National Library of Energy BETA

Sample records for intermediate base lamps

  1. Candelabra and Intermediate Base Lamps Enforcement Policy Statement |

    Energy Savers [EERE]

    Department of Energy Candelabra and Intermediate Base Lamps Enforcement Policy Statement Candelabra and Intermediate Base Lamps Enforcement Policy Statement July 1, 2011 - 5:00pm Addthis The Department issued guidance today advising manufacturers, importers and private labelers that DOE will not enforce the energy conservation standards and compliance certification requirements for candelabra and intermediate base lamps until January 1, 2012. Addthis Related Articles DOE Opens Investigation

  2. Electric lamp, base for use therewith and method of assembling same

    DOE Patents [OSTI]

    Hough, Harold L. (Beverly, MA); English, George J. (Reading, MA); Chakrabarti, Kirti B. (Danvers, MA)

    1989-02-14

    An electric lamp including a reflector, at least one conductive ferrule located within a surface of the reflector and a lead-in conductor electrically connected to the ferrule and extending within the reflector. The lamp includes a base having an insulative (e.g., ceramic) cap located substantially about the ferrule, barrier means (e.g., ceramic fiber) located within the cap to define an open chamber substantially about the ferrule, an electrical conductor (e.g., wire) extending within the cap and electrically connected (e.g., silver soldered) to the ferrule, and sealing means (e.g., high temperature cement) located within the cap to provide a seal therefore. The barrier means serves to separate the sealing means from the open chamber about the ferrule such that the heat generated by the ferrule can be vented through spaced apertures located within the cap's side wall. A method of assembling a base on an electric lamp is also provided.

  3. Guidance Concerning Enforcement of EISA 2007 Standards Candelabra Base and

    Office of Environmental Management (EM)

    Intermediate Base Lamps | Department of Energy Concerning Enforcement of EISA 2007 Standards Candelabra Base and Intermediate Base Lamps Guidance Concerning Enforcement of EISA 2007 Standards Candelabra Base and Intermediate Base Lamps The Energy Independence and Security Act of 2007 (EISA 2007) imposed energy conservation standards for candelabra and intermediate base lamps, and those provisions became effective with the statute. PDF icon Microsoft Word - Guidance Concerning Enforcement of

  4. Lamp Divisions

    Office of Legacy Management (LM)

    --- /A;; i :' r%i;in~house ilEc;' i:Z3:~cra:ion Lamp Divisions , _.. (I +i. 0 :,,,rg. . I . . -= i?e p/q! qe)-' &se pw E.rcale?l iev, Je!sey 07m March 20, 1 gs? ::r . J. A. Jones I ti. 5. Muclear Regulatory Commission .> = ..- haterials Licensing Branch -s - ,.I, - - Division of Fuel Cycle and hateri al Safety LY. , $2 - _ . ' -' . 3 _- - Yeshington, C. C. 2@555 - :_ :--, =-- -- .-?J -.: y...., : :- 7 Dear Mr. Jones : y-- --, ? . *I 2=15 2 r; X -P The following is our final report of the

  5. Aperture lamp

    DOE Patents [OSTI]

    MacLennan, Donald A.; Turner, Brian P.

    2003-01-01

    A discharge lamp includes means for containing a light emitting fill, the fill being capable of absorbing light at one wavelength and re-emitting the light at a different wavelength, the light emitted from the fill having a first spectral power distribution in the absence of reflection of light back into the fill; means for exciting the fill to cause the fill to emit light; and means for reflecting some of the light emitted by the fill back into the fill while allowing some light to exit, the exiting light having a second spectral power distribution with proportionately more light in the visible region as compared to the first spectral power distribution, wherein the light re-emitted by the fill is shifted in wavelength with respect to the absorbed light and the magnitude of the shift is in relation to an effective optical path length. Another discharge lamp includes an envelope; a fill which emits light when excited disposed in the envelope; a source of excitation power coupled to the fill to excite the fill and cause the fill to emit light; and a reflective ceramic structure disposed around the envelope and defining an light emitting opening, wherein the structure comprises a sintered body built up directly on the envelope and made from a combination of alumina and silica.

  6. LED lamp

    SciTech Connect (OSTI)

    Galvez, Miguel; Grossman, Kenneth; Betts, David

    2013-11-12

    There is herein described a lamp for providing white light comprising a plurality of light sources positioned on a substrate. Each of said light sources comprises a blue light emitting diode (LED) and a dome that substantially covers said LED. A first portion of said blue light from said LEDs is transmitted through said domes and a second portion of said blue light is converted into a red light by a first phosphor contained in said domes. A cover is disposed over all of said light sources that transmits at least a portion of said red and blue light emitted by said light sources. The cover contains a second phosphor that emits a yellow light in response to said blue light. The red, blue and yellow light combining to form the white light and the white light having a color rendering index (CRI) of at least about 80.

  7. Lamp with a truncated reflector cup

    DOE Patents [OSTI]

    Li, Ming; Allen, Steven C.; Bazydola, Sarah; Ghiu, Camil-Daniel

    2013-10-15

    A lamp assembly, and method for making same. The lamp assembly includes first and second truncated reflector cups. The lamp assembly also includes at least one base plate disposed between the first and second truncated reflector cups, and a light engine disposed on a top surface of the at least one base plate. The light engine is configured to emit light to be reflected by one of the first and second truncated reflector cups.

  8. LED MR16 Lamps

    SciTech Connect (OSTI)

    2012-07-01

    Solid-state lighting program technology fact sheet that describes the performance of LED MR16 lamps and discusses electronic compatibility concerns.

  9. Turning on LAMP

    ScienceCinema (OSTI)

    Bostedt, Christoph

    2014-07-16

    Christoph Bostedt, a senior staff scientist at SLAC's Linac Coherent Light Source X-ray laser, provides a sneak peek of a powerful new instrument, called LAMP, that is now available for experiments that probe the atomic and molecular realm. LAMP replaces and updates the first instrument at LCLS, dubbed CAMP, which will be installed at an X-ray laser in Germany.

  10. Jacketed lamp bulb envelope

    DOE Patents [OSTI]

    MacLennan, Donald A.; Turner, Brian P.; Gitsevich, Aleksandr; Bass, Gary K.; Dolan, James T.; Kipling, Kent; Kirkpatrick, Douglas A.; Leng, Yongzhang; Levin, Izrail; Roy, Robert J.; Shanks, Bruce; Smith, Malcolm; Trimble, William C.; Tsai, Peter

    2001-01-01

    A jacketed lamp bulb envelope includes a ceramic cup having an open end and a partially closed end, the partially closed end defining an aperture, a lamp bulb positioned inside the ceramic cup abutting the aperture, and a reflective ceramic material at least partially covering a portion of the bulb not abutting the aperture. The reflective ceramic material may substantially fill an interior volume of the ceramic cup not occupied by the bulb. The ceramic cup may include a structural feature for aiding in alignment of the jacketed lamp bulb envelope in a lamp. The ceramic cup may include an external flange about a periphery thereof. One example of a jacketed lamp bulb envelope includes a ceramic cup having an open end and a closed end, a ceramic washer covering the open end of the ceramic cup, the washer defining an aperture therethrough, a lamp bulb positioned inside the ceramic cup abutting the aperture, and a reflective ceramic material filling an interior volume of the ceramic cup not occupied by the bulb. A method of packing a jacketed lamp bulb envelope of the type comprising a ceramic cup with a lamp bulb disposed therein includes the steps of filling the ceramic cup with a flowable slurry of reflective material, and applying centrifugal force to the cup to pack the reflective material therein.

  11. Fluorescent Tube Lamps

    Broader source: Energy.gov [DOE]

    FEMP temporarily suspended its energy efficiency requirements for fluorescent tube lamps as it evaluates the market impact of the pending 2012 minimum efficiency standards for fluorescent lamps. The program will issue updated energy efficiency requirements when the market distribution of this product category stabilizes and when doing so has the potential to result in significant Federal energy savings.

  12. High-Heat Flux Testing of Irradiated Tungsten based Materials for Fusion Applications using Infrared Plasma Arc Lamps

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Sabau, Adrian S; Ohriner, Evan Keith; Kiggans, Jr, James O; Schaich, Charles Ross; Ueda, Yoshio; Harper, David C; Katoh, Yutai; Snead, Lance Lewis; Byun, Thak Sang

    2014-01-01

    Testing of advanced materials and component mock-ups under prototypical fusion high-heat flux conditions, while historically a mainstay of fusion research has proved challenging, especially for irradiated materials. A new high-heat flux testing facility based on water-wall Plasma Arc Lamps (PALs) is now being used for materials and small component testing. Two PAL systems, utilizing a 12,000 C plasma arc contained in a quartz tube cooled by a spiral water flow over the inside tube surface, are currently in use. The first PAL system provides a maximum incident heat flux of 4.2 MW/m2 over an area of 9x12 cm2. The secondmore » PAL available at ORNL provides a maximum incident heat flux of 27 MW/m2 over an area of 1x10 cm2. The absorbed heat fluxes into a tungsten target for the two PALs are approximately 1.97 and 12.7 MW/m2, respectively. This paper will present the overall design of the new PAL facilities as well as the design and implementation of the Irradiated Material Target Station (IMTS). The IMTS is primarily designed for testing the effects of heat flux or thermal cycling on material coupons of interested, such as those for plasma facing components. Moreover, IMTS designs are underway to extend the testing of small mock-ups for assessing the combined heating and thermomechanical effects of cooled, irradiated components. For the testing of material coupons , the specimens are placed in a shallow recess within the molybdenum holder that is attached to a water-cooled copper alloy rod. As the measurement of the specimen temperature for PAL is historically challenging since traditional approaches of temperature measurement cannot be employed due to the infrared heating and proximity of the PAL reflector to the specimen that does not allow a direct line of site, experiments for temperature calibration are presented. Finally, results for the high-heat flux testing of tungsten-based materials using the PAL are presented. As a demonstration of the system, results will be shown of thermal fatigue and high-heat flux testing of tungsten coupon specimens that were neutron irradiated in the HFIR reactor to neutron dose consistent to ITER lifetime.« less

  13. High-Heat Flux Testing of Irradiated Tungsten based Materials for Fusion Applications using Infrared Plasma Arc Lamps

    SciTech Connect (OSTI)

    Sabau, Adrian S; Ohriner, Evan Keith; Kiggans Jr, James O; Schaich, Charles Ross; Ueda, Yoshio; Harper, David C; Katoh, Yutai; Snead, Lance Lewis; Byun, Thak Sang

    2014-01-01

    Testing of advanced materials and component mock-ups under prototypical fusion high-heat flux conditions, while historically a mainstay of fusion research has proved challenging, especially for irradiated materials. A new high-heat flux testing facility based on water-wall Plasma Arc Lamps (PALs) is now being used for materials and small component testing. Two PAL systems, utilizing a 12,000 C plasma arc contained in a quartz tube cooled by a spiral water flow over the inside tube surface, are currently in use. The first PAL system provides a maximum incident heat flux of 4.2 MW/m2 over an area of 9x12 cm2. The second PAL available at ORNL provides a maximum incident heat flux of 27 MW/m2 over an area of 1x10 cm2. The absorbed heat fluxes into a tungsten target for the two PALs are approximately 1.97 and 12.7 MW/m2, respectively. This paper will present the overall design of the new PAL facilities as well as the design and implementation of the Irradiated Material Target Station (IMTS). The IMTS is primarily designed for testing the effects of heat flux or thermal cycling on material coupons of interested, such as those for plasma facing components. Moreover, IMTS designs are underway to extend the testing of small mock-ups for assessing the combined heating and thermomechanical effects of cooled, irradiated components. For the testing of material coupons , the specimens are placed in a shallow recess within the molybdenum holder that is attached to a water-cooled copper alloy rod. As the measurement of the specimen temperature for PAL is historically challenging since traditional approaches of temperature measurement cannot be employed due to the infrared heating and proximity of the PAL reflector to the specimen that does not allow a direct line of site, experiments for temperature calibration are presented. Finally, results for the high-heat flux testing of tungsten-based materials using the PAL are presented. As a demonstration of the system, results will be shown of thermal fatigue and high-heat flux testing of tungsten coupon specimens that were neutron irradiated in the HFIR reactor to neutron dose consistent to ITER lifetime.

  14. Compact fluorescent lamp using horizontal and vertical insulating septums and convective venting geometry

    DOE Patents [OSTI]

    Siminovitch, Michael (El Sobrante, CA)

    1998-01-01

    A novel design for a compact fluorescent lamp, including a lamp geometry which will increase light output and efficacy of the lamp in a base down operating position by providing horizontal and vertical insulating septums positioned in the ballast compartment of the lamp to provide a cooler coldspot. Selective convective venting provides additional cooling of the ballast compartment.

  15. Compact fluorescent lamp using horizontal and vertical insulating septums and convective venting geometry

    DOE Patents [OSTI]

    Siminovitch, M.

    1998-02-10

    A novel design is described for a compact fluorescent lamp, including a lamp geometry which will increase light output and efficacy of the lamp in a base down operating position by providing horizontal and vertical insulating septums positioned in the ballast compartment of the lamp to provide a cooler coldspot. Selective convective venting provides additional cooling of the ballast compartment. 9 figs.

  16. LED Directional Lamps

    SciTech Connect (OSTI)

    2012-11-01

    Solid-state lighting program technology fact sheet that provides an overview of the current performance of LED PAR-, BR-, R-, and AR-shaped lamps, which were all investigated by CALiPER in 2012.

  17. Magnetic fluorescent lamp

    DOE Patents [OSTI]

    Berman, S.M.; Richardson R.W.

    1983-12-29

    The radiant emission of a mercury-argon discharge in a fluorescent lamp assembly is enhanced by providing means for establishing a magnetic field with lines of force along the path of electron flow through the bulb of the lamp assembly, to provide Zeeman splitting of the ultraviolet spectral line. Optimum results are obtained when the magnetic field strength causes a Zeeman splitting of approximately 1.7 times the thermal line width.

  18. Snapshot: MR16 Lamps | Department of Energy

    Energy Savers [EERE]

    Snapshot: MR16 Lamps Snapshot: MR16 Lamps PDF icon Snapshot: MR16 Lamps (8 pages, January 2016) More Documents & Publications FEBRUARY 2016 POSTINGS LED MR16 Lamps LED Directional

  19. LED Directional Lamps | Department of Energy

    Energy Savers [EERE]

    Directional Lamps LED Directional Lamps BTP EERE Solid-State Lighting Program PDF icon led_directional_lamps.pdf More Documents & Publications Energy Savings Estimates of Light Emitting Diodes Recessed LED Downlights General Service LED Lamps

  20. LED MR16 Lamps | Department of Energy

    Energy Savers [EERE]

    LED MR16 Lamps LED MR16 Lamps A U.S. DOE Solid-State Lighting Program technology fact sheet on LED MR16 lamps. PDF icon led_mr16-lamps.pdf More Documents & Publications Report 22.1: Photoelectric Performance of LED MR16 Lamps Caliper Retail Lamps Study 3.1: Dimming, Flicker, and Power Quality Characteristics of LED A Lamps Snapshot: MR16 Lamps

  1. Evaluation of Cooling Conditions for a High Heat Flux Testing Facility Based on Plasma-Arc Lamps

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Charry, Carlos H.; Abdel-khalik, Said I.; Yoda, Minami; Sabau, Adrian S.; Snead, Lance Lewis

    2015-07-31

    The new Irradiated Material Target Station (IMTS) facility for fusion materials at Oak Ridge National Laboratory (ORNL) uses an infrared plasma-arc lamp (PAL) to deliver incident heat fluxes as high as 27 MW/m2. The facility is being used to test irradiated plasma-facing component materials as part of the joint US-Japan PHENIX program. The irradiated samples are to be mounted on molybdenum sample holders attached to a water-cooled copper rod. Depending on the size and geometry of samples, several sample holders and copper rod configurations have been fabricated and tested. As a part of the effort to design sample holders compatiblemore » with the high heat flux (HHF) testing to be conducted at the IMTS facility, numerical simulations have been performed for two different water-cooled sample holder designs using the ANSYS FLUENT 14.0 commercial computational fluid dynamics (CFD) software package. The primary objective of this work is to evaluate the cooling capability of different sample holder designs, i.e. to estimate their maximum allowable incident heat flux values. 2D axisymmetric numerical simulations are performed using the realizable k-ε turbulence model and the RPI nucleate boiling model within ANSYS FLUENT 14.0. The results of the numerical model were compared against the experimental data for two sample holder designs tested in the IMTS facility. The model has been used to parametrically evaluate the effect of various operational parameters on the predicted temperature distributions. The results were used to identify the limiting parameter for safe operation of the two sample holders and the associated peak heat flux limits. The results of this investigation will help guide the development of new sample holder designs.« less

  2. Evaluation of Cooling Conditions for a High Heat Flux Testing Facility Based on Plasma-Arc Lamps

    SciTech Connect (OSTI)

    Charry, Carlos H.; Abdel-khalik, Said I.; Yoda, Minami; Sabau, Adrian S.; Snead, Lance Lewis

    2015-07-31

    The new Irradiated Material Target Station (IMTS) facility for fusion materials at Oak Ridge National Laboratory (ORNL) uses an infrared plasma-arc lamp (PAL) to deliver incident heat fluxes as high as 27 MW/m2. The facility is being used to test irradiated plasma-facing component materials as part of the joint US-Japan PHENIX program. The irradiated samples are to be mounted on molybdenum sample holders attached to a water-cooled copper rod. Depending on the size and geometry of samples, several sample holders and copper rod configurations have been fabricated and tested. As a part of the effort to design sample holders compatible with the high heat flux (HHF) testing to be conducted at the IMTS facility, numerical simulations have been performed for two different water-cooled sample holder designs using the ANSYS FLUENT 14.0 commercial computational fluid dynamics (CFD) software package. The primary objective of this work is to evaluate the cooling capability of different sample holder designs, i.e. to estimate their maximum allowable incident heat flux values. 2D axisymmetric numerical simulations are performed using the realizable k-? turbulence model and the RPI nucleate boiling model within ANSYS FLUENT 14.0. The results of the numerical model were compared against the experimental data for two sample holder designs tested in the IMTS facility. The model has been used to parametrically evaluate the effect of various operational parameters on the predicted temperature distributions. The results were used to identify the limiting parameter for safe operation of the two sample holders and the associated peak heat flux limits. The results of this investigation will help guide the development of new sample holder designs.

  3. General Service LED Lamps | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    General Service LED Lamps General Service LED Lamps A U.S. DOE SSL technology fact sheet that compares general service LED light bulbs with incandescent and CFL bulbs. PDF icon led_general-service-lamps.pdf More Documents & Publications LED Directional Lamps Emerging Lighting Technology LED T8 Replacement Lamps

  4. High brightness microwave lamp

    DOE Patents [OSTI]

    Kirkpatrick, Douglas A.; Dolan, James T.; MacLennan, Donald A.; Turner, Brian P.; Simpson, James E.

    2003-09-09

    An electrodeless microwave discharge lamp includes a source of microwave energy, a microwave cavity, a structure configured to transmit the microwave energy from the source to the microwave cavity, a bulb disposed within the microwave cavity, the bulb including a discharge forming fill which emits light when excited by the microwave energy, and a reflector disposed within the microwave cavity, wherein the reflector defines a reflective cavity which encompasses the bulb within its volume and has an inside surface area which is sufficiently less than an inside surface area of the microwave cavity. A portion of the reflector may define a light emitting aperture which extends from a position closely spaced to the bulb to a light transmissive end of the microwave cavity. Preferably, at least a portion of the reflector is spaced from a wall of the microwave cavity. The lamp may be substantially sealed from environmental contamination. The cavity may include a dielectric material is a sufficient amount to require a reduction in the size of the cavity to support the desired resonant mode.

  5. Inductive tuners for microwave driven discharge lamps

    DOE Patents [OSTI]

    Simpson, James E.

    1999-01-01

    An RF powered electrodeless lamp utilizing an inductive tuner in the waveguide which couples the RF power to the lamp cavity, for reducing reflected RF power and causing the lamp to operate efficiently.

  6. LED MR16 Lamps | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    report provides detailed analysis of LED MR16 lamp performance, covering basic performance ... Application Summary Report 22: LED MR16 Lamps An initial sample of 27 LED MR16 lamps and 8 ...

  7. Highly Efficient Small Form Factor LED Retrofit Lamp

    SciTech Connect (OSTI)

    Steven Allen; Fred Palmer; Ming Li

    2011-09-11

    This report summarizes work to develop a high efficiency LED-based MR16 lamp downlight at OSRAM SYLVANIA under US Department of Energy contract DE-EE0000611. A new multichip LED package, electronic driver, and reflector optic were developed for these lamps. At steady-state, the lamp luminous flux was 409 lumens (lm), luminous efficacy of 87 lumens per watt (LPW), CRI (Ra) of 87, and R9 of 85 at a correlated color temperature (CCT) of 3285K. The LED alone achieved 120 lumens per watt efficacy and 600 lumen flux output at 25 C. The driver had 90% electrical conversion efficiency while maintaining excellent power quality with power factor >0.90 at a power of only 5 watts. Compared to similar existing MR16 lamps using LED sources, these lamps had much higher efficacy and color quality. The objective of this work was to demonstrate a LED-based MR16 retrofit lamp for replacement of 35W halogen MR16 lamps having (1) luminous flux of 500 lumens, (2) luminous efficacy of 100 lumens per watt, (3) beam angle less than 40{sup o} and center beam candlepower of at least 1000 candelas, and (4) excellent color quality.

  8. Application Summary Report 22: LED MR16 Lamps

    SciTech Connect (OSTI)

    Royer, Michael P.

    2014-07-23

    This report analyzes the independently tested photometric performance of 27 LED MR16 lamps. It describes initial performance based on light output, efficacy, distribution, color quality, electrical characteristics, and form factor, with comparisons to a selection of benchmark halogen MR16s and ENERGY STAR qualification thresholds. Three types of products were targeted. First, CALiPER sought 3000 K lamps with the highest rated lumen output (i.e., at least 500 lm) or a claim of equivalency to a 50 W halogen MR16 or higher. The test results indicate that while the initial performance of LED MR16s has improved across the board, market-available products still do not produce the lumen output and center beam intensity of typical 50 W halogen MR16 lamps. In fact, most of the 18 lamps in this category had lower lumen output and center beam intensity than a typical 35 W halogen MR16 lamp. Second, CALiPER sought lamps with a CRI of 90 or greater. Only four manufacturers were identified with a product in this category. CALiPER testing confirmed the performance of these lamps, which are a good option for applications where high color fidelity is needed. A vast majority of the LED MR16 lamps have a CRI in the low 80s; this is generally acceptable for ambient lighting, but may not always be acceptable for focal lighting. For typical LED packages, there is a fundamental tradeoff between CRI and efficacy, but the lamps in the high-CRI group in this report still offer comparable performance to the rest of the Series 22 products in other performance areas. Finally, CALiPER sought lamps with a narrow distribution, denoted as a beam angle less than 15°. Five such lamps were purchased. Notably, no lamp was identified as having high lumen output (500 lumens or greater), high CRI (90 or greater), a narrow distribution (15° or less), and an efficacy greater than 60 lm/W. This would be an important achievement for LED MR16s especially if output could reach approximately 700 800 lumens, or the approximate equivalent of a 50 W halogen MR16 lamp. Many factors beyond photometric performance should be considered during specification. For example, performance over time, transformer and dimmer compatibility, and total system performance are all critical to a successful installation. Subsequent CALiPER reports will investigate more complex issues.

  9. Retail Replacement Lamps | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    CALiPER Testing » Application Reports » Retail Replacement Lamps Retail Replacement Lamps Annual CALiPER testing of A19, G25, candelabra, night light, MR16/PAR16, PAR20, and PAR30 replacement lamps - purchased directly from store shelves - offers insights on performance trends from year to year. The report findings offer valuable insights for manufacturers and retailers alike. Retail Lamps Study 3 (48 pages, February 2014) Retail Lamps Study 3.1: Dimming, Flicker, and Power Quality

  10. Medium Base Compact Fluorescent Lamps

    Broader source: Energy.gov [DOE]

    The Department of Energy (DOE) develops standardized data templates for reporting the results of tests conducted in accordance with current DOE test procedures. Templates may be used by third-party laboratories under contract with DOE that conduct testing in support of ENERGY STAR® verification, DOE rulemakings, and enforcement of the federal energy conservation standards.

  11. High pressure neon arc lamp

    DOE Patents [OSTI]

    Sze, Robert C.; Bigio, Irving J.

    2003-07-15

    A high pressure neon arc lamp and method of using the same for photodynamic therapies is provided. The high pressure neon arc lamp includes a housing that encloses a quantity of neon gas pressurized to about 500 Torr to about 22,000 Torr. At each end of the housing the lamp is connected by electrodes and wires to a pulse generator. The pulse generator generates an initial pulse voltage to breakdown the impedance of the neon gas. Then the pulse generator delivers a current through the neon gas to create an electrical arc that emits light having wavelengths from about 620 nanometers to about 645 nanometers. A method for activating a photosensitizer is provided. Initially, a photosensitizer is administered to a patient and allowed time to be absorbed into target cells. Then the high pressure neon arc lamp is used to illuminate the target cells with red light having wavelengths from about 620 nanometers to about 645 nanometers. The red light activates the photosensitizers to start a chain reaction that may involve oxygen free radicals to destroy the target cells. In this manner, a high pressure neon arc lamp that is inexpensive and efficiently generates red light useful in photodynamic therapy is provided.

  12. CALiPER Snapshot: MR16 Lamps

    Energy Savers [EERE]

    C L E A N C I T I E S www.lightingfacts.com CALiPER last issued an LED Lighting Facts ... MR16 lamp is one of the most difficult lamps for LED technology to successfully replicate. ...

  13. Performance of T12 and T8 Fluorescent Lamps and Troffers and LED Linear Replacement Lamps CALiPER Benchmark Report

    SciTech Connect (OSTI)

    Myer, Michael; Paget, Maria L.; Lingard, Robert D.

    2009-01-16

    The Department of Energy (DOE) Commercially Available LED Product Evaluation and Reporting (CALiPER) Program was established in 2006 to investigate the performance of light-emitting diode (LED) based luminaires and replacement lamps. To help users better compare LED products with conventional lighting technologies, CALiPER has also performed benchmark research and testing of traditional (i.e., non-LED) lamps and fixtures. This benchmark report addresses standard 4-foot fluorescent lamps (i.e., T12 and T8) and the 2-foot by 4-foot recessed troffers in which they are commonly used. This report also examines available LED replacements for T12 and T8 fluorescent lamps, and their application in fluorescent troffers. The construction and operation of linear fluorescent lamps and troffers are discussed, as well as fluorescent lamp and fixture performance, based on manufacturer data and CALiPER benchmark testing. In addition, the report describes LED replacements for linear fluorescent lamps, and compares their bare lamp and in situ performance with fluorescent benchmarks on a range of standard lighting measures, including power usage, light output and distribution, efficacy, correlated color temperature, and the color rendering index. Potential performance and application issues indicated by CALiPER testing results are also examined.

  14. Retail Lamps Study 3.2: Lumen and Chromaticity Maintenance of LED A Lamps

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Operated in Steady-State Conditions | Department of Energy Retail Lamps Study 3.2: Lumen and Chromaticity Maintenance of LED A Lamps Operated in Steady-State Conditions Retail Lamps Study 3.2: Lumen and Chromaticity Maintenance of LED A Lamps Operated in Steady-State Conditions PDF icon Retail Lamps Study 3.2: Lumen and Chromaticity Maintenance of LED A Lamps Operated in Steady-State Conditions (42 pages, December 2014) More Documents & Publications Report 20.4: Lumen and Chromaticity

  15. Analysis of the efficiency of intermediate band solar cells based on quantum dot supercrystals

    SciTech Connect (OSTI)

    Heshmati, S; Golmohammadi, S; Abedi, K; Taleb, H

    2014-03-28

    We have studied the influence of the quantum-dot (QD) width and the quantum-dot conduction band (QD-CB) offset on the efficiency of quantum-dot intermediate band solar cells (QD-IBSCs). Simulation results demonstrate that with increasing QD-CB offset and decreasing QD width, the maximum efficiency is achieved. (laser applications and other topics in quantum electronics)

  16. Fluorescent Lamp Ballasts | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fluorescent Lamp Ballasts Fluorescent Lamp Ballasts The Department of Energy (DOE) develops standardized data templates for reporting the results of tests conducted in accordance with current DOE test procedures. Templates may be used by third-party laboratories under contract with DOE that conduct testing in support of ENERGY STAR® verification, DOE rulemakings, and enforcement of the federal energy conservation standards. File Fluorescent Lamp Ballasts -- v2.0 More Documents &

  17. LED PAR38 Lamps | Department of Energy

    Energy Savers [EERE]

    PAR38 Lamps LED PAR38 Lamps The following CALiPER reports provide detailed analysis of LED PAR38 lamp performance, covering basic performance characteristics as well as subjective evaluation of beam, shadow, and color quality. Pending reports will offer analysis on flicker, dimming and power quality characteristics; stress testing; and lumen and chromaticity maintenance. These reports are intended to educate the industry on market trends, potential issues, and important areas for improvement.

  18. Lamp bulb with integral reflector

    DOE Patents [OSTI]

    Levin, Izrail; Shanks, Bruce; Sumner, Thomas L.

    2001-01-01

    An improved electrodeless discharge lamp bulb includes an integral ceramic reflector as a portion of the bulb envelope. The bulb envelope further includes two pieces, a reflector portion or segment is cast quartz ceramic and a light transmissive portion is a clear fused silica. In one embodiment, the cast quartz ceramic segment includes heat sink fins or stubs providing an increased outside surface area to dissipate internal heat. In another embodiment, the quartz ceramic segment includes an outside surface fused to eliminate gas permeation by polishing.

  19. Discharge lamp with reflective jacket

    DOE Patents [OSTI]

    MacLennan, Donald A.; Turner, Brian P.; Kipling, Kent

    2001-01-01

    A discharge lamp includes an envelope, a fill which emits light when excited disposed in the envelope, a source of excitation power coupled to the fill to excite the fill and cause the fill to emit light, and a reflector disposed around the envelope and defining an opening, the reflector being configured to reflect some of the light emitted by the fill back into the fill while allowing some light to exit through the opening. The reflector may be made from a material having a similar thermal index of expansion as compared to the envelope and which is closely spaced to the envelope. The envelope material may be quartz and the reflector material may be either silica or alumina. The reflector may be formed as a jacket having a rigid structure which does not adhere to the envelope. The lamp may further include an optical clement spaced from the envelope and configured to reflect an unwanted component of light which exited the envelope back into the envelope through the opening in the reflector. Light which can be beneficially recaptured includes selected wavelength regions, a selected polarization, and selected angular components.

  20. DuraLamp USA: Order (2010-CE-0912)

    Broader source: Energy.gov [DOE]

    DOE ordered DuraLamp USA, Inc. to pay a $2,500 civil penalty after finding DuraLamp USA had failed to certify that model PAR 30, an incandescent reflector lamp, complies with the applicable energy conservation standards.

  1. Energy Cost Calculator for Compact Fluorescent Lamps | Department of Energy

    Office of Environmental Management (EM)

    Compact Fluorescent Lamps Energy Cost Calculator for Compact Fluorescent Lamps This tool calculates the payback period for your calc retrofit project. Modify the default values to suit your project requirements. Existing incandescent lamp wattage Watts Incandescent lamp cost dollars Incandescent lamp life 1000 hours calc wattage Watts calc cost dollars calc life (6000 hours for moderate use, 10000 hours for high use) 8000 hours Number of lamps in retrofit project Hours operating per week hours

  2. Portable lamp with dynamically controlled lighting distribution

    DOE Patents [OSTI]

    Siminovitch, Michael J.; Page, Erik R.

    2001-01-01

    A double lamp table or floor lamp lighting system has a pair of compact fluorescent lamps (CFLs) arranged vertically with a reflective septum in between. By selectively turning on one or both of the CFLs, down lighting, up lighting, or both up and down lighting is produced. The control system can also vary the light intensity from each CFL. The reflective septum insures that almost all the light produced by each lamp will be directed into the desired light distribution pattern which is selected and easily changed by the user. Planar compact fluorescent lamps, e.g. circular CFLs, particularly oriented horizontally, are preferable. CFLs provide energy efficiency. The lighting system may be designed for the home, hospitality, office or other environments.

  3. Use of Standard Fluorescent UV Weathering Lamps to Perform UV...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Use of Standard Fluorescent UV Weathering Lamps to Perform UV Conditioning Tests Prescribed in IEC Qualification Standards Use of Standard Fluorescent UV Weathering Lamps to...

  4. Text-Alternative Version: CALiPER Report Series 20 on LED PAR38 Lamps |

    Energy Savers [EERE]

    Department of Energy Text-Alternative Version: CALiPER Report Series 20 on LED PAR38 Lamps Text-Alternative Version: CALiPER Report Series 20 on LED PAR38 Lamps Michael Royer, Lighting Engineer, Pacific Northwest National Laboratory: The CALiPER program looks at typical LED lamp performance attributes. As we've gone through the progression of reports, we've really seen that a lot of times we're coming to the same conclusions-- that based on basic performance, LED products, at least some of

  5. Lamp system for uniform semiconductor wafer heating

    DOE Patents [OSTI]

    Zapata, Luis E. (Livermore, CA); Hackel, Lloyd (Livermore, CA)

    2001-01-01

    A lamp system with a very soft high-intensity output is provided over a large area by water cooling a long-arc lamp inside a diffuse reflector of polytetrafluorethylene (PTFE) and titanium dioxide (TiO.sub.2) white pigment. The water is kept clean and pure by a one micron particulate filter and an activated charcoal/ultraviolet irradiation system that circulates and de-ionizes and biologically sterilizes the coolant water at all times, even when the long-arc lamp is off.

  6. CALiPER Retail Lamps Study 3

    SciTech Connect (OSTI)

    Royer, Michael P.; Beeson, Tracy A.

    2014-02-01

    The CALiPER program first began investigating LED lamps sold at retail stores in 2010, purchasing 33 products from eight retailers and covering six product categories. The findings revealed a fragmented marketplace, with large disparities in performance of different products, accuracy of manufacturer claims, and offerings from different retail outlets. Although there were some good products, looking back many would not be considered viable competitors to other available options, with too little lumen output, not high enough efficacy, or poor color quality. CALiPER took another look in late 2011purchasing 38 products of five different types from nine retailers and the improvement was marked. Performance was up; retailer claims were more accurate; and the price per lumen and price per unit efficacy were down, although the price per product had not changed much. Nonetheless, there was still plenty of room for improvement, with the performance of LED lamps not yet reaching that of well-established classes of conventional lamps (e.g., 75 W incandescent A19 lamps). Since the second retail lamp study was published in early 2012, there has been substantial progress in all aspects of LED lamps available from retailers. To document this progress, CALiPER again purchased a sample of lamps from retail stores 46 products in total, focusing on A19, PAR30, and MR16 lamps but instead of a random sample, sought to select products to answer specific hypotheses about performance. These hypotheses focused on expanding ranges of LED equivalency, the accuracy of lifetime claims, efficacy and price trends, as well as changes to product designs. Among other results, key findings include: There are now very good LED options to compete with 60 W, 75 W, and 100 W incandescent A19 lamps, and 75 W halogen PAR30 lamps. MR16 lamps have shown less progress, but there are now acceptable alternatives to 35 W, 12 V halogen MR16 lamps and 50 W, 120 V halogen MR16 lamps for some applications. Other uses, such as in enclosed luminaires, may require more development. At the same price point, lamps purchased in 2013 tended to have higher output and slightly higher efficacy than in 2011 or 2010. Over 30% of the products purchased in 2013 exceeded the maximum efficacy measured in 2011 (71 lm/W), with the most efficacious product measured at 105 lm/W. There appears to be increasing consistency in color quality, with a vast majority of products having a CCT of 2700 K or 3000 K and a CRI between 80 and 85. There were also fewer poor performing products tested and more high-performing products available in 2013 than in previous years. The accuracy of equivalency and performance claims was better than in 2011, but remains a concern, with 43% of tested products failing to completely meet their equivalency claim and 20% of products failing to match the manufacturer’s performance data. Although progress has been substantial, on average LED lamps remain more expensive than other energy efficiency lighting technologies -- although some aspects can be superior. Although not universal to all product lines or all product types, the issue of insufficient lumen output from LED lamps is waning. Thus, manufacturers can focus on other issues, such as reducing cost, improving electrical/dimmer compatibility, eliminating flicker, or improving color quality. While these issues are not inherent to all products, they remain a concern for the broader market.

  7. LED lamp power management system and method

    SciTech Connect (OSTI)

    Gaines, James; Clauberg, Bernd; Van Erp, Josephus A. M.

    2013-03-19

    An LED lamp power management system and method including an LED lamp having an LED controller 58; a plurality of LED channels 60 operably connected to the LED controller 58, each of the plurality of LED channels 60 having a channel switch 62 in series with at least one shunted LED circuit 83, the shunted LED circuit 83 having a shunt switch 68 in parallel with an LED source 80. The LED controller 58 reduces power loss in one of the channel switch 62 and the shunt switch 68 when LED lamp electronics power loss (P.sub.loss) exceeds an LED lamp electronics power loss limit (P.sub.lim); and each of the channel switches 62 receives a channel switch control signal 63 from the LED controller 58 and each of the shunt switches 68 receives a shunt switch control signal 69 from the LED controller 58.

  8. LED Linear Lamps and Troffer Lighting | Department of Energy

    Energy Savers [EERE]

    Linear Lamps and Troffer Lighting LED Linear Lamps and Troffer Lighting View the video about CALiPER Series 21 on LED Linear Lamps and Troffer Lighting. The CALiPER program performed a series of investigations on linear LED lamps. Each report in the series covers the performance of up to 31 linear LED lamps, which were purchased in late 2012 or 2013. The first report focuses on bare lamp performance of LED T8 replacement lamps and subsequent reports examine performance in various troffers, as

  9. High frequency inductive lamp and power oscillator

    DOE Patents [OSTI]

    MacLennan, Donald A.; Turner, Brian P.; Dolan, James T.; Kirkpatrick, Douglas A.; Leng, Yongzhang

    2000-01-01

    A high frequency inductively coupled electrodeless lamp includes an excitation coil with an effective electrical length which is less than one half wavelength of a driving frequency applied thereto, preferably much less. The driving frequency may be greater than 100 MHz and is preferably as high as 915 MHz. Preferably, the excitation coil is configured as a non-helical, semi-cylindrical conductive surface having less than one turn, in the general shape of a wedding ring. At high frequencies, the current in the coil forms two loops which are spaced apart and parallel to each other. Configured appropriately, the coil approximates a Helmholtz configuration. The lamp preferably utilizes an bulb encased in a reflective ceramic cup with a pre-formed aperture defined therethrough. The ceramic cup may include structural features to aid in alignment and/or a flanged face to aid in thermal management. The lamp head is preferably an integrated lamp head comprising a metal matrix composite surrounding an insulating ceramic with the excitation integrally formed on the ceramic. A novel solid-state oscillator preferably provides RF power to the lamp. The oscillator is a single active element device capable of providing over 70 watts of power at over 70% efficiency. Various control circuits may be employed to match the driving frequency of the oscillator to a plurality of tuning states of the lamp.

  10. LED T8 Replacement Lamps | Department of Energy

    Energy Savers [EERE]

    LED T8 Replacement Lamps LED T8 Replacement Lamps This documents provides an overview of LED T8 replacement lamps and helps define a reasonable minimum performance level for the purpose of plant-wide improvement. PDF icon LED T8 Replacement Lamps (April 2010) More Documents & Publications Emerging Lighting Technology General Service LED Lamps Guiding Market Introduction of High-Performance SSL Products

  11. High frequency inductive lamp and power oscillator

    DOE Patents [OSTI]

    MacLennan, Donald A.; Dymond, Jr., Lauren E.; Gitsevich, Aleksandr; Grimm, William G.; Kipling, Kent; Kirkpatrick, Douglas A.; Ola, Samuel A.; Simpson, James E.; Trimble, William C.; Tsai, Peter; Turner, Brian P.

    2001-01-01

    A high frequency inductively coupled electrodeless lamp includes an excitation coil with an effective electrical length which is less than one half wavelength of a driving frequency applied thereto, preferably much less. The driving frequency may be greater than 100 MHz and is preferably as high as 915 MHz. Preferably, the excitation coil is configured as a non-helical, semi-cylindrical conductive surface having less than one turn, in the general shape of a wedding ring. At high frequencies, the current in the coil forms two loops which are spaced apart and parallel to each other. Configured appropriately, the coil approximates a Helmholtz configuration. The lamp preferably utilizes an bulb encased in a reflective ceramic cup with a pre-formed aperture defined therethrough. The ceramic cup may include structural features to aid in alignment and I or a flanged face to aid in thermal management. The lamp head is preferably an integrated lamp head comprising a metal matrix composite surrounding an insulating ceramic with the excitation integrally formed on the ceramic. A novel solid-state oscillator preferably provides RF power to the lamp. The oscillator is a single active element device capable of providing over 70 watts of power at over 70% efficiency. Various control circuits may be employed to adjust the driving frequency of the oscillator.

  12. Retail Lamps Study 3.1: Dimming, Flicker, and Power Quality Characteristics of LED A Lamps.

    SciTech Connect (OSTI)

    Royer, Michael P.; Poplawski, Michael E.; Brown, Charles C.

    2014-12-14

    To date, all three reports in the retail lamps series have focused on basic performance parameters, such as lumen output, efficacy, and color quality. This report goes a step further, examining the photoelectric characteristics (i.e., dimming and flicker) of a subset of lamps from CALiPER Retails Lamps Study 3. Specifically, this report focuses on the dimming, power quality, and flicker characteristics of 14 LED A lamps, as controlled by four different retail-available dimmers. The results demonstrate notable variation across the various lamps, but little variation between the four dimmers. Overall, the LED lamps: ~tended to have higher relative light output compared to the incandescent and halogen benchmark at the same dimmer output signal (RMS voltage). The lamps’ dimming curves (i.e., the relationship between control signal and relative light output) ranged from linear to very similar to the square-law curve typical of an incandescent lamp. ~generally exhibited symmetrical behavior—the same dimming curve—when measured proceeding from maximum to minimum or minimum to maximum control signal. ~mostly dimmed below 10% of full light output, with some exceptions for specific lamp and dimmer combinations ~exhibited a range of flicker characteristics, with many comparing favorably to the level typical of a magnetically-ballasted fluorescent lamp through at least a majority of the dimming range. ~ always exceeded the relative (normalized) efficacy over the dimming range of the benchmark lamps, which rapidly decline in efficacy when they are dimmed. This report generally does not attempt to rank the performance of one product compared to another, but instead focuses on the collective performance of the group versus conventional incandescent or halogen lamps, the performance of which is likely to be the baseline for a majority of consumers. Undoubtedly, some LED lamps perform better—or more similar to conventional lamps—than others. Some perform desirably for one characteristic, but not others. Consumers (and specifiers) may have a hard time distinguishing better-performing lamps from one another; at this time, physical experimentation is likely the best evaluation tool.

  13. Laboratory Evaluation of LED T8 Replacement Lamp Products

    SciTech Connect (OSTI)

    Richman, Eric E.; Kinzey, Bruce R.; Miller, Naomi J.

    2011-05-23

    A report on a lab setting analysis involving LED lamps intended to directly replace T8 fluorescent lamps (4') showing light output, power, and economic comparisons with other fluorescent options.

  14. DuraLamp USA: Proposed Penalty (2010-CE-0912)

    Office of Energy Efficiency and Renewable Energy (EERE)

    DOE alleged in a Notice of Proposed Civil Penalty that DuraLamp USA, Inc. failed to certify a variety of general service fluorescent lamps as compliant with the applicable energy conservation standards.

  15. Demonstration of Light-Emitting Diode (LED) Retrofit Lamps

    SciTech Connect (OSTI)

    Miller, N.

    2011-09-01

    GATEWAY program report on a demonstration of LED retrofit lamps at the Jordan Schnitzer Museum of art in Eugene, OR

  16. Text-Alternative Version: LED Replacements for Linear Fluorescent Lamps

    Broader source: Energy.gov [DOE]

    Below is the text-alternative version of the "LED Replacements for Linear Fluorescent Lamps" webcast, held June 20, 2011.

  17. CALiPER Retail Lamps Study 3.1: Dimming, Flicker, and Power Quality Characteristics of LED A Lamps

    SciTech Connect (OSTI)

    none,

    2014-12-31

    This CALiPER report examines the characteristics of a subset of lamps from CALiPER Retail Lamps Study 3 in more detail. Specifically, it focuses on the dimming, power quality, and flicker characteristics of 14 LED A lamps, as controlled by four different retail-available dimmers.

  18. Controlling the vapor pressure of a mercury lamp

    DOE Patents [OSTI]

    Grossman, Mark W. (Belmont, MA); George, William A. (Rockport, MA)

    1988-01-01

    The invention described herein discloses a method and apparatus for controlling the Hg vapor pressure within a lamp. This is done by establishing and controlling two temperature zones within the lamp. One zone is colder than the other zone. The first zone is called the cold spot. By controlling the temperature of the cold spot, the Hg vapor pressure within the lamp is controlled. Likewise, by controlling the Hg vapor pressure of the lamp, the intensity and linewidth of the radiation emitted from the lamp is controlled.

  19. LED Performance Specification Series: T8 Replacement Lamps

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Photo credit: PNNL LED T8 replacements may contain dozens of high power LEDs or hundreds of 5mm LEDs behind a clear or frosted lens, all in a medium bi-pin T8 lamp package. Table 1. CALiPER Test Results for 4-foot LED T8 Replacements with Fluorescent Benchmarks Performance Characteristics LED T8 Replacements Fluorescent Benchmarks Range (12 lamps tested) Average Mfr. Data (75 lamps) CALiPER (2 fxtures tested) Initial Lamp Light Output (lm) 345 - 1,579 1,111 2,778 3,091 Initial 2-Lamp System

  20. Controlling the vapor pressure of a mercury lamp

    DOE Patents [OSTI]

    Grossman, M.W.; George, W.A.

    1988-05-24

    The invention described herein discloses a method and apparatus for controlling the Hg vapor pressure within a lamp. This is done by establishing and controlling two temperature zones within the lamp. One zone is colder than the other zone. The first zone is called the cold spot. By controlling the temperature of the cold spot, the Hg vapor pressure within the lamp is controlled. Likewise, by controlling the Hg vapor pressure of the lamp, the intensity and linewidth of the radiation emitted from the lamp is controlled. 2 figs.

  1. LED lamp color control system and method

    SciTech Connect (OSTI)

    Gaines, James; Clauberg, Bernd; Van Erp, Josephus A.M.

    2013-02-05

    An LED lamp color control system and method including an LED lamp having an LED controller 58; and a plurality of LED channels 60 operably connected to the LED controller 58, each of the plurality of LED channels 60 having a channel switch 62 in series with at least one shunted LED circuit 83, the shunted LED circuit 83 having a shunt switch 68 in parallel with an LED source 80. The LED controller 58 determines whether the LED source 80 is in a feedback controllable range, stores measured optical flux for the LED source 80 when the LED source 80 is in the feedback controllable range, and bypasses storing the measured optical flux when the LED source 80 is not in the feedback controllable range.

  2. Energy-Efficient, High-Color-Rendering LED Lamps Using Oxyfluoride and Fluoride Phosphors

    SciTech Connect (OSTI)

    Setlur, A.; Radkov, E; Henderson, C; Her, J; Srivastava, A; Karkada, N; Kishore, M; Kumar, N; Aesram, D; et al.

    2010-01-01

    LED lamps using phosphor downconversion can be designed to replace incandescent or halogen sources with a 'warm-white' correlated color temperature (CCT) of 2700-3200 K and a color rendering index (CRI) greater than 90. However, these lamps have efficacies of {approx}70% of standard 'cool-white' LED packages (CCT = 4500-6000 K; CRI = 75-80). In this report, we describe structural and luminescence properties of fluoride and oxyfluoride phosphors, specifically a (Sr,Ca){sub 3}(Al,Si)O{sub 4}(F,O):Ce{sup 3+} yellow-green phosphor and a K{sub 2}TiF{sub 6}:Mn{sup 4+} red phosphor, that can reduce this gap and therefore meet the spectral and efficiency requirements for high-efficacy LED lighting. LED lamps with a warm-white color temperature (3088 K), high CRI (90), and an efficacy of {approx}82 lm/W are demonstrated using these phosphors. This efficacy is {approx}85% of comparable cool-white lamps using typical Y{sub 3}Al{sub 5}O{sub 12}:Ce{sup 3+}-based phosphors, significantly reducing the efficacy gap between warm-white and cool-white LED lamps that use phosphor downconversion.

  3. CALiPER Retail Lamps Study 3

    SciTech Connect (OSTI)

    none,

    2014-02-01

    This is a special CALiPER report on LED lamps available through the retail marketplace and targeted toward general consumers. It follows similar reports published in 2011 and 2012 (products purchased in 2010 and 2011), and is intended as a continuation that identifies long-term trends. For this report, products were selected to investigate specific hypotheses, rather than represent a sample of the increasingly large retail LED market.

  4. Lamp method and apparatus using multiple reflections

    DOE Patents [OSTI]

    MacLennan, Donald A.; Turner, Brian; Kipling, Kent

    1999-01-01

    A method wherein the light in a sulfur or selenium lamp is reflected through the fill a multiplicity of times to convert ultraviolet radiation to visible. A light emitting device comprised of an electrodeless envelope which bears a light reflecting covering around a first portion which does not crack due to differential thermal expansion and which has a second portion which comprises a light transmissive aperture.

  5. Lamp method and apparatus using multiple reflections

    DOE Patents [OSTI]

    MacLennan, D.A.; Turner, B.; Kipling, K.

    1999-05-11

    A method wherein the light in a sulfur or selenium lamp is reflected through the fill a multiplicity of times to convert ultraviolet radiation to visible is disclosed. A light emitting device comprised of an electrodeless envelope which bears a light reflecting covering around a first portion which does not crack due to differential thermal expansion and which has a second portion which comprises a light transmissive aperture. 20 figs.

  6. High output lamp with high brightness

    DOE Patents [OSTI]

    Kirkpatrick, Douglas A.; Bass, Gary K.; Copsey, Jesse F.; Garber, Jr., William E.; Kwong, Vincent H.; Levin, Izrail; MacLennan, Donald A.; Roy, Robert J.; Steiner, Paul E.; Tsai, Peter; Turner, Brian P.

    2002-01-01

    An ultra bright, low wattage inductively coupled electrodeless aperture lamp is powered by a solid state RF source in the range of several tens to several hundreds of watts at various frequencies in the range of 400 to 900 MHz. Numerous novel lamp circuits and components are disclosed including a wedding ring shaped coil having one axial and one radial lead, a high accuracy capacitor stack, a high thermal conductivity aperture cup and various other aperture bulb configurations, a coaxial capacitor arrangement, and an integrated coil and capacitor assembly. Numerous novel RF circuits are also disclosed including a high power oscillator circuit with reduced complexity resonant pole configuration, parallel RF power FET transistors with soft gate switching, a continuously variable frequency tuning circuit, a six port directional coupler, an impedance switching RF source, and an RF source with controlled frequency-load characteristics. Numerous novel RF control methods are disclosed including controlled adjustment of the operating frequency to find a resonant frequency and reduce reflected RF power, controlled switching of an impedance switched lamp system, active power control and active gate bias control.

  7. High Efficiency LED Lamp for Solid-State Lighting

    SciTech Connect (OSTI)

    James Ibbetson

    2006-12-31

    This report contains a summary of technical achievements during a three-year project to demonstrate high efficiency, solid-state lamps based on gallium nitride/silicon carbide light-emitting diodes. Novel chip designs and fabrication processes are described for a new type of nitride light-emitting diode with the potential for very high efficiency. This work resulted in the demonstration of blue light-emitting diodes in the one watt class that achieved up to 495 mW of light output at 350 mA drive current, corresponding to quantum and wall plug efficiencies of 51% and 45%, respectively. When combined with a phosphor in Cree's 7090 XLamp package, these advanced blue-emitting devices resulted in white light-emitting diodes whose efficacy exceeded 85 lumens per watt. In addition, up to 1040 lumens at greater than 85 lumens per watt was achieved by combining multiple devices to make a compact white lamp module with high optical efficiency.

  8. Seeking Feedback on General Service Lamps | Department of Energy

    Energy Savers [EERE]

    Seeking Feedback on General Service Lamps Seeking Feedback on General Service Lamps March 18, 2016 - 10:47am Addthis The United States (U.S.) Department of Energy (DOE) Building Technologies Office (BTO) Emerging Technologies Program is seeking information from the public regarding lamps in general illumination applications. The Emerging Technologies Program supports applied research and development (R&D) for technologies and systems that contribute to reductions in building energy

  9. Purchasing Energy-Efficient General Service Fluorescent Lamps | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Purchasing Energy-Efficient General Service Fluorescent Lamps Purchasing Energy-Efficient General Service Fluorescent Lamps The Federal Energy Management Program (FEMP) provides acquisition guidance for general service fluorescent lamps (GSFLs), a product category covered by FEMP efficiency requirements. Federal laws and requirements mandate that agencies purchase ENERGY STAR qualified or FEMP designated products in all product categories covered by these programs and in any

  10. Metal Halide Lamp Ballasts and Fixtures | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Metal Halide Lamp Ballasts and Fixtures Metal Halide Lamp Ballasts and Fixtures The Department of Energy (DOE) develops standardized data templates for reporting the results of tests conducted in accordance with current DOE test procedures. Templates may be used by third-party laboratories under contract with DOE that conduct testing in support of ENERGY STAR® verification, DOE rulemakings, and enforcement of the federal energy conservation standards. File Metal Halide Lamp Ballasts and

  11. LED Replacements for Linear Fluorescent Lamps Webcast | Department of

    Energy Savers [EERE]

    Energy Replacements for Linear Fluorescent Lamps Webcast LED Replacements for Linear Fluorescent Lamps Webcast In this June 20, 2011 webcast on LED products marketed as replacements for linear fluorescent lamps, Jason Tuenge of the Pacific Northwest National Laboratory (PNNL) discussed current Lighting Facts-listed products as well as products evaluated in the latest CALiPER reports. Eric Richman, also of PNNL, reported on a recently completed GATEWAY demonstration project, in which LED and

  12. Fluorescent lamp unit with magnetic field generating means

    DOE Patents [OSTI]

    Grossman, M.W.; George, W.A.

    1989-08-08

    A fluorescent lamp unit having a magnetic field generating means for improving the performance of the fluorescent lamp is disclosed. In a preferred embodiment the fluorescent lamp comprises four longitudinally extending leg portions disposed in substantially quadrangular columnar array and joined by three generally U-shaped portions disposed in different planes. In another embodiment of the invention the magnetic field generating means comprises a plurality of permanent magnets secured together to form a single columnar structure disposed within a centrally located region defined by the shape of lamp envelope. 4 figs.

  13. Max Tech and Beyond: High-Intensity Discharge Lamps (Technical...

    Office of Scientific and Technical Information (OSTI)

    the light source of choice in street and area lighting, and sports stadium illumination. ... HID lamps offer important advantages compared to other lighting technologies, making them ...

  14. Heat transfer assembly for a fluorescent lamp and fixture

    DOE Patents [OSTI]

    Siminovitch, M.J.; Rubenstein, F.M.; Whitman, R.E.

    1992-12-29

    In a lighting fixture including a lamp and a housing, a heat transfer structure is disclosed for reducing the minimum lamp wall temperature of a fluorescent light bulb. The heat transfer structure, constructed of thermally conductive material, extends from inside the housing to outside the housing, transferring heat energy generated from a fluorescent light bulb to outside the housing where the heat energy is dissipated to the ambient air outside the housing. Also disclosed is a method for reducing minimum lamp wall temperatures. Further disclosed is an improved lighting fixture including a lamp, a housing and the aforementioned heat transfer structure. 11 figs.

  15. Heat transfer assembly for a fluorescent lamp and fixture

    DOE Patents [OSTI]

    Siminovitch, Michael J.; Rubenstein, Francis M.; Whitman, Richard E.

    1992-01-01

    In a lighting fixture including a lamp and a housing, a heat transfer structure is disclosed for reducing the minimum lamp wall temperature of a fluorescent light bulb. The heat transfer structure, constructed of thermally conductive material, extends from inside the housing to outside the housing, transferring heat energy generated from a fluorescent light bulb to outside the housing where the heat energy is dissipated to the ambient air outside the housing. Also disclosed is a method for reducing minimum lamp wall temperatures. Further disclosed is an improved lighting fixture including a lamp, a housing and the aforementioned heat transfer structure.

  16. Fluorescent lamp unit with magnetic field generating means

    DOE Patents [OSTI]

    Grossman, Mark W. (Belmont, MA); George, William A. (Rockport, MA)

    1989-01-01

    A fluorescent lamp unit having a magnetic field generating means for improving the performance of the fluorescent lamp is disclosed. In a preferred embodiment the fluorescent lamp comprises four longitudinally extending leg portions disposed in substantially quadrangular columnar array and joined by three generally U-shaped portions disposed in different planes. In another embodiment of the invention the magnetic field generating means comprises a plurality of permanent magnets secured together to form a single columnar structure disposed within a centrally located region defined by the shape of lamp envelope.

  17. Report 22.1: Photoelectric Performance of LED MR16 Lamps | Department of

    Energy Savers [EERE]

    Energy 2.1: Photoelectric Performance of LED MR16 Lamps Report 22.1: Photoelectric Performance of LED MR16 Lamps PDF icon caliper_22-1_mr16.pdf More Documents & Publications LED MR16 Lamps Caliper Retail Lamps Study 3.1: Dimming, Flicker, and Power Quality Characteristics of LED A Lamps LED Directional

  18. Compact microwave lamp having a tuning block and a dielectric located in a lamp cavity

    DOE Patents [OSTI]

    Simpson, James E.

    2000-01-01

    A microwave lamp having a compact structure utilizing a coupling slot which has a dielectric member extending therethrough and a tuning block adjoining the coupling slot. A non-conventional waveguide is used which has about the width of a WR-284 waveguide and about the length of a WR-340 waveguide.

  19. RF driven sulfur lamp having driving electrodes arranged to cool the lamp

    DOE Patents [OSTI]

    Gabor, G.; Orr, T.R.; Greene, C.M.; Crawford, D.G.; Berman, S.M.

    1998-10-20

    A high intensity discharge lamp without mercury is disclosed radiating a selected spectrum of which can be almost entirely in the visible range from an envelope that contains a sulfur containing substance. The lamp utilizes a signal source that generates an excitation signal that is externally coupled to the exterior surface of the envelope to excite the enclosed sulfur containing substance. Various embodiments of the lamp use electrodes adjacent the envelope to couple the excitation signal thereto with the face of the electrodes shaped to complement the shape of the exterior surface of the envelope. Two shapes discussed are spherical and cylindrical. To minimize filamentary discharges each envelope may include an elongated stem affixed to the exterior thereof whereby a rotational subsystem spins the envelope. In yet another embodiment the envelope has a Dewar configuration with two electrodes, one positioned near the external curved side surface of the body, and a second to the inner surface of the hole through the envelope. Further, the envelope may contain a backfill of a selected inert gas to assist in the excitation of lamp with that backfill at a pressure of less than 1 atmosphere, wherein the backfill pressure is directly related to the increase or decrease of peak output and inversely related to the increase and decrease of the emitted spectrum from the envelope. The emitting fill can be less than 6 mg/cc, or at least 2 mg/cc of the envelope of a sulfur containing substance. 17 figs.

  20. RF driven sulfur lamp having driving electrodes arranged to cool the lamp

    DOE Patents [OSTI]

    Gabor, George (820 Skywood Rd., Lafayette, CA 94549); Orr, Thomas Robert (2285 Vestal, Castro Valley, CA 94546); Greene, Charles Maurice (6450 Regent St., Oakland, CA 94618); Crawford, Douglas Gordon (33 Longridge Rd., Orinda, CA 94563); Berman, Samuel Maurice (2832 Union St., San Francisco, CA 94123)

    1998-01-01

    A high intensity discharge lamp without mercury is disclosed radiating a selected spectrum of which can be almost entirely in the visible range from an envelope that contains a sulfur containing substance. The lamp utilizes a signal source that generates an excitation signal that is externally coupled to the exterior surface of the envelope to excite the enclosed sulfur containing substance. Various embodiments of the lamp use electrodes adjacent the envelope to couple the excitation signal thereto with the face of the electrodes shaped to complement the shape of the exterior surface of the envelope. Two shapes discussed are spherical and cylindrical. To minimize filamentary discharges each envelope may include an elongated stem affixed to the exterior thereof whereby a rotational subsystem spins the envelope. In yet another embodiment the envelope has a Dewar configuration with two electrodes, one positioned near the external curved side surface of the body, and a second to the inner surface of the hole through the envelope. Further, the envelope may contain a backfill of a selected inert gas to assist in the excitation of lamp with that backfill at a pressure of less than 1 atmosphere, wherein the backfill pressure is directly related to the increase or decrease of peak output and inversely related to the increase and decrease of the emitted spectrum from the envelope. The emitting fill can be less than 6 mg/cc, or at least 2 mg/cc of the envelope of a sulfur containing substance.

  1. Segregation At Stacking Faults Within The ?' Phase Of Two Ni-base Superalloys Following Intermediate Temperature Creep

    SciTech Connect (OSTI)

    Viswanathan, G. B.; Shi, R.; Genc, Arda; Vorontsov, V. A.; Kovarik, Libor; Rae, C.M. F.; Mills, M. J.

    2015-01-01

    Using state-of-the-art energy dispersive spectroscopy, it has been established for the first time that there exists significant compositional variation (enrichment of Co and Cr and deficiency of Ni and Al) associated with superlattice intrinsic stacking faults created in the ordered ?' precipitates following intermediate temperature deformation of two commercial superalloys. The results indicate that long range diffusion of these elements is intimately involved in the precipitate shearing process and is therefore closely linked to the time-dependent deformation of the alloys.

  2. CALiPER Report 21.2. Linear (T8) LED Lamp Performance in Five Types of Recessed Troffers

    SciTech Connect (OSTI)

    2014-05-01

    Although lensed troffers are numerous, there are many other types of optical systems as well. This report looks at the performance of three linear (T8) LED lamps—chosen primarily based on their luminous intensity distributions (narrow, medium, and wide beam angles)—as well as a benchmark fluorescent lamp in five different troffer types. Also included are the results of a subjective evaluation. Results show that linear (T8) LED lamps can improve luminaire efficiency in K12-lensed and parabolic-louvered troffers, effect little change in volumetric and high-performance diffuse-lensed type luminaires, but reduce efficiency in recessed indirect troffers. These changes can be accompanied by visual appearance and visual comfort consequences, especially when LED lamps with clear lenses and narrow distributions are installed. Linear (T8) LED lamps with diffuse apertures exhibited wider beam angles, performed more similarly to fluorescent lamps, and received better ratings from observers. Guidance is provided on which luminaires are the best candidates for retrofitting with linear (T8) LED lamps.

  3. Lamp for generating high power ultraviolet radiation

    DOE Patents [OSTI]

    Morgan, Gary L. (Elkridge, MD); Potter, James M. (Los Alamos, NM)

    2001-01-01

    The apparatus is a gas filled ultraviolet generating lamp for use as a liquid purifier. The lamp is powred by high voltage AC, but has no metallic electrodes within or in contact with the gas enclosure which is constructed as two concentric quartz cylinders sealed together at their ends with the gas fill between the cylinders. Cooling liquid is pumped through the volume inside the inner quartz cylinder where an electrically conductive pipe spaced from the inner cylinder is used to supply the cooling liquid and act as the high voltage electrode. The gas enclosure is enclosed within but spaced from a metal housing which is connected to operate as the ground electrode of the circuit and through which the treated fluid flows. Thus, the electrical circuit is from the central pipe, and through the cooling liquid, the gas enclosure, the treated liquid on the outside of the outer quartz cylinder, and to the housing. The high voltage electrode is electrically isolated from the source of cooling liquid by a length of insulated hose which also supplies the cooling liquid.

  4. Retail Lamps Study 3.2: Lumen and Chromaticity Maintenance of...

    Office of Environmental Management (EM)

    Retail Lamps Study 3.2: Lumen and Chromaticity Maintenance of LED A Lamps Operated in Steady-State Conditions Retail Lamps Study 3.2: Lumen and Chromaticity Maintenance of LED A ...

  5. Caliper Retail Lamps Study 3.1: Dimming, Flicker, and Power Quality...

    Energy Savers [EERE]

    and Power Quality Characteristics of LED A Lamps Caliper Retail Lamps Study 3.1: Dimming, Flicker, and Power Quality Characteristics of LED A Lamps PDF icon caliperretail-study...

  6. Fluorescent lamp with static magnetic field generating means

    DOE Patents [OSTI]

    Moskowitz, P.E.; Maya, J.

    1987-09-08

    A fluorescent lamp wherein magnetic field generating means (e.g., permanent magnets) are utilized to generate a static magnetic field across the respective electrode structures of the lamp such that maximum field strength is located at the electrode's filament. An increase in efficacy during operation has been observed. 2 figs.

  7. Convection venting lensed reflector-type compact fluorescent lamp system

    DOE Patents [OSTI]

    Pelton, B.A.; Siminovitch, M.

    1997-07-29

    Disclosed herein is a fluorescent lamp housing assembly capable of providing convection cooling to the lamp and the ballast. The lens of the present invention includes two distinct portions, a central portion and an apertured portion. The housing assembly further includes apertures so that air mass is able to freely move up through the assembly and out ventilation apertures. 12 figs.

  8. Convection venting lensed reflector-type compact fluorescent lamp system

    DOE Patents [OSTI]

    Pelton, Bruce A. (825 Manor Rd., El Sobrante, CA 94803); Siminovitch, Michael (829 Manor Rd., El Sobrante, CA 94803)

    1997-01-01

    Disclosed herein is a fluorescent lamp housing assembly capable of providing convection cooling to the lamp and the ballast. The lens of the present invention includes two distinct portions, a central portion and an apertured portion. The housing assembly further includes apertures so that air mass is able to freely move up through the assembly and out ventilation apertures.

  9. Fluorescent lamp with static magnetic field generating means

    DOE Patents [OSTI]

    Moskowitz, Philip E. (Peabody, MA); Maya, Jakob (Brookline, MA)

    1987-01-01

    A fluorescent lamp wherein magnetic field generating means (e.g., permanent magnets) are utilized to generate a static magnetic field across the respective electrode structures of the lamp such that maximum field strength is located at the electrode's filament. An increase in efficacy during operation has been observed.

  10. Report 20.3: Stress Testing of LED PAR38 Lamps | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    0.3: Stress Testing of LED PAR38 Lamps Report 20.3: Stress Testing of LED PAR38 Lamps PDF icon Report 20.3: Stress Testing of LED PAR38 Lamps More Documents & Publications Report 20.4: Lumen and Chromaticity Maintenance of LED PAR38 Lamps Retail Lamps Study 3.2: Lumen and Chromaticity Maintenance of LED A Lamps Operated in Steady-State Conditions February 2015 Postings

  11. CALiPER Retail Lamps Study 3.2: Lumen and Chromaticity Maintenance...

    Energy Savers [EERE]

    Retail Lamps Study 3.2: Lumen and Chromaticity Maintenance of LED A Lamps Operated in ... Especially given the rapid development cycle for LED products, specifiers and purchasers ...

  12. CALiPER Benchmark Report: Performance of Incandescent A Type and Decorative Lamps and LED Replacements

    SciTech Connect (OSTI)

    Lingard, R. D.; Myer, M. A.; Paget, M. L.

    2008-11-01

    This benchmark report addresses common omnidirectional incandescent lamps - A-type and small decorative, candelabra-type lamps - and their commercially available light-emitting diode (LED) replacements.

  13. Structurally Integrated Coatings for Wear and Corrosion (SICWC): Arc Lamp, InfraRed (IR) Thermal Processing

    SciTech Connect (OSTI)

    Mackiewicz-Ludtka, G.; Sebright, J.

    2007-12-15

    The primary goal of this Cooperative Research and Development Agreement (CRADA) betwe1311 UT-Battelle (Contractor) and Caterpillar Inc. (Participant) was to develop the plasma arc lamp (PAL), infrared (IR) thermal processing technology 1.) to enhance surface coating performance by improving the interfacial bond strength between selected coatings and substrates; and 2.) to extend this technology base for transitioning of the arc lamp processing to the industrial Participant. Completion of the following three key technical tasks (described below) was necessary in order to accomplish this goal. First, thermophysical property data sets were successfully determined for composite coatings applied to 1010 steel substrates, with a more limited data set successfully measured for free-standing coatings. These data are necessary for the computer modeling simulations and parametric studies to; A.) simulate PAL IR processing, facilitating the development of the initial processing parameters; and B.) help develop a better understanding of the basic PAL IR fusing process fundamentals, including predicting the influence of melt pool stirring and heat tnmsfar characteristics introduced during plasma arc lamp infrared (IR) processing; Second, a methodology and a set of procedures were successfully developed and the plasma arc lamp (PAL) power profiles were successfully mapped as a function of PAL power level for the ORNL PAL. The latter data also are necessary input for the computer model to accurately simulate PAL processing during process modeling simulations, and to facilitate a better understand of the fusing process fundamentals. Third, several computer modeling codes have been evaluated as to their capabilities and accuracy in being able to capture and simulate convective mixing that may occur during PAL thermal processing. The results from these evaluation efforts are summarized in this report. The intention of this project was to extend the technology base and provide for transitioning of the arc lamp processing to the industrial Participant.

  14. ARM - SGP Intermediate Facility

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Intermediate Facility SGP Related Links Virtual Tour Facilities and Instruments Central Facility Boundary Facility Extended Facility Intermediate Facility Radiometric Calibration Facility Geographic Information ES&H Guidance Statement Operations Science Field Campaigns Visiting the Site SGP Fact Sheet Images Information for Guest Scientists Contacts SGP Intermediate Facility For over 20 years, 3 intermediate facilities, within 6.2 miles (10 km) of the Central Facility, provided a

  15. Stress Testing of the Philips 60W Replacement Lamp L Prize Entry

    SciTech Connect (OSTI)

    Poplawski, Michael E.; Ledbetter, Marc R.; Smith, Mark

    2012-04-24

    The Pacific Northwest National Laboratory, operated by Battelle for the U.S. Department of Energy, worked with Intertek to develop a procedure for stress testing medium screw-base light sources. This procedure, composed of alternating stress cycles and performance evaluation, was used to qualitatively compare and contrast the durability and reliability of the Philips 60W replacement lamp L Prize entry with market-proven compact fluorescent lamps (CFLs) with comparable light output and functionality. The stress cycles applied simultaneous combinations of electrical, thermal, vibration, and humidity stresses of increasing magnitude. Performance evaluations measured relative illuminance, x chromaticity and y chromaticity shifts after each stress cycle. The Philips L Prize entry lamps appear to be appreciably more durable than the incumbent energy-efficient technology, as represented by the evaluated CFLs, and with respect to the applied stresses. Through the course of testing, all 15 CFL samples permanently ceased to function as a result of the applied stresses, while only 1 Philips L Prize entry lamp exhibited a failure, the nature of which was minor, non-destructive, and a consequence of a known (and resolved) subcontractor issue. Given that current CFL technology appears to be moderately mature and no Philips L Prize entry failures could be produced within the stress envelope causing 100 percent failure of the benchmark CFLs, it seems that, in this particular implementation, light-emitting diode (LED) technology would be much more durable in the field than current CFL technology. However, the Philips L Prize entry lamps used for testing were carefully designed and built for the competition, while the benchmark CFLs were mass produced for retail salea distinction that should be taken into consideration. Further reliability testing on final production samples would be necessary to judge the extent to which the results of this analysis apply to production versions of the Philips L Prize entry.

  16. DOE CALiPER Program, Report 21.2: Linear (T8) LED Lamp Performance in Five Types of Recessed Troffers

    SciTech Connect (OSTI)

    Miller, Naomi J.; Perrin, Tess E.; Royer, Michael P.; Wilkerson, Andrea M.; Beeson, Tracy A.

    2014-05-20

    Although lensed troffers are numerous, there are many other types of optical systems as well. This report looked at the performance of three linear (T8) LED lamps chosen primarily based on their luminous intensity distributions (narrow, medium, and wide beam angles) as well as a benchmark fluorescent lamp in five different troffer types. Also included are the results of a subjective evaluation. Results show that linear (T8) LED lamps can improve luminaire efficiency in K12-lensed and parabolic-louvered troffers, effect little change in volumetric and high-performance diffuse-lensed type luminaires, but reduce efficiency in recessed indirect troffers. These changes can be accompanied by visual appearance and visual comfort consequences, especially when LED lamps with clear lenses and narrow distributions are installed. Linear (T8) LED lamps with diffuse apertures exhibited wider beam angles, performed more similarly to fluorescent lamps, and received better ratings from observers. Guidance is provided on which luminaires are the best candidates for retrofitting with linear (T8) LED lamps.

  17. DOE Publishes New CALiPER Report on Retail Lamps

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy's CALiPER program has released a special report on LED lamps available through the retail marketplace and targeted toward general consumers. While previous reports in...

  18. One piece microwave container screens for electrodeless lamps

    DOE Patents [OSTI]

    Turner, Brian; Ury, Michael

    1998-01-01

    A microwave powered electrodeless lamp includes an improved screen unit having mesh and solid sections with an internal reflector to reflect light into a light-transmitting chamber defined in the lamp microwave cavity by the reflector and the mesh section. A discharge envelope of a bulb is disposed in the light-transmitting chamber. Light emitted from the envelope is prevented by the reflector from entering the cavity portion bounded by the solid section of the screen. Replacing mesh material by solid metal material as part of the screen unit significantly reduces leakage of microwave energy from the lamp. The solid section has multiple compliant fingers defined therein for engaging the periphery of a flange on the waveguide unit so that a hose clamp can easily secure the screen to the assembly. Screen units of this type having different mesh section configurations can be interchanged in the lamp assembly to produce different respective illumination patterns.

  19. Lamp method and apparatus using multiple reflections

    DOE Patents [OSTI]

    MacLennan, Donald A.; Turner, Brian P.

    2001-01-01

    An electrodeless microwave discharge lamp includes an envelope with a discharge forming fill disposed therein which emits light, the fill being capable of absorbing light at one wavelength and re-emitting the absorbed light at a different wavelength, the light emitted from the fill having a first spectral power distribution in the absence of reflection of light back into the fill, a source of microwave energy coupled to the fill to excite the fill and cause the fill to emit light, and a reflector disposed within the microwave cavity and configured to reflect at least some of the light emitted by the fill back into the fill while allowing some light to exit, the exiting light having a second spectral power distribution with proportionately more light in the visible region as compared to the first spectral power distribution, wherein the light re-emitted by the fill is shifted in wavelength with respect to the absorbed light and the magnitude of the shift is in relation to an effective optical path length.

  20. Caliper Retail Lamps Study 3.1: Dimming, Flicker, and Power Quality

    Energy Savers [EERE]

    Characteristics of LED A Lamps | Department of Energy Caliper Retail Lamps Study 3.1: Dimming, Flicker, and Power Quality Characteristics of LED A Lamps Caliper Retail Lamps Study 3.1: Dimming, Flicker, and Power Quality Characteristics of LED A Lamps PDF icon caliper_retail-study_3-1.pdf More Documents & Publications Report 22.1: Photoelectric Performance of LED MR16 Lamps Report 20.3: Stress Testing of LED PAR38 Lamps DOE Booth Presentations from LIGHTFAIR International 2015

  1. DOE Publishes Long-Term Testing Investigation of Retail Lamps | Department

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    of Energy Long-Term Testing Investigation of Retail Lamps DOE Publishes Long-Term Testing Investigation of Retail Lamps February 13, 2015 - 2:58pm Addthis The U.S. Department of Energy's CALiPER program has released another special report on LED lamps that are available through the retail marketplace and targeted toward general consumers. CALiPER Retail Lamps Study 3.2 focuses on lumen depreciation and color shift in a subset of 15 LED A lamps from CALiPER Retail Lamps Study 3. The lamps

  2. Magnetic fluorescent lamp having reduced ultraviolet self-absorption

    DOE Patents [OSTI]

    Berman, Samuel M. (San Francisco, CA); Richardson, Robert W. (Pelham, NY)

    1985-01-01

    The radiant emission of a mercury-argon discharge in a fluorescent lamp assembly (10) is enhanced by providing means (30) for establishing a magnetic field with lines of force along the path of electron flow through the bulb (12) of the lamp assembly, to provide Zeeman splitting of the ultraviolet spectral line. Optimum results are obtained when the magnetic field strength causes a Zeeman splitting of approximately 1.7 times the thermal line width.

  3. Defining the Effectiveness of UV Lamps Installed in Circulating Air

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Ductwork (Technical Report) | SciTech Connect Defining the Effectiveness of UV Lamps Installed in Circulating Air Ductwork Citation Details In-Document Search Title: Defining the Effectiveness of UV Lamps Installed in Circulating Air Ductwork × You are accessing a document from the Department of Energy's (DOE) SciTech Connect. This site is a product of DOE's Office of Scientific and Technical Information (OSTI) and is provided as a public service. Visit OSTI to utilize additional

  4. Intermediate future forecasting system

    SciTech Connect (OSTI)

    Gass, S.I.; Murphy, F.H.; Shaw, S.H.

    1983-12-01

    The purposes of the Symposium on the Department of Energy's Intermediate Future Forecasting System (IFFS) were: (1) to present to the energy community details of DOE's new energy market model IFFS; and (2) to have an open forum in which IFFS and its major elements could be reviewed and critiqued by external experts. DOE speakers discussed the total system, its software design, and the modeling aspects of oil and gas supply, refineries, electric utilities, coal, and the energy economy. Invited experts critiqued each of these topics and offered suggestions for modifications and improvement. This volume documents the proceedings (papers and discussion) of the Symposium. Separate abstracts have been prepared for each presentation for inclusion in the Energy Data Base.

  5. Simulation of quantum dots size and spacing effect for intermediate band solar cell application based on InAs quantum dots arrangement in GaAs

    SciTech Connect (OSTI)

    Hendra, P. I. B. Rahayu, F. Darma, Y.

    2014-03-24

    Intermediate band solar cell (IBSC) has become a promising technology in increasing solar cell efficiency. In this work we compare absorption coefficient profile between InAs quantum dots with GaAs bulk. We calculate the efficiency of GaAs bulk and GaAs doped with 2, 5, and 10 nm InAs quantum dot. Effective distances in quantum dot arrangement based on electron tunneling consideration were also calculated. We presented a simple calculation method with low computing power demand. Results showed that arrangement of quantum dot InAs in GaAs can increase solar cell efficiency from 23.9 % initially up to 60.4%. The effective distance between two quantum dots was found 2 nm in order to give adequate distance to prevent electron tunneling and wave functions overlap.

  6. LED Replacement Lamps: Current Performance and the Latest on ENERGY STAR®

    Energy Savers [EERE]

    | Department of Energy Replacement Lamps: Current Performance and the Latest on ENERGY STAR® LED Replacement Lamps: Current Performance and the Latest on ENERGY STAR® This May 19, 2009 webcast summarized CALiPER's recent benchmark testing of common omnidirectional incandescent lamps (e.g., A-lamps), and provided an update on ENERGY STAR criteria for LED integral replacement lamps - currently in its second draft. Robert Lingard of Pacific Northwest National Laboratory (PNNL) gave an

  7. CALiPER Benchmark Report: Performance of T12 and T8 Fluorescent Lamps and Troffers and LED Linear Replacement Lamps

    SciTech Connect (OSTI)

    Myer, M. A.; Paget, M. L.; Lingard, R. D.

    2009-01-01

    This report examines standard fluorescent lamps, the recessed troffers they are commonly used in, and available LED replacements for T12 and T8 fluorescent lamps and their application in fluorescent troffers.

  8. LED lamp or bulb with remote phosphor and diffuser configuration with enhanced scattering properties

    SciTech Connect (OSTI)

    Tong, Tao; Le Toquin, Ronan; Keller, Bernd; Tarsa, Eric; Youmans, Mark; Lowes, Theodore; Medendorp, Jr., Nicholas W; Van De Ven, Antony; Negley, Gerald

    2014-11-11

    An LED lamp or bulb is disclosed that comprises a light source, a heat sink structure and an optical cavity. The optical cavity comprises a phosphor carrier having a conversions material and arranged over an opening to the cavity. The phosphor carrier comprises a thermally conductive transparent material and is thermally coupled to the heat sink structure. An LED based light source is mounted in the optical cavity remote to the phosphor carrier with light from the light source passing through the phosphor carrier. A diffuser dome is included that is mounted over the optical cavity, with light from the optical cavity passing through the diffuser dome. The properties of the diffuser, such as geometry, scattering properties of the scattering layer, surface roughness or smoothness, and spatial distribution of the scattering layer properties may be used to control various lamp properties such as color uniformity and light intensity distribution as a function of viewing angle.

  9. Magical Mystery Devices or Not: How do LED Lamps and Luminaires Really Measure-Up?

    SciTech Connect (OSTI)

    Paget, Maria L.; McCullough, Jeffrey J.; Steward, Heidi E.

    2008-08-15

    Solid-state lighting products for general lighting applications are now gaining a market presence, and more and more people are asking, “Which of these are ‘good’ products? Do they perform as claimed? How do they compare? Light Emitting Diodes (LEDs) differ from other light sources enough to require new procedures for measuring their performance and comparing to other lighting options, so both manufacturers and buyers are facing a learning curve. The energy-efficiency community has traditionally compared light sources based on system efficacy: rated lamp lumens divided by power into the system. This doesn’t work for LEDs because there are no standard LED “lamp” packages and no lamp ratings, and because LED performance depends heavily on thermal, electrical, and optical design of complete lighting unit or ‘luminaire’. Luminaire efficacy is the preferred metric for LEDs because it measures the net light output from the luminaire divided by power into the system.

  10. Red phosphors for use in high CRI fluorescent lamps

    DOE Patents [OSTI]

    Srivastava, Alok; Comanzo, Holly; Manivannan, Vankatesan; Setlur, Anant Achyut

    2005-11-15

    Novel red emitting phosphors for use in fluorescent lamps resulting in superior color rendering index values compared to conventional red phosphors. Also disclosed is a fluorescent lamp including a phosphor layer comprising blends of one or more of a blue phosphor, a blue-green phosphor, a green phosphor and a red a phosphor selected from the group consisting of SrY.sub.2 O.sub.4 :Eu.sup.3+, (Y,Gd)Al.sub.3 B.sub.4 O.sub.12 :Eu.sup.3+, and [(Y.sub.1-x-y-m La.sub.y)Gd.sub.x ]BO.sub.3 :Eu.sub.m wherein y<0.50 and m=0.001-0.3. The phosphor layer can optionally include an additional deep red phosphor and a yellow emitting phosphor. The resulting lamp will exhibit a white light having a color rendering index of 90 or higher with a correlated color temperature of from 2500 to 10000 Kelvin. The use of the disclosed red phosphors in phosphor blends of lamps results in high CRI light sources with increased stability and acceptable lumen maintenance over the course of the lamp life.

  11. Very high efficacy electrodeless high intensity discharge lamps

    DOE Patents [OSTI]

    Johnson, P.D.

    1985-10-03

    An electrodeless arc lamp comprises an outer jacket hermetically sealing and thermally protecting an arc tube inside which has an upwardly convex bottom center section. The absence of chemically reactive electrode material makes it possible to use metal halides other than iodides. The tube contains chlorides, bromides or a mixture thereof of scandium and sodium in a nearly equimolar relationship in addition to mercury and an inert gas. Good color balance can be obtained at reduced reservoir temperature and with less power loss. Reduction in wall temperature makes it possible to attain longer lamp life.

  12. DOE Publishes CALiPER Report on LED T8 Lamps

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy's CALiPER program has released an Application Summary Report that focuses on the bare-lamp performance of 31 linear LED lamps intended as an alternative to T8...

  13. DOE Publishes CALiPER Snapshot Report on LED MR16 Lamps | Department...

    Energy Savers [EERE]

    Snapshot Report on LED MR16 Lamps DOE Publishes CALiPER Snapshot Report on LED MR16 Lamps March 5, 2014 - 4:23pm Addthis The U.S. Department of Energy's CALiPER program has ...

  14. Report 20.5: Chromaticity Shift Modes of LED PAR38 Lamps Operated...

    Energy Savers [EERE]

    5: Chromaticity Shift Modes of LED PAR38 Lamps Operated in Steady-State Conditions Report 20.5: Chromaticity Shift Modes of LED PAR38 Lamps Operated in Steady-State Conditions PDF ...

  15. Report 20.4: Lumen and Chromaticity Maintenance of LED PAR38 Lamps |

    Energy Savers [EERE]

    Department of Energy 4: Lumen and Chromaticity Maintenance of LED PAR38 Lamps Report 20.4: Lumen and Chromaticity Maintenance of LED PAR38 Lamps PDF icon Report 20.4: Lumen and Chromaticity Maintenance

  16. Demonstration of LED Retrofit Lamps at the Smithsonian Art Museum, Washington, DC

    SciTech Connect (OSTI)

    Miller, N. J.; Rosenfeld, S. M.

    2012-06-01

    GATEWAY program report on a demonstration of LED retrofit lamps at the Smithsonian American Art Museum in Washington, DC.

  17. DOE Publishes CALiPER Report on Cost-Effectiveness of Linear (T8) LED Lamps

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy's CALiPER program has released Report 21.3, which is part of a series of investigations on linear LED lamps. Report 21.3 details a set of life-cycle cost simulations that compared a two-lamp troffer using LED lamps (38W total power draw) or fluorescent lamps (51W total power draw) over a 10-year study period.

  18. CALiPER Benchmark Report: Performance of Halogen Incandescent MR16 Lamps and LED Replacement

    SciTech Connect (OSTI)

    Paget, M. L.; Lingard, R. D.; Myer, M. A.

    2008-11-01

    This benchmark report addresses the halogen MR16 lamp and its commercially available light-emitting diode (LED) replacements.

  19. CALiPER Special Summary Report: Retail Replacement Lamp Testing

    SciTech Connect (OSTI)

    2011-04-01

    CALiPER testing has evaluated many products for commercial lighting markets and found some excellent performers. However, many of these are not available on the retail market. This special testing was undertaken to identify and test solid-state lighting (SSL) replacement lamp products that are available to the general public through retail stores and websites.

  20. CALiPER Exploratory Study Retail Replacement Lamps – 2011

    SciTech Connect (OSTI)

    2012-04-02

    In 2010, CALiPER conducted a study on LED replacement lamps found in retail stores. The results were less than satisfactory, and many products were classified as being unlikely to meet consumer expectations. In November 2011, CALiPER purchased a new sample of products for a follow-up study, with the intent of characterizing the progress of this essential market segment.

  1. Thermal element for maintaining minimum lamp wall temperature in fluorescent fixtures

    DOE Patents [OSTI]

    Siminovitch, Michael J.

    1992-01-01

    In a lighting fixture including a lamp and a housing, an improvement is disclosed for maintaining a lamp envelope area at a cooler, reduced temperature relative to the enclosed housing ambient. The improvement comprises a thermal element in thermal communication with the housing extending to and springably urging thermal communication with a predetermined area of the lamp envelope surface.

  2. Thermal element for maintaining minimum lamp wall temperature in fluorescent fixtures

    DOE Patents [OSTI]

    Siminovitch, M.J.

    1992-11-10

    In a lighting fixture including a lamp and a housing, an improvement is disclosed for maintaining a lamp envelope area at a cooler, reduced temperature relative to the enclosed housing ambient. The improvement comprises a thermal element in thermal communication with the housing extending to and springably urging thermal communication with a predetermined area of the lamp envelope surface. 12 figs.

  3. CALiPER Retail Lamps Study 3.2: Lumen and Chromaticity Maintenance of LED A Lamps Operated in Steady-State Conditions

    SciTech Connect (OSTI)

    none,

    2014-12-31

    This CALiPER report examines lumen depreciation and color shift of 17 different A lamps in steady-state conditions (15 LED, 1 CFL, 1 halogen). The goal of this investigation was to examine the long-term performance of complete LED lamps relative to benchmark halogen and CFL lamps—in this case, A lamps emitting approximately 800 lumens operated continuously at a relatively high ambient temperature of 45°C.

  4. Report 20.5: Chromaticity Shift Modes of LED PAR38 Lamps Operated in

    Energy Savers [EERE]

    Steady-State Conditions | Department of Energy 5: Chromaticity Shift Modes of LED PAR38 Lamps Operated in Steady-State Conditions Report 20.5: Chromaticity Shift Modes of LED PAR38 Lamps Operated in Steady-State Conditions PDF icon Report 20.5: Chromaticity Shift Modes of LED PAR38 Lamps Operated in Steady-State Conditions More Documents & Publications Report 20.4: Lumen and Chromaticity Maintenance of LED PAR38 Lamps Retail Lamps Study 3.2: Lumen and Chromaticity Maintenance of LED A

  5. ISSUANCE 2015-12-02: Energy Conservation Program: Energy Conservation Standards for High-Intensity Discharge Lamps, Final Determination

    Broader source: Energy.gov [DOE]

    Energy Conservation Program: Energy Conservation Standards for High-Intensity Discharge Lamps, Final Determination

  6. ISSUANCE 2014-12-29: Energy Conservation Program: Clarification for Energy Conservation Standards and Test Procedures for Fluorescent Lamp Ballasts

    Broader source: Energy.gov [DOE]

    Energy Conservation Program: Clarification for Energy Conservation Standards and Test Procedures for Fluorescent Lamp Ballasts

  7. ISSUANCE 2016-03-24: Energy Conservation Program: Clarification of Test Procedures for Fluorescent Lamps Ballasts, Final Rule

    Broader source: Energy.gov [DOE]

    Energy Conservation Program: Clarification of Test Procedures for Fluorescent Lamps Ballasts, Final Rule

  8. Intermediate Energy Infobook and Intermediate Infobook Activities...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    school, save energy and reduce costs Collection of science-based, climate education resources and programs, aligned to national science education standards. Find info on the...

  9. 2014-04-11 Issuance: Energy Conservation Standards for General Service Fluorescent Lamps and Incandescent Reflector Lamps; Notice of Proposed Rulemaking

    Broader source: Energy.gov [DOE]

    This document is a pre-publication Federal Register notice of proposed rulemaking regarding energy conservation standards for general service fluorescent lamps and incandescent reflectors lamps, as issued by the Assistant Secretary for Energy Efficiency and Renewable Energy on April 11, 2014.

  10. Low pressure arc discharge lamp apparatus with magnetic field generating means

    DOE Patents [OSTI]

    Grossman, M.W.; George, W.A.; Maya, J.

    1987-10-06

    A low-pressure arc discharge apparatus having a magnetic field generating means for increasing the output of a discharge lamp is disclosed. The magnetic field generating means, which in one embodiment includes a plurality of permanent magnets, is disposed along the lamp for applying a constant transverse magnetic field over at least a portion of the positive discharge column produced in the arc discharge lamp operating at an ambient temperature greater than about 25 C. 3 figs.

  11. 2014-10-14 Issuance: Test Procedures Correction for Fluorescent Lamp

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Ballasts; Notice of Proposed Rulemaking | Department of Energy 4 Issuance: Test Procedures Correction for Fluorescent Lamp Ballasts; Notice of Proposed Rulemaking 2014-10-14 Issuance: Test Procedures Correction for Fluorescent Lamp Ballasts; Notice of Proposed Rulemaking This document is a pre-publication Federal Register notice of proposed rulemaking regarding test procedures for fluorescent lamp ballasts, as issued by the Deputy Assistant Secretary for Energy Efficiency on October 14,

  12. Lumen and Chromaticity Maintenance of LED PAR38 Lamps Operated in Steady-State Conditions

    SciTech Connect (OSTI)

    Royer, Michael P.

    2014-12-01

    The lumen depreciation and color shift of 38 different lamps (32 LED, 2 CFL, 1 ceramic metal halide [CMH], 3 halogen) were monitored in a specially developed automated long-term test apparatus (ALTA2) for nearly 14,000 hours. Five samples of each lamp model were tested, with measurements recorded on a weekly basis. The lamps were operated continuously at a target ambient temperature between 44°C and 45°C.

  13. Low pressure arc discharge lamp apparatus with magnetic field generating means

    DOE Patents [OSTI]

    Grossman, Mark W. (Belmont, MA); George, William A. (Rockport, MA); Maya, Jakob (Brookline, MA)

    1987-01-01

    A low-pressure arc discharge apparatus having a magnetic field generating means for increasing the output of a discharge lamp is disclosed. The magnetic field generating means, which in one embodiment includes a plurality of permanent magnets, is disposed along the lamp for applying a constant transverse magnetic field over at least a portion of the positive discharge column produced in the arc discharge lamp operating at an ambient temperature greater than about 25.degree. C.

  14. Text-Alternative Version: CALiPER Series 21 on LED Linear Lamps and Troffer

    Energy Savers [EERE]

    Lighting | Department of Energy Information Resources » Videos » Text-Alternative Version: CALiPER Series 21 on LED Linear Lamps and Troffer Lighting Text-Alternative Version: CALiPER Series 21 on LED Linear Lamps and Troffer Lighting Following is a text version of a video about CALiPER Application Report Series 21 on LED Linear Lamps and Troffer Lighting. Tracy Beeson, Lighting Engineer, Pacific Northwest National Laboratory: Fluorescent troffers are widely used in office spaces, meeting

  15. Conservation potential of compact fluorescent lamps in India and Brazil

    SciTech Connect (OSTI)

    Gadgil, A.; Martino Jannuzzi, G. de (Lawrence Berkeley Lab., CA (USA); Universidade Estadual de Campinas, SP (Brazil). Faculdade de Engenharia)

    1989-07-01

    We evaluate the conservation potential of compact fluorescent lamps (CFLs) for managing the rapidly increasing electrical energy and peak demand in India and Brazil. Using very conservative assumptions, we find that the cost of conserved energy using 16 W CFLs is 4 and 6 times less than the long range marginal cost of electricity for the two countries. The cost of avoided peak installed capacity is 6 and 9.5 times less than the cost of new installed capacity for India and Brazil. The analysis is undertaken from the three separate perspectives of the national economies, the consumers, and the utilities. We find that because residential electricity is subsidized, the consumers have little or no incentive to purchase and install the CFLs, unless they too are subsidized. However, the benefits of CFL installation to the utility are so large that subsidizing them is a paying proposition for the utility are so large that subsidizing them is a paying proposition for the utility in almost all cases. As an illustration of a gradual introduction strategy for CFLs, we calculate a scenario where national savings of the order of US $1.2 million per day for India and US $2.5 million per day for Brazil are reached in 10 years by a small and gradual transfer of subsidy from residential electricity to CFLs. We then explore the barriers to immediate large scale introduction of these lamps in the two countries. Specific technical and marketing problems are identified and discussed, which would require solution before such an introduction can be attempted. Lastly, we discuss the range of policy instruments, in addition to a subsidy scheme, that can be used for promoting the diffusion of these lamps in the domestic and commercial sector. 47 refs., 15 figs., 2 tabs.

  16. EA-1881: Energy Conservation Program: Energy Conservation Standards for Fluorescent Lamp Ballasts

    Office of Energy Efficiency and Renewable Energy (EERE)

    This EA evaluates the environmental impacts of a proposal to amend energy conservation standards for various consumer products and certain commercial and industrial equipment, including fluorescent lamp ballasts.

  17. DOE Publishes Special CALiPER Report on Retail Lamps | Department...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    The report follows similar reports published in 2011 and 2012. LED replacement lamps are available through many retail outlets, and CALiPER testing offers insights on performance ...

  18. Demonstration of LED Retrofit Lamps at the Smithsonian American Art Museum, Washington, DC

    SciTech Connect (OSTI)

    Miller, Naomi J.; Rosenfeld, Scott M.

    2012-06-22

    This report documents observations and results obtained from a lighting demonstration project conducted under the U.S. Department of Energy GATEWAY Solid-State Lighting (SSL) Technology Demonstration Program at the Smithsonain American Art Museum in Washington, DC. LED Lamp samples were tested in the museum workshop, temporarily installed in a gallery for feedback, and ultimately replaced all traditional incandescent lamps in one gallery of modernist art at the American Art Museum and partially replacing lamps in two galleries at the Musesum's Renwick Gallery. This report describes the selection and testing process, technology challenges, perceptions, economics, energy use, and mixed results of usign LED replacement lamps in art galleries housing national treasures.

  19. Text-Alternative Version: LED Replacement Lamps: Current Performance and the Latest on ENERGY STAR®

    Broader source: Energy.gov [DOE]

    Below is the text-alternative version of the LED Replacement Lamps: Current Performance and the Latest on ENERGY STAR® webcast.

  20. EA-1911: Energy Conservation Standards for Certain Reflector, Elliptical Reflector, and Bulged Reflector Incandescent Lamps

    Broader source: Energy.gov [DOE]

    This EA will evaluate the environmental impacts of a proposal to amend energy conservation standards for Certain Reflector, Elliptical Reflector, and Bulged Reflector Incandescent Lamps.

  1. Max Tech and Beyond: High-Intensity Discharge Lamps (Technical Report) |

    Office of Scientific and Technical Information (OSTI)

    SciTech Connect High-Intensity Discharge Lamps Citation Details In-Document Search Title: Max Tech and Beyond: High-Intensity Discharge Lamps High-intensity discharge (HID) lamps are most often found in industrial and commercial applications, and are the light source of choice in street and area lighting, and sports stadium illumination. HID lamps are produced in three types - mercury vapor (MV), high pressure sodium (HPS) and metal halide (MH). Of these, MV and MH are considered white-light

  2. DOE Publishes Special CALiPER Report on Retail Lamps | Department of Energy

    Energy Savers [EERE]

    Publishes Special CALiPER Report on Retail Lamps DOE Publishes Special CALiPER Report on Retail Lamps March 4, 2014 - 12:00am Addthis The U.S. Department of Energy's CALiPER program has released a special report on LED lamps available through the retail marketplace and targeted toward general consumers. The report follows similar reports published in 2011 and 2012. LED replacement lamps are available through many retail outlets, and CALiPER testing offers insights on performance trends from year

  3. LED Linear Lamps and Troffer Lighting: CALiPER Report Series 21

    SciTech Connect (OSTI)

    Beeson, Tracy; Miller, Naomi

    2014-06-17

    Video about CALiPER Report Series 21 on LED Linear Lamps and Troffer Lighting, featuring interviews with Tracy Beeson and Naomi Miller of Pacific Northwest National Laboratory.

  4. LED Linear Lamps and Troffer Lighting: CALiPER Report Series 21

    ScienceCinema (OSTI)

    Beeson, Tracy; Miller, Naomi

    2014-06-23

    Video about CALiPER Report Series 21 on LED Linear Lamps and Troffer Lighting, featuring interviews with Tracy Beeson and Naomi Miller of Pacific Northwest National Laboratory.

  5. Microwave lamp with multi-purpose rotary motor

    DOE Patents [OSTI]

    Ury, M.G.; Turner, B.; Wooten, R.D.

    1999-02-02

    In a microwave powered electrodeless lamp, a single rotary motor is used to (a) rotate the bulb and (b) provide rotary motion to a blower or pump means for providing cooling fluid to the magnetron and/or to a forced gas cooler for providing cooling gas to the bulb. The blower may consist of only of an impeller without the usual blower housing. The motor, bulb stem and bulb, or motor, bulb stem, bulb and blower may be formed as an integral unit so as to facilitate replacement. 8 figs.

  6. Microwave lamp with multi-purpose rotary motor

    DOE Patents [OSTI]

    Ury, Michael G.; Turner, Brian; Wooten, Robert D.

    1999-01-01

    In a microwave powered electrodeless lamp, a single rotary motor is used to a) rotate the bulb and b) provide rotary motion to a blower or pump means for providing cooling fluid to the magnetron and/or to a forced gas cooling for providing cooler gas to the bulb. The blower may consist of only of an impeller without the usual blower housing. The motor, bulb stem and bulb, or motor, bulb stem, bulb and blower may be formed as an integral unit so as to facilitate replacement.

  7. CALiPER Retail Lamps Study RRL3.2 Lumen and Chromaticity Maintenance of LED A lamps Operated in Steady-State Conditions

    SciTech Connect (OSTI)

    Royer, Michael P.; McCullough, Jeffrey J.; Tucker, Joseph C.

    2014-12-01

    The lumen depreciation and color shift of 17 different A lamps (15 LED, 1 CFL, 1 halogen) was monitored in the automated long-term test apparatus (ALTA) for more than 7,500 hours. Ten samples of each lamp model were tested, with measurements recorded on a weekly basis. The lamps were operated continuously at an ambient temperature of 45°C (-1°C). Importantly, the steady-state test conditions were not optimized for inducing catastrophic failure for any of the lamp technologies—to which thermal cycling is a strong contributor— and are not typical of normal use patterns—which usually include off periods where the lamp cools down. Further, the test conditions differ from those used in standardized long-term test methods (i.e., IES LM-80, IES LM-84), so the results should not be directly compared. On the other hand, the test conditions are similar to those used by ENERGY STAR (when elevated temperature testing is called for). Likewise, the conditions and assumptions used by manufacturers to generated lifetime claims may vary; the CALiPER long-term data is informative, but cannot necessarily be used to discredit manufacturer claims. The test method used for this investigation should be interpreted as one more focused on the long-term effects of elevated temperature operation, at an ambient temperature that is not uncommon in luminaires. On average, the lumen maintenance of the LED lamps monitored in the ALTA was better than benchmark lamps, but there was considerable variation from lamp model to lamp model. While three lamp models had average lumen maintenance above 99% at the end of the study period, two products had average lumen maintenance below 65%, constituting a parametric failure. These two products, along with a third, also exhibited substantial color shift, another form of parametric failure. While none of the LED lamps exhibited catastrophic failure—and all of the benchmarks did—the early degradation of performance is concerning, especially with a new technology trying to build a reputation with consumers. Beyond the observed parametric failures nearly half of the products failed to meet early-life thresholds for lumen maintenance, which were borrowed from ENERGY STAR specifications. That is, the lumen maintenance was sufficiently low at 6,000 hours that seven of the products are unlikely to have lumen maintenance above 70% at their rated lifetime (which was usually 25,000 hours). Given the methods used for this investigation—most notably continuous operation—the results should not be interpreted as indicative of a lamp’s performance in a typical environment. Likewise, these results are not directly relatable to manufacturer lifetime claims. This report is best used to understand the variation in LED product performance, compare the robustness of LED lamps and benchmark conventional lamps, and understand the characteristics of lumen and chromaticity change. A key takeaway is that the long-term performance of LED lamps can vary greatly from model to model (i.e., the technology is not homogenous), although the lamp-to-lamp consistency within a given model is relatively good. Further, operation of LED lamps in an enclosed luminaire (or otherwise in high ambient temperatures), can induce parametric failure of LEDs much earlier than their rated lifetime; manufacturer warnings about such conditions should be followed if performance degradation is unacceptable.

  8. Kondo universality, energy scales, and intermediate valence in plutonium

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | SciTech Connect Journal Article: Kondo universality, energy scales, and intermediate valence in plutonium Citation Details In-Document Search Title: Kondo universality, energy scales, and intermediate valence in plutonium On the basis of the concepts of an intermediate-valence (IV) regime, an analysis is carried out of macroscopic properties of the {alpha} and {delta} phases of plutonium, as well as of several model systems based on rare earth elements. Within a

  9. The evolving price of household LED lamps: Recent trends and historical comparisons for the US market

    SciTech Connect (OSTI)

    Gerke, Brian F.; Ngo, Allison T.; Alstone, Andrea L.; Fisseha, Kibret S.

    2014-10-14

    In recent years, household LED light bulbs (LED A lamps) have undergone a dramatic price decline. Since late 2011, we have been collecting data, on a weekly basis, for retail offerings of LED A lamps on the Internet. The resulting data set allows us to track the recent price decline in detail. LED A lamp prices declined roughly exponentially with time in 2011-2014, with decline rates of 28percent to 44percent per year depending on lumen output, and with higher-lumen lamps exhibiting more rapid price declines. By combining the Internet price data with publicly available lamp shipments indices for the US market, it is also possible to correlate LED A lamp prices against cumulative production, yielding an experience curve for LED A lamps. In 2012-2013, LED A lamp prices declined by 20-25percent for each doubling in cumulative shipments. Similar analysis of historical data for other lighting technologies reveals that LED prices have fallen significantly more rapidly with cumulative production than did their technological predecessors, which exhibited a historical decline of 14-15percent per doubling of production.

  10. Spectral irradiance model for tungsten halogen lamps in 340-850 nm wavelength range

    SciTech Connect (OSTI)

    Ojanen, Maija; Kaerhae, Petri; Ikonen, Erkki

    2010-02-10

    We have developed a physical model for the spectral irradiance of 1 kW tungsten halogen incandescent lamps for the wavelength range 340-850 nm. The model consists of the Planck's radiation law, published values for the emissivity of tungsten, and a residual spectral correction function taking into account unknown factors of the lamp. The correction function was determined by measuring the spectra of a 1000 W, quartz-halogen, tungsten coiled filament (FEL) lamp at different temperatures. The new model was tested with lamps of types FEL and 1000 W, 120 V quartz halogen (DXW). Comparisons with measurements of two national standards laboratories indicate that the model can account for the spectral irradiance values of lamps with an agreement better than 1% throughout the spectral region studied. We further demonstrate that the spectral irradiance of a lamp can be predicted with an expanded uncertainty of 2.6% if the color temperature and illuminance values for the lamp are known with expanded uncertainties of 20 K and 2%, respectively. In addition, it is suggested that the spectral irradiance may be derived from resistance measurements of the filament with lamp on and off.

  11. Table lamp with dynamically controlled lighting distribution and uniformly illuminated luminous shade

    DOE Patents [OSTI]

    Siminovitch, Michael J.; Page, Erik R.

    2002-01-01

    A double lamp table or floor lamp lighting system has a pair of compact fluorescent lamps (CFLs) or other lamps arranged vertically, i.e. one lamp above the other, with a reflective septum in between. By selectively turning on one or both of the CFLs, down lighting, up lighting, or both up and down lighting is produced. The control system can also vary the light intensity from each CFL. The reflective septum ensures that almost all the light produced by each lamp will be directed into the desired light distribution pattern which is selected and easily changed by the user. In a particular configuration, the reflective septum is bowl shaped, with the upper CFL sitting in the bowl, and a luminous shade hanging down from the bowl. The lower CFL provides both task lighting and uniform shade luminance. Planar compact fluorescent lamps, e.g. circular CFLs, particularly oriented horizontally, are preferable. CFLs provide energy efficiency. However, other types of lamps, including incandescent, halogen, and LEDs can also be used in the fixture. The lighting system may be designed for the home, hospitality, office or other environments.

  12. CALiPER Report 20.3: Robustness of LED PAR38 Lamps

    SciTech Connect (OSTI)

    Poplawski, Michael E.; Royer, Michael P.; Brown, Charles C.

    2014-12-31

    Three samples of 40 of the Series 20 PAR38 lamps underwent multi-stress testing, whereby samples were subjected to increasing levels of simultaneous thermal, humidity, electrical, and vibrational stress. The results do not explicitly predict expected lifetime or reliability, but they can be compared with one another, as well as with benchmark conventional products, to assess the relative robustness of the product designs. On average, the 32 LED lamp models tested were substantially more robust than the conventional benchmark lamps. As with other performance attributes, however, there was great variability in the robustness and design maturity of the LED lamps. Several LED lamp samples failed within the first one or two levels of the ten-level stress plan, while all three samples of some lamp models completed all ten levels. One potential area of improvement is design maturity, given that more than 25% of the lamp models demonstrated a difference in failure level for the three samples that was greater than or equal to the maximum for the benchmarks. At the same time, the fact that nearly 75% of the lamp models exhibited better design maturity than the benchmarks is noteworthy, given the relative stage of development for the technology.

  13. CALiPER Application Summary Report 21. Linear (T8) LED Lamps

    SciTech Connect (OSTI)

    2014-03-01

    This report focuses on the bare lamp performance of 31 linear LED lamps intended as an alternative to T8 fluorescent lamps. Data obtained in accordance with IES LM-79-08 indicated that the mean efficacy is similar to that of fluorescent lamps, but that lumen output is often much lower. This presents a situation where something must change in order for energy savings and equivalent illumination levels to be achieved simultaneously. In this case, the luminous intensity distribution of all the tested lamps was directional or semi-directional, rather than omnidirectional. Also discussed in this report are several issues related to the electrical configuration of the lamps, such as the required socket types and power feed location. While no configuration is necessarily better, the multitude of options can make specifying and installing linear LED lamps more difficult, with the potential for safety issues. Similarly, the variety of color and power quality attributes adds a layer of complexity to the specification process. Many products offered good or excellent quality attributes, but some did not and thus could be perceived as inferior to fluorescent lamps in some installations.

  14. CALiPER Application Summary Report 17. LED AR111 and PAR36 Lamps

    SciTech Connect (OSTI)

    none,

    2012-08-01

    Report 17 analyzes the performance of a group of six LED products labeled as AR111 lamps. Results indicate that this product category lags behind other types of directional LED lamps but may perform acceptably in some applications and provide some energy savings.

  15. A Radiative Transport Model for Heating Paints using High Density Plasma Arc Lamps

    SciTech Connect (OSTI)

    Sabau, Adrian S; Duty, Chad E; Dinwiddie, Ralph Barton; Nichols, Mark; Blue, Craig A; Ott, Ronald D

    2009-01-01

    The energy distribution and ensuing temperature evolution within paint-like systems under the influence of infrared radiation was studied. Thermal radiation effects as well as those due to heat conduction were considered. A complete set of material properties was derived and discussed. Infrared measurements were conducted to obtain experimental data for the temperature in the paint film. The heat flux of the incident radiation from the plasma arc lamp was measured using a heat flux sensor with a very short response time. The comparison between the computed and experimental results for temperature show that the models that are based on spectral four-flux RTE and accurate optical properties yield accurate results for the black paint systems.

  16. The Molecular Architecture for the Intermediate Filaments of Hard α -Keratin Based on the Superlattice Data Obtained from a Study of Mammals Using Synchrotron Fibre Diffraction

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    James, Veronica

    2011-01-01

    High- and low-angle X-ray diffraction studies of hard α -keratin have been studied, and various models have been proposed over the last 70 years. Most of these studies have been confined to one or two forms of alpha keratin. This high- and low-angle synchrotron fibre diffraction study extends the study to cover all available data for all known forms of hard α -keratin including hairs, fingernails, hooves, horn, and quills from mammals, marsupials, and a monotreme, and it confirms that the model proposed is universally acceptable for all mammals. A complete Bragg analysis of the meridional diffraction patterns, includingmore » multiple-time exposures to verify any weak reflections, verified the existence of a superlattice consisting of two infinite lattices and three finite lattices. An analysis of the equatorial patterns establishes the radii of the oligomeric levels of dimers, tetramers, and intermediate filaments (IFs) together with the centre to centre distance for the IFs, thus confirming the proposed helices within helices molecular architecture for hard α -keratin. The results verify that the structure proposed by Feughelman and James meets the criteria for a valid α -keratin structure.« less

  17. A light diet for a giant appetite: An assessment of China's proposed fluorescent lamp standard

    SciTech Connect (OSTI)

    Lin, Jiang

    2002-04-11

    Lighting has been one of the fastest growing electric end-uses in China over the last twenty years, with an average annual growth rate of 14%. Fluorescent lighting provides a significant portion of China's lighting need. In 1998, China produced 680 million fluorescent lamps, of which 420 million were linear fluorescent lamps of various diameters (T8 to T12). There are substantial variations both in energy efficiency and lighting performance among locally produced fluorescent lamps. Such variations present a perfect opportunity for policy intervention through efficiency standards to promote the adoption of more efficient fluorescent lamps in China. This paper analyzes China's proposed minimum efficiency standard for fluorescent lamps and presents an assessment of its likely impacts on China's lighting energy consumption and GHG emissions.

  18. Energy Conservation Program: Data Collection and Comparison with Forecasted Unit Sales for Five Lamp Types, Notice of Data Availability

    Broader source: Energy.gov [DOE]

    Energy Conservation Program: Data Collection and Comparison with Forecasted Unit Sales for Five Lamp Types, Notice of Data Availability

  19. CALiPER Report 21.3: Cost-Effectiveness of Linear (T8) LED Lamps

    SciTech Connect (OSTI)

    Miller, Naomi J.; Perrin, Tess E.; Royer, Michael P.

    2014-05-27

    Meeting performance expectations is important for driving adoption of linear LED lamps, but cost-effectiveness may be an overriding factor in many cases. Linear LED lamps cost more initially than fluorescent lamps, but energy and maintenance savings may mean that the life-cycle cost is lower. This report details a series of life-cycle cost simulations that compared a two-lamp troffer using LED lamps (38 W total power draw) or fluorescent lamps (51 W total power draw) over a 10-year study period. Variables included LED system cost ($40, $80, or $120), annual operating hours (2,000 hours or 4,000 hours), LED installation time (15 minutes or 30 minutes), and melded electricity rate ($0.06/kWh, $0.12/kWh, $0.18/kWh, or $0.24/kWh). A full factorial of simulations allows users to interpolate between these values to aid in making rough estimates of economic feasibility for their own projects. In general, while their initial cost premium remains high, linear LED lamps are more likely to be cost-effective when electric utility rates are higher than average and hours of operation are long, and if their installation time is shorter.

  20. CALiPER Report 21.3. Cost Effectiveness of Linear (T8) LED Lamps

    SciTech Connect (OSTI)

    2014-05-01

    Meeting performance expectations is important for driving adoption of linear LED lamps, but cost-effectiveness may be an overriding factor in many cases. Linear LED lamps cost more initially than fluorescent lamps, but energy and maintenance savings may mean that the life-cycle cost is lower. This report details a series of life-cycle cost simulations that compared a two-lamp troffer using LED lamps (38 W total power draw) or fluorescent lamps (51 W total power draw) over a 10-year study period. Variables included LED system cost ($40, $80, or $120), annual operating hours (2,000 hours or 4,000 hours), LED installation time (15 minutes or 30 minutes), and melded electricity rate ($0.06/kWh, $0.12/kWh, $0.18/kWh, or $0.24/kWh). A full factorial of simulations allows users to interpolate between these values to aid in making rough estimates of economic feasibility for their own projects. In general, while their initial cost premium remains high, linear LED lamps are more likely to be cost-effective when electric utility rates are higher than average and hours of operation are long, and if their installation time is shorter.

  1. DOE Publishes CALiPER Report on Linear (T8) LED Lamps in a 2x4 K12-Lensed

    Energy Savers [EERE]

    Troffer | Department of Energy Linear (T8) LED Lamps in a 2x4 K12-Lensed Troffer DOE Publishes CALiPER Report on Linear (T8) LED Lamps in a 2x4 K12-Lensed Troffer May 2, 2014 - 4:48pm Addthis The U.S. Department of Energy's CALiPER program has released Report 21.1, which is part of a series of investigations on linear LED lamps. Report 21.1 focuses on the performance of 31 types of linear LED lamps operated in a typical 2x4 troffer with a K12 prismatic lens. The lamps were intended as

  2. CALiPER Report 21.1. Linear (T8) Lamps in a 2x4 K12-Lensed Troffer

    SciTech Connect (OSTI)

    2014-04-01

    This report focuses on the performance of the same 31 linear LED lamps operated in a typical troffer with a K12 prismatic lens. In general, luminaire efficacy is strongly dictated by lamp efficacy, but the optical system of the luminaire substantially reduces the differences between the luminous intensity distributions of the lamps. While the distributions in the luminaire are similar, the differences remain large enough that workplane illuminance uniformity may be reduced if linear LED lamps with a narrow distribution are used. At the same time, linear LED lamps with a narrower distribution result in slightly higher luminaire efficiency.

  3. Lamp system with conditioned water coolant and diffuse reflector of polytetrafluorethylene(PTFE)

    DOE Patents [OSTI]

    Zapata, Luis E. (Livermore, CA); Hackel, Lloyd (Livermore, CA)

    1999-01-01

    A lamp system with a very soft high-intensity output is provided over a large area by water cooling a long-arc lamp inside a diffuse reflector of polytetrafluorethylene (PTFE) and titanium dioxide (TiO.sub.2) white pigment. The water is kept clean and pure by a one micron particulate filter and an activated charcoal/ultraviolet irradiation system that circulates and de-ionizes and biologically sterilizes the coolant water at all times, even when the long-arc lamp is off.

  4. LED Linear Lamps and Troffer Lighting: CALiPER Report Series 21 |

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Department of Energy Videos » LED Linear Lamps and Troffer Lighting: CALiPER Report Series 21 LED Linear Lamps and Troffer Lighting: CALiPER Report Series 21 View the video about CALiPER Report Series 21 on LED Linear Lamps and Troffer Lighting, featuring interviews with Tracy Beeson and Naomi Miller of Pacific Northwest National Laboratory. View the text-alternative version. Solid-State Lighting Home About the Solid-State Lighting Program Research & Development SSL Basics Using LEDs

  5. CALiPER Publishes New Snapshot on MR16 Lamps | Department of Energy

    Energy Savers [EERE]

    CALiPER Publishes New Snapshot on MR16 Lamps CALiPER Publishes New Snapshot on MR16 Lamps February 9, 2016 - 3:34pm Addthis DOE's CALiPER program has published a new Snapshot Report on LED MR16 lamps, which updates a similar Snapshot Report published in January 2014. In the past two years, LED technology has progressed rapidly, but the progress has been much slower for LED MR16s. The increase in mean efficacy is about half of that seen for other categories, and lumen output and center beam

  6. ISSUANCE 2015-01-26: Energy Conservation Program: Energy Conservation Standards for High-Intensity Lamps, Notice to Reopen Comment Period

    Office of Energy Efficiency and Renewable Energy (EERE)

    Energy Conservation Program: Energy Conservation Standards for High-Intensity Lamps, Notice to Reopen Comment Period

  7. DOE Publishes CALiPER Snapshot Report on LED A Lamps

    Office of Energy Efficiency and Renewable Energy (EERE)

    DOE's CALiPER program has released a Snapshot Report on LED A lamps, which utilizes the LED Lighting Facts program's extensive product database to help industry stakeholders understand the current state and trajectory of the market for that class

  8. Integrated starting and running amalgam assembly for an electrodeless fluorescent lamp

    DOE Patents [OSTI]

    Borowiec, Joseph Christopher (Schenectady, NY); Cocoma, John Paul (Clifton Park, NY); Roberts, Victor David (Burnt Hills, NY)

    1998-01-01

    An integrated starting and running amalgam assembly for an electrodeless SEF fluorescent lamp includes a wire mesh amalgam support constructed to jointly optimize positions of a starting amalgam and a running amalgam in the lamp, thereby optimizing mercury vapor pressure in the lamp during both starting and steady-state operation in order to rapidly achieve and maintain high light output. The wire mesh amalgam support is constructed to support the starting amalgam toward one end thereof and the running amalgam toward the other end thereof, and the wire mesh is rolled for friction-fitting within the exhaust tube of the lamp. The positions of the starting and running amalgams on the wire mesh are jointly optimized such that high light output is achieved quickly and maintained, while avoiding any significant reduction in light output between starting and running operation.

  9. DOE Publishes CALiPER Application Summary Report on LED MR16 Lamps

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy’s CALiPER program has released an Application Summary Report that focuses on the photometric performance of 27 LED MR16 lamps. Entitled Application Summary Report 22:...

  10. DOE Publishes New CALiPER Report on Subjective Evaluation of LED PAR38 Lamps

    Broader source: Energy.gov [DOE]

    DOE has published the first in a series of four special investigations intended to extend the findings of CALiPER Application Summary Report 20: LED PAR38 Lamps, which was published late last year.

  11. Text-Alternative Version: CALiPER Series 21 on LED Linear Lamps...

    Energy Savers [EERE]

    Information Resources Videos Text-Alternative Version: CALiPER Series 21 on LED Linear Lamps and Troffer Lighting Text-Alternative Version: CALiPER Series 21 on LED Linear ...

  12. Bayesian Models for Life Prediction and Fault-Mode Classification in Solid State Lamps

    SciTech Connect (OSTI)

    Lall, Pradeep; Wei, Junchao; Sakalaukus, Peter

    2015-04-19

    A new method has been developed for assessment of the onset of degradation in solid state luminaires to classifY failure mechanisms by using metrics beyond lumen degradation that are currently used for identification of failure. Luminous Flux output, Correlated Color Temperature Data on Philips LED Lamps has been gathered under 85C/85%RH till lamp failure. The acquired data has been used in conjunction with Bayesian Probabilistic Models to identifY luminaires with onset of degradation much prior to failure through identification of decision boundaries between lamps with accrued damage and lamps beyond the failure threshold in the feature space. In addition luminaires with different failure modes have been classified separately from healthy pristine luminaires. It is expected that, the new test technique will allow the development of failure distributions without testing till L 70 life for the manifestation of failure.

  13. CALiPER Application Summary Report 20. LED PAR38 Lamps

    SciTech Connect (OSTI)

    none,

    2012-11-01

    This report analyzes the independently tested photometric performance of 38 LED PAR38 lamps. The test results indicate substantial improvement versus earlier CALiPER testing of similar products, and performance comparable to recent data from LED Lighting Facts and ENERGY STAR. Additional testing that focuses on performance attributes beyond those covered by LM-79-08 is planned for this group of lamps, and will be presented in subsequent reports.

  14. Use of Standard Fluorescent UV Weathering Lamps to Perform UV Conditioning

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Tests Prescribed in IEC Qualification Standards | Department of Energy Use of Standard Fluorescent UV Weathering Lamps to Perform UV Conditioning Tests Prescribed in IEC Qualification Standards Use of Standard Fluorescent UV Weathering Lamps to Perform UV Conditioning Tests Prescribed in IEC Qualification Standards Presented at the PV Module Reliability Workshop, February 26 - 27 2013, Golden, Colorado PDF icon pvmrw13_ps5_qlab_fowler.pdf More Documents & Publications Weathering

  15. Demonstration of LED Retrofit Lamps at the Jordan Schnitzer Museum of Art

    SciTech Connect (OSTI)

    Miller, Naomi J.

    2011-09-01

    The Jordan Schnitzer Museum of Art in Eugene, Oregon, houses a remarkable permanent collection of Asian art and antiquities, modern art, and sculpture, and also hosts traveling exhibitions. In the winter and spring of 2011, a series of digital photographs by artist Chris Jordan, titled "Running the Numbers," was exhibited in the Coeta and Donald Barker Special Exhibitions Gallery. These works graphically illustrate waste (energy, money, health, consumer objects, etc.) in contemporary culture. The Bonneville Power Administration and the Eugene Water and Electricity Board provided a set of Cree 12W light-emitting diode (LED) PAR38 replacement lamps (Cree LRP38) for the museum to test for accent lighting in lieu of their standard Sylvania 90W PAR38 130V Narrow Flood lamps (which draw 78.9W at 120V). At the same time, the museum tested LED replacement lamps from three other manufacturers, and chose the Cree lamp as the most versatile and most appropriate color product for this exhibit. The lamps were installed for the opening of the show in January 2011. This report describes the process for the demonstration, the energy and economic results, and results of a survey of the museum staff and gallery visitors on four similar clusters of art lighted separately by four PAR38 lamps.

  16. Compact intermediates in RNA folding

    SciTech Connect (OSTI)

    Woodson, S.A. (JHU)

    2011-12-14

    Large noncoding RNAs fold into their biologically functional structures via compact yet disordered intermediates, which couple the stable secondary structure of the RNA with the emerging tertiary fold. The specificity of the collapse transition, which coincides with the assembly of helical domains, depends on RNA sequence and counterions. It determines the specificity of the folding pathways and the magnitude of the free energy barriers to the ensuing search for the native conformation. By coupling helix assembly with nascent tertiary interactions, compact folding intermediates in RNA also play a crucial role in ligand binding and RNA-protein recognition.

  17. EffectsIntermediateEthanolBlends.pdf | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    EffectsIntermediateEthanolBlends.pdf EffectsIntermediateEthanolBlends.pdf EffectsIntermediateEthanolBlends.pdf PDF icon EffectsIntermediateEthanolBlends.pdf More Documents &...

  18. Intermediate Energy Infobook Activities (29 Activities)

    K-12 Energy Lesson Plans and Activities Web site (EERE)

    Information about Intermediate Energy Infobook, 29 student activities on energy basics for grades 5-8.

  19. DOE Publishes Notice of Public Meeting and Availability of the Framework Document for General Service Lamps Energy Conservation Standards

    Broader source: Energy.gov [DOE]

    The Department of Energy has published a Federal Register notice of public meeting and availability of the framework document regarding energy conservation standards for general service lamps.

  20. New Energy Efficiency Standards for Metal Halide Lamp Fixtures to Save on

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Energy Bills and Reduce Carbon Pollution | Department of Energy for Metal Halide Lamp Fixtures to Save on Energy Bills and Reduce Carbon Pollution New Energy Efficiency Standards for Metal Halide Lamp Fixtures to Save on Energy Bills and Reduce Carbon Pollution January 30, 2014 - 9:30am Addthis News Media Contact (202) 586-4940 WASHINGTON - As part of the Energy Department's efforts to develop efficiency standards that cut carbon pollution and save money by saving energy, U.S. Energy

  1. DOE Publishes CALiPER Report on Linear (T8) LED Lamps in a 2x4...

    Energy Savers [EERE]

    Linear (T8) LED Lamps in a 2x4 K12-Lensed Troffer DOE Publishes CALiPER Report on Linear (T8) LED Lamps in a 2x4 K12-Lensed Troffer May 2, 2014 - 4:48pm Addthis The U.S. Department ...

  2. Observed Minimum Illuminance Threshold for Night Market Vendors in Kenya who use LED Lamps

    SciTech Connect (OSTI)

    Johnstone, Peter; Jacobson, Arne; Mills, Evan; Radecsky, Kristen

    2009-03-21

    Creation of light for work, socializing, and general illumination is a fundamental application of technology around the world. For those who lack access to electricity, an emerging and diverse range of LED based lighting products hold promise for replacing and/or augmenting their current fuel-based lighting sources that are costly and dirty. Along with analysis of environmental factors, economic models for total cost-ofownership of LED lighting products are an important tool for studying the impacts of these products as they emerge in markets of developing countries. One important metric in those models is the minimum illuminance demanded by end-users for a given task before recharging the lamp or replacing batteries. It impacts the lighting service cost per unit time if charging is done with purchased electricity, batteries, or charging services. The concept is illustrated in figure 1: LED lighting products are generally brightest immediately after the battery is charged or replaced and the illuminance degrades as the battery is discharged. When a minimum threshold level of illuminance is reached, the operational time for the battery charge cycle is over. The cost to recharge depends on the method utilized; these include charging at a shop at a fixed price per charge, charging on personal grid connections, using solar chargers, and purchasing dry cell batteries. This Research Note reports on the observed"charge-triggering" illuminance level threshold for night market vendors who use LED lighting products to provide general and task oriented illumination. All the study participants charged with AC power, either at a fixed-price charge shop or with electricity at their home.

  3. Characterization of protein folding intermediates

    SciTech Connect (OSTI)

    Kim, P.S.

    1986-01-01

    The three-dimensional structure of a protein is encoded in its linear sequence of amino acids. Studies of protein folding are aimed at understanding the nature of this code which translates one-dimensional information to three-dimensions. It is now well-established that protein folding intermediates exist and can be populated significantly under some conditions. A method to characterize kinetic folding intermediates is described. The method takes advantage of the decrease in exchange rates between amide protons (i.e., peptide backbone NH) and solvent water protons, when the amide proton is involved in structure. The feasibility of using amide proton exchange to pulse-label proteins during folding has been demonstrated using (/sup 3/H)-H/sub 2/O. The results with ribonuclease A (RNase A) support a framework model for folding, in which the secondary structure of a protein is formed before tertiary structure changes are complete. Extension of these studies using NMR should permit characterization of early secondary structure folding frameworks.

  4. ISSUANCE 2015-08-14: Energy Efficiency Program for Consumer Products: Energy Conservation Standards for Fluorescent Lamp Ballasts, Reopening of the Comment Period

    Broader source: Energy.gov [DOE]

    Energy Efficiency Program for Consumer Products: Energy Conservation Standards for Fluorescent Lamp Ballasts, Reopening of the Comment Period

  5. ISSUANCE 2015-06-25: Energy Conservation Program: Test Procedures for Integrated Light-Emitting Diode Lamps, Supplemental Notice of Proposed Rulemaking

    Broader source: Energy.gov [DOE]

    Energy Conservation Program: Test Procedures for Integrated Light-Emitting Diode Lamps, Supplemental Notice of Proposed Rulemaking

  6. Demonstration Assessment of Light-Emitting Diode (LED) Retrofit Lamps at an Exhibit of 19th Century Photography at the Getty Museum

    SciTech Connect (OSTI)

    Miller, N. J.; Druzik, J. R.

    2012-03-01

    GATEWAY program report on a demonstration of LED retrofit lamps at the J. Paul Getty Museum in Malibu, CA.

  7. ISSUANCE 2015-06-17: Energy Conservation Standards for Fluorescent Lamp Ballasts, Notice of Public Meeting and Availability of the Framework Document

    Broader source: Energy.gov [DOE]

    Energy Conservation Standards for Fluorescent Lamp Ballasts, Notice of Public Meeting and Availability of the Framework Document

  8. RF driven sulfur lamp having driving electrodes which face each other

    DOE Patents [OSTI]

    Gabor, G.; Orr, T.R.; Greene, C.M.; Crawford, D.G.; Berman, S.M.

    1999-06-22

    A high intensity discharge lamp without mercury is disclosed radiating a selected spectrum of which can be almost entirely in the visible range from an envelope that contains a sulfur containing substance. The lamp utilizes a signal source that generates an excitation signal that is externally coupled to the exterior surface of the envelope to excite the enclosed sulfur containing substance. Various embodiments of the lamp use electrodes adjacent the envelope to couple the excitation signal thereto with the face of the electrodes shaped to complement the shape of the exterior surface of the envelope. Two shapes discussed are spherical and cylindrical. To minimize filamentary discharges each envelope may include an elongated stem affixed to the exterior thereof whereby a rotational subsystem spins the envelope. In yet another embodiment the envelope has a Dewar configuration with two electrodes, one positioned near the external curved side surface of the body, and a second to the inner surface of the hole through the envelope. Further, the envelope may contain a backfill of a selected inert gas to assist in the excitation of lamp with that backfill at a pressure of less than 1 atmosphere, wherein the backfill pressure is directly related to the increase or decrease of peak output and inversely related to the increase and decrease of the emitted spectrum from the envelope. The emitting fill can be less than 6 mg/cc, or at least 2 mg/cc of the envelope of a sulfur containing substance. 17 figs.

  9. DOE Publishes CALiPER Report on Chromaticity Shift Modes of LED PAR38 Lamps

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy's CALiPER program has released Report 20.5, which is part of a series of investigations on LED PAR38 lamps. The new report builds on CALiPER Report 20.4 by providing a...

  10. DOE Publishes CALiPER Report on Linear (T8) LED Lamps in Recessed Troffers

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy's CALiPER program has released Report 21.2, which is part of a series of investigations on linear LED lamps. Report 21.2 focuses on the performance of three linear (T8...

  11. CALiPER Application Summary Report 16. LED BR30 and R30 Lamps

    SciTech Connect (OSTI)

    none,

    2012-07-01

    This report analyzes the independently tested performance of 13 LED products labeled as BR30 or R30 lamps. The test results indicate substantial improvement versus earlier CALiPER testing of similar products, and performance comparable to recent data from LED Lighting Facts and ENERGY STAR.

  12. DOE Publishes CALiPER Report on Cost-Effectiveness of Linear (T8) LED Lamps

    Broader source: Energy.gov [DOE]

    The U.S. Department of Energy's CALiPER program has released Report 21.3, which is part of a series of investigations on linear LED lamps. Report 21.3 details a set of life-cycle cost simulations...

  13. Method for removal of phosgene from boron trichloride. [DOE patent application; mercury arc lamp

    DOE Patents [OSTI]

    Freund, S.M.

    1981-09-03

    Selective ultraviolet photolysis using an unfiltered mercury arc lamp has been used to substantially reduce the phosgene impurity in a mixture of boron trichloride and phosgene. Infrared spectrophotometric analysis of the sample before and after irradiation shows that it is possible to highly purify commercially available boron trichloride with this method.

  14. Method and apparatus for powering an electrodeless lamp with reduced radio frequency interference

    DOE Patents [OSTI]

    Simpson, J.E.

    1999-06-08

    An electrodeless lamp waveguide structure includes tuned absorbers for spurious RF signals. A lamp waveguide with an integral frequency selective attenuation includes resonant absorbers positioned within the waveguide to absorb spurious out-of-band RF energy. The absorbers have a negligible effect on energy at the selected frequency used to excite plasma in the lamp. In a first embodiment, one or more thin slabs of lossy magnetic material are affixed to the sidewalls of the waveguide at approximately one quarter wavelength of the spurious signal from an end wall of the waveguide. The positioning of the lossy material optimizes absorption of power from the spurious signal. In a second embodiment, one or more thin slabs of lossy magnetic material are used in conjunction with band rejection waveguide filter elements. In a third embodiment, one or more microstrip filter elements are tuned to the frequency of the spurious signal and positioned within the waveguide to couple and absorb the spurious signal's energy. All three embodiments absorb negligible energy at the selected frequency and so do not significantly diminish the energy efficiency of the lamp. 18 figs.

  15. Method and apparatus for powering an electrodeless lamp with reduced radio frequency interference

    DOE Patents [OSTI]

    Simpson, James E.

    1999-01-01

    An electrodeless lamp waveguide structure includes tuned absorbers for spurious RF signals. A lamp waveguide with an integral frequency selective attenuation includes resonant absorbers positioned within the waveguide to absorb spurious out-of-band RF energy. The absorbers have a negligible effect on energy at the selected frequency used to excite plasma in the lamp. In a first embodiment, one or more thin slabs of lossy magnetic material are affixed to the sidewalls of the waveguide at approximately one quarter wavelength of the spurious signal from an end wall of the waveguide. The positioning of the lossy material optimizes absorption of power from the spurious signal. In a second embodiment, one or more thin slabs of lossy magnetic material are used in conjunction with band rejection waveguide filter elements. In a third embodiment, one or more microstrip filter elements are tuned to the frequency of the spurious signal and positioned within the waveguide to couple and absorb the spurious signal's energy. All three embodiments absorb negligible energy at the selected frequency and so do not significantly diminish the energy efficiency of the lamp.

  16. Electronic screw-in ballast and improved circline lamp phase I. Final report

    SciTech Connect (OSTI)

    Kohler, T.P.

    1980-09-01

    A solid state ballast has been designed for the efficient operation of a 10 in circline fluorescent lamp. The circuit can be manufactured using power hybrid technology. Eight discrete component versions of the ballasts have been delivered to LBL for testing. The results show the solid state fluorescent ballast system is more efficient than the core-coil ballasted systems on the market.

  17. CALiPER Report 20.3: Robustness of LED PAR38 Lamps

    SciTech Connect (OSTI)

    none,

    2014-12-30

    A small sample of each of the CALiPER Application Summary Report 20 PAR38 lamp types underwent stress testing that included substantial temperature and humidity changes, electrical variation, and vibration. The results do not directly address expected lifetime, but can be compared with one another, as well as with benchmark conventional products, to assess the relative robustness of the product designs.

  18. RF driven sulfur lamp having driving electrodes which face each other

    DOE Patents [OSTI]

    Gabor, George (Lafayette, CA); Orr, Thomas Robert (Castro Valley, CA); Greene, Charles Maurice (Oakland, CA); Crawford, Douglas Gordon (Orinda, CA); Berman, Samuel Maurice (San Francisco, CA)

    1999-01-01

    A high intensity discharge lamp without mercury is disclosed radiating a selected spectrum of which can be almost entirely in the visible range from an envelope that contains a sulfur containing substance. The lamp utilizes a signal source that generates an excitation signal that is externally coupled to the exterior surface of the envelope to excite the enclosed sulfur containing substance. Various embodiments of the lamp use electrodes adjacent the envelope to couple the excitation signal thereto with the face of the electrodes shaped to complement the shape of the exterior surface of the envelope. Two shapes discussed are spherical and cylindrical. To minimize filamentary discharges each envelope may include an elongated stem affixed to the exterior thereof whereby a rotational subsystem spins the envelope. In yet another embodiment the envelope has a Dewar configuration with two electrodes, one positioned near the external curved side surface of the body, and a second to the inner surface of the hole through the envelope. Further, the envelope may contain a backfill of a selected inert gas to assist in the excitation of lamp with that backfill at a pressure of less than 1 atmosphere, wherein the backfill pressure is directly related to the increase or decrease of peak output and inversely related to the increase and decrease of the emitted spectrum from the envelope. The emitting fill can be less than 6 mg/cc, or at least 2 mg/cc of the envelope of a sulfur containing substance.

  19. CALiPER Report 20.2: Dimming, Flicker, and Power Quality Characteristics of LED PAR38 Lamps

    SciTech Connect (OSTI)

    None, None

    2014-03-31

    This report focuses on the flicker and power quality performance of the Series 20 lamps at full output and various dimmed levels. All of the Series 20 PAR38 lamps that manufacturers claimed to be dimmable (including all halogen lamps) were evaluated individually (one lamp at a time) both on a switch and under the control of a phase-cut dimmer designed for use with "all classes of bulbs." Measurements of luminous flux, flicker, and power quality were taken at 10 target dimmed settings and compared with operation on a switch. Because only a single unit of each product was evaluated on a single dimmer that may or may not have been recommended by its manufacturer, this report focuses on the performance of the products relative to each other, rather than the best-case performance of each lamp or variation in performance delivered from each lamp. Despite these limitations, the results suggest that LED performance is improving, and performance trends are beginning to emerge, perhaps due in part to the identification of preferred LED driver strategies for lamp products.

  20. CALiPER Report 20.1: Quality of Beam, Shadow, and Color in LED PAR38 Lamps

    Energy Savers [EERE]

    | Department of Energy CALiPER Report 20.1: Quality of Beam, Shadow, and Color in LED PAR38 Lamps CALiPER Report 20.1: Quality of Beam, Shadow, and Color in LED PAR38 Lamps View the video about CALiPER Report 20.1 which focuses on human-evaluated characteristics, including beam quality, shadow quality, and color quality in LED PAR38 lamps. View the text-alternative version. Solid-State Lighting Home About the Solid-State Lighting Program Research & Development

  1. Protein Vivisection Reveals Elusive Intermediates in Folding

    SciTech Connect (OSTI)

    Zheng, Zhongzhou; Sosnick, Tobin R. (UC)

    2010-05-25

    Although most folding intermediates escape detection, their characterization is crucial to the elucidation of folding mechanisms. Here, we outline a powerful strategy to populate partially unfolded intermediates: A buried aliphatic residue is substituted with a charged residue (e.g., Leu {yields} Glu{sup -}) to destabilize and unfold a specific region of the protein. We applied this strategy to ubiquitin, reversibly trapping a folding intermediate in which the {beta}5-strand is unfolded. The intermediate refolds to a native-like structure upon charge neutralization under mildly acidic conditions. Characterization of the trapped intermediate using NMR and hydrogen exchange methods identifies a second folding intermediate and reveals the order and free energies of the two major folding events on the native side of the rate-limiting step. This general strategy may be combined with other methods and have broad applications in the study of protein folding and other reactions that require trapping of high-energy states.

  2. Enol Intermediates Unexpectedly Found in Flames

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Enol Intermediates Unexpectedly Found in Flames Enol Intermediates Unexpectedly Found in Flames Print Wednesday, 27 July 2005 00:00 For those studying flame chemistry and the properties of combustion intermediates by means of molecular beam mass spectrometry, the addition of tunable vacuum ultraviolet (VUV) from a synchrotron to photoionize the beam for mass spectrometry makes for a powerful technique capable of differentiating between isomers with the same molecular weight and composition. With

  3. Enol Intermediates Unexpectedly Found in Flames

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    output, high-concentration intermediates, and major products. However, for improving combustion efficiency and controlling pollution, it is necessary to understand flame...

  4. Direct Kinetic Measurements of a Criegee Intermediate

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Direct Kinetic Measurements of a Criegee Intermediate Print In the earth's troposphere, which blankets the planet surface where we live and breathe, dust particles, gas molecules,...

  5. Direct Kinetic Measurements of a Criegee Intermediate

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    quantities. Because Criegee intermediates have long been thought to play a key role in atmospheric chemistry, the announcement of a method to directly measure their reactivity...

  6. Experiments in intermediate energy physics

    SciTech Connect (OSTI)

    Dehnhard, D.

    2003-02-28

    Research in experimental nuclear physics was done from 1979 to 2002 primarily at intermediate energy facilities that provide pion, proton, and kaon beams. Particularly successful has been the work at the Los Alamos Meson Physics Facility (LAMPF) on unraveling the neutron and proton contributions to nuclear ground state and transition densities. This work was done on a wide variety of nuclei and with great detail on the carbon, oxygen, and helium isotopes. Some of the investigations involved the use of polarized targets which allowed the extraction of information on the spin-dependent part of the triangle-nucleon interaction. At the Indiana University Cyclotron Facility (IUCF) we studied proton-induced charge exchange reactions with results of importance to astrophysics and the nuclear few-body problem. During the first few years, the analysis of heavy-ion nucleus scattering data that had been taken prior to 1979 was completed. During the last few years we created hypernuclei by use of a kaon beam at Brookhaven National Laboratory (BNL) and an electron beam at Jefferson Laboratory (JLab). The data taken at BNL for a study of the non-mesonic weak decay of the A particle in a nucleus are still under analysis by our collaborators. The work at JLab resulted in the best resolution hypernuclear spectra measured thus far with magnetic spectrometers.

  7. The Carbon-Land Model Intercomparison Project (C-LAMP): A Model-Data Comparison System for Evaluation of Coupled Biosphere-Atmosphere Models

    SciTech Connect (OSTI)

    Hoffman, Forrest M; Randerson, Jim; Thornton, Peter E; Mahowald, Natalie; Bonan, Gordon; Running, Steven; Fung, Inez

    2009-01-01

    The need to capture important climate feebacks in general circulation models (GCMs) has resulted in new efforts to include atmospheric chemistry and land and ocean biogeochemistry into the next generation of production climate models, now often referred to as Earth System Models (ESMs). While many terrestrial and ocean carbon models have been coupled to GCMs, recent work has shown that such models can yield a wide range of results, suggesting that a more rigorous set of offline and partially coupled experiments, along with detailed analyses of processes and comparisons with measurements, are warranted. The Carbon-Land Model Intercomparison Project (C-LAMP) provides a simulation protocol and model performance metrics based upon comparisons against best-available satellite- and ground-based measurements (Hoffman et al., 2007). C-LAMP provides feedback to the modeling community regarding model improvements and to the measurement community by suggesting new observational campaigns. C-LAMP Experiment 1 consists of a set of uncoupled simulations of terrestrial carbon models specifically designed to examine the ability of the models to reproduce surface carbon and energy fluxes at multiple sites and to exhibit the influence of climate variability, prescribed atmospheric carbon dioxide (CO{sub 2}), nitrogen (N) deposition, and land cover change on projections of terrestrial carbon fluxes during the 20th century. Experiment 2 consists of partially coupled simulations of the terrestrial carbon model with an active atmosphere model exchanging energy and moisture fluxes. In all experiments, atmospheric CO{sub 2} follows the prescribed historical trajectory from C{sup 4}MIP. In Experiment 2, the atmosphere model is forced with prescribed sea surface temperatures (SSTs) and corresponding sea ice concentrations from the Hadley Centre; prescribed CO{sub 2} is radiatively active; and land, fossil fuel, and ocean CO{sub 2} fluxes are advected by the model. Both sets of experiments have been performed using two different terrestrial biogeochemistry modules coupled to the Community Land Model version 3 (CLM3) in the Community Climate System Model version 3 (CCSM3): The CASA model of Fung, et al., and the carbon-nitrogen (CN) model of Thornton. Comparisons against Ameriflus site measurements, MODIS satellite observations, NOAA flask records, TRANSCOM inversions, and Free Air CO{sub 2} Enrichment (FACE) site measurements, and other datasets have been performed and are described in Randerson et al. (2009). The C-LAMP diagnostics package was used to validate improvements to CASA and CN for use in the next generation model, CLM4. It is hoped that this effort will serve as a prototype for an international carbon-cycle model benchmarking activity for models being used for the Inter-governmental Panel on Climate Change (IPCC) Fifth Assessment Report. More information about C-LAMP, the experimental protocol, performance metrics, output standards, and model-data comparisons from the CLM3-CASA and CLM3-CN models are available at http://www.climatemodeling.org/c-lamp.

  8. ENHANCED CHEMICAL CLEANING: EFFECTIVENESS OF THE UV LAMP TO DECOMPOSE OXALATES

    SciTech Connect (OSTI)

    Ketusky, E.; Huff, T.; Sudduth, C.

    2010-01-19

    Enhanced Chemical Cleaning is a new process scheduled to begin cleaning Savannah River Site High Level Waste Tanks in 2012. It is an improvement over the current chemical cleaning method, in that it minimizes downstream impacts on the High Level Waste System. It is based on a state of the art scale removal process used on the secondary side of nuclear power plants, with modifications to accommodate the unique constraints created by the tanks. Both Enhanced Chemical Cleaning and the scale removal process are founded on dissolving metal oxides/hydroxides using oxalic acid, with subsequent oxalate decomposition via hydroxylation using ozone or peroxide, and UV light as a catalyst. A divergence Enhanced Chemical Cleaning has from nuclear power scale removal is the significantly increased solids concentration during oxalate decomposition. These solids can limit the ability of the UV light to create hydroxyl radicals, either by limiting the ability of the light to penetrate through the solution, or by increasing the fouling rate on the UV light. Both will decrease the overall catalytic effectiveness, thereby decreasing the concentration of formed hydroxyl radicals. The hydroxyl radicals are the driving force behind the oxalate decomposition. To understand the impact of increased solids, testing was performed using a medium pressure UV light inside an ozone supplied Oxalate Decomposition Reactor. Using a dissolved metal sludge simulant with an initial oxalate concentration greater than 12,000 ppm, and an initial pH of about 2.0, the spent acid solution was recirculated through the reactor, while the UV light was allowed to foul. For the first few hours, the oxalate decomposition rate was about 1,300 ppm/hour. After about 3 hours, enough time for the UV lamp to foul, the oxalate decomposition rate decreased to about 500 ppm/hour. The decomposition rate then remained roughly constant for the next 16 hours. Overall, testing showed that the oxalate destruction rate decreased by about 2.8. Results from very similartests with similar chemistry suggest that the impact should be about 10. Based on the limited reaction pathwayfor the creation of hydroxyl radicals with iron, ozone, and no UV, the discrepancy suggests that initially, at 'time zero' the UV light failed to perform up to expectations. It is therefore concluded that regardless of the fouling rate, either the increased solids concentration is impacting the initial penetrability (i.e. to many solids), or the light is not adequately sized/configured to have the appropriate flux.

  9. 2015-01-28 Issuance: Test Procedure for Fluorescent Lamp Ballasts; Final Rule Correction

    Broader source: Energy.gov [DOE]

    This document is a pre-publication Federal Register final rule correction regarding test procedures for fluorescent lamp ballasts, as issued by the Deputy Assistant Secretary for Energy Efficiency on January 28, 2014. Though it is not intended or expected, should any discrepancy occur between the document posted here and the document published in the Federal Register, the Federal Register publication controls. This document is being made available through the Internet solely as a means to facilitate the public's access to this document.

  10. Spatiotemporal study of the local thermodynamic equilibrium deviations in high-intensity discharge lamps

    SciTech Connect (OSTI)

    Helali, H.; Bchir, T.; Araoud, Z.; Charrada, K.

    2013-04-15

    The aim of this work is to study the local thermodynamic equilibrium (LTE) deviations in arc discharges plasma generated in high-intensity discharge lamps operating under an ac (50 Hz) power supply. To achieve this goal, we elaborate a two-temperature, two-dimensional, and time-depending model. We have found numerical results almost reproducing the experimental data, which allows us to validate this model. After validation, we have discussed different energy term effects on the LTE deviations.

  11. Guidance Concerning Enforcement of EISA 2007 Standards Candelabra...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Candelabra Base and Intermediate Base Lamps The Energy Independence and Security Act of 2007 (EISA 2007) imposed energy conservation standards for candelabra and...

  12. Enol Intermediates Unexpectedly Found in Flames

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Enol Intermediates Unexpectedly Found in Flames Print For those studying flame chemistry and the properties of combustion intermediates by means of molecular beam mass spectrometry, the addition of tunable vacuum ultraviolet (VUV) from a synchrotron to photoionize the beam for mass spectrometry makes for a powerful technique capable of differentiating between isomers with the same molecular weight and composition. With the help of a unique experimental apparatus, an international team of

  13. Enol Intermediates Unexpectedly Found in Flames

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Enol Intermediates Unexpectedly Found in Flames Print For those studying flame chemistry and the properties of combustion intermediates by means of molecular beam mass spectrometry, the addition of tunable vacuum ultraviolet (VUV) from a synchrotron to photoionize the beam for mass spectrometry makes for a powerful technique capable of differentiating between isomers with the same molecular weight and composition. With the help of a unique experimental apparatus, an international team of

  14. Enol Intermediates Unexpectedly Found in Flames

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Enol Intermediates Unexpectedly Found in Flames Print For those studying flame chemistry and the properties of combustion intermediates by means of molecular beam mass spectrometry, the addition of tunable vacuum ultraviolet (VUV) from a synchrotron to photoionize the beam for mass spectrometry makes for a powerful technique capable of differentiating between isomers with the same molecular weight and composition. With the help of a unique experimental apparatus, an international team of

  15. Enol Intermediates Unexpectedly Found in Flames

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Enol Intermediates Unexpectedly Found in Flames Print For those studying flame chemistry and the properties of combustion intermediates by means of molecular beam mass spectrometry, the addition of tunable vacuum ultraviolet (VUV) from a synchrotron to photoionize the beam for mass spectrometry makes for a powerful technique capable of differentiating between isomers with the same molecular weight and composition. With the help of a unique experimental apparatus, an international team of

  16. Direct Kinetic Measurements of a Criegee Intermediate

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Direct Kinetic Measurements of a Criegee Intermediate Direct Kinetic Measurements of a Criegee Intermediate Print Wednesday, 25 January 2012 00:00 In the earth's troposphere, which blankets the planet surface where we live and breathe, dust particles, gas molecules, water vapor, and sunlight provide the ingredients for a multitude of chemical reactions that can generate effects ranging from clouds and smog to acid rain and climate change. In 1949, chemist Rudolf Criegee proposed a novel chemical

  17. Data requirements for intermediate energy nuclear applications

    SciTech Connect (OSTI)

    Pearlstein, S.

    1990-01-01

    Several applications that include spallation neutron sources, space radiation effects, biomedical isotope production, accelerator shielding and radiation therapy make use of intermediate energy nuclear data extending to several GeV. The overlapping data needs of these applications are discussed in terms of what projectiles, targets and reactions are of interest. Included is a discussion of what is generally known about these data and what is needed to facilitate their use in intermediate energy applications. 40 refs., 2 figs., 2 tabs.

  18. Enol Intermediates Unexpectedly Found in Flames

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Enol Intermediates Unexpectedly Found in Flames Print For those studying flame chemistry and the properties of combustion intermediates by means of molecular beam mass spectrometry, the addition of tunable vacuum ultraviolet (VUV) from a synchrotron to photoionize the beam for mass spectrometry makes for a powerful technique capable of differentiating between isomers with the same molecular weight and composition. With the help of a unique experimental apparatus, an international team of

  19. Enol Intermediates Unexpectedly Found in Flames

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Enol Intermediates Unexpectedly Found in Flames Print For those studying flame chemistry and the properties of combustion intermediates by means of molecular beam mass spectrometry, the addition of tunable vacuum ultraviolet (VUV) from a synchrotron to photoionize the beam for mass spectrometry makes for a powerful technique capable of differentiating between isomers with the same molecular weight and composition. With the help of a unique experimental apparatus, an international team of

  20. Enol Intermediates Unexpectedly Found in Flames

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Enol Intermediates Unexpectedly Found in Flames Print For those studying flame chemistry and the properties of combustion intermediates by means of molecular beam mass spectrometry, the addition of tunable vacuum ultraviolet (VUV) from a synchrotron to photoionize the beam for mass spectrometry makes for a powerful technique capable of differentiating between isomers with the same molecular weight and composition. With the help of a unique experimental apparatus, an international team of

  1. Facility for high heat flux testing of irradiated fusion materials and components using infrared plasma arc lamps

    SciTech Connect (OSTI)

    Sabau, Adrian S; Ohriner, Evan Keith; Kiggans, Jim; Harper, David C; Snead, Lance Lewis; Schaich, Charles Ross

    2014-01-01

    A new high-heat flux testing facility using water-wall stabilized high-power high-pressure argon Plasma Arc Lamps (PALs) has been developed for fusion applications. It can handle irradiated plasma facing component materials and mock-up divertor components. Two PALs currently available at ORNL can provide maximum incident heat fluxes of 4.2 and 27 MW/m2 over a heated area of 9x12 and 1x10 cm2, respectively, which are fusion-prototypical steady state heat flux conditions. The facility will be described and the main differences between the photon-based high-heat flux testing facilities, such as PALs, and the e-beam and particle beam facilities more commonly used for fusion HHF testing are discussed. The components of the test chamber were designed to accommodate radiation safety and materials compatibility requirements posed by high-temperature exposure of low levels irradiated tungsten articles. Issues related to the operation and temperature measurements during testing are presented and discussed.

  2. Method of controlling the mercury vapor pressure in a photo-chemical lamp or vapor filter used for Hg[sup 196] enrichment

    DOE Patents [OSTI]

    Grossman, M.W.

    1993-02-16

    The present invention is directed to a method of eliminating the cold spot zones presently used on Hg[sup 196] isotope separation lamps and filters by the use of a mercury amalgams, preferably mercury - indium amalgams. The use of an amalgam affords optimization of the mercury density in the lamp and filter of a mercury enrichment reactor, particularly multilamp enrichment reactors. Moreover, the use of an amalgam in such lamps and/or filters affords the ability to control the spectral line width of radiation emitted from lamps, a requirement for mercury enrichment.

  3. Method of controlling the mercury vapor pressure in a photo-chemical lamp or vapor filter used for Hg.sup.196 enrichment

    DOE Patents [OSTI]

    Grossman, Mark W. (Belmont, MA)

    1993-01-01

    The present invention is directed to a method of eliminating the cold spot zones presently used on Hg.sup.196 isotope separation lamps and filters by the use of a mercury amalgams, preferably mercury - indium amalgams. The use of an amalgam affords optimization of the mercury density in the lamp and filter of a mercury enrichment reactor, particularly multilamp enrichment reactors. Moreover, the use of an amalgam in such lamps and/or filters affords the ability to control the spectral line width of radiation emitted from lamps, a requirement for mercury enrichment.

  4. DOE Publishes Final Rule for the Request for Exclusion of 100 Watt R20 Short Incandescent Reflector Lamps from Energy Conservation Standards

    Broader source: Energy.gov [DOE]

    The Department of Energy has published a final rule regarding the request for exclusion of 100 Watt R20 short incandescent reflector lamps from energy conservation standards.

  5. Super-radiance in the sodium resonance lines from sodium iodide arc lamps

    SciTech Connect (OSTI)

    Karabourniotis, D.; Drakakis, E.

    2010-08-09

    Super-radiance observed within the centers of the sodium resonance D lines emitted by arc lamps containing sodium iodide as additive in a high-pressure mercury plasma environment was studied by high-resolution emission spectroscopy. The spectral radiance of these self-reversed lines including super-radiance was simulated by considering a local enhancement of the source function due to the presence of an additional source of radiation near the arc wall. Causes of this hitherto unrecognized source of radiation are given.

  6. This document, concerning general service lamps is an action issued by the Depar

    Energy Savers [EERE]

    general service lamps is an action issued by the Department of Energy. Though it is not intended or expected, should any discrepancy occur between the document posted here and the document published in the Federal Register, the Federal Register publication controls. This document is being made available through the Internet solely as a means to facilitate the public's access to this document. 1 6450-01-P DEPARTMENT OF ENERGY 10 CFR Parts 429 and 430 [Docket Number EERE-2013-BT-STD-0051] RIN:

  7. Highly Mismatched Alloys for Intermediate Band Solar Cells

    SciTech Connect (OSTI)

    Walukiewicz, W.; Yu, K.M.; Wu, J.; Ager III, J.W.; Shan, W.; Scrapulla, M.A.; Dubon, O.D.; Becla, P.

    2005-03-21

    It has long been recognized that the introduction of a narrow band of states in a semiconductor band gap could be used to achieve improved power conversion efficiency in semiconductor-based solar cells. The intermediate band would serve as a ''stepping stone'' for photons of different energy to excite electrons from the valence to the conduction band. An important advantage of this design is that it requires formation of only a single p-n junction, which is a crucial simplification in comparison to multijunction solar cells. A detailed balance analysis predicts a limiting efficiency of more than 50% for an optimized, single intermediate band solar cell. This is higher than the efficiency of an optimized two junction solar cell. Using ion beam implantation and pulsed laser melting we have synthesized Zn{sub 1-y}Mn{sub y}O{sub x}Te{sub 1-x} alloys with x<0.03. These highly mismatched alloys have a unique electronic structure with a narrow oxygen-derived intermediate band. The width and the location of the band is described by the Band Anticrossing model and can be varied by controlling the oxygen content. This provides a unique opportunity to optimize the absorption of solar photons for best solar cell performance. We have carried out systematic studies of the effects of the intermediate band on the optical and electrical properties of Zn{sub 1-y}Mn{sub y}O{sub x}Te{sub 1-x} alloys. We observe an extension of the photovoltaic response towards lower photon energies, which is a clear indication of optical transitions from the valence to the intermediate band.

  8. A Thermoelectric Generator with an Intermediate Heat Exchanger...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    A Thermoelectric Generator with an Intermediate Heat Exchanger for Automotive Waste Heat Recovery System A Thermoelectric Generator with an Intermediate Heat Exchanger for...

  9. Ubiquity of linear resistivity at intermediate temperature in...

    Office of Scientific and Technical Information (OSTI)

    Ubiquity of linear resistivity at intermediate temperature in bad metals Prev Next Title: Ubiquity of linear resistivity at intermediate temperature in bad metals Authors: ...

  10. Ubiquity of linear resistivity at intermediate temperature in...

    Office of Scientific and Technical Information (OSTI)

    Ubiquity of linear resistivity at intermediate temperature in bad metals Citation Details In-Document Search Title: Ubiquity of linear resistivity at intermediate temperature in ...

  11. Sandia Energy - CRF: First Direct Detection of QOOH Intermediate...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of QOOH Intermediate Shows Long Lifetime of Key Species Previous Next CRF: First Direct Detection of QOOH Intermediate Shows Long Lifetime of Key Species Authors J.D....

  12. Integrating NABC bio-oil intermediates into the petroleum refinery...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Integrating NABC bio-oil intermediates into the petroleum refinery Integrating NABC bio-oil intermediates into the petroleum refinery Breakout Session 2: Frontiers and Horizons ...

  13. CALiPER Report 20.4: Lumen and Chromaticity Maintenance of LED PAR38 Lamps Operated in Steady-State Conditions

    SciTech Connect (OSTI)

    none,

    2014-12-30

    This CALiPER report focuses on lumen maintenance, chromaticity maintenance, and catastrophic failure in 32 of the Series 20 LED PAR38 lamps and 8 benchmark lamps, which were monitored for nearly 14,000 hours at ambient temperatures between 44°C and 45°C.

  14. Intermediate Temperature SOFC Operation Using Lanthanum Gallate Electrolyte

    SciTech Connect (OSTI)

    Elangovan, S.; Balagopal, S. Hartvigsen, J.; Tipmer, M.; Larsen, D.

    2005-01-27

    This presentation discusses intermediate temperature SOFC operation using lanthanum gallate electrolyte.

  15. Direct Kinetic Measurements of a Criegee Intermediate

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    J.D. Savee, D.L. Osborn, S.S. Vasu, C.J. Percival, D.E. Shallcross, and C.A. Taatjes, "Direct Kinetic Measurements of Criegee Intermediate (CH2OO) Formed by Reaction of CH2I...

  16. THERMAL ANNEALING OF ZNO FILMS USING HIGH-DENSITY PLASMA ARC LAMPS

    SciTech Connect (OSTI)

    Sabau, Adrian S; Dinwiddie, Ralph Barton; Xu, Jun; Angelini, Joseph Attilio; Harper, David C

    2011-01-01

    Nanostructured materials are rarely synthesized with appropriate phase and/or morphology. In this study, critical additional of as-synthesized nanostructured materials, such as annealing and/or activation of dopants, are addressed using infrared plasma arc lamps (PAL) over areas as large as 1,000 cm2. The broad spectral range of the PAL and the spectral variation of light absorption in nanostructured materials make the selection of processing parameters extremely difficult, posing a major technological barrier. In this study, the measurement of the surface temperature using various techniques for ZnO films on crystalline silicon wafers is discussed. An energy transport model for the simulation of rapid thermal processing using PAL is presented. The experimental and computational results show that the surface temperature cannot be measured directly and that computer simulation results are an effective tool for obtaining accurate data on processing temperatures.

  17. partially oxidized combustion interme-diates

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    partially oxidized combustion interme-diates - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization Battery Testing Nuclear Fuel Cycle Defense Waste

  18. Direct Kinetic Measurements of a Criegee Intermediate

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Direct Kinetic Measurements of a Criegee Intermediate Print In the earth's troposphere, which blankets the planet surface where we live and breathe, dust particles, gas molecules, water vapor, and sunlight provide the ingredients for a multitude of chemical reactions that can generate effects ranging from clouds and smog to acid rain and climate change. In 1949, chemist Rudolf Criegee proposed a novel chemical pathway for one such reaction, known as ozonolysis: the destruction of alkenes (a type

  19. Direct Kinetic Measurements of a Criegee Intermediate

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Direct Kinetic Measurements of a Criegee Intermediate Print In the earth's troposphere, which blankets the planet surface where we live and breathe, dust particles, gas molecules, water vapor, and sunlight provide the ingredients for a multitude of chemical reactions that can generate effects ranging from clouds and smog to acid rain and climate change. In 1949, chemist Rudolf Criegee proposed a novel chemical pathway for one such reaction, known as ozonolysis: the destruction of alkenes (a type

  20. Direct Kinetic Measurements of a Criegee Intermediate

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Direct Kinetic Measurements of a Criegee Intermediate Print In the earth's troposphere, which blankets the planet surface where we live and breathe, dust particles, gas molecules, water vapor, and sunlight provide the ingredients for a multitude of chemical reactions that can generate effects ranging from clouds and smog to acid rain and climate change. In 1949, chemist Rudolf Criegee proposed a novel chemical pathway for one such reaction, known as ozonolysis: the destruction of alkenes (a type

  1. Direct Kinetic Measurements of a Criegee Intermediate

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Direct Kinetic Measurements of a Criegee Intermediate Print In the earth's troposphere, which blankets the planet surface where we live and breathe, dust particles, gas molecules, water vapor, and sunlight provide the ingredients for a multitude of chemical reactions that can generate effects ranging from clouds and smog to acid rain and climate change. In 1949, chemist Rudolf Criegee proposed a novel chemical pathway for one such reaction, known as ozonolysis: the destruction of alkenes (a type

  2. Direct Kinetic Measurements of a Criegee Intermediate

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Direct Kinetic Measurements of a Criegee Intermediate Print In the earth's troposphere, which blankets the planet surface where we live and breathe, dust particles, gas molecules, water vapor, and sunlight provide the ingredients for a multitude of chemical reactions that can generate effects ranging from clouds and smog to acid rain and climate change. In 1949, chemist Rudolf Criegee proposed a novel chemical pathway for one such reaction, known as ozonolysis: the destruction of alkenes (a type

  3. Direct Kinetic Measurements of a Criegee Intermediate

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Direct Kinetic Measurements of a Criegee Intermediate Print In the earth's troposphere, which blankets the planet surface where we live and breathe, dust particles, gas molecules, water vapor, and sunlight provide the ingredients for a multitude of chemical reactions that can generate effects ranging from clouds and smog to acid rain and climate change. In 1949, chemist Rudolf Criegee proposed a novel chemical pathway for one such reaction, known as ozonolysis: the destruction of alkenes (a type

  4. Direct Kinetic Measurements of a Criegee Intermediate

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Direct Kinetic Measurements of a Criegee Intermediate Print In the earth's troposphere, which blankets the planet surface where we live and breathe, dust particles, gas molecules, water vapor, and sunlight provide the ingredients for a multitude of chemical reactions that can generate effects ranging from clouds and smog to acid rain and climate change. In 1949, chemist Rudolf Criegee proposed a novel chemical pathway for one such reaction, known as ozonolysis: the destruction of alkenes (a type

  5. Dilute group III-V nitride intermediate band solar cells with contact blocking layers

    DOE Patents [OSTI]

    Walukiewicz, Wladyslaw; Yu, Kin Man

    2015-02-24

    An intermediate band solar cell (IBSC) is provided including a p-n junction based on dilute III-V nitride materials and a pair of contact blocking layers positioned on opposite surfaces of the p-n junction for electrically isolating the intermediate band of the p-n junction by blocking the charge transport in the intermediate band without affecting the electron and hole collection efficiency of the p-n junction, thereby increasing open circuit voltage (V.sub.OC) of the IBSC and increasing the photocurrent by utilizing the intermediate band to absorb photons with energy below the band gap of the absorber layers of the IBSC. Hence, the overall power conversion efficiency of a IBSC will be much higher than an conventional single junction solar cell. The p-n junction absorber layers of the IBSC may further have compositionally graded nitrogen concentrations to provide an electric field for more efficient charge collection.

  6. Dilute Group III-V nitride intermediate band solar cells with contact blocking layers

    DOE Patents [OSTI]

    Walukiewicz, Wladyslaw; Yu, Kin Man

    2012-07-31

    An intermediate band solar cell (IBSC) is provided including a p-n junction based on dilute III-V nitride materials and a pair of contact blocking layers positioned on opposite surfaces of the p-n junction for electrically isolating the intermediate band of the p-n junction by blocking the charge transport in the intermediate band without affecting the electron and hole collection efficiency of the p-n junction, thereby increasing open circuit voltage (V.sub.OC) of the IBSC and increasing the photocurrent by utilizing the intermediate band to absorb photons with energy below the band gap of the absorber layers of the IBSC. Hence, the overall power conversion efficiency of a IBSC will be much higher than an conventional single junction solar cell. The p-n junction absorber layers of the IBSC may further have compositionally graded nitrogen concentrations to provide an electric field for more efficient charge collection.

  7. Kondo universality, energy scales, and intermediate valence in plutonium

    SciTech Connect (OSTI)

    Clementyev, E. S.; Mirmelstein, A. V.

    2009-07-15

    On the basis of the concepts of an intermediate-valence (IV) regime, an analysis is carried out of macroscopic properties of the {alpha} and {delta} phases of plutonium, as well as of several model systems based on rare earth elements. Within a single-site approximation (SSA), the characteristic Kondo interaction energy, the f-electron shell occupation number, the effective degeneracy of the ground-state f multiplet, and the crystal field splitting energy are estimated. The ground state in plutonium is considered as a quantum-mechanical superposition of states with different valences. The temperature dependence of the static magnetic susceptibility of {delta} plutonium is calculated. It is shown that {delta} plutonium satisfies the Wilson and Kadowaki-Woods universal relations, whereby it can be classified as a Kondo system. At the same time, the problem of the position of plutonium in the general classification of solids, as well as the problem of the temperature dependence of magnetic susceptibility of {delta} plutonium, remains open. The concept of multiple intermediate valence (MIV) is put forward as a possible means for solving the above problems. The MIV regime is characterized by fluctuations from the basic configuration 3+ to the states 4+ and 2+, which make a fundamental difference between plutonium and 4f electron systems based, say, on samarium.

  8. Effects of Intermediate Ethanol Blends on Legacy Vehicles and...

    Broader source: Energy.gov (indexed) [DOE]

    Intermediate Ethanol Blends on Legacy Vehicles and Small Non-Road Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non-Road Engines, Report 1 Updated Feb 2009...

  9. Fact Sheet: Effects of Intermediate Ethanol Blends | Department of Energy

    Energy Savers [EERE]

    Effects of Intermediate Ethanol Blends Fact Sheet: Effects of Intermediate Ethanol Blends October 7, 2008 - 4:14pm Addthis In August 2007, the U.S. Department of Energy (DOE) initiated a test program to assess the potential impacts of higher intermediate ethanol blends on conventional vehicles and other engines that rely on gasoline. The test program focuses specifically on the effects of intermediate blends of E15 and E20-gasoline blended with 15 and 20 percent ethanol, respectively-on

  10. Thermoelectric power generator with intermediate loop

    DOE Patents [OSTI]

    Bell, Lon E; Crane, Douglas Todd

    2013-05-21

    A thermoelectric power generator is disclosed for use to generate electrical power from heat, typically waste heat. An intermediate heat transfer loop forms a part of the system to permit added control and adjustability in the system. This allows the thermoelectric power generator to more effectively and efficiently generate power in the face of dynamically varying temperatures and heat flux conditions, such as where the heat source is the exhaust of an automobile, or any other heat source with dynamic temperature and heat flux conditions.

  11. Thermoelectric power generator with intermediate loop

    DOE Patents [OSTI]

    Bel,; Lon E.; Crane, Douglas Todd

    2009-10-27

    A thermoelectric power generator is disclosed for use to generate electrical power from heat, typically waste heat. An intermediate heat transfer loop forms a part of the system to permit added control and adjustability in the system. This allows the thermoelectric power generator to more effectively and efficiently generate power in the face of dynamically varying temperatures and heat flux conditions, such as where the heat source is the exhaust of an automobile, or any other heat source with dynamic temperature and heat flux conditions.

  12. Method and apparatus for mounting a dichroic mirror in a microwave powered lamp assembly using deformable tabs

    DOE Patents [OSTI]

    Ury, M.; Sowers, F.; Harper, C.; Love, W.

    1998-11-24

    A microwave powered electrodeless lamp includes an improved screen unit having mesh and solid sections with an internal reflector secured at the juncture of the two sections to reflect light into a light-transmitting chamber defined in the lamp microwave cavity by the reflector and the mesh section. A discharge envelope of a bulb is disposed in the light-transmitting chamber. Light emitted from the envelope is prevented by the reflector from entering the cavity portion bounded by the solid section of the screen. The reflector is mounted in the cavity by tabs formed in the screen unit and bendable into the cavity to define support planes abutting respective surfaces of the reflector. The mesh section and tabs are preferably formed by etching a thin metal sheet. 7 figs.

  13. Method and apparatus for mounting a dichroic mirror in a microwave powered lamp assembly using deformable tabs

    DOE Patents [OSTI]

    Ury, Michael; Sowers, Frank; Harper, Curt; Love, Wayne

    1998-01-01

    A microwave powered electrodeless lamp includes an improved screen unit having mesh and solid sections with an internal reflector secured at the juncture of the two sections to reflect light into a light-transmitting chamber defined in the lamp microwave cavity by the reflector and the mesh section. A discharge envelope of a bulb is disposed in the light-transmitting chamber. Light emitted from the envelope is prevented by the reflector from entering the cavity portion bounded by the solid section of the screen. The reflector is mounted in the cavity by tabs formed in the screen unit and bendable into the cavity to define support planes abutting respective surfaces of the reflector. The mesh section and tabs are preferably formed by etching a thin metal sheet.

  14. Color stable phosphors for LED lamps and methods for preparing them

    SciTech Connect (OSTI)

    Murphy, James Edward; Setlur, Anant Achyut; Camardello, Samuel Joseph

    2013-11-26

    An LED lamp includes a light source configured to emit radiation with a peak intensity at a wavelength between about 250 nm and about 550 nm; and a phosphor composition configured to be radiationally coupled to the light source. The phosphor composition includes particles of a phosphor of formula I, said particles having a coating composition disposed on surfaces thereof; ((Sr.sub.1-zM.sub.z).sub.1-(x+w)A.sub.wCe.sub.x).sub.3(Al.sub.1-ySi.sub.y-)O.sub.4+y+3(x-w)F.sub.1-y-3(x-w) I wherein the coating composition comprises a material selected from aluminum oxide, magnesium oxide, calcium oxide, barium oxide, strontium oxide, zinc oxide, aluminum hydroxide, magnesium hydroxide, calcium hydroxide, barium hydroxide, strontium hydroxide, zinc hydroxide, aluminum phosphate, magnesium phosphate, calcium phosphate, barium phosphate, strontium phosphate, and combinations thereof; and A is Li, NA, K, or Rb, or a combination thereof; M is Ca, Ba, Mg, Zn, or a combination thereof; and 0

  15. Kinetic advantage of controlled intermediate nuclear fusion

    SciTech Connect (OSTI)

    Guo Xiaoming

    2012-09-26

    The dominated process of controlled fusion is to let nuclei gain enough kinetic energy to overcome Coulomb barrier. As a result, a fusion scheme can consider two factors in its design: to increase kinetic energy of nuclei and to alter the Coulomb barrier. Cold Fusion and Hot fusion are all one-factor schemes while Intermediate Fusion is a twofactors scheme. This made CINF kinetically superior. Cold Fusion reduces deuteron-deuteron distance, addressing Coulomb barrier, and Hot Fusion heat up plasma into extreme high temperature, addressing kinetic energy. Without enough kinetic energy made Cold Fusion skeptical. Extreme high temperature made Hot Fusion very difficult to engineer. Because CIFN addresses both factors, CIFN is a more promising technique to be industrialized.

  16. Intermediate Ethanol Blends Catalyst Durability Program

    SciTech Connect (OSTI)

    West, Brian H; Sluder, Scott; Knoll, Keith; Orban, John; Feng, Jingyu

    2012-02-01

    In the summer of 2007, the U.S. Department of Energy (DOE) initiated a test program to evaluate the potential impacts of intermediate ethanol blends (also known as mid-level blends) on legacy vehicles and other engines. The purpose of the test program was to develop information important to assessing the viability of using intermediate blends as a contributor to meeting national goals for the use of renewable fuels. Through a wide range of experimental activities, DOE is evaluating the effects of E15 and E20 - gasoline blended with 15% and 20% ethanol - on tailpipe and evaporative emissions, catalyst and engine durability, vehicle driveability, engine operability, and vehicle and engine materials. This report provides the results of the catalyst durability study, a substantial part of the overall test program. Results from additional projects will be reported separately. The principal purpose of the catalyst durability study was to investigate the effects of adding up to 20% ethanol to gasoline on the durability of catalysts and other aspects of the emissions control systems of vehicles. Section 1 provides further information about the purpose and context of the study. Section 2 describes the experimental approach for the test program, including vehicle selection, aging and emissions test cycle, fuel selection, and data handling and analysis. Section 3 summarizes the effects of the ethanol blends on emissions and fuel economy of the test vehicles. Section 4 summarizes notable unscheduled maintenance and testing issues experienced during the program. The appendixes provide additional detail about the statistical models used in the analysis, detailed statistical analyses, and detailed vehicle specifications.

  17. GLASS AND GLASS-DERIVATIVE SEALS FOR USE IN ENERGY-EFFICIENT FUEL CELLS AND LAMPS

    SciTech Connect (OSTI)

    Scott Misture; Arun Varshneya; Matthew Hall; Sylvia DeCarr; Steve Bancheri

    2004-08-15

    As the project approaches the end of the first year, the materials screening components of the work are ahead of schedule, while all other tasks are on schedule. For solid oxide fuel cells (SOFC), a series of 16 sealing glasses have been prepared and characterized. Traditional melting was used to prepare all of the glasses, and the sol-gel approach has been used to prepare some of the glasses as well as other compositions that might be viable because of the low processing temperatures afforded by the sol-gel method. The glass characterization included measurements of the viscosity and thermal expansion of the glasses, as well as the thermal expansion of the partly crystalline glass ceramics. In addition, the wetting and sintering behavior of all glasses has been measured, as well as the crystallization behavior. The time and temperature at which crystalline phases form from the glasses has been determined for all of the glasses. Each glass ceramic contains at least two crystalline phases, and most of the crystalline phases have been positively identified. Room temperature leak testing has been completed for all sealants, and experiments are in progress to determine the DC electrochemical degradation and degradation in wet hydrogen. The second component of the work, focused on seals for higher-temperature discharge lighting, has focused on determining the phase relations in the yttria--alumina--silica system at various silica levels. Again, traditional melting and sol-gel synthesis have been employed, and the sol-gel method was successful for preparing new phases that were discovered during the work. High temperature diffraction and annealing studies have clarified the phase relations for the samples studies, although additional work remains. Four new phases have been identified and synthesized in pure form, from which full structure solutions were obtained as well as the anisotropic thermal expansion for each phase. Functional testing of lamps are on on-going and will be analyzed during year 2 of the contract.

  18. Comparison of Global Model Results from the Carbon-Land Model Intercomparison Project (C-LAMP) with Free-Air Carbon Dioxide Enrichment (FACE) Manipulation Experiments

    SciTech Connect (OSTI)

    Hoffman, Forrest M; Randerson, Jim; Fung, Inez; Thornton, Peter E; Covey, Curtis; Bonan, Gordon; Running, Steven; Norby, Richard J

    2008-01-01

    Free-Air CO{sub 2} Enrichment (FACE) manipulation experiments have been carried out at a handful of sites to gauge the response of the biosphere to significant increases in atmospheric [CO{sub 2}]. Early synthesis results from four temperate forest sites suggest that the response of net primary productivity (NPP) is conserved across a broad range of productivity with a stimulation at the median of 23 {+-} 2% when the surrounding air [CO{sub 2}] was raised to 550{approx}ppm. As a part of the Carbon-Land Model Intercomparison Project (C-LAMP), a community-based model-data comparison activity, the authors have performed a global FACE modeling experiment using two terrestrial biogeochemistry modules, CLM3-CASA and CLM3-CN, coupled to the National Center for Atmospheric Research (NCAR) Community Climate System Model (CCSM). The two models were forced with an improved NCEP/NCAR reanalysis data set and reconstructed atmospheric [CO{sub 2}] and N deposition data through 1997. At the beginning of 1997 in the transient simulations, global atmospheric [CO{sub 2}] was abruptly raised to 550{approx}ppm, the target value used at the FACE sites. In the control runs, [CO{sub 2}] continued to rise following observations until 2004, after which it was held constant out to year 2100. In both simulations, the last 25 years of reanalysis forcing and a constant N deposition were applied after year 2004. Across all forest biomes, the NPP responses from both models are weaker than those reported for the four FACE sites. Moreover, model responses vary widely geographically with a decreasing trend of NPP increases from 40{sup o}N to 70{sup o}N. For CLM3-CASA, the largest responses occur in arid regions of western North America and central Asia, suggesting that responses are most strongly influenced by increased water use efficiency for this model. CLM3-CN exhibits consistently weaker responses than CLM3-CASA' with the strongest responses in central Asia, but significantly constrained by N limitation. C-LAMP is a sub-project of the Computational Climate Science End Station led by Dr. Warren Washington, using computing resources at the U.S. Department of Energy's National Center for Computational Sciences (NCCS).

  19. Recent advances in modeling fission cross sections over intermediate

    Office of Scientific and Technical Information (OSTI)

    structures (Conference) | SciTech Connect modeling fission cross sections over intermediate structures Citation Details In-Document Search Title: Recent advances in modeling fission cross sections over intermediate structures More accurate fission cross section calculations in presence of underlying intermediate structure are strongly desired. This paper recalls the common approximations used below the fission threshold and quantifies their impact. In particular, an exact expanded R-matrix

  20. Intermediate SCADA Security Training Course Slides (September 2006) |

    Energy Savers [EERE]

    Department of Energy Intermediate SCADA Security Training Course Slides (September 2006) Intermediate SCADA Security Training Course Slides (September 2006) Presentation for Intermediate SCADA Security, SS-2 SANS SCADA Summit, September 28-29, 2006. The class enabled attendees to develop an understanding of tools and methods that can be used to discover and identify system vulnerabilities (CIP-005 R3.2, CIP-005 R4, & CIP-007 R8); develop mitigation strategies for resolving these issues

  1. Effects of Intermediate Ethanol Blends on Legacy Vehicles and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    117 Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non-Road Engines, Report 1 - Updated February 2009 Prepared by Keith Knoll Brian West Wendy Clark...

  2. The low and intermediate mass dilepton and photon results

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Ruan, Lijuan

    2014-10-18

    I summarize and discuss some of the experimental results on the low and intermediate mass dileptons and direct photons presented at Quark Matter 2014.

  3. Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small

    Office of Environmental Management (EM)

    Non-Road Engines, Report 1 … Updated Feb 2009 | Department of Energy Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non-Road Engines, Report 1 … Updated Feb 2009 Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non-Road Engines, Report 1 … Updated Feb 2009 Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non-Road Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non-Road Engines, Report 1 … Updated Feb 2009 PDF

  4. 2014-06-18 Issuance: Test Procedure for Integrated Light-Emitting Diode Lamps; Supplemental Notice of Proposed Rulemaking

    Broader source: Energy.gov [DOE]

    This document is a pre-publication Federal Register Supplemental Notice of Proposed Rulemaking regarding Test Procedures for Integrated Light-Emitting Diode Lamps, as issued by the Deputy Assistant Secretary for Energy Efficiency on June 18, 2014. Though it is not intended or expected, should any discrepancy occur between the document posted here and the document published in the Federal Register, the Federal Register publication controls. This document is being made available through the Internet solely as a means to facilitate the public's access to this document.

  5. 2014-05-05 Issuance: Test Procedures for High-Intensity Discharge Lamps; Supplemental Notice of Proposed Rulemaking

    Broader source: Energy.gov [DOE]

    This document is a pre-publication Federal Register supplemental notice of proposed rulemaking regarding test procedures for high-intesity discharge lamps, as issued by the Deputy Assistant Secretary for Energy Efficiency on May 5, 2014. Though it is not intended or expected, should any discrepancy occur between the document posted here and the document published in the Federal Register, the Federal Register publication controls. This document is being made available through the Internet solely as a means to facilitate the public's access to this document.

  6. 2014-05-16 Issuance: Test Procedures for Integrated Light-Emitting Diode Lamps; Supplemental Notice of Proposed Rulemaking

    Broader source: Energy.gov [DOE]

    This document is a pre-publication Federal Register supplemental notice of proposed rulemaking regarding test procedures for integrated light-emitting diode lamps, as issued by the Deputy Assistant Secretary for Energy Efficiency on May 16, 2014. Though it is not intended or expected, should any discrepancy occur between the document posted here and the document published in the Federal Register, the Federal Register publication controls. This document is being made available through the Internet solely as a means to facilitate the public's access to this document.

  7. Criegee intermediates in the indoor environment. New insights

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Shallcross, D. E.; Taatjes, C. A.; Percival, C. J.

    2014-03-25

    Criegee intermediates are formed in the ozonolysis of alkenes and play an important role in indoor chemistry, notably as a source of OH radicals. Recent studies have shown that these Criegee intermediates react very quickly with NO2, SO2, and carbonyls, and in this study, steady-state calculations are used to inspect the potential impact of these data on indoor chemistry. It is shown that these reactions could accelerate NO3 formation and SO2 removal in the indoor environment significantly. In addition, reaction between Criegee intermediates and halogenated carbonyls could provide a significant loss process indoors, where currently one does not exist.

  8. Is Androgen Deprivation Therapy Necessary in All Intermediate-Risk Prostate Cancer Patients Treated in the Dose Escalation Era?

    SciTech Connect (OSTI)

    Castle, Katherine O.; Hoffman, Karen E.; Levy, Lawrence B.; Lee, Andrew K.; Choi, Seungtaek; Nguyen, Quynh N.; Frank, Steven J.; Pugh, Thomas J.; McGuire, Sean E.; Kuban, Deborah A.

    2013-03-01

    Purpose: The benefit of adding androgen deprivation therapy (ADT) to dose-escalated radiation therapy (RT) for men with intermediate-risk prostate cancer is unclear; therefore, we assessed the impact of adding ADT to dose-escalated RT on freedom from failure (FFF). Methods: Three groups of men treated with intensity modulated RT or 3-dimensional conformal RT (75.6-78 Gy) from 1993-2008 for prostate cancer were categorized as (1) 326 intermediate-risk patients treated with RT alone, (2) 218 intermediate-risk patients treated with RT and ?6 months of ADT, and (3) 274 low-risk patients treated with definitive RT. Median follow-up was 58 months. Recursive partitioning analysis based on FFF using Gleason score (GS), T stage, and pretreatment PSA concentration was applied to the intermediate-risk patients treated with RT alone. The Kaplan-Meier method was used to estimate 5-year FFF. Results: Based on recursive partitioning analysis, intermediate-risk patients treated with RT alone were divided into 3 prognostic groups: (1) 188 favorable patients: GS 6, ?T2b or GS 3+4, ?T1c; (2) 71 marginal patients: GS 3+4, T2a-b; and (3) 68 unfavorable patients: GS 4+3 or T2c disease. Hazard ratios (HR) for recurrence in each group were 1.0, 2.1, and 4.6, respectively. When intermediate-risk patients treated with RT alone were compared to intermediate-risk patients treated with RT and ADT, the greatest benefit from ADT was seen for the unfavorable intermediate-risk patients (FFF, 74% vs 94%, respectively; P=.005). Favorable intermediate-risk patients had no significant benefit from the addition of ADT to RT (FFF, 94% vs 95%, respectively; P=.85), and FFF for favorable intermediate-risk patients treated with RT alone approached that of low-risk patients treated with RT alone (98%). Conclusions: Patients with favorable intermediate-risk prostate cancer did not benefit from the addition of ADT to dose-escalated RT, and their FFF was nearly as good as patients with low-risk disease. In patients with GS 4+3 or T2c disease, the addition of ADT to dose-escalated RT did improve FFF.

  9. Effects of intermediate mass black holes on nuclear star clusters

    SciTech Connect (OSTI)

    Mastrobuono-Battisti, Alessandra; Perets, Hagai B.; Loeb, Abraham

    2014-11-20

    Nuclear star clusters (NSCs) are dense stellar clusters observed in galactic nuclei, typically hosting a central massive black hole. Here we study the possible formation and evolution of NSCs through the inspiral of multiple star clusters hosting intermediate mass black holes (IMBHs). Using an N-body code, we examine the dynamics of the IMBHs and their effects on the NSC. We find that IMBHs inspiral to the core of the newly formed NSC and segregate there. Although the IMBHs scatter each other and the stars, none of them is ejected from the NSC. The IMBHs are excited to high eccentricities and their radial density profile develops a steep power-law cusp. The stars also develop a power-law cusp (instead of the central core that forms in their absence), but with a shallower slope. The relaxation rate of the NSC is accelerated due to the presence of IMBHs, which act as massive perturbers. This in turn fills the loss cone and boosts the tidal disruption rate of stars both by the MBH and the IMBHs to a value excluded by rate estimates based on current observations. Rate estimates of tidal disruptions can therefore provide a cumulative constraint on the existence of IMBHs in NSCs.

  10. Intermediate connector for stacked organic light emitting devices

    DOE Patents [OSTI]

    D'Andrade, Brian

    2013-02-12

    A device is provided, having an anode, a cathode, and an intermediate connector disposed between the anode and the cathode. A first organic layer including an emissive sublayer is disposed between the anode and the intermediate connector, and a second including an emissive sublayer is disposed between the intermediate connector and the cathode. The intermediate connector includes a first metal having a work function lower than 4.0 eV and a second metal having a work function lower than 5.0 eV. The work function of the first metal is at least 0.5 eV less than the work function of the second metal. The first metal is in contact with a sublayer of the second organic layer that includes a material well adapted to receive holes from a low work function metal.

  11. Kondo universality, energy scales, and intermediate valence in...

    Office of Scientific and Technical Information (OSTI)

    On the basis of the concepts of an intermediate-valence (IV) regime, an analysis is carried out of macroscopic properties of the alpha and delta phases of plutonium, as well as ...

  12. Syngas Conversion to Hydrocarbon Fuels through Mixed Alcohol Intermediates

    SciTech Connect (OSTI)

    Dagle, Robert A.; Lebarbier, Vanessa M.; Albrecht, Karl O.; Li, Jinjing; Taylor, Charles E.; Bao, Xinhe; Wang, Yong

    2013-05-13

    Synthesis gas (syngas) can be used to synthesize a variety of fuels and chemicals. Domestic transportation and military operational interests have driven continued focus on domestic syngas-based fuels production. Liquid transportation fuels may be made from syngas via four basic processes: 1) higher alcohols, 2) Fischer-Tropsch (FT), 3) methanol-to-gasoline (MTG), and 4) methanol-to-olefins (MTO) and olefins-to-gasoline/distillate (MOGD). Compared to FT and higher alcohols, MTG and MTO-MOGD have received less attention in recent years. Due to the high capital cost of these synthetic fuel plants, the production cost of the finished fuel cannot compete with petroleum-derived fuel. Pacific Northwest National Laboratory has recently evaluated one way to potentially reduce capital cost and overall production cost for MTG by combining the methanol and MTG syntheses in a single reactor. The concept consists of mixing the conventional MTG catalyst (i.e. HZSM-5) with an alcohol synthesis catalyst. It was found that a methanol synthesis catalyst, stable at high temperature (i.e. Pd/ZnO/Al2O3) [1], when mixed with ZSM-5, was active for syngas conversion. Relatively high syngas conversion can be achieved as the equilibrium-driven conversion limitations for methanol and dimethyl ether are removed as they are intermediates to the final hydrocarbon product. However, selectivity control was difficult to achieve as formation of undesirable durene and light hydrocarbons was problematic [2]. The objective of the present study was thus to evaluate other potential composite catalyst systems and optimize the reactions conditions for the conversion of syngas to hydrocarbon fuels, through the use of mixed alcohol intermediates. Mixed alcohols are of interest as they have recently been reported to produce higher yields of gasoline compared to methanol [3]. 1. Lebarbier, V.M., Dagle, R.A., Kovarik, L., Lizarazo-Adarme, J.A., King, D.L., Palo, D.R., Catalyst Science & Technology, 2012, 2, 2116-2127. 2. Zhu, Y., Jones, S.B., Biddy, M.J., Dagle, R.A., Palo, D.P., Bioresource Technology, 2012, 117, 341-351. 3. Gujar, A.C., Guda, V.K., Nolan, M., Yan W., Toghiani, H., White, M.G., Applied Catalysis A: General, 2009, 363, 115-121.

  13. Structures of the Ribosome in Intermediate States of Ratcheting

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Structures of the Ribosome in Intermediate States of Ratcheting Structures of the Ribosome in Intermediate States of Ratcheting Print Wednesday, 31 March 2010 00:00 Protein synthesis is conducted by the ribosome: a megadalton sized complex responsible for making proteins from amino acids. Translation-the conversion of a three letter nucleic acid code (a codon) in a messenger RNA (mRNA) into an amino acid sequence-is essential to gene expression. For this reason, translational accuracy is

  14. A Thermoelectric Generator with an Intermediate Heat Exchanger for

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Automotive Waste Heat Recovery System | Department of Energy A Thermoelectric Generator with an Intermediate Heat Exchanger for Automotive Waste Heat Recovery System A Thermoelectric Generator with an Intermediate Heat Exchanger for Automotive Waste Heat Recovery System Poster presented at the 16th Directions in Engine-Efficiency and Emissions Research (DEER) Conference in Detroit, MI, September 27-30, 2010. PDF icon p-20_kim.pdf More Documents & Publications Low and high Temperature

  15. Recent advances in modeling fission cross sections over intermediate

    Office of Scientific and Technical Information (OSTI)

    structures (Conference) | SciTech Connect modeling fission cross sections over intermediate structures Citation Details In-Document Search Title: Recent advances in modeling fission cross sections over intermediate structures × You are accessing a document from the Department of Energy's (DOE) SciTech Connect. This site is a product of DOE's Office of Scientific and Technical Information (OSTI) and is provided as a public service. Visit OSTI to utilize additional information resources in

  16. Ubiquity of linear resistivity at intermediate temperature in bad metals

    Office of Scientific and Technical Information (OSTI)

    (Journal Article) | DOE PAGES Ubiquity of linear resistivity at intermediate temperature in bad metals Title: Ubiquity of linear resistivity at intermediate temperature in bad metals Authors: Boyd, G. R. ; Zlatić, V. ; Freericks, J. K. Publication Date: 2015-02-20 OSTI Identifier: 1181226 Grant/Contract Number: SC0007091; FG02-08ER46542 Type: Publisher's Accepted Manuscript Journal Name: Physical Review B Additional Journal Information: Journal Volume: 91; Journal Issue: 7; Journal ID: ISSN

  17. Intermediate depth burial of classified transuranic wastes in arid alluvium

    SciTech Connect (OSTI)

    Cochran, J.R. [Sandia National Labs., Albuquerque, NM (United States). Environmental Risk and Decision Analysis Dept.; Crowe, B.M. [Los Alamos National Lab., NM (United States). Geologic Integration Group; Di Sanza, F. [Dept. of Energy, Las Vegas, NV (United States). Nevada Operations Office

    1999-04-01

    Intermediate depth disposal operations were conducted by the US Department of Energy (DOE) at the DOE`s Nevada Test Site (NTS) from 1984 through 1989. These operations emplaced high-specific activity low-level wastes (LLW) and limited quantities of classified transuranic (TRU) wastes in 37 m (120-ft) deep, Greater Confinement Disposal (GCD) boreholes. The GCD boreholes are 3 m (10 ft) in diameter and founded in a thick sequence of arid alluvium. The bottom 15 m (50 ft) of each borehole was used for waste emplacement and the upper 21 m (70 ft) was backfilled with native alluvium. The bottom of each GCD borehole is almost 200 m (650 ft) above the water table. The GCD boreholes are located in one of the most arid portions of the US, with an average precipitation of 13 cm (5 inches) per year. The limited precipitation, coupled with generally warm temperatures and low humidities results in a hydrologic system dominated by evapotranspiration. The US Environmental Protection Agency`s (EPA`s) 40 CFR 191 defines the requirements for protection of human health from disposed TRU wastes. This EPA standard sets a number of requirements, including probabilistic limits on the cumulative releases of radionuclides to the accessible environment for 10,000 years. The DOE Nevada Operations Office (DOE/NV) has contracted with Sandia National Laboratories (Sandia) to conduct a performance assessment (PA) to determine if the TRU wastes emplaced in the GCD boreholes complies with the EPA`s 40 CFR 191 requirements. This paper describes DOE`s actions undertaken to evaluate whether the TRU wastes in the GCD boreholes will, or will not, endanger human health. Based on preliminary modeling, the TRU wastes in the GCD boreholes meet the EPA`s requirements, and are, therefore, protective of human health.

  18. The Intermediate Higgs (Journal Article) | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    The Intermediate Higgs Citation Details In-Document Search Title: The Intermediate Higgs Authors: Katz, Emanuel ; /Boston U. /SLAC ; Nelson, Ann E. ; /Washington U., Seattle ; Walker, Devin G.E. ; /Harvard U. Publication Date: 2005-06-20 OSTI Identifier: 890349 Report Number(s): SLAC-PUB-11111 hep-ph/0504252 DOE Contract Number: AC02-76SF00515 Resource Type: Journal Article Resource Relation: Journal Name: JHEP 0508:074,2005 Research Org: Stanford Linear Accelerator Center (SLAC) Sponsoring Org:

  19. DOE CALiPER Program, Report 20.1 Subjective Evaluation of Beam Quality, Shadow Quality, and Color Quality for LED PAR38 Lamps

    SciTech Connect (OSTI)

    Royer, Michael P.; Poplawski, Michael E.; Miller, Naomi J.

    2013-10-01

    This report focuses on human-evaluated characteristics, including beam quality, shadow quality, and color quality. Using a questionnaire that included rank ordering, opinions on 27 of the Report 20 PAR38 lamps were gathered during a demonstration event for members of the local Illuminating Engineering Society (IES) chapter. This was not a rigorous scientific experiment, and the data should not be extrapolated beyond the scope of the demonstration. The results suggest that many of the LED products compared favorably to halogen PAR38 benchmarks in all attributes considered. LED lamps using a single-emitter design were generally preferred for their beam quality and shadow quality, and the IES members ranking of color quality did not always match the rank according to the color rendering index (CRI).

  20. CALiPER Report 20.1: Subjective Evaluation of Beam Quality, Shadow Quality, and Color Quality for LED PAR38 Lamps

    SciTech Connect (OSTI)

    None, None

    2013-11-07

    This report focuses on human-evaluated characteristics, including beam quality, shadow quality, and color quality. Using a questionnaire that included rank-ordering, opinions on 27 of the Report 20 PAR38 lamps were gathered during a demonstration event for members of the local Illuminating Engineering Society (IES) chapter. This was not a rigorous scientific experiment, and the data should not be extrapolated beyond the scope of the demonstration. The results suggest that many of the LED products compared favorably to halogen PAR38 benchmarks in all attributes considered. LED lamps using a single-emitter design were generally preferred for their beam quality and shadow quality, and the IES members' ranking of color quality did not always match the rank according to the color rendering index (CRI).

  1. Organic Flash Cycles for Intermediate and High Temperature Waste

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Reclamation - Energy Innovation Portal Industrial Technologies Industrial Technologies Energy Storage Energy Storage Building Energy Efficiency Building Energy Efficiency Find More Like This Return to Search Organic Flash Cycles for Intermediate and High Temperature Waste Reclamation Lawrence Berkeley National Laboratory Contact LBL About This Technology Publications: PDF Document Publication LBNL Commercial Analysis Report (682 KB) Technology Marketing Summary Researchers at Berkeley Lab

  2. Demonstration of LED Retrofit Lamps at an Exhibit of 19th Century Photography at the Getty Museum

    SciTech Connect (OSTI)

    Miller, Naomi J.; Druzik, Jim

    2012-03-02

    This document is a report of observations and results obtained from a lighting demonstration project conducted under the U.S. Department of Energy (DOE) GATEWAY Demonstration Program. The program supports demonstrations of high-performance solid-state lighting (SSL) products in order to develop empirical data and experience with in-the-field applications of this advanced lighting technology. The DOE GATEWAY Demonstration Program focuses on providing a source of independent, third-party data for use in decision-making by lighting users and professionals; this data should be considered in combination with other information relevant to the particular site and application under examination. Each GATEWAY Demonstration compares SSL products against the incumbent technologies used in that location. Depending on available information and circumstances, the SSL product may also be compared to alternate lighting technologies. Though products demonstrated in the GATEWAY program may have been prescreened for performance, DOE does not endorse any commercial product or in any way guarantee that users will achieve the same results through use of these products. This report reviews the installation and use of LED PAR38 lamps to light a collection of toned albument photographic prints at the J. Paul Getty Museum in Malibu, California. Research results provided by the Getty Conservation Institute are incorporated and discussed.

  3. Contribution to the numerical study of turbulence in high intensity discharge lamps

    SciTech Connect (OSTI)

    Kaziz, S.; Ben Ahmed, R.; Helali, H.; Gazzah, H.; Charrada, K. [Unite d'Etude des Milieux Ionises et Reactifs, IPEIM, 5019 route de Kairouan Monastir (Tunisia)

    2011-07-15

    We present in this paper a comparison between results obtained with a laminar and turbulent models for high-pressure mercury arc. The two models are based on the resolution of bidimensional time-dependent equations by a semi-implicit finite-element code. The numerical computation of turbulent model is solved with large eddy simulation model; this approach takes into account the various scales of turbulence by a filtering method on each scale. The results show the quantitative influence of turbulence on the flow fields and also the difference between laminar and turbulent effects on the dynamic thermal behaviour and on the characteristics of the discharge.

  4. Solid-state lighting :lamp targets and implications for the semiconductor chip.

    SciTech Connect (OSTI)

    Tsao, Jeffrey Yeenien

    2003-01-01

    Once again GaAs MANTECH (with III-Vs Review acting as media sponsor) promises to deliver high quality papers covering all aspects of compound semiconductor manufacturing, with speakers from leading-edge equipment, epiwafer, and device suppliers. Since its launch in 1986, GaAs MANTECH has consistently been one of the highlight events of the conference calendar. Coverage includes all compound-based semiconductors, not just GaAs. With an excellent technical program comprising of almost 80 papers and expanded workshop sessions, the 2003 event should prove the best ever. As in previous years, an Interactive Forum and Ugly Picture Contest will be included. A major attraction will be the associated exhibition, with more than 70 suppliers expected to participate.

  5. Hydrocyclone Separation of Targeted Algal Intermediates and Products

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Algal Feedstocks Research and Development Richard Brotzman Argonne National Laboratory 1.3.3.100: Hydrocyclone Separation of Targeted Algal Intermediates and Products This presentation does not contain any proprietary, confidential, or otherwise restricted information 2 Project Goals  Evaluate an energy-efficient, separation process - Technology: Hydrocyclone separation of components in a fluid mixture - Main application: Dewatering of algal cultures  Program tasks - Establish baseline

  6. Expanded Intermediate-State Structure of a Bacterial Mechanosensitive

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Channel Expanded Intermediate-State Structure of a Bacterial Mechanosensitive Channel Human and other animals rely on the senses of touch and hearing to perceive mechanical stimuli, a process known as mechanosensation. Bacteria also have the ability to sense mechanical forces through mechanosensitive channels located in their plasma membrane. These channels open and close in response to membrane tension and serve as "pressure relief valves" that protect bacteria from bursting due

  7. MCNP5 CRITICALITY VALIDATION AND BIAS FOR INTERMEDIATE ENRICHED URANIUM SYSTEMS

    SciTech Connect (OSTI)

    FINFROCK SH

    2009-12-10

    The purpose of this analysis is to validate the Monte Carlo N-Particle 5 (MCNP5) code Version 1.40 (LA-UR-03-1987, 2005) and its cross-section database for k-code calculations of intermediate enriched uranium systems on INTEL{reg_sign} processor based PC's running any version of the WINDOWS operating system. Configurations with intermediate enriched uranium were modeled with the moderator range of 39 {le} H/Fissile {le} 1438. See Table 2-1 for brief descriptions of selected cases and Table 3-1 for the range of applicability for this validation. A total of 167 input cases were evaluated including bare and reflected systems in a single body or arrays. The 167 cases were taken directly from the previous (Version 4C [Lan 2005]) validation database. Section 2.0 list data used to calculate k-effective (k{sub eff}) for the 167 experimental criticality benchmark cases using the MCNP5 code v1.40 and its cross section database. Appendix B lists the MCNP cross-section database entries validated for use in evaluating the intermediate enriched uranium systems for criticality safety. The dimensions and atom densities for the intermediate enriched uranium experiments were taken from NEA/NSC/DOC(95)03, September 2005, which will be referred to as the benchmark handbook throughout the report. For these input values, the experimental benchmark k{sub eff} is approximately 1.0. The MCNP validation computer runs ran to an accuracy of approximately {+-} 0.001. For the cases where the reported benchmark k{sub eff} was not equal to 1.0000 the MCNP calculational results were normalized. The difference between the MCNP validation computer runs and the experimentally measured k{sub eff} is the MCNP5 v1.40 bias. The USLSTATS code (ORNL 1998) was utilized to perform the statistical analysis and generate an acceptable maximum k{sub eff} limit for calculations of the intermediate enriched uranium type systems.

  8. Intermediates and the folding of proteins L and G

    SciTech Connect (OSTI)

    Brown, Scott; Head-Gordon, Teresa

    2003-07-01

    We use a minimalist protein model, in combination with a sequence design strategy, to determine differences in primary structure for proteins L and G that are responsible for the two proteins folding through distinctly different folding mechanisms. We find that the folding of proteins L and G are consistent with a nucleation-condensation mechanism, each of which is described as helix-assisted {beta}-1 and {beta}-2 hairpin formation, respectively. We determine that the model for protein G exhibits an early intermediate that precedes the rate-limiting barrier of folding and which draws together misaligned secondary structure elements that are stabilized by hydrophobic core contacts involving the third {beta}-strand, and presages the later transition state in which the correct strand alignment of these same secondary structure elements is restored. Finally the validity of the targeted intermediate ensemble for protein G was analyzed by fitting the kinetic data to a two-step first order reversible reaction, proving that protein G folding involves an on-pathway early intermediate, and should be populated and therefore observable by experiment.

  9. CALiPER Report 20.4: Lumen and Chromaticity Maintenance of LED PAR38 Lamps Operated in Steady-State Conditions

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    20.4: Lumen and Chromaticity Maintenance of LED PAR38 Lamps Operated in Steady-State Conditions December 2014 Prepared for: Solid-State Lighting Program Building Technologies Office Office of Energy Efficiency and Renewable Energy U.S. Department of Energy Prepared by: Pacific Northwest National Laboratory PNNL-SA-23988 Preface The U.S. Department of Energy (DOE) CALiPER program has been purchasing and testing general illumination solid-state lighting (SSL) products since 2006. CALiPER relies on

  10. General Service LED Lamps

    SciTech Connect (OSTI)

    2012-04-01

    Solid-state lighting program technology fact sheet that compares general service incandescent lamps—i.e., light bulbs—to LED and CFL alternatives.

  11. Phosphors for LED lamps

    DOE Patents [OSTI]

    Murphy, James Edward; Manepalli, Satya Kishore; Kumar, Prasanth Nammalwar

    2013-08-13

    A phosphor, a phosphor blend including the phosphor, a phosphor prepared by a process, and a lighting apparatus including the phosphor blend are disclosed. The phosphor has the formula (Ca.sub.1-p-qCe.sub.pK.sub.q).sub.xSc.sub.y(Si.sub.1-rGa.sub.r).sub.zO.su- b.12+.delta. or derived from a process followed using disclosed amounts of reactants. In the formula, (0

  12. Structures of the Ribosome in Intermediate States of Ratcheting

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Structures of the Ribosome in Intermediate States of Ratcheting Print Protein synthesis is conducted by the ribosome: a megadalton sized complex responsible for making proteins from amino acids. Translation-the conversion of a three letter nucleic acid code (a codon) in a messenger RNA (mRNA) into an amino acid sequence-is essential to gene expression. For this reason, translational accuracy is imperative, and has a very low error rate of 10-3 to 10-4. Translation and other manipulations of

  13. Structures of the Ribosome in Intermediate States of Ratcheting

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Structures of the Ribosome in Intermediate States of Ratcheting Print Protein synthesis is conducted by the ribosome: a megadalton sized complex responsible for making proteins from amino acids. Translation-the conversion of a three letter nucleic acid code (a codon) in a messenger RNA (mRNA) into an amino acid sequence-is essential to gene expression. For this reason, translational accuracy is imperative, and has a very low error rate of 10-3 to 10-4. Translation and other manipulations of

  14. Structures of the Ribosome in Intermediate States of Ratcheting

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Structures of the Ribosome in Intermediate States of Ratcheting Print Protein synthesis is conducted by the ribosome: a megadalton sized complex responsible for making proteins from amino acids. Translation-the conversion of a three letter nucleic acid code (a codon) in a messenger RNA (mRNA) into an amino acid sequence-is essential to gene expression. For this reason, translational accuracy is imperative, and has a very low error rate of 10-3 to 10-4. Translation and other manipulations of

  15. Structures of the Ribosome in Intermediate States of Ratcheting

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Structures of the Ribosome in Intermediate States of Ratcheting Print Protein synthesis is conducted by the ribosome: a megadalton sized complex responsible for making proteins from amino acids. Translation-the conversion of a three letter nucleic acid code (a codon) in a messenger RNA (mRNA) into an amino acid sequence-is essential to gene expression. For this reason, translational accuracy is imperative, and has a very low error rate of 10-3 to 10-4. Translation and other manipulations of

  16. Structures of the Ribosome in Intermediate States of Ratcheting

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Structures of the Ribosome in Intermediate States of Ratcheting Print Protein synthesis is conducted by the ribosome: a megadalton sized complex responsible for making proteins from amino acids. Translation-the conversion of a three letter nucleic acid code (a codon) in a messenger RNA (mRNA) into an amino acid sequence-is essential to gene expression. For this reason, translational accuracy is imperative, and has a very low error rate of 10-3 to 10-4. Translation and other manipulations of

  17. Structures of the Ribosome in Intermediate States of Ratcheting

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Structures of the Ribosome in Intermediate States of Ratcheting Print Protein synthesis is conducted by the ribosome: a megadalton sized complex responsible for making proteins from amino acids. Translation-the conversion of a three letter nucleic acid code (a codon) in a messenger RNA (mRNA) into an amino acid sequence-is essential to gene expression. For this reason, translational accuracy is imperative, and has a very low error rate of 10-3 to 10-4. Translation and other manipulations of

  18. Intermediate band solar cells: Recent progress and future directions

    SciTech Connect (OSTI)

    Okada, Y. Tamaki, R.; Farrell, D. J.; Yoshida, K.; Ahsan, N.; Shoji, Y.; Sogabe, T.; Ekins-Daukes, N. J. Yoshida, M.; Pusch, A.; Hess, O.; Phillips, C. C.; Kita, T.; Guillemoles, J.-F.

    2015-06-15

    Extensive literature and publications on intermediate band solar cells (IBSCs) are reviewed. A detailed discussion is given on the thermodynamics of solar energy conversion in IBSCs, the device physics, and the carrier dynamics processes with a particular emphasis on the two-step inter-subband absorption/recombination processes that are of paramount importance in a successful implementation high-efficiency IBSC. The experimental solar cell performance is further discussed, which has been recently demonstrated by using highly mismatched alloys and high-density quantum dot arrays and superlattice. IBSCs having widely different structures, materials, and spectral responses are also covered, as is the optimization of device parameters to achieve maximum performance.

  19. Digital intermediate frequency QAM modulator using parallel processing

    DOE Patents [OSTI]

    Pao, Hsueh-Yuan (Livermore, CA); Tran, Binh-Nien (San Ramon, CA)

    2008-05-27

    The digital Intermediate Frequency (IF) modulator applies to various modulation types and offers a simple and low cost method to implement a high-speed digital IF modulator using field programmable gate arrays (FPGAs). The architecture eliminates multipliers and sequential processing by storing the pre-computed modulated cosine and sine carriers in ROM look-up-tables (LUTs). The high-speed input data stream is parallel processed using the corresponding LUTs, which reduces the main processing speed, allowing the use of low cost FPGAs.

  20. The 1994 intermediate reline of H-3 furnace

    SciTech Connect (OSTI)

    James, J.D.; Nanavati, K.S.; Spirko, E.J.; Wakelin, D.H.

    1995-12-01

    LTV Steel`s Indiana Harbor Works H-3 Blast Furnace was rebuilt in 1988 to provide reliable operations at high production rates without damage to the shell for an overall campaign. This Rebuild included: (1) complete bosh and partial stack shell replacement; (2) a spray cooled carbon bosh; (3) a row of staves at the mantle and six rows of stack staves, all stack staves had noses (ledges at the top of the stave) with the exception of row 5; (4) silicon carbide filled semi graphite brick for the bosh, silicon carbide brick from the mantle area and to the top of stave row No. 1, super duty brick in front of the remaining staves and phosphate bonded high alumina brick in the upper stack; (5) movable throat armor; (6) upgraded instrumentation to follow furnace operation and lining wear occurring in the furnace. No work was done to the hearth walls and bottom, since these had been replaced in 1982 with a first generation graphite cooled design and has experienced 7.7 million NTHM. The furnace was blown in November 18, 1988 and operated through September 3, 1994, at which time it was blown down for its first intermediate repair after 7.85 million NTHM. This paper summarizes the operation of the furnace and then discusses the major aspects of the 1994 intermediate repair.

  1. Peptide concentration alters intermediate species in amyloid ? fibrillation kinetics

    SciTech Connect (OSTI)

    Garvey, M., E-mail: megan.garvey@molbiotech.rwth-aachen.de [Max-Planck Research Unit for Enzymology of Protein Folding, Weinbergweg 22, 06120 Halle (Saale) (Germany); Morgado, I., E-mail: immorgado@ualg.pt [Max-Planck Research Unit for Enzymology of Protein Folding, Weinbergweg 22, 06120 Halle (Saale) (Germany)

    2013-04-12

    Highlights: ? A?(140) aggregation in vitro has been monitored at different concentrations. ? A?(140) fibrillation does not always follow conventional kinetic mechanisms. ? We demonstrate non-linear features in the kinetics of A?(140) fibril formation. ? At high A?(140) concentrations secondary processes dictate fibrillation speed. ? Intermediate species may play significant roles on final amyloid fibril development. -- Abstract: The kinetic mechanism of amyloid aggregation remains to be fully understood. Investigations into the species present in the different kinetic phases can assist our comprehension of amyloid diseases and further our understanding of the mechanism behind amyloid ? (A?) (140) peptide aggregation. Thioflavin T (ThT) fluorescence and transmission electron microscopy (TEM) have been used in combination to monitor A?(140) aggregation in vitro at both normal and higher than standard concentrations. The observed fibrillation behaviour deviates, in several respects, from standard concepts of the nucleationpolymerisation models and shows such features as concentration-dependent non-linear effects in the assembly mechanism. A?(140) fibrillation kinetics do not always follow conventional kinetic mechanisms and, specifically at high concentrations, intermediate structures become populated and secondary processes may further modify the fibrillation mechanism.

  2. HOx radical chemistry in oxidation flow reactors with low-pressure mercury lamps systematically examined by modeling

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Peng, Z.; Day, D. A.; Stark, H.; Li, R.; Palm, B. B.; Brune, W. H.; Jimenez, J. L.

    2015-04-20

    Oxidation flow reactors (OFRs) using OH produced from low-pressure Hg lamps at 254 nm (OFR254) or both 185 and 254 nm (OFR185) are commonly used in atmospheric chemistry and other fields. OFR254 requires the addition of externally formed O3 since OH is formed from O3 photolysis, while OFR185 does not since O2 can be photolyzed to produce O3 and OH can also be formed from H2O photolysis. In this study, we use a plug-flow kinetic model to investigate OFR properties under a very wide range of conditions applicable to both field and laboratory studies. We show that the radical chemistrymore » in OFRs can be characterized as a function of UV light intensity, H2O concentration, and total external OH reactivity (OHRext, e.g., from VOCs, NOx, and SO2). OH exposure is decreased by added external OH reactivity. OFR185 is especially sensitive to this effect at low UV intensity due to low primary OH production. OFR254 can be more resilient against OH suppression at high injected O3 (e.g., 70 ppm), as a larger primary OH source from O3, as well as enhanced recycling of HO2 to OH, make external perturbations to the radical chemistry less significant. However if the external OH reactivity in OFR254 is much larger than OH reactivity from injected O3, OH suppression can reach two orders of magnitude. For a typical input of 7 ppm O3 (OHRO3 = 10 s−1) ten-fold OH suppression is observed at OHRext ∼ 100 s−1, which is similar or lower than used in many laboratory studies. This finding may have important implications for the interpretation of past laboratory studies, as applying OHexp measurements acquired under different conditions could lead to over an order-of-magnitude error in the estimated OHexp. The uncertainties of key model outputs due to uncertainty in all rate constants and absorption cross-sections in the model are within ± 25% for OH exposure and within ± 60% for other parameters. These uncertainties are small relative to the dynamic range of outputs. Uncertainty analysis shows that most of the uncertainty is contributed by photolysis rates of O3, O2, and H2O and reactions of OH and HO2 with themselves or with some abundant species, i.e., O3 and H2O2. Using HOx-recycling vs. destructive external OH reactivity only leads to small changes in OHexp under most conditions. Changing the identity (rate constant) of external OH reactants can result in substantial changes in OHexp due to different reductions in OH suppression as the reactant is consumed. We also report two equations for estimating OH exposure in OFR254. We find that the equation estimating OHexp from measured O3 consumption performs better than an alternative equation that does not use it, and thus recommend measuring both input and output O3 concentrations in OFR254 experiments. This study contributes to establishing a firm and systematic understanding of the gas-phase HOx and Ox chemistry in these reactors, and enables better experiment planning and interpretation as well as improved design of future reactors.« less

  3. Intermediate hearth repair technique at Thyssen Stahl AG

    SciTech Connect (OSTI)

    Kowalski, W.; Bachhofen, H.J.; Ruether, P.; Ballewski, T.

    1996-12-31

    Nowadays various techniques for the fastest possible intermediate repair and/or emplacement of refractory materials above the tuyere level allow a significant extension of furnace campaign life. The latter are hence now exclusively determined by the service life of the hearth. The improvement of hearth monitoring and the estimation of residual brick strength of the refractory lining on the basis of temperature measurements in the hearth enable the location of individual zones of premature wear. These measurement methods, which were developed by Thyssen Stahl AG, aid the decision to undertake selective repair of the hearth. Three areas of repair are differentiated: taphole zone; hearth wall, localized; and hearth wall, extensive. This hearth repair method is described in this report using the example of hearth refurbishing blast furnace 8, Hamborn.

  4. EVALUATION OF TRANSPORTATION OPTIONS FOR INTERMEDIATE NON DESTRUCTIVE EXAMINATIONS

    SciTech Connect (OSTI)

    Case, Susan; Hoggard, Gary

    2014-07-01

    Idaho National Laboratory (INL) shipments of irradiated experiments from the Advanced Test Reactor (ATR) to the Hot Fuels Examination Facility (HFEF) have historically been accomplished using the General Electric Model 2000 (GE 2000) Type B shipping container. Battelle Energy Alliance (BEA) concerns regarding the future availability and leasing and handling costs associated with the GE 2000 cask have warranted an evaluation of alternative shipping options. One or more of these shipping options may be utilized to perform non destructive examinations (NDE) such as neutron radiography and precision gamma scans of irradiated experiments at HFEF and then return the experiments to ATR for further irradiation, hereafter referred to as “intermediate NDE.”

  5. Elastic Hadron Scattering on Li Isotopes at Intermediate Energies

    SciTech Connect (OSTI)

    Zhusupov, M.A.; Imambekov, O.; Ibraeva, E.T.

    2005-01-01

    The elastic scattering of hadrons (protons, charged pions, and positively charged kaons) on {sup 6,7,8}Li nuclei is analyzed on the basis of Glauber-Sitenko diffraction theory. A few nuclear-wave-function versions found within two- and three-particle potential cluster models are used in the calculations. It is shown that the application of these wave functions in diffraction theory makes it possible to describe adequately the experimental differential cross sections and analyzing powers in hadron scattering at intermediate energies. In this study, particular attention is given to a comparison of the scattering of different particles on the same target nucleus, as well as to a comparison of scattering of particles of the same sort on different target nuclei.

  6. Intermediate-band photosensitive device with quantum dots having tunneling barrier embedded in organic matrix

    DOE Patents [OSTI]

    Forrest, Stephen R. (Ann Arbor, MI)

    2008-08-19

    A plurality of quantum dots each have a shell. The quantum dots are embedded in an organic matrix. At least the quantum dots and the organic matrix are photoconductive semiconductors. The shell of each quantum dot is arranged as a tunneling barrier to require a charge carrier (an electron or a hole) at a base of the tunneling barrier in the organic matrix to perform quantum mechanical tunneling to reach the respective quantum dot. A first quantum state in each quantum dot is between a lowest unoccupied molecular orbital (LUMO) and a highest occupied molecular orbital (HOMO) of the organic matrix. Wave functions of the first quantum state of the plurality of quantum dots may overlap to form an intermediate band.

  7. Cross sections for electron scattering by propane in the low- and intermediate-energy ranges

    SciTech Connect (OSTI)

    Souza, G. L. C. de; Lee, M.-T.; Sanches, I. P.; Rawat, P.; Iga, I.; Santos, A. S. dos; Machado, L. E.; Sugohara, R. T.; Brescansin, L. M.; Homem, M. G. P.; Lucchese, R. R.

    2010-07-15

    We present a joint theoretical-experimental study on electron scattering by propane (C{sub 3}H{sub 8}) in the low- and intermediate-energy ranges. Calculated elastic differential, integral, and momentum transfer as well as total (elastic + inelastic) and total absorption cross sections are reported for impact energies ranging from 2 to 500 eV. Also, experimental absolute elastic cross sections are reported in the 40- to 500-eV energy range. A complex optical potential is used to represent the electron-molecule interaction dynamics. A theoretical method based on the single-center-expansion close-coupling framework and corrected by the Pade approximant is used to solve the scattering equations. The experimental angular distributions of the scattered electrons are converted to absolute cross sections using the relative flow technique. The comparison of our calculated with our measured results, as well as with other experimental and theoretical data available in the literature, is encouraging.

  8. Thorium, uranium and rare earth elements content in lanthanide concentrate (LC) and water leach purification (WLP) residue of Lynas advanced materials plant (LAMP)

    SciTech Connect (OSTI)

    AL-Areqi, Wadeeah M. Majid, Amran Ab. Sarmani, Sukiman

    2014-02-12

    Lynas Advanced Materials Plant (LAMP) has been licensed to produce the rare earths elements since early 2013 in Malaysia. LAMP processes lanthanide concentrate (LC) to extract rare earth elements and subsequently produce large volumes of water leach purification (WLP) residue containing naturally occurring radioactive material (NORM). This residue has been rising up the environmental issue because it was suspected to accumulate thorium with significant activity concentration and has been classified as radioactive residue. The aim of this study is to determine Th-232, U-238 and rare earth elements in lanthanide concentrate (LC) and water leach purification (WLP) residue collected from LAMP and to evaluate the potential radiological impacts of the WLP residue on the environment. Instrumental Neutron Activation Analysis and ?-spectrometry were used for determination of Th, U and rare earth elements concentrations. The results of this study found that the concentration of Th in LC was 1289.7 129 ppm (5274.9 527.6Bq/kg) whereas the Th and U concentrations in WLP were determined to be 1952.917.6 ppm (7987.4 71.9 Bq/kg) and 17.2 2.4 ppm respectively. The concentrations of Th and U in LC and WLP samples determined by ?- spectrometry were 1156 ppm (4728 22 Bq/kg) and 18.8 ppm and 1763.2 ppm (7211.4 Bq/kg) and 29.97 ppm respectively. This study showed that thorium concentrations were higher in WLP compare to LC. This study also indicate that WLP residue has high radioactivity of {sup 232}Th compared to Malaysian soil natural background (63 - 110 Bq/kg) and come under preview of Act 304 and regulations. In LC, the Ce and Nd concentrations determined by INAA were 13.2 0.6% and 4.7 0.1% respectively whereas the concentrations of La, Ce, Nd and Sm in WLP were 0.36 0.04%, 1.6%, 0.22% and 0.06% respectively. This result showed that some amount of rare earth had not been extracted and remained in the WLP and may be considered to be reextracted.

  9. Synchrotron photoionization mass spectrometry study of intermediates in fuel-rich 1,2-dimethoxyethane flame

    SciTech Connect (OSTI)

    Lin, Z. K.; Han, D. L.; Li, S. F.; Li, Y. Y.; Yuan, T.

    2009-04-21

    Intermediates in a fuel-rich premixed laminar 1,2-dimethoxyethane (DME) flame are studied by molecular beam mass spectrometry combined with tunable synchrotron vacuum ultraviolet photoionization. About 30 intermediate species are identified in the present work, and their mole fraction profiles are evaluated. The experimental results show that the formations of intermediates, both hydrocarbons and oxygenated hydrocarbons, are closely linked to the structure of fuel, which is consistent with the previous reports. Species produced from H atom abstraction and beta scission of DME usually have much higher concentrations than others. The oxygen atoms in DME are considered to act as partitions of the primary intermediates; therefore farther reactions among these primary intermediates are difficult to occur, resulting in absence of most large intermediate species.

  10. THE INFRARED SPECTRUM OF URANIUM HOLLOW CATHODE LAMPS FROM 850 nm to 4000 nm: WAVENUMBERS AND LINE IDENTIFICATIONS FROM FOURIER TRANSFORM SPECTRA

    SciTech Connect (OSTI)

    Redman, Stephen L.; Ramsey, Lawrence W.; Mahadevan, Suvrath [Department of Astronomy and Astrophysics, Pennsylvania State University, University Park, PA 16802 (United States); Lawler, James E. [Department of Physics, University of Wisconsin, 1150 University Avenue, Madison, WI 53706 (United States); Nave, Gillian [National Institute of Standards and Technology, Gaithersburg, MD 20899 (United States)

    2011-08-01

    We provide new measurements of wavenumbers and line identifications of 10, 100 U I and U II near-infrared (NIR) emission lines between 2500 cm{sup -1} and 12, 000 cm{sup -1} (4000-850 nm) using archival Fourier transform spectrometer spectra from the National Solar Observatory. This line list includes isolated uranium lines in the Y, J, H, K, and L bands (0.9-1.1 {mu}m, 1.2-1.35 {mu}m, 1.5-1.65 {mu}m, 2.0-2.4 {mu}m, and 3.0-4.0 {mu}m, respectively), and provides six times as many calibration lines as thorium in the NIR spectral range. The line lists we provide enable inexpensive, commercially available uranium hollow cathode lamps to be used for high-precision wavelength calibration of existing and future high-resolution NIR spectrographs.

  11. HOx radical chemistry in oxidation flow reactors with low-pressure mercury lamps systematically examined by modeling

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Peng, Z.; Day, D. A.; Stark, H.; Li, R.; Lee-Taylor, J.; Palm, B. B.; Brune, W. H.; Jimenez, J. L.

    2015-11-20

    Oxidation flow reactors (OFRs) using OH produced from low-pressure Hg lamps at 254 nm (OFR254) or both 185 and 254 nm (OFR185) are commonly used in atmospheric chemistry and other fields. OFR254 requires the addition of externally formed O3 since OH is formed from O3 photolysis, while OFR185 does not since O2 can be photolyzed to produce O3, and OH can also be formed from H2O photolysis. In this study, we use a plug-flow kinetic model to investigate OFR properties under a very wide range of conditions applicable to both field and laboratory studies. We show that the radical chemistrymore » in OFRs can be characterized as a function of UV light intensity, H2O concentration, and total external OH reactivity (OHRext, e.g., from volatile organic compounds (VOCs), NOx, and SO2). OH exposure is decreased by added external OH reactivity. OFR185 is especially sensitive to this effect at low UV intensity due to low primary OH production. OFR254 can be more resilient against OH suppression at high injected O3 (e.g., 70 ppm), as a larger primary OH source from O3, as well as enhanced recycling of HO2 to OH, make external perturbations to the radical chemistry less significant. However if the external OH reactivity in OFR254 is much larger than OH reactivity from injected O3, OH suppression can reach 2 orders of magnitude. For a typical input of 7 ppm O3 (OHRO3 = 10 s−1), 10-fold OH suppression is observed at OHRext ~ 100 s−1, which is similar or lower than used in many laboratory studies. The range of modeled OH suppression for literature experiments is consistent with the measured values except for those with isoprene. The finding on OH suppression may have important implications for the interpretation of past laboratory studies, as applying OHexp measurements acquired under different conditions could lead to over a 1-order-of-magnitude error in the estimated OHexp. The uncertainties of key model outputs due to uncertainty in all rate constants and absorption cross-sections in the model are within ±25 % for OH exposure and within ±60 % for other parameters. These uncertainties are small relative to the dynamic range of outputs. Uncertainty analysis shows that most of the uncertainty is contributed by photolysis rates of O3, O2, and H2O and reactions of OH and HO2 with themselves or with some abundant species, i.e., O3 and H2O2. OHexp calculated from direct integration and estimated from SO2 decay in the model with laminar and measured residence time distributions (RTDs) are generally within a factor of 2 from the plug-flow OHexp. However, in the models with RTDs, OHexp estimated from SO2 is systematically lower than directly integrated OHexp in the case of significant SO2 consumption. We thus recommended using OHexp estimated from the decay of the species under study when possible, to obtain the most appropriate information on photochemical aging in the OFR. Using HOx-recycling vs. destructive external OH reactivity only leads to small changes in OHexp under most conditions. Changing the identity (rate constant) of external OH reactants can result in substantial changes in OHexp due to different reductions in OH suppression as the reactant is consumed. We also report two equations for estimating OH exposure in OFR254. We find that the equation estimating OHexp from measured O3 consumption performs better than an alternative equation that does not use it, and thus recommend measuring both input and output O3 concentrations in OFR254 experiments. This study contributes to establishing a firm and systematic understanding of the gas-phase HOx and Ox chemistry in these reactors, and enables better experiment planning and interpretation as well as improved design of future reactors.« less

  12. Effects of intermediate ethanol blends on legacy vehicles and small non-road engines, report 1

    SciTech Connect (OSTI)

    West, Brian; Knoll, Keith; Clark, Wendy; Graves, Ronald; Orban, John; Przesmitzki, Steve; Theiss, Timothy

    2008-10-01

    Report on the test program to assess the viability of using intermediate ethanol blends as a contributor to meeting national goals in the use of renewable fuels.

  13. INTERMEDIATE ENERGY X-RAY (IEX) BEAMLINE AT THE ADVANCED PHOTON...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    INTERMEDIATE ENERGY X-RAY (IEX) BEAMLINE AT THE ADVANCED PHOTON SOURCE Jessica McChesney, APS beamline scientist, connecting the transition edge sensor (TES) detector to the...

  14. Intermediate evaluation of USAID/Cairo energy policy planning project

    SciTech Connect (OSTI)

    Wilbanks, T.J.; Wright, S.B.; Barron, W.F.; Kamel, A.M.; Santiago, H.T.

    1992-09-01

    Three years ago, a team from the Oak Ridge National Laboratory and the Oak Ridge Associated Universities, supplemented by an expert from the US Department of Energy and a senior Egyptian energy professional, carried out what was termed an ``intermediate evaluation`` of a major energy policy project in Egypt. Supported by USAID/Cairo, the project had concentrated on developing and strengthening an Organization for Energy Planning (OEP) within the Government of India, and it was actually scheduled to end less than a year after this evaluation. The evaluation was submitted to USAID/Cairo and circulated elsewhere in the US Agency for International Development and the Government of Egypt as an internal report. Over the next several years, the USAID energy planning project ended and the functions performed by OEP were merged with planning capabilities in the electric power sector. Now that the major issues addressed by the evaluation report have been resolved, we are making it available to a broader audience as a contribution to the general literature on development project evaluation and institution-building.

  15. Intermediate evaluation of USAID/Cairo energy policy planning project

    SciTech Connect (OSTI)

    Wilbanks, T.J.; Wright, S.B. ); Barron, W.F. ); Kamel, A.M. ); Santiago, H.T. )

    1992-01-01

    Three years ago, a team from the Oak Ridge National Laboratory and the Oak Ridge Associated Universities, supplemented by an expert from the US Department of Energy and a senior Egyptian energy professional, carried out what was termed an intermediate evaluation'' of a major energy policy project in Egypt. Supported by USAID/Cairo, the project had concentrated on developing and strengthening an Organization for Energy Planning (OEP) within the Government of India, and it was actually scheduled to end less than a year after this evaluation. The evaluation was submitted to USAID/Cairo and circulated elsewhere in the US Agency for International Development and the Government of Egypt as an internal report. Over the next several years, the USAID energy planning project ended and the functions performed by OEP were merged with planning capabilities in the electric power sector. Now that the major issues addressed by the evaluation report have been resolved, we are making it available to a broader audience as a contribution to the general literature on development project evaluation and institution-building.

  16. A far-infrared spectroscopic survey of intermediate redshift (ultra) luminous infrared galaxies

    SciTech Connect (OSTI)

    Magdis, Georgios E.; Rigopoulou, D.; Hopwood, R.; Clements, D.; Huang, J.-S.; Farrah, D.; Pearson, C.; Alonso-Herrero, Almudena; Bock, J. J.; Cooray, A.; Griffin, M. J.; Oliver, S.; Perez Fournon, I.; Riechers, D.; Swinyard, B. M.; Thatte, N.; Scott, D.; Valtchanov, I.; Vaccari, M.

    2014-11-20

    We present Herschel far-IR photometry and spectroscopy as well as ground-based CO observations of an intermediate redshift (0.21 ? z ? 0.88) sample of Herschel-selected (ultra)-luminous infrared galaxies (L {sub IR} > 10{sup 11.5} L {sub ?}). With these measurements, we trace the dust continuum, far-IR atomic line emission, in particular [C II] 157.7 ?m, as well as the molecular gas of z ? 0.3 luminous and ultraluminous infrared galaxies (LIRGs and ULIRGs) and perform a detailed investigation of the interstellar medium of the population. We find that the majority of Herschel-selected intermediate redshift (U)LIRGs have L {sub C} {sub II}/L {sub FIR} ratios that are a factor of about 10 higher than that of local ULIRGs and comparable to that of local normal and high-z star-forming galaxies. Using our sample to bridge local and high-z [C II] observations, we find that the majority of galaxies at all redshifts and all luminosities follow an L {sub C} {sub II}L {sub FIR} relation with a slope of unity, from which local ULIRGs and high- z active-galactic-nucleus-dominated sources are clear outliers. We also confirm that the strong anti-correlation between the L {sub C} {sub II}/L {sub FIR} ratio and the far-IR color L {sub 60}/L {sub 100} observed in the local universe holds over a broad range of redshifts and luminosities, in the sense that warmer sources exhibit lower L {sub C} {sub II}/L {sub FIR} at any epoch. Intermediate redshift ULIRGs are also characterized by large molecular gas reservoirs and by lower star formation efficiencies compared to that of local ULIRGs. The high L {sub C} {sub II}/L {sub FIR} ratios, the moderate star formation efficiencies (L {sub IR}/L{sub CO}{sup ?} or L {sub IR}/M{sub H{sub 2}}), and the relatively low dust temperatures of our sample (which are also common characteristics of high-z star-forming galaxies with ULIRG-like luminosities) indicate that the evolution of the physical properties of (U)LIRGs between the present day and z > 1 is already significant by z ? 0.3.

  17. Identification of combustion intermediates in a low-pressure premixed laminar 2,5-dimethylfuran/oxygen/argon flame with tunable synchrotron photoionization

    SciTech Connect (OSTI)

    Wu, Xuesong; Huang, Zuohua; Wei, Lixia [State Key Laboratory of Multiphase Flow in Power Engineering, Xi'an Jiaotong University, Xi'an 710049 (China); Yuan, Tao; Zhang, Kuiwen [National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei 230029 (China)

    2009-07-15

    Low-pressure (4.0 kPa) premixed laminar 2,5-dimethylfuran (DMF)/oxygen/argon flame with an equivalence ratio of 2.0 was studied with tunable vacuum ultraviolet (VUV) synchrotron radiation photoionization and molecular-beam mass spectrometry. Photoionization mass spectra of DMF/O{sub 2}/Ar flame were recorded and the photoionization efficiency curves of the combustion intermediates were measured. Flame species, including isomeric intermediates, are identified by comparing the measured ionization energies with those reported in literatures or those calculated with Gaussian-3 procedure. More than 70 species have been detected, including furan and its derivatives, aromatics, and free radicals. Possible reaction pathways of DMF, 2-methylfuran, and furan are proposed based on the intermediates identified. DMF can be consumed by H-abstraction and pyrolysis reactions. 2-Methylfuran and furan can be consumed by H-abstraction, H-addition and pyrolysis reactions. (author)

  18. Kinetics and mechanisms of reactions involving small aromatic reactive intermediates

    SciTech Connect (OSTI)

    Lin, M.C.

    1993-12-01

    Small aromatic radicals such as C{sub 6}H{sub 5}, C{sub 6}H{sub 5}O and C{sub 6}H{sub 4} are key prototype species of their homologs. C{sub 6}H{sub 5} and its oxidation product, C{sub 6}H{sub 5}O are believed to be important intermediates which play a pivotal role in hydrocarbon combustion, particularly with regard to soot formation. Despite their fundamental importance, experimental data on the reaction mechanisms and reactivities of these species are very limited. For C{sub 6}H{sub 5}, most kinetic data except its reactions with NO and NO{sub 2}, were obtained by relative rate measurements. For C{sub 6}H{sub 5}O, the authors have earlier measured its fragmentation reaction producing C{sub 5}H{sub 5} + CO in shock waves. For C{sub 6}H{sub 4}, the only rate constant measured in the gas phase is its recombination rate at room temperature. The authors have proposed to investigate systematically the kinetics and mechanisms of this important class of molecules using two parallel laser diagnostic techniques--laser resonance absorption (LRA) and resonance enhanced multiphoton ionization mass spectrometry (REMPI/MS). In the past two years, study has been focused on the development of a new multipass adsorption technique--the {open_quotes}cavity-ring-down{close_quotes} technique for kinetic applications. The preliminary results of this study appear to be quite good and the sensitivity of the technique is at least comparable to that of the laser-induced fluorescence method.

  19. Intermediate coating layer for high temperature rubbing seals for rotary regenerators

    DOE Patents [OSTI]

    Schienle, James L. (Phoenix, AZ); Strangman, Thomas E. (Phoenix, AZ)

    1995-01-01

    A metallic regenerator seal is provided having multi-layer coating comprising a NiCrAlY bond layer, a yttria stabilized zirconia (YSZ) intermediate layer, and a ceramic high temperature solid lubricant surface layer comprising zinc oxide, calcium fluoride, and tin oxide. Because of the YSZ intermediate layer, the coating is thermodynamically stable and resists swelling at high temperatures.

  20. Spatial and kinematic distributions of transition populations in intermediate redshift galaxy clusters

    SciTech Connect (OSTI)

    Crawford, Steven M.; Wirth, Gregory D.; Bershady, Matthew A. E-mail: wirth@keck.hawaii.edu

    2014-05-01

    We analyze the spatial and velocity distributions of confirmed members in five massive clusters of galaxies at intermediate redshift (0.5 < z < 0.9) to investigate the physical processes driving galaxy evolution. Based on spectral classifications derived from broad- and narrow-band photometry, we define four distinct galaxy populations representing different evolutionary stages: red sequence (RS) galaxies, blue cloud (BC) galaxies, green valley (GV) galaxies, and luminous compact blue galaxies (LCBGs). For each galaxy class, we derive the projected spatial and velocity distribution and characterize the degree of subclustering. We find that RS, BC, and GV galaxies in these clusters have similar velocity distributions, but that BC and GV galaxies tend to avoid the core of the two z ? 0.55 clusters. GV galaxies exhibit subclustering properties similar to RS galaxies, but their radial velocity distribution is significantly platykurtic compared to the RS galaxies. The absence of GV galaxies in the cluster cores may explain their somewhat prolonged star-formation history. The LCBGs appear to have recently fallen into the cluster based on their larger velocity dispersion, absence from the cores of the clusters, and different radial velocity distribution than the RS galaxies. Both LCBG and BC galaxies show a high degree of subclustering on the smallest scales, leading us to conclude that star formation is likely triggered by galaxy-galaxy interactions during infall into the cluster.

  1. Applications of Cu{sub 2}O octahedral particles on ITO glass in photocatalytic degradation of dye pollutants under a halogen tungsten lamp

    SciTech Connect (OSTI)

    Zhai, Wei; Sun, Fengqiang; Chen, Wei; Zhang, Lihe; Min, Zhilin; Li, Weishan

    2013-11-15

    Graphical abstract: - Highlights: Photocatalytic activity of Cu{sub 2}O octahedral microcrystals on ITO glass was studied. They showed high abilities in degradation of methylene blue in the presence of H{sub 2}O{sub 2}. H{sub 2}O{sub 2} amount could affect the degradation efficiency. Such particles could be easily recycled and still kept high activity. Many dye pollutants and their mixtures could be efficiently degraded. - Abstract: Cu{sub 2}O octahedral microcrystals were prepared on the ITO glass by galvanostatic electrodeposition in CuSO{sub 4} solution with poly(vinylpryrrolidone) as the surfactant. By controlling the electrodeposition time, the microcrystals could be randomly distributed on the ITO glass and separated from each other, resulting in as many as possible (1 1 1) crystalline planes were exposed. Such microcrystals immobilized on ITO glass were employed in photodegradation of dye pollutants in the presence of H{sub 2}O{sub 2} under a 150 W halogen tungsten lamp. The photodegradation of methylene blue was taken as an example to evaluate the photocatalytic activities of the octahedral Cu{sub 2}O microcrystals. Effects of electrodeposition time and H{sub 2}O{sub 2} amount on the degradation efficiency was discussed, giving the optimum conditions and the corresponding degradation mechanism. The catalyst showed high ability in degradation of methylene blue, methyl orange, rhodamine B, eosin B and their mixtures under identical conditions.

  2. ECONOMIC ASSESSMENT ON VITRIFICATION FACILITY OF LOW-AND INTERMEDIATE-LEVEL RADIOACTIVE WASTES IN KOREA

    SciTech Connect (OSTI)

    Kim, Sung Il; Lee, Kun Jai; Ji, Pyung Kook; Park, Jong Kil; Ha, Jong Hyun; Song, Myung Jae

    2003-02-27

    The usefulness of vitrification technology for low-and intermediate-level radioactive wastes was demonstrated with high volume reduction capability and good mechanical and chemical stability of final waste forms, and commercial vitrification facility is expected to be constructed at Ulchin site of Korean Nuclear Power Plant Ulchin Unit 5 and 6. Hence, overall economic assessment was necessary to find out the economic advantage of the vitrification facility and to predict the construction and operation costs of the facility on the preliminary bases. Additionally, the generation characteristics of radioactive wastes were investigated. The results of the cost analysis showed that the disposal cost of radioactive wastes treated by vitrification facility reduced to 85 percent compared with that by current waste treatment system. And the present worth analysis was performed through the cost-benefit analysis method for the commercial vitrification facility. The results showed that the vitrification facility combining cold crucible melter (CCM) for treatment of combustible DAW, spent resin, and borated liquid waste concentrate and plasma torch melter (PTM) for non-combustible DAW and spent filter is more economical than current waste treatment system when the escalation rate of disposal cost of more than 10 percent per year was applied.

  3. Total reaction cross sections in CEM and MCNP6 at intermediate energies

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Kerby, Leslie M.; Mashnik, Stepan G.

    2015-05-14

    Accurate total reaction cross section models are important to achieving reliable predictions from spallation and transport codes. The latest version of the Cascade Exciton Model (CEM) as incorporated in the code CEM03.03, and the Monte Carlo N-Particle transport code (MCNP6), both developed at Los Alamos National Laboratory (LANL), each use such cross sections. Having accurate total reaction cross section models in the intermediate energy region (50 MeV to 5 GeV) is very important for different applications, including analysis of space environments, use in medical physics, and accelerator design, to name just a few. The current inverse cross sections used inmore » the preequilibrium and evaporation stages of CEM are based on the Dostrovsky et al. model, published in 1959. Better cross section models are now available. Implementing better cross section models in CEM and MCNP6 should yield improved predictions for particle spectra and total production cross sections, among other results.« less

  4. Effects of Porous Medium Heterogeneity on Vadose Zone Desiccation: Intermediate-scale Laboratory Experiments and Simulations

    SciTech Connect (OSTI)

    Oostrom, Martinus; Freedman, Vicky L.; Wietsma, Thomas W.; Dane, Jacob H.; Truex, Michael J.

    2012-11-01

    Soil desiccation (drying), involving water evaporation induced by dry gas injection, is a potentially robust vadose zone remediation process to limit contaminant transport through the vadose zone. A series of four intermediate-scale flow cell experiments was conducted in homogeneous and simple layered heterogeneous porous medium systems to investigate the effects of heterogeneity on desiccation of unsaturated porous media. The permeability ratios of porous medium layers ranged from about five to almost two orders of magnitude. The insulated flow cell was equipped with twenty humidity and temperature sensors and a dual-energy gamma system was used to determine water saturations at various times. The multiphase code STOMP was used to simulate the desiccation process. Results show that injected dry gas flowed predominantly in the higher permeability layer and delayed water removal from the lower permeability material. For the configurations tested, water vapor diffusion from the lower to the higher permeability zone was considerable over the duration of the experiments, resulting in much larger relative humidity values of the outgoing air than based on permeability ratios alone. Acceptable numerical matches with the experimental data were obtained when an extension of the saturation-capillary pressure relation below the residual water saturation was used. The agreements between numerical and experimental results suggest that the correct physics are implemented in the simulator and that the thermal and hydraulic properties of the porous media, flow cell wall and insulation materials were properly represented.

  5. Methods and intermediates for the synthesis of dipyrrin-substituted porphyrinic macrocycles

    DOE Patents [OSTI]

    Yu, Lianhe (Raleigh, NC); Muthukumaran, Kannan (Raleigh, NC); Sreedharan, Prathapan (Kerala, IN); Lindsey, Jonathan S. (Raleigh, NC)

    2008-02-19

    The present invention provides dipyrrin substituted porphyrinic macrocycles, intermediates useful for making the same, and methods of making the same. Such compounds may be used for purposes including the making of molecular memory devices, solar cells and light harvesting arrays.

  6. Band filling effects on temperature performance of intermediate band quantum wire solar cells

    SciTech Connect (OSTI)

    Kunets, Vas. P. Furrow, C. S.; Ware, M. E.; Souza, L. D. de; Benamara, M.; Salamo, G. J.; Mortazavi, M.

    2014-08-28

    Detailed studies of solar cell efficiency as a function of temperature were performed for quantum wire intermediate band solar cells grown on the (311)A plane. A remotely doped one-dimensional intermediate band made of self-assembled In{sub 0.4}Ga{sub 0.6}As quantum wires was compared to an undoped intermediate band and a reference p-i-n GaAs sample. These studies indicate that the efficiencies of these solar cells depend on the population of the one-dimensional band by equilibrium free carriers. A change in this population by free electrons under various temperatures affects absorption and carrier transport of non-equilibrium carriers generated by incident light. This results in different efficiencies for both the doped and undoped intermediate band solar cells in comparison with the reference GaAs p-i-n solar cell device.

  7. Methods and intermediates for the synthesis of dipyrrin-substituted porphyrinic macrocycles

    DOE Patents [OSTI]

    Yu, Lianhe; Muthukumaran, Kannan; Sreedharan, Prathapan; Lindsey, Jonathan S.

    2010-05-25

    The present invention provides dipyrrin substituted porphyrinic macrocycles, intermediates useful for making the same, and methods of making the same. Such compounds may be used for purposes including the making of molecular memory devices, solar cells and light harvesting arrays.

  8. Methods and intermediates for the synthesis of dipyrrin-substituted porphyrinic macrocycles

    DOE Patents [OSTI]

    Yu, Lianhe (Raleigh, NC); Muthukumaran, Kannan (Raleigh, NC); Sreedharan, Prathapan (Kerata, IN); Lindsey, Jonathan S. (Raleigh, NC)

    2011-05-24

    The present invention provides dipyrrin substituted porphyrinic macrocycles, intermediates useful for making the same, and methods of making the same. Such compounds may be used for purposes including the making of molecular memory devices, solar cells and light harvesting arrays.

  9. Methods and intermediates for the synthesis of dipyrrin-substituted porphyrinic macrocycles

    DOE Patents [OSTI]

    Yu, Lianhe (Raleigh, NC); Muthukumaran, Kannan (Raleigh, NC); Sreedharan, Prathapan (Kerala, IN); Lindsey, Jonathan S. (Raleigh, NC)

    2012-03-06

    The present invention provides dipyrrin substituted porphyrinic macrocycles, intermediates useful for making the same, and methods of making the same. Such compounds may be used for purposes including the making of molecular memory devices, solar cells and light harvesting arrays.

  10. Sub-picosecond IR study of the reactive intermediate in an alkane...

    Office of Scientific and Technical Information (OSTI)

    Journal Article: Sub-picosecond IR study of the reactive intermediate in an alkane C-H bond activation reaction by CpRh(CO)2 Citation Details In-Document Search Title: ...

  11. Helicity amplitudes of di-photons production at the LHC with scalar unparticles intermediate states

    SciTech Connect (OSTI)

    Aliane, I.; Mebarki, N.; Haouchine, M.

    2012-06-27

    The helecity amplitudes of the subprocess gg{yields}{gamma}{gamma} via scalar unparticles intermediate states are calculated. The differential cross section is compared to that of the standard model. Phenomenological implications are also discussed.

  12. Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non-Road Engines, Report 1

    SciTech Connect (OSTI)

    Knoll, Keith; West, Brian; Clark, Wendy; Graves, Ronald; Orban, John; Przesmitzki, Steve; Theiss, Timothy

    2009-02-01

    This report (February 2009) is an update of the original version, which was published in October 2008. This report is the result of the U.S. Department of Energy's test program to evaluate the potential impacts of intermediate ethanol blends on legacy vehicles and other engines. The purpose of the test program is to assess the viability of using intermediate blends as a contributor to meeting national goals in the use of renewable fuels.

  13. Generalized thickness and configuration of the top of the intermediate aquifer, West-Central Florida

    SciTech Connect (OSTI)

    Corral, M.A. Jr.; Wolansky, R.M.

    1984-01-01

    The water-bearing units of the intermediate aquifer consist of discontinuous sand, gravel, shell, and limestone and dolomite beds in the Tamiami Formation of late Miocene age and the Hawthorn Formation of middle Miocene age. Within parts of Polk, Manatee, Hardee, De Soto, Sarasota, and Charlotte Counties, sand and clay beds within the Tampa Limestone that are hydraulically connected to the Hawthorn Formation are also included in the intermediate aquifer. 15 refs.

  14. Wavelength-conserving grating router for intermediate wavelength density

    DOE Patents [OSTI]

    Deri, Robert J.; Patel, Rajesh R.; Bond, Steven W.; Bennett, Cory V.

    2007-03-20

    A wavelength router to be used for fiber optical networking router is based on a diffraction grating which utilizes only N wavelengths to interconnect N inputs to N outputs. The basic approach is to augment the grating with additional couplers or wavelength selective elements so than N-1 of the 2N-1 outputs are combined with other N outputs (leaving only N outputs). One embodiment uses directional couplers as combiners. Another embodiment uses wavelength-selective couplers. Another embodiment uses a pair of diffraction gratings to maintain parallel propagation of all optical beams. Also, beam combining can be implemented either by using retroflection back through the grating pair or by using couplers.

  15. NN inversion potentials intermediate energy proton-nucleus elastic scattering

    SciTech Connect (OSTI)

    Arellano, H.F.; Brieva, F.A.; Love, W.G.; Geramb, H.V. von

    1995-10-01

    Recently developed nucleon-nucleon interactions using the quantum inverse scattering method shed new fight on the off-shell properties of the internucleon effective force for nucleon-nucleus scattering. Calculations of proton elastic scattering from {sup 40}Ca and {sup 208}Pb in the 500 MeV region show that variations in off-shell contributions are determined to a great extent by the accuracy with which the nucleon-nucleon phase shifts are reproduced. The study is based on the full-folding approach to the nucleon-nucleus optical potential which allows a deep understanding of the interplay between on- and off-shell effects in nucleon scattering. Results and the promising extension offered by the inversion potentials beyond the range of validity of the low-energy internucleon forces will be discussed.

  16. Legacy Vehicle Fuel System Testing with Intermediate Ethanol Blends

    SciTech Connect (OSTI)

    Davis, G. W.; Hoff, C. J.; Borton, Z.; Ratcliff, M. A.

    2012-03-01

    The effects of E10 and E17 on legacy fuel system components from three common mid-1990s vintage vehicle models (Ford, GM, and Toyota) were studied. The fuel systems comprised a fuel sending unit with pump, a fuel rail and integrated pressure regulator, and the fuel injectors. The fuel system components were characterized and then installed and tested in sample aging test rigs to simulate the exposure and operation of the fuel system components in an operating vehicle. The fuel injectors were cycled with varying pulse widths during pump operation. Operational performance, such as fuel flow and pressure, was monitored during the aging tests. Both of the Toyota fuel pumps demonstrated some degradation in performance during testing. Six injectors were tested in each aging rig. The Ford and GM injectors showed little change over the aging tests. Overall, based on the results of both the fuel pump testing and the fuel injector testing, no major failures were observed that could be attributed to E17 exposure. The unknown fuel component histories add a large uncertainty to the aging tests. Acquiring fuel system components from operational legacy vehicles would reduce the uncertainty.

  17. THE EGNoG SURVEY: MOLECULAR GAS IN INTERMEDIATE-REDSHIFT STAR-FORMING GALAXIES

    SciTech Connect (OSTI)

    Bauermeister, A.; Blitz, L.; Wright, M.; Bolatto, A.; Teuben, P.; Bureau, M.; Leroy, A.; Ostriker, E.; Wong, T.

    2013-05-10

    We present the Evolution of molecular Gas in Normal Galaxies (EGNoG) survey, an observational study of molecular gas in 31 star-forming galaxies from z = 0.05 to z = 0.5, with stellar masses of (4-30) Multiplication-Sign 10{sup 10} M{sub Sun} and star formation rates of 4-100 M{sub Sun} yr{sup -1}. This survey probes a relatively un-observed redshift range in which the molecular gas content of galaxies is expected to have evolved significantly. To trace the molecular gas in the EGNoG galaxies, we observe the CO(J = 1 {yields} 0) and CO(J = 3 {yields} 2) rotational lines using the Combined Array for Research in Millimeter-wave Astronomy (CARMA). We detect 24 of 31 galaxies and present resolved maps of 10 galaxies in the lower redshift portion of the survey. We use a bimodal prescription for the CO to molecular gas conversion factor, based on specific star formation rate, and compare the EGNoG galaxies to a large sample of galaxies assembled from the literature. We find an average molecular gas depletion time of 0.76 {+-} 0.54 Gyr for normal galaxies and 0.06 {+-} 0.04 Gyr for starburst galaxies. We calculate an average molecular gas fraction of 7%-20% at the intermediate redshifts probed by the EGNoG survey. By expressing the molecular gas fraction in terms of the specific star formation rate and molecular gas depletion time (using typical values), we also calculate the expected evolution of the molecular gas fraction with redshift. The predicted behavior agrees well with the significant evolution observed from z {approx} 2.5 to today.

  18. Intermediate Heat Transfer Loop Study for High Temperature Gas-Cooled Reactor

    SciTech Connect (OSTI)

    C. H. Oh; C. Davis; S. Sherman

    2008-08-01

    A number of possible configurations for a system that transfers heat between the nuclear reactor and the hydrogen and/or electrical generation plants were identified. These configurations included both direct and indirect cycles for the production of electricity. Both helium and liquid salts were considered as the working fluid in the intermediate heat transport loop. Methods were developed to perform thermal-hydraulic and cycleefficiency evaluations of the different configurations and coolants. The thermal-hydraulic evaluations estimated the sizes of various components in the intermediate heat transport loop for the different configurations. This paper also includes a portion of stress analyses performed on pipe configurations.

  19. Sub-picosecond IR study of the reactive intermediate in an alkane C-H bond

    Office of Scientific and Technical Information (OSTI)

    activation reaction by CpRh(CO)2 (Journal Article) | SciTech Connect Journal Article: Sub-picosecond IR study of the reactive intermediate in an alkane C-H bond activation reaction by CpRh(CO)2 Citation Details In-Document Search Title: Sub-picosecond IR study of the reactive intermediate in an alkane C-H bond activation reaction by CpRh(CO)2 No abstract prepared. Authors: Asbury, John B. ; Ghosh, Hirendra N. ; Yeston, Jake S. ; Bergman, Robert G. ; Lian, Tianquan Publication Date:

  20. Electric Power Generation from Low to Intermediate Temperature Resources

    SciTech Connect (OSTI)

    Gosnold, William D.

    2015-06-18

    This project was designed to test the concept on the Eland-Lodgepole Field near Dickinson, North Dakota in the Williston Basin. The field is in secondary-recovery water-flood and consists of 12 producing oil wells, 5 water injection wells and one disposal well. Water production at the site averages approximately 320 gallons per minute (20.2 l s-1) and the temperature is 100 ⁰C. Engineers at Ormat estimated power production potential with the existing resource to be approximately 350 kWh. Unfortunately, ownership of the field was transferred from Encore, Inc., to Denbury, Inc., within the first week of the project. After two years of discussion and planning, Denbury decided not to pursue this project due to complications with the site location and its proximity to Patterson Lake. Attempts to find other partners operating in the Williston Basin were unsuccessful. Consequently, we were unable to pursue the primary objective of the project. However, during negations with Denbury and subsequent time spent contacting other potential partners, we focused on objectives 2 and 3 and developed a clear understanding of the potential for co-produced production in the Williston Basin and the best practices for developing similar projects. At least nine water bearing formations with temperatures greater than 90 ⁰C extend over areas of several 10s of km2. The total energy contained in the rock volume of those geothermal aquifers is 283.6 EJ (1 EJ = 1018 J). The total energy contained in the water volume, determined from porosities which range from 2 percent to 8 percent, is 6.8 EJ. The aquifers grouped by 10 ⁰C temperature bins (Table 1) include one or more formations due to the bowl-shape structure of the basin. Table 1. Summary of energy available in geothermal aquifers in the Williston Basin Analysis of overall fluid production from active wells, units, fields and formations in North Dakota showed that few sites co-produce sufficient fluid for significant power production with ORC technology. Average co-produced water for 10,480 wells is 3.2 gallons per minute (gpm). Even excluding the tight formations, Bakken and Three Forks, average co-produced water for the remaining 3,337 is only 5 gpm. The output of the highest producing well is 184 gpm and the average of the top 100 wells is 52 gpm. Due to the depth of the oil producing formations in the Williston Basin, typically 3 km or greater, pumps are operated slowly to prevent watering out thus total fluid production is purposefully maintained at low volumes. There remain potential possibilities for development of geothermal fluids in the Williston Basin. Unitized fields in which water production from several tens of wells is collected at a single site are good possibilities for development. Water production in the unitized fields is greater than 1000 gpm is several areas. A similar possibility occurs where infill-drilling between Bakken and Three Forks horizontal wells has created areas where large volumes of geothermal fluids are available on multi-well pads and in unitized fields. Although the Bakken produces small amounts of water, the water/oil ration is typically less than 1, the oil and water mix produced at the well head can be sent through the heat exchanger on an ORC. It is estimated that several tens of MWh of power could be generated by a distributed system of ORC engines in the areas of high-density drilling in the Bakken Formation. Finally, horizontal drilling in water bearing formations is the other possibility. Several secondary recovery water-flood projects in the basin are producing water above 100 ⁰C at rates of 300 gpm to 850 gpm. Those systems also could produce several tens of MWh of power with ORC technology. Objective 3 of the project was highly successful. The program has produced 5 PhDs, 7 MS, and 3 BS students with theses in geothermal energy. The team has involved 7 faculty in 4 different engineering and science disciplines, ChE, EE, GE, and Geol. The team has produced 26 peer-reviewed papers and 62 presentations at professional meetings. Faculty involved in the program developed five graduate level courses covering different elements in heat flow and geothermal energy that are now offered in the Harold Hamm School of Geology and Geological Engineering. Lessons learned – Keys to developing a successful project;1. Determine target formations; a. Data from oil and gas operators, state oil and gas regulatory agencies, and state geological surveys help to identify producing formations and their properties; 2. Determine the quantity of energy available in the target formations; a. A complete thermal analysis of the basin or region yields the most useful information; b. Critical data include: BHT, heat flow, stratigraphy, lithology, lithological properties, and thermal conductivity, subsurface structure; 3. Determine fluid production potential; a. State oil and gas regulatory agencies, and state geological surveys have data on oil, gas and water production. State Water Commission/Agencies have data on water quality, aquifers, and regulations; b. Consider single horizontal wells, multiple conventional wells, and unitized fields; 4. Calculate energy production capacity of each formation based on different well combination and power plant scenarios. This is a broad overview rather than a site specific analysis; 5. Research and understand the local electrical power industry. Obtain the PPA before committing to the project; 6. Work with the high-level personnel in the oil company partner. Obtain an MOU that addresses all issues in the project including what to expect if the company goes out of business, is bought out, changes management, etc; and 7. Be prepared for project delays.

  1. Natural succession impeded by smooth brome (Bromus inermis) and intermediate wheatgrass (Agropyron intermedium) in an abandoned agricultural field

    SciTech Connect (OSTI)

    Nelson, J.K.

    1997-11-01

    In 1975, an abandoned agricultural field at Rocky Flats Environmental Technology Site (Site) that had been cultivated for more than 38 years, was seeded with smooth brome (Bromus inermis) and intermediate wheatgrass (Agropyron intermedium). Although these species are commonly planted in reclamation and roadside seed mixtures, few studies have documented their impact on the re-establishment of native plant communities. In 1994, species richness, cover, and biomass were sampled in the agricultural field and compared to the surrounding mixed-grass prairie at the Site. The agricultural field contained only 61 plant species (62% native), compared to 143 species (81% native) in the surrounding mixed-grass prairie. Community similarity based on species presence/absence was 0.47 (Sorensen coefficient of similarity). Basal vegetative cover was 11.2% in the agricultural field and 29.1% in the mixed-grass prairie. Smooth brome and intermediate wheatgrass accounted for 93% of the relative foliar cover and 96% of the biomass in the agricultural field. The aggressive nature of these two planted species has impeded the natural succession of the agricultural field to a more native prairie community. Studies of natural succession on abandoned fields and roads in northeastern Colorado have indicated that if left alone, fields would return to their native climax state in approximately 50 years and would be approaching their native state after 20--25 years. Based on the results of this study, this agricultural field may take more than 100 years to return to a native mixed-grass prairie state and it may never achieve a native state without human intervention.

  2. Intermediate photovoltaic system application experiment operational performance report. Volume 3. For G. N. Wilcox Memorial Hospital, Kauai, Hawaii

    SciTech Connect (OSTI)

    Not Available

    1982-09-01

    Presented are the project description, list of participants, and system specifications for the intermediate photovoltaic project at G.N. Wilcox Memorial Hospital, Kauai, Hawaii.

  3. Generator-Absorber heat exchange transfer apparatus and method using an intermediate liquor

    DOE Patents [OSTI]

    Phillips, Benjamin A. (Benton Harbor, MI); Zawacki, Thomas S. (St. Joseph, MI)

    1996-11-05

    Numerous embodiments and related methods for generator-absorber heat exchange (GAX) are disclosed, particularly for absorption heat pump systems. Such embodiments and related methods use the working solution of the absorption system for the heat transfer medium where the working solution has an intermediate liquor concentration.

  4. Intermediate Energy X-ray Beamline at the Advanced Photon Source | Argonne

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    National Laboratory Intermediate Energy X-ray Beamline at the Advanced Photon Source Using relatively low-energy X-rays, the IEX beamline will help illuminate electronic ordering and emergent phenomena in ordered materials to better understand the origins of distinct electronic properties. PDF icon IEX_fact_sheet

  5. Methods of forming single source precursors, methods of forming polymeric single source precursors, and single source precursors and intermediate products formed by such methods

    DOE Patents [OSTI]

    Fox, Robert V.; Rodriguez, Rene G.; Pak, Joshua J.; Sun, Chivin; Margulieux, Kelsey R.; Holland, Andrew W.

    2012-12-04

    Methods of forming single source precursors (SSPs) include forming intermediate products having the empirical formula 1/2{L.sub.2N(.mu.-X).sub.2M'X.sub.2}.sub.2, and reacting MER with the intermediate products to form SSPs of the formula L.sub.2N(.mu.-ER).sub.2M'(ER).sub.2, wherein L is a Lewis base, M is a Group IA atom, N is a Group IB atom, M' is a Group IIIB atom, each E is a Group VIB atom, each X is a Group VIIA atom or a nitrate group, and each R group is an alkyl, aryl, vinyl, (per)fluoro alkyl, (per)fluoro aryl, silane, or carbamato group. Methods of forming polymeric or copolymeric SSPs include reacting at least one of HE.sup.1R.sup.1E.sup.1H and MER with one or more substances having the empirical formula L.sub.2N(.mu.-ER).sub.2M'(ER).sub.2 or L.sub.2N(.mu.-X).sub.2M'(X).sub.2 to form a polymeric or copolymeric SSP. New SSPs and intermediate products are formed by such methods.

  6. Structure and Electronic Configurations of the Intermediates of Water Oxidation in Blue Ruthenium Dimer Catalysis

    SciTech Connect (OSTI)

    Moonshiram, Dooshaye; Jurss, Jonah W.; Concepcion, Javier J.; Zakharova, Taisiya; Alperovich, Igor; Meyer, Thomas J.; Pushkar, Yulia

    2013-04-08

    Catalytic O{sub 2} evolution with cis,cis-[(bpy){sub 2}(H{sub 2}O)Ru{sup III}ORu{sup III}(OH{sub 2})(bpy){sub 2}]{sup 4+} (bpy is 2,2-bipyridine), the so-called blue dimer, the first designed water oxidation catalyst, was monitored by UV-vis, EPR, and X-ray absorption spectroscopy (XAS) with ms time resolution. Two processes were identified, one of which occurs on a time scale of 100 ms to a few seconds and results in oxidation of the catalyst with the formation of an intermediate, here termed [3,4]'. A slower process occurring on the time scale of minutes results in the decay of this intermediate and O{sub 2} evolution. Spectroscopic data suggest that within the fast process there is a short-lived transient intermediate, which is a precursor of [3,4]'. When excess oxidant was used, a highly oxidized form of the blue dimer [4,5] was spectroscopically resolved within the time frame of the fast process. Its structure and electronic state were confirmed by EPR and XAS. As reported earlier, the [3,4]' intermediate likely results from reaction of [4,5] with water. While it is generated under strongly oxidizing conditions, it does not display oxidation of the Ru centers past [3,4] according to EPR and XAS. EXAFS analysis demonstrates a considerably modified ligand environment in [3,4]'. Raman measurements confirmed the presence of the O-O fragment by detecting a new vibration band in [3,4]' that undergoes a 46 cm{sup -1} shift to lower energy upon {sup 16}O/{sup 18}O exchange. Under the conditions of the experiment at pH 1, the [3,4]' intermediate is the catalytic steady state form of the blue dimer catalyst, suggesting that its oxidation is the rate-limiting step.

  7. Next Generation Nuclear Plant Steam Generator and Intermediate Heat Exchanger Materials Research and Development Plan

    SciTech Connect (OSTI)

    J. K. Wright

    2010-09-01

    DOE has selected the High Temperature Gas-cooled Reactor (HTGR) design for the Next Generation Nuclear Plant (NGNP) Project. The NGNP will demonstrate the use of nuclear power for electricity and hydrogen production. It will have an outlet gas temperature in the range of 900°C and a plant design service life of 60 years. The reactor design will be a graphite moderated, helium-cooled, prismatic or pebble-bed reactor and use low-enriched uranium, Tri-Isotopic (TRISO)-coated fuel. The plant size, reactor thermal power, and core configuration will ensure passive decay heat removal without fuel damage or radioactive material releases during accidents. The NGNP Materials Research and Development (R&D) Program is responsible for performing R&D on likely NGNP materials in support of the NGNP design, licensing, and construction activities. Today’s high-temperature alloys and associated ASME Codes for reactor applications are approved up to 760°C. However, some primary system components, such as the Intermediate Heat Exchanger (IHX) for the NGNP will require use of materials that can withstand higher temperatures. The thermal, environmental, and service life conditions of the NGNP will make selection and qualification of some high-temperature materials a significant challenge. Examples include materials for the core barrel and core internals, such as the control rod sleeves. The requirements of the materials for the IHX are among the most demanding. Selection of the technology and design configuration for the NGNP must consider both the cost and risk profiles to ensure that the demonstration plant establishes a sound foundation for future commercial deployments. The NGNP challenge is to achieve a significant advancement in nuclear technology while at the same time setting the stage for an economically viable deployment of the new technology in the commercial sector soon after 2020. A number of solid solution strengthened nickel based alloys have been considered for application in heat exchangers and core internals for the NGNP. The primary candidates are Inconel 617, Haynes 230, Incoloy 800H and Hastelloy XR. Based on the technical maturity, availability in required product forms, experience base, and high temperature mechanical properties all of the vendor pre-conceptual design studies have specified Alloy 617 as the material of choice for heat exchangers. Also a draft code case for Alloy 617 was developed previously. Although action was suspended before the code case was accepted by ASME, this draft code case provides a significant head start for achieving codification of the material. Similarly, Alloy 800H is the material of choice for control rod sleeves. In addition to the above listed considerations, Alloy 800H is already listed in the nuclear section of the ASME Code; although the maximum use temperature and time need to be increased.

  8. Next Generation Nuclear Plant Intermediate Heat Exchanger Materials Research and Development Plan (PLN-2804)

    SciTech Connect (OSTI)

    J. K. Wright

    2008-04-01

    DOE has selected the High Temperature Gas-cooled Reactor (HTGR) design for the Next Generation Nuclear Plant (NGNP) Project. The NGNP will demonstrate the use of nuclear power for electricity and hydrogen production. It will have an outlet gas temperature in the range of 900°C and a plant design service life of 60 years. The reactor design will be a graphite moderated, helium-cooled, prismatic or pebble-bed reactor and use low-enriched uranium, Tri-Isotopic (TRISO)-coated fuel. The plant size, reactor thermal power, and core configuration will ensure passive decay heat removal without fuel damage or radioactive material releases during accidents. The NGNP Materials Research and Development (R&D) Program is responsible for performing R&D on likely NGNP materials in support of the NGNP design, licensing, and construction activities. Today’s high-temperature alloys and associated ASME Codes for reactor applications are approved up to 760°C. However, some primary system components, such as the Intermediate Heat Exchanger (IHX) for the NGNP will require use of materials that can withstand higher temperatures. The thermal, environmental, and service life conditions of the NGNP will make selection and qualification of some high-temperature materials a significant challenge. Examples include materials for the core barrel and core internals, such as the control rod sleeves. The requirements of the materials for the IHX are among the most demanding. Selection of the technology and design configuration for the NGNP must consider both the cost and risk profiles to ensure that the demonstration plant establishes a sound foundation for future commercial deployments. The NGNP challenge is to achieve a significant advancement in nuclear technology while at the same time setting the stage for an economically viable deployment of the new technology in the commercial sector soon after 2020. A number of solid solution strengthened nickel based alloys have been considered for application in heat exchangers and core internals for the NGNP. The primary candidates are Inconel 617, Haynes 230, Incoloy 800H and Hastelloy XR. Based on the technical maturity, availability in required product forms, experience base, and high temperature mechanical properties all of the vendor pre-conceptual design studies have specified Alloy 617 as the material of choice for heat exchangers. Also a draft code case for Alloy 617 was developed previously. Although action was suspended before the code case was accepted by ASME, this draft code case provides a significant head start for achieving codification of the material. Similarly, Alloy 800H is the material of choice for control rod sleeves. In addition to the above listed considerations, Alloy 800H is already listed in the nuclear section of the ASME Code; although the maximum use temperature and time need to be increased.

  9. ISO standardization of scaling factor method for low and intermediate level radioactive wastes generated at nuclear power plants

    SciTech Connect (OSTI)

    Kashiwagi, Makoto; Masui, Hideki; Denda, Yasutaka; James, David; Lantes, Bertrand; Mueller, Wolfgang; Garamszeghy, Mike; Leganes, Jose Luis; Maxeiner, Harald; Van Velzen, Leo

    2007-07-01

    Low- and intermediate-level radioactive wastes (L-ILW ) generated at nuclear power plants are disposed of in various countries. In the disposal of such wastes, it is required that the radioactivity concentrations of waste packages should be declared with respect to difficult-to-measure nuclides (DTM nuclides), such as C-14, Ni-63 and a-emitting nuclides, which are often limited to maximum values in disposal licenses, safety cases and/or regulations for maximum radioactive concentrations. To fulfill this requirement, the Scaling Factor method (SF method) has been applied in various countries as a principal method for determining the concentrations of DTM nuclides. In the SF method, the concentrations of DTM nuclides are determined by multiplying the concentrations of certain key nuclides by SF values (the determined ratios of radioactive concentration between DTM nuclides and those key nuclides). The SF values used as conversion factors are determined from the correlation between DTM nuclides and key nuclides such as Co-60. The concentrations of key nuclides are determined by {gamma} ray measurements which can be made comparatively easily from outside the waste package. The SF values are calculated based on the data obtained from the radiochemical analysis of waste samples. The use of SFs, which are empirically based on analytical data, has become established as a widely recognized 'de facto standard'. A number of countries have independently collected nuclide data by analysis over many years and each has developed its own SF method, but all the SF methods that have been adopted are similar. The project team for standardization had been organized for establishing this SF method as a 'de jure standard' in the international standardization system of the International Organization for Standardization (ISO). The project team for standardization has advanced the standardization through technical studies, based upon each country's study results and analysis data. The conclusions reached by the project team was published as ISO International Standard 21238:2007 'The Scaling Factor method to determine the radioactivity of low- and intermediate-level radioactive waste packages generated at nuclear power plants'. This paper gives an introduction to the international standardization process for the SF method and the contents of the recently published International Standard. (authors)

  10. MCNP6 Simulation of Light and Medium Nuclei Fragmentation at Intermediate Energies

    SciTech Connect (OSTI)

    Mashnik, Stepan Georgievich; Kerby, Leslie Marie

    2015-08-24

    Fragmentation reactions induced on light and medium nuclei by protons and light nuclei of energies around 1 GeV/nucleon and below are studied with the Los Alamos transport code MCNP6 and with its CEM03.03 and LAQGSM03.03 event generators. CEM and LAQGSM assume that intermediate-energy fragmentation reactions on light nuclei occur generally in two stages. The first stage is the intranuclear cascade (INC), followed by the second, Fermi breakup disintegration of light excited residual nuclei produced after the INC. CEM and LAQGSM account also for coalescence of light fragments (complex particles) up to sup>4He from energetic nucleons emitted during INC. We investigate the validity and performance of MCNP6, CEM, and LAQGSM in simulating fragmentation reactions at intermediate energies and discuss possible ways of further improving these codes.

  11. IPHAS J062746.41+014811.3: A DEEPLY ECLIPSING INTERMEDIATE POLAR

    SciTech Connect (OSTI)

    Aungwerojwit, A.; Gaensicke, B. T.; Wheatley, P. J.; Pyrzas, S.; Staels, B.; Krajci, T.; Rodriguez-Gil, P.

    2012-10-20

    We present time-resolved photometry of a cataclysmic variable discovered in the Isaac Newton Telescope Photometric H{alpha} Survey of the northern galactic plane, IPHAS J062746.41+014811.3, and classify the system as the fourth deeply eclipsing intermediate polar known with an orbital period of P {sub orb} = 8.16 hr and a spin period of P {sub spin} = 2210 s. The system shows mild variations of its brightness that appear to be accompanied by a change in the amplitude of the spin modulation at optical wavelengths and a change in the morphology of the eclipse profile. The inferred magnetic moment of the white dwarf is {mu}{sub wd} {approx} (6-7) Multiplication-Sign 10{sup 33} G cm{sup 3}, and in this case IPHAS J062746.41+014811.3 will evolve either into a short-period EX Hya-like intermediate polar with a large P {sub spin}/P{sub orb} ratio or, perhaps more likely, into a synchronized polar. Swift observations show that the system is an ultraviolet and X-ray source, with a hard X-ray spectrum that is consistent with those seen in other intermediate polars. The ultraviolet light curve shows orbital modulation and an eclipse, while the low signal-to-noise ratio X-ray light curve does not show a significant modulation on the spin period. The measured X-ray flux is about an order of magnitude lower than would be expected from scaling by the optical fluxes of well-known X-ray-selected intermediate polars.

  12. CRF: First Direct Detection of QOOH Intermediate Shows Long Lifetime of Key

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Species CRF: First Direct Detection of QOOH Intermediate Shows Long Lifetime of Key Species - Sandia Energy Energy Search Icon Sandia Home Locations Contact Us Employee Locator Energy & Climate Secure & Sustainable Energy Future Stationary Power Energy Conversion Efficiency Solar Energy Wind Energy Water Power Supercritical CO2 Geothermal Natural Gas Safety, Security & Resilience of the Energy Infrastructure Energy Storage Nuclear Power & Engineering Grid Modernization

  13. Liquid Fuels via Upgrading of Syngas Intermediates Presentation for BETO 2015 Project Peer Review

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    11.2.13 Liquid Fuels via Upgrading of Syngas Intermediates March 26 th , 2015 Indirect Liquefaction Technology Area Review Robert A. Dagle, Karthi Ramasamy, Michel J. Gray Pacific Northwest National Laboratory This presentation does not contain any proprietary, confidential, or otherwise restricted information Goal Statement  Problem: Conventional synthetic fuel synthesis processes (e.g., FT, MTG, MTOGD) have drawbacks, specifically for the scale of biomass.  FT provides diesel blend but

  14. Conversion Technologies II: Bio-Oils, Sugar Intermediates, Precursors, Distributed Models, and Refinery Co-Processing

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Conversion Technologies II: Bio-Oils, Sugar Intermediates, Precursors, Distributed Models, and Refinery Co-Processing July 30, 2014 Bryna Berendzen Technology Manager BETO Conversion Program 2 | Bioenergy Technologies Office Conversion Program FY13/14 Workshops * In the past year BETO has held 3 public workshops to engage stakeholders in discussions on the R&D needs within the various conversion technologies * Biochemical: o PRINCE - Process Integration and Carbon Efficiencies - June 11-12,

  15. Catalytic Upgrading of Thermochemical Intermediates to Hydrocarbons Presentation for BETO 2015 Project Peer Review

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    International RTI International RTI International is a trade name of Research Triangle Institute. www.rti.org 2015 DOE Bioenergy Technologies Office (BETO) Project Peer Review WBS 2.5.4.405 - Catalytic Upgrading of Thermochemical Intermediates to Hydrocarbons March 24, 2015 Bio-Oil Technology Area Review David C. Dayton, PI RTI International This presentation does not contain any proprietary, confidential, or otherwise restricted information RTI International Goals and Objectives Objective:

  16. Characteristics and sources of intermediate size particles in recovery boilers : final project report.

    SciTech Connect (OSTI)

    Baxter, Larry L.; Shaddix, Christopher R.; Verrill, Christopher L.; Wessel, Richard A.

    2005-02-01

    As part of the U.S. Department of Energy (DOE) Office of Industrial Technologies (OIT) Industries of the Future (IOF) Forest Products research program, a collaborative investigation was conducted on the sources, characteristics, and deposition of particles intermediate in size between submicron fume and carryover in recovery boilers. Laboratory experiments on suspended-drop combustion of black liquor and on black liquor char bed combustion demonstrated that both processes generate intermediate size particles (ISP), amounting to 0.5-2% of the black liquor dry solids mass (BLS). Measurements in two U.S. recovery boilers show variable loadings of ISP in the upper furnace, typically between 0.6-3 g/Nm{sup 3}, or 0.3-1.5% of BLS. The measurements show that the ISP mass size distribution increases with size from 5-100 {micro}m, implying that a substantial amount of ISP inertially deposits on steam tubes. ISP particles are depleted in potassium, chlorine, and sulfur relative to the fuel composition. Comprehensive boiler modeling demonstrates that ISP concentrations are substantially overpredicted when using a previously developed algorithm for ISP generation. Equilibrium calculations suggest that alkali carbonate decomposition occurs at intermediate heights in the furnace and may lead to partial destruction of ISP particles formed lower in the furnace. ISP deposition is predicted to occur in the superheater sections, at temperatures greater than 750 C, when the particles are at least partially molten.

  17. Buildings Energy Data Book: 7.6 Efficiency Standards for Lighting

    Buildings Energy Data Book [EERE]

    3 Efficiency Standards for Medium Base Compact Fluorescent Lamps (1) Factor Requirements Lamp Power (W) & Configuration Minimum Efficacy: lumens/watt (based upon initial lumen data) Bare Lamp: Lamp Power < 15 45.0 Lamp Power ≥ 15 60.0 Covered Lamp (no reflector): Lamp Power < 15 40.0 15 ≤ Lamp Power < 19 48.0 19 ≤ Lamp Power < 25 50.0 25 ≤ Lamp Power 55.0 Note(s): Source(s): 1) Effective for products manufactured on or after January 1, 2006

  18. Single-Step Syngas-to-Distillates (S2D) Synthesis via Methanol and Dimethyl Ether Intermediates: Final Report

    SciTech Connect (OSTI)

    Dagle, Robert A.; Lebarbier, Vanessa MC; Lizarazo Adarme, Jair A.; King, David L.; Zhu, Yunhua; Gray, Michel J.; Jones, Susanne B.; Biddy, Mary J.; Hallen, Richard T.; Wang, Yong; White, James F.; Holladay, Johnathan E.; Palo, Daniel R.

    2013-11-26

    The objective of the work was to enhance price-competitive, synthesis gas (syngas)-based production of transportation fuels that are directly compatible with the existing vehicle fleet (i.e., vehicles fueled by gasoline, diesel, jet fuel, etc.). To accomplish this, modifications to the traditional methanol-to-gasoline (MTG) process were investigated. In this study, we investigated direct conversion of syngas to distillates using methanol and dimethyl ether intermediates. For this application, a Pd/ZnO/Al2O3 (PdZnAl) catalyst previously developed for methanol steam reforming was evaluated. The PdZnAl catalyst was shown to be far superior to a conventional copper-based methanol catalyst when operated at relatively high temperatures (i.e., >300°C), which is necessary for MTG-type applications. Catalytic performance was evaluated through parametric studies. Process conditions such as temperature, pressure, gas-hour-space velocity, and syngas feed ratio (i.e., hydrogen:carbon monoxide) were investigated. PdZnAl catalyst formulation also was optimized to maximize conversion and selectivity to methanol and dimethyl ether while suppressing methane formation. Thus, a PdZn/Al2O3 catalyst optimized for methanol and dimethyl ether formation was developed through combined catalytic material and process parameter exploration. However, even after compositional optimization, a significant amount of undesirable carbon dioxide was produced (formed via the water-gas-shift reaction), and some degree of methane formation could not be completely avoided. Pd/ZnO/Al2O3 used in combination with ZSM-5 was investigated for direct syngas-to-distillates conversion. High conversion was achieved as thermodynamic constraints are alleviated when methanol and dimethyl are intermediates for hydrocarbon formation. When methanol and/or dimethyl ether are products formed separately, equilibrium restrictions occur. Thermodynamic relaxation also enables the use of lower operating pressures than what would be allowed for methanol synthesis alone. Aromatic-rich hydrocarbon liquid (C5+), containing a significant amount of methylated benzenes, was produced under these conditions. However, selectivity control to liquid hydrocarbons was difficult to achieve. Carbon dioxide and methane formation was problematic. Furthermore, saturation of the olefinic intermediates formed in the zeolite, and necessary for gasoline production, occurred over PdZnAl. Thus, yield to desirable hydrocarbon liquid product was limited. Evaluation of other oxygenate-producing catalysts could possibly lead to future advances. Potential exists with discovery of other types of catalysts that suppress carbon dioxide and light hydrocarbon formation. Comparative techno-economics for a single-step syngas-to-distillates process and a more conventional MTG-type process were investigated. Results suggest operating and capital cost savings could only modestly be achieved, given future improvements to catalyst performance. Sensitivity analysis indicated that increased single-pass yield to hydrocarbon liquid is a primary need for this process to achieve cost competiveness.

  19. Energy barriers, cooperativity, and hidden intermediates in the folding of small proteins

    SciTech Connect (OSTI)

    Bai Yawen [Laboratory of Biochemistry, National Cancer Institute, NIH, Building 37, Room 6114E, Bethesda, MD 20892 (United States)]. E-mail: yawen@helix.nih.gov

    2006-02-17

    Current theoretical views of the folding process of small proteins (<{approx}100 amino acids) postulate that the landscape of potential mean force (PMF) for the formation of the native state has a funnel shape and that the free energy barrier to folding arises from the chain configurational entropy only. However, recent theoretical studies on the formation of hydrophobic clusters with explicit water suggest that a barrier should exist on the PMF of folding, consistent with the fact that protein folding generally involves a large positive activation enthalpy at room temperature. In addition, high-resolution structural studies of the hidden partially unfolded intermediates have revealed the existence of non-native interactions, suggesting that the correction of the non-native interactions during folding should also lead to barriers on PMF. To explore the effect of a PMF barrier on the folding behavior of proteins, we modified Zwanzig's model for protein folding with an uphill landscape of PMF for the formation of transition states. We found that the modified model for short peptide segments can satisfy the thermodynamic and kinetic criteria for an apparently two-state folding. Since the Levinthal paradox can be solved by a stepwise folding of short peptide segments, a landscape of PMF with a locally uphill search for the transition state and cooperative stabilization of folding intermediates/native state is able to explain the available experimental results for small proteins. We speculate that the existence of cooperative hidden folding intermediates in small proteins could be the consequence of the highly specific structures of the native state, which are selected by evolution to perform specific functions and fold in a biologically meaningful time scale.

  20. Implementation of Treatment Systems for Low and Intermediate Radioactive Waste at Site Radwaste Treatment Facility (SRTF), PR China - 12556

    SciTech Connect (OSTI)

    Lohmann, Peter; Nasarek, Ralph; Aign, Joerg

    2012-07-01

    The AP1000 reactors being built in the People's Republic of China require a waste treatment facility to process the low and intermediate radioactive waste produced by these nuclear power stations. Westinghouse Electric Germany GmbH was successful in being awarded a contract as to the planning, delivery and commissioning of such a waste treatment facility. The Site Radwaste Treatment Facility (SRTF) is a waste treatment facility that can meet the AP1000 requirements and it will become operational in the near future. The SRTF is situated at the location of Sanmen, People's Republic of China, next to one of the AP1000 and is an adherent building to the AP1000 comprising different waste treatment processes for radioactive spent filter cartridges, ion-exchange resins and radioactive liquid and solid waste. The final product of the SRTF-treatment is a 200 l drum with cemented waste or grouted waste packages for storage in a local storage facility. The systems used in the SRTF are developed for these special requirements, based on experience from similar systems in the German nuclear industry. The main waste treatment systems in the SRTF are: - Filter Cartridge Processing System (FCS); - HVAC-Filter and Solid Waste Treatment Systems (HVS); - Chemical Liquid Treatment Systems (CTS); - Spent Resin Processing Systems (RES); - Mobile Treatment System (MBS). (authors)

  1. A novel and facile decay path of Criegee intermediates by intramolecular insertion reactions via roaming transition states

    SciTech Connect (OSTI)

    Nguyen, Trong-Nghia; Putikam, Raghunath; Lin, M. C.

    2015-03-28

    We have discovered a new and highly competitive product channel in the unimolecular decay process for small Criegee intermediates, CH{sub 2}OO and anti/syn-CH{sub 3}C(H)OO, occurring by intramolecular insertion reactions via a roaming-like transition state (TS) based on quantum-chemical calculations. Our results show that in the decomposition of CH{sub 2}OO and anti-CH{sub 3}C(H)OO, the predominant paths directly produce cis-HC(O)OH and syn-CH{sub 3}C(O)OH acids with >110 kcal/mol exothermicities via loose roaming-like insertion TSs involving the terminal O atom and the neighboring CH bonds. For syn-CH{sub 3}C(H)OO, the major decomposition channel occurs by abstraction of a H atom from the CH{sub 3} group by the terminal O atom producing CH{sub 2}C(H)OOH. At 298 K, the intramolecular insertion process in CH{sub 2}OO was found to be 600 times faster than the commonly assumed ring-closing reaction.

  2. Transition Metal Donor-Peptide-Acceptor Complexes: From Intramolecular Electron Transfer Reactions to the Study of Reactive Intermediates

    SciTech Connect (OSTI)

    Isied, Stephan S.

    2003-03-11

    The trans-polyproline (PII) oligomers (Figure 1) are unusually rigid peptide structures which have been extensively studied by our group for peptide mediated intramolecular electron transfer (ET) at long distances. We have previously studied ET across a series of metal ion donor (D) acceptor (A) oligoproline peptides with different distances, driving forces and reorganizational energies. The majority of these experiments involve generating the ET intermediate using pulse radiolysis methods, although more recently photochemical methods are also used. Results of these studies showed that ET across peptides can vary by more than twelve orders of magnitude. Using ruthenium bipyridine donors, ET reaction rate constants across several proline residues (n = 4 - 9) occurred in the millisecond (ms) to {micro}s timescale, thus limiting the proline peptide conformational motions to only minor changes (far smaller than the large changes that occur on the ms to sec timescale, such as trans to cis proline isomerization). The present report describes our large data base of experimental results for D-peptide-A complexes in terms of a model where the involvement of both superexchange and hopping (hole and electron) mechanisms account for the long range ET rate constants observed. Our data shows that the change from superexchange to hopping mechanisms occurs at different distances depending on the type of D and A and their interactions with the peptides. Our model is also consistent with generalized models for superexchange and hopping which have been put forward by a number of theoretical groups to account for long range ET phenomena.

  3. Intermediate photovoltaic system application experiment operational performance report for G. N. Wilcox Memorial Hospital, Kauai, Hawaii, for November 1982

    SciTech Connect (OSTI)

    Not Available

    1982-01-01

    The data accumulated during November 1982 at the intermediate photovoltaic project at G.N. Wilcox Memorial Hospital, Kauai, Hawaii, are presented. Generated energy and environmental (weather) data are presented graphically. Explanations of irregularities not attributable to weather are provided.

  4. The Precipitation of Sb2Te3 in Sb-rich AgSbTe2 via the Intermediate...

    Office of Scientific and Technical Information (OSTI)

    Title: The Precipitation of Sb2Te3 in Sb-rich AgSbTe2 via the Intermediate Phase (AgSb)3Te4. Abstract not provided. Authors: Sugar, Joshua Daniel ; Medlin, Douglas L. Publication ...

  5. Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non-Road Engines, Report 1 - Updated

    SciTech Connect (OSTI)

    Knoll, K.; West, B.; Clark, W.; Graves, R.; Orban, J.; Przesmitzki, S.; Theiss, T.

    2009-02-01

    Intended for policymakers and others who make decisions about, and set guidelines for, the proper use of intermediate ethanol blends such as E20 in both vehicle engines and other engine types.

  6. Novel intermediate energy X-ray beamline opening for researchers | Argonne

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    National Laboratory A schematic drawing of the Intermediate Energy X-ray beamline optics, showing the source, an EM-VPU; M0 and M1, planar horizontal deflecting mirrors; M2, an internally cooled plane mirror that deflects the beam vertically onto one of the three gratings in the monochromator; M3R, a movable cylindrical mirror that horizontally focuses the source onto the RSXS sample position; M4R, a cylindrical mirror that vertically focuses the exit slit onto the RSXS sample position; and

  7. Liquid Fuels via Uprading of Syngas Intermediates Presentation for BETO 2015 Project Peer Review

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    2015 Project Peer Review March 26, 2015 Liquid Fuels via Upgrading of Syngas Intermediates 2.3.1.305/2.3.1.306 Jesse Hensley - NREL Ted Krause - ANL This presentation does not contain any proprietary, confidential, or otherwise restricted information 2 | Bioenergy Technologies Office 2.3.1.305/2.3.1.306 Goal Statement Project Goal - To develop and demonstrate catalyst technologies that convert biomass-derived synthesis gas to drop-in hydrocarbon fuels and to reduce total cost from the FY14 SOT

  8. Excitation of the 3p states in electron-sodium scattering at intermediate energies

    SciTech Connect (OSTI)

    Kamali, M. Z. M.; Wong, B. R.; Chin, J. H.; Ratnavelu, K.

    2014-03-05

    A coupled-channel-optical method (CCOM), to investigate the excitation of the 3p states for e{sup ?}-Na scattering at intermediate energies, is reported. Nine atomic states( Na(3s), Na(3p), Na(4s), Na(3d), Na(4p), Na(5s), Na(4d), Na(5p), Na(5d) ) together with three optical potentials are used in this work. The inelastic differential cross sections (DCS) as well as the reduced Stokes parameters are compared with latest theoretical data and experimental measurements.

  9. A brief review of intermediate controlled nuclear syntheses (ICNS) without harmful radiations

    SciTech Connect (OSTI)

    Lanjewar, R. B.

    2015-03-10

    Hadronic mechanics gave birth to new magnecular fuels. The present day demand is of clean energy source that is cheap and abundant. Clean energy can be obtained by harnessing renewable energy sources like solar, wind etc. Nuclear energy conventionally produced by fission reactions emits hazardous radiation and radioactive waste. The requirements of clean and safe energy gets fulfilled by novel fuel that achieved by elevating the traditional quantum mechanics to hadronic mechanics and to hadronic chemistry. In the present paper, a comprehensive review on both the theoretical and experimental aspect of the Intermediate Controlled Nuclear Synthesis (ICNS) as developed by Italian American Scientist Professor R. M. Santilli.

  10. Solid-state graphene formation via a nickel carbide intermediate phase [Nickel carbide (Ni3C) as an intermediate phase for graphene formation

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Xiong, W; Zhou, Yunshen; Hou, Wenjia; Guillemet, Thomas; Silvain, Jean-François; Lahaye, Michel; Lebraud, Eric; Xu, Shen; Wang, Xinwei; Cullen, David A; et al

    2015-11-10

    Direct formation of graphene with controlled number of graphitic layers on dielectric surfaces is highly desired for practical applications. Despite significant progress achieved in understanding the formation of graphene on metallic surfaces through chemical vapor deposition (CVD) of hydrocarbons, very limited research is available elucidating the graphene formation process via rapid thermal processing (RTP) of solid-state amorphous carbon, through which graphene is formed directly on dielectric surfaces accompanied by autonomous nickel evaporation. It is suggested that a metastable hexagonal nickel carbide (Ni3C) intermediate phase plays a critical role in transforming amorphous carbon to 2D crystalline graphene and contributing to themore » autonomous Ni evaporation. Temperature resolved carbon and nickel evolution in the RTP process is investigated using Auger electron spectroscopic (AES) depth profiling and glancing-angle X-ray diffraction (GAXRD). Formation, migration and decomposition of the hexagonal Ni3C are confirmed to be responsible for the formation of graphene and the evaporation of Ni at 1100 °C. The Ni3C-assisted graphene formation mechanism expands the understanding of Ni-catalyzed graphene formation, and provides insightful guidance for controlled growth of graphene through the solid-state transformation process.« less

  11. Biochemical Control With Radiotherapy Improves Overall Survival in Intermediate and High-Risk Prostate Cancer Patients Who Have an Estimated 10-Year Overall Survival of >90%

    SciTech Connect (OSTI)

    Herbert, Christopher; Liu, Mitchell; Tyldesley, Scott; Morris, W. James; Joffres, Michel; Khaira, Mandip; Kwan, Winkle; Moiseenko, Vitali; Pickles, Thomas

    2012-05-01

    Purpose: To identify subgroups of patients with carcinoma of the prostate treated with radical radiotherapy that have improved overall survival when disease is biochemically controlled. Methods and Materials: A cohort of 1,060 prostate cancer patients treated with radical radiotherapy was divided into nine subgroups based on National Comprehensive Cancer Network risk category and estimated 10-year overall survival (eOS 10y) derived from the age adjusted Charlson Comorbidity Index. Patients with and without biochemical control were compared with respect to overall survival. Actuarial estimates of overall survival were calculated using the Kaplan-Meier method. Univariate and multivariate Cox proportional hazards models were used for analysis of overall survival. Results: Median follow-up was 125 months (range, 51-176 months). Only the subgroups with high or intermediate risk disease and an eOS 10y of >90% had a statistically significantly improved overall survival when prostate cancer was biochemically controlled. In all other groups, biochemical control made no significant difference to overall survival. In the subgroup with high-risk disease and eOS 10y >90%, actuarial overall survival was 86.3% (95% confidence interval [CI] 78.5%-94.1%) and 62.1% (95% CI 52.9%-71.3%) for patients with biochemical control and biochemical relapse respectively (p = 0.002). In the intermediate risk group with eOS >90%, actuarial overall survival was 95.3% (95% CI 89.0%-100%) and 79.8% (95% CI 68.0%-91.6%) for biochemically controlled and biochemically relapsed patients (p = 0.033). On multivariate analysis, National Comprehensive Cancer Network risk group (p = 0.005), biochemical control (p = 0.033) and eOS 10y (p < 0.001) were statistically significant. Conclusion: Biochemical control translates into improved overall survival in patients with high or intermediate risk disease and an estimated 10-year overall survival of >90%.

  12. Engineering report on drilling in the Sand Wash Basin intermediate grade project

    SciTech Connect (OSTI)

    1980-09-01

    The Sand Wash Basin Intermediate Grade Drilling Project was conducted by Bendix Field Engineering Corporation in support of the US Department of Energy (DOE) National Uranium Resource Evaluation (NURE) program. This project consisted of 19 drill holes ranging in depth from 275 to 1220 feet (83.9 to 372.1 m). A total of 11,569 feet (3528.5 m) was rotary drilled and 130 feet (39.7 m) were cored for a total of 11,699 feet (3568.2 m) for the project. The project objective was to provide comprehensive subsurface geologic data relevant to Intermediate Grade uranium mineralization of the Browns Park Formation in the Sugar Loaf Peak Site A, and the Little Juniper Mountain Site B areas. All boreholes are located on the USGS Juniper Hot Springs and the Lay 7.5-Minute Series (Topographic) Quadrangles. The project began May 2, 1980; drilling was completed June 3, 1980. Site restoration and clean up was initiated immediately upon the completion of the last borehole and was completed June 8, 1980.

  13. Workshop on hadron structure from photo-reactions at intermediate energies: Proceedings

    SciTech Connect (OSTI)

    Nathan, A.M.; Sandorfi, A.M.

    1992-10-01

    This report contains papers on the following topics: The proton compton effect: Recent measurements of the electric and magnetic polorizabilities of the proton; experiments on the electric polarizability of the neutron; chiral symmetry and nucleon polarizabilities; chiral model predictions for electromagnetic polarizabilities of the nucleon, a consumer report; the polarizabilities of bound nucleons; nucleon polarizability in free space and in nuclear matter; mechanisms of photon scattering on nucleons at intermediate energies; pion polarizabilities in chiral perturbation theory; pion polarizabilities and the shielding of {sigma}(700)-meson exchange in {gamma}{gamma}{yields}{pi}{pi} processes; pion and kaon polarizabilities in the quark confinement model; radiative pion photoproduction and pion polarizabilities; pion and sigma polarizabilities and radiative transitions; the quadrupole amplitude in the {gamma}{Nu}-{Delta} transition; pion photoproduction and the {gamma}{Nu}-{Delta} amplitudes; effective- lagrangians, Watson`s theorem, and the E2/M1 mixing ratio in the excitation of the delta resonance; new measurements of the p({rvec {gamma}}, {pi}{sup o}) reaction; multipole analyses and photo-decay couplings at intermediate energies; compton scattering off the proton; connections between compton scattering and pion photoproduction in the delta region; single-pion electroproduction and the transverse one-half and scalar helicity transition form factors; relativistic effects, QCD mixing angles, and {Nu} {yields} {Nu}{gamma} and {Delta} {yields} {gamma}{Nu} transition form factors; electroproduction studies of the {Nu} {yields} {Delta} transition at bates and CEBAF.

  14. THE SIZE DISTRIBUTION OF THE NEPTUNE TROJANS AND THE MISSING INTERMEDIATE-SIZED PLANETESIMALS

    SciTech Connect (OSTI)

    Sheppard, Scott S.; Trujillo, Chadwick A.

    2010-11-10

    We present an ultra-deep survey for Neptune Trojans using the Subaru 8.2 m and Magellan 6.5 m telescopes. The survey reached a 50% detection efficiency in the R band at m{sub R} = 25.7 mag and covered 49 deg{sup 2} of sky. m{sub R} = 25.7 mag corresponds to Neptune Trojans that are about 16 km in radius (assuming an albedo of 0.05). A paucity of smaller Neptune Trojans (radii < 45 km) compared with larger ones was found. The brightest Neptune Trojans appear to follow a steep power-law slope (q = 5 {+-} 1) similar to the brightest objects in the other known stable reservoirs such as the Kuiper Belt, Jupiter Trojans, and main belt asteroids. We find a roll-over for the Neptune Trojans that occurs around a radius of r = 45 {+-} 10 km (m{sub R} = 23.5 {+-} 0.3), which is also very similar to the other stable reservoirs. All the observed stable regions in the solar system show evidence for Missing Intermediate-Sized Planetesimals (MISPs). This indicates a primordial and not collisional origin, which suggests that planetesimal formation proceeded directly from small to large objects. The scarcity of intermediate- and smaller-sized Neptune Trojans may limit them as being a strong source for the short period comets.

  15. Reservoir Modeling by Data Integration via Intermediate Spaces and Artificial Intelligence Tools in MPS Simulation Frameworks

    SciTech Connect (OSTI)

    Ahmadi, Rouhollah; Khamehchi, Ehsan

    2013-12-15

    Conditioning stochastic simulations are very important in many geostatistical applications that call for the introduction of nonlinear and multiple-point data in reservoir modeling. Here, a new methodology is proposed for the incorporation of different data types into multiple-point statistics (MPS) simulation frameworks. Unlike the previous techniques that call for an approximate forward model (filter) for integration of secondary data into geologically constructed models, the proposed approach develops an intermediate space where all the primary and secondary data are easily mapped onto. Definition of the intermediate space, as may be achieved via application of artificial intelligence tools like neural networks and fuzzy inference systems, eliminates the need for using filters as in previous techniques. The applicability of the proposed approach in conditioning MPS simulations to static and geologic data is verified by modeling a real example of discrete fracture networks using conventional well-log data. The training patterns are well reproduced in the realizations, while the model is also consistent with the map of secondary data.

  16. Is Intermediate Radiation Dose Escalation With Concurrent Chemotherapy for Stage III NonSmall-Cell Lung Cancer Beneficial? A Multi-Institutional Propensity Score MatchedAnalysis

    SciTech Connect (OSTI)

    Rodrigues, George; Oberije, Cary; Senan, Suresh; Tsujino, Kayoko; Wiersma, Terry; Moreno-Jimenez, Marta; Kim, Tae Hyun; Marks, Lawrence B.; Rengan, Ramesh; De Petris, Luigi; Ramella, Sara; DeRuyck, Kim; De Dios, Nria Rodriguez; Warner, Andrew; Bradley, Jeffrey D.; Palma, David A.

    2015-01-01

    Purpose: The clinical benefits and risks of dose escalation (DE) for stage III nonsmall-cell lung cancer (NSCLC) remain uncertain despite the results from Radiation Therapy Oncology Group (RTOG) protocol 0617. There is significant heterogeneity of practice, with many clinicians prescribing intermediate dose levels between the 0617 study arms of 60 and 74Gy. This study investigated whether this strategy is associated with any survival benefits/risks by analyzing a large multi-institutional database. Methods and Materials: An individual patient database of stage III NSCLC patients treated with radical intent concurrent chemoradiation therapy was created (13 institutions, n=1274 patients). Patients were divided into 2 groups based on tumor Biological Effective Dose at 10 Gy (BED 10): those receiving standard dose (SD; n=552), consisting of 72Gy?BED 10?76.8Gy (eg 60-64Gy/30-32 fractions [fr]), and those receiving intermediate dose (ID; n=497), consisting of 76.8Gy64Gy/32 fr and <74Gy/37 fr), with lower-dose patients (n=225) excluded from consideration. Patients were then matched using propensity scores, leading to 2 matched groups of 196 patients. Outcomes were compared using various statistics including interquartile range (IQR), Kaplan-Meier curves, and adjusted Cox regression analysis. Results: Matched groups were found to be balanced except for N stage (more N3 disease in SD), median treatment year (SD in 2003; ID in 2007), platinum and taxane chemotherapy (SD in 28%; ID in 39%), and median follow-up (SD were 89months; ID were 40months). Median dose fractionation was 60Gy/30 fr in SD (BED 10 IQR: 72.0-75.5Gy) and 66Gy/33 fr (BED 10 IQR: 78.6-79.2Gy) in ID. Survival curves for SD and ID matched cohorts were statistically similar (P=.27); however, a nonstatistically significant trend toward better survival for ID was observed after 15months (median survival SD: 19.3months; ID: 21.0months). There was an increase in grades III to V lung toxicity associated with ID (13.0% vs 4.9%, respectively). Conclusions: No significant overall survival benefits were found with intermediate DE; however, more grade III or greater lung toxicity was observed. The separation of survival curves after 15months of follow-up suggests that a small overall survival improvement associated with intermediate DE cannot be excluded.

  17. GRB060218 AS A TIDAL DISRUPTION OF A WHITE DWARF BY AN INTERMEDIATE-MASS BLACK HOLE

    SciTech Connect (OSTI)

    Shcherbakov, Roman V.; Reynolds, Christopher S.; Pe'er, Asaf; Haas, Roland; Bode, Tanja; Laguna, Pablo

    2013-06-01

    The highly unusual pair of a gamma-ray burst (GRB) GRB060218 and an associated supernova, SN2006aj, has puzzled theorists for years. A supernova shock breakout and a jet from a newborn stellar mass compact object have been proposed to explain this pair's multiwavelength signature. Alternatively, we propose that the source is naturally explained by another channel: the tidal disruption of a white dwarf (WD) by an intermediate-mass black hole (IMBH). This tidal disruption is accompanied by a tidal pinching, which leads to the ignition of a WD and a supernova. Some debris falls back onto the IMBH, forms a disk, which quickly amplifies the magnetic field, and launches a jet. We successfully fit soft X-ray spectra with the Comptonized blackbody emission from a jet photosphere. The optical/UV emission is consistent with self-absorbed synchrotron emission from the expanding jet front. The temporal dependence of the accretion rate M-dot (t) in a tidal disruption provides a good fit to the soft X-ray light curve. The IMBH mass is found to be about 10{sup 4} M{sub Sun} in three independent estimates: (1) fitting the tidal disruption M-dot (t) to the soft X-ray light curve, (2) computing the jet base radius in a jet photospheric emission model, and (3) inferring the mass of the central black hole based on the host dwarf galaxy's stellar mass. The position of the supernova is consistent with the center of the host galaxy, while the low supernova ejecta mass is consistent with that of a WD. The high expected rate of tidal disruptions in dwarf galaxies is consistent with one source observed by the Swift satellite over several years at a distance of 150 Mpc measured for GRB060218. Encounters with WDs provide much fuel for the growth of IMBHs.

  18. Crystal Chemistry and Luminescence of Ce3+ -Doped Lu2CaMg2(Si,Ge)3O12 and Its Use in LED Based Lighting

    SciTech Connect (OSTI)

    Setlur,A.; Heward, W.; Gao, Y.; Srivastava, A.; Chandron, R.; Shankar, M.

    2006-01-01

    In this paper, we describe the formation and luminescence of a new garnet phosphor for light emitting diode (LED) based lighting, Lu{sub 2}CaMg{sub 2}(Si,Ge){sub 3}O{sub 12}:Ce{sup 3+}.The regions for garnet phase formation are initially described with respect to larger rare earth substitution and show reasonable correlation to previous crystal chemistry studies for the garnet parent structure. While the pure silicate phosphor also has apatite second phases, a significant amount of Ce{sup 3+} enters the garnet phase, giving Ce{sup 3+} luminescence that is significantly redder when compared to typical Al{sup 3+} garnet phosphors with quantum efficiencies comparable to commercial Ce{sup 3+} garnet phosphors. Potential reasons for the emission red shift and the high quantum efficiency are discussed. Finally, the performance of these new phosphors is tested within LED based lamps. Lamps using these phosphors can reach color temperatures required for general illumination lighting and also have comparable phosphor conversion efficiencies when compared to lamps using typical garnet phosphors.

  19. Workshop on hadron structure from photo-reactions at intermediate energies: Proceedings

    SciTech Connect (OSTI)

    Nathan, A.M.; Sandorfi, A.M.

    1992-01-01

    This report contains papers on the following topics: The proton compton effect: Recent measurements of the electric and magnetic polorizabilities of the proton; experiments on the electric polarizability of the neutron; chiral symmetry and nucleon polarizabilities; chiral model predictions for electromagnetic polarizabilities of the nucleon, a consumer report; the polarizabilities of bound nucleons; nucleon polarizability in free space and in nuclear matter; mechanisms of photon scattering on nucleons at intermediate energies; pion polarizabilities in chiral perturbation theory; pion polarizabilities and the shielding of [sigma](700)-meson exchange in [gamma][gamma][yields][pi][pi] processes; pion and kaon polarizabilities in the quark confinement model; radiative pion photoproduction and pion polarizabilities; pion and sigma polarizabilities and radiative transitions; the quadrupole amplitude in the [gamma][Nu]-[Delta] transition; pion photoproduction and the [gamma][Nu]-[Delta] amplitudes; effective- lagrangians, Watson's theorem, and the E2/M1 mixing ratio in the excitation of the delta resonance; new measurements of the p([rvec [gamma

  20. Intermediate-band photosensitive device with quantum dots embedded in energy fence barrier

    DOE Patents [OSTI]

    Forrest, Stephen R. (Ann Arbor, MI); Wei, Guodan (Ann Arbor, MI)

    2010-07-06

    A plurality of layers of a first semiconductor material and a plurality of dots-in-a-fence barriers disposed in a stack between a first electrode and a second electrode. Each dots-in-a-fence barrier consists essentially of a plurality of quantum dots of a second semiconductor material embedded between and in direct contact with two layers of a third semiconductor material. Wave functions of the quantum dots overlap as at least one intermediate band. The layers of the third semiconductor material are arranged as tunneling barriers to require a first electron and/or a first hole in a layer of the first material to perform quantum mechanical tunneling to reach the second material within a respective quantum dot, and to require a second electron and/or a second hole in a layer of the first semiconductor material to perform quantum mechanical tunneling to reach another layer of the first semiconductor material.

  1. Theoretical and experimental study of the intermediate field dynamics of ocean thermal energy conversion plants. Progress report 1978-1979

    SciTech Connect (OSTI)

    Jirka, G.H.; Jones, J.M.; Sargent, F.E.

    1980-03-01

    Results are described of a two-year research effort which has been conducted with the following objectives: (1) investigate analytically and experimentally the intermediate field spreading in a steady ocean current; (2) investigate analytically and experimentally the transient intermediate field spreading in a stagnant ocean; (3) compare the results with other available data on buoyancy driven currents in stratified surroundings, including the concurrent experimental program at MIT Parsons Laboratory; and (4) use the results in the formulation of preliminary siting guidelines for multiple OTEC plant interactions. The theoretical background for the intermediate field spreading is given including both steady-state and transient results. The experiments performed in the Stratified Flow Modeling Basin at Cornell University are described, and the data are compared to the theoretical results and to available experimental data from other sources. The application of the intermediate field results to the OTEC design problem is discussed. Typical intermediate field behavior is predicted for different plant sizes (100 MW/sub e/ and 1 MW/sub e/), designs and ambient ocean conditions. (WHK)

  2. HERSCHEL OBSERVATIONS OF FAR-INFRARED COOLING LINES IN INTERMEDIATE REDSHIFT (ULTRA)-LUMINOUS INFRARED GALAXIES

    SciTech Connect (OSTI)

    Rigopoulou, D.; Magdis, G. E.; Thatte, N.; Hopwood, R.; Clements, D.; Swinyard, B. M.; Pearson, C.; Farrah, D.; Huang, J.-S.; Alonso-Herrero, A.; Bock, J. J.; Cooray, A.; Griffin, M. J.; Oliver, S.; Smith, A.; Wang, L.; Riechers, D.; Scott, D.; Vaccari, M.; Valtchanov, I.

    2014-01-20

    We report the first results from a spectroscopic survey of the [C II] 158?m line from a sample of intermediate redshift (0.2 10{sup 11.5} L {sub ?}), using the Spectral and Photometric Imaging REceiver-Fourier Transform Spectrometer on board the Herschel Space Observatory. This is the first survey of [C II] emission, an important tracer of star formation, at a redshift range where the star formation rate density of the universe increases rapidly. We detect strong [C II] 158?m line emission from over 80% of the sample. We find that the [C II] line is luminous, in the range (0.8-4) 10{sup 3} of the far-infrared continuum luminosity of our sources, and appears to arise from photodissociation regions on the surface of molecular clouds. The L{sub [C} {sub II]}/L {sub IR} ratio in our intermediate redshift (U)LIRGs is on average ?10times larger than that of local ULIRGs. Furthermore, we find that the L{sub [C} {sub II]}/L {sub IR} and L{sub [CII]}/L{sub CO(1-0)} ratios in our sample are similar to those of local normal galaxies and high-z star-forming galaxies. ULIRGs at z ? 0.5 show many similarities to the properties of local normal and high-z star-forming galaxies. Our findings strongly suggest that rapid evolution in the properties of the star-forming regions of (U)LIRGs is likely to have occurred in the last 5 billion years.

  3. Review of Current Experience on Intermediate Heat Exchanger (IHX) and A Recommended Code Approach

    SciTech Connect (OSTI)

    Duane Spencer; Kevin McCoy

    2010-02-02

    The purpose of the ASME/DOE Gen IV Task 7 Part I is to review the current experience on various high temperature reactor intermediate heat exchanger (IHX) concepts. There are several different IHX concepts that could be envisioned for HTR/VHTR applications in a range of temperature from 850C to 950C. The concepts that will be primarily discussed herein are: (1) Tubular Helical Coil Heat Exchanger (THCHE); (2) Plate-Stamped Heat Exchanger (PSHE); (3) Plate-Fin Heat Exchanger (PFHE); and (4) Plate-Machined Heat Exchanger (PMHE). The primary coolant of the NGNP is potentially subject to radioactive contamination by the core as well as contamination from the secondary loop fluid. To isolate the radioactivity to minimize radiation doses to personnel, and protect the primary circuit from contamination, intermediate heat exchangers (IHXs) have been proposed as a means for separating the primary circuit of the NGNP (Next Generation Nuclear Plant) or other process heat application from the remainder of the plant. This task will first review the different concepts of IHX that could be envisioned for HTR/VHTR applications in a range of temperature from 850 to 950 C. This will cover shell-and-tube and compact designs (including the platefin concept). The review will then discuss the maturity of the concepts in terms of design, fabricability and component testing (or feedback from experience when applicable). Particular attention will be paid to the feasibility of developing the IHX concepts for the NGNP with operation expected in 2018-2021. This report will also discuss material candidates for IHX applications and will discuss specific issues that will have to be addressed in the context of the HTR design (thermal aging, corrosion, creep, creep-fatigue, etc). Particular attention will be paid to specific issues associated with operation at the upper end of the creep regime.

  4. EXPLORING INTERMEDIATE (5-40 AU) SCALES AROUND AB AURIGAE WITH THE PALOMAR FIBER NULLER

    SciTech Connect (OSTI)

    Khn, J.; Mennesson, B.; Liewer, K.; Martin, S.; Loya, F.; Serabyn, E.; Millan-gabet, R.

    2015-02-10

    We report on recent K{sub s} -band interferometric observations of the young pre-main-sequence star AB Aurigae obtained with the Palomar Fiber Nuller (PFN). Reaching a contrast of a few 10{sup 4} inside a field of view extending from 35 to 275 mas (5-40 AU at AB Aur's distance), the PFN is able to explore angular scales that are intermediate between those accessed by coronagraphic imaging and long baseline interferometry. This intermediate region is of special interest given that many young stellar objects are believed to harbor extended halos at such angular scales. Using destructive interference (nulling) between two sub-apertures of the Palomar 200 inch telescope and rotating the telescope pupil, we measured a resolved circumstellar excess at all probed azimuth angles. The astrophysical null measured over the full rotation is fairly constant, with a mean value of 1.52%, and a slight additional azimuthal modulation of 0.2%. The isotropic astrophysical null is indicative of circumstellar emission dominated by an azimuthally extended source, possibly a halo, or one or more rings of dust, accounting for several percent of the total K{sub s}-band flux. The modest azimuthal variation may be explained by some skewness or anisotropy of the spatially extended source, e.g., an elliptical or spiral geometry, or clumping, but it could also be due to the presence of a point source located at a separation of ?120 mas (17 AU) with ?6 10{sup 3} of the stellar flux. We combine our results with previous Infrared Optical Telescope Array observations of AB Aur at H band, and demonstrate that a dust ring located at ?30 mas (4.3 AU) represents the best-fitting model to explain both sets of visibilities. We are also able to test a few previously hypothesized models of the incoherent component evident at longer interferometric baselines.

  5. Two-Step Nucleation and Growth of InP Quantum Dots via Magic-Sized Cluster Intermediates

    SciTech Connect (OSTI)

    Gary, Dylan C.; Terban, Maxwell W.; Billinge, Simon J. L.; Cossairt, Brandi M.

    2015-01-30

    We report on the role of magic-sized clusters (MSCs) as key intermediates in the synthesis of indium phosphide quantum dots (InP QDs) from molecular precursors. These observations suggest that previous efforts to control nucleation and growth by tuning precursor reactivity have been undermined by formation of these kinetically persistent MSCs prior to QD formation. The thermal stability of InP MSCs is influenced by the presence of exogenous bases as well as choice of the anionic ligand set. Addition of a primary amine, a common additive in previous InP QD syntheses, to carboxylate terminated MSCs was found to bypass the formation of MSCs, allowing for homogeneous growth of InP QDs through a continuum of isolable sizes. Substitution of the carboxylate ligand set for a phosphonate ligand set increased the thermal stability of one particular InP MSC to 400C. The structure and optical properties of the MSCs with both carboxylate and phosphonate ligand sets were studied by UV-Vis absorption spectroscopy, powder XRD analysis, and solution P{H} and H NMR spectroscopy. Finally, the carboxylate terminated MSCs were identified as effective single source precursors (SSPs) for the synthesis of high quality InP QDs. Employing InP MSCs as SSPs for QDs effectively decouples the formation of MSCs from the subsequent second nucleation event and growth of InP QDs. The concentration dependence of this SSP reaction, as well as the shape uniformity of particles observed by TEM suggests that the stepwise growth from MSCs directly to QDs proceeds via a second nucleation event rather than an aggregative growth mechanism.

  6. Two-Step Nucleation and Growth of InP Quantum Dots via Magic-Sized Cluster Intermediates

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gary, Dylan C.; Terban, Maxwell W.; Billinge, Simon J. L.; Cossairt, Brandi M.

    2015-01-30

    We report on the role of magic-sized clusters (MSCs) as key intermediates in the synthesis of indium phosphide quantum dots (InP QDs) from molecular precursors. These observations suggest that previous efforts to control nucleation and growth by tuning precursor reactivity have been undermined by formation of these kinetically persistent MSCs prior to QD formation. The thermal stability of InP MSCs is influenced by the presence of exogenous bases as well as choice of the anionic ligand set. Addition of a primary amine, a common additive in previous InP QD syntheses, to carboxylate terminated MSCs was found to bypass the formationmore » of MSCs, allowing for homogeneous growth of InP QDs through a continuum of isolable sizes. Substitution of the carboxylate ligand set for a phosphonate ligand set increased the thermal stability of one particular InP MSC to 400°C. The structure and optical properties of the MSCs with both carboxylate and phosphonate ligand sets were studied by UV-Vis absorption spectroscopy, powder XRD analysis, and solution ³¹P{¹H} and ¹H NMR spectroscopy. Finally, the carboxylate terminated MSCs were identified as effective single source precursors (SSPs) for the synthesis of high quality InP QDs. Employing InP MSCs as SSPs for QDs effectively decouples the formation of MSCs from the subsequent second nucleation event and growth of InP QDs. The concentration dependence of this SSP reaction, as well as the shape uniformity of particles observed by TEM suggests that the stepwise growth from MSCs directly to QDs proceeds via a second nucleation event rather than an aggregative growth mechanism.« less

  7. Surface-Bound Intermediates in Low-Temperature Methanol Synthesis on Copper. Participants and Spectators

    SciTech Connect (OSTI)

    Yang, Yong; Mei, Donghai; Peden, Charles H.F.; Campbell, Charles T.; Mims, Charles A.

    2015-11-03

    The reactivity of surface adsorbed species present on copper catalysts during methanol synthesis at low temperatures was studied by simultaneous infrared spectroscopy (IR) and mass spectroscopy (MS) measurements during “titration” (transient surface reaction) experiments with isotopic tracing. The results show that adsorbed formate is a major bystander species present on the surface under steady-state methanol synthesis reaction conditions, but it cannot be converted to methanol by reaction with pure H2, nor with H2 plus added water. Formate-containing surface adlayers for these experiments were produced during steady state catalysis in (a) H2:CO2 (with substantial formate coverage) and (b) moist H2:CO (with no IR visible formate species). Both these reaction conditions produce methanol at steady state with relatively high rates. Adlayers containing formate were also produced by (c) formic acid adsorption. Various "titration" gases were used to probe these adlayers at modest temperatures (T = 410-450K) and 6 bar total pressure. Methanol gas (up to ~1% monolayer equivalent) was produced in "titration" from the H2:CO2 catalytic adlayers by H2 plus water, but not by dry hydrogen. The decay in the formate IR features accelerated in the presence of added water vapor. The H2:CO:H2O catalytic adlayer produced similar methanol titration yields in H2 plus water but showed no surface formate features in IR (less than 0.2% monolayer coverage). Finally, formate from formic acid chemisorption produced no methanol under any titration conditions. Even under (H2:CO2) catalytic reaction conditions, isotope tracing showed that pre-adsorbed formate from formic acid did not contribute to the methanol produced. Although non-formate intermediates exist during low temperature methanol synthesis on copper which can be converted to methanol gas by titration with pure H2 plus water in sufficient quantities for that intermediate to be observable by IR, formate itself is only a "spectator" in this reaction and gives no observable methanol upon any titration we performed with H2 or H2 plus water.

  8. Intermediate photovoltaic system application experiment operational performance report, for G. N. Wilcox Memorial Hospital, Kauai, Hawaii. Vol. 9

    SciTech Connect (OSTI)

    Not Available

    1983-06-01

    This report presents the data accumulated during January 1983 at the intermediate photovoltaic project at G.N. Wilcox Memorial Hospital, Kauai, Hawaii. Generated energy and environmental (weather) data are presented graphically. Explanations of irregularities not attributable to weather are provided.

  9. Intermediate photovoltaic system application experiment operational performance report. Volume 1. For G. N. Wilcox Memorial Hospital, Kauai, Hawaii

    SciTech Connect (OSTI)

    Not Available

    1982-09-01

    Presented are the data accumulated during January, February, and March 1982 at the intermediate photovoltaic project at G.N. Wilcox Memorial Hospital, Kauai, Hawaii. Generated energy and environmental (weather) data are presented graphically. Explanations of irregularities not attributable to weather are provided.

  10. Intermediate photovoltaic system application experiment operational performance report. Volume 2 for G. N. Wilcox Memorial Hospital, Kauai, HI

    SciTech Connect (OSTI)

    Not Available

    1982-10-01

    Presented are the data accumulated during April and May 1982 at this intermediate photovoltaic project at G.N. Wilcox Memorial Hospital, Kauai, Hawaii. Generated energy and environmental (weather) data are presented graphically. Explanations of irregularities not attributable to weather are provided.

  11. Energy and Mass Dependences of the Parameters of the Semimicroscopic Folding Model for Alpha Particles at Low and Intermediate Energies

    SciTech Connect (OSTI)

    Kuterbekov, K.A.; Zholdybayev, T.K.; Kukhtina, I.N.; Penionzhkevich, Yu.E.

    2005-06-01

    The energy and mass dependences of the parameters of the semimicroscopic alpha-particle potential are investigated for the first time in the region of low and intermediate energies. Within the semimicroscopic folding model, both elastic and inelastic differential and total cross sections for reactions on various nuclei are well described by using global parameters obtained in this study.

  12. MCNP6 Simulation of Light and Medium Nuclei Fragmentation at Intermediate Energies

    SciTech Connect (OSTI)

    Mashnik, Stepan Georgievich; Kerby, Leslie Marie

    2015-05-22

    MCNP6, the latest and most advanced LANL Monte Carlo transport code, representing a merger of MCNP5 and MCNPX, is actually much more than the sum of those two computer codes; MCNP6 is available to the public via RSICC at Oak Ridge, TN, USA. In the present work, MCNP6 was validated and verified (V&V) against different experimental data on intermediate-energy fragmentation reactions, and results by several other codes, using mainly the latest modifications of the Cascade-Exciton Model (CEM) and of the Los Alamos version of the Quark-Gluon String Model (LAQGSM) event generators CEM03.03 and LAQGSM03.03. It was found that MCNP6 using CEM03.03 and LAQGSM03.03 describes well fragmentation reactions induced on light and medium target nuclei by protons and light nuclei of energies around 1 GeV/nucleon and below, and can serve as a reliable simulation tool for different applications, like cosmic-ray-induced single event upsets (SEU’s), radiation protection, and cancer therapy with proton and ion beams, to name just a few. Future improvements of the predicting capabilities of MCNP6 for such reactions are possible, and are discussed in this work.

  13. A tidal disruption event in a nearby galaxy hosting an intermediate mass black hole

    SciTech Connect (OSTI)

    Donato, D.; Troja, E.; Pursimo, T.; Cheung, C. C.; Kutyrev, A.; Landt, H.; Butler, N. R.

    2014-02-01

    We report the serendipitous discovery of a bright point source flare in the Abell cluster A1795 with archival EUVE and Chandra observations. Assuming the EUVE emission is associated with the Chandra source, the X-ray 0.5-7 keV flux declined by a factor of ?2300 over a time span of 6 yr, following a power-law decay with index ?2.44 0.40. The Chandra data alone vary by a factor of ?20. The spectrum is well fit by a blackbody with a constant temperature of kT ? 0.09 keV (?10{sup 6} K). The flare is spatially coincident with the nuclear region of a faint, inactive galaxy with a photometric redshift consistent at the 1? level with the cluster (z = 0.062476). We argue that these properties are indicative of a tidal disruption of a star by a black hole (BH) with log (M {sub BH}/M {sub ?}) ? 5.5 0.5. If so, such a discovery indicates that tidal disruption flares may be used to probe BHs in the intermediate mass range, which are very difficult to study by other means.

  14. Communication: Ultraviolet photodissociation dynamics of the simplest Criegee intermediate CH{sub 2}OO

    SciTech Connect (OSTI)

    Lehman, Julia H.; Li, Hongwei; Beames, Joseph M.; Lester, Marsha I.

    2013-10-14

    The velocity and angular distributions of O {sup 1}D photofragments arising from UV excitation of the CH{sub 2}OO intermediate on the B {sup 1}A??X {sup 1}A? transition are characterized using velocity map ion imaging. The anisotropic angular distribution yields the orientation of the transition dipole moment, which reflects the ?*?? character of the electronic transition associated with the COO group. The total kinetic energy release distributions obtained at several photolysis wavelengths provide detail on the internal energy distribution of the formaldehyde cofragments and the dissociation energy of CH{sub 2}OO X {sup 1}A? to O {sup 1}D + H{sub 2}CO X {sup 1}A{sub 1}. A common termination of the total kinetic energy distributions, after accounting for the different excitation energies, gives an upper limit for the CH{sub 2}OO X {sup 1}A? dissociation energy of D{sub 0}? 54 kcal mol{sup ?1}, which is compared with theoretical predictions including high level multi-reference ab initio calculations.

  15. Structure of intermediate shocks in collisionless anisotropic Hall-magnetohydrodynamics plasma models

    SciTech Connect (OSTI)

    Snchez-Arriaga, G.

    2013-10-15

    The existence of discontinuities within the double-adiabatic Hall-magnetohydrodynamics (MHD) model is discussed. These solutions are transitional layers where some of the plasma properties change from one equilibrium state to another. Under the assumption of traveling wave solutions with velocity C and propagation angle ? with respect to the ambient magnetic field, the Hall-MHD model reduces to a dynamical system and the waves are heteroclinic orbits joining two different fixed points. The analysis of the fixed points rules out the existence of rotational discontinuities. Simple considerations about the Hamiltonian nature of the system show that, unlike dissipative models, the intermediate shock waves are organized in branches in parameter space, i.e., they occur if a given relationship between ? and C is satisfied. Electron-polarized (ion-polarized) shock waves exhibit, in addition to a reversal of the magnetic field component tangential to the shock front, a maximum (minimum) of the magnetic field amplitude. The jumps of the magnetic field and the relative specific volume between the downstream and the upstream states as a function of the plasma properties are presented. The organization in parameter space of localized structures including in the model the influence of finite Larmor radius is discussed.

  16. Intermediate-scale high-solids anaerobic digestion system operational development

    SciTech Connect (OSTI)

    Rivard, C.J.

    1995-02-01

    Anaerobic bioconversion of solid organic wastes represents a disposal option in which two useful products may be produced, including a medium Btu fuel gas (biogas) and a compost-quality organic residue. The application of high-solids technology may offer several advantages over conventional low-solids digester technology. Operation of the anaerobic digestion process at high solids reduces the level of process water and thereby the size and capital costs for the digester system. In addition, by virtue of the lack of available water, the microbial catalysts are more productive in feedstock polymer hydrolysis. The National Renewable Energy Laboratory (NREL) has developed a unique digester system capable of uniformly mixing high-solids materials at low cost. Information gained from laboratory-scale digester research was used to develop die intermediate-scale digester system. This system represents a 50-fold scale-up of the original digester system and includes continuous feed addition and computer monitoring and control. During the first 1.15 years of operation, a variety of modifications and improvements were instituted to increase the safety, reliability, and performance of the system. Those improvements -- which may be critical in further scale-up efforts using the NREL high-solids digester design -- are detailed in this report.

  17. Sensor and numerical simulator evaluation for porous medium desiccation and rewetting at the intermediate laboratory scale

    SciTech Connect (OSTI)

    Oostrom, Martinus; Wietsma, Thomas W.; Strickland, Christopher E.; Freedman, Vicky L.; Truex, Michael J.

    2012-02-01

    Soil desiccation, in conjunction with surface infiltration control, is considered at the Hanford Site as a potential technology to limit the flux of technetium and other contaminants in the vadose zone to the groundwater. An intermediate-scale experiment was conducted to test the response of a series of instruments to desiccation and subsequent rewetting of porous media. The instruments include thermistors, thermocouple psychrometers, dual-probe heat pulse sensors, heat dissipation units, and humidity probes. The experiment was simulated with the multifluid flow simulator STOMP, using independently obtained hydraulic and thermal porous medium properties. All instrument types used for this experiment were able to indicate when the desiccation front passed a certain location. In most cases the changes were sharp, indicating rapid changes in moisture content, water potential, or humidity. However, a response to the changing conditions was recorded only when the drying front was very close to a sensor. Of the tested instruments, only the heat dissipation unit and humidity probes were able to detect rewetting. The numerical simulation results reasonably match the experimental data, indicating that the simulator captures the pertinent gas flow and transport processes related to desiccation and rewetting and may be useful in the design and analysis of field tests.

  18. Intermediate-scale tests of sodium interactions with calcite and dolomite aggregate concretes. [LMFBR

    SciTech Connect (OSTI)

    Randich, E.; Acton, R.U.

    1983-09-01

    Two intermediate-scale tests were performed to compare the behavior of calcite and dolomite aggregate concretes when attacked by molten sodium. The tests were performed as part of an interlaboratory comparison between Sandia National Laboratories and Hanford Engineering Development Laboratories. Results of the tests at Sandia National Laboratories are reported here. The results show that both concretes exhibit similar exothermic reactions with molten sodium. The large difference in reaction vigor suggested by thermodynamic considerations of CO/sub 2/ release from calcite and dolomite was not realized. Penetration rates of 1.4 to 1.7 mm/min were observed for short periods of time with reaction zone temperatures in excess of 800/sup 0/C during the energetic attack. The penetration was not uniform over the entire sodium-concrete contact area. Rapid attack may be localized due to inhomogeneities in the concrete. The chemical reaction zone is less then one cm thick for the calcite concrete but is about seven cm thick for the dolomite concrete.

  19. A population of relic intermediate-mass black holes in the halo of the Milky Way

    SciTech Connect (OSTI)

    Rashkov, Valery; Madau, Piero

    2014-01-10

    If 'seed' central black holes were common in the subgalactic building blocks that merged to form present-day massive galaxies, then relic intermediate-mass black holes (IMBHs) should be present in the Galactic bulge and halo. We use a particle tagging technique to dynamically populate the N-body Via Lactea II high-resolution simulation with black holes, and assess the size, properties, and detectability of the leftover population. The method assigns a black hole to the most tightly bound central particle of each subhalo at infall according to an extrapolation of the M {sub BH}-?{sub *} relation, and self-consistently follows the accretion and disruption of Milky Way progenitor dwarfs and their holes in a cosmological 'live' host from high redshift to today. We show that, depending on the minimum stellar velocity dispersion, ? {sub m}, below which central black holes are assumed to be increasingly rare, as many as ?2000 (? {sub m} = 3 km s{sup 1}) or as few as ?70 (? {sub m} = 12 km s{sup 1}) IMBHs may be left wandering in the halo of the Milky Way today. The fraction of IMBHs forced from their hosts by gravitational recoil is ? 20%. We identify two main Galactic subpopulations, 'naked' IMBHs, whose host subhalos were totally destroyed after infall, and 'clothed' IMBHs residing in dark matter satellites that survived tidal stripping. Naked IMBHs typically constitute 40%-50% of the total and are more centrally concentrated. We show that, in the ? {sub m} = 12 km s{sup 1} scenario, the clusters of tightly bound stars that should accompany naked IMBHs would be fainter than m{sub V} = 16 mag, spatially resolvable, and have proper motions of 0.1-10 mas yr{sup 1}. Their detection may provide an observational tool to constrain the formation history of massive black holes in the early universe.

  20. INTERMEDIATE-AGE STELLAR POPULATIONS IN CLASSICAL QUASI-STELLAR OBJECT HOST GALAXIES

    SciTech Connect (OSTI)

    Canalizo, Gabriela; Stockton, Alan E-mail: stockton@ifa.hawaii.edu

    2013-08-01

    Although mergers and starbursts are often invoked in the discussion of quasi-stellar object (QSO) activity in the context of galaxy evolution, several studies have questioned their importance or even their presence in QSO host galaxies. Accordingly, we are conducting a study of z {approx} 0.2 QSO host galaxies previously classified as passively evolving elliptical galaxies. We present deep Keck/LRIS spectroscopy of a sample of 15 hosts and model their stellar absorption spectra using stellar synthesis models. The high signal-to-noise ratio of our spectra allows us to break various degeneracies that arise from different combinations of models, varying metallicities, and contamination from QSO light. We find that none of the host spectra can be modeled by purely old stellar populations and that the majority of the hosts (14/15) have a substantial contribution from intermediate-age populations with ages ranging from 0.7 to 2.4 Gyr. An average host spectrum is strikingly well fit by a combination of an old population and a 2.1 (+0.5, -0.7) Gyr population. The morphologies of the host galaxies suggest that these aging starbursts were induced during the early stages of the mergers that resulted in the elliptical-shaped galaxies that we observe. The current active galactic nucleus activity likely corresponds to the late episodes of accretion predicted by numerical simulations, which occur near the end of the mergers, whereas earlier episodes may be more difficult to observe due to obscuration. Our off-axis observations prevent us from detecting any current star formation or young stellar populations that may be present in the central few kiloparsecs.

  1. A CLOSE-PAIR ANALYSIS OF DAMP MERGERS AT INTERMEDIATE REDSHIFTS

    SciTech Connect (OSTI)

    Chou, Richard C. Y.; Abraham, Roberto G.; Bridge, Carrie R. E-mail: abraham@astro.utoronto.ca

    2012-12-01

    We have studied the kinematics of {approx}2800 candidate close-pair galaxies at 0.1 < z < 1.2 identified from the Canada-France-Hawaii Telescope Legacy Survey fields. Spectra of these systems were obtained using spectrometers on the 6.5 m Magellan and 5 m Hale telescopes. These data allow us to constrain the rate of dry mergers at intermediate redshifts and to test the 'hot halo' model for quenching of star formation. Using virial radii estimated from the correlation between dynamical and stellar masses published by Leauthaud et al., we find that around 1/5 of our candidate pairs are likely to share a common dark matter halo (our metric for close physical association). These pairs are divided into red-red, blue-red, and blue-blue systems using the rest-frame colors classification method introduced in Chou et al.. Galaxies classified as red in our sample have very low star formation rates, but they need not be totally quiescent, and hence we refer to them as 'damp', rather than 'dry', systems. After correcting for known selection effects, the fraction of blue-blue pairs is significantly greater than that of red-red and blue-red pairs. Red-red pairs are almost entirely absent from our sample, suggesting that damp mergers are rare at z {approx} 0.5. Our data support models with a short merging timescale (<0.5 Gyr) in which star formation is enhanced in the early phase of mergers, but quenched in the late phase. Hot halo models may explain this behavior, but only if virial shocks that heat gas are inefficient until major mergers are nearly complete.

  2. Pore-Water Extraction from Unsaturated Porous Media: Intermediate-Scale Laboratory

    SciTech Connect (OSTI)

    Oostrom, Martinus; Truex, Michael J.; Wietsma, Thomas W.; Tartakovsky, Guzel D.

    2014-08-15

    As a remedial approach, vacuum-induced pore-water extraction offers the possibility of contaminant and water removal from the vadose zone, which may be beneficial in reducing the flux of vadose zone contaminants to groundwater. Vadose zone water extraction is being considered at the Hanford Site in Washington State as a means to remove technetium-99 contamination from low permeability sediments with relatively high water contents. A series of intermediate-scale laboratory experiments have been conducted to improve the fundamental understanding and limitations of the technique. Column experiments were designed to investigate the relations between imposed suctions, water saturations, and water production. Flow cell experiments were conducted to investigate the effects of high-permeability layers and near-well compaction on pore-water extraction efficiency. Results show that water extraction from unsaturated systems can be achieved in low permeability sediments, provided that the initial water saturations are relatively high. The presence of a high-permeability layer decreased the yield, and compaction near the well screen had a limited effect on overall performance. In all experiments, large pressure gradients were observed near the extraction screen. Minimum requirements for water extraction include an imposed vacuum-induced suction larger than the initial sediment capillary pressure, in combination with a fully saturated seepage-face boundary. A numerical multiphase simulator with a coupled seepage-face boundary conditions was used to simulate the experiments. Reasonable matches were obtained between measured and simulated results for both water extraction and capillary pressures, suggesting that numerical simulations may be used as a design tool for field-scale applications of pore-water extraction.

  3. The Precipitation of Sb2Te3 in Sb-rich AgSbTe2 via the Intermediate Phase

    Office of Scientific and Technical Information (OSTI)

    (AgSb)3Te4. (Journal Article) | SciTech Connect The Precipitation of Sb2Te3 in Sb-rich AgSbTe2 via the Intermediate Phase (AgSb)3Te4. Citation Details In-Document Search Title: The Precipitation of Sb2Te3 in Sb-rich AgSbTe2 via the Intermediate Phase (AgSb)3Te4. Abstract not provided. Authors: Sugar, Joshua Daniel ; Medlin, Douglas L. Publication Date: 2010-07-01 OSTI Identifier: 1124220 Report Number(s): SAND2010-5024J 492792 DOE Contract Number: DE-AC04-94AL85000 Resource Type: Journal

  4. Photometric investigation of the totally eclipsing contact binary V12 in the intermediate-age open cluster NGC 7789

    SciTech Connect (OSTI)

    Qian, S.-B.; Wang, J.-J.; Liu, L.; Zhou, X.; Essam, A.; Ali, G. B.; Haroon, A.-A.

    2015-02-01

    NGC 7789 is an intermediate-age open cluster with an age similar to the mean age of contact binary stars. V12 is a bright W UMa-type binary star with an orbital period of 0.3917 days. The first complete light curves of V12 in the V, R, and I bands are presented and analyzed with the WilsonDevinney (W-D) method. The results show that V12 is an intermediate-contact binary (f=43.0(2.2)%) with a mass ratio of 3.848, and it is a W-type contact binary where the less massive component is slightly hotter than the more massive one. The asymmetry of the light curves is explained by the presence of a dark spot on the more massive component. The derived orbital inclination (i=83{sub .}{sup ?}6) indicates that it is a totally eclipsing binary, which suggests that the determined parameters are reliable. The orbital period may show a long-term increase at a rate of P-dot =+2.48(0.17)10{sup ?6} days yr{sup ?1} that reveals a rapid mass transfer from the less massive component to the more massive one. However, more observations are needed to confirm this conclusion. The presence of an intermediate-contact binary in an intermediate-age open cluster may suggest that some contact binaries have a very short pre-contact timescale. The presence of a third body and/or stellar collision may help to shorten the pre-contact evolution.

  5. Magneto thermal conductivity of superconducting Nb with intermediate level of impurity

    SciTech Connect (OSTI)

    L.S. Sharath Chandra, M.K. Chattopadhyay, S.B. Roy, V.C. Sahni, G.R. Myneni

    2012-03-01

    Niobium materials with intermediate purity level are used for fabrication of superconducting radio frequency cavities (SCRF), and thermal conductivity is an important parameter influencing the performance of such SCRF cavities. We report here the temperature and magnetic field dependence of thermal conductivity {kappa} for superconducting niobium (Nb) samples, for which the electron mean free path I{sub e}, the phonon mean free path I{sub g}, and the vortex core diameter 2r{sub C} are of the same order of magnitude. The measured thermal conductivity is analyzed using the effective gap model (developed for I{sub e} >> 2r{sub C} (Dubeck et al 1963 Phys. Rev. Lett. 10 98)) and the normal core model (developed for I{sub e} << 2r{sub C} (Ward and Dew-Hughes 1970 J. Phys. C: Solid St. Phys. 3 2245)). However, it is found that the effective gap model is not suitable for low temperatures when I{sub e} {approx} 2r{sub C}. The normal core model, on the other hand, is able to describe {kappa}(T,H) over the entire temperature range except in the field regime between H{sub C1} and H{sub C2} i.e. in the mixed state. It is shown that to understand the complete behavior of {kappa} in the mixed state, the scattering of quasi-particles from the vortex cores and the intervortex quasi-particle tunneling are to be invoked. The quasi-particle scattering from vortices for the present system is understood in terms of the framework of Sergeenkov and Ausloos (1995 Phys. Rev. B 52 3614) extending their approach to the case of Nb. The intervortex tunneling is understood within the framework of Schmidbauer et al (1970 Z. Phys. 240 30). Analysis of the field dependence of thermal conductivity shows that while the quasi-particle scattering from vortices dominates in the low fields, the intervortex quasi-particle tunneling dominates in high fields. Analysis of the temperature dependence of thermal conductivity shows that while the quasi-particle scattering is dominant at low temperatures, the intervortex quasi-particle tunneling is dominant at high temperatures.

  6. Technical Issues Associated With the Use of Intermediate Ethanol Blends (>E10) in the U.S. Legacy Fleet

    SciTech Connect (OSTI)

    Rich, Bechtold; Thomas, John F; Huff, Shean P; Szybist, James P; West, Brian H; Theiss, Timothy J; Timbario, Tom; Goodman, Marc

    2007-08-01

    The Oak Ridge National Laboratory (ORNL) supports the U.S. Department of Energy (DOE) in assessing the impact of using intermediate ethanol blends (E10 to E30) in the legacy fleet of vehicles in the U.S. fleet. The purpose of this report is to: (1) identify the issues associated with intermediate ethanol blends with an emphasis on the end-use or vehicle impacts of increased ethanol levels; (2) assess the likely severity of the issues and whether they will become more severe with higher ethanol blend levels, or identify where the issue is most severe; (3) identify where gaps in knowledge exist and what might be required to fill those knowledge gaps; and (4) compile a current and complete bibliography of key references on intermediate ethanol blends. This effort is chiefly a critical review and assessment of available studies. Subject matter experts (authors and selected expert contacts) were consulted to help with interpretation and assessment. The scope of this report is limited to technical issues. Additional issues associated with consumer, vehicle manufacturer, and regulatory acceptance of ethanol blends greater than E10 are not considered. The key findings from this study are given.

  7. Use of Multiple Reheat Helium Brayton Cycles to Eliminate the Intermediate Heat Transfer Loop for Advanced Loop Type SFRs

    SciTech Connect (OSTI)

    Haihua Zhao; Hongbin Zhang; Samuel E. Bays

    2009-05-01

    The sodium intermediate heat transfer loop is used in existing sodium cooled fast reactor (SFR) plant design as a necessary safety measure to separate the radioactive primary loop sodium from the water of the steam Rankine power cycle. However, the intermediate heat transfer loop significantly increases the SFR plant cost and decreases the plant reliability due to the relatively high possibility of sodium leakage. A previous study shows that helium Brayton cycles with multiple reheat and intercooling for SFRs with reactor outlet temperature in the range of 510C to 650C can achieve thermal efficiencies comparable to or higher than steam cycles or recently proposed supercritical CO2 cycles. Use of inert helium as the power conversion working fluid provides major advantages over steam or CO2 by removing the requirement for safety systems to prevent and mitigate the sodium-water or sodium-CO2 reactions. A helium Brayton cycle power conversion system therefore makes the elimination of the intermediate heat transfer loop possible. This paper presents a pre-conceptual design of multiple reheat helium Brayton cycle for an advanced loop type SFR. This design widely refers the new horizontal shaft distributed PBMR helium power conversion design features. For a loop type SFR with reactor outlet temperature 550C, the design achieves 42.4% thermal efficiency with favorable power density comparing with high temperature gas cooled reactors.

  8. Thioozonide decomposition: sulfur and oxygen atom transfer. Evidence for the formation of a carbonyl O-sulfide intermediate

    SciTech Connect (OSTI)

    Matturro, M.G.; Reynolds, R.P.; Kastrup, R.V.; Pictroski, C.F.

    1986-05-14

    The chemistry of ozonides is of considerable interest from a practical and theoretical viewpoint. Thioozonide 1, formally the monosulfur-substituted ozonide of dimethylcyclobutadiene, has been proposed as an intermediate in the room temperature photooxidation of 2,5-dimethylthiophene. Subsequent low-temperature studies confirmed this structural assignment. When 1 is allowed to warm to room temperature, it rearranges to a mixture of sulfine 2 and cis- and trans-3-hexene-2,5-diones (3c and 3t). Recent examination of the thermal decomposition of 1 has led to a proposed mechanism involving a carbonyl sulfide 4 as an intermediate along the sulfur expulsion pathway to 3c; however, no experimental support for this hypothesis was given. Carbonyl O-sulfides have also been implicated as intermediates from the photolysis of oxathiiranes. The authors report evidence for the formation of 4 during the decomposition of 1 and that elemental sulfur (S/sub 8/) is formed during the reaction by concatenation of sulfur atoms or fragments (S/sub 2/, S/sub 3/, etc.).

  9. Technical support document: Energy efficiency standards for consumer products: Room air conditioners, water heaters, direct heating equipment, mobile home furnaces, kitchen ranges and ovens, pool heaters, fluorescent lamp ballasts and television sets. Volume 2, Fluorescent lamp ballasts, television sets, room air conditioners, and kitchen ranges and ovens

    SciTech Connect (OSTI)

    Not Available

    1993-11-01

    This document is divided into ``volumes`` B through E, dealing with individual classes of consumer products. Chapters in each present engineering analysis, base case forecasts, projected national impacts of standards, life-cycle costs and payback periods, impacts on manufacturers, impacts of standards on electric utilities, and environmental effects. Supporting appendices are included.

  10. Intermediate photovoltaic system application experiment operational performance report. Volume 5. For G. N. Wilcox Memorial Hospital, Kauai, Hawaii for September 1982

    SciTech Connect (OSTI)

    Not Available

    1983-01-01

    Presented are the data accumulated during September 1982 at the intermediate photovoltaic project at G.N. Wilcox Memorial Hospital, Kauai, Hawaii. Generated energy and environmental (weather) data are presented graphically. Explanations of irregularities not attributable to weather are provided.

  11. Intermediate photovoltaic system application experiment operational performance report for G. N. Wilcox Memorial Hospital, Kauai, Hawaii for October 1982. Volume VI

    SciTech Connect (OSTI)

    Not Available

    1983-01-01

    Presented are the data accumulated during October 1982 at the intermediate project at G.N. Wilcox Memorial Hospital, Kauai, Hawaii. Generated energy and environmental (weather) data are presented graphically. Explanations of irregularities not attributable to weather are provided.

  12. Intermediate photovoltaic system application experiment operational performance report. Volume 8. For G. N. Wilcox Memorial Hospital, Kauai, Hawaii for December 1982

    SciTech Connect (OSTI)

    Not Available

    1983-03-01

    Presented are the data accumulated during December 1982 at the intermediate photovoltaic project at G. N. Wilcox Memorial Hospital, Kauai, Hawaii. Generated energy and environmental (weather) data are presented graphiclaly. Explanations of irregularities not attributable to weather are provided.

  13. Advanced Biocatalytic Processing of Heterogeneous Lignocellulosic Feedstocks to a Platform Chemical Intermediate (Lactic acid Ester)

    SciTech Connect (OSTI)

    Dr. Sharon Shoemaker

    2004-09-03

    The development of commercial boi-based processes and products derived from agricultural waste biomass has the potential for significant impact on the economy and security of our nation. Adding value, rather than disposing of the waste of agriculture, can solve an environmental problem and reduce our dependence on foreign sources of fossil fuel for production of chemicals, materials and fuels.

  14. Low and intermediate temperature oxidation of ethanol and ethanol-PRF blends: An experimental and modeling study

    SciTech Connect (OSTI)

    Haas, Francis M.; Chaos, Marcos; Dryer, Frederick L.

    2009-12-15

    In this brief communication, we present new experimental species profile measurements for the low and intermediate temperature oxidation of ethanol under knock-prone conditions. These experiments show that ethanol exhibits no global low temperature reactivity at these conditions, although we note the heterogeneous decomposition of ethanol to ethylene and water. Similar behavior is reported for an E85 blend in n-heptane. Kinetic modeling results are presented to complement these experiments and elucidate the interaction of ethanol and primary reference fuels undergoing cooxidation. (author)

  15. The Path of Carbon in Photosynthesis IV. The Identity and Sequence of the Intermediates in Sucrose Synthesis

    DOE R&D Accomplishments [OSTI]

    Calvin, M.; Benson, A.

    1948-12-14

    The synthesis of sucrose from C{sup 14}0{sub 2} by green algae has been investigated and the intermediates separated by the method of paper chromatography. It is shown that sucrose is the first free sugar appearing during photosynthesis. It is apparently formed by condensation of the glucose-I-phosphate and a fructose phosphate. A series of radioautographs of paper chromatograms of extracts from plants which have photosynthesized for different periods of time has been prepared. The results indicate that 2-phosphoglyceric acid is the first product synthesized from C0{sub 2} during photosynthesis.

  16. Chemically induced Parkinson's disease: intermediates in the oxidation of 1-methyl-4-phenyl-1,2,3,6-tetrahydropyridine to the 1-methyl-4-phenyl-pyridinium ion

    SciTech Connect (OSTI)

    Chacon, J.N.; Chedekel, M.R.; Land, E.J.; Truscott, T.G.

    1987-04-29

    Various unstable intermediate oxidation states have been postulated in the metabolic activation of 1-methyl-4-phenyl-1,2,3,6-tetrahydropyridine to the 1-methyl-4-phenyl pyridinium ion. We now report the first direct observation of these free radical intermediates by pulse radiolysis and flash photolysis. Studies are described of various reactions of such species, in particular with dopamine whose autoxidation to dopamine quinone is reported to be potentiated by 1-methyl-4-phenyl-1,2,3, 6-tetrahydropyridine.

  17. Communication: Spectroscopic characterization of an alkyl substituted Criegee intermediate syn-CH{sub 3}CHOO through pure rotational transitions

    SciTech Connect (OSTI)

    Nakajima, Masakazu; Endo, Yasuki

    2014-01-07

    An alkyl-substituted Criegee intermediate syn-CH{sub 3}CHOO was detected in the gas phase through Fourier-transform microwave spectroscopy. Observed pure rotational transitions show a small splitting corresponding to the A/E components due to the threefold methyl internal rotation. The rotational constants and the barrier height of the hindered methyl rotation were determined to be A = 17?586.5295(15) MHz, B = 7133.4799(41) MHz, C = 5229.1704(40) MHz, and V{sub 3} = 837.1(17)cm{sup ?1}. High-level ab initio calculations which reproduce the experimentally determined values well indicate that the in-plane CH bond in the methyl moiety is trans to the CO bond, and other two protons are directed to the terminal oxygen atom for the most stable structure of syn-CH{sub 3}CHOO. The torsional barrier of the methyl top is fairly large in syn-CH{sub 3}CHOO, implying a significant interaction between the terminal oxygen and the protons of the methyl moiety, which may be responsible for the high production yields of the OH radical from energized alkyl-substituted Criegee intermediates.

  18. Bulgeless galaxies at intermediate redshift: Sample selection, color properties, and the existence of powerful active galactic nuclei

    SciTech Connect (OSTI)

    Bizzocchi, Luca; Leonardo, Elvira; Grossi, Marco; Afonso, Jos; Fernandes, Cristina; Retr, Joo; Filho, Mercedes E.; Lobo, Catarina; Griffith, Roger L.; Anton, Sonia; Bell, Eric F.; Brinchmann, Jarle; Henriques, Bruno; Messias, Hugo

    2014-02-10

    We present a catalog of bulgeless galaxies, which includes 19,225 objects selected in four of the deepest, largest multi-wavelength data sets availableCOSMOS, AEGIS, GEMS, and GOODSat intermediate redshift (0.4 ? z ? 1.0). The morphological classification was provided by the Advanced Camera for Surveys General Catalog (ACS-GC), which used publicly available data obtained with the ACS instrument on the Hubble Space Telescope. Rest-frame photometric quantities were derived using kcorrect. We analyze the properties of the sample and the evolution of pure-disk systems with redshift. Very massive [log (M {sub *}/M {sub ?}) > 10.5] bulgeless galaxies contribute to ?30% of the total galaxy population number density at z ? 0.7, but their number density drops substantially with decreasing redshift. We show that only a negligible fraction of pure disks appear to be quiescent systems, and red sequence bulgeless galaxies show indications of dust-obscured star formation. X-ray catalogs were used to search for X-ray emission within our sample. After visual inspection and detailed parametric morphological fitting we identify 30 active galactic nuclei (AGNs) that reside in galaxies without a classical bulge. The finding of such peculiar objects at intermediate redshift shows that while AGN growth in merger-free systems is a rare event (0.2% AGN hosts in this sample of bulgeless galaxies), it can indeed happen relatively early in the history of the universe.

  19. Absolute total and partial dissociative cross sections of pyrimidine at electron and proton intermediate impact velocities

    SciTech Connect (OSTI)

    Wolff, Wania Luna, Hugo; Sigaud, Lucas; Montenegro, Eduardo C.; Tavares, Andre C.

    2014-02-14

    Absolute total non-dissociative and partial dissociative cross sections of pyrimidine were measured for electron impact energies ranging from 70 to 400 eV and for proton impact energies from 125 up to 2500 keV. MOs ionization induced by coulomb interaction were studied by measuring both ionization and partial dissociative cross sections through time of flight mass spectrometry and by obtaining the branching ratios for fragment formation via a model calculation based on the Born approximation. The partial yields and the absolute cross sections measured as a function of the energy combined with the model calculation proved to be a useful tool to determine the vacancy population of the valence MOs from which several sets of fragment ions are produced. It was also a key point to distinguish the dissociation regimes induced by both particles. A comparison with previous experimental results is also presented.

  20. Reactivity and reaction intermediates for acetic acid adsorbed on CeO2(111)

    SciTech Connect (OSTI)

    Calaza, Florencia; Chen, Tsung-Liang; Mullins, David R; Xu, Ye; Overbury, Steven {Steve} H

    2015-01-01

    Adsorption and reaction of acetic acid on a CeO2(1 1 1) surface was studied by a combination of ultra-highvacuum based methods including temperature desorption spectroscopy (TPD), soft X-ray photoelectronspectroscopy (sXPS), near edge X-ray absorption spectroscopy (NEXAFS) and reflection absorption IRspectroscopy (RAIRS), together with density functional theory (DFT) calculations. TPD shows that thedesorption products are strongly dependent upon the initial oxidation state of the CeO2surface, includingselectivity between acetone and acetaldehyde products. The combination of sXPS and NEXAFS demon-strate that acetate forms upon adsorption at low temperature and is stable to above 500 K, above whichpoint ketene, acetone and acetic acid desorb. DFT and RAIRS show that below 500 K, bridge bondedacetate coexists with a moiety formed by adsorption of an acetate at an oxygen vacancy, formed bywater desorption.

  1. Effects of Intermediate Ethanol Blends on Legacy Vehicles and Small Non?Road Engines, Report 1 - Updated

    SciTech Connect (OSTI)

    Knoll, Keith; West, Brian H; Clark, Wendy; Graves, Ronald L; Orban, John; Przesmitzki, Steve; Theiss, Timothy J

    2009-02-01

    In summer 2007, the U.S. Department of Energy (DOE) initiated a test program to evaluate the potential impacts of intermediate ethanol blends on legacy vehicles and other engines. The purpose of the test program is to assess the viability of using intermediate blends as a contributor to meeting national goals in the use of renewable fuels. Through a wide range of experimental activities, DOE is evaluating the effects of E15 and E20--gasoline blended with 15 and 20% ethanol--on tailpipe and evaporative emissions, catalyst and engine durability, vehicle driveability, engine operability, and vehicle and engine materials. This first report provides the results available to date from the first stages of a much larger overall test program. Results from additional projects that are currently underway or in the planning stages are not included in this first report. The purpose of this initial study was to quickly investigate the effects of adding up to 20% ethanol to gasoline on the following: (1) Regulated tailpipe emissions for 13 popular late model vehicles on a drive cycle similar to real-world driving and 28 small non-road engines (SNREs) under certification or typical in use procedures. (2) Exhaust and catalyst temperatures of the same vehicles under more severe conditions. (3) Temperature of key engine components of the same SNREs under certification or typical in-use conditions. (4) Observable operational issues with either the vehicles or SNREs during the course of testing. As discussed in the concluding section of this report, a wide range of additional studies are underway or planned to consider the effects of intermediate ethanol blends on materials, emissions, durability, and driveability of vehicles, as well as impacts on a wider range of nonautomotive engines, including marine applications, snowmobiles, and motorcycles. Section 1 (Introduction) gives background on the test program and describes collaborations with industry and agencies to date. Section 2 (Experimental Setup) provides details concerning test fuels, vehicle and SNRE selection, and test methods used to conduct the studies presented in this report. Section 3 (Results and Discussion) summarizes the vehicle and SNRE studies and presents data from testing completed to date. Section 4 (Next Steps) describes planned future activities. The appendixes provide test procedure details, vehicle and SNRE emissions standards, analysis details, and additional data and tables from vehicle and SNRE tests.

  2. Structure and reactivity of chemisorbed species and reaction intermediates: Progress report, December 1, 1984--November 30, 1985

    SciTech Connect (OSTI)

    Madey, T.E.; Kelley, R.D.

    1985-08-01

    The areas of work have supported a common theme: the structure and reactivity of chemisorbed species and reaction intermediate of importance to catalysis. A variety of tools have been to study the structure and chemistry of surface species, and to develop models and concepts of broad utility in chemisorption and catalysis. Adsorption of carbon monoxide, ammonia, hydrogen, and sulfur are discussed. Results of the research conducted or completed in the last year, as well as plans for the coming year, are summarized in this report. The results will be presented in three sections: (a) Surface Molecular Structure and Reactivity as Studied Using Electron Simulated Desorption Ion Angular Distribution (ESDIAD) and High Resolution Electron Energy Loss Spectroscopy (HREELS); (b) Neutron Inelastic Scattering Studies of Adsorption and Reaction on Catalysts; and (c) Reaction Kinetics at High Pressures over Single Crystal Catalysts.

  3. Acetaldehyde as an intermediate in the electroreduction of carbon monoxide to ethanol on oxide-derived copper

    SciTech Connect (OSTI)

    Bertheussen, Erlend; Verdaguer-Casadevall, Arnau; Ravasio, Davide; Montoya, Joseph H.; Trimarco, Daniel B.; Roy, Claudie; Meier, Sebastian; Wendland, Jrgen; Nrskov, Jens K.; Stephens, Ifan E. L.; Chorkendorff, Ib

    2015-12-21

    Oxide-derived copper (OD-Cu) electrodes exhibit unprecedented CO reduction performance towards liquid fuels, producing ethanol and acetate with >50 % Faradaic efficiency at -0.3 V (vs. RHE). By using static headspace-gas chromatography for liquid phase analysis, we identify acetaldehyde as a minor product and key intermediate in the electroreduction of CO to ethanol on OD-Cu electrodes. Acetaldehyde is produced with a Faradaic efficiency of ?5 % at -0.33 V (vs. RHE). We show that acetaldehyde forms at low steady-state concentrations, and that free acetaldehyde is difficult to detect in alkaline solutions using NMR spectroscopy, requiring alternative methods for detection and quantification. Our results indicate an important step towards understanding the CO reduction mechanism on OD-Cu electrodes.

  4. Equilibrium intermediate-state patterns in a type-I superconducting slab in an arbitrarily oriented applied magnetic field

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Clem, John; Prozorov, Ruslan; Wijngaarden, Rinke J.

    2013-09-04

    The equilibrium topology of superconducting and normal domains in flat type-I superconductors is investigated. Important improvements with respect to previous work are that (1) the energy of the external magnetic field, as deformed by the presence of superconducting domains, is calculated in the same way for three different topologies and (2) calculations are made for arbitrary orientation of the applied field. A phase diagram is presented for the minimum-energy topology as a function of applied field magnitude and angle. For small (large) applied fields, normal (superconducting) tubes are found, while for intermediate fields, parallel domains have a lower energy. Themore » range of field magnitudes for which the superconducting-tubes structure is favored shrinks when the field is more in-plane oriented.« less

  5. Fresnel zone plate stacking in the intermediate field for high efficiency focusing in the hard X-ray regime

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Gleber, Sophie -Charlotte; Wojcik, Michael; Liu, Jie; Roehrig, Chris; Cummings, Marvin; Vila-Comamala, Joan; Li, Kenan; Lai, Barry; Shu, Deming; Vogt, Stefan

    2014-11-05

    Focusing efficiency of Fresnel zone plates (FZPs) for X-rays depends on zone height, while the achievable spatial resolution depends on the width of the finest zones. FZPs with optimal efficiency and sub-100-nm spatial resolution require high aspect ratio structures which are difficult to fabricate with current technology especially for the hard X-ray regime. A possible solution is to stack several zone plates. To increase the number of FZPs within one stack, we first demonstrate intermediate-field stacking and apply this method by stacks of up to five FZPs with adjusted diameters. Approaching the respective optimum zone height, we maximized efficiencies formorehigh resolution focusing at three different energies, 10, 11.8, and 25 keV.less

  6. Comparative analysis of compact heat exchangers for application as the intermediate heat exchanger for advanced nuclear reactors

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bartel, N.; Chen, M.; Utgikar, V. P.; Sun, X.; Kim, I. -H.; Christensen, R.; Sabharwall, P.

    2015-04-04

    A comparative evaluation of alternative compact heat exchanger designs for use as the intermediate heat exchanger in advanced nuclear reactor systems is presented in this article. Candidate heat exchangers investigated included the Printed circuit heat exchanger (PCHE) and offset strip-fin heat exchanger (OSFHE). Both these heat exchangers offer high surface area to volume ratio (a measure of compactness [m2/m3]), high thermal effectiveness, and overall low pressure drop. Helium–helium heat exchanger designs for different heat exchanger types were developed for a 600 MW thermal advanced nuclear reactor. The wavy channel PCHE with a 15° pitch angle was found to offer optimummore » combination of heat transfer coefficient, compactness and pressure drop as compared to other alternatives. The principles of the comparative analysis presented here will be useful for heat exchanger evaluations in other applications as well.« less

  7. Acetaldehyde as an intermediate in the electroreduction of carbon monoxide to ethanol on oxide-derived copper

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Bertheussen, Erlend; Verdaguer-Casadevall, Arnau; Ravasio, Davide; Montoya, Joseph H.; Trimarco, Daniel B.; Roy, Claudie; Meier, Sebastian; Wendland, Jürgen; Nørskov, Jens K.; Stephens, Ifan E. L.; et al

    2015-12-21

    Oxide-derived copper (OD-Cu) electrodes exhibit unprecedented CO reduction performance towards liquid fuels, producing ethanol and acetate with >50 % Faradaic efficiency at -0.3 V (vs. RHE). By using static headspace-gas chromatography for liquid phase analysis, we identify acetaldehyde as a minor product and key intermediate in the electroreduction of CO to ethanol on OD-Cu electrodes. Acetaldehyde is produced with a Faradaic efficiency of ≈5 % at -0.33 V (vs. RHE). We show that acetaldehyde forms at low steady-state concentrations, and that free acetaldehyde is difficult to detect in alkaline solutions using NMR spectroscopy, requiring alternative methods for detection and quantification.more » Our results indicate an important step towards understanding the CO reduction mechanism on OD-Cu electrodes.« less

  8. A Study on Optimized Management Options for the Wolsong Low- and Intermediate - Level Waste Disposal Center in Korea - 13479

    SciTech Connect (OSTI)

    Park, JooWan; Kim, DongSun; Choi, DongEun [Korea Radioactive Waste Management Corporation, Korea 89, Bukseongno, Gyeongju, 780-050 (Korea, Republic of)] [Korea Radioactive Waste Management Corporation, Korea 89, Bukseongno, Gyeongju, 780-050 (Korea, Republic of)

    2013-07-01

    The safe and effective management of radioactive waste is a national task required for sustainable generation of nuclear power and for energy self-reliance in Korea. Currently, for permanent disposal of low- and intermediate-level waste (LILW), the Wolsong LILW Disposal Center (WLDC) is under construction. It will accommodate a total of 800,000 drums at the final stage after stepwise expansion. As an implementing strategy for cost-effective development of the WLDC, various disposal options suitable for waste classification schemes would be considered. It is also needed an optimized management of the WLDC by taking a countermeasure of volume reduction treatment. In this study, various management options to be applied to each waste class are analyzed in terms of its inventory and disposal cost. For the volume reduction and stabilization of waste, the vitrification and plasma melting methods are considered for combustible and incombustible waste, respectively. (authors)

  9. Oblique-incidence sputtering of Ru intermediate layer for decoupling of intergranular exchange in perpendicular recording media

    SciTech Connect (OSTI)

    Saito, Shin; Inoue, Ken; Takahashi, Migaku

    2011-04-01

    During the Ru deposition process for granular type perpendicular magnetic recording media, both a reduction in the Ru intermediate layer thickness and lowering of sputtering gas pressure were successfully achieved by focusing on a self-shadowing effect. Oblique-incidence sputtering with a 60 deg. incident angle under an Ar gas pressure of 0.6 Pa yielded (1) columnar Ru grains with a growth direction of 30 deg. from the film normal, (2) c-plane sheet texture by epitaxial growth on the Pt underlayer, and (3) a flat envelope of the surface and a deep gap at grain boundaries. This change in the Ru structure significantly contributes to reducing exchange coupling among magnetic grains, especially in the initial growth region in an overlying granular medium.

  10. Development of a Raman spectroscopy technique to detect alternate transportation fuel hydrocarbon intermediates in complex combustion environments.

    SciTech Connect (OSTI)

    Ekoto, Isaac W.; Barlow, Robert S.

    2012-12-01

    Spontaneous Raman spectra for important hydrocarbon fuels and combustion intermediates were recorded over a range of low-to-moderate flame temperatures using the multiscalar measurement facility located at Sandia/CA. Recorded spectra were extrapolated to higher flame temperatures and then converted into empirical spectral libraries that can readily be incorporated into existing post-processing analysis models that account for crosstalk from overlapping hydrocarbon channel signal. Performance testing of the developed libraries and reduction methods was conducted through an examination of results from well-characterized laminar reference flames, and was found to provide good agreement. The diagnostic development allows for temporally and spatially resolved flame measurements of speciated hydrocarbon concentrations whose parent is more chemically complex than methane. Such data are needed to validate increasingly complex flame simulations.

  11. Relating Pore-Scale Uranium Aquatic Speciation to Intermediate-Scale Aquifer Heterogeneity

    SciTech Connect (OSTI)

    Ranville, James

    2013-04-01

    The speciation and transport of uranium (VI) through porous media is highly dependent on solution conditions, the presence of complexing ligands, and the nature of the porous media. The dependency on many variables makes prediction of U transport in bench-scale experiments and in the field difficult. In particular, the identification of colloidal U phases poses a technical challenge. Transport of U in the presence and absence of natural organic matter (Suwannee River humic acid, SRHA) through silica sand and hematite coated silica sand was tested at pH 4 and 5 using static columns, where flow is controlled by gravity and residence time between advective pore volume exchanges can be strictly controlled. The column effluents were characterized by traditional techniques including ICPMS quantification of total [U] and [Fe], TOC analysis of [DOC], and pH analysis, and also by non-traditional techniques: flow field flow fractionation with online ICPMS detection (FlFFF-ICPMS) and specific UV absorbance (SUVA) characterization of effluent fractions. Key results include that the transport of U through the columns was enhanced by pre-equilibration with SRHA, and previously deposited U was remobilized by the addition of SRHA. The advanced techniques yielded important insights on the mechanisms of transport: FlFFF-ICPMS identified a U?SRHA complex as the mobile U species and directly quantified relative amounts of the complex, while specific UV absorbance (SUVA) measurements indicated a composition-based fractionation onto the porous media.

  12. Measuring Bio-Oil Upgrade Intermediates and Corrosive Species with Polarity-Matched Analytical Approaches

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Connatser, Raynella M; Lewis Sr, Samuel Arthur; Keiser, James R; Choi, Jae-Soon

    2014-01-01

    Integrating biofuels with conventional petroleum products requires improvements in processing to increase blendability with existing fuels. This work demonstrates analysis techniques for more hydrophilic bio-oil liquids that give improved quantitative and qualitative description of the total acid content and organic acid profiles. To protect infrastructure from damage and reduce the cost associated with upgrading, accurate determination of acid content and representative chemical compound analysis are central imperatives to assessing both the corrosivity and the progress toward removing oxygen and acidity in processed biomass liquids. Established techniques form an ample basis for bio-liquids evaluation. However, early in the upgrading process, themore » unique physical phases and varied hydrophilicity of many pyrolysis liquids can render analytical methods originally designed for use in petroleum-derived oils inadequate. In this work, the water solubility of the organic acids present in bio-oils is exploited in a novel extraction and titration technique followed by analysis on the water-based capillary electrophoresis (CE) platform. The modification of ASTM D664, the standard for Total Acid Number (TAN), to include aqueous carrier solvents improves the utility of that approach for quantifying acid content in hydrophilic bio-oils. Termed AMTAN (modified Total Acid Number), this technique offers 1.2% relative standard deviation and dynamic range comparable to the conventional ASTM method. The results of corrosion product evaluations using several different sources of real bio-oil are discussed in the context of the unique AMTAN and CE analytical approaches developed to facilitate those measurements. Keywords: biomass, capillary electrophoresis, Total Acid Number, pyrolysis oil upgrading, carboxylic acid, corrosion« less

  13. Pore-Water Extraction Intermediate-Scale Laboratory Experiments and Numerical Simulations

    SciTech Connect (OSTI)

    Oostrom, Martinus; Freedman, Vicky L.; Wietsma, Thomas W.; Truex, Michael J.

    2011-06-30

    A series of flow cell experiments was conducted to demonstrate the process of water removal through pore-water extraction in unsaturated systems. In this process, a vacuum (negative pressure) is applied at the extraction well establishing gas and water pressure gradients towards the well. The gradient may force water and dissolved contaminants, such as 99Tc, to move towards the well. The tested flow cell configurations consist of packings, with or without fine-grained well pack material, representing, in terms of particle size distribution, subsurface sediments at the SX tank farm. A pore water extraction process should not be considered to be equal to soil vapor extraction because during soil vapor extraction, the main goal may be to maximize gas removal. For pore water extraction systems, pressure gradients in both the gas and water phases need to be considered while for soil vapor extraction purposes, gas phase flow is the only concern. In general, based on the limited set (six) of flow experiments that were conducted, it can be concluded that pore water extraction rates and cumulative outflow are related to water content, the applied vacuum, and the dimensions of the sediment layer providing the extracted water. In particular, it was observed that application of a 100-cm vacuum (negative pressure) in a controlled manner leads to pore-water extraction until the water pressure gradients towards the well approach zero. Increased cumulative outflow was obtained with an increase in initial water content from 0.11 to 0.18, an increase in the applied vacuum to 200 cm, and when the water-supplying sediment was not limited. The experimental matrix was not sufficiently large to come to conclusions regarding maximizing cumulative outflow.

  14. Hydrogen Selective Inorganic membranes for Gas Separations under High Pressure Intermediate Temperature Hydrocarbonic Envrionment

    SciTech Connect (OSTI)

    Rich Ciora; Paul KT Liu

    2012-06-27

    In this project, we have successfully developed a full scale commercially ready carbon molecular sieve (CMS) based membrane for applications in H{sub 2} recovery from refinery waste and other aggressive gas streams. Field tests at a refinery pilot plant and a coal gasification facility have successfully demonstrated its ability to recovery hydrogen from hydrotreating and raw syngas respectively. High purity H{sub 2} and excellent stability of the membrane permeance and selectivity were obtained in testing conducted over >500 hours at each site. The results from these field tests as well as laboratory testing conclude that the membranes can be operated at high pressures (up to 1,000 psig) and temperatures (up to 300 C) in presence of aggressive contaminants, such as sulfur and nitrogen containing species (H{sub 2}S, CO{sub 2}, NH{sub 3}, etc), condensable hydrocarbons, tar-like species, heavy metals, etc. with no observable effect on membrane performance. By comparison, similar operating conditions and/or environments would rapidly destroy competing membranes, such as polymeric, palladium, zeolitic, etc. Significant cost savings can be achieved through recovering H{sub 2} from refinery waste gas using this newly developed CMS membrane. Annual savings of $2 to 4MM/year (per 20,000 scfd of waste gas) can be realized by recovering the H{sub 2} for reuse (versus fuel). Projecting these values over the entire US market, potential H{sub 2} savings from refinery waste gases on the order of 750 to 1,000MM scfd and $750 to $1,000MM per year are possible. In addition to the cost savings, potential energy savings are projected to be ca. 150 to 220 tBTU/yr and CO{sub 2} gas emission reductions are projected to be ca. 5,000 to 6,500MMtons/year. The full scale membrane bundle developed as part of this project, i.e., 85 x 30 inch ceramic membrane tubes packaged into a full ceramic potting, is an important accomplishment. No comparable commercial scale product exists in the inorganic membrane field. Further, this newly developed full scale bundle concept can be extended to other thin film inorganic membrane technology (Pd, zeolite, etc), providing a potential commercialization pathway for these membrane materials that demonstrate high potential in a variety of separation applications yet remain a laboratory 'novelty' for lack of a full scale support. Overall, the project has been highly successful and all of the project objectives have been met. We have developed the first of its kind commercial scale carbon molecular sieve membrane and demonstrated its performance in field testing under aggressive operating conditions and in the presence of chemical contaminants that would rapidly destroy alternative organic and inorganic membranes. This innovative membrane permits H{sub 2} recovery from gas streams that up until now have not been successfully treated with membrane or conventional technology. Our end user participant is currently pursuing the field demonstration of this membrane for hydrogen recovery at its refinery site.

  15. InAs quantum dot growth on Al{sub x}Ga{sub 1?x}As by metalorganic vapor phase epitaxy for intermediate band solar cells

    SciTech Connect (OSTI)

    Jakomin, R.; Kawabata, R. M. S.; Souza, P. L.; Mouro, R. T.; Pires, M. P.; Micha, D. N.

    2014-09-07

    InAs quantum dot multilayers have been grown using Al{sub x}Ga{sub 1?x}As spacers with dimensions and compositions near the theoretical values for optimized efficiencies in intermediate band photovoltaic cells. Using an aluminium composition of x?=?0.3 and InAs dot vertical dimensions of 5?nm, transitions to an intermediate band with energy close to the ideal theoretical value have been obtained. Optimum size uniformity and density have been achieved by capping the quantum dots with GaAs following the indium-flush method. This approach has also resulted in minimization of crystalline defects in the epilayer structure.

  16. Accelerated Stress Testing of Hydrocarbon-Based Encapsulants for Medium-Concentration CPV Applications

    SciTech Connect (OSTI)

    Kempe, M. D.; Moricone, T. J.; Kilkenny, M.; Zhang, J. Z.

    2011-02-01

    Concentrating photovoltaic (CPV) systems have great potential to reduce photovoltaic (PV) electricity costs because of the relatively low cost of optical components as compared to PV cells. A transparent polymeric material is used to optically couple the PV cell to optical components and is thus exposed to the concentrated light source at elevated temperatures. In this work polymeric encapsulant materials are positioned close to a Xenon arc lamp to expose them to ultraviolet radiation (UV) that is about 42 times as intense as sunlight. Furthermore, different glass types are used as filters to modify the spectral distribution of light in the UV range. A strong sensitivity of non-silicone-based encapsulants to light below ~350 nm is demonstrated. Of all the materials examined in this study, the polydimethyl silicone samples performed the best. The next best material was an ionomer which maintained optical transmission but became photo-oxidized where exposed to the atmosphere.

  17. Extended main sequence turnoffs in intermediate-age star clusters: a correlation between turnoff width and early escape velocity

    SciTech Connect (OSTI)

    Goudfrooij, Paul; Kozhurina-Platais, Vera; Kalirai, Jason S.; Correnti, Matteo E-mail: verap@stsci.edu E-mail: correnti@stsci.edu; and others

    2014-12-10

    We present a color-magnitude diagram analysis of deep Hubble Space Telescope imaging of a mass-limited sample of 18 intermediate-age (1-2 Gyr old) star clusters in the Magellanic Clouds, including eight clusters for which new data were obtained. We find that all star clusters in our sample feature extended main-sequence turnoff (eMSTO) regions that are wider than can be accounted for by a simple stellar population (including unresolved binary stars). FWHM widths of the MSTOs indicate age spreads of 200-550 Myr. We evaluate the dynamical evolution of clusters with and without initial mass segregation. Our main results are (1) the fraction of red clump (RC) stars in secondary RCs in eMSTO clusters scales with the fraction of MSTO stars having pseudo-ages of ?1.35 Gyr; (2) the width of the pseudo-age distributions of eMSTO clusters is correlated with their central escape velocity v {sub esc}, both currently and at an age of 10 Myr. We find that these two results are unlikely to be reproduced by the effects of interactive binary stars or a range of stellar rotation velocities. We therefore argue that the eMSTO phenomenon is mainly caused by extended star formation within the clusters; and (3) we find that v {sub esc} ? 15 km s{sup 1} out to ages of at least 100 Myr for all clusters featuring eMSTOs, and v {sub esc} ? 12 km s{sup 1} at all ages for two lower-mass clusters in the same age range that do not show eMSTOs. We argue that eMSTOs only occur for clusters whose early escape velocities are higher than the wind velocities of stars that provide material from which second-generation stars can form. The threshold of 12-15 km s{sup 1} is consistent with wind velocities of intermediate-mass asymptotic giant branch stars and massive binary stars in the literature.

  18. V&V of MCNP 6.1.1 Beta Against Intermediate and High-Energy Experimental Data

    SciTech Connect (OSTI)

    Mashnik, Stepan G

    2014-09-08

    This report presents a set of validation and verification (V&V) MCNP 6.1.1 beta results calculated in parallel, with MPI, obtained using its event generators at intermediate and high-energies compared against various experimental data. It also contains several examples of results using the models at energies below 150 MeV, down to 10 MeV, where data libraries are normally used. This report can be considered as the forth part of a set of MCNP6 Testing Primers, after its first, LA-UR-11-05129, and second, LA-UR-11-05627, and third, LA-UR-26944, publications, but is devoted to V&V with the latest, 1.1 beta version of MCNP6. The MCNP6 test-problems discussed here are presented in the /VALIDATION_CEM/and/VALIDATION_LAQGSM/subdirectories in the MCNP6/Testing/directory. README files that contain short descriptions of every input file, the experiment, the quantity of interest that the experiment measures and its description in the MCNP6 output files, and the publication reference of that experiment are presented for every test problem. Templates for plotting the corresponding results with xmgrace as well as pdf files with figures representing the final results of our V&V efforts are presented. Several technical bugs in MCNP 6.1.1 beta were discovered during our current V&V of MCNP6 while running it in parallel with MPI using its event generators. These bugs are to be fixed in the following version of MCNP6. Our results show that MCNP 6.1.1 beta using its CEM03.03, LAQGSM03.03, Bertini, and INCL+ABLA, event generators describes, as a rule, reasonably well different intermediate- and high-energy measured data. This primer isnt meant to be read from cover to cover. Readers may skip some sections and go directly to any test problem in which they are interested.

  19. Intermediate photovoltaic system application experiment operational performance report. Volume 4. For G. N. Wilcox Memorial Hospital, Kauai, Hawaii for June, July, and August 1982

    SciTech Connect (OSTI)

    Not Available

    1982-12-01

    Presented are the data accumulated during June, July, and August 1982 at the intermediate photovoltaic project at G.N. Wilcox Memorial Hospital, Kauai, Hawaii. Generated energy and environmental (weather) data are presented graphically. Explanations of irregularities not attributable to weater are provided.

  20. Biological Production of a Hydrocarbon Fuel Intermediate Polyhydroxybutyrate (PHB) from a Process Relevant Lignocellulosic Derived Sugar (Poster)

    SciTech Connect (OSTI)

    Wang, W.; Mittal, A.; Mohagheghi, A.; Johnson, D. K.

    2014-04-01

    PHAs are synthesized by many microorganisms to serve as intracellular carbon storage molecules. In some bacterial strains, PHB can account for up to 80% of cell mass. In addition to its application in the packaging sector, PHB also has great potential as an intermediate in the production of hydrocarbon fuels. PHB can be thermally depolymerized and decarboxylated to propene which can be upgraded to hydrocarbon fuels via commercial oligomerization technologies. Cupriavidus necator is the microorganism that has been most extensively studied and used for PHB production on an industrial scale; However the substrates used for producing PHB are mainly fructose, glucose, sucrose, fatty acids, glycerol, etc., which are expensive. In this study, we demonstrate production of PHB from a process relevant lignocellulosic derived sugar stream, i.e., saccharified slurry from pretreated corn stover. The strain was first investigated in shake flasks for its ability to utilize glucose, xylose and acetate. In addition, the strain was also grown on pretreated lignocellulose hydrolyzate slurry and evaluated in terms of cell growth, sugar utilization, PHB accumulation, etc. The mechanism of inhibition in the toxic hydrolysate generated by the pretreatment and saccharification process of biomass, was also studied.

  1. Structure and reactivity of chemisorbed species and reaction intermediates: Progress report, December 1, 1985-November 30, 1986

    SciTech Connect (OSTI)

    Madey, T.E.

    1986-07-01

    The areas of work supported under this contract by DOE during the period 12/1/85-11/30/86 have a common theme: the structure and reactivity of chemisorbed species and reaction intermediates of importance to catalysis. A variety of tools have been used to study the structure and chemistry of surface species, and to develop models and concepts of broad utility in chemisorption and catalysis. Fourteen papers have appeared, are in press, or in preparation in FY86. Results of the research conducted or completed in the last year are summarized in this report. The results are presented in three sections: surface molecular structure and reactivity as studied using electron stimulated desoprtion ion angular distribution (ESDIAD) and high resolution electron energy loss spectroscopy (HREELS); neutron inelastic scattering studies of adsorption and reaction on metal catalysts and zeolite catalysts; reaction kinetics at high pressures over single crystal metal catalysts: mechanisms of catalyst poisoning. A listing of publications during the past year is included.

  2. IS THERE AN INTERMEDIATE MASSIVE BLACK HOLE IN THE GALACTIC CENTER: IMPRINTS ON THE STELLAR TIDAL-DISRUPTION RATE

    SciTech Connect (OSTI)

    Chen, Xian; Liu, F. K. E-mail: fkliu@pku.edu.cn

    2013-01-10

    It has been suggested that an intermediate-massive black hole (IMBH) with mass 10{sup 3-5} M {sub Sun} could fall into the galactic center (GC) and form a massive black hole binary (MBHB) with the central supermassive black hole, but current observations are not sensitive to constrain all mass and distance ranges. Motivated by the recent discovery that MBHBs could enhance the rate of tidal-disruption events (TDEs) of stellar objects, we investigate the prospect of using stellar-disruption rate to probe IMBHs in the GC. We incorporated the perturbation by an IMBH into the loss-cone theory and calculated the stellar-disruption rates in the GC. We found that an IMBH heavier than 2000 M {sub Sun} could distinguishably enhance the stellar-disruption rate. By comparing observations of Sgr A* with the fall-back model for stellar debris, we suggested that the TDE rate in our Galaxy should not significantly exceed 0.002 yr{sup -1}, therefore a fraction of the parameter space for the IMBH, concentrating at the high-mass end, can already be excluded. To derive constraint in the remaining parameter space, it is crucial to observationally confirm or reject the stellar-disruption rate between 10{sup -4} and 10{sup -2} yr{sup -1}, and we discussed possible strategies to make such measurements.

  3. TIDAL DISRUPTIONS OF WHITE DWARFS FROM ULTRA-CLOSE ENCOUNTERS WITH INTERMEDIATE-MASS SPINNING BLACK HOLES

    SciTech Connect (OSTI)

    Haas, Roland; Bode, Tanja; Laguna, Pablo; Shcherbakov, Roman V.

    2012-04-20

    We present numerical relativity results of tidal disruptions of white dwarfs from ultra-close encounters with a spinning, intermediate-mass black hole (IMBH). These encounters require a full general relativistic treatment of gravity. We show that the disruption process and prompt accretion of the debris strongly depend on the magnitude and orientation of the black hole (BH) spin. However, the late-time accretion onto the BH follows the same decay, M-dot {proportional_to} t{sup -5/3}, estimated from Newtonian gravity disruption studies. We compute the spectrum of the disk formed from the fallback material using a slim disk model. The disk spectrum peaks in the soft X-rays and sustains Eddington luminosity for 1-3 yr after the disruption. For arbitrary BH spin orientations, the disrupted material is scattered away from the orbital plane by relativistic frame dragging, which often leads to obscuration of the inner fallback disk by the outflowing debris. The disruption events also yield bursts of gravitational radiation with characteristic frequencies of {approx}3.2 Hz and strain amplitudes of {approx}10{sup -18} for galactic IMBHs. The optimistic rate of considered ultra-close disruptions is consistent with no sources found in the ROSAT all-sky survey. Future missions like Wide-Field X-ray Telescope could observe dozens of events.

  4. Shockley-Read-Hall recombination in pre-filled and photo-filled intermediate band solar cells

    SciTech Connect (OSTI)

    Mayani, Maryam Gholami; Reenaas, Turid Worren

    2014-08-18

    In this work, we study how Shockley-Read-Hall (SRH) recombination via energy levels in the bandgap, caused by defects or impurities, affects the performance of both photo-filled and pre-filled intermediate band solar cells (IBSCs). For a pre-filled cell, the IB is half-filled in equilibrium, while it is empty for the photo-filled cell in equilibrium. The energy level, density, and capture cross-sections of the defects/impurities are varied systematically. We find that the photo-filled cells are, in general, less efficient than pre-filled cells, except when the defect level is between the conduction band and the IB. In that case, for a range of light intensities, the photo-filled cell performs better than the pre-filled. When the defect level is at the same energy as the IB, the efficiency is above 82% of the defect-free case, when less than 50% of the states at the IB lead to SRH recombination. This shows that even if SRH recombination via the IB takes place, high efficiencies can be achieved. We also show that band gap optimization can be used to reduce the SRH recombination.

  5. TRAC-PF1/MOD1 independent assessment: Semiscale Mod-2A intermediate break test S-IB-3

    SciTech Connect (OSTI)

    Kmetyk, L N

    1986-02-01

    The TRAC-PF1/MOD1 independent assessment project at Sandia National Laboratories is part of an overall effort funded by the NRC to determine the ability of various system codes to predict the detailed thermal/hydraulic response of light water reactors during accident and off-normal conditions. The TRAC code is being assessed at SNLA against test data from various integral and separate effects test facilities. As part of this assessment matrix, an intermediate break test (S-IB-3), performed at the Semiscale Mod-2A facility, has been analyzed. Using an input model with a 3-D VESSEL component, the vessel and downcomer inventories during 3-IB-3 were generally well predicted, but the core heatup was underpredicted compared to data. An equivalent calculation with an all 1-D input model ran about twice as fast as our basecase analysis using a 3-D VESSEL in the input model, but the results of the two calculations diverged significantly for many parameters of interest, with the 3-D VESSEL model results in better agreement with data. 22 refs., 100 figs.

  6. Medicine Lodge Intermediate Facility

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Medicine Lodge

  7. Meeker Intermediate Facility

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

  8. Engineering Analysis of Intermediate Loop and Process Heat Exchanger Requirements to Include Configuration Analysis and Materials Needs

    SciTech Connect (OSTI)

    T.M. Lillo; R.L. Williamson; T.R. Reed; C.B. Davis; D.M. Ginosar

    2005-09-01

    The need to locate advanced hydrogen production facilities a finite distance away from a nuclear power source necessitates the need for an intermediate heat transport loop (IHTL). This IHTL must not only efficiently transport energy over distances up to 500 meters but must also be capable of operating at high temperatures (>850oC) for many years. High temperature, long term operation raises concerns of material strength, creep resistance and general material stability (corrosion resistance). IHTL design is currently in the initial stages. Many questions remain to be answered before intelligent design can begin. The report begins to look at some of the issues surrounding the main components of an IHTL. Specifically, a stress analysis of a compact heat exchanger design under expected operating conditions is reported. Also the results of a thermal analysis performed on two ITHL pipe configurations for different heat transport fluids are presented. The configurations consist of separate hot supply and cold return legs as well as annular design in which the hot fluid is carried in an inner pipe and the cold return fluids travels in the opposite direction in the annular space around the hot pipe. The effects of insulation configurations on pipe configuration performance are also reported. Finally, a simple analysis of two different process heat exchanger designs, one a tube in shell type and the other a compact or microchannel reactor are evaluated in light of catalyst requirements. Important insights into the critical areas of research and development are gained from these analyses, guiding the direction of future areas of research.

  9. Early-type galaxies at intermediate redshift observed with Hubble space telescope WFC3: perspectives on recent star formation

    SciTech Connect (OSTI)

    Rutkowski, Michael J.; Jeong, Hyunjin; Yi, Sukyoung K.; Cohen, Seth H.; Windhorst, Rogier A.; Kaviraj, Sugata; Ryan, Russell E. Jr.; Koekemoer, Anton; Hathi, Nimish P.; Dopita, Michael A.

    2014-12-01

    We present an analysis of the stellar populations of 102 visually selected early-type galaxies (ETGs) with spectroscopic redshifts (0.35 ? z ? 1.5) from observations in the Early Release Science program with the Wide Field Camera 3 (WFC3) on the Hubble Space Telescope (HST). We fit one- and two-component synthetic stellar models to the ETGs UV-optical-near-IR spectral energy distributions and find that a large fraction (?40%) are likely to have experienced a minor (f{sub YC} ? 10% of stellar mass) burst of recent (t{sub YC} ? 1 Gyr) star formation. The measured age and mass fraction of the young stellar populations do not strongly trend with measurements of galaxy morphology. We note that massive (M > 10{sup 10.5} M {sub ?}) recent star-forming ETGs appear to have larger sizes. Furthermore, high-mass, quiescent ETGs identified with likely companions populate a distinct region in the size-mass parameter space, in comparison with the distribution of massive ETGs with evidence of recent star formation (RSF). We conclude that both mechanisms of quenching star formation in disk-like ETGs and (gas-rich, minor) merger activity contribute to the formation of young stars and the size-mass evolution of intermediate redshift ETGs. The number of ETGs for which we have both HST WFC3 panchromatic (especially UV) imaging and spectroscopically confirmed redshifts is relatively small, therefore, a conclusion about the relative roles of both of these mechanisms remains an open question.

  10. On the physical processes ruling an atmospheric pressure air glow discharge operating in an intermediate current regime

    SciTech Connect (OSTI)

    Prevosto, L. Mancinelli, B.; Chamorro, J. C.; Cejas, E.; Kelly, H.

    2015-02-15

    Low-frequency (100?Hz), intermediate-current (50 to 200?mA) glow discharges were experimentally investigated in atmospheric pressure air between blunt copper electrodes. Voltagecurrent characteristics and images of the discharge for different inter-electrode distances are reported. A cathode-fall voltage close to 360?V and a current density at the cathode surface of about 11?A/cm{sup 2}, both independent of the discharge current, were found. The visible emissive structure of the discharge resembles to that of a typical low-pressure glow, thus suggesting a glow-like electric field distribution in the discharge. A kinetic model for the discharge ionization processes is also presented with the aim of identifying the main physical processes ruling the discharge behavior. The numerical results indicate the presence of a non-equilibrium plasma with rather high gas temperature (above 4000?K) leading to the production of components such as NO, O, and N which are usually absent in low-current glows. Hence, the ionization by electron-impact is replaced by associative ionization, which is independent of the reduced electric field. This leads to a negative current-voltage characteristic curve, in spite of the glow-like features of the discharge. On the other hand, several estimations show that the discharge seems to be stabilized by heat conduction; being thermally stable due to its reduced size. All the quoted results indicate that although this discharge regime might be considered to be close to an arc, it is still a glow discharge as demonstrated by its overall properties, supported also by the presence of thermal non-equilibrium.

  11. Structure of Naegleria Tet-like dioxygenase (NgTet1) in complexes with a reaction intermediate 5-hydroxymethylcytosine DNA

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Hashimoto, Hideharu; Pais, June E.; Dai, Nan; Corrêa, Jr., Ivan R.; Zhang, Xing; Zheng, Yu; Cheng, Xiaodong

    2015-08-31

    The family of ten-eleven translocation (Tet) dioxygenases is widely distributed across the eukaryotic tree of life, from mammals to the amoeboflagellate Naegleria gruberi. Like mammalian Tet proteins, the Naegleria Tet-like protein, NgTet1, acts on 5-methylcytosine (5mC) and generates 5-hydroxymethylcytosine (5hmC), 5-formylcytosine (5fC) and 5-carboxylcytosine (5caC) in three consecutive, Fe(II)- and α-ketoglutarate-dependent oxidation reactions. The two intermediates, 5hmC and 5fC, could be considered either as the reaction product of the previous enzymatic cycle or the substrate for the next cycle. Here we present a new crystal structure of NgTet1 in complex with DNA containing a 5hmC. Along with the previously solvedmore » NgTet1–5mC structure, the two complexes offer a detailed picture of the active site at individual stages of the reaction cycle. In the crystal, the hydroxymethyl (OH-CH2-) moiety of 5hmC points to the metal center, representing the reaction product of 5mC hydroxylation. The hydroxyl oxygen atom could be rotated away from the metal center, to a hydrophobic pocket formed by Ala212, Val293 and Phe295. Such rotation turns the hydroxyl oxygen atom away from the product conformation, and exposes the target CH2 towards the metal-ligand water molecule, where a dioxygen O2 molecule would occupy to initiate the next round of reaction by abstracting a hydrogen atom from the substrate. The Ala212-to-Val (A212V) mutant profoundly limits the product to 5hmC, probably due to the reduced hydrophobic pocket size restricts the binding of 5hmC as a substrate.« less

  12. HUD (Housing and Urban Development) Intermediate Minimum Property Standards Supplement 4930. 2 (1989 edition). Solar heating and domestic hot water systems

    SciTech Connect (OSTI)

    Not Available

    1989-12-01

    The Minimum Property Standards for Housing 4910.1 were developed to provide a sound technical basis for housing under numerous programs of the Department of Housing and Urban Development (HUD). These Intermediate Minimum Property Standards for Solar Heating and Domestic Hot Water Systems are intended to provide a companion technical basis for the planning and design of solar heating and domestic hot water systems. These standards have been prepared as a supplement to the Minimum Property Standards (MPS) and deal only with aspects of planning and design that are different from conventional housing by reason of the solar systems under consideration. The document contains requirements and standards applicable to one- and two-family dwellings, multifamily housing, and nursing homes and intermediate care facilities references made in the text to the MPS refer to the same section in the Minimum Property Standards for Housing 4910.1.

  13. Highly stable and efficient tandem organic light-emitting devices with intermediate connectors using lithium amide as n-type dopant

    SciTech Connect (OSTI)

    Zhou, Dong-Ying; Zu, Feng-Shuo; Shi, Xiao-Bo; Liao, Liang-Sheng E-mail: lsliao@suda.edu.cn; Zhang, Ying-Jie; Aziz, Hany E-mail: lsliao@suda.edu.cn

    2014-08-25

    In this work, we report thermally decomposable lithium amide (LiNH{sub 2}) feasible to function as an effective n-type dopant for intermediate connectors in tandem organic light-emitting devices (OLEDs). Metallic lithium, which is released from the decomposition process of LiNH{sub 2}, is proved by X-ray photoelectron spectroscopy and responsible for n-type electrical doping of electron transporting materials. We demonstrate that tandem OLEDs using LiNH{sub 2} and Cs{sub 2}CO{sub 3} as n-type dopants, respectively, give a comparable electroluminescence efficiency and, moreover, the device with LiNH{sub 2} has far longer operational lifetime. The results therefore highlight the significance of selecting suitable n-type dopant in intermediate connectors to fabricate high-stability tandem OLEDs.

  14. Self-corrected Sensors Based On Atomic Absorption Spectroscopy For Atom Flux Measurements In Molecular Beam Epitaxy

    SciTech Connect (OSTI)

    Du, Yingge; Droubay, Timothy C.; Liyu, Andrey V.; Li, Guosheng; Chambers, Scott A.

    2014-04-24

    A high sensitivity atom flux sensor based on atomic absorption spectroscopy has been designed and implemented to control electron beam evaporators and effusion cells in a molecular beam epitaxy system. Using a high-resolution spectrometer and a two-dimensional charge coupled device (CCD) detector in a double-beam configuration, we employ a non-resonant line or a resonant line with lower absorbance from the same hollow cathode lamp as the reference for nearly perfect background correction and baseline drift removal. This setup also significantly shortens the warm-up time needed compared to other sensor technologies and drastically reduces the noise coming from the surrounding environment. In addition, the high-resolution spectrometer allows the most sensitive resonant line to be isolated and used to provide excellent signal-to-noise ratio.

  15. Self-corrected sensors based on atomic absorption spectroscopy for atom flux measurements in molecular beam epitaxy

    SciTech Connect (OSTI)

    Du, Y. E-mail: scott.chambers@pnnl.gov; Liyu, A. V.; Droubay, T. C.; Chambers, S. A. E-mail: scott.chambers@pnnl.gov; Li, G.

    2014-04-21

    A high sensitivity atom flux sensor based on atomic absorption spectroscopy has been designed and implemented to control electron beam evaporators and effusion cells in a molecular beam epitaxy system. Using a high-resolution spectrometer and a two-dimensional charge coupled device detector in a double-beam configuration, we employ either a non-resonant line or a resonant line with low cross section from the same hollow cathode lamp as the reference for nearly perfect background correction and baseline drift removal. This setup also significantly shortens the warm-up time needed compared to other sensor technologies and drastically reduces the noise coming from the surrounding environment. In addition, the high-resolution spectrometer allows the most sensitive resonant line to be isolated and used to provide excellent signal-to-noise ratio.

  16. Self-reported Impacts of LED Lighting Technology Compared to Fuel-based Lighting on Night Market Business Prosperity in Kenya

    SciTech Connect (OSTI)

    Johnstone, Peter; Jacobson, Arne; Mills, Evan; Mumbi, Maina

    2009-02-11

    The notion of"productive use" is often invoked in discussions about whether new technologies improve productivity or otherwise enhance commerce in developing-country contexts. It an elusive concept,especially when quantitative measures are sought. Improved and more energy efficient illumination systems for off-gridapplication--the focus of the Lumina Project--provide a case in which a significant productivity benefit can be imagined, given the importance of light to the successful performance of many tasks, and the very low quality of baseline illumination provided by flame-based source. This Research Note summarizes self-reported quantitative and qualitative impacts of switching to LED lighting technology on the prosperity of night-market business owners and operators. The information was gathered in the context of our 2008 market testing field work in Kenya?s Rift Valley Province, which was performed in the towns of Maai Mahiu and Karagita by Arne Jacobson, Kristen Radecsky, Peter Johnstone, Maina Mumbi, and others. Maai Mahiu is a crossroads town; provision of services to travelers and freight carriers is a primary income source for the residents. In contrast, the primary income for Karagita's residents is from work in the large, factory style flower farms on the eastern shores of Lake Naivasha that specialize in producing cut flowers for export to the European market. According to residents, both towns had populations of 6,000 to 8,000 people in June 2008. We focused on quantifying the economics of fuel-based and LED lighting technology in the context of business use by night market vendors and shop keepers. Our research activities with the business owners and operators included baseline measurement of their fuel-based lighting use, an initial survey, offering for sale data logger equipped rechargeable LED lamps, monitoring the adoption of the LED lamps, and a follow-up survey.

  17. Housing standards: change to HUD 4930. 2 Intermediate Minimum Property Standard (IMPS) supplement for solar heating and domestic hot water systems

    SciTech Connect (OSTI)

    Not Available

    1982-08-17

    This rule is made to provide an updating, clarification, and improvement of requirements contained in HUD Handbook 4930.2, Intermediate Minimum Property Standards (IMPS) Supplement concerning solar heating and domestic hot water systems. Changes pertain to fire protection, penetration, roof covering, conditions of use, thermal stability, rain resistance, ultraviolet stability, and compatibility with transfer medium. Additional changes cover applicable standards, labeling, flash point, chemical and physical commpatibility, flame spread classification, lightening protection, and parts of a solar energy system. Altogether, there are over 50 changes, some of which apply to tables and worksheets. Footnotes are included.

  18. Integrity assessment of the ferritic / austenitic dissimilar weld joint between intermediate heat exchanger and steam generator in fast reactor

    SciTech Connect (OSTI)

    Jayakumar, T.; Laha, K.; Chandravathi, K. S.; Parameswaran, P.; Goyal, S.; Kumar, J. G.; Mathew, M. D.

    2012-07-01

    Integrity of the modified 9Cr-1Mo / alloy 800 dissimilar joint welded with Inconel 182 electrodes has been assessed under creep condition based on the detailed analysis of microstructure and stress distribution across the joint by finite element analysis. A hardness peak at the ferritic / austenitic weld interface and a hardness trough at the inter-critical heat affected zone (HAZ) in ferritic base metal developed. Un-tempered martensite was found at the ferritic / austenitic weld interface to impart high hardness in it; whereas annealing of martensitic structure of modified 9Cr-1Mo steel by inter-critical heating during welding thermal cycle resulted in hardness tough in the inter-critical HAZ. Creep tests were carried out on the joint and ferritic steel base metal at 823 K over a stress range of 160-320 MPa. The joint possessed lower creep rupture strength than its ferritic steel base metal. Failure of the joint at relatively lower stresses occurred at the ferritic / austenitic weld interface; whereas it occurred at inter-critical region of HAZ at moderate stresses. Cavity nucleation associated with the weld interface particles led to premature failure of the joint. Finite element analysis of stress distribution across the weld joint considering the micro-mechanical strength inhomogeneity across it revealed higher von-Mises and principal stresses at the weld interface. These stresses induced preferential creep cavitation at the weld interface. Role of precipitate in enhancing creep cavitation at the weld interface has been elucidated based on the FE analysis of stress distribution across it. (authors)

  19. EPICS BASE

    Energy Science and Technology Software Center (OSTI)

    002230MLTPL00 Experimental Physics and Industrial Control System BASE http://www.aps.anl.gov/epics

  20. Microsoft Word - EXC-12-0001thru03.doc

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    certain types of GSFLs based upon minimum average lumens-per- watt (lmW) efficacy and color rendering index (CRI) levels, as follows: Lamp type Nominal lamp wattage Minimum CRI...

  1. Process Design and Economics for the Conversion of Lignocellulosic Biomass to High Octane Gasoline: Thermochemical Research Pathway with Indirect Gasification and Methanol Intermediate

    SciTech Connect (OSTI)

    Tan, Eric; Talmadge, M.; Dutta, Abhijit; Hensley, Jesse; Schaidle, Josh; Biddy, Mary J.; Humbird, David; Snowden-Swan, Lesley J.; Ross, Jeff; Sexton, Danielle; Yap, Raymond; Lukas, John

    2015-03-01

    The U.S. Department of Energy (DOE) promotes research for enabling cost-competitive liquid fuels production from lignocellulosic biomass feedstocks. The research is geared to advance the state of technology (SOT) of biomass feedstock supply and logistics, conversion, and overall system sustainability. As part of their involvement in this program, the National Renewable Energy Laboratory (NREL) and the Pacific Northwest National Laboratory (PNNL) investigate the economics of conversion pathways through the development of conceptual biorefinery process models. This report describes in detail one potential conversion process for the production of high octane gasoline blendstock via indirect liquefaction (IDL). The steps involve the conversion of biomass to syngas via indirect gasification followed by gas cleanup and catalytic syngas conversion to a methanol intermediate; methanol is then further catalytically converted to high octane hydrocarbons. The conversion process model leverages technologies previously advanced by research funded by the Bioenergy Technologies Office (BETO) and demonstrated in 2012 with the production of mixed alcohols from biomass. Biomass-derived syngas cleanup via tar and hydrocarbons reforming was one of the key technology advancements as part of that research. The process described in this report evaluates a new technology area with downstream utilization of clean biomass-syngas for the production of high octane hydrocarbon products through a methanol intermediate, i.e., dehydration of methanol to dimethyl ether (DME) which subsequently undergoes homologation to high octane hydrocarbon products.

  2. Nucleon-induced reactions at intermediate energies: New data at 96 MeV and theoretical status

    SciTech Connect (OSTI)

    Blideanu, V.; Lecolley, F.R.; Lecolley, J.F.; Lefort, T.; Marie, N.; Ban, G.; Louvel, M.; Dangtip, S.; Tippawan, U.; Elmgren, K.; Eudes, Ph.; Guertin, A.

    2004-07-01

    Double-differential cross sections for light charged particle production (up to A=4) were measured in 96 MeV neutron-induced reactions, at the TSL Laboratory Cyclotron in Uppsala (Sweden). Measurements for three targets, Fe, Pb, and U, were performed using two independent devices, SCANDAL and MEDLEY. The data were recorded with low-energy thresholds and for a wide angular range (20 deg. -160 deg. ). The normalization procedure used to extract the cross sections is based on the np elastic scattering reaction that we measured and for which we present experimental results. A good control of the systematic uncertainties affecting the results is achieved. Calculations using the exciton model are reported. Two different theoretical approaches proposed to improve its predictive power regarding the complex particle emission are tested. The capabilities of each approach is illustrated by comparison with the 96 MeV data that we measured, and with other experimental results available in the literature.

  3. Ambient synthesis, characterization, and electrochemical activity of LiFePO? nanomaterials derived from iron phosphate intermediates

    SciTech Connect (OSTI)

    Patete, Jonathan M.; Wong, Stanislaus S.; Scofield, Megan E.; Volkov, Vyacheslav; Koenigsmann, Christopher; Zhang, Yiman; Marschilok, Amy C.; Wang, Xiaoya; Bai, Jianming; Han, Jinkyu; Wang, Lei; Wang, Feng; Zhu, Yimei; Graetz, Jason A.

    2015-05-30

    LiFePO? materials have become increasingly popular as a cathode material due to the many benefits they possess including thermal stability, durability, low cost, and long life span. Nevertheless, to broaden the general appeal of this material for practical electrochemical applications, it would be useful to develop a relatively mild, reasonably simple synthesis method of this cathode material. Herein, we describe a generalizable, 2-step methodology of sustainably synthesizing LiFePO? by incorporating a template-based, ambient, surfactantless, seedless, U-tube protocol in order to generate size and morphologically tailored, crystalline, phase-pure nanowires. The purity, composition, crystallinity, and intrinsic quality of these wires were systematically assessed using transmission electron microscopy TEM, HRTEM, SEM, XRD, SAED, EDAX and high-resolution synchrotron XRD. From these techniques, we were able to determine that there is an absence of defects present in our wires, supporting the viability of our synthetic approach. Electrochemical analysis was also employed to assess their electrochemical activity. Although our nanowires do not contain any noticeable impurities, we attribute their less than optimal electrochemical rigor to differences in the chemical bonding between our LiFePO? nanowires and their bulk-like counterparts. Specifically, we demonstrate for the first time experimentally that the Fe-O3 chemical bond plays an important role in determining the overall conductivity of the material, an assertion which is further supported by recent first principles calculations. Nonetheless, our ambient, solution-based synthesis technique is capable of generating highly crystalline and phase-pure energy-storage-relevant nanowires that can be tailored so as to fabricate different sized materials of reproducible, reliable morphology.

  4. Ambient synthesis, characterization, and electrochemical activity of LiFePO₄ nanomaterials derived from iron phosphate intermediates

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Patete, Jonathan M.; Wong, Stanislaus S.; Scofield, Megan E.; Volkov, Vyacheslav; Koenigsmann, Christopher; Zhang, Yiman; Marschilok, Amy C.; Wang, Xiaoya; Bai, Jianming; Han, Jinkyu; et al

    2015-05-30

    LiFePO₄ materials have become increasingly popular as a cathode material due to the many benefits they possess including thermal stability, durability, low cost, and long life span. Nevertheless, to broaden the general appeal of this material for practical electrochemical applications, it would be useful to develop a relatively mild, reasonably simple synthesis method of this cathode material. Herein, we describe a generalizable, 2-step methodology of sustainably synthesizing LiFePO₄ by incorporating a template-based, ambient, surfactantless, seedless, U-tube protocol in order to generate size and morphologically tailored, crystalline, phase-pure nanowires. The purity, composition, crystallinity, and intrinsic quality of these wires were systematicallymore » assessed using transmission electron microscopy TEM, HRTEM, SEM, XRD, SAED, EDAX and high-resolution synchrotron XRD. From these techniques, we were able to determine that there is an absence of defects present in our wires, supporting the viability of our synthetic approach. Electrochemical analysis was also employed to assess their electrochemical activity. Although our nanowires do not contain any noticeable impurities, we attribute their less than optimal electrochemical rigor to differences in the chemical bonding between our LiFePO₄ nanowires and their bulk-like counterparts. Specifically, we demonstrate for the first time experimentally that the Fe-O3 chemical bond plays an important role in determining the overall conductivity of the material, an assertion which is further supported by recent first principles calculations. Nonetheless, our ambient, solution-based synthesis technique is capable of generating highly crystalline and phase-pure energy-storage-relevant nanowires that can be tailored so as to fabricate different sized materials of reproducible, reliable morphology.« less

  5. Understanding the role of histidine in the GHSxG acyltransferase active site motif: Evidence for histidine stabilization of the malonyl-enzyme intermediate

    SciTech Connect (OSTI)

    Poust, Sean; Yoon, Isu; Adams, Paul D.; Katz, Leonard; Petzold, Christopher J.; Keasling, Jay D.

    2014-10-06

    Acyltransferases determine which extender units are incorporated into polyketide and fatty acid products. Thus, the ping-pong acyltransferase mechanism utilizes a serine in a conserved GHSxG motif. However, the role of the conserved histidine in this motif is poorly understood. We observed that a histidine to alanine mutation (H640A) in the GHSxG motif of the malonyl-CoA specific yersiniabactin acyltransferase results in an approximately seven-fold higher hydrolysis rate over the wildtype enzyme, while retaining transacylation activity. We propose two possibilities for the reduction in hydrolysis rate: either H640 structurally stabilizes the protein by hydrogen bonding with a conserved asparagine in the ferredoxin-like subdomain of the protein, or a water-mediated hydrogen bond between H640 and the malonyl moiety stabilizes the malonyl-O-AT ester intermediate.

  6. Understanding the role of histidine in the GHSxG acyltransferase active site motif: Evidence for histidine stabilization of the malonyl-enzyme intermediate

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Poust, Sean; Yoon, Isu; Adams, Paul D.; Katz, Leonard; Petzold, Christopher J.; Keasling, Jay D.

    2014-10-06

    Acyltransferases determine which extender units are incorporated into polyketide and fatty acid products. Thus, the ping-pong acyltransferase mechanism utilizes a serine in a conserved GHSxG motif. However, the role of the conserved histidine in this motif is poorly understood. We observed that a histidine to alanine mutation (H640A) in the GHSxG motif of the malonyl-CoA specific yersiniabactin acyltransferase results in an approximately seven-fold higher hydrolysis rate over the wildtype enzyme, while retaining transacylation activity. We propose two possibilities for the reduction in hydrolysis rate: either H640 structurally stabilizes the protein by hydrogen bonding with a conserved asparagine in the ferredoxin-likemore » subdomain of the protein, or a water-mediated hydrogen bond between H640 and the malonyl moiety stabilizes the malonyl-O-AT ester intermediate.« less

  7. Electron-impact excitation of Fe{sup 2+}: A comparison of intermediate coupling frame transformation, Breit-Pauli and Dirac R-matrix calculations

    SciTech Connect (OSTI)

    Badnell, N. R.; Ballance, C. P.

    2014-04-20

    Modeling the spectral emission of low-charge iron group ions enables the diagnostic determination of the local physical conditions of many cool plasma environments such as those found in H II regions, planetary nebulae, active galactic nuclei, etc. Electron-impact excitation drives the population of the emitting levels and, hence, their emissivities. By carrying-out Breit-Pauli and intermediate coupling frame transformation (ICFT) R-matrix calculations for the electron-impact excitation of Fe{sup 2+}, which both use the exact same atomic structure and the same close-coupling expansion, we demonstrate the validity of the application of the powerful ICFT method to low-charge iron group ions. This is in contradiction to the finding of Bautista et al., who carried-out ICFT and Dirac R-matrix calculations for the same ion. We discuss possible reasons.

  8. Structural, dynamic, electronic, and vibrational properties of flexible, intermediate, and stressed rigid As-Se glasses and liquids from first principles molecular dynamics

    SciTech Connect (OSTI)

    Bauchy, M.; Kachmar, A.; Micoulaut, M.

    2014-11-21

    The structural, vibrational, electronic, and dynamic properties of amorphous and liquid As{sub x}Se{sub 1-x} (0.10 intermediate phase in these glassy networks, observed at 0.27

  9. Experimental investigation of supercritical CO2 trapping mechanisms at the Intermediate Laboratory Scale in well-defined heterogeneous porous media

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Trevisan, Luca; Pini, Ronny; Cihan, Abdullah; Birkholzer, Jens T.; Zhou, Quanlin; Illangasekare, Tissa H.

    2014-12-31

    The heterogeneous nature of typical sedimentary formations can play a major role in the propagation of the CO2 plume, eventually dampening the accumulation of mobile phase underneath the caprock. From core flooding experiments, it is also known that contrasts in capillary threshold pressure due to different pore size can affect the flow paths of the invading and displaced fluids and consequently influence the build- up of non-wetting phase (NWP) at interfaces between geological facies. The full characterization of the geologic variability at all relevant scales and the ability to make observations on the spatial and temporal distribution of the migrationmore » and trapping of supercritical CO2 is not feasible from a practical perspective. To provide insight into the impact of well-defined heterogeneous systems on the flow dynamics and trapping efficiency of supercritical CO2 under drainage and imbibition conditions, we present an experimental investigation at the meter scale conducted in synthetic sand reservoirs packed in a quasi-two-dimensional flow-cell. Two immiscible displacement experiments have been performed to observe the preferential entrapment of NWP in simple heterogeneous porous media. The experiments consisted of an injection, a fluid redistribution, and a forced imbibition stages conducted in an uncorrelated permeability field and a homogeneous base case scenario. We adopted x-ray attenuation analysis as a non-destructive technique that allows a precise measurement of phase saturations throughout the entire flow domain. By comparing a homogeneous and a heterogeneous scenario we have identified some important effects that can be attributed to capillary barriers, such as dampened plume advancement, higher non-wetting phase saturations, larger contact area between the injected and displaced phases, and a larger range of non-wetting phase saturations.« less

  10. POPULATION PARAMETERS OF INTERMEDIATE-AGE STAR CLUSTERS IN THE LARGE MAGELLANIC CLOUD. III. DYNAMICAL EVIDENCE FOR A RANGE OF AGES BEING RESPONSIBLE FOR EXTENDED MAIN-SEQUENCE TURNOFFS

    SciTech Connect (OSTI)

    Goudfrooij, Paul; Kozhurina-Platais, Vera; Puzia, Thomas H.; Chandar, Rupali E-mail: verap@stsci.edu E-mail: rupali.chandar@utoledo.edu

    2011-08-10

    We present a new analysis of 11 intermediate-age (1-2 Gyr) star clusters in the Large Magellanic Cloud based on Hubble Space Telescope imaging data. Seven of the clusters feature main-sequence turnoff (MSTO) regions that are wider than can be accounted for by a simple stellar population, whereas their red giant branches (RGBs) indicate a single value of [Fe/H]. The star clusters cover a range in present-day mass from about 1 x 10{sup 4} M{sub sun} to 2 x 10{sup 5} M{sub sun}. We compare radial distributions of stars in the upper and lower parts of the MSTO region, and calculate cluster masses and escape velocities from the present time back to a cluster age of 10 Myr. Our main result is that for all clusters in our sample with estimated escape velocities v{sub esc} {approx}> 15 km s{sup -1} at an age of 10 Myr, the stars in the brightest half of the MSTO region are significantly more centrally concentrated than the stars in the faintest half and more massive RGB and asymptotic giant branch stars. This is not the case for clusters with v{sub esc} {approx}< 10 km s{sup -1} at an age of 10 Myr. We argue that the wide MSTO region of such clusters is caused mainly by a {approx}200-500 Myr range in the ages of cluster stars due to extended star formation within the cluster from material shed by first-generation stars featuring slow stellar winds. Dilution of this enriched material by accretion of ambient interstellar matter is deemed plausible if the spread of [Fe/H] in this ambient gas was very small when the second-generation stars were formed in the cluster.

  11. Fluorescent Lighting | Department of Energy

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Electricity & Fuel » Lighting » Fluorescent Lighting Fluorescent Lighting Fluorescent Lighting Fluorescent lamps use 25%-35% of the energy used by incandescent products to provide a similar amount of light. They also last about 10 times longer (7,000-24,000 hours). The two general types of fluorescent lamps are: Compact fluorescent lamps (CFLs) -- commonly found with integral ballasts and screw bases, these are popular lamps often used in household fixtures Fluorescent tube and circline

  12. Phosphor blends for high-CRI fluorescent lamps

    DOE Patents [OSTI]

    Setlur, Anant Achyut (Niskayuna, NY); Srivastava, Alok Mani (Niskayuna, NY); Comanzo, Holly Ann (Niskayuna, NY); Manivannan, Venkatesan (Clifton Park, NY); Beers, William Winder (Chesterland, OH); Toth, Katalin (Pomaz, HU); Balazs, Laszlo D. (Budapest, HU)

    2008-06-24

    A phosphor blend comprises at least two phosphors each selected from one of the groups of phosphors that absorb UV electromagnetic radiation and emit in a region of visible light. The phosphor blend can be applied to a discharge gas radiation source to produce light sources having high color rendering index. A phosphor blend is advantageously includes the phosphor (Tb,Y,LuLa,Gd).sub.x(Al,Ga).sub.yO.sub.12:Ce.sup.3+, wherein x is in the range from about 2.8 to and including 3 and y is in the range from about 4 to and including 5.

  13. Zero energy-storage ballast for compact fluorescent lamps

    DOE Patents [OSTI]

    Schultz, William Newell (Niskayuna, NY); Thomas, Robert James (Rexford, NY)

    1999-01-01

    A CFL ballast includes complementary-type switching devices connected in series with their gates connected together at a control node. The switching devices supply a resonant tank circuit which is tuned to a frequency near, but slightly lower than, the resonant frequency of a resonant control circuit. As a result, the tank circuit restarts oscillations immediately following each zero crossing of the bus voltage. Such rapid restarts avoid undesirable flickering while maintaining the operational advantages and high efficacy of the CFL ballast.

  14. Zero energy-storage ballast for compact fluorescent lamps

    DOE Patents [OSTI]

    Schultz, W.N.; Thomas, R.J.

    1999-08-31

    A CFL ballast includes complementary-type switching devices connected in series with their gates connected together at a control node. The switching devices supply a resonant tank circuit which is tuned to a frequency near, but slightly lower than, the resonant frequency of a resonant control circuit. As a result, the tank circuit restarts oscillations immediately following each zero crossing of the bus voltage. Such rapid restarts avoid undesirable flickering while maintaining the operational advantages and high efficacy of the CFL ballast. 4 figs.

  15. CALiPER Snapshot Report: MR16 Lamps

    SciTech Connect (OSTI)

    2014-01-01

    Snapshot reports use data from DOE's LED Lighting Facts product list to compare the LED performance to standard technologies, and are designed to help lighting retailers, distributors, designers, utilities, energy efficiency program sponsors, and other stakeholders understand the current state of the LED market and its trajectory.

  16. New Energy Efficiency Standards for Metal Halide Lamp Fixtures...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    WASHINGTON - As part of the Energy Department's efforts to develop efficiency standards that cut carbon pollution and save money by saving energy, U.S. Energy Secretary Ernest ...

  17. PQL: Proposed Penalty (2013-CE-27001)

    Broader source: Energy.gov [DOE]

    DOE alleged in a Notice of Proposed Civil Penalty that P.Q.L., Inc. failed to certify various basic models of medium base compact fluorescent lamps, general service fluorescent lamps, fluorescent lamp ballasts, and illuminated exit signs as compliant with the applicable energy conservation standards.

  18. PQL: Order (2013-CE-27001)

    Broader source: Energy.gov [DOE]

    DOE ordered P.Q.L., Inc. to pay a $8,000 civil penalty after finding PQL had failed to certify that various basic models of medium base compact fluorescent lamps, general service fluorescent lamps, fluorescent lamp ballasts, and illuminated exit signs comply with the applicable energy conservation standards.

  19. Intermediate valence in single crystals of (Lu{sub 1?x}Y b{sub x}){sub 3}Rh{sub 4}Ge{sub 13} (0 ? x ? 1)

    SciTech Connect (OSTI)

    Rai, Binod K.; Morosan, E.

    2015-04-01

    Single crystals of (Lu{sub 1?x}Y b{sub x}){sub 3}Rh{sub 4}Ge{sub 13} were characterized by magnetization, specific heat, and electrical resistivity measurements. Doping Yb into the non-magnetic Lu{sub 3}Rh{sub 4}Ge{sub 13} compound tunes this cubic systems properties from a superconductor with disordered metal normal state (x < 0.05) to a Kondo for 0.05 ? x ?0.2 and intermediate valence at the highest Yb concentrations. The evidence for intermediate Yb valence comes from a broad maximum in the magnetic susceptibility and X-ray photoelectron spectroscopy. Furthermore, the resistivity displays a local maximum at finite temperatures at intermediate compositions x, followed by apparent metallic behavior closest to the Yb end compound in the series.

  20. Intermediate Energy Infobook and Intermediate Infobook Activities (29 Activities)

    Broader source: Energy.gov [DOE]

    The Teacher Infobook provides fact sheets about energy, the major energy sources, electricity, energy consumption, and energy efficiency and conservation. The background section includes an introduction to energy and details about individual energy sources. There are also sections on global climate change and several detailed fact sheets on electricity and energy consumption and efficiency. The companion student activities book reinforces the general information and facts about the energy sources.

  1. Functionally graded alumina-based thin film systems

    DOE Patents [OSTI]

    Moore, John J.; Zhong, Dalong

    2006-08-29

    The present invention provides coating systems that minimize thermal and residual stresses to create a fatigue- and soldering-resistant coating for aluminum die casting dies. The coating systems include at least three layers. The outer layer is an alumina- or boro-carbide-based outer layer that has superior non-wettability characteristics with molten aluminum coupled with oxidation and wear resistance. A functionally-graded intermediate layer or "interlayer" enhances the erosive wear, toughness, and corrosion resistance of the die. A thin adhesion layer of reactive metal is used between the die substrate and the interlayer to increase adhesion of the coating system to the die surface.

  2. Expression of low-, intermediate-, and high-affinity IL-2 receptors on B cell lines derived from patients with undifferentiated lymphoma of Burkitt's and non-Burkitt's types

    SciTech Connect (OSTI)

    Benjamin, D.; Rosolen, A.; Wormsley, S.B.; DeBault, L.E.; Colamonici, O.R. )

    1990-08-01

    IL-2 receptors on T cells exist in at least three forms which differ in their ligand-binding affinity. The low-affinity IL-2 receptor (IL-2R) consists of the 55-kDa Tac protein (p55 alpha), the intermediate-affinity site corresponds to the 70-kDa molecule (p70 beta), and the high-affinity IL-2R consists of a noncovalent heterodimeric structure involving both p55 alpha and p70 beta. We studied 24 B cell lines (8 EBV-negative and 16 EBV-positive) for IL-2R expression in the presence or absence of the tumor promoter, teleocidin. 125I-IL-2 radioreceptor binding assays and crosslinking studies demonstrated the sole expression of p55 alpha in EBV-negative cell lines only, whereas p55 alpha present in EBV-positive cell lines was always associated with p70 beta to construct high-affinity IL-2R. p70 beta was not detected in any of the EBV-negative cell lines, but was expressed on most of the EBV-positive cell lines (13 of 16). Our data also indicate that the expression of p55 alpha and p70 beta by radiolabeling correlates with their expression in flow cytometry, and that a large excess of p55 alpha is required to construct high-affinity IL-2R. Coexpression of p55 alpha and p70 beta on human B cells contributed to constructing high-affinity IL-2R hybrid complex as shown by rapid association rate contributed by p55 alpha and slow dissociation rate by p70 beta; teleocidin's ability to induce p55 alpha on cell lines which express p70 beta only, resulting in appearance of high-affinity IL-2R; and blocking p55 alpha by anti-Tac mAb in cell lines which constitutively express high-affinity IL-2R eliminated both high- and low-affinity components. The existence of low, intermediate, and high IL-2R on human B cells bears important future implications for understanding the mechanism of IL-2 signaling and the role of IL-2 in B cell activation, proliferation, and differentiation.

  3. Bio-based photosynthetic conversion of CO2 and water to replace petroleum

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    feedstock on an industrial scale - Energy Innovation Portal Early Stage R&D Early Stage R&D Biomass and Biofuels Biomass and Biofuels Find More Like This Return to Search Bio-based photosynthetic conversion of CO2 and water to replace petroleum feedstock on an industrial scale National Renewable Energy Laboratory Contact NREL About This Technology Technology Marketing Summary Alpha-ketoglutarate (AKG) is widely used as an organic synthesis intermediate, a medical and biochemical

  4. Diversity in short-to-intermediate range order in pure forms of amorphous silicon generated by a variety of experimental and modeling techniques

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Holmstrom, Eero; Haberl, Bianca; Pakarinen, Olli H; Nordlund, Kai; Djurabekova, Flyura; Arenal, Raul; Williams, James S.; Bradby, Jodie E.; Petersen, Timothy C.; Liu, Amelia

    2016-01-01

    Variability in the short-to-intermediate range order of pure amorphous silicon prepared by different experimental and computational techniques is probed by measuring mass density, atomic coordination, bond-angle deviation, and dihedral angle deviation. It is found that there is significant variability in order parameters at these length scales in this archetypal covalently bonded, monoatomic system. This diversity strongly reflects preparation technique and thermal history in both experimental and simulated systems. Experiment and simulation do not fully quantitatively agree, partly due to differences in the way parameters are accessed. However, qualitative agreement in the trends is identified. Relaxed forms of amorphous silicon closelymore » resemble continuous random networks generated by a hybrid method of bond-switching Monte Carlo and molecular dynamics simulation. As-prepared ion implanted amorphous silicon can be adequately modeled using a structure generated from amorphization via ion bombardement using energetic recoils. Preparation methods which narrowly avoid crystallization such as experimental pressure-induced amorphization or simulated melt-quenching result in inhomogeneous structures that contain regions with significant variations in atomic ordering. Ad hoc simulated structures containing small (1 nm) diamond cubic crystal inclusions were found to possess relatively high bond-angle deviations and low dihedral angle deviations, a trend that could not be reconciled with any experimental material.« less

  5. THE CENTRAL ENGINES OF TWO UNUSUAL RADIO-INTERMEDIATE/QUIET ACTIVE GALACTIC NUCLEI: III Zw 2 AND PG 1407+265

    SciTech Connect (OSTI)

    Chen Liang; Cao Xinwu; Bai, J. M. E-mail: cxw@shao.ac.cn

    2012-04-01

    We use the accretion disk/corona+jet model to fit the multi-band spectral energy distributions (SEDs) of two unusual radio-intermediate/quiet quasars. It is found that the optical/UV emission of III Zw 2 is probably dominated by the emission from the accretion disk. The X-ray emission should be dominated by the radiation from the jet, while the contribution of the disk corona is negligible. The optical/UV component in the SED of PG 1407+265 can be well modeled as the emission from the accretion disk, while the IR component is attributed to the thermal radiation from the dust torus with an opening angle of {approx}50 Degree-Sign . If the X-ray continuum emission is dominated by the synchrotron emission of the jet, the source should be a 'high peak frequency blazar', which obviously deviates from the normal blazar sequence. The observed SED can also be fitted quite well by the accretion disk/corona model with the viscosity parameter {alpha} = 0.5. The spectrum of the accretion disk/corona in PG 1407+265 satisfies the weak-line quasar criterion suggested in Laor and Davis.

  6. RELAP5-3D Modeling of Heat Transfer Components (Intermediate Heat Exchanger and Helical-Coil Steam Generator) for NGNP Application

    SciTech Connect (OSTI)

    N. A. Anderson; P. Sabharwall

    2014-01-01

    The Next Generation Nuclear Plant project is aimed at the research and development of a helium-cooled high-temperature gas reactor that could generate both electricity and process heat for the production of hydrogen. The heat from the high-temperature primary loop must be transferred via an intermediate heat exchanger to a secondary loop. Using RELAP5-3D, a model was developed for two of the heat exchanger options a printed-circuit heat exchanger and a helical-coil steam generator. The RELAP5-3D models were used to simulate an exponential decrease in pressure over a 20 second period. The results of this loss of coolant analysis indicate that heat is initially transferred from the primary loop to the secondary loop, but after the decrease in pressure in the primary loop the heat is transferred from the secondary loop to the primary loop. A high-temperature gas reactor model should be developed and connected to the heat transfer component to simulate other transients.

  7. Diversity in short-to-intermediate range order in pure forms of amorphous silicon generated by a variety of experimental and modeling techniques

    SciTech Connect (OSTI)

    Holmstrom, Eero; Haberl, Bianca; Pakarinen, Olli H; Nordlund, Kai; Djurabekova, Flyura; Arenal, Raul; Williams, James S.; Bradby, Jodie E.; Petersen, Timothy C.; Liu, Amelia

    2016-01-01

    Variability in the short-to-intermediate range order of pure amorphous silicon prepared by different experimental and computational techniques is probed by measuring mass density, atomic coordination, bond-angle deviation, and dihedral angle deviation. It is found that there is significant variability in order parameters at these length scales in this archetypal covalently bonded, monoatomic system. This diversity strongly reflects preparation technique and thermal history in both experimental and simulated systems. Experiment and simulation do not fully quantitatively agree, partly due to differences in the way parameters are accessed. However, qualitative agreement in the trends is identified. Relaxed forms of amorphous silicon closely resemble continuous random networks generated by a hybrid method of bond-switching Monte Carlo and molecular dynamics simulation. As-prepared ion implanted amorphous silicon can be adequately modeled using a structure generated from amorphization via ion bombardement using energetic recoils. Preparation methods which narrowly avoid crystallization such as experimental pressure-induced amorphization or simulated melt-quenching result in inhomogeneous structures that contain regions with significant variations in atomic ordering. Ad hoc simulated structures containing small (1 nm) diamond cubic crystal inclusions were found to possess relatively high bond-angle deviations and low dihedral angle deviations, a trend that could not be reconciled with any experimental material.

  8. Revisions included in HUD Intermediate Minimum Property Standards Supplement 4930. 2, 1977 edition: solar heating and domestic hot-water systems

    SciTech Connect (OSTI)

    Not Available

    1984-04-01

    This addendum to a 1977 HUD publication contains revisions and additions to the existing intermediate minimum property standards supplment for solar heating and cooling systems. Building design revisions cover fire protection, penetrations, and roof coverings. Changes to guidelines for materials, such as those for thermal and ultraviolet stability and moisture resistance, are detailed. Flash points of toxic and combustive fluids, chemical and physical compatibility, and flame spread and resistance of insulation materials are also explained. Construction standards were revised for hail loads; waterproofing insulated exterior storage containers, pipes, and ducts; and for passive systems. Standards also were revised for power-operated protection, dust and dirt prevention, and chimney and vent heights. Radiation temperature, draft control, and thermal energy storage and loss standards were deleted. Other standards for insulation values for thermal devices, lighting protection, and sealing and testing air distribution systems were added. Appended materials contain revisions to calculation procedures for determining the thermal performance of active, solar space heating, and domestic hot water systems. A revised materials list for properties of typical cover materials, absorptive coatings, thermal storage unit containers, and heat-transfer liquids is provided. Revisions to acceptable engineering practice standards are also included.

  9. Spectroscopic study of reaction intermediates and mechanisms in nitramine decomposition and combustion. Final report, 20 March 1992-19 March 1995

    SciTech Connect (OSTI)

    Jacox, M.B.

    1995-05-20

    The infrared spectra of reaction intermediates trapped in solid neon were studied in order to support the development of diagnostics for short-lived species which are reaction carriers in nitramine decomposition and combustion and to derive information about reactions which are important in the condensed-phase decomposition of nitramines. Nitromethane and monomethylnitramine were used as model compounds in these studies. Evidence was obtained for the formation of water complexes with both of these species. The results support the water-catalyzed decomposition mechanism for nitramines that was proposed by Melius. Studies of the photodecomposition of isotopically substituted monomethylnitramine demonstrate that four different groups of products are formed. Tentative spectral assignments are made for the aci-isomer of monomethylnitramine and for CH3NHONO. The final photodecomposition products are CH4, NO, CH3OH, and N20. Other studies have provided evidence for the formation of a weakly bonded complex of H2 with H20, as well as spectral data for the HCC free radical and for the H20+, N02+, NO(2-), and NO(3-), molecular ions.

  10. Numerical techniques for steady two-dimensional transcritical stratified flow problems, with an application to the intermediate field dynamics of Ocean Thermal Energy Conversion plants

    SciTech Connect (OSTI)

    Jones, J.M.; Jirka, G.H.; Caughey, D.A.

    1985-01-01

    The development of predictive techniques for the predominantly horizontal, layered fluid motions that result when a continuous buoyant source is discharged into an ambient fluid at a bounding surface, interface or equilibrium level is studied. Although the numerical techniques developed are applicable to general discharge configurations, the model development is focused on the particular case of a radial source of buoyancy and momentum discharged into a uniform ambient crossflow. The resulting density current is analyzed by application of the depth-integrated hydrodynamic equations. The density current dynamics are shown to vary with the relative intermediate- to near-field strengths, as characterized by the ratio of their respective length scales. The complete range of this interaction, from small near-field effects to large near-field effects, is investigated. Results are presented as the depth integrated velocity and current thickness distributions for different field strength values. The model predictions are compared to two sets of laboratory data and to limited field information, involving a river discharge and a submerged outfall into the ocean. Good agreement is obtained in all cases. Finally, the model results are applied to the prediction of a river plume into a coastal ocean current and to the continuous discharge from an OTEC plant operating in the stratified ocean. In both cases, the results indicate the significant horizontal extent (order of several kilometers) of the resulting current, together with their limited vertical extent (order of several meters). Their strong sensitivity to ambient current magnitude and stratification strength is demonstrated.

  11. High temperature phase stabilities and electrochemical properties of InBaCo4-xZnxO7 cathodes for intermediate temperature solid oxide fuel cells

    SciTech Connect (OSTI)

    Kim, Jung-Hyun; Young Nam, Kim; Bi, Zhonghe; Manthiram, Arumugam; Paranthaman, Mariappan Parans; Huq, Ashfia

    2011-01-01

    InBaCo4-xZnxO7 oxides have been synthesized and characterized as cathode materials for intermediate temperature solid oxide fuel cells (IT-SOFC). The effect of Zn substitution for Co on the structure, phase stability, thermal expansion, and electrochemical properties of the InBaCo4-xZnxO7 has been investigated. The increase in the Zn content from x = 1 to 1.5 improves the high temperature phase stability at 600 oC and 700 oC for 100 h, and chemical stability against a Gd0.2Ce0.8O1.9 (GDC) electrolyte. Thermal expansion coefficient (TEC) values of the InBaCo4-xZnxO7 (x = 1, 1.5, 2) specimens were determined to be 8.6 10-6 9.6 10-6 /oC in the range of 80 900 oC, which provides good thermal expansion compatibility with the standard SOFC electrolyte materials. The InBaCo4-xZnxO7 + GDC (50:50 wt. %) composite cathodes exhibit improved cathode performances compared to those obtained from the simple InBaCo4-xZnxO7 cathodes due to the extended triple-phase boundary (TPB) and enhanced oxide-ion conductivity through the GDC portion in the composites.

  12. Conceptual process design and economics for the production of high-octane gasoline blendstock via indirect liquefaction of biomass through methanol/dimethyl ether intermediates

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Tan, Eric C. D.; Talmadge, Michael; Dutta, Abhijit; Hensley, Jesse; Snowden-Swan, Lesley J.; Humbird, David; Schaidle, Joshua; Biddy, Mary

    2015-10-28

    This paper describes in detail one potential conversion process for the production of high-octane gasoline blendstock via indirect liquefaction of biomass. The processing steps of this pathway include the conversion of biomass to synthesis gas via indirect gasification, gas clean-up via reforming of tars and other hydrocarbons, catalytic conversion of syngas to methanol, methanol dehydration to dimethyl ether (DME), and the homologation of DME over a zeolite catalyst to high-octane gasoline-range hydrocarbon products. The current process configuration has similarities to conventional methanol-to-gasoline (MTG) technologies, but there are key distinctions, specifically regarding the product slate, catalysts, and reactor conditions. A techno-economicmore » analysis is performed to investigate the production of high-octane gasoline blendstock. The design features a processing daily capacity of 2000 tonnes (2205 short tons) of dry biomass. The process yields 271 liters of liquid fuel per dry tonne of biomass (65 gal/dry ton), for an annual fuel production rate of 178 million liters (47 MM gal) at 90% on-stream time. The estimated total capital investment for an nth-plant is $438 million. The resulting minimum fuel selling price (MFSP) is $0.86 per liter or $3.25 per gallon in 2011 US dollars. A rigorous sensitivity analysis captures uncertainties in costs and plant performance. Sustainability metrics for the conversion process are quantified and assessed. The potential premium value of the high-octane gasoline blendstock is examined and found to be at least as competitive as fossil-derived blendstocks. A simple blending strategy is proposed to demonstrate the potential for blending the biomass-derived blendstock with petroleum-derived intermediates. Published 2015. This article is a U.S. Government work and is in the public domain in the USA. Biofuels, Bioproducts and Biorefining published by Society of Industrial Chemistry and John Wiley & Sons Ltd.« less

  13. New clues to the cause of extended main-sequence turnoffs in intermediate-age star clusters in the Magellanic Clouds

    SciTech Connect (OSTI)

    Correnti, Matteo; Goudfrooij, Paul; Kalirai, Jason S.; Girardi, Leo; Puzia, Thomas H.; Kerber, Leandro E-mail: goudfroo@stsci.edu E-mail: leo.girardi@oapd.inaf.it E-mail: lkerber@gmail.com

    2014-10-01

    We use the Wide Field Camera 3 on board the Hubble Space Telescope (HST) to obtain deep, high-resolution images of two intermediate-age star clusters in the Large Magellanic Cloud of relatively low mass (?10{sup 4} M {sub ?}) and significantly different core radii, namely NGC 2209 and NGC 2249. For comparison purposes, we also reanalyzed archival HST images of NGC 1795 and IC 2146, two other relatively low-mass star clusters. From the comparison of the observed color-magnitude diagrams with Monte Carlo simulations, we find that the main-sequence turnoff (MSTO) regions in NGC 2209 and NGC 2249 are significantly wider than that derived from simulations of simple stellar populations, while those in NGC 1795 and IC 2146 are not. We determine the evolution of the clusters' masses and escape velocities from an age of 10 Myr to the present age. We find that differences among these clusters can be explained by dynamical evolution arguments if the currently extended clusters (NGC 2209 and IC 2146) experienced stronger levels of initial mass segregation than the currently compact ones (NGC 2249 and NGC 1795). Under this assumption, we find that NGC 2209 and NGC 2249 have estimated escape velocities, V {sub esc} ? 15 km s{sup 1} at an age of 10 Myr, large enough to retain material ejected by slow winds of first-generation stars, while the two clusters that do not feature extended MSTOs have V {sub esc} ? 12 km s{sup 1} at that age. These results suggest that the extended MSTO phenomenon can be better explained by a range of stellar ages rather than a range of stellar rotation velocities or interacting binaries.

  14. Structure of Naegleria Tet-like dioxygenase (NgTet1) in complexes with a reaction intermediate 5-hydroxymethylcytosine DNA

    SciTech Connect (OSTI)

    Hashimoto, Hideharu; Pais, June E.; Dai, Nan; Corra, Jr., Ivan R.; Zhang, Xing; Zheng, Yu; Cheng, Xiaodong

    2015-08-31

    The family of ten-eleven translocation (Tet) dioxygenases is widely distributed across the eukaryotic tree of life, from mammals to the amoeboflagellate Naegleria gruberi. Like mammalian Tet proteins, the Naegleria Tet-like protein, NgTet1, acts on 5-methylcytosine (5mC) and generates 5-hydroxymethylcytosine (5hmC), 5-formylcytosine (5fC) and 5-carboxylcytosine (5caC) in three consecutive, Fe(II)- and ?-ketoglutarate-dependent oxidation reactions. The two intermediates, 5hmC and 5fC, could be considered either as the reaction product of the previous enzymatic cycle or the substrate for the next cycle. Here we present a new crystal structure of NgTet1 in complex with DNA containing a 5hmC. Along with the previously solved NgTet15mC structure, the two complexes offer a detailed picture of the active site at individual stages of the reaction cycle. In the crystal, the hydroxymethyl (OH-CH2-) moiety of 5hmC points to the metal center, representing the reaction product of 5mC hydroxylation. The hydroxyl oxygen atom could be rotated away from the metal center, to a hydrophobic pocket formed by Ala212, Val293 and Phe295. Such rotation turns the hydroxyl oxygen atom away from the product conformation, and exposes the target CH2 towards the metal-ligand water molecule, where a dioxygen O2 molecule would occupy to initiate the next round of reaction by abstracting a hydrogen atom from the substrate. The Ala212-to-Val (A212V) mutant profoundly limits the product to 5hmC, probably due to the reduced hydrophobic pocket size restricts the binding of 5hmC as a substrate.

  15. Conceptual process design and economics for the production of high-octane gasoline blendstock via indirect liquefaction of biomass through methanol/dimethyl ether intermediates

    SciTech Connect (OSTI)

    Tan, Eric C. D.; Talmadge, Michael; Dutta, Abhijit; Hensley, Jesse; Snowden-Swan, Lesley J.; Humbird, David; Schaidle, Joshua; Biddy, Mary

    2015-10-28

    This paper describes in detail one potential conversion process for the production of high-octane gasoline blendstock via indirect liquefaction of biomass. The processing steps of this pathway include the conversion of biomass to synthesis gas via indirect gasification, gas clean-up via reforming of tars and other hydrocarbons, catalytic conversion of syngas to methanol, methanol dehydration to dimethyl ether (DME), and the homologation of DME over a zeolite catalyst to high-octane gasoline-range hydrocarbon products. The current process configuration has similarities to conventional methanol-to-gasoline (MTG) technologies, but there are key distinctions, specifically regarding the product slate, catalysts, and reactor conditions. A techno-economic analysis is performed to investigate the production of high-octane gasoline blendstock. The design features a processing daily capacity of 2000 tonnes (2205 short tons) of dry biomass. The process yields 271 liters of liquid fuel per dry tonne of biomass (65 gal/dry ton), for an annual fuel production rate of 178 million liters (47 MM gal) at 90% on-stream time. The estimated total capital investment for an nth-plant is $438 million. The resulting minimum fuel selling price (MFSP) is $0.86 per liter or $3.25 per gallon in 2011 US dollars. A rigorous sensitivity analysis captures uncertainties in costs and plant performance. Sustainability metrics for the conversion process are quantified and assessed. The potential premium value of the high-octane gasoline blendstock is examined and found to be at least as competitive as fossil-derived blendstocks. A simple blending strategy is proposed to demonstrate the potential for blending the biomass-derived blendstock with petroleum-derived intermediates. Published 2015. This article is a U.S. Government work and is in the public domain in the USA. Biofuels, Bioproducts and Biorefining published by Society of Industrial Chemistry and John Wiley & Sons Ltd.

  16. Role of the reaction intermediates in determining PHIP (parahydrogen induced polarization) effect in the hydrogenation of acetylene dicarboxylic acid with the complex [Rh (dppb)]{sup +} (dppb: 1,4-bis(diphenylphosphino)butane)

    SciTech Connect (OSTI)

    Reineri, F.; Aime, S.; Gobetto, R.; Nervi, C.

    2014-03-07

    This study deals with the parahydrogenation of the symmetric substrate acetylene dicarboxylic acid catalyzed by a Rh(I) complex bearing the chelating diphosphine dppb (1,4-bis(diphenylphosphino)butane). The two magnetically equivalent protons of the product yield a hyperpolarized emission signal in the {sup 1}H-NMR spectrum. Their polarization intensity varies upon changing the reaction solvent from methanol to acetone. A detailed analysis of the hydrogenation pathway is carried out by means of density functional theory calculations to assess the structure of hydrogenation intermediates and their stability in the two solvents. The observed polarization effects have been accounted on the basis of the obtained structures. Insights into the lifetime of a short-lived reaction intermediate are also obtained.

  17. System and Battery Charge Control for PV-Powered AC Lighting Systems

    SciTech Connect (OSTI)

    Kern, G.

    1999-04-01

    This report reviews a number of issues specific to stand-alone AC lighting systems. A review of AC lighting technology is presented, which discusses the advantages and disadvantages of various lamps. The best lamps for small lighting systems are compact fluorescent. The best lamps for intermediate-size systems are high- or low-pressure sodium. Specifications for battery charging and load control are provided with the goal of achieving lamp lifetimes on the order of 16,000 to 24,000 hours and battery lifetimes of 4 to 5 years. A rough estimate of the potential domestic and global markets for stand-alone AC lighting systems is presented. DC current injection tests were performed on high-pressure sodium lamps and the test results are presented. Finally, a prototype system was designed and a prototype system controller (with battery charger and DC/AC inverter) was developed and built.

  18. Computational Chemistry-Based Identification of Ultra-Low Temperature Water-Gas-Shift Catalysts

    SciTech Connect (OSTI)

    Manos Mavrikakis

    2008-08-31

    The current work seeks to identify novel, catalytically-active, stable, poison-resistant LWGS catalysts that retain the superior activity typical of conventional Cu catalysts but can be operated at similar or lower temperatures. A database for the Binding Energies (BEs) of the LWGS relevant species, namely CO, O and OH on the most-stable, close-packed facets of a set of 17 catalytically relevant transition metals was established. This BE data and a database of previously established segregation energies was utilized to predict the stability of bimetallic NSAs that could be synthesized by combinations of the 17 parent transition metals. NSAs that were potentially stable both in vacuo and under the influence of strong-binding WGS intermediates were then selected for adsorption studies. A set of 40 NSAs were identified that satisfied all three screener criteria and the binding energies of CO, O and OH were calculated on a set of 66, 43 and 79 NSA candidates respectively. Several NSAs were found that bound intermediates weaker than the monometallic catalysts and were thus potentially poison-resistant. Finally, kinetic studies were performed and resulted in the discovery of a specific NSA-based bimetallic catalyst Cu/Pt that is potentially a promising LWGS catalyst. This stable Cu/Pt subsurface alloy is expected to provide facile H{sub 2}O activation and remain relatively resistant from the poisoning by CO, S and formate intermediates.

  19. Etasolar Ltd | Open Energy Information

    Open Energy Info (EERE)

    Sector: Solar Product: Korea-based manufacturer of monocrystalline PV modules, inverters, tracking systems, and solar-powered street lamp. Coordinates: 35.841728,...

  20. Fuel from Tobacco and Arundo Donax: Synthetic Crop for Direct Drop-in Biofuel Production through Re-routing the Photorespiration Intermediates and Engineering Terpenoid Pathways

    SciTech Connect (OSTI)

    None

    2012-02-15

    PETRO Project: Biofuels offer renewable alternatives to petroleum-based fuels that reduce net greenhouse gas emissions to nearly zero. However, traditional biofuels production is limited not only by the small amount of solar energy that plants convert through photosynthesis into biological materials, but also by inefficient processes for converting these biological materials into fuels. Farm-ready, non-food crops are needed that produce fuels or fuel-like precursors at significantly lower costs with significantly higher productivity. To make biofuels cost-competitive with petroleum-based fuels, biofuels production costs must be cut in half.