Sample records for initial heavy metal

  1. Heavy metal biosensor

    SciTech Connect (OSTI)

    Hillson, Nathan J; Shapiro, Lucille; Hu, Ping; Andersen, Gary L

    2014-04-15T23:59:59.000Z

    Compositions and methods are provided for detection of certain heavy metals using bacterial whole cell biosensors.

  2. PHYTOEXTRACTION OF HEAVY METALS

    E-Print Network [OSTI]

    Blouin-Demers, Gabriel

    Plants Chelating agents Pb hyperaccumulation Effects of pH on metal extraction Disposal options contaminants from soils Contaminants must be in harvestable portions of the plant (Wongkongkatep et al. 2003) Chelating Agents: desorb heavy metals from soil matrix and form water-soluble metal complexes (Shen et al

  3. Heavy Metal Humor: Reconsidering Carnival in Heavy Metal Culture

    E-Print Network [OSTI]

    Powell, Gary Botts

    2013-06-05T23:59:59.000Z

    This thesis considers Bakhtin?s carnivalesque theory by analyzing comedic rhetoric performed by two comedic metal bands. Through the theories of Johan Huizinga and Mikhail Bakhtin, Chapter I: I Play Metal argues that heavy metal culture is a modern...

  4. Process for removing heavy metal compounds from heavy crude oil

    DOE Patents [OSTI]

    Cha, Chang Y. (Golden, CO); Boysen, John E. (Laramie, WY); Branthaver, Jan F. (Laramie, WY)

    1991-01-01T23:59:59.000Z

    A process is provided for removing heavy metal compounds from heavy crude oil by mixing the heavy crude oil with tar sand; preheating the mixture to a temperature of about 650.degree. F.; heating said mixture to up to 800.degree. F.; and separating tar sand from the light oils formed during said heating. The heavy metals removed from the heavy oils can be recovered from the spent sand for other uses.

  5. Removal of Heavy Metals from Aqueous Systems with Thiol Functionalized...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Heavy Metals from Aqueous Systems with Thiol Functionalized Superparamagnetic Nanoparticles. Removal of Heavy Metals from Aqueous Systems with Thiol Functionalized...

  6. Functionalized Nanoporous Silica for Removal of Heavy Metals...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Nanoporous Silica for Removal of Heavy Metals from Biological Systems; Adsorption and Application. Functionalized Nanoporous Silica for Removal of Heavy Metals from Biological...

  7. atmospheric heavy metal: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    381Chemistry 330 Study Guide 217 Unit 7 Toxic Heavy Metals Overview In ancient Rome wine was stored. Metals--especially heavy metals--pose a unique environmental pollution...

  8. aquatic heavy metals: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    381Chemistry 330 Study Guide 217 Unit 7 Toxic Heavy Metals Overview In ancient Rome wine was stored. Metals--especially heavy metals--pose a unique environmental pollution...

  9. assess heavy metals: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    381Chemistry 330 Study Guide 217 Unit 7 Toxic Heavy Metals Overview In ancient Rome wine was stored. Metals--especially heavy metals--pose a unique environmental pollution...

  10. airborne heavy metals: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    381Chemistry 330 Study Guide 217 Unit 7 Toxic Heavy Metals Overview In ancient Rome wine was stored. Metals--especially heavy metals--pose a unique environmental pollution...

  11. avoid heavy metals: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    381Chemistry 330 Study Guide 217 Unit 7 Toxic Heavy Metals Overview In ancient Rome wine was stored. Metals--especially heavy metals--pose a unique environmental pollution...

  12. Heavy Metal Humor: Reconsidering Carnival in Heavy Metal Culture

    E-Print Network [OSTI]

    Powell, Gary Botts

    2013-06-05T23:59:59.000Z

    the majority of the land and maintained a social hierarchy that created a vast wealth disparity between the peasants and the church and upper classes. The Church?s feudal ownership of the land meant that it had power over the peasants, limiting social... manifest itself in metal culture. It may further 16 be suggested that the socio-economic climate from which metal culture developed has analogous threads to 16th century French feudal society. While feudalism and capitalism differ, both French...

  13. A Fuzzy Model of Heavy Metal Loadings in Marine Environment

    E-Print Network [OSTI]

    Kuncheva, Ludmila I.

    A Fuzzy Model of Heavy Metal Loadings in Marine Environment L.I. Kuncheva1 , J. Wrench2 , L.C. Jain model of the loadings of heavy metals for two coastal areas of the Irish Sea (Liverpool Bay, Morecambe Bay, heavy metal concentrations, index of spa- tial distribution, spatial data analysis. 1

  14. Plant rhamnogalacturonan II complexation of heavy metal cations

    DOE Patents [OSTI]

    O'Neill, Malcolm A. (Winterville, GA); Pellerin, Patrice J. M. (Montpellier, FR); Warrenfeltz, Dennis (Athens, GA); Vidal, Stephane (Combaillaux, FR); Darvill, Alan G. (Athens, GA); Albersheim, Peter (Athens, GA)

    1999-01-01T23:59:59.000Z

    The present invention provides rhamnogalacturonan-II (RG-II) and relates to its ability to complex specific multivalent heavy metal cations. In the presence of boric acid, RG-II monomers form dimers that are cross-linked by a borate ester. The yield of such borate ester cross-linked dimers of RG-II is enhanced in the presence of specific heavy metal cations. The present invention further relates to the utility of RG-II in assays for the detection of specific heavy metal contamination; as a reagent useful in the removal of specific heavy metal cations contaminating foods and liquids, for example, fish, wines, etc.; as a pharmaceutical composition useful as an antidote in specific heavy metal cation poisoning; as a treatment for the detoxification of specific heavy metal cations from blood and/or tissues; and in a method of remediation of waters and soils contaminated with specific heavy metal cations.

  15. Plant rhamnogalacturonan II complexation of heavy metal cations

    DOE Patents [OSTI]

    O`Neill, M.A.; Pellerin, P.J.M.; Warrenfeltz, D.; Vidal, S.; Darvill, A.G.; Albersheim, P.

    1999-03-02T23:59:59.000Z

    The present invention provides rhamnogalacturonan-II (RG-II) and relates to its ability to complex specific multivalent heavy metal cations. In the presence of boric acid, RG-II monomers form dimers that are cross-linked by a borate ester. The yield of such borate ester cross-linked dimers of RG-II is enhanced in the presence of specific heavy metal cations. The present invention further relates to the utility of RG-II in assays for the detection of specific heavy metal contamination; as a reagent useful in the removal of specific heavy metal cations contaminating foods and liquids, for example, fish, wines, etc.; as a pharmaceutical composition useful as an antidote in specific heavy metal cation poisoning; as a treatment for the detoxification of specific heavy metal cations from blood and/or tissues; and in a method of remediation of waters and soils contaminated with specific heavy metal cations. 15 figs.

  16. TOLERANCE OF HEAVY METALS IN VASCULAR PLANTS: ARSENIC HYPERACCUMULATIONBY

    E-Print Network [OSTI]

    Ma, Lena

    CHAPTER 28 b TOLERANCE OF HEAVY METALS IN VASCULAR PLANTS: ARSENIC HYPERACCUMULATIONBY CHINESE the roots take up colossal amounts of a toxic metal from soils and rapidly sequester into their above-ground hyperaccumulation in the light of accumulated knowledge on heavy metal tolerance in higher plants. 1.INTRODUCTION

  17. Metal sulfide initiators for metal oxide sorbent regeneration

    DOE Patents [OSTI]

    Turk, B.S.; Gupta, R.P.

    1999-06-22T23:59:59.000Z

    A process of regenerating a sulfided sorbent is provided. According to the process of the invention, a substantial portion of the energy necessary to initiate the regeneration reaction is provided by the combustion of a particulate metal sulfide additive. In using the particulate metal sulfide additive, the oxygen-containing gas used to regenerate the sulfided sorbent can be fed to the regeneration zone without heating or at a lower temperature than used in conventional processes wherein the regeneration reaction is initiated only by heating the oxygen-containing gas. The particulate metal sulfide additive is preferably an inexpensive mineral ore such as iron pyrite which does not adversely affect the regeneration or corresponding desulfurization reactions. The invention further includes a sorbent composition comprising the particulate metal sulfide additive in admixture with an active metal oxide sorbent capable of removing one or more sulfur compounds from a sulfur-containing gas stream. 1 fig.

  18. Contamination of heavy metals in mangroves: A comparison between Cao Martn Pea and

    E-Print Network [OSTI]

    Gilbes, Fernando

    Contamination of heavy metals in mangroves: A comparison between Cao that contamination of heavy metals in mangroves decrease their chlorophyll levels and how heavy metals contamination has affected them. The images utilized

  19. Initial Parton Distribution just after Heavy Ion Collisions

    E-Print Network [OSTI]

    Ghi R. Shin; Kang S. Lee

    2006-12-08T23:59:59.000Z

    We study the initial distribution of a parton system which is formed just after relativistic heavy ion collision by the elastic scattering among the constituent partons in details and analyze the baryon and strangeness contents of the primary parton system. We present the rapidity and energy distributions of the system.

  20. Heavy metals emission from controlled combustion of PVC

    E-Print Network [OSTI]

    El-Ayyoubi, Mohammed A.

    1989-01-01T23:59:59.000Z

    . Malave (Mem er) G. mble Bennett (Head of Depar tment) August 1989 ABSTRACT Heavy Metals Emission from Combustion of PVC. (August 1989) Mohammed A. El-Ayyoubi, B. S. , Texas ASM University; Chair of Advisory Committee: Dr. John P. Wagner... The primary purpose of this research paper is the identification of heavy metals and other potentially harmful smoke components emitted to the atmosphere as a result of Poly(vinyl chloride) combustion in municipal incinerators . In addition, analysis...

  1. Heavy metal ions are potent inhibitors of protein folding

    SciTech Connect (OSTI)

    Sharma, Sandeep K. [Biochemisches Institut, Universitaet Zuerich, CH-8057 Zuerich (Switzerland); Departement de Biologie Moleculaire Vegetale, Universite de Lausanne, CH-1015 Lausanne (Switzerland); Goloubinoff, Pierre [Departement de Biologie Moleculaire Vegetale, Universite de Lausanne, CH-1015 Lausanne (Switzerland); Christen, Philipp [Biochemisches Institut, Universitaet Zuerich, CH-8057 Zuerich (Switzerland)], E-mail: christen@bioc.uzh.ch

    2008-07-25T23:59:59.000Z

    Environmental and occupational exposure to heavy metals such as cadmium, mercury and lead results in severe health hazards including prenatal and developmental defects. The deleterious effects of heavy metal ions have hitherto been attributed to their interactions with specific, particularly susceptible native proteins. Here, we report an as yet undescribed mode of heavy metal toxicity. Cd{sup 2+}, Hg{sup 2+} and Pb{sup 2+} proved to inhibit very efficiently the spontaneous refolding of chemically denatured proteins by forming high-affinity multidentate complexes with thiol and other functional groups (IC{sub 50} in the nanomolar range). With similar efficacy, the heavy metal ions inhibited the chaperone-assisted refolding of chemically denatured and heat-denatured proteins. Thus, the toxic effects of heavy metal ions may result as well from their interaction with the more readily accessible functional groups of proteins in nascent and other non-native form. The toxic scope of heavy metals seems to be substantially larger than assumed so far.

  2. Heavy metal geochemistry of the Pontchartrain-Maurepas estuarine complex

    SciTech Connect (OSTI)

    Flowers, G.C. (Tulane Univ., New Orleans, LA (USA)); Isphording, W.C. (Univ. of South Alabama, Mobile (USA))

    1990-09-01T23:59:59.000Z

    The Pontchartrain-Maurepas estuarine complex has become the focus of an intense debate concerning hydraulic shell dredging and its effects. Besides disrupting the benthic community, it has been alleged by the opponents of shell dredging that the mining process releases harmful concentrations of heavy metals into the water column. Bottom sediment heavy metal data combined with ion-site partitioning analyses provide a basis for estimating heavy metal release during dredging. The concentrations of Cu, Cr, Ni, Fe, Zn, V, Co, Pb, and Ba were determined for bottom sediment samples collected during 1987. The areal distribution of metals in the complex is controlled largely by sediment texture. As the clay content of the sediment increases, so does metal content. This observation seems to hold for most estuaries along the northern Gulf of Mexico. The concentrations of all metals except Pb were found to be positively correlated with Fe-content. Comparison of average metal contents with data from other estuaries along the Gulf Coast indicates that the complex has not been heavily impacted by anthropogenic input of metals. Because dredging disrupts redox conditions in the sediment, the potential release of metals into the water column is a real concern. However, partitioning analyses indicate that the majority of metal present in the bottom sediments is in relatively stable phases. The metal content of the exchangeable and organic phases, which are most easily affected by redox changes, was found to be minor. The rapid process of hydraulic shell mining, the positive Eh of the lake water, and the fine-grained suspended sediments result in a minor impact of dredging on water quality. Released metals are rapidly scavenged by adsorption and coprecipitation reactions.

  3. Heavy metal characterization of municipal solid waste compost

    E-Print Network [OSTI]

    Worsham, Michael Craig

    1992-01-01T23:59:59.000Z

    -Chair of Committee) Emile A. Schweikert (Member) James T. P Y o (Head of Depar ment) May 1992 ABSTRA. CT Heavy Metal Characterization Of Municipal Solid Waste Compost (May 1992) Michael Craig Worsham, B. S. , S. U. N. Y. at Stony Brook Co-Chairs of Advisory... Committee: Dr. Bill Batchelor Dr. Kirk W. Brown Waste incineration and composting create solid residues which are later applied to or buried under soils. Although incinerator ash has been studied extensively for heavy metal content, much less is known...

  4. Heavy metal concentration in bay sediments of Japan

    SciTech Connect (OSTI)

    Fukue, Masaharu; Kato, Yoshihisa; Nakamura, Takaaki [Tokai Univ., Shimizu (Japan); Yamasaki, Shoichi [Aoki Marine Ltd., Fukushima, Osaka (Japan)

    1995-12-31T23:59:59.000Z

    Because industry discharge wastes into the sea, marine sediments can be contaminated with various kinds of hazardous and toxic substances. This study discusses how the degree of pollution of heavy metals affects the marine sediments from Osaka Bay and Tokyo Bay. In this study, the concentrations of various metals, such as manganese, iron, aluminum, titanium, vanadium, copper, phosphorus, etc., were measured from sediment samples obtained from different sites in the bays. However, the results had to be corrected because background concentrations for each metal differ with site location and grain size characteristics. The large difference between background and individual concentrations at various soil depths indicates that the surface layers of the seabed are significantly polluted with some species of heavy metal and other elements.

  5. Heavy metals in composted municipal solid wastes for

    E-Print Network [OSTI]

    Blouin-Demers, Gabriel

    Heavy metals in composted municipal solid wastes for amendment of agricultural soils/ Mtaux lourds dans le compost de dchets municipaux pour application agricole Valrie Duchesneau, #4634809 EVS4904 mtaux lourds des compostes de dchets municipaux? http://www.ecometiers.com/fiche/images/43.jpg La

  6. THERMODYNAMIC STUDY OF HEAVY METALS BEHAVIOUR DURING MUNICIPAL WASTE INCINERATION

    E-Print Network [OSTI]

    Boyer, Edmond

    THERMODYNAMIC STUDY OF HEAVY METALS BEHAVIOUR DURING MUNICIPAL WASTE INCINERATION Y. ME NARD, A Metallurgie (LSG2M) Nancy, France T he incineration of municipal solid waste (MSW) contributes occurring during waste combustion. Second, results from the bed model were taken as boundary conditions

  7. Heavy Metal Islands | The Ames Laboratory

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cn SunnybankD.jpgHanfordDepartment ofHeat Transfer inoperation inElementHeavy

  8. IMPACT OF HEAVY METALS IN SEWAGE SLUDGE ON SOIL AND PLANTS (COLZA and WHEAT)

    E-Print Network [OSTI]

    Paris-Sud XI, Universit de

    IMPACT OF HEAVY METALS IN SEWAGE SLUDGE ON SOIL AND PLANTS (COLZA and WHEAT) Najla LASSOUED1@emse.fr Abstract We are testing the impact of heavy metals in sludge from urban and industrial wastewater treatment> Cu> Ni> Co> Cd The contents of heavy metals in the sludge is made very high and exceed European

  9. Utilization of a duckweed bioassay to evaluate leaching of heavy metals in smelter contaminated soils

    SciTech Connect (OSTI)

    Youngman, A.L.; Lydy, M.J. [Wichita State Univ., KS (United States). Dept. of Biological Sciences; Williams, T.L. [Laidlaw Environmental Services, Wichita, KS (United States)

    1998-12-31T23:59:59.000Z

    The purpose of this study was to determine whether a duckweed bioassay could be used to evaluate the downward migration of heavy metals in smelter soils. The duckweed bioassay was initially used to evaluate elutriates prepared from samples of smelter soils. These initial tests verified that the elutriates would elicit toxic responses. Elutriate testing was followed with an evaluation of leachate from untreated soil cores or soil cores that had been amended with organic matter either unplanted or planted to a grass-forb seed mixture. There was an inverse linear relationship between heavy-metal concentrations in leachate and NOEC and IC{sub 50} values expressed as percentages among all soil cores. Based on these preliminary duckweed bioassays, there were no differences between soil types or organic amended or non-amended soil, but leachate from vegetated soil cores were less toxic than were leachates from non-vegetated soil cores. Overall, the duckweed bioassays were useful in detecting heavy metal availability in elutriate and leachate samples from smelter soils.

  10. Situ formation of apatite for sequestering radionuclides and heavy metals

    DOE Patents [OSTI]

    Moore, Robert C. (Edgewood, NM)

    2003-07-15T23:59:59.000Z

    Methods for in situ formation in soil of a permeable reactive barrier or zone comprising a phosphate precipitate, such as apatite or hydroxyapatite, which is capable of selectively trapping and removing radionuclides and heavy metal contaminants from the soil, while allowing water or other compounds to pass through. A preparation of a phosphate reagent and a chelated calcium reagent is mixed aboveground and injected into the soil. Subsequently, the chelated calcium reagent biodegrades and slowly releases free calcium. The free calcium reacts with the phosphate reagent to form a phosphate precipitate. Under the proper chemical conditions, apatite or hydroxyapatite can form. Radionuclide and heavy metal contaminants, including lead, strontium, lanthanides, and uranium are then selectively sequestered by sorbing them onto the phosphate precipitate. A reducing agent can be added for reduction and selective sequestration of technetium or selenium contaminants.

  11. Surfactant biocatalyst for remediation of recalcitrant organics and heavy metals

    DOE Patents [OSTI]

    Brigmon, Robin L. (North Augusta, SC); Story, Sandra (Greenville, SC); Altman, Denis J. (Evans, GA); Berry, Christopher J. (Aiken, SC)

    2011-05-03T23:59:59.000Z

    Novel strains of isolated and purified bacteria have been identified which have the ability to degrade petroleum hydrocarbons including a variety of PAHs. Several isolates also exhibit the ability to produce a biosurfactant. The combination of the biosurfactant-producing ability along with the ability to degrade PAHs enhances the efficiency with which PAHs may be degraded. Additionally, the biosurfactant also provides an additional ability to bind heavy metal ions for removal from a soil or aquatic environment.

  12. Surfactant biocatalyst for remediation of recalcitrant organics and heavy metals

    DOE Patents [OSTI]

    Brigmon, Robin L. (North Augusta, SC); Story, Sandra (Greenville, SC); Altman, Denis (Evans, GA); Berry, Christopher J. (Aiken, SC)

    2009-01-06T23:59:59.000Z

    Novel strains of isolated and purified bacteria have been identified which have the ability to degrade petroleum hydrocarbons including a variety of PAHs. Several isolates also exhibit the ability to produce a biosurfactant. The combination of the biosurfactant-producing ability along with the ability to degrade PAHs enhances the efficiency with which PAHs may be degraded. Additionally, the biosurfactant also provides an additional ability to bind heavy metal ions for removal from a soil or aquatic environment.

  13. Surfactant biocatalyst for remediation of recalcitrant organics and heavy metals

    DOE Patents [OSTI]

    Brigmon, Robin L. (North Augusta, SC); Story, Sandra (Greenville, SC); Altman; Denis J. (Evans, GA); Berry, Christopher J. (Aiken, SC)

    2011-03-29T23:59:59.000Z

    Novel strains of isolated and purified bacteria have been identified which have the ability to degrade petroleum hydrocarbons including a variety of PAHs. Several isolates also exhibit the ability to produce a biosurfactant. The combination of the biosurfactant-producing ability along with the ability to degrade PAHs enhances the efficiency with which PAHs may be degraded. Additionally, the biosurfactant also provides an additional ability to bind heavy metal ions for removal from a soil or aquatic environment.

  14. Surfactant biocatalyst for remediation of recalcitrant organics and heavy metals

    DOE Patents [OSTI]

    Brigmon, Robin L. (North Augusta, SC); Story, Sandra (Greenville, SC); Altman, Denis J. (Evans, GA); Berry, Christopher J. (Aiken, SC)

    2011-03-15T23:59:59.000Z

    Novel strains of isolated and purified bacteria have been identified which have the ability to degrade petroleum hydrocarbons including a variety of PAHs. Several isolates also exhibit the ability to produce a biosurfactant. The combination of the biosurfactant-producing ability along with the ability to degrade PAHs enhances the efficiency with which PAHs may be degraded. Additionally, the biosurfactant also provides an additional ability to bind heavy metal ions for removal from a soil or aquatic environment.

  15. Heavy Metal Contamination in the Taimyr Peninsula, Siberian Arctic

    SciTech Connect (OSTI)

    Allen-Gil, Susan M.; Ford, Jesse; Lasorsa, Brenda K.; Monetti, Matthew; Vlasova, Tamara; Landers, Dixon H.

    2003-01-01T23:59:59.000Z

    The Taimyr Peninsula is directly north of the world's largest heavy metal smelting complex (Norilsk, Russia). Despite this proximity, there has been little research to examine the extent of contamination of the Taimyr Peninsula. We analyzed heavy metal concentrations in lichen (Cetraria cucullata), moss (Hylocomium splendens), soils, lake sediment, freshwater fish (Salvelinus alpinus, Lota lota, and Coregonus spp.) and collared lemming (Dicrostonyx torquatus) from 13 sites between 30 and 300 km from Norilsk. Element concentrations were low in both C. cucullata and H. splendens, although concentrations of Al, Fe, Cu, Ni, and Pb were significantly higher than those in Arctic Alaska, probably due to natural differences in the geochemical environments. Inorganic surface soils had significantly higher concentrations of Cd, Zn, Pb, and Mg than inorganic soils at depth, although a lake sediment core from the eastern Taimyr Peninsula indicated no recent enrichment by atmospherically transported elements. Tissue concentrations of heavy metals in fish and lemming were not elevated relative to other Arctic sites. Our results show that the impact of the Norilsk smelting complex is primarily localized rather than regional, and does not extend northward beyond 100 km.

  16. Method of removal of heavy metal from molten salt in IFR fuel pyroprocessing

    DOE Patents [OSTI]

    Gay, Eddie C. (Park Forest, IL)

    1995-01-01T23:59:59.000Z

    An electrochemical method of separating heavy metal values from a radioactive molten salt including Li halide at temperatures of about 500.degree. C. The method comprises positioning a solid Li--Cd alloy anode in the molten salt containing the heavy metal values, positioning a Cd-containing cathode or a solid cathode positioned above a catch crucible in the molten salt to recover the heavy metal values, establishing a voltage drop between the anode and the cathode to deposit material at the cathode to reduce the concentration of heavy metals in the salt, and controlling the deposition rate at the cathode by controlling the current between the anode and cathode.

  17. Attrition resistant catalysts and sorbents based on heavy metal poisoned FCC catalysts

    DOE Patents [OSTI]

    Gangwal, S.; Jothimurugesan, K.

    1999-07-27T23:59:59.000Z

    A heavy metal poisoned, spent FCC catalyst is treated by chemically impregnating the poisoned catalyst with a new catalytic metal or metal salt to provide an attrition resistant catalyst or sorbent for a different catalytic or absorption process, such as catalysts for Fischer-Tropsh Synthesis, and sorbents for removal of sulfur gases from fuel gases and flue-gases. The heavy metal contaminated FCC catalyst is directly used as a support for preparing catalysts having new catalytic properties and sorbents having new sorbent properties, without removing or passivating the heavy metals on the spent FCC catalyst as an intermediate step.

  18. Heavy Metals contamination in two bioluminescent bays of Puerto Rico Yadira Soto Viruet

    E-Print Network [OSTI]

    Gilbes, Fernando

    1 Heavy Metals contamination in two bioluminescent bays of Puerto Rico Yadira Soto Viruet #802 characteristics. The main purpose of this research was to evaluate the presence of heavy metals of pesticides for agriculture, untreated wastewater and variety of industrial activities (power plants, oil

  19. HEAVY METALS IN THE NORTHERN FUR SEAL, CALLORHINUS URSIN US, AND

    E-Print Network [OSTI]

    HEAVY METALS IN THE NORTHERN FUR SEAL, CALLORHINUS URSIN US, AND HARBOR SEAL, PHOCA VITULINA Calillnnia harbor seal and 170 ppm in a fur seal taken oil the Washington coast. Concentrations of cadmium of mercury were from southern California seals. Heavy metals are persistent contaminants that ultimately end

  20. 1529-6466/00/0049-0007$10.00 Quantitative Speciation of Heavy Metals

    E-Print Network [OSTI]

    1529-6466/00/0049-0007$10.00 Quantitative Speciation of Heavy Metals in Soils and Sediments sites, and the major consequence in terms of contamination by heavy metals are areas of wasteland the activities of humans (Smedley and Kinniburgh 2002). Pollution of ground and surface waters, and hence

  1. Heavy-metal toxicity phenomena in laboratory-scale ANFLOW bioreactors

    SciTech Connect (OSTI)

    Rivera, A.L.

    1982-04-01T23:59:59.000Z

    An energy-conserving wastewater treatment system was developed based on an anaerobic, upflow (ANFLOW) bioreactor. Since many applications of the ANFLOW process could involve the treatment of wastewaters containing heavy metals, the potentially toxic effects of these metals on the biological processes occurring in ANFLOW columns (primarily acetogenesis and methanogenesis) were investigated. Both step and pulse inputs of zinc ranging from 100 to 1000 mg/L were added to synthetic wastewaters being treated in ANFLOW columns with 0.057-m/sup 3/ volumes. Column responses were used to develop descriptive models for toxicity phenomena in such systems. It was found that an inhibition function could be defined and used to modify a model based on plugflow with axial dispersion and first-order kinetics for soluble substrate removal. The inhibitory effects of zinc on soluble substrate removal were found to be predominantly associated with its sorption by biosolids. Sorption initially occurred in the lower regions of the column, but was gradually observed in higher regions as the sorption capacity of the lower regions was exhausted. Sorption phenomena could be described with the Freundlich equation. Sorption processes were accompanied by shifts of biological processes to regions higher in the columns. A regenerative process was observed when feeding of wastewaters without zinc was resumed. It was postulated that regeneration could be based on sloughing of layers of biofilms, or other biosolids involved in zinc sorption, followed by continued growth of lower layers of biofilms not involved in heavy-metal sorption.

  2. Portable X-Ray, K-Edge Heavy Metal Detector

    SciTech Connect (OSTI)

    Fricke, V.

    1999-10-25T23:59:59.000Z

    The X-Ray, K-Edge Heavy Metal Detection System was designed and built by Ames Laboratory and the Center for Nondestructive Evaluation at Iowa State University. The system uses a C-frame inspection head with an X-ray tube mounted on one side of the frame and an imaging unit and a high purity germanium detector on the other side. the inspection head is portable and can be easily positioned around ventilation ducts and pipes up to 36 inches in diameter. Wide angle and narrow beam X-ray shots are used to identify the type of holdup material and the amount of the contaminant. Precise assay data can be obtained within minutes of the interrogation. A profile of the containerized holdup material and a permanent record of the measurement are immediately available.

  3. A study of immobilization of four heavy metals by solidification/stabilization with portland cement

    E-Print Network [OSTI]

    Trussell, Susan A

    1994-01-01T23:59:59.000Z

    A STUDY OF IMMOBILIZATION OF FOUR HEAUY METALS BY SOLIDIFICATION/STABILIZATION WITH PORTLAND CEMEhK A Thesis by SUSAN ANN TRUSSELL Submitted to Texas AdcM University in partial fulfillment of the requirements for the degree of MASTER... of Immobilization of Four Heavy Metals By Solidification/Stabilization with Portland Cement. (May 1994) Susan Trussell, B. S. , Baylor University; M. A. , Texas ARM University Chair of Advisory Committee: Dr. Bill Batchelor Immobilization of four heavy metals...

  4. Heavy metals and lead isotopes in sdB stars

    E-Print Network [OSTI]

    S. O'Toole; U. Heber

    2006-12-19T23:59:59.000Z

    We present a detailed abundance analysis of high-resolution ultraviolet echelle spectra of five subdwarf B stars obtained with HST-STIS The goal of our observations was to test the hypothesis that pulsations in sdBs are correlated to the surface abundances of iron-group elements. We study two pulsators and three non-pulsators and determined abundances for 25 elements including the iron group and even heavier elements such as tin and lead using LTE spectrum synthesis techniques. We find strong enrichments of heavy elements up to 2.9dex with respect to solar which are probably caused by atomic diffusion processes. No clear-cut correlation between pulsations and metal abundances becomes apparent. Abundances for lead isotopes are derived from very high resolution spectra using an UV line of triply ionised lead. As Pb terminates the s-process sequence Pb isotopic abundance ratios yield important constraints. It is very difficult to measure them in hot stars. For the first time we were able to measure them in two subluminous B stars and conclude that the 207Pb/208Pb is solar.

  5. Method of removal of heavy metal from molten salt in IFR fuel pyroprocessing

    DOE Patents [OSTI]

    Gay, E.C.

    1995-10-03T23:59:59.000Z

    An electrochemical method is described for separating heavy metal values from a radioactive molten salt including Li halide at temperatures of about 500 C. The method comprises positioning a solid Li--Cd alloy anode in the molten salt containing the heavy metal values, positioning a Cd-containing cathode or a solid cathode positioned above a catch crucible in the molten salt to recover the heavy metal values, establishing a voltage drop between the anode and the cathode to deposit material at the cathode to reduce the concentration of heavy metals in the salt, and controlling the deposition rate at the cathode by controlling the current between the anode and cathode. 3 figs.

  6. Lichens as bioindicators of aerial fallout of heavy metals in Zaria, Nigeria

    SciTech Connect (OSTI)

    Kapu, M.M. (Univ. of Illinois, Urbana (United States) Ahmadu Bello Univ., Zaria (Nigeria)); Ipaye, M.M.; Ega, R.A.I.; Balarabe, M.L. (Ahmadu Bello Univ., Zaria (Nigeria)); Akanya, H.O. (Federal Univ. of Technology, Minna (Nigeria)); Schaeffer, D.J. (Univ. of Illinois, Urbana (United States))

    1991-09-01T23:59:59.000Z

    Lichens and other epiphytic cryptogams possess efficient ion-exchange mechanisms which enable many species to accumulate airborne metals and which probably contribute to their tolerating metals at concentrations high enough to cause death to other plant species. A direct relationship between the distribution pattern of lichens and the trace metal content of the surrounding air has been demonstrated. The present study used lichens to assess the aerial fallout of heavy metals from traffic in Zaria, northern Nigeria.

  7. ANALYSIS OF THE ELECTRON EXCITATION SPECTRA IN HEAVY RARE EARTH METALS, HYDRIDES AND OXIDES

    E-Print Network [OSTI]

    Boyer, Edmond

    397 ANALYSIS OF THE ELECTRON EXCITATION SPECTRA IN HEAVY RARE EARTH METALS, HYDRIDES AND OXIDES C thin evaporated foils of heavy rare earths (Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu) in three different chemical of high energy incident electrons (75 keV) transmitted through thin foils of yttric rare earth elements

  8. Silica coated magnetite nanoparticles for removal of heavy metal ions from polluted waters

    E-Print Network [OSTI]

    Dash, Monika

    2013-01-01T23:59:59.000Z

    Magnetic removal of Hg2+ and other heavy metal ions like Cd2+, Pb2+ etc. using silica coated magnetite particles from polluted waters is a current topic of active research to provide efficient water recycling and long term high quality water. The technique used to study the bonding characteristics of such kind of nanoparticles with the heavy metal ions is a very sensitive hyperfine specroscopy technique called the perturbed angular correlation technique (PAC).

  9. Enrichment of Heavy Metals in Sediment Resulting from Soil

    E-Print Network [OSTI]

    Quinton, John

    agrochemicals has enriched sediment metal concentrations to toxic levels which breach many accepted standards

  10. Using stable lead isotopes to trace heavy metal contamination sources in sediments of Xiangjiang and Lishui Rivers in China

    E-Print Network [OSTI]

    Hu, Qinhong "Max"

    Using stable lead isotopes to trace heavy metal contamination sources in sediments of Xiangjiang higher than natural values, suggesting the contaminations of heavy metals from extensive ore such as Hunan province is rich in mineral resources including non-ferrous metals (Zaw et al., 2007). Many kinds

  11. Method for fixating sludges and soils contaminated with mercury and other heavy metals

    DOE Patents [OSTI]

    Broderick, Thomas E.; Roth, Rachel L.; Carlson, Allan L.

    2005-06-28T23:59:59.000Z

    The invention relates to a method, composition and apparatus for stabilizing mercury and other heavy metals present in a particulate material such that the metals will not leach from the particulate material. The method generally involves the application of a metal reagent, a sulfur-containing compound, and the addition of oxygen to the particulate material, either through agitation, sparging or the addition of an oxygen-containing compound.

  12. Process for the enhanced capture of heavy metal emissions

    DOE Patents [OSTI]

    Biswas, Pratim (Chesterfield, MO); Wu, Chang-Yu (Gainsville, FL)

    2001-01-01T23:59:59.000Z

    This invention is directed to a process for forming a sorbent-metal complex. The process includes oxidizing a sorbent precursor and contacting the sorbent precursor with a metallic species. The process further includes chemically reacting the sorbent precursor and the metallic species, thereby forming a sorbent-metal complex. In one particular aspect of the invention, at least a portion of the sorbent precursor is transformed into sorbent particles during the oxidation step. These sorbent particles then are contacted with the metallic species and chemically reacted with the metallic species, thereby forming a sorbent-metal complex. Another aspect of the invention is directed to a process for forming a sorbent metal complex in a combustion system. The process includes introducing a sorbent precursor into a combustion system and subjecting the sorbent precursor to an elevated temperature sufficient to oxidize the sorbent precursor and transform the sorbent precursor into sorbent particles. The process further includes contacting the sorbent particles with a metallic species and exposing the sorbent particles and the metallic species to a complex-forming temperature whereby the metallic species reacts with the sorbent particles thereby forming a sorbent-metal complex under UV irradiation.

  13. A Liquid Metal PMI/PFC Initiative ! R. Maingi, on behalf of

    E-Print Network [OSTI]

    A Liquid Metal PMI/PFC Initiative ! R. Maingi, on behalf of a Liquid Metal PFC Working Group FESAC a number of challenges; focal area of worldwide PMI program 3 Accepted heat flux exhaust limit for W is 5

  14. A review of the global emissions, transport and effects of heavy metals in the environment

    SciTech Connect (OSTI)

    Friedman, J.R.; Ashton, W.B.; Rapoport, R.D.

    1993-06-01T23:59:59.000Z

    The purpose of this report is to describe the current state of knowledge regarding the sources and quantities of heavy metal emissions, their transport and fate, their potential health and environmental effects, and strategies to control them. The approach is to review the literature on this topic and to consult with experts in the field. Ongoing research activities and research needs are discussed. Estimates of global anthropogenic and natural emissions indicate that anthropogenic emissions are responsible for most of the heavy metals released into the atmosphere and that industrial activities have had a significant impact on the global cycling of trace metals. The largest anthropogenic sources of trace metals are coal combustion and the nonferrous metal industry. Atmospheric deposition is an important pathway by which trace metals enter the environment. Atmospheric deposition varies according to the solubility of the element and the length of time it resides in the atmosphere. Evidence suggests that deposition is influenced by other chemicals in the atmosphere, such as ozone and sulfur dioxide. Trace metals also enter the environment through leaching. Existing emissions-control technologies such as electrostatic precipitators, baghouses, and scrubbers are designed to remove other particulates from the flue gas of coal-fired power plants and are only partially effective at removing heavy metals. Emerging technologies such as flue gas desulfurization, lignite coke, and fluidized bed combustion could further reduce emissions. 108 refs.

  15. Relationship between meteorological variables and total suspended and heavy metal particulates in Little Rock, Arkansas

    E-Print Network [OSTI]

    Avery, Mary Gwendolyn

    1985-01-01T23:59:59.000Z

    RELATIONSHIP BETWEEN METEOROLOGICAL VARIABLES AND TOTAL SUSPENDED AND HEAVY NFXAL PARTICULATES IN LITTLE ROCK, ARKANSAS A Thesis MARY GWENDOLl'N AVERY Submitted to the Graduate College of Texas ALM University in partial fulfillment... of the requirements for the degree of MASTER OF SCIENCE May 1985 Major Subject: Meteorology RELATIONSHIP BETWEEN METEOROLOGICAL VARIABLES AND TOTAL SUSPENDED AND HEAVY METAL PARTICULATES IN LITTLE ROCK, ARKANSAS A Thesis MARY GWENDOLYN AVERY Approved...

  16. AMOUNT AND LEACHING POTENTIAL OF HEAVY METALS IN BARK MULCH AND COMPOST USED ON THE UNIVERSITY OF

    E-Print Network [OSTI]

    AMOUNT AND LEACHING POTENTIAL OF HEAVY METALS IN BARK MULCH AND COMPOST USED ON THE UNIVERSITY mulch and compost, determine whether or not either of these substances could be significant contributors the presence of heavy metals in fresh bark mulch, soil (used in compost mixtures) and compost being used at UBC

  17. Heavy metal distribution in sediments from Calabar River, southeastern Nigeria

    SciTech Connect (OSTI)

    Ntekim, E.E.U.; Ekwere, S.J.; Ukpong, E.E. [Univ. of Calabar (Nigeria)

    1993-08-01T23:59:59.000Z

    The concentration and areal distribution of selected metals (Pb, Zn, Cu, Cd, Ni, Fe, and Cr) in the sediments of the Calabar River were studied to determine the extent of anthropogenic input and to estimate the effects of dumping industrial waste materials into the river. The concentrations of Pb, Zn, and Cu indicate relatively moderate pollution mainly on the left-hand side of the river while Ni, Cr, Co, Cd, and Fe levels are below values found to have adverse effects on the lives of marine biota. High metal contents are found close to industrial establishments and so enhanced metal concentrations are related to industrial sewage and metal leaching from garbage and solid waste dumps. 15 refs., 6 figs., 5 tabs.

  18. Plasma treatment of INEL soil contaminated with heavy metals

    SciTech Connect (OSTI)

    Detering, B.A.; Batdorf, J.A.

    1992-01-01T23:59:59.000Z

    INEL soil spiked with inorganic salts of chromium, lead, mercury, silver, and zinc was melted in a 150 kW plasma furnace to produce a glassy slag product. This glassy slag is an environmentally safe waste form. In order to reduce the melting temperature of the soil, sodium carbonate was added to half of the test batches. Random sample from each batch of glassy slag product were analyzed by an independent laboratory for total metals concentration and leachability of metals via the Environmental Protection Agency (EPA) toxicity characterization leaching procedure (RCLP) tests. These tests showed the residual metals were very tightly bound to the slag matrix and were within EPA TCLP limits under these test conditions. Additionally, scanning electron microscopy (SEM) and emissions dispersive spectroscopy (EDS) analysis of the vitrified soil also confirmed that the added metals present in the vitrified soil were totally contained in the crystalline phase as distinct oxide crystallites.

  19. Supercritical Fluid Extraction of Actinides and Heavy Metals for Environmental Cleanup: A Process Development Perspective

    SciTech Connect (OSTI)

    Lin, Yuehe; Smart, Neil G.; A. S. Gopalan, C. M. Wai, and H. K. Jacobs

    2003-08-30T23:59:59.000Z

    The extraction of heavy metal ions and actinide ions is demonstrated using supercritical carbon dioxide (CO2) containing dissolved protonated ligands, such as diketones and organophosphinic acids. High efficiency extraction is observed. The mechanism of the extraction reaction is discussed and, in particular, the effect of addition of water to the sample matrix is highlighted. In-process dissociation of metal-ligand complexes for ligand regeneration and recycle is also discussed. A general concept for a process using this technology is outlined.

  20. Metallomics of two microorganisms relevant to heavy metal bioremediation reveal fundamental differences in metal assimilation and utilization

    SciTech Connect (OSTI)

    Lancaster, Andrew [University of Georgia, Athens, GA] [University of Georgia, Athens, GA; Menon, Angeli [University of Georgia, Athens, GA] [University of Georgia, Athens, GA; Scott, Israel [University of Georgia, Athens, GA] [University of Georgia, Athens, GA; Poole, Farris [University of Georgia, Athens, GA] [University of Georgia, Athens, GA; Vaccaro, Brian [University of Georgia, Athens, GA] [University of Georgia, Athens, GA; Thorgersen, Michael P [ORNL] [ORNL; Geller, Jil [Lawrence Berkeley National Laboratory (LBNL)] [Lawrence Berkeley National Laboratory (LBNL); Hazen, Terry C [ORNL] [ORNL; Hurt, Jr., Richard Ashley [ORNL; Brown, Steven D [ORNL] [ORNL; Elias, Dwayne A [ORNL] [ORNL; Adams, Michael W. W. [University of Georgia, Athens, GA] [University of Georgia, Athens, GA

    2014-01-01T23:59:59.000Z

    Although as many as half of all proteins are thought to require a metal cofactor, the metalloproteomes of microorganisms remain relatively unexplored. Microorganisms from different environments are likely to vary greatly in the metals that they assimilate, not just among the metals with well-characterized roles but also those lacking any known function. Herein we investigated the metal utilization of two microorganisms that were isolated from very similar environments and are of interest because of potential roles in the immobilization of heavy metals, such as uranium and chromium. The metals assimilated and their concentrations in the cytoplasm of Desulfovibrio vulgaris strain Hildenborough (DvH) and Enterobacter cloacae strain Hanford (EcH) varied dramatically, with a larger number of metals present in Enterobacter. For example, a total of 9 and 19 metals were assimilated into their cytoplasmic fractions, respectively, and DvH did not assimilate significant amounts of zinc or copper whereas EcH assimilated both. However, bioinformatic analysis of their genome sequences revealed a comparable number of predicted metalloproteins, 813 in DvH and 953 in EcH. These allowed some rationalization of the types of metal assimilated in some cases (Fe, Cu, Mo, W, V) but not in others (Zn, Nd, Ce, Pr, Dy, Hf and Th). It was also shown that U binds an unknown soluble protein in EcH but this incorporation was the result of extracellular U binding to cytoplasmic components after cell lysis.

  1. Initialization of hydrodynamics in relativistic heavy ion collisions with an energy-momentum transport model

    E-Print Network [OSTI]

    V. Yu. Naboka; S. V. Akkelin; Iu. A. Karpenko; Yu. M. Sinyukov

    2015-01-14T23:59:59.000Z

    A key ingredient of hydrodynamical modeling of relativistic heavy ion collisions is thermal initial conditions, an input that is the consequence of a pre-thermal dynamics which is not completely understood yet. In the paper we employ a recently developed energy-momentum transport model of the pre-thermal stage to study influence of the alternative initial states in nucleus-nucleus collisions on flow and energy density distributions of the matter at the starting time of hydrodynamics. In particular, the dependence of the results on isotropic and anisotropic initial states is analyzed. It is found that at the thermalization time the transverse flow is larger and the maximal energy density is higher for the longitudinally squeezed initial momentum distributions. The results are also sensitive to the relaxation time parameter, equation of state at the thermalization time, and transverse profile of initial energy density distribution: Gaussian approximation, Glauber Monte Carlo profiles, etc. Also, test results ensure that the numerical code based on the energy-momentum transport model is capable of providing both averaged and fluctuating initial conditions for the hydrodynamic simulations of relativistic nuclear collisions.

  2. Characterization of sperm motility in sea bass: the effect of heavy metals and physicochemical

    E-Print Network [OSTI]

    Villefranche sur mer

    to sperm motility in several fish species, including sea bass Dicentrarchus labrax (L.) (Fauvel et alCharacterization of sperm motility in sea bass: the effect of heavy metals and physicochemical) was used to characterize the motility of sea bass Dicentrarchus labrax spermatozoa and to study the effect

  3. ADVANCES IN BIOSORPTION OF HEAVY METALS David Kratochvil and Bohumil Volesky

    E-Print Network [OSTI]

    Volesky, Bohumil

    exchange, and precipitation with bio- sulphide (H2S produced by sulfate-reducing bacteria), the biosorption dead biomass to sequester toxic heavy metals. It is particularly feasible to use for removal then be packed in sorption columns which are perhaps the most effective device for the continuous removal

  4. Heavy Metals in the Environment Effect of Biosolids Processing on Lead Bioavailability in an Urban Soil

    E-Print Network [OSTI]

    Brown, Sally

    Heavy Metals in the Environment Effect of Biosolids Processing on Lead Bioavailability in an Urban for biosolids products to reduce Pb availability in both in a soil matrix and as pure minerals, can altersoil was tested on a high Pb urban soil with biosolids from a treatment plant that used different processing

  5. Heavy-Section Steel Technology Program: Recent developments in crack initiation and arrest research

    SciTech Connect (OSTI)

    Pennell, W.E.

    1991-01-01T23:59:59.000Z

    Technology for the analysis of crack initiation and arrest is central to the reactor pressure vessel fracture-margin-assessment process. Regulatory procedures for nuclear plants utilize this technology to assure the retention of adequate fracture-prevention margins throughout the plant operating license period. As nuclear plants age and regulatory procedures dictate that fracture-margin assessments be performed, interest in the fracture-mechanics technology incorporated into those procedures has heightened. This has led to proposals from a number of sources for development and refinement of the underlying crack-initiation and arrest-analysis technology. This paper presents an overview of ongoing Heavy-Section Steel Technology (HSST) Program research aimed at refining the fracture toughness data used in the analysis of fracture margins under pressurized-thermal-shock loading conditions. 33 refs., 13 figs.

  6. Removal of heavy metal ions from oil shale beneficiation process water by ferrite process

    SciTech Connect (OSTI)

    Mehta, R.K.; Zhang, L.; Lamont, W.E.; Schultz, C.W. (Alabama Univ., University, AL (United States). Mineral Resources Inst.)

    1991-01-01T23:59:59.000Z

    The ferrite process is an established technique for removing heavy metals from waste water. Because the process water resulting from oil shale beneficiation falls into the category of industrial waste water, it is anticipated that this process may turn out to be a potential viable treatment for oil shale beneficiation process water containing many heave metal ions. The process is chemoremedial because not only effluent water comply with quality standards, but harmful heavy metals are converted into a valuable, chemically stable by-product known as ferrite. These spinel ferrites have magnetic properties, and therefore can be use in applications such as magnetic marker, ferrofluid, microwave absorbing and scavenging material. Experimental results from this process are presented along with results of treatment technique such as sulfide precipitation.

  7. Removal of heavy metal ions from oil shale beneficiation process water by ferrite process

    SciTech Connect (OSTI)

    Mehta, R.K.; Zhang, L.; Lamont, W.E.; Schultz, C.W. [Alabama Univ., University, AL (United States). Mineral Resources Inst.

    1991-12-31T23:59:59.000Z

    The ferrite process is an established technique for removing heavy metals from waste water. Because the process water resulting from oil shale beneficiation falls into the category of industrial waste water, it is anticipated that this process may turn out to be a potential viable treatment for oil shale beneficiation process water containing many heave metal ions. The process is chemoremedial because not only effluent water comply with quality standards, but harmful heavy metals are converted into a valuable, chemically stable by-product known as ferrite. These spinel ferrites have magnetic properties, and therefore can be use in applications such as magnetic marker, ferrofluid, microwave absorbing and scavenging material. Experimental results from this process are presented along with results of treatment technique such as sulfide precipitation.

  8. Modeling of heavy metal transport in a contaminated soil

    SciTech Connect (OSTI)

    Cernik, M.; Federer, P.; Borkovec, M.; Sticher, H. [Inst. of Terrestrial Ecology, Schlieren (Switzerland)

    1994-11-01T23:59:59.000Z

    Observed depth profiles in soils polluted by Zn and Cu that originate from a metal smelter are quantitatively interpreted by combining the production history of the smelter with established transport models. Using independent laboratory and field data, we were able to calculate the present depth profiles semiquantitatively by applying the pure convection model without parameter fitting. The agreement of the calculated depth profiles with the experimental data can be improved by including dispersion effects in the convection-dispersion model or the stochastic convection model. For the latter model, the depth profiles were calculated analytically. These models were used to calculate the expected depth profiles in the future and to judge possible remediation strategies. 48 refs., 12 figs., 1 tab.

  9. Zwitterionic Group VIII transition metal initiators supported by olefin ligands

    DOE Patents [OSTI]

    Bazan, Guillermo C. (Goleta, CA); Chen, Yaofeng (Shanghai, CN)

    2011-10-25T23:59:59.000Z

    A zwitterionic Group VIII transition metal complex containing the simple and relatively small 3-(arylimino)-but-1-en-2-olato ligand that catalyzes the formation of polypropylene and high molecular weight polyethylene. A novel feature of this catalyst is that the active species is stabilized by a chelated olefin adduct. The present invention also provides methods of polymerizing olefin monomers using zwitterionic catalysts, particularly polypropylene and high molecular weight polyethylene.

  10. Heavy-metal contamination on training ranges at the Grafenwoehr Training Area, Germany

    SciTech Connect (OSTI)

    Zellmer, S.D.; Schneider, J.F.

    1993-05-01T23:59:59.000Z

    Large quantities of lead and other heavy metals are deposited in the environment of weapons ranges during training exercises. This study was conducted to determine the type, degree, and extent of heavy-metal contamination on selected handgun, rifle, and hand-grenade ranges at Grafenwoehr Training Area, Germany. Soil, vegetation, and surface-water samples were collected and analyzed using the inductively-coupled plasma atomic-emission spectroscopy (ICP-AES) method and the toxic characterization leaching procedure (TCLP). The ICP-AES results show that above-normal levels of lead and copper are in the surface soil at the handgun range, high concentrations of lead and copper are in the berm and soil surface at the rifle range, and elevated levels of cadmium and above-normal concentrations of arsenic, copper, and zinc are present in the surface soil at the hand-grenade range. The TCLP results show that surface soils can be considered hazardous waste because of lead content at the rifle range and because of cadmium concentration at the hand-grenade range. Vegetation at the handgun and rifle ranges has above-normal concentrations of lead. At the hand-grenade range, both vegetation and surface water have high levels of cadmium. A hand-held X-ray fluorescence (XRF) spectrum analyzer was used to measure lead concentrations in soils in a field test of the method. Comparison of XRF readings with ICP-AES results for lead indicate that the accuracy and precision of the hand-held XRF unit must improve before the unit can be used as more than a screening tool. Results of this study show that heavy-metal contamination at all three ranges is limited to the surface soil; heavy metals are not being leached into the soil profile or transported into adjacent areas.

  11. Removal of radioactive materials and heavy metals from water using magnetic resin

    DOE Patents [OSTI]

    Kochen, Robert L. (Boulder, CO); Navratil, James D. (Simi Valley, CA)

    1997-01-21T23:59:59.000Z

    Magnetic polymer resins capable of efficient removal of actinides and heavy metals from contaminated water are disclosed together with methods for making, using, and regenerating them. The resins comprise polyamine-epichlorohydrin resin beads with ferrites attached to the surfaces of the beads. Markedly improved water decontamination is demonstrated using these magnetic polymer resins of the invention in the presence of a magnetic field, as compared with water decontamination methods employing ordinary ion exchange resins or ferrites taken separately.

  12. Removal of radioactive materials and heavy metals from water using magnetic resin

    DOE Patents [OSTI]

    Kochen, R.L.; Navratil, J.D.

    1997-01-21T23:59:59.000Z

    Magnetic polymer resins capable of efficient removal of actinides and heavy metals from contaminated water are disclosed together with methods for making, using, and regenerating them. The resins comprise polyamine-epichlorohydrin resin beads with ferrites attached to the surfaces of the beads. Markedly improved water decontamination is demonstrated using these magnetic polymer resins of the invention in the presence of a magnetic field, as compared with water decontamination methods employing ordinary ion exchange resins or ferrites taken separately. 9 figs.

  13. Uranium and other heavy metals in soil and vegetation from the Hanford environs

    SciTech Connect (OSTI)

    Price, K.R.; Kinnison, R.R.

    1982-11-01T23:59:59.000Z

    Strong winds that could transport contaminated dust and other materials offsite from the Hanford 300 Area typically blow from the west or southwest. Samples were collected from an offsite study area located across the Columbia River and downwind from the 300 Area to estimate the concentrations of uranium and other heavy metals in soils and vegetation. Results were compared to similar measurements collected at control sites located both on and off the Hanford Site. These comparisons were used to test hypotheses that uranium and other heavy metals had been transported offsite by wind-blown dust or other materials. The conclusion from this study was that operations at the 300 Area have not resulted in a detectable impact on the offsite environs across the river. The concentration of uranium in soil samples from the study area was statistically greater than comparable samples from control sites, but there was no evidence that the uranium in the study-area samples was other than naturally occurring. There was no statistical difference in the concentration of lead, silver, zinc or copper in soil samples from the study area as compared to the control sites. No statistically significant differences in uranium or other heavy metals were noted among vegetation samples from the various sampling sites.

  14. Heavy metal inventory and fuel sustainability of recycling TRU in FBR design

    SciTech Connect (OSTI)

    Permana, Sidik; Suzuki, Mitsutoshi; Su'ud, Zaki [Department of Science and Technology for Nuclear Material Management (STNM), Japan Atomic Energy Agency (JAEA), 2-4 Shirane, Shirakata, Tokai Mura, Naka-gun, Ibaraki 319-1195 Nuclear Physics and Bio (Indonesia); Department of Science and Technology for Nuclear Material Management (STNM), Japan Atomic Energy Agency (JAEA), 2-4 Shirane, Shirakata, Tokai Mura, Naka-gun, Ibaraki 319-1195 (Japan); Nuclear Physics and Bio Physics Research Group, Department of Physics, Bandung Institute of Technology, Gedung Fisika, Jl. Ganesha 10, Bandung 40132 (Indonesia)

    2012-06-06T23:59:59.000Z

    Nuclear fuel materials from spent fuel of light water reactors have a potential to be used for destructive devices with very huge energy release or in the same time, it can be utilized as a peaceful energy or civil applications, for generating electricity, desalination of water, medical application and others applications. Several research activities showed some recycled spent fuel can be used as additional fuel loading for increasing fuel breeding capability as well as improving intrinsic aspect of nuclear non-proliferation. The present investigation intends to evaluate the composition of heavy metals inventories and fuel breeding capability in the FBR design based on the loaded fuel of light water reactor (LWR) spent fuel (SF) of 33 GWd/t with 5 years cooling time by adopting depletion code of ORIGEN. Whole core analysis of FBR design is performed by adopting and coupling codes such as SLAROM code, JOINT and CITATION codes. Nuclear data library, JFS-3-J-3.2R which is based on the JENDL 3.2 has been used for nuclear data analysis. JSFR design is the basis design reference which basically adopted 800 days cycle length for 4 batches system. Higher inventories of plutonium of MOX fuel and TRU fuel types at equilibrium composition than initial composition have been shown. Minor actinide (MA) inventory compositions obtain a different inventory trends at equilibrium composition for both fuel types. Higher Inventory of MA is obtained by MOX fuel and less MA inventory for TRU fuel at equilibrium composition than initial composition. Some different MA inventories can be estimated from the different inventory trend of americium (Am). Higher americium inventory for MOX fuel and less americium inventory for TRU fuel at equilibrium condition. Breeding ratio of TRU fuel is relatively higher compared with MOX fuel type. It can be estimated from relatively higher production of Pu-238 (through converted MA) in TRU fuel, and Pu-238 converts through neutron capture to produce Pu-239. Higher breeding ratio of MOX fuel and TRU fuel types at equilibrium condition are estimated from converted fertile material during reactor operation into fissile material of plutonium such as converted uranium fuel (converted U-238 into Pu-239) or additional converted fuel from MA into Pu-238 and changes into Pu-239 by capturing neutron. Loading LWR SF gives better fuel breeding capability and increase inventory of MA for doping material of MOX fuel; however, it requires more supply MA inventory for TRU fuel type.

  15. Mobility of Source Zone Heavy Metals and Radionuclides: The Mixed Roles of Fermentative Activity on Fate and Transport of U and Cr. Final Report

    SciTech Connect (OSTI)

    Gerlach, Robin [Montana State Univ., Bozeman, MT (United States); Peyton, Brent M. [Montana State Univ., Bozeman, MT (United States); Apel, William A. [Idaho National Lab., Idaho Falls, ID (United States)

    2014-01-29T23:59:59.000Z

    Various U. S. Department of Energy (DOE) low and medium-level radioactive waste sites contain mixtures of heavy metals, radionuclides and assorted organic materials. In addition, there are numerous sites around the world that are contaminated with a mixture of organic and inorganic contaminants. In most sites, over time, water infiltrates the wastes, and releases metals, radionuclides and other contaminants causing transport into the surrounding environment. We investigated the role of fermentative microorganisms in such sites that may control metal, radionuclide and organics migration from source zones. The project was initiated based on the following overarching hypothesis: Metals, radionuclides and other contaminants can be mobilized by infiltration of water into waste storage sites. Microbial communities of lignocellulose degrading and fermenting microorganisms present in the subsurface of contaminated DOE sites can significantly impact migration by directly reducing and immobilizing metals and radionuclides while degrading complex organic matter to low molecular weight organic compounds. These low molecular weight organic acids and alcohols can increase metal and radionuclide mobility by chelation (i.e., certain organic acids) or decrease mobility by stimulating respiratory metal reducing microorganisms. We demonstrated that fermentative organisms capable of affecting the fate of Cr6+, U6+ and trinitrotoluene can be isolated from organic-rich low level waste sites as well as from less organic rich subsurface environments. The mechanisms, pathways and extent of contaminant transformation depend on a variety of factors related to the type of organisms present, the aqueous chemistry as well as the geochemistry and mineralogy. This work provides observations and quantitative data across multiple scales that identify and predict the coupled effects of fermentative carbon and electron flow on the transport of radionuclides, heavy metals and organic contaminants in the subsurface; a primary concern of the DOE Environmental Remediation Science Division (ERSD) and Subsurface Geochemical Research (SBR) Program.

  16. Heavy Metal Immobilization Through Phosphate and Thermal Treatment of Dredged Sediments

    SciTech Connect (OSTI)

    Ndiba,P.; Axe, L.; Boonfueng, T.

    2008-01-01T23:59:59.000Z

    Disposal of dredged sediments is expensive and poses a major challenge for harbor dredging projects. Therefore beneficial reuse of these sediments as construction material is highly desirable assuming contaminants such as heavy metals are immobilized and organics are mineralized. In this research, the effect of the addition of 2.5% phosphate, followed by thermal treatment at 700 C, was investigated for metal contaminants in dredged sediments. Specifically, Zn speciation was evaluated, using X-ray absorption spectroscopy (XAS), by applying principal component analysis (PCA), target transformation (TT), and linear combination fit (LCF) to identify the main phases and their combination from an array of reference compounds. In dredged sediments, Zn was present as smithsonite (67%) and adsorbed to hydrous manganese oxides (18%) and hydrous iron oxides (15%). Phosphate addition resulted in precipitation of hopeite (22%), while calcination induced formation of spinels, gahnite (44%), and franklinite (34%). Although calcination was previously used to agglomerate phosphate phases by sintering, we found that it formed sparingly soluble Zn phases. Results from the U.S. EPA toxicity characteristic leaching procedure (TCLP) confirmed both phosphate addition and calcination reduced leachability of heavy metals with the combined treatment achieving up to an 89% reduction.

  17. INITIAL CHARACTERIZATION AND PERFORMANCE EVALUATION OF A ZIRCONIUM-BASED METALLIC WASTE FORM

    SciTech Connect (OSTI)

    Kane, M; Robert Sindelar, R

    2008-09-30T23:59:59.000Z

    A metallic waste form or alloy system for immobilization of Zircaloy cladding hulls, Undissolved Solids (UDS), Technicium (Tc) metal and Transition Metal Fission Products (TMFP) waste stream materials from separations processes for commercial spent nuclear fuel has been developed, and initial characterization of the phase assemblage and composition, and corrosion testing under aqueous conditions has been completed for the waste form with various levels of surrogate waste species. The waste stream materials are those from processes being developed as part of the Separations Campaign under the Department of Energy's (DOE's) Global Nuclear Energy Partnership (GNEP) program. The development of waste forms for these materials is under the Waste Form Campaign.

  18. Heavy Metals Contaminated Soil Project, Resource Recovery Project, and Dynamic Underground Stripping Project

    SciTech Connect (OSTI)

    Not Available

    1994-02-01T23:59:59.000Z

    The Department of Energy (DOE) established the Office of Technology Development (EM-50) (OTD) as an element of Environmental Restoration and Waste Management (EM) in November, 1989. OTD has begun to search out, develop, test and demonstrate technologies that can now or in the future be applied to the enormous remediation problem now facing the DOE and the United States public in general. Technology demonstration projects have been designed to attack a separate problem as defined by DOE. The Heavy Metals Contaminated Soil Project was conceived to test and demonstrate off-the-shelf technologies (dominantly from the mining industry) that can be brought to bear on the problem of radionuclide and heavy metal contamination in soils and sediments. The Resource Recovery Project is tasked with identifying, developing, testing, and evaluating new and innovative technologies for the remediation of metal contaminated surface and groundwater. An innovative twist on this project is the stated goal of recovering the metals, formerly disposed of as a waste, for reuse and resale, thereby transforming them into a usable resource. Finally, the Dynamic Underground Stripping Project was developed to demonstrate and remediate underground spills of hydrocarbons from formations that are (1) too deep for excavation, and/or (2) require in-situ remediation efforts of long duration. This project has already been shown effective in reducing the time for remediation by conventional methods from an estimated 200 years at the Lawrence Livermore National Laboratory (LLNL) to less than one year. The savings in time and dollars from this technology alone can be immeasurable.

  19. Determination of heavy metals and halogens in plastics from electric and electronic waste

    SciTech Connect (OSTI)

    Dimitrakakis, Emmanouil [Laboratory of Toxic and Hazardous Waste Management, Department of Environmental Engineering, Technical University of Crete, University Campus, 73100 Chania (Greece); Janz, Alexander; Bilitewski, Bernd [Institute for Waste Management and Contaminated Site Treatment, Dresden University of Technology, Pratzschwitzerstrasse 15, 01796 Pirna (Germany); Gidarakos, Evangelos [Laboratory of Toxic and Hazardous Waste Management, Department of Environmental Engineering, Technical University of Crete, University Campus, 73100 Chania (Greece)], E-mail: gidarako@mred.tuc.gr

    2009-10-15T23:59:59.000Z

    The presence of hazardous substances and preparations in small waste electrical and electronic equipment (sWEEE) found in the residual household waste stream of the city of Dresden, Germany has been investigated. The content of sWEEE plastics in heavy metals and halogens is determined using handheld X-ray fluorescence analysis (HXRF), elemental analysis by means of atomic absorption spectrometry (AAS) and ion exchange chromatography (IEC). Mean value of results for heavy metals in samples (n = 51) by AAS are 17.4 mg/kg for Pb, 5.7 mg/kg for Cd, 8.4 mg/kg for Cr. The mass fraction of an additive as shown by HXRF (n = 161) can vary over a wide range. Precise deductions as regards sWEEE plastics content in hazardous substances and preparations cannot be made. Additional research would be expedient regarding the influence of hazardous substances to recycling processes, in particular regarding the contamination of clean fractions in the exit streams of a WEEE treatment plant. Suitable standards for calibrating HXRF for use on EEE plastics or complex electr(on)ic components do not exist and should be developed.

  20. Metagenomic insights into evolution of heavy metal-contaminated groundwater microbial community

    SciTech Connect (OSTI)

    Hemme, C.L.; Deng, Y.; Gentry, T.J.; Fields, M.W.; Wu, L.; Barua, S.; Barry, K.; Green-Tringe, S.; Watson, D.B.; He, Z.; Hazen, T.C.; Tiedje, J.M.; Rubin, E.M.; Zhou, J.

    2010-07-01T23:59:59.000Z

    Understanding adaptation of biological communities to environmental change is a central issue in ecology and evolution. Metagenomic analysis of a stressed groundwater microbial community reveals that prolonged exposure to high concentrations of heavy metals, nitric acid and organic solvents ({approx}50 years) has resulted in a massive decrease in species and allelic diversity as well as a significant loss of metabolic diversity. Although the surviving microbial community possesses all metabolic pathways necessary for survival and growth in such an extreme environment, its structure is very simple, primarily composed of clonal denitrifying {gamma}- and {beta}-proteobacterial populations. The resulting community is overabundant in key genes conferring resistance to specific stresses including nitrate, heavy metals and acetone. Evolutionary analysis indicates that lateral gene transfer could have a key function in rapid response and adaptation to environmental contamination. The results presented in this study have important implications in understanding, assessing and predicting the impacts of human-induced activities on microbial communities ranging from human health to agriculture to environmental management, and their responses to environmental changes.

  1. Metagenomic Insights into Evolution of a Heavy Metal-Contaminated Groundwater Microbial Community

    SciTech Connect (OSTI)

    Hemme, Christopher L.; Deng, Ye; Gentry, Terry J.; Fields, Matthew W.; Wu, Liyou; Barua, Soumitra; Barry, Kerrie; Tringe, Susannah G.; Watson, David B.; He, Zhili; Hazen, Terry C.; Tiedje, James M.; Rubin, Edward M.; Zhou, Jizhong

    2010-02-15T23:59:59.000Z

    Understanding adaptation of biological communities to environmental change is a central issue in ecology and evolution. Metagenomic analysis of a stressed groundwater microbial community reveals that prolonged exposure to high concentrations of heavy metals, nitric acid and organic solvents (~;;50 years) have resulted in a massive decrease in species and allelic diversity as well as a significant loss of metabolic diversity. Although the surviving microbial community possesses all metabolic pathways necessary for survival and growth in such an extreme environment, its structure is very simple, primarily composed of clonal denitrifying ?- and ?-proteobacterial populations. The resulting community is over-abundant in key genes conferring resistance to specific stresses including nitrate, heavy metals and acetone. Evolutionary analysis indicates that lateral gene transfer could be a key mechanism in rapidly responding and adapting to environmental contamination. The results presented in this study have important implications in understanding, assessing and predicting the impacts of human-induced activities on microbial communities ranging from human health to agriculture to environmental management, and their responses to environmental changes.

  2. Treatment of Arsenic, Heavy Metals, and Acidity Using a Mixed ZVI-Compost PRB

    SciTech Connect (OSTI)

    Ludwig, R.; Smyth, D; Blowes, D; Spink, L; Wilkin, R; Jewett, D; Weisener, C

    2009-01-01T23:59:59.000Z

    A 30-month performance evaluation of a pilot permeable reactive barrier (PRB) consisting of a mixture of leaf compost, zero-valent iron (ZVI), limestone, and pea gravel was conducted at a former phosphate fertilizer manufacturing facility in Charleston, SC. The PRB is designed to remove heavy metals and arsenic from groundwater by promoting microbially mediated sulfate reduction and sulfide-mineral precipitation and arsenic and heavy metal sorption. Performance monitoring showed effective treatment of As, Pb, Cd, Zn, and Ni from concentrations as high as 206 mg L{sup -1}, 2.02 mg L{sup -1}, 0.324 mg L{sup -1}, 1060 mg L{sup -1}, and 2.12 mg L{sup -1}, respectively, entering the PRB, to average concentrations of <0.03 mg L{sup -1}, < 0.003 mg L{sup -1}, < 0.001 mg L{sup -1}, < 0.23 mg L{sup -1}, and <0.003 mg L{sup -1}, respectively, within the PRB. Both As(III) and As(V) were effectively removed from solution with X-ray absorption near edge structure (XANES) analysis of core samples indicating the presence of As(V) in oxygen-bound form and As(III) in both oxygen- and sulfur-bound forms. XANES solid phase sulfur analysis indicated decreases in the peak amplitude of intermediate oxidized sulfur species and sulfate components with increasing distance and depth within the PRB.

  3. Metagenomic insights into evolution of a heavy metal-contaminated groundwater microbial community

    SciTech Connect (OSTI)

    Hemme, Christopher [University of Oklahoma; Deng, Ye [University of Oklahoma; Gentry, Terry [Texas A& M University; Fields, Matthew Wayne [Miami University, Oxford, OH; Wu, Liyou [University of Oklahoma, Norman; Barua, Soumitra [University of Oklahoma; Barry, Kerry [Joint Genome Institute; Green-Tringe, Susannah [Joint Genome Institute, Walnut Creek, California; Watson, David B [ORNL; He, Zhili [University of Oklahoma; Hazen, Terry [Lawrence Berkeley National Laboratory (LBNL); Tiedje, James M. [Michigan State University, East Lansing; Rubin, Edward M. [Joint Genome Institute, Walnut Creek, California; Zhou, Jizhong [University of Oklahoma, Norman

    2010-02-01T23:59:59.000Z

    Understanding adaptation of biological communities to environmental change is a central issue in ecology and evolution. Metagenomic analysis of a stressed groundwater microbial community reveals that prolonged exposure to high concentrations of heavy metals, nitric acid and organic solvents (~50 years) has resulted in a massive decrease in species and allelic diversity as well as a significant loss of metabolic diversity. Although the surviving microbial community possesses all metabolic pathways necessary for survival and growth in such an extreme environment, its structure is very simple, primarily composed of clonal denitrifying - and -proteobacterial populations. The resulting community is overabundant in key genes conferring resistance to specific stresses including nitrate, heavy metals and acetone. Evolutionary analysis indicates that lateral gene transfer could have a key function in rapid response and adaptation to environmental contamination. The results presented in this study have important implications in understanding, assessing and predicting the impacts of human-induced activities on microbial communities ranging from human health to agriculture to environmental management, and their responses to environmental changes.

  4. Synthesis of Functionalized Superparamagnetic Iron Oxide Nanoparticles from a Common Precursor and their Application as Heavy Metal and Actinide Sorbents

    SciTech Connect (OSTI)

    Warner, Marvin G.; Warner, Cynthia L.; Addleman, Raymond S.; Droubay, Timothy C.; Engelhard, Mark H.; Davidson, Joseph D.; Cinson, Anthony D.; Nash, Michael A.; Yantasee, Wassana

    2009-10-12T23:59:59.000Z

    We describe the use of a simple and versatile technique to generate a series of ligand stabilized iron oxide nanoparticles containing different ? functionalities with specificities toward heavy metals and actinides at the periphery of the stabilizing ligand shell from a common, easy to synthesize precursor nanoparticle. The resulting nanoparticles are designed to contain affinity ligands that make them excellent sorbent materials for a variety of heavy metals from contaminated aqueous systems such as river water and ground water as well as actinides from clinical samples such as blood and urine. Functionalized superparamagnetic nanoparticles make ideal reagents for extraction of heavy metal and actinide contaminants from environmental and clinical samples since they are easily removed from the media once bound to the contaminant by simply applying a magnetic field. In addition, these engineered nanomaterials have an inherently high active surface area (often > 100 m2/g) making them ideal sorbent materials for these types of applications

  5. Method and device for electroextraction of heavy metals from technological solutions and wastewater

    DOE Patents [OSTI]

    Khalemsky, Aron Mikhailov; Payusov, Sergei Abramovic; Kelner, Leonid; Jo, Jae

    2005-05-03T23:59:59.000Z

    The basic principles of the method for heavy metals electroextraction from technological solutions and wastewater includes pretreating to remove Chromium-6 and high concentrations of heavy metals and periodically treating in a six-electrode bipolar cylindrical electroreactor made of non-conducting material to achieve lower accepted levels of impurities. Six cylindrical steel electrodes form two triode stacks and are fed with three-phase alternating current of commercial frequency (50-60 Hz), which can be pulsed. Each phase of the three-phase current is connected to three electrodes of one triode stack or in parallel to two triode stacks. The parallel connection of three-phase current to two triode stacks is performed so that the same phase of the three phase current is connected in parallel with each two opposite electrodes of six electrodes located along the periphery, or with two adjacent electrodes. A bipolar stationary aluminum electrode is situated in the inter-electrode space. In one of the embodiments, the bipolar electrode is made of a perforated heat-resistant plastic container filled with secondary aluminum and duralumin scrap. In another embodiment, the bipolar electrode of aluminum or duralumin scrap may be made without a perforated container and is placed in the inter-electrode space as a bulk scrap. In this case, to prevent shorts, each of six steel electrodes is placed in isolated perforated plastic shell with holes of 5 mm in diameter. Non-ferrous metals are extracted in a form of ferrite-chromites, and aluminates as well as hydroxyl salts deposited in the inter-electrode space without electrolysis deposits on electrodes. Deposits are separated from solution by known methods of filtration.

  6. Heavy metal leaching from coal fly ash amended container substrates during Syngonium production

    SciTech Connect (OSTI)

    Li, Q.S.; Chen, J.J.; Li, Y.C. [University of Florida, Apopka, FL (United States)

    2008-02-15T23:59:59.000Z

    Coal fly ash has been proposed to be an alternative to lime amendment and a nutrient source of container substrates for ornamental plant production. A great concern over this proposed beneficial use, however, is the potential contamination of surface and ground water by heavy metals. In this study, three fly ashes collected from Florida, Michigan, and North Carolina and a commercial dolomite were amended in a basal substrate. The formulated substrates were used to produce Syngonium podophyllum Schott 'Berry Allusion' in 15-cm diameter containers in a shaded greenhouse. Leachates from the containers were collected during the entire six months of plant production and analyzed for heavy metal concentrations. There were no detectable As, Cr, Hg, Pb, and Se in the leachates; Cd and Mo were only detected in few leachate samples. The metals constantly detected were Cu, Mn, Ni, and Zn. The total amounts of Cu, Mn, Ni, and Zn leached during the six-month production period were 95, 210, 44, and 337 {mu} g per container, indicating that such amounts in leachates may contribute little to contamination of surface and ground water. In addition, plant growth indices and fresh and dry weights of S. podophyllum 'Berry Allusion' produced from fly ash and dolomite-amended substrates were comparable except for the plants produced from the substrate amended with fly ash collected from Michigan which had reduced growth indices and fresh and dry weights. Thus, selected fly ashes can be alternatives to commercial dolomites as amendments to container substrates for ornamental plant production. The use of fly ashes as container substrate amendments should represent a new market for the beneficial use of this coal combustion byproduct.

  7. Placental concentrations of heavy metals in a mother-child cohort

    SciTech Connect (OSTI)

    Amaya, E., E-mail: eamayag@ugr.es [Laboratory of Medical Investigations, San Cecilio University Hospital, University of Granada, 18071 Granada (Spain); Gil, F. [Department of Legal Medicine, Toxicology and Physic Anthropology, Faculty of Medicine, University of Granada, 18071 Granada (Spain)] [Department of Legal Medicine, Toxicology and Physic Anthropology, Faculty of Medicine, University of Granada, 18071 Granada (Spain); Freire, C. [Laboratory of Medical Investigations, San Cecilio University Hospital, University of Granada, 18071 Granada (Spain) [Laboratory of Medical Investigations, San Cecilio University Hospital, University of Granada, 18071 Granada (Spain); National School of Public Health, Oswaldo Cruz Foundation (FIOCRUZ), 21041-210 Rio de Janeiro (Brazil); Olmedo, P. [Department of Legal Medicine, Toxicology and Physic Anthropology, Faculty of Medicine, University of Granada, 18071 Granada (Spain)] [Department of Legal Medicine, Toxicology and Physic Anthropology, Faculty of Medicine, University of Granada, 18071 Granada (Spain); Fernandez-Rodriguez, M. [Laboratory of Medical Investigations, San Cecilio University Hospital, University of Granada, 18071 Granada (Spain)] [Laboratory of Medical Investigations, San Cecilio University Hospital, University of Granada, 18071 Granada (Spain); Fernandez, M.F.; Olea, N. [Laboratory of Medical Investigations, San Cecilio University Hospital, University of Granada, 18071 Granada (Spain) [Laboratory of Medical Investigations, San Cecilio University Hospital, University of Granada, 18071 Granada (Spain); CIBER de Epidemiologia y Salud Publica (CIBERESP) (Spain)

    2013-01-15T23:59:59.000Z

    Heavy metals are environmental contaminants with properties known to be toxic for wildlife and humans. Despite strong concerns about their harmful effects, little information is available on intrauterine exposure in humans. The aim of this study was to evaluate prenatal exposure to As, Cd, Cr, Hg, Mn, and Pb and its association with maternal factors in a population-based mother-child cohort in Southern Spain. Between 2000 and 2002, 700 pregnant women were recruited and 137 placentas from the cohort were randomly selected and analyzed for the selected metals by atomic absorption. Maternal sociodemographic and lifestyle factors were obtained by questionnaire after delivery. Bivariate analysis and multivariate linear regression were performed. Cd and Mn concentrations were detected in all placentas, while Cr, Pb, and Hg were found in 98.5%, 35.0%, and 30.7% of samples, respectively. The highest concentrations were observed for Pb (mean: 94.80 ng/g wet weight of placenta), followed by Mn (63.80 ng/g), Cr (63.70 ng/g), Cd (3.45 ng/g), and Hg (0.024 ng/g). Arsenic was not detected in any sample. Gestational age and smoking during pregnancy were associated with placental Cd concentrations, while no factor appeared to influence concentrations of Cr, Hg, Mn, or Pb. In comparison to results of European studies, these concentrations are in a low-intermediate position. Studies are required to investigate the factors contributing to early exposure to heavy metals and to determine how placental transfer of these toxic compounds may affect children's health.

  8. An ecological study examining the correlation of end-stage renal disease and ground water heavy metal content in Texas counties

    E-Print Network [OSTI]

    Bishop, Scott Alan

    1999-01-01T23:59:59.000Z

    An ecological study was conducted to examine the correlation of end-stage renal disease (ESRD) and the ground water heavy metal level of lead, arsenic, cadmium, mercury and the cumulative level of all four metals in Texas counties. The heavy meal...

  9. Ion assisted deposition of optical and protective coatings for heavy metal fluoride glass

    SciTech Connect (OSTI)

    McNally, J.J.; Al-Jumaily, G.A.; McNeil, J.R.

    1986-06-15T23:59:59.000Z

    Heavy metal fluoride glass materials are attractive for optical applications in the near UV through IR wavelength regions. However, many compositions are relatively soft and hygroscopic and possess low softening temperature (250--300/sup 0/C). We have applied ion assisted deposition (IAD) techniques to deposit MgF/sub 2/, SiO/sub 2/, and Al/sub 2/O/sub 3//SiO/sub 2/ thin film structures on fluoride glass substrates at ambient substrate temperature (--100/sup 0/C). The coatings deposited using IAD improve the environmental durability of the fluoride glass and appear to have reasonably good optical characteristics; without application of IAD, the deposited coatings are not durable and have poor adhesion.

  10. Studies on the content of heavy metals in Aries River using ICP-MS

    SciTech Connect (OSTI)

    Voica, Cezara, E-mail: Cezara.Voica@itim-cj.ro; Kovacs, Melinda, E-mail: Cezara.Voica@itim-cj.ro; Feher, Ioana, E-mail: Cezara.Voica@itim-cj.ro [National Institute for Research and Development of Isotopic and Molecular Technologies, 65-103 Donath Str., 400293 Cluj-Napoca (Romania)] [National Institute for Research and Development of Isotopic and Molecular Technologies, 65-103 Donath Str., 400293 Cluj-Napoca (Romania)

    2013-11-13T23:59:59.000Z

    Among the industrial branches, the mining industry has always been an important source of environmental pollution, both aesthetically and chemically. Through this paper results of ICP-MS characterization of Aries River Basin are reported. Mining activities from this area has resulted in contamination of environment and its surrounding biota. This is clearly evidenced in analyzed water samples, especially from Baia de Aries site where increased amount of trace elements as Cr, Zn, As, Se, Cd, Pb and U were founded. Also in this site greater amount of rare earth elements was evidenced also. Through monitoring of Aries River from other non-mining area it was observed that the quantitative content of heavy metals was below the maximum permissible levels which made us to conclude that the water table wasn't seriously affected (which possibly might be attributed to the cessation of mining activities in this area from a few years ago)

  11. INTERPRETING THE RESULTS OF SOIL TESTS FOR HEAVY METALS Vern Grubinger and Don Ross, University of Vermont

    E-Print Network [OSTI]

    Hayden, Nancy J.

    amounts of heavy metals to the soil, which can build up over time with repeated applications. The actual Results The US Environmental Protection Agency (EPA) and NY Department of Environmental Conservation (NYS to guide clean-up efforts of contaminated sites; NYS DEC levels are based on removing human health risks

  12. Sedimentation and chronology of heavy metal pollution in Oslo harbor, Norway Aivo Lepland a,*, Thorbjrn J. Andersen b

    E-Print Network [OSTI]

    Alve, Elisabeth

    Sedimentation and chronology of heavy metal pollution in Oslo harbor, Norway Aivo Lepland a,d , Anders Rindby e a Geological Survey of Norway, Leiv Eirikssons vei 39, 7491 Trondheim, Norway b Norwegian Geotechnical Institute, P.O. Box 3930 Ullevål Stadion, 0806 Oslo, Norway d Department

  13. Sol-gel synthesis of high-quality heavy-metal fluoride glasses

    SciTech Connect (OSTI)

    Dejneka, M.; Riman, R.E.; Snitzer, E. (Rutgers, The State Univ. of New Jersey, Piscataway, NJ (United States). Dept. of Ceramics)

    1993-12-01T23:59:59.000Z

    Fluoride glasses are excellent laser hosts and are very well suited for a broad spectrum of optical applications. However, current fluoride glass synthesis is expensive. The sol-gel method is an affordable alternative for producing high-performance, optical-quality heavy-metal fluoride glasses. The method involves forming a hydrous oxide gel of the constituent metal alkoxides and salts, polymerizing the solution to form a gel, fluorinating the gel with anhydrous HF, melting the amorphous material in an oxidizing atmosphere of SF[sub 6], and casting the melt into desired shapes. ZBLA (57ZrF[sub 4] [times] 36BaF[sub 2] [times] 4LaF[sub 3] [times] 3AlF[sub 3], in mol%) and Nd-doped (0.3 mol%) ZBLA glass rods were prepared by this process and their properties were measured. The sol-gel-based glasses had thermal and optical properties similar to those found in the literature for conventionally prepared fluorides.

  14. Sequential Extraction Versus Comprehensive Characterization of Heavy Metal Species in Brownfield Soils

    SciTech Connect (OSTI)

    Dahlin, Cheryl L.; Williamson, Connie A.; Collins, W. Keith; Dahlin, David C.

    2002-06-01T23:59:59.000Z

    The applicability of sequential extraction as a means to determine species of heavy-metals was examined by a study on soil samples from two Superfund sites: the National Lead Company site in Pedricktown, NJ, and the Roebling Steel, Inc., site in Florence, NJ. Data from a standard sequential extraction procedure were compared to those from a comprehensive study that combined optical- and scanning-electron microscopy, X-ray diffraction, and chemical analyses. The study shows that larger particles of contaminants, encapsulated contaminants, and/or man-made materials such as slags, coke, metals, and plastics are subject to incasement, non-selectivity, and redistribution in the sequential extraction process. The results indicate that standard sequential extraction procedures that were developed for characterizing species of contaminants in river sediments may be unsuitable for stand-alone determinative evaluations of contaminant species in industrial-site materials. However, if employed as part of a comprehensive, site-specific characterization study, sequential extraction could be a very useful tool.

  15. Pulmonary toxicity after exposure to military-relevant heavy metal tungsten alloy particles

    SciTech Connect (OSTI)

    Roedel, Erik Q., E-mail: Erik.Roedel@amedd.army.mil [Department of General Surgery, Tripler Army Medical Center, Honolulu, HI 96859 (United States); Cafasso, Danielle E., E-mail: Danielle.Cafasso@amedd.army.mil [Department of General Surgery, Tripler Army Medical Center, Honolulu, HI 96859 (United States); Lee, Karen W.M., E-mail: Karen.W.Lee@amedd.army.mil [Department of Clinical Investigation, Tripler Army Medical Center, Honolulu, HI 96859 (United States); Pierce, Lisa M., E-mail: Lisa.Pierce@amedd.army.mil [Department of Clinical Investigation, Tripler Army Medical Center, Honolulu, HI 96859 (United States)

    2012-02-15T23:59:59.000Z

    Significant controversy over the environmental and public health impact of depleted uranium use in the Gulf War and the war in the Balkans has prompted the investigation and use of other materials including heavy metal tungsten alloys (HMTAs) as nontoxic alternatives. Interest in the health effects of HMTAs has peaked since the recent discovery that rats intramuscularly implanted with pellets containing 91.1% tungsten/6% nickel/2.9% cobalt rapidly developed aggressive metastatic tumors at the implantation site. Very little is known, however, regarding the cellular and molecular mechanisms associated with the effects of inhalation exposure to HMTAs despite the recognized risk of this route of exposure to military personnel. In the current study military-relevant metal powder mixtures consisting of 92% tungsten/5% nickel/3% cobalt (WNiCo) and 92% tungsten/5% nickel/3% iron (WNiFe), pure metals, or vehicle (saline) were instilled intratracheally in rats. Pulmonary toxicity was assessed by cytologic analysis, lactate dehydrogenase activity, albumin content, and inflammatory cytokine levels in bronchoalveolar lavage fluid 24 h after instillation. The expression of 84 stress and toxicity-related genes was profiled in lung tissue and bronchoalveolar lavage cells using real-time quantitative PCR arrays, and in vitro assays were performed to measure the oxidative burst response and phagocytosis by lung macrophages. Results from this study determined that exposure to WNiCo and WNiFe induces pulmonary inflammation and altered expression of genes associated with oxidative and metabolic stress and toxicity. Inhalation exposure to both HMTAs likely causes lung injury by inducing macrophage activation, neutrophilia, and the generation of toxic oxygen radicals. -- Highlights: ? Intratracheal instillation of WNiCo and WNiFe induces lung inflammation in rats. ? WNiCo and WNiFe alter expression of oxidative stress and toxicity genes. ? WNiCo induces a greater oxidative burst response than WNiFe in lung macrophages.

  16. A correlation between the heavy element content of transiting extrasolar planets and the metallicity of their parent stars

    E-Print Network [OSTI]

    Tristan Guillot; Nuno C. Santos; Frdric Pont; Nicolas Iro; Claudio Melo; Ignasi Ribas

    2006-05-31T23:59:59.000Z

    Nine extrasolar planets with masses between 110 and 430M are known to transit their star. The knowledge of their masses and radii allows an estimate of their composition, but uncertainties on equations of state, opacities and possible missing energy sources imply that only inaccurate constraints can be derived when considering each planet separately. Aims: We seek to better understand the composition of transiting extrasolar planets by considering them as an ensemble, and by comparing the obtained planetary properties to that of the parent stars. Methods: We use evolution models and constraints on the stellar ages to derive the mass of heavy elements present in the planets. Possible additional energy sources like tidal dissipation due to an inclined orbit or to downward kinetic energy transport are considered. Results: We show that the nine transiting planets discovered so far belong to a quite homogeneous ensemble that is characterized by a mass of heavy elements that is a relatively steep function of the stellar metallicity, from less than 20 earth masses of heavy elements around solar composition stars, to up to 100M for three times the solar metallicity (the precise values being model-dependant). The correlation is still to be ascertained however. Statistical tests imply a worst-case 1/3 probability of a false positive. Conclusions: Together with the observed lack of giant planets in close orbits around metal-poor stars, these results appear to imply that heavy elements play a key role in the formation of close-in giant planets. The large masses of heavy elements inferred for planets orbiting metal rich stars was not anticipated by planet formation models and shows the need for alternative theories including migration and subsequent collection of planetesimals.

  17. Effect of initial fluctuations on the collective flow in intermediate-energy heavy ion collisions

    E-Print Network [OSTI]

    Jia Wang; Yu-Gang Ma; Guo-Qiang Zhang; Wen-Qing Shen

    2014-11-07T23:59:59.000Z

    A systemical analysis of the initial fluctuation effect on the collective flows for Au+Au at 1$A$ GeV has been presented in the framework of Isospin-dependent Quantum Molecular Dynamics model (IQMD), and a special focus on the initial fluctuation effect on the squeeze-out is emphasized. The flows calculated by the participant plane reconstructedby the initial geometry in coordinate space are compared with those calculated by both the ideal reaction plane and event plane methods. It is found that initial fluctuation weakens squeeze-out effect, and somediscrepancies between the flows extracted by the above different plane methods appearwhich indicate that the flows are affected by the evolution of dynamics. In addition, we found that the squeeze-out flow is also proportional to initial eccentricity. Our calculations also qualitatively give the similar trend for the excitation function of the elliptic flow of the FOPI experimental data. Finally we address the nucleon number scaling of the flows for light particles. Even though initial fluctuation decreases the ratio of $v_4/v_2^2$ as well as $v_3/(v_1v_2$) a lot, all fragments to mass number 4 keep the same curve and shows independent of transverse momentum.

  18. ON THE INITIAL MASS FUNCTION OF LOW-METALLICITY STARS: THE IMPORTANCE OF DUST COOLING

    SciTech Connect (OSTI)

    Dopcke, Gustavo [Member of the International Max Planck Research School for Astronomy and Cosmic Physics at the University of Heidelberg, IMPRS-HD, Germany. (Germany)] [Member of the International Max Planck Research School for Astronomy and Cosmic Physics at the University of Heidelberg, IMPRS-HD, Germany. (Germany); Glover, Simon C. O.; Clark, Paul C.; Klessen, Ralf S., E-mail: gustavo@uni-hd.de [Zentrum fuer Astronomie, Institut fuer Theoretische Astrophysik, Universitaet Heidelberg, Albert-Ueberle-Str. 2, D-69120 Heidelberg (Germany)

    2013-04-01T23:59:59.000Z

    The first stars to form in the universe are believed to have distribution of masses biased toward massive stars. This contrasts with the present-day initial mass function, which has a predominance of stars with masses lower than 1 M{sub Sun }. Therefore, the mode of star formation must have changed as the universe evolved. Such a transition is attributed to a more efficient cooling provided by increasing metallicity. Especially dust cooling can overcome the compressional heating, which lowers the gas temperature thus increasing its instability to fragmentation. The purpose of this paper is to verify if dust cooling can efficiently cool the gas, and enhance the fragmentation of gas clouds at the early stages of the universe. To confirm that, we calculate a set of hydrodynamic simulations that include sink particles, which represent contracting protostars. The thermal evolution of the gas during the collapse is followed by making use of a primordial chemical network and also a recipe for dust cooling. We model four clouds with different amounts of metals (10{sup -4}, 10{sup -5}, 10-6 Z{sub Sun }, and 0), and analyze how this property affect the fragmentation of star-forming clouds. We find evidence for fragmentation in all four cases, and hence conclude that there is no critical metallicity below which fragmentation is impossible. Nevertheless, there is a clear change in the behavior of the clouds at Z {approx}< 10{sup -5} Z{sub Sun }, caused by the fact that at this metallicity, fragmentation takes longer to occur than accretion, leading to a flat mass function at lower metallicities.

  19. N, P, and heavy metal dynamics in wetlands and lakes of the Danube Delta, Romania

    SciTech Connect (OSTI)

    Lajtha, K.; Keller, B.; Jamil, A. [Oregon State Univ., Corvallis, OR (United States)]|[Boston Univ., MA (United States)]|[Univ. of Bucharest (Romania)] [and others

    1995-09-01T23:59:59.000Z

    The Danube Delta stands at the interface between the Danube and the western Black Sea. Although it is assumed that such extensive wetlands can effectively filter nutrients and pollutants from surrounding waters, recent anthropogenic factors such as increased loading from upstream sources, dredging, channelization, and engineering impoundments may all serve to decrease the filtering potential of the marshes. We sampled sediments, water, and mussels from lakes, and plants and sediments from marshes along an eastward gradient as well as with distance from a main channel in the Delta to examine controls on filtering efficiency. N and P in water decreased with distance from the western gateway, although the magnitude of this decrease varied among years with changes in hydrology. Heavy metals in roots of Phragmites did not vary predictably over this gradient, although concentrations in roots from dredged channel sediments were significantly higher than in roots from natural marshes. Accumulation in mussels reflected hydrologic flow within the Delta, which may be significantly altered by channelization and dredging.

  20. Wet extraction of heavy metals and chloride from MSWI and straw combustion fly ashes

    SciTech Connect (OSTI)

    Aguiar del Toro, M. [Hamburg University of Technology, Institute of Environmental Technology and Energy Economics, Eissendorfer Street 40, D-21073 Hamburg (Germany); Calmano, W. [Hamburg University of Technology, Institute of Environmental Technology and Energy Economics, Eissendorfer Street 40, D-21073 Hamburg (Germany)], E-mail: calmano@tuhh.de; Ecke, H. [Vattenfall Research and Development AB, SE-814 26 Alvkarleby (Sweden)

    2009-09-15T23:59:59.000Z

    Fly ash residues from combustion often do not meet the criteria neither for reuse as construction materials nor landfilling as non-hazardous waste, mainly because of the high concentration of heavy metals and chlorides. This work aimed to technically evaluate an innovative wet treatment process for the extraction of chloride (Cl{sup -}), cadmium (Cd), copper (Cu), lead (Pb) and zinc (Zn) from fly ashes from a municipal solid waste incineration (MSWI) plant and from a straw combustion (SC) facility. Factors investigated were liquid/solid (L/S) ratio, full carbonation (CO{sub 2} treatment), influence of pH and leaching time, using a two-level full factorial design. The most significant factor for all responses was low pH, followed by L/S ratio. Multiple linear regression models describing the variation in extraction data had R{sup 2} values ranging from 58% to 98%. An optimization of the element extraction models was performed and a set of treatment conditions is suggested.

  1. Properties of the Initial Participant Matter Interaction Zone in Near Fermi-Energy Heavy Ion Collisions

    E-Print Network [OSTI]

    J. Wang; T. Keutgen; R. Wada; K. Hagel; S. Kowalski; T. Materna; L. Qin; Z. Chen; J. B. Natowitz; Y. G. Ma; M. Murray; A. Keksis; E. Martin; A. Ruangma; D. V. Shetty; G. Souliotis; M. Veselsky; E. M. Winchester; S. J. Yennello; D. Fabris; M. Lunardon; S. Moretto; G. Nebbia; S. Pesente; V. Rizzi; G. Viesti; M. Cinausero; G. Prete; J. Cibor; W. Zipper; Z. Majka; P. Staszel; Y. El Masri; R. Alfarro; A. Martinez-Davalos; A. Menchaca-Rocha; A. Ono

    2006-03-07T23:59:59.000Z

    The sizes, temperatures and free neutron to proton ratios of the initial interaction zones produced in the collisions of 40 MeV/nucleon $^{40}$Ar + $^{112}$Sn and 55 MeV/nucleon$^{27}$Al + $^{124}$Sn are derived using total detected neutron plus charged particle multiplicity as a measure of the impact parameter range and number of participant nucleons. The size of the initial interaction zone, determined from a coalescence model analysis, increases significantly with decreasing impact parameter. The temperatures and free neutron to proton ratios in the interaction zones are relatively similar for different impact parameter ranges and evolve in a similar fashion.

  2. The role of mycorrhizal fungi in the uptake of heavy metals by Salix. A preproposal for the McIntire-Stennis Research Program

    E-Print Network [OSTI]

    Chatterjee, Avik P.

    at ESF. As part of this project, biosolids are being used as fertilizer. This raises the possibility that heavy metals present in these biosolids may enter the rhizosphere. The use of mycorrhizal biopeptides

  3. Using a Consensus Conference to Characterize Regulatory Concerns Regarding Bioremediation of Radionuclides and Heavy Metals in Mixed Wastes at DOE Sites

    SciTech Connect (OSTI)

    Lach, Denise

    2005-06-01T23:59:59.000Z

    We have spent this first part of the project preparing background material for conference participants and making arrangements for the conference itself. Material regarding state regulatory constraints to the use of bioremediation in the cleanup of radionuclides and heavy metals at DOE sites around the country has been added to the Bioremediation Briefing paper for participants. The Steering Committee has been formulated and will hold their first meeting via phone conference on Monday, September 13, 2005. On the agenda is identification of conference participants, experts, and initial issues likely to be addressed. Human Subjects approval has been secured from the University. The ''pre-test'' has been developed and is ready to implement. The Consensus Conference will be held in Phoenix, AZ during January and February 2005; we are working with the Chamber of Commerce to find an appropriate site.

  4. Metal-fueled HWR (heavy water reactors) severe accident issues: Differences and similarities to commercial LWRs (light water reactors)

    SciTech Connect (OSTI)

    Ellison, P.G.; Hyder, M.L.; Monson, P.R. (Westinghouse Savannah River Co., Aiken, SC (USA)); Coryell, E.W. (EG and G Idaho, Inc., Idaho Falls, ID (USA))

    1990-01-01T23:59:59.000Z

    Differences and similarities in severe accident progression and phenomena between commercial Light Water Reactors (LWR) and metal-fueled isotopic production Heavy Water Reactors (HWR) are described. It is very important to distinguish between accident progression in the two systems because each reactor type behaves in a unique manner to a fuel melting accident. Some of the lessons learned as a result of the extensive commercial severe accident research are not applicable to metal-fueled heavy water reactors. A direct application of severe accident phenomena developed from oxide-fueled LWRs to metal-fueled HWRs may lead to large errors or substantial uncertainties. In general, the application of severe accident LWR concepts to HWRs should be done with the intent to define the relevant issues, define differences, and determine areas of overlap. This paper describes the relevant differences between LWR and metal-fueled HWR severe accident phenomena. Also included in the paper is a description of the phenomena that govern the source term in HWRs, the areas where research is needed to resolve major uncertainties, and areas in which LWR technology can be directly applied with few modifications.

  5. The effect of heavy metal in CMOS on neutron induced single event upset simulated with Geant4

    E-Print Network [OSTI]

    Zhang, Huan; Chen, Wei; Yang, Shan-chao

    2015-01-01T23:59:59.000Z

    Local metal interconnection is widely used in modern complementary metal oxide semiconductor (CMOS) technology. The most frequently used local materials are some heavy metals, such as tungsten (W) or copper (Cu). It's well known that single event upset (SEU) could occur in a CMOS under neutron exposure. In this paper the rectangular parallelepiped (RPP) method is used to investigate the SEU response of a typical CMOS. SEU induced by 1$\\sim$14\\:MeV neutrons are simulated with Geant4 and the cross sections are calculated. The results show that only in the structure with W, secondary particle $\\alpha$ is created and SEUs are generated when the energy of neutron is less than $4$\\:MeV.

  6. MOVEMENT OF HEAVY METALS THROUGH UNDISTURBED AND HOMOGENIZED SOIL COLUMNS Vincent J. Camobreco , Brian K. Richards , Tammo S. Steenhuis , John H. Peverly , and Murray B. McBride1 1* 1 2 2

    E-Print Network [OSTI]

    Walter, M.Todd

    and in combination with organic-facilitated transport, can accelerate metal leaching through soils. KEYWORDS Heavy been assumed that these metals are immobile in managed agricultural soils (McBride 1995), factorsMOVEMENT OF HEAVY METALS THROUGH UNDISTURBED AND HOMOGENIZED SOIL COLUMNS Vincent J. Camobreco

  7. EVIDENCE FOR A MILD STEEPENING AND BOTTOM-HEAVY INITIAL MASS FUNCTION IN MASSIVE GALAXIES FROM SODIUM AND TITANIUM-OXIDE INDICATORS

    SciTech Connect (OSTI)

    Spiniello, C.; Trager, S. C.; Koopmans, L. V. E.; Chen, Y. P. [Kapteyn Institute, University of Groningen, P.O. Box 800, 9700 AV Groningen (Netherlands)

    2012-07-10T23:59:59.000Z

    We measure equivalent widths (EWs)-focusing on two unique features (NaI and TiO{sub 2}) of low-mass stars ({approx}< 0.3 M{sub Sun })-for luminous red galaxy spectra from the Sloan Digital Sky Survey (SDSS) and X-Shooter Lens Survey (XLENS) in order to study the low-mass end of the initial mass function (IMF). We compare these EWs to those derived from simple stellar population models computed with different IMFs, ages, [{alpha}/Fe], and elemental abundances. We find that models are able to simultaneously reproduce the observed NaD {lambda}5895 and Na I {lambda}8190 features for lower-mass ({approx}{sigma}{sub *}) early-type galaxies (ETGs) but deviate increasingly for more massive ETGs, due to strongly mismatching NaD EWs. The TiO{sub 2} {lambda}6230 and the Na I {lambda}8190 features together appear to be a powerful IMF diagnostic, with age and metallicity effects orthogonal to the effect of IMF. We find that both features correlate strongly with galaxy velocity dispersion. The XLENS ETG (SDSS J0912+0029) and an SDSS ETG (SDSS J0041-0914) appear to require both an extreme dwarf-rich IMF and a high sodium enhancement ([Na/Fe] = +0.4). In addition, lensing constraints on the total mass of the XLENS system within its Einstein radius limit a bottom-heavy IMF with a power-law slope to x {<=} 3.0 at the 90% CL. We conclude that NaI and TiO features, in comparison with state-of-the-art simple stellar population models, suggest a mildly steepening IMF from Salpeter (dn/dm {proportional_to} m {sup -x} with x = 2.35) to x Almost-Equal-To 3.0 for ETGs in the range {sigma} = 200-335 km s{sup -1}.

  8. Radionuclide and heavy metal concentrations in soil, vegetation, and fish collected around and within Tsicoma Lake in Santa Clara Canyon

    SciTech Connect (OSTI)

    Fresquez, P.R.; Armstrong, D.R.; Naranjo, L. Jr.

    1996-03-01T23:59:59.000Z

    Radionuclide ({sup 3}H, {sup 90}Sr, {sup 137}Cs, {sup 238}Pu, {sup 239}Pu, total U) and heavy metal (Ag, As, Ba, Be, Cd, Cr, Hg, Ni, Pb, Sb, Se, Tl) contents were determined in soil, vegetation (overstory and understory), and fish (rainbow trout) collected around and within Tsicoma Lake in Santa Clara Canyon in 1995. All heavy metal and most radionuclide contents around or within the lake, except for U in soil, vegetation, and fish, were within or just above upper limit background. Detectable levels (where the analytical result was greater than two times counting uncertainty) of U in soils, vegetation, and fish were found in slightly higher concentrations than in background samples. Overall, however, maximum total committed effective dose equivalent (CEDE)(95% confidence level)--based on consumption of 46 lb of fish--from Tsicoma Lake (0.066 mrem/y) was within the maximum total CEDE from the ingestion of fish from the Mescalero National Fish Hatchery (background)(0.113 mrem/y).

  9. Radionuclides and heavy metals in rainbow trout from Tsichomo, Nana Ka, Wen Povi, and Pin De Lakes in Santa Clara Canyon

    SciTech Connect (OSTI)

    Fresquez, P.R.; Armstrong, D.R.; Naranjo, L. Jr.

    1998-04-01T23:59:59.000Z

    Radionuclide ({sup 3}H, {sup 90}Sr, {sup 137}Cs, {sup 238}Pu, {sup 239}Pu, and total uranium) and heavy metal (Ag, As, Ba, Be, Cd, Cr, Hg, Ni, Pb, Sb, Se, and TI) concentrations were determined in rainbow trout collected from Tsichomo, Nana Ka, Wen Povi, and Pin De lakes in Santa Clara Canyon in 1997. Most radionuclide and heavy metal concentrations in fish collected from these four lakes were within or just above upper limit background concentrations (Abiquiu reservoir), and as a group were statistically (p < 0.05) similar in most parameters to background.

  10. The occurrence of heavy metals in the vicinity of industrial complexes in Nigeria

    SciTech Connect (OSTI)

    Ndiokwere, C.L.; Ezihe, C.A. (Univ. of Benin, Benin City (Nigeria))

    1990-01-01T23:59:59.000Z

    The accumulation of Cd, Cr, Cu, Ni, Pb, and Zn in soils, crops, and plants as a result of industrial activities has been examined at various locations in the vicinities of steel and refinery complexes. High concentrations of the metals were recorded in all the samples from the sites close to the emission sources and the levels decreased with distance away from the sources. Considerable amounts of the metals found in the crops and plants were mainly due to aerial deposition. Soil and crop contamination by the metals was generally higher in the steel complex than the refinery. Cadmium and lead levels were particularly high in all the samples from both complexes.

  11. Proceedings of Soil Decon `93: Technology targeting radionuclides and heavy metals

    SciTech Connect (OSTI)

    Not Available

    1993-09-01T23:59:59.000Z

    The principal objective for convening this workshop was to exchange ideas and discuss with scientists and engineers methods for removing radionuclides and/or toxic metals from soils. Over the years there have been numerous symposia, conferences, and workshops directed at soil remediation. However, this may be the first where the scope was narrowed to the removal of radionuclides and toxic metals from soils. The intent was to focus on the separation processes controlling the removal of the radionuclide and/or metal from soil. Its purpose was not intended to be a soil washing/leaching workshop, but rather to identify a variety or combination of processes (chemical, physical, and biological) that can be used in concert with the applicable engineering approaches to decontaminate soils of radionuclides and toxic metals. Abstracts and visual aids used by the speakers of the workshop are presented in this document.

  12. Baseline concentrations of radionuclides and heavy metals in soils and vegetation around the DARHT facility: Construction phase (1996)

    SciTech Connect (OSTI)

    Fresquez, P.R.; Haagenstad, H.T.; Naranjo, L. Jr.

    1997-04-01T23:59:59.000Z

    As part of the Department of Energy`s Mitigation Action Plan for the Dual Axis Radiographic Hydrodynamic Test (DARHT) Facility at Los Alamos National Laboratory (LANL), baseline concentrations of radionuclides ({sup 3}H, {sup 137}Cs, {sup 90}Sr, {sup 238}Pu, {sup 239}Pu, {sup 241}Am, total U), and heavy metals (Ag, As, Ba, Be, Cd, Cr, Cu, Hg, Ni, Pb, Sb, Se and Tl) in soil, sediment, and vegetation (overstory and understory) around the DARHT facility during the construction phase in 1996 were determined. Also, U and Be concentrations in soil samples collected in 1993 from within the proposed DARHT facility area are reported. Most radionuclides in soils, sediments, and vegetation were within current background and/or long-term regional statistical reference levels.

  13. MOLYBDENUM, RUTHENIUM, AND THE HEAVY r-PROCESS ELEMENTS IN MODERATELY METAL-POOR MAIN-SEQUENCE TURNOFF STARS

    SciTech Connect (OSTI)

    Peterson, Ruth C. [Astrophysical Advances, 607 Marion Place, Palo Alto, CA 94301 (United States)

    2013-05-01T23:59:59.000Z

    The ratios of elemental abundances observed in metal-poor stars of the Galactic halo provide a unique present-day record of the nucleosynthesis products of its earliest stars. While the heaviest elements were synthesized by the r- and s-processes, dominant production mechanisms of light trans-ironic elements were obscure until recently. This work investigates further our 2011 conclusion that the low-entropy regime of a high-entropy wind (HEW) produced molybdenum and ruthenium in two moderately metal-poor turnoff stars that showed extreme overabundances of those elements with respect to iron. Only a few, rare nucleosynthesis events may have been involved. Here we determine abundances for Mo, Ru, and other trans-Fe elements for 28 similar stars by matching spectral calculations to well-exposed near-UV Keck HIRES spectra obtained for beryllium abundances. In each of the 26 turnoff stars with Mo or Ru line detections and no evidence for s-process production (therefore old), we find Mo and Ru to be three to six times overabundant. In contrast, the maximum overabundance is reduced to factors of three and two for the neighboring elements zirconium and palladium. Since the overproduction peaks sharply at Mo and Ru, a low-entropy HEW is confirmed as its origin. The overabundance level of the heavy r-process elements varies significantly, from none to a factor of four, but is uncorrelated with Mo and Ru overabundances. Despite their moderate metallicity, stars in this group trace the products of different nucleosynthetic events: possibly very few events, possibly events whose output depended on environment, metallicity, or time.

  14. Heavy metal contamination in highway soils. Comparison of Corpus Christi, Texas and Cincinnati, Ohio shows organic matter is key to mobility

    E-Print Network [OSTI]

    Maynard, J. Barry

    Heavy metal contamination in highway soils. Comparison of Corpus Christi, Texas and Cincinnati and Cincinnati, Ohio was measured to as- sess the degree of contamination such soils contain and the likelihood that this contamination can be remobilized. High values of Ba, Cu, Pb, and Zn can be attributed to anthropogenic effects

  15. Carpathian Journal of Earth and Environmental Sciences, September 2011, Vol. 6, No. 2, p. 85 -100 ACCUMULATION OF HEAVY METALS IN NATIVE PLANTS GROWING

    E-Print Network [OSTI]

    Paris-Sud XI, Universit de

    and Technologies of Energy, Technopark of Borj Cdria University of Carthage - 2050 Hammam-Lif, Tunisia; Hassen ACCUMULATION OF HEAVY METALS IN NATIVE PLANTS GROWING NEAR THE PHOSPHATE TREATMENT INDUSTRY, TUNISIA Ins for phytostabilization of contaminated sites with Cd (BCF=23.51). Our study showed that native plant species growing

  16. Lead in Your Drinking Water Lead (Pb) is an extremely toxic heavy metal that unfortunately occurs widely in our environment. The

    E-Print Network [OSTI]

    Maynard, J. Barry

    Lead in Your Drinking Water Lead (Pb) is an extremely toxic heavy metal that unfortunately occurs widely in our environment. The chief sources of exposure are from (1) Lead paint commonly present in house interiors (2) Leaded gasoline soils along major roadways are strongly enriched in lead

  17. Electrospun and oxidized cellulose materials for environmental remediation of heavy metals in groundwater

    SciTech Connect (OSTI)

    Han, Dong [Stony Brook University (SUNY); Halada, Gary P. [Stony Brook University (SUNY); Spalding, Brian Patrick [ORNL; Brooks, Scott C [ORNL

    2009-12-01T23:59:59.000Z

    This chapter focuses on the use of modified cellulosic materials in the field of environmental remediation. Two different chemical methods were involved in fabricating oxidized cellulose (OC), which has shown promise as a metal ion chelator in environmental applications. Electrospinning was utilized to introduce a more porous structure into an oxidized cellulose matrix. FTIR and Raman spectroscopy were used to study both the formation of OC and its surface complexation with metal ions. IR and Raman spectroscopic data demonstrate the formation of characteristic carboxylic groups in the structure of the final products and the successful formation of OC-metal complexes. Subsequent field tests at the Field Research Site at Oak Ridge National Laboratory confirmed the value of OC for sorption of both U and Th ions.

  18. Heavy metals in fish from the Aleutians: Interspecific and locational differences

    SciTech Connect (OSTI)

    Burger, Joanna, E-mail: burger@biology.rutgers.edu [Division of Life Sciences, Rutgers University, 604 Allison Road, Piscataway, NJ (United States); Environmental and Occupational Health Sciences Institute, Rutgers University, Piscataway, NJ (United States); Consortium for Risk Evaluation with Stakeholder Participation, Vanderbilt University, Nashville, TN 37235 (United States); Gochfeld, Michael [Environmental and Occupational Health Sciences Institute, Rutgers University, Piscataway, NJ (United States); Consortium for Risk Evaluation with Stakeholder Participation, Vanderbilt University, Nashville, TN 37235 (United States); Environmental and Occupational Medicine, Rutgers-Robert Wood Johnson Medical School, Piscataway, NJ 08854 (United States); Jeitner, Christian; Pittfield, Taryn [Division of Life Sciences, Rutgers University, 604 Allison Road, Piscataway, NJ (United States); Environmental and Occupational Health Sciences Institute, Rutgers University, Piscataway, NJ (United States); Consortium for Risk Evaluation with Stakeholder Participation, Vanderbilt University, Nashville, TN 37235 (United States); Donio, Mark [Division of Life Sciences, Rutgers University, 604 Allison Road, Piscataway, NJ (United States)

    2014-05-01T23:59:59.000Z

    The objectives of this study were to examine levels of arsenic, cadmium, lead, mercury and selenium in edible tissue of seven species of marine fish collected from several Aleutian islands (in 2004) to determine: (1) interspecific differences, (2) locational differences (among Aleutian Islands), (3) size-related differences in any metal levels within a species, and (4) potential risk to the fish or to predators on the fish, including humans. We also compared metals levels to those of three other fish species previously examined in detail, as well as examining metals in the edible tissue of octopus (Octopus dofleini). Octopus did not have the highest levels of any metal. There were significant interspecific differences in all metal levels among the fish species, although the differences were less than an order of magnitude, except for arsenic (mean of 19,500 ppb in Flathead sole, Hippoglossoides elassodon). Significant intraisland variation occurred among the four sites on Amchitka, but there was not a consistent pattern. There were significant interisland differences for some metals and species. Mercury levels increased significantly with size for several species; lead increased significantly for only one fish species; and cadmium and selenium decreased significantly with size for halibut (Hippoglossus stenolepis). The Alaskan Department of Health and Social Services supports unrestricted consumption of most Alaskan fish species for all people, including pregnant women. Most mean metal concentrations were well below the levels known to adversely affect the fish themselves, or predators that consume them (including humans), except for mercury in three fish species (mean levels just below 0.3 ppm), and arsenic in two fish species. However, even at low mercury levels, people who consume fish almost daily will exceed guideline values from the Centers for Disease Control and the Environmental Protection Agency. - Highlights: Cadmium, lead, mercury and selenium levels differed among 10 fish species from the Aleutians. Mean Arsenic was as high as 19,500 ppb (flathead sole, Hippoglossoides elassodon). Mercury levels increased significantly with fish size for several species. Metal levels were generally below adverse effects levels for fish and their predators. Mercury and arsenic might pose a risk to human consumers, and require further examination.

  19. ORIGINAL ARTICLE Speciation and mobility of heavy metals in mud in coastal

    E-Print Network [OSTI]

    Jiao, Jiu Jimmy

    reduction of the metals with time of burial observed in the reclamation site. Keywords Land reclamation , land reclamation has gained much popularity along coastal areas of China due to the rapid development. Before land reclamation, temporal dikes around the coastal sea area to be reclaimed were constructed

  20. Initial Evaluation of Processing Methods for an Epsilon Metal Waste Form

    SciTech Connect (OSTI)

    Crum, Jarrod V.; Strachan, Denis M.; Zumhoff, Mac R.

    2012-06-11T23:59:59.000Z

    During irradiation of nuclear fuel in a reactor, the five metals, Mo, Pd, Rh, Ru, and Tc, migrate to the fuel grain boundaries and form small metal particles of an alloy known as epsilon metal ({var_epsilon}-metal). When the fuel is dissolved in a reprocessing plant, these metal particles remain behind with a residue - the undissolved solids (UDS). Some of these same metals that comprise this alloy that have not formed the alloy are dissolved into the aqueous stream. These metals limit the waste loading for a borosilicate glass that is being developed for the reprocessing wastes. Epsilon metal is being developed as a waste form for the noble metals from a number of waste streams in the aqueous reprocessing of used nuclear fuel (UNF) - (1) the {var_epsilon}-metal from the UDS, (2) soluble Tc (ion-exchanged), and (3) soluble noble metals (TRUEX raffinate). Separate immobilization of these metals has benefits other than allowing an increase in the glass waste loading. These materials are quite resistant to dissolution (corrosion) as evidenced by the fact that they survive the chemically aggressive conditions in the fuel dissolver. Remnants of {var_epsilon}-metal particles have survived in the geologically natural reactors found in Gabon, Africa, indicating that they have sufficient durability to survive for {approx} 2.5 billion years in a reducing geologic environment. Additionally, the {var_epsilon}-metal can be made without additives and incorporate sufficient foreign material (oxides) that are also present in the UDS. Although {var_epsilon}-metal is found in fuel and Gabon as small particles ({approx}10 {micro}m in diameter) and has survived intact, an ideal waste form is one in which the surface area is minimized. Therefore, the main effort in developing {var_epsilon}-metal as a waste form is to develop a process to consolidate the particles into a monolith. Individually, these metals have high melting points (2617 C for Mo to 1552 C for Pd) and the alloy is expected to have a high melting point as well, perhaps exceeding 1500 C. The purpose of the work reported here is to find a potential commercial process with which {var_epsilon}-metal plus other components of UDS can be consolidated into a solid with minimum surface area and high strength Here, we report the results from the preliminary evaluation of spark-plasma sintering (SPS), hot-isostatic pressing (HIP), and microwave sintering (MS). Since bulk {var_epsilon}-metal is not available and companies could not handle radioactive materials, we prepared mixtures of the five individual metal powders (Mo, Ru, Rh, Pd, and Re) and baddeleyite (ZrO{sub 2}) to send the vendors of SPS, HIP, and MS. The processed samples were then evaluated at the Pacific Northwest National Laboratory (PNNL) for bulk density and phase assemblage with X-ray diffraction (XRD) and phase composition with scanning electron microscopy (SEM). Physical strength was evaluated qualitatively. Results of these scoping tests showed that fully dense cermet (ceramic-metal composite) materials with up to 35 mass% of ZrO{sub 2} were produced with SPS and HIP. Bulk density of the SPS samples ranged from 87 to 98% of theoretical density, while HIP samples ranged from 96 to 100% of theoretical density. Microwave sintered samples containing ZrO{sub 2} had low densities of 55 to 60% of theoretical density. Structurally, the cermet samples showed that the individual metals alloyed in to {var_epsilon}-phase - hexagonal-close-packed (HCP) alloy (4-95 mass %), the {alpha}-phase - face-centered-cubic (FCC) alloy structure (3-86 mass %), while ZrO{sub 2} remained in the monoclinic structure of baddeleyite. Elementally, the samples appeared to have nearly uniform composition, but with some areas rich in Mo and Re, the two components with the highest melting points. The homogeneity in distribution of the elements in the alloy is significantly improved in the presence of ZrO{sub 2}. However, ZrO{sub 2} does not appear to react with the alloy, nor was Zr found in the alloy.

  1. The south central Texas heavy rain event of October 1998: an MM5 simulation and diagnosis of convective initiation

    E-Print Network [OSTI]

    Scott, Richard Kevin

    2001-01-01T23:59:59.000Z

    During the weekend of 17-18 October 1998, extremely heavy rainfall over south central Texas resulted in widespread flash flooding and numerous river floods. Southern Hays County received 760 mm of rainfall, and an area of 18,000 km recorded over...

  2. HST Observations of Heavy Elements in Metal-Poor Galactic Halo Stars

    E-Print Network [OSTI]

    John J. Cowan; Christopher Sneden; Timothy C. Beers; James E. Lawler; Jennifer Simmerer; James W. Truran; Francesca Primas; Jason Collier; Scott Burles

    2005-02-28T23:59:59.000Z

    We present new abundance determinations of neutron-capture elements Ge, Zr, Os, Ir, and Pt in a sample of 11 metal-poor (-3.1 56) elements. However, the large (and correlated) scatters of [Eu,Os,Ir,Pt/Fe] suggests that the heaviest neutron-capture r-process elements are not formed in all supernovae. In contrast, the Ge abundances of all program stars track their Fe abundances, very well. An explosive process on iron-peak nuclei (e.g., the alpha-rich freeze-out in supernovae), rather than neutron capture, appears to have been the dominant synthesis mechanism for this element at low metallicities -- Ge abundances seem completely uncorrelated with Eu.

  3. Heavy metal contents of epiphytic acrocarpous mosses within inhabited sites in southwest Nigeria

    SciTech Connect (OSTI)

    Onianwa, P.C.; Ajayi, S.O.

    1987-01-01T23:59:59.000Z

    The levels of the metals Pb, Zn, Cu, Cd, Ni, Mn, and Fe accumulated in acrocarpous mosses within inhabited parts of villages and towns in the southwest region of Nigeria were determined, and then used for a classification of the area into relative pollution zones. Ibadan City was found to be the most polluted in the study area. Other zones of low and medium polluted villages and towns were identified. The zonations based on metal levels in these mosses were to some extent similar to that already obtained in a separate study of the same area with epiphytic forest mosses. The enrichment factors show that the gradients between zones of different pollution levels were higher in mosses within the inhabited sites.

  4. Effects of asphaltene precipitation and reprecipitation on the metal-containing compounds in heavy residua

    SciTech Connect (OSTI)

    Reynolds, J.G.; Biggs, W.R.

    1986-01-01T23:59:59.000Z

    Boscan vacuum residuum (VR) has been separated into isooctane insoluble asphaltenes and isooctane soluble maltenes. The asphaltenes were dissolved in a minimum of toluene and were further separated by two additional reprecipitations using isooctane as the precipitating solvent. The authors examined the fractions, including the recovered isooctane soluble material, by size exclusion chromatography (SEC) with inductively coupled plasma (ICP) emission spectroscopy to determine the effects, if any, the reprecipitations have on the size distribution of the metal-containing compounds.

  5. Metallic nanospheres embedded in nanowires initiated on nanostructures and methods for synthesis thereof

    DOE Patents [OSTI]

    Zaidi, Saleem (Albuquerque, NM); Tringe, Joseph W. (Walnut Creek, CA); Vanamu, Ganesh (Sunnyvale, CA); Prinja, Rajiv (Albuquerque, NM)

    2012-01-10T23:59:59.000Z

    A nanostructure includes a nanowire having metallic spheres formed therein, the spheres being characterized as having at least one of about a uniform diameter and about a uniform spacing there between. A nanostructure in another embodiment includes a substrate having an area with a nanofeature; and a nanowire extending from the nanofeature, the nanowire having metallic spheres formed therein, the spheres being characterized as having at least one of about a uniform diameter and about a uniform spacing there between. A method for forming a nanostructure is also presented. A method for reading and writing data is also presented. A method for preparing nanoparticles is also presented.

  6. Cesium and heavy metal removal from flue dusts and other matrices

    SciTech Connect (OSTI)

    Soderstrom, D.J.; May, R.; Spaulding, S. [Lockheed Environmental Systems and Technologies Co., Las Vegas, NV (United States). Technology Applications Div.

    1994-12-31T23:59:59.000Z

    A problem exists in the steel industry because of the generation of radioactive waste that is caused by the accidental destruction of nuclear detection instruments. The flue dust from electric Arc Furnaces (EAF) becomes contaminated with the radionuclide used. Typically the radionuclide is cesium 137. The problem is a concern to the industry since the contamination results in the generation of a mixed waste which is costly to dispose of properly. In the interest of providing a viable solution to the problem, Lockheed Environmental Systems and Technologies has developed a process for removal of cesium from flue dust. While removing the cesium from the treatment residue, the process also isolates the other major elements of concern and renders them innocuous, saleable, or readily disposable. However, several innovative techniques have been applied which make the process far more economical, and in addition, the changes simplify the operation and render it controllable. The process involves the dissolution of the various metallic and non-metallic constituents through the use of a mild mineral acid leach. This treatment solubilizes the majority of the constituents including the cesium.

  7. Comparative evaluation of several small mammal species as monitors of heavy metals, radionuclides, and selected organic compounds in the environment

    SciTech Connect (OSTI)

    Talmage, S.S. (Tennessee Univ., Knoxville, TN (USA) Oak Ridge National Lab., TN (USA)); Walton, B.T. (Oak Ridge National Lab., TN (USA))

    1990-08-01T23:59:59.000Z

    The primary purpose of this study was to evaluate which small mammal species are the best monitors of specific environmental contaminants. The evaluation is based on the published literature and on an analysis of small mammals trapped at several sites on the Oak Ridge National Laboratory (ORNL) Reservation in Oak Ridge, Tennessee. Studies on the uptake of heavy metals, radionuclides, and organic chemicals are reviewed in Chapter II to evaluate several small mammal species for their capacity to serve as sentinels for the presence, accumulation, and effects of various contaminants. Where several species were present at a site, a comparative evaluation was made and species are ranked for their capacity to serve as monitors of specific contaminants. Food chain accumulation and food habits of the species are used to establish a relationship with suitability as a biomonitor. Tissue-specific concentration factors were noted in order to establish target tissues. Life histories, habitat, and food habits are reviewed in order to make generalizations concerning the ability of similar taxa to serve as biomonitor. Finally, the usefulness of several small mammal species as monitors of three contaminants -- benzo(a)pyrene, mercury, and strontium-90 -- present on or near the ORNL facilities was investigated. 133 refs., 5 figs., 20 tabs.

  8. The simulation of condensation removal of a heavy metal from exhaust gases onto sorbent particles

    SciTech Connect (OSTI)

    Rodriguez, A.; Hall, M.J

    2003-07-01T23:59:59.000Z

    A numerical model BAEROSOL for solving the general dynamic equation (GDE) of aerosols is presented. The goal was to model the capture of volatilized metals by sorbents under incinerator-like conditions. The model is based on algorithms presented by Jacobson and Turco [Aerosol Science and Technology 22 (1995) 73]. A hybrid size bin was used to model growth and formation of particles from the continuum phase and the coagulation of existing particles. Condensation and evaporation growth were calculated in a moving size bin approach, where coagulation and nucleation was modeled in the fixed size bin model of the hybrid grid. To account for the thermodynamic equilibrium in the gas phase, a thermodynamic equilibrium code CET89 was implemented. The particle size distribution (PSD) calculated with the model was then compared to analytical solutions provided for growth, coagulation and both combined. Finally, experimental findings by Rodriguez and Hall [Waste Management 21 (2001) 589-607] were compared to the PSD predicted by the developed model and the applicability of the model under incineration conditions is discussed.

  9. The Metallicity Dependence of the Stellar Luminosity and Initial Mass Functions: HST Observations of Open and Globular Clusters

    E-Print Network [OSTI]

    Ted von Hippel; Gerard Gilmore; Nial Tanvir; David Robinson; Derek H. P. Jones

    1996-05-02T23:59:59.000Z

    Using HST and the WFPC2 we have acquired very deep V- and I-band photometry of stars in NGC 2420 and NGC 2477 to study cluster luminosity functions at approximately solar metallicity. We have determined these cluster luminosity functions down to $M_I$ = 10.5 (0.2 M$_{\\odot}$) and find that the luminosity function of NGC 2420 turns over at $M_I$ $\\approx$ 9.0, and possibly stops altogether by $M_I$ $\\approx$ 9.5. The luminosity function of NGC 2477 may flatten at $M_I$ $\\geq$ 9.5. We compare our open cluster luminosity functions to the solar neighborhood field star luminosity function of Kroupa, Tout \\& Gilmore (1993) and the four published HST globular cluster luminosity functions: $\\omega$ Cen (Elson {\\it et al.}\\ 1995), 47 Tuc (De Marchi \\& Paresce 1995b), M 15 (De Marchi \\& Paresce 1995a), and NGC 6397 (Paresce, De Marchi \\& Romaniello 1995). We find a smooth relation between the location of the luminosity function turn-over and the metallicity for all these low mass star samples which matches the expected $M_I$ versus [Fe/H] trend for a model star of $\\approx$ 0.27 M$_{\\odot}$ (Saumon 1995; Alexander {\\it et al.}\\ 1996). We interpret this smooth and systematic behavior in the cluster luminosity functions as strong evidence in favor of an invariant initial mass function and a metallicity-dependent mass-luminosity relation.

  10. Initial Assessment of Alternate Metals in Chalcogels | SciTech Connect

    Office of Scientific and Technical Information (OSTI)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOn AprilAElectronicCurves | SciTech Connect Journal Article: Improved DarkW-^^Initial

  11. Influences of statistics and initial size fluctuation on high-order cumulants of conserved quantities in relativistic heavy ion collisions

    E-Print Network [OSTI]

    Lizhu Chen; Zhiming Li; Yuanfang Wu

    2014-08-28T23:59:59.000Z

    By the generator of the UrQMD model, event statistics for the products of kurtosis ($\\kappa$) and variance ($\\sigma^2$) of net-proton and net-charge multiplicity distributions are carefully studied. It is shown that the statistics at RHIC/BES below $\\sqrt {s_{NN}} statistics dependence of the data and reduce the initial size fluctuation as well.

  12. Initiation of atomic layer deposition of metal oxides on polymer substrates by water plasma pretreatment

    SciTech Connect (OSTI)

    Steven Brandt, E.; Grace, Jeremy M. [Eastman Kodak Company, 1999 Lake Avenue, Rochester, New York 14650-2022 (United States)

    2012-01-15T23:59:59.000Z

    The role of surface hydroxyl content in atomic layer deposition (ALD) of aluminum oxide (AO) on polymers is demonstrated by performing an atomic layer deposition of AO onto a variety of polymer types, before and after pretreatment in a plasma struck in water vapor. The treatment and deposition reactions are performed in situ in a high vacuum chamber that is interfaced to an x-ray photoelectron spectrometer to prevent adventitious exposure to atmospheric contaminants. X-ray photoelectron spectroscopy is used to follow the surface chemistries of the polymers, including theformation of surface hydroxyls and subsequent growth of AO by ALD. Using dimethyl aluminum isopropoxide and water as reactants, ALD is obtained for water-plasma-treated poly(styrene) (PS), poly(propylene) (PP), poly(vinyl alcohol) (PVA), and poly(ethylene naphthalate) (PEN). For PS, PP, and PEN, initial growth rates of AO on the native (untreated) polymers are at least an order of magnitude lower than on the same polymer surface following the plasma treatment. By contrast, native PVA is shown to initiate ALD of AO as a result of the presence of intrinsic surface hydroxyls that are derived from the repeat unit of this polymer.

  13. X-ray absorption spectroscopy study of the local structure of heavy metal ions incorporated into electrodeposited nickel oxide films

    SciTech Connect (OSTI)

    Balasubramanian, M.; Melendres, C.A. [Argonne National Lab., IL (United States). Chemical Technology Div.] [Argonne National Lab., IL (United States). Chemical Technology Div.; Mansour, A.N. [Naval Surface Warfare Center, Bethesda, MD (United States). Carderock Div.] [Naval Surface Warfare Center, Bethesda, MD (United States). Carderock Div.

    1999-02-01T23:59:59.000Z

    The incorporation of heavy metal ions into simulated corrosion films has been investigated using spectroscopic and electrochemical techniques. The films were formed by electrodeposition of the appropriate oxide (hydroxide) onto a graphite substrate. Synchrotron X-ray absorption spectroscopy (XAS) was used to determine the structure and composition of the host oxide film, as well as the local structure of the impurity ion. Results on the incorporation of Ce and Sr into surface films of Ni(OH){sub 2} and NiOOH are reported. Cathodically deposited Ni(OH){sub 2} was found to be mainly in the alpha form while anodically prepared NiOOH showed the presence of Ni{sup +2} and Ni{sup +4}. Cerium incorporated into Ni(OH){sub 2} exists as mixed Ce{sup +3} and Ce{sup +4} phases; a Ce{sup +4} species was found when Ce was codeposited with NiOOH. The structure of the Ce{sup +4} phase in anodic films appears similar to a Ce(OH){sub 4} standard. However, XAS, X-ray diffraction, and laser Raman measurements indicate that the latter chemical formulation is probably incorrect and that the material is really a disordered form of hydrous cerium oxide. The local structure of this material is similar to CeO{sub 2} but has much higher structural disorder. The significance of this finding on the question of the structure of Ce-based corrosion inhibitors in aluminum oxide films is pointed out. Moreover, the authors found it possible to form pure Ce oxide (hydroxide) films on graphite by both cathodic and anodic electrodeposition; their structures have also been elucidated. Strontium incorporated into nickel oxide films consists of Sr{sup +2} which is coordinated to oxygen atoms and is likely to exist as small domains of coprecipitated material.

  14. AN INITIAL ASSESSMENT OF POTENTIAL PRODUCTION TECHNOLOGIES FOR EPSILON-METAL WASTE FORMS

    SciTech Connect (OSTI)

    Rohatgi, Aashish; Strachan, Denis M.

    2011-03-01T23:59:59.000Z

    This report examines and ranks a total of seven materials processing techniques that may be potentially utilized to consolidate the undissolved solids from nuclear fuel reprocessing into a low-surface area form. Commercial vendors of processing equipment were contacted and literature researched to gather information for this report. Typical equipment and their operation, corresponding to each of the seven techniques, are described in the report based upon the discussions and information provided by the vendors. Although the report does not purport to describe all the capabilities and issues of various consolidation techniques, it is anticipated that this report will serve as a guide by highlighting the key advantages and disadvantages of these techniques. The processing techniques described in this report were broadly classified into those that employed melting and solidification, and those in which the consolidation takes place in the solid-state. Four additional techniques were examined that were deemed impractical, but were included for completeness. The techniques were ranked based on criteria such as flexibility in accepting wide-variety of feed-stock (chemistry, form, and quantity), ease of long-term maintenance, hot cell space requirements, generation of additional waste streams, cost, and any special considerations. Based on the assumption of ~2.5 L of waste to be consolidated per day, sintering based techniques, namely, microwave sintering, spark plasma sintering and hot isostatic pressing, were ranked as the top-3 choices, respectively. Melting and solidification based techniques were ranked lower on account of generation of volatile phases and difficulties associated with reactivity and containment of the molten metal.

  15. ISSN 0378-4738 = Water SA Vol. 27 No. 1 January 2001 71Available on website http://www.wrc.org.za Plant-soil interactions of sludge-borne heavy metals and the

    E-Print Network [OSTI]

    ://www.wrc.org.za Plant-soil interactions of sludge-borne heavy metals and the effect on maize (Zea mays L.) seedling 0002, South Africa Abstract The use of sewage sludge as an organic fertiliser under South African interpreted as total metal content is limiting the agricultural use of sludge. A glasshouse experiment, which

  16. Selected heavy metals in tissues of bottlenose dolphins (Tursiops truncatus) stranded along thr Texas and Florida Gulf coasts

    E-Print Network [OSTI]

    Haubold, Elsa Maria

    1995-01-01T23:59:59.000Z

    of bottlenose dolphins in other geographic regions. Two metal-metal correlations were examined in liver, kidney and muscle tissue. Strong positive correlations were found between mercury and selenium in the three tissues. No correlations existed between cadmium...

  17. Steel and Aluminum Energy Conservation and Technology Competitiveness Act of 1988: Annual report of the metals initiative for fiscal year 1996

    SciTech Connect (OSTI)

    NONE

    1998-01-01T23:59:59.000Z

    This annual report has been prepared for the President and Congress describing the activities carried out under the Steel and Aluminum Energy Conservation and Technology Competitiveness Act of 1988, commonly referred to as the Metals Initiative. The Act has the following purposes: (1) increase energy efficiency and enhance the competitiveness of the American steel, aluminum, and copper industries; and (2) continue research and development efforts begun under the U.S. Department of Energy (DOE) program known as the Steel Initiative. These activities are detailed in a subsequent section. Other sections describe the appropriation history, the distribution of funds through fiscal year 1996, and the estimated funds necessary to continue projects through fiscal year 1997. The Metals Initiative supported four research and development projects with the U.S. Steel industry: (1) steel plant waste oxide recycling and resource recovery by smelting, (2) electrochemical dezincing of steel scrap, (3) rapid analysis of molten metals using laser-produced plasmas, and (4) advanced process control. There are three Metals Initiative projects with the aluminum industry: (1) evaluation of TiB2-G cathode components, (2) energy efficient pressure calciner, and (3) spray forming of aluminum. 1 tab.

  18. anion heavy-atom salt: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    of nutrients and heavy metals in experimental salt marsh ecosystems. Environmental Pollution,effects of nutrients and heavy metals in experimental salt marsh ecosystems....

  19. Experimental investigation and thermodynamic modeling of extraction of heavy metal ions from aqueous solutions by chelation in supercritical carbon dioxide

    E-Print Network [OSTI]

    Uyansoy, Hakki

    1995-01-01T23:59:59.000Z

    or electricaHy charged. A metal-complex forming agent has to have at least two atoms which can be coordmated by the metal at the same time. Such atoms are usually oxygen, nitrogen and 11 sulfur. A further requirement is that at least one active group...

  20. Lead in Your Drinking Water Lead (Pb) is an extremely toxic heavy metal that unfortunately occurs widely in

    E-Print Network [OSTI]

    Maynard, J. Barry

    the potential for accelerated galvanic corrosion, as illustrated below. Build up of excess scale at the junction, Cu sulfate dominates. #12;Corrosion Scale Minerals The corrosion products that build up often have a heavy build-up of iron oxides, mostly goethite and magnetite with some lepidocrocite. Lead

  1. Analytical and experimental investigations of the behavior of thermal neutrons in lattices of uranium metal rods in heavy water

    E-Print Network [OSTI]

    Simms, Richard

    1963-01-01T23:59:59.000Z

    Measurements of the intracellular distribution of the activation of foils by neutrons were made in lattices of 1/4-inch diameter, 1.03% U-235, uranium rods moderated by heavy water, with bare and cadmium-covered foils of ...

  2. Using a Consensus Conference to Characterize Regulatory Concerns Regarding Bioremediation of Radionuclides and Heavy Metals in Mixed Waste at DOE Sites

    SciTech Connect (OSTI)

    Denise Lach; Stephanie Sanford

    2006-09-01T23:59:59.000Z

    A consensus workshop was developed and convened with ten state regulators to characterize concerns regarding emerging bioremediation technology to be used to clean-up radionuclides and heavy metals in mixed wastes at US DOE sites. Two questions were explored: integrated questions: (1) What impact does participation in a consensus workshop have on the knowledge, attitudes, and practices of state regulators regarding bioremediation technology? (2) How effective is a consensus workshop as a strategy for eliciting and articulating regulators concerns regarding the use of bioremediation to clean up radionuclides and heavy metals in mixed wastes at U.S. Department of Energy Sites around the county? State regulators met together for five days over two months to learn about bioremediation technology and develop a consensus report of their recommendations regarding state regulatory concerns. In summary we found that panel members: - quickly grasped the science related to bioremediation and were able to effectively interact with scientists working on complicated issues related to the development and implementation of the technology; - are generally accepting of in situ bioremediation, but concerned about costs, implementation (e.g., institutional controls), and long-term effectiveness of the technology; - are concerned equally about technological and implementation issues; and - believed that the consensus workshop approach to learning about bioremediation was appropriate and useful. Finally, regulators wanted decision makers at US DOE to know they are willing to work with DOE regarding innovative approaches to clean-up at their sites, and consider a strong relationship between states and the DOE as critical to any effective clean-up. They do not want perceive themselves to be and do not want others to perceive them as barriers to successful clean-up at their sites.

  3. Experimental investigation and thermodynamic modeling of extraction of heavy metal ions from aqueous solutions by chelation in supercritical carbon dioxide

    E-Print Network [OSTI]

    Uyansoy, Hakki

    1995-01-01T23:59:59.000Z

    thermodynamic model has been developed. This model predicts the system pH which is a important factor in design of metal extraction units. With the model the efficiency of the extraction with different chelating agents at different temperatures and pressures...

  4. The distribution of potentially toxic heavy metals in the sediments of San Antonio Bay and the northwest Gulf of Mexico

    E-Print Network [OSTI]

    Trefry, John Harold

    1974-01-01T23:59:59.000Z

    total of 123 sediment samples from 48 locations in the northwest Gulf of Mexico, including San Antonio Bay and the Mississippi River Delta, were acid leached and analyzed for iron, manganese, lead, zinc, cadmium, copper, and nickel by atomic... of the river mouths, also showed slightly higher than expected levels of nickel, lead, and cadmium. The proposition that shell dredging operations in the bay remobilize significant quantities of toxic metals and make them available to the biota of the area...

  5. Evaluation of the Initial Isothermal Physics Measurements at the Fast Flux Test Facility, a Prototypic Liquid Metal Fast Breeder Reactor

    SciTech Connect (OSTI)

    John D. Bess

    2010-03-01T23:59:59.000Z

    The Fast Flux Test Facility (FFTF) was a 400-MWt, sodium-cooled, low-pressure, high-temperature, fast-neutron flux, nuclear fission reactor plant designed for the irradiation testing of nuclear reactor fuels and materials for the development of liquid metal fast breeder reactors (LMFBRs). The FFTF was fueled with plutonium-uranium mixed oxide (MOX) and reflected by Inconel-600. Westinghouse Hanford Company operated the FFTF as part of the Hanford Engineering Development Laboratory (HEDL) for the U.S. Department of Energy on the Hanford Site near Richland, Washington. Although the FFTF was a testing facility not specifically designed to breed fuel or produce electricity, it did provide valuable information for LMFBR projects and base technology programs in the areas of plant system and component design, component fabrication, prototype testing, and site construction. The major objectives of the FFTF were to provide a strong, disciplined engineering base for the LMFBR program, provide fast flux testing for other U.S. programs, and contribute to the development of a viable self-sustaining competitive U.S. LMFBR industry. During its ten years of operation, the FFTF acted as a national research facility to test advanced nuclear fuels, materials, components, systems, nuclear power plant operating and maintenance procedures, and active and passive reactor safety technologies; it also produced a large number of isotopes for medical and industrial users, generated tritium for the U.S. fusion research program, and participated in cooperative, international research work. Prior to the implementation of the reactor characterization program, a series of isothermal physics measurements were performed; this acceptance testing program consisted of a series of control rod worths, critical rod positions, subcriticality measurements, maximum reactivity addition rates, shutdown margins, excess reactivity, and isothermal temperature coefficient reactivity. The results of these experiments were of particular importance because they provide extensive information which can be directly applied to the design of large LMFBRs. It should be recognized that the data presented in the initial report were evaluated only to the extent necessary to ensure that adequate data were obtained. Later reports provided further interpretation and detailed comparisons with prediction techniques. The conclusion of the isothermal physics measurements was that the FFTF nuclear characteristics were essentially as designed and all safety requirements were satisfied. From a nuclear point of view, the FFTF was qualified to proceed into power operation mode. The FFTF was completed in 1978 and first achieved criticality on February 9, 1980. Upon completion of the isothermal physics and reactor characterization programs, the FFTF operated for ten years from April 1982 to April 1992. Reactor operations of the FFTF were terminated and the reactor facility was then defueled, deactivated, and placed into cold standby condition. Deactivation of the reactor was put on hold from 1996 to 2000 while the U.S. Department of Energy examined alternative uses for the FFTF but then announced the permanent deactivation of the FFTF in December 2001. Its core support basket was later drilled in May 2005, so as to remove all remaining sodium coolant. On April 17, 2006, the American Nuclear Society designated the FFTF as a National Nuclear Historic Landmark.

  6. Association of the sites of heavy metals with nanoscale carbon in a Kentucky electrostatic precipitator fly ash

    SciTech Connect (OSTI)

    James C. Hower; Uschi M. Graham; Alan Dozier; Michael T. Tseng; Rajesh A. Khatri [University of Kentucky, Lexington, KY (United States). Center for Applied Energy Research

    2008-11-15T23:59:59.000Z

    A combination of high-resolution transmission electron microscopy, scanning transmission electron microscopy, and electron energy-loss spectroscopy (HRTEM-STEM-EELS) was used to study fly ashes produced from the combustion of an eastern Kentucky coal at a southeastern-Kentucky wall-fired pulverized coal utility boiler retrofitted for low-NOx combustion. Fly ash was collected from individual hoppers in each row of the electrostatic precipitators (ESP) pollution-control system, with multiple hoppers sampled within each of the three rows. Temperatures within the ESP array range from about 200 {degree}C at the entry to the first row to <150{degree}C at the exit of the third row. HRTEM-STEM-EELS study demonstrated the presence of nanoscale (10 s nm) C agglomerates with typical soot-like appearance and others with graphitic fullerene-like nanocarbon structures. The minute carbon agglomerates are typically juxtaposed and intergrown with slightly larger aluminosilicate spheres and often form an ultrathin halo or deposit on the fly ash particles. The STEM-EELS analyses revealed that the nanocarbon agglomerates host even finer (<3 nm) metal and metal oxide particles. Elemental analysis indicated an association of Hg with the nanocarbon. Arsenic, Se, Pb, Co, and traces of Ti and Ba are often associated with Fe-rich particles within the nanocarbon deposits. 57 refs., 5 figs.

  7. In vitro profiling of epigenetic modifications underlying heavy metal toxicity of tungsten-alloy and its components

    SciTech Connect (OSTI)

    Verma, Ranjana, E-mail: Ranjana.Verma.CTR@usuhs.mil [Anatomy, Physiology and Genetics, Uniformed Services University of the Health Sciences, Bethesda, MD 20814 (United States); Center for Neuroscience and Regenerative Medicine, Uniformed Services University of the Health Sciences, Bethesda, MD 20814 (United States); Xu, Xiufen, E-mail: Xiufen.Xu.CTR@usuhs.mil [Anatomy, Physiology and Genetics, Uniformed Services University of the Health Sciences, Bethesda, MD 20814 (United States); Jaiswal, Manoj K., E-mail: Manoj.Jaiswal.CTR@usuhs.mil [Anatomy, Physiology and Genetics, Uniformed Services University of the Health Sciences, Bethesda, MD 20814 (United States); Center for Neuroscience and Regenerative Medicine, Uniformed Services University of the Health Sciences, Bethesda, MD 20814 (United States); Olsen, Cara, E-mail: colsen@usuhs.mil [Department of Preventive Medicine and Biometrics, Uniformed Services University of the Health Sciences, Bethesda, MD 20814 (United States); Mears, David, E-mail: dmears@usuhs.mil [Anatomy, Physiology and Genetics, Uniformed Services University of the Health Sciences, Bethesda, MD 20814 (United States); Caretti, Giuseppina, E-mail: giuseppina.caretti@unimi.it [Department of Biomolecular Sciences and Biotechnology, University of Milan (Italy); Galdzicki, Zygmunt, E-mail: zgaldzicki@usuhs.mil [Anatomy, Physiology and Genetics, Uniformed Services University of the Health Sciences, Bethesda, MD 20814 (United States); Center for Neuroscience and Regenerative Medicine, Uniformed Services University of the Health Sciences, Bethesda, MD 20814 (United States)

    2011-06-15T23:59:59.000Z

    Tungsten-alloy has carcinogenic potential as demonstrated by cancer development in rats with intramuscular implanted tungsten-alloy pellets. This suggests a potential involvement of epigenetic events previously implicated as environmental triggers of cancer. Here, we tested metal induced cytotoxicity and epigenetic modifications including H3 acetylation, H3-Ser10 phosphorylation and H3-K4 trimethylation. We exposed human embryonic kidney (HEK293), human neuroepithelioma (SKNMC), and mouse myoblast (C2C12) cultures for 1-day and hippocampal primary neuronal cultures for 1-week to 50-200 {mu}g/ml of tungsten-alloy (91% tungsten/6% nickel/3% cobalt), tungsten, nickel, and cobalt. We also examined the potential role of intracellular calcium in metal mediated histone modifications by addition of calcium channel blockers/chelators to the metal solutions. Tungsten and its alloy showed cytotoxicity at concentrations > 50 {mu}g/ml, while we found significant toxicity with cobalt and nickel for most tested concentrations. Diverse cell-specific toxic effects were observed, with C2C12 being relatively resistant to tungsten-alloy mediated toxic impact. Tungsten-alloy, but not tungsten, caused almost complete dephosphorylation of H3-Ser10 in C2C12 and hippocampal primary neuronal cultures with H3-hypoacetylation in C2C12. Dramatic H3-Ser10 dephosphorylation was found in all cobalt treated cultures with a decrease in H3 pan-acetylation in C2C12, SKNMC and HEK293. Trimethylation of H3-K4 was not affected. Both tungsten-alloy and cobalt mediated H3-Ser10 dephosphorylation were reversed with BAPTA-AM, highlighting the role of intracellular calcium, confirmed with 2-photon calcium imaging. In summary, our results for the first time reveal epigenetic modifications triggered by tungsten-alloy exposure in C2C12 and hippocampal primary neuronal cultures suggesting the underlying synergistic effects of tungsten, nickel and cobalt mediated by changes in intracellular calcium homeostasis and buffering. - Highlights: > Tungsten-alloy caused H3-Ser10 dephosphorylation in C2C12 and hippocampal primary cultures. > Dramatic H3-Ser10 dephosphorylation was found in all cobalt treated cultures. > C2C12 cultures exposed to tungsten-alloy or cobalt exhibited decrease in H3 pan-acetylation. > Tungsten-alloy and cobalt mediated H3-Ser10 dephosphorylation was reversed with BAPTA-AM. > These epigenetic modifications were mediated by changes in calcium homeostasis and buffering.

  8. Estimation of the formation rates of polyatomic species of heavy metals in plutonium analyses using a multicollector ICP-MS with a desolvating nebulizer

    SciTech Connect (OSTI)

    Mitroshkov, Alexandre V. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Olsen, Khris B. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States); Thomas, Linda M. [Pacific Northwest National Lab. (PNNL), Richland, WA (United States)

    2015-01-01T23:59:59.000Z

    The analyses of IAEA and environmental samples for Plutonium isotopic content are conducted normally at very low concentrations of Puusually in the range of part per trillion level and even more often at the parts per quadrillion level. To analyze such low concentrations, the interferences in the analytical solution must be reduced as much as possible. Polyatomic interferences (PIs), formed by the heavy metals (HMs) from Hf to Bi are known to create the problems for Pu isotopic analyses, because even the relatively high resolution of a modern multicollector ICP-MS is not enough to separate Pu isotopes from this PIs in most of the cases. Desolvating nebulizers (DSN) (e.g. APEX and AridusII) reduce significantly the formation of PIs compare to the use of wet plasma. The purpose of this work was to investigate the rate of formation of PIs, produced by HMs, when high resolution MC ICP-MS with desolvating nebulizer was used for Pu isotopic analyses and to estimate the influence of the metals present in the sample on the results of analyses. The NU Plasma HR Multicollector and AridusII desolvating nebulizer were used in this investigation. This investigation was done for all Pu isotopes normally analyzed by ICP-MS, including ??Pu, with the exception of ?Pu, which most of the time cant be analyzed by ICP-MS, because of the overwhelming presence of ?U in the solutions. The PI formation rates were determined and reported for all 12 HMs from Hf to Bi. Selected IAEA samples were scanned for the presence of HMs and the influence of HMs on the results of Pu isotopic analyses was evaluated. It was found that the implemented separation procedure provides sufficient separation of HM from Pu, although the effect of PIs on the measurement of low level isotopes like ?Pu and ?Pu in some cases can still be observed.

  9. SciTech Connect: Metal-Organic Framework Templated Inorganic...

    Office of Scientific and Technical Information (OSTI)

    Metal-Organic Framework Templated Inorganic Sorbents for Rapid and Efficient Extraction of Heavy Metals Citation Details In-Document Search Title: Metal-Organic Framework Templated...

  10. An Estimate of the Order of Magnitude of the Explosion During a Core Meltdown-Compaction Accident for Heavy Liquid Metal Fast Reactors: A disquieting result updating the Bethe-Tait model

    E-Print Network [OSTI]

    Arias, Francisco J.; Parks, Geoffrey T.

    2014-12-09T23:59:59.000Z

    but lasting over a timescale of milliseconds. The forms of the energy release and of the resulting struc- tural damage differ significantly between a high explosive detonation and a propellant conflagration. Considering the yield of TNT Containment Law... gravitational compaction of the 100 MWth core, the ves- sel could withstand the 60 kg TNT-equivalent explosion from a 100 $/s reactivity insertion if a bare core is as- sumed; however, allowing for the presence of the unboiled heavy liquid metal coolant...

  11. Treatability of Stormwater Heavy Metals

    E-Print Network [OSTI]

    Clark, Shirley E.

    for Chemical Treatment Type 1 water: high turbidity, >100 NTU, and high alkalinity, >250 mg/L as CaCO3, CaCO3 (alkalinity may need to be added for alum or ferric chloride). Type 3 water: low turbidity, 250 mg/L as CaCO3 (most stormwaters approach this category

  12. Coupling and Testing the Fate and Transport of Heavy Metals and Other Ionic Species in a Groundwater Setting at Oak Ridge, TN - 13498

    SciTech Connect (OSTI)

    Noosai, Nantaporn; Fuentes, Hector R. [CEE Florida International University, Miami, FL 33174 (United States)] [CEE Florida International University, Miami, FL 33174 (United States)

    2013-07-01T23:59:59.000Z

    Historical data show that heavy metals (including mercury) were released from Y -12 National Security Complex (NSC) at Oak Ridge, Tennessee, to the surrounding environments during its operation in 1950's. Studies have also shown that metals accumulated in the soil, rock, and groundwater, and are, at the present time, sources of contamination to nearby rivers and creeks (e.g., East Fork Poplar Creek, Bear Creek). For instance, mercury (Hg), zinc (Zn), cadmium (Cd) and lead (Pb) have been found and reported on the site groundwater. The groundwater type at the site is Ca-Mg-HCO{sub 3}. This paper presents a modeling application of PHREEQC, a model that simulates geochemical processes and couples them to flow and transport settings. The objective was to assess the capability of PHREEQC to simulate the transport of ionic species in groundwater at Oak Ridge, Tennessee; data were available from core holes and monitoring wells over a 736-m distance, within 60-300 m depths. First, predictions of the transport of major ionic species (i.e., Ca{sup 2+} and Mg{sup 2+}) in the water were made between monitoring wells and for GW-131. Second, the model was used to assess hypotheses under two scenarios of transport for Zn, Cd, Pb and Hg, in Ca-Mg-HCO{sub 3} water, as influenced by the following solid-liquid interactions: a) the role of ion exchange and b) the role of both ion exchange and sorption, the latter via surface complexation with Fe(OH){sub 3}. The transport scenario with ion exchange suggests that significant ion exchange is expected to occur for Zn, Cd and Pb concentrations, with no significant impact on Hg, within the first 100 m. Predictions match the expected values of the exchange coefficients relative to Ca{sup 2+} and Mg{sup 2+} (e.g., K{sub Ca/Zn} = K{sub Ca/Cd} > K{sub Ca/Pb} > K{sub Ca/Hg}). The scenario with both ion exchange and sorption does affect the concentrations of Zn and Cd to a small extent within the first 100 m, but does more meaningfully reduce the concentration of Pb, within the same distance, and also decreases the concentration of Hg in between core holes. Analysis of the above results, in the light of available literature on the ions of this study, does fundamentally support the capability of PHREEQC to predict the transport of major ions in a groundwater setting; it also generally supports the hypothesized role of ion exchange and sorption. The results indicate the potential of the model as a tool in the screening, selection and monitoring of remediation technologies for contaminated groundwater sites. (authors)

  13. Mobility of Source Zone Heavy Metals and Radionuclides: The Mixed Roles of Fermentative Activity on Fate and Transport of U and Cr

    SciTech Connect (OSTI)

    Apel, William; Peyton, Brent; Gerlach, Robin; Lee, Brady

    2006-06-01T23:59:59.000Z

    Predicting the potential migration of metals and radionuclides from waste pits and trenches will require understanding the effects of carbon and electron flow through these environments. Important aspects of this flow include the physiological activity of cellulolytic and non-cellulolytic fermentative microbial populations, as well as the subsequent activity of metal and radionuclide reducing bacteria. The activity of subsurface fermentative microbial populations is significantly understudied even though these organisms can affect contaminant migration by at least two mechanisms. In the first mechanism, products of the fermentation process can act as chelators for metals and radionuclides increasing their transport through underlying geological media. The second mechanism is the reduction and immobilization of metals and radionuclides since some fermentative bacteria have been shown to directly reduce metals and radionuclides, while their fermentation products can provide carbon and energy for respiratory metal reducing bacteria that can also reduce oxidized metals and radionuclides.

  14. SciTech Connect: CRACK TIP PLASTICITY AND FRACTURE INITIATION...

    Office of Scientific and Technical Information (OSTI)

    N50000* --Metals, Ceramics, & Other Materials; CRACKS; FRACTURE PROPERTIES; METALS BUILDING MATERIALSfracture of metal, crack tip plasticity and initiation criteria for;...

  15. Equilibrium metal concentration at zero net sorption (EMC{sub 0}): A new concept

    SciTech Connect (OSTI)

    Yuan, G.; Lavkulich, L.M. [Univ. of British Columbia, Vancouver, British Columbia (Canada). Dept. of Soil Sciences

    1995-12-31T23:59:59.000Z

    Heavy metals in soils and waters are of environmental concerns. Since total concentration of a metal in soil is not directly related to its bioavailability, soil tests rely on measurement of extractable or labile fractions of metals. However, reagents used in the measurements are significantly different from natural waters entering soils in terms of ionic strength, acidity, and heavy metal concentration, making the direct interpretation of test results difficult if correlation between chemical test data and plant response in the field is not available. It is suggested that EMC{sub 0} be used as an indicator of heavy metal status in soils. EMC{sub 0} can be determined as follows: solutions with various metal concentrations (C{sub 0}) in 0.005 M CaCl{sub 2} matrix are added to soil samples at a fixed soil/solution ratio. The suspensions are shaken 24 hrs to achieve equilibrium, and centrifuged. Metal concentrations in supernatants are analyzed and plotted against C{sub 0}. A regression line based on plotted data an da 1:1 line are drawn. The X-axis value corresponding t the intersection of the liens is EMC{sub 0}. At the intersection, metal concentration at equilibrium equals that in the initial solution; indicating net sorption of the metal is zero. A EMC{sub 0} value of 0.27 mg/kg Zn was determined in a soil sample from the Fraser Valley in British Columbia. The soil received heavy applications of poultry manure.This value is much greater than water soluble Zn (0.06 mg/kg) of the sample. The significance of EMC{sub 0} is when concentrations of a metal in natural waters are less than EMC{sub 0}, soil will release the metal to soil solution. EMC{sub 0} may be useful in comparing relative degrees of contamination in contaminated soils.

  16. Magnetic fluctuations and heavy electron superconductivity

    SciTech Connect (OSTI)

    Norman, M.R.

    1988-01-01T23:59:59.000Z

    A magnetic fluctuation self-energy based on neutron scattering data is used to calculate mass renormalizations, and superconducting critical temperatures and order parameters, for various heavy electron metals.

  17. Effects of Adding Sewage Sludge and Urea-Phosphate Fertilizers to the Great Sippewissett Salt Marsh, Falmouth, MA on Heavy Metals and Microbial N-Cycling

    E-Print Network [OSTI]

    Vallino, Joseph J.

    in the United States is in car and industrial lead- acid batteries (Wernick & Themelis 1998). Zinc is the least is important in regulating the exchange of nitrogen through the air, soil and organic matter. In this study, the Clean Water Act and Clean Air Act were passed to help combat the increase of metal contamination

  18. Metal speciation in landfill leachates with a focus on the influence of organic matter

    SciTech Connect (OSTI)

    Claret, Francis, E-mail: f.claret@brgm.fr [BRGM, 3 avenue C. Guillemin, BP 6009, 45060 Orleans (France); Tournassat, Christophe; Crouzet, Catherine; Gaucher, Eric C. [BRGM, 3 avenue C. Guillemin, BP 6009, 45060 Orleans (France); Schaefer, Thorsten [Karlsruhe Institute of Technology (KIT), Institute for Nuclear Waste Disposal (INE), P.O. Box 3640, 76021 Karlsruhe (Germany); Freie Universitaet Berlin, Institute of Geological Sciences, Department of Earth Sciences, Hydrogeology Group, D-12249 Berlin (Germany); Braibant, Gilles; Guyonnet, Dominique [BRGM, 3 avenue C. Guillemin, BP 6009, 45060 Orleans (France)

    2011-09-15T23:59:59.000Z

    Highlights: > This study characterises the heavy-metal content in leachates collected from eight landfills in France. > Most of the metals are concentrated in the <30 kDa fraction, while Pb, Cu and Cd are associated with larger particles. > Metal complexation with OM is not sufficient to explain apparent supersaturation of metals with sulphide minerals. - Abstract: This study characterises the heavy-metal content in leachates collected from eight landfills in France. In order to identify heavy metal occurrence in the different size fractions of leachates, a cascade filtration protocol was applied directly in the field, under a nitrogen gas atmosphere to avoid metal oxidation. The results of analyses performed on the leachates suggest that most of the metals are concentrated in the <30 kDa fraction, while lead, copper and cadmium show an association with larger particles. Initial speciation calculations, without considering metal association with organic matter, suggest that leachate concentrations in lead, copper, nickel and zinc are super-saturated with respect to sulphur phases. Speciation calculations that account for metal complexation with organic matter, considered as fulvic acids based on C1(s) NEXAFS spectroscopy, show that this mechanism is not sufficient to explain such deviation from equilibrium conditions. It is therefore hypothesized that the deviation results also from the influence of biological activity on the kinetics of mineral phase precipitation and dissolution, thus providing a dynamic system. The results of chemical analyses of sampled fluids are compared with speciation calculations and some implications for the assessment of metal mobility and natural attenuation in a context of landfill risk assessment are discussed.

  19. Upgrading platform using alkali metals

    DOE Patents [OSTI]

    Gordon, John Howard

    2014-09-09T23:59:59.000Z

    A process for removing sulfur, nitrogen or metals from an oil feedstock (such as heavy oil, bitumen, shale oil, etc.) The method involves reacting the oil feedstock with an alkali metal and a radical capping substance. The alkali metal reacts with the metal, sulfur or nitrogen content to form one or more inorganic products and the radical capping substance reacts with the carbon and hydrogen content to form a hydrocarbon phase. The inorganic products may then be separated out from the hydrocarbon phase.

  20. Metal Speciation in Landfill Leachates with a Focus on the Influence of Organic Matter

    SciTech Connect (OSTI)

    F Claret; C Tournassat; C Crouzet; E Gaucher; T Schfer; G Braibant; D Guyonnet

    2011-12-31T23:59:59.000Z

    This study characterizes the heavy-metal content in leachates collected from eight landfills in France. In order to identify heavy metal occurrence in the different size fractions of leachates, a cascade filtration protocol was applied directly in the field, under a nitrogen gas atmosphere to avoid metal oxidation. The results of analyses performed on the leachates suggest that most of the metals are concentrated in the <30 kDa fraction, while lead, copper and cadmium show an association with larger particles. Initial speciation calculations, without considering metal association with organic matter, suggest that leachate concentrations in lead, copper, nickel and zinc are super-saturated with respect to sulphur phases. Speciation calculations that account for metal complexation with organic matter, considered as fulvic acids based on C1(s) NEXAFS spectroscopy, show that this mechanism is not sufficient to explain such deviation from equilibrium conditions. It is therefore hypothesized that the deviation results also from the influence of biological activity on the kinetics of mineral phase precipitation and dissolution, thus providing a dynamic system. The results of chemical analyses of sampled fluids are compared with speciation calculations and some implications for the assessment of metal mobility and natural attenuation in a context of landfill risk assessment are discussed.

  1. Adsorption of Chromium (VI) by metal hydroxide sludge from the metal finishing

    E-Print Network [OSTI]

    Paris-Sud XI, Universit de

    1 Adsorption of Chromium (VI) by metal hydroxide sludge from the metal finishing Loc Perrin Ecole sludge (MHS) during the treatment of their liquid effluents charged with heavy metals. Generally, a small part of these sludge is valorized because of their important metal fickleness. Consequently

  2. aqueous single metal: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    with water-soluble salts of heavy metals. The best results were obtained with lanthanum nitrate, uranyl acetate, and lead perchlorate. The molecules appear as filaments...

  3. ? Production in Heavy Ion Collisions at LHC

    E-Print Network [OSTI]

    Kai Zhou; Nu Xu; Pengfei Zhuang

    2014-08-19T23:59:59.000Z

    We investigate the {\\Upsilon} production in heavy ion collisions at LHC energy in the frame of a dynamical transport approach. Both the initial production and in-medium regeneration and both the cold and hot nuclear matter effects are included in the calculations. In comparison with the ground state {\\Upsilon}(1s), the excited state {\\Upsilon}(2s) is much more sensitive to the heavy quark potential at finite temperature.

  4. Probing the Symmetry Energy with Heavy Ions

    E-Print Network [OSTI]

    W. G. Lynch; M. B. Tsang; Y. Zhang; P. Danielewicz; M. Famiano; Z. Li; A. W. Steiner

    2009-01-05T23:59:59.000Z

    Constraints on the EoS for symmetric matter (equal neutron and proton numbers) at supra-saturation densities have been extracted from energetic collisions of heavy ions. Collisions of neutron-deficient and neutron-rich heavy ions now provide initial constraints on the EoS of neutron-rich matter at sub-saturation densities. Comparisons are made to other available constraints.

  5. Removal of metal ions from aqueous solution

    DOE Patents [OSTI]

    Jackson, Paul J. (Los Alamos, NM); Delhaize, Emmanuel (Los Alamos, NM); Robinson, Nigel J. (Durham, GB2); Unkefer, Clifford J. (Los Alamos, NM); Furlong, Clement (Seattle, WA)

    1990-01-01T23:59:59.000Z

    A method of removing heavy metals from aqueous solution, a composition of matter used in effecting said removal, and apparatus used in effecting said removal. One or more of the polypeptides, poly (.gamma.-glutamylcysteinyl)glycines, is immobilized on an inert material in particulate form. Upon contact with an aqueous solution containing heavy metals, the polypeptides sequester the metals, removing them from the solution. There is selectivity of poly (.gamma.-glutamylcysteinyl)glycines having a particular number of monomer repeat units for particular metals. The polypeptides are easily regenerated by contact with a small amount of an organic acid, so that they can be used again to remove heavy metals from solution. This also results in the removal of the metals from the column in a concentrated form.

  6. SCB initiator

    DOE Patents [OSTI]

    Bickes Jr., Robert W.; Renlund, Anita M.; Stanton, Philip L.

    1994-11-01T23:59:59.000Z

    A detonator for high explosives initiated by mechanical impact includes a cylindrical barrel, a layer of flyer material mechanically covering the barrel at one end, and a semiconductor bridge ignitor including a pair of electrically conductive pads connected by a semiconductor bridge. The bridge is in operational contact with the layer, whereby ignition of said bridge forces a portion of the layer through the barrel to detonate the explosive. Input means are provided for igniting the semiconductor bridge ignitor.

  7. SCB initiator

    DOE Patents [OSTI]

    Bickes, Jr., Robert W. (Albuquerque, NM); Renlund, Anita M. (Albuquerque, NM); Stanton, Philip L. (Albuquerque, NM)

    1994-01-01T23:59:59.000Z

    A detonator for high explosives initiated by mechanical impact includes a cylindrical barrel, a layer of flyer material mechanically covering the barrel at one end, and a semiconductor bridge ignitor including a pair of electrically conductive pads connected by a semiconductor bridge. The bridge is in operational contact with the layer, whereby ignition of said bridge forces a portion of the layer through the barrel to detonate the explosive. Input means are provided for igniting the semiconductor bridge ignitor.

  8. ORIGINAL ARTICLE The study of metal contamination in urban topsoils of Mexico City

    E-Print Network [OSTI]

    Short, Daniel

    - politan area of Mexico City. Keywords Heavy metals Á GIS Á Mexico City Á Urban topsoils Á Pollution ÁORIGINAL ARTICLE The study of metal contamination in urban topsoils of Mexico City using GIS Mari distribution of heavy metals (Pb, Cu, Zn, Ba, Co, Cr, Ni and V) in the urban environments of Mexico City using

  9. Exploiting heavy oil reserves

    E-Print Network [OSTI]

    Levi, Ran

    North Sea investment potential Exploiting heavy oil reserves Beneath the waves in 3D Aberdeen the potential of heavy oil 8/9 Taking the legal lessons learned in the north Sea to a global audience 10 potential Exploiting heavy oil reserves Aberdeen: A community of science AT WORK FOR THE ENERGY SECTOR ISSUE

  10. Definition of heavy oil and natural bitumen

    SciTech Connect (OSTI)

    Meyer, R.F.

    1988-08-01T23:59:59.000Z

    Definition and categorization of heavy oils and natural bitumens are generally based on physical or chemical attributes or on methods of extraction. Ultimately, the hydrocarbon's chemical composition will govern both its physical state and the extraction technique applicable. These oils and bitumens closely resemble the residuum from wholecrude distillation to about 1,000/degree/F; if the residuum constitutes at least 15% of the crude, it is considered to be heavy. In this material is concentrated most of the trace elements, such as sulfur, oxygen, and nitrogen, and metals, such as nickel and vanadium. A widely used definition separates heavy oil from natural bitumen by viscosity, crude oil being less, and bitumen more viscous than 10,000 cp. Heavy crude then falls in the range 10/degree/-20/degree/ API inclusive and extra-heavy oil less than 10/degree/ API. Most natural bitumen is natural asphalt (tar sands, oil sands) and has been defined as rock containing hydrocarbons more viscous than 10,000 cp or else hydrocarbons that may be extracted from mined or quarried rock. Other natural bitumens are solids, such as gilsonite, grahamite, and ozokerite, which are distinguished by streak, fusibility, and solubility. The upper limit for heavy oil may also be set at 18/degree/ API, the approximate limit for recovery by waterflood.

  11. Initial Proposal

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHigh SchoolIn Other News linkThermal PhenomenaInitial

  12. Causal dissipative hydrodynamics for heavy ion collisions

    E-Print Network [OSTI]

    Chaudhuri, A K

    2011-01-01T23:59:59.000Z

    We briefly discuss the recent developments in causal dissipative hydrodynamic for relativistic heavy ion collisions. Phenomenological estimate of QGP viscosity over entropy ratio from several experimental data, e.g. STAR's $\\phi$ meson data, centrality dependence of elliptic flow, universal scaling elliptic flow etc. are discussed. QGP viscosity, extracted from hydrodynamical model analysis can have very large systematic uncertainty due to uncertain initial conditions.

  13. Causal dissipative hydrodynamics for heavy ion collisions

    E-Print Network [OSTI]

    A. K. Chaudhuri

    2011-01-23T23:59:59.000Z

    We briefly discuss the recent developments in causal dissipative hydrodynamic for relativistic heavy ion collisions. Phenomenological estimate of QGP viscosity over entropy ratio from several experimental data, e.g. STAR's $\\phi$ meson data, centrality dependence of elliptic flow, universal scaling elliptic flow etc. are discussed. QGP viscosity, extracted from hydrodynamical model analysis can have very large systematic uncertainty due to uncertain initial conditions.

  14. Stabilization of Electrocatalytic Metal Nanoparticles at Metal...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electrocatalytic Metal Nanoparticles at Metal-Metal Oxide-Graphene Triple Junction Points. Stabilization of Electrocatalytic Metal Nanoparticles at Metal-Metal Oxide-Graphene...

  15. Heavy Ion Fusion Science Virtual National Laboratory 4th Quarter 2009 Milestone Report: Measure and simulate target temperature and dynamic response in optimized NDCX-I configurations with initial diagnostics suite

    SciTech Connect (OSTI)

    Bieniosek, F.M.; Barnard, J.J.; Henestroza, E.; Logan, B.G.; Lidia, S.; More, R.M.; Ni, P.A.; Seidl, P.A.; Vay, J.-L.; Grote, D.; Friedman, A.

    2009-09-30T23:59:59.000Z

    This milestone has been met. The effort contains two main components: (1) Experimental results of warm dense matter target experiments on optimized NDCX-I configurations that include measurements of target temperature and transient target behavior. (2) A theoretical model of the target response to beam heating that includes an equilibrium heating model of the target foil and a model for droplet formation in the target for comparison with experimental results. The experiments on ion-beam target heating use a 300-350-keV K{sup +} pulsed beam from the Neutralized Compression Drift Experiment (NDCX-I) accelerator at LBNL. The NDCX-I accelerator delivers an uncompressed pulse beam of several microseconds with a typical power density of >100 kW/cm{sup 2} over a final focus spot size of about 1 mm. An induction bunching module the NDCX-I compresses a portion of the beam pulse to reach a much higher power density over 2 nanoseconds. Under these conditions the free-standing foil targets are rapidly heated to temperatures to over 4000 K. We model the target thermal dynamics using the equation of heat conduction for the temperature T(x,t) as a function of time (t) and spatial dimension along the beam direction (x). The competing cooling processes release energy from the surface of the foil due to evaporation, radiation, and thermionic (Richardson) emission. A description of the experimental configuration of the target chamber and results from initial beam-target experiments are reported in our FY08 4th Quarter and FY09 2nd Quarter Milestone Reports. The WDM target diagnostics include a high-speed multichannel optical pyrometer, optical streak camera, VISAR, and high-speed gated cameras. The fast optical pyrometer is a unique and significant new diagnostic which provides valuable information on the temperature evolution of the heated target.

  16. Relics of metal-free low mass stars exploding as thermonuclear supernovae

    E-Print Network [OSTI]

    Takuji Tsujimoto; Toshikazu Shigeyama

    2006-01-16T23:59:59.000Z

    Renewed interest in the first stars that were formed in the universe has led to the discovery of extremely iron-poor stars. Since several competing scenarios exist, our understanding of the mass range that determines the observed elemental abundances remains unclear. In this study, we consider three well-studied metal-poor stars in terms of the theoretical supernovae (SNe) model. Our results suggest that the observed abundance patterns in the metal-poor star BD +80 245 and the pair of stars HD 134439/40 agree strongly with the theoretical possibility that these stars inherited their heavy element abundance patterns from SNe initiated by thermonuclear runaways in the degenerate carbon-oxygen cores of primordial asymptotic giant branch stars with \\~3.5-5 solar masses. Recent theoretical calculations have predicted that such SNe could be originated from metal-free stars in the intermediate mass range. On the other hand, intermediate mass stars containing some metals would end their lives as white dwarfs after expelling their envelopes in the wind due to intense momentum transport from outgoing photons to heavy elements. This new pathway for the formation of SNe requires that stars are formed from the primordial gas. Thus, we suggest that stars of a few solar masses were formed from the primordial gas and that some of them caused thermonuclear explosions when the mass of their degenerate carbon-oxygen cores increased to the Chandrasekhar limit without experiencing efficient mass loss.

  17. Removal of metal ions from aqueous solution

    DOE Patents [OSTI]

    Jackson, Paul J. (both Los Alamos, NM); Delhaize, Emmanuel (both Los Alamos, NM); Robinson, Nigel J. (Durham, GB2); Unkefer, Clifford J. (Los Alamos, NM); Furlong, Clement (Seattle, WA)

    1990-11-13T23:59:59.000Z

    A method of removing heavy metals from aqueous solution, a composition of matter used in effecting said removal, and apparatus used in effecting said removal. One or more of the polypeptides, poly (.gamma.-glutamylcysteinyl)glycines, is immobilized on an inert material in particulate form. Upon contact with an aqueous solution containing heavy metals, the polypeptides sequester the metals, removing them from the solution. There is selectivity of poly (.gamma.-glutamylcysteinyl)glycines having a particular number of monomer repeat unit for particular metals. The polypeptides are easily regenerated by contact with a small amount of an organic acid, so that they can be used again to remove heayv metals from solution. This also results in the removal of the metals from the column in a concentrated form.

  18. Effect of GOR, Temperature, and Initial Water Saturation on Solution-Gas Drive in

    E-Print Network [OSTI]

    Firoozabadi, Abbas

    Effect of GOR, Temperature, and Initial Water Saturation on Solution-Gas Drive in Heavy-Oil have carried out an extensive set of tests on solution-gas drive for a heavy oil to study the effects was approximately 16% and higher. Introduction Solution-gas drive from some heavy oil reservoirs in Canada, Ven

  19. Heavy electron superconductivity: From 1K to 90K to

    SciTech Connect (OSTI)

    Pethick, C.J.; Pines, D.

    1987-01-01T23:59:59.000Z

    This paper reviews the experimental results and physical arguments which led us to conclude that in heavy electron systems the physical mechanism responsible for superconductivity is an attractive interaction between the heavy electrons which results from the virtual exchange of antiferromagnetic f-electron moment fluctuations. In these systems, then, the superconductivity is of purely electronic origin; the phonon-induced interaction between electrons which leads to superconductivity in ordinary metals plays little or no role.

  20. The mass-metallicity relation of tidal dwarf galaxies

    E-Print Network [OSTI]

    Recchi, S; Ploeckinger, S

    2015-01-01T23:59:59.000Z

    Dwarf galaxies generally follow a mass-metallicity (MZ) relation, where more massive objects retain a larger fraction of heavy elements. Young tidal dwarf galaxies (TDGs), born in the tidal tails produced by interacting gas-rich galaxies, have been thought to not follow the MZ relation, because they inherit the metallicity of the more massive parent galaxies. We present chemical evolution models to investigate if TDGs that formed at very high redshifts, where the metallicity of their parent galaxy was very low, can produce the observed MZ relation. Assuming that galaxy interactions were more frequent in the denser high-redshift universe, TDGs could constitute an important contribution to the dwarf galaxy population. The survey of chemical evolution models of TDGs presented here captures for the first time an initial mass function (IMF) of stars that is dependent on both the star formation rate and the gas metallicity via the integrated galactic IMF (IGIMF) theory. As TDGs form in the tidal debris of interacti...

  1. Hydrotreating Uinta Basin bitumen-derived heavy oils

    SciTech Connect (OSTI)

    Longstaff, D.C.; Balaji, G.V.; Kim, J.W. [Univ. of Utah, Salt Lake City, UT (United States)] [and others

    1995-12-31T23:59:59.000Z

    Heavy oils derived from Uinta Basin bitumens have been hydrotreated under varying conditions. The process variables investigated included total reactor pressure (11.0-16.9 MPa), reactor temperature (616-711 K), feed rate (0.29-1.38 WHSV), and catalyst composition. The extent of heteroatom removal and residuum conversion were determined by the feed molecular weight and catalyst selection. Catalytic activity for heteroatom conversion removal was primarily influenced by metal loading. The heteroatom removal activity of the catalysts studied were ranked HDN catalysts > HDM catalysts > HDN-support. Catalytic activity for residuum conversion was influenced by both metal loading and catalyst surface area. The residuum conversion activity of HDN catalysts were always higher than the activity of HDM catalysts and HDN supports. The residuum conversion activity of HDN-supports surpassed the activity of HDM catalyst at higher temperatures. The conversions achieved with HDN catalysts relative to the HDM catalysts indicated that the low metals contents of the Uinta Basin bitumens obviate the need for hydrodemetallation as an initial upgrading step with these bitumens. The upgrading of Uinta Basin bitumens for integration into refinery feed slates should emphasize molecular weight and boiling range reduction first, followed by hydrotreating of the total liquid product produced in the pyrolysis process. Kinetics of residuum conversion can be modeled by invoking a consecutive-parallel mechanism in which native residuum in the feed is rapidly converted to volatile products and to product residuum. Deep conversion of residuum is only achieved when the more refractory product residuum is converted to volatile products.

  2. Nucleic acids encoding metal uptake transporters and their uses

    DOE Patents [OSTI]

    Schroeder, Julian I. (La Jolla, CA); Antosiewicz, Danuta M. (Warsaw, PL); Schachtman, Daniel P. (Tranmere, AU); Clemens, Stephan (San Diego, CA)

    1999-01-01T23:59:59.000Z

    The invention provides LCT1 nucleic acids which encode metal ion uptake transporters. The invention also provides methods of modulating heavy metal and alkali metal uptake in plants. The methods involve producing transgenic plants comprising a recombinant expression cassette containing an LCT1 nucleic acid linked to a plant promoter.

  3. ONDES DE SPIN MAGNETISM IN THE LIGHT RARE EARTH 'METALS

    E-Print Network [OSTI]

    Boyer, Edmond

    ONDES DE SPIN MAGNETISM IN THE LIGHT RARE EARTH 'METALS A. R. MACKINTOSH H. C. Mrsted Institute terres rares Ikgeres. Abstract. -The magnetic properties of the light rare earth metals are reviewed the last decade, the magnetism of the heavy rare earth metals is now rather well understood. The magnetic

  4. Developments in bioremediation of soils and sediments polluted with metals and radionuclides: 2. Field research on bioremediation of metals

    E-Print Network [OSTI]

    Hazen, Terry

    Developments in bioremediation of soils and sediments polluted with metals and radionuclides: 2. Field research on bioremediation of metals and radionuclides Terry C. Hazen1, * & Henry H. Tabak2 1 for correspondence e-mail: tchazen@lbl.gov) Key words: heavy metal, radionuclide, field test, bioremediation

  5. HEAVY-ION RADIOGRAPHY AND HEAVY-ION COMPUTED TOMOGRAPHY

    E-Print Network [OSTI]

    Fabrikant, J.I.

    2010-01-01T23:59:59.000Z

    RADIOGRAPHY AND HEAVY-ION COMPUTED TOMOGRAPHY 1,2 Jacob I .RADIOGRAPHY AND HEAVY-ION COMPUTED TOMOGRAPHY J I Fabrikant,

  6. Metal aminoboranes

    DOE Patents [OSTI]

    Burrell, Anthony K.; Davis, Benjamin J.; Thorn, David L.; Gordon, John C.; Baker, R. Thomas; Semelsberger, Troy Allen; Tumas, William; Diyabalanage, Himashinie Vichalya; Shrestha, Roshan P.

    2010-05-11T23:59:59.000Z

    Metal aminoboranes of the formula M(NH2BH3)n have been synthesized. Metal aminoboranes are hydrogen storage materials. Metal aminoboranes are also precursors for synthesizing other metal aminoboranes. Metal aminoboranes can be dehydrogenated to form hydrogen and a reaction product. The reaction product can react with hydrogen to form a hydrogen storage material. Metal aminoboranes can be included in a kit.

  7. Relativistic heavy ion research

    SciTech Connect (OSTI)

    Nagamiya, Shoji.

    1992-01-01T23:59:59.000Z

    This report discusses the following topics: antiproton production; Bose-Einstein correlations; high-transverse momentum spectra; strangeness enhancement in heavy ion collisions; search for rare negative secondaries of antiprotons and antinuclei produced in heavy ion collisions; quark matter; and time-of-flight systems test at Brookhaven AGS. (LSP).

  8. From The Boston Globe, February 22, 2008 Dance troupe is game for some heavy lifting

    E-Print Network [OSTI]

    Machery, Edouard

    From The Boston Globe, February 22, 2008 Dance troupe is game for some heavy lifting From left and uses heavy steel pieces as props? A game-show story? Who are these people? "Ideally, we're a mix beyond the industry, but steel is part of the soul of the town. . . . When the metal is molten and hot

  9. Single-layer transition metal sulfide catalysts

    DOE Patents [OSTI]

    Thoma, Steven G. (Albuquerque, NM)

    2011-05-31T23:59:59.000Z

    Transition Metal Sulfides (TMS), such as molybdenum disulfide (MoS.sub.2), are the petroleum industry's "workhorse" catalysts for upgrading heavy petroleum feedstocks and removing sulfur, nitrogen and other pollutants from fuels. We have developed an improved synthesis technique to produce SLTMS catalysts, such as molybdenum disulfide, with potentially greater activity and specificity than those currently available. Applications for this technology include heavy feed upgrading, in-situ catalysis, bio-fuel conversion and coal liquefaction.

  10. Upgrading of petroleum oil feedstocks using alkali metals and hydrocarbons

    DOE Patents [OSTI]

    Gordon, John Howard

    2014-09-09T23:59:59.000Z

    A method of upgrading an oil feedstock by removing heteroatoms and/or one or more heavy metals from the oil feedstock composition. This method reacts the oil feedstock with an alkali metal and an upgradant hydrocarbon. The alkali metal reacts with a portion of the heteroatoms and/or one or more heavy metals to form an inorganic phase separable from the organic oil feedstock material. The upgradant hydrocarbon bonds to the oil feedstock material and increases the number of carbon atoms in the product. This increase in the number of carbon atoms of the product increases the energy value of the resulting oil feedstock.

  11. EVOLUTION OF THE HIGH-MASS END OF THE STELLAR INITIAL MASS FUNCTIONS IN STARBURST GALAXIES

    SciTech Connect (OSTI)

    Bekki, Kenji; Meurer, Gerhardt R. [ICRAR, M468, The University of Western Australia, 35 Stirling Highway, Crawley, WA 6009 (Australia)

    2013-03-01T23:59:59.000Z

    We investigate the time evolution and spatial variation of the stellar initial mass function (IMF) in star-forming disk galaxies by using chemodynamical simulations with an IMF model depending both on local densities and metallicities ([Fe/H]) of the interstellar medium (ISM). We find that the slope ({alpha}) of a power-law IMF (N(m){proportional_to}m {sup -{alpha}}) for stellar masses larger than 1 M{sub Sun} evolves from the canonical Salpeter IMF ({alpha} Almost-Equal-To 2.35) to be moderately top-heavy one ({alpha} Almost-Equal-To 1.9) in the simulated disk galaxies with starbursts triggered by galaxy interaction. We also find that {alpha} in star-forming regions correlates with star formation rate densities ({Sigma}{sub SFR} in units of M{sub Sun} yr{sup -1} kpc{sup -2}). Feedback effects of Type Ia and II supernovae are found to prevent IMFs from being too top-heavy ({alpha} < 1.5). The simulation predicts {alpha} Almost-Equal-To 0.23log {Sigma}{sub SFR} + 1.7 for log {Sigma}{sub SFR} {>=} -2 (i.e., more top-heavy in higher {Sigma}{sub SFR}), which is reasonably consistent with corresponding recent observational results. The present study also predicts that inner regions of starburst disk galaxies have smaller {alpha} and thus are more top-heavy (d{alpha}/dR {approx} 0.07 kpc{sup -1} for R {<=} 5 kpc). The predicted radial {alpha} gradient can be tested against future observational studies of the {alpha} variation in star-forming galaxies.

  12. On possible $?$ vacua states in heavy ion collisions

    E-Print Network [OSTI]

    A. K. Chaudhuri

    2000-12-06T23:59:59.000Z

    We have simulated the possible $\\Theta$ vacua states in heavy ion collisions. In a quench like scenario, random phases of the chiral fields were evolved in a zero temperature potential incorporating the breaking of $U_A(1)$ symmetry. Initial random phases very quickly settles into oscillation around the values dictated by the potential. The simulation indicate that $\\Theta$ vacua states that can be populated in heavy ion collisions is a coherent superposition of a number of modes.

  13. HEAVY ION INERTIAL FUSION

    E-Print Network [OSTI]

    Keefe, D.

    2008-01-01T23:59:59.000Z

    Accelerators as Drivers for Inertially Confined Fusion, W.B.LBL-9332/SLAC-22l (1979) Fusion Driven by Heavy Ion Beams,OF CALIFORNIA f Accelerator & Fusion Research Division

  14. FY 80 heavy oil program. Second quarterly report, April 1980

    SciTech Connect (OSTI)

    Wayland, J.R.; Fox, R.L.

    1980-06-01T23:59:59.000Z

    The research and development efforts in support of the heavy oil program reservoir access and alternate extraction activities that were initiated last quarter have been continued and expanded. The development of a short course on the utilization of specialized drilling technology to heavy oil sands has been investigated. The steam quality sampler is undergoing laboratory testing. A special report on possible application of sand control methods to heavy oil steam injection tests has been prepared. The first stage of the analysis of R.F. and microwave heating has been completed. The results of a series of laboratory experiments on in situ hydrogenation are presented.

  15. Metal inks

    DOE Patents [OSTI]

    Ginley, David S; Curtis, Calvin J; Miedaner, Alex; van Hest, Marinus Franciscus Antonius Maria; Kaydanova, Tatiana

    2014-02-04T23:59:59.000Z

    Self-reducing metal inks and systems and methods for producing and using the same are disclosed. In an exemplary embodiment, a method may comprise selecting metal-organic (MO) precursor, selecting a reducing agent, and dissolving the MO precursor and the reducing agent in an organic solvent to produce a metal ink that remains in a liquid phase at room temperature. Metal inks, including self-reducing and fire-through metal inks, are also disclosed, as are various applications of the metal inks.

  16. Silicone metalization

    DOE Patents [OSTI]

    Maghribi, Mariam N. (Livermore, CA); Krulevitch, Peter (Pleasanton, CA); Hamilton, Julie (Tracy, CA)

    2008-12-09T23:59:59.000Z

    A system for providing metal features on silicone comprising providing a silicone layer on a matrix and providing a metal layer on the silicone layer. An electronic apparatus can be produced by the system. The electronic apparatus comprises a silicone body and metal features on the silicone body that provide an electronic device.

  17. Direct laser initiation of PETN

    SciTech Connect (OSTI)

    Early, J. W. (James W.); Kennedy, J. E. (James E.)

    2001-01-01T23:59:59.000Z

    In the early 1970s Yang and Menichelli demonstrated that direct laser illumination of low-density secondary explosive prr:ssings through a transparent window could produce detonation. 'The energy requirement for threshold initiation of detonation was reduced when a thin metal coating of metal covered the side of the window against which the low-density explosive was pressed. We have obtained experimental results that are in general agreement with the results of Renllund, Stanton and Trott (1 989) and recent: work by Nagayama, hou and Nakahara (2001). We report exploration of the effects of laser beam diameter, PEiTN density and specific surface area, and thickness of a titanium coating on the window.

  18. Creation and Testing of the ACES Heavy Heavy-Duty Diesel Engine...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Testing of the ACES Heavy Heavy-Duty Diesel Engine Test Schedule for Representative Measurement of Heavy-Duty Engine Emissions Creation and Testing of the ACES Heavy Heavy-Duty...

  19. Heavy Quark production at HERA and Heavy Quark contributions

    E-Print Network [OSTI]

    Detlef Bartsch, University of Bonn on behalf of the ZEUS and H1 Collaborations · Introduction · Heavy 1500 0 100 200 300 400 electrons positrons low E HERA-1 HERA-2 Detlef Bartsch Heavy Quark production Detlef Bartsch Heavy Quark production at HERA, Feb. 23rd 2008 3 #12;pQCD approximations Massive scheme

  20. Heavy-light quarks interactions in QCD vacuum

    E-Print Network [OSTI]

    Mirzayusuf Musakhanov

    2015-03-20T23:59:59.000Z

    QCD vacuum instantons induce very strong interactions between light quarks, which generate large dynamical light quark mass M for initially almost massless quarks and can bound these quarks to produce almost massless pions in accordance with the spontaneous breaking of chiral symmetry (S\\chiSB). On the other hand, the QCD vacuum instantons generate heavy-light quark interactions terms, which are responsible for the effects of S\\chiSB in a heavy-light quark system. Summing the re-scattering series that lead to the total light quark propagator and making few further steps, we get the fermionized representation of low-frequencies light quark determinant in the presence of the quark sources, which is relevant for our problems. The next important step in the line of this strategy is to derive the equation and calculate the heavy quark propagator in the instanton media and in the presence of light quarks. This one provide finally the heavy and N_f light quarks interaction term. As an example, we derive heavy quark-light mesons interaction term for the N_f=2 case. If we take the average instanton size \\rho=0.35 fm, and average inter-instanton distance R=0.856 fm from our previous estimates, we obtain at LO on 1/N_c expansion dynamical light quark mass M = 570 MeV and instanton media contribution to heavy quark mass \\Delta M=148 MeV. These factors define the coupling between heavy and light quarks and, certainly, between heavy quarks and light mesons. We will apply this approach to heavy quark and heavy-light quark systems.

  1. Method for mobilization of hazardous metal ions in soils

    DOE Patents [OSTI]

    Dugan, Patrick R. (Idaho Falls, ID); Pfister, Robert M. (Powell, OH)

    1995-01-01T23:59:59.000Z

    A microbial process for removing heavy metals such as bismuth, cadmium, lead, thorium, uranium and other transuranics from soils and sediments, utilizing indigenous, or isolates of indigenous, microorganisms and reducing agents, such as cysteine or sodium thioglycollate, or complexing agents such as the amino acid glycine, to effect the mobilization or release of the metals from the soil particles.

  2. Metals in Municipal Landfill Leachate And Their Health Effects

    E-Print Network [OSTI]

    Laughlin, Robert B.

    raw leachate contains concentrations of heavy metals in excess ofthe drinking water standards of the un- saturated zone. If municipal solid waste is placed di- rectly into ground water, or if leachateMetals in Municipal Landfill Leachate And Their Health Effects STEPHEN C. JAMES, BS, MSCE Abstract

  3. Heavy Vehicle Systems

    SciTech Connect (OSTI)

    Sid Diamond; Richard Wares; Jules Routbort

    2000-04-11T23:59:59.000Z

    Heavy Vehicle (HV) systems are a necessary component of achieving OHVT goals. Elements are in place for a far-ranging program: short, intermediate, and long-term. Solicitation will bring industrial input and support. Future funding trend is positive, outlook for HV systems is good.

  4. Heavy Quark Physics

    E-Print Network [OSTI]

    Paul B. Mackenzie

    1992-12-14T23:59:59.000Z

    Lattice calculations of heavy quark systems provide very good measures of the lattice spacing, a key element in recent determinations of the strong coupling constant using lattice methods. They also provide excellent testing grounds for lattice methods in general. I review recent phenomenological and technical developments in this field.

  5. Reversing a heavy-ion collision

    E-Print Network [OSTI]

    Mikhail Stephanov; Yi Yin

    2014-04-23T23:59:59.000Z

    We introduce a novel approach to study the longitudinal hydrodynamic expansion of the quark-gluon fluid created in heavy-ion collisions. It consists of two steps: First, we apply the maximum entropy method to reconstruct the freeze-out surface from experimentally measured particle distribution. We then take the output of the reconstruction as the "initial" condition to evolve the system back in time by solving the 1+1 ideal hydrodynamic equations analytically, using the method of Khalatnikov and Landau. We find an approximate Bjorken-like plateau in the energy density vs rapidity profile at the early times, which shrinks with time as the boundary shocks propagate inward. In Bjorken frame, the fluid velocity is close to zero within the plateau, as in the Bjorken solution, but increases outside the plateau. The results carry implications for fully numerical hydrodynamic simulations as well as models of heavy-ion collisions based on gauge-gravity duality.

  6. Sink property of metallic glass free surfaces

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Shao, Lin; Fu, Engang; Price, Lloyd; Chen, Di; Chen, Tianyi; Wang, Yongqiang; Xie, Guoqiang; Lucca, Don A.

    2015-03-16T23:59:59.000Z

    When heated to a temperature close to glass transition temperature, metallic glasses (MGs) begin to crystallize. Under deformation or particle irradiation, crystallization occurs at even lower temperatures. Hence, phase instability represents an application limit for MGs. Here, we report that MG membranes of a few nanometers thickness exhibit properties different from their bulk MG counterparts. The study uses in situ transmission electron microscopy with concurrent heavy ion irradiation and annealing to observe crystallization behaviors of MGs. For relatively thick membranes, ion irradiations introduce excessive free volumes and thus induce nanocrystal formation at a temperature linearly decreasing with increasing ion fluences.moreFor ultra-thin membranes, however, the critical temperature to initiate crystallization is about 100 K higher than the bulk glass transition temperature. Molecular dynamics simulations indicate that this effect is due to the sink property of the surfaces which can effectively remove excessive free volumes. These findings suggest that nanostructured MGs having a higher surface to volume ratio are expected to have higher crystallization resistance, which could pave new paths for materials applications in harsh environments requiring higher stabilities.less

  7. Coordination chemistry of two heavy metals: I, Ligand preferences in lead(II) complexation, toward the development of therapeutic agents for lead poisoning: II, Plutonium solubility and speciation relevant to the environment

    SciTech Connect (OSTI)

    Neu, M.P. [Lawrence Berkeley Lab., CA (United States)

    1993-11-01T23:59:59.000Z

    The coordination chemistry and solution behavior of the toxic ions lead(II) and plutonium(IV, V, VI) have been investigated. The ligand pK{sub a}s and ligand-lead(II) stability constants of one hydroxamic acid and four thiohydroaxamic acids were determined. Solution thermodynamic results indicate that thiohydroxamic acids are more acidic and slightly better lead chelators than hydroxamates, e.g., N-methylthioaceto-hydroxamic acid, pK{sub a} = 5.94, log{beta}{sub 120} = 10.92; acetohydroxamic acid, pK{sub a} = 9.34, log{beta}{sub l20} = 9.52. The syntheses of lead complexes of two bulky hydroxamate ligands are presented. The X-ray crystal structures show the lead hydroxamates are di-bridged dimers with irregular five-coordinate geometry about the metal atom and a stereochemically active lone pair of electrons. Molecular orbital calculations of a lead hydroxamate and a highly symmetric pseudo octahedral lead complex were performed. The thermodynamic stability of plutonium(IV) complexes of the siderophore, desferrioxamine B (DFO), and two octadentate derivatives of DFO were investigated using competition spectrophotometric titrations. The stability constant measured for the plutonium(IV) complex of DFO-methylterephthalamide is log{beta}{sub 110} = 41.7. The solubility limited speciation of {sup 242}Pu as a function of time in near neutral carbonate solution was measured. Individual solutions of plutonium in a single oxidation state were added to individual solutions at pH = 6.0, T = 30.0, 1.93 mM dissolved carbonate, and sampled over intervals up to 150 days. Plutonium solubility was measured, and speciation was investigated using laser photoacoustic spectroscopy and chemical methods.

  8. MONTANA PALLADIUM RESEARCH INITIATIVE

    SciTech Connect (OSTI)

    Peters, John

    2012-05-09T23:59:59.000Z

    Project Objective: The overarching objective of the Montana Palladium Research Initiative is to perform scientific research on the properties and uses of palladium in the context of the U.S. Department of Energy'????????????????s Hydrogen, Fuel Cells and Infrastructure Technologies Program. The purpose of the research will be to explore possible palladium as an alternative to platinum in hydrogen-economy applications. To achieve this objective, the Initiatives activities will focus on several cutting-edge research approaches across a range of disciplines, including metallurgy, biomimetics, instrumentation development, and systems analysis. Background: Platinum-group elements (PGEs) play significant roles in processing hydrogen, an element that shows high potential to address this need in the U.S. and the world for inexpensive, reliable, clean energy. Platinum, however, is a very expensive component of current and planned systems, so less-expensive alternatives that have similar physical properties are being sought. To this end, several tasks have been defined under the rubric of the Montana Palladium Research Iniative. This broad swath of activities will allow progress on several fronts. The membrane-related activities of Task 1 employs state-of-the-art and leading-edge technologies to develop new, ceramic-substrate metallic membranes for the production of high-purity hydrogen, and develop techniques for the production of thin, defect-free platinum group element catalytic membranes for energy production and pollution control. The biomimetic work in Task 2 explores the use of substrate-attached hydrogen-producing enzymes and the encapsulation of palladium in virion-based protein coats to determine their utility for distributed hydrogen production. Task 3 work involves developing laser-induced breakdown spectroscopy (LIBS) as a real-time, in situ diagnostic technique to characterize PGEs nanoparticles for process monitoring and control. The systems engineering work in task 4 will determine how fuel cells ????????????????taken as systems behave over periods of time that should show how their reformers and other subsystems deteriorate with time.

  9. Metal binding proteins, recombinant host cells and methods

    DOE Patents [OSTI]

    Summers, Anne O.; Caguiat, Jonathan J.

    2004-06-15T23:59:59.000Z

    The present disclosure provides artificial heavy metal binding proteins termed chelons by the inventors. These chelons bind cadmium and/or mercuric ions with relatively high affinity. Also disclosed are coding sequences, recombinant DNA molecules and recombinant host cells comprising those recombinant DNA molecules for expression of the chelon proteins. In the recombinant host cells or transgenic plants, the chelons can be used to bind heavy metals taken up from contaminated soil, groundwater or irrigation water and to concentrate and sequester those ions. Recombinant enteric bacteria can be used within the gastrointestinal tracts of animals or humans exposed to toxic metal ions such as mercury and/or cadmium, where the chelon recombinantly expressed in chosen in accordance with the ion to be rededicated. Alternatively, the chelons can be immobilized to solid supports to bind and concentrate heavy metals from a contaminated aqueous medium including biological fluids.

  10. Relics of metal-free low mass stars exploding as thermonuclear supernovae

    E-Print Network [OSTI]

    Tsujimoto, T; Tsujimoto, Takuji; Shigeyama, Toshikazu

    2006-01-01T23:59:59.000Z

    Renewed interest in the first stars that were formed in the universe has led to the discovery of extremely iron-poor stars. Since several competing scenarios exist, our understanding of the mass range that determines the observed elemental abundances remains unclear. In this study, we consider three well-studied metal-poor stars in terms of the theoretical supernovae (SNe) model. Our results suggest that the observed abundance patterns in the metal-poor star BD +80 245 and the pair of stars HD 134439/40 agree strongly with the theoretical possibility that these stars inherited their heavy element abundance patterns from SNe initiated by thermonuclear runaways in the degenerate carbon-oxygen cores of primordial asymptotic giant branch stars with \\~3.5-5 solar masses. Recent theoretical calculations have predicted that such SNe could be originated from metal-free stars in the intermediate mass range. On the other hand, intermediate mass stars containing some metals would end their lives as white dwarfs after ex...

  11. Uptake and Cellular Compartmentalization of Metals from the Rhizosphere by Hyperaccumulating Plants: A Real Time

    E-Print Network [OSTI]

    Sparks, Donald L.

    Uptake and Cellular Compartmentalization of Metals from the Rhizosphere by Hyperaccumulating Plants in hyperaccumulating plants. Previous attempts to establish the path of metal ingress into plant tissues have suffered-vivo response of plants to heavy metals in the rhizosphere. We first focused on characterizing the species

  12. Color-magnitude relations within globular cluster systems of giant elliptical galaxies: The effects of globular cluster mass loss and the stellar initial mass function

    SciTech Connect (OSTI)

    Goudfrooij, Paul [Space Telescope Science Institute, 3700 San Martin Drive, Baltimore, MD 21218 (United States); Kruijssen, J. M. Diederik, E-mail: goudfroo@stsci.edu, E-mail: kruijssen@mpa-garching.mpg.de [Max-Planck Institut fr Astrophysik, Karl-Schwarzschild-Str. 1, D-85741 Garching (Germany)

    2014-01-01T23:59:59.000Z

    Several recent studies have provided evidence for a 'bottom-heavy' stellar initial mass function (IMF) in massive elliptical galaxies. Here we investigate the influence of the IMF shape on the recently discovered color-magnitude relation (CMR) among globular clusters (GCs) in such galaxies. To this end we use calculations of GC mass loss due to stellar and dynamical evolution to evaluate (1) the shapes of stellar mass functions in GCs after 12 Gyr of evolution as a function of current GC mass along with their effects on integrated-light colors and mass-to-light ratios, and (2) their impact on the effects of GC self-enrichment using the 2009 'reference' model of Bailin and Harris. As to the class of metal-poor GCs, we find the observed shape of the CMR (often referred to as the 'blue tilt') to be very well reproduced by Bailin and Harris's reference self-enrichment model once 12 Gyr of GC mass loss is taken into account. The influence of the IMF on this result is found to be insignificant. However, we find that the observed CMR among the class of metal-rich GCs (the 'red tilt') can only be adequately reproduced if the IMF was bottom-heavy (3.0 ? ? ? 2.3 in dN/dM?M{sup ?}), which causes the stellar mass function at subsolar masses to depend relatively strongly on GC mass. This constitutes additional evidence that the metal-rich stellar populations in giant elliptical galaxies were formed with a bottom-heavy IMF.

  13. Heavy Vehicle Propulsion Materials

    SciTech Connect (OSTI)

    Ray Johnson

    2000-01-31T23:59:59.000Z

    The objectives are to Provide Key Enabling Materials Technologies to Increase Energy Efficiency and Reduce Exhaust Emissions. The following goals are listed: Goal 1: By 3rd quarter 2002, complete development of materials enabling the maintenance or improvement of fuel efficiency {ge} 45% of class 7-8 truck engines while meeting the EPA/Justice Department ''Consent Decree'' for emissions reduction. Goal 2: By 4th quarter 2004, complete development of enabling materials for light-duty (class 1-2) diesel truck engines with efficiency over 40%, over a wide range of loads and speeds, while meeting EPA Tier 2 emission regulations. Goal 3: By 4th quarter 2006, complete development of materials solutions to enable heavy-duty diesel engine efficiency of 50% while meeting the emission reduction goals identified in the EPA proposed rule for heavy-duty highway engines.''

  14. Metal Oxide Semiconductor Nanoparticles Open the Door to New...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Innovations Technology available for licensing: novel nanometer-sized metal oxide semiconductors that allow targeting, initiating and control of in vitro and in vivo chemical...

  15. Utah Heavy Oil Program

    SciTech Connect (OSTI)

    J. Bauman; S. Burian; M. Deo; E. Eddings; R. Gani; R. Goel; C.K. Huang; M. Hogue; R. Keiter; L. Li; J. Ruple; T. Ring; P. Rose; M. Skliar; P.J. Smith; J.P. Spinti; P. Tiwari; J. Wilkey; K. Uchitel

    2009-10-20T23:59:59.000Z

    The Utah Heavy Oil Program (UHOP) was established in June 2006 to provide multidisciplinary research support to federal and state constituents for addressing the wide-ranging issues surrounding the creation of an industry for unconventional oil production in the United States. Additionally, UHOP was to serve as an on-going source of unbiased information to the nation surrounding technical, economic, legal and environmental aspects of developing heavy oil, oil sands, and oil shale resources. UHOP fulGilled its role by completing three tasks. First, in response to the Energy Policy Act of 2005 Section 369(p), UHOP published an update report to the 1987 technical and economic assessment of domestic heavy oil resources that was prepared by the Interstate Oil and Gas Compact Commission. The UHOP report, entitled 'A Technical, Economic, and Legal Assessment of North American Heavy Oil, Oil Sands, and Oil Shale Resources' was published in electronic and hard copy form in October 2007. Second, UHOP developed of a comprehensive, publicly accessible online repository of unconventional oil resources in North America based on the DSpace software platform. An interactive map was also developed as a source of geospatial information and as a means to interact with the repository from a geospatial setting. All documents uploaded to the repository are fully searchable by author, title, and keywords. Third, UHOP sponsored Give research projects related to unconventional fuels development. Two projects looked at issues associated with oil shale production, including oil shale pyrolysis kinetics, resource heterogeneity, and reservoir simulation. One project evaluated in situ production from Utah oil sands. Another project focused on water availability and produced water treatments. The last project considered commercial oil shale leasing from a policy, environmental, and economic perspective.

  16. Heavy-Duty Low-Temperature and Diesel Combustion & Heavy-Duty...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Heavy-Duty Low-Temperature and Diesel Combustion & Heavy-Duty Combustion Modeling Heavy-Duty Low-Temperature and Diesel Combustion &...

  17. Heavy Vehicle Propulsion Materials: Recent Progress and Future Plans

    SciTech Connect (OSTI)

    D. Ray Johnson; Sidney Diamond

    2001-05-14T23:59:59.000Z

    The Heavy Vehicle Propulsion Materials Program provides enabling materials technology for the U.S. DOE Office of Heavy Vehicle Technologies (OHVT). The technical agenda for the program is based on an industry assessment and the technology roadmap for the OHVT. A five-year program plan was published in 2000. Major efforts in the program are materials for diesel engine fuel systems, exhaust aftertreatment, and air handling. Additional efforts include diesel engine valve-train materials, structural components, and thermal management. Advanced materials, including high-temperature metal alloys, intermetallics, cermets, ceramics, amorphous materials, metal- and ceramic-matrix composites, and coatings, are investigated for critical engine applications. Selected technical issues and planned and ongoing projects as well as brief summaries of several technical highlights are given.

  18. Metal oxide films on metal

    DOE Patents [OSTI]

    Wu, Xin D. (Los Alamos, NM); Tiwari, Prabhat (Los Alamos, NM)

    1995-01-01T23:59:59.000Z

    A structure including a thin film of a conductive alkaline earth metal oxide selected from the group consisting of strontium ruthenium trioxide, calcium ruthenium trioxide, barium ruthenium trioxide, lanthanum-strontium cobalt oxide or mixed alkaline earth ruthenium trioxides thereof upon a thin film of a noble metal such as platinum is provided.

  19. Fluctuating initial conditions and fluctuations in elliptic and triangular flow

    E-Print Network [OSTI]

    A. K. Chaudhuri

    2012-02-24T23:59:59.000Z

    In heavy ion collisions, event-by-event fluctuations in participating nucleon positions can lead to triangular flow. With fluctuating initial conditions, flow coefficients will also fluctuate. In a hydrodynamic model, we study the fluctuations in elliptic and triangular flow, due to fluctuating initial conditions. Both elliptic and triangular flow fluctuates strongly, triangular flow more strongly than the elliptic flow. Strong fluctuations greatly reduce the sensitivity of elliptic and triangular flow to viscosity.

  20. APEC Smart Grid Initiative

    SciTech Connect (OSTI)

    Bloyd, Cary N.

    2012-03-01T23:59:59.000Z

    This brief paper describes the activities of the Asia Pacific Economic Cooperation (APEC) Smart Grid Initiative (ASGI) which is being led by the U.S. and developed by the APEC Energy Working Group. In the paper, I describe the origin of the initiative and briefly mention the four major elements of the initiative along with existing APEC projects which support it.

  1. Fluctuating initial conditions and fluctuations in elliptic and triangular flow

    E-Print Network [OSTI]

    Chaudhuri, A K

    2011-01-01T23:59:59.000Z

    In heavy ion collisions, event-by-event fluctuations in participating nucleon positions can lead to triangular flow. In a hydrodynamic model with fluctuating initial conditions, we study the fluctuations in elliptic and triangular flow. Both elliptic and triangular flow fluctuates strongly. Strong fluctuations greatly reduces the sensitivity of elliptic and triangular flow on viscosity.

  2. Metals 2000

    SciTech Connect (OSTI)

    Allison, S.W.; Rogers, L.C.; Slaughter, G. [Oak Ridge National Lab., TN (United States); Boensch, F.D. [6025 Oak Hill Lane, Centerville, OH (United States); Claus, R.O.; de Vries, M. [Virginia Polytechnic Inst. and State Univ., Blacksburg, VA (United States)

    1993-05-01T23:59:59.000Z

    This strategic planning exercise identified and characterized new and emerging advanced metallic technologies in the context of the drastic changes in global politics and decreasing fiscal resources. In consideration of a hierarchy of technology thrusts stated by various Department of Defense (DOD) spokesmen, and the need to find new and creative ways to acquire and organize programs within an evolving Wright Laboratory, five major candidate programs identified are: C-17 Flap, Transport Fuselage, Mach 5 Aircraft, 4.Fighter Structures, and 5. Missile Structures. These results were formed by extensive discussion with selected major contractors and other experts, and a survey of advanced metallic structure materials. Candidate structural applications with detailed metal structure descriptions bracket a wide variety of uses which warrant consideration for the suggested programs. An analysis on implementing smart skins and structures concepts is given from a metal structures perspective.

  3. Dendritic metal nanostructures

    DOE Patents [OSTI]

    Shelnutt, John A. (Tijeras, NM); Song, Yujiang (Albuquerque, NM); Pereira, Eulalia F. (Vila Nova de Gaia, PT); Medforth, Craig J. (Winters, CA)

    2010-08-31T23:59:59.000Z

    Dendritic metal nanostructures made using a surfactant structure template, a metal salt, and electron donor species.

  4. Heavy Truck Engine Program

    SciTech Connect (OSTI)

    Nelson, Christopher

    2009-01-08T23:59:59.000Z

    The Heavy Duty Truck Engine Program at Cummins embodied three significant development phases. All phases of work strove to demonstrate a high level of diesel engine efficiency in the face of increasingly stringent emission requirements. Concurrently, aftertreatment system development and refinement was pursued in support of these efficiency demonstrations. The program's first phase focused on the demonstration in-vehicle of a high level of heavy duty diesel engine efficiency (45% Brake Thermal Efficiency) at a typical cruise condition while achieving composite emissions results which met the 2004 U.S. EPA legislated standards. With a combination of engine combustion calibration tuning and the development and application of Urea-based SCR and particulate aftertreatment, these demonstrations were successfully performed by Q4 of 2002. The second phase of the program directed efforts towards an in-vehicle demonstration of an engine system capable of meeting 2007 U.S. EPA legislated emissions requirements while achieving 45% Brake Thermal Efficiency at cruise conditions. Through further combustion optimization, the refinement of Cummins Cooled EGR architecture, the application of a high pressure common rail fuel system and the incorporation of optimized engine parasitics, Cummins Inc. successfully demonstrated these deliverables in Q2 of 2004. The program's final phase set a stretch goal of demonstrating 50% Brake Thermal Efficiency from a heavy duty diesel engine system capable of meeting 2010 U.S. EPA legislated emissions requirements. Cummins chose to pursue this goal through further combustion development and refinement of the Cooled EGR system architecture and also applied a Rankine cycle Waste Heat Recovery technique to convert otherwise wasted thermal energy to useful power. The engine and heat recovery system was demonstrated to achieve 50% Brake Thermal Efficiency while operating at a torque peak condition in second quarter, 2006. The 50% efficient engine system was capable of meeting 2010 emissions requirements through the application of NOx and particulate matter reduction techniques proven earlier in the program.

  5. INL '@work' heavy equipment mechanic

    SciTech Connect (OSTI)

    Christensen, Cad

    2008-01-01T23:59:59.000Z

    INL's Cad Christensen is a heavy equipment mechanic. For more information about INL careers, visit http://www.facebook.com/idahonationallaboratory.

  6. INL '@work' heavy equipment mechanic

    ScienceCinema (OSTI)

    Christensen, Cad

    2013-05-28T23:59:59.000Z

    INL's Cad Christensen is a heavy equipment mechanic. For more information about INL careers, visit http://www.facebook.com/idahonationallaboratory.

  7. RHIC | Relativistic Heavy Ion Collider

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Photo of LINAC The Relativistic Heavy Ion Collider (RHIC) is a world-class particle accelerator at Brookhaven National Laboratory where physicists are exploring the most...

  8. Super Heavy Nuclei

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What'sis Taking Over Our InstagramStructure of All-Polymer. .Energy8 Career DaySunShotSuper Heavy

  9. Surface-initiated polymerization from TiO2 nanoparticle surfaces through a biomimetic initiator: A new route toward

    E-Print Network [OSTI]

    Surface-initiated polymerization from TiO2 nanoparticle surfaces through a biomimetic initiator radical polymerization (SI-ATRP) gave rise to PMMA polymer shell layers tethered to TiO2 nanoparticle functionalized metal oxide nanoparticles that may be useful for construction of functional polymer nanocomposites

  10. Near-threshold photodetachment of heavy alkali-metal anions

    SciTech Connect (OSTI)

    Bahrim, C.; Thumm, U.; Khuskivadze, A.A.; Fabrikant, I.I. [Department of Physics, Kansas State University, Manhattan, Kansas 66506-2604 (United States); Department of Chemistry and Physics, Lamar University, Beaumont, Texas 77710-10046 (United States); Department of Physics, Kansas State University, Manhattan, Kansas 66506-2604 (United States); Department of Physics and Astronomy, University of Nebraska, Lincoln, Nebraska 68588-0111 (United States)

    2002-11-01T23:59:59.000Z

    We calculate near-threshold photodetachment cross sections for Rb{sup -}, Cs{sup -}, and Fr{sup -} using the Pauli equation method with a model potential describing the effective electron-atom interaction. Parameters of the model potential are fitted to reproduce ab initio scattering phase shifts obtained from Dirac R-matrix calculations. Special care is taken to formulate the boundary conditions near the atomic nucleus for solving the Pauli equation, based on the analytic solution of the Dirac equation for a Coulomb potential. We find a {sup 3}P{sub 1}{sup o} resonance contribution to the photodetachment cross section of Rb{sup -}, Cs{sup -}, and Fr{sup -} ions. Our calculated total photodetachment cross sections for Cs agree with experiments after tuning the resonance position by 2.4 meV. For Rb{sup -} and Fr{sup -} the resonance contribution is much smaller than for Cs. We therefore also provide angle-differential cross sections and asymmetry parameters which are much more sensitive to the resonant contribution than total cross sections.

  11. High-Level Treatment of Stormwater Heavy Metals

    E-Print Network [OSTI]

    Clark, Shirley E.

    2Penn State - Harrisburg, PA Water World and Environmental Resources Conference, ASCE EWRI June 2004

  12. Permeable Reactive Biobarriers for the Containment of Heavy Metal

    E-Print Network [OSTI]

    Fay, Noah

    , ethanol was used as the electron donor. Representative reactions for our set-up: SO4 -2 + EtOH HS- + CO2OH, SO4 2- No Copper R2 EtOH, SO4 2- Copper Two UASB reactors for sulfate reduction using ethanol

  13. Pesticide and heavy metal residues in Louisiana river otter

    E-Print Network [OSTI]

    Beck, Debra Lynn

    1977-01-01T23:59:59.000Z

    of Hg pollution, and hypothesized that Hg was an important cause of the species' decline in Sweden since 1950. There has been no comparable work in North America, but two studies have provided information on tissue levels of contaminants in otter...

  14. Heavy Metals in Glass Beads Used in Pavement Markings

    E-Print Network [OSTI]

    Mangalgiri, Kiranmayi

    2012-07-16T23:59:59.000Z

    Pavement markings are vital for safely navigating roadways. The nighttime visibility of pavement markings is enhanced by addition of retroreflective glass beads, most of which are made from recycled glass. Concern has been raised over the presence...

  15. Micellar enhanced ultrafiltration of heavy metals using lecithin

    E-Print Network [OSTI]

    Ahmadi, Saman Nameghi

    1992-01-01T23:59:59.000Z

    Apparatus. 10 14 16 17 6. Water Flux at Different Pressures, T=30'C, Agitation=420 rpm. . . . . 31 7. Flux at Various Lecithin Concentrations, T='30 C, P=552 kPa, Agitation=220 rpm. . 8. Pure Water Flux, T=30'C, P=690 kPa, Agitation=250 rpm.... . . . . . . . 9. Mixture Flux. . . 32 33 34 10. Flux with Various Lecithins, T=30'C, P=690 kPa, Agitation=250 rpm. 11. Pure Water Flux through Various Membranes, T=30'C, P=690 kPa, Agitation=250 rpm. . 12. Permeate Flux at Varying Lecithin Concentrations...

  16. United abominations: Density functional studies of heavy metal chemistry

    SciTech Connect (OSTI)

    Schoendorff, George

    2012-04-02T23:59:59.000Z

    Carbonyl and nitrile addition to uranyl (UO{sup 2}{sup 2+}) are studied. The competition between nitrile and water ligands in the formation of uranyl complexes is investigated. The possibility of hypercoordinated uranyl with acetone ligands is examined. Uranyl is studied with diactone alcohol ligands as a means to explain the apparent hypercoordinated uranyl. A discussion of the formation of mesityl oxide ligands is also included. A joint theory/experimental study of reactions of zwitterionic boratoiridium(I) complexes with oxazoline-based scorpionate ligands is reported. A computational study was done of the catalytic hydroamination/cyclization of aminoalkenes with zirconium-based catalysts. Techniques are surveyed for programming for graphical processing units (GPUs) using Fortran.

  17. Micellar enhanced ultrafiltration of heavy metals using lecithin

    E-Print Network [OSTI]

    Ahmadi, Saman Nameghi

    1992-01-01T23:59:59.000Z

    unit operations with significant water use are electroplating, electroless plating, etching, cleaning, grinding, heat treating, welding, painting, and mechanical plating (2). Wastewaters generated from the above processes contain pollutants... such as sodium dodecyl sulfate (SDS). Lecithin, a natural surfactant, is inexpensive, non-toxic, and biodegradable. In this project the binding characteristics of lecithin to cadmium, copper, lead, nickel, and lead were examined. The process parameters of a...

  18. Gold Nanoparticle-Based Sensing of "Spectroscopically Silent" Heavy Metal

    E-Print Network [OSTI]

    to ultrasen- sitive detection has been described by Alivisatos and co- workers.2 They retain the fluorescence

  19. SEPARATION OF HEAVY METALS: REMOVAL FROM INDUSTRIAL WASTEWATERS

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What's PossibleRadiation Protection245C Unlimited Release PrintedDEVIATIONSReduce Waste and link

  20. Method and device for electroextraction of heavy metals from technological

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHighand Retrievals from aRodMIT-Harvard

  1. Energy Security Initiatives Update

    Broader source: Energy.gov [DOE]

    Presentationgiven at the Spring 2009 Federal Utility Partnership Working Group (FUPWG) meetinglists Federal government energy security initiatives.

  2. Initiating Business with INL

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Initiating Business with INL The INL Small Business Program Office (SBPO) serves as the advocate and point of contact for businesses seeking contracting opportunities. We ask you...

  3. Strategic Growth Initiative (Michigan)

    Broader source: Energy.gov [DOE]

    A joint venture between Michigan Department of Agriculture and Rural Development (MDARD) and the Michigan Economic Development Corporation (MEDC), the Strategic Growth Initiative Grant Program was...

  4. Salt Waste Processing Initiatives

    Office of Environmental Management (EM)

    1 Patricia Suggs Salt Processing Team Lead Assistant Manager for Waste Disposition Project Office of Environmental Management Savannah River Site Salt Waste Processing Initiatives...

  5. The Birth of a Galaxy: Primoridal Metal Enrichment and Population II Stellar Populations

    E-Print Network [OSTI]

    Wise, John H; Norman, Michael L; Abel, Tom

    2010-01-01T23:59:59.000Z

    Population III stars first form in dark matter halos with masses around 10^6 Msun. By definition, they are metal-free, and their protostellar collapse is driven by molecular hydrogen cooling in the gas-phase, leading to a massive characteristic mass ~100 Msun and suppressed fragmentation. Population II stars with lower characteristic masses form when the star-forming gas reaches a critical metallicity of 10^{-6} - 10^{-3.5} Zsun, depending on whether dust cooling is important. We present adaptive mesh refinement radiation hydrodynamics simulations that follows the transition from Population III to II star formation. We model stellar radiative feedback with adaptive ray tracing. A top-heavy initial mass function for the Population III stars is considered, resulting in a plausible distribution of pair-instability supernovae and associated metal enrichment. We find that the gas fraction recovers from 5 percent to nearly the cosmic fraction in halos with merger histories rich in halos above 10^7 Msun. A single pa...

  6. D-sJ(2317) meson production in ultrarelativistic heavy ion collisions RID A-2398-2009

    E-Print Network [OSTI]

    Chen, L. W.; Ko, Che Ming; Liu, W.; Nielsen, M.

    2007-01-01T23:59:59.000Z

    Production of D-sJ(2317) mesons in relativistic heavy ion collisions at the BNL Relativistic Heavy Ion Collider is studied. Using the quark coalescence model, we first determine the initial number of D-sJ(2317) mesons produced during hadronization...

  7. Metal Hydrides

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative Fuels Data Center Home Page on Google Bookmark EERE: Alternative Fuels DataDepartment of Energy Your Density Isn't YourTransport(FactDepartment3311, 3312), OctoberMay 18-19,DepartmentEnergyMetalMetal

  8. A Materials Facilities Initiative -

    E-Print Network [OSTI]

    A Materials Facilities Initiative - FMITS & MPEX D.L. Hillis and ORNL Team Fusion & Materials for Nuclear Systems Division July 10, 2014 #12;2 Materials Facilities Initiative JET ITER FNSF Fusion Reactor Challenges for materials: fluxes and fluence, temperatures 50 x divertor ion fluxes up to 100 x neutron

  9. Trending: Metal Oxo Bonds

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    including materials science, chemistry, and biology. Highly covalent metal-oxygen multiple bonds (metal oxos) are the building blocks of metal oxides and have a bearing...

  10. Heavy vehicle propulsion system materials program semiannual progress report for April 1999 through September 1999

    SciTech Connect (OSTI)

    Johnson, D.R.

    2000-01-01T23:59:59.000Z

    The purpose of the Heavy Vehicle Propulsion System Materials Program is the development of materials: ceramics, intermetallics, metal alloys, and metal and ceramic coatings, to support the dieselization of class 1-3 trucks to realize a 35% fuel-economy improvement over current gasoline-fueled trucks and to support commercialization of fuel-flexible LE-55 low-emissions, high-efficiency diesel engines for class 7-8 trucks.

  11. Initial data engineering

    E-Print Network [OSTI]

    Piotr T. Chrusciel; James Isenberg; Daniel Pollack

    2005-06-16T23:59:59.000Z

    We present a local gluing construction for general relativistic initial data sets. The method applies to generic initial data, in a sense which is made precise. In particular the trace of the extrinsic curvature is not assumed to be constant near the gluing points, which was the case for previous such constructions. No global conditions on the initial data sets such as compactness, completeness, or asymptotic conditions are imposed. As an application, we prove existence of spatially compact, maximal globally hyperbolic, vacuum space-times without any closed constant mean curvature spacelike hypersurface.

  12. Metalization of lipid vesicles via electroless plating

    SciTech Connect (OSTI)

    Ferrar, W.T.; O'Brien, D.F.; Warshawsky, A.; Voycheck, C.L.

    1988-01-06T23:59:59.000Z

    The encapsulation of metallic particles and metallic oxides within lipid vesicles has recently been of interest for applications such as catalysis, water splitting, and magnetic control of spin coupling. In this communication the authors introduce the concept and practice of the deposition of metal on vesicles by using electroless plating techniques. Coordination of low valent transition metals to organic functional groups on the surface of the bilayer membrane provides a means of binding metal atoms to vesicles. Chemical reduction produced zero valent atoms which serve as sites for further metal deposition by the chemical reduction techniques of electroless plating. Specifically, this procedure involved the binding of a small amount of tetrachloropalladate to the vesicle bilayer, reduction of the palladium(II) to palladium(0), followed by the deposition of much larger amounts of metal from an electroless plating solution. Electroless plating solutions were used for the deposition of palladium, nickel, cobalt, or copper metal onto the catalytic palladium centers. Since the metallic particles were associated with the vesicles, colloids were formed that were stable in water for much longer periods than the control metal particles formed in water alone. If the vesicles were composed in part of unsaturated lipids, with the olefinic groups on the hydrocarbon chains, the initial evidence suggests the transition metal was directed into the bilayer, rather than staying on the surface.

  13. The President's Biofuels Initiative

    Broader source: Energy.gov (indexed) [DOE]

    Biofuels Initiative Neil Rossmeissl Office of the Biomass Program Energy Efficiency and Renewable Energy Why Can't We Regulate Our Way There? 25 20 15 10 5 0 1970 1980 1990 2000...

  14. Mississippi Clean Energy Initiative

    Broader source: Energy.gov [DOE]

    In April 2010, the Mississippi Legislature enacted [http://billstatus.ls.state.ms.us/documents/2010/pdf/HB/1700-1799/HB1701S... HB 1701], establishing the Mississippi Clean Energy Initiative. This...

  15. President's Hydrogen Fuel Initiative

    Broader source: Energy.gov (indexed) [DOE]

    Hydrogen Fuel Initiative Workshop on Manufacturing R&D for the Hydrogen Economy Washington, DC July 13, 2005 JoAnn Milliken DOE Hydrogen Program Planning U.S. Energy Dependence is...

  16. Method for mobilization of hazardous metal ions in soils

    DOE Patents [OSTI]

    Dugan, P.R.; Pfister, R.M.

    1995-06-27T23:59:59.000Z

    A microbial process is revealed for removing heavy metals such as bismuth, cadmium, lead, thorium, uranium and other transuranics from soils and sediments. The method utilizes indigenous, or isolates of indigenous, microorganisms and reducing agents, such as cysteine or sodium thioglycollate, or complexing agents such as the amino acid glycine, to effect the mobilization or release of the metals from the soil particles. 5 figs.

  17. Metal Enrichment in the Intra-Cluster Medium

    E-Print Network [OSTI]

    Sabine Schindler

    2006-11-20T23:59:59.000Z

    The enrichment of the Intra-Cluster Medium (ICM) with heavy elements is reviewed. There is now good observational evidence for enrichment including abundance ratios and metallicity distributions. Various processes involved in the enrichment process -- ram-pressure stripping, galactic winds, galaxy-galaxy interactions, AGN outflows and intra-cluster supernovae -- are described. Simulations of the ICM evolution taking into account metal enrichment are presented.

  18. Heavy Oil Program. Quarterly progress report No. 1, April 1-June 30, 1980

    SciTech Connect (OSTI)

    Wayland, J. R.; Bartel, L. C.; Johnson, D. R.; Fox, R. L.

    1980-12-01T23:59:59.000Z

    Research and development efforts in support of the DOE Heavy Oil RD and D Program in reservoir access were initiated. Preliminary activities in the survey of sand control, drilling, and fracturing techniques in heavy oil formations are described. The continued development of a high temperature packer for use in steam injection applications is presented. A new application of controlled source audio magnetotelluric survey to developing thermal fronts from in situ combustion and steam drive is described.

  19. Heavy Flavour in a Nutshell

    E-Print Network [OSTI]

    Robert W. Lambert

    2011-05-06T23:59:59.000Z

    Moriond QCD brings together particle physicists of varied interests. This review and introduction to heavy flavour physics is aimed at those not in the heavy-flavour field to describe the motivation and methodology of precision flavour physics, and introduce the most tantalising searches for new physics. The LHC experiments are expected to make great inroads into constraining the new physics parameter space and discover the new physics which I will argue \\emph{must} be present to describe our observed universe.

  20. LCLS Heavy Met Outgassing Tests

    SciTech Connect (OSTI)

    Kishiyama, K. I.

    2010-12-01T23:59:59.000Z

    A Heavy Met that is 95% tungsten, 3% nickel and 2% iron and sintered to 100% density and is Ultra High Vacuum (UHV) compatible is proposed for use as the X-ray slit in the Front End Enclosure and the Fixed Mask for the Linac Coherent Light Source (LCLS). The Heavy Met was tested in the LLNL Vacuum Sciences and Engineering Lab (VSEL) to determine its outgassing rate and its overall compatibility with the vacuum requirements for LCLS.

  1. Systematics of cross sections for target K-vacancy production in heavy ion collisions

    E-Print Network [OSTI]

    Peng, Yong

    2007-04-25T23:59:59.000Z

    Cross sections for K-shell ionization by heavy ions have been determined from the measurements of target K x-ray yields. The measurements were performed with Ar, Kr, and Xe ions at energies from 2.5 to 25 MeV/amu and self-supported metallic foil...

  2. Heavy ion irradiation of crystalline water ice

    E-Print Network [OSTI]

    Dartois, E; Boduch, P; Brunetto, R; Chabot, M; Domaracka, A; Ding, J J; Kamalou, O; Lv, X Y; Rothard, H; da Silveira, E F; Thomas, J C

    2015-01-01T23:59:59.000Z

    Under cosmic irradiation, the interstellar water ice mantles evolve towards a compact amorphous state. Crystalline ice amorphisation was previously monitored mainly in the keV to hundreds of keV ion energies. We experimentally investigate heavy ion irradiation amorphisation of crystalline ice, at high energies closer to true cosmic rays, and explore the water-ice sputtering yield. We irradiated thin crystalline ice films with MeV to GeV swift ion beams, produced at the GANIL accelerator. The ice infrared spectral evolution as a function of fluence is monitored with in-situ infrared spectroscopy (induced amorphisation of the initial crystalline state into a compact amorphous phase). The crystalline ice amorphisation cross-section is measured in the high electronic stopping-power range for different temperatures. At large fluence, the ice sputtering is measured on the infrared spectra, and the fitted sputtering-yield dependence, combined with previous measurements, is quadratic over three decades of electronic ...

  3. Induction linacs for heavy ion fusion research

    SciTech Connect (OSTI)

    Fessenden, T.J.

    1984-05-01T23:59:59.000Z

    The new features of employing an induction linac as a driver for inertial fusion involve (1) transport of high-current low-emittance heavy ion beams, (2) multiple independently-focussed beams threading the same accelerator structure, and (3) synthesis of voltage waveforms to accomplish beam current amplification. A research program is underway at LBL to develop accelerators that test all these features with the final goal of producing an ion beam capable of heating matter to approx. 70 eV. This paper presents a discussion of some properties of induction linacs and how they may be used for HIF research. Physics designs of the High Temperature Experiment (HTE) and the Multiple Beam Experiment (MBE) accelerators are presented along with initial concepts of the MBE induction units.

  4. HEAVY WATER COMPONENTS TEST REACTOR DECOMMISSIONING

    SciTech Connect (OSTI)

    Austin, W.; Brinkley, D.

    2011-10-13T23:59:59.000Z

    The Heavy Water Components Test Reactor (HWCTR) Decommissioning Project was initiated in 2009 as a Comprehensive Environmental Response, Compensation and Liability Act (CERCLA) Removal Action with funding from the American Recovery and Reinvestment Act (ARRA). This paper summarizes the history prior to 2009, the major D&D activities, and final end state of the facility at completion of decommissioning in June 2011. The HWCTR facility was built in 1961, operated from 1962 to 1964, and is located in the northwest quadrant of the Savannah River Site (SRS) approximately three miles from the site boundary. The HWCTR was a pressurized heavy water test reactor used to develop candidate fuel designs for heavy water power reactors. In December of 1964, operations were terminated and the facility was placed in a standby condition as a result of the decision by the U.S. Atomic Energy Commission to redirect research and development work on heavy water power reactors to reactors cooled with organic materials. For about one year, site personnel maintained the facility in a standby status, and then retired the reactor in place. In the early 1990s, DOE began planning to decommission HWCTR. Yet, in the face of new budget constraints, DOE deferred dismantlement and placed HWCTR in an extended surveillance and maintenance mode. The doors of the reactor facility were welded shut to protect workers and discourage intruders. In 2009 the $1.6 billion allocation from the ARRA to SRS for site footprint reduction at SRS reopened the doors to HWCTR - this time for final decommissioning. Alternative studies concluded that the most environmentally safe, cost effective option for final decommissioning was to remove the reactor vessel, both steam generators, and all equipment above grade including the dome. The transfer coffin, originally above grade, was to be placed in the cavity vacated by the reactor vessel and the remaining below grade spaces would be grouted. Once all above equipment including the dome was removed, a concrete cover was to be placed over the remaining footprint and the groundwater monitored for an indefinite period to ensure compliance with environmental regulations.

  5. Humus forms and metal pollution in soil S. GILLET & J.F. PONGE

    E-Print Network [OSTI]

    Paris-Sud XI, Université de

    : Humus forms and metal pollution Summary Smelters in northern France are a serious source of soil pollution by heavy metals. We have studied a poplar plantation downwind of an active zinc smelter. Three humus profiles were sampled at increasing distance from the smelter, and the thickness of topsoil

  6. Heavy-Duty Low-Temperature and Diesel Combustion & Heavy-Duty...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    ce001musculus2010o.pdf More Documents & Publications Heavy-Duty Low-Temperature and Diesel Combustion & Heavy-Duty Combustion Modeling Heavy-Duty Low-Temperature and Diesel...

  7. Breckinridge Project, initial effort

    SciTech Connect (OSTI)

    none,

    1982-01-01T23:59:59.000Z

    Report IV, Volume 3, provides descriptions, data, and drawings pertaining to H-COAL Recycle Slurry Preparation (Plant 5), H-COAL Recycle Hydrogen Compression (Plant 6), and H-COAL Distillate Separation (Plant 17). H-COAL Recycle Slurry Preparation (Plant 5) receives a slurry stream from H-COAL Primary Separation (Plant 4), and then pumps the slurry through hydrocyclones, producing two slurry streams. One, dilute in solids is recycled back to the reactor. The other, concentrated in solids, is further processed to recover liquid products and is then transferred to Gasification and Purification (Plant 12). H-COAL Recycle Hydrogen Compression (Plant 6) compresses and recycles back to the reactor system hydrogen-rich vapor from H-COAL Primary Separation (Plant 4). This recycling maintains a hydrogen partial pressure and gas flow through the reactor vessel. H-COAL Distillate Separation (Plant 17) processes products from H-COAL Primary Separation (Plant 4) and H-COAL Recycle Slurry Preparation to produce light naphtha for the Gas Plant (Plant 7), middle and heavy distillates for tank farms, and heavy naphtha for Naphtha Hydrotreating and Reforming (Plant 18). The following information is included for each of the three plants: a description of the plant's process design, including the utility balance, heat and material balance (if applicable), and a process flow diagram; an equipment list, including item numbers and descriptions; data sheets and sketches for major plant components; and pertinent engineering drawings. An appendix contains: an overall site plan showing the locations of all plants; and the symbols and legend for the piping and instrument diagrams included in this volume.

  8. Clean Coal Power Initiative

    SciTech Connect (OSTI)

    Doug Bartlett; Rob James; John McDermott; Neel Parikh; Sanjay Patnaik; Camilla Podowski

    2006-03-31T23:59:59.000Z

    This report is the fifth quarterly Technical Progress Report submitted by NeuCo, Incorporated, under Award Identification Number, DE-FC26-04NT41768. This award is part of the Clean Coal Power Initiative (''CCPI''), the ten-year, $2B initiative to demonstrate new clean coal technologies in the field. This report is one of the required reports listed in Attachment B Federal Assistance Reporting Checklist, part of the Cooperative Agreement. The report covers the award period January 1, 2006 - March 31, 2006 and NeuCo's efforts within design, development, and deployment of on-line optimization systems during that period.

  9. Initiatives | Department of Energy

    Office of Environmental Management (EM)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742 33 111 1,613 122Commercial602 1,39732on Armed ServicesDepartmentInformationInitiatives Initiatives

  10. Heavy-Duty Low-Temperature and Diesel Combustion & Heavy-Duty...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    More Documents & Publications Heavy-Duty Low-Temperature and Diesel Combustion & Heavy-Duty Combustion Modeling Vehicle Technologies Office Merit Review 2014:...

  11. Heavy-Duty Low-Temperature and Diesel Combustion & Heavy-Duty...

    Broader source: Energy.gov (indexed) [DOE]

    6 AEC001: Heavy-Duty Low-Temperature and Diesel Combustion & Heavy-Duty Combustion Modeling This presentation does not contain any proprietary, confidential, or otherwise...

  12. Heavy-Duty Low-Temperature and Diesel Combustion & Heavy-Duty...

    Broader source: Energy.gov (indexed) [DOE]

    2 AEC001: Heavy-Duty Low-Temperature and Diesel Combustion & Heavy-Duty Combustion Modeling This presentation does not contain any proprietary, confidential, or otherwise...

  13. Chemistry of heavy ion reactions

    SciTech Connect (OSTI)

    Hoffman, D.C.

    1988-10-01T23:59:59.000Z

    The use of heavy ions to induce nuclear reactions was reported as early as 1950. Since that time it has been one of the most active areas of nuclear research. Intense beams of ions as heavy as uranium with energies high enough to overcome the Coulomb barriers of even the heaviest elements are available. The wide variety of possible reactions gives rise to a multitude of products which have been studied by many ingenious chemical and physical techniques. Chemical techniques have been of special value for the separation and unequivocal identification of low yield species from the plethora of other nuclides present. Heavy ion reactions have been essential for the production of the trans-Md elements and a host of new isotopes. The systematics of compound nucleus reactions, transfer reactions, and deeply inelastic reactions have been elucidated using chemical techniques. A review of the variety of chemical procedures and techniques which have been developed for the study of heavy ion reactions and their products is given. Determination of the chemical properties of the trans-Md elements, which are very short-lived and can only be produced an ''atom-at-a-time'' via heavy ion reactions, is discussed. 53 refs., 19 figs.

  14. GLOBAL TAXONOMY INITIATIVE

    E-Print Network [OSTI]

    Grant, Taran

    #12;THE GLOBAL TAXONOMY INITIATIVE: Using Systematic Inventories to Meet Country and Regional Needs International #12;Table of Contents Introduction 1 I. Using Inventories to Build Capacity and Advance the GTI 2 for systematic inventories. A major component of the workshop addressed how systematic inventories can serve

  15. BRAZIL RESEARCH INITIATIVES

    E-Print Network [OSTI]

    Liu, Taosheng

    BRAZIL RESEARCH INITIATIVES Michigan State University (MSU) identifies Brazil as a global priority and challenges become increasingly part of the U.S.-Brazil agenda, MSU desires partnerships aimed at producing in the U.S. and one in Brazil, to share research strategies and explore joint projects in several research

  16. ----------------IRI ---------------Initiative & Referendum Institute

    E-Print Network [OSTI]

    Rohs, Remo

    results a conservative cast: Marijuana rejected. Marijuana proponents went 0-4 on election night. California's Propo- sition 19 that would have legalized marijuana was one of the highest profile initiatives this year. In early polls, it led substantially but ended up failing 45-55. The silver lining for marijuana

  17. Staff Initials ______ Membership Application*

    E-Print Network [OSTI]

    NOT include the basketball gym. #12;Staff Initials ______ Furman University Fitness Center Acknowledgement and Release Form I, the undersigned, acknowledge that I am at least 18 years of age and that I am voluntarily here) I acknowledge that I am aware of the possible risks, dangers, and hazards associated with my

  18. The Sustainability "Green Initiative"

    E-Print Network [OSTI]

    Harms, Kyle E.

    sustainability approach aimed at: Lowering energy use and cost Reducing greenhouse gases Water and waste waterThe Sustainability "Green Initiative" At LAPPA October, 2008 #12;Sustainability is the capacity Carbon Footprint Ozone Friendly Global Warming Renewable Energy Biodegradable What does this whole

  19. PERSPECTIVES ON INTRACLUSTER ENRICHMENT AND THE STELLAR INITIAL MASS FUNCTION IN ELLIPTICAL GALAXIES

    SciTech Connect (OSTI)

    Loewenstein, Michael, E-mail: Michael.Loewenstein.1@nasa.gov [Also at CRESST and X-ray Astrophysics Laboratory, NASA/GSFC, Greenbelt, MD (United States)

    2013-08-10T23:59:59.000Z

    Stars formed in galaxy cluster potential wells must be responsible for the high level of enrichment measured in the intracluster medium (ICM); however, there is increasing tension between this truism and the parsimonious assumption that the stars in the generally old population studied optically in cluster galaxies emerged from the same formation sites at the same epochs. We construct a phenomenological cluster enrichment model to demonstrate that ICM elemental abundances are underestimated by a factor >2 for standard assumptions about the stellar population-a discrepancy we call the ''cluster elemental abundance paradox''. Recent evidence of an elliptical galaxy initial mass function (IMF) skewed to low masses deepens the paradox. We quantify the adjustments to the star formation efficiency and IMF, and Type Ia supernovae (SNIa) production efficiency, required to resolve this while being consistent with the observed ICM abundance pattern. The necessary enhancement in metal enrichment may, in principle, originate in the observed stellar population if a larger fraction of stars in the supernova-progenitor mass range form from an IMF that is either bottom-light or top-heavy, with the latter in some conflict with observed ICM abundance ratios. Other alternatives that imply more modest revisions to the IMF, mass return and remnant fractions, and primordial fraction, posit an increase in the fraction of 3-8 M{sub Sun} stars that explode as SNIa or assume that there are more stars than conventionally thought-although the latter implies a high star formation efficiency. We discuss the feasibility of these various solutions and the implications for the diversity of star formation in the universe, the process of elliptical galaxy formation, and the origin of this ''hidden'' source of ICM metal enrichment.

  20. Extracting metals directly from metal oxides

    DOE Patents [OSTI]

    Wai, C.M.; Smart, N.G.; Phelps, C.

    1997-02-25T23:59:59.000Z

    A method of extracting metals directly from metal oxides by exposing the oxide to a supercritical fluid solvent containing a chelating agent is described. Preferably, the metal is an actinide or a lanthanide. More preferably, the metal is uranium, thorium or plutonium. The chelating agent forms chelates that are soluble in the supercritical fluid, thereby allowing direct removal of the metal from the metal oxide. In preferred embodiments, the extraction solvent is supercritical carbon dioxide and the chelating agent is selected from the group consisting of {beta}-diketones, halogenated {beta}-diketones, phosphinic acids, halogenated phosphinic acids, carboxylic acids, halogenated carboxylic acids, and mixtures thereof. In especially preferred embodiments, at least one of the chelating agents is fluorinated. The method provides an environmentally benign process for removing metals from metal oxides without using acids or biologically harmful solvents. The chelate and supercritical fluid can be regenerated, and the metal recovered, to provide an economic, efficient process. 4 figs.

  1. Extracting metals directly from metal oxides

    DOE Patents [OSTI]

    Wai, Chien M. (Moscow, ID); Smart, Neil G. (Moscow, ID); Phelps, Cindy (Moscow, ID)

    1997-01-01T23:59:59.000Z

    A method of extracting metals directly from metal oxides by exposing the oxide to a supercritical fluid solvent containing a chelating agent is described. Preferably, the metal is an actinide or a lanthanide. More preferably, the metal is uranium, thorium or plutonium. The chelating agent forms chelates that are soluble in the supercritical fluid, thereby allowing direct removal of the metal from the metal oxide. In preferred embodiments, the extraction solvent is supercritical carbon dioxide and the chelating agent is selected from the group consisting of .beta.-diketones, halogenated .beta.-diketones, phosphinic acids, halogenated phosphinic acids, carboxylic acids, halogenated carboxylic acids, and mixtures thereof. In especially preferred embodiments, at least one of the chelating agents is fluorinated. The method provides an environmentally benign process for removing metals from metal oxides without using acids or biologically harmful solvents. The chelate and supercritical fluid can be regenerated, and the metal recovered, to provide an economic, efficient process.

  2. Heavy flavour production at LHC

    E-Print Network [OSTI]

    Alessandro Grelli; Andre Mischke

    2009-09-25T23:59:59.000Z

    The Large Hadron Collider (LHC) will open a new era in high energy physics. The expected large cross section for heavy flavour production in proton-proton collisions at $\\sqrt{s}$ = 14 TeV will allow detailed studies of the production mechanisms and an extensive test of Quantum Chromodynamics. Since charm and beauty has been proposed as a good probe to study hot and dense QCD matter, the understanding of the production mechanisms in elementary proton-proton collisions is of primary importance as a reference for studies in heavy-ion collisions. In the early phase of LHC operation the experiments will focus on the investigation of the heavy flavour production mechanisms.

  3. Pionic Fusion of Heavy Ions

    E-Print Network [OSTI]

    D. Horn; G. C. Ball; D. R. Bowman; W. G. Davies; D. Fox; A. Galindo-Uribarri; A. C. Hayes; G. Savard; L. Beaulieu; Y. Larochelle; C. St-Pierre

    1996-08-13T23:59:59.000Z

    We report the first experimental observation of the pionic fusion of two heavy ions. The 12C(12C,24Mg)pi0 and 12C(12C,24Na)pi+ cross sections have been measured to be 208 +/- 38 and 182 +/- 84 picobarns, respectively, at E_cm = 137 MeV. This cross section for heavy-ion pion production, at an energy just 6 MeV above the absolute energy-conservation limit, constrains possible production mechanisms to incorporate the kinetic energy of the entire projectile-target system as well as the binding energy gained in fusion.

  4. Reaction sequence of metallopetroporphyrins during heavy residuum upgrading

    SciTech Connect (OSTI)

    Reynolds, J.G.; Biggs, W.R.; Bezman, S.A.

    1986-04-01T23:59:59.000Z

    The authors analyzed the metallopetroporphyrins and the metallo-nonporphyrins during thermal and catalytic upgrading of heavy residua. By size exclusion chromatography with element specific detection (SEC-HPLC-ICP), they found thermal treatment reduces the size of the remaining metal-containing compounds, while catalytic treatment preferentially removes the metal-containing molecules in the size range of the catalyst pore. In both cases the metallopetroporphyrins process easily. By applying column chromatography and UV-vis spectroscopy, we have been able to detect and quantitate some of the probable intermediates of the demetallation sequence for vanadyl petroporphyrins. These results show the demetallation pathway is probably through the reduction of the porphyrins to chlorins and other reduced species. These results are in agreement with metalloporphyrin model compound work seen in the literature.

  5. Longitudinal Decorrelation of Anisotropic Flows in Heavy-ion Collisions at the CERN Large Hadron Collider

    E-Print Network [OSTI]

    Long-Gang Pang; Guang-You Qin; Victor Roy; Xin-Nian Wang; Guo-Liang Ma

    2015-04-22T23:59:59.000Z

    Fluctuations in the initial transverse energy-density distribution lead to anisotropic flows as observed in central high-energy heavy-ion collisions. Studies of longitudinal fluctuations of the anisotropic flows can shed further light on the initial conditions and dynamical evolution of the hot quark-gluon matter in these collisions. Correlations between anisotropic flows with varying pseudorapidity gaps in Pb+Pb collisions at the CERN Large Hadron Collider are investigated using both an event-by-event (3+1)-D ideal hydrodynamical model with fluctuating initial conditions and the a multiphase transport (AMPT) Monte Carlo model for high-energy heavy-ion collisions. Anisotropic flows at different pseudorapidities are found to become significantly decorrelated with increasing pseudo-rapidity gaps due to longitudinal fluctuations in the initial states of heavy-ion collisions. The longitudinal correlation of the elliptic flow shows a strong centrality dependence while the correlation of the triangular flow is independent of the centrality. Longitudinal fluctuations as a source of the decorrelation are further shown to consist of a twist or gradual rotation in flow angles between the forward and backward direction and additional fluctuations on top of the twist. Within the AMPT model, longitudinal correlations of anisotropic flows are also found to depend on the value of partonic cross sections. The implicatiosn of constraining the initial conditions and shear viscosity to entropy density ratio of the partonic matter in high-energy heavy-ion collisions are also discussed.

  6. Magnetic metallic multilayers

    SciTech Connect (OSTI)

    Hood, R.Q.

    1994-04-01T23:59:59.000Z

    Utilizing self-consistent Hartree-Fock calculations, several aspects of multilayers and interfaces are explored: enhancement and reduction of the local magnetic moments, magnetic coupling at the interfaces, magnetic arrangements within each film and among non-neighboring films, global symmetry of the systems, frustration, orientation of the various moments with respect to an outside applied field, and magnetic-field induced transitions. Magnetoresistance of ferromagnetic-normal-metal multilayers is found by solving the Boltzmann equation. Results explain the giant negative magnetoresistance encountered in these systems when an initial antiparallel arrangement is changed into a parallel configuration by an external magnetic field. The calculation depends on (1) geometric parameters (thicknesses of layers), (2) intrinsic metal parameters (number of conduction electrons, magnetization, and effective masses in layers), (3) bulk sample properties (conductivity relaxation times), (4) interface scattering properties (diffuse scattering versus potential scattering at the interfaces, and (5) outer surface scattering properties (specular versus diffuse surface scattering). It is found that a large negative magnetoresistance requires considerable asymmetry in interface scattering for the two spin orientations. Features of the interfaces that may produce an asymmetrical spin-dependent scattering are studied: varying interfacial geometric random roughness with no lateral coherence, correlated (quasi-periodic) roughness, and varying chemical composition of the interfaces. The interplay between these aspects of the interfaces may enhance or suppress the magnetoresistance, depending on whether it increases or decreases the asymmetry in the spin-dependent scattering of the conduction electrons.

  7. ``Towards Strange Metallic Holography'

    SciTech Connect (OSTI)

    Hartnoll, Sean A.; /Harvard U., Phys. Dept. /Santa Barbara, KITP /UC, Santa Barbara; Polchinski, Joseph; Silverstein, Eva; /Santa Barbara, KITP /UC, Santa Barbara; Tong, David; /Cambridge U., DAMTP /Santa Barbara, KITP /UC, Santa Barbara

    2010-08-26T23:59:59.000Z

    We initiate a holographic model building approach to 'strange metallic' phenomenology. Our model couples a neutral Lifshitz-invariant quantum critical theory, dual to a bulk gravitational background, to a finite density of gapped probe charge carriers, dually described by D-branes. In the physical regime of temperature much lower than the charge density and gap, we exhibit anomalous scalings of the temperature and frequency dependent conductivity. Choosing the dynamical critical exponent z appropriately we can match the non-Fermi liquid scalings, such as linear resistivity, observed in strange metal regimes. As part of our investigation we outline three distinct string theory realizations of Lifshitz geometries: from F theory, from polarized branes, and from a gravitating charged Fermi gas. We also identify general features of renormalization group flow in Lifshitz theories, such as the appearance of relevant charge-charge interactions when z {ge} 2. We outline a program to extend this model building approach to other anomalous observables of interest such as the Hall conductivity.

  8. Gulf Petro Initiative

    SciTech Connect (OSTI)

    Fathi Boukadi

    2011-02-05T23:59:59.000Z

    In this report, technologies for petroleum production and exploration enhancement in deepwater and mature fields are developed through basic and applied research by: (1) Designing new fluids to efficiently drill deepwater wells that can not be cost-effectively drilled with current technologies. The new fluids will be heavy liquid foams that have low-density at shallow dept to avoid formation breakdown and high density at drilling depth to control formation pressure. The goal of this project is to provide industry with formulations of new fluids for reducing casing programs and thus well construction cost in deepwater development. (2) Studying the effects of flue gas/CO{sub 2} huff n puff on incremental oil recovery in Louisiana oilfields bearing light oil. An artificial neural network (ANN) model will be developed and used to map recovery efficiencies for candidate reservoirs in Louisiana. (3) Arriving at a quantitative understanding for the three-dimensional controlled-source electromagnetic (CSEM) geophysical response of typical Gulf of Mexico hydrocarbon reservoirs. We will seek to make available tools for the qualitative, rapid interpretation of marine CSEM signatures, and tools for efficient, three-dimensional subsurface conductivity modeling.

  9. Title Quantum Optics and Heavy Ion Physics

    E-Print Network [OSTI]

    Roy J. Glauber

    2006-04-10T23:59:59.000Z

    I shall try to say a few words about two particular ways in which my own work has a certain relation to your work with heavy ions. My title is therefore "Quantum Optics and Heavy Ion Physics".

  10. Metal-phosphate binders

    DOE Patents [OSTI]

    Howe, Beth Ann [Lewistown, IL; Chaps-Cabrera, Jesus Guadalupe [Coahuila, MX

    2009-05-12T23:59:59.000Z

    A metal-phosphate binder is provided. The binder may include an aqueous phosphoric acid solution, a metal-cation donor including a metal other than aluminum, an aluminum-cation donor, and a non-carbohydrate electron donor.

  11. Production of metal waste forms from spent fuel treatment

    SciTech Connect (OSTI)

    Westphal, B.R.; Keiser, D.D.; Rigg, R.H.; Laug, D.V.

    1995-02-01T23:59:59.000Z

    Treatment of spent nuclear fuel at Argonne National Laboratory consists of a pyroprocessing scheme in which the development of suitable waste forms is being advanced. Of the two waste forms being proposed, metal and mineral, the production of the metal waste form utilizes induction melting to stabilize the waste product. Alloying of metallic nuclear materials by induction melting has long been an Argonne strength and thus, the transition to metallic waste processing seems compatible. A test program is being initiated to coalesce the production of the metal waste forms with current induction melting capabilities.

  12. Hydroconversion of heavy oils. [Residue of tar sand bitumen distillation

    SciTech Connect (OSTI)

    Garg, D.

    1986-08-19T23:59:59.000Z

    A method is described for hydroconversion of feedstocks consisting essentially of at least one heavy hydrocarbon oil selected from the group consisting of residue of petroleum oil distillation and the residue of tar sand bitumen distillation to enhance the recovery of 350/sup 0/-650/sup 0/F boiling product fraction. The method comprises treating such feed stock with hydrogen at superatmospheric pressure and in the presence of finely divided active hydrogenation catalyst in consecutive reaction stages. An initial reaction stage is carried out at a temperature in the range of 780/sup 0/-825/sup 0/F, and a subsequent reaction stage is directly carried out after the initial reaction stage at a higher temperature in the range of 800/sup 0/F-860/sup 0/F, the temperature of the subsequent reaction stage being at least 20/sup 0/F higher than that of the initial reaction stage.

  13. The Search for Heavy Elements

    ScienceCinema (OSTI)

    None

    2010-01-08T23:59:59.000Z

    The 1994 documentary "The Search for Heavy Elements" chronicles the expansion of the periodic table through the creation at Berkeley Lab of elements heavier than uranium. The documentary features a mix of rarely-seen archival footage, historical photos, and interviews with scientists who made history, such as Glenn Seaborg and Albert Ghiorso.

  14. Heavy quark physics from LEP

    SciTech Connect (OSTI)

    Dornan, P.J. [Imperial College of Science Technology and Medicine, London (United Kingdom)

    1997-01-01T23:59:59.000Z

    A review of some of the latest results on heavy flavor physics from the LEP Collaborations is presented. The emphasis is on B physics, particularly new results and those where discrepancies is given of the many techniques which have been developed to permit these analyses.

  15. DIESEL/HEAVY The diesel/heavy equipment certificate offers training in maintenance

    E-Print Network [OSTI]

    Ickert-Bond, Steffi

    DIESEL/HEAVY EQUIPMENT The diesel/heavy equipment certificate offers training in maintenance and repair of heavy equipment and trucks. Students will learn to work on electrical and air systems, diesel Small Engines Automotive Maintenance Welding Training for entry level heavy diesel equipment

  16. NO HEAVY-ELEMENT DISPERSION IN THE GLOBULAR CLUSTER M92

    SciTech Connect (OSTI)

    Cohen, Judith G., E-mail: jlc@astro.caltech.edu [Palomar Observatory, Mail Stop 249-17, California Institute of Technology, Pasadena, CA 91125 (United States)

    2011-10-20T23:59:59.000Z

    Although there have been recent claims that there is a large dispersion in the abundances of the heavy neutron capture elements in the old Galactic globular cluster M92, we show that the measured dispersion for the absolute abundances of four of the rare earth elements within a sample of 12 luminous red giants in M92 ({<=}0.07 dex) does not exceed the relevant sources of uncertainty. As expected from previous studies, the heavy elements show the signature of the r-process. Their abundance ratios are essentially identical to those of M30, another nearby globular cluster of similar metallicity.

  17. 3, 37453768, 2003 Heavy hydrogen in

    E-Print Network [OSTI]

    Paris-Sud XI, Universit de

    ACPD 3, 37453768, 2003 Heavy hydrogen in the stratosphere T. Rockmann et al. Title Page Abstract/3745/ European Geosciences Union 2003 Atmospheric Chemistry and Physics Discussions Heavy hydrogen Heavy hydrogen in the stratosphere T. Rockmann et al. Title Page Abstract Introduction Conclusions

  18. Light-Quark Decays in Heavy Hadrons

    E-Print Network [OSTI]

    Faller, Sven

    2015-01-01T23:59:59.000Z

    We consider weak decays of heavy hadrons (bottom and charmed) where the heavy quark acts as a spectator. Theses decays are heavily phase-space suppressed but may become experimentally accessible in the near future. These decays are interesting as a QCD laboratory to study the behaviour of the light quarks in the colour-background field of the heavy spectator.

  19. Metal Hydrides - Science Needs

    Broader source: Energy.gov (indexed) [DOE]

    with traditions in metal hydride research Metal and Ceramic Sciences Condensed Matter Physics Materials Chemistry Chemical and Biological Sciences Located on campus of Tier...

  20. Comparing Emissions Benefits from Regulating Heavy Vehicle Idling...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    from Regulating Heavy Vehicle Idling Comparing Emissions Benefits from Regulating Heavy Vehicle Idling 2005 Diesel Engine Emissions Reduction (DEER) Conference...

  1. Hanford tanks initiative plan

    SciTech Connect (OSTI)

    McKinney, K.E.

    1997-07-01T23:59:59.000Z

    Abstract: The Hanford Tanks Initiative (HTI) is a five-year project resulting from the technical and financial partnership of the U.S. Department of Energy`s Office of Waste Management (EM-30) and Office of Science and Technology Development (EM-50). The HTI project accelerates activities to gain key technical, cost performance, and regulatory information on two high-level waste tanks. The HTI will provide a basis for design and regulatory decisions affecting the remainder of the Tank Waste Remediation System`s tank waste retrieval Program.

  2. UNLV Nuclear Hydrogen Initiative

    SciTech Connect (OSTI)

    Hechanova, Anthony E.; Johnson, Allen; O'Toole, Brendan; Trabia, Mohamed; Peterson, Per

    2012-10-25T23:59:59.000Z

    Evaluation of the Crack growth rate (CGR) of Alloy 617 and Alloy 276 under constant K at ambient temperature has been completed. Creep deformation of Alloy 230 at different temperature range and load level has been completed and heat to heat variation has been noticed. Creep deformation study of Alloy 276 has been completed under an applied initial stress level of 10% of yield stress at 950C. The grain size evaluation of the tested creep specimens of Alloy 276 has been completed.

  3. World Consensus Initiative 2004

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office of ScienceandMesa del SolStrengtheningWildfires may contribute more toConsensus Initiative 2004 Texas

  4. Precision flyer initiator

    DOE Patents [OSTI]

    Frank, A.M.; Lee, R.S.

    1998-05-26T23:59:59.000Z

    A precision flyer initiator forms a substantially spherical detonation wave in a high explosive (HE) pellet. An explosive driver, such as a detonating cord, a wire bridge circuit or a small explosive, is detonated. A flyer material is sandwiched between the explosive driver and an end of a barrel that contains an inner channel. A projectile or ``flyer`` is sheared from the flyer material by the force of the explosive driver and projected through the inner channel. The flyer than strikes the HE pellet, which is supported above a second end of the barrel by a spacer ring. A gap or shock decoupling material delays the shock wave in the barrel from predetonating the HE pellet before the flyer. A spherical detonation wave is formed in the HE pellet. Thus, a shock wave traveling through the barrel fails to reach the HE pellet before the flyer strikes the HE pellet. The precision flyer initiator can be used in mining devices, well-drilling devices and anti-tank devices. 10 figs.

  5. Precision flyer initiator

    DOE Patents [OSTI]

    Frank, Alan M. (Livermore, CA); Lee, Ronald S. (Livermore, CA)

    1998-01-01T23:59:59.000Z

    A precision flyer initiator forms a substantially spherical detonation wave in a high explosive (HE) pellet. An explosive driver, such as a detonating cord, a wire bridge circuit or a small explosive, is detonated. A flyer material is sandwiched between the explosive driver and an end of a barrel that contains an inner channel. A projectile or "flyer" is sheared from the flyer material by the force of the explosive driver and projected through the inner channel. The flyer than strikes the HE pellet, which is supported above a second end of the barrel by a spacer ring. A gap or shock decoupling material delays the shock wave in the barrel from predetonating the HE pellet before the flyer. A spherical detonation wave is formed in the HE pellet. Thus, a shock wave traveling through the barrel fails to reach the HE pellet before the flyer strikes the HE pellet. The precision flyer initiator can be used in mining devices, well-drilling devices and anti-tank devices.

  6. Metal extraction

    SciTech Connect (OSTI)

    Covington, J.W.; Whittemore, R.G.

    1980-10-21T23:59:59.000Z

    In a process according to the present invention uranium is extracted into solution from its ore by leaching with an aqueous solution containing peroxomonosulphuric acid, the peroxoacid oxidizing the uranium through to its hexavalent state. Preferably the leaching is carried out at a temperature in the range of 50* to 100* C. The leach liquor can initially contain additional amounts of sulphuric acid or merely that present by virtue of the method of making the peroxomonosulphuric acid. In a preferred method of operation, the peroxoacid is introduced progressively into the leach liquor during the course of the leaching so as to maintain an electrochemical potential in the range of 450 to 650 mV. By use of the process, uranium is cleanly extracted into solution.

  7. $?$ vacua states in heavy ion collisions in presence of dissipation and noise

    E-Print Network [OSTI]

    A. K. Chaudhuri

    2001-09-24T23:59:59.000Z

    We have studied possible formation of $\\Theta$ vacua states in heavy ion collisions. Random phases of the chiral fields were evolved in a finite temperature potential, incorporating the breaking of $U_A(1)$ symmetry. Initial random phases very quickly settle into oscillation around the values dictated by the potential. The simulation study indicate that an initial $\\Theta$=0 state do not evolve into a $\\Theta$ $\

  8. Method for dry etching of transition metals

    DOE Patents [OSTI]

    Ashby, Carol I. H. (Edgewood, NM); Baca, Albert G. (Albuquerque, NM); Esherick, Peter (Albuquerque, NM); Parmeter, John E. (Albuquerque, NM); Rieger, Dennis J. (Tijeras, NM); Shul, Randy J. (Albuquerque, NM)

    1998-01-01T23:59:59.000Z

    A method for dry etching of transition metals. The method for dry etching of a transition metal (or a transition metal alloy such as a silicide) on a substrate comprises providing at least one nitrogen- or phosphorous-containing .pi.-acceptor ligand in proximity to the transition metal, and etching the transition metal to form a volatile transition metal/.pi.-acceptor ligand complex. The dry etching may be performed in a plasma etching system such as a reactive ion etching (RIE) system, a downstream plasma etching system (i.e. a plasma afterglow), a chemically-assisted ion beam etching (CAIBE) system or the like. The dry etching may also be performed by generating the .pi.-acceptor ligands directly from a ligand source gas (e.g. nitrosyl ligands generated from nitric oxide), or from contact with energized particles such as photons, electrons, ions, atoms, or molecules. In some preferred embodiments of the present invention, an intermediary reactant species such as carbonyl or a halide ligand is used for an initial chemical reaction with the transition metal, with the intermediary reactant species being replaced at least in part by the .pi.-acceptor ligand for forming the volatile transition metal/.pi.-acceptor ligand complex.

  9. Metal recovery from fly ash generated from vitrification process for MSW ash

    SciTech Connect (OSTI)

    Izumikawa, Chiaki [Dowa Mining Co. Ltd., Chiyoda, Tokyo (Japan)] [Dowa Mining Co. Ltd., Chiyoda, Tokyo (Japan)

    1996-12-31T23:59:59.000Z

    Metal-bearing wastes have to be carefully treated because heavy metals could be leached out under uncontrolled conditions when disposed of in a landfill. Consequently, heavy metals should be principally recovered and recycled forever. From this standpoint, the author has been trying to develop a technology to recover heavy metals from toxic vitrification fly ash for recycling to smelters. After a number of laboratory-scale experiments, pilot plant tests were successfully carried out and the developed process has been proven to be commercially realized. The main features of the process are that it recovers almost 100% of the heavy metals, simultaneously separating the metals which are recovered in a lead smelter from those in a zinc smelter, and that the output of the process are only metallurgical products recyclable for smelters and the effluent water which can be released into the environment. The process is considered an ideal one for the treatment of toxic fly ash from the viewpoint of not only natural resources but also environmental conservation.

  10. Instrumented Pipeline Initiative

    SciTech Connect (OSTI)

    Thomas Piro; Michael Ream

    2010-07-31T23:59:59.000Z

    This report summarizes technical progress achieved during the cooperative agreement between Concurrent Technologies Corporation (CTC) and U.S. Department of Energy to address the need for a for low-cost monitoring and inspection sensor system as identified in the Department of Energy (DOE) National Gas Infrastructure Research & Development (R&D) Delivery Reliability Program Roadmap.. The Instrumented Pipeline Initiative (IPI) achieved the objective by researching technologies for the monitoring of pipeline delivery integrity, through a ubiquitous network of sensors and controllers to detect and diagnose incipient defects, leaks, and failures. This report is organized by tasks as detailed in the Statement of Project Objectives (SOPO). The sections all state the objective and approach before detailing results of work.

  11. Metal-dependent Fermi-level movement in the metal/sulfur-passivated InGaP contact

    E-Print Network [OSTI]

    Kim, Sehun

    Metal-dependent Fermi-level movement in the metal/sulfur-passivated InGaP contact Y. K. Kim formed on S-passivated n-InGaP 100 surface reveals that the species produced by the chemical reaction. The initial sulfur passivation of n-InGaP 100 surface efficiently reduced the gap states within the band gap

  12. Pyroprocessing of IFR Metal Fuel

    SciTech Connect (OSTI)

    Laidler, J.J. [Argonne National Laboratory, IL (United States)

    1993-12-31T23:59:59.000Z

    The Integral Fast Reactor (IFR) fuel cycle features the use of an innovative reprocessing method, known as {open_quotes}pyroprocessing{close_quotes} featuring fused-salt electrofining of the spent fuel. Electrofining of IFR spent fuel involves uranium recovery by electro-transport to a solid steel cathode. The thermodynamics of the system preclude plutonium recovery in the same way, so a liquid cadmium cathode located in the electrolyte salt phase is utilized. The deposition of Pu, Am, Np, and Cm takes place at the liquid cadmium cathode in the form of cadmium intermetallic compounds (e.g, PuCd{sub 6}), and uranium deposits as the pure metal when cadmium saturation is reached. A small amount of rare earth fission products deposit together with the heavy metals at both the solid and liquid cadmium cathodes, providing a significant degree of self-protection. A full scope demonstration of the IFR fuel cycle will begin in 1993, using fuel irradiated in EBR-II.

  13. SOVENT BASED ENHANCED OIL RECOVERY FOR IN-SITU UPGRADING OF HEAVY OIL SANDS

    SciTech Connect (OSTI)

    Munroe, Norman

    2009-01-30T23:59:59.000Z

    With the depletion of conventional crude oil reserves in the world, heavy oil and bitumen resources have great potential to meet the future demand for petroleum products. However, oil recovery from heavy oil and bitumen reservoirs is much more difficult than that from conventional oil reservoirs. This is mainly because heavy oil or bitumen is partially or completely immobile under reservoir conditions due to its extremely high viscosity, which creates special production challenges. In order to overcome these challenges significant efforts were devoted by Applied Research Center (ARC) at Florida International University and The Center for Energy Economics (CEE) at the University of Texas. A simplified model was developed to assess the density of the upgraded crude depending on the ratio of solvent mass to crude oil mass, temperature, pressure and the properties of the crude oil. The simplified model incorporated the interaction dynamics into a homogeneous, porous heavy oil reservoir to simulate the dispersion and concentration of injected CO2. The model also incorporated the characteristic of a highly varying CO2 density near the critical point. Since the major challenge in heavy oil recovery is its high viscosity, most researchers have focused their investigations on this parameter in the laboratory as well as in the field resulting in disparaging results. This was attributed to oil being a complex poly-disperse blend of light and heavy paraffins, aromatics, resins and asphaltenes, which have diverse behaviors at reservoir temperature and pressures. The situation is exacerbated by a dearth of experimental data on gas diffusion coefficients in heavy oils due to the tedious nature of diffusivity measurements. Ultimately, the viscosity and thus oil recovery is regulated by pressure and its effect on the diffusion coefficient and oil swelling factors. The generation of a new phase within the crude and the differences in mobility between the new crude matrix and the precipitate readily enables removal of asphaltenes. Thus, an upgraded crude low in heavy metal, sulfur and nitrogen is more conducive for further purification.

  14. Metal behavior during fluidized bed thermal treatment of soil

    SciTech Connect (OSTI)

    Ho, T.C.; Lee, H.T.; Shiao, C.C.; Hopper, J.R. [Lamar Univ., Beaumont, TX (United States). Dept. of Chemical Engineering] [Lamar Univ., Beaumont, TX (United States). Dept. of Chemical Engineering; Bostick, W.D. [Martin Marietta Energy Systems, Inc., Oak Ridge, TN (United States). Chemistry Dept.] [Martin Marietta Energy Systems, Inc., Oak Ridge, TN (United States). Chemistry Dept.

    1995-12-31T23:59:59.000Z

    The Superfund dumpsites are frequently composed of soils contaminated with hazardous organic constituents and toxic heavy metals. While thermal treatment is an effective method of remediating the contaminated soils, the major environmental concerns are the emissions of toxic metal fumes during the treatment and the leaching of metals from the treated soil. The US EPA has reported that metals can account for almost all of the identified cancer risks from waste incineration systems. Research leading to better understanding of their behavior and better controlling of their emissions is urgently needed. In this study, the behavior of metals during the fluidized bed thermal treatment of artificially prepared metal-contaminated clay was experimentally and theoretically investigated. The objective of the study was to evaluate the effects of operating conditions on metal volatilization and metal leachability associated with the process. Metal experiments were carried out in a well instrumented 76 mm (3 inch) i.d. fluidized bed incinerator. The metals involved were compounds of lead and cadmium and the operating parameters included metal concentration, air flow rate, treatment temperature and treatment duration. The observed results indicated that metal volatilization is mainly a function of treatment temperature and treatment duration. The degree of volatilization was observed to range from 5 to 40% depending on the operating conditions. Cadmium leachability was observed to be relatively high compared to that of lead. In addition to the experimental study, a theoretical model based on the laws of heat and mass transfer operations and reaction kinetics was derived to simulate the metal volatilization process. The derived model was found to predict reasonably well the experimental observations.

  15. Development of a heavy-ion identification method using a combined time-of-flight [delta]E-E technique

    E-Print Network [OSTI]

    Hanus, Roy Gene

    1976-01-01T23:59:59.000Z

    Nagatani Identification of heavy-ion reaction products produced at the Texas A&H Variable Energy Cyclotron has been done primarily through the use of the AE-E detector telescope technique. The telescope is formed by placing two detectors together... of the partzcles eo their total initial energy, they can uniquely be identified. However, this technique for identification of heavy-ion reaction prod- ucts is adequate only for isotopes up through those of oxygen. Beyond oxygen, only element identification can...

  16. SECTION II: HEAVY ION REACTIONS

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What's PossibleRadiation Protection245C Unlimited Release PrintedDEVIATIONS F O INTERACTIONSII. HEAVY

  17. Sustainable Forest Bioenergy Initiative

    SciTech Connect (OSTI)

    Breger, Dwayne; Rizzo, Rob

    2011-09-20T23:59:59.000Z

    In the states Electricity Restructuring Act of 1998, the Commonwealth of Massachusetts recognized the opportunity and strategic benefits to diversifying its electric generation capacity with renewable energy. Through this legislation, the Commonwealth established one of the nations first Renewable Energy Portfolio Standard (RPS) programs, mandating the increasing use of renewable resources in its energy mix. Bioenergy, meeting low emissions and advanced technology standards, was recognized as an eligible renewable energy technology. Stimulated by the states RPS program, several project development groups have been looking seriously at building large woody biomass generation units in western Massachusetts to utilize the woody biomass resource. As a direct result of this development, numerous stakeholders have raised concerns and have prompted the state to take a leadership position in pursuing a science based analysis of biomass impacts on forest and carbon emissions, and proceed through a rulemaking process to establish prudent policy to support biomass development which can contribute to the states carbon reduction commitments and maintain safeguards for forest sustainability. The Massachusetts Sustainable Forest Bioenergy Initiative (SFBI) was funded by the Department of Energy and started by the Department of Energy Resources before these contentious biomass issues were fully raised in the state, and continued throughout the substantive periods of this policy development. Thereby, while SFBI maintained its focus on the initially proposed Scope of Work, some aspects of this scope were expanded or realigned to meet the needs for groundbreaking research and policy development being advanced by DOER. SFBI provided DOER and the Commonwealth with a foundation of state specific information on biomass technology and the biomass industry and markets, the most comprehensive biomass fuel supply assessment for the region, the economic development impact associated with biomass usage, an understanding of forest management trends including harvesting and fuel processing methods, and the carbon profile of utilizing forest based woody biomass for the emerging biomass markets. Each of the tasks and subtasks have provided an increased level of understanding to support new directives, policies and adaptation of existing regulations within Massachusetts. The project has provided the essential information to allow state policymakers and regulators to address emerging markets, while ensuring forest sustainability and understanding the complex science on CO2 accounting and impacts as a result of biomass harvesting for power generation. The public at large and electricity ratepayers in Massachusetts will all benefit from the information garnered through this project. This is a result of the states interest to provide financial incentives to only biomass projects that demonstrate an acceptable carbon profile, an efficient use of the constrained supply of fuel, and the harvest of biomass to ensure forest sustainability. The goals of the Massachusetts Sustainable Forest Bioenergy Initiative as proposed in 2006 were identified as: increase the diversity of the Massachusetts energy mix through biomass; promote economic development in the rural economy through forest industry job creation; help fulfill the states energy and climate commitments under the Renewable Energy Portfolio Standard and Climate Protection Plan; assist the development of a biomass fuel supply infrastructure to support energy project demands; provide education and outreach to the public on the benefits and impacts of bioenergy; improve the theory and practice of sustainable forestry in the Commonwealth. Completed project activities summarized below will demonstrate the effectiveness of the project in meeting the above goals. In addition, as discussed above, Massachusetts DOER needed to make some modifications to its work plan and objectives during the term of this project due to changing public policy demands brought forth in the course of the public discours

  18. Woodland Park Healthy Forest Initiative

    E-Print Network [OSTI]

    March 2010 Woodland Park Healthy Forest Initiative Collaboration Case Study #12;Woodland Park Healthy Forest Initiative 1 1 Colorado Forest Restoration Institute Collaboration Case Study: Woodland at Colorado State University, to conduct case studies of two collaborative forest health efforts

  19. Digital Library Initiative Rice University

    E-Print Network [OSTI]

    Digital Library Initiative Rice University Project Management General guidelines for digital projects Contact: dli (at) rice (dot) edu October, 2007 #12;Digital Library Initiative, Rice University................................................................................................8 #12;Guidelines for managing digital projects Page 2 STATEMENT OF PURPOSE We recognized

  20. Cadmium, copper, and lead in soils and garden produce near a metal smelter at Flin Flon, Manitoba

    SciTech Connect (OSTI)

    Pip, E. (Univ. of Winnipeg, Manitoba (Canada))

    1991-05-01T23:59:59.000Z

    Towns in the vicinity of base metal smelters are subject to contamination from atmospheric fallout containing heavy metals. Many smelters have been in operation for decades, and have resulted in substantial accumulation of metals in the surrounding soils. Metal contamination of edible vegetation near mines and smelters has been the source of health concerns in a number of countries. One smelter that has operated for more than half a century is located at Flin Flon, Manitoba. Many Flin Flon residents utilize home vegetable gardens year after year. However little is known regarding heavy metal contamination of locally grown garden produce. Since food can contribute as much as 90% of total body uptake of metals it is important to identify any sources which may account for the disproportionate share. The objective of the present study was to examine concentrations of cadmium, copper and lead in soils and garden produce in the vicinity of the Flin Flon smelter.

  1. Oklahoma GSHP Initiative Jim Bullington

    E-Print Network [OSTI]

    10/1/2012 1 Oklahoma GSHP Initiative Jim Bullington Trade & Industrial Education Oklahoma the Oklahoma CareerTech GSHP Initiative Model Provide my contact information for you to share with your and Technical Education Encourage you to contact them to get an initiative rolling Who is Oklahoma Career

  2. Heavy vehicle propulsion system materials program semiannual progress report for April 1998 thru September 1998

    SciTech Connect (OSTI)

    Johnson, D.R.

    1999-01-01T23:59:59.000Z

    The purpose of the Heavy Vehicle Propulsion System Materials Program is the development of materials: ceramics, intermetallics, metal alloys, and metal and ceramic coatings, to support the dieselization of class 1--3 trucks to realize a 35{percent} fuel-economy improvement over current gasoline-fueled trucks and to support commercialization of fuel-flexible LE-55 low-emissions, high-efficiency diesel engines for class 7--8 trucks. The Office of Transportation Technologies, Office of Heavy Vehicle Technologies (OTT OHVT) has an active program to develop the technology for advanced LE-55 diesel engines with 55{percent} efficiency and low emissions levels of 2.0 g/bhp-h NO{sub x} and 0.05 g/bhp-h particulates. The goal is also for the LE-55 engine to run on natural gas with efficiency approaching that of diesel fuel. The LE-55 program is being completed in FY 1997 and, after approximately 10 years of effort, has largely met the program goals of 55{percent} efficiency and low emissions. However, the commercialization of the LE-55 technology requires more durable materials than those that have been used to demonstrate the goals. Heavy Vehicle Propulsion System Materials will, in concert with the heavy-duty diesel engine companies, develop the durable materials required to commercialize the LE-55 technologies.

  3. Initial Cladding Condition

    SciTech Connect (OSTI)

    E. Siegmann

    2000-08-22T23:59:59.000Z

    The purpose of this analysis is to describe the condition of commercial Zircaloy clad fuel as it is received at the Yucca Mountain Project (YMP) site. Most commercial nuclear fuel is encased in Zircaloy cladding. This analysis is developed to describe cladding degradation from the expected failure modes. This includes reactor operation impacts including incipient failures, potential degradation after reactor operation during spent fuel storage in pool and dry storage and impacts due to transportation. Degradation modes include cladding creep, and delayed hydride cracking during dry storage and transportation. Mechanical stresses from fuel handling and transportation vibrations are also included. This Analysis and Model Report (AMR) does not address any potential damage to assemblies that might occur at the YMP surface facilities. Ranges and uncertainties have been defined. This analysis will be the initial boundary condition for the analysis of cladding degradation inside the repository. In accordance with AP-2.13Q, ''Technical Product Development Planning'', a work plan (CRWMS M&O 2000c) was developed, issued, and utilized in the preparation of this document. There are constraints, caveats and limitations to this analysis. This cladding degradation analysis is based on commercial Pressurized Water Reactor (PWR) fuel with Zircaloy cladding but is applicable to Boiling Water Reactor (BWR) fuel. Reactor operating experience for both PWRs and BWRs is used to establish fuel reliability from reactor operation. It is limited to fuel exposed to normal operation and anticipated operational occurrences (i.e. events which are anticipated to occur within a reactor lifetime), and not to fuel that has been exposed to severe accidents. Fuel burnup projections have been limited to the current commercial reactor licensing environment with restrictions on fuel enrichment, oxide coating thickness and rod plenum pressures. The information provided in this analysis will be used in evaluating the post-closure performance of the Monitored Geologic Repository (MGR) in relation to waste form degradation.

  4. Composite Metal-hydrogen Electrodes for Metal-Hydrogen Batteries

    SciTech Connect (OSTI)

    Ruckman, M W; Wiesmann, H; Strongin, M; Young, K; Fetcenko, M

    1997-04-01T23:59:59.000Z

    The purpose of this project is to develop and conduct a feasibility study of metallic thin films (multilayered and alloy composition) produced by advanced sputtering techniques for use as anodes in Ni-metal hydrogen batteries. The anodes could be incorporated in thin film solid state Ni-metal hydrogen batteries that would be deposited as distinct anode, electrolyte and cathode layers in thin film devices. The materials could also be incorporated in secondary consumer batteries (i.e. type AF(4/3 or 4/5)) which use electrodes in the form of tapes. The project was based on pioneering studies of hydrogen uptake by ultra-thin Pd-capped metal-hydrogen ratios exceeding and fast hydrogen charging and Nb films, these studies suggested that materials with those of commercially available metal hydride materials discharging kinetics could be produced. The project initially concentrated on gas phase and electrochemical studies of Pd-capped niobium films in laboratory-scale NiMH cells. This extended the pioneering work to the wet electrochemical environment of NiMH batteries and exploited advanced synchrotron radiation techniques not available during the earlier work to conduct in-situ studies of such materials during hydrogen charging and discharging. Although batteries with fast charging kinetics and hydrogen-metal ratios approaching unity could be fabricated, it was found that oxidation, cracking and corrosion in aqueous solutions made pure Nb films-and multiiayers poor candidates for battery application. The project emphasis shifted to alloy films based on known elemental materials used for NiMH batteries. Although commercial NiMH anode materials contain many metals, it was found that 0.24 m thick sputtered Zr-Ni films cycled at least 50 times with charging efficiencies exceeding 95% and [H]/[M] ratios of 0.7-1.0. Multilayered or thicker Zr-Ni films could be candidates for a thin film NiMH battery that may have practical applications as an integrated power source for modern electronic devices.

  5. Metal-Air Batteries

    SciTech Connect (OSTI)

    Zhang, Jiguang; Bruce, Peter G.; Zhang, Gregory

    2011-08-01T23:59:59.000Z

    Metal-air batteries have much higher specific energies than most currently available primary and rechargeable batteries. Recent advances in electrode materials and electrolytes, as well as new designs on metal-air batteries, have attracted intensive effort in recent years, especially in the development of lithium-air batteries. The general principle in metal-air batteries will be reviewed in this chapter. The materials, preparation methods, and performances of metal-air batteries will be discussed. Two main metal-air batteries, Zn-air and Li-air batteries will be discussed in detail. Other type of metal-air batteries will also be described.

  6. Heavy-Duty Low-Temperature and Diesel Combustion & Heavy-Duty...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    D.C. ace01musculus.pdf More Documents & Publications Heavy-Duty Low-Temperature and Diesel Combustion & Heavy-Duty Combustion Modeling Vehicle Technologies Office Merit Review...

  7. Heavy Oil Consumption Reduction Program (Quebec, Canada)

    Broader source: Energy.gov [DOE]

    This program helps heavy oil consumers move toward sustainable development while improving their competitive position by reducing their consumption. Financial assistance is offered to carry out...

  8. Factorization for hadronic heavy quarkonium production

    E-Print Network [OSTI]

    Jian-Wei Qiu

    2006-10-31T23:59:59.000Z

    We briefly review several models of heavy quarkonium production in hadronic collisions, and discuss the status of QCD factorization for these production models.

  9. Heavy flavor production in the STAR experiment

    E-Print Network [OSTI]

    Barbara Trzeciak; for the STAR Collaboration

    2014-09-11T23:59:59.000Z

    In this paper, recent STAR heavy flavor measurements in proton-proton and heavy-ion collisions are highlighted. We report studies of open charm mesons, reconstructed directly from hadronic decay products, and studies of electrons from semi-leptonic decays of heavy flavor hadrons. We also present J/$\\psi$ measurements via the di-electron decay channel at various collision systems and energies. In Au+Au collisions the energy dependence of J/$\\psi$ production measured at $\\sqrt{s_{NN}}$ = 39, 62.4 and 200 GeV is shown. Finally, prospects of heavy flavor measurements with the STAR detector upgrades are discussed.

  10. Demonstration of Automated Heavy-Duty Vehicles

    E-Print Network [OSTI]

    2006-01-01T23:59:59.000Z

    a future in which vehicle automation technologies are ableto support the heavy vehicle automation including PrecisionCommittee on Vehicle-Highway Automation, and the attendees

  11. Isospin Splittings of Doubly Heavy Baryons

    SciTech Connect (OSTI)

    Brodsky, Stanley J.; /SLAC; Guo, Feng-Kun; /Bonn U., HISKP /Bonn U.; Hanhart, Christoph; /Julich, Forschungszentrum /JCHP, Julich /IAS, Julich; Meissner, Ulf-G.; /Julich, Forschungszentrum /JCHP, Julich /IAS, Julich /Bonn U., HISKP /Bonn U.

    2011-08-18T23:59:59.000Z

    The SELEX Collaboration has reported a very large isospin splitting of doubly charmed baryons. We show that this effect would imply that the doubly charmed baryons are very compact. One intriguing possibility is that such baryons have a linear geometry Q-q-Q where the light quark q oscillates between the two heavy quarks Q, analogous to a linear molecule such as carbon dioxide. However, using conventional arguments, the size of a heavy-light hadron is expected to be around 0.5 fm, much larger than the size needed to explain the observed large isospin splitting. Assuming the distance between two heavy quarks is much smaller than that between the light quark and a heavy one, the doubly heavy baryons are related to the heavy mesons via heavy quark-diquark symmetry. Based on this symmetry, we predict the isospin splittings for doubly heavy baryons including {Xi}{sub cc}, {Xi}{sub bb} and {Xi}{sub bc}. The prediction for the {Xi}{sub cc} is much smaller than the SELEX value. On the other hand, the {Xi}{sub bb} baryons are predicted to have an isospin splitting as large as (6.3 {+-} 1.7) MeV. An experimental study of doubly bottomed baryons is therefore very important to better understand the structure of baryons with heavy quarks.

  12. Lattice QCD and Hydro/Cascade Model of Heavy Ion Collisions

    E-Print Network [OSTI]

    Michael Cheng

    2010-05-11T23:59:59.000Z

    We report here on a recent lattice study of the QCD transition region at finite temperature and zero chemical potential using domain wall fermions (DWF). We also present a parameterization of the QCD equation of state obtained from lattice QCD that is suitable for use in hydrodynamics studies of heavy ion collisions. Finally, we show preliminary results from a multi-stage hydrodynamics/hadron cascade model of a heavy ion collision, in an attempt to understand how well the experimental data (e.g. particle spectra, elliptic flow, and HBT radii) can constrain the inputs (e.g. initial temperature, freezeout temperature, shear viscosity, equation of state) of the theoretical model.

  13. Jet Quenching in Heavy-Ion Collisions - The Transition Era from RHIC to LHC

    E-Print Network [OSTI]

    Barbara Betz

    2012-11-26T23:59:59.000Z

    A status report on the jet quenching physics in heavy-ion collisions is given as it appears after more than 10 years of collecting and analysing data at the Relativistic Heavy Ion Collider (RHIC) and ~1.5 years of physics at the Large Hadron Collider (LHC). The (theoretical) predictions and expectations before the start of the LHC program are contrasted with the most recent experimental results, focussing on the nuclear modification factor R_{AA}, the elliptic flow v_2 of high-p_T particles, and on the problem of initial conditions.

  14. Heavy Ions - 88-Inch Cyclotron

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625 1,006 492 742EnergyOnItem NotEnergy,ARMFormsGasReleaseSpeechesHallNot Logged3 HanfordHarry S.Heat PumpsHeavy

  15. SECTION II. HEAVY ION REACTIONS

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level:Energy: Grid Integration Redefining What's PossibleRadiation Protection245C Unlimited Release PrintedDEVIATIONS F O INTERACTIONSII. HEAVY ION

  16. Heavy Actinides | ornl.gov

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cn SunnybankD.jpgHanfordDepartment ofHeat Transfer inoperation in timeHeavy

  17. X-ray Crystal Structures Elucidate the Nucleotidyl Transfer Reaction of Transcript Initiation Using Two Nucleotides

    SciTech Connect (OSTI)

    M Gleghorn; E Davydova; R Basu; L Rothman-Denes; K Murakami

    2011-12-31T23:59:59.000Z

    We have determined the X-ray crystal structures of the pre- and postcatalytic forms of the initiation complex of bacteriophage N4 RNA polymerase that provide the complete set of atomic images depicting the process of transcript initiation by a single-subunit RNA polymerase. As observed during T7 RNA polymerase transcript elongation, substrate loading for the initiation process also drives a conformational change of the O helix, but only the correct base pairing between the +2 substrate and DNA base is able to complete the O-helix conformational transition. Substrate binding also facilitates catalytic metal binding that leads to alignment of the reactive groups of substrates for the nucleotidyl transfer reaction. Although all nucleic acid polymerases use two divalent metals for catalysis, they differ in the requirements and the timing of binding of each metal. In the case of bacteriophage RNA polymerase, we propose that catalytic metal binding is the last step before the nucleotidyl transfer reaction.

  18. Pollution prevention and waste minimization in metal finishing

    SciTech Connect (OSTI)

    Stimetz, C.J.

    1994-12-01T23:59:59.000Z

    This study was done to identify pollution prevention and waste minimization opportunities in the general plating department and the printed circuit board processing department. Recommendations for certain recycle and recovery technologies were mad in order to reduce usage of acids and the volume of heavy metal sludge that is formed at the industrial Wastewater Pretreatment Facility (IWPF). Some of these technologies discussed were acid purification, electrowinning, and ion exchange. Specific technologies are prescribed for specific processes. Those plating processes where the metals can be recovered are copper, nickel, gold, cadmium, tin, lead, and rhodium.

  19. Heavy Truck Duty Cycle (HTDC) Project The Heavy Truck Duty Cycle (HTDC)

    E-Print Network [OSTI]

    Heavy Truck Duty Cycle (HTDC) Project OVERVIEW The Heavy Truck Duty Cycle (HTDC) Project of accounting for real-world driving performance within heavy truck analyses. The Program is being led by Oak to collect 104 channels of information at 100Hz. Another industry partner, Michelin Tires, was interested

  20. The Heavy Ion Fusion Virtual National Laboratory The Heavy Ion Path to Fusion Energy

    E-Print Network [OSTI]

    , describes R&D needs for heavy-ion accelerator, target and chamber R&D. 44 pages. Defines goals and criteria tasks) - ion accelerator technologies - chamber and maintenance technologies - pulsed power technologiesThe Heavy Ion Fusion Virtual National Laboratory The Heavy Ion Path to Fusion Energy Grant Logan

  1. Heavy-Ion Fusion Mechanism And Predictions Of Super-Heavy Elements Production

    E-Print Network [OSTI]

    Boyer, Edmond

    Heavy-Ion Fusion Mechanism And Predictions Of Super-Heavy Elements Production Yasuhisa Abea University, Omsk, RU-644077, Russia Abstract. Fusion process is shown to firstly form largely deformed mono-ion Fusion; Fusion hindrance; Super-heavy elements; Cross section. PACS: 25.70, Jj, 25.70. Lm, 27.90. +b

  2. Metal phthalocyanine catalysts

    DOE Patents [OSTI]

    Ellis, Jr., Paul E. (Downingtown, PA); Lyons, James E. (Wallingford, PA)

    1994-01-01T23:59:59.000Z

    As a new composition of matter, alkali metal or ammonium or tetraalkylammonium diazidoperfluorophthalocyanatoferrate. Other embodiments of the invention comprise compositions wherein the metal of the coordination complex is cobalt, manganese and chromium.

  3. Liquid Metal Transformers

    E-Print Network [OSTI]

    Sheng, Lei; Liu, Jing

    2014-01-01T23:59:59.000Z

    The room temperature liquid metal is quickly emerging as an important functional material in a variety of areas like chip cooling, 3D printing or printed electronics etc. With diverse capabilities in electrical, thermal and flowing behaviors, such fluid owns many intriguing properties that had never been anticipated before. Here, we show a group of unconventional phenomena occurring on the liquid metal objects. Through applying electrical field on the liquid metals immersed in water, a series of complex transformation behaviors such as self-assembling of a sheet of liquid metal film into a single sphere, quick mergences of separate metal droplets, controlled self-rotation and planar locomotion of liquid metal objects can be realized. Meanwhile, it was also found that two accompanying water vortexes were induced and reliably swirled near the rotating liquid metal sphere. Further, effects of the shape, size, voltage, orientation and geometries of the electrodes to control the liquid metal transformers were clar...

  4. Florida Hydrogen Initiative

    SciTech Connect (OSTI)

    Block, David L

    2013-06-30T23:59:59.000Z

    The Florida Hydrogen Initiative (FHI) was a research, development and demonstration hydrogen and fuel cell program. The FHI program objectives were to develop Florida?s hydrogen and fuel cell infrastructure and to assist DOE in its hydrogen and fuel cell activities The FHI program funded 12 RD&D projects as follows: Hydrogen Refueling Infrastructure and Rental Car Strategies -- L. Lines, Rollins College This project analyzes strategies for Florida's early stage adaptation of hydrogen-powered public transportation. In particular, the report investigates urban and statewide network of refueling stations and the feasibility of establishing a hydrogen rental-car fleet based in Orlando. Methanol Fuel Cell Vehicle Charging Station at Florida Atlantic University ? M. Fuchs, EnerFuel, Inc. The project objectives were to design, and demonstrate a 10 kWnet proton exchange membrane fuel cell stationary power plant operating on methanol, to achieve an electrical energy efficiency of 32% and to demonstrate transient response time of less than 3 milliseconds. Assessment of Public Understanding of the Hydrogen Economy Through Science Center Exhibits, J. Newman, Orlando Science Center The project objective was to design and build an interactive Science Center exhibit called: ?H2Now: the Great Hydrogen Xchange?. On-site Reformation of Diesel Fuel for Hydrogen Fueling Station Applications ? A. Raissi, Florida Solar Energy Center This project developed an on-demand forecourt hydrogen production technology by catalytically converting high-sulfur hydrocarbon fuels to an essentially sulfur-free gas. The removal of sulfur from reformate is critical since most catalysts used for the steam reformation have limited sulfur tolerance. Chemochromic Hydrogen Leak Detectors for Safety Monitoring ? N. Mohajeri and N. Muradov, Florida Solar Energy Center This project developed and demonstrated a cost-effective and highly selective chemochromic (visual) hydrogen leak detector for safety monitoring at any facility engaged in transport, handling and use of hydrogen. Development of High Efficiency Low Cost Electrocatalysts for Hydrogen Production and PEM Fuel Cell Applications ? M. Rodgers, Florida Solar Energy Center The objective of this project was to decrease platinum usage in fuel cells by conducting experiments to improve catalyst activity while lowering platinum loading through pulse electrodeposition. Optimum values of several variables during electrodeposition were selected to achieve the highest electrode performance, which was related to catalyst morphology. Understanding Mechanical and Chemical Durability of Fuel Cell Membrane Electrode Assemblies ? D. Slattery, Florida Solar Energy Center The objective of this project was to increase the knowledge base of the degradation mechanisms for membranes used in proton exchange membrane fuel cells. The results show the addition of ceria (cerium oxide) has given durability improvements by reducing fluoride emissions by an order of magnitude during an accelerated durability test. Production of Low-Cost Hydrogen from Biowaste (HyBrTec?) ? R. Parker, SRT Group, Inc., Miami, FL This project developed a hydrogen bromide (HyBrTec?) process which produces hydrogen bromide from wet-cellulosic waste and co-produces carbon dioxide. Eelectrolysis dissociates hydrogen bromide producing recyclable bromine and hydrogen. A demonstration reactor and electrolysis vessel was designed, built and operated. Development of a Low-Cost and High-Efficiency 500 W Portable PEMFC System ? J. Zheng, Florida State University, H. Chen, Bing Energy, Inc. The objectives of this project were to develop a new catalyst structures comprised of highly conductive buckypaper and Pt catalyst nanoparticles coated on its surface and to demonstrate fuel cell efficiency improvement and durability and cell cost reductions in the buckypaper based electrodes. Development of an Interdisciplinary Hydrogen and Fuel Cell Technology Academic Program ? J. Politano, Florida Institute of Technology, Melbourne, FL This project developed a hydrogen and fuel cel

  5. Heavy quark production at CDF

    SciTech Connect (OSTI)

    M. Bishai

    2002-12-13T23:59:59.000Z

    Heavy quark production cross-sections, correlations and polarizations have been measured at the Collider Detector at Fermilab (CDF) using 118 pb{sup -1} of data collected from the 1992 to 1995 Run I of the Fermilab Tevatron. There is still disagreement between theoretical predictions of bottom and charm hadro-production cross-sections and the Run I results. The observed transverse momentum spectrum of the prompt J/{psi} production polarization is still not understood. Run II of the Tevatron began in July of 2001 and the CDF Run II detector [11] has collected 70 pb{sup -1} of physics quality data since January 2002. Large statistics of onia states have been collected. Exclusive B meson decay modes have been reconstructed and the SVT level 2 displaced track trigger has produced large samples of D mesons. The prompt charm and b {yields} cX fractions in both charmonium and D meson samples have been measured. Run II is now poised to greatly enhance the knowledge of heavy quark production dynamics well beyond the reach of the Run I detector.

  6. Heavy Flavour results from Tevatron

    E-Print Network [OSTI]

    G. Borissov

    2012-06-21T23:59:59.000Z

    The CDF and D0 experiments finalize the analysis of their full statistics collected in the $p \\bar p$ collisions at a center-of-mass energy of $\\sqrt{s} = 1.96$ TeV at the Fermilab Tevatron collider. This paper presents several new results on the properties of hadrons containing heavy $b$- and $c$-quarks obtained by both collaborations. These results include the search for the rare decays $B^0, B^0_s \\to \\mu^+ \\mu^-$ (CDF), the study of CP asymmetry in $B_s \\to J\\psi \\phi$ decay (CDF, D0), the measurement of the like-sign dimuon charge asymmetry (D0), the measurement of CP asymmetry in $D^0 \\to K^+K^-$ and $D^0 \\to \\pi^+\\pi^-$ decays (CDF), and the new measurement of the $B_s \\to D_s^{(*)+} D_s^{(*)-}$ branching fraction (CDF). Both experiments still expect to produce more results on the properties of heavy flavours.

  7. Durable metallized polymer mirror

    DOE Patents [OSTI]

    Schissel, Paul O. (Golden, CO); Kennedy, Cheryl E. (Lafayette, CO); Jorgensen, Gary J. (Pine, CO); Shinton, Yvonne D. (Northglenn, CO); Goggin, Rita M. (Englewood, CO)

    1994-01-01T23:59:59.000Z

    A metallized polymer mirror construction having improved durability against delamination and tunneling, comprising: an outer layer of polymeric material; a metal oxide layer underlying the outer layer of polymeric material; a silver reflective layer underneath the metal oxide layer; and a layer of adhesive attaching the silver layer to a substrate.

  8. Durable metallized polymer mirror

    DOE Patents [OSTI]

    Schissel, P.O.; Kennedy, C.E.; Jorgensen, G.J.; Shinton, Y.D.; Goggin, R.M.

    1994-11-01T23:59:59.000Z

    A metallized polymer mirror construction is disclosed having improved durability against delamination and tunneling, comprising: an outer layer of polymeric material; a metal oxide layer underlying the outer layer of polymeric material; a silver reflective layer underneath the metal oxide layer; and a layer of adhesive attaching the silver layer to a substrate. 6 figs.

  9. SILER: Seismic-Initiated events risk mitigation in Lead-cooled Reactors

    SciTech Connect (OSTI)

    Forni, M. [ENEA, Via Martin di Monte Sole 4, 40129 Bologna (Italy); De Grandis, S. [SINTEC, Via Santo Stefano 20, 40125 Bologna (Italy)

    2012-07-01T23:59:59.000Z

    SILER is a Collaborative Project, partially funded by the European Commission, aimed at studying the risk associated to seismic initiated events in Generation IV Heavy Liquid Metal reactors and developing adequate protection measures. The attention is focused on the evaluation of the effects of earthquakes (with particular regards to beyond design seismic events) and to the identification of mitigation strategies, acting both on structures and components design (as well as on the development of seismic isolation devices) which can also have positive effects on economics, leading to an high level of plant design standardization. Attention is also devoted to the identification of plant layout solutions able to avoid risks of radioactive release from both the core and other structures (i.e. the spent fuel storage pools). Specific effort is paid to the development of guidelines and design recommendations for addressing the seismic issue in next generation reactor systems. In addition, consideration will be devoted to transfer the knowledge developed in the project to Generation III advanced systems, in line with the objective of the SNE-TP SRA to support present and future Light Water Reactors and their further development, for which safety issues are key aspects to be addressed. Note, in this respect, that the benefits of base isolation in terms of response to design seismic actions are already widely recognized for Generation III LWRs, along with the possibility of a significant standardization of structural and equipment design. SILER activities started on October 1 st 2011 and are carried out by 18 partners: ENEA (Italy, Coordinator), AREVA NP SAS (France), SCK-CEN (Belgium), FIP Industriale (Italy), MAURER SOHENE (Germany), EC-JRC (Ispra (Italy)), SINTEC (Italy), KTH (Sweden), BOA-BKT (Germany), IDOM (Spain), ANSALDO (Italy), IPUL (Latvia), NUMERIA (Italy), VCE (Austria), SRS (Italy), CEA (France), EA (Spain), NUVIA (France). (authors)

  10. Column Initialization 1 Initializing Distillation Column Models 1

    E-Print Network [OSTI]

    Dundee, University of

    Column Initialization 1 Initializing Distillation Column Models 1 Roger Fletcher \\Lambda with the optimisation of distillation column models by non linear programming are considered. The paper presents of the distillation column model. A certain limiting case of the column model is examined, that of infinite reflux

  11. Innovative Manufacturing Initiative Recognition Day

    Broader source: Energy.gov [DOE]

    The Innovative Manufacturing Initiative (IMI) Recognition Day (held in Washington, DC on June 20, 2012) showcased IMI projects selected by the Energy Department to help American manufacturers...

  12. The Solar Heavy Element Abundances: I. Constraints from Stellar Interiors

    E-Print Network [OSTI]

    Delahaye, F; Delahaye, Franck; Pinsonneault, Marc

    2005-01-01T23:59:59.000Z

    The latest solar atmosphere models include non-LTE corrections and 3D hydrodynamic convection simulations. These models predict a significant reduction in the solar metal abundance, which leads to a serious conflict between helioseismic data and the predictions of solar interiors models. We demonstrate that the helioseismic constraints on the surface convection zone depth and helium abundance combined with stellar interiors models can be used to define the goodness of fit for a given chemical composition. After a detailed examination of the errors in the theoretical models we conclude that models constructed with the older solar abundances are consistent (seismic data. Models constructed with the proposed new low abundance scale are strongly disfavored, disagreeing at the 15 \\sigma level. We then use the sensitivity of the seismic properties to abundance changes to invert the problem and infer a seismic solar heavy element abundance mix with two components: meteoritic abundances, and th...

  13. Electron-State Hybridization in Heavy-Fermion Systems

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electron-State Hybridization in Heavy-Fermion Systems Electron-State Hybridization in Heavy-Fermion Systems Print Wednesday, 27 September 2006 00:00 Heavy-fermion systems are...

  14. Vehicle Technologies Office Merit Review 2014: Heavy-Duty Low...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Heavy-Duty Low-Temperature and Diesel Combustion & Heavy-Duty Combustion Modeling Vehicle Technologies Office Merit Review 2014: Heavy-Duty Low-Temperature and Diesel Combustion &...

  15. Simulation of chamber transport for heavy-ion fusion

    E-Print Network [OSTI]

    2002-01-01T23:59:59.000Z

    Simulation of Chamber Transport for Heavy-Ion Fusion W. M.et al. , Modeling Chamber Transport for Heavy-Ion Fusion,et al. , "Chamber Transport of `Foot' Pulses for Heavy-Ion

  16. Composition and process for organic and metal contaminant fixation in soil

    DOE Patents [OSTI]

    Schwitzgebel, Klaus (7507 Chimney Corners, Austin, TX 78731)

    1994-02-08T23:59:59.000Z

    A method and compositions using a first ferrous iron containing solution with the iron concentration in excess of theoretical requirements to treat a contaminated site to reduce hexavalent chromium to trivalent chromium and coprecipitate trivalent chromium with other heavy metals and using a second solution of silicate containing a destabilizing salt to form a relatively impermeable gel in the contaminated site thereby fixing metals and organics to the extent that there should be no detectable ground water contamination.

  17. The performance of 3500 MWth homogeneous and heterogeneous metal fueled core designs

    SciTech Connect (OSTI)

    Turski, R.; Yang, Shi-tien

    1987-11-01T23:59:59.000Z

    Performance parameters are calculated for a representative 3500 MWth homogeneous and a heterogeneous metal fueled reactor design. The equilibrium cycle neutronic characteristics, safety coefficients, control system requirements, and control rod worths are evaluated. The thermal-hydraulic characteristics for both configurations are also compared. The heavy metal fuel loading requirements and neutronic performance characteristics are also evaluated for the uranium startup option. 14 refs., 14 figs., 20 tabs.

  18. Lattice studies of hadrons with heavy flavors

    SciTech Connect (OSTI)

    Christopher Aubin

    2009-07-01T23:59:59.000Z

    I will discuss recent developments in lattice studies of hadrons composed of heavy quarks. I will mostly cover topics which are at a state of direct comparison with experiment, but will also discuss new ideas and promising techniques to aid future studies of lattice heavy quark physics.

  19. Relativistic heavy ion research. Progress report

    SciTech Connect (OSTI)

    Nagamiya, Shoji

    1992-07-01T23:59:59.000Z

    This report discusses the following topics: antiproton production; Bose-Einstein correlations; high-transverse momentum spectra; strangeness enhancement in heavy ion collisions; search for rare negative secondaries of antiprotons and antinuclei produced in heavy ion collisions; quark matter; and time-of-flight systems test at Brookhaven AGS. (LSP).

  20. Heavy ion, recirculating linac, design optimization

    SciTech Connect (OSTI)

    Hewett, D.W. (Lawrence Livermore National Lab., CA (United States)); Godlove, T.F. (FM Technologies, Inc., Fairfax Station, VA (United States))

    1991-06-04T23:59:59.000Z

    Cost optimization is important to the development of high-current, heavy-ion accelerators for power production based on inertial confinement fusion. Two heavy-ion, recirculating linac configurations are examined that eliminate the necessity to provide reset pulses for the cores used in the linac induction accelerating modules. 3 refs., 2 figs.

  1. Innovative Structural and Joining Concepts for Lightweight Design of Heavy Vehicle Systems

    SciTech Connect (OSTI)

    Jacky C. Prucz; Samir N. Shoukry; Gergis W. William

    2005-08-31T23:59:59.000Z

    Recent advances in the area of Metal Matrix Composites (MMC's) have brought these materials to a maturity stage where the technology is ready for transition to large-volume production and commercialization. The new materials seem to allow the fabrication of higher quality parts at less than 50 percent of the weight as compared to steel, especially when they are selectively reinforced with carbon, silicon carbide, or aluminum oxide fibers. Most of the developments in the MMC materials have been spurred, mainly by applications that require high structural performance at elevated temperatures, the heavy vehicle industry could also benefit from this emerging technology. Increasing requirements of weight savings and extended durability are the main drivers for potential insertion of MMC technology into the heavy vehicle market. Critical elements of a typical tractor-trailer combination, such as highly loaded sections of the structure, engine components, brakes, suspensions, joints and bearings could be improved through judicious use of MMC materials. Such an outcome would promote the DOE's programmatic objectives of increasing the fuel efficiency of heavy vehicles and reducing their life cycle costs and pollution levels. However, significant technical and economical barriers are likely to hinder or even prevent broad applications of MMC materials in heavy vehicles. The tradeoffs between such expected benefits (lower weights and longer durability) and penalties (higher costs, brittle behavior, and difficult to machine) must be thoroughly investigated both from the performance and cost viewpoints, before the transfer of MMC technology to heavy vehicle systems can be properly assessed and implemented. MMC materials are considered to form one element of the comprehensive, multi-faceted strategy pursued by the High Strength/Weight Reduction (HS/WR) Materials program of the U.S. Department of Energy (DOE) for structural weight savings and quality enhancements in heavy vehicles. The research work planed for the first year of this project (June 1, 2003 through May 30, 2004) focused on a theoretical investigation of weight benefits and structural performance tradeoffs associated with the design, fabrication, and joining of MMC components for heavy-duty vehicles. This early research work conducted at West Virginia University yielded the development of integrated material-structural models that predicted marginal benefits and significant barriers to MMC applications in heavy trailers. The results also indicated that potential applications of MMC materials in heavy vehicles are limited to components identified as critical for either loadings or weight savings. Therefore, the scope of the project was expanded in the following year (June 1, 2004 through May 30, 2005) focused on expanding the lightweight material-structural design concepts for heavy vehicles from the component to the system level. Thus, the following objectives were set: (1) Devise and evaluate lightweight structural configurations for heavy vehicles. (2) Study the feasibility of using Metal Matrix Composites (MMC) for critical structural components and joints in heavy vehicles. (3) Develop analysis tools, methods, and validated test data for comparative assessments of innovative design and joining concepts. (4) Develop analytical models and software for durability predictions of typical heavy vehicle components made of particulate MMC or fiber-reinforced composites. This report summarizes the results of the research work conducted during the past two years in this projects.

  2. Induced biochemical interactions in immature and biodegraded heavy crude oils

    SciTech Connect (OSTI)

    Premuzic, E.T.; Lin, M.S.; Bohenek, M.; Joshi-Tope, G.; Shelenkova, L.; Zhou, W.M.

    1998-11-01T23:59:59.000Z

    Studies in which selective chemical markers have been used to explore the mechanisms by which biocatalysts interact with heavy crude oils have shown that the biochemical reactions follow distinct trends. The term biocatalyst refers to a group of extremophilic microorganisms which, under the experimental conditions used, interact with heavy crude oils to (1) cause a redistribution of hydrocarbons, (2) cause chemical changes in oil fractions containing sulfur compounds and lower the sulfur content, (3) decrease organic nitrogen content, and (4) decrease the concentration of trace metals. Current data indicate that the overall effect is due to simultaneous reactions yielding products with relatively higher concentration of saturates and lower concentrations of aromatics and resins. The compositional changes depend on the microbial species and the chemistry of the crudes. Economic analysis of a potential technology based on the available data indicate that such a technology, used in a pre-refinery mode, may be cost efficient and promising. In the present paper, the background of oil biocatalysis and some recent results will be discussed.

  3. INDUCED BIOCHEMICAL INTERACTIONS IN IMMATURE AND BIODEGRADED HEAVY CRUDE OILS

    SciTech Connect (OSTI)

    PREMUZIC,E.T.; LIN,M.S.; BOHENEK,M.; JOSHI-TOPE,G.; SHELENKOVA,L.; ZHOU,W.M.

    1998-10-27T23:59:59.000Z

    Studies in which selective chemical markers have been used to explore the mechanisms by which biocatalysts interact with heavy crude oils have shown that the biochemical reactions follow distinct trends. The term biocatalyst refers to a group of extremophilic microorganisms which, under the experimental conditions used, interact with heavy crude oils to (1) cause a redistribution of hydrocarbons, (2) cause chemical changes in oil fractions containing sulfur compounds and lower the sulfur content, (3) decrease organic nitrogen content, and (4) decrease the concentration of trace metals. Current data indicate that the overall effect is due to simultaneous reactions yielding products with relatively higher concentration of saturates and lower concentrations of aromatics and resins. The compositional changes depend on the microbial species and the chemistry of the crudes. Economic analysis of a potential technology based on the available data indicate that such a technology, used in a pre-refinery mode, may be cost efficient and promising. In the present paper, the background of oil biocatalysis and some recent results will be discussed.

  4. Heavy photon search experiment at JLAB

    SciTech Connect (OSTI)

    Stepanyan, S. [Jefferson Lab, Newport News, VA (United States); Collaboration: HPS Collaboration

    2013-11-07T23:59:59.000Z

    The Heavy Photon Search (HPS) experiment in Hall-B at Jefferson Lab will search for new heavy vector boson(s), aka 'heavy photons', in the mass range of 20 MeV/c{sup 2} to 1000 MeV/c{sup 2} using the scattering of high energy, high intensity electron beams off a high Z target. The proposed measurements will cover the region of parameter space favored by the muon g-2 anomaly, and will explore a significant region of parameter space, not only at large couplings (??/? > 10{sup ?7}), but also in the regions of small couplings, down to ??/??10{sup ?10}. The excellent vertexing capability of the Si-tracker uniquely enables HPS to cover the small coupling region. Also, HPS will search for heavy photons in an alternative to the e{sup +}e{sup ?} decay mode, in the heavy photon's decay to ?{sup +}??.

  5. Production, elliptic flow and energy loss of heavy quarks in the quark-gluon plasma

    E-Print Network [OSTI]

    Jan Uphoff; Oliver Fochler; Zhe Xu; Carsten Greiner

    2010-11-10T23:59:59.000Z

    Production, elliptic flow and the nuclear modification factor of charm and bottom quarks are studied in central and non-central heavy-ion collisions at RHIC and LHC using the partonic transport model Boltzmann Approach of MultiParton Scatterings (BAMPS). Employing an initial heavy quark yield obtained with PYTHIA the full space-time evolution of charm and bottom quarks in the quark-gluon plasma (QGP) is carried out with BAMPS, taking also secondary production in the QGP into account. Only elastic collisions of heavy quarks with particles from the medium cannot describe the experimentally observed elliptic flow and nuclear modification factor. However, using an improved Debye screening and the running coupling yields a result which is much closer to data.

  6. Liquid Metal Transformers

    E-Print Network [OSTI]

    Lei Sheng; Jie Zhang; Jing Liu

    2014-01-30T23:59:59.000Z

    The room temperature liquid metal is quickly emerging as an important functional material in a variety of areas like chip cooling, 3D printing or printed electronics etc. With diverse capabilities in electrical, thermal and flowing behaviors, such fluid owns many intriguing properties that had never been anticipated before. Here, we show a group of unconventional phenomena occurring on the liquid metal objects. Through applying electrical field on the liquid metals immersed in water, a series of complex transformation behaviors such as self-assembling of a sheet of liquid metal film into a single sphere, quick mergences of separate metal droplets, controlled self-rotation and planar locomotion of liquid metal objects can be realized. Meanwhile, it was also found that two accompanying water vortexes were induced and reliably swirled near the rotating liquid metal sphere. Further, effects of the shape, size, voltage, orientation and geometries of the electrodes to control the liquid metal transformers were clarified. Such events are hard to achieve otherwise on rigid metal or conventional liquid spheres. This finding has both fundamental and practical significances which suggest a generalized way of making smart soft machine, collecting discrete metal fluids, as well as flexibly manipulating liquid metal objects including accompanying devices.

  7. Mean multiplicity of light and heavy quark initiated Redamy Prez-Ramos

    E-Print Network [OSTI]

    Boyer, Edmond

    very important for such Higgs boson searches. Needless to say, the relevance of b-tagging extends over

  8. The metal enrichment of elliptical galaxies in hierarchical galaxy formation models

    E-Print Network [OSTI]

    Masahiro Nagashima; Cedric G. Lacey; Takashi Okamoto; Carlton M. Baugh; Carlos S. Frenk; Shaun Cole

    2005-07-14T23:59:59.000Z

    We investigate the metal enrichment of elliptical galaxies in the framework of hierarchical models of galaxy formation. The semi-analytical model we use in this Letter, which has been used to study the metal enrichment of the intracluster medium (ICM) by Nagashima et al., includes the effects of flows of gas and metals both into and out of galaxies and the processes of metal enrichment due to both type Ia and type II supernovae. We adopt a solar neighbourhood IMF for star formation in discs, but consider models in which starbursts have either a solar neighbourhood IMF or a top-heavy IMF. We find that the alpha-element abundance in ellipticals is consistent with observed values only if the top-heavy IMF is used. This result is consistent with our previous study on the metal enrichment of the ICM. We also discuss the abundance ratio of alpha elements to iron as a function of velocity dispersion and metallicity. We find that models with a top-heavy IMF match the alpha/Fe ratios observed in typical L_* ellipticals, but none of the models reproduce the observed increase of alpha/Fe with velocity dispersion.

  9. Systems Engineering Advancement Research Initiative

    E-Print Network [OSTI]

    de Weck, Olivier L.

    Systems Engineering Advancement Research Initiative RESEARCH PORTFOLIO Fall 2008 About SEAri http://seari.mit.edu The Systems Engineering Advancement Research Initiative brings together a set of sponsored research projects and a consortium of systems engineering leaders from industry, government, and academia. SEAri is positioned within

  10. Electron-State Hybridization in Heavy-Fermion Systems

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Electron-State Hybridization in Heavy-Fermion Systems Print Heavy-fermion systems are characterized by electrons with extremely large effective masses. The corresponding...

  11. Long Plasma Source for Heavy Ion Beam Charge Neutralization

    E-Print Network [OSTI]

    Efthimion, P.C.

    2009-01-01T23:59:59.000Z

    neutralizing plasma column the heavy ion beam can focus to aPlasmas are a source of unbound electrons for charge neutralizing intense heavy ion beams to focus

  12. Molecular dynamics simulations of ion range profiles for heavy...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    simulations of ion range profiles for heavy ions in light targets. Molecular dynamics simulations of ion range profiles for heavy ions in light targets. Abstract: The determination...

  13. NOx Adsorbers for Heavy Duty Truck Engines - Testing and Simulation...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Adsorbers for Heavy Duty Truck Engines - Testing and Simulation NOx Adsorbers for Heavy Duty Truck Engines - Testing and Simulation This report provides the results of an...

  14. Design and Implementation of Silicon Nitride Valves for Heavy...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Implementation of Silicon Nitride Valves for Heavy Duty Diesel Engines Design and Implementation of Silicon Nitride Valves for Heavy Duty Diesel Engines Poster presentation at the...

  15. Integrated Virtual Lab in Supporting Heavy Duty Engine and Vehicle...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Virtual Lab in Supporting Heavy Duty Engine and Vehicle Emission Rulemaking Integrated Virtual Lab in Supporting Heavy Duty Engine and Vehicle Emission Rulemaking Presentation...

  16. Advanced Natural Gas Engine Technology for Heavy Duty Vehicles

    Broader source: Energy.gov (indexed) [DOE]

    ALTERNATIVE. EVERY Advanced Natural Gas Engine Advanced Natural Gas Engine Technology for Heavy Duty Vehicles Technology for Heavy Duty Vehicles Dr. Mostafa M Kamel Dr. Mostafa M...

  17. WORKSHOP REPORT: Trucks and Heavy-Duty Vehicles Technical Requirements...

    Energy Savers [EERE]

    Heavy-Duty Vehicles Technical Requirements and Gaps for Lightweight and Propulsion Materials WORKSHOP REPORT: Trucks and Heavy-Duty Vehicles Technical Requirements and Gaps for...

  18. A High Temperature Direct Vehicle Exhaust Flowmeter for Heavy...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    A High Temperature Direct Vehicle Exhaust Flowmeter for Heavy Duty Diesel Emission Measurements. A High Temperature Direct Vehicle Exhaust Flowmeter for Heavy Duty Diesel Emission...

  19. Medium- and Heavy-Duty Electric Drive Vehicle Simulation and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Medium- and Heavy-Duty Electric Drive Vehicle Simulation and Analysis Medium- and Heavy-Duty Electric Drive Vehicle Simulation and Analysis 2011 DOE Hydrogen and Fuel Cells...

  20. Development and Demonstration of Fischer-Tropsch Fueled Heavy...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Fischer-Tropsch Fueled Heavy-Duty Vehicles with Control Technologies for Reduced Diesel Exhaust Emissions Development and Demonstration of Fischer-Tropsch Fueled Heavy-Duty...

  1. Extraction process for removing metallic impurities from alkalide metals

    DOE Patents [OSTI]

    Royer, Lamar T. (Knoxville, TN)

    1988-01-01T23:59:59.000Z

    A development is described for removing metallic impurities from alkali metals by employing an extraction process wherein the metallic impurities are extracted from a molten alkali metal into molten lithium metal due to the immiscibility of the alkali metals in lithium and the miscibility of the metallic contaminants or impurities in the lithium. The purified alkali metal may be readily separated from the contaminant-containing lithium metal by simple decanting due to the differences in densities and melting temperatures of the alkali metals as compared to lithium.

  2. Heavy Duty Vehicle Futures Analysis.

    SciTech Connect (OSTI)

    Askin, Amanda Christine; Barter, Garrett; West, Todd H.; Manley, Dawn Kataoka

    2014-05-01T23:59:59.000Z

    This report describes work performed for an Early Career Research and Development project. This project developed a heavy-duty vehicle (HDV) sector model to assess the factors influencing alternative fuel and efficiency technology adoption. This model builds on a Sandia light duty vehicle sector model and provides a platform for assessing potential impacts of technological advancements developed at the Combustion Research Facility. Alternative fuel and technology adoption modeling is typically developed around a small set of scenarios. This HDV sector model segments the HDV sector and parameterizes input values, such as fuel prices, efficiencies, and vehicle costs. This parameterization enables sensitivity and trade space analyses to identify the inputs that are most associated with outputs of interest, such as diesel consumption and greenhouse gas emissions. Thus this analysis tool enables identification of the most significant HDV sector drivers that can be used to support energy security and climate change goals.

  3. Heavy quark physics from SLD

    SciTech Connect (OSTI)

    Messner, R. [Stanford Univ., CA (United States)

    1997-01-01T23:59:59.000Z

    This report covers preliminary measurements from SLD on heavy quark production at the Z{sup 0}, using 150,000 hadronic Z{sup 0} decays accumulated during the 1993-1995 runs. A measurement of R{sub b} with a lifetime double tag is presented. The high electron beam polarization of the SLC is employed in the direct measurement of the parity-violating parameters A{sub b} and A{sub c} by use of the left-right forward-backward asymmetry. The lifetimes of B{sup +} and B{sup 0} mesons have been measured by two analyses. The first identifies semileptonic decays of B mesons with high (p,p{sub t}) leptons; the second analysis isolates a sample of B meson decays with a two-dimensional impact parameter tag and reconstructs the decay length and charge using a topological vertex reconstruction method.

  4. HIGH ENERGY DENSITY PHYSICS EXPERIMENTS WITH INTENSE HEAVY ION BEAMS

    SciTech Connect (OSTI)

    Bieniosek, F.M.; Henestroza, E.; Leitner, M.; Logan, B.G.; More, R.M.; Roy, P.K.; Ni, P.; Seidl, P.A.; Waldron, W.L.; Barnard, J.J.

    2008-08-01T23:59:59.000Z

    The US heavy ion fusion science program has developed techniques for heating ion-beam-driven warm dense matter (WDM) targets. The WDM conditions are to be achieved by combined longitudinal and transverse space-charge neutralized drift compression of the ion beam to provide a hot spot on the target with a beam spot size of about 1 mm, and pulse length about 1-2 ns. As a technique for heating volumetric samples of matter to high energy density, intense beams of heavy ions are capable of delivering precise and uniform beam energy deposition dE/dx, in a relatively large sample size, and the ability to heat any solid-phase target material. Initial experiments use a 0.3 MeV K+ beam (below the Bragg peak) from the NDCX-I accelerator. Future plans include target experiments using the NDCX-II accelerator, which is designed to heat targets at the Bragg peak using a 3-6 MeV lithium ion beam. The range of the beams in solid matter targets is about 1 micron, which can be lengthened by using porous targets at reduced density. We have completed the fabrication of a new experimental target chamber facility for WDM experiments, and implemented initial target diagnostics to be used for the first target experiments in NDCX-1. The target chamber has been installed on the NDCX-I beamline. The target diagnostics include a fast multi-channel optical pyrometer, optical streak camera, VISAR, and high-speed gated cameras. Initial WDM experiments will heat targets by compressed NDCX-I beams and will explore measurement of temperature and other target parameters. Experiments are planned in areas such as dense electronegative targets, porous target homogenization and two-phase equation of state.

  5. GE funds initiative to support STEM initiatives in Oklahoma ...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    STEM Empowers OK: Initiative to enrich STEM education in Oklahoma Click to email this to a friend (Opens in new window) Share on Facebook (Opens in new window) Click to share...

  6. Mixed metal films with switchable optical properties

    SciTech Connect (OSTI)

    Richardson, Thomas J.; Slack, Jonathan L.; Farangis, Baker; Rubin, Michael D.

    2001-10-16T23:59:59.000Z

    Thin, Pd-capped metallic films containing magnesium and first row transition metals (Mn, Fe, Co) switch reversibly from their initial reflecting state to visually transparent states when exposed to gaseous hydrogen or following cathodic polarization in an alkaline electrolyte. Reversion to the reflecting state is achieved by exposure to air or by anodic polarization. The films were prepared by co-sputtering from one magnesium target and one manganese, iron, or cobalt target. Both the dynamic optical switching range and the speed of the transition depend on the magnesium-transition metal ratio. Infrared spectra of films in the transparent, hydrided (deuterided) states support the presence of the intermetallic hydride phases Mg3MnH7, Mg2FeH6, and Mg2CoH5.

  7. Transparent monolithic metal ion containing nanophase aerogels

    SciTech Connect (OSTI)

    Risen, W. M., Jr.; Hu, X.; Ji, S.; Littrell, K.

    1999-12-01T23:59:59.000Z

    The formation of monolithic and transparent transition metal containing aerogels has been achieved through cooperative interactions of high molecular weight functionalized carbohydrates and silica precursors, which strongly influence the kinetics of gelation. After initial gelation, subsequent modification of the ligating character of the system, coordination of the group VIII metal ions, and supercritical extraction afford the aerogels. The structures at the nanophase level have been probed by photon and electron transmission and neutron scattering techniques to help elucidate the basis for structural integrity together with the small entity sizes that permit transparency in the visible range. They also help with understanding the chemical reactivities of the metal-containing sites in these very high surface area materials. These results are discussed in connection with new reaction studies.

  8. METALLIC HYDRIDES. Magnetic properties of laves-phase rare earth hydrides

    E-Print Network [OSTI]

    Boyer, Edmond

    METALLIC HYDRIDES. Magnetic properties of laves-phase rare earth hydrides J. J. Rhyne and G. E on the rare earth site. The rare earth spins disorder at a temperature lower than the bulk Tc in ErFe2 H3 5 per formula unit assuming complete occupation of 3 tetrahedral sites. The heavy rare earth (RFe2

  9. Experimental and numerical analysis of metal leaching from fly ash-amended highway bases

    E-Print Network [OSTI]

    Aydilek, Ahmet

    December 2011 Available online xxxx Keywords: Coal combustion by products Fly ash Heavy metals Leaching road materials (URM) mixed with lime activated high carbon fly ashes and to evaluate groundwater is produced in the United States as a by-product of burning coal in electric power plants (ACAA, 2009

  10. The r-Process in Metal Poor Stars and Black Hole Formation

    SciTech Connect (OSTI)

    Boyd, R N; Famiano, M A; Meyer, B S; Motizuki, Y; Kajino, T; Roederer, I U

    2011-11-30T23:59:59.000Z

    Nucleosynthesis of heavy nuclei in metal-poor stars is generally ascribed to the r-process, as the abundance pattern in many such stars agrees with the inferred Solar r-process abundances. Nonetheless, a significant number of these stars do not share this r-process template. they suggest that many such stars have begun an r-process, but it was prevented from running to completion in more massive stars by collapse to black holes, creating a 'truncated r-process,' or 'tr-process'. The observed fraction of tr-process stars is found to be consistent with expectations from the initial mass function (IMF), and they suggest that an apparent sharp truncation observed at around mass 160 could result from a combination of collapses to black holes and the difficulty of observing the higher mass rare earths. They test the tr-process hypothesis with calculations that are terminated before all r-process trajectories have been ejected. These produce qualitative agreement with observation when both black hole collapse and observational realities are taken into account.

  11. Thin-film optical initiator

    DOE Patents [OSTI]

    Erickson, Kenneth L. (Albuquerque, NM)

    2001-01-01T23:59:59.000Z

    A thin-film optical initiator having an inert, transparent substrate, a reactive thin film, which can be either an explosive or a pyrotechnic, and a reflective thin film. The resultant thin-film optical initiator system also comprises a fiber-optic cable connected to a low-energy laser source, an output charge, and an initiator housing. The reactive thin film, which may contain very thin embedded layers or be a co-deposit of a light-absorbing material such as carbon, absorbs the incident laser light, is volumetrically heated, and explodes against the output charge, imparting about 5 to 20 times more energy than in the incident laser pulse.

  12. Collisional energy loss of heavy quarks

    E-Print Network [OSTI]

    Alex Meistrenko; Andre Peshier; Jan Uphoff; Carsten Greiner

    2013-04-13T23:59:59.000Z

    We develop a transport approach for heavy quarks in a quark-gluon plasma, which is based on improved binary collision rates taking into account quantum statistics, the running of the QCD coupling and an effective screening mass adjusted to hard-thermal loop calculations. We quantify the effects of in-medium collisions by calculating the heavy flavor nuclear modification factor and the elliptic flow for RHIC energies, which are comparable to radiative effects. We also derive an analytic formula for the mean collisional energy loss of an energetic heavy quark in a streaming quark gluon plasma.

  13. ENERGY DEMAND AND CONSERVATION IN KENYA: INITIAL APPRAISAL

    E-Print Network [OSTI]

    Schipper, Lee

    2013-01-01T23:59:59.000Z

    Railway Corp, from heavy fuel oil to lighter diesel oil,NAIROBI FUEL OIL DIESEL OIL (HEAVY) If GAS OIL (LIGHT MOTOROil Crude & Prod. , Stock 15800 Net Kerosene LPG (Cylinders) Prem I Heavy :!!?

  14. Energy Efficient Schools Initiative- Grants

    Broader source: Energy.gov [DOE]

    The Energy Efficient Schools Initiative was created in May 2008 to provide grants and [http://www.dsireusa.org/incentives/incentive.cfm?Incentive_Code=TN57F&re... loans] to Tennessee school...

  15. Georgia Power- Advanced Solar Initiative

    Broader source: Energy.gov [DOE]

    Note: According to Georgia Power's website, the Advanced Solar Initiative's final program guidelines are due to be published on June 25th and the bidding period for is expected to open on July 10,...

  16. Initial

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOEThe Bonneville PowerCherries 82981-1cnHigh SchoolIn Other News linkThermal Phenomena

  17. Metal atomization spray nozzle

    DOE Patents [OSTI]

    Huxford, T.J.

    1993-11-16T23:59:59.000Z

    A spray nozzle for a magnetohydrodynamic atomization apparatus has a feed passage for molten metal and a pair of spray electrodes mounted in the feed passage. The electrodes, diverging surfaces which define a nozzle throat and diverge at an acute angle from the throat. Current passes through molten metal when fed through the throat which creates the Lorentz force necessary to provide atomization of the molten metal. 6 figures.

  18. Jet initiation of PBX 9502

    SciTech Connect (OSTI)

    McAfee, J.M.

    1987-07-01T23:59:59.000Z

    This report details the progress of an effort to determine the quantitative aspects of the initiation of PBX 9502 (95% TATB, 5% Kel-F 800) by copper jets. The particular jet used was that produced by the LAW warhead (66-mm diameter, 42/sup 0/ angle cone, copper-lined, conical shaped charge). Fifteen experiments, in various configurations, have been fired to define the essential parameters for quantitatively measuring the jet performance and initiation of bare PBX 9502. 7 refs., 8 figs.

  19. Energy Efficiency in Heavy Vehicle Tires, Drivetrains, and Braking Systems

    SciTech Connect (OSTI)

    Peter J. Blau

    2000-04-26T23:59:59.000Z

    This document was prepared to support the primary goals of the Department of Energy, Office of Heavy Vehicle Technologies. These were recently stated as follows: ''Develop by 2004 the enabling technologies for a class 7-8 truck with a fuel efficiency of 10 mpg (at 65 mph) which will meet prevailing emission standards. For Class 3-6 trucks operating on an urban driving cycle, develop by 2004 commercially viable vehicles that achieve at least double the fuel economy of comparable current vehicles (1999), and as a research goal, reduce criteria pollutants to 30% below EPA standards. Develop by 2004 the diesel engine enabling technologies to support large-scale industry dieselization of Class 1 and 2 trucks, achieving a 35 % fuel efficiency improvement over comparable gasoline-fueled trucks, while meeting applicable emissions standards.'' The enabling technologies for improving the fuel efficiency of trucks, include not only engine technologies but also technologies involved with lowering the rolling resistance of tires, reducing vehicle aerodynamic drag, improving thermal management, and reducing parasitic frictional losses in drive train components. Opportunities also exist for making better use of the energy that might ordinarily be dissipated during vehicle braking. Braking systems must be included in this evaluation since safety in truck operations is vital, and braking requirements are greater for vehicles having lowered resistance to rolling. The Office of Heavy Vehicle Technologies has initiated a program to improve the aerodynamics of heavy vehicles through wind tunnel testing, computational modeling, and on-road evaluations. That activity is described in a separate multi-year plan; therefore, emphasis in this document will be on tires, drive trains, and braking systems. Recent, dramatic fluctuations in diesel fuel prices have emphasized the importance of effecting savings in truck fuel economy by implementing new component designs and materials.

  20. Southface Energy Institute: Advanced Commercial Buildings Initiative...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Southface Energy Institute: Advanced Commercial Buildings Initiative - 2015 Peer Review Southface Energy Institute: Advanced Commercial Buildings Initiative - 2015 Peer Review...

  1. Clean Energy Manufacturing Initiative Midwest Regional Summit...

    Office of Environmental Management (EM)

    Clean Energy Manufacturing Initiative Midwest Regional Summit: Lightweighting Breakout Session Summary Clean Energy Manufacturing Initiative Midwest Regional Summit: Lightweighting...

  2. Research Initiative Will Demonstrate Low Temperature Geothermal...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Research Initiative Will Demonstrate Low Temperature Geothermal Electrical Power Generation Systems Using Oilfield Fluids Research Initiative Will Demonstrate Low Temperature...

  3. Noble metal catalysts for oxidation of mercury in flue gas

    SciTech Connect (OSTI)

    Presto, A.A.; Granite, E.J.

    2008-04-01T23:59:59.000Z

    The use of precious metals and platinum group metals as catalysts for oxidation of mercury in flue gas is an active area of study. To date, field studies have recently focused on gold and palladium catalysts installed at pilot-scale. In this work, we introduce bench-scale results for gold, platinum, and palladium catalysts tested in realistic simulated flue gas. Initial results reveal intriguing characteristics of catalytic mercury oxidation and provide insight for future research.

  4. Heavy Oil Upgrading from Electron Beam (E-Beam) Irradiation

    E-Print Network [OSTI]

    Yang, Daegil

    2011-02-22T23:59:59.000Z

    -heavy oil, and oil shale. Tremendous amounts of heavy oil resources are available in the world. Fig. 1.1 shows the total world oil reserves, and indicates that heavy oil, extra heavy oil, and bitumen make up about 70% of the world?s total oil resources...

  5. Heavy Mobile Equipment Mechanic (One Mechanic Shop)

    Broader source: Energy.gov [DOE]

    The position is a Heavy Mobile Equipment Mechanic (One Mechanic Shop) located in Kent, Washington, and will be responsible for the safe and efficient operation of a field garage performing...

  6. Partonic coalescence in relativistic heavy ion collisions

    E-Print Network [OSTI]

    Greco, V.; Ko, Che Ming; Levai, P.

    2003-01-01T23:59:59.000Z

    Using a covariant coalescence model, we study hadron production in relativistic heavy ion collisions from both soft partons in the quark-gluon plasma and hard partons in minijets. Including transverse flow of soft partons and independent...

  7. Heavy Ion Fusion Science Virtual National Laboratory

    E-Print Network [OSTI]

    progress with more modest near-term budgets. #12;Slide 5 Heavy Ion Fusion Science Virtual National requirement: modest growth of HIFS-VNL budget from present 7.7 M$/yr to ~16M$/yr, including suppo

  8. Hadron Production in Heavy Ion Collisions

    E-Print Network [OSTI]

    Helmut Oeschler; Hans Georg Ritter; Nu Xu

    2009-08-12T23:59:59.000Z

    We review hadron production in heavy ion collisions with emphasis on pion and kaon production at energies below 2 AGeV and on partonic collectivity at RHIC energies.

  9. NUCLEAR STRUCTURE AND HEAVY-ION FUSION

    E-Print Network [OSTI]

    Stokstad, R.G.

    2010-01-01T23:59:59.000Z

    Nuclear Structure and Heavy-Ton Fusion* A series of lecturesthe cross section for fusion in the experiments consideredEffects g in III. Subharrier Fusion Cross Sections for Light

  10. HEAVY-ION IMAGING APPLIED TO MEDICINE

    E-Print Network [OSTI]

    Fabrikant, J.I.

    2013-01-01T23:59:59.000Z

    heavy particles rat h er than the vax~at1.on 1n t h e x-rayprograms on the a PDPll-34 and VAX- 780 computers. The image

  11. Heavy Ion Fusion Science Virtual National Laboratory

    E-Print Network [OSTI]

    line- of-sight damage from target debris, neutron and gamma radiation. · Target injection: Heavy ions-liquid-protected target chambers with 30 yr lifetimes. · Robust final optics: Focusing magnets for ion beams avoid direct

  12. Jets in relativistic heavy ion collisions

    SciTech Connect (OSTI)

    Wang, Xin-Nian; Gyulassy, M.

    1990-09-01T23:59:59.000Z

    Several aspects of hard and semihard QCD jets in relativistic heavy ion collisions are discussed, including multiproduction of minijets and the interaction of a jet with dense nuclear matter. The reduction of jet quenching effect in deconfined phase of nuclear matter is speculated to provide a signature of the formation of quark gluon plasma. HIJING Monte Carlo program which can simulate events of jets production and quenching in heavy ion collisions is briefly described. 35 refs., 13 figs.

  13. Lead and other metals in dried fish from Nigerian markets

    SciTech Connect (OSTI)

    Okoye, C.O.B. (Univ. of Nigeria, Nsukka (Nigeria))

    1994-06-01T23:59:59.000Z

    The Nigerian economy had remarkable industrial growth between 1970 and 1980 and industrialization and urbanization have been sustained albeit at a slower rate. Nevertheless, waste management remains grossly underdeveloped. Environmental concern is only a recent phenomenon, resulting thus far in the launching of a monthly clean-up campaign in 1984 and the establishment of the Federal Environmental Protection Agency (FEPA) in 1988. The level of public awareness has not been encouraging. The indiscriminate discharge of largely untreated factory and urban effluents has continued. Streets and home surroundings become littered soon after clean-up exercises. Inadequate facilities contribute to the unwholesome situation. Refuse collecting centers are mostly without any holding containers, and solid wastes, the focus of the monthly clean-up, are left on the bare ground. Heavy automobile traffic and high lead content of the local automobile fuels have not helped matters. Heavy metals in the human environment are of global concern. In developed countries, limits of concentrations in fish and other foods have been set to safeguard public health, but Nigeria has yet to set any standards because of lack of baseline data. Within the last decade, scientists have been reporting on heavy metal levels in fish from the aquatic environment of Nigeria. Among the metals, lead was the most prominent, with a mean value comparable to the set limits in Great Britain and New Zealand. The present study was aimed at further establishing the levels of contamination in fish by lead and other metals in the Nigerian aquatic systems. Smoke-dried fish, being the most consumed by the local population, was chosen for the survey on the levels of cadmium, cobalt, copper, chromium, iron, manganese, lead and zinc. Possible surface contamination arising from observed poor handling practices was also investigated. 18 refs., 1 fig., 4 tabs.

  14. WINCO Metal Recycle annual report, FY 1993

    SciTech Connect (OSTI)

    Bechtold, T.E. [ed.

    1993-12-01T23:59:59.000Z

    This report is a summary of the first year progress of the WINCO Metal Recycle Program. Efforts were directed towards assessment of radioactive scrap metal inventories, economics and concepts for recycling, technology development, and transfer of technology to the private sector. Seven DOE laboratories worked together to develop a means for characterizing scrap metal. Radioactive scrap metal generation rates were established for several of these laboratories. Initial cost estimates indicate that recycle may be preferable over burial if sufficient decontamination factors can be achieved during melt refining. Radiation levels of resulting ingots must be minimized in order to keep fabrication costs low. Industry has much of the expertise and capability to execute the recycling of radioactive scrap metal. While no single company can sort, melt, refine, roll and fabricate, a combination of two to three can complete this operation. The one process which requires development is in melt refining for removal of radionuclides other than uranium. WINCO is developing this capability in conjunction with academia and industry. This work will continue into FY-94.

  15. Multi Module Modeling of Ultra-Relativistic Heavy Ion Collisions.

    SciTech Connect (OSTI)

    Magas, V. K.; Csernai, L. P. (Lszl P.); Keranen, A.; Manninen, J.; Strottman, D. D. (Daniel D.)

    2002-01-01T23:59:59.000Z

    Multi Module Model is required for the realistic and detailed description of an ultrarelativistic heavy ion reaction. We are working in the framework of such a model: initial stages are described by Effective String Rope Model with expanding final streaks; hydrodynamical approach is used for the intermediate stages. This paper is mainly devoted to Third Module - the one dealing with Freeze Out (FO). Two possibilities are discussed in details: (A) freeze out at the constant time hypersurface, where the statistical production model is used to describe post FO particle species; and (B) simultaneous hadronization and freeze out from supercooled QGP. For the last case the ALCOR-like algorithm for calculation of the post FO particle species is presented, due to the fact that these do not have time to reach chemical equilibrium.

  16. Determination of toxic elements in the ecological evaluation of metalliferous deposits of heavy oil and natural bitumens

    SciTech Connect (OSTI)

    Goldberg, I.S.

    1995-12-31T23:59:59.000Z

    Elements such as vanadium, nickel, zinc, arsenic, selenium, and mercury are present in highly toxic compounds in many workable deposits of heavy oil and natural bitumens. Refining this raw material and, especially, using the heavy residues as furnace fuel and as binding material for road paving, can lead to contamination of the environment unless measures are taken to remove the metals. Various investigations of the rare and disseminated elements in heavy oil and natural bitumens have encompassed a broad range of problems: (1) In refining, assessing the role of rare elements in technological processes in order to choose the optimal schemes for refining and improving the quality of petroleum products. (2) In protecting the environment and, in particular, identifying toxic compounds in fuel oils which, when burned at power stations, emit a substantial number of harmful substances into the atmosphere. (3) In determining commercial by-products, such as vanadium and nickel, in the petroleum and bitumen raw material.

  17. Transition Metal Dopants Essential for Producing Ferromagnetism...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Metal Dopants Essential for Producing Ferromagnetism in Metal Oxide Nanoparticles. Transition Metal Dopants Essential for Producing Ferromagnetism in Metal Oxide Nanoparticles....

  18. Metal roofing Shingle roofing

    E-Print Network [OSTI]

    Hutcheon, James M.

    Metal roofing panel Shingle roofing Water & ice barrier Thermal Barrier Plywood Student: Arpit between the roof and the attic. Apply modifications to traditional roofing assembly and roofing roof with only a water barrier between the plywood and the roofing panels. Metal roofing panel Shingle

  19. Porous metallic bodies

    DOE Patents [OSTI]

    Landingham, R.L.

    1984-03-13T23:59:59.000Z

    Porous metallic bodies having a substantially uniform pore size of less than about 200 microns and a density of less than about 25 percent theoretical, as well as the method for making them, are disclosed. Group IIA, IIIB, IVB, VB, and rare earth metal hydrides a

  20. Mask-assisted seeded growth of segmented metallic heteronanostructures

    DOE Public Access Gateway for Energy & Science Beta (PAGES Beta)

    Crane, Cameron C.; Tao, Jing; Wang, Feng; Zhu, Yimei; Chen, Jingyi

    2014-12-04T23:59:59.000Z

    Controlling the deposition of exotic metals in the seeded growth of multi-metal nanostructures is challenging. This work describes a seeded growth method assisted by a mask for synthesis of segmented binary or ternary metal nanostructures. Silica is used as a mask to partially block the surface of a seed and a second metal is subsequently deposited on the exposed area, forming a bimetallic heterodimer. The initial demonstration was carried out on a Au seed, followed by deposition of Pd or Pt on the seed. It was found that Pd tends to spread out laterally on the seed while Pt inclinesmoreto grow vertically into branched topology on Au. Without removal of the SiO? mask, Pt could be further deposited on the unblocked Pd of the Pd-Au dimer to form a Pt-Pd-Au trimer. The mask-assisted seeded growth provides a general strategy to construct segmented metallic nanoarchitectures.less

  1. Mask-assisted seeded growth of segmented metallic heteronanostructures

    SciTech Connect (OSTI)

    Crane, Cameron C. [Univ. of Arkansas, Fayetteville, AR (United States); Tao, Jing [Brookhaven National Lab. (BNL), Upton, NY (United States); Wang, Feng [Univ. of Arkansas, Fayetteville, AR (United States); Zhu, Yimei [Brookhaven National Lab. (BNL), Upton, NY (United States); Chen, Jingyi [Univ. of Arkansas, Fayetteville, AR (United States)

    2014-12-04T23:59:59.000Z

    Controlling the deposition of exotic metals in the seeded growth of multi-metal nanostructures is challenging. This work describes a seeded growth method assisted by a mask for synthesis of segmented binary or ternary metal nanostructures. Silica is used as a mask to partially block the surface of a seed and a second metal is subsequently deposited on the exposed area, forming a bimetallic heterodimer. The initial demonstration was carried out on a Au seed, followed by deposition of Pd or Pt on the seed. It was found that Pd tends to spread out laterally on the seed while Pt inclines to grow vertically into branched topology on Au. Without removal of the SiO? mask, Pt could be further deposited on the unblocked Pd of the Pd-Au dimer to form a Pt-Pd-Au trimer. The mask-assisted seeded growth provides a general strategy to construct segmented metallic nanoarchitectures.

  2. Process for direct conversion of reactive metals to glass

    DOE Patents [OSTI]

    Rajan, John B. (Naperville, IL); Kumar, Romesh (Naperville, IL); Vissers, Donald R. (Naperville, IL)

    1990-01-01T23:59:59.000Z

    Radioactive alkali metal is introduced into a cyclone reactor in droplet form by an aspirating gas. In the cyclone metal reactor the aspirated alkali metal is contacted with silica powder introduced in an air stream to form in one step a glass. The sides of the cyclone reactor are preheated to ensure that the initial glass formed coats the side of the reactor forming a protective coating against the reactants which are maintained in excess of 1000.degree. C. to ensure the formation of glass in a single step.

  3. Production of magnesium metal

    DOE Patents [OSTI]

    Blencoe, James G. (Harriman, TN) [Harriman, TN; Anovitz, Lawrence M. (Knoxville, TN) [Knoxville, TN; Palmer, Donald A. (Oliver Springs, TN) [Oliver Springs, TN; Beard, James S. (Martinsville, VA) [Martinsville, VA

    2010-02-23T23:59:59.000Z

    A process of producing magnesium metal includes providing magnesium carbonate, and reacting the magnesium carbonate to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The carbon dioxide is used as a reactant in a second process. In another embodiment of the process, a magnesium silicate is reacted with a caustic material to produce magnesium hydroxide. The magnesium hydroxide is reacted with a source of carbon dioxide to produce magnesium carbonate. The magnesium carbonate is reacted to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The invention further relates to a process for production of magnesium metal or a magnesium compound where an external source of carbon dioxide is not used in any of the reactions of the process. The invention also relates to the magnesium metal produced by the processes described herein.

  4. Prompt Iron Enrichment, Two r-Process Components, and Abundances in Very Metal-Poor Stars

    E-Print Network [OSTI]

    G. J. Wasserburg; Y. -Z. Qian

    1999-11-30T23:59:59.000Z

    We present a model to explain the wide range of abundances for heavy r-process elements (mass number A > 130) at low [Fe/H]. This model requires rapid star formation and/or an initial population of supermassive stars in the earliest condensed clots of matter to provide a prompt or initial Fe inventory. Subsequent Fe and r-process enrichment was provided by two types of supernovae: one producing heavy r-elements with no Fe on a rather short timescale and the other producing light r-elements (A < or = 130) with Fe on a much longer timescale.

  5. Molecular characterization of vanadyl and nickel non-porphyrin compounds in heavy crude petroleums and residua

    SciTech Connect (OSTI)

    Reynolds, J.G.; Biggs, W.R.; Fetzer, J.C.; Gallegos, E.J.; Fish, R.H.; Komlenic, J.J.; Wines, B.K.

    1984-01-01T23:59:59.000Z

    The molecular characterization of vanadium and nickel compounds in heavy crude petroleums has been the subject of current research. Arabian Heavy, Maya, Boscan, Cerro Negro, Prudhoe Bay, Wilmington Beta, Kern River, and Morichal crude petroleums have been examined. Fractions from D 2007 separations, porphyrin extractions, and solvent selective extraction with reversed phase column separations of these petroleums have been studied thoroughly by EPR. Important structural aspects are emerging from the presented data: (1) There are non-porphyrin metal complexes in the crude petroleums. (2) They appear to be smaller molecules with MW < 400 which are liberated when the tertiary structure of the large asphaltics is denatured. (3) The first coordination spheres of this class of compounds are possibly 4N, N O 2S, and 4S. 10 references, 3 figures, 1 table.

  6. AVAILABLE ONLINE AT: INITIATED BY:

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645U.S. DOE Office511041cloth DocumentationProducts (VAP) VAP7-0973 1 Introduction In the design INITIATED BY: INITIATED

  7. Heavy vehicle propulsion system materials program semi-annual progress report for October 1997 through March 1998

    SciTech Connect (OSTI)

    Johnson, D.R.

    1998-06-01T23:59:59.000Z

    The purpose of the Heavy Vehicle Propulsion System materials Program is the development of materials: ceramics, intermetallics, metal alloys, and metal and ceramic coatings, to support the dieselization of class 1--3 trucks to realize a 35{percent} fuel-economy improvement over current gasoline-fueled trucks and to support commercialization of fuel-flexible LE-55 low-emissions, high-efficiency diesel engines for class 7--8 trucks. The Office of Transportation Technologies, Office of Heavy Vehicle Technologies (OTT OHVT) has an active program to develop the technology for advanced LE-55 diesel engines with 55{percent} efficiency and low emissions levels of 2.0 g/bhp-h NO{sub x} and 0.05 g/bhp-h particulates. The goal is also for the LE-55 engine to run on natural gas with efficiency approaching that of diesel fuel. The LE-55 program is being completed in FY 1997 and, after approximately 10 years of effort, has largely met the program goals of 55{percent} efficiency and low emissions. However, the commercialization of the LE-55 technology requires more durable materials than those that have been used to demonstrate the goals. Heavy Vehicle Propulsion System Materials will, in concert with the heavy-duty diesel engine companies, develop the durable materials required to commercialize the LE-55 technologies.

  8. Heavy vehicle propulsion system materials program: Semiannual progress report, April 1996--September 1996

    SciTech Connect (OSTI)

    Johnson, D.R.

    1997-04-01T23:59:59.000Z

    The purpose of the Heavy Vehicle Propulsion System Materials Program is the development of materials: ceramics, intermetallics, metal alloys, and metal and ceramic coatings, to support the dieselization of class 1-3 trucks to realize a 35% fuel-economy improvement over current gasoline-fueled trucks and to support commercialization of fuel-flexible LE-55 low-emissions, high-efficiency diesel engines for class 7-8 trucks. The Office of Transportation Technologies, Office of Heavy Vehicle Technologies (OTT OHVT) has an active program to develop the technology for advanced LE-55 diesel engines with 55% efficiency and low emissions levels of 2.0 g/bhp-h NO{sub x} and 0.05 g/bhp-h particulates. The goal is also for the LE-55 engine to run on natural gas with efficiency approaching that of diesel fuel. The LE-55 program is being completed in FY 1997 and, after approximately 10 years of effort, has largely met the program goals of 55% efficiency and low emissions. However, the commercialization of the LE-55 technology requires more durable materials than those that have been used to demonstrate the goals. Heavy Vehicle Propulsion System Materials will, in concert with the heavy duty diesel engine companies, develop the durable materials required to commercialize the LE-55 technologies. OTT OHVT also recognizes a significant opportunity for reduction in petroleum consumption by dieselization of pickup trucks, vans, and sport utility vehicles. Application of the diesel engine to class 1, 2, and 3 trucks is expected to yield a 35% increase in fuel economy per vehicle. The foremost barrier to diesel use in this market is emission control. Once an engine is made certifiable, subsequent challenges will be in cost; noise, vibration, and harshness (NVH); and performance. Separate abstracts have been submitted to the database for contributions to this report.

  9. Energy loss, hadronization and hadronic interactions of heavy flavors in relativistic heavy-ion collisions

    E-Print Network [OSTI]

    Cao, Shanshan; Bass, Steffen A

    2015-01-01T23:59:59.000Z

    We construct a theoretical framework to describe the evolution of heavy flavors produced in relativistic heavy-ion collisions. The in-medium energy loss of heavy quarks is described using our modified Langevin equation that incorporates both quasi-elastic scatterings and the medium-induced gluon radiation. The space-time profiles of the fireball is described by a (2+1)-dimensional hydrodynamics simulation. A hybrid model of fragmentation and coalescence is utilized for heavy quark hadronization, after which the produced heavy mesons together with the soft hadrons produced from the bulk QGP are fed into the hadron cascade UrQMD model to simulate the subsequent hadronic interactions. We find that the medium-induced gluon radiation contributes significantly to heavy quark energy loss at high $p_\\mathrm{T}$; heavy-light quark coalescence enhances heavy meson production at intermediate $p_\\mathrm{T}$; and scatterings inside the hadron gas further suppress the $D$ meson $R_\\mathrm{AA}$ at large $p_\\mathrm{T}$ and e...

  10. Water issues associated with heavy oil production.

    SciTech Connect (OSTI)

    Veil, J. A.; Quinn, J. J.; Environmental Science Division

    2008-11-28T23:59:59.000Z

    Crude oil occurs in many different forms throughout the world. An important characteristic of crude oil that affects the ease with which it can be produced is its density and viscosity. Lighter crude oil typically can be produced more easily and at lower cost than heavier crude oil. Historically, much of the nation's oil supply came from domestic or international light or medium crude oil sources. California's extensive heavy oil production for more than a century is a notable exception. Oil and gas companies are actively looking toward heavier crude oil sources to help meet demands and to take advantage of large heavy oil reserves located in North and South America. Heavy oil includes very viscous oil resources like those found in some fields in California and Venezuela, oil shale, and tar sands (called oil sands in Canada). These are described in more detail in the next chapter. Water is integrally associated with conventional oil production. Produced water is the largest byproduct associated with oil production. The cost of managing large volumes of produced water is an important component of the overall cost of producing oil. Most mature oil fields rely on injected water to maintain formation pressure during production. The processes involved with heavy oil production often require external water supplies for steam generation, washing, and other steps. While some heavy oil processes generate produced water, others generate different types of industrial wastewater. Management and disposition of the wastewater presents challenges and costs for the operators. This report describes water requirements relating to heavy oil production and potential sources for that water. The report also describes how water is used and the resulting water quality impacts associated with heavy oil production.

  11. I. Bloch, DESY/Hamburg University -CIPANP, Puerto Rico 30.5.-03.06.'06 1Heavy Quarks at HERA Heavy Quark ProductionHeavy Quark Production

    E-Print Network [OSTI]

    I. Bloch, DESY/Hamburg University - CIPANP, Puerto Rico 30.5.-03.06.'06 1Heavy Quarks at HERA Heavy, Puerto Rico 30.5.-03.06.'06 2Heavy Quarks at HERA HERA: ep collisions within H1 & ZEUS 920 GeV protons920/Hamburg University - CIPANP, Puerto Rico 30.5.-03.06.'06 3Heavy Quarks at HERA H1&ZEUS integrated Luminosity: 96

  12. Preparation of uniform nanoparticles of ultra-high purity metal oxides, mixed metal oxides, metals, and metal alloys

    DOE Patents [OSTI]

    Woodfield, Brian F.; Liu, Shengfeng; Boerio-Goates, Juliana; Liu, Qingyuan; Smith, Stacey Janel

    2012-07-03T23:59:59.000Z

    In preferred embodiments, metal nanoparticles, mixed-metal (alloy) nanoparticles, metal oxide nanoparticles and mixed-metal oxide nanoparticles are provided. According to embodiments, the nanoparticles may possess narrow size distributions and high purities. In certain preferred embodiments, methods of preparing metal nanoparticles, mixed-metal nanoparticles, metal oxide nanoparticles and mixed-metal nanoparticles are provided. These methods may provide tight control of particle size, size distribution, and oxidation state. Other preferred embodiments relate to a precursor material that may be used to form nanoparticles. In addition, products prepared from such nanoparticles are disclosed.

  13. Simulated Interdiction: Proliferation Security Initiative

    E-Print Network [OSTI]

    2009-01-01T23:59:59.000Z

    ... Technical Capabilities to Support PSI Foreign Policy and External Relations ............... Republic of Bevostan .. Geography ... iii 1 3 4 5 6 7 8 8 8 8 8 9 9 10... Security, Science and Policy Institute (NSSPI) Texas A&M University May 6, 2009 Simulated Interdiction: The Proliferation Security Initiative (PSI) Acknowledgements The National Nuclear Security Administration (NNSA) of the U.S. Department...

  14. Zentrum fr Nutzfahrzeugtechnologie Initial situation

    E-Print Network [OSTI]

    Berns, Karsten

    with a vehicle model in the MKS software for the study of vehicle dynamic behavior. Schindler03_2012_03 Zentrum to calculate the tyre dynamic behavior when travelling through the soil surface. It can be fur- ther integratedZentrum für Nutzfahrzeugtechnologie Initial situation: The study on the trafficability

  15. Managing Critical Management Improvement Initiatives

    Broader source: Directives, Delegations, and Requirements [Office of Management (MA)]

    2003-10-01T23:59:59.000Z

    Provides requirements and responsibilities for planning, executing and assessing critical management improvement initiatives within DOE. DOE N 251.59, dated 9/27/2004, extends this Notice until 10/01/2005. Archived 11-8-10. Does not cancel other directives.

  16. Heavy flavours in heavy-ion collisions: quenching, flow and correlations

    E-Print Network [OSTI]

    A. Beraudo; A. De Pace; M. Monteno; M. Nardi; F. Prino

    2014-12-17T23:59:59.000Z

    We present results for the quenching, elliptic flow and azimuthal correlations of heavy flavour particles in high-energy nucleus-nucleus collisions obtained through the POWLANG transport setup, developed in the past to study the propagation of heavy quarks in the Quark-Gluon Plasma and here extended to include a modeling of their hadronization in the presence of a medium. Hadronization is described as occurring via the fragmentation of strings with endpoints given by the heavy (anti-)quark Q(Qbar) and a thermal parton qbar(q) from the medium. The flow of the light quarks is shown to affect significantly the R_AA and v_2 of the final D mesons, leading to a better agreement with the experimental data. The approach allows also predictions for the angular correlation between heavy-flavour hadrons (or their decay electrons) and the charged particles produced in the fragmentation of the heavy-quark strings.

  17. Elliptic flow and energy loss of heavy quarks in ultrarelativistic heavy ion collisions

    SciTech Connect (OSTI)

    Uphoff, Jan; Fochler, Oliver; Greiner, Carsten [Institut fuer Theoretische Physik, Johann Wolfgang Goethe-Universitaet Frankfurt, Max-von-Laue-Strasse 1, D-60438 Frankfurt am Main (Germany); Xu, Zhe [Institut fuer Theoretische Physik, Johann Wolfgang Goethe-Universitaet Frankfurt, Max-von-Laue-Strasse 1, D-60438 Frankfurt am Main (Germany); Frankfurt Institute for Advanced Studies, Ruth-Moufang-Strasse 1, D-60438 Frankfurt am Main (Germany)

    2011-08-15T23:59:59.000Z

    The space-time propagation of heavy quarks in ultrarelativistic heavy ion collisions is studied within the partonic transport model Boltzmann approach of multiparton scatterings (BAMPS). In this model heavy quarks interact with the partonic medium via binary scatterings. The cross sections for these interactions are calculated with leading-order perturbative QCD, but feature a more precise Debye screening derived within the hard thermal loop approximation and obey the running of the coupling. Within this framework the elliptic flow and the nuclear modification factor of heavy quarks are computed for the BNL Relativistic Heavy Ion Collider (RHIC) and the CERN Large Hadron Collider (LHC) energies and compared to available experimental data. It is found that binary scatterings alone cannot reproduce the data and therefore radiative corrections have to be taken into account.

  18. Lewis acidic metal complexes with polydentate ligands for the preparation of biorenewable polymers

    E-Print Network [OSTI]

    Gamboa Martinez, Sergio Aaron; Gamboa, Sergio Aaron M.; Martinez, Sergio Aaron Gamboa

    2014-06-28T23:59:59.000Z

    Due to the ever increasing necessity to reduce our dependence on fossil fuels as feedstocks for polymeric materials, the work presented herein describes the investigation of new metal complexes as initiators for the ...

  19. Energy Conservation Design Features of the ARCO Metals Logan County Aluminum Process Complex

    E-Print Network [OSTI]

    Speer, J. A.

    1983-01-01T23:59:59.000Z

    ARCO Metals Company (Formerly Anaconda Aluminum Company) is proceeding as scheduled with the construction of a $400 Million aluminum processing complex in Logan County, Kentucky. When the initial construction phase is completed in the Fall 1983...

  20. Nonlinear Structure of the Diffusing Gas-Metal Interface in a Thermonuclear Plasma

    E-Print Network [OSTI]

    Molvig, Kim

    This Letter describes the theoretical structure of the plasma diffusion layer that develops from an initially sharp gas-metal interface. The layer dynamics under isothermal and isobaric conditions is considered so that ...

  1. Initiation disruptor systems and methods of initiation disruption

    DOE Patents [OSTI]

    Baum, Dennis W

    2014-09-23T23:59:59.000Z

    A system that may be used as an initiation disruption system (IDS) according to one embodiment includes an explosive charge; a plurality of particles in a layer at least partially surrounding the explosive charge; and a fire suppressant adjacent the plurality of particles. A method for disabling an object according to one embodiment includes placing the system as recited above near an object; and causing the explosive charge to initiate, thereby applying mechanical loading to the object such that the object becomes disabled. Additional systems and methods are also presented. A device according to another embodiment includes a plurality of particles bound by a binder thereby defining a sidewall having an interior for receiving an explosive; and a fire suppressant adjacent the plurality of particles and binder. Additional systems and methods are also presented.

  2. Liquid metal electric pump

    DOE Patents [OSTI]

    Abbin, J.P.; Andraka, C.E.; Lukens, L.L.; Moreno, J.B.

    1992-01-14T23:59:59.000Z

    An electrical pump for pumping liquid metals to high pressures in high temperature environments without the use of magnets or moving mechanical parts. The pump employs a non-porous solid electrolyte membrane, typically ceramic, specific to the liquid metal to be pumped. A DC voltage is applied across the thickness of the membrane causing ions to form and enter the membrane on the electrically positive surface, with the ions being neutralized on the opposite surface. This action provides pumping of the liquid metal from one side of the non-porous solid electrolyte membrane to the other. 3 figs.

  3. Actinide metal processing

    DOE Patents [OSTI]

    Sauer, N.N.; Watkin, J.G.

    1992-03-24T23:59:59.000Z

    A process for converting an actinide metal such as thorium, uranium, or plutonium to an actinide oxide material by admixing the actinide metal in an aqueous medium with a hypochlorite as an oxidizing agent for sufficient time to form the actinide oxide material and recovering the actinide oxide material is described together with a low temperature process for preparing an actinide oxide nitrate such as uranyl nitrate. Additionally, a composition of matter comprising the reaction product of uranium metal and sodium hypochlorite is provided, the reaction product being an essentially insoluble uranium oxide material suitable for disposal or long term storage.

  4. Actinide metal processing

    DOE Patents [OSTI]

    Sauer, Nancy N. (Los Alamos, NM); Watkin, John G. (Los Alamos, NM)

    1992-01-01T23:59:59.000Z

    A process of converting an actinide metal such as thorium, uranium, or plnium to an actinide oxide material by admixing the actinide metal in an aqueous medium with a hypochlorite as an oxidizing agent for sufficient time to form the actinide oxide material and recovering the actinide oxide material is provided together with a low temperature process of preparing an actinide oxide nitrate such as uranyl nitrte. Additionally, a composition of matter comprising the reaction product of uranium metal and sodium hypochlorite is provided, the reaction product being an essentially insoluble uranium oxide material suitable for disposal or long term storage.

  5. Transition Metal Switchable Mirror

    ScienceCinema (OSTI)

    None

    2010-01-08T23:59:59.000Z

    The switchable-mirrors technology was developed by Tom Richardson and Jonathan Slack of Berkeley Lab's Environmental Energy Technologies Division. By using transition metals rather than the rare earth metals used in the first metal-hydride switchable mirrors, Richardson and Slack were able to lower the cost and simplify the manufacturing process. Energy performance is improved as well, because the new windows can reflect or transmit both visible and infrared light. Besides windows for offices and homes, possible applications include automobile sunroofs, signs and displays, aircraft windows, and spacecraft.

  6. Transition Metal Switchable Mirror

    ScienceCinema (OSTI)

    None

    2013-05-29T23:59:59.000Z

    The switchable-mirrors technology was developed by Tom Richardson and Jonathan Slack of Berkeley Lab's Environmental Energy Technologies Division. By using transition metals rather than the rare earth metals used in the first metal-hydride switchable mirrors, Richardson and Slack were able to lower the cost and simplify the manufacturing process. Energy performance is improved as well, because the new windows can reflect or transmit both visible and infrared light. Besides windows for offices and homes, possible applications include automobile sunroofs, signs and displays, aircraft windows, and spacecraft. More information at: http://windows.lbl.gov/materials/chromogenics/default.htm

  7. Transition Metal Switchable Mirror

    SciTech Connect (OSTI)

    None

    2009-01-01T23:59:59.000Z

    The switchable-mirrors technology was developed by Tom Richardson and Jonathan Slack of Berkeley Lab's Environmental Energy Technologies Division. By using transition metals rather than the rare earth metals used in the first metal-hydride switchable mirrors, Richardson and Slack were able to lower the cost and simplify the manufacturing process. Energy performance is improved as well, because the new windows can reflect or transmit both visible and infrared light. Besides windows for offices and homes, possible applications include automobile sunroofs, signs and displays, aircraft windows, and spacecraft. More information at: http://windows.lbl.gov/materials/chromogenics/default.htm

  8. Transition Metal Switchable Mirror

    SciTech Connect (OSTI)

    2009-08-21T23:59:59.000Z

    The switchable-mirrors technology was developed by Tom Richardson and Jonathan Slack of Berkeley Lab's Environmental Energy Technologies Division. By using transition metals rather than the rare earth metals used in the first metal-hydride switchable mirrors, Richardson and Slack were able to lower the cost and simplify the manufacturing process. Energy performance is improved as well, because the new windows can reflect or transmit both visible and infrared light. Besides windows for offices and homes, possible applications include automobile sunroofs, signs and displays, aircraft windows, and spacecraft.

  9. Liquid metal electric pump

    DOE Patents [OSTI]

    Abbin, Joseph P. (Albuquerque, NM); Andraka, Charles E. (Albuquerque, NM); Lukens, Laurance L. (Albuquerque, NM); Moreno, James B. (Albuquerque, NM)

    1992-01-01T23:59:59.000Z

    An electrical pump for pumping liquid metals to high pressures in high temperature environments without the use of magnets or moving mechanical parts. The pump employs a non-porous solid electrolyte membrane, typically ceramic, specific to the liquid metal to be pumped. A DC voltage is applied across the thickness of the membrane causing ions to form and enter the membrane on the electrically positive surface, with the ions being neutralized on the opposite surface. This action provides pumping of the liquid metal from one side of the non-porous solid electrolyte membrane to the other.

  10. Quarkonia Disintegration due to time dependence of the $q \\bar{q}$ potential in Relativistic Heavy Ion Collisions

    E-Print Network [OSTI]

    Partha Bagchi; Ajit M. Srivastava

    2014-11-20T23:59:59.000Z

    Rapid thermalization in ultra-relativistic heavy-ion collisions leads to fast changing potential between a heavy quark and antiquark from zero temperature potential to the finite temperature one. Time dependent perturbation theory can then be used to calculate the survival probability of the initial quarkonium state. In view of very short time scales of thermalization at RHIC and LHC energies, we calculate the survival probability of $J/\\psi$ and $\\Upsilon$ using sudden approximation. Our results show that quarkonium decay may be significant even when temperature of QGP remains low enough so that the conventional quarkonium melting due to Debye screening is ineffective.

  11. Performance of metal and oxide fuels during accidents in a large liquid metal cooled reactor

    SciTech Connect (OSTI)

    Cahalan, J.; Wigeland, R. (Argonne National Lab., IL (USA)); Friedel, G. (Internationale Atomreaktorbau GmbH (INTERATOM), Bergisch Gladbach (Germany, F.R.)); Kussmaul, G.; Royl, P. (Kernforschungszentrum Karlsruhe GmbH (Germany, F.R.)); Moreau, J. (CEA Centre d'Etudes Nucleaires de Cadarache, 13 - Saint-Paul-lez-Durance (France)); Perks, M. (UKAEA Risley Nuclear Power Development Establishment (UK)

    1990-01-01T23:59:59.000Z

    In a cooperative effort among European and US analysts, an assessment of the comparative safety performance of metal and oxide fuels during accidents in a large (3500 MWt), pool-type, liquid-metal-cooled reactor (LMR) was performed. The study focused on three accident initiators with failure to scram: the unprotected loss-of-flow (ULOF), the unprotected transient overpower (UTOP), and the unprotected loss-of-heat-sink (ULOHS). Emphasis was placed on identification of design features that provide passive, self-limiting responses to upset conditions, and quantification of relative safety margins. The analyses show that in ULOF and ULOHS sequences, metal-fueled LMRs with pool-type primary systems provide larger temperature margins to coolant boiling than oxide-fueled reactors of the same design. 3 refs., 4 figs.

  12. Impact of beam transport method on chamber and driver design for heavy ion inertial fusion energy

    E-Print Network [OSTI]

    Rose, D.V.; Welch, D.R.; Olson, C.L.; Yu, S.S.; Neff, S.; Sharp, W.M.

    2002-01-01T23:59:59.000Z

    neutralization on heavy-ion fusion chamber transport, totechniques for heavy ion fusion chamber transport, Nucl.liquid heavy-ion fusion target chambers, Fusion Technol.

  13. Damage Profile and Ion Distribution of Slow Heavy Ions in Compounds...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Profile and Ion Distribution of Slow Heavy Ions in Compounds. Damage Profile and Ion Distribution of Slow Heavy Ions in Compounds. Abstract: Slow heavy ions inevitably produce a...

  14. California Solar Initiative California Public Utilities Commission

    E-Print Network [OSTI]

    California Solar Initiative California Public Utilities Commission Staff Progress Report January 2008 #12;California Solar Initiative, CPUC Staff Progress Report, January 2008 This page intentionally left blank. #12;California Solar Initiative, CPUC Staff Progress Report, January 2008 Table of Contents

  15. Green Button Initiative Growing | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    Initiative Growing Green Button Initiative Growing May 17, 2013 - 1:17pm Addthis The Green Button initiative, which is the common-sense idea that electricity customers should...

  16. Lithium metal reduction of plutonium oxide to produce plutonium metal

    DOE Patents [OSTI]

    Coops, Melvin S. (Livermore, CA)

    1992-01-01T23:59:59.000Z

    A method is described for the chemical reduction of plutonium oxides to plutonium metal by the use of pure lithium metal. Lithium metal is used to reduce plutonium oxide to alpha plutonium metal (alpha-Pu). The lithium oxide by-product is reclaimed by sublimation and converted to the chloride salt, and after electrolysis, is removed as lithium metal. Zinc may be used as a solvent metal to improve thermodynamics of the reduction reaction at lower temperatures. Lithium metal reduction enables plutonium oxide reduction without the production of huge quantities of CaO--CaCl.sub.2 residues normally produced in conventional direct oxide reduction processes.

  17. Divalent metal nanoparticles

    E-Print Network [OSTI]

    DeVries, Gretchen Anne

    2008-01-01T23:59:59.000Z

    Metal nanoparticles hold promise for many scientific and technological applications, such as chemical and biological sensors, vehicles for drug delivery, and subdiffraction limit waveguides. To fabricate such devices, a ...

  18. Production of magnesium metal

    DOE Patents [OSTI]

    Blencoe, James G. (Harriman, TN); Anovitz, Lawrence M. (Knoxville, TN); Palmer, Donald A. (Oliver Springs, TN); Beard, James S. (Martinsville, VA)

    2012-04-10T23:59:59.000Z

    A process of producing magnesium metal includes providing magnesium carbonate, and reacting the magnesium carbonate to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The carbon dioxide is used as a reactant in a second process. In another embodiment of the process, a magnesium silicate is reacted with a caustic material to produce magnesium hydroxide. The magnesium hydroxide is reacted with a source of carbon dioxide to produce magnesium carbonate. The magnesium carbonate is reacted to produce a magnesium-containing compound and carbon dioxide. The magnesium-containing compound is reacted to produce magnesium metal. The invention also relates to the magnesium metal produced by the processes described herein.

  19. Functionalized Silicone Nanospheres: Synthesis, Transition Metal...

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    Functionalized Silicone Nanospheres: Synthesis, Transition Metal Immobilization, and Catalytic Applications. Functionalized Silicone Nanospheres: Synthesis, Transition Metal...

  20. Alloy Design and Thermomechanical Processing of a Beta Titanium Alloy for a Heavy Vehicle Application

    SciTech Connect (OSTI)

    Blue, C.A.; Peter, W.H.

    2010-07-02T23:59:59.000Z

    With the strength of steel, but at half the weight, titanium has the potential to offer significant benefits in the weight reduction of heavy vehicle components while possibly improving performance. However, the cost of conventional titanium fabrication is a major barrier in implementation. New reduction technologies are now available that have the potential to create a paradigm shift in the way the United States uses titanium, and the economics associated with fabrication of titanium components. This CRADA project evaluated the potential to develop a heavy vehicle component from titanium powders. The project included alloy design, development of manufacturing practices, and modeling the economics associated with the new component. New Beta alloys were designed for this project to provide the required mechanical specifications while utilizing the benefits of the new fabrication approach. Manufacturing procedures were developed specific to the heavy vehicle component. Ageing and thermal treatment optimization was performed to provide the desired microstructures. The CRADA partner established fabrication practices and targeted capital investment required for fabricating the component out of titanium. Though initial results were promising, the full project was not executed due to termination of the effort by the CRADA partner and economic trends observed in the heavy vehicle market.

  1. Grazing collisions of gravitational shock waves and entropy production in heavy ion collisions

    SciTech Connect (OSTI)

    Lin Shu; Shuryak, Edward [Department of Physics and Astronomy, SUNY, Stony Brook, New York 11794 (United States)

    2009-06-15T23:59:59.000Z

    AdS/CFT correspondence is now widely used for the study of strongly coupled plasmas, such as those produced in ultrarelativistic heavy ion collisions at the Relativistic Heavy Ion Collider. While properties of equilibrated plasma and small deviations from equilibrium are by now reasonably well understood, the plasma's initial formation and thermal equilibration is a much more challenging issue which remains to be studied. In the dual gravity language, these problems are related to the formation of bulk black holes, and studying trapped surfaces, as we do in this work, is a way to estimate the properties (temperature and entropy) of such black holes. Extending the work by Gubser et al. for central collisions, we find numerically trapped surfaces for noncentral collisions of ultrarelativistic black holes (gravitational shock waves) with different energies. We observe that beyond a certain critical impact parameter, the trapped surface does not exist, and we argue that there are some experimental indications for a similar jump in entropy production as a function of the impact parameter in real heavy ion collisions. We also present a simple solvable example of the so-called wall-on-wall collision, for colliding objects that depend on the holographic coordinate only. Finally, we critically discuss the applicability of the AdS/CFT approach to real-world heavy ion collisions.

  2. Heavy Truck Clean Diesel Cooperative Research Program

    SciTech Connect (OSTI)

    Milam, David

    2006-12-31T23:59:59.000Z

    This report is the final report for the Department of Energy on the Heavy Truck Engine Program (Contract No. DE-FC05-00OR22806) also known as Heavy Truck Clean Diesel (HTCD) Program. Originally, this was scoped to be a $38M project over 5 years, to be 50/50 co-funded by DOE and Caterpillar. The program started in June 2000. During the program the timeline was extended to a sixth year. The program completed in December 2006. The program goal was to develop and demonstrate the technologies required to enable compliance with the 2007 and 2010 (0.2g/bhph NOx, 0.01g/bhph PM) on-highway emission standards for Heavy Duty Trucks in the US with improvements in fuel efficiency compared to today's engines. Thermal efficiency improvement from a baseline of 43% to 50% was targeted.

  3. Molten metal reactors

    DOE Patents [OSTI]

    Bingham, Dennis N; Klingler, Kerry M; Turner, Terry D; Wilding, Bruce M

    2013-11-05T23:59:59.000Z

    A molten metal reactor for converting a carbon material and steam into a gas comprising hydrogen, carbon monoxide, and carbon dioxide is disclosed. The reactor includes an interior crucible having a portion contained within an exterior crucible. The interior crucible includes an inlet and an outlet; the outlet leads to the exterior crucible and may comprise a diffuser. The exterior crucible may contain a molten alkaline metal compound. Contained between the exterior crucible and the interior crucible is at least one baffle.

  4. Guam Initial Technical Assessment Report

    SciTech Connect (OSTI)

    Baring-Gould, I.; Conrad, M.; Haase, S.; Hotchkiss, E.; McNutt, P.

    2011-04-01T23:59:59.000Z

    Under an interagency agreement, funded by the Department of Interior's (DOI) Office of Insular Affairs (OIA), the National Renewable Energy Laboratory (NREL) was tasked to deliver technical assistance to the island of Guam by conducting an island initial technical assessment that would lay out energy consumption and production data and establish a baseline. This assessment will be used to conduct future analysis and studies by NREL that will estimate energy efficiency and renewable energy potential for the island of Guam.

  5. The President's Biofuels Initiative | Department of Energy

    Broader source: Energy.gov (indexed) [DOE]

    The President's Biofuels Initiative The President's Biofuels Initiative Presentation by Neil Rossmeissl at the October 24, 2006 Bio-Derived Liquids to Hydrogen Distributed...

  6. Voluntary Initiative on Incentives: Toolkit Training Webinar...

    Energy Savers [EERE]

    Voluntary Initiative on Incentives: Toolkit Training Webinar Voluntary Initiative on Incentives: Toolkit Training Webinar March 26, 2015 12:30PM to 2:0...

  7. Innovative Corridors Initiative: Business Model Analysis

    E-Print Network [OSTI]

    Shaheen, Susan; Lingham, Viginia; Finson, Rachel S.

    2007-01-01T23:59:59.000Z

    Wenger, Joyce. Business Models for Vehicle InfrastructureCorridors Initiative: Business Model Analysis Rachel S.Corridors Initiative: Business Model Analysis Task Order

  8. Advanced Manufacturing Initiative Improves Turbine Blade Productivity...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Advanced Manufacturing Initiative Improves Turbine Blade Productivity Advanced Manufacturing Initiative Improves Turbine Blade Productivity May 20, 2011 - 2:56pm Addthis This is an...

  9. Climate VISION: Private Sector Initiatives: Cement: Resources...

    Office of Scientific and Technical Information (OSTI)

    The Cement Sustainability Initiative Coordinated by the World Business Council for Sustainable Development, the Cement Sustainability Initiative (CSI) helps the cement...

  10. Clean Coal Power Initiative | Department of Energy

    Office of Environmental Management (EM)

    Clean Coal Power Initiative Clean Coal Power Initiative "Clean coal technology" describes a new generation of energy processes that sharply reduce air emissions and other...

  11. California Low Carbon Fuels Infrastructure Investment Initiative...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Low Carbon Fuels Infrastructure Investment Initiative California Low Carbon Fuels Infrastructure Investment Initiative 2012 DOE Hydrogen and Fuel Cells Program and Vehicle...

  12. Energy Innovation: Green Button Initiative Empowering Americans...

    Energy Savers [EERE]

    Energy Innovation: Green Button Initiative Empowering Americans to Save Energy and Money Energy Innovation: Green Button Initiative Empowering Americans to Save Energy and Money...

  13. Energy Transition Initiative: Islands Playbook (Book) | OSTI...

    Office of Scientific and Technical Information (OSTI)

    Energy Transition Initiative: Islands Playbook (Book) Re-direct Destination: The Island Energy Playbook (the Playbook) provides an action-oriented guide to successfully initiating,...

  14. Joint resummation for heavy quark production.

    E-Print Network [OSTI]

    Banfi, Andrea; Laenen, Eric

    ar X iv :h ep -p h/ 05 10 14 9v 1 1 2 O ct 2 00 5 February 2, 2008 4:14 WSPC/INSTRUCTION FILE jr International Journal of Modern Physics A c World Scientific Publishing Company JOINT RESUMMATION FOR HEAVY QUARK PRODUCTION ANDREA BANFI Cavendish... hadroproduction, at next-to-leading logarithmic accuracy. We exhibit their dependence on the production channel and the color configurations, and compare these distributions to eachother and to NLO. Keywords: Resummation; heavy quark production. 1. Joint threshold...

  15. Recent developments in heavy flavour production

    E-Print Network [OSTI]

    G. Kramer

    2007-07-12T23:59:59.000Z

    We review one-particle inclusive production of heavy-flavoured hadrons in a framework which resums the large collinear logarithms through the evolution of the FFs and PDFs and retains the full dependence on the heavy-quark mass without additional theoretical assumptions. We focus on presenting results for the inclusive cross section for the production of charmed mesons in p anti-p collisions and the comparison with CDF data from the Tevatron as well as on inclusive B-meson production and comparison with recent CDF data. The third topic is the production of D^* mesons in photoproduction and comparison with recent H1 data from HERA.

  16. Full Jet Reconstruction in Heavy Ion Collisions

    E-Print Network [OSTI]

    Sevil Salur

    2009-09-16T23:59:59.000Z

    Full jet reconstruction has traditionally been thought to be difficult in heavy ion events due to large multiplicity backgrounds. The search for new physics in high luminosity p+p collisions at the LHC similarly requires the precise measurement of jets over large backgrounds caused by pile up; this has motivated the development of a new generation of jet reconstruction algorithms which are also applicable in the heavy ion environment. We review the latest results on jet-medium interactions as seen in A+A collisions at RHIC, focusing on the new techniques for full jet reconstruction.

  17. New lattice action for heavy quarks

    SciTech Connect (OSTI)

    Oktay, Mehmet B.; Kronfeld, Andreas S. [Department of Physics, University of Illinois at Urbana-Champaign, Urbana, Illinois 61801 (United States) and School of Mathematics, Trinity College, Dublin 2 (Ireland); Theoretical Physics Department, Fermi National Accelerator Laboratory, Batavia, Illinois 60510 (United States)

    2008-07-01T23:59:59.000Z

    We extend the Fermilab method for heavy quarks to include interactions of dimensions 6 and 7 in the action. There are, in general, many new interactions, but we carry out the calculations needed to match the lattice action to continuum QCD at the tree level, finding six nonzero couplings. Using the heavy-quark theory of cutoff effects, we estimate how large the remaining discretization errors are. We find that our tree-level matching, augmented with one-loop matching of the dimension-5 interactions, can bring these errors below 1%, at currently available lattice spacings.

  18. Electropositive bivalent metallic ion unsaturated polyester complexed polymer concrete

    DOE Patents [OSTI]

    Sugama, T.; Kukacka, L.E.; Horn, W.H.

    1983-05-13T23:59:59.000Z

    Quick setting polymer concrete compositions are described which are mixtures of unsaturated polyesters and crosslinking monomers together with appropriate initiators and promoters in association with aggregate which may be wet and a source of bivalent metallic ions which will set to polymer concrete with excellent structural properties.

  19. Electropositive bivalent metallic ion unsaturated polyester complexed polymer concrete

    DOE Patents [OSTI]

    Sugama, Toshifumi (Mastic Beach, NY); Kukacka, Lawrence E. (Port Jefferson, NY); Horn, William H. (Brookhaven, NY)

    1985-01-01T23:59:59.000Z

    Quick setting polymer concrete compositions with excellent structural properties are disclosed; these polymer concrete compositions are mixtures of unsaturated polyesters and crosslinking monomers together with appropriate initiators and promoters in association with aggregate, which may be wet, and with a source of bivalent metallic ions.

  20. Electropositive bivalent metallic ion unsaturated polyester complexed polymer concrete

    DOE Patents [OSTI]

    Sugama, T.; Kukacka, L.E.; Horn, W.H.

    1981-11-04T23:59:59.000Z

    Quick setting polymer concrete compositions which are mixtures of unsaturated polyesters and crosslinking monomers together with appropriate initiators and promoters in association with aggregate which may be wet and a source of bivalent metallic ions which will set to polymer concrete with excellent structural properties.

  1. The Solar Heavy Element Abundances: I. Constraints from Stellar Interiors

    E-Print Network [OSTI]

    Franck Delahaye; Marc Pinsonneault

    2005-11-29T23:59:59.000Z

    The latest solar atmosphere models include non-LTE corrections and 3D hydrodynamic convection simulations. These models predict a significant reduction in the solar metal abundance, which leads to a serious conflict between helioseismic data and the predictions of solar interiors models. We demonstrate that the helioseismic constraints on the surface convection zone depth and helium abundance combined with stellar interiors models can be used to define the goodness of fit for a given chemical composition. After a detailed examination of the errors in the theoretical models we conclude that models constructed with the older solar abundances are consistent (seismic data. Models constructed with the proposed new low abundance scale are strongly disfavored, disagreeing at the 15 \\sigma level. We then use the sensitivity of the seismic properties to abundance changes to invert the problem and infer a seismic solar heavy element abundance mix with two components: meteoritic abundances, and the light metals CNONe. Seismic degeneracies between the best solutions for the elements arise for changes in the relative CNONe abundances and their effects are quantified. We obtain Fe/H=7.50+/-0.045+/-0.003(CNNe) and O/H=8.86+/-0.041+/-0.025(CNNe) for the relative CNNe in the GS98 mixture. The inferred solar oxygen abundance disagree with the abundance inferred from the 3D hydro models. Changes in the Ne abundance can mimic changes in O for the purposes of scalar constraints.Models constructed with low oxygen and high neon are inconsistent with the solar sound speed profile. The implications for the solar abundance scale are discussed.

  2. Engineering Metal Impurities in Multicrystalline Silicon Solar Cells

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    AFDC Printable Version Share this resource Send a link to EERE: Alternative Fuels Data Center Home Page to someone by E-mail Share EERE: Alternative Fuels Data Center Home Page on Facebook Tweet about EERE: Alternative Fuels Data Center Home Page on Twitter Bookmark EERE: Alternative1 First Use of Energy for All Purposes (Fuel and Nonfuel), 2002; Level: National5Sales for4,645 3,625govInstrumentstdmadapInactiveVisitingContractElectron-StateEnergyHeavyDepartment ofBusinessesEngineering Metal

  3. Measurement of electrons from heavy-flavor decays from $p$+$p$, $d$+Au, and Cu+Cu collisions in the PHENIX experiment

    E-Print Network [OSTI]

    Sanghoon Lim

    2014-08-18T23:59:59.000Z

    Charm and bottom quarks are formed predominantly by gluon fusion in the initial hard scatterings at RHIC, making them good probes of the full medium evolution. Previous measurements at RHIC have shown large suppression and azimuthal anisotropy of open heavy-flavor hadrons in Au+Au collisions at $\\sqrt{s_{NN}}=200~{\\rm GeV}$. Explaining the simultaneously large suppression and flow of heavy quarks has been challenging. To further understand the heavy-flavor transport in the hot and dense medium, it is imperative to also measure cold nuclear matter effects which affect the initial distribution of heavy quarks as well as the system size dependence of the final state suppression. In this talk, new measurements by the PHENIX collaboration of electrons from heavy-flavor decays in $p$+$p$, $d$+Au, and Cu+Cu collisions at $\\sqrt{s_{NN}}=200~{\\rm GeV}$ are presented. In particular, a surprising enhancement of intermediate transverse momentum heavy-flavor decay leptons in $d$+Au at mid and backward rapidity are also seen in mid-central Cu+Cu collisions. This enhancement is much larger than the expectation from anti-shadowing of the parton distributions and is theoretically unexplained.

  4. Petroporphyrins The most abundant and problematic metal compounds in crude oil exist as organic complexes of vanadium

    E-Print Network [OSTI]

    McQuade, D. Tyler

    Petroporphyrins The most abundant and problematic metal compounds in crude oil exist as organic of porphyrins is critical for developing petroleum upgrading processes, as well as linking crude oil to source routine analytical techniques due to the increased complexity associated with heavy crudes. Atmospheric

  5. Method for forming metal contacts

    DOE Patents [OSTI]

    Reddington, Erik; Sutter, Thomas C; Bu, Lujia; Cannon, Alexandra; Habas, Susan E; Curtis, Calvin J; Miedaner, Alexander; Ginley, David S; Van Hest, Marinus Franciscus Antonius Maria

    2013-09-17T23:59:59.000Z

    Methods of forming metal contacts with metal inks in the manufacture of photovoltaic devices are disclosed. The metal inks are selectively deposited on semiconductor coatings by inkjet and aerosol apparatus. The composite is heated to selective temperatures where the metal inks burn through the coating to form an electrical contact with the semiconductor. Metal layers are then deposited on the electrical contacts by light induced or light assisted plating.

  6. Charged Particle and Photon Multiplicity, and Transverse Energy Production in High-Energy Heavy-Ion Collisions

    E-Print Network [OSTI]

    Sahoo, Raghunath; Behera, Nirbhay K; Nandi, Basanta K

    2014-01-01T23:59:59.000Z

    We review the charged particle and photon multiplicity, and transverse energy production in heavy-ion collisions starting from few GeV to TeV energies. The experimental results of pseudorapidity distribution of charged particles and photons at different collision energies and centralities are discussed. We also discuss the hypothesis of limiting fragmentation and expansion dynamics using the Landau hydrodynamics and the underlying physics. Meanwhile, we present the estimation of initial energy density multiplied with formation time as a function of different collision energies and centralities. In the end, the transverse energy per charged particle in connection with the chemical freeze-out criteria is discussed. We invoke various models and phenomenological arguments to interpret and characterize the fireball created in heavy-ion collisions. This review overall provides a scope to understand the heavy-ion collision data and a possible formation of a deconfined phase of partons via the global observables like...

  7. Difficulty of Measuring Emissions from Heavy-Duty Engines Equipped...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Difficulty of Measuring Emissions from Heavy-Duty Engines Equipped with SCR and DPF Difficulty of Measuring Emissions from Heavy-Duty Engines Equipped with SCR and DPF In reference...

  8. Modeling chamber transport for heavy-ion fusion

    E-Print Network [OSTI]

    2002-01-01T23:59:59.000Z

    Modeling Chamber Transport for Heavy-Ion Fusion W. M. Sharp,Peterson, "Chamber Transport of 'Foot' Pulses for Heavy-Ionstate of beam ions. Although several chamber- transport

  9. Chamber transport of "foot" pulses for heavy-ion fusion

    E-Print Network [OSTI]

    Sharp, W.M.; Callahan-Miller, D.A.; Tabak, M.; Yu, S.S.; Peterson, P.F.

    2002-01-01T23:59:59.000Z

    Neutralization on Heavy-Ion-Fusion Chamber Transport," to beChamber transport of "foot" pulses for heavy-ion fusion W.chamber-transport effectiveness is the fraction of enclosed beam ions

  10. INERTIAL FUSION DRIVEN BY INTENSE HEAVY-ION BEAMS

    E-Print Network [OSTI]

    Sharp, W. M.

    2011-01-01T23:59:59.000Z

    HIFAN 1830 INERTIAL FUSION DRIVEN BY INTENSE HEAVY-ION BEAMSAC02-05CH11231. INERTIAL FUSION DRIVEN BY INTENSE HEAVY-ION467 (1992). [38] R. W. Moir, Fusion Tech. 25, 5 (1994) [39

  11. Identification of geometrical and elastostatic parameters of heavy industrial robots

    E-Print Network [OSTI]

    Paris-Sud XI, Universit de

    Identification of geometrical and elastostatic parameters of heavy industrial robots A. Klimchik, Y modeling of heavy industrial robots with gravity compensators. The main attention is paid of huge aircraft compo- nents where industrial robots successfully replace conven- tional CNC

  12. additional heavy bosons: Topics by E-print Network

    Broader source: All U.S. Department of Energy (DOE) Office Webpages (Extended Search)

    21 22 23 24 25 Next Page Last Page Topic Index 1 Anomalous Radiative Decay of Heavy Higgs Boson HEP - Phenomenology (arXiv) Summary: The radiative decay width of a heavy Higgs...

  13. Medium- and Heavy-Duty Electric Drive Vehicle Simulation and...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    Medium- and Heavy-Duty Electric Drive Vehicle Simulation and Analysis Medium- and Heavy-Duty Electric Drive Vehicle Simulation and Analysis 2012 DOE Hydrogen and Fuel Cells Program...

  14. High-Temperature Zirconia Oxygen Sensor with Sealed Metal/Metal...

    Office of Energy Efficiency and Renewable Energy (EERE) Indexed Site

    High-Temperature Zirconia Oxygen Sensor with Sealed MetalMetal Oxide Internal Reference High-Temperature Zirconia Oxygen Sensor with Sealed MetalMetal Oxide Internal Reference...

  15. Dynamic crack initiation toughness : experiments and peridynamic modeling.

    SciTech Connect (OSTI)

    Foster, John T.

    2009-10-01T23:59:59.000Z

    This is a dissertation on research conducted studying the dynamic crack initiation toughness of a 4340 steel. Researchers have been conducting experimental testing of dynamic crack initiation toughness, K{sub Ic}, for many years, using many experimental techniques with vastly different trends in the results when reporting K{sub Ic} as a function of loading rate. The dissertation describes a novel experimental technique for measuring K{sub Ic} in metals using the Kolsky bar. The method borrows from improvements made in recent years in traditional Kolsky bar testing by using pulse shaping techniques to ensure a constant loading rate applied to the sample before crack initiation. Dynamic crack initiation measurements were reported on a 4340 steel at two different loading rates. The steel was shown to exhibit a rate dependence, with the recorded values of K{sub Ic} being much higher at the higher loading rate. Using the knowledge of this rate dependence as a motivation in attempting to model the fracture events, a viscoplastic constitutive model was implemented into a peridynamic computational mechanics code. Peridynamics is a newly developed theory in solid mechanics that replaces the classical partial differential equations of motion with integral-differential equations which do not require the existence of spatial derivatives in the displacement field. This allows for the straightforward modeling of unguided crack initiation and growth. To date, peridynamic implementations have used severely restricted constitutive models. This research represents the first implementation of a complex material model and its validation. After showing results comparing deformations to experimental Taylor anvil impact for the viscoplastic material model, a novel failure criterion is introduced to model the dynamic crack initiation toughness experiments. The failure model is based on an energy criterion and uses the K{sub Ic} values recorded experimentally as an input. The failure model is then validated against one class of problems showing good agreement with experimental results.

  16. Flavor Physics Data from the Heavy Flavor Averaging Group (HFAG)

    DOE Data Explorer [Office of Scientific and Technical Information (OSTI)]

    The Heavy Flavor Averaging Group (HFAG) was established at the May 2002 Flavor Physics and CP Violation Conference in Philadelphia, and continues the LEP Heavy Flavor Steering Group's tradition of providing regular updates to the world averages of heavy flavor quantities. Data are provided by six subgroups that each focus on a different set of heavy flavor measurements: B lifetimes and oscillation parameters, Semi-leptonic B decays, Rare B decays, Unitarity triangle parameters, B decays to charm final states, and Charm Physics.

  17. Measurements of Heavy Flavour Production at ATLAS and CMS

    E-Print Network [OSTI]

    Gladilin, Leonid; The ATLAS collaboration

    2015-01-01T23:59:59.000Z

    New and updated (after the previous Moriond QCD) ATLAS and CMS results on heavy flavour production are reviewed.

  18. Systems of two heavy quarks with effective field theories

    E-Print Network [OSTI]

    Nora Brambilla

    2006-09-22T23:59:59.000Z

    I discuss results and applications of QCD nonrelativistic effective field theories for systems with two heavy quarks.

  19. The quarkonium saga in heavy ion collisions

    E-Print Network [OSTI]

    Tserruya, Itzhak

    2013-01-01T23:59:59.000Z

    J/psi suppression was proposed more than 25 years ago as an unambiguous signature for the formation of the Quark Gluon Plasma in relativistic heavy ion collisions. After intensive efforts, both experimental and theoretical, the quarkonium saga remains exciting, producing surprising results and not fully understood. This talk focuses on recent results on quarkonium production at RHIC and the LHC.

  20. Thermal processes for heavy oil recovery

    SciTech Connect (OSTI)

    Sarkar, A.K.; Sarathi, P.S.

    1993-11-01T23:59:59.000Z

    This status report summarizes the project BE11B (Thermal Processes for Heavy Oil Recovery) research activities conducted in FY93 and completes milestone 7 of this project. A major portion of project research during FY93 was concentrated on modeling and reservoir studies to determine the applicability of steam injection oil recovery techniques in Texas Gulf Coast heavy oil reservoirs. In addition, an in-depth evaluation of a steamflood predictive model developed by Mobil Exploration and Production Co. (Mobil E&P) was performed. Details of these two studies are presented. A topical report (NIPER-675) assessing the NIPER Thermal EOR Research Program over the past 10 years was also written during this fiscal year and delivered to DOE. Results of the Gulf Coast heavy oil reservoir simulation studies indicated that though these reservoirs can be successfully steamflooded and could recover more than 50% of oil-in-place, steamflooding may not be economical at current heavy oil prices. Assessment of Mobil E&P`s steamflood predictive model capabilities indicate that the model in its present form gives reasonably good predictions of California steam projects, but fails to predict adequately the performance of non-California steam projects.