network [OSTI]

of Dye-Sensitized Solar Cells under Low Light Intensities Jo-Lin Lan, Tzu-Chien Wei,*, Shien-Ping Feng of dye-sensitized solar cells under lower light intensities. By analyzing the current-voltage behavior results in an exclusive application for indoor use. 1. INTRODUCTION Dye-sensitized solar cell (DSSC) has

Cao, Guozhong

178

Bromine and iodine chemistry in a global chemistry-climate model: description and evaluation of very short-lived oceanic sources  

E-Print Network [OSTI]

radiation flux at the surface and the dissolved organic carbon (DOC) con- centration over the ocean.

2012-01-01T23:59:59.000Z

179

Evaluation of ischemia and myocardial viability in patients with coronary artery disease (CAD) with iodine-123-labeled 15-(p-iodophenyl)-3-R,S-methylpentadecanoic acid (BMIPP)  

SciTech Connect (OSTI)

Twenty patients with coronary artery disease (CAD) controlled by coronary arteriography (CA) and biplane left ventricular cineventriculography (LVCV) were investigated with the 15- (p[I-123]iodophenyl)-3-R,S-methylpentadecanoic acid (BMIPP) fatty acid analogue. During maximal symptom limited exercise 5 mCi (200 MBq) of BMIPP were injected followed by two SPECT studies within three hours. After another 30 min, with the patient at rest a third SPECT was performed after reinjection of 3 mCi (100 MBq) BMIPP. Visual inspection of the short and long axis slices and quantitative comparison of the short axis slices of the tomograms were performed to grade BMIPP uptake and refill and detect turnover abnormalities. These were addressed either as scar or as ischemia and compared to CA and a graded score of regional wall motion by LVCV which provided values for sensitivity (SE) and specificity (SP) to detect CAD. Fifteen infarctions had corresponded clinical, angiographic and scintigraphic findings in 93%.

Kropp, J.; Joergens, M.; Glaenzer, K.P.; Luederitz, B.; Biersack, H.J. [Bonn Univ. (Germany); Knapp, F.F. Jr. [Oak Ridge National Lab., TN (United States)

1993-10-01T23:59:59.000Z

180

Study of the kinetics of the gas-phase, iodine catalyzed elimination of HBr from isobutylbromide: the tertiary C-H bond dissociation energy in isobutylbromide.  

E-Print Network [OSTI]

, (with the possible exception of the very electronegative F atom) unless the substituent can delocalize the odd electron such as with the vinyI substituent, i. e. the allyl radical. The stabi'Iization energy is defined as the difference between... of formation of the radical. f s indicated in section (II); the stabilization energy of bromine bridged radical by the delocalization of tne odd electron can be obtained by comparisior, with a localized free radical. Thus, the stabi11zat1on energy...

Jirustithipong, Pongsiri

2012-06-07T23:59:59.000Z

Note: This page contains sample records for the topic "iodine phos phorus" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Physical features of small disperse coal dust fraction transportation and structurization processes in iodine air filters of absorption type in ventilation systems at nuclear power plants  

E-Print Network [OSTI]

The research on the physical features of transportation and structurization processes by the air-dust aerosol in the granular filtering medium with the cylindrical coal adsorbent granules in an air filter of the adsorption type in the heating ventilation and cooling (HVAC) system at the nuclear power plant is completed. The physical origins of the coal dust masses distribution along the absorber with the granular filtering medium with the cylindrical coal granules during the air-dust aerosol intake process in the near the surface layer of absorber are researched. The quantitative technical characteristics of air filtering elements, which have to be considered during the optimization of air filters designs for the application in the ventilation systems at the nuclear power plants, are obtained.

Ledenyov, Oleg P; Poltinin, P Ya; Fedorova, L I

2012-01-01T23:59:59.000Z

182

Microchemical systems for singlet oxygen generation  

E-Print Network [OSTI]

Chemical Oxygen-Iodine Lasers (COIL) are a technology of interest for industrial and military audiences. COILs are flowing gas lasers where the gain medium of iodine atoms is collisionally pumped by singlet delta oxygen ...

Hill, Tyrone F. (Tyrone Frank), 1980-

2008-01-01T23:59:59.000Z

183

GSK-3? phosphorylation of functionally distinct tau isoforms has differential, but mild effects  

E-Print Network [OSTI]

with AD-tau, as determined by mass spectrometry, and phos- phorylation site-specific antibodies [11-14]. In vivo, treat- ment of transgenic mouse models of tau-induced neurodegeneration with lithium chloride, an inhibitor of GSK-3?, reduces both tau... (Perkin-Elmer, Boston, MA). Sam- ples were filtered and washed to remove unincorporated ?-32P, then counted in a liquid scintillation counter (Pack- ard 1600TR) [19]. Assay Kit (Cytoskeleton, Inc., Denver, CO) using the man- ufacturer's protocol. Varying...

Voss, Kellen; Gamblin, Truman Chris

2009-05-02T23:59:59.000Z

184

Water quality and urban runoff in selected canal communities along the Texas coast  

E-Print Network [OSTI]

at points along the canal. There are data included in this report on monthly canal water quality for the seven study areas. Samples were analyzed for coli- forms, nitrite, nitrate, Kjeldahl nitrogen (organic nitrogen), phos- phates, TOC, BOD , dissolved..., temperature and salinity profiles, and Rhodamine dye dis- placement. The purpose of this report is to evaluate the sources of pollu- tional loading within the study communities . These data along with information from the literature on coastal canals...

Messenger, Allen Lester

1979-01-01T23:59:59.000Z

185

The interaction of nitrogen and magnesium deficiences in certain aspects of the physiology of the cotton plant  

E-Print Network [OSTI]

effective in raising the phos- phorous content of peas. Their results support the theory that magnesium functions as a carrier of phosphorous. They also point out the need of giving more attention to the magnesium status of agricultural soils with a view... and magnesium deficiencies occurring in the same plant as developed under the experimental conditions stated above. Oftentimes poor growth of plants in the field may result from the lack of two or mox'e nutrients and such simultaneous characterization...

Ghosh, Debabrata

2012-06-07T23:59:59.000Z

186

Organic Phosphoric Acid of the Soil.  

E-Print Network [OSTI]

TEXAS AGRICULTURAL EXPERIMENT STATIONS BULLETIN NO. +6CT /36 CHEMICAL SECTION, FEBRUARY, 191 1 I TECHNICAL BULLETIN Organic Phosphoric Acid of the Soil BY G. S. FRAPS, Chemist POSTOFFICE College Station, Brazos County, 'Texas. ,\\ustin... . ................................................ introduction 5 .............................. hmmonia-Soluble Phosphoric Acid 5 ................ Solubility of Phosphates in Ammonia 6 I Fixation of Phosphoric Acid from Ammonia .......... 7 Effect of Ratio of Soil to Solvent in Extraction of Phos- I I...

Fraps, G. S. (George Stronach)

1911-01-01T23:59:59.000Z

187

Lait (1994) 74, 325-332 Elsevier/INRA  

E-Print Network [OSTI]

was to study p-casein solubilization from native phos- phocaseinate in the conditions of cold storage.0 and 1.6 g/kg) before pH adjustment (4.0, 4.6 and 5.2) followed by cold storage (O°C). The amount did not have a marked effect. native phosphocaseinate II3-casein 1solubilization 1cold storage Résumé

Boyer, Edmond

188

Energy (Cost) Savings by Zero Discharge in Cooling Towers  

E-Print Network [OSTI]

. Relatively clean water may be added directly to the cooling tower basin (see Figure n. Reuse streams containing high suspended solids but of otherwise acceptable quality may be input just before the filters ~n the J The remainingireuse The flowrate..., silica, phos phates, and suspended solids. Other potential foulants and scale-forming species must be controlled by inhibitors or removed by an additional process in the sidestream treatment. Waste streams with scaling and corrosion potential before...

Matson, J. V.; Gardiner, W. M.; Harris, T. G.; Puckorius, P. R.

1982-01-01T23:59:59.000Z

189

Looking before we leap: an ongoing, quantative investigation of asteroid and comet impact hazard mitigation  

SciTech Connect (OSTI)

There are many outstanding questions about the correct response to an asteroid or comet impact threat on Earth. Nuclear munitions are currently thought to be the most efficient method of delivering an impact-preventing impulse to a potentially hazardous object (PHO). However, there are major uncertainties about the response of PHOs to a nuclear burst, and the most appropriate ways to use nuclear munitions for hazard mitigation.

Plesko, Catherine S [Los Alamos National Laboratory; Weaver, Robert P [Los Alamos National Laboratory; Bradley, Paul A [Los Alamos National Laboratory; Huebner, Walter F [Los Alamos National Laboratory

2010-01-01T23:59:59.000Z

190

A Chemical and Microbiological Study of Lufkin Fine Sandy Loam in Relation to Productiveness.  

E-Print Network [OSTI]

and significantly correlated with the yields of cotton and corn. The nitrifying capacity of the soil was a better index of the crop-producing power of the soil than the total nitrogen, the total phosphoric acid, or the active phos- phoric acid of the soil.... The addition of nitrogenous materials, cottonseed meal and manure, and of phosphoric acid, as superphosphate and ground rock phosphate, stimulated the nitrifying power of the soil and increased the production of nitrates in field soil. Under conditions...

Reynolds, E. B. (Elbert Brunner)

1931-01-01T23:59:59.000Z

191

invited Paper CommercialApplications for COIL  

E-Print Network [OSTI]

oxygen-iodine laser (COIL), the University of Illinois at Urbana-Champaign (UIUC)/STI Optronics team

Carroll, David L.

192

E-Print Network 3.0 - aqueous potassium hypochlorite Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

activated carbons Iodine acetylene, ammonia, hydrogen Mercury sulfuric... Potassium carbon tetrachloride, carbon dioxide, water Potassium chlorate sulfuric and other ......

193

I/I ratios and halogen concentrations in pore waters of the Hydrate Ridge: Relevance for the origin of gas hydrates in ODP Leg 204  

E-Print Network [OSTI]

in fluids associated with hydrocarbons, such as oil field brines (Moran et al., 1995) or coal-bed methane association of iodine with methane allows the identification of the organic source material responsible for iodine and methane in gas hydrates. In all cores, iodine concentrations were found to increase strongly

Fehn, Udo

194

Proceedings of the XIII International Symposium on Gas Flow and Chemical Lasers and High Power Laser Conference, Florence, Italy 18-22 September 2000, The Int. Soc. for Opt. Eng. Vol. 4184, P.O. Box 10, Bellingham, WA 98227-0010, pp. 40-44.  

E-Print Network [OSTI]

, electrical singlet oxygen generation, iodine dissociation. 1. INTRODUCTION Several dramatic changes to gain generator technologies are needed to allow chemical oxygen-iodine laser (COIL) systems to achieve their full improvements in generation of excited states of both oxygen and iodine. The development of gas phase O2(1 D

Carroll, David L.

195

*cuaerospace@cuaerospace.com; phone 217-333-8274; fax 217-244-7757; http://cuaerospace.com; CU Aerospace, 2004 S. Wright St. Ext., Urbana, IL, 61801; **wsolomon@uiuc.edu; phone 217-244-7646; fax 217-244-0720; http://www.aae.uiuc.edu;  

E-Print Network [OSTI]

chemistry singlet oxygen generator (SOG). However, the logistic issues of dealing with the liquid SOG Work on the Development of an Electric Discharge Oxygen Iodine Laser D. L. Carroll*a , J. T. Verdeyen discharge oxygen-iodine laser (ElectriCOIL) system in conjunction with injection of pre-dissociated iodine

Carroll, David L.

196

Proceedings of the Gas and Chemical Lasers and Intense Beam Applications III Conference, San Jose, California 22-24 January 2002, The Int. Soc. for Opt. Eng. Vol. 4631, P.O. Box 10, Bellingham, WA 98227-0010, pp. 154-160.  

E-Print Network [OSTI]

by a liquid chemistry singlet oxygen generator (SOG). Workers at CUA and UIUC are now addressing. Keywords: chemical oxygen-iodine laser, COIL, ElectriCOIL, RF excitation of oxygen, singlet-delta oxygen 1 oxygen-iodine laser (COIL) [McDermott, 1978] operates on the electronic transition of the iodine atom

Carroll, David L.

197

Nordisk kernesikkerhedsforskning Norrnar kjarnryggisrannsknir  

E-Print Network [OSTI]

. Key words Iodine, nuclear safety, severe accident, containment, ozone NKS-204 ISBN 978 identification code Iodine, nuclear safety, severe accident, containment, ozone Summary The behaviour of iodine ydinturvallisuustutkimus Nordisk kjernesikkerhetsforskning Nordisk kärnsäkerhetsforskning Nordic nuclear safety research

198

Natural Organic Matter (NOM) in Aquatic Systems: Interactions with Radionuclides (234Th (IV), 129 I) and Biofilms  

E-Print Network [OSTI]

in natural waters. At the F-area of the Savannah River Site (SRS), iodine species in the groundwater consisted of 48.8 percent iodide, 27.3 percent iodate and 23.9 percent organo-iodine. Each of these iodine species exhibited vastly different transport...

Zhang, Saijin

2011-10-21T23:59:59.000Z

199

United States Office of Air and Radiation EPA 402-R-04-002C Environmental Protection Agency July 2004  

E-Print Network [OSTI]

and Available Kd Values for Americium, Arsenic, Curium, Iodine, Neptunium, Radium, and Technetium #12;i and Available Kd Values for Americium, Arsenic, Curium, Iodine, Neptunium, Radium, and Technetium July 2004: americium, arsenic, curium, iodine, neptunium, radium, and technetium. This three-volume report also

200

Proceedings of the International Conference on Lasers '98, ed. V.J. Corcoran, STS Press, McLean VA, 1999, in press. PERFORMANCE OF A HIGH POWER CHEMICAL OXYGEN-IODINE LASER  

E-Print Network [OSTI]

, IL 61801 C.H. Fisher STI Optronics, 2755 Northup Way Bellevue, WA 98004-1495 Abstract The Verti-Champaign (UIUC)/STI Optronics team identified the decommissioning and decontamination (D&D) of nuclear facilities

Carroll, David L.

Note: This page contains sample records for the topic "iodine phos phorus" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Further evaluation of dose estimation using the FBX dosimeter  

E-Print Network [OSTI]

offset and general discrep- ancy between the expected dose and the one measured by the FBX dosimeter. To determine the origin of these anomalies, the dosimeter was used in intimate mixtures with tritiated water, HTO, iodine crystals, and various dilute... iodine solutions. When mixed with HTO, the doses measured by the FBX solution were in better agree- ment with the doses predicted by MIRD techniques than the measurements with I. In 131 subsequent mixtures with stable iodine crystals, the dosimeter...

Helfinstine, Suzanne Yvette

1988-01-01T23:59:59.000Z

202

Calling on a million minds for community annotation in WikiProteins  

E-Print Network [OSTI]

search engine be case insensitive and find CLB2 based on the query term Clb2, but in a wider context, case insensitivity leads to aggravation of the ambiguity prob- lem. For example, in PubMed, the query 'Clb2' delivers papers on dental self... '. Furthermore, the authors of this abstract have used several constructs that make text mining difficult as they enter conjugate terms such as 'mitotic cyclin (Clb2)-bound Cdc28 (Cdk1 homolog)', 'Clb2-Cdc28', 'Clb2-Cdc28-phos- phorylated Swe1', 'Cdc28/Cdk1...

Mons, Barend; Ashburner, Michael; Chichester, Christine; van Mulligen, Erik; Weeber, Marc; den Dunnen, Johan T; Musen, Marc; Cockerill, Matthew; Hermjakob, Henning; Packer, Abel; Pacheco, Roberto; Lewis, Suzanna; Berkeley, Alfred; Melton, William; Barris, Nickolas; Borner, Katy; Meijssen, Gerard; Moeller, Erik; Roes, Peter Jan; Mons, Albert; van Ommen, Gert; Wales, Jimmy; Bairoch, Amos

2008-05-28T23:59:59.000Z

203

The effects of various long term fertility treatments on the phosphorus status of three Texas Vertisols  

E-Print Network [OSTI]

in the Houston Black clay, Furthermore, the data obtained show that regardless of the rate of P20~ applied, added phos- phates accumulated in the calcium, reductant-soluble, aluminum and dicalcium fractions in an approximate 2$". 0". 2. "I ratio. In the San... Saba clay, applied P was converted pri- marily to Che aluminum and reductant- soluble forms. Pertllizatlon wiCh N or N, P tended to decrease Che eel= cium phosphate levels even though Che soil is still dis- tinctly calcareous. Percentagewise...

Supak, James Raymond

1969-01-01T23:59:59.000Z

204

Commercial Fertilizers and Poisonous Insecticides in 1906-7.  

E-Print Network [OSTI]

used in Texas is comparatively small. The amount is increasing and may be expected to increase yearly. The quantity sold in Texas in 1905-06 was 13,500 tons. In 1906-07 it was 19,200 tons, this being an increase of 42 per cent. This does not in... to the soil in such forms that the plant can take it up easily. It thus supplements the avail- able plant food of the soil and increases the crop if the soil does not provide enough plant food. The essential constituents of a fertilizer are phos- phoric...

Fraps, G. S. (George Stronach)

1907-01-01T23:59:59.000Z

205

E-Print Network 3.0 - age-dependent radium retention Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Protection Agency July 2004 Summary: and Available Kd Values for Americium, Arsenic, Curium, Iodine, Neptunium, Radium, and Technetium 12;i... and Available Kd Values for...

206

Biofortifying Brassica with calcium (Ca) and magnesium (Mg)  

E-Print Network [OSTI]

zinc, copper, calcium, magnesium, selenium and iodine. NewE. 2008. Role of dietary magnesium in cardiovascular diseaseShoot calcium (Ca) and magnesium (Mg) concentrations differ

2009-01-01T23:59:59.000Z

207

alejados del implante: Topics by E-print Network  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Purpose: Permanent prostate brachytherapy (PPB) as a treatment option for prostate cancer requires implantation of 80-150 radioactive iodine-125 (I-125) "seeds" into the...

208

Analytical Data Report of Water Samples Collected For I-129 Analysis  

SciTech Connect (OSTI)

This is an analytical data report for samples received from the central plateau contractor. The samples were analyzed for iodine-129.

Lindberg, Michael J.

2009-10-26T23:59:59.000Z

209

For permission to copy or to republish, contact the copyright owner named on the first page. For AIAA-held copyright, write to AIAA Permissions Department,  

E-Print Network [OSTI]

by a liquid chemistry singlet oxygen generator (SOG). * Engineering Director, CU Aerospace, Senior Member AIAA) may be produced in an electrical discharge that may permit lasing of an electric discharge oxygen oxygen-iodine laser (COIL) [McDermott, 1978] operates on the electronic transition of the iodine atom

Carroll, David L.

210

JOURNAL DE PHYSIQUE IV Colloque C7, suppldment au Journal de Physique 111,Vol. 1, dkembre 1991  

E-Print Network [OSTI]

SOMEFEATURES OF THE KINETICS OF OXYGEN-IODINELASER WITH PHOTOLYTICAL SINGLETOXYGEN GENERATION M.P. FROLOV, Yu of the kinetics of the pulsed oxygen-iodine laser with photolytic source of singlet oxygen are presented influence of oxygen atoms on molecular iodine dissociation and energy store relaxation is observed

Paris-Sud XI, Université de

211

wsolomon@uiuc.edu; phone 1-217-244-7646; fax 1-217-244-0720; http://www.aae.uiuc.edu; Univ. of Illinois, 306 Talbot Lab, 104 S. Wright St., Urbana, IL 61801.  

E-Print Network [OSTI]

(1 ) is produced by a liquid chemistry singlet oxygen generator (SOG). However, the difficulties of employing oscillation of a chemical oxygen-iodine laser system in conjunction with injection of pre-dissociated iodine. Results of those studies along with recent experimental results indicate that generation of O2(1 ) can

Carroll, David L.

212

For permission to copy or to republish, contact the copyright owner named on the first page. For AIAA-held copyright, write to AIAA Permissions Department,  

E-Print Network [OSTI]

oxygen generator (SOG). However, the logistic issues of dealing with the liquid SOG * Engineering oxygen-iodine laser (COIL) [McDermott, 1978] operates on the electronic transition of the iodine atom electric generation scheme to provide the precursor energy donor species O2(1 D) and that an electrically

Carroll, David L.

213

IEEE JOURNAL OF QUANTUM ELECTRONICS, VOL. 41, NO. 10, OCTOBER 2005 1309 Studies of CW Laser Oscillation on the 1315-nm  

E-Print Network [OSTI]

is produced by a liquid chemistry singlet oxygen generator (SOG). There are many system issues having to do composed of two 99.995% reflective mirrors. Index Terms--Chemical oxygen­iodine laser (COIL), electric discharge oxygen­iodine laser, electriCOIL, radio frequency (RF) excitation of oxygen, singlet-delta oxygen

Carroll, David L.

214

wsolomon@uiuc.edu; phone 1-217-244-7646; fax 1-217-244-0720; http://www.aae.uiuc.edu; Univ. of Illinois, 306 Talbot Lab, 104 S. Wright St., Urbana, IL 61801.  

E-Print Network [OSTI]

oxygen generator (SOG). However, the difficult issues involving liquid SOG systems motivated permit lasing of an electric discharge oxygen-iodine laser (ElectriCOIL) system, possibly in conjunctionCOIL, COIL, chemical oxygen iodine laser, electric discharge modeling 1. INTRODUCTION The classic chemical

Carroll, David L.

215

JOURNALDE PHYSIQUEIV ColloqueC7, suppl6ment au Journal de Physique 111,Vol. 1, dhmbre 1991  

E-Print Network [OSTI]

system (figure I)consists o f a bubble column singlet oxygen generator, a water vapor cold trap are being conducted on a high power chemical oxygen iodine laser. Optical diagnostics were developed t o power o f at least one kilowatt i s expected. 1 - Introduction The chemical oxygen iodine laser (COIL

Boyer, Edmond

216

Volume 170, number 5,6 CHEMICAL PHYSICS LETTERS 20 July 1990 Nature of the red emission  

E-Print Network [OSTI]

in the chemical oxygen iodine laser system Ruiping Huang `, Rong Zhang ' and Richard N. Zare Deparfmenfof at 703 nm is observed when a heated metal wire is placed downstream of an O,( `A& generator used in the chemical oxygen iodine laser (COIL) system. The O2(`4) isproduced by bubbling Cl, through an alkaline

Zare, Richard N.

217

AIAA Plasmadynamics and Lasers Conference 5-8 June 2006, San Francisco, California  

E-Print Network [OSTI]

chemical singlet oxygen generator (SOG) with an electrically excited all gas phase system.3,4 Other to improvements in the hybrid Electric Oxygen-Iodine Laser (ElectricOIL) system that significantly increased system parameters. I. Introduction The classical chemical oxygen iodine laser (COIL) system1 employs

Carroll, David L.

218

Modeling of a Multi-Stream Injection COIL with Enhanced Mixing Ejectors  

E-Print Network [OSTI]

- oxygen generator (SOG). The liquid SOG technology has developed to a fairly mature state. However, much-pressure chemical oxygen- iodine laser (COIL) have been experimentally tested. To obtain a better understanding The chemical oxygen-iodine laser (COIL) was first demonstrated in 1978 [McDermott, 1978]. Since that initial

Carroll, David L.

219

Investigation of the Production of O2(a1 ) in Rectangular  

E-Print Network [OSTI]

is not simply a flow consisting primarily of O2(a) and O2(X) (as in classic COIL singlet-oxygen generation Oxygen- Iodine Laser (ElectricOIL) system. This continuous wave (cw) laser operating on the 1315 nm-section and multi-circular tube discharges. I. Introduction The electrically driven oxygen-iodine laser (Electric

Carroll, David L.

220

"Thyroid Disorders" Deaf Health Talks  

E-Print Network [OSTI]

gland to function and make thyroid hormones Naturally occurs in soil and ocean 40% of people in world on the thyroid C. Radiation exposure D. Lack of iodine E. Alien snatching our thyroid glands #12;What is the most itself on the thyroid C. Radiation exposure D. Lack of iodine E. Alien snatching our thyroid glands #12

Goldman, Steven A.

Note: This page contains sample records for the topic "iodine phos phorus" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

United States Environmental Protection Agency Office of Radiation and Indoor Air (6608J) PAG Manual Fact Sheet | April 2013 Page 1 http://www.epa.gov/radiation/rert/pags.html  

E-Print Network [OSTI]

://www.epa.gov/radiation/rert/pags.html · Food Guidance: Planners are referred to current guidance on radioactive contamination in food from of a potassium iodide (KI), a compound that inhibits the thyroid's uptake of radioactive iodine taken radioactive iodine; it does not provide protection against other radioactive substances.) · Guidance

222

Supporting Information Available. Supplementary Figure 1: PEG-Nanorod Synthesis and Stability In Vitro. A) The plasmon resonance of  

E-Print Network [OSTI]

. Notably, iodine reagents lack absorbance in the near- infrared that could allow remote photothermal heating. B) Photothermal heating comparison between PEG-Nanorods, iodine, and saline monitored using Modeling of Photothermal Tumor Heating. A) X-ray CT image of PEG-Nanorod distribution in tumor B) A 3D

Bhatia, Sangeeta

223

MODELLING RADIOIODINE DYNAMICS Modelling the Dynamics of Radioiodine in Dairy Cows  

E-Print Network [OSTI]

Department of Physiology & Environmental Science University of Nottingham Sutton Bonington LE12 5RD UK G for significant fecal excretion of radioiodine. The5 model is used to consider the effect of dietary stable iodine of iodine, in particular I-131, are important components in fallout from2 nuclear accidents

Crout, Neil

224

Transmutation of {sup 129}I Using an Accelerator-Driven System  

SciTech Connect (OSTI)

A conceptual blanket design for {sup 129}I transmutation is proposed for an accelerator-driven system (ADS) that is designed to transmute minor actinides (MAs). In this ADS, 250 kg/yr of MA and 56 kg/yr of iodine are simultaneously transmuted, and they correspond to the quantities generated from {approx}10 units of existing light water reactors. Furthermore, an introduction scenario and the benefit of iodine transmutation are studied for future introduction of fast breeder reactors. It is shown that the transmutation of iodine benefits the concept of underground disposal.

Nishihara, Kenji; Takano, Hideki [Japan Atomic Energy Research Institute (Japan)

2002-01-15T23:59:59.000Z

225

Study of the neutral mesons in Pb-Pb collisions at $\\sqrt{s_{NN}}$ = 2.76 TeV in the ALICE experiment at LHC  

E-Print Network [OSTI]

The $\\pi^{0}$ and $\\eta$ meson production in Pb-Pb collisions at $\\sqrt{s_{NN}}$ = 2.76 TeV is studied with the ALICE experiment at the LHC. The $\\pi^{0}$ invariant yields and nuclear modification factor $R_{\\mbox{AA}}$ are presented here in six centrality classes. The results are a combined measurement using the Photon Conversion Method (PCM) and the PHOS detector, in the transverse momentum range 0.4 $< p_{\\mbox{T}} <$ 12 GeV/$c$. The $\\pi^{0}$ $R_{\\mbox{AA}}$ is studied in different centrality classes and compared with results from experiments at lower energies, both as a function of transverse momentum. The $\\eta$ meson production is studied using the PCM and the EMCal detector. The combination of the individual results will make possible the measurement of the $\\eta$ differential invariant cross section as a function of transverse momentum from 1 to 22 GeV/$c$ in different centrality classes.

Lucia Leardini; for the ALICE Collaboration

2014-12-05T23:59:59.000Z

226

Graphical Abstract 1) base prepared from  

E-Print Network [OSTI]

_____________________________________________ Synthesis of C,N'-linked bis-heterocycles using a deprotometalation-iodination-N-arylation sequence of benzoxazole (10% less). The crude iodides were involved in the N-arylation of pyrrole, indole, carbazole

Paris-Sud XI, Université de

227

I-XE ANALYSES OF TAGISH LAKE MAGNETITE AND MONAHANS HALITE. A. Busfield1 , J. D. Gil-  

E-Print Network [OSTI]

- leases were dominated by iodine-derived xenon (129 Xe/132 Xe > 10 consistently). This sample produced of solar sys- tem history. Acknowledgements: We are grateful to R. Wieler for providing the halite grain

Grossman, Lawrence

228

!""#$%&'()*+,-#.',&"*/'-0*12!*,"*-0#*34'5#* 6,(,5'*7&#'$,(**  

E-Print Network [OSTI]

-'-F*@$ O O OH PO NC ABz O O O O O GiBu O O O ODMT P NONC T tetrazole then iodine O O O PO NC ABz O O O O O

Barthelat, Francois

229

HYDROLOGY AND EROSION IMPACTS OF MINING DERIVED COASTAL SAND DUNES, C H ~ A R A LBAY, CHILE  

E-Print Network [OSTI]

HYDROLOGY AND EROSION IMPACTS OF MINING DERIVED COASTAL SAND DUNES, C H ~ A R A LBAY, CHILE Daniel, nitrates, iodine, and lithium. Some of the gold and silverandallofthemolybdenumareproducedasby- products

230

CX-010652: Categorical Exclusion Determination  

Broader source: Energy.gov [DOE]

Technetium and Iodine Removal Studies with SuperLig Resin CX(s) Applied: B3.6 Date: 06/26/2013 Location(s): South Carolina Offices(s): Savannah River Operations Office

231

Initial Assessment of the Consolidation of Chalcogels into a Viable Waste Form  

SciTech Connect (OSTI)

This report provides some preliminary data for the consolidation of chalcogen-based aerogels. The chalcogels tested to date at PNNL show great promise as iodine sorbents and preliminary consolidation research shows that they can be melted into a phase-pure glass at moderate temperatures. The preliminary consolidation experiments show that these materials might attack fused quartz so an alternative crucible material will likely need to be used to prevent this. The next steps will be to • Consider melting other chalcogel chemistries, e.g., Sn-Sb-S, Ge-Sn-S chalcogels • Consider melting chalcogels with adsorbed iodine to monitor iodine loss during melting • Optimize the consolidation temperatures to minimize the iodine loss and volatilization

Riley, Brian J.; Lepry, William C.

2012-08-31T23:59:59.000Z

232

Combinatorial design and synthesis of peptidomimics and small molecules for protein-protein interactions  

E-Print Network [OSTI]

pharmacophores and to adjust the solubilities of the products. The fluorinated template also gave libraries of cyclic peptidomimetics on solid phase in good yields and purities. These libraries have improved water solubility over the iodinated libraries. The 3...

Park, Chihyo

2007-04-25T23:59:59.000Z

233

Depletion, quantum jumps, and temperature measurements of ??Sr? ions in a linear Paul Trap  

E-Print Network [OSTI]

This thesis describes the design and construction of two laser systems to probe the 674nm transition of ??Sr? ions in a linear Paul trap. The first laser system made use of a molecular transition in Iodine to stabilize the ...

Richerme, Philip J

2006-01-01T23:59:59.000Z

234

Phorochrriii\\rn. und Phofuhiologr. Vol. 29. pp. 439-444. Pergamon Press Ltd. 1979. Printed in Great Britain  

E-Print Network [OSTI]

of the spectroscopy of iodine. nitrogen dioxide, s-tetrazine and various van der Waals molecular complexes molecule like s-tetrazine is effectively "frozen" out giving one of the few highly resolved gas phase

Govindjee

235

PROGRAM & ABSTRACTS 13. DANSKE HAVFORSKERMDE  

E-Print Network [OSTI]

Department, DK-4000 Roskilde 129 I (15.7 Ma) is a naturally occurring radioisotope of iodine. The ratio as A Oceanographic Tracer Xiaolin Hou, H. Dahlgaard, S.P. Nielsen Risø National Laboratory, Radiation Research

236

Centers for Disease Control and Prevention National Center for Environmental Health  

E-Print Network [OSTI]

, Idaho and Oregon; the scientific and academic communities; and the media. This communications plan............................................................................. 18 National Scientific and Academic Communities 12 years of scientific research on the human health effects of iodine-131 released in the 1940s

237

Examination of offsite radiological emergency protective measures for nuclear reactor accidents involving core melt  

E-Print Network [OSTI]

Evacuation, sheltering followed by population relocation, and iodine prophylaxis are evaluated as offsite public protective measures in response to nuclear reactor accidents involving core-melt. Evaluations were conducted ...

Aldrich, David C.

1979-01-01T23:59:59.000Z

238

Laser development for laser fusion applications. Research progress report, October 1978-September 1979  

SciTech Connect (OSTI)

During this report period, emphasis has been directed toward the advanced development of the HF, KrF, Se(/sup 1/S)-Se(/sup 3/P), and the chemically pumped iodine laser systems.

Not Available

1980-05-01T23:59:59.000Z

239

Assessing beef hide interventions as a means to reduce carcass contamination  

E-Print Network [OSTI]

following a water wash. Treatments (distilled water, isopropyl alcohol, 3% hydrogen peroxide, 2% L-lactic acid, 1% cetylpyridinium chloride (CPC), and 10% Povidone-iodine) then were applied to each section and sampled for aerobic plate counts (APCs...

Baird, Bridget Elaine

2007-04-25T23:59:59.000Z

240

For Immediate release: 04/12/12 Contact: Ingrid Wright  

E-Print Network [OSTI]

. Hydrogen generators can serve as effective hydrogen storage systems for fuel cells and other applications, hydrogen, and iodine-containing gas species. Oxygen generators can produce more oxygen, show higher

Ward, Karen

Note: This page contains sample records for the topic "iodine phos phorus" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

Task-based strategy for optimized contrast enhanced breast imaging: Analysis of six imaging techniques for mammography and tomosynthesis  

SciTech Connect (OSTI)

Purpose: The use of contrast agents in breast imaging has the capability of enhancing nodule detectability and providing physiological information. Accordingly, there has been a growing trend toward using iodine as a contrast medium in digital mammography (DM) and digital breast tomosynthesis (DBT). Widespread use raises concerns about the best way to use iodine in DM and DBT, and thus a comparison is necessary to evaluate typical iodine-enhanced imaging methods. This study used a task-based observer model to determine the optimal imaging approach by analyzing six imaging paradigms in terms of their ability to resolve iodine at a given dose: unsubtracted mammography and tomosynthesis, temporal subtraction mammography and tomosynthesis, and dual energy subtraction mammography and tomosynthesis. Methods: Imaging performance was characterized using a detectability index d{sup ?}, derived from the system task transfer function (TTF), an imaging task, iodine signal difference, and the noise power spectrum (NPS). The task modeled a 10 mm diameter lesion containing iodine concentrations between 2.1 mg/cc and 8.6 mg/cc. TTF was obtained using an edge phantom, and the NPS was measured over several exposure levels, energies, and target-filter combinations. Using a structured CIRS phantom, d{sup ?} was generated as a function of dose and iodine concentration. Results: For all iodine concentrations and dose, temporal subtraction techniques for mammography and tomosynthesis yielded the highest d{sup ?}, while dual energy techniques for both modalities demonstrated the next best performance. Unsubtracted imaging resulted in the lowest d{sup ?} values for both modalities, with unsubtracted mammography performing the worst out of all six paradigms. Conclusions: At any dose, temporal subtraction imaging provides the greatest detectability, with temporally subtracted DBT performing the highest. The authors attribute the successful performance to excellent cancellation of inplane structures and improved signal difference in the lesion.

Ikejimba, Lynda C., E-mail: lci@duke.edu [Medical Physics Graduate Program, Duke University, Durham, North Carolina 27705 and Carl E. Ravin Advanced Imaging Laboratories, Department of Radiology, Duke University Medical Center, Durham, North Carolina 27705 (United States); Kiarashi, Nooshin [Carl E. Ravin Advanced Imaging Laboratories, Department of Radiology, Duke University Medical Center, Durham, North Carolina 27705 and Department of Electrical and Computer Engineering, Duke University, Durham, North Carolina 27705 (United States)] [Carl E. Ravin Advanced Imaging Laboratories, Department of Radiology, Duke University Medical Center, Durham, North Carolina 27705 and Department of Electrical and Computer Engineering, Duke University, Durham, North Carolina 27705 (United States); Ghate, Sujata V. [Carl E. Ravin Advanced Imaging Laboratories, Department of Radiology, Duke University Medical Center, Durham, North Carolina 27705 (United States)] [Carl E. Ravin Advanced Imaging Laboratories, Department of Radiology, Duke University Medical Center, Durham, North Carolina 27705 (United States); Samei, Ehsan [Medical Physics Graduate Program, Duke University, Durham, North Carolina 27705 (United States) [Medical Physics Graduate Program, Duke University, Durham, North Carolina 27705 (United States); Carl E. Ravin Advanced Imaging Laboratories, Department of Radiology, Duke University Medical Center, Durham, North Carolina 27705 (United States); Department of Electrical and Computer Engineering, Duke University, Durham, North Carolina 27705 (United States); Department of Physics, Duke University, Durham, North Carolina 27705 (United States); Department of Biomedical Engineering, Duke University, Durham, North Carolina 27705 (United States); Lo, Joseph Y. [Medical Physics Graduate Program, Duke University, Durham, North Carolina 27705 (United States) [Medical Physics Graduate Program, Duke University, Durham, North Carolina 27705 (United States); Carl E. Ravin Advanced Imaging Laboratories, Department of Radiology, Duke University Medical Center, Durham, North Carolina 27705 (United States); Department of Electrical and Computer Engineering, Duke University, Durham, North Carolina 27705 (United States); Department of Biomedical Engineering, Duke University, Durham, North Carolina 27705 (United States)

2014-06-15T23:59:59.000Z

242

Evidence for a receptor for ceruloplasmin on chick aortic and heart cell membranes  

E-Print Network [OSTI]

OF TABLES LIST OF FIGURES. INTRODUCTION MATERIALS AND METHODS. page Vl Vl1 Viii 1. X Animals Preparation of Aortic and Heart Membranes Purification of Chick Ceruloplasmin Iodination of Ceruloplasmin Binding Studies Purification of Glycoproteins... Preparation of Asialoglycoprotein RESULTS. 7 7 8 9 10 11 12 13 Membrane Preparation. Purification of Chick Ceruloplasmin Iodination of Ceruloplasmin Binding Studies Characterization of the Receptor. DISCUSSION REFERENCES VITA 13 13 22 22...

Stevens, Michael Duane

1982-01-01T23:59:59.000Z

243

Complete Phase I Tests As Described in the Multi-lab Test Plan for the Evaluation of CH3I Adsorption on AgZ  

SciTech Connect (OSTI)

Silver-exchanged mordenite (AgZ) has been identified as a potential sorbent for iodine present in the off-gas streams of a used nuclear fuel reprocessing facility. In such a facility, both elemental and organic forms of iodine are released from the dissolver in gaseous form. These species of iodine must be captured with high efficiency for a facility to avoid radioactive iodine release above regulatory limits in the gaseous effluent of the plant. Studies completed at Idaho National Laboratory (INL) examined the adsorption of organic iodine in the form of CH3I by AgZ. Upon breakthrough of the feed gas through the sorbent bed, elemental iodine was observed in the effluent stream, despite the fact that the only source of iodine in the system was the CH3I in the feed gas.1 This behavior does not appear to have been reported previously nor has it been independently confirmed. Thus, as a result of these prior studies, multiple knowledge gaps relating to the adsorption of CH3I by AgZ were identified, and a multi-lab test plan, including Oak Ridge National Laboratory (ORNL), INL, Pacific Northwest National Laboratory (PNNL), and Sandia National Laboratories, was formulated to address each in a systematic way.2 For this report, the scope of work for ORNL was further narrowed to three thin-bed experiments that would characterize CH3I adsorption onto AgZ in the presence of water, NO, and NO2. Completion of these three-thin bed experiments demonstrated that organic iodine in the form of CH3I was adsorbed by reduced silver mordenite (Ag0Z) to a 50% higher loading than that of I2 when adsorbed from a dry air stream. Adsorption curves suggest different adsorption mechanisms for I2 and CH3I. In the presence of NO and NO2 gas, the loading of CH3I onto Ag0Z is suppressed and may be reversible. Further, the presence of NO and NO2 gas appears to oxidize CH3I to I2; this is indicated by an adsorption curve similar to that of I2 on Ag0Z. Finally, the loss of organic iodine loading capacity by Ag0Z in the presence of NOx is unaffected by the addition of water vapor to the gas stream; no marked additional loss in capacity or retention was observed.

Bruffey, S. H. [ORNL; Jubin, R. T. [ORNL

2014-09-30T23:59:59.000Z

244

Silver-Mordenite for Radiologic Gas Capture from Complex Streams: Dual Catalytic CH3I Decomposition and I Confinement  

SciTech Connect (OSTI)

The effective capture and storage of radiological iodine (129I) remains a strong concern for safe nuclear waste storage and safe nuclear energy. Silver-containing mordenite (MOR) is a longstanding benchmark for iodine capture. In nuclear fuel reprocessing scenarios, complex gas streams will be present and the need for high selectivity of all iodine containing compounds is of the utmost importance for safety and the environment. In particular, a molecular level understanding of the sorption of organic iodine compounds is not well understood. Here we probe the structure and distribution of methyl iodide sorbed by silver-containing MOR using a combination of crystallographic and materials characterization techniques including: infrared spectroscopy, thermogravimetric analysis with mass spectrometry, Micro-X-ray Fluorescence, powder X-ray diffraction analysis, and pair distribution function analysis. The iodine is captured inside the MOR pore in the form of AgI nanoparticles, that is consistent with the pores sizes of the MOR, indicating that the molecule is both physically and chemically captured in the Ag-MOR. The organic component is surface catalyzed by the zeolite via the formation of Surface Methoxy Species (SMS) that result in downstream organics of dimethyl ether and methanol formation.

Tina M. Nenoff; Mark Rodriguez; Nick Soelberg; Karena W. Chapman

2014-12-01T23:59:59.000Z

245

Chemical aspects of pellet-cladding interaction in light water reactor fuel elements  

SciTech Connect (OSTI)

In contrast to the extensive literature on the mechanical aspects of pellet-cladding interaction (PCI) in light water reactor fuel elements, the chemical features of this phenomenon are so poorly understood that there is still disagreement concerning the chemical agent responsible. Since the earliest work by Rosenbaum, Davies and Pon, laboratory and in-reactor experiments designed to elucidate the mechanism of PCI fuel rod failures have concentrated almost exclusively on iodine. The assumption that this is the reponsible chemical agent is contained in models of PCI which have been constructed for incorporation into fuel performance codes. The evidence implicating iodine is circumstantial, being based primarily upon the volatility and significant fission yield of this element and on the microstructural similarity of the failed Zircaloy specimens exposed to iodine in laboratory stress corrosion cracking (SCC) tests to cladding failures by PCI.

Olander, D.R.

1982-01-01T23:59:59.000Z

246

Halogenated sulfidohydroboranes for nuclear medicine and boron neutron capture therapy  

DOE Patents [OSTI]

A method for performing boron neutron capture therapy for the treatment of tumors is disclosed. The method includes administering to a patient an iodinated sulfidohydroborane, a boron-10-containing compound. The site of the tumor is localized by visualizing the increased concentration of the iodine labelled compound at the tumor. The targeted tumor is then irradiated with a beam of neutrons having an energy distribution effective for neutron capture. Destruction of the tumor occurs due to high LET particle irradiation of the tissue secondary to the incident neutrons being captured by the boron-10 nuclei. Iodinated sulfidohydroboranes are disclosed which are especially suitable for the method of the invention. In a preferred embodiment, a compound having the formula Na.sub.4 B.sub.12 I.sub.11 SSB.sub.12 I.sub.11, or another pharmaceutically acceptable salt of the compound, may be administered to a cancer patient for boron neutron capture therapy.

Miura, Michiko (Hampton Bays, NY); Slatkin, Daniel N. (Southold, NY)

1997-03-18T23:59:59.000Z

247

Halogenated sulfidohydroboranes for nuclear medicine and boron neutron capture therapy  

DOE Patents [OSTI]

A method for performing boron neutron capture therapy for the treatment of tumors is disclosed. The method includes administering to a patient an iodinated sulfidohydroborane, a boron-10-containing compound. The site of the tumor is localized by visualizing the increased concentration of the iodine labelled compound at the tumor. The targeted tumor is then irradiated with a beam of neutrons having an energy distribution effective for neutron capture. Destruction of the tumor occurs due to high LET particle irradiation of the tissue secondary to the incident neutrons being captured by the boron-10 nuclei. Iodinated sulfidohydroboranes are disclosed which are especially suitable for the method of the invention. In a preferred embodiment, a compound having the formula Na{sub 4}B{sub 12}I{sub 11}SSB{sub 12}I{sub 11}, or another pharmaceutically acceptable salt of the compound, may be administered to a cancer patient for boron neutron capture therapy. 1 fig.

Miura, M.; Slatkin, D.N.

1997-03-18T23:59:59.000Z

248

Halogenated sulfidohydroboranes for nuclear medicine and boron neutron capture therapy  

DOE Patents [OSTI]

A method for performing boron neutron capture therapy for the treatment of tumors is disclosed. The method includes administering to a patient an iodinated sulfidohydroborane, a boron-10-containing compound. The site of the tumor is localized by visualizing the increased concentration of the iodine labelled compound at the tumor. The targeted tumor is then irradiated with a beam of neutrons having an energy distribution effective for neutron capture. Destruction of the tumor occurs due to high LET particle irradiation of the tissue secondary to the incident neutrons being captured by the boron-10 nuclei. Iodinated sulfidohydroboranes are disclosed which are especially suitable for the method of the invention. In a preferred embodiment, a compound having the formula Na.sub.4 B.sub.12 I.sub.11 SSB.sub.12 I.sub.11, or another pharmaceutically acceptable salt of the compound, may be administered to a cancer patient for boron neutron capture therapy.

Miura, Michiko (Hampton Bays, NY); Slatkin, Daniel N. (Southold, NY)

1995-10-03T23:59:59.000Z

249

Halogenated sulfidohydroboranes for nuclear medicine and boron neutron capture therapy  

DOE Patents [OSTI]

A method for performing boron neutron capture therapy for the treatment of tumors is disclosed. The method includes administering to a patient an iodinated sulfidohydroborane, a boron-10-containing compound. The site of the tumor is localized by visualizing the increased concentration of the iodine labelled compound at the tumor. The targeted tumor is then irradiated with a beam of neutrons having an energy distribution effective for neutron capture. Destruction of the tumor occurs due to high LET particle irradiation of the tissue secondary to the incident neutrons being captured by the boron-10 nuclei. Iodinated sulfidohydroboranes are disclosed which are especially suitable for the method of the invention. In a preferred embodiment, a compound having the formula Na{sub 4}B{sub 12}I{sub 11}SSB{sub 12}I{sub 11}, or another pharmaceutically acceptable salt of the compound, may be administered to a cancer patient for boron neutron capture therapy. 1 fig.

Miura, M.; Slatkin, D.N.

1997-08-05T23:59:59.000Z

250

Halogenated sulfidohydroboranes for nuclear medicine and boron neutron capture therapy  

DOE Patents [OSTI]

A method for performing boron neutron capture therapy for the treatment of tumors is disclosed. The method includes administering to a patient an iodinated sulfidohydroborane, a boron-10-containing compound. The site of the tumor is localized. by visualizing the increased concentration of the iodine labelled compound at the tumor. The targeted tumor is then irradiated with a beam of neutrons having an energy distribution effective for neutron capture. Destruction of the tumor occurs due to high LET particle irradiation of the tissue secondary to the incident neutrons being captured by the boron-10 nuclei. Iodinated sulfidohydroboranes are disclosed which are especially suitable for the method of the invention. In a preferred embodiment, a compound having the formula Na.sub.4 B.sub.12 I.sub.11 SSB.sub.12 I.sub.11, or another pharmaceutically acceptable salt of the compound, may be administered to a cancer patient for boron neutron capture therapy.

Miura, Michiko (Hampton Bays, NY); Slatkin, Daniel N. (Southold, NY)

1997-08-05T23:59:59.000Z

251

Improved method for preparing rare earth sesquichalcogenides  

DOE Patents [OSTI]

An improved method for the preparation of high purity rare earth sesquichalcogenides is described. The rare earth, as one or more pieces of the metal, is sealed under a vacuum with a stoichiometric amount of sulfur or selenium and a small amount of iodine into a quartz reaction vessel. The sealed vessel is then heated to above the vaporization temperature of the chalcogen and below the melting temperature of the rare earth metal and maintained until the product has been formed. The iodine is then vaporized off leaving a pure product. The rare earth sulfides and selenides thus formed are useful as semiconductors and as thermoelectric generators. 3 tables.

Takeshita, T.; Beaudry, B.J.; Gschneidner, K.A. Jr.

1982-04-14T23:59:59.000Z

252

Exploding conducting film laser pumping apparatus  

DOE Patents [OSTI]

Exploding conducting film laser optical pumping apparatus. The 342-nm molecular iodine and the 1.315-.mu.m atomic iodine lasers have been optically pumped by intense light from exploding-metal-film discharges. Brightness temperatures for the exploding-film discharges were approximately 25,000 K. Although lower output energies were achieved for such discharges when compared to exploding-wire techniques, the larger surface area and smaller inductance inherent in the exploding-film should lead to improved efficiency for optically-pumped gas lasers.

Ware, Kenneth D. (San Diego, CA); Jones, Claude R. (Los Alamos, NM)

1986-01-01T23:59:59.000Z

253

A theoretical analysis of proportional counter response versus LET  

E-Print Network [OSTI]

crimlurator settin A computer program rvas devcloned to couple t'ie energy disLribution and IDT equation;. of Lhe five b, rta emitter, : argon-41& krypton-85, iodine-333, xenon-133 and cesium-137, for clcLccror chamber sizes oF 50 cm. v 10 crn. x I c. m.... Fwergy spectrum of the 8 rays from A-gon-41. 18 F'IG. B. Fnezgy spectrum of the 8 rays from Krypton-85. . . FIG. 9. Energ~ spectrum of the 8 rays from Iodine-131. . . 20 FIG. 10. FIG. 11. Energy spectrum of the 8 rays from Xenon-133. . . Energy...

Martin, George Gerald

1970-01-01T23:59:59.000Z

254

Developing the Sandia National Laboratories transportation infrastructure for isotope products and wastes  

SciTech Connect (OSTI)

The US Department of Energy (DOE) plans to establish a medical isotope project that would ensure a reliable domestic supply of molybdenum-99 ({sup 99}Mo) and related medical isotopes (Iodine-125, Iodine-131, and Xenon-133). The Department`s plan for production will modify the Annular Core Research Reactor (ACRR) and associated hot cell facility at Sandia National Laboratories (SNL)/New Mexico and the Chemistry and Metallurgy Research facility at Los Alamos National Laboratory (LANL). Transportation activities associated with such production is discussed.

Trennel, A.J.

1997-11-01T23:59:59.000Z

255

Determining and modeling near site dispersion of gaseous releases to the environment  

E-Print Network [OSTI]

mm Hg at 0. 9 C. There 21 are 7. 48 x 10 iodine atoms per milliter of ethyl iodide and the thermal neutron activation cross-section is 6. 1 barns for iodine-127 which is 100 percent atom abundance (HOLDEN and WALKER, 1972). 16 Following a neutron... extension of the technique to atmospheric dispersion studies. 2 Assuming 10 ml of ethyl iodide is released and sampled at 3 -5 I m /sec at the location of the 10 dilution factor with a 90% collection efficiency (ACKLEY, ADAMS, and BROWNING, 1967; CRAIG...

Flynn, Charles Rene

1974-01-01T23:59:59.000Z

256

Phase 1 Methyl Iodide Deep-Bed Adsorption Tests  

SciTech Connect (OSTI)

Nuclear fission results in the production of fission products (FPs) and activation products including iodine-129, which could evolve into used fuel reprocessing facility off-gas systems, and could require off-gas control to limit air emissions to levels within acceptable emission limits. Research, demonstrations, and some reprocessing plant experience have indicated that diatomic iodine can be captured with efficiencies high enough to meet regulatory requirements. Research on the capture of organic iodides has also been performed, but to a lesser extent [Jubin 2012b]. Several questions remain open regarding the capture of iodine bound in organic compounds. Deep-bed methyl iodide adsorption testing has progressed according to a multi-laboratory methyl iodide adsorption test plan. This report summarizes the first phase of methyl iodide adsorption work performed according to this test plan using the deep-bed iodine adsorption test system at the Idaho National Laboratory (INL), performed during Fiscal Year (FY) 2013 and early FY-2014. Testing has been performed to address questions posed in the test plan, and followed the testing outline in the test plan. Tests established detection limits, developed procedures for sample analysis with minimal analytical interferences, and confirmed earlier results that show that the methyl iodide reacts when in contact with the AgZ sorbent, and not significantly in the gas flow upstream of the sorbent. The reaction(s) enable separation of the iodine from the organic moiety, so that the iodine can chemisorb onto the sorbent. The organic moiety can form other compounds, some of which are organic compounds that are detected and can be tentatively identified using GC-FID and GCMS. Test results also show that other gas constituents (NOx and/or H2O) can affect the methyl iodide reactions. With NOx and H2O present in the gas stream, the majority of uncaptured iodine exiting iodine-laden sorbent beds is in the form of I2 or HI, species that are soluble in NaOH scrubbing solution for iodine analysis. But when NOx and H2O are not present, then the majority of the uncaptured iodine exiting iodine-laden sorbent is in the form of methyl iodide. Methyl iodide adsorption efficiencies have been high enough so that initial DFs exceed 1,000 to 10,000. The methyl iodide mass transfer zone depths are estimated at 4-8 inches, possibly deeper than mass transfer zone depths estimated for I2 adsorption on AgZ. Additional deep-bed testing and analyses are recommended to (a) expand the data base for methyl iodide adsorption under various conditions specified in the methyl iodide test plan, and (b) provide more data for evaluating organic iodide reactions and reaction byproducts for different potential adsorption conditions.

Nick Soelberg; Tony Watson

2014-08-01T23:59:59.000Z

257

RADIOIODINE GEOCHEMISTRY IN THE SRS SUBSURFACE ENVIRONMENT  

SciTech Connect (OSTI)

Iodine-129 is one of the key risk drivers for several Savannah River Site (SRS) performance assessments (PA), including that for the Low-Level Waste Disposal Facility in E-Area. In an effort to reduce the uncertainty associated with the conceptual model and the input values used in PA, several studies have recently been conducted dealing with radioiodine geochemistry at the SRS. The objective of this report was to review these recent studies and evaluate their implications on SRS PA calculations. For the first time, these studies measured iodine speciation in SRS groundwater and provided technical justification for assuming the presence of more strongly sorbing species (iodate and organo-iodine), and measured greater iodine sediment sorption when experiments included these newly identified species; specifically they measured greater sorption coefficients (K{sub d} values: the concentration ratio of iodine on the solid phase divided by the concentration in the aqueous phase). Based on these recent studies, new best estimates were proposed for future PA calculations. The new K{sub d} values are greater than previous recommended values. These proposed K{sub d} values reflect a better understanding of iodine geochemistry in the SRS subsurface environment, which permits reducing the associated conservatism included in the original estimates to account for uncertainty. Among the key contributing discoveries supporting the contention that the K{sub d} values should be increased are that: 1) not only iodide (I{sup -}), but also the more strongly sorbing iodate (IO{sub 3}{sup -}) species exists in SRS groundwater (average total iodine = 15% iodide, 42% iodate, and 43% organoiodine), 2) when iodine was added as iodate, the measured K{sub d} values were 2 to 6 times greater than when the iodine was added as iodide, and perhaps most importantly, 3) higher desorption (10 to 20 mL/g) than (ad)sorption (all previous studies) K{sub d} values were measured. The implications of this latter point is that the iodine desorption process would be appreciably slower than the (ad)sorption process, and as such would control the rate (and the PA K{sub d} value) that iodine sorbed to and therefore migrated through the subsurface sediment. High desorption K{sub d} values would result in the “effective K{sub d}” for a reactive transport model being closer to the desorption K{sub d} value (the rate limiting value) than the (ad)sorption K{sub d} value. In summary, our understanding of {sup 129}I geochemistry has greatly improved, reducing the uncertainty associated with the PA’s conceptual model, thereby permitting us to reduce the conservatism presently incorporated in PA input values to describe {sup 129}I fate and transport in the SRS subsurface environment.

Kaplan, D.; Emerson, H.; Powell, B.; Roberts, K.; Zhang, S.; Xu, C.; Schwer, K.; Li, H.; Ho, Y.; Denham, M.; Yeager, C.; Santschi, P.

2013-05-16T23:59:59.000Z

258

The Relation of the Phosphoric Acid of the Soil to Pot Experiments.  

E-Print Network [OSTI]

.6 62.4 56.1 67.2 50.0 Phosphoric Ac~d per Million of soil 3.9 6.0 9.9 17.6 12.5 KN Total gm. 16.9 28.8 33.1 57.2 45.4 Phos horic ~ciBper crop gm. .0178 .0323 .0384 .OX01 .0539 KN per crop gm. 8.5 14.4 16.6 28.6 22....87 17.36 15.38 11.92 18.97 31.01 31.75 22.12 Crop No. 2-Sorghum KN.. ............................. 7.71 9.99 11.17 11.86 11.25 8.23 14.14 26.21 18.98 20.18 Crop No. 3-Corn KN. ................................. 9.39 6.60 12.60 11.01 10.59 5.03 10...

Fraps, G. S. (George Stronach)

1920-01-01T23:59:59.000Z

259

Hyperactivated Motility of Stallion Spermatozoa  

E-Print Network [OSTI]

s t s of chan ges t o t he s perm pl as m a m em brane, c yt os ol and a xonem al s t ruct ures , i ncl u di ng i ncreas ed p rot ei n t yros i ne phos phor yl at i on (P Y, [ 9 ] ), i ncre as ed i nt ra cel l ul ar pH [ 10 - 13 ] , i ncreas ed i nt racel l... ] . B i carbonat e s t i m ul at es t he prot ei n ki nas e A pat hw a y vi a s t i m ul at i on of t he s perm s ol ubl e aden yl at e c yc l as e and product i on o f cAM P [ 27 ] and a l s o fac i l i t at es an i ncreas e i n m e di um pH, whi ch...

Loux, Shavahn C

2013-12-02T23:59:59.000Z

260

Capturing fleeting intermediates in a catalytic CH amination reaction cycle  

E-Print Network [OSTI]

droplets in a stream of gas form a spray that impacts a surface containing a sample of interest the mechanism for Rh-catalyzed C­H amination depicted in Fig. 1. Sulfamate 2 and iodine oxidant 3 condense and extracts analyte into secondary microdroplets. Subsequent desolvation generates gas-phase ions that can

Zare, Richard N.

Note: This page contains sample records for the topic "iodine phos phorus" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Abstract: The deproto-metalation reactions of pyrimidine and pyrazine were regioselectively carried out using lithium  

E-Print Network [OSTI]

carried out using lithium tri(2,2,6,6-tetramethylpiperidino)cadmate in tetrahydrofuran at room temperature instead of 1/3). Key words: Metalations, Cadmium, Lithium, Heterocycles, Iodine. Procedure 1 25 mmol scale metalation of aromatic rings, and various strong bases such as alkylli- thiums and lithium dialkylamides have

Boyer, Edmond

262

JOINT EPA/DOE STATEMENT: Radiation Monitors Confirm That No Radiation...  

Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

levels amount to a level of approximately 0.0002 disintegrations per second per cubic meter of air (0.2 mBqm3). Specifically, the level of Iodine-131 was 0.165 mBqm3, the level...

263

COMMENTARY/COMMENTAIRE The radiological consequences of the Chernobyl  

E-Print Network [OSTI]

COMMENTARY/COMMENTAIRE The radiological consequences of the Chernobyl accident The First­22 March 1996 Eric Voice Abstract: The human health consequences of the Chernobyl accident in 1986 have are discussed with particular focus on thyroid cancers and exposures to iodine-131. Key words: Chernobyl

Shlyakhter, Ilya

264

Ris-R-665(EN) Predicted Effects of  

E-Print Network [OSTI]

on a hypotheti- cal core-melt accident in a unit of the Ringhab nuclear power station followed by a release Hideaki Yamamoto*, Sven P. Nielsen and Flemming Nielsen *Japan Atomic Energy Research Institute Risř with iodine-131, cćsium-134 and cacsium-137 after a release of radioactive materials from the Ringhals nuclear

265

AIAA Plasmadynamics and Lasers Conference 6-9 June 2005, Toronto, Ontario Canada  

E-Print Network [OSTI]

. Conventionally, a two phase (gas-liquid) chemistry singlet oxygen generator (SOG) produces the O2(a In an electric discharge Oxygen-Iodine laser (ElectricOIL), laser action at 1315 nm on the I(2 P1/2) I(2 P3 using a low-pressure electric discharge. The discharge production of atomic oxygen, ozone, and other

Carroll, David L.

266

carroll@cuaerospace.com; phone 1-217-333-8274; fax 1-217-244-7757; http://cuaerospace.com; CU Aerospace, 60 Hazelwood Dr., Champaign, IL 61820.  

E-Print Network [OSTI]

reaction has been fed by a liquid chemistry singlet oxygen generator (SOG). Over the past several years. Atomic oxygen titration experiments are presented along with gain as a function of power input to the system. Keywords: DOIL, EOIL, chemical oxygen-iodine laser, COIL, ElectriCOIL, RF excitation of oxygen

Carroll, David L.

267

AIAA Plasmadynamics and Lasers Conference 6-9 June 2005, Toronto, Ontario Canada  

E-Print Network [OSTI]

, the O2(a) is produced by a liquid chemistry singlet oxygen generator (SOG). There are many system issues The classic chemical oxygen-iodine laser (COIL) system1 operates on the I(2 P1/2) I(2 P3/2) [hereafter inversion is produced by the near resonant energy transfer between the metastable excited singlet oxygen

Carroll, David L.

268

JOURNAL DE PHYSIQUE N ColloqueC7,suppl6mentau Journalde Physique 111,Vol. 1,dkembre 1991  

E-Print Network [OSTI]

.The use of solid compounds for the singlet oxygen (SO) generator was investigated. By the means of the SO generator is minimal. Today the power of Chemical Oxygen-Iodine Laser (COIL) and it efficiency is determined mainly by the operational characteristics of the Singlet Oxygen Generator (SOG)[1,2]. The known

Paris-Sud XI, Université de

269

Performance of a Multi-Stream Injection COIL with Starlet Darren M. King1  

E-Print Network [OSTI]

. Pressures in the singlet oxygen generator (SOG) were relatively constant with ejector flow rate suggesting generator performance for pressure recovery potential. I. Introduction The chemical oxygen-iodine laser]. Much of the COIL technology development to date has focused on the singlet- oxygen generator (SOG

Carroll, David L.

270

ElectricOIL discharge and post-discharge kinetics experiments and modeling  

E-Print Network [OSTI]

oxygen, ozone, and other excited species adds levels of complexity to the singlet oxygen generator (SOG has been obtained by a near resonant energy transfer from O2(a1 ) produced using a low­pressure oxygen/helium/nitric-oxide discharge. In the electric discharge oxygen-iodine laser (ElectricOIL) the discharge production of atomic

Carroll, David L.

271

JOURNALDE PHYSIQUE IV ColloqueC7,supplt5ment au Journalde Physique111,Vol, 1,dkembre 1991  

E-Print Network [OSTI]

IODINELASER UTILIZED HIGH-PRESSURE PULSED SINGLET OXYGEN GENERATOR M. ENDO,K. SHIROKIand T. UCHIYAMA-ku, Yokohama223,Japan ABSTRACT : A pulsed iodine laser driven by a chemical oxygen generator was developed. The energy deposition on I(2P3/2) was made by a high pressure pulsed 02(alAg) generator. Although this scheme

Boyer, Edmond

272

IOP PUBLISHING JOURNAL OF PHYSICS D: APPLIED PHYSICS J. Phys. D: Appl. Phys. 43 (2010) 025208 (10pp) doi:10.1088/0022-3727/43/2/025208  

E-Print Network [OSTI]

. Logistic issues with this chemical singlet oxygen generator (SOG) motivated many investigations­He­NO gas mixture. Active oxygen and nitrogen species were observed downstream of the discharge regionW in a supersonic flow cavity. 1. Introduction The classical chemical oxygen­iodine laser (COIL) reported by Mc

Carroll, David L.

2010-01-01T23:59:59.000Z

273

Proceedings of the International Conference on Lasers 2000, eds. V.J. Corcoran and T.A. Corcoran, STS Press, McLean VA, 2001, pp. 265-272.  

E-Print Network [OSTI]

oxygen-iodine laser (COIL) singlet oxygen generator (SOG) based on discharge excitation of molecular/2). Historically, this pumping reaction has been fed by a liquid chemistry singlet oxygen generator (SOG, STS Press, McLean VA, 2001, pp. 265-272. 265 ElectriCOIL: Preliminary Experiments of Excited Oxygen

Carroll, David L.

274

Nuclear medicine program progress report for quarter ending December 31, 1991  

SciTech Connect (OSTI)

This report presents information on (1) a new improved synthesis of carrier-free rhenium-188-labeled Re(V) dimercaptosuccinic acid (DMSA) complex as a potential therapeutic agent for treatment of thyroid medullary carcinoma; and (2) the synthesis and evaluation of a series of iodine-125-labeled analogues of altanserine for imaging of serotonin receptors.

Knapp, F.F. Jr.; Ambrose, K.R.; Callahan, A.P.; McPherson, D.W.; Mirzadeh, S.; Srivastava, P.C.; Hasan, A.; Lambert, C.R.; Lambert, S.J.; Rice, D.E.

1992-04-01T23:59:59.000Z

275

Na double-edge magneto-optic filter for Na lidar profiling of wind and temperature in the  

E-Print Network [OSTI]

proposed by one of the authors (Williams), originating from the Na magneto-optic filter in solar-edge magneto-optic fil- ter (Na-DEMOF). It has advantages over the FPIs and iodine filters because of its magnetic field across the Na cell causes the Zeeman splitting of Na energy levels, which shifts

Chu, Xinzhao

276

JOURNAL DE PHYSIQUE IV ColloqueC7,supplkmentau Journal de Physique 111,Vol. 1,dkmbre 1991  

E-Print Network [OSTI]

tailored to pump lasers, such as flashlamps, arc lamps, and lasers for pumping. The advantages of solar lasers are that the solar energy is free, non-local, pollution free, and abundant. Indeed, direct solar of power laser beaming in spaceand its applicationsare presented. A direct solar-pumped iodine laser

Paris-Sud XI, Université de

277

BIOCHEMISTRY OF SNAKE VENOM NEUROTOXINS AND THEIR APPLICATION TO THE STUDY OF THE SYNAPSE  

E-Print Network [OSTI]

Bgt s-Bgt BSA CD Q.1 OviF Ddt D! viS d- TC DTT GABA HNB 3H-Labeling of a-Bgt and Ddt. Iodinated derivatives of the twodendra- toxin ([125r]-ddt) was the only product isolated (

Hanley, M.R.

2011-01-01T23:59:59.000Z

278

Carbon Allocation in Underground Storage Organs  

E-Print Network [OSTI]

Carbon Allocation in Underground Storage Organs Studies on Accumulation of Starch, Sugars and Oil Cover: Starch granules in cells of fresh potato tuber visualised by iodine staining. #12;Carbon By increasing knowledge of carbon allocation in underground storage organs and using the knowledge to improve

279

Polyacrylonitrile-Chalcogel Hybrid Sorbents for Radioiodine Capture  

SciTech Connect (OSTI)

Powders of a Sn2S3 chalcogen-based aerogel (chalcogel) were combined with powdered polyacrylonitrile (PAN) in different mass ratios (SnS33, SnS50, and SnS70; # = mass% of chalcogel), dissolved in dimethyl sulfoxide, and added dropwise to deionized water to form pellets of a porous PAN-chalcogel hybrid material. These pellets, along with pure powdered (SnSp) and granular (SnSg) forms of the chalcogel, were then used to capture iodine gas under both dynamic (dilute) and static (concentrated) conditions. Both SnSp and SnSg chalcogels showed very high iodine loadings at 67.2 and 68.3 mass%, respectively. The SnS50 hybrid sorbent demonstrated a high, although slightly reduced, maximum iodine loading (53.5 mass%) with greatly improved mechanical rigidity. In all cases, X-ray diffraction results showed the formation of crystalline SnI4 and SnI4(S8)2, revealing that the iodine binding in these materials is mainly due to a chemisorption process, although a small amount of physisorption was observed.

Brian J. Riley; David A. Pierce; Jaehun Chun; Josef Matyas; William C. Lepry; Troy G. Garn; Jack D. Law; Mercouri G. Kanatzidis

2014-04-01T23:59:59.000Z

280

RIS-M-2234 A NOTE ON THE RELATIONSHIP BETWEEN OUTDOOR AND INDOOR  

E-Print Network [OSTI]

POLLUTION OP OUTDOOR ORIGIN H.L. Gjørup and Jørn Roed Health Physics Department Abstract. Beryllium-7-descriotors; AIR POLLUTION, BERYLLIUM 7, BUILDINGS, INHALATION, IODINE 131, MEASURING METHODS, RADIATION DOSES from its counterpart in Danish dated Hay 1979. 2. GENERAL INFORMATION Any pollution of inhaled air

Note: This page contains sample records for the topic "iodine phos phorus" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

Microbe Identification Activity The purpose of this activity is to differentiate (tell the difference) between various bacterial  

E-Print Network [OSTI]

Microbe Identification Activity Purpose The purpose of this activity is to differentiate (tell between gram-positive and gram-negative bacteria - Tell the difference between catalase positive species Materials Microscope slide Crystal Violet Gram's Iodine Ethanol (de-stain) Safranin Malachite

Rose, Michael R.

282

Prevalence of Salmonella sp. in domestic cats in an animal shelter and the comparison of culture and polymerase chain reaction techniques as diagnostic tools  

E-Print Network [OSTI]

Laboratory the prevalence of Salmonella in shelter cat feces was determined in this current study. The culture protocol used included Xylose Lysine Tergitol 4 (XLT4) and MacConkey (MAC) agars with a primary enrichment in Tetrathionate broth (TTH) with iodine...

Lee, Melinda J.

2004-11-15T23:59:59.000Z

283

Segmented Waves from a Spatiotemporal Transverse Wave Instability Lingfa Yang, Igal Berenstein, and Irving R. Epstein*  

E-Print Network [OSTI]

Segmented Waves from a Spatiotemporal Transverse Wave Instability Lingfa Yang, Igal Berenstein observe traveling waves emitted from Turing spots in the chlorine dioxide-iodine-malonic acid reaction. The newborn waves are continuous, but they break into segments as they propagate, and the propagation

Epstein, Irving R.

284

Radioiodinated glucose analogues for use as imaging agents  

DOE Patents [OSTI]

A radioiodinated branched carbohydrate for tissue imaging. Iodine-123 is stabilized in the compound by attaching it to a vinyl functional group that is on the carbohydrate. The compound exhibits good uptake and retention and is promising in the development of radiopharmaceuticals for brain, heart and tumor imaging.

Goodman, Mark M. (Knoxville, TN); Knapp, Jr., Furn F. (Oak Ridge, TN)

1988-01-01T23:59:59.000Z

285

Radioiodinated branched carbohydrates  

DOE Patents [OSTI]

A radioiodinated branched carbohydrate for tissue imaging. Iodine-123 is stabilized in the compound by attaching it to a vinyl functional group that is on the carbohydrate. The compound exhibits good uptake and retention and is promising in the development of radiopharmaceuticals for brain, heart and tumor imaging.

Goodman, Mark M. (Knoxville, TN); Knapp, Jr., Furn F. (Oak Ridge, TN)

1989-01-01T23:59:59.000Z

286

Page 1 of 4 Radiogram No. 8492u Form 24 for 02/21/2012  

E-Print Network [OSTI]

Makita Battery Charge 08:10-08:50 FE-2 Maintenance activation of spare Atmosphere Purification System Atmosphere Purification System Emergency Vacuum Valves [ ] 08:40-11:10 FE-5 IMV Cleaning 08:50-09:10 FE-4:00-14:30 FE-5 Water Recovery System (WRS) CWC-I (Iodinated Contingency Water Container) Fill Part 1 14

Waliser, Duane E.

287

Molecular Level Characterization and Mobility of Radionuclide-Carrying Natural Organic Matter in Aquatic Environments  

E-Print Network [OSTI]

small-size aromatic subunit (~10 kDa), while the large-size subunit (~90 kDa), which likely linked the small-size unit through some weak chemical forces, determined the relative mobility of iodine bound to organic matter. Soil resuspension experiments...

Xu, Chen

2012-10-19T23:59:59.000Z

288

sine.I0 Cyclization of 4 to a tetrahydrobenzazepine 5 could be followed by oxidative fission of one aromatic ring. in a  

E-Print Network [OSTI]

Excited Iodine Monochloride with Halogenated Olefins Sir: We report here the photochemical separation, the trans- ClHC=CHCl photoproduct has a 35C1:37C1ratio of 2:1 compared to 3:l for naturally occurring trans with a new means of following organic gas-phase photochemical reac- tions with state selection

Zare, Richard N.

289

Halogenation of cobalt dicarbollide  

DOE Patents [OSTI]

A method for selectively adding chlorine, bromine, or iodine to cobalt dicarbollide anions by means of electrophilic substitution reactions. Halogens are added only to the B10 and B10{prime} positions of the anion. The process involves use of hypohalous acid or N-halosuccinimide or gaseous chlorine in the presence of iron. 1 fig.

Hurlburt, P.K.; Abney, K.D.; Kinkead, S.A.

1997-05-20T23:59:59.000Z

290

Dynamics of the radiation situation on the territory of the Republic of Belarus  

SciTech Connect (OSTI)

This paper examines the environmental contamination in Belarus before the Chernobyl accident and after it. The soil concentration was determined for iodine-131 in 1986, cerium-144 in 1986, and cesium-137 in 1993. Surface water contamination was determined for cesium-137 from 1987-1991. The vertical migration of cesium 137 was determined in soil.

Matveyenko, I.I.; Zhukova, O.M. [Republic Centre of Radiation and Environment Monitoring, Minsk (Belarus). Belarus State Dept. for Hydrometerology

1993-12-31T23:59:59.000Z

291

Tracer Studies at Los Alamos 266 Los Alamos Science Number 23 1995  

E-Print Network [OSTI]

from atmospheric nuclear weapons testing. One said, "We've got to stop. We're going to hurt somebody was a problem for children in particular. You see, the radioactive iodine produced by nuclear weapons falls," while the other said, "We can't afford to stop. We need to test if we are going to survive militarily

Massey, Thomas N.

292

Spectral inhomogeneity induced by vacancies and thermal phonons and associated observables in time-and frequency-domain nonlinear  

E-Print Network [OSTI]

Spectral inhomogeneity induced by vacancies and thermal phonons and associated observables in time by vacancies and thermally populated phonons, specializing to molecular iodine isolated in an Ar matrix. At experimentally relevant temperatures, for a vacancy concentration of 1.4%, both defect-induced and phonon

Apkarian, V. Ara

293

Ionising Radiation emitters Spill Procedure Page 1 of 3 Version: 3.2, 5/02/2013  

E-Print Network [OSTI]

as necessary to reduce contamination close to background levels. For spills involving radioactive iodine, use.......................................................................................................3 1. Purpose and Scope Immediate control procedures for radioactive spillages of gamma Procedure Instructions In the Event of a Radioactive Spill in this Room Immediate control procedures

New South Wales, University of

294

Laser-produced plasma-wall interaction O. RENNER,1  

E-Print Network [OSTI]

Laser-produced plasma-wall interaction O. RENNER,1 R. LISKA,2 AND F.B. ROSMEJ3,4 1 Institute, France (RECEIVED 30 August 2009; ACCEPTED 21 September 2009) Abstract Jets of laser­generated plasma surfaces (walls). The pilot experiments carried out on the iodine laser system (5­200 J, 0.44 mm, 0

Liska, Richard

295

Polyacrylonitrile-Chalcogel Hybrid Sorbents for Radioiodine Capture  

SciTech Connect (OSTI)

Powders of a Sn2S3 chalcogen-based aerogel (chalcogel) were combined with powdered polyacrylonitrile (PAN) in different mass ratios (SnS33, SnS50, and SnS70 in mass% of chalcogel), dissolved into dimethyl sulfoxide, and dropped into deionized water to form pellets of a porous PAN-chalcogel hybrid material. Pellets of these hybrid sorbents, along with pure powdered (SnSp) and granular (SnSg) forms of the chalcogel, were then used to adsorb iodine gas under both concentrated and dilute conditions. Both the SnSp and SnSg chalcogels showed very high maximum iodine loadings at 67.2 and 68.3 mass%. The maximum iodine loadings in the SnS33 and SnS50 were high at 32.8 and 53.5 mass%. In all cases, X-ray diffraction results showed the formation of Sn-I phases of SnI4 and SnI4(S8)2 revealing that the iodine binding in these materials is mainly due to a chemisorption process although some evidence also exists that supports a physisorption process.

Riley, Brian J.; Pierce, David A.; Chun, Jaehun; Matyas, Josef; Lepry, William C.; Garn, Troy; Law, Jack; Kanatzidis, Mercouri G.

2014-04-16T23:59:59.000Z

296

Mercuric iodate precipitation from radioiodine-containing off-gas scrubber solution  

DOE Patents [OSTI]

Mercuric nitrate-nitric acid scrub solutions containing radioiodine may be reduced in volume without excessive loss of volatile iodine. The use of concentrated nitric acid during an evaporation process oxidizes the mercury-iodide complex to a less volatile mercuric iodate precipitate.

Partridge, Jerry A. (Richland, WA); Bosuego, Gail P. (Richland, WA)

1982-01-01T23:59:59.000Z

297

SPECT assay of radiolabeled monoclonal antibodies. Final performance report, March 1992--November 1995  

SciTech Connect (OSTI)

Research is described in the following areas: development and evaluation quantitatively of reconstruction algorithms with improved compensations for attenuation, scatter, and geometric collimator response; evaluation of single photon emission computed tomography (SPECT) quantification of iodine 123 and astatine 211; and the development and evaluation of SPECT pinhole imaging for low and medium energy photons.

Jaszczak, R.J.

1995-12-01T23:59:59.000Z

298

Features of coal dust dynamics at action of differently oriented forces in granular filtering medium  

E-Print Network [OSTI]

The process of the coal dust particles transportation and structurization in the experimental horizontal model of air filter with the cylindrical coal adsorbent granules as in the iodine air filter at the nuclear power plant is researched. In the investigated case the vector of carrying away force of air flow and the vector of gravitation force are mutually perpendicular, and the scattering of the dust particles on the granules occurs in the normal directions. It is found that the phenomenon of non controlled spontaneous sharp increase of aerodynamic resistance in the iodine air filter under the big integral volumes of filtered air and the big masses of introduced coal dust particles is not observed at the described experimental conditions in distinction from the case of the parallel orientation of this forces as in the vertical iodine air filters at the nuclear power plant. The quantitative measurements of the main parameters of the process of the dust masses transportation and structurization are made on a developed experimental model of the iodine air filter with the cylindrical coal adsorbent granules.

I. M. Neklyudov; L. I. Fedorova; P. Ya. Poltinin; O. P. Ledenyov

2013-01-24T23:59:59.000Z

299

Analytical optimization of digital subtraction mammography with contrast medium using a commercial unit  

SciTech Connect (OSTI)

Contrast-medium-enhanced digital mammography (CEDM) is an image subtraction technique which might help unmasking lesions embedded in very dense breasts. Previous works have stated the feasibility of CEDM and the imperative need of radiological optimization. This work presents an extension of a former analytical formalism to predict contrast-to-noise ratio (CNR) in subtracted mammograms. The goal is to optimize radiological parameters available in a clinical mammographic unit (x-ray tube anode/filter combination, voltage, and loading) by maximizing CNR and minimizing total mean glandular dose (D{sub gT}), simulating the experimental application of an iodine-based contrast medium and the image subtraction under dual-energy nontemporal, and single- or dual-energy temporal modalities. Total breast-entrance air kerma is limited to a fixed 8.76 mGy (1 R, similar to screening studies). Mathematical expressions obtained from the formalism are evaluated using computed mammographic x-ray spectra attenuated by an adipose/glandular breast containing an elongated structure filled with an iodinated solution in various concentrations. A systematic study of contrast, its associated variance, and CNR for different spectral combinations is performed, concluding in the proposal of optimum x-ray spectra. The linearity between contrast in subtracted images and iodine mass thickness is proven, including the determination of iodine visualization limits based on Rose's detection criterion. Finally, total breast-entrance air kerma is distributed between both images in various proportions in order to maximize the figure of merit CNR{sup 2}/D{sub gT}. Predicted results indicate the advantage of temporal subtraction (either single- or dual-energy modalities) with optimum parameters corresponding to high-voltage, strongly hardened Rh/Rh spectra. For temporal techniques, CNR was found to depend mostly on the energy of the iodinated image, and thus reduction in D{sub gT} could be achieved if the spectral energy of the noniodinated image is decreased and the breast-entrance air kerma is evenly distributed between both acquisitions. Predicted limits, in terms of iodine concentration, are found to guarantee the visualization of common clinical angiogenic concentrations in the breast.

Rosado-Mendez, I.; Palma, B. A.; Brandan, M. E. [Instituto de Fisica, Universidad Nacional Autonoma de Mexico, 04510 Mexico City (Mexico)

2008-12-15T23:59:59.000Z

300

Antimocrobial Polymer  

DOE Patents [OSTI]

A polymeric composition having antimicrobial properties and a process for rendering the surface of a substrate antimicrobial are disclosed. The composition comprises a crosslinked chemical combination of (i) a polymer having amino group-containing side chains along a backbone forming the polymer, (ii) an antimicrobial agent selected from quaternary ammonium compounds, gentian violet compounds, substituted or unsubstituted phenols, biguanide compounds, iodine compounds, and mixtures thereof, and (iii) a crosslinking agent containing functional groups capable of reacting with the amino groups. In one embodiment, the polymer is a polyamide formed from a maleic anhydride or maleic acid ester monomer and alkylamines thereby producing a polyamide having amino substituted alkyl chains on one side of the polyamide backbone; the crosslinking agent is a phosphine having the general formula (A)3P wherein A is hydroxyalkyl; and the antimicrobial agent is chlorhexidine, dimethylchlorophenol, cetyl pyridinium chloride, gentian violet, triclosan, thymol, iodine, and mixtures thereof.

McDonald, William F. (Utica, OH); Huang, Zhi-Heng (Walnut Creek, CA); Wright, Stacy C. (Columbus, GA)

2005-09-06T23:59:59.000Z

Note: This page contains sample records for the topic "iodine phos phorus" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Workshop on development of radionuclide getters for the Yucca Mountain waste repository: proceedings.  

SciTech Connect (OSTI)

The proposed Yucca Mountain repository, located in southern Nevada, is to be the first facility for permanent disposal of spent reactor fuel and high-level radioactive waste in the United States. Total Systems Performance Assessment (TSPA) analysis has indicated that among the major radionuclides contributing to dose are technetium, iodine, and neptunium, all of which are highly mobile in the environment. Containment of these radionuclides within the repository is a priority for the Yucca Mountain Project (YMP). These proceedings review current research and technology efforts for sequestration of the radionuclides with a focus on technetium, iodine, and neptunium. This workshop also covered issues concerning the Yucca Mountain environment and getter characteristics required for potential placement into the repository.

Moore, Robert Charles; Lukens, Wayne W. (Lawrence Berkeley National Laboratory)

2006-03-01T23:59:59.000Z

302

Nuclear Medicine Program progress report, quarter ending March 31, 1992  

SciTech Connect (OSTI)

We describe the design synthesis and initial animal testing of a new iodine-131-labeled triglyceride analogue for the potential evaluation of clinical pancreatic insufficiency. The new agent is 1,2-dipalmitoyl-3-[(15-p-iodophenyl)pentadecanoyl] rac-glycerol(1,2-Pal-3-IPPA). Following oral administration of the iodine-125-labeled agent to rats, 34.5+8.8% of the administered activity was excreted in the urine within one day, demonstrating that radioiodinated IPPA is absorbed in the intestine after release from the triglyceride by pancreatic lipase. The final catabolic product of IPPA is then conjugated and excreted via the urinary bladder. Urine analysis following oral administration of this new agent to patients may thus be a new, simple method for the clinical evaluation of various gastrointestinal diseases. The synthesis and the initial biological evaluation of the 3R-isomer of [{sup 125}I]IQNP are also described.

Knapp, F.F. Jr.; Ambrose, K.R.; Callahan, A.P.; McPherson, D.W.; Mirzadeh, S.; Hasan, A.; Lambert, C.R.; Rice, D.E.

1992-07-01T23:59:59.000Z

303

Nuclear Medicine Program progress report, quarter ending March 31, 1992  

SciTech Connect (OSTI)

We describe the design synthesis and initial animal testing of a new iodine-131-labeled triglyceride analogue for the potential evaluation of clinical pancreatic insufficiency. The new agent is 1,2-dipalmitoyl-3-((15-p-iodophenyl)pentadecanoyl) rac-glycerol(1,2-Pal-3-IPPA). Following oral administration of the iodine-125-labeled agent to rats, 34.5+8.8% of the administered activity was excreted in the urine within one day, demonstrating that radioiodinated IPPA is absorbed in the intestine after release from the triglyceride by pancreatic lipase. The final catabolic product of IPPA is then conjugated and excreted via the urinary bladder. Urine analysis following oral administration of this new agent to patients may thus be a new, simple method for the clinical evaluation of various gastrointestinal diseases. The synthesis and the initial biological evaluation of the 3R-isomer of ({sup 125}I)IQNP are also described.

Knapp, F.F. Jr.; Ambrose, K.R.; Callahan, A.P.; McPherson, D.W.; Mirzadeh, S.; Hasan, A.; Lambert, C.R.; Rice, D.E.

1992-07-01T23:59:59.000Z

304

Containment atmosphere response (CAR) program. Second status report. [HTGR  

SciTech Connect (OSTI)

This report contains a summary of the work performed under the Containment Atmosphere Response (CAR) Program of the High-Temperature Gas-Cooled Reactor (HTGR) Safety Research Task since the publication of the previous status report (February 1978). The work concentrated on development of models describing containment phenomena during core heatup in support of probabilistic risk assessment studies. Models were completed for fission product iodine sorption on coated surfaces, diffusivity and retentivity of untreated concrete, iodine interaction with condensing steam on the containment atmosphere boundaries, and the cleanup filter system. These models were incorporated into a new computer program called CARCAS, a substantial extension of the CNTB computer program, and applied to Accident Initiation and Progression Analysis for Phase II core heatup sequences. Development was begun on models describing the postulated behavior of particulate fission products or aerosols within and leaking out of the containment.

Landoni, J.A.

1980-03-01T23:59:59.000Z

305

Distribution of Radioactive Materials in the Absheron Peninsula, Azerbaijan - 13567  

SciTech Connect (OSTI)

The Absheron Peninsula forms the extreme Eastern part of Azerbaijan and juts into the Caspian Sea. The region has a long history of oil and gas exploration, transport, and processing and includes a number of abandoned chemical plants that were used in the separation of iodine from formation waters. As a result of lax environmental standards during the Soviet era, the industrial activity has led to serious contamination from oils residues, heavy metals and naturally occurring radioactive materials (NORM). Radiometric surveys performed over a wide range of the Absheron Peninsula showed generally low NORM concentrations. However, radiation levels two to three orders of magnitude above background levels were detected at two abandoned iodine separation plants near the capital city, Baku. These elevated radiation levels are mainly due to Ra-226 and U-238 with lower contributions from Ra-228 and U-235. (authors)

Vandergraaf, Tjalle T. [Consultant, Pinawa, MB, R0E 1L0 (Canada)] [Consultant, Pinawa, MB, R0E 1L0 (Canada); Mamedov, Gudrat G.; Ramazanov, Mahammadali A.; Badalov, Vatan H. [Baku State University, Baku (Azerbaijan)] [Baku State University, Baku (Azerbaijan); Naghiyev, Jalal A. [Institute of Radiation Problems of ANAS, Baku (Azerbaijan)] [Institute of Radiation Problems of ANAS, Baku (Azerbaijan); Mehdiyeva, Afat A. [National Aerospace Agency of Ministry of Defense Industry, Baku (Azerbaijan)] [National Aerospace Agency of Ministry of Defense Industry, Baku (Azerbaijan)

2013-07-01T23:59:59.000Z

306

Estimation of thyroid doses received by the population of Belarus as a result of the Chernobyl accident  

SciTech Connect (OSTI)

Within weeks of the Chernobyl accident ABOUT 300,000 measurements of human thyroidal iodine-131 content were conducted in the more contaminated areas of Belarus. Results of these and other measurements form the basis of thyroid-dose reconstruction for the residents. For Class 1 (measured dose), individual doses are estimated directly from measured thyroidal iodine content plus information on life style and dietary habits. Such estimates are available for about 130,000 individuals from Gomel and Mogilev Oblasts and Minsk City. For Class 2 (passport doses), every settlement with a sufficient number of residents with measured doses, individual thyroid-dose distributions were determined for several age groups and levels of milk consumption. A population of about 2.7 million resides in the passport settlements.

Gavrilin, Y.; Khrouch, V.; Shinkarev, S. [Institut Biofiziki, Moscow (Russian Federation); Drozdovitch, V.; Minenko, V.; Shemyakina, E. [Institute of Radiation Medicine, Minsk (Belarus); Bouville, A. [National Cancer Inst., Rockville, MD (United States); Anspaugh, L. [Lawrence Livermore National Lab., CA (United States)

1996-02-01T23:59:59.000Z

307

Identification and differentiation of individual beta emitters in waste mixtures by liquid scintillation spectrometry  

E-Print Network [OSTI]

carbon-14, tritium, and iodine-125 liquid scintillation wastes, provided that the activity and isotopes present can be documented. This legislation has generated a significant interest in developing a quick, cost efficient method of identificatior.... Differentiation of various components within a two isotope mixture, and the detection level of a small activity of one nuclide in a large activity of a second radioisotope was examined. A catalogue of spectra, including the isotopic ratio of each component...

Siskel, Robin Lynn

1988-01-01T23:59:59.000Z

308

Proceedings of the XI International Symposium on Gas Flow and Chemical Lasers and High Power Laser Conference, Edinburgh, UK 25-30 August 1996, SPIE Vol. 3092, ed. H.J. Baker, pp. 758-763 (1997).  

E-Print Network [OSTI]

Proceedings of the XI International Symposium on Gas Flow and Chemical Lasers and High Power Laser of 20 mm were obtained in aluminum and 41 mm in carbon steel using an N2 gas assist and 5-6 kW of power study of cutting thick aluminum and steel with a chemical oxygen-iodine laser using an N2 or O2 gas

Carroll, David L.

309

Positron emission tomographic imaging of tumors using monoclonal antibodies. Progress report, April 15, 1992--October 31, 1992  

SciTech Connect (OSTI)

This research project is developing methods for utilizing positron emission tomography (PET) to increase the clinical potential of radiolabeled monoclonal antibodies (MAbs). This report describes the development of methods for labeling MAbs and their fragments with positron-emitting halogen nuclides, fluorine-18 and iodine-124. These nulides were selected because of the widespread availability of F-18 and because of our extensive experience in the development of new protein radiohalogenation methods.

Zalutsky, M.R.

1992-08-01T23:59:59.000Z

310

Positron emission tomographic imaging of tumors using monoclonal antibodies  

SciTech Connect (OSTI)

This research project is developing methods for utilizing positron emission tomography (PET) to increase the clinical potential of radiolabeled monoclonal antibodies (MAbs). This report describes the development of methods for labeling MAbs and their fragments with positron-emitting halogen nuclides, fluorine-18 and iodine-124. These nulides were selected because of the widespread availability of F-18 and because of our extensive experience in the development of new protein radiohalogenation methods.

Zalutsky, M.R.

1992-08-01T23:59:59.000Z

311

Failure of the Shockley-Haynes Mobility Experiment with organic semiconducting materials  

E-Print Network [OSTI]

in olose proximity on the surface of a germanium block and possess high back-voltage rectifier oharacteristics. The emitter is biased in the forward or high ourrent flow direction snd the oollector is biased in the re- verse or low current flow... probe contact resistance measurements. 7. Typioal current versus voltage curve for pyrene- iodine samples, . . . , . . . , . . . . . . . . 25 8. Typical ourrsnt versus' voltage curve for perylene- iodf ne samples . . . . . . . ? . . . . . . . , 26...

Boehme, Hollis Clyde

1961-01-01T23:59:59.000Z

312

INSTITUTE OF PHYSICS PUBLISHING SEMICONDUCTOR SCIENCE AND TECHNOLOGY Semicond. Sci. Technol. 20 (2005) L40L42 doi:10.1088/0268-1242/20/8/L04  

E-Print Network [OSTI]

noise on the functioning of the dye-sensitized solar cell, notably the effect of adsorbed iodine of the dye-sensitized solar cells are discussed. TiO2 nanocrystalline films used for noise measurements were (2005) L40­L42 doi:10.1088/0268-1242/20/8/L04 LETTER TO THE EDITOR 1/f noise and dye-sensitized solar

Perera, A. G. Unil

313

Environmental Levels Of 129I Present In Bovine Thyroid And Fresh Water In Argentina  

SciTech Connect (OSTI)

Concentrations of {sup 129}I in bovine thyroid and fresh water samples coming from all over Argentina were analyzed by Accelerator Mass Spectrometry (AMS) and total iodine present in samples by Gas Chromatography (GC) and Inductive Coupled Plasma Mass Spectrometry (ICP-MS), respectively. Once we complete this study, it will be the first set of data of this kind from an extended region of the south American subcontinent.

Negri, A. E.; Arazi, A.; Carnellia, P. F. F.; Barbara, E. de; Figueira, J. M.; Fimiani, L.; Heimanna, D. M.; Zalazara, L. [Laboratorio TANDAR, CNEA, Av. Gral. Paz 1499, B1650KNA, San Martin, Buenos Aires (Argentina); Fernandez Niello, J. [Laboratorio TANDAR, CNEA, Av. Gral. Paz 1499, B1650KNA, San Martin, Buenos Aires (Argentina); Universidad Nacional de San Martin, Campus Miguelete, B1650BWA, Buenos Aires (Argentina); La Gamma, A. M. [Gerencia Quimica, CNEA, Av. Gral. Paz 1499, B1650KNA, San Martin, Buenos Aires (Argentina); Wallner, A. [VERA-Laboratory, Faculty of Physics, University of Vienna, Waehringer Str. 17, A-1090 Wien (Austria)

2010-08-04T23:59:59.000Z

314

Preparation of uranium compounds  

DOE Patents [OSTI]

UI.sub.3(1,4-dioxane).sub.1.5 and UI.sub.4(1,4-dioxane).sub.2, were synthesized in high yield by reacting turnings of elemental uranium with iodine dissolved in 1,4-dioxane under mild conditions. These molecular compounds of uranium are thermally stable and excellent precursor materials for synthesizing other molecular compounds of uranium including alkoxide, amide, organometallic, and halide compounds.

Kiplinger, Jaqueline L; Montreal, Marisa J; Thomson, Robert K; Cantat, Thibault; Travia, Nicholas E

2013-02-19T23:59:59.000Z

315

Summary Report for the Development of Materials for Volatile Radionuclides  

SciTech Connect (OSTI)

The materials development summarized here is in support of the Waste Forms campaign, Volatile Radionuclide task. Specifically, materials are being developed for the removal and immobilization of iodine and krypton, specifically 129I and 85Kr. During FY 2010, aerogel materials were investigated for removal and immobilization of 129I. Two aerogel formulations were investigated, one based on silica aerogels and the second on chalcogenides. For 85Kr, metal organic framework (MOF) structures were investigated.

Strachan, Denis M.; Chun, Jaehun; Henager, Charles H.; Matyas, Josef; Riley, Brian J.; Ryan, Joseph V.; Thallapally, Praveen K.

2010-11-22T23:59:59.000Z

316

New Approaches for Passivation of Crystalline and Amorphous Silicon: Cooperative Research and Development Final Report, CRADA Number CRD-09-351  

SciTech Connect (OSTI)

New approaches of passivating crystalline, multicrystalline, and amorphous silicon will be explored. These will include the use of aqueous solution of KCN and a proprietary composition formulated by Mallinckrodt Baker, Inc. The surface passivation will be compared with that provided by an iodine-ethanol solution, and bulk passivation will be compared with that of H-passivation obtained by silicon nitride, in a fire-through process.

Sopori, B.

2012-09-01T23:59:59.000Z

317

Evaluation of Salmonella disinfection strategies for pre-slaughter broiler crop decontamination  

E-Print Network [OSTI]

mortality I'rom navel infections, brooder pneumonia and other bacterial infections including Salmonella (O'Meara and Chute, 1959; Avens and Miller, 1974). Currently, formaldehyde is the most common hatchery disinfectant used, and is under increasing..., formaldehyde, formic acid, hipuric acid/ethanol, iodine/ethanol, potassium iodide, quaternary ammonia, shikimic acid, sodium hypochlorite, and 2-imidazolidone. In all experiments, each mL of DL was solubilized with 1 g DSS. For screening, the test tubes...

Barnhart, Eric Thomas

1998-01-01T23:59:59.000Z

318

Nuclear waste management. Quarterly progress report, January-March 1980  

SciTech Connect (OSTI)

Reported are: high-level waste immobilization, alternative waste forms, nuclear waste materials characterization, TRU waste immobilization, TRU waste decontamination, krypton solidification, thermal outgassing, iodine-129 fixation, unsaturated zone transport, well-logging instrumentation development, mobile organic complexes of fission products, waste management system and safety studies, assessment of effectiveness of geologic isolation systems, waste/rock interactions, engineered barriers, criteria for defining waste isolation, and spent fuel and pool component integrity. (DLC)

Platt, A.M.; Powell, J.A. (comps.)

1980-06-01T23:59:59.000Z

319

Nuclear waste management. Quarterly progress report, October-December 1979  

SciTech Connect (OSTI)

Progress and activities are reported on the following: high-level waste immobilization, alternative waste forms, nuclear waste materials characterization, TRU waste immobilization programs, TRU waste decontamination, krypton solidification, thermal outgassing, iodine-129 fixation, monitoring of unsaturated zone transport, well-logging instrumentation development, mobile organic complexes of fission products, waste management system and safety studies, assessment of effectiveness of geologic isolation systems, waste/rock interactions technology, spent fuel and fuel pool integrity program, and engineered barriers. (DLC)

Platt, A.M.; Powell, J.A. (comps.)

1980-04-01T23:59:59.000Z

320

Properties of zinc selenide grown by chemical vapor transport and its application to room-temperature radiation detection  

SciTech Connect (OSTI)

The authors have characterized ZnSe material grown by chemical vapor transport in iodine using triple-axis X-ray diffraction (TAD), photo-induced current transient spectroscopy (PICTS), photoluminescence (PL), current-voltage measurements and gamma-ray spectroscopy. The material was found to have inadequate carrier transport for nuclear spectrometer use, but there was a discernible difference in performance between crystals which could be correlated with crystallinity as determined by the TAD rocking curves.

Brunett, B.A.; Toney, J.E.; Schlesinger, T.E. [Carnegie Mellon Univ., Pittsburgh, PA (United States); Yoon, H.; Goorsky, M.S. [Univ. of California, Los Angeles, CA (United States). Dept. of Materials Science and Engineering; Schieber, M.; James, R.B. [Sandia National Labs., Livermore, CA (United States); Rudolph, P. [Inst. fuer KrystallZuechtung, Berlin (Germany)

1998-12-31T23:59:59.000Z

Note: This page contains sample records for the topic "iodine phos phorus" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Diffusion of vaporous guests into a seemingly non-porous organic crystal  

SciTech Connect (OSTI)

The tetragonal apohost phase of p-tert-butyltetramethoxythiacalix[4]arene absorbs hydrochloric acid and iodine. These guest molecules occupy different sites in the solid-state structure -- either within the small intrinsic voids of the macrocycle or within the interstitial spaces between the host molecules. This study illustrates the dynamic deformation of the host, providing strong mechanistic insight into the diffusion of guests into this seemingly non-porous material.

Herbert, Simon A.; Janiak, Agnieszka; Thallapally, Praveen K.; Atwood, Jerry L.; Barbour, Leonard J.

2014-12-15T23:59:59.000Z

322

Air pathway report: Phase I of the Hanford Environmental Dose Reconstruction Project  

SciTech Connect (OSTI)

Phase 1 of the air-pathway portion of the Hanford Environmental Dose Reconstruction (HEDR) Project sought to determine whether dose estimates could be calculated for populations in the 10 counties nearest the Hanford Site from atmospheric releases of iodine-131 from the site from 1944--1947. Phase 1 demonstrated the following: HEDR-calculated source-term estimates of iodine-131 releases to the atmosphere were within 20% of previously published estimates; calculated vegetation concentrations of iodine-131 agree well with previously published measurements; the highest of the Phase 1 preliminary dose estimates to the thyroid are consistent with independent, previously published estimates of doses to maximally exposed individuals; and, relatively crude, previously published measurements of thyroid burdens for Hanford workers are in the range of average burdens that the HEDR model estimated for similar reference individuals'' for the period 1944--1947. Preliminary median dose estimates summed over the year 1945--1947 for the primary pathway, air-pasture-cow-milk-thyroid, ranged from low median values of 0.006 rad for upwind adults who obtained milk from backyard cows not on pasture to high median values of 68.0 rad for downwind infants who drank milk from pasture-fed cows. Extremes of the estimated range are a low of essentially zero to upwind adults and a high of almost 3000 rem to downwind infants. 37 refs., 37 figs., 2 tabs.

Not Available

1991-07-01T23:59:59.000Z

323

Z-(R,R)-IQNP shows higher brain and heart uptake in rats than IDEX and 4IQNB  

SciTech Connect (OSTI)

Z-(R)-1-Azabicyclo[2.2.2]oct-3-yl (R)-{alpha}-hydroxy-{alpha}-(1-iodo-1-propen-3-yl)-{alpha}-phenylacetate (Z-(R,R)-IQNP) shows potential for the in vivo imaging of muscarinic receptors (mAChR) by SPECT. In vivo biodistribution studies show high uptake and prolonged retention in areas of the brain containing mAChR. We compared the biodistribution of Z-(R,R)-IQNP with 4-iodoexetimide (IDEX) and R-3 quinuclidinyl S-4-iodobenzilate (41QNB), two established muscarinic imaging agents. IDEX was labeled with iodine-125, 4IQNB was labeled with iodine-131 and IQNP was labeled with iodine-123. A solution containing the three compounds was injected in the same rat (n=5/time point). Animals were sacrificed at 30, 120, and 240 minutes and the levels of the three radioisotopes determined in various tissues. Z-(R,R)-IQNP was retained at twice the level as compared to IDEX and significantly higher than 4-IQNB in the hear and regions of the brain (Table). Z-(R,R)-IQNP also demonstrated low liver uptake as compared to IDEX. These data indicate that Z-(R,R)-IQNP is an attractive candidate for the imaging of mAChR by SPECT.

McPherson, D.W.; Ambrose, K.R.; Luo, H. [Oak Ridge National Lab., TN (United States)] [and others

1996-05-01T23:59:59.000Z

324

Chalcogen-Based Aerogels as Sorbents for Radionuclide Remediation  

SciTech Connect (OSTI)

The efficient capture of radionuclides having long half-lives such as technetium-99 (99Tc), uranium-238 (238U), and iodine-129 (129I) is pivotal to prevent their transport into groundwater and/or release into the atmosphere. While different sorbents have been considered for capturing each of them, in the current work, a new nanostructured chalcogen-based aerogel, called a chalcogel, is shown to be very effective to capture ionic forms of 99Tc and 238U, as well as nonradioactive gaseous iodine (i.e., a surrogate for 129I), irrespective of the sorbent polarity. Some of the chalcogels performed better than others but the PtGeS sorbent performed the best with capture efficiencies of 98% and 99.4% for 99Tc and 238U, respectively. All sorbents showed >99% capture efficiency for iodine over the test duration. This unified sorbent would be an attractive option in environmental remediation for various radionuclides associated with legacy wastes from nuclear weapons production, wastes from nuclear power production, or potential future nuclear fuel reprocessing.

Riley, Brian J.; Chun, Jaehun; Um, Wooyong; Lepry, William C.; Matyas, Josef; Olszta, Matthew J.; Li, Xiaohong; Polychronopoulou, Kyriaki; Kanatzidis, Mercouri G.

2013-06-13T23:59:59.000Z

325

Amino acid analogs for tumor imaging  

DOE Patents [OSTI]

The invention provides novel amino acid compounds of use in detecting and evaluating brain and body tumors. These compounds combine the advantageous properties of 1-amino-cycloalkyl-1-carboxylic acids, namely, their rapid uptake and prolonged retention in tumors with the properties of halogen substituents, including certain useful halogen isotopes including fluorine-18, iodine-123, iodine-125, iodine-131, bromine-75, bromine-76, bromine-77 and bromine-82. In one aspect, the invention features amino acid compounds that have a high specificity for target sites when administered to a subject in vivo. Preferred amino acid compounds show a target to non-target ratio of at least 5:1, are stable in vivo and substantially localized to target within 1 hour after administration. An especially preferred amino acid compound is [{sup 18}F]-1-amino-3-fluorocyclobutane-1-carboxylic acid (FACBC). In another aspect, the invention features pharmaceutical compositions comprised of an {alpha}-amino acid moiety attached to either a four, five, or a six member carbon-chain ring. In addition, the invention features analogs of {alpha}-aminoisobutyric acid.

Goodman, M.M.; Shoup, T.

1998-10-06T23:59:59.000Z

326

Amino acid analogs for tumor imaging  

DOE Patents [OSTI]

The invention provides novel amino acid compounds of use in detecting and evaluating brain and body tumors. These compounds combine the advantageous properties of 1-amino-cycloalkyl-1-carboxylic acids, namely, their rapid uptake and prolonged retention in tumors with the properties of halogen substituents, including certain useful halogen isotopes including fluorine-18, iodine-123, iodine-125, iodine-131, bromine-75, bromine-76, bromine-77 and bromine-82. In one aspect, the invention features amino acid compounds that have a high specificity for target sites when administered to a subject in vivo. Preferred amino acid compounds show a target to non-target ratio of at least 5:1, are stable in vivo and substantially localized to target within 1 hour after administration. An especially preferred amino acid compound is [{sup 18}F]-1-amino-3-fluorocyclobutane-1-carboxylic acid (FACBC). In another aspect, the invention features pharmaceutical compositions comprised of an {alpha}-amino acid moiety attached to either a four, five, or a six member carbon-chain ring. In addition, the invention features analogs of {alpha}-aminoisobutyric acid.

Goodman, M.M.; Shoup, T.

1998-09-15T23:59:59.000Z

327

Amino acid analogs for tumor imaging  

DOE Patents [OSTI]

The invention provides novel amino acid compounds of use in detecting and evaluating brain and body tumors. These compounds combine the advantageous properties of 1-amino-cycloalkyl-1-carboxylic acids, namely, their rapid uptake and prolonged retention in tumors with the properties of halogen substituents, including certain useful halogen isotopes including fluorine-18, iodine-123, iodine-125, iodine-131, bromine-75, bromine-76, bromine-77 and bromine-82. In one aspect, the invention features amino acid compounds that have a high specificity for target sites when administered to a subject in vivo. Preferred amino acid compounds show a target to non-target ratio of at least 5:1, are stable in vivo and substantially localized to target within 1 hour after administration. An especially preferred amino acid compound is ›.sup.18 F!-1-amino-3-fluorocyclobutane-1-carboxylic acid (FACBC). In another aspect, the invention features pharmaceutical compositions comprised of an .alpha.-amino acid moiety attached to either a four, five, or a six member carbon-chain ring. In addition, the invention features analogs of .alpha.-aminoisobutyric acid.

Goodman, Mark M. (Atlanta, GA); Shoup, Timothy (Decatur, GA)

1998-09-15T23:59:59.000Z

328

Amino acid analogs for tumor imaging  

DOE Patents [OSTI]

The invention provides novel amino acid compounds of use in detecting and evaluating brain and body tumors. These compounds combine the advantageous properties of 1-amino-cycloalkyl-1-carboxylic acids, namely, their rapid uptake and prolonged retention in tumors with the properties of halogen substituents, including certain useful halogen isotopes including fluorine-18, iodine-123, iodine-125, iodine-131, bromine-75, bromine-76, bromine-77 and bromine-82. In one aspect, the invention features amino acid compounds that have a high specificity for target sites when administered to a subject in vivo. Preferred amino acid compounds show a target to non-target ratio of at least 5:1, are stable in vivo and substantially localized to target within 1 hour after administration. An especially preferred amino acid compound is ›.sup.18 F!-1-amino-3-fluorocyclobutane-1-carboxylic acid (FACBC). In another aspect, the invention features pharmaceutical compositions comprised of an .alpha.-amino acid moiety attached to either a four, five, or a six member carbon-chain ring. In addition, the invention features analogs of .alpha.-aminoisobutyric acid.

Goodman, Mark M. (Atlanta, GA); Shoup, Timothy (Decatur, GA)

1998-10-06T23:59:59.000Z

329

Draft Air Pathway Report: Phase 1 of the Hanford Environmental Dose Reconstruction Project  

SciTech Connect (OSTI)

This report summarizes the air pathway portion of the first phase of the Hanford Environmental Dose Reconstruction (HEDR) Project, conducted by Battelle staff at the Pacific Northwest Laboratory under the direction of an independent Technical Steering Panel. The HEDR Project is estimating historical radiation doses that could have been received by populations near the Department of Energy's Hanford Site, in southeastern Washington State. Phase 1 of the air-pathway dose reconstruction sought to determine whether dose estimates could be calculated for populations in the 10 counties nearest the Hanford Site from atmospheric releases of iodine-131 from the site from 1944--1947. Phase 1 demonstrated the following: HEDR-calculated source-term estimates of iodine-131 releases to the atmosphere were within 20% of previously published estimates; calculated vegetation concentrations of iodine-131 agree well with previously published measurements; the highest of the Phase 1 preliminary dose estimates to the thyroid are consistent with independent, previously published estimates of doses to maximally exposed individuals; and relatively crude, previously published measurements of thyroid burdens for Hanford workers are in the range of average burdens that the HEDR model estimated for similar reference individuals'' for the period 1944--1947. 4 refs., 10 figs., 9 tabs.

Not Available

1990-07-20T23:59:59.000Z

330

Use of CAP88 PC to infer differences in the chemical form of I-129 emitted from a fuel reprocessing facility  

SciTech Connect (OSTI)

Emissions of 129I from nuclear fuel separations conducted at the Hanford Site in Washington State have been occurring since the 1940’s. Fuel separation on the Hanford Site stopped in 1988, but emissions of 129I have continued as venting of the building occurred. In this study, atmospheric measurements of 129I concentrations were coupled with an EPA approved plume dispersion model (CAP-88PC) to evaluate the effectiveness of the dispersion model for estimating ambient concentrations at the Hanford Site. This evaluation led to the hypothesis of different chemical forms of iodine being emitted over the years; this hypothesis was developed as an explanation for the model agreeing with measurements over some time periods, but not over all time periods. The model was then run with modified emissions to simulate the short atmospheric half-life of the suspected reactive chemical form of iodine being emitted. This modification resulted in good agreement between the modeled and measured concentrations over the entire 20 year study period, and provided evidence that the hypothesis of a reactive form of iodine being emitted was correct.

Fritz, Brad G.; Phillips, Nathan RJ

2013-06-17T23:59:59.000Z

331

Quality Characteristics of Luffa aegyptiaca seed oil. * 2 1 1 1  

E-Print Network [OSTI]

The oil content and quality characteristics of Luffa aegyptiaca seed oil are described. The straight vegetable oil (SVO) was extracted from the seed using hexane. On a dry matter basis, the oil content was 19-25 % of ground seeds. The quality characteristics of the seed oil were: saponification value (SV), 168mg KOH/g of oil, iodine value (IV), 130g iodine/100g of oil, peroxide value (PV), 280 meq peroxide/kg of oil, free fatty acid (FFA) 10.36 % of oil and acid value (AV) 20.62%. The density of the oil was 0.91g/cm 3 and the specific gravity was 0.92g/ml oil and kinematic viscosity 13.98mm 2 /s at 30 0 C. The saponin content and the unsaponifiable matter of the oil were also determined. The oil quality parameters suggest that the oil may find use as feedstock for biodiesel production. Owing to its iodine value, the oil may also be used in surface coating applications.

O. M Abayeh; I. H Garba; H. M Adamu; O. J Abayeh

332

Features of coal dust dynamics at action of differently oriented forces in granular filtering medium  

E-Print Network [OSTI]

The process of the coal dust particles transportation and structurization in the experimental horizontal model of air filter with the cylindrical coal adsorbent granules as in the iodine air filter at the nuclear power plant is researched. In the investigated case the vector of carrying away force of air flow and the vector of gravitation force are mutually perpendicular, and the scattering of the dust particles on the granules occurs in the normal directions. It is found that the phenomenon of non controlled spontaneous sharp increase of aerodynamic resistance in the iodine air filter under the big integral volumes of filtered air and the big masses of introduced coal dust particles is not observed at the described experimental conditions in distinction from the case of the parallel orientation of this forces as in the vertical iodine air filters at the nuclear power plant. The quantitative measurements of the main parameters of the process of the dust masses transportation and structurization are made on a ...

Neklyudov, I M; Poltinin, P Ya; Ledenyov, O P

2013-01-01T23:59:59.000Z

333

Rapid sonochemical preparation of shape-selective lead iodide  

SciTech Connect (OSTI)

Graphical abstract: SEM morphologies of various PbI2 products obtained with the iodine concentration of 6.7 g/L and irradiation time of 1 minute at the reaction temperatures of 35 °C (a), 25 °C (b), and 15 °C (c). Highlights: ? PbI{sub 2} with various morphologies were rapidly formed at room temperature. ? We could well control the morphologies of PbI{sub 2} by changing reaction conditions. ? The PbI{sub 2} films could better resist rolling in a liquid media. -- Abstract: Lead iodide (PbI{sub 2}) films/crystals with various nano/micro morphologies (e.g., Nanoflake, block and microrod) were rapidly synthesized by taking advantage of a simple sonochemical method. The PbI{sub 2} crystals with uniform nanoflake structures could be fabricated directly on lead foils with the irradiation time as short as 36 s via interfacial reaction between lead foils and elemental iodine in ethanol at ambient temperature. It was found experimentally that the morphologies of the resulting thin films/crystals could be well controlled by the adjustment of several parameters including irradiation time, reaction solvents, iodine concentration, ultrasonic power, and reaction temperature. Most importantly, the resultant PbI{sub 2} films are stable enough to resist rolling under the drastic ultrasound irradiation in a liquid media. This method is believed to be the fastest way for in situ fabrication of morphology-controlled semiconductor films on various metal substrates for subsequent applications related to the other metal iodide or metal sulfide semiconductor films.

Huang, Baojun [Key Laboratory of Micro-Nano Materials for Energy Storage and Conversion of Henan Province, Institute of Surface Micro and Nano Materials, Xuchang University, Xuchang, Henan 461000 (China)] [Key Laboratory of Micro-Nano Materials for Energy Storage and Conversion of Henan Province, Institute of Surface Micro and Nano Materials, Xuchang University, Xuchang, Henan 461000 (China); He, Qin [College of Chemistry and Chemical Engineering, Xuchang University, Xuchang, Henan 461000 (China)] [College of Chemistry and Chemical Engineering, Xuchang University, Xuchang, Henan 461000 (China); Fa, Wenjun; Li, Pinjiang; Zhang, Yange [Key Laboratory of Micro-Nano Materials for Energy Storage and Conversion of Henan Province, Institute of Surface Micro and Nano Materials, Xuchang University, Xuchang, Henan 461000 (China)] [Key Laboratory of Micro-Nano Materials for Energy Storage and Conversion of Henan Province, Institute of Surface Micro and Nano Materials, Xuchang University, Xuchang, Henan 461000 (China); Zheng, Zhi, E-mail: zzheng@xcu.edu.cn [Key Laboratory of Micro-Nano Materials for Energy Storage and Conversion of Henan Province, Institute of Surface Micro and Nano Materials, Xuchang University, Xuchang, Henan 461000 (China)] [Key Laboratory of Micro-Nano Materials for Energy Storage and Conversion of Henan Province, Institute of Surface Micro and Nano Materials, Xuchang University, Xuchang, Henan 461000 (China)

2012-09-15T23:59:59.000Z

334

Quantitative studies of transfer in vivo of low density, Sf 12-60, and Sf 60-400 lipoproteins between plasma and arterial intima in humans  

SciTech Connect (OSTI)

To assess the potential of various plasma lipoprotein classes to contribute to the lipid content of the arterial intima, influx and efflux of these plasma lipoprotein fractions into and from the intima of human carotid arteries were measured in vivo. While low density lipoprotein (LDL) is known to transfer from plasma into the arterial wall, there is less information on the atherogenic potential of lipoproteins of intermediate density (Sf 12-60) or of very low density (Sf 60-400). Aliquots of the same lipoprotein (LDL, Sf 12-60 lipoprotein particles, or Sf 60-400 lipoprotein particles) iodinated with iodine-125 and iodine-131 were injected intravenously 18-29 hours and 3-6 hours, respectively, before elective surgical removal of atheromatous arterial tissue, and the intimal clearance of lipoproteins, lipoprotein influx, and fractional loss of newly entered lipoproteins were calculated. Intimal clearance of Sf 60-400 particles was not detectable (less than 0.3 microliter x hr-1 x cm-2), whereas the average value for both LDL and Sf 12-60 lipoprotein particles was 0.9 microliter x hr-1 x cm-2. Since the fractional loss of newly entered LDL and Sf 12-60 lipoprotein particles was also similar, the results suggest similar modes of entry and exit for these two particles. However, due to lower plasma concentrations of Sf 12-60 lipoproteins as compared with LDL, the mass influx of cholesterol in the Sf 12-60 particles was on the order of one 10th of that in LDL, and that of apolipoprotein B was about one 20th.

Shaikh, M.; Wootton, R.; Nordestgaard, B.G.; Baskerville, P.; Lumley, J.S.; La Ville, A.E.; Quiney, J.; Lewis, B. (Guys Hospital, London, (United Kingdom))

1991-05-01T23:59:59.000Z

335

Refractory for Black Liquor Gasifiers  

SciTech Connect (OSTI)

The University of Missouri-Rolla will identify materials that will permit the safe, reliable and economical operation of combined cycle gasifiers by the pulp and paper industry. The primary emphasis of this project will be to resolve the material problems encountered during the operation of low-pressure high-temperature (LPHT) and low-pressure low-temperature (LPLT) gasifiers while simultaneously understanding the materials barriers to the successful demonstration of high-pressure high-temperature (HPHT) black liquor gasifiers. This study will define the chemical, thermal and physical conditions in current and proposed gasifier designs and then modify existing materials and develop new materials to successfully meet the formidable material challenges. Resolving the material challenges of black liquor gasification combined cycle technology will provide energy, environmental, and economic benefits that include higher thermal efficiencies, up to three times greater electrical output per unit of fuel, and lower emissions. In the near term, adoption of this technology will allow the pulp and paper industry greater capital effectiveness and flexibility, as gasifiers are added to increase mill capacity. In the long term, combined-cycle gasification will lessen the industry's environmental impact while increasing its potential for energy production, allowing the production of all the mill's heat and power needs along with surplus electricity being returned to the grid. An added benefit will be the potential elimination of the possibility of smelt-water explosions, which constitute an important safety concern wherever conventional Tomlinson recovery boilers are operated. Developing cost-effective materials with improved performance in gasifier environments may be the best answer to the material challenges presented by black liquor gasification. Refractory materials may be selected/developed that either react with the gasifier environment to form protective surfaces in-situ; are functionally-graded to give the best combination of thermal, mechanical, and physical properties and chemical stability; or are relatively inexpensive, reliable repair materials. This report covers Task 1.4, Industrial Trial of candidate materials developed by refractory producers and in the laboratory based on the results of Task 1.1, 1.2 and 1.3. Refractories provided by in-kind sponsors to industrial installations tested by cup testing, density/porosity determinations, chemical analysis and microscopy. None of the materials produced in this program have been tried in high temperature gasifiers, but the mortar developed Morcocoat SP-P is outperforming other mortars tested at ORNL. MORCO PhosGun M-90-O has shown in laboratory testing to be an acceptable candidate for hot and cold repairs of existing high temperature gasifiers. It may prove to be an acceptable lining material.

William L. Headrick Jr; Musa Karakus; Xiaoting Laing

2005-10-01T23:59:59.000Z

336

Laser studies of chemical reaction and collision processes  

SciTech Connect (OSTI)

This work has concentrated on several interrelated projects in the area of laser photochemistry and photophysics which impinge on a variety of questions in combustion chemistry and general chemical kinetics. Infrared diode laser probes of the quenching of molecules with {open_quotes}chemically significant{close_quotes} amounts of energy in which the energy transferred to the quencher has, for the first time, been separated into its vibrational, rotational, and translational components. Probes of quantum state distributions and velocity profiles for atomic fragments produced in photodissociation reactions have been explored for iodine chloride.

Flynn, G. [Columbia Univ., New York, NY (United States)

1993-12-01T23:59:59.000Z

337

Engineering Design Elements of a Two-Phase Thermosyphon to Trannsfer NGNP Nuclear Thermal Energy to a Hydrogen Plant  

SciTech Connect (OSTI)

Two hydrogen production processes, both powered by a Next Generation Nuclear Plant (NGNP), are currently under investigation at Idaho National Laboratory. The first is high-temperature steam electrolysis, which uses both heat and electricity; the second is thermo-chemical production through the sulfur iodine process primarily using heat. Both processes require a high temperature (>850°C) for enhanced efficiency; temperatures indicative of the NGNP. Safety and licensing mandates prudently dictate that the NGNP and the hydrogen production facility be physically isolated, perhaps requiring separation of over 100 m.

Piyush Sabharwal

2009-07-01T23:59:59.000Z

338

Beneficial effects of dietary L-arginine supplementation to diabetic rats  

E-Print Network [OSTI]

of Fukushima and Nixon (64). EC were lysed in 0.3 ml of 0.1 M phosphoric acid containing 5mM dithioerythritol (an antioxidant) and 35ul of 2M trichloroacetic acid. Cell debris was removed by centrifugation. Extracts were oxidized with acidic or basic iodine... release of endothelium-derived constricting factors (17); or (3) decreased release or production of nitric oxide (NO) (13,18). Hyperglycemia contributes directly to above mentioned factors and thus to endothelial dysfunction. There is substantial...

Kohli, Ripla

2004-09-30T23:59:59.000Z

339

Assessment of Neptunium, Americium, and Curium in the Savannah River Site Environment  

SciTech Connect (OSTI)

A series of documents has been published in which the impact of various radionuclides released to the environment by Savannah River Site (SRS) operations has been assessed. The quantity released, the disposition of the radionuclides in the environment, and the dose to offsite individuals has been presented for activation products, carbon cesium, iodine, plutonium, selected fission products, strontium, technetium, tritium, uranium, and the noble gases. An assessment of the impact of nonradioactive mercury also has been published.This document assesses the impact of radioactive transuranics released from SRS facilities since the first reactor became operational late in 1953. The isotopes reported here are 239Np, 241Am, and 244Cm.

Carlton, W.H. [Westinghouse Savannah River Company, AIKEN, SC (United States)

1997-12-17T23:59:59.000Z

340

Cork Embedded Internal Features and Contrast Mechanisms with Del Using 18, 20, 30, 36 and 40 keV Synchrotron X-rays  

SciTech Connect (OSTI)

Images of the cork used for wine and other bottles are visualized with the use of diffraction-enhanced imaging (DEI) technique. Present experimental studies allowed us to identify the cracks, holes, porosity, and importance of soft-matter (soft-material) and associated biology by visualization of the embedded internal complex features of the biological material such as cork and its microstructure. Highlighted the contrast mechanisms above and below the K-absorption edge of iodine and studied the attenuation through a combination of weakly and strongly attenuating materials.

Rao, D.V.; Zhong, Z.; Akatsuka, T.; Yuasa, T.; Hasan, M.Z.; Takeda, T.

2010-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "iodine phos phorus" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Temporal and spectral imaging with micro-CT  

SciTech Connect (OSTI)

Purpose: Micro-CT is widely used for small animal imaging in preclinical studies of cardiopulmonary disease, but further development is needed to improve spatial resolution, temporal resolution, and material contrast. We present a technique for visualizing the changing distribution of iodine in the cardiac cycle with dual source micro-CT. Methods: The approach entails a retrospectively gated dual energy scan with optimized filters and voltages, and a series of computational operations to reconstruct the data. Projection interpolation and five-dimensional bilateral filtration (three spatial dimensions + time + energy) are used to reduce noise and artifacts associated with retrospective gating. We reconstruct separate volumes corresponding to different cardiac phases and apply a linear transformation to decompose these volumes into components representing concentrations of water and iodine. Since the resulting material images are still compromised by noise, we improve their quality in an iterative process that minimizes the discrepancy between the original acquired projections and the projections predicted by the reconstructed volumes. The values in the voxels of each of the reconstructed volumes represent the coefficients of linear combinations of basis functions over time and energy. We have implemented the reconstruction algorithm on a graphics processing unit (GPU) with CUDA. We tested the utility of the technique in simulations and applied the technique in an in vivo scan of a C57BL/6 mouse injected with blood pool contrast agent at a dose of 0.01 ml/g body weight. Postreconstruction, at each cardiac phase in the iodine images, we segmented the left ventricle and computed its volume. Using the maximum and minimum volumes in the left ventricle, we calculated the stroke volume, the ejection fraction, and the cardiac output. Results: Our proposed method produces five-dimensional volumetric images that distinguish different materials at different points in time, and can be used to segment regions containing iodinated blood and compute measures of cardiac function. Conclusions: We believe this combined spectral and temporal imaging technique will be useful for future studies of cardiopulmonary disease in small animals.

Johnston, Samuel M.; Johnson, G. Allan; Badea, Cristian T. [Center for In Vivo Microscopy, Duke University Medical Center, Durham, North Carolina 27710 (United States)

2012-08-15T23:59:59.000Z

342

Measurement of Fukushima Aerosol Debris in Sequim and Richland, WA and Ketchikan, AK  

SciTech Connect (OSTI)

Aerosol collections were initiated at several locations by PNNL shortly after the Great East Japan Earthquake of May 2011. Aerosol samples were transferred to laboratory high-resolution gamma spectrometers for analysis. Similar to treaty monitoring stations operating across the Northern hemisphere, iodine and other isotopes which could be volatilized at high temperature were detected. Though these locations are not far apart, they have significant variations with respect to water, mountain-range placement, and local topography. Variation in computed source terms will be shown to bound the variability of this approach to source estimation.

Miley, Harry S.; Bowyer, Ted W.; Engelmann, Mark D.; Eslinger, Paul W.; Friese, Judah I.; Greenwood, Lawrence R.; Haas, Derek A.; Hayes, James C.; Keillor, Martin E.; Kiddy, Robert A.; Kirkham, Randy R.; Landen, Jonathan W.; Lepel, Elwood A.; Lidey, Lance S.; Litke, Kevin E.; Morris, Scott J.; Olsen, Khris B.; Thompson, Robert C.; Valenzuela, Blandina R.; Woods, Vincent T.; Biegalski, Steven R.

2013-05-01T23:59:59.000Z

343

Effect of mixing on polymerization of styrene  

E-Print Network [OSTI]

Model R404 Differential Refractometer (DRI) was used to continuously monitor the reactor effluent. A portion of the liquid medium from the feed tank was used as a static reference in the DRI. To introduce a change in the refractive index of the fluid... the mixing pattern was made by desolving iodine crystals in the styrene used for pulse generation. A strobotact was used to monitor the rpm of the impeller shaft. To reduce the amount of degassing occurring in the reactor during the runs, the liquid...

Treybig, Michael Norris

2012-06-07T23:59:59.000Z

344

Quarterly report for Oak Ridge Enrichment Technical Support (ETS), October--December 1993  

SciTech Connect (OSTI)

Reported topics include: a model to compute CFC-114 inventory in the cooling systems at the GDP`s, an analysis of Paducah recycle cooler performance test data operating with C{sub 4}F{sub 10}, estimation of Portsmouth in-process test cell coolant system performance, cascade equipment reliability, separation measurements in the single stage separation system, SOLGAS user`s manual, conversion of waste gases, recycling of HF, replacement coolants containing iodine, various aspects of UF{sub 6} coolant mixtures.

Higgins, R.L.

1994-03-01T23:59:59.000Z

345

Effects of membrane fluidity on hormone action in cultured cells  

E-Print Network [OSTI]

av intracellular protein degradation, while growth of the Wt cell line in cholesterol-free media resulted in an increased effectiveness of only 10% serum. The control rates of protein synthesis are increased in the Wt when grown in either 100PN... ue 12 Procedure for Measurin Rates of Protein Degradation 13 Procedure for Measurin Rates of Protein S nthesis 15 Procedure for Measurin Rates of C-2-deo glucose U take 14 16 Procedure for Iodination of Porcine Insulin 17 Procedure for Measuring...

Williams, Gary Wayne

1982-01-01T23:59:59.000Z

346

Electrochemical cell  

DOE Patents [OSTI]

An electrochemical cell is described having an alkali metal negative electrode such as sodium and a positive electrode including Ni or transition metals, separated by a [beta] alumina electrolyte and NaAlCl[sub 4] or other compatible material. Various concentrations of a bromine, iodine and/or sulfur containing additive and pore formers are disclosed, which enhance cell capacity and power. The pore formers may be the ammonium salts of carbonic acid or a weak organic acid or oxamide or methylcellulose. 6 figs.

Redey, L.I.; Vissers, D.R.; Prakash, J.

1994-08-23T23:59:59.000Z

347

Studies on the Use of Liquid Surface Passivation for Lifetime Measurements on Good-Quality Silicon Wafers  

SciTech Connect (OSTI)

We evaluated several liquid passivants, viz. solutions of iodine ethanol (IE), quinhydrone methanol (QHM), and potassium cyanide (KCN), for measuring minority-carrier lifetime. Lifetime was measured by the WCT-100 (Sinton Instruments) and WT-2000 (Semilab). Our results show that both IE and QHM passivation are reliable mechanisms. We also find that the KCN solution is moderately passivating on oxidized surfaces, but is only minimally effective on bare Si surfaces. This paper presents details of our studies. In particular, the effect of illumination on IE-passivated surfaces and possible reasons for variations in lifetime measurement are discussed.

Devayajanam, S.; Rupnowski, P.; Shet, S.; Sopori, B. L.; Ravindra, N. M.; Caskey, D.; Chang, J.; Covington, J.

2011-01-01T23:59:59.000Z

348

A study of the effect and efficiency of germicides on bacteria that produce ropiness in bread  

E-Print Network [OSTI]

~ while the other oentalnsd 53$ avallabls chlorine. The formaldehyde content of the ooaasrcisl foraslin eaploysd was deteralned by oxldising the foraaldebyde ~ contained ln 5. 0 c. o. of a 1. 0$ aqueous solution of the foraalln, to foraic acid with 40..., . ~~QIBI (Van graengsa) Holland is not sterilised ly Q chroaio soid, 0. 1+ iodine, or ~ formaldehyde when sub/ected to these agents at 37 G i'or one hoar. 9KggaLaia Suspensions of spores for death rate studies vers prepared as seeded from ths stock...

Ashby, Gerald K

1937-01-01T23:59:59.000Z

349

Technical basis for internal dosimetry at Hanford  

SciTech Connect (OSTI)

The Hanford Internal Dosimetry Program, administered by Pacific Northwest Laboratory for the US Department of Energy, provides routine bioassay monitoring for employees who are potentially exposed to radionuclides in the workplace. This report presents the technical basis for routine bioassay monitoring and the assessment of internal dose at Hanford. The radionuclides of concern include tritium, corrosion products (/sup 58/Co, /sup 60/Co, /sup 54/Mn, and /sup 59/Fe), strontium, cesium, iodine, europium, uranium, plutonium, and americium. Sections on each of these radionuclides discuss the sources and characteristics; dosimetry; bioassay measurements and monitoring; dose measurement, assessment, and mitigation; and bioassay follow-up treatment. 64 refs., 42 figs., 118 tabs.

Sula, M.J.; Carbaugh, E.H.; Bihl, D.E.

1989-04-01T23:59:59.000Z

350

Technical basis for internal dosimetry at Hanford  

SciTech Connect (OSTI)

The Hanford Internal Dosimetry Program, administered by Pacific Northwest Laboratory for the US Department of Energy, provides routine bioassay monitoring for employees who are potentially exposed to radionuclides in the workplace. This report presents the technical basis for routine bioassay monitoring and the assessment of internal dose at Hanford. The radionuclides of concern include tritium, corrosion products ({sup 58}Co, {sup 60}Co, {sup 54}Mn, and {sup 59}Fe), strontium, cesium, iodine, europium, uranium, plutonium, and americium,. Sections on each of these radionuclides discuss the sources and characteristics; dosimetry; bioassay measurements and monitoring; dose measurement, assessment, and mitigation and bioassay follow-up treatment. 78 refs., 35 figs., 115 tabs.

Sula, M.J.; Carbaugh, E.H.; Bihl, D.E.

1991-07-01T23:59:59.000Z

351

Recent MELCOR and VICTORIA Fission Product Research at the NRC  

SciTech Connect (OSTI)

The MELCOR and VICTORIA severe accident analysis codes, which were developed at Sandia National Laboratories for the U. S. Nuclear Regulatory Commission, are designed to estimate fission product releases during nuclear reactor accidents in light water reactors. MELCOR is an integrated plant-assessment code that models the key phenomena in adequate detail for risk-assessment purposes. VICTORIA is a more specialized fission- product code that provides detailed modeling of chemical reactions and aerosol processes under the high-temperature conditions encountered in the reactor coolant system during a severe reactor accident. This paper focuses on recent enhancements and assessments of the two codes in the area of fission product chemistry modeling. Recently, a model for iodine chemistry in aqueous pools in the containment building was incorporated into the MELCOR code. The model calculates dissolution of iodine into the pool and releases of organic and inorganic iodine vapors from the pool into the containment atmosphere. The main purpose of this model is to evaluate the effect of long-term revolatilization of dissolved iodine. Inputs to the model include dose rate in the pool, the amount of chloride-containing polymer, such as Hypalon, and the amount of buffering agents in the containment. Model predictions are compared against the Radioiodine Test Facility (RTF) experiments conduced by Atomic Energy of Canada Limited (AECL), specifically International Standard Problem 41. Improvements to VICTORIA's chemical reactions models were implemented as a result of recommendations from a peer review of VICTORIA that was completed last year. Specifically, an option is now included to model aerosols and deposited fission products as three condensed phases in addition to the original option of a single condensed phase. The three-condensed-phase model results in somewhat higher predicted fission product volatilities than does the single-condensed-phase model. Modeling of U02 thermochemistry was also improved, and results in better prediction of vaporization of uranium from fuel, which can react with released fission products to affect their volatility. This model also improves the prediction of fission product release rates from fuel. Finally, recent comparisons of MELCOR and VICTORIA with International Standard Problem 40 (STORM) data are presented. These comparisons focus on predicted therrnophoretic deposition, which is the dominant deposition mechanism. Sensitivity studies were performed with the codes to examine experimental and modeling uncertainties.

Bixler, N.E.; Cole, R.K.; Gauntt, R.O.; Schaperow, J.H.; Young, M.F.

1999-01-21T23:59:59.000Z

352

Radioiodine Biogeochemistry and Prevalence in Groundwater  

SciTech Connect (OSTI)

129I is commonly either the top or among the top risk drivers, along with 99Tc, at radiological waste disposal sites and contaminated groundwater sites where nuclear material fabrication or reprocessing has occurred. The risk stems largely from 129I having a high toxicity, a high bioaccumulation factor (90% of all the body’s iodine concentrates in the thyroid), a high inventory at source terms (due to its high fission yield), an extremely long half-life (16M yr), and rapid mobility in the subsurface environment. Another important reason that 129I is a key risk driver is that there is the uncertainty regarding its biogeochemical fate and transport in the environment. We typically can define 129I mass balance and flux at sites, but cannot predict accurately its response to changes in the environment. As a consequence of some of these characteristics, 129I has a very low Drinking Water Standard, DWS, which is set at 1 pCi/L, the lowest of all radionuclides in the Federal Register. Recently, significant advancements have been made in detecting iodine species at ambient groundwater concentrations, defining the nature of the organic matter and iodine bond, and quantifying the role of naturally occurring sediment microbes to promote iodine oxidation and reduction. These recent studies have led to a more mechanistic understanding of radioiodine biogeochemistry. The objective of this review is to describe these advances and to provide a state of the science of radioiodine biogeochemistry relevant to its fate and transport in the terrestrial environment and provide information useful for making decisions regarding the stewardship and remediation of 129I contaminated sites. As part of this review, knowledge gaps were identified that would significantly advance the goals of basic and applied research programs for accelerating 129I environmental remediation and reducing uncertainty associated with disposal of 129I waste. Together the information gained from addressing these knowledge gaps will not alter the observation that 129I is primarily mobile, but it will likely permit demonstration that the entire 129I pool in the source term is not moving at the same rate and some may be tightly bound to the sediment, thereby “smearing” the modeled 129I peak and reducing maximum calculated risk.

Kaplan, Daniel I.; Denham, Miles E.; Zhang, Saijin; Yeager, Chris; Xu, Chen; Schwehr, Kathy; Li, Hsiu-Ping; Ho, Yi-Fang; Wellman, Dawn M.; Santschi, Peter H.

2014-08-03T23:59:59.000Z

353

Method for the recovery of silver from silver zeolite  

DOE Patents [OSTI]

High purity silver is recovered from silver exchanged zeolite used to capture radioactive iodine from nuclear reactor and nuclear fuel reprocessing environments. The silver exchanged zeolite is heated with slag formers to melt and fluidize the zeolite and release the silver, the radioactivity removing with the slag. The silver containing metallic impurities is remelted and treated with oxygen and a flux to remove the metal impurities. About 98% of the silver in the silver exchanged zeolite having a purity of 99% or better is recoverable by the method.

Reimann, G.A.

1985-03-05T23:59:59.000Z

354

Fallout: The experiences of a medical team in the care of a Marshallese population accidentally exposed to fallout radiation  

SciTech Connect (OSTI)

This report presents an historical account of the experiences of the Brookhaven Medical team in the examination and treatment of the Marshallese people following their accidental exposure to radioactive fallout in 1954. This is the first time that a population has been heavily exposed to radioactive fallout, and even though this was a tragic mishap, the medical findings have provided valuable information for other accidents involving fallout such as the recent reactor accident at Chernobyl. Particularly important has been the unexpected importance of radioactive iodine in the fallout in producing thyroid abnormalities.

Conard, R.A.

1991-01-01T23:59:59.000Z

355

Fallout: The experiences of a medical team in the care of a Marshallese population accidentally exposed to fallout radiation  

SciTech Connect (OSTI)

This report presents an historical account of the experiences of the Brookhaven Medical team in the examination and treatment of the Marshallese people following their accidental exposure to radioactive fallout in 1954. This is the first time that a population has been heavily exposed to radioactive fallout, and even though this was a tragic mishap, the medical findings have provided valuable information for other accidents involving fallout such as the recent reactor accident at Chernobyl. Particularly important has been the unexpected importance of radioactive iodine in the fallout in producing thyroid abnormalities.

Conard, R.A.

1991-12-31T23:59:59.000Z

356

Fallout: The experiences of a medical team in the care of a Marshallese population accidently exposed to fallout radiation  

SciTech Connect (OSTI)

This report presents an historical account of the experiences of the Brookhaven Medical Team in the examination and treatment of the Marshallese people following their accidental exposure to radioactive fallout in 1954. This is the first time that a population has been heavily exposed to radioactive fallout, and even though this was a tragic mishap, the medical findings have provided valuable information for other accidents involving fallout such as the recent reactor accident at Chernobyl. Noteworthy has been the unexpected importance of radioactive iodine in the fallout in producing thyroid abnormalities.

Conard, R.A.

1992-09-01T23:59:59.000Z

357

Los Alamos Air Monitoring Data Related to the Fukushima Daiichi Reactor  

SciTech Connect (OSTI)

In response to the disasters in Japan on March 11, 2011, Los Alamos National Laboratory (LANL) is collecting air data and analyzing the data for fission products. At present, we report preliminary data from three high-volume air samplers and one stack sampler. Iodine-131 (I-131) is not optimally measured by our standard polypropylene filters. In addition to the filter data, we have one measurement obtained from a charcoal cartridge. These data, together with measurements of other radionuclides are adequate for a preliminary assessment and assure us that radionuclides from Fukushima Daiichi do not present a threat to human health at or near Los Alamos.

McNaughton, Michael [Los Alamos National Laboratory

2011-01-01T23:59:59.000Z

358

Environmental radiation data report 80, October-December 1994. Final report  

SciTech Connect (OSTI)

Environmental Radiation Data (ERD) contains data from the Environmental Radiation Ambient Monitoring System (ERAMS). Sampling locations are selected to provide optimal population coverage while functioning to monitor fallout from nuclear devices and other forms of radioactive contamination of the environment. The radiation analyses performed on these samples include gross alpha and gross beta levels, gamma analyses for fission products, and specific analyses for uranium, plutonium, stronthium, iodine, radium, and tritium. This monitoring effort also provides ancillary information on natural background levels and on routine and accidental releases into the environment from stationary sources.

NONE

1997-02-01T23:59:59.000Z

359

Environmental radiation data report 73, January-March 1993. Quarterly report  

SciTech Connect (OSTI)

Environmental Radiation Data (ERD) contains data from the Environmental Radiation Ambients Monitoring System (ERAMS). The ERAMS is comprised of nationwide sampling stations that provide air, surface and drinking water and milk samples from which environmental radiation levels are derived. Sampling locations are selected to provide optimal population coverage while functioning to monitor fallout from nuclear devices and other forms of radioactive contamination of the environment. The radiation analyses performed on these samples include gross alpha and gross beta levels, gamma analyses for fission products, and specific analyses for uranium, plutonium, strontium, iodine, radium, krypton, and tritium.

Not Available

1993-10-01T23:59:59.000Z

360

Environmental radiation data report 79, July-September 1994. Final report  

SciTech Connect (OSTI)

Environmental Radiation Data (ERD) contains data from the Environmental Radiation Ambient Monitoring System (ERAMS). Sampling locations are selected to provide optimal population coverage while functioning to monitor fallout from nuclear devices and other forms of radioactive contamination of the environment. The radiation analyses performed on these samples include gross alpha and gross beta levels, gamma analyses for fission products, and specific analyses for uranium, plutonium, stronthium, iodine, radium, and tritium. This monitoring effort also provides ancillary information on natural background levels and on routine and accidental releases into the environment from stationary sources.

NONE

1997-02-01T23:59:59.000Z

Note: This page contains sample records for the topic "iodine phos phorus" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Environmental radiation data report 81, January-March 1995. Final report  

SciTech Connect (OSTI)

Environmental Radiation Data (ERD) contains data from the Environmental Radiation Ambient Monitoring System (ERAMS). Sampling locations are selected to provide optimal population coverage while functioning to monitor fallout from nuclear devices and other forms of radioactive contamination of the environment. The radiation analyses performed on these samples include gross alpha and gross beta levels, gamma analyses for fission products, and specific analyses for uranium, plutonium, stronthium, iodine, radium, and tritium. This monitoring effort also provides ancillary information on natural background levels and on routine and accidental releases into the environment from stationary sources.

NONE

1997-02-01T23:59:59.000Z

362

Environmental radiation data report 82, April-June 1995. Final report  

SciTech Connect (OSTI)

Environmental Radiation Data (ERD) contains data from the Environmental Radiation Ambient Monitoring System (ERAMS). Sampling locations are selected to provide optimal population coverage while functioning to monitor fallout from nuclear devices and other forms of radioactive contamination of the environment. The radiation analyses performed on these samples include gross alpha and gross beta levels, gamma analyses for fission products, and specific analyses for uranium, plutonium, stronthium, iodine, radium, and tritium. This monitoring effort also provides ancillary information on natural background levels and on routine and accidental releases into the environment from stationary sources.

NONE

1997-02-01T23:59:59.000Z

363

Iodide Sorption to Clays and the Relationship to Surface Charge and Clay Texture - 12356  

SciTech Connect (OSTI)

Iodine is assumed to behave conservatively in clay barriers around nuclear waste repositories and in natural sediments. Batch experiments tend to show little to no sorption, while in column experiments iodine is often retarded relative to tritiated water. Current surface complexation theory cannot account for negatively charged ion sorption to a negatively charged clay particle. Surface protonation and iodide sorption to clay minerals were examined using surface titrations and batch sorption experiments with a suite of clay minerals. Surface titrations were completed spanning a range of both pH values and ionic strengths. For reference, similar titrations were performed on pure forms of an Al-O powder. The titration curves were deconvoluted to attain the pKa distribution for each material at each ionic strength. The pKa distribution for the Al-O shows two distinct peaks at 4.8 and 7.5, which are invariant with ionic strength. The pKa distribution of clays was highly variable between the different minerals and as a function of ionic strength. Iodide sorption experiments were completed at high solid:solution ratios to exacerbate sorption properties. Palygorskite and kaolinite had the highest amount of iodide sorption and montmorillonite had the least. (authors)

Miller, Andrew; Kruichiak, Jessica; Tellez, Hernesto; Wang, Yifeng [Sandia National Laboratories, Albuquerque, NM 87185 (United States)

2012-07-01T23:59:59.000Z

364

In situ monitoring of electrochemically induced roughening with the crystal truncation rod technique  

SciTech Connect (OSTI)

We have employed the crystal truncation rod technique to monitor (in situ) the electrochemically induced roughening of a Pt(111) electrode pretreated with a chemisorbed layer of iodine. We find that for the electrode as prepared (both in air and in contact with an electrolyte solution at the rest potential) the surface is best described by one that has an rms roughness of 3.30 {plus_minus} 0.3 {angstrom} and where the atoms that are displaced from a perfectly truncated lattice still occupy lattice positions. Reductive desorption of the iodine adlayer at {minus}0.90 V does not alter the interfacial roughness. However, the application of a potential of +1.0 V for 15 min results on a significantly rougher interface. In this case the roughness due to displaced atoms occupying lattice positions is 3.35 {plus_minus} 0.34 {angstrom}, and there is also a second contribution to the roughness that can be described in terms of a Debye-Walker factor and which contributes an additional roughness of 2.05 {plus_minus} 0.25 {angstrom}. 19 refs., 4 figs.

Bommarito, G.M.; Acevedo, D.; Abruna, H.D. [Cornell Univ., Ithaca, NY (United States)

1992-04-16T23:59:59.000Z

365

MERCURY CONTAMINATED MATERIAL DECONTAMINATION METHODS: INVESTIGATION AND ASSESSMENT  

SciTech Connect (OSTI)

Over the years mercury has been recognized as having serious impacts on human health and the environment. This recognition has led to numerous studies that deal with the properties of various mercury forms, the development of methods to quantify and speciate the forms, fate and transport, toxicology studies, and the development of site remediation and decontamination technologies. This report reviews several critical areas that will be used in developing technologies for cleaning mercury from mercury-contaminated surfaces of metals and porous materials found in many DOE facilities. The technologies used for decontamination of water and mixed wastes (solid) are specifically discussed. Many technologies that have recently appeared in the literature are included in the report. Current surface decontamination processes have been reviewed, and the limitations of these technologies for mercury decontamination are discussed. Based on the currently available technologies and the processes published recently in the literature, several processes, including strippable coatings, chemical cleaning with iodine/iodide lixiviant, chemisorbing surface wipes with forager sponge and grafted cotton, and surface/pore fixation through amalgamation or stabilization, have been identified as potential techniques for decontamination of mercury-contaminated metal and porous surfaces. Their potential merits and applicability are discussed. Finally, two processes, strippable coatings and chemical cleaning with iodine/iodide lixiviant, were experimentally investigated in Phase II of this project.

M.A. Ebadian, Ph.D.

2001-01-01T23:59:59.000Z

366

Status of radioiodine control for nuclear fuel reprocessing plants  

SciTech Connect (OSTI)

This report summarizes the status of radioiodine control in a nuclear fuel reprocessing plant with respect to capture, fixation, and disposal. Where possible, we refer the reader to a number of survey documents which have been published in the last four years. We provide updates where necessary. Also discussed are factors which must be considered in developing criteria for iodine control. For capture from gas streams, silver mordenite and a silver nitrate impregnated silica (AC-6120) are considered state-of-the-art and are recommended. Three aqueous scrubbing processes have been demonstrated: Caustic scrubbing is simple but probably will not give an adequate iodine retention by itself. Mercurex (mercuric nitrate-nitric acid scrubbing) has a number of disadvantages including the use of toxic mercury. Iodox (hyperazeotropic nitric acid scrubbing) is effective but employs a very corrosive and hazardous material. Other technologies have been tested but require extensive development. The waste forms recommended for long-term storage or disposal are silver iodide, the iodates of barium, strontium, or calcium, and silver loaded sorbents, all fixed in cement. Copper iodide in bitumen (asphalt) is a possibility but requires testing. The selection of a specific form will be influenced by the capture process used.

Burger, L.L.; Scheele, R.D.

1983-07-01T23:59:59.000Z

367

Nuclear medicine program progress report for quarter ending March 31, 1991  

SciTech Connect (OSTI)

In this report the first fabrication and evaluation of an activated carbon-based osmium-194/iridium-194 generator system is described. Iridium-194 (t{sub {1/2}} = 19.2 h) decays by {Beta}{sup {minus}} emission (E{sub max} = 2.24 MeV) and is a potential candidate for radioimmunotherapy. An important characteristic is availability of {sup 194}Ir from decay of reactor-produced {sup 194}Os (t{sub {1/2}} = 6 y). A novel gas thermochromatographic method was developed for the one step conversion of metallic Os to OsO{sub 4} and subsequent separation and purification of OsO{sub 4}, which was then converted to the K{sub 2}OsCl{sub 6} for generator loading. The yield and the elution profile of carrier-free {sup 194}Ir, and {sup 194}Os breakthrough were determined for a prototype generator which was evaluated over a 10 month-period.l During this period several agents were also supplied to Medical Cooperative investigators, including iodine-123-labelled and iodine-125-labelled fatty acid analogues for studies at the Brookhaven National Laboratory. In addition, gold-198 and tungsten-188/-rhenium-188 generators were shipped to various investigators for therapeutic studies involving tumor-specific antibodies. 19 refs., 3 figs.

Knapp, F.F. Jr.; Ambrose, K.R.; Callahan, A.P.; McPherson, D.W.; Mirzadeh, S.; Srivastava, P.C.; Allred, J.F.; Hasan, A.; Lambert, C.R.; Lambert, S.J.; Rice, D.E.

1991-08-01T23:59:59.000Z

368

Life cycle assessment of hydrogen production from S-I thermochemical process coupled to a high temperature gas reactor  

SciTech Connect (OSTI)

The purpose of this paper is to quantify the greenhouse gas (GHG) emissions associated to the hydrogen produced by the sulfur-iodine thermochemical process, coupled to a high temperature nuclear reactor, and to compare the results with other life cycle analysis (LCA) studies on hydrogen production technologies, both conventional and emerging. The LCA tool was used to quantify the impacts associated with climate change. The product system was defined by the following steps: (i) extraction and manufacturing of raw materials (upstream flows), (U) external energy supplied to the system, (iii) nuclear power plant, and (iv) hydrogen production plant. Particular attention was focused to those processes where there was limited information from literature about inventory data, as the TRISO fuel manufacture, and the production of iodine. The results show that the electric power, supplied to the hydrogen plant, is a sensitive parameter for GHG emissions. When the nuclear power plant supplied the electrical power, low GHG emissions were obtained. These results improve those reported by conventional hydrogen production methods, such as steam reforming. (authors)

Giraldi, M. R.; Francois, J. L.; Castro-Uriegas, D. [Departamento de Sistemas Energeticos, Facultad de Ingenieria, Universidad Nacional Autonoma de Mexico, Paseo Cuauhnahuac No. 8532, Col. Progreso, C.P. 62550, Jiutepec, Morelos (Mexico)

2012-07-01T23:59:59.000Z

369

Milk cow feed intake and milk production and distribution estimates for Phase 1  

SciTech Connect (OSTI)

This report provides initial information on milk production and distribution in the Hanford Environmental Dose Reconstruction (HEDR) Project Phase I study area. The Phase I study area consists of eight countries in central Washington and two countries in northern Oregon. The primary objective of the HEDR Project is to develop estimates of the radiation doses populations could have received from Hanford operations. The objective of Phase I of the project was to determine the feasibility of reconstructing data, models, and development of preliminary dose estimates received by people living in the ten countries surrounding Hanford from 1944 to 1947. One of the most important contributors to radiation doses from Hanford during the period of interest was radioactive iodine. Consumption of milk from cows that ate vegetation contaminated with iodine is likely the dominant pathway of human exposure. To estimate the doses people could have received from this pathway, it is necessary to estimate the amount of milk that the people living in the Phase I area consumed, the source of the milk, and the type of feed that the milk cows ate. The objective of the milk model subtask is to identify the sources of milk supplied to residents of each community in the study area as well as the sources of feeds that were fed to the milk cows. In this report, we focus on Grade A cow's milk (fresh milk used for human consumption).

Beck, D.M.; Darwin, R.F.; Erickson, A.R.; Eckert, R.L.

1992-04-01T23:59:59.000Z

370

Thermochemical water-splitting cycle, bench-scale investigations and process engineering. Annual report, October 1, 1978-September 30, 1979  

SciTech Connect (OSTI)

A program to investigate thermochemical water splitting has been under way at General Atomic Company (GA) since October 1972. This document is an annual progress report of Department of Energy (DOE) sponsored process development work on the GA sulfur-iodine thermochemical water splitting cycle. The work consisted of laboratory bench-scale investigations, demonstration of the process in a closed-loop cycle demonstrator, and process engineering design studies. A bench-scale system, consisting of three subunits, has been designed to study the cycle under continuous flow conditions. The designs of subunit I, which models the main solution reaction and product separation, and subunit II, which models the concentration and decomposition of sulfuric acid, were presented in an earlier annual report. The design of subunit III, which models the purification and decomposition of hydrogen iodide, is given in this report. Progress on the installation and operation of subunits I and II is described. A closed-loop cycle demonstrator was installed and operated based on a DOE request. Operation of the GA sulfur-iodine cycle was demonstrated in this system under recycle conditions. The process engineering addresses the flowsheet design of a large-scale production process consisting of four chemical sections (I through IV) and one helium heat supply section (V). The completed designs for sections I through V are presented. The thermal efficiency of the process calculated from the present flowsheet is 47%.

Caprioglio, G.; McCorkle, K.H.; Besenbruch, G.E.; Rode, J.S.

1980-03-01T23:59:59.000Z

371

Decay dynamics of nascent acetonitrile and nitromethane dipole-bound anions produced by intracluster charge-transfer  

SciTech Connect (OSTI)

Decay dynamics of nascent dipole bound states of acetonitrile and nitromethane are examined using time-resolved photoelectron imaging of iodide-acetonitrile (I{sup ?}·CH{sub 3}CN) and iodide-nitromethane (I{sup ?}·CH{sub 3}NO{sub 2}) complexes. Dipole-bound anions are created by UV-initiated electron transfer to the molecule of interest from the associated iodide ion at energies just below the vertical detachment energy of the halide-molecule complex. The acetonitrile anion is observed to decay biexponentially with time constants in the range of 4–900 ps. In contrast, the dipole bound state of nitromethane decays rapidly over 400 fs to form the valence bound anion. The nitromethane valence anion species then decays biexponentially with time constants of 2 ps and 1200 ps. The biexponential decay dynamics in acetonitrile are interpreted as iodine atom loss and autodetachment from the excited dipole-bound anion, followed by slower autodetachment of the relaxed metastable ion, while the dynamics of the nitromethane system suggest that a dipole-bound anion to valence anion transition proceeds via intramolecular vibrational energy redistribution to nitro group modes in the vicinity of the iodine atom.

Yandell, Margaret A.; King, Sarah B. [Department of Chemistry, University of California, Berkeley, California 94720 (United States)] [Department of Chemistry, University of California, Berkeley, California 94720 (United States); Neumark, Daniel M., E-mail: dneumark@berkeley.edu [Department of Chemistry, University of California, Berkeley, California 94720 (United States); Chemical Sciences Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States)

2014-05-14T23:59:59.000Z

372

End-of-life destructive examination of light water breeder reactor fuel rods (LWBR Development Program)  

SciTech Connect (OSTI)

Destructive examination of 12 representative Light Water Breeder Reactor fuel rods was performed following successful operation in the Shippingport Atomic Power Station for 29,047 effective full power hours, about five years. Light Water Breeder Reactor fuel rods were unique in that the thorium oxide and uranium-233 oxide fuel was contained within Zircaloy-4 cladding. Destructive examinations included analysis of released fission gas; chemical analysis of the fuel to determine depletion, iodine, and cesium levels; chemical analysis of the cladding to determine hydrogen, iodine, and cesium levels; metallographic examination of the cladding, fuel, and other rod components to determine microstructural features and cladding corrosion features; and tensile testing of the irradiated cladding to determine mechanical strength. The examinations confirmed that Light Water Breeder Reactor fuel rod performance was excellent. No evidence of fuel rod failure was observed, and the fuel operating temperature was low (below 2580/sup 0/F at which an increased percentage of fission gas is released). 21 refs., 80 figs., 20 tabs.

Richardson, K.D.

1987-10-01T23:59:59.000Z

373

Thyroid absorbed dose for people at Rongelap, Utirik, and Sifo on March 1, 1954  

SciTech Connect (OSTI)

A study was undertaken to reexamine thyroid absorbed dose estimates for people accidentally exposed to fallout at Rongelap, Sifo, and Utirik Islands from the Pacific weapon test known as Operation Castle BRAVO. The study included: (1) reevaluation of radiochemical analysis, to relate results from pooled urine to intake, retention, and excretion functions; (2) analysis of neutron-irradiation studies of archival soil samples, to estimate areal activities of the iodine isotopes; (3) analysis of source term, weather data, and meteorological functions used in predicting atmospheric diffusion and fallout deposition, to estimate airborne concentrations of the iodine isotopes; and (4) reevaluation of radioactive fallout, which contaminated a Japanese fishing vessel in the vicinity of Rongelap Island on March 1, 1954, to determine fallout components. The conclusions of the acute exposure study were that the population mean thyroid absorbed doses were 21 gray (2100 rad) at Rongelap, 6.7 gray (670 rad) at Sifo, and 2.8 gray (280 rad) at Utirik. The overall thyroid cancer risk we estimated was in agreement with results published on the Japanese exposed at Nagasaki and Hiroshima. We now postulate that the major route for intake of fallout was by direct ingestion of food prepared and consumed outdoors. 66 refs., 13 figs., 25 tabs.

Lessard, E.T.; Miltenberger, R.P.; Conrad, R.A.; Musoline, S.V.; Naidu, J.R.; Moorthy, A.; Schopfer, C.J.

1985-03-01T23:59:59.000Z

374

CAUSE OF A MULTI-SPECIES RADIOIODINE PLUME THAT IS INCREASING IN CONCENTRATION  

SciTech Connect (OSTI)

Field and laboratory studies were carried out to understand the cause for steady increases in {sup 129}I concentrations emanating from radiological seepage basins located on the Savannah River Site. The basins were closed in 1988 by adding limestone and blast furnace slag and then capping with a RCRA low permeability engineered cover. Groundwater {sup 129}I concentrations in a well near the seepage basin in 1993 were 200 pCi L{sup -1} and are presently between 400 and 1000 pCi L{sup -1}. Iodine speciation in the plume was not uniform. Near the source, the iodine was comprised of 86% iodide, 2% iodate, and 12% organo-iodine (total activity = 178 pCi L{sup -1}). Whereas, groundwater iodine speciation 365 m down stream (25 m up stream from a wetland) was 0% iodide, 93% iodate, and 7% organo iodine. Batch desorption studies demonstrated that high concentrations of {sup 129}I could be incrementally desorbed from an archived seepage basin sediment sample by raising the pH. Batch sorption studies showed that iodate, IO{sub 3}{sup -}, sorbed more strongly than iodide, I{sup -}, to a subsurface clayey sediment, but equally well as iodide to a subsurface sandy sediment and a wetland sediment. Placing an organic-rich wetland sediment, but not nearby mineral sediments, under reducing (or microaerobic) conditions resulted in a large decrease in iodide K{sub d} values (from 73 to 10 mL g{sup -1}) and iodate K{sub d} values (from 80 to 7 mL g{sup -1}). Between pH and reduction-oxidation potential, it appears that pH seems to have a stronger influence on iodide and iodate sorption to mineral sediment. This may not be true for sediments containing higher concentrations of organic matter, such as the 7.6% organic matter sediment used in this study. First order calculations based on desorption studies with seepage basin sediments indicate that the modest increase of 0.7 pH units detected in the study site groundwater over the last 17 years since closure of the seepage basin may be sufficient to produce the observed increased groundwater {sup 129}I concentrations. Groundwater monitoring of the plume at the F-Area seepage basin has shown that the migration of many of the high risk radionuclides originally present at this complex site has been attenuated. However, {sup 129}I continues to leave the source at a rate that may have been exacerbated by the initial remediation efforts. This study underscores the important of identifying the appropriate in situ stabilization technologies for all contaminants present at a source term, especially if their geochemical behaviors differ.

Kaplan, D.

2010-09-30T23:59:59.000Z

375

JV Task 90 - Activated Carbon Production from North Dakota Lignite  

SciTech Connect (OSTI)

The Energy & Environmental Research Center (EERC) has pursued a research program for producing activated carbon from North Dakota lignite that can be competitive with commercial-grade activated carbon. As part of this effort, small-scale production of activated carbon was produced from Fort Union lignite. A conceptual design of a commercial activated carbon production plant was drawn, and a market assessment was performed to determine likely revenue streams for the produced carbon. Activated carbon was produced from lignite coal in both laboratory-scale fixed-bed reactors and in a small pilot-scale rotary kiln. The EERC was successfully able to upgrade the laboratory-scale activated carbon production system to a pilot-scale rotary kiln system. The activated carbon produced from North Dakota lignite was superior to commercial grade DARCO{reg_sign} FGD and Rheinbraun's HOK activated coke product with respect to iodine number. The iodine number of North Dakota lignite-derived activated carbon was between 600 and 800 mg I{sub 2}/g, whereas the iodine number of DARCO FGD was between 500 and 600 mg I{sub 2}/g, and the iodine number of Rheinbraun's HOK activated coke product was around 275 mg I{sub 2}/g. The EERC performed both bench-scale and pilot-scale mercury capture tests using the activated carbon made under various optimization process conditions. For comparison, the mercury capture capability of commercial DARCO FGD was also tested. The lab-scale apparatus is a thin fixed-bed mercury-screening system, which has been used by the EERC for many mercury capture screen tests. The pilot-scale systems included two combustion units, both equipped with an electrostatic precipitator (ESP). Activated carbons were also tested in a slipstream baghouse at a Texas power plant. The results indicated that the activated carbon produced from North Dakota lignite coal is capable of removing mercury from flue gas. The tests showed that activated carbon with the greatest iodine number was superior to commercial DARCO FGD for mercury capture. The results of the activated carbon market assessment indicate an existing market for water treatment and an emerging application for mercury control. That market will involve both existing and new coal-fired plants. It is expected that 20% of the existing coal-fired plants will implement activated carbon injection by 2015, representing about 200,000 tons of annual demand. The potential annual demand by new plants is even greater. In the mercury control market, two characteristics are going to dominate the customer's buying habit-performance and price. As continued demonstration testing of activated carbon injection at the various coal-fired power plants progresses, the importance of fuel type and plant configuration on the type of activated carbon best suited is being identified.

Steven Benson; Charlene Crocker; Rokan Zaman; Mark Musich; Edwin Olson

2008-03-31T23:59:59.000Z

376

Measuring Radioactivity from Fukushima Daiichi in New Mexico  

SciTech Connect (OSTI)

On March 11, 2011, the Fukushima Daiichi nuclear power plant was damaged by the tsunami that followed the 'Great East Japan Earthquake,' and the reactor subsequently leaked radioactive material. In response, LANL augmented the routine ambient (AIRNET) and stack (Rad-NESHAP) measurements with three high-volume samplers: No.167 at the Old White Rock Fire Station; No.173 at the TA-49 gate, and No.211 at the Los Alamos Medical Center. Previous accidents, such as the Three-Mile-Island accident in 1979 and the Chernobyl accident in 1986, indicated that the most likely releases were (a) the noble gases: krypton and xenon; and (b) the volatile elements: cesium, tellurium, and iodine. At the latitude of Fukushima, the predominant winds across the Pacific Ocean are from west to east, and models predicted that the plume would arrive in the western US on about March 18. By this time the shorter-lived isotopes would have decayed. Therefore, the expected radionuclides were xenon-133, cesium-134, cesium-136, cesium-137, tellurium-132, iodine-131, and iodine-132. As expected, cesium-134, cesium-136, cesium-137, tellurium-132, iodine-131, and iodine-132 were all detected by all three high-volume samplers during March 17-21. The concentrations peaked during the March 24-28 period. After this, concentrations of all nuclides declined. In general, the concentrations were consistent with those measured by the EPA RadNet system and many other monitoring systems throughout the world. At the time of writing, preliminary results from the AIRNET and Rad-NESHAP systems are being reported. More detailed results are described in LA-UR-11-10304 and will be reported in full in the annual environmental report for 2011. All previous releases from nuclear reactors have been dominated by noble gases, primarily krypton and xenon, which are not measured by the high-volume samplers or the AIRNET system. However, in sufficient concentrations these and other fission products would be detected by NEWNET. Consistent with this possibility, all NEWNET detectors recorded an increase of 0.2 {micro}R/h from March 19-1, followed by an additional increase of 0.1 {micro}R/h on March 24 (Figure 1). The consistency of the NEWNET stations is indicated by the error bars, which represent the standard error of the mean of the individual stations. Over the next 10 days, the NEWNET readings declined with approximately the 5-day half life of xenon-133, returning to near normal levels on April 2. After this, any further decrease was masked by high radon concentrations on April 3, by a weather system that moved into New Mexico on April 4, and by rainfall on April 6-9. Furthermore, it is likely that all NEWNET detectors responded to a gradually increasing trend in terrestrial radiation during the month of March as the ground dried out. It is difficult to distinguish the hypothetical effects of xenon-133 from the fluctuations of radon decay products. However, at present we do not have an alternative hypothesis for the sharp increase that was observed in all NEWNET stations from March 19-21. Perhaps some of the increase was caused by radon or terrestrial radiation, in which case the observed increase is an upper limit to that caused by releases from Fukushima. LANL data are consistent with those of the EPA RadNet monitoring system. The EPA has repeatedly stated that 'The levels detected are far below levels of concern.'

McNaughton, Michael [Los Alamos National Laboratory

2011-01-01T23:59:59.000Z

377

Photoelectronic properties of zinc phosphide crystals, films, and heterojunctions. Quarterly progress report No. 11, October 1-December 31, 1981  

SciTech Connect (OSTI)

Variations in crystal growth techniques are continuing with the goal of: (1) improving single crystal quality; and (2) producing variations in crystal properties by doping and post-growth variations of stoichiometry. DLTS measurements using Mg/Zn/sub 3/P/sub 2/ Schottky diodes gave information on three deep levels between 0.55 and 0.66 eV above the valence band in sublimation grown crystals with densities in the 10/sup 15/ to 10/sup 16/ cm/sup -3/ range, and a shallower level at 0.12 eV with a density of 10/sup 15/ cm/sup -3/ in an iodine-transport grown crystal. Investigation of surface properties of Zn/sub 3/P/sub 2/ indicate that a Br-MeOH etch leaves a Zn-rich surface for both sublimation-grown and iodine-transport grown crystals. Detailed measurements were made on thick Mg/Zn/sub 3/P/sub 2/ junctions on sublimation-grown and iodine-transport grown crystals of log J-V characteristics as a function of temperature, for crystal substrates as etched, and after heat treatment in hydrogen at several temperatures. A systematic change in the junction transport mechanism from tunneling at heat-treatment temperatures less than 300/sup 0/C to recombination/generation for heat-treatment temperatures between 300 and 500/sup 0/C was found for Zn/sub 3/P/sub 2/ crystals grown by both growth techniques. A simple model involving a depletion of free carrier density near the surface as a result of heat treatment in hydrogen is proposed. Thin film Mg/Zn/sub 3/P/sub 2/ cells showed log J-V characteristics that are strongly light dependent, indicating an increase in tunneling with illumination. Evidence that the barrier height of the Mg/Zn/sub 3/P/sub 2/ junction is actually of the order of 0.9 to 1.0 eV was obtained. Attempts to prepare ITO/Zn/sub 3/P/sub 2/ junctions by electron-beam evaporation of ITO on single crystal substrates yielded poor diodes and negligible photovoltaic behavior.

Bube, R.H.

1981-01-01T23:59:59.000Z

378

Radionuclide Migration through Sediment and Concrete: 16 Years of Investigations  

SciTech Connect (OSTI)

The Waste Management Project provides safe, compliant, and cost-effective waste management services for the Hanford Site and the U.S. Department of Energy (DOE) complex. Part of these services includes safe disposal of low-level waste and mixed low-level waste at the Hanford Low-Level Waste Burial Grounds in accordance with the requirements of DOE Order 435.1, Radioactive Waste Management. To partially satisfy these requirements, performance assessment analyses were completed and approved. DOE Order 435.1 also requires continuing data collection to increase confidence in the critical assumptions used in these analyses to characterize the operational features of the disposal facility that are relied on to satisfy the performance objectives identified in the order. Cement-based solidification and stabilization is considered for hazardous waste disposal because it is easily done and cost-efficient. One critical assumption is that concrete will be used as a waste form or container material at the Hanford Site to control and minimize the release of radionuclide constituents in waste into the surrounding environment. Concrete encasement would contain and isolate the waste packages from the hydrologic environment and act as an intrusion barrier. Any failure of concrete encasement may result in water intrusion and consequent mobilization of radionuclides from the waste packages. The radionuclides iodine-129, selenium-75, technetium-99, and uranium-238 have been identified as long-term dose contributors (Mann et al. 2001; Wood et al. 1995). Because of their anionic nature in aqueous solutions, these constituents of potential concern may be released from the encased concrete by mass flow and/or diffusion and migrate into the surrounding subsurface environment (Serne et al. 1989; 1992; 1993a, b; 1995). Therefore, it is necessary to assess the performance of the concrete encasement structure and the ability of the surrounding soil to retard radionuclide migration. Each of the test methods performed throughout the lifetime of the project has focused on different aspects of the concrete waste form weathering process. Diffusion of different analytes [technetium-99 (Tc-99), iodine-125 (I-125), stable iodine (I), uranium (U), and rhenium (Re)] has been quantified from experiments under both saturated and unsaturated conditions. The water-saturated conditions provide a conservative estimate of the concrete’s performance in situ, and the unsaturated conditions provide a more accurate estimate of the diffusion of contaminants from the concrete.

Golovich, Elizabeth C.; Mattigod, Shas V.; Snyder, Michelle MV; Powers, Laura; Whyatt, Greg A.; Wellman, Dawn M.

2014-11-06T23:59:59.000Z

379

K-Edge Subtraction Angiography with Synchrotron X-Rays  

SciTech Connect (OSTI)

The purpose of this project was to utilize dual energy, monochromatic X-rays produced from synchrotrons radiation in order to obtain noninvasive medical imaging. The application of synchrotrons radiation to medical imaging is based on the principle of iodine dichromography, first described by Bertil Jacobson of the Karolinska Institute in 1953. Medical imaging using synchrotrons radiation and K-edge dichromography was pioneered at Stanford University under the leadership of Dr. Ed Rubenstein, and the late Nobel Laureate in Physics, Dr. Robert Hofstadter. With progressive refinements in hardware, clinical-quality images were obtained of human coronary arteries utilizing peripheral injections of iodinated contrast agent. These images even now are far superior to those being presented by investigators using MRI as an imaging tool for coronary arteries. However, new supplies and instruments in the cardiac catheterization laboratory have served to transform coronary angiography into an outpatient procedure, with relatively little morbidity. We extended the principles learned with coronary angiography to noninvasive imaging of the human bronchial tree. For these images, we utilized xenon as the contrast agent, as it has a K-edge very similar to that of iodine. In this case, there is no true competing diagnostic test, and pulmonary neoplasm is an enormous public health concern. In early experiments, we demonstrated remarkably clear images of the human bronchial tree. These images have been shown internationally; however, funding difficulties primarily with the Department of Energy have not allowed for progression of this promising avenue of research. One potential criticism of the project is that in order to obtain these images, we utilized national laboratories. Some have questioned whether this would lead to a practical imaging modality. However, we have shown that the technology exists to allow for construction of a miniature storage ring, with a superconducting wiggler magnet, which would occupy minimal space, and would be of a cost comparable with that of a clinical cardiac catheterization laboratory. Much of the focus of this research is now shifting to Europe, where individual whom we have trained or with whom we have worked are now heading up extensive efforts in medical imaging and K-edge dichromography. This work is occurring mostly at DESY in Hamburg, and at the European Synchrotrons Research Laboratory (ESRF) in Grenoble. (B204)

Giacomini, John C.

1996-12-31T23:59:59.000Z

380

Molecular modelling and simulation of the surface tension of real quadrupolar fluids  

E-Print Network [OSTI]

Molecular modelling and simulation of the surface tension of fluids with force fields is discussed. 29 real fluids are studied, including nitrogen, oxygen, carbon dioxide, carbon monoxide, fluorine, chlorine, bromine, iodine, ethane, ethylene, acetylene, propyne, propylene, propadiene, carbon disulfide, sulfur hexafluoride, and many refrigerants. The fluids are represented by two-centre Lennard-Jones plus point quadrupole models from the literature. These models were adjusted only to experimental data of the vapour pressure and saturated liquid density so that the results for the surface tension are predictions. The deviations between the predictions and experimental data for the surface tension are of the order of 20 percent. The surface tension is usually overestimated by the models. For further improvements, data on the surface tension can be included in the model development. A suitable strategy for this is multi-criteria optimization based on Pareto sets. This is demonstrated using the model for carbon dioxide as an example.

Stephan Werth; Katrin Stöbener; Peter Klein; Karl-Heinz Küfer; Martin Horsch; Hans Hasse

2014-08-21T23:59:59.000Z

Note: This page contains sample records for the topic "iodine phos phorus" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

GROUNDWATER RADIOIODINE: PREVALENCE, BIOGEOCHEMISTRY, AND POTENTIAL REMEDIAL APPROACHES  

SciTech Connect (OSTI)

Iodine-129 ({sup 129}I) has not received as much attention in basic and applied research as other contaminants associated with DOE plumes. These other contaminants, such as uranium, plutonium, strontium, and technetium are more widespread and exist at more DOE facilities. Yet, at the Hanford Site and the Savannah River Site {sup 129}I occurs in groundwater at concentrations significantly above the primary drinking water standard and there is no accepted method for treating it, other than pump-and-treat systems. With the potential arrival of a 'Nuclear Renaissance', new nuclear power facilities will be creating additional {sup 129}I waste at a rate of 1 Ci/gigawatts energy produced. If all 22 proposed nuclear power facilities in the U.S. get approved, they will produce more {sup 129}I waste in seven years than presently exists at the two facilities containing the largest {sup 129}I inventories, ({approx}146 Ci {sup 129}I at the Hanford Site and the Savannah River Site). Hence, there is an important need to fully understand {sup 129}I behavior in the environment to clean up existing plumes and to support the expected future expansion of nuclear power production. {sup 129}I is among the key risk drivers at all DOE nuclear disposal facilities where {sup 129}I is buried, because of its long half-life (16 million years), high toxicity (90% of the body's iodine accumulates in the thyroid), high inventory, and perceived high mobility in the subsurface environment. Another important reason that {sup 129}I is a key risk driver is that there is the uncertainty regarding its biogeochemical fate and transport in the environment. We typically can define {sup 129}I mass balance and flux at sites, but can not accurately predict its response to changes in the environment. This uncertainty is in part responsible for the low drinking water standard, 1 pCi/L {sup 129}I, and the low permissible inventory limits (Ci) at the Savannah River Site, Hanford Site, and the former Yucca Mountain disposal facilities. The objectives of this report are to: (1) compile the background information necessary to understand behavior of {sup 129}I in the environment, (2) discuss sustainable remediation approaches to {sup 129}I contaminated groundwater, and (3) identify areas of research that will facilitate remediation of {sup 129}I contaminated areas on DOE sites. Lines of scientific inquiry that would significantly advance the goals of basic and applied research programs for accelerating {sup 129}I environmental remediation and reducing uncertainty associated with disposal of {sup 129}I waste are: (1) Evaluation of amendments or other treatment systems that can sequester subsurface groundwater {sup 129}I. (2) Develop analytical techniques for measurement of total {sup 129}I that eliminate the necessity of collecting and shipping large samples of groundwater. (3) Develop and evaluate ways to manipulate areas with organic-rich soil, such as wetlands, to maximize {sup 129}I sorption, minimizing releases during anoxic conditions. (4) Develop analytical techniques that can identify the various {sup 129}I species in the subsurface aqueous and solid phases at ambient concentrations and under ambient conditions. (5) Identify the mechanisms and factors controlling iodine-natural organic matter interactions at appropriate environmental concentrations. (6) Understand the biological processes that transform iodine species throughout different compartments of subsurface waste sites and the role that these processes have on {sup 129}I flux.

Denham, M.; Kaplan, D.; Yeager, C.

2009-09-23T23:59:59.000Z

382

Final Project Report: Release of aged contaminants from weathered sediments: Effects of sorbate speciation on scaling of reactive transport  

SciTech Connect (OSTI)

Hanford sediments impacted by hyperalkaline high level radioactive waste have undergone incongruent silicate mineral weathering concurrent with contaminant uptake. In this project, we studied the impact of background pore water (BPW) on strontium, cesium and iodine desorption and transport in Hanford sediments that were experimentally weathered by contact with simulated hyperalkaline tank waste leachate (STWL) solutions. Using those lab-weathered Hanford sediments (HS) and model precipitates formed during nucleation from homogeneous STWL solutions (HN), we (i) provided detailed characterization of reaction products over a matrix of field-relevant gradients in contaminant concentration, PCO2, and reaction time; (ii) improved molecular-scale understanding of how sorbate speciation controls contaminant desorption from weathered sediments upon removal of caustic sources; and (iii) developed a mechanistic, predictive model of meso- to field-scale contaminant reactive transport under these conditions.

Jon Chorover, University of Arizona; Peggy O' €  ™ Day, University of California, Merced; Karl Mueller, Penn State University; Wooyong Um, Pacific Northwest National Laboratory; Carl Steefel, Lawrence Berkeley National Laboratory

2012-10-01T23:59:59.000Z

383

Migration in alluvium of chlorine-36 and tritium from an underground nuclear test  

SciTech Connect (OSTI)

This article describes a field experiment studying the migration in alluvium of radioactive elements away from an underground nuclear explosion at the Nevada Test Site in the United States. Nuclides detected in the pumped water are tritium, chlorine-36, iodine-129, and krypton-85 - all at levels below the maximum permissible concentration for drinking water in controlled areas. The chlorine-36 elution curve precedes that of tritium, and is due to an anion exclusion process. A conventional two-dimensional convection-diffusion equation does not fully describe the elution curves for tritium and chlorine-36; the tailing of the curves is longer than predicted. Successful modeling of this experiment will be important for validating codes and models to be used in the high-level nuclear waste program.

Ogard, A.E.; Thompson, J.L.; Rundberg, R.S.; Wolfsberg, K.; Kubik, P.W.; Elmore, D.; Bentley, H.W.

1987-01-01T23:59:59.000Z

384

Method of increments for the halogen molecular crystals: Cl, Br, and I  

SciTech Connect (OSTI)

Method of increments (MI) calculations reveal the n-body correlation contributions to binding in solid chlorine, bromine, and iodine. Secondary binding contributions as well as d-correlation energies are estimated and compared between each solid halogen. We illustrate that binding is entirely determined by two-body correlation effects, which account for >80% of the total correlation energy. One-body, three-body, and exchange contributions are repulsive. Using density-fitting (DF) local coupled-cluster singles, doubles, and perturbative triples for incremental calculations, we obtain excellent agreement with the experimental cohesive energies. MI results from DF local second-order Mřller-Plesset perturbation (LMP2) yield considerably over-bound cohesive energies. Comparative calculations with density functional theory and periodic LMP2 method are also shown to be less accurate for the solid halogens.

Steenbergen, Krista G. [Physikalische und Theoretische Chemie, Freie Universität Berlin, Takustr. 3, 14195 Berlin (Germany); MacDiarmid Institute for Advanced Materials and Nanotechnology, Victoria University of Wellington, P.O. Box 600, Wellington 6012 (New Zealand); Gaston, Nicola [MacDiarmid Institute for Advanced Materials and Nanotechnology, Victoria University of Wellington, P.O. Box 600, Wellington 6012 (New Zealand); Müller, Carsten; Paulus, Beate [Physikalische und Theoretische Chemie, Freie Universität Berlin, Takustr. 3, 14195 Berlin (Germany)

2014-09-28T23:59:59.000Z

385

Aluminium plasma production at high laser intensity  

SciTech Connect (OSTI)

Thick and thin films of Al targets were irradiated in vacuum with iodine laser at 1315?nm wavelength, 300 ps pulse duration at a maximum intensity of about 10{sup 16}?W/cm{sup 2} by varying the pulse energy and focal position. The laser-generated plasma was monitored in forward and backward directions by using ion collectors, SiC detectors, Thomson parabola spectrometer, and X-ray streak camera. Ion emission shows maximum proton energy of about 4?MeV in self-focusing conditions and a maximum Al ion energy of about 50?MeV. An evaluation of the electric field driving ions in conditions of target normal sheath acceleration is given.

Torrisi, L.; Cutroneo, M. [Dip.to di Fisica e S.d.T. Universitŕ di Messina, V.S. d'Alcontres 31, 98166 S. Agata (Italy)

2014-02-28T23:59:59.000Z

386

Mid-Infrared Fiber-Coupled QCl-QEPAS Sensor  

SciTech Connect (OSTI)

An innovative spectroscopic system based on an external cavity quantum cascade laser (EC-QCL) coupled with a mid-infrared (mid-IR) fiber and quartz enhanced photoacoustic spectroscopy (QEPAS) is described. SF6 has been selected as a target gas in demonstration of the system for trace gas sensing. Single mode laser delivery through the prongs of the quartz tuning fork has been obtained employing a hollow waveguide fiber with inner silver–silver iodine (Ag–AgI) coatings and internal core diameter of 300 lm. A detailed design and realization of the QCL fiber coupling and output collimator system allowed almost practically all (99.4 %) of the laser beam to be transmitted through the spectrophone module. The achieved sensitivity of the system is 50 parts per trillion in 1 s, corresponding to a record for QEPAS normalized noise-equivalent absorption 2.7 9 10-10 W cm-1 Hz-1/2.

Spagnolo, V.; Patimisco, P.; Borri, Simone; Scamarcio, G.; Bernacki, Bruce E.; Kriesel, J.M.

2013-08-01T23:59:59.000Z

387

Molecular modelling and simulation of the surface tension of real quadrupolar fluids  

E-Print Network [OSTI]

Molecular modelling and simulation of the surface tension of fluids with force fields is discussed. 29 real fluids are studied, including nitrogen, oxygen, carbon dioxide, carbon monoxide, fluorine, chlorine, bromine, iodine, ethane, ethylene, acetylene, propyne, propylene, propadiene, carbon disulfide, sulfur hexafluoride, and many refrigerants. The fluids are represented by two-centre Lennard-Jones plus point quadrupole models from the literature. These models were adjusted only to experimental data of the vapour pressure and saturated liquid density so that the results for the surface tension are predictions. The deviations between the predictions and experimental data for the surface tension are of the order of 20 percent. The surface tension is usually overestimated by the models. For further improvements, data on the surface tension can be included in the model development. A suitable strategy for this is multi-criteria optimization based on Pareto sets. This is demonstrated using the model for carbon d...

Werth, Stephan; Klein, Peter; Küfer, Karl-Heinz; Horsch, Martin; Hasse, Hans

2014-01-01T23:59:59.000Z

388

High Efficiency Hydrogen Production from Nuclear Energy: Laboratory Demonstration of S-I Water-Splitting  

SciTech Connect (OSTI)

The objective of the French CEA, US-DOE INERI project is to perform a lab scale demonstration of the sulfur iodine (S-I) water splitting cycle, and assess the potential of this cycle for application to nuclear hydrogen production. The project will design, construct and test the three major component reaction sections that make up the S-I cycle. The CEA will design and test the prime (Bunsen) reaction section. General Atomics will develop and test the HI decomposition section, and SNL will develop and test the H2SO4 decomposition section. Activities for this period included initial program coordination and information exchange, the development of models and analyses that will support the design of the component sections, and preliminary designs for the component reaction sections. The sections are being designed to facilitate integration into a closed loop demonstration in a later stage of the program.

Buckingham, R.; Russ, B.; Brown, L.; Besenbruch, G.E.; Gelbard, F.; Pickard F.S.; Leybros, J.; Le Duigou, A.; Borgard, J.M.

2004-11-30T23:59:59.000Z

389

Extraordinarily Efficient Conduction in a Redox-Active Ionic Liquid  

E-Print Network [OSTI]

Iodine added to iodide-based ionic liquids leads to extraordinarily efficient charge transport, vastly exceeding that expected for such viscous systems. Using terahertz time-domain spectroscopy, in conjunction with dc conductivity, diffusivity and viscosity measurements we unravel the conductivity pathways in 1-methyl-3-propylimidazolium iodide melts. This study presents evidence of the Grotthuss mechanism as a significant contributor to the conductivity, and provides new insights into ion pairing processes as well as the formation of polyiodides. The terahertz and transport results are reunited in a model providing a quantitative description of the conduction by physical diffusion and the Grotthuss bond-exchange process. These novel results are important for the fundamental understanding of conduction in molten salts and for applications where ionic liquids are used as charge-transporting media such as in batteries and dye-sensitized solar cells.

Verner K. Thorsmřlle; Guido Rothenberger; Daniel Topgaard; Jan C. Brauer; Dai-Bin Kuang; Shaik M. Zakeeruddin; Björn Lindman; Michael Grätzel; Jacques-E. Moser

2010-11-09T23:59:59.000Z

390

Interaction of water with epoxy.  

SciTech Connect (OSTI)

The chemistries of reactants, plasticizers, solvents and additives in an epoxy paint are discussed. Polyamide additives may play an important role in the absorption of molecular iodine by epoxy paints. It is recommended that the unsaturation of the polyamide additive in the epoxy cure be determined. Experimental studies of water absorption by epoxy resins are discussed. These studies show that absorption can disrupt hydrogen bonds among segments of the polymers and cause swelling of the polymer. The water absorption increases the diffusion coefficient of water within the polymer. Permanent damage to the polymer can result if water causes hydrolysis of ether linkages. Water desorption studies are recommended to ascertain how water absorption affects epoxy paint.

Powers, Dana Auburn

2009-07-01T23:59:59.000Z

391

Nuclear waste management. Quarterly progress report, April-June 1980  

SciTech Connect (OSTI)

The status of the following programs is reported: high-level waste immobilization; alternative waste forms; Nuclear Waste Materials Characterization Center; TRU waste immobilization; TRU waste decontamination; krypton solidification; thermal outgassing; iodine-129 fixation; monitoring and physical characterization of unsaturated zone transport; well-logging instrumentation development; mobility of organic complexes of fission products in soils; waste management system studies; waste management safety studies; assessment of effectiveness of geologic isolation systems; waste/rock interactions technology; systems study on engineered barriers; criteria for defining waste isolation; spent fuel and fuel pool component integrity program; analysis of spent fuel policy implementation; asphalt emulsion sealing of uranium tailings; application of long-term chemical biobarriers for uranium tailings; and development of backfill material.

Platt, A.M.; Powell, J.A. (comps.)

1980-09-01T23:59:59.000Z

392

The Modular Helium Reactor for Hydrogen Production  

SciTech Connect (OSTI)

For electricity and hydrogen production, an advanced reactor technology receiving considerable international interest is a modular, passively-safe version of the high-temperature, gas-cooled reactor (HTGR), known in the U.S. as the Modular Helium Reactor (MHR), which operates at a power level of 600 MW(t). For hydrogen production, the concept is referred to as the H2-MHR. Two concepts that make direct use of the MHR high-temperature process heat are being investigated in order to improve the efficiency and economics of hydrogen production. The first concept involves coupling the MHR to the Sulfur-Iodine (SI) thermochemical water splitting process and is referred to as the SI-Based H2-MHR. The second concept involves coupling the MHR to high-temperature electrolysis (HTE) and is referred to as the HTE-Based H2-MHR.

E. Harvego; M. Richards; A. Shenoy; K. Schultz; L. Brown; M. Fukuie

2006-10-01T23:59:59.000Z

393

WWER Expert System for Fuel Failure Analysis Using Data on Primary Coolant Activity  

SciTech Connect (OSTI)

The computer expert system for fuel failure analysis of WWER during operation is presented. The diagnostics is based on the measurement of specific activity of reference nuclides in reactor primary coolant and application of a computer code for the data interpretation. The data analysis includes an evaluation of tramp uranium mass in reactor core, detection of failures by iodine and caesium spikes, evaluation of burnup of defective fuel. Evaluation of defective fuel burnup was carried out by applying the relation of caesium nuclides activity in spikes and relations of activities of gaseous fission products for steady state operational conditions. The method of burnup evaluation of defective fuel by use of fission gas activity is presented in detail. The neural-network analysis is performed for determination of failed fuel rod number and defect size. Results of the expert system application are illustrated for several fuel campaigns on operating WWER NPPs. (authors)

Likhanskii, V.V.; Evdokimov, I.A.; Sorokin, A.A.; Khromov, A.G.; Kanukova, V.D.; Apollonova, O.V. [SRC RF TRINITI, 142190, Troitsk, Moscow Reg. (Russian Federation); Ugryumov, A.V. [JSC TVEL, 119017, 24/26 Bolshaya Ordynka st., Moscow (Russian Federation)

2007-07-01T23:59:59.000Z

394

Determination of radionuclides and pathways contributing to dose in 1945  

SciTech Connect (OSTI)

A series of scoping calculations has been undertaken to evaluate the absolute and relative contributions of different radionuclides and exposure pathways to doses that may have been received by individuals living in the vicinity of the Hanford Site. This scoping calculation (Calculation 003) examined the contributions of numerous radionuclides to dose via environmental exposures and accumulation in foods. This study builds on the work initiated in the first scoping study of iodine in cow's milk (calculation 001). Addressed in this calculation were the contributions to organ and effective dose of infants and adults from (1) air submersion and groundshine external dose, (2) inhalation, (3) ingestion of soil by humans, (4) ingestion of leafy vegetables, (5) ingestion of other vegetables and fruits, (6) ingestion of meat, (7) ingestion of eggs, and (8) ingestion of cows' milk from Feeding Regime 1, as described in Calculation 001.

Napier, B.A.

1992-12-01T23:59:59.000Z

395

Determination of radionuclides and pathways contributing to dose in 1945. Hanford Environmental Dose Reconstruction Project: Dose code recovery activities, Calculation 003  

SciTech Connect (OSTI)

A series of scoping calculations has been undertaken to evaluate the absolute and relative contributions of different radionuclides and exposure pathways to doses that may have been received by individuals living in the vicinity of the Hanford Site. This scoping calculation (Calculation 003) examined the contributions of numerous radionuclides to dose via environmental exposures and accumulation in foods. This study builds on the work initiated in the first scoping study of iodine in cow`s milk (calculation 001). Addressed in this calculation were the contributions to organ and effective dose of infants and adults from (1) air submersion and groundshine external dose, (2) inhalation, (3) ingestion of soil by humans, (4) ingestion of leafy vegetables, (5) ingestion of other vegetables and fruits, (6) ingestion of meat, (7) ingestion of eggs, and (8) ingestion of cows` milk from Feeding Regime 1, as described in Calculation 001.

Napier, B.A.

1992-12-01T23:59:59.000Z

396

Progress in chemical processing of LEU targets for {sup 99}Mo production -- 1997  

SciTech Connect (OSTI)

Presented here are recent experimental results of the continuing development activities associated with converting current processes for producing fission-product {sup 99}Mo from targets using high-enriched uranium (HEU) to low-enriched uranium (LEU). Studies were focused in four areas: (1) measuring the chemical behavior of iodine, rhodium, and silver in the LEU-modified Cintichem process, (2) performing experiments and calculations to assess the suitability of zinc fission barriers for LEU metal foil targets, (3) developing an actinide separations method for measuring alpha contamination of the purified {sup 99}Mo product, and (4) developing a cooperation with Sandia National Laboratories and Los Alamos National Laboratory that will lead to approval by the US Federal Drug Administration for production of {sup 99}Mo from LEU targets. Experimental results continue to show the technical feasibility of converting current HEU processes to LEU.

Vandegrift, G.F.; Conner, C.; Sedlet, J.; Wygmans, D.G. [Argonne National Lab., IL (United States); Wu, D. [Univ. of Illinois, Urbana, IL (United States); Iskander, F.; Landsberger, S. [Univ. of Texas, Austin, TX (United States)

1997-10-01T23:59:59.000Z

397

Comparison of Fission Product Yields and Their Impact  

SciTech Connect (OSTI)

This memorandum describes the Naval Reactors Prime Contractor Team (NRPCT) Space Nuclear Power Program (SNPP) interest in determining the expected fission product yields from a Prometheus-type reactor and assessing the impact of these species on materials found in the fuel element and balance of plant. Theoretical yield calculations using ORIGEN-S and RACER computer models are included in graphical and tabular form in Attachment, with focus on the desired fast neutron spectrum data. The known fission product interaction concerns are the corrosive attack of iron- and nickel-based alloys by volatile fission products, such as cesium, tellurium, and iodine, and the radiological transmutation of krypton-85 in the coolant to rubidium-85, a potentially corrosive agent to the coolant system metal piping.

S. Harrison

2006-02-01T23:59:59.000Z

398

Variable temperature effects on release rates of readily soluble nuclides  

SciTech Connect (OSTI)

In this paper we study the effect of temperature on the release rate of readily soluble nuclides, as affected by a time-temperature dependent diffusion coefficient. In this analysis ground water fills the voids in the waste package at t = 0 and one percent of the inventories of cesium and iodine are immediately dissolved into the void water. Mass transfer resistance of partly failed container and cladding is conservatively neglected. The nuclides move through the void space into the surrounding rock under a concentration gradient. We use an analytic solution to compute the nuclide concentration in the gap or void, and the mass flux rate into the porous rock. 8 refs., 4 figs.

Kim, C.-L.; Light, W.B.; Lee, W.W.-L.; Chambre, P.L.; Pigford, T.H. (Korea Advanced Energy Research Inst., Daeduk (Republic of Korea); Lawrence Berkeley Lab., CA (USA))

1988-09-01T23:59:59.000Z

399

Origin of carrier generation in photovoltaic perovskite variant Cs2SnI6  

E-Print Network [OSTI]

Cs2SnI6 is an air-stable & non-toxic variant of perovskite-type photovoltaic materials. In this letter, stability of intrinsic defects in Cs2SnI6 was examined by density functional theory calculations. We found that iodine vacancy and tin interstitial are the dominant defects, mainly responsible for the intrinsic n-type conductivity in Cs2SnI6. However, the transition levels of the dominant defects are deep, which makes it difficult to achieve high-density n-type doping. Tin vacancy is expected for p-type doping, but it has a very high formation energy > 3.6 eV because of the strong Sn-I covalent bonds and can hardly be generated. Instead, cesium vacancy is formed at an extremely Cs-poor condition and explains already-reported p-type conductivity by SnI2 doping.

Xiao, Zewen; Kamiya, Toshio

2015-01-01T23:59:59.000Z

400

Status of initial testing of the H2SO4 section of the ILS experiment.  

SciTech Connect (OSTI)

A sulfuric acid catalytic decomposer section was assembled and tested for the Integrated Laboratory Scale experiments of the Sulfur-Iodine Thermochemical Cycle. This cycle is being studied as part of the U. S. Department of Energy Nuclear Hydrogen Initiative. Tests confirmed that the 54-inch long silicon carbide bayonet could produce in excess of the design objective of 100 liters/hr of SO{sub 2} at 2 bar. Furthermore, at 3 bar the system produced 135 liters/hr of SO{sub 2} with only 31 mol% acid. The gas production rate was close to the theoretical maximum determined by equilibrium, which indicates that the design provides adequate catalyst contact and heat transfer. Several design improvements were also implemented to greatly minimize leakage of SO{sub 2} out of the apparatus. The primary modifications were a separate additional enclosure within the skid enclosure, and replacement of Teflon tubing with glass-lined steel pipes.

Moore, Robert Charles; Parma, Edward J., Jr.; Gelbard, Fred

2007-12-01T23:59:59.000Z

Note: This page contains sample records for the topic "iodine phos phorus" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Atomic energy as an humane endeavor: Retrospective on its development  

SciTech Connect (OSTI)

This report is a speech delivered in Tokyo, Japan, by the author. It covers the historical aspects of atomic energy, from the pre-fission days until present. Such pioneer experiments conducted by O. Hahn, L. Meitner, and F. Strassmann to describe barium isotopes as the result of bombardment of uranium with neutrons are discussed. The author also discussed in detail the pre-war nuclear research at Berkeley, a leading center of nuclear research. Such important events as the synthesis and identification of cobalt-60, iodine-131, and technetium-99m are also discussed. The author discussed the nuclear power as a source of electricity and the perspective on the future of nuclear power. 32 refs., 19 figs., 5 tabs.

Seaborg, G.T.; Stahlkopf, K.E.

1989-01-01T23:59:59.000Z

402

The Halogenation of Oils with Special Attention to the Method of Wijs  

E-Print Network [OSTI]

by him in the following manner: !• In the preparation of the solutions. HgCl 8 + 41 = Hg I a + 2 IC1 IC1 + H 20 5 HC1 + HIO 2. On keeping the solution. 2 HIO + C 2H 60 = 21 + 2H 20 + C 2H 40 3. In the absorption (oleic acid). C0 2H.Ci 7H a a + HIO... at once a substance capable of liberating iodine from potassium iodide. He expressed the chemical change by the following equation: HgCl + I 2 - Hg C1I + IC1 Ephraim regarded the fact that he could ob­ tain results identical to those of Hubl, by using...

Rhodes, Edmund Oliver

1913-05-15T23:59:59.000Z

403

Nuclear waste management. Quarterly progress report, April-June 1981  

SciTech Connect (OSTI)

Reports and summaries are presented for the following: high-level waste process development; alternative waste forms; TMI zeolite vitrification demonstration program; nuclear waste materials characterization center; TRU waste immobilization; TRU waste decontamination; krypton implantation; thermal outgassing; iodine-129 fixation; NWVP off-gas analysis; monitoring and physical characterization of unsaturated zone transport; well-logging instrumentation development; verification instrument development; mobility of organic complexes of radionuclides in soils; handbook of methods to decrease the generation of low-level waste; waste management system studies; waste management safety studies; assessment of effectiveness of geologic isolation systems; waste/rock interactions technology program; high-level waste form preparation; development of backfill materials; development of structural engineered barriers; disposal charge analysis; and analysis of spent fuel policy implementation.

Chikalla, T.D.; Powell, J.A.

1981-09-01T23:59:59.000Z

404

Treatment of gaseous effluents at nuclear facilities  

SciTech Connect (OSTI)

Airborne effluents from nuclear facilities represent the major environmental impact from such plants both under routine conditions or after plant accidents. Effective control of such emissions, therefore, constitutes a major aspect of plant design for nuclear power plants and other facilities in the nuclear fuel cycle. This volume brings together a number of review articles by experts in the various areas of concern and describes some of the removal systems that have been designed for power plants and, particularly, for reprocessing plants. Besides controlling the release of radionuclides, other potentially hazardous effluents, such as nitrous oxides, must be minimized, and these are included in some of the systems described. The various chapters deal with historic developments and current technology in reducing emission of fission products, noble gases, iodine, and tritium, and consider design requirements for practical installations.

Goossen, W.R.A. [Studiecentrum voor Kernenergie, Mol (Belgium). Dept. of Chemical Engineering] [ed.; Eichholz, G.G.; Tedder, D.W. [eds.] [Georgia Institute of Technology, Atlanta, GA (United States)

1991-12-31T23:59:59.000Z

405

Highly deformed high-spin band in {sup 125}I  

SciTech Connect (OSTI)

High-spin states in {sup 125}I have been investigated using the reaction {sup 82}Se({sup 48}Ca, p4n) at a beam energy of 200 MeV and {gamma}-ray coincidence events were detected using the Gammasphere spectrometer. A deformed rotational band, extending up to I{sup {pi}=}95/2{sup -}, was observed for the first time in a heavier odd-A iodine nucleus. The characteristics of the band are very similar to those of the highly deformed bands observed recently in neighboring nuclei and it is essentially identical to one of the previously known bands in {sup 126}Xe. The experimental results are compared to cranked Nilsson-Strutinsky calculations and possible configurations for the band are discussed.

Singh, Purnima; Nag, Somnath; Singh, A. K.; Ragnarsson, I.; Huebel, H.; Al-Khatib, A.; Bringel, P.; Engelhardt, C.; Neusser-Neffgen, A.; Hagemann, G. B.; Hansen, C. R.; Herskind, B.; Sletten, G.; Bracco, A.; Benzoni, G.; Camera, F.; Fallon, P.; Clark, R. M.; Carpenter, M. P.; Janssens, R. V. F. [Department of Physics and Meteorology, Indian Institute of Technology Kharagpur, Kharagpur, IN-721302 (India); Department of Mathematical Physics, Lund Institute of Technology, Box 118, S-221 Lund (Sweden); Helmholtz-Institut fuer Strahlen- und Kernphysik, Universitaet Bonn, Nussallee 14-16, D-53115 Bonn (Germany); Niels Bohr Institute, Blegdamsvej 17, DK-2100 Copenhagen O (Denmark); Dipartimento di Fisica, Universita di Milano and INFN, Sezione di Milano, I-20133 Milano (Italy); Nuclear Science Division, Lawrence Berkeley National Laboratory, Berkeley, California 94720 (United States); Physics Division, Argonne National Laboratory, Argonne, Illinois 60439 (United States); Department of Physics, University of Massachusetts Lowell, Lowell, Massachusetts 01854 (United States); Department of Radiation Oncology, University of Michigan, Ann Arbor, Michigan 48109 (United States)

2011-08-15T23:59:59.000Z

406

Method oil shale pollutant sorption/NO.sub.x reburning multi-pollutant control  

DOE Patents [OSTI]

A method of decreasing pollutants produced in a combustion process. The method comprises combusting coal in a combustion chamber to produce at least one pollutant selected from the group consisting of a nitrogen-containing pollutant, sulfuric acid, sulfur trioxide, carbonyl sulfide, carbon disulfide, chlorine, hydroiodic acid, iodine, hydrofluoric acid, fluorine, hydrobromic acid, bromine, phosphoric acid, phosphorous pentaoxide, elemental mercury, and mercuric chloride. Oil shale particles are introduced into the combustion chamber and are combusted to produce sorbent particulates and a reductant. The at least one pollutant is contacted with at least one of the sorbent particulates and the reductant to decrease an amount of the at least one pollutant in the combustion chamber. The reductant may chemically reduce the at least one pollutant to a benign species. The sorbent particulates may adsorb or absorb the at least one pollutant. A combustion chamber that produces decreased pollutants in a combustion process is also disclosed.

Boardman, Richard D. (Idaho Falls, ID); Carrington, Robert A. (Idaho Falls, ID)

2008-06-10T23:59:59.000Z

407

Waste Acceptance Testing of Secondary Waste Forms: Cast Stone, Ceramicrete and DuraLith  

SciTech Connect (OSTI)

To support the selection of a waste form for the liquid secondary wastes from WTP, Washington River Protection Solutions has initiated secondary-waste-form testing work at Pacific Northwest National Laboratory (PNNL). In anticipation of a down-selection process for a waste form for the Solidification Treatment Unit to be added to the ETF, PNNL is conducting tests on four candidate waste forms to evaluate their ability to meet potential waste acceptance criteria for immobilized secondary wastes that would be placed in the IDF. All three waste forms demonstrated compressive strengths above the minimum 3.45 MPa (500 psi) set as a target for cement-based waste forms. Further, none of the waste forms showed any significant degradation in compressive strength after undergoing thermal cycling (30 cycles in a 10 day period) between -40 C and 60 C or water immersion for 90 days. The three leach test methods are intended to measure the diffusion rates of contaminants from the waste forms. Results are reported in terms of diffusion coefficients and a leachability index (LI) calculated based on the diffusion coefficients. A smaller diffusion coefficient and a larger LI are desired. The NRC, in its Waste Form Technical Position (NRC 1991), provides recommendations and guidance regarding methods to demonstrate waste stability for land disposal of radioactive waste. Included is a recommendation to conduct leach tests using the ANS 16.1 method. The resulting leachability index (LI) should be greater than 6.0. For Hanford secondary wastes, the LI > 6.0 criterion applies to sodium leached from the waste form. For technetium and iodine, higher targets of LI > 9 for Tc and LI > 11 for iodine have been set based on early waste-disposal risk and performance assessment analyses. The results of these three leach tests conducted for a total time between 11days (ASTM C1308) to 90 days (ANS 16.1) showed: (1) Technetium diffusivity: ANSI/ANS 16.1, ASTM C1308, and EPA 1315 tests indicated that all the waste forms had leachability indices better than the target LI > 9 for technetium; (2) Rhenium diffusivity: Cast Stone 2M specimens, when tested using EPA 1315 protocol, had leachability indices better than the target LI > 9 for technetium based on rhenium as a surrogate for technetium. All other waste forms tested by ANSI/ANS 16.1, ASTM C1308, and EPA 1315 test methods had leachability indices that were below the target LI > 9 for Tc based on rhenium release. These studies indicated that use of Re(VII) as a surrogate for 99Tc(VII) in low temperature secondary waste forms containing reductants will provide overestimated diffusivity values for 99Tc. Therefore, it is not appropriate to use Re as a surrogate 99Tc in future low temperature waste form studies. (3) Iodine diffusivity: ANSI/ANS 16.1, ASTM C1308, and EPA 1315 tests indicated that the three waste forms had leachability indices that were below the target LI > 11 for iodine. Therefore, it may be necessary to use a more effective sequestering material than silver zeolite used in two of the waste forms (Ceramicrete and DuraLith); (4) Sodium diffusivity: All the waste form specimens tested by the three leach methods (ANSI/ANS 16.1, ASTM C1308, and EPA 1315) exceeded the target LI value of 6; (5) All three leach methods (ANS 16.1, ASTM C1308 and EPA 1315) provided similar 99Tc diffusivity values for both short-time transient diffusivity effects as well as long-term ({approx}90 days) steady diffusivity from each of the three tested waste forms (Cast Stone 2M, Ceramicrete and DuraLith). Therefore, any one of the three methods can be used to determine the contaminant diffusivities from a selected waste form.

Mattigod, Shas V.; Westsik, Joseph H.; Chung, Chul-Woo; Lindberg, Michael J.; Parker, Kent E.

2011-08-12T23:59:59.000Z

408

Converting Homogeneous to Heterogeneous in Electrophilic Catalysis using Monodisperse Metal Nanoparticles  

SciTech Connect (OSTI)

A continuing goal in catalysis is the transformation of processes from homogeneous to heterogeneous. To this end, nanoparticles represent a new frontier in heterogeneous catalysis, where this conversion is supplemented by the ability to obtain new or divergent reactivity and selectivity. We report a novel method for applying heterogeneous catalysts to known homogeneous catalytic reactions through the design and synthesis of electrophilic platinum nanoparticles. These nanoparticles are selectively oxidized by the hypervalent iodine species PhICl{sub 2}, and catalyze a range of {pi}-bond activation reactions previously only homogeneously catalyzed. Multiple experimental methods are utilized to unambiguously verify the heterogeneity of the catalytic process. The discovery of treatments for nanoparticles that induce the desired homogeneous catalytic activity should lead to the further development of reactions previously inaccessible in heterogeneous catalysis. Furthermore, our size and capping agent study revealed that Pt PAMAM dendrimer-capped nanoparticles demonstrate superior activity and recyclability compared to larger, polymer-capped analogues.

Witham, Cole A.; Huang, Wenyu; Tsung, Chia-Kuang; Kuhn, John N.; Somorjai, Gabor A.; Toste, F. Dean

2009-10-15T23:59:59.000Z

409

Nuclear waste management. Quarterly progress report, October through December 1980  

SciTech Connect (OSTI)

Progress reports and summaries are presented under the following headings: high-level waste process development; alternative waste forms; nuclear waste materials characterization center; TRU waste immobilization; TRU waste decontamination; krypton solidification; thermal outgassing; iodine-129 fixation; monitoring and physical characterization of unsaturated zone transport; well-logging instrumentation development; mobility of organic complexes of radionuclides in soils; waste management system studies; waste management safety studies; assessment of effectiveness of geologic isolation systems; waste/rock interactions technology; high level waste form preparation; development of backfill material; development of structural engineered barriers; ONWI disposal charge analysis; spent fuel and fuel component integrity program; analysis of spent fuel policy implementation; analysis of postulated criticality events in a storage array of spent LWR fuel; asphalt emulsion sealing of uranium tailings; liner evaluation for uranium mill tailings; multilayer barriers for sealing of uranium tailings; application of long-term chemical biobarriers for uranium tailings; revegetation of inactive uranium tailing sites; verification instrument development.

Chikalla, T.D.; Powell, J.A. (comps.)

1981-03-01T23:59:59.000Z

410

Pyrochemical separations technologies envisioned for the U. S. accelerator transmutation of waste system  

SciTech Connect (OSTI)

A program has been initiated for the purpose of developing the chemical separations technologies necessary to support a large Accelerator Transmutation of Waste (ATW) system capable of dealing with the projected inventory of spent fuel from the commercial nuclear power stations in the United States. The baseline process selected combines aqueous and pyrochemical processes to enable the efficient separation of uranium, technetium, iodine, and the transuranic elements from LWR spent fuel. The diversity of processing methods was chosen for both technical and economic factors. A six-year technology evaluation and development program is foreseen, by the end of which an informed decision can be made on proceeding with demonstration of the ATW system.

Laidler, J. J.

2000-02-17T23:59:59.000Z

411

High Temperature Heat Exchanger Project  

SciTech Connect (OSTI)

The UNLV Research Foundation assembled a research consortium for high temperature heat exchanger design and materials compatibility and performance comprised of university and private industry partners under the auspices of the US DOE-NE Nuclear Hydrogen Initiative in October 2003. The objectives of the consortium were to conduct investigations of candidate materials for high temperature heat exchanger componets in hydrogen production processes and design and perform prototypical testing of heat exchangers. The initial research of the consortium focused on the intermediate heat exchanger (located between the nuclear reactor and hydrogen production plan) and the components for the hydrogen iodine decomposition process and sulfuric acid decomposition process. These heat exchanger components were deemed the most challenging from a materials performance and compatibility perspective

Anthony E. Hechanova, Ph.D.

2008-09-30T23:59:59.000Z

412

Fission product behavior during the PBF (Power Burst Facility) Severe Fuel Damage Test 1-1  

SciTech Connect (OSTI)

In response to the accident at Three Mile Island Unit 2 (TMI-2), the United States Nuclear Regulatory Commission (USNRC) initiated a series of Severe Fuel Damage tests that were performed in the Power Burst Facility at the Idaho National Engineering Laboratory to obtain data necessary to understand (a) fission product release, transport, and deposition; (b) hydrogen generation; and (c) fuel/cladding material behavior during degraded core accidents. Data are presented about fission product behavior noted during the second experiment of this series, the Severe Fuel Damage Test 1-1, with an in-depth analysis of the fission product release, transport, and deposition phenomena that were observed. Real-time release and transport data of certain fission products were obtained from on-line gamma spectroscopy measurements. Liquid and gas effluent grab samples were collected at selected periods during the test transient. Additional information was obtained from steamline deposition analysis. From these and other data, fission product release rates and total release fractions are estimated and compared with predicted release behavior using current models. Fission product distributions and a mass balance are also summarized, and certain probable chemical forms are predicted for iodine, cesium, and tellurium. An in-depth evaluation of phenomena affecting the behavior of the high-volatility fission products - xenon, krypton, iodine, cesium, and tellurium - is presented. Analysis indicates that volatile release from fuel is strongly influenced by parameters other than fuel temperature. Fission product behavior during transport through the Power Burst Facility effluent line to the fission product monitoring system is assessed. Tellurium release behavior is also examined relatve to the extent of Zircaloy cladding oxidation. 81 fig., 53 tabs.

Hartwell, J K; Petti, D A; Hagrman, D L; Jensen, S M; Cronenberg, A W

1987-05-01T23:59:59.000Z

413

Effects of welding fumes on nuclear air cleaning system carbon adsorber banks  

SciTech Connect (OSTI)

Standard Technical Specifications for nuclear air cleaning systems include requirements for surveillance tests following fire, painting, or chemical release in areas communicating with the affected system. To conservatively implement this requirement, many plants categorize welding as a chemical release process, and institute controls to ensure that welding fumes do not interact with carbon adsorbers in a filter system. After reviewing research data that indicated welding had a minimal impact on adsorber iodine removal efficiency, further testing was performed with the goal of establishing a welding threshold. It was anticipated that some quantity of weld electrodes could be determined that had a corresponding detrimental impact on iodine removal efficiency for the exposed adsorber. This value could be used to determine a conservative sampling schedule that would allow the station to perform laboratory testing to ensure system degradation did not occur without a full battery of surveillance tests. A series of tests was designed to demonstrate carbon efficiency versus cumulative welding fume exposure. Three series of tests were performed, one for each of three different types of commonly used weld electrodes. Carbon sampling was performed at baseline conditions, and every five pounds of electrode thereafter. Two different laboratory tests were performed for each sample; one in accordance with ASTM 3803/1989 at 95% relative humidity and 30 degrees C, and another using the less rigorous conditions of 70% relative humidity and 80 degrees C. Review of the test data for all three types of electrodes failed to show a significant correlation between carbon efficiency degradation and welding fume exposure. Accordingly, welding is no longer categorized as a `chemical release process` at McGuire Nuclear Station, and limits on welding fume interaction with ventilation systems have been eliminated. 4 refs., 3 figs., 1 tab.

Roberson, P.W. [Duke Power Company, Huntersville, NC (United States)

1997-08-01T23:59:59.000Z

414

Nuclear Medicine Program progress report for quarter ending June 30, 1991  

SciTech Connect (OSTI)

In this report the excitation functions for production of gallium-66 via {alpha}-induced nuclear reactions on enriched zinc-66 have been measured with E{sub {alpha}}{le}27.3 Mev and E{sub {alpha}}{le}43.7 MeV employing the stack thin-target technique. In addition, the induced activity of gallium-67 in the same sets of targets allowed an evaluation of the excitation functions of the corresponding nuclear reactions. These preliminary studies have demonstrated that sufficient levels of gallium-66 can be produced by {alpha}-induced reactions on enriched zinc targets. A series of radioiodinated analogues of 1-azabicyclo(2.2.2)oct-3-yl {alpha}-hydroxy-{alpha}, {alpha}-diphenylacetate (QNB) have been prepared. These new analogues include 1-azabicyclo-(2.2.2)oct-3-yl{alpha}-hydroxy-{alpha}-(4-iodophenyl)-{alpha}-methylacetate(2,I-WNA), 1-azabicyclo(2.2.2)oct-3-yl (3-iodo)-xanthene-9-carboxylate (3,I-QNX), and 1-azabicyclo(2.2.2)oct-3-yl {alpha}-hydroxy-{alpha}-(E-1-iodo-1-propen-3-yl)-{alpha}-phenylacetate (4,I-QNP), which have also been radiolabeled with iodine-125 with high specific activity. The biodistribution, brain uptake, and receptor specificity of these new analogues are currently being studied. Shipments of radioactive agents made to collaborators during this period included. One shipment of iodine-125-labeled 15-(p-iodophenyl)-3-R,S-methylpentadecanoic acid (BMIPP) and tungsten-188/rhenium-188 generator. 16 refs., 7 figs., 1 tab.

Knapp, F.F. Jr.; Ambrose, K.R.; Callahan, A.P.; McPherson, D.W.; Mirzadeh, S.; Srivastava, P.C.; Hasan, A.; Lambert, C.R.; Lambert, S.J.; Rice, D.E.

1991-09-01T23:59:59.000Z

415

X-ray intravital microscopy for functional imaging in rat hearts using synchrotron radiation coronary microangiography  

SciTech Connect (OSTI)

An X-ray intravital microscopy technique was developed to enable in vivo visualization of the coronary, cerebral, and pulmonary arteries in rats without exposure of organs and with spatial resolution in the micrometer range and temporal resolution in the millisecond range. We have refined the system continually in terms of the spatial resolution and exposure time. X-rays transmitted through an object are detected by an X-ray direct-conversion type detector, which incorporates an X-ray SATICON pickup tube. The spatial resolution has been improved to 6 {mu}m, yielding sharp images of small arteries. The exposure time has been shortened to around 2 ms using a new rotating-disk X-ray shutter, enabling imaging of beating rat hearts. Quantitative evaluations of the X-ray intravital microscopy technique were extracted from measurements of the smallest-detectable vessel size and detection of the vessel function. The smallest-diameter vessel viewed for measurements is determined primarily by the concentration of iodinated contrast material. The iodine concentration depends on the injection technique. We used ex vivo rat hearts under Langendorff perfusion for accurate evaluation. After the contrast agent is injected into the origin of the aorta in an isolated perfused rat heart, the contrast agent is delivered directly into the coronary arteries with minimum dilution. The vascular internal diameter response of coronary arterial circulation is analyzed to evaluate the vessel function. Small blood vessels of more than about 50 {mu}m diameters were visualized clearly at heart rates of around 300 beats/min. Vasodilation compared to the control was observed quantitatively using drug manipulation. Furthermore, the apparent increase in the number of small vessels with diameters of less than about 50 {mu}m was observed after the vasoactive agents increased the diameters of invisible small blood vessels to visible sizes. This technique is expected to offer the potential for direct investigation of mechanisms of vascular dysfunctions.

Umetani, K. [Japan Synchrotron Radiation Research Institute, SPring-8, Sayo-cho, Sayo-gun, Hyogo 679-5198 (Japan); Fukushima, K. [National Cerebral and Cardiovascular Center Hospital, Fujishirodai, Suita-shi, Osaka 565-8565 (Japan)

2013-03-15T23:59:59.000Z

416

Selective Gaseous Extraction: Research, Development and Training for Isotope Production, Final Technical Report  

SciTech Connect (OSTI)

General Atomics and the University of Missouri Research Reactor (MURR) completed research and development of selective gaseous extraction of fission products from irradiated fuel, which included training and education of MURR students. The process used porous fuel and after irradiation flowed product gases through the fuel to selectively removed desired fission products with the primary goal of demonstrating the removal of rhodium 105. High removal rates for the ruthenium/rhodium (Ru/Rh), tellurium/iodine (Te/I) and molybdenum/technetium (Mo/Tc) series were demonstrated. The success of this research provides for the reuse of the target for further production, significantly reducing the production of actinide wastes relative to processes that dissolve the target. This effort was conducted under DOE funding (DE-SC0007772). General Atomics objective of the project was to conduct R&D on alternative methods to produce a number of radioactive isotopes currently needed for medical and industry applications to include rhodium-105 and other useful isotopes. Selective gaseous extraction was shown to be effective at removing radioisotopes of the ruthenium/rhodium, tellurium/iodine and molybdenum/technetium decay chains while having trace to no quantities of other fission products or actinides. This adds a new, credible method to the area of certain commercial isotope production beyond current techniques, while providing significant potential reduction of process wastes. Waste reduction, along with reduced processing time/cost provides for superior economic feasibility which may allow domestic production under full cost recovery practices. This provides the potential for improved access to domestically produced isotopes for medical diagnostics and treatment at reduced cost, providing for the public good.

Bertch, Timothy C, [General Atomics

2014-03-31T23:59:59.000Z

417

Dissolver Off-gas Hot Operations Authorization (AFCI CETE Milestone Report)  

SciTech Connect (OSTI)

The head-end processing of the Coupled-End-to-End (CETE) Demonstration includes fuel receipt, fuel disassembly, exposure of fuel (e.g., by segmenting the fuel pins), voloxidation of the fuel to separate tritium, and fuel dissolution. All of these processing steps with the exception of the dissolution step will be accomplished in the Irradiated Fuels Examination Laboratory (IFEL) (Building 3525). The final headend step will be performed in the Radiochemical Engineering Development Center (Building 7920). The primary purpose of the fuel dissolution step is to prepare the solid fuel for subsequent liquid separations steps. This is accomplished by dissolving the fuel solids using nitric acid. During the dissolution process gases are evolved. Oxides of nitrogen are the primary off-gas components generated by the reactions of nitric acid and the fuel oxides however, during the dissolution and sparging of the resulting solution, iodine, C-14 as carbon dioxide, xenon, and krypton gasses are also released to the off-gas stream. The Dissolver Off-gas treatment rack provides a means of trapping these volatile fission products and other gases via various trapping media. Specifically the rack will recover iodine on a solid sorbent bed, scrub NOx in a water/acid column, scrub CO{sub 2} in a caustic scrubber column, remove moisture with solid sorbent drier beds and recover Xe and Kr using solid absorbent beds. The primary purpose of this experimental rack and the off-gas rack associated with the voloxidation equipment located at IFEL is to close the material balances around the volatile gases and to provide an understanding of the impacts of specific processing conditions on the fractions of the volatile components released from the various head-end processing steps.

Jubin, Robert Thomas [ORNL

2009-06-01T23:59:59.000Z

418

Assessment of radionuclide vapor-phase transport in unsaturated tuff  

SciTech Connect (OSTI)

This report describes bounding calculations performed to investigate the possibility of radionuclide migration in a vapor phase associated with the emplacement of high-level waste canister in unsaturated tuff formations. Two potential radionuclide transport mechanisms in the vapor phase were examined: aerosol migration and convection/diffusion of volatile species. The former may have significant impact on the release of radionuclides to the accessible environment as the concentration in the aerosols will be equal to that in the ground water. A conservative analysis of air diffusion in a stagnant liquid film indicated that for all expected repository conditions, aerosol formation is not possible. The migration of volatile species was examined both in the vicinity of a waste canister and outside the thermally disturbed zone. Two-dimensional (radial) and three-dimensional (radial-vertical) coupled heat transfer-gas flow-liquid flow simulations were performed using the TOUGH computer code. The gas flow rate relative to the liquid flow rate predicted from the simulations allowed calculations of mobility ratios due to convection which led to the conclusion that, except for the immediate region near the canister, transport in the liquid phase will be dominant for radionuclides heavier than radon. Near the waste canister, iodine transport may also be important in the vapor phase. Bounding calculations for vertical mobility ratios were carried out as a function of saturation. These calculations are conservative and agree well with the two-dimensional simulations. Based on this analysis, it is clear that vapor-phase transport will not be important for radionuclides such as cesium and heavier species. Vapor transport for iodine may play a role in the overall release scenario depending on the particular repository conditions.

Smith, D.M.; Updegraff, C.D.; Bonano, E.J.; Randall, J.D.

1986-11-01T23:59:59.000Z

419

Modeling Fission Product Sorption in Graphite Structures  

SciTech Connect (OSTI)

The goal of this project is to determine changes in adsorption and desorption of fission products to/from nuclear-grade graphite in response to a changing chemical environment. First, the project team will employ principle calculations and thermodynamic analysis to predict stability of fission products on graphite in the presence of structural defects commonly observed in very high- temperature reactor (VHTR) graphites. Desorption rates will be determined as a function of partial pressure of oxygen and iodine, relative humidity, and temperature. They will then carry out experimental characterization to determine the statistical distribution of structural features. This structural information will yield distributions of binding sites to be used as an input for a sorption model. Sorption isotherms calculated under this project will contribute to understanding of the physical bases of the source terms that are used in higher-level codes that model fission product transport and retention in graphite. The project will include the following tasks: Perform structural characterization of the VHTR graphite to determine crystallographic phases, defect structures and their distribution, volume fraction of coke, and amount of sp2 versus sp3 bonding. This information will be used as guidance for ab initio modeling and as input for sorptivity models; Perform ab initio calculations of binding energies to determine stability of fission products on the different sorption sites present in nuclear graphite microstructures. The project will use density functional theory (DFT) methods to calculate binding energies in vacuum and in oxidizing environments. The team will also calculate stability of iodine complexes with fission products on graphite sorption sites; Model graphite sorption isotherms to quantify concentration of fission products in graphite. The binding energies will be combined with a Langmuir isotherm statistical model to predict the sorbed concentration of fission products on each type of graphite site. The model will include multiple simultaneous adsorbing species, which will allow for competitive adsorption effects between different fission product species and O and OH (for modeling accident conditions).

Szlufarska, Izabela [University of Wisconsin, Madison, WI (United States); Morgan, Dane [University of Wisconsin, Madison, WI (United States); Allen, Todd [University of Wisconsin, Madison, WI (United States)

2013-04-08T23:59:59.000Z

420

Photodissociation dynamics of C{sub 3}H{sub 5}I in the near-ultraviolet region  

SciTech Connect (OSTI)

The ultraviolet photodissociation dynamics of allyl iodide (C{sub 3}H{sub 5}I) have been studied by ion-imaging at 266 nm and 213 nm. These photolysis wavelengths are located in the two lowest absorption bands in the near-ultraviolet region. The atomic iodine products were detected by [2+1] resonantly enhanced multiphoton ionization spectroscopy. The spectra showed that the branching fraction for the spin-orbit excited ({sup 2}P{sub 1/2}) state was larger than that for the ground ({sup 2}P{sub 3/2}) state at both photolysis wavelengths. The state-resolved scattering images of iodine showed two maxima in the velocity distributions in the {sup 2}P{sub 3/2} state and a single peak in the {sup 2}P{sub 1/2} state. The spin-orbit specificity indicates that the C?I bond cleavage at both absorption bands is governed by the dissociative n{sub I}?{sup *}{sub C?I} potential energy surfaces. The nascent internal energy distribution of the allyl radical (C{sub 3}H{sub 5}) counter product, which was obtained by the analysis of the state-resolved scattering distributions, showed a marked difference between the photolysis at 266 nm and 213 nm. The generation of the colder C{sub 3}H{sub 5} with the higher translational energy at 266 nm implied the direct photoexcitation to the n{sub I}?{sup *}{sub C?I} repulsive surfaces, whereas the internally hot C{sub 3}H{sub 5} at 213 nm was ascribed to the local ?{sub CC}?{sup *}{sub CC} photoinitiation in the allyl framework followed by predissociation to the n{sub I}?{sup *}{sub C?I} states.

Sumida, Masataka; Hanada, Takuya; Yamasaki, Katsuyoshi; Kohguchi, Hiroshi, E-mail: kohguchi@hiroshima-u.ac.jp [Department of Chemistry, Graduate School of Science, Hiroshima University, Kagamiyama 1-3-1, Higashi-Hiroshima, Hiroshima 739-8526 (Japan)

2014-09-14T23:59:59.000Z

Note: This page contains sample records for the topic "iodine phos phorus" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Micro Ion Source Program NA22 Plutonium Detection Portfolio Final Report  

SciTech Connect (OSTI)

The purpose of the micro ion source program was to enhance the performance of thermal ionization mass spectrometry (TIMS) for various actinides and fission products. The proposal hypothesized that when ions are created at the ion optic center of the mass spectrometer, ion transmission is significantly increased and the resulting ion beam is more sharply focused. Computer modeling demonstrated this logic. In order to prove this hypothesis it was first necessary to understand the chemistry and physics governing the particular ion production process that concentrates the emission of ions into a small area. This has been achieved for uranium and technetium, as was shown in the original proposal and the improvement of both the beam transmission and sharpness of focus were proven. Significantly improved analytical methods have been developed for these two elements based upon this research. The iodine portion of the proposal turned out to be impractical due to volatility of iodine and its compounds. We knew this was a possibility prior to research and we proceeded anyway but did not succeed. Plutonium is a potential option, but is not quite up to the performance level of resin beads. Now, we more clearly understand the chemical and physical issues for plutonium, but have not yet translated this knowledge into improved analytical processes. The problems are that plutonium is considerably more difficult to convert to the required intermediate species, plutonium carbide, and the chemical method we developed that works with uranium functions only moderately well with plutonium. We are of the opinion that, with this knowledge, similar progress can be made with plutonium.

James E. Delmore

2010-09-01T23:59:59.000Z

422

Implementation of dual-energy technique for virtual monochromatic and linearly mixed CBCTs  

SciTech Connect (OSTI)

Purpose: To implement dual-energy imaging technique for virtual monochromatic (VM) and linearly mixed (LM) cone beam CTs (CBCTs) and to demonstrate their potential applications in metal artifact reduction and contrast enhancement in image-guided radiation therapy (IGRT). Methods: A bench-top CBCT system was used to acquire 80 kVp and 150 kVp projections, with an additional 0.8 mm tin filtration. To implement the VM technique, these projections were first decomposed into acrylic and aluminum basis material projections to synthesize VM projections, which were then used to reconstruct VM CBCTs. The effect of VM CBCT on the metal artifact reduction was evaluated with an in-house titanium-BB phantom. The optimal VM energy to maximize contrast-to-noise ratio (CNR) for iodine contrast and minimize beam hardening in VM CBCT was determined using a water phantom containing two iodine concentrations. The LM technique was implemented by linearly combining the low-energy (80 kVp) and high-energy (150 kVp) CBCTs. The dose partitioning between low-energy and high-energy CBCTs was varied (20%, 40%, 60%, and 80% for low-energy) while keeping total dose approximately equal to single-energy CBCTs, measured using an ion chamber. Noise levels and CNRs for four tissue types were investigated for dual-energy LM CBCTs in comparison with single-energy CBCTs at 80, 100, 125, and 150 kVp. Results: The VM technique showed substantial reduction of metal artifacts at 100 keV with a 40% reduction in the background standard deviation compared to a 125 kVp single-energy scan of equal dose. The VM energy to maximize CNR for both iodine concentrations and minimize beam hardening in the metal-free object was 50 keV and 60 keV, respectively. The difference of average noise levels measured in the phantom background was 1.2% between dual-energy LM CBCTs and equivalent-dose single-energy CBCTs. CNR values in the LM CBCTs of any dose partitioning are better than those of 150 kVp single-energy CBCTs. The average CNR for four tissue types with 80% dose fraction at low-energy showed 9.0% and 4.1% improvement relative to 100 kVp and 125 kVp single-energy CBCTs, respectively. CNRs for low-contrast objects improved as dose partitioning was more heavily weighted toward low-energy (80 kVp) for LM CBCTs. Conclusions: Dual-energy CBCT imaging techniques were implemented to synthesize VM CBCT and LM CBCTs. VM CBCT was effective at achieving metal artifact reduction. Depending on the dose-partitioning scheme, LM CBCT demonstrated the potential to improve CNR for low contrast objects compared to single-energy CBCT acquired with equivalent dose.

Li Hao; Giles, William; Ren Lei; Bowsher, James; Yin Fangfang [Medical Physics Graduate Program, Duke University, Durham, North Carolina 27710 (United States); Department of Radiation Oncology, Duke University Medical Center, Durham, North Carolina 27710 (United States)

2012-10-15T23:59:59.000Z

423

Anatomical noise in contrast-enhanced digital mammography. Part II. Dual-energy imaging  

SciTech Connect (OSTI)

Purpose: Dual-energy (DE) contrast-enhanced digital mammography (CEDM) uses an iodinated contrast agent in combination with digital mammography (DM) to evaluate lesions on the basis of tumor angiogenesis. In DE imaging, low-energy (LE) and high-energy (HE) images are acquired after contrast administration and their logarithms are subtracted to cancel the appearance of normal breast tissue. Often there is incomplete signal cancellation in the subtracted images, creating a background “clutter” that can impair lesion detection. This is the second component of a two-part report on anatomical noise in CEDM. In Part I the authors characterized the anatomical noise for single-energy (SE) temporal subtraction CEDM by a power law, with model parameters ? and ?. In this work the authors quantify the anatomical noise in DE CEDM clinical images and compare this with the noise in SE CEDM. The influence on the anatomical noise of the presence of iodine in the breast, the timing of imaging postcontrast administration, and the x-ray energy used for acquisition are each evaluated.Methods: The power law parameters, ? and ?, were measured from unprocessed LE and HE images and from DE subtracted images to quantify the anatomical noise. A total of 98 DE CEDM cases acquired in a previous clinical pilot study were assessed. Conventional DM images from 75 of the women were evaluated for comparison with DE CEDM. The influence of the imaging technique on anatomical noise was determined from an analysis of differences between the power law parameters as measured in DM, LE, HE, and DE subtracted images for each subject.Results: In DE CEDM, weighted image subtraction lowers ? to about 1.1 from 3.2 and 3.1 in LE and HE unprocessed images, respectively. The presence of iodine has a small but significant effect in LE images, reducing ? by about 0.07 compared to DM, with ? unchanged. Increasing the x-ray energy, from that typical in DM to a HE beam, significantly decreases ? by about 2 × 10{sup ?5} mm{sup 2}, and lowers ? by about 0.14 compared to LE images. A comparison of SE and DE CEDM at 4 min postcontrast shows equivalent power law parameters in unprocessed images, and lower ? and ? by about 3 × 10{sup ?5} mm{sup 2} and 0.50, respectively, in DE versus SE subtracted images.Conclusions: Image subtraction in both SE and DE CEDM reduces ? by over a factor of 2, while maintaining ? below that in DM. Given the equivalent ? between SE and DE unprocessed CEDM images, and the smaller anatomical noise in the DE subtracted images, the DE approach may have an advantage over SE CEDM. It will be necessary to test this potential advantage in future lesion detectability experiments, which account for realistic lesion signals. The authors' results suggest that LE images could be used in place of DM images in CEDM exam interpretation.

Hill, Melissa L.; Yaffe, Martin J. [Sunnybrook Research Institute, 2075 Bayview Avenue, Toronto, Ontario M4N 3M5, Canada and Department of Medical Biophysics, University of Toronto, 2075 Bayview Avenue, Toronto, Ontario M4N 3M5 (Canada)] [Sunnybrook Research Institute, 2075 Bayview Avenue, Toronto, Ontario M4N 3M5, Canada and Department of Medical Biophysics, University of Toronto, 2075 Bayview Avenue, Toronto, Ontario M4N 3M5 (Canada); Mainprize, James G. [Sunnybrook Research Institute, 2075 Bayview Avenue, Toronto, Ontario M4N 3M5 (Canada)] [Sunnybrook Research Institute, 2075 Bayview Avenue, Toronto, Ontario M4N 3M5 (Canada); Carton, Ann-Katherine; Saab-Puong, Sylvie; Iordache, R?zvan; Muller, Serge [GE Healthcare, 283 rue de la Miničre, Buc 78530 (France)] [GE Healthcare, 283 rue de la Miničre, Buc 78530 (France); Jong, Roberta A. [Breast Imaging, Sunnybrook Health Sciences Centre, 2075 Bayview Avenue, Toronto, Ontario M4N 3M5 (Canada)] [Breast Imaging, Sunnybrook Health Sciences Centre, 2075 Bayview Avenue, Toronto, Ontario M4N 3M5 (Canada); Dromain, Clarisse [Department of Radiology, Institut Gustave Roussy, 39 rue Camille Desmoulin, Villejuif 94805 (France)] [Department of Radiology, Institut Gustave Roussy, 39 rue Camille Desmoulin, Villejuif 94805 (France)

2013-08-15T23:59:59.000Z

424

Final Report, "Molecular Design of Hydrocarbon Oxidation Catalytic Processes"  

SciTech Connect (OSTI)

The main goal of this project had been to use model systems to correlate selectivities in partial oxidation catalysis with the presence of specific sites on the surface of the catalyst. Extensive work was performed this year on characterizing oxygen-treated nickel surfaces by chemical means. Specifically, the surface chemistry of ammonia coadsorbed with atomic oxygen on Ni(110) single-crystal surfaces was studied by temperature-programmed desorption (TPD) and X-ray photoelectron spectroscopy (XPS). It was determined that at intermediate oxygen coverages direct ammonia adsorption on nickel sites is suppressed, but a new high-temperature reaction regime is generated at 400 K where NHx surface fragments are rehydrogenated concurrently with the production of water and molecular hydrogen. The extensive isotope scrambling and hydrogen transfer seen from nitrogen- to oxygen-containing surface intermediates, and the optimum yields seen for this 400 K state at intermediate oxygen coverages, strongly suggest the direct interaction of the adsorbed ammonia with oxygen atoms at the end of the –Ni–O- rows that form upon reconstruction of the surface. Hydrogen transfer between ammonia and oxygen appears to take place directly via hydrogen bonding, and to be reversible but biased towards water formation. An equilibrium is reached between the produced water and the reacting surface oxygen and hydrogen. The strong influence of the OH surface groups on the thermal chemistry of the adsorbed ammonia was interpreted in terms of the adsorbing geometry of the OH groups on the surface, and of hydrogen bonding between adsorbed OH and NH3 species. In terms of alcohol reactivity, the adsorption of 2-iodoethanol, a precursor for the preparation of 2-hydroxyethyl and oxametallacycle surface species, was found to lead to two configurations involving either just the iodine atom or both iodine and hydroxyl ends of the molecule. A complex chemical behavior starts around 140 K with the production of small amounts of ethylene and water, most likely via the concerted decomposition or disproportionation of the adsorbed molecular species. The bulk of the 2-iodoethanol decomposes at about 150 K via an initial carbon-iodine scission to form –O(H)CH2CH2– (~80%) and 2-hydroxyethyl (~20%) intermediates. Two competing reactions are involved with the subsequent conversion of the 2-hydroxyethyl species around 160 K, a reductive elimination with surface hydrogen to yield ethanol, and a ?-H elimination to surface vinyl alcohol. The –O(H)CH2CH2–, on the other hand, dehydrogenates to a –OCH2CH2– oxametallacycle species about the same temperature. Both 2-hydroxyethyl and oxametallacycle species tautomerize to acetaldehyde, around 210 K and above 250 K, respectively, and some of that acetaldehyde desorbs while the rest decomposes to hydrogen and carbon monoxide. We contend that a better understanding of the surface chemistry of oxygen-containing surfaces can lead to better selectivities in catalysis. This is arguably the most important issue in the field of catalysis in the near future, and one that impacts several technologies of interest to DOE such as the manufacturing of speciality chemicals and the control and removal of pollutants. Additional work was performed on the characterization of the chemistry of methyl and methylene adsorbed species on oxygen-treated nickel surfaces. Complex chemistry was observed involving not only hydrogenation and dehydrogenation steps, but also C-C couplings and methylene insertions to produce heavier hydrocarbons, and oxygen insertion reactions that yield oxygenates. Finally, a dual titration technique employing xenon and a chemically sensitive probe was developed to identify minority catalytic sites on oxide surfaces. In the case of oxygen-treated Ni(110) single crystals, it was found that both hydrogen transfer with adsorbed water or ammonia and certain hydrocarbon hydrogenation reactions take place at the end of the –Ni–O rows that form in this system. Carbon and nitrogen oxides, on the other hand, display no pre

Professor Francisco Zaera

2007-08-09T23:59:59.000Z

425

Preparation and evaluation of 3-methyl isomers of 15-(p-iodophenyl)-3-methylpentadecanoic acid (BMIPP): 3R-BMIPP shows greater heart uptake than 3S-BMIPP in rats  

SciTech Connect (OSTI)

Iodine-123 racemic (3-R,S) BMIPP is of widespread interest for evaluation of myocardial viability. To evaluate the effects of the asymmetric C-3 center of BMIPP on heart uptake/clearance we have resolved and characterized 3R- and 3S-BMIPP (H-1 and C-13 NMR, MS, HPLC, [{alpha}], m.p.) and evaluated the radioiodinated isomers in rats. A thiophene {open_quotes}template{close_quotes} approach using ethyl 3R-methylglutarate was used to synthesize the authentic 3R-BMPPA substrate (mp 41-42 {degrees}C, [{alpha}] + 1.45 {degrees}). Reaction of racemic 3-R, S-BNPPA with S-(-)-{alpha}-methylbenzylamine gave the diastereomeric amides, separated by TLC, column or HPLC. The more polar isomer was identical to the amide prepared from the 3R-isomer. HCI cleavage of the purified diastereomers provided 3R- and 3S-BMPPA (mp 40-41 {degrees}C, [{alpha}] - 3.90 {degrees}). Iodination (TTFAA/KI) gave 3R-BMIPP (mp 51-52 {degrees}C, [{alpha}] + 0.74 {degrees}) and 3S-BMIPP (mp 45-46 {degrees}C, [{alpha}] - 1.67 {degrees}), which formed amides identical with the two amides separated from the 3-R, S-BMIPP amide mixture. A [I-125]-3R-BMIPP and [I-131]-3S-BMIPP mixture was administered to groups of fasted rats (n = 5/group) sacrificed at 5, 15, 60 and 180 minutes. While blood levels and uptake and clearance from liver, lungs and kidney were nearly identical for both isomers, 3R-BMIPP had higher heart uptake at all periods evaluated (%ID/gram, i.e., 15 min: 3R = 5.25 {plus_minus} 0.77, 3S= 4.51 {plus_minus} 0.50; 180 min: 3R = 2.31 {plus_minus} 0.51, 3S = 1.98 {plus_minus} 0.26), suggesting that transport into the myocytes is different for the isomers. Higher heart uptake suggests that the 3R-BMIPP isomer should be further evaluated.

Knapp, F.F.R. Jr.; Lin, Q.; Luo, H. [Oak Ridge National Lab., TN (United States)] [and others

1996-05-01T23:59:59.000Z

426

The effects of gantry tilt on breast dose and image noise in cardiac CT  

SciTech Connect (OSTI)

Purpose: This study investigated the effects of tilted-gantry acquisition on image noise and glandular breast dose in females during cardiac computed tomography (CT) scans. Reducing the dose to glandular breast tissue is important due to its high radiosensitivity and limited diagnostic significance in cardiac CT scans.Methods: Tilted-gantry acquisition was investigated through computer simulations and experimental measurements. Upon IRB approval, eight voxelized phantoms were constructed from previously acquired cardiac CT datasets. Monte Carlo simulations quantified the dose deposited in glandular breast tissue over a range of tilt angles. The effects of tilted-gantry acquisition on breast dose were measured on a clinical CT scanner (CT750HD, GE Healthcare) using an anthropomorphic phantom with MOSFET dosimeters in the breast regions. In both simulations and experiments, scans were performed at gantry tilt angles of 0°–30°, in 5° increments. The percent change in breast dose was calculated relative to the nontilted scan for all tilt angles. The percent change in noise standard deviation due to gantry tilt was calculated in all reconstructed simulated and experimental images.Results: Tilting the gantry reduced the breast dose in all simulated and experimental phantoms, with generally greater dose reduction at increased gantry tilts. For example, at 30° gantry tilt, the dosimeters located in the superior, middle, and inferior breast regions measured dose reductions of 74%, 61%, and 9%, respectively. The simulations estimated 0%–30% total breast dose reduction across the eight phantoms and range of tilt angles. However, tilted-gantry acquisition also increased the noise standard deviation in the simulated phantoms by 2%–50% due to increased pathlength through the iodine-filled heart. The experimental phantom, which did not contain iodine in the blood, demonstrated decreased breast dose and decreased noise at all gantry tilt angles.Conclusions: Tilting the gantry reduced the dose to the breast, while also increasing noise standard deviation. Overall, the noise increase outweighed the dose reduction for the eight voxelized phantoms, suggesting that tilted gantry acquisition may not be beneficial for reducing breast dose while maintaining image quality.

Hoppe, Michael E.; Gandhi, Diksha; Schmidt, Taly Gilat [Department of Biomedical Engineering, Marquette University, Milwaukee, Wisconsin 53233 (United States)] [Department of Biomedical Engineering, Marquette University, Milwaukee, Wisconsin 53233 (United States); Stevens, Grant M. [GE Healthcare, Waukesha, Wisconsin 53188 (United States)] [GE Healthcare, Waukesha, Wisconsin 53188 (United States); Foley, W. Dennis [Department of Radiology, Medical College of Wisconsin, Froedtert Memorial Lutheran Hospital, Milwaukee, Wisconsin 53226 (United States)] [Department of Radiology, Medical College of Wisconsin, Froedtert Memorial Lutheran Hospital, Milwaukee, Wisconsin 53226 (United States)

2013-12-15T23:59:59.000Z

427

Reservoir environment of the Onuma geothermal power plant, northeast Japan, estimated by forward analysis of long-term artificial-tracer concentration change, using single-box-model simulator  

SciTech Connect (OSTI)

A single-box-model numerical simulator for personal computer analysis was developed in order to estimate macroscopic parameter values for exploited geothermal reservoirs and essential fluids coming from the depth. The simulator was designed to compute history data concerning total production and reinjection fluids at geothermal power plants from the assumed parameter values, based on conservation laws for water mass, heat energy and masses of conservative chemical constituents of geothermal fluids. Using two kinds of forward analysis techniques, i.e. the cast-net and pursuit methods, programs containing the simulator can semiautomatically select the optimum combination of the unknown parameter values by minimizing the differences between the simulated and measured history data for specific enthalpy and chemical compositions of the production fluids. The forward analysis programs were applied to the history data from the Onuma geothermal power plant (production capacity, 10MWe) where waste hot water reinjection, chemical monitoring and artificial tracer tests have been conducted since 1970, almost the beginning of the geothermal exploitation. Using the history data, enthalpy and iodine concentrations of the total production fluids with the amounts of KI tracer injected as spikes, the macroscopic parameter values for the exploited reservoir and the essential hot water from the depth were uniquely determined as follows: mass of the hot water convecting in the exploited reservoir (M0), 3.23x109kg; recycling fraction of the reinjected waste hot water to the reservoir (R), 0.74; specific enthalpy of the essential water from the depth (H1), 385kcalkg; iodine concentration of the water (I1), 0.086mg/kg with chlorine concentration (C1), 259mg/kg. These results support the conceptual model that the exploited Onuma reservoir mainly in the Tertiary volcanics is supplied with the neutral Na-Cl type hot water of abnormally high B/CI mole ratio of around 1.0 by a large essential reservoir distributed at depth in the Paleozoic to Mesozoic detrital marine sedimentary rocks.

Shigeno, Hiroshi; Takahashi, Masaaki; Tetsuro, Noda

1993-01-28T23:59:59.000Z

428

The extended chain compounds Ln {sub 12}(C{sub 2}){sub 3}I{sub 17} (Ln=Pr, Nd, Gd, Dy): Synthesis, structure and physical properties  

SciTech Connect (OSTI)

The title compounds are obtained in high yield from stoichiometric mixtures of Ln, LnI{sub 3} and graphite, heated at 900-950 deg. C in welded Ta containers. The crystal structures of new Pr and Nd phases determined by single-crystal X-ray diffraction are related to those of other Ln {sub 12}(C{sub 2}){sub 3}I{sub 17}-type compounds (C 2/c, a=19.610(1) and 19.574(4) A, b=12.406(2) and 12.393(3) A, c=19.062(5) and 19.003(5) A, {beta}=90.45(3){sup o} and 90.41(3){sup o}, for Pr{sub 12}(C{sub 2}){sub 3}I{sub 17} and Nd{sub 12}(C{sub 2}){sub 3}I{sub 17}, respectively). All compounds contain infinite zigzag chains of C{sub 2}-centered metal atom octahedra condensed by edge-sharing into the [tcc] {sub {infinity}} sequence (c=cis, t=trans) and surrounded by edge-bridging iodine atoms as well as by apical iodine atoms that bridge between chains. The polycrystalline Gd{sub 12}(C{sub 2}){sub 3}I{sub 17} sample exhibits semiconducting thermal behavior which is consistent with an ionic formulation (Ln {sup 3+}){sub 12}(C{sub 2} {sup 6-}){sub 3}(I{sup -}){sub 17}(e{sup -}) under the assumption that one extra electron is localized in metal-metal bonding. The magnetization measurements on Nd{sub 12}(C{sub 2}){sub 3}I{sub 17}, Gd{sub 12}(C{sub 2}){sub 3}I{sub 17} and Dy{sub 12}(C{sub 2}){sub 3}I{sub 17} indicate the coexistence of competing magnetic interactions leading to spin freezing at T {sub f}=5 K for the Gd phase. The Nd and Dy compounds order antiferromagnetically at T {sub N}=25 and 29 K, respectively. For Dy{sub 12}(C{sub 2}){sub 3}I{sub 17}, a metamagnetic transition is observed at a critical magnetic field H{approx}25 kOe. - Graphical abstract: Zigzag chains of edge-sharing metal atom octahedra in Ln {sub 12}(C{sub 2}){sub 3}I{sub 17}.

Ryazanov, Mikhail [Max-Planck-Institut fuer Festkoerperforschung, Heisenbergstr. 1, D-70569 Stuttgart (Germany); Mattausch, Hansjuergen [Max-Planck-Institut fuer Festkoerperforschung, Heisenbergstr. 1, D-70569 Stuttgart (Germany); Simon, Arndt [Max-Planck-Institut fuer Festkoerperforschung, Heisenbergstr. 1, D-70569 Stuttgart (Germany)], E-mail: A.Simon@fkf.mpg.de

2007-04-15T23:59:59.000Z

429

Peripheral Venous Access Ports: Outcomes Analysis in 109 Patients  

SciTech Connect (OSTI)

Purpose: To perform a retrospective outcomes analysis of central venous catheters with peripheral venous access ports, with comparison to published data.Methods: One hundred and twelve central venous catheters with peripherally placed access ports were placed under sonographic guidance in 109 patients over a 4-year period. Ports were placed for the administration of chemotherapy, hyperalimentation, long-term antibiotic therapy, gamma-globulin therapy, and frequent blood sampling. A vein in the upper arm was accessed in each case and the catheter was passed to the superior vena cava or right atrium. Povidone iodine skin preparation was used in the first 65 port insertions. A combination of Iodophor solution and povidone iodine solution was used in the last 47 port insertions. Forty patients received low-dose (1 mg) warfarin sodium beginning the day after port insertion. Three patients received higher doses of warfarin sodium for preexistent venous thrombosis. Catheter performance and complications were assessed and compared with published data.Results: Access into the basilic or brachial veins was obtained in all cases. Ports remained functional for a total of 28,936 patient days. The port functioned in 50% of patients until completion of therapy, or the patient's expiration. Ports were removed prior to completion of therapy in 18% of patients. Eleven patients (9.9% of ports placed) suffered an infectious complication (0.38 per thousand catheter-days)-in nine, at the port implantation site, in two along the catheter. In all 11 instances the port was removed. Port pocket infection in the early postoperative period occurred in three patients (4.7%) receiving a Betadine prep vs two patients (4.2%) receiving a standard O.R. prep. This difference was not statistically significant (p = 0.9). Venous thrombosis occurred in three patients (6.8%) receiving warfarin sodium and in two patients (3%) not receiving warfarin sodium. This difference was not statistically significant (p = 0.6). Aspiration occlusion occurred in 13 patients (11.7%). Intracatheter urokinase was infused in eight of these patients and successfully restored catheter function in all but two instances. These complication rates are comparable to or better than those reported with chest ports.Conclusion: Peripheral ports for long-term central venous access placed by interventional radiologists in the interventional radiology suite are as safe and as effective as chest ports.

Bodner, Leonard J.; Nosher, John L.; Patel, Kaushik M.; Siegel, Randall L.; Biswal, Rajiv; Gribbin, Christopher E.; Tokarz, Robert [Department of Radiology, MEB 404, UMDNJ-Robert Wood Johnson Medical School, One Robert Wood Johnson Place, New Brunswick, NJ 08903-0019 (United States)

2000-03-15T23:59:59.000Z

430

Ligands for SPECT and PET imaging of muscarinic-cholinergic receptors of the heart and brain  

SciTech Connect (OSTI)

Interest in the potential use of cerebral SPECT and PET imaging for determination of the density and activity of muscarinic-cholinergic receptors (mAChR) has been stimulated by the changes in these receptors which occur in many neurological diseases. In addition, the important involvement of mAChR in modulating negative inotropic cardiac activity suggests that such receptor ligands may have important applications in evaluation of changes which may occur in cardiac disease. In this paper, the properties of several key muscarinic receptor ligands being developed or which have been used for clinical SPECT and PET are discussed. In addition, the ORNL development of the new iodinated IQNP ligand based on QNB and the results of in vivo biodistribution studies in rats, in vitro competitive binding studies and ex vivo autoradiographic experiments are described. The use of radioiodinated IQNP may offer several advantages in comparison to IQNB because of its easy and high yield preparation and high brain uptake and the potential usefulness of the {open_quotes}partial{close_quotes} subtype selective IONP isomers. We also describe the development of new IQNP-type analogues which offer the opportunity for radiolabeling with positron-emitting radioisotopes (carbon-11, fluorine-18 and bromine-76) for potential use with PET.

Knapp, F.F. Jr.; McPherson, D.W.; Luo, H. [and others

1995-06-01T23:59:59.000Z

431

Correlation of hetorogeneous blood flow and uptake of a di-methyl-branched IODO fatty acid in the normal and ischemic dog heart  

SciTech Connect (OSTI)

Myocardial blood flow (MBF) is heterogeneously distributed in normal and ischemic myocardium (myoc). Methylated iodinated fatty acids, like 15-(p-I-125-iodophenyl)-3,3-dimethylpentadecanoic acid (DMIPPA) can be used to study fatty acid metabolism with SPECT. We studied the relationship between DMIPPA uptake and MBF. In 10 open-chest dogs, ischemica was induced in the LAD coronary artery by an extra-corporal bypass system. MBF was measured with Sc-46 labeled microspheres. Fourty min. after DMIPPA iv. (34{plus_minus}4 MBq), hearts were excised and left ventricles were cut into 120 pieces, weighed and radioactivities counted. MBF and DMIPPA uptake were determined by counting in normal and ischemic myoc. Heterogeneity is expressed as the coefficient of variation (CV) and agreement as the CV of the DMIPPA uptake to MBF ratio. A control study, normal flow in LAD, in 4 dogs revealed no differences in MBF or DMIPPA uptake between the cannulated versus native perfused myoc. We conclude the DMIPPA detects ischemia, in which it shows a different relation with MBF compared to normal myoc. DMIPPA is less heterogeneously distributed than MBF and agreement between MFB and DMIPPA uptake decreases during ischemia.

Sloof, G.W.; Visser, F.C.; Comans, E.F.I. [Free Univ. Hospital, Amsterdam (Netherlands)]|[Oak Ridge National Lab., TN (United States)] [and others

1995-05-01T23:59:59.000Z

432

Novel Chemical Strategies for Labeling Small Molecule Ligands for Androgen, Progestin, and Peroxisome Proliferator-Activated Receptors for Imaging Prostate and Breast Cancer and the Heart  

SciTech Connect (OSTI)

Summary of Progress The specific aims of this project can be summarized as follows: • Aim 1: Prepare and evaluate radiolabeled ligands for the peroxisome proliferator-activated receptor ? (PPAR?), a new nuclear hormone receptor target for tumor imaging and hormone therapy. • Aim 2: Prepare steroids labeled with a cyclopentadienyl tricarbonyl technetium or rhenium unit. • Aim 3: Prepare and evaluate other organometallic systems of novel design as ligand mimics and halogenated ligands for nuclear hormone receptor-based tumor imaging. As is described in detail below, we made excellent progress on all three of these aims; the highlights of our progress are the following: • we have prepared the first fluorine-18 labeled analogs of ligands for the PPAR? receptor and used these in tissue distribution studies in rats • we have developed three new methods for the synthesis of cyclopentadienyltricarbonyl rhenium and technetium (CpRe(CO)3 and CpTc(CO)3) systems and we have adapted these to the synthesis of steroids labeled with these metals, as well as ligands for other receptor systems • we have prepared a number of fluorine-18 labeled steroidal and non-steroidal androgens and measured their tissue distribution in rats • we have prepared iodine and bromine-labeled progestins with high progesterone receptor binding affinity • we have prepared inorganic metal tricarbonyl complexes and steroid receptor ligands in which the metal tricarbonyl unit is an integral part off the ligand core.

Katzenellenbogen, John, A.

2007-04-19T23:59:59.000Z

433

Fission-product-release signatures for LWR fuel rods failed during PCM and RIA transients  

SciTech Connect (OSTI)

This paper discusses fission product release from light-water-reactor-type fuel rods to the coolant loop during design basis accident tests. One of the tests was a power-cooling-mismatch test in which a single fuel rod was operated in film boiling beyond failure. Other tests discussed include reactivity initiated accident (RIA) tests, in which the fuel rods failed as a result of power bursts that produced radial-average peak fuel enthalpies ranging from 250 to 350 cal/g. One of the RIA tests used two previously irradiated fuel rods. On-line gamma spectroscopic measurements of short-lived fission products, and important aspects of fission product behavior observed during the tests, are discussed. Time-dependent release fractions for short-lived fission products are compared with release fractions suggested by: the Reactor Safety Study; NRC Regulatory Guides; and measurements from the Three Mile Island accident. Iodine behavior observed during the tests is discussed, and fuel powdering is identified as a source of particulate fission product activity, the latter of which is neglected for most accident analyses.

Osetek, D.J.; King, J.J.; Croucher, D.W.

1981-01-01T23:59:59.000Z

434

SL-1 Accident Briefing Report - 1961 Nuclear Reactor Meltdown Educational Documentary  

SciTech Connect (OSTI)

U.S. Atomic Energy Commission (Idaho Operations Office) briefing about the SL-1 Nuclear Reactor Meltdown. The SL-1, or Stationary Low-Power Reactor Number One, was a United States Army experimental nuclear power reactor which underwent a steam explosion and meltdown on January 3, 1961, killing its three operators. The direct cause was the improper withdrawal of the central control rod, responsible for absorbing neutrons in the reactor core. The event is the only known fatal reactor accident in the United States. The accident released about 80 curies (3.0 TBq) of Iodine-131, which was not considered significant due to its location in a remote desert of Idaho. About 1,100 curies (41 TBq) of fission products were released into the atmosphere. The facility, located at the National Reactor Testing Station approximately 40 miles (64 km) west of Idaho Falls, Idaho, was part of the Army Nuclear Power Program and was known as the Argonne Low Power Reactor (ALPR) during its design and build phase. It was intended to provide electrical power and heat for small, remote military facilities, such as radar sites near the Arctic Circle, and those in the DEW Line. The design power was 3 MW (thermal). Operating power was 200 kW electrical and 400 kW thermal for space heating. In the accident, the core power level reached nearly 20 GW in just four milliseconds, precipitating the reactor accident and steam explosion.

None

2013-09-25T23:59:59.000Z

435

Effect of turing pattern indicators on CIMA oscillators  

SciTech Connect (OSTI)

Past experiments on Turing patterns have all been conducted using the chlorite-iodide-malonic acid (CIMA) reaction with Thiodene from Prolabo as an indicator. In this work two other indicators have been examined and found to yield Turing patterns similar to those obtained with Thiodene: soluble starch and poly(vinyl alcohol) (PVA). The present work shows that Thiodene is not simply a soluble starch, as previously assumed, but is probably made by mixing about 7% starch with 93% molten urea. To determine whether the indicators might also effect the chemical kinetics, the effect of the indicators was examined in batch studies of two CIMA systems: the minimal CIMA system (chlorine dioxide-iodine-malonic acid) and the CIMA-Cl system (chlorine dioxide-iodomalonic acid-chloride). It was found that starch and poly(vinyl alcohol) affect the dynamics of the minimal CIMA oscillator but they have no effect on the CIMA-Cl system. On the other hand, in the same or even larger weight/volume concentration glucose and 2-propanol has no effect on the minimal CIMA system. These finding prove that starch and poly(vinyl alcohol) participate exclusively in triiodide complex-forming reactions: they react with an enzyme-like selectivity. Thiodene, however, has an effect on the CIMA-Cl reaction because of its urea content. 19 refs., 6 figs.

Noszticzius, Z. [Univ. of Texas, Austin, TX (United States)]|[Technical Univ. of Budapest (Hungary); Qi Ouyang; McCormick, W.D.; Swinney, H.L. [Univ. of Texas, Austin, TX (United States)

1992-07-23T23:59:59.000Z

436

Long-lived oscillations in the chlorite-iodide-malonic acid reaction in batch  

SciTech Connect (OSTI)

The title reaction is the subject of current interest because the first experimental Turing patterns were observed recently in this system. Here, the authors report the first observation of oscillations that are long lived (over 1 h) in this system in a batch reactor; even after cessation the oscillations can be restarted several times by adding ClO{sub 2} to the exhausted system. These low-frequency low-amplitude (LL) oscillations were detected with both platinum and iodide-selective electrodes in the chlorite-iodide-malonic acid (original CIMA) reaction and in the closely related chlorine dioxide-iodide-malonic acid (minimal CIMA) system. The LL oscillations follow after the already known high frequency oscillations, sometimes separated by a second induction period. LL oscillations can appear without any induction period if appropriate concentrations of chlorine dioxide, iodomalonic acid, and chloride (CIMA-Cl system) are established in a dilute sulfuric acid medium. In this case neither iodine, iodide, nor malonic acid is needed. Some suggestions are made regarding the mechanism of these newly discovered oscillations. 33 refs., 6 figs., 1 tab.

Noszticzius, Z.; Ouyang, Qi; McCormick, W.D.; Swinney, H.L. [Univ. of Texas, Austin, TX (United States)

1992-05-20T23:59:59.000Z

437

Localized structures and front propagation in the Lengyel-Epstein model  

SciTech Connect (OSTI)

Pattern selection, localized structure formation, and front propagation are analyzed within the framework of a model for the chlorine dioxide--iodine--malonic acid reaction that represents a key to understanding recently obtained Turing structures. This model is distinguished from previously studied, simple reaction-diffusion models by producing a strongly subcritical transition to stripes. The wave number for the modes of maximum linear gain is calculated and compared with the dominant wave number for the finally selected, stationary structures grown from the homogeneous steady state or developed behind a traveling front. The speed of propagation for a front between the homogeneous steady state and a one-dimensional (1D) Turing structure is obtained. This velocity shows a characteristic change in behavior at the crossover between the subcritical and supercritical regimes for the Turing bifurcation. In the subcritical regime there is an interval where the front velocity vanishes as a result of a pinning of the front to the underlying structure. In 2D, two different nucleation mechanisms for hexagonal structures are illustrated on the Lengyel-Epstein and the Brusselator model. Finally, the observation of 1D and 2D spirals with Turing-induced cores is reported.

Jensen, O.; Pannbacker, V.O.; Mosekilde, E.; Dewel, G.; Borckmans, P. (Physics Department, Technical University of Denmark, 2800 Lyngby (Denmark) Service de Chimie-Physique, Code Postal 231 Universite Libre de Bruxelles, 1050 Brussels (Belgium))

1994-08-01T23:59:59.000Z

438

H-Area seepage basins groundwater monitoring report. Volume 1, First and second quarters 1995  

SciTech Connect (OSTI)

Groundwater at the H-Area Seepage Basins (HASB) is monitored in compliance with the September 30, 1992, modification of South Carolina Hazardous Waste Permit SCl-890-008-989. The monitoring wells network is composed of 130 HSB wells that monitor the three separate hydrostratigraphic units that make up the uppermost aquifer beneath the HASB. A detailed description of the uppermost aquifer is included in the Resource Conservation and Recovery Act Part B post-closure care permit application for the H-Area Hazardous Waste Management Facility submitted to the South Carolina Department of Health and Environmental Control (SCDHEC) in December 1990. Data from 16 HSL wells are included in this report only to provide additional information for the HASB. Monitoring results are compared to the SCDHEC Groundwater Protection Standard (GWPS), established in Appendix IIID-A of the permit. Historically as well as currently, nitrate, nonvolatile beta, and tritium have been among the primary constituents to exceed standards. Other radionuclides and hazardous constituents also exceeded the GWPS in the groundwater at the HASB (notably aluminum, iodine-129, strontium-90, and zinc) during the first half of 1995. Elevated constituents were found primarily in Aquifer Zone IIB and in the upper portion of Aquifer Zone IIB. However, constituents exceeding standards also occurred in several wells screened in the lower portion of Aquifer Zone IIB, and Aquifer Unit IIA.

NONE

1995-09-01T23:59:59.000Z

439

H-Area Seepage Basins groundwater monitoring report. Volume 1, First and second quarters 1993  

SciTech Connect (OSTI)

During the first half of 1993, the groundwater at the H-Area Seepage Basins (HASB) was monitored in compliance with the September 30, 1992, modification of South Carolina Hazardous Waste Permit. Samples were collected from 130 wells that monitor the three separate hydrostratigraphic units that make up the uppermost aquifer beneath the HASB. A detailed description of the uppermost aquifer is included in the Resource Conservation and Recovery Act Part B Post-Closure Care Permit Application for the H-Area Hazardous Waste Management Facility submitted to the South Carolina Department of Health and Environmental Control (SCDHEC) in December 1990. HASB`s Groundwater Protection Standard is the standard for comparison. Historically, as well as currently, gross alpha, nitrate, nonvolatile beta, and tritium have been among the primary constituents to exceed standards. Other radionuclides and hazardous constituents also exceeded the GWPS in the groundwater at the HASB, notably aluminum, iodine-129, mercury, nickel-63, strontium-89, strontium-90, technetium-99, and zinc during the first half of 1993. Elevated constituents are found primarily in Aquifer Zone IIB{sub 2} (Water Table) and in the upper portion of Aquifer Zone IIB{sub 1}. However, constituents exceeding standards also occur in several wells screened in the lower portion of Aquifer Zone IIB{sub 1} and Aquifer Unit IIA.

Not Available

1993-09-01T23:59:59.000Z

440

Selecting activated carbon for water and wastewater treatability studies  

SciTech Connect (OSTI)

A series of follow-up investigations were performed to produce data for improving the four-indicator carbon selection method that we developed to identify high-potential activated carbons effective for removing specific organic water pollutants. The carbon's pore structure and surface chemistry are dependent on the raw material and the activation process. Coconut carbons have relatively more small pores than large pores; coal and apricot nutshell/walnut shell fruit carbons have the desirable pore structures for removing adsorbates of all sizes. Chemical activation, excessive activation, and/or thermal reactivation enlarge small pores, resulting in reduced phenol number and higher tannic acid number. Activated carbon's phenol, iodine, methylene blue, and tannic acid numbers are convenient indicators of its surface area and pore volume of pore diameters < 10, 10-15, 15-28, and > 28 angstrom, respectively. The phenol number of a carbon is also a good indicator of its surface acidity of oxygen-containing organic functional groups that affect the adsorptive capacity for aromatic and other small polar organics. The tannic acid number is an indicator of carbon's capacity for large, high-molecular-weight natural organic precursors of disinfection by-products in water treatment. The experimental results for removing nitrobenzene, methyl-tert-butyl ether, 4,4-bisphenol, humic acid, and the organic constituents of a biologically treated coking-plant effluent have demonstrated the effectiveness of this capacity-indicator-based method of carbon selection.

Zhang, W.; Chang, Q.G.; Liu, W.D.; Li, B.J.; Jiang, W.X.; Fu, L.J.; Ying, W.C. [East China University of Chemical Technology, Shanghai (China)

2007-10-15T23:59:59.000Z

Note: This page contains sample records for the topic "iodine phos phorus" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


441

Integrated municipal solid waste treatment using a grate furnace incinerator: The Indaver case  

SciTech Connect (OSTI)

An integrated installation for treatment of municipal solid waste and comparable waste from industrial origin is described. It consists of three grate furnace lines with flue gas treatment by half-wet scrubbing followed by wet scrubbing, and an installation for wet treatment of bottom ash. It is demonstrated that this integrated installation combines high recovery of energy (40.8% net) with high materials recovery. The following fractions were obtained after wet treatment of the bottom ash: ferrous metals, non-ferrous metals, three granulate fractions with different particle sizes, and sludge. The ferrous and non-ferrous metal fractions can both be recycled as high quality raw materials; the two larger particle size particle fractions can be applied as secondary raw materials in building applications; the sand fraction can be used for applications on a landfill; and the sludge is landfilled. For all components of interest, emissions to air are below the limit values. The integrated grate furnace installation is characterised by zero wastewater discharge and high occupational safety. Moreover, with the considered installation, major pollutants, such as PCDD/PCDF, Hg and iodine-136 are to a large extent removed from the environment and concentrated in a small residual waste stream (flue gas cleaning residue), which can be landfilled after stabilisation.

Vandecasteele, C. [Department of Chemical Engineering, Katholieke Universiteit Leuven, De Croylaan 46, 3001 Leuven (Belgium)], E-mail: carlo.vandecasteele@cit.kuleuven.be; Wauters, G. [Indaver, Dijle 17a, 2800 Mechelen (Belgium); Arickx, S. [Department of Chemical Engineering, Katholieke Universiteit Leuven, De Croylaan 46, 3001 Leuven (Belgium); Jaspers, M. [Indaver, Dijle 17a, 2800 Mechelen (Belgium); Van Gerven, T. [Department of Chemical Engineering, Katholieke Universiteit Leuven, De Croylaan 46, 3001 Leuven (Belgium)

2007-07-01T23:59:59.000Z

442

Load follow simulation of three-dimensional boiling water reactor core by PACS-32 parallel microprocessor system  

SciTech Connect (OSTI)

The three-dimensional boiling water reactor (BWR) core following the daily load was simulated by the use of the processor array for continuum simulation (PACS-32), a newly developed parallel microprocessor system. The PACS system consists of 32 processing units (PUs) (microprocessors) and has a multiinstruction, multidata type architecture, being optimum to the numerical simulation of the partial differential equations. The BWR core model includes the modified twogroup finite difference, coarse-mesh model for neutronics, steady-state model for thermohydraulics, criticality control by core coolant flow, and the time-dependent solution of iodine-xenon dynamics with constant flux level. The analysis of the parallel processing program revealed that the overhead is independent from the number of PUs and that the efficiency of PUs, i.e., the ratio of effective calculation over total, amounts to 75%, even up to 90% if it is limited to the core part. Simulation was made on the daily load follow for 144 h including the weekend, which took 1.3 central processing unit hours by the PACS system. The PACS system demonstrated a computation speed nearly one-tenth that of the large-scale high-speed general purpose computer, with a 25 times better cost performance ratio and showed that the system could be used as the pratical BWR core simulator with more complicated core models.

Hoshino, T.; Shirakawa, T.

1982-03-01T23:59:59.000Z

443

A new approach to control of xenon spatial oscillation during load follow operation via robust servo systems  

SciTech Connect (OSTI)

The control problem of xenon-induced spatial oscillations of PWR in the axial direction during a load following operation is investigated. The system models are described by a one-group diffusion equation with xenon and temperature feed-backs, iodine and xenon dynamic equations, and heat conductions processes. Control is implemented by the full-length and the part-length control rods and the boron concentration. In order to achieve the control purpose, control models are formulated as the design problem of robust servo systems for distributed parameter reactor systems. The total thermal power and the axial offset are chosen as outputs to be controlled. The control systems consist of servo compensators and stabilizing compensators. They are designed based on the finite-dimensional systems which are constructed by linearizing around steady states, approximately by the Galerkin method, and reducing dimensions via the singular perturbation method. A new and simple computational algorithm to obtain an approximate solution of a steady-state neutron balance is developed via the perturbation method. Some results of numerical simulations are shown in order to discuss the effectiveness of the theory developed in this paper. In particular, it is shown that the designed servo systems are robust against model errors with linearization and modal truncation.

Ukai, Hiroyuki; Iwazumi, Tetsuo (Nagoya Inst. of Technology (Japan). Dept. of Electrical and Computer Engineering)

1994-12-01T23:59:59.000Z

444

In situ formation of magnetite reactive barriers in soil for waste stabilization  

DOE Patents [OSTI]

Reactive barriers containing magnetite and methods for making magnetite reactive barriers in situ in soil for sequestering soil contaminants including actinides and heavy metals, organic materials, iodine and technetium are disclosed. According to one embodiment, a two-step reagent introduction into soil takes place. In the first step, free oxygen is removed from the soil by separately injecting into the soil aqueous solutions of iron (II) salt, for example FeCl.sub.2, and base, for example NaOH or NH.sub.3 in about a 1:1 volume ratio. Then, in the second step, similar reagents are injected a second time (however, according to about a 1:2 volume ratio, iron to salt) to form magnetite. The magnetite formation is facilitated, in part, due to slow intrusion of oxygen into the soil from the surface. The invention techniques are suited to injection of reagents into soil in proximity to a contamination plume or source allowing in situ formation of the reactive barrier at the location of waste or hazardous material. Mixing of reagents to form. precipitate is mediated and enhanced through movement of reagents in soil as a result of phenomena including capillary action, movement of groundwater, soil washing and reagent injection pressure.

Moore, Robert C. (Edgewood, NM)

2003-01-01T23:59:59.000Z

445

Characterization of supersonic mixing in a nonreacting Mach 2 combustor  

SciTech Connect (OSTI)

Planar measurements of the injection mole fraction distribution and the velocity field within a nonreacting model SCRAMJET combustor have been made using laser-induced iodine fluorescence. The combustor geometry investigated in this work is staged transverse injection of air into a Mach 2 freestream. A complete three-dimensional survey of the injectant mole fraction distribution has been generated and a single planar velocity measurement has been completed. The measurements reveal the dramatic effect of streamwise vortices on the mixing of the injectant in the near field of the injectors, as well as the rapid mixing generated by staging two field injectors. Analysis of the downstream decay of the maximum injectant mole fraction in this and other nonreacting combustor geometries indicates that the relative rate of injectant mixing well downstream of the injectors is independent of combustor geometry, combustor Mach number, and injectant molecular weight. Mixing within this region of the combustor is dominated by turbulent diffusion within the injectant plume. The transition of the dominant mixing mechanism, from vortex-driven mixing in the near field to turbulent diffusion in the far field, was found to occur in the region between 10 and 20 jet diameters downstream of the injectors. 22 refs.

Hollo, S.D.; Mcdaniel, J.C.; Hartfield, R.J., JR. (Virginia, University, Charlottesville (United States))

1992-01-01T23:59:59.000Z

446

Methods for implementing microbeam radiation therapy  

DOE Patents [OSTI]

A method of performing radiation therapy includes delivering a therapeutic dose such as X-ray only to a target (e.g., tumor) with continuous broad beam (or in-effect continuous) using arrays of parallel planes of radiation (microbeams/microplanar beams). Microbeams spare normal tissues, and when interlaced at a tumor, form a broad-beam for tumor ablation. Bidirectional interlaced microbeam radiation therapy (BIMRT) uses two orthogonal arrays with inter-beam spacing equal to beam thickness. Multidirectional interlaced MRT (MIMRT) includes irradiations of arrays from several angles, which interleave at the target. Contrast agents, such as tungsten and gold, are administered to preferentially increase the target dose relative to the dose in normal tissue. Lighter elements, such as iodine and gadolinium, are used as scattering agents in conjunction with non-interleaving geometries of array(s) (e.g., unidirectional or cross-fired (intersecting) to generate a broad beam effect only within the target by preferentially increasing the valley dose within the tumor.

Dilmanian, F. Avraham; Morris, Gerard M.; Hainfeld, James F.

2007-03-20T23:59:59.000Z

447

Extensive separations (CLEAN) processing strategy compared to TRUEX strategy and sludge wash ion exchange  

SciTech Connect (OSTI)

Numerous pretreatment flowsheets have been proposed for processing the radioactive wastes in Hanford`s 177 underground storage tanks. The CLEAN Option is examined along with two other flowsheet alternatives to quantify the trade-off of greater capital equipment and operating costs for aggressive separations with the reduced waste disposal costs and decreased environmental/health risks. The effect on the volume of HLW glass product and radiotoxicity of the LLW glass or grout product is predicted with current assumptions about waste characteristics and separations processes using a mass balance model. The prediction is made on three principal processing options: washing of tank wastes with removal of cesium and technetium from the supernatant, with washed solids routed directly to the glass (referred to as the Sludge Wash C processing strategy); the previous steps plus dissolution of the solids and removal of transuranic (TRU) elements, uranium, and strontium using solvent extraction processes (referred to as the Transuranic Extraction Option C (TRUEX-C) processing strategy); and an aggressive yet feasible processing strategy for separating the waste components to meet several main goals or objectives (referred to as the CLEAN Option processing strategy), such as the LLW is required to meet the US Nuclear Regulatory Commission Class A limits; concentrations of technetium, iodine, and uranium are reduced as low as reasonably achievable; and HLW will be contained within 1,000 borosilicate glass canisters that meet current Hanford Waste Vitrification Plant glass specifications.

Knutson, B.J.; Jansen, G.; Zimmerman, B.D.; Seeman, S.E. [Westinghouse Hanford Co., Richland, WA (United States); Lauerhass, L.; Hoza, M. [Pacific Northwest Lab., Richland, WA (United States)

1994-08-01T23:59:59.000Z

448

Solar rotation inferred from radial velocities of the sun-as-a-star during the 2012 May 21 eclipse  

E-Print Network [OSTI]

With an aim to examine how much information of solar rotation can be obtained purely spectroscopically by observing the sun-as-a-star during the 2012 May 21 eclipse at Okayama Astrophysical Observatory, we studied the variation of radial velocities (V_r), which were derived by using the iodine-cell technique based on a set of 184 high-dispersion spectra consecutively obtained over the time span of ~4 hours. The resulting V_r(t) was confirmed to show the characteristic variation (Rossiter-McLaughlin effect) caused by time-varying visibility of the solar disk. By comparing the observed V_r(t) curve with the theoretical ones, which were simulated with the latitude (psi) dependent solar rotation law omega(psi) = A + B sin^2(psi) (deg/day), we found that the relation B = -5.5 A + 77 gives the best fit, though separate determinations of A and B were not possible. Since this relationship is consistent with the real values known for the sun (A = 14.5, B = -2.8), we may state that our analysis yielded satisfactory res...

Takeda, Yoichi; Kambe, Eiji; Toda, Hiroyuki; Koyano, Hisashi; Sato, Bun'ei; Nakamura, Yasuhisa; Narita, Norio; Sekii, Takashi

2014-01-01T23:59:59.000Z

449

Method for treating a nuclear process off-gas stream  

DOE Patents [OSTI]

Disclosed is a method for selectively removing and recovering the noble gas and other gaseous components typically emitted during nuclear process operations. The method is adaptable and useful for treating dissolver off-gas effluents released during reprocessing of spent nuclear fuels whereby to permit radioactive contaminant recovery prior to releasing the remaining off-gases to the atmosphere. Briefly, the method sequentially comprises treating the off-gas stream to preliminarily remove NO.sub.x, hydrogen and carbon-containing organic compounds, and semivolatile fission product metal oxide components therefrom; adsorbing iodine components on silver-exchanged mordenite; removing water vapor carried by said stream by means of a molecular sieve; selectively removing the carbon dioxide components of said off-gas stream by means of a molecular sieve; selectively removing xenon in gas phase by passing said stream through a molecular sieve comprising silver-exchanged mordenite; selectively separating krypton from oxygen by means of a molecular sieve comprising silver-exchanged mordenite; selectively separating krypton from the bulk nitrogen stream using a molecular sieve comprising silver-exchanged mordenite cooled to about -140.degree. to -160.degree. C.; concentrating the desorbed krypton upon a molecular sieve comprising silver-exchange mordenite cooled to about -140.degree. to -160.degree. C.; and further cryogenically concentrating, and the recovering for storage, the desorbed krypton.

Pence, Dallas T. (San Diego, CA); Chou, Chun-Chao (San Diego, CA)

1984-01-01T23:59:59.000Z

450

Delayed neutron energy spectra of {sup 87}Br, {sup 88}Br, {sup 89}Br, {sup 90}Br, {sup 137}I, {sup 138}I, {sup 139}I, and {sup 186}Te  

SciTech Connect (OSTI)

In prior publications, the authors reported measurements of the energy spectra of delayed neutrons for the isotope-separated fission product precursors {sup 93}Rb, {sup 94}Rb, {sup 95}Rb, {sup 96}Rb, {sup 97}Rb, {sup 143}Cs, {sup 144}Cs, and {sup 145}Cs. Such studies of delayed neutron energy spectra have important applications in reactor physics, primarily relating to the fundamental role played by delayed neutrons in the kinetic behavior of nuclear reactors. Measurement of the energy spectra of delayed neutrons for the isotope-separated, fission product precursors {sup 87}Br, {sup 88}Br, {sup 89}Br, {sup 90}Br, {sup 137}I, {sup 138}I, {sup 139}I, and {sup 136}Te are reported for an energy range up to 1,213 keV and with lower cutoff energies of 11.1, 11.1, 29.9, 48.9, 14.2, 23.3, 29.9, and 48.9 keV, respectively. These data were obtained at the TRISTAN Isotope Separation On-Line facility using H{sub 2} and CH{sub 4} gas-filled proportional counters. The data for each of the bromine, iodine, and tellurium isotopes show good qualitative agreement with the published {sup 3}He ionization chamber data at energies above {approximately}200 keV. In addition, they provide definitive spectral information down to their respective cut-off energies.

Greenwood, R.C.; Watts, K.D. [Lockheed Idaho Technologies Co., Idaho Falls, ID (United States). Idaho National Engineering Lab.

1997-07-01T23:59:59.000Z

451

Photofragmentation spectra of halogenated methanes in the VUV photon energy range  

SciTech Connect (OSTI)

In this paper an investigation of the photofragmentation of dihalomethanes CH{sub 2}X{sub 2} (X = F, Cl, Br, I) and chlorinated methanes (CH{sub n}Cl{sub 4?n} with n = 0–3) with VUV helium, neon, and argon discharge lamps is reported and the role played by the different halogen atoms is discussed. Halogenated methanes are a class of molecules used in several fields of chemistry and the study of their physical and chemical proprieties is of fundamental interest. In particular their photodissociation and photoionization are of great importance since the decomposition of these compounds in the atmosphere strongly affects the environment. The results of the present work show that the halogen-loss is the predominant fragmentation channel for these molecules in the VUV photon energy range and confirm their role as reservoir of chlorine, bromine, and iodine atoms in the atmosphere. Moreover, the results highlight the peculiar feature of CH{sub 2}F{sub 2} as a source of both fluorine and hydrogen atoms and the characteristic formation of I{sub 2}{sup +} and CH{sub 2}{sup +} ions from the photofragmentation of the CH{sub 2}I{sub 2} molecule.

Cartoni, Antonella, E-mail: antonella.cartoni@uniroma1.it [Dipartimento di Chimica e Tecnologie del Farmaco, Sapienza Universitŕ di Roma, P.le Aldo Moro 5, Roma 00185 (Italy)] [Dipartimento di Chimica e Tecnologie del Farmaco, Sapienza Universitŕ di Roma, P.le Aldo Moro 5, Roma 00185 (Italy); Bolognesi, Paola; Fainelli, Ettore; Avaldi, Lorenzo [CNR-IMIP, Area della Ricerca di Roma 1, Monterotondo Scalo (Rm) 00015 (Italy)] [CNR-IMIP, Area della Ricerca di Roma 1, Monterotondo Scalo (Rm) 00015 (Italy)

2014-05-14T23:59:59.000Z

452

Yucca Mountain Project - Science & Technology Radionuclide Absorbers Development Program Overview  

SciTech Connect (OSTI)

The proposed Yucca Mountain repository is anticipated to be the first facility for long-term disposal of commercial spent nuclear fuel and high-level radioactive waste in the United States. The facility, located in the southern Nevada desert, is currently in the planning stages with initial exploratory excavations completed. It is an underground facility mined into the tuffaceous volcanic rocks that sit above the local water table. The focus of the work described in this paper is the development of radionuclide absorbers or ''getter'' materials for neptunium (Np), iodine (I), and technetium (Tc) for potential deployment in the repository. ''Getter'' materials retard the migration of radionuclides through sorption, reduction, or other chemical and physical processes, thereby slowing or preventing the release and transport of radionuclides. An overview of the objectives and approaches utilized in this work with respect to materials selection and modeling of ion ''getters'' is presented. The benefits of the ''getter'' development program to the United States Department of Energy (US DOE) are outlined.

Hong-Nian Jow; R.C. Moore; K.B. Helean; S. Mattigod; M. Hochella; A.R. Felmy; J. Liu; K. Rosso; G. Fryxell; J. Krumhansl; Y. Wang

2005-01-14T23:59:59.000Z

453

Nuclear medicine program progress report for quarter ending December 31, 1992  

SciTech Connect (OSTI)

We describe the synthesis of the cis- and trans-iodovinyl isomers of the new ORNL cholinergic-muscarinicreceptorligand, 1 -azabicyclo[2.2-2]oct-3-yl[alpha]-hydroxy-[alpha]-(1-iodo-l-propen-3-yl)-[alpha]-phenylacetate ( IQNP''). This agent is prepared in high radiochemical yield, and the racemic mixture shows high specificity and selectivity for the cerebral and myocardial receptors. Since two chiral centers are present in this molecule, it is important to evaluate the importance of the absolute configuration of the two centers on receptor specificity. The tributyltin substrates were carefully separated by column chromatography, converted to the iodine-125 analogues by iododestannylation, and evaluated in rats in vivo. While the E'' (trans) isomer cleared rapidly from the receptor-rich areas of rat brain, the Z'' (cis) isomer showed high uptake in these areas but also high concentration in the cerebellum. In contrast, the E,Z-isomeric mixture showed good uptake and retention in the receptor rich areas. Also described in this report is a description of neutron flux measurements in the hydraulic tube position at the ORNL High Flux Isotope Reactor (HFIR). Also during this period, samples of [l-125]- and [l-131]-labeled racemic IQNP'' were supplied through a collaborative program with the Brookhaven National Laboratory for high resolution autoradiographic studies in rat tissues.

Knapp, F.F. Jr.; Ambrose, K.R.; Beets, A.L.; Callahan, A.P.; McPherson, D.W.; Mirzadeh, S.; Hasan, A.; Lambert, C.R.

1993-03-01T23:59:59.000Z

454

Nuclear medicine program progress report for quarter ending December 31, 1992  

SciTech Connect (OSTI)

We describe the synthesis of the cis- and trans-iodovinyl isomers of the new ORNL cholinergic-muscarinicreceptorligand, 1 -azabicyclo[2.2-2]oct-3-yl{alpha}-hydroxy-{alpha}-(1-iodo-l-propen-3-yl)-{alpha}-phenylacetate (``IQNP``). This agent is prepared in high radiochemical yield, and the racemic mixture shows high specificity and selectivity for the cerebral and myocardial receptors. Since two chiral centers are present in this molecule, it is important to evaluate the importance of the absolute configuration of the two centers on receptor specificity. The tributyltin substrates were carefully separated by column chromatography, converted to the iodine-125 analogues by iododestannylation, and evaluated in rats in vivo. While the ``E`` (trans) isomer cleared rapidly from the receptor-rich areas of rat brain, the ``Z`` (cis) isomer showed high uptake in these areas but also high concentration in the cerebellum. In contrast, the E,Z-isomeric mixture showed good uptake and retention in the receptor rich areas. Also described in this report is a description of neutron flux measurements in the hydraulic tube position at the ORNL High Flux Isotope Reactor (HFIR). Also during this period, samples of [l-125]- and [l-131]-labeled racemic ``IQNP`` were supplied through a collaborative program with the Brookhaven National Laboratory for high resolution autoradiographic studies in rat tissues.

Knapp, F.F. Jr.; Ambrose, K.R.; Beets, A.L.; Callahan, A.P.; McPherson, D.W.; Mirzadeh, S.; Hasan, A.; Lambert, C.R.

1993-03-01T23:59:59.000Z

455

X-ray and synchrotron studies of porous silicon  

SciTech Connect (OSTI)

The results of comprehensive studies of layers of porous silicon of different conductivity types, grown by anodizing standard Si(111) substrates in an electrolyte based on fluoric acid and ethanol with the addition of 5% of iodine and kept in air for a long time, are discussed. Measurements are performed by scanning electron microscopy, high-resolution X-ray diffraction, and ultrasoft X-ray spectroscopy using synchrotron radiation. The structural parameters of the layers (thickness, strain, and porosity) and atomic and chemical composition of the porous-silicon surface are determined. It is found that an oxide layer 1.5-2.3-nm thick is formed on the surface of the silicon skeleton. The near-edge fine structure of the Si 2p absorption spectrum of this layer corresponds to the fine structure of the 2p spectrum of well coordinated SiO{sub 2}. In this case, the fine structure in the Si 2p-edge absorption region of the silicon skeleton is identical to that of the 2p absorption spectrum of crystalline silicon.

Sivkov, V. N., E-mail: svn@dm.komisc.ru [Russian Academy of Sciences, Komi Scientific Center, Ural Branch (Russian Federation); Lomov, A. A. [Russian Academy of Sciences, Physical-Technological Institute (Russian Federation)] [Russian Academy of Sciences, Physical-Technological Institute (Russian Federation); Vasil'ev, A. L. [Russian Academy of Sciences, Shubnikov Institute of Crystallography (Russian Federation)] [Russian Academy of Sciences, Shubnikov Institute of Crystallography (Russian Federation); Nekipelov, S. V. [Komi State Pedagogical Institute (Russian Federation)] [Komi State Pedagogical Institute (Russian Federation); Petrova, O. V. [Russian Academy of Sciences, Komi Scientific Center, Ural Branch (Russian Federation)] [Russian Academy of Sciences, Komi Scientific Center, Ural Branch (Russian Federation)

2013-08-15T23:59:59.000Z

456

Facile method for synthesis of TiO{sub 2} film and its application in high efficiency dye sensitized-solar cell (DSSC)  

SciTech Connect (OSTI)

Dye-sensitized solar cells (DSSC) is a device which converts a solar energy to electrical energy. Different with semiconductor thin film based solar cell, DSSC utilize the sensitized-dye to absorb the photon and semiconductor such as titanium dioxide (TiO{sub 2}) and zinc oxide (ZnO) as a working electrode photoanode. In this report, the preparation of TiO{sub 2} film using a facile method of spray deposition and its application in DSSC have been presented. TiO{sub 2} photoanode was synthesized by growing the droplet of titanium tetraisopropoxide diluted in acid solution on the substrate of conductive glass flourine-doped tin oxide (FTO) with variation of precursor volume. DSSC was assemblied by sandwiching both of photoanode electrode and platinum counter electrode subsequently filling the area between these electrodes with triodine/iodine electrolite solution as redox pairs. The characterization of the as prepared DSSC using solar simulator (AM 1.5G, 100 mW/cm{sup 2}) and I-V source meter Keithley 2400 showed that the performance of DSSC was affected by the precursor volume.. The overall conversion efficiency of DSSC using the optimum TiO{sub 2} film was about 1.97% with the open circuit voltage (V{sub oc}) of 0.73 V, short circuit current density (J{sub sc}) of 4.61 mA and fill factor (FF) of 0.58.

Widiyandari, Hendri, E-mail: h.widiyandari@undip.ac.id; Gunawan, S. K.V.; Suseno, Jatmiko Endro [Department of Physics, Diponegoro University, Jl. Prof. H. Soedarto SH, Semarang, Central Java 50275 (Indonesia); Purwanto, Agus [Department of Chemical Engineering, Sebelas Maret University, Jl. Ir. Sutami No. 36 A, Surakarta (Indonesia); Diharjo, Kuncoro [Department of Mechanical Engineering, Sebelas Maret University, Jl. Ir. Sutami No. 36 A, Surakarta (Indonesia)

2014-02-24T23:59:59.000Z

457

Investigation and Optimization of Biodiesel Chemistry for HCCI Combustion  

SciTech Connect (OSTI)

Over the past 5 years, ORNL has run 95 diesel range fuels in homogene-ous charge compression ignition (HCCI), including 40 bio-diesels and associated diesel fuels in their blending. The bio-diesel blends varied in oxygen content, iodine number, cetane, boiling point distribution, chemical composition, and some contained nitrogen. All fuels were run in an HCCI engine at 1800 rpm, in the power range of 2.5 to 4.5 bar IMEP, using intake air heating for combustion phasing control, and at a compression ratio of 10.6. The engine response to fuel variables has been analyzed statistically. Generally, the engine responded well to fuels with lower nitrogen and oxygen, lower cetane, and lower aromatics. Because of the wide range of fuels combined in the model, it provides only a broad overview of the engine response. It is recommended that data be truncated and re-modeled to obtain finer resolution of engine response to particular fuel variables.

Bunting, Bruce G [ORNL] [ORNL; Bunce, Michael [ORNL] [ORNL; Joyce, Blake [ORNL] [ORNL; Crawford, Robert W [Rincon Ranch Consulting] [Rincon Ranch Consulting

2011-01-01T23:59:59.000Z

458

DISSOLVED CONCENTRATION LIMITS OF RADIOACTIVE ELEMENTS  

SciTech Connect (OSTI)

The purpose of this study is to evaluate dissolved concentration limits (also referred to as solubility limits) of elements with radioactive isotopes under probable repository conditions, based on geochemical modeling calculations using geochemical modeling tools, thermodynamic databases, field measurements, and laboratory experiments. The scope of this modeling activity is to predict dissolved concentrations or solubility limits for 14 elements with radioactive isotopes (actinium, americium, carbon, cesium, iodine, lead, neptunium, plutonium, protactinium, radium, strontium, technetium, thorium, and uranium) important to calculated dose. Model outputs for uranium, plutonium, neptunium, thorium, americium, and protactinium are in the form of tabulated functions with pH and log (line integral) CO{sub 2} as independent variables, plus one or more uncertainty terms. The solubility limits for the remaining elements are either in the form of distributions or single values. The output data from this report are fundamental inputs for Total System Performance Assessment for the License Application (TSPA-LA) to determine the estimated release of these elements from waste packages and the engineered barrier system. Consistent modeling approaches and environmental conditions were used to develop solubility models for all of the actinides. These models cover broad ranges of environmental conditions so that they are applicable to both waste packages and the invert. Uncertainties from thermodynamic data, water chemistry, temperature variation, and activity coefficients have been quantified or otherwise addressed.

NA

2004-11-22T23:59:59.000Z

459

Tritium management in fusion synfuel designs  

SciTech Connect (OSTI)

Two blanket types are being studied: a lithium-sodium pool boiler and a lithium-oxide- or lithium-sodium pool boiler and a lithium-oxide- or aluminate-microsphere moving bed. For each, a wide variety of current technology was considered in handling the tritium. Here, we show the pool boiler with the sulfur-iodine thermochemical cycle first developed and now being piloted by the General Atomic Company. The tritium (T/sub 2/) will be generated in the lithium-sodium mixture where the concentration is approx. 10 ppM and held constant by a scavenging system consisting mainly of permeators. An intermediate sodium loop carries the blanket heat to the thermochemical cycle, and the T/sub 2/ in this loop is held to 1 ppM by a similar scavenging system. With this design, we have maintained blanket inventory at 1 kg of tritium, kept thermochemical cycle losses to 5 Ci/d and environmental loss to 10 Ci/d, and held total plant risk inventory at 7 kg tritium.

Galloway, T.R.

1980-04-25T23:59:59.000Z

460

Advanced sodium fast reactor accident source terms : research needs.  

SciTech Connect (OSTI)

An expert opinion elicitation has been used to evaluate phenomena that could affect releases of radionuclides during accidents at sodium-cooled fast reactors. The intent was to identify research needed to develop a mechanistic model of radionuclide release for licensing and risk assessment purposes. Experts from the USA, France, the European Union, and Japan identified phenomena that could affect the release of radionuclides under hypothesized accident conditions. They qualitatively evaluated the importance of these phenomena and the need for additional experimental research. The experts identified seven phenomena that are of high importance and have a high need for additional experimental research: High temperature release of radionuclides from fuel during an energetic eventEnergetic interactions between molten reactor fuel and sodium coolant and associated transfer of radionuclides from the fuel to the coolantEntrainment of fuel and sodium bond material during the depressurization of a fuel rod with breached claddingRates of radionuclide leaching from fuel by liquid sodiumSurface enrichment of sodium pools by dissolved and suspended radionuclidesThermal decomposition of sodium iodide in the containment atmosphereReactions of iodine species in the containment to form volatile organic iodides. Other issues of high importance were identified that might merit further research as development of the mechanistic model of radionuclide release progressed.

Powers, Dana Auburn; Clement, Bernard [IRSN/DPAM.SEMIC Bt 702, Saint-Paul-lez-Durance, France; Denning, Richard [Ohio State University, Columbus, OH; Ohno, Shuji [Japan Atomic Energy Agency, Ibaraki, Japan; Zeyen, Roland [Institute for Energy Petten, Saint-Paul-lez-Durance, France

2010-09-01T23:59:59.000Z

Note: This page contains sample records for the topic "iodine phos phorus" from the National Library of EnergyBeta (NLEBeta).
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