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Note: This page contains sample records for the topic "iodine phos phorus" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


1

PHYTOPLANKTON, PHOTOSYNTHESIS, AND PH05PHORUS IN ...  

Science Journals Connector (OSTI)

Therefore daily integral photosynthesis at any locality can be calculated from measurements of the chlorophyll concentration and the rate of photosynthesis in a.

2

Iodine in Texas Soils.  

E-Print Network [OSTI]

in order of the increasing average iodine content of their s, the divisions rank as follows, beginning with the lowest: ~tral Basin 1.7 parts per million, East Texas Timber Country Gulf Coast Prairie 3.5, High Plains 3.9, West Cross Timbers to 5..... ................................. .......................................... Gulf Coast Pralrle.. Elackland Pralrles. .......................................... ........................................... Rio .Grande Plain. ............................................... Roll~ng Pla~ns High Pla...

Fraps, G. S. (George Stronach); Fudge, J. F. (Joseph Franklin)

1939-01-01T23:59:59.000Z

3

Iodine content of food groups  

Science Journals Connector (OSTI)

The iodine content of several kinds of foods representing different product groups available on the Swiss market was analyzed by isotope dilution inductively coupled plasma mass spectrometry using the enriched long-lived nuclide 129I. Considerable variations in levels of iodine between single foodstuffs within food groups were found, which also applied for levels in different food groups. The contribution of the food groups to the average daily iodine intake for the Swiss population was estimated from recent food consumption data. Bread and milk were identified as significant sources of iodine in the Swiss diet as they contributed 58 and 29?g/day, respectively. The estimated contribution of all basic food groups to the per capita intake of iodine was approximately 140?g/day, which was somewhat below the amount recognized for adequate nutrition (150?g/day). In view of the additional consumption of iodized kitchen salt, an average of 140?g/day underestimates the actual iodine intake.

M. Haldimann; A. Alt; A. Blanc; K. Blondeau

2005-01-01T23:59:59.000Z

4

It's Elemental - The Element Iodine  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Tellurium Tellurium Previous Element (Tellurium) The Periodic Table of Elements Next Element (Xenon) Xenon The Element Iodine [Click for Isotope Data] 53 I Iodine 126.90447 Atomic Number: 53 Atomic Weight: 126.90447 Melting Point: 386.85 K (113.7°C or 236.7°F) Boiling Point: 457.55 K (184.4°C or 364.0°F) Density: 4.93 grams per cubic centimeter Phase at Room Temperature: Solid Element Classification: Non-metal Period Number: 5 Group Number: 17 Group Name: Halogen What's in a name? From the Greek word for violet, iodes. Say what? Iodine is pronounced as EYE-eh-dine or as EYE-eh-din. History and Uses: Iodine was discovered by the French chemist Barnard Courtois in 1811. Courtois was extracting sodium and potassium compounds from seaweed ash. Once these compounds were removed, he added sulfuric acid (H2SO4) to

5

MSIV leakage airborne iodine transport  

SciTech Connect (OSTI)

Gaseous iodine deposits on surfaces exposed to vapors. Basic chemical and physical principles predict this behavior, and several laboratory and in-plant measurements demonstrate the characteristic. An empirical model was developed that describes the deposition, resuspension, and transformation of airborne radioiodine molecular species as a stream containing these forms moves along its pathway. The model uses a data base of measured values of deposition and resuspension rates in its application and describes the conversion of the more reactive inorganic iodine species I[sub 2] to the less reactive organic species CH[sub 3]I as the iodine deposits and resuspends along the path. It also considers radioactive decay and chemical surface bonding during residence on surfaces. For the 8-day [sup 131]I, decay during the airborne portion of the transport is negligible. Verification of the model included measurement tests of long gaseous-activity sampling lines of different diameters, operated at different flow rates and stream temperatures. The model was applied to the streams at a boiling water reactor nuclear power plant to describe the transport through leaking main steam isolation valves (MSIVs), following a loss-of-coolant accident.

Cline, J.E. (Cline Associates Inc., Rockville, MD (United States))

1993-01-01T23:59:59.000Z

6

Iodine transport analysis in the ESBWR.  

SciTech Connect (OSTI)

A simplified ESBWR MELCOR model was developed to track the transport of iodine released from damaged reactor fuel in a hypothesized core damage accident. To account for the effects of iodine pool chemistry, radiolysis of air and cable insulation, and surface coatings (i.e., paint) the iodine pool model in MELCOR was activated. Modifications were made to MELCOR to add sodium pentaborate as a buffer in the iodine pool chemistry model. An issue of specific interest was whether iodine vapor removed from the drywell vapor space by the PCCS heat exchangers would be sequestered in water pools or if it would be rereleased as vapor back into the drywell. As iodine vapor is not included in the deposition models for diffusiophoresis or thermophoresis in current version of MELCOR, a parametric study was conducted to evaluate the impact of a range of iodine removal coefficients in the PCCS heat exchangers. The study found that higher removal coefficients resulted in a lower mass of iodine vapor in the drywell vapor space.

Kalinich, Donald A.; Gauntt, Randall O.; Young, Michael Francis; Longmire, Pamela

2009-03-01T23:59:59.000Z

7

Iodine monofluoride discharge laser investigation  

SciTech Connect (OSTI)

The results of an experimental investigation to improve the performance of a discharge-pumped iodine monofluoride laser are reported. Lasing was observed at 478.7, 484.7, 490.7, and 496.5 nm. Electrical measurements of the discharge characteristics permitted the energy flow in the circuit to be followed and laser efficiencies to be calculated. Parametric studies of gas mixtures were carried out. By optimizing several parameters, single-pulse lasing energies greater than 50 mJ were obtained.

Harris, D.G.; Blauer, J.A.; Hurlock, S.C. (Rockwell International, Rocketdyne Division, Canoga Park, CA (USA))

1990-10-15T23:59:59.000Z

8

Comparison of dual-energy CT-derived iodine content and iodine overlay of normal, inflammatory and metastatic squamous cell carcinoma cervical lymph nodes  

Science Journals Connector (OSTI)

To evaluate whether dual-energy computed tomography (DECT)-derived iodine content and iodine overlay could differentiate between normal,...

Ahmed M. Tawfik; A. A. Razek; J. Matthias Kerl; N. E. Nour-Eldin

2014-03-01T23:59:59.000Z

9

Subnanosecond photodissociation atomic iodine laser  

SciTech Connect (OSTI)

The Q factor of an iodine photodissociation laser was switched periodically by a quarter-wave Pockels cell. The voltage applied to the cell was produced by discharging a cable line and it represented a sequence of damped trapezoidal pulses with steep edges. The repetition period of the transmission maxima of the switch was equal to the round-trip time of the resonator. The gas mixture consisted of C/sub 3/F/sub 7/I (7--15 Torr) and Ar; the total pressure was 1 atm. A train of subnanosecond laser pulses consisting of 3--4 pulses was obtained. The total energy of the train was 10--20 mJ and the minimum duration of a single pulse was 0.4 nsec.

Acnenkov, V.I.; Belotserkovets, A.V.; Grigorovich, S.V.

1981-09-01T23:59:59.000Z

10

Mixed-layered bismuth-oxygen-iodine materials for capture and waste disposal of radioactive iodine  

DOE Patents [OSTI]

Materials and methods of synthesizing mixed-layered bismuth oxy-iodine materials, which can be synthesized in the presence of aqueous radioactive iodine species found in caustic solutions (e.g. NaOH or KOH). This technology provides a one-step process for both iodine sequestration and storage from nuclear fuel cycles. It results in materials that will be durable for repository conditions much like those found in Waste Isolation Pilot Plant (WIPP) and estimated for Yucca Mountain (YMP). By controlled reactant concentrations, optimized compositions of these mixed-layered bismuth oxy-iodine inorganic materials are produced that have both a high iodine weight percentage and a low solubility in groundwater environments.

Krumhansl, James L; Nenoff, Tina M

2013-02-26T23:59:59.000Z

11

Iodine Solubility in Low-Activity Waste Borosilicate Glass at...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Iodine Solubility in Low-Activity Waste Borosilicate Glass at 1000 C. Iodine Solubility in Low-Activity Waste Borosilicate Glass at 1000 C. Abstract: The purpose of this...

12

J. N. Am. Benthol. Soc., 1992, 11(4):405-419 ? 1992 by The North American Benthological Society  

E-Print Network [OSTI]

reactive phosphorus (SRP)concentrations also decreased along the transect. During the period from June exhibited longitudinal trends. Re- gressions between phosphatase activity and streamwater SRP concentration and between phos- phorus content and streamwater SRP were highly significant for all data combined, with SRP

Rosemond, Amy Daum

13

Biodegradation of organic compounds in vadose zone and aquifer sediments.  

Science Journals Connector (OSTI)

...rotary head. Conventional, steam-cleaned, hollow-stem augers...phos- phorus, by using the ignition method (34); total nitrogen...mineral nitrogen, by using steam distillation (22); and exchangeable...substrates. This suggestion is based on the assumption that the affinities...

A Konopka; R Turco

1991-08-01T23:59:59.000Z

14

Detection of iodine monoxide in the tropical free troposphere  

E-Print Network [OSTI]

19, 2012) Atmospheric iodine monoxide (IO) is a radical that catalytically destroys heat trapping in the remote tropical marine boundary layer (MBL) (2­4). IO further affects the oxidative capacity iodine species over the remote ocean remain poorly understood (11, 14) but are currently thought

15

Viscosity of high-temperature iodine  

Science Journals Connector (OSTI)

The viscosity coefficient of iodine in the temperature range 500?T?3000 K is calculated. Because of the low dissociation energy of the I2 molecules, the dissociation degree of the gas increases quickly with temperature, and I+I2 and I+I collisions must be taken into account in calculations of viscosity at temperatures greater than 1000. Several possible channels for atom-atom interaction are considered, and the resulting collision integrals are averaged over all the important channels. It is also shown that the rigid-sphere model is inaccurate in predictions of the viscosity. The approach of the present work is general and can be used for other diatomic gases with arbitrary dissociation degree.

Steve H. Kang and Joseph A. Kunc

1991-09-15T23:59:59.000Z

16

Iodine in Drinking Waters, Vegetables, Cottonseed Meal, and Roughages.  

E-Print Network [OSTI]

LIBRARY, A & M COLLEGE, G. S. FRAPS and J. F. FUDGE Division of Chemistry TEXAS AGRICULTURAL EXPERIMENT STATION A. B. CONNER, DIRECTOR, College Station, Texas BULLETIN NO. 595 NOVEMBER 1940 -- IODINE IN DRINKING WATERS, VEGETABLES..., COTTONSEED MEAL, AND ROUGEIAGES ! .I rq?,\\?Y - AGRICULTURAL AND MECHANICAL COLLEGE OF TEXAS T. 0. WALTON, President A96-1140-7M-LJ.80 5 [Blank Page in Original Bulletin] Iodine was determined in nearly 500 samples of city and rural drinking waters...

Fudge, J. F. (Joseph Franklin); Fraps, G. S. (George Stronach)

1940-01-01T23:59:59.000Z

17

Recycle of iodine-loaded silver mordenite by hydrogen reduction  

SciTech Connect (OSTI)

In 1977 and 1978, workers at Idaho National Engineering Laboratory (INEL) developed and tested a process for the regeneration and reuse of silver mordenite, AgZ, used to trap iodine from the dissolver off-gas stream of a nuclear fuel reprocessing plant. We were requested by the Airborne Waste Management Program Office of the Department of Energy to perform a confirmatory recycle study using repeated loadings at about 150/sup 0/C with elemental iodine, each followed by a drying step at 300/sup 0/C, then by iodine removal using elemental hydrogen at 500/sup 0/C. The results of our study show that AgZ can be recycled. There was considerable difficulty in stripping the iodine at 500/sup 0/C.; however, this step went reasonably well at 550/sup 0/C or slightly higher, with no apparent loss in the iodine-loading capacity of the AgZ. Large releases of elemental iodine occurred during the drying stage and the early part of the stripping stage. Lead zeolite, which was employed in the original design to trap the HI produced, is ineffective in removal of I/sub 2/. The process needs modification to handle the iodine. Severe corrosion of the stainless steel components of the system resulted from the HI-I/sub 2/-H/sub 2/O mixture. Monel or other halogen-resistant materials need to be examined for this application. Because of difficulty with the stripping stage and with corrosion, the experiments were terminated after 12 cycles. Thus, the maximum lifetime (cycles) of recycle AgZ has not been determined. Mechanistic studies of iodine retention by silver zeolites and of the behavior of silver atoms on the reduction stage would be of assistance in optimizing silver mordenite recycle.

Burger, L.L.; Scheele, R.D.

1982-11-01T23:59:59.000Z

18

E-Print Network 3.0 - atomic iodine laser Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

iodine laser Search Powered by Explorit Topic List Advanced Search Sample search results for: atomic iodine laser Page: << < 1 2 3 4 5 > >> 1 JOURNALDE PHYSIQUEIV ColloqueC7,...

19

Light-Induced Passivation of Si by Iodine Ethanol Solution: Preprint  

SciTech Connect (OSTI)

We report on our observations of light-activated passivation of silicon surfaces by iodine-ethanol solution.

Sopori, B.; Rupnowski, P.; Appel, J.; Guhaabiswas, D.; Anderson-Jackson, L.

2009-02-01T23:59:59.000Z

20

Sorption and transport of iodine species in sediments from the Savannah River and Hanford Sites  

E-Print Network [OSTI]

Sorption and transport of iodine species in sediments from the Savannah River and Hanford Sites analytical techniques to study the sorption and transport behavior of iodine species (iodide, iodate, and 4 and batch experiments to investigate the interconversion, sorption and transport of iodine species

Hu, Qinhong "Max"

Note: This page contains sample records for the topic "iodine phos phorus" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


21

Dry deposition of gaseous elemental iodine on water  

E-Print Network [OSTI]

DRy DEPOSITION OF GASEOUS ELEMENTAL IODINE ON WATER A Thesis by MICHAEL DANA ALLEN Submitted to the Graduate College of Texas AlkM University in partial fulfillment of the requirements for the degree of MASTER OF SCIENCE August 19/4 Ma...Jor SubJect: Nuclear Engineering (Health Physics) DRY DEPOSITION OF GASEOUS ELEMENTAL IODINE ON WATER A Thesis MICHAEL DANA ALLEN Approved as to style and content by: irman of C ttee) ( a of Department) (Member) (Member) August 1974 3. 1. 595') 6...

Allen, Michael Dana

2012-06-07T23:59:59.000Z

22

Aging of Iodine-Loaded Silver Mordenite in NO2  

SciTech Connect (OSTI)

Used nuclear fuel facilities need to control and minimize radioactive emissions. Off-gas systems are designed to remove radioactive contaminants, such as 85Kr, 14C, 3H, and 129I. In an off-gas system, any capture material will be exposed to a gas stream for months at a time. This gas stream may be at elevated temperature and could contain water, NOx gas, or a variety of other constituents comprising the dissolver off-gas stream in a nuclear fuel reprocessing plant. For this reason, it is important to evaluate the effects of long-term exposure, or aging, on proposed capture materials. One material under consideration is reduced silver mordenite (Ag0Z), which is recognized for its efficient iodine capture properties. Iodine is immobilized on Ag0Z as AgI, a solid with low volatility (m.p. ? 500C). The aim of this study was to determine whether extended aging at elevated temperature in a nominally 2% NO2 environment would result in a loss of immobilized iodine from this material due to either physical or chemical changes that might occur during aging. Charges of iodine-loaded reduced silver mordenite (I2-Ag0Z) were exposed to a 2% NO2 environment for 1, 2, 3, and 4 months at 150C, then analyzed for iodine losses The aging study was completed successfully. The material did not visibly change color or form. The results demonstrate that no significant iodine loss was observed over the course of 4 months of 2% NO2 aging of I2-Ag0Z at elevated temperature within the margin of error and the variability (~10%) in the loading along the beds. This provides assurance that iodine will remain immobilized on Ag0Z during extended online use in an off-gas capture treatment system. Future tests should expose I2-Ag0Z to progressively more complex feed gases in an effort to accurately replicate the conditions expected in a reprocessing facility.

Bruffey, Stephanie H. [ORNL; Jubin, Robert Thomas [ORNL; Patton, Kaara K. [ORNL; Walker Jr, Joseph Franklin [ORNL

2014-04-01T23:59:59.000Z

23

Iodine-129 and Iodine-127 speciation in groundwater at the Hanford Site, U.S.: iodate incorporation into calcite  

SciTech Connect (OSTI)

The Hanford Site, the most contaminated nuclear site in the United States, has large radioactive waste plumes containing high 129I levels. The geochemical transport and fate of radioiodine depends largely on its chemical speciation that is greatly affected by environmental factors. This study reports, for the first time, the speciation of stable and radioactive iodine in the groundwater from the Hanford Site. Iodate was the dominant species and accounts for up to 84%, followed by organo-iodine and minimal levels of iodide. The relatively high pH and oxidizing environment may have prevented iodate reduction. Our results identified that calcite precipitation caused by degassing of CO2 during deep groundwater sampling incorporated between 7 to 40% of dissolved iodine (including 127I and 129I) that was originally in the groundwater, transforming dissolved to particulate iodate during sampling. In order to understand the mechanisms underlying iodine incorporation by calcite, laboratory experiments were carried out to replicate this iodine sequestering processes. Two methods were utilized in this study, 1) addition of sodium carbonate; 2) addition of calcium chloride followed by sodium carbonate where the pH was well controlled at ~8.2, which is close to the average pH of Hanford Site groundwater. It was demonstrated that iodate was the main species incorporated into calcite and this incorporation process could be impeded by elevated pH and decreasing ionic strength in groundwater. This study provides critical information for predicting the long-term fate and transport of 129I at the Hanford Site and reveals a potential means for improved remediation strategies of 129I.

Zhang, Saijin [Texas A and M Univ. at Galveston, TX (United States). Dept. of Marine Science; Xu, Chen [Texas A and M Univ. at Galveston, TX (United States). Dept. of Marine Science; Creeley, Danielle [Texas A and M Univ. at Galveston, TX (United States). Dept. of Marine Science; Ho, Yi-Fang [Texas A and M Univ. at Galveston, TX (United States). Dept. of Marine Science; Li, Hsiu-Ping [Texas A and M Univ. at Galveston, TX (United States). Dept. of Marine Science; Grandbois, Russell [Texas A and M Univ. at Galveston, TX (United States). Dept. of Marine Science; Schwehr, Kathy [Texas A and M Univ. at Galveston, TX (United States). Dept. of Marine Science; Kaplan, Daniel I. [Savannah River National Laboratory, Aiken, SC (United States); Yeager, Chris [Los Alamos National Laboratory (LANL), Los Alamos, NM (United States); Wellman, Dawn M. [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Santschi, Peter H. [Texas A and M Univ. at Galveston, TX (United States). Dept. of Marine Science

2013-07-25T23:59:59.000Z

24

Response to Comment on Iodine-129 and Iodine-127 Speciation in Groundwater at Hanford Site, U.S.: Iodate Incorporation into Calcite  

SciTech Connect (OSTI)

In his comment on our paper Iodine-129 and Iodine-127 Speciation in Groundwater at Hanford Site, U.S.: Iodate Incorporation into Calcite, Lu specified three concerns for Zhang et als study,1 including (1) precipitation mechanism (degassing vs freezing), (2) analytical methods, and (3) mass balance control. In response, comparative and comprehensive discussions on the precipitation mechanisms and iodine incorporation can be found in the paper, as well as below. This includes additional experiments of iodine distribution and speciation in calcite precipitates. In addition, the measurements of total iodine in soils/sediment were clarified below as well. The calculations on mass balance in this comment were clarified by using correct data sets. Lu proposed that freezing samples

Zhang, Saijin; Xu, Chen; Creeley, Danielle; Ho, Yi-Fang; Li, Hsiu-Ping; Grandbois, Russell; Schwehr, Kathy; Kaplan, D. I.; Yeager, Chris; Wellman, Dawn M.; Santschi, Peter H.

2013-11-04T23:59:59.000Z

25

Iodine-131 releases from the Hanford Site, 1944--1947  

SciTech Connect (OSTI)

Releases of fission product iodine-131 are calculated for the 1944 through 1947 period from the Hanford Reservation. Releases to the atmosphere were from the ventilation stacks of T and B separation plants. A reconstruction of daily separation plant operations forms the basis of the releases. The reconstruction traces the iodine-131 content of each fuel discharge from the B, D, and F Reactors to the dissolving step in the separation plants. Statistical computer modeling techniques are used to estimate hourly release histories based on sampling mathematical distribution functions that express the uncertainties in the source data and timing. The reported daily, monthly, and yearly estimates are averages and uncertainty ranges are based on 100 independent Monte Carlo realizations'' of the hourly release histories.

Heeb, C.M.

1993-03-01T23:59:59.000Z

26

Iodine Loading of NO Aged Silver Exchanged Mordenite  

SciTech Connect (OSTI)

In an off-gas treatment system for used nuclear fuel processing, a solid sorbent will typically be exposed to a gas stream for months at a time. This gas stream may be at elevated temperature and could contain water vapor, gaseous nitrogen oxides (NO{sub x}), nitric acid vapors, and a variety of other constituents. For this reason, it is important to evaluate the effects of long-term exposure, or aging, on proposed sorbents. Silver exchanged mordenite (AgZ) is being studied at Oak Ridge National Laboratory (ORNL) to determine its iodine sorption capacity after long term exposure to increasingly more complex chemical environments. Studies previously conducted at ORNL investigated the effects of aging reduced silver exchanged mordenite (Ag{sup 0}Z) in dry air, moist air, and NO2. This study investigated the effects of extended exposure to nitric oxide (NO) gas on the iodine capture performance of Ag{sup 0}Z. A deep bed of Ag{sup 0}Z was aged in a 1% nitric oxide (NO) air stream, and portions of the bed were removed at pre-determined intervals. After being removed from the NO stream, each sample was loaded with iodine in a thin bed configuration. These samples were analyzed by neutron activation analysis (NAA) to quantify the iodine content in the sample. Samples were removed at one week and one month. A 78% decrease in sample capacity was seen after one week of exposure, with no further decrease observed after 1 month of aging. The observed loss in capacity is larger in magnitude than previous studies exposing Ag{sup 0}Z to dry air, moist air, or NO2 gas. The aging study was terminated after one month and repeated; this successfully demonstrated the reproducibility of the results.

Patton, K. K. [ORNL; Bruffey, S. H. [ORNL; Jubin, J. T. [ORNL; Walker, Jr., J. F. [ORNL

2014-09-30T23:59:59.000Z

27

Transition of Iodine Analysis to Accelerator Mass Spectrometry  

SciTech Connect (OSTI)

This NA 22 funded research project investigated the transition of iodine isotopic analyses from thermal ionization mass spectrometry (TIMS) to an accelerator mass spectrometry (AMS) system. Previous work (Fiscal Year 2010) had demonstrated comparable data from TIMS and AMS. With AMS providing comparable data with improved background levels and vastly superior sample throughput, improvement in the sample extraction from environmental sample matrices was needed to bring sample preparation throughput closer to the operation level of the instrument. Previous research used an extraction chemistry that was not optimized for yield or refined for reduced labor to prove the principle. This research was done to find an extraction with better yield using less labor per sample to produce a sample ready for the AMS instrument. An extraction method using tetramethyl ammonium hydroxide (TMAH) was developed for removal of iodine species from high volume air filters. The TMAH with gentle heating was superior to the following three extraction methods: ammonium hydroxide aided by sonication, acidic and basic extraction aided by microwave, and ethanol mixed with sodium hydroxide. Taking the iodine from the extraction solvent to being ready for AMS analysis was accomplished by a direct precipitation, as well as, using silver wool to harvest the iodine from the TMAH. Portions of the same filters processed in FY 2010 were processed again with the improved extraction scheme followed by successful analysis by AMS at the Swiss Federal Institute of Technology. The data favorably matched the data obtained in 2010. The time required for analysis has been reduced over the aqueous extraction/AMS approach developed in FY 2010. For a hypothetical batch of 30 samples, the AMS methodology is about 10 times faster than the traditional gas phase chemistry and TIMS analysis. As an additional benefit, background levels for the AMS method are about 1000 times lower than TIMS. This results from the fundamental mechanisms of ionization in the AMS system and which produces a beneficial cleanup of molecular interferences. Continued clean operation of the extraction process was demonstrated through blank analysis included with all sample sets analyzed. INL work showed improvement on the first years demonstration of AMS vs. TIMS. An improved extraction of high volume air filters followed by isotopic analysis by AMS, can be used successfully to make iodine measurements with results comparable to those obtained by filter combustion and TIMS analysis. More progress on the conversion from an extract solution to an AMS sample ready for analysis is still needed. Although the preparation scheme through AMS is already at a higher performing thoughput than TIMS, the chemical preparation cannot match the instrument capability for number of samples per day without further development.

M. L. Adamic; J. E. Olson; D. D. Jenson; J. G. Eisenmenger; M. G. Watrous

2012-09-01T23:59:59.000Z

28

Roles of Naturally Occurring Bacteria in Controlling Iodine-129 Mobility in Subsurface Soils  

E-Print Network [OSTI]

Stable iodine 129I Radioactive iodine-129 238U Uranium-238 ABTS 2, 2-azino-bis-3-ethylbenzothiazoline-6-sulphonic acid ATP Adenosine-5'-triphosphate Br- Bromide Cl- Chloride CoA Coenzyme A DOE Department of Energy DOE-EM Department... 5.5 Discussion ................................................................................ 95 VI SUMMARY ......................................................................................... 100 6.1 Accumulation of I...

Li, Hsiu-Ping

2012-10-19T23:59:59.000Z

29

Iodine stabilization of a diode laser in the optical communication band  

E-Print Network [OSTI]

Iodine stabilization of a diode laser in the optical communication band Hsiang-Chen Chui and Sen September 23, 2004 The iodine molecule has frequently been used as a frequency reference from the green provides a simple, compact, and high-performance frequency reference in the optical communication band

Shy,Jow-Tsong

30

Investigation of silver electrodeposition on polycrystalline platinum by iodine chemisorption  

E-Print Network [OSTI]

Qb)ja'A (12) Silver electrodeposition onto the I-pretreated polycrystalline Pt electrode was done using 2 mM AgC104 in 1 M H2SO4. Under these conditions, Ag deposition consists of two underpotential deposition peaks at 0. 65 and 0. 50 V (peaks 1...INVESTIGATION OF SILVER ELECIRODEPOSITION ON POLYCRYSTALLINE PLATINUM BY IODINE CHEMISORPTION A Thesis by JOHN EUGENE HARRIS Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment of the requirements...

Harris, John Eugene

1988-01-01T23:59:59.000Z

31

Soil Iodine Determination in Deccan Syneclise, India: Implications for Near Surface Geochemical Hydrocarbon Prospecting  

SciTech Connect (OSTI)

The association of iodine with organic matter in sedimentary basins is well documented. High iodine concentration in soils overlying oil and gas fields and areas with hydrocarbon microseepage has been observed and used as a geochemical exploratory tool for hydrocarbons in a few studies. In this study, we measure iodine concentration in soil samples collected from parts of Deccan Syneclise in the west central India to investigate its potential application as a geochemical indicator for hydrocarbons. The Deccan Syneclise consists of rifted depositional sites with Gondwana-Mesozoic sediments up to 3.5 km concealed under the Deccan Traps and is considered prospective for hydrocarbons. The concentration of iodine in soil samples is determined using ICP-MS and the values range between 1.1 and 19.3 ppm. High iodine values are characteristic of the northern part of the sampled region. The total organic carbon (TOC) content of the soil samples range between 0.1 and 1.3%. The TOC correlates poorly with the soil iodine (r{sup 2} < 1), indicating a lack of association of iodine with the surficial organic matter and the possibility of interaction between the seeping hydrocarbons and soil iodine. Further, the distribution pattern of iodine compares well with two surface geochemical indicators: the adsorbed light gaseous hydrocarbons (methane through butane) and the propane-oxidizing bacterial populations in the soil. The integration of geochemical observations show the occurrence of elevated values in the northern part of the study area, which is also coincident with the presence of exposed dyke swarms that probably serve as conduits for hydrocarbon microseepage. The corroboration of iodine with existing geological, geophysical, and geochemical data suggests its efficacy as one of the potential tool in surface geochemical exploration of hydrocarbons. Our study supports Deccan Syneclise to be promising in terms of its hydrocarbon prospects.

Mani, Devleena, E-mail: devleenatiwari@ngri.res.in [National Geophysical Research Institute (Council of Scientific and Industrial Research) (India); Kumar, T. Satish [Oil India Limited (India); Rasheed, M. A.; Patil, D. J.; Dayal, A. M.; Rao, T. Gnaneshwar; Balaram, V. [National Geophysical Research Institute (Council of Scientific and Industrial Research) (India)

2011-03-15T23:59:59.000Z

32

Determination of Iodine-129 in Low Level Radioactive Wastes - 13334  

SciTech Connect (OSTI)

For the radioactivity determination of {sup 129}I in the radioactive wastes, alkali fusion and anion-exchange resin separation methods, which are sample pretreatment methods, have been investigated in this study. To separate and quantify the {sup 129}I radionuclide in an evaporator bottom and spent resin, the radionuclide was chemically leached from the wastes and adsorbed on an anion exchange resin at pH 4, 7, 9. In the case of dry active waste and another solid type, the alkali fusion method was applied. KNO{sub 3} was added as a KOH and oxidizer to the wastes. It was then fused at 450 deg. C for 1 hour. The radioactivity of the separated iodine was measured with a low energy gamma spectrometer after the sample pretreatment. Finally, it was confirmed that the recovery rate of the iodine for the alkali fusion method was 83.63.8%, and 86.41.6% for the anionic exchange separation method. (authors)

Choi, K.C.; Ahn, J.H.; Park, Y.J.; Song, K.S. [Nuclear Chemistry Research Division, Korea Atomic Energy Research Institute, Daejeon, 305-600 (Korea, Republic of)] [Nuclear Chemistry Research Division, Korea Atomic Energy Research Institute, Daejeon, 305-600 (Korea, Republic of)

2013-07-01T23:59:59.000Z

33

Iodine Adsorption on Ion-Exchange Resins and Activated Carbons Batch Testing  

SciTech Connect (OSTI)

Iodine sorption onto seven resins and six carbon materials was evaluated using water from well 299-W19-36 on the Hanford Site. These materials were tested using a range of solution-to-solid ratios. The test results are as follows: The efficacy of the resin and granular activated carbon materials was less than predicted based on manufacturers performance data. It is hypothesized that this is due to the differences in speciation previously determined for Hanford groundwater. The sorption of iodine is affected by the iodine species in the source water. Iodine loading on resins using source water ranged from 1.47 to 1.70 g/g with the corresponding Kd values from 189.9 to 227.0 mL/g. The sorption values when the iodine is converted to iodide ranged from 2.75 to 5.90 g/g with the corresponding Kd values from 536.3 to 2979.6 mL/g. It is recommended that methods to convert iodine to iodide be investigated in fiscal year (FY) 2015. The chemicals used to convert iodine to iodate adversely affected the sorption of iodine onto the carbon materials. Using as-received source water, loading and Kd values ranged from 1.47 to 1.70 g/g and 189.8 to 226.3 mL/g respectively. After treatment, loading and Kd values could not be calculated because there was little change between the initial and final iodine concentration. It is recommended the cause of the decrease in iodine sorption be investigated in FY15. In direct support of CH2M HILL Plateau Remediation Company, Pacific Northwest National Laboratory has evaluated samples from within the 200W pump and treat bioreactors. As part of this analysis, pictures taken within the bioreactor reveal a precipitate that, based on physical properties and known aqueous chemistry, is hypothesized to be iron pyrite or chalcopyrite, which could affect iodine adsorption. It is recommended these materials be tested at different solution-to-solid ratios in FY15 to determine their effect on iodine sorption.

Parker, Kent E.; Golovich, Elizabeth C.; Wellman, Dawn M.

2014-09-30T23:59:59.000Z

34

Converting solar energy into laser radiation using a fullerene-oxygen-iodine laser with solar pumping  

Science Journals Connector (OSTI)

The concept of a system for directly converting solar energy into laser radiation on the basis of a fullerene-oxygen-iodine laser has been developed. It is shown that this system has...

Mak, A A; Belousova, I M; Kiselev, V M; Grenishin, A S; Danilov, O B; Sosnov, E N

2009-01-01T23:59:59.000Z

35

Doping efficiency of single and randomly stacked bilayer graphene by iodine adsorption  

SciTech Connect (OSTI)

We report on the efficiency and thermal stability of p-doping by iodine on single and randomly stacked, weakly coupled bilayer polycrystalline graphene, as directly measured by photoelectron emission microscopy. The doping results in work function value increase of 0.40.5?eV, with a higher degree of iodine uptake by the bilayer (2%) as compared to the single layer (1%) suggesting iodine intercalation in the bilayer. The chemistry of iodine is identified accordingly as I{sub 3}{sup ?} and I{sub 5}{sup ?} poly iodide anionic complexes with slightly higher concentration of I{sub 5}{sup ?} in bilayer than monolayer graphene, likely attributed to differences in doping mechanisms. Temperature dependent in-situ annealing of the doped films demonstrated that the doping remains efficient up to 200?C.

Kim, HoKwon; Renault, Olivier; Rouchon, Denis; Mariolle, Denis; Chevalier, Nicolas [Univ. Grenoble Alpes, F-38000 Grenoble, France and CEA, LETI, MINATEC Campus, F-38054 Grenoble (France); Tyurnina, Anastasia; Simonato, Jean-Pierre; Dijon, Jean [Univ. Grenoble Alpes, F-38000 Grenoble, France and CEA, LITEN, Minatec Campus, F-38054 Grenoble (France)

2014-07-07T23:59:59.000Z

36

Development of Efficient Flowsheet and Transient Modeling for Nuclear Heat Coupled Sulfur Iodine Cyclefor Hydrogen Production  

SciTech Connect (OSTI)

The realization of the hydrogen as an energy carrier for future power sources relies on a practical method of producing hydrogen in large scale with no emission of green house gases. Hydrogen is an energy carrier which can be produced by a thermochemical water splitting process. The Sulfur-Iodine (SI) process is an example of a water splitting method using iodine and sulfur as recycling agents.

Shripad T. Revankar; Nicholas R. Brown; Cheikhou Kane; Seungmin Oh

2010-05-01T23:59:59.000Z

37

Effect of iodine chemical form on thyroid doses during a severe accident  

Science Journals Connector (OSTI)

In most of the accidents that may occur in nuclear reactors, the short-term radiological consequences are expected to be dominated by isotopes of iodine. The assessment of doses resulting from iodine release during a severe reactor accident requires knowledge of the iodine chemical forms and removal mechanisms prior to the release to the environment. In this paper, the arguments concerning iodine chemical form in severe accidents are stated. Removal mechanisms prior to release to the environment are summarised. Various assumptions of iodine chemical form during a severe accident were used to assess the radiation doses to thyroid at site boundaries and at the low population zone of a pressurised water reactor. Doses were calculated for an adult and a ten-year-old child. It was concluded that if the spray system was used prior to the release, with proper additives to raise the pH of the sump, the doses are generally reduced. The main contributor to dose in this case is organic iodine.

Mohamed Y. Khalil; Mohamed S. Nagy; Kamal A. Talha; Mohga I. Hassan

2006-01-01T23:59:59.000Z

38

NO2 Aging and Iodine Loading of Silver-Functionalized Aerogels  

SciTech Connect (OSTI)

Off-gas treatment systems in used fuel reprocessing which use fixed-bed adsorbers are typically designed to operate for an extended period of time before replacement or regeneration of the adsorbent. During this time, the sorbent material will be exposed to the off-gas stream. Exposure could last for months, depending on the replacement cycle time. The gas stream will be at elevated temperature and will possibly contain a mixture of water vapor, NOx, nitric acid vapors, and a variety of other constituents in addition to the radionuclides of capture interest. A series of studies were undertaken to evaluate the effects of long-term exposure, or aging, on proposed iodine sorbent materials under increasingly harsh off-gas conditions. Previous studies have evaluated the effects of up to 6 months of aging under dry air and under humid air conditions on the iodine loading behavior of Ag0-functionalized aerogels. This study examines the effects of extended exposure (up to 6 months) to NO2 on the iodine loading capacity of Ag0- functionalized aerogels. Material aged for 1 and 2 months appeared to have a similar total loading capacity to fresh material. Over an aging period of 4 months, a loss of approximately 15% of the total iodine capacity was seen. The iodine capacity loss on silver-functionalized aerogels due to NO2 was smaller than the iodine capacity loss due to humid or dry air aging.

Patton, K K [ORNL; Bruffey, S H [ORNL; Walker, J F [ORNL; Jubin, R T [ORNL

2014-07-31T23:59:59.000Z

39

The development of autocatalytic structural materials for use in the sulfur-iodine process for the production of hydrogen .  

E-Print Network [OSTI]

??The Sulfur-Iodine Cycle for the thermochemical production of hydrogen offers many benefits to traditional methods of hydrogen production. As opposed to steam methane reforming - (more)

Miu, Kevin (Kevin K.)

2006-01-01T23:59:59.000Z

40

The structure of tissue on cell culture-extracted thyroglobulin is independent of its iodine content  

Science Journals Connector (OSTI)

The major protein synthesized in vitro by the ovine thyroid cell line OVNIS 6H is the prothyroid hormone thyroglobulin. Purified from serum-free cell culture media using sucrose gradient centrifugation, the thyroglobulin dimer was analysed for iodine content and observed by electron microscopy. In their usual medium, the OVNIS 6H cells produce a very poorly iodinated thyroglobulin containing 0.05 I atom per molecule. When cultured with methimazole or propylthiouracil, two inhibitors of iodide organification, less than 0.007 I atom/molecules was found. These molecules purified from cell cultures were compared to those purified from ovine thyroid tissue containing 26 I atoms/mol. Despite large differences in iodine content, the three preparations all consist of 19 S thyroglobulin dimers with the classical ovoidal shape. The variability in size measurements remains in a 2% range for all thyroglobulin types. Consequently, no real significant variation can be found between the highly iodinated thyroglobulin isolated from tissue, and the poorly or non-iodinated thyroglobulins isolated from cells cultured with or without methimazole or propylthiouracil.

E. Delain; A. Aouani; A. Vignal; E. Couture-Tosi; S. Hovspian; G. Fayet

1987-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "iodine phos phorus" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


41

Effects of municipal effluent on algal growth  

E-Print Network [OSTI]

'luent with phos- phorus removed by lime and 3. Secondary eff'luent with phosphorus and nitrogen removed by high lime addition and air stripping. Laboratory experiments demonstrated that the dilution of' the econdary ef'f'luent to 1~0 by volume or tertiary ef... OF TABLES Table ~Pa DILUTIONS OF THE SAMPLES WITH TAP WATER RELATIONSHIP BETWFEN TOTAL PHOSPHORUS CONCENTRATION AND pH TO LI1&iE CONCENTRATION TOTAL KJELDAHL NITROGEN OF THE SECONDARY EFFLUENT AFTER MIXING WITH 750 ppm CaO, FOLLOWED BY 2-HOUR...

Sung, Yeh-Min

2012-06-07T23:59:59.000Z

42

Wafer Preparation and Iodine-Ethanol-Ethanol Passivation Procedure for Reproducible Minority-Carrier Lifetime Measurement: Preprint  

SciTech Connect (OSTI)

This paper describes reasons that lifetime measurments may be irreproducible using iodine-in-ethanol (I-E) passivation. Possible factors include the strength of the iodine in ethanol solution, wafer cleaning procedures, influence of wafer container during lifetime measurement, and stability of I-E.

Sopori, B.; Rupnowski, P.; Appel, J.; Mehta, V.; Li, C.; Johnston, S.

2008-05-01T23:59:59.000Z

43

Continuous-wave laser oscillation on the 1315 nm transition of atomic iodine pumped by O2,,a1  

E-Print Network [OSTI]

diagram of the flow tube setup is shown in Fig. 1. A radio-frequency rf electric discharge at 13.56 MHz nm transition of atomic iodine where the O2 a1 used to pump the iodine was produced by a radio-frequency operating between two internal hollow cathode electrodes was used as the excitation source. The plasma zone

Carroll, David L.

44

Electrochemical study of iodine in the LiAlCl/sub 4/. 3SO/sub 2/ electrolyte  

SciTech Connect (OSTI)

Cyclic voltammograms and chronopotentiometric curves recorded at microelectrodes in LiAlCl/sub 4/ . 3SO/sub 2/ solvate containing iodine reagents are discussed. Iodine reduction was found to be a diffusion-limited process. The product of this reduction reacts with the SO/sub 2/ solvate allowing a catalytic reduction of sulfur dioxide.

Lojou, E.; Messina, R.; Perichon, J. (L.E.C.S.O. (FR)); Descroix, J.P.; Sarre, G. (SAFT (FR))

1989-05-01T23:59:59.000Z

45

Purex Plant gaseous iodine-129 control capability and process development requirements  

SciTech Connect (OSTI)

This report describes the ability of the Purex Plant to effectively control iodine-129 emissions. Based on historical evidence, the current Purex Plant iodine control system appears capable of meeting the goal of limiting gaseous iodine-129 emissions at the point of discharge to levels stipulated by the Department of Energy (DOE) for an uncontrolled area. Expected decontamination factors (DF`s) with the current system will average about 100 and will be above the calculated DF`s of 2.2 and 87 required to meet DOE yearly average concentration limits for controlled and uncontrolled areas respectively, but below the calculated DF of 352 required for meeting the proposed Environmental Protection Agency (EPA) mass emission limit. Chemical costs for maintaining compliance with the DOE limits will be approximately $166 per metric ton of fuel processed (based on a silver nitrate price of $12.38/oz). Costs will increase in proportion to increases in silver prices.

Evoniuk, C.J.

1981-01-01T23:59:59.000Z

46

Ductility loss of ion-irradiated zircaloy-2 in iodine. [55 MeV alpha particles  

SciTech Connect (OSTI)

An ion bombardment simulation technique for neutron irradiation was applied to 'thick' materials to study the effect of radiation damage on the ductility change in Zircaloy-2 in an iodine environment. Specimens were prepared from actual cladding tubes and, prior to the irradiation, they were heat-treated in vacuo at 450, 580, and 700/degree/C for 2 h. Irradiation was performed by 52-MeV alpha particles up to the 0.32 displacements per atom (dpa) at 340/degree/C. Ductility loss begins to appear after 0.03 dpa irradiation, both in iodine and argon gas environments. The iodine presence resulted in ductility reduction, compared with the argon result in all irradiation dose ranges examined. The stress applied during irradiation caused ductility loss to commence at lower dosage than in the case of stress-free irradiation. These results are discussed in relation to the existing stress corrosion cracking models.

Shimada, M.; Terasawa, M.; Yamamoto, S.; Kamei, H.; Koizumi, K.

1981-01-01T23:59:59.000Z

47

Extraction and Quantitative Analysis of Iodine in Solid and Solution Matrixes  

SciTech Connect (OSTI)

129I is a contaminant of interest in the vadose zone and groundwater at numerous federal and privately-owned facilities. Several techniques have been utilized to extract iodine from solid matrices; however, all of them rely on two fundamental approaches: liquid extraction or chemical/heat facilitated volatilization. While these methods are typically chosen for their ease of implementation, they do not totally dissolve the solid. Because some of the iodine partitions onto the soil, extraction methods that do not result in total sample dissolution could underestimate the total iodine content of solid samples. We defined a method that produces complete solid dissolution and conducted laboratory tests to assess its efficacy to completely extract iodine from solid matrices. Testing consisted of potassium nitrate/potassium hydroxide fusion of the sample, followed by sample dissolution in a mixture of sulfuric acid and sodium bisulfite. Direct analysis of the dissolved sample was performed via inductively coupled plasma mass spectrometry (Perkin Elmer Elan DRC II) using a tertiary amine (Spectrasol CFA-C) carrier solution. The fusion extraction method resulted in complete sample dissolution of all solid matrices tested: sediment, glass samples containing low-levels of iodine, as well as tank waste material collected from the Hanford Site. Quantitative analysis of iodine (127I and 129I) showed better than ? 10% accuracy for certified reference standards, with the linear operating range extending more than three orders of magnitude (0.005 to 5 ug/L). Extraction and analysis of four replicates of standard reference material (San Joaquin Soil) from the National Institute of Standards and Technology, Gaithersburg, MD, resulted in an average recovery of 98% with a relative percent deviation of 6%. This simple and cost-effective technique can be applied to solid samples of varying matrices with little or no adaptation.

Brown, Christopher F.; Geiszler, Keith N.; Vickerman, Tanya S.

2005-11-01T23:59:59.000Z

48

Technetium and Iodine Getters to Improve Cast Stone Performance  

SciTech Connect (OSTI)

To determine the effectiveness of the various getter materials prior to their solidification in Cast Stone, a series of batch sorption experiments was performed at Pacific Northwest National Laboratory. To quantify the effectiveness of the removal of Tc(VII) and I(I) from solution by getters, the distribution coefficient, Kd (mL/g), was calculated. Testing involved placing getter material in contact with spiked waste solutions at a 1:100 solid-to-solution ratio for periods up to 45 days with periodic solution sampling. One Tc getter was also tested at a 1:10 solid-to-solution ratio. Two different solution media, 18.2 M? deionized water (DI H2O) and a 7.8 M Na LAW simulant, were used in the batch sorption tests. Each test was conducted at room temperature in an anoxic chamber containing N2 with a small amount of H2 (0.7%) to maintain anoxic conditions. Each getter-solution combination was run in duplicate. Three Tc- and I-doping concentrations were used separately in aliquots of both the 18.2 M? DI H2O and a 7.8 M Na LAW waste simulant. The 1 concentration was developed based on Hanford Tank Waste Operations Simulator (HTWOS) model runs to support the River Protection Project System Plan Revision 6. The other two concentrations were 5 and 10 of the HTWOS values. The Tc and I tests were run separately (i.e., the solutions did not contain both solutes). Sampling of the solid-solution mixtures occurred nominally after 0.2, 1, 3, 6, 9, 12, 15 days and ~35 to 45 days. Seven getter materials were tested for Tc and five materials were tested for I. The seven Tc getters were blast furnace slag 1 (BFS1) (northwest source), BFS2 (southeast source), Sn(II)-treated apatite, Sn(II) chloride, nano tin phosphate, KMS (a potassium-metal-sulfide), and tin hydroxapatite. The five iodine getters were layered bismuth hydroxide (LBH), argentite mineral, synthetic argentite, silver-treated carbon, and silver-treated zeolite. The Tc Kd values measured from experiments conducted using the 7.8 M Na LAW simulant (the simulant selected to represent LAW) for the first 15 days for four Tc getters (BFS1, BFS2, Sn(II)-treated apatite, and Sn(II) chloride) show no, to a very small, capacity to remove Tc from the LAW simulant. For the Tc-getter experiments in the 7.8 M LAW simulant, the majority of the effluent samples show very small drops in Tc concentrations for the 35-day compared to the 15-day samplings. However, the Tc concentration in the simulant blanks also dropped slightly during this period, so the effect of the getter contacting LAW simulant at 35 days compared to 15 days is minimal; except that the BFS1 1:10 test shows a slow but steady decrease in Tc concentration in the LAW simulant supernatant from the beginning to the 35 day contact at which point about 20% of the original Tc has been removed from solution. Lastly, the KMS getter gives the highest Kd value for Tc at 35 days where Kd values have increased to 104 mL/g. When considering the different I getters reacting with the 7.8 M LAW simulant, two getters are much more effective than the others: Ag zeolite and Syn Arg. The other getters have calculated iodide distribution coefficients that show very limited effectiveness in the caustic conditions created by the LAW simulant. These are preliminary results that will need more detailed analyses including both pre- and post-batch sorption getter solid-phase characterization using state-of-the-art instrumentation such as synchrotron X ray absorption spectroscopy, which can delineate the oxidation state of the Tc and likely iodine species as well as some of the getters key major components, sulfur and iron in the BFS, and tin and sulfur in the tin-bearing and sulfur-bearing getters. This report also describes future experimental studies to be performed to better elucidate the mechanisms controlling the Tc and I sequestration processes in the various getters and leach tests of getter-bearing Cast Stone monoliths.

Qafoku, Nikolla; Neeway, James J.; Lawter, Amanda R.; Levitskaia, Tatiana G.; Serne, R. Jeffrey; Westsik, Joseph H.; Snyder, Michelle MV

2014-07-01T23:59:59.000Z

49

8 March 2010 Role of dietary iodine and cruciferous vegetables in thyroid cancer  

E-Print Network [OSTI]

8 March 2010 1 Role of dietary iodine and cruciferous vegetables in thyroid cancer: A countrywide Rougier, MD4 Pascal Guénel, MD, PhD1,2 Author affiliations 1 Environmental Epidemiology of Cancer, CESP: Pascal Guénel, MD, PhD Environmental Epidemiology of Cancer UMRS 1018, Inserm CESP 16 avenue Paul

Paris-Sud XI, Université de

50

Gain recovery in an electric oxygen-iodine laser J. W. Zimmerman,1,a  

E-Print Network [OSTI]

of this experiment shows that reducing the forward pumping rate by an effective factor of approximately 4 to simulate American Institute of Physics. DOI: 10.1063/1.3064163 The electrically driven oxygen-iodine laser Electri passes through a water-cooled heat exchanger and then passes through a duct containing injectors

Carroll, David L.

51

Sources and reservoirs of anthropogenic iodine-129 in western New York  

Science Journals Connector (OSTI)

Large quantities of iodine-129 have been released during nuclear weapons testing, and from nuclear power and fuel reprocessing plants. The distribution of this isotope was investigated in 110 surface water and soil samples from western New York (where several potential point sources are located) and other areas of North America, to evaluate its sources, transport pathways, and reservoirs. Elevated 129I concentrations associated with a former reprocessing facility at West Valley, NY, can be tracked to Lakes Erie and Ontario via site drainage, and for over 200 km via atmospheric transport, while only a negligible signal is associated with active power plants in the area. The results point to local reprocessing as the major source of 129I in western New York, while bomb fallout constitutes less than 0.5% of the signal. Surface soil is the dominant reservoir for anthropogenic 129I in this region. Across North America, 129I concentrations are lower than in western New York, although still significantly higher than expected weapons fallout. Reprocessing releases are currently seen to be the major source for elevated 129I concentrations on a global scale, in contrast to previous suggestions that most anthropogenic 129I was still derived from weapons fallout. Concentrations of 129I and iodine in surface reservoirs are generally found to be uncorrelated, implying that natural iodine and anthropogenic 129I are not yet in equilibrium. The results suggest that anthropogenic 129I is cycled between the atmosphere-soil-vegetation systems more rapidly than natural, pre-anthropogenic iodine.

Usha Rao; Udo Fehn

1999-01-01T23:59:59.000Z

52

THE RELATION OF DETERIORATION OF ORANGE JUICE TO ITS IODINE REDUCING VALUE  

Science Journals Connector (OSTI)

...maturity, variety and treatment on the iodine value...MCNAIR CHICAGO, ILLINOIS WATER SOLUBLE MAGNESIUM IN...this lake from a 1 to 5 water extract, have been...test as an indicator of water soluble and exchangeable...NEW MULTIPLE-UNIT ELECTRODIALYSIS ous fields of science...

M. A. Joslyn; G. L. Marsh

1932-07-22T23:59:59.000Z

53

Deficiencies of sodium and iodine in grazing sheep in northern China  

E-Print Network [OSTI]

Deficiencies of sodium and iodine in grazing sheep in northern China DG Masters JR Lindsay SX Yu DX of Traditional Veterinary Medicine, Chinese Academy of Agricultural Science, Xiaoxihu, Lanzhou, Gansu, China An examination of the mineral status of grazing sheep at 3 sites in northern China has provided evidence

Paris-Sud XI, Université de

54

Singlet oxygen generation using iodinated squaraine and squaraine-rotaxane dyesw  

E-Print Network [OSTI]

Singlet oxygen generation using iodinated squaraine and squaraine-rotaxane dyesw Easwaran Arunkumar-rotaxanes to generate singlet oxygen for potential application in photodynamic therapy (PDT). Specifically, we compare-to-face orientations in the solid state. Singlet oxygen generation efficiency was measured by trapping with 1

Smith, Bradley D.

55

Behavior of mercury and iodine during vitrification of simulated alkaline Purex waste  

SciTech Connect (OSTI)

Current plans indicate that the high-level wastes stored at the Savannah River Plant will be solidified by vitrification. The behavior of mercury and iodine during the vitrification process is of concern because: mercury is present in the waste in high concentrations (0.1 to 2.8 wt%); mercury will react with iodine and the other halogens present in the waste during vitrification and; the mercury compounds formed will be volatilized from the vitrification process placing a high particulate load in the vitrification system off-gas. Twelve experiments were completed to study the behavior of mercury during vitrification of simulated SRP Purex waste. The mercury was completely volatized from the vitrification system in all experiments. The mercury reacted with iodine, chlorine and oxygen to form a fine particulate solid. Quantitative recovery of mercury compounds formed in the vitrification system off-gas was not possible due to high (37 to 90%) deposition of solids in the off-gas piping. The behavior of mercury and iodine was most strongly influenced by the vitrification system atmosphere. During experiments performed in which the oxygen content of the vitrification system atmosphere was low (< 1 vol%); iodine retention in the glass product was 27 to 55%, the mercury composition of the solids recovered from the off-gas scrub solutions was 75 to 85 wt%, and a small quantity of metallic mercury was recovered from the off-gas scrub solution. During experiments performed in which the oxygen content of the vitrification system atmosphere was high (20 vol%), iodide retention in the glass product was 3 to 15%, the mercury composition of the solids recovered from the off-gas scrub solutions was 60 to 80 wt%, and very little metallic mercury was recovered from the off-gas scrub solution.

Holton, L.K.

1981-09-01T23:59:59.000Z

56

Adsorbate-induced corrosion: anodic dissolution of palladium induced by chemisorbed iodine in halide-free acid solutions  

E-Print Network [OSTI]

ADSORBATE-INDUCED CORROSION: ANODIC DISSOLUTION OF PALLADIUM INDUCED BY CHEMISORBED IODINE IN HALIDE-FREE ACID SOLUTIONS A Thesis JANEMARIE A. SCHIMPF Submitted to the Office of Graduate Studies of Texas A&M University in partial fulfillment... of the requirements for the degree of MASTER OF SCIENCE December 1991 Major Subject: Chemistry ADSORBATE-INDUCED CORROSION: ANODIC DISSOLUTION OF PALLADIUM INDUCED BY CHEMISORBED IODINE IN HALIDE-FREE ACID SOLUTIONS A Thesis JANEMARIE A. SCHIMPF Approved...

Schimpf, Janemarie A

2012-06-07T23:59:59.000Z

57

Resistivity measurements of iodine single crystals by an A.C. technique  

E-Print Network [OSTI]

The temperature dep ndence of th. ! capac! tance of tvlo iodine sin;, le crystals. Iiessur. . cents on samp! e 8 acre rinds in the c- crystallo''rcphic diection and those on samo) e C 0 . , 'DPlatl 5 ( !Gout PP5' ) in the a-c p]ane. 20 :t. CI 0 Lu LIJ LJ I... The temperature dep ndence of th. ! capac! tance of tvlo iodine sin;, le crystals. Iiessur. . cents on samp! e 8 acre rinds in the c- crystallo''rcphic diection and those on samo) e C 0 . , 'DPlatl 5 ( !Gout PP5' ) in the a-c p]ane. 20 :t. CI 0 Lu LIJ LJ I...

Intararithi, Thanom

2012-06-07T23:59:59.000Z

58

Expanded Analysis of Hot Isostatic Pressed Iodine-Loaded Silver-Exchanged Mordenite  

SciTech Connect (OSTI)

Reduced silver-exchanged mordenite (Ag0Z) is being evaluated as a potential material to control the release of radioactive iodine that is released during the reprocessing of used nuclear fuel into the plant off-gas streams. The purpose of this study was to determine if hot pressing could directly convert this iodine loaded sorbent into a waste form suitable for long-term disposition. The minimal pretreatment required for production of pressed pellets makes hot pressing a technically and economically desirable process. Initial scoping studies utilized hot uniaxial pressing (HUPing) to prepare samples of non-iodine-loaded reduced silver exchanged mordenite (Ag0Z). The resulting samples were very fragile due to the low pressure (~ 28 MPa) used. It was recommended that hot isostatic pressing (HIPing), performed at higher temperatures and pressures, be investigated. HIPing was carried out in two phases, with a third and final phase currently underway. Phase I evaluated the effects of pressure and temperature conditions on the manufacture of a pressed sample. The base material was an engineered form of silver zeolite. Six samples of Ag0Z and two samples of I-Ag0Z were pressed. It was found that HIPing produced a pressed pellet of high density. Analysis of each pressed pellet by scanning electron microscopy-energy dispersive spectrophotometry (SEM-EDS) and X-ray diffraction (XRD) demonstrated that under the conditions used for pressing, the majority of the material transforms into an amorphous structure. The only crystalline phase observed in the pressed Ag0Z material was SiO2. For the samples loaded with iodine (I-Ag0Z) iodine was present as AgI clusters at low temperatures, and transformed into AgIO4 at high temperatures. Surface mapping and EDS demonstrate segregation between silver iodide phases and silicon dioxide phases. Based on the results of the Phase I study, an expanded test matrix was developed to examine the effects of multiple source materials, compositional variations, and an expanded temperature range. Each sample was analyzed with the approach used in Phase I. In all cases, there is nothing in the SEM or XRD analyses that indicates creation of any AgI-containing silicon phase, with the samples being found to be largely amorphous. Phase III of this study has been initiated and is the final phase of scoping tests. It will expand upon the test matrix completed in Phase II and will examine the durability of the pressed pellets through product consistency testing (PCT) studies. Transformation of the component material into a well-characterized iodine-containing mineral phase would be desirable. This would limit the additional experimental testing and modeling required to determine the long-term stability of the pressed pellet, as much of that information has already been learned for several common iodine-containing minerals. However, this is not an absolute requirement, especially if pellets produced by hot isostatic pressing can be demonstrated through initial PCT studies to retain iodine well despite their amorphous composition.

Jubin, R. T. [ORNL; Bruffey, S. H. [ORNL; Patton, K. K. [ORNL

2014-09-30T23:59:59.000Z

59

What can be learned with an iodine solar-neutrino detector?  

SciTech Connect (OSTI)

We study the potential benefits of an iodine-based solar-neutrino detector for testing hypotheses that involve neutrino oscillations. We argue that such a detector will have a good chance of distinguishing the two allowed regions of {Delta}{ital m}{sup 2}-sin{sup 2}2{theta} parameter space if neutrino conversion is occurring in the Sun. It should also be able to detect seasonal variations in the signal due to vacuum oscillations and might be sensitive enough to detect day/night variations due to MSW transitions in the earth. Although it would need to be calibrated, a working iodine detector could be completed long before more ambitious projects that seek to accomplish the same things.

Engel, J. [Department of Physics and Astronomy, CB3255, University of North Carolina, Chapel Hill, North Carolina 27599 (United States)] [Department of Physics and Astronomy, CB3255, University of North Carolina, Chapel Hill, North Carolina 27599 (United States); Krastev, P.I. [Institute for Advanced Study, Princeton, New Jersey 08540 (United States)] [Institute for Advanced Study, Princeton, New Jersey 08540 (United States); Lande, K. [Department of Astronomy and Astrophysics, University of Pennsylvania, Philadelphia, Pennsylvania 19104 (United States)] [Department of Astronomy and Astrophysics, University of Pennsylvania, Philadelphia, Pennsylvania 19104 (United States)

1995-05-01T23:59:59.000Z

60

Coupling the nickel-iodine-sulphur cycle with a nuclear reactor  

Science Journals Connector (OSTI)

Nuclear hydrogen production is a technically feasible and economically viable option for addressing future energy needs. Several projects have been started on the co-generation of hydrogen and electricity from nuclear energy. In this report, the nickel sulphur iodine (NIS) cycle, a thermochemical water splitting cycle originally developed in ENEA for solar hydrogen production, was studied to be coupled with a new generation nuclear reactor for massive hydrogen production.

Pier Paolo Prosini

2013-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "iodine phos phorus" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


61

Laboratory studies on the evolution of iodine-129 during Purex-uranium metal dissolution  

SciTech Connect (OSTI)

The path of iodine from the Purex dissolver was determined during fuel dissolution using /sup 125/I tracer. Laboratory-scale equipment qualification studies were completed using sections of nonirradiated uranium N-reactor fuel elements. A proof-of-principle dissolution study was completed at the end of FY 1979 in the PNL hot cells using wafers of irradiated N-reactor fuel. The findings include the following: the laboratory-scale dissolver/downdraft condenser was designed at a factor of 5 x 10/sup -5/ of the Purex flowsheet; with no refluxing, 5.6 moles of HNO/sub 3/ were required per mole of dissolved uranium. With NO/sub x/ recovery in the reflux stream, an average of 3.6 moles of HNO/sub 3/ was required. These results formed the basis for adequate modeling of the laboratory Purex downdraft dissolver; approximately 8% of the iodine was found in the final dissolver solution when the /sup 125/I tracer was added to the initial dissolver solution prior to the first cut, 6-h dissolution; when the /sup 125/I was added continuously during the 6-h dissolution without any refluxing of the condenser acid back to the dissolver, approximately 16% of the iodine was found in the dissolver solution; when irradiated N-reactor fuel was dissolved while /sup 125/I tracer was continuously added to the dissolver during the 6-h test, 11% of the /sup 125/I tracer was found in the dissolver solution. After 2 h of refluxing with air sparging, 6% of the /sup 125/I tracer was found in the dissolver solution; and analysis of the fission product /sup 129/I in the fuel duplicated the tracer study results with 8% and 7% of the iodine remaining in the dissolver solution after 6 and 8 h, respectively.

Bray, L.A.

1980-03-01T23:59:59.000Z

62

Atmospheric dispersion and deposition of iodine-131 released from the Hanford Site  

SciTech Connect (OSTI)

Approximately 2.6x10{sup 4} TBq (700,000 curies) of iodine-131 were released to the air from reactor fuel processing plants on the Hanford Site in southcentral Washington State from December 1944 through December 1949. The Hanford Environmental Dose Reconstruction (HEDR) Project developed a suite of codes to estimate the doses that might have resulted from these releases. The Regional Atmospheric Transport Code for Hanford Emission Tracking (RATCHET) computer code is part of this suite. The RATCHET code implements a Lagrangian-trajectory, Gaussian-puff dispersion model that uses hourly meteorological and release rate data to estimate daily time-integrated air concentrations and surface contamination for use in dose estimates. In this model, iodine is treated as a mixture of three species (nominally, inorganic gases, organic gases, and particles). Model deposition parameters are functions of the mixture and meteorological conditions. A resistance model is used to calculate dry deposition velocities. Equilibrium between concentrations in the precipitation and the air near the ground is assumed in calculating wet deposition of gases, and irreversible washout of the particles is assumed. RATCHET explicitly treats the uncertainties in model parameters and meteorological conditions. Uncertainties in iodine-131 release rates and partitioning among the nominal species are treated by varying model input. The results of 100 model runs for December 1944 through December 1949 indicate that monthly average air concentrations and deposition have uncertainties ranging from a factor of two near the center of the time-integrated plume to more than an order of magnitude near the edge. These results indicate that -10% of the iodine-131 released to the atmosphere decayed during transit in the study area, -56% was deposited within the study area, and the remaining 34% was transported out of the study area while still in the air.

Ramsdell, J.V.; Simonen, C.A.; Burk, K.W.; Stage, S.A.

1994-06-01T23:59:59.000Z

63

Physical features of accumulation and distribution processes of small disperse coal dust precipitations and absorbed radioactive chemical elements in iodine air filter at nuclear power plant  

E-Print Network [OSTI]

The physical features of absorption process of radioactive chemical elements and their isotopes in the iodine air filters of the type of AU-1500 at the nuclear power plants are researched. It is shown that the non-homogenous spatial distribution of absorbed radioactive chemical elements and their isotopes in the iodine air filter, probed by the gamma-activation analysis method, is well correlated with the spatial distribution of small disperse coal dust precipitations in the iodine air filter. This circumstance points out to an important role by the small disperse coal dust fractions of absorber in the absorption process of radioactive chemical elements and their isotopes in the iodine air filter. The physical origins of characteristic interaction between the radioactive chemical elements and the accumulated small disperse coal dust precipitations in an iodine air filter are considered. The analysis of influence by the researched physical processes on the technical characteristics and functionality of iodine ...

Ledenyov, Oleg P; Poltinin, P Ya; Fedorova, L I

2012-01-01T23:59:59.000Z

64

Iodine doping effects on the lattice thermal conductivity of oxidized polyacetylene nanofibers  

SciTech Connect (OSTI)

Thermal transport in oxidized polyacetylene (PA) nanofibers with diameters in the range between 74 and 126?nm is measured with the use of a suspended micro heater device. With the error due to both radiation and contact thermal resistance corrected via a differential measurement procedure, the obtained thermal conductivity of oxidized PA nanofibers varies in the range between 0.84 and 1.24?W?m{sup ?1}?K{sup ?1} near room temperature, and decreases by 40%70% after iodine doping. It is also found that the thermal conductivity of oxidized PA nanofibers increases with temperature between 100 and 350?K. Because of exposure to oxygen during sample preparation, the PA nanofibers are oxidized to be electrically insulating before and after iodine doping. The measurement results reveal that iodine doping can result in enhanced lattice disorder and reduced lattice thermal conductivity of PA nanofibers. If the oxidation issue can be addressed via further research to increase the electrical conductivity via doping, the observed suppressed lattice thermal conductivity in doped polymer nanofibers can be useful for the development of such conducting polymer nanostructures for thermoelectric energy conversion.

Bi, Kedong, E-mail: lishi@mail.utexas.edu, E-mail: kedongbi@seu.edu.cn [Jiangsu Key Laboratory for Design and Manufacture of Micro-Nano Biomedical Instruments, School of Mechanical Engineering, Southeast University, Nanjing 211189 (China); Department of Mechanical Engineering, University of Texas at Austin, Austin, Texas 78712 (United States); Weathers, Annie; Pettes, Michael T.; Shi, Li, E-mail: lishi@mail.utexas.edu, E-mail: kedongbi@seu.edu.cn [Department of Mechanical Engineering, University of Texas at Austin, Austin, Texas 78712 (United States); Matsushita, Satoshi; Akagi, Kazuo [Department of Polymer Chemistry, Kyoto University, Kyoto 615-8510 (Japan); Goh, Munju [Department of Polymer Chemistry, Kyoto University, Kyoto 615-8510 (Japan); Institute of Advanced Composite Materials, Korea Institute of Science and Technology (KIST), Eunha-ri san 101, Bondong-eup, Wanju-gun, Jeolabuk-do 565-905 (Korea, Republic of)

2013-11-21T23:59:59.000Z

65

Determine Minimum Silver Flake Addition to GCM for Iodine Loaded AgZ  

SciTech Connect (OSTI)

The minimum amount of silver flake required to prevent loss of I{sub 2} during sintering in air for a SNL Glass Composite Material (GCM) Waste Form containing AgI-MOR (ORNL, 8.7 wt%) was determined to be 1.1 wt% Ag. The final GCM composition prior to sintering was 20 wt% AgI-MOR, 1.1 wt% Ag, and 80 wt% Bi-Si oxide glass. The amount of silver flake needed to suppress iodine loss was determined using thermo gravimetric analysis with mass spectroscopic off-gas analysis. These studies found that the ratio of silver to AgI-MOR required is lower in the presence of the glass than without it. Therefore an additional benefit of the GCM is that it serves to inhibit some iodine loss during processing. Alternatively, heating the AgI-MOR in inert atmosphere instead of air allowed for densified GCM formation without I{sub 2} loss, and no necessity for the addition of Ag. The cause of this behavior is found to be related to the oxidation of the metallic Ag to Ag{sup +} when heated to above ~300{degrees}C in air. Heating rate, iodine loading levels and atmosphere are the important variables that determine AgI migration and results suggest that AgI may be completely incorporated into the mordenite structure by the 550{degrees}C sintering temperature.

Terry J. Garino; Tina M. Nenoff; Mark A. Rodriguez

2014-04-01T23:59:59.000Z

66

Dissolved iodine in rainfall,cloud,stream and groundwater in the Plynlimon area of mid-Wales Hydrol. Earth Syst. Sci., 11(1), 283293, 2007  

E-Print Network [OSTI]

). Further, there are issues of radioactive iodine contamination from nuclear weapon testing, nuclear, much higher concentrations can occur in brines associated with oil fields where concentrations can

Paris-Sud XI, Université de

67

Iodine-129 and plutonium isotopes in Arctic kelp as historical indicators of transport of nuclear fuel-reprocessing wastes from mid-to-high latitudes in the Atlantic Ocean  

Science Journals Connector (OSTI)

...Iodine-129:iodine-127 ratios were determined using accelerator mass spectrometry in 34 Arctic marine algae collected between 1930 and 1993. A smaller set (5) of marine algae were also analyzed mass spectrometr...

L. W. Cooper; T. M. Beasley; X.-L. Zhao; C. Soto; K. L. Vinogradova

1998-06-01T23:59:59.000Z

68

LITERATURE SURVEY FOR GROUNDWATER TREATMENT OPTIONS FOR NITRATE IODINE-129 AND URANIUM 200-ZP-1 OPERABLE UNIT HANFORD SITE  

SciTech Connect (OSTI)

This literature review presents treatment options for nitrate, iodine-129, and uranium, which are present in groundwater at the 200-ZP-I Groundwater Operable Unit (OU) within the 200 West Area of the Hanford Site. The objective of this review is to determine available methods to treat or sequester these contaminants in place (i.e., in situ) or to pump-and-treat the groundwater aboveground (i.e., ex situ). This review has been conducted with emphasis on commercially available or field-tested technologies, but theoretical studies have, in some cases, been considered when no published field data exist. The initial scope of this literature review included only nitrate and iodine-I 29, but it was later expanded to include uranium. The focus of the literature review was weighted toward researching methods for treatment of nitrate and iodine-129 over uranium because of the relatively greater impact of those compounds identified at the 200-ZP-I OU.

BYRNES ME

2008-06-05T23:59:59.000Z

69

Sulfur Iodine Process Summary for the Hydrogen Technology Down-Selection: Process Performance Package  

SciTech Connect (OSTI)

This document describes the details of implementing a Sulfur-Iodine (S-I) hydrogen production plant to deploy with the Next General Nuclear Power Plant (NGNP). Technical requirements and specifications are included, and a conceptual plant design is presented. The following areas of interest are outlined in particular as a baseline for the various technology comparisons: (1) Performance Criteria - (a) Quantity of hydrogen produced, (b) Purity of hydrogen produced, (c) Flexibility to serve various applications, (d) Waste management; (2) Economic Considerations - (a) Cost of hydrogen, (b) Development costs; and (3) Risk - (a) Technical maturity of the S-I process, (b) Development risk, (c) Scale up options.

Benjamin Russ

2009-06-01T23:59:59.000Z

70

Use of iodine surface geochemical surveys in the Lodgepole and Minnelusa plays, U.S. northern Rockies  

SciTech Connect (OSTI)

The use of surface geochemistry is becoming more prevalent in oil exploration, especially for focusing specific target areas for 2D and 3D seismic surveys. Presented here are two surface geochemical surveys utilizing the iodine method in delineating Upper Minnelusa sands of Permian age in the Powder River basin and Lodgepole Waulsortian-like mounds of Mississippian age in the Williston basin. Iodine is an indirect indicator of a petroleum accumulation at depth. Increases in iodine anomalies are caused by the presence of petroleum seepage in the upper part of the soil section. In the very shallow surface, less than 10 ft, a reaction occurs between hydrocarbons and iodine under sunlight forming inorganic compounds. The source of the iodine is either from minerals in the soil and/or from the atmosphere with ultraviolet light as the initiator of the reaction. Any iodine in the subsurface could not migrate far in the presence of hydrocarbons and due to its large molecular size. The compounds that form in the soil remain solid and are relatively difficult to remove. Any surface geochemical anomaly needs to be followed by seismic in order to provide a specific drilling target. If a surface geochemical survey is properly designed and implemented, when no anomaly is present, then to date regardless of the type of method used the results have been dry holes. If a surface geochemical anomaly is present, the intensity, areal extent, and quality of the anomaly cannot determine the economic viability of the accumulation of depth, but there is a significant increase in the success rate. The best utilization of these methods is to determine areas where there is no possibility of finding petroleum and focusing on areas that do. In the case of the Lodgepole and Minnelusa plays, surface geochemistry allows a low cost approach and helps focus and minimize 2D and 3D survey costs.

Tedesco, S.A.; Bretz, S. [Atoka Geochemical Services Corp., Englewood, CO (United States)

1995-06-05T23:59:59.000Z

71

Generation of concentration density maxima of small dispersive coal dust particles in horizontal iodine air filter at air-dust aerosol blow  

E-Print Network [OSTI]

The spatial distributions of the small dispersive coal dust particles with the nano and micro sizes in the granular filtering medium with the cylindrical coal granules in the absorber in the horizontal iodine air filter during its long term operation at the nuclear power plant are researched. It is shown that the concentration density maxima of the small dispersive coal dust particles appear in the granular filtering medium with the cylindrical coal absorbent granules in the horizontal iodine air filter at an action by the air dust aerosol blow. The comparison of the measured aerodynamic resistances of the horizontal and vertical iodine air filters is conducted. The main conclusion is that the magnitude of the aerodynamic resistance of the horizontal iodine air filters is much smaller in comparison with the magnitude of the aerodynamic resistance of the vertical iodine air filters at the same loads of the air dust aerosol volumes. It is explained that the direction of the air dust aerosol blow and the direction of the gravitation force in the horizontal iodine air filter are orthogonal, hence the effective accumulation of the small dispersive coal dust particles takes place at the bottom of absorber in the horizontal iodine air filter. It is found that the air dust aerosol stream flow in the horizontal iodine air filter is not limited by the appearing structures, made of the precipitated small dispersive coal dust particles, in distinction from the vertical iodine air filter, in the process of long term operation of the iodine air filters at the nuclear power plant.

I. M. Neklyudov; O. P. Ledenyov; L. I. Fedorova; P. Ya. Poltinin

2013-06-11T23:59:59.000Z

72

Removal of mercury from solids using the potassium iodide/iodine leaching process  

SciTech Connect (OSTI)

Potassium iodide (KI) and iodine (I{sub 2}) leaching solutions have been evaluated for use in a process for removing mercury from contaminated mixed waste solids. Most of the experimental work was completed using surrogate waste. During the last quarter of fiscal year 1995, this process was evaluated using an actual mixed waste (storm sewer sediment from the Oak Ridge Y-12 Site). The mercury content of the storm sewer sediment was measured and determined to be approximately 35,000 mg/kg. A solution consisting of 0.2 M I{sub 2} and 0.4 M KI proved to be the most effective leachant used in the experiments when applied for 2 to 4 h at ambient temperature. Over 98% of the mercury was removed from the storm sewer sediment using this solution. Iodine recovery and recycle of the leaching agent were also accomplished successfully. Mathematical model was used to predict the amount of secondary waste in the process. Both surrogate waste and actual waste were used to study the fate of radionuclides (uranium) in the leaching process.

Klasson, K.T.; Koran, L.J. Jr.; Gates, D.D.; Cameron, P.A.

1997-12-01T23:59:59.000Z

73

Comparative EPMA and -XRF methods for mapping micro-scale distribution of iodine in biocarbonates of the CallovianOxfordian  

E-Print Network [OSTI]

in radioactive waste, iodine 129 I will make a significant contribution to potential overall long-term dose resulting from waste storage ( [Altmann, 2008] and [Grambow, 2008] ). 129 I has a complex chemistry of the Callovian­Oxfordian (160 Ma) clayey formation from the ANDRA (French Radioactive Waste Management Agency

Paris-Sud XI, Université de

74

UV-vis spectroscopy of iodine adsorbed on alkali-metal-modified zeolite catalysts for addition of carbon dioxide to ethylene oxide  

SciTech Connect (OSTI)

The basicity of alkali-metal-exchange (Na, K, Cs) zeolites X and Y was probed by UV-vis diffuse reflectance spectroscopy of adsorbed iodine. The observed blue shift in the visible absorption spectrum of adsorbed iodine, compared to gaseous iodine, correlated well with the negative charge on the framework oxygen atoms calculated from the Sanderson electronegativity equalization principle. The blue shifts associated with iodine adsorbed on classical catalytic supports like silica, alumina, and magnesia suggest that the iodine adsorption technique for probing basicity is applicable to a wide variety of solids. Iodine was also adsorbed on X and Y zeolites containing occluded cesium oxide formed by decomposition of impregnated cesium acetate. However, the iodine appeared to irreversibly react on these strongly basic samples, possibly forming an adsorbed triiodide ions. As a complement to the adsorption studies, the activity of alkali-metal-containing zeolites for the base-catalyzed formation of ethylene carbonate from ethylene oxide and carbon dioxide was investigated. Among the ion-exchanged zeolites, the cesium form of zeolite X exhibited the highest activity for ethylene carbonate formation. The catalytic activity of a zeolite containing occluded cesium was even higher than that of a cesium-exchanged zeolite. The presence of water adsorbed in zeolite pores promoted the rate of ethylene carbonate formation for both cesium-exchanged and cesium-impregnated zeolite X.

Doskocil, E.J.; Bordawekar, S.V.; Kaye, B.G.; Davis, R.J. [Univ. of Virginia, Charlottesville, VA (United States). Dept. of Chemical Engineering] [Univ. of Virginia, Charlottesville, VA (United States). Dept. of Chemical Engineering

1999-07-29T23:59:59.000Z

75

Stable n-CuInSe/sub 2/iodide-iodine photoelectrochemical cell  

DOE Patents [OSTI]

In a photoelectrochemical solar cell, stable output and solar efficiency in excess of 10% are achieved with a photoanode of n-CuInSe/sub 2/ electrode material and an iodine/iodide redox couple used in a liquid electrolyte. The photoanode is prepared by treating the electrode material by chemical etching, for example in Br/sub 2//MeOH; heating the etched electrode material in air or oxygen; depositing a surface film coating of indium on the electrode material after the initial heating; and thereafter again heating the electrode material in air or oxygen to oxidize the indium. The electrolyte is treated by the addition of Cu/sup +/ or Cu/sup 2 +/ salts and in In/sup 3 +/ salts.

Cahen, D.; Chen, Y.W.

1984-09-20T23:59:59.000Z

76

Test bed for a high throughput supersonic chemical oxygen - iodine laser  

SciTech Connect (OSTI)

The paper reports the development of a test bed for a chemical oxygen - iodine laser based on a high throughput jet flow singlet oxygen generator (JSOG). The system provides vertical singlet oxygen extraction followed by horizontal orientation of subsequent subsystems. This design enables the study of flow complexities and engineering aspects of a distributed weight system as an input for mobile and other platform-mounted systems developed for large scale power levels. The system under consideration is modular and consists of twin SOGs, plenum and supersonic nozzle modules, with the active medium produced in the laser cavity. The maximal chlorine flow rate for the laser is {approx}1.5 mole s{sup -1} achieving a typical chemical efficiency of about 18%. (lasers)

Singhal, Gaurav; Mainuddin; Rajesh, R; Varshney, A K; Dohare, R K; Kumar, Sanjeev; Singh, V K; Kumar, Ashwani; Verma, Avinash C; Arora, B S; Chaturvedi, M K; Tyagi, R K; Dawar, A L

2011-05-31T23:59:59.000Z

77

The generation of singlet Delta oxygen - A technology overview. [For use in chemical oxygen iodine lasers  

SciTech Connect (OSTI)

The rate of generation of O2(1Delta g) using the chlorine-basic-hydrogen-peroxide reaction is a key element to predict the performance of the chemical oxygen iodine laser. O2(1Delta g) carries the energy in the laser, and thus is one of the prime determinants of power in the flow. To predict the performance of O2(1Delta g) generators requires the prediction of the utilization of chlorine, the yield of excited oxygen, and the concentration of potential contaminants in the chemical exhaust of the generator. This paper describes an approach to the analysis of O2(1Delta g) generators. 6 refs.

Mcdermott, W.E. (Rockwell International Corp., Rocketdyne Div., Canoga Park, CA (United States))

1992-07-01T23:59:59.000Z

78

Diffusion of Iodine and Rhenium in Category 3 Waste Encasement Concrete and Soil Fill Material  

SciTech Connect (OSTI)

Assessing long-term performance of Category 3 waste cement grouts for radionuclide encasement requires knowledge of the radionuclide-cement interactions and mechanisms of retention (i.e. sorption or precipitation). This understanding will enable accurate prediction of radionuclide fate when the waste forms come in contact with groundwater. A set of diffusion experiments using carbonated and non-carbonated concrete-soil half cells was conducted under unsaturated conditions (4% and 7% by wt moisture content). Spiked concrete half-cell specimens were prepared with and without colloidal metallic iron addition and were carbonated using supercritical carbon dioxide. Spikes of I and Re were added to achieve measurable diffusion profile in the soil part of the half-cell. In addition, properties of concrete materials likely to influence radionuclide migration such as carbonation were evaluated in an effort to correlate these properties with the release of iodine and rhenium.

Wellman, Dawn M.; Mattigod, Shas V.; Whyatt, Greg A.; Powers, Laura; Parker, Kent E.; Wood, Marcus I.

2006-12-15T23:59:59.000Z

79

Iodine Treatment of LigninCellulose Acetate Electrospun Fibers: Enhancement of Green Fiber Carbonization  

Science Journals Connector (OSTI)

Iodine Treatment of LigninCellulose Acetate Electrospun Fibers: Enhancement of Green Fiber Carbonization ... The chemical composition of the samples were analyzed using an Oxford Instruments X-Max20 energy dispersive X-ray spectrometer (EDS), Thermo Scientific Nicolet 6700 Fourier transform infrared (FTIR) spectrometer with a GladiATR single reflection ATR accessory (operated between 400 and 4000 cm1 with a 4 cm1 resolution averaged over 40 scans), and Renishaw Raman spectrometer operated using a 785 nm near-infrared laser (11001900 cm1 with a 0.8 cm1 resolution averaged over 3 scans). ... This work presents a systematic study of the ratio between the integrated intensities of the disorder-induced D and G Raman bands (ID/IG) in nanographite samples with different crystallite sizes (La) and using different excitation laser energies. ...

Makoto Schreiber; Singaravelu Vivekanandhan; Amar Kumar Mohanty; Manjusri Misra

2014-11-06T23:59:59.000Z

80

Stable N-CuInSe.sub.2 /iodide-iodine photoelectrochemical cell  

DOE Patents [OSTI]

In a photoelectrochemical solar cell, stable output and solar efficiency in excess of 10% are achieved with a photoanode of n-CuInSe.sub.2 electrode material and an iodine/iodide redox couple used in a liquid electrolyte. The photoanode is prepared by treating the electrode material by chemical etching, for example in Br.sub.2 /MeOH; heating the etched electrode material in air or oxygen; depositing a surface film coating of indium on the electrode material after the initial heating; and thereafter again heating the electrode material in air or oxygen to oxidize the indium. The electrolyte is treated by the addition of Cu.sup.+ or Cu.sup.2+ salts and In.sup.3+ salts.

Cahen, David (Rehovot, IL); Chen, Yih W. (Lakewood, CO)

1985-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "iodine phos phorus" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


81

Two-dimensional real-time imaging system for subtraction angiography using an iodine filter  

SciTech Connect (OSTI)

A new type of subtraction imaging system was developed using an iodine filter and a single-energy broad bandwidth monochromatized x ray. The x-ray images of coronary arteries made after intravenous injection of a contrast agent are enhanced by an energy-subtraction technique. Filter chopping of the x-ray beam switches energies rapidly, so that a nearly simultaneous pair of filtered and nonfiltered images can be made. By using a high-speed video camera, a pair of two 512 {times} 512 pixel images can be obtained within 9 ms. Three hundred eighty-four images (raw data) are stored in a 144-Mbyte frame memory. After phantom studies, {ital in} {ital vivo} subtracted images of coronary arteries in dogs were obtained at a rate of 15 images/s.

Umetani, K.; Ueda, K. (Central Research Laboratory, Hitachi, Ltd., Kokubunji, Tokyo 185 (Japan)); Takeda, T.; Anno, I.; Itai, Y. (Institute of Clinical Medicine, University of Tsukuba, Ibaraki 305 (Japan)); Akisada, M.; Nakajima, T. (Tama Health Management Center, Tachikawa, Tokyo 190 (Japan))

1992-01-01T23:59:59.000Z

82

Can we remove iodine-131 from tap water in Japan by boiling? Experimental testing in response to the Fukushima Daiichi Nuclear Power Plant accident  

Science Journals Connector (OSTI)

Iodine-131 concentrations in tap water higher than 100BqL?1 were reported by several local governments in Japan following the Fukushima Daiichi Nuclear Power Plant accident. Some individuals in the emergency-response community recommended the boiling of tap water to remove iodine-131. However, the tap water boiling tests in this study showed no iodine-131 loss from the tap water with either short-term boiling (110min) or prolonged boiling (up to 30min) resulting in up to 3-fold volume reductions. In this situation, boiling was shown to be not effective in removing iodine-131 from tap water; indeed even higher concentrations may result from the liquid-volume reduction accompanying this process.

K. Tagami; S. Uchida

2011-01-01T23:59:59.000Z

83

Influence by small dispersive coal dust particles of different fractional consistence on characteristics of iodine air filter at nuclear power plant  

E-Print Network [OSTI]

The main purpose of research is to determine the influence by the small dispersive coal dust particles of the different fractional consistence on the technical characteristics of the vertical iodine air filter at nuclear power plant. The research on the transport properties of the small dispersive coal dust particles in the granular filtering medium of absorber in the vertical iodine air filter is completed in the case, when the modeled aerodynamic conditions are similar to the real aerodynamic conditions. It is shown that the appearance of the different fractional consistence of small dispersive coal dust particles with the decreasing dimensions down to the micro and nano sizes at the action of the air dust aerosol stream normally results in a significant change of distribution of the small dispersive coal dust particles masses in the granular filtering medium of an absorber in the vertical iodine air filter, changing the vertical iodine air filter aerodynamic characteristics. The precise characterization of...

Neklyudov, I M; Fedorova, L I; Poltinin, P Ya

2013-01-01T23:59:59.000Z

84

Influence by small dispersive coal dust particles of different fractional consistence on characteristics of iodine air filter at nuclear power plant  

E-Print Network [OSTI]

The main purpose of research is to determine the influence by the small dispersive coal dust particles of the different fractional consistence on the technical characteristics of the vertical iodine air filter at nuclear power plant. The research on the transport properties of the small dispersive coal dust particles in the granular filtering medium of absorber in the vertical iodine air filter is completed in the case, when the modeled aerodynamic conditions are similar to the real aerodynamic conditions. It is shown that the appearance of the different fractional consistence of small dispersive coal dust particles with the decreasing dimensions down to the micro and nano sizes at the action of the air dust aerosol stream normally results in a significant change of distribution of the small dispersive coal dust particles masses in the granular filtering medium of an absorber in the vertical iodine air filter, changing the vertical iodine air filter aerodynamic characteristics. The precise characterization of the aerodynamic resistance of a model of the vertical iodine air filter is completed. The comparative analysis of the technical characteristics of the vertical and horizontal iodine air filters is also made.

I. M. Neklyudov; O. P. Ledenyov; L. I. Fedorova; P. Ya. Poltinin

2013-02-18T23:59:59.000Z

85

Ion-ion neutralization of iodine in radio-frequency inductive discharges of Xe and I2 mixtures  

E-Print Network [OSTI]

. There is a considerable body of research investigating rare gas- halogen kinetics in the context of atmospheric pressure. The plasma is sustained in an 3.8 cm i.d. by 7.6-cm- long quartz tube. The excitation coil is a solenoid, and having eight and three-quarters turns. Variable rf power is supplied to the sys- tem at 11.3 MHz. Iodine

Kushner, Mark

86

Distributions of selenium, iodine, lead, thorium and uranium in Japanese river waters  

SciTech Connect (OSTI)

Long-lived radionuclides released from nuclear facilities, such as deep underground disposal facilities, could reach humans through several transfer paths in the environment. Uses of ground water and river water for agricultural field irrigation and for drinking water are important paths. In order to understand behavior of long-lived radionuclides in the terrestrial water environment, we carried out a natural analogue study, that is, measurement of selenium (Se), iodine (I), lead (Pb), thorium (Th) and uranium (U) concentrations in 45 Japanese rivers at 10 sampling points from the upper stream to the river mouth for each river. Geometric mean concentrations for Se, I, Pb, Th and U were 0.057, 1.4, 0.039, 0.0055, 0.0109 ng/mL, respectively. Distribution patterns from upper stream to river mouth were different by elements, for instance, the concentrations of I, Th and U increased when the sampling points were nearer the river mouth, while that of Se were almost constant. For Pb, the highest value was observed in the middle part of each river in many cases. (authors)

Tagami, K.; Uchida, S. [National Institute of Radiological Sciences, Chiba (Japan)

2007-07-01T23:59:59.000Z

87

Optical saturation and extraction from the chemical oxygen-iodine laser medium  

SciTech Connect (OSTI)

A rate equation model for the loaded gain of a flowing chemical oxygen-iodine laser is described. The solution of the model is obtained for the loaded gain when the medium is stimulated by a multimode field. It is shown that optical saturation of the COIL medium is governed by three parameters: the ratio of the collision to Doppler linewidth measuring how much of the total linewidth is accessed; a saturation parameter measuring the field strength required to overcome medium quenching; and a cross-relaxation parameter measuring the ability of the velocity and hyper-fine relaxation to restore homogeneity to the transition. Criteria for the saturation character, homogeneous, inhomogeneous, or mixed, are established. This gain model is used to parametrically examine the sensitivity of the loaded gain and optical extraction efficiency to cavity pressure and to the uncertainty in the magnitude of the velocity cross-relaxation rates. It is shown, under single-mode operating conditions, that the extraction efficiency increases as the rate of velocity cross-relaxation increases and that the saturation behavior of the medium can be totally changed by only modes changes in the cavity operating conditions. The implication when interpreting experimental data and scaling from low to high power operation are briefly discussed and it is shown that interpreting test data without consideration of the factors presented here can lead to substantial error in estimating the power available from the flow.

Copeland, D.A.; Bauer, A.H. (Rockwell International Corp., Canoga Park, CA (United States). Rocketdyne Div.)

1993-09-01T23:59:59.000Z

88

Abatement of Xenon and Iodine Emissions from Medical Isotope Production Facilities  

SciTech Connect (OSTI)

The capability of the International Monitoring System (IMS) to detect xenon from underground nuclear explosions is dependent on the radioactive xenon background. Adding to the background, medical isotope production (MIP) by fission releases several important xenon isotopes including xenon-133 and iodine-133 that decays to xenon-133. The amount of xenon released from these facilities may be equivalent to or exceed that released from an underground nuclear explosion. Thus the release of gaseous fission products within days of irradiation makes it difficult to distinguish MIP emissions from a nuclear explosion. In addition, recent shortages in molybdenum-99 have created interest and investment opportunities to design and build new MIP facilities in the United States and throughout the world. Due to the potential increase in the number of MIP facilities, a discussion of abatement technologies provides insight into how the problem of emission control from MIP facilities can be tackled. A review of practices is provided to delineate methods useful for abatement of medical isotopes.

Doll, Charles G. [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Sorensen, Christina M. [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Bowyer, Ted W. [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Friese, Judah I. [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Hayes, James C. [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States); Hoffman, Emma L. [Australian Nuclear Science and Technology Organisation, Menai (Australia); Kephart, Rosara F. [Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)

2014-04-01T23:59:59.000Z

89

The mechanical properties of Zircaloy-2 after exposure to iodine-methanol solutions  

Science Journals Connector (OSTI)

An investigation is described into the changes in mechanical properties of Zircaloy-2 after corrosion in boiling iodinemethanol solutions. As-received specimens, 0.7 mm thick, corroded rapidly in the boiling solution (0.25 g of iodine/litre of methanol); for preoxidised specimens the presence of an intact oxide film inhibited corrosive attack in direct proportion to the oxide thickness. Preoxidised specimens showed reduced corrosion resistance after prestraining 2.0 0.25% before corrosion. Tensile tests at room temperature indicated that when the corrosion weight loss exceeded 7 mg/dm2, the strength and uniform ductility became adversely effected. Such changes were associated with extensive intergranular attack in as-received specimens or with localized intergranular attack below cracks in the oxide in preoxidised specimens. The final failure was always by a transgranular ductile tearing process. Thus above 7 mg/dm2 weight loss, corresponding to a maximum of 70 ?m intergranular penetration, the fall in strength was due to the loss of load-bearing section in this specimen geometry and section thickness.

R.D. Nicholson

1980-01-01T23:59:59.000Z

90

Development of a Novel Iodine-Vitamin C/Vanadium Redox Flow Battery  

Science Journals Connector (OSTI)

Abstract A novel (I+/I2)/vitamin C vs. V4+/V5+ semi-vanadium redox flow battery (semi-VRFB) with iodine, vitamin C, and V4+/V5+ redox couples, using multiple electrodes was investigated. The electrodes, Ni-P/carbon paper and Ni-P/TiO2/carbon paper, were modified by the electroless plating method and sol-gel process. The electrochemical characteristics and the performance of the semi-VRFB were verified by the cyclic voltammetry method and a charge-discharge test. This study shows modified electrodes can improve the reversibility and symmetry of the oxidation-reduction reaction of the semi-VRFB system, and effectively raise its storage ability. The coulomb efficiency of the semi-VRFB system is close to 96%, which is higher than the all-VRFB. The semi-VRFB system can reduce the amount of vanadium salt, therefore, it is not only a reduction in cost, but also has a great potential for the development of energy storage systems.

Mei-Ling Chen; Shu-Ling Huang; Chin-Lung Hsieh; Jan- Yen Lee; Tz-Jiun Tsai

2014-01-01T23:59:59.000Z

91

LABORATORY REPORT ON IODINE ({sup 129}I AND {sup 127}I) SPECIATION, TRANSFORMATION AND MOBILITY IN HANFORD GROUNDWATER, SUSPENDED PARTICLES AND SEDIMENTS  

SciTech Connect (OSTI)

The Hanford Site in eastern Washington produced plutonium for several decades and in the process generated billions of gallons of radioactive waste. Included in this complex mixture of waste was 50 Ci of iodine-129 ({sup 129}I). Iodine-129s high abundance, due to its high fission yield, and extreme toxicity result in iodine-129 becoming a key risk driver at many Department of Energy (DOE) sites. The mobility of radioiodine in arid environments, such as the Hanford Site, depends largely on its chemical speciation and is also greatly affected by many other environmental factors, especially natural sediment organic matter (SOM). Groundwater radioiodine speciation has not been measured in arid regions with major plumes or large disposed {sup 129}I inventories, including the Hanford Site, Idaho National Laboratory, and Nevada Test Site. In this study, stable iodine-127 and radioiodine-129 speciation, pH, and dissolved organic carbon (DOC) of groundwater samples collected from seven wells located in the 200-West Area of the Hanford site were investigated. The most striking finding was that iodate (IO{sub 3}{sup -}) was the most abundant species. Unexpectedly, iodide (I{sup -}), which was likely the form of iodine in the source materials and the expected dominant groundwater species based on thermodynamic considerations, only accounted for 1-2% of the total iodine concentration. It is likely that the relatively high pH and the low abundance of sedimentary organic matter (SOM) that is present at the site slowed down or even inhibited the reduction of iodate, as SOM abiotically reduce iodate into iodide. Moreover, a study on the kinetics of iodide and iodate uptake and aqueous speciation transformation by three representative subsurface Hanford sediments was performed over a period of about one month. This study was carried out by using iodide-125 or iodate-125 at the ambient iodine-127concentration found at the site. Iodate K{sub d} values were on average 89% greater than iodide K{sub d} values, and the K{sub d} values for both species tended to increase with the amount of organic carbon (OC) present in the sediment. It is especially noteworthy that this trend existed at the very low OC concentrations that naturally exist in the Hanford sediments. Iodine and OC can form essentially irreversible covalent bonds, thereby providing a yet unstudied {sup 129}I retardation reaction at the Hanford Site. In addition to the transformation of iodine species, the sediment collected from the vadose zone also released stable iodide into the aqueous phase. It was found that the three sediments all took up the ambient iodate from the groundwater and slowly transformed it into iodide under the laboratory conditions, likely dependent on the abundance of reducing agents such as organic matter and Fe{sup 2+}. Therefore two competitive iodine processes were identified, the tendency for the sediment to reduce iodate to iodide, and the groundwater chemistry to maintain the iodine as iodate, presumably it is largely the result of natural pH and dissolved O{sub 2}/Eh levels. Suspended carbonate (and silica) particles collected from Hanford groundwater contained elevated amounts of iodine (142 8 ?g/g iodine), consisting mainly of iodate (>99%). Iodate was likely incorporated into the carbonate structure during calcite precipitation upon degasing of CO{sub 2} as the groundwater samples were removed from the subsurface. This concentration of groundwater iodate in precipitated carbonate has implication to long-term fate and transport of 129I and on active in-situ {sup 129}I groundwater remediation. This study provides some of the first groundwater radioiodine speciation studies conducted in arid environments and provides much needed mechanistic descriptions to permit making informed decisions about low-cost/high intellectual input remediation options, such as monitored natural attenuation, or long-term stewardship of nuclear waste disposal sites.

Kaplan, D.; Santschi, P.; Xu, C.; Zhang, S.; Ho, Y.; Li, H.; Schwehr, K.

2012-09-30T23:59:59.000Z

92

Generation of concentration density maxima of small dispersive coal dust particles in horizontal iodine air filter at air-dust aerosol blow  

E-Print Network [OSTI]

The spatial distributions of the small dispersive coal dust particles with the nano and micro sizes in the granular filtering medium with the cylindrical coal granules in the absorber in the horizontal iodine air filter during its long term operation at the nuclear power plant are researched. It is shown that the concentration density maxima of the small dispersive coal dust particles appear in the granular filtering medium with the cylindrical coal absorbent granules in the horizontal iodine air filter at an action by the air dust aerosol blow. The comparison of the measured aerodynamic resistances of the horizontal and vertical iodine air filters is conducted. The main conclusion is that the magnitude of the aerodynamic resistance of the horizontal iodine air filters is much smaller in comparison with the magnitude of the aerodynamic resistance of the vertical iodine air filters at the same loads of the air dust aerosol volumes. It is explained that the direction of the air dust aerosol blow and the directi...

Neklyudov, I M; Fedorova, L I; Poltinin, P Ya

2013-01-01T23:59:59.000Z

93

Separation, Concentration, and Immobilization of Technetium and Iodine from Alkaline Supernate Waste  

SciTech Connect (OSTI)

Development of remediation technologies for the characterization, retrieval, treatment, concentration, and final disposal of radioactive and chemical tank waste stored within the Department of Energy (DOE) complex represents an enormous scientific and technological challenge. A combined total of over 90 million gallons of high-level waste (HLW) and low-level waste (LLW) are stored in 335 underground storage tanks at four different DOE sites. Roughly 98% of this waste is highly alkaline in nature and contains high concentrations of nitrate and nitrite salts along with lesser concentrations of other salts. The primary waste forms are sludge, saltcake, and liquid supernatant with the bulk of the radioactivity contained in the sludge, making it the largest source of HLW. The saltcake (liquid waste with most of the water removed) and liquid supernatant consist mainly of sodium nitrate and sodium hydroxide salts. The main radioactive constituent in the alkaline supernatant is cesium-137, but strontium-90, technetium-99, and transuranic nuclides are also present in varying concentrations. Reduction of the radioactivity below Nuclear Regulatory Commission (NRC) limits would allow the bulk of the waste to be disposed of as LLW. Because of the long half-life of technetium-99 (2.1 x 10 5 y) and the mobility of the pertechnetate ion (TcO 4 - ) in the environment, it is expected that technetium will have to be removed from the Hanford wastes prior to disposal as LLW. Also, for some of the wastes, some level of technetium removal will be required to meet LLW criteria for radioactive content. Therefore, DOE has identified a need to develop technologies for the separation and concentration of technetium-99 from LLW streams. Eichrom has responded to this DOE-identified need by demonstrating a complete flowsheet for the separation, concentration, and immobilization of technetium (and iodine) from alkaline supernatant waste.

James Harvey; Michael Gula

1998-12-07T23:59:59.000Z

94

High pressure sulfuric acid decomposition experiments for the sulfur-iodine thermochemical cycle.  

SciTech Connect (OSTI)

A series of three pressurized sulfuric acid decomposition tests were performed to (1) obtain data on the fraction of sulfuric acid catalytically converted to sulfur dioxide, oxygen, and water as a function of temperature and pressure, (2) demonstrate real-time measurements of acid conversion for use as process control, (3) obtain multiple measurements of conversion as a function of temperature within a single experiment, and (4) assess rapid quenching to minimize corrosion of metallic components by undecomposed acid. All four of these objectives were successfully accomplished. This report documents the completion of the NHI milestone on high pressure H{sub 2}SO{sub 4} decomposition tests for the Sulfur-Iodine (SI) thermochemical cycle project. All heated sections of the apparatus, (i.e. the boiler, decomposer, and condenser) were fabricated from Hastelloy C276. A ceramic acid injection tube and a ceramic-sheathed thermocouple were used to minimize corrosion of hot liquid acid on the boiler surfaces. Negligible fracturing of the platinum on zirconia catalyst was observed in the high temperature decomposer. Temperature measurements at the exit of the decomposer and at the entry of the condenser indicated that the hot acid vapors were rapidly quenched from about 400 C to less than 20 C within a 14 cm length of the flow path. Real-time gas flow rate measurements of the decomposition products provided a direct measurement of acid conversion. Pressure in the apparatus was preset by a pressure-relief valve that worked well at controlling the system pressure. However, these valves sometimes underwent abrupt transitions that resulted in rapidly varying gas flow rates with concomitant variations in the acid conversion fraction.

Velasquez, Carlos E; Reay, Andrew R.; Andazola, James C.; Naranjo, Gerald E.; Gelbard, Fred

2005-09-01T23:59:59.000Z

95

Test Plan to Demonstrate Removal of Iodine and Tritium from Simulated Nuclear Fuel Recycle Plant Off-gas Streams using Adsorption Processes  

SciTech Connect (OSTI)

This letter documents the completion of the FCR&D Level 4 milestone for the Sigma Team Off-Gas - ORNL work package (FT-14OR031202), Co-absorption studies - Design system complete/test plan complete (M4FT-14OR0312022), due November 15, 2013. The objective of this test plan is to describe research that will determine the effectiveness of silver mordenite and molecular sieve beds to remove iodine and water (tritium) from off-gas streams arising from used nuclear fuel recycling processes, and to demonstrate that the iodine and water can be recovered separately from one another.

Bruffey, Stephanie H. [ORNL] [ORNL; Spencer, Barry B. [ORNL] [ORNL; Jubin, Robert Thomas [ORNL] [ORNL

2013-12-11T23:59:59.000Z

96

Fracture-mechanics analysis of iodine stress-corrosion crack propagation in zircaloy tubing used to clad oxide-pellet fuel rods. LWBR Development Program  

SciTech Connect (OSTI)

A fracture mechanics model is presented for analysis of iodine induced stress corrosion crack growth in Zircaloy tubing. The model utilizes a power law to relate crack velocity to stress intensity factor, a hyperbolic tangent function for the influence of iodine concentration, and an exponential function for the influence of temperature and material strength. Comparisons of predicted to measured failure times show that predicted failure times are within a factor of two of the measured failure times for a majority of the specimens considered.

Crescimanno, P.J.; Campbell, W.R.; Goldberg, I.

1983-04-01T23:59:59.000Z

97

Anion retention in soil: Possible application to reduce migration of buried technetium and iodine  

SciTech Connect (OSTI)

This report summarizes a literature review of our present knowledge of the anion exchange properties of a number of soils and minerals, which may potentially be used as anion exchangers to retard migration of such anions as iodide (I{sup {minus}}), iodate (IO{sub 3}{sup {minus}}) and pertechnetate (TcO{sub 4}{sup {minus}}) away from disposal site. The amorphous clays allophane and imogolite, are found to be among the most important soil components capable of developing appreciable amounts of positive charge for anion exchange even at about neutral pH. Decreases in the SiO{sub 2}/Al{sub 2}O{sub 3} ratio and soil pH result in an increase in soil AEC. Allophane and imogolite rich soils have an AEC ranging from 1 to 18 meq/100g at pH about 6. Highly weathered soils dominated by Fe and Al oxides and kaolinite may develop a significant amount of AEC as soil pH falls. The retention of iodine (I) and technetium ({Tc}), by soils is associated with both soil organic matter, and Fe and Al oxides, whereas sorption on layer silicate minerals in negligible. Fe and Al oxides become more important in the retention of anionic I{sup {minus}}, IO{sub 3}{sup {minus}}, and TcO{sub 4}{sup {minus}} as pH falls, since more positive charge is developed on the oxide surfaces. Although few studies, if any, have been conducted on I and {Tc} sorption by soil allophane and imogolite, it is estimated that a surface plough soil (2 million pounds soil per acre) with 5 meq/100g AEC, as is commonly found in andisols, shall retain approximately 5900 kg I and 4500 kg {Tc}. It is conceivable that an anion exchanger such as an andisol could be used to modify the near field environment of a radioactive waste disposal facility. This whole disposal system would then offer similar migration resistance to anions as is normally afforded to cations by usual and normal soils. 93 refs., 10 figs., 7 tabs.

Gu, B.; Schulz, R.K. (California Univ., Berkeley, CA (United States). Dept. of Soil Science)

1991-10-01T23:59:59.000Z

98

Fission gas and iodine release measured up to 15 GWd/t UO/sub 2/ burnup  

SciTech Connect (OSTI)

A summary is presented of the measured release of xenon, krypton and iodine up to 15 GWd/t UO/sub 2/ burnup for fuel centerline temperatures ranging from 950 to 1800 K, at average linear heat ratings of 15 to 35 kW/m. The IFA-430 is composed of four 1.28-m-long fuel rods containing 10% enriched UO/sub 2/ pellet fuel. Two of the fuel rods are connected, top and bottom, to a gas flow system that permits the fission gases released from the fuel pellets to be swept out of the rods during irradiation and measured via gamma spectrometry. The release/burnup increased significantly between 10 and 15 GWd/t burnup. Fuel temperature did not change. Increased releases were due to physical changes in the fuel-surface area. Changes appeared to be due to higher power operation and burnup.

Appelhans, A.D.

1983-01-01T23:59:59.000Z

99

The effects of texture and surface condition on the iodine stress corrosion cracking susceptibility of unirradiated Zircaloy-2  

SciTech Connect (OSTI)

Four lots of stress-relieved Zircaloy-2 tubing were prepared from a single heat of the alloy. Tube reduction parameters were controlled so that each lot had a different crystallographic texture. The tubing with the most radial (least tangential) basal pole intensity was shown to have a Kearns texture number in the radial direction of 0.61, whereas the equivalent value for the tubing with the least radial texture was 0.48. Each lot of tubing was given one of three surface treatments: etched, etched and grit blasted, or lightly etched and shot blasted. The iodine stress corrosion cracking (SCC) susceptibility of the unirradiated tubing was determined by measuring the time to failure in a standard tube pressurization test at about 593 K in which 6 mg of iodine was present for each square centimetre of exposed Zircaloy surface. The results showed that texture has a large effect on SCC susceptibility and that surface condition has a significant but lesser effect. The SCC resistance was lowest in the material with the most tangential basal pole intensity and increased as the texture became more radial. The lightly etched and shot-blasted surface resulted in times to failure that were shorter than the times for the other two surface conditions. However, it seems likely that the influence of surface treatment is quite complex and that SCC susceptibility can change significantly with a seemingly minor change in the surface treatment technique. The effect of texture was interpreted in terms of its influence on strength, on deformation characteristics, and on orientation of SCC susceptible planes with respect to the dominant tensile (hoop) stress. The effect of surface condition was interpreted in terms of its influence on residual stresses, on local texture changes, on local stress concentration, and on chemical activity.

Syrett, B.C.; Cubicciotti, D.; Jones, R.L.

1981-12-01T23:59:59.000Z

100

Iodine-stress corrosion cracking of Zircaloy-2 cladding under near plane strain and localized stress-strain conditions  

SciTech Connect (OSTI)

The segmented expanding mandrel test (SEMT) method is generally regarded as a good laboratory simulator of pellet-cladding interactions (PCI) in LWR fuel rods. Yet it does not reproduce the low strain failures in Zircaloy cladding typical of PCI-failed fuel elements and commonly observed in other types of laboratory specimens. This investigation addressed this apparent inconsistency. Iodine-stress corrosion cracking (I-SCC) of cold worked, unirradiated Zircaloy-2 cladding was induced in three different types of tubing specimens (known as regular, thin-wall, and chamfered) in a modified SEMT apparatus designed to test mechanical conditions that could lead to slow strain failures. Only the chamfered sample, which has been shown to be subjected to more nearly plane strain conditions than either of the other two specimen types, failed consistently at low (0.8%) total diametral strains in good agreement with in-reactor failure data. Such conditions were numerically and experimentally quantified by means of finite element calculational models and local strain measurements. The numerical analyses and strain measurements provide valuable insight into the PCI simulating power of the segmented expanding mandrel test and its experimental limitations. Failure-strain results for chamfered barrier claddings were obtained and compared with available literature data. The improved I-SCC resistance of this type of cladding was confirmed but the failure strains were significantly lower than reported for regular barrier tubes.

Nobrega, B.N.

1984-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "iodine phos phorus" from the National Library of EnergyBeta (NLEBeta).
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We encourage you to perform a real-time search of NLEBeta
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101

The application of iodine and magnetic susceptibility surface geochemical surveys in the Lodgepole Play, Eastern Williston Basin, North Dakota  

SciTech Connect (OSTI)

The use of surface geochemistry as a first pass exploration tool is becoming more prevalent in petroleum exploration. This is especially true due to the high cost of 2-D and 3-D surveys in defining small targets such as the Waulsortian mounds of the Lodgepole Formation. Surface geochemical surveys are very effective in pinpointing specific target areas for seismic surveying and thus reducing costs. Presented are examples of surface geochemical surveys utilizing magnetic susceptibility and iodine methods in delineating reservoirs in the Lodgepole, Mission Canyon and Red River formations. The types of surveys presented vary from reconnaissance to detail and examples of how to define a grid will be discussed. Surface geochemical surveys can be very effective when the areal extent of the target(s) and the purpose of the survey are clearly defined prior to implementation. By determining which areas have microseepage and which areas do not, surface geochemistry can be a very effective tool in focusing exploration efforts and maximizing exploration dollars.

Tedesco, S.A. [Atoka Geochemical Services Corp., Englewood, CO (United States)

1996-06-01T23:59:59.000Z

102

Dosimetric and Late Radiation Toxicity Comparison Between Iodine-125 Brachytherapy and Stereotactic Radiation Therapy for Juxtapapillary Choroidal Melanoma  

SciTech Connect (OSTI)

Purpose: To compare the dose distributions and late radiation toxicities for {sup 125}I brachytherapy (IBT) and stereotactic radiation therapy (SRT) in the treatment of juxtapapillary choroidal melanoma. Methods: Ninety-four consecutive patients with juxtapapillary melanoma were reviewed: 30 have been treated with IBT and 64 with SRT. Iodine-125 brachytherapy cases were modeled with plaque simulator software for dosimetric analysis. The SRT dosimetric data were obtained from the Radionics XKnife RT3 software. Mean doses at predetermined intraocular points were calculated. Kaplan-Meier estimates determined the actuarial rates of late toxicities, and the logrank test compared the estimates. Results: The median follow-up was 46 months in both cohorts. The 2 cohorts were balanced with respect to pretreatment clinical and tumor characteristics. Comparisons of radiation toxicity rates between the IBT and SRT cohorts yielded actuarial rates at 50 months for cataracts of 62% and 75% (P=.1), for neovascular glaucoma 8% and 47% (P=.002), for radiation retinopathy 59% and 89% (P=.0001), and for radiation papillopathy 39% and 74% (P=.003), respectively. Dosimetric comparisons between the IBT and SRT cohorts yielded mean doses of 12.8 and 14.1 Gy (P=.56) for the lens center, 17.6 and 19.7 Gy (P=.44) for the lens posterior pole, 13.9 and 10.8 Gy (P=.30) for the ciliary body, 61.9 and 69.7 Gy (P=.03) for optic disc center, and 48.9 and 60.1 Gy (P<.0001) for retina at 5-mm distance from tumor margin, respectively. Conclusions: Late radiation-induced toxicities were greater with SRT, which is secondary to the high-dose exposure inherent to the technique as compared with IBT. When technically feasible, IBT is preferred to treat juxtapapillary choroidal melanoma.

Krema, Hatem, E-mail: htmkrm19@yahoo.com [Department of Ocular Oncology, Princess Margaret Hospital/University Health Network, University of Toronto, Toronto, Ontario (Canada)] [Department of Ocular Oncology, Princess Margaret Hospital/University Health Network, University of Toronto, Toronto, Ontario (Canada); Heydarian, Mostafa [Department of Radiation Medicine, Princess Margaret Hospital/University Health Network, University of Toronto, Toronto, Ontario (Canada)] [Department of Radiation Medicine, Princess Margaret Hospital/University Health Network, University of Toronto, Toronto, Ontario (Canada); Beiki-Ardakani, Akbar [Department of Radiation Oncology, Princess Margaret Hospital/University Health Network, University of Toronto, Toronto, Ontario (Canada)] [Department of Radiation Oncology, Princess Margaret Hospital/University Health Network, University of Toronto, Toronto, Ontario (Canada); Weisbrod, Daniel [Department of Ocular Oncology, Princess Margaret Hospital/University Health Network, University of Toronto, Toronto, Ontario (Canada)] [Department of Ocular Oncology, Princess Margaret Hospital/University Health Network, University of Toronto, Toronto, Ontario (Canada); Xu, Wei [Department of Biostatistics, Princess Margaret Hospital/University Health Network, University of Toronto, Toronto, Ontario (Canada)] [Department of Biostatistics, Princess Margaret Hospital/University Health Network, University of Toronto, Toronto, Ontario (Canada); Laperriere, Normand J.; Sahgal, Arjun [Department of Radiation Oncology, Princess Margaret Hospital/University Health Network, University of Toronto, Toronto, Ontario (Canada)] [Department of Radiation Oncology, Princess Margaret Hospital/University Health Network, University of Toronto, Toronto, Ontario (Canada)

2013-07-01T23:59:59.000Z

103

Reaction with Propane of I(52P1/2), produced by Photolysis of Iodine in the Continuum of the B3?ou+X1?g+ System, and by Collisional Release inside the Banded Region  

Science Journals Connector (OSTI)

... and the ^-propyl iodide was determined by gas chromatography, after separation of the unreacted propane on a low-temperature still. The quantum yield is independent of the area of ... 60 C in a mixture of 0-20 mm of iodine with 100 mm of propane, the quantum yield for the formation of ^-propyl iodide is 1-5 x ...

A. B. CALLEAR; J. F. WILSON

1966-07-30T23:59:59.000Z

104

Fission product iodine during early Hanford-Site operations: Its production and behavior during fuel processing, off-gas treatment and release to the atmosphere  

SciTech Connect (OSTI)

The Hanford Environmental Dose Reconstruction (HEDR) Project was established to estimate the radiological dose impact that Hanford Site operations may have made on the local and regional population. This impact is estimated by examining operations involving radioactive materials that were conducted at the Hanford Site from the startup of the first reactor in 1944 to the present. HEDR Project work is divided among several technical tasks. One of these tasks, Source Terms, is designed to develop quantitative estimates of all significant emissions of radionuclides by Hanford Site operations since 1944. Radiation doses can be estimated from these emissions by accounting for specific radionuclide transport conditions and population demography. This document provides technical information to assist in the evaluation of iodine releases. 115 refs., 5 figs., 3 tabs.

Burger, L.L.

1991-05-01T23:59:59.000Z

105

Generation of iodine L-shell X-rays under excitation of large CF{sub 3}I clusters by femtosecond laser radiation  

SciTech Connect (OSTI)

The use of clusters of polyatomic molecules with a relatively low ionisation energy ({approx}10 eV) is proposed for the efficient production of X-ray radiation. We have observed for the first time the generation of characteristic X-ray radiation due to L transitions in iodine atoms under the high-intensity femtosecond laser irradiation of molecular CF{sub 3}I clusters, which were a small admixture to Ar carrier gas. The X-ray conversion efficiency amounts to {approx}10{sup -6} (for a yield of {approx}10{sup 7} photons per pulse), which is an order of magnitude higher than the efficiency we obtained in the case of argon clusters under comparable conditions. (letters)

Gordienko, Vyacheslav M; Dzhidzhoev, M S; Zhvaniya, I A; Pribytkov, Andrei V; Trubnikov, Dmitrii N; Fedorov, D O

2012-11-30T23:59:59.000Z

106

Distribution of small dispersive coal dust particles and absorbed radioactive chemical elements in conditions of forced acoustic resonance in iodine air filter at nuclear power plant  

E-Print Network [OSTI]

The physical features of distribution of the small dispersive coal dust particles and the adsorbed radioactive chemical elements and their isotopes in the absorber with the granular filtering medium with the cylindrical coal granules were researched in the case of the intensive air dust aerosol stream flow through the iodine air filter (IAF). It was shown that, at the certain aerodynamic conditions in the IAF, the generation of the acoustic oscillations is possible. It was found that the acoustic oscillations generation results in an appearance of the standing acoustic waves of the air pressure (density) in the IAF. In the case of the intensive blow of the air dust aerosol, it was demonstrated that the standing acoustic waves have some strong influences on both: 1) the dynamics of small dispersive coal dust particles movement and their accumulation in the IAF; 2) the oversaturation of the cylindrical coal granules by the adsorbed radioactive chemical elements and their isotopes in the regions, where the antin...

Ledenyov, Oleg P

2013-01-01T23:59:59.000Z

107

E-Print Network 3.0 - alice phos calorimeter Sample Search Results  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

to trigger on and measure hard probes... methods to study high energy density QCD at the LHC. The ALICE Electromagnetic Calorimeter (EMCal) adds... from other ALICE detector...

108

The development and deployment of a ground-based, laser-induced fluorescence instrument for the in situ detection of iodine monoxide radicals  

SciTech Connect (OSTI)

High abundances of iodine monoxide (IO) are known to exist and to participate in local photochemistry of the marine boundary layer. Of particular interest are the roles IO plays in the formation of new particles in coastal marine environments and in depletion episodes of ozone and mercury in the Arctic polar spring. This paper describes a ground-based instrument that measures IO at mixing ratios less than one part in 10{sup 12}. The IO radical is measured by detecting laser-induced fluorescence at wavelengths longer that 500 nm. Tunable visible light is used to pump the A{sup 2}?{sub 3/2} (v{sup ?} = 2) ? X{sup 2}?{sub 3/2} (v{sup ?} = 0) transition of IO near 445 nm. The laser light is produced by a solid-state, Nd:YAG-pumped Ti:Sapphire laser at 5 kHz repetition rate. The laser-induced fluorescence instrument performs reliably with very high signal-to-noise ratios (>10) achieved in short integration times (<1 min). The observations from a validation deployment to the Shoals Marine Lab on Appledore Island, ME are presented and are broadly consistent with in situ observations from European Coastal Sites. Mixing ratios ranged from the instrumental detection limit (<1 pptv) to 10 pptv. These data represent the first in situ point measurements of IO in North America.

Thurlow, M. E., E-mail: thurlow@huarp.harvard.edu; Hannun, R. A.; Lapson, L. B.; Anderson, J. G. [Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138 (United States)] [Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138 (United States); Co, D. T. [Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138 (United States) [Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138 (United States); Argonne-Northwestern Solar Energy Research Center and Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208-3113 (United States); O'Brien, A. S. [Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138 (United States) [Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138 (United States); Department of Civil and Environmental Engineering, Princeton University, Princeton, New Jersey 08544 (United States); Hanisco, T. F. [Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138 (United States) [Department of Chemistry and Chemical Biology, Harvard University, 12 Oxford Street, Cambridge, Massachusetts 02138 (United States); NASA Goddard Space Flight Center, Code 614, Greenbelt, Maryland 20771 (United States)

2014-04-15T23:59:59.000Z

109

Distribution of small dispersive coal dust particles and absorbed radioactive chemical elements in conditions of forced acoustic resonance in iodine air filter at nuclear power plant  

E-Print Network [OSTI]

The physical features of distribution of the small dispersive coal dust particles and the adsorbed radioactive chemical elements and their isotopes in the absorber with the granular filtering medium with the cylindrical coal granules were researched in the case of the intensive air dust aerosol stream flow through the iodine air filter (IAF). It was shown that, at the certain aerodynamic conditions in the IAF, the generation of the acoustic oscillations is possible. It was found that the acoustic oscillations generation results in an appearance of the standing acoustic waves of the air pressure (density) in the IAF. In the case of the intensive blow of the air dust aerosol, it was demonstrated that the standing acoustic waves have some strong influences on both: 1) the dynamics of small dispersive coal dust particles movement and their accumulation in the IAF; 2) the oversaturation of the cylindrical coal granules by the adsorbed radioactive chemical elements and their isotopes in the regions, where the antinodes of the acoustic waves are positioned. Finally, we completed the comparative analysis of the theoretical calculations with the experimental results, obtained for the cases of: 1) the experimental aerodynamic modeling of physical processes of the absorbed radioactive chemical elements and their isotopes distribution in the IAF; and 2) the gamma-activation spectroscopy analysis of the absorbed radioactive chemical elements and their isotopes distribution in the IAF. We made the innovative propositions on the necessary technical modifications with the purpose to improve the IAF technical characteristics and increase its operational time at the nuclear power plant (NPP), going from the completed precise characterization of the IAF parameters at the long term operation.

Oleg P. Ledenyov; Ivan M. Neklyudov

2013-06-14T23:59:59.000Z

110

Iodine-131 Releases from Radioactive Lanthanum Processing at the X-10 Site in Oak Ridge, Tennessee (1944-1956)- An Assessment of Quantities released, Off-Site Radiation Doses, and Potential Excess Risks of Thyroid Cancer, Volume 1  

SciTech Connect (OSTI)

In the early 1990s, concern about the Oak Ridge Reservation's past releases of contaminants to the environment prompted Tennessee's public health officials to pursue an in-depth study of potential off-site health effects at Oak Ridge. This study, the Oak Ridge dose reconstruction, was supported by an agreement between the U.S. Department of Energy (DOE) and the State of Tennessee, and was overseen by a 12-member panel appointed by Tennessee's Commissioner of Health. One of the major contaminants studied in the dose reconstruction was radioactive iodine, which was released to the air by X-10 (now called Oak Ridge National Laboratory) as it processed spent nuclear reactor fuel from 1944 through 1956. The process recovered radioactive lanthanum for use in weapons development. Iodine concentrates in the thyroid gland so health concerns include various diseases of the thyroid, such as thyroid cancer. The large report, ''Iodine-131 Releases from Radioactive Lanthanum Processing at the X-10 Site in Oak Ridge, Tennessee (1944-1956) - An Assessment of Quantities Released, Off-site Radiation Doses, and Potential Excess Risks of Thyroid Cancer,'' is in two volumes. Volume 1 is the main body of the report, and Volume 1A, which has the same title, consists of 22 supporting appendices. Together, these reports serve the following purposes: (1) describe the methodologies used to estimate the amount of iodine-131 (I-131) released; (2) evaluate I-131's pathway from air to vegetation to food to humans; (3) estimate doses received by human thyroids; (4) estimate excess risk of acquiring a thyroid cancer during ones lifetime; and (5) provide equations, examples of historical documents used, and tables of calculated values. Results indicate that females born in 1952 who consumed milk from a goat pastured a few miles east of X-10 received the highest doses from I-131 and would have had the highest risks of contracting thyroid cancer. Doses from cow's milk are considerably less . Detailed dose and risk estimates, and associated uncertainties, for other contaminants studied for the Oak Ridge dose reconstruction are presented in several other technical reports. One way to easily locate them in OSTI's Information Bridge is by searching the ''report number field'' for the number DOE/OR/21981*. Be sure to place the asterisk after the base number so your search can list the complete series of reports related to Oak Ridge Dose Reconstruction.

Apostoaei, A.I.; Burns, R.E.; Hoffman, F.O.; Ijaz, T.; Lewis, C.J.; Nair, S.K.; Widner, T.E.

1999-07-01T23:59:59.000Z

111

Download  

Science Journals Connector (OSTI)

phorus, other indices of algal biomass, transparency, or ... science and its completion is as arduous and as frustrating ... and some index of its fit to the data, like.

112

The Seebeck coefficient of iodine  

E-Print Network [OSTI]

~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ ~ Dry and Wet Crystals ~ ~ ~ ~ ~ ~ ~ ~ Thermoelectric emf Measurement ~ ~ ~ ~ Temperature Variation and Measurement Seebeck Coefficient Measurement Shields and Ground Accuracy Time Required to Obtain Steady-State Miscellaneous 5 5 5 5 7 7 7... the term in the variation of the scattering mechanism, varies as CHAPTER I THEORY The Seebeck effect is the appearance of a voltage drop (thermo- electric emf) in the sample due to a temperature gradient. The Seebeck coefficient of a material...

Perez-Fernandez, Domingo Miguel

2012-06-07T23:59:59.000Z

113

Iodine-129 in Terrestrial Ores  

Science Journals Connector (OSTI)

...from the Broken Hill district of New South Wales...breaking the seal and heating the charcoal to2000C...observed in many major geothermal areas studied in Iceland...within the region of geothermal alteration of the surface...faults, and, in many geothermal areas, faults provide...

B. Srinivasan; E. C. Alexander Jr.; O. K. Manuel

1971-07-23T23:59:59.000Z

114

Equilibria in aqueous iodine solutions  

E-Print Network [OSTI]

for the determination of pH and. 1odide concentration. This instrument, reads pH to 0. 001 pH units and millivolts to F 1 mv. An Orion Specific Ion Electrode, Iodide Model 94-53, was used in the iodide determination. A Corning Triple Purpose pH glass elect- rode... with such electrodes fully confirms this statement. The optimum concentration of Solution I was found to be between 5 x 10 and 10 H iodide. Error in ZIIF Although short-term reproducibility to within 0. 001 26 pH unit can in principle be achieved. with the glass...

Burger, Joanne Denise

1970-01-01T23:59:59.000Z

115

The {sup 2}P{sub 1/2} {yields} {sup 2}P{sub 3/2} laser transition in atomic iodine and the problem of search for signals from extraterrestrial intelligence  

SciTech Connect (OSTI)

It is proposed to search for signals from extraterrestrial intelligence (ETI) at a wavelength of 1.315 {mu}m of the laser {sup 2}P{sub 1/2} {yields} {sup 2}P{sub 3/2} transition in the atomic iodine, which can be used for this purpose as the natural frequency reference. The search at this wavelength is promising because active quantum filters (AQFs) with the quantum sensitivity limit have been developed for this wavelength, which are capable of receiving laser signals, consisting of only a few photons, against the background of emission from a star under study. In addition, high-power iodine lasers emitting diffraction-limited radiation at 1.315 {mu}m have been created, which highly developed ETI also can have. If a ETI sends in our direction a diffraction-limited 10-ns, 1-kJ laser pulse with the beam diameter of 10 m, a receiver with an AQF mounted on a ten-meter extra-atmospheric optical telescope can detect this signal at a distance of up to 300 light years, irrespective of the ETI position on the celestial sphere. The realisation of the projects for manufacturing optical telescopes of diameter 30 m will increase the research range up to 2700 light years. A weak absorption of the 1.315-{mu}m radiation in the Earth atmosphere (the signal is attenuated by less than 20%) allows the search for ETI signals by using ground telescopes equipped with adaptive optical systems. (laser applications and other topics in quantum electronics)

Kutaev, Yu F; Mankevich, S K ['Astrofizika' Research and Production Association (Russian Federation); Nosach, O Yu; Orlov, E P [P.N. Lebedev Physics Institute, Russian Academy of Sciences, Moscow (Russian Federation)

2007-07-31T23:59:59.000Z

116

Iodine Charge-Transfer Salts of Benzene-Bridged Bis(1,2,3,5-diselenadiazolyl) Diradicals. Electrocrystallization and Solid-State Characterization of 1,3- and 1,4-[(Se2N2C)C6H4(CN2Se2)][I  

Science Journals Connector (OSTI)

Electroreduction of 1,3- and 1,4-benzene-bridged bis(diselenadiazolium) salts [1,4-Se][SbF6]2 and [1,4-Se][SbF6]2 in acetonitrile, at a Pt wire and in the presence of iodine affords the 1:1 charge-transfer salts [1,4-Se][I] and [1,3-Se][I]. Crystals of [1,...

C. D. Bryan; A. W. Cordes; N. A. George; R. C. Haddon; C. D. MacKinnon; R. T. Oakley; T. T. M. Palstra; A. S. Perel

1996-03-14T23:59:59.000Z

117

Iodine-131 Releases from Radioactive Lanthanum Processing at the X-10 Site in Oak Ridge, Tennessee (1944-1956)- An Assessment of Quantities released, Off-Site Radiation Doses, and Potential Excess Risks of Thyroid Cancer- APPENDICES Appendices-Volume 1A  

SciTech Connect (OSTI)

This report consists of all the appendices for the report described below: In the early 1990s, concern about the Oak Ridge Reservation's past releases of contaminants to the environment prompted Tennessee's public health officials to pursue an in-depth study of potential off-site health effects at Oak Ridge. This study, the Oak Ridge dose reconstruction, was supported by an agreement between the U.S. Department of Energy (DOE) and the State of Tennessee, and was overseen by a 12-member panel appointed by Tennessee's Commissioner of Health. One of the major contaminants studied in the dose reconstruction was radioactive iodine, which was released to the air by X-10 (now called Oak Ridge National Laboratory) as it processed spent nuclear reactor fuel from 1944 through 1956. The process recovered radioactive lanthanum for use in weapons development. Iodine concentrates in the thyroid gland so health concerns include various diseases of the thyroid, such as thyroid cancer. The large report, ''Iodine-131 Releases from Radioactive Lanthanum Processing at the X-10 Site in Oak Ridge, Tennessee (1944-1956) - An Assessment of Quantities Released, Off-site Radiation Doses, and Potential Excess Risks of Thyroid Cancer,'' is in two volumes. Volume 1 is the main body of the report, and Volume 1A, which has the same title, consists of 22 supporting appendices. Together, these reports serve the following purposes: (1) describe the methodologies used to estimate the amount of iodine-131 (I-131) released; (2) evaluate I-131's pathway from air to vegetation to food to humans; (3) estimate doses received by human thyroids; (4) estimate excess risk of acquiring a thyroid cancer during ones lifetime; and (5) provide equations, examples of historical documents used, and tables of calculated values as appendices. Results indicate that females born in 1952 who consumed milk from a goat pastured a few miles east of X-10 received the highest doses from I-131 and would have had the highest risks of contracting thyroid cancer. Doses from cow's milk are considerably less. Detailed dose and risk estimates, and associated uncertainties, for other contaminants studied in the Oak Ridge dose reconstruction are presented in several other technical reports. One way to easily locate them in OSTI's Information Bridge is by searching the ''report number field'' for the number DOE/OR/21981*. Be sure to place the asterisk after the base number so your search can list the complete series of reports related to Oak Ridge Dose Reconstruction.

Apostoaei, A.I.; Burns, R.E.; Hoffman, F.O.; Ijaz, T.; Lewis, C.J.; Nair, S.K.; Widner, T.E.

1999-07-01T23:59:59.000Z

118

Enzymatic Iodination of Sindbis Virus Proteins  

Science Journals Connector (OSTI)

...in 0.3 ml of growth medium. Adsorption was allowed to pro- ceed for 60 min at 36 C with occasional shaking. Eagle medium (2...Migration here and in subsequent figures was from left to right. ceed for 10 min, at which time the monolayer was washed three times...

Bartholomew M. Sefton; Gary G. Wickus; Boyce W. Burge

1973-05-01T23:59:59.000Z

119

Photo-effects in iodine single crystals  

E-Print Network [OSTI]

Effects 29 29 29 34 34 4D CHAPTER V. DISCUSSIGN A. Dark EMF Values B. photo EMP Spectral Response D. Tenperature Dependence 42 42 44 45 APPENDIX A . Tabulation of Driginal Experlnsntal Data B. Changes in Dark end I hoto EMP... with Tenperature 50 58 54 REFKRENCES LIST OP TABLES Table Effects of various gaseous amhients on dark and photo emf values Page 31 II Effects of cooling on dark and photo emf values 33 vi LIST OF PIGVRES Figure Possible photo-transitions in sn...

Rieves, John Michael

2012-06-07T23:59:59.000Z

120

Speciation of dissolved iodine in estuarine waters  

Science Journals Connector (OSTI)

... at 4 C in the dark, and analysed within a month of collection. Previous storage experiments showed that no measurable changes in iodate or iodide occurred in water stored in ... ) was determined by a procedure different from that used for estuarine waters.

J. DAVID SMITH; EDWARD C. V. BUTLER

1979-02-08T23:59:59.000Z

Note: This page contains sample records for the topic "iodine phos phorus" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


121

Equilibria in trialkylarsine oxide-iodine solutions  

E-Print Network [OSTI]

. Copley, F. Fairbrother, and A. Thompson, J. Less-Common Metals, 8, 256 (1965) ~ 5 ~ 9. 10. 12 L. J. Andrews, Chem. Revs. , ~4, 713 (1954). L. E. Orgel, Quart. Revs. , 8, 422 (1954) . S. P. NcGlynn, Chem. Revs. , ~8, 1113 (1958). L. J. Andrews...

Kolar, Frank Lee

2012-06-07T23:59:59.000Z

122

Natural iodine in a clay formation: Implications for iodine fate in geological disposals  

E-Print Network [OSTI]

a significant contribution to potential overall long-term dose resulting from the waste storage (Altmann, 2008 Laboratory of Environmental Geology, Research Group of Geoenvironmental/Engineering Division of Solid Waste problematic radioisotopes in the context of nuclear waste geological disposal due to its high mobility

Paris-Sud XI, Université de

123

The crystal structure of the triphenylphosphine sulfide - iodine addition complex  

E-Print Network [OSTI]

AND REFINENENT Page 3 5 REFERENCES DISCUSSION OF THE STRUCTURE . . . 10 LIST OF FICUPES Figure l. 2 ~ 3 ~ Page Composite of' the Intensity Statistics f' or the ( 010 ) and ( 001 ) crojections . . . . . lip The Assn'etric Unit in a-axis Pro lection...&lycee . or -', o. ' inc, c&srb)on& anci hydro, "l&&rr;&ave tho f ollowing r&. sul. s: 'od ne &1 oor' I;yd, ogcn 0 b . , ". r' v F& d 56. 33', ' 3 2. 26;:r. h. . o c?r& al 3 c&'' ';) ) ; or ono raolcc ulc o" t, r&c complox irr thc, rni ?, . c...

Schweikert, William Walter

2012-06-07T23:59:59.000Z

124

The contribution of oceanic methyl iodide to stratospheric iodine  

E-Print Network [OSTI]

horizontal wind speed and vertical transport efficiency (speed Horizontal wind speed and vertical transport CH 3 Ivertical transport. Note that for these two days high www.atmos-chem-phys.net/13/11869/2013/ horizontal wind speeds

2013-01-01T23:59:59.000Z

125

Simulation of the sulphur iodine thermochemical cycle / Bothwell Nyoni.  

E-Print Network [OSTI]

??The demand for energy is increasing throughout the world, and fossil fuel resources are diminishing. At the same time, the use of fossil fuels is (more)

Nyoni, Bothwell

2011-01-01T23:59:59.000Z

126

Technetium and Iodine Separations in the UREX Process.  

SciTech Connect (OSTI)

The Accelerator Transmutation of Waste (ATW) program is being developed to determine the feasibility of separatin and transmutating the transactinides (Pu-Cm) and long-lived fission product (99Tc and 'I) from spent light water reactor (LWR) fuel. This approach would help with the disposal of spent commercial fuel. In addition, since the residual waste after ATW treatment will have much lower levels of long-lived species, this process may improve the performance and acceptability of long-term geologic disposal of nuclear waste. A roadmap for the Accelerator Transmutation of Waste (ATW) was submitted to Congress in 1999.' This document gave an overall view of the ATW concept and program. A subsequent document prepared by the Technical Working Group for ATW Separations Technologies and Waste Forms issued a second roadmap that dealt more specifically with the radionuclide separations and waste disposal needs for the ATW program.' This latter document discusses the UREX (Uranium Extraction) process. The latest iteration of the UREX flowsheet is shown in Figure le3T his flowsheet anticipates the co-extraction of technetium with uranium from dissolved LWR fuel by tributylphosphate (TBP) and their subsequent sequential bwk-extraction from the TBP stream.

Schroeder, N. C. (Norman C.); Attrep, Moses; Marrero, T. (Thomas)

2001-01-01T23:59:59.000Z

127

Measurement of the resistivity versus temperature in iodine single crystals  

E-Print Network [OSTI]

Me:. . of: the' aygnreti'up. O'M:~e =', ? brana, rod, - C' ln the- oopper blond, ", E . e-, the-. heater. &&re; . . : ';;;!, :; and 8' 9:e ?tIie danplj mounted Xn the ogIindH. oa1, ~11 of' '. ' the pgaQB 8lfclei 1 , -. 9y p1ac&! the. button...&ge ;kanp1e Pre@erat;ao'n', md. "EgM jument -i'=q=, =';~=' . ' IX~, . ". '. :Keasurcdent . of 'Hes5stk~4y as a Pm'@Mon o5 ';" . -'2sinjsrshure. an/ BeitiiICs; ~. ' j -, ', '-'. v ~ . '- . ? t XTjfe. . . '?Df sonation. of Resnlt'8 ~ ~ ~ ' s ~ ', e...

Somoano, Robert Bonner

2012-06-07T23:59:59.000Z

128

Distribution of iodine in soils of Northern Ireland  

Science Journals Connector (OSTI)

...geochemical and airborne geophysical survey...concentrates while the airborne geophysical survey...square. 2-mm fraction pulverized in...Lead collection fire assay/ ICP-MS...Lead collection fire assay/ ICP-MS...the 2 150 mum fraction. Examined for...1958). The release of highly radioactive...

Dermot Smyth; Christopher C. Johnson

129

Synthetic Approaches to a Novel Iodinated Analogue of BPA  

Science Journals Connector (OSTI)

Prevailing clinical boron carriers for BNCT are disodium mercaptoundecahydro-closo...-dodecaborate (sodium borocaptate, BSH) and 4-dihydroxyboryl phenylalanine (4-boronophenylalanine, BPA). It has been shown that...

M. Suominen; J. Vhtalo; J. Yli-Kauhaluoma

2001-01-01T23:59:59.000Z

130

The standard potential of the iodate/iodine electrode  

E-Print Network [OSTI]

THE STAJ'JDAPD POTDi TIAL IODATE/IODI JJE EDEC'i ROJ E A Thesis RODNEY, DJ&ll . RT SPITZ Suhmitted to the Gregau?te Coliec, :e of Texas AJ'H Ln: uer; its in pvrtia1 fu' fi11ment of the re. ". , uir?. ". : nt for the deosr'. e of MASTER OE.... O. Lundberg and W. M. Latimer, J. Amer. Chem. Soc. 56, 858 (1934) VITA Rodney Dwight Spitz was born in Saqinaw, Michigan on August 8, 1935. He is the son of Albert F. . Spitz of Saginaw, Michigan and Aurelia O. Prater. of Ventura, California...

Spitz, Rodney Dwight

2012-06-07T23:59:59.000Z

131

Detection of iodine monoxide in the tropical free troposphere  

Science Journals Connector (OSTI)

...runs were conducted with WRF (22): (i) a 60-h...km) to better resolve local deep convection. The model...retrieval. Fig. S3. WRF simulations from a cloud-resolving...line. Scattered trade wind cumulus clouds (gray...research and forecast model (WRF) analysis of air...

Barbara Dix; Sunil Baidar; James F. Bresch; Samuel R. Hall; K. Sebastian Schmidt; Siyuan Wang; Rainer Volkamer

2013-01-01T23:59:59.000Z

132

Download Full-text PDF  

Science Journals Connector (OSTI)

... seawater with cium phosphates such as apatites and phos- calcium phosphates in two regions of the phorites; an ion product which in its. North Pacific Ocean.

2000-01-13T23:59:59.000Z

133

Download Full-text PDF  

Science Journals Connector (OSTI)

Carlson-type trophic state index (Carlson 1977; Kratzer and. Brezonik 1981). Dense stands of .... 3C through completion of analysis. Nitrate (NO ) and phos-. 3.

2005-10-25T23:59:59.000Z

134

Synthesis and study of ligands for Pd-catalyzed C-O and C-N coupling  

E-Print Network [OSTI]

A new ligand, AdBrettPhos, was synthesized and its use, along with tBuBrettPhos, in C-O coupling reactions at low temperatures was investigated. Using Pd catalysts containing these ligands, electron-neutral aryl bromides ...

Davis, Nicole R

2009-01-01T23:59:59.000Z

135

Iodine molecule for neutrino mass spectroscopy: ab initio calculation of spectral rate  

Science Journals Connector (OSTI)

......such as tritium for the measurement of an averaged absolute neutrino mass value, and (2) the search of neutrinoless double beta decay for verification of lepton number violation related to a finite Majorana type of masses. So far negative......

Motomichi Tashiro; Masahiro Ehara; Susumu Kuma; Yuki Miyamoto; Noboru Sasao; Satoshi Uetake; Motohiko Yoshimura

2014-01-01T23:59:59.000Z

136

Space-charge-limited current measurements in iodine crystals by pulse techniques  

E-Print Network [OSTI]

to x = d. using the con- ditions: ae E(0 ~ t) 0 Q t-0 pd b. ) E dx = V = constant 0 c. Q~(x, t) = 0 &x one obtains 2 ](d. t) = a~ E (d. t) 'Sw d Now at x = d, before the leading front of the carriers arrives, p(d. t) = 0 , t&ti so that Jc... = 0 at x = d for t ti (the transit time of the carriers). This implies that dE = 0 o t&ti 'bxx=d Therefore we see from E&Ls. (3) and (0) that hE(d, t) = 8E (d. , t) ~ t&ti st 2d (5) A solution to Eq. (5) is E=V 1 d ~oct with ~= 1 and. t = d...

Robinette, William Clayton

2012-06-07T23:59:59.000Z

137

Distribution coefficient values describing iodine, neptunium, selenium, technetium, and uranium sorption to Hanford sediments. Supplement 1  

SciTech Connect (OSTI)

Burial of vitrified low-level waste (LLW) in the vadose zone of the Hanford Site is being considered as a long-term disposal option. Regulations dealing with LLW disposal require that performance assessment (PA) analyses be conducted. Preliminary modeling efforts for the Hanford Site LLW PA were conducted to evaluate the potential health risk of a number of radionuclides, including Ac, Am, C, Ce, Cm, Co, Cs, Eu, 1, Nb, Ni, Np, Pa, Pb, Pu, Ra, Ru, Se, Sn, Sr, Tc, Th, U, and Zr (Piepho et al. 1994). The radionuclides, {sup 129}I, {sup 237}Np, {sup 79}Se, {sup 99}Tc, and {sup 234,235,238}U, were identified as posing the greatest potential health hazard. It was also determined that the outcome of these simulations were very sensitive to the parameter describing the extent to which radionuclides sorbed to the subsurface matrix, described as a distribution coefficient (K{sub d}). The distribution coefficient is a ratio of the radionuclide concentration associated with the solid phase to that in the liquid phase. The literature-derived K{sub d} values used in these simulations were conservative, i.e., lowest values within the range of reasonable values used to provide an estimate of the maximum health threat. Thus, these preliminary modeling results reflect a conservative estimate rather than a best estimate of what is likely to occur. The potential problem with providing only a conservative estimate is that it may mislead us into directing resources to resolve nonexisting problems.

Kaplan, D.I.; Seme, R.J.

1995-03-01T23:59:59.000Z

138

The iodineplutoniumxenon age of the MoonEarth system revisited  

Science Journals Connector (OSTI)

...to a higher thermal regime of the...Isotopic spectrum of xenon relative...Ozima. 2012 Thermal evolution of...Plutonium-fission xenon found...spallation and neutron-induced reactions...I. High-energy irradiances...

2014-01-01T23:59:59.000Z

139

Thermochemical H 2- Production with Sulfur-Iodine Process and Solar Energy Adaptation  

Science Journals Connector (OSTI)

A thermochemical cycle for hydrogen production is a process in which water is used as a feedstock along with a non-fossil high temperature heat source to produce H2 and O2 as product gases. The water splitting pr...

K. F. Knoche

1991-01-01T23:59:59.000Z

140

Carrier envelope phase stabilization of a femtosecond laser and iodine spectroscopy  

E-Print Network [OSTI]

for carrier envelope phase stabilization. An f to 2f interferometer was used to detect the carrier envelope offset frequency, and a fast photo diode was employed to measure the repetition rate. Two similar designed phase lock loops are used to stabilize both...

Zhu, Feng

2006-10-30T23:59:59.000Z

Note: This page contains sample records for the topic "iodine phos phorus" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


141

On the mobility and potential retention of iodine in the Callovovian-Oxfordian formation  

E-Print Network [OSTI]

manuscript, published in "Physics and Chemistry of the Earth Parts A/B/C 32 (2007) 539-551" DOI : 10.1016/j.pce organic matter of the sediment before and during deposition, and early diagenesis. At variance with total diffusion on similar rock materials have already shown that iodide does not behave like chloride

Paris-Sud XI, Université de

142

Enhancement of electric oxygen-iodine laser performance using a rectangular discharge and longer gain length  

E-Print Network [OSTI]

is produced by a single radio-frequency-excited electric discharge sustained in an O2­He­NO gas mixture a is produced by a single transverse capacitive 13.56 MHz rf excited electric discharge sustained in an O2­He discharge channel section has an internal flow cross section of 1.6 cm by 7.5 cm. The plasma zone filled

Carroll, David L.

143

Capture of Solar and Higher-Energy Neutrinos by Iodine 127  

E-Print Network [OSTI]

We discuss and improve a recent treatment of the absorption of solar neutrinos by ${}^{127}$I, in connection with a proposed solar neutrino detector. With standard-solar-model fluxes and an in-medium value of -1.0 for the axial-vector coupling constant $g_A$, we obtain a ${}^8$B-neutrino cross section of 3.3$\\times 10^{-42}$, about 50\\% larger than in our previous work, and a ${}^7$Be cross section that is less certain but nevertheless also larger than before. We then apply the improved techniques to higher incoming energies that obtain at the LAMPF beam dump, where an experiment is underway to finalize a calibration of the ${}^{127}$I with electron neutrinos from muon decay. We find that forbidden operators, which play no role in solar-neutrino absorption, contribute nonnegligibly to the LAMPF cross section, and that the preliminary LAMPF mean value is significantly larger than our prediction.

J. Engel; S. Pittel; P. Vogel

1994-02-17T23:59:59.000Z

144

Solar-Grade Silicon from Metallurgical-Grade Silicon Via Iodine Chemical Vapor Transport Purification: Preprint  

SciTech Connect (OSTI)

This conference paper describes the atmospheric-pressure in an ''open'' reactor, SiI2 transfers from a hot (>1100C) Si source to a cooler (>750C) Si substrate and decomposes easily via 2SiI2 Si+ SiI4 with up to 5?m/min deposition rate. SiI4 returns to cyclically transport more Si. When the source is metallurgical-grade Si, impurities can be effectively removed by three mechanisms: (1) differing free energies of formation in forming silicon and impurity iodides; (2) distillation; and (3) differing standard free energies of formation during deposition. Distillation has been previously reported. Here, we focused on mechanisms (1) and (3). We made feedstock, analyzed the impurity levels, grew Czochralski single crystals, and evaluated crystal and photovoltaic properties. Cell efficiencies of 9.5% were obtained. Incorporating distillation (step 2) should increase this to a viable level.

Ciszek, T. F.; Wang, T. H.; Page, M. R.; Bauer, R. E.; Landry, M. D.

2002-05-01T23:59:59.000Z

145

Characterization of an iodine-based ionic liquid ion source and studies on ion fragmentation  

E-Print Network [OSTI]

Electrosprays are a well studied source of charged droplets and ions. A specific subclass is the ionic liquid ion source (ILIS), which produce ion beams from the electrostatically stressed meniscus of ionic liquids. ILIS ...

Fedkiw, Timothy Peter

2010-01-01T23:59:59.000Z

146

Prolonged survival of Pseudomonas cepacia in commercially manufactured povidone-iodine.  

Science Journals Connector (OSTI)

...facturing plant. A plant investigation was initiated to deter...would all seem prudent as remedial measures. Manu- facturers...W. J. Martone. 1984. Investigations into the survival of Pseudomonas...commercial iodophor solution: investigation of the implicated manufacturing...

R L Anderson; R W Vess; A L Panlilio; M S Favero

1990-11-01T23:59:59.000Z

147

Microhydration Effects on the Intermediates of the SN2 Reacation of Iodide Anion with Methyl Iodine  

SciTech Connect (OSTI)

Reactions of halide anions with methyl halides (X- + CH3Y ? XCH3 + Y-) are bimolecular nucleophilic substitution (SN2) reactions that have been well investigated in the last few decades.[1] Figure 1 shows typical potential energy surfaces (PESs) proposed for symmetric (X- + CH3X ? XCH3 + X-) SN2 reactions along the reaction coordinate. In the gas phase, the PES has two minima corresponding to the stable X-(CH3X) complexes.[2] The PES is substantially distorted by the solvation. Since the negative charge is delocalized over the [XCH3X]- moiety at the transition state the stabilization energy gained by the solvation is smaller for the transition state than that for the (X- + CH3X) reactants or the X- (CH3X) complexes. In solution, a large potential barrier exists between the reactants and products. The rate constants of these reactions in protic solvents were reported to be a few orders of magnitude smaller than those in aprotic solvents; this trend was explained by the formation of solvation shells of protic molecules around the halide anions.[1,3] Morokuma has previously reported a theoretical study on the PES of the (Cl- + CH3Cl ? ClCH3 + Cl-) SN2 reaction with a few H2O molecules. The attachment of H2O molecules to the Cl-(CH3Cl) reactive system produces metastable isomers, which affect the reaction mechanism.[4] Johnson and coworkers extensively investigated the structure and reactions of halide anion complexes in the gas phase using photodissociation spectroscopy.

Doi, Keisuke; Togano, Eijiro; Xantheas, Sotiris S.; Nakanishi, Ryuzo; Nagata, Takashi; Ebata, Takayuki; Inokuchi, Yoshiya

2013-04-15T23:59:59.000Z

148

Impact of Foliar Fertilizer Containing Iodine on Golden Delicious Apple Trees  

E-Print Network [OSTI]

on marketable Golden Delicious/M.9 apple production. At thecontaining fertilizer on apple fruits firmness and theirold Golden Delicious/M.9 apple trees Trees were spaced at

Szwonek, Eugeniusz

2009-01-01T23:59:59.000Z

149

Iodine Isotopes (127I and 129I) in Aerosols at High Altitude Alp Stations  

Science Journals Connector (OSTI)

Since there are no local pollution sources and the observatory itself is supplied with electricity through cable, the SBO has the ideal characteristics of a high alpine background station. ... In the period of Jan 16 to Feb 1 (first 129I maximum at Zugspitze) the winds came mainly from southeast to southwest, but beginning with Jan 29 the main wind direction was from northwest to west. ... Also we would expect influence from air masses with southern origin at Sonnblick, while at Zugspitze the air flow should be mainly from northwest with the exception of foehn situations (which occur more frequently during spring). ...

Tania Jabbar; Peter Steier; Gabriele Wallner; Alfred Priller; Norbert Kandler; August Kaiser

2012-07-23T23:59:59.000Z

150

Evaluation of radiation-induced myocardial damage using iodine-123 ?-methyl-iodophenyl pentadecanoic acid scintigraphy  

Science Journals Connector (OSTI)

......short follow-up period after completion of RT for cardiac dysfunction...most useful as a prognostic index for RT-induced cardiac events...has become a widely accepted index of heart failure or heart remodeling...The median interval from completion of RT to I-123 BMIPP scintigraphy......

Rei Umezawa; Kei Takase; Keiichi Jingu; Kentaro Takanami; Hideki Ota; Tomohiro Kaneta; Ken Takeda; Haruo Matsushita; Hisanori Ariga; Shoki Takahashi; Shogo Yamada

2013-09-01T23:59:59.000Z

151

Novel 125 I production and recovery system  

E-Print Network [OSTI]

This research suggests ways of reducing contamination of iodine-126 in iodine-125 and lays out a simpler iodine-125 production technique to increase the yield. By using aluminum irradiation vessels the yield of iodine-125 produced by neutron...

Kar, Adwitiya

2009-05-15T23:59:59.000Z

152

Meta-Analysis of Arabidopsis thaliana Phospho-Proteomics Data Reveals Compartmentalization of Phosphorylation Motifs  

Science Journals Connector (OSTI)

...accessible through the joint portal of MASCP Gator (Joshi et al., 2011). Several plant p-proteomics...Arabidopsis proteome aggregator database MASCP Gator (Joshi et al., 2011) at http://gator.masc-proteomics.org/ . In PhosPhAt...

Klaas J. van Wijk; Giulia Friso; Dirk Walther; Waltraud X. Schulze

2014-06-03T23:59:59.000Z

153

Loss of High-Energy Phosphate following Hyperthermia Demonstrated by in Vivo 31P-Nuclear Magnetic Resonance Spectroscopy  

Science Journals Connector (OSTI)

...even after substantial heat exposure. An obvious...discrepancy is that the loss of high-energy phos...correlation between loss of ATP, cell kill, and heat dose, when compared...Inhomogenous heat distribution, variable metabolic...

Michael B. Lilly; Thian C. Ng; William T. Evanochko; Charles R. Katholi; Narinder G. Kumar; Gabriel A. Elgavish; John R. Durant; Raymond Hiramoto; Vithal Ghanta; and Jerry D. Glickson

1984-02-01T23:59:59.000Z

154

Biotechnological storage and utilization of entrapped solar energy  

Science Journals Connector (OSTI)

Our laboratory has recently developed a device employing immobilized F0F1...adenosine triphosphatase (ATPase) that allows synthesis of adenosine triphosphate (ATP) from adenosine 5?-diphosphate and inorganic phos...

Sumana Bhattacharya; Marc Schiavone; Amiya Nayak

2005-03-01T23:59:59.000Z

155

BIOCHEMICAL AND BIOPHYSICAL RESEARCH COMMUNICATIONS 243, 664668 (1998) ARTICLE NO. RC988151  

E-Print Network [OSTI]

) particles from potato tuber. N-terminal se-between F1 and Fo and regulate energy coupling in quences characterised protein phos- Mitochondria were isolated and purified from potato tubers (Sola- phorylation

Allen, John F.

156

ABSTRACTS:  

Science Journals Connector (OSTI)

......Then the tissues were brought into room temperature and hydrated with cacodylate buffer...one of the purified mold lipases and snake venom phos- pholipases, respectively...from known amino acid sequence. 11. Development of quantitative immunoelectron mi- croscopy......

The Thirty-first Symposium of the Japanese Society of Electron Microscopy Held at Faculty of Engineering; University of Tokyo; Tokyo; Japan October 17-18; 1985 Main Theme: Localization of Constituents

1986-01-01T23:59:59.000Z

157

A Matrix Isolation Study of the Photochemically Induced Reactions of Ozone with Iodine Cyanide and Bromine Cyanide  

Science Journals Connector (OSTI)

Robin J. H. Clark ,* Loraine J. Foley , and Stephen D. Price ... Clark, Robin J. H.; Dann, Jonathan R.; Foley, Loraine J. ... Clark, Robin J. H.; Dann, Jonathan R.; Foley, Loraine J. ...

Robin J. H. Clark; Loraine J. Foley; Stephen D. Price

2000-10-21T23:59:59.000Z

158

The level of serum protein-bound iodine, its repeatability and relationship to rate of gain in immature beef cattle  

E-Print Network [OSTI]

Crockshank0 Mr, Jo P? Smith and their Vi 3 NA assistants fcr their help and cooperation at the PanTech Farms Amarillo,, Texas; D r 0 Tom G, Cartwright and assistants for their help and cooperation, Nj at Substation 239 McGregor9 Texas; Mr? John K? Riggs... Experiment Station, Substation 23, McGregor, Texas, and the PanTech .Farm, Amarillo, Texas, respectively? The third group consisted of animals that were, purchased by the Department of Animal Husbandry, A? and M 0 College of Texas, for demons tr a tiona.1...

Green, George G.

2013-10-04T23:59:59.000Z

159

The effect of vitamin B 12 and various levels of iodine in the diet of growing chicks and mature hens  

E-Print Network [OSTI]

. "sent in fish meal a. ;d brews" yeast (Carlsox' ct al, . '940), liver and dolactosed ilried whey (Menge, *"onibs and dhorb, 1949), fish soiubles (eundo ct al. , . ' 350) anti distillors solubles (iNorris ot al. , 1950). The offcut of vitamin D, 2... deiactosed whey, as shown in 'l'able IH. Tbe hens were artHiclaQy insemhated twice each week with 0. s ml. oi pooled semen iron: New Hampshire '. iales. The eggs were gathered daily, marked with hen number and dat' andstored bi a constant tempera- ture...

Banta, Edward Mack

2012-06-07T23:59:59.000Z

160

The influence of iodinated casein and high fat diets on the performance and incidence of fatty livers in laying hens  

E-Print Network [OSTI]

&iocasein caused no chango in egg p"eduction i&i&en fc&3 by (?itt&. ridge and Novi!&off (1&347), . &ilson (1&34&3) and Iianson and Smyth (1'355) at 200 grims per tor. . -gg production w:is not affected wTi &n iodinai, =d ca cirl w'is f&'d b) oillie et al...&iocasein caused no chango in egg p"eduction i&i&en fc&3 by (?itt&. ridge and Novi!&off (1&347), . &ilson (1&34&3) and Iianson and Smyth (1'355) at 200 grims per tor. . -gg production w:is not affected wTi &n iodinai, =d ca cirl w'is f&'d b) oillie et al...

Young, Louis Lee

2012-06-07T23:59:59.000Z

Note: This page contains sample records for the topic "iodine phos phorus" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


161

Novel Parameter Predicting Grade 2 Rectal Bleeding After Iodine-125 Prostate Brachytherapy Combined With External Beam Radiation Therapy  

SciTech Connect (OSTI)

Purpose: To propose a novel parameter predicting rectal bleeding on the basis of generalized equivalent uniform doses (gEUD) after {sup 125}I prostate brachytherapy combined with external beam radiation therapy and to assess the predictive value of this parameter. Methods and Materials: To account for differences among radiation treatment modalities and fractionation schedules, rectal dosevolume histograms (DVHs) of 369 patients with localized prostate cancer undergoing combined therapy retrieved from corresponding treatment planning systems were converted to equivalent dose-based DVHs. The gEUDs for the rectum were calculated from these converted DVHs. The total gEUD (gEUD{sub sum}) was determined by a summation of the brachytherapy and external-beam radiation therapy components. Results: Thirty-eight patients (10.3%) developed grade 2+ rectal bleeding. The grade 2+ rectal bleeding rate increased as the gEUD{sub sum} increased: 2.0% (2 of 102 patients) for <70 Gy, 10.3% (15 of 145 patients) for 70-80 Gy, 15.8% (12 of 76 patients) for 80-90 Gy, and 19.6% (9 of 46 patients) for >90 Gy (P=.002). Multivariate analysis identified age (P=.024) and gEUD{sub sum} (P=.000) as risk factors for grade 2+ rectal bleeding. Conclusions: Our results demonstrate gEUD to be a potential predictive factor for grade 2+ late rectal bleeding after combined therapy for prostate cancer.

Shiraishi, Yutaka, E-mail: shiraishi@rad.med.keio.ac.jp [Department of Radiology, Keio University School of Medicine, Tokyo (Japan); Hanada, Takashi; Ohashi, Toshio [Department of Radiology, Keio University School of Medicine, Tokyo (Japan); Yorozu, Atsunori; Toya, Kazuhito [Department of Radiology, National Hospital Organization Tokyo Medical Center, Tokyo (Japan); Saito, Shiro [Department of Urology, National Hospital Organization Tokyo Medical Center, Tokyo (Japan); Shigematsu, Naoyuki [Department of Radiology, Keio University School of Medicine, Tokyo (Japan)

2013-09-01T23:59:59.000Z

162

Iodine Pathways and Off-Gas Stream Characteristics for Aqueous Reprocessing Plants A Literature Survey and Assessment  

SciTech Connect (OSTI)

Used nuclear fuel is currently being reprocessed in only a few countries, notably France, England, Japan, and Russia. The need to control emissions of the gaseous radionuclides to the air during nuclear fuel reprocessing has already been reported for the entire plant. But since the gaseous radionuclides can partition to various different reprocessing off-gas streams, for example, from the head end, dissolver, vessel, cell, and melter, an understanding of each of these streams is critical. These off-gas streams have different flow rates and compositions and could have different gaseous radionuclide control requirements, depending on how the gaseous radionuclides partition. This report reviews the available literature to summarize specific engineering data on the flow rates, forms of the volatile radionuclides in off-gas streams, distributions of these radionuclides in these streams, and temperatures of these streams. This document contains an extensive bibliography of the information contained in the open literature.

R. T. Jubin; D. M. Strachan; N. R. Soelberg

2013-09-01T23:59:59.000Z

163

Relation between clinical and laboratory parameters with radiation dose rates from patients receiving iodine-131 therapy for thyroid carcinoma  

Science Journals Connector (OSTI)

......educate every patient on radiation safety procedures for the dosage...improvised containers; the safety officer transferred...origin of emission, and radiation detection survey metre...significant. SPSS for Windows software package (Release 11......

Isa Neshandar Asli; Nastaran Baharfard; Babak Shafiei; Faraj Tabei; Hamid Javadi; Mohammad Seyedabadi; Iraj Nabipour; Majid Assadi

2010-03-01T23:59:59.000Z

164

Radioactive iodine (131I) therapy for differentiated thyroid cancer in Japan: current issues with historical review and future perspective  

Science Journals Connector (OSTI)

Finally, we are looking forward to receiving international supports abroad. The situation in Fukushima is changing every day and people in Fukushima are still now confronting a variety of...55...]. Due to their o...

Tatsuya Higashi; Takashi Kudo; Seigo Kinuya

2012-02-01T23:59:59.000Z

165

Proteins iodinated by the Chloramine-T method appear to be degraded at an abnormally rapid rate after endocytosis  

Science Journals Connector (OSTI)

...of Biomedical Sciences, and Biology Division, Oak Ridge National Laboratory, Oak Ridge, Tennessee 37830 Communicated by Alexander Hollaender...yolk proteins lipovitellin and phosvitin. These workers demonstrated that 96% of the radioactivity contained...

L. Opresko; H. S. Wiley; R. A. Wallace

1980-01-01T23:59:59.000Z

166

A study of the reactions related to the catalytic decomposition of hydrogen peroxide by the iodate-iodine couple  

E-Print Network [OSTI]

salt used as a source of thallous ion. Thus, we were confined, at any tempera- ture, within certain limits of [I ], the lower limit being governed by solubility of T1NO and salt effect; and the upper by the possibility of occurence of Reac- tions B... salt used as a source of thallous ion. Thus, we were confined, at any tempera- ture, within certain limits of [I ], the lower limit being governed by solubility of T1NO and salt effect; and the upper by the possibility of occurence of Reac- tions B...

Simic, Radmilo

2012-06-07T23:59:59.000Z

167

129 Iodine: A New Hydrologic Tracer for Aquifer Recharge Conditions Influenced by River Flow Rate and Evapotranspiration  

E-Print Network [OSTI]

County using boron isotopes and general geochemistry, In Lawrence Livermore National Laboratory UCRL-ID-133529 (pp. 44). ? Davisson, M.L., Hudson, G.B., Herndon, R., & Woodside, G. (1999b). Report on isotope tracer investigations in the Forebay... of the Orange County Groundwater Basin: Fiscal years 1996 and 1997, In Lawrence Livermore National Laboratory UCRL-ID- 133531 (pp. 44). ? Dissanayake, C.B. & Chandrajith, R. (1999). Medical geochemistry of tropical environments. Earth-Science Reviews 47, 219...

Schwehr, K. A.; Santschi, P. H.; Moran, J. E.

2003-01-01T23:59:59.000Z

168

Fallout of atmospheric nuclear tests in 1950s and 1960s exposed more people to Iodine-131 than Chernobyl accident  

SciTech Connect (OSTI)

A National Cancer Institute report on I-131 radiation exposure from atmospheric nuclear weapon tests in the USA is summarized. (AIP)

Goodwin, I. [Physics Today, American Center for Physics, One Physics Ellipse, College Park, Maryland 20740-3843 (United States)

1997-09-01T23:59:59.000Z

169

Toxoplasma gondii Oocysts in Water  

E-Print Network [OSTI]

Pavlo. 2005. Do iodine water purification tablets provide an1997. Efficacy of iodine water purification tablets againstwater: 1) concentration and filtration, 2) elution and purification

Wainwright, Katlyn E.

2008-01-01T23:59:59.000Z

170

Characterization of a New Charge Sensitive Preamplifier (CSP) for the Electromagnetic Calorimeters of the ALICE Experiment  

SciTech Connect (OSTI)

The ALICE calorimeters PHOS and EMCal (including its extension DCal) are based on Avalanche Photo-Diode (APD) photosensors with Charge Sensitive Preamplifiers (CSPs) for readout of the scintillating elements. A new CSP has been developed on the basis of the design of the PHOS CSP, but modified to meet the requirements of the EMCal and DCal. Modifications were made specifically for a different APD choice with different characteristics, and also with the goals of less noise, faster rise time, and reduced cost. This paper presents a detailed description of the new CSP features and the test results.

Wang, Yaping [Inst. of Particle Physics/Key Lab. of Quark and Lepton Physics, Central China Normal Univ., Wuhan, C; Muller, Hans [CERN, Geneva, Switzerland; Cai, Xu [Inst. of Particle Physics/Key Lab. of Quark and Lepton Physics, Central China Normal Univ., Wuhan, C; Zhou, Daicui [Inst. of Particle Physics/Key Lab. of Quark and Lepton Physics, Central China Normal Univ., Wuhan, C; Awes, Terry C [ORNL; Yin, Zhongbao [Inst. of Particle Physics/Key Lab. of Quark and Lepton Physics, Central China Normal Univ., Wuhan, C

2012-01-01T23:59:59.000Z

171

Photovoltaics: Cheap, colourful solar cells  

Science Journals Connector (OSTI)

... composed of lead; methylammonium; and iodine or bromine, or both. Semiconductors used in solar ...solarcells ...

2013-04-17T23:59:59.000Z

172

DOE/RL-2010-89 Review Copy October 1, 2010  

E-Print Network [OSTI]

such as chromium, nitrate, carbon tetrachloride, tritium, iodine-129, and technetium-99 at concentrations above

Hubbard, Susan

173

Bromine and iodine chemistry in a global chemistry-climate model: description and evaluation of very short-lived oceanic sources  

E-Print Network [OSTI]

J. , Troe, J. , ,and Wallington, T. J. : Evaluated kinetic12/1423/2012/ Bilde, M. , Wallington, T. J. , Ferronato,

2012-01-01T23:59:59.000Z

174

Evaluation of ischemia and myocardial viability in patients with coronary artery disease (CAD) with iodine-123-labeled 15-(p-iodophenyl)-3-R,S-methylpentadecanoic acid (BMIPP)  

SciTech Connect (OSTI)

Twenty patients with coronary artery disease (CAD) controlled by coronary arteriography (CA) and biplane left ventricular cineventriculography (LVCV) were investigated with the 15- (p[I-123]iodophenyl)-3-R,S-methylpentadecanoic acid (BMIPP) fatty acid analogue. During maximal symptom limited exercise 5 mCi (200 MBq) of BMIPP were injected followed by two SPECT studies within three hours. After another 30 min, with the patient at rest a third SPECT was performed after reinjection of 3 mCi (100 MBq) BMIPP. Visual inspection of the short and long axis slices and quantitative comparison of the short axis slices of the tomograms were performed to grade BMIPP uptake and refill and detect turnover abnormalities. These were addressed either as scar or as ischemia and compared to CA and a graded score of regional wall motion by LVCV which provided values for sensitivity (SE) and specificity (SP) to detect CAD. Fifteen infarctions had corresponded clinical, angiographic and scintigraphic findings in 93%.

Kropp, J.; Joergens, M.; Glaenzer, K.P.; Luederitz, B.; Biersack, H.J. [Bonn Univ. (Germany); Knapp, F.F. Jr. [Oak Ridge National Lab., TN (United States)

1993-10-01T23:59:59.000Z

175

Continuous-wave laser oscillation in subsonic flow on the 1315 nm atomic iodine transition pumped by electric discharge produced O2,,a 1  

E-Print Network [OSTI]

of the experimental setup is shown in Fig. 1. A radio frequency rf electric discharge at 13.56 MHz operating between a 1 produced by a radio-frequency-excited electric discharge. The electric discharge was sustained two internal hollow cathode electrodes was used as the excitation source. The plasma zone

Carroll, David L.

176

Development and comparison of computational models for estimation of absorbed organ radiation dose in rainbow trout (Oncorhynchus mykiss) from uptake of iodine-131  

Science Journals Connector (OSTI)

Abstract This study develops and compares different, increasingly detailed anatomical phantoms for rainbow trout (Oncorhynchus mykiss) for the purpose of estimating organ absorbed radiation dose and dose rates from 131I uptake in multiple organs. The models considered are: a simplistic geometry considering a single organ, a more specific geometry employing additional organs with anatomically relevant size and location, and voxel reconstruction of internal anatomy obtained from CT imaging (referred to as CSUTROUT). Dose Conversion Factors (DCFs) for whole body as well as selected organs of O.mykiss were computed using Monte Carlo modeling, and combined with estimated activity concentrations, to approximate dose rates and ultimately determine cumulative radiation dose (?Gy) to selected organs after several half-lives of 131I. The different computational models provided similar results, especially for source organs (less than 30% difference between estimated doses), and whole body \\{DCFs\\} for each model (?3נ10?3?Gyd?1perBqkg?1) were comparable to \\{DCFs\\} listed in ICRP 108 for 131I. The main benefit provided by the computational models developed here is the ability to accurately determine organ dose. A conservative mass-ratio approach may provide reasonable results for sufficiently large organs, but is only applicable to individual source organs. Although CSUTROUT is the more anatomically realistic phantom, it required much more resource dedication to develop and is less flexible than the stylized phantom for similar results. There may be instances where a detailed phantom such as CSUTROUT is appropriate, but generally the stylized phantom appears to be the best choice for an ideal balance between accuracy and resource requirements.

N.E. Martinez; T.E. Johnson; K. Capello; J.E. Pinder III

2014-01-01T23:59:59.000Z

177

Study of the kinetics of the gas-phase, iodine catalyzed elimination of HBr from isobutylbromide: the tertiary C-H bond dissociation energy in isobutylbromide.  

E-Print Network [OSTI]

, (with the possible exception of the very electronegative F atom) unless the substituent can delocalize the odd electron such as with the vinyI substituent, i. e. the allyl radical. The stabi'Iization energy is defined as the difference between... of formation of the radical. f s indicated in section (II); the stabilization energy of bromine bridged radical by the delocalization of tne odd electron can be obtained by comparisior, with a localized free radical. Thus, the stabi11zat1on energy...

Jirustithipong, Pongsiri

2012-06-07T23:59:59.000Z

178

Nucleophilic vinylic substitutions of (Z)-(2-aroyloxyvinyl)phenyl-?3-iodanes with tetrabutylammonium halides: vinylic SN2 reactions and ligand coupling on iodine(III)  

Science Journals Connector (OSTI)

Treatment of (Z)-(?-benzoyloxyvinyl)phenyl-?3-iodanes, readily prepared from ethynyl(phenyl)(tetrafluoroborato)-?3-iodane via stereoselective Michael-type addition of benzoic acids in methanol in the presence of sodium benzoates, with tetrabutylammonium halides in THF at 65C results in a vinylic SN2 reaction to give the inverted (E)-?-benzoyloxyvinyl halides in high yields.

Masahito Ochiai; Yoshio Nishi; Masaya Hirobe

2005-01-01T23:59:59.000Z

179

Physical features of small disperse coal dust fraction transportation and structurization processes in iodine air filters of absorption type in ventilation systems at nuclear power plants  

E-Print Network [OSTI]

The research on the physical features of transportation and structurization processes by the air-dust aerosol in the granular filtering medium with the cylindrical coal adsorbent granules in an air filter of the adsorption type in the heating ventilation and cooling (HVAC) system at the nuclear power plant is completed. The physical origins of the coal dust masses distribution along the absorber with the granular filtering medium with the cylindrical coal granules during the air-dust aerosol intake process in the near the surface layer of absorber are researched. The quantitative technical characteristics of air filtering elements, which have to be considered during the optimization of air filters designs for the application in the ventilation systems at the nuclear power plants, are obtained.

Ledenyov, Oleg P; Poltinin, P Ya; Fedorova, L I

2012-01-01T23:59:59.000Z

180

ABSTRACT:  

Science Journals Connector (OSTI)

......was developed on Ihe around of H similar principle to that of aerial survey and was applied to measurements of the rat and mouse...acid phos- phatase) activity in chicken bone tissues. Osamu Fukushima, Hlroshi Yamashlta and Carol V. Gay Dept.Anat.Jikei Univ......

The Forty-seventh Annual Meeting of the Japanese Society of Electron Microscopy

1991-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "iodine phos phorus" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


181

Effect of Prolactin on Growth and the Estrogen Receptor Level of Human Breast Cancer Cells (MCF-7)  

Science Journals Connector (OSTI)

...enzyme or by the elevation of cAMP phos phodiesterase activity...enzymes such as thymidine kinase. cAMP has been implicated in tumor...Whether the endogenous level of cAMP is related to the effect of...106. New York: Appleton-Century-Crofts, 1971. 8. Godefroi...

Samir Shafie and S. C. Brooks

1977-03-01T23:59:59.000Z

182

The Chemi-Ionization Detector: A Flameless Ionization Detector  

Science Journals Connector (OSTI)

......phos- JOURNAL OF CHROMATOGRAPHIC SCIENCE VOL 8 AUGUST 1970 465 0 0 0 0000000 0 0 O C g 0 0 20 0 CsBr HEATER ON SAMPLE HEATER ON 60 SAMPLE HEATER OFF SAMPLE HEATER ON CsBr HEATER OFF 4 20 24 NAR I RITE VYCOR TUBE 00000000/100000000000 N2......

Martin Scolnick

1970-08-01T23:59:59.000Z

183

A Lipid-modified Phosphoinositide-specific Phospholipase C (TcPI-PLC) Is Involved in Differentiation of Trypomastigotes to  

E-Print Network [OSTI]

A Lipid-modified Phosphoinositide-specific Phospholipase C (TcPI-PLC) Is Involved C (PI- PLC) is an important component of the inositol phos- phate/diacylglycerol signaling pathway. A newly discov- ered Trypanosoma cruzi PI-PLC (TcPI-PLC) is lipid modified in its N terminus, targeted

Singer, Randall

184

Supporting Information Halevy et al. 10.1073/pnas.1109444108  

E-Print Network [OSTI]

and Purification. We performed three stepped phos- phoric acid digestions of gently crushed bulk Allan Hills 84001 (ALH84001) at a temperature of 90 ? 1 °C, each consisting of three digestion steps. The aliquot weights for more than 16 h before being dropped into the acid. The CO2 evolved from acid digestion was continuously

Fischer, Woodward

185

Chemical Geology, 112 ( 1994 ) 91-104 91 Elsevier Science B.V., Amsterdam  

E-Print Network [OSTI]

August 1987 from eight stations along the longitudinal salinity gradient of the Beaulieu River Estuary the effectof salinity, agitation, biological activity, addition of a carbon source and degree of water of changing salinity on phos- 0009-2541/94/$07.00 © 1994 Elsevier Science B.V. All rights reserved. SSDI 0009

Canberra, University of

186

Regulation of the Chlamydomonas Cell Cycle by a Stable, Chromatin-Associated Retinoblastoma Tumor Suppressor Complex  

Science Journals Connector (OSTI)

...blotted to Immobilon-P PVDF membranes (Millipore) in 10 mM Tris, 100 mM Gly, and 10% methanol for 45 min at 400 mA with an Xcel-Blot apparatus (Invitrogen). Phos-Tag gels were incubated for 10 min in transfer buffer with 1 mM EDTA, washed twice...

Bradley J.S.C. Olson; Michael Oberholzer; Yubing Li; James M. Zones; Harjivan S. Kohli; Katerina Bisova; Su-Chiung Fang; Jill Meisenhelder; Tony Hunter; James G. Umen

2010-10-26T23:59:59.000Z

187

Inositol phosphates in the environment  

Science Journals Connector (OSTI)

...the numbering system, the reader is...cereal grains (Wheeler & Ferrel 1971...matter in aquatic systems (Anderson et...a comparative study of the adsorptive...magnetic resonance study of the phos...grassland farming systems in the UK. Soil...L. D. L. Foster & J. A. Dearing...

2002-01-01T23:59:59.000Z

188

The importance of intrinsic disorder for protein phosphorylation  

E-Print Network [OSTI]

The importance of intrinsic disorder for protein phosphorylation Lilia M. Iakoucheva, Predrag-based tool for the prediction of protein phos- phorylation sites, DISPHOS (DISorder-enhanced PHOSphorylation are very similar to those of intrinsically disordered protein regions. Thus, DISPHOS uses position

Radivojac, Predrag

189

17. J. Haywood, The Penguin Historical Atlas of the Vi-kings (Penguin Books, London, 1995).  

E-Print Network [OSTI]

adenine dinucleotide phos- phate. Low micromolar concentrations of carbon monoxide inhibited the DNA binding activity of holo-NPAS2 but not that of apo-NPAS2. Upon exposure to carbon monoxide, inactive BMAL1 heme binding during the purification of NPAS2, a mammali- an bHLH (basic helix-loop-helix)­PAS tran

Rutter, Jared

190

Cholesterol lowering by soya lecithins in the rat in vivo: stimulation of the hepa-  

E-Print Network [OSTI]

of HDL-cholesterol and increase of bile lipid secretion. E Poli-E Poli- chetti N Diaconescu L Malli I You) Gastroenterology 94, A621 ]. The implication of HDL-PC in the bile lipid secretion was also previously shown) containing only 25% pure phos- phatidylcholine (PC). Lecithin stimulates bile secretion [Rioux et al (1988

Paris-Sud XI, Université de

191

Zone Melting  

Science Journals Connector (OSTI)

...four-turn induction coils of water-cooled copper tubing...by introducing a bit of water vapor into the hydrogen...apparatus (6). The water vapor combines with the...indium antimo-nide, gallium arsenide, gallium phos-phide...

W. G. Pfann

1962-03-30T23:59:59.000Z

192

Different central nervous system cell types display distinct and nonrandom arrangements of satellite DNA sequences  

Science Journals Connector (OSTI)

...Digestion was termi- nated by washing sections (3 times for 10 min each) in phos- phate-buffered saline containing 5 mM EDIA, glycine (4 mng/ml), and 0.5 mM phenylmethylsulfonyl fluoride. We also tried several other methods to avoid Pronase...

L Manuelidis

1984-01-01T23:59:59.000Z

193

This is an author-deposited version published in: http://oatao.univ-toulouse.fr/ Eprints ID: 5685  

E-Print Network [OSTI]

electrodes. Then, hydrogen is produced in an electrolytic cell using a phos- phate solution as the catholyte, nuclear, sustainable, etc.). The synthetic fuel mainly considered is hydrogen, which could make up of hydrogen through water electrolysis is performed using aqueous KOH (30%w) at 80 C and applying a cell

Mailhes, Corinne

194

Effect of 1-Methyl-1-nitrosourea on Poly(Adenosine Diphosphate-Ribose) Polymerase Activity at the Nucleosomal Level  

Science Journals Connector (OSTI)

...6000 units/mg) and snake venom phos phodiesterase...from Drug Research and Development Program, National Cancer...that heating at high temperatures does not affect poly...was carried out using snake venom phosphodiestemase...After 15 mm at room temperature, the reaction was stopped...

Swaroop Sudhakar; Kenneth D. Tew; and Mark E. Smulson

1979-04-01T23:59:59.000Z

195

Microchemical systems for singlet oxygen generation  

E-Print Network [OSTI]

Chemical Oxygen-Iodine Lasers (COIL) are a technology of interest for industrial and military audiences. COILs are flowing gas lasers where the gain medium of iodine atoms is collisionally pumped by singlet delta oxygen ...

Hill, Tyrone F. (Tyrone Frank), 1980-

2008-01-01T23:59:59.000Z

196

Experimental: Gel Electrolyte The gel mixtures were designed to be cast as  

E-Print Network [OSTI]

PEDOT:PSS as counter electrode, which demonstrated good Iodine regenerative catalytic activity .[2] www.risoe.dk/solarcells

197

invited Paper CommercialApplications for COIL  

E-Print Network [OSTI]

oxygen-iodine laser (COIL), the University of Illinois at Urbana-Champaign (UIUC)/STI Optronics team

Carroll, David L.

198

Natural Organic Matter (NOM) in Aquatic Systems: Interactions with Radionuclides (234Th (IV), 129 I) and Biofilms  

E-Print Network [OSTI]

in natural waters. At the F-area of the Savannah River Site (SRS), iodine species in the groundwater consisted of 48.8 percent iodide, 27.3 percent iodate and 23.9 percent organo-iodine. Each of these iodine species exhibited vastly different transport...

Zhang, Saijin

2011-10-21T23:59:59.000Z

199

I/I ratios and halogen concentrations in pore waters of the Hydrate Ridge: Relevance for the origin of gas hydrates in ODP Leg 204  

E-Print Network [OSTI]

in fluids associated with hydrocarbons, such as oil field brines (Moran et al., 1995) or coal-bed methane association of iodine with methane allows the identification of the organic source material responsible for iodine and methane in gas hydrates. In all cores, iodine concentrations were found to increase strongly

Fehn, Udo

200

United States Office of Air and Radiation EPA 402-R-04-002C Environmental Protection Agency July 2004  

E-Print Network [OSTI]

and Available Kd Values for Americium, Arsenic, Curium, Iodine, Neptunium, Radium, and Technetium #12;i and Available Kd Values for Americium, Arsenic, Curium, Iodine, Neptunium, Radium, and Technetium July 2004: americium, arsenic, curium, iodine, neptunium, radium, and technetium. This three-volume report also

Note: This page contains sample records for the topic "iodine phos phorus" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


201

Iodized Salt  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Iodized Salt Iodized Salt Name: Theresa Location: N/A Country: N/A Date: N/A Question: Why do they put iodine in salt? Replies: Iodine was introduced into salt at earlier this century when it was discovered that certain areas of the US had a mark deficiency in iodine in the diet of people, and people developed a neck swelling (goiter). The Great Lakes region is one of these areas where the soil is lacking iodine. Goiter can be caused when the thyroid gland swells because of a lack of iodine in the diet. Most medical advise now states that iodine in salt is no longer necessary due to our food sources arising from all over the world. Steve Sample Hi Theresa...see, there are a variety of elements and compounds that are necessary for the proper maintenance of our life. One of these is iodine, since a small quantity of iodine is needed for the adequate functioning of the thyroid gland. A deficiency of iodine produces dire effects, as goiter, where the thyroid gland swollens due to the lack of iodine traces in the diet. The iodine affects directly the tyrhoid gland secretions, which themselves, to a great extent, control heart action, nerve response to stimuli, rate of body growth and metabolism.

202

Hydrothermally Grown Upright-Standing Nanoporous Nanosheets of Iodine-Doped ZnO (ZnO:I) Nanocrystallites for a High-Efficiency Dye-Sensitized Solar Cell  

Science Journals Connector (OSTI)

Nanoporous nanosheets of ZnO and ZnO:I nanocrsytallites were washed with DI water and baked in air at 350 C for 30 min in order to remove any residual organics and optimize solar cell performance. ... The proposed growth process is a simple and low-cost approach for the large scale production of nanomaterials with high conversion efficiency to fabricate DSSCs and hybrid solar cells. ... This method is also anticipated to be equally applicable to other semiconductor photoelectrodes in DSSCs and organicinorganic hybrid solar cells. ...

Khalid Mahmood; Hyun Wook Kang; Seung Bin Park; Hyung Jin Sung

2013-03-19T23:59:59.000Z

203

Proceedings of the International Conference on Lasers '98, ed. V.J. Corcoran, STS Press, McLean VA, 1999, in press. PERFORMANCE OF A HIGH POWER CHEMICAL OXYGEN-IODINE LASER  

E-Print Network [OSTI]

, IL 61801 C.H. Fisher STI Optronics, 2755 Northup Way Bellevue, WA 98004-1495 Abstract The Verti-Champaign (UIUC)/STI Optronics team identified the decommissioning and decontamination (D&D) of nuclear facilities

Carroll, David L.

204

Organic Phosphoric Acid of the Soil.  

E-Print Network [OSTI]

TEXAS AGRICULTURAL EXPERIMENT STATIONS BULLETIN NO. +6CT /36 CHEMICAL SECTION, FEBRUARY, 191 1 I TECHNICAL BULLETIN Organic Phosphoric Acid of the Soil BY G. S. FRAPS, Chemist POSTOFFICE College Station, Brazos County, 'Texas. ,\\ustin... . ................................................ introduction 5 .............................. hmmonia-Soluble Phosphoric Acid 5 ................ Solubility of Phosphates in Ammonia 6 I Fixation of Phosphoric Acid from Ammonia .......... 7 Effect of Ratio of Soil to Solvent in Extraction of Phos- I I...

Fraps, G. S. (George Stronach)

1911-01-01T23:59:59.000Z

205

Control of the activity and synthesis of aspartate transcarbamylase in Aerobacter aerogenes  

E-Print Network [OSTI]

, uridine; CMP, cytidine-5'-monophosphate; CTP, cytidine-5'- triphosphate; UMP, uridine-5'-monophosphate; udp, uridine-phos- phorylase. INTRODUCTION In an endeavor to ascribe possible taxonomic and evolutionary relationships between organisms... the concentration -3 of carbamyl phosphate from an original concentration of 5 x 10 N -4 to a lower concentration of 5 x 10 M greater inhibition was observed by CMP and UMP. The triphosphates were then examined and -3 it was found that CTP (5 x 10 M) inhibited...

Deutsch, Walter Andrew

2012-06-07T23:59:59.000Z

206

Nitrification Capacities of Texas Soil Types and Factors which Affect Nitrification.  

E-Print Network [OSTI]

, the test was repeated n-ith the use of normal nitric acid. Basicity is expressed in terms of percentage of calcium carbonate. The acid was neutralized chiefly by calcium derived from calcium carbonate, if present, from calcium in the base exchange... to neutralize the nitric and sulphuric acids pro- duced, or of both. .4 few soils needed additions of available phos- phates for high nitrification (35) and there was a small percentage left which still did not nitrify the ammonium sulphate completely...

Sterges, A. J.; Fraps, G S. (George Stronach)

1947-01-01T23:59:59.000Z

207

The interaction of nitrogen and magnesium deficiences in certain aspects of the physiology of the cotton plant  

E-Print Network [OSTI]

effective in raising the phos- phorous content of peas. Their results support the theory that magnesium functions as a carrier of phosphorous. They also point out the need of giving more attention to the magnesium status of agricultural soils with a view... and magnesium deficiencies occurring in the same plant as developed under the experimental conditions stated above. Oftentimes poor growth of plants in the field may result from the lack of two or mox'e nutrients and such simultaneous characterization...

Ghosh, Debabrata

2012-06-07T23:59:59.000Z

208

The Active Potash of the Soil and Its Relation to Pot Experiments.  

E-Print Network [OSTI]

agreed with field tests on clay soils but not other types of soils (12). Moore (4) compares the quantity of potash and phos extracted from the soil by dilute acids, with the quanti by crops from the soil, regardless of the deficiencies of t any... ------------, Lufkin sand, subsoil Houston black clay -------------- Houston black clay --------------- Houston black clay --------------- Houston black clay ,-------------- Houston black clay --------------- July 20-September 8 --------------- July 20-September...

Fraps, G. S. (George Stronach)

1912-01-01T23:59:59.000Z

209

Energy (Cost) Savings by Zero Discharge in Cooling Towers  

E-Print Network [OSTI]

. Relatively clean water may be added directly to the cooling tower basin (see Figure n. Reuse streams containing high suspended solids but of otherwise acceptable quality may be input just before the filters ~n the J The remainingireuse The flowrate..., silica, phos phates, and suspended solids. Other potential foulants and scale-forming species must be controlled by inhibitors or removed by an additional process in the sidestream treatment. Waste streams with scaling and corrosion potential before...

Matson, J. V.; Gardiner, W. M.; Harris, T. G.; Puckorius, P. R.

1982-01-01T23:59:59.000Z

210

WHO Guidelines on Hand Hygiene in Health Care  

E-Print Network [OSTI]

.6 Hexachlorophene 11.7 Iodine and iodophors 11.8 Quaternary ammonium compounds 11.9 Triclosan 11.10 Other agents 11

Kim, Duck O.

211

E-Print Network 3.0 - age-dependent radium retention Sample Search...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Protection Agency July 2004 Summary: and Available Kd Values for Americium, Arsenic, Curium, Iodine, Neptunium, Radium, and Technetium 12;i... and Available Kd Values for...

212

HELSINKI UNIVERSITY OF TECHNOLOGY ENE-47.153 Halogens, dioxins/Halogens, dioxins/furansfurans  

E-Print Network [OSTI]

OrimulsionTM ~700 Petroleum coke, "petcoke" ~ 300 Natural gas - * Iodine 0.5 - 1.5 mg/kg #12;HELSINKI

Zevenhoven, Ron

213

Biofortifying Brassica with calcium (Ca) and magnesium (Mg)  

E-Print Network [OSTI]

zinc, copper, calcium, magnesium, selenium and iodine. NewE. 2008. Role of dietary magnesium in cardiovascular diseaseShoot calcium (Ca) and magnesium (Mg) concentrations differ

2009-01-01T23:59:59.000Z

214

EMSL - solids  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

solids en Iodine Solubility in Low-Activity Waste Borosilicate Glass at 1000 C. http:www.emsl.pnl.govemslwebpublicationsiodine-solubility-low-activity-waste-borosilicate-...

215

EMSL - liquids  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

liquids en Iodine Solubility in Low-Activity Waste Borosilicate Glass at 1000 C. http:www.emsl.pnl.govemslwebpublicationsiodine-solubility-low-activity-waste-borosilicate...

216

PART THREE REMEDIAL AND CORRECTIVE ACTIONS ARTICLE XIII. FINDINGS...  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

substances, including chromium, strontium-90, tritium, iodine-129, uranium, cyanide, carbon tetrachloride, nitrates, and technetium-99 have been detected in the groundwater...

217

Slide 1  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

(Reduction of Tc-99 is potentially reversible) Iodine-129 Nitrate Hexavalent Chromium Carbon Tetrachloride HNF-49889-VA Technology - In Situ Vitrification General Description *...

218

The effects of 20-hydroxyecdysone on cell surface proteins and cell interactions in Drosophila melanogaster cell lines  

E-Print Network [OSTI]

]-N-Acetylglucosamine 3 Immunoprecipitation with Disc Membrane Antiserum Lectin Affinity Chromatography 12 12 24 27 32 IV DISCUSSION AND CONCLUSIONS 40 REFERENCES 49 VITA 54 V1 LIST OF FIGURES FIGURE Page 1 7. 5% SDS- PAGE of NP-40 extracts of iodinated S3... cells. . . 14 2 7. 5%, SDS-PAGE of NP-40 extracts of iodinated L3 cells. 16 3 Two-dimensional gels of NP-40 extracts of iodinated S3 cells. 19 4 Two-dimensional gels of NP-40 extracts of iodinated L3 cells. 21 5 Two-dimensional gel of the acidic...

Stachowiak, Janice Ann

2012-06-07T23:59:59.000Z

219

Analytical Data Report of Water Samples Collected For I-129 Analysis  

SciTech Connect (OSTI)

This is an analytical data report for samples received from the central plateau contractor. The samples were analyzed for iodine-129.

Lindberg, Michael J.

2009-10-26T23:59:59.000Z

220

Commercial Fertilizers and Poisonous Insecticides in 1906-7.  

E-Print Network [OSTI]

used in Texas is comparatively small. The amount is increasing and may be expected to increase yearly. The quantity sold in Texas in 1905-06 was 13,500 tons. In 1906-07 it was 19,200 tons, this being an increase of 42 per cent. This does not in... to the soil in such forms that the plant can take it up easily. It thus supplements the avail- able plant food of the soil and increases the crop if the soil does not provide enough plant food. The essential constituents of a fertilizer are phos- phoric...

Fraps, G. S. (George Stronach)

1907-01-01T23:59:59.000Z

Note: This page contains sample records for the topic "iodine phos phorus" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


221

Nature and Use of Commercial Fertilizers.  

E-Print Network [OSTI]

on the Texas market. Formula 1.8-2-2 Fertilizer. This fertilizer contains 8 per cent available phosphoric acicl, 2 per cent potash and 1.65 per cent nitrogen. It may be prepared by mixing the following ingredients : ............. Acid phosphate, 14 per... phosphoric acid is rorth $1.00 per 100 pounds, the 14 per cent acid phosphate is worth $1.17 per 100 pounds, or very nearly 20 per cent more. Thus the consumer who purchases 14 per cent of acid phos- phate, when both I2 and 14 per cent are selling a...

Fraps, G. S. (George Stronach)

1908-01-01T23:59:59.000Z

222

The Soils of Eastland, El Paso, Lubbock and San Saba Counties.  

E-Print Network [OSTI]

foods in the soil. example, with the Caddo fine sandy loam of Camp county, the corn possibility for active phosphoric acid is 18, for the active potash 80, and for total nitrogen 23. The soil is probably deficient first in phos- phoric acid..., and vegetables are also produced as well as live stock. Table 4 contains the acreage and percentage of some of the types of soils which occur in Eastland county. Sixteen types were mapped and grouped into seven series. The Windthorst fine sandy loam occupies...

Fraps, G. S. (George Stronach)

1926-01-01T23:59:59.000Z

223

MODELLING RADIOIODINE DYNAMICS Modelling the Dynamics of Radioiodine in Dairy Cows  

E-Print Network [OSTI]

Department of Physiology & Environmental Science University of Nottingham Sutton Bonington LE12 5RD UK G for significant fecal excretion of radioiodine. The5 model is used to consider the effect of dietary stable iodine of iodine, in particular I-131, are important components in fallout from2 nuclear accidents

Crout, Neil

224

"Thyroid Disorders" Deaf Health Talks  

E-Print Network [OSTI]

gland to function and make thyroid hormones Naturally occurs in soil and ocean 40% of people in world on the thyroid C. Radiation exposure D. Lack of iodine E. Alien snatching our thyroid glands #12;What is the most itself on the thyroid C. Radiation exposure D. Lack of iodine E. Alien snatching our thyroid glands #12

Goldman, Steven A.

225

O R E G O N of the Hanford Thyroid Disease Study  

E-Print Network [OSTI]

to provide the necessary data for evaluation of thyroid disease and estimation of radiation dose. Data of Hanford's iodine-131, researchers studied a group of people with a wide range of radiation doses or consumed in contaminated food. Iodine-131 was the primary source of radiation for many people exposed

226

Missile Defense Rides Again  

Science Journals Connector (OSTI)

...oxygen-iodine laser mounted in the nose of a Boeing 747. Although such systems were heavily...and program manager for the NMD team at Boeing Co. which last April won a $1.6 billion...oxygen-iodine laser mounted in the nose of a Boeing 747. Although such systems were heavily...

James Glanz

1999-04-16T23:59:59.000Z

227

JOURNALDE PHYSIQUE IV ColloqueC7,supplt5ment au Journalde Physique111,Vol, 1,dkembre 1991  

E-Print Network [OSTI]

], and it is utilized for studies of laser nuclear fusion, X-lay lasers, and other plasma physics[2][3] such as glass-ku, Yokohama223,Japan ABSTRACT : A pulsed iodine laser driven by a chemical oxygen generator was developed is same as the conventional Chemically pumped Oxygen-Iodine Lasers (COIL), it is unique in that the pulsed

Boyer, Edmond

228

Application of modeling of the texture dependence of environmentally assisted crack growth of long and short cracks to ZIRCALOY fuel tubing  

SciTech Connect (OSTI)

Argon and iodine stress-rupture tests were performed on five lots of ZIRCALOY-4 tubing with relatively large differences in texture. The addition of iodine relative to argon decreases the failure time. The iodine data exhibited increasing failure times with decreasing stress until a plateau or threshold stress level was reached. The threshold stress was used to evaluate a model developed from fracture mechanics crack propagation data. Modification of this model was necessary in order to account for tubing texture, tubing fracture surface characteristics, test temperature, and the embrittling effect of iodine. The adjusted model predicts that moderate increases in the iodine threshold stress may be obtained with very low tangential texture tubing.

Foster, J.P.; Comstock, R.J. (Westinghouse Electric Corp., Pittsburgh, PA (USA). Research and Development Center)

1989-10-01T23:59:59.000Z

229

Model for the transport of airborne radioiodine  

SciTech Connect (OSTI)

Gaseous iodine deposits on surfaces exposed to the vapors. The industry has observed gaseous iodine transport behavior for years, and groups have proposed models describing the phenomena with limited success. The transport models attempt to describe the complicated chemical processes in terms of empirical rate constants. The current model, also empirical, treats deposition, conversion, and resuspension along a path of short segments where the assumption of instantaneous and homogeneous mixing is adequate, passing on the results as input to the next segment. The number of segments depends on line and flow parameters and can be as many as 100,000 for a long, large-diameter pipe with low flow. It includes a chemical bonding reaction rate to iodine deposited on the surface. The model has five compartments in each segment: concentrations of the three airborne iodine species, surface activity available for resuspension, and reacted surface iodine that is fixed on the surface. All iodine in the segment undergoes radioactive decay. The calculation divides the time period into small time division, typically 100, where the assumption of instantaneous equilibrium is applicable. The model initially developed by Science Applications International describes deposition, resuspension, and conversion of iodine in four differential equations that describe, respectively, airborne elemental, HOI and organic, and surface activities.

Cline, J.E.

1991-11-01T23:59:59.000Z

230

Influence of surface passivation on the minority carrier lifetime, Fe-B pair density and recombination center concentration  

Science Journals Connector (OSTI)

Three kinds of methods (0.08 mol/L iodine in ethanol, SiN x :H, and 40% HF) are used to passivate solar-grade Czochralski (Cz) silicon wafers. Thereafter, minority carrier lifeti...

Feng Li; ZhongQuan Ma; XiaJie Meng; Peng L; ZhengShan Yu

2010-06-01T23:59:59.000Z

231

Assessing beef hide interventions as a means to reduce carcass contamination  

E-Print Network [OSTI]

following a water wash. Treatments (distilled water, isopropyl alcohol, 3% hydrogen peroxide, 2% L-lactic acid, 1% cetylpyridinium chloride (CPC), and 10% Povidone-iodine) then were applied to each section and sampled for aerobic plate counts (APCs...

Baird, Bridget Elaine

2007-04-25T23:59:59.000Z

232

I-XE ANALYSES OF TAGISH LAKE MAGNETITE AND MONAHANS HALITE. A. Busfield1 , J. D. Gil-  

E-Print Network [OSTI]

- leases were dominated by iodine-derived xenon (129 Xe/132 Xe > 10 consistently). This sample produced of solar sys- tem history. Acknowledgements: We are grateful to R. Wieler for providing the halite grain

Grossman, Lawrence

233

Radiation Protection at Light Water Reactors  

Science Journals Connector (OSTI)

......refers primarily to US regulatory guidelines (e.g...worker monitoring. Regulatory limits such as contamination...appropriate references to regulatory guidelines for these...monitoring sections review particulate, radio-iodine...permits, ALARA work plans and scaffold management......

Ken Veinot

2013-11-01T23:59:59.000Z

234

!""#$%&'()*+,-#.',&"*/'-0*12!*,"*-0#*34'5#* 6,(,5'*7&#'$,(**  

E-Print Network [OSTI]

-'-F*@$ O O OH PO NC ABz O O O O O GiBu O O O ODMT P NONC T tetrazole then iodine O O O PO NC ABz O O O O O

Barthelat, Francois

235

DOCTORATES CONFERRED BY AMERICAN UNIVERSITIES  

Science Journals Connector (OSTI)

...Siceloff: " Simple Groups from Order 2001 to order 3640." Benjamin Roy Simpson: "Correlation of Mental Abilities. " Bertram...Photo-electric Properties of Vapors of Alkali Metals. ' Stuart Jeffery Bates: "The Iodine Coulometer and the Value of the Faraday...

1912-08-02T23:59:59.000Z

236

SciTech Connect: Deep Bed Adsorption Testing using Silver-Functionaliz...  

Office of Scientific and Technical Information (OSTI)

transfer zone may be as short as 0.5 inches under the sorption conditions of the first test. Only a small fraction of the iodine sorbed on Bed 1 was desorbed during the purge...

237

Phorochrriii\\rn. und Phofuhiologr. Vol. 29. pp. 439-444. Pergamon Press Ltd. 1979. Printed in Great Britain  

E-Print Network [OSTI]

of the spectroscopy of iodine. nitrogen dioxide, s-tetrazine and various van der Waals molecular complexes molecule like s-tetrazine is effectively "frozen" out giving one of the few highly resolved gas phase

Govindjee

238

Rapid determination of trace concentrations of lead in gasoline by anodic stripping voltammetry  

Science Journals Connector (OSTI)

Anodic stripping voltammetry can be used for the determination of ?g/l concentrations of lead in gasoline. A gasoline sample is extracted with iodine monochloride reagent solution. An aliquot of the aqueous ph...

Pentti Laukkanen

239

Examination of offsite radiological emergency protective measures for nuclear reactor accidents involving core melt  

E-Print Network [OSTI]

Evacuation, sheltering followed by population relocation, and iodine prophylaxis are evaluated as offsite public protective measures in response to nuclear reactor accidents involving core-melt. Evaluations were conducted ...

Aldrich, David C.

1979-01-01T23:59:59.000Z

240

Comparison of enrichment techniques for the isolation of Salmonella sp. from swine feces  

E-Print Network [OSTI]

seven comparative techniques for isolation. A standard protocol, consisting of xylose lysine tergitol-4 agar (XLT4) paired with a primary enrichment in tetrathionate broth with iodine (TTH) and secondary enrichment in Rappaport-Vassiliadis R10 broth (RV...

Andrews, Kimberley Denise

2012-06-07T23:59:59.000Z

Note: This page contains sample records for the topic "iodine phos phorus" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


241

PROGRAM & ABSTRACTS 13. DANSKE HAVFORSKERMDE  

E-Print Network [OSTI]

Department, DK-4000 Roskilde 129 I (15.7 Ma) is a naturally occurring radioisotope of iodine. The ratio as A Oceanographic Tracer Xiaolin Hou, H. Dahlgaard, S.P. Nielsen Risø National Laboratory, Radiation Research

242

Combinatorial design and synthesis of peptidomimics and small molecules for protein-protein interactions  

E-Print Network [OSTI]

pharmacophores and to adjust the solubilities of the products. The fluorinated template also gave libraries of cyclic peptidomimetics on solid phase in good yields and purities. These libraries have improved water solubility over the iodinated libraries. The 3...

Park, Chihyo

2007-04-25T23:59:59.000Z

243

Potential application of Zircaloy chemical embrittlement to volume reduction of spent-fuel cladding  

SciTech Connect (OSTI)

Embrittlement of Zircaloy fuel cladding tubes by corrosion media was studied from the viewpoint of its applicability to spent-fuel reprocessing. The results from irradiated as well as unirradiated tubes are summarized as follows: (1) when iodine was employed as the solute, the use of methanol as the solvent caused significant embrittlement of the Zircaloy; (2) for the iodine-methanol solution, the embrittlement increased with the iodine content but saturated at 1 wt%; (3) a water content of up to 10 vol% in the iodine-methanol solution did not decrease the extent of embrittlement; (4) fracture was of the grain-boundary type, and a fuel cladding tube irradiated to [approximately] 35GWd/t showed the same embrittlement behavior as an unirradiated one.

Nakatsuka, Masafumi (Nippon Nuclear Fuel Development Co., Ltd., Ibaraki (Japan))

1993-09-01T23:59:59.000Z

244

Centers for Disease Control and Prevention National Center for Environmental Health  

E-Print Network [OSTI]

, Idaho and Oregon; the scientific and academic communities; and the media. This communications plan............................................................................. 18 National Scientific and Academic Communities 12 years of scientific research on the human health effects of iodine-131 released in the 1940s

245

RESULTS OF FIRST EXPERIMENTS ON NEUTRON GENERATION IN THE VITA NEUTRON SOURCE  

E-Print Network [OSTI]

as activation detector due to capture of epithermal neutrons by iodine also. Bubble detectors were used shell and reliably protected from magnetic fields and electromagnetic noises. Stability of the power

Taskaev, Sergey Yur'evich

246

For Immediate release: 04/12/12 Contact: Ingrid Wright  

E-Print Network [OSTI]

. Hydrogen generators can serve as effective hydrogen storage systems for fuel cells and other applications, hydrogen, and iodine-containing gas species. Oxygen generators can produce more oxygen, show higher

Ward, Karen

247

environmental | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

leads are available at this time. Iodine Solubility in Low-Activity Waste Borosilicate Glass at 1000 C. Abstract: The purpose of this study was to determine the solubility of...

248

liquids | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

leads are available at this time. Iodine Solubility in Low-Activity Waste Borosilicate Glass at 1000 C. Abstract: The purpose of this study was to determine the solubility of...

249

solids | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

leads are available at this time. Iodine Solubility in Low-Activity Waste Borosilicate Glass at 1000 C. Abstract: The purpose of this study was to determine the solubility of...

250

cation migration | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

leads are available at this time. Iodine Solubility in Low-Activity Waste Borosilicate Glass at 1000 C. Abstract: The purpose of this study was to determine the solubility of...

251

Imaging | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

leads are available at this time. Iodine Solubility in Low-Activity Waste Borosilicate Glass at 1000 C. Abstract: The purpose of this study was to determine the solubility of...

252

quadrupolar nuclei | EMSL  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

leads are available at this time. Iodine Solubility in Low-Activity Waste Borosilicate Glass at 1000 C. Abstract: The purpose of this study was to determine the solubility of...

253

Laser development for laser fusion applications. Research progress report, October 1978-September 1979  

SciTech Connect (OSTI)

During this report period, emphasis has been directed toward the advanced development of the HF, KrF, Se(/sup 1/S)-Se(/sup 3/P), and the chemically pumped iodine laser systems.

Not Available

1980-05-01T23:59:59.000Z

254

Evidence for a receptor for ceruloplasmin on chick aortic and heart cell membranes  

E-Print Network [OSTI]

OF TABLES LIST OF FIGURES. INTRODUCTION MATERIALS AND METHODS. page Vl Vl1 Viii 1. X Animals Preparation of Aortic and Heart Membranes Purification of Chick Ceruloplasmin Iodination of Ceruloplasmin Binding Studies Purification of Glycoproteins... Preparation of Asialoglycoprotein RESULTS. 7 7 8 9 10 11 12 13 Membrane Preparation. Purification of Chick Ceruloplasmin Iodination of Ceruloplasmin Binding Studies Characterization of the Receptor. DISCUSSION REFERENCES VITA 13 13 22 22...

Stevens, Michael Duane

1982-01-01T23:59:59.000Z

255

Study of the neutral mesons in Pb-Pb collisions at $\\sqrt{s_{NN}}$ = 2.76 TeV in the ALICE experiment at LHC  

E-Print Network [OSTI]

The $\\pi^{0}$ and $\\eta$ meson production in Pb-Pb collisions at $\\sqrt{s_{NN}}$ = 2.76 TeV is studied with the ALICE experiment at the LHC. The $\\pi^{0}$ invariant yields and nuclear modification factor $R_{\\mbox{AA}}$ are presented here in six centrality classes. The results are a combined measurement using the Photon Conversion Method (PCM) and the PHOS detector, in the transverse momentum range 0.4 $< p_{\\mbox{T}} <$ 12 GeV/$c$. The $\\pi^{0}$ $R_{\\mbox{AA}}$ is studied in different centrality classes and compared with results from experiments at lower energies, both as a function of transverse momentum. The $\\eta$ meson production is studied using the PCM and the EMCal detector. The combination of the individual results will make possible the measurement of the $\\eta$ differential invariant cross section as a function of transverse momentum from 1 to 22 GeV/$c$ in different centrality classes.

Lucia Leardini; for the ALICE Collaboration

2014-12-05T23:59:59.000Z

256

Hippocampal phosphoproteomics of F344 rats exposed to 1-bromopropane  

Science Journals Connector (OSTI)

Abstract 1-Bromopropane (1-BP) is neurotoxic in both experimental animals and human. To identify phosphorylated modification on the unrecognized post-translational modifications of proteins and investigate their role in 1-BP-induced neurotoxicity, changes in hippocampal phosphoprotein expression levels were analyzed quantitatively in male F344 rats exposed to 1-BP inhalation at 0, 400, or 1000ppm for 8h/day for 1 or 4weeks. Hippocampal protein extracts were analyzed qualitatively and quantitatively by Pro-Q Diamond gel staining and SYPRO Ruby staining coupled with two-dimensional difference in gel electrophoresis (2D-DIGE), respectively, as well as by matrix-assisted laser-desorption ionization time-of-flight (MALDI-TOF) mass spectrometry (MS) to identify phosphoproteins. Changes in selected proteins were further confirmed by Manganese II (Mn2+)-Phos-tag SDS-polyacrylamide gel electrophoresis (SDS-PAGE). Bax and cytochrome c protein levels were determined by western blotting. Pro-Q Diamond gel staining combined with 2D-DIGE identified 26 phosphoprotein spots (p<0.05), and MALDI-TOF/MS identified 18 up-regulated proteins and 8 down-regulated proteins. These proteins are involved in the biological process of response to stimuli, metabolic processes, and apoptosis signaling. Changes in the expression of phosphorylated 14-3-3 ? were further confirmed by Mn2+-Phos-tag SDS-PAGE. Western blotting showed overexpression of Bax protein in the mitochondria with down-regulation in the cytoplasm, whereas cytochrome c expression was high in the cytoplasm but low in the mitochondria after 1-BP exposure. Our results suggest that the pathogenesis of 1-BP-induced hippocampal damage involves inhibition of antiapoptosis process. Phosphoproteins identified in this study can potentially serve as biomarkers for 1-BP-induced neurotoxicity.

Zhenlie Huang; Sahoko Ichihara; Shinji Oikawa; Jie Chang; Lingyi Zhang; Shijie Hu; Hanlin Huang; Gaku Ichihara

2014-01-01T23:59:59.000Z

257

Reaccin con borohidruro de sodio de 3, 3-etiln-bis (3,4-dihidro-6-halo-sustituido-2h-1,3-benzoxazina) donde halo es: flor, cloro, bromo y yodo / Reaction with sodium borohydride of 3, 3-etylene-bis (3,4-dihydro-6-halo-substituted-2h-1,3-benzoxazine) where halo is: fluorine, chlorine, bromine and iodine .  

E-Print Network [OSTI]

??Rojas Salgado, Jicli Jos (2010) Reaccin con borohidruro de sodio de 3, 3-etiln-bis (3,4-dihidro-6-halo-sustituido-2h-1,3-benzoxazina) donde halo es: flor, cloro, bromo y yodo / Reaction with (more)

Rojas Salgado, Jicli Jos

2010-01-01T23:59:59.000Z

258

Complete Phase I Tests As Described in the Multi-lab Test Plan for the Evaluation of CH3I Adsorption on AgZ  

SciTech Connect (OSTI)

Silver-exchanged mordenite (AgZ) has been identified as a potential sorbent for iodine present in the off-gas streams of a used nuclear fuel reprocessing facility. In such a facility, both elemental and organic forms of iodine are released from the dissolver in gaseous form. These species of iodine must be captured with high efficiency for a facility to avoid radioactive iodine release above regulatory limits in the gaseous effluent of the plant. Studies completed at Idaho National Laboratory (INL) examined the adsorption of organic iodine in the form of CH3I by AgZ. Upon breakthrough of the feed gas through the sorbent bed, elemental iodine was observed in the effluent stream, despite the fact that the only source of iodine in the system was the CH3I in the feed gas.1 This behavior does not appear to have been reported previously nor has it been independently confirmed. Thus, as a result of these prior studies, multiple knowledge gaps relating to the adsorption of CH3I by AgZ were identified, and a multi-lab test plan, including Oak Ridge National Laboratory (ORNL), INL, Pacific Northwest National Laboratory (PNNL), and Sandia National Laboratories, was formulated to address each in a systematic way.2 For this report, the scope of work for ORNL was further narrowed to three thin-bed experiments that would characterize CH3I adsorption onto AgZ in the presence of water, NO, and NO2. Completion of these three-thin bed experiments demonstrated that organic iodine in the form of CH3I was adsorbed by reduced silver mordenite (Ag0Z) to a 50% higher loading than that of I2 when adsorbed from a dry air stream. Adsorption curves suggest different adsorption mechanisms for I2 and CH3I. In the presence of NO and NO2 gas, the loading of CH3I onto Ag0Z is suppressed and may be reversible. Further, the presence of NO and NO2 gas appears to oxidize CH3I to I2; this is indicated by an adsorption curve similar to that of I2 on Ag0Z. Finally, the loss of organic iodine loading capacity by Ag0Z in the presence of NOx is unaffected by the addition of water vapor to the gas stream; no marked additional loss in capacity or retention was observed.

Bruffey, S. H. [ORNL; Jubin, R. T. [ORNL

2014-09-30T23:59:59.000Z

259

Silver-Mordenite for Radiologic Gas Capture from Complex Streams: Dual Catalytic CH3I Decomposition and I Confinement  

SciTech Connect (OSTI)

The effective capture and storage of radiological iodine (129I) remains a strong concern for safe nuclear waste storage and safe nuclear energy. Silver-containing mordenite (MOR) is a longstanding benchmark for iodine capture. In nuclear fuel reprocessing scenarios, complex gas streams will be present and the need for high selectivity of all iodine containing compounds is of the utmost importance for safety and the environment. In particular, a molecular level understanding of the sorption of organic iodine compounds is not well understood. Here we probe the structure and distribution of methyl iodide sorbed by silver-containing MOR using a combination of crystallographic and materials characterization techniques including: infrared spectroscopy, thermogravimetric analysis with mass spectrometry, Micro-X-ray Fluorescence, powder X-ray diffraction analysis, and pair distribution function analysis. The iodine is captured inside the MOR pore in the form of AgI nanoparticles, that is consistent with the pores sizes of the MOR, indicating that the molecule is both physically and chemically captured in the Ag-MOR. The organic component is surface catalyzed by the zeolite via the formation of Surface Methoxy Species (SMS) that result in downstream organics of dimethyl ether and methanol formation.

Tina M. Nenoff; Mark Rodriguez; Nick Soelberg; Karena W. Chapman

2014-12-01T23:59:59.000Z

260

Development of low level liquid waste treatment systems: April-September 1981  

SciTech Connect (OSTI)

The pilot plant reverse osmosis system was demonstrated to be effective in removing large percentages of cobalt-60, iodine-125, and a mixture of cesium-137, cobalt-60, and iodine-125 from two types of aqueous streams. The effectiveness of three membrane porosities, 0, 50, and 97% salt rejection, were explored with each isotope. The 97% salt rejection membrane was the most effective in each experiment. Removals as high as 97.5% of the cobalt, 92.9% of the iodine and 95.1% of the combined isotopes were achieved. The effect of possibly interfering factors on the adsorbence of cobalt-60 and iodine-129 on selected ion exchange resins were investigated. The factors thought to affect cobalt-60 adsorption were (OH/sup -/), (NH/sub 4//sup +/), and (SO/sub 3//sup =/). None of the seven factors investigated had any effect on iodine-129 adsorption. Cesium-137 was removed from a 4600-gal aqueous waste containing a large amount of sodium hydroxide by treatment with sodium tetraphenyl boron. The cesium concentration of the supernatant portion was reduced from 570 to 4 counts/min/ml.

Williams, M.K.; Colvin, C.M.; Bond, W.H.

1982-03-05T23:59:59.000Z

Note: This page contains sample records for the topic "iodine phos phorus" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


261

Halogenated sulfidohydroboranes for nuclear medicine and boron neutron capture therapy  

DOE Patents [OSTI]

A method for performing boron neutron capture therapy for the treatment of tumors is disclosed. The method includes administering to a patient an iodinated sulfidohydroborane, a boron-10-containing compound. The site of the tumor is localized by visualizing the increased concentration of the iodine labelled compound at the tumor. The targeted tumor is then irradiated with a beam of neutrons having an energy distribution effective for neutron capture. Destruction of the tumor occurs due to high LET particle irradiation of the tissue secondary to the incident neutrons being captured by the boron-10 nuclei. Iodinated sulfidohydroboranes are disclosed which are especially suitable for the method of the invention. In a preferred embodiment, a compound having the formula Na.sub.4 B.sub.12 I.sub.11 SSB.sub.12 I.sub.11, or another pharmaceutically acceptable salt of the compound, may be administered to a cancer patient for boron neutron capture therapy.

Miura, Michiko (Hampton Bays, NY); Slatkin, Daniel N. (Southold, NY)

1997-03-18T23:59:59.000Z

262

Halogenated sulfidohydroboranes for nuclear medicine and boron neutron capture therapy  

DOE Patents [OSTI]

A method for performing boron neutron capture therapy for the treatment of tumors is disclosed. The method includes administering to a patient an iodinated sulfidohydroborane, a boron-10-containing compound. The site of the tumor is localized by visualizing the increased concentration of the iodine labelled compound at the tumor. The targeted tumor is then irradiated with a beam of neutrons having an energy distribution effective for neutron capture. Destruction of the tumor occurs due to high LET particle irradiation of the tissue secondary to the incident neutrons being captured by the boron-10 nuclei. Iodinated sulfidohydroboranes are disclosed which are especially suitable for the method of the invention. In a preferred embodiment, a compound having the formula Na{sub 4}B{sub 12}I{sub 11}SSB{sub 12}I{sub 11}, or another pharmaceutically acceptable salt of the compound, may be administered to a cancer patient for boron neutron capture therapy. 1 fig.

Miura, M.; Slatkin, D.N.

1997-03-18T23:59:59.000Z

263

Halogenated sulfidohydroboranes for nuclear medicine and boron neutron capture therapy  

DOE Patents [OSTI]

A method for performing boron neutron capture therapy for the treatment of tumors is disclosed. The method includes administering to a patient an iodinated sulfidohydroborane, a boron-10-containing compound. The site of the tumor is localized by visualizing the increased concentration of the iodine labelled compound at the tumor. The targeted tumor is then irradiated with a beam of neutrons having an energy distribution effective for neutron capture. Destruction of the tumor occurs due to high LET particle irradiation of the tissue secondary to the incident neutrons being captured by the boron-10 nuclei. Iodinated sulfidohydroboranes are disclosed which are especially suitable for the method of the invention. In a preferred embodiment, a compound having the formula Na.sub.4 B.sub.12 I.sub.11 SSB.sub.12 I.sub.11, or another pharmaceutically acceptable salt of the compound, may be administered to a cancer patient for boron neutron capture therapy.

Miura, Michiko (Hampton Bays, NY); Slatkin, Daniel N. (Southold, NY)

1995-10-03T23:59:59.000Z

264

Halogenated sulfidohydroboranes for nuclear medicine and boron neutron capture therapy  

DOE Patents [OSTI]

A method for performing boron neutron capture therapy for the treatment of tumors is disclosed. The method includes administering to a patient an iodinated sulfidohydroborane, a boron-10-containing compound. The site of the tumor is localized by visualizing the increased concentration of the iodine labelled compound at the tumor. The targeted tumor is then irradiated with a beam of neutrons having an energy distribution effective for neutron capture. Destruction of the tumor occurs due to high LET particle irradiation of the tissue secondary to the incident neutrons being captured by the boron-10 nuclei. Iodinated sulfidohydroboranes are disclosed which are especially suitable for the method of the invention. In a preferred embodiment, a compound having the formula Na{sub 4}B{sub 12}I{sub 11}SSB{sub 12}I{sub 11}, or another pharmaceutically acceptable salt of the compound, may be administered to a cancer patient for boron neutron capture therapy. 1 fig.

Miura, M.; Slatkin, D.N.

1997-08-05T23:59:59.000Z

265

Halogenated sulfidohydroboranes for nuclear medicine and boron neutron capture therapy  

DOE Patents [OSTI]

A method for performing boron neutron capture therapy for the treatment of tumors is disclosed. The method includes administering to a patient an iodinated sulfidohydroborane, a boron-10-containing compound. The site of the tumor is localized. by visualizing the increased concentration of the iodine labelled compound at the tumor. The targeted tumor is then irradiated with a beam of neutrons having an energy distribution effective for neutron capture. Destruction of the tumor occurs due to high LET particle irradiation of the tissue secondary to the incident neutrons being captured by the boron-10 nuclei. Iodinated sulfidohydroboranes are disclosed which are especially suitable for the method of the invention. In a preferred embodiment, a compound having the formula Na.sub.4 B.sub.12 I.sub.11 SSB.sub.12 I.sub.11, or another pharmaceutically acceptable salt of the compound, may be administered to a cancer patient for boron neutron capture therapy.

Miura, Michiko (Hampton Bays, NY); Slatkin, Daniel N. (Southold, NY)

1997-08-05T23:59:59.000Z

266

Chemical aspects of pellet-cladding interaction in light water reactor fuel elements  

SciTech Connect (OSTI)

In contrast to the extensive literature on the mechanical aspects of pellet-cladding interaction (PCI) in light water reactor fuel elements, the chemical features of this phenomenon are so poorly understood that there is still disagreement concerning the chemical agent responsible. Since the earliest work by Rosenbaum, Davies and Pon, laboratory and in-reactor experiments designed to elucidate the mechanism of PCI fuel rod failures have concentrated almost exclusively on iodine. The assumption that this is the reponsible chemical agent is contained in models of PCI which have been constructed for incorporation into fuel performance codes. The evidence implicating iodine is circumstantial, being based primarily upon the volatility and significant fission yield of this element and on the microstructural similarity of the failed Zircaloy specimens exposed to iodine in laboratory stress corrosion cracking (SCC) tests to cladding failures by PCI.

Olander, D.R.

1982-01-01T23:59:59.000Z

267

An axial xenon oscillation model  

Science Journals Connector (OSTI)

A two-point xenon oscillation model was developed for PWRs. The model employs the nonlinear xenon and iodine balance equations and the one group, one-dimensional neutron diffusion equation having nonlinear power reactivity feedback. A two-term spatial harmonic series solution was assumed for the flux, xenon and iodine distributions. The system was made as close to critical as possible with the assumed distributions using a variational principle. The xenon and iodine concentrations were then obtained from their governing differential equations. The input/output nature of the model makes it ideal for simulation of xenon-induced reactor transients. A comparison of the simulated plant to actual plant data was made. The period of oscillation, stability index and flux amplitude of the simulated plant were all found to match the actual plant data with less than 10% error.

R.J. Onega; R.A. Kisner

1978-01-01T23:59:59.000Z

268

Fabrication of atomic-scale gold junctions by electrochemical plating using a common medical liquid  

Science Journals Connector (OSTI)

Fabrication of nanometer-separated gold junctions has been performed using iodine tincture a medical liquid known as a disinfectant as an etching/deposition electrolyte. In the gold-dissolved iodine tincture goldelectrodes were grown or eroded slowly enough to form quantum point contacts in an atomic scale. The resistance evolution during the electrochemicaldeposition showed plateaus at integer multiples of the resistance quantum ( 2 e 2 ? h ) ? 1 at room temperature ( e : the elementary charge h : the Planck constant). Iodine tincture is a commercially available common material which makes the fabrication process to be simple and cost effective. Moreover in contrast to the conventional electrochemical approaches this method is free from highly toxic cyanide compounds or extraordinarily strong acids.

A. Umeno; K. Hirakawa

2005-01-01T23:59:59.000Z

269

Developing the Sandia National Laboratories transportation infrastructure for isotope products and wastes  

SciTech Connect (OSTI)

The US Department of Energy (DOE) plans to establish a medical isotope project that would ensure a reliable domestic supply of molybdenum-99 ({sup 99}Mo) and related medical isotopes (Iodine-125, Iodine-131, and Xenon-133). The Department`s plan for production will modify the Annular Core Research Reactor (ACRR) and associated hot cell facility at Sandia National Laboratories (SNL)/New Mexico and the Chemistry and Metallurgy Research facility at Los Alamos National Laboratory (LANL). Transportation activities associated with such production is discussed.

Trennel, A.J.

1997-11-01T23:59:59.000Z

270

Failure of the Shockley-Haynes Mobility Experiment with organic semiconducting materials  

E-Print Network [OSTI]

of the teflon cylinder was 0. 20$ cm + 0. 00$ cm whioh was slight- ly smaller than the graphite rods used, This arrapgement provided an airtight seal to prevent the sublimation of iodine from the samples after pressing Small holes were drilled through...-iodine was lower than that reported, The upper limit of 3000 lb/i. n for the pressure used to 2 oompress the samples was dictated by the graphite rods used and the wall thickness of the teflon oylinders. Pressures above $000 lb/in oaused either the ends...

Boehme, Hollis Clyde

2012-06-07T23:59:59.000Z

271

Optimal control of xenon concentration by observer design under reactor model uncertainty  

SciTech Connect (OSTI)

The state feedback in control theory enjoys many advantages, such as stabilization and improved transient response, which could be beneficially used for control of the xenon oscillation in a power reactor. It is, however, not possible in nuclear reactors to measure the state variables, such as xenon and iodine concentrations. For implementation of the optimal state feedback control law, it is thus necessary to estimate the unmeasurable state variables. This paper uses the Luenberger observer to estimate the xenon and iodine concentrations to be used in a linear quadratic problem with state feedback. To overcome the stiffness problem in reactor kinetics, a singular perturbation method is used.

Cho, Nam Z.; Yang, Chae Y.; Woo, Hae S.

1989-01-01T23:59:59.000Z

272

Improved method for preparing rare earth sesquichalcogenides  

DOE Patents [OSTI]

An improved method for the preparation of high purity rare earth sesquichalcogenides is described. The rare earth, as one or more pieces of the metal, is sealed under a vacuum with a stoichiometric amount of sulfur or selenium and a small amount of iodine into a quartz reaction vessel. The sealed vessel is then heated to above the vaporization temperature of the chalcogen and below the melting temperature of the rare earth metal and maintained until the product has been formed. The iodine is then vaporized off leaving a pure product. The rare earth sulfides and selenides thus formed are useful as semiconductors and as thermoelectric generators. 3 tables.

Takeshita, T.; Beaudry, B.J.; Gschneidner, K.A. Jr.

1982-04-14T23:59:59.000Z

273

K-edge Subtraction Angiography with Synchrotron X-Rays: Final Technical Report, (February 1, 1984 to January 31, 1987)  

DOE R&D Accomplishments [OSTI]

The aim was the development of an angiographic method and appropriate equipment for imaging with x-rays the coronary arteries in a non-invasive manner. Successive steps involved studies with phantoms, live animals and finally with human subjects. Clinical evaluation of human coronary arteries remains a goal of this and a continuing project, and steps along the way to such an achievement are in process. Transvenous injection of a dye using the method of iodine dichromography near 33.2 keV, the K-edge of iodine, forms the basis of the method

Hofstadter, R.

1987-09-00T23:59:59.000Z

274

Phase 1 Methyl Iodide Deep-Bed Adsorption Tests  

SciTech Connect (OSTI)

Nuclear fission results in the production of fission products (FPs) and activation products including iodine-129, which could evolve into used fuel reprocessing facility off-gas systems, and could require off-gas control to limit air emissions to levels within acceptable emission limits. Research, demonstrations, and some reprocessing plant experience have indicated that diatomic iodine can be captured with efficiencies high enough to meet regulatory requirements. Research on the capture of organic iodides has also been performed, but to a lesser extent [Jubin 2012b]. Several questions remain open regarding the capture of iodine bound in organic compounds. Deep-bed methyl iodide adsorption testing has progressed according to a multi-laboratory methyl iodide adsorption test plan. This report summarizes the first phase of methyl iodide adsorption work performed according to this test plan using the deep-bed iodine adsorption test system at the Idaho National Laboratory (INL), performed during Fiscal Year (FY) 2013 and early FY-2014. Testing has been performed to address questions posed in the test plan, and followed the testing outline in the test plan. Tests established detection limits, developed procedures for sample analysis with minimal analytical interferences, and confirmed earlier results that show that the methyl iodide reacts when in contact with the AgZ sorbent, and not significantly in the gas flow upstream of the sorbent. The reaction(s) enable separation of the iodine from the organic moiety, so that the iodine can chemisorb onto the sorbent. The organic moiety can form other compounds, some of which are organic compounds that are detected and can be tentatively identified using GC-FID and GCMS. Test results also show that other gas constituents (NOx and/or H2O) can affect the methyl iodide reactions. With NOx and H2O present in the gas stream, the majority of uncaptured iodine exiting iodine-laden sorbent beds is in the form of I2 or HI, species that are soluble in NaOH scrubbing solution for iodine analysis. But when NOx and H2O are not present, then the majority of the uncaptured iodine exiting iodine-laden sorbent is in the form of methyl iodide. Methyl iodide adsorption efficiencies have been high enough so that initial DFs exceed 1,000 to 10,000. The methyl iodide mass transfer zone depths are estimated at 4-8 inches, possibly deeper than mass transfer zone depths estimated for I2 adsorption on AgZ. Additional deep-bed testing and analyses are recommended to (a) expand the data base for methyl iodide adsorption under various conditions specified in the methyl iodide test plan, and (b) provide more data for evaluating organic iodide reactions and reaction byproducts for different potential adsorption conditions.

Nick Soelberg; Tony Watson

2014-08-01T23:59:59.000Z

275

Ionising Radiation emitters Spill Procedure Page 1 of 3 Version: 3.2, 5/02/2013  

E-Print Network [OSTI]

as necessary to reduce contamination close to background levels. For spills involving radioactive iodine, use.......................................................................................................3 1. Purpose and Scope Immediate control procedures for radioactive spillages of gamma Procedure Instructions In the Event of a Radioactive Spill in this Room Immediate control procedures

New South Wales, University of

276

Laser-produced plasma-wall interaction O. RENNER,1  

E-Print Network [OSTI]

Laser-produced plasma-wall interaction O. RENNER,1 R. LISKA,2 AND F.B. ROSMEJ3,4 1 Institute, France (RECEIVED 30 August 2009; ACCEPTED 21 September 2009) Abstract Jets of laser­generated plasma surfaces (walls). The pilot experiments carried out on the iodine laser system (5­200 J, 0.44 mm, 0

Liska, Richard

277

Non-invasive nuclear detection of choroidal melanoma  

SciTech Connect (OSTI)

The biodistribution of over 30 radiopharmaceuticals thought to be tumor-seeking agents were studied using hamsters and mice. Several radiopharmaceuticals were found to be appropriate as melanoma localizing agents. Results with modified dual pinhole collimator and a pigment affinic agent (iodine-123 labeled quinoline) and a non-specific tumor seeking agent (gallium-67 citrate) are also reported.

Packer, S.; Lambrecht, R.M.; Fairchild, R.G.; Wolf, A.P.; Atkins, H.L.; Fand, I.

1981-01-01T23:59:59.000Z

278

Mercuric iodate precipitation from radioiodine-containing off-gas scrubber solution  

DOE Patents [OSTI]

Mercuric nitrate-nitric acid scrub solutions containing radioiodine may be reduced in volume without excessive loss of volatile iodine. The use of concentrated nitric acid during an evaporation process oxidizes the mercury-iodide complex to a less volatile mercuric iodate precipitate.

Partridge, Jerry A. (Richland, WA); Bosuego, Gail P. (Richland, WA)

1982-01-01T23:59:59.000Z

279

SPECT assay of radiolabeled monoclonal antibodies. Final performance report, March 1992--November 1995  

SciTech Connect (OSTI)

Research is described in the following areas: development and evaluation quantitatively of reconstruction algorithms with improved compensations for attenuation, scatter, and geometric collimator response; evaluation of single photon emission computed tomography (SPECT) quantification of iodine 123 and astatine 211; and the development and evaluation of SPECT pinhole imaging for low and medium energy photons.

Jaszczak, R.J.

1995-12-01T23:59:59.000Z

280

RIS-M-2234 A NOTE ON THE RELATIONSHIP BETWEEN OUTDOOR AND INDOOR  

E-Print Network [OSTI]

POLLUTION OP OUTDOOR ORIGIN H.L. Gjørup and Jørn Roed Health Physics Department Abstract. Beryllium-7-descriotors; AIR POLLUTION, BERYLLIUM 7, BUILDINGS, INHALATION, IODINE 131, MEASURING METHODS, RADIATION DOSES from its counterpart in Danish dated Hay 1979. 2. GENERAL INFORMATION Any pollution of inhaled air

Note: This page contains sample records for the topic "iodine phos phorus" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


281

A NEW MULTIPLE-UNIT ELECTRODIALYSIS APPARATUS  

Science Journals Connector (OSTI)

...NEW MULTIPLE-UNIT ELECTRODIALYSIS APPARATUS 10.1126...NEW MULTIPLE-UNIT ELECTRODIALYSIS APPARATUS. | Journal...maturity, variety and treatment on the iodine value...CHICAGO, ILLINOIS WATER SOLUBLE MAGNESIUM...NEW MULTIPLE-UNIT ELECTRODIALYSIS ous fields of science...

Aasulv Lddesl

1932-07-22T23:59:59.000Z

282

Detonation of Nitrogen Iodide, NI3NH3  

Science Journals Connector (OSTI)

... the other hand, the substance can be completely decomposed into iodine and permanent gases without detonation occurring if the pressure of the permanent gases be not allowed to fall below 2 ... state is reached, on subjecting the residue to a hard vacuum it detonates. On detonation, the amount of permanent gas produced is only 3050 per cent of that ...

W. E. GARNER; W. E. LATCHEM

1935-05-18T23:59:59.000Z

283

Phase II Study of Oral Capsular 4-Hydroxyphenylretinamide (4-HPR/Fenretinide) in Pediatric Patients with Refractory or Recurrent Neuroblastoma: A Report from the Children's Oncology Group  

Science Journals Connector (OSTI)

...14:2005-9. 9. Hsieh TC , Ng C Wu JM. The synthetic...499-506. 10. Kazmi SM , Plante RK, Visconti V Lau...0 Iodine Radioisotopes 0 Radiopharmaceuticals 65646-68-6 Fenretinide...blood drug therapy pathology Radiopharmaceuticals diagnostic use pharmacokinetics...

Judith G. Villablanca; Wendy B. London; Arlene Naranjo; Patrick McGrady; Matthew M. Ames; Joel M. Reid; Renee M. McGovern; Sarah A. Buhrow; Hollie Jackson; Enno Stranzinger; Brenda J. Kitchen; Paul M. Sondel; Marguerite T. Parisi; Barry Shulkin; Gregory A. Yanik; Susan L. Cohn; and C. Patrick Reynolds

2011-11-01T23:59:59.000Z

284

Iodide accumulation provides kelp with an inorganic antioxidant impacting atmospheric chemistry  

Science Journals Connector (OSTI)

...impacting atmospheric chemistry...of Earth, Atmospheric, and Environmental...precursors to cloud condensation nuclei. In...exploitation of brine waters accompanying...deposits for the recovery of iodine...for cloud condensation nuclei (10...solvent, water. The reduced...desiccation, and atmospheric O 3 we simulated...

Frithjof C. Kpper; Lucy J. Carpenter; Gordon B. McFiggans; Carl J. Palmer; Tim J. Waite; Eva-Maria Boneberg; Sonja Woitsch; Markus Weiller; Rafael Abela; Daniel Grolimund; Philippe Potin; Alison Butler; George W. Luther III; Peter M. H. Kroneck; Wolfram Meyer-Klaucke; Martin C. Feiters

2008-01-01T23:59:59.000Z

285

Natural source of tetraalkyllead in air  

Science Journals Connector (OSTI)

... on a 0.45-m membrane filter (Millipore type HAWP 04700) and determined by flameless atomic absorption spectrometry after extraction into acid solution7. Tetraalkyllead was trapped quantitatively downstream of ... downstream of the filter in iodine monochloride solution and the lead concentration was determined by flameless atomic absorption spectrometry after selective extraction into acid solution, by means of a technique ...

ROY M. HARRISON; DUNCAN P. H. LAXEN

1978-10-26T23:59:59.000Z

286

One-Step Production of Immobilized ?-Amylase in Recombinant Escherichia coli  

Science Journals Connector (OSTI)

...pH and gelatinized by heating until boiling for 10...medium or periplasmic space (26, 29). While...further supported here by construction of a hybrid gene encoding...Lugols iodine staining. Sectors are as follows: A...oligonucleotides and the construction of plasmid pET14b-BLAphaC...

Indira A. Rasiah; Bernd H. A. Rehm

2009-02-05T23:59:59.000Z

287

Polyacrylonitrile-Chalcogel Hybrid Sorbents for Radioiodine Capture  

SciTech Connect (OSTI)

Powders of a Sn2S3 chalcogen-based aerogel (chalcogel) were combined with powdered polyacrylonitrile (PAN) in different mass ratios (SnS33, SnS50, and SnS70 in mass% of chalcogel), dissolved into dimethyl sulfoxide, and dropped into deionized water to form pellets of a porous PAN-chalcogel hybrid material. Pellets of these hybrid sorbents, along with pure powdered (SnSp) and granular (SnSg) forms of the chalcogel, were then used to adsorb iodine gas under both concentrated and dilute conditions. Both the SnSp and SnSg chalcogels showed very high maximum iodine loadings at 67.2 and 68.3 mass%. The maximum iodine loadings in the SnS33 and SnS50 were high at 32.8 and 53.5 mass%. In all cases, X-ray diffraction results showed the formation of Sn-I phases of SnI4 and SnI4(S8)2 revealing that the iodine binding in these materials is mainly due to a chemisorption process although some evidence also exists that supports a physisorption process.

Riley, Brian J.; Pierce, David A.; Chun, Jaehun; Matyas, Josef; Lepry, William C.; Garn, Troy; Law, Jack; Kanatzidis, Mercouri G.

2014-04-16T23:59:59.000Z

288

Radiation dose profile in 125I brachytherapy: an 8-year review  

Science Journals Connector (OSTI)

......brachytherapy: an 8-year review A. N. Al-Haj...prepare the treatment plan. The radiation oncologists...KFSHRC Secondary Standard Dosimetry Laboratory...DNS-26 depleted uranium standard reference...brachytherapy: an 8-year review. | The use of episcleral...Journal Article Review | 0 Iodine Radioisotopes......

A. N. Al-Haj; A. M. Lobriguito; C. S. Lagarde

2004-08-01T23:59:59.000Z

289

Polyacrylonitrile-Chalcogel Hybrid Sorbents for Radioiodine Capture  

SciTech Connect (OSTI)

Powders of a Sn2S3 chalcogen-based aerogel (chalcogel) were combined with powdered polyacrylonitrile (PAN) in different mass ratios (SnS33, SnS50, and SnS70; # = mass% of chalcogel), dissolved in dimethyl sulfoxide, and added dropwise to deionized water to form pellets of a porous PAN-chalcogel hybrid material. These pellets, along with pure powdered (SnSp) and granular (SnSg) forms of the chalcogel, were then used to capture iodine gas under both dynamic (dilute) and static (concentrated) conditions. Both SnSp and SnSg chalcogels showed very high iodine loadings at 67.2 and 68.3 mass%, respectively. The SnS50 hybrid sorbent demonstrated a high, although slightly reduced, maximum iodine loading (53.5 mass%) with greatly improved mechanical rigidity. In all cases, X-ray diffraction results showed the formation of crystalline SnI4 and SnI4(S8)2, revealing that the iodine binding in these materials is mainly due to a chemisorption process, although a small amount of physisorption was observed.

Brian J. Riley; David A. Pierce; Jaehun Chun; Josef Matyas; William C. Lepry; Troy G. Garn; Jack D. Law; Mercouri G. Kanatzidis

2014-04-01T23:59:59.000Z

290

Chainpur-like Chondrites: Primitive Precursors of Ordinary Chondrites?  

Science Journals Connector (OSTI)

...carbonaceous chond;rites. Thus, if iodine is depleted in ordinary chondrites but not in car-bonaceous...the sensitive trace elements that are depleted in their recrystallized and equilibrated...29).] Simple metamorphism may have depleted some sensitive trace elements (10...

R. A. Schmitt; R. H. Smith; G. G. Goles

1966-08-05T23:59:59.000Z

291

A literature Review on Radioactivity Transfer to  

E-Print Network [OSTI]

, resuspension, and translocation are the transfer processes dis- cussed. Theory and experimental data; IODINE 131; MATHEMAT- ICAL MODELS; PARTICLE RESUSPENSION; PLANTS; PRECIPITATION SCAV- ENGING 53 6.2. Retention during initial phase 53 6.3. Weathering 55 7. RESUSPENSION 60 7.1. Introduction 60

292

Titanium Lubrication  

Science Journals Connector (OSTI)

... Iodine and n-butylbenzene were analytical reagent grade and were used without further purification. The SAE 10, 150 SUS oil was a highly refined straight chain hydrocarbon oil without additives. ... 0-25-0-38 Little wear, wear track had

RICHARD W. ROBERTS; ROBERT S. OWENS

1963-10-26T23:59:59.000Z

293

Capturing fleeting intermediates in a catalytic CH amination reaction cycle  

E-Print Network [OSTI]

droplets in a stream of gas form a spray that impacts a surface containing a sample of interest the mechanism for Rh-catalyzed C­H amination depicted in Fig. 1. Sulfamate 2 and iodine oxidant 3 condense and extracts analyte into secondary microdroplets. Subsequent desolvation generates gas-phase ions that can

Zare, Richard N.

294

Abstract: The deproto-metalation reactions of pyrimidine and pyrazine were regioselectively carried out using lithium  

E-Print Network [OSTI]

carried out using lithium tri(2,2,6,6-tetramethylpiperidino)cadmate in tetrahydrofuran at room temperature instead of 1/3). Key words: Metalations, Cadmium, Lithium, Heterocycles, Iodine. Procedure 1 25 mmol scale metalation of aromatic rings, and various strong bases such as alkylli- thiums and lithium dialkylamides have

Boyer, Edmond

295

www.solas-int.org //00//00 surface ocean -lower atmosphere study Mid-Term Strategy theme: Air-sea gas fluxes at Eastern boundary Upwelling and Oxygen Minimum Zone (OMZ) systems  

E-Print Network [OSTI]

to space (aerosol direct effect), and have the potential to modify cloud cover and thus Earth's albedo (aerosol indirect effect). One such molecule is glyoxal that forms secondary organic aerosol (SOA). SOA, the first ship-based detection of glyoxal and iodine oxide was demonstrated over the remote tropical Pacific

296

Synthesis and Characterization of Bismuth Complexes [BiI2(4,4?-bpy)(S2CNR2)]? and [BiI(S2CNR2)2]? and Crystal Structure of [BiI2(4,4?-bpy)(S2CNC4H8O)]? and [BiI(S2CNC5H10)2]?  

Science Journals Connector (OSTI)

In this complex, the piperidyldithiocarbamate groups bond to Bi atom in bidentate fashion. The bond angles, forming by three sulfur atoms of S2CNC4H8 ligands and one iodine atom [S(3)-Bi(1)-S(4) 66.8(2), S(4)-Bi...

Handong Yin; Feng Li; Fahui Li; Daqi Wang

2006-06-01T23:59:59.000Z

297

The Active Site Is the Least Stable Structure in the Unfolding Pathway of a Multidomain Cold-Adapted ?-Amylase  

Science Journals Connector (OSTI)

...top). The break, which occurred...cold-adapted a-amylase has two stability...1 to 2 min on starch-containing agarose...haloplanktis a-amylase. Domain A (pink...electrophoresis down the gel. An inverse...cold-adapted a-amylase at 12C (left...with iodine for starch hydrolysis activity...

Khawar S. Siddiqui; Georges Feller; Salvino D'Amico; Charles Gerday; Laura Giaquinto; Ricardo Cavicchioli

2005-09-01T23:59:59.000Z

298

0-600 kev Gamma-Ray Spectra from Thermal Neutron Capture in the Region A=104to198  

Science Journals Connector (OSTI)

The energies and absolute intensities of prominent peaks in the 0-600 kev region of the gamma-ray spectrum following thermal neutron capture have been measured with a single NaI(Tl) scintillation spectrometer. The elements investigated were rhodium, silver, cadmium, indium, antimony, tellurium, iodine, samarium, europium, gadolinium, terbium, dysprosium, holmium, erbium, thulium, hafnium, tantalum, rhenium, iridium, platinum, and gold.

James E. Draper

1959-04-01T23:59:59.000Z

299

Download Full-text PDF  

Science Journals Connector (OSTI)

water. An accuracy of 0.1% was obscrvcc~, so the tcchniquc nppcars suitable for oxygen analysts requiring ... bc valid, and the solubility values wcrc sug- .... eration of iodine under a nitrogen atmo- ... oxygen gas was attached to the lower ball.

300

Radiation Therapy with Tositumomab (B1) Anti-CD20 Monoclonal Antibody Initiates Extracellular Signal-Regulated Kinase/Mitogen-Activated Protein KinaseDependent Cell Death that Overcomes Resistance to Apoptosis  

Science Journals Connector (OSTI)

...Image-Pro Plus 6.0 software (MediaCybernetics...Microsoft Excel or SPSS 13 software (SPSS, Inc.). Results...U0126 on tositumomab and radiation-induced additive cell...et al. Efficacy and safety of tositumomab and iodine-131...2005;23:712-9. Radiation therapy with tositumomab...

Andrey Ivanov; Sergei Krysov; Mark S. Cragg; and Tim Illidge

2008-08-01T23:59:59.000Z

Note: This page contains sample records for the topic "iodine phos phorus" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


301

Time-resolved coherent anti-Stokes Raman-scattering measurements of I2 in solid Kr: Vibrational dephasing on the ground electronic state  

E-Print Network [OSTI]

Time-resolved coherent anti-Stokes Raman-scattering measurements of I2 in solid Kr: Vibrational; published online 18 August 2005 Time-resolved coherent anti-Stokes Raman-scattering CARS measurements are carried out for iodine I2 in solid krypton matrices. The dependence of vibrational dephasing time

Apkarian, V. Ara

302

Na double-edge magneto-optic filter for Na lidar profiling of wind and temperature in the  

E-Print Network [OSTI]

proposed by one of the authors (Williams), originating from the Na magneto-optic filter in solar-edge magneto-optic fil- ter (Na-DEMOF). It has advantages over the FPIs and iodine filters because of its magnetic field across the Na cell causes the Zeeman splitting of Na energy levels, which shifts

Chu, Xinzhao

303

JOURNAL DE PHYSIQUE IV ColloqueC7,supplkmentau Journal de Physique 111,Vol. 1,dkmbre 1991  

E-Print Network [OSTI]

tailored to pump lasers, such as flashlamps, arc lamps, and lasers for pumping. The advantages of solar lasers are that the solar energy is free, non-local, pollution free, and abundant. Indeed, direct solar of power laser beaming in spaceand its applicationsare presented. A direct solar-pumped iodine laser

Paris-Sud XI, Université de

304

Radiolabeling of Antibodies  

Science Journals Connector (OSTI)

...nucleophilic species such as water or pyridine. In electrophilic...0.05 M solution in water decreased in oxidizing power by only 0.02%/month...are generally mild, car rier iodine is needed...from the protein and a water-soluble chelate is...

William C. Eckelman; Chang H. Paik; and Richard C. Reba

1980-08-01T23:59:59.000Z

305

Excretion of volatile 131I from rats following administration of Na131I or MIBG-131I  

Science Journals Connector (OSTI)

......Laboratories, Atomic Energy of Canada Limited...hospital and at home. As iodine can...Laboratories, Atomic Energy of Canada Limited...each rat, daily consumption of food and water...5 g with an average of 11.62.1...3) (99.7) Average (81.93.3...the patient's home has 600 m3 space......

Chunsheng Li; Baki Sadi; Heather Wyatt; Michelle Bugden; Diana Wilkinson; Jack Cornett; Gary H. Kramer

2012-01-01T23:59:59.000Z

306

Prevalence of Salmonella sp. in domestic cats in an animal shelter and the comparison of culture and polymerase chain reaction techniques as diagnostic tools  

E-Print Network [OSTI]

Laboratory the prevalence of Salmonella in shelter cat feces was determined in this current study. The culture protocol used included Xylose Lysine Tergitol 4 (XLT4) and MacConkey (MAC) agars with a primary enrichment in Tetrathionate broth (TTH) with iodine...

Lee, Melinda J.

2004-11-15T23:59:59.000Z

307

Biology of the Precambrian Genus Kakabekia: New Observations on Living Kakabekia barghoorniana  

Science Journals Connector (OSTI)

...response-- Tests specimens Positive Negative Iodine 6 0 100 Sudan III 8 0 100 Tetrazolium-glucose 9 100 0 p-Cresol 8 0 100...15'30'W), but is definitely absent from the more active thermal and volcanic areas, including Surtsey itself. The results...

B. Z. Siegel; S. M. Siegel

1970-01-01T23:59:59.000Z

308

INTRODUCTIONSURVEY OF RESEARCH FIELDS AND NEEDS  

Science Journals Connector (OSTI)

...tion-absorbing gas similar to iodine...Corporationi re- ported on progress in this field at...symposium. An expanded report of their work will...are needed. Rapid progress has been made at...use with a water turbine constitutes perhaps...of Energy." The report of this committee...

Farrington Daniels

1961-01-01T23:59:59.000Z

309

Segmented Waves from a Spatiotemporal Transverse Wave Instability Lingfa Yang, Igal Berenstein, and Irving R. Epstein*  

E-Print Network [OSTI]

Segmented Waves from a Spatiotemporal Transverse Wave Instability Lingfa Yang, Igal Berenstein observe traveling waves emitted from Turing spots in the chlorine dioxide-iodine-malonic acid reaction. The newborn waves are continuous, but they break into segments as they propagate, and the propagation

Epstein, Irving R.

310

Radioiodinated glucose analogues for use as imaging agents  

DOE Patents [OSTI]

A radioiodinated branched carbohydrate for tissue imaging. Iodine-123 is stabilized in the compound by attaching it to a vinyl functional group that is on the carbohydrate. The compound exhibits good uptake and retention and is promising in the development of radiopharmaceuticals for brain, heart and tumor imaging.

Goodman, Mark M. (Knoxville, TN); Knapp, Jr., Furn F. (Oak Ridge, TN)

1988-01-01T23:59:59.000Z

311

Radioiodinated branched carbohydrates  

DOE Patents [OSTI]

A radioiodinated branched carbohydrate for tissue imaging. Iodine-123 is stabilized in the compound by attaching it to a vinyl functional group that is on the carbohydrate. The compound exhibits good uptake and retention and is promising in the development of radiopharmaceuticals for brain, heart and tumor imaging.

Goodman, Mark M. (Knoxville, TN); Knapp, Jr., Furn F. (Oak Ridge, TN)

1989-01-01T23:59:59.000Z

312

Page 1 of 4 Radiogram No. 8492u Form 24 for 02/21/2012  

E-Print Network [OSTI]

Makita Battery Charge 08:10-08:50 FE-2 Maintenance activation of spare Atmosphere Purification System Atmosphere Purification System Emergency Vacuum Valves [ ] 08:40-11:10 FE-5 IMV Cleaning 08:50-09:10 FE-4:00-14:30 FE-5 Water Recovery System (WRS) CWC-I (Iodinated Contingency Water Container) Fill Part 1 14

Waliser, Duane E.

313

COMMENTARY/COMMENTAIRE The radiological consequences of the Chernobyl  

E-Print Network [OSTI]

COMMENTARY/COMMENTAIRE The radiological consequences of the Chernobyl accident The First­22 March 1996 Eric Voice Abstract: The human health consequences of the Chernobyl accident in 1986 have are discussed with particular focus on thyroid cancers and exposures to iodine-131. Key words: Chernobyl

Shlyakhter, Ilya

314

Molecular Level Characterization and Mobility of Radionuclide-Carrying Natural Organic Matter in Aquatic Environments  

E-Print Network [OSTI]

small-size aromatic subunit (~10 kDa), while the large-size subunit (~90 kDa), which likely linked the small-size unit through some weak chemical forces, determined the relative mobility of iodine bound to organic matter. Soil resuspension experiments...

Xu, Chen

2012-10-19T23:59:59.000Z

315

sine.I0 Cyclization of 4 to a tetrahydrobenzazepine 5 could be followed by oxidative fission of one aromatic ring. in a  

E-Print Network [OSTI]

Excited Iodine Monochloride with Halogenated Olefins Sir: We report here the photochemical separation, the trans- ClHC=CHCl photoproduct has a 35C1:37C1ratio of 2:1 compared to 3:l for naturally occurring trans with a new means of following organic gas-phase photochemical reac- tions with state selection

Zare, Richard N.

316

Carbon Allocation in Underground Storage Organs  

E-Print Network [OSTI]

Carbon Allocation in Underground Storage Organs Studies on Accumulation of Starch, Sugars and Oil Cover: Starch granules in cells of fresh potato tuber visualised by iodine staining. #12;Carbon By increasing knowledge of carbon allocation in underground storage organs and using the knowledge to improve

317

Equation of state data for gold in the pressure range <10 TPa  

Science Journals Connector (OSTI)

We report experimental data on the equation of state of gold in the pressure range 210 TPa obtained using laser-driven shock waves. The experiments have been realized using an iodine high-power laser with subnanosecond pulses and techniques like phase zone plates and hohlraums to produce spatially uniform shocks. Our data are compared with existing equation of state models.

Dimitri Batani, Antonio Balducci, Daniele Beretta, Andrea Bernardinello, Thorsten Lwer, Michel Koenig, Alessandra Benuzzi, Bernard Faral, and Tom Hall

2000-04-01T23:59:59.000Z

318

Features of coal dust dynamics at action of differently oriented forces in granular filtering medium  

E-Print Network [OSTI]

The process of the coal dust particles transportation and structurization in the experimental horizontal model of air filter with the cylindrical coal adsorbent granules as in the iodine air filter at the nuclear power plant is researched. In the investigated case the vector of carrying away force of air flow and the vector of gravitation force are mutually perpendicular, and the scattering of the dust particles on the granules occurs in the normal directions. It is found that the phenomenon of non controlled spontaneous sharp increase of aerodynamic resistance in the iodine air filter under the big integral volumes of filtered air and the big masses of introduced coal dust particles is not observed at the described experimental conditions in distinction from the case of the parallel orientation of this forces as in the vertical iodine air filters at the nuclear power plant. The quantitative measurements of the main parameters of the process of the dust masses transportation and structurization are made on a developed experimental model of the iodine air filter with the cylindrical coal adsorbent granules.

I. M. Neklyudov; L. I. Fedorova; P. Ya. Poltinin; O. P. Ledenyov

2013-01-24T23:59:59.000Z

319

Contortrostatin, a Snake Venom Disintegrin, Inhibits ?1 Integrin-mediated Human Metastatic Melanoma Cell Adhesion and Blocks Experimental Metastasis  

Science Journals Connector (OSTI)

...to be involved in the development of the metastatic phenotype...Crotalidae and Viperidae snake species (9 "18...Contortrostatin, a Snake Venom Disintegrin...was incubated at room temperature overnight. Absorbance...for 5 "6mm at room temperature. Excess iodine was...

Mohit Trikha; Yves A. De Clerck; and Francis S. Markland

1994-09-15T23:59:59.000Z

320

Halogenation of cobalt dicarbollide  

DOE Patents [OSTI]

A method for selectively adding chlorine, bromine, or iodine to cobalt dicarbollide anions by means of electrophilic substitution reactions. Halogens are added only to the B10 and B10{prime} positions of the anion. The process involves use of hypohalous acid or N-halosuccinimide or gaseous chlorine in the presence of iron. 1 fig.

Hurlburt, P.K.; Abney, K.D.; Kinkead, S.A.

1997-05-20T23:59:59.000Z

Note: This page contains sample records for the topic "iodine phos phorus" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


321

Spectral inhomogeneity induced by vacancies and thermal phonons and associated observables in time-and frequency-domain nonlinear  

E-Print Network [OSTI]

Spectral inhomogeneity induced by vacancies and thermal phonons and associated observables in time by vacancies and thermally populated phonons, specializing to molecular iodine isolated in an Ar matrix. At experimentally relevant temperatures, for a vacancy concentration of 1.4%, both defect-induced and phonon

Apkarian, V. Ara

322

NA Standards | Refinement Parameters | X-PLOR param file for high  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

the file for different bond distances and angles of C2'and C3'-endo the file for different bond distances and angles of C2'and C3'-endo remark K= scale*(kT/sigma**2), scales=Base 0.1875, Sugar 0.566, Phos 1.548 ! removed references to CA, CF, CS, MG, NH3, OS (ATB 12/30/94) ! removed TIP3 water model (ATB 12/30/94) ! mapped NA->NNA, CH3E->CC3E (ATB 12/30/94) ! G.PARKINSON, J.VOJTECHOVSKY, L.CLOWNEY, A.T.BRUNGER ! H.M.BERMAN ! NEW PARAMETERS FOR THE REFINEMENT OF NUCLEIC ACID CONTAINING ! STRUCTURES ! ACTA CRYST.D (1996) v. 52 57-64 set echo=false end !the generic bonds were taken from param11.dna with 3*kq bond C5R OH 876.000 1.4300 ! 5' end bond C5D OH 876.000 1.4300 ! 5' end bond C3R OH 876.000 1.4300 ! 3' end bond C3D OH 876.000 1.4300 ! 3' end bond HHO O2R 1350.000 0.9572 !Mod HO to HHO 05/15/96

323

Hyperactivated Motility of Stallion Spermatozoa  

E-Print Network [OSTI]

s t s of chan ges t o t he s perm pl as m a m em brane, c yt os ol and a xonem al s t ruct ures , i ncl u di ng i ncreas ed p rot ei n t yros i ne phos phor yl at i on (P Y, [ 9 ] ), i ncre as ed i nt ra cel l ul ar pH [ 10 - 13 ] , i ncreas ed i nt racel l... ] . B i carbonat e s t i m ul at es t he prot ei n ki nas e A pat hw a y vi a s t i m ul at i on of t he s perm s ol ubl e aden yl at e c yc l as e and product i on o f cAM P [ 27 ] and a l s o fac i l i t at es an i ncreas e i n m e di um pH, whi ch...

Loux, Shavahn C

2013-12-02T23:59:59.000Z

324

Oral Histories: Health Physicist Constantine J. Maletskos, Ph.D.  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

3 3 HUMAN RADIATION STUDIES: REMEMBERING THE EARLY YEARS Oral History of Health Physicist Constantine J. Maletskos, Ph.D. Conducted January 20, 1995 United States Department of Energy Office of Human Radiation Experiments September 1995 CONTENTS Foreword Short Biography Early Education and Career (1920 to Mid '50s) Early Dosimetry Research (1940s to 1960) Radium Dial Painter Research (Early '50s–60s) Fernald School Calcium Metabolism Studies (1948 to Early '50s) Iodine-131 Thyroid Research (Early '50s); Additional Calcium Metabolism Studies on Elderly Subjects (Early '50s) Iodine-131 Research and the Fernald School (Early to Mid '50s) Robley Evans's Role in Experiment Oversight and Funding Information Experiment Safety Protocols, Clarified (1950s) Radium and Thorium Ingestion by Human Subjects (Late '50s to Early '60s)

325

CX-002201: Categorical Exclusion Determination | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

201: Categorical Exclusion Determination 201: Categorical Exclusion Determination CX-002201: Categorical Exclusion Determination Iodine Speciation CX(s) Applied: B3.6 Date: 04/28/2010 Location(s): Aiken, South Carolina Office(s): Environmental Management, Savannah River Operations Office The objective of this study is to analyze for iodine speciation in Savannah River Site samples (groundwater and soil) by testing for iodide, iodate and organo-Iodide concentrations. This work will be conducted in B-122 and/or B107, B127 in 773-A. This is in support of PA-CA (performance assessment-composite analysis) test and research. DOCUMENT(S) AVAILABLE FOR DOWNLOAD CX-002201.pdf More Documents & Publications CX-003638: Categorical Exclusion Determination CX-000560: Categorical Exclusion Determination CX-005109

326

Estimation of thyroid doses received by the population of Belarus as a result of the Chernobyl accident  

SciTech Connect (OSTI)

Within weeks of the Chernobyl accident ABOUT 300,000 measurements of human thyroidal iodine-131 content were conducted in the more contaminated areas of Belarus. Results of these and other measurements form the basis of thyroid-dose reconstruction for the residents. For Class 1 (measured dose), individual doses are estimated directly from measured thyroidal iodine content plus information on life style and dietary habits. Such estimates are available for about 130,000 individuals from Gomel and Mogilev Oblasts and Minsk City. For Class 2 (passport doses), every settlement with a sufficient number of residents with measured doses, individual thyroid-dose distributions were determined for several age groups and levels of milk consumption. A population of about 2.7 million resides in the passport settlements.

Gavrilin, Y.; Khrouch, V.; Shinkarev, S. [Institut Biofiziki, Moscow (Russian Federation); Drozdovitch, V.; Minenko, V.; Shemyakina, E. [Institute of Radiation Medicine, Minsk (Belarus); Bouville, A. [National Cancer Inst., Rockville, MD (United States); Anspaugh, L. [Lawrence Livermore National Lab., CA (United States)

1996-02-01T23:59:59.000Z

327

Purification and deposition of silicon by an iodide disproportionation reaction  

DOE Patents [OSTI]

Method and apparatus for producing purified bulk silicon from highly impure metallurgical-grade silicon source material at atmospheric pressure. Method involves: (1) initially reacting iodine and metallurgical-grade silicon to create silicon tetraiodide and impurity iodide byproducts in a cold-wall reactor chamber; (2) isolating silicon tetraiodide from the impurity iodide byproducts and purifying it by distillation in a distillation chamber; and (3) transferring the purified silicon tetraiodide back to the cold-wall reactor chamber, reacting it with additional iodine and metallurgical-grade silicon to produce silicon diiodide and depositing the silicon diiodide onto a substrate within the cold-wall reactor chamber. The two chambers are at atmospheric pressure and the system is open to allow the introduction of additional source material and to remove and replace finished substrates.

Wang, Tihu (Littleton, CO); Ciszek, Theodore F. (Evergreen, CO)

2002-01-01T23:59:59.000Z

328

Nuclear Medicine Program progress report, quarter ending March 31, 1992  

SciTech Connect (OSTI)

We describe the design synthesis and initial animal testing of a new iodine-131-labeled triglyceride analogue for the potential evaluation of clinical pancreatic insufficiency. The new agent is 1,2-dipalmitoyl-3-[(15-p-iodophenyl)pentadecanoyl] rac-glycerol(1,2-Pal-3-IPPA). Following oral administration of the iodine-125-labeled agent to rats, 34.5+8.8% of the administered activity was excreted in the urine within one day, demonstrating that radioiodinated IPPA is absorbed in the intestine after release from the triglyceride by pancreatic lipase. The final catabolic product of IPPA is then conjugated and excreted via the urinary bladder. Urine analysis following oral administration of this new agent to patients may thus be a new, simple method for the clinical evaluation of various gastrointestinal diseases. The synthesis and the initial biological evaluation of the 3R-isomer of [{sup 125}I]IQNP are also described.

Knapp, F.F. Jr.; Ambrose, K.R.; Callahan, A.P.; McPherson, D.W.; Mirzadeh, S.; Hasan, A.; Lambert, C.R.; Rice, D.E.

1992-07-01T23:59:59.000Z

329

Nuclear Medicine Program progress report, quarter ending March 31, 1992  

SciTech Connect (OSTI)

We describe the design synthesis and initial animal testing of a new iodine-131-labeled triglyceride analogue for the potential evaluation of clinical pancreatic insufficiency. The new agent is 1,2-dipalmitoyl-3-((15-p-iodophenyl)pentadecanoyl) rac-glycerol(1,2-Pal-3-IPPA). Following oral administration of the iodine-125-labeled agent to rats, 34.5+8.8% of the administered activity was excreted in the urine within one day, demonstrating that radioiodinated IPPA is absorbed in the intestine after release from the triglyceride by pancreatic lipase. The final catabolic product of IPPA is then conjugated and excreted via the urinary bladder. Urine analysis following oral administration of this new agent to patients may thus be a new, simple method for the clinical evaluation of various gastrointestinal diseases. The synthesis and the initial biological evaluation of the 3R-isomer of ({sup 125}I)IQNP are also described.

Knapp, F.F. Jr.; Ambrose, K.R.; Callahan, A.P.; McPherson, D.W.; Mirzadeh, S.; Hasan, A.; Lambert, C.R.; Rice, D.E.

1992-07-01T23:59:59.000Z

330

Soft computing systems applied to PWR's xenon  

Science Journals Connector (OSTI)

The present work intends to introduce a soft computing technique as an effective and robust tool available to deal with nuclear engineering problems. This goal is reached by the presentation of an application: a genetic programming system (GP) able to automatically design a controller for the axial xenon oscillations in a pressurized water reactors (PWRs). The axial xenon oscillations control methodology is based on three axial offsets: the xenon axial offset (AOx), the iodine axial offset (AOi) and the neutron flux axial offset (AOf), effectively used in former work. Simulations were made using a two-point xenon oscillation model which employs the non-linear xenon and iodine balance equations and the one group, one-dimensional neutron diffusion equation, with non-linear power reactivity feedback, also proposed in the literature. Obtained results showed the ability of the GP in finding a strategy which can effectively control the axial xenon oscillations.

Roberto P. Domingos; Roberto Schirru; Aquilino Senra Martinez

2005-01-01T23:59:59.000Z

331

PWR's xenon oscillation control through a fuzzy expert system automatically designed by means of genetic programming  

Science Journals Connector (OSTI)

This work proposes the use of genetic programming (GP) for automatic design of a fuzzy expert system aimed to provide the control of axial xenon oscillations in pressurized water reactors (PWRs). The control methodology is based on three axial offsets of xenon (AOx), iodine (AOi) and neutron flux (AOf), effectively used in former work. Simulations were made using a two-point xenon oscillation model, which employs the non-linear xenon and iodine balance equations and the one group, one-dimensional neutron diffusion equation, with non-linear power reactivity feedback, also proposed in the literature. Results have demonstrated the ability of the GP in finding a good fuzzy strategy, which can effectively control the axial xenon oscillations.

Roberto P. Domingos; Gustavo H.F. Caldas; Cludio M.N.A. Pereira; Roberto Schirru

2003-01-01T23:59:59.000Z

332

Impacts of Stable Element Intake on C and I Dose Estimates - Implications for Proposed Yucca Mountain Repository  

SciTech Connect (OSTI)

The purpose of this study was to evaluate the influence of the intake of stable isotopes of carbon and iodine on the committed doses due to the ingestion of {sup 14}C and {sup 129}I. This was accomplished through the application of two different computational approaches. The first was based on the assumption that ground (drinking) water was the only source of intake of both {sup 14}C and {sup 129}I and stable carbon and stable iodine. For purposes of the second approach, the intake of {sup 14}C and {sup 129}I was still assumed to be only that in the ground (drinking) water, but the intake of stable carbon and stable iodine was assumed to be that in the drinking water plus other components of the diet. The doses were estimated using either a conversion formula or the applicable dose coefficients in Federal Guidance Reports No. 11 and No. 13. Serving as input for the analyses was the estimated maximum concentration of {sup 14}C or {sup 129}I that would be present in the ground water due to potential releases from the proposed Yucca Mountain high-level radioactive waste repository during the first 10,000 years after closure. The estimated concentrations of stable carbon and iodine were based on analyses of ground water samples collected in the Amargosa Valley, NV. Based on the accompanying analyses, three conclusions were reached. First, no dose estimate, using a conversion formula in which the ratios of the stable to radioactive isotopes of an element serve as input, should ever be made without including the stable element intake contributions from all components of the diet. Second, the study suggests that the dose coefficients for {sup 129}I in Federal Guidance Reports No. 11 and No. 12 which, in turn, are based on publications of the ICRP, may not be appropriate for application in developed nations of the world, especially those in which relatively large amounts of seafood are consumed and the use of iodized salt is common. The estimated average daily intake of stable iodine by the adult U.S. population, for example, is 400 pg. This is twice the value listed by the ICRP for Reference Man. This leads to a dose estimate that is too high by a factor of two. Although the ICRP accounts for stable isotope contributions through the selection of a corresponding biological half-time for iodine, the selection in this case may need reevaluation especially with respect to assessments of potential {sup 129}I releases from the proposed Yucca Mountain high-level radioactive waste repository. The third conclusion, which confirms earlier studies, is that an increase in the intake of either {sup 14}C or {sup 129}I will not lead to an increase in the dose if there is a corresponding increase in the intake of stable carbon or iodine such that the ratio of {sup 14}C or {sup 129}I to stable carbon or iodine does not change.

D.W. Moeller; M.T. Ryan; Lin-Shen C. Sun; R.N. Cherry Jr.

2004-12-21T23:59:59.000Z

333

Distribution of Radioactive Materials in the Absheron Peninsula, Azerbaijan - 13567  

SciTech Connect (OSTI)

The Absheron Peninsula forms the extreme Eastern part of Azerbaijan and juts into the Caspian Sea. The region has a long history of oil and gas exploration, transport, and processing and includes a number of abandoned chemical plants that were used in the separation of iodine from formation waters. As a result of lax environmental standards during the Soviet era, the industrial activity has led to serious contamination from oils residues, heavy metals and naturally occurring radioactive materials (NORM). Radiometric surveys performed over a wide range of the Absheron Peninsula showed generally low NORM concentrations. However, radiation levels two to three orders of magnitude above background levels were detected at two abandoned iodine separation plants near the capital city, Baku. These elevated radiation levels are mainly due to Ra-226 and U-238 with lower contributions from Ra-228 and U-235. (authors)

Vandergraaf, Tjalle T. [Consultant, Pinawa, MB, R0E 1L0 (Canada)] [Consultant, Pinawa, MB, R0E 1L0 (Canada); Mamedov, Gudrat G.; Ramazanov, Mahammadali A.; Badalov, Vatan H. [Baku State University, Baku (Azerbaijan)] [Baku State University, Baku (Azerbaijan); Naghiyev, Jalal A. [Institute of Radiation Problems of ANAS, Baku (Azerbaijan)] [Institute of Radiation Problems of ANAS, Baku (Azerbaijan); Mehdiyeva, Afat A. [National Aerospace Agency of Ministry of Defense Industry, Baku (Azerbaijan)] [National Aerospace Agency of Ministry of Defense Industry, Baku (Azerbaijan)

2013-07-01T23:59:59.000Z

334

Effects of simulated fission products on the mechnical properties of zircaloy-2  

SciTech Connect (OSTI)

Room temperature tensile tests were carried out on Zircaloy-2 specimens exposed to the simulated fission products tellurium, selenium, bromine, iodine, cadmium, indium, antimony, and molybdenum up to 3.6 Ms (1000 h) in the temperature range from 623 to 973 K. Exposure at 623 or 773 K did not significantly affect either strength or elongation values of Zircaloy-2, irrespective of the chemical environment. All specimens showed high reduction of area and ductile fracture morphology. Exposure to these elements at 973 K, on the other hand, results in a general reduction of the tensile properties at room temperature; in fact, iodine, bromine, and molybdenum cause nonductile fracture with little or no reduction of area. These results are significant, since molybdenum is an abundant fission product.

Kohli, R.; Holub, F.

1980-04-01T23:59:59.000Z

335

Nuclear waste management. Quarterly progress report, October-December 1979  

SciTech Connect (OSTI)

Progress and activities are reported on the following: high-level waste immobilization, alternative waste forms, nuclear waste materials characterization, TRU waste immobilization programs, TRU waste decontamination, krypton solidification, thermal outgassing, iodine-129 fixation, monitoring of unsaturated zone transport, well-logging instrumentation development, mobile organic complexes of fission products, waste management system and safety studies, assessment of effectiveness of geologic isolation systems, waste/rock interactions technology, spent fuel and fuel pool integrity program, and engineered barriers. (DLC)

Platt, A.M.; Powell, J.A. (comps.)

1980-04-01T23:59:59.000Z

336

Trapping phosphate anions inside the [Ag{sub 4}I]{sup 3+} framework: Structure, bonding, and properties of Ag{sub 4}I(PO{sub 4})  

SciTech Connect (OSTI)

Orange-red Ag{sub 4}I(PO{sub 4}) crystallizes in the monoclinic system, space group P2{sub 1}/m (No. 11), with the unit cell dimensions a=9.0874(6) A, b=6.8809(5) A, c=11.1260(7) A, {beta}=109.450(1){sup o}, and Z=4. The crystal structure is fully ordered; it comprises the silver-iodine three-dimensional positively charged framework hosting the tetrahedral PO{sub 4}{sup 3-} guest anions. The framework features high coordination numbers for iodine and manifold Ag-Ag bonds ranging from 3.01 to 3.46 A. The Ag-Ag interaction is bonding, it involves silver 4d and 5s orbitals lying, together with the orbitals of iodine, just below the Fermi level. Though the orbitals of silver and iodine define the conducting properties of the title compound, the interaction between the framework and the guest anions is also important and is responsive to the number of the silver atoms surrounding the PO{sub 4}{sup 3-} tetrahedra. Ag{sub 4}I(PO{sub 4}) melts incongruently at 591 K and produces a mixture of the silver phosphate and an amorphous phase upon cooling. Pure Ag{sub 4}I(PO{sub 4}) is a poor conductor with a room temperature conductivity of 3x10{sup -6} S m{sup -1}. The discrepancies between the properties observed here and those reported previously in the literature are discussed. - Graphical abstract: Regular [PO{sub 4}] tetrahedra fill large voids in the Ag-I framework to form a host-guest compound, Ag{sub 4}I(PO{sub 4}). It has a perfectly ordered crystal structure, atypical for this kind of compounds, rendering the study of the manifold Ag-Ag bonds and the host-guest interaction. However, this ordering leads to low ionic conductivity.

Oleneva, Olga S.; Kirsanova, Maria A.; Shestimerova, Tatiana A.; Abramchuk, Nikolay S.; Davliatshin, Dmitry I.; Bykov, Mikhail A. [Department of Chemistry, Lomonosov Moscow State University (Russian Federation); Dikarev, Evgeny V. [Department of Chemistry, University at Albany (United States); Shevelkov, Andrei V. [Department of Chemistry, Lomonosov Moscow State University (Russian Federation)], E-mail: shev@inorg.chem.msu.ru

2008-01-15T23:59:59.000Z

337

Nuclear waste management. Quarterly progress report, January-March 1980  

SciTech Connect (OSTI)

Reported are: high-level waste immobilization, alternative waste forms, nuclear waste materials characterization, TRU waste immobilization, TRU waste decontamination, krypton solidification, thermal outgassing, iodine-129 fixation, unsaturated zone transport, well-logging instrumentation development, mobile organic complexes of fission products, waste management system and safety studies, assessment of effectiveness of geologic isolation systems, waste/rock interactions, engineered barriers, criteria for defining waste isolation, and spent fuel and pool component integrity. (DLC)

Platt, A.M.; Powell, J.A. (comps.)

1980-06-01T23:59:59.000Z

338

Identification and differentiation of individual beta emitters in waste mixtures by liquid scintillation spectrometry  

E-Print Network [OSTI]

carbon-14, tritium, and iodine-125 liquid scintillation wastes, provided that the activity and isotopes present can be documented. This legislation has generated a significant interest in developing a quick, cost efficient method of identificatior.... Differentiation of various components within a two isotope mixture, and the detection level of a small activity of one nuclide in a large activity of a second radioisotope was examined. A catalogue of spectra, including the isotopic ratio of each component...

Siskel, Robin Lynn

1988-01-01T23:59:59.000Z

339

Synthesis of N-formyl-3,4-di-t-butoxycarbonyloxy-6(trimethylstannyl)-L-phenylalanine ethyl ester and its regioselective radiofluorodestannylation to 6-[{sup 18}F]fluoro-1-dopa  

DOE Patents [OSTI]

A process is revealed for forming a 6-fluoro derivative of compounds in the L-Dopa family comprising the steps of protecting the groups attached to the benzene ring in the compound followed by serially reacting the protected compound with (a) iodine and silver trifluoroacetic acid; (b) Bb{sub 3}; (c) dit-butyldicarbonate; (d) hexamethyltin; (e) a fluoro compound; (f) hydrobromic acid; and (g) raising the pH to {<=}7. 1 fig.

Satyamurthy, N.; Barrio, J.R.; Bishop, A.J.; Namavari, M.; Bida, G.T.

1996-04-23T23:59:59.000Z

340

Proceedings of the XI International Symposium on Gas Flow and Chemical Lasers and High Power Laser Conference, Edinburgh, UK 25-30 August 1996, SPIE Vol. 3092, ed. H.J. Baker, pp. 758-763 (1997).  

E-Print Network [OSTI]

Proceedings of the XI International Symposium on Gas Flow and Chemical Lasers and High Power Laser of 20 mm were obtained in aluminum and 41 mm in carbon steel using an N2 gas assist and 5-6 kW of power study of cutting thick aluminum and steel with a chemical oxygen-iodine laser using an N2 or O2 gas

Carroll, David L.

Note: This page contains sample records for the topic "iodine phos phorus" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


341

Positron emission tomographic imaging of tumors using monoclonal antibodies. Progress report, April 15, 1992--October 31, 1992  

SciTech Connect (OSTI)

This research project is developing methods for utilizing positron emission tomography (PET) to increase the clinical potential of radiolabeled monoclonal antibodies (MAbs). This report describes the development of methods for labeling MAbs and their fragments with positron-emitting halogen nuclides, fluorine-18 and iodine-124. These nulides were selected because of the widespread availability of F-18 and because of our extensive experience in the development of new protein radiohalogenation methods.

Zalutsky, M.R.

1992-08-01T23:59:59.000Z

342

Positron emission tomographic imaging of tumors using monoclonal antibodies  

SciTech Connect (OSTI)

This research project is developing methods for utilizing positron emission tomography (PET) to increase the clinical potential of radiolabeled monoclonal antibodies (MAbs). This report describes the development of methods for labeling MAbs and their fragments with positron-emitting halogen nuclides, fluorine-18 and iodine-124. These nulides were selected because of the widespread availability of F-18 and because of our extensive experience in the development of new protein radiohalogenation methods.

Zalutsky, M.R.

1992-08-01T23:59:59.000Z

343

The effects of temperature on thyroid hormone binding to serum proteins in sea turtles  

E-Print Network [OSTI]

vertebrates, has the capability of sequestering iodine and synthesizing iodoproteins. In mammals this gland arises from endoderm of the embryonic pharynx between the first and second pharyngeal pouches (Boyd, 1964). It synthesizes two hormones, tri... in vertebrates. In addition to these morphological actions, thyroid hormones influence oxygen consumption and overall metabolic rate (Gorbman et al. , 1983). Thus This thesis folloms the style and format of ~Gener 1 and ~tom aratl e ~tndoorinoto...

Haynes, Shane Patrick

2012-06-07T23:59:59.000Z

344

Environmental Levels Of 129I Present In Bovine Thyroid And Fresh Water In Argentina  

SciTech Connect (OSTI)

Concentrations of {sup 129}I in bovine thyroid and fresh water samples coming from all over Argentina were analyzed by Accelerator Mass Spectrometry (AMS) and total iodine present in samples by Gas Chromatography (GC) and Inductive Coupled Plasma Mass Spectrometry (ICP-MS), respectively. Once we complete this study, it will be the first set of data of this kind from an extended region of the south American subcontinent.

Negri, A. E.; Arazi, A.; Carnellia, P. F. F.; Barbara, E. de; Figueira, J. M.; Fimiani, L.; Heimanna, D. M.; Zalazara, L. [Laboratorio TANDAR, CNEA, Av. Gral. Paz 1499, B1650KNA, San Martin, Buenos Aires (Argentina); Fernandez Niello, J. [Laboratorio TANDAR, CNEA, Av. Gral. Paz 1499, B1650KNA, San Martin, Buenos Aires (Argentina); Universidad Nacional de San Martin, Campus Miguelete, B1650BWA, Buenos Aires (Argentina); La Gamma, A. M. [Gerencia Quimica, CNEA, Av. Gral. Paz 1499, B1650KNA, San Martin, Buenos Aires (Argentina); Wallner, A. [VERA-Laboratory, Faculty of Physics, University of Vienna, Waehringer Str. 17, A-1090 Wien (Austria)

2010-08-04T23:59:59.000Z

345

REPRODUCTIVE TOXINS OSHA Laboratory Standard Definition: Reproductive toxin means chemicals  

E-Print Network [OSTI]

acetate 111-15-9 Ethylene glycol monomethyl ether acetate 110-49-6 Ethylene thiourea 96-45-7 Etoposide-73-2 Iodine-131 24267-56-9 Isotretinoin 4759-48-2 Lead Lithium carbonate 554-13-2 Lithium citrate 919-16-4 Lorazapam 846-49-1 Lovastatin 75330-75-5 Medroxyprogesterone acetate 71-58-9 Megestrol acetate 595

Jalali. Bahram

346

New Approaches for Passivation of Crystalline and Amorphous Silicon: Cooperative Research and Development Final Report, CRADA Number CRD-09-351  

SciTech Connect (OSTI)

New approaches of passivating crystalline, multicrystalline, and amorphous silicon will be explored. These will include the use of aqueous solution of KCN and a proprietary composition formulated by Mallinckrodt Baker, Inc. The surface passivation will be compared with that provided by an iodine-ethanol solution, and bulk passivation will be compared with that of H-passivation obtained by silicon nitride, in a fire-through process.

Sopori, B.

2012-09-01T23:59:59.000Z

347

Normal coordinate analysis of trimethyl-antimony oxide  

E-Print Network [OSTI]

and from Columbia Organic Chemicals, Co. , Inc. Anhydrous ether, from J. T. Baker Chemical Company, was dried over sodium wire. Red and white phosphorus were obtained from Mallinckrodt Chemical Works. Sodium thiosulfate was purchased from Merck and Co.... Silver nitrate was obtained from Sargent-Welch Scientific Company. Anhydrous calcium chloride, from Matheson, Coleman, and Bell, was oven-dried at 110 before use. Antimony trichloride, methanol, magnesium turnings, and iodine were all obtained from...

Morris, Wayne A

2012-06-07T23:59:59.000Z

348

Use of CAP88 PC to infer differences in the chemical form of I-129 emitted from a fuel reprocessing facility  

SciTech Connect (OSTI)

Emissions of 129I from nuclear fuel separations conducted at the Hanford Site in Washington State have been occurring since the 1940s. Fuel separation on the Hanford Site stopped in 1988, but emissions of 129I have continued as venting of the building occurred. In this study, atmospheric measurements of 129I concentrations were coupled with an EPA approved plume dispersion model (CAP-88PC) to evaluate the effectiveness of the dispersion model for estimating ambient concentrations at the Hanford Site. This evaluation led to the hypothesis of different chemical forms of iodine being emitted over the years; this hypothesis was developed as an explanation for the model agreeing with measurements over some time periods, but not over all time periods. The model was then run with modified emissions to simulate the short atmospheric half-life of the suspected reactive chemical form of iodine being emitted. This modification resulted in good agreement between the modeled and measured concentrations over the entire 20 year study period, and provided evidence that the hypothesis of a reactive form of iodine being emitted was correct.

Fritz, Brad G.; Phillips, Nathan RJ

2013-06-17T23:59:59.000Z

349

Singlet oxygen generation according to flame-sheet and finite-rate chlorine/BHP reaction models. [Basic Hydrogen Peroxide  

SciTech Connect (OSTI)

In a flowing chemical oxygen--iodine laser, the photon energy is emitted by excited iodine atoms. These atoms are produced by energy transfer from O[sub 2]([sup 1][Delta]) after molecular iodine is dissociated upon mixing and reaction with the O[sub 2]([sup 1][Delta]). The generation of singlet delta oxygen, O[sub 2]([sup 1][Delta]), following gaseous chlorine diffusion into and reaction with liquid basic hydrogen peroxide (solution of KOH or NaOH in H[sub 2]O[sub 2] and H[sub 2]O) is investigated. Both flame-sheet and finite-rate reaction models for Cl[sub 2]/BHP are developed. A closed-form solution for the O[sub 2]([sup 1][Delta]) yield is obtained with the flame-sheet analysis, while a solution involving an integral equation is derived with the finite-rate analysis. The models are applied to a rotating disk type O[sub 2]([sup 1][Delta]) generator for illustration. The results do not differ greatly between the two models, and they show favorable agreement with reported experimental data.

Quan, V.; Copeland, D.A.; Blauer, J.A.; Rodriguez, S.E. (Rockwell International, Canoga Park, CA (United States). Rocketdyne Div.)

1994-05-01T23:59:59.000Z

350

Air pathway report: Phase I of the Hanford Environmental Dose Reconstruction Project  

SciTech Connect (OSTI)

Phase 1 of the air-pathway portion of the Hanford Environmental Dose Reconstruction (HEDR) Project sought to determine whether dose estimates could be calculated for populations in the 10 counties nearest the Hanford Site from atmospheric releases of iodine-131 from the site from 1944--1947. Phase 1 demonstrated the following: HEDR-calculated source-term estimates of iodine-131 releases to the atmosphere were within 20% of previously published estimates; calculated vegetation concentrations of iodine-131 agree well with previously published measurements; the highest of the Phase 1 preliminary dose estimates to the thyroid are consistent with independent, previously published estimates of doses to maximally exposed individuals; and, relatively crude, previously published measurements of thyroid burdens for Hanford workers are in the range of average burdens that the HEDR model estimated for similar reference individuals'' for the period 1944--1947. Preliminary median dose estimates summed over the year 1945--1947 for the primary pathway, air-pasture-cow-milk-thyroid, ranged from low median values of 0.006 rad for upwind adults who obtained milk from backyard cows not on pasture to high median values of 68.0 rad for downwind infants who drank milk from pasture-fed cows. Extremes of the estimated range are a low of essentially zero to upwind adults and a high of almost 3000 rem to downwind infants. 37 refs., 37 figs., 2 tabs.

Not Available

1991-07-01T23:59:59.000Z

351

Z-(R,R)-IQNP shows higher brain and heart uptake in rats than IDEX and 4IQNB  

SciTech Connect (OSTI)

Z-(R)-1-Azabicyclo[2.2.2]oct-3-yl (R)-{alpha}-hydroxy-{alpha}-(1-iodo-1-propen-3-yl)-{alpha}-phenylacetate (Z-(R,R)-IQNP) shows potential for the in vivo imaging of muscarinic receptors (mAChR) by SPECT. In vivo biodistribution studies show high uptake and prolonged retention in areas of the brain containing mAChR. We compared the biodistribution of Z-(R,R)-IQNP with 4-iodoexetimide (IDEX) and R-3 quinuclidinyl S-4-iodobenzilate (41QNB), two established muscarinic imaging agents. IDEX was labeled with iodine-125, 4IQNB was labeled with iodine-131 and IQNP was labeled with iodine-123. A solution containing the three compounds was injected in the same rat (n=5/time point). Animals were sacrificed at 30, 120, and 240 minutes and the levels of the three radioisotopes determined in various tissues. Z-(R,R)-IQNP was retained at twice the level as compared to IDEX and significantly higher than 4-IQNB in the hear and regions of the brain (Table). Z-(R,R)-IQNP also demonstrated low liver uptake as compared to IDEX. These data indicate that Z-(R,R)-IQNP is an attractive candidate for the imaging of mAChR by SPECT.

McPherson, D.W.; Ambrose, K.R.; Luo, H. [Oak Ridge National Lab., TN (United States)] [and others

1996-05-01T23:59:59.000Z

352

Carbon microspheres from ethanol at low temperature: Fabrication, characterization and their use as an electrocatalyst support for methanol oxidation  

SciTech Connect (OSTI)

Highlights: ? Carbon microbeads were prepared by the carbonization of ethanol at low temperature. ? The low temperature carbonization of ethanol was catalyzed by iodine. ? Carbon microbeads can serve as ideal candidate for catalyst supports. -- Abstract: Carbon microspheres (CMSs) with a diameter range of 23 ?m were prepared by the iodine-catalyzed carbonization of ethanol at low temperatures by solvothermal synthesis. The reaction time, concentrations of reactants, temperatures, different alcohols as carbon precursors and reaction environments were systematically altered to determine the optimal synthesis conditions. The size and shape were characterized by scanning and transmission electron microscopy and their structure was characterized by X-ray powder diffraction and Raman spectroscopy. Energy dispersive X-ray spectroscopy, Fourier transform infrared and X-ray photoelectron spectroscopy showed that abundant oxygen-containing functional groups remain on the surface of the carbon spheres. The formation mechanism involves iodine promotion of the oxidation of ethanol, which results in formation of the CMSs. The specific activity of the CMS-supported Pt catalyst is higher than that of a commercial Pt catalyst from E-TEK or the unsupported Pt catalyst.

Lian, Suoyuan [Institute of Functional Nano and Soft Materials and Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Soochow University, Suzhou 215123 (China) [Institute of Functional Nano and Soft Materials and Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Soochow University, Suzhou 215123 (China); School of Light Industry and Chemical Engineering, Dalian Polytechnic University, Dalian 116034 (China); Ming, Hai; Huang, Hui [Institute of Functional Nano and Soft Materials and Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Soochow University, Suzhou 215123 (China)] [Institute of Functional Nano and Soft Materials and Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Soochow University, Suzhou 215123 (China); Kang, Zhenhui, E-mail: zhkang@suda.edu.cn [Institute of Functional Nano and Soft Materials and Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Soochow University, Suzhou 215123 (China)] [Institute of Functional Nano and Soft Materials and Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Soochow University, Suzhou 215123 (China); Liu, Yang [Institute of Functional Nano and Soft Materials and Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Soochow University, Suzhou 215123 (China)] [Institute of Functional Nano and Soft Materials and Jiangsu Key Laboratory for Carbon-Based Functional Materials and Devices, Soochow University, Suzhou 215123 (China)

2012-11-15T23:59:59.000Z

353

Features of coal dust dynamics at action of differently oriented forces in granular filtering medium  

E-Print Network [OSTI]

The process of the coal dust particles transportation and structurization in the experimental horizontal model of air filter with the cylindrical coal adsorbent granules as in the iodine air filter at the nuclear power plant is researched. In the investigated case the vector of carrying away force of air flow and the vector of gravitation force are mutually perpendicular, and the scattering of the dust particles on the granules occurs in the normal directions. It is found that the phenomenon of non controlled spontaneous sharp increase of aerodynamic resistance in the iodine air filter under the big integral volumes of filtered air and the big masses of introduced coal dust particles is not observed at the described experimental conditions in distinction from the case of the parallel orientation of this forces as in the vertical iodine air filters at the nuclear power plant. The quantitative measurements of the main parameters of the process of the dust masses transportation and structurization are made on a ...

Neklyudov, I M; Poltinin, P Ya; Ledenyov, O P

2013-01-01T23:59:59.000Z

354

Tritium Movement and Accumulation in the NGNP System Interface and Hydrogen Plant  

SciTech Connect (OSTI)

Tritium movement and accumulation in a Next Generation Nuclear Plant with a hydrogen plant using a high temperature electrolysis process and a thermochemical water splitting sulfur iodine process are estimated by the numerical code THYTAN as a function of design, operational, and material parameters. Estimated tritium concentrations in the hydrogen product and in process chemicals in the hydrogen plant of the Next Generation Nuclear Plant using the high temperature electrolysis process are slightly higher than the drinking water limit defined by the U.S. Environmental Protection Agency and the limit in the effluent at the boundary of an unrestricted area of a nuclear plant as defined by the U.S. Nuclear Regulatory Commission. However, these concentrations can be reduced to within the limits through use of some designs and modified operations. Tritium concentrations in the Next Generation Nuclear Plant using the Sulfur-Iodine Process are significantly higher as calculated and are affected by parameters with large uncertainties (i.e., tritium permeability of the process heat exchanger, the hydrogen concentration in the heat transfer and process fluids, the equilibrium constant of the isotope exchange reaction between HT and H2SO4). These parameters, including tritium generation and the release rate in the reactor core, should be more accurately estimated in the near future to improve the calculations for the NGNP using the Sulfur-Iodine Process. Decreasing the tritium permeation through the heat exchanger between the primary and secondary circuits may be an an effective measure for decreasing tritium concentrations in the hydrogen product, the hydrogen plant, and the tertiary coolant.

Hirofumi Ohashi; Steven R. Sherman

2007-06-01T23:59:59.000Z

355

Rapid sonochemical preparation of shape-selective lead iodide  

SciTech Connect (OSTI)

Graphical abstract: SEM morphologies of various PbI2 products obtained with the iodine concentration of 6.7 g/L and irradiation time of 1 minute at the reaction temperatures of 35 C (a), 25 C (b), and 15 C (c). Highlights: ? PbI{sub 2} with various morphologies were rapidly formed at room temperature. ? We could well control the morphologies of PbI{sub 2} by changing reaction conditions. ? The PbI{sub 2} films could better resist rolling in a liquid media. -- Abstract: Lead iodide (PbI{sub 2}) films/crystals with various nano/micro morphologies (e.g., Nanoflake, block and microrod) were rapidly synthesized by taking advantage of a simple sonochemical method. The PbI{sub 2} crystals with uniform nanoflake structures could be fabricated directly on lead foils with the irradiation time as short as 36 s via interfacial reaction between lead foils and elemental iodine in ethanol at ambient temperature. It was found experimentally that the morphologies of the resulting thin films/crystals could be well controlled by the adjustment of several parameters including irradiation time, reaction solvents, iodine concentration, ultrasonic power, and reaction temperature. Most importantly, the resultant PbI{sub 2} films are stable enough to resist rolling under the drastic ultrasound irradiation in a liquid media. This method is believed to be the fastest way for in situ fabrication of morphology-controlled semiconductor films on various metal substrates for subsequent applications related to the other metal iodide or metal sulfide semiconductor films.

Huang, Baojun [Key Laboratory of Micro-Nano Materials for Energy Storage and Conversion of Henan Province, Institute of Surface Micro and Nano Materials, Xuchang University, Xuchang, Henan 461000 (China)] [Key Laboratory of Micro-Nano Materials for Energy Storage and Conversion of Henan Province, Institute of Surface Micro and Nano Materials, Xuchang University, Xuchang, Henan 461000 (China); He, Qin [College of Chemistry and Chemical Engineering, Xuchang University, Xuchang, Henan 461000 (China)] [College of Chemistry and Chemical Engineering, Xuchang University, Xuchang, Henan 461000 (China); Fa, Wenjun; Li, Pinjiang; Zhang, Yange [Key Laboratory of Micro-Nano Materials for Energy Storage and Conversion of Henan Province, Institute of Surface Micro and Nano Materials, Xuchang University, Xuchang, Henan 461000 (China)] [Key Laboratory of Micro-Nano Materials for Energy Storage and Conversion of Henan Province, Institute of Surface Micro and Nano Materials, Xuchang University, Xuchang, Henan 461000 (China); Zheng, Zhi, E-mail: zzheng@xcu.edu.cn [Key Laboratory of Micro-Nano Materials for Energy Storage and Conversion of Henan Province, Institute of Surface Micro and Nano Materials, Xuchang University, Xuchang, Henan 461000 (China)] [Key Laboratory of Micro-Nano Materials for Energy Storage and Conversion of Henan Province, Institute of Surface Micro and Nano Materials, Xuchang University, Xuchang, Henan 461000 (China)

2012-09-15T23:59:59.000Z

356

Quantitative studies of transfer in vivo of low density, Sf 12-60, and Sf 60-400 lipoproteins between plasma and arterial intima in humans  

SciTech Connect (OSTI)

To assess the potential of various plasma lipoprotein classes to contribute to the lipid content of the arterial intima, influx and efflux of these plasma lipoprotein fractions into and from the intima of human carotid arteries were measured in vivo. While low density lipoprotein (LDL) is known to transfer from plasma into the arterial wall, there is less information on the atherogenic potential of lipoproteins of intermediate density (Sf 12-60) or of very low density (Sf 60-400). Aliquots of the same lipoprotein (LDL, Sf 12-60 lipoprotein particles, or Sf 60-400 lipoprotein particles) iodinated with iodine-125 and iodine-131 were injected intravenously 18-29 hours and 3-6 hours, respectively, before elective surgical removal of atheromatous arterial tissue, and the intimal clearance of lipoproteins, lipoprotein influx, and fractional loss of newly entered lipoproteins were calculated. Intimal clearance of Sf 60-400 particles was not detectable (less than 0.3 microliter x hr-1 x cm-2), whereas the average value for both LDL and Sf 12-60 lipoprotein particles was 0.9 microliter x hr-1 x cm-2. Since the fractional loss of newly entered LDL and Sf 12-60 lipoprotein particles was also similar, the results suggest similar modes of entry and exit for these two particles. However, due to lower plasma concentrations of Sf 12-60 lipoproteins as compared with LDL, the mass influx of cholesterol in the Sf 12-60 particles was on the order of one 10th of that in LDL, and that of apolipoprotein B was about one 20th.

Shaikh, M.; Wootton, R.; Nordestgaard, B.G.; Baskerville, P.; Lumley, J.S.; La Ville, A.E.; Quiney, J.; Lewis, B. (Guys Hospital, London, (United Kingdom))

1991-05-01T23:59:59.000Z

357

Microsoft Word - SyrB2.doc  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

6 6 Figure 1. Crystal structure of the non-heme iron halogenase SyrB2. A. Overall structure showing cupin fold. B. Active site iron coordination. Iron (brown) is coordinated by two histidines, α- ketoglutarate (grey sticks), water (cyan), and chloride (green). Crystal Structure of Iron-dependent Halogenase Over 4000 natural products contain halide atoms such as chlorine, bromine, or iodine. 1 Halogenated natural products are medically valuable and include antibiotics (chlorotetracycline and vancomycin), antitumor agents (rebeccamycin and calichemycin), and human thyroid hormone (thyroxine). 2 Halogenation is essential to the biological activity and chemical reactivity of such compounds, and often generates versatile molecular building

358

Improved method for detection of starch hydrolysis  

SciTech Connect (OSTI)

A new starch hydrolysis detection method which does not rely on iodine staining or the use of color-complexed starch is described. A linear relationship was obtained with agar-starch plates when net clearing zones around colonies of yeasts were plotted against enzyme levels (semilogarithm scale) produced by the same yeast strains in liquid medium. A similar relationship between starch clearing zones and alpha-amylase levels from three different sources was observed. These observations suggest that the method is useful in mutant isolations, strain improvement programs, and the prediction of alpha-amylase activities in culture filtrates or column effluents. (Refs. 18).

Ohawale, M.R.; Wilson, J.J.; Khachatourians, G.G.; Ingledew, W.M.

1982-09-01T23:59:59.000Z

359

Studies on the Use of Liquid Surface Passivation for Lifetime Measurements on Good-Quality Silicon Wafers  

SciTech Connect (OSTI)

We evaluated several liquid passivants, viz. solutions of iodine ethanol (IE), quinhydrone methanol (QHM), and potassium cyanide (KCN), for measuring minority-carrier lifetime. Lifetime was measured by the WCT-100 (Sinton Instruments) and WT-2000 (Semilab). Our results show that both IE and QHM passivation are reliable mechanisms. We also find that the KCN solution is moderately passivating on oxidized surfaces, but is only minimally effective on bare Si surfaces. This paper presents details of our studies. In particular, the effect of illumination on IE-passivated surfaces and possible reasons for variations in lifetime measurement are discussed.

Devayajanam, S.; Rupnowski, P.; Shet, S.; Sopori, B. L.; Ravindra, N. M.; Caskey, D.; Chang, J.; Covington, J.

2011-01-01T23:59:59.000Z

360

Quantitative and qualitative evaluation of the bacterial flora of stallion semen  

E-Print Network [OSTI]

Averages 10. 3 8. 5 7. 1 79. 4 The ejaculates from each stallion were collected 1 twice a week using a standard collection technique modified by employing a Missouri USDA style artificial vagina (AV). The AV liners were washed with povidone iodine soap... for 30 minutes. The stallion's penis was washed with a 3/o hexachlorophene soap, rinsed with water and dried with a sterile towel immediately prior to each collection. Each AV liner was tested for significant levels of contamination prior to each...

Simpson, Russell Bruce

2012-06-07T23:59:59.000Z

Note: This page contains sample records for the topic "iodine phos phorus" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


361

Experimental development of nuclear pumped laser candidate inertial confinement fusion driver  

SciTech Connect (OSTI)

This progress report is submitted at the end of the first year of a 3-year project grant studying development of a nuclear pumped atomic iodine laser. The first section of the report will provide background on the study and briefly describe the original plans for the 3-year project. The second section will detail the work done to date. Included will be a description of the preparations made for experimentation, as well as some preliminary results recently obtained. Plans for the upcoming budget year are covered in the accompanying proposal, Project Plans for 1989--1990.''

Miley, G.H.

1989-05-31T23:59:59.000Z

362

Experimental development of nuclear pumped laser candidate inertial confinement fusion driver. Technical progress report, Phase 1, 1988--1989  

SciTech Connect (OSTI)

This progress report is submitted at the end of the first year of a 3-year project grant studying development of a nuclear pumped atomic iodine laser. The first section of the report will provide background on the study and briefly describe the original plans for the 3-year project. The second section will detail the work done to date. Included will be a description of the preparations made for experimentation, as well as some preliminary results recently obtained. Plans for the upcoming budget year are covered in the accompanying proposal, ``Project Plans for 1989--1990.``

Miley, G.H.

1989-05-31T23:59:59.000Z

363

Effect of mixing on polymerization of styrene  

E-Print Network [OSTI]

Model R404 Differential Refractometer (DRI) was used to continuously monitor the reactor effluent. A portion of the liquid medium from the feed tank was used as a static reference in the DRI. To introduce a change in the refractive index of the fluid... the mixing pattern was made by desolving iodine crystals in the styrene used for pulse generation. A strobotact was used to monitor the rpm of the impeller shaft. To reduce the amount of degassing occurring in the reactor during the runs, the liquid...

Treybig, Michael Norris

2012-06-07T23:59:59.000Z

364

Effects of membrane fluidity on hormone action in cultured cells  

E-Print Network [OSTI]

av intracellular protein degradation, while growth of the Wt cell line in cholesterol-free media resulted in an increased effectiveness of only 10% serum. The control rates of protein synthesis are increased in the Wt when grown in either 100PN... ue 12 Procedure for Measurin Rates of Protein Degradation 13 Procedure for Measurin Rates of Protein S nthesis 15 Procedure for Measurin Rates of C-2-deo glucose U take 14 16 Procedure for Iodination of Porcine Insulin 17 Procedure for Measuring...

Williams, Gary Wayne

1982-01-01T23:59:59.000Z

365

Laser studies of chemical reaction and collision processes  

SciTech Connect (OSTI)

This work has concentrated on several interrelated projects in the area of laser photochemistry and photophysics which impinge on a variety of questions in combustion chemistry and general chemical kinetics. Infrared diode laser probes of the quenching of molecules with {open_quotes}chemically significant{close_quotes} amounts of energy in which the energy transferred to the quencher has, for the first time, been separated into its vibrational, rotational, and translational components. Probes of quantum state distributions and velocity profiles for atomic fragments produced in photodissociation reactions have been explored for iodine chloride.

Flynn, G. [Columbia Univ., New York, NY (United States)

1993-12-01T23:59:59.000Z

366

Engineering Design Elements of a Two-Phase Thermosyphon to Trannsfer NGNP Nuclear Thermal Energy to a Hydrogen Plant  

SciTech Connect (OSTI)

Two hydrogen production processes, both powered by a Next Generation Nuclear Plant (NGNP), are currently under investigation at Idaho National Laboratory. The first is high-temperature steam electrolysis, which uses both heat and electricity; the second is thermo-chemical production through the sulfur iodine process primarily using heat. Both processes require a high temperature (>850C) for enhanced efficiency; temperatures indicative of the NGNP. Safety and licensing mandates prudently dictate that the NGNP and the hydrogen production facility be physically isolated, perhaps requiring separation of over 100 m.

Piyush Sabharwal

2009-07-01T23:59:59.000Z

367

Cork Embedded Internal Features and Contrast Mechanisms with Del Using 18, 20, 30, 36 and 40 keV Synchrotron X-rays  

SciTech Connect (OSTI)

Images of the cork used for wine and other bottles are visualized with the use of diffraction-enhanced imaging (DEI) technique. Present experimental studies allowed us to identify the cracks, holes, porosity, and importance of soft-matter (soft-material) and associated biology by visualization of the embedded internal complex features of the biological material such as cork and its microstructure. Highlighted the contrast mechanisms above and below the K-absorption edge of iodine and studied the attenuation through a combination of weakly and strongly attenuating materials.

Rao, D.V.; Zhong, Z.; Akatsuka, T.; Yuasa, T.; Hasan, M.Z.; Takeda, T.

2010-01-01T23:59:59.000Z

368

Measurement of Fukushima Aerosol Debris in Sequim and Richland, WA and Ketchikan, AK  

SciTech Connect (OSTI)

Aerosol collections were initiated at several locations by PNNL shortly after the Great East Japan Earthquake of May 2011. Aerosol samples were transferred to laboratory high-resolution gamma spectrometers for analysis. Similar to treaty monitoring stations operating across the Northern hemisphere, iodine and other isotopes which could be volatilized at high temperature were detected. Though these locations are not far apart, they have significant variations with respect to water, mountain-range placement, and local topography. Variation in computed source terms will be shown to bound the variability of this approach to source estimation.

Miley, Harry S.; Bowyer, Ted W.; Engelmann, Mark D.; Eslinger, Paul W.; Friese, Judah I.; Greenwood, Lawrence R.; Haas, Derek A.; Hayes, James C.; Keillor, Martin E.; Kiddy, Robert A.; Kirkham, Randy R.; Landen, Jonathan W.; Lepel, Elwood A.; Lidey, Lance S.; Litke, Kevin E.; Morris, Scott J.; Olsen, Khris B.; Thompson, Robert C.; Valenzuela, Blandina R.; Woods, Vincent T.; Biegalski, Steven R.

2013-05-01T23:59:59.000Z

369

Power density axial oscillations induced by Xenon dynamics: Parameter identification via genetic algorithms  

Science Journals Connector (OSTI)

In this paper we describe the axial flux oscillations in \\{PWRs\\} by means of the Onega and Kisner model (1978), a two-point xenon oscillation model based on the one-group, one-dimensional neutron diffusion equation with nonlinear power reactivity feedback and on the nonlinear xenon and iodine balance equations. We investigate the feasibility of using genetic algorithms for estimating the effective nuclear parameters involved. This approach has the advantage of allowing the periodic re-estimation of the effective parameter values pertaining to each reactor on the basis of its recent history. By so doing, other effects, such as the burn up, are automatically taken into account.

M. Marseguerra; E. Zio; G. Torri

2003-01-01T23:59:59.000Z

370

Thyroid cancer incidence in relation to volcanic activity  

SciTech Connect (OSTI)

Environmental or genetic factors are sought to explain the high incidence of thyroid cancer in Iceland. At present, it is impossible to cite any environmental factor, particularly one related to the volcanic activity in the country, which could explain the high incidence of thyroid cancer in Iceland. However, the thyroid gland in Icelanders is very small due to the high intake of iodine from seafood. It is, therefore, easier for physicians to find thyroid tumors. Furthermore, genetic factors are very likely to be of great importance in the small, isolated island of Iceland.

Arnbjoernsson, E.A.; Arnbjoernsson, A.O.; Olafsson, A.

1986-01-01T23:59:59.000Z

371

Fallout: The experiences of a medical team in the care of a Marshallese population accidentally exposed to fallout radiation  

SciTech Connect (OSTI)

This report presents an historical account of the experiences of the Brookhaven Medical team in the examination and treatment of the Marshallese people following their accidental exposure to radioactive fallout in 1954. This is the first time that a population has been heavily exposed to radioactive fallout, and even though this was a tragic mishap, the medical findings have provided valuable information for other accidents involving fallout such as the recent reactor accident at Chernobyl. Particularly important has been the unexpected importance of radioactive iodine in the fallout in producing thyroid abnormalities.

Conard, R.A.

1991-01-01T23:59:59.000Z

372

Fallout: The experiences of a medical team in the care of a Marshallese population accidentally exposed to fallout radiation  

SciTech Connect (OSTI)

This report presents an historical account of the experiences of the Brookhaven Medical team in the examination and treatment of the Marshallese people following their accidental exposure to radioactive fallout in 1954. This is the first time that a population has been heavily exposed to radioactive fallout, and even though this was a tragic mishap, the medical findings have provided valuable information for other accidents involving fallout such as the recent reactor accident at Chernobyl. Particularly important has been the unexpected importance of radioactive iodine in the fallout in producing thyroid abnormalities.

Conard, R.A.

1991-12-31T23:59:59.000Z

373

Technical basis for internal dosimetry at Hanford  

SciTech Connect (OSTI)

The Hanford Internal Dosimetry Program, administered by Pacific Northwest Laboratory for the US Department of Energy, provides routine bioassay monitoring for employees who are potentially exposed to radionuclides in the workplace. This report presents the technical basis for routine bioassay monitoring and the assessment of internal dose at Hanford. The radionuclides of concern include tritium, corrosion products ({sup 58}Co, {sup 60}Co, {sup 54}Mn, and {sup 59}Fe), strontium, cesium, iodine, europium, uranium, plutonium, and americium,. Sections on each of these radionuclides discuss the sources and characteristics; dosimetry; bioassay measurements and monitoring; dose measurement, assessment, and mitigation and bioassay follow-up treatment. 78 refs., 35 figs., 115 tabs.

Sula, M.J.; Carbaugh, E.H.; Bihl, D.E.

1991-07-01T23:59:59.000Z

374

Roadmap to the Project: Experiments List  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

University of California, Los Angeles University of California, Los Angeles ‡ ‡ ‡ UCLA-1. Early Experimental Imaging of the Thyroid Gland Using Iodine-131 IN 1951, the University of California, Los Angeles conducted a series of tests on humans to study the uptake of radioiodine into the thyroid gland. Additional tests were made on patients at the Sawtelle Veteran's Hospital. The main purpose of this study was to test a new automatic scanner and recorder. Initial scans were made using a collimated gamma scintillation counter. This equipment enabled a record to be obtained on which an image of the gland was visible and which the researchers concluded was better than a total activity count for clinical studies of thyroid disease. The second set of scans was made on a frozen tissue preparation obtained from a terminal patient who had been given 3 millicuries of iodine-131, 14 hours before his death. The measured total activity of the thyroid gland at the time it was scanned was about 50 microcuries.

375

End-of-life destructive examination of light water breeder reactor fuel rods (LWBR Development Program)  

SciTech Connect (OSTI)

Destructive examination of 12 representative Light Water Breeder Reactor fuel rods was performed following successful operation in the Shippingport Atomic Power Station for 29,047 effective full power hours, about five years. Light Water Breeder Reactor fuel rods were unique in that the thorium oxide and uranium-233 oxide fuel was contained within Zircaloy-4 cladding. Destructive examinations included analysis of released fission gas; chemical analysis of the fuel to determine depletion, iodine, and cesium levels; chemical analysis of the cladding to determine hydrogen, iodine, and cesium levels; metallographic examination of the cladding, fuel, and other rod components to determine microstructural features and cladding corrosion features; and tensile testing of the irradiated cladding to determine mechanical strength. The examinations confirmed that Light Water Breeder Reactor fuel rod performance was excellent. No evidence of fuel rod failure was observed, and the fuel operating temperature was low (below 2580/sup 0/F at which an increased percentage of fission gas is released). 21 refs., 80 figs., 20 tabs.

Richardson, K.D.

1987-10-01T23:59:59.000Z

376

Iodide Sorption to Clays and the Relationship to Surface Charge and Clay Texture - 12356  

SciTech Connect (OSTI)

Iodine is assumed to behave conservatively in clay barriers around nuclear waste repositories and in natural sediments. Batch experiments tend to show little to no sorption, while in column experiments iodine is often retarded relative to tritiated water. Current surface complexation theory cannot account for negatively charged ion sorption to a negatively charged clay particle. Surface protonation and iodide sorption to clay minerals were examined using surface titrations and batch sorption experiments with a suite of clay minerals. Surface titrations were completed spanning a range of both pH values and ionic strengths. For reference, similar titrations were performed on pure forms of an Al-O powder. The titration curves were deconvoluted to attain the pKa distribution for each material at each ionic strength. The pKa distribution for the Al-O shows two distinct peaks at 4.8 and 7.5, which are invariant with ionic strength. The pKa distribution of clays was highly variable between the different minerals and as a function of ionic strength. Iodide sorption experiments were completed at high solid:solution ratios to exacerbate sorption properties. Palygorskite and kaolinite had the highest amount of iodide sorption and montmorillonite had the least. (authors)

Miller, Andrew; Kruichiak, Jessica; Tellez, Hernesto; Wang, Yifeng [Sandia National Laboratories, Albuquerque, NM 87185 (United States)

2012-07-01T23:59:59.000Z

377

Life cycle assessment of hydrogen production from S-I thermochemical process coupled to a high temperature gas reactor  

SciTech Connect (OSTI)

The purpose of this paper is to quantify the greenhouse gas (GHG) emissions associated to the hydrogen produced by the sulfur-iodine thermochemical process, coupled to a high temperature nuclear reactor, and to compare the results with other life cycle analysis (LCA) studies on hydrogen production technologies, both conventional and emerging. The LCA tool was used to quantify the impacts associated with climate change. The product system was defined by the following steps: (i) extraction and manufacturing of raw materials (upstream flows), (U) external energy supplied to the system, (iii) nuclear power plant, and (iv) hydrogen production plant. Particular attention was focused to those processes where there was limited information from literature about inventory data, as the TRISO fuel manufacture, and the production of iodine. The results show that the electric power, supplied to the hydrogen plant, is a sensitive parameter for GHG emissions. When the nuclear power plant supplied the electrical power, low GHG emissions were obtained. These results improve those reported by conventional hydrogen production methods, such as steam reforming. (authors)

Giraldi, M. R.; Francois, J. L.; Castro-Uriegas, D. [Departamento de Sistemas Energeticos, Facultad de Ingenieria, Universidad Nacional Autonoma de Mexico, Paseo Cuauhnahuac No. 8532, Col. Progreso, C.P. 62550, Jiutepec, Morelos (Mexico)

2012-07-01T23:59:59.000Z

378

Status of radioiodine control for nuclear fuel reprocessing plants  

SciTech Connect (OSTI)

This report summarizes the status of radioiodine control in a nuclear fuel reprocessing plant with respect to capture, fixation, and disposal. Where possible, we refer the reader to a number of survey documents which have been published in the last four years. We provide updates where necessary. Also discussed are factors which must be considered in developing criteria for iodine control. For capture from gas streams, silver mordenite and a silver nitrate impregnated silica (AC-6120) are considered state-of-the-art and are recommended. Three aqueous scrubbing processes have been demonstrated: Caustic scrubbing is simple but probably will not give an adequate iodine retention by itself. Mercurex (mercuric nitrate-nitric acid scrubbing) has a number of disadvantages including the use of toxic mercury. Iodox (hyperazeotropic nitric acid scrubbing) is effective but employs a very corrosive and hazardous material. Other technologies have been tested but require extensive development. The waste forms recommended for long-term storage or disposal are silver iodide, the iodates of barium, strontium, or calcium, and silver loaded sorbents, all fixed in cement. Copper iodide in bitumen (asphalt) is a possibility but requires testing. The selection of a specific form will be influenced by the capture process used.

Burger, L.L.; Scheele, R.D.

1983-07-01T23:59:59.000Z

379

Nuclear medicine program progress report for quarter ending March 31, 1991  

SciTech Connect (OSTI)

In this report the first fabrication and evaluation of an activated carbon-based osmium-194/iridium-194 generator system is described. Iridium-194 (t{sub {1/2}} = 19.2 h) decays by {Beta}{sup {minus}} emission (E{sub max} = 2.24 MeV) and is a potential candidate for radioimmunotherapy. An important characteristic is availability of {sup 194}Ir from decay of reactor-produced {sup 194}Os (t{sub {1/2}} = 6 y). A novel gas thermochromatographic method was developed for the one step conversion of metallic Os to OsO{sub 4} and subsequent separation and purification of OsO{sub 4}, which was then converted to the K{sub 2}OsCl{sub 6} for generator loading. The yield and the elution profile of carrier-free {sup 194}Ir, and {sup 194}Os breakthrough were determined for a prototype generator which was evaluated over a 10 month-period.l During this period several agents were also supplied to Medical Cooperative investigators, including iodine-123-labelled and iodine-125-labelled fatty acid analogues for studies at the Brookhaven National Laboratory. In addition, gold-198 and tungsten-188/-rhenium-188 generators were shipped to various investigators for therapeutic studies involving tumor-specific antibodies. 19 refs., 3 figs.

Knapp, F.F. Jr.; Ambrose, K.R.; Callahan, A.P.; McPherson, D.W.; Mirzadeh, S.; Srivastava, P.C.; Allred, J.F.; Hasan, A.; Lambert, C.R.; Lambert, S.J.; Rice, D.E.

1991-08-01T23:59:59.000Z

380

Thermochemical water-splitting cycle, bench-scale investigations and process engineering. Annual report, October 1, 1978-September 30, 1979  

SciTech Connect (OSTI)

A program to investigate thermochemical water splitting has been under way at General Atomic Company (GA) since October 1972. This document is an annual progress report of Department of Energy (DOE) sponsored process development work on the GA sulfur-iodine thermochemical water splitting cycle. The work consisted of laboratory bench-scale investigations, demonstration of the process in a closed-loop cycle demonstrator, and process engineering design studies. A bench-scale system, consisting of three subunits, has been designed to study the cycle under continuous flow conditions. The designs of subunit I, which models the main solution reaction and product separation, and subunit II, which models the concentration and decomposition of sulfuric acid, were presented in an earlier annual report. The design of subunit III, which models the purification and decomposition of hydrogen iodide, is given in this report. Progress on the installation and operation of subunits I and II is described. A closed-loop cycle demonstrator was installed and operated based on a DOE request. Operation of the GA sulfur-iodine cycle was demonstrated in this system under recycle conditions. The process engineering addresses the flowsheet design of a large-scale production process consisting of four chemical sections (I through IV) and one helium heat supply section (V). The completed designs for sections I through V are presented. The thermal efficiency of the process calculated from the present flowsheet is 47%.

Caprioglio, G.; McCorkle, K.H.; Besenbruch, G.E.; Rode, J.S.

1980-03-01T23:59:59.000Z

Note: This page contains sample records for the topic "iodine phos phorus" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


381

Roadmap to the Project: Experiments List  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Brookhaven National Laboratory Brookhaven National Laboratory BNL-1. Effectiveness of Iodine-131 in Diagnosing and Treating Graves = Disease and Metastatic Carcinoma of the Thyroid IN 1950, BROOKHAVEN National Laboratory conducted a study on the use of iodine-131 (I131) to treat patients with metastatic carcinoma of the thyroid or with Graves=disease. Patients for the study were sent to Brookhaven from Memorial Hospital in New York City. In the study, a therapeutic dose of 4 to 360 millicuries of I131 was given to the patients; the exact dose depended in part on the number of metastases and on previous radiation treatment. Graves=disease patients who were unsuitable for surgical therapy were treated with I131 in doses of 6 to 20 millicuries. The patients were monitored for hematological damage. Metabolic studies were also conducted, including study of the effects of radiation dose on renal tubular function. Twelve patients participated in the study, ranging in age from 15 to 63 years. Of the 12 patients, 8 were female. The study was conducted in conjunction with the Memorial Hospital and was funded by the U.S. Atomic Energy Commission. (Included in The DOE Roadmap of February 1995)

382

Thyroid absorbed dose for people at Rongelap, Utirik, and Sifo on March 1, 1954  

SciTech Connect (OSTI)

A study was undertaken to reexamine thyroid absorbed dose estimates for people accidentally exposed to fallout at Rongelap, Sifo, and Utirik Islands from the Pacific weapon test known as Operation Castle BRAVO. The study included: (1) reevaluation of radiochemical analysis, to relate results from pooled urine to intake, retention, and excretion functions; (2) analysis of neutron-irradiation studies of archival soil samples, to estimate areal activities of the iodine isotopes; (3) analysis of source term, weather data, and meteorological functions used in predicting atmospheric diffusion and fallout deposition, to estimate airborne concentrations of the iodine isotopes; and (4) reevaluation of radioactive fallout, which contaminated a Japanese fishing vessel in the vicinity of Rongelap Island on March 1, 1954, to determine fallout components. The conclusions of the acute exposure study were that the population mean thyroid absorbed doses were 21 gray (2100 rad) at Rongelap, 6.7 gray (670 rad) at Sifo, and 2.8 gray (280 rad) at Utirik. The overall thyroid cancer risk we estimated was in agreement with results published on the Japanese exposed at Nagasaki and Hiroshima. We now postulate that the major route for intake of fallout was by direct ingestion of food prepared and consumed outdoors. 66 refs., 13 figs., 25 tabs.

Lessard, E.T.; Miltenberger, R.P.; Conrad, R.A.; Musoline, S.V.; Naidu, J.R.; Moorthy, A.; Schopfer, C.J.

1985-03-01T23:59:59.000Z

383

CAUSE OF A MULTI-SPECIES RADIOIODINE PLUME THAT IS INCREASING IN CONCENTRATION  

SciTech Connect (OSTI)

Field and laboratory studies were carried out to understand the cause for steady increases in {sup 129}I concentrations emanating from radiological seepage basins located on the Savannah River Site. The basins were closed in 1988 by adding limestone and blast furnace slag and then capping with a RCRA low permeability engineered cover. Groundwater {sup 129}I concentrations in a well near the seepage basin in 1993 were 200 pCi L{sup -1} and are presently between 400 and 1000 pCi L{sup -1}. Iodine speciation in the plume was not uniform. Near the source, the iodine was comprised of 86% iodide, 2% iodate, and 12% organo-iodine (total activity = 178 pCi L{sup -1}). Whereas, groundwater iodine speciation 365 m down stream (25 m up stream from a wetland) was 0% iodide, 93% iodate, and 7% organo iodine. Batch desorption studies demonstrated that high concentrations of {sup 129}I could be incrementally desorbed from an archived seepage basin sediment sample by raising the pH. Batch sorption studies showed that iodate, IO{sub 3}{sup -}, sorbed more strongly than iodide, I{sup -}, to a subsurface clayey sediment, but equally well as iodide to a subsurface sandy sediment and a wetland sediment. Placing an organic-rich wetland sediment, but not nearby mineral sediments, under reducing (or microaerobic) conditions resulted in a large decrease in iodide K{sub d} values (from 73 to 10 mL g{sup -1}) and iodate K{sub d} values (from 80 to 7 mL g{sup -1}). Between pH and reduction-oxidation potential, it appears that pH seems to have a stronger influence on iodide and iodate sorption to mineral sediment. This may not be true for sediments containing higher concentrations of organic matter, such as the 7.6% organic matter sediment used in this study. First order calculations based on desorption studies with seepage basin sediments indicate that the modest increase of 0.7 pH units detected in the study site groundwater over the last 17 years since closure of the seepage basin may be sufficient to produce the observed increased groundwater {sup 129}I concentrations. Groundwater monitoring of the plume at the F-Area seepage basin has shown that the migration of many of the high risk radionuclides originally present at this complex site has been attenuated. However, {sup 129}I continues to leave the source at a rate that may have been exacerbated by the initial remediation efforts. This study underscores the important of identifying the appropriate in situ stabilization technologies for all contaminants present at a source term, especially if their geochemical behaviors differ.

Kaplan, D.

2010-09-30T23:59:59.000Z

384

Dual-energy contrast-enhanced breast tomosynthesis: optimization of beam quality for dose and image quality  

Science Journals Connector (OSTI)

Dual-energy contrast-enhanced breast tomosynthesis is a promising technique to obtain three-dimensional functional information from the breast with high resolution and speed. To optimize this new method, this study searched for the beam quality that maximized image quality in terms of mass detection performance. A digital tomosynthesis system was modeled using a fast ray-tracing algorithm, which created simulated projection images by tracking photons through a voxelized anatomical breast phantom containing iodinated lesions. The single-energy images were combined into dual-energy images through a weighted log subtraction process. The weighting factor was optimized to minimize anatomical noise, while the dose distribution was chosen to minimize quantum noise. The dual-energy images were analyzed for the signal difference to noise ratio (SdNR) of iodinated masses. The fast ray-tracing explored 523?776 dual-energy combinations to identify which yields optimum mass SdNR. The ray-tracing results were verified using a Monte Carlo model for a breast tomosynthesis system with a selenium-based flat-panel detector. The projection images from our voxelized breast phantom were obtained at a constant total glandular dose. The projections were combined using weighted log subtraction and reconstructed using commercial reconstruction software. The lesion SdNR was measured in the central reconstructed slice. The SdNR performance varied markedly across the kVp and filtration space. Ray-tracing results indicated that the mass SdNR was maximized with a high-energy tungsten beam at 49 kVp with 92.5 m of copper filtration and a low-energy tungsten beam at 49 kVp with 95 m of tin filtration. This result was consistent with Monte Carlo findings. This mammographic technique led to a mass SdNR of 0.92 0.03 in the projections and 3.68 0.19 in the reconstructed slices. These values were markedly higher than those for non-optimized techniques. Our findings indicate that dual-energy breast tomosynthesis can be performed optimally at 49 kVp with alternative copper and tin filters, with reconstruction following weighted subtraction. The optimum technique provides best visibility of iodine against structured breast background in dual-energy contrast-enhanced breast tomosynthesis.

Ehsan Samei; Robert S Saunders Jr

2011-01-01T23:59:59.000Z

385

Radionuclide Migration through Sediment and Concrete: 16 Years of Investigations  

SciTech Connect (OSTI)

The Waste Management Project provides safe, compliant, and cost-effective waste management services for the Hanford Site and the U.S. Department of Energy (DOE) complex. Part of these services includes safe disposal of low-level waste and mixed low-level waste at the Hanford Low-Level Waste Burial Grounds in accordance with the requirements of DOE Order 435.1, Radioactive Waste Management. To partially satisfy these requirements, performance assessment analyses were completed and approved. DOE Order 435.1 also requires continuing data collection to increase confidence in the critical assumptions used in these analyses to characterize the operational features of the disposal facility that are relied on to satisfy the performance objectives identified in the order. Cement-based solidification and stabilization is considered for hazardous waste disposal because it is easily done and cost-efficient. One critical assumption is that concrete will be used as a waste form or container material at the Hanford Site to control and minimize the release of radionuclide constituents in waste into the surrounding environment. Concrete encasement would contain and isolate the waste packages from the hydrologic environment and act as an intrusion barrier. Any failure of concrete encasement may result in water intrusion and consequent mobilization of radionuclides from the waste packages. The radionuclides iodine-129, selenium-75, technetium-99, and uranium-238 have been identified as long-term dose contributors (Mann et al. 2001; Wood et al. 1995). Because of their anionic nature in aqueous solutions, these constituents of potential concern may be released from the encased concrete by mass flow and/or diffusion and migrate into the surrounding subsurface environment (Serne et al. 1989; 1992; 1993a, b; 1995). Therefore, it is necessary to assess the performance of the concrete encasement structure and the ability of the surrounding soil to retard radionuclide migration. Each of the test methods performed throughout the lifetime of the project has focused on different aspects of the concrete waste form weathering process. Diffusion of different analytes [technetium-99 (Tc-99), iodine-125 (I-125), stable iodine (I), uranium (U), and rhenium (Re)] has been quantified from experiments under both saturated and unsaturated conditions. The water-saturated conditions provide a conservative estimate of the concretes performance in situ, and the unsaturated conditions provide a more accurate estimate of the diffusion of contaminants from the concrete.

Golovich, Elizabeth C.; Mattigod, Shas V.; Snyder, Michelle MV; Powers, Laura; Whyatt, Greg A.; Wellman, Dawn M.

2014-11-06T23:59:59.000Z

386

K-Edge Subtraction Angiography with Synchrotron X-Rays  

SciTech Connect (OSTI)

The purpose of this project was to utilize dual energy, monochromatic X-rays produced from synchrotrons radiation in order to obtain noninvasive medical imaging. The application of synchrotrons radiation to medical imaging is based on the principle of iodine dichromography, first described by Bertil Jacobson of the Karolinska Institute in 1953. Medical imaging using synchrotrons radiation and K-edge dichromography was pioneered at Stanford University under the leadership of Dr. Ed Rubenstein, and the late Nobel Laureate in Physics, Dr. Robert Hofstadter. With progressive refinements in hardware, clinical-quality images were obtained of human coronary arteries utilizing peripheral injections of iodinated contrast agent. These images even now are far superior to those being presented by investigators using MRI as an imaging tool for coronary arteries. However, new supplies and instruments in the cardiac catheterization laboratory have served to transform coronary angiography into an outpatient procedure, with relatively little morbidity. We extended the principles learned with coronary angiography to noninvasive imaging of the human bronchial tree. For these images, we utilized xenon as the contrast agent, as it has a K-edge very similar to that of iodine. In this case, there is no true competing diagnostic test, and pulmonary neoplasm is an enormous public health concern. In early experiments, we demonstrated remarkably clear images of the human bronchial tree. These images have been shown internationally; however, funding difficulties primarily with the Department of Energy have not allowed for progression of this promising avenue of research. One potential criticism of the project is that in order to obtain these images, we utilized national laboratories. Some have questioned whether this would lead to a practical imaging modality. However, we have shown that the technology exists to allow for construction of a miniature storage ring, with a superconducting wiggler magnet, which would occupy minimal space, and would be of a cost comparable with that of a clinical cardiac catheterization laboratory. Much of the focus of this research is now shifting to Europe, where individual whom we have trained or with whom we have worked are now heading up extensive efforts in medical imaging and K-edge dichromography. This work is occurring mostly at DESY in Hamburg, and at the European Synchrotrons Research Laboratory (ESRF) in Grenoble. (B204)

Giacomini, John C.

1996-12-31T23:59:59.000Z

387

CX-010119: Categorical Exclusion Determination | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

9: Categorical Exclusion Determination 9: Categorical Exclusion Determination CX-010119: Categorical Exclusion Determination Humate Injection CX(s) Applied: B3.1 Date: 03/26/2013 Location(s): South Carolina Offices(s): Savannah River Operations Office Savannah River National Laboratory (SRNL) is conducting a humate injection study at the F Area Hazardous Waste Management Facility (FHWMF) as part of the Department of Energy EM-12 Office of Soil and Groundwater Remediation "Attenuation-Based Remedies for the Subsurface Applied Field Research Initiative (ABRS AFRI)". SRNL will perform a humate injection test in a monitoring well downgradient of the seepage basins at the FHWMF to evaluate the use of a humate amendment for the stabilization of dissolved uranium, strontium-90 and iodine-129 in an acidic groundwater plume.

388

Hypothyroidism prevalence following exposure to radioiodines in childhood  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hypothyroidism prevalence following exposure to radioiodines in childhood Hypothyroidism prevalence following exposure to radioiodines in childhood and adolescence: Belarusian-American Cohort Study of Thyroid Cancer and Other Thyroid Diseases after the Chernobyl Accident Ostroumova Evgenia National Cancer Institute Abstract Background. Hypothyroidism is the most common thyroid abnormality in patients treated with high doses of iodine-131 (131I). Data on risk of hypothyroidism from low to moderate 131I thyroid doses are limited and inconsistent. Objective. To assess the risk of hypothyroidism prevalence in relation to 131I doses from Chernobyl fallout exposure. Materials and methods. The analysis is based on the first screening cycle (1996–2003) of a Belarus-American study of thyroid diseases in a cohort of 10,827 individuals under 18 years of age at the time of the

389

At the Crossroads of Chromosomes | Advanced Photon Source  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Unveiling the Structure of Adenovirus Unveiling the Structure of Adenovirus Making Silicon Melt in Reverse In or Out: Setting a Trap for Radioactive Iodine Probing Spin Liquids with a New Pulsed-Magnet System Making a Magnetic Moment in a Split Picosecond Science Highlights Archives: 2013 | 2012 | 2011 | 2010 2009 | 2008 | 2007 | 2006 2005 | 2004 | 2003 | 2002 2001 | 2000 | 1998 | Subscribe to APS Science Highlights rss feed At the Crossroads of Chromosomes SEPTEMBER 21, 2010 Bookmark and Share Structure of the centromere histone complex containing two chains of CENP-A (red) and two copies of its close binding partner, histone H4 (blue). (Image: Ben E. Black, University of Pennsylvania School of Medicine) On average, one hundred billion cells in the human body divide over the course of a day. Most of the time the body gets it right but sometimes,

390

Reading Comprehension - Digestion and Nutrition  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Digestion and Nutrition Digestion and Nutrition 1. The pouchlike muscular organ that secretes acids and digestive enzymes is the _________ stomach esophagus intestines . 2. _________ saliva enzymes chime is the watery material that results form digestion in the stomach. 3. Iron, potassium, and iodine are _________ vitamins minerals amino acids . 4. The human body is about 60 percent _________ salt water nutrients . 5. The teeth break down food by _________ chemical digestion mechanical digestion . 6. _________ Teeth Your tongue Saliva in the mouth helps to chemically digest food. 7. _________ Mechanical digestion Chemical digestion takes place in the mouth, stomach, and small intestine with the help of chemicals called _________ amino acids vitamins enzymes . 8. Proteins are made up of smaller building blocks called _________

391

CX-003638: Categorical Exclusion Determination | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

8: Categorical Exclusion Determination 8: Categorical Exclusion Determination CX-003638: Categorical Exclusion Determination Silver (Ag) Extraction of Sediments CX(s) Applied: B3.6 Date: 07/30/2010 Location(s): Aiken, South Carolina Office(s): Savannah River Operations Office This activity involves extracting silver (Ag) from core (sediment) collected from F-Area. Silver chloride (AgCl) was injected into the ground in F-Area in an effort to immobilize iodine (goal was to form a precipitate silver iodide). Four soil borings were collected in order to test the core for silver. Collected sediments will be mixed with a sodium thiosulfate pentahydrate solution in order to dissolve the Ag. The resulting solutions will be collected and analyzed for Ag. DOCUMENT(S) AVAILABLE FOR DOWNLOAD CX-003638.pdf More Documents & Publications

392

Next Step to Drought-Resistant Plants? | Advanced Photon Source  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

A Boring Material "Stretched" Could Lead to an Electronics Revolution A Boring Material "Stretched" Could Lead to an Electronics Revolution At the Crossroads of Chromosomes Unveiling the Structure of Adenovirus Making Silicon Melt in Reverse In or Out: Setting a Trap for Radioactive Iodine Science Highlights Archives: 2013 | 2012 | 2011 | 2010 2009 | 2008 | 2007 | 2006 2005 | 2004 | 2003 | 2002 2001 | 2000 | 1998 | Subscribe to APS Science Highlights rss feed Next Step to Drought-Resistant Plants? SEPTEMBER 30, 2010 Bookmark and Share Photo by Tim McCabe. Copyright USDA National Resources Conservation Service, http://www.earthgauge.net/kids-january/do Environmentally-friendly sprays that help plants survive drought and other stresses in harsh environments could result from findings based on research carried out at the U.S. Department of Energy's Advanced Photon Source (APS)

393

Finding Aids: Epidemiologic Studies  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Hanford Site: A Guide to Record Series Supporting Epidemiologic Studies Conducted for the Department of Energy Oak Ridge Volume I: Y-12 Mercury Task Force Files: A Guide to Record Series of The Department of Energy and Its Contractors Oak Ridge Volume II: Records Relating to Cesium at the K-25 Plant: A Guide to Record Series of the Department of Energy and Its Contractors Oak Ridge Volume III: Records Relating to RaLa, Iodine-131, and Cesium-137 at the Oak Ridge National Laboratory and the Oak Ridge Operations Office: A Guide to Record Series of the Department of Energy and Its Contractors Oak Ridge Institute for Science and Education: A Guide to Record Series Supporting Epidemiologic Studies Conducted for the Department of Energy The September 1957 Rocky Flats Fire: A Guide to Record Series of the Department of Energy and its Contractors

394

NIDC: Online Catalog of Isotope Products | Product Search  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Product Search Product Search Step 1 - Enter your search criteria below. Element Name Actinium Aluminum Americium Antimony Argon Arsenic Astatine Barium Berkelium Beryllium Bismuth Bohrium Boron Bromine Cadmium Caesium Calcium Californium Carbon Cerium Chlorine Chromium Cobalt Copernicium Copper Curium Darmstadtium Dubnium Dysprosium Einsteinium Erbium Europium Fermium Fluorine Francium Gadolinium Gallium Germanium Gold Hafnium Hassium Helium Holmium Hydrogen Indium Iodine Iridium Iron Krypton Lanthanum Lawrencium Lead Lithium Lutetium Magnesium Manganese Meitnerium Mendelevium Mercury Molybdenum Neodymium Neon Neptunium Nickel Niobium Nitrogen Nobelium Osmium Oxygen Palladium Phosphorus Platinum Plutonium Polonium Potassium Praseodymium Promethium Protactinium Radium Radon Rhenium Rhodium Roentgenium Rubidium Ruthenium Rutherfordium Samarium Scandium Seaborgium Selenium Silicon Silver Sodium Strontium Sulfur Tantalum Technetium Tellurium Terbium Thallium Thorium Thulium Tin Titanium Tungsten Ununhexium Ununoctium Ununpentium Ununquadium Ununseptium Ununtrium Uranium Vanadium Xenon Ytterbium Yttrium Zinc Zirconium

395

ESS 2012 Peer Review - Sodium-based Battery Development - Dave Ingersoll, SNL  

Broader source: Energy.gov (indexed) [DOE]

Sodium-based Battery Development Sodium-based Battery Development A Family of Batteries for Large Scale Energy Storage D. Ingersoll, C. Apblett, E. Spoerke, K. Zavadil, R. Cygan, J. Ihlefeld, F. Delnick, & T. Anderson Sandia National Laboratories, Albuquerque, NM Prof. E. Wachsman University of Maryland, College Park, MD Profs. R. Kee & J. Porter, Dr. H. Zhu Colorado School of Mines, Golden, CO S. Bhavaraju & M. Robins Ceramatec, Inc, Salt Lake City, UT D. Beeaff CoorsTek, Inc, Golden, CO J. Martin Boulder Ionics, Golden CO US DOE Energy Storage Systems Research Program Peer Review, Washington, DC, Sept. 26-28, 2012 Sodium-based batteries  Purpose  Demonstrate a family of sodium-based battery chemistries  sodium-iodine, sodium-bromine, sodium-air, sodium insertion, sodium-metal, etc

396

Oral Histories: Cell Biologist Don Francis Petersen, Ph.D.  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

0 0 HUMAN RADIATION STUDIES: REMEMBERING THE EARLY YEARS Oral History of Cell Biologist Don Francis Petersen, Ph.D. Conducted November 29, 1994 United States Department of Energy Office of Human Radiation Experiments August 1995 CONTENTS Foreword Short Biography From South Dakota to University of Chicago (1950) to Los Alamos (1956) Outlining the Agenda for Radiation Research (Early '50s) MET Lab Research in the Metabolism of Radionuclides Choosing a Career at Los Alamos (1956) Nuclear Weapons Fallout Studies (1946–54) The Radiobiology Group's Research Project Approval Process Mission of the Los Alamos Biomedical Group in the 1950s Participation as a Subject in Human Radiation Studies Measuring Iodine-131 Uptake in Children (Circa 1963) AEC Authorization of the Use of Human Subjects (1956)

397

Argonne Chemical Sciences & Engineering - Nuclear & Environmental Processes  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Recycling Long-lived Fissile Materials as Fuel Recycling Long-lived Fissile Materials as Fuel Used Fuel Assembly Uranium accounts for the bulk of used fuel. The fissile component comprises less than 1 percent of the uranium, near the fraction found in the natural ore. This uranium may be disposable as low-level waste or stored for eventual re-enrichment for reactor fuel. Used fuel contains essentially all of the elements in the periodic table. However, nearly all of the risk associated with the disposal of spent fuel comes from approximately 1 percent of its content-primarily the transuranic elements: plutonium, neptunium, americium, and curium, and the long-lived isotopes of iodine and technetium. The very high short-term radioactivity comes primarily from two elements, cesium and strontium. In a

398

NIDC: Online Catalog of Isotope Products | Request a New Product  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Request a New Product Request a New Product Step 1 - Enter the new product's criteria below. Element Name Actinium Aluminum Americium Antimony Argon Arsenic Astatine Barium Berkelium Beryllium Bismuth Bohrium Boron Bromine Cadmium Caesium Calcium Californium Carbon Cerium Chlorine Chromium Cobalt Copernicium Copper Curium Darmstadtium Dubnium Dysprosium Einsteinium Erbium Europium Fermium Fluorine Francium Gadolinium Gallium Germanium Gold Hafnium Hassium Helium Holmium Hydrogen Indium Iodine Iridium Iron Krypton Lanthanum Lawrencium Lead Lithium Lutetium Magnesium Manganese Meitnerium Mendelevium Mercury Molybdenum Neodymium Neon Neptunium Nickel Niobium Nitrogen Nobelium Osmium Oxygen Palladium Phosphorus Platinum Plutonium Polonium Potassium Praseodymium Promethium Protactinium Radium Radon Rhenium Rhodium Roentgenium Rubidium Ruthenium Rutherfordium Samarium Scandium Seaborgium Selenium Silicon Silver Sodium Strontium Sulfur Tantalum Technetium Tellurium Terbium Thallium Thorium Thulium Tin Titanium Tungsten Ununhexium Ununoctium Ununpentium Ununquadium Ununseptium Ununtrium Uranium Vanadium Xenon Ytterbium Yttrium Zinc Zirconium

399

Page not found | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

11 - 4820 of 26,777 results. 11 - 4820 of 26,777 results. Download CX-002199: Categorical Exclusion Determination 661-G, Small Arms Training Area (SATA) Complex Deactivation and Decommissioning CX(s) Applied: B1.23 Date: 04/28/2010 Location(s): Aiken, South Carolina Office(s): Environmental Management, Savannah River Operations Office http://energy.gov/nepa/downloads/cx-002199-categorical-exclusion-determination Download CX-002201: Categorical Exclusion Determination Iodine Speciation CX(s) Applied: B3.6 Date: 04/28/2010 Location(s): Aiken, South Carolina Office(s): Environmental Management, Savannah River Operations Office http://energy.gov/nepa/downloads/cx-002201-categorical-exclusion-determination Download CX-001817: Categorical Exclusion Determination Lean Gasoline System Development for Fuel Efficient Small Cars (Warren)

400

U.S. Department of Energy Categorical Exclusion Determination Form  

Broader source: Energy.gov (indexed) [DOE]

Humate Injection Humate Injection Savannah River Site Aiken/Aiken/South Carolina SRNL is conducting a humate injection study at the F Area Hazardous Waste Management Facility (FHWMF) as part of the Department of Energy EM-12 Office of Soil and Groundwater Remediation "Attenuation-Based Remedies for the Subsurface Applied Field Research Initiative (ABRS AFRI)". SRNL will perform a humate injection test in a monitoring well downgradient of the seepage basins at the FHWMF to evaluate the use of a humate amendment for the stabilization of dissolved uranium, strontium-90 and iodine-129 in an acidic groundwater plume. B3.1 - Site characterization and environmental monitoring Andrew R. Grainger Digitally signed by Andrew R. Grainger DN: cn=Andrew R. Grainger, o=DOE-SR, ou=EQMD,

Note: This page contains sample records for the topic "iodine phos phorus" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


401

Page not found | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

11 - 25620 of 28,560 results. 11 - 25620 of 28,560 results. Download CX-010018: Categorical Exclusion Determination 2H Evaporator Scale Sample Analysis CX(s) Applied: B3.6 Date: 01/28/2013 Location(s): South Carolina Offices(s): Savannah River Operations Office http://energy.gov/nepa/downloads/cx-010018-categorical-exclusion-determination Download CX-010019: Categorical Exclusion Determination Iodine Speciation CX(s) Applied: B3.6 Date: 01/28/2013 Location(s): South Carolina Offices(s): Savannah River Operations Office http://energy.gov/nepa/downloads/cx-010019-categorical-exclusion-determination Article Energy Department Launches Public-Private Partnership to Deploy Hydrogen Infrastructure The Energy Department launched H2USA -- a new public-private partnership focused on advancing hydrogen infrastructure to support more transportation

402

Human Radiation Experiments: Multimedia: Film Clips  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Film Clips Multimedia Film Clips Multimedia Home Roadmap What's New Multimedia Related Sites Feedback Sound Bytes Film Clips Historical Photographs Films require: Get Real Player 5.0 to view the films on this page. The Atom and You Second in the series The Atom and You, Paramount News, March 25, 1953, shows tests conducted at Hanford, Washington, on effects of exposure of sheep and salmon to radiation; testing of radioactive dust at UCLA laboratory; the use of radioisotopes and tracer materials for detecting cancer in patients at Oak Ridge, Tennessee; the use of rays from the cobalt source at N.Y. city’s Moncure Hospital, to treat cancer of the brain. (Time: 5 min 9 secs) Real Media Download Versions 28.8 kbps version (782k) 56.0 kbps version (1.3mb) T1 version (7.5mb) Iodine 131

403

Unveiling the Structure of Adenovirus | Advanced Photon Source  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Making Silicon Melt in Reverse Making Silicon Melt in Reverse In or Out: Setting a Trap for Radioactive Iodine Probing Spin Liquids with a New Pulsed-Magnet System Making a Magnetic Moment in a Split Picosecond Unpeeling Atoms and Molecules from the Inside Out Science Highlights Archives: 2013 | 2012 | 2011 | 2010 2009 | 2008 | 2007 | 2006 2005 | 2004 | 2003 | 2002 2001 | 2000 | 1998 | Subscribe to APS Science Highlights rss feed Unveiling the Structure of Adenovirus SEPTEMBER 14, 2010 Bookmark and Share Shown on the left is a surface rendered diagram of adenovirus illustrating the organization of the major and minor capsid proteins (in different colors) on the outer capsid (protein shell of the virus). On the right is a close-up view of the penton base-fiber complex found at the vertices of the

404

Report of the Review of the Hanford Solid Waste Environmental Impact  

Broader source: Energy.gov (indexed) [DOE]

of the Review of the Hanford Solid Waste Environmental of the Review of the Hanford Solid Waste Environmental Impact Statement regarding Data Quality Control and Management Issues Report of the Review of the Hanford Solid Waste Environmental Impact Statement regarding Data Quality Control and Management Issues As part of the litigation involving receipt of offsite waste and the HSW EIS, the Court allowed the State of Washington a limited amount of discovery pertaining to iodine-129, technetium-99, and groundwater analyses. While compiling information to respond to the State discovery request, Battelle discovered three data quality issues within the data sets used for the cumulative groundwater impact analysis: As a result of these data quality issues, a team was commissioned to review the HSW EIS for additional data quality issues as well as any programmatic problems which

405

A Boring Material "Stretched" Could Lead to an Electronics Revolution |  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

At the Crossroads of Chromosomes At the Crossroads of Chromosomes Unveiling the Structure of Adenovirus Making Silicon Melt in Reverse In or Out: Setting a Trap for Radioactive Iodine Probing Spin Liquids with a New Pulsed-Magnet System Science Highlights Archives: 2013 | 2012 | 2011 | 2010 2009 | 2008 | 2007 | 2006 2005 | 2004 | 2003 | 2002 2001 | 2000 | 1998 | Subscribe to APS Science Highlights rss feed A Boring Material "Stretched" Could Lead to an Electronics Revolution SEPTEMBER 30, 2010 Bookmark and Share Predicted effect of biaxial strain on EuTiO3 and the approach to imparting such strain in EuTiO3 films using epitaxy. This schematic shows the in-plane expansion due to biaxial tension. (From Lee et al., Nature 466, 954, 19 August 2010) The oxide compound europium titanate is pretty boring on its own. But

406

Page not found | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

901 - 25910 of 31,917 results. 901 - 25910 of 31,917 results. Download CX-002201: Categorical Exclusion Determination Iodine Speciation CX(s) Applied: B3.6 Date: 04/28/2010 Location(s): Aiken, South Carolina Office(s): Environmental Management, Savannah River Operations Office http://energy.gov/nepa/downloads/cx-002201-categorical-exclusion-determination Download CX-003668: Categorical Exclusion Determination Subsurface Soils Exploration for Potential Pit Disassembly and Conversion Project Sandfilter Footprint CX(s) Applied: B3.1 Date: 07/20/2010 Location(s): Aiken, South Carolina Office(s): Savannah River Operations Office http://energy.gov/nepa/downloads/cx-003668-categorical-exclusion-determination Download CX-002984: Categorical Exclusion Determination Improvements to L Area Sidewalks

407

Iodate Refuses to Intimidate | Advanced Photon Source  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Creating the Heart of a Planet in the Heart of a Gem Creating the Heart of a Planet in the Heart of a Gem How a Powerful Antibody Neutralizes HIV Taking a Page from Nature to Build Better Nanomaterials Hard as Diamond: A New Form of Carbon Created under Ultrahigh Pressure How Algae Use a "Sulfate Trap" to Selectively Biomineralize Strontium Science Highlights Archives: 2013 | 2012 | 2011 | 2010 2009 | 2008 | 2007 | 2006 2005 | 2004 | 2003 | 2002 2001 | 2000 | 1998 | Subscribe to APS Science Highlights rss feed Iodate Refuses to Intimidate NOVEMBER 11, 2011 Bookmark and Share For the first time, scientists were able to determine why iodate ions reside in water: The iodine atom's positive nature allows it to draw in three water molecules and these additional water molecules in turn allow the iodate ion to fit within water's structure. Image from Marcel D. Baer

408

Status of initial testing of the H2SO4 section of the ILS experiment.  

SciTech Connect (OSTI)

A sulfuric acid catalytic decomposer section was assembled and tested for the Integrated Laboratory Scale experiments of the Sulfur-Iodine Thermochemical Cycle. This cycle is being studied as part of the U. S. Department of Energy Nuclear Hydrogen Initiative. Tests confirmed that the 54-inch long silicon carbide bayonet could produce in excess of the design objective of 100 liters/hr of SO{sub 2} at 2 bar. Furthermore, at 3 bar the system produced 135 liters/hr of SO{sub 2} with only 31 mol% acid. The gas production rate was close to the theoretical maximum determined by equilibrium, which indicates that the design provides adequate catalyst contact and heat transfer. Several design improvements were also implemented to greatly minimize leakage of SO{sub 2} out of the apparatus. The primary modifications were a separate additional enclosure within the skid enclosure, and replacement of Teflon tubing with glass-lined steel pipes.

Moore, Robert Charles; Parma, Edward J., Jr.; Gelbard, Fred

2007-12-01T23:59:59.000Z

409

A theoretical analysis of proportional counter response versus LET  

E-Print Network [OSTI]

'lowing this inspection, the beta spectrum for each of the five isotopes was generaL. d and the Ites'I) ts a~e shown in FTGS. 7, 8, 9, 10 and 11. The reduced EET equation wa. . compuLcd for an eI argy range of 0. 01 Ifcy to 1, 2 I'!eV 44hi! h inc1udcs the eneri y...V) FIG. 15. NcighLcd mass-absorption energy losses for iodine-131 negaL~ns in air . 28 1 0 0 ~ 8 0. 6 03 'a 0 ' 4 'o Ql P s' 0 ~ 2 0 ' 04 0 ~ 12 0 ~ 20 Energy (I'1eV) 0 ~ 36 11G. 16. '~~'sigh Led rsess ? absorption ener gy losses tor Xenon...

Martin, George Gerald

2012-06-07T23:59:59.000Z

410

Atomic energy as an humane endeavor: Retrospective on its development  

SciTech Connect (OSTI)

This report is a speech delivered in Tokyo, Japan, by the author. It covers the historical aspects of atomic energy, from the pre-fission days until present. Such pioneer experiments conducted by O. Hahn, L. Meitner, and F. Strassmann to describe barium isotopes as the result of bombardment of uranium with neutrons are discussed. The author also discussed in detail the pre-war nuclear research at Berkeley, a leading center of nuclear research. Such important events as the synthesis and identification of cobalt-60, iodine-131, and technetium-99m are also discussed. The author discussed the nuclear power as a source of electricity and the perspective on the future of nuclear power. 32 refs., 19 figs., 5 tabs.

Seaborg, G.T.; Stahlkopf, K.E.

1989-01-01T23:59:59.000Z

411

The Halogenation of Oils with Special Attention to the Method of Wijs  

E-Print Network [OSTI]

by him in the following manner: ! In the preparation of the solutions. HgCl 8 + 41 = Hg I a + 2 IC1 IC1 + H 20 5 HC1 + HIO 2. On keeping the solution. 2 HIO + C 2H 60 = 21 + 2H 20 + C 2H 40 3. In the absorption (oleic acid). C0 2H.Ci 7H a a + HIO... at once a substance capable of liberating iodine from potassium iodide. He expressed the chemical change by the following equation: HgCl + I 2 - Hg C1I + IC1 Ephraim regarded the fact that he could ob tain results identical to those of Hubl, by using...

Rhodes, Edmund Oliver

1913-05-15T23:59:59.000Z

412

Interaction of water with epoxy.  

SciTech Connect (OSTI)

The chemistries of reactants, plasticizers, solvents and additives in an epoxy paint are discussed. Polyamide additives may play an important role in the absorption of molecular iodine by epoxy paints. It is recommended that the unsaturation of the polyamide additive in the epoxy cure be determined. Experimental studies of water absorption by epoxy resins are discussed. These studies show that absorption can disrupt hydrogen bonds among segments of the polymers and cause swelling of the polymer. The water absorption increases the diffusion coefficient of water within the polymer. Permanent damage to the polymer can result if water causes hydrolysis of ether linkages. Water desorption studies are recommended to ascertain how water absorption affects epoxy paint.

Powers, Dana Auburn

2009-07-01T23:59:59.000Z

413

Waste Acceptance Testing of Secondary Waste Forms: Cast Stone, Ceramicrete and DuraLith  

SciTech Connect (OSTI)

To support the selection of a waste form for the liquid secondary wastes from WTP, Washington River Protection Solutions has initiated secondary-waste-form testing work at Pacific Northwest National Laboratory (PNNL). In anticipation of a down-selection process for a waste form for the Solidification Treatment Unit to be added to the ETF, PNNL is conducting tests on four candidate waste forms to evaluate their ability to meet potential waste acceptance criteria for immobilized secondary wastes that would be placed in the IDF. All three waste forms demonstrated compressive strengths above the minimum 3.45 MPa (500 psi) set as a target for cement-based waste forms. Further, none of the waste forms showed any significant degradation in compressive strength after undergoing thermal cycling (30 cycles in a 10 day period) between -40 C and 60 C or water immersion for 90 days. The three leach test methods are intended to measure the diffusion rates of contaminants from the waste forms. Results are reported in terms of diffusion coefficients and a leachability index (LI) calculated based on the diffusion coefficients. A smaller diffusion coefficient and a larger LI are desired. The NRC, in its Waste Form Technical Position (NRC 1991), provides recommendations and guidance regarding methods to demonstrate waste stability for land disposal of radioactive waste. Included is a recommendation to conduct leach tests using the ANS 16.1 method. The resulting leachability index (LI) should be greater than 6.0. For Hanford secondary wastes, the LI > 6.0 criterion applies to sodium leached from the waste form. For technetium and iodine, higher targets of LI > 9 for Tc and LI > 11 for iodine have been set based on early waste-disposal risk and performance assessment analyses. The results of these three leach tests conducted for a total time between 11days (ASTM C1308) to 90 days (ANS 16.1) showed: (1) Technetium diffusivity: ANSI/ANS 16.1, ASTM C1308, and EPA 1315 tests indicated that all the waste forms had leachability indices better than the target LI > 9 for technetium; (2) Rhenium diffusivity: Cast Stone 2M specimens, when tested using EPA 1315 protocol, had leachability indices better than the target LI > 9 for technetium based on rhenium as a surrogate for technetium. All other waste forms tested by ANSI/ANS 16.1, ASTM C1308, and EPA 1315 test methods had leachability indices that were below the target LI > 9 for Tc based on rhenium release. These studies indicated that use of Re(VII) as a surrogate for 99Tc(VII) in low temperature secondary waste forms containing reductants will provide overestimated diffusivity values for 99Tc. Therefore, it is not appropriate to use Re as a surrogate 99Tc in future low temperature waste form studies. (3) Iodine diffusivity: ANSI/ANS 16.1, ASTM C1308, and EPA 1315 tests indicated that the three waste forms had leachability indices that were below the target LI > 11 for iodine. Therefore, it may be necessary to use a more effective sequestering material than silver zeolite used in two of the waste forms (Ceramicrete and DuraLith); (4) Sodium diffusivity: All the waste form specimens tested by the three leach methods (ANSI/ANS 16.1, ASTM C1308, and EPA 1315) exceeded the target LI value of 6; (5) All three leach methods (ANS 16.1, ASTM C1308 and EPA 1315) provided similar 99Tc diffusivity values for both short-time transient diffusivity effects as well as long-term ({approx}90 days) steady diffusivity from each of the three tested waste forms (Cast Stone 2M, Ceramicrete and DuraLith). Therefore, any one of the three methods can be used to determine the contaminant diffusivities from a selected waste form.

Mattigod, Shas V.; Westsik, Joseph H.; Chung, Chul-Woo; Lindberg, Michael J.; Parker, Kent E.

2011-08-12T23:59:59.000Z

414

Structural trends and bonding of the 5-elements (U-Am) with the oxoligand I03-.  

SciTech Connect (OSTI)

The solid state chemistry of transuranium compounds has received considerably less attention than their uranium analogs owing to decreased availability and the highly specialized facilities needed to safely study long-lived {alpha}-emitters. However, understanding the behavior of the early transuranium elements is critical for assessing their environmental impact as long-term contributors to radioactive dose in nuclear waste repositories. Of particular interest is how these elements might react with fission product radionuclides such as 129I, or their derivatives. In fact, iodine can exist in solution in both oxidized and reduced forms, i .e. as I03 and F, and studies on the nature of129I in nuclear waste suggested the existence of iodate, 103.2

Bean, A. C. (Amanda Cherise); Scott, B. L. (Brian L.); Albrecht-Schmitt, T. E. (Thomas E.); Runde, W. H. (Wolfgang H.)

2003-01-01T23:59:59.000Z

415

Influence of Fe Contamination on the Minority Carrier Lifetime of Multi-crystalline Silicon  

Science Journals Connector (OSTI)

We investigate the influence of Fe contamination on the minority carrier lifetimes of multi-crystalline silicon. The minority carrier lifetime is measured by the microwave photoconductive decay method. The original bulk lifetime is about 30 ?s after passivation with iodine solution. After intentional Fe contamination, the bulk lifetime declines with increasing temperature. Fast cooling in air conduces to the formation of more interstitial Fe ([Fe]i). Slow cooling through the control of the furnace temperature limits the formation of more [Fe]i, but leads to the formation of precipitation. The data support the idea that the minority carrier lifetime in multi-crystalline silicon mainly depends on the distribution of Fe but not the total amount. A favorite effect of [Fe]i gettering is discovered after conventional phosphorus diffusion, and the [Fe]i concentration remaining in the silicon wafer is acceptable for solar cell applications.

Meng Xia-Jie; Ma Zhong-Quan; Li Feng; Shen Cheng; Yin Yan-Ting; Zhao Lei; Li Yong-Hua; Xu Fei

2010-01-01T23:59:59.000Z

416

Mid-Infrared Fiber-Coupled QCl-QEPAS Sensor  

SciTech Connect (OSTI)

An innovative spectroscopic system based on an external cavity quantum cascade laser (EC-QCL) coupled with a mid-infrared (mid-IR) fiber and quartz enhanced photoacoustic spectroscopy (QEPAS) is described. SF6 has been selected as a target gas in demonstration of the system for trace gas sensing. Single mode laser delivery through the prongs of the quartz tuning fork has been obtained employing a hollow waveguide fiber with inner silversilver iodine (AgAgI) coatings and internal core diameter of 300 lm. A detailed design and realization of the QCL fiber coupling and output collimator system allowed almost practically all (99.4 %) of the laser beam to be transmitted through the spectrophone module. The achieved sensitivity of the system is 50 parts per trillion in 1 s, corresponding to a record for QEPAS normalized noise-equivalent absorption 2.7 9 10-10 W cm-1 Hz-1/2.

Spagnolo, V.; Patimisco, P.; Borri, Simone; Scamarcio, G.; Bernacki, Bruce E.; Kriesel, J.M.

2013-08-01T23:59:59.000Z

417

Molecular modelling and simulation of the surface tension of real quadrupolar fluids  

E-Print Network [OSTI]

Molecular modelling and simulation of the surface tension of fluids with force fields is discussed. 29 real fluids are studied, including nitrogen, oxygen, carbon dioxide, carbon monoxide, fluorine, chlorine, bromine, iodine, ethane, ethylene, acetylene, propyne, propylene, propadiene, carbon disulfide, sulfur hexafluoride, and many refrigerants. The fluids are represented by two-centre Lennard-Jones plus point quadrupole models from the literature. These models were adjusted only to experimental data of the vapour pressure and saturated liquid density so that the results for the surface tension are predictions. The deviations between the predictions and experimental data for the surface tension are of the order of 20 percent. The surface tension is usually overestimated by the models. For further improvements, data on the surface tension can be included in the model development. A suitable strategy for this is multi-criteria optimization based on Pareto sets. This is demonstrated using the model for carbon d...

Werth, Stephan; Klein, Peter; Kfer, Karl-Heinz; Horsch, Martin; Hasse, Hans

2014-01-01T23:59:59.000Z

418

Method oil shale pollutant sorption/NO.sub.x reburning multi-pollutant control  

DOE Patents [OSTI]

A method of decreasing pollutants produced in a combustion process. The method comprises combusting coal in a combustion chamber to produce at least one pollutant selected from the group consisting of a nitrogen-containing pollutant, sulfuric acid, sulfur trioxide, carbonyl sulfide, carbon disulfide, chlorine, hydroiodic acid, iodine, hydrofluoric acid, fluorine, hydrobromic acid, bromine, phosphoric acid, phosphorous pentaoxide, elemental mercury, and mercuric chloride. Oil shale particles are introduced into the combustion chamber and are combusted to produce sorbent particulates and a reductant. The at least one pollutant is contacted with at least one of the sorbent particulates and the reductant to decrease an amount of the at least one pollutant in the combustion chamber. The reductant may chemically reduce the at least one pollutant to a benign species. The sorbent particulates may adsorb or absorb the at least one pollutant. A combustion chamber that produces decreased pollutants in a combustion process is also disclosed.

Boardman, Richard D. (Idaho Falls, ID); Carrington, Robert A. (Idaho Falls, ID)

2008-06-10T23:59:59.000Z

419

Producing hydrogen using nuclear energy  

Science Journals Connector (OSTI)

The earliest means of separating hydrogen from water was by electrolysis using electrical energy that usually had been produced by low-efficiency thermodynamic processes. Substitution of thermal energy for electrical energy in high-temperature electrolysis gives a somewhat higher overall efficiency, but significantly complicates the process. Today, the vast majority of hydrogen is produced by steam methane reforming (SMR) followed by a water-shift reaction. A well-designed SMR plant will yield hydrogen having 75??80% of the energy of the methane used. Recent work in Japan has demonstrated the feasibility of substituting high-temperature heat from a gas-cooled nuclear reactor to replace the heat supplied in SMR by the combustion of methane. Using high-temperature heat from nuclear plants to drive thermochemical processes for producing hydrogen has been studied extensively. Bench-scale tests have been carried out in Japan demonstrating the sulphur-iodine (SI) process to produce hydrogen.

Robert E. Uhrig

2008-01-01T23:59:59.000Z

420

General Insights into Structural Evolution of Layered Double Hydroxide: Underlying Aspects in Topochemical Transformation from Brucite to Layered Double Hydroxide  

Science Journals Connector (OSTI)

General Insights into Structural Evolution of Layered Double Hydroxide: Underlying Aspects in Topochemical Transformation from Brucite to Layered Double Hydroxide ... The topochemical transformation from transition-metal brucite hydroxide (Co1-xFex(OH)2, Co(OH)2, Co1-xNix(OH)2) to corresponding (Co2+(Co3+)Fe3+, Co2+(Ni2+)Co3+) LDH under oxidizing halogen agents (iodine, bromine) exhibits different staging phenomena depending on the metallic composition/ratio in starting brucite. ... A plausible charge hopping mechanism based on valence interchange between redoxable charge center (Fe3+/Co3+) and neighboring divalent sites in the host sheet is proposed to understand the restoration of electron donor sites at the interface between brucite crystallites and halogen agents, which ensures a continual oxidative reaction, and a staged intercalation/diffusion of in situ reduced halide anions into the interlayer gallery commensurate with the host charge propagation. ...

Renzhi Ma; Jianbo Liang; Xiaohe Liu; Takayoshi Sasaki

2012-11-08T23:59:59.000Z

Note: This page contains sample records for the topic "iodine phos phorus" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


421

Final Project Report: Release of aged contaminants from weathered sediments: Effects of sorbate speciation on scaling of reactive transport  

SciTech Connect (OSTI)

Hanford sediments impacted by hyperalkaline high level radioactive waste have undergone incongruent silicate mineral weathering concurrent with contaminant uptake. In this project, we studied the impact of background pore water (BPW) on strontium, cesium and iodine desorption and transport in Hanford sediments that were experimentally weathered by contact with simulated hyperalkaline tank waste leachate (STWL) solutions. Using those lab-weathered Hanford sediments (HS) and model precipitates formed during nucleation from homogeneous STWL solutions (HN), we (i) provided detailed characterization of reaction products over a matrix of field-relevant gradients in contaminant concentration, PCO2, and reaction time; (ii) improved molecular-scale understanding of how sorbate speciation controls contaminant desorption from weathered sediments upon removal of caustic sources; and (iii) developed a mechanistic, predictive model of meso- to field-scale contaminant reactive transport under these conditions.

Jon Chorover, University of Arizona; Peggy O'‚ € ‚ ™ Day, University of California, Merced; Karl Mueller, Penn State University; Wooyong Um, Pacific Northwest National Laboratory; Carl Steefel, Lawrence Berkeley National Laboratory

2012-10-01T23:59:59.000Z

422

Coupling a hydrogen production process to a nuclear reactor  

Science Journals Connector (OSTI)

Work is currently underway to define a pre-conceptual design of a hydrogen production plant. The reference case is a VHTR dedicated to hydrogen production using the sulphur-iodine process. The chemical part of the plant is based on a very detailed flow-sheet where all components are listed. Considering the volume and flow-rates of the circulating products, a detailed image of the chemical plant is drawn with several shops in parallel. A coupling circuit using gases was also studied with two intermediate heat exchangers at very high temperature. A specific heat transfer circuit is added inside the chemical part to distribute heat at the correct temperature. Optimisation of this circuit should lead to an increase in the overall efficiency of the process. Finally a methodology is proposed for the safety of the hydrogen production plant.

Pascal Anzieu; Patrick Aujollet; Dominique Barbier; Anne Bassi; Frederic Bertrand; Alain Le Duigou; Jean Leybros; Gilles Rodriguez

2008-01-01T23:59:59.000Z

423

Molecular modelling and simulation of the surface tension of real quadrupolar fluids  

E-Print Network [OSTI]

Molecular modelling and simulation of the surface tension of fluids with force fields is discussed. 29 real fluids are studied, including nitrogen, oxygen, carbon dioxide, carbon monoxide, fluorine, chlorine, bromine, iodine, ethane, ethylene, acetylene, propyne, propylene, propadiene, carbon disulfide, sulfur hexafluoride, and many refrigerants. The fluids are represented by two-centre Lennard-Jones plus point quadrupole models from the literature. These models were adjusted only to experimental data of the vapour pressure and saturated liquid density so that the results for the surface tension are predictions. The deviations between the predictions and experimental data for the surface tension are of the order of 20 percent. The surface tension is usually overestimated by the models. For further improvements, data on the surface tension can be included in the model development. A suitable strategy for this is multi-criteria optimization based on Pareto sets. This is demonstrated using the model for carbon dioxide as an example.

Stephan Werth; Katrin Stbener; Peter Klein; Karl-Heinz Kfer; Martin Horsch; Hans Hasse

2014-08-21T23:59:59.000Z

424

An X-Ray Fluorescence Study on the Segregation of Cs and I in and Inverted Organic Solar Cell  

SciTech Connect (OSTI)

X-ray near-total-reflection fluorescence reveals that in multilayers of the inverted organic solar cell (ITO/CsI/P3HT:PCBM-based) Cs diffuses into the organic layer and iodide diffuses into the ITO. Laser ablation inductively coupled plasma mass spectrometry measurements, which integrate elemental concentration across the whole multilayer structure, indicate that the Cs:I ratio remains 1:1 confirming there is no loss of iodine from the sample. Iodide diffusion to the bulk ITO layer is also found in a similarly prepared ITO/NaI/P3HT:PCBM multilayer structure. Our results are consistent with recent XPS measurements which show that the Cs:I ratio at the ITO/CsI surface exceeds 8:1, and rationalize this observation.

Lindemann, William R. [Ames Laboratory; Xiao, Teng [Ames Laboratory; Wang, Wenjie [Ames Laboratory; Berry, Jonna E. [Ames Laboratory; Anderson, Nathaniel A. [Ames Laboratory; Houk, Robert S. [Ames Laboratory; Shinar, Ruth [Ames Laboratory; Shinar, Joseph [Ames Laboratory; Vaknin, David [Ames Laboratory

2013-10-08T23:59:59.000Z

425

Migration in alluvium of chlorine-36 and tritium from an underground nuclear test  

SciTech Connect (OSTI)

This article describes a field experiment studying the migration in alluvium of radioactive elements away from an underground nuclear explosion at the Nevada Test Site in the United States. Nuclides detected in the pumped water are tritium, chlorine-36, iodine-129, and krypton-85 - all at levels below the maximum permissible concentration for drinking water in controlled areas. The chlorine-36 elution curve precedes that of tritium, and is due to an anion exclusion process. A conventional two-dimensional convection-diffusion equation does not fully describe the elution curves for tritium and chlorine-36; the tailing of the curves is longer than predicted. Successful modeling of this experiment will be important for validating codes and models to be used in the high-level nuclear waste program.

Ogard, A.E.; Thompson, J.L.; Rundberg, R.S.; Wolfsberg, K.; Kubik, P.W.; Elmore, D.; Bentley, H.W.

1987-01-01T23:59:59.000Z

426

Multidimensional effects in optimal control analysis for nuclear reactors  

SciTech Connect (OSTI)

Physically realistic step function control rod models are shown to be unsolvable under traditional formulations of distributed parameter optimal control theory. Extensions to the theory are proposed and derived to allow these systems to be analyzed using straightforward optimality conditions. The extended theory is then applied to a xenon-iodine oscillation problem in two dimensions. The conditions of optimality are found, and analytical insights concerning the importance of the control rod tip for the optimality condition are obtained. The flux influence function is found by solving an eigenvalue problem, and the required normalization condition is found in one of the optimality conditions. The optimality and normalization conditions are solved numerically for a severe xenon transient, and the transient is stabilized by the intervention of the optimal control.

Wyss, G.D.; Alford, R.A.

1988-12-01T23:59:59.000Z

427

Optimal control of xenon oscillations in load follow of a large nuclear reactor  

Science Journals Connector (OSTI)

The problem of xenon spatial oscillations control during the load follow of large pressure water reactors is formulated as an optimization problem. The state equations of the system are composed of the one-group diffusion equation with temperature and xenon feedbacks, the iodine-xenon dynamics equations, and an energy balance equation for the core. The resulting distributed parameter model is first coverted into a lumped one by eigenfunction expansion and then a combination method, based on Differential Dynamic Programming and Matrix Riccati Method, is developed to obtain the optimal solution which can closely follow the desired power demand and maintain the desired flux distribution without too much control effort. Computational results show that the algorithms used in the proposed method converge for a broad spectrum of load follows. With the same precision, the combination method, comparing with DDP alone, is fairly computationally efficient.

Yang Xinping; Fu Longzhou

1985-01-01T23:59:59.000Z

428

OPTIMAL CONTROL OF XENON OSCILLATIONS IN LOAD FOLLOW OF A LARGE NUCLEAR REACTOR  

Science Journals Connector (OSTI)

Abstract The problem of xenon spatial oscillations control during the load follow of large pressure water reactors is formulated as an optimization problem. The state equations of the system are composed of the one-group diffusion equation with temperature and xenon feedbacks, the iodine-xenon dynamics equations, and an energy balance equation for the core. The resulting distributed parameter model is first coverted into a lumped one by eigenfunction expansion and then a combination method, based on Differential Dynamic Programming and Matrix Riccati Method, is developed to obtain the optimal solution which can closely follow the desired power demand and maintain the desired flux distribution without too much control effort. Computational results show that the algorithms used in the proposed method converge for a broad spectrum of load follows. With the same precision, the combination method, comparing with DDP alone, is fairly computationally efficient. Keywords. Differential dynamic programming; optimization; Nuclear reactor; load follow; xenon oscillations.

Xinping Yang; Longzhou Fu

1986-01-01T23:59:59.000Z

429

Nonlinear diffusion theory model for xenon-induced flux oscillations  

SciTech Connect (OSTI)

A nonlinear model is developed for the xenon induced flux oscillation problem that occurs in nuclear power plants. The model is based on Galerkins's method of weighted residuals applied to multigroup diffusion theory. A similar linear model is developed by the same methods in order to consider the effects of the nonlinearities of the system. The effects of multi- and single-energy group considerations are also examined. Finally the effects of various number of basis functions used to approximate the flux, iodine, and xenon concentrations is determined. A partial listing of the computer program XORA, developed from the nonlinear and linear models, is given along with representative input and output from this program.

Teachman, J.D.

1981-01-01T23:59:59.000Z

430

Direct numerical technique of mathematical programming for optimal control of Xenon oscillation in load following operation  

SciTech Connect (OSTI)

A simple core control code is developed for the control of a nuclear reactor in the load following operation. The core state equations are described by the one-group diffusion equation with moderator temperuture and xenon feedbacks and iodine-xenon dynamics equations. The control via control rod, boron, and coolant inlet temperature is considered. To avoid the conventional difficulties of a two-point boundary value problem, the optimal control problem is solved by the direct numerical technique of the mathematical programming without the separation of space and time variables. This quadratic programming problem is solved by the Davidon-Fletcher-Powell method, which is a general unconstrained optimization method. In the cases of the load following operation of Korea Nuclear Units 7 and 8, the results obtained by using the present model show that the scheduled load demand is successfully followed, and the power distribution maintains the desired distribution with a minimum amount of control action.

Yoon, M.H.; No, H.C.

1985-06-01T23:59:59.000Z

431

WWER Expert System for Fuel Failure Analysis Using Data on Primary Coolant Activity  

SciTech Connect (OSTI)

The computer expert system for fuel failure analysis of WWER during operation is presented. The diagnostics is based on the measurement of specific activity of reference nuclides in reactor primary coolant and application of a computer code for the data interpretation. The data analysis includes an evaluation of tramp uranium mass in reactor core, detection of failures by iodine and caesium spikes, evaluation of burnup of defective fuel. Evaluation of defective fuel burnup was carried out by applying the relation of caesium nuclides activity in spikes and relations of activities of gaseous fission products for steady state operational conditions. The method of burnup evaluation of defective fuel by use of fission gas activity is presented in detail. The neural-network analysis is performed for determination of failed fuel rod number and defect size. Results of the expert system application are illustrated for several fuel campaigns on operating WWER NPPs. (authors)

Likhanskii, V.V.; Evdokimov, I.A.; Sorokin, A.A.; Khromov, A.G.; Kanukova, V.D.; Apollonova, O.V. [SRC RF TRINITI, 142190, Troitsk, Moscow Reg. (Russian Federation); Ugryumov, A.V. [JSC TVEL, 119017, 24/26 Bolshaya Ordynka st., Moscow (Russian Federation)

2007-07-01T23:59:59.000Z

432

Nuclear waste management. Quarterly progress report, April-June 1980  

SciTech Connect (OSTI)

The status of the following programs is reported: high-level waste immobilization; alternative waste forms; Nuclear Waste Materials Characterization Center; TRU waste immobilization; TRU waste decontamination; krypton solidification; thermal outgassing; iodine-129 fixation; monitoring and physical characterization of unsaturated zone transport; well-logging instrumentation development; mobility of organic complexes of fission products in soils; waste management system studies; waste management safety studies; assessment of effectiveness of geologic isolation systems; waste/rock interactions technology; systems study on engineered barriers; criteria for defining waste isolation; spent fuel and fuel pool component integrity program; analysis of spent fuel policy implementation; asphalt emulsion sealing of uranium tailings; application of long-term chemical biobarriers for uranium tailings; and development of backfill material.

Platt, A.M.; Powell, J.A. (comps.)

1980-09-01T23:59:59.000Z

433

Categorical Exclusion Determinations: Environmental Management | Department  

Broader source: Energy.gov (indexed) [DOE]

April 28, 2010 April 28, 2010 CX-002201: Categorical Exclusion Determination Iodine Speciation CX(s) Applied: B3.6 Date: 04/28/2010 Location(s): Aiken, South Carolina Office(s): Environmental Management, Savannah River Operations Office April 28, 2010 CX-002199: Categorical Exclusion Determination 661-G, Small Arms Training Area (SATA) Complex Deactivation and Decommissioning CX(s) Applied: B1.23 Date: 04/28/2010 Location(s): Aiken, South Carolina Office(s): Environmental Management, Savannah River Operations Office April 28, 2010 CX-002544: Categorical Exclusion Determination Bubbler Upgrade Support - Defense Waste Processing Facility CX(s) Applied: B1.3 Date: 04/28/2010 Location(s): Aiken, South Carolina Office(s): Environmental Management, Savannah River Operations Office April 28, 2010

434

Fermilab Today  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

0, 2011 0, 2011 spacer Subscribe | Contact Us | Archive | Classifieds | Guidelines | Help Search GO spacer Calendar Have a safe day! Monday, Oct. 10 2:30 p.m. Particle Astrophysics Seminar - One West Speaker: Surhad S. More, University of Chicago Title: Galaxy-Dark Matter Connection: A Cosmological Perspective 3:30 p.m. DIRECTOR'S COFFEE BREAK - 2nd Flr X-Over 4 p.m. All Experimenters' Meeting - Curia II Special Topics: SRF Cryomodule-2 Components Tested; T-1017 CIRTE - Iodine Threshold in COUPP 5:30 p.m. Budker Seminar - Music Room in the Users' Center Title: High Pressure Gas Filled RF Cavity Beam Test at the MuCool Test Area Tuesday, Oct. 11 3:30 p.m. DIRECTOR'S COFFEE BREAK - 2nd Flr X-Over THERE WILL BE NO ACCELERATOR PHYSICS AND TECHNOLOGY SEMINAR TODAY Click here for NALCAL,

435

NEPA Reports and Records of Decision | Department of Energy  

Broader source: Energy.gov (indexed) [DOE]

NEPA Reports and Records of Decision NEPA Reports and Records of Decision NEPA Reports and Records of Decision Report of the Review of the Hanford Solid Waste Environmental Impact Statement regarding Data Quality Control and Management Issues - As part of the litigation involving receipt of offsite waste and the HSW EIS, the Court allowed the State of Washington a limited amount of discovery pertaining to iodine-129, technetium-99, and groundwater analyses. While compiling information to respond to the State discovery request, Battelle discovered three data quality issues within the data sets used for the cumulative groundwater impact analysis: As a result of these data quality issues, a team was commissioned to review the HSW EIS for additional data quality issues as well as any programmatic problems which might have

436

Nuclear Medicine Program progress report for quarter ending June 30, 1991  

SciTech Connect (OSTI)

In this report the excitation functions for production of gallium-66 via {alpha}-induced nuclear reactions on enriched zinc-66 have been measured with E{sub {alpha}}{le}27.3 Mev and E{sub {alpha}}{le}43.7 MeV employing the stack thin-target technique. In addition, the induced activity of gallium-67 in the same sets of targets allowed an evaluation of the excitation functions of the corresponding nuclear reactions. These preliminary studies have demonstrated that sufficient levels of gallium-66 can be produced by {alpha}-induced reactions on enriched zinc targets. A series of radioiodinated analogues of 1-azabicyclo(2.2.2)oct-3-yl {alpha}-hydroxy-{alpha}, {alpha}-diphenylacetate (QNB) have been prepared. These new analogues include 1-azabicyclo-(2.2.2)oct-3-yl{alpha}-hydroxy-{alpha}-(4-iodophenyl)-{alpha}-methylacetate(2,I-WNA), 1-azabicyclo(2.2.2)oct-3-yl (3-iodo)-xanthene-9-carboxylate (3,I-QNX), and 1-azabicyclo(2.2.2)oct-3-yl {alpha}-hydroxy-{alpha}-(E-1-iodo-1-propen-3-yl)-{alpha}-phenylacetate (4,I-QNP), which have also been radiolabeled with iodine-125 with high specific activity. The biodistribution, brain uptake, and receptor specificity of these new analogues are currently being studied. Shipments of radioactive agents made to collaborators during this period included. One shipment of iodine-125-labeled 15-(p-iodophenyl)-3-R,S-methylpentadecanoic acid (BMIPP) and tungsten-188/rhenium-188 generator. 16 refs., 7 figs., 1 tab.

Knapp, F.F. Jr.; Ambrose, K.R.; Callahan, A.P.; McPherson, D.W.; Mirzadeh, S.; Srivastava, P.C.; Hasan, A.; Lambert, C.R.; Lambert, S.J.; Rice, D.E.

1991-09-01T23:59:59.000Z

437

Selective Gaseous Extraction: Research, Development and Training for Isotope Production, Final Technical Report  

SciTech Connect (OSTI)

General Atomics and the University of Missouri Research Reactor (MURR) completed research and development of selective gaseous extraction of fission products from irradiated fuel, which included training and education of MURR students. The process used porous fuel and after irradiation flowed product gases through the fuel to selectively removed desired fission products with the primary goal of demonstrating the removal of rhodium 105. High removal rates for the ruthenium/rhodium (Ru/Rh), tellurium/iodine (Te/I) and molybdenum/technetium (Mo/Tc) series were demonstrated. The success of this research provides for the reuse of the target for further production, significantly reducing the production of actinide wastes relative to processes that dissolve the target. This effort was conducted under DOE funding (DE-SC0007772). General Atomics objective of the project was to conduct R&D on alternative methods to produce a number of radioactive isotopes currently needed for medical and industry applications to include rhodium-105 and other useful isotopes. Selective gaseous extraction was shown to be effective at removing radioisotopes of the ruthenium/rhodium, tellurium/iodine and molybdenum/technetium decay chains while having trace to no quantities of other fission products or actinides. This adds a new, credible method to the area of certain commercial isotope production beyond current techniques, while providing significant potential reduction of process wastes. Waste reduction, along with reduced processing time/cost provides for superior economic feasibility which may allow domestic production under full cost recovery practices. This provides the potential for improved access to domestically produced isotopes for medical diagnostics and treatment at reduced cost, providing for the public good.

Bertch, Timothy C, [General Atomics

2014-03-31T23:59:59.000Z

438

Adjuvant stereotactic permanent seed breast implant: A boost series in view of partial breast irradiation  

SciTech Connect (OSTI)

Purpose: The aim of this study was to use permanent seed implants in the breast and describe our experience with 15 cases, using iodine seed implants as a tumor bed boost. Methods and Materials: Breasts were fixed with a thermoplastic sheet, a template bridge applied, the thorax scanned and the images rotated to be perpendicular to the implant axis. Skin, heart, and lung were delineated. A preplan was made, prescribing 50 Gy to the clinical target volume (CTV), consisting in this boost series of nearly a quadrant. Iodine (125) seeds were stereotactically implanted through the template, and results were checked with a postplan computed tomographic (CT) scan. Results: The breast was immobilized reproducibly. Simulation, scanning, and implant were performed without difficulties. Preplan CTV D90% (the dose delivered to 90% of the CTV) was 66 Gy, and postoperative fluoroscopic or CT scan checks were satisfactory. Pre- and postplan dose-volume histogram showed good organ sparing: mean postplan skin, heart, and lung V30 Gy (the organ volume receiving a dose of 30 Gy) of 2 {+-} 2.2 mL, 0.24 {+-} 0.34 mL, and 3.5 {+-} 5 mL, respectively. No short-term toxicity above Grade 1 was noted, except for transient Grade 3 neuropathy in 1 patient. Conclusions: Seeds remained in the right place, as assessed by fluoroscopy, absence of significant pre- to postplan dose-volume histogram change for critical organs, and total irradiated breast volume. The method could be proposed as a boost when high dosimetric selectivity is required (young patients after cardiotoxic chemotherapy for left-sided cancer). This boost series was a preliminary step before testing partial breast irradiation by permanent seed implant in a prospective trial.

Jansen, Nicolas [Department of Radiation Oncology, Liege University Hospital, Liege (Belgium)]. E-mail: nicolas.jansen@chu.ulg.ac.be; Deneufbourg, Jean-Marie [Department of Radiation Oncology, Liege University Hospital, Liege (Belgium); Nickers, Philippe [Department of Radiation Oncology, Liege University Hospital, Liege (Belgium)

2007-03-15T23:59:59.000Z

439

Modeling Fission Product Sorption in Graphite Structures  

SciTech Connect (OSTI)

The goal of this project is to determine changes in adsorption and desorption of fission products to/from nuclear-grade graphite in response to a changing chemical environment. First, the project team will employ principle calculations and thermodynamic analysis to predict stability of fission products on graphite in the presence of structural defects commonly observed in very high- temperature reactor (VHTR) graphites. Desorption rates will be determined as a function of partial pressure of oxygen and iodine, relative humidity, and temperature. They will then carry out experimental characterization to determine the statistical distribution of structural features. This structural information will yield distributions of binding sites to be used as an input for a sorption model. Sorption isotherms calculated under this project will contribute to understanding of the physical bases of the source terms that are used in higher-level codes that model fission product transport and retention in graphite. The project will include the following tasks: Perform structural characterization of the VHTR graphite to determine crystallographic phases, defect structures and their distribution, volume fraction of coke, and amount of sp2 versus sp3 bonding. This information will be used as guidance for ab initio modeling and as input for sorptivity models; Perform ab initio calculations of binding energies to determine stability of fission products on the different sorption sites present in nuclear graphite microstructures. The project will use density functional theory (DFT) methods to calculate binding energies in vacuum and in oxidizing environments. The team will also calculate stability of iodine complexes with fission products on graphite sorption sites; Model graphite sorption isotherms to quantify concentration of fission products in graphite. The binding energies will be combined with a Langmuir isotherm statistical model to predict the sorbed concentration of fission products on each type of graphite site. The model will include multiple simultaneous adsorbing species, which will allow for competitive adsorption effects between different fission product species and O and OH (for modeling accident conditions).

Szlufarska, Izabela [University of Wisconsin, Madison, WI (United States); Morgan, Dane [University of Wisconsin, Madison, WI (United States); Allen, Todd [University of Wisconsin, Madison, WI (United States)

2013-04-08T23:59:59.000Z

440

X-ray intravital microscopy for functional imaging in rat hearts using synchrotron radiation coronary microangiography  

SciTech Connect (OSTI)

An X-ray intravital microscopy technique was developed to enable in vivo visualization of the coronary, cerebral, and pulmonary arteries in rats without exposure of organs and with spatial resolution in the micrometer range and temporal resolution in the millisecond range. We have refined the system continually in terms of the spatial resolution and exposure time. X-rays transmitted through an object are detected by an X-ray direct-conversion type detector, which incorporates an X-ray SATICON pickup tube. The spatial resolution has been improved to 6 {mu}m, yielding sharp images of small arteries. The exposure time has been shortened to around 2 ms using a new rotating-disk X-ray shutter, enabling imaging of beating rat hearts. Quantitative evaluations of the X-ray intravital microscopy technique were extracted from measurements of the smallest-detectable vessel size and detection of the vessel function. The smallest-diameter vessel viewed for measurements is determined primarily by the concentration of iodinated contrast material. The iodine concentration depends on the injection technique. We used ex vivo rat hearts under Langendorff perfusion for accurate evaluation. After the contrast agent is injected into the origin of the aorta in an isolated perfused rat heart, the contrast agent is delivered directly into the coronary arteries with minimum dilution. The vascular internal diameter response of coronary arterial circulation is analyzed to evaluate the vessel function. Small blood vessels of more than about 50 {mu}m diameters were visualized clearly at heart rates of around 300 beats/min. Vasodilation compared to the control was observed quantitatively using drug manipulation. Furthermore, the apparent increase in the number of small vessels with diameters of less than about 50 {mu}m was observed after the vasoactive agents increased the diameters of invisible small blood vessels to visible sizes. This technique is expected to offer the potential for direct investigation of mechanisms of vascular dysfunctions.

Umetani, K. [Japan Synchrotron Radiation Research Institute, SPring-8, Sayo-cho, Sayo-gun, Hyogo 679-5198 (Japan); Fukushima, K. [National Cerebral and Cardiovascular Center Hospital, Fujishirodai, Suita-shi, Osaka 565-8565 (Japan)

2013-03-15T23:59:59.000Z

Note: This page contains sample records for the topic "iodine phos phorus" from the National Library of EnergyBeta (NLEBeta).
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441

Implementation of dual-energy technique for virtual monochromatic and linearly mixed CBCTs  

SciTech Connect (OSTI)

Purpose: To implement dual-energy imaging technique for virtual monochromatic (VM) and linearly mixed (LM) cone beam CTs (CBCTs) and to demonstrate their potential applications in metal artifact reduction and contrast enhancement in image-guided radiation therapy (IGRT). Methods: A bench-top CBCT system was used to acquire 80 kVp and 150 kVp projections, with an additional 0.8 mm tin filtration. To implement the VM technique, these projections were first decomposed into acrylic and aluminum basis material projections to synthesize VM projections, which were then used to reconstruct VM CBCTs. The effect of VM CBCT on the metal artifact reduction was evaluated with an in-house titanium-BB phantom. The optimal VM energy to maximize contrast-to-noise ratio (CNR) for iodine contrast and minimize beam hardening in VM CBCT was determined using a water phantom containing two iodine concentrations. The LM technique was implemented by linearly combining the low-energy (80 kVp) and high-energy (150 kVp) CBCTs. The dose partitioning between low-energy and high-energy CBCTs was varied (20%, 40%, 60%, and 80% for low-energy) while keeping total dose approximately equal to single-energy CBCTs, measured using an ion chamber. Noise levels and CNRs for four tissue types were investigated for dual-energy LM CBCTs in comparison with single-energy CBCTs at 80, 100, 125, and 150 kVp. Results: The VM technique showed substantial reduction of metal artifacts at 100 keV with a 40% reduction in the background standard deviation compared to a 125 kVp single-energy scan of equal dose. The VM energy to maximize CNR for both iodine concentrations and minimize beam hardening in the metal-free object was 50 keV and 60 keV, respectively. The difference of average noise levels measured in the phantom background was 1.2% between dual-energy LM CBCTs and equivalent-dose single-energy CBCTs. CNR values in the LM CBCTs of any dose partitioning are better than those of 150 kVp single-energy CBCTs. The average CNR for four tissue types with 80% dose fraction at low-energy showed 9.0% and 4.1% improvement relative to 100 kVp and 125 kVp single-energy CBCTs, respectively. CNRs for low-contrast objects improved as dose partitioning was more heavily weighted toward low-energy (80 kVp) for LM CBCTs. Conclusions: Dual-energy CBCT imaging techniques were implemented to synthesize VM CBCT and LM CBCTs. VM CBCT was effective at achieving metal artifact reduction. Depending on the dose-partitioning scheme, LM CBCT demonstrated the potential to improve CNR for low contrast objects compared to single-energy CBCT acquired with equivalent dose.

Li Hao; Giles, William; Ren Lei; Bowsher, James; Yin Fangfang [Medical Physics Graduate Program, Duke University, Durham, North Carolina 27710 (United States); Department of Radiation Oncology, Duke University Medical Center, Durham, North Carolina 27710 (United States)

2012-10-15T23:59:59.000Z

442

Peripheral Venous Access Ports: Outcomes Analysis in 109 Patients  

SciTech Connect (OSTI)

Purpose: To perform a retrospective outcomes analysis of central venous catheters with peripheral venous access ports, with comparison to published data.Methods: One hundred and twelve central venous catheters with peripherally placed access ports were placed under sonographic guidance in 109 patients over a 4-year period. Ports were placed for the administration of chemotherapy, hyperalimentation, long-term antibiotic therapy, gamma-globulin therapy, and frequent blood sampling. A vein in the upper arm was accessed in each case and the catheter was passed to the superior vena cava or right atrium. Povidone iodine skin preparation was used in the first 65 port insertions. A combination of Iodophor solution and povidone iodine solution was used in the last 47 port insertions. Forty patients received low-dose (1 mg) warfarin sodium beginning the day after port insertion. Three patients received higher doses of warfarin sodium for preexistent venous thrombosis. Catheter performance and complications were assessed and compared with published data.Results: Access into the basilic or brachial veins was obtained in all cases. Ports remained functional for a total of 28,936 patient days. The port functioned in 50% of patients until completion of therapy, or the patient's expiration. Ports were removed prior to completion of therapy in 18% of patients. Eleven patients (9.9% of ports placed) suffered an infectious complication (0.38 per thousand catheter-days)-in nine, at the port implantation site, in two along the catheter. In all 11 instances the port was removed. Port pocket infection in the early postoperative period occurred in three patients (4.7%) receiving a Betadine prep vs two patients (4.2%) receiving a standard O.R. prep. This difference was not statistically significant (p = 0.9). Venous thrombosis occurred in three patients (6.8%) receiving warfarin sodium and in two patients (3%) not receiving warfarin sodium. This difference was not statistically significant (p = 0.6). Aspiration occlusion occurred in 13 patients (11.7%). Intracatheter urokinase was infused in eight of these patients and successfully restored catheter function in all but two instances. These complication rates are comparable to or better than those reported with chest ports.Conclusion: Peripheral ports for long-term central venous access placed by interventional radiologists in the interventional radiology suite are as safe and as effective as chest ports.

Bodner, Leonard J.; Nosher, John L.; Patel, Kaushik M.; Siegel, Randall L.; Biswal, Rajiv; Gribbin, Christopher E.; Tokarz, Robert [Department of Radiology, MEB 404, UMDNJ-Robert Wood Johnson Medical School, One Robert Wood Johnson Place, New Brunswick, NJ 08903-0019 (United States)

2000-03-15T23:59:59.000Z

443

Exposure to pyrethroids insecticides and serum levels of thyroid-related measures in pregnant women  

SciTech Connect (OSTI)

Possible association between environmental exposure to pyrethroid insecticides and serum thyroid-related measures was explored in 231 pregnant women of 1012 gestational weeks recruited at a university hospital in Tokyo during 20092011. Serum levels of free thyroxine (fT4), thyroid stimulating hormone (TSH) and thyroid biding globulin (TBG) and urinary pyrethroid insecticide metabolite (3-phenoxybenzoic acid, 3-PBA) were measured. Obstetrical information was obtained from medical records and dietary and lifestyle information was collected by self-administered questionnaire. Geometric mean concentration of creatinine-adjusted urinary 3-PBA was 0.363 (geometric standard deviation: 3.06) ?g/g cre, which was consistent with the previously reported levels for non-exposed Japanese adult females. The range of serum fT4, TSH and TBG level was 0.833.41 ng/dL, 0.0127.4 ?IU/mL and 16.454.4 ?g/mL, respectively. Multiple regression analysis was carried out by using either one of serum levels of thyroid-related measures as a dependent variable and urinary 3-PBA as well as other potential covariates (age, pre-pregnancy BMI, parity, urinary iodine, smoking and drinking status) as independent variables: 3-PBA was not found as a significant predictor of serum level of thyroid-related measures. Lack of association may be due to lower pyrethroid insecticide exposure level of the present subjects. Taking the ability of pyrethroid insecticides and their metabolite to bind to nuclear thyroid hormone (TH) receptor, as well as their ability of placental transfer, into consideration, it is warranted to investigate if pyrethroid pesticides do not have any effect on TH actions in fetus brain even though maternal circulating TH level is not affected. -- Highlights: Pyrethroid exposure and thyroid hormone status was examined in pregnant women. Urinary 3-phenoxybenzoic acid was used as a biomarker of exposure. Iodine nutrition, age and other covariates were included in statistical models. No association was found between levels of thyroid hormone and pyrethroid exposure. The result may be ascribed to lower exposure level.

Zhang, Jie; Hisada, Aya [Department of Environmental Studies, The University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8563 (Japan)] [Department of Environmental Studies, The University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8563 (Japan); Yoshinaga, Jun, E-mail: junyosh@k.u-tokyo.ac.jp [Department of Environmental Studies, The University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8563 (Japan)] [Department of Environmental Studies, The University of Tokyo, 5-1-5 Kashiwanoha, Kashiwa, Chiba 277-8563 (Japan); Shiraishi, Hiroaki [National Institute for Environmental Studies, Onogawa 16-2, Tsukuba, Ibaraki 305-8563 (Japan)] [National Institute for Environmental Studies, Onogawa 16-2, Tsukuba, Ibaraki 305-8563 (Japan); Shimodaira, Kazuhisa; Okai, Takashi [Department of Obstetrics and Gynecology, Showa University School of Medicine, 1-5-8 Hatanodai, Shinagawa, Tokyo 142-8555 (Japan)] [Department of Obstetrics and Gynecology, Showa University School of Medicine, 1-5-8 Hatanodai, Shinagawa, Tokyo 142-8555 (Japan); Noda, Yumiko; Shirakawa, Miyako; Kato, Nobumasa [Department of Psychiatry and Neurology, Showa University School of Medicine, 1-5-8 Hatanodai, Shinagawa, Tokyo 142-8555 (Japan)] [Department of Psychiatry and Neurology, Showa University School of Medicine, 1-5-8 Hatanodai, Shinagawa, Tokyo 142-8555 (Japan)

2013-11-15T23:59:59.000Z

444

Preparation and evaluation of 3-methyl isomers of 15-(p-iodophenyl)-3-methylpentadecanoic acid (BMIPP): 3R-BMIPP shows greater heart uptake than 3S-BMIPP in rats  

SciTech Connect (OSTI)

Iodine-123 racemic (3-R,S) BMIPP is of widespread interest for evaluation of myocardial viability. To evaluate the effects of the asymmetric C-3 center of BMIPP on heart uptake/clearance we have resolved and characterized 3R- and 3S-BMIPP (H-1 and C-13 NMR, MS, HPLC, [{alpha}], m.p.) and evaluated the radioiodinated isomers in rats. A thiophene {open_quotes}template{close_quotes} approach using ethyl 3R-methylglutarate was used to synthesize the authentic 3R-BMPPA substrate (mp 41-42 {degrees}C, [{alpha}] + 1.45 {degrees}). Reaction of racemic 3-R, S-BNPPA with S-(-)-{alpha}-methylbenzylamine gave the diastereomeric amides, separated by TLC, column or HPLC. The more polar isomer was identical to the amide prepared from the 3R-isomer. HCI cleavage of the purified diastereomers provided 3R- and 3S-BMPPA (mp 40-41 {degrees}C, [{alpha}] - 3.90 {degrees}). Iodination (TTFAA/KI) gave 3R-BMIPP (mp 51-52 {degrees}C, [{alpha}] + 0.74 {degrees}) and 3S-BMIPP (mp 45-46 {degrees}C, [{alpha}] - 1.67 {degrees}), which formed amides identical with the two amides separated from the 3-R, S-BMIPP amide mixture. A [I-125]-3R-BMIPP and [I-131]-3S-BMIPP mixture was administered to groups of fasted rats (n = 5/group) sacrificed at 5, 15, 60 and 180 minutes. While blood levels and uptake and clearance from liver, lungs and kidney were nearly identical for both isomers, 3R-BMIPP had higher heart uptake at all periods evaluated (%ID/gram, i.e., 15 min: 3R = 5.25 {plus_minus} 0.77, 3S= 4.51 {plus_minus} 0.50; 180 min: 3R = 2.31 {plus_minus} 0.51, 3S = 1.98 {plus_minus} 0.26), suggesting that transport into the myocytes is different for the isomers. Higher heart uptake suggests that the 3R-BMIPP isomer should be further evaluated.

Knapp, F.F.R. Jr.; Lin, Q.; Luo, H. [Oak Ridge National Lab., TN (United States)] [and others

1996-05-01T23:59:59.000Z

445

Comparison of blood flow models and acquisitions for quantitative myocardial perfusion estimation from dynamic CT  

Science Journals Connector (OSTI)

Myocardial blood flow (MBF) can be estimated from dynamic contrast enhanced (DCE) cardiac CT acquisitions, leading to quantitative assessment of regional perfusion. The need for low radiation dose and the lack of consensus on MBF estimation methods motivates this study to refine the selection of acquisition protocols and models for CT-derived MBF. DCE cardiac CT acquisitions were simulated for a range of flow states (MBF = 0.5, 1, 2, 3ml (min g)?1, cardiac output = 3, 5, 8 L min?1). Patient kinetics were generated by a mathematical model of iodine exchange incorporating numerous physiological features including heterogenenous microvascular flow, permeability and capillary contrast gradients. CT acquisitions were simulated for multiple realizations of realistic x-ray flux levels. CT acquisitions that reduce radiation exposure were implemented by varying both temporal sampling (1, 2, and 3s sampling intervals) and tube currents (140, 70, and 25 mAs). For all acquisitions, we compared three quantitative MBF estimation methods (two-compartment model, an axially-distributed model, and the adiabatic approximation to the tissue homogeneous model) and a qualitative slope-based method. In total, over 11000 time attenuation curves were used to evaluate MBF estimation in multiple patient and imaging scenarios. After iodine-based beam hardening correction, the slope method consistently underestimated flow by on average 47.5% and the quantitative models provided estimates with less than 6.5% average bias and increasing variance with increasing dose reductions. The three quantitative models performed equally well, offering estimates with essentially identical root mean squared error (RMSE) for matched acquisitions. MBF estimates using the qualitative slope method were inferior in terms of bias and RMSE compared to the quantitative methods. MBF estimate error was equal at matched dose reductions for all quantitative methods and range of techniques evaluated. This suggests that there is no particular advantage between quantitative estimation methods nor to performing dose reduction via tube current reduction compared to temporal sampling reduction. These data are important for optimizing implementation of cardiac dynamic CT in clinical practice and in prospective CT MBF trials.

Michael Bindschadler; Dimple Modgil; Kelley R Branch; Patrick J La Riviere; Adam M Alessio

2014-01-01T23:59:59.000Z

446

The extended chain compounds Ln {sub 12}(C{sub 2}){sub 3}I{sub 17} (Ln=Pr, Nd, Gd, Dy): Synthesis, structure and physical properties  

SciTech Connect (OSTI)

The title compounds are obtained in high yield from stoichiometric mixtures of Ln, LnI{sub 3} and graphite, heated at 900-950 deg. C in welded Ta containers. The crystal structures of new Pr and Nd phases determined by single-crystal X-ray diffraction are related to those of other Ln {sub 12}(C{sub 2}){sub 3}I{sub 17}-type compounds (C 2/c, a=19.610(1) and 19.574(4) A, b=12.406(2) and 12.393(3) A, c=19.062(5) and 19.003(5) A, {beta}=90.45(3){sup o} and 90.41(3){sup o}, for Pr{sub 12}(C{sub 2}){sub 3}I{sub 17} and Nd{sub 12}(C{sub 2}){sub 3}I{sub 17}, respectively). All compounds contain infinite zigzag chains of C{sub 2}-centered metal atom octahedra condensed by edge-sharing into the [tcc] {sub {infinity}} sequence (c=cis, t=trans) and surrounded by edge-bridging iodine atoms as well as by apical iodine atoms that bridge between chains. The polycrystalline Gd{sub 12}(C{sub 2}){sub 3}I{sub 17} sample exhibits semiconducting thermal behavior which is consistent with an ionic formulation (Ln {sup 3+}){sub 12}(C{sub 2} {sup 6-}){sub 3}(I{sup -}){sub 17}(e{sup -}) under the assumption that one extra electron is localized in metal-metal bonding. The magnetization measurements on Nd{sub 12}(C{sub 2}){sub 3}I{sub 17}, Gd{sub 12}(C{sub 2}){sub 3}I{sub 17} and Dy{sub 12}(C{sub 2}){sub 3}I{sub 17} indicate the coexistence of competing magnetic interactions leading to spin freezing at T {sub f}=5 K for the Gd phase. The Nd and Dy compounds order antiferromagnetically at T {sub N}=25 and 29 K, respectively. For Dy{sub 12}(C{sub 2}){sub 3}I{sub 17}, a metamagnetic transition is observed at a critical magnetic field H{approx}25 kOe. - Graphical abstract: Zigzag chains of edge-sharing metal atom octahedra in Ln {sub 12}(C{sub 2}){sub 3}I{sub 17}.

Ryazanov, Mikhail [Max-Planck-Institut fuer Festkoerperforschung, Heisenbergstr. 1, D-70569 Stuttgart (Germany); Mattausch, Hansjuergen [Max-Planck-Institut fuer Festkoerperforschung, Heisenbergstr. 1, D-70569 Stuttgart (Germany); Simon, Arndt [Max-Planck-Institut fuer Festkoerperforschung, Heisenbergstr. 1, D-70569 Stuttgart (Germany)], E-mail: A.Simon@fkf.mpg.de

2007-04-15T23:59:59.000Z

447

Fluorspar  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Fluorspar Fluorspar Nature Bulletin No. 361-A December 6, 1969 Forest Preserve District of Cook County George W. Dunne, President Roland F. Eisenbeis, Supt. of Conservation FLUORSPAR Among all the states, Illinois stands at the top or very near the top in its production of corn, hogs, soybeans, oats and chickens. The same is true in industries: meat packing, steel, agricultural machinery, tractors, radios, telephones, paint, candy and many others. It is one of the leading producers of coal. Not commonly known, however, is the fact that the world's largest fluorite mines are located in Pope and Hardin counties along the Ohio River, and few people realize what an important part this mineral plays in our daily lives. Chlorine, bromine, iodine and fluorine are chemical elements always found in combination with some metal. Common salt is chloride of sodium. Fluorspar, or Fluorite, is fluoride of calcium. Although quite common, occurring in several states and in foreign countries, there are few deposits with veins large enough to be mined commercially. Almost half of what is used in this country comes from southern Illinois and most of the remainder from Kentucky, just across the river. It is mined from veins as much as 800 feet below the surface.

448

It's Elemental - The Periodic Table of Elements - Elements Listed by Atomic  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Atomic Number Atomic Number 1 Hydrogen H 2 Helium He 3 Lithium Li 4 Beryllium Be 5 Boron B 6 Carbon C 7 Nitrogen N 8 Oxygen O 9 Fluorine F 10 Neon Ne 11 Sodium Na 12 Magnesium Mg 13 Aluminum Al 14 Silicon Si 15 Phosphorus P 16 Sulfur S 17 Chlorine Cl 18 Argon Ar 19 Potassium K 20 Calcium Ca 21 Scandium Sc 22 Titanium Ti 23 Vanadium V 24 Chromium Cr 25 Manganese Mn 26 Iron Fe 27 Cobalt Co 28 Nickel Ni 29 Copper Cu 30 Zinc Zn 31 Gallium Ga 32 Germanium Ge 33 Arsenic As 34 Selenium Se 35 Bromine Br 36 Krypton Kr 37 Rubidium Rb 38 Strontium Sr 39 Yttrium Y 40 Zirconium Zr 41 Niobium Nb 42 Molybdenum Mo 43 Technetium Tc 44 Ruthenium Ru 45 Rhodium Rh 46 Palladium Pd 47 Silver Ag 48 Cadmium Cd 49 Indium In 50 Tin Sn 51 Antimony Sb 52 Tellurium Te 53 Iodine I 54 Xenon Xe 55 Cesium Cs 56 Barium Ba 57 Lanthanum La 58 Cerium Ce

449

It's Elemental - The Periodic Table of Elements - Elements Listed by  

Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

Chemical Name Chemical Name Actinium Ac 89 Aluminum Al 13 Americium Am 95 Antimony Sb 51 Argon Ar 18 Arsenic As 33 Astatine At 85 Barium Ba 56 Berkelium Bk 97 Beryllium Be 4 Bismuth Bi 83 Bohrium Bh 107 Boron B 5 Bromine Br 35 Cadmium Cd 48 Calcium Ca 20 Californium Cf 98 Carbon C 6 Cerium Ce 58 Cesium Cs 55 Chlorine Cl 17 Chromium Cr 24 Cobalt Co 27 Copernicium Cn 112 Copper Cu 29 Curium Cm 96 Darmstadtium Ds 110 Dubnium Db 105 Dysprosium Dy 66 Einsteinium Es 99 Erbium Er 68 Europium Eu 63 Fermium Fm 100 Flerovium Fl 114 Fluorine F 9 Francium Fr 87 Gadolinium Gd 64 Gallium Ga 31 Germanium Ge 32 Gold Au 79 Hafnium Hf 72 Hassium Hs 108 Helium He 2 Holmium Ho 67 Hydrogen H 1 Indium In 49 Iodine I 53 Iridium Ir 77 Iron Fe 26 Krypton Kr 36 Lanthanum La 57 Lawrencium Lr 103 Lead Pb 82 Lithium Li 3 Livermorium Lv 116

450

Contaminant Release Data Package for Residual Waste in Single-Shell Hanford Tanks  

SciTech Connect (OSTI)

The Hanford Federal Facility Agreement and Consent Order requires that a Resource Conservation and Recovery Act (RCRA) Facility Investigation report be submitted to the Washington State Department of Ecology. The RCRA Facility Investigation report will provide a detailed description of the state of knowledge needed for tank farm performance assessments. This data package provides detailed technical information about contaminant release from closed single-shell tanks necessary to support the RCRA Facility Investigation report. It was prepared by Pacific Northwest National Laboratory (PNNL) for CH2M HILL Hanford Group, Inc., which is tasked by the U.S. Department of Energy (DOE) with tank closure. This data package is a compilation of contaminant release rate data for residual waste in the four Hanford single-shell tanks (SSTs) that have been tested (C-103, C-106, C-202, and C-203). The report describes the geochemical properties of the primary contaminants of interest from the perspective of long-term risk to groundwater (uranium, technetium-99, iodine-129, chromium, transuranics, and nitrate), the occurrence of these contaminants in the residual waste, release mechanisms from the solid waste to water infiltrating the tanks in the future, and the laboratory tests conducted to measure release rates.

Deutsch, William J.; Cantrell, Kirk J.; Krupka, Kenneth M.

2007-12-01T23:59:59.000Z

451

Development of the Updated Environmental Protection Agency Manual of Protective Action Guides (PAGS) and Protective Actions for Nuclear Incidents  

SciTech Connect (OSTI)

As a student intern with the United States Environmental Protection Agency (EPA) Headquarters, the author was trained in the National Response Plan (NRP) and assisted in the editing of the new (unpublished) EPA Protective Action Guides (PAGs) [1] which has been revised in light of the perceived post 9/11 potential for 'Dirty Bomb' and 'Improvised Nuclear Device' attacks on civilian areas. Technical aspects and the public policy aspects of developing the new guides are discussed. Early Phase initial responses discussed include: Notification of state and/or local authorities, immediate evacuation/sheltering prior to release information or measurements, monitoring of releases and exposure rate measurements, estimation of dose consequences, implementation of protective actions in other areas. The new PAG clarifies the use of 1992 PAGs [2] for incidents other than nuclear power plant accidents, lowers projected thyroid dose for potassium iodine (KI), provides drinking water guidance, includes guidance for long-term site restoration, and updates dosimetry from ICRP 26 to ICRP 60. (authors)

Carter, L.M. [Texas A and M Univ., College Station, TX (United States)

2008-07-01T23:59:59.000Z

452

Spatial Analysis of Contaminants in 200 West Area Groundwater in Support of the 200-ZP-1 Operable Unit Pre-Conceptual Remedy Design  

SciTech Connect (OSTI)

This report documents a preliminary spatial and geostatistical analysis of the distribution of several contaminants of interest (COIs) in groundwater within the unconfined aquifer beneath the 200 West Area of the Hanford Site. The contaminant plumes of interest extend within the 200-ZP-1 and 200-UP-1 groundwater operable units. The COIs included in the PNNL study were carbon tetrachloride (CTET), technetium-99 (Tc-99), iodine-129 (I-129), chloroform, plutonium, uranium, trichloroethylene (TCE), and nitrate. The project included three tasks. Task 1 involved the development of a database that includes all relevant depth-discrete data on the distribution of COIs in the study area. The second task involved a spatial analysis of the three-dimensional (3D) distribution of data for the COIs in the study area. The main focus of the task was to determine if sufficient data are available for geostatistical mapping of the COIs in 3D. Task 3 involved the generation of numerical grids of the concentration of CTET, chloroform, and Tc-99.

Murray, Christopher J.; Bott, Yi-Ju

2008-12-30T23:59:59.000Z

453

Chapter 22 - Heterogeneous Catalytic Reduction for Water Purification: Nanoscale Effects on Catalytic Activity, Selectivity, and Sustainability  

Science Journals Connector (OSTI)

Reductive catalysis is a promising water treatment technology that employs heterogeneous metal catalysts (e.g., Pd nanoparticles on a support) to convert dihydrogen to adsorbed atomic hydrogen in order to promote reactions with functional groups in various contaminants. Reductive catalysis has several potential advantages, including high selectivity for a given target, fast rates under mild conditions, and low production of harmful by-products. The technology has been applied mostly for remediation of groundwater contaminated with halogenated hydrocarbons and for treatment of nitrate, but recent studies have expanded the range of target contaminants to include perchlorate and N-nitrosamines. Palladium-based catalysts hold tremendous promise for their ability to selectively destroy several drinking water contaminants, and some compounds that exhibit slow reaction kinetics with Pd alone are rapidly degraded when a second, promoter metal is added to the catalyst. However, there is a lack of information about the long-term sustainability of these catalytic treatment processes, which is a major consideration in their possible adoption for remediation applications. Recent research has focused on the nanoscale characterization of these heterogeneous catalysts in order to develop an improved understanding of their mechanisms of deactivation and the pathways for regeneration. Two examples of studies from the authors laboratories, involving (i) hydrodehalogenation of iodinated X-ray contrast media with Ni or Pd catalysts and (ii) selective reduction of nitrate with a regenerable Pd-In/alumina catalyst, are discussed in this chapter.

Timothy J. Strathmann; Charles J. Werth; John R. Shapley

2014-01-01T23:59:59.000Z

454

Dye-sensitized solar cells based on electrospun polyacrylonitrile (PAN) nanofibre membrane gel electrolyte  

Science Journals Connector (OSTI)

Abstract Dye Sensitized Solar Cells (DSSCs) based on electrospun nanofibre membrane electrolytes offer several advantages over liquid electrolyte based solar cells. Nanofibre membranes having different thicknesses were prepared by electrospinning on platinum electrodes from a 11 wt% solution of polyacrylonitrile (PAN) in N,N-dimethylformamide (DMF) at an applied voltage of 8kV. The membranes were then activated by immersing in a solution containing potassium iodide (KI) (0.06g), propylene carbonate (PC) (0.8g) and iodine (I2) (0.0092g) for 30minutes to obtain gel type membrane electrolytes with different thicknesses. These nanofibre membrane electrolytes were used to fabricate quasi-solid state (gel) \\{DSSCs\\} and the performance of these solar cells were compared with \\{DSSCs\\} fabricated with liquid electrolyte (KI:PC:I2) and conventional PAN based gel electrolyte (PAN:KI:PC:I2). DSSC with nanofibre membrane electrolyte of thickness 9.14?m showed the highest light-to-electricity conversion efficiency of 5.2% whereas an identical cell based on corresponding liquid electrolyte showed an efficiency of 5.3%. The open circuit voltage (VOC), short circuit current density (JSc) and fill factor for the solar cell based on this electrolyte was 0.67V, 13.31mAcm?2 and 59% respectively at an incident light intensity of 1000Wm?2 with a 1.5 AM filter.

M.A.K.L. Dissanayake; H.K.D.W.M.N.R. Divarathne; C.A. Thotawatthage; C.B. Dissanayake; G.K.R. Senadeera; B.M.R. Bandara

2014-01-01T23:59:59.000Z

455

U.S./Belarus/Ukraine joint research on the biomedical effects of the Chernobyl Reactor Accident. Final report  

SciTech Connect (OSTI)

The National Cancer Institute has negotiated with the governments of Belarus and Ukraine (Ministers/Ministries of Health, institutions and scientists) to develop scientific research protocols to study the effects of radioactive iodine released by the Chernobyl accident upon thyroid anatomy and function in defined cohorts of persons under the age of 19 years at the time of the accident. These studies include prospective long term medical follow-up of the cohort and the reconstruction of the radiation dose to each cohort subject's thyroid. The protocol for the study in Belarus was signed by the US and Belorussian governments in May 1994 and the protocol for the study in Ukraine was signed by the US and Ukraine in May 1995. A second scientific research protocol also was negotiated with Ukraine to study the feasibility of a long term study to follow the development of leukemia and lymphoma among Ukrainian cleanup workers; this protocol was signed by the US and Ukraine in October 1996.

Bruce Wachholz

2000-06-20T23:59:59.000Z

456

Radionuclide Retention in Concrete Wasteforms  

SciTech Connect (OSTI)

Assessing long-term performance of Category 3 waste cement grouts for radionuclide encasement requires knowledge of the radionuclide-cement interactions and mechanisms of retention (i.e., sorption or precipitation); the mechanism of contaminant release; the significance of contaminant release pathways; how wasteform performance is affected by the full range of environmental conditions within the disposal facility; the process of wasteform aging under conditions that are representative of processes occurring in response to changing environmental conditions within the disposal facility; the effect of wasteform aging on chemical, physical, and radiological properties; and the associated impact on contaminant release. This knowledge will enable accurate prediction of radionuclide fate when the wasteforms come in contact with groundwater. Data collected throughout the course of this work will be used to quantify the efficacy of concrete wasteforms, similar to those used in the disposal of LLW and MLLW, for the immobilization of key radionuclides (i.e., uranium, technetium, and iodine). Data collected will also be used to quantify the physical and chemical properties of the concrete affecting radionuclide retention.

Wellman, Dawn M.; Jansik, Danielle P.; Golovich, Elizabeth C.; Cordova, Elsa A.

2012-09-24T23:59:59.000Z

457

Future Supply of Medical Radioisotopes for the UK Report 2014  

E-Print Network [OSTI]

The UK has no research nuclear reactors and relies on the importation of 99Mo and other medical radioisotopes (e.g. Iodine-131) from overseas (excluding PET radioisotopes). The UK is therefore vulnerable not only to global shortages, but to problems with shipping and importation of the products. In this context Professor Erika Denton UK national Clinical Director for Diagnostics requested that the British Nuclear Medicine Society lead a working group with stakeholders including representatives from the Science & Technology Facilities Council (STFC) to prepare a report. The group had a first meeting on 10 April 2013 followed by a working group meeting with presentations on 9th September 2013 where the scope of the work required to produce a report was agreed. The objectives of the report are: to describe the status of the use of medical radioisotopes in the UK; to anticipate the potential impact of shortages for the UK; to assess potential alternative avenues of medical radioisotope production for the UK m...

Neilly, Brian; Ballinger, Jim; Buscombe, John; Clarke, Rob; Ellis, Beverley; Flux, Glenn; Fraser, Louise; Hall, Adrian; Owen, Hywel; Paterson, Audrey; Perkins, Alan; Scarsbrook, Andrew

2015-01-01T23:59:59.000Z

458

Selected radionuclides important to low-level radioactive waste management  

SciTech Connect (OSTI)

The purpose of this document is to provide information to state representatives and developers of low level radioactive waste (LLW) management facilities about the radiological, chemical, and physical characteristics of selected radionuclides and their behavior in the environment. Extensive surveys of available literature provided information for this report. Certain radionuclides may contribute significantly to the dose estimated during a radiological performance assessment analysis of an LLW disposal facility. Among these are the radionuclides listed in Title 10 of the Code of Federal Regulations Part 61.55, Tables 1 and 2 (including alpha emitting transuranics with half-lives greater than 5 years). This report discusses these radionuclides and other radionuclides that may be significant during a radiological performance assessment analysis of an LLW disposal facility. This report not only includes essential information on each radionuclide, but also incorporates waste and disposal information on the radionuclide, and behavior of the radionuclide in the environment and in the human body. Radionuclides addressed in this document include technetium-99, carbon-14, iodine-129, tritium, cesium-137, strontium-90, nickel-59, plutonium-241, nickel-63, niobium-94, cobalt-60, curium -42, americium-241, uranium-238, and neptunium-237.

NONE

1996-11-01T23:59:59.000Z

459

The distribution of 129I around West Valley, an inactive nuclear fuel reprocessing facility in Western New York  

Science Journals Connector (OSTI)

A study of 129I levels in surface waters around an inactive nuclear fuel reprocessing facility at West Valley, Cattaraugus County, New York shows a strong presence of this long-lived radoiisotope (T12 = 15.7 Ma) of iodine around the facility. The signal is strong in creeks which drain the facility as well as those in the general vicinity over two decades after reprocessing activities at the site ceased in 1972. Highest 129I levels (1.36 1011 atoms/L) are observed at the site boundary in Buttermilk Creek which drains the site, and the resulting plume can be tracked into Lake Erie via Cattaraugus Creek. Other creeks in the West Valley area which do not receive drainage from the site have 129I concentrations on the order of 1091010 atoms/L, indicating that atmospheric transport of the radionuclide is significant. 129I levels in surface waters around West Valley are 101000 times higher than background lelels in western New York, including 129I levels around active nuclear power plants (reported in Rao and Fehn, in preparation), and 10010000 times higher than levels of 129I in areas outside western New York. However, 36ClCl and 3H measurements in Buttermilk Creek at the site boundary are consistent with present day rainwater values for the region.

Usha Rao; Udo Fehn

1997-01-01T23:59:59.000Z

460

A New F-18 Labeled PET Agent For Imaging Alzheimer's Plaques  

SciTech Connect (OSTI)

Amyloid plaques and neurofibrillary tangles are hallmarks of Alzheimer's disease (AD). Advances in development of imaging agents have focused on targeting amyloid plaques. Notable success has been the development of C-11 labeled PIB (Pittsburgh Compound) and a number of studies have demonstrated the utility of this agent. However, the short half life of C-11 (t1/2: 20 min), is a limitation, thus has prompted the development of F-18 labeled agents. Most of these agents are derivatives of amyloid binding dyes; Congo red and Thioflavin. Some of these agents are in clinical trials with encouraging results. We have been exploring new class of agents based on 8-hydroxy quinoline, a weak metal chelator, targeting elevated levels of metals in plaques. Iodine-123 labeled clioquinol showed affinity for amyloid plaques however, it had limited brain uptake and was not successful in imaging in intact animals and humans. We have been successful in synthesizing F-18 labeled 8-hydroxy quinoline. Small animal PET/CT imaging studies with this agent showed high (7-10% ID/g), rapid brain uptake and fast washout of the agent from normal mice brains and delayed washout from transgenic Alzheimer's mice. These promising results encouraged us in further evaluation of this class of compounds for imaging AD plaques.

Kulkarni, Padmakar V.; Hao Guiyang; Arora, Veera; Long, Michael; Slavine, Nikolai; Chiguru, Srinivas; Qu Baoxi; Sun Xiankai; Bennett, Michael; Antich, Peter P.; Bonte, Frederick J. [UT Southwestern Medical Center, 5323 Harry Hines Blvd., Dallas, TX 75390 (United States); Vasdev, Neil [CAMH PET Centre and Department of Psychiatry, University of Toronto, Toronto ONT, M5T-1R8 (Canada)

2011-06-01T23:59:59.000Z

Note: This page contains sample records for the topic "iodine phos phorus" from the National Library of EnergyBeta (NLEBeta).
While these samples are representative of the content of NLEBeta,
they are not comprehensive nor are they the most current set.
We encourage you to perform a real-time search of NLEBeta
to obtain the most current and comprehensive results.


461

DISSOLVED CONCENTRATION LIMITS OF RADIOACTIVE ELEMENTS  

SciTech Connect (OSTI)

The purpose of this study is to evaluate dissolved concentration limits (also referred to as solubility limits) of elements with radioactive isotopes under probable repository conditions, based on geochemical modeling calculations using geochemical modeling tools, thermodynamic databases, field measurements, and laboratory experiments. The scope of this modeling activity is to predict dissolved concentrations or solubility limits for 14 elements with radioactive isotopes (actinium, americium, carbon, cesium, iodine, lead, neptunium, plutonium, protactinium, radium, strontium, technetium, thorium, and uranium) important to calculated dose. Model outputs for uranium, plutonium, neptunium, thorium, americium, and protactinium are in the form of tabulated functions with pH and log (line integral) CO{sub 2} as independent variables, plus one or more uncertainty terms. The solubility limits for the remaining elements are either in the form of distributions or single values. The output data from this report are fundamental inputs for Total System Performance Assessment for the License Application (TSPA-LA) to determine the estimated release of these elements from waste packages and the engineered barrier system. Consistent modeling approaches and environmental conditions were used to develop solubility models for all of the actinides. These models cover broad ranges of environmental conditions so that they are applicable to both waste packages and the invert. Uncertainties from thermodynamic data, water chemistry, temperature variation, and activity coefficients have been quantified or otherwise addressed.

NA

2004-11-22T23:59:59.000Z

462

Fission product transport and behavior during two postulated loss-of-flow transients in the Advanced Test Reactor  

SciTech Connect (OSTI)

The fission product behavior during two postulated loss-of-flow accidents (leading to high- and low-pressure core degradations) in the Advanced Test Reactor (ATR) has been analyzed. These transients are designated ATR transients LCP 15 (high pressure) and LPP9 (low pressure). Normally, transients of this nature would be easily mitigated using existing safety systems and procedures. In these analyses, failure of these safety systems was assumed so that core degradation and fission product release could be studied. A probabilistic risk analysis was performed that indicated that the probability of occurrence for these two transients is on the order of 10[sup [minus]5] and 10[sup [minus]7] per reactor year for LCP15 and LPP9, respectively. The fission product behavior analysis included calculations of the gaseous and highly volatile fission product (xenon, krypton, cesium, iodine, and tellurium) inventories in the fuel before accident initiation, release of the fission products from the fuel into the reactor vessel during core melt, the probable chemical forms, and transport of the fission products from the core through the reactor vessel and existing piping to the confinement. In addition to a base-case analysis of fission product behavior, a series of analyses was performed to determine the sensitivity of fission product release to several parameters including steam flow rate, (structural) aluminum oxidation, and initial aerosol size. The base-case analyses indicate that the volatile fission products (excluding the noble gases) will be transported as condensed species on zinc aerosols.

Adams, J.P.; Carboneau, M.L.; Hagrman, D.L. (Idaho National Engineering Lab. EG and G Idaho, Idaho Falls, ID (United States))

1993-07-01T23:59:59.000Z

463

Regulation of thyroid peroxidase activity by thyrotropin, epidermal growth factor and phorbol ester in porcine thyroid follicles cultured in suspension  

Science Journals Connector (OSTI)

The activity of thyroid peroxidase (TPO) in porcine follicles cultured for 96 h in suspension with five hormones (5H) still attained over 50 % of that in the freshly isolated follicles. On the other hand, the activity in those cultured with 5H + TSH (6H) was several times higher than that cultured with 5H after 96 h, although an initial decrease of TPO activity during the first 24 h culture was observed in both conditions. The ability of follicles to metabolize iodide (uptake and organification) when cultured with 6H for 96 h was also several times higher than that of those cultured with 5H. The half-maximal dose of TSH for stimulation of TPO activity and iodide metabolism was 0.03 0.04 mU/ml and the effect was mediated by cAMP. These results indicate that in porcine thyroid follicles in primary suspension culture, TPO activity as well as the ability of iodine metabolism is induced by chronic TSH stimulation. In addition, epidermal growth factor (EGF, 10?9 M) and phorbol 12-myristate 13-acetate (PMA, 10?8 M) completely inhibited TSH stimulation on both activities and also basal (5H) activity of iodide metabolism.

Kikuo Kasai; Takeshi Ohmori; Narumi Koizumi; Toichiro Hosoya; Masaki Hiraiwa; Tatsushi Emoto; Yoshiyuki Hattori; Shin-Ichi Shimoda

1989-01-01T23:59:59.000Z

464

NCl(b) based short wavelength chemical laser. Final report, 15 October 1992-14 February 1994  

SciTech Connect (OSTI)

Based on the results of this work, the prospects of development of a visible chemical laser based on NCl(b) are promising. NCl, in the electronically excited b-state emits to the ground state at 665 nm. The NCl b-state is generated by energy-pooling of NCl(a) and excited iodine atoms I*. All of these species can be generated from chemical reactions solely. This work has shown that: (1) In the generation of NCl, the branching ratio for NCl(a) is high. 65% of the HN3 ends up in the NCl(a) state; (2) The rate constant for the energy-pooling reaction NCl(a) + I NCl(b) is quite favorably large, approximately 10-11 cu cm/sec; (3) A gain on the order of 1x10(exp 4)/cm was obtained; and (4) Variations of the cavity ring-down experiment showed that virtually no NCl(x) is formed via reaction.

Yang, T.T.; Gylys, V.T.; Hindy, R.N.

1994-02-14T23:59:59.000Z

465

Fiber scrambling for high-resolution spectrographs. II. A double fiber scrambler for Keck Observatory  

E-Print Network [OSTI]

We have designed a fiber scrambler as a prototype for the Keck HIRES spectrograph, using double scrambling to stabilize illumination of the spectrometer and a pupil slicer to increase spectral resolution to R = 70,000 with minimal slit losses. We find that the spectral line spread function (SLSF) for the double scrambler observations is 18 times more stable than the SLSF for comparable slit observations and 9 times more stable than the SLSF for a single fiber scrambler that we tested in 2010. For the double scrambler test data, we further reduced the radial velocity scatter from an average of 2.1 m/s to 1.5 m/s after adopting a median description of the stabilized SLSF in our Doppler model. This demonstrates that inaccuracies in modeling the SLSF contribute to the velocity RMS. Imperfect knowledge of the SLSF, rather than stellar jitter, sets the precision floor for chromospherically quiet stars analyzed with the iodine technique using Keck HIRES and other slit-fed spectrometers. It is increasingly common pra...

Spronck, Julien F P; Kaplan, Zachary; Jurgenson, Colby; Valenti, Jeff; Moriarty, John; Szymkowiak, Andrew E

2015-01-01T23:59:59.000Z

466

Radionuclide Retention in Concrete Wasteforms - FY13  

SciTech Connect (OSTI)

Assessing long-term performance of Category 3 waste cement grouts for radionuclide encasement requires knowledge of the radionuclide-cement interactions and mechanisms of retention (i.e., sorption or precipitation); the mechanism of contaminant release; the significance of contaminant release pathways; how wasteform performance is affected by the full range of environmental conditions within the disposal facility; the process of wasteform aging under conditions that are representative of processes occurring in response to changing environmental conditions within the disposal facility; the effect of wasteform aging on chemical, physical, and radiological properties; and the associated impact on contaminant release. This knowledge will enable accurate prediction of radionuclide fate when the wasteforms come in contact with groundwater. Data collected throughout the course of this work will be used to quantify the efficacy of concrete wasteforms, similar to those used in the disposal of low-level waste and mixed low-level waste, for the immobilization of key radionuclides (i.e., uranium, technetium, and iodine). Data collected will also be used to quantify the physical and chemical properties of the concrete affecting radionuclide retention.

Snyder, Michelle MV; Golovich, Elizabeth C.; Wellman, Dawn M.; Crum, Jarrod V.; Lapierre, Robert; Dage, Denomy C.; Parker, Kent E.; Cordova, Elsa A.

2013-10-15T23:59:59.000Z

467

Release of aged contaminants from weathered sediments: Effects of sorbate speciation on scaling of reactive transport  

SciTech Connect (OSTI)

Hanford sediments impacted by hyperalkaline high level radioactive waste have undergone incongruent silicate mineral weathering concurrent with contaminant uptake. In this project, we studied the impact of background pore water (BPW) on strontium, cesium and iodine desorption and transport in Hanford sediments that were experimentally weathered by contact with simulated hyperalkaline tank waste leachate (STWL) solutions. Using those lab-weathered Hanford sediments (HS) and model precipitates formed during nucleation from homogeneous STWL solutions (HN), we (i) provided thorough characterization of reaction products over a matrix of field-relevant gradients in contaminant concentration, partial pressure of carbon dioxide, and reaction time; (ii) improved molecular-scale understanding of how sorbate speciation controls contaminant desorption from weathered sediments upon removal of caustic sources; and (iii) developed a mechanistic, predictive model of meso- to field-scale contaminant reactive transport under these conditions. In this final report, we provide detailed descriptions of our results from this three-year study, completed in 2012 following a one-year no cost extension.

Chorover, Jon; Perdrial, Nico; Mueller, Karl; Strepka, Caleb; Oƒ ƒ ‚ ¢ƒ ‚ ‚ € ƒ ‚ ‚ ™ Day, Peggy; Rivera, Nelson; Um, Wooyong; Chang, Hyun-Shik; Steefel, Carl; Thompson, Aaron

2012-11-05T23:59:59.000Z

468

Ligands for SPECT and PET imaging of muscarinic-cholinergic receptors of the heart and brain  

SciTech Connect (OSTI)

Interest in the potential use of cerebral SPECT and PET imaging for determination of the density and activity of muscarinic-cholinergic receptors (mAChR) has been stimulated by the changes in these receptors which occur in many neurological diseases. In addition, the important involvement of mAChR in modulating negative inotropic cardiac activity suggests that such receptor ligands may have important applications in evaluation of changes which may occur in cardiac disease. In this paper, the properties of several key muscarinic receptor ligands being developed or which have been used for clinical SPECT and PET are discussed. In addition, the ORNL development of the new iodinated IQNP ligand based on QNB and the results of in vivo biodistribution studies in rats, in vitro competitive binding studies and ex vivo autoradiographic experiments are described. The use of radioiodinated IQNP may offer several advantages in comparison to IQNB because of its easy and high yield preparation and high brain uptake and the potential usefulness of the {open_quotes}partial{close_quotes} subtype selective IONP isomers. We also describe the development of new IQNP-type analogues which offer the opportunity for radiolabeling with positron-emitting radioisotopes (carbon-11, fluorine-18 and bromine-76) for potential use with PET.

Knapp, F.F. Jr.; McPherson, D.W.; Luo, H. [and others

1995-06-01T23:59:59.000Z

469

Correlation of hetorogeneous blood flow and uptake of a di-methyl-branched IODO fatty acid in the normal and ischemic dog heart  

SciTech Connect (OSTI)

Myocardial blood flow (MBF) is heterogeneously distributed in normal and ischemic myocardium (myoc). Methylated iodinated fatty acids, like 15-(p-I-125-iodophenyl)-3,3-dimethylpentadecanoic acid (DMIPPA) can be used to study fatty acid metabolism with SPECT. We studied the relationship between DMIPPA uptake and MBF. In 10 open-chest dogs, ischemica was induced in the LAD coronary artery by an extra-corporal bypass system. MBF was measured with Sc-46 labeled microspheres. Fourty min. after DMIPPA iv. (34{plus_minus}4 MBq), hearts were excised and left ventricles were cut into 120 pieces, weighed and radioactivities counted. MBF and DMIPPA uptake were determined by counting in normal and ischemic myoc. Heterogeneity is expressed as the coefficient of variation (CV) and agreement as the CV of the DMIPPA uptake to MBF ratio. A control study, normal flow in LAD, in 4 dogs revealed no differences in MBF or DMIPPA uptake between the cannulated versus native perfused myoc. We conclude the DMIPPA detects ischemia, in which it shows a different relation with MBF compared to normal myoc. DMIPPA is less heterogeneously distributed than MBF and agreement between MFB and DMIPPA uptake decreases during ischemia.

Sloof, G.W.; Visser, F.C.; Comans, E.F.I. [Free Univ. Hospital, Amsterdam (Netherlands)]|[Oak Ridge National Lab., TN (United States)] [and others

1995-05-01T23:59:59.000Z

470

Novel Chemical Strategies for Labeling Small Molecule Ligands for Androgen, Progestin, and Peroxisome Proliferator-Activated Receptors for Imaging Prostate and Breast Cancer and the Heart  

SciTech Connect (OSTI)

Summary of Progress The specific aims of this project can be summarized as follows: Aim 1: Prepare and evaluate radiolabeled ligands for the peroxisome proliferator-activated receptor ? (PPAR?), a new nuclear hormone receptor target for tumor imaging and hormone therapy. Aim 2: Prepare steroids labeled with a cyclopentadienyl tricarbonyl technetium or rhenium unit. Aim 3: Prepare and evaluate other organometallic systems of novel design as ligand mimics and halogenated ligands for nuclear hormone receptor-based tumor imaging. As is described in detail below, we made excellent progress on all three of these aims; the highlights of our progress are the following: we have prepared the first fluorine-18 labeled analogs of ligands for the PPAR? receptor and used these in tissue distribution studies in rats we have developed three new methods for the synthesis of cyclopentadienyltricarbonyl rhenium and technetium (CpRe(CO)3 and CpTc(CO)3) systems and we have adapted these to the synthesis of steroids labeled with these metals, as well as ligands for other receptor systems we have prepared a number of fluorine-18 labeled steroidal and non-steroidal androgens and measured their tissue distribution in rats we have prepared iodine and bromine-labeled progestins with high progesterone receptor binding affinity we have prepared inorganic metal tricarbonyl complexes and steroid receptor ligands in which the metal tricarbonyl unit is an integral part off the ligand core.

Katzenellenbogen, John, A.

2007-04-19T23:59:59.000Z

471

H-Area seepage basins groundwater monitoring report. Volume 1, First and second quarters 1995  

SciTech Connect (OSTI)

Groundwater at the H-Area Seepage Basins (HASB) is monitored in compliance with the September 30, 1992, modification of South Carolina Hazardous Waste Permit SCl-890-008-989. The monitoring wells network is composed of 130 HSB wells that monitor the three separate hydrostratigraphic units that make up the uppermost aquifer beneath the HASB. A detailed description of the uppermost aquifer is included in the Resource Conservation and Recovery Act Part B post-closure care permit application for the H-Area Hazardous Waste Management Facility submitted to the South Carolina Department of Health and Environmental Control (SCDHEC) in December 1990. Data from 16 HSL wells are included in this report only to provide additional information for the HASB. Monitoring results are compared to the SCDHEC Groundwater Protection Standard (GWPS), established in Appendix IIID-A of the permit. Historically as well as currently, nitrate, nonvolatile beta, and tritium have been among the primary constituents to exceed standards. Other radionuclides and hazardous constituents also exceeded the GWPS in the groundwater at the HASB (notably aluminum, iodine-129, strontium-90, and zinc) during the first half of 1995. Elevated constituents were found primarily in Aquifer Zone IIB and in the upper portion of Aquifer Zone IIB. However, constituents exceeding standards also occurred in several wells screened in the lower portion of Aquifer Zone IIB, and Aquifer Unit IIA.

NONE

1995-09-01T23:59:59.000Z

472

H-Area Seepage Basins groundwater monitoring report. Volume 1, First and second quarters 1993  

SciTech Connect (OSTI)

During the first half of 1993, the groundwater at the H-Area Seepage Basins (HASB) was monitored in compliance with the September 30, 1992, modification of South Carolina Hazardous Waste Permit. Samples were collected from 130 wells that monitor the three separate hydrostratigraphic units that make up the uppermost aquifer beneath the HASB. A detailed description of the uppermost aquifer is included in the Resource Conservation and Recovery Act Part B Post-Closure Care Permit Application for the H-Area Hazardous Waste Management Facility submitted to the South Carolina Department of Health and Environmental Control (SCDHEC) in December 1990. HASB`s Groundwater Protection Standard is the standard for comparison. Historically, as well as currently, gross alpha, nitrate, nonvolatile beta, and tritium have been among the primary constituents to exceed standards. Other radionuclides and hazardous constituents also exceeded the GWPS in the groundwater at the HASB, notably aluminum, iodine-129, mercury, nickel-63, strontium-89, strontium-90, technetium-99, and zinc during the first half of 1993. Elevated constituents are found primarily in Aquifer Zone IIB{sub 2} (Water Table) and in the upper portion of Aquifer Zone IIB{sub 1}. However, constituents exceeding standards also occur in several wells screened in the lower portion of Aquifer Zone IIB{sub 1} and Aquifer Unit IIA.

Not Available

1993-09-01T23:59:59.000Z

473

Hanford Site Groundwater Monitoring for Fiscal Year 2000  

SciTech Connect (OSTI)

This report presents the results of groundwater and vadose zone monitoring and remediation for fiscal year 2000 on the U.S. Department of Energy's Hanford Site, Washington. The most extensive contaminant plumes are tritium, iodine-129, and nitrate, which all had multiple sources and are very mobile in groundwater. Carbon tetrachloride and associated organic constituents form a relatively large plume beneath the central part of the Site. Hexavalent chromium is present in smaller plumes beneath the reactor areas along the river and beneath the central part of the site. Strontium-90 exceeds standards beneath each of the reactor areas, and technetium-99 and uranium are present in the 200 Areas. RCRA groundwater monitoring continued during fiscal year 2000. Vadose zone monitoring, characterization, remediation, and several technical demonstrations were conducted in fiscal year 2000. Soil gas monitoring at the 618-11 burial ground provided a preliminary indication of the location of tritium in the vadose zone and in groundwater. Groundwater modeling efforts focused on 1) identifying and characterizing major uncertainties in the current conceptual model and 2) performing a transient inverse calibration of the existing site-wide model. Specific model applications were conducted in support of the Hanford Site carbon tetrachloride Innovative Treatment Remediation Technology; to support the performance assessment of the Immobilized Low-Activity Waste Disposal Facility; and in development of the System Assessment Capability, which is intended to predict cumulative site-wide effects from all significant Hanford Site contaminants.

Hartman, Mary J.; Morasch, Launa F.; Webber, William D.

2001-03-01T23:59:59.000Z

474

Quantitative structureactivity relationships for toxicity and genotoxicity of halogenated aliphatic compounds: Wing spot test of Drosophila melanogaster  

Science Journals Connector (OSTI)

Halogenated aliphatic compounds were evaluated for toxic and genotoxic effects in the somatic mutation and recombination test employing Drosophila melanogaster. The tested chemicals included chlorinated, brominated and iodinated; mono-, di- and tri-substituted; saturated and unsaturated alkanes: 1,2-dibromoethane, 1-bromo-2-chloroethane, 1-iodopropane, 2,3-dichloropropene, 3-bromo-1-propene, epibromohydrin, 2-iodobutane, 3-chloro-2-methylpropene, 1,2,3-trichloropropane, 1,2-dichloroethane, 1,2-dichlorobutane, 1-chloro-2-methylpropane, 1,3-dichloropropane, 1,2-dichloropropane, 2-chloroethymethylether, 1-bromo-2-methylpropane and 1-chloropentane. N-methyl-N-nitrosourea served as the positive and distilled water as the negative control. The set of chemicals for the toxicological testing was selected by the use of statistical experiment design. Group of unsaturated aliphatic hydrocarbons were generally more toxic than saturated analogues. The genotoxic effect was observed with 14 compounds in the wing spot test, while 3 substances did not show any genotoxicity by using the wing spot test at 50% lethal concentration. The highest number of wing spots was observed in genotoxicity assay with 1-bromo-2-chloroethane, 1,2-dichloroethane, 1,2-dibromoethane and 1-iodopropane. Nucleophilic superdelocalizability calculated by quantum mechanics appears to be a good parameter for prediction of both toxicity and genotoxicity effects of halogenated aliphatic compounds.

Karel Chroust; Martina Pavlov; Zbyn?k Prokop; Jan Mendel; Kate?ina Bokov; Zden?k Kubt; Veronika Zaj??kov; Ji?? Damborsk

2007-01-01T23:59:59.000Z

475

Dual-etalon, cavity-ring-down, frequency comb spectroscopy.  

SciTech Connect (OSTI)

The 'dual etalon frequency comb spectrometer' is a novel low cost spectometer with limited moving parts. A broad band light source (pulsed laser, LED, lamp ...) is split into two beam paths. One travels through an etalon and a sample gas, while the second arm is just an etalon cavity, and the two beams are recombined onto a single detector. If the free spectral ranges (FSR) of the two cavities are not identical, the intensity pattern at the detector with consist of a series of heterodyne frequencies. Each mode out of the sample arm etalon with have a unique frequency in RF (radio-frequency) range, where modern electronics can easily record the signals. By monitoring these RF beat frequencies we can then determine when an optical frequencies is absorbed. The resolution is set by the FSR of the cavity, typically 10 MHz, with a bandwidth up to 100s of cm{sup -1}. In this report, the new spectrometer is described in detail and demonstration experiments on Iodine absorption are carried out. Further we discuss powerful potential next generation steps to developing this into a point sensor for monitoring combustion by-products, environmental pollutants, and warfare agents.

Strecker, Kevin E.; Chandler, David W.

2010-10-01T23:59:59.000Z

476

Amplifiers involving two-photon energy-extraction schemes  

Science Journals Connector (OSTI)

Amplifiers based on two-photon decay channels of inverted metastable species are examined from a rate-equation and practical-feasibility viewpoint. Approximate analytical solutions, within the rate-equation approximation, predict that resonant parametric generation coupled with anti-Stokes-stimulated Raman scattering (ASRS) is a strong competitor to straight two-photon emission. Expressions for initial growth rates indicate that large linear chromatic dispersion, proper linear absorptions, and resonant enhancements can initially favor two-photon emission, but that ASRS will ultimately dominate in most practical situations if inversion depletion does not occur early. For an amplifier based on degenerate two-photon processes, this situation has led to the proposal of running the system as an odd-harmonic generator, first extracting energy via two-photon emission followed by greater-than-100% conversion to the third, fifth, seventh, etc., harmonics. This type of amplifier response has important potential applications for laser-induced thermonuclear fusion as well as for the production of coherent vacuum-uv soft-x-ray systems. An examination of practical constraints provides further analytical relationships between various physical properties of prospective metastable species. Combining these results, several two-photon schemes are pointed out. Based on current technology, atomic iodine, which is inverted to the P122 state, appears to be the best medium for experiments, but other materials, such as atomic oxygen, show greater promise if absolute population inversions of high-density material are created at high efficiency.

R. L. Carman

1975-09-01T23:59:59.000Z

477

Characterization of supersonic mixing in a nonreacting Mach 2 combustor  

SciTech Connect (OSTI)

Planar measurements of the injection mole fraction distribution and the velocity field within a nonreacting model SCRAMJET combustor have been made using laser-induced iodine fluorescence. The combustor geometry investigated in this work is staged transverse injection of air into a Mach 2 freestream. A complete three-dimensional survey of the injectant mole fraction distribution has been generated and a single planar velocity measurement has been completed. The measurements reveal the dramatic effect of streamwise vortices on the mixing of the injectant in the near field of the injectors, as well as the rapid mixing generated by staging two field injectors. Analysis of the downstream decay of the maximum injectant mole fraction in this and other nonreacting combustor geometries indicates that the relative rate of injectant mixing well downstream of the injectors is independent of combustor geometry, combustor Mach number, and injectant molecular weight. Mixing within this region of the combustor is dominated by turbulent diffusion within the injectant plume. The transition of the dominant mixing mechanism, from vortex-driven mixing in the near field to turbulent diffusion in the far field, was found to occur in the region between 10 and 20 jet diameters downstream of the injectors. 22 refs.

Hollo, S.D.; Mcdaniel, J.C.; Hartfield, R.J., JR. (Virginia, University, Charlottesville (United States))

1992-01-01T23:59:59.000Z

478

Extensive separations (CLEAN) processing strategy compared to TRUEX strategy and sludge wash ion exchange  

SciTech Connect (OSTI)

Numerous pretreatment flowsheets have been proposed for processing the radioactive wastes in Hanford`s 177 underground storage tanks. The CLEAN Option is examined along with two other flowsheet alternatives to quantify the trade-off of greater capital equipment and operating costs for aggressive separations with the reduced waste disposal costs and decreased environmental/health risks. The effect on the volume of HLW glass product and radiotoxicity of the LLW glass or grout product is predicted with current assumptions about waste characteristics and separations processes using a mass balance model. The prediction is made on three principal processing options: washing of tank wastes with removal of cesium and technetium from the supernatant, with washed solids routed directly to the glass (referred to as the Sludge Wash C processing strategy); the previous steps plus dissolution of the solids and removal of transuranic (TRU) elements, uranium, and strontium using solvent extraction processes (referred to as the Transuranic Extraction Option C (TRUEX-C) processing strategy); and an aggressive yet feasible processing strategy for separating the waste components to meet several main goals or objectives (referred to as the CLEAN Option processing strategy), such as the LLW is required to meet the US Nuclear Regulatory Commission Class A limits; concentrations of technetium, iodine, and uranium are reduced as low as reasonably achievable; and HLW will be contained within 1,000 borosilicate glass canisters that meet current Hanford Waste Vitrification Plant glass specifications.

Knutson, B.J.; Jansen, G.; Zimmerman, B.D.; Seeman, S.E. [Westinghouse Hanford Co., Richland, WA (United States); Lauerhass, L.; Hoza, M. [Pacific Northwest Lab., Richland, WA (United States)

1994-08-01T23:59:59.000Z

479

Atmospheric radionuclides from the Fukushima Dai-ichi nuclear reactor accident observed in Vietnam  

Science Journals Connector (OSTI)

Radionuclides from the reactor accident at the Fukushima Dai-ichi Nuclear Power Plant were observed in the surface air at stations in Hanoi, Dalat, and Ho Chi Minh City (HCMC) in Vietnam, about 4500km southwest of Japan, during the period from March 27 to April 22, 2011. The maximum activity concentrations in the air measured at those three sites were 193, 33, and 37?Bqm?3 for 131I, 134Cs, and 137Cs, respectively. Peaks of radionuclide concentrations in the air corresponded to arrival of the air mass from Fukushima to Vietnam after traveling for 8d over the Pacific Ocean. Cesium-134 was detected with the 134Cs/137Cs activity ratio of about 0.85 in line with observations made elsewhere. The 131I/137Cs activity ratio was observed to decrease exponentially with time as expected from radioactive decay. The ratio at Dalat, where is 1500m high, was higher than those at Hanoi and HCMC in low lands, indicating the relative enrichment of the iodine in comparison to cesium at high altitudes. The time-integrated surface air concentrations of the Fukushima-derived radionuclides in the Southeast Asia showed exponential decrease with distance from Fukushima.

N.Q. Long; Y. Truong; P.D. Hien; N.T. Binh; L.N. Sieu; T.V. Giap; N.T. Phan

2012-01-01T23:59:59.000Z

480

On the use of 127Xe standards for the quality control of CTBTO noble gas stations and support laboratories  

Science Journals Connector (OSTI)

Abstract 127Xe has a longer half-life than 131mXe, it can be easily purely produced and it is present in the environment at very low level. For these reasons, 127Xe is supposed to be a convenient quality control radionuclide for remote noble gas stations of the International Monitoring System (IMS) network. As CEA/DAM has recently developed two new photon/electron setups for low-level detection of 131mXe, 133mXe, 133Xe and 135Xe, we took the opportunity to test these setups for the measurement of a 127Xe standard. The results and a detailed description of these measurements are presented in this paper. They illustrate the complexity of 127Xe decay, emitting simultaneously several ?, X-rays, conversion electrons and Auger electrons; this results in highly summated coincidence spectra. The measurements performed provide precise electron energy calibration of the setups. The count rate of electrons in coincidence with iodine K? X-rays was found to be surprisingly low, leading to the study of electron-gated photon spectrum. Finally, a comparison of three photon/electron coincidence spectra obtained with three different setups is given. The use of 127Xe as